National Library of Energy BETA

Sample records for nickel-metal hydride number

  1. Hydridable material for the negative electrode in a nickel-metal hydride storage battery

    DOE Patents [OSTI]

    Knosp, Bernard (Neuilly-sur-Seine, FR); Bouet, Jacques (Paris, FR); Jordy, Christian (Dourdan, FR); Mimoun, Michel (Neuilly-sur-Marne, FR); Gicquel, Daniel (Lanorville, FR)

    1997-01-01

    A monophase hydridable material for the negative electrode of a nickel-metal hydride storage battery with a "Lave's phase" structure of hexagonal C14 type (MgZn.sub.2) has the general formula: Zr.sub.1-x Ti.sub.x Ni.sub.a Mn.sub.b Al.sub.c Co.sub.d V.sub.e where ##EQU1##

  2. Mathematical modeling of the nickel/metal hydride battery system

    SciTech Connect (OSTI)

    Paxton, B K [Univ. of California, Berkeley, CA (United States). Dept. of Chemical Engineering

    1995-09-01

    A group of compounds referred to as metal hydrides, when used as electrode materials, is a less toxic alternative to the cadmium hydroxide electrode found in nickel/cadmium secondary battery systems. For this and other reasons, the nickel/metal hydride battery system is becoming a popular rechargeable battery for electric vehicle and consumer electronics applications. A model of this battery system is presented. Specifically the metal hydride material, LaNi{sub 5}H{sub 6}, is chosen for investigation due to the wealth of information available in the literature on this compound. The model results are compared to experiments found in the literature. Fundamental analyses as well as engineering optimizations are performed from the results of the battery model. In order to examine diffusion limitations in the nickel oxide electrode, a ``pseudo 2-D model`` is developed. This model allows for the theoretical examination of the effects of a diffusion coefficient that is a function of the state of charge of the active material. It is found using present data from the literature that diffusion in the solid phase is usually not an important limitation in the nickel oxide electrode. This finding is contrary to the conclusions reached by other authors. Although diffusion in the nickel oxide active material is treated rigorously with the pseudo 2-D model, a general methodology is presented for determining the best constant diffusion coefficient to use in a standard one-dimensional battery model. The diffusion coefficients determined by this method are shown to be able to partially capture the behavior that results from a diffusion coefficient that varies with the state of charge of the active material.

  3. Feasibility study for the recycling of nickel metal hydride electric vehicle batteries. Final report

    SciTech Connect (OSTI)

    Sabatini, J.C.; Field, E.L.; Wu, I.C.; Cox, M.R.; Barnett, B.M.; Coleman, J.T. [Little (Arthur D.), Inc., Cambridge, MA (United States)

    1994-01-01

    This feasibility study examined three possible recycling processes for two compositions (AB{sub 2} and AB{sub 5}) of nickel metal hydride electric vehicle batteries to determine possible rotes for recovering battery materials. Analysts examined the processes, estimated the costs for capital equipment and operation, and estimated the value of the reclaimed material. They examined the following three processes: (1) a chemical process that leached battery powders using hydrochloric acid, (2) a pyrometallurical process, and (3) a physical separation/chemical process. The economic analysis revealed that the physical separation/chemical process generated the most revenue.

  4. A non-isothermal model of a nickelmetal hydride cell , M. Mohammedb

    E-Print Network [OSTI]

    A non-isothermal model of a nickel±metal hydride cell B. Wua , M. Mohammedb , D. Brighamb , R. Elderb , R.E. Whitea,* a Department of Chemical Engineering, University of South Carolina, Columbia, SC Abstract A model for a nickel±metal hydride cell was constructed based on the planar electrode

  5. Steps to Commercialization: Nickel Metal Hydride Batteries | Department of

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirley Ann JacksonDepartment of EnergyResearchers at the Energyonecelebrates specialwarmEnergy

  6. Steps to Commercialization: Nickel Metal Hydride Batteries | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative FuelsofProgram: Report15 Meeting State Energy Advisory BoardStateFailures

  7. CRADA (AL-C-2009-02) Final Report: Phase I. Lanthanum-based Start Materials for Hydride Batteries

    SciTech Connect (OSTI)

    Gschneidner, Jr., Karl; Schmidt, Frederick; Frerichs, A.E.; Ament, Katherine A.

    2013-05-01

    The purpose of Phase I of this work is to focus on developing a La-based start material for making nickel-metal (lanthanum)-hydride batteries based on our carbothermic-silicon process. The goal is to develop a protocol for the manufacture of (La{sub 1-x}R{sub x})(Ni{sub 1-y}M{sub y})(Si{sub z}), where R is a rare earth metal and M is a non-rare earth metal, to be utilized as the negative electrode in nickel-metal hydride (NiMH) rechargeable batteries.

  8. Analytical assessment of the thermal behavior of nickel-metal hydride batteries

    E-Print Network [OSTI]

    Bahrami, Majid

    * , Maryam Yazdanpour, Majid Bahrami Laboratory for Alternative Energy Conversion (LAEC), Mechatronic Systems value problems of heat conduction, Dover Publications, New York, 1989 [3] M.S. Wu et al., J. Power Sour inside the battery can be approximated from the well-known energy balance analysis proposed by Bernardi

  9. Method Of Charging Maintenance-Free Nickel Metal Hydride Storage Cells

    DOE Patents [OSTI]

    Berlureau, Thierry (Bordeaux, FR); Liska, Jean-Louis (Bordeaux, FR)

    1999-11-16

    A method of charging an industrial maintenance-free Ni-MH storage cell, the method comprising in combination a first stage at a constant current I.sub.1 lying in the range I.sub.c /10 to I.sub.c /2, and a second stage at a constant current I.sub.2 lying in the range I.sub.c /50 to I.sub.c /10, the changeover from the first stage to the second stage taking place when the time derivative of the temperature reaches a threshold value which varies as a function of the temperature at the time of the changeover.

  10. Improving nickel metal hydride batteries through research in negative electrode corrosion control and novel electrode materials 

    E-Print Network [OSTI]

    Alexander, Michael Scott

    1997-01-01

    electrode materials. In order to fully understand the processes involved in the corrosion study, tests were carried at Brookhaven National Laboratory using X-ray Absorption Near Edge Spectroscopy. These tests showed that Zn prevented the corrosion of Ni...

  11. Hydride compositions

    DOE Patents [OSTI]

    Lee, Myung, W.

    1994-01-01

    Disclosed are a composition for use in storing hydrogen and a method for making the composition. The composition comprises a mixture of two or more hydrides, each hydride having a different series of hydrogen sorption isotherms that contribute to the overall isotherms of the mixture. The hydrides are chosen so that the isotherms of the mixture have regions wherein the H equilibrium pressure increases with increasing hydrogen, preferably linearly. The isotherms of the mixture can be adjusted by selecting hydrides with different isotherms and by varying the amounts of the individual hydrides, or both. Preferably, the mixture is made up of hydrides that have isotherms with substantially flat plateaus and in nearly equimolar amounts. The composition is activated by degassing, exposing to H, and then heating below the softening temperature of any of the constituents. When the composition is used to store hydrogen, its hydrogen content can be found simply by measuring P{sub H}{sub 2} and determining H/M from the isothermic function of the composition.

  12. Metal Hydride Hydrogen Storage Research and Development

    Broader source: Energy.gov [DOE]

    DOE's research on complex metal hydrides targets the development of advanced metal hydride materials including light-weight complex hydrides, destabilized binary hydrides, intermetallic hydrides,...

  13. Hydride compressor

    DOE Patents [OSTI]

    Powell, James R. (Wading River, NY); Salzano, Francis J. (Patchogue, NY)

    1978-01-01

    Method of producing high energy pressurized gas working fluid power from a low energy, low temperature heat source, wherein the compression energy is gained by using the low energy heat source to desorb hydrogen gas from a metal hydride bed and the desorbed hydrogen for producing power is recycled to the bed, where it is re-adsorbed, with the recycling being powered by the low energy heat source. In one embodiment, the adsorption-desorption cycle provides a chemical compressor that is powered by the low energy heat source, and the compressor is connected to a regenerative gas turbine having a high energy, high temperature heat source with the recycling being powered by the low energy heat source.

  14. Metastable Metal Hydrides for Hydrogen Storage

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Graetz, Jason

    2012-01-01

    The possibility of using hydrogen as a reliable energy carrier for both stationary and mobile applications has gained renewed interest in recent years due to improvements in high temperature fuel cells and a reduction in hydrogen production costs. However, a number of challenges remain and new media are needed that are capable of safely storing hydrogen with high gravimetric and volumetric densities. Metal hydrides and complex metal hydrides offer some hope of overcoming these challenges; however, many of the high capacity “reversible” hydrides exhibit a large endothermic decomposition enthalpy making it difficult to release the hydrogen at low temperatures. Onmore »the other hand, the metastable hydrides are characterized by a low reaction enthalpy and a decomposition reaction that is thermodynamically favorable under ambient conditions. The rapid, low temperature hydrogen evolution rates that can be achieved with these materials offer much promise for mobile PEM fuel cell applications. However, a critical challenge exists to develop new methods to regenerate these hydrides directly from the reactants and hydrogen gas. This spotlight paper presents an overview of some of the metastable metal hydrides for hydrogen storage and a few new approaches being investigated to address the key challenges associated with these materials.« less

  15. Results of NDE Technique Evaluation of Clad Hydrides

    SciTech Connect (OSTI)

    Dennis C. Kunerth

    2014-09-01

    This report fulfills the M4 milestone, M4FT-14IN0805023, Results of NDE Technique Evaluation of Clad Hydrides, under Work Package Number FT-14IN080502. During service, zirconium alloy fuel cladding will degrade via corrosion/oxidation. Hydrogen, a byproduct of the oxidation process, will be absorbed into the cladding and eventually form hydrides due to low hydrogen solubility limits. The hydride phase is detrimental to the mechanical properties of the cladding and therefore it is important to be able to detect and characterize the presence of this constituent within the cladding. Presently, hydrides are evaluated using destructive examination. If nondestructive evaluation techniques can be used to detect and characterize the hydrides, the potential exists to significantly increase test sample coverage while reducing evaluation time and cost. To demonstrate the viability this approach, an initial evaluation of eddy current and ultrasonic techniques were performed to demonstrate the basic ability to these techniques to detect hydrides or their effects on the microstructure. Conventional continuous wave eddy current techniques were applied to zirconium based cladding test samples thermally processed with hydrogen gas to promote the absorption of hydrogen and subsequent formation of hydrides. The results of the evaluation demonstrate that eddy current inspection approaches have the potential to detect both the physical damage induced by hydrides, e.g. blisters and cracking, as well as the combined effects of absorbed hydrogen and hydride precipitates on the electrical properties of the zirconium alloy. Similarly, measurements of ultrasonic wave velocities indicate changes in the elastic properties resulting from the combined effects of absorbed hydrogen and hydride precipitates as well as changes in geometry in regions of severe degradation. However, for both approaches, the signal responses intended to make the desired measurement incorporate a number of contributing parameters. These contributing factors need to be recognized and a means to control them or separate their contributions will be required to obtain the desired information.

  16. Destabilization of magnesium hydride through interface engineering

    E-Print Network [OSTI]

    Dam, Bernard

    Destabilization of magnesium hydride through interface engineering Lennard Mooij #12;Destabilization of magnesium hydride through interface engineering PROEFSCHRIFT ter verkrijging van de graad van . . . . . . . . . . . . . . . . . . . . . . . . . 10 1.3 Magnesium hydride . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13 1

  17. Method for preparing porous metal hydride compacts

    DOE Patents [OSTI]

    Ron, M.; Gruen, D.M.; Mendelsohn, M.H.; Sheft, I.

    1980-01-21

    A method for preparing porous metallic-matrix hydride compacts which can be repeatedly hydrided and dehydrided without disintegration. A mixture of a finely divided metal hydride and a finely divided matrix metal is contacted with a poison which prevents the metal hydride from dehydriding at room temperature and atmospheric pressure. The mixture of matrix metal and poisoned metal hydride is then compacted under pressure at room temperature to form porous metallic-matrix hydride compacts.

  18. Method for preparing porous metal hydride compacts

    DOE Patents [OSTI]

    Ron, Moshe (Haifa, IL); Gruen, Dieter M. (Downers Grove, IL); Mendelsohn, Marshall H. (Woodridge, IL); Sheft, Irving (Oak Park, IL)

    1981-01-01

    A method for preparing porous metallic-matrix hydride compacts which can be repeatedly hydrided and dehydrided without disintegration. A mixture of a finely divided metal hydride and a finely divided matrix metal is contacted with a poison which prevents the metal hydride from dehydriding at room temperature and atmospheric pressure. The mixture of matrix metal and poisoned metal hydride is then compacted under pressure at room temperature to form porous metallic-matrix hydride compacts.

  19. Dimensionally stable metallic hydride composition

    DOE Patents [OSTI]

    Heung, Leung K. (Aiken, SC)

    1994-01-01

    A stable, metallic hydride composition and a process for making such a composition. The composition comprises a uniformly blended mixture of a metal hydride, kieselguhr, and a ballast metal, all in the form of particles. The composition is made by subjecting a metal hydride to one or more hydrogen absorption/desorption cycles to disintegrate the hydride particles to less than approximately 100 microns in size. The particles are partly oxidized, then blended with the ballast metal and the kieselguhr to form a uniform mixture. The mixture is compressed into pellets and calcined. Preferably, the mixture includes approximately 10 vol. % or more kieselguhr and approximately 50 vol. % or more ballast. Metal hydrides that can be used in the composition include Zr, Ti, V, Nb, Pd, as well as binary, tertiary, and more complex alloys of La, Al, Cu, Ti, Co, Ni, Fe, Zr, Mg, Ca, Mn, and mixtures and other combinations thereof. Ballast metals include Al, Cu and Ni.

  20. Optimization of Hydride Rim Formation in Unirradiated Zr 4 Cladding

    SciTech Connect (OSTI)

    Shimskey, Rick W.; Hanson, Brady D.; MacFarlan, Paul J.

    2013-09-30

    The purpose of this work is to build on the results reported in the M2 milestone M2FT 13PN0805051, document number FCRD-USED-2013-000151 (Hanson, 2013). In that work, it was demonstrated that unirradiated samples of zircaloy-4 cladding could be pre-hydrided at temperatures below 400°C in pure hydrogen gas and that the growth of hydrides on the surface could be controlled by changing the surface condition of the samples and form a desired hydride rim on the outside diameter of the cladding. The work performed at Pacific Northwest National Laboratory since the issuing of the M2 milestone has focused its efforts to optimize the formation of a hydride rim on available zircaloy-4 cladding samples by controlling temperature variation and gas flow control during pre-hydriding treatments. Surface conditioning of the outside surface was also examined as a variable. The results of test indicate that much of the variability in the hydride thickness is due to temperature variation occurring in the furnaces as well as how hydrogen gas flows across the sample surface. Efforts to examine other alloys, gas concentrations, and different surface conditioning plan to be pursed in the next FY as more cladding samples become available

  1. Low density metal hydride foams

    DOE Patents [OSTI]

    Maienschein, Jon L. (Oakland, CA); Barry, Patrick E. (Pleasant Hill, CA)

    1991-01-01

    Disclosed is a low density foam having a porosity of from 0 to 98% and a density less than about 0.67 gm/cc, prepared by heating a mixture of powered lithium hydride and beryllium hydride in an inert atmosphere at a temperature ranging from about 455 to about 490 K for a period of time sufficient to cause foaming of said mixture, and cooling the foam thus produced. Also disclosed is the process of making the foam.

  2. Hydrogen, lithium, and lithium hydride production

    DOE Patents [OSTI]

    Brown, Sam W; Spencer, Larry S; Phillips, Michael R; Powell, G. Louis; Campbell, Peggy J

    2014-03-25

    A method of producing high purity lithium metal is provided, where gaseous-phase lithium metal is extracted from lithium hydride and condensed to form solid high purity lithium metal. The high purity lithium metal may be hydrided to provide high purity lithium hydride.

  3. Ab initio treatment of electron correlations in polymers: Lithium hydride chain and beryllium hydride polymer

    E-Print Network [OSTI]

    Birkenheuer, Uwe

    Ab initio treatment of electron correlations in polymers: Lithium hydride chain and berylliumH and beryllium hydride Be2H4 . First, employing a Wannier-function-based approach, the systems are studiedH and the beryllium hydride polymer Be2H4 . As a simple, but due to its ionic character, non- trivial model polymer

  4. Complex hydrides for hydrogen storage

    DOE Patents [OSTI]

    Zidan, Ragaiy

    2006-08-22

    A hydrogen storage material and process of forming the material is provided in which complex hydrides are combined under conditions of elevated temperatures and/or elevated temperature and pressure with a titanium metal such as titanium butoxide. The resulting fused product exhibits hydrogen desorption kinetics having a first hydrogen release point which occurs at normal atmospheres and at a temperature between 50.degree. C. and 90.degree. C.

  5. Incorporation of Hydride Nuclear Fuels in Commercial Light Water Reactors

    E-Print Network [OSTI]

    Terrani, Kurt Amir

    2010-01-01

    1.2.1 PWRs . . . . . . . . . . . . . . . . . . . . 1.2.2Actinides Multi-Recycling in PWR Using Hydride Fuels. InRecycling in Hydride Fueled PWR Cores. Nuclear Engineering

  6. Direct synthesis of catalyzed hydride compounds

    DOE Patents [OSTI]

    Gross, Karl J.; Majzoub, Eric

    2004-09-21

    A method is disclosed for directly preparing alkali metal aluminum hydrides such as NaAlH.sub.4 and Na.sub.3 AlH.sub.6 from either the alkali metal or its hydride, and aluminum. The hydride thus prepared is doped with a small portion of a transition metal catalyst compound, such as TiCl.sub.3, TiF.sub.3, or a mixture of these materials, in order to render them reversibly hydridable. The process provides for mechanically mixing the dry reagents under an inert atmosphere followed by charging the mixed materials with high pressure hydrogen while heating the mixture to about 125.degree. C. The method is relatively simple and inexpensive and provides reversible hydride compounds which are free of the usual contamination introduced by prior art wet chemical methods.

  7. Activated aluminum hydride hydrogen storage compositions and uses thereof

    DOE Patents [OSTI]

    Sandrock, Gary (Ringwood, NJ); Reilly, James (Bellport, NY); Graetz, Jason (Mastic, NY); Wegrzyn, James E. (Brookhaven, NY)

    2010-11-23

    In one aspect, the invention relates to activated aluminum hydride hydrogen storage compositions containing aluminum hydride in the presence of, or absence of, hydrogen desorption stimulants. The invention particularly relates to such compositions having one or more hydrogen desorption stimulants selected from metal hydrides and metal aluminum hydrides. In another aspect, the invention relates to methods for generating hydrogen from such hydrogen storage compositions.

  8. Wire Wrapped Hexagonal Pin Arrays for Hydride Fueled PWRs

    E-Print Network [OSTI]

    Diller, Peter

    This work contributes to the Hydride Fuels Project, a collaborative effort between UC Berkeley and MIT

  9. Hydrogen-storing hydride complexes

    DOE Patents [OSTI]

    Srinivasan, Sesha S. (Tampa, FL); Niemann, Michael U. (Venice, FL); Goswami, D. Yogi (Tampa, FL); Stefanakos, Elias K. (Tampa, FL)

    2012-04-10

    A ternary hydrogen storage system having a constant stoichiometric molar ratio of LiNH.sub.2:MgH.sub.2:LiBH.sub.4 of 2:1:1. It was found that the incorporation of MgH.sub.2 particles of approximately 10 nm to 20 nm exhibit a lower initial hydrogen release temperature of 150.degree. C. Furthermore, it is observed that the particle size of LiBNH quaternary hydride has a significant effect on the hydrogen sorption concentration with an optimum size of 28 nm. The as-synthesized hydrides exhibit two main hydrogen release temperatures, one around 160.degree. C. and the other around 300.degree. C., with the main hydrogen release temperature reduced from 310.degree. C. to 270.degree. C., while hydrogen is first reversibly released at temperatures as low as 150.degree. C. with a total hydrogen capacity of 6 wt. % to 8 wt. %. Detailed thermal, capacity, structural and microstructural properties have been demonstrated and correlated with the activation energies of these materials.

  10. Liquid suspensions of reversible metal hydrides

    DOE Patents [OSTI]

    Reilly, J.J.; Grohse, E.W.; Winsche, W.E.

    1983-12-08

    The reversibility of the process M + x/2 H/sub 2/ ..-->.. MH/sub x/, where M is a metal hydride former that forms a hydride MH/sub x/ in the presence of H/sub 2/, generally used to store and recall H/sub 2/, is found to proceed under a liquid, thereby to reduce contamination, provide better temperature control and provide in situ mobility of the reactants. Thus, a slurry of particles of a metal hydride former with an inert solvent is subjected to temperature and pressure controlled atmosphere containing H/sub 2/, to store hydrogen (at high pressures) and to release (at low pressures) previously stored hydrogen. The direction of the flow of the H/sub 2/ through the liquid is dependent upon the H/sub 2/ pressure in the gas phase at a given temperature. When the former is above the equilibrium absorption pressure of the respective hydride the reaction proceeds to the right, i.e., the metal hydride is formed and hydrogen is stored in the solid particle. When the H/sub 2/ pressure in the gas phase is below the equilibrium dissociation pressure of the respective hydride the reaction proceeds to the left, the metal hydride is decomposed and hydrogen is released into the gas phase.

  11. METALLIC HYDRIDES. Magnetic properties of laves-phase rare earth hydrides

    E-Print Network [OSTI]

    Boyer, Edmond

    METALLIC HYDRIDES. Magnetic properties of laves-phase rare earth hydrides J. J. Rhyne and G. E on the rare earth site. The rare earth spins disorder at a temperature lower than the bulk Tc in ErFe2 H3 5 per formula unit assuming complete occupation of 3 tetrahedral sites. The heavy rare earth (RFe2

  12. Optimization of hydride fueled pressurized water reactor cores

    E-Print Network [OSTI]

    Shuffler, Carter Alexander

    2004-01-01

    This thesis contributes to the Hydride Fuels Project, a collaborative effort between UC Berkeley and MIT aimed at investigating the potential benefits of hydride fuel use in light water reactors (LWRs). This pursuit involves ...

  13. Advances in Design of the Next Generation Hydride Bed | Department...

    Office of Environmental Management (EM)

    Design of the Next Generation Hydride Bed Advances in Design of the Next Generation Hydride Bed Presentation from the 32nd Tritium Focus Group Meeting held in Germantown, Maryland...

  14. Thermal hydraulic analysis of hydride fuels in BWR's

    E-Print Network [OSTI]

    Creighton, John Everett

    2005-01-01

    This thesis contributes to the hydride nuclear fuel project being completed by UC Berkeley and MIT to assess the possible benefits of using hydride fuel in light water nuclear reactors (LWR's). More specifically, this ...

  15. Friction Stir Welding of Hydrided Titanium Alloys Mark Taylor, D.P. Field

    E-Print Network [OSTI]

    Collins, Gary S.

    Friction Stir Welding of Hydrided Titanium Alloys Mark Taylor, D.P. Field Multi-Scale Engineering for Undergraduates program under grant number EEC-0754370 During Friction Stir Welding (FSW), a non-consumable tool-state welding process, much frictional heating and force is required of the tool. This steep demand on the tool

  16. Atomistic Potentials for Palladium-Silver Hydrides

    E-Print Network [OSTI]

    Hale, L M; Zimmerman, J A; Zhou, X

    2013-01-01

    New EAM potentials for the ternary palladium-silver-hydrogen system are developed by extending a previously developed palladium-hydrogen potential. The ternary potentials accurately capture the heat of mixing and structural properties associated with solid solution alloys of palladium-silver. Stable hydrides are produced with properties that smoothly transition across the compositions. Additions of silver to palladium are predicted to alter the properties of the hydrides by decreasing the miscibility gap and increasing the likelihood of hydrogen atoms occupying tetrahedral interstitial sites over octahedral interstitial sites.

  17. Metal hydride fuel storage and method thereof

    DOE Patents [OSTI]

    Morse, Jeffrey D. (Martinez, CA); Jankowski, Alan F. (Livermore, CA); Yu, Conrad (Antioch, CA)

    2006-10-17

    Disclosed herein is a metal hydride fuel storage cartridge having integrated resistive heaters that can be used in conjunction with fuel cells such as MEMS-based fuel cells. The cartridge is fabricated using micromachining methods and thin/thick film materials synthesis techniques.

  18. Metal hydride fuel storage and method thereof

    DOE Patents [OSTI]

    Morse, Jeffrey D [Martinez, CA; Jankowski, Alan F [Livermore, CA; Yu, Conrad [Antioch, CA

    2009-05-05

    Disclosed herein is a metal hydride fuel storage cartridge having integrated resistive heaters that can be used in conjunction with fuel cells such as MEMS-based fuel cells. The cartridge is fabricated using micromachining methods and thin/thick film materials synthesis techniques.

  19. SANS Measurement of Hydrides in Uranium

    SciTech Connect (OSTI)

    Spooner, S; Ludtka, G.M.; Bullock, J.S.; Bridges, R.L.; Powell, G.L.

    2001-09-04

    SANS scattering is shown to be an effective method for detecting the presence of hydrogen precipitates in uranium. High purity polycrystalline samples of depleted uranium were given several hydriding treatments which included extended exposures to hydrogen gas at two different pressures at 630 C as well as a furnace anneal at 850 C followed by slow cooling in the near absence hydrogen gas. All samples exhibited neutron scattering that was in proportion to the expected levels of hydrogen content. While the scattering signal was strong, the shape of the scattering curve indicated that the scattering objects were large sized objects. Only by use of a very high angular resolution SANS technique was it possible to make estimates of the major diameter of the scattering objects. This analysis permits an estimate of the volume fraction and means size of the hydride precipitates in uranium.

  20. METAL HYDRIDE HYDROGEN COMPRESSORS: A REVIEW

    SciTech Connect (OSTI)

    Bowman Jr, Robert C; Yartys, Dr. Volodymyr A.; Lototskyy, Dr. Michael V; Pollet, Dr. B.G.

    2014-01-01

    Metal hydride (MH) thermal sorption compression is an efficient and reliable method allowing a conversion of energy from heat into a compressed hydrogen gas. The most important component of such a thermal engine the metal hydride material itself should possess several material features in order to achieve an efficient performance in the hydrogen compression. Apart from the hydrogen storage characteristics important for every solid H storage material (e.g. gravimetric and volumetric efficiency of H storage, hydrogen sorption kinetics and effective thermal conductivity), the thermodynamics of the metal-hydrogen systems is of primary importance resulting in a temperature dependence of the absorption/desorption pressures). Several specific features should be optimized to govern the performance of the MH-compressors including synchronisation of the pressure plateaus for multi-stage compressors, reduction of slope of the isotherms and hysteresis, increase of cycling stability and life time, together with challenges in system design associated with volume expansion of the metal matrix during the hydrogenation. The present review summarises numerous papers and patent literature dealing with MH hydrogen compression technology. The review considers (a) fundamental aspects of materials development with a focus on structure and phase equilibria in the metal-hydrogen systems suitable for the hydrogen compression; and (b) applied aspects, including their consideration from the applied thermodynamic viewpoint, system design features and performances of the metal hydride compressors and major applications.

  1. Incorporation of Hydride Nuclear Fuels in Commercial Light Water Reactors

    E-Print Network [OSTI]

    Terrani, Kurt Amir

    2010-01-01

    Uranium in the fuel remains metallic since the equilibriumtype of hydride fuel consists of metallic uranium particlesalloying the metallic components of the fuel followed by a

  2. Documentation of Hybrid Hydride Model for Incorporation into...

    Energy Savers [EERE]

    does not currently solve the stress state that forms dynamically in the precipitate or matrix surrounding the precipitate. A path forward is presented. DocHybridHydrid...

  3. Incorporation of Hydride Nuclear Fuels in Commercial Light Water Reactors

    E-Print Network [OSTI]

    Terrani, Kurt Amir

    2010-01-01

    filled gap between the zirconia layer and the hydride fuel (calculated peaks for zirconia is possibly due to preferredpossibly coupled with a thin zirconia layer, as a kinetic

  4. Neutron Irradiation of Hydrided Cladding Material in HFIR Summary...

    Broader source: Energy.gov (indexed) [DOE]

    Nuclear Fuel Vibration Integrity Investigations Model for Simulation of Hydride Precipitation in Zr-Based Used Fuel Claddings: A Status Report on Current Model Capabilities...

  5. LANL/PNNL Virtual Center for Chemical Hydrides and New Concepts...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    LANLPNNL Virtual Center for Chemical Hydrides and New Concepts for Hydrogen Storage LANLPNNL Virtual Center for Chemical Hydrides and New Concepts for Hydrogen Storage...

  6. Metal Hydride Thermal Storage: Reversible Metal Hydride Thermal Storage for High-Temperature Power Generation Systems

    SciTech Connect (OSTI)

    2011-12-05

    HEATS Project: PNNL is developing a thermal energy storage system based on a Reversible Metal Hydride Thermochemical (RMHT) system, which uses metal hydride as a heat storage material. Heat storage materials are critical to the energy storage process. In solar thermal storage systems, heat can be stored in these materials during the day and released at night—when the sun is not out—to drive a turbine and produce electricity. In nuclear storage systems, heat can be stored in these materials at night and released to produce electricity during daytime peak-demand hours. PNNL’s metal hydride material can reversibly store heat as hydrogen cycles in and out of the material. In a RHMT system, metal hydrides remain stable in high temperatures (600- 800°C). A high-temperature tank in PNNL’s storage system releases heat as hydrogen is absorbed, and a low-temperature tank stores the heat until it is needed. The low-cost material and simplicity of PNNL’s thermal energy storage system is expected to keep costs down. The system has the potential to significantly increase energy density.

  7. Method of making crack-free zirconium hydride

    DOE Patents [OSTI]

    Sullivan, Richard W. (Denver, CO)

    1980-01-01

    Crack-free hydrides of zirconium and zirconium-uranium alloys are produced by alloying the zirconium or zirconium-uranium alloy with beryllium, or nickel, or beryllium and scandium, or nickel and scandium, or beryllium and nickel, or beryllium, nickel and scandium and thereafter hydriding.

  8. Metal Hydrides for High-Temperature Power Generation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ronnebro, Ewa; Whyatt, Greg A.; Powell, Michael R.; Westman, Matthew P.; Zheng, Feng; Fang, Zhigang Zak

    2015-08-10

    Metal hydrides can be utilized for hydrogen storage and for thermal energy storage (TES) applications. By using TES with solar technologies, heat can be stored from sun energy to be used later which enables continuous power generation. We are developing a TES technology based on a dual-bed metal hydride system, which has a high-temperature (HT) metal hydride operating reversibly at 600-800°C to generate heat as well as a low-temperature (LT) hydride near room temperature that is used for hydrogen storage during sun hours until there is a need to produce electricity, such as during night time, a cloudy day, ormore »during peak hours. We proceeded from selecting a high-energy density, low-cost HT-hydride based on performance characterization on gram size samples, to scale-up to kilogram quantities and design, fabrication and testing of a 1.5kWh, 200kWh/m3 bench-scale TES prototype based on a HT-bed of titanium hydride and a hydrogen gas storage instead of a LT-hydride. COMSOL Multiphysics was used to make performance predictions for cylindrical hydride beds with varying diameters and thermal conductivities. Based on experimental and modeling results, a bench-scale prototype was designed and fabricated and we successfully showed feasibility to meet or exceed all performance targets.« less

  9. Porous metal hydride composite and preparation and uses thereof

    DOE Patents [OSTI]

    Steyert, William A. (Los Alamos, NM); Olsen, Clayton E. (Los Alamos, NM)

    1982-01-01

    A composite formed from large pieces of aggregate formed from (1) metal hydride (or hydride-former) powder and (2) either metal powder or plastic powder or both is prepared. The composite has large macroscopic interconnected pores (much larger than the sizes of the powders which are used) and will have a very fast heat transfer rate and low windage loss. It will be useful, for example, in heat engines, hydrogen storage devices, and refrigerator components which depend for their utility upon both a fast rate of hydriding and dehydriding. Additionally, a method of preparing the composite and a method of increasing the rates of hydriding and dehydriding of metal hydrides are also given.

  10. Porous metal hydride composite and preparation and uses thereof

    DOE Patents [OSTI]

    Steyert, W.A.; Olsen, C.E.

    1980-03-12

    A composite formed from large pieces of aggregate formed from (1) metal hydride (or hydride-former) powder and (2) either metal powder or plastic powder or both is prepared. The composite has large macroscopic interconnected pores (much larger than the sizes of the powders which are used) and will have a very fast heat transfer rate and low windage loss. It will be useful, for example, in heat engines, hydrogen storage devices, and refrigerator components which depend for their utility upon both a fast rate of hydriding and dehydriding. Additionally, a method of preparing the composite and a method of increasing the rates of hydriding and dehydriding of metal hydrides are also given.

  11. Recent advances in metal hydrides for clean energy applications

    SciTech Connect (OSTI)

    Ronnebro, Ewa; Majzoub, Eric H.

    2013-06-01

    Metal hydrides are a fascinating class of materials that can be utilized for a surprising variety of clean energy applications, including smart solar collectors, smart windows, sensors, thermal energy storage, and batteries, in addition to their traditional application for hydrogen storage. Over the past decade, research on metal hydrides for hydrogen storage increased due to global governmental incentives and an increased focus on hydrogen storage research for polymer electrolyte membrane fuel cell operation. Tremendous progress has been made in so-called complex metal hydrides for hydrogen storage applications with the discovery of many new hydrides containing covalently bound complex anions. Many of these materials have applications beyond hydrogen storage and are being investigated for lithium-ion battery separator and anode materials. In this issue of MRS Bulletin , we present the state of the art of key evolving metal-hydride-based clean energy technologies with an outlook toward future needs.

  12. Highly Concentrated Palladium Hydrides/Deuterides; Theory

    SciTech Connect (OSTI)

    Papaconstantopoulos, Dimitrios

    2013-11-26

    Accomplishments are reported in these areas: tight-binding molecular dynamics study of palladium; First-principles calculations and tight-binding molecular dynamics simulations of the palladium-hydrogen system; tight-binding studies of bulk properties and hydrogen vacancies in KBH{sub 4}; tight-binding study of boron structures; development of angular dependent potentials for Pd-H; and density functional and tight-binding calculations for the light-hydrides NaAlH4 and NaBH4

  13. Metal hydride fuel storage and method thereof

    DOE Patents [OSTI]

    Morse, Jeffrey D. (Martinez, CA); Jankowski, Alan F. (Livermore, CA); Yu, Conrad (Antioch, CA)

    2010-08-10

    An apparatus having a first substrate having (1) a cavity, (2) one or more resistive heaters, and (3) one or more coatings forming a diffusion barrier to hydrogen; a second substrate having (1) an outlet valve comprising a pressure relief structure and (2) one or more coatings forming a diffusion barrier to hydrogen, wherein said second substrate is coupled to said first substrate forming a sealed volume in said cavity; a metal hydride material contained within said cavity; and a gas distribution system formed by coupling a microfluidic interconnect to said pressure relief structure. Additional apparatuses and methods are also disclosed.

  14. Experimental Validation of Voltage-Based State-of-Charge Algorithm for Power Batteries

    E-Print Network [OSTI]

    Jia, Zhuo

    2013-01-01

    for nickel metal hydride batteries including hysteresis” ,Control of Lithium-Ion Batteries”, Control Systems, IEEE,modeling of lead acid batteries”, Applied Power Electronics

  15. Recycling Programs | Department of Energy

    Energy Savers [EERE]

    Germantown Paperclips Supply Stores. Batteries accepted for recycling are: Alkaline, Lithium Ion, Nickel Cadmium (Ni-Cd), Nickel-Iron, and Nickel Metal Hydride (NiMH). Toner...

  16. Carbon-Fluorine Bond Cleavage by Zirconium Metal Hydride Complexes

    E-Print Network [OSTI]

    Jones, William D.

    Carbon-Fluorine Bond Cleavage by Zirconium Metal Hydride Complexes Brian L. Edelbach, A. K. Fazlur, Rochester, New York 14627 Received April 8, 1999 The zirconium hydride dimer [Cp2ZrH2]2 reacts with C6F6. [Cp2ZrH2]2 reacts with C6F5H to give Cp2Zr(p-C6F4H)F, Cp2ZrF2, C6F4H2, and H2. The zirconium hydride

  17. Chemical Hydride Slurry for Hydrogen Production and Storage

    SciTech Connect (OSTI)

    McClaine, Andrew W.

    2008-09-30

    The purpose of this project was to investigate and evaluate the attractiveness of using a magnesium chemical hydride slurry as a hydrogen storage, delivery, and production medium for automobiles. To fully evaluate the potential for magnesium hydride slurry to act as a carrier of hydrogen, potential slurry compositions, potential hydrogen release techniques, and the processes (and their costs) that will be used to recycle the byproducts back to a high hydrogen content slurry were evaluated. A 75% MgH2 slurry was demonstrated, which was just short of the 76% goal. This slurry is pumpable and storable for months at a time at room temperature and pressure conditions and it has the consistency of paint. Two techniques were demonstrated for reacting the slurry with water to release hydrogen. The first technique was a continuous mixing process that was tested for several hours at a time and demonstrated operation without external heat addition. Further work will be required to reduce this design to a reliable, robust system. The second technique was a semi-continuous process. It was demonstrated on a 2 kWh scale. This system operated continuously and reliably for hours at a time, including starts and stops. This process could be readily reduced to practice for commercial applications. The processes and costs associated with recycling the byproducts of the water/slurry reaction were also evaluated. This included recovering and recycling the oils of the slurry, reforming the magnesium hydroxide and magnesium oxide byproduct to magnesium metal, hydriding the magnesium metal with hydrogen to form magnesium hydride, and preparing the slurry. We found that the SOM process, under development by Boston University, offers the lowest cost alternative for producing and recycling the slurry. Using the H2A framework, a total cost of production, delivery, and distribution of $4.50/kg of hydrogen delivered or $4.50/gge was determined. Experiments performed at Boston University have demonstrated the technical viability of the process and have provided data for the cost analyses that have been performed. We also concluded that a carbothermic process could also produce magnesium at acceptable costs. The use of slurry as a medium to carry chemical hydrides has been shown during this project to offer significant advantages for storing, delivering, and distributing hydrogen: • Magnesium hydride slurry is stable for months and pumpable. • The oils of the slurry minimize the contact of oxygen and moisture in the air with the metal hydride in the slurry. Thus reactive chemicals, such as lithium hydride, can be handled safely in the air when encased in the oils of the slurry. • Though magnesium hydride offers an additional safety feature of not reacting readily with water at room temperatures, it does react readily with water at temperatures above the boiling point of water. Thus when hydrogen is needed, the slurry and water are heated until the reaction begins, then the reaction energy provides heat for more slurry and water to be heated. • The reaction system can be relatively small and light and the slurry can be stored in conventional liquid fuel tanks. When transported and stored, the conventional liquid fuel infrastructure can be used. • The particular metal hydride of interest in this project, magnesium hydride, forms benign byproducts, magnesium hydroxide (“Milk of Magnesia”) and magnesium oxide. • We have estimated that a magnesium hydride slurry system (including the mixer device and tanks) could meet the DOE 2010 energy density goals. ? During the investigation of hydriding techniques, we learned that magnesium hydride in a slurry can also be cycled in a rechargeable fashion. Thus, magnesium hydride slurry can act either as a chemical hydride storage medium or as a rechargeable hydride storage system. Hydrogen can be stored and delivered and then stored again thus significantly reducing the cost of storing and delivering hydrogen. Further evaluation and development of this concept will be performed as follow-on work under a

  18. The Hydriding Kinetics of Organic Hydrogen Getters

    SciTech Connect (OSTI)

    Powell, G. L.

