National Library of Energy BETA

Sample records for nickel-metal hydride packs

  1. Hydridable material for the negative electrode in a nickel-metal hydride storage battery

    DOE Patents [OSTI]

    Knosp, Bernard (Neuilly-sur-Seine, FR); Bouet, Jacques (Paris, FR); Jordy, Christian (Dourdan, FR); Mimoun, Michel (Neuilly-sur-Marne, FR); Gicquel, Daniel (Lanorville, FR)

    1997-01-01

    A monophase hydridable material for the negative electrode of a nickel-metal hydride storage battery with a "Lave's phase" structure of hexagonal C14 type (MgZn.sub.2) has the general formula: Zr.sub.1-x Ti.sub.x Ni.sub.a Mn.sub.b Al.sub.c Co.sub.d V.sub.e where ##EQU1##

  2. Mathematical modeling of the nickel/metal hydride battery system

    SciTech Connect (OSTI)

    Paxton, B K [Univ. of California, Berkeley, CA (United States). Dept. of Chemical Engineering

    1995-09-01

    A group of compounds referred to as metal hydrides, when used as electrode materials, is a less toxic alternative to the cadmium hydroxide electrode found in nickel/cadmium secondary battery systems. For this and other reasons, the nickel/metal hydride battery system is becoming a popular rechargeable battery for electric vehicle and consumer electronics applications. A model of this battery system is presented. Specifically the metal hydride material, LaNi{sub 5}H{sub 6}, is chosen for investigation due to the wealth of information available in the literature on this compound. The model results are compared to experiments found in the literature. Fundamental analyses as well as engineering optimizations are performed from the results of the battery model. In order to examine diffusion limitations in the nickel oxide electrode, a ``pseudo 2-D model`` is developed. This model allows for the theoretical examination of the effects of a diffusion coefficient that is a function of the state of charge of the active material. It is found using present data from the literature that diffusion in the solid phase is usually not an important limitation in the nickel oxide electrode. This finding is contrary to the conclusions reached by other authors. Although diffusion in the nickel oxide active material is treated rigorously with the pseudo 2-D model, a general methodology is presented for determining the best constant diffusion coefficient to use in a standard one-dimensional battery model. The diffusion coefficients determined by this method are shown to be able to partially capture the behavior that results from a diffusion coefficient that varies with the state of charge of the active material.

  3. Feasibility study for the recycling of nickel metal hydride electric vehicle batteries. Final report

    SciTech Connect (OSTI)

    Sabatini, J.C.; Field, E.L.; Wu, I.C.; Cox, M.R.; Barnett, B.M.; Coleman, J.T. [Little (Arthur D.), Inc., Cambridge, MA (United States)

    1994-01-01

    This feasibility study examined three possible recycling processes for two compositions (AB{sub 2} and AB{sub 5}) of nickel metal hydride electric vehicle batteries to determine possible rotes for recovering battery materials. Analysts examined the processes, estimated the costs for capital equipment and operation, and estimated the value of the reclaimed material. They examined the following three processes: (1) a chemical process that leached battery powders using hydrochloric acid, (2) a pyrometallurical process, and (3) a physical separation/chemical process. The economic analysis revealed that the physical separation/chemical process generated the most revenue.

  4. Models for Metal Hydride Particle Shape, Packing, and Heat Transfer

    E-Print Network [OSTI]

    Kyle C. Smith; Timothy S. Fisher

    2012-05-04

    A multiphysics modeling approach for heat conduction in metal hydride powders is presented, including particle shape distribution, size distribution, granular packing structure, and effective thermal conductivity. A statistical geometric model is presented that replicates features of particle size and shape distributions observed experimentally that result from cyclic hydride decreptitation. The quasi-static dense packing of a sample set of these particles is simulated via energy-based structural optimization methods. These particles jam (i.e., solidify) at a density (solid volume fraction) of 0.665+/-0.015 - higher than prior experimental estimates. Effective thermal conductivity of the jammed system is simulated and found to follow the behavior predicted by granular effective medium theory. Finally, a theory is presented that links the properties of bi-porous cohesive powders to the present systems based on recent experimental observations of jammed packings of fine powder. This theory produces quantitative experimental agreement with metal hydride powders of various compositions.

  5. A non-isothermal model of a nickelmetal hydride cell , M. Mohammedb

    E-Print Network [OSTI]

    A non-isothermal model of a nickel±metal hydride cell B. Wua , M. Mohammedb , D. Brighamb , R. Elderb , R.E. Whitea,* a Department of Chemical Engineering, University of South Carolina, Columbia, SC Abstract A model for a nickel±metal hydride cell was constructed based on the planar electrode

  6. Steps to Commercialization: Nickel Metal Hydride Batteries | Department of

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirley Ann JacksonDepartment of EnergyResearchers at the Energyonecelebrates specialwarmEnergy

  7. Steps to Commercialization: Nickel Metal Hydride Batteries | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative FuelsofProgram: Report15 Meeting State Energy Advisory BoardStateFailures

  8. CRADA (AL-C-2009-02) Final Report: Phase I. Lanthanum-based Start Materials for Hydride Batteries

    SciTech Connect (OSTI)

    Gschneidner, Jr., Karl; Schmidt, Frederick; Frerichs, A.E.; Ament, Katherine A.

    2013-05-01

    The purpose of Phase I of this work is to focus on developing a La-based start material for making nickel-metal (lanthanum)-hydride batteries based on our carbothermic-silicon process. The goal is to develop a protocol for the manufacture of (La{sub 1-x}R{sub x})(Ni{sub 1-y}M{sub y})(Si{sub z}), where R is a rare earth metal and M is a non-rare earth metal, to be utilized as the negative electrode in nickel-metal hydride (NiMH) rechargeable batteries.

  9. Analytical assessment of the thermal behavior of nickel-metal hydride batteries

    E-Print Network [OSTI]

    Bahrami, Majid

    * , Maryam Yazdanpour, Majid Bahrami Laboratory for Alternative Energy Conversion (LAEC), Mechatronic Systems value problems of heat conduction, Dover Publications, New York, 1989 [3] M.S. Wu et al., J. Power Sour inside the battery can be approximated from the well-known energy balance analysis proposed by Bernardi

  10. Method Of Charging Maintenance-Free Nickel Metal Hydride Storage Cells

    DOE Patents [OSTI]

    Berlureau, Thierry (Bordeaux, FR); Liska, Jean-Louis (Bordeaux, FR)

    1999-11-16

    A method of charging an industrial maintenance-free Ni-MH storage cell, the method comprising in combination a first stage at a constant current I.sub.1 lying in the range I.sub.c /10 to I.sub.c /2, and a second stage at a constant current I.sub.2 lying in the range I.sub.c /50 to I.sub.c /10, the changeover from the first stage to the second stage taking place when the time derivative of the temperature reaches a threshold value which varies as a function of the temperature at the time of the changeover.

  11. Improving nickel metal hydride batteries through research in negative electrode corrosion control and novel electrode materials 

    E-Print Network [OSTI]

    Alexander, Michael Scott

    1997-01-01

    electrode materials. In order to fully understand the processes involved in the corrosion study, tests were carried at Brookhaven National Laboratory using X-ray Absorption Near Edge Spectroscopy. These tests showed that Zn prevented the corrosion of Ni...

  12. Hydride compositions

    DOE Patents [OSTI]

    Lee, Myung, W.

    1994-01-01

    Disclosed are a composition for use in storing hydrogen and a method for making the composition. The composition comprises a mixture of two or more hydrides, each hydride having a different series of hydrogen sorption isotherms that contribute to the overall isotherms of the mixture. The hydrides are chosen so that the isotherms of the mixture have regions wherein the H equilibrium pressure increases with increasing hydrogen, preferably linearly. The isotherms of the mixture can be adjusted by selecting hydrides with different isotherms and by varying the amounts of the individual hydrides, or both. Preferably, the mixture is made up of hydrides that have isotherms with substantially flat plateaus and in nearly equimolar amounts. The composition is activated by degassing, exposing to H, and then heating below the softening temperature of any of the constituents. When the composition is used to store hydrogen, its hydrogen content can be found simply by measuring P{sub H}{sub 2} and determining H/M from the isothermic function of the composition.

  13. Metal Hydride Hydrogen Storage Research and Development

    Broader source: Energy.gov [DOE]

    DOE's research on complex metal hydrides targets the development of advanced metal hydride materials including light-weight complex hydrides, destabilized binary hydrides, intermetallic hydrides,...

  14. Hydride compressor

    DOE Patents [OSTI]

    Powell, James R. (Wading River, NY); Salzano, Francis J. (Patchogue, NY)

    1978-01-01

    Method of producing high energy pressurized gas working fluid power from a low energy, low temperature heat source, wherein the compression energy is gained by using the low energy heat source to desorb hydrogen gas from a metal hydride bed and the desorbed hydrogen for producing power is recycled to the bed, where it is re-adsorbed, with the recycling being powered by the low energy heat source. In one embodiment, the adsorption-desorption cycle provides a chemical compressor that is powered by the low energy heat source, and the compressor is connected to a regenerative gas turbine having a high energy, high temperature heat source with the recycling being powered by the low energy heat source.

  15. Destabilization of magnesium hydride through interface engineering

    E-Print Network [OSTI]

    Dam, Bernard

    Destabilization of magnesium hydride through interface engineering Lennard Mooij #12;Destabilization of magnesium hydride through interface engineering PROEFSCHRIFT ter verkrijging van de graad van . . . . . . . . . . . . . . . . . . . . . . . . . 10 1.3 Magnesium hydride . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13 1

  16. Method for preparing porous metal hydride compacts

    DOE Patents [OSTI]

    Ron, M.; Gruen, D.M.; Mendelsohn, M.H.; Sheft, I.

    1980-01-21

    A method for preparing porous metallic-matrix hydride compacts which can be repeatedly hydrided and dehydrided without disintegration. A mixture of a finely divided metal hydride and a finely divided matrix metal is contacted with a poison which prevents the metal hydride from dehydriding at room temperature and atmospheric pressure. The mixture of matrix metal and poisoned metal hydride is then compacted under pressure at room temperature to form porous metallic-matrix hydride compacts.

  17. Method for preparing porous metal hydride compacts

    DOE Patents [OSTI]

    Ron, Moshe (Haifa, IL); Gruen, Dieter M. (Downers Grove, IL); Mendelsohn, Marshall H. (Woodridge, IL); Sheft, Irving (Oak Park, IL)

    1981-01-01

    A method for preparing porous metallic-matrix hydride compacts which can be repeatedly hydrided and dehydrided without disintegration. A mixture of a finely divided metal hydride and a finely divided matrix metal is contacted with a poison which prevents the metal hydride from dehydriding at room temperature and atmospheric pressure. The mixture of matrix metal and poisoned metal hydride is then compacted under pressure at room temperature to form porous metallic-matrix hydride compacts.

  18. Packed Lunches. 

    E-Print Network [OSTI]

    Reasonover, Frances L.

    1982-01-01

    puddings; hard cheeses; unopen ed, r~urized process cheese spreads. Jot Group. Canned potted meats, canned meat spreads, canned Vienna sausages, canned luncheon meats, jerky and canned fish such as salmon, sardines, shrimp, tuna; peanut butter and nuts.... Wash your hands before handling the food and clean the working areas and utensils used to prepare it. Also store food properly after it is purchased. Packing Pointers Time Savers Buy fresh fruits that only require washing in prepa ration for lunch...

  19. Dimensionally stable metallic hydride composition

    DOE Patents [OSTI]

    Heung, Leung K. (Aiken, SC)

    1994-01-01

    A stable, metallic hydride composition and a process for making such a composition. The composition comprises a uniformly blended mixture of a metal hydride, kieselguhr, and a ballast metal, all in the form of particles. The composition is made by subjecting a metal hydride to one or more hydrogen absorption/desorption cycles to disintegrate the hydride particles to less than approximately 100 microns in size. The particles are partly oxidized, then blended with the ballast metal and the kieselguhr to form a uniform mixture. The mixture is compressed into pellets and calcined. Preferably, the mixture includes approximately 10 vol. % or more kieselguhr and approximately 50 vol. % or more ballast. Metal hydrides that can be used in the composition include Zr, Ti, V, Nb, Pd, as well as binary, tertiary, and more complex alloys of La, Al, Cu, Ti, Co, Ni, Fe, Zr, Mg, Ca, Mn, and mixtures and other combinations thereof. Ballast metals include Al, Cu and Ni.

  20. Characteristics of Interconnected Delta-Hydride Precipitates in Zr

    SciTech Connect (OSTI)

    L.J. Carroll; M.R. Tonks; T.M. Lillo; B.S. Fromm; DC Haggard; T.C. Morris; W.D. Swank; T.L. Trowbridge; M.C. Carroll

    2014-09-01

    Characterization of extended delta-ZrH1.66 structures in unalloyed zirconium by electron backscatter diffraction analysis confirms that they consist of many interconnected precipitates of multiple, but distinctly related, orientations. The expected orientation relationship of (0001)a-Zr//(111)delta-ZrH1.66 is confirmed between the hydride and one of the surrounding a-Zr matrix grains. The delta-ZrH1.66 precipitates do not extend in a discrete crystalline orientation, but are regularly divided by 60° type {111} twins in which adjacent delta-ZrH1.66 grains share a {111} plane. The observed matching of the close-packed FCC planes of impinging or twinned hydrides within an interconnected structure enables the minimization of the overall interfacial energy through successive nucleation and growth events and twinning.

  1. Low density metal hydride foams

    DOE Patents [OSTI]

    Maienschein, Jon L. (Oakland, CA); Barry, Patrick E. (Pleasant Hill, CA)

    1991-01-01

    Disclosed is a low density foam having a porosity of from 0 to 98% and a density less than about 0.67 gm/cc, prepared by heating a mixture of powered lithium hydride and beryllium hydride in an inert atmosphere at a temperature ranging from about 455 to about 490 K for a period of time sufficient to cause foaming of said mixture, and cooling the foam thus produced. Also disclosed is the process of making the foam.

  2. Metal Hydride Chemical Heat Pumps for Industrial Use 

    E-Print Network [OSTI]

    Ally, M. R.; Rebello, W. J.; Rosso, M. J., Jr.

    1984-01-01

    occasionally, the ideal behaviour shown in Figure 1 is observed, in practice there are usually slight deviations from this ideal. Fig ure 2 shows isotherms obtained for a gractical nickel-aluminium-mischmetal compound. t1) Note that the plateau is sloped.... The expansion is accomodated by the loosely packed individual capsules, preventing any stress on the main container walls. Each capsule is a thin-walled aluminium tube containing the hydride can, capped on one or both ends with a porous metal filter. Such a...

  3. Hydrogen, lithium, and lithium hydride production

    DOE Patents [OSTI]

    Brown, Sam W; Spencer, Larry S; Phillips, Michael R; Powell, G. Louis; Campbell, Peggy J

    2014-03-25

    A method of producing high purity lithium metal is provided, where gaseous-phase lithium metal is extracted from lithium hydride and condensed to form solid high purity lithium metal. The high purity lithium metal may be hydrided to provide high purity lithium hydride.

  4. Ab initio treatment of electron correlations in polymers: Lithium hydride chain and beryllium hydride polymer

    E-Print Network [OSTI]

    Birkenheuer, Uwe

    Ab initio treatment of electron correlations in polymers: Lithium hydride chain and berylliumH and beryllium hydride Be2H4 . First, employing a Wannier-function-based approach, the systems are studiedH and the beryllium hydride polymer Be2H4 . As a simple, but due to its ionic character, non- trivial model polymer

  5. Complex hydrides for hydrogen storage

    DOE Patents [OSTI]

    Zidan, Ragaiy

    2006-08-22

    A hydrogen storage material and process of forming the material is provided in which complex hydrides are combined under conditions of elevated temperatures and/or elevated temperature and pressure with a titanium metal such as titanium butoxide. The resulting fused product exhibits hydrogen desorption kinetics having a first hydrogen release point which occurs at normal atmospheres and at a temperature between 50.degree. C. and 90.degree. C.

  6. Incorporation of Hydride Nuclear Fuels in Commercial Light Water Reactors

    E-Print Network [OSTI]

    Terrani, Kurt Amir

    2010-01-01

    1.2.1 PWRs . . . . . . . . . . . . . . . . . . . . 1.2.2Actinides Multi-Recycling in PWR Using Hydride Fuels. InRecycling in Hydride Fueled PWR Cores. Nuclear Engineering

  7. Direct synthesis of catalyzed hydride compounds

    DOE Patents [OSTI]

    Gross, Karl J.; Majzoub, Eric

    2004-09-21

    A method is disclosed for directly preparing alkali metal aluminum hydrides such as NaAlH.sub.4 and Na.sub.3 AlH.sub.6 from either the alkali metal or its hydride, and aluminum. The hydride thus prepared is doped with a small portion of a transition metal catalyst compound, such as TiCl.sub.3, TiF.sub.3, or a mixture of these materials, in order to render them reversibly hydridable. The process provides for mechanically mixing the dry reagents under an inert atmosphere followed by charging the mixed materials with high pressure hydrogen while heating the mixture to about 125.degree. C. The method is relatively simple and inexpensive and provides reversible hydride compounds which are free of the usual contamination introduced by prior art wet chemical methods.

  8. Activated aluminum hydride hydrogen storage compositions and uses thereof

    DOE Patents [OSTI]

    Sandrock, Gary (Ringwood, NJ); Reilly, James (Bellport, NY); Graetz, Jason (Mastic, NY); Wegrzyn, James E. (Brookhaven, NY)

    2010-11-23

    In one aspect, the invention relates to activated aluminum hydride hydrogen storage compositions containing aluminum hydride in the presence of, or absence of, hydrogen desorption stimulants. The invention particularly relates to such compositions having one or more hydrogen desorption stimulants selected from metal hydrides and metal aluminum hydrides. In another aspect, the invention relates to methods for generating hydrogen from such hydrogen storage compositions.

  9. Wire Wrapped Hexagonal Pin Arrays for Hydride Fueled PWRs

    E-Print Network [OSTI]

    Diller, Peter

    This work contributes to the Hydride Fuels Project, a collaborative effort between UC Berkeley and MIT

  10. Hydrogen-storing hydride complexes

    DOE Patents [OSTI]

    Srinivasan, Sesha S. (Tampa, FL); Niemann, Michael U. (Venice, FL); Goswami, D. Yogi (Tampa, FL); Stefanakos, Elias K. (Tampa, FL)

    2012-04-10

    A ternary hydrogen storage system having a constant stoichiometric molar ratio of LiNH.sub.2:MgH.sub.2:LiBH.sub.4 of 2:1:1. It was found that the incorporation of MgH.sub.2 particles of approximately 10 nm to 20 nm exhibit a lower initial hydrogen release temperature of 150.degree. C. Furthermore, it is observed that the particle size of LiBNH quaternary hydride has a significant effect on the hydrogen sorption concentration with an optimum size of 28 nm. The as-synthesized hydrides exhibit two main hydrogen release temperatures, one around 160.degree. C. and the other around 300.degree. C., with the main hydrogen release temperature reduced from 310.degree. C. to 270.degree. C., while hydrogen is first reversibly released at temperatures as low as 150.degree. C. with a total hydrogen capacity of 6 wt. % to 8 wt. %. Detailed thermal, capacity, structural and microstructural properties have been demonstrated and correlated with the activation energies of these materials.

  11. Liquid suspensions of reversible metal hydrides

    DOE Patents [OSTI]

    Reilly, J.J.; Grohse, E.W.; Winsche, W.E.

    1983-12-08

    The reversibility of the process M + x/2 H/sub 2/ ..-->.. MH/sub x/, where M is a metal hydride former that forms a hydride MH/sub x/ in the presence of H/sub 2/, generally used to store and recall H/sub 2/, is found to proceed under a liquid, thereby to reduce contamination, provide better temperature control and provide in situ mobility of the reactants. Thus, a slurry of particles of a metal hydride former with an inert solvent is subjected to temperature and pressure controlled atmosphere containing H/sub 2/, to store hydrogen (at high pressures) and to release (at low pressures) previously stored hydrogen. The direction of the flow of the H/sub 2/ through the liquid is dependent upon the H/sub 2/ pressure in the gas phase at a given temperature. When the former is above the equilibrium absorption pressure of the respective hydride the reaction proceeds to the right, i.e., the metal hydride is formed and hydrogen is stored in the solid particle. When the H/sub 2/ pressure in the gas phase is below the equilibrium dissociation pressure of the respective hydride the reaction proceeds to the left, the metal hydride is decomposed and hydrogen is released into the gas phase.

  12. Graphitic packing removal tool

    DOE Patents [OSTI]

    Meyers, Kurt Edward (Avella, PA); Kolsun, George J. (Pittsburgh, PA)

    1997-01-01

    Graphitic packing removal tools for removal of the seal rings in one piece. he packing removal tool has a cylindrical base ring the same size as the packing ring with a surface finish, perforations, knurling or threads for adhesion to the seal ring. Elongated leg shanks are mounted axially along the circumferential center. A slit or slits permit insertion around shafts. A removal tool follower stabilizes the upper portion of the legs to allow a spanner wrench to be used for insertion and removal.

  13. Graphitic packing removal tool

    DOE Patents [OSTI]

    Meyers, K.E.; Kolsun, G.J.

    1997-11-11

    Graphitic packing removal tools for removal of the seal rings in one piece are disclosed. The packing removal tool has a cylindrical base ring the same size as the packing ring with a surface finish, perforations, knurling or threads for adhesion to the seal ring. Elongated leg shanks are mounted axially along the circumferential center. A slit or slits permit insertion around shafts. A removal tool follower stabilizes the upper portion of the legs to allow a spanner wrench to be used for insertion and removal. 5 figs.

  14. Metastable Metal Hydrides for Hydrogen Storage

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Graetz, Jason

    2012-01-01

    The possibility of using hydrogen as a reliable energy carrier for both stationary and mobile applications has gained renewed interest in recent years due to improvements in high temperature fuel cells and a reduction in hydrogen production costs. However, a number of challenges remain and new media are needed that are capable of safely storing hydrogen with high gravimetric and volumetric densities. Metal hydrides and complex metal hydrides offer some hope of overcoming these challenges; however, many of the high capacity “reversible” hydrides exhibit a large endothermic decomposition enthalpy making it difficult to release the hydrogen at low temperatures. Onmore »the other hand, the metastable hydrides are characterized by a low reaction enthalpy and a decomposition reaction that is thermodynamically favorable under ambient conditions. The rapid, low temperature hydrogen evolution rates that can be achieved with these materials offer much promise for mobile PEM fuel cell applications. However, a critical challenge exists to develop new methods to regenerate these hydrides directly from the reactants and hydrogen gas. This spotlight paper presents an overview of some of the metastable metal hydrides for hydrogen storage and a few new approaches being investigated to address the key challenges associated with these materials.« less

  15. METALLIC HYDRIDES. Magnetic properties of laves-phase rare earth hydrides

    E-Print Network [OSTI]

    Boyer, Edmond

    METALLIC HYDRIDES. Magnetic properties of laves-phase rare earth hydrides J. J. Rhyne and G. E on the rare earth site. The rare earth spins disorder at a temperature lower than the bulk Tc in ErFe2 H3 5 per formula unit assuming complete occupation of 3 tetrahedral sites. The heavy rare earth (RFe2

  16. Optimization of hydride fueled pressurized water reactor cores

    E-Print Network [OSTI]

    Shuffler, Carter Alexander

    2004-01-01

    This thesis contributes to the Hydride Fuels Project, a collaborative effort between UC Berkeley and MIT aimed at investigating the potential benefits of hydride fuel use in light water reactors (LWRs). This pursuit involves ...

  17. Advances in Design of the Next Generation Hydride Bed | Department...

    Office of Environmental Management (EM)

    Design of the Next Generation Hydride Bed Advances in Design of the Next Generation Hydride Bed Presentation from the 32nd Tritium Focus Group Meeting held in Germantown, Maryland...

  18. Thermal hydraulic analysis of hydride fuels in BWR's

    E-Print Network [OSTI]

    Creighton, John Everett

    2005-01-01

    This thesis contributes to the hydride nuclear fuel project being completed by UC Berkeley and MIT to assess the possible benefits of using hydride fuel in light water nuclear reactors (LWR's). More specifically, this ...

  19. Professional Training Information Pack

    E-Print Network [OSTI]

    Davies, Christopher

    Intending Professional Training Students Year 2 Information Pack #12;- 1 - Applying for a Professional Training Placement To be allowed to do the Professional Training you must have enrolled on one must talk to Dr J. M. Thompson immediately. General introduction to professional training Students

  20. Optimization of blended battery packs

    E-Print Network [OSTI]

    Erb, Dylan C. (Dylan Charles)

    2013-01-01

    This thesis reviews the traditional battery pack design process for hybrid and electric vehicles, and presents a dynamic programming (DP) based algorithm that eases the process of cell selection and pack design, especially ...

  1. Atomistic Potentials for Palladium-Silver Hydrides

    E-Print Network [OSTI]

    Hale, L M; Zimmerman, J A; Zhou, X

    2013-01-01

    New EAM potentials for the ternary palladium-silver-hydrogen system are developed by extending a previously developed palladium-hydrogen potential. The ternary potentials accurately capture the heat of mixing and structural properties associated with solid solution alloys of palladium-silver. Stable hydrides are produced with properties that smoothly transition across the compositions. Additions of silver to palladium are predicted to alter the properties of the hydrides by decreasing the miscibility gap and increasing the likelihood of hydrogen atoms occupying tetrahedral interstitial sites over octahedral interstitial sites.

  2. Packed Bed Combustion: An Overview

    E-Print Network [OSTI]

    Hallett, William L.H.

    Packed Bed Combustion: An Overview William Hallett Dept. of Mechanical Engineering Université d'Ottawa - University of Ottawa #12;Packed Bed Combustion - University of Ottawa - CICS 2005 Introduction air fuel feedproducts xbed grate Packed Bed Combustion: fairly large particles of solid fuel on a grate, air supplied

  3. Metal hydride fuel storage and method thereof

    DOE Patents [OSTI]

    Morse, Jeffrey D. (Martinez, CA); Jankowski, Alan F. (Livermore, CA); Yu, Conrad (Antioch, CA)

    2006-10-17

    Disclosed herein is a metal hydride fuel storage cartridge having integrated resistive heaters that can be used in conjunction with fuel cells such as MEMS-based fuel cells. The cartridge is fabricated using micromachining methods and thin/thick film materials synthesis techniques.

  4. Metal hydride fuel storage and method thereof

    DOE Patents [OSTI]

    Morse, Jeffrey D [Martinez, CA; Jankowski, Alan F [Livermore, CA; Yu, Conrad [Antioch, CA

    2009-05-05

    Disclosed herein is a metal hydride fuel storage cartridge having integrated resistive heaters that can be used in conjunction with fuel cells such as MEMS-based fuel cells. The cartridge is fabricated using micromachining methods and thin/thick film materials synthesis techniques.

  5. Enumerating rigid sphere packings

    E-Print Network [OSTI]

    Miranda C. Holmes-Cerfon

    2015-05-08

    Packing problems, which ask how to arrange a collection of objects in space to meet certain criteria, are important in a great many physical and biological systems, where geometrical arrangements at small scales control behaviour at larger ones. In many systems there is no single, optimal packing that dominates, but rather one must understand the entire set of possible packings. As a step in this direction we enumerate rigid clusters of identical hard spheres for $n\\leq 14$, and clusters with the maximum number of contacts for $n\\leq 19$. A rigid cluster is one that cannot be continuously deformed while maintaining all contacts. This is a nonlinear notion that arises naturally because such clusters are the metastable states when the spheres interact with a short-range potential, as is the case in many nano- or micro-scale systems. We expect these lists are nearly complete, except for a small number of highly singular clusters (linearly floppy but nonlinearly rigid.) The data contains some major geometrical surprises, such as the prevalence of hypostatic clusters: those with less than the $3n-6$ contacts generically necessary for rigidity. We discuss these and several other unusual clusters, whose geometries may shed insight into physical mechanisms, pose mathematical and computational problems, or bring inspiration for designing new materials.

  6. What to Pack for Mars

    E-Print Network [OSTI]

    De Weck, Olivier L.

    De Weck, O.L. “What to Pack for Mars.” Spectrum, IEEE 46.6 (2009): 39. © 2009 Institute of Electrical and Electronics Engineers

  7. SANS Measurement of Hydrides in Uranium

    SciTech Connect (OSTI)

    Spooner, S; Ludtka, G.M.; Bullock, J.S.; Bridges, R.L.; Powell, G.L.

    2001-09-04

    SANS scattering is shown to be an effective method for detecting the presence of hydrogen precipitates in uranium. High purity polycrystalline samples of depleted uranium were given several hydriding treatments which included extended exposures to hydrogen gas at two different pressures at 630 C as well as a furnace anneal at 850 C followed by slow cooling in the near absence hydrogen gas. All samples exhibited neutron scattering that was in proportion to the expected levels of hydrogen content. While the scattering signal was strong, the shape of the scattering curve indicated that the scattering objects were large sized objects. Only by use of a very high angular resolution SANS technique was it possible to make estimates of the major diameter of the scattering objects. This analysis permits an estimate of the volume fraction and means size of the hydride precipitates in uranium.

  8. METAL HYDRIDE HYDROGEN COMPRESSORS: A REVIEW

    SciTech Connect (OSTI)

    Bowman Jr, Robert C; Yartys, Dr. Volodymyr A.; Lototskyy, Dr. Michael V; Pollet, Dr. B.G.

    2014-01-01

    Metal hydride (MH) thermal sorption compression is an efficient and reliable method allowing a conversion of energy from heat into a compressed hydrogen gas. The most important component of such a thermal engine the metal hydride material itself should possess several material features in order to achieve an efficient performance in the hydrogen compression. Apart from the hydrogen storage characteristics important for every solid H storage material (e.g. gravimetric and volumetric efficiency of H storage, hydrogen sorption kinetics and effective thermal conductivity), the thermodynamics of the metal-hydrogen systems is of primary importance resulting in a temperature dependence of the absorption/desorption pressures). Several specific features should be optimized to govern the performance of the MH-compressors including synchronisation of the pressure plateaus for multi-stage compressors, reduction of slope of the isotherms and hysteresis, increase of cycling stability and life time, together with challenges in system design associated with volume expansion of the metal matrix during the hydrogenation. The present review summarises numerous papers and patent literature dealing with MH hydrogen compression technology. The review considers (a) fundamental aspects of materials development with a focus on structure and phase equilibria in the metal-hydrogen systems suitable for the hydrogen compression; and (b) applied aspects, including their consideration from the applied thermodynamic viewpoint, system design features and performances of the metal hydride compressors and major applications.

  9. Incorporation of Hydride Nuclear Fuels in Commercial Light Water Reactors

    E-Print Network [OSTI]

    Terrani, Kurt Amir

    2010-01-01

    Uranium in the fuel remains metallic since the equilibriumtype of hydride fuel consists of metallic uranium particlesalloying the metallic components of the fuel followed by a

  10. Documentation of Hybrid Hydride Model for Incorporation into...

    Energy Savers [EERE]

    does not currently solve the stress state that forms dynamically in the precipitate or matrix surrounding the precipitate. A path forward is presented. DocHybridHydrid...

  11. Incorporation of Hydride Nuclear Fuels in Commercial Light Water Reactors

    E-Print Network [OSTI]

    Terrani, Kurt Amir

    2010-01-01

    filled gap between the zirconia layer and the hydride fuel (calculated peaks for zirconia is possibly due to preferredpossibly coupled with a thin zirconia layer, as a kinetic

  12. Neutron Irradiation of Hydrided Cladding Material in HFIR Summary...

    Broader source: Energy.gov (indexed) [DOE]

    Nuclear Fuel Vibration Integrity Investigations Model for Simulation of Hydride Precipitation in Zr-Based Used Fuel Claddings: A Status Report on Current Model Capabilities...

  13. LANL/PNNL Virtual Center for Chemical Hydrides and New Concepts...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    LANLPNNL Virtual Center for Chemical Hydrides and New Concepts for Hydrogen Storage LANLPNNL Virtual Center for Chemical Hydrides and New Concepts for Hydrogen Storage...

  14. Convex Optimization Course Welcome Pack

    E-Print Network [OSTI]

    Hall, Julian

    1 NATCOR Convex Optimization Course 23rd ­ 27th June 2014 Welcome Pack This pack contains. ABSTRACT Convex optimization is the fundamental process of optimal decision-making. Although mathematically restrictive, many practical problems may be modelled directly as convex optimization problems. Convex

  15. Undergraduate Offer Pack 2015 2016

    E-Print Network [OSTI]

    Undergraduate Offer Pack 2015 ­ 2016 #12;#12;Graduate Offer Pack 2015-2016 5 Welcome from the Dean of Undergraduate Studies 5 What you need to do now 6-11 Your Checklist 7 Types of Offer 9 Accepting your Offer 9 Meeting the conditions of your Offer 10 Deferring your Offer 11 Rejecting an Offer 11 Financial

  16. Metal Hydride Thermal Storage: Reversible Metal Hydride Thermal Storage for High-Temperature Power Generation Systems

    SciTech Connect (OSTI)

    2011-12-05

    HEATS Project: PNNL is developing a thermal energy storage system based on a Reversible Metal Hydride Thermochemical (RMHT) system, which uses metal hydride as a heat storage material. Heat storage materials are critical to the energy storage process. In solar thermal storage systems, heat can be stored in these materials during the day and released at night—when the sun is not out—to drive a turbine and produce electricity. In nuclear storage systems, heat can be stored in these materials at night and released to produce electricity during daytime peak-demand hours. PNNL’s metal hydride material can reversibly store heat as hydrogen cycles in and out of the material. In a RHMT system, metal hydrides remain stable in high temperatures (600- 800°C). A high-temperature tank in PNNL’s storage system releases heat as hydrogen is absorbed, and a low-temperature tank stores the heat until it is needed. The low-cost material and simplicity of PNNL’s thermal energy storage system is expected to keep costs down. The system has the potential to significantly increase energy density.

  17. Method of making crack-free zirconium hydride

    DOE Patents [OSTI]

    Sullivan, Richard W. (Denver, CO)

    1980-01-01

    Crack-free hydrides of zirconium and zirconium-uranium alloys are produced by alloying the zirconium or zirconium-uranium alloy with beryllium, or nickel, or beryllium and scandium, or nickel and scandium, or beryllium and nickel, or beryllium, nickel and scandium and thereafter hydriding.

  18. Metal Hydrides for High-Temperature Power Generation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ronnebro, Ewa; Whyatt, Greg A.; Powell, Michael R.; Westman, Matthew P.; Zheng, Feng; Fang, Zhigang Zak

    2015-08-10

    Metal hydrides can be utilized for hydrogen storage and for thermal energy storage (TES) applications. By using TES with solar technologies, heat can be stored from sun energy to be used later which enables continuous power generation. We are developing a TES technology based on a dual-bed metal hydride system, which has a high-temperature (HT) metal hydride operating reversibly at 600-800°C to generate heat as well as a low-temperature (LT) hydride near room temperature that is used for hydrogen storage during sun hours until there is a need to produce electricity, such as during night time, a cloudy day, ormore »during peak hours. We proceeded from selecting a high-energy density, low-cost HT-hydride based on performance characterization on gram size samples, to scale-up to kilogram quantities and design, fabrication and testing of a 1.5kWh, 200kWh/m3 bench-scale TES prototype based on a HT-bed of titanium hydride and a hydrogen gas storage instead of a LT-hydride. COMSOL Multiphysics was used to make performance predictions for cylindrical hydride beds with varying diameters and thermal conductivities. Based on experimental and modeling results, a bench-scale prototype was designed and fabricated and we successfully showed feasibility to meet or exceed all performance targets.« less

  19. Valve stem and packing assembly

    DOE Patents [OSTI]

    Wordin, J.J.

    1991-09-03

    A valve stem and packing assembly is provided in which a rotatable valve stem includes a first tractrix surface for sliding contact with a stem packing and also includes a second tractrix surface for sliding contact with a bonnet. Force is applied by means of a spring, gland flange, and gland on the stem packing so the stem packing seals to the valve stem and bonnet. This configuration serves to create and maintain a reliable seal between the stem packing and the valve stem. The bonnet includes a second complementary tractrix surface for contacting the second sliding tractrix surface, the combination serving as a journal bearing for the entire valve stem and packing assembly. The journal bearing so configured is known as a Schiele's pivot. The Schiele's pivot also serves to maintain proper alignment of the valve stem with respect to the bonnet. Vertical wear between the surfaces of the Schiele's pivot is uniform at all points of contact between the second sliding tractrix surface and the second complementary tractrix surface of a bonnet. The valve stem is connected to a valve plug by means of a slip joint. The valve is opened and closed by rotating the valve stem. The slip joint compensates for wear on the Schiele's pivot and on the valve plug. A ledge is provided on the valve bonnet for the retaining nut to bear against. The ledge prevents over tightening of the retaining nut and the resulting excessive friction between stem and stem packing. 2 figures.

  20. Valve stem and packing assembly

    DOE Patents [OSTI]

    Wordin, John J. (Bingham County, ID)

    1991-01-01

    A valve stem and packing assembly is provided in which a rotatable valve stem includes a first tractrix surface for sliding contact with a stem packing and also includes a second tractrix surface for sliding contact with a bonnet. Force is applied by means of a spring, gland flange, and gland on the stem packing so the stem packing seals to the valve stem and bonnet. This configuration serves to create and maintain a reliable seal between the stem packing and the valve stem. The bonnet includes a second complementary tractrix surface for contacting the second sliding tractrix surface, the combination serving as a journal bearing for the entire valve stem and packing assembly. The journal bearing so configured is known as a Schiele's pivot. The Schiele's pivot also serves to maintain proper alignment of the valve stem with respect to the bonnet. Vertical wear between the surfaces of the Schiele's pivot is uniform at all points of contact between the second sliding tractrix surface and the second complementary tractrix surface of a bonnet. The valve stem is connected to a valve plug by means of a slip joint. The valve is opened and closed by rotating the valve stem. The slip joint compensates for wear on the Schiele's pivot and on the valve plug. A ledge is provided on the valve bonnet for the retaining nut to bear against. The ledge prevents overtightening of the retaining nut and the resulting excessive friction between stem and stem packing.

  1. test problem for packing_sumit

    E-Print Network [OSTI]

    chenwang

    2006-07-21

    Test problems of circles in circle packing with constraints and known ... test problems for circles packing problem with the optimal solutions known. That is ...

  2. Porous metal hydride composite and preparation and uses thereof

    DOE Patents [OSTI]

    Steyert, William A. (Los Alamos, NM); Olsen, Clayton E. (Los Alamos, NM)

    1982-01-01

    A composite formed from large pieces of aggregate formed from (1) metal hydride (or hydride-former) powder and (2) either metal powder or plastic powder or both is prepared. The composite has large macroscopic interconnected pores (much larger than the sizes of the powders which are used) and will have a very fast heat transfer rate and low windage loss. It will be useful, for example, in heat engines, hydrogen storage devices, and refrigerator components which depend for their utility upon both a fast rate of hydriding and dehydriding. Additionally, a method of preparing the composite and a method of increasing the rates of hydriding and dehydriding of metal hydrides are also given.

  3. Porous metal hydride composite and preparation and uses thereof

    DOE Patents [OSTI]

    Steyert, W.A.; Olsen, C.E.

    1980-03-12

    A composite formed from large pieces of aggregate formed from (1) metal hydride (or hydride-former) powder and (2) either metal powder or plastic powder or both is prepared. The composite has large macroscopic interconnected pores (much larger than the sizes of the powders which are used) and will have a very fast heat transfer rate and low windage loss. It will be useful, for example, in heat engines, hydrogen storage devices, and refrigerator components which depend for their utility upon both a fast rate of hydriding and dehydriding. Additionally, a method of preparing the composite and a method of increasing the rates of hydriding and dehydriding of metal hydrides are also given.

  4. Recent advances in metal hydrides for clean energy applications

    SciTech Connect (OSTI)

    Ronnebro, Ewa; Majzoub, Eric H.

    2013-06-01

    Metal hydrides are a fascinating class of materials that can be utilized for a surprising variety of clean energy applications, including smart solar collectors, smart windows, sensors, thermal energy storage, and batteries, in addition to their traditional application for hydrogen storage. Over the past decade, research on metal hydrides for hydrogen storage increased due to global governmental incentives and an increased focus on hydrogen storage research for polymer electrolyte membrane fuel cell operation. Tremendous progress has been made in so-called complex metal hydrides for hydrogen storage applications with the discovery of many new hydrides containing covalently bound complex anions. Many of these materials have applications beyond hydrogen storage and are being investigated for lithium-ion battery separator and anode materials. In this issue of MRS Bulletin , we present the state of the art of key evolving metal-hydride-based clean energy technologies with an outlook toward future needs.

  5. Method for packing chromatographic beds

    DOE Patents [OSTI]

    Freeman, David H. (Potomac, MD); Angeles, Rosalie M. (Germantown, MD); Keller, Suzanne (Rockville, MD)

    1991-01-01

    Column chromatography beds are packed through the application of static force. A slurry of the chromatography bed material and a non-viscous liquid is filled into the column plugged at one end, and allowed to settle. The column is transferred to a centrifuge, and centrifuged for a brief period of time to achieve a predetermined packing level, at a range generally of 100-5,000 gravities. Thereafter, the plug is removed, other fixtures may be secured, and the liquid is allowed to flow out through the bed. This results in an evenly packed bed, with no channeling or preferential flow characteristics.

  6. Highly Concentrated Palladium Hydrides/Deuterides; Theory

    SciTech Connect (OSTI)

    Papaconstantopoulos, Dimitrios

    2013-11-26

    Accomplishments are reported in these areas: tight-binding molecular dynamics study of palladium; First-principles calculations and tight-binding molecular dynamics simulations of the palladium-hydrogen system; tight-binding studies of bulk properties and hydrogen vacancies in KBH{sub 4}; tight-binding study of boron structures; development of angular dependent potentials for Pd-H; and density functional and tight-binding calculations for the light-hydrides NaAlH4 and NaBH4

  7. Metal hydride fuel storage and method thereof

    DOE Patents [OSTI]

    Morse, Jeffrey D. (Martinez, CA); Jankowski, Alan F. (Livermore, CA); Yu, Conrad (Antioch, CA)

    2010-08-10

    An apparatus having a first substrate having (1) a cavity, (2) one or more resistive heaters, and (3) one or more coatings forming a diffusion barrier to hydrogen; a second substrate having (1) an outlet valve comprising a pressure relief structure and (2) one or more coatings forming a diffusion barrier to hydrogen, wherein said second substrate is coupled to said first substrate forming a sealed volume in said cavity; a metal hydride material contained within said cavity; and a gas distribution system formed by coupling a microfluidic interconnect to said pressure relief structure. Additional apparatuses and methods are also disclosed.

  8. Results of NDE Technique Evaluation of Clad Hydrides

    SciTech Connect (OSTI)

    Dennis C. Kunerth

    2014-09-01

    This report fulfills the M4 milestone, M4FT-14IN0805023, Results of NDE Technique Evaluation of Clad Hydrides, under Work Package Number FT-14IN080502. During service, zirconium alloy fuel cladding will degrade via corrosion/oxidation. Hydrogen, a byproduct of the oxidation process, will be absorbed into the cladding and eventually form hydrides due to low hydrogen solubility limits. The hydride phase is detrimental to the mechanical properties of the cladding and therefore it is important to be able to detect and characterize the presence of this constituent within the cladding. Presently, hydrides are evaluated using destructive examination. If nondestructive evaluation techniques can be used to detect and characterize the hydrides, the potential exists to significantly increase test sample coverage while reducing evaluation time and cost. To demonstrate the viability this approach, an initial evaluation of eddy current and ultrasonic techniques were performed to demonstrate the basic ability to these techniques to detect hydrides or their effects on the microstructure. Conventional continuous wave eddy current techniques were applied to zirconium based cladding test samples thermally processed with hydrogen gas to promote the absorption of hydrogen and subsequent formation of hydrides. The results of the evaluation demonstrate that eddy current inspection approaches have the potential to detect both the physical damage induced by hydrides, e.g. blisters and cracking, as well as the combined effects of absorbed hydrogen and hydride precipitates on the electrical properties of the zirconium alloy. Similarly, measurements of ultrasonic wave velocities indicate changes in the elastic properties resulting from the combined effects of absorbed hydrogen and hydride precipitates as well as changes in geometry in regions of severe degradation. However, for both approaches, the signal responses intended to make the desired measurement incorporate a number of contributing parameters. These contributing factors need to be recognized and a means to control them or separate their contributions will be required to obtain the desired information.

  9. Ball Packings with Periodic Constraints

    E-Print Network [OSTI]

    Robert Connelly; Jeffrey D. Shen; Alexander D. Smith

    2013-01-04

    We call a periodic ball packing in d-dimensional Euclidean space periodically (strictly) jammed with respect to a period lattice if there are no nontrivial motions of the balls that preserve the period (that maintain some period with smaller or equal volume). In particular, we call a packing consistently periodically (strictly) jammed if it is periodically (strictly) jammed on every one of its periods. After extending a well-known bar framework and stress condition to strict jamming, we prove that a packing with period Lambda is consistently strictly jammed if and only if it is strictly jammed with respect to Lambda and consistently periodically jammed. We next extend a result about rigid unit mode spectra in crystallography to characterize periodic jamming on sublattices. After that, we prove that there are finitely many strictly jammed packings of m unit balls and other similar results. An interesting example shows that the size of the first sublattice on which a packing is first periodically unjammed is not bounded. Finally, we find an example of a consistently periodically jammed packing of low density \\delta = \\frac{4 \\pi}{6 \\sqrt{3} + 11} + \\epsilon ~ 0.59, where \\epsilon is an arbitrarily small positive number. Throughout the paper, the statements for the closely related notions of periodic infinitesimal rigidity and affine infinitesimal rigidity for tensegrity frameworks are also given.

  10. Experimental Validation of Voltage-Based State-of-Charge Algorithm for Power Batteries

    E-Print Network [OSTI]

    Jia, Zhuo

    2013-01-01

    for nickel metal hydride batteries including hysteresis” ,Control of Lithium-Ion Batteries”, Control Systems, IEEE,modeling of lead acid batteries”, Applied Power Electronics

  11. Recycling Programs | Department of Energy

    Energy Savers [EERE]

    Germantown Paperclips Supply Stores. Batteries accepted for recycling are: Alkaline, Lithium Ion, Nickel Cadmium (Ni-Cd), Nickel-Iron, and Nickel Metal Hydride (NiMH). Toner...

  12. Carbon-Fluorine Bond Cleavage by Zirconium Metal Hydride Complexes

    E-Print Network [OSTI]

    Jones, William D.

