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Note: This page contains sample records for the topic "ni pd pt" from the National Library of EnergyBeta (NLEBeta).
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1

Middle distillate hydrotreatment zeolite catalysts containing Pt/Pd or Ni  

E-Print Network [OSTI]

A study on middle distillate hydrotreatment zeolite catalysts containing Pt/Pd and/or Ni was performed. The effect of the addition of the corresponding CoMo, CoMoPd, CoMoPtPd and CoMoNi in PdNiPt-zeolite, Pt-zeolite, Ni-zeolite, and Pd...

Marin-Rosas, Celia

2009-05-15T23:59:59.000Z

2

Catalyst and process development for hydrogen preparation from future fuel cell feedstocks. Quarterly progress report, January 1, 1980-March 31, 1980. [Pt/Rh, Pd, Pt, Rh, Ni/Rh, Rh/Re, Ni  

SciTech Connect (OSTI)

Catalysts are being screened to steam reform hydrocarbons in an autothermal reformer (STR). Twenty-one samples have been screened in a 1-in.-diam (ATR) reactor using No. 2 oil as the hydrocarbon feed. A series of platinum-rhodium catalysts were evaluated to study the effect of varying compositions. A sample containing 1.7% Pt/0.3% Rh was most active but the difference among the samples was within the range of test variability. Development of a more realistic test has been started. The effect of O/sub 2//C level on the gas composition leaving the catalytic partial oxidation section has been determined. The amount of unreacted oil increases as O/sub 2//C level decreases. The unreacted oil is more aromatic than the feedstock. The gas composition contains considerably more olefins as the O/sub 2//C level decreases. Post-run catalyst characterization indicates that the catalyst carrier does not deteriorate in the ATR test. A drastic decrease in CO chemisorption is noted on the Pt/Rh samples. This decline in CO chemisorption could either be due to metal sintering or to carbon deposition on the metal. Other analysis are required to determine which is causing the decline in CO chemisorption. Very low coke levels were found on Pt, Rh, and Pt/Rh samples. Addition of Rh to nickel reduces the coke level over that observed for nickel catalysts.

Yarrington, R M; Feins, I R; Hwang, H S

1980-04-01T23:59:59.000Z

3

Deactivation Mechanisms of Pt/Pd-based Diesel Oxidation Catalysts...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Oh, DB Brown, DH Kim, JH Lee, and CHF Peden.2012."Deactivation Mechanisms of PtPd-based Diesel Oxidation Catalysts."Catalysis Today 184(1):197-204. doi:10.1016...

4

Growth of Epitaxial Thin Pd(111) Films on Pt(111) and Oxygen...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Growth of Epitaxial Thin Pd(111) Films on Pt(111) and Oxygen-Terminated FeO(111) Surfaces . Growth of Epitaxial Thin Pd(111) Films on Pt(111) and Oxygen-Terminated FeO(111)...

5

Crystalline Ice Growth on Pt(111) and Pd(111): Nonwetting Growth...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Crystalline Ice Growth on Pt(111) and Pd(111): Nonwetting Growth on a Hydrophobic Water Monolayer. Crystalline Ice Growth on Pt(111) and Pd(111): Nonwetting Growth on a Hydrophobic...

6

A photoemission study of Pd ultrathin films on Pt(111)  

SciTech Connect (OSTI)

The origin of surface core-level shift (SCLS) of Pd thin films on Pt(111) substrate is investigated. At sub-monolayer coverage of Pd thin films, the splitting of Pd 3d core level peaks indicate the contribution of both initial and final-state of photo-ionization processes while there is almost no change on valence band (VB) spectra. When the coverage of Pd reaches to single monolayer, the final-state relaxation effect on the Pd 3d vanishes and only the initial-state effect, a negative SCLS, is present. Also, the VB spectrum at Pd monolayer films shows a clear band narrowing, that is the origin of the negative SCLS at monolayer coverage. As the Pd coverage is increased to more than monolayer thickness, the Pd 3d peaks start to show the surface layer contribution from second and third layers, positive SCLS, and the VB spectrum shows even narrower band width, possibly due to the formation of surface states and strained effect of Pd adlayers on top of the first pseudomorphic layer.

Mun, Bongjin Simon; Lee, Choongman; Stamenkovic, Vojislav; Markovic, Nenad M.; Ross Jr., Philip N.

2005-05-11T23:59:59.000Z

7

CO adsorption and kinetics on well-characterized Pd films on Pt(111) in alkaline solutions  

E-Print Network [OSTI]

voltammetric profiles of Pt(111)-xPd surfaces. The correlation between the PdPd films were prepared and well characterized in UHV and subsequently transferred into the electrochemical cell for the registration of the voltammetric profiles.

Arenz, M.; Stamenkovic, V.; Wandelt, K.; Ross, P.N.; Markovic, N.M.

2002-01-01T23:59:59.000Z

8

PT AND PT/NI "NEEDLE" ELETROCATALYSTS ON CARBON NANOTUBES WITH HIGH ACTIVITY FOR THE ORR  

SciTech Connect (OSTI)

Platinum and platinum/nickel alloy electrocatalysts supported on graphitized (gCNT) or nitrogen doped carbon nanotubes (nCNT) are prepared and characterized. Pt deposition onto carbon nanotubes results in Pt 'needle' formations that are 3.5 nm in diameter and {approx}100 nm in length. Subsequent Ni deposition and heat treatment results in PtNi 'needles' with an increased diameter. All Pt and Pt/Ni materials were tested as electrocatalysts for the oxygen reduction reaction (ORR). The Pt and Pt/Ni catalysts showed excellent performance for the ORR, with the heat treated PtNi/gCNT (1.06 mA/cm{sup 2}) and PtNi/nCNT (0.664 mA/cm{sup 2}) showing the highest activity.

Colon-Mercado, H.

2011-11-10T23:59:59.000Z

9

Mechanism of olefin production on Pt, Rh, and Pd catalysts  

SciTech Connect (OSTI)

The partial oxidation of ethylene, propylene, and butylene in an autothermal reactor at atmospheric pressure with contact times less that {approximately}10 milliseconds leads to high selectivities to mono-olefins over Pt/Al{sub 2}O{sub 3}, synthesis gas over Rh/Al{sub 2}O{sub 3}, and rapid carbon deposition and deactivation over Pd/Al{sub 2}O{sub 3} at complete oxygen conversion and high alkane conversion. In all cases, thermodynamics predicts carbon deposition. We will show how the product distributions vary with choice of catalyst and reaction conditions. We will use an elementary step model based on surface reaction rates on the various metals obtained from the surface science literature to simulate these experimental results. The dominant reaction pathways on the different metals can be explained by the relative preference for {beta} elimination reactions on Pt, nearly even split between {alpha} and {beta} elimination on Rh, and rapid {alpha} elimination on Pd.

Huff, M.; Schmidt, L.D. [Univ. of Minnesota, Minneapolis, MN (United States)

1995-12-01T23:59:59.000Z

10

The influence of Pt redistribution on Ni{sub 1-x}Pt{sub x}Si growth properties  

SciTech Connect (OSTI)

We have studied the influence of Pt on the growth of Ni silicide thin films by examining the Pt redistribution during silicide growth. Three different initial Pt configurations were investigated, i.e., a Pt alloy (Ni+Pt/), a Pt capping layer (Pt/Ni/) and a Pt interlayer (Ni/Pt/), all containing 7 at. % Pt relative to the Ni content. The Pt redistribution was probed using in situ real-time Rutherford backscattering spectrometry (RBS) whereas the phase sequence was monitored during the solid phase reaction (SPR) using in situ real-time x-ray diffraction. We found that the capping layer and alloy exhibit a SPR comparable to the pure Ni/ system, whereas Pt added as an interlayer has a much more drastic influence on the Ni silicide phase sequence. Nevertheless, for all initial sample configurations, Pt redistributes in an erratic way. This phenomenon can be assigned to the low solubility of Pt in Ni{sub 2}Si compared to NiSi and the high mobility of Pt in Ni{sub 2}Si compared to pure Ni. Real-time RBS further revealed that the crucial issue determining the growth properties of each silicide phase is the Pt concentration at the Si interface during the initial stages of phase formation. The formation of areas rich in Pt reduce the Ni silicide growth kinetics which influences the phase sequence and properties of the silicides.

Demeulemeester, J.; Smeets, D.; Temst, K.; Vantomme, A. [Instituut voor Kern-en Stralingsfysica and INPAC, K.U.Leuven, Celestijnenlaan 200D, B-3001 Leuven (Belgium); Comrie, C. M. [Department of Physics, University of Cape Town, Rondebosch 7700 (South Africa); Van Bockstael, C.; Knaepen, W.; Detavernier, C. [Department of Solid State Sciences, Ghent University, B-9000 Gent (Belgium)

2010-08-15T23:59:59.000Z

11

Ni-Pt Silicide Formation Through Ti Mediating Layers  

SciTech Connect (OSTI)

With Ni1-xPtxSi, the variation in queue time between the final surface cleaning and Ni-Pt deposition represents a significant manufacturability issue. A short queue time is often difficult to maintain, leading to the formation of an oxide layer on the Si substrate prior to Ni-Pt deposition that can affect the formation of Ni1-xPtxSi and its texture. In this manuscript, it will be shown that an extended queue time prior to Ni-Pt deposition leads to morphological changes in the Ni1-xPtxSi formation sequence. A layer of Ti deposited between Ni-Pt and Si reduces the native oxide and may facilitate Ni1-xPtxSi formation. With increasing Ti thickness, the presence of metal-rich phases is gradually reduced and the formation temperature of Ni1-xPtxSi increases, suggesting a direct formation of Ni1-xPtxSi from Ni-Pt. In the presence of an interfacial oxide, an increase in formation temperature is also observed with increasing Ti interlayer thickness. When the Ti layer is sufficiently thick, the phase formation sequence becomes relatively insensitive to the presence of an interfacial oxide or extended queue time.

Besser,P.; Lavoie, C.; Ozcan, A.; Murray, C.; Strane, J.; Wong, K.; Gribelyuk, M.; Wang, Y.; Parks, C.; Jordan-Sweet, J.

2007-01-01T23:59:59.000Z

12

The effect of specific chloride adsorption on the electrochemical behavior of ultrathin Pd films deposited on Pt(111) in acid solution  

E-Print Network [OSTI]

the Pd surface coverage modifies the voltammetric profilesFigure 2 voltammetric profiles of the Pt(111)-Pd electrodethe voltammetric profiles that demonstrate the effect of Pd.

Arenz, M.; Stamenkovic, V.; Schmidt, T.J.; Wandelt, K.; Ross, P.N.; Markovic, N.M.

2002-01-01T23:59:59.000Z

13

Pt/Pd electrocatalyst electrons for fuel cells  

DOE Patents [OSTI]

This invention relates to improved electrochemical cells and to novel electrodes for use therein. In particular, the present invention comprises a fuel cell used primarily for the consumption of impure hydrogen fuels containing carbon monoxide or carbonaceous fuels where the electrode in contact with the fuel is not substantially poisoned by carbon monoxide. The anode of the fuel cell comprises a Pd/Pt alloy supported on a graphitized or partially graphitized carbon material. Fuel cells which comprise as essential elements a fuel electrode, an oxidizing electrode, and an electrolyte between said electrodes are devices for the direct production of electricity through the electrochemical combustion of a fuel and oxidant. These devices are recognized for their high efficiency as energy conversion units, since unlike conventional combustion engines, they are not subject to the limitations of the Carnot heat cycle. It is the primary object of the present invention to provide an electrode having high electrochemical activity for an electrochemical cell. It is another object of the present invention to provide an electrode having an electro-catalyst which is highly resistant to the corrosive environment of an electrochemical cell.

Stonehart, P.

1981-11-03T23:59:59.000Z

14

Thermomechanical Characterization of a TiPdNi High Temperature SMA under Tension  

E-Print Network [OSTI]

Thermomechanical Characterization of a TiPdNi High Temperature SMA under Tension Parikshith K issues, a nominal composition of Ti50Pd40Ni10 HTSMA was used. The alloy was fabricated using a vacuum arc Electrode Discharge Machining (EDM). A high temperature experimental setup was developed on a load frame

15

High Performance Plasma Sputtered PdPt Fuel Cell Electrodes with Ultra Low Loading  

E-Print Network [OSTI]

: the catalyst of a fuel cell can cost no more than 5/3 per kilowatt [1]. If the catalyst is platinum (~40 g-1High Performance Plasma Sputtered PdPt Fuel Cell Electrodes with Ultra Low Loading M. Mougenot1, 2 potential for the fuel cell technology to overcome the upcoming energy and resources issues in our society

Paris-Sud XI, Université de

16

Effect of Pd on the Ni{sub 2}Si stress relaxation during the Ni-silicide formation at low temperature  

SciTech Connect (OSTI)

The thermally induced solid-state reaction between a 50-nm-thick Ni(6%Pd) layer and a Si(100) substrate was investigated using in situ and simultaneous x-ray diffraction and sheet resistance. The reaction begins with the growth of the stressed {delta}-Ni{sub 2}Si phase, and the transient {theta}-Ni{sub 2}Si. At the end of the {theta}-Ni{sub 2}Si consumption, a NiSi seed is formed. Then, the {delta}-Ni{sub 2}Si relaxation occurs simultaneously with its subsequent growth and the Pd out diffusion from the unreacted Ni(Pd) layer. It is suggested that the driving force for the Pd diffusion out of the metal layer is linked to both the higher solubility of Pd in NiSi compared to Ni{sub 2}Si and to the Ni{sub 2}Si relaxation.

Putero, M.; Mangelinck, D. [Aix-Marseille Univ., IM2NP, Faculte des Sciences de Jerome, F-13397 Marseille (France); CNRS, IM2NP-UMR 7334, Faculte des Sciences de Jerome, F-13397 Marseille (France)

2012-09-10T23:59:59.000Z

17

Synthesis of Pt?Pd Core?Shell Nanostructures by Atomic Layer Deposition: Application in Propane Oxidative Dehydrogenation to Propylene  

SciTech Connect (OSTI)

Atomic layer deposition (ALD) was employed to synthesize supported Pt?Pd bimetallic particles in the 1 to 2 nm range. The metal loading and composition of the supported Pt?Pd nanoparticles were controlled by varying the deposition temperature and by applying ALD metal oxide coatings to modify the support surface chemistry. Highresolution scanning transmission electron microscopy images showed monodispersed Pt?Pd nanoparticles on ALD Al2O3 - and TiO2 -modi?ed SiO2 gel. X-ray absorption spectroscopy revealed that the bimetallic nanoparticles have a stable Pt-core, Pd-shell nanostructure. Density functional theory calculations revealed that the most stable surface con?guration for the Pt? Pd alloys in an H2 environment has a Pt-core, Pd-shell nanostructure. In comparison to their monometallic counterparts, the small Pt?Pd bimetallic core?shell nanoparticles exhibited higher activity in propane oxidative dehydrogenation as compared to their physical mixture.

Lei, Y.; Liu, Bin; Lu, Junling; Lobo-Lapidus, Rodrigo J.; Wu, Tianpin; Feng, Hao; Xia, Xiaoxing; Mane, Anil U.; Libera, Joseph A.; Greeley, Jeffrey P.; Miller, Jeffrey T.; Elam, J. W.

2012-08-20T23:59:59.000Z

18

Thermomechanical Cyclic Response of TiNiPd High-Temperature Shape Memory Alloys  

E-Print Network [OSTI]

TiNiPd high-temperature shape memory alloys (HTSMAs) have attracted considerable attention as potential solid-state actuators capable of operating at temperatures up to 500 °C, exhibiting excellent corrosion resistance, adequate ductility levels...

Atli, Kadri

2012-10-19T23:59:59.000Z

19

The wetting behavior of NiAl and NiPtAl on polycrystalline alumina  

SciTech Connect (OSTI)

In order to understand the beneficial effect of Pt on the adherence of thermally grown alumina scales, sessile drop experiments were performed to study the wetting of poly-crystalline alumina by nickel-aluminum alloys with or without platinum addition where the amount of Pt ranged from 2.4 to 10 at.%. Subsequent interfacial structure was evaluated using atomic force microscopy. Platinum addition enhances the wettability of NiAl alloys on alumina, reduces the oxide/alloy interface energy and increases the interfacial mass transport rates.

Saiz, Eduardo; Gauffier, Antoine; Saiz, Eduardo; Tomsia, Antoni P.; Hou, Peggy Y.

2007-07-01T23:59:59.000Z

20

Tunable magnetization dynamics in disordered FePdPt ternary alloys: Effects of spin orbit coupling  

SciTech Connect (OSTI)

The magnetization dynamics of disordered Fe{sub 0.5}(Pd{sub 1?x}Pt{sub x}){sub 0.5} alloy films was studied by time-resolved magneto-optical Kerr effect and ferromagnetic resonance. The intrinsic Gilbert damping parameter ?{sub 0} and the resonance linewidth change linearly with the Pt atomic concentration. In particular, the induced in-plane uniaxial anisotropy constant K{sub U} also increases for x increasing from 0 to 1. All these results can be attributed to the tuning effect of the spin orbit coupling. For the disordered ternary alloys, an approach is proposed to control the induced in-plane uniaxial anisotropy, different from conventional thermal treat methods, which is helpful to design and fabrications of spintronic devices.

Ma, L.; Fan, W. J., E-mail: stslts@mail.sysu.edu.cn; Chen, F. L.; Zhou, S. M. [Shanghai Key Laboratory of Special Artificial Microstructure and Pohl Institute of Solid State Physics and School of Physics Science and Engineering, Tongji University, Shanghai 200092 (China); Li, S. F.; Lai, T. S., E-mail: eleanorfan@163.com [State Key Laboratory of Optoelectronic Materials and Technologies, School of Physics and Engineering, Sun Yat-Sen University, Guangzhou 510275 (China); He, P. [Department of Physics, Fudan University, Shanghai 200433 (China); Xu, X. G.; Jiang, Y. [State Key Laboratory for Advanced Metals and Materials, School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083 (China)

2014-09-21T23:59:59.000Z

Note: This page contains sample records for the topic "ni pd pt" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Characterizations Of Precipitate Phases In a Ti-Ni-Pd Alloy  

SciTech Connect (OSTI)

Precipitates in the Ti46Ni37.5Pd16.5 alloy were investigated by electron diffraction and high-resolution scanning transmission electron microscopy. The phase content and stability were determined at several different temperatures and times. Aging at 400 C for an hour results in a new phase, which is consumed by P-phase at longer aging time. At 450 C, the new phase appears first, and then coexists with P-phase. At 500 C, the entire alloy transformed into the new phase. At 550 C, Ti3(Ni,Pd)4 phase begins to form.

Yang, Fan; Kovarik, Libor; Phillips, Patrick J.; Noebe, Ronald D.; Mills, M. J.

2012-06-01T23:59:59.000Z

22

Effect of Pt addition on Ni silicide formation at low temperature: Growth, redistribution, and solubility  

SciTech Connect (OSTI)

The formation of Ni silicide during the reaction between Ni(5% Pt) and a Si(100) substrate has been analyzed by differential scanning calorimetry (DSC), in situ x-ray diffraction (XRD), cross-sectional transmission electron microscopy (TEM), and {sup 4}He{sup +} Rutherford backscattering. The DSC measurements show evidence of the Ni{sub 2}Si nucleation followed by lateral growth formation. In situ XRD and TEM have been used to investigate the sequence of formation of the silicides. These experiments show that the formations of Ni{sub 2}Si and NiSi occur simultaneously in the presence of the Pt alloy. The redistribution of platinum at different stages of the Ni silicide growth has been determined. We have estimated the solubility limit of platinum (1 at. % at 573 K) in the Ni{sub 2}Si phase by extrapolation from a measured value at 1073 K. This redistribution is explained in terms of the solubility limits and the diffusion of Pt in the Ni{sub 2}Si and NiSi phases. Pt is more likely to reside at the silicide grain boundaries and the interfaces where it can slow down the silicide growth kinetics.

Hoummada, K.; Perrin-Pellegrino, C.; Mangelinck, D. [Aix-Marseille Universite, IM2NP, Campus de Saint-Jerome, Avenue Escadrille Normandie Niemen-Case 142, F-13397 Marseille Cedex (France); CNRS, IM2NP (UMR 6242), Case 142, Faculte de Saint-Jerome, F-13397 Marseille Cedex (France)

2009-09-15T23:59:59.000Z

23

Microstructural Characterization and Shape Memory Response of Ni-Rich NiTiHf and NiTiZr High Temperature Shape Memory Alloys  

E-Print Network [OSTI]

NiTiHf and NiTiZr high temperature shape memory alloys (HTSMAs) have drawn a great deal of attention as cheaper alternatives to Pt, Pd and Au alloyed NiTi-based HTSMAs while NiTiZr alloys also providing at least 20% weight reduction then its Ni...

Evirgen, Alper

2014-08-14T23:59:59.000Z

24

Activity and Evolution of Vapor Deposited Pt-Pd Oxygen Reduction Catalysts for Solid Acid Fuel Cells  

SciTech Connect (OSTI)

The performance of hydrogen fuel cells based on the crystalline solid proton conductor CsH2PO4 is circumscribed by the mass activity of platinum oxygen reduction catalysts in the cathode. Here we report on the first application of an alloy catalyst in a solid acid fuel cell, and demonstrate an activity 4.5 times greater than Pt at 0.8 V. These activity enhancements were obtained with platinum-palladium alloys that were vapor-deposited directly on CsH2PO4 at 210 C. Catalyst mass activity peaks at a composition of 84 at% Pd, though smaller activity enhancements are observed for catalyst compositions exceeding 50 at% Pd. Prior to fuel cell testing, Pd-rich catalysts display lattice parameter expansions of up to 2% due to the presence of interstitial carbon. After fuel cell testing, a Pt-Pd solid solution absent of lattice dilatation and depleted in carbon is recovered. The structural evolution of the catalysts is correlated with catalyst de-activation.

Papandrew, Alexander B [ORNL; Chisholm, Calum R [ORNL; Zecevic, strahinja [LiOx, Inc., Pasadena, California 91106, United States; Veith, Gabriel M [ORNL; Zawodzinski, Thomas A [ORNL

2013-01-01T23:59:59.000Z

25

Tuning magnetotransport in PdPt/Y{sub 3}Fe{sub 5}O{sub 12}: Effects of magnetic proximity and spin-orbit coupling  

SciTech Connect (OSTI)

We report that anisotropic magnetoresistance (AMR) and anomalous Hall conductivity (AHC) in the Pd{sub 1?x}Pt{sub x}/Y{sub 3}Fe{sub 5}O{sub 12} (YIG) bilayers could be tuned by varying the Pt concentration (x) and also temperature (T). In particular, the AHC at low T changes its sign when x increases from 0 to 1, agreeing with the negative and positive AHC predicted by our ab initio calculations for the magnetic proximity (MP)-induced ferromagnetic Pd and Pt, respectively. The AMR ratio is enhanced by ten times when x increases from 0 to 1. Furthermore, the AMR of PdPt/YIG bilayers shows similar T-dependence as the magnetic susceptibility of the corresponding bulk Pd/Pt, also indicating the MP effect as the origin of the AMR. The present work demonstrates that the alloying of Pt and Pd not only offers tunable spin-orbit coupling but also is useful to reveal the nature of the AMR and AHC in Pt/YIG bilayers, which are useful for spintronics applications.

Zhou, X.; Ma, L.; Shi, Z.; Zhou, S. M., E-mail: shiming@tongji.edu.cn [Shanghai Key Laboratory of Special Artificial Microstructure and Pohl Institute of Solid State Physics and School of Physics Science and Engineering, Tongji University, Shanghai 200092 (China); Guo, G. Y., E-mail: gyguo@phys.ntu.edu.tw [Department of Physics, National Taiwan University, Taipei 10617, Taiwan (China); Hu, J.; Wu, R. Q. [Department of Physics and Astronomy, University of California, Irvine, California 92697-4575 (United States)

2014-07-07T23:59:59.000Z

26

Effective work function of Pt, Pd, and Re on atomic layer deposited HfO{sub 2}  

SciTech Connect (OSTI)

Platinum and Pd show a significant difference in work function on SiO{sub 2} and high-K materials (HfO{sub 2}). The effective metal work functions for Pd, Pt, and Re on atomic layer deposited HfO{sub 2}, which are different from the vacuum work function and important for device threshold voltage control, are measured by the C-V method. The difference is attributed to the dipoles at the metal/HfO{sub 2} interface, which is a result of charge transfer across the interface. Moreover, the extracted charge neutrality level and screening parameter are correlated with the phase development, film stoichiometry, and density of interface states at the metal/high-K interface.

Gu Diefeng; Dey, Sandwip K.; Majhi, Prashant [Department of Chemical and Materials Engineering, Arizona State University, Tempe, Arizona 85287-6006 (United States) and Department of Electrical Engineering, Arizona State University, Tempe, Arizona 85287-5706 (United States); Planar CMOS Scaling, SEMATECH, Austin, Texas 78741 (United States)

2006-08-21T23:59:59.000Z

27

Phase formation and morphological stability of ultrathin Ni-Co-Pt silicide films formed on Si(100)  

SciTech Connect (OSTI)

Ultrathin Ni, Co, and Pt films, each no more than 4?nm in thickness, as well as their various combinations are employed to investigate the competing growth of epitaxial Co{sub 1-y}Ni{sub y}Si{sub 2} films against polycrystalline Pt{sub 1-z}Ni{sub z}Si. The phase formation critically affects the morphological stability of the resulting silicide films, with the epitaxial films being superior to the polycrystalline ones. Any combination of those metals improves the morphological stability with reference to their parent individual metal silicide films. When Ni, Co, and Pt are all included, the precise initial location of Pt does little to affect the final phase formation in the silicide films and the epitaxial growth of Co{sub 1-x}Ni{sub x}Si{sub 2} films is always perturbed, in accordance to thermodynamics that shows a preferential formation of Pt{sub 1-z}Ni{sub z}Si over that of Co{sub 1-y}Ni{sub y}Si{sub 2}.

Xu, Peng; Wu, Dongping, E-mail: dongpingwu@fudan.edu.cn [State Key Laboratory of ASIC and System, Fudan University, Shanghai 200433 (China); Kubart, Tomas; Gao, Xindong [Solid-State Electronics, The Ångström Laboratory, Uppsala University, P.O. Box 534, 75121 Uppsala (Sweden); Zhang, Shi-Li, E-mail: shili.zhang@angstrom.uu.se [State Key Laboratory of ASIC and System, Fudan University, Shanghai 200433, China and Solid-State Electronics, The Ångström Laboratory, Uppsala University, P.O. Box 534, 75121 Uppsala (Sweden)

2014-05-15T23:59:59.000Z

28

Final Technical Report: First Principles Investigations for the Ensemble Effects of PdAu and PtAu Bimetallic Nanocatalysts  

SciTech Connect (OSTI)

Bimetallic surfaces with tunable chemical properties have attracted broad attention in recent years due to their ample potential for heterogeneous catalysis applications. The local chemical properties of constituents are strongly altered from their parent metals by 'ligand effect', a term encompassing the influences of charge transfer, orbital rehybridization and lattice strain. In comparison to the aforementioned, the 'ensemble effect' associated with particular arrangements of the active constituents have received much less attention, despite their notable importance towards the determination of reactivity and selectivity of bimetallic catalysts. We performed theoretical studies for understanding the ensemble effects on bimetallic catalysis: (i) simulations for the formation of different ensembles on PdAu and PtAu nanoclusters; (ii) studies of the size, shape, and substrate dependence of their electronic properties; and (iii) simulations for model reactions such as CO oxidation, methanol, ethylene and water dehydrogenation on PdAu and PtAu nanoclusters. In close collaboration with leading experimental groups, our theoretical research elucidated the fundamentals of Au based bimetallic nanocatalysts.

Ruqian Wu

2012-05-18T23:59:59.000Z

29

The morphology of electroless Ni deposition on a colloidal Pd(II) catalyst  

SciTech Connect (OSTI)

The surface morphology of a surface-bound colloidal Pd(II) catalyst and its effect on the particle sizes with the largest particles reaching approximately 50 nm in diameter. Catalyst surface coverages as low as 20% are found to be sufficient to initiate complete and homogeneous metallization. The distribution of particle sizes for the electroless metal deposit, found to be a function of plating time, is broad with the maximum Ni particle size exceeding 120 nm. Results indicate controlling the size of the bound catalyst is the principal determining factor in controlling the particle size of the electroless deposit. Modification of the surface by depleting the concentration of surface functional groups capable of binding catalyst is used to shift the size distribution of bound catalyst to smaller values. A resulting three-to fourfold reduction in the particle size of the electroless deposit is demonstrated.

Brandow, S.L.; Dressick, W.J.; Marrian, C.R.K.; Chow, G.M.; Calvert, J.M. [Naval Research Laboratory, Washington, DC (United States)

1995-07-01T23:59:59.000Z

30

Well-defined ultrathin Pd films on Pt(111): electrochemical preparation and interfacial chemistry  

E-Print Network [OSTI]

. In both methods, between the coverage regimes studied, the growth of the Pd films follows the Stranski-Krastanov mechanism. The interfacial electrochemical properties associated with the film-to-bulk transition were characterized by conventional...

Park, Yeon Su

2005-08-29T23:59:59.000Z

31

Time-domain detection of current controlled magnetization damping in Pt/Ni{sub 81}Fe{sub 19} bilayer and determination of Pt spin Hall angle  

SciTech Connect (OSTI)

The effect of spin torque from the spin Hall effect in Pt/Ni{sub 81}Fe{sub 19} rectangular bilayer film was investigated using time-resolved magneto-optical Kerr microscopy. Current flow through the stack resulted in a linear variation of effective damping up to ±7%, attributed to spin current injection from the Pt into the Ni{sub 81}Fe{sub 19}. The spin Hall angle of Pt was estimated as 0.11?±?0.03. The modulation of the damping depended on the angle between the current and the bias magnetic field. These results demonstrate the importance of optical detection of precessional magnetization dynamics for studying spin transfer torque due to spin Hall effect.

Ganguly, A.; Haldar, A.; Sinha, J.; Barman, A., E-mail: abarman@bose.res.in, E-mail: del.atkinson@durham.ac.uk [Thematic Unit of Excellence on Nanodevice Technology, Department of Condensed Matter Physics and Material Sciences, S. N. Bose National Centre for Basic Sciences, Kolkata 700098 (India); Rowan-Robinson, R. M.; Jaiswal, S.; Hindmarch, A. T.; Atkinson, D. A., E-mail: abarman@bose.res.in, E-mail: del.atkinson@durham.ac.uk [Department of Physics, Durham University, South Road, Durham DH1 3LE (United Kingdom)

2014-09-15T23:59:59.000Z

32

Digital Deposition of Ultrathin Pd Films on Well-Defined Pt(111) Electrodes via Surface-Limited Redox Replacement Reaction: An Electron Spectroscopy-Electrochemistry Study  

E-Print Network [OSTI]

monolayer of a nonnoble metal (Cu) is deposited on a noble metal (Pt) by underpotential deposition (UPD). When the UPD adlayer is exposed to cations of less reactive metals (Pd^2 ), it is oxidatively stripped and reductively displaced by the more inert metal...

Hossain, Mohammad

2010-12-04T23:59:59.000Z

33

High Temperature Oxidation Behavior of gamma-Ni+gamma'-Ni3Al Alloys and Coatings Modified with Pt and Reactive Elements  

SciTech Connect (OSTI)

Materials for high-pressure turbine blades must be able to operate in the high-temperature gases (above 1000 C) emerging from the combustion chamber. Accordingly, the development of nickel-based superalloys has been constantly motivated by the need to have improved engine efficiency, reliability and service lifetime under the harsh conditions imposed by the turbine environment. However, the melting point of nickel (1455 C) provides a natural ceiling for the temperature capability of nickel-based superalloys. Thus, surface-engineered turbine components with modified diffusion coatings and overlay coatings are used. Theses coatings are capable of forming a compact and adherent oxide scale, which greatly impedes the further transport of reactants between the high-temperature gases and the underlying metal and thus reducing attack by the atmosphere. Typically, these coatings contain {beta}-NiAl as a principal constituent phase in order to have sufficient aluminum content to form an Al{sub 2}O{sub 3} scale at elevated temperatures. The drawbacks to the currently-used {beta}-based coatings, such as phase instabilities, associated stresses induced by such phase instabilities, and extensive coating/substrate interdiffusion, are major motivations in this study to seek next-generation coatings. The high-temperature oxidation resistance of novel Pt + Hf-modified {gamma}-Ni + {gamma}-Ni{sub 3}Al-based alloys and coatings were investigated in this study. Both early-stage and 4-days isothermal oxidation behavior of single-phase {gamma}-Ni and {gamma}{prime}-Ni{sub 3}Al alloys were assessed by examining the weight changes, oxide-scale structures, and elemental concentration profiles through the scales and subsurface alloy regions. It was found that Pt promotes Al{sub 2}O{sub 3} formation by suppressing the NiO growth on both {gamma}-Ni and {gamma}{prime}Ni{sub 3}Al single-phase alloys. This effect increases with increasing Pt content. Moreover, Pt exhibits this effect even at lower temperatures ({approx}970 C) in the very early stage of oxidation. It was also inferred that Pt enhances the diffusive flux of aluminum from the substrate to the scale/alloy interface. Relatively low levels of hafnium addition to Pt-free {gamma}{prime}-Ni{sub 3}Al increased the extent of external NiO formation due to non-protective HfO{sub 2} formation. Accordingly, this effect intensified with increasing Hf content from 0.2 to 0.5 at.%.

Nan Mu

2007-12-01T23:59:59.000Z

34

Shape memory behavior of ultrafine grained NiTi and TiNiPd shape memory alloys  

E-Print Network [OSTI]

The cyclic instability in shape memory characteristics of NiTi-based shape memory alloys (SMAs), such as transformation temperatures, transformation and irrecoverable strains and transformation hysteresis upon thermal and mechanical cycling limits...

Kockar, Benat

2009-05-15T23:59:59.000Z

35

Effect of Pt promotion on Ni/Al{sub 2}O{sub 3} for the selective catalytic reduction of NO with hydrogen  

SciTech Connect (OSTI)

Ni/Al{sub 2}O{sub 3} (10 wt.% Ni) and Ni-Pt/Al{sub 2}O{sub 3} (10 wt.% Ni, 0.5 wt.% Pt) were comparatively tested in the hydrogen selective catalytic reduction process (H{sub 2}-SCR), at reaction temperatures below 350°C. Catalytic activity tests consisted in temperature programmed reactions (TPRea) under plug flow conditions from 50 to 350°C, with a temperature rate of 5°C/min, using a feed stream with a reactant ratio NO:H{sub 2}?=?1:1.3 and a GHSV of 4500 h{sup ?1}. Promotion with Pt increases the catalytic performances of the Ni based catalyst, in respect to NO conversion, N{sub 2} selectivity and N{sub 2} yield. The reaction temperatures for NO conversion above 95% decrease significantly due to Pt addition, from 250°C for Ni/Al{sub 2}O{sub 3} to 125°C for Ni-Pt/Al{sub 2}O{sub 3}. Characterization of catalysts was performed by: X ray powder diffraction (XRD) for the estimation of Ni crystallite size, temperature programmed reduction (TPR) for the catalyst reducibility, temperature programmed desorption of hydrogen (H{sub 2}-TPD) for the investigation of active sites and metal dispersion on the support, N{sub 2} adsorption-desorption isotherms at ?196°C for the determination of total specific surface area and pore size distribution, and H/D isotopic exchange on the catalyst surface.

Mihet, Maria, E-mail: maria.mihet@itim-cj.ro; Lazar, Mihaela D., E-mail: maria.mihet@itim-cj.ro; Borodi, G., E-mail: maria.mihet@itim-cj.ro; Almasan, V., E-mail: maria.mihet@itim-cj.ro [National Institute for Research and Development of Isotopic and Molecular Technologies-INCDTIM, 65-103 Donath Str., 400293 Cluj-Napoca (Romania)

2013-11-13T23:59:59.000Z

36

High performance of a carbon supported ternary PdIrNi catalyst for ethanol electro-oxidation in anion-exchange membrane direct ethanol fuel cells  

E-Print Network [OSTI]

-oxidation in anion-exchange membrane direct ethanol fuel cells Shuiyun Shen, T. S. Zhao,* Jianbo Xu and Yinshi Li-exchange membrane direct ethanol fuel cells (AEM DEFCs). We demonstrate that the use of the ternary PdIrNi catalyst for the ethanol oxidation reaction (EOR) in anion-exchange membrane direct ethanol fuel cells (AEM DEFCs) offers

Zhao, Tianshou

37

Exploitation of a Self-limiting Process for Reproducible Formation of Ultrathin Ni(1-x)Pt(x) Silicide Films  

SciTech Connect (OSTI)

This letter reports on a process scheme to obtain highly reproducible Ni{sub 1-x}Pt{sub x} silicide films of 3-6 nm thickness formed on a Si(100) substrate. Such ultrathin silicide films are readily attained by sputter deposition of metal films, metal stripping in wet chemicals, and final silicidation by rapid thermal processing. This process sequence warrants an invariant amount of metal intermixed with Si in the substrate surface region independent of the initial metal thickness, thereby leading to a self-limiting formation of ultrathin silicide films. The crystallographic structure, thickness, uniformity, and morphological stability of the final silicide films depend sensitively on the initial Pt fraction.

Z Zhang; B Yang; Y Zhu; S Gaudet; S Rossnagel; A Kellock; A Ozcan; C Murray; P Desjardins; et al.

2011-12-31T23:59:59.000Z

38

Mechanisms Associated with Rumpling of Pt-Modified Beta-NiAl Coatings  

SciTech Connect (OSTI)

The formation of surface undulations (i.e. rumpling) at the bond coat/thermally grown oxide (TGO) interface has been shown to cause failure by spallation of the ceramic top coat in aero-turbine systems. Many mechanisms have been proposed concerning the cause of these surface distortions; however, there is little agreement on what may be the dominating cause of the rumpling behavior. Of there mechanisms, the reversible phase transformation from a cubic {beta}-NiAl structure to a face centered tetragonal (FCT) martensitic phase was of particular interest because of its ability to form surface rumpling in Pt-modified {beta} bulk alloys. However, the bulk alloys used in obtaining that result were simple ternary systems and not relevant to actual coating compositions as other alloying elements enter the coating due to coating/substrate interdiffusion at high temperature. In the current study, the depletion behavior of a commercial coating was studied. Compositions from the depletion path were determined and bulk alloys representing these coating compositions were prepared. The martensitic phase transformation was then characterized using DSC and XRD. The martensitic start temperature on cooling, Ms, was consistently found to be significantly lower than previously reported values (e.g. 530 C vs 100 C). Because of the low Ms temperature, the formation of the martensitic phase was concluded to be unnecessary for the occurrence of rumpling. However, cyclic exposure treatments at low temperature ({approx} 400 C) of bulk alloys and commercial coatings did show the detrimental effects of the phase transformation in the form of crack formation and propagation leading to eventual failure of the alloys. The current work also infers that the differences in coefficient of thermal expansion (CTE) mismatch between the coating and substrate are the dominating factor leading to rumpling. Dilatometry measurements were made on bulk alloys representing depleted coatings and the superalloy substrate to determine CTE as a function of temperature. Finally, simulations were completed to help determine the role of CTE mismatch. It was found that these results compared closely to those collected during experimental cyclic exposure treatments; although, modification to the current model were found to be needed in order to truly simulate rumpling.

Joseph Peter Henderkott

2007-12-01T23:59:59.000Z

39

Suppression of the spin pumping in Pd/Ni{sub 81}Fe{sub 19} bilayers with nano-oxide layer  

SciTech Connect (OSTI)

We demonstrate that the spin pumping effect can be effectively suppressed with a nano-oxide layer. Spin pumping effect manifests itself by an enhancement of the Gilbert damping parameter in normal metal/ferromagnetic hetero-structures, while many spintronics devices prefer smaller damping parameter. Since the spin pumping effect is directly related with the spin dependent interface conductance, we can modify the spin pumping by altering the interface conductance with the nano-oxide layer. We prepared series of Pd/Ni{sub 81}Fe{sub 19} bilayers with different pausing time between Pd and Ni{sub 81}Fe{sub 19} depositions in order to control the interface conductance. The Gilbert damping parameters are determined from the line-width measurements in the ferromagnetic resonance spectra for each pausing time sample. They are 0.0490, 0.0296, 0.0278, and 0.0251 for 0, 6, 30, and 60 s pausing time, respectively. We find that the damping parameter of Pd/Ni{sub 81}Fe{sub 19} is almost recovered to one of the Cu/Ni{sub 81}Fe{sub 19} bilayer with 60 s pausing time, while the static magnetic properties are not noticeably changed.

Kim, Duck-Ho; Kim, Hong-Hyoun; You, Chun-Yeol [Department of Physics, Inha University, Namgu Incheon 402-751 (Korea, Republic of)

2011-08-15T23:59:59.000Z

40

A theoretical study of the electronic structure of Invar Fe*3Pt and related materials  

SciTech Connect (OSTI)

The Full Potential Linear Augmented Plane Wave (FPLAPW or FLAPW) method is used for a spin-polarized band calculation for ordered Fe{sub 3}Pt. As major purpose, the momentum distributions of the spin-polarized electrons are calculated and compared with results from a magnetic Compton scattering measurement. To get related information, the electronic behavior is also analyzed by examining the partial densities of states and the spatial electron distributions; the role of alloying effects is then explored by studying the electrons in some related alloys: Fe{sub 3}Ni, Fe{sub 3}Pd, Ni{sub 3}Pt and Co{sub 3}Pt.

Zuo, Zhiqi

1997-01-10T23:59:59.000Z

Note: This page contains sample records for the topic "ni pd pt" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Systematics of the temperature-dependent interplane resistivity in Ba(Fe1-xMx)?As? (M=Co, Rh, Ni, and Pd)  

DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

Temperature-dependent interplane resistivity ?c(T) was measured systematically as a function of transition-metal substitution in the iron-arsenide superconductors Ba(Fe1-xMx)?As?, M=Ni, Pd, Rh. The data are compared with the behavior found in Ba(Fe1-xCox)?As?, revealing resistive signatures of pseudogap. In all compounds we find resistivity crossover at a characteristic pseudogap temperature T* from nonmetallic to metallic temperature dependence on cooling. Suppression of T* proceeds very similarly in cases of Ni and Pd doping and much faster than in similar cases of Co and Rh doping. In cases of Co and Rh doping an additional minimum in the temperature-dependent ?c emerges for high dopings, when superconductivity is completely suppressed. These features are consistent with the existence of a charge gap covering part of the Fermi surface. The part of the Fermi surface affected by this gap is notably larger for Ni- and Pd-doped compositions than in Co- and Rh-doped compounds.

Tanatar, M. A.; Ni, N.; Thaler, A.; Bud’ko, S. L.; Canfield, P. C.; Prozorov, R.

2011-07-01T23:59:59.000Z

42

The effect of Au and Ni doping on the heavy fermion state of the Kondo lattice antiferromagnet CePtZn  

SciTech Connect (OSTI)

We have probed the effect of doping CePtZn with Au and Ni and also investigated in detail the magnetic behavior of the iso-structural CeAuZn. A magnetic ground state is observed in both CePt{sub 0.9}Au{sub 0.1}Zn and CePt{sub 0.9}Ni{sub 0.1}Zn with T{sub N}?=?2.1 and 1.1?K and the coefficient of the linear term of electronic heat capacity ??=?0.34 and 0.9?J/mol K{sup 2}, respectively. The corresponding values for CePtZn are 1.7?K and 0.6?J/mol K{sup 2}. The altered values of T{sub N} and ? show that the electronic correlations in CePtZn are affected by doping with Au and Ni. CeAuZn orders magnetically near 1.7?K and its electrical resistivity shows a normal metallic behavior. Together with a ? of 0.022?J/mol K{sup 2} the data indicate a weak 4f-conduction electron hybridization in CeAuZn characteristic of normal trivalent cerium based systems.

Dhar, S. K., E-mail: sudesh@tifr.res.in [DCMPMS, T.I.F.R., Homi Bhabha Road, Colaba, Mumbai 400005 (India); Aoki, Y.; Suemitsu, B.; Miyazaki, R. [Department of Physics, Tokyo Metropolitan University, Minami-Ohsawa 1-1, Hachioji-Shi, Tokyo (Japan); Provino, A.; Manfrinetti, P. [Departimento Physica Chemicale, Universita di Genova, Via Dodecaneso, 16146 Genova (Italy)

2014-05-07T23:59:59.000Z

43

Deep oxidation of methane on particles derived from YSZ-supported Pd-Pt-(O) coatings synthesized by pulsed filtered cathodic arc  

E-Print Network [OSTI]

2009) Deep oxidation of methane on particles derived fromAbstract Methane conversion tests were performed on Pd, PdOFigure captions Figure 1: Methane conversion a), methane

Horwat, D.

2009-01-01T23:59:59.000Z

44

Catalyst and process development for hydrogen preparation from future fuel cell feedstocks. Quarterly progress report, October 1, 1979-December 31, 1979. [Pt/Rh, Ni/Rh, Ni/Pt/Rh, Ni, Ni/Ru, Ni/Pt, Ni/Co  

SciTech Connect (OSTI)

Twelve steam reforming catalysts were evaluated using an autothermal reforming screening unit. Duplicate tests were run with two samples to determine test variability. The samples tested contained either base metals, precious metals, or combinations of base and precious metals. The test was capable of distinguishing among samples where gross variations in composition are the main factor; for example, catalysts containing 2% by weight precious metals are more active than catalysts containing 15% by weight nickel. The results show a decrease in hydrocarbon breakthrough as the weight of nickel charged to the constant volume reactor increases. A commercial nickel catalyst, G90C, appears slightly better than some Engelhard prepared samples of equal nickel concentrations due to the higher density of G90C. Visual observation of the used catalysts show that samples containing only precious metals (Pt/Rh) did not coke during the run. The samples containing only base metals (nickel, cobalt) were coked and were magnetic. Samples containing 14.5% nickel by weight with 0.5% precious metals by weight added were not coked, were not magnetic, and had a blue colored core as compared to the black core of the virgin samples. Some speculation about deactivation mechanisms based on these observations are made.

Yarrington, R M; Feins, I R; Hwang, H S; Mayer, C P

1980-01-01T23:59:59.000Z

45

Chemisorption of atomic oxygen on Pt(1 1 1) and Pt/Ni(1 1 1) surfaces Timo Jacob, Boris V. Merinov, William A. Goddard III *  

E-Print Network [OSTI]

at electrodes provides a significant opportunity for im- proving fuel cell performance. To make progress. Nowadays in PEM fuel cells Pt and Pt-based mate- rials are commonly used to catalyze the reactions Elsevier B.V. All rights reserved. 1. Introduction Optimization of the electro-catalytic processes

Goddard III, William A.

46

Surface tension-driven shape-recovery of micro/nanometer-scale surface features in a Pt(57.5)Ni(5.3)Cu(14.7)P(22.5) metallic glass in the supercooled liquid region: A numerical modeling capability  

E-Print Network [OSTI]

Recent experiments in the literature show that micro/nano-scale features imprinted in a Pt-based metallic glass, Pt57.5Ni5.3Cu14.7P22.5 [Pt subscript 57.5 Ni subscript 5.3 Cu subscript 14.7 P subscript 22.5], using ...

Henann, David Lee

47

Effect of modifier Pd metal on hydrocracking of polyaromatic compounds over Ni-loaded Y-type zeolite and its application as hydrodesulfurization catalysts  

SciTech Connect (OSTI)

Coal tar obtained from coal carbonization is a treasure of polyaromatic hydrocarbons, where more than 400 kinds of aromatic compounds are found to be contained. The development of new catalysts being able to convert these aromatics into mono or diaromatic compounds is one of objectives for utilization of polyaromatics. Hydrocracking of polyaromatic compounds is believed to proceed via formation of terminal-naphthenic ring of starting aromatic compounds, followed by cleavage of the naphthenic ring to produce alkylated aromatic compounds which has less numbers of ring than starting aromatics. Accordingly, hydrogenation of aromatic rings and cracking of resulting naphthenic rings are key steps of hydrocracking reaction, so that dual functional catalysts such as metal-supported acid catalysts are considered to be one of the best catalysts. Zeolite has controlled pore structures and strong acidity enough to crack naphthenic rings, being characteristics in exchanging metal species with ease. We have been studying the hydrocracking of polyaromatic compounds over Ni-loaded zeolite catalysts (ZSM-5, mordenite, and Y-type) and found the fact that pore size of zeolite exerts an interesting effect on product distribution. We also conducted computer-simulation for diffusion phenomena of the polyaromatic hydrocarbons in the pore of these zeolites and found that diffusion ability of the substrate affects strongly the product distributions Recently we found that modifying of Ni-loaded Y-type zeolite by Pd-loading enhanced hydrocracking ability of the catalyst. In this report, we would like to refer to the results of both hydrocracking reaction of pyrene and hydrodesulfurization of dibenzothiophene using Pd-modified Ni-loaded Y-type zeolite.