    2002-02-11

    The aging of hermetically sealed systems is often accompanied by the gradual production of hydrogen gas that is a result of the decay of environmental gases and the degradation of organic materials. In particular, the oxygen, water, hydrogen ''equilibrium'' is affected by the removal of oxygen due the oxidation of metals and organic materials. This shift of the above ''equilibrium'' towards the formation of hydrogen gas, particularly in crevices, may eventually reach an explosive level of hydrogen gas or degrade metals by hydriding them. The latter process is generally delayed until the oxidizing species are significantly reduced. Organic hydrogen getters introduced by Allied Signal Aerospace Company, Kansas City Division have proven to be a very effective means of preventing hydrogen gas accumulation in sealed containers. These getters are relatively unaffected by air and environmental gases. They can be packaged in a variety of ways to fit particular needs such as porous pellets, fine or coarse [gravel] powder, or loaded into silicone rubber. The hydrogen gettering reactions are extremely irreversible since the hydrogen gas is converted into an organic hydrocarbon. These getters are based on the palladium-catalyzed hydrogenation of triple bonds to double and then single bonds in aromatic aryl compounds. DEB (1,4 bis (phenyl ethynyl) benzene) typically mixed with 25% by weight carbon with palladium (1% by weight of carbon) is one of the newest and best of these organic hydrogen getters. The reaction mechanisms are complex involving solid state reaction with a heterogeneous catalyst leading to the many intermediates, including mixed alkyl and aryl hydrocarbons with the possibilities of many isomers. The reaction kinetics mechanisms are also strongly influenced by the form in which they are packaged. For example, the hydriding rates for pellets and gravel have a strong dependence on reaction extent (i.e., DEB reduction) and a kinetic order in pressure of 0.76. Silicone rubber based DEB getters hydride at a much lower rate, have little dependence on reaction extent, have a higher kinetic order in pressure (0.87), and have a lower activation energy. The kinetics of the reaction as a function of hydrogen pressure, stoichiometry, and temperature for hydrogen and deuterium near ambient temperature (0 to 75 C) for pressures near or below 100 Pa over a wide range (in some cases, the complete) hydrogenation range are presented along with multi-dimensional rate models.

  19. A new phase in palladium hydride technology

    SciTech Connect (OSTI)

    Walters, R.T.

    1991-01-01

    Two plateaux are observed in both the absorption and desorption isotherms of palladium hydride. For the absorption isotherm, a change in plateau pressure is observed at a hydrogen-to-metal (H/M) ratio of about 0.35 for all temperatures studied. For the desorption isotherm, the change in plateau pressure appears to be a function of temperature, ranging from an H/M ratio of 0.18 at 80{degrees}C to 0.3 at 140{degrees}C. These data are interpreted as being experimentally observed boundaries to an equilibrium phase line located in the miscibility gap of the palladium/hydrogen phase diagram. This new phase does not appear to be a stoichiometric compounds, but rather its composition seems to vary with temperature. 6 refs., 4 figs.

  20. A new phase in palladium hydride technology

    SciTech Connect (OSTI)

    Walters, R.T.

    1991-12-31

    Two plateaux are observed in both the absorption and desorption isotherms of palladium hydride. For the absorption isotherm, a change in plateau pressure is observed at a hydrogen-to-metal (H/M) ratio of about 0.35 for all temperatures studied. For the desorption isotherm, the change in plateau pressure appears to be a function of temperature, ranging from an H/M ratio of 0.18 at 80{degrees}C to 0.3 at 140{degrees}C. These data are interpreted as being experimentally observed boundaries to an equilibrium phase line located in the miscibility gap of the palladium/hydrogen phase diagram. This new phase does not appear to be a stoichiometric compounds, but rather its composition seems to vary with temperature. 6 refs., 4 figs.

  1. Ni/metal hydride secondary element

    DOE Patents [OSTI]

    Bauerlein, Peter

    2005-04-19

    A Ni/metal hydride secondary element having a positive nickel hydroxide electrode, a negative electrode having a hydrogen storage alloy, and an alkaline electrolyte, the positive electrode, provided with a three-dimensional metallic conductive structure, also contains an aluminum compound which is soluble in the electrolyte, in addition to nickel hydroxide and cobalt oxide. The aluminum compound is aluminum hydroxide and/or aluminum oxide, and the mass of the aluminum compound which is present in the positive bulk material mixture is 0.1 to 2% by weight relative to the mass of the nickel hydroxide which is present. In combination with aluminum hydroxide or aluminum oxide, the positive electrode further contains lanthanoid oxidic compounds Y.sub.2 O.sub.3, La.sub.2 O.sub.3 and Ca(OH).sub.2, as well as mixtures of these compounds.

  2. Process for production of a metal hydride

    DOE Patents [OSTI]

    Allen, Nathan Tait; Butterick, III, Robert; Chin, Arthur Achhing; Millar, Dean Michael; Molzahn, David Craig

    2014-08-12

    A process for production of a metal hydride compound MH.sub.x, wherein x is one or two and M is an alkali metal, Be or Mg. The process comprises combining a compound of formula (R.sup.1O).sub.xM with aluminum, hydrogen and at least one metal selected from among titanium, zirconium, hafnium, niobium, vanadium, tantalum and iron to produce a compound of formula MH.sub.x. R.sup.1 is phenyl or phenyl substituted by at least one alkyl or alkoxy group. A mole ratio of aluminum to (R.sup.1O).sub.xM is from 0.1:1 to 1:1. The catalyst is present at a level of at least 200 ppm based on weight of aluminum.

  3. Complex Hydride Compounds with Enhanced Hydrogen Storage Capacity

    SciTech Connect (OSTI)

    Mosher, Daniel A.; Opalka, Susanne M.; Tang, Xia; Laube, Bruce L.; Brown, Ronald J.; Vanderspurt, Thomas H.; Arsenault, Sarah; Wu, Robert; Strickler, Jamie; Anton, Donald L.; Zidan, Ragaiy; Berseth, Polly

    2008-02-18

    The United Technologies Research Center (UTRC), in collaboration with major partners Albemarle Corporation (Albemarle) and the Savannah River National Laboratory (SRNL), conducted research to discover new hydride materials for the storage of hydrogen having on-board reversibility and a target gravimetric capacity of ? 7.5 weight percent (wt %). When integrated into a system with a reasonable efficiency of 60% (mass of hydride / total mass), this target material would produce a system gravimetric capacity of ? 4.5 wt %, consistent with the DOE 2007 target. The approach established for the project combined first principles modeling (FPM - UTRC) with multiple synthesis methods: Solid State Processing (SSP - UTRC), Solution Based Processing (SBP - Albemarle) and Molten State Processing (MSP - SRNL). In the search for novel compounds, each of these methods has advantages and disadvantages; by combining them, the potential for success was increased. During the project, UTRC refined its FPM framework which includes ground state (0 Kelvin) structural determinations, elevated temperature thermodynamic predictions and thermodynamic / phase diagram calculations. This modeling was used both to precede synthesis in a virtual search for new compounds and after initial synthesis to examine reaction details and options for modifications including co-reactant additions. The SSP synthesis method involved high energy ball milling which was simple, efficient for small batches and has proven effective for other storage material compositions. The SBP method produced very homogeneous chemical reactions, some of which cannot be performed via solid state routes, and would be the preferred approach for large scale production. The MSP technique is similar to the SSP method, but involves higher temperature and hydrogen pressure conditions to achieve greater species mobility. During the initial phases of the project, the focus was on higher order alanate complexes in the phase space between alkaline metal hydrides (AmH), Alkaline earth metal hydrides (AeH2), alane (AlH3), transition metal (Tm) hydrides (TmHz, where z=1-3) and molecular hydrogen (H2). The effort started first with variations of known alanates and subsequently extended the search to unknown compounds. In this stage, the FPM techniques were developed and validated on known alanate materials such as NaAlH4 and Na2LiAlH6. The coupled predictive methodologies were used to survey over 200 proposed phases in six quaternary spaces, formed from various combinations of Na, Li Mg and/or Ti with Al and H. A wide range of alanate compounds was examined using SSP having additions of Ti, Cr, Co, Ni and Fe. A number of compositions and reaction paths were identified having H weight fractions up to 5.6 wt %, but none meeting the 7.5 wt%H reversible goal. Similarly, MSP of alanates produced a number of interesting compounds and general conclusions regarding reaction behavior of mixtures during processing, but no alanate based candidates meeting the 7.5 wt% goal. A novel alanate, LiMg(AlH4)3, was synthesized using SBP that demonstrated a 7.0 wt% capacity with a desorption temperature of 150°C. The deuteride form was synthesized and characterized by the Institute for Energy (IFE) in Norway to determine its crystalline structure for related FPM studies. However, the reaction exhibited exothermicity and therefore was not reversible under acceptable hydrogen gas pressures for on-board recharging. After the extensive studies of alanates, the material class of emphasis was shifted to borohydrides. Through SBP, several ligand-stabilized Mg(BH4)2 complexes were synthesized. The Mg(BH4)2*2NH3 complex was found to change behavior with slightly different synthesis conditions and/or aging. One of the two mechanisms was an amine-borane (NH3BH3) like dissociation reaction which released up to 16 wt %H and more conservatively 9 wt%H when not including H2 released from the NH3. From FPM, the stability of the Mg(BH4)2*2NH3 compound was found to increase with the inclusion of NH3 groups in the inner-Mg coordination

  4. Hydrogen storage in sodium aluminum hydride.

    SciTech Connect (OSTI)

    Ozolins, Vidvuds; Herberg, J.L.; McCarty, Kevin F.; Maxwell, Robert S.; Stumpf, Roland Rudolph; Majzoub, Eric H.

    2005-11-01

    Sodium aluminum hydride, NaAlH{sub 4}, has been studied for use as a hydrogen storage material. The effect of Ti, as a few mol. % dopant in the system to increase kinetics of hydrogen sorption, is studied with respect to changes in lattice structure of the crystal. No Ti substitution is found in the crystal lattice. Electronic structure calculations indicate that the NaAlH{sub 4} and Na{sub 3}AlH{sub 6} structures are complex-ionic hydrides with Na{sup +} cations and AlH{sub 4}{sup -} and AlH{sub 6}{sup 3-} anions, respectively. Compound formation studies indicate the primary Ti-compound formed when doping the material at 33 at. % is TiAl{sub 3} , and likely Ti-Al compounds at lower doping rates. A general study of sorption kinetics of NaAlH{sub 4}, when doped with a variety of Ti-halide compounds, indicates a uniform response with the kinetics similar for all dopants. NMR multiple quantum studies of solution-doped samples indicate solvent interaction with the doped alanate. Raman spectroscopy was used to study the lattice dynamics of NaAlH{sub 4}, and illustrated the molecular ionic nature of the lattice as a separation of vibrational modes between the AlH{sub 4}{sup -} anion-modes and lattice-modes. In-situ Raman measurements indicate a stable AlH{sub 4}{sup -} anion that is stable at the melting temperature of NaAlH{sub 4}, indicating that Ti-dopants must affect the Al-H bond strength.

  5. Use of Solid Hydride Fuel for Improved long-Life LWR Core Designs

    SciTech Connect (OSTI)

    Greenspan, E

    2006-04-30

    The primary objective of this project was to assess the feasibility of improving the performance of PWR and BWR cores by using solid hydride fuels instead of the commonly used oxide fuel. The primary measure of performance considered is the bus-bar cost of electricity (COE). Additional performance measures considered are safety, fuel bundle design simplicity – in particular for BWR’s, and plutonium incineration capability. It was found that hydride fuel can safely operate in PWR’s and BWR’s without restricting the linear heat generation rate of these reactors relative to that attainable with oxide fuel. A couple of promising applications of hydride fuel in PWR’s and BWR’s were identified: (1) Eliminating dedicated water moderator volumes in BWR cores thus enabling to significantly increase the cooled fuel rods surface area as well as the coolant flow cross section area in a given volume fuel bundle while significantly reducing the heterogeneity of BWR fuel bundles thus achieving flatter pin-by-pin power distribution. The net result is a possibility to significantly increase the core power density – on the order of 30% and, possibly, more, while greatly simplifying the fuel bundle design. Implementation of the above modifications is, though, not straightforward; it requires a design of completely different control system that could probably be implemented only in newly designed plants. It also requires increasing the coolant pressure drop across the core. (2) Recycling plutonium in PWR’s more effectively than is possible with oxide fuel by virtue of a couple of unique features of hydride fuel – reduced inventory of U-238 and increased inventory of hydrogen. As a result, the hydride fuelled core achieves nearly double the average discharge burnup and the fraction of the loaded Pu it incinerates in one pass is double that of the MOX fuel. The fissile fraction of the Pu in the discharged hydride fuel is only ~2/3 that of the MOX fuel and the discharged hydride fuel is more proliferation resistant. Preliminary feasibility assessment indicates that by replacing some of the ZrH1.6 by ThH2 it will be possible to further improve the plutonium incineration capability of PWR’s. Other possibly promising applications of hydride fuel were identified but not evaluated in this work. A number of promising oxide fueled PWR core designs were also found as spin-offs of this study: (1) The optimal oxide fueled PWR core design features smaller fuel rod diameter of D=6.5 mm and a larger pitch-to-diameter ratio of P/D=1.39 than presently practiced by industry – 9.5mm and 1.326. This optimal design can provide a 30% increase in the power density and a 24% reduction in the cost of electricity (COE) provided the PWR could be designed to have the coolant pressure drop across the core increased from the reference 29 psia to 60 psia. (2) Using wire wrapped oxide fuel rods in hexagonal fuel assemblies it is possible to design PWR cores to operate at 54% higher power density than the reference PWR design that uses grid spacers and a square lattice, provided 60 psia coolant pressure drop across the core could be accommodated. Uprating existing PWR’s to use such cores could result in 40% reduction in the COE. The optimal lattice geometry is D = 8.08 mm and P/D = 1.41. The most notable advantages of wire wraps over grid spacers are their significant lower pressure drop, higher critical heat flux and improved vibrations characteristics.

  6. High capacity stabilized complex hydrides for hydrogen storage

    DOE Patents [OSTI]

    Zidan, Ragaiy; Mohtadi, Rana F; Fewox, Christopher; Sivasubramanian, Premkumar

    2014-11-11

    Complex hydrides based on Al(BH.sub.4).sub.3 are stabilized by the presence of one or more additional metal elements or organic adducts to provide high capacity hydrogen storage material.

  7. Effects of outgassing of loader chamber walls on hydriding of...

    Office of Scientific and Technical Information (OSTI)

    gas pressure. Complete process data for (1) a copper-(1.83 wt. %)beryllium wet hydrogen fired passivated (600 C-1 h) externally heated pipe hydriding chamber are reported....

  8. Investigation of Cracked Lithium Hydride Reactor Vessels

    SciTech Connect (OSTI)

    bird, e.l.; mustaleski, t.m.

    1999-06-01

    Visual examination of lithium hydride reactor vessels revealed cracks that were adjacent to welds, most of which were circumferentially located in the bottom portion of the vessels. Sections were cut from the vessels containing these cracks and examined by use of the metallograph, scanning electron microscope, and microprobe to determine the cause of cracking. Most of the cracks originated on the outer surface just outside the weld fusion line in the base material and propagated along grain boundaries. Crack depths of those examined sections ranged from {approximately}300 to 500 {micro}m. Other cracks were reported to have reached a maximum depth of 1/8 in. The primary cause of cracking was the creation of high tensile stresses associated with the differences in the coefficients of thermal expansion between the filler metal and the base metal during operation of the vessel in a thermally cyclic environment. This failure mechanism could be described as creep-type fatigue, whereby crack propagation may have been aided by the presence of brittle chromium carbides along the grain boundaries, which indicates a slightly sensitized microstructure.

  9. Synthesis and small molecule chemistry of the niobaziridine-hydride functional group

    E-Print Network [OSTI]

    Figueroa, Joshua S

    2005-01-01

    Chapter 1. Synthesis and Divergent Reactivity of the Niobaziridine-Hydride Functional Group The synthesis, characterization and reactivity of the niobaziridine-hydride complex Nb(H)([eta]˛-t- ]Bu(H)C=NAr)(N[Np]Ar)? (la-H; ...

  10. Analytical assessment of the thermal behavior of nickelemetal hydride batteries during fast charging

    E-Print Network [OSTI]

    Bahrami, Majid

    Analytical assessment of the thermal behavior of nickelemetal hydride batteries during fast (LAEC), Mechatronic Systems Engineering, School of Engineering Science, Simon Fraser University, Surrey charging of batteries Charging efficiency Integral-transformation technique Nickelemetal hydride battery

  11. Thermochemistry and Kinetics of Silicon Hydride Cluster Formation during Thermal Decomposition of Silane

    E-Print Network [OSTI]

    Swihart, Mark T.

    Thermochemistry and Kinetics of Silicon Hydride Cluster Formation during Thermal Decomposition of Silane Mark T. Swihart*, and Steven L. Girshick Department of Mechanical Engineering, Uni an extensive chemical kinetic mechanism for silicon hydride cluster formation during silane pyrolysis

  12. Structural properties and enthalpy of formation of magnesium hydride from quantum Monte Carlo calculations

    E-Print Network [OSTI]

    Alfč, Dario

    Structural properties and enthalpy of formation of magnesium hydride from quantum Monte Carlo calculations to study the structural properties of magnesium hydride MgH2 , including the pressure. INTRODUCTION The energetics of metal hydrides has recently become an issue of large scientific

  13. Enhancement of heat and mass transfer in metal hydride beds with the addition of Al plates

    E-Print Network [OSTI]

    Guo, Zhixiong "James"

    in the hydriding process with the addition of internal aluminum plates. The two-dimensional equations governing during the absorption/desorption process in the metal hydride beds. The main factors governing the metal hydride matrix and kinetics of the hydrogen sorption processes, etc. By ne- glecting the hydrogen

  14. Composite Materials for Hazard Mitigation of Reactive Metal Hydrides.

    SciTech Connect (OSTI)

    Pratt, Joseph William; Cordaro, Joseph Gabriel; Sartor, George B.; Dedrick, Daniel E.; Reeder, Craig L.

    2012-02-01

    In an attempt to mitigate the hazards associated with storing large quantities of reactive metal hydrides, polymer composite materials were synthesized and tested under simulated usage and accident conditions. The composites were made by polymerizing vinyl monomers using free-radical polymerization chemistry, in the presence of the metal hydride. Composites with vinyl-containing siloxane oligomers were also polymerized with and without added styrene and divinyl benzene. Hydrogen capacity measurements revealed that addition of the polymer to the metal hydride reduced the inherent hydrogen storage capacity of the material. The composites were found to be initially effective at reducing the amount of heat released during oxidation. However, upon cycling the composites, the mitigating behavior was lost. While the polymer composites we investigated have mitigating potential and are physically robust, they undergo a chemical change upon cycling that makes them subsequently ineffective at mitigating heat release upon oxidation of the metal hydride. Acknowledgements The authors would like to thank the following people who participated in this project: Ned Stetson (U.S. Department of Energy) for sponsorship and support of the project. Ken Stewart (Sandia) for building the flow-through calorimeter and cycling test stations. Isidro Ruvalcaba, Jr. (Sandia) for qualitative experiments on the interaction of sodium alanate with water. Terry Johnson (Sandia) for sharing his expertise and knowledge of metal hydrides, and sodium alanate in particular. Marcina Moreno (Sandia) for programmatic assistance. John Khalil (United Technologies Research Corp) for insight into the hazards of reactive metal hydrides and real-world accident scenario experiments. Summary In an attempt to mitigate and/or manage hazards associated with storing bulk quantities of reactive metal hydrides, polymer composite materials (a mixture of a mitigating polymer and a metal hydride) were synthesized and tested under simulated usage and accident conditions. Mitigating the hazards associated with reactive metal hydrides during an accident while finding a way to keep the original capability of the active material intact during normal use has been the focus of this work. These composites were made by polymerizing vinyl monomers using free-radical polymerization chemistry, in the presence of the metal hydride, in this case a prepared sodium alanate (chosen as a representative reactive metal hydride). It was found that the polymerization of styrene and divinyl benzene could be initiated using AIBN in toluene at 70 degC. The resulting composite materials can be either hard or brittle solids depending on the cross-linking density. Thermal decomposition of these styrene-based composite materials is lower than neat polystyrene indicating that the chemical nature of the polymer is affected by the formation of the composite. The char-forming nature of cross-linked polystyrene is low and therefore, not an ideal polymer for hazard mitigation. To obtain composite materials containing a polymer with higher char-forming potential, siloxane-based monomers were investigated. Four vinyl-containing siloxane oligomers were polymerized with and without added styrene and divinyl benzene. Like the styrene materials, these composite materials exhibited thermal decomposition behavior significantly different than the neat polymers. Specifically, the thermal decomposition temperature was shifted approximately 100 degC lower than the neat polymer signifying a major chemical change to the polymer network. Thermal analysis of the cycled samples was performed on the siloxane-based composite materials. It was found that after 30 cycles the siloxane-containing polymer composite material has similar TGA/DSC-MS traces as the virgin composite material indicating that the polymer is physically intact upon cycling. Hydrogen capacity measurements revealed that addition of the polymer to the metal hydride in the form of a composite material reduced the inherent hydrogen storage capacity of the material. This

  15. Models for Metal Hydride Particle Shape, Packing, and Heat Transfer

    E-Print Network [OSTI]

    Kyle C. Smith; Timothy S. Fisher

    2012-05-04

    A multiphysics modeling approach for heat conduction in metal hydride powders is presented, including particle shape distribution, size distribution, granular packing structure, and effective thermal conductivity. A statistical geometric model is presented that replicates features of particle size and shape distributions observed experimentally that result from cyclic hydride decreptitation. The quasi-static dense packing of a sample set of these particles is simulated via energy-based structural optimization methods. These particles jam (i.e., solidify) at a density (solid volume fraction) of 0.665+/-0.015 - higher than prior experimental estimates. Effective thermal conductivity of the jammed system is simulated and found to follow the behavior predicted by granular effective medium theory. Finally, a theory is presented that links the properties of bi-porous cohesive powders to the present systems based on recent experimental observations of jammed packings of fine powder. This theory produces quantitative experimental agreement with metal hydride powders of various compositions.

  16. FEASIBILITY OF RECYCLING PLUTONIUM AND MINOR ACTINIDES IN LIGHT WATER REACTORS USING HYDRIDE FUEL

    SciTech Connect (OSTI)

    Greenspan, Ehud; Todreas, Neil; Taiwo, Temitope

    2009-03-10

    The objective of this DOE NERI program sponsored project was to assess the feasibility of improving the plutonium (Pu) and minor actinide (MA) recycling capabilities of pressurized water reactors (PWRs) by using hydride instead of oxide fuels. There are four general parts to this assessment: 1) Identifying promising hydride fuel assembly designs for recycling Pu and MAs in PWRs 2) Performing a comprehensive systems analysis that compares the fuel cycle characteristics of Pu and MA recycling in PWRs using the promising hydride fuel assembly designs identified in Part 1 versus using oxide fuel assembly designs 3) Conducting a safety analysis to assess the likelihood of licensing hydride fuel assembly designs 4) Assessing the compatibility of hydride fuel with cladding materials and water under typical PWR operating conditions Hydride fuel was found to offer promising transmutation characteristics and is recommended for further examination as a possible preferred option for recycling plutonium in PWRs.

  17. Characteristics of Interconnected Delta-Hydride Precipitates in Zr

    SciTech Connect (OSTI)

    L.J. Carroll; M.R. Tonks; T.M. Lillo; B.S. Fromm; DC Haggard; T.C. Morris; W.D. Swank; T.L. Trowbridge; M.C. Carroll

    2014-09-01

    Characterization of extended delta-ZrH1.66 structures in unalloyed zirconium by electron backscatter diffraction analysis confirms that they consist of many interconnected precipitates of multiple, but distinctly related, orientations. The expected orientation relationship of (0001)a-Zr//(111)delta-ZrH1.66 is confirmed between the hydride and one of the surrounding a-Zr matrix grains. The delta-ZrH1.66 precipitates do not extend in a discrete crystalline orientation, but are regularly divided by 60° type {111} twins in which adjacent delta-ZrH1.66 grains share a {111} plane. The observed matching of the close-packed FCC planes of impinging or twinned hydrides within an interconnected structure enables the minimization of the overall interfacial energy through successive nucleation and growth events and twinning.

  18. Thermomechanics of hydrogen storage in metallic hydrides: modeling and analysis

    E-Print Network [OSTI]

    Tomas Roubicek; Giuseppe Tomassetti

    2013-09-12

    A thermodynamically consistent mathematical model for hydrogen adsorption in metal hydrides is proposed. Beside hydrogen diffusion, the model accounts for phase transformation accompanied by hysteresis, swelling, temperature and heat transfer, strain, and stress. We prove existence of solutions of the ensuing system of partial differential equations by a carefully-designed, semi-implicit approximation scheme. A generalization for a drift-diffusion of multi-component ionized "gas" is outlined, too.

  19. Diffusional exchange of isotopes in a metal hydride sphere.

    SciTech Connect (OSTI)

    Wolfer, Wilhelm G.; Hamilton, John C.; James, Scott Carlton

    2011-04-01

    This report describes the Spherical Particle Exchange Model (SPEM), which simulates exchange of one hydrogen isotope by another hydrogen isotope in a spherical metal hydride particle. This is one of the fundamental physical processes during isotope exchange in a bed of spherical metal particles and is thus one of the key components in any comprehensive physics-based model of exchange. There are two important physical processes in the model. One is the entropy of mixing between the two isotopes; the entropy of mixing is increased by having both isotopes randomly placed at interstitial sites on the lattice and thus impedes the exchange process. The other physical process is the elastic interaction between isotope atoms on the lattice. The elastic interaction is the cause for {beta}-phase formation and is independent of the isotope species. In this report the coupled diffusion equations for two isotopes in the {beta}-phase hydride are solved. A key concept is that the diffusion of one isotope depends not only on its concentration gradient, but also on the concentration gradient of the other isotope. Diffusion rate constants and the chemical potentials for deuterium and hydrogen in the {beta}-phase hydride are reviewed because these quantities are essential for an accurate model of the diffusion process. Finally, a summary of some of the predictions from the SPEM model are provided.

  20. Measurement and modeling of strain fields in zirconium hydrides precipitated at a stress concentration

    SciTech Connect (OSTI)

    Allen, Gregory B.; Kerr, Matthew; Daymond, Mark R. (Queens)

    2012-10-23

    Hydrogen adsorption into zirconium, as a result of corrosion in aqueous environments, leads to the precipitation of a secondary brittle hydride phase. These hydrides tend to first form at stress concentrations such as fretting flaws or cracks in engineering components, potentially degrading the structural integrity of the component. One mechanism for component failure is a slow crack growth mechanism known as Delayed Hydride Cracking (DHC), where hydride fracture occurs followed by crack arrest in the ductile zirconium matrix. The current work employs both an experimental and a modeling approach to better characterize the effects and behavior of hydride precipitation at such stress concentrations. Strains around stress concentrations containing hydrides were mapped using High Energy X-ray Diffraction (HEXRD). These studies highlighted important differences in the behavior of the hydride phase and the surrounding zirconium matrix, as well as the strain associated with the precipitation of the hydride. A finite element model was also developed and compared to the X-ray strain mapping results. This model provided greater insight into details that could not be obtained directly from the experimental approaches, as well as providing a framework for future modeling to predict the effects of hydride precipitation under varied conditions.

  1. Thermal Design of a Metal Hydride Storage Bed, Permitting Tritium Accountancy to 0.1% Resolution and Repeatability

    E-Print Network [OSTI]

    Thermal Design of a Metal Hydride Storage Bed, Permitting Tritium Accountancy to 0.1% Resolution and Repeatability

  2. Combined on-board hydride slurry storage and reactor system and process for hydrogen-powered vehicles and devices

    DOE Patents [OSTI]

    Brooks, Kriston P; Holladay, Jamelyn D; Simmons, Kevin L; Herling, Darrell R

    2014-11-18

    An on-board hydride storage system and process are described. The system includes a slurry storage system that includes a slurry reactor and a variable concentration slurry. In one preferred configuration, the storage system stores a slurry containing a hydride storage material in a carrier fluid at a first concentration of hydride solids. The slurry reactor receives the slurry containing a second concentration of the hydride storage material and releases hydrogen as a fuel to hydrogen-power devices and vehicles.

  3. UNDERSTANDING OF HYDRIDING MECHANISMS OF ZIRCALOY-4 ALLOY DURING CORROSION IN PWR SIMULATED CONDITIONS

    E-Print Network [OSTI]

    Motta, Arthur T.

    1 UNDERSTANDING OF HYDRIDING MECHANISMS OF ZIRCALOY-4 ALLOY DURING CORROSION IN PWR SIMULATED CONDITIONS AND INFLUENCE OF ZIRCONIUM HYDRIDES ON ZIRCALOY-4 CORROSION C. BISOR-MELLOUL, M. TUPIN, P. BOSSIS-sur-Yvette ­ France A. MOTTA Mechanical and Nuclear Engineering Department, Penn State University 227 Reber Building

  4. 1,2-Aryl and 1,2-Hydride Migration in Transition Metal Complex Catalyzed

    E-Print Network [OSTI]

    Wang, Jianbo

    1,2-Aryl and 1,2-Hydride Migration in Transition Metal Complex Catalyzed Diazo Decomposition of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, Department of Chemistry, Peking Uni,2-hydride migration was studied. A reaction mechanism involving a "bridged" phenonium ion is proposed

  5. Hydrogen storage material and process using graphite additive with metal-doped complex hydrides

    DOE Patents [OSTI]

    Zidan, Ragaiy (Aiken, SC); Ritter, James A. (Lexington, SC); Ebner, Armin D. (Lexington, SC); Wang, Jun (Columbia, SC); Holland, Charles E. (Cayce, SC)

    2008-06-10

    A hydrogen storage material having improved hydrogen absorbtion and desorption kinetics is provided by adding graphite to a complex hydride such as a metal-doped alanate, i.e., NaAlH.sub.4. The incorporation of graphite into the complex hydride significantly enhances the rate of hydrogen absorbtion and desorption and lowers the desorption temperature needed to release stored hydrogen.

  6. Hydride transfer reaction dynamics of OD+ Li Liu, Elizabeth S. Richards, and James M. Farrara

    E-Print Network [OSTI]

    Farrar, James M.

    Hydride transfer reaction dynamics of OD+ +C3H6 Li Liu, Elizabeth S. Richards, and James M. Farrara 30 April 2007; published online 29 June 2007 The hydride transfer reaction between OD+ and C3H6 has, with maxima close to the velocity and direction of the precursor propylene beam, characteristic of direct

  7. Hydride precipitation kinetics in Zircaloy-4 studied using synchrotron X-ray diffraction

    E-Print Network [OSTI]

    Motta, Arthur T.

    Hydride precipitation kinetics in Zircaloy-4 studied using synchrotron X-ray diffraction Olivier F fuel cladding and precipitate as brittle hydride particles, which may reduce cladding ductility. Dissolved hydrogen responds to temperature gradients, resulting in transport and precipitation into cold

  8. Metal Hydride Chemical Heat Pumps for Industrial Use 

    E-Print Network [OSTI]

    Ally, M. R.; Rebello, W. J.; Rosso, M. J., Jr.

    1984-01-01

    occasionally, the ideal behaviour shown in Figure 1 is observed, in practice there are usually slight deviations from this ideal. Fig ure 2 shows isotherms obtained for a gractical nickel-aluminium-mischmetal compound. t1) Note that the plateau is sloped.... The expansion is accomodated by the loosely packed individual capsules, preventing any stress on the main container walls. Each capsule is a thin-walled aluminium tube containing the hydride can, capped on one or both ends with a porous metal filter. Such a...

  9. Chemical Hydrides for Hydrogen Storage in Fuel Cell Applications

    SciTech Connect (OSTI)

    Devarakonda, Maruthi N.; Brooks, Kriston P.; Ronnebro, Ewa; Rassat, Scot D.; Holladay, Jamelyn D.

    2012-04-16

    Due to its high hydrogen storage capacity (up to 19.6% by weight for the release of 2.5 molar equivalents of hydrogen gas) and its stability under typical ambient conditions, ammonia borane (AB) is a promising material for chemical hydrogen storage for fuel cell applications in transportation sector. Several systems models for chemical hydride materials such as solid AB, liquid AB and alane were developed and evaluated at PNNL to determine an optimal configuration that would meet the 2010 and future DOE targets for hydrogen storage. This paper presents an overview of those systems models and discusses the simulation results for various transient drive cycle scenarios.

  10. The calculated rovibronic spectrum of scandium hydride, ScH

    E-Print Network [OSTI]

    Lodi, Lorenzo; Tennyson\\, Jonathan

    2015-01-01

    The electronic structure of six low-lying electronic states of scandium hydride, $X\\,{}^{1}\\Sigma^+$, $a\\,{}^{3}\\Delta$, $b\\,{}^{3}\\Pi$, $A\\,{}^{1}\\Delta$ $c\\,{}^{3}\\Sigma^+$, and $B\\,{}^{1}\\Pi$, is studied using multi-reference configuration interaction as a function of bond length. Diagonal and off-diagonal dipole moment, spin-orbit coupling and electronic angular momentum curves are also computed. The results are benchmarked against experimental measurements and calculations on atomic scandium. The resulting curves are used to compute a line list of molecular ro-vibronic transitions for $^{45}$ScH.

  11. Electrochemical process and production of novel complex hydrides

    DOE Patents [OSTI]

    Zidan, Ragaiy

    2013-06-25

    A process of using an electrochemical cell to generate aluminum hydride (AlH.sub.3) is provided. The electrolytic cell uses a polar solvent to solubilize NaAlH.sub.4. The resulting electrochemical process results in the formation of AlH.sub.3. The AlH.sub.3 can be recovered and used as a source of hydrogen for the automotive industry. The resulting spent aluminum can be regenerated into NaAlH.sub.4 as part of a closed loop process of AlH.sub.3 generation.

  12. Working with SRNL - Our Facilities - Metal Hydride Laboratories

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust,Field-effectWorking WithTelecentricNCubictheThepresented in1: ModelGloveboxMetal Hydride

  13. Method of generating hydrogen-storing hydride complexes

    DOE Patents [OSTI]

    Srinivasan, Sesha S; Niemann, Michael U; Goswami, D. Yogi; Stefanakos, Elias K

    2013-05-14

    A ternary hydrogen storage system having a constant stoichiometric molar ratio of LiNH.sub.2:MgH.sub.2:LiBH.sub.4 of 2:1:1. It was found that the incorporation of MgH.sub.2 particles of approximately 10 nm to 20 nm exhibit a lower initial hydrogen release temperature of 150.degree. C. Furthermore, it is observed that the particle size of LiBNH quaternary hydride has a significant effect on the hydrogen sorption concentration with an optimum size of 28 nm. The as-synthesized hydrides exhibit two main hydrogen release temperatures, one around 160.degree. C. and the other around 300.degree. C., with the main hydrogen release temperature reduced from 310.degree. C. to 270.degree. C., while hydrogen is first reversibly released at temperatures as low as 150.degree. C. with a total hydrogen capacity of 6 wt. % to 8 wt. %. Detailed thermal, capacity, structural and microstructural properties have been demonstrated and correlated with the activation energies of these materials.

  14. GAS-PHASE REACTIONS OF HYDRIDE ANION, H{sup -}

    SciTech Connect (OSTI)

    Martinez, Oscar; Yang Zhibo; Demarais, Nicholas J.; Bierbaum, Veronica M. [Department of Chemistry and Biochemistry, 215 UCB, University of Colorado, Boulder, CO 80309-0215 (United States); Snow, Theodore P., E-mail: Oscar.Martinez@colorado.ed, E-mail: Zhibo.Yang@colorado.ed, E-mail: Nicholas.Demarais@colorado.ed, E-mail: Veronica.Bierbaum@colorado.ed, E-mail: Theodore.Snow@colorado.ed [Department of Astrophysical and Planetary Sciences, 391 UCB, University of Colorado, Boulder, CO 80309-0391 (United States)

    2010-09-01

    Rate constants were measured at 300 K for the reactions of the hydride anion, H{sup -}, with neutral molecules C{sub 2}H{sub 2}, H{sub 2}O, CH{sub 3}CN, CH{sub 3}OH, (CH{sub 3}){sub 2}CO, CH{sub 3}CHO, N{sub 2}O, CO{sub 2}, O{sub 2}, CO, CH{sub 3}Cl, (CH{sub 3}){sub 3}CCl, (CH{sub 3}CH{sub 2}){sub 2}O, C{sub 6}H{sub 6}, and D{sub 2} using a flowing-afterglow instrument. Experimental work was supplemented by ab initio calculations to provide insight into the viability of reaction pathways. Our reported rate constants should prove useful to models of astrophysical environments where conditions prevail for the existence of both H{sup -} and neutral species. The variety of neutral reactants studied includes representative species from prototypical chemical groups, effectively mapping reactivity trends for the hydride anion.

  15. ACCEPTABILITY ENVELOPE FOR METAL HYDRIDE-BASED HYDROGEN STORAGE SYSTEMS

    SciTech Connect (OSTI)

    Hardy, B.; Corgnale, C.; Tamburello, D.; Garrison, S.; Anton, D.

    2011-07-18

    The design and evaluation of media based hydrogen storage systems requires the use of detailed numerical models and experimental studies, with significant amount of time and monetary investment. Thus a scoping tool, referred to as the Acceptability Envelope, was developed to screen preliminary candidate media and storage vessel designs, identifying the range of chemical, physical and geometrical parameters for the coupled media and storage vessel system that allow it to meet performance targets. The model which underpins the analysis allows simplifying the storage system, thus resulting in one input-one output scheme, by grouping of selected quantities. Two cases have been analyzed and results are presented here. In the first application the DOE technical targets (Year 2010, Year 2015 and Ultimate) are used to determine the range of parameters required for the metal hydride media and storage vessel. In the second case the most promising metal hydrides available are compared, highlighting the potential of storage systems, utilizing them, to achieve 40% of the 2010 DOE technical target. Results show that systems based on Li-Mg media have the best potential to attain these performance targets.

  16. Final report for the DOE Metal Hydride Center of Excellence.

    SciTech Connect (OSTI)

    Keller, Jay O.; Klebanoff, Leonard E.

    2012-01-01

    This report summarizes the R&D activities within the U.S. Department of Energy Metal Hydride Center of Excellence (MHCoE) from March 2005 to June 2010. The purpose of the MHCoE has been to conduct highly collaborative and multi-disciplinary applied R&D to develop new reversible hydrogen storage materials that meet or exceed DOE 2010 and 2015 system goals for hydrogen storage materials. The MHCoE combines three broad areas: mechanisms and modeling (which provide a theoretically driven basis for pursuing new materials), materials development (in which new materials are synthesized and characterized) and system design and engineering (which allow these new materials to be realized as practical automotive hydrogen storage systems). This Final Report summarizes the organization and execution of the 5-year research program to develop practical hydrogen storage materials for light duty vehicles. Major results from the MHCoE are summarized, along with suggestions for future research areas.

  17. The Development of a Cathodic Charging System to Form Hydrides in Zircaloy-4 

    E-Print Network [OSTI]

    Brito, Ryan

    2013-02-01

    This project investigates several methods of electrochemical insertion of hydrogen into Zircaloy nuclear fuel cladding. These systems are being assembled at Texas A & M to form zirconium hydride in cladding to model crack propagation during storage...

  18. The Use of Metal Hydrides for Hydrogen Recovery from Industrial Off-Gas Streams 

    E-Print Network [OSTI]

    Rebello, W. J.; Guerrero, P. S.; Goodell, P. D.

    1987-01-01

    technical factors may make it economically attractive for them to consider the hydride separation technology. Table 1 SECONDARY HYDROGEN CAPACITY IN 15 INDUSTRIES elements including palladium, vana dium, and magnesium. and with allo s based...