    Carbon-Fluorine Bond Cleavage by Zirconium Metal Hydride Complexes Brian L. Edelbach, A. K. Fazlur, Rochester, New York 14627 Received April 8, 1999 The zirconium hydride dimer [Cp2ZrH2]2 reacts with C6F6. [Cp2ZrH2]2 reacts with C6F5H to give Cp2Zr(p-C6F4H)F, Cp2ZrF2, C6F4H2, and H2. The zirconium hydride

  13. Chemical Hydride Slurry for Hydrogen Production and Storage

    SciTech Connect (OSTI)

    McClaine, Andrew W.

    2008-09-30

    The purpose of this project was to investigate and evaluate the attractiveness of using a magnesium chemical hydride slurry as a hydrogen storage, delivery, and production medium for automobiles. To fully evaluate the potential for magnesium hydride slurry to act as a carrier of hydrogen, potential slurry compositions, potential hydrogen release techniques, and the processes (and their costs) that will be used to recycle the byproducts back to a high hydrogen content slurry were evaluated. A 75% MgH2 slurry was demonstrated, which was just short of the 76% goal. This slurry is pumpable and storable for months at a time at room temperature and pressure conditions and it has the consistency of paint. Two techniques were demonstrated for reacting the slurry with water to release hydrogen. The first technique was a continuous mixing process that was tested for several hours at a time and demonstrated operation without external heat addition. Further work will be required to reduce this design to a reliable, robust system. The second technique was a semi-continuous process. It was demonstrated on a 2 kWh scale. This system operated continuously and reliably for hours at a time, including starts and stops. This process could be readily reduced to practice for commercial applications. The processes and costs associated with recycling the byproducts of the water/slurry reaction were also evaluated. This included recovering and recycling the oils of the slurry, reforming the magnesium hydroxide and magnesium oxide byproduct to magnesium metal, hydriding the magnesium metal with hydrogen to form magnesium hydride, and preparing the slurry. We found that the SOM process, under development by Boston University, offers the lowest cost alternative for producing and recycling the slurry. Using the H2A framework, a total cost of production, delivery, and distribution of $4.50/kg of hydrogen delivered or $4.50/gge was determined. Experiments performed at Boston University have demonstrated the technical viability of the process and have provided data for the cost analyses that have been performed. We also concluded that a carbothermic process could also produce magnesium at acceptable costs. The use of slurry as a medium to carry chemical hydrides has been shown during this project to offer significant advantages for storing, delivering, and distributing hydrogen: • Magnesium hydride slurry is stable for months and pumpable. • The oils of the slurry minimize the contact of oxygen and moisture in the air with the metal hydride in the slurry. Thus reactive chemicals, such as lithium hydride, can be handled safely in the air when encased in the oils of the slurry. • Though magnesium hydride offers an additional safety feature of not reacting readily with water at room temperatures, it does react readily with water at temperatures above the boiling point of water. Thus when hydrogen is needed, the slurry and water are heated until the reaction begins, then the reaction energy provides heat for more slurry and water to be heated. • The reaction system can be relatively small and light and the slurry can be stored in conventional liquid fuel tanks. When transported and stored, the conventional liquid fuel infrastructure can be used. • The particular metal hydride of interest in this project, magnesium hydride, forms benign byproducts, magnesium hydroxide (“Milk of Magnesia”) and magnesium oxide. • We have estimated that a magnesium hydride slurry system (including the mixer device and tanks) could meet the DOE 2010 energy density goals. ? During the investigation of hydriding techniques, we learned that magnesium hydride in a slurry can also be cycled in a rechargeable fashion. Thus, magnesium hydride slurry can act either as a chemical hydride storage medium or as a rechargeable hydride storage system. Hydrogen can be stored and delivered and then stored again thus significantly reducing the cost of storing and delivering hydrogen. Further evaluation and development of this concept will be performed as follow-on work under a

  14. The Hydriding Kinetics of Organic Hydrogen Getters

    SciTech Connect (OSTI)

    Powell, G. L.

    2002-02-11

    The aging of hermetically sealed systems is often accompanied by the gradual production of hydrogen gas that is a result of the decay of environmental gases and the degradation of organic materials. In particular, the oxygen, water, hydrogen ''equilibrium'' is affected by the removal of oxygen due the oxidation of metals and organic materials. This shift of the above ''equilibrium'' towards the formation of hydrogen gas, particularly in crevices, may eventually reach an explosive level of hydrogen gas or degrade metals by hydriding them. The latter process is generally delayed until the oxidizing species are significantly reduced. Organic hydrogen getters introduced by Allied Signal Aerospace Company, Kansas City Division have proven to be a very effective means of preventing hydrogen gas accumulation in sealed containers. These getters are relatively unaffected by air and environmental gases. They can be packaged in a variety of ways to fit particular needs such as porous pellets, fine or coarse [gravel] powder, or loaded into silicone rubber. The hydrogen gettering reactions are extremely irreversible since the hydrogen gas is converted into an organic hydrocarbon. These getters are based on the palladium-catalyzed hydrogenation of triple bonds to double and then single bonds in aromatic aryl compounds. DEB (1,4 bis (phenyl ethynyl) benzene) typically mixed with 25% by weight carbon with palladium (1% by weight of carbon) is one of the newest and best of these organic hydrogen getters. The reaction mechanisms are complex involving solid state reaction with a heterogeneous catalyst leading to the many intermediates, including mixed alkyl and aryl hydrocarbons with the possibilities of many isomers. The reaction kinetics mechanisms are also strongly influenced by the form in which they are packaged. For example, the hydriding rates for pellets and gravel have a strong dependence on reaction extent (i.e., DEB reduction) and a kinetic order in pressure of 0.76. Silicone rubber based DEB getters hydride at a much lower rate, have little dependence on reaction extent, have a higher kinetic order in pressure (0.87), and have a lower activation energy. The kinetics of the reaction as a function of hydrogen pressure, stoichiometry, and temperature for hydrogen and deuterium near ambient temperature (0 to 75 C) for pressures near or below 100 Pa over a wide range (in some cases, the complete) hydrogenation range are presented along with multi-dimensional rate models.

  15. A new phase in palladium hydride technology

    SciTech Connect (OSTI)

    Walters, R.T.

    1991-01-01

    Two plateaux are observed in both the absorption and desorption isotherms of palladium hydride. For the absorption isotherm, a change in plateau pressure is observed at a hydrogen-to-metal (H/M) ratio of about 0.35 for all temperatures studied. For the desorption isotherm, the change in plateau pressure appears to be a function of temperature, ranging from an H/M ratio of 0.18 at 80{degrees}C to 0.3 at 140{degrees}C. These data are interpreted as being experimentally observed boundaries to an equilibrium phase line located in the miscibility gap of the palladium/hydrogen phase diagram. This new phase does not appear to be a stoichiometric compounds, but rather its composition seems to vary with temperature. 6 refs., 4 figs.

  16. A new phase in palladium hydride technology

    SciTech Connect (OSTI)

    Walters, R.T.

    1991-12-31

    Two plateaux are observed in both the absorption and desorption isotherms of palladium hydride. For the absorption isotherm, a change in plateau pressure is observed at a hydrogen-to-metal (H/M) ratio of about 0.35 for all temperatures studied. For the desorption isotherm, the change in plateau pressure appears to be a function of temperature, ranging from an H/M ratio of 0.18 at 80{degrees}C to 0.3 at 140{degrees}C. These data are interpreted as being experimentally observed boundaries to an equilibrium phase line located in the miscibility gap of the palladium/hydrogen phase diagram. This new phase does not appear to be a stoichiometric compounds, but rather its composition seems to vary with temperature. 6 refs., 4 figs.

  17. Ni/metal hydride secondary element

    DOE Patents [OSTI]

    Bauerlein, Peter

    2005-04-19

    A Ni/metal hydride secondary element having a positive nickel hydroxide electrode, a negative electrode having a hydrogen storage alloy, and an alkaline electrolyte, the positive electrode, provided with a three-dimensional metallic conductive structure, also contains an aluminum compound which is soluble in the electrolyte, in addition to nickel hydroxide and cobalt oxide. The aluminum compound is aluminum hydroxide and/or aluminum oxide, and the mass of the aluminum compound which is present in the positive bulk material mixture is 0.1 to 2% by weight relative to the mass of the nickel hydroxide which is present. In combination with aluminum hydroxide or aluminum oxide, the positive electrode further contains lanthanoid oxidic compounds Y.sub.2 O.sub.3, La.sub.2 O.sub.3 and Ca(OH).sub.2, as well as mixtures of these compounds.

  18. Process for production of a metal hydride

    DOE Patents [OSTI]

    Allen, Nathan Tait; Butterick, III, Robert; Chin, Arthur Achhing; Millar, Dean Michael; Molzahn, David Craig

    2014-08-12

    A process for production of a metal hydride compound MH.sub.x, wherein x is one or two and M is an alkali metal, Be or Mg. The process comprises combining a compound of formula (R.sup.1O).sub.xM with aluminum, hydrogen and at least one metal selected from among titanium, zirconium, hafnium, niobium, vanadium, tantalum and iron to produce a compound of formula MH.sub.x. R.sup.1 is phenyl or phenyl substituted by at least one alkyl or alkoxy group. A mole ratio of aluminum to (R.sup.1O).sub.xM is from 0.1:1 to 1:1. The catalyst is present at a level of at least 200 ppm based on weight of aluminum.

  19. Hydrogen storage in sodium aluminum hydride.

    SciTech Connect (OSTI)

    Ozolins, Vidvuds; Herberg, J.L.; McCarty, Kevin F.; Maxwell, Robert S.; Stumpf, Roland Rudolph; Majzoub, Eric H.

    2005-11-01

    Sodium aluminum hydride, NaAlH{sub 4}, has been studied for use as a hydrogen storage material. The effect of Ti, as a few mol. % dopant in the system to increase kinetics of hydrogen sorption, is studied with respect to changes in lattice structure of the crystal. No Ti substitution is found in the crystal lattice. Electronic structure calculations indicate that the NaAlH{sub 4} and Na{sub 3}AlH{sub 6} structures are complex-ionic hydrides with Na{sup +} cations and AlH{sub 4}{sup -} and AlH{sub 6}{sup 3-} anions, respectively. Compound formation studies indicate the primary Ti-compound formed when doping the material at 33 at. % is TiAl{sub 3} , and likely Ti-Al compounds at lower doping rates. A general study of sorption kinetics of NaAlH{sub 4}, when doped with a variety of Ti-halide compounds, indicates a uniform response with the kinetics similar for all dopants. NMR multiple quantum studies of solution-doped samples indicate solvent interaction with the doped alanate. Raman spectroscopy was used to study the lattice dynamics of NaAlH{sub 4}, and illustrated the molecular ionic nature of the lattice as a separation of vibrational modes between the AlH{sub 4}{sup -} anion-modes and lattice-modes. In-situ Raman measurements indicate a stable AlH{sub 4}{sup -} anion that is stable at the melting temperature of NaAlH{sub 4}, indicating that Ti-dopants must affect the Al-H bond strength.

  20. High capacity stabilized complex hydrides for hydrogen storage

    DOE Patents [OSTI]

    Zidan, Ragaiy; Mohtadi, Rana F; Fewox, Christopher; Sivasubramanian, Premkumar

    2014-11-11

    Complex hydrides based on Al(BH.sub.4).sub.3 are stabilized by the presence of one or more additional metal elements or organic adducts to provide high capacity hydrogen storage material.

  1. Effects of outgassing of loader chamber walls on hydriding of...

    Office of Scientific and Technical Information (OSTI)

    gas pressure. Complete process data for (1) a copper-(1.83 wt. %)beryllium wet hydrogen fired passivated (600 C-1 h) externally heated pipe hydriding chamber are reported....

  2. Cylinder valve packing nut studies

    SciTech Connect (OSTI)

    Blue, S.C. [Martin Marietta Energy Systems, Inc., Paducah, KY (United States)

    1991-12-31

    The design, manufacture, and use of cylinder valve packing nuts have been studied to improve their resistance to failure from stress corrosion cracking. Stress frozen photoelastic models have been analyzed to measure the stress concentrations at observed points of failure. The load effects induced by assembly torque and thermal expansion of stem packing were observed by strain gaging nuts. The effects of finishing operations and heat treatment were studied by the strain gage hole boring and X-ray methods. Modifications of manufacturing and operation practices are reducing the frequency of stress corrosion failures.

  3. Optimization of Hydride Rim Formation in Unirradiated Zr 4 Cladding

    SciTech Connect (OSTI)

    Shimskey, Rick W.; Hanson, Brady D.; MacFarlan, Paul J.

    2013-09-30

    The purpose of this work is to build on the results reported in the M2 milestone M2FT 13PN0805051, document number FCRD-USED-2013-000151 (Hanson, 2013). In that work, it was demonstrated that unirradiated samples of zircaloy-4 cladding could be pre-hydrided at temperatures below 400°C in pure hydrogen gas and that the growth of hydrides on the surface could be controlled by changing the surface condition of the samples and form a desired hydride rim on the outside diameter of the cladding. The work performed at Pacific Northwest National Laboratory since the issuing of the M2 milestone has focused its efforts to optimize the formation of a hydride rim on available zircaloy-4 cladding samples by controlling temperature variation and gas flow control during pre-hydriding treatments. Surface conditioning of the outside surface was also examined as a variable. The results of test indicate that much of the variability in the hydride thickness is due to temperature variation occurring in the furnaces as well as how hydrogen gas flows across the sample surface. Efforts to examine other alloys, gas concentrations, and different surface conditioning plan to be pursed in the next FY as more cladding samples become available

  4. Microfabricated packed gas chromatographic column

    DOE Patents [OSTI]

    Kottenstette, Richard; Matzke, Carolyn M.; Frye-Mason, Gregory C.

    2003-12-16

    A new class of miniaturized gas chromatographic columns has been invented. These chromatographic columns are formed using conventional micromachining techniques, and allow packed columns having lengths on the order of a meter to be fabricated with a footprint on the order of a square centimeter.

  5. Investigation of Cracked Lithium Hydride Reactor Vessels

    SciTech Connect (OSTI)

    bird, e.l.; mustaleski, t.m.

    1999-06-01

    Visual examination of lithium hydride reactor vessels revealed cracks that were adjacent to welds, most of which were circumferentially located in the bottom portion of the vessels. Sections were cut from the vessels containing these cracks and examined by use of the metallograph, scanning electron microscope, and microprobe to determine the cause of cracking. Most of the cracks originated on the outer surface just outside the weld fusion line in the base material and propagated along grain boundaries. Crack depths of those examined sections ranged from {approximately}300 to 500 {micro}m. Other cracks were reported to have reached a maximum depth of 1/8 in. The primary cause of cracking was the creation of high tensile stresses associated with the differences in the coefficients of thermal expansion between the filler metal and the base metal during operation of the vessel in a thermally cyclic environment. This failure mechanism could be described as creep-type fatigue, whereby crack propagation may have been aided by the presence of brittle chromium carbides along the grain boundaries, which indicates a slightly sensitized microstructure.

  6. Synthesis and small molecule chemistry of the niobaziridine-hydride functional group

    E-Print Network [OSTI]

    Figueroa, Joshua S

    2005-01-01

    Chapter 1. Synthesis and Divergent Reactivity of the Niobaziridine-Hydride Functional Group The synthesis, characterization and reactivity of the niobaziridine-hydride complex Nb(H)([eta]²-t- ]Bu(H)C=NAr)(N[Np]Ar)? (la-H; ...

  7. Analytical assessment of the thermal behavior of nickelemetal hydride batteries during fast charging

    E-Print Network [OSTI]

    Bahrami, Majid

    Analytical assessment of the thermal behavior of nickelemetal hydride batteries during fast (LAEC), Mechatronic Systems Engineering, School of Engineering Science, Simon Fraser University, Surrey charging of batteries Charging efficiency Integral-transformation technique Nickelemetal hydride battery

  8. Thermochemistry and Kinetics of Silicon Hydride Cluster Formation during Thermal Decomposition of Silane

    E-Print Network [OSTI]

    Swihart, Mark T.

    Thermochemistry and Kinetics of Silicon Hydride Cluster Formation during Thermal Decomposition of Silane Mark T. Swihart*, and Steven L. Girshick Department of Mechanical Engineering, Uni an extensive chemical kinetic mechanism for silicon hydride cluster formation during silane pyrolysis

  9. Adhesive Loose Packings of Small Particles

    E-Print Network [OSTI]

    Wenwei Liu; Shuiqing Li; Adrian Baule; Hernán A. Makse

    2014-10-08

    We explore adhesive loose packings of dry small spherical particles of micrometer size using 3D discrete-element simulations with adhesive contact mechanics. A dimensionless adhesion parameter ($Ad$) successfully combines the effects of particle velocities, sizes and the work of adhesion, identifying a universal regime of adhesive packings for $Ad>1$. The structural properties of the packings in this regime are well described by an ensemble approach based on a coarse-grained volume function that includes correlations between bulk and contact spheres. Our theoretical and numerical results predict: (i) An equation of state for adhesive loose packings that appears as a continuation from the frictionless random close packing (RCP) point in the jamming phase diagram; (ii) The existence of a maximal loose packing point at the coordination number $Z=2$ and packing fraction $\\phi=1/2^{3}$. Our results highlight that adhesion leads to a universal packing regime at packing fractions much smaller than the random loose packing, which can be described within a statistical mechanical framework. We present a general phase diagram of jammed matter comprising frictionless, frictional, adhesive as well as non-spherical particles, providing a classification of packings in terms of their continuation from the spherical frictionless RCP.

  10. Structural properties and enthalpy of formation of magnesium hydride from quantum Monte Carlo calculations

    E-Print Network [OSTI]

    Alfè, Dario

    Structural properties and enthalpy of formation of magnesium hydride from quantum Monte Carlo calculations to study the structural properties of magnesium hydride MgH2 , including the pressure. INTRODUCTION The energetics of metal hydrides has recently become an issue of large scientific

  11. Enhancement of heat and mass transfer in metal hydride beds with the addition of Al plates

    E-Print Network [OSTI]

    Guo, Zhixiong "James"

    in the hydriding process with the addition of internal aluminum plates. The two-dimensional equations governing during the absorption/desorption process in the metal hydride beds. The main factors governing the metal hydride matrix and kinetics of the hydrogen sorption processes, etc. By ne- glecting the hydrogen

  12. Composite Materials for Hazard Mitigation of Reactive Metal Hydrides.

    SciTech Connect (OSTI)

    Pratt, Joseph William; Cordaro, Joseph Gabriel; Sartor, George B.; Dedrick, Daniel E.; Reeder, Craig L.

    2012-02-01

    In an attempt to mitigate the hazards associated with storing large quantities of reactive metal hydrides, polymer composite materials were synthesized and tested under simulated usage and accident conditions. The composites were made by polymerizing vinyl monomers using free-radical polymerization chemistry, in the presence of the metal hydride. Composites with vinyl-containing siloxane oligomers were also polymerized with and without added styrene and divinyl benzene. Hydrogen capacity measurements revealed that addition of the polymer to the metal hydride reduced the inherent hydrogen storage capacity of the material. The composites were found to be initially effective at reducing the amount of heat released during oxidation. However, upon cycling the composites, the mitigating behavior was lost. While the polymer composites we investigated have mitigating potential and are physically robust, they undergo a chemical change upon cycling that makes them subsequently ineffective at mitigating heat release upon oxidation of the metal hydride. Acknowledgements The authors would like to thank the following people who participated in this project: Ned Stetson (U.S. Department of Energy) for sponsorship and support of the project. Ken Stewart (Sandia) for building the flow-through calorimeter and cycling test stations. Isidro Ruvalcaba, Jr. (Sandia) for qualitative experiments on the interaction of sodium alanate with water. Terry Johnson (Sandia) for sharing his expertise and knowledge of metal hydrides, and sodium alanate in particular. Marcina Moreno (Sandia) for programmatic assistance. John Khalil (United Technologies Research Corp) for insight into the hazards of reactive metal hydrides and real-world accident scenario experiments. Summary In an attempt to mitigate and/or manage hazards associated with storing bulk quantities of reactive metal hydrides, polymer composite materials (a mixture of a mitigating polymer and a metal hydride) were synthesized and tested under simulated usage and accident conditions. Mitigating the hazards associated with reactive metal hydrides during an accident while finding a way to keep the original capability of the active material intact during normal use has been the focus of this work. These composites were made by polymerizing vinyl monomers using free-radical polymerization chemistry, in the presence of the metal hydride, in this case a prepared sodium alanate (chosen as a representative reactive metal hydride). It was found that the polymerization of styrene and divinyl benzene could be initiated using AIBN in toluene at 70 degC. The resulting composite materials can be either hard or brittle solids depending on the cross-linking density. Thermal decomposition of these styrene-based composite materials is lower than neat polystyrene indicating that the chemical nature of the polymer is affected by the formation of the composite. The char-forming nature of cross-linked polystyrene is low and therefore, not an ideal polymer for hazard mitigation. To obtain composite materials containing a polymer with higher char-forming potential, siloxane-based monomers were investigated. Four vinyl-containing siloxane oligomers were polymerized with and without added styrene and divinyl benzene. Like the styrene materials, these composite materials exhibited thermal decomposition behavior significantly different than the neat polymers. Specifically, the thermal decomposition temperature was shifted approximately 100 degC lower than the neat polymer signifying a major chemical change to the polymer network. Thermal analysis of the cycled samples was performed on the siloxane-based composite materials. It was found that after 30 cycles the siloxane-containing polymer composite material has similar TGA/DSC-MS traces as the virgin composite material indicating that the polymer is physically intact upon cycling. Hydrogen capacity measurements revealed that addition of the polymer to the metal hydride in the form of a composite material reduced the inherent hydrogen storage capacity of the material. This

  13. Studies of isotopic exchange between gaseous hydrogen and palladium hydride powder

    SciTech Connect (OSTI)

    Foltz, G.W.; Melius, C.F.

    1987-12-01

    A gas flow apparatus has been constructed and used to study the isotopic exchange reaction occurring between the solid and gas phases in hydrogen (deuterium) gas flows directed through packed-powder beds of ..beta..-phase palladium deuteride (hydride). Spontaneous Raman light scattering is employed to obtain a real-time analysis of the isotopic composition of the gas (H/sub 2/, D/sub 2/, HD) exiting from the bed. A parametric rate-equation model is described which depicts the time-dependent behavior of the isotopic exchange process. The exchange mechanism is assumed to be rate-limited by processes occurring on the surface of the powder. The fundamental kinetic parameter of the model is the isotopic exchange probability, p, which is the probability that an isotopic exchange event occurs during a collision of a gas-phase atom with the surface. Isotope effects between the gas and solid phases are explicitly included in terms of the isotope separation factor, ..cap alpha... Results of the model are compared with the experimental measurements and, using a literature value of ..cap alpha.. = 2.4, good agreement is obtained for p approx. = 10/sup -7/. In view of the importance of the isotope effects in the hydrogen/palladium system and the range of a values reported for the ..beta..-phase in the literature, the sensitivity of the model results to a variation in the value of ..cap alpha.. is examined.

  14. Modeling of temporal behavior of isotopic exchange between gaseous hydrogen and palladium hydride power

    SciTech Connect (OSTI)

    Melius, C F; Foltz, G W

    1987-01-01

    A parametric rate-equation model is described which depicts the time dependent behavior of the isotopic exchange process occurring between the solid and gas phases in gaseous hydrogen (deuterium) flows through packed-powder palladium deuteride (hydride) beds. The exchange mechanism is assumed to be rate-limited by processes taking place on the surface of the powder. The fundamental kinetic parameter of the model is the isotopic exchange probability, p, which is the probability that an isotopic exchange event occurs during a collision of a gas phase atom with the surface. Isotope effects between the gas and solid phases are explicitly included in terms of the isotope separation factor, ..cap alpha... Results of the model are compared with recent experimental measurements of isotope exchange in the ..beta..-phase hydrogen/palladium system and, using a literature value of ..cap alpha.. = 2.4, a good description of the experimental data is obtained for p approx. 10/sup -7/. In view of the importance of the isotope effects in the hydrogen/palladium system and the range of ..cap alpha.. values reported for the ..beta..-phase in the literature, the sensitivity of the model results to a variation in the value of ..cap alpha.. is examined.

  15. The Packing of Granular Polymer Chains

    SciTech Connect (OSTI)

    Zou, Ling-Nan; Cheng, Xiang; Rivers, Mark L.; Jaeger, Heinrich M.; Nagel, Sidney R.; UC

    2009-12-01

    Rigid particles pack into structures, such as sand dunes on the beach, whose overall stability is determined by the average number of contacts between particles. However, when packing spatially extended objects with flexible shapes, additional concepts must be invoked to understand the stability of the resulting structure. Here, we examine the disordered packing of chains constructed out of flexibly connected hard spheres. Using x-ray tomography, we find that long chains pack into a low-density structure whose mechanical rigidity is mainly provided by the backbone. On compaction, randomly oriented, semi-rigid loops form along the chain, and the packing of chains can be understood as the jamming of these elements. Finally, we uncover close similarities between the packing of chains and the glass transition in polymers.

  16. Analysis of Heat Transfer in Metal Hydride Based Hydrogen Separation

    SciTech Connect (OSTI)

    Fleming, W.H. Jr.

    1999-10-20

    This thesis presents a transient heat transfer analysis to model the heat transfer in the Pd/k packed column, and the impact of adding metallic foam.

  17. New value packing technology extends service life

    SciTech Connect (OSTI)

    Miller, M.; Jackson, R. (Fisher Controls International, Inc., Marshalltown, IA (United States))

    1993-10-01

    New packing techniques can extend packing life and retain low stem leakage. The HPI can use these designs to avoid mandatory monitoring and repair schedules for valves that exceed the 500-ppm emission threshold. New EPA leakage limits will enforce monitoring and maintenance programs if more than 2% of the facility's valves exceed this limit. Because valves are dynamic, their control actions are prone to leakage. Also, the best fire-resistant packing material, graphite, has inherent deficiencies such as high compression stress and a high-friction coefficient that shortens its service life. Four basic principles overcome graphite packing's shortcomings for control valve applications. Examples show how these criteria improve sliding stem and rotary valve performance. Incorporating these principles into valve-packing designs can ensure long, low-maintenance service life, and the added benefit of low leakage. Graphite is a very important packing material for the HPI. Unlike fluoropolymer (e.g., PTFE) packing, graphite can tolerate high process temperature without decomposing or losing its sealing properties. More importantly, graphite packing is fire safe. It can survive a fire without a catastrophic failure that could add more flammable materials.

  18. How to Pack Microfossils By Skip Lyles

    E-Print Network [OSTI]

    Miller, Scott

    are the materials that we will be using to pack this roll of slides: raw bedding cotton 6" x 4" empty Kodak box materials that you're going to need are flexible corrugated cardboard and masking tape. Here we'll show you how to pack microfossils step-by-step using only these two materials. Step 1: Here are the materials

  19. Application pack for funding commencing in 2012

    E-Print Network [OSTI]

    Kheifets, Anatoli

    Application pack for funding commencing in 2012 GROUP OF EIGHT AUSTRALIA­GERMANY JOINT RESEARCH COOPERATION SCHEME #12;PAGE 2 OF 9GROUP OF EIGHT AUSTRALIA­GERMANY JOINT RESEARCH COOPERATION SCHEME © GROUP OF EIGHT Application pack for funding commencing in 2012 ABOUT THE GROUP OF EIGHT AUSTRALIA­GERMANY JOINT

  20. Graduate Offer Pack 2 University College Dublin

    E-Print Network [OSTI]

    Graduate Offer Pack 2015-2016 #12;2 University College Dublin #12;Graduate Offer Pack 2015-2016 3 Welcome from the Dean of Graduate Studies 5 What you need to do now 6-11 Your Checklist 7 Types of Offer 9 Accepting your Offer 9 Meeting the conditions of your Offer 10 Deferring your Offer 11 Rejecting an Offer 11

  1. Packing of elastic wires in flexible shells

    E-Print Network [OSTI]

    Vetter, Roman; Herrmann, Hans J

    2015-01-01

    The packing problem of long thin filaments that are injected into confined spaces is of fundamental interest for physicists, biologists and materials engineers alike. How linear threads pack and coil is well known only for the ideal case of rigid containers, however. Here, we force long elastic rods into flexible spatial confinement borne by an elastic shell to examine under which conditions recently acquired knowledge on wire packing in rigid spheres breaks down. We find that unlike in rigid cavities, friction plays a key role by giving rise to the emergence of two distinct packing patterns. At low friction, the wire densely coils into an ordered toroidal bundle with semi-ellipsoidal cross section, while at high friction, it packs into a highly disordered, self-similar structure. These two morphologies are shown to be separated by a continuous phase transition.

  2. Packing of elastic wires in flexible shells

    E-Print Network [OSTI]

    Roman Vetter; Falk K. Wittel; Hans J. Herrmann

    2015-04-03

    The packing problem of long thin filaments that are injected into confined spaces is of fundamental interest for physicists, biologists and materials engineers alike. How linear threads pack and coil is well known only for the ideal case of rigid containers, however. Here, we force long elastic rods into flexible spatial confinement borne by an elastic shell to examine under which conditions recently acquired knowledge on wire packing in rigid spheres breaks down. We find that unlike in rigid cavities, friction plays a key role by giving rise to the emergence of two distinct packing patterns. At low friction, the wire densely coils into an ordered toroidal bundle with semi-ellipsoidal cross section, while at high friction, it packs into a highly disordered, self-similar structure. These two morphologies are shown to be separated by a continuous phase transition.

  3. Coalescence preference in densely packed microbubbles

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kim, Yeseul; Lim, Su Jin; Gim, Bopil; Weon, Byung Mook

    2015-01-13

    A bubble merged from two parent bubbles with different size tends to be placed closer to the larger parent. This phenomenon is known as the coalescence preference. Here we demonstrate that the coalescence preference can be blocked inside a densely packed cluster of bubbles. We utilized high-speed high-resolution X-ray microscopy to clearly visualize individual coalescence events inside densely packed microbubbles with a local packing fraction of ~40%. Thus, the surface energy release theory predicts an exponent of 5 in a relation between the relative coalescence position and the parent size ratio, whereas our observation for coalescence in densely packed microbubblesmore »shows a different exponent of 2. We believe that this result would be important to understand the reality of coalescence dynamics in a variety of packing situations of soft matter.« less

  4. FEASIBILITY OF RECYCLING PLUTONIUM AND MINOR ACTINIDES IN LIGHT WATER REACTORS USING HYDRIDE FUEL

    SciTech Connect (OSTI)

    Greenspan, Ehud; Todreas, Neil; Taiwo, Temitope

    2009-03-10

    The objective of this DOE NERI program sponsored project was to assess the feasibility of improving the plutonium (Pu) and minor actinide (MA) recycling capabilities of pressurized water reactors (PWRs) by using hydride instead of oxide fuels. There are four general parts to this assessment: 1) Identifying promising hydride fuel assembly designs for recycling Pu and MAs in PWRs 2) Performing a comprehensive systems analysis that compares the fuel cycle characteristics of Pu and MA recycling in PWRs using the promising hydride fuel assembly designs identified in Part 1 versus using oxide fuel assembly designs 3) Conducting a safety analysis to assess the likelihood of licensing hydride fuel assembly designs 4) Assessing the compatibility of hydride fuel with cladding materials and water under typical PWR operating conditions Hydride fuel was found to offer promising transmutation characteristics and is recommended for further examination as a possible preferred option for recycling plutonium in PWRs.

  5. Thermomechanics of hydrogen storage in metallic hydrides: modeling and analysis

    E-Print Network [OSTI]

    Tomas Roubicek; Giuseppe Tomassetti

    2013-09-12

    A thermodynamically consistent mathematical model for hydrogen adsorption in metal hydrides is proposed. Beside hydrogen diffusion, the model accounts for phase transformation accompanied by hysteresis, swelling, temperature and heat transfer, strain, and stress. We prove existence of solutions of the ensuing system of partial differential equations by a carefully-designed, semi-implicit approximation scheme. A generalization for a drift-diffusion of multi-component ionized "gas" is outlined, too.

  6. EV Everywhere Batteries Workshop - Pack Design and Optimization...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Pack Design and Optimization Breakout Session Report EV Everywhere Batteries Workshop - Pack Design and Optimization Breakout Session Report Breakout session presentation for the...

  7. Packing TRU Waste Containers Design | Department of Energy

    Office of Environmental Management (EM)

    Packing TRU Waste Containers Design Packing TRU Waste Containers Design This document was used to determine facts and conditions during the Department of Energy Accident...

  8. Diffusional exchange of isotopes in a metal hydride sphere.

    SciTech Connect (OSTI)

    Wolfer, Wilhelm G.; Hamilton, John C.; James, Scott Carlton

    2011-04-01

    This report describes the Spherical Particle Exchange Model (SPEM), which simulates exchange of one hydrogen isotope by another hydrogen isotope in a spherical metal hydride particle. This is one of the fundamental physical processes during isotope exchange in a bed of spherical metal particles and is thus one of the key components in any comprehensive physics-based model of exchange. There are two important physical processes in the model. One is the entropy of mixing between the two isotopes; the entropy of mixing is increased by having both isotopes randomly placed at interstitial sites on the lattice and thus impedes the exchange process. The other physical process is the elastic interaction between isotope atoms on the lattice. The elastic interaction is the cause for {beta}-phase formation and is independent of the isotope species. In this report the coupled diffusion equations for two isotopes in the {beta}-phase hydride are solved. A key concept is that the diffusion of one isotope depends not only on its concentration gradient, but also on the concentration gradient of the other isotope. Diffusion rate constants and the chemical potentials for deuterium and hydrogen in the {beta}-phase hydride are reviewed because these quantities are essential for an accurate model of the diffusion process. Finally, a summary of some of the predictions from the SPEM model are provided.

  9. Measurement and modeling of strain fields in zirconium hydrides precipitated at a stress concentration

    SciTech Connect (OSTI)

    Allen, Gregory B.; Kerr, Matthew; Daymond, Mark R. (Queens)

    2012-10-23

    Hydrogen adsorption into zirconium, as a result of corrosion in aqueous environments, leads to the precipitation of a secondary brittle hydride phase. These hydrides tend to first form at stress concentrations such as fretting flaws or cracks in engineering components, potentially degrading the structural integrity of the component. One mechanism for component failure is a slow crack growth mechanism known as Delayed Hydride Cracking (DHC), where hydride fracture occurs followed by crack arrest in the ductile zirconium matrix. The current work employs both an experimental and a modeling approach to better characterize the effects and behavior of hydride precipitation at such stress concentrations. Strains around stress concentrations containing hydrides were mapped using High Energy X-ray Diffraction (HEXRD). These studies highlighted important differences in the behavior of the hydride phase and the surrounding zirconium matrix, as well as the strain associated with the precipitation of the hydride. A finite element model was also developed and compared to the X-ray strain mapping results. This model provided greater insight into details that could not be obtained directly from the experimental approaches, as well as providing a framework for future modeling to predict the effects of hydride precipitation under varied conditions.

  10. Groundwater well with reactive filter pack

    DOE Patents [OSTI]

    Gilmore, T.J.; Holdren, G.R. Jr.; Kaplan, D.I.

    1998-09-08

    A method and apparatus are disclosed for the remediation of contaminated soil and ground water wherein a reactive pack material is added to the annular fill material utilized in standard well construction techniques. 3 figs.

  11. Groundwater well with reactive filter pack

    DOE Patents [OSTI]

    Gilmore, Tyler J. (Pasco, WA); Holdren, Jr., George R. (Kennewick, WA); Kaplan, Daniel I. (Richland, WA)

    1998-01-01

    A method and apparatus for the remediation of contaminated soil and ground water wherein a reactive pack material is added to the annular fill material utilized in standard well construction techniques.

  12. Beta dose distribution for randomly packed microspheres 

    E-Print Network [OSTI]

    Urashkin, Alexander

    2007-04-25

    of radiation dose distribution when utilizing this technique. This study focuses on random packing of microspheres and seeks to determine dose distributions for specific cases. The Monte Carlo Neutral Particle code (MCNP) developed by Los Alamos National...

  13. Thermal Design of a Metal Hydride Storage Bed, Permitting Tritium Accountancy to 0.1% Resolution and Repeatability

    E-Print Network [OSTI]

    Thermal Design of a Metal Hydride Storage Bed, Permitting Tritium Accountancy to 0.1% Resolution and Repeatability

  14. Combined on-board hydride slurry storage and reactor system and process for hydrogen-powered vehicles and devices

    DOE Patents [OSTI]

    Brooks, Kriston P; Holladay, Jamelyn D; Simmons, Kevin L; Herling, Darrell R

    2014-11-18

    An on-board hydride storage system and process are described. The system includes a slurry storage system that includes a slurry reactor and a variable concentration slurry. In one preferred configuration, the storage system stores a slurry containing a hydride storage material in a carrier fluid at a first concentration of hydride solids. The slurry reactor receives the slurry containing a second concentration of the hydride storage material and releases hydrogen as a fuel to hydrogen-power devices and vehicles.

  15. UNDERSTANDING OF HYDRIDING MECHANISMS OF ZIRCALOY-4 ALLOY DURING CORROSION IN PWR SIMULATED CONDITIONS

    E-Print Network [OSTI]

    Motta, Arthur T.

    1 UNDERSTANDING OF HYDRIDING MECHANISMS OF ZIRCALOY-4 ALLOY DURING CORROSION IN PWR SIMULATED CONDITIONS AND INFLUENCE OF ZIRCONIUM HYDRIDES ON ZIRCALOY-4 CORROSION C. BISOR-MELLOUL, M. TUPIN, P. BOSSIS-sur-Yvette ­ France A. MOTTA Mechanical and Nuclear Engineering Department, Penn State University 227 Reber Building

  16. 1,2-Aryl and 1,2-Hydride Migration in Transition Metal Complex Catalyzed

    E-Print Network [OSTI]

    Wang, Jianbo

    1,2-Aryl and 1,2-Hydride Migration in Transition Metal Complex Catalyzed Diazo Decomposition of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, Department of Chemistry, Peking Uni,2-hydride migration was studied. A reaction mechanism involving a "bridged" phenonium ion is proposed

  17. Hydrogen storage material and process using graphite additive with metal-doped complex hydrides

    DOE Patents [OSTI]

    Zidan, Ragaiy (Aiken, SC); Ritter, James A. (Lexington, SC); Ebner, Armin D. (Lexington, SC); Wang, Jun (Columbia, SC); Holland, Charles E. (Cayce, SC)

    2008-06-10

    A hydrogen storage material having improved hydrogen absorbtion and desorption kinetics is provided by adding graphite to a complex hydride such as a metal-doped alanate, i.e., NaAlH.sub.4. The incorporation of graphite into the complex hydride significantly enhances the rate of hydrogen absorbtion and desorption and lowers the desorption temperature needed to release stored hydrogen.

  18. Hydride transfer reaction dynamics of OD+ Li Liu, Elizabeth S. Richards, and James M. Farrara

    E-Print Network [OSTI]

    Farrar, James M.

    Hydride transfer reaction dynamics of OD+ +C3H6 Li Liu, Elizabeth S. Richards, and James M. Farrara 30 April 2007; published online 29 June 2007 The hydride transfer reaction between OD+ and C3H6 has, with maxima close to the velocity and direction of the precursor propylene beam, characteristic of direct

  19. Hydride precipitation kinetics in Zircaloy-4 studied using synchrotron X-ray diffraction

    E-Print Network [OSTI]

    Motta, Arthur T.

    Hydride precipitation kinetics in Zircaloy-4 studied using synchrotron X-ray diffraction Olivier F fuel cladding and precipitate as brittle hydride particles, which may reduce cladding ductility. Dissolved hydrogen responds to temperature gradients, resulting in transport and precipitation into cold

  20. Chemical Hydrides for Hydrogen Storage in Fuel Cell Applications

    SciTech Connect (OSTI)

    Devarakonda, Maruthi N.; Brooks, Kriston P.; Ronnebro, Ewa; Rassat, Scot D.; Holladay, Jamelyn D.

    2012-04-16

    Due to its high hydrogen storage capacity (up to 19.6% by weight for the release of 2.5 molar equivalents of hydrogen gas) and its stability under typical ambient conditions, ammonia borane (AB) is a promising material for chemical hydrogen storage for fuel cell applications in transportation sector. Several systems models for chemical hydride materials such as solid AB, liquid AB and alane were developed and evaluated at PNNL to determine an optimal configuration that would meet the 2010 and future DOE targets for hydrogen storage. This paper presents an overview of those systems models and discusses the simulation results for various transient drive cycle scenarios.

  1. The calculated rovibronic spectrum of scandium hydride, ScH

    E-Print Network [OSTI]

    Lodi, Lorenzo; Tennyson\\, Jonathan

    2015-01-01

    The electronic structure of six low-lying electronic states of scandium hydride, $X\\,{}^{1}\\Sigma^+$, $a\\,{}^{3}\\Delta$, $b\\,{}^{3}\\Pi$, $A\\,{}^{1}\\Delta$ $c\\,{}^{3}\\Sigma^+$, and $B\\,{}^{1}\\Pi$, is studied using multi-reference configuration interaction as a function of bond length. Diagonal and off-diagonal dipole moment, spin-orbit coupling and electronic angular momentum curves are also computed. The results are benchmarked against experimental measurements and calculations on atomic scandium. The resulting curves are used to compute a line list of molecular ro-vibronic transitions for $^{45}$ScH.

  2. Electrochemical process and production of novel complex hydrides

    DOE Patents [OSTI]

    Zidan, Ragaiy

    2013-06-25

    A process of using an electrochemical cell to generate aluminum hydride (AlH.sub.3) is provided. The electrolytic cell uses a polar solvent to solubilize NaAlH.sub.4. The resulting electrochemical process results in the formation of AlH.sub.3. The AlH.sub.3 can be recovered and used as a source of hydrogen for the automotive industry. The resulting spent aluminum can be regenerated into NaAlH.sub.4 as part of a closed loop process of AlH.sub.3 generation.

  3. Working with SRNL - Our Facilities - Metal Hydride Laboratories

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust,Field-effectWorking WithTelecentricNCubictheThepresented in1: ModelGloveboxMetal Hydride

  4. Method for packed column separations and purifications

    DOE Patents [OSTI]

    Holman, David A. (Richland, WA); Bruckner-Lea, Cynthia J. (Richland, WA); Brockman, Fred J. (Kennewick, WA); Chandler, Darrell P. (Richland, WA)

    2006-08-15

    The invention encompasses a method of packing and unpacking a column chamber. A mixture of a fluid and a matrix material are introduced through a column chamber inlet so that the matrix material is packed within a column chamber to form a packed column. The column chamber having the column chamber inlet or first port for receiving the mixture further has an outlet port and an actuator port. The outlet port is partially closed for capturing the matrix material and permitting the fluid to flow therepast by rotating relative one to the other of a rod placed in the actuator port. Further rotation relative one to the other of the rod and the column chamber opens the outlet and permits the matrix material and the fluid to flow therethrough thereby unpacking the matrix material from the column chamber.

  5. Method of generating hydrogen-storing hydride complexes

    DOE Patents [OSTI]

    Srinivasan, Sesha S; Niemann, Michael U; Goswami, D. Yogi; Stefanakos, Elias K

    2013-05-14

    A ternary hydrogen storage system having a constant stoichiometric molar ratio of LiNH.sub.2:MgH.sub.2:LiBH.sub.4 of 2:1:1. It was found that the incorporation of MgH.sub.2 particles of approximately 10 nm to 20 nm exhibit a lower initial hydrogen release temperature of 150.degree. C. Furthermore, it is observed that the particle size of LiBNH quaternary hydride has a significant effect on the hydrogen sorption concentration with an optimum size of 28 nm. The as-synthesized hydrides exhibit two main hydrogen release temperatures, one around 160.degree. C. and the other around 300.degree. C., with the main hydrogen release temperature reduced from 310.degree. C. to 270.degree. C., while hydrogen is first reversibly released at temperatures as low as 150.degree. C. with a total hydrogen capacity of 6 wt. % to 8 wt. %. Detailed thermal, capacity, structural and microstructural properties have been demonstrated and correlated with the activation energies of these materials.

  6. GAS-PHASE REACTIONS OF HYDRIDE ANION, H{sup -}

    SciTech Connect (OSTI)

    Martinez, Oscar; Yang Zhibo; Demarais, Nicholas J.; Bierbaum, Veronica M. [Department of Chemistry and Biochemistry, 215 UCB, University of Colorado, Boulder, CO 80309-0215 (United States); Snow, Theodore P., E-mail: Oscar.Martinez@colorado.ed, E-mail: Zhibo.Yang@colorado.ed, E-mail: Nicholas.Demarais@colorado.ed, E-mail: Veronica.Bierbaum@colorado.ed, E-mail: Theodore.Snow@colorado.ed [Department of Astrophysical and Planetary Sciences, 391 UCB, University of Colorado, Boulder, CO 80309-0391 (United States)

    2010-09-01

    Rate constants were measured at 300 K for the reactions of the hydride anion, H{sup -}, with neutral molecules C{sub 2}H{sub 2}, H{sub 2}O, CH{sub 3}CN, CH{sub 3}OH, (CH{sub 3}){sub 2}CO, CH{sub 3}CHO, N{sub 2}O, CO{sub 2}, O{sub 2}, CO, CH{sub 3}Cl, (CH{sub 3}){sub 3}CCl, (CH{sub 3}CH{sub 2}){sub 2}O, C{sub 6}H{sub 6}, and D{sub 2} using a flowing-afterglow instrument. Experimental work was supplemented by ab initio calculations to provide insight into the viability of reaction pathways. Our reported rate constants should prove useful to models of astrophysical environments where conditions prevail for the existence of both H{sup -} and neutral species. The variety of neutral reactants studied includes representative species from prototypical chemical groups, effectively mapping reactivity trends for the hydride anion.

  7. ACCEPTABILITY ENVELOPE FOR METAL HYDRIDE-BASED HYDROGEN STORAGE SYSTEMS

    SciTech Connect (OSTI)

    Hardy, B.; Corgnale, C.; Tamburello, D.; Garrison, S.; Anton, D.

    2011-07-18

    The design and evaluation of media based hydrogen storage systems requires the use of detailed numerical models and experimental studies, with significant amount of time and monetary investment. Thus a scoping tool, referred to as the Acceptability Envelope, was developed to screen preliminary candidate media and storage vessel designs, identifying the range of chemical, physical and geometrical parameters for the coupled media and storage vessel system that allow it to meet performance targets. The model which underpins the analysis allows simplifying the storage system, thus resulting in one input-one output scheme, by grouping of selected quantities. Two cases have been analyzed and results are presented here. In the first application the DOE technical targets (Year 2010, Year 2015 and Ultimate) are used to determine the range of parameters required for the metal hydride media and storage vessel. In the second case the most promising metal hydrides available are compared, highlighting the potential of storage systems, utilizing them, to achieve 40% of the 2010 DOE technical target. Results show that systems based on Li-Mg media have the best potential to attain these performance targets.

