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  1. Steps to Commercialization: Nickel Metal Hydride Batteries | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Steps to Commercialization: Nickel Metal Hydride Batteries Steps to Commercialization: Nickel Metal Hydride Batteries October 17, 2011 - 10:42am Addthis Steps to Commercialization: Nickel Metal Hydride Batteries Matthew Loveless Matthew Loveless Data Integration Specialist, Office of Public Affairs How does it work? Through licensing and collaborative work, Energy Department-sponsored research can yield great economic benefits and help bring important new products to market. The

  2. Hydridable material for the negative electrode in a nickel-metal hydride storage battery

    DOE Patents [OSTI]

    Knosp, Bernard; Bouet, Jacques; Jordy, Christian; Mimoun, Michel; Gicquel, Daniel

    1997-01-01

    A monophase hydridable material for the negative electrode of a nickel-metal hydride storage battery with a "Lave's phase" structure of hexagonal C14 type (MgZn.sub.2) has the general formula: Zr.sub.1-x Ti.sub.x Ni.sub.a Mn.sub.b Al.sub.c Co.sub.d V.sub.e where ##EQU1##

  3. Mathematical modeling of the nickel/metal hydride battery system

    SciTech Connect (OSTI)

    Paxton, B K

    1995-09-01

    A group of compounds referred to as metal hydrides, when used as electrode materials, is a less toxic alternative to the cadmium hydroxide electrode found in nickel/cadmium secondary battery systems. For this and other reasons, the nickel/metal hydride battery system is becoming a popular rechargeable battery for electric vehicle and consumer electronics applications. A model of this battery system is presented. Specifically the metal hydride material, LaNi{sub 5}H{sub 6}, is chosen for investigation due to the wealth of information available in the literature on this compound. The model results are compared to experiments found in the literature. Fundamental analyses as well as engineering optimizations are performed from the results of the battery model. In order to examine diffusion limitations in the nickel oxide electrode, a ``pseudo 2-D model`` is developed. This model allows for the theoretical examination of the effects of a diffusion coefficient that is a function of the state of charge of the active material. It is found using present data from the literature that diffusion in the solid phase is usually not an important limitation in the nickel oxide electrode. This finding is contrary to the conclusions reached by other authors. Although diffusion in the nickel oxide active material is treated rigorously with the pseudo 2-D model, a general methodology is presented for determining the best constant diffusion coefficient to use in a standard one-dimensional battery model. The diffusion coefficients determined by this method are shown to be able to partially capture the behavior that results from a diffusion coefficient that varies with the state of charge of the active material.

  4. Nickel-metal hydride battery development. Final technical report

    SciTech Connect (OSTI)

    1995-06-01

    Rechargeable batteries are used as the power source for a broad range of portable equipment. Key battery selection criteria typically are weight, volume, first cost, life cycle cost, and environmental impact. Rechargeable batteries are favored from a life cycle cost and environmental impact standpoint over primary batteries. The nickel-metal hydride (Ni-MH) battery system has emerged as the battery of choice for many applications based on its superior characteristics when judged on the above criteria against other battery types. In most cases commercial Ni-MH batteries are constructed with coiled electrodes in cylindrical metal containers. Electro Energy, Inc. (EEI) has been developing a novel flat bipolar configuration of the Ni-MH system that offers weight, volume, and cost advantages when compared to cylindrical cells. The unique bipolar approach consists of fabricating individual flat wafer cells in conductive, carbon-filled, plastic face plates. The individual cells contain a nonconductive plastic border which is heat sealed around the perimeter to make a totally sealed unit cell. Multi-cell batteries are fabricated by stacking the individual wafer cells in such a way that the positive face of one cell contacts the negative face of the adjacent cell. The stack is then contained in an outer housing with end contacts. The purpose of this program was to develop, evaluate, and demonstrate the capabilities of the EEI Ni-MH battery system for consumer applications. The work was directed at the development and evaluation of the compact bipolar construction for its potential advantages of high power and energy density. Experimental investigations were performed on various nickel electrode types, hydride electrode formulations, and alternate separator materials. Studies were also directed at evaluating various oxygen recombination techniques for low pressure operation during charge and overcharge.

  5. Feasibility study for the recycling of nickel metal hydride electric vehicle batteries. Final report

    SciTech Connect (OSTI)

    Sabatini, J.C.; Field, E.L.; Wu, I.C.; Cox, M.R.; Barnett, B.M.; Coleman, J.T.

    1994-01-01

    This feasibility study examined three possible recycling processes for two compositions (AB{sub 2} and AB{sub 5}) of nickel metal hydride electric vehicle batteries to determine possible rotes for recovering battery materials. Analysts examined the processes, estimated the costs for capital equipment and operation, and estimated the value of the reclaimed material. They examined the following three processes: (1) a chemical process that leached battery powders using hydrochloric acid, (2) a pyrometallurical process, and (3) a physical separation/chemical process. The economic analysis revealed that the physical separation/chemical process generated the most revenue.

  6. Current status of environmental, health, and safety issues of nickel metal-hydride batteries for electric vehicles

    SciTech Connect (OSTI)

    Corbus, D.; Hammel, C.J.; Mark, J.

    1993-08-01

    This report identifies important environment, health, and safety issues associated with nickel metal-hydride (Ni-MH) batteries and assesses the need for further testing and analysis. Among the issues discussed are cell and battery safety, workplace health and safety, shipping requirements, and in-vehicle safety. The manufacture and recycling of Ni-MH batteries are also examined. This report also overviews the ``FH&S`` issues associated with other nickel-based electric vehicle batteries; it examines venting characteristics, toxicity of battery materials, and the status of spent batteries as a hazardous waste.

  7. Gas atomization processing of tin and silicon modified LaNi{sub 5} for nickel-metal hydride battery applications

    SciTech Connect (OSTI)

    Ting, J.

    1999-02-12

    Numerous researchers have studied the relevant material properties of so-called AB{sub 5} alloys for battery applications. These studies involved LaNi{sub 5} substituted alloys which were prepared using conventional cast and crush alloying techniques. While valuable to the understanding of metal hydride effects, the previous work nearly ignored the potential for alternative direct powder production methods, like high pressure gas atomization (HPGA). Thus, there is a need to understand the relationship between gas atomization processes, powder particle solidification phases, and hydrogen absorption properties of ultra fine (< 25 {micro}m) atomized powders with high surface area for enhanced battery performance. Concurrently, development of a gas atomization nozzle that is more efficient than all current designs is needed to increase the yield of ultrafine AB{sub 5} alloy powder for further processing advantage. Gas atomization processing of the AB{sub 5} alloys was demonstrated to be effective in producing ultrafine spherical powders that were resilient to hydrogen cycling for the benefit of improving corrosion resistance in battery application. These ultrafine powders benefited from the rapid solidification process by having refined solute segregation in the microstructure of the gas atomized powders which enabled a rapid anneal treatment of the powders. The author has demonstrated the ability to produce high yields of ultrafine powder efficiently and cost effectively, using the new HPGA-III technology. Thus, the potential benefits of processing AB{sub 5} alloys using the new HPGA technology could reduce manufacturing cost of nickel-metal hydride powder. In the near future, the manufacture of AB{sub 5} alloy powders could become a continuous and rapid production process. The economic benefit of an improved AB{sub 5} production process may thereby encourage the use of nickel-metal hydride rechargeable batteries in electrical vehicle applications in the foreseeable

  8. Steps to Commercialization: Nickel Metal Hydride Batteries |...

    Broader source: Energy.gov (indexed) [DOE]

    funds cutting-edge research on a broad range of topics ranging from advanced battery construction to the modeling of industrial processes and supercomputer simulation of...

  9. Phase I. Lanthanum-based Start Materials for Hydride Batteries

    SciTech Connect (OSTI)

    Gschneidner, K. A.; Schmidt, F. A.; Frerichs, A. E.; Ament, K. A.

    2013-08-20

    The purpose of Phase I of this work is to focus on developing a La-based start material for making nickel-metal (lanthanum)-hydride batteries based on our carbothermic-silicon process. The goal is to develop a protocol for the manufacture of (La1-xRx)(Ni1-yMy)(Siz), where R is a rare earth metal and M is a non-rare earth metal, to be utilized as the negative electrode in nickel-metal hydride (NiMH) rechargeable batteries.

  10. CRADA (AL-C-2009-02) Final Report: Phase I. Lanthanum-based Start Materials for Hydride Batteries

    SciTech Connect (OSTI)

    Gschneidner, Jr., Karl; Schmidt, Frederick; Frerichs, A. E.; Ament, Katherine A.

    2013-05-01

    The purpose of Phase I of this work is to focus on developing a La-based start material for making nickel-metal (lanthanum)-hydride batteries based on our carbothermic-silicon process. The goal is to develop a protocol for the manufacture of (La{sub 1-x}R{sub x})(Ni{sub 1-y}M{sub y})(Si{sub z}), where R is a rare earth metal and M is a non-rare earth metal, to be utilized as the negative electrode in nickel-metal hydride (NiMH) rechargeable batteries.

  11. Method Of Charging Maintenance-Free Nickel Metal Hydride Storage Cells

    DOE Patents [OSTI]

    Berlureau, Thierry; Liska, Jean-Louis

    1999-11-16

    A method of charging an industrial maintenance-free Ni-MH storage cell, the method comprising in combination a first stage at a constant current I.sub.1 lying in the range I.sub.c /10 to I.sub.c /2, and a second stage at a constant current I.sub.2 lying in the range I.sub.c /50 to I.sub.c /10, the changeover from the first stage to the second stage taking place when the time derivative of the temperature reaches a threshold value which varies as a function of the temperature at the time of the changeover.

  12. Hydriding process

    DOE Patents [OSTI]

    Raymond, J.W.; Taketani, H.

    1973-12-01

    BS>A method is described for hydriding a body of a Group IV-B metal, preferably zirconium, to produce a crack-free metal-hydride bedy of high hydrogen content by cooling the body at the beta to beta + delta boundary, without further addition of hydrogen, to precipitate a fine-grained delta-phase metal hydride in the beta + delta phase region and then resuming the hydriding, preferably preceded by a reheating step. (Official Gazette)

  13. [Cu32(H)20{S2P(O i Pr)2 }12 ]: The Largest Number of Hydrides Recorded in a Molecular Nanocluster by Neutron Diffraction

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Dhayal, Rajendra S.; Liao, Jian-Hong; Kahlal, Samia; Wang, Xiaoping; Liu, Yu-Chiao; Chiang, Ming-Hsi; van Zyl, Werner E.; Saillard, Jean-Yves; Liu, C. W.

    2015-04-20

    An air- and moisture-stable nanoscale polyhydrido copper cluster [Cu32(H)20{S2P(O i Pr)2 }12 ] (1H) was synthesized and structurally characterized. The molecular structure of 1H exhibits a hexacapped pseudo-rhombohedral core of 14 Cu atoms sandwiched between two nestlike triangular cupola fragments of (2x9) Cu atoms in an elongated triangular gyrobicupola polyhedron. The discrete Cu32 cluster is stabilized by 12 dithiophosphate ligands and a record number of 20 hydride ligands, which were found by high-resolution neutron diffraction to exhibit tri-, tetra-, and pentacoordinated hydrides in capping and interstitial modes. We conclude that this result was further supported by a density functional theorymore » investigation on the simplified model [Cu32(H)20(S2PH2)12].« less

  14. Metal hydrides

    SciTech Connect (OSTI)

    Carnes, J.R.; Kherani, N.P.

    1987-11-01

    Metal hydride information is not available for most hydrides in a consolidated quick-reference source. This report's objective is to fill the need for such a document providing basic thermodynamic data for as many metal hydrides as possible. We conduced a computerized library search to access as many sources as possible and screened each source for such thermodynamic data as pressure-temperature graphs, van't Hoff curves, and impurity effects. We included any other relevant information and commented on it. A primary concern to be investigated in the future is the behavior of metal tritides. This would be important in the area of emergency tritium cleanup systems. The hydride graphs are useful, however, as tritides may be expected in most cases to behave similarly and at least follow trends of their respective hydrides. 42 refs., 40 figs., 5 tabs.

  15. Metal Hydrides

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Metal Hydrides Theodore Motyka Savannah River National Laboratory Metal Hydride System Architect Jose-Miguel Pasini, & Bart van Hassel UTRC Claudio Corgnale & Bruce Hardy SRNL Kevin Simmons and Mark Weimar PNNL Darsh Kumar GM, Matthew Thornton NREL, Kevin Drost OSU DOE Materials-Based Hydrogen Storage Summit Defining Pathways for Onboard Automotive Applications 2 Outline * Background and MH History * MH HSECoE Results * Material Operating Requirements * Modeling and Analyses * BOP and

  16. Hydride compositions

    DOE Patents [OSTI]

    Lee, Myung, W.

    1994-01-01

    Disclosed are a composition for use in storing hydrogen and a method for making the composition. The composition comprises a mixture of two or more hydrides, each hydride having a different series of hydrogen sorption isotherms that contribute to the overall isotherms of the mixture. The hydrides are chosen so that the isotherms of the mixture have regions wherein the H equilibrium pressure increases with increasing hydrogen, preferably linearly. The isotherms of the mixture can be adjusted by selecting hydrides with different isotherms and by varying the amounts of the individual hydrides, or both. Preferably, the mixture is made up of hydrides that have isotherms with substantially flat plateaus and in nearly equimolar amounts. The composition is activated by degassing, exposing to H, and then heating below the softening temperature of any of the constituents. When the composition is used to store hydrogen, its hydrogen content can be found simply by measuring P{sub H}{sub 2} and determining H/M from the isothermic function of the composition.

  17. Hydride compositions

    DOE Patents [OSTI]

    Lee, Myung W.

    1995-01-01

    A composition for use in storing hydrogen, and a method for making the composition. The composition comprises a mixture of two or more hydrides, each hydride having a different series of hydrogen sorption isotherms that contribute to the overall isotherms of the mixture. The hydrides are chosen so that the isotherms of the mixture have regions wherein the hydrogen equilibrium pressure increases with increasing hydrogen, preferably linearly. The isotherms of the mixture can be adjusted by selecting hydrides with different isotherms and by varying the amounts of the individual hydrides, or both. Preferably, the mixture is made up of hydrides that have isotherms with substantially flat plateaus and in nearly equimolar amounts. The composition is activated by degassing, exposing to hydrogen and then heating at a temperature below the softening temperature of any of the. constituents so that their chemical and structural integrity is preserved. When the composition is used to store hydrogen, its hydrogen content can be found simply by measuring P.sub.H.sbsb.2 and determining H/M from the isothermic function of the composition.

  18. Metal Hydride Hydrogen Storage Research and Development

    Broader source: Energy.gov [DOE]

    DOE's research on complex metal hydrides targets the development of advanced metal hydride materials including light-weight complex hydrides, destabilized binary hydrides, intermetallic hydrides,...

  19. Hydride compressor

    DOE Patents [OSTI]

    Powell, James R.; Salzano, Francis J.

    1978-01-01

    Method of producing high energy pressurized gas working fluid power from a low energy, low temperature heat source, wherein the compression energy is gained by using the low energy heat source to desorb hydrogen gas from a metal hydride bed and the desorbed hydrogen for producing power is recycled to the bed, where it is re-adsorbed, with the recycling being powered by the low energy heat source. In one embodiment, the adsorption-desorption cycle provides a chemical compressor that is powered by the low energy heat source, and the compressor is connected to a regenerative gas turbine having a high energy, high temperature heat source with the recycling being powered by the low energy heat source.

  20. Metastable Metal Hydrides for Hydrogen Storage

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Graetz, Jason

    2012-01-01

    The possibility of using hydrogen as a reliable energy carrier for both stationary and mobile applications has gained renewed interest in recent years due to improvements in high temperature fuel cells and a reduction in hydrogen production costs. However, a number of challenges remain and new media are needed that are capable of safely storing hydrogen with high gravimetric and volumetric densities. Metal hydrides and complex metal hydrides offer some hope of overcoming these challenges; however, many of the high capacity “reversible” hydrides exhibit a large endothermic decomposition enthalpy making it difficult to release the hydrogen at low temperatures. Onmore » the other hand, the metastable hydrides are characterized by a low reaction enthalpy and a decomposition reaction that is thermodynamically favorable under ambient conditions. The rapid, low temperature hydrogen evolution rates that can be achieved with these materials offer much promise for mobile PEM fuel cell applications. However, a critical challenge exists to develop new methods to regenerate these hydrides directly from the reactants and hydrogen gas. This spotlight paper presents an overview of some of the metastable metal hydrides for hydrogen storage and a few new approaches being investigated to address the key challenges associated with these materials.« less

  1. Hydride heat pump

    DOE Patents [OSTI]

    Cottingham, James G.

    1977-01-01

    Method and apparatus for the use of hydrides to exhaust heat from one temperature source and deliver the thermal energy extracted for use at a higher temperature, thereby acting as a heat pump. For this purpose there are employed a pair of hydridable metal compounds having different characteristics working together in a closed pressure system employing a high temperature source to upgrade the heat supplied from a low temperature source.

  2. Results of NDE Technique Evaluation of Clad Hydrides

    SciTech Connect (OSTI)

    Dennis C. Kunerth

    2014-09-01

    This report fulfills the M4 milestone, M4FT-14IN0805023, Results of NDE Technique Evaluation of Clad Hydrides, under Work Package Number FT-14IN080502. During service, zirconium alloy fuel cladding will degrade via corrosion/oxidation. Hydrogen, a byproduct of the oxidation process, will be absorbed into the cladding and eventually form hydrides due to low hydrogen solubility limits. The hydride phase is detrimental to the mechanical properties of the cladding and therefore it is important to be able to detect and characterize the presence of this constituent within the cladding. Presently, hydrides are evaluated using destructive examination. If nondestructive evaluation techniques can be used to detect and characterize the hydrides, the potential exists to significantly increase test sample coverage while reducing evaluation time and cost. To demonstrate the viability this approach, an initial evaluation of eddy current and ultrasonic techniques were performed to demonstrate the basic ability to these techniques to detect hydrides or their effects on the microstructure. Conventional continuous wave eddy current techniques were applied to zirconium based cladding test samples thermally processed with hydrogen gas to promote the absorption of hydrogen and subsequent formation of hydrides. The results of the evaluation demonstrate that eddy current inspection approaches have the potential to detect both the physical damage induced by hydrides, e.g. blisters and cracking, as well as the combined effects of absorbed hydrogen and hydride precipitates on the electrical properties of the zirconium alloy. Similarly, measurements of ultrasonic wave velocities indicate changes in the elastic properties resulting from the combined effects of absorbed hydrogen and hydride precipitates as well as changes in geometry in regions of severe degradation. However, for both approaches, the signal responses intended to make the desired measurement incorporate a number of contributing

  3. Working with SRNL - Our Facilities - Metal Hydride Laboratories

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Metal Hydride Laboratories Working with SRNL Our Facilities - Metal Hydride Laboratories The Metal Hydride Laboratories are used for research and development on metal hydride absorption and desorption performance

  4. Boron hydride polymer coated substrates

    DOE Patents [OSTI]

    Pearson, Richard K.; Bystroff, Roman I.; Miller, Dale E.

    1987-01-01

    A method is disclosed for coating a substrate with a uniformly smooth layer of a boron hydride polymer. The method comprises providing a reaction chamber which contains the substrate and the boron hydride plasma. A boron hydride feed stock is introduced into the chamber simultaneously with the generation of a plasma discharge within the chamber. A boron hydride plasma of ions, electrons and free radicals which is generated by the plasma discharge interacts to form a uniformly smooth boron hydride polymer which is deposited on the substrate.

  5. Boron hydride polymer coated substrates

    DOE Patents [OSTI]

    Pearson, R.K.; Bystroff, R.I.; Miller, D.E.

    1986-08-27

    A method is disclosed for coating a substrate with a uniformly smooth layer of a boron hydride polymer. The method comprises providing a reaction chamber which contains the substrate and the boron hydride plasma. A boron hydride feed stock is introduced into the chamber simultaneously with the generation of a plasma discharge within the chamber. A boron hydride plasma of ions, electrons and free radicals which is generated by the plasma discharge interacts to form a uniformly smooth boron hydride polymer which is deposited on the substrate.

  6. Develop improved metal hydride technology for the storage of hydrogen. Final technical report

    SciTech Connect (OSTI)

    Sapru, K.

    1998-12-04

    The overall objective was to develop commercially viable metal hydrides capable of reversibly storing at least 3 wt.% hydrogen for use with PEM fuel cells and hydrogen fueled internal combustion engine (HICE) applications. Such alloys are expected to result in system capacities of greater than 2 wt.%, making metal hydride storage systems (MHSS`s) a practical means of supplying hydrogen for many consumer applications. ECD`s (Energy Conversion Devices, Inc.) past work on sputtered thin films of transition metal-based alloys led to the commercialization of it`s nickel/metal hydride batteries, and similar work on thin film Mg-based alloys demonstrated potential to achieve very high gravimetric and volumetric energy densities approaching 2,500 Wh/Kg and 2,500 Wh/M{sup 3} respectively. Under this 2-year cost shared project with the DOE, the authors have successfully demonstrated the feasibility of scaling up the Mg-based hydrides from thin film to bulk production without substantial loss of storage capacity. ECD made progress in alloy development by means of compositional and process modification. Processes used include Mechanical Alloying, Melt spinning and novel Gas Phase Condensation. It was showed that the same composition when prepared by melt-spinning resulted in a more homogeneous material having a higher PCT plateau pressure as compared to mechanical alloying. It was also shown that mechanically alloyed Mg-Al-Zn results in much higher plateau pressures, which is an important step towards reducing the desorption temperature. While significant progress has been made during the past two years in alloy development and understanding the relationship between composition, structure, morphology, and processing parameters, additional R and D needs to be performed to achieve the goals of this work.

  7. Method for preparing porous metal hydride compacts

    DOE Patents [OSTI]

    Ron, Moshe; Gruen, Dieter M.; Mendelsohn, Marshall H.; Sheft, Irving

    1981-01-01

    A method for preparing porous metallic-matrix hydride compacts which can be repeatedly hydrided and dehydrided without disintegration. A mixture of a finely divided metal hydride and a finely divided matrix metal is contacted with a poison which prevents the metal hydride from dehydriding at room temperature and atmospheric pressure. The mixture of matrix metal and poisoned metal hydride is then compacted under pressure at room temperature to form porous metallic-matrix hydride compacts.

  8. Hydrogenation using hydrides and acid

    DOE Patents [OSTI]

    Bullock, R. Morris

    1990-10-30

    A process for the non-catalytic hydrogenation of organic compounds, which contain at least one reducible functional group, which comprises reacting the organic compound, a hydride complex, preferably a transition metal hydride complex or an organosilane, and a strong acid in a liquid phase.

  9. Dimensionally stable metallic hydride composition

    DOE Patents [OSTI]

    Heung, Leung K.

    1994-01-01

    A stable, metallic hydride composition and a process for making such a composition. The composition comprises a uniformly blended mixture of a metal hydride, kieselguhr, and a ballast metal, all in the form of particles. The composition is made by subjecting a metal hydride to one or more hydrogen absorption/desorption cycles to disintegrate the hydride particles to less than approximately 100 microns in size. The particles are partly oxidized, then blended with the ballast metal and the kieselguhr to form a uniform mixture. The mixture is compressed into pellets and calcined. Preferably, the mixture includes approximately 10 vol. % or more kieselguhr and approximately 50 vol. % or more ballast. Metal hydrides that can be used in the composition include Zr, Ti, V, Nb, Pd, as well as binary, tertiary, and more complex alloys of La, Al, Cu, Ti, Co, Ni, Fe, Zr, Mg, Ca, Mn, and mixtures and other combinations thereof. Ballast metals include Al, Cu and Ni.

  10. Optimization of Hydride Rim Formation in Unirradiated Zr 4 Cladding

    SciTech Connect (OSTI)

    Shimskey, Rick W.; Hanson, Brady D.; MacFarlan, Paul J.

    2013-09-30

    The purpose of this work is to build on the results reported in the M2 milestone M2FT 13PN0805051, document number FCRD-USED-2013-000151 (Hanson, 2013). In that work, it was demonstrated that unirradiated samples of zircaloy-4 cladding could be pre-hydrided at temperatures below 400°C in pure hydrogen gas and that the growth of hydrides on the surface could be controlled by changing the surface condition of the samples and form a desired hydride rim on the outside diameter of the cladding. The work performed at Pacific Northwest National Laboratory since the issuing of the M2 milestone has focused its efforts to optimize the formation of a hydride rim on available zircaloy-4 cladding samples by controlling temperature variation and gas flow control during pre-hydriding treatments. Surface conditioning of the outside surface was also examined as a variable. The results of test indicate that much of the variability in the hydride thickness is due to temperature variation occurring in the furnaces as well as how hydrogen gas flows across the sample surface. Efforts to examine other alloys, gas concentrations, and different surface conditioning plan to be pursed in the next FY as more cladding samples become available

  11. Erbium hydride decomposition kinetics.

    SciTech Connect (OSTI)

    Ferrizz, Robert Matthew

    2006-11-01

    Thermal desorption spectroscopy (TDS) is used to study the decomposition kinetics of erbium hydride thin films. The TDS results presented in this report are analyzed quantitatively using Redhead's method to yield kinetic parameters (E{sub A} {approx} 54.2 kcal/mol), which are then utilized to predict hydrogen outgassing in vacuum for a variety of thermal treatments. Interestingly, it was found that the activation energy for desorption can vary by more than 7 kcal/mol (0.30 eV) for seemingly similar samples. In addition, small amounts of less-stable hydrogen were observed for all erbium dihydride films. A detailed explanation of several approaches for analyzing thermal desorption spectra to obtain kinetic information is included as an appendix.

  12. Low density metal hydride foams

    DOE Patents [OSTI]

    Maienschein, Jon L.; Barry, Patrick E.

    1991-01-01

    Disclosed is a low density foam having a porosity of from 0 to 98% and a density less than about 0.67 gm/cc, prepared by heating a mixture of powered lithium hydride and beryllium hydride in an inert atmosphere at a temperature ranging from about 455 to about 490 K for a period of time sufficient to cause foaming of said mixture, and cooling the foam thus produced. Also disclosed is the process of making the foam.

  13. Hydride Rim Formation in Unirradiated Zircaloy

    Broader source: Energy.gov [DOE]

    The purpose of this work is to develop the means of pre-hydriding unirradiated Zircaloy cladding such that a high concentration, or rim, of hydrides is formed at the cladding outside diameter.

  14. Vanadium hydride deuterium-tritium generator

    DOE Patents [OSTI]

    Christensen, Leslie D.

    1982-01-01

    A pressure controlled vanadium hydride gas generator to provide deuterium-tritium gas in a series of pressure increments. A high pressure chamber filled with vanadium-deuterium-tritium hydride is surrounded by a heater which controls the hydride temperature. The heater is actuated by a power controller which responds to the difference signal between the actual pressure signal and a programmed pressure signal.

  15. Hydrogen, lithium, and lithium hydride production

    SciTech Connect (OSTI)

    Brown, Sam W; Spencer, Larry S; Phillips, Michael R; Powell, G. Louis; Campbell, Peggy J

    2014-03-25

    A method of producing high purity lithium metal is provided, where gaseous-phase lithium metal is extracted from lithium hydride and condensed to form solid high purity lithium metal. The high purity lithium metal may be hydrided to provide high purity lithium hydride.

  16. Method of producing a chemical hydride

    DOE Patents [OSTI]

    Klingler, Kerry M.; Zollinger, William T.; Wilding, Bruce M.; Bingham, Dennis N.; Wendt, Kraig M.

    2007-11-13

    A method of producing a chemical hydride is described and which includes selecting a composition having chemical bonds and which is capable of forming a chemical hydride; providing a source of a hydrocarbon; and reacting the composition with the source of the hydrocarbon to generate a chemical hydride.

  17. First Principles Contributions to the Thermodynamic Assessment of Solid State Metal Hydride and Complex Hydride Phases

    Broader source: Energy.gov [DOE]

    Presentation on the Thermodynamic Assessment of Solid State Metal Hydride and Complex Hydride Phases given at the DOE Theory Focus Session on Hydrogen Storage Materials on May 18, 2006.

  18. Metal hydride composition and method of making

    DOE Patents [OSTI]

    Congdon, James W.

    1995-01-01

    A dimensionally stable hydride composition and a method for making such a composition. The composition is made by forming particles of a metal hydride into porous granules, mixing the granules with a matrix material, forming the mixture into pellets, and sintering the pellets in the absence of oxygen. The ratio of matrix material to hydride is preferably between approximately 2:1 and 4:1 by volume. The porous structure of the granules accommodates the expansion that occurs when the metal hydride particles absorb hydrogen. The porous matrix allows the flow of hydrogen therethrough to contact the hydride particles, yet supports the granules and contains the hydride fines that result from repeated absorption/desorption cycles.

  19. Use of hydrides in motor vehicles

    SciTech Connect (OSTI)

    Toepler, J.; Bernauer, O.; Buchner, H.

    1980-09-01

    Results of research on hydrogen driven vehicles and hydride storage tanks are presented, along with a detailed discussion of the operational possibilities of low temperature hydrides, such as TiFe-H2, and of high temperature hydrides, such as Mg2Ni-H4. Attention is given to their cyclization stability and thermal conductivity. Heat storage and heat recovery with the aid of hydrides are discussed, and a theoretical hydride storage capacity of a Mg-Ni-alloy is presented. It was concluded that all hydride tanks will be 10 to 20 times heavier than the conventional gasoline tank. The problems of tank weight and gasoline shortage can be solved by a combination hydrogen/gasoline fuel. Existing energy infrastructures must be utilized, as the setting up of a hydrogen infrastructure is, at the present time, both technically and economically unfeasible.

  20. Complex hydrides for hydrogen storage

    DOE Patents [OSTI]

    Zidan, Ragaiy

    2006-08-22

    A hydrogen storage material and process of forming the material is provided in which complex hydrides are combined under conditions of elevated temperatures and/or elevated temperature and pressure with a titanium metal such as titanium butoxide. The resulting fused product exhibits hydrogen desorption kinetics having a first hydrogen release point which occurs at normal atmospheres and at a temperature between 50.degree. C. and 90.degree. C.

  1. Vanadium hydride deuterium-tritium generator

    DOE Patents [OSTI]

    Christensen, L.D.

    1980-03-13

    A pressure controlled vanadium hydride gas generator was designed to provide deuterium-tritium gas in a series of pressure increments. A high pressure chamber filled with vanadium-deuterium-tritium hydride is surrounded by a heater which controls the hydride temperature. The heater is actuated by a power controller which responds to the difference signal between the actual pressure signal and a programmed pressure signal.

  2. Activated aluminum hydride hydrogen storage compositions and...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Analysis Energy Storage Geothermal Hydrogen and Fuel Cell Hydropower, Wave and Tidal ... Return to Search Activated aluminum hydride hydrogen storage compositions and uses thereof ...

  3. Igniter containing titanium hydride and potassium perchlorate

    DOE Patents [OSTI]

    Dietzel, Russel W.; Leslie, William B.

    1976-01-01

    An explosive device is described which employs a particular titanium hydride-potassium perchlorate composition directly ignitible by an electrical bridgewire.

  4. Project Profile: Engineering a Novel High Temperature Metal Hydride...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Innovation PNNL CSP TESFigure.jpg The titanium hydride-based system is expected to provide higher exergetic efficiency than lower temperature systems such as magnesium hydride or ...

  5. Reversible Metal Hydride Thermal Energy Storage for High Temperature...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Reversible Metal Hydride Thermal Energy Storage for High Temperature Power Generation Systems Reversible Metal Hydride Thermal Energy Storage for High Temperature Power Generation ...

  6. Kinetics of hydride front in Zircaloy-2 and H release from a fractional hydrided surface

    SciTech Connect (OSTI)

    Diaz, M.; Gonzalez-Gonzalez, A.; Moya, J. S.; Remartinez, B.; Perez, S.; Sacedon, J. L.

    2009-07-15

    The authors study the hydriding process on commercial nuclear fuel claddings from their inner surface using an ultrahigh vacuum method. The method allows determining the incubation and failure times of the fuel claddings, as well as the dissipated energy and the partial pressure of the desorbed H{sub 2} from the outer surface of fuel claddings during the hydriding process. The correlation between the hydriding dissipated energy and the amount of zirconium hydride (formed at different stages of the hydriding process) leads to a near t{sup 1/2} potential law corresponding to the time scaling of the reaction for the majority of the tested samples. The calibrated relation between energy and hydride thickness allows one to calculate the enthalpy of the {delta}-ZrH{sub 1.5} phase. The measured H{sub 2} desorption from the external surface is in agreement with a proposed kinetic desorption model from the hydrides precipitated at the surface.

  7. Direct synthesis of catalyzed hydride compounds

    DOE Patents [OSTI]

    Gross, Karl J.; Majzoub, Eric

    2004-09-21

    A method is disclosed for directly preparing alkali metal aluminum hydrides such as NaAlH.sub.4 and Na.sub.3 AlH.sub.6 from either the alkali metal or its hydride, and aluminum. The hydride thus prepared is doped with a small portion of a transition metal catalyst compound, such as TiCl.sub.3, TiF.sub.3, or a mixture of these materials, in order to render them reversibly hydridable. The process provides for mechanically mixing the dry reagents under an inert atmosphere followed by charging the mixed materials with high pressure hydrogen while heating the mixture to about 125.degree. C. The method is relatively simple and inexpensive and provides reversible hydride compounds which are free of the usual contamination introduced by prior art wet chemical methods.

  8. Zirconium hydride containing explosive composition

    DOE Patents [OSTI]

    Walker, Franklin E.; Wasley, Richard J.

    1981-01-01

    An improved explosive composition is disclosed and comprises a major portion of an explosive having a detonation velocity between about 1500 and 10,000 meters per second and a minor amount of a donor additive comprising a non-explosive compound or mixture of non-explosive compounds which when subjected to an energy fluence of 1000 calories/cm.sup.2 or less is capable of releasing free radicals each having a molecular weight between 1 and 120. Exemplary donor additives are dibasic acids, polyamines and metal hydrides.

  9. Activated aluminum hydride hydrogen storage compositions and uses thereof

    DOE Patents [OSTI]

    Sandrock, Gary; Reilly, James; Graetz, Jason; Wegrzyn, James E.

    2010-11-23

    In one aspect, the invention relates to activated aluminum hydride hydrogen storage compositions containing aluminum hydride in the presence of, or absence of, hydrogen desorption stimulants. The invention particularly relates to such compositions having one or more hydrogen desorption stimulants selected from metal hydrides and metal aluminum hydrides. In another aspect, the invention relates to methods for generating hydrogen from such hydrogen storage compositions.

  10. Hydrogen-storing hydride complexes

    DOE Patents [OSTI]

    Srinivasan, Sesha S.; Niemann, Michael U.; Goswami, D. Yogi; Stefanakos, Elias K.

    2012-04-10

    A ternary hydrogen storage system having a constant stoichiometric molar ratio of LiNH.sub.2:MgH.sub.2:LiBH.sub.4 of 2:1:1. It was found that the incorporation of MgH.sub.2 particles of approximately 10 nm to 20 nm exhibit a lower initial hydrogen release temperature of 150.degree. C. Furthermore, it is observed that the particle size of LiBNH quaternary hydride has a significant effect on the hydrogen sorption concentration with an optimum size of 28 nm. The as-synthesized hydrides exhibit two main hydrogen release temperatures, one around 160.degree. C. and the other around 300.degree. C., with the main hydrogen release temperature reduced from 310.degree. C. to 270.degree. C., while hydrogen is first reversibly released at temperatures as low as 150.degree. C. with a total hydrogen capacity of 6 wt. % to 8 wt. %. Detailed thermal, capacity, structural and microstructural properties have been demonstrated and correlated with the activation energies of these materials.

  11. Liquid suspensions of reversible metal hydrides

    DOE Patents [OSTI]

    Reilly, J.J.; Grohse, E.W.; Winsche, W.E.

    1983-12-08

    The reversibility of the process M + x/2 H/sub 2/ ..-->.. MH/sub x/, where M is a metal hydride former that forms a hydride MH/sub x/ in the presence of H/sub 2/, generally used to store and recall H/sub 2/, is found to proceed under a liquid, thereby to reduce contamination, provide better temperature control and provide in situ mobility of the reactants. Thus, a slurry of particles of a metal hydride former with an inert solvent is subjected to temperature and pressure controlled atmosphere containing H/sub 2/, to store hydrogen (at high pressures) and to release (at low pressures) previously stored hydrogen. The direction of the flow of the H/sub 2/ through the liquid is dependent upon the H/sub 2/ pressure in the gas phase at a given temperature. When the former is above the equilibrium absorption pressure of the respective hydride the reaction proceeds to the right, i.e., the metal hydride is formed and hydrogen is stored in the solid particle. When the H/sub 2/ pressure in the gas phase is below the equilibrium dissociation pressure of the respective hydride the reaction proceeds to the left, the metal hydride is decomposed and hydrogen is released into the gas phase.

  12. Disposal of tritium-exposed metal hydrides

    SciTech Connect (OSTI)

    Nobile, A.; Motyka, T.

    1991-01-01

    A plan has been established for disposal of tritium-exposed metal hydrides used in Savannah River Site (SRS) tritium production or Materials Test Facility (MTF) R D operations. The recommended plan assumes that the first tritium-exposed metal hydrides will be disposed of after startup of the Solid Waste Disposal Facility (SWDF) Expansion Project in 1992, and thus the plan is consistent with the new disposal requiremkents that will be in effect for the SWDF Expansion Project. Process beds containing tritium-exposed metal hydride powder will be disposed of without removal of the powder from the bed; however, disposal of tritium-exposed metal hydride powder that has been removed from its process vessel is also addressed.

  13. Disposal of tritium-exposed metal hydrides

    SciTech Connect (OSTI)

    Nobile, A.; Motyka, T.

    1991-12-31

    A plan has been established for disposal of tritium-exposed metal hydrides used in Savannah River Site (SRS) tritium production or Materials Test Facility (MTF) R&D operations. The recommended plan assumes that the first tritium-exposed metal hydrides will be disposed of after startup of the Solid Waste Disposal Facility (SWDF) Expansion Project in 1992, and thus the plan is consistent with the new disposal requiremkents that will be in effect for the SWDF Expansion Project. Process beds containing tritium-exposed metal hydride powder will be disposed of without removal of the powder from the bed; however, disposal of tritium-exposed metal hydride powder that has been removed from its process vessel is also addressed.

  14. Regeneration of Aluminum Hydride - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Regeneration of Aluminum Hydride Brookhaven National Laboratory Contact BNL About This Technology Publications: PDF Document Publication Regeneration of Lithium Aluminum Hydride (919 KB) Technology Marketing Summary Alane is one of the most promising solutions to storing hydrogen for use in hydrogen fuel cells. This technology provides exceptional improvement in solving the difficult problem of economically preparing the material. Description Describes methods and materials required for the

  15. Metal hydride fuel storage and method thereof

    DOE Patents [OSTI]

    Morse, Jeffrey D.; Jankowski, Alan F.; Yu, Conrad

    2006-10-17

    Disclosed herein is a metal hydride fuel storage cartridge having integrated resistive heaters that can be used in conjunction with fuel cells such as MEMS-based fuel cells. The cartridge is fabricated using micromachining methods and thin/thick film materials synthesis techniques.

  16. Metal hydride fuel storage and method thereof

    DOE Patents [OSTI]

    Morse, Jeffrey D [Martinez, CA; Jankowski, Alan F [Livermore, CA; Yu, Conrad [Antioch, CA

    2009-05-05

    Disclosed herein is a metal hydride fuel storage cartridge having integrated resistive heaters that can be used in conjunction with fuel cells such as MEMS-based fuel cells. The cartridge is fabricated using micromachining methods and thin/thick film materials synthesis techniques.

  17. Ductility Evaluation of As-Hydrided and Hydride Reoriented Zircaloy-4 Cladding under Simulated Dry-Storage Condition

    SciTech Connect (OSTI)

    Yan, Yong; Plummer, Lee K; Ray, Holly B; Cook, Tyler S; Bilheux, Hassina Z

    2014-01-01

    Pre-storage drying-transfer operations and early stage storage expose cladding to higher temperatures and much higher pressure-induced tensile hoop stresses relative to normal operation in-reactor and pool storage under these conditions. Radial hydrides could precipitate during slow cooling and provide an additional embrittlement mechanism as the cladding temperature decreases below the ductile-to-brittle transition temperature. As a means of simulating this behavior, unirradiated hydrided Zircaloy-4 samples were fabricated by a gas charging method to levels that encompass the range of hydrogen concentrations observed in current used fuel. Mechanical testing was carried out by the ring compression test (RCT) method at various temperatures to evaluate the sample s ductility for both as-hydrided and post-hydride reorientation treated specimens. As-hydrided samples with higher hydrogen concentration (>800 ppm) resulted in lower strain before fracture and reduced maximum load. Increasing RCT temperatures resulted in increased ductility of the as-hydrided cladding. A systematic radial hydride treatment was conducted at various pressures and temperatures for the hydrided samples with H content around 200 ppm. Following the radial hydride treatment, RCTs on the hydride reoriented samples were conducted and exhibited lower ductility compared to as-hydrided samples.

  18. METHOD OF FABRICATING A URANIUM-ZIRCONIUM HYDRIDE REACTOR CORE

    DOE Patents [OSTI]

    Weeks, I.F.; Goeddel, W.V.