  19. Electrochromically switched, gas-reservoir metal hydride devices with application to energy-efficient windows

    E-Print Network [OSTI]

    Anders, Andre

    2008-01-01

    allow molecular hydrogen to reach the palladium-capped metalhydrogen is converted to protons, which are transported through the ZrO 2 electrolyte to the palladiumhydrogen and transforms into a transparent hydride. A catalytic capping layer of palladium

  20. Model for Simulation of Hydride Precipitation in Zr-Based Used...

    Broader source: Energy.gov (indexed) [DOE]

    a meso-scale, microstructural evolution model for simulation of zirconium hydride precipitation in the cladding of used fuels during long-term dry-storage. While the Zr-based...

  1. Advanced Metal-Hydrides-Based Thermal Battery: A New Generation of High Density Thermal Battery Based on Advanced Metal Hydrides

    SciTech Connect (OSTI)

    2011-12-01

    HEATS Project: The University of Utah is developing a compact hot-and-cold thermal battery using advanced metal hydrides that could offer efficient climate control system for EVs. The team’s innovative designs of heating and cooling systems for EVs with high energy density, low-cost thermal batteries could significantly reduce the weight and eliminate the space constraint in automobiles. The thermal battery can be charged by plugging it into an electrical outlet while charging the electric battery and it produces heat and cold through a heat exchanger when discharging. The ultimate goal of the project is a climate-controlling thermal battery that can last up to 5,000 charge and discharge cycles while substantially increasing the driving range of EVs, thus reducing the drain on electric batteries.

  2. First-principles calculations of niobium hydride formation in superconducting radio-frequency cavities

    SciTech Connect (OSTI)

    Ford, Denise C.; Cooley, Lance D.; Seidman, David N.

    2013-09-01

    Niobium hydride is suspected to be a major contributor to degradation of the quality factor of niobium superconducting radio-frequency (SRF) cavities. In this study, we connect the fundamental properties of hydrogen in niobium to SRF cavity performance and processing. We modeled several of the niobium hydride phases relevant to SRF cavities and present their thermodynamic, electronic, and geometric properties determined from calculations based on density-functional theory. We find that the absorption of hydrogen from the gas phase into niobium is exothermic and hydrogen becomes somewhat anionic. The absorption of hydrogen by niobium lattice vacancies is strongly preferred over absorption into interstitial sites. A single vacancy can accommodate six hydrogen atoms in the symmetrically equivalent lowest-energy sites and additional hydrogen in the nearby interstitial sites affected by the strain field: this indicates that a vacancy can serve as a nucleation center for hydride phase formation. Small hydride precipitates may then occur near lattice vacancies upon cooling. Vacancy clusters and extended defects should also be enriched in hydrogen, potentially resulting in extended hydride phase regions upon cooling. We also assess the phase changes in the niobium-hydrogen system based on charge transfer between niobium and hydrogen, the strain field associated with interstitial hydrogen, and the geometry of the hydride phases. The results of this study stress the importance of not only the hydrogen content in niobium, but also the recovery state of niobium for the performance of SRF cavities.

  3. Effects of outgassing of loader chamber walls on hydriding of thin films for commercial applications

    SciTech Connect (OSTI)

    Provo, James L., E-mail: jlprovo@verizon.net [Consultant, J.L. Provo Consulting, Trinity, Florida 34655-7179 (United States)

    2014-07-01

    An important aspect of understanding industrial processing is to know the characteristics of the materials used in such processes. A study was performed to determine the effects of hydriding chamber material on the degree of hydriding for the commercial production of thin film hydride targets for various research universities, commercial companies, and government national laboratories. The goal was to increase the degree of hydriding of various thin film hydrides and to study the vacuum environment during air-exposure hydriding. For this purpose, dynamic residual gas analysis during deuterium gas hydride processing was utilized with erbium thin films, employing a special set-up for direct dynamic hydride gas sampling during processing at elevated temperature and full loading gas pressure. Complete process data for (1) a copper–(1.83?wt.?%)beryllium wet hydrogen fired passivated (600?°C–1?h) externally heated pipe hydriding chamber are reported. Dynamic residual gas analysis comparisons during hydriding are presented for hydriding chambers made from (2) alumina (99.8 wt.?%), (3) copper (with an interior aluminum coating ?10 k Ĺ thick, and (4) for a stainless-steel air-fired passivated (900?°C–1?h) chamber. Dynamic data with deuterium gas in the chamber at the hydriding temperature (450?°C) showed the presence and growth of water vapor (D{sub 2}O) and related mixed ion species(H{sub 2}O{sup +}, HDO{sup +}, D{sub 2}O{sup +}, and OD{sup +}) from hydrogen isotope exchange reactions during the 1?h process time. Peaks at mass-to-charge ratios (i.e., m/e) of 12(C{sup +}), 16(CD{sub 2}{sup +}), 17(CHD{sub 2}{sup +}), and 18(CD{sub 3}{sup +}, OD{sup +}) increased for approximately the first half hour of a 1?h hydriding process and then approach steady state. Mass-to-charge peaks at 19(HDO{sup +}) and 20(D{sub 2}O{sup +}) continue to increase throughout the process cycle. Using the m/e?=?20 (D{sub 2}O{sup +}) peak intensity from chamber (1)–Cu(1.83 wt.?%)Be as a standard, the peak intensity from chamber (4)—stainless-steel (air-fired) was 7.1× higher, indicating that the surface of stainless-steel had a larger concentration of reactive oxygen and/or water than hydrogen. The (D{sub 2}O{sup +}) peak intensity from chamber (3)—Cu (interior Al coating) was 1.55× larger and chamber (2)—alumina(99.8%) was 1.33× higher than Cu(1.83 wt.?%)Be. Thus copper–(1.83 wt.?%)beryllium was the best hydriding chamber material studied followed closely by the alumina (99.8 wt.?%) chamber. Gas take-up by Er occluder targets processed in Cu(1.83?wt.?%)Be hydriding chambers (i.e., gas/metal atomic ratios) correlate with the dynamic RGA data.

  4. Fact #603: December 28, 2009 Where Does Lithium Come From?

    Broader source: Energy.gov [DOE]

    Lithium ion batteries will be used in many of the upcoming plug-in hybrid vehicles and electric vehicles because they are lighter and more powerful than the nickel-metal hydride batteries used in...

  5. Multifunctional microtruss laminates: Textile synthesis and properties

    E-Print Network [OSTI]

    Wadley, Haydn

    .N.G. Wadley Department of Materials Science and Engineering, 116 Engineer's Way, School of Engineering heat exchangers and as the electrodes in nickel metal hydride batteries.4 Their Young's moduli

  6. A. M. Sastry B. E. Layton

    E-Print Network [OSTI]

    Sastry, Ann Marie

    X. Cheng A. M. Sastry B. E. Layton Department of Mechanical Engineering and Applied Mechanics for production of posi- tive electrodes for NiMH nickel-metal hydride batteries are comprised of two or more

  7. Technological assessment and evaluation of high power batteries and their commercial values

    E-Print Network [OSTI]

    Teo, Seh Kiat

    2006-01-01

    Lithium Ion (Li-ion) battery technology has the potential to compete with the more matured Nickel Metal Hydride (NiMH) battery technology in the Hybrid Electric Vehicle (HEV) energy storage market as it has higher specific ...

  8. New sealed rechargeable batteries and supercapacitors

    SciTech Connect (OSTI)

    Barnett, B.M. ); Dowgiallo, E. ); Halpert, G. ); Matsuda, Y. ); Takehara, Z.I. )

    1993-01-01

    This conference was divided into the following sections: supercapacitors; nickel-metal hydride batteries; lithium polymer batteries; lithium/carbon batteries; cathode materials; and lithium batteries. Separate abstracts were prepared for the 46 papers of this conference.

  9. Documentation of Hybrid Hydride Model for Incorporation into Moose-Bison and Validation Strategy.

    SciTech Connect (OSTI)

    Weck, Philippe F; Tikare, Veena; Schultz, Peter Andrew; Clark, B; Mitchell, J; Glazoff, Michael V.; Homer, Eric R.

    2014-10-01

    This report documents the development, demonstration and validation of a mesoscale, microstructural evolution model for simulation of zirconium hydride ?-ZrH{sub 1.5} precipitation in the cladding of used nuclear fuels that may occur during long-term dry storage. While the Zr-based claddings are manufactured free of any hydrogen, they absorb hydrogen during service, in the reactor by a process commonly termed ‘hydrogen pick-up’. The precipitation and growth of zirconium hydrides during dry storage is one of the most likely fuel rod integrity failure mechanisms either by embrittlement or delayed hydride cracking of the cladding (Hanson et al., 2011). While the phenomenon is well documented and identified as a potential key failure mechanism during long-term dry storage (Birk et al., 2012 and NUREG/CR-7116), the ability to actually predict the formation of hydrides is poor. The model being documented in this work is a computational capability for the prediction of hydride formation in different claddings of used nuclear fuels. This work supports the Used Fuel Disposition Research and Development Campaign in assessing the structural engineering performance of the cladding during and after long-term dry storage. In this work, a model to numerically simulate hydride precipitation at the microstructural scale, in a wide variety of Zr-based claddings, under dry-storage conditions is being developed. It will be used to aid in the evaluation of the mechanical integrity of used fuel rods during dry storage and transportation by providing the structural conditions from the microstructural scale to the continuum scale to engineering component scale models to predict if the used fuel rods will perform without failure under normal and off-normal conditions. The microstructure, especially, the hydride structure is thought to be a primary determinant of cladding failure, thus this component of UFD’s storage and transportation analysis program is critical. The model development, application and validation of the model are documented and the limitations of the current model are discussed. The model has been shown to simulate hydride precipitation in Zircaloy-4 cladding with correct morphology, thermodynamics and kinetics. An unexpected insight obtained from simulations hydride formation in Zircaloy-4 is that small (sub-micron) precipitates need to order themselves to form the larger hydrides typically described as radially-reoriented precipitates. A limitation of this model is that it does not currently solve the stress state that forms dynamically in the precipitate or matrix surrounding the precipitate. A method to overcome the limitations is suggested and described in detail. The necessary experiments to provide key materials physics and to validate the model are also recommended.

  10. Electronic structure and crystal phase stability of palladium hydrides

    SciTech Connect (OSTI)

    Houari, Abdesalem; Matar, Samir F.; Eyert, Volker

    2014-11-07

    The results of electronic structure calculations for a variety of palladium hydrides are presented. The calculations are based on density functional theory and used different local and semilocal approximations. The thermodynamic stability of all structures as well as the electronic and chemical bonding properties are addressed. For the monohydride, taking into account the zero-point energy is important to identify the octahedral Pd-H arrangement with its larger voids and, hence, softer hydrogen vibrational modes as favorable over the tetrahedral arrangement as found in the zincblende and wurtzite structures. Stabilization of the rocksalt structure is due to strong bonding of the 4d and 1s orbitals, which form a characteristic split-off band separated from the main d-band group. Increased filling of the formerly pure d states of the metal causes strong reduction of the density of states at the Fermi energy, which undermines possible long-range ferromagnetic order otherwise favored by strong magnetovolume effects. For the dihydride, octahedral Pd-H arrangement as realized, e.g., in the pyrite structure turns out to be unstable against tetrahedral arrangement as found in the fluorite structure. Yet, from both heat of formation and chemical bonding considerations, the dihydride turns out to be less favorable than the monohydride. Finally, the vacancy ordered defect phase Pd{sub 3}H{sub 4} follows the general trend of favoring the octahedral arrangement of the rocksalt structure for Pd:H ratios less or equal to one.

  11. The affect of erbium hydride on the conversion efficience to accelerated protons from ultra-shsort pulse laser irradiated foils

    SciTech Connect (OSTI)

    Offermann, D

    2008-09-04

    This thesis work explores, experimentally, the potential gains in the conversion efficiency from ultra-intense laser light to proton beams using erbium hydride coatings. For years, it has been known that contaminants at the rear surface of an ultra-intense laser irradiated thin foil will be accelerated to multi-MeV. Inertial Confinement Fusion fast ignition using proton beams as the igniter source requires of about 10{sup 16} protons with an average energy of about 3MeV. This is far more than the 10{sup 12} protons available in the contaminant layer. Target designs must include some form of a hydrogen rich coating that can be made thick enough to support the beam requirements of fast ignition. Work with computer simulations of thin foils suggest the atomic mass of the non-hydrogen atoms in the surface layer has a strong affect on the conversion efficiency to protons. For example, the 167amu erbium atoms will take less energy away from the proton beam than a coating using carbon with a mass of 12amu. A pure hydrogen coating would be ideal, but technologically is not feasible at this time. In the experiments performed for my thesis, ErH{sub 3} coatings on 5 {micro}m gold foils are compared with typical contaminants which are approximately equivalent to CH{sub 1.7}. It will be shown that there was a factor of 1.25 {+-} 0.19 improvement in the conversion efficiency for protons above 3MeV using erbium hydride using the Callisto laser. Callisto is a 10J per pulse, 800nm wavelength laser with a pulse duration of 200fs and can be focused to a peak intensity of about 5 x 10{sup 19}W/cm{sup 2}. The total number of protons from either target type was on the order of 10{sup 10}. Furthermore, the same experiment was performed on the Titan laser, which has a 500fs pulse duration, 150J of energy and can be focused to about 3 x 10{sup 20} W/cm{sup 2}. In this experiment 10{sup 12} protons were seen from both erbium hydride and contaminants on 14 {micro} m gold foils. Significant improvements were also observed but possibly because of the depletion of hydrogen in the contaminant layer case.

  12. Hydride transfer reaction dynamics of OD{sup +}+C{sub 3}H{sub 6}

    SciTech Connect (OSTI)

    Liu, Li; Richards, Elizabeth S.; Farrar, James M. [Department of Chemistry, University of Rochester, Rochester, New York 14627 (United States)

    2007-06-28

    The hydride transfer reaction between OD{sup +} and C{sub 3}H{sub 6} has been studied experimentally and theoretically over the center of mass collision energy range from 0.21 to 0.92 eV using the crossed beam technique and density functional theory calculations. The center of mass flux distributions of the product ions at three different energies are highly asymmetric, with maxima close to the velocity and direction of the precursor propylene beam, characteristic of direct reactions. In the hydride transfer process, the entire reaction exothermicity is transformed into product internal excitation, consistent with mixed energy release in which the hydride ion is transferred with both the breaking and forming bonds extended. At higher collision energies, at least 85% of the incremental translational energy appears in product translation, providing a clear example of induced repulsive energy release. Compared to the related reaction of OD{sup +} with C{sub 2}H{sub 4}, reaction along the pathway initiated by addition of OD{sup +} to the C=C bond in propylene has a critical bottleneck caused by the torsional motion of the methyl substituent on the double bond. This bottleneck suppresses reaction through an intermediate complex in favor of direct hydride abstraction. Hydride abstraction appears to be a sequential process initiated by electron transfer in the triplet manifold, followed by rapid intersystem crossing and subsequent hydrogen atom transfer to form ground state allyl cation and HOD.

  13. Materials Down-selection Decisions Made within the DOE Metal Hydride Center of Excellence (MHCoE) - September-October 2007

    Fuel Cell Technologies Publication and Product Library (EERE)

    Reports on which hydrogen storage materials offer potential for further research as decided by DOE's Metal Hydride Center of Excellence.

  14. Materials Down-selection Decisions Made within the DOE Metal Hydride Center of Excellence (MHCoE) - September-October 2007

    SciTech Connect (OSTI)

    Klebanoff, Lennie [Sandia National Lab. (SNL-CA), Livermore, CA (United States)

    2007-09-01

    Reports on which hydrogen storage materials offer potential for further research as decided by DOE's Metal Hydride Center of Excellence.

  15. Deadtime Correction and Hydride Evaluation for Atom-Probe Data, with Applications for Studies of Nanoscale Grains and Carbon

    E-Print Network [OSTI]

    Deadtime Correction and Hydride Evaluation for Atom-Probe Data, with Applications for Studies for Atom-Probe Tomography, Dept. of Materials Science and Engineering, Northwestern University, Evanston hydride formation [3]. Measurements for this study are made with a Cameca LEAP 4000X Si atom

  16. Stimulated Emission from As-grown GaN Hexagons by Selective Area Growth Hydride Vapor Phase Epitaxy

    E-Print Network [OSTI]

    Stimulated Emission from As-grown GaN Hexagons by Selective Area Growth Hydride Vapor Phase Epitaxy Engineering and the Photonics Center, Boston University, 8 Saint Mary's St., Boston, MA 02215-2421, USA R hydride vapor phase epitaxy. We found the threshold for bulk stimulated emission to be 3.4 MW cm2

  17. Enantioselective Organocatalytic Hydride Reduction Stephane G. Ouellet, Jamison B. Tuttle, and David W. C. MacMillan*

    E-Print Network [OSTI]

    MacMillan, David W. C.

    Enantioselective Organocatalytic Hydride Reduction Ste´phane G. Ouellet, Jamison B. Tuttle, and David W. C. MacMillan* DiVision of Chemistry and Chemical Engineering, California Institute enzymes and hydride-reduction cofactors such as NADH or FADH2.2 On this basis, we recently questioned

  18. Scanning Kelvin probe microscopy of surface electronic structure in GaN grown by hydride vapor phase epitaxy

    E-Print Network [OSTI]

    Yu, Edward T.

    Scanning Kelvin probe microscopy of surface electronic structure in GaN grown by hydride vapor Engineering and Program in Materials Science and Engineering, University of California at San Diego, La Jolla microscopy is used to image surface potential variations in GaN 0001 grown by hydride vapor phase epitaxy

  19. Acid strength and solvation effects on methylation, hydride transfer, and isomerization rates during catalytic homologation of C1 species

    E-Print Network [OSTI]

    Iglesia, Enrique

    Acid strength and solvation effects on methylation, hydride transfer, and isomerization rates,b, a Department of Chemical and Biomolecular Engineering, University of California at Berkeley, USA b Division, FAU, MFI) via methylation and hydride transfer steps that favor isobutane and triptane formation

  20. High Density Hydrogen Storage System Demonstration Using NaAlH4 Based Complex Compound Hydrides

    SciTech Connect (OSTI)

    Daniel A. Mosher; Xia Tang; Ronald J. Brown; Sarah Arsenault; Salvatore Saitta; Bruce L. Laube; Robert H. Dold; Donald L. Anton

    2007-07-27

    This final report describes the motivations, activities and results of the hydrogen storage independent project "High Density Hydrogen Storage System Demonstration Using NaAlH4 Based Complex Compound Hydrides" performed by the United Technologies Research Center under the Department of Energy Hydrogen Program, contract # DE-FC36-02AL67610. The objectives of the project were to identify and address the key systems technologies associated with applying complex hydride materials, particularly ones which differ from those for conventional metal hydride based storage. This involved the design, fabrication and testing of two prototype systems based on the hydrogen storage material NaAlH4. Safety testing, catalysis studies, heat exchanger optimization, reaction kinetics modeling, thermochemical finite element analysis, powder densification development and material neutralization were elements included in the effort.

  1. Titanium tritide radioisotope heat source development : palladium-coated titanium hydriding kinetics and tritium loading tests.

    SciTech Connect (OSTI)

    Van Blarigan, Peter; Shugard, Andrew D.; Walters, R. Tom

    2012-01-01

    We have found that a 180 nm palladium coating enables titanium to be loaded with hydrogen isotopes without the typical 400-500 C vacuum activation step. The hydriding kinetics of Pd coated Ti can be described by the Mintz-Bloch adherent film model, where the rate of hydrogen absorption is controlled by diffusion through an adherent metal-hydride layer. Hydriding rate constants of Pd coated and vacuum activated Ti were found to be very similar. In addition, deuterium/tritium loading experiments were done on stacks of Pd coated Ti foil in a representative-size radioisotope heat source vessel. The experiments demonstrated that such a vessel could be loaded completely, at temperatures below 300 C, in less than 10 hours, using existing department-of-energy tritium handling infrastructure.

  2. A mechanistic study of aryl halide reactions with lithium aluminum hydride 

    E-Print Network [OSTI]

    Chung, Fu-Fan

    1980-01-01

    A M:"CHA~JISTIC STUDv OF ARYL HALID RHAC IC~JS ' ITH LITHIUM ALUM 'J"M HYDRIDE A Thesis FU-FAJJ CHUI'JG Submitted to the Graduate College of Texas ARM University in nartial fulfillment of the reauirement for the degree of MASTER OF SCI- JC... August Jo80 Major Subject: Chemistry A MECHANISTIC STUDY OF ARYL HALIDE REACTIONS 1'IITH LITHIUM ALUMINUM HYDRIDE A Thesis by FU-FAN CHUNG Approved as to style and content by; (Chairman of Co ittee) (Member) , . 7 1 (Member) (Member) i (Head...

  3. Method of production of pure hydrogen near room temperature from aluminum-based hydride materials

    DOE Patents [OSTI]

    Pecharsky, Vitalij K.; Balema, Viktor P.

    2004-08-10

    The present invention provides a cost-effective method of producing pure hydrogen gas from hydride-based solid materials. The hydride-based solid material is mechanically processed in the presence of a catalyst to obtain pure gaseous hydrogen. Unlike previous methods, hydrogen may be obtained from the solid material without heating, and without the addition of a solvent during processing. The described method of hydrogen production is useful for energy conversion and production technologies that consume pure gaseous hydrogen as a fuel.

  4. Method and composition in which metal hydride particles are embedded in a silica network

    DOE Patents [OSTI]

    Heung, Leung K. (Aiken, SC)

    1999-01-01

    A silica embedded metal hydride composition and a method for making such a composition. The composition is made via the following process: A quantity of fumed silica is blended with water to make a paste. After adding metal hydride particles, the paste is dried to form a solid. According to one embodiment of the invention, the solid is ground into granules for use of the product in hydrogen storage. Alternatively, the paste can be molded into plates or cylinders and then dried for use of the product as a hydrogen filter. Where mechanical strength is required, the paste can be impregnated in a porous substrate or wire network.

  5. An Electrolytic Method to Form Zirconium Hydride Phases in Zirconium Alloys with Morphologies Similar to Hydrides Formed in Used Nuclear Fuel 

    E-Print Network [OSTI]

    Kuhr, Samuel Houston

    2012-10-19

    )........................................................................................................... 56 Figure 23 Copper from the bronze electrode dissolved into solution and electroplated on top of graphite anode. ............................................... 60 Figure 24 Method 2 sample holder configuration... morphologies, densities, and geometries of hydrides which mimic those found in the real world application. 2.3.1 Electrolytic Method Electrolytic methods involving sulfuric acid baths or molten salt baths are used to coat the outside of the sample...

  6. Stabilization of Nickel Metal Catalysts for Aqueous Processing Systems -

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust,Field-effect Photovoltaics -7541C.3 SpecialSponsor GuidelinesPlasma Physics and

  7. A PROTOTYPE FOUR INCH SHORT HYDRIDE (FISH) BED AS A REPLACEMENT TRITIUM STORAGE BED

    SciTech Connect (OSTI)

    Klein, J.; Estochen, E.; Shanahan, K.; Heung, L.

    2011-02-23

    The Savannah River Site (SRS) tritium facilities have used 1st generation (Gen1) metal hydride storage bed assemblies with process vessels (PVs) fabricated from 3 inch nominal pipe size (NPS) pipe to hold up to 12.6 kg of LaNi{sub 4.25}Al{sub 0.75} metal hydride for tritium gas absorption, storage, and desorption for over 15 years. The 2nd generation (Gen2) of the bed design used the same NPS for the PV, but the added internal components produced a bed nominally 1.2 m long, and presented a significant challenge for heater cartridge replacement in a footprint limited glove-box. A prototype 3rd generation (Gen3) metal hydride storage bed has been designed and fabricated as a replacement candidate for the Gen2 storage bed. The prototype Gen3 bed uses a PV pipe diameter of 4 inch NPS so the bed length can be reduced below 0.7 m to facilitate heater cartridge replacement. For the Gen3 prototype bed, modeling results show increased absorption rates when using hydrides with lower absorption pressures. To improve absorption performance compared to the Gen2 beds, a LaNi{sub 4.15}Al{sub 0.85} material was procured and processed to obtain the desired pressure-composition-temperature (PCT) properties. Other bed design improvements are also presented.

  8. Elucidating Reactivity Differences in Palladium-Catalyzed Coupling Processes: The Chemistry of Palladium Hydrides

    E-Print Network [OSTI]

    Fu, Gregory C.

    Elucidating Reactivity Differences in Palladium-Catalyzed Coupling Processes: The Chemistry of Palladium Hydrides Ivory D. Hills and Gregory C. Fu* Department of Chemistry, Massachusetts Institute recently been described in the develop- ment of highly active palladium-based catalysts for cross

  9. FAILURE OF ZIRCALOY-4 SHEET CONTAINING HYDRIDE BLISTERS O.N. Pierron1

    E-Print Network [OSTI]

    Motta, Arthur T.

    FAILURE OF ZIRCALOY-4 SHEET CONTAINING HYDRIDE BLISTERS O.N. Pierron1 , D.A. Koss1 , A.T. Motta2 , R.S. Daum3 , and K.S. Chan4 1 Dept. Materials Science and Engineering, Penn State Univ., University Park, PA 16802 2 Dept. Mechanical and Nuclear Engineering, Penn State University, University Park, PA

  10. INFLUENCE OF HYDRIDE MICROSTRUCTURE ON THROUGH-THICKNESS CRACK GROWTH IN ZIRCALOY-4 SHEET

    E-Print Network [OSTI]

    Motta, Arthur T.

    1 INFLUENCE OF HYDRIDE MICROSTRUCTURE ON THROUGH-THICKNESS CRACK GROWTH IN ZIRCALOY-4 SHEET P. A and Engineering, The Pennsylvania State University, University Park, PA 16802 2 Department of Mechanical and Nuclear Engineering, The Pennsylvania State University, University Park, PA 16802 3 Southwest Research

  11. The influence of hydride blisters on the fracture of Zircaloy-4 O.N. Pierron a

    E-Print Network [OSTI]

    Motta, Arthur T.

    The influence of hydride blisters on the fracture of Zircaloy-4 O.N. Pierron a , D.A. Koss a,*, A.T. Motta b , K.S. Chan c a Department of Materials Science and Engineering, Pennsylvania State University Engineering, Pennsylvania State University, University Park, PA 16802, USA c Southwest Research Institute, San

  12. Model for the Prediction of the Hydriding Thermodynamics of Pd-Rh-Co Ternary Alloys

    SciTech Connect (OSTI)

    Teter, D.F.; Thoma, D.J.

    1999-03-01

    A dilute solution model (with respect to the substitutional alloying elements) has been developed, which accurately predicts the hydride formation and decomposition thermodynamics and the storage capacities of dilute ternary Pd-Rh-Co alloys. The effect of varying the rhodium and cobalt compositions on the thermodynamics of hydride formation and decomposition and hydrogen capacity of several palladium-rhodium-cobalt ternary alloys has been investigated using pressure-composition (PC) isotherms. Alloying in the dilute regime (<10 at.%) causes the enthalpy for hydride formation to linearly decrease with increasing alloying content. Cobalt has a stronger effect on the reduction in enthalpy than rhodium for equivalent alloying amounts. Also, cobalt reduces the hydrogen storage capacity with increasing alloying content. The plateau thermodynamics are strongly linked to the lattice parameters of the alloys. A near-linear dependence of the enthalpy of hydride formation on the lattice parameter was observed for both the binary Pd-Rh and Pd-Co alloys, as well as for the ternary Pd-Rh-Co alloys. The Pd-5Rh-3Co (at. %) alloy was found to have similar plateau thermodynamics as a Pd-10Rh alloy, however, this ternary alloy had a diminished hydrogen storage capacity relative to Pd-10Rh.

  13. First Principles Studies of Phase Stability and Reaction Dynamics in Complex Metal Hydrides

    SciTech Connect (OSTI)

    Chou, Mei-Yin

    2014-09-29

    Complex metal hydrides are believed to be one of the most promising materials for developing hydrogen storage systems that can operate under desirable conditions. At the same time, these are also a class of materials that exhibit intriguing properties. We have used state-of-the-art computational techniques to study the fundamental properties of these materials.

  14. First-row hydrides: Dissociation and ground state energies using quantum Monte Carlo

    E-Print Network [OSTI]

    Anderson, James B.

    First-row hydrides: Dissociation and ground state energies using quantum Monte Carlo Arne Lu, Pennsylvania 16802 Received 20 May 1996; accepted 24 July 1996 Accurate ground state energies comparable FN-DQMC method. The residual energy, the nodal error due to the error in the nodal structure

  15. Internal hydriding in irradiated defected Zircaloy fuel rods: A review (LWBR Development Program)

    SciTech Connect (OSTI)

    Clayton, J C

    1987-10-01

    Although not a problem in recent commercial power reactors, including the Shippingport Light Water Breeder Reactor, internal hydriding of Zircaloy cladding was a persistent cause of gross cladding failures during the 1960s. It occurred in the fuel rods of water-cooled nuclear power reactors that had a small cladding defect. This report summarizes the experimental findings, causes, mechanisms, and methods of minimizing internal hydriding in defected Zircaloy-clad fuel rods. Irradiation test data on the different types of defected fuel rods, intentionally fabricated defected and in-pile operationally defected rods, are compared. Significant factors affecting internal hydriding in defected Zircaloy-clad fuel rods (defect hole size, internal and external sources of hydrogen, Zircaloy cladding surface properties, nickel alloy contamination of Zircaloy, the effect of heat flux and fluence) are discussed. Pertinent in-pile and out-of-pile test results from Bettis and other laboratories are used as a data base in constructing a qualitative model which explains hydrogen generation and distribution in Zircaloy cladding of defected water-cooled reactor fuel rods. Techniques for minimizing internal hydride failures in Zircaloy-clad fuel rods are evaluated.

  16. ANALYSIS OF THE ELECTRON EXCITATION SPECTRA IN HEAVY RARE EARTH METALS, HYDRIDES AND OXIDES

    E-Print Network [OSTI]

    Boyer, Edmond

    397 ANALYSIS OF THE ELECTRON EXCITATION SPECTRA IN HEAVY RARE EARTH METALS, HYDRIDES AND OXIDES C thin evaporated foils of heavy rare earths (Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu) in three different chemical of high energy incident electrons (75 keV) transmitted through thin foils of yttric rare earth elements

  17. Preparation of Prototypic Irradiated Hydrided-Zircaloy Cladding for UFDC Programs

    SciTech Connect (OSTI)

    Ott, Larry J [ORNL] [ORNL; Howard, Richard H [ORNL] [ORNL; Howard, Rob L [ORNL] [ORNL; McDuffee, Joel Lee [ORNL] [ORNL; Yan, Yong [ORNL] [ORNL

    2013-01-01

    The DOE Used Fuel Disposition Campaign (UFDC) has tasked ORNL to investigate the behavior of light-water-reactor fuel cladding material performance related to extended storage and transportation of used fuel. Fast neutron irradiation of pre-hydrided zirconium-alloy cladding in the High Flux Isotope Reactor (HFIR) at elevated temperatures has been used to simulate the effects of high burnup on used fuel cladding for use in understanding the materials properties relevant to very long-term storage (VLTS) and subsequent transportation. The irradiated pre-hydrided metallic materials will generate baseline data to benchmark hot-cell testing of high-burnup used fuel cladding; and, more importantly, samples free of alpha contamination can be provided to the researchers who do not have hot cell facilities to handle highly contaminated high-burnup used fuel cladding to support their research projects for the UFDC. In order to accomplish this research, ORNL has produced unirradiated zirconium-based cladding tubes with a certain hydrogen concentration. Two capsules (HYCD-1 and HYCD-2) containing hydrided zirconium-based samples, 9.50 mm (0.374 in) in diameter, were inserted in HFIR for neutron irradiation. HYCD-1 was removed after Cycle 440B and HYCD-2 after Cycle 442. This paper will describe the general HYCD experiment configuration, achieved temperatures, and temperature gradients within the cladding, and current results of the PIE of the irradiated hydrided cladding samples.

  18. Effect of Gaseous Impurities on Long-Term Thermal Cycling and Aging Properties of Complex Hydrides for Hydrogen Storage

    SciTech Connect (OSTI)

    Chandra, Dhanesh; Lamb, Joshua; Chien, Wen-Ming; Talekar, Anjali; and Pal, Narendra.

    2011-03-28

    This program was dedicated to understanding the effect of impurities on Long-Term Thermal Cycling and aging properties of Complex Hydrides for Hydrogen Storage. At the start of the program we found reversibility between Li2NH+LiH ? LiH+LiNH2 (yielding ~5.8 wt.%H capacity). Then we tested the effect of impurity in H2 gas by pressure cycling at 255oC; first with industrial gas containing ppm levels of O2 and H2O as major impurities. Both these impurities had a significant impact on the reversibility and decreased the capacity by 2.65 wt.%H. Further increase in number of cycles from 500 to 1100 showed only a 0.2 wt%H more weight loss, showing some capacity is still maintained after a significant number of cycles. The loss of capacity is attributed to the formation of ~55 wt% LiH and ~30% Li2O, as major contaminant phases, along with the hydride Li2NH phase; suggesting loss of nitrogen during cycling. The effect of 100 ppm H2O in H2 also showed a decrease of ~2.5 wt.%H (after 560 cycles), and 100ppm O2 in H2; a loss of ~4.1 wt.%. Methane impurity (100 ppm, 100cycles), showed a very small capacity loss of 0.9 wt.%H under similar conditions. However, when Li3N was pressure cycled with 100ppmN2-H2 there were beneficial effects were observed (255oC); the reversible capacity increased to 8.4wt.%H after 853 cycles. Furthermore, with 20 mol.%N2-H2 capacity increased to ~10 wt.%H after 516 cycles. We attribute this enhancement to the reaction of nitrogen with liquid lithium during cycling as the Gibbs free energy of formation of Li3N (?Go = -98.7 kJ/mol) is more negative than that of LiH (?Go = -50.3 kJ/mol). We propose that the mitigation of hydrogen capacity losses is due to the destabilization of the LiH phase that tends to accumulate during cycling. Also more Li2NH phase was found in the cycled product. Mixed Alanates (3LiNH2:Li3AlH6) showed that 7 wt% hydrogen desorbed under dynamic vacuum. Equilibrium experiments (maximum 12 bar H2) showed up to 4wt% hydrogen reversibly stored in the material after the first desorption. The activation energy was found to be 51 kJ/mol, as compared to 81 kJ/mol for pure lithium alanate. It is proposed that based on the data obtained and CALPHAD modeling that the improvement in cycling is due to the formation of pure lithium (liquid at 255oC), which is able to react with nitrogen specifically forming Li3N. The presence of nitrogen in the 80/20 molar mixtures in a hydride bed along with hydrogen causes Li to form Li3N rather than LiH, and subsequently regenerates the Li2NH phase and yields a ~10 wt.%H reversibly.

  19. URANIUM METAL POWDER PRODUCTION, PARTICLE DISTRIBUTION ANALYSIS, AND REACTION RATE STUDIES OF A HYDRIDE-DEHYDRIDE PROCESS 

    E-Print Network [OSTI]

    Sames, William

    2011-08-08

    Work was done to study a hydride-dehydride method for producing uranium metal powder. Particle distribution analysis was conducted using digital microscopy and grayscale image analysis software. The particle size was found ...

  20. Thermal analysis of uranium zirconium hydride fuel using a lead-bismuth gap at LWR operating temperatures

    E-Print Network [OSTI]

    Ensor, Brendan M. (Brendan Melvin)

    2012-01-01

    Next generation nuclear technology calls for more advanced fuels to maximize the effectiveness of new designs. A fuel currently being studied for use in advanced light water reactors (LWRs) is uranium zirconium hydride ...

  1. The influence of surface morphology and oxide microstructure on the nucleation and growth of uranium hydride on alpha uranium

    SciTech Connect (OSTI)

    Hanrahan, R.J. Jr.; Hawley, M.E.; Brown, G.W.

    1998-12-31

    While the bulk kinetics of the uranium-hydrogen reaction are well understood, the mechanisms underlying the initial nucleation of uranium hydride on uranium remain controversial. In this study, the authors have employed environmental cell optical microscopy, Scanning Electron Microscopy (SEM) and Atomic Force Microscopy, (AFM) in an attempt to relate the structure of the surface and the microstructure of the substrate with the susceptibility and site of hydride nucleation. Samples have been investigated with varying grain size, inclusion (carbide) concentration, and thermal history. There is a clear correlation to heat treatment immediately prior to hydrogen exposure. Susceptibility to hydride formation also appears to be related to impurities in the uranium. The oxidized surface is very complex, exhibiting wide variations in thickness and topography between samples, between grains in the same sample, and within individual grains. It is, however, very difficult to relate this fine scale variability to the relatively sparse hydride initiation sites. Therefore, the surface oxide layer itself does not appear to control the sites where hydride attack is initiated, although it must play a role in the induction period prior to hydride initiation.

  2. Fast, Quantitative, and Nondestructive Evaluation on Hydrided LWR Fuel Cladding by Small Angle Incoherent Neutron Scattering of Hydrogen

    SciTech Connect (OSTI)

    Yan, Yong; Qian, Shuo; Littrell, Ken; Parish, Chad M; Plummer, Lee K

    2015-01-01

    A non-destructive neutron scattering method to precisely measure the uptake of hydrogen and the distribution of hydride precipitates in light water reactor (LWR) fuel cladding was developed. Zircaloy-4 cladding used in commercial LWRs was used to produce hydrided specimens. The hydriding apparatus consists of a closed stainless steel vessel that contains Zr alloy specimens and hydrogen gas. Following hydrogen charging, the hydrogen content of the hydrided specimens was measured using the vacuum hot extraction method, by which the samples with desired hydrogen concentration were selected for the neutron study. Optical microscopy shows that our hydriding procedure results in uniform distribution of circumferential hydrides across the wall. Small angle neutron incoherent scattering was performed in the High Flux Isotope Reactor at Oak Ridge National Laboratory. Our study demonstrates that the hydrogen in commercial Zircaloy-4 cladding can be measured very accurately in minutes by this nondestructive method over a wide range of hydrogen concentrations from a very small amount ( 20 ppm) to over 1000 ppm. The hydrogen distribution in a tube sample was obtained by scaling the neutron scattering rate with a factor determined by a calibration process using standard, destructive direct chemical analysis methods on the specimens. This scale factor can be used in future tests with unknown hydrogen concentrations, thus providing a nondestructive method for absolute hydrogen concentration determination.

  3. Using magnetization measurements to detect small amounts of plutonium hydride formation in plutonium metal

    SciTech Connect (OSTI)

    Kim, Jae Wook [Rutgers Univ., New Brunswick, NJ (United States); Mielke, Charles H. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Zapf, Vivien [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Baiardo, Joseph P. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Mitchell, Jeremy N. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Richmond, Scott [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Schwartz, Daniel S. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Mun, Eun D. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Smith, Alice Iulia [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2014-10-20

    We report the formation of plutonium hydride in 2 at % Ga-stabilized ?-Pu, with 1 atomic % H charging. We show that magnetization measurements are a sensitive, quantitative measure of ferromagnetic plutonium hydride against the nonmagnetic background of plutonium. It was previously shown that at low hydrogen concentrations, hydrogen forms super-abundant vacancy complexes with plutonium, resulting in a bulk lattice contraction. Here we use magnetization, X-ray and neutron diffraction measurements to show that in addition to forming vacancy complexes, at least 30% of the H atoms bond with Pu to precipitate PuHx, largely on the surface of the sample with x ~ 1.9. We observe magnetic hysteresis loops below 40 K with magnetic remanence, consistent with precipitates of ferromagnetic PuH1.9.

  4. Method to predict relative hydriding within a group of zirconium alloys under nuclear irradiation

    DOE Patents [OSTI]

    Johnson, A.B. Jr.; Levy, I.S.; Trimble, D.J.; Lanning, D.D.; Gerber, F.S.

    1990-04-10

    An out-of-reactor method for screening to predict relative in-reactor hydriding behavior of zirconium-based materials is disclosed. Samples of zirconium-based materials having different compositions and/or fabrication methods are autoclaved in a relatively concentrated (0.3 to 1.0M) aqueous lithium hydroxide solution at constant temperatures within the water reactor coolant temperature range (280 to 316 C). Samples tested by this out-of-reactor procedure, when compared on the basis of the ratio of hydrogen weight gain to oxide weight gain, accurately predict the relative rate of hydriding for the same materials when subject to in-reactor (irradiated) corrosion. 1 figure.