  8. Module: Material Structure Focus: Crystal Packing

    E-Print Network [OSTI]

    Rowley, Clarence W.

    ) and body centered cubic. Materials: Styrofoam Balls (20) Smaller Styrofoam Ball Round Toothpicks (16-258-5598 Teacher Notes: After a short review of crystal packing, have the students take 4 Styrofoam balls the students take 8 Styrofoam balls and attach them using toothpick so that they form 2 -4 ball diamond shape

  9. Climate Change Action Pack Climate & Habitats

    E-Print Network [OSTI]

    Gunawardena, Arunika

    Climate Change Action Pack Climate & Habitats B A C K G R O U DN C H E C K ! Habitat, Food, Water. Disease,predation,pollution, accidents and climatic conditions are among other limiting factors which can affect an animal's ability to meet its needs. This section will look further into the impact of Climate

  10. Energy Saving in Distillation Using Structured Packing and Vapor Recompression 

    E-Print Network [OSTI]

    Hill, J.H.

    1987-01-01

    "Distillation is a big consumer of energy in process plant operations. A first step to energy cost savings is the use of high efficiency structured packing in place of trays or dumped packings in conventionally operated ...

  11. Copyright Office of Information Technology, University of Maryland Campus Pack

    E-Print Network [OSTI]

    Yorke, James

    Copyright © Office of Information Technology, University of Maryland Campus Pack Blogs of Maryland College Park Spring 2015 #12;#12;1 Contents Introduction to Campus Pack Blogs Blog, Wiki, or Journal to an ELMS Course Space......................................... 3

  12. Final report for the DOE Metal Hydride Center of Excellence.

    SciTech Connect (OSTI)

    Keller, Jay O.; Klebanoff, Leonard E.

    2012-01-01

    This report summarizes the R&D activities within the U.S. Department of Energy Metal Hydride Center of Excellence (MHCoE) from March 2005 to June 2010. The purpose of the MHCoE has been to conduct highly collaborative and multi-disciplinary applied R&D to develop new reversible hydrogen storage materials that meet or exceed DOE 2010 and 2015 system goals for hydrogen storage materials. The MHCoE combines three broad areas: mechanisms and modeling (which provide a theoretically driven basis for pursuing new materials), materials development (in which new materials are synthesized and characterized) and system design and engineering (which allow these new materials to be realized as practical automotive hydrogen storage systems). This Final Report summarizes the organization and execution of the 5-year research program to develop practical hydrogen storage materials for light duty vehicles. Major results from the MHCoE are summarized, along with suggestions for future research areas.

  13. The Development of a Cathodic Charging System to Form Hydrides in Zircaloy-4 

    E-Print Network [OSTI]

    Brito, Ryan

    2013-02-01

    This project investigates several methods of electrochemical insertion of hydrogen into Zircaloy nuclear fuel cladding. These systems are being assembled at Texas A & M to form zirconium hydride in cladding to model crack propagation during storage...

  14. The Use of Metal Hydrides for Hydrogen Recovery from Industrial Off-Gas Streams 

    E-Print Network [OSTI]

    Rebello, W. J.; Guerrero, P. S.; Goodell, P. D.

    1987-01-01

    technical factors may make it economically attractive for them to consider the hydride separation technology. Table 1 SECONDARY HYDROGEN CAPACITY IN 15 INDUSTRIES elements including palladium, vana dium, and magnesium. and with allo s based...

  15. Electrochromically switched, gas-reservoir metal hydride devices with application to energy-efficient windows

    E-Print Network [OSTI]

    Anders, Andre

    2008-01-01

    allow molecular hydrogen to reach the palladium-capped metalhydrogen is converted to protons, which are transported through the ZrO 2 electrolyte to the palladiumhydrogen and transforms into a transparent hydride. A catalytic capping layer of palladium

  16. Model for Simulation of Hydride Precipitation in Zr-Based Used...

    Broader source: Energy.gov (indexed) [DOE]

    a meso-scale, microstructural evolution model for simulation of zirconium hydride precipitation in the cladding of used fuels during long-term dry-storage. While the Zr-based...

  17. Advanced Metal-Hydrides-Based Thermal Battery: A New Generation of High Density Thermal Battery Based on Advanced Metal Hydrides

    SciTech Connect (OSTI)

    2011-12-01

    HEATS Project: The University of Utah is developing a compact hot-and-cold thermal battery using advanced metal hydrides that could offer efficient climate control system for EVs. The team’s innovative designs of heating and cooling systems for EVs with high energy density, low-cost thermal batteries could significantly reduce the weight and eliminate the space constraint in automobiles. The thermal battery can be charged by plugging it into an electrical outlet while charging the electric battery and it produces heat and cold through a heat exchanger when discharging. The ultimate goal of the project is a climate-controlling thermal battery that can last up to 5,000 charge and discharge cycles while substantially increasing the driving range of EVs, thus reducing the drain on electric batteries.

  18. First-principles calculations of niobium hydride formation in superconducting radio-frequency cavities

    SciTech Connect (OSTI)

    Ford, Denise C.; Cooley, Lance D.; Seidman, David N.

    2013-09-01

    Niobium hydride is suspected to be a major contributor to degradation of the quality factor of niobium superconducting radio-frequency (SRF) cavities. In this study, we connect the fundamental properties of hydrogen in niobium to SRF cavity performance and processing. We modeled several of the niobium hydride phases relevant to SRF cavities and present their thermodynamic, electronic, and geometric properties determined from calculations based on density-functional theory. We find that the absorption of hydrogen from the gas phase into niobium is exothermic and hydrogen becomes somewhat anionic. The absorption of hydrogen by niobium lattice vacancies is strongly preferred over absorption into interstitial sites. A single vacancy can accommodate six hydrogen atoms in the symmetrically equivalent lowest-energy sites and additional hydrogen in the nearby interstitial sites affected by the strain field: this indicates that a vacancy can serve as a nucleation center for hydride phase formation. Small hydride precipitates may then occur near lattice vacancies upon cooling. Vacancy clusters and extended defects should also be enriched in hydrogen, potentially resulting in extended hydride phase regions upon cooling. We also assess the phase changes in the niobium-hydrogen system based on charge transfer between niobium and hydrogen, the strain field associated with interstitial hydrogen, and the geometry of the hydride phases. The results of this study stress the importance of not only the hydrogen content in niobium, but also the recovery state of niobium for the performance of SRF cavities.

  19. Probe with integrated heater and thermocouple pack

    DOE Patents [OSTI]

    McCulloch, Reg W. (Oak Ridge, TN); Dial, Ralph E. (Concord, TN); Finnell, Wilber K. R. (Kingston, TN)

    1990-01-01

    A probe for measuring heat includes an elongate rod fitted within a sheath, and a plurality of annular recesses are formed on the surface of the rod in a spaced-apart relationship to form annular chambers that are resistant to heat flow. A longitudinal bore extends axially into the rod and within the cylinders defined by the annular chambers, and an integrated heater and thermocouple pack is dimensioned to fit within the bore. In construction, the integrated pack includes a plurality of wires disposed in electrical insulation within a sheath and a heater cable. These wires include one common wire and a plurality of thermocuple wires. The common wire is constructed of one type of conductive material while the thermocouple wires are each constructed of two types of materials so that at least one thermocouple junction is formed therein. All of the wires extend the length of the integrated pack and are connected together at their ends. The thermocouple wires are constructed to form thermocouple junctions proximate to each annular chamber for producing electromotive forces corresponding to the temperature of the rod within the annular chambers relative to outside the chambers. In the preferred embodiment, each thermocouple wire forms two thermocouple junctions, one junction being disposed within an annular chamber and the second junction being disposed outside of, but proximate to, the same annular chamber. In one embodiment two thermocouple wires are configured to double the sensitivity of the probe in one region.

  20. Effects of outgassing of loader chamber walls on hydriding of thin films for commercial applications

    SciTech Connect (OSTI)

    Provo, James L., E-mail: jlprovo@verizon.net [Consultant, J.L. Provo Consulting, Trinity, Florida 34655-7179 (United States)

    2014-07-01

    An important aspect of understanding industrial processing is to know the characteristics of the materials used in such processes. A study was performed to determine the effects of hydriding chamber material on the degree of hydriding for the commercial production of thin film hydride targets for various research universities, commercial companies, and government national laboratories. The goal was to increase the degree of hydriding of various thin film hydrides and to study the vacuum environment during air-exposure hydriding. For this purpose, dynamic residual gas analysis during deuterium gas hydride processing was utilized with erbium thin films, employing a special set-up for direct dynamic hydride gas sampling during processing at elevated temperature and full loading gas pressure. Complete process data for (1) a copper–(1.83?wt.?%)beryllium wet hydrogen fired passivated (600?°C–1?h) externally heated pipe hydriding chamber are reported. Dynamic residual gas analysis comparisons during hydriding are presented for hydriding chambers made from (2) alumina (99.8 wt.?%), (3) copper (with an interior aluminum coating ?10 k Å thick, and (4) for a stainless-steel air-fired passivated (900?°C–1?h) chamber. Dynamic data with deuterium gas in the chamber at the hydriding temperature (450?°C) showed the presence and growth of water vapor (D{sub 2}O) and related mixed ion species(H{sub 2}O{sup +}, HDO{sup +}, D{sub 2}O{sup +}, and OD{sup +}) from hydrogen isotope exchange reactions during the 1?h process time. Peaks at mass-to-charge ratios (i.e., m/e) of 12(C{sup +}), 16(CD{sub 2}{sup +}), 17(CHD{sub 2}{sup +}), and 18(CD{sub 3}{sup +}, OD{sup +}) increased for approximately the first half hour of a 1?h hydriding process and then approach steady state. Mass-to-charge peaks at 19(HDO{sup +}) and 20(D{sub 2}O{sup +}) continue to increase throughout the process cycle. Using the m/e?=?20 (D{sub 2}O{sup +}) peak intensity from chamber (1)–Cu(1.83 wt.?%)Be as a standard, the peak intensity from chamber (4)—stainless-steel (air-fired) was 7.1× higher, indicating that the surface of stainless-steel had a larger concentration of reactive oxygen and/or water than hydrogen. The (D{sub 2}O{sup +}) peak intensity from chamber (3)—Cu (interior Al coating) was 1.55× larger and chamber (2)—alumina(99.8%) was 1.33× higher than Cu(1.83 wt.?%)Be. Thus copper–(1.83 wt.?%)beryllium was the best hydriding chamber material studied followed closely by the alumina (99.8 wt.?%) chamber. Gas take-up by Er occluder targets processed in Cu(1.83?wt.?%)Be hydriding chambers (i.e., gas/metal atomic ratios) correlate with the dynamic RGA data.

  1. Fact #603: December 28, 2009 Where Does Lithium Come From?

    Broader source: Energy.gov [DOE]

    Lithium ion batteries will be used in many of the upcoming plug-in hybrid vehicles and electric vehicles because they are lighter and more powerful than the nickel-metal hydride batteries used in...

  2. Multifunctional microtruss laminates: Textile synthesis and properties

    E-Print Network [OSTI]

    Wadley, Haydn

    .N.G. Wadley Department of Materials Science and Engineering, 116 Engineer's Way, School of Engineering heat exchangers and as the electrodes in nickel metal hydride batteries.4 Their Young's moduli

  3. A. M. Sastry B. E. Layton

    E-Print Network [OSTI]

    Sastry, Ann Marie

    X. Cheng A. M. Sastry B. E. Layton Department of Mechanical Engineering and Applied Mechanics for production of posi- tive electrodes for NiMH nickel-metal hydride batteries are comprised of two or more

  4. Technological assessment and evaluation of high power batteries and their commercial values

    E-Print Network [OSTI]

    Teo, Seh Kiat

    2006-01-01

    Lithium Ion (Li-ion) battery technology has the potential to compete with the more matured Nickel Metal Hydride (NiMH) battery technology in the Hybrid Electric Vehicle (HEV) energy storage market as it has higher specific ...

  5. New sealed rechargeable batteries and supercapacitors

    SciTech Connect (OSTI)

    Barnett, B.M. ); Dowgiallo, E. ); Halpert, G. ); Matsuda, Y. ); Takehara, Z.I. )

    1993-01-01

    This conference was divided into the following sections: supercapacitors; nickel-metal hydride batteries; lithium polymer batteries; lithium/carbon batteries; cathode materials; and lithium batteries. Separate abstracts were prepared for the 46 papers of this conference.

  6. Complex Hydride Compounds with Enhanced Hydrogen Storage Capacity

    SciTech Connect (OSTI)

    Mosher, Daniel A.; Opalka, Susanne M.; Tang, Xia; Laube, Bruce L.; Brown, Ronald J.; Vanderspurt, Thomas H.; Arsenault, Sarah; Wu, Robert; Strickler, Jamie; Anton, Donald L.; Zidan, Ragaiy; Berseth, Polly

    2008-02-18

    The United Technologies Research Center (UTRC), in collaboration with major partners Albemarle Corporation (Albemarle) and the Savannah River National Laboratory (SRNL), conducted research to discover new hydride materials for the storage of hydrogen having on-board reversibility and a target gravimetric capacity of ? 7.5 weight percent (wt %). When integrated into a system with a reasonable efficiency of 60% (mass of hydride / total mass), this target material would produce a system gravimetric capacity of ? 4.5 wt %, consistent with the DOE 2007 target. The approach established for the project combined first principles modeling (FPM - UTRC) with multiple synthesis methods: Solid State Processing (SSP - UTRC), Solution Based Processing (SBP - Albemarle) and Molten State Processing (MSP - SRNL). In the search for novel compounds, each of these methods has advantages and disadvantages; by combining them, the potential for success was increased. During the project, UTRC refined its FPM framework which includes ground state (0 Kelvin) structural determinations, elevated temperature thermodynamic predictions and thermodynamic / phase diagram calculations. This modeling was used both to precede synthesis in a virtual search for new compounds and after initial synthesis to examine reaction details and options for modifications including co-reactant additions. The SSP synthesis method involved high energy ball milling which was simple, efficient for small batches and has proven effective for other storage material compositions. The SBP method produced very homogeneous chemical reactions, some of which cannot be performed via solid state routes, and would be the preferred approach for large scale production. The MSP technique is similar to the SSP method, but involves higher temperature and hydrogen pressure conditions to achieve greater species mobility. During the initial phases of the project, the focus was on higher order alanate complexes in the phase space between alkaline metal hydrides (AmH), Alkaline earth metal hydrides (AeH2), alane (AlH3), transition metal (Tm) hydrides (TmHz, where z=1-3) and molecular hydrogen (H2). The effort started first with variations of known alanates and subsequently extended the search to unknown compounds. In this stage, the FPM techniques were developed and validated on known alanate materials such as NaAlH4 and Na2LiAlH6. The coupled predictive methodologies were used to survey over 200 proposed phases in six quaternary spaces, formed from various combinations of Na, Li Mg and/or Ti with Al and H. A wide range of alanate compounds was examined using SSP having additions of Ti, Cr, Co, Ni and Fe. A number of compositions and reaction paths were identified having H weight fractions up to 5.6 wt %, but none meeting the 7.5 wt%H reversible goal. Similarly, MSP of alanates produced a number of interesting compounds and general conclusions regarding reaction behavior of mixtures during processing, but no alanate based candidates meeting the 7.5 wt% goal. A novel alanate, LiMg(AlH4)3, was synthesized using SBP that demonstrated a 7.0 wt% capacity with a desorption temperature of 150°C. The deuteride form was synthesized and characterized by the Institute for Energy (IFE) in Norway to determine its crystalline structure for related FPM studies. However, the reaction exhibited exothermicity and therefore was not reversible under acceptable hydrogen gas pressures for on-board recharging. After the extensive studies of alanates, the material class of emphasis was shifted to borohydrides. Through SBP, several ligand-stabilized Mg(BH4)2 complexes were synthesized. The Mg(BH4)2*2NH3 complex was found to change behavior with slightly different synthesis conditions and/or aging. One of the two mechanisms was an amine-borane (NH3BH3) like dissociation reaction which released up to 16 wt %H and more conservatively 9 wt%H when not including H2 released from the NH3. From FPM, the stability of the Mg(BH4)2*2NH3 compound was found to increase with the inclusion of NH3 groups in the inner-Mg coordination

  7. Documentation of Hybrid Hydride Model for Incorporation into Moose-Bison and Validation Strategy.

    SciTech Connect (OSTI)

    Weck, Philippe F; Tikare, Veena; Schultz, Peter Andrew; Clark, B; Mitchell, J; Glazoff, Michael V.; Homer, Eric R.

    2014-10-01

    This report documents the development, demonstration and validation of a mesoscale, microstructural evolution model for simulation of zirconium hydride ?-ZrH{sub 1.5} precipitation in the cladding of used nuclear fuels that may occur during long-term dry storage. While the Zr-based claddings are manufactured free of any hydrogen, they absorb hydrogen during service, in the reactor by a process commonly termed ‘hydrogen pick-up’. The precipitation and growth of zirconium hydrides during dry storage is one of the most likely fuel rod integrity failure mechanisms either by embrittlement or delayed hydride cracking of the cladding (Hanson et al., 2011). While the phenomenon is well documented and identified as a potential key failure mechanism during long-term dry storage (Birk et al., 2012 and NUREG/CR-7116), the ability to actually predict the formation of hydrides is poor. The model being documented in this work is a computational capability for the prediction of hydride formation in different claddings of used nuclear fuels. This work supports the Used Fuel Disposition Research and Development Campaign in assessing the structural engineering performance of the cladding during and after long-term dry storage. In this work, a model to numerically simulate hydride precipitation at the microstructural scale, in a wide variety of Zr-based claddings, under dry-storage conditions is being developed. It will be used to aid in the evaluation of the mechanical integrity of used fuel rods during dry storage and transportation by providing the structural conditions from the microstructural scale to the continuum scale to engineering component scale models to predict if the used fuel rods will perform without failure under normal and off-normal conditions. The microstructure, especially, the hydride structure is thought to be a primary determinant of cladding failure, thus this component of UFD’s storage and transportation analysis program is critical. The model development, application and validation of the model are documented and the limitations of the current model are discussed. The model has been shown to simulate hydride precipitation in Zircaloy-4 cladding with correct morphology, thermodynamics and kinetics. An unexpected insight obtained from simulations hydride formation in Zircaloy-4 is that small (sub-micron) precipitates need to order themselves to form the larger hydrides typically described as radially-reoriented precipitates. A limitation of this model is that it does not currently solve the stress state that forms dynamically in the precipitate or matrix surrounding the precipitate. A method to overcome the limitations is suggested and described in detail. The necessary experiments to provide key materials physics and to validate the model are also recommended.

  8. Electronic structure and crystal phase stability of palladium hydrides

    SciTech Connect (OSTI)

    Houari, Abdesalem; Matar, Samir F.; Eyert, Volker

    2014-11-07

    The results of electronic structure calculations for a variety of palladium hydrides are presented. The calculations are based on density functional theory and used different local and semilocal approximations. The thermodynamic stability of all structures as well as the electronic and chemical bonding properties are addressed. For the monohydride, taking into account the zero-point energy is important to identify the octahedral Pd-H arrangement with its larger voids and, hence, softer hydrogen vibrational modes as favorable over the tetrahedral arrangement as found in the zincblende and wurtzite structures. Stabilization of the rocksalt structure is due to strong bonding of the 4d and 1s orbitals, which form a characteristic split-off band separated from the main d-band group. Increased filling of the formerly pure d states of the metal causes strong reduction of the density of states at the Fermi energy, which undermines possible long-range ferromagnetic order otherwise favored by strong magnetovolume effects. For the dihydride, octahedral Pd-H arrangement as realized, e.g., in the pyrite structure turns out to be unstable against tetrahedral arrangement as found in the fluorite structure. Yet, from both heat of formation and chemical bonding considerations, the dihydride turns out to be less favorable than the monohydride. Finally, the vacancy ordered defect phase Pd{sub 3}H{sub 4} follows the general trend of favoring the octahedral arrangement of the rocksalt structure for Pd:H ratios less or equal to one.

  9. Energy transport in jammed sphere packings

    E-Print Network [OSTI]

    Ning Xu; Vincenzo Vitelli; Matthieu Wyart; Andrea J. Liu; Sidney R. Nagel

    2008-11-17

    We calculate the normal modes of vibration in jammed sphere packings to obtain the energy diffusivity, a spectral measure of transport. At the boson peak frequency, we find an Ioffe-Regel crossover from a diffusivity that drops rapidly with frequency to one that is nearly frequency-independent. This crossover frequency shifts to zero as the system is decompressed towards the jamming transition, providing unambiguous evidence of a regime in frequency of nearly constant diffusivity. Such a regime, postulated to exist in glasses to explain the temperature dependence of the thermal conductivity, therefore appears to arise from properties of the jamming transition.

  10. Packed fluidized bed blanket for fusion reactor

    DOE Patents [OSTI]

    Chi, John W. H. (Mt. Lebanon, PA)

    1984-01-01

    A packed fluidized bed blanket for a fusion reactor providing for efficient radiation absorption for energy recovery, efficient neutron absorption for nuclear transformations, ease of blanket removal, processing and replacement, and on-line fueling/refueling. The blanket of the reactor contains a bed of stationary particles during reactor operation, cooled by a radial flow of coolant. During fueling/refueling, an axial flow is introduced into the bed in stages at various axial locations to fluidize the bed. When desired, the fluidization flow can be used to remove particles from the blanket.

  11. Hydride transfer reaction dynamics of OD{sup +}+C{sub 3}H{sub 6}

    SciTech Connect (OSTI)

    Liu, Li; Richards, Elizabeth S.; Farrar, James M. [Department of Chemistry, University of Rochester, Rochester, New York 14627 (United States)

    2007-06-28

    The hydride transfer reaction between OD{sup +} and C{sub 3}H{sub 6} has been studied experimentally and theoretically over the center of mass collision energy range from 0.21 to 0.92 eV using the crossed beam technique and density functional theory calculations. The center of mass flux distributions of the product ions at three different energies are highly asymmetric, with maxima close to the velocity and direction of the precursor propylene beam, characteristic of direct reactions. In the hydride transfer process, the entire reaction exothermicity is transformed into product internal excitation, consistent with mixed energy release in which the hydride ion is transferred with both the breaking and forming bonds extended. At higher collision energies, at least 85% of the incremental translational energy appears in product translation, providing a clear example of induced repulsive energy release. Compared to the related reaction of OD{sup +} with C{sub 2}H{sub 4}, reaction along the pathway initiated by addition of OD{sup +} to the C=C bond in propylene has a critical bottleneck caused by the torsional motion of the methyl substituent on the double bond. This bottleneck suppresses reaction through an intermediate complex in favor of direct hydride abstraction. Hydride abstraction appears to be a sequential process initiated by electron transfer in the triplet manifold, followed by rapid intersystem crossing and subsequent hydrogen atom transfer to form ground state allyl cation and HOD.

  12. Materials Down-selection Decisions Made within the DOE Metal Hydride Center of Excellence (MHCoE) - September-October 2007

    Fuel Cell Technologies Publication and Product Library (EERE)

    Reports on which hydrogen storage materials offer potential for further research as decided by DOE's Metal Hydride Center of Excellence.

  13. Materials Down-selection Decisions Made within the DOE Metal Hydride Center of Excellence (MHCoE) - September-October 2007

    SciTech Connect (OSTI)

    Klebanoff, Lennie [Sandia National Lab. (SNL-CA), Livermore, CA (United States)

    2007-09-01

    Reports on which hydrogen storage materials offer potential for further research as decided by DOE's Metal Hydride Center of Excellence.

  14. Understanding shape entropy through local dense packing

    E-Print Network [OSTI]

    Greg van Anders; Daphne Klotsa; N. Khalid Ahmed; Michael Engel; Sharon C. Glotzer

    2014-10-28

    Entropy drives the phase behavior of colloids ranging from dense suspensions of hard spheres or rods to dilute suspensions of hard spheres and depletants. Entropic ordering of anisotropic shapes into complex crystals, liquid crystals, and even quasicrystals has been demonstrated recently in computer simulations and experiments. The ordering of shapes appears to arise from the emergence of directional entropic forces (DEFs) that align neighboring particles, but these forces have been neither rigorously defined nor quantified in generic systems. Here, we show quantitatively that shape drives the phase behavior of systems of anisotropic particles upon crowding through DEFs. We define DEFs in generic systems, and compute them for several hard particle systems. We show that they are on the order of a few kT at the onset of ordering, placing DEFs on par with traditional depletion, van der Waals, and other intrinsic interactions. In experimental systems with these other interactions, we provide direct quantitative evidence that entropic effects of shape also contribute to self-assembly. We use DEFs to draw a distinction between self-assembly and packing behavior. We show that the mechanism that generates directional entropic forces is the maximization of entropy by optimizing local particle packing. We show that this mechanism occurs in a wide class of systems, and we treat, in a unified way, the entropy-driven phase behavior of arbitrary shapes incorporating the well-known works of Kirkwood, Onsager, and Asakura and Oosawa.

  15. A study of a cooling tower with variable packing heights 

    E-Print Network [OSTI]

    Khan, A. M. M. Farid

    1957-01-01

    and Electronic Relay 17 6. 7 ~ 8. View of the Instrument Panel Racking Arrangement Spacer and Packing Types 23 23 10. Effect of Tower Height on Range/Approach Ratio for Rectangular Packing 35 Effect of Tower Height on Range/Approach Rptio for Circular... - round type packing 33 VI. Average results ? triangular packing with vertex up 34 SYMBOLS ALUB ABB?', 'VIATIO&IS mass air flow rate, pounds per (hour)(unit ground area) h" ent'halpy of saturated ai- at water temperature, Btu per pound of dry air. ha...

  16. Packed bed carburization of tantalum and tantalum alloy

    DOE Patents [OSTI]

    Lopez, Peter C. (Espanola, NM); Rodriguez, Patrick J. (Espanola, NM); Pereyra, Ramiro A. (Medanales, NM)

    1999-01-01

    Packed bed carburization of a tantalum or tantalum alloy object. A method for producing corrosion-resistant tantalum or tantalum alloy objects is described. The method includes the steps of placing the object in contact with a carburizing pack, heating the packed object in vacuum furnace to a temperature whereby carbon from the pack diffuses into the object forming grains with tantalum carbide along the grain boundaries, and etching the surface of the carburized object. This latter step removes tantalum carbides from the surface of the carburized tantalum object while leaving the tantalum carbide along the grain boundaries.

  17. Packed bed carburization of tantalum and tantalum alloy

    DOE Patents [OSTI]

    Lopez, P.C.; Rodriguez, P.J.; Pereyra, R.A.

    1999-06-29

    Packed bed carburization of a tantalum or tantalum alloy object is disclosed. A method for producing corrosion-resistant tantalum or tantalum alloy objects is described. The method includes the steps of placing the object in contact with a carburizing pack, heating the packed object in vacuum furnace to a temperature whereby carbon from the pack diffuses into the object forming grains with tantalum carbide along the grain boundaries, and etching the surface of the carburized object. This latter step removes tantalum carbides from the surface of the carburized tantalum object while leaving the tantalum carbide along the grain boundaries. 4 figs.

  18. Deadtime Correction and Hydride Evaluation for Atom-Probe Data, with Applications for Studies of Nanoscale Grains and Carbon

    E-Print Network [OSTI]

    Deadtime Correction and Hydride Evaluation for Atom-Probe Data, with Applications for Studies for Atom-Probe Tomography, Dept. of Materials Science and Engineering, Northwestern University, Evanston hydride formation [3]. Measurements for this study are made with a Cameca LEAP 4000X Si atom

  19. Stimulated Emission from As-grown GaN Hexagons by Selective Area Growth Hydride Vapor Phase Epitaxy

    E-Print Network [OSTI]

    Stimulated Emission from As-grown GaN Hexagons by Selective Area Growth Hydride Vapor Phase Epitaxy Engineering and the Photonics Center, Boston University, 8 Saint Mary's St., Boston, MA 02215-2421, USA R hydride vapor phase epitaxy. We found the threshold for bulk stimulated emission to be 3.4 MW cm2

  20. Enantioselective Organocatalytic Hydride Reduction Stephane G. Ouellet, Jamison B. Tuttle, and David W. C. MacMillan*

    E-Print Network [OSTI]

    MacMillan, David W. C.

    Enantioselective Organocatalytic Hydride Reduction Ste´phane G. Ouellet, Jamison B. Tuttle, and David W. C. MacMillan* DiVision of Chemistry and Chemical Engineering, California Institute enzymes and hydride-reduction cofactors such as NADH or FADH2.2 On this basis, we recently questioned

  1. Scanning Kelvin probe microscopy of surface electronic structure in GaN grown by hydride vapor phase epitaxy

    E-Print Network [OSTI]

    Yu, Edward T.

    Scanning Kelvin probe microscopy of surface electronic structure in GaN grown by hydride vapor Engineering and Program in Materials Science and Engineering, University of California at San Diego, La Jolla microscopy is used to image surface potential variations in GaN 0001 grown by hydride vapor phase epitaxy

  2. Acid strength and solvation effects on methylation, hydride transfer, and isomerization rates during catalytic homologation of C1 species

    E-Print Network [OSTI]

    Iglesia, Enrique

    Acid strength and solvation effects on methylation, hydride transfer, and isomerization rates,b, a Department of Chemical and Biomolecular Engineering, University of California at Berkeley, USA b Division, FAU, MFI) via methylation and hydride transfer steps that favor isobutane and triptane formation

  3. High Density Hydrogen Storage System Demonstration Using NaAlH4 Based Complex Compound Hydrides

    SciTech Connect (OSTI)

    Daniel A. Mosher; Xia Tang; Ronald J. Brown; Sarah Arsenault; Salvatore Saitta; Bruce L. Laube; Robert H. Dold; Donald L. Anton

    2007-07-27

    This final report describes the motivations, activities and results of the hydrogen storage independent project "High Density Hydrogen Storage System Demonstration Using NaAlH4 Based Complex Compound Hydrides" performed by the United Technologies Research Center under the Department of Energy Hydrogen Program, contract # DE-FC36-02AL67610. The objectives of the project were to identify and address the key systems technologies associated with applying complex hydride materials, particularly ones which differ from those for conventional metal hydride based storage. This involved the design, fabrication and testing of two prototype systems based on the hydrogen storage material NaAlH4. Safety testing, catalysis studies, heat exchanger optimization, reaction kinetics modeling, thermochemical finite element analysis, powder densification development and material neutralization were elements included in the effort.

  4. Titanium tritide radioisotope heat source development : palladium-coated titanium hydriding kinetics and tritium loading tests.

    SciTech Connect (OSTI)

    Van Blarigan, Peter; Shugard, Andrew D.; Walters, R. Tom

    2012-01-01

    We have found that a 180 nm palladium coating enables titanium to be loaded with hydrogen isotopes without the typical 400-500 C vacuum activation step. The hydriding kinetics of Pd coated Ti can be described by the Mintz-Bloch adherent film model, where the rate of hydrogen absorption is controlled by diffusion through an adherent metal-hydride layer. Hydriding rate constants of Pd coated and vacuum activated Ti were found to be very similar. In addition, deuterium/tritium loading experiments were done on stacks of Pd coated Ti foil in a representative-size radioisotope heat source vessel. The experiments demonstrated that such a vessel could be loaded completely, at temperatures below 300 C, in less than 10 hours, using existing department-of-energy tritium handling infrastructure.

  5. A mechanistic study of aryl halide reactions with lithium aluminum hydride 

    E-Print Network [OSTI]

    Chung, Fu-Fan

    1980-01-01

    A M:"CHA~JISTIC STUDv OF ARYL HALID RHAC IC~JS ' ITH LITHIUM ALUM 'J"M HYDRIDE A Thesis FU-FAJJ CHUI'JG Submitted to the Graduate College of Texas ARM University in nartial fulfillment of the reauirement for the degree of MASTER OF SCI- JC... August Jo80 Major Subject: Chemistry A MECHANISTIC STUDY OF ARYL HALIDE REACTIONS 1'IITH LITHIUM ALUMINUM HYDRIDE A Thesis by FU-FAN CHUNG Approved as to style and content by; (Chairman of Co ittee) (Member) , . 7 1 (Member) (Member) i (Head...

  6. Method of production of pure hydrogen near room temperature from aluminum-based hydride materials

    DOE Patents [OSTI]

    Pecharsky, Vitalij K.; Balema, Viktor P.

    2004-08-10

    The present invention provides a cost-effective method of producing pure hydrogen gas from hydride-based solid materials. The hydride-based solid material is mechanically processed in the presence of a catalyst to obtain pure gaseous hydrogen. Unlike previous methods, hydrogen may be obtained from the solid material without heating, and without the addition of a solvent during processing. The described method of hydrogen production is useful for energy conversion and production technologies that consume pure gaseous hydrogen as a fuel.

  7. Method and composition in which metal hydride particles are embedded in a silica network

    DOE Patents [OSTI]

    Heung, Leung K. (Aiken, SC)

    1999-01-01

    A silica embedded metal hydride composition and a method for making such a composition. The composition is made via the following process: A quantity of fumed silica is blended with water to make a paste. After adding metal hydride particles, the paste is dried to form a solid. According to one embodiment of the invention, the solid is ground into granules for use of the product in hydrogen storage. Alternatively, the paste can be molded into plates or cylinders and then dried for use of the product as a hydrogen filter. Where mechanical strength is required, the paste can be impregnated in a porous substrate or wire network.

  8. Volatile Components from Packing Matrials, Rev. 2

    SciTech Connect (OSTI)

    Smith, R. A.

    2006-03-01

    An outgassing study was conducted on five packing materials, comprising two experiments. These materials comprised 277-4 borated concrete, Borobond4 concrete, polyethylene bags, silica-filled silicone rubber seals, and silicone foam padding. The purpose was measure the volume of gases which diffuse from packaging materials when sealed in containers. Two heating profiles were used to study the offgassing quantities in a set of accelerated aging tests. It was determined that the concretes contain a large quantity of water. The plastic materials hold much less moisture, with the silicone materials even consuming water, possibly due to the presence of silica filler. Polyethylene tends to degrade as the temperature is elevated and the foam stiffens.

  9. Granular impact and the critical packing state

    E-Print Network [OSTI]

    Umbanhowar, Paul; 10.1103/PhysRevE.82.010301

    2010-01-01

    Impact dynamics during collisions of spheres with granular media reveal a pronounced and non-trivial dependence on volume fraction \\phi. Post impact crater morphology identifies the critical packing state \\phi_{cps}, where sheared grains neither dilate nor consolidate, and indicates an associated change in spatial response. Current phenomenological models fail to capture the observed impact force for most \\phi; only near \\phi_{cps} is force separable into additive terms linear in depth and quadratic in velocity. At fixed depth the quadratic drag coefficient decreases (increases) with depth for \\phi \\phi_{cps}). At fixed low velocity, depth dependence of force shows a Janssen-type exponential response with a length scale that decreases with increasing \\phi; and is nearly constant for \\phi > \\phi_{cps}.

  10. Granular impact and the critical packing state

    E-Print Network [OSTI]

    Paul Umbanhowar; Daniel I. Goldman

    2010-07-16

    Impact dynamics during collisions of spheres with granular media reveal a pronounced and non-trivial dependence on volume fraction \\phi. Post impact crater morphology identifies the critical packing state \\phi_{cps}, where sheared grains neither dilate nor consolidate, and indicates an associated change in spatial response. Current phenomenological models fail to capture the observed impact force for most \\phi; only near \\phi_{cps} is force separable into additive terms linear in depth and quadratic in velocity. At fixed depth the quadratic drag coefficient decreases (increases) with depth for \\phi \\phi_{cps}). At fixed low velocity, depth dependence of force shows a Janssen-type exponential response with a length scale that decreases with increasing \\phi; and is nearly constant for \\phi > \\phi_{cps}.

  11. Packed bed reactor for photochemical .sup.196 Hg isotope separation

    DOE Patents [OSTI]

    Grossman, Mark W. (Belmont, MA); Speer, Richard (Reading, MA)

    1992-01-01

    Straight tubes and randomly oriented pieces of tubing having been employed in a photochemical mercury enrichment reactor and have been found to improve the enrichment factor (E) and utilization (U) compared to a non-packed reactor. One preferred embodiment of this system uses a moving bed (via gravity) for random packing.

  12. . AN IMPROVED AND PRACTICAL METHOD OF PACKING FISH FOR TRANSPORTATION

    E-Print Network [OSTI]

    = . AN IMPROVED AND PRACTICAL METHOD OF PACKING FISH FOR TRANSPORTATION $- By A. Selling Commissioner to the Danish Government Fisheries Department, London, England Paper presented before the Fourth for pagination #12;AN IMPROVED AND PRACTICAL METHOD OF PACKING FISH FOR TRANSPORTATION. ,JI By A. Stl

  13. Campus Pack Blogs, Wikis & Journals August 2, 2014 Release

    E-Print Network [OSTI]

    Yorke, James

    Campus Pack Blogs, Wikis & Journals August 2, 2014 Release Campus Pack has introduced a new version Navigation Navigate through the wiki (blog, journal) pages by clicking the "Pages" button in the upper left. All of the pages will be listed. Click the "Add New Page" button to add pages to the blog, wiki

  14. Procedure for Packing Weather Files for DOE-2e 

    E-Print Network [OSTI]

    Kim, K. H.; Baltazar-Cervantes, J. C.

    2010-01-01

    -09-03 Procedure for Packing Weather Files for DOE-2e Kee Han Kim Juan-Carlos Baltazar-Cervantes, Ph.D. September 2010 ESL-TR-10-09-03 TABLE OF CONTENTS CHAPTER 1... ................................................................................................................................................. 7 1. OVERVIEW ..................................................................................................................................... 7 2. PROCESS OF PACKING WEATHER DATA FOR DOE-2e SIMULATION ............................... 8 2...

  15. An Electrolytic Method to Form Zirconium Hydride Phases in Zirconium Alloys with Morphologies Similar to Hydrides Formed in Used Nuclear Fuel 

    E-Print Network [OSTI]

    Kuhr, Samuel Houston

    2012-10-19

    )........................................................................................................... 56 Figure 23 Copper from the bronze electrode dissolved into solution and electroplated on top of graphite anode. ............................................... 60 Figure 24 Method 2 sample holder configuration... morphologies, densities, and geometries of hydrides which mimic those found in the real world application. 2.3.1 Electrolytic Method Electrolytic methods involving sulfuric acid baths or molten salt baths are used to coat the outside of the sample...

  16. Measured Black Carbon Deposition on the Sierra Nevada Snow Pack and Implication for Snow Pack Retreat

    SciTech Connect (OSTI)

    Hadley, O.L.; Corrigan, C.E.; Kirchstetter, T.W.; Cliff, S.S.; Ramanathan, V.

    2010-01-12

    Modeling studies show that the darkening of snow and ice by black carbon deposition is a major factor for the rapid disappearance of arctic sea ice, mountain glaciers and snow packs. This study provides one of the first direct measurements for the efficient removal of black carbon from the atmosphere by snow and its subsequent deposition to the snow packs of California. The early melting of the snow packs in the Sierras is one of the contributing factors to the severe water problems in California. BC concentrations in falling snow were measured at two mountain locations and in rain at a coastal site. All three stations reveal large BC concentrations in precipitation, ranging from 1.7 ng/g to 12.9 ng/g. The BC concentrations in the air after the snow fall were negligible suggesting an extremely efficient removal of BC by snow. The data suggest that below cloud scavenging, rather than ice nuclei, was the dominant source of BC in the snow. A five-year comparison of BC, dust, and total fine aerosol mass concentrations at multiple sites reveals that the measurements made at the sampling sites were representative of large scale deposition in the Sierra Nevada. The relative concentration of iron and calcium in the mountain aerosol indicates that one-quarter to one-third of the BC may have been transported from Asia.

  17. Stabilization of Nickel Metal Catalysts for Aqueous Processing Systems -

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust,Field-effect Photovoltaics -7541C.3 SpecialSponsor GuidelinesPlasma Physics and

  18. A PROTOTYPE FOUR INCH SHORT HYDRIDE (FISH) BED AS A REPLACEMENT TRITIUM STORAGE BED

    SciTech Connect (OSTI)

    Klein, J.; Estochen, E.; Shanahan, K.; Heung, L.

    2011-02-23

    The Savannah River Site (SRS) tritium facilities have used 1st generation (Gen1) metal hydride storage bed assemblies with process vessels (PVs) fabricated from 3 inch nominal pipe size (NPS) pipe to hold up to 12.6 kg of LaNi{sub 4.25}Al{sub 0.75} metal hydride for tritium gas absorption, storage, and desorption for over 15 years. The 2nd generation (Gen2) of the bed design used the same NPS for the PV, but the added internal components produced a bed nominally 1.2 m long, and presented a significant challenge for heater cartridge replacement in a footprint limited glove-box. A prototype 3rd generation (Gen3) metal hydride storage bed has been designed and fabricated as a replacement candidate for the Gen2 storage bed. The prototype Gen3 bed uses a PV pipe diameter of 4 inch NPS so the bed length can be reduced below 0.7 m to facilitate heater cartridge replacement. For the Gen3 prototype bed, modeling results show increased absorption rates when using hydrides with lower absorption pressures. To improve absorption performance compared to the Gen2 beds, a LaNi{sub 4.15}Al{sub 0.85} material was procured and processed to obtain the desired pressure-composition-temperature (PCT) properties. Other bed design improvements are also presented.

  19. Elucidating Reactivity Differences in Palladium-Catalyzed Coupling Processes: The Chemistry of Palladium Hydrides

    E-Print Network [OSTI]

    Fu, Gregory C.

    Elucidating Reactivity Differences in Palladium-Catalyzed Coupling Processes: The Chemistry of Palladium Hydrides Ivory D. Hills and Gregory C. Fu* Department of Chemistry, Massachusetts Institute recently been described in the develop- ment of highly active palladium-based catalysts for cross

  20. FAILURE OF ZIRCALOY-4 SHEET CONTAINING HYDRIDE BLISTERS O.N. Pierron1

    E-Print Network [OSTI]

    Motta, Arthur T.

    FAILURE OF ZIRCALOY-4 SHEET CONTAINING HYDRIDE BLISTERS O.N. Pierron1 , D.A. Koss1 , A.T. Motta2 , R.S. Daum3 , and K.S. Chan4 1 Dept. Materials Science and Engineering, Penn State Univ., University Park, PA 16802 2 Dept. Mechanical and Nuclear Engineering, Penn State University, University Park, PA

  1. INFLUENCE OF HYDRIDE MICROSTRUCTURE ON THROUGH-THICKNESS CRACK GROWTH IN ZIRCALOY-4 SHEET

    E-Print Network [OSTI]

    Motta, Arthur T.

    1 INFLUENCE OF HYDRIDE MICROSTRUCTURE ON THROUGH-THICKNESS CRACK GROWTH IN ZIRCALOY-4 SHEET P. A and Engineering, The Pennsylvania State University, University Park, PA 16802 2 Department of Mechanical and Nuclear Engineering, The Pennsylvania State University, University Park, PA 16802 3 Southwest Research

  2. The influence of hydride blisters on the fracture of Zircaloy-4 O.N. Pierron a

    E-Print Network [OSTI]

    Motta, Arthur T.

    The influence of hydride blisters on the fracture of Zircaloy-4 O.N. Pierron a , D.A. Koss a,*, A.T. Motta b , K.S. Chan c a Department of Materials Science and Engineering, Pennsylvania State University Engineering, Pennsylvania State University, University Park, PA 16802, USA c Southwest Research Institute, San

  3. Friction Stir Welding of Hydrided Titanium Alloys Mark Taylor, D.P. Field

    E-Print Network [OSTI]

    Collins, Gary S.

    Friction Stir Welding of Hydrided Titanium Alloys Mark Taylor, D.P. Field Multi-Scale Engineering for Undergraduates program under grant number EEC-0754370 During Friction Stir Welding (FSW), a non-consumable tool-state welding process, much frictional heating and force is required of the tool. This steep demand on the tool

  4. Model for the Prediction of the Hydriding Thermodynamics of Pd-Rh-Co Ternary Alloys

    SciTech Connect (OSTI)

    Teter, D.F.; Thoma, D.J.

    1999-03-01

    A dilute solution model (with respect to the substitutional alloying elements) has been developed, which accurately predicts the hydride formation and decomposition thermodynamics and the storage capacities of dilute ternary Pd-Rh-Co alloys. The effect of varying the rhodium and cobalt compositions on the thermodynamics of hydride formation and decomposition and hydrogen capacity of several palladium-rhodium-cobalt ternary alloys has been investigated using pressure-composition (PC) isotherms. Alloying in the dilute regime (<10 at.%) causes the enthalpy for hydride formation to linearly decrease with increasing alloying content. Cobalt has a stronger effect on the reduction in enthalpy than rhodium for equivalent alloying amounts. Also, cobalt reduces the hydrogen storage capacity with increasing alloying content. The plateau thermodynamics are strongly linked to the lattice parameters of the alloys. A near-linear dependence of the enthalpy of hydride formation on the lattice parameter was observed for both the binary Pd-Rh and Pd-Co alloys, as well as for the ternary Pd-Rh-Co alloys. The Pd-5Rh-3Co (at. %) alloy was found to have similar plateau thermodynamics as a Pd-10Rh alloy, however, this ternary alloy had a diminished hydrogen storage capacity relative to Pd-10Rh.

  5. First Principles Studies of Phase Stability and Reaction Dynamics in Complex Metal Hydrides

    SciTech Connect (OSTI)

    Chou, Mei-Yin

    2014-09-29

    Complex metal hydrides are believed to be one of the most promising materials for developing hydrogen storage systems that can operate under desirable conditions. At the same time, these are also a class of materials that exhibit intriguing properties. We have used state-of-the-art computational techniques to study the fundamental properties of these materials.

  6. First-row hydrides: Dissociation and ground state energies using quantum Monte Carlo

    E-Print Network [OSTI]

    Anderson, James B.