    1960-03-22

    A method is described of evenly dispersing uranlum metal in a zirconium hydride moderator to produce a fuel element for nuclear reactors. According to the invention enriched uranium hydride and zirconium hydride powders of 200 mesh particle size are thoroughly admixed to form a mixture containing 0.1 to 3% by weight of U/sup 235/ hydride. The mixed powders are placed in a die and pressed at 100 tons per square inch at room temperature. The resultant compacts are heated in a vacuum to 300 deg C, whereby the uranium hydride deoomposes into uranium metal and hydrogen gas. The escaping hydrogen gas forms a porous matrix of zirconium hydride, with uramum metal evenly dispersed therethrough. The advantage of the invention is that the porosity and uranium distribution of the final fuel element can be more closely determined and controlled than was possible using prior methods of producing such fuel ele- ments.

  19. Activated Aluminum Hydride Hydrogen Storage Compositions - Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Innovation Portal Startup America Startup America Hydrogen and Fuel Cell Hydrogen and Fuel Cell Find More Like This Return to Search Activated Aluminum Hydride Hydrogen Storage Compositions Brookhaven National Laboratory Contact BNL About This Technology Publications: PDF Document Publication Alane for Hydrogen Storage and Delivery - Accelerating Innovation Webinar Presentation - June 2012 (7,079 KB) <p> Schematic representation of &nbsp;mechanical alloying reaction during ball

  20. Regeneration of aluminum hydride - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    268,288 Site Map Printable Version Share this resource About Search Categories (15) Advanced Materials Biomass and Biofuels Building Energy Efficiency Electricity Transmission Energy Analysis Energy Storage Geothermal Hydrogen and Fuel Cell Hydropower, Wave and Tidal Industrial Technologies Solar Photovoltaic Solar Thermal Startup America Vehicles and Fuels Wind Energy Partners (27) Visual Patent Search Success Stories Find More Like This Return to Search Regeneration of aluminum hydride United

  1. METAL HYDRIDE HYDROGEN COMPRESSORS: A REVIEW

    SciTech Connect (OSTI)

    Bowman Jr, Robert C; Yartys, Dr. Volodymyr A.; Lototskyy, Dr. Michael V; Pollet, Dr. B.G.

    2014-01-01

    Metal hydride (MH) thermal sorption compression is an efficient and reliable method allowing a conversion of energy from heat into a compressed hydrogen gas. The most important component of such a thermal engine the metal hydride material itself should possess several material features in order to achieve an efficient performance in the hydrogen compression. Apart from the hydrogen storage characteristics important for every solid H storage material (e.g. gravimetric and volumetric efficiency of H storage, hydrogen sorption kinetics and effective thermal conductivity), the thermodynamics of the metal-hydrogen systems is of primary importance resulting in a temperature dependence of the absorption/desorption pressures). Several specific features should be optimized to govern the performance of the MH-compressors including synchronisation of the pressure plateaus for multi-stage compressors, reduction of slope of the isotherms and hysteresis, increase of cycling stability and life time, together with challenges in system design associated with volume expansion of the metal matrix during the hydrogenation. The present review summarises numerous papers and patent literature dealing with MH hydrogen compression technology. The review considers (a) fundamental aspects of materials development with a focus on structure and phase equilibria in the metal-hydrogen systems suitable for the hydrogen compression; and (b) applied aspects, including their consideration from the applied thermodynamic viewpoint, system design features and performances of the metal hydride compressors and major applications.

  2. METHOD AND APPARATUS FOR MAKING URANIUM-HYDRIDE COMPACTS

    DOE Patents [OSTI]

    Wellborn, W.; Armstrong, J.R.

    1959-03-10

    A method and apparatus are presented for making compacts of pyrophoric hydrides in a continuous operation out of contact with air. It is particularly useful for the preparation of a canned compact of uranium hydride possessing high density and purity. The metallic uranium is enclosed in a container, positioned in a die body evacuated and nvert the uranium to the hydride is admitted and the container sealed. Heat is applied to bring about the formation of the hydride, following which compression is used to form the compact sealed in a container ready for use.

  3. Documentation of Hybrid Hydride Model for Incorporation into...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    into Moose-Bison and Validation Strategy Documentation of Hybrid Hydride Model for Incorporation into Moose-Bison and Validation Strategy This report documents the ...

  4. Neutron Irradiation of Hydrided Cladding Material in HFIR Summary...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    (HFIR). Irradiation of the capsules was conducted for post-irradiation examination (PIE) metallography. PDF icon Neutron Irradiation of Hydrided Cladding Material in HFIR...

  5. Metal Hydride Thermal Storage: Reversible Metal Hydride Thermal Storage for High-Temperature Power Generation Systems

    SciTech Connect (OSTI)

    2011-12-05

    HEATS Project: PNNL is developing a thermal energy storage system based on a Reversible Metal Hydride Thermochemical (RMHT) system, which uses metal hydride as a heat storage material. Heat storage materials are critical to the energy storage process. In solar thermal storage systems, heat can be stored in these materials during the day and released at nightwhen the sun is not outto drive a turbine and produce electricity. In nuclear storage systems, heat can be stored in these materials at night and released to produce electricity during daytime peak-demand hours. PNNLs metal hydride material can reversibly store heat as hydrogen cycles in and out of the material. In a RHMT system, metal hydrides remain stable in high temperatures (600- 800C). A high-temperature tank in PNNLs storage system releases heat as hydrogen is absorbed, and a low-temperature tank stores the heat until it is needed. The low-cost material and simplicity of PNNLs thermal energy storage system is expected to keep costs down. The system has the potential to significantly increase energy density.

  6. Method of making crack-free zirconium hydride

    DOE Patents [OSTI]

    Sullivan, Richard W.

    1980-01-01

    Crack-free hydrides of zirconium and zirconium-uranium alloys are produced by alloying the zirconium or zirconium-uranium alloy with beryllium, or nickel, or beryllium and scandium, or nickel and scandium, or beryllium and nickel, or beryllium, nickel and scandium and thereafter hydriding.

  7. Metal Hydrides for High-Temperature Power Generation

    SciTech Connect (OSTI)

    Ronnebro, Ewa; Whyatt, Greg A.; Powell, Michael R.; Westman, Matthew P.; Zheng, Feng; Fang, Zhigang Zak

    2015-08-10

    Metal hydrides can be utilized for hydrogen storage and for thermal energy storage (TES) applications. By using TES with solar technologies, heat can be stored from sun energy to be used later which enables continuous power generation. We are developing a TES technology based on a dual-bed metal hydride system, which has a high-temperature (HT) metal hydride operating reversibly at 600-800°C to generate heat as well as a low-temperature (LT) hydride near room temperature that is used for hydrogen storage during sun hours until there is a need to produce electricity, such as during night time, a cloudy day, or during peak hours. We proceeded from selecting a high-energy density, low-cost HT-hydride based on performance characterization on gram size samples, to scale-up to kilogram quantities and design, fabrication and testing of a 1.5kWh, 200kWh/m3 bench-scale TES prototype based on a HT-bed of titanium hydride and a hydrogen gas storage instead of a LT-hydride. COMSOL Multiphysics was used to make performance predictions for cylindrical hydride beds with varying diameters and thermal conductivities. Based on experimental and modeling results, a bench-scale prototype was designed and fabricated and we successfully showed feasibility to meet or exceed all performance targets.

  8. High energy density battery based on complex hydrides

    DOE Patents [OSTI]

    Zidan, Ragaiy

    2016-04-26

    A battery and process of operating a battery system is provided using high hydrogen capacity complex hydrides in an organic non-aqueous solvent that allows the transport of hydride ions such as AlH.sub.4.sup.- and metal ions during respective discharging and charging steps.

  9. Project Profile: Engineering a Novel High Temperature Metal Hydride

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Thermochemical Storage | Department of Energy Project Profile: Engineering a Novel High Temperature Metal Hydride Thermochemical Storage Project Profile: Engineering a Novel High Temperature Metal Hydride Thermochemical Storage PNNL Logo Pacific Northwest National Lab (PNNL), through the Concentrating Solar Power: Efficiently Leveraging Equilibrium Mechanisms for Engineering New Thermochemical Storage (CSP: ELEMENTS) funding program, is developing a concept for high energy density

  10. Metal Hydrides for High-Temperature Power Generation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ronnebro, Ewa; Whyatt, Greg A.; Powell, Michael R.; Westman, Matthew P.; Zheng, Feng; Fang, Zhigang Zak

    2015-08-10

    Metal hydrides can be utilized for hydrogen storage and for thermal energy storage (TES) applications. By using TES with solar technologies, heat can be stored from sun energy to be used later which enables continuous power generation. We are developing a TES technology based on a dual-bed metal hydride system, which has a high-temperature (HT) metal hydride operating reversibly at 600-800°C to generate heat as well as a low-temperature (LT) hydride near room temperature that is used for hydrogen storage during sun hours until there is a need to produce electricity, such as during night time, a cloudy day, ormore » during peak hours. We proceeded from selecting a high-energy density, low-cost HT-hydride based on performance characterization on gram size samples, to scale-up to kilogram quantities and design, fabrication and testing of a 1.5kWh, 200kWh/m3 bench-scale TES prototype based on a HT-bed of titanium hydride and a hydrogen gas storage instead of a LT-hydride. COMSOL Multiphysics was used to make performance predictions for cylindrical hydride beds with varying diameters and thermal conductivities. Based on experimental and modeling results, a bench-scale prototype was designed and fabricated and we successfully showed feasibility to meet or exceed all performance targets.« less

  11. Porous metal hydride composite and preparation and uses thereof

    DOE Patents [OSTI]

    Steyert, William A.; Olsen, Clayton E.

    1982-01-01

    A composite formed from large pieces of aggregate formed from (1) metal hydride (or hydride-former) powder and (2) either metal powder or plastic powder or both is prepared. The composite has large macroscopic interconnected pores (much larger than the sizes of the powders which are used) and will have a very fast heat transfer rate and low windage loss. It will be useful, for example, in heat engines, hydrogen storage devices, and refrigerator components which depend for their utility upon both a fast rate of hydriding and dehydriding. Additionally, a method of preparing the composite and a method of increasing the rates of hydriding and dehydriding of metal hydrides are also given.

  12. Porous metal hydride composite and preparation and uses thereof

    DOE Patents [OSTI]

    Steyert, W.A.; Olsen, C.E.

    1980-03-12

    A composite formed from large pieces of aggregate formed from (1) metal hydride (or hydride-former) powder and (2) either metal powder or plastic powder or both is prepared. The composite has large macroscopic interconnected pores (much larger than the sizes of the powders which are used) and will have a very fast heat transfer rate and low windage loss. It will be useful, for example, in heat engines, hydrogen storage devices, and refrigerator components which depend for their utility upon both a fast rate of hydriding and dehydriding. Additionally, a method of preparing the composite and a method of increasing the rates of hydriding and dehydriding of metal hydrides are also given.

  13. Recent advances in metal hydrides for clean energy applications

    SciTech Connect (OSTI)

    Ronnebro, Ewa; Majzoub, Eric H.

    2013-06-01

    Metal hydrides are a fascinating class of materials that can be utilized for a surprising variety of clean energy applications, including smart solar collectors, smart windows, sensors, thermal energy storage, and batteries, in addition to their traditional application for hydrogen storage. Over the past decade, research on metal hydrides for hydrogen storage increased due to global governmental incentives and an increased focus on hydrogen storage research for polymer electrolyte membrane fuel cell operation. Tremendous progress has been made in so-called complex metal hydrides for hydrogen storage applications with the discovery of many new hydrides containing covalently bound complex anions. Many of these materials have applications beyond hydrogen storage and are being investigated for lithium-ion battery separator and anode materials. In this issue of MRS Bulletin , we present the state of the art of key evolving metal-hydride-based clean energy technologies with an outlook toward future needs.

  14. Metal hydride fuel storage and method thereof

    DOE Patents [OSTI]

    Morse, Jeffrey D.; Jankowski, Alan F.; Yu, Conrad

    2010-08-10

    An apparatus having a first substrate having (1) a cavity, (2) one or more resistive heaters, and (3) one or more coatings forming a diffusion barrier to hydrogen; a second substrate having (1) an outlet valve comprising a pressure relief structure and (2) one or more coatings forming a diffusion barrier to hydrogen, wherein said second substrate is coupled to said first substrate forming a sealed volume in said cavity; a metal hydride material contained within said cavity; and a gas distribution system formed by coupling a microfluidic interconnect to said pressure relief structure. Additional apparatuses and methods are also disclosed.

  15. Highly Concentrated Palladium Hydrides/Deuterides; Theory

    SciTech Connect (OSTI)

    Papaconstantopoulos, Dimitrios

    2013-11-26

    Accomplishments are reported in these areas: tight-binding molecular dynamics study of palladium; First-principles calculations and tight-binding molecular dynamics simulations of the palladium-hydrogen system; tight-binding studies of bulk properties and hydrogen vacancies in KBH{sub 4}; tight-binding study of boron structures; development of angular dependent potentials for Pd-H; and density functional and tight-binding calculations for the light-hydrides NaAlH4 and NaBH4

  16. The Hydriding Kinetics of Organic Hydrogen Getters

    SciTech Connect (OSTI)

    Powell, G. L.

    2002-02-11

    The aging of hermetically sealed systems is often accompanied by the gradual production of hydrogen gas that is a result of the decay of environmental gases and the degradation of organic materials. In particular, the oxygen, water, hydrogen ''equilibrium'' is affected by the removal of oxygen due the oxidation of metals and organic materials. This shift of the above ''equilibrium'' towards the formation of hydrogen gas, particularly in crevices, may eventually reach an explosive level of hydrogen gas or degrade metals by hydriding them. The latter process is generally delayed until the oxidizing species are significantly reduced. Organic hydrogen getters introduced by Allied Signal Aerospace Company, Kansas City Division have proven to be a very effective means of preventing hydrogen gas accumulation in sealed containers. These getters are relatively unaffected by air and environmental gases. They can be packaged in a variety of ways to fit particular needs such as porous pellets, fine or coarse [gravel] powder, or loaded into silicone rubber. The hydrogen gettering reactions are extremely irreversible since the hydrogen gas is converted into an organic hydrocarbon. These getters are based on the palladium-catalyzed hydrogenation of triple bonds to double and then single bonds in aromatic aryl compounds. DEB (1,4 bis (phenyl ethynyl) benzene) typically mixed with 25% by weight carbon with palladium (1% by weight of carbon) is one of the newest and best of these organic hydrogen getters. The reaction mechanisms are complex involving solid state reaction with a heterogeneous catalyst leading to the many intermediates, including mixed alkyl and aryl hydrocarbons with the possibilities of many isomers. The reaction kinetics mechanisms are also strongly influenced by the form in which they are packaged. For example, the hydriding rates for pellets and gravel have a strong dependence on reaction extent (i.e., DEB reduction) and a kinetic order in pressure of 0

  17. A new phase in palladium hydride technology

    SciTech Connect (OSTI)

    Walters, R.T.

    1991-12-31

    Two plateaux are observed in both the absorption and desorption isotherms of palladium hydride. For the absorption isotherm, a change in plateau pressure is observed at a hydrogen-to-metal (H/M) ratio of about 0.35 for all temperatures studied. For the desorption isotherm, the change in plateau pressure appears to be a function of temperature, ranging from an H/M ratio of 0.18 at 80{degrees}C to 0.3 at 140{degrees}C. These data are interpreted as being experimentally observed boundaries to an equilibrium phase line located in the miscibility gap of the palladium/hydrogen phase diagram. This new phase does not appear to be a stoichiometric compounds, but rather its composition seems to vary with temperature. 6 refs., 4 figs.

  18. A new phase in palladium hydride technology

    SciTech Connect (OSTI)

    Walters, R.T.

    1991-01-01

    Two plateaux are observed in both the absorption and desorption isotherms of palladium hydride. For the absorption isotherm, a change in plateau pressure is observed at a hydrogen-to-metal (H/M) ratio of about 0.35 for all temperatures studied. For the desorption isotherm, the change in plateau pressure appears to be a function of temperature, ranging from an H/M ratio of 0.18 at 80{degrees}C to 0.3 at 140{degrees}C. These data are interpreted as being experimentally observed boundaries to an equilibrium phase line located in the miscibility gap of the palladium/hydrogen phase diagram. This new phase does not appear to be a stoichiometric compounds, but rather its composition seems to vary with temperature. 6 refs., 4 figs.

  19. Process for production of a metal hydride

    DOE Patents [OSTI]

    Allen, Nathan Tait; Butterick, III, Robert; Chin, Arthur Achhing; Millar, Dean Michael; Molzahn, David Craig

    2014-08-12

    A process for production of a metal hydride compound MH.sub.x, wherein x is one or two and M is an alkali metal, Be or Mg. The process comprises combining a compound of formula (R.sup.1O).sub.xM with aluminum, hydrogen and at least one metal selected from among titanium, zirconium, hafnium, niobium, vanadium, tantalum and iron to produce a compound of formula MH.sub.x. R.sup.1 is phenyl or phenyl substituted by at least one alkyl or alkoxy group. A mole ratio of aluminum to (R.sup.1O).sub.xM is from 0.1:1 to 1:1. The catalyst is present at a level of at least 200 ppm based on weight of aluminum.

  20. Ni/metal hydride secondary element

    DOE Patents [OSTI]

    Bauerlein, Peter

    2005-04-19

    A Ni/metal hydride secondary element having a positive nickel hydroxide electrode, a negative electrode having a hydrogen storage alloy, and an alkaline electrolyte, the positive electrode, provided with a three-dimensional metallic conductive structure, also contains an aluminum compound which is soluble in the electrolyte, in addition to nickel hydroxide and cobalt oxide. The aluminum compound is aluminum hydroxide and/or aluminum oxide, and the mass of the aluminum compound which is present in the positive bulk material mixture is 0.1 to 2% by weight relative to the mass of the nickel hydroxide which is present. In combination with aluminum hydroxide or aluminum oxide, the positive electrode further contains lanthanoid oxidic compounds Y.sub.2 O.sub.3, La.sub.2 O.sub.3 and Ca(OH).sub.2, as well as mixtures of these compounds.

  1. Hydrogen storage in sodium aluminum hydride.

    SciTech Connect (OSTI)

    Ozolins, Vidvuds; Herberg, J.L.; McCarty, Kevin F.; Maxwell, Robert S.; Stumpf, Roland Rudolph; Majzoub, Eric H.

    2005-11-01

    Sodium aluminum hydride, NaAlH{sub 4}, has been studied for use as a hydrogen storage material. The effect of Ti, as a few mol. % dopant in the system to increase kinetics of hydrogen sorption, is studied with respect to changes in lattice structure of the crystal. No Ti substitution is found in the crystal lattice. Electronic structure calculations indicate that the NaAlH{sub 4} and Na{sub 3}AlH{sub 6} structures are complex-ionic hydrides with Na{sup +} cations and AlH{sub 4}{sup -} and AlH{sub 6}{sup 3-} anions, respectively. Compound formation studies indicate the primary Ti-compound formed when doping the material at 33 at. % is TiAl{sub 3} , and likely Ti-Al compounds at lower doping rates. A general study of sorption kinetics of NaAlH{sub 4}, when doped with a variety of Ti-halide compounds, indicates a uniform response with the kinetics similar for all dopants. NMR multiple quantum studies of solution-doped samples indicate solvent interaction with the doped alanate. Raman spectroscopy was used to study the lattice dynamics of NaAlH{sub 4}, and illustrated the molecular ionic nature of the lattice as a separation of vibrational modes between the AlH{sub 4}{sup -} anion-modes and lattice-modes. In-situ Raman measurements indicate a stable AlH{sub 4}{sup -} anion that is stable at the melting temperature of NaAlH{sub 4}, indicating that Ti-dopants must affect the Al-H bond strength.

  2. Complex Hydride Compounds with Enhanced Hydrogen Storage Capacity

    SciTech Connect (OSTI)

    Mosher, Daniel A.; Opalka, Susanne M.; Tang, Xia; Laube, Bruce L.; Brown, Ronald J.; Vanderspurt, Thomas H.; Arsenault, Sarah; Wu, Robert; Strickler, Jamie; Anton, Donald L.; Zidan, Ragaiy; Berseth, Polly

    2008-02-18

    between alkaline metal hydrides (AmH), Alkaline earth metal hydrides (AeH2), alane (AlH3), transition metal (Tm) hydrides (TmHz, where z=1-3) and molecular hydrogen (H2). The effort started first with variations of known alanates and subsequently extended the search to unknown compounds. In this stage, the FPM techniques were developed and validated on known alanate materials such as NaAlH4 and Na2LiAlH6. The coupled predictive methodologies were used to survey over 200 proposed phases in six quaternary spaces, formed from various combinations of Na, Li Mg and/or Ti with Al and H. A wide range of alanate compounds was examined using SSP having additions of Ti, Cr, Co, Ni and Fe. A number of compositions and reaction paths were identified having H weight fractions up to 5.6 wt %, but none meeting the 7.5 wt%H reversible goal. Similarly, MSP of alanates produced a number of interesting compounds and general conclusions regarding reaction behavior of mixtures during processing, but no alanate based candidates meeting the 7.5 wt% goal. A novel alanate, LiMg(AlH4)3, was synthesized using SBP that demonstrated a 7.0 wt% capacity with a desorption temperature of 150°C. The deuteride form was synthesized and characterized by the Institute for Energy (IFE) in Norway to determine its crystalline structure for related FPM studies. However, the reaction exhibited exothermicity and therefore was not reversible under acceptable hydrogen gas pressures for on-board recharging. After the extensive studies of alanates, the material class of emphasis was shifted to borohydrides. Through SBP, several ligand-stabilized Mg(BH4)2 complexes were synthesized. The Mg(BH4)2*2NH3 complex was found to change behavior with slightly different synthesis conditions and/or aging. One of the two mechanisms was an amine-borane (NH3BH3) like dissociation reaction which released up to 16 wt %H and more conservatively 9 wt%H when not including H2 released from the NH3. From FPM, the stability of the Mg(BH4

  3. Nonaqueous actinide hydride dissolution and production of actinide $beta$- diketonates

    DOE Patents [OSTI]

    Crisler, L.R.

    1975-11-11

    Actinide beta-diketonate complex molecular compounds are produced by reacting a beta-diketone compound with a hydride of the actinide material in a mixture of carbon tetrachloride and methanol. (auth)

  4. Effects of outgassing of loader chamber walls on hydriding of...

    Office of Scientific and Technical Information (OSTI)

    gas pressure. Complete process data for (1) a copper-(1.83 wt. %)beryllium wet hydrogen fired passivated (600 C-1 h) externally heated pipe hydriding chamber are reported....

  5. High capacity stabilized complex hydrides for hydrogen storage

    DOE Patents [OSTI]

    Zidan, Ragaiy; Mohtadi, Rana F; Fewox, Christopher; Sivasubramanian, Premkumar

    2014-11-11

    Complex hydrides based on Al(BH.sub.4).sub.3 are stabilized by the presence of one or more additional metal elements or organic adducts to provide high capacity hydrogen storage material.

  6. Method of selective reduction of halodisilanes with alkyltin hydrides

    DOE Patents [OSTI]

    D'Errico, John J.; Sharp, Kenneth G.

    1989-01-01

    The invention relates to the selective and sequential reduction of halodisilanes by reacting these compounds at room temperature or below with trialkyltin hydrides or dialkyltin dihydrides without the use of free radical intermediates. The alkyltin hydrides selectively and sequentially reduce the Si-Cl, Si-Br or Si-I bonds while leaving intact the Si-Si and Si-F bonds present.

  7. Method of selective reduction of polyhalosilanes with alkyltin hydrides

    DOE Patents [OSTI]

    Sharp, Kenneth G.; D'Errico, John J.

    1989-01-01

    The invention relates to the selective and stepwise reduction of polyhalosilanes by reacting at room temperature or below with alkyltin hydrides without the use of free radical intermediates. Alkyltin hydrides selectively and stepwise reduce the Si--Br, Si--Cl, or Si--I bonds while leaving intact any Si--F bonds. When two or more different halogens are present on the polyhalosilane, the halogen with the highest atomic weight is preferentially reduced.

  8. Duracell | Open Energy Information

    Open Energy Info (EERE)

    search Name: Duracell Product: Alkaline batteries manufacturer. Also markets primary lithium and zinc air batteries as well as rechargeable nickel-metal hydride batteries....

  9. Electro Energy Inc | Open Energy Information

    Open Energy Info (EERE)

    storage systems and solutions based on Bipolar Nickel Metal Hydride, Bipolar Lithium Ion and Super Ni-Cd Prismatic technologies. Coordinates: 46.00689, -92.373344...

  10. AIR PASSIVATION OF METAL HYDRIDE BEDS FOR WASTE DISPOSAL

    SciTech Connect (OSTI)

    Klein, J; R. H. Hsu, R

    2007-07-02

    Metal hydride beds offer compact, safe storage of tritium. After metal hydride beds have reached the end of their useful life, the beds will replaced with new beds and the old beds prepared for disposal. One acceptance criteria for hydride bed waste disposal is that the material inside the bed not be pyrophoric. To determine the pyrophoric nature of spent metal hydride beds, controlled air ingress tests were performed. A simple gas handling manifold fitted with pressure transducers and a calibrated volume were used to introduce controlled quantities of air into a metal hydride bed and the bed temperature rise monitored for reactivity with the air. A desorbed, 4.4 kg titanium prototype hydride storage vessel (HSV) produced a 4.4 C internal temperature rise upon the first air exposure cycle and a 0.1 C temperature rise upon a second air exposure. A total of 346 scc air was consumed by the bed (0.08 scc per gram Ti). A desorbed, 9.66 kg LaNi{sub 4.25}Al{sub 0.75} prototype storage bed experienced larger temperature rises over successive cycles of air ingress and evacuation. The cycles were performed over a period of days with the bed effectively passivated after the 12th cycle. Nine to ten STP-L of air reacted with the bed producing both oxidized metal and water.

  11. Chemical Hydride Slurry for Hydrogen Production and Storage

    SciTech Connect (OSTI)

    McClaine, Andrew W

    2008-09-30

    The purpose of this project was to investigate and evaluate the attractiveness of using a magnesium chemical hydride slurry as a hydrogen storage, delivery, and production medium for automobiles. To fully evaluate the potential for magnesium hydride slurry to act as a carrier of hydrogen, potential slurry compositions, potential hydrogen release techniques, and the processes (and their costs) that will be used to recycle the byproducts back to a high hydrogen content slurry were evaluated. A 75% MgH2 slurry was demonstrated, which was just short of the 76% goal. This slurry is pumpable and storable for months at a time at room temperature and pressure conditions and it has the consistency of paint. Two techniques were demonstrated for reacting the slurry with water to release hydrogen. The first technique was a continuous mixing process that was tested for several hours at a time and demonstrated operation without external heat addition. Further work will be required to reduce this design to a reliable, robust system. The second technique was a semi-continuous process. It was demonstrated on a 2 kWh scale. This system operated continuously and reliably for hours at a time, including starts and stops. This process could be readily reduced to practice for commercial applications. The processes and costs associated with recycling the byproducts of the water/slurry reaction were also evaluated. This included recovering and recycling the oils of the slurry, reforming the magnesium hydroxide and magnesium oxide byproduct to magnesium metal, hydriding the magnesium metal with hydrogen to form magnesium hydride, and preparing the slurry. We found that the SOM process, under development by Boston University, offers the lowest cost alternative for producing and recycling the slurry. Using the H2A framework, a total cost of production, delivery, and distribution of $4.50/kg of hydrogen delivered or $4.50/gge was determined. Experiments performed at Boston

  12. Influence of uranium hydride oxidation on uranium metal behaviour

    SciTech Connect (OSTI)

    Patel, N.; Hambley, D.; Clarke, S.A.; Simpson, K.

    2013-07-01

    This work addresses concerns that the rapid, exothermic oxidation of active uranium hydride in air could stimulate an exothermic reaction (burning) involving any adjacent uranium metal, so as to increase the potential hazard arising from a hydride reaction. The effect of the thermal reaction of active uranium hydride, especially in contact with uranium metal, does not increase in proportion with hydride mass, particularly when considering large quantities of hydride. Whether uranium metal continues to burn in the long term is a function of the uranium metal and its surroundings. The source of the initial heat input to the uranium, if sufficient to cause ignition, is not important. Sustained burning of uranium requires the rate of heat generation to be sufficient to offset the total rate of heat loss so as to maintain an elevated temperature. For dense uranium, this is very difficult to achieve in naturally occurring circumstances. Areas of the uranium surface can lose heat but not generate heat. Heat can be lost by conduction, through contact with other materials, and by convection and radiation, e.g. from areas where the uranium surface is covered with a layer of oxidised material, such as burned-out hydride or from fuel cladding. These rates of heat loss are highly significant in relation to the rate of heat generation by sustained oxidation of uranium in air. Finite volume modelling has been used to examine the behaviour of a magnesium-clad uranium metal fuel element within a bottle surrounded by other un-bottled fuel elements. In the event that the bottle is breached, suddenly, in air, it can be concluded that the bulk uranium metal oxidation reaction will not reach a self-sustaining level and the mass of uranium oxidised will likely to be small in relation to mass of uranium hydride oxidised. (authors)

  13. Investigation of Cracked Lithium Hydride Reactor Vessels

    SciTech Connect (OSTI)

    bird, e.l.; mustaleski, t.m.

    1999-06-01

    Visual examination of lithium hydride reactor vessels revealed cracks that were adjacent to welds, most of which were circumferentially located in the bottom portion of the vessels. Sections were cut from the vessels containing these cracks and examined by use of the metallograph, scanning electron microscope, and microprobe to determine the cause of cracking. Most of the cracks originated on the outer surface just outside the weld fusion line in the base material and propagated along grain boundaries. Crack depths of those examined sections ranged from {approximately}300 to 500 {micro}m. Other cracks were reported to have reached a maximum depth of 1/8 in. The primary cause of cracking was the creation of high tensile stresses associated with the differences in the coefficients of thermal expansion between the filler metal and the base metal during operation of the vessel in a thermally cyclic environment. This failure mechanism could be described as creep-type fatigue, whereby crack propagation may have been aided by the presence of brittle chromium carbides along the grain boundaries, which indicates a slightly sensitized microstructure.

  14. Metal hydride hydrogen compression: Recent advances and future prospects

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bowman, Jr., Robert C.; Yartys, Volodymyr A.; Lototskyy, Mykhaylo V.; Linkov, Vladimir; Grant, David; Stuart, Alastair; Eriksen, Jon; Denys, Roman

    2016-03-17

    Metal hydride (MH) thermal sorption compression is one of the more important applications of the metal hydrides. The present paper reviews recent advances in the field based on the analysis of the fundamental principles of this technology. The performances when boosting hydrogen pressure, along with two- and three-step compression units are analyzed. The paper includes also a theoretical modeling of a two-stage compressor aimed at both describing the performance of the experimentally studied systems, but, also, on their optimization and design of more advanced MH compressors. Business developments in the field are reviewed for the Norwegian company HYSTORSYS AS andmore » the South African Institute for Advanced Materials Chemistry. Finally, future prospects are outlined presenting the role of the metal hydride compression in the overall development of the hydrogen driven energy systems. Lastly, the work is based on the analysis of the development of the technology in Europe, USA and South Africa.« less

  15. Method for preparing hydride configurations and reactive metal surfaces

    DOE Patents [OSTI]

    Silver, G.L.

    1984-05-18

    A method for preparing reactive metal surfaces, particularly uranium surfaces is disclosed, whereby the metal is immediately reactive to hydrogen gas at room temperature and low pressure. The metal surfaces are first pretreated by exposure to an acid which forms an adherent hydride-bearing composition on the metal surface. Subsequent heating of the pretreated metal at a temperature sufficient to decompose the hydride coating in vacuum or inert gas renders the metal surface instantaneously reactive to hydrogen gas at room temperature and low pressure.

  16. Ab-initio study of transition metal hydrides

    SciTech Connect (OSTI)

    Sharma, Ramesh; Shukla, Seema Dwivedi, Shalini Sharma, Yamini

    2014-04-24

    We have performed ab initio self consistent calculations based on Full potential linearized augmented plane wave (FP-LAPW) method to investigate the optical and thermal properties of yttrium hydrides. From the band structure and density of states, the optical absorption spectra and specific heats have been calculated. The band structure of Yttrium metal changes dramatically due to hybridization of Y sp orbitals with H s orbitals and there is a net charge transfer from metal to hydrogen site. The electrical resistivity and specific heats of yttrium hydrides are lowered but the thermal conductivity is slightly enhanced due to increase in scattering from hydrogen sites.

  17. METHOD OF PREPARING SINTERED ZIRCONIUM METAL FROM ITS HYDRIDES

    DOE Patents [OSTI]

    Angier, R.P.

    1958-02-11

    The invention relates to the preparation of metal shapes from zirconium hydride by powder metallurgical techniques. The zirconium hydride powder which is to be used for this purpose can be prepared by rendering massive pieces of crystal bar zirconium friable by heat treatment in purified hydrogen. This any then be ground into powder and powder can be handled in the air without danger of it igniting. It may then be compacted in the normal manner by being piaced in a die. The compact is sintered under vacuum conditions preferably at a temperature ranging from 1200 to 1300 deg C and for periods of one to three hours.

  18. Process of forming a sol-gel/metal hydride composite

    DOE Patents [OSTI]

    Congdon, James W.

    2009-03-17

    An external gelation process is described which produces granules of metal hydride particles contained within a sol-gel matrix. The resulting granules are dimensionally stable and are useful for applications such as hydrogen separation and hydrogen purification. An additional coating technique for strengthening the granules is also provided.

  19. Cascades for hydrogen isotope separation using metal hydrides

    SciTech Connect (OSTI)

    Hill, F.B.; Grzetic, V.

    1982-01-01

    Designs are presented for continuous countercurrent hydrogen isotope separation cascades based on the use of metal hydrides. The cascades are made up of pressure swing adsorption (PSA) or temperature swing adsorption (TSA) stages. The designs were evolved from consideration of previously conducted studies of the separation performance of four types of PSA and TSA processes.

  20. Composite Materials for Hazard Mitigation of Reactive Metal Hydrides.

    SciTech Connect (OSTI)

    Pratt, Joseph William; Cordaro, Joseph Gabriel; Sartor, George B.; Dedrick, Daniel E.; Reeder, Craig L.

    2012-02-01

    In an attempt to mitigate the hazards associated with storing large quantities of reactive metal hydrides, polymer composite materials were synthesized and tested under simulated usage and accident conditions. The composites were made by polymerizing vinyl monomers using free-radical polymerization chemistry, in the presence of the metal hydride. Composites with vinyl-containing siloxane oligomers were also polymerized with and without added styrene and divinyl benzene. Hydrogen capacity measurements revealed that addition of the polymer to the metal hydride reduced the inherent hydrogen storage capacity of the material. The composites were found to be initially effective at reducing the amount of heat released during oxidation. However, upon cycling the composites, the mitigating behavior was lost. While the polymer composites we investigated have mitigating potential and are physically robust, they undergo a chemical change upon cycling that makes them subsequently ineffective at mitigating heat release upon oxidation of the metal hydride. Acknowledgements The authors would like to thank the following people who participated in this project: Ned Stetson (U.S. Department of Energy) for sponsorship and support of the project. Ken Stewart (Sandia) for building the flow-through calorimeter and cycling test stations. Isidro Ruvalcaba, Jr. (Sandia) for qualitative experiments on the interaction of sodium alanate with water. Terry Johnson (Sandia) for sharing his expertise and knowledge of metal hydrides, and sodium alanate in particular. Marcina Moreno (Sandia) for programmatic assistance. John Khalil (United Technologies Research Corp) for insight into the hazards of reactive metal hydrides and real-world accident scenario experiments. Summary In an attempt to mitigate and/or manage hazards associated with storing bulk quantities of reactive metal hydrides, polymer composite materials (a mixture of a mitigating polymer and a metal hydride) were synthesized and tested

  1. FEASIBILITY OF RECYCLING PLUTONIUM AND MINOR ACTINIDES IN LIGHT WATER REACTORS USING HYDRIDE FUEL

    SciTech Connect (OSTI)

    Greenspan, Ehud; Todreas, Neil; Taiwo, Temitope

    2009-03-10

    The objective of this DOE NERI program sponsored project was to assess the feasibility of improving the plutonium (Pu) and minor actinide (MA) recycling capabilities of pressurized water reactors (PWRs) by using hydride instead of oxide fuels. There are four general parts to this assessment: 1) Identifying promising hydride fuel assembly designs for recycling Pu and MAs in PWRs 2) Performing a comprehensive systems analysis that compares the fuel cycle characteristics of Pu and MA recycling in PWRs using the promising hydride fuel assembly designs identified in Part 1 versus using oxide fuel assembly designs 3) Conducting a safety analysis to assess the likelihood of licensing hydride fuel assembly designs 4) Assessing the compatibility of hydride fuel with cladding materials and water under typical PWR operating conditions Hydride fuel was found to offer promising transmutation characteristics and is recommended for further examination as a possible preferred option for recycling plutonium in PWRs.

  2. The Role of Impurities in the Complex Hydrides

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Impurities in the Complex Hydrides Eric H. Majzoub Center for Nanoscience Department of Physics University of Missouri - St. Louis Acknowledgements UMSL Xianfeng Liu, David Peaslee, Tim Mason, Dongxue Zhao, Gang Wang, Chris Carr, Waruni Jayawardana, Alyssa McFarlane, Henry Hamper, Hua Ning SNL Vitalie Stavila, Mark Allendorf, Lennie Klebanoff * Department of Energy EERE * Boeing * NASA Space grant Consortium 2 Objectives and Overview I. Fundamental Limitations - density of hydrogen and

  3. METHOD OF MAKING DELTA ZIRCONIUM HYDRIDE MONOLITHIC MODERATOR PIECES

    DOE Patents [OSTI]

    Vetrano, J.B.

    1962-01-23

    A method is given for preparing large, sound bodies of delta zirconium hydride. The method includes the steps of heating a zirconium body to a temperature of not less than l000 deg C, providing a hydrogen atmosphere for the zirconium body at a pressure not greater than one atmosphere, reducing the temperature slowly to 800 deg C at such a rate that cracks do not form while maintaining the hydrogen pressure substantially constant, and cooling in an atmosphere of hydrogen. (AEC)

  4. Parking heater and method using hydrides in motor vehicles powered by hydrogen

    SciTech Connect (OSTI)

    Buchner, H.; Saufferer, H.

    1980-07-29

    A method for parking heating of at least the passenger compartment of motor vehicles operated at least partially on hydrogen and having a hydride reservoir, wherein the hydride reservoir is a Lt/Ht hydride combination, comprising supplying the heat capacity of the Ht reservoir, present after the engine is shut off or produced by charging with hydrogen, at least partially to the passenger compartment.

  5. Project Profile: Low-Cost Metal Hydride Thermal Energy Storage System |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Metal Hydride Thermal Energy Storage System Project Profile: Low-Cost Metal Hydride Thermal Energy Storage System Savannah River National Laboratory logo -- This project is inactive -- The Savannah River National Laboratory (SRNL), under the National Laboratory R&D competitive funding opportunity, is collaborating with Curtin University (CU) to evaluate new metal hydride materials for thermal energy storage (TES) that meet the SunShot cost and performance targets for

  6. Diffusional exchange of isotopes in a metal hydride sphere.

    SciTech Connect (OSTI)

    Wolfer, Wilhelm G.; Hamilton, John C.; James, Scott Carlton

    2011-04-01

    This report describes the Spherical Particle Exchange Model (SPEM), which simulates exchange of one hydrogen isotope by another hydrogen isotope in a spherical metal hydride particle. This is one of the fundamental physical processes during isotope exchange in a bed of spherical metal particles and is thus one of the key components in any comprehensive physics-based model of exchange. There are two important physical processes in the model. One is the entropy of mixing between the two isotopes; the entropy of mixing is increased by having both isotopes randomly placed at interstitial sites on the lattice and thus impedes the exchange process. The other physical process is the elastic interaction between isotope atoms on the lattice. The elastic interaction is the cause for {beta}-phase formation and is independent of the isotope species. In this report the coupled diffusion equations for two isotopes in the {beta}-phase hydride are solved. A key concept is that the diffusion of one isotope depends not only on its concentration gradient, but also on the concentration gradient of the other isotope. Diffusion rate constants and the chemical potentials for deuterium and hydrogen in the {beta}-phase hydride are reviewed because these quantities are essential for an accurate model of the diffusion process. Finally, a summary of some of the predictions from the SPEM model are provided.

  7. Uranium metal reactions with hydrogen and water vapour and the reactivity of the uranium hydride produced

    SciTech Connect (OSTI)

    Godfrey, H.; Broan, C.; Goddard, D.; Hodge, N.; Woodhouse, G.; Diggle, A.; Orr, R.

    2013-07-01

    Within the nuclear industry, metallic uranium has been used as a fuel. If this metal is stored in a hydrogen rich environment then the uranium metal can react with the hydrogen to form uranium hydride which can be pyrophoric when exposed to air. The UK National Nuclear Laboratory has been carrying out a programme of research for Sellafield Limited to investigate the conditions required for the formation and persistence of uranium hydride and the reactivity of the material formed. The experimental results presented here have described new results characterising uranium hydride formed from bulk uranium at 50 and 160 C. degrees and measurements of the hydrolysis kinetics of these materials in liquid water. It has been shown that there is an increase in the proportion of alpha-uranium hydride in material formed at lower temperatures and that there is an increase in the rate of reaction with water of uranium hydride formed at lower temperatures. This may at least in part be attributable to a difference in the reaction rate between alpha and beta-uranium hydride. A striking observation is the strong dependence of the hydrolysis reaction rate on the temperature of preparation of the uranium hydride. For example, the reaction rate of uranium hydride prepared at 50 C. degrees was over ten times higher than that prepared at 160 C. degrees at 20% extent of reaction. The decrease in reaction rate with the extent of reaction also depended on the temperature of uranium hydride preparation.