  5. High Resolution Neutron Radiography and Tomography of Hydrided Zircaloy-4 Cladding Materials

    SciTech Connect (OSTI)

    Smith, Tyler S; Bilheux, Hassina Z; Ray, Holly B; Bilheux, Jean-Christophe; Yan, Yong

    2015-01-01

    Neutron radiography for hydrogen analysis was performed with several Zircaloy-4 cladding samples with controlled hydrogen concentrations up to 1100 ppm. Hydrogen charging was performed in a process tube that was heated to facilitate hydrogen absorption by the metal. A correlation between the hydrogen concentration in the hydrided tubes and the neutron intensity was established, by which hydrogen content can be determined precisely in a small area (55 m x 55 m). Radiography analysis was also performed to evaluate the heating rate and its correlation with the hydrogen distribution through hydrided materials. In addition to radiography analysis, tomography experiments were performed on Zircaloy-4 tube samples to study the local hydrogen distribution. Through tomography analysis a 3D reconstruction of the tube was evaluated in which an uneven hydrogen distribution in the circumferential direction can be observed.

  6. Synthesis, NMR spectra, and structure of rhodium hydride complexes with Rh-Sn bonds

    SciTech Connect (OSTI)

    Krut'ko, B.P.; Permin, A.B.; Petrosyan, V.S.; Reutov, O.A.

    1985-06-20

    The authors study the hydride complexes using Sn 119 and H 1 NMR spectroscopy. The spectra were taken in a pulse mode on a Varian FT-80A spectrometer equipped with a wideband system at 29.66 and 79.54 MHz. The Sn 119 and H 1 NMR spectral parameters for a solution of the complex (Bu/sub 4/N)/sub 3/ (HRh(SnCl/sub 3/)/sub 5/) in CD/sub 3/CN are shown, the spectra show that the (HRh(SnCl/sub 3/)/sub 5/)/sup 3 -/ anion has octahedral structure with four equatorial and one axial Rh-Sn bonds. New rhodium hydride complexes with general formula (R/sub 4/N)/sub 3/(HRh(SnCl/sub 3/)/sub 5/) were synthesized.

  7. Engineering of the band gap and optical properties of thin films of yttrium hydride

    SciTech Connect (OSTI)

    You, Chang Chuan; Mongstad, Trygve; Maehlen, Jan Petter; Karazhanov, Smagul, E-mail: smagulk@ife.no [Institute for Energy Technology, P.O. Box 40, NO-2027 Kjeller (Norway)

    2014-07-21

    Thin films of oxygen-containing yttrium hydride show photochromic effect at room temperature. In this work, we have studied structural and optical properties of the films deposited at different deposition pressures, discovering the possibility of engineering the optical band gap by variation of the oxygen content. In sum, the transparency of the films and the wavelength range of photons triggering the photochromic effect can be controlled by variation of the deposition pressure.

  8. Venkat Srinivasan John W. Weidner Ralph E. White Mathematical models of the nickel hydroxide active material

    E-Print Network [OSTI]

    -cadmium, nickel-metal hydride, nickel-zinc, and nickel-hydrogen batteries [1]. However, even after a century. The negative electrode used in the cell could be a porous cadmium, metal hydride, zinc, or gas-fed hydrogen Á R.E. White (&) Department of Chemical Engineering, Swearingen Engineering Building, University

  9. OPTIMIZATION OF INTERNAL HEAT EXCHANGERS FOR HYDROGEN STORAGE TANKS UTILIZING METAL HYDRIDES

    SciTech Connect (OSTI)

    Garrison, S.; Tamburello, D.; Hardy, B.; Anton, D.; Gorbounov, M.; Cognale, C.; van Hassel, B.; Mosher, D.

    2011-07-14

    Two detailed, unit-cell models, a transverse fin design and a longitudinal fin design, of a combined hydride bed and heat exchanger are developed in COMSOL{reg_sign} Multiphysics incorporating and accounting for heat transfer and reaction kinetic limitations. MatLab{reg_sign} scripts for autonomous model generation are developed and incorporated into (1) a grid-based and (2) a systematic optimization routine based on the Nelder-Mead downhill simplex method to determine the geometrical parameters that lead to the optimal structure for each fin design that maximizes the hydrogen stored within the hydride. The optimal designs for both the transverse and longitudinal fin designs point toward closely-spaced, small cooling fluid tubes. Under the hydrogen feed conditions studied (50 bar), a 25 times improvement or better in the hydrogen storage kinetics will be required to simultaneously meet the Department of Energy technical targets for gravimetric capacity and fill time. These models and methodology can be rapidly applied to other hydrogen storage materials, such as other metal hydrides or to cryoadsorbents, in future work.

  10. Gas Diffusion in Metals: Fundamental Study of Helium-Point Defect Interactions in Iron and Kinetics of Hydrogen Desorption from Zirconium Hydride

    E-Print Network [OSTI]

    Hu, Xunxiang

    2013-01-01

    steel, nickel, iron and zirconium. Nucl. Instrum. MethodsSteinbruck. Hydrogen absorption by zirconium alloys at highHydride formation in zirconium alloys. JOM. 64 R. Yang, O.

  11. Draft of M2 Report on Integration of the Hybrid Hydride Model into INL’s MBM Framework for Review

    SciTech Connect (OSTI)

    Tikare, Veena; Weck, Philippe F.; Schultz, Peter A.; Clark, Blythe; Glazoff, Michael; Homer, Eric

    2014-07-01

    This report documents the development, demonstration and validation of a mesoscale, microstructural evolution model for simulation of zirconium hydride {delta}-ZrH{sub 1.5} precipitation in the cladding of used nuclear fuels that may occur during long-term dry storage. While the Zr-based claddings are manufactured free of any hydrogen, they absorb hydrogen during service, in the reactor by a process commonly termed ‘hydrogen pick-up’. The precipitation and growth of zirconium hydrides during dry storage is one of the most likely fuel rod integrity failure mechanisms either by embrittlement or delayed hydride cracking of the cladding (Hanson et al., 2011). While the phenomenon is well documented and identified as a potential key failure mechanism during long-term dry storage (Birk et al., 2012 and NUREG/CR-7116), the ability to actually predict the formation of hydrides is poor. The model being documented in this work is a computational capability for the prediction of hydride formation in different claddings of used nuclear fuels. This work supports the Used Fuel Disposition Research and Development Campaign in assessing the structural engineering performance of the cladding during and after long-term dry storage. This document demonstrates a basic hydride precipitation model that is built on a recently developed hybrid Potts-phase field model that combines elements of Potts-Monte Carlo and the phase-field models (Homer et al., 2013; Tikare and Schultz, 2012). The model capabilities are demonstrated along with the incorporation of the starting microstructure, thermodynamics of the Zr-H system and the hydride formation mechanism.

  12. ReaxFFMgH Reactive Force Field for Magnesium Hydride Systems Sam Cheung, Wei-Qiao Deng, Adri C. T. van Duin, and William A. Goddard III*

    E-Print Network [OSTI]

    van Duin, Adri

    ReaxFFMgH Reactive Force Field for Magnesium Hydride Systems Sam Cheung, Wei-Qiao Deng, Adri C. T and Chemical Engineering, California Institute of Technology, Pasadena, California 91125 ReceiVed: September 3FFMgH) for magnesium and magnesium hydride systems. The parameters for this force field were derived from fitting

  13. Time-resolved photoluminescence studies of free and donor-bound exciton in GaN grown by hydride vapor phase epitaxy

    E-Print Network [OSTI]

    Time-resolved photoluminescence studies of free and donor-bound exciton in GaN grown by hydride and Electrical and Computer Engineering and Photonics Center, Boston University, Boston, Massachusetts, 02215 R in unintentionally doped GaN grown by hydride vapor phase epitaxy. Low temperature (4 K), time-integrated PL spectra

  14. Modifying Carbon Cryogel-Hydride Nanocomposites for H2 Storage Saghar Sepehri, Betzaida Batalla Garca, Aaron Feaver, Qifeng Zhang, and Guozhong Cao

    E-Print Network [OSTI]

    Cao, Guozhong

    Modifying Carbon Cryogel- Hydride Nanocomposites for H2 Storage Saghar Sepehri, Betzaida Batalla García, Aaron Feaver, Qifeng Zhang, and Guozhong Cao Materials Science and Engineering, University resorcinol-formaldehyde CCs as nanoscaffold for hydrides. Ammonia borane (AB), a stable, white, crystalline

  15. Calculation of properties of crystalline lithium hydride using correlated wave function theory S. J. Nolan,1 M. J. Gillan,2,3 D. Alf,2,3,4 N. L. Allan,1 and F. R. Manby1

    E-Print Network [OSTI]

    Alfč, Dario

    Calculation of properties of crystalline lithium hydride using correlated wave function theory S. J, and cohesive energy of lithium hydride are calculated to very high accuracy through a combination of periodic. All calculated properties of lithium hydride and deuteride agree with empirical observations to within

  16. Mechanistic study of the isotopic-exchange reaction between gaseous hydrogen and palladium hydride powder

    SciTech Connect (OSTI)

    Outka, D.A.; Foltz, G.W. (Sandia National Labs., Livermore, CA (USA))

    1991-07-01

    A detailed mechanism for the isotopic-exchange reaction between gaseous hydrogen and solid palladium hydride is developed which extends previous model for this reaction by specifically including surface reactions. The modeling indicates that there are two surface-related processes that contribute to the overall rate of exchange: the desorption of hydrogen from the surface and the exchange between surface hydrogen and bulk hydrogen. This conclusion is based upon measurements examining the effect of small concentrations of carbon monoxide were helpful in elucidating the mechanism. Carbon monoxide reversibly inhibits certain steps in the exchange; this slows the overall rate of exchange and changes the distribution of products from the reactor.

  17. Metal hydrides as electrode/catalyst materials for oxygen evolution/reduction in electrochemical devices

    DOE Patents [OSTI]

    Bugga, Ratnakumar V. (Arcadia, CA); Halpert, Gerald (Pasadena, CA); Fultz, Brent (Pasadena, CA); Witham, Charles K. (Pasadena, CA); Bowman, Robert C. (La Mesa, CA); Hightower, Adrian (Whittier, CA)

    1997-01-01

    An at least ternary metal alloy of the formula, AB.sub.(5-Y)X(.sub.y), is claimed. In this formula, A is selected from the rare earth elements, B is selected from the elements of groups 8, 9, and 10 of the periodic table of the elements, and X includes at least one of the following: antimony, arsenic, and bismuth. Ternary or higher-order substitutions, to the base AB.sub.5 alloys, that form strong kinetic interactions with the predominant metals in the base metal hydride are used to form metal alloys with high structural integrity after multiple cycles of hydrogen sorption.

  18. Measurements of Ionic Structure in Shock Compressed Lithium Hydride from Ultrafast X-Ray Thomson Scattering

    SciTech Connect (OSTI)

    Kritcher, A. L. [L-399, Lawrence Livermore National Laboratory, P.O. Box 808, Livermore, California 94551 (United States); Department of Nuclear Engineering, University of California Berkeley, Berkeley, California 94709 (United States); Neumayer, P.; Doeppner, T.; Landen, O. L.; Glenzer, S. H. [L-399, Lawrence Livermore National Laboratory, P.O. Box 808, Livermore, California 94551 (United States); Brown, C. R. D. [Department of Physics, Imperial College, London SW7 2AZ (United Kingdom); AWE plc., Aldermaston, Reading, RG7 4PR (United Kingdom); Davis, P. [L-399, Lawrence Livermore National Laboratory, P.O. Box 808, Livermore, California 94551 (United States); Department of Physics, University of California Berkeley, Berkeley, California 94709 (United States); Falcone, R. W.; Lee, H. J. [Department of Physics, University of California Berkeley, Berkeley, California 94709 (United States); Gericke, D. O.; Vorberger, J.; Wuensch, K. [CFSA, Department of Physics, University of Warwick, Coventry CV4 7AL (United Kingdom); Gregori, G. [Department of Physics, Oxford University, Oxford OX1 3PU (United Kingdom); Holst, B.; Redmer, R. [Universitaet Rostock, Institut fuer Physik, D-18051 Rostock (Germany); Morse, E. C. [Department of Nuclear Engineering, University of California Berkeley, Berkeley, California 94709 (United States); Pelka, A.; Roth, M. [Institut fuer Kernphysik, Technische Universitaet Darmstadt, Darmstadt (Germany)

    2009-12-11

    We present the first ultrafast temporally, spectrally, and angularly resolved x-ray scattering measurements from shock-compressed matter. The experimental spectra yield the absolute elastic and inelastic scattering intensities from the measured density of free electrons. Laser-compressed lithium-hydride samples are well characterized by inelastic Compton and plasmon scattering of a K-alpha x-ray probe providing independent measurements of temperature and density. The data show excellent agreement with the total intensity and structure when using the two-species form factor and accounting for the screening of ion-ion interactions.

  19. Method and apparatus for storing hydrogen isotopes. [stored as uranium hydride in a block of copper

    DOE Patents [OSTI]

    McMullen, J.W.; Wheeler, M.G.; Cullingford, H.S.; Sherman, R.H.

    1982-08-10

    An improved method and apparatus for storing isotopes of hydrogen (especially tritium) are provided. The hydrogen gas is stored as hydrides of material (for example uranium) within boreholes in a block of copper. The mass of the block is critically important to the operation, as is the selection of copper, because no cooling pipes are used. Because no cooling pipes are used, there can be no failure due to cooling pipes. And because copper is used instead of stainless steel, a significantly higher temperature can be reached before the eutectic formation of uranium with copper occurs, (the eutectic of uranium with the iron in stainless steel forms at a significantly lower temperature).

  20. Complex Hydrides-A New Frontier for Future Energy Applications | The Ames

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would like submit the following commentsMethods for Estimating:ILaboratory Hydrides-A New

  1. The effects of phosphorous donor ligand substitution on the reactivity of anionic group 6 transition metal carbonyl hydrides 

    E-Print Network [OSTI]

    Lusk, Richard Jay

    1986-01-01

    in THP, followed by protonation with methanol, gave rise to a new group of chromium and tungsten hydrides, 7 HM(CO) P . The importance of the P-substituted hydr ides is enhanced 4 reactivity as well as the possibility of selective hydride transfer... reduction products were thus benzyl alcohol and octane. Initial GC runs were undertaken using THF solutions of benzyl alcohol of three different concentrations, corresponding to yields of 25, 100, and 150$. Each of the three also contained an equivalent...

  2. THERMAL ENHANCEMENT CARTRIDGE HEATER MODIFIED TECH MOD TRITIUM HYDRIDE BED DEVELOPMENT PART I DESIGN AND FABRICATION

    SciTech Connect (OSTI)

    Klein, J.; Estochen, E.

    2014-03-06

    The Savannah River Site (SRS) tritium facilities have used 1{sup st} generation (Gen1) LaNi{sub 4.25}Al{sub 0.75} (LANA0.75) metal hydride storage beds for tritium absorption, storage, and desorption. The Gen1 design utilizes hot and cold nitrogen supplies to thermally cycle these beds. Second and 3{sup rd} generation (Gen2 and Gen3) storage bed designs include heat conducting foam and divider plates to spatially fix the hydride within the bed. For thermal cycling, the Gen2 and Gen 3 beds utilize internal electric heaters and glovebox atmosphere flow over the bed inside the bed external jacket for cooling. The currently installed Gen1 beds require replacement due to tritium aging effects on the LANA0.75 material, and cannot be replaced with Gen2 or Gen3 beds due to different designs of these beds. At the end of service life, Gen1 bed desorption efficiencies are limited by the upper temperature of hot nitrogen supply. To increase end-of-life desorption efficiency, the Gen1 bed design was modified, and a Thermal Enhancement Cartridge Heater Modified (TECH Mod) bed was developed. Internal electric cartridge heaters in the new design to improve end-of-life desorption, and also permit in-bed tritium accountability (IBA) calibration measurements to be made without the use of process tritium. Additional enhancements implemented into the TECH Mod design are also discussed.

  3. A Novel Zr-1Nb Alloy and a New Look at Hydriding

    SciTech Connect (OSTI)

    Robert D. Mariani; James I. Cole; Assel Aitkaliyeva

    2013-09-01

    A novel Zr-1Nb has begun development based on a working model that takes into account the hydrogen permeabilities for zirconium and niobium metals. The beta-Nb secondary phase particles (SPPs) in Zr-1Nb are believed to promote more rapid hydrogen dynamics in the alloy in comparison to other zirconium alloys. Furthermore, some hydrogen release is expected at the lower temperatures corresponding to outages when the partial pressure of H2 in the coolant is less. These characteristics lessen the negative synergism between corrosion and hydriding that is otherwise observed in cladding alloys without niobium. In accord with the working model, development of nanoscale precursors was initiated to enhance the performance of existing Zr-1Nb alloys. Their characteristics and properties can be compared to oxide-dispersion strengthened alloys, and material additions have been proposed to zirconium-based LWR cladding to guard further against hydriding and to fix the size of the SPPs for microstructure stability enhancements. A preparative route is being investigated that does not require mechanical alloying, and 10 nanometer molybdenum particles have been prepared which are part of the nanoscale precursors. If successful, the approach has implications for long term dry storage of used fuel and for new routes to nanoferritic and ODS alloys.

  4. Rapid hydrogen gas generation using reactive thermal decomposition of uranium hydride.

    SciTech Connect (OSTI)

    Kanouff, Michael P.; Van Blarigan, Peter; Robinson, David B.; Shugard, Andrew D.; Gharagozloo, Patricia E.; Buffleben, George M.; James, Scott Carlton; Mills, Bernice E.

    2011-09-01

    Oxygen gas injection has been studied as one method for rapidly generating hydrogen gas from a uranium hydride storage system. Small scale reactors, 2.9 g UH{sub 3}, were used to study the process experimentally. Complimentary numerical simulations were used to better characterize and understand the strongly coupled chemical and thermal transport processes controlling hydrogen gas liberation. The results indicate that UH{sub 3} and O{sub 2} are sufficiently reactive to enable a well designed system to release gram quantities of hydrogen in {approx} 2 seconds over a broad temperature range. The major system-design challenge appears to be heat management. In addition to the oxidation tests, H/D isotope exchange experiments were performed. The rate limiting step in the overall gas-to-particle exchange process was found to be hydrogen diffusion in the {approx}0.5 {mu}m hydride particles. The experiments generated a set of high quality experimental data; from which effective intra-particle diffusion coefficients can be inferred.

  5. Extensive relativistic calculations on the palladium hydride molecule Merethe Sjo"voll, Hilde Fagerli, Odd Gropen, and Jan Almlofa)

    E-Print Network [OSTI]

    Helgaker, Trygve

    Extensive relativistic calculations on the palladium hydride molecule Merethe Sjo"voll, Hilde to a series of molecules.8 Palladium and palladium compounds are important in catalytic processes of this, there have been relatively few calculations on palladium compounds.10 Essential

  6. In-situ study of hydride precipitation kinetics and re-orientation in Zircaloy using synchrotron radiation

    E-Print Network [OSTI]

    Motta, Arthur T.

    In-situ study of hydride precipitation kinetics and re- orientation in Zircaloy using synchrotron. Banchik4 , P. Vizcaino4 and J. R. Santisteban5 1. Department of Mechanical and Nuclear Engineering, Penn, Argonne, IL, USA 3. Department of Mechanical and Materials Engineering, Queen's University, Kingston, ON

  7. Identification and quantification of hydride phases in Zircaloy-4 cladding using synchrotron X-ray diffraction q

    E-Print Network [OSTI]

    Motta, Arthur T.

    Identification and quantification of hydride phases in Zircaloy-4 cladding using synchrotron X-ray diffraction q R.S. Daum a,1 , Y.S. Chu b,2 , A.T. Motta c,* a Nuclear Engineering Division, Argonne National, IL 60439, United States c Department of Mechanical and Nuclear Engineering, The Pennsylvania State

  8. Verification and Validation Strategy for Implementation of Hybrid Potts-Phase Field Hydride Modeling Capability in MBM

    SciTech Connect (OSTI)

    Jason D. Hales; Veena Tikare

    2014-04-01

    The Used Fuel Disposition (UFD) program has initiated a project to develop a hydride formation modeling tool using a hybrid Potts­phase field approach. The Potts model is incorporated in the SPPARKS code from Sandia National Laboratories. The phase field model is provided through MARMOT from Idaho National Laboratory.

  9. Metal Hydrides

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankADVANCED MANUFACTURING OFFICESpecial ReportProposal to changeNovemberEnergyMessage fromMetal

  10. Hydride vapor phase GaN films with reduced density of residual electrons and deep traps

    SciTech Connect (OSTI)

    Polyakov, A. Y.; Smirnov, N. B.; Govorkov, A. V.; Yugova, T. G.; Cox, H.; Helava, H.; Makarov, Yu.; Usikov, A. S.

    2014-05-14

    Electrical properties and deep electron and hole traps spectra are compared for undoped n-GaN films grown by hydride vapor phase epitaxy (HVPE) in the regular process (standard HVPE samples) and in HVPE process optimized for decreasing the concentration of residual donor impurities (improved HVPE samples). It is shown that the residual donor density can be reduced by optimization from ?10{sup 17}?cm{sup ?3} to (2–5)?×?10{sup 14}?cm{sup ?3}. The density of deep hole traps and deep electron traps decreases with decreased donor density, so that the concentration of deep hole traps in the improved samples is reduced to ?5?×?10{sup 13}?cm{sup ?3} versus 2.9?×?10{sup 16}?cm{sup ?3} in the standard samples, with a similar decrease in the electron traps concentration.

  11. Reaction kinetics relevant to the recycle hydride-dehydride process for plutonium recovery

    SciTech Connect (OSTI)

    Haschke, J.M.; Allen, T.H.

    1997-10-01

    Objectives of this one-year, Laboratory Directed Research and Development (LDRD) project were the expansion of fundamental knowledge of plutonium chemistry and the development of information for enhancing plutonium recovery methods and weapons safety. Results of kinetic studies demonstrate that the monoxide monohydride, PuO(H), formed during corrosion of plutonium by water in pyrophoric when dry and acts as an initiator for hydride-catalyzed reaction of the metal with air. The catalyzed corrosion rate of Pu is 10{sup 8} times faster than that in dry air and transforms plutonium into a readily aerosolized material. A potential application for the catalytic reaction is in the direct recovery of plutonium as oxide. Wet PuO(H) is non-pyrophoric and the safety hazard posed by its formation is reduced if the material is not allowed to dry.

  12. LaNi{sub 5}-based metal hydride electrode in Ni-MH rechargeable cells

    DOE Patents [OSTI]

    Bugga, R.V.; Fultz, B.; Bowman, R.; Surampudi, S.R.; Witham, C.K.; Hightower, A.

    1999-03-30

    An at least ternary metal alloy of the formula AB{sub (Z-Y)}X{sub (Y)} is disclosed. In this formula, A is selected from the rare earth elements, B is selected from the elements of Groups 8, 9, and 10 of the Periodic Table of the Elements, and X includes at least one of the following: antimony, arsenic, germanium, tin or bismuth. Z is greater than or equal to 4.8 and less than or equal to 6.0. Y is greater than 0 and less than 1. Ternary or higher-order substitutions to the base AB{sub 5} alloys that form strong kinetic interactions with the predominant metals in the base metal hydride are used to form metal alloys with high structural integrity after multiple cycles of hydrogen sorption. 16 figs.

  13. Method to predict relative hydriding within a group of zirconium alloys under nuclear irradiation

    DOE Patents [OSTI]

    Johnson, Jr., A. Burtron (Richland, WA); Levy, Ira S. (Kennewick, WA); Trimble, Dennis J. (Kennewick, WA); Lanning, Donald D. (Kennewick, WA); Gerber, Franna S. (Richland, WA)

    1990-01-01

    An out-of-reactor method for screening to predict relative in-reactor hydriding behavior of zirconium-bsed materials is disclosed. Samples of zirconium-based materials having different composition and/or fabrication are autoclaved in a relatively concentrated (0.3 to 1.0M) aqueous lithium hydroxide solution at constant temperatures within the water reactor coolant temperature range (280.degree. to 316.degree. C.). Samples tested by this out-of-reactor procedure, when compared on the basis of the ratio of hydrogen weight gain to oxide weight gain, accurately predict the relative rate of hyriding for the same materials when subject to in-reactor (irradiated) corrision.

  14. RF sputtering for controlling dihydride and monohydride bond densities in amorphous silicon hydride

    DOE Patents [OSTI]

    Jeffery, F.R.; Shanks, H.R.

    1980-08-26

    A process is described for controlling the dihydride and monohydride bond densities in hydrogenated amorphous silicone produced by reactive rf sputtering of an amorphous silicon target. There is provided a chamber with an amorphous silicon target and a substrate therein with the substrate and the target positioned such that when rf power is applied to the target the substrate is in contact with the sputtering plasma produced thereby. Hydrogen and argon are fed to the chamber and the pressure is reduced in the chamber to a value sufficient to maintain a sputtering plasma therein, and then rf power is applied to the silicon target to provide a power density in the range of from about 7 watts per square inch to about 22 watts per square inch to sputter an amorphous solicone hydride onto the substrate, the dihydride bond density decreasing with an increase in the rf power density. Substantially pure monohydride films may be produced.

  15. The anti-perovskite type hydride InPd{sub 3}H{sub 0.89}

    SciTech Connect (OSTI)

    Kohlmann, H.; Skripov, A.V.; Soloninin, A.V.; Udovic, T.J.

    2010-10-15

    Hydrogenation of tetragonal InPd{sub 3} in the ZrAl{sub 3} type structure (four-fold ccp superstructure) yields a hydride with a cubic AuCu{sub 3} type structure (one-fold ccp superstructure). Deuterium can be located by neutron powder diffraction in octahedral voids surrounded exclusively by palladium, [Pd{sub 6}], which are 88.5(6)% occupied in a statistical manner. The resulting deuteride InPd{sub 3}D{sub 0.89} thus crystallizes in a cubic anti-perovskite type structure (space group Pm3-bar m (no. 221), a=402.25(1) pm at 299(2) K). The Pd-D distance of 201.13(1) pm is typical for interstitial hydrides with palladium. Inelastic neutron scattering on the hydride InPd{sub 3}H{sub 0.89}, which shows a spectrum similar to that of binary palladium hydride, confirms the cubic site symmetry of hydrogen in [Pd{sub 6}] interstices. This is also confirmed by the absence of any quadrupole splitting in the {sup 2}D-NMR signal of the deuteride. {sup 1}H NMR spectra of InPd{sub 3}H{sub 0.89} do not show any motional narrowing. Values found for the H jump rate {tau}{sup -1} in InPd{sub 3}H{sub 0.89} remain below 10{sup 6} s{sup -1} in the studied temperature range 28-360 K, indicating a small hydrogen mobility in InPd{sub 3}H{sub 0.8} as compared with binary palladium hydride, PdH{sub {<=}1}. This can be attributed to the large spatial separation of the [Pd{sub 6}] sites. - Graphical abstract: Hydrogen induces a rearrangement in InPd{sub 3} from a ZrAl{sub 3} type structure to a cubic AuCu{sub 3} type structure, thus forming an anti-perovskite type hydride InPd{sub 3}H{sub 0.89}.

  16. Erroneous Wave Functions of Ciuchi et al for Collective Modes in Neutron Production on Metallic Hydride Cathodes

    E-Print Network [OSTI]

    A. Widom; Y. N. Srivastava; L. Larsen

    2012-10-17

    There is a recent comment (Ciuchi et al., 2012) concerning the theory of collective many body effects on the neutron production rates in a chemical battery cathode. Ciuchi et al employ an inverse beta decay expression that contains a two body amplitude. Only one electron and one proton may exist in the Ciuchi et al model initial state wave function. A flaw in their reasoning is that one cannot in reality describe collective many body correlations with only a two particle wave function. One needs very many particles to describe collective effects. In the model wave functions of Ciuchi et al there are no metallic hydrides, there are no cathodes and there are no chemical batteries. Employing a wave function with only one electron and one proton is inadequate for describing collective metallic hydride surface quantum plasma physics in cathodes accurately.

  17. Facile synthesis of Ba1-xKxFe?As? superconductors via hydride route

    SciTech Connect (OSTI)

    Zaikina, Julia V. [Univ. of California at Davis, Davis, CA (United States); Batuk, Maria [Univ. of Antwerp, Antwerp (Belgium); Abakumov, Artem M. [Univ. of Antwerp, Antwerp (Belgium); Navrotsky, Alexandra [Univ. of California at Davis, Davis, CA (United States); Kauzlarich, Susan M. [Univ. of California at Davis, Davis, CA (United States)

    2014-12-03

    We have developed a fast, easy, and scalable synthesis method for Ba1-xKxFe?As? (0 ? x ? 1) superconductors using hydrides BaH? and KH as a source of barium and potassium metals. Synthesis from hydrides provides better mixing and easier handling of the starting materials, consequently leading to faster reactions and/or lower synthesis temperatures. The reducing atmosphere provided by the evolved hydrogen facilitates preparation of oxygen-free powders. By a combination of methods we have shown that Ba1-xKxFe?As? obtained via hydride route has the same characteristics as when it is prepared by traditional solid-state synthesis. Refinement from synchrotron powder X-ray diffraction data confirms a linear dependence of unit cell parameters upon K content as well as the tetragonal to orthorhombic transition at low temperatures for compositions with x < 0.2. Magnetic measurements revealed dome-like dependence of superconducting transition temperature Tc upon K content with a maximum of 38 K for x close to 0.4. Electron diffraction and high-resolution high-angle annular dark-field scanning transmission electron microscopy indicates an absence of Ba/K ordering, while local inhomogeneity in the Ba/K distribution takes place at a scale of several angstroms along [110] crystallographic direction.

  18. Microstructure and hydriding studies of AB/sub 5/ hydrogen storage compounds. Final report

    SciTech Connect (OSTI)

    Goodell, P.D.; Sandrock, G.D.; Huston, E.L.

    1980-01-01

    New data on the microstructure, pressure-composition-temperature, and absorption/desorption kinetics of AB/sub 5/ metal hydrides are presented. The most significant result to emerge from the investigation is that many of the AB/sub 5/ metal hydrides, especially the LaNi/sub 5/ related materials, show instantaneous absorption and desorption response in proportion to the amount of cooling or heating which is provided. Eight categories of materials were studied: reference alloys (LaNi/sub 5/, LaNi/sub 4/ /sub 9/Al/sub 0/ /sub 1/, LaNi/sub 3/Co/sub 2/); Ni second phase particles (LaNi/sub 5/ /sub 67/, LaNi/sub 7/, LaNi/sub 11/ /sub 3/); eutectoid microstructure (SmCo/sub 5/); other second phases (LaNi/sub 3/ /sub 8/Fe/sub 1/ /sub 2/, LaNi/sub 3/ /sub 5/Cr/sub 1/ /sub 5/, LaNi/sub 4/Cr, LaNi/sub 4/Si; LaNi/sub 4/Sn, MNi/sub 4/Sn, MNi/sub 4/ /sub 3/Al/sub 0/ /sub 7/); substitutional elements (LaNi/sub 4/Cu, LaNi/sub 4/ /sub 5/Pd/sub 0/ /sub 5/, LaNi/sub 4/ /sub 7/Sn/sub 0/ /sub 3/, LaNi/sub 4/ /sub 8/C/sub 0/ /sub 2/, MNi/sub 4/ /sub 3/Mn/sub 0/ /sub 7/); surface active elements (LaNi/sub 4/ /sub 8/B/sub 0/ /sub 2/, LaNi/sub 4/ /sub 9/S/sub 0/ /sub 1/, LaNi/sub 4/ /sub 9/Se/sub 0/ /sub 1/); large diameter atom substitutions (Mg/sub 0/ /sub 1/La/sub 0/ /sub 9/Ni/sub 5/, Ca/sub 0/ /sub 2/La/sub 0/ /sub 8/Ni/sub 5/, Sr/sub 0/ /sub 2/La/sub 0/ /sub 8/Ni/sub 5/, Ba/sub 0/ /sub 2/La/sub 0/ /sub 8/Ni/sub 5/); other compositions (LaNi/sub 3/); and Pd plating (electroless plated samples and mechanically alloyed specimens).

  19. Change Number

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 OutreachProductswsicloudwsiclouddenDVA N C E D BGene Network ShapingDate: M-16-04-04 Federal FacilityChange Number

  20. Studies of isotopic exchange between gaseous hydrogen and palladium hydride powder

    SciTech Connect (OSTI)

    Foltz, G.W.; Melius, C.F.

    1987-12-01

    A gas flow apparatus has been constructed and used to study the isotopic exchange reaction occurring between the solid and gas phases in hydrogen (deuterium) gas flows directed through packed-powder beds of ..beta..-phase palladium deuteride (hydride). Spontaneous Raman light scattering is employed to obtain a real-time analysis of the isotopic composition of the gas (H/sub 2/, D/sub 2/, HD) exiting from the bed. A parametric rate-equation model is described which depicts the time-dependent behavior of the isotopic exchange process. The exchange mechanism is assumed to be rate-limited by processes occurring on the surface of the powder. The fundamental kinetic parameter of the model is the isotopic exchange probability, p, which is the probability that an isotopic exchange event occurs during a collision of a gas-phase atom with the surface. Isotope effects between the gas and solid phases are explicitly included in terms of the isotope separation factor, ..cap alpha... Results of the model are compared with the experimental measurements and, using a literature value of ..cap alpha.. = 2.4, good agreement is obtained for p approx. = 10/sup -7/. In view of the importance of the isotope effects in the hydrogen/palladium system and the range of a values reported for the ..beta..-phase in the literature, the sensitivity of the model results to a variation in the value of ..cap alpha.. is examined.

  1. Discovery of Novel Complex Metal Hydrides for Hydrogen Storage through Molecular Modeling and Combinatorial Methods

    SciTech Connect (OSTI)

    Lesch, David A; Adriaan Sachtler, J.W. J.; Low, John J; Jensen, Craig M; Ozolins, Vidvuds; Siegel, Don

    2011-02-14

    UOP LLC, a Honeywell Company, Ford Motor Company, and Striatus, Inc., collaborated with Professor Craig Jensen of the University of Hawaii and Professor Vidvuds Ozolins of University of California, Los Angeles on a multi-year cost-shared program to discover novel complex metal hydrides for hydrogen storage. This innovative program combined sophisticated molecular modeling with high throughput combinatorial experiments to maximize the probability of identifying commercially relevant, economical hydrogen storage materials with broad application. A set of tools was developed to pursue the medium throughput (MT) and high throughput (HT) combinatorial exploratory investigation of novel complex metal hydrides for hydrogen storage. The assay programs consisted of monitoring hydrogen evolution as a function of temperature. This project also incorporated theoretical methods to help select candidate materials families for testing. The Virtual High Throughput Screening served as a virtual laboratory, calculating structures and their properties. First Principles calculations were applied to various systems to examine hydrogen storage reaction pathways and the associated thermodynamics. The experimental program began with the validation of the MT assay tool with NaAlH4/0.02 mole Ti, the state of the art hydrogen storage system given by decomposition of sodium alanate to sodium hydride, aluminum metal, and hydrogen. Once certified, a combinatorial 21-point study of the NaAlH4 â?? LiAlH4 â??Mg(AlH4)2 phase diagram was investigated with the MT assay. Stability proved to be a problem as many of the materials decomposed during synthesis, altering the expected assay results. This resulted in repeating the entire experiment with a mild milling approach, which only temporarily increased capacity. NaAlH4 was the best performer in both studies and no new mixed alanates were observed, a result consistent with the VHTS. Powder XRD suggested that the reverse reaction, the regeneration of the alanate from alkali hydride, Al and hydrogen, was hampering reversibility. The reverse reaction was then studied for the same phase diagram, starting with LiH, NaH, and MgH2, and Al. The study was extended to phase diagrams including KH and CaH2 as well. The observed hydrogen storage capacity in the Al hexahydrides was less than 4 wt. %, well short of DOE targets. The HT assay came on line and after certification with studies on NaAlH4, was first applied to the LiNH2 - LiBH4 - MgH2 phase diagram. The 60-point study elucidated trends within the system locating an optimum material of 0.6 LiNH2 â?? 0.3 MgH2 â?? 0.1 LiBH4 that stored about 4 wt. % H2 reversibly and operated below 220 °C. Also present was the phase Li4(NH2)3BH4, which had been discovered in the LiNH2 -LiBH4 system. This new ternary formulation performed much better than the well-known 2 LiNH2 â?? MgH2 system by 50 °C in the HT assay. The Li4(NH2)3BH4 is a low melting ionic liquid under our test conditions and facilitates the phase transformations required in the hydrogen storage reaction, which no longer relies on a higher energy solid state reaction pathway. Further study showed that the 0.6 LiNH2 â?? 0.3 MgH2 â?? 0.1 LiBH4 formulation was very stable with respect to ammonia and diborane desorption, the observed desorption was from hydrogen. This result could not have been anticipated and was made possible by the efficiency of HT combinatorial methods. Investigation of the analogous LiNH2 â?? LiBH4 â?? CaH2 phase diagram revealed new reversible hydrogen storage materials 0.625 LiBH4 + 0.375 CaH2 and 0.375 LiNH2 + 0.25 LiBH4 + 0.375 CaH2 operating at 1 wt. % reversible hydrogen below 175 °C. Powder x-ray diffraction revealed a new structure for the spent materials which had not been previously observed. While the storage capacity was not impressive, an important aspect is that it boron appears to participate in a low temperature reversible reaction. The last major area of study also focused

  2. ExoMol molecular line lists X: The spectrum of sodium hydride

    E-Print Network [OSTI]

    Rivlin, Tom; Yurchenko, Sergei N; Tennyson, Jonathan; Roy, Robert J Le

    2015-01-01

    Accurate and complete rotational, rotational-vibrational and rotational-vibrational-electronic line lists are calculated for sodium hydride: both the NaH and NaD isotopologues are considered. These line lists cover all ro-vibrational states of the ground ($X$~$^1\\Sigma^+$) and first excited ($A$~$^1\\Sigma^+$) electronic states. The calculations use available spectroscopically-determined potential energy curves and new high-quality, \\textit{ab initio} dipole moment curves. Partition functions for both isotopologues are calculated and the effect of quasibound states is considered. The resulting line lists are suitable for temperatures up to about 7000~K and are designed for studies of exoplanet atmospheres, brown dwarfs and cool stars. In particular, the NaH $A-X$ band is found to show a broad absorption feature at about 385 nm which should provide a signature for the molecule. All partition functions, lines and transitions are available as Supplementary Information to this article and at \\url{www.exomol.com}.

  3. Atomic-Scale Chemical, Physical and Electronic Properties of the Subsurface Hydride of Palladium

    SciTech Connect (OSTI)

    Weiss, Paul

    2014-01-20

    We employed low-temperature, extreme-high vacuum scanning tunneling microscopy (STM) to investigate the roles of subsurface hydride (H) and deuteride (D) in the surface reconstruction and surface reactivity of Pd{110}. Specifically, we gained the ability to tailor the surface structure of Pd{110} both by preparation method and by deposition of deuterium from the gas phase. We observed thiophene at low coverage on Pd{110} to determine its adsorption orientation and electronic structure through scanning tunneling spectroscopy (STS) – namely, conductance spectroscopy and differential conductance imaging. We developed the methods necessary to coadsorb D adatoms with thiophene molecules, and to induce the reaction of individual molecules with predefined subsurface H or D features. In the case of Pd{110}, we found a much more pronounced effect from subsurface D, as it is influenced by the surface directionality. These experiments facilitate an understanding of the role of surface and subsurface H and D in heterogeneous catalytic processes, specifically in the hydrodesulfuization (HDS) of thiophene, an important and ubiquitous component found to be detrimental to petroleum refining.