Wada, Takema; Murata, Satoru; Nomura, Masakatsu [Osaka Univ. (Japan)

1995-12-31T23:59:59.000Z

48

Effect of Thick Film Firing Conditions on the Solderability and Structure of Au-Pt-Pd Conductor for Low-Temperature, Co-Fired Ceramic Substrates  

SciTech Connect (OSTI)

Low-temperature, co-fired ceramics (LTCC) are the substrate material-of-choice for a growing number of multi-chip module (MCM) applications. Unlike the longer-standing hybrid microcircuit technology based upon alumina substrates, the manufacturability and reliability of thick film solder joints on LTCC substrates have not been widely studied. An investigation was undertaken to fully characterize such solder joints. A surface mount test vehicle with Daisy chain electrical connections was designed and built with Dupont{trademark} 951 tape. The Dupont{trademark} 4569 thick film ink (Au76-Pt21 -Pd3 wt.%) was used to establish the surface conductor pattern. The conductor pattern was fired onto the LTCC substrate in a matrix of process conditions that included: (1) double versus triple prints, (2) dielectric frame versus no frame, and (3) three firing temperatures (800 C, 875 C and 950 C). Pads were examined from the test vehicles. The porosity of the thick film layers was measured using quantitative image analysis in both the transverse and short transverse directions. A significant dependence on firing temperature was recorded for porosity. Solder paste comprised of Sn63-Pb37 powder with an RMA flux was screen printed onto the circuit boards. The appropriate components, which included chip capacitors of sizes 0805 up to 2225 and 50 mil pitch, leadless ceramic chip carriers having sizes of 16 I/O to 68 I/O, were then placed on the circuit boards. The test vehicles were oven reflowed under a N{sub 2} atmosphere. The solderability of the thick film pads was also observed to be sensitive to the firing conditions. Solderability appeared to degrade by the added processing steps needed for the triple print and dielectric window depositions. However, the primary factor in solderability was the firing temperature. Solderability was poorer when the firing temperature was higher.

Hernandez, C.L; Vianco, P.T.

1999-03-16T23:59:59.000Z

49

Exploitation of a self-limiting process for reproducible formation of ultrathin Ni{sub 1-x}Pt{sub x} silicide films  

SciTech Connect (OSTI)

This letter reports on a process scheme to obtain highly reproducible Ni{sub 1-x}Pt{sub x} silicide films of 3-6 nm thickness formed on a Si(100) substrate. Such ultrathin silicide films are readily attained by sputter deposition of metal films, metal stripping in wet chemicals, and final silicidation by rapid thermal processing. This process sequence warrants an invariant amount of metal intermixed with Si in the substrate surface region independent of the initial metal thickness, thereby leading to a self-limiting formation of ultrathin silicide films. The crystallographic structure, thickness, uniformity, and morphological stability of the final silicide films depend sensitively on the initial Pt fraction.

Zhang Zhen; Zhu Yu; Rossnagel, Steve; Murray, Conal; Jordan-Sweet, Jean [IBM T.J. Watson Research Center, Yorktown Heights, New York 10598 (United States); Yang, Bin [GlobalFoundries, Inc., T.J. Watson Research Center, Yorktown Heights, New York 10598 (United States); Gaudet, Simon; Desjardins, Patrick [Ecole Polytechnique de Montreal, Montreal, Quebec H3C 3A7 (Canada); Kellock, Andrew J. [IBM Almaden Research Center, San Jose, California 95120 (United States); Ozcan, Ahmet [IBM Microelectronics, Hopewell Junction, New York 12533 (United States); Zhang Shili [Solid-State Electronics, The Angstroem Laboratory, Uppsala University, Box 534, SE-751 21 Uppsala (Sweden); Lavoie, Christian [IBM T.J. Watson Research Center, Yorktown Heights, New York 10598 (United States); Ecole Polytechnique de Montreal, Montreal, Quebec H3C 3A7 (Canada)

2010-12-20T23:59:59.000Z

50

The adhesion of electroless Ni(P) on alumina ceramic using a vacuum-deposited Ti-Pd activator layer  

SciTech Connect (OSTI)

The adhesion of electrolessly deposited nickel on Al[sub 2]O[sub 3] ceramic substrates using sputtered and evaporated Ti-Pd activator films was studied. The adhesion was measured using the direct pull-off test and the 90[degree] peel test. The morphology and the chemical composition of the fracture surfaces of the samples with evaporated Ti-Pd activator film were studied with scanning electron microscopy/energy, dispersive x-ray, and static secondary ion mass spectroscopy. Failure did not occur along the metal-ceramic interface, but mainly in the alumina, and therefore the strength of the system is determined primarily by the substrate material. Cross-sectional transmission electron microscopy and high-resolution transmission electron microscopy were used to study the interface structure before failure. The oxidation state of Ti at the interface was measured with X-ray photoelectron spectroscopy. This was carried out in the (sub)monolayer range by using a Ti wedge deposited on alumina with a maximum thickness of 0.35 nm. It is concluded that the strong adhesion at the metal-ceramic interface is caused by chemical bonding of the first Ti monolayer with substrate oxygen atoms.

Severin, J.W.; Hokke, R.; Wel, H. van der; Johnson, M.T.; With, G. de (Philips Research Labs., Eindhoven (Netherlands))

1993-06-01T23:59:59.000Z

51

Quantum Critical Fluctuations in the Heavy fermion compound Ce(Ni0.935Pd0.065)2Ge2  

SciTech Connect (OSTI)

Electric resistivity, specific heat, magnetic susceptibility, and inelastic neutron scattering experi- ments were performed on a single crystal of the heavy fermion compound Ce(Ni0.935Pd0.065)2Ge2 in order to study the spin fluctuations near an antiferromagnetic (AF) quantum critical point (QCP). The resistivity and the specific heat coefficient for T = 1 K exhibit the power law behavior expected for a 3D itinerant AF QCP (?(T) ~ T^3/2 and ?(T) ~ ?0 -bT^1/2). However, for 2 = T = 10 K, the susceptibility and specific heat vary as logT and the resistivity varies linearly with temperature. Furthermore, despite the fact that the resistivity and specific heat exhibit the non-Fermi liquid behavior expected at a QCP, the correlation length, correlation time, and staggered susceptibility of the spin fluctuations remain finite at low temperature. We suggest that these deviations from the divergent behavior expected for a QCP may result from alloy disorder.

C. H. Wang; L. Poudel; A. E. Taylor; J. M. Lawrence; A. D. Christianson; S. Chang; J. A. Rodriguez-Rivera; J. W. Lynn; A. A. Podlesnyak; G. Ehlers; R. E. Baumbach; E. D. Bauer; K. Gofryk; F. Ronning; K. J. McClellan; J. D. Thompson

2014-12-01T23:59:59.000Z

52

Oxidation of Methanol on 2nd and 3rd Row Group VIII Transition Metals (Pt, Ir, Os, Pd, Rh, and Ru): Application to Direct Methanol  

E-Print Network [OSTI]

to electric energy in a hydrogen/oxygen fuel cell was demon- strated. Although hydrogen/oxygen fuel cells): Application to Direct Methanol Fuel Cells Jeremy Kua and William A. Goddard III* Contribution from and designing new catalysts. We find that methanol dehydrogenation is most facile on Pt, with the hydrogens

Goddard III, William A.

53

Kinetic Characterization of PtRu Fuel Cell Anode Catalysts Made by Spontaneous Pt Deposition on Ru Nanoparticles  

E-Print Network [OSTI]

rotating disk electrode without using Nafion film to stabilize them. Nonlinear fittings of the entire for a polycrystalline Pt electrode. For the PtRu20 , PtRu10 , and PtRu5 samples prepared by spontaneous deposition of 1 spontaneous deposition of Pt4 and Pd5 on Ru-single crystals, which facilitates a new method

Brankovic, Stanko R.

54

Catalyst and process development for hydrogen preparation from future fuel cell feedstocks. Quarterly report, April 1-June 30, 1980. [Pt/Pd  

SciTech Connect (OSTI)

Phase II of the contract, which involved catalyst preparation and evaluation, was nearly completed this quarter. Phase III, which calls for the design and construction of a fuel processor, was started. During the quarter, four types of tests were run on the small scale catalyst screening unit. The operating line for coke-free operations was found to be approximately between 0.41 to 0.44 O/sub 2//C level. Screening at lower O/sub 2//C levels led to problems with plugging. In other tests, increased severity for screening steam reforming catalysts was obtained by doubling the space velocity. Another series of tests were run to determine the gas composition from the catalytic partial oxidation (CPO) section and to evaluate two CPO catalysts. In the other series of tests, catalysts were aged for about 20 hours using a propane, steam, and air mixture before testing with No. 2 oil for another five hours. This latter test has been used to study Pt/Rh catalysts made with various supports. Differences were readily determined for Pt/Rh supported on alpha alumina and Pt/Rh supported on stabilized alumina. This test method will find continued use in evaluating metal-support interactions. Several samples must be evaluated by this method before aging runs are made in the larger unit. After leaching alumina from a used Pt/Rh catalyst, the x-ray diffraction pattern showed the presence of a Pt-Rh alloy in the metal residue. Experiments were run to show that the alloy was formed in the reactor during testing and not during catalyst preparation. A larger version of the ATR reactor has been designed and major components are on order. Completion of the construction phase is scheduled for the next quarter.

Yarrington, R M; Feins, I R; Hwang, H S

1980-07-01T23:59:59.000Z

55

Durable pd-based alloy and hydrogen generation membrane thereof  

DOE Patents [OSTI]

A durable Pd-based alloy is used for a H.sub.2-selective membrane in a hydrogen generator, as in the fuel processor of a fuel cell plant. The Pd-based alloy includes Cu as a binary element, and further includes "X", where "X" comprises at least one metal from group "M" that is BCC and acts to stabilize the .beta. BCC phase for stability during operating temperatures. The metal from group "M" is selected from the group consisting of Fe, Cr, Nb, Ta, V, Mo, and W, with Nb and Ta being most preferred. "X" may further comprise at least one metal from a group "N" that is non-BCC, preferably FCC, that enhances other properties of the membrane, such as ductility. The metal from group "N" is selected from the group consisting of Ag, Au, Re, Ru, Rh, Y, Ce, Ni, Ir, Pt, Co, La and In. The at. % of Pd in the binary Pd--Cu alloy ranges from about 35 at. % to about 55 at. %, and the at. % of "X" in the higher order alloy, based on said binary alloy, is in the range of about 1 at. % to about 15 at. %. The metals are selected according to a novel process.

Benn, Raymond C. (Madison, CT); Opalka, Susanne M. (Glastonbury, CT); Vanderspurt, Thomas Henry (Glastonbury, CT)

2010-02-02T23:59:59.000Z

56

Comparison of [Ni(PPh2NPh2)2(CH3CN)]2+ and [Pd(PPh2NPh2)2]2+ as Electrocatalysts for H2 Production  

SciTech Connect (OSTI)

The complexes [Ni(PPh2NPh2)2(CH3CN)]2+ and [Pd(PPh2NPh2)2]2+, where PPh2NPh2 is 1,5-diphenyl-3,7-diphenyl-1,5-diaza-3,7-diphosphacyclooctane, are compared as electrocatalysts for H2 production under identical experimental conditions. With [(DMF)H]+ as the acid in acetonitrile solution, [Pd(PPh2NPh2)2]2+ afforded a turnover frequency (TOF) of 230 s-1 for formation of H2 under dry conditions and a TOF of 640 s-1 when H2O was added. These rates are similar to the TOF’s of 590 s-1 (dry) and 720 s-1 (wet) that were previously measured for [Ni(PPh2NPh2)2(CH3CN)]2+ using [(DMF)H]+. The [Ni(PPh2NPh2)2(CH3CN)]2+ and [Pd(PPh2NPh2)2]2+ complexes both exhibited large current enhancements when treated with trifluoroacetic acid (TFA). At a TFA concentration of 1.8 M, TOF values of 5670 s-1 and 2060 s-1 were measured for [Ni(PPh2NPh2)2(CH3CN)]2+ and [Pd(PPh2NPh2)2]2+, respectively. The fast rates observed using TFA are, in part, attributed to homoconjugation of TFA in acetonitrile solutions, which decreases the effective pKa of the acid. In support of this hypothesis, dramatically lower rates of H2 production were observed using p anisidinium, which has a pKa comparable to TFA but does not homoconjugate significantly in acetonitrile solutions. This research was supported as part of the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences. Pacific Northwest National Laboratory is oper-ated by Battelle for the U.S. Department of Energy.

Wiedner, Eric S.; Helm, Monte L.

2014-09-22T23:59:59.000Z

57

An analysis of the pull strength behaviors of fine-pitch, flip chip solder interconnections using a Au-Pt-Pd thick film conductor on Low-Temperature, Co-fired Ceramic (LTCC) substrates.  

SciTech Connect (OSTI)

The assembly of the BDYE detector requires the attachment of sixteen silicon (Si) processor dice (eight on the top side; eight on the bottom side) onto a low-temperature, co-fired ceramic (LTCC) substrate using 63Sn-37Pb (wt.%, Sn-Pb) in a double-reflow soldering process (nitrogen). There are 132 solder joints per die. The bond pads were gold-platinum-palladium (71Au-26Pt-3Pd, wt.%) thick film layers fired onto the LTCC in a post-process sequence. The pull strength and failure modes provided the quality metrics for the Sn-Pb solder joints. Pull strengths were measured in both the as-fabricated condition and after exposure to thermal cycling (-55/125 C; 15 min hold times; 20 cycles). Extremely low pull strengths--referred to as the low pull strength phenomenon--were observed intermittently throughout the product build, resulting in added program costs, schedule delays, and a long-term reliability concern for the detector. There was no statistically significant correlation between the low pull strength phenomenon and (1) the LTCC 'sub-floor' lot; (2) grit blasting the LTCC surfaces prior to the post-process steps; (3) the post-process parameters; (4) the conductor pad height (thickness); (5) the dice soldering assembly sequence; or (5) the dice pull test sequence. Formation of an intermetallic compound (IMC)/LTCC interface caused by thick film consumption during either the soldering process or by solid-state IMC formation was not directly responsible for the low-strength phenomenon. Metallographic cross sections of solder joints from dice that exhibited the low pull strength behavior, revealed the presence of a reaction layer resulting from an interaction between Sn from the molten Sn-Pb and the glassy phase at the TKN/LTCC interface. The thick film porosity did not contribute, explicitly, to the occurrence of reaction layer. Rather, the process of printing the very thin conductor pads was too sensitive to minor thixotropic changes to ink, which resulted in inconsistent proportions of metal and glassy phase particles present during the subsequent firing process. The consequences were subtle, intermittent changes to the thick film microstructure that gave rise to the reaction layer and, thus, the low pull strength phenomenon. A mitigation strategy would be the use of physical vapor deposition (PVD) techniques to create thin film bond pads; this is multi-chip module, deposited (MCM-D) technology.

Uribe, Fernando R.; Kilgo, Alice C.; Grazier, John Mark; Vianco, Paul Thomas; Zender, Gary L.; Hlava, Paul Frank; Rejent, Jerome Andrew

2008-09-01T23:59:59.000Z

58

Pull strength evaluation of Sn-Pb solder joints made to Au-Pt-Pd and Au thick film structures on low-temperature co-fired ceramic -final report for the MC4652 crypto-coded switch (W80).  

SciTech Connect (OSTI)

A study was performed that examined the microstructure and mechanical properties of 63Sn-37Pb (wt.%, Sn-Pb) solder joints made to thick film layers on low-temperature co-fired (LTCC) substrates. The thick film layers were combinations of the Dupont{trademark} 4596 (Au-Pt-Pd) conductor and Dupont{trademark} 5742 (Au) conductor, the latter having been deposited between the 4596 layer and LTCC substrate. Single (1x) and triple (3x) thicknesses of the 4596 layer were evaluated. Three footprint sizes were evaluated of the 5742 thick film. The solder joints exhibited excellent solderability of both the copper (Cu) lead and thick film surface. In all test sample configurations, the 5742 thick film prevented side wall cracking of the vias. The pull strengths were in the range of 3.4-4.0 lbs, which were only slightly lower than historical values for alumina (Al{sub 2}O{sub 3}) substrates. General (qualitative) observations: (a) The pull strength was maximized when the total number of thick film layers was between two and three. Fewer that two layers did not develop as strong of a bond at the thick film/LTCC interface; more than three layers and of increased footprint area, developed higher residual stresses at the thick film/LTCC interface and in the underlying LTCC material that weakened the joint. (b) Minimizing the area of the weaker 4596/LTCC interface (e.g., larger 5742 area) improved pull strength. Specific observations: (a) In the presence of vias and the need for the 3x 4596 thick film, the preferred 4596:5742 ratio was 1.0:0.5. (b) For those LTCC components that require the 3x 4596 layer, but do not have vias, it is preferred to refrain from using the 5742 layer. (c) In the absence of vias, the highest strength was realized with a 1x thick 5742 layer, a 1x thick 4596 layer, and a footprint ratio of 1.0:1.0.

Uribe, Fernando; Vianco, Paul Thomas; Zender, Gary L.

2006-06-01T23:59:59.000Z

59

Surface Science Letters Spontaneous deposition of Pd on a Ru(0 0 0 1) surface  

E-Print Network [OSTI]

deposition of Pd on a Pt(1 1 1) electrode, monolayer [3], or submonolayer [4,7] coverages were reportedSurface Science Letters Spontaneous deposition of Pd on a Ru(0 0 0 1) surface S.R. Brankovic, J. Mc March 2001 Abstract Spontaneous deposition of Pd on a Ru(0 0 0 1) single crystal surface has been

Brankovic, Stanko R.

60

Fabrication and local laser heating of freestanding Ni{sub 80}Fe{sub 20} bridges with Pt contacts displaying anisotropic magnetoresistance and anomalous Nernst effect  

SciTech Connect (OSTI)

In spin caloritronics, ferromagnetic samples subject to relatively large in-plane temperature gradients ?T have turned out to be extremely interesting. We report on a preparation technique that allows us to create freely suspended permalloy/Pt hybrid structures where a scanning laser induces ?T on the order of a few K/?m. We observe both the anisotropic magnetoresistance at room temperature and the magnetic field dependent anomalous Nernst effect under laser heating. The technique is promising for the realization of device concepts considered in spin caloritronics based on suspended ferromagnetic nanostructures with electrical contacts.

Brandl, F.; Grundler, D., E-mail: grundler@ph.tum.de [Lehrstuhl für Physik funktionaler Schichtsysteme, Physik-Department E10, Technische Universität München, James-Franck-Str. 1, D-85748 Garching b. München (Germany)

2014-04-28T23:59:59.000Z

Note: This page contains sample records for the topic "ni pd pt" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Effect of Spin-Crossover-Induced Pore Contraction on CO{sub 2}-Host Interactions in the Porous Coordination Polymers [Fe(pyrazine)M(CN){sub 4}] (M = Ni, Pt)  

SciTech Connect (OSTI)

Variable-temperature in situ ATR-FTIR spectra are presented for the porous spin-crossover compounds [Fe(pyrazine)- Ni(CN){sub 4}] and [Fe(pyrazine)Pt(CN){sub 4}] under CO{sub 2} pressures of up to 8 bar. Significant shifts in the ?{sub 3} and ?{sub 2} IR absorption bands of adsorbed CO{sub 2} are observed as the host materials undergo transition between low- and high-spin states. Computational models used to determine the packing arrangement of CO{sub 2} within the pore structures show a preferred orientation of one of the adsorbed CO{sub 2} molecules with close O=C=O···H contacts with the pyrazine pillar ligands. The interaction is a consequence of the commensurate distance of the inter-pyrazine separations and the length of the CO{sub 2} molecule, which allows the adsorbed CO{sub 2} to effectively bridge the pyrazine pillars in the structure. The models were used to assign the distinct shifts in the IR absorption bands of the adsorbed CO{sub 2} that arise from changes in the O=C=O···H contacts that strengthen and weaken in correlation with changes in the Fe–N bond lengths as the spin state of Fe changes. The results indicate that spin-crossover compounds can function as a unique type of flexible sorbent in which the pore contractions associated with spin transition can affect the strength of CO{sub 2}–host interactions.

Culp, Jeffrey T.; Chen, De-Li; Liu, Jinchen; Chirdon, Danielle; Kauffman, Kristi; Goodman, Angela; Johnson, J. Karl

2013-02-01T23:59:59.000Z

62

LEED crystallography studies of the structure of clean and adsorbate-covered Ir, Pt and Rh crystal surfaces  

SciTech Connect (OSTI)

There have only been a few Low Energy Electron Diffraction (LEED) intensity analyses carried out to determine the structure of molecules adsorbed on metal surfaces; most surface crystallography studies concentrated on the structure of clean unreconstructed or atomic adsorbate-covered transition metal faces. The few molecular adsorption systems already investigated by dynamical LEED are CO on Ni(100), Cu(100) and Pd(100) as well as C/sub 2/H/sub 2/ and C/sub 2/H/sub 4/ adsorbed on Pt(111). The emphasis of this thesis research has been to extend the applicability of LEED crystallography to the more complicated unit cells found in molecular overlayers on transition metals or in there constructed surfaces of clean transition metals.

Koestner, R.J.

1982-08-01T23:59:59.000Z

63

Investigation of the electrocatalysis for oxygen reduction reaction by Pt and binary Pt alloys: an XRD, XAS and electrochemical study  

SciTech Connect (OSTI)

Electrocatalysis for the oxygen reduction reaction (ORR) on five binary Pt alloy electrocatalysts (PtCr/C, PtMn/C, PtFe/C, PtCo/C and PtNi/C) supported on carbon have been investigated. The electrochemical characteristics for ORR in a proton conducting fuel cell environment has been correlated with the electronic and structural parameters determined under in situ conditions using XANES and EXAFS technique respectively. Results indicate that all the alloys possess higher Pt 5d band vacancies as compared to Pt/C. There is also evidence of lattice contraction in the alloys (supported by XRD results). Further, the Pt/C shows increase in Pt 5 d band vacancies during potential transitions from 0.54 to 0.84 V vs. RHE, which has been ration@ on the basis of OH type adsorption. In contrast to this, the alloys do not exhibit such an enhancement. Detailed EXAFS analysis supports the presence of OH species on Pt/C and its relative absence in the alloys. Correlation of the electrochemical results with bond distances and d-band vacancies show a volcano type behavior with the PtCr/C on top of the curve.

Mukerjee, S.; McBreen, J. [Brookhaven National Lab., Upton, NY (United States); Srinivasan, S. [Texas A and M Univ., College Station, TX (United States). Texas Engineering Experiment Station

1995-12-31T23:59:59.000Z

64

alloying ni yoru: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

memory alloy Elastic modulus Wrinkling Thermoelastic strain in a polycrystalline Fe-Pd thin film 213 (X?1.5) Alloys 1 CiteSeer Summary: A series Ni41-xMn50Sn9+x of Heusler...

65

alloy films ni: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

memory alloy Elastic modulus Wrinkling Thermoelastic strain in a polycrystalline Fe-Pd thin film 22 Magnetic and Structural Properties of Ni-Mn-Ga Films Produced Via Physical...

66

Fuel cell with Pt/Pd electrocatalyst electrode  

DOE Patents [OSTI]

An electrode for use in a phosphoric acid fuel cell comprising a graphitized or partially graphitized carbon support having a platinum/palladium electrocatalyst thereon. Preferably, the platinum/palladium catalyst comprises 20 to 65 weight percent palladium.

Stonehart, Paul (Madison, CT)

1983-01-01T23:59:59.000Z

67

Novel Mg-rich materials for hydrogen storage: bulk and nanoconfined Mg6Pd1-xTMx  

E-Print Network [OSTI]

Novel Mg-rich materials for hydrogen storage: bulk and nanoconfined Mg6Pd1-xTMx (TM = Ni, Ag, Cu for hydrogen storage: bulk and nanoconfined Mg6Pd1-xTMx (TM = Ni, Ag, Cu) compounds and MgH2-TiH2 on Hydrogen Storage) and in Warsaw (E-MRS Fall Meeting). I would like to share this PhD thesis with all

Paris-Sud XI, Université de

68

Synthesis and characterization of Pd(0), PdS, and Pd-PdO core-shell nanoparticles by solventless thermolysis of a Pd-thiolate cluster  

SciTech Connect (OSTI)

Colloids of palladium nanoparticles have been prepared by the solvated metal atom dispersion (SMAD) method. The as-prepared Pd colloid consists of particles with an average diameter of 2.8{+-}0.1 nm. Digestive ripening of the as-prepared Pd colloid, a process involving refluxing the as-prepared colloid at or near the boiling point of the solvent in the presence of a passivating agent, dodecanethiol resulted in a previously reported Pd-thiolate cluster, [Pd(SC{sub 12}H{sub 25}){sub 2}]{sub 6} but did not render the expected narrowing down of the particle size distribution. Solventless thermolysis of the Pd-thiolate complex resulted in various Pd systems such as Pd(0), PdS, and Pd-PdO core-shell nanoparticles thus demonstrating its versatility. These Pd nanostructures have been characterized using high-resolution electron microscopy and powder X-ray diffraction methods. - Graphical abstract: Solventless thermolysis of a single palladium-thiolate cluster affords various Pd systems such as Pd(0), Pd-PdO core-shell, and PdS nanoparticles demonstrating the versatility of the precursor and the methodology.

Jose, Deepa [Department of Inorganic and Physical Chemistry, Indian Institute of Science, Bangalore 560 012 (India); Jagirdar, Balaji R., E-mail: jagirdar@ipc.iisc.ernet.i [Department of Inorganic and Physical Chemistry, Indian Institute of Science, Bangalore 560 012 (India)

2010-09-15T23:59:59.000Z

69

Investigation of Pt, Pt3Co, and Pt3CoMo Cathodes for the ORR in a Microfluidic H2O2 Fuel Cell  

E-Print Network [OSTI]

-based chalcogenides,5-7 metal oxides,8 transition carbides,9 cobalt­polypyrole­carbon composites,10 enzymes,11 with transition metals i.e., M = Co, Ni, Fe, Cu, etc. not only re- duces catalyst costs by lowering Pt loading to leaching of the transition metals from the alloys.2,28 According to Gasteiger et al., transition-metal

Kenis, Paul J. A.

70

IEEE TRANSACTIONS ON MAGNETICS, VOL. 38, NO. 4, JULY 2002 1803 New Ni5Al3 Underlayer for Longitudinal  

E-Print Network [OSTI]

IEEE TRANSACTIONS ON MAGNETICS, VOL. 38, NO. 4, JULY 2002 1803 New Ni5Al3 Underlayer--We describe a new Ni5Al3 underlayer for high-den- sity longitudinal magnetic recording. The Ni5Al3 underlayer has the FCC derivative Ga3Pt5 structure. The Ni5Al3 (221) plane has good lattice match with the Co

Laughlin, David E.

71

Author's personal copy CO/NO and CO/NO/O2 reactions over a AuPd single crystal catalyst  

E-Print Network [OSTI]

Model catalyst CO oxidation NO reduction Surface segregation Polarization modulation Infrared reflection 0) model catalyst at near atmospheric pressures. The alloy catalyst exhibits higher CO2 formation of Pd- only TWCs is near that of Pt/Rh TWCs, it is preferred since Rh is not required. Moreover, Pd

Goodman, Wayne

72

Carbon-Supported bimetallic Pd-Fe catalysts for vapor-phase hydrodeoxygenation of guaiacol  

SciTech Connect (OSTI)

Abstract Carbon supported metal catalysts (Cu/C, Fe/C, Pd/C, Pt/C, PdFe/C and Ru/C) have been prepared, characterized and tested for vapor-phase hydrodeoxygenation (HDO) of guaiacol (GUA) at atmospheric pressure. Phenol was the major intermediate on all catalysts. Over the noble metal catalysts saturation of the aromatic ring was the major pathway observed at low temperature (250 °C), forming predominantly cyclohexanone and cyclohexanol. Substantial ring opening reaction was observed on Pt/C and Ru/C at higher reaction temperatures (e.g., 350 °C). Base metal catalysts, especially Fe/C, were found to exhibit high HDO activity without ring-saturation or ring-opening with the main products being benzene, phenol along with small amounts of cresol, toluene and trimethylbenzene (TMB). A substantial enhancement in HDO activity was observed on the PdFe/C catalysts. Compared with Fe/C, the yield to oxygen-free aromatic products (i.e., benzene/toluene/TMB) on PdFe/C increased by a factor of four at 350 °C, and by approximately a factor of two (83.2% versus 43.3%) at 450 °C. The enhanced activity of PdFe/C is attributed to the formation of PdFe alloy as evidenced by STEM, EDS and TPR.

Sun, Junming; Karim, Ayman M.; Zhang, He; Kovarik, Libor; Li, Xiaohong S.; Hensley, Alyssa; McEwen, Jean-Sabin; Wang, Yong

2013-10-01T23:59:59.000Z

73

Pd/Ni-WO3 anodic double layer gasochromic device  

DOE Patents [OSTI]

An anodic double layer gasochromic sensor structure for optical detection of hydrogen in improved response time and with improved optical absorption real time constants, comprising: a glass substrate; a tungsten-doped nickel oxide layer coated on the glass substrate; and a palladium layer coated on the tungsten-doped nickel oxide layer.

Lee, Se-Hee; Tracy, C. Edwin; Pitts, J. Roland; Liu, Ping

2004-04-20T23:59:59.000Z

74

The Surface Organometallic Chemistry of Pd Electrodes: Studies with Aromatic Compounds  

E-Print Network [OSTI]

voltammogram between adsorbed and un-adsorbed 2,5- dihydroxythiophenol (DHT) shows that both have reversible redox peaks with similar potentials. This result confirmed the electroactivity of the diphenol group of DHT. However, the voltammetric curve of Pt... to interact for a redox reaction. The Pd electrode also provides a venue for charge-transfer between two DHT molecules. Figure 4 shows the cyclic voltammogram of chemisorbed DHT on a Pd electrode. In the cathodic scan, the peak is broader than the 20...

Cruz, Juan

2012-10-19T23:59:59.000Z

75

JUNE 13-PD.xlsx  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

No I-00516-0005 22-2&3-PD 083095 ISSUANCE OF MODIFICATION 9 TO KENTUCKY HAZARDOUS WASTE MANAGEMENT PERMIT - PGDP KDEP DOE-PAD, ERWM SITE MANAGER, BETHESDA MD, USEC No...

76

Highly durable graphene nanoplatelets supported Pt nanocatalysts...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

durable graphene nanoplatelets supported Pt nanocatalysts for oxygen reduction . Highly durable graphene nanoplatelets supported Pt nanocatalysts for oxygen reduction . Abstract:...

77

August 2000 Z .Materials Letters 45 2000 128132  

E-Print Network [OSTI]

. TiNiHf alloys exhibit better shape memory properties than other TiNiX Z .XsPt, Pd, Au, Zr and Ni­132 129 Fig. 1. Schematic illustration for the SME measurement in the bending test. electrode

Zheng, Yufeng

78

Infrared study on the adsorption of CO and NO on silica-supported Pd and Pt-Pd  

SciTech Connect (OSTI)

The IR spectra of NO adsorbed on silica-supported palladium had bands at 1735 and 1645/cm, which were assigned to linearly bound NO and to NO linearly bound to low-coordinated palladium, respectively. Bands at 1980 and 2070/cm in the spectrum of CO adsorbed on palladium were assigned multiply coordinated and linear CO, respectively. Carbon monoxide was completely displaced from palladium by nitric oxide, preadsorbed nitric oxide was partly displaced from palladium by carbon monoxide, and carbon dioxide and nitrous oxide were formed in both processes. A band at 2180/cm provided evidence for adsorbed isocyanate species. All bands shifted to higher frequencies by approx. 10/cm for 1:1 palladium/platinum bimetallic clusters; the carbon monoxide was readily removed by evacuating at room temperature, a fact that my be used in catalyst surface area determinations.

Grill, C.M.; Gonzalez, R.D.

1980-04-17T23:59:59.000Z

79

Hydrogen Dissociation on Pd4S Surfaces  

SciTech Connect (OSTI)

Exposure of Pd-based hydrogen purification membranes to H,S. a common contaminant in coal gasification streams, can cause membrane performance to deteriorate, either by deactivating surface sites required for dissociative H, adsorption or by forming a low-permeability sulfide scale. In this work. the composition, structure, and catalytic activity of Pd4S, a surface scale commonly observed in Pd-membrane separation of hydrogen from sulfur-containing gas streams, were examined using a combination of experimental characterization and density functional theory (DFT) calculations. A Pd,S sample was prepared by exposing a 100 f1m Pd foil to H2S at 908 K. Both X-ray photoemission depth profiling and low energy ion scattering spectroscopic (LEISS) analysis reveal slight sulfur-enrichment of the top surface of the sample. This view is consistent with the predictions of DFT atomistic thermodynamic calculations. which identified S-terminated Pd,S surfaces as energetically favored over corresponding Pd-terminated surfaces. Activation barriers for H2 dissociation on the Pd,S surfaces were calculated. Although barriers are higher than on Pd(lll). transition state theory analysis identified reaction pathways on the S-terminated surfaces for which hydrogen dissociation rates are high enough to sustain the separation process at conditions relevant to gasification applications.

Miller, J.B.; Alfonso, D.R.; Howard, B.H.; O'Brien, C.P.; Morreale, B.D.

2009-01-01T23:59:59.000Z

80

UCSF PD Emergency Management Division UCSF PD Website: http://police.ucsf.edu/  

E-Print Network [OSTI]

UCSF PD Emergency Management Division UCSF PD Website: http://police.ucsf.edu/ Emergency Kit 2014.doc Version Date: 02 2014 Emergency Preparedness Kit Suggestions You can purchase premade emergency kits and supplies. UCSF PD has contracted with Your Safety Place to offer specially priced disaster

Derisi, Joseph

Note: This page contains sample records for the topic "ni pd pt" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Morphological Stability and Specific Resistivity of sub-10 nm Silicide Films of Ni1 xPtx on Si Substrate  

SciTech Connect (OSTI)

This letter studies the morphological stability and specific resistivity of sub-10 nm silicide films of Ni, Ni{sub 0.95}Pt{sub 0.05}, and Ni{sub 0.9}Pt{sub 0.1} formed on Si(100) substrate. When the deposited metal films are below 1 to 4 nm in thickness depending on the Pt content, the resultant silicide films tend to become epitaxially aligned to the Si substrate and hence exhibit an extraordinary morphological stability up to 800 C. The presence of Pt in the silicides increases the film resistivity through alloy scattering, but alleviates, owing to a reduced electron mean free path, the frequently encountered sharp increase in resistivity in the sub-10 nm regime.

Zhang, Z.; Zhang, S; Yang, B; Zhu, Y; Rossnagel, S; Gaudet, S; Kellock, A; Jordan-Sweet, J; Lavoie, C

2010-01-01T23:59:59.000Z

82

Development and characterization of PdCr temperature-compensaated wire resistance strain gage  

SciTech Connect (OSTI)

A temperature-compensated resistance static strain gage with potential to be used to 600 C was recently developed. Gages were fabricated from specially developed palladium-13 w/o chromium (Pd-13Cr) wire and platinum (Pt) compensator. When bonded to high temperature Hastelloy X, the apparent strain from room temperature to 600 C was within 400 microstrain for gages with no preheat treatment and within 3500 microstrain for gages with 16 hours prestabilization at 640 C. The apparent strain versus temperature relationship of stabilized PdCr gages were repeatable with the reproducibility within 100 microstrain during three thermal cycles to 600 C and an 11 hours soak at 600 C. The gage fabrication, construction and installation is described. Also, the coating system used for this compensated resistance strain gage is explained. The electrical properties of the strain sensing element and main characteristics of the compensated gage including apparent strain, drift and reproducibility are discussed.

Lei, J.F.

1989-10-01T23:59:59.000Z

83

Role of metal components in Pd?Cu bimetallic catalysts supported on CeO2 for the oxygen-enhanced water gas shift  

SciTech Connect (OSTI)

Catalytic hydrogen production and CO removal in a post-reforming process are critical for low-temperature fuel cell applications. The present study aims at clarifying the role of metal components in bimetallic catalysts for oxygen-enhanced water gas shift (OWGS), wherein a small amount of O{sub 2} is added to H{sub 2}-rich reformate gas to enhance CO shift. Among CeO{sub 2}-supported bimetallic catalysts, Pd-Cu and Pt-Cu combinations were found to show strong synergetic promoting effect in OWGS, which leads to much higher CO conversion and higher H{sub 2} yield than WGS at low temperature around 250 C. Temperature programmed reduction (TPR) showed strong interaction between Pd and Cu in Pd-Cu/CeO{sub 2} by a single reduction peak in contrast to multiple peaks on monometallic Cu/CeO{sub 2}. Extended X-ray absorption fine structure (EXAFS) analysis revealed that such bimetallic Pd-Cu and Pt-Cu form alloy nanoparticles, where noble metal is mainly surrounded by Cu atoms. Oxygen storage capacity (OSC) measurements point to higher resistance of Pd-Cu to oxidation indicating that Pd keeps Cu in reduced state in air pulse condition. From kinetic study, Pd in Pd-Cu was found to promote CO shift, rather than CO oxidation by increasing the number of active sites and by suppressing H{sub 2} activation (that is inherent to monometallic Pd), which minimizes both the inhibition effect of H{sub 2} and the loss of H{sub 2} by oxidation in OWGS. Transient response technique revealed that Cu in Pd-Cu enhances desorption of strongly chemisorbed CO{sub 2} on catalyst surface in contrast to very slow CO{sub 2} desorption from surface of monometallic Pd. Thus, the excellent OWGS activity of Pd-Cu catalyst has been attributed to the complementary roles of the two metals for enhancing CO shift, which is realized by its alloy structure and the accompanying strong interaction between metal components.

Kugai, J.; Miller, J. T.; Guo, N.; Song, C. (Chemical Sciences and Engineering Division); ( PSC-USR); (Penn State Univ.)

2011-06-01T23:59:59.000Z

84

Supporting Information Localized Pd Overgrowth on Cubic Pt Nanocrystals for Enhanced  

E-Print Network [OSTI]

. For CO stripping experiments, CO gas (Praxair, 99.99%) was bubbled at an open circuit through 0.5 M H2SO4

Yang, Peidong

85

Tailoring Silica-alumina Supported Pt-Pd As Poison Tolerant Catalyst...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

the efficiency of the catalyst in the presence of sulfur. Citation: Yu Y, OY Gutierrez, GL Haller, RJ Colby, BC Kabius, JA Rob van Veen, A Jentys, and JA Lercher.2013."Tailoring...

86

E-Print Network 3.0 - ammonia oxidation pt--pd--rd Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

ammonia emissions... gaseous ammonia (NH3) which through chemical reaction in rainwater changes into ammonium ion (NH4 Source: Aneja, Viney P. - Department of Marine,...

87

Dissociative Adsorption of Methane on Surface Oxide Structures of Pd-Pt Alloys Arezoo Dianat,*,,  

E-Print Network [OSTI]

/C ratio of methane, the heat of combustion per mole of generated CO2 is higher than for other fuels

Cuniberti, Gianaurelio

88

au-pt-pd thick film: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

heatingcooling system. Calibrate the sample temperature. Measure the Tg of PS thin film - and compare an ellipsometer with an INSTEC heatingcooling stage so that...

89

Tailoring Silica-alumina Supported Pt-Pd As Poison Tolerant Catalyst For  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security AdministrationcontrollerNanocrystallineForeign ObjectOUR TableE9.security Tag: securityTailoredAromatics

90

Deactivation Mechanisms of Pt/Pd-based Diesel Oxidation Catalysts. | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation Proposed Newcatalyst phasesData Files Data Files 1 EIA BestDavidNERSCPhysicsDeactivation

91

Growth of Epitaxial Thin Pd(111) Films on Pt(111) and Oxygen-Terminated  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFun with Big Sky LearningGetGraphene'sEMSL barium oxide nanoclustersFeO(111)

92

Crystalline Ice Growth on Pt(111) and Pd(111): Nonwetting Growth on a  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation Proposed Newcatalyst phases on γ-Al2O3.WinterCrystal Structurewith

93

Formatted: Footer, Left Formatted: Font: 10 pt  

E-Print Network [OSTI]

Formatted: Space Before: 12 pt, Border: Bottom: (Single solid line, Auto, 0.5 pt Line width) Deleted: Angelis ­ Sacramento Municipal Utility District Anne Gillette ­ California Public Utilities Commission Steven Kelly

94

The formation of PdCx over Pd-based catalysts in vapor-phase vinyl acetate synthesis: does a PdAu alloy catalyst resist carbide formation?  

E-Print Network [OSTI]

­Au alloy catalyst resist carbide formation? Y.-F. Han, D. Kumar, C. Sivadinarayana, A. Clearfield, and D October 2003; accepted 24 February 2004 The formation of Pd carbide (PdCx) during the synthesis of vinyl­Au/SiO2; XRD. 1. Introduction The formation of carbides over supported Pd catalysts was first reported

Goodman, Wayne

95

Rhombohedral AlPt films formed by self-propagating, high temperature synthesis.  

SciTech Connect (OSTI)

High-purity AlPt thin films prepared by self-propagating, high temperature combustion synthesis show evidence for a new rhombohedral phase. Sputter deposited Al/Pt multilayers of various designs are reacted at different rates in air and in vacuum, and each form a new trigonal/hexagonal aluminide phase with unit cell parameters a = 15.571(8) {angstrom}, c = 5.304(1) {angstrom}, space group R-3 (148), and Z, the number of formula units within a unit cell, = 39. The lattice is isostructural to that of the AlPd R-3 lattice as reported by Matkovic and Schubert (Matkovic, 1977). Reacted films have a random in-plane crystallographic texture, a modest out-of-plane (001) texture, and equiaxed grains with dimensions on the order of film thickness.

Adams, David Price; Rodriguez, Mark Andrew; Kotula, Paul Gabriel

2005-11-01T23:59:59.000Z

96

THE EFFECT OF CO ON HYDROGEN PERMEATION THROUGH PD AND INTERNALLY OXIDIZED AND UN-OXIDIZED PD ALLOY MEMBRANES  

SciTech Connect (OSTI)

The H permeation of internally oxidized Pd alloy membranes such as Pd-Al and Pd-Fe, but not Pd-Y alloys, is shown to be more resistant to inhibition by CO(g) as compared to Pd or un-oxidized Pd alloy membranes. The increased resistance to CO is found to be greater at 423 K than at 473 K or 523 K. In these experiments CO was pre-adsorbed onto the membranes and then CO-free H{sub 2} was introduced to initiate the H permeation.

Shanahan, K.; Flanagan, T.; Wang, D.

2010-10-20T23:59:59.000Z

97

PT-Rotations, PT-Spherical Harmonics and the PT-Hydrogen Atom  

E-Print Network [OSTI]

We have constructed a set of non-Hermitian operators that satisfy the commutation relations of the SO(3)-Lie algebra. It is shown that this operators generate rotations in the configuration space and not in the momentum space but in a modified non-Hermitian momentum space. This generators are related with a new type of spherical harmonics that result to be PT-orthonormal. Additionally, we have shown that this operators represent conserved quantities for a non-Hermitian Hamiltonian with an additional complex term. As a particular case, the solutions of the corresponding PT-Hydrogen atom that includes a complex term are obtained, and it is found that a non-Hermitian Runge-Lenz vector is a conserved quantity. In this way, we obtain a set of non-Hermitian operators that satisfy the SO(4)-Lie algebra.

Juan M. Romero; R. Bernal-Jaquez; O. Gonzalez-Gaxiola

2010-01-11T23:59:59.000Z

98

Direct Determination of the Ionization Energies of PtC, PtO, and PtO2 with VUVRadiation  

SciTech Connect (OSTI)

Photoionization efficiency curves were measured for gas-phase PtC, PtO, and PtO2 using tunable vacuum ultraviolet (VUV) radiation at the Advanced Light Source. The molecules were prepared by laser ablation of a platinum tube, followed by reaction with CH4 or N2O and supersonic expansion. These measurements providethe first directly measured ionization energy for PtC, IE(PtC) = 9.45 +- 0.05 eV. The direct measurement also gives greatly improved ionization energies for the platinum oxides, IE(PtO) = 10.0 +- 0.1 eV and IE(PtO2) = 11.35 +- 0.05 eV. The ionization energy connects the dissociation energies of the neutral and cation, leading to greatly improved 0 K bond dissociation energies for the neutrals: D0(Pt-C) = 5.95 +- 0.07 eV, D0(Pt-O)= 4.30 +- 0.12 eV, and D0(OPt-O) = 4.41 +- 0.13 eV, as well as enthalpies of formation for the gas-phase molecules Delta H0 f,0(PtC(g)) = 701 +- 7 kJ/mol, Delta H0f,0(PtO(g)) = 396 +- 12 kJ/mol, and Delta H0f,0(PtO2(g)) = 218 +- 11 kJ/mol. Much of the error in previous Knudsen cell measurements of platinum oxide bond dissociation energies is due to the use of thermodynamic second law extrapolations. Third law values calculated using statistical mechanical thermodynamic functions are in much better agreement with values obtained from ionization energies and ion energetics. These experiments demonstrate that laser ablation production with direct VUV ionization measurements is a versatile tool to measure ionization energies and bond dissociation energies for catalytically interesting species such as metal oxides and carbides.

Citir, Murat; Metz, Ricardo B.; Belau, Leonid; Ahmed, Musahid

2008-07-21T23:59:59.000Z

99

Catalytic studies of supported Pd-Au catalysts  

E-Print Network [OSTI]

reaction conditions is the ultimate goal. This thesis is mainly focused on the application of Pd-Au supported catalysts for vinyl acetate synthesis and CO oxidation reactions using highsurface area catalysts. We have attempted to improve the conventional Pd...

Boopalachandran, Praveenkumar

2006-08-16T23:59:59.000Z

100

Simultaneous deposition of Ni nanoparticles and wires on a tubular halloysite template: A novel metallized ceramic microstructure  

SciTech Connect (OSTI)

Tubular halloysite can be used as a template to fabricate a novel metallized ceramic microstructure through electroless plating. Reduction of Pd ions by methanol is conducted to initiate Ni plating. There is a simultaneous deposition of Ni nanoparticles on the outer surface and discontinuous wires in the lumen site of the halloysite template obtained. The different deposition could be caused by the different composition distribution of ferric oxide impurity in the wall due to the isomorphic substitution during the formation of halloysite template. Its magnetic property is mainly attributed to the Ni nanoparticles, not the wires. The metallized ceramic microstructure has the potential to be utilized as a novel magnetic material.