    First-row hydrides: Dissociation and ground state energies using quantum Monte Carlo Arne Lu, Pennsylvania 16802 Received 20 May 1996; accepted 24 July 1996 Accurate ground state energies comparable FN-DQMC method. The residual energy, the nodal error due to the error in the nodal structure

  7. Internal hydriding in irradiated defected Zircaloy fuel rods: A review (LWBR Development Program)

    SciTech Connect (OSTI)

    Clayton, J C

    1987-10-01

    Although not a problem in recent commercial power reactors, including the Shippingport Light Water Breeder Reactor, internal hydriding of Zircaloy cladding was a persistent cause of gross cladding failures during the 1960s. It occurred in the fuel rods of water-cooled nuclear power reactors that had a small cladding defect. This report summarizes the experimental findings, causes, mechanisms, and methods of minimizing internal hydriding in defected Zircaloy-clad fuel rods. Irradiation test data on the different types of defected fuel rods, intentionally fabricated defected and in-pile operationally defected rods, are compared. Significant factors affecting internal hydriding in defected Zircaloy-clad fuel rods (defect hole size, internal and external sources of hydrogen, Zircaloy cladding surface properties, nickel alloy contamination of Zircaloy, the effect of heat flux and fluence) are discussed. Pertinent in-pile and out-of-pile test results from Bettis and other laboratories are used as a data base in constructing a qualitative model which explains hydrogen generation and distribution in Zircaloy cladding of defected water-cooled reactor fuel rods. Techniques for minimizing internal hydride failures in Zircaloy-clad fuel rods are evaluated.

  8. ANALYSIS OF THE ELECTRON EXCITATION SPECTRA IN HEAVY RARE EARTH METALS, HYDRIDES AND OXIDES

    E-Print Network [OSTI]

    Boyer, Edmond

    397 ANALYSIS OF THE ELECTRON EXCITATION SPECTRA IN HEAVY RARE EARTH METALS, HYDRIDES AND OXIDES C thin evaporated foils of heavy rare earths (Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu) in three different chemical of high energy incident electrons (75 keV) transmitted through thin foils of yttric rare earth elements

  9. Preparation of Prototypic Irradiated Hydrided-Zircaloy Cladding for UFDC Programs

    SciTech Connect (OSTI)

    Ott, Larry J [ORNL] [ORNL; Howard, Richard H [ORNL] [ORNL; Howard, Rob L [ORNL] [ORNL; McDuffee, Joel Lee [ORNL] [ORNL; Yan, Yong [ORNL] [ORNL

    2013-01-01

    The DOE Used Fuel Disposition Campaign (UFDC) has tasked ORNL to investigate the behavior of light-water-reactor fuel cladding material performance related to extended storage and transportation of used fuel. Fast neutron irradiation of pre-hydrided zirconium-alloy cladding in the High Flux Isotope Reactor (HFIR) at elevated temperatures has been used to simulate the effects of high burnup on used fuel cladding for use in understanding the materials properties relevant to very long-term storage (VLTS) and subsequent transportation. The irradiated pre-hydrided metallic materials will generate baseline data to benchmark hot-cell testing of high-burnup used fuel cladding; and, more importantly, samples free of alpha contamination can be provided to the researchers who do not have hot cell facilities to handle highly contaminated high-burnup used fuel cladding to support their research projects for the UFDC. In order to accomplish this research, ORNL has produced unirradiated zirconium-based cladding tubes with a certain hydrogen concentration. Two capsules (HYCD-1 and HYCD-2) containing hydrided zirconium-based samples, 9.50 mm (0.374 in) in diameter, were inserted in HFIR for neutron irradiation. HYCD-1 was removed after Cycle 440B and HYCD-2 after Cycle 442. This paper will describe the general HYCD experiment configuration, achieved temperatures, and temperature gradients within the cladding, and current results of the PIE of the irradiated hydrided cladding samples.

  10. PACKING TRIANGLES ON A SPHERE ISAAC OTTONI WILHELM

    E-Print Network [OSTI]

    May, J. Peter

    a more general procedure that we call the Windmill Algorithm for packing equilateral triangles onto a sphere. In Section 4 we prove several facts about the Windmill Algorithm and use those facts to prove

  11. FOR THE RECORD RosettaHoles2: A volumetric packing

    E-Print Network [OSTI]

    Baker, David

    FOR THE RECORD RosettaHoles2: A volumetric packing measure for protein structure refinement volumetric in nature. However, the total cavity volume is not a good dis- criminator between computational

  12. URANIUM METAL POWDER PRODUCTION, PARTICLE DISTRIBUTION ANALYSIS, AND REACTION RATE STUDIES OF A HYDRIDE-DEHYDRIDE PROCESS 

    E-Print Network [OSTI]

    Sames, William

    2011-08-08

    Work was done to study a hydride-dehydride method for producing uranium metal powder. Particle distribution analysis was conducted using digital microscopy and grayscale image analysis software. The particle size was found ...

  13. Thermal analysis of uranium zirconium hydride fuel using a lead-bismuth gap at LWR operating temperatures

    E-Print Network [OSTI]

    Ensor, Brendan M. (Brendan Melvin)

    2012-01-01

    Next generation nuclear technology calls for more advanced fuels to maximize the effectiveness of new designs. A fuel currently being studied for use in advanced light water reactors (LWRs) is uranium zirconium hydride ...

  14. Performance characterization of a packed bed electro-filter 

    E-Print Network [OSTI]

    Narayanan, Ajay

    1990-01-01

    PERFORMANCE CHARACTERIZATION OF A PACKED BED ELECTRO-FILTER A Thesis by A JAY NARAYANAN Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE... December 1990 Major Subject: Safety Engineering PERFORMANCE CHARACTERIZATION OF A PACKED BED ELECTRO-FILTER A Thesis by AJAY NARAYANAN Approved as to style and content by: John P. Wagn (Ch ' of the Com ittee) Aydin Akgerman (Member) Ri ard B...

  15. The influence of surface morphology and oxide microstructure on the nucleation and growth of uranium hydride on alpha uranium

    SciTech Connect (OSTI)

    Hanrahan, R.J. Jr.; Hawley, M.E.; Brown, G.W.

    1998-12-31

    While the bulk kinetics of the uranium-hydrogen reaction are well understood, the mechanisms underlying the initial nucleation of uranium hydride on uranium remain controversial. In this study, the authors have employed environmental cell optical microscopy, Scanning Electron Microscopy (SEM) and Atomic Force Microscopy, (AFM) in an attempt to relate the structure of the surface and the microstructure of the substrate with the susceptibility and site of hydride nucleation. Samples have been investigated with varying grain size, inclusion (carbide) concentration, and thermal history. There is a clear correlation to heat treatment immediately prior to hydrogen exposure. Susceptibility to hydride formation also appears to be related to impurities in the uranium. The oxidized surface is very complex, exhibiting wide variations in thickness and topography between samples, between grains in the same sample, and within individual grains. It is, however, very difficult to relate this fine scale variability to the relatively sparse hydride initiation sites. Therefore, the surface oxide layer itself does not appear to control the sites where hydride attack is initiated, although it must play a role in the induction period prior to hydride initiation.

  16. Fast, Quantitative, and Nondestructive Evaluation on Hydrided LWR Fuel Cladding by Small Angle Incoherent Neutron Scattering of Hydrogen

    SciTech Connect (OSTI)

    Yan, Yong; Qian, Shuo; Littrell, Ken; Parish, Chad M; Plummer, Lee K

    2015-01-01

    A non-destructive neutron scattering method to precisely measure the uptake of hydrogen and the distribution of hydride precipitates in light water reactor (LWR) fuel cladding was developed. Zircaloy-4 cladding used in commercial LWRs was used to produce hydrided specimens. The hydriding apparatus consists of a closed stainless steel vessel that contains Zr alloy specimens and hydrogen gas. Following hydrogen charging, the hydrogen content of the hydrided specimens was measured using the vacuum hot extraction method, by which the samples with desired hydrogen concentration were selected for the neutron study. Optical microscopy shows that our hydriding procedure results in uniform distribution of circumferential hydrides across the wall. Small angle neutron incoherent scattering was performed in the High Flux Isotope Reactor at Oak Ridge National Laboratory. Our study demonstrates that the hydrogen in commercial Zircaloy-4 cladding can be measured very accurately in minutes by this nondestructive method over a wide range of hydrogen concentrations from a very small amount ( 20 ppm) to over 1000 ppm. The hydrogen distribution in a tube sample was obtained by scaling the neutron scattering rate with a factor determined by a calibration process using standard, destructive direct chemical analysis methods on the specimens. This scale factor can be used in future tests with unknown hydrogen concentrations, thus providing a nondestructive method for absolute hydrogen concentration determination.

  17. Using magnetization measurements to detect small amounts of plutonium hydride formation in plutonium metal

    SciTech Connect (OSTI)

    Kim, Jae Wook [Rutgers Univ., New Brunswick, NJ (United States); Mielke, Charles H. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Zapf, Vivien [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Baiardo, Joseph P. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Mitchell, Jeremy N. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Richmond, Scott [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Schwartz, Daniel S. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Mun, Eun D. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Smith, Alice Iulia [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2014-10-20

    We report the formation of plutonium hydride in 2 at % Ga-stabilized ?-Pu, with 1 atomic % H charging. We show that magnetization measurements are a sensitive, quantitative measure of ferromagnetic plutonium hydride against the nonmagnetic background of plutonium. It was previously shown that at low hydrogen concentrations, hydrogen forms super-abundant vacancy complexes with plutonium, resulting in a bulk lattice contraction. Here we use magnetization, X-ray and neutron diffraction measurements to show that in addition to forming vacancy complexes, at least 30% of the H atoms bond with Pu to precipitate PuHx, largely on the surface of the sample with x ~ 1.9. We observe magnetic hysteresis loops below 40 K with magnetic remanence, consistent with precipitates of ferromagnetic PuH1.9.

  18. Method to predict relative hydriding within a group of zirconium alloys under nuclear irradiation

    DOE Patents [OSTI]

    Johnson, A.B. Jr.; Levy, I.S.; Trimble, D.J.; Lanning, D.D.; Gerber, F.S.

    1990-04-10

    An out-of-reactor method for screening to predict relative in-reactor hydriding behavior of zirconium-based materials is disclosed. Samples of zirconium-based materials having different compositions and/or fabrication methods are autoclaved in a relatively concentrated (0.3 to 1.0M) aqueous lithium hydroxide solution at constant temperatures within the water reactor coolant temperature range (280 to 316 C). Samples tested by this out-of-reactor procedure, when compared on the basis of the ratio of hydrogen weight gain to oxide weight gain, accurately predict the relative rate of hydriding for the same materials when subject to in-reactor (irradiated) corrosion. 1 figure.

  19. High Resolution Neutron Radiography and Tomography of Hydrided Zircaloy-4 Cladding Materials

    SciTech Connect (OSTI)

    Smith, Tyler S; Bilheux, Hassina Z; Ray, Holly B; Bilheux, Jean-Christophe; Yan, Yong

    2015-01-01

    Neutron radiography for hydrogen analysis was performed with several Zircaloy-4 cladding samples with controlled hydrogen concentrations up to 1100 ppm. Hydrogen charging was performed in a process tube that was heated to facilitate hydrogen absorption by the metal. A correlation between the hydrogen concentration in the hydrided tubes and the neutron intensity was established, by which hydrogen content can be determined precisely in a small area (55 m x 55 m). Radiography analysis was also performed to evaluate the heating rate and its correlation with the hydrogen distribution through hydrided materials. In addition to radiography analysis, tomography experiments were performed on Zircaloy-4 tube samples to study the local hydrogen distribution. Through tomography analysis a 3D reconstruction of the tube was evaluated in which an uneven hydrogen distribution in the circumferential direction can be observed.

  20. Use of Solid Hydride Fuel for Improved long-Life LWR Core Designs

    SciTech Connect (OSTI)

    Greenspan, E

    2006-04-30

    The primary objective of this project was to assess the feasibility of improving the performance of PWR and BWR cores by using solid hydride fuels instead of the commonly used oxide fuel. The primary measure of performance considered is the bus-bar cost of electricity (COE). Additional performance measures considered are safety, fuel bundle design simplicity – in particular for BWR’s, and plutonium incineration capability. It was found that hydride fuel can safely operate in PWR’s and BWR’s without restricting the linear heat generation rate of these reactors relative to that attainable with oxide fuel. A couple of promising applications of hydride fuel in PWR’s and BWR’s were identified: (1) Eliminating dedicated water moderator volumes in BWR cores thus enabling to significantly increase the cooled fuel rods surface area as well as the coolant flow cross section area in a given volume fuel bundle while significantly reducing the heterogeneity of BWR fuel bundles thus achieving flatter pin-by-pin power distribution. The net result is a possibility to significantly increase the core power density – on the order of 30% and, possibly, more, while greatly simplifying the fuel bundle design. Implementation of the above modifications is, though, not straightforward; it requires a design of completely different control system that could probably be implemented only in newly designed plants. It also requires increasing the coolant pressure drop across the core. (2) Recycling plutonium in PWR’s more effectively than is possible with oxide fuel by virtue of a couple of unique features of hydride fuel – reduced inventory of U-238 and increased inventory of hydrogen. As a result, the hydride fuelled core achieves nearly double the average discharge burnup and the fraction of the loaded Pu it incinerates in one pass is double that of the MOX fuel. The fissile fraction of the Pu in the discharged hydride fuel is only ~2/3 that of the MOX fuel and the discharged hydride fuel is more proliferation resistant. Preliminary feasibility assessment indicates that by replacing some of the ZrH1.6 by ThH2 it will be possible to further improve the plutonium incineration capability of PWR’s. Other possibly promising applications of hydride fuel were identified but not evaluated in this work. A number of promising oxide fueled PWR core designs were also found as spin-offs of this study: (1) The optimal oxide fueled PWR core design features smaller fuel rod diameter of D=6.5 mm and a larger pitch-to-diameter ratio of P/D=1.39 than presently practiced by industry – 9.5mm and 1.326. This optimal design can provide a 30% increase in the power density and a 24% reduction in the cost of electricity (COE) provided the PWR could be designed to have the coolant pressure drop across the core increased from the reference 29 psia to 60 psia. (2) Using wire wrapped oxide fuel rods in hexagonal fuel assemblies it is possible to design PWR cores to operate at 54% higher power density than the reference PWR design that uses grid spacers and a square lattice, provided 60 psia coolant pressure drop across the core could be accommodated. Uprating existing PWR’s to use such cores could result in 40% reduction in the COE. The optimal lattice geometry is D = 8.08 mm and P/D = 1.41. The most notable advantages of wire wraps over grid spacers are their significant lower pressure drop, higher critical heat flux and improved vibrations characteristics.

  1. Synthesis, NMR spectra, and structure of rhodium hydride complexes with Rh-Sn bonds

    SciTech Connect (OSTI)

    Krut'ko, B.P.; Permin, A.B.; Petrosyan, V.S.; Reutov, O.A.

    1985-06-20

    The authors study the hydride complexes using Sn 119 and H 1 NMR spectroscopy. The spectra were taken in a pulse mode on a Varian FT-80A spectrometer equipped with a wideband system at 29.66 and 79.54 MHz. The Sn 119 and H 1 NMR spectral parameters for a solution of the complex (Bu/sub 4/N)/sub 3/ (HRh(SnCl/sub 3/)/sub 5/) in CD/sub 3/CN are shown, the spectra show that the (HRh(SnCl/sub 3/)/sub 5/)/sup 3 -/ anion has octahedral structure with four equatorial and one axial Rh-Sn bonds. New rhodium hydride complexes with general formula (R/sub 4/N)/sub 3/(HRh(SnCl/sub 3/)/sub 5/) were synthesized.

  2. Engineering of the band gap and optical properties of thin films of yttrium hydride

    SciTech Connect (OSTI)

    You, Chang Chuan; Mongstad, Trygve; Maehlen, Jan Petter; Karazhanov, Smagul, E-mail: smagulk@ife.no [Institute for Energy Technology, P.O. Box 40, NO-2027 Kjeller (Norway)

    2014-07-21

    Thin films of oxygen-containing yttrium hydride show photochromic effect at room temperature. In this work, we have studied structural and optical properties of the films deposited at different deposition pressures, discovering the possibility of engineering the optical band gap by variation of the oxygen content. In sum, the transparency of the films and the wavelength range of photons triggering the photochromic effect can be controlled by variation of the deposition pressure.

  3. Venkat Srinivasan John W. Weidner Ralph E. White Mathematical models of the nickel hydroxide active material

    E-Print Network [OSTI]

    -cadmium, nickel-metal hydride, nickel-zinc, and nickel-hydrogen batteries [1]. However, even after a century. The negative electrode used in the cell could be a porous cadmium, metal hydride, zinc, or gas-fed hydrogen Á R.E. White (&) Department of Chemical Engineering, Swearingen Engineering Building, University

  4. OPTIMIZATION OF INTERNAL HEAT EXCHANGERS FOR HYDROGEN STORAGE TANKS UTILIZING METAL HYDRIDES

    SciTech Connect (OSTI)

    Garrison, S.; Tamburello, D.; Hardy, B.; Anton, D.; Gorbounov, M.; Cognale, C.; van Hassel, B.; Mosher, D.

    2011-07-14

    Two detailed, unit-cell models, a transverse fin design and a longitudinal fin design, of a combined hydride bed and heat exchanger are developed in COMSOL{reg_sign} Multiphysics incorporating and accounting for heat transfer and reaction kinetic limitations. MatLab{reg_sign} scripts for autonomous model generation are developed and incorporated into (1) a grid-based and (2) a systematic optimization routine based on the Nelder-Mead downhill simplex method to determine the geometrical parameters that lead to the optimal structure for each fin design that maximizes the hydrogen stored within the hydride. The optimal designs for both the transverse and longitudinal fin designs point toward closely-spaced, small cooling fluid tubes. Under the hydrogen feed conditions studied (50 bar), a 25 times improvement or better in the hydrogen storage kinetics will be required to simultaneously meet the Department of Energy technical targets for gravimetric capacity and fill time. These models and methodology can be rapidly applied to other hydrogen storage materials, such as other metal hydrides or to cryoadsorbents, in future work.

  5. Gas Diffusion in Metals: Fundamental Study of Helium-Point Defect Interactions in Iron and Kinetics of Hydrogen Desorption from Zirconium Hydride

    E-Print Network [OSTI]

    Hu, Xunxiang

    2013-01-01

    steel, nickel, iron and zirconium. Nucl. Instrum. MethodsSteinbruck. Hydrogen absorption by zirconium alloys at highHydride formation in zirconium alloys. JOM. 64 R. Yang, O.

  6. Draft of M2 Report on Integration of the Hybrid Hydride Model into INL’s MBM Framework for Review

    SciTech Connect (OSTI)

    Tikare, Veena; Weck, Philippe F.; Schultz, Peter A.; Clark, Blythe; Glazoff, Michael; Homer, Eric

    2014-07-01

    This report documents the development, demonstration and validation of a mesoscale, microstructural evolution model for simulation of zirconium hydride {delta}-ZrH{sub 1.5} precipitation in the cladding of used nuclear fuels that may occur during long-term dry storage. While the Zr-based claddings are manufactured free of any hydrogen, they absorb hydrogen during service, in the reactor by a process commonly termed ‘hydrogen pick-up’. The precipitation and growth of zirconium hydrides during dry storage is one of the most likely fuel rod integrity failure mechanisms either by embrittlement or delayed hydride cracking of the cladding (Hanson et al., 2011). While the phenomenon is well documented and identified as a potential key failure mechanism during long-term dry storage (Birk et al., 2012 and NUREG/CR-7116), the ability to actually predict the formation of hydrides is poor. The model being documented in this work is a computational capability for the prediction of hydride formation in different claddings of used nuclear fuels. This work supports the Used Fuel Disposition Research and Development Campaign in assessing the structural engineering performance of the cladding during and after long-term dry storage. This document demonstrates a basic hydride precipitation model that is built on a recently developed hybrid Potts-phase field model that combines elements of Potts-Monte Carlo and the phase-field models (Homer et al., 2013; Tikare and Schultz, 2012). The model capabilities are demonstrated along with the incorporation of the starting microstructure, thermodynamics of the Zr-H system and the hydride formation mechanism.

  7. ReaxFFMgH Reactive Force Field for Magnesium Hydride Systems Sam Cheung, Wei-Qiao Deng, Adri C. T. van Duin, and William A. Goddard III*

    E-Print Network [OSTI]

    van Duin, Adri

    ReaxFFMgH Reactive Force Field for Magnesium Hydride Systems Sam Cheung, Wei-Qiao Deng, Adri C. T and Chemical Engineering, California Institute of Technology, Pasadena, California 91125 ReceiVed: September 3FFMgH) for magnesium and magnesium hydride systems. The parameters for this force field were derived from fitting

  8. Time-resolved photoluminescence studies of free and donor-bound exciton in GaN grown by hydride vapor phase epitaxy

    E-Print Network [OSTI]

    Time-resolved photoluminescence studies of free and donor-bound exciton in GaN grown by hydride and Electrical and Computer Engineering and Photonics Center, Boston University, Boston, Massachusetts, 02215 R in unintentionally doped GaN grown by hydride vapor phase epitaxy. Low temperature (4 K), time-integrated PL spectra

  9. Modifying Carbon Cryogel-Hydride Nanocomposites for H2 Storage Saghar Sepehri, Betzaida Batalla Garca, Aaron Feaver, Qifeng Zhang, and Guozhong Cao

    E-Print Network [OSTI]

    Cao, Guozhong

    Modifying Carbon Cryogel- Hydride Nanocomposites for H2 Storage Saghar Sepehri, Betzaida Batalla García, Aaron Feaver, Qifeng Zhang, and Guozhong Cao Materials Science and Engineering, University resorcinol-formaldehyde CCs as nanoscaffold for hydrides. Ammonia borane (AB), a stable, white, crystalline

  10. Calculation of properties of crystalline lithium hydride using correlated wave function theory S. J. Nolan,1 M. J. Gillan,2,3 D. Alf,2,3,4 N. L. Allan,1 and F. R. Manby1

    E-Print Network [OSTI]

    Alfè, Dario

    Calculation of properties of crystalline lithium hydride using correlated wave function theory S. J, and cohesive energy of lithium hydride are calculated to very high accuracy through a combination of periodic. All calculated properties of lithium hydride and deuteride agree with empirical observations to within

  11. Hydrogen Bonding Increases Packing Density in the Protein Interior

    E-Print Network [OSTI]

    Hydrogen Bonding Increases Packing Density in the Protein Interior David Schell,1,2 Jerry Tsai,1 J System Health Science Center, College Station, Texas 77843-1114 ABSTRACT The contribution of hydrogen to the stability, but experimental studies show that bury- ing polar groups, especially those that are hydrogen

  12. FUTURE POWER GRID INITIATIVE GridPACK: Grid Parallel Advanced

    E-Print Network [OSTI]

    FUTURE POWER GRID INITIATIVE GridPACK: Grid Parallel Advanced Computational Kernels OBJECTIVE The U Pacific Northwest National Laboratory (509) 375-3899 bruce.palmer@pnnl.gov ABOUT FPGI The Future Power and ensure a more secure, efficient and reliable future grid. Building on the Electricity Infrastructure

  13. Geometry and Optimal Packing of Twisted Columns and Filaments

    E-Print Network [OSTI]

    Gregory M. Grason

    2015-01-30

    This review presents recent progress in understanding constraints and consequences of close-packing geometry of filamentous or columnar materials possessing non-trivial textures, focusing in particular on the common motifs of twisted and toroidal structures. The mathematical framework is presented that relates spacing between line-like, filamentous elements to their backbone orientations, highlighting the explicit connection between the inter-filament {\\it metric} properties and the geometry of non-Euclidean surfaces. The consequences of the hidden connection between packing in twisted filament bundles and packing on positively curved surfaces, like the Thomson problem, are demonstrated for the defect-riddled ground states of physical models of twisted filament bundles. The connection between the "ideal" geometry of {\\it fibrations} of curved three-dimensional space, including the Hopf fibration, and the non-Euclidean constraints of filament packing in twisted and toroidal bundles is presented, with a focus on the broader dependence of metric geometry on the simultaneous twisting and folded of multi-filament bundles.

  14. Synopsis: Repulsion Helps Virus Pack DNA APS/Joan Tycko

    E-Print Network [OSTI]

    Smith, Douglas E.

    Synopsis: Repulsion Helps Virus Pack DNA APS/Joan Tycko Repulsive DNA-DNA Interactions Accelerate, and Douglas E. Smith Phys. Rev. Lett. 112, 248101 (2014) Published June 17, 2014 Featured in Physics Editors reported in Physical Review Letters show that, surprisingly, switching the DNA self-interaction from

  15. Local analysis of the history dependence in tetrahedra packings

    E-Print Network [OSTI]

    N. Nirmal Thyagu; Max Neudecker; Matthias Schröter

    2015-01-19

    The mechanical properties of a granular sample can depend on the way the packing was prepared. However, the variables which store this information are often unknown. Here we present an X-ray tomography study of tetrahedra packings prepared with three different tapping strengths. Our main result is that the relative contribution of the three different contact types possible between tetrahedra -- face-to-face (F2F), edge-to-face (E2F), and point contacts -- is one variable which stores the preparation history. We show this by preparing pairs of packings that differ either in their bulk volume fraction $\\phi_{global}$ or in their number of mechanical constraints per particle $C$, where $C$ is determined from all three contact types which each fix a different amount of constraints. For the pairs with the same $\\phi_{global}$ the number of E2F and point contacts varies with preparation, while the number of F2F contacts stays constant. For the iso-constraint packings the relative contribution of all three contact types stays the same. We then perform a local analysis of the contact distribution by grouping the particles together according to their individual volume fraction $\\phi_{local}$ computed from a Voronoi tessellation. We find that the probability distribution of $\\phi_{local}$ depends only on $\\phi_{global}$, not on $C$. The number of F2F and E2F contacts increases in all experiments with $\\phi_{local}$; the number of point contacts, while always being the largest, decreases with $\\phi_{local}$. However, only the number of F2F contacts can be described by an universal function of $\\phi_{local}$. This behavior differs from spheres and ellipsoids and posses a significant constraint for any mean-field approach to tetrahedra packings.

  16. Mechanistic study of the isotopic-exchange reaction between gaseous hydrogen and palladium hydride powder

    SciTech Connect (OSTI)

    Outka, D.A.; Foltz, G.W. (Sandia National Labs., Livermore, CA (USA))

    1991-07-01

    A detailed mechanism for the isotopic-exchange reaction between gaseous hydrogen and solid palladium hydride is developed which extends previous model for this reaction by specifically including surface reactions. The modeling indicates that there are two surface-related processes that contribute to the overall rate of exchange: the desorption of hydrogen from the surface and the exchange between surface hydrogen and bulk hydrogen. This conclusion is based upon measurements examining the effect of small concentrations of carbon monoxide were helpful in elucidating the mechanism. Carbon monoxide reversibly inhibits certain steps in the exchange; this slows the overall rate of exchange and changes the distribution of products from the reactor.

  17. Metal hydrides as electrode/catalyst materials for oxygen evolution/reduction in electrochemical devices

    DOE Patents [OSTI]

    Bugga, Ratnakumar V. (Arcadia, CA); Halpert, Gerald (Pasadena, CA); Fultz, Brent (Pasadena, CA); Witham, Charles K. (Pasadena, CA); Bowman, Robert C. (La Mesa, CA); Hightower, Adrian (Whittier, CA)

    1997-01-01

    An at least ternary metal alloy of the formula, AB.sub.(5-Y)X(.sub.y), is claimed. In this formula, A is selected from the rare earth elements, B is selected from the elements of groups 8, 9, and 10 of the periodic table of the elements, and X includes at least one of the following: antimony, arsenic, and bismuth. Ternary or higher-order substitutions, to the base AB.sub.5 alloys, that form strong kinetic interactions with the predominant metals in the base metal hydride are used to form metal alloys with high structural integrity after multiple cycles of hydrogen sorption.

  18. Measurements of Ionic Structure in Shock Compressed Lithium Hydride from Ultrafast X-Ray Thomson Scattering

    SciTech Connect (OSTI)

    Kritcher, A. L. [L-399, Lawrence Livermore National Laboratory, P.O. Box 808, Livermore, California 94551 (United States); Department of Nuclear Engineering, University of California Berkeley, Berkeley, California 94709 (United States); Neumayer, P.; Doeppner, T.; Landen, O. L.; Glenzer, S. H. [L-399, Lawrence Livermore National Laboratory, P.O. Box 808, Livermore, California 94551 (United States); Brown, C. R. D. [Department of Physics, Imperial College, London SW7 2AZ (United Kingdom); AWE plc., Aldermaston, Reading, RG7 4PR (United Kingdom); Davis, P. [L-399, Lawrence Livermore National Laboratory, P.O. Box 808, Livermore, California 94551 (United States); Department of Physics, University of California Berkeley, Berkeley, California 94709 (United States); Falcone, R. W.; Lee, H. J. [Department of Physics, University of California Berkeley, Berkeley, California 94709 (United States); Gericke, D. O.; Vorberger, J.; Wuensch, K. [CFSA, Department of Physics, University of Warwick, Coventry CV4 7AL (United Kingdom); Gregori, G. [Department of Physics, Oxford University, Oxford OX1 3PU (United Kingdom); Holst, B.; Redmer, R. [Universitaet Rostock, Institut fuer Physik, D-18051 Rostock (Germany); Morse, E. C. [Department of Nuclear Engineering, University of California Berkeley, Berkeley, California 94709 (United States); Pelka, A.; Roth, M. [Institut fuer Kernphysik, Technische Universitaet Darmstadt, Darmstadt (Germany)

    2009-12-11

    We present the first ultrafast temporally, spectrally, and angularly resolved x-ray scattering measurements from shock-compressed matter. The experimental spectra yield the absolute elastic and inelastic scattering intensities from the measured density of free electrons. Laser-compressed lithium-hydride samples are well characterized by inelastic Compton and plasmon scattering of a K-alpha x-ray probe providing independent measurements of temperature and density. The data show excellent agreement with the total intensity and structure when using the two-species form factor and accounting for the screening of ion-ion interactions.

  19. Method and apparatus for storing hydrogen isotopes. [stored as uranium hydride in a block of copper

    DOE Patents [OSTI]

    McMullen, J.W.; Wheeler, M.G.; Cullingford, H.S.; Sherman, R.H.

    1982-08-10

    An improved method and apparatus for storing isotopes of hydrogen (especially tritium) are provided. The hydrogen gas is stored as hydrides of material (for example uranium) within boreholes in a block of copper. The mass of the block is critically important to the operation, as is the selection of copper, because no cooling pipes are used. Because no cooling pipes are used, there can be no failure due to cooling pipes. And because copper is used instead of stainless steel, a significantly higher temperature can be reached before the eutectic formation of uranium with copper occurs, (the eutectic of uranium with the iron in stainless steel forms at a significantly lower temperature).

  20. Complex Hydrides-A New Frontier for Future Energy Applications | The Ames

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would like submit the following commentsMethods for Estimating:ILaboratory Hydrides-A New

  1. Piston ring pack design effects on production spark ignition engine oil consumption : a simulation analysis

    E-Print Network [OSTI]

    Senzer, Eric B

    2007-01-01

    One of the most significant contributors to an engine's total oil consumption is the piston ring-pack. As a result, optimization of the ring pack is becoming more important for engine manufacturers and lubricant suppliers. ...

  2. Effects of lubricant viscosity and surface texturing on ring-pack performance in internal combustion engines

    E-Print Network [OSTI]

    Takata, Rosalind (Rosalind Kazuko), 1978-

    2006-01-01

    The piston ring-pack contributes approximately 25% of the mechanical losses in an internal combustion engine. Both lubricant viscosity and surface texturing were investigated in an effort to reduce this ring-pack friction ...

  3. Modeling the lubrication of the piston ring pack in internal combustion engines using the deterministic method

    E-Print Network [OSTI]

    Chen, Haijie

    2011-01-01

    Piston ring packs are used in internal combustion engines to seal both the high pressure gas in the combustion chamber and the lubricant oil in the crank case. The interaction between the piston ring pack and the cylinder ...

  4. The effect of surface finish on piston ring-pack performance in advanced reciprocating engine systems

    E-Print Network [OSTI]

    Jocsak, Jeffrey (Jeffrey Alan)

    2005-01-01

    Frictional losses in the piston ring-pack of an engine account for approximately 20% of the total frictional losses within an engine. Methods of surface texture optimization were investigated to reduce piston ring-pack ...

  5. Real Time (20 Second) Data Base Single Loop (Packed into 3 bytes)

    E-Print Network [OSTI]

    ) Data Base Single Loop (Packed into 3 bytes) ------------------------------------------- Data Element;------------------------------------------------------------------------- --- Real Time (20 Second) Data Base Station (Packed into 3 bytes Loops | 3 | [0]|Data Present, 0=No Data | |Scan Cnt| 11 | [0]|

  6. The effects of phosphorous donor ligand substitution on the reactivity of anionic group 6 transition metal carbonyl hydrides 

    E-Print Network [OSTI]

    Lusk, Richard Jay

    1986-01-01

    in THP, followed by protonation with methanol, gave rise to a new group of chromium and tungsten hydrides, 7 HM(CO) P . The importance of the P-substituted hydr ides is enhanced 4 reactivity as well as the possibility of selective hydride transfer... reduction products were thus benzyl alcohol and octane. Initial GC runs were undertaken using THF solutions of benzyl alcohol of three different concentrations, corresponding to yields of 25, 100, and 150$. Each of the three also contained an equivalent...

  7. New packing in absorption systems for trapping benzene from coke-oven gas

    SciTech Connect (OSTI)

    V.V. Grabko; V.M. Li; T.A. Shevchenko; M.A. Solov'ev

    2009-07-15

    The efficiency of benzene removal from coke-oven gas in absorption units OAO Alchevskkoks with new packing is assessed.

  8. Computer modeling approach for microsphere-packed bone scaffold Pallavi Lal, Wei Sun*

    E-Print Network [OSTI]

    Sun, Wei

    bone graft [5,6], for structural and human cellular assessment of scaffolds for bone repair [7 modeling approach for constructing a three-dimensional microsphere-packed bone graft structure is presented packing model to determine the number of microspheres packed in a synthesized bone graft. The pore size

  9. Vacuum packing: a model system for laboratory-scale silage fermentations

    E-Print Network [OSTI]

    Griffith, Gareth

    Vacuum packing: a model system for laboratory-scale silage fermentations H.E. Johnson1 , R.J. Merry, M.K. THEODOROU AND G.W. GRIFFITH. 2004. Aims: To determine the utility of vacuum-packed polythene (as assessed by pH measurement) occurred in glass tube and vacuum-packed silos over a 35-day period

  10. Design of a Lithium-ion Battery Pack for PHEV Using a Hybrid Optimization Method

    E-Print Network [OSTI]

    Papalambros, Panos

    Design of a Lithium-ion Battery Pack for PHEV Using a Hybrid Optimization Method Nansi Xue1 Abstract This paper outlines a method for optimizing the design of a lithium-ion battery pack for hy- brid, volume or material cost. Keywords: Lithium-ion, Optimization, Hybrid vehicle, Battery pack design

  11. Estimates of the optimal density of sphere packings in high dimensions

    E-Print Network [OSTI]

    Stillinger, Frank

    though existing upper bounds suggest that such improve­ ment should be possible. Using a statistical in digital communications and storage. 12 Physicists have investigated sphere packings in high dimensions theory. 4,5,12,16,17 The packing density or simply density #1; of a sphere packing is the fraction

  12. QccPack: An open-source software library for quantization, compression, and coding

    E-Print Network [OSTI]

    Fowler, James E.

    -message routines. All QccPack functionality is accessible via library calls; additionally, many utility programsPack Web page, is published under the terms of the GNU General Public License and the GNU Library GeneralQccPack: An open-source software library for quantization, compression, and coding James E. Fowler

  13. QccPack: An Open-Source Software Library for Quantization, Compression, and Coding

    E-Print Network [OSTI]

    Fowler, James E.

    Pack functionality is accessible via library calls; additionally, many utility programs provide command-line accessPack software package is published under the terms of the GNU General Public License and the GNU Library GeneralQccPack: An Open-Source Software Library for Quantization, Compression, and Coding James E. Fowler

  14. Frustration and Packing in Curved-Filament Assemblies: From Isometric to Isomorphic Bundles

    E-Print Network [OSTI]

    Gregory M. Grason

    2013-01-21

    Densely-packed bundles of biological filaments (filamentous proteins) are common and critical structural elements in range of biological materials. While most bundles form from intrinsically straight filaments, there are notable examples of protein filaments possessing a natural, or intrinsic, curvature, such as the helical bacterial flagellum. We study the non-linear interplay between thermodynamic preference for dense and regular inter-filament packing and the mechanical preference for uniform filament shape in bundles of helically-curved filaments. Geometric constraints in bundles make perfect inter-filament (constant spacing, or isometric) packing incompatible with perfect intra-filament (constant shape, or isomorphic) packing. As a consequence, we predict that bundle packing exhibits a strong sensitivity to bundle size, evolving from the isometric packing at small radii to an isomorphic packing at large radii. The nature of the transition between these extremal states depends on thermodynamic costs of packing distortion, with packing in elastically-constrained bundles evolving smoothly with size, while packing in osmotically-compressed bundles may exhibit a singular transition from the isometric packing at a finite bundle radius. We consider the equilibrium assembly of bundles in a saturated solution of filaments and show that mechanical cost of isomorphic packing leads to self-limited equilibrium bundle diameters, whose size and range of thermodynamic stability depend both on condensation mechanism, as well as the helical geometry of filaments.

  15. THERMAL ENHANCEMENT CARTRIDGE HEATER MODIFIED TECH MOD TRITIUM HYDRIDE BED DEVELOPMENT PART I DESIGN AND FABRICATION

    SciTech Connect (OSTI)

    Klein, J.; Estochen, E.

    2014-03-06

    The Savannah River Site (SRS) tritium facilities have used 1{sup st} generation (Gen1) LaNi{sub 4.25}Al{sub 0.75} (LANA0.75) metal hydride storage beds for tritium absorption, storage, and desorption. The Gen1 design utilizes hot and cold nitrogen supplies to thermally cycle these beds. Second and 3{sup rd} generation (Gen2 and Gen3) storage bed designs include heat conducting foam and divider plates to spatially fix the hydride within the bed. For thermal cycling, the Gen2 and Gen 3 beds utilize internal electric heaters and glovebox atmosphere flow over the bed inside the bed external jacket for cooling. The currently installed Gen1 beds require replacement due to tritium aging effects on the LANA0.75 material, and cannot be replaced with Gen2 or Gen3 beds due to different designs of these beds. At the end of service life, Gen1 bed desorption efficiencies are limited by the upper temperature of hot nitrogen supply. To increase end-of-life desorption efficiency, the Gen1 bed design was modified, and a Thermal Enhancement Cartridge Heater Modified (TECH Mod) bed was developed. Internal electric cartridge heaters in the new design to improve end-of-life desorption, and also permit in-bed tritium accountability (IBA) calibration measurements to be made without the use of process tritium. Additional enhancements implemented into the TECH Mod design are also discussed.

  16. A Novel Zr-1Nb Alloy and a New Look at Hydriding

    SciTech Connect (OSTI)

    Robert D. Mariani; James I. Cole; Assel Aitkaliyeva

    2013-09-01

    A novel Zr-1Nb has begun development based on a working model that takes into account the hydrogen permeabilities for zirconium and niobium metals. The beta-Nb secondary phase particles (SPPs) in Zr-1Nb are believed to promote more rapid hydrogen dynamics in the alloy in comparison to other zirconium alloys. Furthermore, some hydrogen release is expected at the lower temperatures corresponding to outages when the partial pressure of H2 in the coolant is less. These characteristics lessen the negative synergism between corrosion and hydriding that is otherwise observed in cladding alloys without niobium. In accord with the working model, development of nanoscale precursors was initiated to enhance the performance of existing Zr-1Nb alloys. Their characteristics and properties can be compared to oxide-dispersion strengthened alloys, and material additions have been proposed to zirconium-based LWR cladding to guard further against hydriding and to fix the size of the SPPs for microstructure stability enhancements. A preparative route is being investigated that does not require mechanical alloying, and 10 nanometer molybdenum particles have been prepared which are part of the nanoscale precursors. If successful, the approach has implications for long term dry storage of used fuel and for new routes to nanoferritic and ODS alloys.

  17. Rapid hydrogen gas generation using reactive thermal decomposition of uranium hydride.

    SciTech Connect (OSTI)

    Kanouff, Michael P.; Van Blarigan, Peter; Robinson, David B.; Shugard, Andrew D.; Gharagozloo, Patricia E.; Buffleben, George M.; James, Scott Carlton; Mills, Bernice E.

    2011-09-01

    Oxygen gas injection has been studied as one method for rapidly generating hydrogen gas from a uranium hydride storage system. Small scale reactors, 2.9 g UH{sub 3}, were used to study the process experimentally. Complimentary numerical simulations were used to better characterize and understand the strongly coupled chemical and thermal transport processes controlling hydrogen gas liberation. The results indicate that UH{sub 3} and O{sub 2} are sufficiently reactive to enable a well designed system to release gram quantities of hydrogen in {approx} 2 seconds over a broad temperature range. The major system-design challenge appears to be heat management. In addition to the oxidation tests, H/D isotope exchange experiments were performed. The rate limiting step in the overall gas-to-particle exchange process was found to be hydrogen diffusion in the {approx}0.5 {mu}m hydride particles. The experiments generated a set of high quality experimental data; from which effective intra-particle diffusion coefficients can be inferred.

  18. Close-packed array of light emitting devices

    DOE Patents [OSTI]

    Ivanov, Ilia N.; Simpson, John T.

    2013-04-09

    A close-packed array of light emitting diodes includes a nonconductive substrate having a plurality of elongate channels extending therethrough from a first side to a second side, where each of the elongate channels in at least a portion of the substrate includes a conductive rod therein. The conductive rods have a density over the substrate of at least about 1,000 rods per square centimeter and include first conductive rods and second conductive rods. The close-packed array further includes a plurality of light emitting diodes on the first side of the substrate, where each light emitting diode is in physical contact with at least one first conductive rod and in electrical contact with at least one second conductive rod.

  19. Extensive relativistic calculations on the palladium hydride molecule Merethe Sjo"voll, Hilde Fagerli, Odd Gropen, and Jan Almlofa)

    E-Print Network [OSTI]

    Helgaker, Trygve

    Extensive relativistic calculations on the palladium hydride molecule Merethe Sjo"voll, Hilde to a series of molecules.8 Palladium and palladium compounds are important in catalytic processes of this, there have been relatively few calculations on palladium compounds.10 Essential

  20. In-situ study of hydride precipitation kinetics and re-orientation in Zircaloy using synchrotron radiation

    E-Print Network [OSTI]

    Motta, Arthur T.

    In-situ study of hydride precipitation kinetics and re- orientation in Zircaloy using synchrotron. Banchik4 , P. Vizcaino4 and J. R. Santisteban5 1. Department of Mechanical and Nuclear Engineering, Penn, Argonne, IL, USA 3. Department of Mechanical and Materials Engineering, Queen's University, Kingston, ON

  1. Identification and quantification of hydride phases in Zircaloy-4 cladding using synchrotron X-ray diffraction q

    E-Print Network [OSTI]

    Motta, Arthur T.

    Identification and quantification of hydride phases in Zircaloy-4 cladding using synchrotron X-ray diffraction q R.S. Daum a,1 , Y.S. Chu b,2 , A.T. Motta c,* a Nuclear Engineering Division, Argonne National, IL 60439, United States c Department of Mechanical and Nuclear Engineering, The Pennsylvania State

  2. Verification and Validation Strategy for Implementation of Hybrid Potts-Phase Field Hydride Modeling Capability in MBM

    SciTech Connect (OSTI)

    Jason D. Hales; Veena Tikare

    2014-04-01

    The Used Fuel Disposition (UFD) program has initiated a project to develop a hydride formation modeling tool using a hybrid Potts­phase field approach. The Potts model is incorporated in the SPPARKS code from Sandia National Laboratories. The phase field model is provided through MARMOT from Idaho National Laboratory.

  3. VolPack: A Volume Rendering Library This chapter describes the design of an experimental software library called VolPack. The

    E-Print Network [OSTI]

    Stanford University

    library based on user­defined callback functions for shading and classification. Alterna­ tivelyChapter 8 VolPack: A Volume Rendering Library This chapter describes the design of an experimental software library called VolPack. The library provides a high­performance implementation of the algorithms

  4. Metal Hydrides

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankADVANCED MANUFACTURING OFFICESpecial ReportProposal to changeNovemberEnergyMessage fromMetal

  5. On 2-coverings and 2-packings of laminar families J. Cheriyan T. Jordan y R. Ravi z

    E-Print Network [OSTI]

    Cheriyan, Joseph

    On 2-coverings and 2-packings of laminar families J. Cheriyan T. Jordan y R. Ravi z January 24: laminar family of subsets, 1-covers, 2-covers, 1-packings, 2-packings, NP-hard, approximation algorithm grant CCR{9625297. 1 #12;1 Introduction Coverings and packings of laminar families by edges Let H

  6. Table of Contents: Entropy difference between the face-centred cubic and hexagonal close-packed crystal structures.

    E-Print Network [OSTI]

    Xie, Xiaoliang Sunney

    -packed crystal structures. Silurian hydrothermal-vent community from the southern Urals, Russia. Abstract Recent

  7. Hydride vapor phase GaN films with reduced density of residual electrons and deep traps

    SciTech Connect (OSTI)

    Polyakov, A. Y.; Smirnov, N. B.; Govorkov, A. V.; Yugova, T. G.; Cox, H.; Helava, H.; Makarov, Yu.; Usikov, A. S.

    2014-05-14

    Electrical properties and deep electron and hole traps spectra are compared for undoped n-GaN films grown by hydride vapor phase epitaxy (HVPE) in the regular process (standard HVPE samples) and in HVPE process optimized for decreasing the concentration of residual donor impurities (improved HVPE samples). It is shown that the residual donor density can be reduced by optimization from ?10{sup 17}?cm{sup ?3} to (2–5)?×?10{sup 14}?cm{sup ?3}. The density of deep hole traps and deep electron traps decreases with decreased donor density, so that the concentration of deep hole traps in the improved samples is reduced to ?5?×?10{sup 13}?cm{sup ?3} versus 2.9?×?10{sup 16}?cm{sup ?3} in the standard samples, with a similar decrease in the electron traps concentration.

  8. Reaction kinetics relevant to the recycle hydride-dehydride process for plutonium recovery

    SciTech Connect (OSTI)

    Haschke, J.M.; Allen, T.H.