  4. Modeling of temporal behavior of isotopic exchange between gaseous hydrogen and palladium hydride power

    SciTech Connect (OSTI)

    Melius, C F; Foltz, G W

    1987-01-01

    A parametric rate-equation model is described which depicts the time dependent behavior of the isotopic exchange process occurring between the solid and gas phases in gaseous hydrogen (deuterium) flows through packed-powder palladium deuteride (hydride) beds. The exchange mechanism is assumed to be rate-limited by processes taking place on the surface of the powder. The fundamental kinetic parameter of the model is the isotopic exchange probability, p, which is the probability that an isotopic exchange event occurs during a collision of a gas phase atom with the surface. Isotope effects between the gas and solid phases are explicitly included in terms of the isotope separation factor, ..cap alpha... Results of the model are compared with recent experimental measurements of isotope exchange in the ..beta..-phase hydrogen/palladium system and, using a literature value of ..cap alpha.. = 2.4, a good description of the experimental data is obtained for p approx. 10/sup -7/. In view of the importance of the isotope effects in the hydrogen/palladium system and the range of ..cap alpha.. values reported for the ..beta..-phase in the literature, the sensitivity of the model results to a variation in the value of ..cap alpha.. is examined.

  5. ELECTRON BEAM -DIRECTED VAPOR DEPOSITION OF MULTIFUNCTIONAL D. T. QUEHEILLALT, Y. KATSUMI, H. N. G. WADLEY

    E-Print Network [OSTI]

    Wadley, Haydn

    . KATSUMI, H. N. G. WADLEY University of Virginia, Department of Materials Science & Engineering, 116 Engineers Way Charlottesville, Virginia, U.S.A. 22904-4745, dougq@virginia.edu ABSTRACT Multifunctional-pipe structures and porous electrode coatings for rechargeable nickel - metal hydride cells. In addition to load

  6. J. Electrochem. Soc., Vol. 142, No. 5, May 1995 9 The Electrochemical Society, Inc. 1401 1. E.g. Lawrence and E. Tannas, Jr., Flat-Panel Displays

    E-Print Network [OSTI]

    Weidner, John W.

    , and H. Sawai, J. Inst. Television Engineers Jpn., 47, 1006 (1993). 8. K. Machida, K. Amano, M. TokuraMotupaUy,*ChristopherC. Streinz,and JohnW. Weidner** Department of Chemical Engineering, University of South Carolina, Columbia/hydrogen, and nickel/metal hydrides. The re- dox reaction taking place at the electrode during discharge and charge can

  7. 34 J. Electrochem. Soc., Vol. 145, No. 1, January 1998 The Electrochemical Society, Inc. 7 dimensionless time, (t I il/nFcNIl)

    E-Print Network [OSTI]

    Weidner, John W.

    ,* Mukul Jain,* Venkat Srinivasan,* and John W. Weidner** Center for Electro chemical Engineering, Department of Chemical Engineering, University of South Carolina, Columbia, South Carolina 29208, USA rechargeable battery systems (e.g., nick- el/cadmium, nickel/zinc, nickel/hydmgen, and nickel/metal hydride

  8. A Novel Routing Metric for Environmentally-Powered Sensors With Hybrid

    E-Print Network [OSTI]

    Ingram, Mary Ann

    Aravind Kailas and Mary Ann Ingram School of Electrical and Computer Engineering, Georgia Institute of Electrical and Computer Engineering, Georgia Institute of Technology, Savannah, Georgia 31407-3039, USA Email, depending on is type (e.g. Nickel Metal Hydride (NiMH) or Lithium Ion Polymer) can have cycle life ranging

  9. 3/21/11 1:37 PMUntitled Page 1 of 3

    E-Print Network [OSTI]

    Braun, Paul

    -like power with battery-like energy," said Braun, a professor of materials science and engineering. "Most both." The performance of typical lithium-ion (Li-ion) or nickel metal hydride (NiMH) rechargeable think of this the same way you do an internal combustion engine. You would just pull up to a charging

  10. Last Revised: 10/2013 Battery Waste Collection Request

    E-Print Network [OSTI]

    Sniadecki, Nathan J.

    Only Storage Location Mixed Batteries (alkaline, carbon zinc, Ni-Cad, nickel metal hydride, mercuryLast Revised: 10/2013 Battery Waste Collection Request www.ehs.washington.edu/forms/epo/1943.pdf Instructions: Fill out the approximate weight of each battery type KG For Environmental Health and Safety Use

  11. Page 1 of 2 UNIVERSAL WASTE

    E-Print Network [OSTI]

    Jia, Songtao

    -Cadmium (Ni-Cd) Nickel Metal Hydride (Ni-MH) Lithium Ion (Li-ion) Large or Small sealed lead acid (Pb) MercuryPage 1 of 2 UNIVERSAL WASTE and OTHER ENVIRONMENTALLY DELETERIOUS PRODUCTS Batteries All Universal Waste Batteries generated in laboratories must be collected through the hazardous waste program

  12. Computational Fluid Dynamics Modeling of a Lithium/Thionyl Chloride Battery with Electrolyte Flow

    E-Print Network [OSTI]

    Wang, Chao-Yang

    Computational Fluid Dynamics Modeling of a Lithium/Thionyl Chloride Battery with Electrolyte Flow W-dimensional model is developed to simulate discharge of a primary lithium/thionyl chloride battery. The model to the first task with important examples of lead-acid,1-3 nickel-metal hydride,4-8 and lithium-based batteries

  13. Maxim > App Notes > BATTERY MANAGEMENT INTERFACE CIRCUITS Keywords: USB, USB Charger, Li+ USB charger, Lithium Ion USB charger, NiMH USB charger, USB battery

    E-Print Network [OSTI]

    Allen, Jont

    charger, Lithium Ion USB charger, NiMH USB charger, USB battery charger, charging batteries from USB, and cabling. An overview of nickel metal hydride (NiMH) and lithium battery technologies, charging methodsMaxim > App Notes > BATTERY MANAGEMENT INTERFACE CIRCUITS Keywords: USB, USB Charger, Li+ USB

  14. On Modeling Bonds in Fused, Porous Networks: 3D Simulations

    E-Print Network [OSTI]

    Sastry, Ann Marie

    , fused, joint, mechanics, nanotube, network, random, sintered, welded. INTRODUCTION EXAMPLES OF FUSED.1177/002199803029725 ß 2003 Sage Publications #12;(nickel-metal hydride) and Li-ion (lithium ion) batteries that contain nanotube mat are among the newest engineered materials constructed in this way. Applications

  15. * corresponding Auithor. Email: cxw31@psu.edu Modeling Discharge and Charge Characteristics

    E-Print Network [OSTI]

    Wang, Chao-Yang

    of OH ­ with respect to the solvent velocity U j,ref open­circuit potential for reaction j: nickel­metal hydride battery, oxygen reaction, modeling and computer simulation #12; 3 LIST OF SYMBOLS _ nj transfer current density of reaction j, A/cm 2 i 0j,ref exchange current density of reaction j

  16. Powering the Next Billion Devices with Wi-Fi Vamsi Talla, Bryce Kellogg, Benjamin Ransford, Saman Naderiparizi,

    E-Print Network [OSTI]

    Van Volkenburgh, Elizabeth

    - nication performance. Building on our design, we prototype battery-free temperature and camera sensors to wirelessly trickle-charge nickel­ metal hydride and lithium-ion coin-cell batteries at distances of up to 28 performance. 1. INTRODUCTION In the late 19th century, Nikola Tesla dreamed of elim- inating wires for both

  17. Modeling of a Nickel-Hydrogen Cell Phase Reactions in the Nickel Active Material

    E-Print Network [OSTI]

    developed high-energy-density batteries, e.g., the nickel-metal hydride battery and the lithium-ion batteryModeling of a Nickel-Hydrogen Cell Phase Reactions in the Nickel Active Material B. Wu and R. E of South Carolina, Columbia, South Carolina 29208, USA A nonisothermal model of a nickel-hydrogen cell has

  18. Resistive companion battery modeling for electric circuit simulations , R. Dougalb

    E-Print Network [OSTI]

    Resistive companion battery modeling for electric circuit simulations B. Wua , R. Dougalb , R be achieved based on RC models. In this study, the construction of RC battery models is investigated. A general battery model and a nickel±metal hydride cell model have been built. Simulations of RC battery

  19. Two plateaux for palladium hydride and the effect of helium from tritium decay on the desorption plateau pressure for palladium tritide

    SciTech Connect (OSTI)

    Walters, R.T.; Lee, M.W. (Westinghouse Savannah River Co., Savannah River Lab., Aiken, SC (US))

    1991-10-01

    Two plateaux are observed in the desorption isotherm for palladium hydride: a lower plateau pressure for a hydrogen/metal atom ratio (H/M) less than about 0.3 and a slightly higher plateau pressure for H/M greater than about 0.3. This higher pressure corresponds to the reported pressure for palladium hydride. These observations were made for a large surface area palladium powder exposed to both protium and tritium. Helium buildup form tritium decay decreases the lower plateau pressure but does not affect the observations for H/M greater than about 0.3. In this paper, a multiple-energy hydrogen site occupancy model is proposed to explain qualitatively both the dual plateau and the helium effect in palladium hydride.

  20. Particle size effect of hydride formation and surface hydrogen absorption of nanosized palladium catalysts : L{sub 3} edge vs K edge x-ray absorption spectroscopy.

    SciTech Connect (OSTI)

    Tew, M. W.; Miller, J. T.; van Bokhoven, J. A.

    2009-08-01

    The particle size effect on the formation of palladium hydride and on surface hydrogen adsorption was studied at room temperature using in situ X-ray absorption spectroscopy at the Pd K and L{sub 3} edges. Hydride formation was indirectly observed by lattice expansion in Pd K edge XANES spectra and by EXAFS analysis. Hydride formation was directly detected in the L{sub 3} edge spectra. A characteristic spectral feature caused by the formation of a Pd-H antibonding state showed strong particle size dependence. The L{sub 3} edge spectra were reproduced using full multiple scattering analysis and density of state calculations, and the contributions of bulk absorbed and surface hydrogen to the XANES spectra could be distinguished. The ratio of hydrogen on the surface versus that in the bulk increased with decreasing particle size, and smaller particles dissolved less hydrogen.

  1. A coupled transport and solid mechanics formulation with improved reaction kinetics parameters for modeling oxidation and decomposition in a uranium hydride bed.

    SciTech Connect (OSTI)

    Salloum, Maher N.; Shugard, Andrew D.; Kanouff, Michael P.; Gharagozloo, Patricia E.

    2013-03-01

    Modeling of reacting flows in porous media has become particularly important with the increased interest in hydrogen solid-storage beds. An advanced type of storage bed has been proposed that utilizes oxidation of uranium hydride to heat and decompose the hydride, releasing the hydrogen. To reduce the cost and time required to develop these systems experimentally, a valid computational model is required that simulates the reaction of uranium hydride and oxygen gas in a hydrogen storage bed using multiphysics finite element modeling. This SAND report discusses the advancements made in FY12 (since our last SAND report SAND2011-6939) to the model developed as a part of an ASC-P&EM project to address the shortcomings of the previous model. The model considers chemical reactions, heat transport, and mass transport within a hydride bed. Previously, the time-varying permeability and porosity were considered uniform. This led to discrepancies between the simulated results and experimental measurements. In this work, the effects of non-uniform changes in permeability and porosity due to phase and thermal expansion are accounted for. These expansions result in mechanical stresses that lead to bed deformation. To describe this, a simplified solid mechanics model for the local variation of permeability and porosity as a function of the local bed deformation is developed. By using this solid mechanics model, the agreement between our reacting bed model and the experimental data is improved. Additionally, more accurate uranium hydride oxidation kinetics parameters are obtained by fitting the experimental results from a pure uranium hydride oxidation measurement to the ones obtained from the coupled transport-solid mechanics model. Finally, the coupled transport-solid mechanics model governing equations and boundary conditions are summarized and recommendations are made for further development of ARIA and other Sandia codes in order for them to sufficiently implement the model.

  2. Presented at the NuMat 2012 Conference, 2225 October 2012, Osaka, Japan Effect of thermo-mechanical cycling on zirconium hydride reorientation

    E-Print Network [OSTI]

    Motta, Arthur T.

    -mechanical cycling on zirconium hydride reorientation studied in situ with synchrotron X-ray diffraction Kimberly B and Nuclear Engineering, Penn State University, University Park, PA 16802, USA b Department of Mechanical and Materials Engineering, Queen's University, Kingston, ON, Canada K7L 3N6 c Advanced Photon Source, Argonne

  3. Li{sub 4}FeH{sub 6}: Iron-containing complex hydride with high gravimetric hydrogen density

    SciTech Connect (OSTI)

    Saitoh, Hiroyuki, E-mail: cyto@spring8.or.jp [Quantum Beam Science Center, Japan Atomic Energy Agency, Hyogo 679-5148 (Japan); Takagi, Shigeyuki; Matsuo, Motoaki; Aoki, Katsutoshi [Institute for Materials Research, Tohoku University, Sendai 980-8577 (Japan); Iijima, Yuki [WPI-Advanced Institute for Materials Research, Tohoku University, Sendai 980-8577 (Japan); Endo, Naruki [Renewable Energy Research Center, National Institute of Advanced Industrial Science and Technology, Fukushima 963-0215 (Japan); Orimo, Shin-ichi [Institute for Materials Research, Tohoku University, Sendai 980-8577 (Japan); WPI-Advanced Institute for Materials Research, Tohoku University, Sendai 980-8577 (Japan)

    2014-07-01

    Li{sub 4}FeH{sub 6}, which has the highest gravimetric hydrogen density of iron-containing complex hydrides reported so far, is synthesized by hydrogenation of a powder mixture of iron and LiH above 6.1 GPa at 900?°C. In situ synchrotron radiation X-ray diffraction measurements reveal that while kinetics require high temperature and thus high pressure for the synthesis, Li{sub 4}FeH{sub 6} is expected to be thermodynamically stable slightly below room temperature at ambient pressure; further synthetic studies to suppress the kinetic effects may enable us to synthesize Li{sub 4}FeH{sub 6} at moderate pressures. Li{sub 4}FeH{sub 6} can be recovered at ambient conditions where Li{sub 4}FeH{sub 6} is metastable.

  4. LaNi.sub.5 is-based metal hydride electrode in Ni-MH rechargeable cells

    DOE Patents [OSTI]

    Bugga, Ratnakumar V. (Arcadia, CA); Fultz, Brent (Pasadena, CA); Bowman, Robert (La Mesa, CA); Surampudi, Subra Rao (Glendora, CA); Witham, Charles K. (Pasadena, CA); Hightower, Adrian (Pasadena, CA)

    1999-01-01

    An at least ternary metal alloy of the formula AB.sub.(Z-Y) X.sub.(Y) is disclosed. In this formula, A is selected from the rare earth elements, B is selected from the elements of Groups 8, 9, and 10 of the Periodic Table of the Elements, and X includes at least one of the following: antimony, arsenic, germanium, tin or bismuth. Z is greater than or equal to 4.8 and less than or equal to 6.0. Y is greater than 0 and less than 1. Ternary or higher-order substitutions to the base AB.sub.5 alloys that form strong kinetic interactions with the predominant metals in the base metal hydride are used to form metal alloys with high structural integrity after multiple cycles of hydrogen sorption.

  5. On Ramsey Numbers

    E-Print Network [OSTI]

    Dhananjay P. Mehendale

    2006-05-24

    In this paper we define new numbers called the Neo-Ramsay numbers. We show that these numbers are in fact equal to the Ramsay numbers. Neo-Ramsey numbers are easy to compute and for finding them it is not necessary to check all possible graphs but enough to check only special kind of graphs having a well-defined adjacency pattern.

  6. 1 -Routing Number 2 -Account Number

    E-Print Network [OSTI]

    Chen, Yiling

    you will need: · Your Harvard University Id Number (HUID) · Your HUID pin number · Your Checking/Savings on the right side of the screen under Payroll and Compensation. #12;*Please, in an effort to save paper and if you do not wish to receive a paper copy of the check. Click the small box above the SAVE button. CLICK

  7. The role of destabilization of palladium hydride on the hydrogen uptake of Pd-containing activated carbons

    SciTech Connect (OSTI)

    Bhat, Vinay V; Contescu, Cristian I; Gallego, Nidia C

    2009-01-01

    This paper reports on differences in stability of Pd hydride phases in palladium particles with various degrees of contact with microporous carbon supports. A sample containing Pd embedded in activated carbon fiber (Pd-ACF; 2 wt% Pd) was compared with commercial Pd nanoparticles deposited on microporous activated carbon (Pd-catalyst, 3 wt% Pd) and with support-free nanocrystalline palladium (Pd-black). The morphology of materials was characterized by electron microscopy, and the phase transformations were analyzed over a large range of hydrogen partial pressures (0.003 - 10 bar) and at several temperatures using in-situ X-ray diffraction. The results were verified with volumetric hydrogen uptake measurements. Results indicate that higher degree of Pd-carbon contacts for Pd particles embedded in a microporous carbon matrix induce efficient pumping of hydrogen out of -PdHx. It was also found that thermal cleaning of carbon surface groups prior to exposure to hydrogen further enhances the hydrogen pumping power of the microporous carbon support. In brief, this study highlights that the stability of -PdHx phase supported on carbon depends on the degree of contact between Pd-carbon and the nature of the carbon surface.

  8. Thermal Release of 3He from Tritium Aged LaNi4.25Al0.75 Hydride

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Staack, Gregory C.; Crowder, Mark L.; Klein, James E.

    2015-02-01

    Recently, the demand for He-3 has increased dramatically due to widespread use in nuclear nonproliferation, cryogenic, and medical applications. Essentially all of the world’s supply of He-3 is created by the radiolytic decay of tritium. The Savannah River Site Tritium Facilities (SRS-TF) utilizes LANA.75 in the tritium process to store hydrogen isotopes. The vast majority of He-3 “born” from tritium stored in LANA.75 is trapped in the hydride metal matrix. The SRS-TF has multiple LANA.75 tritium storage beds that have been retired from service with significant quantities of He-3 trapped in the metal. To support He-3 recovery, the Savannah Rivermore »National Laboratory (SRNL) conducted thermogravimetric analysis coupled with mass spectrometry (TGA-MS) on a tritium aged LANA.75 sample. TGA-MS testing was performed in an argon environment. Prior to testing, the sample was isotopically exchanged with deuterium to reduce residual tritium and passivated with air to alleviate pyrophoric concerns associated with handling the material outside of an inert glovebox. Analyses indicated that gas release from this sample was bimodal, with peaks near 220 and 490°C. The first peak consisted of both He-3 and residual hydrogen isotopes, the second was primarily He-3. The bulk of the gas was released by 600 °C« less

  9. Shannon Capacity Ramsey Numbers

    E-Print Network [OSTI]

    Radziszowski, Stanislaw P.

    Shannon Capacity Ramsey Numbers Old links between Shannon and Ramsey New links between Shannon and Ramsey Bounds on Shannon Capacity and Ramsey Numbers from Product of Graphs Xiaodong Xu1 Stanislaw Institute of Technology, NY, USA March 2014 1/24 #12;Shannon Capacity Ramsey Numbers Old links between

  10. Number Theory Seminar

    E-Print Network [OSTI]

    $author.value

    2014-12-03

    Dec 3, 2014 ... TBA, Rachel Davis ... September 26, Rachel Davis .... Dessins d'Enfants · Indiana Pi Bill · Notes and Publications · Number Theory Seminar ...

  11. Highly chemoselective palladium-catalyzed conjugate reduction of. cap alpha. ,. beta. -unsaturated carbonyl compounds with silicon hydrides and zinc chloride cocatalyst

    SciTech Connect (OSTI)

    Keinan, E.; Greenspoon, N.

    1986-11-12

    A three-component system comprised of a soluble palladium catalyst, hydridosilane, and zinc chloride is capable of efficient conjugate reduction of ..cap alpha..,..beta..-unsaturated ketones and aldehydes. The optimal set of conditions includes diphenylsilane as the most effective hydride donor, any soluble palladium complex in either the O or II oxidation state, when it is stabilized by phosphine ligands, and ZnCl/sub 2/ as the best Lewis acid cocatalyst. The reaction is very general with respect to a broad range of unsaturated ketones and aldehydes, and it is highly selective for these Michael acceptors, as reduction of ..cap alpha..,..beta..-unsaturated carboxylic acid derivatives is very sluggish under these conditions. When dideuteriodiphenylsilane is used to reduce unsaturated ketones, deuterium is stereoselectivity introduced at the less-hindered fact of the substrate and regioselectively at the ..beta..-position. Conversely, when reductions are carried out in the presence of traces of D/sub 2/O, deuterium incorporation occurs at the ..cap alpha..-position. On the basis of deuterium-incorporation experiments and /sup 1/H NMR studies a catalytic cycle is postulated in which the first step involves reversible coordination of the palladium complex to the electron-deficient olefin and oxidative addition of silicon hydride to form a hydridopalladium olefin complex.

  12. Electrochemical Oxidation of H? Catalyzed by Ruthenium Hydride Complexes Bearing P?N? Ligands With Pendant Amines as Proton Relays

    SciTech Connect (OSTI)

    Liu, Tianbiao L.; Rakowski DuBois, Mary; DuBois, Daniel L.; Bullock, R. Morris

    2014-01-01

    Two Ru hydride complexes (Cp*Ru(PPh?NBn?)H, (1-H) and Cp*Ru(PtBu?NBn?)H, (2-H) supported by cyclic PR?NR'? ligands (Cp* = n?-C?Me?; 1,5-diaza-3,7-diphosphacyclooctane, where R = Ph or tBu and R' = Bn) have been synthesized and fully characterized. Both complexes are demonstrated to be electrocatalysts for oxidation of H? (1 atm, 22 °C) in the presence of external base, DBU (1,8-diazabicyclo[5.4.0]undec-7-ene). The turnover frequency of 2-H is 1.2 s-1, with an overpotential at Ecat/2 of 0.45 V, while catalysis by 1-H has a turnover frequency of 0.6 s-1 and an overpotential of 0.6 V at Ecat/2. Addition of H?O facilitates oxidation of H? by 2-H and increases its turnover frequency to 1.9 s-1 while , H?O slows down the catalysis by 1-H. The different effects of H?O for 1-H and 2-H are ascribed to different binding affinities of H?O to the Ru center of the corresponding unsaturated species, [Cp*Ru(PPh?NBn?)]+ and [Cp*Ru(PPh?NBn?)]+. In addition, studies of Cp*Ru(dmpm)H (where dmpm = bis(dimethylphosphino)methane), a control complex lacking pendent amines in its diphosphine ligand, confirms the critical roles of the pendent amines of P?N? ligands for oxidation of H?. We thank the U.S. Department of Energy, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences and Biosciences, for supporting initial parts of the work. Current work is supported by the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences. Pacific Northwest National Laboratory is operated by Battelle for the U.S. Department of Energy.

  13. Please cite this article in press as: Malen, J.A., et al., Thermal hydraulic design of a hydride-fueled inverted PWR core. Nucl. Eng. Des. (2009), doi:10.1016/j.nucengdes.2009.02.026

    E-Print Network [OSTI]

    Malen, Jonathan A.

    2009-01-01

    Please cite this article in press as: Malen, J.A., et al., Thermal hydraulic design of a hydride-5320; No.of Pages10 Nuclear Engineering and Design xxx (2009) xxx­xxx Contents lists available at ScienceDirect Nuclear Engineering and Design journal homepage: www.elsevier.com/locate/nucengdes Thermal

  14. Please cite this article in press as: Greenspan, E., et al., Hydride fuel for LWRs--Project overview. Nucl. Eng. Des. (2009), doi:10.1016/j.nucengdes.2008.11.023

    E-Print Network [OSTI]

    Malen, Jonathan A.

    2009-01-01

    ) and boiling water reactor (BWR) cores by using solid hydride fuels instead of the commonly used oxide fuel of this project was to assess the feasibility of improving the performance of pressurised water reactor (PWR it fissions in one pass is double that of the MOX fuel. (2) Eliminating dedicated water moderator volumes

  15. Vibration-rotation emission spectra and combined isotopomer analyses for the coinage metal hydrides: CuH & CuD, AgH & AgD, and AuH

    E-Print Network [OSTI]

    Le Roy, Robert J.

    Vibration-rotation emission spectra and combined isotopomer analyses for the coinage metal hydrides 1999 High resolution infrared emission spectra have been measured for AuH and AuD and for two , and in spite of intense background thermal emission from the furnace at 2000 °C , vibration­rotation emission

  16. Big Numbers | Jefferson Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    with a length of 35 cm, which certainly helps . With Avogadro's number and the density of liquid hydrogen, we have about 1024 protons per cm2. We then take the beam of 160...

  17. KPA Activity Number

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    September 2002 Page 1 KPA Activity Number KPA Activity SEM Section SME Work Product SQSE Web Site http:cio.doe.govsqse REQUIREMENTS MANAGEMENT RM-1 The software engineering...

  18. Report number codes

    SciTech Connect (OSTI)

    Nelson, R.N.

    1985-05-01

    This publication lists all report number codes processed by the Office of Scientific and Technical Information. The report codes are substantially based on the American National Standards Institute, Standard Technical Report Number (STRN)-Format and Creation Z39.23-1983. The Standard Technical Report Number (STRN) provides one of the primary methods of identifying a specific technical report. The STRN consists of two parts: The report code and the sequential number. The report code identifies the issuing organization, a specific program, or a type of document. The sequential number, which is assigned in sequence by each report issuing entity, is not included in this publication. Part I of this compilation is alphabetized by report codes followed by issuing installations. Part II lists the issuing organization followed by the assigned report code(s). In both Parts I and II, the names of issuing organizations appear for the most part in the form used at the time the reports were issued. However, for some of the more prolific installations which have had name changes, all entries have been merged under the current name.

  19. Battery Electrode Materials with High Cycle Lifetimes

    SciTech Connect (OSTI)

    Prof. Brent Fultz

    2001-06-29

    In an effort to understand the capacity fade of nickel-metal hydride (Ni-MH) batteries, we performed a systematic study of the effects of solute additions on the cycle life of metal hydride electrodes. We also performed a series of measurements on hydrogen absorption capacities of novel carbon and graphite-based materials including graphite nanofibers and single-walled carbon nanotubes. Towards the end of this project we turned our attention to work on Li-ion cells with a focus on anode materials.

  20. PNNL Chemical Hydride Capabilities

    Broader source: Energy.gov [DOE]

    Presentation from the Hydrogen Storage Pre-Solicitation Meeting held June 19, 2003 in Washington, DC.

  1. Metal Hydrides- Science Needs

    Broader source: Energy.gov [DOE]

    Presentation from the Hydrogen Storage Pre-Solicitation Meeting held June 19, 2003 in Washington, DC.

  2. Regeneration of aluminum hydride

    DOE Patents [OSTI]

    Graetz, Jason Allan (Mastic, NY); Reilly, James J. (Bellport, NY)

    2009-04-21

    The present invention provides methods and materials for the formation of hydrogen storage alanes, AlH.sub.x, where x is greater than 0 and less than or equal to 6 at reduced H.sub.2 pressures and temperatures. The methods rely upon reduction of the change in free energy of the reaction between aluminum and molecular H.sub.2. The change in free energy is reduced by lowering the entropy change during the reaction by providing aluminum in a state of high entropy, by increasing the magnitude of the change in enthalpy of the reaction or combinations thereof.

  3. Regeneration of aluminum hydride

    DOE Patents [OSTI]

    Graetz, Jason Allan; Reilly, James J; Wegrzyn, James E

    2012-09-18

    The present invention provides methods and materials for the formation of hydrogen storage alanes, AlH.sub.x, where x is greater than 0 and less than or equal to 6 at reduced H.sub.2 pressures and temperatures. The methods rely upon reduction of the change in free energy of the reaction between aluminum and molecular H.sub.2. The change in free energy is reduced by lowering the entropy change during the reaction by providing aluminum in a state of high entropy, and by increasing the magnitude of the change in enthalpy of the reaction or combinations thereof.

  4. UCGE Reports Number 20284

    E-Print Network [OSTI]

    Calgary, University of

    ABSTRACT Oil and gas are global fuels obtained primarily from drilling wells in underground terrestrial reservoirs. Vertical drilling is preferred because of its simplicity and therefore low cost, but subsurfaceUCGE Reports Number 20284 Department of Geomatics Engineering Continuous Measurement-While-Drilling

  5. Student Code Number: Thermodynamics

    E-Print Network [OSTI]

    Feeny, Brian

    Student Code Number: Thermodynamics Ph.D. Qualifying Exam Department of Mechanical Engineering;Thermodynamics Qualifier January 2013 Problem 1 Air is compressed in an axial-flow compressor operating at steady of exergy destruction within the compressor, in kJ per kg of air flowing. #12;Thermodynamics Qualifier

  6. UCGE Reports Number 20146

    E-Print Network [OSTI]

    Calgary, University of

    in considerable operational cost savings for many exploration and open-pit mining companies in the energy sectorUCGE Reports Number 20146 Department of Geomatics Engineering Development of a Mobile Equipment Equipment Management System solution. In the open-pit mining industries there is a need for these companies

  7. Australia NO REGISTRATION NUMBER

    E-Print Network [OSTI]

    Portugal Romania Slovenia Spain Turkey UK USA Australia Austria Belgium Cyprus France Germany Greece#12;#12;Australia Austria Belgium Cyprus France Germany Greece Ireland Italy Japan Macedonia Ireland Italy Japan Macedonia Portugal Romania Slovenia Spain Turkey UK USA #12;NO REGISTRATION NUMBER 1

  8. Environmental effects on noble-gas hydrides: HXeBr, HXeCCH, and HXeH in noble-gas and molecular matrices

    SciTech Connect (OSTI)

    Tsuge, Masashi E-mail: leonid.khriachtchev@helsinki.fi; Lignell, Antti; Räsänen, Markku; Khriachtchev, Leonid E-mail: leonid.khriachtchev@helsinki.fi

    2013-11-28

    Noble-gas hydrides HNgY (Ng is a noble-gas atom and Y is an electronegative group) are sensitive probes of local environment due to their relatively weak bonding and large dipole moments. We experimentally studied HXeBr in Ar, Kr, and N{sub 2} matrices, HXeCCH in Ne and N{sub 2} matrices, and HXeH in an N{sub 2} matrix. These are the first observations of noble-gas hydrides in an N{sub 2} matrix. An N{sub 2} matrix strongly increases the H–Xe stretching frequency of HXeBr and HXeCCH with respect to a Ne matrix, which is presumably due to a strong interaction between the HNgY dipole moment and quadrupole moments of the surrounding lattice N{sub 2} molecules. The spectral shift of HXeBr in an N{sub 2} matrix is similar to that in a CO{sub 2} matrix, which is a rather unexpected result because the quadrupole moment of CO{sub 2} is about three times as large as that of N{sub 2}. The H–Xe stretching frequencies of HXeBr and HXeCCH in noble-gas matrices show a trend of ?(Ne) < ?(Xe) < ?(Kr) < ?(Ar), which is a non-monotonous function of the dielectric constants of the noble-gas solids. The MP2(full) calculations of HXeBr and HXeCCH with the polarizable continuum model as well as the CCSD(T) calculations of the HXeBr···Ng and HXeCCH···Ng (Ng = Ne, Ar, Kr, and Xe) complexes cannot fully explain the experimental observations. It is concluded that more sophisticated computational models should be used to describe these experimental findings.

  9. Quantum random number generator

    E-Print Network [OSTI]

    M. Stipcevic; B. Medved Rogina

    2007-01-01

    We report upon a novel principle for realization of a fast nondeterministic random number generator whose randomness relies on intrinsic randomness of the quantum physical processes of photonic emission in semiconductors and subsequent detection by the photoelectric effect. Timing information of detected photons is used to generate binary random digits-bits. The bit extraction method based on restartable clock theoretically eliminates both bias and autocorrelation while reaching efficiency of almost 0.5 bits per random event. A prototype has been built and statistically tested.

  10. Neither Name, Nor Number

    E-Print Network [OSTI]

    Federico Holik

    2011-12-20

    Since its origins, Quantum mechanics has presented problems with the concept of individuality. It is argued that quantum particles do not have individuality, and so, one can speak about "entities without identity". On the contrary, we claim that the problem of quantum non individuality goes deeper, and that one of its most important features is the fact that there are quantum systems for which particle number is not well defined. In this work, we continue this discussion in relation to the problem about the one and the many.

  11. On Some Zarankiewicz Numbers and Bipartite Ramsey Numbers for

    E-Print Network [OSTI]

    Radziszowski, Stanislaw P.

    On Some Zarankiewicz Numbers and Bipartite Ramsey Numbers for Quadrilateral Janusz Dybizba Ramsey number b(n1, · · · , nk) is the least positive integer b such that any coloring of the edges of Kb Ramsey numbers avoiding quadrilateral. In particular, we prove that b4(2) = 19, and establish new general

  12. Final Report for DOE Project Number: DE-FG02-05ER46241

    SciTech Connect (OSTI)

    Gang Chen; Mildred S. Dresselhaus; Costas P. Grigoropoulos; Samuel S. Mao; Xiaodong Xiang; Taofang Zeng

    2010-03-15

    Hydrogen storage is the most challenging task for the hydrogen economy. We established a multidisciplinary research program for high throughput combinatorial synthesis and characterization of novel nanoporous and metastable complex hydrides, coupled to fundamental material studies including electronic, structural and kinetic transport modeling, and pump-probe experiments. Our research is based the concept of hybrid nanostructures that store hydrogen by a combination of chemi- and physorption: atomic hydrogen is stored in metastable hydrides while molecule hydrogen is stored in the nanometer pores of the hydrides. Metastable nanostructured hydride has been achieved by introducing structural and compositional disorders through high throughput elemental substitution/doping, catalyst addition, and nonequilibrium processing. Fast screening compatible with the combinatorial synthesis was achieved by combining X-ray structural characterization with the development of a laser-based microbalance. Manufacturing of nanoporous metahydrides that are identified as promising by the combinatorial synthesis has been explored along with the materials search.

  13. The Distribution of Ramsey Numbers

    E-Print Network [OSTI]

    Lane Clark; Frank Gaitan

    2014-11-10

    We prove that the number of integers in the interval [0,x] that are non-trivial Ramsey numbers r(k,n) (3 <= k <= n) has order of magnitude (x ln x)**(1/2).

  14. Ordered Ramsey numbers David Conlon

    E-Print Network [OSTI]

    Fox, Jacob

    Ordered Ramsey numbers David Conlon Jacob Fox Choongbum Lee Benny Sudakov§ Abstract Given a labeled graph H with vertex set {1, 2, . . . , n}, the ordered Ramsey number r with vertices appearing in the same order as in H. The ordered Ramsey number of a labeled graph H is at least

  15. Hypergraph Ramsey numbers David Conlon

    E-Print Network [OSTI]

    Fox, Jacob

    Hypergraph Ramsey numbers David Conlon Jacob Fox Benny Sudakov Abstract The Ramsey number rk(s, n). In this paper we obtain new estimates for several basic hypergraph Ramsey problems. We give a new upper bound-color Ramsey number r3(n, n, n), which is the minimum N such that every 3-coloring of the triples

  16. Data Compression with Prime Numbers

    E-Print Network [OSTI]

    Gordon Chalmers

    2005-11-16

    A compression algorithm is presented that uses the set of prime numbers. Sequences of numbers are correlated with the prime numbers, and labeled with the integers. The algorithm can be iterated on data sets, generating factors of doubles on the compression.

  17. Compendium of Experimental Cetane Numbers

    SciTech Connect (OSTI)

    Yanowitz, J.; Ratcliff, M. A.; McCormick, R. L.; Taylor, J. D.; Murphy, M. J.

    2014-08-01

    This report is an updated version of the 2004 Compendium of Experimental Cetane Number Data and presents a compilation of measured cetane numbers for pure chemical compounds. It includes all available single compound cetane number data found in the scientific literature up until March 2014 as well as a number of unpublished values, most measured over the past decade at the National Renewable Energy Laboratory. This Compendium contains cetane values for 389 pure compounds, including 189 hydrocarbons and 201 oxygenates. More than 250 individual measurements are new to this version of the Compendium. For many compounds, numerous measurements are included, often collected by different researchers using different methods. Cetane number is a relative ranking of a fuel's autoignition characteristics for use in compression ignition engines; it is based on the amount of time between fuel injection and ignition, also known as ignition delay. The cetane number is typically measured either in a single-cylinder engine or a constant volume combustion chamber. Values in the previous Compendium derived from octane numbers have been removed, and replaced with a brief analysis of the correlation between cetane numbers and octane numbers. The discussion on the accuracy and precision of the most commonly used methods for measuring cetane has been expanded and the data has been annotated extensively to provide additional information that will help the reader judge the relative reliability of individual results.

  18. Evaluation of hoop creep behaviors in long-term dry storage condition of pre-hydrided and high burn-up nuclear fuel cladding

    SciTech Connect (OSTI)

    Kim, Sun-Ki; Bang, J.G.; Kim, D.H.; Yang, Y.S.

    2007-07-01

    Related to the degradation of the mechanical properties of Zr-based nuclear fuel cladding tubes under long term dry storage condition, the mechanical tests which can simulate the degradation of the mechanical properties properly are needed. Especially, the degradation of the mechanical properties by creep mechanism seems to be dominant under long term dry storage condition. Accordingly, in this paper, ring creep tests were performed in order to evaluate the creep behaviors of high burn-up fuel cladding under a hoop loading condition in a hot cell. The tests are performed with Zircaloy-4 fuel cladding whose burn-up is approximately {approx}60,000 MWd/tU in the temperature range from 350 deg. to 550 deg.. The tests are also performed with pre-hydrided Zircaloy-4 and ZIRLO up to 1,000 ppm. First of all, the hoop loading grip for the ring creep test was designed in order that a constant curvature of the specimen was maintained during the creep deformation, and the graphite lubricant was used to minimize the friction between the outer surface of the die insert and the inner surface of the ring specimen. The specimen for the ring creep test was designed to limit the deformation within the gauge section and to maximize the uniformity of the strain distribution. It was confirmed that the mechanical properties under a hoop loading condition can be correctly evaluated by using this test technique. In this paper, secondary creep rate with increasing hydrogen content are drawn, and then kinetic data such as pre-exponential factor and activation energy for creep process are also drawn. In addition, creep life are predicted by obtaining LMP (Larson-Miller parameter) correlation in the function of hydrogen content and applied stress to yield stress ratio. (authors)

  19. Number

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-SessionsSouthReport for the Weldon Spring,7=cr5rnP 7694 i+lJNew York,' , /v-i 2

  20. Pipeline MT Instructions Identification Number

    E-Print Network [OSTI]

    Hong, Don

    Pipeline MT Instructions Identification Number For identification purposes, you will be assigned a special identification number. M# You can activate your MT email, login to PipelineMT to register for classes or pay tuition and fees. Activating the MTSU Email and PipelineMT accounts: Visit the website

  1. Types of random numbers and Monte Carlo Methods Pseudorandom number generation

    E-Print Network [OSTI]

    Mascagni, Michael

    Types of random numbers and Monte Carlo Methods Pseudorandom number generation Quasirandom number generation Conclusions WE246: Random Number Generation A Practitioner's Overview Prof. Michael Mascagni #12;Types of random numbers and Monte Carlo Methods Pseudorandom number generation Quasirandom number

  2. Motion at low Reynolds number

    E-Print Network [OSTI]

    Tam, Daniel See Wai, 1980-

    2008-01-01

    The work described in this thesis centers on inertialess motion at low Reynolds numbers at the crossroad between biofluids and microfluids. Here we address questions regarding locomotion of micro-swimmers, transport of ...

  3. Departmental Business Instrument Numbering System

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2005-01-27

    The Order prescribes the procedures for assigning identifying numbers to all Department of Energy (DOE) and National Nuclear Security Administration (NNSA) business instruments. Cancels DOE O 540.1. Canceled by DOE O 540.1B.