Fu Yubin [Institute of Solid State Physics, China Academy of Sciences, Hefei 230031 (China) and Luoyang Ship Material Research Institute, Luoyang 471039 (China)]. E-mail: ffyybb725@vip.sina.com; Zhang Lide [Institute of Solid State Physics, China Academy of Sciences, Hefei 230031 (China)

2005-11-15T23:59:59.000Z

Note: This page contains sample records for the topic "ni pd pt" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Pd modified Au on carbon as an effective and durable catalyst for the direct oxidation of HMF to FDCA  

SciTech Connect (OSTI)

We show that the modification of a gold/carbon catalyst with Pt or Pd produces stable and recyclable catalysts for the selective oxidation of 5-hydroxymethylfurfural (HMF) to 2,5-furandicarboxylic acid (FDCA). This finding is a significant advance over current conversion technology because of the technological importance of FDCA. Indeed, FDCA has been identified as one of twelve potential building blocks for the production of value added chemicals derived from biosources.1 FDCA is a potential replacement source of terephthalic acid, the monomer presently used for the production of polyethylene terephthalate (PET) and derived from hydrocarbon sources.2

Villa, Alberto [Universita di Milano, Italy; Schiavoni, Marco [University of Milan and INFN, Milano, Italy; Campisi, Sebastiano [University of Milan and INFN, Milano, Italy; Veith, Gabriel M [ORNL; Prati, Laura [Universita di Milano, Italy

2013-01-01T23:59:59.000Z

102

Design of FePd spring actuators Taishi Wada*  

E-Print Network [OSTI]

. The coil spring made by a FSMA is activated by the attractive magnetic force produced by electromagnets on the above principle by using polycrystalline FePd alloy. Since the stiffness of the FePd coil spring become actuation. Keywords: actuator, coil spring, FePd, wire, ferromagnetic shape memory alloy, superelasticity

Taya, Minoru

103

PD Dr. Martin Stetter, Siemens AG 1 Das lineare Modell  

E-Print Network [OSTI]

PD Dr. Martin Stetter, Siemens AG 1 Das lineare Modell · Ausgangspunkt: Lineares Perceptron vorgegeben, werden nicht gelernt #12;PD Dr. Martin Stetter, Siemens AG 2 · Geschrieben als Regressionsmodell Regression: Lineares Modell #12;PD Dr. Martin Stetter, Siemens AG 3 · ML-Parameterschätzung des linearen

Popeea, Corneliu - Chair for Foundations of Software Reliability and Theoretical Computer Science

104

PT2_US.xls  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the1 - September 2006 TheSteven Ashby Dr. Steven Para buscarBurbank,Nita MPT1. EnergyPT2.

105

Ca{sub 2}Pd{sub 3}Ge, a new fully ordered ternary Laves phase structure  

SciTech Connect (OSTI)

The title compound, Ca{sub 2}Pd{sub 3}Ge, was prepared as a part of a systematic investigation of the Ca-Pd-Ge ternary phase diagram. The structure was determined and refined from single-crystal X-ray diffraction data. It is a new fully ordered ternary Laves phase with the space group R-3m, Z=3, a=5.6191 (5) A, c=12.1674 (7) A, wR{sub 2}=0.054 (all data) and is isostructural to Mg{sub 2}Ni{sub 3}Si (Noreus et al., 1985 [17]) but due to the larger size of all elements in Ca{sub 2}Pd{sub 3}Ge, the cell axes are approximately 10% longer. The compound may formally be considered as a Zintl compound, with [Pd{sub 3}Ge]{sup 4-} forming a poly-anionic network and divalent Ca cations located in truncated tetrahedral interstices. The electronic structure and chemical bonding of Ca{sub 2}Pd{sub 3}Ge is discussed in terms of LMTO band structure calculations and compared with CaPd{sub 2} (MgCu{sub 2}-type). - Graphical abstract: The title compound, Ca{sub 2}Pd{sub 3}Ge is a new fully ordered ternary Laves phase which may formally be considered as a Zintl compound, with [Pd{sub 3}Ge]{sup 4-} forming a poly-anionic network and divalent Ca cations located in truncated tetrahedral interstices. The structure is composed of Kagome net layers, consisting of Pd atoms only, which are stacked in an ABC sequence. Band structure calculations show that the Fermi level is located at a local minimum of the DOS (pseudo-gap) indicating that the charge is roughly optimized in the structure. Highlights: Black-Right-Pointing-Pointer Site specific segregation in a Laves phase that is also a Zintl phase. Black-Right-Pointing-Pointer Pseudo-gap at the Fermi level in a Laves phase. Black-Right-Pointing-Pointer Distorted Frank-Kasper polyhedron.

Doverbratt, Isa, E-mail: isa.doverbratt@polymat.lth.se [Centre for Analysis and Synthesis, Lund University, P.O. Box 124, 22100 Lund (Sweden); Ponou, Simeon; Lidin, Sven [Centre for Analysis and Synthesis, Lund University, P.O. Box 124, 22100 Lund (Sweden)

2013-01-15T23:59:59.000Z

106

In Situ Generation of Pd/PdO Nanoparticle Methane Combustion Catalyst: Correlation of Particle Surface Chemistry with Ignition  

E-Print Network [OSTI]

supported in fixed-bed reactors. The extensive work on the kinetics of Pd oxidation and its relation applications, the typical fixed-bed catalytic reactor approach is not possible because of the high flowIn Situ Generation of Pd/PdO Nanoparticle Methane Combustion Catalyst: Correlation of Particle

Anderson, Scott L.

107

Fabrication of Pd/Pd-Alloy Films by Surfactant Induced Electroless Plating for Hydrogen Separation from Advanced Coal Gasification Processes  

SciTech Connect (OSTI)

Dense Pd, Pd-Cu and Pd-Ag composite membranes on microporous stainless steel substrate (MPSS) were fabricated by a novel electroless plating (EP) process. In the conventional Pd-EP process, the oxidation-reduction reactions between Pd-complex and hydrazine result in an evolution of NH{sub 3} and N{sub 2} gas bubbles. When adhered to the substrate surface and in the pores, these gas bubbles hinder uniform Pd-film deposition which results in dendrite growth leading to poor film formation. This problem was addressed by introducing cationic surfactant in the electroless plating process known as surfactant induced electroless plating (SIEP). The unique features of this innovation provide control of Pd-deposition rate, and Pd-grain size distribution. The surfactant molecules play an important role in the EP process by tailoring grain size and the process of agglomeration by removing tiny gas bubbles through adsorption at the gas-liquid interface. As a result surfactant can tailor a nanocrystalline Pd, Cu and Ag deposition in the film resulting in reduced membrane film thickness. Also, it produces a uniform, agglomerated film structure. The Pd-Cu and Pd-Ag membranes on MPSS support were fabricated by sequential deposition using SIEP method. The pre- and post-annealing characterizations of these membranes (Pd, Pd-Cu and Pd-Ag on MPSS substrate) were carried out by SEM, EDX, XRD, and AFM studies. The SEM images show significant improvement of the membrane surface morphology, in terms of metal grain structures and grain agglomeration compared to the membranes fabricated by conventional EP process. The SEM images and helium gas-tightness studies indicate that dense and thinner films of Pd, Pd-Cu and Pd-Ag membranes can be produced with shorter deposition time using surfactant. H{sub 2} Flux through the membranes fabricated by SIEP shows large improvement compared to those by CEP with comparable permselectivity. Pd-MPSS composite membrane was subjected to test for long term performance and thermal cycling (573 - 723 - 573 K) at 15 psi pressure drop for 1200 hours. Pd membranes showed excellent hydrogen permeability and thermal stability during the operational period. Under thermal cycling (573 K - 873 K - 573 K), Pd-Cu-MPSS membrane was stable and retained hydrogen permeation characteristics for over three months of operation. From this limited study, we conclude that SIEP is viable method for fabrication of defect-free, robust Pd-alloy membranes for high-temperature H{sub 2}-separation applications.

Ilias, Shamsuddin; Kumar, Dhananjay

2012-07-31T23:59:59.000Z

108

Kinetics of monolayer graphene growth by segregation on Pd(111)  

SciTech Connect (OSTI)

Using in situ low-energy electron microscopy and density functional theory calculations, we follow the growth of monolayer graphene on Pd(111) via surface segregation of bulk-dissolved carbon. Upon lowering the substrate temperature, nucleation of graphene begins on graphene-free Pd surface and continues to occur during graphene growth. Measurements of graphene growth rates and Pd surface work functions establish that this continued nucleation is due to increasing C adatom concentration on the Pd surface with time. We attribute this anomalous phenomenon to a large barrier for attachment of C adatoms to graphene coupled with a strong binding of the non-graphitic C to the Pd surface.

Mok, H. S.; Murata, Y.; Kodambaka, S., E-mail: kodambaka@ucla.edu [Department of Materials Science and Engineering, University of California Los Angeles, Los Angeles, California 90095 (United States); Ebnonnasir, A.; Ciobanu, C. V. [Department of Mechanical Engineering and Materials Science Program, Colorado School of Mines, Golden, Colorado 80401 (United States); Nie, S.; McCarty, K. F. [Sandia National Laboratories, Livermore, California 94550 (United States)

2014-03-10T23:59:59.000Z

109

Seed influence on the ferromagnetic resonance response of Co/Ni multilayers  

SciTech Connect (OSTI)

The effect of Pd and Ru seed layers on the magnetic properties of [Co/Ni]{sub N} multilayers with varying number of bilayer repeats N is investigated using vector network analyzer ferromagnetic resonance. The effective anisotropy field H{sub Keff} is found to increase with N for Ru seed, but decreases for Pd until N?=?15. As N is increased beyond 15, H{sub Keff} decreases for both seeds. In contrast, the damping parameter ? decreases with N regardless of the seed, showing a 1/N dependence. Taking spin pumping into account, the intrinsic damping ?{sub 0} for both Pd and Ru seeds reduce to ?{sub 0} ? 0.01. These results demonstrate that there can be a strong influence of the seed/Co interface on anisotropy, especially for sufficiently low N, but not necessarily on ?{sub 0}.

Sabino, Maria Patricia Rouelli, E-mail: maria-sabino@dsi.a-star.edu.sg; Tran, Michael; Hin Sim, Cheow; Ji Feng, Ying; Eason, Kwaku [Data Storage Institute, Agency for Science, Technology and Research, 5 Engineering Drive 1, Singapore 117608 (Singapore)

2014-05-07T23:59:59.000Z

110

Carbon nanotubes decorated with Pt nanoparticles via electrostatic...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

nanotubes decorated with Pt nanoparticles via electrostatic self-assembly: a highly active oxygen reduction Carbon nanotubes decorated with Pt nanoparticles via electrostatic...

111

Enhanced Activity and Stability of Pt catalysts on Functionalized...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Enhanced Activity and Stability of Pt catalysts on Functionalized Graphene Sheets for Electrocatalytic Oxygen Reduction . Enhanced Activity and Stability of Pt catalysts on...

112

Crystalline Ice Growth on Pt(111): Observation of a Hydrophobic...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Crystalline Ice Growth on Pt(111): Observation of a Hydrophobic Water Monolayer. Crystalline Ice Growth on Pt(111): Observation of a Hydrophobic Water Monolayer. Abstract: The...

113

Ni Ni: University of California - Los Angeles  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the Contributions andDataNationalNewport News Business55NewsNextNextEra EnergyEsmond G.Ni

114

Au-Pt heteroaggregate dendritic nanostructures and Au-Pt alloy nanoparticles and their use as catalysts  

DOE Patents [OSTI]

Au--Pt heteroaggregate dendritic nanostructures and AuPt alloy nanoparticles, and their use as anodic catalysts in fuel cells.

Eichhorn, Bryan W. (University Park, MD); Zhou, Shenghu (Greenbelt, MD); Jackson, Gregory Scott (University Park, MD)

2011-10-18T23:59:59.000Z

115

Bulk Migration of Ni/NiO in Ni-YSZ during Reducing Conditions  

SciTech Connect (OSTI)

Understanding the migration of Ni/NiO in Ni-YSZ can potentially help to design a better solid oxide fuel cell (SOFC) anode. We have observed that extensive hydrogen reduction and methane steam reforming of Ni-YSZ caused bulk migration of Ni/NiO to at least ~ 5 µm deeper from the Ni-YSZ surface. No significant bulk migration effects were detected after simple thermal treatments in non-reducing/non-reforming environment. Surface analysis of a single zirconia grain in the first 10-20 nm region from annealed, hydrogen reduced and methane steam reformed Ni-YSZ shows Ni-enriched surface supporting earlier claims of Ni exsolution. 3D-EBSD analysis of thermally treated sample before exposing it to reducing and reforming environment indicated mixed NiO/YSZ phase with some porosity and random grain orientation. The surface analysis and mapping were carried out using ToF-SIMS and AES whereas EDS maps on FIB sliced areas on Ni-YSZ were utilized for the bulk analysis. The results provide additional information related to complex reactions occurring in SOFC during internal reforming conditions.

Saraf, Laxmikant V.; Baer, Donald R.; Lea, Alan S.; Zhu, Zihua; Strohm, James J.; Sitzman, S. D.; King, David L.

2010-02-09T23:59:59.000Z

116

Structural and magnetic properties of the ordered FePt{sub 3}, FePt and Fe{sub 3}Pt nanoparticles  

SciTech Connect (OSTI)

The Fe{sub x}Pt{sub 100?x} nanoparticles (NPs) with different nominal atomic rations (30?x?80) were synthesized at 700 °C by the sol–gel method. The structure, morphology and magnetic properties of the samples were investigated. When the Fe content in the Fe–Pt alloy NPs was 30 at%, FePt{sub 3} NPs were successfully synthesized. With the increase in Fe content up to 50 at%, it was found that the superlattice reflections (0 0 1) and (1 1 0) appeared, which indicated the formation of the L1{sub 0}-FePt phase. Meanwhile, the FePt{sub 3} fraction was reduced. When the Fe content increased to 60 at%, single-phase L1{sub 0}-FePt NPs were synthesized. The coercivity (Hc), saturation magnetization (Ms) and chemical order parameter S for Fe{sub 60}Pt{sub 40} NPs were as high as 10,200 Oe, 17.567 emu/g and 0.928, respectively. With the further increase of the Fe content to 80 at%, only Fe{sub 3}Pt phase existed and the Hc of the Fe{sub 3}Pt NPs decreased drastically to 360 Oe. - Graphical abstract: Fe{sub 3}Pt, FePt and FePt{sub 3} nanoparticles was obtained by sol–gel method. The effect of iron and platinum content on structural and magnetic properties of the FePt nanoparticles was investigated. Display Omitted - Highlights: • L1{sub 2}-FePt{sub 3}, L1{sub 0}-FePt and L1{sub 2}-Fe{sub 3}Pt NPs were synthesized by sol–gel method. • The chemical order parameter S affects the magnetic properties of the Fe–Pt alloy. • Structural and magnetic properties of the Fe–Pt alloy NPs were studied. • The synthetic route in this study will open up the possibilities of practical use.

Liu, Yang [Institute of Condensed State Physics, Jilin Normal University, Siping 136000 (China); Key Laboratory of Functional Materials Physics and Chemistry (Jilin Normal University), Ministry of Education, Siping 136000 (China); Institute of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013 (China); Jiang, Yuhong; Zhang, Xiaolong; Wang, Yaxin; Zhang, Yongjun; Liu, Huilian; Zhai, Hongju; Liu, Yanqing [Institute of Condensed State Physics, Jilin Normal University, Siping 136000 (China); Key Laboratory of Functional Materials Physics and Chemistry (Jilin Normal University), Ministry of Education, Siping 136000 (China); Yang, Jinghai, E-mail: jhyang1@jlnu.edu.cn [Institute of Condensed State Physics, Jilin Normal University, Siping 136000 (China); Key Laboratory of Functional Materials Physics and Chemistry (Jilin Normal University), Ministry of Education, Siping 136000 (China); Yan, Yongsheng, E-mail: yanyongsheng215@126.com [Institute of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013 (China)

2014-01-15T23:59:59.000Z

117

au ag pd: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

and theoretical approaches agreed well, demonstrating the potential use Wang, Lihong 19 NANO EXPRESS Open Access AuPd core-shell nanoparticles with varied hollow Energy Storage,...

118

PT-Symmetric Optomechanically-Induced Transparency  

E-Print Network [OSTI]

Optomechanically-induced transparency (OMIT) and the associated slow-light propagation provide the basis for storing photons in nanofabricated phononic devices. Here we study OMIT in parity-time (PT)-symmetric microresonators with a tunable gain-to-loss ratio. This system features a reversed, non-amplifying transparency: inverted-OMIT. When the gain-to-loss ratio is steered, the system exhibits a transition from the PT-symmetric phase to the broken-PT-symmetric phase. We show that by tuning the pump power at fixed gain-to-loss ratio or the gain-to-loss ratio at fixed pump power, one can switch from slow to fast light and vice versa. Moreover, the presence of PT-phase transition results in the reversal of the pump and gain dependence of transmission rates. These features provide new tools for controlling light propagation using optomechanical devices.

H. Jing; S. K. Özdemir; Z. Geng; J. Zhang; X. -Y. Lü; B. Peng; L. Yang; F. Nori

2014-12-09T23:59:59.000Z

119

Location of platinum clusters in PtCaY and PtNaY zeolites  

E-Print Network [OSTI]

) 350'C . . . ~ . . . . . . . . . . . . . 32 Pt 4f spectra of PtCaY: (A) after heating in flowing oxygen at 100'C for 2 hr, (B) after reduction in flowing hydrogen in increments of 100'C/hr to 350'C, (C) after deammination and dehydration in flowing... oxygen in incre- ments of 100'C/hr to 350'C, evacuation at 25'C followed by reduction in flowing hydrogen in increments oi 100'C/hr to 400'C Pt 4d spectra of PtCaY: (A) after heating in flowing oxygen at 100'C for 2 hr, (B) after reduction...

Treybig, Duane Steven

1980-01-01T23:59:59.000Z

120

Scanning tuneeling microscopy studies of fivefold surfaces of icosahedral Al-Pd-Mn quasicrystals and of thin silver films on those surfaces  

SciTech Connect (OSTI)

The present work in this dissertation mainly focuses on the clean fivefold surfaces of i-Al-Pd-Mn quasicrystals as well as the nucleation and growth of Ag films on these surfaces. In addition, Ag film growth on NiAl(110) has been explored in the frame of this dissertation. First, we have investigated the equilibration of a fivefold surface of icosahedral Al-Pd-Mn quasicrystal at 900-915 K and 925-950 K, using Omicron variable temperature scanning tunneling microscope (STM). Annealing at low temperatures resulted in many voids on some terraces while the others were almost void-free. After annealing at 925-950K, void-rich terraces became much rarer. Our STM images suggest that through growth and coalescence of the voids, a different termination becomes exposed on host terraces. All of these observations in our study indicate that even after the quasicrystalline terrace-step structure appears, it evolves with time and temperature. More specifically, based on the STM observations, we conclude that during the annealing a wide range of energetically similar layers nucleate as surface terminations, however, with increasing temperature (and time) this distribution gets narrower via elimination of the metastable void-rich terraces. Next, we have examined the bulk structural models of icosahedral Al-Pd-Mn quasicrystal in terms of the densities, compositions and interplanar spacings for the fivefold planes that might represent physical surface terminations. In our analyses, we mainly have focused on four deterministic models which have no partial or mixed occupancy but we have made some comparisons with an undeterministic model. We have compared the models with each other and also with the available experimental data including STM, LEED-IV, XPD and LEIS. In all deterministic models, there are two different families of layers (a pair of planes), and the nondeterministic model contains similar group of planes. These two families differ in terms of the chemical decoration of their top planes. Hence, we name them as Pd+(with Pd) and Pd-(without Pd). Based on their planer structure and the step height, it can be said that these two families can be viable surface terminations. However, besides the Pd content, these two sets differ in terms of relative densities of their top planes as well as the gap separating the layer from the nearest atomic plane. The experimental data and other arguments lead to the conclusion that the Pd- family is favored over the Pd+. This has an important implication on the interpretation of local motifs seen in the high resolution STM images. In other words, the dark stars are not formed by cut-Bergmans rather they are formed by cut-Mackays.

Unal, Baris

2008-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "ni pd pt" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Atomic force microscopy and x-ray photoelectron spectroscopy investigations of the morphology and chemistry of a PdCl{sub 2}/SnCl{sub 2} electroless plating catalysis system adsorbed onto shape memory alloy particles  

SciTech Connect (OSTI)

A study of the different stages of the electroless deposition of copper on micronic NiTi shape memory alloy particles activated by one-step and two-step methods has been conducted from both a chemical and a morphological point of view. The combination of x-ray photoelectron spectroscopy (XPS) measurements and atomic force microscopy (AFM) imaging has allowed detection of the distribution of the formed compounds and depth quantification and estimation of the surface topographic parameters. For the two-step method, at the sensitization of the early stages, it is observed by AFM that Sn is absorbed in form of clusters that tend to completely cover the surface and form a continuous film. XPS analysis have shown that Sn and Pd are first absorbed in form of oxide (SnO{sub 2} and PdO) and hydroxide [Sn(OH){sub 4}]. After the entire sensitization step, the NiTi substrate is covered with Sn-based compounds. After the sensitization and the activation steps the powder roughness increases. Behavior of the Sn and Pd growth for the one-step method does not follow the behavior found for the two-step method. Indeed, XPS analysis shows a three-dimensional (3D) growth of Pd clusters on top of a mixture of metallic tin, oxide (SnO) and hydroxide [Sn(OH){sub 2}]. These Pd clusters are covered with a thin layer of Pd-oxide contamination induced by the electroless process. The mean roughness for the one-step and two-step processes are equivalent. After copper deposition, the decrease of mean roughness is attributed to a filling of surface valleys, observed after the Sn-Pd coating step.

Silvain, J.F.; Fouassier, O.; Lescaux, S. [Institut de Chimie de la Matiere Condensee de Bordeaux (ICMCB) - CNRS, Universite de Bordeaux 1, 87 Avenue du Dr A. Schweitzer, F-33608 PESSAC (France); Veeco, Z.I. de la Gaudree, 11 Rue Marie Poussepin, F-91412 Dourdain (France)

2004-11-01T23:59:59.000Z

122

Electrochemical hydrogenation of aromatic compounds chemisorbed at polycrystalline and single-crystal Pd surfaces  

E-Print Network [OSTI]

The chemisorption and electrochemical hydrogenation of hydroquinone (H2Q) at polycrystalline (pc) Pd, well-ordered Pd(100), and Pd-modified Au(hkl) electrodes were studied using a combination of ultra-high vacuum (UHV) surface spectroscopy...

Sanabria-Chinchilla, Jean

2009-06-02T23:59:59.000Z

123

PD Dr. Martin Stetter, Siemens AG 1 Optimierungsverfahren  

E-Print Network [OSTI]

PD Dr. Martin Stetter, Siemens AG 1 Optimierungsverfahren · Optimierung konvexer Funktionen: Optimierungsverfahren #12;PD Dr. Martin Stetter, Siemens AG 2 Optimierung konvexer Funktionen · Häufiges Problem bei Stetter, Siemens AG 3 Funktionen einer Variable )(wF · 1D-Gradientenabstieg: Gehe ein kleines Stück

Popeea, Corneliu - Chair for Foundations of Software Reliability and Theoretical Computer Science

124

CX-009904: Categorical Exclusion Determination | Department of...  

Broader source: Energy.gov (indexed) [DOE]

using high surface area nitrogen doped titania nanotube arrays, sensitized with nano-dimensional islands of co-catalysts copper and Ni, Pd or Pt. CX-009904.pdf More...

125

Microsoft Word - 25A1028 Continued  

Broader source: Energy.gov (indexed) [DOE]

using high surface area nitrogen doped titania nanotube arrays, sensitized with nano-dimensional islands of co-catalysts copper and Ni, Pd or Pt Varghese et al., Nano...

126

Neutral bimetallic transition metal phenoxyiminato catalysts and related polymerization methods  

DOE Patents [OSTI]

A catalyst composition comprising a neutral bimetallic diphenoxydiiminate complex of group 10 metals or Ni, Pd or Pt is disclosed. The compositions can be used for the preparation of homo- and co-polymers of olefinic monomer compounds.

Marks, Tobin J. (Evanston, IL); Rodriguez, Brandon A. (Evanston, IL); Delferro, Massimiliano (Chicago, IL)

2012-08-07T23:59:59.000Z

127

Jet energy scale setting with "photon+Jet" events at LHC energies. Selection of events with a clean "photon+Jet" topology and photon Pt - jet Pt disbalance  

E-Print Network [OSTI]

It is shown in the paper that Pt activity limitation (modulus of the vector sum) of all particle beyond "photon+Jet" system Pt^out leads to the noticeable photon Pt - jet Pt disbalance decreasing. On a simultaneous restriction of the cluster Pt and Pt^out from above it is possible to reach an acceptable balance between photon Pt - jet Pt with a sufficient number of the photon Pt - jet Pt events for the jet energy scale setting and hadron calorimeter calibratiom of the CMS detector at LHC.

D. V. Bandourin; V. F. Konoplyanikov; N. B. Skachkov

2001-04-27T23:59:59.000Z

128

May 22, 2003 DOE Hydrogen and Fuel Cells 2003 Annual Merit Review  

E-Print Network [OSTI]

(Ceria) electrolytes · Use various (Pt, Pd, Au, Ni) metal electrode combinations H2 + OO H2O + VO .. + 2e- CO + OO CO Nafion® as the proton conducting membrane · Use Pt or Ru electrode as working electrode · Electrode is sensitive to CO poisoning · Use Pt-Ru electrode as a counter electrode · Electrode is tolerant

129

Free Tetra-and hexa-coordinated Platinum-Cyanide Dianions, PT...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Dianions, PT(CN)4 2- and PT(CN)6 2-: A Combined Photodetachment Photoelectron Free Tetra-and hexa-coordinated Platinum-Cyanide Dianions, PT(CN)4 2- and PT(CN)6 2-: A...

130

Molecular Dynamics Simulations of Supported Pt Nanoclusters  

E-Print Network [OSTI]

¤Introduction and Background ¤Constructing a Physical Model ¤Details of the Simulation ¤Results and Conclusions · Petroleum reformation · Gasification of biomass for biofuels #12;Previous Investigation of NanoclustersMolecular Dynamics Simulations of Supported Pt Nanoclusters Jeffrey Moore #12;A Brief Outline

Washington at Seattle, University of - Department of Physics, Electroweak Interaction Research Group

131

ENHANCEMENT OF SUPERCONDUCTING Tc IN Pd-H LIKE COMPOUNDS BY OPTICAL PHONONS  

E-Print Network [OSTI]

1227 ENHANCEMENT OF SUPERCONDUCTING Tc IN Pd-H LIKE COMPOUNDS BY OPTICAL PHONONS J. P. BURGER and D.450 1. Introduction. - The high superconducting tran- sition temperatures recently observed in Pd [1 interaction inhibiting superconductivity in pure Pd. As the density of states in Pd-H is rather similar [5

Boyer, Edmond

132

Synthesis of Methanol and Dimethyl Ether from Syngas over Pd...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of the catalysts has been established. Hence, two types of sites are required for the direct conversion of syngas to DME: 1) PdZn particles are active for the synthesis of...

133

The Role of the PD-1 Immunoreceptor in Pregnancy  

E-Print Network [OSTI]

During pregnancy, the maternal immune system must be carefully modulated as the fetus is immunologically foreign to her leukocytes. We propose that the CD28 family immune receptor, PD-1, functions during pregnancy to control maternal immune...

Taglauer, Elizabeth Susan

2008-08-08T23:59:59.000Z

134

Methane Combustion over Pd/ZrO2/SiC, Pd/CeO2/SiC, Pd/Zr0.5Ce0.5O2/SiC Catalysts  

E-Print Network [OSTI]

1 Methane Combustion over Pd/ZrO2/SiC, Pd/CeO2/SiC, Pd/Zr0.5Ce0.5O2/SiC Catalysts Xiaoning Guo a Laboratory of Coal Conversion, Institute of Coal Chemistry, Taiyuan 030001, PR China b GREMI UMR6606 CNRS0.5O2 solid solution) modified Pd/SiC catalysts for methane combustion are studied. XRD and XPS

Paris-Sud XI, Université de

135

Composite Pd and Pd Alloy Porous Stainless Steel Membranes for Hydrogen Production and Process Intensification  

SciTech Connect (OSTI)

The synthesis of composite Pd membranes has been modified by the addition of a Al(OH){sub 3} graded layer and sequential annealing at high temperatures to obtain membranes with high permeance and outstanding selectivity stability for over 4000 hours at 450°C. Most of the membranes achieved in this work showed H{sub 2} flux well above 2010 DOE targets and in some case, also above 2015 DOE targets. Similar composite membranes were tested in water gas shift reaction atmospheres and showed to be stable with high CO conversion and high hydrogen recovery for over 1000 hours. The H{sub 2} permeance of composite Pd-Au membranes was studied as well as its resistance in H{sub 2}S containing atmospheres. H{sub 2}S poisoning of Pd-based membranes was reduced by the addition of Au and the loss undergone by membranes was found to be almost totally recoverable with 10-30 wt%Au. PSA technique was studied to test the possibility of H{sub 2}S and COS removal from feed stream with limited success since the removal of H{sub 2}S also led to the removal of a large fraction of the CO{sub 2}. The economics of a WGS bundle reactor, using the information of the membranes fabricated under this project and integrated into an IGCC plant were studied based on a 2D reactor modeling. The calculations showed that without a government incentive to impose a CO{sub 2} tax, application of WGS membrane reactors in IGCC would be not as economically attractive as regular pulverized coal plants.

Yi Hua Ma; Nikolaos Kazantzis; Ivan Mardilovich; Federico Guazzone; Alexander Augustine; Reyyan Koc

2011-11-06T23:59:59.000Z

136

Cu--Pd--M hydrogen separation membranes  

DOE Patents [OSTI]

The disclosure provides an H2 separation membrane comprised of an allow having the composition Cu.Sub.(100-x-y)Pd.sub.xM.sub.y, where x is from about 35 to about 50 atomic percent and where y is from greater than 0 to about 20 atomic percent, and where M consists of magnesium, yttrium, aluminum, titanium, lanthanum, or combinations thereof. The M elements act as strong stabilizers for the B2 phase of the allow, and extend the critical temperature of the alloy for a given hydrogen concentration and pressure. Due to the phase stabilization and the greater temperature range over which a B2 phase can be maintained, the allow is well suited for service as a H2 separation membrane, particularly when applicable conditions are established or cycled above about 600.degree. C. over the course of expected operations. In certain embodiments, the B2 phase comprises at least 60 estimated volume percent of the allow at a steady-state temperature of 400.degree. C. The B2 phase stability is experimentally validated through HT-XRD.

Do{hacek over (g)}an, Omer N; Gao, Michael C; Young, Rongxiang Hu; Tafen, De Nyago

2013-12-17T23:59:59.000Z

137

The PD-1/PD-L1 complex resembles the antigen-binding Fv domains of antibodies and T cell receptors  

SciTech Connect (OSTI)

Signaling through the programmed death 1 (PD-1) inhibitory receptor upon binding its ligand, PD-L1, suppresses immune responses against autoantigens and tumors and plays an important role in the maintenance of peripheral immune tolerance. Release from PD-1 inhibitory signaling revives 'exhausted' virus-specific T cells in chronic viral infections. Here we present the crystal structure of murine PD-1 in complex with human PD-L1. PD-1 and PD-L1 interact through the conserved front and side of their Ig variable (IgV) domains, as do the IgV domains of antibodies and T cell receptors. This places the loops at the ends of the IgV domains on the same side of the PD-1/PD-L1 complex, forming a surface that is similar to the antigen-binding surface of antibodies and T cell receptors. Mapping conserved residues allowed the identification of residues that are important in forming the PD-1/PD-L1 interface. Based on the structure, we show that some reported loss-of-binding mutations involve the PD-1/PD-L1 interaction but that others compromise protein folding. The PD-1/PD-L1 interaction described here may be blocked by antibodies or by designed small-molecule drugs to lower inhibitory signaling that results in a stronger immune response. The immune receptor-like loops offer a new surface for further study and potentially the design of molecules that would affect PD-1/PD-L1 complex formation and thereby modulate the immune response.

Lin, David Yin-wei; Tanaka, Yoshimasa; Iwasaki, Masashi; Gittis, Apostolos G.; Su, Hua-Poo; Mikami, Bunzo; Okazaki, Taku; Honjo, Tasuku; Minato, Nagahiro; Garboczi, David N. (NIH); (Kyoto)

2008-07-29T23:59:59.000Z

138

Thermal Treatment of PtNiCo Electrocatalysts: Effects of Nanoscale Strain  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear SecurityTensile Strain Switched Ferromagnetism in Layered NbS2 andThe1 MembersStability of MnBi Magneticand Structure

139

First-principles Study of Phenol Hydrogenation on Pt and Ni Catalysts in  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsing ZirconiaPolicyFeasibilityField OfficeFirmFirst ProofgaseousFirstorderAqueous

140

Giant Quadrupole-Resonance in Ni Isotopes  

E-Print Network [OSTI]

Inelastic scattering of 129 MeV alpha particles has been used to excite the giant quadrupole resonance in Ni-58, Ni-60, Ni-62, Ni-64. The resonance was found to exhaust 58 +/- 12%, 76 +/- 14%, 78 +/- 14%, and 90 +/-16% of the E2 energy-weighted sum...

Youngblood, David H.; Lui, YW; Garg, U.; Peterson, R. J.

1992-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "ni pd pt" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Synthesis And Characterization of Pt Clusters in Aqueous Solutions  

SciTech Connect (OSTI)

Extended X-ray absorption fine structure (EXAFS) and UV-visible (UV-vis) spectroscopies were used to monitor the various steps involved in the synthesis of unprotected and poly(vinyl alcohol) (PVA)-protected aqueous colloidal Pt suspensions. The results indicate that on hydrolysis of the H{sub 2}PtCl{sub 6} precursor, the Cl{sup -} ligands were partially replaced by aquo ligands in the first coordination shell of Pt to form [PtCl{sub 2}(H{sub 2}O){sub 4}]{sup 2+}. Treatment of these species with NaBH{sub 4} under controlled pH conditions led to the formation of nearly uniform Pt{sub 4} and Pt{sub 6} clusters in the absence and presence of PVA, respectively. These highly dispersed colloidal Pt suspensions were stable for several months. The addition of 2-propanol (IPA) to both types of Pt suspensions led to some sintering of the Pt clusters, although both suspensions retained their colloidal nature. Less sintering was evident in the PVA-protected Pt suspension. Both the unprotected and the PVA-protected colloidal Pt suspensions were catalytically active for the liquid-phase selective oxidation of 2-propanol to acetone, with the unprotected suspension exhibiting the highest activity.

Siani, A.; Wigal, K.R.; Alexeev, O.S.; Amiridis, M.D.

2009-05-26T23:59:59.000Z

142

Effect of nitrogen upon structural and magnetic properties of FePt in FePt/AlN multilayer structures  

SciTech Connect (OSTI)

This paper investigates the effect of the addition of nitrogen in FePt layers for ultrathin FePt/AlN multilayer structures. X-ray diffraction results reveal that a compressive stress relaxation occurs after annealing owing to the release of interstitial nitrogen atoms in the FePt layers. The introduction of nitrogen also induces a large in-plane compressive strain during grain growth not seen in FePt deposited without nitrogen. This strain is considered to decrease the driving force for (111) grain growth and FePt ordering.

Gao, Tenghua, E-mail: gao.t.ab@m.titech.ac.jp; Zhang, Cong; Sannomiya, Takumi; Muraishi, Shinji; Nakamura, Yoshio; Shi, Ji [Department of Metallurgy and Ceramics Science, Tokyo Institute of Technology, 2-12-1 Oh-okayama, Meguro-ku, Tokyo 152-8552 (Japan)

2014-09-01T23:59:59.000Z

143

PdZnAl Catalysts for the Reactions of Water-Gas-Shift, Methanol Steam Reforming, and Reverse-Water-Gas-Shift  

SciTech Connect (OSTI)

Pd/ZnO/Al2O3 catalysts were studied for water-gas-shift (WGS), methanol steam reforming, and reverse-water-gas-shift (RWGS) reactions. WGS activity was found to be dependent on the Pd:Zn ratio with a maximum activity obtained at approximately 0.50, which was comparable to that of a commercial Pt-based catalyst. The catalyst stability was demonstrated for 100 hours time-on-stream at a temperature of 3600C without evidence of metal sintering. WGS reaction rates were approximately 1st order with respect to CO concentration, and kinetic parameters were determined to be Ea = 58.3 kJ mol-1 and k0 = 6.1x107 min-1. During methanol steam reforming, the CO selectivities were observed to be lower than the calculated equilibrium values over a range of temperatures and steam/carbon ratios studied while the reaction rate constants were approximately of the same magnitude for both WGS and methanol steam reforming. These results indicate that although Pd/ZnO/Al2O3 are active WGS catalysts, WGS is not involved in methanol steam reforming. RWGS rate constants are on the order of about 20 times lower than that of methanol steam reforming, suggesting that RWGS reaction could be one of the sources for small amount of CO formation in methanol steam reforming.

Dagle, Robert A.; Platon, Alexandru; Datye, Abhaya K.; Vohs, John M.; Wang, Yong; Palo, Daniel R.

2008-03-07T23:59:59.000Z

144

Influence of nuclear structure on sub-barrier hindrance in Ni+Ni fusion  

E-Print Network [OSTI]

Fusion-evaporation cross sections for $^{64}$Ni+$^{64}$Ni have been measured down to the 10 nb level. For fusion between two open-shell nuclei, this is the first observation of a maximum in the $S$-factor, which signals a strong sub-barrier hindrance. A comparison with the $^{58}$Ni+$^{58}$Ni, $^{58}$Ni+$^{60}$Ni, and $^{58}$Ni+$^{64}$Ni systems indicates a strong dependence of the energy where the hindrance occurs on the stiffness of the interacting nuclei.

C. L. Jiang; K. E. Rehm; R. V. F. Janssens; H. Esbensen; I. Ahmad; B. B. Back; P. Collon; C. N. Davids; J. P. Greene; D. J. Henderson; G. Mukherjee; R. C. Pardo; M. Paul; T. O. Pennington; D. Seweryniak; S. Sinha; Z. Zhou

2004-02-25T23:59:59.000Z

145

An exactly solvable PT symmetric potential from the Natanzon class  

E-Print Network [OSTI]

The ${\\cal PT}$ symmetric version of the generalised Ginocchio potential, a member of the general exactly solvable Natanzon potential class is analysed and its properties are compared with those of ${\\cal PT}$ symmetric potentials from the more restricted shape-invariant class. It is found that the ${\\cal PT}$ symmetric generalised Ginocchio potential has a number of properties in common with the latter potentials: it can be generated by an imaginary coordinate shift $x\\to x+{\\rm i}\\epsilon$; its states are characterised by the quasi-parity quantum number; the spontaneous breakdown of ${\\cal PT}$ symmetry occurs at the same time for all the energy levels; and it has two supersymmetric partners which cease to be ${\\cal PT}$ symmetric when the ${\\cal PT}$ symmetry of the original potential is spontaneously broken.

G. Levai; A. Sinha; P. Roy

2003-06-04T23:59:59.000Z

146

New Exactly Solvable Isospectral Partners for PT Symmetric Potentials  

E-Print Network [OSTI]

We examine in detail the possibilty of applying Darboux transformation to non Hermitian hamiltonians. In particular we propose a simple method of constructing exactly solvable PT symmetric potentials by applying Darboux transformation to higher states of an exactly solvable PT symmetric potential. It is shown that the resulting hamiltonian and the original one are pseudo supersymmetric partners. We also discuss application of Darboux transformation to hamiltonians with spontaneously broken PT symmetry.

Anjana Sinha; Pinaki Roy

2003-12-18T23:59:59.000Z

147

PtRu/Carbon Nanotube Nanocomposite Synthesized in Supercritical...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Synthesized in Supercritical Fluid: A Novel Electrocatalyst for Direct Methanol Fuel Cell. PtRuCarbon Nanotube Nanocomposite Synthesized in Supercritical Fluid: A Novel...

148

Effect of reductive treatments on Pt behavior and NOx storage...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

represent a promising approach to meet increasingly stringent NOx emission regulations on diesel and other lean-burn engines. Pt material properties, including dispersion and...

149

Graphene decorated with PtAu alloy nanoparticles: facile synthesis...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

nanoparticles: facile synthesis and promising application for formic acid oxidation. Graphene decorated with PtAu alloy nanoparticles: facile synthesis and promising application...

150

UCRL-MA-110662 PT I U  

Office of Scientific and Technical Information (OSTI)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinanInformation InInformation In closing, an National Carbon Capture Center at ,iMA-110662 PT I U b EQ3/6,

151

Methanol Synthesis from CO2 Hydrogenation over a Pd4/In2O3 Model...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Methanol Synthesis from CO2 Hydrogenation over a Pd4In2O3 Model Catalyst: A Combined DFT and Kinetic Study. Methanol Synthesis from CO2 Hydrogenation over a Pd4In2O3 Model...

152

Comparative and Functional Genomics of Rhodococcus opacus PD630 for Biofuels Development  

E-Print Network [OSTI]

Comparative and Functional Genomics of Rhodococcus opacus PD630 for Biofuels Development Jason W and Functional Genomics of Rhodococcus opacus PD630 for Biofuels Development. PLoS Genet 7(9): e1002219. doi:10

Sinskey, Anthony J.

153

PD Dr. Martin Stetter, Siemens AG 1 Neuronale Verfahren zur Regression  

E-Print Network [OSTI]

PD Dr. Martin Stetter, Siemens AG 1 Neuronale Verfahren zur Regression · Lineares Modell · Vom: Optimierungsverfahren #12;PD Dr. Martin Stetter, Siemens AG 2 Optimierung konvexer Funktionen · Häufiges Problem bei

Popeea, Corneliu - Chair for Foundations of Software Reliability and Theoretical Computer Science

154

Development and Applications of Pd Catalysts for C-N Cross-Coupling Reactions  

E-Print Network [OSTI]

Chapter 1 A procedure for forming a highly active Pd(0) catalyst from Pd(OAc) 2, water, and biarylphosphine ligands has been developed. This protocol generates a catalyst system, which exhibits excellent reactivity and ...

Fors, Brett P

2011-01-01T23:59:59.000Z

155

Syngas Conversion to Gasoline-Range Hydrocarbons over Pd/ZnO...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Syngas Conversion to Gasoline-Range Hydrocarbons over PdZnOAl2O3 and ZSM-5 Composite Catalyst System. Syngas Conversion to Gasoline-Range Hydrocarbons over PdZnOAl2O3 and ZSM-5...

156

PdZnAl Catalysts for the Reactions of Water-Gas-Shift, Methanol...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

PdZnAl Catalysts for the Reactions of Water-Gas-Shift, Methanol Steam Reforming, and Reverse-Water-Gas-Shift. PdZnAl Catalysts for the Reactions of Water-Gas-Shift, Methanol Steam...

157

CO/FTIR Spectroscopic Characterization of Pd/ZnO/Al2O3 Catalysts...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

COFTIR Spectroscopic Characterization of PdZnOAl2O3 Catalysts for Methanol Steam Reforming. COFTIR Spectroscopic Characterization of PdZnOAl2O3 Catalysts for Methanol Steam...

158

Carbon-Supported bimetallic Pd-Fe catalysts for vapor-phasehydrodeoxy...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Carbon-Supported bimetallic Pd-Fe catalysts for vapor-phase hydrodeoxygenation of guaiacol. Carbon-Supported bimetallic Pd-Fe catalysts for vapor-phase hydrodeoxygenation of...

159

The Obviative Suffix -ni- In Algonquian  

E-Print Network [OSTI]

the marker -ni- is used specifically when an argument has been established as obviative earlier in the discourse. By tracing -ni- in the morphology of Fox and Kickapoo and in Bloomfield's comparative Algonquian work (Bloomfield 1946), the present paper...

Gathercole, Geoffrey

1979-01-01T23:59:59.000Z

160

Kinetics of Ni Sorption in Soils: Roles of Soil Organic Matter and Ni Precipitation  

E-Print Network [OSTI]

sorption in soils may be controlled by different reaction mechanisms at various time scales be an important path for Ni sequestration in soils.9 The mechanisms of Ni-LDH formation have been investigatedKinetics of Ni Sorption in Soils: Roles of Soil Organic Matter and Ni Precipitation Zhenqing Shi

Sparks, Donald L.

Note: This page contains sample records for the topic "ni pd pt" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Hydrogen Absorption in Pd-based Nanostructures - Final Report  

SciTech Connect (OSTI)

Pd is known to absorb hydrogen. Molecules are normally chemisorbed at the surface in a process where the molecule breaks into two hydrogen atoms, and the protons are then absorbed into the bulk. This process consists of electron filling holes in the Pd 4d band near the Fermi energy, which due to the high density of states at the Fermi energy, is an energetically favorable process. Our aim with this project was to determine possible changes in magnetic properties with Pd nm-length-scale thick layers intercalated by magnetic materials. Before the start of this work, the literature indicated that there were several possible scenarios by which this could happen: i) the Pd will be magnetized due to a proximity effect with nearby magnetic layers, resulting in changes in the magnetization due to H2 absorption; ii) some H will be absorbed into the magnetic layers, causing a change in the magnetic exchange interactions; or iii) absorption of H2 will cause an expansion of the lattice, resulting in a magnetoelastic effect which changes the magnetic properties.

David Lederman

2012-10-22T23:59:59.000Z

162

Vacancies below the ,,111... surface of Pd Russel P. Kauffman*  

E-Print Network [OSTI]

Vacancies below the ,,111... surface of Pd Russel P. Kauffman* Department of Physics, Muhlenberg is used to investigate vacancies at or below the 111 surface of palladium and in the bulk. An accurate. The interaction of the vacancy, a point defect, with a surface, a planar defect, is investigated. Also studied

Rappe, Andrew M.

163

Single Pd atoms in activated carbon fibers and their contribution to hydrogen storage 5  

E-Print Network [OSTI]

Single Pd atoms in activated carbon fibers and their contribution to hydrogen storage 5 Cristian I carbon fibers (Pd-ACF) were synthesized by melt-spinning, carbonization and activation of an isotropic pitch carbon precursor premixed with an orga- nometallic Pd compound. The hydrogen uptake at 25 °C

Pennycook, Steve

164

PD Dr. Martin Stetter, Siemens AG 1 Neuronale Lernverfahren fr Klassifikation  

E-Print Network [OSTI]

PD Dr. Martin Stetter, Siemens AG 1 Neuronale Lernverfahren für Klassifikation · Das Perceptron #12;PD Dr. Martin Stetter, Siemens AG 2 Das Perceptron Klassifikation: Perceptron · Neuronale Struktur- Klassifikationsfehler 1x w )(m x 1)( =m y 0^ =y 1^ +=y 2x #12;PD Dr. Martin Stetter, Siemens AG 3Klassifikation

Popeea, Corneliu - Chair for Foundations of Software Reliability and Theoretical Computer Science

165

PD Dr. Martin Stetter, Siemens AG 1 Lernen von Datenmodellen: Fehlerminimierung und Regularisierung  

E-Print Network [OSTI]

PD Dr. Martin Stetter, Siemens AG 1 Lernen von Datenmodellen: Fehlerminimierung und Regularisierung: Fehlerminimierung #12;PD Dr. Martin Stetter, Siemens AG 2 Maximum-Likelihood und Fehlerminimierung · Likelihood: Fehlerfunktionen #12;PD Dr. Martin Stetter, Siemens AG 3 · Def. Fehlerfunktion: 0))|(,,( wxfyxl yxyyx ,0),,( =lmit

Popeea, Corneliu - Chair for Foundations of Software Reliability and Theoretical Computer Science

166

PD Dr. Martin Stetter, Siemens AG 1 Lernen von Datenmodellen: Approximation  

E-Print Network [OSTI]

PD Dr. Martin Stetter, Siemens AG 1 Lernen von Datenmodellen: Approximation · Bayes`sches Schließen: Approximation #12;PD Dr. Martin Stetter, Siemens AG 2 Ziel maschinellen Lernens (=statistische Inferenz) · Man Datenmodellen: Approximation #12;PD Dr. Martin Stetter, Siemens AG 3 Bayes`sches Schließen · Es gilt, die Daten

Popeea, Corneliu - Chair for Foundations of Software Reliability and Theoretical Computer Science

167

PD Dr. Martin Stetter, Siemens AG 1 Neuronale Verfahren zur Regression  

E-Print Network [OSTI]

PD Dr. Martin Stetter, Siemens AG 1 Neuronale Verfahren zur Regression · Lineares Modell · Vom-Netze Regression #12;PD Dr. Martin Stetter, Siemens AG 2 Das lineare Modell · Ausgangspunkt: Lineares Perceptron vorgegeben, werden nicht gelernt #12;PD Dr. Martin Stetter, Siemens AG 3 · Geschrieben als Regressionsmodell

Popeea, Corneliu - Chair for Foundations of Software Reliability and Theoretical Computer Science

168

subm. to PCCP Geometric and electronic structure of Pd/4-aminothiophenol/Au(111)  

E-Print Network [OSTI]

in order to prevent the formation of the adsorption of Pd on the Au electrode [2, 3, 7­9]. The fact that the Pd layer is indeed deposited on top of the SAM and does not bind directly to the metal electrodesubm. to PCCP Geometric and electronic structure of Pd/4-aminothiophenol/Au(111) metal

Pfeifer, Holger

169

Ethylene combustion on unsupported and supported Pd: a comparative , Y.-F. Hana,b  

E-Print Network [OSTI]

Ethylene combustion on unsupported and supported Pd: a comparative study D. Kumara , Y.-F. Hana Ethylene combustion is studied at elevated pressures on Pd(100) and compared with supported Pd catalysts with increasing O2 pressure. The combustion kinetics is related to the corresponding surface carbon coverage

Goodman, Wayne

170

Design of graphene sheets-supported Pt catalyst layer in PEM...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

graphene sheets-supported Pt catalyst layer in PEM fuel cells. Design of graphene sheets-supported Pt catalyst layer in PEM fuel cells. Abstract: A series of cathodes using Pt...