    1997-10-01

    Objectives of this one-year, Laboratory Directed Research and Development (LDRD) project were the expansion of fundamental knowledge of plutonium chemistry and the development of information for enhancing plutonium recovery methods and weapons safety. Results of kinetic studies demonstrate that the monoxide monohydride, PuO(H), formed during corrosion of plutonium by water in pyrophoric when dry and acts as an initiator for hydride-catalyzed reaction of the metal with air. The catalyzed corrosion rate of Pu is 10{sup 8} times faster than that in dry air and transforms plutonium into a readily aerosolized material. A potential application for the catalytic reaction is in the direct recovery of plutonium as oxide. Wet PuO(H) is non-pyrophoric and the safety hazard posed by its formation is reduced if the material is not allowed to dry.

  9. LaNi{sub 5}-based metal hydride electrode in Ni-MH rechargeable cells

    DOE Patents [OSTI]

    Bugga, R.V.; Fultz, B.; Bowman, R.; Surampudi, S.R.; Witham, C.K.; Hightower, A.

    1999-03-30

    An at least ternary metal alloy of the formula AB{sub (Z-Y)}X{sub (Y)} is disclosed. In this formula, A is selected from the rare earth elements, B is selected from the elements of Groups 8, 9, and 10 of the Periodic Table of the Elements, and X includes at least one of the following: antimony, arsenic, germanium, tin or bismuth. Z is greater than or equal to 4.8 and less than or equal to 6.0. Y is greater than 0 and less than 1. Ternary or higher-order substitutions to the base AB{sub 5} alloys that form strong kinetic interactions with the predominant metals in the base metal hydride are used to form metal alloys with high structural integrity after multiple cycles of hydrogen sorption. 16 figs.

  10. Method to predict relative hydriding within a group of zirconium alloys under nuclear irradiation

    DOE Patents [OSTI]

    Johnson, Jr., A. Burtron (Richland, WA); Levy, Ira S. (Kennewick, WA); Trimble, Dennis J. (Kennewick, WA); Lanning, Donald D. (Kennewick, WA); Gerber, Franna S. (Richland, WA)

    1990-01-01

    An out-of-reactor method for screening to predict relative in-reactor hydriding behavior of zirconium-bsed materials is disclosed. Samples of zirconium-based materials having different composition and/or fabrication are autoclaved in a relatively concentrated (0.3 to 1.0M) aqueous lithium hydroxide solution at constant temperatures within the water reactor coolant temperature range (280.degree. to 316.degree. C.). Samples tested by this out-of-reactor procedure, when compared on the basis of the ratio of hydrogen weight gain to oxide weight gain, accurately predict the relative rate of hyriding for the same materials when subject to in-reactor (irradiated) corrision.

  11. RF sputtering for controlling dihydride and monohydride bond densities in amorphous silicon hydride

    DOE Patents [OSTI]

    Jeffery, F.R.; Shanks, H.R.

    1980-08-26

    A process is described for controlling the dihydride and monohydride bond densities in hydrogenated amorphous silicone produced by reactive rf sputtering of an amorphous silicon target. There is provided a chamber with an amorphous silicon target and a substrate therein with the substrate and the target positioned such that when rf power is applied to the target the substrate is in contact with the sputtering plasma produced thereby. Hydrogen and argon are fed to the chamber and the pressure is reduced in the chamber to a value sufficient to maintain a sputtering plasma therein, and then rf power is applied to the silicon target to provide a power density in the range of from about 7 watts per square inch to about 22 watts per square inch to sputter an amorphous solicone hydride onto the substrate, the dihydride bond density decreasing with an increase in the rf power density. Substantially pure monohydride films may be produced.

  12. Power-law friction in closely-packed granular materials

    E-Print Network [OSTI]

    Takahiro Hatano

    2007-05-08

    In order to understand the nature of friction in closely-packed granular materials, a discrete element simulation on granular layers subjected to isobaric plain shear is performed. It is found that the friction coefficient increases as the power of the shear rate, the exponent of which does not depend on the material constants. Using a nondimensional parameter that is known as the inertial number, the power-law can be cast in a generalized form so that the friction coefficients at different confining pressures collapse on the same curve. We show that the volume fraction also obeys a power-law.

  13. Grain Scale Modeling of Arbitrary Fluid Saturation in Random Packings

    E-Print Network [OSTI]

    Konstantin Melnikov; Roman Mani; Falk K. Wittel; Marcel Thielmann; Hans J. Herrmann

    2015-03-25

    We propose a model for increasing liquid saturation in a granular packing which can account for liquid redistribution at saturation levels beyond the well-studied capillary bridge regime. The model is capable of resolving and combining capillary bridges, menisci and fully saturated pores to form local liquid clusters of any shape. They can exchange volume due to the local Laplace pressure gradient via a liquid film on the surfaces of grains. Local instabilities like Haines jumps trigger the discontinuous evolution of the liquid front. The applicability of the model is demonstrated and compared to benchmark experiments on the level of individual liquid structures as well as on larger systems.

  14. Hydraulically refueled battery employing a packed bed metal particle electrode

    DOE Patents [OSTI]

    Siu, S.C.; Evans, J.W.

    1998-12-15

    A secondary zinc air cell, or another selected metal air cell, employing a spouted/packed metal particle bed and an air electrode is described. More specifically, two embodiments of a cell, one that is capable of being hydraulically recharged, and a second that is capable of being either hydraulically or electrically recharged. Additionally, each cell includes a sloped bottom portion to cause stirring of the electrolyte/metal particulate slurry when the cell is being hydraulically emptied and refilled during hydraulically recharging of the cell. 15 figs.

  15. The anti-perovskite type hydride InPd{sub 3}H{sub 0.89}

    SciTech Connect (OSTI)

    Kohlmann, H.; Skripov, A.V.; Soloninin, A.V.; Udovic, T.J.

    2010-10-15

    Hydrogenation of tetragonal InPd{sub 3} in the ZrAl{sub 3} type structure (four-fold ccp superstructure) yields a hydride with a cubic AuCu{sub 3} type structure (one-fold ccp superstructure). Deuterium can be located by neutron powder diffraction in octahedral voids surrounded exclusively by palladium, [Pd{sub 6}], which are 88.5(6)% occupied in a statistical manner. The resulting deuteride InPd{sub 3}D{sub 0.89} thus crystallizes in a cubic anti-perovskite type structure (space group Pm3-bar m (no. 221), a=402.25(1) pm at 299(2) K). The Pd-D distance of 201.13(1) pm is typical for interstitial hydrides with palladium. Inelastic neutron scattering on the hydride InPd{sub 3}H{sub 0.89}, which shows a spectrum similar to that of binary palladium hydride, confirms the cubic site symmetry of hydrogen in [Pd{sub 6}] interstices. This is also confirmed by the absence of any quadrupole splitting in the {sup 2}D-NMR signal of the deuteride. {sup 1}H NMR spectra of InPd{sub 3}H{sub 0.89} do not show any motional narrowing. Values found for the H jump rate {tau}{sup -1} in InPd{sub 3}H{sub 0.89} remain below 10{sup 6} s{sup -1} in the studied temperature range 28-360 K, indicating a small hydrogen mobility in InPd{sub 3}H{sub 0.8} as compared with binary palladium hydride, PdH{sub {<=}1}. This can be attributed to the large spatial separation of the [Pd{sub 6}] sites. - Graphical abstract: Hydrogen induces a rearrangement in InPd{sub 3} from a ZrAl{sub 3} type structure to a cubic AuCu{sub 3} type structure, thus forming an anti-perovskite type hydride InPd{sub 3}H{sub 0.89}.

  16. Goddard rattler-jamming mechanism for quantifying pressure dependence of elastic moduli of grain packs

    SciTech Connect (OSTI)

    Pride, Steven R.; Berryman, James G.

    2009-01-05

    An analysis is presented to show how it is possible for unconsolidated granular packings to obey overall non-Hertzian pressure dependence due to the imperfect and random spatial arrangements of the grains in these packs. With imperfect arrangement, some gaps that remain between grains can be closed by strains applied to the grain packing. As these gaps are closed, former rattler grains become jammed and new stress-bearing contacts are created that increase the elastic stiffness of the packing. By allowing for such a mechanism, detailed analytical expressions are obtained for increases in bulk modulus of a random packing of grains with increasing stress and strain. Only isotropic stress and strain are considered in this analysis. The model is shown to give a favorable fit to laboratory data on variations in bulk modulus due to variations in applied pressure for bead packs.

  17. Shear modulus and Dilatancy Softening in Granular Packings above Jamming

    E-Print Network [OSTI]

    Corentin Coulais; Antoine Seguin; Olivier Dauchot

    2014-11-07

    We investigate experimentally the mechanical response of a monolayer of bi-disperse frictional grains to an inhomogeneous shear perturbation across the jamming transition. We inflate an intruder inside the packing and use photo-elasticity and tracking techniques to measure the induced shear strain and stresses at the grain scale. We quantify experimentally the constitutive relations for strain amplitudes as low as 0.001 and for a range of packing fractions within 2% variation around the jamming transition. At the transition strong nonlinear effects set in : both the shear modulus and the dilatancy shear-soften at small strain until a critical strain is reached where effective linearity is recovered. The dependencies of the critical strain and the associated critical stresses on the distance from jamming are extracted via scaling analysis. We check that the constitutive laws, when applied to the equations governing mechanical equilibrium, lead to the observed stress and strain profiles. These profiles exhibit a spatial crossover between an effective linear regime close to the inflater and the truly nonlinear regime away from it. The crossover length diverges at the jamming transition.

  18. Method for immobilizing particulate materials in a packed bed

    DOE Patents [OSTI]

    Even, W.R. Jr.; Guthrie, S.E.; Raber, T.N.; Wally, K.; Whinnery, L.L.; Zifer, T.

    1999-02-02

    The present invention pertains generally to immobilizing particulate matter contained in a packed bed reactor so as to prevent powder migration, compaction, coalescence, or the like. More specifically, this invention relates to a technique for immobilizing particulate materials using a microporous foam-like polymer such that (a) the particulate retains its essential chemical nature, (b) the local movement of the particulate particles is not unduly restricted, (c) bulk powder migration and is prevented, (d) physical and chemical access to the particulate is unchanged over time, and (e) very high particulate densities are achieved. The immobilized bed of the present invention comprises a vessel for holding particulate matter, inlet and an outlet ports or fittings, a loosely packed bed of particulate material contained within the vessel, and a three dimensional porous matrix for surrounding and confining the particles thereby fixing the movement of an individual particle to a limited local position. The established matrix is composed of a series of cells or chambers comprising walls surrounding void space, each wall forming the wall of an adjacent cell; each wall containing many holes penetrating through the wall yielding an overall porous structure and allowing useful levels of gas transport. 4 figs.

  19. Method for immobilizing particulate materials in a packed bed

    DOE Patents [OSTI]

    Even, Jr., William R. (Livermore, CA); Guthrie, Stephen E. (Livermore, CA); Raber, Thomas N. (Livermore, CA); Wally, Karl (Lafayette, CA); Whinnery, LeRoy L. (Livermore, CA); Zifer, Thomas (Manteca, CA)

    1999-01-01

    The present invention pertains generally to immobilizing particulate matter contained in a "packed" bed reactor so as to prevent powder migration, compaction, coalescence, or the like. More specifically, this invention relates to a technique for immobilizing particulate materials using a microporous foam-like polymer such that a) the particulate retains its essential chemical nature, b) the local movement of the particulate particles is not unduly restricted, c) bulk powder migration and is prevented, d) physical and chemical access to the particulate is unchanged over time, and e) very high particulate densities are achieved. The immobilized bed of the present invention comprises a vessel for holding particulate matter, inlet and an outlet ports or fittings, a loosely packed bed of particulate material contained within the vessel, and a three dimensional porous matrix for surrounding and confining the particles thereby fixing the movement of individual particle to a limited local position. The established matrix is composed of a series of cells or chambers comprising walls surrounding void space, each wall forming the wall of an adjacent cell; each wall containing many holes penetrating through the wall yielding an overall porous structure and allowing useful levels of gas transport.

  20. Development of Cell/Pack Level Models for Automotive Li-Ion Batteries...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    with Experimental Validation Development of CellPack Level Models for Automotive Li-Ion Batteries with Experimental Validation 2012 DOE Hydrogen and Fuel Cells Program and...

  1. Multi-Node Thermal System Model for Lithium-Ion Battery Packs: Preprint

    SciTech Connect (OSTI)

    Shi, Ying; Smith, Kandler; Wood, Eric; Pesaran, Ahmad

    2015-09-14

    Temperature is one of the main factors that controls the degradation in lithium ion batteries. Accurate knowledge and control of cell temperatures in a pack helps the battery management system (BMS) to maximize cell utilization and ensure pack safety and service life. In a pack with arrays of cells, a cells temperature is not only affected by its own thermal characteristics but also by its neighbors, the cooling system and pack configuration, which increase the noise level and the complexity of cell temperatures prediction. This work proposes to model lithium ion packs thermal behavior using a multi-node thermal network model, which predicts the cell temperatures by zones. The model was parametrized and validated using commercial lithium-ion battery packs. neighbors, the cooling system and pack configuration, which increase the noise level and the complexity of cell temperatures prediction. This work proposes to model lithium ion packs thermal behavior using a multi-node thermal network model, which predicts the cell temperatures by zones. The model was parametrized and validated using commercial lithium-ion battery packs.

  2. Erroneous Wave Functions of Ciuchi et al for Collective Modes in Neutron Production on Metallic Hydride Cathodes

    E-Print Network [OSTI]

    A. Widom; Y. N. Srivastava; L. Larsen

    2012-10-17

    There is a recent comment (Ciuchi et al., 2012) concerning the theory of collective many body effects on the neutron production rates in a chemical battery cathode. Ciuchi et al employ an inverse beta decay expression that contains a two body amplitude. Only one electron and one proton may exist in the Ciuchi et al model initial state wave function. A flaw in their reasoning is that one cannot in reality describe collective many body correlations with only a two particle wave function. One needs very many particles to describe collective effects. In the model wave functions of Ciuchi et al there are no metallic hydrides, there are no cathodes and there are no chemical batteries. Employing a wave function with only one electron and one proton is inadequate for describing collective metallic hydride surface quantum plasma physics in cathodes accurately.

  3. Facile synthesis of Ba1-xKxFe?As? superconductors via hydride route

    SciTech Connect (OSTI)

    Zaikina, Julia V. [Univ. of California at Davis, Davis, CA (United States); Batuk, Maria [Univ. of Antwerp, Antwerp (Belgium); Abakumov, Artem M. [Univ. of Antwerp, Antwerp (Belgium); Navrotsky, Alexandra [Univ. of California at Davis, Davis, CA (United States); Kauzlarich, Susan M. [Univ. of California at Davis, Davis, CA (United States)

    2014-12-03

    We have developed a fast, easy, and scalable synthesis method for Ba1-xKxFe?As? (0 ? x ? 1) superconductors using hydrides BaH? and KH as a source of barium and potassium metals. Synthesis from hydrides provides better mixing and easier handling of the starting materials, consequently leading to faster reactions and/or lower synthesis temperatures. The reducing atmosphere provided by the evolved hydrogen facilitates preparation of oxygen-free powders. By a combination of methods we have shown that Ba1-xKxFe?As? obtained via hydride route has the same characteristics as when it is prepared by traditional solid-state synthesis. Refinement from synchrotron powder X-ray diffraction data confirms a linear dependence of unit cell parameters upon K content as well as the tetragonal to orthorhombic transition at low temperatures for compositions with x < 0.2. Magnetic measurements revealed dome-like dependence of superconducting transition temperature Tc upon K content with a maximum of 38 K for x close to 0.4. Electron diffraction and high-resolution high-angle annular dark-field scanning transmission electron microscopy indicates an absence of Ba/K ordering, while local inhomogeneity in the Ba/K distribution takes place at a scale of several angstroms along [110] crystallographic direction.

  4. Microstructure and hydriding studies of AB/sub 5/ hydrogen storage compounds. Final report

    SciTech Connect (OSTI)

    Goodell, P.D.; Sandrock, G.D.; Huston, E.L.

    1980-01-01

    New data on the microstructure, pressure-composition-temperature, and absorption/desorption kinetics of AB/sub 5/ metal hydrides are presented. The most significant result to emerge from the investigation is that many of the AB/sub 5/ metal hydrides, especially the LaNi/sub 5/ related materials, show instantaneous absorption and desorption response in proportion to the amount of cooling or heating which is provided. Eight categories of materials were studied: reference alloys (LaNi/sub 5/, LaNi/sub 4/ /sub 9/Al/sub 0/ /sub 1/, LaNi/sub 3/Co/sub 2/); Ni second phase particles (LaNi/sub 5/ /sub 67/, LaNi/sub 7/, LaNi/sub 11/ /sub 3/); eutectoid microstructure (SmCo/sub 5/); other second phases (LaNi/sub 3/ /sub 8/Fe/sub 1/ /sub 2/, LaNi/sub 3/ /sub 5/Cr/sub 1/ /sub 5/, LaNi/sub 4/Cr, LaNi/sub 4/Si; LaNi/sub 4/Sn, MNi/sub 4/Sn, MNi/sub 4/ /sub 3/Al/sub 0/ /sub 7/); substitutional elements (LaNi/sub 4/Cu, LaNi/sub 4/ /sub 5/Pd/sub 0/ /sub 5/, LaNi/sub 4/ /sub 7/Sn/sub 0/ /sub 3/, LaNi/sub 4/ /sub 8/C/sub 0/ /sub 2/, MNi/sub 4/ /sub 3/Mn/sub 0/ /sub 7/); surface active elements (LaNi/sub 4/ /sub 8/B/sub 0/ /sub 2/, LaNi/sub 4/ /sub 9/S/sub 0/ /sub 1/, LaNi/sub 4/ /sub 9/Se/sub 0/ /sub 1/); large diameter atom substitutions (Mg/sub 0/ /sub 1/La/sub 0/ /sub 9/Ni/sub 5/, Ca/sub 0/ /sub 2/La/sub 0/ /sub 8/Ni/sub 5/, Sr/sub 0/ /sub 2/La/sub 0/ /sub 8/Ni/sub 5/, Ba/sub 0/ /sub 2/La/sub 0/ /sub 8/Ni/sub 5/); other compositions (LaNi/sub 3/); and Pd plating (electroless plated samples and mechanically alloyed specimens).

  5. Potential use of battery packs from NCAP tested vehicles.

    SciTech Connect (OSTI)

    Lamb, Joshua; Orendorff, Christopher J.

    2013-10-01

    Several large electric vehicle batteries available to the National Highway Traffic Safety Administration are candidates for use in future safety testing programs. The batteries, from vehicles subjected to NCAP crashworthiness testing, are considered potentially damaged due to the nature of testing their associated vehicles have been subjected to. Criteria for safe shipping to Sandia is discussed, as well as condition the batteries must be in to perform testing work. Also discussed are potential tests that could be performed under a variety of conditions. The ultimate value of potential testing performed on these cells will rest on the level of access available to the battery pack, i.e. external access only, access to the on board monitoring system/CAN port or internal electrical access to the battery. Greater access to the battery than external visual and temperature monitoring would likely require input from the battery manufacturer.

  6. Critical-like Features of Stress Response in Frictional Packings

    E-Print Network [OSTI]

    Abdullah Cakir; Leonardo E. Silbert

    2015-02-25

    The mechanical response of static, unconfined, overcompressed face centred cubic, granular arrays is studied using large-scale, discrete element method simulations. Specifically, the stress response due to the application of a localised force perturbation - the Green function technique - is obtained in granular packings generated over several orders of magnitude in both the particle friction coefficient and the applied forcing. We observe crossover behaviour in the mechanical state of the system characterised by the changing nature of the resulting stress response. The transition between anisotropic and isotropic stress response exhibits critical-like features through the identification of a diverging length scale that distinguishes the spatial extent of anisotropic regions from those that display isotropic behaviour. A multidimensional phase diagram is constructed that parameterises the response of the system due to changing friction and force perturbations.

  7. GravitinoPack and decays of supersymmetric metastable particles

    E-Print Network [OSTI]

    Eberl, Helmut

    2015-01-01

    We present the package GravitinoPack that calculates the two- and three-body decays of unstable supersymmetric particles involving the gravitino in the final or initial state. In a previous paper, we already showed results for the gravitino decays into two and three particles. In this paper, we incorporate the processes where an unstable neutralino, stau or stop decays into a gravitino and Standard Model particles. This is the case in gravitino dark matter supersymmetric models, where the gravitino is the lightest SUSY particle. We give instructions for the installation and the use of the package. In the numerical analysis, we discuss various MSSM scenarios. We show that the calculation of all the decay channels and the three-body decay branching ratios is essential for the accurate application of cosmological bounds on these models.

  8. METHOD TO TEST ISOTOPIC SEPARATION EFFICIENCY OF PALLADIUM PACKED COLUMNS

    SciTech Connect (OSTI)

    Heung, L; Gregory Staack, G; James Klein, J; William Jacobs, W

    2007-06-27

    The isotopic effect of palladium has been applied in different ways to separate hydrogen isotopes for many years. At Savannah River Site palladium deposited on kieselguhr (Pd/k) is used in a thermal cycling absorption process (TCAP) to purify tritium for over ten years. The need to design columns for different throughputs and the desire to advance the performance of TCAP created the need to evaluate different column designs and packing materials for their separation efficiency. In this work, columns with variations in length, diameter and metal foam use, were tested using an isotope displacement method. A simple computer model was also developed to calculate the number of theoretical separation stages using the test results. The effects of column diameter, metal foam and gas flow rate were identified.

  9. Tests of isotopic separation efficiency of palladium packed columns

    SciTech Connect (OSTI)

    Heung, L. K.; Staack, G. C.; Klein, J. E.; Jacobs, W. D.

    2008-07-15

    The isotopic effect of palladium has been applied in different ways to separate hydrogen isotopes for many years. At Savannah River Site palladium deposited on kieselguhr (Pd/k) is used in a thermal cycling absorption process (TCAP) to purify tritium for over ten years. The need to design columns for different throughputs and the desire to advance the performance of TCAP created the need to evaluate different column designs and packing materials for their separation efficiency. In this work, columns with variations in length, diameter and metal foam presence were tested using an isotope displacement method. A simple computer model was also developed to calculate the number of theoretical separation stages based on the test results. The effects of column diameter, metal foam presence and gas flow rate were identified. (authors)

  10. Confined polymer nematics: order and packing in a nematic drop

    E-Print Network [OSTI]

    Daniel Svenšek; Gregor Veble; Rudolf Podgornik

    2010-05-04

    We investigate the tight packing of nematic polymers inside a confining hard sphere. We model the polymer {\\sl via} the continuum Frank elastic free energy augmented by a simple density dependent part as well as by taking proper care of the connectivity of the polymer chains when compared with simple nematics. The free energy {\\sl ansatz} is capable of describing an orientational ordering transition within the sample between an isotropic polymer solution and a polymer nematic phase. We solve the Euler-Lagrange equations numerically with the appropriate boundary conditions for the director and density field and investigate the orientation and density profile within a sphere. Two important parameters of the solution are the exact locations of the beginning and the end of the polymer chain. Pending on their spatial distribution and the actual size of the hard sphere enclosure we can get a plethora of various configurations of the chain exhibiting different defect geometry.

  11. Aalborg Universitet Multi-Objective Control of Balancing Systems for Li-Ion Battery Packs

    E-Print Network [OSTI]

    Andreasen, Søren Juhl

    in a e-mobility application. Simulation results demonstrate the technical feasibility of this newlyAalborg Universitet Multi-Objective Control of Balancing Systems for Li-Ion Battery Packs Barreras, R. E. (2014). Multi-Objective Control of Balancing Systems for Li-Ion Battery Packs: A paradigm

  12. ERROR OF THE NETWORK APPROXIMATION FOR DENSELY PACKED COMPOSITES WITH IRREGULAR GEOMETRY

    E-Print Network [OSTI]

    Berlyand, Leonid

    of the effective conductivity of the high contrast, highly packed composites in which inclusions are irregularly in the case of the high contrast, highly packed particulate composites, that is, when the conductivity inclusions is high is particularly relevant to polymer/ceramic composites, because a polymer matrix com

  13. Close-Packed Floating Clusters: Granular Hydrodynamics Beyond the Freezing Point? Baruch Meerson,1

    E-Print Network [OSTI]

    Meerson, Baruch

    Close-Packed Floating Clusters: Granular Hydrodynamics Beyond the Freezing Point? Baruch Meerson,1 a simple explanation for the success of NSGH beyond the freezing point. DOI: 10.1103/PhysRevLett.91 the packing fraction approaches the freezing point value f ' 0:49 (in three dimensions) or 0.69 (in two

  14. The Texas Meat Packing Industry -- Structure, Operational Characteristics, and Competitive Practices 

    E-Print Network [OSTI]

    Dietrich, Raymond A.; Farris, Donald E.

    1976-01-01

    Bulletin] The Texas Meat Packing Industry - Structure, Operational Characteristics, and Competitive Practices Mention of a trademar k'or a proprietary product does not constitute a guarantee or warranty of the product by The Texas Agricultural..., age, or national origin. [Blank Page in Original Bulletin] CONTENT S Page Highlights ................................................... ii Structural Characteristics of the Slaughter Industry ......... 3 Meat Packing Operations...

  15. Parametric On-Line Packing x F. K. Miyazawa y Y. Wakabayashi z

    E-Print Network [OSTI]

    | C. Postal 6176 | 13083-970 | Campinas{SP | Brazil. z Instituto de Matem#19;atica e Estat#19~ao Paulo{SP | Brazil. #12; 1. Strip Packing Problem (SPP): Given a list L of rectangles, and a rectangle, and rectangles of unit dimensions R = (1; 1), called bins, pack the rectangles of L into a minimum number of bins

  16. Chromate transport through columns packed with surfactant-modified zeolite/zero valent iron pellets

    E-Print Network [OSTI]

    Li, Zhaohui

    Chromate transport through columns packed with surfactant-modified zeolite/zero valent iron pellets Chromate transport through columns packed with zeolite/zero valent iron (Z/ZVI) pellets, either untreated originated from chromate sorption onto the HDTMA modified Z/ZVI pellets. Due to dual porosity, the presence

  17. Aalborg Universitet Development of a 400 W High Temperature PEM Fuel Cell Power Pack -Modelling and

    E-Print Network [OSTI]

    Berning, Torsten

    Aalborg Universitet Development of a 400 W High Temperature PEM Fuel Cell Power Pack - Modelling., Korsgaard, A., Nielsen, M. P., & Kær, S. K. (2006). Development of a 400 W High Temperature PEM Fuel Cell Power Pack - Modelling and System Control. Poster session presented at Fuel Cell Seminar 2006 Conference

  18. The Climate Change Action Pack An interactive teaching supplement designed to

    E-Print Network [OSTI]

    Gunawardena, Arunika

    #12;The Climate Change Action Pack An interactive teaching supplement designed to: · Increase the understanding among young Nova Scotians and educators of the science and issues of climate change · Equip Nova at home and in their future workplaces. #12;Climate Change Action Pack printed Mar. 2002 TABLE OF CONTENTS

  19. Simulated Annealing Based Algorithm for the 2D Bin Packing Problem with Impurities

    E-Print Network [OSTI]

    Kochetov, Yuri

    Simulated Annealing Based Algorithm for the 2D Bin Packing Problem with Impurities B. Beisiegel1 real-world problem originating in the steel industry. The bins are inhomogeneous sheets with impurities;Simulated Annealing Based Algorithm for the 2D Bin Packing Problem with Impurities 3 The oriented tree

  20. The Climate Change Action Pack An interactive teaching supplement designed to

    E-Print Network [OSTI]

    Gunawardena, Arunika

    #3: (Backgrounder) Alternative Energy 118 The Atlantic Conference on Alternative Energy Sources 120 at home and in their future workplaces. #12;Climate Change Action Pack printed Mar. 2002 TABLE OF CONTENTS;Climate Change Action Pack printed Mar. 2002 ENERGY SECTION Lesson #1: (Backgrounder) What is Energy? 101

  1. Discovery of Novel Complex Metal Hydrides for Hydrogen Storage through Molecular Modeling and Combinatorial Methods

    SciTech Connect (OSTI)

    Lesch, David A; Adriaan Sachtler, J.W. J.; Low, John J; Jensen, Craig M; Ozolins, Vidvuds; Siegel, Don

    2011-02-14

    UOP LLC, a Honeywell Company, Ford Motor Company, and Striatus, Inc., collaborated with Professor Craig Jensen of the University of Hawaii and Professor Vidvuds Ozolins of University of California, Los Angeles on a multi-year cost-shared program to discover novel complex metal hydrides for hydrogen storage. This innovative program combined sophisticated molecular modeling with high throughput combinatorial experiments to maximize the probability of identifying commercially relevant, economical hydrogen storage materials with broad application. A set of tools was developed to pursue the medium throughput (MT) and high throughput (HT) combinatorial exploratory investigation of novel complex metal hydrides for hydrogen storage. The assay programs consisted of monitoring hydrogen evolution as a function of temperature. This project also incorporated theoretical methods to help select candidate materials families for testing. The Virtual High Throughput Screening served as a virtual laboratory, calculating structures and their properties. First Principles calculations were applied to various systems to examine hydrogen storage reaction pathways and the associated thermodynamics. The experimental program began with the validation of the MT assay tool with NaAlH4/0.02 mole Ti, the state of the art hydrogen storage system given by decomposition of sodium alanate to sodium hydride, aluminum metal, and hydrogen. Once certified, a combinatorial 21-point study of the NaAlH4 â?? LiAlH4 â??Mg(AlH4)2 phase diagram was investigated with the MT assay. Stability proved to be a problem as many of the materials decomposed during synthesis, altering the expected assay results. This resulted in repeating the entire experiment with a mild milling approach, which only temporarily increased capacity. NaAlH4 was the best performer in both studies and no new mixed alanates were observed, a result consistent with the VHTS. Powder XRD suggested that the reverse reaction, the regeneration of the alanate from alkali hydride, Al and hydrogen, was hampering reversibility. The reverse reaction was then studied for the same phase diagram, starting with LiH, NaH, and MgH2, and Al. The study was extended to phase diagrams including KH and CaH2 as well. The observed hydrogen storage capacity in the Al hexahydrides was less than 4 wt. %, well short of DOE targets. The HT assay came on line and after certification with studies on NaAlH4, was first applied to the LiNH2 - LiBH4 - MgH2 phase diagram. The 60-point study elucidated trends within the system locating an optimum material of 0.6 LiNH2 â?? 0.3 MgH2 â?? 0.1 LiBH4 that stored about 4 wt. % H2 reversibly and operated below 220 °C. Also present was the phase Li4(NH2)3BH4, which had been discovered in the LiNH2 -LiBH4 system. This new ternary formulation performed much better than the well-known 2 LiNH2 â?? MgH2 system by 50 °C in the HT assay. The Li4(NH2)3BH4 is a low melting ionic liquid under our test conditions and facilitates the phase transformations required in the hydrogen storage reaction, which no longer relies on a higher energy solid state reaction pathway. Further study showed that the 0.6 LiNH2 â?? 0.3 MgH2 â?? 0.1 LiBH4 formulation was very stable with respect to ammonia and diborane desorption, the observed desorption was from hydrogen. This result could not have been anticipated and was made possible by the efficiency of HT combinatorial methods. Investigation of the analogous LiNH2 â?? LiBH4 â?? CaH2 phase diagram revealed new reversible hydrogen storage materials 0.625 LiBH4 + 0.375 CaH2 and 0.375 LiNH2 + 0.25 LiBH4 + 0.375 CaH2 operating at 1 wt. % reversible hydrogen below 175 °C. Powder x-ray diffraction revealed a new structure for the spent materials which had not been previously observed. While the storage capacity was not impressive, an important aspect is that it boron appears to participate in a low temperature reversible reaction. The last major area of study also focused

  2. ExoMol molecular line lists X: The spectrum of sodium hydride

    E-Print Network [OSTI]

    Rivlin, Tom; Yurchenko, Sergei N; Tennyson, Jonathan; Roy, Robert J Le

    2015-01-01

    Accurate and complete rotational, rotational-vibrational and rotational-vibrational-electronic line lists are calculated for sodium hydride: both the NaH and NaD isotopologues are considered. These line lists cover all ro-vibrational states of the ground ($X$~$^1\\Sigma^+$) and first excited ($A$~$^1\\Sigma^+$) electronic states. The calculations use available spectroscopically-determined potential energy curves and new high-quality, \\textit{ab initio} dipole moment curves. Partition functions for both isotopologues are calculated and the effect of quasibound states is considered. The resulting line lists are suitable for temperatures up to about 7000~K and are designed for studies of exoplanet atmospheres, brown dwarfs and cool stars. In particular, the NaH $A-X$ band is found to show a broad absorption feature at about 385 nm which should provide a signature for the molecule. All partition functions, lines and transitions are available as Supplementary Information to this article and at \\url{www.exomol.com}.

  3. Atomic-Scale Chemical, Physical and Electronic Properties of the Subsurface Hydride of Palladium

    SciTech Connect (OSTI)

    Weiss, Paul

    2014-01-20

    We employed low-temperature, extreme-high vacuum scanning tunneling microscopy (STM) to investigate the roles of subsurface hydride (H) and deuteride (D) in the surface reconstruction and surface reactivity of Pd{110}. Specifically, we gained the ability to tailor the surface structure of Pd{110} both by preparation method and by deposition of deuterium from the gas phase. We observed thiophene at low coverage on Pd{110} to determine its adsorption orientation and electronic structure through scanning tunneling spectroscopy (STS) – namely, conductance spectroscopy and differential conductance imaging. We developed the methods necessary to coadsorb D adatoms with thiophene molecules, and to induce the reaction of individual molecules with predefined subsurface H or D features. In the case of Pd{110}, we found a much more pronounced effect from subsurface D, as it is influenced by the surface directionality. These experiments facilitate an understanding of the role of surface and subsurface H and D in heterogeneous catalytic processes, specifically in the hydrodesulfuization (HDS) of thiophene, an important and ubiquitous component found to be detrimental to petroleum refining.

  4. Effect of long-range repulsive Coulomb interactions on packing structure of adhesive particles

    E-Print Network [OSTI]

    Sheng Chen; Shuiqing Li; Wenwei Liu; Hernán A. Makse

    2015-09-26

    The packing of charged micron-sized particles was investigated using discrete element simulations based on adhesive contact dynamic model. The formation process and the final obtained structures of ballistic packings are studied to show the effect of interparticle Coulomb force. It was found that increasing the charge on particles causes a remarkable decrease of the packing volume fraction \\phi and the average coordination number Z, indicating a looser and chainlike structure. Force-scaling analysis shows that the long-range Coulomb interaction changes packing structures through its influence on particle inertia before they are bonded into the force networks. Once contact networks are formed, the expansion effect caused by repulsive Coulomb forces are dominated by short-range adhesion. Based on abundant results from simulations, a dimensionless adhesion parameter Ad* , which combines the effects of the particle inertia, the short-range adhesion and the long-range Coulomb interaction, is proposed and successfully scales the packing results for micron-sized particles within the latestly derived adhesive loose packing (ALP) regime. The structural properties of our packings follow well the recent theoretical prediction which is described by an ensemble approach based on a coarse-grained volume function, indicating some kind of universality in the low packing density regime of the phase diagram regardless of adhesion or particle charge. Based on the comprehensive consideration of the complicated inter-particle interactions, our findings provide insight into the roles of short-range adhesion and repulsive Coulomb force during packing formation and should be useful for further design of packings.

  5. UBC Social Ecological Economic Development Studies (SEEDS) Student Report An Investigation into Packing Materials for the New Student Union Building

    E-Print Network [OSTI]

    into Packing Materials for the New Student Union Building Caleb Ng, Jun Oh, Siamak Rahmanian University Investigation into Packing Materials for the New Student Union Building APSC 262 April 4, 2013 Caleb Ng

  6. Fact #823: June 2, 2014 Hybrid Vehicles use more Battery Packs but Plug-in Vehicles use More Battery Capacity

    Broader source: Energy.gov [DOE]

    Of the battery packs used for electrified vehicle powertrains in model year 2013, the greatest number went into conventional hybrid vehicles which use battery packs that average about 1.3 kilowatt...

  7. ELECTRON BEAM -DIRECTED VAPOR DEPOSITION OF MULTIFUNCTIONAL D. T. QUEHEILLALT, Y. KATSUMI, H. N. G. WADLEY

    E-Print Network [OSTI]

    Wadley, Haydn

    . KATSUMI, H. N. G. WADLEY University of Virginia, Department of Materials Science & Engineering, 116 Engineers Way Charlottesville, Virginia, U.S.A. 22904-4745, dougq@virginia.edu ABSTRACT Multifunctional-pipe structures and porous electrode coatings for rechargeable nickel - metal hydride cells. In addition to load

  8. J. Electrochem. Soc., Vol. 142, No. 5, May 1995 9 The Electrochemical Society, Inc. 1401 1. E.g. Lawrence and E. Tannas, Jr., Flat-Panel Displays

    E-Print Network [OSTI]

    Weidner, John W.

    , and H. Sawai, J. Inst. Television Engineers Jpn., 47, 1006 (1993). 8. K. Machida, K. Amano, M. TokuraMotupaUy,*ChristopherC. Streinz,and JohnW. Weidner** Department of Chemical Engineering, University of South Carolina, Columbia/hydrogen, and nickel/metal hydrides. The re- dox reaction taking place at the electrode during discharge and charge can

  9. 34 J. Electrochem. Soc., Vol. 145, No. 1, January 1998 The Electrochemical Society, Inc. 7 dimensionless time, (t I il/nFcNIl)

    E-Print Network [OSTI]

    Weidner, John W.

    ,* Mukul Jain,* Venkat Srinivasan,* and John W. Weidner** Center for Electro chemical Engineering, Department of Chemical Engineering, University of South Carolina, Columbia, South Carolina 29208, USA rechargeable battery systems (e.g., nick- el/cadmium, nickel/zinc, nickel/hydmgen, and nickel/metal hydride

  10. A Novel Routing Metric for Environmentally-Powered Sensors With Hybrid

    E-Print Network [OSTI]

    Ingram, Mary Ann

    Aravind Kailas and Mary Ann Ingram School of Electrical and Computer Engineering, Georgia Institute of Electrical and Computer Engineering, Georgia Institute of Technology, Savannah, Georgia 31407-3039, USA Email, depending on is type (e.g. Nickel Metal Hydride (NiMH) or Lithium Ion Polymer) can have cycle life ranging

  11. 3/21/11 1:37 PMUntitled Page 1 of 3

    E-Print Network [OSTI]

    Braun, Paul

    -like power with battery-like energy," said Braun, a professor of materials science and engineering. "Most both." The performance of typical lithium-ion (Li-ion) or nickel metal hydride (NiMH) rechargeable think of this the same way you do an internal combustion engine. You would just pull up to a charging

  12. Last Revised: 10/2013 Battery Waste Collection Request

    E-Print Network [OSTI]

    Sniadecki, Nathan J.

    Only Storage Location Mixed Batteries (alkaline, carbon zinc, Ni-Cad, nickel metal hydride, mercuryLast Revised: 10/2013 Battery Waste Collection Request www.ehs.washington.edu/forms/epo/1943.pdf Instructions: Fill out the approximate weight of each battery type KG For Environmental Health and Safety Use

  13. Page 1 of 2 UNIVERSAL WASTE

    E-Print Network [OSTI]

    Jia, Songtao

    -Cadmium (Ni-Cd) Nickel Metal Hydride (Ni-MH) Lithium Ion (Li-ion) Large or Small sealed lead acid (Pb) MercuryPage 1 of 2 UNIVERSAL WASTE and OTHER ENVIRONMENTALLY DELETERIOUS PRODUCTS Batteries All Universal Waste Batteries generated in laboratories must be collected through the hazardous waste program

  14. Computational Fluid Dynamics Modeling of a Lithium/Thionyl Chloride Battery with Electrolyte Flow

    E-Print Network [OSTI]

    Wang, Chao-Yang

    Computational Fluid Dynamics Modeling of a Lithium/Thionyl Chloride Battery with Electrolyte Flow W-dimensional model is developed to simulate discharge of a primary lithium/thionyl chloride battery. The model to the first task with important examples of lead-acid,1-3 nickel-metal hydride,4-8 and lithium-based batteries

  15. Maxim > App Notes > BATTERY MANAGEMENT INTERFACE CIRCUITS Keywords: USB, USB Charger, Li+ USB charger, Lithium Ion USB charger, NiMH USB charger, USB battery

    E-Print Network [OSTI]

    Allen, Jont

    charger, Lithium Ion USB charger, NiMH USB charger, USB battery charger, charging batteries from USB, and cabling. An overview of nickel metal hydride (NiMH) and lithium battery technologies, charging methodsMaxim > App Notes > BATTERY MANAGEMENT INTERFACE CIRCUITS Keywords: USB, USB Charger, Li+ USB

  16. On Modeling Bonds in Fused, Porous Networks: 3D Simulations

    E-Print Network [OSTI]

    Sastry, Ann Marie

    , fused, joint, mechanics, nanotube, network, random, sintered, welded. INTRODUCTION EXAMPLES OF FUSED.1177/002199803029725 ß 2003 Sage Publications #12;(nickel-metal hydride) and Li-ion (lithium ion) batteries that contain nanotube mat are among the newest engineered materials constructed in this way. Applications

  17. * corresponding Auithor. Email: cxw31@psu.edu Modeling Discharge and Charge Characteristics

    E-Print Network [OSTI]

    Wang, Chao-Yang

    of OH ­ with respect to the solvent velocity U j,ref open­circuit potential for reaction j: nickel­metal hydride battery, oxygen reaction, modeling and computer simulation #12; 3 LIST OF SYMBOLS _ nj transfer current density of reaction j, A/cm 2 i 0j,ref exchange current density of reaction j

  18. Powering the Next Billion Devices with Wi-Fi Vamsi Talla, Bryce Kellogg, Benjamin Ransford, Saman Naderiparizi,

    E-Print Network [OSTI]

    Van Volkenburgh, Elizabeth

    - nication performance. Building on our design, we prototype battery-free temperature and camera sensors to wirelessly trickle-charge nickel­ metal hydride and lithium-ion coin-cell batteries at distances of up to 28 performance. 1. INTRODUCTION In the late 19th century, Nikola Tesla dreamed of elim- inating wires for both

  19. Modeling of a Nickel-Hydrogen Cell Phase Reactions in the Nickel Active Material

    E-Print Network [OSTI]

    developed high-energy-density batteries, e.g., the nickel-metal hydride battery and the lithium-ion batteryModeling of a Nickel-Hydrogen Cell Phase Reactions in the Nickel Active Material B. Wu and R. E of South Carolina, Columbia, South Carolina 29208, USA A nonisothermal model of a nickel-hydrogen cell has

  20. Resistive companion battery modeling for electric circuit simulations , R. Dougalb

    E-Print Network [OSTI]

    Resistive companion battery modeling for electric circuit simulations B. Wua , R. Dougalb , R be achieved based on RC models. In this study, the construction of RC battery models is investigated. A general battery model and a nickel±metal hydride cell model have been built. Simulations of RC battery

  1. Two plateaux for palladium hydride and the effect of helium from tritium decay on the desorption plateau pressure for palladium tritide

    SciTech Connect (OSTI)

    Walters, R.T.; Lee, M.W. (Westinghouse Savannah River Co., Savannah River Lab., Aiken, SC (US))

    1991-10-01

    Two plateaux are observed in the desorption isotherm for palladium hydride: a lower plateau pressure for a hydrogen/metal atom ratio (H/M) less than about 0.3 and a slightly higher plateau pressure for H/M greater than about 0.3. This higher pressure corresponds to the reported pressure for palladium hydride. These observations were made for a large surface area palladium powder exposed to both protium and tritium. Helium buildup form tritium decay decreases the lower plateau pressure but does not affect the observations for H/M greater than about 0.3. In this paper, a multiple-energy hydrogen site occupancy model is proposed to explain qualitatively both the dual plateau and the helium effect in palladium hydride.

  2. Particle size effect of hydride formation and surface hydrogen absorption of nanosized palladium catalysts : L{sub 3} edge vs K edge x-ray absorption spectroscopy.

    SciTech Connect (OSTI)

    Tew, M. W.; Miller, J. T.; van Bokhoven, J. A.

    2009-08-01

    The particle size effect on the formation of palladium hydride and on surface hydrogen adsorption was studied at room temperature using in situ X-ray absorption spectroscopy at the Pd K and L{sub 3} edges. Hydride formation was indirectly observed by lattice expansion in Pd K edge XANES spectra and by EXAFS analysis. Hydride formation was directly detected in the L{sub 3} edge spectra. A characteristic spectral feature caused by the formation of a Pd-H antibonding state showed strong particle size dependence. The L{sub 3} edge spectra were reproduced using full multiple scattering analysis and density of state calculations, and the contributions of bulk absorbed and surface hydrogen to the XANES spectra could be distinguished. The ratio of hydrogen on the surface versus that in the bulk increased with decreasing particle size, and smaller particles dissolved less hydrogen.

  3. Centrifugal compression of soft particle packings - theory and experiment

    E-Print Network [OSTI]

    K. N. Nordstrom; E. Verneuil; W. G. Ellenbroek; T. C. Lubensky; J. P. Gollub; D. J. Durian

    2010-09-15

    An exact method is developed for computing the height of an elastic medium subjected to centrifugal compression, for arbitrary constitutive relation between stress and strain. Example solutions are obtained for power-law media and for cases where the stress diverges at a critical strain -- for example as required by packings composed of deformable but incompressible particles. Experimental data are presented for the centrifugal compression of thermo-responsive N-isopropylacrylamide (NIPA) microgel beads in water. For small radial acceleration, the results are consistent with Hertzian elasticity, and are analyzed in terms of the Young elastic modulus of the bead material. For large radial acceleration, the sample compression asymptotes to a value corresponding to a space-filling particle volume fraction of unity. Therefore we conclude that the gel beads are incompressible, and deform without deswelling. In addition, we find that the Young elastic modulus of the particulate gel material scales with cross-link density raised to the power 3.3+-0.8, somewhat larger than the Flory expectation.

  4. A coupled transport and solid mechanics formulation with improved reaction kinetics parameters for modeling oxidation and decomposition in a uranium hydride bed.

    SciTech Connect (OSTI)

    Salloum, Maher N.; Shugard, Andrew D.; Kanouff, Michael P.; Gharagozloo, Patricia E.