  4. Departmental Business Instrument Numbering System

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2000-12-05

    To prescribe procedures for assigning identifying numbers to all Department of Energy (DOE), including the National Nuclear Security Administration, business instruments. Cancels DOE 1331.2B. Canceled by DOE O 540.1A.

  5. MOTOR POOL RESERVATIONS Reservation Number:_______________

    E-Print Network [OSTI]

    Ottino, Julio M.

    of Department Chair or Organization Advisor: ________________________________________ Chart String Number: Fund: ______________________________________________________________________ Name of Department or Organization: _____________________________________________________ Name reservations require the "Organization Authorization for University Vehicles" form to be faxed to Motor Pool

  6. Kentucky Natural Gas Number of Residential Consumers (Number of Elements)

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963Residential Consumers (Number of Elements) Kentucky Natural Gas Number

  7. TRANSPORT NUMBER GRADIENTS AND SOLID ELECTROLYTE DEGRADATION

    E-Print Network [OSTI]

    De Jonghe, Lutgard C.

    2014-01-01

    NUMBER GRADIENTS AND SOLID ELECTROLYTE DEGRADATION LutgardNUMBER GRADIENTS AND SOLID ELECTROLYTE DEGRADATION LutgardNUMBER GRADIENTS AND SOLID ELECTROLYTE DEGRADATION Lutgard

  8. TRANSPORT NUMBER GRADIENTS AND SOLID ELECTROLYTE DEGRADATION

    E-Print Network [OSTI]

    De Jonghe, Lutgard C.

    2012-01-01

    NUMBER GRADIENTS AND SOLID ELECTROLYTE DEGRADATION LutgardNUMBER GRADIENTS AND SOLID ELECTROLYTE DEGRADATION LutgardNUMBER GRADIENTS AND SOLID ELECTROLYTE DEGRADATION Lutgard

  9. Experimental determination of Ramsey numbers

    E-Print Network [OSTI]

    Zhengbing Bian; Fabian Chudak; William G. Macready; Lane Clark; Frank Gaitan

    2013-08-14

    Ramsey theory is a highly active research area in mathematics that studies the emergence of order in large disordered structures. Ramsey numbers mark the threshold at which order first appears and are extremely difficult to calculate due to their explosive rate of growth. Recently, an algorithm that can be implemented using adiabatic quantum evolution has been proposed that calculates the two-color Ramsey numbers $R(m,n)$. Here we present results of an experimental implementation of this algorithm and show that it correctly determines the Ramsey numbers R(3,3) and $R(m,2)$ for $4\\leq m\\leq 8$. The R(8,2) computation used 84 qubits of which 28 were computational qubits. This computation is the largest experimental implementation of a scientifically meaningful adiabatic evolution algorithm that has been done to date.

  10. Advanced batteries for electric vehicle applications

    SciTech Connect (OSTI)

    Henriksen, G.L.

    1993-08-01

    A technology assessment is given for electric batteries with potential for use in electric powered vehicles. Parameters considered include: specific energy, specific power, energy density, power density, cycle life, service life, recharge time, and selling price. Near term batteries include: nickel/cadmium and lead-acid batteries. Mid term batteries include: sodium/sulfur, sodium/nickel chloride, nickel/metal hydride, zinc/air, zinc/bromine, and nickel/iron systems. Long term batteries include: lithium/iron disulfide and lithium- polymer systems. Performance and life testing data for these systems are discussed. (GHH)

  11. Constrained Ramsey Numbers of Graphs

    E-Print Network [OSTI]

    Jiang, Tao

    Constrained Ramsey Numbers of Graphs Robert E. Jamison,1 Tao Jiang,2* and Alan C. H. Ling3 1-like trees. � 2002 Wiley Periodicals, Inc. J Graph Theory 42: 1­16, 2003 Keywords: Ramsey; monochromatic edges have the same color and rainbow iff all of its edges have different colors. In classical Ramsey

  12. Swimming by numbers QUANTUM CONTROL

    E-Print Network [OSTI]

    Mahadevan, L.

    flow, providing key qualitative insight in fluid mechanics. For example, the so-called Reynolds number be described by a universal mechanical principle seems optimistic -- if not entirely unrealistic. Now, however and pressure forces relevant for net propulsion. A measure of the thrust force is given by the mass

  13. Chemical Hydrides Ken Stroh, facilitator

    E-Print Network [OSTI]

    and reactor engineering · Development of process designs and PFDs · System integration issues · Technology Development Approach To Deliver Economic H2 via NaBH4 NaBH4 Natural Gas Solar Energy Hydro Power H2 Catalyst (theoretical) energy requirements including regeneration ­ Availability of basic components ­ Safety

  14. Louisiana Natural Gas Number of Residential Consumers (Number of Elements)

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963Residential Consumers (Number of33Cubic Foot)Year Jan

  15. California Natural Gas Number of Residential Consumers (Number of Elements)

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4 ArizonaResidential Consumers (Number of Elements)

  16. Nebraska Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home PageMonthly","10/2015"4,"Ames5 Tables July 1996 Energy Information Administration Office of Coal, Nuclear,Decade Year-03.823,172 3,009165,360Industrial Consumers (Number of

  17. Nebraska Natural Gas Number of Residential Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home PageMonthly","10/2015"4,"Ames5 Tables July 1996 Energy Information Administration Office of Coal, Nuclear,Decade Year-03.823,172 3,009165,360Industrial Consumers (Number

  18. North Dakota Natural Gas Number of Industrial Consumers (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home PageMonthly","10/2015"4,"Ames5 Tables July 1996 Energy Information Administration Office of Coal, Nuclear,DecadeYear Jan FebElements) Industrial Consumers (Number of

  19. North Dakota Natural Gas Number of Residential Consumers (Number of

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home PageMonthly","10/2015"4,"Ames5 Tables July 1996 Energy Information Administration Office of Coal, Nuclear,DecadeYear Jan FebElements) Industrial Consumers (Number

  20. The Fermat and Mersenne Numbers 

    E-Print Network [OSTI]

    Nowlin, W. D.

    1960-01-01

    . (Throughout this thesis, F will always denote a Feraat nmaber and M a Mersenne nuuber. ) The problea of deternining p which of the Fernat and Mersenne nmabers are prius has concerned uany matheuaticians during the last two centuries. This research has... or a Fermat, number. Next? Froth~a theorem, of which Pepin's test is a special case, is stated and proved. In the last section the theory of recurring series is used to establish primality tests of the Lucas type for both the Fermat and Mersenne...

  1. Hydrides of CeNi/sub 5/, MmNi/sub 5/, Ca/sub 0/ /sub 2/(Ce/sub 0/ /sub 65/Mm/sub 0/ /sub 35/)/sub 0/ /sub 8/Ni/sub 5/, Ca/sub 0/ /sub 2/Ce/sub 0/ /sub 8/Ni/sub 5/, Ca/sub 0/ /sub 2/Mm/sub 0/ /sub 8/Ni/sub 5/, and mixed CeNi/sub 5//MmNi/sub 5/

    SciTech Connect (OSTI)

    Lakner, J.F.; Chow, T.S.

    1982-09-01

    Six intermetallic alloys (CeNi/sub 5/, MmNi/sub 5/, Ca/sub 0/ /sub 2/(Ce/sub 0/ /sub 65/Mm/sub 0/ /sub 35/)/sub 0/ /sub 8/Ni/sub 5/, Ca/sub 0/ /sub 2/Ce/sub 0/ /sub 8/Ni/sub 5/, Ca/sub 0/ /sub 2/Mm/sub 0/ /sub 8/Ni/sub 5/, and a mixed alloy, CeNi/sub 5//MmNi/sub 5/) were investigated with respect to their suitability to provide high hydrogen capacity and their potential for use in providing substantial hydrogen pressure at both low and high temperatures. A second phase of our investigation dealt with ball-milling and hydriding and dehydriding cycles to produce fine particles for use in hydride powder transfer studies. A summary of several Van't Hoff plots is also included for hydride-forming alloys.

  2. DRAFT CRUISE REPORT Cruise Number: DY0807

    E-Print Network [OSTI]

    Neuston (Neu) 68 Deployment of satellite buoy (SatBuoy) 3 Samples Collected Tows Number Number of larvae of buoy or mooring (Deploy) 3 3 Stimulated fluorescence collected during CTD casts (Fluor) 18 Number

  3. Ramsey numbers of sparse hypergraphs David Conlon

    E-Print Network [OSTI]

    Fox, Jacob

    Ramsey numbers of sparse hypergraphs David Conlon Jacob Fox Benny Sudakov Abstract We give a short proof that any k-uniform hypergraph H on n vertices with bounded degree has Ramsey number at most c(, k on the Ramsey number of hypergraphs with at most m edges. 1 Introduction For a graph H, the Ramsey number r

  4. Department for Analysis and Computational Number Theory Additive functions and number systems

    E-Print Network [OSTI]

    Department for Analysis and Computational Number Theory Additive functions and number systems systems April 7, 2010 1 / 35 #12;Department for Analysis and Computational Number Theory Outline Number and Computational Number Theory Number systems Let R be an integral domain, b R, and N = {n1, . . . , nm} R

  5. Prime number generation and factor elimination

    E-Print Network [OSTI]

    Vineet Kumar

    2014-10-06

    We have presented a multivariate polynomial function termed as factor elimination function,by which, we can generate prime numbers. This function's mapping behavior can explain the irregularities in the occurrence of prime numbers on the number line. Generally the different categories of prime numbers found till date, satisfy the form of this function. We present some absolute and probabilistic conditions for the primality of the number generated by this method. This function is capable of leading to highly efficient algorithms for generating prime numbers.

  6. Turing's normal numbers: towards randomness Veronica Becher

    E-Print Network [OSTI]

    presumably in 1938 Alan Turing gave an algorithm that produces real numbers normal to every integer base- putable normal numbers, and this result should be attributed to Alan Turing. His manuscript entitled "A

  7. Small Ramsey Numbers Stanislaw P. Radziszowski

    E-Print Network [OSTI]

    Radziszowski, Stanislaw P.

    Small Ramsey Numbers Stanislaw P. Radziszowski Department of Computer Science Rochester Institute Ramsey numbers, where the avoided graphs are complete or complete without one edge. Many results per behavior of Ramsey numbers, but rather we concentrate on their specific values. Mathematical Reviews

  8. Ramsey Numbers Involving Cycles Stanislaw P. Radziszowski

    E-Print Network [OSTI]

    Radziszowski, Stanislaw P.

    Ramsey Numbers Involving Cycles Stanislaw P. Radziszowski Department of Computer Science Rochester and data on Ramsey numbers involving cycles. This survey is based on the author's 2009 revi- sion #12 of the Dynamic Survey DS1, "Small Ramsey Numbers", at the Electronic Journal of Combinatorics. Table of Contents

  9. SHARP THRESHOLDS FOR HYPERGRAPH REGRESSIVE RAMSEY NUMBERS

    E-Print Network [OSTI]

    Lee, Gyesik

    SHARP THRESHOLDS FOR HYPERGRAPH REGRESSIVE RAMSEY NUMBERS LORENZO CARLUCCI, GYESIK LEE, AND ANDREAS WEIERMANN Abstract. The f-regressive Ramsey number Rreg f (d, n) is the minimum N such that every colouring regressive Ramsey numbers as defined by Kanamori and McAloon. In this paper we classifiy the growth

  10. Motivation Examples Star Avoiding Ramsey Numbers

    E-Print Network [OSTI]

    Isaak, Garth

    Motivation Examples Star Avoiding Ramsey Numbers Jonelle Hook, Garth Isaak Department and Cryptography Jonelle Hook, Garth Isaak Star Avoiding Ramsey Numbers #12;Motivation Examples Graph Ramsey-coloring of K13 has a red C5 or a blue K4. Jonelle Hook, Garth Isaak Star Avoiding Ramsey Numbers #12

  11. Diagonal Ramsey Numbers in Multipartite Graphs

    E-Print Network [OSTI]

    van Vuuren, Jan H.

    Diagonal Ramsey Numbers in Multipartite Graphs AP Burger , PJP Grobler , EH Stipp & JH van Vuuren September 17, 2003 Abstract The notion of a graph theoretic Ramsey number is generalised by assuming definition. Some small multipartite Ramsey numbers are found, while upper and lower bounds are established

  12. Diagonal Ramsey Numbers in Multipartite Graphs

    E-Print Network [OSTI]

    van Vuuren, Jan H.

    Diagonal Ramsey Numbers in Multipartite Graphs AP Burger + , PJP Grobler # , EH Stipp # & JH van Vuuren # September 17, 2003 Abstract The notion of a graph theoretic Ramsey number is generalised as in the classical definition. Some small multipartite Ramsey numbers are found, while upper and lower bounds

  13. Number of peer-reviewed publications

    E-Print Network [OSTI]

    ·Number of peer- reviewed publications produced per year ·Data accurate as of 02 April 2012 · Number of publications produced per institution (top 10) ·Collaborations counted multiple times · Non-cumulative number of citations received by OER publications per year ·Data accurate as of 02 April 2012 · The work

  14. Company number 5857955 Wellcome Trust Finance plc

    E-Print Network [OSTI]

    Rambaut, Andrew

    Company number 5857955 Wellcome Trust Finance plc Annual Report and Financial Statements Year ended 30 September 2014 #12;Company number 5857955 Wellcome Trust Finance plc Contents Page Strategic number 58579551 Wellcome Trust Finance plc Strategic Report For the year ended 30 September 2014

  15. KIAS SEOUL, February 2004 Transcendental Number Theory

    E-Print Network [OSTI]

    Waldschmidt, Michel

    ) ­ Introductio in Analysin Infinitorum. Suggests the transcendence of log 1/ log 2 when this number is irrational in Analysin Infinitorum. Suggests the transcendence of log 1/ log 2 when this number is irrational (for this number is irrational (for algebraic 1 and 2). http://www.math.jussieu.fr/miw/ 14 #12;Euler (1748

  16. Number Theory I: Tools and Diophantine Equations

    E-Print Network [OSTI]

    Cohen, Henri

    covered by two other books of the author [Coh0] and [Coh1]. The central (although not unique) theme in integers, rational numbers, or more generally in algebraic numbers. This theme is in particular the central of the reader that he or she is familiar with the standard basic theory of number fields, up to and including

  17. Clar number of catacondensed benzenoid hydrocarbons

    E-Print Network [OSTI]

    Klavzar, Sandi

    Clar number of catacondensed benzenoid hydrocarbons Sandi KlavŸzar a,# , Petra Ÿ Zigert a , Ivan hydrocarbon: CL is equal to the minimum number of straight lines required to intersect all hexagons theory; Clar formula; Clar number; Resonance graph; Benzenoid hydrocarbons 1. Introduction Within

  18. Tip sheet: Expanded Library of Congress Call Number Classification system Call Number Subject Matter

    E-Print Network [OSTI]

    Kambhampati, Patanjali

    Tip sheet: Expanded Library of Congress Call Number Classification system Call Number Subject R: Medicine T: Technology U: Military Science Z: Bibliography. Library Science. Information

  19. Bounds on Some Ramsey Numbers Involving Quadrilateral +

    E-Print Network [OSTI]

    Radziszowski, Stanislaw P.

    Bounds on Some Ramsey Numbers Involving Quadrilateral + Xiaodong Xu Guangxi Academy of Sciences@cs.rit.edu Abstract. For graphs G 1 , G 2 , · · · , Gm , the Ramsey number R(G 1 , G 2 , · · · , Gm ) is defined Ramsey numbers involving quadrilateral C 4 , including R(C 4 , K 9 ) # 32, 19 # R(C 4 , C 4 , K 4 ) # 22

  20. Predicting landfalling hurricane numbers from basin hurricane numbers: basic statistical analysis

    E-Print Network [OSTI]

    Laepple, T; Penzer, J; Bellone, E; Nzerem, K; Laepple, Thomas; Jewson, Stephen; Penzer, Jeremy; Bellone, Enrica; Nzerem, Kechi

    2007-01-01

    One possible method for predicting landfalling hurricane numbers is to first predict the number of hurricanes in the basin and then convert that prediction to a prediction of landfalling hurricane numbers using an estimated proportion. Should this work better than just predicting landfalling hurricane numbers directly? We perform a basic statistical analysis of this question in the context of a simple abstract model.

  1. Harmonic resolution as a holographic quantum number

    E-Print Network [OSTI]

    Bousso, Raphael

    2009-01-01

    LBNL- 57239 Harmonic resolution as a holographic quantumhep-th/0310223 UCB-PTH-03/26 Harmonic resolution as aquantum number, the harmonic resolution K. The Bekenstein

  2. REFINED BOUNDS ON THE NUMBER OF CONNECTED ...

    E-Print Network [OSTI]

    2011-04-06

    Apr 6, 2011 ... Smith inequality (see Theorem 2.5) a bound on the number of semi- ... then using Smith inequality, have been used before in several different ...

  3. Call Numbers** A, B, C 3rd

    E-Print Network [OSTI]

    Saldin, Dilano

    Call Numbers** A, B, C 3rd Floor Southeast . D, E, F, G, H, J, K, L 3rd Floor West . . . . . P 3rd Floor West . Q, R

  4. Numbers, proof and 'all that jazz'.

    E-Print Network [OSTI]

    2007-01-08

    CHAPTER 1. Numbers, proof and 'all that jazz'. There is a fundamental difference between mathematics and other sciences. In most sciences, one does ...

  5. A Thermodynamic Classification of Real Numbers

    E-Print Network [OSTI]

    Thomas Garrity

    2009-03-15

    A new classification scheme for real numbers is given, motivated by ideas from statistical mechanics in general and work of Knauf and of Fiala and Kleban in particular. Critical for this classification of a real number will be the Diophantine properties of its continued fraction expansion.

  6. Circular Chromatic Ramsey Number Kyle F. Jao

    E-Print Network [OSTI]

    West, Douglas B.

    Circular Chromatic Ramsey Number Kyle F. Jao , Claude Tardif , Douglas B. West , Xuding Zhu, the circular chromatic Ramsey number Rc (F, G) is the infimum of c(H) over graphs H such that every red of a Ramsey problem for the families of homomorphic images of F and G. Letting zk = 3 - 2-k, we prove that zk

  7. 2001 TRAFFIC ZONE BOUNDARIES Zone Numbers

    E-Print Network [OSTI]

    Toronto, University of

    2001 TRAFFIC ZONE BOUNDARIES Zone Numbers & Detailed Definitions #12;2001 TRAFFIC ZONE BOUNDARIES of Toronto Joint Program in Transportation January 2003 #12;PREFACE This report presents the 2001 traffic zone numbers by local municipalities in the 2001 TTS survey area. The second part presents detailed

  8. Real numbers and other completions Fred Richman

    E-Print Network [OSTI]

    Richman, Fred

    Real numbers and other completions Fred Richman Florida Atlantic University Boca Raton, FL 33431 11 March 2007 Abstract A notion of completeness and completion suitable for use in the absence of countable choice is developed. This encompasses the con- struction of the real numbers as well as the completion

  9. Company number 5857955 Wellcome Trust Finance plc

    E-Print Network [OSTI]

    Rambaut, Andrew

    Company number 5857955 Wellcome Trust Finance plc Annual Report and Financial Statements Year ended 30 September 2012 #12;Company number 5857955 Wellcome Trust Finance plc Contents Page Directors Trust Finance plc Directors' Report for the year ended 30 September 2012 Report of the Directors

  10. Company number 5857955 Wellcome Trust Finance plc

    E-Print Network [OSTI]

    Rambaut, Andrew

    Company number 5857955 Wellcome Trust Finance plc Annual Report and Financial Statements Year ended 30 September 2013 #12;Company number 5857955 Wellcome Trust Finance plc Contents Page Directors Trust Finance plc Directors' Report For the year ended 30 September 2013 Report of the Directors

  11. RNG: A Practitioner's Overview Random Number Generation

    E-Print Network [OSTI]

    Mascagni, Michael

    -Kac/path integral methods to solve partial differential equations with random walks Defense: neutronics, nuclear random numbers 1. Each calculation is a numerical experiment Subject to known and unknown sources a calculation with the same numbers Across different machines (modulo arithmetic issues) Parallel

  12. Resolution-Stationary Random Number Generators

    E-Print Network [OSTI]

    L'Ecuyer, Pierre

    of successive output values over their entire period length. For F2-linear generators, the commonly adopted efficient ways of implementing high-quality and long-period Tausworthe generators. Key words: random number un [0, 1) is the output of the generator at step n and the number of bits in this output, L

  13. enter part number BNC / RP-BNC

    E-Print Network [OSTI]

    Berns, Hans-Gerd

    enter part number Products 7/16 1.0/2.3 1.6/5.6 AFI AMC BNC / RP-BNC C FAKRA SMB FME HN MCX Mini ------- Product Search ------- Inventory Search Search Results for: 31-10152-RFX Results: 1 - 1 of 1 Part Number. All rights reserved. Copyright | Terms & Conditions | RF E-Mail Client | Contact Us | Amphenol

  14. Ramsey numbers and adiabatic quantum computing

    E-Print Network [OSTI]

    Frank Gaitan; Lane Clark

    2012-01-08

    The graph-theoretic Ramsey numbers are notoriously difficult to calculate. In fact, for the two-color Ramsey numbers $R(m,n)$ with $m,n\\geq 3$, only nine are currently known. We present a quantum algorithm for the computation of the Ramsey numbers $R(m,n)$. We show how the computation of $R(m,n)$ can be mapped to a combinatorial optimization problem whose solution can be found using adiabatic quantum evolution. We numerically simulate this adiabatic quantum algorithm and show that it correctly determines the Ramsey numbers R(3,3) and R(2,s) for $5\\leq s\\leq 7$. We then discuss the algorithm's experimental implementation, and close by showing that Ramsey number computation belongs to the quantum complexity class QMA.

  15. A STUDY OF FUNDAMENTAL REACTION PATHWAYS FOR TRANSITION METAL ALKYL COMPLEXES. I. THE REACTION OF A NICKEL METHYL COMPLEX WITH ALKYNES. II. THE MECHANISM OF ALDEHYDE FORMATION IN THE REACTION OF A MOLYBDENUM HYDRIDE WITH MOLYBDENUM ALKYLS

    SciTech Connect (OSTI)

    Huggins, John Mitchell

    1980-06-01

    I. This study reports the rapid reaction under mild conditions of internal or terminal alkynes with methyl (acetyl~ acetonato) (triphenylphosphine) nickel (1) in either aromatic or ether solvents. In all cases vinylnickel products 2 are formed by insertion of the alkyne into the nickel=methyl bond. These complexes may be converted into a variety of organic products (e.g. alkenes, esters, vinyl halides) by treatment with appropriate reagents. Unsymmetrical alkynes give selectively the one regioisomer with the sterically largest substituent next to the nickel atom. In order to investigate the stereochemistry of the initial insertion, a x-ray diffraction study of the reaction of 1 with diphenylacetylene was carried out. This showed that the vinylnickel complex formed by overall trans insertion was the product of the reaction. Furthermore, subsequent slow isomerization of this complex, to a mixture of it and the corresponding cis isomer, demonstrated that this trans addition product is the kinetic product of the reaction. In studies with other alkynes, the product of trans addition was not always exclusively (or even predominantly) formed, but the ratio of the stereoisomers formed kinetically was substantially different from the thermodynamic ratio. Isotope labeling, added phosphine, and other experiments have allowed us to conclude that the mechanism of this reaction does involve initial cis addition. However, a coordinatively unsaturated vinylnickel complex is initially formed which can undergo rapid, phosphine-catalyzed cis-trans isomerization in competition with its conversion to the isolable phosphine-substituted kinetic reaction products. II. The reaction of CpMo(CO){sub 3}H (1a) with CpMo(CO){sub 3}R (2, R= CH{sub 3}, C{sub 2}H{sub 5}) at 50{degrees} C in THF gives the aldehyde RCHO and the dimers [CpMo(CO){sub 3}]{sub 2} (3a) and [CpMo(CO){sub 2}]{sub 2} (4a). Labeling one of the reactants with a methylcyclopentadienyl ligand it was possible to show that the mixed dimers MeCpMo(CO){sub 3}-(CO){sub 3}MoCp (3b) and MeCpMo(CO){sub 2}{triple_bond}(CO){sub 2}MoCp (4b) are the predominant kinetic products of the reaction. Additionally labeling the carbonyl ligands of 1a with {sup 13}CO led to the conclusion that all three of the carbonyl ligands in 1a end up in the tetracarbonyl dimers 4a if the reaction is carried out under a continuous purge of argon Trapping studies failed to find any evidence for the intermediacy of either [CpMo(CO){sub 3}]{sup -} or [CpMo(CO){sub 3}]{sup +} in this reaction. A mechanism is proposed that involves the initial migration of the alkyl ligand in 2 to CO forming an unsaturated acyl complex which reacts with 1a to give a binuclear complex containing a three center-two electron Mo-H-Mo bond. This complex then selectively looses a carbonyl from the acyl molybdenum, migrates the hydride to that same metal, and forms a metal-metal bond. This binuclear complex with the hydride and acyl ligands on one metal reductively eliminates aldehyde, and migrates a carbonyl ligand, to give 4a directly. The other product 3a is formed by addition of two molecules of free CO to 4a.

  16. Position Number: (Assigned when added to Library)

    E-Print Network [OSTI]

    California at Davis, University of

    Position Number: (Assigned when added to Library) 02016240 Dept: INST OF TRANSPORTATION STUDIES distributions to social media and trade media. 20% WEBSITE, SOCIAL MEDIA AND MEDIA MONITORING Monitor trends

  17. Polygonal Numbers, Primes and Ternary Quadratic Forms

    E-Print Network [OSTI]

    Sun, Zhi-Wei

    Polygonal Numbers, Primes and Ternary Quadratic Forms Zhi-Wei Sun Nanjing University Nanjing 210093 three papers: Z. W. Sun [Acta Arith. 2007], S. Guo, H. Pan & Z. W. Sun [Integers, 2007], and B. K. Oh

  18. High speed optical quantum random number generation

    E-Print Network [OSTI]

    Weinfurter, Harald

    High speed optical quantum random number generation Martin F¨urst1,2,, Henning Weier1,2, Sebastian/publicationFile/30276/ais20 pdf.pdf (1999). 2. "Fips 140-2, security requirements for cryptographic modules

  19. Unpredictability and the transmission of numbers

    E-Print Network [OSTI]

    Myers, John M

    2015-01-01

    Curiously overlooked in physics is its dependence on the transmission of numbers. For example the transmission of numerical clock readings is implicit in the concept of a coordinate system. The transmission of numbers and other logical distinctions is often achieved over a computer-mediated communications network in the face of an unpredictable environment. By unpredictable we mean something stronger than the spread of probabilities over given possible outcomes, namely an opening to unforeseeable possibilities. Unpredictability, until now overlooked in theoretical physics, makes the transmission of numbers interesting. Based on recent proofs within quantum theory that provide a theoretical foundation to unpredictability, here we show how regularities in physics rest on a background of channels over which numbers are transmitted. As is known to engineers of digital communications, numerical transmissions depend on coordination reminiscent of the cycle of throwing and catching by players tossing a ball back and...

  20. Department.: Music Department Course number: 210W

    E-Print Network [OSTI]

    Alpay, S. Pamir

    Department.: Music Department Course number: 210W Course title: Music, History, and Ideas Credits: 3 Contact Person: Alain Frogley Catalog Copy: MUSI 210W. Music, History, and Ideas Either semester

  1. Department.: Psychology Course Number: PSYC 210W

    E-Print Network [OSTI]

    Alpay, S. Pamir

    Department.: Psychology Course Number: PSYC 210W Course Title: Lab in Cognition Credits: 3 Contact in these experiments, the writing assignments provide a richer and fuller of the nature of psychological inquiry

  2. Department.: Psychology Course Number: PSYC 244W

    E-Print Network [OSTI]

    Alpay, S. Pamir

    Department.: Psychology Course Number: PSYC 244W Course Title: Laboratory in Personality Credits: 3 Psychological Association. The total report is at least 15 pages in length. The final report is the primary

  3. Department.: Psychology Course Number: PSYC 263W

    E-Print Network [OSTI]

    Alpay, S. Pamir

    Department.: Psychology Course Number: PSYC 263W Course Title: Laboratory in Animal Learning or 253 , and consent of instructor; ENGL 105 or 110 or 111 or 250 . W Criteria: Psychology 263W is a lab

  4. Student ID (R) Number ________________________ Semester/Year______ ________________________

    E-Print Network [OSTI]

    Rock, Chris

    Student ID (R) Number ________________________ Semester/Year______ ________________________ THIRD: ______________________________________________________ CHECK ALL THAT APPLY: _____First-time Third Party Student _____TTU Campus Student _____Non sponsor and the Third Party Sponsor Agreement prior to the due date to ensure timely posting of third

  5. Computing the Betti Numbers of Arrangements

    E-Print Network [OSTI]

    2015-08-29

    To our knowledge ... on ?. Categories and Subject Descriptors ... sets defined in terms of such hypersurfaces can be topolog- ... The first bounds on the individual Betti numbers of semi- .... The idea of using filtrations for computing Betti num-.

  6. Dynamical real numbers and living systems

    E-Print Network [OSTI]

    Dhurjati Prasad Datta

    2010-01-11

    Recently uncovered second derivative discontinuous solutions of the simplest linear ordinary differential equation define not only an nonstandard extension of the framework of the ordinary calculus, but also provide a dynamical representation of the ordinary real number system. Every real number can be visualized as a living cell -like structure, endowed with a definite evolutionary arrow. We discuss the relevance of this extended calculus in the study of living systems. We also present an intelligent version of the Newton's first law of motion.

  7. True random numbers from amplified quantum vacuum

    E-Print Network [OSTI]

    M. Jofre; M. Curty; F. Steinlechner; G. Anzolin; J. P. Torres; M. W. Mitchell; V. Pruneri

    2011-10-17

    Random numbers are essential for applications ranging from secure communications to numerical simulation and quantitative finance. Algorithms can rapidly produce pseudo-random outcomes, series of numbers that mimic most properties of true random numbers while quantum random number generators (QRNGs) exploit intrinsic quantum randomness to produce true random numbers. Single-photon QRNGs are conceptually simple but produce few random bits per detection. In contrast, vacuum fluctuations are a vast resource for QRNGs: they are broad-band and thus can encode many random bits per second. Direct recording of vacuum fluctuations is possible, but requires shot-noise-limited detectors, at the cost of bandwidth. We demonstrate efficient conversion of vacuum fluctuations to true random bits using optical amplification of vacuum and interferometry. Using commercially-available optical components we demonstrate a QRNG at a bit rate of 1.11 Gbps. The proposed scheme has the potential to be extended to 10 Gbps and even up to 100 Gbps by taking advantage of high speed modulation sources and detectors for optical fiber telecommunication devices.

  8. Unpredictability and the transmission of numbers

    E-Print Network [OSTI]

    John M. Myers; F. Hadi Madjid

    2015-08-05

    Curiously overlooked in physics is its dependence on the transmission of numbers. For example the transmission of numerical clock readings is implicit in the concept of a coordinate system. The transmission of numbers and other logical distinctions is often achieved over a computer-mediated communications network in the face of an unpredictable environment. By unpredictable we mean something stronger than the spread of probabilities over given possible outcomes, namely an opening to unforeseeable possibilities. Unpredictability, until now overlooked in theoretical physics, makes the transmission of numbers interesting. Based on recent proofs within quantum theory that provide a theoretical foundation to unpredictability, here we show how regularities in physics rest on a background of channels over which numbers are transmitted. As is known to engineers of digital communications, numerical transmissions depend on coordination reminiscent of the cycle of throwing and catching by players tossing a ball back and forth. In digital communications, the players are computers, and the required coordination involves unpredictably adjusting "live clocks" that step these computers through phases of a cycle. We show how this phasing, which we call `logical synchronization,' constrains number-carrying networks, and, if a spacetime manifold in invoked, put "stripes" on spacetime. Via its logically synchronized channels, a network of live clocks serves as a reference against which to locate events. Such a network in any case underpins a coordinate frame, and in some cases the direct use of a network can be tailored to investigate an unpredictable environment. Examples include explorations of gravitational variations near Earth.

  9. Baryon Number as the Fourth Color

    E-Print Network [OSTI]

    Fornal, Bartosz; Tait, Tim M P

    2015-01-01

    We propose an extension of the Standard Model in which baryon number is promoted to be part of a non-Abelian gauge symmetry at high energies. Specifically, we consider the gauge group SU(4) x SU(2)_L x U(1)_X, where the SU(4) unifies baryon number and color. This symmetry is spontaneously broken down to the Standard Model gauge group at a scale which can be as low as a few TeV. The SU(4) structure implies that each SM quark comes along with an uncolored quark partner, the lightest of which is stabilized by the generalized baryon number symmetry and can play the role of dark matter. We explore circumstances under which one can realize a model of asymmetric dark matter whose relic abundance is connected to the observed baryon asymmetry, and discuss unique signatures that can be searched for at the LHC.

  10. Hypergraph Ramsey Numbers and Adiabatic Quantum Algorithm

    E-Print Network [OSTI]

    Ri Qu; Yan-ru Bao

    2012-07-18

    Gaitan and Clark [Phys. Rev. Lett. 108, 010501 (2012)] have recently presented a quantum algorithm for the computation of the Ramsey numbers R(m, n) using adiabatic quantum evolution. We consider that the two-color Ramsey numbers R(m, n; r) for r-uniform hypergraphs can be computed by using the similar ways in [Phys. Rev. Lett. 108, 010501 (2012)]. In this comment, we show how the computation of R(m, n; r) can be mapped to a combinatorial optimization problem whose solution be found using adiabatic quantum evolution.

  11. Probing lepton number violation on three frontiers

    SciTech Connect (OSTI)

    Deppisch, Frank F. [Department of Physics and Astronomy, University College London (United Kingdom)

    2013-12-30

    Neutrinoless double beta decay constitutes the main probe for lepton number violation at low energies, motivated by the expected Majorana nature of the light but massive neutrinos. On the other hand, the theoretical interpretation of the (non-)observation of this process is not straightforward as the Majorana neutrinos can destructively interfere in their contribution and many other New Physics mechanisms can additionally mediate the process. We here highlight the potential of combining neutrinoless double beta decay with searches for Tritium decay, cosmological observations and LHC physics to improve the quantitative insight into the neutrino properties and to unravel potential sources of lepton number violation.

  12. Determine Ramsey numbers on a quantum computer

    E-Print Network [OSTI]

    Hefeng Wang

    2015-10-07

    We present a quantum algorithm for computing the Ramsey numbers whose computational complexity grows super-exponentially with the number of vertices of a graph on a classical computer. The problem is mapped to a decision problem on a quantum computer, a probe qubit is coupled to a register that represents the problem and detects the energy levels of the problem Hamiltonian. The decision problem is solved by determining whether the probe qubit exhibits resonance dynamics. The algorithm shows a quadratic speedup over its classical counterparts, and the degenerate ground state problem in the adiabatic quantum evolution algorithm for this problem is avoided.

  13. Compare Activities by Number of Employees

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)DecadeYear Jan Feb Mar Apr May Jun Jul Aug Sep3,118,592Number of ComputersNumber

  14. The New Element Curium (Atomic Number 96)

    DOE R&D Accomplishments [OSTI]

    Seaborg, G. T.; James, R. A.; Ghiorso, A.

    1948-00-00

    Two isotopes of the element with atomic number 96 have been produced by the helium-ion bombardment of plutonium. The name curium, symbol Cm, is proposed for element 96. The chemical experiments indicate that the most stable oxidation state of curium is the III state.

  15. Department .: Sociology Course number : Soci 290W

    E-Print Network [OSTI]

    Alpay, S. Pamir

    Department .: Sociology Course number : Soci 290W Title : Social Movements and Social Change Credits : 3 Contact Person : Brad Wright Catalog Copy : Soci 290. Social Movements and Social Change, and escapist movements. Soci 290W. Social Movements and Social Change. Prerequisite: Engl 110 or 111 or 250. W

  16. Department .: Sociology Course number : Soci 227W

    E-Print Network [OSTI]

    Alpay, S. Pamir

    Department .: Sociology Course number : Soci 227W Title : Revolutionary Social Movements Around the World Credits : 3 Contact Person : Brad Wright Catalog Copy : Soci 227. Revolutionary Social Movements, and Nicaraguan revolutions and movements in South Africa and the Middle East. Soci 227W. Revolutionary Social

  17. Entropy Numbers, Operators and Support Vector Kernels

    E-Print Network [OSTI]

    Botea, Adi

    feature of the present paper is the manner in which we directly bound the covering numbers of interest Supported by the Australian Research Council and the DFG (# Ja 379/71). P. Fischer and H.U. Simon (Eds.): EuroCOLT'99, LNAI 1572, pp. 285­298, 1999. c Springer-Verlag Berlin Heidelberg 1999 #12;286 Robert C

  18. Code Number: Department of Mechanical Engineering

    E-Print Network [OSTI]

    Feeny, Brian

    that the drag force on a plate of length L is given by = L wallD wdxxF 0 )( , calculate the overall drag if the Reynolds number ReL is large making the drag coefficient small, the drag force FD becomes large. Use of a falling sphere depends on the sphere diameter, sphere density, fluid density, fluid viscosity

  19. Department: HISTORY Course number: 3551 W

    E-Print Network [OSTI]

    Alpay, S. Pamir

    Department: HISTORY Course number: 3551 W Course title: Topics in U.S. Legal History Credits: 3 Contact Person: Sherri Olson Q/W: W Catalog Copy:HIST 3551W [248W]. Topics in U.S.Legal History. 3 credits

  20. Department: HISTORY Course number: 3412 W

    E-Print Network [OSTI]

    Alpay, S. Pamir

    Department: HISTORY Course number: 3412 W Course title: Intellectual and Social History of Europe]. Intellectual and Social History of Europe in the Nineteenth Century LANSING, DINTENFASS Prerequisite: ENGL 105 or 110 or 111 or 250. Course Information: The course explores the history of European thought in its

  1. QUARTERLY OF APPLIED MATHEMATICS VOLUME , NUMBER 0

    E-Print Network [OSTI]

    Zhu, Song Chun

    reweighting the energy function. We construct ELMs in the model space for two classic statistical learning, two-step EM and Swendsen-Wang cuts, in the energy landscapes. 1. Introduction. In many statisticalQUARTERLY OF APPLIED MATHEMATICS VOLUME , NUMBER 0 XXXX XXXX, PAGES 000­000 MAPPING ENERGY

  2. Maine Number of Natural Gas Consumers

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    20,806 21,142 22,461 23,555 24,765 27,047 1987-2014 Sales 21,141 22,461 23,555 24,765 27,047 1997-2014 Transported 1 0 0 0 0 2010-2014 Commercial Number of Consumers 8,815 9,084...

  3. Department.: Marketing Course number: MKTG 4997W

    E-Print Network [OSTI]

    Alpay, S. Pamir

    Department.: Marketing Course number: MKTG 4997W Course title: Senior Thesis in Marketing Credits that it become a 'W' course: 4997. Senior Thesis in Marketing (296) Either semester. Three credits. Hours by arrangement. Prerequisite: Open only to Marketing Department Honor Students with consent of instructor

  4. Materials Science Volume 7, Number 4

    E-Print Network [OSTI]

    Poeppelmeier, Kenneth R.