  8. Combined on-board hydride slurry storage and reactor system and process for hydrogen-powered vehicles and devices

    DOE Patents [OSTI]

    Brooks, Kriston P; Holladay, Jamelyn D; Simmons, Kevin L; Herling, Darrell R

    2014-11-18

    An on-board hydride storage system and process are described. The system includes a slurry storage system that includes a slurry reactor and a variable concentration slurry. In one preferred configuration, the storage system stores a slurry containing a hydride storage material in a carrier fluid at a first concentration of hydride solids. The slurry reactor receives the slurry containing a second concentration of the hydride storage material and releases hydrogen as a fuel to hydrogen-power devices and vehicles.

  9. Hydrogen storage as a hydride. (Latest citations from the Aerospace database). Published Search

    SciTech Connect (OSTI)

    1995-01-01

    The bibliography contains citations concerning the storage of hydrogen in various metal hydrides. Binary and intermetallic hydrides are considered. Specific alloys discussed are iron-titanium, lanthanum-nickel, magnesium-copper, and magnesium-nickel among others. (Contains a minimum of 220 citations and includes a subject term index and title list.)

  10. Hydrogen storage material and process using graphite additive with metal-doped complex hydrides

    DOE Patents [OSTI]

    Zidan, Ragaiy; Ritter, James A.; Ebner, Armin D.; Wang, Jun; Holland, Charles E.

    2008-06-10

    A hydrogen storage material having improved hydrogen absorbtion and desorption kinetics is provided by adding graphite to a complex hydride such as a metal-doped alanate, i.e., NaAlH.sub.4. The incorporation of graphite into the complex hydride significantly enhances the rate of hydrogen absorbtion and desorption and lowers the desorption temperature needed to release stored hydrogen.

  11. Chemical Hydrides for Hydrogen Storage in Fuel Cell Applications

    SciTech Connect (OSTI)

    Devarakonda, Maruthi N.; Brooks, Kriston P.; Ronnebro, Ewa; Rassat, Scot D.; Holladay, Jamelyn D.

    2012-04-16

    Due to its high hydrogen storage capacity (up to 19.6% by weight for the release of 2.5 molar equivalents of hydrogen gas) and its stability under typical ambient conditions, ammonia borane (AB) is a promising material for chemical hydrogen storage for fuel cell applications in transportation sector. Several systems models for chemical hydride materials such as solid AB, liquid AB and alane were developed and evaluated at PNNL to determine an optimal configuration that would meet the 2010 and future DOE targets for hydrogen storage. This paper presents an overview of those systems models and discusses the simulation results for various transient drive cycle scenarios.

  12. Electrochemical process and production of novel complex hydrides

    DOE Patents [OSTI]

    Zidan, Ragaiy

    2013-06-25

    A process of using an electrochemical cell to generate aluminum hydride (AlH.sub.3) is provided. The electrolytic cell uses a polar solvent to solubilize NaAlH.sub.4. The resulting electrochemical process results in the formation of AlH.sub.3. The AlH.sub.3 can be recovered and used as a source of hydrogen for the automotive industry. The resulting spent aluminum can be regenerated into NaAlH.sub.4 as part of a closed loop process of AlH.sub.3 generation.

  13. ACCEPTABILITY ENVELOPE FOR METAL HYDRIDE-BASED HYDROGEN STORAGE SYSTEMS

    SciTech Connect (OSTI)

    Hardy, B.; Corgnale, C.; Tamburello, D.; Garrison, S.; Anton, D.

    2011-07-18

    The design and evaluation of media based hydrogen storage systems requires the use of detailed numerical models and experimental studies, with significant amount of time and monetary investment. Thus a scoping tool, referred to as the Acceptability Envelope, was developed to screen preliminary candidate media and storage vessel designs, identifying the range of chemical, physical and geometrical parameters for the coupled media and storage vessel system that allow it to meet performance targets. The model which underpins the analysis allows simplifying the storage system, thus resulting in one input-one output scheme, by grouping of selected quantities. Two cases have been analyzed and results are presented here. In the first application the DOE technical targets (Year 2010, Year 2015 and Ultimate) are used to determine the range of parameters required for the metal hydride media and storage vessel. In the second case the most promising metal hydrides available are compared, highlighting the potential of storage systems, utilizing them, to achieve 40% of the 2010 DOE technical target. Results show that systems based on Li-Mg media have the best potential to attain these performance targets.

  14. Method of generating hydrogen-storing hydride complexes

    DOE Patents [OSTI]

    Srinivasan, Sesha S; Niemann, Michael U; Goswami, D. Yogi; Stefanakos, Elias K

    2013-05-14

    A ternary hydrogen storage system having a constant stoichiometric molar ratio of LiNH.sub.2:MgH.sub.2:LiBH.sub.4 of 2:1:1. It was found that the incorporation of MgH.sub.2 particles of approximately 10 nm to 20 nm exhibit a lower initial hydrogen release temperature of 150.degree. C. Furthermore, it is observed that the particle size of LiBNH quaternary hydride has a significant effect on the hydrogen sorption concentration with an optimum size of 28 nm. The as-synthesized hydrides exhibit two main hydrogen release temperatures, one around 160.degree. C. and the other around 300.degree. C., with the main hydrogen release temperature reduced from 310.degree. C. to 270.degree. C., while hydrogen is first reversibly released at temperatures as low as 150.degree. C. with a total hydrogen capacity of 6 wt. % to 8 wt. %. Detailed thermal, capacity, structural and microstructural properties have been demonstrated and correlated with the activation energies of these materials.

  15. Final report for the DOE Metal Hydride Center of Excellence.

    SciTech Connect (OSTI)

    Keller, Jay O.; Klebanoff, Leonard E.

    2012-01-01

    This report summarizes the R&D activities within the U.S. Department of Energy Metal Hydride Center of Excellence (MHCoE) from March 2005 to June 2010. The purpose of the MHCoE has been to conduct highly collaborative and multi-disciplinary applied R&D to develop new reversible hydrogen storage materials that meet or exceed DOE 2010 and 2015 system goals for hydrogen storage materials. The MHCoE combines three broad areas: mechanisms and modeling (which provide a theoretically driven basis for pursuing new materials), materials development (in which new materials are synthesized and characterized) and system design and engineering (which allow these new materials to be realized as practical automotive hydrogen storage systems). This Final Report summarizes the organization and execution of the 5-year research program to develop practical hydrogen storage materials for light duty vehicles. Major results from the MHCoE are summarized, along with suggestions for future research areas.

  16. Neutron Irradiation of Hydrided Cladding Material in HFIR Summary of Initial Activities

    Office of Energy Efficiency and Renewable Energy (EERE)

    Irradiation is known to have a significant impact on the properties and performance of Zircaloy cladding and structural materials (material degradation processes, e.g., effects of hydriding).  This...

  17. Documentation of Hybrid Hydride Model for Incorporation into Moose-Bison and Validation Strategy

    Office of Energy Efficiency and Renewable Energy (EERE)

    This report documents the development, demonstration and validation of a mesoscale, microstructural evolution model for simulation of zirconium hydride d-ZrH1.5 precipitation in the cladding of...

  18. Request Number:

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3023307 Name: Madeleine Brown Organization: nJa Address: --- -------- -------- -- Country: Phone Number: United States Fax Number: n/a E-mail: --- -------- --------_._------ --- Reasonably Describe Records Description: Please send me a copy of the emails and records relating to the decision to allow the underage son of Bill Gates to tour Hanford in June 2010. Please also send the emails and records that justify the Department of Energy to prevent other minors from visiting B Reactor. Optional

  19. Request Number:

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1074438 Name: Gayle Cooper Organization: nla Address: _ Country: United States Phone Number: Fax Number: nla E-mail: . ~===--------- Reasonably Describe Records Description: Information pertaining to the Department of Energy's cost estimate for reinstating pension benefit service years to the Enterprise Company (ENCO) employees who are active plan participants in the Hanford Site Pension Plan. This cost estimate was an outcome of the DOE's Worker Town Hall Meetings held on September 17-18, 2009.

  20. Final Report for the DOE Metal Hydride Center of Excellence | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy for the DOE Metal Hydride Center of Excellence Final Report for the DOE Metal Hydride Center of Excellence This technical report describes the activities carried out, key accomplishments, and recommendations from the DOE's Chemical Hydrogen Storage Center of Excellence, led by Los Alamos National Laboratory with Pacific Northwest National Laboratory from 2005 through 2010. The center's focus was the development of advanced chemical hydrogen storage materials that had the potential to

  1. Photogeneration of Hydride Donors and Their Use Toward CO2 Reduction

    SciTech Connect (OSTI)

    Fujita,E.; Muckerman, J.T.; Polyansky, D.E.

    2009-06-07

    Despite substantial effort, no one has succeeded in efficiently producing methanol from CO2 using homogeneous photocatalytic systems. We are pursuing reaction schemes based on a sequence of hydride-ion transfers to carry out stepwise reduction of CO2 to methanol. We are using hydride-ion transfer from photoproduced C-H bonds in metal complexes with bio-inspired ligands (i.e., NADH-like ligands) that are known to store one proton and two electrons.

  2. Advanced Metal-Hydrides-Based Thermal Battery: A New Generation of High Density Thermal Battery Based on Advanced Metal Hydrides

    SciTech Connect (OSTI)

    2011-12-01

    HEATS Project: The University of Utah is developing a compact hot-and-cold thermal battery using advanced metal hydrides that could offer efficient climate control system for EVs. The team’s innovative designs of heating and cooling systems for EVs with high energy density, low-cost thermal batteries could significantly reduce the weight and eliminate the space constraint in automobiles. The thermal battery can be charged by plugging it into an electrical outlet while charging the electric battery and it produces heat and cold through a heat exchanger when discharging. The ultimate goal of the project is a climate-controlling thermal battery that can last up to 5,000 charge and discharge cycles while substantially increasing the driving range of EVs, thus reducing the drain on electric batteries.

  3. First-principles calculations of niobium hydride formation in superconducting radio-frequency cavities

    SciTech Connect (OSTI)

    Ford, Denise C.; Cooley, Lance D.; Seidman, David N.

    2013-09-01

    Niobium hydride is suspected to be a major contributor to degradation of the quality factor of niobium superconducting radio-frequency (SRF) cavities. In this study, we connect the fundamental properties of hydrogen in niobium to SRF cavity performance and processing. We modeled several of the niobium hydride phases relevant to SRF cavities and present their thermodynamic, electronic, and geometric properties determined from calculations based on density-functional theory. We find that the absorption of hydrogen from the gas phase into niobium is exothermic and hydrogen becomes somewhat anionic. The absorption of hydrogen by niobium lattice vacancies is strongly preferred over absorption into interstitial sites. A single vacancy can accommodate six hydrogen atoms in the symmetrically equivalent lowest-energy sites and additional hydrogen in the nearby interstitial sites affected by the strain field: this indicates that a vacancy can serve as a nucleation center for hydride phase formation. Small hydride precipitates may then occur near lattice vacancies upon cooling. Vacancy clusters and extended defects should also be enriched in hydrogen, potentially resulting in extended hydride phase regions upon cooling. We also assess the phase changes in the niobium-hydrogen system based on charge transfer between niobium and hydrogen, the strain field associated with interstitial hydrogen, and the geometry of the hydride phases. The results of this study stress the importance of not only the hydrogen content in niobium, but also the recovery state of niobium for the performance of SRF cavities.

  4. (Document Number)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A TA-53 TOUR FORM/RADIOLOGICAL LOG (Send completed form to MS H831) _____________ _____________________________ _________________________________ Tour Date Purpose of Tour or Tour Title Start Time and Approximate Duration ___________________________ ______________ _______________________ _________________ Tour Point of Contact/Requestor Z# (if applicable) Organization/Phone Number Signature Locations Visited: (Check all that apply, and list any others not shown. Prior approval must be obtained

  5. Documentation of Hybrid Hydride Model for Incorporation into Moose-Bison and Validation Strategy.

    SciTech Connect (OSTI)

    Weck, Philippe F; Tikare, Veena; Schultz, Peter Andrew; Clark, B; Mitchell, J; Glazoff, Michael V.; Homer, Eric R.

    2014-10-01

    This report documents the development, demonstration and validation of a mesoscale, microstructural evolution model for simulation of zirconium hydride δ-ZrH{sub 1.5} precipitation in the cladding of used nuclear fuels that may occur during long-term dry storage. While the Zr-based claddings are manufactured free of any hydrogen, they absorb hydrogen during service, in the reactor by a process commonly termed ‘hydrogen pick-up’. The precipitation and growth of zirconium hydrides during dry storage is one of the most likely fuel rod integrity failure mechanisms either by embrittlement or delayed hydride cracking of the cladding (Hanson et al., 2011). While the phenomenon is well documented and identified as a potential key failure mechanism during long-term dry storage (Birk et al., 2012 and NUREG/CR-7116), the ability to actually predict the formation of hydrides is poor. The model being documented in this work is a computational capability for the prediction of hydride formation in different claddings of used nuclear fuels. This work supports the Used Fuel Disposition Research and Development Campaign in assessing the structural engineering performance of the cladding during and after long-term dry storage. In this work, a model to numerically simulate hydride precipitation at the microstructural scale, in a wide variety of Zr-based claddings, under dry-storage conditions is being developed. It will be used to aid in the evaluation of the mechanical integrity of used fuel rods during dry storage and transportation by providing the structural conditions from the microstructural scale to the continuum scale to engineering component scale models to predict if the used fuel rods will perform without failure under normal and off-normal conditions. The microstructure, especially, the hydride structure is thought to be a primary determinant of cladding failure, thus this component of UFD’s storage and transportation analysis program is critical. The model

  6. Homogeneous hydride formation path in α-Zr: Molecular dynamics simulations with the charge-optimized many-body potential

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhang, Yongfeng; Bai, Xian-Ming; Yu, Jianguo; Tonks, Michael R.; Noordhoek, Mark J.; Phillpot, Simon R.

    2016-06-01

    A formation path for homogeneous γ hydride formation in hcp α-Zr, from solid solution to the ζ and then the γ hydride, was demonstrated using molecular static calculations and molecular dynamic simulations with the charge-optimized many-body (COMB) potential. Hydrogen has limited solubility in α-Zr. Once the solubility limit is exceeded, the stability of solid solution gives way to that of coherent hydride phases such as the ζ hydride by planar precipitation of hydrogen. At finite temperatures, the ζ hydride goes through a partial hcp-fcc transformation via 1/3 <1¯100> slip on the basal plane, and transforms into a mixture of γmore » hydride and α-Zr. In the ζ hydride, slip on the basal plane is favored thermodynamically with negligible barrier, and is therefore feasible at finite temperatures without mechanical loading. The transformation process involves slips of three equivalent shear partials, in contrast to that proposed in the literature where only a single shear partial was involved. The adoption of multiple slip partials minimizes the macroscopic shape change of embedded hydride clusters and the shear strain accumulation in the matrix, and thus reduces the overall barrier needed for homogeneous γ hydride formation. In conclusion, this formation path requires finite temperatures for hydrogen diffusion without mechanical loading. Therefore, it should be effective at the cladding operating conditions.« less

  7. Synthesis and characterization of metal hydride electrodes. Interim report

    SciTech Connect (OSTI)

    McBreen, J.; Reilly, J.J.

    1995-10-01

    The objective of this project is to elucidate the compositional and structural parameters that affect the thermodynamics, kinetics and stability of alloy hydride electrodes and to use this information in the development of new high capacity long life hydride electrodes for rechargeable batteries. The work focuses on the development of AB{sub 5} alloys and the application of in situ methods, at NSLS, such as x-ray absorption (XAS), to elucidate the role of the alloying elements in hydrogen storage and corrosion inhibition. The most significant results to date are: The decay of electrode capacity on cycling was directly related to alloy corrosion. The rate of corrosion depended in part on both the alloy composition and the partial molar volume of hydrogen, V{sub H}. The corrosion rate depended on the composition of the A component in AB{sub 5} (LaNi{sub 5} type) alloys. Partial substitution of La with Ce in AB{sub 5} alloys substantially inhibits electrode corrosion on cycling. Recent results indicate that Co also greatly inhibits electrode corrosion, possibly by minimizing V{sub H}. The AB{sub 5} alloys investigated included LaNi{sub 5}, ternary alloys (e.g. LaN{sub 4.8}Sn{sub 0.2} and La{sub 0.8}Ce{sub 0.2}Ni{sub 5}), alloys with various substitutions for both La and Ni (e.g. La{sub 0.8}Ce{sub 0.2}Ni{sub 4.8}Sn{sub 0.2}) and mischmetal (Mm) alloys of the type normally used in batteries, such as MmB{sub 5} (B = Ni{sub 3.55}Mn{sub 0.4}A1{sub 0.3}Co{sub 0.75}). A major effort was devoted to the effects of La substitution in the A component. Both in situ and ex situ XAS measurements are used to study the electronic effects that occur on the addition of various metal substitutions and on the ingress of hydrogen.

  8. Applications of nuclear reaction analysis to metal hydride film characterization at the GEND 200 KeV accelerator facility

    SciTech Connect (OSTI)

    Malbrough, D.J.; Becker, R.H.

    1985-01-01

    Nuclear reaction analysis (NRA) is a quantitative analytical technique that usually involves the use of MeV ion beams and resonant nuclear reactions to non-destructively probe materials for elemental content and depth profiles. Low energy, non-resonant nuclear reactions can also be exploited for NRA and procedures have been developed for using the GEND 200-KeV accelerator to characterize neutron generator components by that technique. The procedures involve the detection and analysis of fusion reaction products generated by the interactions of deuteron beams with light elements in metal hydride films. A description of the accelerator system is presented along with some of the unique NRA procedures that have recently been developed for its use. The system is used to measure neutron output efficiencies of metal deuterides and tritides by the associated particle technique (APT) and accurate neutron yield measurements have been made for a number of materials for which data was formerly not available.

  9. Electronic structure and crystal phase stability of palladium hydrides

    SciTech Connect (OSTI)

    Houari, Abdesalem; Matar, Samir F.; Eyert, Volker

    2014-11-07

    The results of electronic structure calculations for a variety of palladium hydrides are presented. The calculations are based on density functional theory and used different local and semilocal approximations. The thermodynamic stability of all structures as well as the electronic and chemical bonding properties are addressed. For the monohydride, taking into account the zero-point energy is important to identify the octahedral Pd-H arrangement with its larger voids and, hence, softer hydrogen vibrational modes as favorable over the tetrahedral arrangement as found in the zincblende and wurtzite structures. Stabilization of the rocksalt structure is due to strong bonding of the 4d and 1s orbitals, which form a characteristic split-off band separated from the main d-band group. Increased filling of the formerly pure d states of the metal causes strong reduction of the density of states at the Fermi energy, which undermines possible long-range ferromagnetic order otherwise favored by strong magnetovolume effects. For the dihydride, octahedral Pd-H arrangement as realized, e.g., in the pyrite structure turns out to be unstable against tetrahedral arrangement as found in the fluorite structure. Yet, from both heat of formation and chemical bonding considerations, the dihydride turns out to be less favorable than the monohydride. Finally, the vacancy ordered defect phase Pd{sub 3}H{sub 4} follows the general trend of favoring the octahedral arrangement of the rocksalt structure for Pd:H ratios less or equal to one.

  10. Benefit-Cost Evaluation of U.S. DOE Investment in Energy Storage...

    Office of Environmental Management (EM)

    in nickel metal hydride (NiMH) and lithium ion (Li-ion) battery technologies-the two chemistry families that power all hybrid and electric cars and trucks on the road today. ...

  11. BYD Company Ltd | Open Energy Information

    Open Energy Info (EERE)

    has two main divisions, IT Parts and Auto. In IT parts, their main products include lithium-ion, nickel-cadmium, and nickel-metal hydride rechargeable batteries. Their...

  12. Johnson Controls Saft Advanced Power Solutions | Open Energy...

    Open Energy Info (EERE)

    venture between SAFT and Johnson Controls to produce and sell nickel-metal-hydride and lithium-ion batteries for HEVs and EVs. References: Johnson Controls-Saft Advanced Power...

  13. New sealed rechargeable batteries and supercapacitors

    SciTech Connect (OSTI)

    Barnett, B.M. ); Dowgiallo, E. ); Halpert, G. ); Matsuda, Y. ); Takehara, Z.I. )

    1993-01-01

    This conference was divided into the following sections: supercapacitors; nickel-metal hydride batteries; lithium polymer batteries; lithium/carbon batteries; cathode materials; and lithium batteries. Separate abstracts were prepared for the 46 papers of this conference.

  14. The affect of erbium hydride on the conversion efficience to accelerated protons from ultra-shsort pulse laser irradiated foils

    SciTech Connect (OSTI)

    Offermann, D

    2008-09-04

    This thesis work explores, experimentally, the potential gains in the conversion efficiency from ultra-intense laser light to proton beams using erbium hydride coatings. For years, it has been known that contaminants at the rear surface of an ultra-intense laser irradiated thin foil will be accelerated to multi-MeV. Inertial Confinement Fusion fast ignition using proton beams as the igniter source requires of about 10{sup 16} protons with an average energy of about 3MeV. This is far more than the 10{sup 12} protons available in the contaminant layer. Target designs must include some form of a hydrogen rich coating that can be made thick enough to support the beam requirements of fast ignition. Work with computer simulations of thin foils suggest the atomic mass of the non-hydrogen atoms in the surface layer has a strong affect on the conversion efficiency to protons. For example, the 167amu erbium atoms will take less energy away from the proton beam than a coating using carbon with a mass of 12amu. A pure hydrogen coating would be ideal, but technologically is not feasible at this time. In the experiments performed for my thesis, ErH{sub 3} coatings on 5 {micro}m gold foils are compared with typical contaminants which are approximately equivalent to CH{sub 1.7}. It will be shown that there was a factor of 1.25 {+-} 0.19 improvement in the conversion efficiency for protons above 3MeV using erbium hydride using the Callisto laser. Callisto is a 10J per pulse, 800nm wavelength laser with a pulse duration of 200fs and can be focused to a peak intensity of about 5 x 10{sup 19}W/cm{sup 2}. The total number of protons from either target type was on the order of 10{sup 10}. Furthermore, the same experiment was performed on the Titan laser, which has a 500fs pulse duration, 150J of energy and can be focused to about 3 x 10{sup 20} W/cm{sup 2}. In this experiment 10{sup 12} protons were seen from both erbium hydride and contaminants on 14 {micro} m gold foils. Significant

  15. Materials Down-selection Decisions Made within the DOE Metal Hydride Center of Excellence (MHCoE) - September-October 2007

    SciTech Connect (OSTI)

    Klebanoff, Lennie

    2007-09-01

    Reports on which hydrogen storage materials offer potential for further research as decided by DOE's Metal Hydride Center of Excellence.

  16. Materials Down-selection Decisions Made within the DOE Metal Hydride Center of Excellence (MHCoE) - September-October 2007

    Fuel Cell Technologies Publication and Product Library (EERE)

    Reports on which hydrogen storage materials offer potential for further research as decided by DOE's Metal Hydride Center of Excellence.

  17. Communications and Public Affairs Homepage | U.S. DOE Office of Science

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Commercialization Commercialization <a href="http://energy.gov/node/307033/">See an example of these steps in the commercialization process of Nickel Metal Hydride Batteries</a>. See an example of these steps in the commercialization process of Nickel Metal Hydride Batteries. Commercialization is the process by which technologies and innovations developed in the lab make their way to market. By licensing patents or using Energy Department facilities, researchers from the

  18. Commercialization | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Commercialization Commercialization <a href="http://energy.gov/node/307033/">See an example of these steps in the commercialization process of Nickel Metal Hydride Batteries</a>. See an example of these steps in the commercialization process of Nickel Metal Hydride Batteries. Commercialization is the process by which technologies and innovations developed in the lab make their way to market. By licensing patents or using Energy Department facilities, researchers from the

  19. Discovery of Novel Complex Metal Hydrides for Hydrogen Storage through Molecular Modeling and Combinatorial Methods

    SciTech Connect (OSTI)

    Lesch, David A; Adriaan Sachtler, J.W. J.; Low, John J; Jensen, Craig M; Ozolins, Vidvuds; Siegel, Don

    2011-02-14

    UOP LLC, a Honeywell Company, Ford Motor Company, and Striatus, Inc., collaborated with Professor Craig Jensen of the University of Hawaii and Professor Vidvuds Ozolins of University of California, Los Angeles on a multi-year cost-shared program to discover novel complex metal hydrides for hydrogen storage. This innovative program combined sophisticated molecular modeling with high throughput combinatorial experiments to maximize the probability of identifying commercially relevant, economical hydrogen storage materials with broad application. A set of tools was developed to pursue the medium throughput (MT) and high throughput (HT) combinatorial exploratory investigation of novel complex metal hydrides for hydrogen storage. The assay programs consisted of monitoring hydrogen evolution as a function of temperature. This project also incorporated theoretical methods to help select candidate materials families for testing. The Virtual High Throughput Screening served as a virtual laboratory, calculating structures and their properties. First Principles calculations were applied to various systems to examine hydrogen storage reaction pathways and the associated thermodynamics. The experimental program began with the validation of the MT assay tool with NaAlH4/0.02 mole Ti, the state of the art hydrogen storage system given by decomposition of sodium alanate to sodium hydride, aluminum metal, and hydrogen. Once certified, a combinatorial 21-point study of the NaAlH4 – LiAlH4 –Mg(AlH4)2 phase diagram was investigated with the MT assay. Stability proved to be a problem as many of the materials decomposed during synthesis, altering the expected assay results. This resulted in repeating the entire experiment with a mild milling approach, which only temporarily increased capacity. NaAlH4 was the best performer in both studies and no new mixed alanates were observed, a result consistent with the VHTS. Powder XRD suggested that the reverse reaction, the regeneration

  20. Titanium tritide radioisotope heat source development : palladium-coated titanium hydriding kinetics and tritium loading tests.

    SciTech Connect (OSTI)

    Van Blarigan, Peter; Shugard, Andrew D.; Walters, R. Tom

    2012-01-01

    We have found that a 180 nm palladium coating enables titanium to be loaded with hydrogen isotopes without the typical 400-500 C vacuum activation step. The hydriding kinetics of Pd coated Ti can be described by the Mintz-Bloch adherent film model, where the rate of hydrogen absorption is controlled by diffusion through an adherent metal-hydride layer. Hydriding rate constants of Pd coated and vacuum activated Ti were found to be very similar. In addition, deuterium/tritium loading experiments were done on stacks of Pd coated Ti foil in a representative-size radioisotope heat source vessel. The experiments demonstrated that such a vessel could be loaded completely, at temperatures below 300 C, in less than 10 hours, using existing department-of-energy tritium handling infrastructure.

  1. Method and composition in which metal hydride particles are embedded in a silica network

    DOE Patents [OSTI]

    Heung, Leung K.

    1999-01-01

    A silica embedded metal hydride composition and a method for making such a composition. The composition is made via the following process: A quantity of fumed silica is blended with water to make a paste. After adding metal hydride particles, the paste is dried to form a solid. According to one embodiment of the invention, the solid is ground into granules for use of the product in hydrogen storage. Alternatively, the paste can be molded into plates or cylinders and then dried for use of the product as a hydrogen filter. Where mechanical strength is required, the paste can be impregnated in a porous substrate or wire network.

  2. Method of production of pure hydrogen near room temperature from aluminum-based hydride materials

    DOE Patents [OSTI]

    Pecharsky, Vitalij K.; Balema, Viktor P.

    2004-08-10

    The present invention provides a cost-effective method of producing pure hydrogen gas from hydride-based solid materials. The hydride-based solid material is mechanically processed in the presence of a catalyst to obtain pure gaseous hydrogen. Unlike previous methods, hydrogen may be obtained from the solid material without heating, and without the addition of a solvent during processing. The described method of hydrogen production is useful for energy conversion and production technologies that consume pure gaseous hydrogen as a fuel.

  3. White Paper Summary of 2nd ASTM International Workshop on Hydrides in Zirconium Alloy Cladding

    SciTech Connect (OSTI)

    Sindelar, R.; Louthan, M.; PNNL, B.

    2015-05-29

    This white paper recommends that ASTM International develop standards to address the potential impact of hydrides on the long term performance of irradiated zirconium alloys. The need for such standards was apparent during the 2nd ASTM International Workshop on Hydrides in Zirconium Alloy Cladding and Assembly Components, sponsored by ASTM International Committee C26.13 and held on June 10-12, 2014, in Jackson, Wyoming. The potentially adverse impacts of hydrogen and hydrides on the long term performance of irradiated zirconium-alloy cladding on used fuel were shown to depend on multiple factors such as alloy chemistry and processing, irradiation and post irradiation history, residual and applied stresses and stress states, and the service environment. These factors determine the hydrogen content and hydride morphology in the alloy, which, in turn, influence the response of the alloy to the thermo-mechanical conditions imposed (and anticipated) during storage, transport and disposal of used nuclear fuel. Workshop presentations and discussions showed that although hydrogen/hydride induced degradation of zirconium alloys may be of concern, the potential for occurrence and the extent of anticipated degradation vary throughout the nuclear industry because of the variations in hydrogen content, hydride morphology, alloy chemistry and irradiation conditions. The tools and techniques used to characterize hydrides and hydride morphologies and their impacts on material performance also vary. Such variations make site-to-site comparisons of test results and observations difficult. There is no consensus that a single material or system characteristic (e.g., reactor type, burnup, hydrogen content, end-of life stress, alloy type, drying temperature, etc.) is an effective predictor of material response during long term storage or of performance after long term storage. Multi-variable correlations made for one alloy may not represent the behavior of another alloy exposed to

  4. Draft of M2 Report on Integration of the Hybrid Hydride Model into INL's MBM Framework for Review

    SciTech Connect (OSTI)

    Tikare, Veena; Weck, Philippe F.; Schultz, Peter A.; Clark, Blythe; Glazoff, Michael; Homer, Eric

    2014-07-01

    This report documents the development, demonstration and validation of a mesoscale, microstructural evolution model for simulation of zirconium hydride {delta}-ZrH{sub 1.5} precipitation in the cladding of used nuclear fuels that may occur during long-term dry storage. While the Zr-based claddings are manufactured free of any hydrogen, they absorb hydrogen during service, in the reactor by a process commonly termed ‘hydrogen pick-up’. The precipitation and growth of zirconium hydrides during dry storage is one of the most likely fuel rod integrity failure mechanisms either by embrittlement or delayed hydride cracking of the cladding. While the phenomenon is well documented and identified as a potential key failure mechanism during long-term dry storage (NUREG/CR-7116), the ability to actually predict the formation of hydrides is poor. The model being documented in this work is a computational capability for the prediction of hydride formation in different claddings of used nuclear fuels. This work supports the Used Fuel Disposition Research and Development Campaign in assessing the structural engineering performance of the cladding during and after long-term dry storage. This document demonstrates a basic hydride precipitation model that is built on a recently developed hybrid Potts-phase field model that combines elements of Potts-Monte Carlo and the phase-field models. The model capabilities are demonstrated along with the incorporation of the starting microstructure, thermodynamics of the Zr-H system and the hydride formation mechanism.

  5. Internal hydriding in irradiated defected Zircaloy fuel rods: A review (LWBR Development Program)

    SciTech Connect (OSTI)

    Clayton, J C

    1987-10-01

    Although not a problem in recent commercial power reactors, including the Shippingport Light Water Breeder Reactor, internal hydriding of Zircaloy cladding was a persistent cause of gross cladding failures during the 1960s. It occurred in the fuel rods of water-cooled nuclear power reactors that had a small cladding defect. This report summarizes the experimental findings, causes, mechanisms, and methods of minimizing internal hydriding in defected Zircaloy-clad fuel rods. Irradiation test data on the different types of defected fuel rods, intentionally fabricated defected and in-pile operationally defected rods, are compared. Significant factors affecting internal hydriding in defected Zircaloy-clad fuel rods (defect hole size, internal and external sources of hydrogen, Zircaloy cladding surface properties, nickel alloy contamination of Zircaloy, the effect of heat flux and fluence) are discussed. Pertinent in-pile and out-of-pile test results from Bettis and other laboratories are used as a data base in constructing a qualitative model which explains hydrogen generation and distribution in Zircaloy cladding of defected water-cooled reactor fuel rods. Techniques for minimizing internal hydride failures in Zircaloy-clad fuel rods are evaluated.

  6. First Principles Studies of Phase Stability and Reaction Dynamics in Complex Metal Hydrides

    SciTech Connect (OSTI)

    Chou, Mei-Yin

    2014-09-29

    Complex metal hydrides are believed to be one of the most promising materials for developing hydrogen storage systems that can operate under desirable conditions. At the same time, these are also a class of materials that exhibit intriguing properties. We have used state-of-the-art computational techniques to study the fundamental properties of these materials.

  7. Neutron diffraction studies of a four-coordinated hydride in near square-planar geometry

    SciTech Connect (OSTI)

    Liao, Jian -Hong; Dhayal, Rajendra Singh; Wang, Xiaoping; Kahlal, Samia; Saillard, Jean -Yves; Liu, C. W.

    2014-10-07

    The structure of a nanospheric polyhydrido copper cluster, [Cu20(H)11{S2P(OiPr)2}9], was determined by single-crystal neutron diffraction. Cu20 cluster consists of an elongated triangular orthobicupola constructed from 18 Cu atoms that encapsulate a [Cu2H5}3- ion in the center with an exceptionally short Cu-Cu distance. The eleven hydrides in the cluster display three different coordination modes to the Cu atoms: Six μ3-hydrides in pyramidal geometry, two μ4-hydrides in tetrahedral cavity, and three μ4-hydrides in an unprecedented near square-planar geometry. The neutron data set was collected on a small crystal of the size 0.20 mm x 0.50 mm x 0.65 mm for seven days using the Spallation Neutron Source TOPAZ single-crystal time-of-flight Laue diffractometer at the Oak Ridge National Laboratory. Furthermore, the final R-factor is 8.64% for 16014 reflections.

  8. Neutron diffraction studies of a four-coordinated hydride in near square-planar geometry

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Liao, Jian -Hong; Dhayal, Rajendra Singh; Wang, Xiaoping; Kahlal, Samia; Saillard, Jean -Yves; Liu, C. W.

    2014-10-07

    The structure of a nanospheric polyhydrido copper cluster, [Cu20(H)11{S2P(OiPr)2}9], was determined by single-crystal neutron diffraction. Cu20 cluster consists of an elongated triangular orthobicupola constructed from 18 Cu atoms that encapsulate a [Cu2H5}3- ion in the center with an exceptionally short Cu-Cu distance. The eleven hydrides in the cluster display three different coordination modes to the Cu atoms: Six μ3-hydrides in pyramidal geometry, two μ4-hydrides in tetrahedral cavity, and three μ4-hydrides in an unprecedented near square-planar geometry. The neutron data set was collected on a small crystal of the size 0.20 mm x 0.50 mm x 0.65 mm for seven daysmore » using the Spallation Neutron Source TOPAZ single-crystal time-of-flight Laue diffractometer at the Oak Ridge National Laboratory. Furthermore, the final R-factor is 8.64% for 16014 reflections.« less

  9. Model for the Prediction of the Hydriding Thermodynamics of Pd-Rh-Co Ternary Alloys

    SciTech Connect (OSTI)

    Teter, D.F.; Thoma, D.J.

    1999-03-01

    A dilute solution model (with respect to the substitutional alloying elements) has been developed, which accurately predicts the hydride formation and decomposition thermodynamics and the storage capacities of dilute ternary Pd-Rh-Co alloys. The effect of varying the rhodium and cobalt compositions on the thermodynamics of hydride formation and decomposition and hydrogen capacity of several palladium-rhodium-cobalt ternary alloys has been investigated using pressure-composition (PC) isotherms. Alloying in the dilute regime (<10 at.%) causes the enthalpy for hydride formation to linearly decrease with increasing alloying content. Cobalt has a stronger effect on the reduction in enthalpy than rhodium for equivalent alloying amounts. Also, cobalt reduces the hydrogen storage capacity with increasing alloying content. The plateau thermodynamics are strongly linked to the lattice parameters of the alloys. A near-linear dependence of the enthalpy of hydride formation on the lattice parameter was observed for both the binary Pd-Rh and Pd-Co alloys, as well as for the ternary Pd-Rh-Co alloys. The Pd-5Rh-3Co (at. %) alloy was found to have similar plateau thermodynamics as a Pd-10Rh alloy, however, this ternary alloy had a diminished hydrogen storage capacity relative to Pd-10Rh.

  10. Stabilization of Nickel Metal Catalysts for Aqueous Processing...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    over a range of temperatures from 200C to 450C. However, these catalysts lose activity over time and must be replenished with new supports to continue facilitating the...

  11. Effect of Gaseous Impurities on Long-Term Thermal Cycling and Aging Properties of Complex Hydrides for Hydrogen Storage

    SciTech Connect (OSTI)

    Chandra, Dhanesh; Lamb, Joshua; Chien, Wen-Ming; Talekar, Anjali; and Pal, Narendra.

    2011-03-28

    This program was dedicated to understanding the effect of impurities on Long-Term Thermal Cycling and aging properties of Complex Hydrides for Hydrogen Storage. At the start of the program we found reversibility between Li2NH+LiH  LiH+LiNH2 (yielding ~5.8 wt.%H capacity). Then we tested the effect of impurity in H2 gas by pressure cycling at 255oC; first with industrial gas containing ppm levels of O2 and H2O as major impurities. Both these impurities had a significant impact on the reversibility and decreased the capacity by 2.65 wt.%H. Further increase in number of cycles from 500 to 1100 showed only a 0.2 wt%H more weight loss, showing some capacity is still maintained after a significant number of cycles. The loss of capacity is attributed to the formation of ~55 wt% LiH and ~30% Li2O, as major contaminant phases, along with the hydride Li2NH phase; suggesting loss of nitrogen during cycling. The effect of 100 ppm H2O in H2 also showed a decrease of ~2.5 wt.%H (after 560 cycles), and 100ppm O2 in H2; a loss of ~4.1 wt.%. Methane impurity (100 ppm, 100cycles), showed a very small capacity loss of 0.9 wt.%H under similar conditions. However, when Li3N was pressure cycled with 100ppmN2-H2 there were beneficial effects were observed (255oC); the reversible capacity increased to 8.4wt.%H after 853 cycles. Furthermore, with 20 mol.%N2-H2 capacity increased to ~10 wt.%H after 516 cycles. We attribute this enhancement to the reaction of nitrogen with liquid lithium during cycling as the Gibbs free energy of formation of Li3N (Go = -98.7 kJ/mol) is more negative than that of LiH (Go = -50.3 kJ/mol). We propose that the mitigation of hydrogen capacity losses is due to the destabilization of the LiH phase that tends to accumulate during cycling. Also more Li2NH phase was found in the cycled product. Mixed Alanates (3LiNH2:Li3AlH6) showed that 7 wt% hydrogen desorbed under dynamic vacuum. Equilibrium experiments (maximum 12 bar H2) showed up to 4wt% hydrogen

  12. Model for Simulation of Hydride Precipitation in Zr-Based Used Fuel Claddings: A Status Report on Current Model Capabilities

    Broader source: Energy.gov [DOE]

    The report demonstrates a meso-scale, microstructural evolution model for simulation of zirconium hydride precipitation in the cladding of used fuels during long-term dry-storage.

  13. Effect of delivery condition on desorption rate of ZrCo metal hydride bed for fusion fuel cycle

    SciTech Connect (OSTI)

    Kang, H.G.; Yun, S.H.; Chung, D.; Oh, Y.H.; Chang, M.H.; Cho, S.; Chung, H.; Song, K.M.

    2015-03-15

    For the safety of fusion fuel cycle, hydrogen isotope gases including tritium are stored as metal hydride form. To satisfy fueling requirement of fusion machine, rapid delivery from metal hydride bed is one of major factors for the development of tritium storage and delivery system. Desorption from metal hydride depends on the operation scenario by pressure and temperature control of the bed. The effect of operation scenario and pump performance on desorption rate of metal hydride bed was experimentally investigated using ZrCo bed. The results showed that the condition of pre-heating scenario before actual delivery of gas affected the delivery performance. Different pumps were connected to desorption line from bed and the effect of pump capacity on desorption rate were also found to be significant. (authors)

  14. Fast, quantitative, and nondestructive evaluation of hydrided LWR fuel cladding by small angle incoherent neutron scattering of hydrogen

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yan, Y.; Qian, S.; Littrell, K.; Parish, C. M.; Plummer, L. K.