    2013-03-01

    Modeling of reacting flows in porous media has become particularly important with the increased interest in hydrogen solid-storage beds. An advanced type of storage bed has been proposed that utilizes oxidation of uranium hydride to heat and decompose the hydride, releasing the hydrogen. To reduce the cost and time required to develop these systems experimentally, a valid computational model is required that simulates the reaction of uranium hydride and oxygen gas in a hydrogen storage bed using multiphysics finite element modeling. This SAND report discusses the advancements made in FY12 (since our last SAND report SAND2011-6939) to the model developed as a part of an ASC-P&EM project to address the shortcomings of the previous model. The model considers chemical reactions, heat transport, and mass transport within a hydride bed. Previously, the time-varying permeability and porosity were considered uniform. This led to discrepancies between the simulated results and experimental measurements. In this work, the effects of non-uniform changes in permeability and porosity due to phase and thermal expansion are accounted for. These expansions result in mechanical stresses that lead to bed deformation. To describe this, a simplified solid mechanics model for the local variation of permeability and porosity as a function of the local bed deformation is developed. By using this solid mechanics model, the agreement between our reacting bed model and the experimental data is improved. Additionally, more accurate uranium hydride oxidation kinetics parameters are obtained by fitting the experimental results from a pure uranium hydride oxidation measurement to the ones obtained from the coupled transport-solid mechanics model. Finally, the coupled transport-solid mechanics model governing equations and boundary conditions are summarized and recommendations are made for further development of ARIA and other Sandia codes in order for them to sufficiently implement the model.

  5. Similar Energetic Contributions of Packing in the Core of Membrane and Water-Soluble Proteins

    SciTech Connect (OSTI)

    Joh, Nathan H.; Oberai, Amit; Yang, Duan; Whitelegge, Julian P.; Bowie, James U.; (UCLA)

    2009-09-15

    A major driving force for water-soluble protein folding is the hydrophobic effect, but membrane proteins cannot make use of this stabilizing contribution in the apolar core of the bilayer. It has been proposed that membrane proteins compensate by packing more efficiently. We therefore investigated packing contributions experimentally by observing the energetic and structural consequences of cavity creating mutations in the core of a membrane protein. We observed little difference in the packing energetics of water and membrane soluble proteins. Our results imply that other mechanisms are employed to stabilize the structure of membrane proteins.

  6. Discrete Elements Method: A New Kind of Initial Conditions - Tetrahedral Packing of Balls

    E-Print Network [OSTI]

    Mark A. Tsayger

    2014-12-15

    The Paper discusses the use of the regular packing of identical balls with the coordination number 4 as a model of a medium consisting of fluid and solid particles in the conditions of fluidization. It is proposed to use the examined packing of balls as an initial condition for the calculations by the Discrete Elements Method (DEM) in technological processes in the fluidized bed in industry, as well as in the modeling of processes that occur in hydraulic and pneumatic transport of granular materials. Filtration properties of such packing required for its use as an initial condition in calculations by DEM are estimated.

  7. Discrete Elements Method: A New Kind of Initial Conditions - Tetrahedral Packing of Balls

    E-Print Network [OSTI]

    Mark A. Tsayger

    2015-10-13

    The Paper discusses the use of the regular packing of identical balls with the coordination number 4 as a model of a medium consisting of fluid and solid particles in the conditions of fluidization. It is proposed to use the examined packing of balls as an initial condition for the calculations by the Discrete Elements Method (DEM) in technological processes in the fluidized bed in industry, as well as in the modeling of processes that occur in hydraulic and pneumatic transport of granular materials. Filtration properties of such packing required for its use as an initial condition in calculations by DEM are estimated.

  8. Electrostatics and packing in biomolecules : accounting for conformational change in protein folding and binding

    E-Print Network [OSTI]

    Caravella, Justin Andrew, 1974-

    2002-01-01

    The role of electrostatics and packing in protein folding and molecular association was assessed in different biomolecular systems. A continuum electrostatic model was applied to long-range electrostatic effects in the ...

  9. Design and fabrication of retrofit e-bike powertrain and custom lithium-ion battery pack

    E-Print Network [OSTI]

    Wang, Helena

    2015-01-01

    A chopper-style bicycle was converted to a functional e-bike with electric powertrain, involving a hub motor, a custom power source, and throttle speed control. A custom battery pack was designed to meet system performance ...

  10. Packed-Bed Reactor Study of NETL Sample 196c for the Removal...

    Office of Scientific and Technical Information (OSTI)

    Reactor Study of NETL Sample 196c for the Removal of Carbon Dioxide from Simulated Flue Gas Mixture Citation Details In-Document Search Title: Packed-Bed Reactor Study of NETL...

  11. An Archaeological Survey for the Wallace Pack Unit Wastewater Treatment Plant Project in Grimes County Texas 

    E-Print Network [OSTI]

    Moore, William

    2015-07-15

    Brazos Valley Research Associates (BVRA) conducted archaeological survey and monitoring at the Wallace Pack Unit, Grimes County, Texas in October 2004 under Antiquities Permit 3570. This investigation examined the site of a proposed lift station...

  12. Electrically recharged battery employing a packed/spouted bed metal particle electrode

    DOE Patents [OSTI]

    Siu, Stanley C. (Alameda, CA); Evans, James W. (Piedmont, CA); Salas-Morales, Juan (Berkeley, CA)

    1995-01-01

    A secondary metal air cell, employing a spouted/packed metal particle bed and an air electrode. More specifically a zinc air cell well suited for use in electric vehicles which is capable of being either electrically or hydraulically recharged.

  13. Designing Safe Lithium-Ion Battery Packs Using Thermal Abuse Models (Presentation)

    SciTech Connect (OSTI)

    Pesaran, A. A.; Kim, G. H.; Smith, K.; Darcy, E.

    2008-12-01

    NREL and NASA developed a thermal-electrical model that resolves PTC and cell behavior under external shorting, now being used to evaluate safety margins of battery packs for spacesuit applications.

  14. Modular Approach for Continuous Cell-Level Balancing to Improve Performance of Large Battery Packs: Preprint

    SciTech Connect (OSTI)

    Muneed ur Rehman, M.; Evzelman, M.; Hathaway, K.; Zane, R.; Plett, G. L.; Smith, K.; Wood, E.; Maksimovic, D.

    2014-10-01

    Energy storage systems require battery cell balancing circuits to avoid divergence of cell state of charge (SOC). A modular approach based on distributed continuous cell-level control is presented that extends the balancing function to higher level pack performance objectives such as improving power capability and increasing pack lifetime. This is achieved by adding DC-DC converters in parallel with cells and using state estimation and control to autonomously bias individual cell SOC and SOC range, forcing healthier cells to be cycled deeper than weaker cells. The result is a pack with improved degradation characteristics and extended lifetime. The modular architecture and control concepts are developed and hardware results are demonstrated for a 91.2-Wh battery pack consisting of four series Li-ion battery cells and four dual active bridge (DAB) bypass DC-DC converters.

  15. MASS TRANSFER CONTROLLED REACTIONS IN PACKED BEDS AT LOW REYNOLDS NUMBERS

    E-Print Network [OSTI]

    Fedkiw, Peter S.

    2011-01-01

    beds. The Effect of Flow Maldistribution in a Packed Bed onthe effect of flow maldistribution in an array of tubes. Histhis idea of flow maldistribution is expanded upon, and in

  16. Utilization of Structured Packing for Energy Savings in Distillation and Absorption Columns 

    E-Print Network [OSTI]

    Berven, O. J.; Howard, W. E.

    1986-01-01

    As the need to reduce production costs causes manufacturers to re-evaluate processing schemes, high efficiency structured packings are increasingly recognized as an effective alternative for reducing energy consumption in ...

  17. It's getting hot in here : temperature gradients in lithium-ion battery packs

    E-Print Network [OSTI]

    Niewood, Benjamin

    2015-01-01

    A 5 channel, 40A battery cycler was constructed for the purpose of carrying out thermal studies on Lithium-ion battery packs. Boston Power Swing Key 442 battery blocks were tested to determine the magnitude of the temperature ...

  18. Fact #823: June 2, 2014 Hybrid Vehicles use more Battery Packs...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    lower volume, their battery packs are much larger with capacities as high as 85 kWh - a battery offering for the Tesla Model S. Number of Batteries Sold and Battery Capacity Sold...

  19. Sand pack residual oil saturations as affected by extraction with various solvents 

    E-Print Network [OSTI]

    Murray, Clarence

    1958-01-01

    LIBRARY S 4 M COLLEGE OF TEXAS SAND PACK RESIDUAL OIL SATURATIONS AS AFFECTED BY EXTRACTION WITH VARIOUS SOLVENTS A Thesis CLARENCE MURRAY, JR. Submitted to the Graduate School of The Agricultural and Mechanical College of Texas in partial... fulfillment of the requirements for the degree of MASTER OF SCIENCE August, I958 Major Subject: Petroleum Engineering SAND PACK RESIDUAL OIL SAT URATIONS AS AFFECTED BY EXTRACTION WITH VARIOUS SOLVENTS A Thesis By CLARENCE MURRAY, JR. Approved...

  20. Investigation of the thermal conductivity of unconsolidated sand packs containing oil, water, and gas 

    E-Print Network [OSTI]

    Gore, David Eugene

    1958-01-01

    INVESTIGATION OF THE THERNAL CONDUCTIVITY OF UNCONSOLIDATED SAND PACKS CONTAINING OIL, WATER, AND GAS A Thesis David E. Gore Submitted to the Graduate School of the Agricultural and Nechanical College oi' Texas in Partial fulfillment... and thxee-phase fluid saturation on the thermal conductivity of sand packs. The current research was conducted using a sand and lubricating oil on which related studies had been pexfoxmed. The thermal conductivity measuxements were made undex condi...

  1. Effect of packing material on methane activation in a dielectric barrier discharge reactor

    SciTech Connect (OSTI)

    Jo, Sungkwon; Hoon Lee, Dae; Seok Kang, Woo; Song, Young-Hoon

    2013-12-15

    The conversion of methane is measured in a planar-type dielectric barrier discharge reactor using ?-Al{sub 2}O{sub 3} (sphere), ?-Al{sub 2}O{sub 3} (sphere), and ?-Al{sub 2}O{sub 3} (16–20 mesh). Investigations on the surface properties and shape of the three packing materials clearly indicate that methane activation is considerably affected by the material used. Capacitances inside the discharge gap are estimated from charge–voltage plots, and a comparison of the generated and transferred charges for different packing conditions show that the difference in surface properties between ?- and ?-phase Al{sub 2}O{sub 3} affects the discharge characteristics. Moreover, all packing conditions show different charge characteristics that are related to the electron density. Finally, the packing material's shape affects the local electron temperature, which is strongly related to methane conversion. The combined results indicate that both microscale and macroscale variations in a packing material affect the discharge characteristics, and a packing material should be considered carefully for effective methane activation.

  2. Presented at the NuMat 2012 Conference, 2225 October 2012, Osaka, Japan Effect of thermo-mechanical cycling on zirconium hydride reorientation

    E-Print Network [OSTI]

    Motta, Arthur T.

    -mechanical cycling on zirconium hydride reorientation studied in situ with synchrotron X-ray diffraction Kimberly B and Nuclear Engineering, Penn State University, University Park, PA 16802, USA b Department of Mechanical and Materials Engineering, Queen's University, Kingston, ON, Canada K7L 3N6 c Advanced Photon Source, Argonne

  3. The affect of erbium hydride on the conversion efficience to accelerated protons from ultra-shsort pulse laser irradiated foils

    SciTech Connect (OSTI)

    Offermann, D

    2008-09-04

    This thesis work explores, experimentally, the potential gains in the conversion efficiency from ultra-intense laser light to proton beams using erbium hydride coatings. For years, it has been known that contaminants at the rear surface of an ultra-intense laser irradiated thin foil will be accelerated to multi-MeV. Inertial Confinement Fusion fast ignition using proton beams as the igniter source requires of about 10{sup 16} protons with an average energy of about 3MeV. This is far more than the 10{sup 12} protons available in the contaminant layer. Target designs must include some form of a hydrogen rich coating that can be made thick enough to support the beam requirements of fast ignition. Work with computer simulations of thin foils suggest the atomic mass of the non-hydrogen atoms in the surface layer has a strong affect on the conversion efficiency to protons. For example, the 167amu erbium atoms will take less energy away from the proton beam than a coating using carbon with a mass of 12amu. A pure hydrogen coating would be ideal, but technologically is not feasible at this time. In the experiments performed for my thesis, ErH{sub 3} coatings on 5 {micro}m gold foils are compared with typical contaminants which are approximately equivalent to CH{sub 1.7}. It will be shown that there was a factor of 1.25 {+-} 0.19 improvement in the conversion efficiency for protons above 3MeV using erbium hydride using the Callisto laser. Callisto is a 10J per pulse, 800nm wavelength laser with a pulse duration of 200fs and can be focused to a peak intensity of about 5 x 10{sup 19}W/cm{sup 2}. The total number of protons from either target type was on the order of 10{sup 10}. Furthermore, the same experiment was performed on the Titan laser, which has a 500fs pulse duration, 150J of energy and can be focused to about 3 x 10{sup 20} W/cm{sup 2}. In this experiment 10{sup 12} protons were seen from both erbium hydride and contaminants on 14 {micro} m gold foils. Significant improvements were also observed but possibly because of the depletion of hydrogen in the contaminant layer case.

  4. Li{sub 4}FeH{sub 6}: Iron-containing complex hydride with high gravimetric hydrogen density

    SciTech Connect (OSTI)

    Saitoh, Hiroyuki, E-mail: cyto@spring8.or.jp [Quantum Beam Science Center, Japan Atomic Energy Agency, Hyogo 679-5148 (Japan); Takagi, Shigeyuki; Matsuo, Motoaki; Aoki, Katsutoshi [Institute for Materials Research, Tohoku University, Sendai 980-8577 (Japan); Iijima, Yuki [WPI-Advanced Institute for Materials Research, Tohoku University, Sendai 980-8577 (Japan); Endo, Naruki [Renewable Energy Research Center, National Institute of Advanced Industrial Science and Technology, Fukushima 963-0215 (Japan); Orimo, Shin-ichi [Institute for Materials Research, Tohoku University, Sendai 980-8577 (Japan); WPI-Advanced Institute for Materials Research, Tohoku University, Sendai 980-8577 (Japan)

    2014-07-01

    Li{sub 4}FeH{sub 6}, which has the highest gravimetric hydrogen density of iron-containing complex hydrides reported so far, is synthesized by hydrogenation of a powder mixture of iron and LiH above 6.1 GPa at 900?°C. In situ synchrotron radiation X-ray diffraction measurements reveal that while kinetics require high temperature and thus high pressure for the synthesis, Li{sub 4}FeH{sub 6} is expected to be thermodynamically stable slightly below room temperature at ambient pressure; further synthetic studies to suppress the kinetic effects may enable us to synthesize Li{sub 4}FeH{sub 6} at moderate pressures. Li{sub 4}FeH{sub 6} can be recovered at ambient conditions where Li{sub 4}FeH{sub 6} is metastable.

  5. LaNi.sub.5 is-based metal hydride electrode in Ni-MH rechargeable cells

    DOE Patents [OSTI]

    Bugga, Ratnakumar V. (Arcadia, CA); Fultz, Brent (Pasadena, CA); Bowman, Robert (La Mesa, CA); Surampudi, Subra Rao (Glendora, CA); Witham, Charles K. (Pasadena, CA); Hightower, Adrian (Pasadena, CA)

    1999-01-01

    An at least ternary metal alloy of the formula AB.sub.(Z-Y) X.sub.(Y) is disclosed. In this formula, A is selected from the rare earth elements, B is selected from the elements of Groups 8, 9, and 10 of the Periodic Table of the Elements, and X includes at least one of the following: antimony, arsenic, germanium, tin or bismuth. Z is greater than or equal to 4.8 and less than or equal to 6.0. Y is greater than 0 and less than 1. Ternary or higher-order substitutions to the base AB.sub.5 alloys that form strong kinetic interactions with the predominant metals in the base metal hydride are used to form metal alloys with high structural integrity after multiple cycles of hydrogen sorption.

  6. PFP Commercial Grade Food Pack Cans for Plutonium Handling and Storage Critical Characteristics

    SciTech Connect (OSTI)

    BONADIE, E.P.

    2000-08-22

    This screening addresses the critical characteristics for food industry type cans and containers used for handling and storage of special nuclear materials at the Plutonium Finishing Plant (PFP). HNF-5460, Revision 0 specified a minimum tin plate of 0.50 Ib./base box. Since the food pack cans currently used and that have been tested have a listed tin plate of 0.20 lbs. per base box, Revision 1 reduced the tin plate to {ge} 0.20 Ib./base box (i.e., No. 20 tinned commercial steel or heavier). This revision lists Critical Characteristics for two (2) large filtered containers, and associated shielding over-packs. These new containers are called ''Nuclear Material Containers'' (NMCs). They are supplied in various sizes, which can be nested, one inside another. The PFP will use NMCs with volumes up to 8-quarts as needed to over-pack largely bulged containers.

  7. Cross-flow versus counter-current flow packed-bed scrubbers: a mathematical analysis

    SciTech Connect (OSTI)

    Fthenakis, V.M.

    1996-02-01

    Little is known about the mass transfer properties of packing media exposed to a crossflow of gas and liquid, whereas there is abundant information related to counter-current scrubbers. This paper presents a theoretical analysis of mass transfer and hydrodynamics in cross- flow packed bed scrubbers and compares those with information available for counter current towers, so that the first can be evaluated and/or designed based on data derived for the second. Mathematical models of mass transfer in cross-flow and counter- current packed bed scrubbers are presented. From those, one can predict the removal effectiveness of a crossflow scrubber from the number of transfer units (NTU) calculated for a similar counterflow operation; alternatively, when the removal effectiveness in counterflow is known, one can predict the corresponding NTU in crossflow.

  8. Conceptual Designs for a Spallation Neutron Target Constructed of a Helium-Cooled, Packed Bed of Tungsten Particles

    E-Print Network [OSTI]

    McDonald, Kirk

    foundation a target and blanket system that is driven by a proton accelerator. The subcritical blanket-cooled, packed bed of tungsten particles. Two packed bed target designs for accelerator transmutation of waste/p and improved axial distribution of neutrons. * E-mail: ammerman@lanl.gov I. INTRODUCTION The Accelerator

  9. Packing hyperspheres highdimensional Euclidean spaces Monica Skoge, Aleksandar Donev, Frank Stillinger, Salvatore Torquato 2,3,4,5,

    E-Print Network [OSTI]

    Stillinger, Frank

    error­correcting codes in communications theory Our focus this paper will the study hard­sphere packings #nonequilibrium# disordered jammed packings hard spheres and their statistical mechanical properties used stringent testing ground such theories. Along these lines and particular interest to paper

  10. Error of the network approximation for densely packed composites with irregular geometry

    E-Print Network [OSTI]

    such as the effective conductivity or the effective dielectric constant of composite materials in which a large number in the case of the high contrast, highly packed particular composites, that is when the conductivity inclusions is high is particularly relevant to polymer/ceramic composites, because a polymer matrix

  11. EXPERIMENTAL INVESTIGATION AND ANALYSIS OF THE EFFECTIVE THERMAL PROPERTIES OF BERYLLIUM PACKED BEDS

    E-Print Network [OSTI]

    Abdou, Mohamed

    , proposed by the European Community for a Demonstration Reactor (DEMO), is based on using ceramic breeder as a material form for the blanket of ITER (International Thermonuclear Experimental Reactor). Beryllium is usedEXPERIMENTAL INVESTIGATION AND ANALYSIS OF THE EFFECTIVE THERMAL PROPERTIES OF BERYLLIUM PACKED

  12. Vehicle Technologies Office Merit Review 2013: A High-Performance PHEV Battery Pack

    Broader source: Energy.gov [DOE]

    Presentation given by LG Chem at 2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting about a high-performance battery pack the company is researching for plug-in electric vehicles.

  13. PennyPacking and TwoDimensional Codes * R. L. Graham and N. J. A. Sloane

    E-Print Network [OSTI]

    Sloane, Neil J. A.

    design, when the points P 1 , . . . , P n form a two­dimensional code [3], [4], [7], U measures of the best packings known for n £ 500. For large n, U ~ Ö``3 n 2 / (4p). _______________ * This appeared diameter d, let P 1 , . . . , P n be their centers and P __ = n - 1 S P i their centroid. Then the problem

  14. Jammed hard-particle packings: From Kepler to Bernal and beyond S. Torquato*

    E-Print Network [OSTI]

    Stillinger, Frank

    ," and polyhedra. Because of their relevance to error-correcting codes and information theory, sphere packings for the Science and Technology of Materials, and Program in Applied and Computational Mathematics, Princeton analysis. A fundamental feature of that diversity is the necessity to classify individual jammed

  15. Structure characterization of hard sphere packings in amorphous and crystalline states

    E-Print Network [OSTI]

    Luding, Stefan

    Structure characterization of hard sphere packings in amorphous and crystalline states Vitaliy. A com- mon microstructural feature is observed in crystalline and glassy jammed states, suggesting with the nucleation and growth of the crystalline phase11. Hard-sphere models are known to successfully reproduce

  16. Power Strip Packing of Malleable Demands in Mohammad M. Karbasioun, Gennady Shaikhet, Evangelos Kranakis, Ioannis Lambadaris

    E-Print Network [OSTI]

    Kranakis, Evangelos

    of the main goals of Demand Side Management (DSM) in smart grid is to reduce the peak to average ratio (PAR1 Power Strip Packing of Malleable Demands in Smart Grid Mohammad M. Karbasioun, Gennady Shaikhet of electrical energy which has to be supplied during the time interval [0, 1]. We assume that each demand has

  17. "Self-assembly of uniform polyhedral silver nanocrystals into densest packings and exotic superlattices"

    SciTech Connect (OSTI)

    Henzie, Joel; Grunwald, Michael; Widmer-Cooper, Asaph; Geissler, Phillip L.; Yang, Peidong

    2011-03-01

    Understanding how polyhedra pack into extended arrangements is integral to the design and discovery of crystalline materials at all length scales. Much progress has been made in enumerating and characterizing the packing of polyhedral shapes, and the self-assembly of polyhedral nanocrystals into ordered superstructures. However, directing the self-assembly of polyhedral nanocrystals into densest packings requires precise control of particle shape, polydispersity,interactions and driving forces. Here we show with experiment and computer simulation that a range of nanoscale Ag polyhedra can self-assemble into their conjectured densest packings. When passivated with adsorbing polymer, the polyhedra behave as quasi-hard particles and assemble into millimetre-sized three-dimensional supercrystals by sedimentation.We also show, by inducing depletion attraction through excess polymer in solution, that octahedra form an exotic superstructure with complex helical motifs rather than the densest Minkowski lattice. Such large-scale Ag supercrystals may facilitate the design of scalable three-dimensional plasmonic metamaterials for sensing, nanophotonics, and photocatalysis.

  18. Proteins with H-bond packing defects are highly interactive with lipid bilayers: Implications

    E-Print Network [OSTI]

    Berry, R. Stephen

    Proteins with H-bond packing defects are highly interactive with lipid bilayers: Implications of Chicago, Chicago, IL 60637; Institute for Protein Research, Osaka University, 3-2 Yamadaoka, Suita, Osaka-related amyloidogenic proteins and espe- cially cellular prion proteins have the highest proportion of incom- pletely

  19. Electrically recharged battery employing a packed/spouted bed metal particle electrode

    DOE Patents [OSTI]

    Siu, S.C.; Evans, J.W.; Salas-Morales, J.

    1995-08-15

    A secondary metal air cell, employing a spouted/packed metal particle bed and an air electrode, is described. More specifically a zinc air cell well suited for use in electric vehicles which is capable of being either electrically or hydraulically recharged. 5 figs.

  20. Fusion Engineering and Design 3940 (1998) 759764 Mechanical behavior and design database of packed beds for

    E-Print Network [OSTI]

    Abdou, Mohamed

    1998-01-01

    Fusion Engineering and Design 39­40 (1998) 759­764 Mechanical behavior and design database of packed beds for blanket designs Alice Y. Ying *, Zi Lu, Mohamed A. Abdou Mechanical and Aerospace to fusion solid breeder blanket designs need to be performed. In this paper, the mechanical behavior

  1. Energy Consumption Tools Pack Leandro Fontoura Cupertino, Georges DaCosta,

    E-Print Network [OSTI]

    Lefèvre, Laurent

    Resource Manager Energy Efficiency 2 Software development Power consumption of a same functionality varies load Workload classes differ depending on DC type App Monitor App Profiler Resource Manager Energy Efficiency Cupertino, DaCosta, Sayah, Pierson (IRIT) Energy Consumption Tools Pack 4 / 23 #12;Introduction

  2. A statistical approach to close packing of elastic rods and to DNA packaging in viral capsids

    E-Print Network [OSTI]

    Adda-Bedia, Mokhtar

    a statistical minimal model based on Edwards' theory to study the conformations of the rod. This approach provA statistical approach to close packing of elastic rods and to DNA packaging in viral capsids E, France Communicated by Sam Edwards, University of Cambridge, Cambridge, United Kingdom, October 13, 2006

  3. Estimates of the optimal density of sphere packings in high dimensions

    E-Print Network [OSTI]

    Stillinger, Frank

    suggest that such improve- ment should be possible. Using a statistical-mechanical procedure to optimize-correcting" codes underlie a variety of systems in digital communications and storage.12 Physicists have in discrete geometry and number theory.4,5,12,16,17 The packing density or simply density of a

  4. Molecular Packing and Solar Cell Performance in Blends of Polymers with a Bisadduct Fullerene

    E-Print Network [OSTI]

    McGehee, Michael

    Molecular Packing and Solar Cell Performance in Blends of Polymers with a Bisadduct Fullerene States *S Supporting Information ABSTRACT: We compare the solar cell performance of several polymers the efficiency of the solar cells only when they do not intercalate between the polymer side chains. When

  5. Computer simulation of random loose packings of micro-particles in presence of adhesion and friction

    E-Print Network [OSTI]

    Wenwei Liu; Shuiqing Li; Sheng Chen

    2015-11-07

    With a novel 3D discrete-element method specially developed with adhesive contact mechanics, random loose packings of uniform spherical micron-sized particles are fully investigated. The results show that large velocity, large size or weak adhesion can produce a relatively dense packing when other parameters are fixed, and these combined effects can be characterized by a dimensionless adhesion parameter ( $Ad=\\omega/2\\rho_pU^2_0R$). Four regimes are identified based on the value of $Ad$: RCP regime with $Adadhesion regime with $120$. Force distribution of these adhesive loose packings follows $P(f)\\sim f^\\theta$ for small forces and $P(f)\\sim \\exp^{-\\beta f}$ for big forces, respectively, which shares a similar form with that in packings without adhesion but results in distinct exponents of $\\theta=0.879$, $\\beta=0.839$. A local mechanical equilibrium analysis shows that adhesion enhances both sliding and rolling resistance so that fewer neighbours are needed to satisfy the force and torque balance.

  6. Aalborg Universitet A novel BEV concept based on fixed and swappable li-ion battery packs

    E-Print Network [OSTI]

    Berning, Torsten

    and Control, Robotics and Mechatronics Center German Aerospace Center (DLR), Wessling, D-82234, Germany Email@fe.up.pt Abstract--In this paper a novel battery electric vehicle (BEV) concept based on a small fixed and a big swappable li-ion battery pack is proposed in order to achieve: longer range, lower initial purchase price

  7. Error of the network approximation for densely packed composites with irregular geometry

    E-Print Network [OSTI]

    Novikov, Alexei

    the concentration of the filling inclusions is high is particularly relevant to polymer/ceramic composites, because a polymer matrix compensates for the brittle nature of ceramics which is their main weakness. A surveyError of the network approximation for densely packed composites with irregular geometry Leonid

  8. Journal of Embedded Computing 2 (2006) 93102 93 Frame packing algorithms for automotive

    E-Print Network [OSTI]

    Navet, Nicolas

    2006-01-01

    Journal of Embedded Computing 2 (2006) 93­102 93 IOS Press Frame packing algorithms for automotive Vandoeuvre-l `es-Nancy, France Abstract. The set of frames exchanged in automotive applications must meet two proposes algorithms for building off-line the set of frames in automotive communica- tions with the two

  9. ONE-DIMENSIONAL PSEUDO-HOMOGENEOUS PACKED BED REACTOR MODELING INCLUDING NO-CO KINETICS

    E-Print Network [OSTI]

    Srinivasan, Anand

    2011-08-31

    -homogeneous packed bed reactor model for this type of reactor setup built in collaboration with the Chemical and Petroleum Engineering Department at the University of Kansas. A brief summary of the pseudo-homogeneous model is presented in order to properly develop...

  10. Centrifugal compression of soft particle packings: Theory and experiment K. N. Nordstrom,1

    E-Print Network [OSTI]

    Gollub, Jerry P.

    Centrifugal compression of soft particle packings: Theory and experiment K. N. Nordstrom,1 E to centrifugal compression, for arbitrary constitutive relation between stress and strain. Example solutions by centrifugal compression, and we illustrate our method with experiments on 1 m diam- eter NIPA microgel beads

  11. Are artificial opals non-close-packed fcc structures? F. Garca-Santamaraa

    E-Print Network [OSTI]

    Braun, Paul

    Are artificial opals non-close-packed fcc structures? F. García-Santamaríaa and P. V. Braun experimental method to accurately measure the volume fraction of artificial opals. The results are modeled in the opal interstices with the optical properties may need revision, especially in the case of high

  12. Future perspectives of using hollow fibers as structured packings in light hydrocarbon distillation

    SciTech Connect (OSTI)

    Yang, Dali; Orler, Bruce; Tornga, Stephanie; Welch, Cindy

    2011-01-26

    Olefin and paraffin are the largest chemical commodities. Furthermore, they are major building blocks for the petrochemical industry. Each year, petroleum refining, consumes 4,500 TBtu/yr in separation energy, making it one of the most energy-intensive industries in the United States). Just considering liquefied petroleum gas (ethane/propane/butane) and olefins (ethylene and propylene) alone, the distillation energy consumption is about 400 TBtu/yr in the US. Since petroleum distillation is a mature technology, incremental improvements in column/tray design will only provide a few percent improvements in the performance. However, each percent saving in net energy use amounts to savings of 10 TBtu/yr and reduces CO{sub 2} emissions by 0.2 MTon/yr. In practice, distillation columns require 100 to 200 trays to achieve the desired separation. The height of a transfer unit (HTU) of conventional packings is typical in the range of 36-60 inch. Since 2006, we had explored using several non-selective membranes as the structured packings to replace the conventional packing materials used in propane and propylene distillation. We obtained the lowest HTU of < 8 inch for the hollow fiber column, which was >5 times shorter than that of the conventional packing materials. In 2008, we also investigated this type of packing materials in iso-/n-butane distillation. Because of a slightly larger relative volatility of iso-/n-butane than that of propane/propylene, a wider and a more stable operational range was obtained for the iso-/n-butane pair. However, all of the experiments were conducted on a small scale with flowrate of < 25 gram/min. Recently, we demonstrated this technology on a larger scale (<250 gram/min). Within the loading range of F-factor < 2.2 Pa{sup 0.5}, a pressure drop on the vapor side is below 50 mbar/m, which suggests that the pressure drop of hollow fibers packings is not an engineering barrier for the applications in distillations. The thermal stability study suggests that polypropylene hollow fibers are stable after a long time exposure to C{sub 2} - C{sub 4} mixtures. The effects of packing density on the separation efficiency will be discussed.

  13. Effect of Gaseous Impurities on Long-Term Thermal Cycling and Aging Properties of Complex Hydrides for Hydrogen Storage

    SciTech Connect (OSTI)

    Chandra, Dhanesh; Lamb, Joshua; Chien, Wen-Ming; Talekar, Anjali; and Pal, Narendra.

    2011-03-28

    This program was dedicated to understanding the effect of impurities on Long-Term Thermal Cycling and aging properties of Complex Hydrides for Hydrogen Storage. At the start of the program we found reversibility between Li2NH+LiH ? LiH+LiNH2 (yielding ~5.8 wt.%H capacity). Then we tested the effect of impurity in H2 gas by pressure cycling at 255oC; first with industrial gas containing ppm levels of O2 and H2O as major impurities. Both these impurities had a significant impact on the reversibility and decreased the capacity by 2.65 wt.%H. Further increase in number of cycles from 500 to 1100 showed only a 0.2 wt%H more weight loss, showing some capacity is still maintained after a significant number of cycles. The loss of capacity is attributed to the formation of ~55 wt% LiH and ~30% Li2O, as major contaminant phases, along with the hydride Li2NH phase; suggesting loss of nitrogen during cycling. The effect of 100 ppm H2O in H2 also showed a decrease of ~2.5 wt.%H (after 560 cycles), and 100ppm O2 in H2; a loss of ~4.1 wt.%. Methane impurity (100 ppm, 100cycles), showed a very small capacity loss of 0.9 wt.%H under similar conditions. However, when Li3N was pressure cycled with 100ppmN2-H2 there were beneficial effects were observed (255oC); the reversible capacity increased to 8.4wt.%H after 853 cycles. Furthermore, with 20 mol.%N2-H2 capacity increased to ~10 wt.%H after 516 cycles. We attribute this enhancement to the reaction of nitrogen with liquid lithium during cycling as the Gibbs free energy of formation of Li3N (?Go = -98.7 kJ/mol) is more negative than that of LiH (?Go = -50.3 kJ/mol). We propose that the mitigation of hydrogen capacity losses is due to the destabilization of the LiH phase that tends to accumulate during cycling. Also more Li2NH phase was found in the cycled product. Mixed Alanates (3LiNH2:Li3AlH6) showed that 7 wt% hydrogen desorbed under dynamic vacuum. Equilibrium experiments (maximum 12 bar H2) showed up to 4wt% hydrogen reversibly stored in the material after the first desorption. The activation energy was found to be 51 kJ/mol, as compared to 81 kJ/mol for pure lithium alanate. It is proposed that based on the data obtained and CALPHAD modeling that the improvement in cycling is due to the formation of pure lithium (liquid at 255oC), which is able to react with nitrogen specifically forming Li3N. The presence of nitrogen in the 80/20 molar mixtures in a hydride bed along with hydrogen causes Li to form Li3N rather than LiH, and subsequently regenerates the Li2NH phase and yields a ~10 wt.%H reversibly.

  14. The role of destabilization of palladium hydride on the hydrogen uptake of Pd-containing activated carbons

    SciTech Connect (OSTI)

    Bhat, Vinay V; Contescu, Cristian I; Gallego, Nidia C

    2009-01-01

    This paper reports on differences in stability of Pd hydride phases in palladium particles with various degrees of contact with microporous carbon supports. A sample containing Pd embedded in activated carbon fiber (Pd-ACF; 2 wt% Pd) was compared with commercial Pd nanoparticles deposited on microporous activated carbon (Pd-catalyst, 3 wt% Pd) and with support-free nanocrystalline palladium (Pd-black). The morphology of materials was characterized by electron microscopy, and the phase transformations were analyzed over a large range of hydrogen partial pressures (0.003 - 10 bar) and at several temperatures using in-situ X-ray diffraction. The results were verified with volumetric hydrogen uptake measurements. Results indicate that higher degree of Pd-carbon contacts for Pd particles embedded in a microporous carbon matrix induce efficient pumping of hydrogen out of -PdHx. It was also found that thermal cleaning of carbon surface groups prior to exposure to hydrogen further enhances the hydrogen pumping power of the microporous carbon support. In brief, this study highlights that the stability of -PdHx phase supported on carbon depends on the degree of contact between Pd-carbon and the nature of the carbon surface.

  15. Thermal Release of 3He from Tritium Aged LaNi4.25Al0.75 Hydride

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Staack, Gregory C.; Crowder, Mark L.; Klein, James E.

    2015-02-01

    Recently, the demand for He-3 has increased dramatically due to widespread use in nuclear nonproliferation, cryogenic, and medical applications. Essentially all of the world’s supply of He-3 is created by the radiolytic decay of tritium. The Savannah River Site Tritium Facilities (SRS-TF) utilizes LANA.75 in the tritium process to store hydrogen isotopes. The vast majority of He-3 “born” from tritium stored in LANA.75 is trapped in the hydride metal matrix. The SRS-TF has multiple LANA.75 tritium storage beds that have been retired from service with significant quantities of He-3 trapped in the metal. To support He-3 recovery, the Savannah Rivermore »National Laboratory (SRNL) conducted thermogravimetric analysis coupled with mass spectrometry (TGA-MS) on a tritium aged LANA.75 sample. TGA-MS testing was performed in an argon environment. Prior to testing, the sample was isotopically exchanged with deuterium to reduce residual tritium and passivated with air to alleviate pyrophoric concerns associated with handling the material outside of an inert glovebox. Analyses indicated that gas release from this sample was bimodal, with peaks near 220 and 490°C. The first peak consisted of both He-3 and residual hydrogen isotopes, the second was primarily He-3. The bulk of the gas was released by 600 °C« less

  16. The structural origin of the hard-sphere glass transition in granular packing

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Xia, Chengjie; Li, Jindong; Cao, Yixin; Kou, Binquan; Xiao, Xianghui; Fezzaa, Kamel; Xiao, Tiqiao; Wang, Yujie

    2015-09-28

    Glass transition is accompanied by a rapid growth of the structural relaxation time and a concomitant decrease of configurational entropy. It remains unclear whether the transition has a thermodynamic origin, and whether the dynamic arrest is associated with the growth of a certain static order. Using granular packing as a model hard-sphere glass, we show the glass transition as a thermodynamic phase transition with a ‘hidden’ polytetrahedral order. This polytetrahedral order is spatially correlated with the slow dynamics. It is geometrically frustrated and has a peculiar fractal dimension. Additionally, as the packing fraction increases, its growth follows an entropy-driven nucleationmore »process, similar to that of the random first-order transition theory. In conclusion, our study essentially identifies a long-sought-after structural glass order in hard-sphere glasses.« less

  17. Review of Inflatable Booms for Deployable Space Structures: Packing and Rigidization

    E-Print Network [OSTI]

    Schenk, Mark; Viquerat, Andrew D.; Seffen, Keith A.; Guest, Simon D.

    2014-04-21

    Review of Inflatable Booms for Deployable Space Structures: Packing and Rigidization Mark Schenk1, Andrew D. Viquerat 2 and Keith A. Seffen 3 and Simon D. Guest 4 Department of Engineering, University of Cambridge, Cambridge, CB2 1PZ, United Kingdom... Senior Lecturer, Cambridge University Engineering Department; kas14@cam.ac.uk 4 Reader, Cambridge University Engineering Department; sdg13@cam.ac.uk 1 Preprint of Mark Schenk, Andrew D. Viquerat, Keith A. Seffen, and Simon D. Guest. "Review...

  18. Modeling engine oil vaporization and transport of the oil vapor in the piston ring pack on internal combustion engines

    E-Print Network [OSTI]

    Cho, Yeunwoo, 1973-

    2004-01-01

    A model was developed to study engine oil vaporization and oil vapor transport in the piston ring pack of internal combustion engines. With the assumption that the multi-grade oil can be modeled as a compound of several ...

  19. Power generation by packed-bed air-cathode microbial fuel cells Xiaoyuan Zhang a,b

    E-Print Network [OSTI]

    Power generation by packed-bed air-cathode microbial fuel cells Xiaoyuan Zhang a,b , Juan Shi c to P15 g significantly reduced power generation because of a reduction in oxygen transfer due

  20. Random loose packing and an order parameter for the parking lot model

    E-Print Network [OSTI]

    K. Hernández; L. I. Reyes

    2010-05-25

    We have obtained the random loose packing fraction of the parking lot model (PLM) by taking the limit of infinite compactivity in the two-variable statistical description of Tarjus and Viot for the PLM. The PLM is a stochastic model of adsorption and desorption of particles on a substrate that have been used as a model for compaction of granular materials. An order parameter $\\rho$ is introduced to characterize how far from a steady state situation the model is. Thus, configurations with $\\rho<1$ age. We propose that $\\rho$ can be a starting point in order to stablish a connection between Edwards' statistical mechanics and granular hydrodynamics.

  1. OVERCOMING THE METER BARRIER AND THE FORMATION OF SYSTEMS WITH TIGHTLY PACKED INNER PLANETS (STIPs)

    SciTech Connect (OSTI)

    Boley, A. C.; Morris, M. A.; Ford, E. B.

    2014-09-10

    We present a solution to the long outstanding meter barrier problem in planet formation theory. As solids spiral inward due to aerodynamic drag, they will enter disk regions that are characterized by high temperatures, densities, and pressures. High partial pressures of rock vapor can suppress solid evaporation, and promote collisions between partially molten solids, allowing rapid growth. This process should be ubiquitous in planet-forming disks, which may be evidenced by the abundant class of Systems with Tightly packed Inner Planets discovered by the NASA Kepler Mission.

  2. GridPACK Toolkit for Developing Power Grid Simulations on High Performance Computing Platforms

    SciTech Connect (OSTI)

    Palmer, Bruce J.; Perkins, William A.; Glass, Kevin A.; Chen, Yousu; Jin, Shuangshuang; Callahan, Charles D.

    2013-11-30

    This paper describes the GridPACK™ framework, which is designed to help power grid engineers develop modeling software capable of running on todays high performance computers. The framework contains modules for setting up distributed power grid networks, assigning buses and branches with arbitrary behaviors to the network, creating distributed matrices and vectors, using parallel linear and non-linear solvers to solve algebraic equations, and mapping functionality to create matrices and vectors based on properties of the network. In addition, the framework contains additional functionality to support IO and to manage errors.

  3. Coexistence of dilute and densely packed domains of ligand-receptor bonds in membrane adhesion

    E-Print Network [OSTI]

    Daniel Schmidt; Timo Bihr; Udo Seifert; Ana-Sun?ana Smith

    2012-07-11

    We analyze the stability of micro-domains of ligand-receptor bonds that mediate the adhesion of biological model membranes. After evaluating the effects of membrane fluctuations on the binding affinity of a single bond, we characterize the organization of bonds within the domains by theoretical means. In a large range of parameters, we find the commonly suggested dense packing to be separated by a free energy barrier from a regime in which bonds are sparsely distributed. If bonds are mobile, a coexistence of the two regimes should emerge, which agrees with recent experimental observations.

  4. Highly chemoselective palladium-catalyzed conjugate reduction of. cap alpha. ,. beta. -unsaturated carbonyl compounds with silicon hydrides and zinc chloride cocatalyst

    SciTech Connect (OSTI)

    Keinan, E.; Greenspoon, N.

    1986-11-12

    A three-component system comprised of a soluble palladium catalyst, hydridosilane, and zinc chloride is capable of efficient conjugate reduction of ..cap alpha..,..beta..-unsaturated ketones and aldehydes. The optimal set of conditions includes diphenylsilane as the most effective hydride donor, any soluble palladium complex in either the O or II oxidation state, when it is stabilized by phosphine ligands, and ZnCl/sub 2/ as the best Lewis acid cocatalyst. The reaction is very general with respect to a broad range of unsaturated ketones and aldehydes, and it is highly selective for these Michael acceptors, as reduction of ..cap alpha..,..beta..-unsaturated carboxylic acid derivatives is very sluggish under these conditions. When dideuteriodiphenylsilane is used to reduce unsaturated ketones, deuterium is stereoselectivity introduced at the less-hindered fact of the substrate and regioselectively at the ..beta..-position. Conversely, when reductions are carried out in the presence of traces of D/sub 2/O, deuterium incorporation occurs at the ..cap alpha..-position. On the basis of deuterium-incorporation experiments and /sup 1/H NMR studies a catalytic cycle is postulated in which the first step involves reversible coordination of the palladium complex to the electron-deficient olefin and oxidative addition of silicon hydride to form a hydridopalladium olefin complex.

  5. Electrochemical Oxidation of H? Catalyzed by Ruthenium Hydride Complexes Bearing P?N? Ligands With Pendant Amines as Proton Relays

    SciTech Connect (OSTI)

    Liu, Tianbiao L.; Rakowski DuBois, Mary; DuBois, Daniel L.; Bullock, R. Morris

    2014-01-01

    Two Ru hydride complexes (Cp*Ru(PPh?NBn?)H, (1-H) and Cp*Ru(PtBu?NBn?)H, (2-H) supported by cyclic PR?NR'? ligands (Cp* = n?-C?Me?; 1,5-diaza-3,7-diphosphacyclooctane, where R = Ph or tBu and R' = Bn) have been synthesized and fully characterized. Both complexes are demonstrated to be electrocatalysts for oxidation of H? (1 atm, 22 °C) in the presence of external base, DBU (1,8-diazabicyclo[5.4.0]undec-7-ene). The turnover frequency of 2-H is 1.2 s-1, with an overpotential at Ecat/2 of 0.45 V, while catalysis by 1-H has a turnover frequency of 0.6 s-1 and an overpotential of 0.6 V at Ecat/2. Addition of H?O facilitates oxidation of H? by 2-H and increases its turnover frequency to 1.9 s-1 while , H?O slows down the catalysis by 1-H. The different effects of H?O for 1-H and 2-H are ascribed to different binding affinities of H?O to the Ru center of the corresponding unsaturated species, [Cp*Ru(PPh?NBn?)]+ and [Cp*Ru(PPh?NBn?)]+. In addition, studies of Cp*Ru(dmpm)H (where dmpm = bis(dimethylphosphino)methane), a control complex lacking pendent amines in its diphosphine ligand, confirms the critical roles of the pendent amines of P?N? ligands for oxidation of H?. We thank the U.S. Department of Energy, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences and Biosciences, for supporting initial parts of the work. Current work is supported by the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences. Pacific Northwest National Laboratory is operated by Battelle for the U.S. Department of Energy.

  6. Please cite this article in press as: Malen, J.A., et al., Thermal hydraulic design of a hydride-fueled inverted PWR core. Nucl. Eng. Des. (2009), doi:10.1016/j.nucengdes.2009.02.026

    E-Print Network [OSTI]

    Malen, Jonathan A.

    2009-01-01

    Please cite this article in press as: Malen, J.A., et al., Thermal hydraulic design of a hydride-5320; No.of Pages10 Nuclear Engineering and Design xxx (2009) xxx­xxx Contents lists available at ScienceDirect Nuclear Engineering and Design journal homepage: www.elsevier.com/locate/nucengdes Thermal

  7. Please cite this article in press as: Greenspan, E., et al., Hydride fuel for LWRs--Project overview. Nucl. Eng. Des. (2009), doi:10.1016/j.nucengdes.2008.11.023

    E-Print Network [OSTI]

    Malen, Jonathan A.

    2009-01-01

    ) and boiling water reactor (BWR) cores by using solid hydride fuels instead of the commonly used oxide fuel of this project was to assess the feasibility of improving the performance of pressurised water reactor (PWR it fissions in one pass is double that of the MOX fuel. (2) Eliminating dedicated water moderator volumes

  8. Vibration-rotation emission spectra and combined isotopomer analyses for the coinage metal hydrides: CuH & CuD, AgH & AgD, and AuH

    E-Print Network [OSTI]

    Le Roy, Robert J.