171

Approved Module Information for PD2003, 2014/5 Module Title/Name: Engineering Principles 2 Module Code: PD2003  

E-Print Network [OSTI]

to apply further engineering principles of mechanics, solid mechanics, energy systems and thermo-fluids and understanding of the fundamental engineering principles of mechanics, solid mechanics and thermo- fluidsApproved Module Information for PD2003, 2014/5 Module Title/Name: Engineering Principles 2 Module

Neirotti, Juan Pablo

172

Graphdiyne as a Promising Substrate for Stabilizing Pt Nanoparticle Catalyst  

E-Print Network [OSTI]

At present, Pt nanoparticle catalysts in fuel cells suffer from aggregation and loss of chemical activity. In this work, graphdiyne, which has natural porous structure, was proposed as substrate with high adsorption ability to stabilize Pt nanoparticles. Using multiscale calculations by ab initio method and the ReaxFF potential, geometry optimizations, molecular dynamics simulations, Metropolis Monte Carlo simulations and minimum energy paths calculations were performed to investigate the adsorption energy and the rates of desorption and migration of Pt nanoparticles on graphdiyne and graphene. According to the comparison between graphdiyne and graphene, it was found that the high adsorption ability of graphdiyne can avoid Pt nanoparticle migration and aggregation on substrate. Then, simulations indicated the potential catalytic ability of graphdiyne-Pt-nanoparticle system to the oxygen reduction reaction in fuel cells. In summary, graphdiyne should be an excellent material to replace graphite or amorphous ca...

Lin, Zheng-Zhe

2015-01-01T23:59:59.000Z

173

Direct Determination of the Ionization Energies of PtC, PtO, and PtO2 with VUV Radiation  

E-Print Network [OSTI]

of the third-row transition metal carbides. 48 For PtC, theyIntroduction Transition metal oxides and carbides have beenunsaturated transition metal oxides and carbides. In

Citir, Murat

2008-01-01T23:59:59.000Z

174

Sulfur Tolerant Pd/Cu and Pd/Au Alloy Membranes for H2 Separation with High Pressure CO2 for Sequestration  

SciTech Connect (OSTI)

The effect of H{sub 2}S poisoning on Pd, Pd/Cu, and Pd/Au alloy composite membranes prepared by the electroless deposition method on porous Inconel supports was investigated to provide a fundamental understanding of the durability and preparation of sulfur tolerant membranes. X-ray photoelectron spectroscopy (XPS) studies showed that the exposure of pure Pd to 50 ppm H{sub 2}S/H{sub 2} mixtures caused bulk sulfide formation at lower temperatures and surface sulfide formation at higher temperatures. Lower temperatures, longer exposure times, and higher H{sub 2}S concentrations resulted in a higher degree of sulfidation. In a Pd membrane, the bulk sulfide formation caused a drastic irrecoverable H{sub 2} permeance decline and an irreparable loss in selectivity. Pd/Cu and Pd/Au alloy membranes exhibited permeance declines due to surface sulfide formation upon exposure to 50 ppm H{sub 2}S/H{sub 2} gas mixtures. However in contrast to the pure Pd membrane, the permeances of the Pd/Cu and Pd/Au alloy membranes were mostly recovered in pure H{sub 2} and the selectivity of the Pd alloy layers remained essentially intact throughout the characterization in H{sub 2}, He and H{sub 2}S/H{sub 2} mixtures which lasted several thousand hours. The amount of irreversible sulfur poisoning decreased with increasing temperature due to the exothermicity of H{sub 2}S adsorption. Longer exposure times increased the amount of irreversible poisoning of the Pd/Cu membrane but not the Pd/Au membrane. Pd/Au coupon studies of the galvanic displacement method showed that higher Au{sup 3+} concentrations, lower pH values, higher bath temperatures and stirring the bath at a rate of 200 rpm yielded faster displacement rates, more uniform depositions, and a higher Au content within the layers. While 400 C was found to be sufficient to form a Pd/Au alloy on the surface, high temperature X-ray diffraction (HTXRD) studies showed that even after annealing between 500-600 C, the Pd/Cu alloys could have part or all of the surface in the less sulfur resistant {beta} phase.

Yi Hua Ma; Natalie Pomerantz; Chao-Huang Chen

2008-09-30T23:59:59.000Z

175

Effect of Pt film thickness on PtSi formation and film surface morphology Jinghua Yina,*, Wei Caib  

E-Print Network [OSTI]

Platinum silicide (PtSi) has been one of the most widely used metal silicides in Si based microelectronic film thickness on the formation of platinum silicide (PtSi) phase, distribution of silicides in the literature [9­12]. According to the annealing conditions, the different silicide structures can be observed

Zheng, Yufeng

176

Interface structures in FePtFe3Pt hard-soft exchange-coupled magnetic nanocomposites  

E-Print Network [OSTI]

Interface structures in FePtÃ?Fe3Pt hard-soft exchange-coupled magnetic nanocomposites Jing Li with sizes 10 nm. This ensures the effective exchange coupling of magnetically hard and soft phases. High magnetic materials, the performance of conventional bulk permanent magnetic ma- terials is limited by its

Liu, J. Ping

177

Pd-vacancy complex in Ge: TDPAC and ab initio study  

SciTech Connect (OSTI)

Low temperature metal-induced-crystallized germanium is a promising alternative for silicon in Complementary Metal-Oxide-Semiconductor (CMOS) technology. Palladium (Pd) is one of the metals suitable for inducing the low temperature crystallization. It is not certain, how residual Pd atoms are integrated into the Ge lattice. Therefore, time-different ?-? perturbed angular correlation (TDPAC) technique using the {sup 100}Pd(?{sup 100}Rh) nuclear probe has been applied to study the hyperfine interactions of this probe in single crystalline undoped Ge. A Pd-vacancy (Pd-V) complex with a unique interaction frequency of 8.4(2) Mrad/s has been identified. The Pd-V complex has been measured to have a maximum fraction after annealing at 350 °C. Density functional theory calculations have confirmed that the Pd-V complex may have the split-vacancy configuration in Ge, in contrast to the full-vacancy configuration observed in Si.

Abiona, Adurafimihan A.; Kemp, Williams; Timmers, Heiko [School of Physical, Environmental and Mathematical Sciences, The University of New South Wales, UNSW Canberra, PO Box 7916, Canberra BC 2610 (Australia)

2014-02-21T23:59:59.000Z

178

Reactivity and stability of platinum and platinum alloy catalysts toward the oxygen reduction reaction  

E-Print Network [OSTI]

Density functional theory (DFT) is used to study the reactivity of Pt and Pt-M (M: Pd, Co, Ni, V, and Rh) alloy catalysts towards the oxygen reduction reaction (ORR) as a function of the alloy overall composition and surface atomic distribution...

Calvo, Sergio Rafael

2009-05-15T23:59:59.000Z

179

Approved Module Information for AM20PD, 2014/5 Module Title/Name: Probability Distributions Module Code: AM20PD  

E-Print Network [OSTI]

Code: AM20PD School: Engineering and Applied Science Module Type: Standard Module New Module? No Module? Not Specified Module Dependancies Pre-requisites: Transition Mathematics (AM10TM). Statistics and ProbabilityApproved Module Information for AM20PD, 2014/5 Module Title/Name: Probability Distributions Module

Neirotti, Juan Pablo

180

Improving the phase stability and oxidation resistance of B-NiAl  

SciTech Connect (OSTI)

High temperature alloys are essential to many industries that require a stable material to perform in harsh oxidative environments. Many of these alloys are suited for specific applications such as jet engine turbine blades where most other materials would either melt or oxidize and crumble (1). These alloys must have a high melting temperature, excellent oxidation resistance, good creep resistance, and decent fracture toughness to be successfully used in such environments. The discovery of Ni based superalloys in the 1940s revolutionized the high temperature alloy industry and there has been continued development of these alloys since their advent (2). These materials are capable of operating in oxidative environments in the presence of combustion gases, water vapor and at temperatures around 1050 C. Demands for increased f uel efficiency, however, has highlighted the need for materials that can be used under similar atmospheres and at temperatures in excess of 1200 C. The current Ni based superalloys are restricted to lower temperatures due to the presence of a number of low melting phases that result in softening of the alloys above 1000 C. Therefore, recent research has been aimed at exploring and developing newer alloy systems that can meet the escalating requirements. This thesis comprises a part of such an effort. The motivation of this work is to develop a novel high temperature alloy system that shows improved performance at higher temperatures than the currently employed alloys. The desired alloy should be in accordance with the requirements established in the National Energy Technology Laboratory (NETL) FutureGen program having an operating temperature around 1300 C. Alloys based on NiAl offer significant potential payoffs as structural materials in gas turbine applications due to a unique range of physical and mechanical properties. Alloying additions to NiAl could be used to further improve the pertinent properties that currently limit this system from replacing Ni based superalloys. Modifications to NiAl were explored to increase the phase stability and oxidation resistance which would allow these alloys to be used at even higher temperatures yielding greater efficiencies. The extended Miedema model was an effective tool that screened all of the potential phase space for ternary substitutions to NiAl and found the few potential systems worth further investigation. After production of the alloys it was determined that Ir, Rh, and Pd were the top candidates for substitution on Ni site up to 12 at%. The melting temperature of NiAl could be increased as much as 150 C with 12 at% Ir and 130 C with 12 at% Rh substitution. Pall adium on the other hand decreased the melting temperature by 50 C at the 12 at% substitution level. The grain size was found to have a profound influence on the oxidation resistance. Both Ir and Rh substitutions resulted in finer grain sizes compared to Pd substitutions or base NiAl. The grain size increased drastically during high temperature annealing with the PGM substitutions hindering grain growth only slightly. However, the addition of 0.05 at% Hf limited the grain growth dramatically during high temperature annealing. NiAl inherently has respectable oxidation resistance up to 1100 C. It was found through experimental testing that both Ir and Rh substitutions improve the oxidation resistance of NiAl at ultra-high temperatures with Ir performing the best. Both PGM substitutions decreased the growth rate as well as forming a more adherent oxide scale. Pd substitutions appeared to have a negligible effect to the oxidation resistance of NiAl. Hafnium addition of 0.05 at% was found to decrease the oxidation rate as well as increase the scale adherence. The combination of both Ir substitution (6-9 at%) and Hf addition (0.05 at%) produced the alloy with the best oxidation resistance. Although improvements in phase stability and oxidation resistance have been made to the NiAl system, more development and testing are still needed. Two major issues yet to be resolved are the low fracture toughn

Brammer, Travis

2011-08-15T23:59:59.000Z

Note: This page contains sample records for the topic "ni pd pt" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Microstructure and Corrosion Behavior of the Cu-Pd-X Ternary Alloys for Hydrogen Separation Membranes  

SciTech Connect (OSTI)

CuPd alloys are among the most promising candidate materials for hydrogen separation membranes and membrane reactor applications due to their high hydrogen permeability and better sulfur resistance. In order to reduce the Pd content and, therefore, the cost of the membrane materials, efforts have been initiated to develop CuPdM ternary alloys having a bcc structure. The advantages of having Pd as a hydrogen separation membrane are: (1) high hydrogen selectivity; and (2) high hydrogen permeability. The disadvantages are: (1) high cost; (2) hydrogen embrittlement ({alpha} {yields} {beta} Pd hydride); and (3) sulfur poisoning. Experiments (XRD, SEM/EDS) verified that Mg, Al, La, Y and Ti are promising alloying elements to expand the B2 phase region in Cu-Pd binary system. HT-XRD showed that the B2 to FCC transition temperatures for Cu-Pd-X (X = Mg, Al, La, Y and Ti) are higher than that of Cu-Pd binary alloys. While the Cu-50Pd alloy had the highest corrosion resistance to the H2S containing syngas, the Cu-Pd-Mg alloy had a comparable resistance.

O.N. Dogan; M.C. Gao; B.H. Howard

2012-02-26T23:59:59.000Z

182

Interaction of carbon monoxide with oxygen in the adsorbed layer on Pd, Ce, Pd-Ce catalysts supported on /gamma/-Al/sub 2/O/sub 3/  

SciTech Connect (OSTI)

The adsorption of CO and the interaction of CO/sub ads/ with O/sub 2/ on Pd, Ce, and Pd-Ce//gamma/-Al/sub 2/O/sub 3/ (0.5 wt. % Pd, 2.0 wt. % Ce) has been studied using the methods of IR spectroscopy and differential scanning calorimetry. The identity of the adsorbed CO complexes, the temperature ranges over which they desorb, and their reactivity with O/sub 2/ have been established. The interaction of bridging and carbonate - carboxylate CO complexes and carbon (disproportionation and dissociation products) with O/sub 2/ on Pd and Pd-Ce catalysts is preceded by the coadsorption of oxygen and the evolution of heat. During the oxidation of CO, autooscillation, heat evolution, and the concentration of oxygen in the flow are observed.

Savel'eva, G.A.; Sass, A.S.; Speranskaya, G.V.; Tenchev, K.K.; Petrov, L.A.; Vozdvizhenskii, V.F.; Galeev, T.K.; Popova, N.M.

1989-01-01T23:59:59.000Z

183

Thermally stable perpendicular magnetic anisotropy features of [Co/Pd]{sub m} multilayer matrix integrated with [CoO/Pd]{sub n} bottom layer  

SciTech Connect (OSTI)

We evaluated the perpendicular magnetic anisotropy (PMA) features of a hybrid [CoO/Pd]{sub 2}/[Co/Pd]{sub 7} multilayer (ML) matrix under annealing in which the [CoO/Pd]{sub 2} bottom layer was inserted. Annealing allowed for the diffusion of oxygen atoms existing in the inserted [CoO/Pd]{sub 2} layer, leading to an atomic structural reconfiguration event. The hybrid matrix was crucial to result in a higher effective anisotropy energy (3.40 Merg/cc) than an ordinary [Co/Pd]{sub 7} ML matrix (1.25 Merg/cc) under annealing at 450?°C. X-ray photoelectron spectroscopy confirmed the presence of Co-O bonding states and annealing dependent oxygen atom diffusion. The possible nature of the enhanced PMA features is discussed.

Lee, JaBin; An, GwangGuk; Yang, SeungMo; Hong, JinPyo, E-mail: jphong@hanyang.ac.kr [Novel Functional Materials and Device Laboratory, Department of Physics, The Research Institute for Natural Science, Hanyang University, Seoul 133-791 (Korea, Republic of); Chung, WooSeong [Nano Quantum Electronics Laboratory, Department of Electronics and Computer Engineering, Hanyang University, Seoul 133-791 (Korea, Republic of)

2014-01-13T23:59:59.000Z

184

Transformation Induced Fatigue of Ni-Rich NiTi Shape Memory Alloy Actuators  

E-Print Network [OSTI]

In this work the transformation induced fatigue of Ni-rich NiTi shape memory alloys (SMAs) was investigated. The aerospace industry is currently considering implementing SMA actuators into new applications. However, before any new applications can...

Schick, Justin Ryan

2011-02-22T23:59:59.000Z

185

Mechanism of O2 Activation and Methanol Production by (Di(2-pyridyl)methanesulfonate)PtII  

E-Print Network [OSTI]

conversion of methane to methanol at low temper- ature is crucial for transportation of shale gas produced it to methanol and its derivatives. In this system, the kinetics of the oxidation of Pt(II) is important because activation and selective conversion of Pt(II) monomethyl complex (dpms)PtII Me(OH2) to its monomethyl Pt

Goddard III, William A.

186

PT -symmetric quantum field theories and the Langevin equation  

E-Print Network [OSTI]

Hyde Park Rd., Santa Fe, NM 87501, USA and Theoretical Division, MSB285, Los Alamos National Laboratory, Los Alamos, NM 87545, USA Received 17 October 2003 Many non-Hermitian but PT -symmetric theories

Savage, Van M.

187

Pt-Co/C Catalysts: PEMFC Performance and Durability  

Broader source: Energy.gov (indexed) [DOE]

ratio - Particle size - Metal loading What causes the performance to drop during accelerated stress test? 2 Pt:Co atomic ratio - 2:1 to 9:1 Alloy particle size - 3 to 5...

188

Coupled Oscillator Systems Having Partial PT Symmetry  

E-Print Network [OSTI]

This paper examines chains of $N$ coupled harmonic oscillators. In isolation, the $j$th oscillator ($1\\leq j\\leq N$) has the natural frequency $\\omega_j$ and is described by the Hamiltonian $\\frac{1}{2}p_j^2+\\frac{1}{2}\\omega_j^2x_j^2$. The oscillators are coupled adjacently with coupling constants that are purely imaginary; the coupling of the $j$th oscillator to the $(j+1)$st oscillator has the bilinear form $i\\gamma x_jx_{j+1}$ ($\\gamma$ real). The complex Hamiltonians for these systems exhibit {\\it partial} $\\mathcal{PT}$ symmetry; that is, they are invariant under $i\\to-i$ (time reversal), $x_j\\to-x_j$ ($j$ odd), and $x_j\\to x_j$ ($j$ even). [They are also invariant under $i\\to-i$, $x_j\\to x_j$ ($j$ odd), and $x_j\\to- x_j$ ($j$ even).] For all $N$ the quantum energy levels of these systems are calculated exactly and it is shown that the ground-state energy is real. When $\\omega_j=1$ for all $j$, the full spectrum consists of a real energy spectrum embedded in a complex one; the eigenfunctions correspondi...

Beygi, Alireza; Bender, Carl M

2015-01-01T23:59:59.000Z

189

PT-invariant one-dimensional Coulomb problem  

E-Print Network [OSTI]

The one-dimensional Coulomb-like potential with a real coupling constant beta, and a centrifugal-like core of strength G = alpha^2 - {1/4}, viz. V(x) = {alpha^2 - (1/4)}/{(x-ic)^2} + beta/|x-ic|, is discussed in the framework of PT-symmetry. The PT-invariant exactly solvable model so formed, is found to admit a double set of real and discrete energies, numbered by a quasi-parity q = +/- 1.

Anjana Sinha; Rajkumar Roychoudhury

2002-07-23T23:59:59.000Z

190

$\\cal{PT}$ symmetric models with nonlinear pseudo supersymmetry  

E-Print Network [OSTI]

By applying the higher order Darboux algorithm to an exactly solvable non Hermitian ${\\cal{PT}}$ symmetric potential, we obtain a hierarchy of new exactly solvable non Hermitian ${\\cal{PT}}$ symmetric potentials with real spectra. It is shown that the symmetry underlying the potentials so generated and the original one is {\\it nonlinear pseudo supersymmetry}. We also show that this formalism can be used to generate a larger class of new solvable potentials when applied to non Hermitian systems.

A. Sinha; P. Roy

2005-05-30T23:59:59.000Z

191

Surface characterization of Pd/Al2O3 sorbents for mercury capture from fuel gas  

SciTech Connect (OSTI)

The surface composition of a series of Pd/alumina sorbents has been characterized to better understand the factors influencing their ability to adsorb mercury from fuel gas. Both a temperature effect and a dispersion effect were found. Maximum adsorption of Hg occurred at the -lowest temperature tested, 204°C, and decreased with increasing temperatures. Maximum adsorption of Hg on a per-atom basis of Pd is observed at low loadings of Pd ( < 8.5% Pd) due to better dispersion of Pd at those loadings; a change in its partitioning occurs at higher loadings. The presence of H2S 'in the fuel gas acts to promote the adsorption of Hg through its association with Hg in the Pd lattice.

Baltrus, J.P.; Granite, E.J.; Stanko, D.C.; Pennline, H.W.

2008-01-01T23:59:59.000Z

192

Surface characterization of Pd/Al2O3 sorbents for mercury capture from fuel gas  

SciTech Connect (OSTI)

The surface composition of a series of Pd/alumina sorbents has been characterized to better understand the factors influencing their ability to adsorb mercury from fuel gas. Both a temperature effect and a dispersion effect were found. Maximum adsorption of Hg occurred at the lowest temperature tested, 2048C, and decreased with increasing temperatures. Maximum adsorption of Hg on a per-atom basis of Pd is observed at low loadings of Pd (58.5% Pd) due to better dispersion of Pd at those loadings; a change in its partitioning occurs at higher loadings. The presence of H2S in the fuel gas acts to promote the adsorption of Hg through its association with Hg in the Pd lattice.

Baltrus, J.P.; Granite, E.J.; Stanko, D.C.; Pennline, H.W.

2008-09-01T23:59:59.000Z

193

Oxygen-induced Y surface segregation in a CuPdY ternary alloy  

SciTech Connect (OSTI)

We present a comprehensive theoretical and experimental study of the segregation behavior of the ternary alloy CuPdY in vacuum (i.e., the clean surface) and in the presence of oxygen. Theoretical prediction shows that for clean surface, yttrium will substitute first for Cu and then for Pd at the subsurface lattice site before segregating to the surface where it substitutes for Cu. XRD characterization of the surface of CuPdY indicates the presence of two major phases, B2 CuPd and Pd{sub 3}Y. In the presence of adsorbed oxygen, theory predicts that Y preferentially occupies surface sites due to its stronger oxygen affinity compared to Cu and Pd. XPS experiments confirm the computational results in the adsorbed oxygen case, showing that surface segregation of yttrium is induced by the formation of Y-oxides at the top-surface of the alloy.

Tafen, D. N.; Miller, J. B.; Dogan, O. N.; Baltrus, J. P.; Kondratyuk, P.

2013-01-01T23:59:59.000Z

194

Underpotential deposition of Ag adlayers on Pt(111): Structures and determination of O{sub 2} adsorption on Pt(111)  

SciTech Connect (OSTI)

The structure of Ag adlayers deposited at underpotentials in sulfuric acid on Pt(111), and the inhibition of O{sub 2} reduction they cause, have been studied using grazing incident angle x-ray diffraction measurements, as well as linear sweep voltammetry and in situ FTIR spectroscopy. Ag forms a hexagonal incommensurate bilayer, with two mutually commensurate monolayers. It is aligned with the Pt(111) substrate, although slightly expanded. The first monolayer has a commensurate (1 x 1) structure. A second layer causes a restructuring of the first monolayer. Deposition of each monolayer is associated with one voltammetry Peak. A complete inhibition of O{sub 2} reduction on Pt(111) has been observed upon deposition of both, Ag monolayer and bilayer. Analysis of the inhibition of O{sub 2} reduction as a function of the Ag coverage shows that during reduction O{sub 2} adsorbs in a bridge configuration on Pt(111).

Marinkovic, N.S.; Wang, J.X.; Adzic, R.R.

1997-09-01T23:59:59.000Z

195

Indirect heating of Pt by non-equilibrium electrons in Au in a nanoscale Pt/Au bilayer  

E-Print Network [OSTI]

-line equivalent-circuit. For optical exciation of either the Pt or Au side of the bilayer, the majority of energy excitations which are then driven out of thermal equilibrium with the vibrations of the atomic lattice.1

Cahill, David G.

196

Interfacial oxygen migration and its effect on the magnetic anisotropy in Pt/Co/MgO/Pt films  

SciTech Connect (OSTI)

This paper reports the interfacial oxygen migration effect and its induced magnetic anisotropy evolution in Pt/Co/MgO/Pt films. During depositing the MgO layer, oxygen atoms from the MgO combine with the neighboring Co atoms, leading to the formation of CoO at the Co/MgO interface. Meanwhile, the films show in-plane magnetic anisotropy (IMA). After annealing, most of the oxygen atoms in CoO migrate back to the MgO layer, resulting in obvious improvement of Co/MgO interface and the enhancement of effective Co-O orbital hybridization. These favor the evolution of magnetic anisotropy from IMA to perpendicular magnetic anisotropy (PMA). The oxygen migration effect is achieved by the redox reaction at the Co/MgO interface. On the contrary, the transfer from IMA to PMA cannot be observed in Pt/Co/Pt films due to the lack of interfacial oxygen migration.

Chen, Xi; Feng, Chun, E-mail: fengchun@ustb.edu.cn, E-mail: ghyu@mater.ustb.edu.cn; Liu, Yang; Jiang, Shaolong; Hua Li, Ming; Hua Yu, Guang, E-mail: fengchun@ustb.edu.cn, E-mail: ghyu@mater.ustb.edu.cn [Department of Materials Physics and Chemistry, University of Science and Technology Beijing, Beijing 100083 (China); Long Wu, Zheng [Analytical and Testing Center, Beijing Normal University, Beijing 100875 (China); Yang, Feng [State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Beijing 102249 (China)

2014-02-03T23:59:59.000Z

197

Electron-Transport Properties of Amorphous (Zr0.64ni0.36)1-Xalx Alloys  

E-Print Network [OSTI]

PHYSICAL REVIEW B VOLUME 39, NUMBER 17 15 JUNE 1989-I Electron transport properties of amorphous (Zro 64Nio 36), ?Al?alloys A. K. Bhatnagar, ' R. Pan, and D. G. Naugle Department ofPhysics, Texas Ad'cM Uniuersity, College Station, Texas 77843...-4242 (Received 28 November 1988; revised manuscript received 16 March 1989) Measurements of the electrical resistivity p(T), thermopower S(T), and Hall coe%cient RH for a series of rapidly quenched Zr-Ni-Al alloys are reported for concentrations from x =0 to 0...

BHATNAGAR, AK; PAN, R.; Naugle, Donald G.

1989-01-01T23:59:59.000Z

198

Monopole Strength in Ni-58  

E-Print Network [OSTI]

PHYSICAL REVIEW C VOLUME 44, NUMBER 5 Monopole strength in Ni NOVEMBER 1991 D. H. Youngblood and Y.-W. Lui Cyclotron Institute, Texas AdkM Uni Uersi ty, College Station, Texas 77843 (Received 20 June 1991) Differential cross-section data from... strength is locat- ed nearer the quadrupole (for Ca [3] and Si [4] at vir- tually the same energy). Only two reports of substantial strength in lighter nuclei are in the literature. Lui et al. [4] reported 66%%uo of the EO energy-weighted sum rule...

Youngblood, David H.; Lui, YW.

1991-01-01T23:59:59.000Z

199

The beta-delayed neutron emission in 78Ni region  

E-Print Network [OSTI]

A systematic study of the total $\\beta$-decay half-lives and $\\beta$-delayed neutron emission probabilities is performed. The $\\beta$-strength function is treated within the self-consistent density-functional + continuum-QRPA framework including the Gamow-Teller and first-forbidden transitions. The experimental total $\\beta$-decay half-lives for the Ni isotopes with $A\\leq$76 are described satisfactorily. The half-lives predicted from $A$=70 up to $A$=86 reveal fairly regular $A$-behaviour which results from simultaneous account for the Gamow-Teller and first-forbidden transitions. For $Z\\approx$ 28 nuclei, a suppression of the delayed neutron emission probability is found when the $N$=50 neutron closed shell is crossed. The effect originates from the high-energy first-forbidden transitions to the states outside the $Q_{\\beta} - S_n$-window in the daughter nuclei. PACS numbers: 23.40.Bw,21.60.Jz,25.30.Pt,26.30.+k

I. N. Borzov

2004-09-09T23:59:59.000Z

200

The beta-delayed neutron emission in 78Ni region  

E-Print Network [OSTI]

A systematic study of the total $\\beta$-decay half-lives and $\\beta$-delayed neutron emission probabilities is performed. The $\\beta$-strength function is treated within the self-consistent density-functional + continuum-QRPA framework including the Gamow-Teller and first-forbidden transitions. The experimental total $\\beta$-decay half-lives for the Ni isotopes with $A\\leq$76 are described satisfactorily. The half-lives predicted from $A$=70 up to $A$=86 reveal fairly regular $A$-behaviour which results from simultaneous account for the Gamow-Teller and first-forbidden transitions. For $Z\\approx$ 28 nuclei, a suppression of the delayed neutron emission probability is found when the $N$=50 neutron closed shell is crossed. The effect originates from the high-energy first-forbidden transitions to the states outside the $Q_{\\beta} - S_n$-window in the daughter nuclei. PACS numbers: 23.40.Bw,21.60.Jz,25.30.Pt,26.30.+k

Borzov, I N

2004-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "ni pd pt" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

anketo chosa ni: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: Recent research shows that the resistance switching characteristics of NiO thin film, in combinations conversion into NiSi using Ni-AMD, and discuss the chemistry of...

202

anteisei ni kansuru: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: Recent research shows that the resistance switching characteristics of NiO thin film, in combinations conversion into NiSi using Ni-AMD, and discuss the chemistry of...

203

atsumitsu katei ni: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: Recent research shows that the resistance switching characteristics of NiO thin film, in combinations conversion into NiSi using Ni-AMD, and discuss the chemistry of...

204

arikata ni kansuru: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: Recent research shows that the resistance switching characteristics of NiO thin film, in combinations conversion into NiSi using Ni-AMD, and discuss the chemistry of...

205

ataeru eikyo ni: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: Recent research shows that the resistance switching characteristics of NiO thin film, in combinations conversion into NiSi using Ni-AMD, and discuss the chemistry of...

206

aisorui ni taisuru: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: Recent research shows that the resistance switching characteristics of NiO thin film, in combinations conversion into NiSi using Ni-AMD, and discuss the chemistry of...

207

anzensei ni kansuru: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: Recent research shows that the resistance switching characteristics of NiO thin film, in combinations conversion into NiSi using Ni-AMD, and discuss the chemistry of...

208

Waste Heat Energy Harvesting Using Olsen Cycle on PZN-5.5PT Single Crystals  

E-Print Network [OSTI]

1 µ m thick Au 0.68 Pd 0.32 electrode. (a) (b) Displacement,1 µ m thick Au 0.68 Pd 0.32 electrodes having ? =16,951 kg/m

McKinley, Ian Meeker; Kandilian, Razmig; Pilon, Laurent

2012-01-01T23:59:59.000Z

209

The PD algorithm: a simulation based partitioning algorithm for ATPG  

E-Print Network [OSTI]

is shown in Figure 17 3(d). Figure 3(d) is very similar to Figure 3(b) but the line f fans out to the gate G8 which is also driven by control line b. There are no circuit graph dommators of the faulty site in this case. Before any attempt to propagate... performs the following tasks. 1. Perform logic calculation. 2. Based on the output value, assign necessary input values. 3. Maintain all stacks. 4. Detect tf there is a conflict, OS dd D' d~ O d(I Sdd dd S I 7 7 P I 4~17 d~ pd PO ~ dd D4 dd...

Lin, Shyh-Horng

1993-01-01T23:59:59.000Z

210

Infrared vibrational studies of CO adsorption on Cu/Pt(lll) and CuPt(111) Jo& A. Rodriguez,@ Charles M. Truong, and D. Wayne Goodmanb)  

E-Print Network [OSTI]

Infrared vibrational studies of CO adsorption on Cu/Pt(lll) and CuPt(111) surfaces Jo& A. Rodriguez supported on Pt ( 111) has been studied using infrared reflection absorption spectroscopy (IRAS). Our results indicate that the infrared intensities of adsorbed CO are not representative of the relative

Goodman, Wayne

211

Electrodeposited NiCo/Cu Superlattices  

SciTech Connect (OSTI)

NiCo/Cu superlattices were electrodeposited on polycrystalline Cu substrates from a single electrolyte under potentiostatic control. The X-ray diffraction (XRD) patterns showed that NiCo/Cu superlattices have the same crystal structure and texture as in their substrates. The films exhibited giant magnetoresistance (GMR) or anisotropic magnetoresistance (AMR), depending on the Cu layer thicknesses.

Safak, M.; Alper, M. [Department of Physics, Faculty of Science and Literature, University of Uludag, Goeruekle, Bursa (Turkey)

2007-04-23T23:59:59.000Z

212

Nanoscale structural heterogeneity in Ni-rich half-Heusler TiNiSn  

SciTech Connect (OSTI)

The structural implications of excess Ni in the TiNiSn half-Heusler compound are examined through a combination of synchrotron x-ray and neutron scattering studies, in conjunction with first principles density functional theory calculations on supercells. Despite the phase diagram suggesting that TiNiSn is a line compound with no solid solution, for small x in TiNi{sub 1+x}Sn there is indeed an appearance—from careful analysis of the scattering—of some solubility, with the excess Ni occupying the interstitial tetrahedral site in the half-Heusler structure. The analysis performed here would point to the excess Ni not being statistically distributed, but rather occurring as coherent nanoclusters. First principles calculations of energetics, carried out using supercells, support a scenario of Ni interstitials clustering, rather than a statistical distribution.

Douglas, Jason E., E-mail: jedouglas@mrl.ucsb.edu; Pollock, Tresa M. [Materials Department, University of California, Santa Barbara, California 93106 (United States); Materials Research Laboratory, University of California, Santa Barbara, California 93106 (United States); Chater, Philip A. [Diamond Light Source, Chilton, Oxfordshire OX11 0DE (United Kingdom); Brown, Craig M. [Center for Neutron Research, National Institute of Standards and Technology, Gaithersburg, Maryland 20899 (United States); Department of Chemical Engineering, University of Delaware, Newark, Delaware 19716 (United States); Seshadri, Ram [Materials Department, University of California, Santa Barbara, California 93106 (United States); Materials Research Laboratory, University of California, Santa Barbara, California 93106 (United States); Department of Chemistry and Biochemistry, University of California, Santa Barbara, California 93106 (United States)

2014-10-28T23:59:59.000Z

213

Purification and Characterization of [NiFe]-Hydrogenase of Shewanella...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Purification and Characterization of NiFe-Hydrogenase of Shewanella oneidensis MR-1. Purification and Characterization of NiFe-Hydrogenase of Shewanella oneidensis MR-1....

214

al ni shape: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

NiAl NANOLAMINATES . Open Access Theses and Dissertations Summary: ??To characterize the self-propagating, high-temperature exothermic alloying reactions of NiAl nanoscaled...

215

Direct Determination of the Ionization Energies of PtC, PtO, and PtO2 with VUV Murat Citir and Ricardo B. Metz*  

E-Print Network [OSTI]

and carbides. I. Introduction Transition-metal oxides and carbides have been the subject of numerous transition-metal oxide cations, including PtO+, can directly convert methane to methanol. Schwarz and co energies and bond dissociation energies for catalytically interesting species such as metal oxides

Metz, Ricardo B.

216

Co-Pt core-shell nanostructured catalyst prepared by selective chemical vapor pulse deposition of Pt on Co as a cathode in polymer electrolyte fuel cells  

SciTech Connect (OSTI)

A new type of PtCo/C catalyst for use as a cathode in polymer electrolyte fuel cells was prepared by selective chemical vapor pulse deposition (CVPD) of Pt on the surface of Co. The activity of the prepared catalyst for oxygen reduction was higher than that of a catalyst prepared by sequential impregnation (IMP) with the two metallic components. This catalytic activity difference occurs because the former catalyst has smaller Pt crystallites that produce stronger Pt-Co interactions and have a larger Pt surface area. Consequently, the CVPD catalyst has a great number of Co particles that are in close contact with the added Pt. The Pt surface was also electronically modified by interactions with Co, which were stronger in the CVPD catalyst than in the IMP catalyst, as indicated by X-ray diffraction, X-ray photoemission spectroscopy, and cyclic voltammetry measurements of the catalysts.

Seo, Sang-Joon; Chung, Ho-Kyoon [SKKU Advanced Institute of Nanotechnology (SAINT) and Center for Human Interface Nanotechnology (HINT), Sungkyunkwan University, Suwon, Gyeonggi 440-746 (Korea, Republic of); Yoo, Ji-Beom [SKKU Advanced Institute of Nanotechnology (SAINT) and Center for Human Interface Nanotechnology (HINT), Sungkyunkwan University, Suwon, Gyeonggi 440-746, Korea and School of Advanced Materials Science and Engineering, Sungkyunkwan University, Suwon, Gyeonggi 440-746 (Korea, Republic of); Chae, Heeyeop; Seo, Seung-Woo; Min Cho, Sung, E-mail: sungmcho@skku.edu [School of Chemical Engineering, Sungkyunkwan University, Suwon, Gyeonggi 440-746 (Korea, Republic of)

2014-01-15T23:59:59.000Z

217

Letters to the Editor STEM imaging of single Pd atoms in activated carbon fibers  

E-Print Network [OSTI]

Letters to the Editor STEM imaging of single Pd atoms in activated carbon fibers considered individual Pd atoms that are highly dispersed throughout the vol- ume of activated carbon fibers by adding transition metals to their microstructure [1]. For instance, activated carbon fibers (ACFs

Pennycook, Steve

218

PD Dr. Martin Stetter, Siemens AG 1 Statistische und neuronale Lernverfahren  

E-Print Network [OSTI]

PD Dr. Martin Stetter, Siemens AG 1 Statistische und neuronale Lernverfahren Martin Stetter SS 2003, Siemens AG 2 Behandelte Themen 0. ,,Motivation": Lernen in Statistik und Biologie 1-Regression 4. Bayes-Belief-Netze Statistische und neuronale Lernverfahren #12;PD Dr. Martin Stetter, Siemens AG

Popeea, Corneliu - Chair for Foundations of Software Reliability and Theoretical Computer Science

219

PD Dr. Martin Stetter, Siemens AG 1 Statistische und neuronale Lernverfahren  

E-Print Network [OSTI]

PD Dr. Martin Stetter, Siemens AG 1 Statistische und neuronale Lernverfahren Martin Stetter WS 03, Siemens AG 2 Behandelte Themen 0. ,,Motivation": Lernen in Statistik und Biologie 1-Regression 4. Bayes-Belief-Netze Statistische und neuronale Lernverfahren #12;PD Dr. Martin Stetter, Siemens AG

Popeea, Corneliu - Chair for Foundations of Software Reliability and Theoretical Computer Science

220

Ion channeling and TEM studies of pulse-melted Fe(Pd) alloys  

SciTech Connect (OSTI)

Metastable Fe(Pd) surface alloys formed by deposition of layers of Pd on (100) Fe and subsequent pulsed (approx. 70 nsec, 1.9 J/cm/sup 2/) electron beam melting into the bcc substrate have been investigated by ion backscattering/channeling and TEM. Repeated pulsed melting allowed examination of the epitaxial growth of the bcc substrate phase into the alloyed region for successively lower Pd concentrations. This procedure permitted detailed examination of the conditions for solidification with the fcc or bcc crystal structure and for metastable phase formation during rapid solidification. Bcc epitaxy is absent at Pd concentrations greater than or equal to 30 at. %, where an fcc surface layer forms. Channeling of the Pd and Fe signals was observed at Pd concentrations less than or equal to 16.5 at. %, where a single-phase, supersaturated bcc alloy is observed. At an intermediate Pd concentration of 22 to 23 at. %, both epitaxial bcc and fcc materials are formed. The observed maximum substitutional Pd concentration in the bcc phase is about a factor of 5 greater than the maximum equilibrium solid solubility.

Knapp, J.A.; Follstaedt, D.M.

1983-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "ni pd pt" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

NANO EXPRESS Open Access Au/Pd core-shell nanoparticles with varied hollow  

E-Print Network [OSTI]

NANO EXPRESS Open Access Au/Pd core-shell nanoparticles with varied hollow Au cores for enhanced on hollow Au nanospheres. The unique nanoparticles were characterized by X-ray diffraction, X of the polycrystalline hollow Au nanospheres was reduced, and the structures became highly porous. After the Pd shell

Liu, Fuqiang

222

Vacancy Jumps in PdIn: Reconciling Nuclear Relaxation and Diffusion Measurements  

E-Print Network [OSTI]

Vacancy Jumps in PdIn: Reconciling Nuclear Relaxation and Diffusion Measurements Gary S. Collins Keywords: point defect, vacancy, diffusion, defect interaction, intermetallic compound, perturbed angular correlation, PAC, nuclear relaxation, diffusion mechanisms Abstract. Vacancy jump frequencies in PdIn were

Collins, Gary S.

223

Edinburgh Research Explorer Quantifying the implicit process flow abstraction in SBGN-PD  

E-Print Network [OSTI]

Edinburgh Research Explorer Quantifying the implicit process flow abstraction in SBGN-PD diagrams the implicit process flow abstraction in SBGN-PD diagrams with Bio-PEPA'. in Proceedings of COMPMOD 2009. ETPCS to publication record in Edinburgh Research Explorer Published In: Proceedings of COMPMOD 2009 General rights

Millar, Andrew J.

224

SEARCH FOR CHARGED -PARTICLE d -d FUSION PRODUCTS IN AN ENCAPSULATED Pd THIN FILM  

E-Print Network [OSTI]

SEARCH FOR CHARGED - PARTICLE d - d FUSION PRODUCTS IN AN ENCAPSULATED Pd THIN FILM E. López, B the possibility of deuteron-deuteron (d-d) fusion at room temperature within the bulk palladium electrode / Pd ratio exceeding 100 %. The palladium film was encapsulated with a thin layer of silicon nitride

Neuhauser, Barbara

225

Chin. Phys. B Vol. 20, No. 11 (2011) 113301 Highly dispersed Pd nanoparticles on chemically  

E-Print Network [OSTI]

Chin. Phys. B Vol. 20, No. 11 (2011) 113301 Highly dispersed Pd nanoparticles on chemically electrode material based on chemically modified graphene (CMG) with aminophenyl groups is covalently of the Pd/CMG composite towards formic acid oxidation are found to be higher than those of reduced graphene

Gao, Hongjun

2011-01-01T23:59:59.000Z

226

Pd and Ag metal-silicate partitioning applied to Earth differentiation and core-mantle exchange  

E-Print Network [OSTI]

Pd and Ag metal-silicate partitioning applied to Earth differentiation and core-mantle exchange metallic sulfide and liquid silicate under plausible magma ocean conditions constrains potential core 107 Ag content and the origin of observed Pd and Ag mantle abundances. DPd metallic sulfide / silicate

Mcdonough, William F.

227

Scattering in a varying mass PT symmetric double heterojunction  

E-Print Network [OSTI]

We observe that the reflection and transmission coefficients of a particle within a double, PT symmetric heterojunction with spatially varying mass, show interesting features, depending on the degree of non Hermiticity, although there is no spontaneous breakdown of PT symmetry. The potential profile in the intermediate layer is considered such that it has a non vanishing imaginary part near the heterojunctions. Exact analytical solutions for the wave function are obtained, and the reflection and transmission coefficients are plotted as a function of energy, for both left as well as right incidence. As expected, the spatial dependence on mass changes the nature of the scattering solutions within the heterojunctions, and the space-time (PT) symmetry is responsible for the left-right asymmetry in the reflection and transmission coefficients. However, the non vanishing imaginary component of the potential near the heterojunctions gives new and interesting results.

Anjana Sinha; R. Roychoudhury

2013-06-10T23:59:59.000Z

228

Equiatomic CoPt thin films with extremely high coercivity  

SciTech Connect (OSTI)

In this paper, magnetic and structural properties of near-equiatomic CoPt thin films, which exhibited a high coercivity in the film-normal direction—suitable for perpendicular magnetic recording media applications—are reported. The films exhibited a larger coercivity of about 6.5 kOe at 8?nm. The coercivity showed a monotonous decrease as the film thickness was increased. The transmission electron microscopy images indicated that the as fabricated CoPt film generally consists of a stack of magnetically hard hexagonal-close-packed phase, followed by stacking faults and face-centred-cubic phase. The thickness dependent magnetic properties are explained on the basis of exchange-coupled composite media. Epitaxial growth on Ru layers is a possible factor leading to the unusual observation of magnetically hard hcp-phase at high concentrations of Pt.

Varghese, Binni; Piramanayagam, S. N., E-mail: Prem-SN@dsi.a-star.edu.sg; Yang, Yi; Kai Wong, Seng; Khume Tan, Hang; Kiat Lee, Wee [Data Storage Institute, (A-STAR) Agency for Science, Technology and Research, DSI Building, 5, Engineering Drive 1, Singapore 117608 (Singapore); Okamoto, Iwao [Western Digital Corporation, Singapore 638552 (Singapore)

2014-05-07T23:59:59.000Z

229

Ni{sub 3}Al aluminide alloys  

SciTech Connect (OSTI)

This paper provides a brief review of the recent progress in research and development of Ni{sub 3}Al and its alloys. Emphasis has been placed on understanding low ductility and brittle fracture of Ni{sub 3}Al alloys at ambient and elevated temperatures. Recent studies have resulted in identifying both intrinsic and extrinsic factors governing the fracture behavior of Ni{sub 3}Al alloys. Parallel efforts on alloy design using physical metallurgy principles have led to properties for structural use. Industrial interest in these alloys is high, and examples of industrial involvement in processing and utilization of these alloys are briefly mentioned.

Liu, C.T.

1993-10-01T23:59:59.000Z

230

Thermal diffusion in Ni/Al multilayer  

SciTech Connect (OSTI)

Two Ni/Al multilayers deposited by ion beam sputtering of nominal design [Ni(200A)/Al(100A)] Multiplication-Sign 5 and [Ni(50A)/Al(227A)] Multiplication-Sign 5 on Si substrates were annealed at 200 Degree-Sign C. As-deposited and annealed samples were characterized by x-ray diffraction (XRD) and x-ray reflectometry (XRR). The effort was to study the path of alloying in the above two multilayers of same elements but of opposite stoichiometric ratio. We find distinct differences in alloying of these samples.

Swain, M.; Bhattacharya, D.; Singh, S.; Basu, S. [Solid State Physics Division, Bhabha Atomic Research Center, Mumbai 400085 (India); Gupta, M. [UGC-DAE-Consortium for Scientific Research, University Campus, Khandwa Road, Indore 452017 (India)

2013-02-05T23:59:59.000Z

231

Metastable phase diagram for Ni-implanted Al and pulse surface melted Al(Ni)  

SciTech Connect (OSTI)

The microstructure of <110> Al implanted with Ni was examined before and after subsequent electron beam pulsed surface melting (65 ns, 1.7 J/cm/sup 2/). Both processes were done with the Al substrate at room temperature. Implantation at several energies (160 to 15 keV) into a given sample produced a nearly constant measured Ni concentration through a approx. 0.1 ..mu..m region below the surface (7). Such samples with concentrations from 8 to 25 at. % Ni were examined, along with a sample with a peak concentration of 32 at. % Ni.

Follstaedt, D.M.; Picraux, S.T.

1984-01-01T23:59:59.000Z

232

Electroslag surfacing of steel shafting with Ni alloy 625 and 70Cu-30Ni strip  

SciTech Connect (OSTI)

A comprehensive study of electroslag surfacing (ESS) of steel with Ni Alloy 625 and 70Cu-30Ni strip electrodes was conducted to establish the feasibility of replacing forged bearing sleeves on propulsion shafting with integral weld surfacing. The base material was MIL-S-23284, Class 1 steel in the form of 41--66 cm (16--26 in.) diameter shafting and 76 mm (3 in.) thick flat plate. All ESS was carried out at a heat input level of approximately 5.9kJ/mm (150 kJ/in.) using 30 x 0.5 mm (1.2 x 0.02 in.) strip electrodes. Assessments of mechanical properties and microstructure of Ni Alloy 625 surfacing and 70Cu-30Ni surfacing were conducted to establish the structure-property relationships in these complex alloy systems. In addition, a solidification cracking test was developed to determine the relative cracking susceptibilities of these strip surfacing alloys. Although the Ni Alloy 625 surfacing contained small islands of interdendritic MC type carbides and Laves phase, the mechanical properties of this surfacing were satisfactory. The 70Cu-30Ni surfacing required a buttering layer of 30Cu-70Ni or pure Ni to prevent solidification cracking. The inherent ductility-dip sensitivity of 70Cu-30Ni surfacing was overcome by the development of a suitable ESS procedure.