    2015-02-13

    A non-destructive neutron scattering method to precisely measure the uptake of hydrogen and the distribution of hydride precipitates in light water reactor (LWR) fuel cladding was developed. Zircaloy-4 cladding used in commercial LWRs was used to produce hydrided specimens. The hydriding apparatus consists of a closed stainless steel vessel that contains Zr alloy specimens and hydrogen gas. Following hydrogen charging, the hydrogen content of the hydrided specimens was measured using the vacuum hot extraction method, by which the samples with desired hydrogen concentration were selected for the neutron study. Optical microscopy shows that our hydriding procedure results in uniform distributionmore » of circumferential hydrides across the wall. Small angle neutron incoherent scattering was performed in the High Flux Isotope Reactor at Oak Ridge National Laboratory. This study demonstrates that the hydrogen in commercial Zircaloy-4 cladding can be measured very accurately in minutes by this nondestructive method over a wide range of hydrogen concentrations from a very small amount ( 20 ppm) to over 1000 ppm. The hydrogen distribution in a tube sample was obtained by scaling the neutron scattering rate with a factor determined by a calibration process using standard, destructive direct chemical analysis methods on the specimens. This scale factor will be used in future tests with unknown hydrogen concentrations, thus providing a nondestructive method for absolute hydrogen concentration determination.« less

  15. Fast, quantitative, and nondestructive evaluation of hydrided LWR fuel cladding by small angle incoherent neutron scattering of hydrogen

    SciTech Connect (OSTI)

    Yan, Y.; Qian, S.; Littrell, K.; Parish, C. M.; Plummer, L. K.

    2015-02-13

    A non-destructive neutron scattering method to precisely measure the uptake of hydrogen and the distribution of hydride precipitates in light water reactor (LWR) fuel cladding was developed. Zircaloy-4 cladding used in commercial LWRs was used to produce hydrided specimens. The hydriding apparatus consists of a closed stainless steel vessel that contains Zr alloy specimens and hydrogen gas. Following hydrogen charging, the hydrogen content of the hydrided specimens was measured using the vacuum hot extraction method, by which the samples with desired hydrogen concentration were selected for the neutron study. Optical microscopy shows that our hydriding procedure results in uniform distribution of circumferential hydrides across the wall. Small angle neutron incoherent scattering was performed in the High Flux Isotope Reactor at Oak Ridge National Laboratory. This study demonstrates that the hydrogen in commercial Zircaloy-4 cladding can be measured very accurately in minutes by this nondestructive method over a wide range of hydrogen concentrations from a very small amount ( 20 ppm) to over 1000 ppm. The hydrogen distribution in a tube sample was obtained by scaling the neutron scattering rate with a factor determined by a calibration process using standard, destructive direct chemical analysis methods on the specimens. This scale factor will be used in future tests with unknown hydrogen concentrations, thus providing a nondestructive method for absolute hydrogen concentration determination.

  16. Fast, Quantitative, and Nondestructive Evaluation on Hydrided LWR Fuel Cladding by Small Angle Incoherent Neutron Scattering of Hydrogen

    SciTech Connect (OSTI)

    Yan, Yong; Qian, Shuo; Littrell, Ken; Parish, Chad M; Plummer, Lee K

    2015-01-01

    A non-destructive neutron scattering method to precisely measure the uptake of hydrogen and the distribution of hydride precipitates in light water reactor (LWR) fuel cladding was developed. Zircaloy-4 cladding used in commercial LWRs was used to produce hydrided specimens. The hydriding apparatus consists of a closed stainless steel vessel that contains Zr alloy specimens and hydrogen gas. Following hydrogen charging, the hydrogen content of the hydrided specimens was measured using the vacuum hot extraction method, by which the samples with desired hydrogen concentration were selected for the neutron study. Optical microscopy shows that our hydriding procedure results in uniform distribution of circumferential hydrides across the wall. Small angle neutron incoherent scattering was performed in the High Flux Isotope Reactor at Oak Ridge National Laboratory. Our study demonstrates that the hydrogen in commercial Zircaloy-4 cladding can be measured very accurately in minutes by this nondestructive method over a wide range of hydrogen concentrations from a very small amount ( 20 ppm) to over 1000 ppm. The hydrogen distribution in a tube sample was obtained by scaling the neutron scattering rate with a factor determined by a calibration process using standard, destructive direct chemical analysis methods on the specimens. This scale factor can be used in future tests with unknown hydrogen concentrations, thus providing a nondestructive method for absolute hydrogen concentration determination.

  17. The influence of surface morphology and oxide microstructure on the nucleation and growth of uranium hydride on alpha uranium

    SciTech Connect (OSTI)

    Hanrahan, R.J. Jr.; Hawley, M.E.; Brown, G.W.

    1998-12-31

    While the bulk kinetics of the uranium-hydrogen reaction are well understood, the mechanisms underlying the initial nucleation of uranium hydride on uranium remain controversial. In this study, the authors have employed environmental cell optical microscopy, Scanning Electron Microscopy (SEM) and Atomic Force Microscopy, (AFM) in an attempt to relate the structure of the surface and the microstructure of the substrate with the susceptibility and site of hydride nucleation. Samples have been investigated with varying grain size, inclusion (carbide) concentration, and thermal history. There is a clear correlation to heat treatment immediately prior to hydrogen exposure. Susceptibility to hydride formation also appears to be related to impurities in the uranium. The oxidized surface is very complex, exhibiting wide variations in thickness and topography between samples, between grains in the same sample, and within individual grains. It is, however, very difficult to relate this fine scale variability to the relatively sparse hydride initiation sites. Therefore, the surface oxide layer itself does not appear to control the sites where hydride attack is initiated, although it must play a role in the induction period prior to hydride initiation.

  18. First principles screening of destabilized metal hydrides for high capacity H2 storage using scandium (presentation had varying title: Accelerating Development of Destabilized Metal Hydrides for Hydrogen Storage Using First Principles Calculations)

    SciTech Connect (OSTI)

    Alapati, S.; Johnson, J.K.; Sholl, D.S.; Dai, B. --last author not shown on publication, only presentation

    2007-10-31

    Favorable thermodynamics are a prerequisite for practical H2 storage materials for vehicular applications. Destabilization of metal hydrides is a versatile route to finding materials that reversibly store large quantities of H2. First principles calculations have proven to be a useful tool for screening large numbers of potential destabilization reactions when tabulated thermodynamic data are unavailable. We have used first principles calculations to screen potential destabilization schemes that involve Sc-containing compounds. Our calculations use a two-stage strategy in which reactions are initially assessed based on their reaction enthalpy alone, followed by more detailed free energy calculations for promising reactions. Our calculations indicate that mixtures of ScH2 + 2LiBH4, which will release 8.9 wt.% H2 at completion and will have an equilibrium pressure of 1 bar at around 330 K, making this compound a promising target for experimental study. Along with thermodynamics, favorable kinetics are also of enormous importance for practical usage of these materials. Experiments would help identify possible kinetic barriers and modify them by developing suitable catalysts.

  19. High Resolution Neutron Radiography and Tomography of Hydrided Zircaloy-4 Cladding Materials

    SciTech Connect (OSTI)

    Smith, Tyler S; Bilheux, Hassina Z; Ray, Holly B; Bilheux, Jean-Christophe; Yan, Yong

    2015-01-01

    Neutron radiography for hydrogen analysis was performed with several Zircaloy-4 cladding samples with controlled hydrogen concentrations up to 1100 ppm. Hydrogen charging was performed in a process tube that was heated to facilitate hydrogen absorption by the metal. A correlation between the hydrogen concentration in the hydrided tubes and the neutron intensity was established, by which hydrogen content can be determined precisely in a small area (55 m x 55 m). Radiography analysis was also performed to evaluate the heating rate and its correlation with the hydrogen distribution through hydrided materials. In addition to radiography analysis, tomography experiments were performed on Zircaloy-4 tube samples to study the local hydrogen distribution. Through tomography analysis a 3D reconstruction of the tube was evaluated in which an uneven hydrogen distribution in the circumferential direction can be observed.

  20. In-bed measurement of tritium loading in process metal hydride beds

    SciTech Connect (OSTI)

    Nobile, A.

    1988-01-01

    The Replacement Tritium Facility at Savannah River Plant will make extensive use of metal hydride technology for the storage, pumping, isotopic separation, and compression of hydrogen isotopes. Two options were considered for routine accountability of tritium stored in metal hydride beds. One option was to use standard P-V-T-mass spectrometry techniques after desorption of storage beds to tanks of known volume. The second option was to develop a technique for direct measurement of bed loading. It was thought that such a technique would be more rapid and would account for heel, although some accuracy would be lost.The static nitrogen and flowing nitrogen methods were considered for this option. The flowing nitrogen method was eventually selected because it was insensitive to bed physical properties and isotopic gas composition, as well as being more accurate and easier to automate.

  1. Method to predict relative hydriding within a group of zirconium alloys under nuclear irradiation

    DOE Patents [OSTI]

    Johnson, A.B. Jr.; Levy, I.S.; Trimble, D.J.; Lanning, D.D.; Gerber, F.S.

    1990-04-10

    An out-of-reactor method for screening to predict relative in-reactor hydriding behavior of zirconium-based materials is disclosed. Samples of zirconium-based materials having different compositions and/or fabrication methods are autoclaved in a relatively concentrated (0.3 to 1.0M) aqueous lithium hydroxide solution at constant temperatures within the water reactor coolant temperature range (280 to 316 C). Samples tested by this out-of-reactor procedure, when compared on the basis of the ratio of hydrogen weight gain to oxide weight gain, accurately predict the relative rate of hydriding for the same materials when subject to in-reactor (irradiated) corrosion. 1 figure.

  2. In-bed accountability of tritium in production scale metal hydride storage beds

    SciTech Connect (OSTI)

    Klein, J.E.

    1995-10-01

    An `in-bed accountability` (IBA) flowing gas calorimetric measurement method has been developed and implemented to eliminate the need to remove tritium from production scale metal hydride storage beds for inventory measurement purposes. Six-point tritium IBA calibration curves have been completed for two, 390 gram tritium metal hydride storage beds. The calibration curves for the two tritium beds are similar to those obtained from the `cold` test program. Tritium inventory errors at the 95 percent confidence level ranged from {+-} 7.3 to 8.6 grams for the cold test results compared to {+-} 4.2 to 7.5 grams obtained for the two tritium calibrated beds. 5 refs., 4 figs., 1 tab.

  3. Synthesis, NMR spectra, and structure of rhodium hydride complexes with Rh-Sn bonds

    SciTech Connect (OSTI)

    Krut'ko, B.P.; Permin, A.B.; Petrosyan, V.S.; Reutov, O.A.

    1985-06-20

    The authors study the hydride complexes using Sn 119 and H 1 NMR spectroscopy. The spectra were taken in a pulse mode on a Varian FT-80A spectrometer equipped with a wideband system at 29.66 and 79.54 MHz. The Sn 119 and H 1 NMR spectral parameters for a solution of the complex (Bu/sub 4/N)/sub 3/ (HRh(SnCl/sub 3/)/sub 5/) in CD/sub 3/CN are shown, the spectra show that the (HRh(SnCl/sub 3/)/sub 5/)/sup 3 -/ anion has octahedral structure with four equatorial and one axial Rh-Sn bonds. New rhodium hydride complexes with general formula (R/sub 4/N)/sub 3/(HRh(SnCl/sub 3/)/sub 5/) were synthesized.

  4. In-Bed Accountability Development for a Passively Cooled, Electrically Heated Hydride (PACE) Bed

    SciTech Connect (OSTI)

    Klein, J.E.

    2005-07-15

    A nominal 1500 STP-L PAssively Cooled, Electrically heated hydride (PACE) Bed has been developed for implementation into a new Savannah River Site tritium project. The 1.2 meter (four-foot) long process vessel contains on internal 'U-tube' for tritium In-Bed Accountability (IBA) measurements. IBA will be performed on six, 12.6 kg production metal hydride storage beds.IBA tests were done on a prototype bed using electric heaters to simulate the radiolytic decay of tritium. Tests had gas flows from 10 to 100 SLPM through the U-tube or 100 SLPM through the bed's vacuum jacket. IBA inventory measurement errors at the 95% confidence level were calculated using the correlation of IBA gas temperature rise, or (hydride) bed temperature rise above ambient temperature, versus simulated tritium inventory.Prototype bed IBA inventory errors at 100 SLPM were the largest for gas flows through the vacuum jacket: 15.2 grams for the bed temperature rise and 11.5 grams for the gas temperature rise. For a 100 SLPM U-tube flow, the inventory error was 2.5 grams using bed temperature rise and 1.6 grams using gas temperature rise. For 50 to 100 SLPM U-tube flows, the IBA gas temperature rise inventory errors were nominally one to two grams that increased above four grams for flows less than 50 SLPM. For 50 to 100 SLPM U-tube flows, the IBA bed temperature rise inventory errors were greater than the gas temperature rise errors, but similar errors were found for both methods at gas flows of 20, 30, and 40 SLPM.Electric heater IBA tests were done for six production hydride beds using a 45 SLPM U-tube gas flow. Of the duplicate runs performed on these beds, five of the six beds produced IBA inventory errors of approximately three grams: consistent with results obtained in the laboratory prototype tests.

  5. In-Bed Accountability Development for a Passively Cooled, Electrically Heated Hydride (PACE) Bed

    SciTech Connect (OSTI)

    KLEIN, JAMES

    2004-10-12

    A nominal 1500 STP-L PAssively Cooled, Electrically heated hydride (PACE) Bed has been developed for implementation into a new Savannah River Site tritium project. The 1.2 meter (four-foot) long process vessel contains an internal ''U-tube'' for tritium In-Bed Accountability (IBA) measurements. IBA will be performed on six, 12.6 kg production metal hydride storage beds. IBA tests were done on a prototype bed using electric heaters to simulate the radiolytic decay of tritium. Tests had gas flows from 10 to 100 SLPM through the U-tube or 100 SLPM through the bed's vacuum jacket. IBA inventory measurement errors at the 95 percent confidence level were calculated using the correlation of IBA gas temperature rise, or (hydride) bed temperature rise above ambient temperature, versus simulated tritium inventory. Prototype bed IBA inventory errors at 100 SLPM were the largest for gas flows through the vacuum jacket: 15.2 grams for the bed temperature rise and 11.5 grams for the gas temperature rise. For a 100 SLPM U-tube flow, the inventory error was 2.5 grams using bed temperature rise and 1.6 grams using gas temperature rise. For 50 to 100 SLPM U-tube flows, the IBA gas temperature rise inventory errors were nominally one to two grams that increased above four grams for flows less than 50 SLPM. For 50 to 100 SLPM U-tube flows, the IBA bed temperature rise inventory errors were greater than the gas temperature rise errors, but similar errors were found for both methods at gas flows of 20, 30, and 40 SLPM. Electric heater IBA tests were done for six production hydride beds using a 45 SLPM U-tube gas flow. Of the duplicate runs performed on these beds, five of the six beds produced IBA inventory errors of approximately three grams: consistent with results obtained in the laboratory prototype tests.

  6. Complex Hydrides-A New Frontier for Future Energy Applications | The Ames

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Laboratory Hydrides-A New Frontier for Future Energy Applications Research Personnel Updates Publications One-Step No-Bake Hydrogen Storage Material Read More Shaken Not Stirred - A Superconducting Material Also Shows Promise for Hydrogen Storage Read More Previous Pause Next Synthesis Every energy-related application of hydrogen (H2) requires safe and efficient storage. H2 can be stored as a compressed gas, a cryogenic liquid, or in an H-rich solid. The first two approaches require

  7. OPTIMIZATION OF INTERNAL HEAT EXCHANGERS FOR HYDROGEN STORAGE TANKS UTILIZING METAL HYDRIDES

    SciTech Connect (OSTI)

    Garrison, S.; Tamburello, D.; Hardy, B.; Anton, D.; Gorbounov, M.; Cognale, C.; van Hassel, B.; Mosher, D.

    2011-07-14

    Two detailed, unit-cell models, a transverse fin design and a longitudinal fin design, of a combined hydride bed and heat exchanger are developed in COMSOL{reg_sign} Multiphysics incorporating and accounting for heat transfer and reaction kinetic limitations. MatLab{reg_sign} scripts for autonomous model generation are developed and incorporated into (1) a grid-based and (2) a systematic optimization routine based on the Nelder-Mead downhill simplex method to determine the geometrical parameters that lead to the optimal structure for each fin design that maximizes the hydrogen stored within the hydride. The optimal designs for both the transverse and longitudinal fin designs point toward closely-spaced, small cooling fluid tubes. Under the hydrogen feed conditions studied (50 bar), a 25 times improvement or better in the hydrogen storage kinetics will be required to simultaneously meet the Department of Energy technical targets for gravimetric capacity and fill time. These models and methodology can be rapidly applied to other hydrogen storage materials, such as other metal hydrides or to cryoadsorbents, in future work.

  8. Mechanical properties of zirconium alloys and zirconium hydrides predicted from density functional perturbation theory

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Weck, Philippe F.; Kim, Eunja; Tikare, Veena; Mitchell, John A.

    2015-10-13

    Here, the elastic properties and mechanical stability of zirconium alloys and zirconium hydrides have been investigated within the framework of density functional perturbation theory. Results show that the lowest-energy cubic Pn-3m with combining macron]m polymorph of δ-ZrH1.5 does not satisfy all the Born requirements for mechanical stability, unlike its nearly degenerate tetragonal P42/mcm polymorph. Elastic moduli predicted with the Voigt–Reuss–Hill approximations suggest that mechanical stability of α-Zr, Zr-alloy and Zr-hydride polycrystalline aggregates is limited by the shear modulus. According to both Pugh's and Poisson's ratios, α-Zr, Zr-alloy and Zr-hydride polycrystalline aggregates can be considered ductile. The Debye temperatures predicted formore » γ-ZrH, δ-ZrH1.5 and ε-ZrH2 are θD = 299.7, 415.6 and 356.9 K, respectively, while θD = 273.6, 284.2, 264.1 and 257.1 K for the α-Zr, Zry-4, ZIRLO and M5 matrices, i.e. suggesting that Zry-4 possesses the highest micro-hardness among Zr matrices.« less

  9. Empirical and physics based mathematical models of uranium hydride decomposition kinetics with quantified uncertainties.

    SciTech Connect (OSTI)

    Salloum, Maher N.; Gharagozloo, Patricia E.

    2013-10-01

    Metal particle beds have recently become a major technique for hydrogen storage. In order to extract hydrogen from such beds, it is crucial to understand the decomposition kinetics of the metal hydride. We are interested in obtaining a a better understanding of the uranium hydride (UH3) decomposition kinetics. We first developed an empirical model by fitting data compiled from different experimental studies in the literature and quantified the uncertainty resulting from the scattered data. We found that the decomposition time range predicted by the obtained kinetics was in a good agreement with published experimental results. Secondly, we developed a physics based mathematical model to simulate the rate of hydrogen diffusion in a hydride particle during the decomposition. We used this model to simulate the decomposition of the particles for temperatures ranging from 300K to 1000K while propagating parametric uncertainty and evaluated the kinetics from the results. We compared the kinetics parameters derived from the empirical and physics based models and found that the uncertainty in the kinetics predicted by the physics based model covers the scattered experimental data. Finally, we used the physics-based kinetics parameters to simulate the effects of boundary resistances and powder morphological changes during decomposition in a continuum level model. We found that the species change within the bed occurring during the decomposition accelerates the hydrogen flow by increasing the bed permeability, while the pressure buildup and the thermal barrier forming at the wall significantly impede the hydrogen extraction.

  10. Metal hydride/chemical heat-pump development project. Phase I. Final report

    SciTech Connect (OSTI)

    Argabright, T.A.

    1982-02-01

    The metal hydride/chemical heat pump (MHHP) is a chemical heat pump containing two hydrides for the storage and/or recovery of thermal energy. It utilizes the heat of reaction of hydrogen with specific metal alloys. The MHHP design can be tailored to provide heating and/or cooling or temperature upgrading over a wide range of input and ambient temperatures. The system can thus be used with a variety of heat sources including waste heat, solar energy or a fossil fuel. The conceptual design of the MHHP was developed. A national market survey including a study of applications and market sectors was conducted. The technical tasks including conceptual development, thermal and mechanical design, laboratory verification of design and material performance, cost analysis and the detailed design of the Engineering Development Test Unit (EDTU) were performed. As a result of the market study, the temperature upgrade cycle of the MHHP was chosen for development. Operating temperature ranges for the upgrader were selected to be from 70 to 110/sup 0/C (160 to 230/sup 0/F) for the source heat and 140 to 190/sup 0/C (280 to 375/sup 0/F) for the product heat. These ranges are applicable to many processes in industries such as food, textile, paper and pulp, and chemical. The hydride pair well suited for these temperatures is LaNi/sub 5//LaNi/sub 4/ /sub 5/Al/sub 0/ /sub 5/. The EDTU was designed for the upgrade cycle. It is a compact finned tube arrangement enclosed in a pressure vessel. This design incorporates high heat transfer and low thermal mass in a system which maximizes the coefficient of performance (COP). It will be constructed in Phase II. Continuation of this effort is recommended.

  11. Mechanistic study of the isotopic-exchange reaction between gaseous hydrogen and palladium hydride powder

    SciTech Connect (OSTI)

    Outka, D.A.; Foltz, G.W. (Sandia National Labs., Livermore, CA (USA))

    1991-07-01

    A detailed mechanism for the isotopic-exchange reaction between gaseous hydrogen and solid palladium hydride is developed which extends previous model for this reaction by specifically including surface reactions. The modeling indicates that there are two surface-related processes that contribute to the overall rate of exchange: the desorption of hydrogen from the surface and the exchange between surface hydrogen and bulk hydrogen. This conclusion is based upon measurements examining the effect of small concentrations of carbon monoxide were helpful in elucidating the mechanism. Carbon monoxide reversibly inhibits certain steps in the exchange; this slows the overall rate of exchange and changes the distribution of products from the reactor.

  12. Method and apparatus for storing hydrogen isotopes. [stored as uranium hydride in a block of copper

    DOE Patents [OSTI]

    McMullen, J.W.; Wheeler, M.G.; Cullingford, H.S.; Sherman, R.H.

    1982-08-10

    An improved method and apparatus for storing isotopes of hydrogen (especially tritium) are provided. The hydrogen gas is stored as hydrides of material (for example uranium) within boreholes in a block of copper. The mass of the block is critically important to the operation, as is the selection of copper, because no cooling pipes are used. Because no cooling pipes are used, there can be no failure due to cooling pipes. And because copper is used instead of stainless steel, a significantly higher temperature can be reached before the eutectic formation of uranium with copper occurs, (the eutectic of uranium with the iron in stainless steel forms at a significantly lower temperature).

  13. Metal hydrides as electrode/catalyst materials for oxygen evolution/reduction in electrochemical devices

    DOE Patents [OSTI]

    Bugga, Ratnakumar V.; Halpert, Gerald; Fultz, Brent; Witham, Charles K.; Bowman, Robert C.; Hightower, Adrian

    1997-01-01

    An at least ternary metal alloy of the formula, AB.sub.(5-Y)X(.sub.y), is claimed. In this formula, A is selected from the rare earth elements, B is selected from the elements of groups 8, 9, and 10 of the periodic table of the elements, and X includes at least one of the following: antimony, arsenic, and bismuth. Ternary or higher-order substitutions, to the base AB.sub.5 alloys, that form strong kinetic interactions with the predominant metals in the base metal hydride are used to form metal alloys with high structural integrity after multiple cycles of hydrogen sorption.

  14. Modeling and Simulation of Used Nuclear Fuel During Transportation with Consideration of Hydride Effects and Cyclic Fatigue

    SciTech Connect (OSTI)

    Chakraborty, Pritam; Sabharwall, Piyush; Spears, Robert Edward; Coleman, Justin Leigh; Sener, Kadir; Varma, Amit H.

    2015-09-30

    The objective of this work is to understand the integrity of Used Nuclear Fuel (UNF) during transportation. Previous analysis work has been performed to look at the integrity of UNF during transportation but these analyses have neglected to analyze the effect of hydrides and flaws (fracture mechanics models to capture radial cracking in the cladding). In this study, the clad regions of interest are near the pellet-pellet interfaces. These regions can experience more complex stress-states than the rest of the clad during cooling and have a greater possibility to develop radially reoriented hydrides during vacuum drying.

  15. Number | Open Energy Information

    Open Energy Info (EERE)

    Property:NumOfPlants Property:NumProdWells Property:NumRepWells Property:Number of Color Cameras Property:Number of Devices Deployed Property:Number of Plants included in...

  16. Rapid hydrogen gas generation using reactive thermal decomposition of uranium hydride.

    SciTech Connect (OSTI)

    Kanouff, Michael P.; Van Blarigan, Peter; Robinson, David B.; Shugard, Andrew D.; Gharagozloo, Patricia E.; Buffleben, George M.; James, Scott Carlton; Mills, Bernice E.

    2011-09-01

    Oxygen gas injection has been studied as one method for rapidly generating hydrogen gas from a uranium hydride storage system. Small scale reactors, 2.9 g UH{sub 3}, were used to study the process experimentally. Complimentary numerical simulations were used to better characterize and understand the strongly coupled chemical and thermal transport processes controlling hydrogen gas liberation. The results indicate that UH{sub 3} and O{sub 2} are sufficiently reactive to enable a well designed system to release gram quantities of hydrogen in {approx} 2 seconds over a broad temperature range. The major system-design challenge appears to be heat management. In addition to the oxidation tests, H/D isotope exchange experiments were performed. The rate limiting step in the overall gas-to-particle exchange process was found to be hydrogen diffusion in the {approx}0.5 {mu}m hydride particles. The experiments generated a set of high quality experimental data; from which effective intra-particle diffusion coefficients can be inferred.

  17. Heat exchanger selection and design analyses for metal hydride heat pump systems

    SciTech Connect (OSTI)

    Mazzucco, Andrea; Voskuilen, Tyler G.; Waters, Essene L.; Pourpoint, Timothee L.; Rokni, Masoud

    2016-01-01

    This paper presents a design analysis for the development of highly efficient heat exchangers within stationary metal hydride heat pumps. The design constraints and selected performance criteria are applied to three representative heat exchangers. The proposed thermal model can be applied to select the most efficient heat exchanger design and provides outcomes generally valid in a pre-design stage. Heat transfer effectiveness is the principal performance parameter guiding the selection analysis, the results of which appear to be mildly (up to 13%) affected by the specific Nusselt correlation used. The thermo-physical properties of the heat transfer medium and geometrical parameters are varied in the sensitivity analysis, suggesting that the length of independent tubes is the physical parameter that influences the performance of the heat exchangers the most. The practical operative regions for each heat exchanger are identified by finding the conditions over which the heat removal from the solid bed enables a complete and continuous hydriding reaction. The most efficient solution is a design example that achieves the target effectiveness of 95%.

  18. ENVIRONMENTAL REACTIVITY OF SOLID STATE HYDRIDE MATERIALS: MODELING AND TESTING FOR AIR AND WATER EXPOSURE

    SciTech Connect (OSTI)

    Anton, D.; James, C.; Cortes-Concepcion, J.; Tamburello, D.; Brinkman, K.; Gray, J.

    2010-05-18

    To make commercially acceptable condensed phase hydrogen storage systems, it is important to understand quantitatively the risks involved in using these materials. A rigorous set of environmental reactivity tests have been developed based on modified testing procedures codified by the United Nations for the transportation of dangerous goods. Potential hydrogen storage material, 2LiBH4{center_dot}MgH2 and NH3BH3, have been tested using these modified procedures to evaluate the relative risks of these materials coming in contact with the environment in hypothetical accident scenarios. It is apparent that an ignition event will only occur if both a flammable concentration of hydrogen and sufficient thermal energy were available to ignite the hydrogen gas mixture. In order to predict hydride behavior for hypothesized accident scenarios, an idealized finite element model was developed for dispersed hydride from a breached system. Empirical thermodynamic calculations based on precise calorimetric experiments were performed in order to quantify the energy and hydrogen release rates and to quantify the reaction products resulting from water and air exposure. Both thermal and compositional predictions were made with identification of potential ignition event scenarios.

  19. First-Principles Modeling of Hydrogen Storage in Metal Hydride Systems

    SciTech Connect (OSTI)

    J. Karl Johnson

    2011-05-20

    The objective of this project is to complement experimental efforts of MHoCE partners by using state-of-the-art theory and modeling to study the structure, thermodynamics, and kinetics of hydrogen storage materials. Specific goals include prediction of the heats of formation and other thermodynamic properties of alloys from first principles methods, identification of new alloys that can be tested experimentally, calculation of surface and energetic properties of nanoparticles, and calculation of kinetics involved with hydrogenation and dehydrogenation processes. Discovery of new metal hydrides with enhanced properties compared with existing materials is a critical need for the Metal Hydride Center of Excellence. New materials discovery can be aided by the use of first principles (ab initio) computational modeling in two ways: (1) The properties, including mechanisms, of existing materials can be better elucidated through a combined modeling/experimental approach. (2) The thermodynamic properties of novel materials that have not been made can, in many cases, be quickly screened with ab initio methods. We have used state-of-the-art computational techniques to explore millions of possible reaction conditions consisting of different element spaces, compositions, and temperatures. We have identified potentially promising single- and multi-step reactions that can be explored experimentally.

  20. THERMAL ENHANCEMENT CARTRIDGE HEATER MODIFIED TECH MOD TRITIUM HYDRIDE BED DEVELOPMENT PART I DESIGN AND FABRICATION

    SciTech Connect (OSTI)

    Klein, J.; Estochen, E.

    2014-03-06

    The Savannah River Site (SRS) tritium facilities have used 1{sup st} generation (Gen1) LaNi{sub 4.25}Al{sub 0.75} (LANA0.75) metal hydride storage beds for tritium absorption, storage, and desorption. The Gen1 design utilizes hot and cold nitrogen supplies to thermally cycle these beds. Second and 3{sup rd} generation (Gen2 and Gen3) storage bed designs include heat conducting foam and divider plates to spatially fix the hydride within the bed. For thermal cycling, the Gen2 and Gen 3 beds utilize internal electric heaters and glovebox atmosphere flow over the bed inside the bed external jacket for cooling. The currently installed Gen1 beds require replacement due to tritium aging effects on the LANA0.75 material, and cannot be replaced with Gen2 or Gen3 beds due to different designs of these beds. At the end of service life, Gen1 bed desorption efficiencies are limited by the upper temperature of hot nitrogen supply. To increase end-of-life desorption efficiency, the Gen1 bed design was modified, and a Thermal Enhancement Cartridge Heater Modified (TECH Mod) bed was developed. Internal electric cartridge heaters in the new design to improve end-of-life desorption, and also permit in-bed tritium accountability (IBA) calibration measurements to be made without the use of process tritium. Additional enhancements implemented into the TECH Mod design are also discussed.

  1. Heat exchanger selection and design analyses for metal hydride heat pump systems

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Mazzucco, Andrea; Voskuilen, Tyler G.; Waters, Essene L.; Pourpoint, Timothee L.; Rokni, Masoud

    2016-01-01

    This paper presents a design analysis for the development of highly efficient heat exchangers within stationary metal hydride heat pumps. The design constraints and selected performance criteria are applied to three representative heat exchangers. The proposed thermal model can be applied to select the most efficient heat exchanger design and provides outcomes generally valid in a pre-design stage. Heat transfer effectiveness is the principal performance parameter guiding the selection analysis, the results of which appear to be mildly (up to 13%) affected by the specific Nusselt correlation used. The thermo-physical properties of the heat transfer medium and geometrical parameters aremore » varied in the sensitivity analysis, suggesting that the length of independent tubes is the physical parameter that influences the performance of the heat exchangers the most. The practical operative regions for each heat exchanger are identified by finding the conditions over which the heat removal from the solid bed enables a complete and continuous hydriding reaction. The most efficient solution is a design example that achieves the target effectiveness of 95%.« less

  2. A Novel Zr-1Nb Alloy and a New Look at Hydriding

    SciTech Connect (OSTI)

    Robert D. Mariani; James I. Cole; Assel Aitkaliyeva

    2013-09-01

    A novel Zr-1Nb has begun development based on a working model that takes into account the hydrogen permeabilities for zirconium and niobium metals. The beta-Nb secondary phase particles (SPPs) in Zr-1Nb are believed to promote more rapid hydrogen dynamics in the alloy in comparison to other zirconium alloys. Furthermore, some hydrogen release is expected at the lower temperatures corresponding to outages when the partial pressure of H2 in the coolant is less. These characteristics lessen the negative synergism between corrosion and hydriding that is otherwise observed in cladding alloys without niobium. In accord with the working model, development of nanoscale precursors was initiated to enhance the performance of existing Zr-1Nb alloys. Their characteristics and properties can be compared to oxide-dispersion strengthened alloys, and material additions have been proposed to zirconium-based LWR cladding to guard further against hydriding and to fix the size of the SPPs for microstructure stability enhancements. A preparative route is being investigated that does not require mechanical alloying, and 10 nanometer molybdenum particles have been prepared which are part of the nanoscale precursors. If successful, the approach has implications for long term dry storage of used fuel and for new routes to nanoferritic and ODS alloys.

  3. EXPERIMENTAL RESULTS FOR THE ISOTOPIC EXCHANGE OF A 1600 LITER TITANIUM HYDRIDE STORAGE VESSEL

    SciTech Connect (OSTI)

    Klein, J.

    2010-12-14

    Titanium is used as a low pressure tritium storage material. The absorption/desorption rates and temperature rise during air passivation have been reported previously for a 4400 gram prototype titanium hydride storage vessel (HSV). A desorption limit of roughly 0.25 Q/M was obtained when heating to 700 C which represents a significant residual tritium process vessel inventory. To prepare an HSV for disposal, batchwise isotopic exchange has been proposed to reduce the tritium content to acceptable levels. A prototype HSV was loaded with deuterium and exchanged with protium to determine the effectiveness of a batch-wise isotopic exchange process. A total of seven exchange cycles were performed. Gas samples were taken nominally at the beginning, middle, and end of each desorption cycle. Sample analyses showed the isotopic exchange process does not follow the standard dilution model commonly reported. Samples taken at the start of the desorption process were lower in deuterium (the gas to be removed) than those taken later in the desorption cycle. The results are explained in terms of incomplete mixing of the exchange gas in the low pressure hydride.

  4. METHOD FOR PRODUCING ISOTOPIC METHANES FROM LITHIUM CARBONATE AND LITHIUM HYDRIDE

    DOE Patents [OSTI]

    Frazer, J.W.

    1959-10-27

    A process is descrlbed for the production of methane and for the production of methane containing isotopes of hydrogen and/or carbon. Finely divided lithium hydrlde and litldum carbonate reactants are mixed in intimate contact and subsequently compacted under pressures of from 5000 to 60,000 psl. The compacted lithium hydride and lithium carbenate reactunts are dispised in a gas collecting apparatus. Subsequently, the compact is heated to a temperature in the range 350 to 400 deg C whereupon a solid-solid reaction takes place and gaseous methane is evolved. The evolved methane is contaminated with gaseous hydrogen and a very small amount of CO/sub 2/; however, the desired methane product is separated from sald impurities by well known chemical processes, e.g., condensation in a cold trap. The product methane contalns isotopes of carbon and hydrogen, the Isotopic composition being determined by the carbon isotopes originally present In the lithium carbonate and the hydrogen isotopes originally present in the lithium hydride.

  5. THE EFFECT OF 3HE ON LOW PRESSURE HYDRIDE ABSORPTION MEASUREMENTS WITH TRITIUM

    SciTech Connect (OSTI)

    Staack, G.; Klein, J.

    2011-01-20

    Absorption isotherm data exists for a wide variety of hydrogen-metal systems. When working with high purity gases, appropriately sized equipment, and hydrides with equilibrium pressures above several hundred Pa, data collection is relatively straightforward. Special consideration must be given to experiments involving low equilibrium pressure hydrides, as even sub-ppm levels of gas impurities can generate partial pressures many times greater than the equilibrium pressures to be measured. Tritium absorption experiments are further complicated by the continuous generation of helium-3. The time required to transfer and absorb a known quantity of tritium onto a sample ultimately limits the minimum pressure range that can be studied using the standard technique. Equations are presented which show the pressure of helium-3 in a sample cell based on the amount of tritium to be absorbed, the sample cell volume and temperature, and the decay time of tritium. Sample calculations for zirconium show that at 300 C, the estimated helium-3 pressure in the cell will be equal to the hydrogen absorption pressure after only milliseconds of tritium decay. An alternate method is presented that permits the collection of equilibrium data at pressures orders of magnitude lower than possible using a direct approach.

  6. Verification and Validation Strategy for Implementation of Hybrid Potts-Phase Field Hydride Modeling Capability in MBM

    SciTech Connect (OSTI)

    Jason D. Hales; Veena Tikare

    2014-04-01

    The Used Fuel Disposition (UFD) program has initiated a project to develop a hydride formation modeling tool using a hybrid Potts­phase field approach. The Potts model is incorporated in the SPPARKS code from Sandia National Laboratories. The phase field model is provided through MARMOT from Idaho National Laboratory.

  7. NSR Key Number Retrieval

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NSR Key Number Retrieval Pease enter key in the box Submit

  8. Hydride vapor phase GaN films with reduced density of residual electrons and deep traps

    SciTech Connect (OSTI)

    Polyakov, A. Y.; Smirnov, N. B.; Govorkov, A. V.; Yugova, T. G.; Cox, H.; Helava, H.; Makarov, Yu.; Usikov, A. S.

    2014-05-14

    Electrical properties and deep electron and hole traps spectra are compared for undoped n-GaN films grown by hydride vapor phase epitaxy (HVPE) in the regular process (standard HVPE samples) and in HVPE process optimized for decreasing the concentration of residual donor impurities (improved HVPE samples). It is shown that the residual donor density can be reduced by optimization from ?10{sup 17}?cm{sup ?3} to (25)??10{sup 14}?cm{sup ?3}. The density of deep hole traps and deep electron traps decreases with decreased donor density, so that the concentration of deep hole traps in the improved samples is reduced to ?5??10{sup 13}?cm{sup ?3} versus 2.9??10{sup 16}?cm{sup ?3} in the standard samples, with a similar decrease in the electron traps concentration.

  9. THE HYDROLYSIS AND OXIDATION BEHAVIOR OF LITHIUM BOROHYDRIDE AND MAGNESIUM HYDRIDE DETERMINED BY CALORIMETRY

    SciTech Connect (OSTI)

    Brinkman, K; Donald Anton, D; Joshua Gray, J; Bruce Hardy, B

    2008-03-13

    Lithium borohydride, magnesium hydride and the 2:1 'destabilized' ball milled mixtures (2LiBH{sub 4}:MgH{sub 2}) underwent liquid phase hydrolysis, gas phase hydrolysis and air oxidation reactions monitored by isothermal calorimetry. The experimentally determined heats of reaction and resulting products were compared with those theoretically predicted using thermodynamic databases. Results showed a discrepancy between the predicted and observed hydrolysis and oxidation products due to both kinetic limitations and to the significant amorphous character of observed reaction products. Gas phase and liquid phase hydrolysis were the dominant reactions in 2LiBH{sub 4}:MgH{sub 2} with approximately the same total energy release and reaction products; liquid phase hydrolysis displayed the maximum heat flow for likely environmental exposure with a peak energy release of 6 (mW/mg).

  10. LaNi{sub 5}-based metal hydride electrode in Ni-MH rechargeable cells

    DOE Patents [OSTI]

    Bugga, R.V.; Fultz, B.; Bowman, R.; Surampudi, S.R.; Witham, C.K.; Hightower, A.

    1999-03-30

    An at least ternary metal alloy of the formula AB{sub (Z-Y)}X{sub (Y)} is disclosed. In this formula, A is selected from the rare earth elements, B is selected from the elements of Groups 8, 9, and 10 of the Periodic Table of the Elements, and X includes at least one of the following: antimony, arsenic, germanium, tin or bismuth. Z is greater than or equal to 4.8 and less than or equal to 6.0. Y is greater than 0 and less than 1. Ternary or higher-order substitutions to the base AB{sub 5} alloys that form strong kinetic interactions with the predominant metals in the base metal hydride are used to form metal alloys with high structural integrity after multiple cycles of hydrogen sorption. 16 figs.

  11. Method to predict relative hydriding within a group of zirconium alloys under nuclear irradiation

    DOE Patents [OSTI]

    Johnson, Jr., A. Burtron; Levy, Ira S.; Trimble, Dennis J.; Lanning, Donald D.; Gerber, Franna S.

    1990-01-01

    An out-of-reactor method for screening to predict relative in-reactor hydriding behavior of zirconium-bsed materials is disclosed. Samples of zirconium-based materials having different composition and/or fabrication are autoclaved in a relatively concentrated (0.3 to 1.0M) aqueous lithium hydroxide solution at constant temperatures within the water reactor coolant temperature range (280.degree. to 316.degree. C.). Samples tested by this out-of-reactor procedure, when compared on the basis of the ratio of hydrogen weight gain to oxide weight gain, accurately predict the relative rate of hyriding for the same materials when subject to in-reactor (irradiated) corrision.

  12. RF sputtering for controlling dihydride and monohydride bond densities in amorphous silicon hydride

    DOE Patents [OSTI]

    Jeffery, F.R.; Shanks, H.R.

    1980-08-26

    A process is described for controlling the dihydride and monohydride bond densities in hydrogenated amorphous silicone produced by reactive rf sputtering of an amorphous silicon target. There is provided a chamber with an amorphous silicon target and a substrate therein with the substrate and the target positioned such that when rf power is applied to the target the substrate is in contact with the sputtering plasma produced thereby. Hydrogen and argon are fed to the chamber and the pressure is reduced in the chamber to a value sufficient to maintain a sputtering plasma therein, and then rf power is applied to the silicon target to provide a power density in the range of from about 7 watts per square inch to about 22 watts per square inch to sputter an amorphous solicone hydride onto the substrate, the dihydride bond density decreasing with an increase in the rf power density. Substantially pure monohydride films may be produced.