    Vibration-rotation emission spectra and combined isotopomer analyses for the coinage metal hydrides 1999 High resolution infrared emission spectra have been measured for AuH and AuD and for two , and in spite of intense background thermal emission from the furnace at 2000 °C , vibration­rotation emission

  9. Turning intractable counting into sampling: computing the granular entropy of three-dimensional jammed packings

    E-Print Network [OSTI]

    Stefano Martiniani; K. Julian Schrenk; Jacob D. Stevenson; David J. Wales; Daan Frenkel

    2015-09-14

    We report a numerical calculation of the total number of disordered jammed configurations $\\Omega$ of $N$ repulsive, three-dimensional spheres in a fixed volume $V$. To make these calculations tractable, we increase the computational efficiency of the approach of Xu et al. (Phys. Rev. Lett. 106, 245502 (2011)) and Asenjo et al. (Phys. Rev. Lett. 112, 098002 (2014)) and we extend the method to allow computation of the granular entropy as a function of pressure. The approach that we use computes the granular entropy by sampling the absolute volume of basins of attraction of the stable packings in the potential energy landscape. We find a surprisingly strong correlation between the pressure of a configuration and the volume of its basin of attraction in the potential energy landscape. This relation is well described by a power law. Our methodology to compute the number of stable packings should be applicable to a wide range of other enumeration problems that aims to find the extrema of a scalar cost function that depends on many degrees of freedom.

  10. Turning intractable counting into sampling: computing the granular entropy of three-dimensional jammed packings

    E-Print Network [OSTI]

    Martiniani, Stefano; Stevenson, Jacob D; Wales, David J; Frenkel, Daan

    2015-01-01

    We report a numerical calculation of the total number of disordered jammed configurations $\\Omega$ of $N$ repulsive, three-dimensional spheres in a fixed volume $V$. To make these calculations tractable, we increase the computational efficiency of the approach of Xu et al. (Phys. Rev. Lett. 106, 245502 (2011)) and Asenjo et al. (Phys. Rev. Lett. 112, 098002 (2014)) and we extend the method to allow computation of the granular entropy as a function of pressure. The approach that we use computes the granular entropy by sampling the absolute volume of basins of attraction of the stable packings in the potential energy landscape. We find a surprisingly strong correlation between the pressure of a configuration and the volume of its basin of attraction in the potential energy landscape. This relation is well described by a power law. Our methodology to compute the number of stable packings should be applicable to a wide range of other enumeration problems that aims to find the extrema of a scalar cost function tha...

  11. Battery Electrode Materials with High Cycle Lifetimes

    SciTech Connect (OSTI)

    Prof. Brent Fultz

    2001-06-29

    In an effort to understand the capacity fade of nickel-metal hydride (Ni-MH) batteries, we performed a systematic study of the effects of solute additions on the cycle life of metal hydride electrodes. We also performed a series of measurements on hydrogen absorption capacities of novel carbon and graphite-based materials including graphite nanofibers and single-walled carbon nanotubes. Towards the end of this project we turned our attention to work on Li-ion cells with a focus on anode materials.

  12. PNNL Chemical Hydride Capabilities

    Broader source: Energy.gov [DOE]

    Presentation from the Hydrogen Storage Pre-Solicitation Meeting held June 19, 2003 in Washington, DC.

  13. Metal Hydrides- Science Needs

    Broader source: Energy.gov [DOE]

    Presentation from the Hydrogen Storage Pre-Solicitation Meeting held June 19, 2003 in Washington, DC.

  14. Regeneration of aluminum hydride

    DOE Patents [OSTI]

    Graetz, Jason Allan (Mastic, NY); Reilly, James J. (Bellport, NY)

    2009-04-21

    The present invention provides methods and materials for the formation of hydrogen storage alanes, AlH.sub.x, where x is greater than 0 and less than or equal to 6 at reduced H.sub.2 pressures and temperatures. The methods rely upon reduction of the change in free energy of the reaction between aluminum and molecular H.sub.2. The change in free energy is reduced by lowering the entropy change during the reaction by providing aluminum in a state of high entropy, by increasing the magnitude of the change in enthalpy of the reaction or combinations thereof.

  15. Regeneration of aluminum hydride

    DOE Patents [OSTI]

    Graetz, Jason Allan; Reilly, James J; Wegrzyn, James E

    2012-09-18

    The present invention provides methods and materials for the formation of hydrogen storage alanes, AlH.sub.x, where x is greater than 0 and less than or equal to 6 at reduced H.sub.2 pressures and temperatures. The methods rely upon reduction of the change in free energy of the reaction between aluminum and molecular H.sub.2. The change in free energy is reduced by lowering the entropy change during the reaction by providing aluminum in a state of high entropy, and by increasing the magnitude of the change in enthalpy of the reaction or combinations thereof.

  16. Integration Issues of Cells into Battery Packs for Plug-in and Hybrid Electric Vehicles: Preprint

    SciTech Connect (OSTI)

    Pesaran, A. A.; Kim, G. H.; Keyser, M.

    2009-05-01

    The main barriers to increased market share of hybrid electric vehicles (HEVs) and commercialization of plug-in HEVs are the cost, safety, and life of lithium ion batteries. Significant effort is being directed to address these issues for lithium ion cells. However, even the best cells may not perform as well when integrated into packs for vehicles because of the environment in which vehicles operate. This paper discusses mechanical, electrical, and thermal integration issues and vehicle interface issues that could impact the cost, life, and safety of the system. It also compares the advantages and disadvantages of using many small cells versus a few large cells and using prismatic cells versus cylindrical cells.

  17. Active coupling control in densely packed subwavelength waveguides via dark mode

    E-Print Network [OSTI]

    Suchowski, Haim; Hatakeyama, Taiki; Wu, Chihhui; Feng, Liang; OBrien, Kevin; Wang, Yuan; Zhang, Xiang

    2015-01-01

    The ever growing need for energy-efficient and fast communications is driving the development of highly integrated photonic circuits where controlling light at the nanoscale becomes the most critical aspect of information transfer . Directional couplers, two interacting optical waveguides placed in close proximity, are important building blocks in these integrated photonics circuits and have been employed as optical modulators and switches for high speed communication, data processing and integrated quantum operations. However, active control over the coupling between closely packed waveguides is highly desirable and yet remains a critical barrier towards ultra small footprint devices. A general approach to achieve active control in waveguide systems is to exploit optical nonlinearities enabled by a strong control pulse. However these devices suffer from the nonlinear absorption induced by the intense control pulse as the signal and its control propagate in the same waveguide. Here we experimentally demonstra...

  18. Pore-scale lattice Boltzmann simulation of laminar and turbulent flow through a sphere pack

    E-Print Network [OSTI]

    Fattahia, Ehsan; Wohlmuth, Barbara; Rüde, Ulrich; Manhart, Michael; Helmig, Rainer

    2015-01-01

    The lattice Boltzmann method can be used to simulate flow through porous media with full geometrical resolution. With such a direct numerical simulation, it becomes possible to study fundamental effects which are difficult to assess either by developing macroscopic mathematical models or experiments. We first evaluate the lattice Boltzmann method with various boundary handling of the solid-wall and various collision operators to assess their suitability for large scale direct numerical simulation of porous media flow. A periodic pressure drop boundary condition is used to mimic the pressure driven flow through the simple sphere pack in a periodic domain. The evaluation of the method is done in the Darcy regime and the results are compared to a semi-analytic solution. Taking into account computational cost and accuracy, we choose the most efficient combination of the solid boundary condition and collision operator. We apply this method to perform simulations for a wide range of Reynolds numbers from Stokes flo...

  19. Recovery of coal from preparation plant effluents using a packed column

    SciTech Connect (OSTI)

    Choudhry, V.; Khan, L.; Yang, D.; Banerjee, D.D.

    1993-12-31

    The feasibility of recovering coal from coal preparation plant waste (or effluent) streams at the pilot scale using the packed column flotation process is demonstrated. In Phase I of the project, a total of four effluent samples were tested at the bench scale with the objective of recovering low-ash, low-sulfur clean coal products that were, at a minimum, compatible with the quality of the clean coal produced by the preparation plants supplying the waste stream samples. Phase II of the project comprised demonstration of the technology at the pilot scale using a 4-in. I.D. {times} 20-ft tall column installed at the Applied Laboratory of the Illinois State Geological Survey. A large effluent sample was conducted, consisting of particle size distribution, proximate and complete analyses, and batch froth flotation testing. Ash, total and pyritic sulfur, and calorific value of the effluent sample were also determined. The effluent feed sample contained 50-55% ash and 2.2% total sulfur. Confirmatory tests were conducted at Michigan Technological University using a bench-scale packed column. A product containing 5.4% ash was obtained at 97.5% ash rejection and 71.8% combustible matter recovery. Changing the process operating parameters allowed the quality of the product to be controlled such that its ash content ranged between 6 and 10%, with combustible matter recoveries in the 71-77% range. Pilot testing was conducted using a test matrix designed to study the effects of primary variables (feed rate, percent solids, and reagent dosage) and operating variables (air rate, wash water, and pulp level) with the objective of optimizing the process performance. Feed rates of 20-108 lb/hour were tested, with very good performance being obtained at a feed rate of 32 lb/hour (374 lb/h/ft{sup 2}).

  20. Environmental effects on noble-gas hydrides: HXeBr, HXeCCH, and HXeH in noble-gas and molecular matrices

    SciTech Connect (OSTI)

    Tsuge, Masashi E-mail: leonid.khriachtchev@helsinki.fi; Lignell, Antti; Räsänen, Markku; Khriachtchev, Leonid E-mail: leonid.khriachtchev@helsinki.fi

    2013-11-28

    Noble-gas hydrides HNgY (Ng is a noble-gas atom and Y is an electronegative group) are sensitive probes of local environment due to their relatively weak bonding and large dipole moments. We experimentally studied HXeBr in Ar, Kr, and N{sub 2} matrices, HXeCCH in Ne and N{sub 2} matrices, and HXeH in an N{sub 2} matrix. These are the first observations of noble-gas hydrides in an N{sub 2} matrix. An N{sub 2} matrix strongly increases the H–Xe stretching frequency of HXeBr and HXeCCH with respect to a Ne matrix, which is presumably due to a strong interaction between the HNgY dipole moment and quadrupole moments of the surrounding lattice N{sub 2} molecules. The spectral shift of HXeBr in an N{sub 2} matrix is similar to that in a CO{sub 2} matrix, which is a rather unexpected result because the quadrupole moment of CO{sub 2} is about three times as large as that of N{sub 2}. The H–Xe stretching frequencies of HXeBr and HXeCCH in noble-gas matrices show a trend of ?(Ne) < ?(Xe) < ?(Kr) < ?(Ar), which is a non-monotonous function of the dielectric constants of the noble-gas solids. The MP2(full) calculations of HXeBr and HXeCCH with the polarizable continuum model as well as the CCSD(T) calculations of the HXeBr···Ng and HXeCCH···Ng (Ng = Ne, Ar, Kr, and Xe) complexes cannot fully explain the experimental observations. It is concluded that more sophisticated computational models should be used to describe these experimental findings.

  1. Fuel Cell-Shaft Power Packs (FC-SPP) Frank Elefsen, Centre Manager, Ph.D., and Sten Frandsen, Head of Section

    E-Print Network [OSTI]

    Fuel Cell-Shaft Power Packs (FC-SPP) Frank Elefsen, Centre Manager, Ph.D., and Sten Frandsen, Head and an improved environment. 1 Fuel Cell-Shaft Power Packs (FC-SPP) A. Background In line with the growing global technology is receiving a great deal of attention. Hydrogen and fuel cells have the potential to replace

  2. UBC Social Ecological Economic Development Studies (SEEDS) Student Report An Investigation into the Use of Biodegradable Packing Materials in the New SUB: A

    E-Print Network [OSTI]

    into the Use of Biodegradable Packing Materials in the New SUB: A Triple Bottom-Line Assessment Ken Tam, Yang of Biodegradable Packing Materials in the New SUB: A Triple Bottom-Line Assessment Submitted on April 4, 2013-biodegradable. Nonetheless, the benefit from materials made from bio-based resources are debatable. The new SUB in UBC

  3. Improved Battery Pack Thermal Management to Reduce Cost and Increase Energy Density: Cooperative Research and Development Final Report, CRADA Number CRD-12-499

    SciTech Connect (OSTI)

    Smith, K.

    2013-10-01

    Under this CRADA NREL will support Creare's project for the Department of Energy entitled 'Improved Battery Pack Thermal Management to Reduce Cost and Increase Energy Density' which involves the development of an air-flow based cooling product that increases energy density, safety, and reliability of hybrid electric vehicle battery packs.

  4. FREE Name Tags for 1st year Students FREE Selected Course Packs for 2nd year Students

    E-Print Network [OSTI]

    Liu, Taosheng

    · FREE Name Tags for 1st year Students · FREE Selected Course Packs for 2nd year Students · Personalized MVMA Lab Coat at Transition Ceremony for 3rd year Students · Educational Presentations with Dinner to $11,000 each year!) · Discounts on Insurance, Rental Cars, and more! · FREE Legal Advice · Expanded

  5. Anisotropic nonlinear elasticity in a spherical-bead pack: Influence of the fabric anisotropy Yacine Khidas* and Xiaoping Jia

    E-Print Network [OSTI]

    Paris 7 - Denis Diderot, Université

    interest but also of practical impor- tance in many fields, including soil mechanics and geophys- ics. Unlike consolidated porous materials such as sedimen- tary rocks, soils, and sintered bead packs, dry inhomogeneous force network 1­6 . The mechanical properties of such materials depend strongly on both

  6. Accelerating Palladium-Catalyzed C-F Bond Formation: Use of a Microflow Packed-Bed Reactor

    E-Print Network [OSTI]

    Maimone, Thomas J.

    A flow process for Pd-catalyzed C-F bond formation is described. A microreactor with a packed-bed design allows for easy handling of large quantities of insoluble CsF with precise control over reaction times, efficient ...

  7. Self-Assembled Monolayers on Pt(111): Molecular Packing Structure and Strain Effects Observed by Scanning Tunneling

    E-Print Network [OSTI]

    Kim, Sehun

    Self-Assembled Monolayers on Pt(111): Molecular Packing Structure and Strain Effects Observed@uci.edu Abstract: Self-assembled monolayers (SAMs) of octanethiol and benzeneethanethiol were deposited on clean Pt° unit cell for the octanethiol SAMs and a 4( 3 × 3)R30° periodicity based on 2 × 2 basic molecular

  8. Formation of Rectangular Packing and One-Dimensional Lines of C60 on 11-Phenoxyundecanethiol Self-Assembled Monolayers on

    E-Print Network [OSTI]

    Sibener, Steven

    Formation of Rectangular Packing and One-Dimensional Lines of C60 on 11-Phenoxyundecanethiol Self Institute and Department of Chemistry, The University of Chicago, 929 E. 57th Street, Chicago, Illinois. We discuss the possible causes for the formation of this structure as well as the differences between

  9. A New Upper Bound 2.5545 on 2D Online Bin Packing XIN HAN, Dalian University of Technology

    E-Print Network [OSTI]

    Chin, Francis Y.L.

    50 A New Upper Bound 2.5545 on 2D Online Bin Packing XIN HAN, Dalian University of Technology was partially supported by NSFC (10971192). Authors' addresses: X. Han, Software School, Dalian University of Technology, Road 8, Economy and Tech- nology Development Zone, Dalian, P.R. China, 116620; email: hanxin

  10. 2000-01-1556 Life-Cycle Cost Sensitivity to Battery-Pack Voltage of an HEV

    E-Print Network [OSTI]

    Tolbert, Leon M.

    drive schedules. These life cycle costs include the initial manufacturing cost of components, fuel cost2000-01-1556 Life-Cycle Cost Sensitivity to Battery-Pack Voltage of an HEV John W. McKeever, Sujit defined the peak power ratings for each HEV drive system's electric components: batteries, battery cables

  11. Charge stabilized crystalline colloidal arrays as templates for fabrication of non-close-packed inverted photonic crystals

    E-Print Network [OSTI]

    Asher, Sanford A.

    devices. Thus, much of the recent work in photonic crystal fabrication has utilized colloidal particle self assembly. The utility of colloidal particle self assembly is evident from the photonic crystal colloidal particle self assembly work has emphasized methods that form close-packed photonic crystal

  12. Recovery Act: Hydroelectric Facility Improvement Project - Replacement of Current Mechanical Seal System with Rope Packing System

    SciTech Connect (OSTI)

    Stephens, Jessica D.

    2013-05-29

    On January 27, 2010 the City of North Little Rock, Arkansas received notification of the awarding of a Department of Energy (DOE) grant totaling $450,000 in funding from the American Recovery and Reinvestment Act (ARRA) under the Project Title: Recovery Act: Hydroelectric Facility Improvement Project – Automated Intake Clearing Equipment and Materials Management. The purpose of the grant was for improvements to be made at the City’s hydroelectric generating facility located on the Arkansas River. Improvements were to be made through the installation of an intake maintenance device (IMD) and the purchase of a large capacity wood grinder. The wood grinder was purchased in order to receive the tree limbs, tree trunks, and other organic debris that collects at the intake of the plant during high flow. The wood grinder eliminates the periodic burning of the waste material that is cleared from the intake and reduces any additional air pollution to the area. The resulting organic mulch has been made available to the public at no charge. Design discussion and planning began immediately and the wood grinder was purchased in July of 2010 and immediately put to work mulching debris that was gathered regularly from the intake of the facility. The mulch is currently available to the public for free. A large majority of the design process was spent in discussion with the Corps of Engineers to obtain approval for drawings, documents, and permits that were required in order to make changes to the structure of the powerhouse. In April of 2011, the City’s Project Engineer, who had overseen the application, resigned and left the City’s employ. A new Systems Mechanical Engineer was hired and tasked with overseeing the project. The transfer of responsibility led to a re-examination of the original assumptions and research upon which the grant proposal was based. At that point, the project went under review and a trip was booked for July 2011 to visit facilities that currently had an IMD installed. This further study of facilities revealed that the implementation of the project as originally described, while proving the benefits described in the original grant application, would likely intensify sand intake. Increased sand intake would lead to an increase in required shutdowns for maintenance and more rapid depreciation of key equipment which would result in a loss of generation capacity. A better solution to the problem, one that continued to meet the criteria for the original grant and ARRA standards, was developed. A supporting day trip was planned to visit other facilities located on the Arkansas River to determine how they were coping with the same strong amounts of sand, silt, and debris. Upon returning from the trip to other Arkansas River facilities it was extremely clear what direction to go in order to most efficiently address the issue of generator capacity and efficiency. Of the plants visited on the Arkansas River, every one of them was running what is called a rope packing shaft sealing system as opposed to mechanical shaft seals, which the facility was running. Rope packing is a time proven sealing method that has been around for centuries. It has proved to perform very well in dirty water situations just like that of the Arkansas River. In April of 2012 a scope change proposal was submitted to the DOE for approval. In August of 2012 the City received word that the change of scope had been approved. Plans were immediately set in motion to begin the conversion from mechanical seals to a packing box at the facility. Contractors arrived on October 1st, 2012 and the project team began unwatering the unit for disassembly. The seal conversion was completed on February 29th, 2013 with start-up of the unit. Further testing and adjusting was done throughout the first two weeks of March.

  13. Braided Bundles and Compact Coils: The Structure and Thermodynamics of Hexagonally-Packed, Chiral Filament Assemblies

    E-Print Network [OSTI]

    Gregory M. Grason

    2008-12-16

    Molecular chirality frustrates the two-dimensional assembly of filamentous molecules, a fact that reflects the generic impossibility of imposing a global twisting of layered materials. We explore the consequences of this frustration for hexagonally-ordered assemblies of chiral filaments that are {\\it finite} in lateral dimension. Specifically, we employ a continuum-elastic description of cylindrical bundles of filaments, allowing us to consider the most general resistance to and preference for chiral ordering of the assembly. We explore two distinct mechanisms by which chirality at the molecular scale of the filament frustrates the assembly into aggregates. In the first, chiral interactions between filaments impart an overall twisting of filaments around the central axis of the bundle. In the second, we consider filaments that are inherently helical in structure, imparting a writhing geometry to the central axis. For both mechanisms, we find that a thermodynamically-stable state of dispersed bundles of {\\it finite} width appears close to, but below, the point of bulk filament condensation. The range of thermodynamic stability of dispersed bundles is sensitive only to the elastic cost and preference for chiral filament packing. The self-limited assembly of chiral filaments has particular implications for a large class of biological molecules -- DNA, filamentous proteins, viruses, bacterial flagella -- which are universally chiral and are observed to form compact bundles under a broad range of conditions.

  14. Conformational Transition Between Four and Five-Stranded Phenylalanine Zippers Determined by a Local Packing Interaction

    SciTech Connect (OSTI)

    Liu,J.; Zheng, Q.; Deng, Y.; Kallenbach, N.; Lu, M.

    2006-01-01

    Alpha-helical coiled coils play a crucial role in mediating specific protein-protein interactions. However, the rules and mechanisms that govern helix-helix association in coiled coils remain incompletely understood. Here we have engineered a seven heptad 'Phe-zipper' protein (Phe-14) with phenylalanine residues at all 14 hydrophobic a and d positions, and generated a further variant (Phe-14{sub M}) in which a single core Phe residue is substituted with Met. Phe-14 forms a discrete {alpha}-helical pentamer in aqueous solution, while Phe-14M folds into a tetrameric helical structure. X-ray crystal structures reveal that in both the tetramer and the pentamer the a and d side-chains interlock in a classical knobs-into-holes packing to produce parallel coiled-coil structures enclosing large tubular cavities. However, the presence of the Met residue in the apolar interface of the tetramer markedly alters its local coiled-coil conformation and superhelical geometry. Thus, short-range interactions involving the Met side-chain serve to preferentially select for tetramer formation, either by inhibiting a nucleation step essential for pentamer folding or by abrogating an intermediate required to form the pentamer. Although specific trigger sequences have not been clearly identified in dimeric coiled coils, higher-order coiled coils, as well as other oligomeric multi-protein complexes, may require such sequences to nucleate and direct their assembly.

  15. Optical, electronic, and structural properties of uncoupled and close-packed arrays of InP quantum dots

    SciTech Connect (OSTI)

    Micic, O.I.; Jones, K.M.; Cahill, A.; Nozik, A.J.

    1998-12-03

    Solid films consisting of close-packed arrays of InP quantum dots have been prepared by slowly evaporating colloidal solutions of InP quantum dots. The diameters of the quantum dots were controlled to be between about 30 to 60 {angstrom}; size-selective precipitation yielded a size distribution of about 10% about the mean diameter. The arrays show regions of hexagonal order, as well as disordered regions. Oxide layers can form irreversibly on the quantum dot surface and limit the effectiveness of the size-selective precipitation. Photoluminescence spectra obtained from close-packed films of InP quantum dots formed from quantum dots with a single mean diameter and from a mixture of two quantum dot sizes show that energy transfer occurs from the photoexcited smaller quantum dots to the larger quantum dots. The efficiency of this energy transfer process is high.

  16. A master equation for force distributions in soft particle packings - Irreversible mechanical responses to isotropic compression and decompression

    E-Print Network [OSTI]

    Kuniyasu Saitoh; Vanessa Magnanimo; Stefan Luding

    2015-07-15

    Mechanical responses of soft particle packings to quasi-static deformations are determined by the microscopic restructuring of force-chain networks, where complex non-affine displacements of constituent particles cause the irreversible macroscopic behavior. Recently, we have proposed a master equation for the probability distribution functions of contact forces and interparticle gaps [K. Saitoh et al., Soft Matter 11, 1253 (2015)], where mutual exchanges of contacts and interparticle gaps, i.e. opening and closing contacts, are also involved in the stochastic description with the aid of Delaunay triangulations. We describe full details of the master equation and numerically investigate irreversible mechanical responses of soft particle packings to cyclic loading. The irreversibility observed in molecular dynamics simulations is well reproduced by the master equation if the system undergoes quasi-static deformations. We also confirm that the degree of irreversible responses is a decreasing function of the area fraction and the number of cycles.

  17. Removal of pollutant compounds from water supplies using ozone, ultraviolet light, and a counter, current packed column. Master's thesis

    SciTech Connect (OSTI)

    Kelly, E.L.

    1991-01-01

    Many water pollutants are determined to be carcinogenic and often appear in very low concentrations and still pose a health risk. Conventional water treatment processes cannot remove these contaminants and there is a great demand for the development of alternative removal technologies. The use of ozone and ultraviolet light in a counter current packed column could prove to be an effective treatment process to remove these contaminants.

  18. Development and Testing of an UltraBattery-Equipped Honda Civic Hybrid

    SciTech Connect (OSTI)

    Sally Sun; Tyler Gray; Pattie Hovorka; Jeffrey Wishart; Donald Karner; James Francfort

    2012-08-01

    The UltraBattery Retrofit Project DP1.8 and Carbon Enriched Project C3, performed by ECOtality North America (ECOtality) and funded by the U.S. Department of Energy and the Advanced Lead Acid Battery Consortium (ALABC), are established to demonstrate the suitability of advanced lead battery technology in hybrid electrical vehicles (HEVs). A profile, termed the “Simulated Honda Civic HEV Profile” (SHCHEVP) has been developed in Project DP1.8 in order to provide reproducible laboratory evaluations of different battery types under real-world HEV conditions. The cycle is based on the Urban Dynamometer Driving Schedule and Highway Fuel Economy Test cycles and simulates operation of a battery pack in a Honda Civic HEV. One pass through the SHCHEVP takes 2,140 seconds and simulates 17.7 miles of driving. A complete nickel metal hydride (NiMH) battery pack was removed from a Honda Civic HEV and operated under SHCHEVP to validate the profile. The voltage behavior and energy balance of the battery during this operation was virtually the same as that displayed by the battery when in the Honda Civic operating on the dynamometer under the Urban Dynamometer Driving Schedule and Highway Fuel Economy Test cycles, thus confirming the efficacy of the simulated profile. An important objective of the project has been to benchmark the performance of the UltraBatteries manufactured by both Furukawa Battery Co., Ltd., Japan (Furakawa) and East Penn Manufacturing Co., Inc. (East Penn). Accordingly, UltraBattery packs from both Furakawa and East Penn have been characterized under a range of conditions. Resistance measurements and capacity tests at various rates show that both battery types are very similar in performance. Both technologies, as well as a standard lead-acid module (included for baseline data), were evaluated under a simple HEV screening test. Both Furakawa and East Penn UltraBattery packs operated for over 32,000 HEV cycles, with minimal loss in performance; whereas the standard lead-acid unit experienced significant degradation after only 6,273 cycles. The high-carbon, ALABC battery manufactured in Project C3 also was tested under the advanced HEV schedule. Its performance was significantly better than the standard lead-acid unit, but was still inferior compared with the UltraBattery. The batteries supplied by Exide as part of the C3 Project performed well under the HEV screening test, especially at high temperatures. The results suggest that higher operating temperatures may improve the performance of lead-acid-based technologies operated under HEV conditions—it is recommended that life studies be conducted on these technologies under such conditions.

  19. Vehicle Technologies Office Merit Review 2014: Development of Cell/Pack Level Models for Automotive Li-Ion Batteries with Experimental Validation

    Broader source: Energy.gov [DOE]

    Presentation given by EC Power at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about evelopment of cell/pack level models...

  20. Modeling the performance of the piston ring-pack with consideration of non-axisymmetric characteristics of the power cylinder system in internal combustion engines

    E-Print Network [OSTI]

    Liu, Liang, 1971-

    2005-01-01

    The performance of the piston ring-pack is directly associated with the friction, oil consumption, wear, and blow-by in internal combustion engines. Because of non-axisymmetric characteristics of the power cylinder system, ...

  1. Simple shearing flow of dry soap foams with TCP structure[Tetrahedrally Close-Packed

    SciTech Connect (OSTI)

    REINELT,DOUGLAS A.; KRAYNIK,ANDREW M.

    2000-02-16

    The microrheology of dry soap foams subjected to large, quasistatic, simple shearing deformations is analyzed. Two different monodisperse foams with tetrahedrally close-packed (TCP) structure are examined: Weaire-Phelan (A15) and Friauf-Laves (C15). The elastic-plastic response is evaluated by calculating foam structures that minimize total surface area at each value of strain. The minimal surfaces are computed with the Surface Evolver program developed by Brakke. The foam geometry and macroscopic stress are piecewise continuous functions of strain. The stress scales as T/V{sup 1/3} where T is surface tension and V is cell volume. Each discontinuity corresponds to large changes in foam geometry and topology that restore equilibrium to unstable configurations that violate Plateau's laws. The instabilities occur when the length of an edge on a polyhedral foam cell vanishes. The length can tend to zero smoothly or abruptly with strain. The abrupt case occurs when a small increase in strain changes the energy profile in the neighborhood of a foam structure from a local minimum to a saddle point, which can lead to symmetry-breaking bifurcations. In general, the new foam topology associated with each stable solution branch results from a cascade of local topology changes called T1 transitions. Each T1 cascade produces different cell neighbors, reduces surface energy, and provides an irreversible, film-level mechanism for plastic yield behavior. Stress-strain curves and average stresses are evaluated by examining foam orientations that admit strain-periodic behavior. For some orientations, the deformation cycle includes Kelvin cells instead of the original TCP structure; but the foam does not remain perfectly ordered. Bifurcations during subsequent T1 cascades lead to disorder and can even cause strain localization.

  2. Evaluation of hoop creep behaviors in long-term dry storage condition of pre-hydrided and high burn-up nuclear fuel cladding

    SciTech Connect (OSTI)

    Kim, Sun-Ki; Bang, J.G.; Kim, D.H.; Yang, Y.S.

    2007-07-01

    Related to the degradation of the mechanical properties of Zr-based nuclear fuel cladding tubes under long term dry storage condition, the mechanical tests which can simulate the degradation of the mechanical properties properly are needed. Especially, the degradation of the mechanical properties by creep mechanism seems to be dominant under long term dry storage condition. Accordingly, in this paper, ring creep tests were performed in order to evaluate the creep behaviors of high burn-up fuel cladding under a hoop loading condition in a hot cell. The tests are performed with Zircaloy-4 fuel cladding whose burn-up is approximately {approx}60,000 MWd/tU in the temperature range from 350 deg. to 550 deg.. The tests are also performed with pre-hydrided Zircaloy-4 and ZIRLO up to 1,000 ppm. First of all, the hoop loading grip for the ring creep test was designed in order that a constant curvature of the specimen was maintained during the creep deformation, and the graphite lubricant was used to minimize the friction between the outer surface of the die insert and the inner surface of the ring specimen. The specimen for the ring creep test was designed to limit the deformation within the gauge section and to maximize the uniformity of the strain distribution. It was confirmed that the mechanical properties under a hoop loading condition can be correctly evaluated by using this test technique. In this paper, secondary creep rate with increasing hydrogen content are drawn, and then kinetic data such as pre-exponential factor and activation energy for creep process are also drawn. In addition, creep life are predicted by obtaining LMP (Larson-Miller parameter) correlation in the function of hydrogen content and applied stress to yield stress ratio. (authors)

  3. PHYSICAL REVIEW E 83, 021304 (2011) Response of a noncohesive packing of grains to a localized force: Deviation from continuum elasticity

    E-Print Network [OSTI]

    Clamond, Didier

    2011-01-01

    commonly used to model the behavior of cohesionless soils in civil engineering or in soil mechanics the mechanical behavior of grain piles, we investigate the response of a noncohesive two-dimensional packing between neighboring grains is generally larger than the number of equilibrium mechanical equations

  4. Assessing Terrain Stability in a GIS using SINMAP Pack, R.T. Research Associate Professor, Tarboton, D.G., Associate Professor1

    E-Print Network [OSTI]

    Tarboton, David

    Assessing Terrain Stability in a GIS using SINMAP Pack, R.T. Research Associate Professor, Tarboton State University, Logan, UT 84322-5230 Presented at the 15th annual GIS conference, GIS 2001, February 19-22, Vancouver, British Columbia Abstract SINMAP (Stability Index MAPping) is an ArcView GIS

  5. The role of sidechain packing and native contact interactions in folding: Discontinuous molecular dynamics folding simulations of an all-atom

    E-Print Network [OSTI]

    Zhou, Yaoqi

    structures of proteins, has been extensively investigated to examine its role in protein folding. However the important role of sidechain packing in determining the specific pathway of protein folding. Additional 96 of Physics. DOI: 10.1063/1.1514574 I. INTRODUCTION Theoretical/computational studies of protein folding

  6. Modelling of Particle Pyrolysis in a Packed Bed Combustor A.R.C. Tuck and W.L.H. Hallett ,1 2*

    E-Print Network [OSTI]

    Hallett, William L.H.

    Modelling of Particle Pyrolysis in a Packed Bed Combustor A.R.C. Tuck and W.L.H. Hallett ,1 2 are accounted for [2]. However, initial efforts to include pyrolysis were quite crude: a simple one-step global presented here is therefore to upgrade the current treatment of pyrolysis in the bed by developing a more

  7. Advanced batteries for electric vehicle applications

    SciTech Connect (OSTI)

    Henriksen, G.L.

    1993-08-01

    A technology assessment is given for electric batteries with potential for use in electric powered vehicles. Parameters considered include: specific energy, specific power, energy density, power density, cycle life, service life, recharge time, and selling price. Near term batteries include: nickel/cadmium and lead-acid batteries. Mid term batteries include: sodium/sulfur, sodium/nickel chloride, nickel/metal hydride, zinc/air, zinc/bromine, and nickel/iron systems. Long term batteries include: lithium/iron disulfide and lithium- polymer systems. Performance and life testing data for these systems are discussed. (GHH)

  8. Chemical Hydrides Ken Stroh, facilitator

    E-Print Network [OSTI]

    and reactor engineering · Development of process designs and PFDs · System integration issues · Technology Development Approach To Deliver Economic H2 via NaBH4 NaBH4 Natural Gas Solar Energy Hydro Power H2 Catalyst (theoretical) energy requirements including regeneration ­ Availability of basic components ­ Safety

  9. Commercial viability of hybrid vehicles : best household use and cross national considerations.

    SciTech Connect (OSTI)

    Santini, D. J.; Vyas, A. D.

    1999-07-16

    Japanese automakers have introduced hybrid passenger cars in Japan and will soon do so in the US. In this paper, we report how we used early computer simulation model results to compare the commercial viability of a hypothetical near-term (next decade) hybrid mid-size passenger car configuration under varying fuel price and driving patterns. The fuel prices and driving patterns evaluated are designed to span likely values for major OECD nations. Two types of models are used. One allows the ''design'' of a hybrid to a specified set of performance requirements and the prediction of fuel economy under a number of possible driving patterns (called driving cycles). Another provides an estimate of the incremental cost of the hybrid in comparison to a comparably performing conventional vehicle. In this paper, the models are applied to predict the NPV cost of conventional gasoline-fueled vehicles vs. parallel hybrid vehicles. The parallel hybrids are assumed to (1) be produced at high volume, (2) use nickel metal hydride battery packs, and (3) have high-strength steel bodies. The conventional vehicle also is assumed to have a high-strength steel body. The simulated vehicles are held constant in many respects, including 0-60 time, engine type, aerodynamic drag coefficient, tire rolling resistance, and frontal area. The hybrids analyzed use the minimum size battery pack and motor to meet specified 0-60 times. A key characteristic affecting commercial viability is noted and quantified: that hybrids achieve the most pronounced fuel economy increase (best use) in slow, average-speed, stop-and-go driving, but when households consistently drive these vehicles under these conditions, they tend to travel fewer miles than average vehicles. We find that hours driven is a more valuable measure than miles. Estimates are developed concerning hours of use of household vehicles versus driving cycle, and the pattern of minimum NPV incremental cost (or benefit) of selecting the hybrid over the conventional vehicle at various fuel prices is illustrated. These results are based on data from various OECD motions on fuel price, annual miles of travel per vehicle, and driving cycles assumed to be applicable in those nations. Scatter in results plotted as a function of average speed, related to details of driving cycles and the vehicles selected for analysis, is discussed.

  10. Hydrides of CeNi/sub 5/, MmNi/sub 5/, Ca/sub 0/ /sub 2/(Ce/sub 0/ /sub 65/Mm/sub 0/ /sub 35/)/sub 0/ /sub 8/Ni/sub 5/, Ca/sub 0/ /sub 2/Ce/sub 0/ /sub 8/Ni/sub 5/, Ca/sub 0/ /sub 2/Mm/sub 0/ /sub 8/Ni/sub 5/, and mixed CeNi/sub 5//MmNi/sub 5/

    SciTech Connect (OSTI)

    Lakner, J.F.; Chow, T.S.

    1982-09-01

    Six intermetallic alloys (CeNi/sub 5/, MmNi/sub 5/, Ca/sub 0/ /sub 2/(Ce/sub 0/ /sub 65/Mm/sub 0/ /sub 35/)/sub 0/ /sub 8/Ni/sub 5/, Ca/sub 0/ /sub 2/Ce/sub 0/ /sub 8/Ni/sub 5/, Ca/sub 0/ /sub 2/Mm/sub 0/ /sub 8/Ni/sub 5/, and a mixed alloy, CeNi/sub 5//MmNi/sub 5/) were investigated with respect to their suitability to provide high hydrogen capacity and their potential for use in providing substantial hydrogen pressure at both low and high temperatures. A second phase of our investigation dealt with ball-milling and hydriding and dehydriding cycles to produce fine particles for use in hydride powder transfer studies. A summary of several Van't Hoff plots is also included for hydride-forming alloys.

  11. Conversion of Russian Defense Enterprises to the production of rechargeable batteries and battery packs. Volume 1. Export trade information

    SciTech Connect (OSTI)

    1996-06-01

    This report, prepared by E-Tech, Inc., was funded by the U.S. Trade and Development Agency on behalf of the International Integration Association of Moscow, Russia. It presents the results of a study which was conducted to assess the economic and technical feasibility of converting the facilities of three Russian defense enterprises to the production of rechargeable batteries and battery packs for sale to the Russian domestic market and to international commercial markets. The three issues that are addressed in the report include: (1) Whether or not a project of this nature can be successful in present-day Russia; (2) Are the Russian enterprises identified for this study are capable of executing the project; and (3) Whether a U.S. company with extensive battery manufacturing experience can carry out a project in Russia. The report is divided into the following sections: (1) Executive Summary; (2) Introduction; (3) Background; (4) Technical Overview; (5) Market Overview; (6) Project Description; (7) Socioeconomic Benefits; (8) Legal Structure; (9) Appendices.

  12. Wiederholung p-CLIQUE ist A[1]-hart p-SET-PACKING ist A[1]-vollstandig p-HOM ist A[1]-vollstandig 1/24 A[1]-vollstandige Probleme (S. 106-114)

    E-Print Network [OSTI]

    Vollmer, Heribert

    Wiederholung p-CLIQUE ist A[1]-hart p-SET-PACKING ist A[1]-vollst¨andig p-HOM ist A[1]-vollst p-CLIQUE ist A[1]-hart p-SET-PACKING ist A[1]-vollst¨andig p-HOM ist A[1]-vollst¨andig 2/24 1 Wiederholung 2 p-CLIQUE ist A[1]-hart 3 p-SET-PACKING ist A[1]-vollst¨andig 4 p-HOM ist A[1]-vollst¨andig #12

  13. Thermal Characterization and Analysis of A123 Systems Battery Cells, Modules and Packs: Cooperative Research and Development Final Report, CRADA Number CRD-07-243

    SciTech Connect (OSTI)

    Pesaran, A.

    2012-03-01

    In support of the A123 Systems battery development program with USABC/DOE, NREL provided technical support in thermal characterization, analysis and management of batteries. NREL's effort was part of Energy Storage Project funded by DOE Vehicle Technologies Program. The purpose of this work was for NREL to perform thermal characterization and analysis of A123 Systems cells and modules with the aim for Al23 Systems to improve the thermal performance of their battery cells, modules and packs.

  14. United Way Pack - 2 

    E-Print Network [OSTI]

    Unknown

    2008-04-25

    records of that tradition?the Hebrew Bible accounts of the fall of Adam and Eve, the trials of Job, the weakening of Samson; the New Testament accounts of the temptation and crucifixion of Jesus, the doubts of the disciples, and the persecution of early... Clarkson, who insists on ?the vast difference of Faith from Reason, ? and how from Faiths royal Prerogative all its seed in Adam was saved, and all Reason in the fallen angel was damned? (190). For the most extreme of these writers, there is no positive...

  15. On Discrete Hyperbox Packing 

    E-Print Network [OSTI]

    Li, Xiafeng

    2010-01-14

    . . . . . . . . . . . . . . . . . . . . . . . . . . 57 1. O?ine Algorithms . . . . . . . . . . . . . . . . . . . . 58 2. Online Algorithms . . . . . . . . . . . . . . . . . . . . 63 B. EA vs. SOPT . . . . . . . . . . . . . . . . . . . . . . . . . 66 1. Lower Bounds... Bounds . . . . . . . . . . . . . . . . . . . . . . 72 C. EA vs. OPT . . . . . . . . . . . . . . . . . . . . . . . . . . 77 1. Unbounded Edge Length . . . . . . . . . . . . . . . . 77 2. Lower Bounds . . . . . . . . . . . . . . . . . . . . . . 80 3. Upper...

  16. Pack a Safe Lunch 

    E-Print Network [OSTI]

    Extension Food and Nutrition Specialists

    2009-01-06

    Lunches taken to school or work can be the cause of food-borne illness. To keep children safe, make sure hot foods are kept hot and cold foods are kept cold. Learn which foods are safe at room temperature, as well as other tips for lunch safety....

  17. Full Pack Inspection 

    E-Print Network [OSTI]

    Unknown

    2011-09-05

    fuller understanding of the trial and execution of ?that man of blood.? Alan Wharam. Murder in the Tower and Other Tales from the State Trials. Aldershot, U.K.: Ashgate, 2001. x + 286 pp. + 12 b&w illus. $84.95. Review by ELLEN J. JENKINS, ARKANSAS... TECH UNIVERSITY. The twists and turns of criminal misdeeds, murder mysteries, and court trials continue to fascinate and intrigue us, a phenomenon that explains the considerable increase over the past few years of cable and network television series...

  18. DataPackInvrpt

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-SessionsSouth DakotaRobbins and700, 1.Reports1 Rev.Metals Case Narrative

  19. Unusual Reaction of -Hydroxy r-Diazo Carbonyl Compounds with Cl3CCN/NaH

    E-Print Network [OSTI]

    Wang, Jianbo

    Wu, Daming Du, and Jianbo Wang*, Key Laboratory of Bioorganic Chemistry and Molecular Engineering-diazo carbonyl compounds.1,2 The migrating group can be a hydride, aryl, or acetoxy group. The Rh2(OAc)4-mediatedV. 1994, 94, 1091. (2) For examples of 1,2-hydride migration, see: (a) Taber, D. F.; Herr, R. J.; Pack, S

  20. A STUDY OF FUNDAMENTAL REACTION PATHWAYS FOR TRANSITION METAL ALKYL COMPLEXES. I. THE REACTION OF A NICKEL METHYL COMPLEX WITH ALKYNES. II. THE MECHANISM OF ALDEHYDE FORMATION IN THE REACTION OF A MOLYBDENUM HYDRIDE WITH MOLYBDENUM ALKYLS

    SciTech Connect (OSTI)

    Huggins, John Mitchell

    1980-06-01

    I. This study reports the rapid reaction under mild conditions of internal or terminal alkynes with methyl (acetyl~ acetonato) (triphenylphosphine) nickel (1) in either aromatic or ether solvents. In all cases vinylnickel products 2 are formed by insertion of the alkyne into the nickel=methyl bond. These complexes may be converted into a variety of organic products (e.g. alkenes, esters, vinyl halides) by treatment with appropriate reagents. Unsymmetrical alkynes give selectively the one regioisomer with the sterically largest substituent next to the nickel atom. In order to investigate the stereochemistry of the initial insertion, a x-ray diffraction study of the reaction of 1 with diphenylacetylene was carried out. This showed that the vinylnickel complex formed by overall trans insertion was the product of the reaction. Furthermore, subsequent slow isomerization of this complex, to a mixture of it and the corresponding cis isomer, demonstrated that this trans addition product is the kinetic product of the reaction. In studies with other alkynes, the product of trans addition was not always exclusively (or even predominantly) formed, but the ratio of the stereoisomers formed kinetically was substantially different from the thermodynamic ratio. Isotope labeling, added phosphine, and other experiments have allowed us to conclude that the mechanism of this reaction does involve initial cis addition. However, a coordinatively unsaturated vinylnickel complex is initially formed which can undergo rapid, phosphine-catalyzed cis-trans isomerization in competition with its conversion to the isolable phosphine-substituted kinetic reaction products. II. The reaction of CpMo(CO){sub 3}H (1a) with CpMo(CO){sub 3}R (2, R= CH{sub 3}, C{sub 2}H{sub 5}) at 50{degrees} C in THF gives the aldehyde RCHO and the dimers [CpMo(CO){sub 3}]{sub 2} (3a) and [CpMo(CO){sub 2}]{sub 2} (4a). Labeling one of the reactants with a methylcyclopentadienyl ligand it was possible to show that the mixed dimers MeCpMo(CO){sub 3}-(CO){sub 3}MoCp (3b) and MeCpMo(CO){sub 2}{triple_bond}(CO){sub 2}MoCp (4b) are the predominant kinetic products of the reaction. Additionally labeling the carbonyl ligands of 1a with {sup 13}CO led to the conclusion that all three of the carbonyl ligands in 1a end up in the tetracarbonyl dimers 4a if the reaction is carried out under a continuous purge of argon Trapping studies failed to find any evidence for the intermediacy of either [CpMo(CO){sub 3}]{sup -} or [CpMo(CO){sub 3}]{sup +} in this reaction. A mechanism is proposed that involves the initial migration of the alkyl ligand in 2 to CO forming an unsaturated acyl complex which reacts with 1a to give a binuclear complex containing a three center-two electron Mo-H-Mo bond. This complex then selectively looses a carbonyl from the acyl molybdenum, migrates the hydride to that same metal, and forms a metal-metal bond. This binuclear complex with the hydride and acyl ligands on one metal reductively eliminates aldehyde, and migrates a carbonyl ligand, to give 4a directly. The other product 3a is formed by addition of two molecules of free CO to 4a.

  1. Steady state and dynamic modeling of a packed bed reactor for the partial oxidation of methanol to formaldehyde: experimental results compared with model predictions

    SciTech Connect (OSTI)

    Schwedock, M.J.; Windes, L.C.; Ray, W.H.