    Materials Science TM Volume 7, Number 4 Technologies for a changing world Nanomaterials for Energy Conversion and Storage Electrode Materials for Lithium Ion Batteries Surface-enhanced Solar Energy Convesion Changing the Landscape of Environmental and Energy Research Through Novel Nanoscale Materials #12

  5. Department: Art History Course number: 3050W

    E-Print Network [OSTI]

    Alpay, S. Pamir

    Department: Art History Course number: 3050W Course title: African American Art Credits: 3 Contact Person:Jean Givens Content Area: Q/W: W only Catalog Copy:ARTH 3050W African American Art, Either semester. 3 credits The artistic and social legacy of African American art from the eighteenth century

  6. Department: Art & Art History Course number: 3375

    E-Print Network [OSTI]

    Alpay, S. Pamir

    Department: Art & Art History Course number: 3375 Course title: Indian Art and Popular Culture Copy: ART 244/3375: Indian Art and Popular Culture: Independence to the Present, 3 credits. Either semester. Instructor: Myers. An interdisciplinary studio art course introducing modern, contemporary, folk

  7. Department: Journalism Course number: 3045W

    E-Print Network [OSTI]

    Alpay, S. Pamir

    Department: Journalism Course number: 3045W Course title: Specialized Reporting Credits: 3 Contact Person: Wayne Worcester Q/W: W Catalog Copy: JOUR 245W. Specialized Journalism Either semester. Three and feature stories and journalism that demands unswerving accuracy, uncommon grace and thoughtful context

  8. Ramsey numbers of cubes versus cliques

    E-Print Network [OSTI]

    Conlon, David

    The cube graph Q[subscript n] is the skeleton of the n-dimensional cube. It is an n-regular graph on 2[superscript n] vertices. The Ramsey number r(Q[subscript n] ;K[subscript s]) is the minimum N such that every graph of ...

  9. Department: Statistics Course number: STAT 202W

    E-Print Network [OSTI]

    Alpay, S. Pamir

    Department: Statistics Course number: STAT 202W Title: Undergraduate Seminar II Credits: 1 Contact, and choose one statistical topic to investigate in detail. The student will write a well revised will attend 6-8 seminars per semester, and choose one statistical topic to investigate in detail. The student

  10. Family Name: . . . . . . . . . . . . . . . . . . . . . . . . . . Other Names: . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ID Number: . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

    E-Print Network [OSTI]

    ; } double price = 54.70 + numberComponents 18.36; return price; } (a) [1 mark] What is the name using BlueJ and enter "Yes" in the dialog box asking for the value of ans). What will it print out? HintStuffOut(String ans){ System.out.println("printStuffOut(" + ans + "):"); String first = "Maybe"; String third = ans

  11. Washington Number of Natural Gas Consumers

    Gasoline and Diesel Fuel Update (EIA)

    059,239 1,067,979 1,079,277 1,088,762 1,102,318 1,118,193 1987-2014 Sales 1,067,979 1,079,277 1,088,762 1,102,318 1,118,193 1997-2014 Commercial Number of Consumers 98,965 99,231...

  12. Building Grassmann Numbers from PI-Algebras

    E-Print Network [OSTI]

    Ricardo M. Bentin; Sergio Mota

    2012-04-06

    This works deals with the formal mathematical structure of so called Grassmann Numbers applied to Theoretical Physics, which is a basic concept on Berezin integration. To achieve this purpose we make use of some constructions from relative modern Polynomial Identity Algebras (PI-Algebras) applied to the special case of the Grassmann algebra.

  13. The 17 GHz active region number

    SciTech Connect (OSTI)

    Selhorst, C. L.; Pacini, A. A.; Costa, J. E. R.; Giménez de Castro, C. G.; Valio, A.; Shibasaki, K.

    2014-08-01

    We report the statistics of the number of active regions (NAR) observed at 17 GHz with the Nobeyama Radioheliograph between 1992, near the maximum of cycle 22, and 2013, which also includes the maximum of cycle 24, and we compare with other activity indexes. We find that NAR minima are shorter than those of the sunspot number (SSN) and radio flux at 10.7 cm (F10.7). This shorter NAR minima could reflect the presence of active regions generated by faint magnetic fields or spotless regions, which were a considerable fraction of the counted active regions. The ratio between the solar radio indexes F10.7/NAR shows a similar reduction during the two minima analyzed, which contrasts with the increase of the ratio of both radio indexes in relation to the SSN during the minimum of cycle 23-24. These results indicate that the radio indexes are more sensitive to weaker magnetic fields than those necessary to form sunspots, of the order of 1500 G. The analysis of the monthly averages of the active region brightness temperatures shows that its long-term variation mimics the solar cycle; however, due to the gyro-resonance emission, a great number of intense spikes are observed in the maximum temperature study. The decrease in the number of these spikes is also evident during the current cycle 24, a consequence of the sunspot magnetic field weakening in the last few years.

  14. Department.: Psychology Course Number: PSYC 239W

    E-Print Network [OSTI]

    Alpay, S. Pamir

    Department.: Psychology Course Number: PSYC 239W Course Title: Current Topics in Developmental Psychology Credits: 3 Contact Person: John Rickards Catalog Copy: Current Topics in Developmental Psychology Division of the Department of Psychology, the faculty have used this "Current Topics" course to fulfill

  15. Department.: Psychology Course Number: PSYC 242W

    E-Print Network [OSTI]

    Alpay, S. Pamir

    Department.: Psychology Course Number: PSYC 242W Course Title: Laboratory in Social Psychology ; PSYC 240 , and consent of instructor. Methods and techniques of research in social psychology psychology in order to be the best resources to the students, given the subject matter. #12;

  16. Department :PSYCHOLOGY Course number: 3370 W

    E-Print Network [OSTI]

    Alpay, S. Pamir

    Department :PSYCHOLOGY Course number: 3370 W Course title: Current Topics in Clinical Psychology Psychology. Three credits. Either semester. Prerequisite: PSYC 243 or PSYC 245 or PSYC 245W or consent of instructor. May be repeated for credit with a change in topic. Justification: Clinical psychology is an area

  17. Department.: Psychology Course Number: PSYC 245W

    E-Print Network [OSTI]

    Alpay, S. Pamir

    Department.: Psychology Course Number: PSYC 245W Course Title: Abnormal Psychology Credits: 3 Criteria: 1. This course covers topics in abnormal psychology, including specific syndromes in several ways. First, the students must read relevant chapters of the Psychology Student Writer's Manual

  18. Department.: Psychology Course Number: PSYC 282W

    E-Print Network [OSTI]

    Alpay, S. Pamir

    Department.: Psychology Course Number: PSYC 282W Course Title: Social-Organizational Psychology Credits: 3 Contact Person: John Rickards Catalog Copy: PSYC 282W. Social-Organizational Psychology. Either semester. Three credits. Prerequisite: PSYC 268 or PSYC 240. Barnes-Farell, Magley. Social psychological

  19. Department.: Psychology Course Number: PSYC 202QW

    E-Print Network [OSTI]

    Alpay, S. Pamir

    Department.: Psychology Course Number: PSYC 202QW Course Title: Principles of Research in Psychology Credits: 4 Contact Person: Charles A. Lowe, Department Head Catalog Copy : PSYC 202QW. Principles of Research in Psychology Either semester. Four credits. Three 1-hour lecture periods and one 2-hour

  20. Department.: Psychology Course Number: PSYC 296W

    E-Print Network [OSTI]

    Alpay, S. Pamir

    Department.: Psychology Course Number: PSYC 296W Course Title: Senior Thesis in Psychology Credits: 3 Contact Person: John Rickards Catalog Copy: Senior Thesis in Psychology. Either semester. ThreeW is an Honors course taken by Psychology majors in their last semester of study; the purpose

  1. Department.: Psychology Course Number: PSYC 232W

    E-Print Network [OSTI]

    Alpay, S. Pamir

    Department.: Psychology Course Number: PSYC 232W Course Title: Laboratory in Developmental Credits psychological research on young children; advanced topics. W Criteria: - The students will perform both as laboratory reports after each is completed. The reports will follow American Psychological Association

  2. Department.: Psychology Course Number: PSYC 280W

    E-Print Network [OSTI]

    Alpay, S. Pamir

    Department.: Psychology Course Number: PSYC 280W Course Title: Current Topics in Industrial/Organizational Psychology Credits: 3 Contact Person: John Rickards Competency Group: W only Catalog Copy: PSYC 280W. Current Topics in Industrial/Organizational Psychology. Three credits. Either semester. Prerequisites: PSYC 135

  3. Department.: Psychology Course Number: PSYC 241W

    E-Print Network [OSTI]

    Alpay, S. Pamir

    Department.: Psychology Course Number: PSYC 241W Course Title: Current Topics in Social Psychology Credits: 3 Contact Person: John Rickards Catalog Copy: 241W. Current Topics in Social Psychology. Semester of bias, communication of prejudice, self-in social psychology, psychosocial aspects of the HIV epidemic

  4. Department.: Psychology Course Number: PSYC 291W

    E-Print Network [OSTI]

    Alpay, S. Pamir

    Department.: Psychology Course Number: PSYC 291W Course Title: The History and Systems of Psychology Credits: 3 Contact Person: John Rickards Catalog Copy: PSYC 291W. The History and Systems of Psychology. Prerequisite: PSYC 135 or 133; ENGL 105 or 110 or 111 or 250. W Criteria: 1. The History

  5. Data Conversion in Residue Number System

    E-Print Network [OSTI]

    Zilic, Zeljko

    ;2 Abstract This thesis tackles the problem of data conversion in the Residue Number System (RNS). The RNS has the use of RNS at the applications. In this thesis, we aim at developing efficient schemes for the conversion from the conventional representation to the RNS representation and vice versa. The conventional

  6. Customer Service Specialist Job Number: 54844874

    E-Print Network [OSTI]

    Heller, Barbara

    Customer Service Specialist Job Number: 54844874 Company Name: Baxter International, Inc Job to the customer and/or the sales team including any corrective actions needed to prevent the failure in the future: Medical Information, Distribution Centers, Planning and Deployment, Credit and Collections, Customer

  7. Integrality of L2 -Betti numbers

    E-Print Network [OSTI]

    Schick, Thomas

    Integrality of L2 -Betti numbers Thomas Schick FB Mathematik -- Universit¨at M¨unster Germany Last algebraic question: e-mail: thomas.schick@math.uni-muenster.de www: http://www.math.uni-muenster.de/u/schickt/ Fax: ++49 -251/83 38370 1 #12;2 Thomas Schick 1.2 Definition. Let Z Q be an additive subgroup

  8. Code Number :.............. HEAT TRANSFER QUALIFYING EXAM

    E-Print Network [OSTI]

    Feeny, Brian

    is at 40 °C, estimate the heat transfer per unit length by radiation and convection between the twoCode Number :.............. HEAT TRANSFER QUALIFYING EXAM January 2010 OPEN BOOK (only one book) The heat transfer coefficient c) The length of pipe needed for a 35 °C increase in mean temperature d

  9. Policy Title: Policy Number: Federal Student Aid

    E-Print Network [OSTI]

    Franco, John

    . All such officials shall further distribute the Code to their direct and indirect reports who havePolicy Title: Policy Number: Federal Student Aid Code of Conduct 1.3.3 Category: Administrative Office of the Bursar University of Cincinnati Federal Student Aid Code of Conduct, page 1 of 5 Background

  10. NUMBER: 1530 TITLE: Code of Student Conduct

    E-Print Network [OSTI]

    . For the purposes of this Code, the term "University Official" is inclusive of "Faculty Member" as defined in IV 1530 1 NUMBER: 1530 TITLE: Code of Student Conduct APPROVED: August 27, 1970; Revised June 14, 2012 I. BASIS AND RATIONALE FOR A CODE OF STUDENT CONDUCT Old Dominion University

  11. TEXAS MEMORIAL MUSEUM Speleological Monographs, Number 7

    E-Print Network [OSTI]

    Suarez, Andrew V.

    TEXAS MEMORIAL MUSEUM Speleological Monographs, Number 7 Studies on the CAVE AND ENDOGEAN FAUNA Science Research Laboratory Museum of Texas Tech University, 3301 4th Street Lubbock, Texas 79409 U.S.A. Email: james.cokendolpher@ttu.edu and James R. Reddell Texas Natural Science Center The University

  12. Random Numbers Certified by Bell's Theorem

    E-Print Network [OSTI]

    S. Pironio; A. Acin; S. Massar; A. Boyer de la Giroday; D. N. Matsukevich; P. Maunz; S. Olmschenk; D. Hayes; L. Luo; T. A. Manning; C. Monroe

    2010-10-19

    Randomness is a fundamental feature in nature and a valuable resource for applications ranging from cryptography and gambling to numerical simulation of physical and biological systems. Random numbers, however, are difficult to characterize mathematically, and their generation must rely on an unpredictable physical process. Inaccuracies in the theoretical modelling of such processes or failures of the devices, possibly due to adversarial attacks, limit the reliability of random number generators in ways that are difficult to control and detect. Here, inspired by earlier work on nonlocality based and device independent quantum information processing, we show that the nonlocal correlations of entangled quantum particles can be used to certify the presence of genuine randomness. It is thereby possible to design of a new type of cryptographically secure random number generator which does not require any assumption on the internal working of the devices. This strong form of randomness generation is impossible classically and possible in quantum systems only if certified by a Bell inequality violation. We carry out a proof-of-concept demonstration of this proposal in a system of two entangled atoms separated by approximately 1 meter. The observed Bell inequality violation, featuring near-perfect detection efficiency, guarantees that 42 new random numbers are generated with 99% confidence. Our results lay the groundwork for future device-independent quantum information experiments and for addressing fundamental issues raised by the intrinsic randomness of quantum theory.

  13. MARINE RESEARCH Volume 66, Number 1

    E-Print Network [OSTI]

    Journal of MARINE RESEARCH Volume 66, Number 1 Mean energy balance in the tropical Pacific Ocean requires energy input from the wind. Previous studies estimate that the mean rate of wind work (or wind global energy input into the ocean circulation, it is also critical in maintaining the east-west tilt

  14. MARINE RESEARCH Volume 56, Number 1

    E-Print Network [OSTI]

    Balmforth, Neil

    Journal of MARINE RESEARCH Volume 56, Number 1 Enhanced dispersion of near-inertial waves at San Diego, La Jolla, California, 92093- 0230, U.S.A. Journal of Marine Research, 56, 1­40, 1998 1 #12 the near-inertial energy in the mixed layer returns to backgroundlevels on a time scale of ten to twenty

  15. NUMBER: 1626 TITLE: Information Technology Management

    E-Print Network [OSTI]

    cost of more than $100,000 but less than $1 million. E. University Advisory Council on Technology (UACT technology project estimated to cost $1 million or more or deemed to be mission-critical. VI. Designated1626 - 1 NUMBER: 1626 TITLE: Information Technology Management APPROVED: September 9, 2005 I

  16. Clar number of catacondensed benzenoid hydrocarbons

    E-Print Network [OSTI]

    Klavzar, Sandi

    Clar number of catacondensed benzenoid hydrocarbons Sandi Klavzara, , Petra Zigerta , Ivan Gutmanb sextets in any of the Clar formulae) of a catacondensed benzenoid hydrocarbon: CL is equal to the minimum; Resonance graph; Benzenoid hydrocarbons 1. Introduction Within the theory that was formulated [1, 2

  17. PROCESSING STUDENT RECORDS Generating Permission Numbers

    E-Print Network [OSTI]

    Ottino, Julio M.

    Numbers Find an Existing Value page appears. Enter the desired Term and Subject Area codes in the fields provided or click on the magnifying glass icon to lookup a term or subject (to narrow your search, type to Records and Enrollment, Term Processing, Class Permissions, Class Permissions. The Class Permission

  18. Page 1 of 33 3 STYLE HEADING NUMBER FOR CHP. (USED FOR FIG. NUMBERING)

    E-Print Network [OSTI]

    Baker, Jack W.

    Page 1 of 33 3 STYLE HEADING NUMBER FOR CHP. (USED FOR FIG. NUMBERING) ACCOUNTING FOR GROUND MOTION intensities considered in the original building design. For modern buildings in the western United States for this spectral shape effect is through selection of a set of ground motions that is specific to the building

  19. Call Numbers Explained 1 8/23/2012 Call Numbers Explained

    E-Print Network [OSTI]

    Su, Xiao

    . In the library, books are organized by call number. 3. A call number classifies a book by its subject and tells in the library. 6. The King Library is unusual because it is both a public library and a university library. Because of this, it uses two different classification systems. That is, two different types of call

  20. Sensitivity in risk analyses with uncertain numbers.

    SciTech Connect (OSTI)

    Tucker, W. Troy; Ferson, Scott

    2006-06-01

    Sensitivity analysis is a study of how changes in the inputs to a model influence the results of the model. Many techniques have recently been proposed for use when the model is probabilistic. This report considers the related problem of sensitivity analysis when the model includes uncertain numbers that can involve both aleatory and epistemic uncertainty and the method of calculation is Dempster-Shafer evidence theory or probability bounds analysis. Some traditional methods for sensitivity analysis generalize directly for use with uncertain numbers, but, in some respects, sensitivity analysis for these analyses differs from traditional deterministic or probabilistic sensitivity analyses. A case study of a dike reliability assessment illustrates several methods of sensitivity analysis, including traditional probabilistic assessment, local derivatives, and a ''pinching'' strategy that hypothetically reduces the epistemic uncertainty or aleatory uncertainty, or both, in an input variable to estimate the reduction of uncertainty in the outputs. The prospects for applying the methods to black box models are also considered.

  1. Diophantine Equations and Congruent Number Equation Solutions

    E-Print Network [OSTI]

    Mamuka Meskhishvili

    2015-04-16

    By using pairs of nontrivial rational solutions of congruent number equation $$ C_N:\\;\\;y^2=x^3-N^2x, $$ constructed are pairs of rational right (Pythagorean) triangles with one common side and the other sides equal to the sum and difference of the squares of the same rational numbers. The parametrizations are found for following Diophantine systems: \\begin{align*} (p^2\\pm q^2)^2-a^2 & =\\square_{1,2}\\,, \\\\[0.2cm] c^2-(p^2\\pm q^2)^2 & =\\square_{1,2}\\,, \\\\[0.2cm] a^2+(p^2\\pm q^2)^2 & =\\square_{1,2}\\,, \\\\[0.2cm] (p^2\\pm q^2)^2-a^2 & =(r^2\\pm s^2)^2. \\end{align*}

  2. Cost Center: 9417 Job Number: 5501

    E-Print Network [OSTI]

    Princeton Plasma Physics Laboratory

    Cost Center: 9417 Job Number: 5501 Job Title: Coil Bus Runs Job Manager: Mark Smith Estimate (user input) SCHEDULE FY09$K HOURS (priced at FY09 rates) ` % USER INPUT TASKS AND DESCRIPTIONS USER INPU $1**EM(analysisengr) EA**(Designer) EC**EM(computingEng EC**SB(ComputingTec EC**TB(ComputingTec EE**EM(ElctrEngr) EE**SM(SeniorElectr

  3. Automatic Sets of Rational Numbers Eric Rowland

    E-Print Network [OSTI]

    Rowland, Eric

    Automatic Sets of Rational Numbers Eric Rowland Universit´e de Li`ege D´epartement de Math Abstract The notion of a k-automatic set of integers is well-studied. We develop a new notion -- the k-automatic recall a well-studied concept, that of k-automatic set (see, e.g., [8, 9, 2]): Definition 1. We say

  4. Automatic Sets of Rational Numbers Eric Rowland

    E-Print Network [OSTI]

    Rowland, Eric

    Automatic Sets of Rational Numbers Eric Rowland Universitâ??e de Liâ??ege Dâ??epartement de Math Abstract The notion of a k­automatic set of integers is well­studied. We develop a new notion --- the k­automatic, as follows: [L] k = {[w] k : w # L}. (2) We now recall a well­studied concept, that of k­automatic set (see

  5. Fractal sets of dual topological quantum numbers

    E-Print Network [OSTI]

    Wellington da Cruz

    2004-06-18

    The universality classes of the quantum Hall transitions are considered in terms of fractal sets of dual topological quantum numbers filling factors, labelled by a fractal or Hausdorff dimension defined into the interval $1 < h < 2$ and associated with fractal curves. We show that our approach to the fractional quantum Hall effect-FQHE is free of any empirical formula and this characteristic appears as a crucial insight for our understanding of the FQHE. According to our formulation, the FQHE gets a fractal structure from the connection between the filling factors and the Hausdoff dimension of the quantum paths of particles termed fractons which obey a fractal distribution function associated with a fractal von Neumann entropy. This way, the quantum Hall transitions satisfy some properties related to the Farey sequences of rational numbers and so our theoretical description of the FQHE establishes a connection between physics, fractal geometry and number theory. The FQHE as a convenient physical system for a possible prove of the Riemann hypothesis is suggested.

  6. About the logic of the prime number distribution

    E-Print Network [OSTI]

    Harry K. Hahn

    2008-01-28

    There are two basic number sequences which play a major role in the prime number distribution. The first Number Sequence SQ1 contains all prime numbers of the form 6n+5 and the second Number Sequence SQ2 contains all prime numbers of the form 6n+1. All existing prime numbers seem to be contained in these two number sequences, except of the prime numbers 2 and 3. Riemanns Zeta Function also seems to indicate, that there is a logical connection between the mentioned number sequences and the distribution of prime numbers. This connection is indicated by lines in the diagram of the Zeta Function, which are formed by the points s where the Zeta Function is real. Another key role in the distribution of the prime numbers plays the number 5 and its periodic occurrence in the two number sequences SQ1 and SQ2. All non-prime numbers in SQ1 and SQ2 are caused by recurrences of these two number sequences with increasing wave-lengths in themselves, in a similar fashion as Overtones (harmonics) or Undertones derive from a fundamental frequency. On the contrary prime numbers represent spots in these two basic Number Sequences SQ1 and SQ2 where there is no interference caused by these recurring number sequences. The distribution of the non-prime numbers and prime numbers can be described in a graphical way with a -Wave Model- (or Interference Model) -- see Table 2.

  7. Thermodynamic properties of metal hydride nanostructures

    E-Print Network [OSTI]

    Bérubé, Vincent, Ph. D. Massachusetts Institute of Technology

    2009-01-01

    Hydrogen is considered a good energy carrier candidate for future automotive applications because of its high abundance and its potential role in a carbon-free cycle. The high gravimetric and volumetric storage capacities ...

  8. Activated Aluminum Hydride Hydrogen Storage Compositions - Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room News Publications Traditional Knowledge KiosksAbout AwardedAcronyms This is a quick

  9. Regeneration of Aluminum Hydride - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMassR&D100 Winners * ImpactsandRegarding Confinement Resonances Print When

  10. Regeneration of aluminum hydride - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMassR&D100 Winners * ImpactsandRegarding Confinement Resonances Print When268,288 Site

  11. Metal Hydride Storage Materials | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuelsof EnergyApril 2014 |Department ofMay 2013 MonthlyMessage from New LPOStorage

  12. Halo occupation numbers and galaxy bias

    E-Print Network [OSTI]

    J. A. Peacock; R. E. Smith

    2000-06-30

    We propose a heuristic model that displays the main features of realistic theories for galaxy bias. We show that the low-order clustering statistics of the dark-matter distribution depend almost entirely on the locations and density profiles of dark-matter haloes. A hypothetical galaxy catalogue depends on (i) the efficiency of galaxy formation, as manifested by the halo occupation number -- the number of galaxies brighter than some sample limit contained in a halo of a given mass; (ii) the location of these galaxies within their halo. The first factor is constrained by the empirical luminosity function of groups. For the second factor, we assume that one galaxy marks the halo centre, with any remaining galaxies acting as satellites that trace the halo mass. These simple assumptions amount to a recipe for non-local bias, in which the probability of finding a galaxy is not a simple function of its local mass density. We have applied this prescription to some CDM models of current interest, and find that the predictions are close to the observed galaxy correlations for a flat $\\Omega=0.3$ model ($\\Lambda$CDM), but not for an $\\Omega=1$ model with the same power spectrum ($\\tau$CDM). This is an inevitable consequence of cluster normalization for the power spectra: cluster-scale haloes of given mass have smaller core radii for high $\\Omega$, and hence display enhanced small-scale clustering. Finally, the pairwise velocity dispersion of galaxies in the $\\Lambda$CDM model is lower than that of the mass, allowing cluster-normalized models to yield a realistic Mach number for the peculiar velocity field. This is largely due to the strong variation of galaxy-formation efficiency with halo mass that is required in this model.

  13. Texas Rice, Volume II, Number

    E-Print Network [OSTI]

    2002-01-01

    Texas A&M University System Agricultural Research and Extension Center Beaumont, Texas June 2002 Volume II Number 4 Texas Rice A Tribute to David Wintermann 28th Annual Field Day at Eagle Lake David Wintermann’s active in- volvement... Sugar Refinery near Eagle Lake and in 1909 he, along with other investors, in- corporated Lakeside Irrigation Co. (previously Eagle Lake Ir- rigation Co.) When R.J. died in 1910, he left all his prop- erty to his wife Louise, and $25,000 to each of his...

  14. Texas Rice, Volume VII, Number

    E-Print Network [OSTI]

    2007-01-01

    Texas A&M University System Agricultural Research and Extension Center Beaumont, Texas September 2007 Volume VII Number 7 Texas Rice Nobel Peace Prize Recipient Dr. Norman Borlaug continued on page 4 September of 2003 was a time etched... Tabien, and Dr. Lee Tarpley. Four years ago this month, the Texas A&M Research and Exten- sion Center at Beaumont was hon- ored to welcome one of the most influential people in agriculture. Nobel Peace Prize recipient, Dr. Norman Borlaug, has a long...

  15. Health Code Number (HCN) Development Procedure

    SciTech Connect (OSTI)

    Petrocchi, Rocky; Craig, Douglas K.; Bond, Jayne-Anne; Trott, Donna M.; Yu, Xiao-Ying

    2013-09-01

    This report provides the detailed description of health code numbers (HCNs) and the procedure of how each HCN is assigned. It contains many guidelines and rationales of HCNs. HCNs are used in the chemical mixture methodology (CMM), a method recommended by the department of energy (DOE) for assessing health effects as a result of exposures to airborne aerosols in an emergency. The procedure is a useful tool for proficient HCN code developers. Intense training and quality assurance with qualified HCN developers are required before an individual comprehends the procedure to develop HCNs for DOE.

  16. Compare Activities by Number of Computers

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)DecadeYear Jan Feb Mar Apr May Jun Jul Aug Sep3,118,592Number of Computers

  17. Property:PhoneNumber | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoop Inc Jump to:Newberg,Energy LLCALLETE Inc dEA EIS ReportNumberOfUnitsOwners

  18. Climate Zone Number 4 | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTIONRobertsdale, Alabama (Utility Company) Jump to:NewMinnesota:Protection Action2BZone Number 4 Jump

  19. Climate Zone Number 6 | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTIONRobertsdale, Alabama (Utility Company) Jump to:NewMinnesota:Protection Action2BZone Number 4

  20. Climate Zone Number 7 | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTIONRobertsdale, Alabama (Utility Company) Jump to:NewMinnesota:Protection Action2BZone Number 4Climate

  1. Climate Zone Number 8 | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTIONRobertsdale, Alabama (Utility Company) Jump to:NewMinnesota:Protection Action2BZone Number

  2. Climate Zone Number 2 | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoopButtePower Ventures Jump to: navigation, search Name:Climate Zone Number 2 Jump to:

  3. Climate Zone Number 3 | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoopButtePower Ventures Jump to: navigation, search Name:Climate Zone Number 2 Jump

  4. Climate Zone Number 5 | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoopButtePower Ventures Jump to: navigation, search Name:Climate Zone Number 2

  5. Grammatical morphology as a source of early number word meanings

    E-Print Network [OSTI]

    2013-01-01

    to counting is important to learning number word meanings,hearing number words used outside of these routines—in thewere given two tests of number word knowledge. The Give-a-

  6. Why is number word learning hard? Evidence from bilingual learners

    E-Print Network [OSTI]

    Wagner, Katie; Kimura, Katherine; Cheung, Pierina; Barner, David

    2015-01-01

    s acquisition of the number words and the counting system.as a source of early number word meanings. PNAS, 110(46),the acquisition of number words. Journal of Child Language,

  7. Pure and Applied Mathematics Quarterly Volume 2, Number 2

    E-Print Network [OSTI]

    Waldschmidt, Michel

    Keywords: Periods, transcendental numbers, irrationality, integrals, series, Diophantine approximation, irrationality measures, transcendence measures, measures of algebraic independence, Gamma function, Beta: to decide whether a period is a rational number, an irrational algebraic number or else a tran- scendental

  8. The New Element Californium (Atomic Number 98)

    DOE R&D Accomplishments [OSTI]

    Seaborg, G. T.; Thompson, S. G.; Street, K. Jr.; Ghiroso, A.

    1950-06-19

    Definite identification has been made of an isotope of the element with atomic number 98 through the irradiation of Cm{sup 242} with about 35-Mev helium ions in the Berkeley Crocker Laboratory 60-inch cyclotron. The isotope which has been identified has an observed half-life of about 45 minutes and is thought to have the mass number 244. The observed mode of decay of 98{sup 244} is through the emission of alpha-particles, with energy of about 7.1 Mev, which agrees with predictions. Other considerations involving the systematics of radioactivity in this region indicate that it should also be unstable toward decay by electron capture. The chemical separation and identification of the new element was accomplished through the use of ion exchange adsorption methods employing the resin Dowex-50. The element 98 isotope appears in the eka-dysprosium position on elution curves containing berkelium and curium as reference points--that is, it precedes berkelium and curium off the column in like manner that dysprosium precedes terbium and gadolinium. The experiments so far have revealed only the tripositive oxidation state of eka-dysprosium character and suggest either that higher oxidation states are not stable in aqueous solutions or that the rates of oxidation are slow. The successful identification of so small an amount of an isotope of element 98 was possible only through having made accurate predictions of the chemical and radioactive properties.

  9. Modeling the Number of Ignitions Following an Earthquake: Developing...

    Office of Environmental Management (EM)

    Modeling the Number of Ignitions Following an Earthquake: Developing Prediction Limits for Overdispersed Count Data Modeling the Number of Ignitions Following an Earthquake:...

  10. Navigating the Numbers: Greenhouse Gas Data and International...

    Open Energy Info (EERE)

    Navigating the Numbers: Greenhouse Gas Data and International Climate Policy Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Navigating the Numbers: Greenhouse Gas Data...

  11. The Number of Planets Around Stars

    E-Print Network [OSTI]

    Noam Soker

    1997-06-24

    Based on the large number of elliptical planetary nebulae I argue that about 55 per cent of all progenitors of planetary nebulae have planets around them. The planets spin up the stars when the later evolve along the red giant branch or along the asymptotic giant branch. The arguments, which were presented in several of my earlier works, and are summarized in the paper, suggest that the presence of four gas-giant planets in the solar system is the generality rather than the exception. I here continue and: (1) examine the possibility of detecting signatures of surviving Saturn-like planets inside planetary nebulae, and, (2) propose a model by which the second parameter of the horizontal branch, which determines the distribution of horizontal branch stars in the HR diagram, is the presence of planets. A red giant branch star that interacts with a planet will lose a large fraction of its envelope and will become a blue horizontal branch star.

  12. Comparison of advanced battery technologies for electric vehicles

    SciTech Connect (OSTI)

    Dickinson, B.E.; Lalk, T.R.; Swan, D.H.

    1993-12-31

    Battery technologies of different chemistries, manufacture and geometry were evaluated as candidates for use in Electric Vehicles (EV). The candidate batteries that were evaluated include four single cell and seven multi-cell modules representing four technologies: Lead-Acid, Nickel-Cadmium, Nickel-Metal Hydride and Zinc-Bromide. A standard set of testing procedures for electric vehicle batteries, based on industry accepted testing procedures, and any tests which were specific to individual battery types were used in the evaluations. The batteries were evaluated by conducting performance tests, and by subjecting them to cyclical loading, using a computer controlled charge--discharge cycler, to simulate typical EV driving cycles. Criteria for comparison of batteries were: performance, projected vehicle range, cost, and applicability to various types of EVs. The four battery technologies have individual strengths and weaknesses and each is suited to fill a particular application. None of the batteries tested can fill every EV application.

  13. Nanostructured material for advanced energy storage : magnesium battery cathode development.

    SciTech Connect (OSTI)

    Sigmund, Wolfgang M.; Woan, Karran V.; Bell, Nelson Simmons

    2010-11-01

    Magnesium batteries are alternatives to the use of lithium ion and nickel metal hydride secondary batteries due to magnesium's abundance, safety of operation, and lower toxicity of disposal. The divalency of the magnesium ion and its chemistry poses some difficulties for its general and industrial use. This work developed a continuous and fibrous nanoscale network of the cathode material through the use of electrospinning with the goal of enhancing performance and reactivity of the battery. The system was characterized and preliminary tests were performed on the constructed battery cells. We were successful in building and testing a series of electrochemical systems that demonstrated good cyclability maintaining 60-70% of discharge capacity after more than 50 charge-discharge cycles.

  14. Improving Battery Design with Electro-Thermal Modeling

    SciTech Connect (OSTI)

    Bharathan, D.; Pesaran, A.; Vlahinos, A.; Kim, G.-H.

    2005-01-01

    Operating temperature greatly affects the performance and life of batteries in electric and hybrid vehicles. Increased attention is necessary to battery thermal management. Electrochemical models and finite element analysis tools are available for predicting the thermal performance of batteries, but each has limitations. In this study we describe an electro-thermal finite element approach that predicts the thermal performance of a cell or module with realistic geometry. To illustrate the process, we simulated the thermal performance of two generations of Panasonic prismatic nickel-metal-hydride modules used in the Toyota Prius. The model showed why the new generation of Panasonic modules had better thermal performance. Thermal images from two battery modules under constant current discharge indicate that the model predicts the experimental trend reasonably well.

  15. Bipartite Ramsey Numbers and Zarankiewicz Wayne Goddard 1

    E-Print Network [OSTI]

    Goddard, Wayne

    Bipartite Ramsey Numbers and Zarankiewicz Numbers Wayne Goddard 1 School of Geological and Computer Ramsey number b(m, n) is the least positive integer b such that if the edges of K(b, b) are coloured are used to bound b(m, n) for m, n 6. Key words: Graphs, bipartite Ramsey numbers, Zarankiewicz, bicliques

  16. Degree Ramsey and On-Line Degree Ramsey Numbers

    E-Print Network [OSTI]

    West, Douglas B.

    Degree Ramsey and On-Line Degree Ramsey Numbers Douglas B. West Department of Mathematics;Parameter Ramsey Numbers Def. H G means every 2-coloring of E(H) gives a monochromatic G. Ramsey's Theorem H exists. Ramsey number R(G) = min{n: Kn G}. #12;Parameter Ramsey Numbers Def. H G means every 2

  17. Classifying the phase transition threshold for unordered regressive Ramsey numbers

    E-Print Network [OSTI]

    Weiermann, Andreas

    Classifying the phase transition threshold for unordered regressive Ramsey numbers Florian the notion of unordered regressive Ramsey numbers or unordered Kanamori-McAloon numbers. We show that these are of Ackermannian growth rate. For a given number- theoretic function f we consider unordered f-regressive Ramsey

  18. Degree Ramsey and On-Line Degree Ramsey Numbers

    E-Print Network [OSTI]

    West, Douglas B.

    Degree Ramsey and On-Line Degree Ramsey Numbers Douglas B. West Department of Mathematics Stocker #12;Parameter Ramsey Numbers Def. H G means every 2-coloring of E(H) gives a monochromatic G. Ramsey's Theorem H exists. Ramsey number R(G) = min{n: Kn G}. #12;Parameter Ramsey Numbers Def. H G

  19. AERODYNAMICS AND DESIGN FOR ULTRA-LOW REYNOLDS NUMBER FLIGHT

    E-Print Network [OSTI]

    Stanford University

    AERODYNAMICS AND DESIGN FOR ULTRA-LOW REYNOLDS NUMBER FLIGHT A DISSERTATION SUBMITTED at Reynolds numbers below 10,000, here termed ultra-low Reynolds numbers. The effects of airfoil geometry at ultra-low Reynolds numbers. To further explore this design space, the flow solver has been coupled

  20. Report Number R99/0497 Report Title

    E-Print Network [OSTI]

    Marsh, Helene

    Report Number R99/0497 Report Title IMPROVING THE ACCURACY OF AERIAL SURVEYS FOR DUGONGS. Report Date December 2004 #12;AFMA Report Number R99/0497 2 IMPROVING THE ACCURACY OF AERIAL SURVEYS, Raleigh, NC 27695-8203, USA AFMA Project Number R 99/0497 December 2004 #12;AFMA Report Number R99/0497 3

  1. Scaling an RNS number using the core function Neil Burgess,

    E-Print Network [OSTI]

    Oklobdzija, Vojin G.

    Scaling an RNS number using the core function Neil Burgess, Cardiff School of Engineering, Cardiff for extracting the core of a Residue Number System (RNS) number within the RNS, this affording a new method for scaling RNS numbers. Suppose an RNS comprises a set of co-prime moduli, mi, with mi = M. This paper

  2. 90 Los Alamos Science Number 23 1995 Number 23 1995 Los Alamos Science 91

    E-Print Network [OSTI]

    Massey, Thomas N.

    in the photo at left graphically portray the rate of can- cer mortality in the United States. On average, one. The purple cir- cles represent excess cancer deaths above the normal rate. The job of the radiation epidemiologist is to determine the number of ex- cess cancer deaths among a group that has been exposed

  3. MIXMAX random number generator. Generalised parameters

    E-Print Network [OSTI]

    Savvidy, Konstantin

    2015-01-01

    We are exploring the parameter space of the MIXMAX random number generator, which is based on Kolmogorov-Anosov C-system defined on a torus. For a two-parameter family of C-system operators A(N,s), parametrised by the integers N and s, we found new larger values of N. One can deduce from this data that the entropy and the period are sharply increasing with N. For all of these parameters, the sequence passes all tests in the BigCrush suite. For the largest of them, N=44851, the period approaches million digits. The generator with N=256 and s=487013230256099064 has the best combination of speed, reasonable size of the state and availability for implementing the parallelisation and is currently the default generator in the ROOT software package at CERN. A three-parameter generator A(N,s,m) of the MIXMX family of generators is also presented, and it provides high quality statistical properties for small values of N.

  4. The Differential Approach to Superlative Index Number Theory

    E-Print Network [OSTI]

    Barnett, William A.; Choi, Ki-Hong; Sinclair, Tara M.

    2003-09-01

    Diewert’s “superlative” index numbers, defined to be exact for second-order aggregator functions, unify index number theory with aggregation theory but have been difficult to identify. We present a new approach to finding ...

  5. ADDITIVITY PROPERTIES OF GENERALIZED BRIDGE NUMBERS OF KNOTS

    E-Print Network [OSTI]

    . Later, Helmut Doll generalized the the notion of bridge number of a knot. Schubert's notion of bridge splitting of S 3 , whereas Doll's more general notion of bridge number can be formulated in terms of a nice

  6. Grammatical morphology as a source of early number word meanings

    E-Print Network [OSTI]

    Almoammer, Alhanouf

    How does cross-linguistic variation in linguistic structure affect children’s acquisition of early number word meanings? We tested this question by investigating number word learning in two unrelated languages that feature ...

  7. Numbers and Arithmetic: Neither Hardwired Nor Out There

    E-Print Network [OSTI]

    Nuńez, Rafael

    Numbers and Arithmetic: Neither Hardwired Nor Out There Rafael N ´u ~nez Department of Cognitive that number concepts and arithmetic are neither hard- wired in the brain, nor do they exist out

  8. Stern-Gerlach Experiments and Complex Numbers in Quantum Physics

    E-Print Network [OSTI]

    S. Sivakumar

    2012-07-09

    It is often stated that complex numbers are essential in quantum theory. In this article, the need for complex numbers in quantum theory is motivated using the results of tandem Stern-Gerlach experiments

  9. Certification of Taxpayer Identification Number for Individuals Please check one

    E-Print Network [OSTI]

    Zallen, Richard

    Substitute Form W-9 Certification of Taxpayer Identification Number for Individuals Please check: ________________________ Middle: _____________________ Last: _______________________________ 2. U.S. taxpayer identification statements are true, correct, and complete and that: 1. The number shown on this form is my correct taxpayer

  10. ORISE: Report shows number of health physics degrees for 2010

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    report shows number of health physics degrees increased for graduates, decreased for undergraduates in 2010 Decreased number of B.S. degrees remains higher than levels in the early...