  13. Production of Hydrogen by Electrocatalysis: Making the H-H Bond by Combining Protons and Hydrides

    SciTech Connect (OSTI)

    Bullock, R. Morris; Appel, Aaron M.; Helm, Monte L.

    2014-03-25

    Generation of hydrogen by reduction of two protons by two electrons can be catalysed by molecular electrocatalysts. Determination of the thermodynamic driving force for elimination of H2 from molecular complexes is important for the rational design of molecular electrocatalysts, and allows the design of metal complexes of abundant, inexpensive metals rather than precious metals (“Cheap Metals for Noble Tasks”). The rate of H2 evolution can be dramatically accelerated by incorporating pendant amines into diphosphine ligands. These pendant amines in the second coordination sphere function as protons relays, accelerating intramolecular and intermolecular proton transfer reactions. The thermodynamics of hydride transfer from metal hydrides and the acidity of protonated pendant amines (pKa of N-H) contribute to the thermodynamics of elimination of H2; both of the hydricity and acidity can be systematically varied by changing the substituents on the ligands. A series of Ni(II) electrocatalysts with pendant amines have been developed. In addition to the thermochemical considerations, the catalytic rate is strongly influenced by the ability to deliver protons to the correct location of the pendant amine. Protonation of the amine endo to the metal leads to the N-H being positioned appropriately to favor rapid heterocoupling with the M-H. Designing ligands that include proton relays that are properly positioned and thermodynamically tuned is a key principle for molecular electrocatalysts for H2 production as well as for other multi-proton, multi-electron reactions important for energy conversions. The research was supported as part of the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences. Pacific Northwest National Laboratory is operated by Battelle for DOE.

  14. Anisotropic Azimuthal Power and Temperature distribution on FuelRod. Impact on Hydride Distribution

    SciTech Connect (OSTI)

    Motta, Arthur; Ivanov, Kostadin; Arramova, Maria; Hales, Jason

    2015-04-29

    The degradation of the zirconium cladding may limit nuclear fuel performance. In the high temperature environment of a reactor, the zirconium in the cladding corrodes, releasing hydrogen in the process. Some of this hydrogen is absorbed by the cladding in a highly inhomogeneous manner. The distribution of the absorbed hydrogen is extremely sensitive to temperature and stress concentration gradients. The absorbed hydrogen tends to concentrate near lower temperatures. This hydrogen absorption and hydride formation can cause cladding failure. This project set out to improve the hydrogen distribution prediction capabilities of the BISON fuel performance code. The project was split into two primary sections, first was the use of a high fidelity multi-physics coupling to accurately predict temperature gradients as a function of r, θ , and z, and the second was to use experimental data to create an analytical hydrogen precipitation model. The Penn State version of thermal hydraulics code COBRA-TF (CTF) was successfully coupled to the DeCART neutronics code. This coupled system was verified by testing and validated by comparison to FRAPCON data. The hydrogen diffusion and precipitation experiments successfully calculated the heat of transport and precipitation rate constant values to be used within the hydrogen model in BISON. These values can only be determined experimentally. These values were successfully implemented in precipitation, diffusion and dissolution kernels that were implemented in the BISON code. The coupled output was fed into BISON models and the hydrogen and hydride distributions behaved as expected. Simulations were conducted in the radial, axial and azimuthal directions to showcase the full capabilities of the hydrogen model.

  15. The anti-perovskite type hydride InPd{sub 3}H{sub 0.89}

    SciTech Connect (OSTI)

    Kohlmann, H.; Skripov, A.V.; Soloninin, A.V.; Udovic, T.J.

    2010-10-15

    Hydrogenation of tetragonal InPd{sub 3} in the ZrAl{sub 3} type structure (four-fold ccp superstructure) yields a hydride with a cubic AuCu{sub 3} type structure (one-fold ccp superstructure). Deuterium can be located by neutron powder diffraction in octahedral voids surrounded exclusively by palladium, [Pd{sub 6}], which are 88.5(6)% occupied in a statistical manner. The resulting deuteride InPd{sub 3}D{sub 0.89} thus crystallizes in a cubic anti-perovskite type structure (space group Pm3-bar m (no. 221), a=402.25(1) pm at 299(2) K). The Pd-D distance of 201.13(1) pm is typical for interstitial hydrides with palladium. Inelastic neutron scattering on the hydride InPd{sub 3}H{sub 0.89}, which shows a spectrum similar to that of binary palladium hydride, confirms the cubic site symmetry of hydrogen in [Pd{sub 6}] interstices. This is also confirmed by the absence of any quadrupole splitting in the {sup 2}D-NMR signal of the deuteride. {sup 1}H NMR spectra of InPd{sub 3}H{sub 0.89} do not show any motional narrowing. Values found for the H jump rate {tau}{sup -1} in InPd{sub 3}H{sub 0.89} remain below 10{sup 6} s{sup -1} in the studied temperature range 28-360 K, indicating a small hydrogen mobility in InPd{sub 3}H{sub 0.8} as compared with binary palladium hydride, PdH{sub {<=}1}. This can be attributed to the large spatial separation of the [Pd{sub 6}] sites. - Graphical abstract: Hydrogen induces a rearrangement in InPd{sub 3} from a ZrAl{sub 3} type structure to a cubic AuCu{sub 3} type structure, thus forming an anti-perovskite type hydride InPd{sub 3}H{sub 0.89}.

  16. Executive Summaries for the Hydrogen Storage Materials Center of Excellence - Chemical Hydrogen Storage CoE, Hydrogen Sorption CoE, and Metal Hydride CoE

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Executive Summaries for the Hydrogen Storage Materials Centers of Excellence Chemical Hydrogen Storage CoE, Hydrogen Sorption CoE, and Metal Hydride CoE Period of Performance: 2005-2010 Fuel Cell Technologies Program Office of Energy Efficiency and Renewable Energy U. S. Department of Energy April 2012 2 3 Primary Authors: Chemical Hydrogen Storage (CHSCoE): Kevin Ott, Los Alamos National Laboratory Hydrogen Sorption (HSCoE): Lin Simpson, National Renewable Energy Laboratory Metal Hydride

  17. Facile synthesis of Ba1-xKxFe?As? superconductors via hydride route

    SciTech Connect (OSTI)

    Zaikina, Julia V. [Univ. of California at Davis, Davis, CA (United States); Batuk, Maria [Univ. of Antwerp, Antwerp (Belgium); Abakumov, Artem M. [Univ. of Antwerp, Antwerp (Belgium); Navrotsky, Alexandra [Univ. of California at Davis, Davis, CA (United States); Kauzlarich, Susan M. [Univ. of California at Davis, Davis, CA (United States)

    2014-12-03

    We have developed a fast, easy, and scalable synthesis method for Ba1-xKxFe?As? (0 ? x ? 1) superconductors using hydrides BaH? and KH as a source of barium and potassium metals. Synthesis from hydrides provides better mixing and easier handling of the starting materials, consequently leading to faster reactions and/or lower synthesis temperatures. The reducing atmosphere provided by the evolved hydrogen facilitates preparation of oxygen-free powders. By a combination of methods we have shown that Ba1-xKxFe?As? obtained via hydride route has the same characteristics as when it is prepared by traditional solid-state synthesis. Refinement from synchrotron powder X-ray diffraction data confirms a linear dependence of unit cell parameters upon K content as well as the tetragonal to orthorhombic transition at low temperatures for compositions with x < 0.2. Magnetic measurements revealed dome-like dependence of superconducting transition temperature Tc upon K content with a maximum of 38 K for x close to 0.4. Electron diffraction and high-resolution high-angle annular dark-field scanning transmission electron microscopy indicates an absence of Ba/K ordering, while local inhomogeneity in the Ba/K distribution takes place at a scale of several angstroms along [110] crystallographic direction.

  18. New York Natural Gas Number of Commercial Consumers (Number of...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Commercial Consumers (Number of Elements) New York Natural Gas Number of Commercial ... Referring Pages: Number of Natural Gas Commercial Consumers New York Number of Natural Gas ...

  19. New Mexico Natural Gas Number of Commercial Consumers (Number...

    Gasoline and Diesel Fuel Update (EIA)

    Commercial Consumers (Number of Elements) New Mexico Natural Gas Number of Commercial ... Referring Pages: Number of Natural Gas Commercial Consumers New Mexico Number of Natural ...

  20. North Dakota Natural Gas Number of Commercial Consumers (Number...

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) North Dakota Natural Gas Number of Commercial ... Referring Pages: Number of Natural Gas Commercial Consumers North Dakota Number of Natural ...

  1. Microstructure and hydriding studies of AB/sub 5/ hydrogen storage compounds. Final report

    SciTech Connect (OSTI)

    Goodell, P.D.; Sandrock, G.D.; Huston, E.L.

    1980-01-01

    New data on the microstructure, pressure-composition-temperature, and absorption/desorption kinetics of AB/sub 5/ metal hydrides are presented. The most significant result to emerge from the investigation is that many of the AB/sub 5/ metal hydrides, especially the LaNi/sub 5/ related materials, show instantaneous absorption and desorption response in proportion to the amount of cooling or heating which is provided. Eight categories of materials were studied: reference alloys (LaNi/sub 5/, LaNi/sub 4/ /sub 9/Al/sub 0/ /sub 1/, LaNi/sub 3/Co/sub 2/); Ni second phase particles (LaNi/sub 5/ /sub 67/, LaNi/sub 7/, LaNi/sub 11/ /sub 3/); eutectoid microstructure (SmCo/sub 5/); other second phases (LaNi/sub 3/ /sub 8/Fe/sub 1/ /sub 2/, LaNi/sub 3/ /sub 5/Cr/sub 1/ /sub 5/, LaNi/sub 4/Cr, LaNi/sub 4/Si; LaNi/sub 4/Sn, MNi/sub 4/Sn, MNi/sub 4/ /sub 3/Al/sub 0/ /sub 7/); substitutional elements (LaNi/sub 4/Cu, LaNi/sub 4/ /sub 5/Pd/sub 0/ /sub 5/, LaNi/sub 4/ /sub 7/Sn/sub 0/ /sub 3/, LaNi/sub 4/ /sub 8/C/sub 0/ /sub 2/, MNi/sub 4/ /sub 3/Mn/sub 0/ /sub 7/); surface active elements (LaNi/sub 4/ /sub 8/B/sub 0/ /sub 2/, LaNi/sub 4/ /sub 9/S/sub 0/ /sub 1/, LaNi/sub 4/ /sub 9/Se/sub 0/ /sub 1/); large diameter atom substitutions (Mg/sub 0/ /sub 1/La/sub 0/ /sub 9/Ni/sub 5/, Ca/sub 0/ /sub 2/La/sub 0/ /sub 8/Ni/sub 5/, Sr/sub 0/ /sub 2/La/sub 0/ /sub 8/Ni/sub 5/, Ba/sub 0/ /sub 2/La/sub 0/ /sub 8/Ni/sub 5/); other compositions (LaNi/sub 3/); and Pd plating (electroless plated samples and mechanically alloyed specimens).

  2. Quantum random number generator

    DOE Patents [OSTI]

    Pooser, Raphael C.

    2016-05-10

    A quantum random number generator (QRNG) and a photon generator for a QRNG are provided. The photon generator may be operated in a spontaneous mode below a lasing threshold to emit photons. Photons emitted from the photon generator may have at least one random characteristic, which may be monitored by the QRNG to generate a random number. In one embodiment, the photon generator may include a photon emitter and an amplifier coupled to the photon emitter. The amplifier may enable the photon generator to be used in the QRNG without introducing significant bias in the random number and may enable multiplexing of multiple random numbers. The amplifier may also desensitize the photon generator to fluctuations in power supplied thereto while operating in the spontaneous mode. In one embodiment, the photon emitter and amplifier may be a tapered diode amplifier.

  3. Report number codes

    SciTech Connect (OSTI)

    Nelson, R.N.

    1985-05-01

    This publication lists all report number codes processed by the Office of Scientific and Technical Information. The report codes are substantially based on the American National Standards Institute, Standard Technical Report Number (STRN)-Format and Creation Z39.23-1983. The Standard Technical Report Number (STRN) provides one of the primary methods of identifying a specific technical report. The STRN consists of two parts: The report code and the sequential number. The report code identifies the issuing organization, a specific program, or a type of document. The sequential number, which is assigned in sequence by each report issuing entity, is not included in this publication. Part I of this compilation is alphabetized by report codes followed by issuing installations. Part II lists the issuing organization followed by the assigned report code(s). In both Parts I and II, the names of issuing organizations appear for the most part in the form used at the time the reports were issued. However, for some of the more prolific installations which have had name changes, all entries have been merged under the current name.

  4. Studies of isotopic exchange between gaseous hydrogen and palladium hydride powder

    SciTech Connect (OSTI)

    Foltz, G.W.; Melius, C.F.

    1987-12-01

    A gas flow apparatus has been constructed and used to study the isotopic exchange reaction occurring between the solid and gas phases in hydrogen (deuterium) gas flows directed through packed-powder beds of ..beta..-phase palladium deuteride (hydride). Spontaneous Raman light scattering is employed to obtain a real-time analysis of the isotopic composition of the gas (H/sub 2/, D/sub 2/, HD) exiting from the bed. A parametric rate-equation model is described which depicts the time-dependent behavior of the isotopic exchange process. The exchange mechanism is assumed to be rate-limited by processes occurring on the surface of the powder. The fundamental kinetic parameter of the model is the isotopic exchange probability, p, which is the probability that an isotopic exchange event occurs during a collision of a gas-phase atom with the surface. Isotope effects between the gas and solid phases are explicitly included in terms of the isotope separation factor, ..cap alpha... Results of the model are compared with the experimental measurements and, using a literature value of ..cap alpha.. = 2.4, good agreement is obtained for p approx. = 10/sup -7/. In view of the importance of the isotope effects in the hydrogen/palladium system and the range of a values reported for the ..beta..-phase in the literature, the sensitivity of the model results to a variation in the value of ..cap alpha.. is examined.

  5. Atomic-Scale Chemical, Physical and Electronic Properties of the Subsurface Hydride of Palladium

    SciTech Connect (OSTI)

    Weiss, Paul

    2014-01-20

    We employed low-temperature, extreme-high vacuum scanning tunneling microscopy (STM) to investigate the roles of subsurface hydride (H) and deuteride (D) in the surface reconstruction and surface reactivity of Pd{110}. Specifically, we gained the ability to tailor the surface structure of Pd{110} both by preparation method and by deposition of deuterium from the gas phase. We observed thiophene at low coverage on Pd{110} to determine its adsorption orientation and electronic structure through scanning tunneling spectroscopy (STS) namely, conductance spectroscopy and differential conductance imaging. We developed the methods necessary to coadsorb D adatoms with thiophene molecules, and to induce the reaction of individual molecules with predefined subsurface H or D features. In the case of Pd{110}, we found a much more pronounced effect from subsurface D, as it is influenced by the surface directionality. These experiments facilitate an understanding of the role of surface and subsurface H and D in heterogeneous catalytic processes, specifically in the hydrodesulfuization (HDS) of thiophene, an important and ubiquitous component found to be detrimental to petroleum refining.

  6. Modeling of temporal behavior of isotopic exchange between gaseous hydrogen and palladium hydride power

    SciTech Connect (OSTI)

    Melius, C F; Foltz, G W

    1987-01-01

    A parametric rate-equation model is described which depicts the time dependent behavior of the isotopic exchange process occurring between the solid and gas phases in gaseous hydrogen (deuterium) flows through packed-powder palladium deuteride (hydride) beds. The exchange mechanism is assumed to be rate-limited by processes taking place on the surface of the powder. The fundamental kinetic parameter of the model is the isotopic exchange probability, p, which is the probability that an isotopic exchange event occurs during a collision of a gas phase atom with the surface. Isotope effects between the gas and solid phases are explicitly included in terms of the isotope separation factor, ..cap alpha... Results of the model are compared with recent experimental measurements of isotope exchange in the ..beta..-phase hydrogen/palladium system and, using a literature value of ..cap alpha.. = 2.4, a good description of the experimental data is obtained for p approx. 10/sup -7/. In view of the importance of the isotope effects in the hydrogen/palladium system and the range of ..cap alpha.. values reported for the ..beta..-phase in the literature, the sensitivity of the model results to a variation in the value of ..cap alpha.. is examined.

  7. Avalanching strain dynamics during the hydriding phase transformation in individual palladium nanoparticles

    SciTech Connect (OSTI)

    Ulvestad, A.; Welland, M. J.; Collins, S. S. E.; Harder, R.; Maxey, E.; Wingert, J.; Singer, A.; Hy, S.; Mulvaney, P.; Zapol, P.; Shpyrko, O. G.

    2015-12-11

    Phase transitions in reactive environments are crucially important in energy and information storage, catalysis and sensors. Nanostructuring active particles can yield faster charging/ discharging kinetics, increased lifespan and record catalytic activities. However, establishing the causal link between structure and function is challenging for nanoparticles, as ensemble measurements convolve intrinsic single-particle properties with sample diversity. Here we study the hydriding phase transformation in individual palladium nanocubes in situ using coherent X-ray diffractive imaging. The phase transformation dynamics, which involve the nucleation and propagation of a hydrogen-rich region, are dependent on absolute time (aging) and involve intermittent dynamics (avalanching). A hydrogen-rich surface layer dominates the crystal strain in the hydrogen-poor phase, while strain inversion occurs at the cube corners in the hydrogen-rich phase. A three-dimensional phase-field model is used to interpret the experimental results. In conclusion, our experimental and theoretical approach provides a general framework for designing and optimizing phase transformations for single nanocrystals in reactive environments.

  8. Systems Modeling of Chemical Hydride Hydrogen Storage Materials for Fuel Cell Applications

    SciTech Connect (OSTI)

    Brooks, Kriston P.; Devarakonda, Maruthi N.; Rassat, Scot D.; Holladay, Jamelyn D.

    2011-10-05

    A fixed bed reactor was designed, modeled and simulated for hydrogen storage on-board the vehicle for PEM fuel cell applications. Ammonia Borane (AB) was selected by DOE's Hydrogen Storage Engineering Center of Excellence (HSECoE) as the initial chemical hydride of study because of its high hydrogen storage capacity (up to {approx}16% by weight for the release of {approx}2.5 molar equivalents of hydrogen gas) and its stability under typical ambient conditions. The design evaluated consisted of a tank with 8 thermally isolated sections in which H2 flows freely between sections to provide ballast. Heating elements are used to initiate reactions in each section when pressure drops below a specified level in the tank. Reactor models in Excel and COMSOL were developed to demonstrate the proof-of-concept, which was then used to develop systems models in Matlab/Simulink. Experiments and drive cycle simulations showed that the storage system meets thirteen 2010 DOE targets in entirety and the remaining four at greater than 60% of the target.

  9. TRITIUM IN-BED ACCOUNTABILITY FOR A PASSIVELY COOLED, ELECTRICALLY HEATED HYDRIDE BED

    SciTech Connect (OSTI)

    Klein, J.; Foster, P.

    2011-01-21

    A PAssively Cooled, Electrically heated hydride (PACE) Bed has been deployed into tritium service in the Savannah River Site (SRS) Tritium Facilities. The bed design, absorption and desorption performance, and cold (non-radioactive) in-bed accountability (IBA) results have been reported previously. Six PACE Beds were fitted with instrumentation to perform the steady-state, flowing gas calorimetric inventory method. An IBA inventory calibration curve, flowing gas temperature rise ({Delta}T) versus simulated or actual tritium loading, was generated for each bed. Results for non-radioactive ('cold') tests using the internal electric heaters and tritium calibration results are presented. Changes in vacuum jacket pressure significantly impact measured IBA {Delta}T values. Higher jacket pressures produce lower IBA {Delta}T values which underestimate bed tritium inventories. The exhaust pressure of the IBA gas flow through the bed's U-tube has little influence on measured IBA {Delta}T values, but larger gas flows reduce the time to reach steady-state conditions and produce smaller tritium measurement uncertainties.

  10. Hydride bridge in [NiFe]-hydrogenase observed by nuclear resonance vibrational spectroscopy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ogata, Hideaki; Krämer, Tobias; Wang, Hongxin; Schilter, David; Pelmenschikov, Vladimir; van Gastel, Maurice; Neese, Frank; Rauchfuss, Thomas B.; Gee, Leland B.; Scott, Aubrey D.; et al

    2015-08-10

    The metabolism of many anaerobes relies on [NiFe]-hydrogenases, whose characterization when bound to substrates has proven non-trivial. Presented here is direct evidence for a hydride bridge in the active site of the 57Fe-labelled fully reduced Ni-R form of Desulfovibrio vulgaris Miyazaki F [NiFe]-hydrogenase. A unique ‘wagging’ mode involving H- motion perpendicular to the Ni(μ-H)57Fe plane was studied using 57Fe-specific nuclear resonance vibrational spectroscopy and density functional theory (DFT) calculations. On Ni(μ-D)57Fe deuteride substitution, this wagging causes a characteristic perturbation of Fe–CO/CN bands. Spectra have been interpreted by comparison with Ni(μ-H/D)57Fe enzyme mimics [(dppe)Ni(μ-pdt)(μ-H/D)57Fe(CO)3]+ and DFT calculations, which collectively indicate amore » low-spin Ni(II)(μ-H)Fe(II) core for Ni-R, with H- binding Ni more tightly than Fe. Lastly, the present methodology is also relevant to characterizing Fe–H moieties in other important natural and synthetic catalysts.« less

  11. Avalanching strain dynamics during the hydriding phase transformation in individual palladium nanoparticles

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ulvestad, A.; Welland, M. J.; Collins, S. S. E.; Harder, R.; Maxey, E.; Wingert, J.; Singer, A.; Hy, S.; Mulvaney, P.; Zapol, P.; et al

    2015-12-11

    Phase transitions in reactive environments are crucially important in energy and information storage, catalysis and sensors. Nanostructuring active particles can yield faster charging/ discharging kinetics, increased lifespan and record catalytic activities. However, establishing the causal link between structure and function is challenging for nanoparticles, as ensemble measurements convolve intrinsic single-particle properties with sample diversity. Here we study the hydriding phase transformation in individual palladium nanocubes in situ using coherent X-ray diffractive imaging. The phase transformation dynamics, which involve the nucleation and propagation of a hydrogen-rich region, are dependent on absolute time (aging) and involve intermittent dynamics (avalanching). A hydrogen-rich surfacemore » layer dominates the crystal strain in the hydrogen-poor phase, while strain inversion occurs at the cube corners in the hydrogen-rich phase. A three-dimensional phase-field model is used to interpret the experimental results. In conclusion, our experimental and theoretical approach provides a general framework for designing and optimizing phase transformations for single nanocrystals in reactive environments.« less

  12. Quantum random number generation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ma, Xiongfeng; Yuan, Xiao; Cao, Zhu; Zhang, Zhen; Qi, Bing

    2016-06-28

    Here, quantum physics can be exploited to generate true random numbers, which play important roles in many applications, especially in cryptography. Genuine randomness from the measurement of a quantum system reveals the inherent nature of quantumness -- coherence, an important feature that differentiates quantum mechanics from classical physics. The generation of genuine randomness is generally considered impossible with only classical means. Based on the degree of trustworthiness on devices, quantum random number generators (QRNGs) can be grouped into three categories. The first category, practical QRNG, is built on fully trusted and calibrated devices and typically can generate randomness at amore » high speed by properly modeling the devices. The second category is self-testing QRNG, where verifiable randomness can be generated without trusting the actual implementation. The third category, semi-self-testing QRNG, is an intermediate category which provides a tradeoff between the trustworthiness on the device and the random number generation speed.« less

  13. ALARA notes, Number 8

    SciTech Connect (OSTI)

    Khan, T.A.; Baum, J.W.; Beckman, M.C.

    1993-10-01

    This document contains information dealing with the lessons learned from the experience of nuclear plants. In this issue the authors tried to avoid the `tyranny` of numbers and concentrated on the main lessons learned. Topics include: filtration devices for air pollution abatement, crack repair and inspection, and remote handling equipment.

  14. Document Details Document Number

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Document Details Document Number Date of Document Document Title/Description [Links below to each document] D195066340 Not listed. N/A REVISIONS IN STRATIGRAPHIC NOMENCLATURE OF COLUMBIA RIVER BASALT GROUP D196000240 Not listed. N/A EPA DENIAL OF LINER LEACHATE COLLECTION SYSTEM REQUIREMENTS D196005916 Not listed. N/A LATE CENOZOIC STRATIGRAPHY AND TECTONIC EVOLUTION WITHIN SUBSIDING BASIN SOUTH CENTRAL WASHINGTON D196025993 RHO-BWI-ST-14 N/A SUPRABASALT SEDIMENTS OF COLD CREEK SYNCLINE AREA

  15. Particle size effect of hydride formation and surface hydrogen absorption of nanosized palladium catalysts : L{sub 3} edge vs K edge x-ray absorption spectroscopy.

    SciTech Connect (OSTI)

    Tew, M. W.; Miller, J. T.; van Bokhoven, J. A.

    2009-08-01

    The particle size effect on the formation of palladium hydride and on surface hydrogen adsorption was studied at room temperature using in situ X-ray absorption spectroscopy at the Pd K and L{sub 3} edges. Hydride formation was indirectly observed by lattice expansion in Pd K edge XANES spectra and by EXAFS analysis. Hydride formation was directly detected in the L{sub 3} edge spectra. A characteristic spectral feature caused by the formation of a Pd-H antibonding state showed strong particle size dependence. The L{sub 3} edge spectra were reproduced using full multiple scattering analysis and density of state calculations, and the contributions of bulk absorbed and surface hydrogen to the XANES spectra could be distinguished. The ratio of hydrogen on the surface versus that in the bulk increased with decreasing particle size, and smaller particles dissolved less hydrogen.

  16. Two plateaux for palladium hydride and the effect of helium from tritium decay on the desorption plateau pressure for palladium tritide

    SciTech Connect (OSTI)

    Walters, R.T.; Lee, M.W. )

    1991-10-01

    Two plateaux are observed in the desorption isotherm for palladium hydride: a lower plateau pressure for a hydrogen/metal atom ratio (H/M) less than about 0.3 and a slightly higher plateau pressure for H/M greater than about 0.3. This higher pressure corresponds to the reported pressure for palladium hydride. These observations were made for a large surface area palladium powder exposed to both protium and tritium. Helium buildup form tritium decay decreases the lower plateau pressure but does not affect the observations for H/M greater than about 0.3. In this paper, a multiple-energy hydrogen site occupancy model is proposed to explain qualitatively both the dual plateau and the helium effect in palladium hydride.

  17. A coupled transport and solid mechanics formulation with improved reaction kinetics parameters for modeling oxidation and decomposition in a uranium hydride bed.

    SciTech Connect (OSTI)

    Salloum, Maher N.; Shugard, Andrew D.; Kanouff, Michael P.; Gharagozloo, Patricia E.

    2013-03-01

    Modeling of reacting flows in porous media has become particularly important with the increased interest in hydrogen solid-storage beds. An advanced type of storage bed has been proposed that utilizes oxidation of uranium hydride to heat and decompose the hydride, releasing the hydrogen. To reduce the cost and time required to develop these systems experimentally, a valid computational model is required that simulates the reaction of uranium hydride and oxygen gas in a hydrogen storage bed using multiphysics finite element modeling. This SAND report discusses the advancements made in FY12 (since our last SAND report SAND2011-6939) to the model developed as a part of an ASC-P&EM project to address the shortcomings of the previous model. The model considers chemical reactions, heat transport, and mass transport within a hydride bed. Previously, the time-varying permeability and porosity were considered uniform. This led to discrepancies between the simulated results and experimental measurements. In this work, the effects of non-uniform changes in permeability and porosity due to phase and thermal expansion are accounted for. These expansions result in mechanical stresses that lead to bed deformation. To describe this, a simplified solid mechanics model for the local variation of permeability and porosity as a function of the local bed deformation is developed. By using this solid mechanics model, the agreement between our reacting bed model and the experimental data is improved. Additionally, more accurate uranium hydride oxidation kinetics parameters are obtained by fitting the experimental results from a pure uranium hydride oxidation measurement to the ones obtained from the coupled transport-solid mechanics model. Finally, the coupled transport-solid mechanics model governing equations and boundary conditions are summarized and recommendations are made for further development of ARIA and other Sandia codes in order for them to sufficiently implement the model.

  18. Modular redundant number systems

    SciTech Connect (OSTI)

    1998-05-31

    With the increased use of public key cryptography, faster modular multiplication has become an important cryptographic issue. Almost all public key cryptography, including most elliptic curve systems, use modular multiplication. Modular multiplication, particularly for the large public key modulii, is very slow. Increasing the speed of modular multiplication is almost synonymous with increasing the speed of public key cryptography. There are two parts to modular multiplication: multiplication and modular reduction. Though there are fast methods for multiplying and fast methods for doing modular reduction, they do not mix well. Most fast techniques require integers to be in a special form. These special forms are not related and converting from one form to another is more costly than using the standard techniques. To this date it has been better to use the fast modular reduction technique coupled with standard multiplication. Standard modular reduction is much more costly than standard multiplication. Fast modular reduction (Montgomery`s method) reduces the reduction cost to approximately that of a standard multiply. Of the fast multiplication techniques, the redundant number system technique (RNS) is one of the most popular. It is simple, converting a large convolution (multiply) into many smaller independent ones. Not only do redundant number systems increase speed, but the independent parts allow for parallelization. RNS form implies working modulo another constant. Depending on the relationship between these two constants; reduction OR division may be possible, but not both. This paper describes a new technique using ideas from both Montgomery`s method and RNS. It avoids the formula problem and allows fast reduction and multiplication. Since RNS form is used throughout, it also allows the entire process to be parallelized.

  19. Review of consequences of uranium hydride formation in N-Reactor fuel elements stored in the K-Basins

    SciTech Connect (OSTI)

    Weber, J.W.

    1994-09-28

    The 105-K Basins on the Hanford site are used to store uranium fuel elements and assemblies irradiated in and discharged from N Reactor. The storage cylinders in KW Basin are known to have some broken N reactor fuel elements in which the exposed uranium is slowly reacting chemically with water in the cylinder. The products of these reactions are uranium oxide, hydrogen, and potentially some uranium hydride. The purpose of this report is to document the results f the latest review of potential, but highly unlikely accidents postulated to occur as closed cylinders containing N reactor fuel assemblies are opened under water in the KW basin and as a fuel assembly is raised from the basin in a shipping cask for transportation to the 327 Building for examination as part of the SNF Characterization Program. The postulated accidents reviews in this report are considered to bound all potential releases of radioactivity and hydrogen. These postulated accidents are: (1) opening and refill of a cylinder containing significant amounts of hydrogen and uranium hydride; and (2) draining of the single element can be used to keep the fuel element submerged in water after the cask containing the can and element is lifted from the KW Basin. Analysis shows the release of radioactivity to the site boundary is significantly less than that allowed by the K Basin Safety Evaluation. Analysis further shows there would be no damage to the K Basin structure nor would there be injury to personnel for credible events.

  20. Virginia Natural Gas Number of Residential Consumers (Number...

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) Virginia Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 ...

  1. Utah Natural Gas Number of Industrial Consumers (Number of Elements...

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Utah Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 ...

  2. Wisconsin Natural Gas Number of Industrial Consumers (Number...

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Wisconsin Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 ...

  3. Virginia Natural Gas Number of Commercial Consumers (Number of...

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) Virginia Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 ...

  4. Utah Natural Gas Number of Residential Consumers (Number of Elements...

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) Utah Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 ...

  5. Vermont Natural Gas Number of Residential Consumers (Number of...

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) Vermont Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 ...

  6. Utah Natural Gas Number of Commercial Consumers (Number of Elements...

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) Utah Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 ...

  7. Virginia Natural Gas Number of Industrial Consumers (Number of...

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Virginia Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 ...

  8. West Virginia Natural Gas Number of Industrial Consumers (Number...

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) West Virginia Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 ...

  9. Wisconsin Natural Gas Number of Residential Consumers (Number...

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) Wisconsin Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 ...

  10. Vermont Natural Gas Number of Commercial Consumers (Number of...

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) Vermont Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 ...

  11. West Virginia Natural Gas Number of Commercial Consumers (Number...

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) West Virginia Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 ...

  12. Washington Natural Gas Number of Commercial Consumers (Number...

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) Washington Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 ...

  13. Washington Natural Gas Number of Residential Consumers (Number...

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) Washington Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 ...

  14. Washington Natural Gas Number of Industrial Consumers (Number...

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Washington Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 ...

  15. Wisconsin Natural Gas Number of Commercial Consumers (Number...

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) Wisconsin Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 ...

  16. Vermont Natural Gas Number of Industrial Consumers (Number of...

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Vermont Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 ...

  17. West Virginia Natural Gas Number of Residential Consumers (Number...

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) West Virginia Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 ...

  18. New York Natural Gas Number of Residential Consumers (Number...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Residential Consumers (Number of Elements) New York Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 ...

  19. New Mexico Natural Gas Number of Residential Consumers (Number...

    Gasoline and Diesel Fuel Update (EIA)

    Residential Consumers (Number of Elements) New Mexico Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 ...

  20. New Jersey Natural Gas Number of Residential Consumers (Number...

    Gasoline and Diesel Fuel Update (EIA)

    Residential Consumers (Number of Elements) New Jersey Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 ...

  1. New Hampshire Natural Gas Number of Commercial Consumers (Number...

    Gasoline and Diesel Fuel Update (EIA)

    Commercial Consumers (Number of Elements) New Hampshire Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 ...

  2. New Hampshire Natural Gas Number of Industrial Consumers (Number...

    Gasoline and Diesel Fuel Update (EIA)

    Industrial Consumers (Number of Elements) New Hampshire Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 ...

  3. New Hampshire Natural Gas Number of Residential Consumers (Number...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Residential Consumers (Number of Elements) New Hampshire Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 ...

  4. New Mexico Natural Gas Number of Industrial Consumers (Number...

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    Industrial Consumers (Number of Elements) New Mexico Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 ...

  5. North Carolina Natural Gas Number of Residential Consumers (Number...

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) North Carolina Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 ...

  6. North Carolina Natural Gas Number of Industrial Consumers (Number...

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) North Carolina Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 ...

  7. North Dakota Natural Gas Number of Industrial Consumers (Number...

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) North Dakota Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 ...

  8. North Dakota Natural Gas Number of Residential Consumers (Number...

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) North Dakota Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 ...

  9. North Carolina Natural Gas Number of Commercial Consumers (Number...

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) North Carolina Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 ...

  10. MULTIDIMENSIONAL CHEMICAL MODELING OF YOUNG STELLAR OBJECTS. III. THE INFLUENCE OF GEOMETRY ON THE ABUNDANCE AND EXCITATION OF DIATOMIC HYDRIDES

    SciTech Connect (OSTI)

    Bruderer, S.; Benz, A. O.; Staeuber, P.; Doty, S. D.

    2010-09-10

    The Herschel Space Observatory enables observations in the far-infrared at high spectral and spatial resolution. A particular class of molecules will be directly observable: light diatomic hydrides and their ions (CH, OH, SH, NH, CH{sup +}, OH{sup +}, SH{sup +}, NH{sup +}). These simple constituents are important both for the chemical evolution of the region and as tracers of high-energy radiation. If outflows of a forming star erode cavities in the envelope, protostellar far-UV (FUV; 6 < E{sub {gamma}} < 13.6 eV) radiation may escape through such low-density regions. Depending on the shape of the cavity, the FUV radiation then irradiates the quiescent envelope in the walls along the outflow. The chemical composition in these outflow walls is altered by photoreactions and heating via FUV photons in a manner similar to photo-dominated regions. In this work, we study the effect of cavity shapes, outflow density, and of a disk with the two-dimensional chemical model of a high-mass young stellar object introduced in the second paper in this series. The model has been extended with a self-consistent calculation of the dust temperature and a multi-zone escape probability method for the calculation of the molecular excitation and the prediction of line fluxes. We find that the shape of the cavity is particularly important in the innermost part of the envelope, where the dust temperatures are high enough ({approx}>100 K) for water ice to evaporate. If the cavity shape allows FUV radiation to penetrate this hot-core region, the abundance of FUV-destroyed species (e.g., water) is decreased. On larger scales, the shape of the cavity is less important for the chemistry in the outflow wall. In particular, diatomic hydrides and their ions CH{sup +}, OH{sup +}, and NH{sup +} are enhanced by many orders of magnitude in the outflow walls due to the combination of high gas temperatures and rapid photodissociation of more saturated species. The enhancement of these diatomic hydrides

  11. LaNi.sub.5 is-based metal hydride electrode in Ni-MH rechargeable cells

    DOE Patents [OSTI]

    Bugga, Ratnakumar V.; Fultz, Brent; Bowman, Robert; Surampudi, Subra Rao; Witham, Charles K.; Hightower, Adrian

    1999-01-01

    An at least ternary metal alloy of the formula AB.sub.(Z-Y) X.sub.(Y) is disclosed. In this formula, A is selected from the rare earth elements, B is selected from the elements of Groups 8, 9, and 10 of the Periodic Table of the Elements, and X includes at least one of the following: antimony, arsenic, germanium, tin or bismuth. Z is greater than or equal to 4.8 and less than or equal to 6.0. Y is greater than 0 and less than 1. Ternary or higher-order substitutions to the base AB.sub.5 alloys that form strong kinetic interactions with the predominant metals in the base metal hydride are used to form metal alloys with high structural integrity after multiple cycles of hydrogen sorption.

  12. Final Report: DE- FC36-05GO15063, Fundamental Studies of Advanced High-Capacity, Reversible Metal Hydrides

    SciTech Connect (OSTI)

    Jensen, Craig; McGrady, Sean; Severa, Godwin; Eliseo, Jennifer; Chong, Marina

    2015-02-08

    The project was component of the US DOE, Metal Hydride Center of Excellence (MHCoE). The Sandia National Laboratory led center was established to conduct highly collaborative and multi-disciplinary applied R&D to develop new reversible hydrogen storage materials that meet or exceed DOE/FreedomCAR 2010 and 2015 system targets for hydrogen storage materials. Our approach entailed a wide variety of activities ranging from synthesis, characterization, and evaluation of new candidate hydrogen storage materials; screening of catalysts for high capacity materials requiring kinetics enhancement; development of low temperature methods for nano-confinement of hydrides and determining its effects on the kinetics and thermodynamics of hydrides; and development of novel processes for the direct re-hydrogenation of materials. These efforts have resulted in several advancements the development of hydrogen storage materials. We have greatly extended the fundamental knowledge about the highly promising hydrogen storage carrier, alane (AlH₃), by carrying out the first crystal structure determinations and the first determination of the heats of dehydrogenation of β–AlH₃ and γ-AlD₃. A low-temperature homogenous organometallic approach to incorporation of Al and Mg based hydrides into carbon aerogels has been developed that that allows high loadings without degradation of the nano-porous scaffold. Nano-confinement was found to significantly improve the dehydrogenation kinetics but not effect the enthalpy of dehydrogenation. We conceived, characterized, and synthesized a novel class of potential hydrogen storage materials, bimetallic borohydrides. These novel compounds were found to have many favorable properties including release of significant amounts of hydrogen at moderate temperatures (75-190ºC). However, in situ IR studies in tandem with thermal gravimetric analysis have shown that about 0.5 equivalents of diborane are released during the dehydrogenation making re

  13. Number

    Office of Legacy Management (LM)

    engaged in the production of thorium compounds. The purpose of the trip vas to: l 1. Learn the type of chemical processes employed in the thorium industry (thorium nitrate). 2. ...

  14. Energy and environmental impacts of electric vehicle battery production and recycling

    SciTech Connect (OSTI)

    Gaines, L.; Singh, M.

    1995-12-31

    Electric vehicle batteries use energy and generate environmental residuals when they are produced and recycled. This study estimates, for 4 selected battery types (advanced lead-acid, sodium-sulfur, nickel-cadmium, and nickel-metal hydride), the impacts of production and recycling of the materials used in electric vehicle batteries. These impacts are compared, with special attention to the locations of the emissions. It is found that the choice among batteries for electric vehicles involves tradeoffs among impacts. For example, although the nickel-cadmium and nickel-metal hydride batteries are similar, energy requirements for production of the cadmium electrodes may be higher than those for the metal hydride electrodes, but the latter may be more difficult to recycle.

  15. Alaska Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Alaska Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 10 11 8 1990's 8 8 10 11 11 9 202 7 7 9 2000's 9 8 9 9 10 12 11 11 6 3 2010's 3 5 3 3 1 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 08/31/2016 Next Release Date: 09/30/2016 Referring Pages: Number of Natural

  16. Hawaii Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Hawaii Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1990's 27 26 29 2000's 28 28 29 29 29 28 26 27 27 25 2010's 24 24 22 22 23 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 08/31/2016 Next Release Date: 09/30/2016 Referring Pages: Number of Natural Gas Industrial

  17. Steric Effect for Proton, Hydrogen-Atom, andHydride Transfer Reactions with Geometric Isomers of NADH-Model Ruthenium Complexes

    SciTech Connect (OSTI)

    Fujita E.; Cohen, B.W.; Polyansky, D.E.; Achord, P.; Cabelli, D.; Muckerman, J.T.; Tanaka, K.; Thummel, R.P.; Zong, R.