Devletian, J.H.; Gao, Y.P.; Wood, W.E. [Oregon Graduate Inst. of Science and Technology, Portland, OR (United States)

1996-12-31T23:59:59.000Z

233

The effect of impregnation sequence on the hydrogenation activity and selectivity of supported Pt/Ni bimetallic catalysts  

E-Print Network [OSTI]

of acetylene in the presence of ethylene [22], and the selective hydrogenation of acrolein toward its

Frenkel, Anatoly

234

New Ni Amidinate Source for ALD/CVD of NiNx, NiO and NiSi , Thiloma Perera1  

E-Print Network [OSTI]

to be particularly important in memory as well as logic applications. Nickel silicide (NiSi) is emerging with a metal-insulator-metal (MIM) structure, offer potential applications for the next generation nonvolatile

235

The durability dependence of Pt/CNT electrocatalysts on the nanostruct...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

The durability dependence of PtCNT electrocatalysts on the nanostructures of carbon nanotubes: hollow- and bamboo-CNTs. The durability dependence of PtCNT electrocatalysts on the...

236

Adsorption and diffusion of a single Pt atom on gamma-Al2O3 surfaces...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

understand the interactions between Pt and &61543;-Al2O3 support, the adsorption and diffusion of a single Pt atom on gamma-Al2O3 was studied using density functional theory....

237

Electrostatic Self-Assembly of Pt-around-Au Nanocomposite with...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Self-Assembly of Pt-around-Au Nanocomposite with High Activity towards Formic Acid Oxidation. Electrostatic Self-Assembly of Pt-around-Au Nanocomposite with High Activity towards...

238

Excellent Sulfur Resistance of Pt/BaO/CeO2 Lean NOx Trap Catalysts...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

NOx Trap Catalysts. Excellent Sulfur Resistance of PtBaOCeO2 Lean NOx Trap Catalysts. Abstract: In this work, we investigated the NOx storage behavior of Pt-BaOCeO2 catalysts,...

239

FTIR study of hydrogen and carbon monoxide adsorption on Pt/TiO{sub 2}, Pt/ZrO{sub 2}, and Pt/Al{sub 2}O{sub 3}  

SciTech Connect (OSTI)

The Pt/TiO{sub 2}, Pt/ZrO{sub 2}, and Pt/Al{sub 2}O{sub 3} catalysts submitted to low-temperature reduction (LTR,200 C) and high-temperature reduction (HTR, 500 C) and exposed to hydrogen and carbon monoxide at room temperature were studied by infrared spectroscopy. There is a strong loss of transmission in the entire infrared spectra on Pt/TiO{sub 2} after its exposure to hydrogen, which is related to the reducibility of the support. A typical SMSI behavior (strong metal-support interaction), such as the decrease in carbon monoxide adsorption capacity, was detected on Pt/TiO{sub 2} and Pt/ZrO{sub 2} after exposure to hydrogen, even for the catalysts submitted to LTR treatment. Also a carbonyl band shift to lower wavenumber was observed on LTR-treated Pt/TiO{sub 2}, Pt/ZrO{sub 2}, and Pt/Al{sub 2}O{sub 3} after exposure to hydrogen. The authors interpreted this SMSI behavior as an electronic rather than morphological effect, which was induced by the presence of hydrogen spillover.

Benvenutti, E.V.; Franken, L.; Moro, C.C.; Davanzo, C.U.

1999-11-09T23:59:59.000Z

240

PT symmetry of a conditionally exactly solvable potential  

E-Print Network [OSTI]

A conditionally exactly solvable potential, the supersymmetric partner of the harmonic oscillator is investigated in the PT-symmetric setting. It is shown that a number of properties characterizing shape-invariant and Natanzon-class potentials generated by an imaginary coordinate shift $x-{\\rm i}\\epsilon$ also hold for this potential outside the Natanzon class.

Anjana Sinha; Geza Levai; Pinaki Roy

2004-01-12T23:59:59.000Z

Note: This page contains sample records for the topic "ni pd pt" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Growth of Pt nanoparticle for proton-exchange-membrane fuel cells by  

E-Print Network [OSTI]

at anode side of a polymer electrolyte membrane (PEM) fuel cell. With a Pt loading of 25 g-Pt/cm2 , current, PEM fuel cell, Mass specific power density, Electrochemical active surface area, Oxygen reduction PEMFC Growth of Pt nanoparticle for proton-exchange-membrane fuel cells

242

PdAgAu alloy with high resistance to corrosion by H{sub 2}S  

SciTech Connect (OSTI)

PdAgAu alloy films were prepared on porous stainless steel supports by sequential electroless deposition. Two specific compositions, Pd{sub 83}Ag{sub 2}Au{sub 15} and Pd{sub 74}Ag{sub 14}Au{sub 12}, were studied for their sulfur tolerance. The alloys and a reference Pd foil were exposed to 1000 H{sub 2}S/H{sub 2} at 623 K for periods of 3 and 30 hours. The microstructure, morphology and bulk composition of both nonexposed and H{sub 2}S-exposed samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDS). XRD and SEM analysis revealed time-dependent growth of a bulk Pd{sub 4}S phase on the Pd foil during H{sub 2}S exposure. In contrast, the PdAgAu ternary alloys displayed the same FCC structure before and after H{sub 2}S exposure. In agreement with the XRD and SEM results, sulfur was not detected in the bulk of either ternary alloy samples by EDS, even after 30 hours of H{sub 2}S exposure. X-ray photoelectron spectroscopy (XPS) depth profiles were acquired for both PdAgAu alloys after 3 and 30 hours of exposure to characterize sulfur contamination near their surfaces. Very low S 2p and S 2s XPS signals were observed at the top-surfaces of the PdAgAu alloys, and those signals disappeared before the etch depth reached ~ 10 nm, even for samples exposed to H{sub 2}S for 30 hours. The depth profile analyses also revealed silver and gold segregation to the surface of the alloys; preferential location of Au on the alloys surface may be related to their resistance to bulk sulfide formation. In preliminary tests, a PdAgAu alloy membrane displayed higher initial H{sub 2} permeability than a similarly prepared pure Pd sample and, consistent with resistance to bulk sulfide formation, lower permeability loss in H{sub 2}S than pure Pd.

Braun, Fernando; Miller, James B.; Gellman, Andrew J.; Tarditi, Ana M.; Fleutot, Benoit; Petro, Kondratyuk, Cornaglia, Laura M

2012-12-01T23:59:59.000Z

243

Electronic circuits having NiAl and Ni.sub.3 Al substrates  

DOE Patents [OSTI]

An electronic circuit component having improved mechanical properties and thermal conductivity comprises NiAl and/or Ni.sub.3 Al, upon which an alumina layer is formed prior to applying the conductive elements. Additional layers of copper-aluminum alloy or copper further improve mechanical strength and thermal conductivity.

Deevi, Seetharama C. (Midlothian, VA); Sikka, Vinod K. (Oak Ridge, TN)

1999-01-01T23:59:59.000Z

244

Ni Sorption on Pyrophyllite: Evidence for the Formation of Ni-Al Hydroxide and Its Transformation into Ni-Silicate by Visible,  

E-Print Network [OSTI]

into Ni-Silicate by Visible, Infrared and XANES Spectroscopy and Thermogravimetry A. C. Scheinost, R. G suggest either the formation of layered double hydroxides or of layer silicates. Desorption studies polymerization of SiO causes the formation of 1:1 or 2:1 Ni silicates, where the original Ni-Al hydroxide

Sparks, Donald L.

245

Photosensitivity of the Ni-A state of [NiFe] hydrogenase from Desulfovibrio vulgaris Miyazaki F with visible light  

SciTech Connect (OSTI)

Highlights: Black-Right-Pointing-Pointer Ni-A state of [NiFe] hydrogenase showed light sensitivity. Black-Right-Pointing-Pointer New FT-IR bands were observed with light irradiation of the Ni-A state. Black-Right-Pointing-Pointer EPR g-values of the Ni-A state shifted upon light irradiation. Black-Right-Pointing-Pointer The light-induced state converted back to the Ni-A state under the dark condition. -- Abstract: [NiFe] hydrogenase catalyzes reversible oxidation of molecular hydrogen. Its active site is constructed of a hetero dinuclear Ni-Fe complex, and the oxidation state of the Ni ion changes according to the redox state of the enzyme. We found that the Ni-A state (an inactive unready, oxidized state) of [NiFe] hydrogenase from Desulfovibrio vulgaris Miyazaki F (DvMF) is light sensitive and forms a new state (Ni-AL) with irradiation of visible light. The Fourier transform infrared (FT-IR) bands at 1956, 2084 and 2094 cm{sup -1} of the Ni-A state shifted to 1971, 2086 and 2098 cm{sup -1} in the Ni-AL state. The g-values of g{sub x} = 2.30, g{sub y} = 2.23 and g{sub z} = 2.01 for the signals in the electron paramagnetic resonance (EPR) spectrum of the Ni-A state at room temperature varied for -0.009, +0.012 and +0.010, respectively, upon light irradiation. The light-induced Ni-AL state converted back immediately to the Ni-A state under dark condition at room temperature. These results show that the coordination structure of the Fe site of the Ni-A state of [NiFe] hydrogenase is perturbed significantly by light irradiation with relatively small coordination change at the Ni site.

Osuka, Hisao [Graduate School of Life Science, University of Hyogo, 3-2-1, Koto, Kamigori-cho, Ako-gun, Hyogo 678-1297 (Japan) [Graduate School of Life Science, University of Hyogo, 3-2-1, Koto, Kamigori-cho, Ako-gun, Hyogo 678-1297 (Japan); Graduate School of Materials Science, Nara Institute of Science and Technology, 8916-5, Takayama-cho, Ikoma-shi, Nara 630-0192 (Japan); Shomura, Yasuhito; Komori, Hirofumi; Shibata, Naoki [Graduate School of Life Science, University of Hyogo, 3-2-1, Koto, Kamigori-cho, Ako-gun, Hyogo 678-1297 (Japan)] [Graduate School of Life Science, University of Hyogo, 3-2-1, Koto, Kamigori-cho, Ako-gun, Hyogo 678-1297 (Japan); Nagao, Satoshi [Graduate School of Materials Science, Nara Institute of Science and Technology, 8916-5, Takayama-cho, Ikoma-shi, Nara 630-0192 (Japan)] [Graduate School of Materials Science, Nara Institute of Science and Technology, 8916-5, Takayama-cho, Ikoma-shi, Nara 630-0192 (Japan); Higuchi, Yoshiki, E-mail: hig@sci.u-hyogo.ac.jp [Graduate School of Life Science, University of Hyogo, 3-2-1, Koto, Kamigori-cho, Ako-gun, Hyogo 678-1297 (Japan) [Graduate School of Life Science, University of Hyogo, 3-2-1, Koto, Kamigori-cho, Ako-gun, Hyogo 678-1297 (Japan); CREST, JST, Gobancho, Chiyoda-ku, Tokyo 102-0076 (Japan); Hirota, Shun, E-mail: hirota@ms.naist.jp [Graduate School of Materials Science, Nara Institute of Science and Technology, 8916-5, Takayama-cho, Ikoma-shi, Nara 630-0192 (Japan) [Graduate School of Materials Science, Nara Institute of Science and Technology, 8916-5, Takayama-cho, Ikoma-shi, Nara 630-0192 (Japan); CREST, JST, Gobancho, Chiyoda-ku, Tokyo 102-0076 (Japan)

2013-01-04T23:59:59.000Z

246

Influence of surface segregation on magnetic properties of FePt nanoparticles  

SciTech Connect (OSTI)

Surface segregation leads to chemical disordering in magnetic alloy nanostructures and thus could have profound impact upon the magnetic properties of these nanostructures. In this study, we used the first-principles density functional theory calculation method to determine how Pt surface segregation (exchanging interior Pt with surface Fe atoms) would affect the magnetic properties of L1{sub 0} ordered FePt nanoparticles. For both cuboid and cuboctahedral FePt nanoparticles, we predicted that the Pt surface segregation process could cause a decrease in total magnetic moments, a change in (easy and/or hard) magnetization axes, and a reduction in magnetic anisotropy.

Lv, Hongyan [Department of Mechanical Engineering and Materials Science, University of Pittsburgh, Pittsburgh, Pennsylvania 15261 (United States) [Department of Mechanical Engineering and Materials Science, University of Pittsburgh, Pittsburgh, Pennsylvania 15261 (United States); Key Laboratory of Artificial Micro- and Nano-Structures of Ministry of Education and School of Physics and Technology, Wuhan University, Wuhan 430072 (China); Lei, Yinkai; Datta, Aditi; Wang, Guofeng [Department of Mechanical Engineering and Materials Science, University of Pittsburgh, Pittsburgh, Pennsylvania 15261 (United States)] [Department of Mechanical Engineering and Materials Science, University of Pittsburgh, Pittsburgh, Pennsylvania 15261 (United States)

2013-09-23T23:59:59.000Z

247

New insights into the nuclear structure in neutron-rich 112,114,115,116,117,118Pd  

SciTech Connect (OSTI)

New level schemes of 112,114,115,116,117,118Pd are established by means of ?–?–??–?–?, ?–?–?–??–?–?–? and ?–?(0)?–?(0) measurements of prompt fission y rays from 252Cf using the Gammasphere multi-detector array. Spins/parities were assigned to levels based on ?–??–? angular correlation measurements, level systematics and decay patterns. In the even-N isotopes 112,114,116Pd, two sets of odd-parity bands were identified and extended with spins measured in each band. The odd-parity bands with large level staggerings were interpreted as disturbed chirality with less pronounced triaxial deformations in the Pd isotopes than observed in the chiral symmetry breaking 110,112Ru with maximum triaxiality. Onset of wobbling motion was identified from the sign of the signature splitting in the ? band of even–even 114Pd, and probably also in 116Pd, as first seen in the N=68N=68 isotone 112Ru. Maximal triaxiality in Ru and Pd isotopes is found to be reached for N=68N=68, 112Ru and 114Pd, 4 neutrons more than predicted in the theoretical calculations. The new data and TRS calculations allowed a systematic study of the band crossings in the even-N112,114,116Pd and odd-N115,117Pd isotopes. Now we find a new overall, more complex shape evolution than previously proposed from triaxial prolate in 110Pd via triaxial oblate in 112Pd to nearly oblate in 114,116Pd with a large change of the triaxial deformation parameter y toward nearly oblate in the (pi g 9/2)2 alignment in 114,115,116,117,118Pd, and triaxial-prolate–triaxial-oblate shape coexisting bands in 115Pd.

Y. X. Luo; J. O. Rasmussen; J. H. Hamilton; A. V. Ramayya; S. Frauendorf; J. K. Hwang; N. J. Stone; S. J. Zhu; N. T. Brewer; E. Wang; I. Y. Lee; S. H. Liu; G. M. TerAkopian; A. V. Daniel; Yu.Ts. Oganessian; M. A. Stoyer; R. Donangelo; W.C. Ma; J. Cole; Yue Shi; F. R. Xu

2013-12-01T23:59:59.000Z

248

Nickel recovery from electronic waste II Electrodeposition of Ni and Ni–Fe alloys from diluted sulfate solutions  

SciTech Connect (OSTI)

Highlights: • Ni can be recovered from EG wastes as pure Ni or as Ni–Fe alloys. • The control of the experimental conditions gives a certain alloy composition. • Unusual deposits morphology shows different nucleation mechanisms for Ni vs Fe. • The nucleation mechanism was progressive for Ni and instantaneous for Fe and Ni–Fe. - Abstract: This study focuses on the electrodeposition of Ni and Ni–Fe alloys from synthetic solutions similar to those obtained by the dissolution of electron gun (an electrical component of cathode ray tubes) waste. The influence of various parameters (pH, electrolyte composition, Ni{sup 2+}/Fe{sup 2+} ratio, current density) on the electrodeposition process was investigated. Scanning electron microscopy (SEM) and X-ray fluorescence analysis (XRFA) were used to provide information about the obtained deposits’ thickness, morphology, and elemental composition. By controlling the experimental parameters, the composition of the Ni–Fe alloys can be tailored towards specific applications. Complementarily, the differences in the nucleation mechanisms for Ni, Fe and Ni–Fe deposition from sulfate solutions have been evaluated and discussed using cyclic voltammetry and potential step chronoamperometry. The obtained results suggest a progressive nucleation mechanism for Ni, while for Fe and Ni–Fe, the obtained data points are best fitted to an instantaneous nucleation model.

Robotin, B. [Babes-Bolyai University, Faculty of Chemistry and Chemical Engineering, 11 Arany Janos Street, RO-400028 Cluj-Napoca (Romania); Ispas, A. [Fachgebiet Elektrochemie und Galvanotechnik II, Technische Universität Ilmenau, D-98693 Ilmenau (Germany); Coman, V. [Babes-Bolyai University, Faculty of Chemistry and Chemical Engineering, 11 Arany Janos Street, RO-400028 Cluj-Napoca (Romania); Bund, A. [Fachgebiet Elektrochemie und Galvanotechnik II, Technische Universität Ilmenau, D-98693 Ilmenau (Germany); Ilea, P., E-mail: pilea@chem.ubbcluj.ro [Babes-Bolyai University, Faculty of Chemistry and Chemical Engineering, 11 Arany Janos Street, RO-400028 Cluj-Napoca (Romania)

2013-11-15T23:59:59.000Z

249

Adsorbate-Induced Segregation in a PdAg Membrane Model System...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

composition on adsorption and vice versa. Therefore, the interaction between hydrogen, carbon monoxide or oxygen with the surface of a PdAg model alloy was studied using periodic...

250

Comparative and Functional Genomics of Rhodococcus opacus PD630 for Biofuels Development  

E-Print Network [OSTI]

The Actinomycetales bacteria Rhodococcus opacus PD630 and Rhodococcus jostii RHA1 bioconvert a diverse range of organic substrates through lipid biosynthesis into large quantities of energy-rich triacylglycerols (TAGs). ...

Ghiviriga, Ion

251

Method and Pd/V2 O5 device for H2 detection  

DOE Patents [OSTI]

Methods and Pd/V.sub.2O.sub.5 devices for hydrogen detection are disclosed. An exemplary method of preparing an improved sensor for chemochromic detection of hydrogen gas over a wide response range exhibits stability during repeated coloring/bleaching cycles upon exposure and removal of hydrogen gas. The method may include providing a substrate. The method may also include depositing a V.sub.20.sub.5 layer that functions as a H.sub.2 insertion host in a Pd/V.sub.20.sub.5 hydrogen sensor to be formed on said substrate. The method may also include depositing a Pd layer onto said V.sub.20.sub.5 layer; said Pd layer functioning as an optical modulator.

Liu, Ping (San Diego, CA); Tracy, C. Edwin (Golden, CO); Pitts, J. Roland (Lakewood, CO); Smith, II, R. Davis (Golden, CO); Lee, Se-Hee (Lakewood, CO)

2011-12-27T23:59:59.000Z

252

Process design and modeling for the production of triacylglycerols (TAGs) in Rhodococcus opacus PD630  

E-Print Network [OSTI]

The oleaginous microorganism Rhodococcus opacus PD630 was used to study the characteristics and kinetics of the accumulation of triacylglycerols (TAGs) in cells. In this process, accumulation of TAG is stimulated when a ...

Miller, Neidi

2012-01-01T23:59:59.000Z

253

Structure Analysis of a Precipitate Phase in an Ni-Rich High...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Structure Analysis of a Precipitate Phase in an Ni-Rich High Temperature NiTiHf Shape Memory Alloy. Structure Analysis of a Precipitate Phase in an Ni-Rich High Temperature NiTiHf...

254

Carbon Nanotube Growth Using Ni Catalyst in Different Layouts  

E-Print Network [OSTI]

Vertically aligned carbon nanotubes have been grown using Ni as catalyst by plasma enhanced chemical vapor deposition system (PECVD) in various pre-patterned substrates. Ni was thermally evaporated on silicon substrates ...

Nguyen, H. Q.

255

Energy absorption in Ni-Mn-Ga/ polymer composites  

E-Print Network [OSTI]

In recent years Ni-Mn-Ga has attracted considerable attention as a new kind of actuator material. Off-stoichiometric single crystals of Ni2MnGa can regularly exhibit 6% strain in tetragonal martensites and orthorhombic ...

Feuchtwanger, Jorge

2006-01-01T23:59:59.000Z

256

ag fe ni: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

conduction-band states of NiO 100 thin films grown onto Ag 100 have charac- terized NiO monocrystalline thin films has shown up both onto insulating i.e., MgO, Ref. 21 Marcon,...

257

Oxygen-related dielectric relaxation and leakage characteristics of Pt,,Ba,Sr...TiO3 Pt thin-film capacitors  

E-Print Network [OSTI]

Oxygen-related dielectric relaxation and leakage characteristics of Pt�,,Ba,Sr...TiO3 �Pt thin to the postannealing temperature in oxygen and nitrogen atmosphere. High leakage currents and low-frequency dielectric and subsequently annealed in oxygen at 350 °C. Such results are related to the mobile oxygen ions and oxygen

Cao, Wenwu

258

Good and bad features of Ni-Cd cell designs  

SciTech Connect (OSTI)

Processes for spacecraft Ni-Cd cells are reviewed. Mechanical impregnation is compared against chemical and thermochemical impregnation.

Gross, S.

1996-02-01T23:59:59.000Z

259

Consistent Data Assimilation of Isotopes: 242Pu and 105Pd  

SciTech Connect (OSTI)

In this annual report we illustrate the methodology of the consistent data assimilation that allows to use the information coming from integral experiments for improving the basic nuclear parameters used in cross section evaluation. A series of integral experiments are analyzed using the EMPIRE evaluated files for 242Pu and 105Pd. In particular irradiation experiments (PROFIL-1 and -2, TRAPU-1, -2 and -3) provide information about capture cross sections, and a critical configuration, COSMO, where fission spectral indexes were measured, provides information about fission cross section. The observed discrepancies between calculated and experimental results are used in conjunction with the computed sensitivity coefficients and covariance matrix for nuclear parameters in a consistent data assimilation. The results obtained by the consistent data assimilation indicate that not so large modifications on some key identified nuclear parameters allow to obtain reasonable C/E. However, for some parameters such variations are outside the range of 1 s of their initial standard deviation. This can indicate a possible conflict between differential measurements (used to calculate the initial standard deviations) and the integral measurements used in the statistical data adjustment. Moreover, an inconsistency between the C/E of two sets of irradiation experiments (PROFIL and TRAPU) is observed for 242Pu. This is the end of this project funded by the Nuclear Physics Program of the DOE Office of Science. We can indicate that a proof of principle has been demonstrated for a few isotopes for this innovative methodology. However, we are still far from having explored all the possibilities and made this methodology to be considered proved and robust. In particular many issues are worth further investigation: • Non-linear effects • Flexibility of nuclear parameters in describing cross sections • Multi-isotope consistent assimilation • Consistency between differential and integral experiments

G. Palmiotti; H. Hiruta; M. Salvatores

2012-09-01T23:59:59.000Z

260

Novel Pt/Mg(In)(Al)O catalysts for ethane and propane dehydrogenation  

SciTech Connect (OSTI)

Catalysts for the dehydrogenation of light alkanes were prepared by dispersing Pt on the surface of a calcined hydrotalcite-like support containing indium, Mg(In)(Al)O. Upon reduction in H{sub 2} at temperatures above 673 K, bimetallic particles of PtIn are observed by TEM, which have an average diameter of 1 nm. Analysis of Pt LIII-edge extended X-ray absorption fine structure (EXAFS) data shows that the In content of the bimetallic particles increases with increasing bulk In/Pt ratio and reduction temperature. Pt LIII-edge X-ray absorption near edge structure (XANES) indicates that an increasing donation of electronic charge from In to Pt occurs with increasing In content in the PtIn particles. The activity and selectivity of the Pt/Mg(In)(Al)O catalysts for ethane and propane dehydrogenation reactions are strongly dependent on the bulk In/Pt ratio. For both reactants, maximum activity was achieved for a bulk In/Pt ratio of 0.48, and at this In/Pt ratio, the selectivity to alkene was nearly 100%. Coke deposition was observed after catalyst use for either ethane or propane dehydrogenation, and it was observed that the alloying of Pt with In greatly reduced the amount of coke deposited. Characterization of the deposit by Raman spectroscopy indicates that the coke is present as highly disordered graphite particles <30 nm in diameter. While the amount of coke deposited during ethane and propane dehydrogenation are comparable, the effects on activity are dependent on reactant composition. Coke deposition had no effect on ethane dehydrogenation activity, but caused a loss in propane dehydrogenation activity. This difference is attributed to the greater ease with which coke produced on the surface of PtIn nanoparticles migrates to the support during ethane dehydrogenation versus propane dehydrogenation.

Sun, Pingping; Siddiqi, Georges; Vining, William C.; Chi, Miaofang; Bell, Alexis T. (UCB); (ORNL)

2011-10-28T23:59:59.000Z

Note: This page contains sample records for the topic "ni pd pt" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

High Temperature coatings based on {beta}-NiAI  

SciTech Connect (OSTI)

High temperature alloys are reviewed, focusing on current superalloys and their coatings. The synthesis, characerization, and oxidation performance of a NiAl–TiB{sub 2} composite are explained. A novel coating process for Mo–Ni–Al alloys for improved oxidation performance is examined. The cyclic oxidation performance of coated and uncoated Mo–Ni–Al alloys is discussed.

Severs, Kevin

2012-07-10T23:59:59.000Z

262

CoNiGa High Temperature Shape Memory Alloys  

E-Print Network [OSTI]

commercially successful SMAs such as NiTi and Cu-based alloys. In recent years, the CoNiGa system has emerged as a new ferromagnetic shape memory alloy with some compositions exhibiting high martensitic transformation temperatures which makes CoNiGa a potential...

Dogan, Ebubekir

2011-10-21T23:59:59.000Z

263

Grain boundary compositon in NiAl  

SciTech Connect (OSTI)

The high temperature strength and oxidation resistance of many transition metal aluminides makes these intermetallic materials attractive for high temperature applications. However, these aluminides are generally brittle at low temperatures and this restricts their technological applications. However, these aluminides are generally brittle at low temperatures and this restricts their technological applications. It has been demonstrated that the addition of more than 200 ppm of boron to the L1{sub 2}-ordered Ni{sub 3}Al changes the fracture behavior from intergranular to transgranular and increases the ductility. The B2-ordered NiAl nickel aluminide is particularly attractive because of its low density and high melting temperature. This aluminide also fractures intergranularly at room temperature. However, no improvement in ductility is observed with similar boron additions even though the intergranular fracture is suppressed and there is a significant increase in the yield strength. In this paper, the results of an atom probe field ion microscopy investigation of the compositions of the grain boundaries in undoped and boron-doped NiAl are presented. The suitability of the atom probe field ion microscopy technique for the characterization of boundaries has clearly been demonstrated in many previous investigations including the characterization of boron segregation to grain boundaries and other planar features in Ni{sub 3}Al.

Miller, M.K.; Jayaram, R.; Camus, P.P. (Metals and Ceramics Div., Oak Ridge National Lab., Oak Ridge, TN (US))

1992-02-15T23:59:59.000Z

264

Electronic structure mechanism of spin-polarized electron transport in a NiC60Ni system  

E-Print Network [OSTI]

Laboratory, Weapons and Materials Research Directorate, ATTN: AMSRD-ARL-WM, Aberdeen Proving Ground, MD 21005 Abstract The nature of chemical bonding and its effect on spin-polarized electron transport in Ni­C60­Ni couple with metallic electrodes (e. g. Ni and Au), a key requirement for the Kondo effect

Pandey, Ravi

265

An An exactly solvable PT symmetric potential from the Natanzon class  

E-Print Network [OSTI]

The ${\\cal PT}$ symmetric version of the generalised Ginocchio potential, a member of the general exactly solvable Natanzon potential class is analysed and its properties are compared with those of ${\\cal PT}$ symmetric potentials from the more restricted shape-invariant class. It is found that the ${\\cal PT}$ symmetric generalised Ginocchio potential has a number of properties in common with the latter potentials: it can be generated by an imaginary coordinate shift $x\\to x+{\\rm i}\\epsilon$; its states are characterised by the quasi-parity quantum number; the spontaneous breakdown of ${\\cal PT}$ symmetry occurs at the same time for all the energy levels; and it has two supersymmetric partners which cease to be ${\\cal PT}$ symmetric when the ${\\cal PT}$ symmetry of the original potential is spontaneously broken.

G. Levai; A. Sinha; P. Roy

2003-06-05T23:59:59.000Z

266

Properties of electroless Ni-W-P amorphous alloys  

SciTech Connect (OSTI)

This paper describes work performed to determine some of the properties of the electroless Ni-W-P amorphous deposits. Phosphorus contents were varied up to 32 at.%, and the amorphous structure was found to be present at phosphorus contents above 5 at.%. Irrespective of P content, all the deposits exhibits excellent adhesion to metallic substrates. The addition of even small amounts of W provided greatly increased hardness compared with the plain Ni-P deposits. The wettability properties of the Ni-W-P deposits were found to be comparable to those of Ni-P and N-B-P deposits but inferior to those of Ni-B deposits.

Zhang Bangwei [Academia Sinica, Shenyang (China). International Centre of Materials Physics] [Academia Sinica, Shenyang (China). International Centre of Materials Physics; [Hunan Univ., Changsha (China). Dept. of Applied Physics; Hu Wangyu; Zhang Qinglong; Qu Xuanyuan [Hunan Univ., Changsha (China). Dept. of Applied Physics] [Hunan Univ., Changsha (China). Dept. of Applied Physics

1996-08-01T23:59:59.000Z

267

Microstructure of electrodeposited Cu-Ni binary alloy films  

SciTech Connect (OSTI)

The codeposition of Cu and Ni in the electrodeposition method without a complexing agent is difficult, since the standard electrode potentials of Cu and Ni differ by approximately 600 mV. In this study, the electrodeposited Cu-Ni alloy films with various compositions were obtained using glycine as the complexing agent. Consequently, composition of the deposited Cu-Ni alloy films can be controlled by bath composition and pH, and the crystallographic structure of all the deposited Cu-Ni alloy films consists of a single solid solution and is not influenced by pH.

Mizushima, Io; Chikazawa, Masatoshi; Watanabe, Tohru [Tokyo Metropolitan Univ. (Japan). Dept. of Industrial Chemistry

1996-06-01T23:59:59.000Z

268

In Situ XAS of Ni-W Hydrocracking Catalysts  

SciTech Connect (OSTI)

Ni-W based catalysts are very attractive in hydrotreating of heavy oil due to their high hydrogenation activity. In the present research, two catalyst samples, prepared by different methods, that exhibit significant differences in activity were sulfided in situ, and the local structure of the Ni and W were studied using X-ray absorption spectroscopy (XAS). The Ni XANES spectra were analyzed using a linear component fitting, and the EXAFS spectra of the WS2 platelets in the sulfided catalysts were modeled. The Ni and W are fully sulfided in the higher activity sample, and there are both unsulfided Ni ({approx}25%) and W (<10%) in the lower activity sample.

Yang, N. [Argonne National Laboratory, Argonne, IL 60439 (United States); Mickelson, G. E.; Greenlay, N.; Bare, Simon R. [UOP LLC, Des Plaines, IL 60016 (United States); Kelly, S. D. [EXAFS Analysis, Bolingbrook, IL 60440 (United States)

2007-02-02T23:59:59.000Z

269

Pd menbrane having improved H.sub.2-permeance, and method of making  

DOE Patents [OSTI]

An H.sub.2-permeable membrane system (117) comprises an electroless-deposited plating (115) of Pd or Pd alloy on a porous support (110, 110'). The Pd plating comprises face-centered cubic crystals cumulatively having a morphology of hexagonal platelets. The permeability to H.sub.2 of the membrane plating (115) on the porous support is significantly enhanced, being at least greater than about 1.3.times.10.sup.-8 molm.sup.-1s.sup.-Pa.sup.-0.5 at 350.degree. C., and even greater than about 3.4.times.10.sup.-8 molm.sup.-1s.sup.-1Pa.sup.-0.5. The porous support (110, 110') may be stainless steel (1100 and include a thin ceramic interlayer (110') on which the Pd is plated. The method of providing the electroless-deposited plating includes preheating a Pd electroless plating solution to near a plating temperature substantially greater than room temperature, e.g. 60.degree. C., prior to plating.

Vanderspurt, Thomas Henry (Glastonbury, CT); She, Ying (Worcester, MA); Dardas, Zissis (Worcester, MA); Walker, Craig (South Glastonbury, CT); MacLeod, James D. (Vernon, CT)

2011-12-06T23:59:59.000Z

270

In situ NiTi/Nb(Ti) composite  

SciTech Connect (OSTI)

Graphical abstract: - Highlights: • In situ NiTi/Nb(Ti) composites were fabricated. • The transformation temperature was affected by the mixing Ti:Ni atomic ratios. • The NiTi component became micron-scale lamella after forging and rolling. • The composite exhibited high strength and high damping capacity. - Abstract: This paper reports on the creation of a series of in situ NiTi/Nb(Ti) composites with controllable transformation temperatures based on the pseudo-binary hypereutectic transformation of NiTi–Nb system. The composite constituent morphology was controlled by forging and rolling. It is found that the thickness of the NiTi lamella in the composite reached micron level after the hot-forging and cold-rolling. The NiTi/Nb(Ti) composite exhibited high damping capacity as well as high yield strength.

Jiang, Daqiang, E-mail: dq80jiang@126.com; Cui, Lishan; Jiang, Jiang; Zheng, Yanjun

2013-12-15T23:59:59.000Z

271

E-Print Network 3.0 - acute abdomen pt Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

PHYSICIAN'S PERSONAL COPY TO: STREET CITY ZIP Summary: % BILIRUBIN mg% RBC HOSPITAL TUBE STATION 31 Platelet Count: INR: PT: PTT: 12;GASTRO INTESTINAL ANGIOGRAPHIC... CONTRAST)...

272

Degradation phenomena and design principles for stable and active Pt/C fuel cell catalysts.  

E-Print Network [OSTI]

??Stabile und aktive Elektrodenmaterialien sind entscheidend für moderne elektrochemische Energiewandler wie Brennstoffzellen. Diese Arbeit untersucht die Aktivität und insbesondere Stabilität von Pt/ C Brennstoffzellenkatalysatoren. In… (more)

Meier, Josef Christian

2013-01-01T23:59:59.000Z

273

Isospectral partners for a complex PT-invariant potential  

E-Print Network [OSTI]

We construct isospectral partner potentials of a complex PT-invariant potential, viz., V(x) = V_1 sech ^2 x - i V_2 sech x tanh x using Darboux's method. Oneset of isospectral potentials are obatined which can be termed 'Satellite potentials', in the sense that they are pf the same form as the original potential. In a particular case, the supersymmetric partner potential has the same spectrum, including the zero energy ground state, a fact which cannot occur in conventional supersymmetric quantum mechanics with real potential. An explicit example of a non-trivial set of isospectral potential is also obtained.

Anjana Sinha; Rajkumar Roychoudhury

2002-05-20T23:59:59.000Z

274

AcqGuide3pt1.doc | Department of Energy  

Office of Environmental Management (EM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "of EnergyEnergy Cooperation |South ValleyASGovLtr.pdfAbout thept1.doc&#0; AcqGuide3pt1.doc&#0;

275

Acqguide18pt0 March 2011 final | Department of Energy  

Office of Environmental Management (EM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "of EnergyEnergy Cooperation |South ValleyASGovLtr.pdfAbout thept1.doc&#0;4170.32702Acqguide18pt0 March

276

AcqGuide38pt1.doc | Department of Energy  

Energy Savers [EERE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion |Energyon ArmedWaste andAccess to OUO Access to OUO DOE M 471.3-1, AcqGuide38pt1.doc&#0;

277

Stripe-to-bubble transition of magnetic domains at the spin reorientation of (Fe/Ni)/Cu/Ni/Cu(001)  

SciTech Connect (OSTI)

Magnetic domain evolution at the spin reorientation transition (SRT) of (Fe/Ni)/Cu/Ni/Cu(001) is investigated using photoemission electron microscopy. While the (Fe/Ni) layer exhibits the SRT, the interlayer coupling of the perpendicularly magnetized Ni layer to the (Fe/Ni) layer serves as a virtual perpendicular magnetic field exerted on the (Fe/Ni) layer. We find that the perpendicular virtual magnetic field breaks the up-down symmetry of the (Fe/Ni) stripe domains to induce a net magnetization in the normal direction of the film. Moreover, as the virtual magnetic field increases to exceed a critical field, the stripe domain phase evolves into a bubble domain phase. Although the critical field depends on the Fe film thickness, we show that the area fraction of the minority domain exhibits a universal value that determines the stripe-to-bubble phase transition.

Wu, J.; Choi, J.; Won, C.; Wu, Y. Z.; Scholl, A.; Doran, A.; Hwang, Chanyong; Qiu, Z.

2010-06-09T23:59:59.000Z

278

Electron yield XAFS study of evaporated Co/Pd multilayers with various thickness ratios of Co to Pd sublayers: Simulations of the Co K-edge XAFS and fourier transforms  

SciTech Connect (OSTI)

Electron-yield XAFS measurements using the NSLS were made on e-beam evaporated Co/Pd multilayers with various sublayer thicknesses and different thickness ratios of Co to Pd sublayers. The Co K-edge and the Pd K-edge XAFS data were obtained for the Co/Pd multilayers with sublayer thicknesses of 3{Angstrom}/ 4{Angstrom}, 15{Angstrom}/4{Angstrom}, 3{Angstrom}/15{Angstrom}, 2.1{Angstrom}/13.5{Angstrom}, and 2.2{Angstrom}/4.5{Angstrom}. Fourier transforms of Co K XAFS for most samples show a splitting of major peak, and the magnitude ratio of these split peaks varies systematically with the thickness ratio of the Pd sublayer to the Co sublayer, whereas the Fourier transforms of the Pd K XAFS for the same samples do not show a splitting of peaks. As a preliminary analysis, the Co K XAFS and the split peaks in the Fourier transform for the Co/Pd(3{Angstrom}/4{Angstrom}) case were simulated by using the FEFF calculations, and the Co K XAFS and the major peak in the fourier transform for the Co/Pd(15{Angstrom}/4{Angstrom}) case were also simulated consistently.

Choi, M. [Catholic Univ. Medical Coll., Seoul (Korea, Republic of). Dept. of Physics; Joo, J.H. [Korea Inst. of Science and Technology, Seoul (Korea, Republic of). Materials Design Lab.; Kim, S.K.; Kang, J.S.; Lee, Y.P. [Research Inst. of Industrial Science Technology, Pohang (Korea, Republic of); Shin, S.C. [Korea Advanced Inst. of Science and Technology, Seoul (Korea, Republic of); Heald, S.M. [Brookhaven National Lab., Upton, NY (United States)

1992-11-01T23:59:59.000Z

279

Electron yield XAFS study of evaporated Co/Pd multilayers with various thickness ratios of Co to Pd sublayers: Simulations of the Co K-edge XAFS and fourier transforms  

SciTech Connect (OSTI)

Electron-yield XAFS measurements using the NSLS were made on e-beam evaporated Co/Pd multilayers with various sublayer thicknesses and different thickness ratios of Co to Pd sublayers. The Co K-edge and the Pd K-edge XAFS data were obtained for the Co/Pd multilayers with sublayer thicknesses of 3[Angstrom]/ 4[Angstrom], 15[Angstrom]/4[Angstrom], 3[Angstrom]/15[Angstrom], 2.1[Angstrom]/13.5[Angstrom], and 2.2[Angstrom]/4.5[Angstrom]. Fourier transforms of Co K XAFS for most samples show a splitting of major peak, and the magnitude ratio of these split peaks varies systematically with the thickness ratio of the Pd sublayer to the Co sublayer, whereas the Fourier transforms of the Pd K XAFS for the same samples do not show a splitting of peaks. As a preliminary analysis, the Co K XAFS and the split peaks in the Fourier transform for the Co/Pd(3[Angstrom]/4[Angstrom]) case were simulated by using the FEFF calculations, and the Co K XAFS and the major peak in the fourier transform for the Co/Pd(15[Angstrom]/4[Angstrom]) case were also simulated consistently.

Choi, M. (Catholic Univ. Medical Coll., Seoul (Korea, Republic of). Dept. of Physics); Joo, J.H. (Korea Inst. of Science and Technology, Seoul (Korea, Republic of). Materials Design Lab.); Kim, S.K.; Kang, J.S.; Lee, Y.P. (Research Inst. of Industrial Science Technology, Pohang (Korea, Republic of)); Shin, S.C. (Korea Advanced Inst. of Science and Technology, Seoul (Korea, Republic of)); Heald, S.M.

1992-01-01T23:59:59.000Z

280

Surface morphology of atomic nitrogen on Pt(111)  

SciTech Connect (OSTI)

The surface morphology of chemisorbed N on the Pt(111) surface has been studied at the atomic level with low temperature scanning tunneling microscopy (STM). When N is coadsorbed with O on the surface, they form a mixed (2 × 2)-N+O structure. When the surface is covered with N atoms only, isolated atoms and incomplete (2 × 2) patches are observed at low coverages. In a dense N layer, two phases, (?3 × ?3)R30°-N and p(2 × 2)-N, are found to coexist at temperatures between 360 and 400 K. The (?3 × ?3)R30° phase converts to the (2 × 2) phase as temperature increases. For both phases, nitrogen occupies fcc-hollow sites. At temperatures above 420 K, nitrogen starts to desorb. The p(2 × 2)-N phase shows a honeycomb structure in STM images with three nitrogen and three platinum atoms forming a six-membered ring, which can be attributed to the strong nitrogen binding to the underlying Pt surface.

Liang, Zhu; Trenary, Michael, E-mail: mtrenary@uic.edu [Department of Chemistry, University of Illinois at Chicago, 845 West Taylor Street, Chicago, Illinois 60607 (United States)] [Department of Chemistry, University of Illinois at Chicago, 845 West Taylor Street, Chicago, Illinois 60607 (United States); Jin Yang, Hyun [Surface and Interface Science Laboratory, RIKEN, 2-1 Hirosawa, Wako-shi, Saitama 351-0198 (Japan) [Surface and Interface Science Laboratory, RIKEN, 2-1 Hirosawa, Wako-shi, Saitama 351-0198 (Japan); Department of Advanced Materials Science, The University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8561 (Japan); Kim, Yousoo, E-mail: ykim@riken.jp [Surface and Interface Science Laboratory, RIKEN, 2-1 Hirosawa, Wako-shi, Saitama 351-0198 (Japan)] [Surface and Interface Science Laboratory, RIKEN, 2-1 Hirosawa, Wako-shi, Saitama 351-0198 (Japan)

2014-03-21T23:59:59.000Z

Note: This page contains sample records for the topic "ni pd pt" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

New Designs of Rigid Pincer Complexes with PXP Ligands and Late Transition Metals and sp3 C-F Bond Activation with Silylium and Alumenium Species  

E-Print Network [OSTI]

. In Chapter V, a series of (TPB)M complexes (M = Ni, Pd, Pt) were synthesized and characterized by multinuclear NMR spectroscopy and X-ray crystallography. The resulting metal complexes displayed strong dative M?B interaction and unusual tetrahedral geometry...

Gu, Weixing

2012-02-14T23:59:59.000Z

282

Electrochemical CO2 and CO Reduction on Metal-Functionalized Porphyrin-like Graphene  

E-Print Network [OSTI]

for producing methanol from CO, featuring an overpotential of 0.22 V. Additionally, we have also examined of the metals was able to produce methanol. The origin of the overpotential remained elusive until recently or methanol. The late transition metals (Cu, Ag, Au, Ni, Pd, Pt, Co, Rh, Ir, Fe, Ru, Os) and some p (B, Al, Ga

Thygesen, Kristian

283

2012NatureAmerica,Inc.Allrightsreserved. 52 | VOL.8 NO.1 | 2013 | nature protocols  

E-Print Network [OSTI]

DuctIon Background SERS was first observed in the 1970s on an electrochemically roughened Ag electrode1­3, which be substantially increased to obtain total enhancement factors of up to 104­105 for Pt, Pd, Ru, Rh, Ni and Co (refs

Wang, Zhong L.

284

This article appeared in a journal published by Elsevier. The attached copy is furnished to the author for internal non-commercial research  

E-Print Network [OSTI]

modified electrode such as Pt [7­9], Au [10,11], Ag [12], Cu [13,14], Ni [15,16], Pd [17], alloy [18NTs electrode. The good analytical performance, low cost and simple preparation method make this novel electrode material promising for the development of effective glucose nonenzymatic glucose sensor. © 2012

Cao, Guozhong

285

PHYSICAL REVIEW B 89, 064307 (2014) Indirect heating of Pt by short-pulse laser irradiation of Au in a nanoscale Pt/Au bilayer  

E-Print Network [OSTI]

-probe measurements and modeling using a transmission-line-equivalent circuit. For optical exciation of either the Pt excitations, which are then driven out of thermal equilibrium with the vibrations of the atomic lattice [1

Cahill, David G.

286

PHYSICAL REVIEW B 85, 205443 (2012) Growth structure and work function of bilayer graphene on Pd(111)  

E-Print Network [OSTI]

PHYSICAL REVIEW B 85, 205443 (2012) Growth structure and work function of bilayer graphene on Pd of bilayer graphene on Pd(111). Low-energy electron diffraction analysis established that the two graphene layer. We propose that the faceted shapes are due to the zigzag-terminated edges bounding graphene

Ciobanu, Cristian

287

Au/Pd coreshell nanoparticles for enhanced electrocatalytic activity and durability Chiajen Hsu, Chienwen Huang, Yaowu Hao , Fuqiang Liu  

E-Print Network [OSTI]

­shell nanoparticles were synthesized via galvanic replacement of Cu by Pd on hollow Au nano-spheres. The catalysts and durability on FAO. In the core­shell structure, the thickness of the Pd shell, coated on the hollow Au nanoparticles [22], is varied as the determining factor to tailor the electronic coupling. The hollow Au core

Liu, Fuqiang

288

Investigation of microstructure, surface morphology, and hardness properties of PtIr films by magnetron sputtering  

SciTech Connect (OSTI)

Pt{sub 1-x}Ir{sub x} films with x varying from 22.76 to 63.25 at. % are deposited on (100) Si wafer substrates at 400 deg. C by magnetron sputtering deposition. The effects of the Ir concentration on the microstructure, morphology, and hardness of PtIr films are investigated by field emission scanning electron microscopy, x-ray diffraction, atomic force microscopy, and nanoindentation system. The columnar structures are observed by field emission scanning electron microscopy. X-ray diffraction analysis reveals that PtIr films have preferred orientation along Pt(111) when the Ir concentration is below 50.84 at. %. When the Ir content is more than 50.84 at. %, the PtIr film shifts to another preferred orientation, Ir(111). The surface morphology is analyzed by atomic force microscopy. The roughness of the PtIr films decreases with increasing Ir content. The hardness of all the PtIr films is below 20 GPa. The maximum hardness of the PtIr films is about 14.9 GPa when the Ir concentration is 57.9 at. %.