    1985-01-01

    Heterogeneous and pseudohomogeneous models are compared to experimental data from a packed bed reactor for the partical oxidation of methanol to formaldehyde over an iron oxide-molybdenum oxide catalyst. Heat transfer parameters which were successful in matching data from experiments without reaction were not successful in matching temperature data from experiments with reaction. This made it necessary to decrease the fluid radial heat transfer to obtain good fit. A good fit was obtained for steady state composition profiles by optimizing selected frequency factors and the activation energy for methanol. A redox rate expression for the oxidation of formaldehyde to carbon monoxide was proposed since a simple first-order rate expression did not fit the data. The pseudohomogeneous model gave results similar to the heterogeneous model for both steady state and dynamic experiments and has been recommended for future experimental state estimation and control studies. 21 refs., 31 figs., 6 tabs.

  2. HTR-PROTEUS PEBBLE BED EXPERIMENTAL PROGRAM CORE 4: RANDOM PACKING WITH A 1:1 MODERATOR-TO-FUEL PEBBLE RATIO

    SciTech Connect (OSTI)

    John D. Bess; Leland M. Montierth

    2013-03-01

    In its deployment as a pebble bed reactor (PBR) critical facility from 1992 to 1996, the PROTEUS facility was designated as HTR-PROTEUS. This experimental program was performed as part of an International Atomic Energy Agency (IAEA) Coordinated Research Project (CRP) on the Validation of Safety Related Physics Calculations for Low Enriched HTGRs. Within this project, critical experiments were conducted for graphite moderated LEU systems to determine core reactivity, flux and power profiles, reaction-rate ratios, the worth of control rods, both in-core and reflector based, the worth of burnable poisons, kinetic parameters, and the effects of moisture ingress on these parameters. One benchmark experiment was evaluated in this report: Core 4. Core 4 represents the only configuration with random pebble packing in the HTR-PROTEUS series of experiments, and has a moderator-to-fuel pebble ratio of 1:1. Three random configurations were performed. The initial configuration, Core 4.1, was rejected because the method for pebble loading, separate delivery tubes for the moderator and fuel pebbles, may not have been completely random; this core loading was rejected by the experimenters. Cores 4.2 and 4.3 were loaded using a single delivery tube, eliminating the possibility for systematic ordering effects. The second and third cores differed slightly in the quantity of pebbles loaded (40 each of moderator and fuel pebbles), stacked height of the pebbles in the core cavity (0.02 m), withdrawn distance of the stainless steel control rods (20 mm), and withdrawn distance of the autorod (30 mm). The 34 coolant channels in the upper axial reflector and the 33 coolant channels in the lower axial reflector were open. Additionally, the axial graphite fillers used in all other HTR-PROTEUS configurations to create a 12-sided core cavity were not used in the randomly packed cores. Instead, graphite fillers were placed on the cavity floor, creating a funnel-like base, to discourage ordering effects during pebble loading. Core 4 was determined to be acceptable benchmark experiment.

  3. HTR-PROTEUS PEBBLE BED EXPERIMENTAL PROGRAM CORE 4: RANDOM PACKING WITH A 1:1 MODERATOR-TO-FUEL PEBBLE RATIO

    SciTech Connect (OSTI)

    John D. Bess; Leland M. Montierth

    2014-03-01

    In its deployment as a pebble bed reactor (PBR) critical facility from 1992 to 1996, the PROTEUS facility was designated as HTR-PROTEUS. This experimental program was performed as part of an International Atomic Energy Agency (IAEA) Coordinated Research Project (CRP) on the Validation of Safety Related Physics Calculations for Low Enriched HTGRs. Within this project, critical experiments were conducted for graphite moderated LEU systems to determine core reactivity, flux and power profiles, reaction-rate ratios, the worth of control rods, both in-core and reflector based, the worth of burnable poisons, kinetic parameters, and the effects of moisture ingress on these parameters. One benchmark experiment was evaluated in this report: Core 4. Core 4 represents the only configuration with random pebble packing in the HTR-PROTEUS series of experiments, and has a moderator-to-fuel pebble ratio of 1:1. Three random configurations were performed. The initial configuration, Core 4.1, was rejected because the method for pebble loading, separate delivery tubes for the moderator and fuel pebbles, may not have been completely random; this core loading was rejected by the experimenters. Cores 4.2 and 4.3 were loaded using a single delivery tube, eliminating the possibility for systematic ordering effects. The second and third cores differed slightly in the quantity of pebbles loaded (40 each of moderator and fuel pebbles), stacked height of the pebbles in the core cavity (0.02 m), withdrawn distance of the stainless steel control rods (20 mm), and withdrawn distance of the autorod (30 mm). The 34 coolant channels in the upper axial reflector and the 33 coolant channels in the lower axial reflector were open. Additionally, the axial graphite fillers used in all other HTR-PROTEUS configurations to create a 12-sided core cavity were not used in the randomly packed cores. Instead, graphite fillers were placed on the cavity floor, creating a funnel-like base, to discourage ordering effects during pebble loading. Core 4 was determined to be acceptable benchmark experiment.

  4. Packed-Bed Reactor Study of NETL Sample 196c for the Removal of Carbon Dioxide from Simulated Flue Gas Mixture

    SciTech Connect (OSTI)

    Hoffman, James S.; Hammache, Sonia; Gray, McMahan L.; Fauth Daniel J.; Pennline, Henry W.

    2012-04-24

    An amine-based solid sorbent process to remove CO2 from flue gas has been investigated. The sorbent consists of polyethylenimine (PEI) immobilized onto silica (SiO2) support. Experiments were conducted in a packed-bed reactor and exit gas composition was monitored using mass spectrometry. The effects of feed gas composition (CO2 and H2O), temperature, and simulated steam regeneration were examined for both the silica support as well as the PEI-based sorbent. The artifact of the empty reactor was also quantified. Sorbent CO2 capacity loading was compared to thermogravimetric (TGA) results to further characterize adsorption isotherms and better define CO2 working capacity. Sorbent stability was monitored by periodically repeating baseline conditions throughout the parametric testing and replacing with fresh sorbent as needed. The concept of the Basic Immobilized Amine Sorbent (BIAS) Process using this sorbent within a system where sorbent continuously flows between the absorber and regenerator was introduced. The basic tenet is to manipulate or control the level of moisture on the sorbent as it travels around the sorbent circulation path between absorption and regeneration stages to minimize its effect on regeneration heat duty.

  5. Thermodynamic properties of metal hydride nanostructures

    E-Print Network [OSTI]

    Bérubé, Vincent, Ph. D. Massachusetts Institute of Technology

    2009-01-01

    Hydrogen is considered a good energy carrier candidate for future automotive applications because of its high abundance and its potential role in a carbon-free cycle. The high gravimetric and volumetric storage capacities ...

  6. Activated Aluminum Hydride Hydrogen Storage Compositions - Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room News Publications Traditional Knowledge KiosksAbout AwardedAcronyms This is a quick

  7. Regeneration of Aluminum Hydride - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMassR&D100 Winners * ImpactsandRegarding Confinement Resonances Print When

  8. Regeneration of aluminum hydride - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMassR&D100 Winners * ImpactsandRegarding Confinement Resonances Print When268,288 Site

  9. Metal Hydride Storage Materials | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuelsof EnergyApril 2014 |Department ofMay 2013 MonthlyMessage from New LPOStorage

  10. HTR-PROTEUS Pebble Bed Experimental Program Cores 1, 1A, 2, and 3: Hexagonal Close Packing with a 1:2 Moderator-to-Fuel Pebble Ratio

    SciTech Connect (OSTI)

    John D. Bess; Barbara H. Dolphin; James W. Sterbentz; Luka Snoj; Igor Lengar; Oliver Köberl

    2012-03-01

    In its deployment as a pebble bed reactor (PBR) critical facility from 1992 to 1996, the PROTEUS facility was designated as HTR-PROTEUS. This experimental program was performed as part of an International Atomic Energy Agency (IAEA) Coordinated Research Project (CRP) on the Validation of Safety Related Physics Calculations for Low Enriched HTGRs. Within this project, critical experiments were conducted for graphite moderated LEU systems to determine core reactivity, flux and power profiles, reaction-rate ratios, the worth of control rods, both in-core and reflector based, the worth of burnable poisons, kinetic parameters, and the effects of moisture ingress on these parameters. Four benchmark experiments were evaluated in this report: Cores 1, 1A, 2, and 3. These core configurations represent the hexagonal close packing (HCP) configurations of the HTR-PROTEUS experiment with a moderator-to-fuel pebble ratio of 1:2. Core 1 represents the only configuration utilizing ZEBRA control rods. Cores 1A, 2, and 3 use withdrawable, hollow, stainless steel control rods. Cores 1 and 1A are similar except for the use of different control rods; Core 1A also has one less layer of pebbles (21 layers instead of 22). Core 2 retains the first 16 layers of pebbles from Cores 1 and 1A and has 16 layers of moderator pebbles stacked above the fueled layers. Core 3 retains the first 17 layers of pebbles but has polyethylene rods inserted between pebbles to simulate water ingress. The additional partial pebble layer (layer 18) for Core 3 was not included as it was used for core operations and not the reported critical configuration. Cores 1, 1A, 2, and 3 were determined to be acceptable benchmark experiments.

  11. HTR-PROTEUS Pebble Bed Experimental Program Cores 1, 1A, 2, and 3: Hexagonal Close Packing with a 1:2 Moderator-to-Fuel Pebble Ratio

    SciTech Connect (OSTI)

    John D. Bess; Barbara H. Dolphin; James W. Sterbentz; Luka Snoj; Igor Lengar; Oliver Köberl

    2013-03-01

    In its deployment as a pebble bed reactor (PBR) critical facility from 1992 to 1996, the PROTEUS facility was designated as HTR-PROTEUS. This experimental program was performed as part of an International Atomic Energy Agency (IAEA) Coordinated Research Project (CRP) on the Validation of Safety Related Physics Calculations for Low Enriched HTGRs. Within this project, critical experiments were conducted for graphite moderated LEU systems to determine core reactivity, flux and power profiles, reaction-rate ratios, the worth of control rods, both in-core and reflector based, the worth of burnable poisons, kinetic parameters, and the effects of moisture ingress on these parameters. Four benchmark experiments were evaluated in this report: Cores 1, 1A, 2, and 3. These core configurations represent the hexagonal close packing (HCP) configurations of the HTR-PROTEUS experiment with a moderator-to-fuel pebble ratio of 1:2. Core 1 represents the only configuration utilizing ZEBRA control rods. Cores 1A, 2, and 3 use withdrawable, hollow, stainless steel control rods. Cores 1 and 1A are similar except for the use of different control rods; Core 1A also has one less layer of pebbles (21 layers instead of 22). Core 2 retains the first 16 layers of pebbles from Cores 1 and 1A and has 16 layers of moderator pebbles stacked above the fueled layers. Core 3 retains the first 17 layers of pebbles but has polyethylene rods inserted between pebbles to simulate water ingress. The additional partial pebble layer (layer 18) for Core 3 was not included as it was used for core operations and not the reported critical configuration. Cores 1, 1A, 2, and 3 were determined to be acceptable benchmark experiments.

  12. Pack & Cap: Adaptive DVFS and Thread Packing Under Power Caps

    E-Print Network [OSTI]

    Coskun, Ayse

    _reda@brown.edu ABSTRACT The ability to cap peak power consumption is a desirable feature in modern data centers for energy control decisions in order to maximize performance within a power budget. In or- der to capture to DVFS alone and reduces workload energy consumption by an average of 51.6% compared to existing control

  13. Comparison of advanced battery technologies for electric vehicles

    SciTech Connect (OSTI)

    Dickinson, B.E.; Lalk, T.R.; Swan, D.H.

    1993-12-31

    Battery technologies of different chemistries, manufacture and geometry were evaluated as candidates for use in Electric Vehicles (EV). The candidate batteries that were evaluated include four single cell and seven multi-cell modules representing four technologies: Lead-Acid, Nickel-Cadmium, Nickel-Metal Hydride and Zinc-Bromide. A standard set of testing procedures for electric vehicle batteries, based on industry accepted testing procedures, and any tests which were specific to individual battery types were used in the evaluations. The batteries were evaluated by conducting performance tests, and by subjecting them to cyclical loading, using a computer controlled charge--discharge cycler, to simulate typical EV driving cycles. Criteria for comparison of batteries were: performance, projected vehicle range, cost, and applicability to various types of EVs. The four battery technologies have individual strengths and weaknesses and each is suited to fill a particular application. None of the batteries tested can fill every EV application.

  14. Nanostructured material for advanced energy storage : magnesium battery cathode development.

    SciTech Connect (OSTI)

    Sigmund, Wolfgang M.; Woan, Karran V.; Bell, Nelson Simmons

    2010-11-01

    Magnesium batteries are alternatives to the use of lithium ion and nickel metal hydride secondary batteries due to magnesium's abundance, safety of operation, and lower toxicity of disposal. The divalency of the magnesium ion and its chemistry poses some difficulties for its general and industrial use. This work developed a continuous and fibrous nanoscale network of the cathode material through the use of electrospinning with the goal of enhancing performance and reactivity of the battery. The system was characterized and preliminary tests were performed on the constructed battery cells. We were successful in building and testing a series of electrochemical systems that demonstrated good cyclability maintaining 60-70% of discharge capacity after more than 50 charge-discharge cycles.

  15. Improving Battery Design with Electro-Thermal Modeling

    SciTech Connect (OSTI)

    Bharathan, D.; Pesaran, A.; Vlahinos, A.; Kim, G.-H.

    2005-01-01

    Operating temperature greatly affects the performance and life of batteries in electric and hybrid vehicles. Increased attention is necessary to battery thermal management. Electrochemical models and finite element analysis tools are available for predicting the thermal performance of batteries, but each has limitations. In this study we describe an electro-thermal finite element approach that predicts the thermal performance of a cell or module with realistic geometry. To illustrate the process, we simulated the thermal performance of two generations of Panasonic prismatic nickel-metal-hydride modules used in the Toyota Prius. The model showed why the new generation of Panasonic modules had better thermal performance. Thermal images from two battery modules under constant current discharge indicate that the model predicts the experimental trend reasonably well.

  16. Triangle Packing with Constraint Programming

    E-Print Network [OSTI]

    Prosser, P.

    Prosser,P. 9th International Workshop on Constraint Modelling and Reformulation (ModRef 2010) pp 1-15

  17. Multidimensional Cube Packing Y. Kohayakawa

    E-Print Network [OSTI]

    Kohayakawa, Yoshiharu

    -dimen- sional cubes and (an unlimited quantity of) d-dimensional unit-capacity cubes, called bins, find´istica -- Universidade de S~ao Paulo. Rua do Mat~ao, 1010 -- 05508­090 -- S~ao Paulo­SP -- Brazil, {yoshi­ SP -- Brazil, fkm@ic.unicamp.br. § Verity, Inc., 892 Ross Drive, Sunnyvale, CA 94089, USA, pragh

  18. Combinatorial Optimization: Packing and Covering

    E-Print Network [OSTI]

    Cornuejols, Gerard P.

    T-Cuts . . . . . . . . . . . . . . . . . . . . . . . 30 2.2.1 Theorems of Seymour and Lov . . . . . . . . . . . . 66 5.4 Binary Clutters . . . . . . . . . . . . . . . . . . . . . . . 69 5.4.1 Seymour's Conjecture . . . . . . . . . . . . . . . 71 5.4.2 Seymour's MFMC Theorem . . . . . . . . . . . . 72 6 0, ±1 Matrices and Integral Polyhedra 73

  19. Combinatorial Optimization: Packing and Covering

    E-Print Network [OSTI]

    Cornuejols, Gerard P.

    ­Cuts . . . . . . . . . . . . . . . . . . . . . . . 30 2.2.1 Theorems of Seymour and Lovâ??asz . . . . . . . . . 30 2.2.2 More Min Max Results . . . . . . . . . . . . . . . . . . . . . . . 69 5.4.1 Seymour's Conjecture . . . . . . . . . . . . . . . 71 5.4.2 Seymour's MFMC Theorem

  20. Development of Production-Intent Plug-In Hybrid Vehicle Using Advanced Lithium-Ion Battery Packs with Deployment to a Demonstration Fleet

    SciTech Connect (OSTI)

    No, author

    2013-09-29

    The primary goal of this project was to speed the development of one of the first commercially available, OEM-produced plug-in hybrid electric vehicles (PHEV). The performance of the PHEV was expected to double the fuel economy of the conventional hybrid version. This vehicle program incorporated a number of advanced technologies, including advanced lithium-ion battery packs and an E85-capable flex-fuel engine. The project developed, fully integrated, and validated plug-in specific systems and controls by using GM’s Global Vehicle Development Process (GVDP) for production vehicles. Engineering Development related activities included the build of mule vehicles and integration vehicles for Phases I & II of the project. Performance data for these vehicles was shared with the U.S. Department of Energy (DOE). The deployment of many of these vehicles was restricted to internal use at GM sites or restricted to assigned GM drivers. Phase III of the project captured the first half or Alpha phase of the Engineering tasks for the development of a new thermal management design for a second generation battery module. The project spanned five years. It included six on-site technical reviews with representatives from the DOE. One unique aspect of the GM/DOE collaborative project was the involvement of the DOE throughout the OEM vehicle development process. The DOE gained an understanding of how an OEM develops vehicle efficiency and FE performance, while balancing many other vehicle performance attributes to provide customers well balanced and fuel efficient vehicles that are exciting to drive. Many vehicle content and performance trade-offs were encountered throughout the vehicle development process to achieve product cost and performance targets for both the OEM and end customer. The project team completed two sets of PHEV development vehicles with fully integrated PHEV systems. Over 50 development vehicles were built and operated for over 180,000 development miles. The team also completed four GM engineering development Buy-Off rides/milestones. The project included numerous engineering vehicle and systems development trips including extreme hot, cold and altitude exposure. The final fuel economy performance demonstrated met the objectives of the PHEV collaborative GM/DOE project. Charge depletion fuel economy of twice that of the non-PHEV model was demonstrated. The project team also designed, developed and tested a high voltage battery module concept that appears to be feasible from a manufacturability, cost and performance standpoint. The project provided important product development and knowledge as well as technological learnings and advancements that include multiple U.S. patent applications.

  1. An autographic device for the film pack

    E-Print Network [OSTI]

    Hood, George J. (George Jô ssen), 1877-1965

    1920-01-01

    in the dark by the face of a luminous watch. The exposure was one- half hour. Tne record on the print shown h ere was made "by usi ng the light that came through the lens of the camera when the picture v/as taken. The record was w ritten on a... to holders for photo­ graphically sensitive elements and a method and means for light recording designations on the contained sensitive element without utilizing a camera lens, and has for its ob­ ject the provision of a simple, compact, easily...

  2. Test problems for quasi-satellite packing????

    E-Print Network [OSTI]

    Administrator

    2008-10-14

    background of the layout optimization problem of a simplified international .... system is used to calculate the moment of inertia of the object in relation to its.

  3. [Band electronic structures and crystal packing forces

    SciTech Connect (OSTI)

    Not Available

    1993-01-01

    We investigated the electronic and structural properties of low-dimensional materials and explored the structure-property correlations governing their physical properties. Progress was made on how to interpret the scanning tunneling microscopy and atomic force microscopy images of layered materials and on how to account for charge density wave instabilities in 2-D metals. Materials studied included transition metal chalcogenides, transition metal halides, organic conducting salts, Mo bronzes, A[sub 2]PdH[sub 2], fullerenes, squarate tetrahydrate polymers Fe, Cu(C[sub 4]O[sub 4])4[center dot]H[sub 2]O, BEDT salts, etc.

  4. Efficient Solvers for Packing Puzzles Tom Verhoeff

    E-Print Network [OSTI]

    Verhoeff, Tom

    210 3 4 5 CBA 210 3 4 5 CBA 210 3 4 5 CBACBA 3 4 5 210210 3 4 5 CBACBA 3 4 5 210 0 1 2 543 A B C 0 1 2

  5. Automated packing systems: Review of industrial implementations.

    E-Print Network [OSTI]

    Whelan, Paul F.

    is built up by considering partial hide in an efficient manner, so as to minimize the leather waste, before they are automatically cut

  6. Packing a Safe School Lunch (Spanish) 

    E-Print Network [OSTI]

    Van Laanen, Peggy

    2001-10-22

    para causar enfemedad. Algunos alimentos deben mantenerse fr?os (a 40 gra- dos F o menos) o calientes (a 140 grados F o mas). Estos son alimentos perecederos tales como carne, aves, mariscos, huevos y productos l?cteos (incluyen- do el yogurt). Lo m...?s importante para preparar una comida sana, es mantener fr?os los alimentos fr?os y caliente los alimentos calientes y mantener todo limpio. A continuaci?n, el por qu? y el c?mo. Para reproducirse, las bacterias que causan enferme- dad alimenticia necesitan...

  7. A High-Performance PHEV Battery Pack

    Broader source: Energy.gov [DOE]

    2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation

  8. Exactly solving packing problems with fragmentation

    E-Print Network [OSTI]

    2015-04-13

    Apr 13, 2015 ... split overhead, in terms of both solutions quality and computing effort. ..... it to optimality, and we use dual information to search for variables having negative ... otherwise, in order to find a proven global optimum, we enter a.

  9. Cooking with Canned Tuna (packed in water) 

    E-Print Network [OSTI]

    Anding, Jenna

    2008-12-09

    four servings. Tuna Macaroni Casserole (makes 4 to 6 servings) What you need 12-ounce can tuna, drained 2 10?-ounce cans cream of mushroom soup 1 cup frozen green peas (if you like) black pepper (to taste) 2 cups cooked...) What you need 7?-ounce box macaroni and cheese dinner *milk and margarine to make the macaroni and cheese ? cup milk 12 ounces canned tuna in water, drained 10?-ounce can cream of mushroom soup *Follow the directions on the package...

  10. GM Li-Ion Battery Pack Manufacturing

    Broader source: Energy.gov [DOE]

    2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  11. Incorporation of Hydride Nuclear Fuels in Commercial Light Water Reactors

    E-Print Network [OSTI]

    Terrani, Kurt Amir

    2010-01-01

    re- actor (PWR) and boiling-water reactor (BWR) designsin integral boiling water super heat reactors. Technical

  12. Incorporation of Hydride Nuclear Fuels in Commercial Light Water Reactors

    E-Print Network [OSTI]

    Terrani, Kurt Amir

    2010-01-01

    Fundamental aspects of nuclear reactor fuel elements.Unlike permanent nuclear reactor core components, nuclearof the first nuclear reactors, commercial nuclear fuel still

  13. Method for preparing hydride configurations and reactive metal surfaces

    DOE Patents [OSTI]

    Silver, Gary L. (Centerville, OH)

    1988-08-16

    A method for preparing highly hydrogen-reactive surfaces on metals which normally require substantial heating, high pressures, or an extended induction period, which involves pretreatment of said surfaces with either a non-oxidizing acid or hydrogen gas to form a hydrogen-bearing coating on said surfaces, and subsequently heating said coated metal in the absence of moisture and oxygen for a period sufficient to decompose said coating and cooling said metal to room temperature. Surfaces so treated will react almost instantaneously with hydrogen gas at room temperature and low pressure. The method is particularly applicable to uranium, thorium, and lanthanide metals.

  14. Project Profile: Engineering a Novel High Temperature Metal Hydride...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Thermochemical Storage (CSP: ELEMENTS) funding program, is developing a concept for high energy density thermochemical energy storage for concentrating solar power (CSP) using...

  15. ANL Capabilities for Hydrogen Storage: Chemical Hydride Center

    Broader source: Energy.gov [DOE]

    Presentation from the Hydrogen Storage Pre-Solicitation Meeting held June 19, 2003 in Washington, DC.

  16. Steady state thermal hydraulic analysis of hydride fueled BWRs

    E-Print Network [OSTI]

    Ferroni, Paolo, Ph. D. Massachusetts Institute of Technology

    2006-01-01

    (cont.) Since the results obtained in the main body of the analysis account only for thermal-hydraulic constraints, an estimate of the power reduction due to the application of neutronic constraints is also performed. This ...

  17. Incorporation of Hydride Nuclear Fuels in Commercial Light Water Reactors

    E-Print Network [OSTI]

    Terrani, Kurt Amir

    2010-01-01

    6.3 Oxide layer characteristics . . . . . . . . . . . . .electron microscopy of the oxide layer grown on the sur-conditions. Different oxide layers were grown on the surface

  18. Incorporation of Hydride Nuclear Fuels in Commercial Light Water Reactors

    E-Print Network [OSTI]

    Terrani, Kurt Amir

    2010-01-01

    Incoherent Quasielastic Neutron Scattering Study of Hydrogenand R.J. Elliott. Neutron scattering from a liquid on a jumpHempelmann. Quasielastic Neutron Scattering and Solid State

  19. Incorporation of Hydride Nuclear Fuels in Commercial Light Water Reactors

    E-Print Network [OSTI]

    Terrani, Kurt Amir

    2010-01-01

    1.4.3 Fission gas release . . . . . . . . . . . . 1.4.4Top: Fission-gas-release to birth-rate ratio as a functionBottom: Fractional fission-gas release as a function of

  20. Process for production of an aluminum hydride compound

    SciTech Connect (OSTI)

    Allen, Nathan Tait; Butterick, III, Robert; Chin, Arthur Achhing; Miller, Dean Michael; Molzahn, David Craig

    2013-08-06

    A compound of formula M(AlH.sub.3OR.sup.1).sub.y, wherein R.sup.1 is phenyl substituted by at least one of: (i) an alkoxy group having from one to six carbon atoms; and (ii) an alkyl group having from three to twelve carbon atoms; wherein M is an alkali metal, Be or Mg; and y is one or two.

  1. Virtual Center of Excellence for Hydrogen Storage- Chemical Hydrides

    Broader source: Energy.gov [DOE]

    Presentation from the Hydrogen Storage Pre-Solicitation Meeting held June 19, 2003 in Washington, DC.

  2. Proposed Virtual Center for Excellence for Metal Hydride Development

    Broader source: Energy.gov [DOE]

    Presentation from the Hydrogen Storage Pre-Solicitation Meeting held June 19, 2003 in Washington, DC.

  3. Non-stoichiometric AB5 alloys for metal hydride electrodes

    DOE Patents [OSTI]

    Reilly, James J. (Bellport, NY); Adzic, Gordana D. (Setauket, NY); Johnson, John R. (Calverton, NY); Vogt, Thomas (Cold Spring Harbor, NY); McBreen, James (Bellport, NY)

    2001-01-01

    The present invention provides a non-stoichiometric alloy comprising a composition having the formula AB.sub.5+X an atomic ratio wherein A is selected from the group consisting of the rare earth metals, yttrium, mischmetal, or a combination thereof; B is nickel and tin, or nickel and tin and at least a third element selected from the group consisting of the elements in group IVA of the periodic table, aluminum, manganese, iron, cobalt, copper, antimony or a combination thereof; X is greater than 0 and less than or equal to about 2.0; and wherein at least one substituted A site is occupied by at least one of the B elements. An electrode incorporating said alloy and an electrochemical cell incorporating said electrode are also described.

  4. THE ABSORPTION OF HYDROGEN ON LOW PRESSURE HYDRIDE MATERIALS

    SciTech Connect (OSTI)

    Morgan, G.; Korinko, P.

    2012-04-03

    For this study, hydrogen getter materials (Zircaloy-4 and pure zirconium) that have a high affinity for hydrogen (and low overpressure) have been investigated to determine the hydrogen equilibrium pressure on Zircaloy-4 and pure zirconium. These materials, as with most getter materials, offered significant challenges to overcome given the low hydrogen equilibrium pressure for the temperature range of interest. Hydrogen-zirconium data exists for pure zirconium at 500 C and the corresponding hydrogen overpressure is roughly 0.01 torr. This manuscript presents the results of the equilibrium pressures for the absorption and desorption of hydrogen on zirconium materials at temperatures ranging from 400 C to 600 C. The equilibrium pressures in this temperature region range from 150 mtorr at 600 C to less than 0.1 mtorr at 400 C. It has been shown that the Zircaloy-4 and zirconium samples are extremely prone to surface oxidation prior to and during heating. This oxidation precludes the hydrogen uptake, and therefore samples must be heated under a minimum vacuum of 5 x 10{sup -6} torr. In addition, the Zircaloy-4 samples should be heated at a sufficiently low rate to maintain the system pressure below 0.5 mtorr since an increase in pressure above 0.5 mtorr could possibly hinder the H{sub 2} absorption kinetics due to surface contamination. The results of this study and the details of the testing protocol will be discussed.

  5. An inverted hydride-fueled pressurized water reactor concept

    E-Print Network [OSTI]

    Ferroni, Paolo, Ph. D. Massachusetts Institute of Technology

    2010-01-01

    Previous studies conducted at MIT showed that power performance of typical pin geometry PWRs are limited by three main constraints: core pressure drop, critical heat flux (CHF) and fretting phenomena of the fuel rods against ...

  6. Isotope exchange kinetics in metal hydrides I : TPLUG model.

    SciTech Connect (OSTI)

    Larson, Rich; James, Scott Carlton; Nilson, Robert H.

    2011-05-01

    A one-dimensional isobaric reactor model is used to simulate hydrogen isotope exchange processes taking place during flow through a powdered palladium bed. This simple model is designed to serve primarily as a platform for the initial development of detailed chemical mechanisms that can then be refined with the aid of more complex reactor descriptions. The one-dimensional model is based on the Sandia in-house code TPLUG, which solves a transient set of governing equations including an overall mass balance for the gas phase, material balances for all of the gas-phase and surface species, and an ideal gas equation of state. An energy equation can also be solved if thermodynamic properties for all of the species involved are known. The code is coupled with the Chemkin package to facilitate the incorporation of arbitrary multistep reaction mechanisms into the simulations. This capability is used here to test and optimize a basic mechanism describing the surface chemistry at or near the interface between the gas phase and a palladium particle. The mechanism includes reversible dissociative adsorptions of the three gas-phase species on the particle surface as well as atomic migrations between the surface and the bulk. The migration steps are more general than those used previously in that they do not require simultaneous movement of two atoms in opposite directions; this makes possible the creation and destruction of bulk vacancies and thus allows the model to account for variations in the bulk stoichiometry with isotopic composition. The optimization code APPSPACK is used to adjust the mass-action rate constants so as to achieve the best possible fit to a given set of experimental data, subject to a set of rigorous thermodynamic constraints. When data for nearly isothermal and isobaric deuterium-to-hydrogen (D {yields} H) and hydrogen-to-deuterium (H {yields} D) exchanges are fitted simultaneously, results for the former are excellent, while those for the latter show pronounced deviations at long times. These discrepancies can be overcome by postulating the presence of a surface poison such as carbon monoxide, but this explanation is highly speculative. When the method is applied to D {yields} H exchanges intentionally poisoned by known amounts of CO, the fitting results are noticeably degraded from those for the nominally CO-free system but are still tolerable. When TPLUG is used to simulate a blowdown-type experiment, which is characterized by large and rapid changes in both pressure and temperature, discrepancies are even more apparent. Thus, it can be concluded that the best use of TPLUG is not in simulating realistic exchange scenarios, but in extracting preliminary estimates for the kinetic parameters from experiments in which variations in temperature and pressure are intentionally minimized.

  7. Activated aluminum hydride hydrogen storage compositions and uses thereof -

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 OutreachProductswsicloudwsicloudden DocumentationAccommodationsRegister / Vol. 72, No. 39 1S1!4T op Document:

  8. Designation of Sites for Remedial Action - Metal Hydrides, Beverly,

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-SessionsSouth DakotaRobbins and Myers CoMadison -T: Designation of Sites for

  9. Neutron Irradiation of Hydrided Cladding Material in HFIR Summary of

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i nAand DOEDepartment ofProgramImports byGeothermalDepartment of

  10. Hydride Rim Formation in Unirradiated Zircaloy | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12,ExecutiveFinancingR Walls -

  11. Final Report for the DOE Metal Hydride Center of Excellence

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12, 2015Executive Order14,Energy 9,UNIVERSITY OF TEXAS AT AUSTINGrid12-0786

  12. The Role of Impurities in the Complex Hydrides

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankADVANCEDInstallers/ContractorsPhotovoltaicsState of Pennsylvania U.S.The6,Category 2TheImpurities in the

  13. Structural stability of 1100{degree}C heated Pd/k during absorption cycling in protium

    SciTech Connect (OSTI)

    Fisher, I.A.

    1993-03-12

    Pd/k is a hydride forming packing material which is used in the Thermal Cycling Absorption Process (TCAP). Palladium is supported on kieselguhr to create a packing material which will provide adequate void space to prevent excessive pressure drops and flow restrictions. The use of unsupported palladium would result in blockage of columns and clogging of filters due to the small particle size of unsupported palladium hydride powder. During pilot scale demonstrations, it was noted that the Pd/k packing material had degraded causing severe flow restrictions within the TCAP column. A solution to the problem involved the heating of Pd/k at 1,110{degree}C to strengthen the packing material, and render it more resistant to breakdown. The 1, 100{degree}C heated Pd/k has been shown to be more resistant to mechanical breakdown than the Pd/k prior to heat treatment. Two primary modes of Pd/k particle degradation have been identified: mechanical breakdown caused by particle fluidization and degradation caused by absorption/desorption cycling. Absorption/desorption cycling causes the palladium particles within the packing to expanded and contract upon formation and decomposition of the hydride, respectively. This expansion and contraction causes large localized stresses within the packing material, which if these stresses can not be accommodated within the packing will cause the material to crack and degrade. The purpose of this report is to document the results of the absorption/desorption cycling of 1,100{degree}C heated Pd/k and compare these results to the results obtained from the absorption/desorption cycling of Pd/k which had not been heated at 1, 100{degree}C.

  14. Structural stability of 1100[degree]C heated Pd/k during absorption cycling in protium. [Palladium supported on kieselguhr

    SciTech Connect (OSTI)

    Fisher, I.A.

    1993-03-12

    Pd/k is a hydride forming packing material which is used in the Thermal Cycling Absorption Process (TCAP). Palladium is supported on kieselguhr to create a packing material which will provide adequate void space to prevent excessive pressure drops and flow restrictions. The use of unsupported palladium would result in blockage of columns and clogging of filters due to the small particle size of unsupported palladium hydride powder. During pilot scale demonstrations, it was noted that the Pd/k packing material had degraded causing severe flow restrictions within the TCAP column. A solution to the problem involved the heating of Pd/k at 1,110[degree]C to strengthen the packing material, and render it more resistant to breakdown. The 1, 100[degree]C heated Pd/k has been shown to be more resistant to mechanical breakdown than the Pd/k prior to heat treatment. Two primary modes of Pd/k particle degradation have been identified: mechanical breakdown caused by particle fluidization and degradation caused by absorption/desorption cycling. Absorption/desorption cycling causes the palladium particles within the packing to expanded and contract upon formation and decomposition of the hydride, respectively. This expansion and contraction causes large localized stresses within the packing material, which if these stresses can not be accommodated within the packing will cause the material to crack and degrade. The purpose of this report is to document the results of the absorption/desorption cycling of 1,100[degree]C heated Pd/k and compare these results to the results obtained from the absorption/desorption cycling of Pd/k which had not been heated at 1, 100[degree]C.

  15. Nickel anode electrode

    DOE Patents [OSTI]

    Singh, Prabhakar (Bethel, CT); Benedict, Mark (Monroe, CT)

    1987-01-01

    A nickel anode electrode fabricated by oxidizing a nickel alloying material to produce a material whose exterior contains nickel oxide and whose interior contains nickel metal throughout which is dispersed the oxide of the alloying material and by reducing and sintering the oxidized material to form a product having a nickel metal exterior and an interior containing nickel metal throughout which is dispersed the oxide of the alloying material.

  16. Measured Black Carbon Deposition on the Sierra Nevada Snow Pack and Implication for Snow Pack Retreat

    E-Print Network [OSTI]

    Hadley, O.L.

    2010-01-01

    on duration of mountain snow cover, Geophysical Researchresponse from black carbon in snow, Journal of Geophysicaltypes - light extinction in snow, Journal De Physique, 48,

  17. Packing Instructions --Class 6 --Toxic and Infectious Substances PACKING INSTRUCTION 650

    E-Print Network [OSTI]

    Feig, Andrew

    using internal hydraulic or pneumatic pressure (gauge) or external vaccum test methods. Internal hydraulic or pneumatic pressure can be applied in most cases as the required pressure differential can be achieved under most circumstances. An external vacuum test is not acceptable if the specified pressure

  18. Measured Black Carbon Deposition on the Sierra Nevada Snow Pack and Implication for Snow Pack Retreat

    E-Print Network [OSTI]

    Hadley, O.L.

    2010-01-01

    using EcoTech, automated rain water samplers (RWS) modifiedof collected snow and rain water were filtered throughcm 3 (kg) of snow or rain water and P is the total measured

  19. Measured Black Carbon Deposition on the Sierra Nevada Snow Pack and Implication for Snow Pack Retreat

    E-Print Network [OSTI]

    Hadley, O.L.

    2010-01-01

    BC emissions in California, transport of pollution from Asiain California. The GATOR-GCMOM (Gas, Aerosol, Transport,

  20. A review of battery life-cycle analysis : state of knowledge and critical needs.

    SciTech Connect (OSTI)

    Sullivan, J. L.; Gaines, L.; Energy Systems

    2010-12-22

    A literature review and evaluation has been conducted on cradle-to-gate life-cycle inventory studies of lead-acid, nickel-cadmium, nickel-metal hydride, sodium-sulfur, and lithium-ion battery technologies. Data were sought that represent the production of battery constituent materials and battery manufacture and assembly. Life-cycle production data for many battery materials are available and usable, though some need updating. For the remaining battery materials, lifecycle data either are nonexistent or, in some cases, in need of updating. Although battery manufacturing processes have occasionally been well described, detailed quantitative information on energy and material flows is missing. For all but the lithium-ion batteries, enough constituent material production energy data are available to approximate material production energies for the batteries, though improved input data for some materials are needed. Due to the potential benefit of battery recycling and a scarcity of associated data, there is a critical need for life-cycle data on battery material recycling. Either on a per kilogram or per watt-hour capacity basis, lead-acid batteries have the lowest production energy, carbon dioxide emissions, and criteria pollutant emissions. Some process-related emissions are also reviewed in this report.

  1. New materials for batteries and fuel cells. Materials Research Society symposium proceedings, Volume 575

    SciTech Connect (OSTI)

    Doughty, D.H.; Nazar, L.F.; Arakawa, Masayasu; Brack, H.P.; Naoi, Katsuhiko

    2000-07-01

    This proceedings volume is organized into seven sections that reflect the materials systems and issues of electrochemical materials R and D in batteries, fuel cells, and capacitors. The first three parts are largely devoted to lithium ion rechargeable battery materials since that electrochemical system has received much of the attention from the scientific community. Part 1 discusses cathodes for lithium ion rechargeable batteries as well as various other battery systems. Part 2 deals with electrolytes and cell stability, and Part 3 discusses anode developments, focusing on carbon and metal oxides. Part 4 focuses on another rechargeable system that has received substantial interest, nickel/metal hydride battery materials. The next two parts discuss fuel cells--Part 5 deals with Proton Exchange Membrane (PEM) fuel cells, and Part 6 discusses oxide materials for solid oxide fuel cells. The former has the benefit of operating around room temperature, whereas the latter has the benefit of operating with a more diverse (non-hydrogen) fuel source. Part 7 presents developments in electrochemical capacitors, termed Supercapacitors. These devices are receiving renewed interest and have shown substantial improvements in the past few years. In all, the results presented at this symposium gave a deeper understanding of the relationship between synthesis, properties, and performance of power source materials. Papers are processed separately for inclusion on the data base.

  2. Generalized Balanced Tournament Packings and Optimal Equitable Symbol

    E-Print Network [OSTI]

    Chee, Yeow Meng

    to applications in sustainable energy strategies, specifically in smart grids (see [15, 17, 25, 34]). However's analysis to general block codes and motivated the study of equitable symbol weight codes (ESWCs

  3. A Combinatorial Characterization of Higher-Dimensional Orthogonal Packing

    E-Print Network [OSTI]

    Fekete, Sándor P.

    problems. In the context of technical computer science, Teich, Fekete, and Schepers (2001) consider.fekete@tu-bs.de Jorg Schepers IBM Germany Gustav-Heinemann-Ufer 120/122 D{50968 Koln GERMANY schepers@de.ibm stock problem. It arises in many industries, where steel, glass, wood, or textile materials are cut

  4. Packing efficiency and accessible surface area of crumpled graphene

    E-Print Network [OSTI]

    Cranford, Steven Wayne

    Graphene holds promise as an ultracapacitor due to its high specific surface area and intrinsic capacitance. To exploit both, a maximum surface area must be accessible while the two-dimensional (2D) graphene is deformed ...

  5. Granular impact and the critical packing state Paul Umbanhowar

    E-Print Network [OSTI]

    Goldman, Daniel I.

    during collisions of spheres with granular media reveal a pronounced and nontrivial dependence on volume phenomenological models fail to capture the observed impact force for most ; only near cps is force separable into additive terms linear in depth and quadratic in velocity. At fixed depth the quadratic drag coefficient

  6. EV Everywhere Batteries Workshop - Pack Design and Optimization...

    Broader source: Energy.gov (indexed) [DOE]

    packdesignb.pdf More Documents & Publications EV Everywhere Batteries Workshop - Beyond Lithium Ion Breakout Session Report EV Everywhere Workshop: Power Electronics and Thermal...

  7. Zooming in on a proton packed with surprises | Jefferson Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Lab experiments, researchers directed the accelerator's polarized electron beam toward liquid hydrogen cooled to 17 Kelvin (-429F). Each electron in the beam has an intrinsic...

  8. PHYSICAL REVIEW E 88, 062151 (2013) Jammed lattice sphere packings

    E-Print Network [OSTI]

    Torquato, Salvatore

    2013-01-01

    for constructing codes in communication and information theory [1]. A classical result of Minkowski provides in Applied and Computational Mathematics, Princeton University, Princeton, New Jersey 08544, USA 5 Princeton of advancing our fundamental understanding of granular matter and structural glasses in three dimensions

  9. Cooking with Canned Tuna (packed in water) (Spanish) 

    E-Print Network [OSTI]

    Anding, Jenna

    2008-12-09

    lata (enlatado con agua) El at?n es una fuente muy nutritiva de prote?na, hierro y niacina. Puesto que ya est? cocinado se puede comer inmediatamente o puede utilizarse para preparar sus platillos favoritos de at?n. Una porci?n es de 2 a 3 onzas y... una lata de 12 onzas rinde aproximadamente 4 porciones. Estofado de at?n y macarrones (rinde entre 4 y 6 porciones) Ingredientes 1 lata de at?n de 12 onzas, drenada 2 latas de crema de champi?ones de 10.75 onzas 1 taza de ch?charos congelados (si...

  10. Origins of Pulsing Regime in Cocurrent Packed-Bed Flows

    E-Print Network [OSTI]

    McCready, Mark J.

    of Chemical Engineering, Purdue University, West Lafayette, IN. March 2004 #12;Abstract The mechanism++ , A. Varma# and M. J. McCready* Department of Chemical Engineering University of Notre Dame Notre Dame: Department of Chemical Engineering, Massachusetts Institute of Technology, Cambridge MA. ++ Current Address

  11. Copyright 2003 by ASME Proceedings of InterPACK03

    E-Print Network [OSTI]

    Sandborn, Peter

    and cost models associated with the conversion of discrete passives to embedded passives in printed circuit that are impacted by the conversion of discrete passives to embedded passives. In addition, a complete set be traded off against the higher cost (per unit area) of boards fabricated with embedded passives (a

  12. Hydrophobically-Driven Self-Assembly: A Geometric Packing Analysis

    E-Print Network [OSTI]

    4, 2003 ABSTRACT We present a new approach to the problem of finding the minimum-energy structures which have served as guides in designing new nanoscale-structured materials. Significant progress has been made in synthesizing a variety of new materials based on the so-called "bottom-up" ap- proach

  13. Packed bed reactor for photochemical sup 196 Hg isotope separation

    SciTech Connect (OSTI)

    Grossman, M.W.; Speer, R.

    1992-03-03

    This patent describes a photochemical reactor useful for the isotopic enrichment of a predetermined isotope of mercury comprising a reactor cell and a monoisotopic light source It comprises: a plurality of transparent, straight reactor cell tubes disposed axially within the internal volume of the reactor cell to increase the surface area thereof for production deposition.

  14. Battery Pack Requirements and Targets Validation FY 2009 DOE...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    mechanical and electric drive Achieving battery life cycle net benefits, given low U.S. gasoline prices * Total project funding - 100% DOE funding * FY09 funding 600K Timeline...

  15. Proceedings of IPACK2005 2005 InterPACK '05

    E-Print Network [OSTI]

    McDonough, James M.

    FEMTOSECOND LASER HEATING OF NANOSCALE METAL FILMS Illayathambi Kunadian Center for Applied Energy Research short-pulse laser heating of metals. 1 Copyright c 2005 by ASME #12;Tzou proposed the dual phase2005-73376 AN EFFICIENT NUMERICAL PROCEDURE FOR SOLVING A MICROSCALE HEAT TRANSPORT EQUATION DURING

  16. Power Consumption Prediction and Power-Aware Packing in Consolidated

    E-Print Network [OSTI]

    Urgaonkar, Bhuvan

    prediction and enforcement of appropriate limits on power consumption--power budgets--within the data center-term energy consumption within that level and 2) a sustained budget to capture any restrictions on sustained as the well-being of our environ- ment. Trends from such platforms suggest that the power consumption in data

  17. Percolation behavior of tritiated water into a soil packed bed

    Broader source: Energy.gov [DOE]

    Presentation from the 34th Tritium Focus Group Meeting held in Idaho Falls, Idaho on September 23-25, 2014.

  18. New ORNL electric vehicle technology packs more punch in smaller...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and tolerance; lighter weight, enabling more compact systems; and higher power density. Additive manufacturing helped researchers explore complex geometries, increase power...

  19. Packed bed thermal energy storage: A simplified experimentally...

    Office of Scientific and Technical Information (OSTI)

    Anderson, Ryan ; Bates, Liana ; Johnson, Erick ; Morris, Jeffrey F. Publication Date: 2015-12-01 OSTI Identifier: 1222500 GrantContract Number: FC36-08GO18151 Type: Published...

  20. Bin packing with general cost structures Leah Epstein

    E-Print Network [OSTI]

    Epstein, Leah

    of Industrial Engineering and Management, The Technion, Haifa, Israel. levinas@ie.technion.ac.il. 1 #12;Anily a larger load than a processor that executes a smaller number of long tasks, even if the total duration are not related to this paper. A related model was studied by Li and Chen [25]. In this model the cost of a bin