    2012-01-01

    Two isomers, [Ru(1)]{sup 2+} (Ru = Ru(bpy){sub 2}, bpy = 2,2{prime}-bipyridine, 1 = 2-(pyrid-2{prime}-yl)-1-azaacridine) and [Ru(2)]{sup 2+} (2 = 3-(pyrid-2{prime}-yl)-4-azaacridine), are bio-inspired model compounds containing the nicotinamide functionality and can serve as precursors for the photogeneration of C-H hydrides for studying reactions pertinent to the photochemical reduction of metal-C{sub 1} complexes and/or carbon dioxide. While it has been shown that the structural differences between the azaacridine ligands of [Ru(1)]{sup 2+} and [Ru(2)]{sup 2+} have a significant effect on the mechanism of formation of the hydride donors, [Ru(1HH)]{sup 2+} and [Ru(2HH)]{sup 2+}, in aqueous solution, we describe the steric implications for proton, net-hydrogen-atom and net-hydride transfer reactions in this work. Protonation of [Ru(2{sup {sm_bullet}-})]{sup +} in aprotic and even protic media is slow compared to that of [Ru(1{sup {sm_bullet}-})]{sup +}. The net hydrogen-atom transfer between *[Ru(1)]{sup 2+} and hydroquinone (H{sub 2}Q) proceeds by one-step EPT, rather than stepwise electron-proton transfer. Such a reaction was not observed for *[Ru(2)]{sup 2+} because the non-coordinated N atom is not easily available for an interaction with H{sub 2}Q. Finally, the rate of the net hydride ion transfer from [Ru(1HH)]{sup 2+} to [Ph{sub 3}C]{sup +} is significantly slower than that of [Ru(2HH)]{sup 2+} owing to steric congestion at the donor site.

  18. ARM - Measurement - Particle number concentration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    number concentration ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Particle number concentration The number of particles present in any given volume of air. Categories Aerosols Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument for a list of all available measurements, including those

  19. Total Number of Operable Refineries

    U.S. Energy Information Administration (EIA) Indexed Site

    Data Series: Total Number of Operable Refineries Number of Operating Refineries Number of Idle Refineries Atmospheric Crude Oil Distillation Operable Capacity (B/CD) Atmospheric Crude Oil Distillation Operating Capacity (B/CD) Atmospheric Crude Oil Distillation Idle Capacity (B/CD) Atmospheric Crude Oil Distillation Operable Capacity (B/SD) Atmospheric Crude Oil Distillation Operating Capacity (B/SD) Atmospheric Crude Oil Distillation Idle Capacity (B/SD) Vacuum Distillation Downstream Charge

  20. Compendium of Experimental Cetane Numbers

    SciTech Connect (OSTI)

    Yanowitz, J.; Ratcliff, M. A.; McCormick, R. L.; Taylor, J. D.; Murphy, M. J.

    2014-08-01

    This report is an updated version of the 2004 Compendium of Experimental Cetane Number Data and presents a compilation of measured cetane numbers for pure chemical compounds. It includes all available single compound cetane number data found in the scientific literature up until March 2014 as well as a number of unpublished values, most measured over the past decade at the National Renewable Energy Laboratory. This Compendium contains cetane values for 389 pure compounds, including 189 hydrocarbons and 201 oxygenates. More than 250 individual measurements are new to this version of the Compendium. For many compounds, numerous measurements are included, often collected by different researchers using different methods. Cetane number is a relative ranking of a fuel's autoignition characteristics for use in compression ignition engines; it is based on the amount of time between fuel injection and ignition, also known as ignition delay. The cetane number is typically measured either in a single-cylinder engine or a constant volume combustion chamber. Values in the previous Compendium derived from octane numbers have been removed, and replaced with a brief analysis of the correlation between cetane numbers and octane numbers. The discussion on the accuracy and precision of the most commonly used methods for measuring cetane has been expanded and the data has been annotated extensively to provide additional information that will help the reader judge the relative reliability of individual results.

  1. Nevada Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Nevada Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 93 98 100 1990's 100 113 114 117 119 120 121 93 93 109 2000's 90 90 96 97 179 192 207 220 189 192 2010's 184 177 177 195 218 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 08/31/2016 Next Release Date: 09/30/2016

  2. Maine Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Maine Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 73 73 74 1990's 80 81 80 66 89 74 87 81 110 108 2000's 178 233 66 65 69 69 73 76 82 85 2010's 94 102 108 120 126 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 08/31/2016 Next Release Date: 09/30/2016 Referring

  3. Montana Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Montana Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 435 435 428 1990's 457 452 459 462 453 463 466 462 454 397 2000's 71 73 439 412 593 716 711 693 693 396 2010's 384 381 372 372 369 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 08/31/2016 Next Release Date:

  4. Wyoming Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Wyoming Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 190 200 230 1990's 284 228 244 194 135 126 170 194 317 314 2000's 308 295 877 179 121 127 133 133 155 130 2010's 120 123 127 132 131 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 08/31/2016 Next Release Date:

  5. Arizona Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Arizona Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 358 344 354 1990's 526 532 532 526 519 530 534 480 514 555 2000's 526 504 488 450 414 425 439 395 383 390 2010's 368 371 379 383 386 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 08/31/2016 Next Release Date:

  6. Delaware Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Delaware Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 241 233 235 1990's 240 243 248 249 252 253 250 265 257 264 2000's 297 316 182 184 186 179 170 185 165 112 2010's 114 129 134 138 141 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 08/31/2016 Next Release Date:

  7. Florida Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Florida Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 575 552 460 1990's 452 377 388 433 481 515 517 561 574 573 2000's 520 518 451 421 398 432 475 467 449 607 2010's 581 630 507 528 520 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 08/31/2016 Next Release Date:

  8. Idaho Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Idaho Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 219 132 64 1990's 62 65 66 75 144 167 183 189 203 200 2000's 217 198 194 191 196 195 192 188 199 187 2010's 184 178 179 183 189 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 08/31/2016 Next Release Date:

  9. Rhode Island Natural Gas Number of Industrial Consumers (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    Elements) Industrial Consumers (Number of Elements) Rhode Island Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 1,158 1,152 1,122 1990's 1,135 1,107 1,096 1,066 1,064 359 363 336 325 302 2000's 317 283 54 236 223 223 245 256 243 260 2010's 249 245 248 271 266 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release

  10. South Dakota Natural Gas Number of Industrial Consumers (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    Elements) Industrial Consumers (Number of Elements) South Dakota Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 261 267 270 1990's 275 283 319 355 381 396 444 481 464 445 2000's 416 402 533 526 475 542 528 548 598 598 2010's 580 556 574 566 575 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 08/31/2016

  11. Thermal Release of 3He from Tritium Aged LaNi4.25Al0.75 Hydride

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Staack, Gregory C.; Crowder, Mark L.; Klein, James E.

    2015-02-01

    Recently, the demand for He-3 has increased dramatically due to widespread use in nuclear nonproliferation, cryogenic, and medical applications. Essentially all of the world’s supply of He-3 is created by the radiolytic decay of tritium. The Savannah River Site Tritium Facilities (SRS-TF) utilizes LANA.75 in the tritium process to store hydrogen isotopes. The vast majority of He-3 “born” from tritium stored in LANA.75 is trapped in the hydride metal matrix. The SRS-TF has multiple LANA.75 tritium storage beds that have been retired from service with significant quantities of He-3 trapped in the metal. To support He-3 recovery, the Savannah Rivermore » National Laboratory (SRNL) conducted thermogravimetric analysis coupled with mass spectrometry (TGA-MS) on a tritium aged LANA.75 sample. TGA-MS testing was performed in an argon environment. Prior to testing, the sample was isotopically exchanged with deuterium to reduce residual tritium and passivated with air to alleviate pyrophoric concerns associated with handling the material outside of an inert glovebox. Analyses indicated that gas release from this sample was bimodal, with peaks near 220 and 490°C. The first peak consisted of both He-3 and residual hydrogen isotopes, the second was primarily He-3. The bulk of the gas was released by 600 °C« less

  12. The role of destabilization of palladium hydride on the hydrogen uptake of Pd-containing activated carbons

    SciTech Connect (OSTI)

    Bhat, Vinay V; Contescu, Cristian I; Gallego, Nidia C

    2009-01-01

    This paper reports on differences in stability of Pd hydride phases in palladium particles with various degrees of contact with microporous carbon supports. A sample containing Pd embedded in activated carbon fiber (Pd-ACF; 2 wt% Pd) was compared with commercial Pd nanoparticles deposited on microporous activated carbon (Pd-catalyst, 3 wt% Pd) and with support-free nanocrystalline palladium (Pd-black). The morphology of materials was characterized by electron microscopy, and the phase transformations were analyzed over a large range of hydrogen partial pressures (0.003 - 10 bar) and at several temperatures using in-situ X-ray diffraction. The results were verified with volumetric hydrogen uptake measurements. Results indicate that higher degree of Pd-carbon contacts for Pd particles embedded in a microporous carbon matrix induce efficient pumping of hydrogen out of -PdHx. It was also found that thermal cleaning of carbon surface groups prior to exposure to hydrogen further enhances the hydrogen pumping power of the microporous carbon support. In brief, this study highlights that the stability of -PdHx phase supported on carbon depends on the degree of contact between Pd-carbon and the nature of the carbon surface.

  13. Ar{sup +}-irradiation-induced damage in hydride vapor-phase epitaxy GaN films

    SciTech Connect (OSTI)

    Nakano, Yoshitaka Ogawa, Daisuke; Nakamura, Keiji; Kawakami, Retsuo; Niibe, Masahito

    2015-07-15

    The authors have investigated the electrical characteristics of hydride vapor-phase epitaxy GaN films exposed to Ar{sup +} irradiation, employing Schottky barrier diodes. The Ar{sup +} irradiation tends to largely increase the effective carrier concentration in the near surface region of GaN up to ∼25 nm, due to the generation of donor-type N vacancy defects, compared to the original value before the irradiation. More interestingly, acceptor-type deep-level defects are found to be formed at ∼2.1, ∼2.9, and ∼3.2 eV below the conduction band in the subsequently deeper region, in which Ga vacancies introduced by the Ar{sup +} irradiation are considered to be in-diffused and immediately combined with hydrogen. These N vacancies and hydrogenated Ga vacancies formed are dominantly responsible for changing the depth profiles of the effective carrier concentration via the carrier generation, the carrier trapping, and/or carrier compensation.

  14. Departmental Business Instrument Numbering System

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2005-01-27

    The Order prescribes the procedures for assigning identifying numbers to all Department of Energy (DOE) and National Nuclear Security Administration (NNSA) business instruments. Cancels DOE O 540.1. Canceled by DOE O 540.1B.

  15. Departmental Business Instrument Numbering System

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2000-12-05

    To prescribe procedures for assigning identifying numbers to all Department of Energy (DOE), including the National Nuclear Security Administration, business instruments. Cancels DOE 1331.2B. Canceled by DOE O 540.1A.

  16. Nebraska Natural Gas Number of Commercial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) Nebraska Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 60,707 61,365 60,377 1990's 60,405 60,947 61,319 60,599 62,045 61,275 61,117 51,661 63,819 53,943 2000's 55,194 55,692 56,560 55,999 57,087 57,389 56,548 55,761 58,160 56,454 2010's 56,246 56,553 56,608 58,005 57,191 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid

  17. Nebraska Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Nebraska Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 675 684 702 1990's 712 718 696 718 766 2,432 2,234 11,553 10,673 10,342 2000's 10,161 10,504 9,156 9,022 8,463 7,973 7,697 7,668 11,627 7,863 2010's 7,912 7,955 8,160 8,495 8,791 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company

  18. Nebraska Natural Gas Number of Residential Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) Nebraska Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 400,218 403,657 406,723 1990's 407,094 413,354 418,611 413,358 428,201 427,720 439,931 444,970 523,790 460,173 2000's 475,673 476,275 487,332 492,451 497,391 501,279 499,504 494,005 512,013 512,551 2010's 510,776 514,481 515,338 527,397 522,408 - = No Data Reported; -- = Not Applicable; NA = Not

  19. Nevada Natural Gas Number of Commercial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) Nevada Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 18,294 18,921 19,924 1990's 20,694 22,124 22,799 23,207 24,521 25,593 26,613 27,629 29,030 30,521 2000's 31,789 32,782 33,877 34,590 35,792 37,093 38,546 40,128 41,098 41,303 2010's 40,801 40,944 41,192 41,710 42,338 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid

  20. Nevada Natural Gas Number of Residential Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) Nevada Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 213,422 219,981 236,237 1990's 256,119 283,307 295,714 305,099 336,353 364,112 393,783 426,221 458,737 490,029 2000's 520,233 550,850 580,319 610,756 648,551 688,058 726,772 750,570 758,315 760,391 2010's 764,435 772,880 782,759 794,150 808,970 - = No Data Reported; -- = Not Applicable; NA = Not

  1. Ohio Natural Gas Number of Commercial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) Ohio Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 213,601 219,257 225,347 1990's 233,075 236,519 237,861 240,684 245,190 250,223 259,663 254,991 258,076 266,102 2000's 269,561 269,327 271,160 271,203 272,445 277,767 270,552 272,555 272,899 270,596 2010's 268,346 268,647 267,793 269,081 269,758 - = No Data Reported; -- = Not Applicable; NA = Not

  2. Ohio Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Ohio Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 7,929 8,163 8,356 1990's 8,301 8,479 8,573 8,678 8,655 8,650 8,672 7,779 8,112 8,136 2000's 8,267 8,515 8,111 8,098 7,899 8,328 6,929 6,858 6,806 6,712 2010's 6,571 6,482 6,381 6,554 6,526 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual

  3. Ohio Natural Gas Number of Residential Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) Ohio Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 2,648,972 2,678,838 2,714,839 1990's 2,766,912 2,801,716 2,826,713 2,867,959 2,921,536 2,967,375 2,994,891 3,041,948 3,050,960 3,111,108 2000's 3,178,840 3,195,584 3,208,466 3,225,908 3,250,068 3,272,307 3,263,062 3,273,791 3,262,716 3,253,184 2010's 3,240,619 3,236,160 3,244,274 3,271,074 3,283,869 -

  4. Oklahoma Natural Gas Number of Commercial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) Oklahoma Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 87,824 86,666 86,172 1990's 85,790 86,744 87,120 88,181 87,494 88,358 89,852 90,284 89,711 80,986 2000's 80,558 79,045 80,029 79,733 79,512 78,726 78,745 93,991 94,247 94,314 2010's 92,430 93,903 94,537 95,385 96,004 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid

  5. Oklahoma Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Oklahoma Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 2,772 2,689 2,877 1990's 2,889 2,840 2,859 2,912 2,853 2,845 2,843 2,531 3,295 3,040 2000's 2,821 3,403 3,438 3,367 3,283 2,855 2,811 2,822 2,920 2,618 2010's 2,731 2,733 2,872 2,958 3,063 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual

  6. Oklahoma Natural Gas Number of Residential Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) Oklahoma Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 809,171 805,107 806,875 1990's 814,296 824,172 832,677 842,130 845,448 856,604 866,531 872,454 877,236 867,922 2000's 859,951 868,314 875,338 876,420 875,271 880,403 879,589 920,616 923,650 924,745 2010's 914,869 922,240 927,346 931,981 937,237 - = No Data Reported; -- = Not Applicable; NA = Not

  7. Oregon Natural Gas Number of Commercial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) Oregon Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 40,967 41,998 43,997 1990's 47,175 55,374 50,251 51,910 53,700 55,409 57,613 60,419 63,085 65,034 2000's 66,893 68,098 69,150 74,515 71,762 73,520 74,683 80,998 76,868 76,893 2010's 77,370 77,822 78,237 79,276 80,480 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid

  8. Oregon Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Oregon Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 676 1,034 738 1990's 699 787 740 696 765 791 799 704 695 718 2000's 717 821 842 926 907 1,118 1,060 1,136 1,075 1,051 2010's 1,053 1,066 1,076 1,085 1,099 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 08/31/2016

  9. Oregon Natural Gas Number of Residential Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) Oregon Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 280,670 288,066 302,156 1990's 326,177 376,166 354,256 371,151 391,845 411,465 433,638 456,960 477,796 502,000 2000's 523,952 542,799 563,744 625,398 595,495 626,685 647,635 664,455 674,421 675,582 2010's 682,737 688,681 693,507 700,211 707,010 - = No Data Reported; -- = Not Applicable; NA = Not

  10. Pennsylvania Natural Gas Number of Commercial Consumers (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    Elements) Commercial Consumers (Number of Elements) Pennsylvania Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 166,901 172,615 178,545 1990's 186,772 191,103 193,863 198,299 206,812 209,245 214,340 215,057 216,519 223,732 2000's 228,037 225,911 226,957 227,708 231,051 233,132 231,540 234,597 233,462 233,334 2010's 233,751 233,588 235,049 237,922 239,681 - = No Data Reported; -- = Not

  11. Pennsylvania Natural Gas Number of Industrial Consumers (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    Elements) Industrial Consumers (Number of Elements) Pennsylvania Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 6,089 6,070 6,023 1990's 6,238 6,344 6,496 6,407 6,388 6,328 6,441 6,492 6,736 7,080 2000's 6,330 6,159 5,880 5,577 5,726 5,577 5,241 4,868 4,772 4,745 2010's 4,624 5,007 5,066 5,024 5,084 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid

  12. Pennsylvania Natural Gas Number of Residential Consumers (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    Elements) Residential Consumers (Number of Elements) Pennsylvania Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 2,237,877 2,271,801 2,291,242 1990's 2,311,795 2,333,377 2,363,575 2,386,249 2,393,053 2,413,715 2,431,909 2,452,524 2,493,639 2,486,704 2000's 2,519,794 2,542,724 2,559,024 2,572,584 2,591,458 2,600,574 2,605,782 2,620,755 2,631,340 2,635,886 2010's 2,646,211 2,667,392 2,678,547

  13. Alabama Natural Gas Number of Commercial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) Alabama Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 53 54,306 55,400 56,822 1990's 56,903 57,265 58,068 57,827 60,320 60,902 62,064 65,919 76,467 64,185 2000's 66,193 65,794 65,788 65,297 65,223 65,294 66,337 65,879 65,313 67,674 2010's 68,163 67,696 67,252 67,136 67,806 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to

  14. Alabama Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Alabama Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 2 2,313 2,293 2,380 1990's 2,431 2,523 2,509 2,458 2,477 2,491 2,512 2,496 2,464 2,620 2000's 2,792 2,781 2,730 2,743 2,799 2,787 2,735 2,704 2,757 3,057 2010's 3,039 2,988 3,045 3,143 3,244 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual

  15. Alabama Natural Gas Number of Residential Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) Alabama Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 656 662,217 668,432 683,528 1990's 686,149 700,195 711,043 730,114 744,394 751,890 766,322 781,711 788,464 775,311 2000's 805,689 807,770 806,389 809,754 806,660 809,454 808,801 796,476 792,236 785,005 2010's 778,985 772,892 767,396 765,957 769,418 - = No Data Reported; -- = Not Applicable; NA = Not

  16. Indiana Natural Gas Number of Commercial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) Indiana Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 116,571 119,458 122,803 1990's 124,919 128,223 129,973 131,925 134,336 137,162 139,097 140,515 141,307 145,631 2000's 148,411 148,830 150,092 151,586 151,943 159,649 154,322 155,885 157,223 155,615 2010's 156,557 161,293 158,213 158,965 159,596 - = No Data Reported; -- = Not Applicable; NA = Not

  17. Indiana Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Indiana Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 5,497 5,696 6,196 1990's 6,439 6,393 6,358 6,508 6,314 6,250 6,586 6,920 6,635 19,069 2000's 10,866 9,778 10,139 8,913 5,368 5,823 5,350 5,427 5,294 5,190 2010's 5,145 5,338 5,204 5,178 5,098 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual

  18. Indiana Natural Gas Number of Residential Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) Indiana Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 1,250,476 1,275,401 1,306,747 1990's 1,327,772 1,358,640 1,377,023 1,402,770 1,438,483 1,463,640 1,489,647 1,509,142 1,531,914 1,570,253 2000's 1,604,456 1,613,373 1,657,640 1,644,715 1,588,738 1,707,195 1,661,186 1,677,857 1,678,158 1,662,663 2010's 1,669,026 1,707,148 1,673,132 1,681,841 1,693,267

  19. Iowa Natural Gas Number of Commercial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) Iowa Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 80,797 81,294 82,549 1990's 83,047 84,387 85,325 86,452 86,918 88,585 89,663 90,643 91,300 92,306 2000's 93,836 95,485 96,496 96,712 97,274 97,767 97,823 97,979 98,144 98,416 2010's 98,396 98,541 99,113 99,017 99,182 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid

  20. Iowa Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Iowa Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 2,033 1,937 1,895 1990's 1,883 1,866 1,835 1,903 1,957 1,957 2,066 1,839 1,862 1,797 2000's 1,831 1,830 1,855 1,791 1,746 1,744 1,670 1,651 1,652 1,626 2010's 1,528 1,465 1,469 1,491 1,572 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual

  1. Iowa Natural Gas Number of Residential Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) Iowa Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 690,532 689,655 701,687 1990's 706,842 716,088 729,081 740,722 750,678 760,848 771,109 780,746 790,162 799,015 2000's 812,323 818,313 824,218 832,230 839,415 850,095 858,915 865,553 872,980 875,781 2010's 879,713 883,733 892,123 895,414 900,420 - = No Data Reported; -- = Not Applicable; NA = Not

  2. Kansas Natural Gas Number of Commercial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) Kansas Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 82,934 83,810 85,143 1990's 85,539 86,874 86,840 87,735 86,457 88,163 89,168 85,018 89,654 86,003 2000's 87,007 86,592 87,397 88,030 86,640 85,634 85,686 85,376 84,703 84,715 2010's 84,446 84,874 84,673 84,969 85,867 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid

  3. Kansas Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Kansas Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 4,440 4,314 4,366 1990's 4,357 3,445 3,296 4,369 3,560 3,079 2,988 7,014 10,706 5,861 2000's 8,833 9,341 9,891 9,295 8,955 8,300 8,152 8,327 8,098 7,793 2010's 7,664 7,954 7,970 7,877 7,429 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual

  4. Kansas Natural Gas Number of Residential Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) Kansas Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 725,676 733,101 731,792 1990's 747,081 753,839 762,545 777,658 773,357 797,524 804,213 811,975 841,843 824,803 2000's 833,662 836,486 843,353 850,464 855,272 856,761 862,203 858,304 853,125 855,454 2010's 853,842 854,730 854,800 858,572 861,092 - = No Data Reported; -- = Not Applicable; NA = Not

  5. Kentucky Natural Gas Number of Commercial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) Kentucky Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 63,024 63,971 65,041 1990's 67,086 68,461 69,466 71,998 73,562 74,521 76,079 77,693 80,147 80,283 2000's 81,588 81,795 82,757 84,110 84,493 85,243 85,236 85,210 84,985 83,862 2010's 84,707 84,977 85,129 85,999 85,318 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid

  6. Kentucky Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Kentucky Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 1,391 1,436 1,443 1990's 1,544 1,587 1,608 1,585 1,621 1,630 1,633 1,698 1,864 1,813 2000's 1,801 1,701 1,785 1,695 1,672 1,698 1,658 1,599 1,585 1,715 2010's 1,742 1,705 1,720 1,767 1,780 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual

  7. Kentucky Natural Gas Number of Residential Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) Kentucky Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 596,320 606,106 614,058 1990's 624,477 633,942 644,281 654,664 668,774 685,481 696,989 713,509 726,960 735,371 2000's 744,816 749,106 756,234 763,290 767,022 770,080 770,171 771,047 753,531 754,761 2010's 758,129 759,584 757,790 761,575 760,131 - = No Data Reported; -- = Not Applicable; NA = Not

  8. Louisiana Natural Gas Number of Commercial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) Louisiana Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 67,382 66,472 64,114 1990's 62,770 61,574 61,030 62,055 62,184 62,930 62,101 62,270 63,029 62,911 2000's 62,710 62,241 62,247 63,512 60,580 58,409 57,097 57,127 57,066 58,396 2010's 58,562 58,749 63,381 59,147 58,611 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to

  9. Louisiana Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Louisiana Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 1,617 1,503 1,531 1990's 1,504 1,469 1,452 1,592 1,737 1,383 1,444 1,406 1,380 1,397 2000's 1,318 1,440 1,357 1,291 1,460 1,086 962 945 988 954 2010's 942 920 963 916 883 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data.

  10. Louisiana Natural Gas Number of Residential Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) Louisiana Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 952,079 946,970 934,472 1990's 934,007 936,423 940,403 941,294 945,387 957,558 945,967 962,786 962,436 961,925 2000's 964,133 952,753 957,048 958,795 940,400 905,857 868,353 879,612 886,084 889,570 2010's 893,400 897,513 963,688 901,635 899,378 - = No Data Reported; -- = Not Applicable; NA = Not

  11. Maine Natural Gas Number of Commercial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) Maine Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 3,435 3,731 3,986 1990's 4,250 4,455 4,838 4,979 5,297 5,819 6,414 6,606 6,662 6,582 2000's 6,954 6,936 7,375 7,517 7,687 8,178 8,168 8,334 8,491 8,815 2010's 9,084 9,681 10,179 11,415 11,810 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual

  12. Maine Natural Gas Number of Residential Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) Maine Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 12,134 11,933 11,902 1990's 12,000 12,424 13,766 13,880 14,104 14,917 14,982 15,221 15,646 15,247 2000's 17,111 17,302 17,921 18,385 18,707 18,633 18,824 18,921 19,571 20,806 2010's 21,142 22,461 23,555 24,765 27,047 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid

  13. Maryland Natural Gas Number of Commercial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) Maryland Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 51,252 53,045 54,740 1990's 55,576 61,878 62,858 63,767 64,698 66,094 69,991 69,056 67,850 69,301 2000's 70,671 70,691 71,824 72,076 72,809 73,780 74,584 74,856 75,053 75,771 2010's 75,192 75,788 75,799 77,117 77,846 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid

  14. Maryland Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Maryland Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 5,222 5,397 5,570 1990's 5,646 520 514 496 516 481 430 479 1,472 536 2000's 329 795 1,434 1,361 1,354 1,325 1,340 1,333 1,225 1,234 2010's 1,255 1,226 1,163 1,173 1,179 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release

  15. Maryland Natural Gas Number of Residential Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) Maryland Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 755,294 760,754 767,219 1990's 774,707 782,373 894,677 807,204 824,137 841,772 871,012 890,195 901,455 939,029 2000's 941,384 959,772 978,319 987,863 1,009,455 1,024,955 1,040,941 1,053,948 1,057,521 1,067,807 2010's 1,071,566 1,077,168 1,078,978 1,099,272 1,101,292 - = No Data Reported; -- = Not

  16. Massachusetts Natural Gas Number of Commercial Consumers (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    Elements) Commercial Consumers (Number of Elements) Massachusetts Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 84,636 93,005 92,252 1990's 85,775 88,746 85,873 102,187 92,744 104,453 105,889 107,926 108,832 113,177 2000's 117,993 120,984 122,447 123,006 125,107 120,167 126,713 128,965 242,693 153,826 2010's 144,487 138,225 142,825 144,246 139,556 - = No Data Reported; -- = Not Applicable;

  17. Massachusetts Natural Gas Number of Industrial Consumers (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    Elements) Industrial Consumers (Number of Elements) Massachusetts Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 5,626 7,199 13,057 1990's 6,539 5,006 8,723 7,283 8,019 10,447 10,952 11,058 11,245 8,027 2000's 8,794 9,750 9,090 11,272 10,949 12,019 12,456 12,678 36,928 19,208 2010's 12,751 10,721 10,840 11,063 10,946 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld

  18. Massachusetts Natural Gas Number of Residential Consumers (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    Elements) Residential Consumers (Number of Elements) Massachusetts Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 1,082,777 1,100,635 1,114,920 1990's 1,118,429 1,127,536 1,137,911 1,155,443 1,179,869 1,180,860 1,188,317 1,204,494 1,212,486 1,232,887 2000's 1,278,781 1,283,008 1,295,952 1,324,715 1,306,142 1,297,508 1,348,848 1,361,470 1,236,480 1,370,353 2010's 1,389,592 1,408,314 1,447,947

  19. Michigan Natural Gas Number of Commercial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) Michigan Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 178,469 185,961 191,474 1990's 195,766 198,890 201,561 204,453 207,629 211,817 214,843 222,726 224,506 227,159 2000's 230,558 225,109 247,818 246,123 246,991 253,415 254,923 253,139 252,382 252,017 2010's 249,309 249,456 249,994 250,994 253,127 - = No Data Reported; -- = Not Applicable; NA = Not

  20. Michigan Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Michigan Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 10,885 11,117 11,452 1990's 11,500 11,446 11,460 11,425 11,308 11,454 11,848 12,233 11,888 14,527 2000's 11,384 11,210 10,468 10,378 10,088 10,049 9,885 9,728 10,563 18,186 2010's 9,332 9,088 8,833 8,497 8,156 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid

  1. Michigan Natural Gas Number of Residential Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) Michigan Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 2,452,554 2,491,149 2,531,304 1990's 2,573,570 2,609,561 2,640,579 2,677,085 2,717,683 2,767,190 2,812,876 2,859,483 2,903,698 2,949,628 2000's 2,999,737 3,011,205 3,110,743 3,140,021 3,161,370 3,187,583 3,193,920 3,188,152 3,172,623 3,169,026 2010's 3,152,468 3,153,895 3,161,033 3,180,349

  2. Minnesota Natural Gas Number of Commercial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) Minnesota Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 88,789 90,256 92,916 1990's 95,474 97,388 99,707 93,062 102,857 103,874 105,531 108,686 110,986 114,127 2000's 116,529 119,007 121,751 123,123 125,133 126,310 129,149 128,367 130,847 131,801 2010's 132,163 132,938 134,394 135,557 136,382 - = No Data Reported; -- = Not Applicable; NA = Not Available;

  3. Minnesota Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Minnesota Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 2,585 2,670 2,638 1990's 2,574 2,486 2,515 2,477 2,592 2,531 2,564 2,233 2,188 2,267 2000's 2,025 1,996 2,029 2,074 2,040 1,432 1,257 1,146 1,131 2,039 2010's 2,106 1,770 1,793 1,870 1,878 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual

  4. Minnesota Natural Gas Number of Residential Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) Minnesota Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 872,148 894,380 911,001 1990's 946,107 970,941 998,201 1,074,631 1,049,263 1,080,009 1,103,709 1,134,019 1,161,423 1,190,190 2000's 1,222,397 1,249,748 1,282,751 1,308,143 1,338,061 1,364,237 1,401,362 1,401,623 1,413,162 1,423,703 2010's 1,429,681 1,436,063 1,445,824 1,459,134 1,472,663 - = No

  5. Mississippi Natural Gas Number of Commercial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) Mississippi Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 43,362 44,170 44,253 1990's 43,184 43,693 44,313 45,310 43,803 45,444 46,029 47,311 45,345 47,620 2000's 50,913 51,109 50,468 50,928 54,027 54,936 55,741 56,155 55,291 50,713 2010's 50,537 50,636 50,689 50,153 50,238 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to

  6. Mississippi Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Mississippi Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 1,312 1,263 1,282 1990's 1,317 1,314 1,327 1,324 1,313 1,298 1,241 1,199 1,165 1,246 2000's 1,199 1,214 1,083 1,161 996 1,205 1,181 1,346 1,132 1,141 2010's 980 982 936 933 943 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company

  7. Mississippi Natural Gas Number of Residential Consumers (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    Elements) Residential Consumers (Number of Elements) Mississippi Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 370,094 372,238 376,353 1990's 382,251 386,264 392,155 398,472 405,312 415,123 418,442 423,397 415,673 426,352 2000's 434,501 438,069 435,146 438,861 445,212 445,856 437,669 445,043 443,025 437,715 2010's 436,840 442,479 442,840 445,589 444,423 - = No Data Reported; -- = Not

  8. Missouri Natural Gas Number of Commercial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) Missouri Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 96,711 97,939 99,721 1990's 105,164 117,675 125,174 125,571 132,378 130,318 133,445 135,553 135,417 133,464 2000's 133,969 135,968 137,924 140,057 141,258 142,148 143,632 142,965 141,529 140,633 2010's 138,670 138,214 144,906 142,495 143,024 - = No Data Reported; -- = Not Applicable; NA = Not

  9. Missouri Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Missouri Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 2,832 2,880 3,063 1990's 3,140 3,096 2,989 3,040 3,115 3,033 3,408 3,097 3,151 3,152 2000's 3,094 3,085 2,935 3,115 3,600 3,545 3,548 3,511 3,514 3,573 2010's 3,541 3,307 3,692 3,538 3,497 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual

  10. Missouri Natural Gas Number of Residential Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) Missouri Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 1,180,546 1,194,985 1,208,523 1990's 1,213,305 1,211,342 1,220,203 1,225,921 1,281,007 1,259,102 1,275,465 1,293,032 1,307,563 1,311,865 2000's 1,324,282 1,326,160 1,340,726 1,343,614 1,346,773 1,348,743 1,353,892 1,354,173 1,352,015 1,348,781 2010's 1,348,549 1,342,920 1,389,910 1,357,740

  11. Montana Natural Gas Number of Commercial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) Montana Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 21,382 22,246 22,219 1990's 23,331 23,185 23,610 24,373 25,349 26,329 26,374 27,457 28,065 28,424 2000's 29,215 29,429 30,250 30,814 31,357 31,304 31,817 32,472 33,008 33,731 2010's 34,002 34,305 34,504 34,909 35,205 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid

  12. Montana Natural Gas Number of Residential Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) Montana Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 167,883 171,785 171,156 1990's 174,384 177,726 182,641 188,879 194,357 203,435 205,199 209,806 218,851 222,114 2000's 224,784 226,171 229,015 232,839 236,511 240,554 245,883 247,035 253,122 255,472 2010's 257,322 259,046 259,957 262,122 265,849 - = No Data Reported; -- = Not Applicable; NA = Not

  13. Wyoming Natural Gas Number of Commercial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) Wyoming Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 15,342 15,093 14,012 1990's 13,767 14,931 15,064 15,315 15,348 15,580 17,036 15,907 16,171 16,317 2000's 16,366 16,027 16,170 17,164 17,490 17,904 18,016 18,062 19,286 19,843 2010's 19,977 20,146 20,387 20,617 20,894 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid

  14. Wyoming Natural Gas Number of Residential Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) Wyoming Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 113,175 112,126 113,129 1990's 113,598 113,463 114,793 116,027 117,385 119,544 131,910 125,740 127,324 127,750 2000's 129,274 129,897 133,445 135,441 137,434 140,013 142,385 143,644 152,439 153,062 2010's 153,852 155,181 157,226 158,889 160,896 - = No Data Reported; -- = Not Applicable; NA = Not

  15. Alaska Natural Gas Number of Commercial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) Alaska Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 11 11,484 11,649 11,806 1990's 11,921 12,071 12,204 12,359 12,475 12,584 12,732 12,945 13,176 13,409 2000's 13,711 14,002 14,342 14,502 13,999 14,120 14,384 13,408 12,764 13,215 2010's 12,998 13,027 13,133 13,246 13,399 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to

  16. Alaska Natural Gas Number of Residential Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) Alaska Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 66 67,648 68,612 69,540 1990's 70,808 72,565 74,268 75,842 77,670 79,474 81,348 83,596 86,243 88,924 2000's 91,297 93,896 97,077 100,404 104,360 108,401 112,269 115,500 119,039 120,124 2010's 121,166 121,736 122,983 124,411 126,416 - = No Data Reported; -- = Not Applicable; NA = Not Available; W =

  17. Arizona Natural Gas Number of Commercial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) Arizona Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 46 46,702 46,636 46,776 1990's 47,292 53,982 47,781 47,678 48,568 49,145 49,693 50,115 51,712 53,022 2000's 54,056 54,724 56,260 56,082 56,186 56,572 57,091 57,169 57,586 57,191 2010's 56,676 56,547 56,532 56,585 56,649 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to

  18. Arizona Natural Gas Number of Residential Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) Arizona Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 545 567,962 564,195 572,461 1990's 586,866 642,659 604,899 610,337 635,335 661,192 689,597 724,911 764,167 802,469 2000's 846,016 884,789 925,927 957,442 993,885 1,042,662 1,088,574 1,119,266 1,128,264 1,130,047 2010's 1,138,448 1,146,286 1,157,688 1,172,003 1,186,794 - = No Data Reported; -- = Not

  19. Arkansas Natural Gas Number of Commercial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) Arkansas Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 60 60,355 61,630 61,848 1990's 61,530 61,731 62,221 62,952 63,821 65,490 67,293 68,413 69,974 71,389 2000's 72,933 71,875 71,530 71,016 70,655 69,990 69,475 69,495 69,144 69,043 2010's 67,987 67,815 68,765 68,791 69,011 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to

  20. Arkansas Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Arkansas Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 1 1,410 1,151 1,412 1990's 1,396 1,367 1,319 1,364 1,417 1,366 1,488 1,336 1,300 1,393 2000's 1,414 1,122 1,407 1,269 1,223 1,120 1,120 1,055 1,104 1,025 2010's 1,079 1,133 990 1,020 1,009 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual

  1. Arkansas Natural Gas Number of Residential Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) Arkansas Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 475 480,839 485,112 491,110 1990's 488,850 495,148 504,722 513,466 521,176 531,182 539,952 544,460 550,017 554,121 2000's 560,055 552,716 553,192 553,211 554,844 555,861 555,905 557,966 556,746 557,355 2010's 549,970 551,795 549,959 549,764 549,034 - = No Data Reported; -- = Not Applicable; NA =

  2. California Natural Gas Number of Commercial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) California Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 413 404,507 407,435 410,231 1990's 415,073 421,278 412,467 411,648 411,140 411,535 408,294 406,803 588,224 416,791 2000's 413,003 416,036 420,690 431,795 432,367 434,899 442,052 446,267 447,160 441,806 2010's 439,572 440,990 442,708 444,342 443,115 - = No Data Reported; -- = Not Applicable; NA =

  3. California Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) California Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 31 44,764 44,680 46,243 1990's 46,048 44,865 40,528 42,748 38,750 38,457 36,613 35,830 36,235 36,435 2000's 35,391 34,893 33,725 34,617 41,487 40,226 38,637 39,134 39,591 38,746 2010's 38,006 37,575 37,686 37,996 37,548 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to

  4. California Natural Gas Number of Residential Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) California Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 7,626 7,904,858 8,113,034 8,313,776 1990's 8,497,848 8,634,774 8,680,613 8,726,187 8,790,733 8,865,541 8,969,308 9,060,473 9,181,928 9,331,206 2000's 9,370,797 9,603,122 9,726,642 9,803,311 9,957,412 10,124,433 10,329,224 10,439,220 10,515,162 10,510,950 2010's 10,542,584 10,625,190 10,681,916

  5. Colorado Natural Gas Number of Commercial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) Colorado Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 108 109,770 110,769 112,004 1990's 112,661 113,945 114,898 115,924 115,994 118,502 121,221 123,580 125,178 129,041 2000's 131,613 134,393 136,489 138,621 138,543 137,513 139,746 141,420 144,719 145,624 2010's 145,460 145,837 145,960 150,145 150,235 - = No Data Reported; -- = Not Applicable; NA = Not

  6. Colorado Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Colorado Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 1 896 923 976 1990's 1,018 1,074 1,108 1,032 1,176 1,528 2,099 2,923 3,349 4,727 2000's 4,994 4,729 4,337 4,054 4,175 4,318 4,472 4,592 4,816 5,084 2010's 6,232 6,529 6,906 7,293 7,823 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual

  7. Colorado Natural Gas Number of Residential Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) Colorado Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 925 942,571 955,810 970,512 1990's 983,592 1,002,154 1,022,542 1,044,699 1,073,308 1,108,899 1,147,743 1,183,978 1,223,433 1,265,032 2000's 1,315,619 1,365,413 1,412,923 1,453,974 1,496,876 1,524,813 1,558,911 1,583,945 1,606,602 1,622,434 2010's 1,634,587 1,645,716 1,659,808 1,672,312 1,690,581 -

  8. Connecticut Natural Gas Number of Commercial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) Connecticut Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 38 40,886 41,594 43,703 1990's 45,364 45,925 46,859 45,529 45,042 45,935 47,055 48,195 47,110 49,930 2000's 52,384 49,815 49,383 50,691 50,839 52,572 52,982 52,389 53,903 54,510 2010's 54,842 55,028 55,407 55,500 56,591 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to

  9. Connecticut Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Connecticut Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 2 2,709 2,818 2,908 1990's 3,061 2,921 2,923 2,952 3,754 3,705 3,435 3,459 3,441 3,465 2000's 3,683 3,881 3,716 3,625 3,470 3,437 3,393 3,317 3,196 3,138 2010's 3,063 3,062 3,148 4,454 4,217 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of

  10. Connecticut Natural Gas Number of Residential Consumers (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    Elements) Residential Consumers (Number of Elements) Connecticut Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 400 411,349 417,831 424,036 1990's 428,912 430,078 432,244 427,761 428,157 431,909 433,778 436,119 438,716 442,457 2000's 458,388 458,404 462,574 466,913 469,332 475,221 478,849 482,902 487,320 489,349 2010's 490,185 494,970 504,138 513,492 522,658 - = No Data Reported; -- = Not

  11. Delaware Natural Gas Number of Commercial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) Delaware Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 6 6,180 6,566 7,074 1990's 7,485 7,895 8,173 8,409 8,721 9,133 9,518 9,807 10,081 10,441 2000's 9,639 11,075 11,463 11,682 11,921 12,070 12,345 12,576 12,703 12,839 2010's 12,861 12,931 12,997 13,163 13,352 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid

  12. Delaware Natural Gas Number of Residential Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) Delaware Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 81 82,829 84,328 86,428 1990's 88,894 91,467 94,027 96,914 100,431 103,531 106,548 109,400 112,507 115,961 2000's 117,845 122,829 126,418 129,870 133,197 137,115 141,276 145,010 147,541 149,006 2010's 150,458 152,005 153,307 155,627 158,502 - = No Data Reported; -- = Not Applicable; NA = Not