Lee, Chao-Te; Liu, Bo-Heng; Chang, Chun-Ming; Lin, Yu-Wei [Instrument Technology Research Center, National Applied Research Laboratories, Hsinchu 300, Taiwan (China)

2010-09-15T23:59:59.000Z

289

A organizao interna do PT no Governo Lula: os vnculos com a sociedade  

E-Print Network [OSTI]

A organização interna do PT no Governo Lula: os vínculos com a sociedade Oswaldo E. do Amaral. halshs-00496150,version1-29Jun2010 #12;2 A organização interna do PT no Governo Lula: os vínculos com década de 90 e ao assumir o comando do Governo Federal pela primeira vez em 2003. O artigo mostra, por

Paris-Sud XI, Université de

290

Carbon supported PtRh catalysts for ethanol oxidation in alkaline direct ethanol fuel cell  

E-Print Network [OSTI]

Carbon supported PtRh catalysts for ethanol oxidation in alkaline direct ethanol fuel cell S 2010 Keywords: Fuel cell Ethanol oxidation reaction (EOR) Alkaline direct ethanol fuel cell Pt reserved. 1. Introduction In terms of fuel, a direct ethanol fuel cell (DEFC) is more attractive than

Zhao, Tianshou

291

CO2 sticking on Pt(111); the role of kinetic energy and internal degrees of freedom  

E-Print Network [OSTI]

CO2 sticking on Pt(111); the role of kinetic energy and internal, S-412 96, G"oteborg, Sweden Abstract CO2 adsorbed measurements of non-dissociative sticking coefficient, S0, of CO2 on the Pt(111) surfac* *e

Persson, Mats

292

Novel Pt/Mg(In)(Al)O catalysts for ethane and propane dehydrogenation Pingping Sun a  

E-Print Network [OSTI]

Novel Pt/Mg(In)(Al)O catalysts for ethane and propane dehydrogenation Pingping Sun a , Georges and propane dehydrogenation reactions are strongly dependent on the bulk In/Pt ratio. For both reactants to alkene was nearly 100%. Coke deposition was observed after catalyst use for either ethane or propane

Iglesia, Enrique

293

NiW and NiRu Bimetallic Catalysts for Ethylene Steam Reforming: Alternative Mechanisms for Sulfur Resistance  

SciTech Connect (OSTI)

Previous investigations of Ni-based catalysts for the steam reforming of hydrocarbons have indicated that the addition of a second metal can reduce the effects of sulfur poisoning. Two systems that have previously shown promise for such applications, NiW and NiRu, are considered here for the steam reforming of ethylene, a key component of biomass derived tars. Monometallic and bimetallic Al{sub 2}O{sub 3}-supported Ni and W catalysts were employed for ethylene steam reforming in the presence and absence of sulfur. The NiW catalysts were less active than Ni in the absence of sulfur, but were more active in the presence of 50 ppm H{sub 2}S. The mechanism for the W-induced improvements in sulfur resistance appears to be different from that for Ru in NiRu. To probe reasons for the sulfur resistance of NiRu, the adsorption of S and C{sub 2}H{sub 4} on several bimetallic NiRu alloy surfaces ranging from 11 to 33 % Ru was studied using density functional theory (DFT). The DFT studies reveal that sulfur adsorption is generally favored on hollow sites containing Ru. Ethylene preferentially adsorbs atop the Ru atom in all the NiRu (111) alloys investigated. By comparing trends across the various bimetallic models considered, sulfur adsorption was observed to be correlated with the density of occupied states near the Fermi level while C{sub 2}H{sub 4} adsorption was correlated with the number of unoccupied states in the d-band. The diverging mechanisms for S and C{sub 2}H{sub 4} adsorption allow for bimetallic surfaces such as NiRu that enhance ethylene binding without accompanying increases in sulfur binding energy. In contrast, bimetallics such as NiSn and NiW appear to decrease the affinity of the surface for both the reagent and the poison.

Rangan, M.; Yung, M. M.; Medlin, J. W.

2012-06-01T23:59:59.000Z

294

First principles investigation of the initial stage of H-induced missing-row reconstruction of Pd(110) surface  

SciTech Connect (OSTI)

The pathway of H diffusion that will induce the migration of Pd atom is investigated by employing first principles calculations based on density functional theory to explain the origin of missing-row reconstruction of Pd(110).The calculated activation barrier and the H-induced reconstruction energy reveal that the long bridge-to-tetrahedral configuration is the energetically favored process for the initial stage of reconstruction phenomenon. While the H diffusion triggers the migration of Pd atom, it is the latter process that significantly contributes to the activated missing-row reconstruction of Pd(110). Nonetheless, the strong interaction between the diffusing H and the Pd atoms dictates the occurrence of reconstructed surface.

Padama, Allan Abraham B. [Department of Applied Physics, Osaka University, Suita, Osaka 565-0871 (Japan); Kasai, Hideaki, E-mail: kasai@dyn.ap.eng.osaka-u.ac.jp [Department of Applied Physics, Osaka University, Suita, Osaka 565-0871 (Japan); Center for Atomic and Molecular Technologies, Osaka University, Suita, Osaka 565-0871 (Japan)

2014-06-28T23:59:59.000Z

295

The spin Hall angle and spin diffusion length of Pd measured by spin pumping and microwave photoresistance  

SciTech Connect (OSTI)

We present the experimental study of the spin Hall angle (SHA) and spin diffusion length of Pd with the spin pumping and microwave photoresistance effects. The Py/Pd bilayer stripes are excited with an out-of-plane microwave magnetic field. The pure spin current is thus pumped and transforms into charge current via the inverse spin Hall effect (ISHE) in Pd layer, yielding an ISHE voltage. The ISHE voltage can be distinguished from the unwanted signal caused by the anisotropic magnetoresistance according to their different symmetries. Together with Pd thickness dependent measurements of in and out-of-plane precessing angles and effective spin mixing conductance, the SHA and spin-diffusion length of Pd are quantified as 0.0056?±?0.0007 and 7.3?±?0.7?nm, respectively.

Tao, X. D.; Feng, Z.; Miao, B. F.; Sun, L.; You, B.; Wu, D.; Du, J.; Zhang, W.; Ding, H. F., E-mail: hfding@nju.edu.cn [Department of Physics, National Laboratory of Solid State Microstructures, Nanjing University, 22 Hankou Road, Nanjing 210093 (China)

2014-05-07T23:59:59.000Z

296

Electrodeposition of ultrathin Pd, Co and Bi films on well-defined noble-metal electrodes: studies by ultrahigh vacuum-electrochemistry (UHV-EC)  

E-Print Network [OSTI]

admetal on a noble-metal surface; and (iii) Co on polycrystalline Pd and Pd(111), a reactive metal on a noble-metal surface. The interfacial electrochemistry of these prototypical systems was characterized using a combination of electrochemical methods...

Baricuatro, Jack Hess L

2006-10-30T23:59:59.000Z

297

Determination of the Pt spin diffusion length by spin-pumping and spin Hall effect  

SciTech Connect (OSTI)

The spin diffusion length of Pt at room temperature and at 8 K is experimentally determined via spin pumping and spin Hall effect in permalloy/Pt bilayers. Voltages generated during excitation of ferromagnetic resonance from the inverse spin Hall effect and anisotropic magnetoresistance effect were investigated with a broadband approach. Varying the Pt layer thickness gives rise to an evolution of the voltage line shape due to the superposition of the above two effects. By studying the ratio of the two voltage components with the Pt layer thickness, the spin diffusion length of Pt can be directly extracted. We obtain a spin diffusion length of ?1.2 nm at room temperature and ?1.6 nm at 8 K.

Zhang, Wei; Pearson, John E.; Hoffmann, Axel [Materials Science Division, Argonne National Laboratory, Argonne, Illinois 60439 (United States)] [Materials Science Division, Argonne National Laboratory, Argonne, Illinois 60439 (United States); Vlaminck, Vincent [Materials Science Division, Argonne National Laboratory, Argonne, Illinois 60439 (United States) [Materials Science Division, Argonne National Laboratory, Argonne, Illinois 60439 (United States); Colegio de Ciencias e Ingenería, Universidad San Fransciso de Quito, Quito (Ecuador); Divan, Ralu [Center for Nanoscale Materials, Argonne National Laboratory, Illinois 60439 (United States)] [Center for Nanoscale Materials, Argonne National Laboratory, Illinois 60439 (United States); Bader, Samuel D. [Materials Science Division, Argonne National Laboratory, Argonne, Illinois 60439 (United States) [Materials Science Division, Argonne National Laboratory, Argonne, Illinois 60439 (United States); Center for Nanoscale Materials, Argonne National Laboratory, Illinois 60439 (United States)

2013-12-09T23:59:59.000Z

298

$J/?$ suppression in Pb+Pb collisions and $p_T$ broadening  

E-Print Network [OSTI]

We have analysed the NA50 data, on the centrality dependence of $p_T$ broadening of $J/\\psi$'s, in Pb+Pb collisions, at the CERN-SPS. The data were analysed in a QCD based model, where $J/\\psi$'s are suppressed in 'nuclear' medium. Without any free parameter, the model could explain the NA50 $p_T$ broadening data. The data were also analysed in a QGP based threshold model, where $J/\\psi$ suppression is 100% above a critical density. The QGP based model could not explain the NA50 $p_T$ broadening data. We have also predicted the centrality dependence of $J/\\psi$ suppression and $p_T$ broadening at RHIC energy. Both the models, the QGP based threshold model and the QCD based nuclear absorption model, predict $p_T$ broadening very close to each other.

A. K. Chaudhuri

2003-04-10T23:59:59.000Z

299

FePt-based exchange-coupled composite perpendicular recording media.  

SciTech Connect (OSTI)

In order to demonstrate the strong and proper exchange coupling between bottom magnetic layer and capping magnetic layer in FePt-based exchange-coupled composite (ECC) perpendicular recording media, we have investigated the thermal stability, writability, degree of exchange coupling, and ECC gain factor of FePt-based ECC media as a function of the thickness of the capping FePt layer. With increasing the thickness of capping FePt layer, both thermal stability and media writability increase simultaneously as a result of the change from strong exchange coupling to proper exchange coupling. The proper exchange-coupled FePt ECC is a promising candidate for future high-density perpendicular recording.

Sun, C.; Stafford, D.; Acharya, R.; X-Ray Science Division; Western Digital Media

2010-06-01T23:59:59.000Z

300

Physical and biological properties of a Pt(ll) complex of a beta-diketiminate ligand with pendant quinoline arms  

E-Print Network [OSTI]

A monoanionic, tetradentate [beta]-diketiminate (BDI) ligand with pendant quinoline arms, BDIQQH was coordinated to Pt(II) to yield the square-planar complex [Pt(BDIQQ)]CI. This complex was characterized by NMR spectroscopy, ...

Hope, Jennifer M

2012-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "ni pd pt" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Catalytic decomposition of Ba(NO3)2 on Pt(111)  

SciTech Connect (OSTI)

The decomposition of Ba(NO3)2 formed on BaO/Pt(111) (Pt(111) surface is partially covered by BaO) in the presence of CO was studied using temperature programmed desorption (TPD), infrared reflection absorption (IRA) and X-ray photoelectron (XP) spectroscopies. The exposure of BaO/Pt(111) to elevated NO2 pressure (1.0×10-4 Torr) at 450 K leads to the formation of Ba(NO3)2, chemisorbed O (OPt) and Pt-oxide-like domains. During TPD, the Ba(NO3)2 begins to thermally decompose near 490 K, releasing NO and NO2 with the maximum NOx desorption rate seen at 605 K. The OPt species formed following the exposure of BaO/Pt(111) to NO2 react with CO to release CO2 at 450 K. The consumption of OPt during CO oxidation initiates the migration of O from the Pt-oxide-like domains to the chemisorbed phase, where the CO oxidation reaction occurs. Therefore, the removal of OPt by CO leads to the reduction of oxidized Pt, and to the formation of metallic Pt(111) domains, where, subsequently, catalytic decomposition of Ba(NO3)2 can take place. The Pt-catalyzed decomposition of Ba(NO3)2 occurs readily at 450 K, a temperature much lower than the onset of the decomposition temperature of Ba(NO3)2 in the presence of oxidized Pt. This work was supported by the US Department of Energy Basic Energy Sciences' Chemical Sciences, Geosciences & Biosciences Division. Pacific Northwest National Laboratory is operated by Battelle for the US Department of Energy.

Mudiyanselage, Kumudu; Weaver, Jason F.; Szanyi, Janos

2011-04-07T23:59:59.000Z

302

Tables for Trials and Failures with PD for Designated Confidence Level  

SciTech Connect (OSTI)

Two attachments are provided for performance testing of sensors and other Physical Protection System (PPS) components.#2; The first attachment is a table of Trials and Failures, giving Probability of Detection (PD) for a designated confidence level and sorted by trials.#2; The second attachment contains the same data, sorted by failures.

Leach, Janice

2014-02-01T23:59:59.000Z

303

Highly ecient kinetic resolution of 2-cyclohexenyl acetate in Pd-catalyzed allylic alkylation  

E-Print Network [OSTI]

Highly ecient kinetic resolution of 2-cyclohexenyl acetate in Pd-catalyzed allylic alkylation James resolution of 2-cyclohexenyl acetate was observed during alkylation. In addition, the reactivity and enantioselectivity showed a strong dependence on the acetate salt with the BSA/MOAc (M=alkali metal) base system

Zhang, Xumu

304

Benchmark Problem: A PK/PD Model and Safety Constraints for Anesthesia Delivery  

E-Print Network [OSTI]

Benchmark Problem: A PK/PD Model and Safety Constraints for Anesthesia Delivery Victor Gan, Guy A of the goals of general anesthesia. In this brief paper we provide a differential equation model of how Introduction General anesthesia is a broad term encompassing the use of drugs to induce and maintain three

Mitchell, Ian

305

Micro Catalytic Combustor with Pd/Nano-porous Alumina for High-Temperature Application  

E-Print Network [OSTI]

Micro Catalytic Combustor with Pd/Nano-porous Alumina for High-Temperature Application Takashi: A micro-scale catalytic combustor using high-precision ceramic tape-casting technology has been developed surface reaction of butane. In combustion experiments with a prototype combustor, the wall temperature

Kasagi, Nobuhide

306

Form P&D initial interview | Faculty of Science |version January 2009 Page 1 of 3  

E-Print Network [OSTI]

­ Password: leiden7 Applicable performance areas from the UFO profile Part B - Agreements the UFO profile, designated tasks, competencies and the personal development of the employee. For instance performance areas from the UFO profile. #12;Form P&D initial interview | Faculty of Science |version January

Hille, Sander

307

Fusion of radioactive $^{132}$Sn with $^{64}$Ni  

E-Print Network [OSTI]

Evaporation residue and fission cross sections of radioactive $^{132}$Sn on $^{64}$Ni were measured near the Coulomb barrier. A large sub-barrier fusion enhancement was observed. Coupled-channel calculations including inelastic excitation of the projectile and target, and neutron transfer are in good agreement with the measured fusion excitation function. When the change in nuclear size and shift in barrier height are accounted for, there is no extra fusion enhancement in $^{132}$Sn+$^{64}$Ni with respect to stable Sn+$^{64}$Ni. A systematic comparison of evaporation residue cross sections for the fusion of even $^{112-124}$Sn and $^{132}$Sn with $^{64}$Ni is presented.

J. F. Liang; D. Shapira; J. R. Beene; C. J. Gross; R. L. Varner; A. Galindo-Uribarri; J. Gomez del Campo; P. A. Hausladen; P. E. Mueller; D. W. Stracener; H. Amro; J. J. Kolata; J. D. Bierman; A. L. Caraley; K. L. Jones; Y. Larochelle; W. Loveland; D. Peterson

2007-04-05T23:59:59.000Z

308

Proton inelastic scattering on {sup 56}Ni in inverse kinematics  

SciTech Connect (OSTI)

Inelastic proton scattering to the first excited 2{sup +} state at 2.701 MeV in doubly magic {sup 56}Ni was studied at 101 MeV/u in inverse kinematics. The radioactive {sup 56}Ni ion beam was obtained from the SIS heavy ion synchrotron at GSI Darmstadt via fragmentation of a {sup 58}Ni beam, and separation by the fragment separator (FRS). A value B(E2, 0{sup +} {yields} 2{sup +}) = 600 {+-} 120 e{sup 2} fm{sup 4} was obtained which corresponds to a deformation parameter {beta} ({sup 56}Ni) = 0.173 {+-} 0.017.

Kraus, G.; Egelhof, P.; Fischer, C.; Geissel, H.; Himmler, A.; Nickel, F.; Muenzenberg, G.; Schwab, W.; Weiss, A. [GSI, Darmstadt (Germany); Chulkov, L.; Golovkov, M.; Ogloblin, A. [I.V. Kurchatov Inst., Moscow (Russian Federation); Friese, J.; Gillitzer, A.; Koerner, H.J.; Peter, M. [TU, Munich (Germany); Henning, W.; Schiffer, J.P. [Argonne National Lab., IL (United States); Kratz, J.V. [Univ. of Mainz (Germany)

1993-10-01T23:59:59.000Z

309

Characterization of Pt/Al/sub 2/O/sub 3/ catalysts by extended X-ray absorption fine structure  

SciTech Connect (OSTI)

Three different Pt/Al/sub 2/O/sub 3/ catalysts with average crystallite sizes of 95, 26, and 8 A., as assessed by hydrogen chemisorption measurements, and reference samples of platimum foil and PtO/sub 2/ were examined by transmission X-ray absorption measurements near the Pt L/sub I//sub I//sub I/ X-ray absorption edge. The fine structure for the reduced catalysts showed that the first Pt-Pt interatomic separation distance in the crystallites did not change with crystallite size. The 95 and 26 A. catalysts had Pt crystallites with fcc crystal structure, the same as in bulk platimum. Adsorption of carbon monoxide on the 26 A. catalyst at room temperature did not disturb crystallite structure, but oxygen chemisorption on that catalyst significantly reduced the magnitude of the first Pt-Pt peak, implying a reduction in the average number of first-nearest-neighbor Pt atoms. The Fourier transform indicated coordination of Pt atoms with oxygen. All Pt-Pt bands vanished when the 8 A. catalyst was exposed to oxygen. Platimum atom electron deficiency decreased significantly after carbon monoxide or oxygen adsorption on the catalysts.

Lornston, J.M.

1980-01-01T23:59:59.000Z

310

Hydrothermal Growth of Mesoporous SBA-15 Silica in the Presence of PVP-Stabilized Pt Nanoparticles: Synthesis,  

E-Print Network [OSTI]

Hydrothermal Growth of Mesoporous SBA-15 Silica in the Presence of PVP-Stabilized Pt Nanoparticles hydrothermal synthesis. Characterization of the Pt/SBA-15 catalysts suggests that Pt particles are located are responsible for ethane decomposition to surface carbon. The ability to design catalytic structures

Yang, Peidong

311

Wide magnetic field range of Ni-P/PZT/Ni-P cylindrical layered magnetoelectric composites  

E-Print Network [OSTI]

magnetoelectric (ME) composites were prepared by electroless deposition. The Ni-P layer has an amorphous with epoxy,5 electrodeposition,6,7 and electroless deposition.8,9 The objective and the develop- ment trend films with good interfacial bonding.12 Nickel is a kind of conventional magnetic material suitable

Volinsky, Alex A.

312

SF 6432-NI (04-95)  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas ConchasPassive Solar HomePromisingStoriesSANDIA REPORT SANDSDN forAA7/31/136432-NI

313

Airtricity Developments NI Ltd | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of Inspector GeneralDepartmentAUDIT REPORT Americium/Curium Vitrification ProjectAVANTIAirey Jump to:NI Ltd Jump

314

Morphology and composition of Ni-Co electrodeposited powders  

SciTech Connect (OSTI)

The morphology, phase and chemical composition of Ni-Co alloy powders electrodeposited from an ammonium sulfate-boric acid containing electrolyte with different ratio of Ni/Co ions were investigated. The ratios of Ni/Co ions were 1/1, 1/2 and 1/3. The morphology, chemical composition and phase composition of the electrodeposited alloy powders were investigated using AES, SEM, EDS and XRD analysis. Composition of the electrolyte, i.e. the ratio of Ni/Co concentrations was found to influence both, the alloy phase composition and the morphology of Ni-Co alloy powders. At the highest ratio of Ni/Co = 1/1 concentrations typical 2D fern-like dendritic particles were obtained. With a decrease of Ni/Co ions ratio among 2D fern-like dendrites, 3D dendrites and different agglomerates were obtained. X-ray diffraction studies showed that the alloy powders mainly consisted of the face-centered cubic {alpha}-nickel phase and hexagonal close-packed {epsilon}-cobalt phase and minor proportions of face-centered cubic {alpha}-cobalt phase. The occurrence of the latter phase was observed only in the alloy powder with the higher cobalt concentration in electrolyte. The electrodeposition of Ni-Co powders occurred in an anomalous manner. - Highlights: Black-Right-Pointing-Pointer Ni-Co alloys powders were successfully electrodeposited. Black-Right-Pointing-Pointer Composition of the electrolyte (Ni/Co ions ratio) was found to influence on morphology of powders. Black-Right-Pointing-Pointer The electrodeposition of Ni-Co powders occurred in an anomalous manner.

Maksimovic, V.M., E-mail: vesnam@vinca.rs [Institute of Nuclear Sciences, 'Vinca', University of Belgrade, 11001 Belgrade, P. O. Box 522 (Serbia); Lacnjevac, U.C. [Institute for Multidisciplinary research, University of Belgrade, P.O. Box 33, 11030 Belgrade (Serbia); Stoiljkovic, M.M. [Institute of Nuclear Sciences, 'Vinca', University of Belgrade, 11001 Belgrade, P. O. Box 522 (Serbia); Pavlovic, M.G. [Institute of Electrochemistry, ICTM, University of Belgrade, 11000 Belgrade, Njegoseva 12 (Serbia); Jovic, V.D. [Institute for Multidisciplinary research, University of Belgrade, P.O. Box 33, 11030 Belgrade (Serbia)

2011-12-15T23:59:59.000Z

315

ag ni zn-addition: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: Recent research shows that the resistance switching characteristics of NiO thin film, in combinations conversion into NiSi using Ni-AMD, and discuss the chemistry of...

316

Ni(II) Salts and 2-Propanol Effect Catalytic Reductive Coupling of Epoxides and Alkynes  

E-Print Network [OSTI]

A Ni-catalyzed reductive coupling of alkynes and epoxides using Ni(II) salts and simple alcohol reducing agents is described. Whereas previously reported conditions relied on Ni(cod)2 and Et3B, this system has several ...

Beaver, Matthew G.

317

Glycerol Hydrogenolysis on Carbon-Supported PtRu and AuRu Bimetallic Catalysts  

SciTech Connect (OSTI)

Bimetallic PtRu and AuRu catalysts were prepared by a surface redox method in which Pt or Au was deposited onto the surface of carbon-supported Ru nanoparticles with an average diameter of 2-3 nm. Characterization by H2 chemisorption, analytical TEM, and X-ray absorption spectroscopy at the Ru K-edge, Pt LIII-edge, and Au LIII-edge confirmed that Pt and Au were successfully deposited onto Ru without disrupting the Ru particles. Depression of the ethane hydrogenolysis rate over Ru after addition of Au provided further evidence of successful deposition. The bimetallic particles were subsequently evaluated in the aqueous-phase hydrogenolysis of glycerol at 473 K and 40 bar H2 at neutral and elevated pH. Although monometallic Pt and Ru exhibited different activities and selectivities to products, the bimetallic PtRu catalyst functioned more like Ru. A similar result was obtained for the AuRu bimetallic catalyst. The PtRu catalyst appeared to be stable under the aqueous-phase reaction conditions, whereas the AuRu catalyst was altered by the harsh conditions. Gold appeared to migrate off the Ru and agglomerate on the carbon during the reaction in liquid water.

Maris,E.; Ketchie, W.; Murayama, M.; Davis, R.

2007-01-01T23:59:59.000Z

318

Comparison of monolith-supported metals for the direct oxidation of methane of syngas  

SciTech Connect (OSTI)

The partial oxidation of CH[sub 4] in O[sub 2] near atmospheric pressure to produce syngas was investigated on monolith-supported Rh, Ni, Pt, Ir, Pd, Pd-La[sub 2]O[sub 3], Fe, Co, Re, and Ru catalysts in an autothermal flow reactor at residence times of [approximately]10 msec (GHSV [approximately] 100,000 hr[sup [minus]1]). Optimal CH[sub 4] conversion and CO and H[sub 2] selectivities of 0.89, 0.95, and 0.90, respectively, were achieved on Rh at 1000[angstrom]C with no loss in activity over many hours. Ni showed similar conversion and selectivities but deactivated. Experiments with up to 25 vol% H[sub 2]O added to the feed showed little evidence of the occurrence of steam reforming and water-gas shift reactions. Pt and Ir sustained stable reaction but a lower selectivities and conversion than Rh or Ni. Pd, Pd-La[sub 2]O[sub 3], and Co deactivated rapidly, while Re, Ru, and Fe would not sustain autothermal reaction. Ni and Re deactivated by volatilization and metal loss, while Pd-La[sub 2]O[sub 3] deactivated by carbon formation, and Pd deactivated by a combination of metal loss and carbon formation. Pd produced up to 14% selectivity to C[sub 2]H[sub 4] and C[sub 2]H[sub 4] and C[sub 2]H[sub 6], Pd-La[sub 2]O[sub 3] up to 5%, Pt [approximately] 1%, and other metals less than 0.2%. 10 refs., 5 figs., 1 tab.

Torniainen, P.M.; Chu, X.; Schmidt, L.D. (Univ. of Minnesota, Minneapolis (United States))

1994-03-01T23:59:59.000Z

319

Absence of topological insulator phases in non-Hermitian PT-symmetric Hamiltonians  

SciTech Connect (OSTI)

In this work, we consider a generalization of the symmetry classification of topological insulators to non-Hermitian Hamiltonians, which satisfy a combined PT symmetry (parity and time reversal). We show via examples and explicit proofs from separate bulk and gapless boundary-state perspectives that the typical paradigm of forming topological insulator states from Dirac Hamiltonians is not compatible with the construction of non-Hermitian PT-symmetric Hamiltonians. The topological insulator states are PT-breaking phases and have energy spectra that are complex (not real) and, thus, are not consistent quantum theories.

Hu Yichen; Hughes, Taylor L. [Department of Physics, University of Illinois, 1110 West Green St., Urbana, Illinois 61801 (United States)

2011-10-15T23:59:59.000Z

320

Absence of topological insulator phases in non-Hermitian PT-symmetric Hamiltonians  

E-Print Network [OSTI]

In this work we consider a generalization of the symmetry classification of topological insulators to non-Hermitian Hamiltonians which satisfy a combined $PT$-symmetry (parity and time-reversal). We show via examples, and explicit bulk and boundary state proofs that the typical paradigm of forming topological insulator states from Dirac Hamiltonians is not compatible with the construction of non-Hermitian $PT$-symmetric Hamiltonians. The topological insulator states are $PT$-breaking phases and have energy spectra which are complex (not real) and thus such non-Hermitian Hamiltonians are not consistent quantum theories.

Yi Chen Hu; Taylor L. Hughes

2011-07-06T23:59:59.000Z

Note: This page contains sample records for the topic "ni pd pt" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Characterization of spin pumping effect in Permalloy/Cu/Pt microfabricated lateral devices  

SciTech Connect (OSTI)

We studied ferromagnetic resonance (FMR) for microfabricated lateral devices consisting of a Permalloy (Py) rectangular element and a Pt nano-element bridged by a Cu wire, which were located on a coplanar waveguide. A change in the resonance linewidth (?f) was observed in the FMR spectra when the distance between Py and Pt (d) was varied. For devices with d?Pt.

Yamamoto, Tatsuya, E-mail: tyamamoto@imr.tohoku.ac.jp; Seki, Takeshi; Takanashi, Koki [Institute for Materials Research, Tohoku University, Sendai 980-8577 (Japan); Ono, Shimpei [Central Research Institute of Electric Power Industry, Tokyo 201-8511 (Japan)

2014-05-07T23:59:59.000Z

322

Kinetics of the reduction of methyl viologen with hydrogen on a colloidal Pt catalyst  

SciTech Connect (OSTI)

The evolution of H/sub 2/ on a Pt catalyst under the influence of one-electron reductors is part of the photocatalytic process of decomposition of H/sub 2/O into H/sub 2/ and O/sub 2/. As a model reaction we selected the reduction of methyl viologen. The bonding constant for hydrogen on colloidal Pt, as well as the effective rate constant of the heterolytic splitting of H/sub 2/ on the same Pt catalyst are determined. A mathematical description of the reduction of methyl viologen with hydrogen is suggested.

Maier, V.E.; Shafirovich, V.Ya.

1988-10-01T23:59:59.000Z

323

Lanthanide Al-Ni base Ericsson cycle magnetic refrigerants  

DOE Patents [OSTI]

A magnetic refrigerant for a magnetic refrigerator using the Ericsson thermodynamic cycle comprises DyAlNi and (Gd{sub 0.54}Er{sub 0.46})AlNi alloys having a relatively constant {Delta}Tmc over a wide temperature range. 16 figs.

Gschneidner, K.A. Jr.; Takeya, Hiroyuki

1995-10-31T23:59:59.000Z

324

''Bare'' single-particle energies in Ni-56  

E-Print Network [OSTI]

The structure of the low-lying levels in the mirror nuclei Ni-57 and Cu-57 is described within the extended unified model. The problem of single-particle energies in Ni-56 is treated in detail. ''Bare'' single-particle energies are extracted from...

Trache, L.; Kolomiets, A.; Shlomo, S.; Heyde, K.; Dejbakhsh, H.; Gagliardi, Carl A.; Tribble, Robert E.; Zhou, XG; Jacob, VE; Oros, AM.

1996-01-01T23:59:59.000Z

325

Lanthanide Al-Ni base Ericsson cycle magnetic refrigerants  

DOE Patents [OSTI]

A magnetic refrigerant for a magnetic refrigerator using the Ericsson thermodynamic cycle comprises DyAlNi and (Gd.sub.0.54 Er.sub.0.46)AlNi alloys having a relatively constant .DELTA.Tmc over a wide temperature range.

Gschneidner, Jr., Karl A. (Ames, IA); Takeya, Hiroyuki (Ibaraki, JP)

1995-10-31T23:59:59.000Z

326

E-Print Network 3.0 - al-ni-co decagonal quasicrystal Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: of decagonal Al-Ni-Co K. Pussi Department of Electrical Engineering, Lappeenranta University of Technology, P... . EARLIER WORK ON d-Al-Ni-Co STRUCTURES Decagonal...

327

Density Functional Theory and Reaction Kinetics Studies of the Water–Gas Shift Reaction on Pt–Re Catalysts  

SciTech Connect (OSTI)

Periodic, self-consistent density functional theory calculations (DFT-GGA-PW91) on Pt(111) and Pt3Re(111) surfaces, reaction kinetics measurements, and microkinetic modeling are employed to study the mechanism of the water–gas shift (WGS) reaction over Pt and Pt–Re catalysts. The values of the reaction rates and reaction orders predicted by the model are in agreement with the ones experimentally determined; the calculated apparent activation energies are matched to within 6% of the experimental values. The primary reaction pathway is predicted to take place through adsorbed carboxyl (COOH) species, whereas formate (HCOO) is predicted to be a spectator species. We conclude that the clean Pt(111) is a good representation of the active site for the WGS reaction on Pt catalysts, whereas the active sites on the Pt–Re alloy catalyst likely contain partially oxidized metal ensembles.

Carrasquillo-Flores, Ronald; Gallo, Jean Marcel R.; Hahn, Konstanze; Dumesic, James A.; Mavrikakis, Manos

2013-12-01T23:59:59.000Z

328

Formation of a Novel Ordered Ni3Al Surface Structure by Codeposition on NiAl(110)  

E-Print Network [OSTI]

The formation of a new type of ordered 2D Ni3Al overlayer by low-temperature codeposition on NiAl(110) is demonstrated by kinetic Monte Carlo simulation of a multisite atomistic lattice-gas model with a precise treatment ...

Han, Yong

329

Characterization of CeO2-Supported Cu-Pd Bimetallic Catalyst for the Oxygen-Assisted Water-Gas Shift Reaction  

SciTech Connect (OSTI)

This study was focused to investigate the roles of Cu and Pd in CuPd/CeO2 bimetallic catalysts containing 20-30 wt% Cu and 0.5-1 wt% Pd used in the oxygen-assisted water-gas shift (OWGS) reaction employing a combined bulk and surface characterization techniques such as XRD, TPR, CO chemisorption, and in-situ XPS. The catalytic activity for CO conversion and the stability of catalyst during on-stream operation increased by the addition of Cu to Pd/CeO2 or Pd to Cu/CeO2 monometallic catalysts, especially when the OWGS reaction was performed under low temperatures, below 200oC. The bimetallic catalyst after leaching with nitric acid retained about 60% of its original activity. The TPR of monometallic Cu/CeO2 showed reduction of CuO supported on CeO2 in two distinct regions, around 150 and 250oC. The high temperature peak disappeared and reduction occurred in a single step around 150oC upon Pd addition. The Pd dispersion decreased from 38.5% for Pd/CeO2 to below 1% for CuPd/CeO2 bimetallic catalyst. In-situ XPS studies showed a shift in Cu 2p peaks toward lower binding energy (BE) with concommitant shift in the Pd 3d peaks toward higher BE. Addition of Pd decreased the surface Cu concentration while the concentration of Pd remained unaltered. All these observations indicated the formation of Cu-Pd surface alloy. The valence band XP spectra collected below 10 eV corroborated the core level XP spectra and indicated that Cu is mainly involved in the catalytic reaction. The improved catalytic activity and stability of CuPd/CeO2 bimetallic catalyst was attributed to the alloy formation.

Fox, Elise; Velu, Subramani; Engelhard, Mark H.; Chin, Ya-Huei; Miller, Jeffrey T.; Kropf, Jeremy; Song, Chunshan

2008-12-10T23:59:59.000Z

330

Adsorption-induced surface core-level shifts of Pt(110)  

SciTech Connect (OSTI)

A detailed investigation of surface- and adsorbate-induced binding-energy shifts of the Pt 4f core level has been carried out using photoemission with synchrotron radiation. Spectra recorded from the clean Pt(110)-(1 x 2) surface show a single surface peak shifted by -0.46 eV relative to the bulk peak. This result is discussed in light of recent structural studies of the reconstructed Pt(110) surface. Adsorption of H, atomic and molecular oxygen, and CO reveal two surface-atom contributions, whose origins are discussed. In some cases the second peak is believed to arise from former bulk atoms that are influenced by the adsorbate. The main adsorption-induced shifts correlate with thermodynamic data in the framework of a Born-Haber cycle. The shifts cannot be directly rationalized in terms of a charge transfer between the adsorbate and the Pt surface atoms.

Dueckers, K.; Prince, K.C.; Bonzel, H.P.; Chab, V.; Horn, K.

1987-10-15T23:59:59.000Z

331

Interfacial current-induced torques in Pt/Co/GdOx  

E-Print Network [OSTI]

Current-driven domain wall (DW) motion is investigated in Pt/Co/GdOx nanostrips with perpendicular magnetic anisotropy. Measurements of the propagation field and the energy barrier for thermally activated DW motion reveal ...

Emori, Satoru

332

Pd-Catalyzed O-Arylation of Ethyl Acetohydroximate: Synthesis of O-Arylhydroxylamines and Substituted Benzofurans  

E-Print Network [OSTI]

An efficient Pd catalyst for the O-arylation of ethyl acetohydroximate with aryl chlorides, bromides, and iodides has been developed. Ethyl acetohydroximate serves as an efficient hydroxylamine equivalent for C?O cross-coupling, ...

Maimone, Thomas

333

COMMENTS ON ANOMALOUS EFFECTS IN CHARGING OF PD POWDERS WITH HIGH DENSITY HYDROGEN ISOTOPES  

SciTech Connect (OSTI)

In Kitamura, et al, Pd-containing materials are exposed to isotopes of hydrogen and anomalous results obtained. These are claimed to be a replication of another experiment conducted by Arata and Zhang. Erroneous basic assumptions are pointed out herein that alter the derived conclusions significantly. The final conclusion is that the reported results are likely normal chemistry combined with noise. Thus the claim to have proven that cold fusion is occurring in these systems is both premature and unlikely.

Shanahan, K.

2009-10-01T23:59:59.000Z

334

Spectral Singularity in confined PT symmetric optical potential  

E-Print Network [OSTI]

We present an analytical study for the scattering amplitudes (Reflection $|R|$ and Transmission $|T|$), of the periodic ${\\cal{PT}}$ symmetric optical potential $ V(x) = \\displaystyle W_0 \\left( \\cos ^2 x + i V_0 \\sin 2x \\right) $ confined within the region $0 \\leq x \\leq L$, embedded in a homogeneous medium having uniform potential $W_0$. The confining length $L$ is considered to be some integral multiple of the period $ \\pi $. We give some new and interesting results. Scattering is observed to be normal ($|T| ^2 \\leq 1, \\ |R|^2 \\leq 1$) for $V_0 \\leq 0.5 $, when the above potential can be mapped to a Hermitian potential by a similarity transformation. Beyond this point ($ V_0 > 0.5 $) scattering is found to be anomalous ($|T| ^2, \\ |R|^2 $ not necessarily $ \\leq 1 $). Additionally, in this parameter regime of $V_0$, one observes infinite number of spectral singularities $E_{SS}$ at different values of $V_0$. Furthermore, for $L= 2 n \\pi$, the transition point $V_0 = 0.5$ shows unidirectional invisibility with zero reflection when the beam is incident from the absorptive side ($Im [V(x)] 0$), transmission being identically unity in both cases. Finally, the scattering coefficients $|R|^2$ and $|T|^2 $ always obey the generalized unitarity relation : $ ||T|^2 - 1| = \\sqrt{|R_R|^2 |R_L|^2}$, where subscripts $R$ and $L$ stand for right and left incidence respectively.

Anjana Sinha; R. Roychoudhury

2013-11-13T23:59:59.000Z

335

The first principle study of Ni{sub 2}ScGa and Ni{sub 2}TiGa  

SciTech Connect (OSTI)

We computed the electronic structure, elastic moduli, vibrational properties, and Ni{sub 2}TiGa and Ni{sub 2}ScGa alloys in the cubic L2{sub 1} structure. The obtained equilibrium lattice constants of these alloys are in good agreement with available data. In cubic systems, there are three independent elastic constants, namely C{sub 11}, C{sub 12} and C{sub 44}. We calculated elastic constants in L2{sub 1} structure for Ni{sub 2}TiGa and Ni{sub 2}ScGa using the energy-strain method. The electronic band structure, total and partial density of states for these alloys were investigated within density functional theory using the plane-wave pseudopotential method implemented in Quantum-Espresso program package. From band structure, total and projected density of states, we observed metallic characters of these compounds. The electronic calculation indicate that the predominant contributions of the density of states at Fermi level come from the Ni 3d states and Sc 3d states for Ni{sub 2}TiGa, Ni 3d states and Sc 3d states for Ni{sub 2}ScGa. The computed density of states at Fermi energy are 2.22 states/eV Cell for Ni{sub 2}TiGa, 0.76 states/eV Cell for Ni{sub 2}ScGa. The vibrational properties were obtained using a linear response in the framework at the density functional perturbation theory. For the alloys, the results show that the L2{sub 1} phase is unstable since the phonon calculations have imagine modes.

Özduran, Mustafa [Ahi Evran Üniversitesi Fen Edebiyat Fakültesi Fizik Bölümü, K?r?ehir (Turkey); Turgut, Kemal [Yüksek Lisans Ö?rencisi, K?r?ehir (Turkey); Arikan, Nihat [Ahi Evran Üniversitesi E?itim Fakültesi ?lkö?retim Bölümü, K?r?ehir (Turkey); ?yigör, Ahmet; Candan, Abdullah [Ahi Evran Üniversitesi Merkezi Ara?t?rma Laboratuvar?, K?r?ehir (Turkey)

2014-10-06T23:59:59.000Z

336

Preparation of Ni-Sn alloys by an electroless-deposition method  

SciTech Connect (OSTI)

Ni-Sn alloy is expected for as a functional material, because of its excellent corrosion resistance, wear resistance, and solderability. Electroless-deposited Ni-Sn alloy films were investigated to increase tin content in the deposit. The maximum tin contents of electroless Ni-Sn-P and Ni-Sn-B were ca. 30 atom percent (a/o) and 42 a/o, respectively. The maximum tin contents in the case of Ni-Sn-B was nearly equal to that of electrodeposited Ni-Sn alloy already reported. The crystallinity of Ni-Sn-P and Ni-Sn-B alloys was raised up with an increase in tin content. The corrosion resistance of Ni-Sn-P and Ni-Sn-B alloys was between that of amorphous and crystalline electroless-deposited Ni-P. Codeposition of tin into Ni-P films improved solderability, but into the Ni-B films, the solderability of Ni-Sn-B films situated in the region between those of Ni-P and NiB, because the solderability of NiB is higher.

Shimauchi, Hidenori; Ozawa, Susumu; Tamura, Keiu; Osaka, Tetsuya (Waseda Univ., Tokyo (Japan). Dept. of Applied Chemistry)

1994-06-01T23:59:59.000Z

337

Kinetics of CO adsorption on epitaxial (111)Cu on (111)Pd thin films  

SciTech Connect (OSTI)

CO adsorption has been studied on (111)Cu/Pd thin-film surfaces grown epitaxially on mica in UHV of base pressure 5 x 10/sup -11/ Torr. Auger electron spectroscopy investigations of the growth of Cu on (111)Pd films showed that layer growth occurred. The Kelvin probe, work function method was used to monitor the CO adsorption at 298 K as a function of Cu overlayer thickness. It was found that very thin Cu overlayers had a drastic effect on saturation CO coverage: one monolayer of copper reduced the saturation CO coverage by /similar to/95%. For the pure (111)Pd thin-film surface, the data showed that the rate of CO adsorption changes when the CO fractional coverage approaches /similar to/0.4. This result is most likely due to the previously reported change in CO superlattice structure that occurs with increasing coverage. The kinetic adsorption data for various bilayers were interpreted in terms of a first-order Kisliuk mobile precursor model.

Oral, B.; Kothari, R.; Vook, R.W.

1989-05-01T23:59:59.000Z

338

TUNING OF SIZE AND SHAPE OF AU-PT NANOCATALYST FOR DIRECT METHANOL FUEL CELLS  

SciTech Connect (OSTI)

In this paper, we report the precise control of the size, shape and surface morphology of Au-Pt nanocatalysts (cubes, blocks, octahedrons and dogbones) synthesized via a seed-mediated approach. Gold 'seeds' of different aspect ratios (1 to 4.2), grown by a silver-assisted approach, were used as templates for high-yield production of novel Au-Pt nanocatalysts at a low temperature (40 C). Characterization by electron microscopy (SEM, TEM, HRTEM), energy dispersive X-ray analysis (EDX), UV-Vis spectroscopy, zeta-potential (surface charge), atomic force microscopy (AFM), X-ray photoelectron spectroscopy (XPS) and inductively coupled plasma mass spectrometry (ICP-MS) were used to better understand their physico-chemical properties, preferred reactivities and underlying nanoparticle growth mechanism. A rotating disk electrode was used to evaluate the Au-Pt nanocatalysts electrochemical performance in the oxygen reduction reaction (ORR) and the methanol oxidation reaction (MOR) of direct methanol fuel cells. The results indicate the Au-Pt dogbones are partially and in some cases completely unaffected by methanol poisoning during the evaluation of the ORR. The ORR performance of the octahedron particles in the absence of MeOH is superior to that of the Au-Pt dogbones and Pt-black, however its performance is affected by the presence of MeOH.

Murph, S.

2011-04-20T23:59:59.000Z

339

Reaction synthesis of Ni-Al based particle composite coatings  

SciTech Connect (OSTI)

Electrodeposited metal matrix/metal particle composite (EMMC) coatings were produced with a nickel matrix and aluminum particles. By optimizing the process parameters, coatings were deposited with 20 volume percent aluminum particles. Coating morphology and composition were characterized using light optical microscopy (LOM), scanning electron microscopy (SEM), and electron probe microanalysis (EPMA). Differential thermal analysis (DTA) was employed to study reactive phase formation. The effect of heat treatment on coating phase formation was studied in the temperature range 415 to 1,000 C. Long-time exposure at low temperature results in the formation of several intermetallic phases at the Ni matrix/Al particle interfaces and concentrically around the original Al particles. Upon heating to the 500--600 C range, the aluminum particles react with the nickel matrix to form NiAl islands within the Ni matrix. When exposed to higher temperatures (600--1,000 C), diffusional reaction between NiAl and nickel produces ({gamma})Ni{sub 3}Al. The final equilibrium microstructure consists of blocks of ({gamma}{prime})Ni{sub 3}Al in a {gamma}(Ni) solid solution matrix, with small pores also present. Pore formation is explained based on local density changes during intermetallic phase formation and microstructural development is discussed with reference to reaction synthesis of bulk nickel aluminides.

SUSAN,DONALD F.; MISIOLEK,WOICECK Z.; MARDER,ARNOLD R.

2000-02-11T23:59:59.000Z

340

Pt nanoparticles modified by rare earth oxides: Electronic effect and influence to catalytic hydrogenation of 3-phenoxybenzaldehyde  

SciTech Connect (OSTI)

Graphical abstract: - Highlights: • The rare earths modified Pt/Al{sub 2}O{sub 3} were prepared by colloidal deposition method. • Modification of Pt by the rare earth enhanced catalytic hydrogenation activity. • The activity improvement is due to electron interaction between Pt and rare earth. • The hydrogenation mechanism of rare earth modified Pt catalyst was proposed. - Abstract: The rare earth elements (La, Ce, Nd, Sm, Pr, and Gd) modified Pt/Al{sub 2}O{sub 3} catalysts were prepared by the colloidal deposition and chemical reduction methods, respectively. Pt nanoparticles with average size 3 ± 0.5 nm were uniformly dispersed on the surface of Al{sub 2}O{sub 3} for the samples prepared by the colloidal deposition method, which exhibited higher activities in the hydrogenation of 3-phenoxybenzadehyde than the corresponding samples prepared by chemical reduction method. Moreover, except Gd, the catalysts modified by rare earth elements showed better catalytic performance than unmodified Pt/Al{sub 2}O{sub 3}. For Pt–Ce/Al{sub 2}O{sub 3} catalyst, when the weight percent of Pt and Ce was 0.5 and 0.25, respectively, the hydrogenation conversion of 3-phenoxybenzaldehyde was 97.3% after 6 h reaction. This activity improvement is due to the electronic interaction between Pt and rare earth elements, which was investigated by X-ray photoelectron spectroscopy.

Mou, Zhigang; Han, Ming; Li, Gang; Du, Yukou [College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123 (China); Yang, Ping, E-mail: pyang@suda.edu.cn [College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123 (China); Zhang, Hailu [Suzhou Institute of Nano-tech and Nano-bionics, Chinese Academy of Sciences, Suzhou 215123 (China); Deng, Zongwu, E-mail: zwdeng2007@sinano.ac.cn [Suzhou Institute of Nano-tech and Nano-bionics, Chinese Academy of Sciences, Suzhou 215123 (China)

2013-11-15T23:59:59.000Z

Note: This page contains sample records for the topic "ni pd pt" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

On the road to doubly-magic {sup 48}Ni  

SciTech Connect (OSTI)

A relativistic primary beam of {sup 58}Ni from the SIS synchrotron at GSI was used to produce proton-rich isotopes in the titanium-to-nickel region by projectile fragmention at the FRS. We report here on the first observation of the T{sub z}=-7/2 nuclei {sup 45}Fe and {sup 49}Ni. In addition, the new isotope {sup 42}Cr (T{sub z}=-3) was identified. This opens the route to the yet unobserved doubly-magic nucleus {sup 48}Ni.

Blank, B.; Czajkowski, S.; Davi, F.; Del Moral, R.; Dufour, J. P.; Fleury, A.; Marchand, C.; Pravikoff, M. S. [Centre d'Etudes Nucleaires de Bordeaux-Gradignan, F-33175 Gradignan Cedex (France); Benlliure, J.; Boue, F.; Collatz, R.; Heinz, A.; Hellstroem, M.; Hu, Z.; Roeckl, E.; Shibata, M.; Suemmerer, K. [Gesellschaft fuer Schwerionenforschung, Planckstr. 1, D-64291 Darmstadt (Germany); Lewitowicz, M. [Grand Accelerateur National des Ions Lourds, B.P. 5027, F-14021 Caen Cedex (France); Janas, Z.; Karny, M. [Institute of Experimental Physics, University of Warsaw, PL-00-681 Warsaw, Hoza 69 (Poland)] (and others)

1998-12-21T23:59:59.000Z

342

Graphene Monolayer Rotation on Ni(111) Facilities Bilayer Graphene Growth  

SciTech Connect (OSTI)

Synthesis of bilayer graphene by chemical vapor deposition is of importance for graphene-based field effect devices. Here, we demonstrate that bilayer graphene preferentially grows by carbon-segregation under graphene sheets that are rotated relative to a Ni(111) substrate. Rotated graphene monolayer films can be synthesized at growth temperatures above 650 C on a Ni(111) thin-film. The segregated second graphene layer is in registry with the Ni(111) substrate and this suppresses further C-segregation, effectively self-limiting graphene formation to two layers.