  11. On the size-Ramsey number of hypergraphs Andrzej Dudek

    E-Print Network [OSTI]

    Mubayi, Dhruv

    On the size-Ramsey number of hypergraphs Andrzej Dudek Steven La Fleur Dhruv Mubayi Vojtech R¨odl§ March 20, 2015 Abstract The size-Ramsey number of a graph G is the minimum number of edges in a graph H such that every 2-edge-coloring of H yields a monochromatic copy of G. Size-Ramsey numbers of graphs have been

  12. MULTI-DEGREE BOUNDS ON THE BETTI NUMBERS OF REAL ...

    E-Print Network [OSTI]

    2015-07-28

    Jul 28, 2015 ... Multidegree bounds, Betti numbers, Smith inequalities, semi-algebraic sets, polynomial partitioning, incidence problems. Basu was partially ...

  13. Experiment Number 19 The Transmission of -Radiation Through Matter

    E-Print Network [OSTI]

    is the Avogadro's number is the density so that the probability of a certain electron being scattered is very

  14. Radio Number for Trees Daphne Der-Fen Liu

    E-Print Network [OSTI]

    Liu, Daphne Der-Fen

    Radio Number for Trees Daphne Der-Fen Liu Department of Mathematics California State University be a connected graph with diameter diam(G). The radio number for G, denoted by rn(G), is the smallest integer k bound for the radio number of trees, and characterize the trees achiev- ing this bound. Moreover, we

  15. Small Ramsey Numbers Stanisl/aw P. Radziszowski

    E-Print Network [OSTI]

    Radziszowski, Stanislaw P.

    Small Ramsey Numbers Stanisl/aw P. Radziszowski Department of Computer Science Rochester Institute Ramsey numbers, where the avoided graphs are complete or complete without one edge. Many results per behavior of Ramsey numbers, but rather we concentrate on their specific values. Mathematical Reviews

  16. Constructive Lower Bounds on Classical Multicolor Ramsey Numbers

    E-Print Network [OSTI]

    Radziszowski, Stanislaw P.

    Constructive Lower Bounds on Classical Multicolor Ramsey Numbers Xu Xiaodong and Xie Zheng bounds for classical multicolor Ramsey numbers, first by giving a short overview of past results-diagonal multicolor Ramsey numbers. In particular, we improve several lower bounds for Rk(4) and Rk(5) for some small

  17. Constructive Lower Bounds on Classical Multicolor Ramsey Numbers

    E-Print Network [OSTI]

    Radziszowski, Stanislaw P.

    Constructive Lower Bounds on Classical Multicolor Ramsey Numbers Xu Xiaodong and Xie Zheng studies lower bounds for classical multicolor Ramsey numbers, #12;rst by giving a short overview of past diagonal and o#11;-diagonal multicolor Ramsey numbers. In particular, we improve several lower bounds for R

  18. Ramsey Numbers for Triangles Almost-Complete Graphs

    E-Print Network [OSTI]

    Radziszowski, Stanislaw P.

    Ramsey Numbers for Triangles versus Almost-Complete Graphs To the fond memory of Paul Erd on the corresponding Ramsey number, R(K 3 ; K 10 e) #20; 38. The new lower bound of 37 for this number is established by one the best previously known lower and upper bounds. We also give the bounds for the next Ramsey

  19. Bounds for Ramsey numbers in multipartite Eugene Heinz Stipp

    E-Print Network [OSTI]

    van Vuuren, Jan H.

    Bounds for Ramsey numbers in multipartite graphs Eugene Heinz Stipp Submitted in partial fulfilment-Committee B. #12;iv ­ ABSTRACT ­ The notion of a classical graph theoretic Ramsey number is generalized as in the standard definition. Some small multipartite Ramsey numbers are found, while upper- and lower bounds

  20. New Computational Upper Bounds for Ramsey Numbers R(3, k)

    E-Print Network [OSTI]

    Radziszowski, Stanislaw P.

    New Computational Upper Bounds for Ramsey Numbers R(3, k) Jan Goedgebeur Department of Applied computational techniques we derive six new upper bounds on the classical two- color Ramsey numbers: R(3, 10) 42) 42. Keywords: Ramsey number; upper bound; computation the electronic journal of combinatorics XX

  1. Shannon Capacity and Ramsey Numbers from Product of Graphs

    E-Print Network [OSTI]

    Radziszowski, Stanislaw P.

    Bounds on Shannon Capacity and Ramsey Numbers from Product of Graphs Xiaodong Xu Guangxi Academy Abstract In this paper we study Shannon capacity of channels in the context of classical Ramsey numbers. We by Abbott and Song and thus establish new lower bounds for a special type of multicolor Ramsey numbers. We

  2. Bounds for Ramsey numbers in multipartite Eugene Heinz Stipp

    E-Print Network [OSTI]

    van Vuuren, Jan H.

    Bounds for Ramsey numbers in multipartite graphs Eugene Heinz Stipp Submitted in partial ful#12 theoretic Ramsey number is generalized by assuming that both the original graph whose edges are arbitrarily of complete graphs as in the standard de#12;nition. Some small multipartite Ramsey numbers are found, while

  3. Degree Ramsey Number of Cycles Douglas B. West

    E-Print Network [OSTI]

    West, Douglas B.

    Degree Ramsey Number of Cycles Douglas B. West Department of Mathematics University of Illinois Jiang, Bill Kinnersley, and Kevin Milans #12;Parameter Ramsey Numbers Def. H G means every 2-coloring of E(H) gives a monochromatic G. Ramsey's Theorem H exists. Ramsey number R(G) = min{n: Kn G}. #12

  4. Comparative estimation of the reproduction number for pandemic

    E-Print Network [OSTI]

    Chowell, Gerardo

    -8523, Japan The reproduction number, R, defined as the average number of secondary cases generated notifications during the autumn wave of the influenza pandemic (Spanish flu) in the city of San Francisco.07, 2.65) for the entire autumn wave. We conclude that the reproduction number for pandemic influenza

  5. Compact floating-gate true random number generator

    E-Print Network [OSTI]

    Maryland at College Park, University of

    Compact floating-gate true random number generator P. Xu, Y.L. Wong, T.K. Horiuchi and P.A. Abshire A compact true random number generator (RNG) integrated circuit with adjustable probability is presented. Introduction: Random number generation is indispensable in crypto- graphy, scientific computing and stochastic

  6. SPICE Simulation of a "Provably Secure" True Random Number Generator

    E-Print Network [OSTI]

    International Association for Cryptologic Research (IACR)

    SPICE Simulation of a "Provably Secure" True Random Number Generator Markus Dichtl, Bernd Meyer True Random Number Generator with Built-in Tolerance to Active Attacks", B. Sunar, W. Mar- tin, and D. Stinson propose a design for a true random number generator. Using SPICE simulation we study the behaviour

  7. Number of Jacobi quartic curves over finite Rongquan Feng1

    E-Print Network [OSTI]

    International Association for Cryptologic Research (IACR)

    Number of Jacobi quartic curves over finite fields Rongquan Feng1 , Hongfeng Wu2 1 LMAM, School@gmail.com Abstract In this paper the number of Fq-isomorphism classes of Jacobi quar- tic curves, i.e., the number of Jacobi quartic curves with distinct j- invariants, over finite field Fq is enumerated. Keywords: Elliptic

  8. TRANSCENDENCE OF THE GAUSSIAN LIOUVILLE NUMBER AND RELATIVES

    E-Print Network [OSTI]

    Borwein, Peter

    TRANSCENDENCE OF THE GAUSSIAN LIOUVILLE NUMBER AND RELATIVES PETER BORWEIN AND MICHAEL COONS to that of Dekking's proof of the transcendence of the Thue­Morse number [7] as well as a theorem of Mahler's [16 is that l is irrational. Theorem 1. If l is the Liouville number, then l / Q. Proof. See proof

  9. MU student numberVISITING STUDENT APPLICATION UNIVERSITY OF MISSOURI

    E-Print Network [OSTI]

    Taylor, Jerry

    (area code) Telephone number (area code) Cellphone number (area code) Fax number (if available) Student officials, and the completed application is to be sent to the Director of Admissions, University of Missouri, 230 Jesse Hall, Columbia, MO 65211-1300. Because this certification is in lieu of an official

  10. Louisiana Natural Gas Number of Gas and Gas Condensate Wells (Number of

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963Residential Consumers (Number of33Cubic Foot)Year Jan FebYear

  11. U.S. Natural Gas Number of Commercial Consumers - Sales (Number of

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)Decade Year-0Proved ReservesData2009 2010Year Jan Feb Mar Apr May Jun (Number

  12. U.S. Natural Gas Number of Industrial Consumers - Sales (Number of

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)Decade Year-0Proved ReservesData2009 2010Year Jan Feb Mar Apr May (Number

  13. U.S. Natural Gas Number of Residential Consumers - Sales (Number of

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)Decade Year-0Proved ReservesData2009 2010Year Jan Feb Mar Apr May (Number

  14. U.S. Natural Gas Number of Industrial Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home PageMonthly","10/2015"4,"Ames5 Tables July 1996 Energy Information Administration Office of Coal,Demand Module of the NationalSalesof(MillionIndustrial Consumers (Number of

  15. U.S. Natural Gas Number of Residential Consumers (Number of Elements)

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home PageMonthly","10/2015"4,"Ames5 Tables July 1996 Energy Information Administration Office of Coal,Demand Module of the NationalSalesof(MillionIndustrial Consumers (Number

  16. Grant Title: INITIATIVE FOR MAXIMIZING STUDENT DEVELOPMENT (IMSD) (R25) Funding Opportunity Number: PAR-13-082. CFDA Number(s): 93.859.

    E-Print Network [OSTI]

    Farritor, Shane

    : PAR-13-082. CFDA Number(s): 93.859. Agency/Department: National Institutes of Health (NIH), National skills, communication skills, time-management, group learning opportunities, independent library or bench career choices with appropriate role models. The proposed research education prog

  17. Commercial viability of hybrid vehicles : best household use and cross national considerations.

    SciTech Connect (OSTI)

    Santini, D. J.; Vyas, A. D.

    1999-07-16

    Japanese automakers have introduced hybrid passenger cars in Japan and will soon do so in the US. In this paper, we report how we used early computer simulation model results to compare the commercial viability of a hypothetical near-term (next decade) hybrid mid-size passenger car configuration under varying fuel price and driving patterns. The fuel prices and driving patterns evaluated are designed to span likely values for major OECD nations. Two types of models are used. One allows the ''design'' of a hybrid to a specified set of performance requirements and the prediction of fuel economy under a number of possible driving patterns (called driving cycles). Another provides an estimate of the incremental cost of the hybrid in comparison to a comparably performing conventional vehicle. In this paper, the models are applied to predict the NPV cost of conventional gasoline-fueled vehicles vs. parallel hybrid vehicles. The parallel hybrids are assumed to (1) be produced at high volume, (2) use nickel metal hydride battery packs, and (3) have high-strength steel bodies. The conventional vehicle also is assumed to have a high-strength steel body. The simulated vehicles are held constant in many respects, including 0-60 time, engine type, aerodynamic drag coefficient, tire rolling resistance, and frontal area. The hybrids analyzed use the minimum size battery pack and motor to meet specified 0-60 times. A key characteristic affecting commercial viability is noted and quantified: that hybrids achieve the most pronounced fuel economy increase (best use) in slow, average-speed, stop-and-go driving, but when households consistently drive these vehicles under these conditions, they tend to travel fewer miles than average vehicles. We find that hours driven is a more valuable measure than miles. Estimates are developed concerning hours of use of household vehicles versus driving cycle, and the pattern of minimum NPV incremental cost (or benefit) of selecting the hybrid over the conventional vehicle at various fuel prices is illustrated. These results are based on data from various OECD motions on fuel price, annual miles of travel per vehicle, and driving cycles assumed to be applicable in those nations. Scatter in results plotted as a function of average speed, related to details of driving cycles and the vehicles selected for analysis, is discussed.

  18. OAK RIDGE NATIONAL LABORATORY U. S. DEPARTMENT OF ENERGY

    E-Print Network [OSTI]

    Deiterding, Ralf

    Laboratory Oak Ridge, Tennessee SIAM Conference on Computational Science and Engineering Costa Mesa version with extended higher-order capabilities and large number of Riemann solvers - Hydrid WENO

  19. Export support of renewable energy industries, grant number 1, deliverable number 3. Final report

    SciTech Connect (OSTI)

    1998-01-14

    The United States Export Council for Renewable Energy (US/ECRE), a consortium of six industry associations, promotes the interests of the renewable energy and energy efficiency member companies which provide goods and services in biomass, geothermal, hydropower, passive solar, photovoltaics, solar thermal, wind, wood energy, and energy efficiency technologies. US/ECRE`s mission is to catalyze export markets for renewable energy and energy efficiency technologies worldwide. Under this grant, US/ECRE has conducted a number of in-house activities, as well as to manage activities by member trade associations, affiliate organizations and non-member contractors and consultants. The purpose of this document is to report on grant coordination and effectiveness.

  20. Export support of renewable energy industries. Task number 1, deliverable number 3. Final report

    SciTech Connect (OSTI)

    1998-01-14

    The United States Export Council for Renewable Energy (US/ECRE), a consortium of six industry associations, promotes the interests of the renewable energy and energy efficiency member companies which provide goods and services in biomass, geothermal, hydropower, passive solar, photovoltaics, solar thermal, wind, wood energy, and energy efficiency technologies. US/ECRE`s mission is to catalyze export markets for renewable energy and energy efficiency technologies worldwide. Under this grant, US/ECRE has conducted a number of in-house activities, as well as to manage activities by member trade associations, affiliate organizations and non-member contractors and consultants. The purpose of this document is to report on task coordination and effectiveness.

  1. Ramsey number of a connected triangle matching Andras Gyarfas

    E-Print Network [OSTI]

    Sarkozy, Gabor

    Ramsey number of a connected triangle matching Andr´as Gy´arf´as Alfr´ed R´enyi Institute Ramsey number of a connected triangle match- ing c(nK3) which is a graph with n vertex disjoint triangles matching, R(nK3, nK3) = 5n. The motivation is to determine the Ramsey number R(C2 n, C2 n) of the square

  2. MULTI-DEGREE BOUNDS ON THE BETTI NUMBERS OF REAL ...

    E-Print Network [OSTI]

    2015-07-28

    Jul 28, 2015 ... problem posed in their paper – on extending their bounds on the number of connected ... sets, polynomial partitioning, incidence problems.

  3. The Chern-Simons Number as a Dynamical Variable

    E-Print Network [OSTI]

    Tye, S -H Henry

    2016-01-01

    In the standard electroweak theory that describes nature, the Chern-Simons number associated with the vacua as well as the unstable sphaleron solutions play a crucial role in the baryon number violating processes. We recall why the Chern-Simons number should be generalized from a set of discrete values to a dynamical (quantum) variable. Via the construction of an appropriate Hopf invariant and the winding number, we discuss how the geometric information in the gauge fields is also captured in the Higgs field. We then discuss the choice of the Hopf variable in relation to the Chern-Simons variable.

  4. Request for Proposals Number RHB-5-52483

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    9 National Renewable Energy Laboratory Managed and Operated by the Alliance for Sustainable Energy, LLC Request for Proposals Number RHB-5-52483 "Subsurface Utility Engineering...

  5. Chicago Office NEPA Tracking Number U. S. DEPARTMENT OF ENERGY

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CH F 560-ACQ (1105) Previous editions are obsolete. Chicago Office NEPA Tracking Number U. S. DEPARTMENT OF ENERGY OFFICE OF SCIENCE -- CHICAGO OFFICE NATIONAL ENVIRONMENTAL...

  6. Reducing the Particulate Emission Numbers in DI Gasoline Engines...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Emission Numbers in DI Gasoline Engines Formation of droplets was minimized through optimization of fuel vaporization and distribution avoiding airfuel zones richer than...

  7. bounding the number of stable homotopy types of a parametrized ...

    E-Print Network [OSTI]

    He obtained a full topological classification of such varieties making ... Wall obtains as a consequence of his classification theorem, that the number of different ...

  8. A multichain polymer slip-spring model with fluctuating number...

    Office of Scientific and Technical Information (OSTI)

    A multichain polymer slip-spring model with fluctuating number of entanglements for linear and nonlinear rheology Citation Details In-Document Search This content will become...

  9. Fleet Management Procedure Policy number 001 -September 2013

    E-Print Network [OSTI]

    Thompson, Michael

    Fleet Management Procedure Policy number 001 - September 2013 Complete Policy Title: Facility Services Fleet and Non- Fleet Maintenance/Operations Policy Number: 001 Approved by: VP Administration Date program that will extend the safety, quality and longevity of all vehicles and equipment owned

  10. The distribution of prime numbers on the square root spiral

    E-Print Network [OSTI]

    Harry K. Hahn; Robert Sachs

    2008-01-09

    Prime Numbers clearly accumulate on defined spiral graphs,which run through the Square Root Spiral. These spiral graphs can be assigned to different spiral-systems, in which all spiral-graphs have the same direction of rotation and the same -second difference- between the numbers, which lie on these spiral-graphs. A mathematical analysis shows, that these spiral graphs are caused exclusively by quadratic polynomials. For example the well known Euler Polynomial x2+x+41 appears on the Square Root Spiral in the form of three spiral-graphs, which are defined by three different quadratic polynomials. All natural numbers,divisible by a certain prime factor, also lie on defined spiral graphs on the Square Root Spiral (or Spiral of Theodorus, or Wurzelspirale). And the Square Numbers 4, 9, 16, 25, 36 even form a highly three-symmetrical system of three spiral graphs, which divides the square root spiral into three equal areas. Fibonacci number sequences also play a part in the structure of the Square Root Spiral. With the help of the Number-Spiral, described by Mr. Robert Sachs, a comparison can be drawn between the Square Root Spiral and the Ulam Spiral. The shown sections of his study of the number spiral contain diagrams, which are related to my analysis results, especially in regards to the distribution of prime numbers.

  11. Brandeis University Environmental Studies current number of majors

    E-Print Network [OSTI]

    Hickey, Timothy J.

    and government agencies to tackle environmental health problems facing primarily low-income residents in areasBrandeis University Environmental Studies fast facts current number of majors and minors: 61 Number- engaged learning Popular second majors: American studies, biology, international and global studies

  12. Heating Season Has Ended An Update On The Numbers

    E-Print Network [OSTI]

    . An Update On The Numbers The attached graphics illustrate electricity consumption over a number of years. As a reference point, electricity comprises 2/3rds of our total fuel costs. Consumption will vary from year)/May and September/October time-frames represent seasonal transition and an opportunity to save on fuel consumption

  13. Submitted to Operations Research manuscript (Please, provide the manuscript number!)

    E-Print Network [OSTI]

    Powell, Warren B.

    , geothermal and biomass, Renewable Portfolio Standards (RPSs) have been implemented in a number of states attributed to the artificial vertical demand curve imposed by regulations. A number of papers (such as Felder arising from a vertical demand curve (or a cliff policy) such as an uncompetitive market, volatile

  14. 142 Los Alamos Science Number 29 2005 Direct Numerical

    E-Print Network [OSTI]

    Kurien, Susan

    142 Los Alamos Science Number 29 2005 Direct Numerical Simulations of Turbulence Data Generation visualization tools. Los Alamos scientists have been able to simulate flows of Reynolds numbers up to 105 subdomain of the 20483 turbulence simulation performed on the ASC Q machine at Los Alamos. The ASC Q machine

  15. On Pattern Ramsey Numbers of Graphs Robert E. Jamison

    E-Print Network [OSTI]

    West, Douglas B.

    On Pattern Ramsey Numbers of Graphs Robert E. Jamison Mathematical Sciences Clemson University is a Ramsey family if there is some integer N such that every edge- coloring of KN has a copy of some pattern in F. The smallest such N is the (pattern) Ramsey number R(F) of F. The classical Canonical Ramsey

  16. Computing Hypergraph Ramsey Numbers by Using Quantum Circuit

    E-Print Network [OSTI]

    Ri Qu; Zong-shang Li; Juan Wang; Yan-ru Bao; Xiao-chun Cao

    2012-10-12

    Gaitan and Clark [Phys. Rev. Lett. 108, 010501 (2012)] have recently shown a quantum algorithm for the computation of the Ramsey numbers using adiabatic quantum evolution. We present a quantum algorithm to compute the two-color Ramsey numbers for r-uniform hypergraphs by using the quantum counting circuit.

  17. Planar Ramsey Numbers for Small Graphs Andrzej Dudek

    E-Print Network [OSTI]

    Ruciñski, Andrzej

    Planar Ramsey Numbers for Small Graphs Andrzej Dudek Department of Mathematics and Computer Science Adam Mickiewicz University Pozna´n, Poland Abstract Given two graphs G1 and G2, the planar Ramsey a copy of G1 or its complement contains a copy of G2. So far, the planar Ramsey numbers have been deter

  18. On Pattern Ramsey Numbers of Graphs Robert E. Jamison

    E-Print Network [OSTI]

    West, Douglas B.

    On Pattern Ramsey Numbers of Graphs Robert E. Jamison Mathematical Sciences Clemson University is a Ramsey family if there is some integer N such that every edge- coloring of KN has a copy of some pattern in F . The smallest such N is the (pattern) Ramsey number R(F ) of F . The classical Canonical Ramsey

  19. New Computational Upper Bounds for Ramsey Numbers R(3, k)

    E-Print Network [OSTI]

    Radziszowski, Stanislaw P.

    New Computational Upper Bounds for Ramsey Numbers R(3, k) Jan Goedgebeur Department of Applied@cs.rit.edu Kolloquium ĂĽber Kombinatorik Berlin, November 16, 2012 1/25 Avoiding Triangles in Ramsey Graphs or independence in triangle-free graphs 1 Ramsey Numbers R(3, k) Asymptotics Some background and history Lower

  20. More Constructive Lower Bounds on Classical Ramsey Numbers

    E-Print Network [OSTI]

    Radziszowski, Stanislaw P.

    More Constructive Lower Bounds on Classical Ramsey Numbers Xiaodong Xu Guangxi Academy of Sciences Abstract. We present several new constructive lower bounds for classical Ramsey numbers. In particular that for all integers k, l, with k 5 and l 3, the connectivity of any Ramsey-critical (k, l

  1. Unsteady Aerodynamic Models for Agile Flight at Low Reynolds Numbers

    E-Print Network [OSTI]

    Rowley, Clarence W.

    for Wagner's and Theodorsen's models, making them compatible with modern control-system analysis. A number thanks are to my advisor, Clancy Rowley, who has been both a role model and a source of encouragementUnsteady Aerodynamic Models for Agile Flight at Low Reynolds Numbers Steven L. Brunton

  2. Page 1 of 7 (page number not for citation purposes)

    E-Print Network [OSTI]

    Page 1 of 7 (page number not for citation purposes) Chemistry Central Journal Open Access operations during large-scale virtual screening jobs. We also implemented an algorithm to output docked in a number of therapeutic programs at the lead discovery stage [1]. Published: 8 September 2008 Chemistry

  3. COMPLETENESS NUMBER OF FAMILIES OF SUBSETS OF CONVERGENCE SPACES

    E-Print Network [OSTI]

    Dolecki, Szymon

    COMPLETENESS NUMBER OF FAMILIES OF SUBSETS OF CONVERGENCE SPACES SZYMON DOLECKI In honor, triquotient maps and extensions of the Choquet active boundary theorem. The completeness number of a family in a convergence space is the least cardinality of collections of covers for which the family becomes complete. 0

  4. Reducing the Cost of Generating APH-distributed Random Numbers

    E-Print Network [OSTI]

    Telek, Miklós

    Reducing the Cost of Generating APH-distributed Random Numbers Philipp Reinecke1 , Mikl´os Telek2 from PH distributions and propose two algorithms for reducing the cost associated with generating representation that minimises the cost associated with generating random numbers. In this paper we study

  5. Effective Reverse Conversion in Residue Number System Processors

    E-Print Network [OSTI]

    propose effective Residue Number System (RNS) to Weighted Number System conversion techniques with k being the num- ber of moduli. First, we introduce an RNS to MRC technique, which ad- dresses in an RNS to MRC with an asymptotic complexity, in terms of arithmetic operations, in the order of O

  6. Modular Arithmetic Implementation with the Residue Number System (RNS)

    E-Print Network [OSTI]

    Sousa, Leonel

    Modular Arithmetic Implementation with the Residue Number System (RNS) Samuel Antăo and Leonel are the addition/subtraction, multiplication and reduction as well as the conversion of Residue Number System (RNS discussed in the following. 1 RNS Forward/Reverse Conversions Forward conversion corresponds

  7. THEORETICAL CRYPTANALYSIS OF THE KLIMOVSHAMIR NUMBER GENERATOR TF1

    E-Print Network [OSTI]

    International Association for Cryptologic Research (IACR)

    THEORETICAL CRYPTANALYSIS OF THE KLIMOV­SHAMIR NUMBER GENERATOR TF­1 BOAZ TSABAN Abstract generator TF­1 was introduced in [2] and is based on the methods developed in [1] and references therein. This is an iterative pseudorandom number generator. Its internal state consists of 4 words a, b, c, d, of size w bits

  8. Analysis of the Linux Random Number Generator Zvi Gutterman

    E-Print Network [OSTI]

    International Association for Cryptologic Research (IACR)

    Analysis of the Linux Random Number Generator Zvi Gutterman Safend and The Hebrew University Abstract Linux is the most popular open source project. The Linux random number generator is part of the kernel of all Linux distributions and is based on generating randomness from entropy of operating system

  9. Jacobi forms over totally real number elds Howard Skogman

    E-Print Network [OSTI]

    Skogman, Howard

    Jacobi forms over totally real number #12;elds Howard Skogman 0 2000 Mathematics Subject Classi#12;cation: 11F50 1 #12; Abstract We de#12;ne Jacobi forms over a totally real algebraic number #12;eld K upper half space respectively. Then symplectic modular forms are created and Jacobi forms arise

  10. SHIFTED JACOBI POLYNOMIALS AND DELANNOY NUMBERS GABOR HETYEI

    E-Print Network [OSTI]

    Jiang, Jiancheng

    SHIFTED JACOBI POLYNOMIALS AND DELANNOY NUMBERS G´ABOR HETYEI `A la m´emoire de Pierre Leroux Abstract. We express a weigthed generalization of the Delannoy numbers in terms of shifted Jacobi Jacobi polynomials. Another specializa- tion provides a weighted lattice path enumeration model

  11. Jacobi Forms over Imaginary Quadratic Number Fields Howard Skogman

    E-Print Network [OSTI]

    Skogman, Howard

    Jacobi Forms over Imaginary Quadratic Number Fields Howard Skogman University of California, San Diego La Jolla, CA 1 #12; Abstract We de#12;ne Jacobi Forms over an imaginary quadratic number #12;eld K half space respectively. We then create symplectic modular forms and create Jacobi forms by taking

  12. True Random Number Generators Secure in a Changing Environment

    E-Print Network [OSTI]

    Shaltiel, Ronen

    , which is applied to the high­entropy source in order to obtain an output string that is shorterTrue Random Number Generators Secure in a Changing Environment Boaz Barak, Ronen Shaltiel, and Eran, ISRAEL Email: {boaz,ronens,tromer}@wisdom.weizmann.ac.il Abstract. A true random number generator (TRNG

  13. Combinatorial Number Theory in China Zhi-Wei Sun

    E-Print Network [OSTI]

    Sun, Zhi-Wei

    Combinatorial Number Theory in China Zhi-Wei Sun Nanjing University Nanjing 210093, P. R. China as number theorists. Zhi-Wei Sun's School: Study covers of the integers or groups, restricted sumsets via Combinatorial Nullstellensatz, and various combinatorial congruences. Remark. Sun and his students view

  14. Convexity in partial cubes: the hull number Marie Albenque1

    E-Print Network [OSTI]

    Felsner, Stefan

    that the combinatorial optimization problem of de- termining the hull number of a partial cube is NP-complete. This makesConvexity in partial cubes: the hull number Marie Albenque1 and Kolja Knauer2 1 LIX UMR 7161 partial cubes the minimal graph class for which NP-completeness of this problem is known and improves some

  15. A Nonempirical Test on the Weight of Pseudorandom Number Generators

    E-Print Network [OSTI]

    Matsumoto, Makoto

    . In middle 80's, physicists began to find the failure of these generators in simulations of physical modelsA Nonempirical Test on the Weight of Pseudorandom Number Generators Makoto Matsumoto1 and Takuji introduce a theoretical test, named weight discrepancy test, on pseu- dorandom number generators. This test

  16. REGULAR POLES AND -NUMBERS IN THE THEORY OF HOLOMORPHIC SEMIGROUPS

    E-Print Network [OSTI]

    Bracci, Filippo

    REGULAR POLES AND -NUMBERS IN THE THEORY OF HOLOMORPHIC SEMIGROUPS FILIPPO BRACCI, MANUEL D. CONTRERAS, AND SANTIAGO D´IAZ-MADRIGAL Abstract. We introduce the notion of regular (boundary) poles- ular poles in terms of -points (i.e. pre-images of values with positive Carleson-Makarov -numbers

  17. New Paradigm for Baryon and Lepton Number Violation

    E-Print Network [OSTI]

    Pavel Fileviez Perez

    2015-08-17

    The possible discovery of proton decay, neutron-antineutron oscillation, neutrinoless beta decay in low energy experiments, and exotic signals related to the violation of the baryon and lepton numbers at collider experiments will change our understanding of the conservation of fundamental symmetries in nature. In this review we discuss the rare processes due to the existence of baryon and lepton number violating interactions. The simplest grand unified theories and the neutrino mass generation mechanisms are discussed. The theories where the baryon and lepton numbers are defined as local gauge symmetries spontaneously broken at the low scale are discussed in detail. The simplest supersymmetric gauge theory which predicts the existence of lepton number violating processes at the low scale is investigated. The main goal of this review is to discuss the main implications of baryon and lepton number violation in physics beyond the Standard Model.

  18. A Proposed Exact Integer Value for Avogadro's Number

    E-Print Network [OSTI]

    Ronald F. Fox; Theodore P. Hill

    2007-04-28

    An exact value for Avodagro's number, namely NA* = (84446888)^3, is proposed. The number 84446888 represents the side length of a cube of atoms whose volume is closest, among all integral side lengths, to the current official NIST value of Avogadro's number. This value NA* is nearly dead center of the estimated range for the value of Avogadro's number, and is within the official standard level of uncertainty. Adoption of this value as the fixed value for NA would eliminate the current time-dependent definition of Avogadro's number, which depends on the definition of kilogram via an unstable physical artifact. It would also eliminate the need for the kilogram artifact altogether, since then, by definition, a kilogram would be exactly 1000/12 the mass of NA* atoms of carbon-12.

  19. Lepton Number Violation and the Baryon Asymmetry of the Universe

    E-Print Network [OSTI]

    Harz, Julia; Päs, Heinrich

    2015-01-01

    Neutrinoless double beta decay, lepton number violating collider processes and the Baryon Asymmetry of the Universe (BAU) are intimately related. In particular lepton number violating processes at low energies in combination with sphaleron transitions will typically erase any pre-existing baryon asymmetry of the Universe. In this contribution we briefly review the tight connection between neutrinoless double beta decay, lepton number violating processes at the LHC and constraints from successful baryogenesis. We argue that far-reaching conclusions can be drawn unless the baryon asymmetry is stabilized via some newly introduced mechanism.

  20. Examining A Hypersonic Turbulent Boundary Layer at Low Reynolds Number 

    E-Print Network [OSTI]

    Semper, Michael Thomas

    2013-05-15

    The purpose of the current study was to answer several questions related to hypersonic, low Reynolds number, turbulent boundary layers, of which available data related to turbulence quantities is scarce. To that end, a ...

  1. Prediction of Thermoacoustic Instabilities: Numerical Study of Mach number Effects.

    E-Print Network [OSTI]

    Nicoud, Franck

    Prediction of Thermoacoustic Instabilities: Numerical Study of Mach number Effects. K. Wieczorek equations. I. Introduction In the calculation of thermoacoustic instabilities, an assumption lead to significant changes in the evaluation of the thermo-acoustic modes present in the combustion

  2. Regulation Indentifier Number Title/Subject/Purpose Rule Type

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of a specific rule, please see the Federal Register at https:www.regulations.gov. Regulation Indentifier Number TitleSubjectPurpose Rule Type Status 1991-AB82 Acquisition...

  3. CRUISE REPORT Cruise Number: DY10-04

    E-Print Network [OSTI]

    of satellite buoy (SatBuoy) 1 Transect (Trans) 3 Samples Collected Tows Number misc species in EtOH (AMGEN) 17 of buoy or mooring (Deploy) 1 1 Stimulated fluorescence collected during CTD casts (Fluor) 12 Any other

  4. To ASME Journal of Mechanical Design Manuscript Number 20302

    E-Print Network [OSTI]

    Chen, Wei

    To ASME Journal of Mechanical Design Revision Manuscript Number 20302 Sequential Optimization and Reliability Assessment Method for Efficient Probabilistic Design Xiaoping Du, Assistant Professor Department of Mechanical and Aerospace Engineering and Engineering Mechanics University of Missouri ­ Rolla Rolla, Missouri

  5. Computing the stability number of a graph via semidefinite and ...

    E-Print Network [OSTI]

    2006-04-27

    then the vertices of G can be numbered so that E(G8) ? E(G ). Thus G8 is the smallest graph G such that ?(1)(G) > ?(G) = 3. We can extend the above reasoning ...

  6. Copositivity cuts for improving SDP bounds on the clique number ...

    E-Print Network [OSTI]

    2008-11-13

    ?(1)(G8) = 3.04328 while cutting with K4-free graphs trivially delivers the exact clique number since G8 itself is K4-free. See Subsection 6.1 below for.

  7. NUMBER: BUSF 1.08 SECTION: Business and Finance

    E-Print Network [OSTI]

    Almor, Amit

    NUMBER: BUSF 1.08 SECTION: Business and Finance SUBJECT: Relocation Expenses DATE: November 1, 2006 can claim reimbursement for your actual expenses such as gas and oil or the standard mileage rate (for

  8. MUS 122: Survey of Jazz Number of Credits 3

    E-Print Network [OSTI]

    MUS 122: Survey of Jazz Number of Credits 3 Instructor Peter Epstein Catalog Description'" (1959) Bessie Smith, "Back Water Blues" (1927) [Count Basie, "One O'Clock Jump" (1937)] Reading: New

  9. Investment dynamics and the timeliness properties of accounting numbers

    E-Print Network [OSTI]

    Papadakis, George, Ph. D. Massachusetts Institute of Technology

    2007-01-01

    This paper examines the properties of accounting numbers using a real investment framework that predicts asymmetric timeliness of both investment and its outcomes (i.e. sales, earnings and operating cash flows) even in the ...

  10. A SHARPER ESTIMATE ON THE BETTI NUMBERS OF SETS ...

    E-Print Network [OSTI]

    2006-10-31

    Oct 31, 2006 ... this paper also apply to the ordinary Betti numbers. (The use of Z2 coefficients is necessitated by our use of Smith inequalities in the proof of the ...

  11. A Taxonomy of Number Entry Error Sarah Wiseman

    E-Print Network [OSTI]

    Cairns, Paul

    an incorrect number is entered when programming a medical infusion pump or when entering financial information. If a medic programs an infusion pump incorrectly the patient may suffer ill consequences or even die

  12. Particle number density fluctuations and pressure effects on structure formation

    E-Print Network [OSTI]

    D. R. Matravers; J. Triginer

    2001-09-21

    We provide a covariant and gauge-invariant approach to the question of how a first order pressure can be incorporated self-consistently in a cosmological scenario. The approximation is relevant, in the linear regime, to weakly self-interacting or warm dark matter models. We also derive number density fluctuations in which new modes appear because the number density fluctuations are no longer simply proportional to the density fluctuations.

  13. Exploration of photon-number entangled states using weak nonlinearities

    E-Print Network [OSTI]

    Yingqiu He; Dong Ding; Fengli Yan; Ting Gao

    2015-04-03

    A method for exploring photon-number entangled states with weak nonlinearities is described. We show that it is possible to create and detect such entanglement at various scales, ranging from microscopic to macroscopic systems. In the present architecture, we suggest that the maximal phase shift induced in the process of interaction between photons is proportional to photon numbers. Also, in the absence of decoherence we analyze maximum error probability and show its feasibility with current technology.

  14. A Conjecture about the Density of Prime Numbers

    E-Print Network [OSTI]

    L. A. Amarante Ribeiro

    2008-03-04

    We present in this work a heuristic expression for the density of prime numbers. Our expression leads to results which possesses approximately the same precision of the Riemann's function in the domain that goes from 2 to 1010 at least. Instead of using a constant as was done by Legendre and others in the formula of Gauss, we try to adjust the data through a function. This function has the remarkable property: its points of discontinuity are the prime numbers.

  15. Nearest neighbor spacing distribution of prime numbers and quantum chaos

    E-Print Network [OSTI]

    Marek Wolf

    2014-01-07

    We give heuristic arguments and computer results to support the hypothesis that, after appropriate rescaling, the statistics of spacings between adjacent prime numbers follows the Poisson distribution. The scaling transformation removes the oscillations in the NNSD of primes. These oscillations have the very profound period of length six. We also calculate the spectral rigidity $\\Delta_3$ for prime numbers by two methods. After suitable averaging one of these methods gives the Poisson dependence $\\Delta_3(L)=L/15$.

  16. Nucleon semimagic numbers and low-energy neutron scattering

    E-Print Network [OSTI]

    D. A. Zaikin; I. V. Surkova

    2010-04-09

    It is shown that experimental values of the cross sections of inelastic low-energy neutron scattering on even-even nuclei together with the description of these cross sections in the framework of the coupled channel optical model may be considered as a reliable method for finding nuclei with a semimagic number (or numbers) of nucleons. Some examples of the application of this method are considered.

  17. On Measurements, Numbers and p-Adic Mathematical Physics

    E-Print Network [OSTI]

    Branko Dragovich

    2012-05-23

    In this short paper I consider relation between measurements, numbers and p-adic mathematical physics. p-Adic numbers are not result of measurements, but nevertheless they play significant role in description of some systems and phenomena. We illustrate their ability for applications referring to some sectors of p-adic mathematical physics and related topics, in particular, to string theory and the genetic code.

  18. Winding number order in the Haldane model with interactions

    E-Print Network [OSTI]

    Emilio Alba; Jiannis Pachos; Juan Jose Garcia-Ripoll

    2015-05-02

    We study the Haldane model with nearest-neighbor interactions. This model is physically motivated by the associated ultracold atoms implementation. We show that the topological phase of the interacting model can be characterized by a physically observable winding number. The robustness of this number extends well beyond the topological insulator phase towards attractive and repulsive interactions that are comparable to the kinetic energy scale of the model. We identify and characterize the relevant phases of the model.

  19. CRUISE REPORT Cruise Number: SU-9503 Leg-1

    E-Print Network [OSTI]

    CRUISE REPORT Cruise Number: SU-9503 Leg-1 FOCI Number: FOCI NOAA Ship: SURVEYOR Area of Operations 166° 03.1' W Line XIV, Station 86 0927 CTD011 11 182 54° 48.4' N '". 165° 51.3' W Line XIV, Station 0803 CTD018 18 5579 51° 01.1' N 173° 32.7' W Line Station 2 1133 CTD019 19 4741 51° 13.9' N 173° 31

  20. INTEGERS: ELECTRONIC JOURNAL OF COMBINATORIAL NUMBER THEORY 7 (2007), #A56 MIXED SUMS OF SQUARES AND TRIANGULAR NUMBERS (II)

    E-Print Network [OSTI]

    Sun, Zhi-Wei

    2007-01-01

    AND TRIANGULAR NUMBERS (II) Song Guo Department of Mathematics, Huaiyin Teachers College, Huaian 223001, P. R 200240, P. R. China haopan79@yahoo.com.cn Zhi-Wei Sun1 Department of Mathematics, Nanjing University