  13. Florida Natural Gas Number of Commercial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) Florida Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 41 42,376 43,178 43,802 1990's 43,674 45,012 45,123 47,344 47,851 46,459 47,578 48,251 46,778 50,052 2000's 50,888 53,118 53,794 55,121 55,324 55,479 55,259 57,320 58,125 59,549 2010's 60,854 61,582 63,477 64,772 67,460 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to

  14. Florida Natural Gas Number of Residential Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) Florida Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 442 444,848 446,690 452,544 1990's 457,648 467,221 471,863 484,816 497,777 512,365 521,674 532,790 542,770 556,628 2000's 571,972 590,221 603,690 617,373 639,014 656,069 673,122 682,996 679,265 674,090 2010's 675,551 679,199 686,994 694,210 703,535 - = No Data Reported; -- = Not Applicable; NA = Not

  15. Georgia Natural Gas Number of Commercial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) Georgia Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 94 98,809 102,277 106,690 1990's 108,295 109,659 111,423 114,889 117,980 120,122 123,200 123,367 126,050 225,020 2000's 128,275 130,373 128,233 129,867 128,923 128,389 127,843 127,832 126,804 127,347 2010's 124,759 123,454 121,243 126,060 122,573 - = No Data Reported; -- = Not Applicable; NA = Not

  16. Georgia Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Georgia Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 3 3,034 3,144 3,079 1990's 3,153 3,124 3,186 3,302 3,277 3,261 3,310 3,310 3,262 5,580 2000's 3,294 3,330 3,219 3,326 3,161 3,543 3,053 2,913 2,890 2,254 2010's 2,174 2,184 2,112 2,242 2,481 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual

  17. Georgia Natural Gas Number of Residential Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) Georgia Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 1,190 1,237,201 1,275,128 1,308,972 1990's 1,334,935 1,363,723 1,396,860 1,430,626 1,460,141 1,495,992 1,538,458 1,553,948 1,659,730 1,732,865 2000's 1,680,749 1,737,850 1,735,063 1,747,017 1,752,346 1,773,121 1,726,239 1,793,650 1,791,256 1,744,934 2010's 1,740,587 1,740,006 1,739,543 1,805,425

  18. Hawaii Natural Gas Number of Commercial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) Hawaii Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 2,896 2,852 2,842 1990's 2,837 2,786 2,793 3,222 2,805 2,825 2,823 2,783 2,761 2,763 2000's 2,768 2,777 2,781 2,804 2,578 2,572 2,548 2,547 2,540 2,535 2010's 2,551 2,560 2,545 2,627 2,789 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual

  19. Hawaii Natural Gas Number of Residential Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) Hawaii Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 28,502 28,761 28,970 1990's 29,137 29,701 29,805 29,984 30,614 30,492 31,017 30,990 30,918 30,708 2000's 30,751 30,794 30,731 30,473 26,255 26,219 25,982 25,899 25,632 25,466 2010's 25,389 25,305 25,184 26,374 28,919 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid

  20. Idaho Natural Gas Number of Commercial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) Idaho Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 17,482 18,454 18,813 1990's 19,452 20,328 21,145 21,989 22,999 24,150 25,271 26,436 27,697 28,923 2000's 30,018 30,789 31,547 32,274 33,104 33,362 33,625 33,767 37,320 38,245 2010's 38,506 38,912 39,202 39,722 40,229 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid

  1. Idaho Natural Gas Number of Residential Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) Idaho Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 104,824 111,532 113,898 1990's 113,954 126,282 136,121 148,582 162,971 175,320 187,756 200,165 213,786 227,807 2000's 240,399 251,004 261,219 274,481 288,380 301,357 316,915 323,114 336,191 342,277 2010's 346,602 350,871 353,963 359,889 367,394 - = No Data Reported; -- = Not Applicable; NA = Not

  2. Illinois Natural Gas Number of Commercial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) Illinois Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 241,367 278,473 252,791 1990's 257,851 261,107 263,988 268,104 262,308 264,756 265,007 268,841 271,585 274,919 2000's 279,179 278,506 279,838 281,877 273,967 276,763 300,606 296,465 298,418 294,226 2010's 291,395 293,213 297,523 282,743 294,391 - = No Data Reported; -- = Not Applicable; NA = Not

  3. Illinois Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Illinois Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 19,460 20,015 25,161 1990's 25,991 26,489 27,178 27,807 25,788 25,929 29,493 28,472 28,063 27,605 2000's 27,348 27,421 27,477 26,698 29,187 29,887 26,109 24,000 23,737 23,857 2010's 25,043 23,722 23,390 23,804 23,829 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid

  4. Illinois Natural Gas Number of Residential Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) Illinois Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 3,170,364 3,180,199 3,248,117 1990's 3,287,091 3,320,285 3,354,679 3,388,983 3,418,052 3,452,975 3,494,545 3,521,707 3,556,736 3,594,071 2000's 3,631,762 3,670,693 3,688,281 3,702,308 3,754,132 3,975,961 3,812,121 3,845,441 3,869,308 3,839,438 2010's 3,842,206 3,855,942 3,878,806 3,838,120

  5. Rhode Island Natural Gas Number of Commercial Consumers (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    Elements) Commercial Consumers (Number of Elements) Rhode Island Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 15,128 16,096 16,924 1990's 17,765 18,430 18,607 21,178 21,208 21,472 21,664 21,862 22,136 22,254 2000's 22,592 22,815 23,364 23,270 22,994 23,082 23,150 23,007 23,010 22,988 2010's 23,049 23,177 23,359 23,742 23,934 - = No Data Reported; -- = Not Applicable; NA = Not Available; W =

  6. Rhode Island Natural Gas Number of Residential Consumers (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    Elements) Residential Consumers (Number of Elements) Rhode Island Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 180,656 185,861 190,796 1990's 195,100 196,438 197,926 198,563 200,959 202,947 204,259 212,777 208,208 211,097 2000's 214,474 216,781 219,769 221,141 223,669 224,320 225,027 223,589 224,103 224,846 2010's 225,204 225,828 228,487 231,763 233,786 - = No Data Reported; -- = Not

  7. South Carolina Natural Gas Number of Commercial Consumers (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    Elements) Commercial Consumers (Number of Elements) South Carolina Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 35,414 37,075 38,856 1990's 39,904 39,999 40,968 42,191 45,487 47,293 48,650 50,817 52,237 53,436 2000's 54,794 55,257 55,608 55,909 56,049 56,974 57,452 57,544 56,317 55,850 2010's 55,853 55,846 55,908 55,997 56,172 - = No Data Reported; -- = Not Applicable; NA = Not Available; W

  8. South Carolina Natural Gas Number of Industrial Consumers (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    Elements) Industrial Consumers (Number of Elements) South Carolina Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 1,256 1,273 1,307 1990's 1,384 1,400 1,568 1,625 1,928 1,802 1,759 1,764 1,728 1,768 2000's 1,715 1,702 1,563 1,574 1,528 1,535 1,528 1,472 1,426 1,358 2010's 1,325 1,329 1,435 1,452 1,426 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid

  9. South Carolina Natural Gas Number of Residential Consumers (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    Elements) Residential Consumers (Number of Elements) South Carolina Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 302,321 313,831 327,527 1990's 339,486 344,763 357,818 370,411 416,773 412,259 426,088 443,093 460,141 473,799 2000's 489,340 501,161 508,686 516,362 527,008 541,523 554,953 570,213 561,196 565,774 2010's 570,797 576,594 583,633 593,286 604,743 - = No Data Reported; -- = Not

  10. South Dakota Natural Gas Number of Commercial Consumers (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    Elements) Commercial Consumers (Number of Elements) South Dakota Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 12,480 12,438 12,771 1990's 13,443 13,692 14,133 16,523 15,539 16,285 16,880 17,432 17,972 18,453 2000's 19,100 19,378 19,794 20,070 20,457 20,771 21,149 21,502 21,819 22,071 2010's 22,267 22,570 22,955 23,214 23,591 - = No Data Reported; -- = Not Applicable; NA = Not Available; W =

  11. South Dakota Natural Gas Number of Residential Consumers (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    Elements) Residential Consumers (Number of Elements) South Dakota Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 101,468 102,084 103,538 1990's 105,436 107,846 110,291 128,029 119,544 124,152 127,269 130,307 133,095 136,789 2000's 142,075 144,310 147,356 150,725 148,105 157,457 160,481 163,458 165,694 168,096 2010's 169,838 170,877 173,856 176,204 179,042 - = No Data Reported; -- = Not

  12. Tennessee Natural Gas Number of Commercial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) Tennessee Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 77,104 81,159 84,040 1990's 88,753 89,863 91,999 94,860 97,943 101,561 103,867 105,925 109,772 112,978 2000's 115,691 118,561 120,130 131,916 125,042 124,755 126,970 126,324 128,007 127,704 2010's 127,914 128,969 130,139 131,091 131,001 - = No Data Reported; -- = Not Applicable; NA = Not Available;

  13. Tennessee Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Tennessee Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 2,206 2,151 2,555 1990's 2,361 2,369 2,425 2,512 2,440 2,393 2,306 2,382 5,149 2,159 2000's 2,386 2,704 2,657 2,755 2,738 2,498 2,545 2,656 2,650 2,717 2010's 2,702 2,729 2,679 2,581 2,595 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual

  14. Tennessee Natural Gas Number of Residential Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) Tennessee Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 534,882 565,856 599,042 1990's 627,031 661,105 696,140 733,363 768,421 804,724 841,232 867,793 905,757 937,896 2000's 969,537 993,363 1,009,225 1,022,628 1,037,429 1,049,307 1,063,328 1,071,756 1,084,102 1,083,573 2010's 1,085,387 1,089,009 1,084,726 1,094,122 1,106,681 - = No Data Reported; -- =

  15. Texas Natural Gas Number of Commercial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) Texas Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 294,879 284,013 270,227 1990's 268,181 269,411 292,990 297,516 306,376 325,785 329,287 332,077 320,922 314,598 2000's 315,906 314,858 317,446 320,786 322,242 322,999 329,918 326,812 324,671 313,384 2010's 312,277 314,041 314,811 314,036 317,217 - = No Data Reported; -- = Not Applicable; NA = Not

  16. Texas Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) Texas Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 4,852 4,427 13,383 1990's 13,659 13,770 5,481 5,823 5,222 9,043 8,796 5,339 5,318 5,655 2000's 11,613 10,047 9,143 9,015 9,359 9,136 8,664 11,063 5,568 8,581 2010's 8,779 8,713 8,953 8,525 8,406 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual

  17. Texas Natural Gas Number of Residential Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) Texas Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 3,155,948 3,166,168 3,201,316 1990's 3,232,849 3,274,482 3,285,025 3,346,809 3,350,314 3,446,120 3,501,853 3,543,027 3,600,505 3,613,864 2000's 3,704,501 3,738,260 3,809,370 3,859,647 3,939,101 3,984,481 4,067,508 4,156,991 4,205,412 4,248,613 2010's 4,288,495 4,326,156 4,370,057 4,424,103 4,469,282 -

  18. Metal hydride differential scanning calorimetry as an approach to compositional determination of mixtures of hydrogen isotopologues and helium

    SciTech Connect (OSTI)

    Robinson, David B.; Luo, Weifang; Cai, Trevor Y.; Stewart, Kenneth D.

    2015-09-26

    Gaseous mixtures of diatomic hydrogen isotopologues and helium are often encountered in the nuclear energy industry and in analytical chemistry. Compositions of stored mixtures can vary due to interactions with storage and handling materials. When tritium is present, it decays to form ions and helium-3, both of which can lead to further compositional variation. Monitoring of composition is typically achieved by mass spectrometry, a method that is bulky and energy-intensive. Mass spectrometers disperse sample material through vacuum pumps, which is especially troublesome if tritium is present. Moreover, our ultimate goal is to create a compact, fast, low-power sensor that can determine composition with minimal gas consumption and waste generation, as a complement to mass spectrometry that can be instantiated more widely. We propose calorimetry of metal hydrides as an approach to this, due to the strong isotope effect on gas absorption, and demonstrate the sensitivity of measured heat flow to atomic composition of the gas. Peak shifts are discernible when mole fractions change by at least 1%. A mass flow restriction results in a unique dependence of the measurement on helium concentration. We present a mathematical model as a first step toward prediction of the peak shapes and positions. The model includes a useful method to compute estimates of phase diagrams for palladium in the presence of arbitrary mixtures of hydrogen isotopologues. As a result, we expect that this approach can be used to deduce unknown atomic compositions from measured calorimetric data over a useful range of partial pressures of each component.

  19. Metal hydride differential scanning calorimetry as an approach to compositional determination of mixtures of hydrogen isotopologues and helium

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Robinson, David B.; Luo, Weifang; Cai, Trevor Y.; Stewart, Kenneth D.

    2015-09-26

    Gaseous mixtures of diatomic hydrogen isotopologues and helium are often encountered in the nuclear energy industry and in analytical chemistry. Compositions of stored mixtures can vary due to interactions with storage and handling materials. When tritium is present, it decays to form ions and helium-3, both of which can lead to further compositional variation. Monitoring of composition is typically achieved by mass spectrometry, a method that is bulky and energy-intensive. Mass spectrometers disperse sample material through vacuum pumps, which is especially troublesome if tritium is present. Moreover, our ultimate goal is to create a compact, fast, low-power sensor that canmore » determine composition with minimal gas consumption and waste generation, as a complement to mass spectrometry that can be instantiated more widely. We propose calorimetry of metal hydrides as an approach to this, due to the strong isotope effect on gas absorption, and demonstrate the sensitivity of measured heat flow to atomic composition of the gas. Peak shifts are discernible when mole fractions change by at least 1%. A mass flow restriction results in a unique dependence of the measurement on helium concentration. We present a mathematical model as a first step toward prediction of the peak shapes and positions. The model includes a useful method to compute estimates of phase diagrams for palladium in the presence of arbitrary mixtures of hydrogen isotopologues. As a result, we expect that this approach can be used to deduce unknown atomic compositions from measured calorimetric data over a useful range of partial pressures of each component.« less

  20. Final Report for DOE Project Number: DE-FG02-05ER46241

    SciTech Connect (OSTI)

    Gang Chen; Mildred S. Dresselhaus; Costas P. Grigoropoulos; Samuel S. Mao; Xiaodong Xiang; Taofang Zeng

    2010-03-15

    Hydrogen storage is the most challenging task for the hydrogen economy. We established a multidisciplinary research program for high throughput combinatorial synthesis and characterization of novel nanoporous and metastable complex hydrides, coupled to fundamental material studies including electronic, structural and kinetic transport modeling, and pump-probe experiments. Our research is based the concept of hybrid nanostructures that store hydrogen by a combination of chemi- and physorption: atomic hydrogen is stored in metastable hydrides while molecule hydrogen is stored in the nanometer pores of the hydrides. Metastable nanostructured hydride has been achieved by introducing structural and compositional disorders through high throughput elemental substitution/doping, catalyst addition, and nonequilibrium processing. Fast screening compatible with the combinatorial synthesis was achieved by combining X-ray structural characterization with the development of a laser-based microbalance. Manufacturing of nanoporous metahydrides that are identified as promising by the combinatorial synthesis has been explored along with the materials search.

  1. Highly chemoselective palladium-catalyzed conjugate reduction of. cap alpha. ,. beta. -unsaturated carbonyl compounds with silicon hydrides and zinc chloride cocatalyst

    SciTech Connect (OSTI)

    Keinan, E.; Greenspoon, N.

    1986-11-12

    A three-component system comprised of a soluble palladium catalyst, hydridosilane, and zinc chloride is capable of efficient conjugate reduction of ..cap alpha..,..beta..-unsaturated ketones and aldehydes. The optimal set of conditions includes diphenylsilane as the most effective hydride donor, any soluble palladium complex in either the O or II oxidation state, when it is stabilized by phosphine ligands, and ZnCl/sub 2/ as the best Lewis acid cocatalyst. The reaction is very general with respect to a broad range of unsaturated ketones and aldehydes, and it is highly selective for these Michael acceptors, as reduction of ..cap alpha..,..beta..-unsaturated carboxylic acid derivatives is very sluggish under these conditions. When dideuteriodiphenylsilane is used to reduce unsaturated ketones, deuterium is stereoselectivity introduced at the less-hindered fact of the substrate and regioselectively at the ..beta..-position. Conversely, when reductions are carried out in the presence of traces of D/sub 2/O, deuterium incorporation occurs at the ..cap alpha..-position. On the basis of deuterium-incorporation experiments and /sup 1/H NMR studies a catalytic cycle is postulated in which the first step involves reversible coordination of the palladium complex to the electron-deficient olefin and oxidative addition of silicon hydride to form a hydridopalladium olefin complex.

  2. Electrochemical Oxidation of H? Catalyzed by Ruthenium Hydride Complexes Bearing P?N? Ligands With Pendant Amines as Proton Relays

    SciTech Connect (OSTI)

    Liu, Tianbiao L.; Rakowski DuBois, Mary; DuBois, Daniel L.; Bullock, R. Morris

    2014-01-01

    Two Ru hydride complexes (Cp*Ru(PPh?NBn?)H, (1-H) and Cp*Ru(PtBu?NBn?)H, (2-H) supported by cyclic PR?NR'? ligands (Cp* = n?-C?Me?; 1,5-diaza-3,7-diphosphacyclooctane, where R = Ph or tBu and R' = Bn) have been synthesized and fully characterized. Both complexes are demonstrated to be electrocatalysts for oxidation of H? (1 atm, 22 C) in the presence of external base, DBU (1,8-diazabicyclo[5.4.0]undec-7-ene). The turnover frequency of 2-H is 1.2 s-1, with an overpotential at Ecat/2 of 0.45 V, while catalysis by 1-H has a turnover frequency of 0.6 s-1 and an overpotential of 0.6 V at Ecat/2. Addition of H?O facilitates oxidation of H? by 2-H and increases its turnover frequency to 1.9 s-1 while , H?O slows down the catalysis by 1-H. The different effects of H?O for 1-H and 2-H are ascribed to different binding affinities of H?O to the Ru center of the corresponding unsaturated species, [Cp*Ru(PPh?NBn?)]+ and [Cp*Ru(PPh?NBn?)]+. In addition, studies of Cp*Ru(dmpm)H (where dmpm = bis(dimethylphosphino)methane), a control complex lacking pendent amines in its diphosphine ligand, confirms the critical roles of the pendent amines of P?N? ligands for oxidation of H?. We thank the U.S. Department of Energy, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences and Biosciences, for supporting initial parts of the work. Current work is supported by the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences. Pacific Northwest National Laboratory is operated by Battelle for the U.S. Department of Energy.

  3. Verification Challenges at Low Numbers

    SciTech Connect (OSTI)

    Benz, Jacob M.; Booker, Paul M.; McDonald, Benjamin S.

    2013-06-01

    Many papers have dealt with the political difficulties and ramifications of deep nuclear arms reductions, and the issues of “Going to Zero”. Political issues include extended deterrence, conventional weapons, ballistic missile defense, and regional and geo-political security issues. At each step on the road to low numbers, the verification required to ensure compliance of all parties will increase significantly. Looking post New START, the next step will likely include warhead limits in the neighborhood of 1000 . Further reductions will include stepping stones at1000 warheads, 100’s of warheads, and then 10’s of warheads before final elimination could be considered of the last few remaining warheads and weapons. This paper will focus on these three threshold reduction levels, 1000, 100’s, 10’s. For each, the issues and challenges will be discussed, potential solutions will be identified, and the verification technologies and chain of custody measures that address these solutions will be surveyed. It is important to note that many of the issues that need to be addressed have no current solution. In these cases, the paper will explore new or novel technologies that could be applied. These technologies will draw from the research and development that is ongoing throughout the national laboratory complex, and will look at technologies utilized in other areas of industry for their application to arms control verification.

  4. Hybrid Vehicle Comparison Testing Using Ultracapacitor vs. Battery Energy Storage (Presentation)

    SciTech Connect (OSTI)

    Gonder, J.; Pesaran, A.; Lustbader, J.; Tataria, H.

    2010-02-01

    With support from General Motors, NREL researchers converted and tested a hybrid electric vehicle (HEV) with three energy storage configurations: a nickel metal-hydride battery and two ultracapacitor (Ucap) modules. They found that the HEV equipped with one Ucap module performed as well as or better than the HEV with a stock NiMH battery configuration. Thus, Ucaps could increase the market penetration and fuel savings of HEVs.

  5. PNNL Chemical Hydride Capabilities

    Broader source: Energy.gov [DOE]

    Presentation from the Hydrogen Storage Pre-Solicitation Meeting held June 19, 2003 in Washington, DC.

  6. Regeneration of aluminum hydride

    DOE Patents [OSTI]

    Graetz, Jason Allan; Reilly, James J.

    2009-04-21

    The present invention provides methods and materials for the formation of hydrogen storage alanes, AlH.sub.x, where x is greater than 0 and less than or equal to 6 at reduced H.sub.2 pressures and temperatures. The methods rely upon reduction of the change in free energy of the reaction between aluminum and molecular H.sub.2. The change in free energy is reduced by lowering the entropy change during the reaction by providing aluminum in a state of high entropy, by increasing the magnitude of the change in enthalpy of the reaction or combinations thereof.

  7. Regeneration of aluminum hydride

    DOE Patents [OSTI]

    Graetz, Jason Allan; Reilly, James J; Wegrzyn, James E

    2012-09-18

    The present invention provides methods and materials for the formation of hydrogen storage alanes, AlH.sub.x, where x is greater than 0 and less than or equal to 6 at reduced H.sub.2 pressures and temperatures. The methods rely upon reduction of the change in free energy of the reaction between aluminum and molecular H.sub.2. The change in free energy is reduced by lowering the entropy change during the reaction by providing aluminum in a state of high entropy, and by increasing the magnitude of the change in enthalpy of the reaction or combinations thereof.

  8. Metal Hydrides- Science Needs

    Broader source: Energy.gov [DOE]

    Presentation from the Hydrogen Storage Pre-Solicitation Meeting held June 19, 2003 in Washington, DC.

  9. Molybdenum Hydride and Dihydride Complexes Bearing Diphosphine Ligands with a Pendant Amine: Formation of Complexes With Bound Amines

    SciTech Connect (OSTI)

    Zhang, Shaoguang; Bullock, R. Morris

    2015-07-06

    CpMo(CO)(PNP)H complexes (PNP = (R2PCH2)2NMe, R = Et or Ph) were synthesized by displacement of two CO ligands of CpMo(CO)3H by the PNP ligand; these complexes were characterized by IR and variable temperature 1H and 31P NMR spectroscopy. CpMo(CO)(PNP)H complexes are formed as mixture of cis and trans-isomers. Both cis-CpMo(CO)(PEtNMePEt)H and trans-CpMo(CO)(PPhNMePPh)H were analyzed by single crystal X-ray diffraction. Electrochemical oxidation of CpMo(CO)(PEtNMePEt)H and CpMo(CO)(PPhNMePPh)H in CH3CN are both irreversible at slow scan rates and quasi-reversible at higher scan rates, with E1/2 = -0.36 V (vs. Cp2Fe+/0) for CpMo(CO)(PEtNMePEt)H and E1/2 = -0.18 V for CpMo(CO)(PPhNMePPh)H. Hydride abstraction from CpMo(CO)(PNP)H with [Ph3C]+[A]- (A = B(C6F5)4 or BArF4; [ArF = 3,5-bis(trifluoromethyl)phenyl]) afforded “tuck-in” [CpMo(CO)(κ3-PNP)]+ complexes that feature the amine bound to the metal. Displacement of the κ3 Mo-N bond by CD3CN gives [CpMo(CO)(PNP)(CD3CN)]+. The kinetics of this reaction were studied by NMR spectroscopy, providing the activation parameters ΔH‡ = 22.1 kcal/mol, ΔS‡ = 1.89 cal/(mol·K), Ea = 22.7 kcal/mol. Protonation of CpMo(CO)(PEtNMePEt)H affords [CpMo(CO)(κ2-PEtNMePEt)(H)2]+ as a Mo dihydride complex, which loses H2 to generate [CpMo(CO)(κ3-PEtNMePEt)]+ at room temperature. CpMo(CO)(dppp)H (dppp = 1,2-bis(diphenylphosphino)propane) was studied as a Mo diphosphine analogue without a pendant amine, and the product of protonation of this complex gives [CpMo(CO)(dppp)(H)2]+. Our results show that the pendant amine has a strong driving force to form stable “tuck-in” [CpMo(CO)(κ3-PNP)]+ complexes, and also promotes hydrogen elimination from [CpMo(CO)(PNP)(H)2]+ complexes by formation of Mo-N dative bond. We thank the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences and Biosciences for support. Pacific Northwest National Laboratory is operated by

  10. Developing and Enhancing Workforce Training Programs: Number...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Developing and Enhancing Workforce Training Programs: Number of Projects by State Developing and Enhancing Workforce Training Programs: Number of Projects by State Map of the ...

  11. Research Update: A hafnium-based metal-organic framework as a catalyst for regioselective ring-opening of epoxides with a mild hydride source

    SciTech Connect (OSTI)

    Stephenson, Casey J.; Hassan Beyzavi, M.; Klet, Rachel C.; Hupp, Joseph T. E-mail: o-farha@northwestern.edu; Farha, Omar K. E-mail: o-farha@northwestern.edu

    2014-12-01

    Reaction of styrene oxide with sodium cyanoborohydride and a catalytic amount of Hf-NU-1000 yields the anti-Markovnikov product, 2-phenylethanol, with over 98% regioselectivity. On the other hand, propylene oxide is ring opened in a Markovnikov fashion to form 2-propanol with 95% regioselectivity. Both styrene oxide and propylene oxide failed to react with sodium cyanoborohydride without the addition of Hf-NU-1000 indicative of the crucial role of Hf-NU-1000 as a catalyst in this reaction. To the best of our knowledge, this is the first report of the use of a metal-organic framework material as a catalyst for ring-opening of epoxides with hydrides.

  12. Environmental effects on noble-gas hydrides: HXeBr, HXeCCH, and HXeH in noble-gas and molecular matrices

    SciTech Connect (OSTI)

    Tsuge, Masashi E-mail: leonid.khriachtchev@helsinki.fi; Lignell, Antti; Rsnen, Markku; Khriachtchev, Leonid E-mail: leonid.khriachtchev@helsinki.fi

    2013-11-28

    Noble-gas hydrides HNgY (Ng is a noble-gas atom and Y is an electronegative group) are sensitive probes of local environment due to their relatively weak bonding and large dipole moments. We experimentally studied HXeBr in Ar, Kr, and N{sub 2} matrices, HXeCCH in Ne and N{sub 2} matrices, and HXeH in an N{sub 2} matrix. These are the first observations of noble-gas hydrides in an N{sub 2} matrix. An N{sub 2} matrix strongly increases the HXe stretching frequency of HXeBr and HXeCCH with respect to a Ne matrix, which is presumably due to a strong interaction between the HNgY dipole moment and quadrupole moments of the surrounding lattice N{sub 2} molecules. The spectral shift of HXeBr in an N{sub 2} matrix is similar to that in a CO{sub 2} matrix, which is a rather unexpected result because the quadrupole moment of CO{sub 2} is about three times as large as that of N{sub 2}. The HXe stretching frequencies of HXeBr and HXeCCH in noble-gas matrices show a trend of ?(Ne) < ?(Xe) < ?(Kr) < ?(Ar), which is a non-monotonous function of the dielectric constants of the noble-gas solids. The MP2(full) calculations of HXeBr and HXeCCH with the polarizable continuum model as well as the CCSD(T) calculations of the HXeBrNg and HXeCCHNg (Ng = Ne, Ar, Kr, and Xe) complexes cannot fully explain the experimental observations. It is concluded that more sophisticated computational models should be used to describe these experimental findings.

  13. Battery Electrode Materials with High Cycle Lifetimes

    SciTech Connect (OSTI)

    Prof. Brent Fultz

    2001-06-29

    In an effort to understand the capacity fade of nickel-metal hydride (Ni-MH) batteries, we performed a systematic study of the effects of solute additions on the cycle life of metal hydride electrodes. We also performed a series of measurements on hydrogen absorption capacities of novel carbon and graphite-based materials including graphite nanofibers and single-walled carbon nanotubes. Towards the end of this project we turned our attention to work on Li-ion cells with a focus on anode materials.

  14. Climate Zone Number 5 | Open Energy Information

    Open Energy Info (EERE)

    Climate Zone Number 5 Jump to: navigation, search A type of climate defined in the ASHRAE 169-2006 standard. Climate Zone Number 5 is defined as Cool- Humid(5A) with IP Units 5400...

  15. ARM - Measurement - Cloud particle number concentration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    from you Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Cloud particle number concentration The total number of cloud particles present in any given volume...

  16. On the binary expansions of algebraic numbers

    SciTech Connect (OSTI)

    Bailey, David H.; Borwein, Jonathan M.; Crandall, Richard E.; Pomerance, Carl

    2003-07-01

    Employing concepts from additive number theory, together with results on binary evaluations and partial series, we establish bounds on the density of 1's in the binary expansions of real algebraic numbers. A central result is that if a real y has algebraic degree D > 1, then the number {number_sign}(|y|, N) of 1-bits in the expansion of |y| through bit position N satisfies {number_sign}(|y|, N) > CN{sup 1/D} for a positive number C (depending on y) and sufficiently large N. This in itself establishes the transcendency of a class of reals {summation}{sub n{ge}0} 1/2{sup f(n)} where the integer-valued function f grows sufficiently fast; say, faster than any fixed power of n. By these methods we re-establish the transcendency of the Kempner--Mahler number {summation}{sub n{ge}0}1/2{sup 2{sup n}}, yet we can also handle numbers with a substantially denser occurrence of 1's. Though the number z = {summation}{sub n{ge}0}1/2{sup n{sup 2}} has too high a 1's density for application of our central result, we are able to invoke some rather intricate number-theoretical analysis and extended computations to reveal aspects of the binary structure of z{sup 2}.

  17. Utah Natural Gas Number of Gas and Gas Condensate Wells (Number...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas and Gas Condensate Wells (Number of Elements) Utah Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 ...

  18. Identification of Export Control Classification Number - ITER

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of Export Control Classification Number - ITER (April 2012) As the "Shipper of Record" ... be shipped from the United States to the ITER International Organization in Cadarache, ...

  19. Particle Number & Particulate Mass Emissions Measurements on...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Heavy-duty Engine using the PMP Methodologies Particle Number & Particulate Mass Emissions Measurements on a 'Euro VI' Heavy-duty Engine using the PMP Methodologies Poster ...

  20. Calculating Atomic Number Densities for Uranium

    Energy Science and Technology Software Center (OSTI)

    1993-01-01

    Provides method to calculate atomic number densities of selected uranium compounds and hydrogenous moderators for use in nuclear criticality safety analyses at gaseous diffusion uranium enrichment facilities.

  1. Thermal Release of 3He from Tritium Aged LaNi4.25Al0.75 Hydride

    SciTech Connect (OSTI)

    Staack, Gregory C.; Crowder, Mark L.; Klein, James E.

    2015-02-01

    Recently, the demand for He-3 has increased dramatically due to widespread use in nuclear nonproliferation, cryogenic, and medical applications. Essentially all of the world’s supply of He-3 is created by the radiolytic decay of tritium. The Savannah River Site Tritium Facilities (SRS-TF) utilizes LANA.75 in the tritium process to store hydrogen isotopes. The vast majority of He-3 “born” from tritium stored in LANA.75 is trapped in the hydride metal matrix. The SRS-TF has multiple LANA.75 tritium storage beds that have been retired from service with significant quantities of He-3 trapped in the metal. To support He-3 recovery, the Savannah River National Laboratory (SRNL) conducted thermogravimetric analysis coupled with mass spectrometry (TGA-MS) on a tritium aged LANA.75 sample. TGA-MS testing was performed in an argon environment. Prior to testing, the sample was isotopically exchanged with deuterium to reduce residual tritium and passivated with air to alleviate pyrophoric concerns associated with handling the material outside of an inert glovebox. Analyses indicated that gas release from this sample was bimodal, with peaks near 220 and 490°C. The first peak consisted of both He-3 and residual hydrogen isotopes, the second was primarily He-3. The bulk of the gas was released by 600 °C

  2. Low Mach Number Models in Computational Astrophysics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ann Almgren Low Mach Number Models in Computational Astrophysics February 4, 2014 Ann Almgren. Berkeley Lab Downloads Almgren-nug2014.pdf | Adobe Acrobat PDF file Low Mach Number Models in Computational Astrophysics - Ann Almgren, Berkeley Lab Last edited: 2016-04-29 11:34:50

  3. Compendium of Experimental Cetane Number Data

    SciTech Connect (OSTI)

    Murphy, M. J.; Taylor, J. D.; McCormick, R. L.

    2004-09-01

    In this report, we present a compilation of reported cetane numbers for pure chemical compounds. The compiled database contains cetane values for 299 pure compounds, including 156 hydrocarbons and 143 oxygenates. Cetane number is a relative ranking of fuels based on the amount of time between fuel injection and ignition. The cetane number is typically measured either in a combustion bomb or in a single-cylinder research engine. This report includes cetane values from several different measurement techniques - each of which has associated uncertainties. Additionally, many of the reported values are determined by measuring blending cetane numbers, which introduces significant error. In many cases, the measurement technique is not reported nor is there any discussion about the purity of the compounds. Nonetheless, the data in this report represent the best pure compound cetane number values available from the literature as of August 2004.

  4. Mo Year Report Period: EIA ID NUMBER:

    U.S. Energy Information Administration (EIA) Indexed Site

    Mo Year Report Period: EIA ID NUMBER: http:www.eia.govsurveyformeia14instructions.pdf Mailing Address: Secure File Transfer option available at: (e.g., PO Box, RR) https:...

  5. Identification of Export Control Classification Number - ITER

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of Export Control Classification Number - ITER (April 2012) As the "Shipper of Record" please provide the appropriate Export Control Classification Number (ECCN) for the products (equipment, components and/or materials) and if applicable the nonproprietary associated installation/maintenance documentation that will be shipped from the United States to the ITER International Organization in Cadarache, France or to ITER Members worldwide on behalf of the Company. In rare instances an

  6. Stockpile Stewardship Quarterly Volume 1, Number 4

    National Nuclear Security Administration (NNSA)

    1, Number 4 * February 2012 Message from the Assistant Deputy Administrator for Stockpile Stewardship, Chris Deeney Defense Programs Stockpile Stewardship in Action Volume 1, Number 4 Inside this Issue 2 Applying Advanced Simulation Models to Neutron Tube Ion Extraction 3 Advanced Optical Cavities for Subcritical and Hydrodynamic Experiments 5 Progress Toward Ignition on the National Ignition Facility 7 Commissioning URSA Minor: The First LTD-Based Accelerator for Radiography 8 Publication

  7. Evaluation of hoop creep behaviors in long-term dry storage condition of pre-hydrided and high burn-up nuclear fuel cladding

    SciTech Connect (OSTI)

    Kim, Sun-Ki; Bang, J.G.; Kim, D.H.; Yang, Y.S.

    2007-07-01

    Related to the degradation of the mechanical properties of Zr-based nuclear fuel cladding tubes under long term dry storage condition, the mechanical tests which can simulate the degradation of the mechanical properties properly are needed. Especially, the degradation of the mechanical properties by creep mechanism seems to be dominant under long term dry storage condition. Accordingly, in this paper, ring creep tests were performed in order to evaluate the creep behaviors of high burn-up fuel cladding under a hoop loading condition in a hot cell. The tests are performed with Zircaloy-4 fuel cladding whose burn-up is approximately {approx}60,000 MWd/tU in the temperature range from 350 deg. to 550 deg.. The tests are also performed with pre-hydrided Zircaloy-4 and ZIRLO up to 1,000 ppm. First of all, the hoop loading grip for the ring creep test was designed in order that a constant curvature of the specimen was maintained during the creep deformation, and the graphite lubricant was used to minimize the friction between the outer surface of the die insert and the inner surface of the ring specimen. The specimen for the ring creep test was designed to limit the deformation within the gauge section and to maximize the uniformity of the strain distribution. It was confirmed that the mechanical properties under a hoop loading condition can be correctly evaluated by using this test technique. In this paper, secondary creep rate with increasing hydrogen content are drawn, and then kinetic data such as pre-exponential factor and activation energy for creep process are also drawn. In addition, creep life are predicted by obtaining LMP (Larson-Miller parameter) correlation in the function of hydrogen content and applied stress to yield stress ratio. (authors)

  8. Approximate resolution of hard numbering problems

    SciTech Connect (OSTI)

    Bailleux, O.; Chabrier, J.J.

    1996-12-31

    We present a new method for estimating the number of solutions of constraint satisfaction problems. We use a stochastic forward checking algorithm for drawing a sample of paths from a search tree. With this sample, we compute two values related to the number of solutions of a CSP instance. First, an unbiased estimate, second, a lower bound with an arbitrary low error probability. We will describe applications to the Boolean Satisfiability problem and the Queens problem. We shall give some experimental results for these problems.

  9. Probing lepton number violation on three frontiers

    SciTech Connect (OSTI)

    Deppisch, Frank F. [Department of Physics and Astronomy, University College London (United Kingdom)

    2013-12-30

    Neutrinoless double beta decay constitutes the main probe for lepton number violation at low energies, motivated by the expected Majorana nature of the light but massive neutrinos. On the other hand, the theoretical interpretation of the (non-)observation of this process is not straightforward as the Majorana neutrinos can destructively interfere in their contribution and many other New Physics mechanisms can additionally mediate the process. We here highlight the potential of combining neutrinoless double beta decay with searches for Tritium decay, cosmological observations and LHC physics to improve the quantitative insight into the neutrino properties and to unravel potential sources of lepton number violation.

  10. WIPP Documents - All documents by number

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Note: Documents that do not have document numbers are not included in this listing. Large file size alert This symbol means the document may be a large file size. All documents by number Common document prefixes DOE/CAO DOE/TRU DOE/CBFO DOE/WIPP DOE/EA NM DOE/EIS Other DOE/CAO Back to top DOE/CAO 95-1095, Oct. 1995 Remote Handled Transuranic Waste Study This study was conducted to satisfy the requirements defined by the WIPP Land Withdrawal Act and considered by DOE to be a prudent exercise in

  11. Battling bird flu by the numbers

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Battling bird flu by the numbers Battling bird flu by the numbers Lab theorists have developed a mathematical tool that could help health experts and crisis managers determine in real time whether an emerging infectious disease such as avian influenza H5N1 is poised to spread globally. May 27, 2008 Los Alamos National Laboratory sits on top of a once-remote mesa in northern New Mexico with the Jemez mountains as a backdrop to research and innovation covering multi-disciplines from bioscience,

  12. The 17 GHz active region number

    SciTech Connect (OSTI)

    Selhorst, C. L.; Pacini, A. A.; Costa, J. E. R.; Gimnez de Castro, C. G.; Valio, A.; Shibasaki, K.

    2014-08-01

    We report the statistics of the number of active regions (NAR) observed at 17 GHz with the Nobeyama Radioheliograph between 1992, near the maximum of cycle 22, and 2013, which also includes the maximum of cycle 24, and we compare with other activity indexes. We find that NAR minima are shorter than those of the sunspot number (SSN) and radio flux at 10.7 cm (F10.7). This shorter NAR minima could reflect the presence of active regions generated by faint magnetic fields or spotless regions, which were a considerable fraction of the counted active regions. The ratio between the solar radio indexes F10.7/NAR shows a similar reduction during the two minima analyzed, which contrasts with the increase of the ratio of both radio indexes in relation to the SSN during the minimum of cycle 23-24. These results indicate that the radio indexes are more sensitive to weaker magnetic fields than those necessary to form sunspots, of the order of 1500 G. The analysis of the monthly averages of the active region brightness temperatures shows that its long-term variation mimics the solar cycle; however, due to the gyro-resonance emission, a great number of intense spikes are observed in the maximum temperature study. The decrease in the number of these spikes is also evident during the current cycle 24, a consequence of the sunspot magnetic field weakening in the last few years.

  13. Pennsylvania Number of Natural Gas Consumers

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    1998-2014 Average Consumption per Consumer (Thousand Cubic Ft.) 618 606 604 540 627 666 1967-2014 Industrial Number of Consumers 4,745 4,624 5,007 5,066 5,024 5,084 1987-2014...

  14. Washington Number of Natural Gas Consumers

    Gasoline and Diesel Fuel Update (EIA)

    059,239 1,067,979 1,079,277 1,088,762 1,102,318 1,118,193 1987-2014 Sales 1,067,979 1,079,277 1,088,762 1,102,318 1,118,193 1997-2014 Commercial Number of Consumers 98,965 99,231...

  15. Kansas Number of Natural Gas Consumers

    Gasoline and Diesel Fuel Update (EIA)

    855,454 853,842 854,730 854,800 858,572 861,092 1987-2014 Sales 853,842 854,730 854,779 858,546 861,066 1997-2014 Transported 0 0 21 26 26 2004-2014 Commercial Number of Consumers...

  16. Climate Zone Number 1 | Open Energy Information

    Open Energy Info (EERE)

    Zone Number 1 is defined as Very Hot - Humid(1A) with IP Units 9000 < CDD50F and SI Units 5000 < CDD10C Dry(1B) with IP Units 9000 < CDD50F and SI Units 5000 < CDD10C...