Batzill M.; Sutter P.; Dahal, A.; Addou, R.

2012-06-11T23:59:59.000Z

343

Application of cluster-plus-glue-atom model to barrierless Cu–Ni–Ti and Cu–Ni–Ta films  

SciTech Connect (OSTI)

To improve the thermal stability of copper and avoid its diffusion into surrounding dielectrics or interfacial reactions with them, the authors applied the cluster-plus-glue-atom model to investigate barrierless Cu–Ni–M (M?=?Ti or Ta) seed layers. The dissolution of the third element (Ti or Ta) in the Cu lattice with the aid of Ni significantly improved the thermal stability of the Cu seed layer. The appropriate M/Ni (M?=?Ti or Ta) ratio was selected to obtain a low resistivity: the resistivity was as low as 2.5??? cm for the (Ti{sub 1.5/13.5}Ni{sub 12/13.5}){sub 0.3}Cu{sub 99.7} film and 2.8??? cm for the (Ta{sub 1.1/13.1}Ni{sub 12/13.1}){sub 0.4}Cu{sub 99.6} film after annealing at 500?°C for 1?h. After annealing at 500?°C for 40?h, the two films remained stable without forming a Cu{sub 3}Si compound. The authors confirmed that the range of applications of the cluster-plus-glue-atom model could be extended. Therefore, a third element M with negative enthalpies of mixing with both Cu and Ni could be selected, under the premise that the mixing enthalpy of M–Ni is more negative than that of M–Cu.

Li, Xiaona, E-mail: lixiaona@dlut.edu.cn; Ding, Jianxin; Wang, Miao; Dong, Chuang [Key Laboratory of Materials Modification by Laser, Ion and Electron Beams (Dalian University of Technology), Ministry of Education, Dalian 116024 (China); Chu, Jinn P. [Department of Materials Science and Engineering, National Taiwan University of Science and Technology, Taipei 10607, Taiwan (China)

2014-11-01T23:59:59.000Z

344

Perpendicular magnetic anisotropy in ion beam sputtered Co/Ni multilayers  

E-Print Network [OSTI]

Co/Ni multilayers display perpendicular magnetic anisotropy and have applications in magnetic devices that could lead to a large increase in the density of magnetic storage. Co/Ni 10-(2 Å Co/ 8Å Ni) and 10-(2 Å Co/ 4 Å Ni) ...

Rasin, Boris

2009-01-01T23:59:59.000Z

345

TiNi shape memory alloy thin films for microactuator application  

E-Print Network [OSTI]

TiNi films were prepared by co-sputtering TiNi target and a separate Ti target. Crystalline structure and phase transformation behaviors of TiNi films were investigated. Results showed that TiNi films had fine grain size ...

Fu, Yongqing

346

Surface Patterns of Tetragonal Phase FePt Thin Films from Pt{at}Fe2O3 Core-Shell Nanoparticles Using Combined Langmuir-Blodgett and Soft Lithographic Techniques  

SciTech Connect (OSTI)

OAK B204 We present the fabrication of micron-sized patterns of FePt thin films from Pt{at}Fe2O3 core-shell nanoparticles. In a typical procedure, Pt@Fe2O3 core-shell nanoparticles were spread and formed a Langmuir film using water as the subphase. This film was lifted onto polydimethylsiloxane (PDMS) stamps with micron-sized patterns of lines, dots and wells, and transferred onto silicon wafers using microcontact printing (u-CP). The patterns of Pt@Fe2O3 core-shell nanoparticles were converted into face-centered tetragonal phase FePt alloy at enhanced temperatures in the presence of 5% hydrogen. Scanning electron microscopy (SEM), atomic force microscopy (AFM), powder X-ray diffraction (PXRD) and superconducting quantum interference device (SQUID) magnetometer were used to characterize the patterns and the properties of the final FePt alloy films.

Guo, Q.; Teng, X.; Yang, H.

2003-09-30T23:59:59.000Z

347

Hydrogen production from methanol decomposition over Pt/Al2O3 and ceria promoted Pt/Al2O3 catalysts  

E-Print Network [OSTI]

rights reserved. Keywords: Methanol decomposition; Pt/alumina; Ceria; Hydrogen; PEM fuel cell 1 exchange mem- brane (PEM) fuel cell system. PEM fuel cells convert hydrogen gas into useful electric power is seen as an attractive means of providing the necessary hydrogen to the fuel cell. With the exception

Gulari, Erdogan

348

$^{64}$Ni+$^{64}$Ni fusion reaction calculated with the density-constrained time-dependent Hartree-Fock formalism  

E-Print Network [OSTI]

We study fusion reactions of the $^{64}$Ni+$^{64}$Ni system using the density-constrained time-dependent Hartree-Fock (TDHF) formalism. In this formalism the fusion barriers are directly obtained from TDHF dynamics. In addition, we incorporate the entrance channel alignments of the slightly deformed (oblate) $^{64}$Ni nuclei due to dynamical Coulomb excitation. We show that alignment leads to a fusion barrier distribution and alters the naive picture for defining which energies are actually sub-barrier. We also show that core polarization effects could play a significant role in fusion cross section calculations.

A. S. Umar; V. E. Oberacker

2007-09-25T23:59:59.000Z

349

Ni(NiO)/single-walled carbon nanotubes composite: Synthesis of electro-deposition, gas sensing property for NO gas and density functional theory calculation  

SciTech Connect (OSTI)

Graphical abstract: The Ni(NiO)/semiconducting single-walled carbon nanotubes composite collected from the cathode after electro-deposition shows a high sensitivity to low-concentration NO gas at room temperature (18 °C). Display Omitted Highlights: ? Ni(NiO) nanoparticles were deposited on semiconducting SWCNTs by electro-deposition. ? Ni(NiO)/semiconducting SWCNTs film shows a high sensitivity to NO gas at 18 °C. ?Theoretical calculation reveals electron transfer from SWCNTs to NO via Ni. -- Abstract: Single-walled carbon nanotubes which contains metallic SWCNTs (m-SWCNTs) and semiconducting SWCNTs (s-SWCNTs) have been obtained under electric arc discharge. Their separation can be effectively achieved by the electro-deposition method. The Ni(NiO)/s-SWCNTs composite was found on cathode where Ni was partially oxidized to NiO at ambient condition with Ni(NiO) nanoparticles deposited uniformly on the bundles of SWCNTs. These results were confirmed by Raman spectra, transmission electron microscopy (TEM), scanning electron microscopy (SEM), UV–vis–NIR and TG characterizations. Furthermore, investigation of the gas sensing property of Ni(NiO)/s-SWCNTs composite film to NO gas at 18 °C demonstrated the sensitivity was approximately 5% at the concentration of 97 ppb. Moreover, density functional theory (DFT) calculations were performed to explore the sensing mechanism which suggested the adsorption of NO molecules onto the composite through N–Ni interaction as well as the proposition of electron transfer mechanisms from SWCNTs to NO via the Ni medium.

Li, Li; Zhang, Guo; Chen, Lei [Key Laboratory of Chemical Engineering Process and Technology for High-efficiency Conversion, College of Heilongjiang Province, Heilongjiang University, Harbin 150080 (China)] [Key Laboratory of Chemical Engineering Process and Technology for High-efficiency Conversion, College of Heilongjiang Province, Heilongjiang University, Harbin 150080 (China); Bi, Hong-Mei [Key Laboratory of Functional Inorganic Material Chemistry, Ministry of Education, School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080 (China)] [Key Laboratory of Functional Inorganic Material Chemistry, Ministry of Education, School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080 (China); Shi, Ke-Ying, E-mail: shikeying2008@yahoo.cn [Key Laboratory of Functional Inorganic Material Chemistry, Ministry of Education, School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080 (China)] [Key Laboratory of Functional Inorganic Material Chemistry, Ministry of Education, School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080 (China)

2013-02-15T23:59:59.000Z

350

Chemo-sensors development based on low-dimensional codoped Mn2O3-ZnO nanoparticles using flat-silver electrodes  

E-Print Network [OSTI]

sensor based on a Pd-Ni/SiNWs electrode. Sens Actuator Bsensor based on a Pd-Ni/SiNWs electrode. App Surf Sci 2009,

Rahman, Mohammed M; Gruner, George; Al-Ghamdi, Mohammed Saad; Daous, Muhammed A; Khan, Sher Bahadar; Asiri, Abdullah M

2013-01-01T23:59:59.000Z

351

The stellar (n,gamma) cross section of 62Ni  

E-Print Network [OSTI]

The 62Ni(n,gamma)63Ni(t_1/2=100+-2 yrs) reaction plays an important role in the control of the flow path of the slow neutron-capture (s-) nucleosynthesis process. We have measured for the first time the total cross section of this reaction for a quasi-Maxwellian (kT = 25 keV) neutron flux. The measurement was performed by fast-neutron activation, combined with accelerator mass spectrometry to detect directly the 63Ni product nuclei. The experimental value of 28.4+-2.8 mb, fairly consistent with a recent theoretical estimate, affects the calculated net yield of 62Ni itself and the whole distribution of nuclei with 62

352

Transverse acoustic actuation of Ni-Mn-Ga single crystals  

E-Print Network [OSTI]

Two methods for the transverse acoustic actuation of {110}-cut Ni-Mn-Ga single crystals are discussed. In this actuation mode, crystals are used that have the {110}- type twinning planes parallel to the base of the crystal. ...

Simon, Jesse Matthew

2007-01-01T23:59:59.000Z

353

Electrodeposition of amorphous matrix Ni-W/Wp̳ composites  

E-Print Network [OSTI]

An amorphous Ni-W alloy matrix was incorporated with W particulate through two types of electrodeposition. The plating bath for the electrodeposition contained nickel sulfate, sodium tungstate, sodium citrate, ammonium ...

Jenket, Donald R. (Donald Robert)

2005-01-01T23:59:59.000Z

354

Double dumbbell shaped AgNi alloy by pulsed electrodeposition  

SciTech Connect (OSTI)

Silver-Nickel is the well-known thermally immiscible system that makes them quite complex for the formation of alloy. This kind of alloy can be attained from electrodeposition method. In the present work, AgNi alloy was synthesized by pulsed electrodeposition in a single bath two electrode system with the use of anodic alumina membrane. The prepared AgNi alloy and pure Ag were characterized with X-ray Diffraction (XRD) for structural confirmation, Scanning Electron Microscopy (SEM) for morphological, and magnetic properties by Vibrating Sample Magnetometer, respectively. The X-ray Diffraction study shows the formation of cubic structure for pure Ag. SEM analysis reveals the double dumbbell morphology for AgNi alloy and spherically agglomeration for pure silver. Hysteresis behaviour from VSM measurement indicates that the AgNi alloy have good ferro-magnetic properties.

Dhanapal, K.; Vasumathi, M.; Santhi, Kalavathy [Materials Science Centre, Department of Nuclear Physics, University of Madras, Guindy Campus, Chennai 600 025 (India); Narayanan, V., E-mail: stephen-arum@hotmail.com; Stephen, A., E-mail: stephen-arum@hotmail.com [Department of Inorganic Chemistry, University of Madras, Guindy Campus, Chennai-600 025 (India)

2014-01-28T23:59:59.000Z

355

Effects of Reduction Temperature and Metal-Support Interactions on the Catalytic Activity of Pt/g-Al2O3 and Pt/TiO2 for the Oxidation of CO in the Presence and Absence of H2.  

SciTech Connect (OSTI)

TiO2- and -Al2O3-supported Pt catalysts were characterized by HRTEM, XPS, EXAFS, and in situ FTIR spectroscopy after activation at various conditions, and their catalytic properties were examined for the oxidation of CO in the absence and presence of H2 (PROX). When {gamma}-Al{sub 2}O{sub 3} was used as the support, the catalytic, electronic, and structural properties of the Pt particles formed were not affected substantially by the pretreatment conditions. In contrast, the surface properties and catalytic activity of Pt/TiO2 were strongly influenced by the pretreatment conditions. In this case, an increase in the reduction temperature led to higher electron density on Pt, altering its chemisorptive properties, weakening the Pt-CO bonds, and increasing its activity for the oxidation of CO. The in situ FTIR data suggest that both the terminal and bridging CO species adsorbed on fully reduced Pt are active for this reaction. The high activity of Pt/TiO2 for the oxidation of CO can also be attributed to the ability of TiO2 to provide or stabilize highly reactive oxygen species at the metal-support interface. However, such species appear to be more reactive toward H{sub 2} than CO. Consequently, Pt/TiO{sub 2} shows substantially lower selectivities toward CO oxidation under PROX conditions than Pt/{gamma}-Al{sub 2}O{sub 3}.

Alexeev,O.; Chin, S.; Engelhard, M.; Ortiz-Soto, L.; Amiridis, M.

2005-01-01T23:59:59.000Z

356

MICROSTRUCTURE OF LONG-TERM AGED IN617 NI-BASE SUPERALLOY  

SciTech Connect (OSTI)

The microstructure of the Ni-base superalloy IN617 that had undergone prolonged aging (approximately 65,000 hours) at a series of temperatures from 482 C to 871 C has been characterized by microhardness measurements, optical microscopy, scanning electron microscopy (SEM), and transmission electron microscopy (TEM). Cr23C6, Mo-rich eta-M6C, and Ti(C,N) constitute the major primary coarse precipitates both within the grains and along the grain boundaries. The secondary carbides were mostly fine Cr23C6, which had a cube-on-cube orientation relationship (OR) with the fcc matrix, and at long times were present in cuboidal and plate-shape forms within the grains and as films along the grain boundaries. Fine, eta-M6C carbides were also observed at low to intermediate temperatures with an OR given by [011] carbide//[011] matrix, carbide// matrix. The coarse eta-M6C carbides increased in extent at 871 C, whereas the counterpart fine carbides were absent. The phase was found to be present at all aging temperatures up to 871 C, with a volume fraction ranging from very low to approximately 5 pct at 593 C, where the peak in microhardness occurs. The observations have also suggested that the presence of a very small amount of at temperatures as high as 871 C at long times may be associated with a reaction between the fine eta-carbides and the matrix. Ultrafine precipitates of the intermetallic phase Ni2(Cr,Mo) with the Pt2Mo-type structure was observed in addition to in samples aged for 28,300 hours at the lowest aging temperature of 482 C. These precipitates were absent in samples aged at higher temperatures. The various observations made have suggested that the long-term thermal stability of the IN617 alloy is reasonably good over a wide temperature range of 538 C to 704 C, whereas at higher temperatures (871 C), the substantial decrease in the volume fraction of and coarsening and clustering of the carbides lead to a large drop in the microhardness. A modified time-temperature-transformation (TTT) diagram was constructed based on the results of this study and comparison with previous reports.

Wu, Quanyan [University of Cincinnati; Shingledecker, John P [ORNL; Vasudevan, Vijay [University of Cincinnati; Swindeman, Robert W [ORNL

2008-01-01T23:59:59.000Z

357

Balance of Nanostructure and Bimetallic Interactions in Pt Model Fuel Cell Catalysts: An in Situ XAS and DFT Study  

SciTech Connect (OSTI)

We have studied the effect of nanostructuring in Pt monolayer model electrocatalysts on a Rh(111) single-crystal substrate on the adsorption strength of chemisorbed species. In situ high energy resolution fluorescence detection X-ray absorption spectroscopy at the Pt L(3) edge reveals characteristic changes of the shape and intensity of the 'white-line' due to chemisorption of atomic hydrogen (H(ad)) at low potentials and oxygen-containing species (O/OH(ad)) at high potentials. On a uniform, two-dimensional Pt monolayer grown by Pt evaporation in ultrahigh vacuum, we observe a significant destabilization of both H(ad) and O/OH(ad) due to strain and ligand effects induced by the underlying Rh(111) substrate. When Pt is deposited via a wet-chemical route, by contrast, three-dimensional Pt islands are formed. In this case, strain and Rh ligand effects are balanced with higher local thickness of the Pt islands as well as higher defect density, shifting H and OH adsorption energies back toward pure Pt. Using density functional theory, we calculate O adsorption energies and corresponding local ORR activities for fcc 3-fold hollow sites with various local geometries that are present in the three-dimensional Pt islands.

Friebel, Daniel; Viswanathan, Venkatasubramanian; Miller, Daniel James; Anniyev, Toyli; Ogasawara, Hirohito; Larsen, Ask Hjorth; O'Grady, Christopher P.; Norskov, Jens K.; Nilsson, Anders

2012-05-31T23:59:59.000Z

358

{sup 103}Pd strings: Monte Carlo assessment of a new approach to brachytherapy source design  

SciTech Connect (OSTI)

Purpose: A new type of{sup 103}Pd source (CivaString and CivaThin by CivaTech Oncology, Inc.) is examined. The source contains {sup 103}Pd and Au radio-opaque marker(s), all contained within low-Z{sub eff} organic polymers that permit source flexibility. The CivaString source is available in lengths L of 10, 20, 30, 40, 50, and 60 mm, and referred to in the current study as CS10–CS60, respectively. A thinner design, CivaThin, has sources designated as CT10–CT60, respectively. The CivaString and CivaThin sources are 0.85 and 0.60 mm in diameter, respectively. The source design is novel and offers an opportunity to examine its interesting dosimetric properties in comparison to conventional {sup 103}Pd seeds. Methods: The MCNP5 radiation transport code was used to estimate air-kerma rate and dose rate distributions with polar and cylindrical coordinate systems. Doses in water and prostate tissue phantoms were compared to determine differences between the TG-43 formalism and realistic clinical circumstances. The influence of Ti encapsulation and 2.7 keV photons was examined. The accuracy of superposition of dose distributions from shorter sources to create longer source dose distributions was also assessed. Results: The normalized air-kerma rate was not highly dependent onL or the polar angle ?, with results being nearly identical between the CivaString and CivaThin sources for common L. The air-kerma strength was also weakly dependent on L. The uncertainty analysis established a standard uncertainty of 1.3% for the dose-rate constant ?, where the largest contributors were ?{sub en}/? and ?/?. The ? values decreased with increasing L, which was largely explained by differences in solid angle. The radial dose function did not substantially vary among the CivaString and CivaThin sources for r ? 1 cm. However, behavior for r < 1 cm indicated that the Au marker(s) shielded radiation for the sources having L = 10, 30, and 50 mm. The 2D anisotropy function exhibited peaks and valleys that corresponded to positions adjacent to {sup 103}Pd wells and Au markers, respectively. Dose distributions of both source types had minimal anisotropy in comparison to conventional {sup 103}Pd seeds. Contributions by 2.7 keV photons comprised ?0.1% of the dose from all photons at positions farther than 0.13 mm from the polymer source surface. Differences between absorbed dose to water and prostate became more substantial as distance from the sources increased, with prostate dose being about 13% lower for r = 5 cm. Using a cylindrical coordinate system, dose superposition of small length sources to replicate the dose distribution for a long length source proved to be a robust technique; a 2.0% tolerance compared with the reference dose distribution did not exceed 0.1 cm{sup 3} for any of the examined source combinations. Conclusions: By design, the CivaString and CivaThin sources have novel dosimetric characteristics in comparison to Ti-encapsulated{sup 103}Pd seeds. The dosimetric characterization has determined the reasons for these differences through analysis using Monte Carlo-based radiation transport simulations.

Rivard, Mark J., E-mail: mark.j.rivard@gmail.com [Department of Radiation Oncology, Tufts University School of Medicine, Boston, Massachusetts 02111 (United States); Reed, Joshua L.; DeWerd, Larry A. [Department of Medical Physics, University of Wisconsin-Madison, Madison, Wisconsin 53705 (United States)] [Department of Medical Physics, University of Wisconsin-Madison, Madison, Wisconsin 53705 (United States)

2014-01-15T23:59:59.000Z

359

High-temperature phase stability and tribological properties of laser clad Mo{sub 2}Ni{sub 3}Si/NiSi metal silicide coatings  

SciTech Connect (OSTI)

Mo{sub 2}Ni{sub 3}Si/NiSi wear-resistant metal silicide composite coatings consisting of Mo{sub 2}Ni{sub 3}Si primary dendrite and interdendritic Mo{sub 2}Ni{sub 3}Si/NiSi eutectic were fabricated on substrate of an austenitic stainless steel AISI321 by laser cladding using Ni-Mo-Si elemental powder blends. The high-temperature structural stability of the coating was evaluated by aging at 800 deg. C for 1-50 h. High-temperature sliding wear resistance of the as-laser clad and aged coatings was evaluated at 600 deg. C. Results indicate that the Mo{sub 2}Ni{sub 3}Si/NiSi metal silicides coating has excellent high temperature phase stability. No phase transformation except the dissolution of the eutectic Mo{sub 2}Ni{sub 3}Si and the corresponding growth of the Mo{sub 2}Ni{sub 3}Si primary dendrite and no elemental diffusion from the coating into the substrate were detected after aging the coating at 800 deg. C for 50 h. Aging of the coating at 800 deg. C leads to gradual dissolution of the interdendritic eutectic Mo{sub 2}Ni{sub 3}Si and subsequent formation of a dual-phase structure with equiaxed Mo{sub 2}Ni{sub 3}Si primary grains distributed in the NiSi single-phase matrix. Because of the strong covalent-dominated atomic bonds and high volume fraction of the ternary metal silicide Mo{sub 2}Ni{sub 3}Si, both the original and the aged Mo{sub 2}Ni{sub 3}Si/NiSi coating has excellent wear resistance under pin-on-disc high-temperature sliding wear test conditions, although hardness of the aged coating is slightly lower than that of the as-clad coating.

Lu, X.D. [Laboratory of Laser Materials Processing and Surface Engineering, School of Materials Science and Engineering, Beihang University (China); Wang, H.M. [Laboratory of Laser Materials Processing and Surface Engineering, School of Materials Science and Engineering, Beihang University (China)]. E-mail: wanghuaming@263.net

2004-10-18T23:59:59.000Z

360

The Role of Partial Crystallinity on Hydrogen Permeation in Fe–Ni–B–Mo Based Metallic Glass Membranes  

SciTech Connect (OSTI)

A potentially exciting material for membrane separations are metallic glass materials due to their low cost, high elastic toughness and resistance to hydrogen embrittlement as compared to crystalline Pd-based membrane systems. However, at elevated temperatures and extended operation times structural changes including partial crystallinity may appear in these amorphous metallic systems. This study reports on the investigation of time and temperature dependent crystalline phase formation in conjunction with in situ crystallization/hydrogen permeation experiments at elevated temperatures. At temperatures near 400 C a FeNi crystalline phase appears as 22 vol.% inside the host amorphous matrix and the resulting composite structure remains stable over 3 h at temperature. The hydrogen permeation at 400 C of the partially crystalline material is similar to the fully amorphous material near 5 x 10{sup -9} mol H{sub 2}/m s Pa{sup 1/2}, while ambient temperature electrochemical permeation at 25 C revealed an order of magnitude decrease in the permeation of partially crystalline materials due to differences in the amorphous versus crystalline phase activation energy for hydrogen permeation.

Brinkman, K.; Su, D.; Fox, E.; Korinko, P.; Missimer, D.; Adams, T.

2011-08-15T23:59:59.000Z

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361

Surface structures of Al-Pd-Mn and Al-Cu-Fe icosahedral quasicrystals  

SciTech Connect (OSTI)

In this dissertation, the author reports on the surface structure of i-Al-Pd-Mn twofold, threefold, fivefold and i-Al-Cu-Fe fivefold surfaces. The LEED studies indicate the existence of two distinct stages in the regrowth of all four surfaces after Ar{sup +} sputtering. In the first stage, upon annealing at relatively low temperature: 500K--800K (depending on different surfaces), a cubic phase appears. The cubic LEED patterns transform irreversibly to unreconstructed quasicrystalline patterns upon annealing to higher temperatures, indicating that the cubic overlayers are metastable. Based upon the data for three chemically-identical, but symmetrically-inequivalent surfaces, a model is developed for the relation between the cubic overlayers and the quasicrystalline substrate. The model is based upon the related symmetries of cubic close-packed and icosahedral-packed materials. These results may be general among Al-rich, icosahedral materials. STM study of Al-Pd-Mn fivefold surface shows that terrace-step-kink structures start to form on the surface after annealing above 700K. Large, atomic ally-flat terraces were formed after annealing at 900K. Fine structures with fivefold icosahedral symmetry were found on those terraces. Data analysis and comparison of the STM images and structure model of icosahedral Al-Pd-Mn suggest that the fine structures in the STM images may be the pseudo Mackay (PMI) clusters which are the structure units of the structure model. Based upon his results, he can conclude that quasicrystalline structures are the stable structures of quasicrystal surfaces. In other words, quasicrystalline structures extend from the bulk to the surface. As a result of the effort reported in this dissertation, he believes that he has increased his understanding of the surface structure of icosahedral quasicrystals to a new level.

Shen, Z.

1999-02-12T23:59:59.000Z

362

Structure and phase transformation behaviour of electroless Ni-P composite coatings  

SciTech Connect (OSTI)

This paper addresses the structural characteristics and phase transformation behaviour of plain electroless Ni-P coating and electroless Ni-P-Si{sub 3}N{sub 4}, Ni-P-CeO{sub 2} and Ni-P-TiO{sub 2} composite coatings. The X-ray diffraction patterns of electroless Ni-P-Si{sub 3}N{sub 4}, Ni-P-CeO{sub 2} and Ni-P-TiO{sub 2} composite coatings are very similar to that of plain electroless Ni-P coating, both in as plated and heat-treated conditions. Selected area electron diffraction (SAED) patterns obtained on the Ni-P matrix of Ni-P-Si{sub 3}N{sub 4}, Ni-P-CeO{sub 2} and Ni-P-TiO{sub 2} composite coatings exhibit diffuse ring patterns resembling the one obtained for plain electroless Ni-P coating. Phase transformation behaviour studied by differential scanning calorimetry (DSC) indicates that the variation in crystallization temperature and the energy evolved during crystallization of plain electroless Ni-P coating and electroless Ni-P-Si{sub 3}N{sub 4}, Ni-P-CeO{sub 2} and Ni-P-TiO{sub 2} composite coatings is not significant. The study concludes that incorporation of Si{sub 3}N{sub 4}, CeO{sub 2} and TiO{sub 2} particles in the Ni-P matrix does not have any influence on the structure and phase transformation behaviour of electroless Ni-P coatings.

Balaraju, J.N. [Surface Engineering Division, National Aerospace Laboratory, Bangalore 560017 (India)]. E-mail: jnbalraj@css.nal.res.in; Narayanan, T.S.N. Sankara [National Metallurgical Laboratory, Madras Centre, CSIR Complex Taramani, Chennai 600113 (India)]. E-mail: tsnsn@rediffmail.com; Seshadri, S.K. [Department of Metallurgical Engineering, Indian Institute of Technology Madras, Chennai 600036 (India)]. E-mail: sks@iitm.ac.in

2006-04-13T23:59:59.000Z

363

Travelling fronts of the CO oxidation on Pd(111) with coverage-dependent diffusion  

SciTech Connect (OSTI)

In this work, we study a surface reaction on Pd(111) crystals under ultra-high-vacuum conditions that can be modeled by two coupled reaction-diffusion equations. In the bistable regime, the reaction exhibits travelling fronts that can be observed experimentally using photo electron emission microscopy. The spatial profile of the fronts reveals a coverage-dependent diffusivity for one of the species. We propose a method to solve the nonlinear eigenvalue problem and compute the direction and the speed of the fronts based on a geometrical construction in phase-space. This method successfully captures the dependence of the speed on control parameters and diffusivities.

Cisternas, Jaime, E-mail: jecisternas@miuandes.cl [Facultad de Ingeniería y Ciencias Aplicadas, Universidad de los Andes, Monseñor Alvaro del Portillo 12455, Las Condes, Santiago (Chile); Karpitschka, Stefan [Physics of Fluids, University of Twente, Drienerlolaan 5, 7522 NB Enschede (Netherlands); Wehner, Stefan [Institut für Integrierte Naturwissenschaften - Physik, Universität Koblenz-Landau, 56070 Koblenz (Germany)

2014-10-28T23:59:59.000Z

364

Enhanced quantum coherence in graphene caused by Pd cluster deposition and its zero-temperature saturation  

E-Print Network [OSTI]

We report on the unexpected increase in the dephasing lengths of a graphene sheet caused by the deposition of Pd nanoclusters, as demonstrated by weak localization measurements. The dephasing lengths reached saturated values at low temperatures, which was essentially related to zero-temperature dephasing. The temperature-dependent dephasing was described by 1/(TlnT) and the saturated dephasing period was found to depend on {\\sigma}le, revealing disorder-induced zero-temperature dephasing in our defect-enriched graphene. Taken together with our theoretical calculations, we suggest that competition between surface scattering and charge transfer leads to the improvement of quantum coherence in cluster-decorated graphene.

Yuyuan Qin; Junhao Han; Guoping Guo; Zhaoguo Li; Yongping Du; You Song; Li Pi; Xuefeng Wang; Xiangang Wan; Wei Ning; Feng Miao; Xinran Wang; Zhe Qu; Jianfeng Zhou; Jianguo Wan; Min Han; Fengqi Song; Baigeng Wang; Guanghou Wang

2014-02-14T23:59:59.000Z

365

Ultra-low loading Pt nanocatalysts prepared by atomic layer deposition on carbon aerogels  

SciTech Connect (OSTI)

Using atomic layer deposition (ALD), we show that Pt nanoparticles can be deposited on the inner surfaces of carbon aerogels (CA). The resultant Pt-loaded materials exhibit high catalytic activity for the oxidation of CO even at loading levels as low as {approx}0.05 mg Pt/cm{sup 2}. We observe a conversion efficiency of nearly 100% in the temperatures range 150-250 C, and the total conversion rate seems to be only limited by the thermal stability of our CA support in ambient oxygen. Our ALD approach described here is universal in nature, and can be applied to the design of new catalytic materials for a variety of applications, including fuel cells, hydrogen storage, pollution control, green chemistry, and liquid fuel production.

King, J S; Wittstock, A; Biener, J; Kucheyev, S O; Wang, Y M; Baumann, T F; Giri, S; Hamza, A V; Baeumer, M; Bent, S F

2008-04-21T23:59:59.000Z

366

Measuring size dependent electrical properties from nanoneedle structures: Pt/ZnO Schottky diodes  

SciTech Connect (OSTI)

This work reports the fabrication and testing of nanoneedle devices with well-defined interfaces that are amenable to a variety of structural and electrical characterization, including transmission electron microscopy. Single Pt/ZnO nanoneedle Schottky diodes were fabricated by a top down method using a combination of electro-polishing, sputtering, and focused ion beam milling. The resulting structures contained nanoscale planar heterojunctions with low ideality factors, the dimensions of which were tuned to study size-dependent electrical properties. The diameter dependence of the Pt/ZnO diode barrier height is explained by a joule heating effect and/or electronic inhomogeneity in the Pt/ZnO contact area.

Mao, Shimin; Anderson, Daniel D. [Department of Materials Science and Engineering, University of Illinois at Urbana-Champaign, Urbana, Illinois 61801 (United States); Shang, Tao [Frederick Seitz Materials Research Laboratory, University of Illinois at Urbana-Champaign, Urbana, Illinois 61801 (United States); Park, Byoungnam [Department of Materials Science and Engineering, University of Illinois at Urbana-Champaign, Urbana, Illinois 61801 (United States); Department of Materials Science and Engineering, Hongik University, 72-1 Sangsu-dong, Mapo-gu, Seoul 121-791 (Korea, Republic of); Dillon, Shen J., E-mail: sdillon@illinois.edu [Department of Materials Science and Engineering, University of Illinois at Urbana-Champaign, Urbana, Illinois 61801 (United States); Frederick Seitz Materials Research Laboratory, University of Illinois at Urbana-Champaign, Urbana, Illinois 61801 (United States)

2014-04-14T23:59:59.000Z

367

Swift heavy ion irradiation of Pt nanocrystals: II. Structural changes and H desorption  

SciTech Connect (OSTI)

The structural properties and H desorption from embedded Pt nanocrystals (NCs) following irradiation with swift heavy ions were investigated as a function of energy and fluence. From x-ray absorption near-edge spectroscopy analysis, Pt-H bonding was identified in NCs annealed in a forming gas (95% N{sub 2} + 5% H{sub 2}) ambient. The H content decreased upon irradiation and the desorption process was NC-size dependent such that larger NCs required a higher fluence to achieve a H-free state. Pt-H bonding and NC dissolution both perturbed the NC structural parameters (coordination number, bond-length and mean-square relative displacement) as determined with extended x-ray absorption fine structure measurements.

Giulian, R.; Araujo, L.L.; Kluth, P.; Sprouster, D.J.; Schnohr, C.S.; Byrne, A.P.; Ridgway, M.C. (ANU)

2014-09-24T23:59:59.000Z

368

Evaluation of the dose distribution for prostate implants using various {sup 125}I and {sup 103}Pd sources  

SciTech Connect (OSTI)

Recently, several different models of {sup 125}I and {sup 103}Pd brachytherapy sources have been introduced in order to meet the increasing demand for prostate seed implants. These sources have different internal structures; hence, their TG-43 dosimetric parameters are not the same. In this study, the effects of the dosimetric differences among the sources on their clinical applications were evaluated. The quantitative and qualitative evaluations were performed by comparisons of dose distributions and dose volume histograms of prostate implants calculated for various designs of {sup 125}I and {sup 103}Pd sources. These comparisons were made for an identical implant scheme with the same number of seeds for each source. The results were compared with the Amersham model 6711 seed for {sup 125}I and the Theragenics model 200 seed for {sup 103}Pd using the same implant scheme.

Meigooni, Ali S.; Luerman, Christine M.; Sowards, Keith T. [Department of Radiation Medicine, North Shore University Hospital, Manhasset, New York 11030 and Department of Radiation Medicine, University of Kentucky Medical Center, Lexington, Kentucky 40536 (United States); Department of Radiation Medicine, University of Kentucky Medical Center, Lexington, Kentucky 40536 (United States); James Graham Brown Cancer Center, University of Louisville, Louisville, Kentucky 40202 (United States)

2009-04-15T23:59:59.000Z

369

Restructuring of hex-Pt(100) under CO gas environments: formation of 2-D nanoclusters  

SciTech Connect (OSTI)

The atomic-scale restructuring of hex-Pt(100) induced by carbon monoxide with a wide pressure range was studied with a newly designed chamber-in-chamber high-pressure STM and theoretical calculations. Both experimental and DFT calculation results show that CO molecules are bound to Pt nanoclusters through a tilted on-top configuration with a separation of {approx}3.7-4.1 {angstrom}. The phenomenon of restructuring of metal catalyst surfaces induced by adsorption, and in particular the formation of small metallic clusters suggests the importance of studying structures of catalyst surfaces under high pressure conditions for understanding catalytic mechanisms.

Tao, Feng; Dag, Sefa; Wang, Lin-Wang; Liu, Zhi; Butcher, Derek; Salmeron, Miquel; Somorjai, Gabor A.

2009-04-24T23:59:59.000Z

370

Nanostructured electrocatalyst for fuel cells : silica templated synthesis of Pt/C composites.  

SciTech Connect (OSTI)

Platinum-based electrocatalysts are currently required for state-of-the-art fuel cells and represent a significant portion of the overall fuel cell cost. If fuel cell technology is to become competitive with other energy conversion technologies, improve the utilization of precious metal catalysts is essential. A primary focus of this work is on creating enhanced nanostructured materials which improve precious-metal utilization. The goal is to engineer superior electrocatalytic materials through the synthesis, development and investigation of novel templated open frame structures synthesized in an aerosol-based approach. Bulk templating methods for both Pt/C and Pt-Ru composites are evaluated in this study and are found to be limited due to the fact that the nanostructure is not maintained throughout the entire sample. Therefore, an accurate examination of structural effects was previously impossible. An aerosol-based templating method of synthesizing nanostructured Pt-Ru electrocatalysts has been developed wherein the effects of structure can be related to electrocatalytic performance. The aerosol-based templating method developed in this work is extremely versatile as it can be conveniently modified to synthesize alternative materials for other systems. The synthesis method was able to be extended to nanostructured Pt-Sn for ethanol oxidation in alkaline media. Nanostructured Pt-Sn electrocatalysts were evaluated in a unique approach tailored to electrocatalytic studies in alkaline media. At low temperatures, nanostructured Pt-Sn electrocatalysts were found to have significantly higher ethanol oxidation activity than a comparable nanostructured Pt catalyst. At higher temperatures, the oxygen-containing species contribution likely provided by Sn is insignificant due to a more oxidized Pt surface. The importance of the surface coverage of oxygen-containing species in the reaction mechanism is established in these studies. The investigations in this work present original studies of anion exchange ionomers as entrapment materials for rotating disc electrode (RDE) studies in alkaline media. Their significance is linked to the development of membrane electrode assemblies (MEAs) with the same ionomer for a KOH-free alkaline fuel cell (AFC).

Stechel, Ellen Beth; Switzer, Elise E.; Fujimoto, Cy H.; Atanassov, Plamen Borissov; Cornelius, Christopher James; Hibbs, Michael R.

2007-09-01T23:59:59.000Z

371

Spin-wave excitation and propagation in microstructured waveguides of yttrium iron garnet/Pt bilayers  

SciTech Connect (OSTI)

We present an experimental study of spin-wave excitation and propagation in microstructured waveguides consisting of a 100?nm thick yttrium iron garnet/platinum (Pt) bilayer. The life time of the spin waves is found to be more than an order of magnitude higher than in comparably sized metallic structures, despite the fact that the Pt capping enhances the Gilbert damping. Utilizing microfocus Brillouin light scattering spectroscopy, we reveal the spin-wave mode structure for different excitation frequencies. An exponential spin-wave amplitude decay length of 31??m is observed which is a significant step towards low damping, insulator based micro-magnonics.

Pirro, P.; Chumak, A. V.; Lägel, B.; Leven, B.; Hillebrands, B. [Fachbereich Physik and Landesforschungszentrum OPTIMAS, Technische Universität Kaiserslautern, D-67663 Kaiserslautern (Germany)] [Fachbereich Physik and Landesforschungszentrum OPTIMAS, Technische Universität Kaiserslautern, D-67663 Kaiserslautern (Germany); Brächer, T. [Fachbereich Physik and Landesforschungszentrum OPTIMAS, Technische Universität Kaiserslautern, D-67663 Kaiserslautern (Germany) [Fachbereich Physik and Landesforschungszentrum OPTIMAS, Technische Universität Kaiserslautern, D-67663 Kaiserslautern (Germany); Graduate School Materials Science in Mainz, Gottlieb-Daimler-Strasse 47, D-67663 Kaiserslautern (Germany); Dubs, C.; Surzhenko, O.; Görnert, P. [Innovent e.V., Prüssingstraße 27B, 07745 Jena (Germany)] [Innovent e.V., Prüssingstraße 27B, 07745 Jena (Germany)

2014-01-06T23:59:59.000Z

372

Fractal Weyl laws for amplified states in PT-symmetric resonators  

E-Print Network [OSTI]

We find that in nonhermitian PT-symmetric systems (as realized in resonators with balanced absorption and amplification), a mechanism based on quantum-to-classical correspondence reduces the occurrence of strongly amplified states. The reduction arises from semiclassically emerging hierarchical phase-space structures that are associated with the coupling of the amplifying and absorbing regions (forward and backward-trapped sets and their complements), and amounts to a generalization of the fractal Weyl law, earlier proposed for ballistically open systems. In the context of the recently introduced class of PT-symmetric laser-absorbers, this phenomenon reduces the number of states participating in the mode competition.

Christopher Birchall; Henning Schomerus

2012-08-10T23:59:59.000Z

373

Universal routes to spontaneous PT-symmetry breaking in non-Hermitian quantum systems  

SciTech Connect (OSTI)

PT-symmetric systems can have a real spectrum even when their Hamiltonian is non-Hermitian, but develop a complex spectrum when the degree of non-Hermiticity increases. Here we utilize random-matrix theory to show that this spontaneous PT-symmetry breaking can occur via two distinct mechanisms, whose predominance is associated to different universality classes. Present optical experiments fall into the orthogonal class, where symmetry-induced level crossings render the characteristic absorption rate independent of the coupling strength between the symmetry-related parts of the system.

Schomerus, Henning [Department of Physics, Lancaster University, Lancaster LA1 4YB (United Kingdom)

2011-03-15T23:59:59.000Z

374

Scattering of linear and nonlinear waves in a waveguide array with a PT-symmetric defect  

SciTech Connect (OSTI)

We study the scattering of linear and nonlinear waves in a long waveguide array with a parity-time (PT)-symmetric defect created by two waveguides with balanced gain and loss. We present exact solutions for the scattering of linear waves on such a defect, and then demonstrate numerically that the linear theory can describe, with a good accuracy, the soliton scattering in the case of weak nonlinearity. We reveal that the reflected and transmitted linear and nonlinear waves can be amplified substantially after interaction with the PT-symmetric defect thus allowing an active control of the wave scattering in the array.

Dmitriev, Sergey V.; Suchkov, Sergey V. [Institute for Metals Superplasticity Problems, Russian Academy of Science, Ufa RU-450001 (Russian Federation); Sukhorukov, Andrey A.; Kivshar, Yuri S. [Nonlinear Physics Centre, Research School of Physics and Engineering,Australian National University, Canberra, ACT 0200 (Australia)

2011-07-15T23:59:59.000Z

375

Ag-Pd-Cu alloy inserted transparent indium tin oxide electrodes for organic solar cells  

SciTech Connect (OSTI)

The authors report on the characteristics of Ag-Pd-Cu (APC) alloy-inserted indium tin oxide (ITO) films sputtered on a glass substrate at room temperature for application as transparent anodes in organic solar cells (OSCs). The effect of the APC interlayer thickness on the electrical, optical, structural, and morphological properties of the ITO/APC/ITO multilayer were investigated and compared to those of ITO/Ag/ITO multilayer electrodes. At the optimized APC thickness of 8?nm, the ITO/APC/ITO multilayer exhibited a resistivity of 8.55?×?10{sup ?5} ? cm, an optical transmittance of 82.63%, and a figure-of-merit value of 13.54?×?10{sup ?3} ?{sup ?1}, comparable to those of the ITO/Ag/ITO multilayer. Unlike the ITO/Ag/ITO multilayer, agglomeration of the metal interlayer was effectively relieved with APC interlayer due to existence of Pd and Cu elements in the thin region of the APC interlayer. The OSCs fabricated on the ITO/APC/ITO multilayer showed higher power conversion efficiency than that of OSCs prepared on the ITO/Ag/ITO multilayer below 10?nm due to the flatness of the APC layer. The improved performance of the OSCs with ITO/APC/ITO multilayer electrodes indicates that the APC alloy interlayer prevents the agglomeration of the Ag-based metal interlayer and can decrease the thickness of the metal interlayer in the oxide-metal-oxide multilayer of high-performance OSCs.

Kim, Hyo-Joong; Seo, Ki-Won; Kim, Han-Ki, E-mail: imdlhkkim@khu.ac.kr [Department of Advanced Materials Engineering for Information and Electronics, Kyung-Hee University, 1 Seocheon-dong, Yongin-si, Gyeonggi-do 446-701 (Korea, Republic of); Noh, Yong-Jin; Na, Seok-In [Graduate School of Flexible and Printable Electronics, Chonbuk National University, 664-14, Deokjin-dong, Jeonju-si, Jeollabuk-do 561-756 (Korea, Republic of)

2014-09-01T23:59:59.000Z

376

Anomalous codeposition of Fe-Ni alloys and Fe-Ni-SiO{sub 2} composites under potentiostatic conditions: Experimental study and mathematical model  

SciTech Connect (OSTI)

A mathematical model has been developed to describe the electrodeposition of Fe-Ni alloys and Fe-Ni-SiO{sub 2} composites under potentiostatic conditions. This model can be used to predict the polarization behavior, partial current densities, and alloy composition of each of the components as a function of the applied potential. Fe-Ni-SiO{sub 2} samples were deposited on platinum rotating disk electrodes from sulfate electrolytes under potentiostatic conditions, and the results obtained were compared to the model. The model predictions were found to agree well with the experimental observations for the Fe-Ni and Fe-Ni-SiO{sub 2} systems.

Ramasubramanian, M.; Popova, S.N.; Popov, B.N.; White, R.E. [Univ. of South Carolina, Columbia, SC (United States). Dept. of Chemical Engineering; Yin, K.M. [Yuan-Ze Inst. of Tech., Taoyuan (Taiwan, Province of China)

1996-07-01T23:59:59.000Z

377

Modified Ni-Cu catalysts for ethanol steam reforming  

SciTech Connect (OSTI)

Three Ni-Cu catalysts, having different Cu content, supported on ?-alumina were synthesized by wet co-impregnation method, characterized and tested in the ethanol steam reforming (ESR) reaction. The catalysts were characterized for determination of: total surface area and porosity (N{sub 2} adsorption - desorption using BET and Dollimer Heal methods), Ni surface area (hydrogen chemisorption), crystallinity and Ni crystallites size (X-Ray Diffraction), type of catalytic active centers (Hydrogen Temperature Programmed Reduction). Total surface area and Ni crystallites size are not significantly influenced by the addition of Cu, while Ni surface area is drastically diminished by increasing of Cu concentration. Steam reforming experiments were performed at atmospheric pressure, temperature range 150-350°C, and ethanol - water molar ration of 1 at 30, using Ar as carrier gas. Ethanol conversion and hydrogen production increase by the addition of Cu. At 350°C there is a direct connection between hydrogen production and Cu concentration. Catalysts deactivation in 24h time on stream was studied by Transmission Electron Microscopy (TEM) and temperature-programmed reduction (TPR) on used catalysts. Coke deposition was observed at all studied temperatures; at 150°C amorphous carbon was evidenced, while at 350°C crystalline, filamentous carbon is formed.

Dan, M.; Mihet, M.; Almasan, V.; Borodi, G. [National Institute for Research and Development of Isotopic and Molecular Technologies, 65-103 Donath Street, 400293, Cluj-Napoca (Romania)] [National Institute for Research and Development of Isotopic and Molecular Technologies, 65-103 Donath Street, 400293, Cluj-Napoca (Romania); Katona, G.; Muresan, L. [Univ. Babes Bolyai, Fac. Chem. and Chem. Eng.,11 Arany Janos, 400028, Cluj-Napoca (Romania)] [Univ. Babes Bolyai, Fac. Chem. and Chem. Eng.,11 Arany Janos, 400028, Cluj-Napoca (Romania); Lazar, M. D., E-mail: diana.lazar@itim-cj.ro [65-103 Donath Street (Romania)

2013-11-13T23:59:59.000Z

378

Atomistic modeling of the directed-assembly of bimetallic Pt-Ru nanoclusters on Ru(0001)-supported monolayer graphene  

E-Print Network [OSTI]

)-supported monolayer graphene Yong Han,1 Albert K. Engstfeld,2 R. Juergen Behm,2 and James W. Evans1,3,* 1 of Pt-Ru nanoclusters (NC's) by sequential deposition of Pt and Ru on a periodically rumpled graphene. The periodic variation of the adsorption energy across the graphene sheet directs the assembly of NC

Ulm, Universität

379

One-Step Synthesis of FePt Nanoparticles with Tunable Size Min Chen,, J. P. Liu, and Shouheng Sun*,  

E-Print Network [OSTI]

One-Step Synthesis of FePt Nanoparticles with Tunable Size Min Chen,, J. P. Liu, and Shouheng SunPt is coated over the seeds. Although size distribution of the particles prepared from all these methods can of the stabilizers and metal precursors, heating rate, heating temperature, and heating duration. Further, core

Liu, J. Ping

380

The Structure-Sensitivity of nHeptane Dehydrocyclization on Pt/ SiO2 Model Catalysts  

E-Print Network [OSTI]

on the nanoparticles are also compared with results obtained on Pt(100) and Pt(110) single crystals, which were run from the underlying silica support. INTRODUCTION Heterogeneous platinum catalysts often produce,3 Formation of aromatics are of particular interest to both industrial and academic communities since

Goodman, Wayne

Note: This page contains sample records for the topic "ni pd pt" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
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381

Oxygen-assisted room-temperature deposition of CoPt3 films with perpendicular magnetic anisotropy  

E-Print Network [OSTI]

Oxygen-assisted room-temperature deposition of CoPt3 films with perpendicular magnetic anisotropy B Jolla, California 92093 Received 23 July 2002; accepted 30 September 2002 Trace amounts of oxygen CoPt3 grown by vapor deposition at or slightly above room temperature. Oxygen is known to act

Hellman, Frances

382

TpPt(IV)Me(H)2 Forms a -CH4 Complex That Is Kinetically Resistant to Methane Liberation  

E-Print Network [OSTI]

TpPt(IV)Me(H)2 Forms a -CH4 Complex That Is Kinetically Resistant to Methane Liberation H demonstra- tion that methane can be catalytically activated by an organometallic complex of Pt(II).2 report that although 1 has a very high energy barrier for the liberation of methane, it readily forms

Keinan, Ehud

383

Nano Res. 2011, 4(8): 780787780 Synthesis of Monodisperse CoPt3 Nanocrystals and Their  

E-Print Network [OSTI]

reduction of platinum(II) acetylacetonate (Pt(acac)2) and decomposition of Co2(CO)8 in organic solvents [24 structure. Measurement of the field emission properties of boron nanowire films showed that the boron nanowires have good field emission characteristics. KEYWORDS CoPt3 nanoparticles, catalytic behavior, boron

Gao, Hongjun

384

Hydrogenation of CO on Pd-Fe/. gamma. -Al/sub 2/O/sub 3/ catalysts  

SciTech Connect (OSTI)

A study has been made of CO hydrogenation on 5% Pd-Fe/..gamma..-Al/sub 2/O/sub 3/ catalysts with various contents of iron. It has been shown that the introduction of iron into the composition of the palladium catalyst reduces the quantity of chemisorbed hydrogen and carbon monoxide and lowers the activity in CO hydrogenation. The observed effects are related to the formation of cationic states of the metals and heteronuclear Pd-Fe clusters, which have little activity in processes of adsorption and catalysis.