  17. Alaska Maximum Number of Active Crews Engaged in Seismic Surveying (Number

    Gasoline and Diesel Fuel Update (EIA)

    of Elements) Seismic Surveying (Number of Elements) Alaska Maximum Number of Active Crews Engaged in Seismic Surveying (Number of Elements) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2000 0 0 2 3 3 3 1 1 0 0 0 0 2001 0 0 0 0 2 2 0 0 0 0 0 0 2002 2 2 2 2 2 2 2 2 2 2 2 1 2003 0 0 2 2 2 2 2 2

  18. Oklahoma Number of Natural Gas Consumers

    Gasoline and Diesel Fuel Update (EIA)

    924,745 914,869 922,240 927,346 931,981 937,237 1987-2014 Sales 914,869 922,240 927,346 931,981 937,237 1997-2014 Transported 0 0 0 0 0 1997-2014 Commercial Number of Consumers 94,314 92,430 93,903 94,537 95,385 96,004 1987-2014 Sales 88,217 89,573 90,097 90,861 91,402 1998-2014 Transported 4,213 4,330 4,440 4,524 4,602 1998-2014 Average Consumption per Consumer (Thousand Cubic Ft.) 439 452 430 382 464 489 1967-2014 Industrial Number of Consumers 2,618 2,731 2,733 2,872 2,958 3,063 1987-2014

  19. Sensitivity in risk analyses with uncertain numbers.

    SciTech Connect (OSTI)

    Tucker, W. Troy; Ferson, Scott

    2006-06-01

    Sensitivity analysis is a study of how changes in the inputs to a model influence the results of the model. Many techniques have recently been proposed for use when the model is probabilistic. This report considers the related problem of sensitivity analysis when the model includes uncertain numbers that can involve both aleatory and epistemic uncertainty and the method of calculation is Dempster-Shafer evidence theory or probability bounds analysis. Some traditional methods for sensitivity analysis generalize directly for use with uncertain numbers, but, in some respects, sensitivity analysis for these analyses differs from traditional deterministic or probabilistic sensitivity analyses. A case study of a dike reliability assessment illustrates several methods of sensitivity analysis, including traditional probabilistic assessment, local derivatives, and a ''pinching'' strategy that hypothetically reduces the epistemic uncertainty or aleatory uncertainty, or both, in an input variable to estimate the reduction of uncertainty in the outputs. The prospects for applying the methods to black box models are also considered.

  20. WIPP Site By The Numbers August 2015

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    0 ft. By the Numbers The Waste Isolation Pilot Plant (WIPP) is a Department of Energy facility designed to safely isolate defense- related transuranic (TRU) waste from people and the environment. WIPP, which began waste disposal operations in 1999, is located 26 miles outside of Carlsbad, New Mexico. Waste temporarily stored at sites around the country is shipped to WIPP and permanently disposed in rooms mined out of an ancient salt formation below the surface. TRU waste destined for WIPP

  1. Stockpile Stewardship Quarterly, Volume 2, Number 1

    National Nuclear Security Administration (NNSA)

    1 * May 2012 Message from the Assistant Deputy Administrator for Stockpile Stewardship, Chris Deeney Defense Programs Stockpile Stewardship in Action Volume 2, Number 1 Inside this Issue 2 LANL and ANL Complete Groundbreaking Shock Experiments at the Advanced Photon Source 3 Characterization of Activity-Size-Distribution of Nuclear Fallout 5 Modeling Mix in High-Energy-Density Plasma 6 Quality Input for Microscopic Fission Theory 8 Fiber Reinforced Composites Under Pressure: A Case Study in

  2. Hydrogen Storage Properties of New Hydrogen-Rich BH3NH3-Metal Hydride (TiH2, ZrH2, MgH2, and/or CaH2) Composite Systems

    SciTech Connect (OSTI)

    Choi, Young Joon; Xu, Yimin; Shaw, Wendy J.; Ronnebro, Ewa

    2012-04-19

    Ammonia borane (AB = NH3BH3) is one of the most attractive materials for chemical hydrogen storage due to its high hydrogen contents of 19.6 wt.%, however, impurity levels of borazine, ammonia and diborane in conjunction with foaming and exothermic hydrogen release calls for finding ways to mitigate the decomposition reactions. In this paper we present a solution by mixing AB with metal hydrides (TiH2, ZrH2, MgH2 and CaH2) which have endothermic hydrogen release in order to control the heat release and impurity levels from AB upon decomposition. The composite materials were prepared by mechanical ball milling, and their H2 release properties were characterized by thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). The formation of volatile products from decomposition side reactions, such as borazine (N3B3H6) was determined by mass spectrometry (MS). Sieverts type pressure-composition-temperature (PCT) gas-solid reaction instrument was adopted to observe the kinetics of the H2 release reactions of the combined systems and neat AB. In situ 11B MAS-NMR revealed a destabilized decomposition pathway. We found that by adding specific metal hydrides to AB we can eliminate the impurities and mitigate the heat release.

  3. Nevada Natural Gas Number of Gas and Gas Condensate Wells (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    Elements) Gas and Gas Condensate Wells (Number of Elements) Nevada Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1990's 5 5 4 4 2000's 4 4 4 4 4 4 4 4 0 0 2010's 0 0 0 4 4 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 8/31/2016 Next Release Date: 9/30/2016 Referring Pages: Number of Producing Gas

  4. Table B14. Number of Establishments in Building, Number of Buildings, 1999

    U.S. Energy Information Administration (EIA) Indexed Site

    4. Number of Establishments in Building, Number of Buildings, 1999" ,"Number of Buildings (thousand)" ,"All Buildings","Number of Establishments in Building" ,,"One","Two to Five","Six to Ten","Eleven to Twenty","More than Twenty","Currently Unoccupied" "All Buildings ................",4657,3528,688,114,48,27,251 "Building Floorspace" "(Square Feet)" "1,001 to 5,000

  5. U.S. Natural Gas Number of Underground Storage Acquifers Capacity (Number

    U.S. Energy Information Administration (EIA) Indexed Site

    of Elements) Acquifers Capacity (Number of Elements) U.S. Natural Gas Number of Underground Storage Acquifers Capacity (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1990's 49 2000's 49 39 38 43 43 44 44 43 43 43 2010's 43 43 44 47 46 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 08/31/2016 Next Release Date: 09/30/2016 Referring Pages: Number of

  6. Property:NumberOfLEDSTools | Open Energy Information

    Open Energy Info (EERE)

    Name NumberOfLEDSTools Property Type Number Retrieved from "http:en.openei.orgwindex.php?titleProperty:NumberOfLEDSTools&oldid322418" Feedback Contact needs updating Image...

  7. Property:Number of Plants Included in Planned Estimate | Open...

    Open Energy Info (EERE)

    Number of Plants Included in Planned Estimate Jump to: navigation, search Property Name Number of Plants Included in Planned Estimate Property Type String Description Number of...

  8. Property:Number of Color Cameras | Open Energy Information

    Open Energy Info (EERE)

    Color Cameras Jump to: navigation, search Property Name Number of Color Cameras Property Type Number Pages using the property "Number of Color Cameras" Showing 25 pages using this...

  9. Experimental Stations by Number | Stanford Synchrotron Radiation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Lightsource Experimental Stations by Number Beam Line by Techniques Photon Source Parameters Station Type Techniques Energy Range Contact Person Experimental Station 1-5 X-ray Materials Small-angle X-ray Scattering (SAXS) focused 4600-16000 eV Christopher J. Tassone Tim J. Dunn Experimental Station 2-1 X-ray Powder diffraction Thin film diffraction Focused 5000 - 14500 eV Apurva Mehta Charles Troxel Jr Experimental Station 2-2 X-ray X-ray Absorption Spectroscopy 5000 to 37000 eV Ryan Davis

  10. Health Code Number (HCN) Development Procedure

    SciTech Connect (OSTI)

    Petrocchi, Rocky; Craig, Douglas K.; Bond, Jayne-Anne; Trott, Donna M.; Yu, Xiao-Ying

    2013-09-01

    This report provides the detailed description of health code numbers (HCNs) and the procedure of how each HCN is assigned. It contains many guidelines and rationales of HCNs. HCNs are used in the chemical mixture methodology (CMM), a method recommended by the department of energy (DOE) for assessing health effects as a result of exposures to airborne aerosols in an emergency. The procedure is a useful tool for proficient HCN code developers. Intense training and quality assurance with qualified HCN developers are required before an individual comprehends the procedure to develop HCNs for DOE.

  11. Nebraska Natural Gas Number of Gas and Gas Condensate Wells (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    Elements) Gas and Gas Condensate Wells (Number of Elements) Nebraska Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 15 1990's 11 12 22 59 87 87 88 91 95 96 2000's 98 96 106 109 111 114 114 186 322 285 2010's 276 322 270 357 310 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 8/31/2016 Next

  12. Oregon Natural Gas Number of Gas and Gas Condensate Wells (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    Elements) Gas and Gas Condensate Wells (Number of Elements) Oregon Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 18 1990's 19 16 16 18 19 17 18 17 15 19 2000's 17 20 18 15 15 15 14 18 21 24 2010's 26 24 27 26 28 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 8/31/2016 Next Release Date:

  13. Maryland Natural Gas Number of Gas and Gas Condensate Wells (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    Elements) Gas and Gas Condensate Wells (Number of Elements) Maryland Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 8 1990's 7 7 9 7 7 7 8 8 8 8 2000's 7 7 5 7 7 7 7 7 7 7 2010's 7 8 9 7 7 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 8/31/2016 Next Release Date: 9/30/2016 Referring Pages:

  14. Missouri Natural Gas Number of Gas and Gas Condensate Wells (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    Elements) Gas and Gas Condensate Wells (Number of Elements) Missouri Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 4 1990's 8 6 5 8 12 15 24 0 0 0 2000's 0 0 0 0 0 0 0 0 0 0 2010's 0 53 100 26 28 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 8/31/2016 Next Release Date: 9/30/2016 Referring

  15. U.S. Natural Gas Number of Commercial Consumers - Transported (Number of

    Gasoline and Diesel Fuel Update (EIA)

    Elements) Transported (Number of Elements) U.S. Natural Gas Number of Commercial Consumers - Transported (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1990's 220,655 410,695 2000's 433,944 464,412 475,420 489,324 495,586 499,402 539,557 2010's 716,692 763,597 837,652 881,196 885,257 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 08/31/2016 Next

  16. Alaska Natural Gas Number of Gas and Gas Condensate Wells (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    Elements) Gas and Gas Condensate Wells (Number of Elements) Alaska Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 108 1990's 111 110 112 113 104 100 102 141 148 99 2000's 152 170 165 195 224 227 231 239 261 261 2010's 269 277 185 159 170 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 8/31/2016

  17. Arizona Natural Gas Number of Gas and Gas Condensate Wells (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    Elements) Gas and Gas Condensate Wells (Number of Elements) Arizona Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 3 1990's 5 6 6 6 6 7 7 8 8 8 2000's 9 8 7 9 6 6 7 7 6 6 2010's 5 5 5 5 5 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 8/31/2016 Next Release Date: 9/30/2016 Referring Pages:

  18. Illinois Natural Gas Number of Gas and Gas Condensate Wells (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    Elements) Gas and Gas Condensate Wells (Number of Elements) Illinois Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 241 1990's 356 373 382 385 390 372 370 372 185 300 2000's 280 300 225 240 251 316 316 43 45 51 2010's 50 40 40 34 36 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 8/31/2016 Next

  19. South Dakota Natural Gas Number of Gas and Gas Condensate Wells (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    Elements) Gas and Gas Condensate Wells (Number of Elements) South Dakota Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 53 1990's 54 54 38 47 55 56 61 60 59 60 2000's 71 68 69 61 61 69 69 71 71 89 2010's 102 100 95 65 68 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 8/31/2016 Next Release Date:

  20. Tennessee Natural Gas Number of Gas and Gas Condensate Wells (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    Elements) Gas and Gas Condensate Wells (Number of Elements) Tennessee Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 700 1990's 690 650 600 505 460 420 2000's 380 350 400 430 280 400 330 305 285 310 2010's 230 210 212 1,089 1,024 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 8/31/2016 Next

  1. Michigan Number of Natural Gas Consumers

    Gasoline and Diesel Fuel Update (EIA)

    3,169,026 3,152,468 3,153,895 3,161,033 3,180,349 3,192,807 1987-2014 Sales 2,952,550 2,946,507 2,939,693 2,950,315 2,985,315 1997-2014 Transported 199,918 207,388 221,340 230,034 207,492 1997-2014 Commercial Number of Consumers 252,017 249,309 249,456 249,994 250,994 253,127 1987-2014 Sales 217,325 213,995 212,411 213,532 219,240 1998-2014 Transported 31,984 35,461 37,583 37,462 33,887 1998-2014 Average Consumption per Consumer (Thousand Cubic Ft.) 649 611 656 578 683 736 1967-2014 Industrial

  2. U.S. Maximum Number of Active Crews Engaged in Seismic Surveying (Number of

    Gasoline and Diesel Fuel Update (EIA)

    Elements) Maximum Number of Active Crews Engaged in Seismic Surveying (Number of Elements) U.S. Maximum Number of Active Crews Engaged in Seismic Surveying (Number of Elements) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2000 0 0 62 63 59 63 58 61 59 63 62 65 2001 61 61 63 65 64 60 58 56 54 58 59 58 2002 54 57 54 50 51 50 52 50 56 57 50 43 2003 40 41 41 40 38 39 41 43 39 39 38 42 2004 43 45 45 45 44 49 48 49 48 48 49 50 2005 52 53 51 50 55 57 54 55 56 57 57 58 2006 55 57 59 58 58 57

  3. Alaska Maximum Number of Active Crews Engaged in Seismic Surveying (Number

    Gasoline and Diesel Fuel Update (EIA)

    of Elements) Seismic Surveying (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 2000's 13 4 23 12

  4. SOLID STATE HYDRIDE SYSTEM ENGINEERING

    SciTech Connect (OSTI)

    Anton, D; Mark Jones, M; Bruce Hardy, B

    2007-10-31

    A typical hydrogen refueling station was designed based on DOE targets and existing gasoline filling station operations. The purpose of this design was to determine typical heat loads, how these heat loads will be handled, and approximate equipment sizes. For the station model, two DOE targets that had the most impact on the design were vehicle driving range and refueling time. The target that hydrogen fueled vehicles should have the equivalent driving range as present automobiles, requires 5 kg hydrogen storage. Assuming refueling occurs when the tank is 80% empty yields a refueling quantity of 4 kg. The DOE target for 2010 of a refueling time of 3 minutes was used in this design. There is additional time needed for payment of the fuel, and connecting and disconnecting hoses and grounds. It was assumed that this could be accomplished in 5 minutes. Using 8 minutes for each vehicle refueling gives a maximum hourly refueling rate of 7.5 cars per hour per fueling point.

  5. Hawaii Number of Natural Gas Consumers

    Gasoline and Diesel Fuel Update (EIA)

    Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2010 0 0 0 0 0 0 0 0 0 0 0 0 2011 0 0 0 0 0 0 0 0 0 0 0 0 2012 0 0 0 0 0 0 0 0 0 0 0 0 2013 1 1 1 1 1 1 1 1 1 1 1 1 2014 1 1 1 1 1 1 1 1 1 1 1 1 2015 0 0 0 0 0 1 1 1 1 1 1 1 2016 1 1 1 1 0 0

    25,466 25,389 25,305 25,184 26,374 28,919 1987-2014 Sales 25,389 25,305 25,184 26,374 28,919 1998-2014 Commercial Number of Consumers 2,535 2,551 2,560 2,545 2,627 2,789 1987-2014 Sales 2,551 2,560 2,545 2,627 2,789 1998-2014 Average Consumption per

  6. New Jersey Natural Gas Number of Commercial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) New Jersey Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 200,387 206,261 212,496 1990's 217,548 215,408 212,726 215,948 219,061 222,632 224,749 226,714 234,459 232,831 2000's 243,541 212,726 214,526 223,564 223,595 226,007 227,819 230,855 229,235 234,125 2010's 234,158 234,721 237,602 236,746 240,083 - = No Data Reported; -- = Not Applicable; NA = Not

  7. New Jersey Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) New Jersey Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 6,265 6,123 6,079 1990's 5,976 8,444 11,474 11,224 10,608 10,362 10,139 17,625 16,282 10,089 2000's 9,686 9,247 8,473 9,027 8,947 8,500 8,245 8,036 7,680 7,871 2010's 7,505 7,391 7,290 7,216 7,157 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of

  8. New York Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) New York Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 23,276 24,654 27,426 1990's 25,008 28,837 28,198 23,833 21,833 22,484 15,300 23,099 5,294 6,136 2000's 6,553 6,501 3,068 2,984 2,963 3,752 3,642 7,484 7,080 6,634 2010's 6,236 6,609 5,910 6,311 6,313 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of

  9. Ohio Natural Gas Number of Gas and Gas Condensate Wells (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    Elements) Gas and Gas Condensate Wells (Number of Elements) Ohio Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 34,450 1990's 34,586 34,760 34,784 34,782 34,731 34,520 34,380 34,238 34,098 33,982 2000's 33,897 33,917 34,593 33,828 33,828 33,735 33,945 34,416 34,416 34,963 2010's 34,931 46,717 35,104 32,664 32,967 - = No Data Reported; -- = Not Applicable; NA = Not Available; W =

  10. Oklahoma Natural Gas Number of Gas and Gas Condensate Wells (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    Elements) Gas and Gas Condensate Wells (Number of Elements) Oklahoma Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 27,443 1990's 24,547 28,216 28,902 29,118 29,121 29,733 29,733 29,734 30,101 21,790 2000's 21,507 32,672 33,279 34,334 35,612 36,704 38,060 38,364 41,921 43,600 2010's 44,000 41,238 40,000 39,776 40,070 - = No Data Reported; -- = Not Applicable; NA = Not Available; W =

  11. Pennsylvania Natural Gas Number of Gas and Gas Condensate Wells (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    Elements) Gas and Gas Condensate Wells (Number of Elements) Pennsylvania Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 30,000 1990's 30,300 31,000 31,000 31,100 31,150 31,025 31,792 32,692 21,576 23,822 2000's 36,000 40,100 40,830 42,437 44,227 46,654 49,750 52,700 55,631 57,356 2010's 44,500 54,347 55,136 53,762 70,400 - = No Data Reported; -- = Not Applicable; NA = Not Available; W

  12. Alabama Natural Gas Number of Gas and Gas Condensate Wells (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    Elements) Gas and Gas Condensate Wells (Number of Elements) Alabama Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 1,701 1990's 2,362 3,392 3,350 3,514 3,565 3,526 4,105 4,156 4,171 4,204 2000's 4,359 4,597 4,803 5,157 5,526 5,523 6,227 6,591 6,860 6,913 2010's 7,026 7,063 6,327 6,165 6,118 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure

  13. Indiana Natural Gas Number of Gas and Gas Condensate Wells (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    Elements) Gas and Gas Condensate Wells (Number of Elements) Indiana Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 1,310 1990's 1,307 1,334 1,333 1,336 1,348 1,347 1,367 1,458 1,479 1,498 2000's 1,502 1,533 1,545 2,291 2,386 2,321 2,336 2,350 525 563 2010's 620 914 819 921 895 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual

  14. Kansas Natural Gas Number of Gas and Gas Condensate Wells (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    Elements) Gas and Gas Condensate Wells (Number of Elements) Kansas Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 13,935 1990's 16,980 17,948 18,400 19,472 19,365 22,020 21,388 21,500 21,000 17,568 2000's 15,206 15,357 16,957 17,387 18,120 18,946 19,713 19,713 17,862 21,243 2010's 22,145 25,758 24,697 23,792 24,354 - = No Data Reported; -- = Not Applicable; NA = Not Available; W =

  15. Kentucky Natural Gas Number of Gas and Gas Condensate Wells (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    Elements) Gas and Gas Condensate Wells (Number of Elements) Kentucky Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 11,248 1990's 11,713 12,169 12,483 12,836 13,036 13,311 13,501 13,825 14,381 14,750 2000's 13,487 14,370 14,367 12,900 13,920 14,175 15,892 16,563 16,290 17,152 2010's 17,670 14,632 17,936 19,494 19,256 - = No Data Reported; -- = Not Applicable; NA = Not Available; W =

  16. Louisiana Natural Gas Number of Gas and Gas Condensate Wells (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    Elements) Gas and Gas Condensate Wells (Number of Elements) Louisiana Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 16,309 1990's 16,889 15,271 13,512 15,569 12,958 14,169 15,295 14,958 18,399 16,717 2000's 15,700 16,350 17,100 16,939 20,734 18,838 17,459 18,145 19,213 18,860 2010's 19,137 21,235 19,792 19,528 19,251 - = No Data Reported; -- = Not Applicable; NA = Not Available; W =

  17. Michigan Natural Gas Number of Gas and Gas Condensate Wells (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    Elements) Gas and Gas Condensate Wells (Number of Elements) Michigan Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 1,207 1990's 1,438 2,620 3,257 5,500 6,000 5,258 5,826 6,825 7,000 6,750 2000's 7,068 7,425 7,700 8,600 8,500 8,900 9,200 9,712 9,995 10,600 2010's 10,100 11,100 10,900 10,550 10,500 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid

  18. Mississippi Natural Gas Number of Gas and Gas Condensate Wells (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    Elements) Gas and Gas Condensate Wells (Number of Elements) Mississippi Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 543 1990's 585 629 507 620 583 535 568 560 527 560 2000's 997 1,143 979 427 1,536 1,676 1,836 2,315 2,343 2,320 2010's 1,979 5,732 1,669 1,967 1,645 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company

  19. Montana Natural Gas Number of Gas and Gas Condensate Wells (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    Elements) Gas and Gas Condensate Wells (Number of Elements) Montana Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 2,700 1990's 2,607 2,802 2,890 3,075 2,940 2,918 2,990 3,071 3,423 3,634 2000's 3,321 4,331 4,544 4,539 4,971 5,751 6,578 6,925 7,095 7,031 2010's 6,059 6,477 6,240 5,754 5,754 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure

  20. Wyoming Natural Gas Number of Gas and Gas Condensate Wells (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    Elements) Gas and Gas Condensate Wells (Number of Elements) Wyoming Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 2,431 1990's 2,600 2,821 3,111 3,615 3,942 4,196 4,510 5,160 5,166 4,950 2000's 9,907 13,978 15,608 18,154 20,244 23,734 25,052 27,350 28,969 25,710 2010's 26,124 26,180 22,171 22,358 22,091 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to

  1. U.S. Natural Gas Number of Industrial Consumers - Sales (Number of

    Gasoline and Diesel Fuel Update (EIA)

    Elements) Gas and Gas Condensate Wells (Number of Elements) U.S. Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 262,483 1990's 269,790 276,987 276,014 282,152 291,773 298,541 301,811 310,971 316,929 302,421 2000's 341,678 373,304 387,772 393,327 406,147 425,887 440,516 452,945 476,652 493,100 2010's 487,627 514,637 482,822 484,994 514,786 - = No Data Reported; -- = Not Applicable; NA

  2. U.S. Natural Gas Number of Industrial Consumers - Transported (Number of

    Gasoline and Diesel Fuel Update (EIA)

    Elements) Transported (Number of Elements) U.S. Natural Gas Number of Industrial Consumers - Transported (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1990's 49,014 71,281 2000's 75,826 64,052 62,738 62,698 57,672 59,773 58,760 2010's 63,611 64,749 67,551 69,164 69,953 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 08/31/2016 Next Release Date:

  3. U.S. Natural Gas Number of Residential Consumers - Sales (Number of

    Gasoline and Diesel Fuel Update (EIA)

    (Number of Elements) U.S. Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 47,710,444 48,474,449 49,309,593 1990's 50,187,178 51,593,206 52,331,397 52,535,411 53,392,557 54,322,179 55,263,673 56,186,958 57,321,746 58,223,229 2000's 59,252,728 60,286,364 61,107,254 61,871,450 62,496,134 63,616,827 64,166,280 64,964,769 65,073,996 65,329,582 2010's 65,542,345 65,940,522 66,375,134 66,812,393

  4. U.S. Natural Gas Number of Residential Consumers - Transported (Number of

    Gasoline and Diesel Fuel Update (EIA)

    Elements) Transported (Number of Elements) U.S. Natural Gas Number of Residential Consumers - Transported (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1990's 252,783 801,264 2,199,519 2000's 2,978,319 3,576,181 3,839,809 4,055,781 3,971,337 3,829,303 4,037,233 2010's 5,274,697 5,531,680 6,364,411 6,934,929 7,005,081 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data.

  5. Arkansas Natural Gas Number of Gas and Gas Condensate Wells (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    Elements) Gas and Gas Condensate Wells (Number of Elements) Arkansas Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 2,830 1990's 2,952 2,780 3,500 3,500 3,500 3,988 4,020 3,700 3,900 3,650 2000's 4,000 4,825 6,755 7,606 3,460 3,462 3,814 4,773 5,592 6,314 2010's 7,397 8,388 8,538 9,843 10,150 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid

  6. California Natural Gas Number of Gas and Gas Condensate Wells (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    Elements) Gas and Gas Condensate Wells (Number of Elements) California Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 1,214 1990's 1,162 1,377 1,126 1,092 1,261 997 978 930 847 1,152 2000's 1,169 1,244 1,232 1,249 1,272 1,356 1,451 1,540 1,645 1,643 2010's 1,580 1,308 1,423 1,335 1,118 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of

  7. Colorado Natural Gas Number of Gas and Gas Condensate Wells (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    Elements) Gas and Gas Condensate Wells (Number of Elements) Colorado Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 5,125 1990's 5,741 5,562 5,912 6,372 7,056 7,017 8,251 12,433 13,838 13,838 2000's 22,442 22,117 23,554 18,774 16,718 22,691 20,568 22,949 25,716 27,021 2010's 28,813 30,101 32,000 32,468 38,346 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld

  8. District of Columbia Natural Gas Number of Commercial Consumers (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    Elements) Commercial Consumers (Number of Elements) District of Columbia Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 11 14,683 11,370 11,354 1990's 11,322 11,318 11,206 11,133 11,132 11,089 10,952 10,874 10,658 12,108 2000's 11,106 10,816 10,870 10,565 10,406 10,381 10,410 9,915 10,024 10,288 2010's 9,879 10,050 9,771 9,963 10,049 - = No Data Reported; -- = Not Applicable; NA = Not

  9. District of Columbia Natural Gas Number of Residential Consumers (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    Elements) Residential Consumers (Number of Elements) District of Columbia Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 134 130,748 134,758 134,837 1990's 136,183 136,629 136,438 135,986 135,119 135,299 135,215 134,807 132,867 137,206 2000's 138,252 138,412 143,874 136,258 138,134 141,012 141,953 142,384 142,819 143,436 2010's 144,151 145,524 145,938 146,712 147,877 - = No Data Reported; --

  10. Texas Natural Gas Number of Gas and Gas Condensate Wells (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    Elements) Gas and Gas Condensate Wells (Number of Elements) Texas Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 48,609 1990's 50,867 47,615 46,298 47,101 48,654 54,635 53,816 56,747 58,736 58,712 2000's 60,577 63,704 65,779 68,572 72,237 74,827 74,265 76,436 87,556 93,507 2010's 95,014 100,966 96,617 97,618 98,279 - = No Data Reported; -- = Not Applicable; NA = Not Available; W =

  11. U.S. Natural Gas Number of Commercial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Commercial Consumers (Number of Elements) U.S. Natural Gas Number of Commercial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 4,013,040 4,124,745 4,168,048 1990's 4,236,280 4,357,252 4,409,699 4,464,906 4,533,905 4,636,500 4,720,227 4,761,409 5,044,497 5,010,189 2000's 5,010,817 4,996,446 5,064,384 5,152,177 5,139,949 5,198,028 5,273,379 5,308,785 5,444,335 5,322,332 2010's 5,301,576 5,319,817 5,356,397 5,372,522 5,418,986 - =

  12. U.S. Natural Gas Number of Gas and Gas Condensate Wells (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    Elements) Gas and Gas Condensate Wells (Number of Elements) U.S. Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 262,483 1990's 269,790 276,987 276,014 282,152 291,773 298,541 301,811 310,971 316,929 302,421 2000's 341,678 373,304 387,772 393,327 406,147 425,887 440,516 452,945 476,652 493,100 2010's 487,627 514,637 482,822 484,994 514,786 - = No Data Reported; -- = Not Applicable; NA

  13. U.S. Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Industrial Consumers (Number of Elements) U.S. Natural Gas Number of Industrial Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 195,544 199,041 225,346 1990's 218,341 216,529 209,616 209,666 202,940 209,398 206,049 234,855 226,191 228,331 2000's 220,251 217,026 205,915 205,514 209,058 206,223 193,830 198,289 225,044 207,624 2010's 192,730 189,301 189,372 192,288 192,135 - = No Data Reported; -- = Not Applicable; NA = Not

  14. U.S. Natural Gas Number of Residential Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    Residential Consumers (Number of Elements) U.S. Natural Gas Number of Residential Consumers (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 47,710,444 48,474,449 49,309,593 1990's 50,187,178 51,593,206 52,331,397 52,535,411 53,392,557 54,322,179 55,263,673 56,186,958 57,321,746 58,223,229 2000's 59,252,728 60,286,364 61,107,254 61,871,450 62,496,134 63,616,827 64,166,280 64,964,769 65,073,996 65,329,582 2010's 65,542,345 65,940,522

  15. Fact #603: December 28, 2009 Where Does Lithium Come From? | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy 3: December 28, 2009 Where Does Lithium Come From? Fact #603: December 28, 2009 Where Does Lithium Come From? Lithium ion batteries will be used in many of the upcoming plug-in hybrid vehicles and electric vehicles because they are lighter and more powerful than the nickel-metal hydride batteries used in current hybrid vehicles. Global lithium production reached 22,800 tons in 2008. Lithium reserves are a topic of debate, with estimates ranging from 4 million tons to 20 million tons.

  16. Implications of NiMH Hysteresis on HEV Battery Testing and Performance

    SciTech Connect (OSTI)

    Motloch, Chester George; Belt, Jeffrey R; Hunt, Gary Lynn; Ashton, Clair Kirkendall; Murphy, Timothy Collins; Miller, Ted J.; Coates, Calvin; Tataria, H. S.; Lucas, Glenn E.; Duong, T.Q.; Barnes, J.A.; Sutula, Raymond

    2002-08-01

    Nickel Metal-Hydride (NiMH) is an advanced high-power battery technology that is presently employed in Hybrid Electric Vehicles (HEVs) and is one of several technologies undergoing continuing research and development by FreedomCAR. Unlike some other HEV battery technologies, NiMH exhibits a strong hysteresis effect upon charge and discharge. This hysteresis has a profound impact on the ability to monitor state-of-charge and battery performance. Researchers at the Idaho National Engineering and Environmental Laboratory (INEEL) have been investigating the implications of NiMH hysteresis on HEV battery testing and performance. Experimental results, insights, and recommendations are presented.

  17. Virginia Natural Gas Number of Gas and Gas Condensate Wells ...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas and Gas Condensate Wells (Number of Elements) Virginia Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 ...

  18. Property:OutagePhoneNumber | Open Energy Information

    Open Energy Info (EERE)

    OutagePhoneNumber Jump to: navigation, search Property Name OutagePhoneNumber Property Type String Description An outage hotline or 24-hour customer service number Note: uses...

  19. Property:NEPA SerialNumber | Open Energy Information

    Open Energy Info (EERE)

    SerialNumber Jump to: navigation, search Property Name NEPA SerialNumber Property Type String This is a property of type String. Pages using the property "NEPA SerialNumber"...

  20. Property:NumberOfLowEmissionDevelopmentStrategiesExample | Open...

    Open Energy Info (EERE)

    issionDevelopmentStrategiesExample Property Type Number Retrieved from "http:en.openei.orgwindex.php?titleProperty:NumberOfLowEmissionDevelopmentStrategiesExample&oldid326472...

  1. Property:NumberOfLowEmissionDevelopmentStrategiesExamples | Open...

    Open Energy Info (EERE)

    sionDevelopmentStrategiesExamples Property Type Number Retrieved from "http:en.openei.orgwindex.php?titleProperty:NumberOfLowEmissionDevelopmentStrategiesExamples&oldid323715...

  2. Property:NumberOfResourceAssessments | Open Energy Information

    Open Energy Info (EERE)

    Jump to: navigation, search This is a property of type Number. Retrieved from "http:en.openei.orgwindex.php?titleProperty:NumberOfResourceAssessments&oldid31439...

  3. Property:Number of Plants included in Capacity Estimate | Open...

    Open Energy Info (EERE)

    Plants included in Capacity Estimate Jump to: navigation, search Property Name Number of Plants included in Capacity Estimate Property Type Number Retrieved from "http:...

  4. Local Energy Assurance Planning: Map of States with Number of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    States with Number of Cities Selected Local Energy Assurance Planning: Map of States with Number of Cities Selected Map of the United States identifying the States with cities ...

  5. West Valley Demonstration Project Site Cleanup By the Numbers...

    Office of Environmental Management (EM)

    West Valley Demonstration Project Site Cleanup By the Numbers West Valley Demonstration Project Site Cleanup By the Numbers West Valley Demonstration Project Site Cleanup By the ...

  6. Fact #857 January 26, 2015 Number of Partner Workplaces Offering...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Number of Partner Workplaces with Electric Vehicle Charging Stations, November 2014 Graph showing number of partner workplaces with electric vehicle charging stations from the ...

  7. Project Registration Number Assignments (Active) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Active) Project Registration Number Assignments (Active) As of: May 2016 Provides a table of Project Registration Number Assignments (Active) Project Registration Number Assignment (Active) (511.76 KB) More Documents & Publications All Active DOE Technical Standards Document Project Registration Number Assignments (Completed

  8. Project Registration Number Assignments (Completed) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Completed) Project Registration Number Assignments (Completed) As of: May 2016 Provides a table of Project Registration Number Assignments (Completed) Project Registration Number Assignments (Completed) (406.85 KB) More Documents & Publications All Active DOE Technical Standards Document Project Registration Number Assignments (Active

  9. High magnetic-refrigeration performance of plate-shaped La{sub 0.5}Pr{sub 0.5}Fe{sub 11.4}Si{sub 1.6} hydrides sintered in high-pressure H{sub 2} atmosphere

    SciTech Connect (OSTI)

    Sun, N. K. Guo, J.; Zhao, X. G. Zhang, Z. D.; Si, P. Z.; Huang, J. H.

    2015-03-02

    La(Fe, Si){sub 13} hydride is regarded as one of the most promising room-temperature refrigerants. However, to use the alloys in an active magnetic regenerator machine, it is vital to prepare thin refrigerants. In this work, a high H{sub 2} gas pressure of 50 MPa was employed to suppress the desorption of hydrogen atoms during the sintering process of plate-shaped La{sub 0.5}Pr{sub 0.5}Fe{sub 11.4}Si{sub 1.6} hydrides. At 330 K, a high-density sintered thin plate shows a large magnetic-entropy change ΔS{sub m} of 15.5 J/kg K (106 mJ/cm{sup 3 }K) for a field change of 2 T. The volumetric ΔS{sub m} is almost twice as large as that of bonded La(Fe,Si){sub 13} hydrides. Favorably, hysteresis is almost absent due to the existence of micropores with a porosity of 0.69% which has been analyzed with high-resolution X-ray microtomography.

  10. Phone Numbers for Beam Lines and Other Services | Stanford Synchrotron

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Radiation Lightsource Phone Numbers for Beam Lines and Other Services The local area code for SSRL is 650. All numbers listed below should be dialed as 650-926-xxxx from other area codes. When calling an onsite location from within SSRL simply dial the 4-digit extension. When calling an offsite number within the 650 area code dial, dial 9 plus the 7-digit number. To call a number in another area code dial 9-1-area code - phone number. Beam Lines Beam Line Extension 1-4 5214 1-5 5215 2-1 5221

  11. Export support of renewable energy industries. Task number 1, deliverable number 3. Final report

    SciTech Connect (OSTI)

    1998-01-14

    The United States Export Council for Renewable Energy (US/ECRE), a consortium of six industry associations, promotes the interests of the renewable energy and energy efficiency member companies which provide goods and services in biomass, geothermal, hydropower, passive solar, photovoltaics, solar thermal, wind, wood energy, and energy efficiency technologies. US/ECRE`s mission is to catalyze export markets for renewable energy and energy efficiency technologies worldwide. Under this grant, US/ECRE has conducted a number of in-house activities, as well as to manage activities by member trade associations, affiliate organizations and non-member contractors and consultants. The purpose of this document is to report on task coordination and effectiveness.

  12. Export support of renewable energy industries, grant number 1, deliverable number 3. Final report

    SciTech Connect (OSTI)

    1998-01-14

    The United States Export Council for Renewable Energy (US/ECRE), a consortium of six industry associations, promotes the interests of the renewable energy and energy efficiency member companies which provide goods and services in biomass, geothermal, hydropower, passive solar, photovoltaics, solar thermal, wind, wood energy, and energy efficiency technologies. US/ECRE`s mission is to catalyze export markets for renewable energy and energy efficiency technologies worldwide. Under this grant, US/ECRE has conducted a number of in-house activities, as well as to manage activities by member trade associations, affiliate organizations and non-member contractors and consultants. The purpose of this document is to report on grant coordination and effectiveness.

  13. Property:ASHRAE 169 Climate Zone Number | Open Energy Information

    Open Energy Info (EERE)

    5 + Adair County, Oklahoma ASHRAE 169-2006 Climate Zone + Climate Zone Number 3 + Adams County, Colorado ASHRAE 169-2006 Climate Zone + Climate Zone Number 5 + Adams County,...

  14. Social Security Number Reduction Project | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Social Security Number Reduction Project Social Security Number Reduction Project The document below provides information regarding acceptable uses of the Social Security Number (SSN). Baseline Inventory.pdf (23.65 KB) More Documents & Publications DOE Guidance on the Use of the SSN Manchester Software 1099 Reporting PIA, Idaho National Laboratory Occupational Medicine - Assistant PIA, Idaho National Laboratory

  15. Toxic Substances Control Act (TSCA) chemical substances inventory: PMN number to EPA accession number link (for microcomputers). Data file

    SciTech Connect (OSTI)

    1995-11-01

    The PMN Number to EPA Accession Number Link Diskette provides a cross-reference of these numbers for commenced PMNs on the confidential portion of the TSCA Master Inventory File. Neither this cross-reference nor the additional information included is TSCA Confidential Business Information. Provided on the diskette for each confidential commenced PMN are the PMN Case Number, EPA Accession Number, Generic Name, and EPA special flags. The sequence of the file is in ascending PMN Case Number order with `P` case numbers sorted first, followed by `Y` case numbers. For more detailed information on the confidential portion of the TSCA Inventory, including generic names, users can consult the introductory material of the printed TSCA Inventory: 1985 Edition and its 1990 Supplement. New versions of this file may be issued in the future. No search software is provided with this DOS formatted diskette.

  16. Random Number Generation for Petascale Quantum Monte Carlo

    SciTech Connect (OSTI)

    Ashok Srinivasan

    2010-03-16

    The quality of random number generators can affect the results of Monte Carlo computations, especially when a large number of random numbers are consumed. Furthermore, correlations present between different random number streams in a parallel computation can further affect the results. The SPRNG software, which the author had developed earlier, has pseudo-random number generators (PRNGs) capable of producing large numbers of streams with large periods. However, they had been empirically tested on only thousand streams earlier. In the work summarized here, we tested the SPRNG generators with over a hundred thousand streams, involving over 10^14 random numbers per test, on some tests. We also tested the popular Mersenne Twister. We believe that these are the largest tests of PRNGs, both in terms of the numbers of streams tested and the number of random numbers tested. We observed defects in some of these generators, including the Mersenne Twister, while a few generators appeared to perform well. We also corrected an error in the implementation of one of the SPRNG generators.

  17. Energy Technology Engineering Center (ETEC) Cleanup By the Numbers |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Energy Technology Engineering Center (ETEC) Cleanup By the Numbers Energy Technology Engineering Center (ETEC) Cleanup By the Numbers Energy Technology Engineering Center (ETEC) Cleanup By the Numbers In 2015, EM developed site infographics highlighting each sites history and important metrics including: Decontamination and demolition of facilities and waste sites Secure storage of spent fuel Retrieval of radioactive sludge and saltcake from tanks Treatment of

  18. Prediction of cloud droplet number in a general circulation model

    SciTech Connect (OSTI)

    Ghan, S.J.; Leung, L.R.

    1996-04-01

    We have applied the Colorado State University Regional Atmospheric Modeling System (RAMS) bulk cloud microphysics parameterization to the treatment of stratiform clouds in the National Center for Atmospheric Research Community Climate Model (CCM2). The RAMS predicts mass concentrations of cloud water, cloud ice, rain and snow, and number concnetration of ice. We have introduced the droplet number conservation equation to predict droplet number and it`s dependence on aerosols.

  19. Developing and Enhancing Workforce Training Programs: Number of Projects by

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    State | Department of Energy Developing and Enhancing Workforce Training Programs: Number of Projects by State Developing and Enhancing Workforce Training Programs: Number of Projects by State Map of the United States showing the location of Workforce Training Projects, funded through the American Recovery and Reinvestment Act Developing and Enhancing Workforce Training Programs: Number of Projects by State (389.21 KB) More Documents & Publications Workforce Development Wind Projects

  20. ORISE: Report shows number of health physics degrees for 2010

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    report shows number of health physics degrees increased for graduates, decreased for undergraduates in 2010 Decreased number of B.S. degrees remains higher than levels in the early 2000 FOR IMMEDIATE RELEASE Dec. 20, 2011 FY12-09 OAK RIDGE, Tenn.-The number of health physics graduate degrees increased for both master's and doctoral candidates in 2010, but decreased for bachelor's degrees, says a report released this year by the Oak Ridge Institute for Science and Education. The ORISE report,