Zakumbaeva, G.D.; Dagirov, T.S.; Dostiyarov, A.M.; Kuanyshev, A.Sh.; Naidin, V.A.; Vozdvizhenskii, V.F.

1986-09-01T23:59:59.000Z

385

Comparative study of the alloying effect on the initial oxidation of Cu-Au(100) and Cu-Pt(100)  

SciTech Connect (OSTI)

Using in situ transmission electron microscopy, we show that the oxidation of the Cu-Au(100) results in the formation of Cu{sub 2}O islands that deeply embed into the Cu-Au substrate while the oxidation of the Cu-Pt(100) leads to the formation of Cu{sub 2}O islands that highly protrude above the Cu-Pt substrate. Their difference is attributed to the different mobilities of Pt and Au in the Cu base alloys for which the sluggish mobility of Pt in Cu results in trapped Pt atoms at the oxide/alloy interface while the faster mobility of Au in Cu leads to enhanced rehomogenization of the alloy composition.

Luo, Langli; Zhou, Guangwen, E-mail: gzhou@binghamton.edu [Department of Mechanical Engineering and Multidisciplinary Program in Materials Science and Engineering, State University of New York, Binghamton, New York 13902 (United States); Kang, Yihong [Department of Mechanical Engineering and Materials Science, University of Pittsburgh, Pittsburgh, Pennsylvania 15261 (United States); Yang, Judith C. [Department of Chemical and Petroleum Engineering, University of Pittsburgh, Pittsburgh, Pennsylvania 15261 (United States); Su, Dong; Stach, Eric A. [Center for Functional Nanomaterials, Brookhaven National Laboratory, Upton, New York 11973 (United States)

2014-03-24T23:59:59.000Z

386

Excited-state properties of platinum(II) complexes containing biphenyl as a ligand: Complexes of the type [(bph)PtL[sub 2  

SciTech Connect (OSTI)

The preparation, physical properties, and photophysical properties of [Pt(bph)(C[sub 2]H[sub 5])[sub 2]S][sub 2], [Pt(bph)(CH[sub 3]CN)[sub 2

Blanton, C.B.; Murtaza, Z.; Shaver, R.J.; Rillema, D.P. (Univ. of North Carolina, Charlotte (United States))

1992-07-22T23:59:59.000Z

387

CO Oxidation over AuPd(100) from Ultrahigh Vacuum to Near-Atmospheric Pressures: CO Adsorption-Induced Surface Segregation and Reaction Kinetics  

E-Print Network [OSTI]

; ReVised Manuscript ReceiVed: July 7, 2009 Polarization-modulation infrared reflection absorptionCO Oxidation over AuPd(100) from Ultrahigh Vacuum to Near-Atmospheric Pressures: CO Adsorption vacuum (UHV) and near-atmospheric pressures.28 AuPd(100) is a good choice for the study since

Goodman, Wayne

388

Superconductivity in SrNi2P2 single crystals  

SciTech Connect (OSTI)

Heat capacity, magnetic susceptibility, and resistivity of SrNi{sub 2}P{sub 2} single crystals are presented, illustrating the structural transition at 325 K, and bulk superconductivity at 1.4 K. The magnitude of {Tc}, fits to the heat capacity data, the small upper critical field H{sub c2} = 390 Oe, and {kappa} = 2.1 suggests a conventional fully gapped superconductor. With applied pressure we find that superconductivity persists into the so-called 'collapsed tetragonal' phase, although the transition temperature is monotonically suppressed with increasing pressure. This argues that reduced dimensionality can be a mechanism for increasing the transition temperatures of layered NiP, as well as layered FeAs and NiAs, superconductors.

Ronning, Filip [Los Alamos National Laboratory; Bauer, Eric D [Los Alamos National Laboratory; Park, Tuscon [Los Alamos National Laboratory; Thompson, Joe D [Los Alamos National Laboratory

2009-01-01T23:59:59.000Z

389

Electrodeposition and corrosion resistance of Ni-W-B coatings  

SciTech Connect (OSTI)

A ternary nickel-base alloy Ni-W-B has been developed for surface corrosion and wear resistance to replace chromium plating, which uses environmentally hazardous solutions. The deposition conditions used an alkaline bath and insoluble anodes. The as-deposited alloy typically contains 40 wt% W and 1 wt% B and has an amorphous or partially amorphous structure. These deposits compare favorably with hexavalent chromium deposits in throwing power, color uniformity, and reflectivity. The corrosion resistance of Ni-W-B alloy was compared with hexavalent chromium and electroless nickel deposits in a variety of acids, including hydrochloric, sulfuric, fluoroboric, and phosphoric. In all cases, best results were obtained with the Ni-W-B deposits.

Steffani, C.P.; Dini, J.W. [Lawrence Livermore National Lab., CA (United States). Manufacturing and Materials Engineering Div.; Groza, J.R.; Palazoglu, A. [Univ. of California, Davis, CA (United States). Dept. of Chemical Engineering and Materials Science

1997-08-01T23:59:59.000Z

390

Bimetallic Fe-Ni Oxygen Carriers for Chemical Looping Combustion  

SciTech Connect (OSTI)

The relative abundance, low cost, and low toxicity of iron make Fe-based oxygen carriers of great interest for chemical looping combustion (CLC), an emerging technology for clean and efficient combustion of fossil and renewable fuels. However, Fe also shows much lower reactivity than other metals (such as Ni and Cu). Here, we demonstrate strong improvement of Fe-based carriers by alloying the metal phase with Ni. Through a combination of carrier synthesis and characterization with thermogravimetric and fixed-bed reactor studies, we demonstrate that the addition of Ni results in a significant enhancement in activity as well as an increase in selectivity for total oxidation. Furthermore, comparing alumina and ceria as support materials highlights the fact that reducible supports can result in a strong increase in oxygen carrier utilization.

Bhavsar, Saurabh; Veser, Goetz

2013-11-06T23:59:59.000Z

391

Hydrotreatment of Athabasca bitumen derived gas oil over Ni-Mo, Ni-W, and Co-Mo catalysts  

SciTech Connect (OSTI)

The hydrotreatment of Athabasca bitumen derived heavy gas oil containing 4.08% S and 0.49% N was carried out in a trickle bed reactor over Ni-W, Ni-Mo, and Co-Mo catalysts supported on zeolite-alumina-silica at 623-698 K, LHSV of 1-4, gas flow rate 890 m[sup 3][sub H2]/m[sup 3][sub oil] (5,000 sef/bbl), and pressure of 6.89 MPa. Analyses for viscosity, density, aniline point, ASTM mid boiling point distillation, C/H ratio, and percentage of N and S in the final product were carried out to characterize the product oil. The amounts of N and S removed indicated the hydrodenitrogenation and hydrodesulfurization activity of the catalysts. Results of zeolite-alumina-silica-supported catalysts are compared to those obtained with commercially available Ni-Mo, Ni-W, and Co-Mo on [gamma]-alumina. Ni-Mo supported on zeolite-alumina-silica was most active and could remove as much as 99 % S and 89% N present in the oil at 698 K. The data for HDN and HDS fitted the pseudo first order model. The kinetic model is described in detail.

Diaz-Real, R.A.; Mann, R.S.; Sambi, I.S. (Univ. of Ottawa, Ontario (Canada). Dept. of Chemical Engineering)

1993-07-01T23:59:59.000Z

392

Preparation of Pt deposited nanotubular TiO{sub 2} as cathodes for enhanced photoelectrochemical hydrogen production using seawater electrolytes  

SciTech Connect (OSTI)

The purpose of this study was to develop effective cathodes to increase the production of hydrogen and use the seawater, an abundant resource in the earth as the electrolyte in photoelectrochemical systems. In order to fabricate the Pt/TiO{sub 2} cathodes, various contents of the Pt precursor (0-0.4 wt%) deposited by the electrodeposition method were used. On the basis of the hydrogen evolution rate, 0.2 wt% Pt/TiO{sub 2} was observed to exhibit the best performance among the various Pt/TiO{sub 2} cathodes with the natural seawater and two concentrated seawater electrolytes obtained from single (nanofiltration) and combined membrane (nanofiltration and reverse osmosis) processes. The surface characterizations exhibited that crystal structures and morphological properties of Pt and TiO{sub 2} found the results of XRD pattern and SEM/TEM images, respectively. - Graphical abstract: On the basis of photoelectrochemical hydrogen production, 0.2 wt% Pt/TiO{sub 2} was observed to exhibit the best performance among the various Pt/TIO{sub 2} cathodes with natural seawater. In comparison of hydrogen evolution rate with various seawater electrolytes, 0.2 wt% Pt/TiO{sub 2} was found to show the better performance as cathode with the concentrated seawater electrolytes obtained from membrane. Highlights: > Pt deposited TiO{sub 2} electrodes are used as cathode in PEC H{sub 2} production. > Natural and concentrated seawater by membranes are used as electrolytes in PEC. > Pt/TiO{sub 2} shows a good performance as cathode with seawater electrolytes. > H{sub 2} evolution rate increases with more concentrated seawater electrolyte. > Highly saline seawater is useful resource for H{sub 2} production.

Nam, Wonsik [Korea Institute of Energy Research, New and Renewable Energy Research Division, Hydrogen Energy Research Center, 71-2 Jang-dong, Yuseong-gu, Daejeon 305-343 (Korea, Republic of); Korea University of Technology and Education, Department of Applied Chemical Engineering, 1800 Chungjeollo, Byeongcheon-myun, Chungnam 330-708 (Korea, Republic of); Oh, Seichang [Korea Institute of Energy Research, New and Renewable Energy Research Division, Hydrogen Energy Research Center, 71-2 Jang-dong, Yuseong-gu, Daejeon 305-343 (Korea, Republic of); Yonsei University, Department of Chemical and Biomolecular Engineering, 134 Shinchon-dong, Seodaemun-gu, Seoul 120-749 (Korea, Republic of); Joo, Hyunku [Korea Institute of Energy Research, New and Renewable Energy Research Division, Hydrogen Energy Research Center, 71-2 Jang-dong, Yuseong-gu, Daejeon 305-343 (Korea, Republic of); Yoon, Jaekyung, E-mail: jyoon@kier.re.kr [Korea Institute of Energy Research, New and Renewable Energy Research Division, Hydrogen Energy Research Center, 71-2 Jang-dong, Yuseong-gu, Daejeon 305-343 (Korea, Republic of)

2011-11-15T23:59:59.000Z

393

Genesis and evolution of surface species during Pt atomic layer deposition on oxide supports characterized by in-situ XAFS analysis and water-gas shift reaction.  

SciTech Connect (OSTI)

Platinum atomic layer deposition (ALD) using MeCpPtMe{sub 3} was employed to prepare high loadings of uniform-sized, 1-2 nm Pt nanoparticles on high surface area Al{sub 2}O{sub 3}, TiO{sub 2}, and SrTiO{sub 3} supports. X-ray absorption fine structure was utilized to monitor the changes in the Pt species during each step of the synthesis. The temperature, precursor exposure time, treatment gas, and number of ALD cycles were found to affect the Pt particle size and density. Lower-temperature MeCpPtMe{sub 3} adsorption yielded smaller particles due to reduced thermal decomposition. A 300 C air treatment of the adsorbed MeCpPtMe{sub 3} leads to PtO. In subsequent ALD cycles, the MeCpPtMe{sub 3} reduces the PtO to metallic Pt in the ratio of one precursor molecule per PtO. A 200 C H{sub 2} treatment of the adsorbed MeCpPtMe{sub 3} leads to the formation of 1-2 nm, metallic Pt nanoparticles. During subsequent ALD cycles, MeCpPtMe{sub 3} adsorbs on the support, which, upon reduction, yields additional Pt nanoparticles with a minimal increase in size of the previously formed nanoparticles. The catalysts produced by ALD had identical water-gas shift reaction rates and reaction kinetics to those of Pt catalysts prepared by standard solution methods. ALD synthesis of catalytic nanoparticles is an attractive method for preparing novel model and practical catalysts.

Setthapun, W.; Williams, W.; Kim, S.; Feng, H.; Elam, J.; Rabuffetti, F.; Poeppelmeier, K.; Stair, P.; Stach, E.; Ribeiro, F.; Miller, J.; Marshall, C.; Northwestern Univ.; Purdue Univ.

2010-06-03T23:59:59.000Z

394

High Power Impulse Magnetron Sputtering deposition of Pt inside fuel cell electrodes  

E-Print Network [OSTI]

1 High Power Impulse Magnetron Sputtering deposition of Pt inside fuel cell electrodes S Cuynet1 as a cathode of a proton exchange membrane fuel cell. An increase of 80 % at 0.65 V of the PEMFC power density) 272001" #12;2 Proton exchange membrane fuel cells (PEMFC) have the potential to provide

Paris-Sud XI, Université de

395

Applied Catalysis B: Environmental 37 (2002) 1725 Selective CO oxidation over Pt/alumina catalysts  

E-Print Network [OSTI]

). methanol or partial oxidation of gasoline followed by water gas shift reaction will produce a gas stream al. [11] studied the kinetics of the selective CO oxidation in H2-rich gas on Pt/Al2O3 in detail rich feed gas to proton exchange membrane (PEM) fuel cells can poison the platinum anode electrode

Gulari, Erdogan

396

Metal-assisted hydrogen storage on Pt-decorated single-walled carbon nanohorns  

E-Print Network [OSTI]

Metal-assisted hydrogen storage on Pt-decorated single-walled carbon nanohorns Yun Liu a,b,*, Craig nanoparticles can assist in enhanced hydrogen storage on high-surface area supports are still under debate. Experimental mea- surements of metal-assisted hydrogen storage have been hampered by inaccurate estima- tion

Geohegan, David B.

397

Unidirectional Pt silicide nanowires grown on vicinal Si,,100... Do Kyung Lim,1  

E-Print Network [OSTI]

this limitation, we focused on noble metal silicide NWs be- cause noble metals rarely form insulating metal oxideUnidirectional Pt silicide nanowires grown on vicinal Si,,100... Do Kyung Lim,1 Sung-Soo Bae,1. In particular, rare-earth silicide NWs on silicon surfaces have attracted in- terest as candidate nanostructures

Kim, Sehun

398

Effect of deposition and treatment conditions on growth of nanometer PtSi heterostructure  

E-Print Network [OSTI]

-X I. INTRODUCTION Transition metal silicides have received a great deal of attention due to their use in a number of devices.1­4 Platinum silicide PtSi is an important metal silicide which is widely of silicides are intensely affected by the deposition and technological parameters. It is also confirmed

Zheng, Yufeng

399

Low resistivity of Pt silicide nanowires measured using double-scanning-probe tunneling microscope  

E-Print Network [OSTI]

experimentally shown to be conductive.8­10 However, RE metal silicide NWs are easily oxidized, so that inert NWs similarly to RE metal silicide NWs.11 It is essential to study the electrical properties, especiallyLow resistivity of Pt silicide nanowires measured using double-scanning- probe tunneling microscope

Kim, Sehun

400

Body copy Arial 11pt black University of Birmingham opportunities for SMEs  

E-Print Network [OSTI]

Body copy ­ Arial 11pt black University of Birmingham opportunities for SMEs The University that of the individual employees; with the overall aim of improving long term profitability. Our services to SMEs internships and placements Student schemes cover a wide range of disciplines - technology, processing, finance

Birmingham, University of

Note: This page contains sample records for the topic "ni pd pt" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Predictions of the Pt8Ti Phase in Unexpected Systems Richard H. Taylor,,  

E-Print Network [OSTI]

Predictions of the Pt8Ti Phase in Unexpected Systems Richard H. Taylor,, Stefano CurtaroloVot 76100, Israel Received March 5, 2010; E-mail: gus.hart@gmail.com; stefano@duke.edu Abstract: The binary in the Rh-W system. A cluster-expansion-based Monte Carlo model reveals a relatively high order

Curtarolo, Stefano

402

Analysis of Pt/C electrode performance in a flowing-electrolyte alkaline fuel cell  

E-Print Network [OSTI]

Analysis of Pt/C electrode performance in a flowing- electrolyte alkaline fuel cell Fikile R 17 October 2011 Accepted 18 October 2011 Available online 12 November 2011 Keywords: Alkaline fuel cell Electrode characterization X-ray micro-computed tomography Microfluidic fuel cell Carbonates a b

Kenis, Paul J. A.

403

Plasma-assisted nitrogen doping of graphene-encapsulated Pt nanocrystals as efficient fuel cell  

E-Print Network [OSTI]

Plasma-assisted nitrogen doping of graphene- encapsulated Pt nanocrystals as efficient fuel cell, their ability to act as a relatively good fuel cell catalyst was confirmed. Furthermore, to further improve with hydrogen and oxygen intermediates to form the nal products,10 explaining their broad use in fuel cell

Tan, Weihong

404

Characterization of Pt/SiO2 Model Catalysts at UHV and Near Atmospheric Pressures  

E-Print Network [OSTI]

catalyst samples, prepared under UHV conditions in a contiguous high pressure reactor cell surface analysis with measurements on a Pt(110) single crystal for direct com- parison. CO desorption measurements and STM measure, turnover frequency (TOF, product molecules produced/site/s) is a standard metric used for comparison

Goodman, Wayne

405

Classical Trajectories of the Continuum States of the ${\\cal{PT}}$ symmetric Scarf II potential  

E-Print Network [OSTI]

We apply the factorization technique developed by Kuru et. al. [Ann. Phys. {\\bf 323} (2008) 413] to obtain the exact analytical classical trajectories and momenta of the continuum states of the non Hermitian but ${\\cal{PT}}$ symmetric Scarf II potential. In particular, we observe that the strange behaviour of the quantum version at the spectral singularity has an interesting classical analogue.

Anjana Sinha

2012-06-29T23:59:59.000Z

406

P0616-Nielsen Platinum Migration at the Pt/YSZ Interface  

E-Print Network [OSTI]

. The oxygen electrode on YSZ surfaces is studied at Pt micro-electrodes prepared by electrochemical etching polarization is confirmed, but furthermore, a very accentuated noise pattern is seen during cathodic step structures from the TPB. The formation of these may explain the observed noise and contribute

407

Correlating Catalytic Methanol Oxidation with the Structure and Oxidation State of Size-Selected Pt Nanoparticles  

E-Print Network [OSTI]

of this process is a limiting factor in the performance of direct methanol fuel cells, which produce electricityCorrelating Catalytic Methanol Oxidation with the Structure and Oxidation State of Size-Selected Pt nanoparticles (NPs) prepared by micelle encapsulation and supported on -Al2O3 during the oxidation of methanol

Kik, Pieter

408

Quasi-model-independent search for new high p(T) physics at D0  

E-Print Network [OSTI]

We apply a quasi-model-independent strategy ("Sleuth") to search for new high p(T) physics in approximate to 100 pb(-1) of p (p) over bar collisions at roots = 1.8 TeV collected by the D0 experiment during 1992-1990 at the ...

Baringer, Philip S.; Bean, Alice; Coppage, Don; Hebert, C.

2001-04-01T23:59:59.000Z

409

Sputter-Deposited Pt PEM Fuel Cell Electrodes: Particles vs M. D. Gasda,a  

E-Print Network [OSTI]

Sputter-Deposited Pt PEM Fuel Cell Electrodes: Particles vs Layers M. D. Gasda,a R. Teki,b T.-M. Lu as cathode electrodes in proton exchange membrane PEM fuel cells using Nafion 1135 membranes and Teflon, 2009. Published March 24, 2009. Polymer electrolyte membrane or proton exchange membrane PEM fuel cells

Gall, Daniel

410

Pt/CARBON XEROGEL CATALYSTS FOR PEM FUEL CELLS Nathalie JOBa  

E-Print Network [OSTI]

Pt/CARBON XEROGEL CATALYSTS FOR PEM FUEL CELLS Nathalie JOBa , Frédéric MAILLARDb , Jean of proton exchange membrane (PEM) fuel cells in order to decrease the mass transport limitations The catalytic layer configuration is a key-element in the design of PEM fuel cells [1]. Indeed, besides

Paris-Sud XI, Université de

411

Femtosecond Near-Infrared Laser Desorption of Multilayer Benzene on Pt{111}: A Molecular Newton's Cradle?  

E-Print Network [OSTI]

Femtosecond Near-Infrared Laser Desorption of Multilayer Benzene on Pt{111}: A Molecular Newton Recently, the intense near-infrared laser desorption of intact benzene molecules has been reported.1 Three, 1999; In Final Form: February 11, 2000 Velocity distributions resulting from the intense, near-IR laser

Levis, Robert J.

412

Oxide-supported PtCo alloy catalyst for intermediate temperature polymer electrolyte fuel cells  

E-Print Network [OSTI]

1 Oxide-supported PtCo alloy catalyst for intermediate temperature polymer electrolyte fuel cells reduction reaction in a polymer electrolyte fuel cell (PEMFC) operating between 80° and 110 °C at different, Fuel cells, Oxygen reduction reaction, Doped Ti-oxide support, Intermediate temperature

Boyer, Edmond

413

Core-Shell Assisted Bimetallic Assembly of Pt and Ru Nanoparticles by DNA Hybridization  

E-Print Network [OSTI]

We have discovered that the current protocols to assemble Au nanoparticles based on DNA hybridization do not work well with the small metal nanoparticles (e.g. 5 nm Au, 3.6 nm Pt and 3.2 nm Ru particles). Further investigations ...

Lee, Jim Yang

414

High coercivity CoCrPt films achieved by post-deposition rapid thermal annealing  

E-Print Network [OSTI]

layer, a CoCrPt mag- netic layer, a capping Mn diffusion layer, and a final CrTi oxidation protection conditions were stud- ied. II. EXPERIMENT All layers were deposited onto glass substrates by rf di- ode, and CrTi oxida- tion protection layer were all 200 Ã? thick. Post-deposition annealing was performed

Laughlin, David E.

415

Acceptability of Four Transformer Top-Oil Thermal Models: Pt. 2: Comparing Metrics  

E-Print Network [OSTI]

1 Acceptability of Four Transformer Top-Oil Thermal Models: Pt. 2: Comparing Metrics Lida Jauregui transformer top-oil thermal models are examined vis-à-vis training with measured data. Acceptability is unacceptable for model identification purposes. The linear top-oil model is acceptable for FOFA transformers

416

Studies of switching field and thermal energy barrier distributions in a FePt nanoparticle system  

E-Print Network [OSTI]

Studies of switching field and thermal energy barrier distributions in a FePt nanoparticle system X dependence of the thermal stability factor, the width of the thermal energy barrier distribution- ropy energy distribution and the interaction and the thermal energy barrier distribution determined

Laughlin, David E.

417

Piezospectroscopic study of substitutional Ni in ZnO  

SciTech Connect (OSTI)

The effect of uniaxial stress on the electronic {sup 3}T{sub 1}(F)?{sup 3}T{sub 2}(F) transitions of Ni{sup 2+} in ZnO at 4216, 4240, and 4247 cm{sup ?1} is investigated by means of Fourier transform IR absorption spectroscopy. A stress Hamiltonian is constructed which accounts for the behavior of these transitions under uniaxial stress. It is shown that the split pattern and polarization properties of these IR absorption lines are consistent with a dynamic Jahn-Teller effect in the {sup 3}T{sub 2}(F) state of Ni.

Lavrov, E. V.; Herklotz, F. [Technische Universität Dresden, 01062 Dresden (Germany); Kutin, Y. S. [Kazan Federal University, Federal Center of Shared Facilities, 420008 Kazan (Russian Federation)

2014-02-21T23:59:59.000Z

418

The Role of -Al2O3 Single Crystal Support to Pt Nanoparticles Construction Zhongfan Zhang*, Long Li*, Lin-lin Wang**, Sergio I. Sanchez***, Qi Wang****,  

E-Print Network [OSTI]

The Role of -Al2O3 Single Crystal Support to Pt Nanoparticles Construction Zhongfan Zhang*, Long Li the preparation of a model Pt/-Al2O3 catalyst and its characterization by a cross-sectional high-resolution electron microscopy (XHREM) method. Pt/-Al2O3 is the most important technologically-relevant heterogeneous

Frenkel, Anatoly

419

Due Friday, November 19, 2010. 1. (5 pt) Show that any finite commutative ring with no nonzero zero divisors is a  

E-Print Network [OSTI]

ring (PIR) with identity (you may assume that such a ring is commutative with identity). a) (5 pt) Show prime ideal is maximal). b) (5 pt) Show that the homomorphic image of a PIR is a PIR. c) (5 pt) Show) Is it true that any subring of a PIR is a PIR? #12;

Coykendall, James

420

Dynamical deformation effects in subbarrier fusion of $^{64}$Ni+$^{132}$Sn  

E-Print Network [OSTI]

We show that dynamical deformation effects play an important role in fusion reactions involving the $^{64}$Ni nucleus, in particular the $^{64}$Ni+$^{132}$Sn system. We calculate fully microscopic interaction potentials and the corresponding subbarrier fusion cross sections.

A. S. Umar; V. E. Oberacker

2006-09-25T23:59:59.000Z

Note: This page contains sample records for the topic "ni pd pt" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Study of Martensitic Phase transformation in a NiTiCu Thin Film...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Phase transformation in a NiTiCu Thin Film Shape Memory Alloy Using Photoelectron Emission Microscopy. Study of Martensitic Phase transformation in a NiTiCu Thin Film Shape...

422

A Hydrogen-Evolving Ni(P2N2)2 Electrocatalyst Covalently Attached...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

A Hydrogen-Evolving Ni(P2N2)2 Electrocatalyst Covalently Attached to a Glassy Carbon Electrode: Preparation, Characterization, A Hydrogen-Evolving Ni(P2N2)2 Electrocatalyst...

423

Mitigation of Sulfur Poisoning of Ni/Zirconia SOFC Anodes by...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Mitigation of Sulfur Poisoning of NiZirconia SOFC Anodes by Antimony and Tin . Mitigation of Sulfur Poisoning of NiZirconia SOFC Anodes by Antimony and Tin . Abstract: Surface...

424

Proton Delivery and Removal in [Ni(PR2NR?2)2]2+ Hydrogen...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Delivery and Removal in Ni(PR2NR?2)22+ Hydrogen Production and Oxidation Catalysts. Proton Delivery and Removal in Ni(PR2NR?2)22+ Hydrogen Production and Oxidation...

425

A MOSSBAUER STUDY OF AUSTENITE STABILITY AND IMPACT FRACTURE IN Fe - 6 Ni STEEL  

E-Print Network [OSTI]

IMPACT FRACTURE IN Fe-6Ni STEEL Brent Thomas Fultz Materialscommercial cryogenic alloy steel was studied with regard toThe Experiments Fe-6Ni-lMn steel plate was received from the

Fultz, Brent

2011-01-01T23:59:59.000Z

426

Effect of Aging Heat Treatments on Ni52Ti48 Shape Memory Alloy  

E-Print Network [OSTI]

Ni-rich NiTi shape memory alloys (SMAs) are capable of attaining a wide range of transformation temperatures depending on the heat treatment conditions and superior thermo-mechanical cycling stability, which are desired for repeated solid...

Akin, Erhan

2011-10-21T23:59:59.000Z

427

Assessing the Bioavailability of Ni in Smelter Contaminated Soils. (S11-everhart242852-oral)  

E-Print Network [OSTI]

Assessing the Bioavailability of Ni in Smelter Contaminated Soils. (S11-everhart242852-oral efforts. In this study, Welland Loam and Quarry Muck soils contaminated with Ni from a smelter facility

Sparks, Donald L.

428

WELDABILITY OF GRAIN-REFINED Fe-12Ni-0.25Ti STEEL FOR CRYOGENIC APPLICATIONS  

E-Print Network [OSTI]

of the Cryogenic Nickel Steels, WRC Bull, 205, May, 1975.REFINED Fe-12Ni-0.25Ti STEEL FOR CRYOGENIC APPLICATIONS D.E.REFINED Fe-12Ni-0.25Ti STEEL FOR CRYOGENIC APPLICATIONS D.

Morris Jr., J.W.

2013-01-01T23:59:59.000Z

429

E-Print Network 3.0 - alloy fracture cu-ni Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

fracture cu-ni Search Powered by Explorit Topic List Advanced Search Sample search results for: alloy fracture cu-ni Page: << < 1 2 3 4 5 > >> 1 Ris-R-1276(EN) Final Report...

430

X-ray absorption spectroscopy at the Ni-K edge in Stackhousia tryonii Bailey hyperaccumulator  

E-Print Network [OSTI]

X-ray absorption spectroscopy at the Ni–K edge inin vivo by micro x-ray absorption spectroscopy (XAS) at theNi–K edge. Both x-ray absorption near edge structure and

Kachenko, A.

2009-01-01T23:59:59.000Z

431

Potential of producing various hydrocarbons from canola oil by catalytic treatment over Pt-ZSM-5  

SciTech Connect (OSTI)

Canola oil conversion was studied at atmospheric pressure over Pt-ZSM-5 catalyst (0.5 wt% Pt) in a fixed bed micro-reactor. The operating conditions were: temperature range of 400--500 C, weight hourly space velocity (WHSV) of 1.8 and 3.6 h{sup {minus}1} and steam/oil ratio of 4:1. The products were coke, gas, an organic liquid product (OLP) and residue. The gas and OLP consisted mainly of hydrocarbons. The objective of this study was to maximize the amount of gasoline range hydrocarbons in the OLP and the selectivity to isohydrocarbons in the gas. The gas yields varied between 22--65 wt% and were higher in the presence of steam compared to the operation without steam. Also, the gas fraction decreased with increase in space velocity. The olefin/paraffin ratio of C{sub 2}-C{sub 4} hydrocarbon gases varied between 0.31--0.79. The amount of isohydrocarbons relative to n-hydrocarbons were higher with Pt-ZSM-5 (1.6--4.8) compared to pure HZSM-5 catalyst (0.2--0.3). The OLP yields with Pt-ZSM-5 (20--55wt% of canola oil) were slightly lower compared to HZSM-5 (40--63wt% of canola oil) under similar conditions. The major components of OLP were aliphatic and aromatic hydrocarbons. The main aromatic hydrocarbons were benzene, toluene, xylenes and trimethylbenzenes. Alkylated pentane and hexane were the main aliphatic hydrocarbons. In the presence of steam, Pt-ZSM-5 gave higher yields of liquid hydrocarbons within the gasoline boiling range than HZSM-5.

Katikaneni, S.P.R.; Adjaye, J.D.; Bakhshi, N.N. [Univ. of Saskatchewan, Saskatoon (Canada)

1995-12-31T23:59:59.000Z

432

Development of a new electrodeposition process for plating of Zn-Ni-X (X=Cd, P) alloys. 1. Corrosion characteristics of Zn-Ni-Cd ternary alloys  

SciTech Connect (OSTI)

A new Zn-Ni-Cd plating process was developed which offers a unique way of controlling and optimizing the Ni and Cd contents in the final deposit. Zinc-nickel-cadmium alloy was deposited from a 0.5 M NiSO{sub 4} + 0.2 M ZnSO{sub 4} bath in the presence of 0.015 M CdSO{sub 4} and 1 g/L nonyl phenyl polyethylene oxide. Using this process a Zn-Ni-Cd ternary alloy, with a higher nickel content as compared to that obtained from conventional Zn-Ni baths, was synthesized. The Zn-Ni-Cd alloy coatings deposited from an electrolyte containing 0.015 M (0.3%) CdSO{sub 4} has a Zn to Ni ratio of 2.5:1. The increase in nickel content accounts for the observed decrease in the corrosion potential to a value lower than that of Cd but higher than the corrosion potential of iron. The coatings have superior corrosion resistance and barrier properties than the typical Zn-Ni and cadmium coatings. Polarization studies and electrochemical impedance spectroscopy analysis on Zn-Ni-Cd coatings show a barrier resistance that is ten times higher than that of a conventional Zn-Ni coating.

Durairajan, A.; Haran, B.S.; White, R.E.; Popov, B.N.

2000-05-01T23:59:59.000Z

433

Kinetics of Mixed Ni-Al Precipitate Formation on a Soil Clay Fraction  

E-Print Network [OSTI]

Kinetics of Mixed Ni-Al Precipitate Formation on a Soil Clay Fraction D A R R Y L R . R O B E R Management Laboratory, Paul Scherrer Institute, CH-5232 Villigen PSI, Switzerland The kinetics of mixed Ni-Al Ni- Al LDH formation. The initial Ni concentration was 3 mM with a solid/solution ratio of 10 g L-1

Sparks, Donald L.

434

Monte Carlo calculations and experimental measurements of dosimetric parameters of the IRA-{sup 103}Pd brachytherapy source  

SciTech Connect (OSTI)

This article presents a brachytherapy source having {sup 103}Pd adsorbed onto a cylindrical silver rod that has been developed by the Agricultural, Medical, and Industrial Research School for permanent implant applications. Dosimetric characteristics (radial dose function, anisotropy function, and anisotropy factor) of this source were experimentally and theoretically determined in terms of the updated AAPM Task group 43 (TG-43U1) recommendations. Monte Carlo simulations were used to calculate the dose rate constant. Measurements were performed using TLD-GR200A circular chip dosimeters using standard methods employing thermoluminescent dosimeters in a Perspex phantom. Precision machined bores in the phantom located the dosimeters and the source in a reproducible fixed geometry, providing for transverse-axis and angular dose profiles over a range of distances from 0.5 to 5 cm. The Monte Carlo N-particle (MCNP) code, version 4C simulation techniques have been used to evaluate the dose-rate distributions around this model {sup 103}Pd source in water and Perspex phantoms. The Monte Carlo calculated dose rate constant of the IRA-{sup 103}Pd source in water was found to be 0.678 cGy h{sup -1} U{sup -1} with an approximate uncertainty of {+-}0.1%. The anisotropy function, F(r,{theta}), and the radial dose function, g(r), of the IRA-{sup 103}Pd source were also measured in a Perspex phantom and calculated in both Perspex and liquid water phantoms.

Sadeghi, Mahdi; Raisali, Gholamreza; Hosseini, S. Hamed; Shavar, Arzhang [Nuclear Medicine Research Group, Agricultural, Medical and Industrial Research School, P.O. Box 31485-498, Karaj (Iran, Islamic Republic of) and Engineering Faculty, Science and Research Campus, Islamic Azad University, P.O. Box 14515-775, Tehran (Iran, Islamic Republic of); Radiation Applications Research School, Nuclear Science and Technology Research Institute, Tehran (Iran, Islamic Republic of); Engineering Faculty, Science and Research Campus, Islamic Azad University, P.O. Box 14515-775, Tehran (Iran, Islamic Republic of); SSDL Group, Agricultural, Medical and Industrial Research School, Karaj (Iran, Islamic Republic of)

2008-04-15T23:59:59.000Z

435

Electronic Friction Dominates Hydrogen Hot-Atom Relaxation on Pd(100) M. Blanco-Rey,1,2  

E-Print Network [OSTI]

initio molecular dynamics simulations that include a friction force to account for the energy transfer February 2014; published 14 March 2014) We study the dynamics of transient hot H atoms on Pd(100 to the electronic system. We find that the excitation of electron-hole pairs is the main channel for energy

Muiño, Ricardo Díez

436

Synthesis and study of ligands for Pd-catalyzed C-O and C-N coupling  

E-Print Network [OSTI]

A new ligand, AdBrettPhos, was synthesized and its use, along with tBuBrettPhos, in C-O coupling reactions at low temperatures was investigated. Using Pd catalysts containing these ligands, electron-neutral aryl bromides ...

Davis, Nicole R. (Nicole Rose)

2009-01-01T23:59:59.000Z

437

Synthesis and characterization of the Au-modified Pd cathode catalyst for alkaline direct ethanol fuel cells  

E-Print Network [OSTI]

Available online 3 August 2010 Keywords: Fuel cell Alkaline direct ethanol fuel cell Oxygen reduction Carbon in large quantities from agricultural products or biomass. Hence, direct ethanol fuel cells (DEFCs) haveSynthesis and characterization of the Au-modified Pd cathode catalyst for alkaline direct ethanol

Zhao, Tianshou

438

Unoccupied electronic states of icosahedral Al-Pd-Mn quasicrystals: Evidence of image potential resonance and pseudogap  

SciTech Connect (OSTI)

We study the unoccupied region of the electronic structure of the fivefold symmetric surface of an icosahedral (i) Al-Pd-Mn quasicrystal. A feature that exhibits parabolic dispersion with an effective mass of (1.15±0.1)me and tracks the change in the work function is assigned to an image potential resonance because our density functional calculation shows an absence of band gap in the respective energy region. We show that Sn grows pseudomorphically on i?Al?Pd?Mn as predicted by density functional theory calculations, and the energy of the image potential resonance tracks the change in the work function with Sn coverage. The image potential resonance appears much weaker in the spectrum from the related crystalline Al-Pd-Mn surface, demonstrating that its strength is related to the compatibility of the quasiperiodic wave functions in i?Al?Pd?Mn with the free-electron-like image potential states. Our investigation of the energy region immediately above EF provides unambiguous evidence for the presence of a pseudogap, in agreement with our density functional theory calculations.

Maniraj, M [UGC-DAE Confortium for Scientific Research; Rai, Abhishek [UGC-DAE Confortium for Scientific Research; Barman, S R [UGC-DAE Confortium for Scientific Research; Krajci, M [Slovak Academy of Sciences; Schlagel, Deborah L [Ames Laboratory; Lograsso, Thomas A [Ames Laboratory; Horn, K [Fritz-Haber-Institut der Max-Planck-Gesellschaft

2014-09-01T23:59:59.000Z

439

Probing the nuclides {sup 102}Pd, {sup 106}Cd, and {sup 144}Sm for resonant neutrinoless double-electron capture  

SciTech Connect (OSTI)

The Q values for double-electron capture in {sup 102}Pd, {sup 106}Cd, and {sup 144}Sm have been measured by Penning-trap mass spectrometry. The results exclude at present all three nuclides from the list of suitable candidates for a search for resonant neutrinoless double-electron capture.

Goncharov, M.; Blaum, K.; Eliseev, S. [Max-Planck-Institut fuer Kernphysik, Saupfercheckweg 1, D-69117 Heidelberg (Germany); Block, M.; Herfurth, F.; Minaya Ramirez, E. [GSI Helmholtzzentrum fuer Schwerionenforschung GmbH, Planckstrasse 1, D-64291 Darmstadt (Germany); Droese, C.; Schweikhard, L. [Institut fuer Physik, Ernst-Moritz-Arndt-Universitaet, D-17487 Greifswald (Germany); Novikov, Yu. N. [Max-Planck-Institut fuer Kernphysik, Saupfercheckweg 1, D-69117 Heidelberg (Germany); Petersburg Nuclear Physics Institute, Gatchina, RU-188300 St. Petersburg (Russian Federation); Department of Physics, St. Petersburg State University, RU-198504 St. Petersburg (Russian Federation); Zuber, K. [Institut fuer Kern- und Teilchenphysik, Technische Universitaet, D-01069 Dresden (Germany)

2011-08-15T23:59:59.000Z

440

Direct oxidation of methane to acetic acid catalyzed by Pd2+ and Cu2+ in the presence of molecular oxygen  

E-Print Network [OSTI]

Direct oxidation of methane to acetic acid catalyzed by Pd2+ and Cu2+ in the presence of molecular published as an Advance Article on the web 3rd August 2004 Methane is catalytically converted primarily. The conversion of methane to acetic acid has attracted recent interest as a pathway for the synthesis

Bell, Alexis T.

Note: This page contains sample records for the topic "ni pd pt" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Refined Glauber model versus Faddeev calculations and experimental data for pd spin observables  

SciTech Connect (OSTI)

Spin-dependent observables in intermediate-energy pd elastic scattering within the framework of the refined Glauber model are considered. The improvements include an account of all ten pp and pn helicity amplitudes at respective energies constructed on the basis of modern phase-shift analysis, accurate deuteron wave functions taken from the modern NN force model and account of charge-exchange effects. Predictions of the refined diffraction model for differential cross section and analyzing powers are compared with exact three-body Faddeev calculations and the recent experimental data. An amazingly good agreement between the results of both theoretical approaches as well as between the refined Glauber model and experiment in a wide angular range not only for differential cross section but also for vector and tensor analyzing powers has been found for the first time. Possible reasons for this agreement are discussed.

Platonova, M. N.; Kukulin, V. I. [D.V. Skobeltsyn Institute of Nuclear Physics, M.V. Lomonosov Moscow State University, Moscow RU-119991 (Russian Federation)

2010-01-15T23:59:59.000Z

442

INVESTIGATION OF NOVEL ALLOY TiC-Ni-Ni3Al FOR SOLID OXIDE FUEL CELL INTERCONNECT APPLICATIONS  

SciTech Connect (OSTI)

Solid oxide fuel cell interconnect materials must meet stringent requirements. Such interconnects must operate at temperatures approaching 800 C while resisting oxidation and reduction, which can occur from the anode and cathode materials and the operating environment. They also must retain their electrical conductivity under these conditions and possess compatible coefficients of thermal expansion as the anode and cathode. Results are presented in this report for fuel cell interconnect candidate materials currently under investigation based upon nano-size titanium carbide (TiC) powders. The TiC is liquid phase sintered with either nickel (Ni) or nickel-aluminide (Ni{sub 3}Al) in varying concentrations. The oxidation resistance of the submicron grain TiC-metal materials is presented as a function weight change versus time at 700 C and 800 C for varying content of metal/intermetallic in the system. Electrical conductivity at 800 C as a function of time is also presented for TiC-Ni to demonstrate the vitality of these materials for interconnect applications. TGA studies showed that the weight gain was 0.8 mg/cm{sup 2} for TiC(30)-Ni(30wt.%) after 100 hours in wet air at 800 C and the weight gain was calculated to be 0.5205 mg/cm{sup 2} for TiC(30)- Ni(10 wt.%) after 100 hours at 700 C and 100 hours at 800 C. At room temperature the electrical conductivity was measured to be 2444 1/[ohm.cm] for TiC-Ni compositions. The electrical conductivities at 800 C in air was recorded to be 19 1/[ohm.cm] after 125 hours. Two identical samples were supplied to PNNL (Dr. Jeff Stevenson) for ASR testing during the pre-decision period and currently they are being tested there. Fabrication, oxidation resistance and electrical conductivity studies indicate that TiC-Ni-Ni{sub 3}Al ternary appears to be a very important system for the development of interconnect composition for solid oxide fuel cells.

Rasit Koc; Geoffrey Swift; Hua Xie

2005-01-25T23:59:59.000Z

443

Shape memory response of ni2mnga and nimncoin magnetic shape memory alloys under compression  

E-Print Network [OSTI]

In this study, the shape memory response of Ni2MnGa and NiMnCoIn magnetic shape memory alloys was observed under compressive stresses. Ni2MnGa is a magnetic shape memory alloy (MSMA) that has been shown to exhibit fully reversible, stressassisted...

Brewer, Andrew Lee

2009-05-15T23:59:59.000Z

444

Vacancy-Vacancy Interactions in NiAl Matthew O. Zacate and Gary S. Collins  

E-Print Network [OSTI]

Vacancy-Vacancy Interactions in NiAl Matthew O. Zacate and Gary S. Collins Department of Physics, Washington State University, Pullman, WA 99164, USA Keywords: point defect, vacancy, defect interaction, intermetallic compound, perturbed angular correlation, PAC, NiAl Abstract. Interactions between Ni vacancies

Collins, Gary S.

445

Directional solidification studies in Ni-Al alloys  

SciTech Connect (OSTI)

Three solid phases are involved in the phase equilibria of the intermetallic compound Ni{sub 3}Al near its melting point, {beta}, {gamma}{prime}(Ni{sub 3}Al), and {gamma}. The generally-accepted phase diagram involves a eutectic reaction between {beta}{prime} and {gamma}, but some recent studies agree with an older diagram due to Schramm, which has a eutectic reaction between the {beta} and {gamma}{prime} phases. The phase equilibria near Ni{sub 3}Al compositions was evaluated using quenched directional solidification experiments, that preserve the microstructures tonned at the solidification front, and using diffusion couple experiments. These experiments show that eutectic forms between {beta} and {gamma}{prime} phases, as in the Schramm diagram. Growth and phase transformations of these three phases are also studied in the directional solidification experiments. Microstructure analysis shows that etching of Ni{sub 3}Al({gamma}{prime}) is very sensitive to small composition variations and crystallographic orientation changes. The eutectic solidification study confirms that the equilibrium eutectic is {gamma}{prime}+{beta}, and that the metastable {gamma}+{beta} eutectic might be also produced in this system according to the impurities, solidification rates, and composition variations.

Lee, Je-hyun

1993-05-01T23:59:59.000Z

446

Precipitation in 9Ni-12Cr-2Cu maraging steels  

SciTech Connect (OSTI)

Two maraging steels with the compositions 9Ni-12Cr-2Cu-4Mo (wt%) and 9Ni-12Cr-2Cu and with small additions of Al and Ti were investigated using atom probe field ion microscopy. Tomographic atom probe investigations were performed to clarify the spatial distribution of elements in and close to the precipitates. Materials heat treated at 475 C for 5, 25 min, 1, 2, 4 and 400 h were analyzed. Precipitates in the Mo-rich material were observed already after 5 min of aging, while in the material without MO, precipitation started later. In both materials precipitation begins with the formation of Cu-rich particles which work as nucleation sites for a Ni-rich phase of type Ni{sub 3}(Ti,Al). A Mo-rich phase was detected in the Mo-rich steel after 2 h of aging. The distribution of alloying elements in the precipitates, their role in the precipitation process, and the mechanism of hardening in the two materials are discussed.

Stiller, K.; Haettestrand, M. [Chalmers Univ. of Technology, Goeteborg (Sweden). Dept. of Physics] [Chalmers Univ. of Technology, Goeteborg (Sweden). Dept. of Physics; Danoix, F. [Univ. de Rouen, Mont Saint Aignan (France). Lab. de Microscopie Ionique] [Univ. de Rouen, Mont Saint Aignan (France). Lab. de Microscopie Ionique

1998-11-02T23:59:59.000Z

447

Monopole resonance strengths in Ni-58 and Pb-208  

E-Print Network [OSTI]

Giant monopole resonance strengths were obtained from small angle inelastic alpha scattering on Ni-58 and Pb-208 using deformed potential and folding models. Folding model analyses increase the sum rule strength in both nuclei, with 160% of the E0...

Youngblood, David H.

1997-01-01T23:59:59.000Z

448

Roles of Pt and BaO in the Sulfation of Pt/BaO/Al2O3 Lean NOx Trap  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the1 -the Mid-Infrared0 Resource ProgramEnergyMaterials: Sulfur K-edge XANES and Pt LIII

449

Stepwise synthesis, characterization, and electrochemical properties of ordered mesoporous carbons containing well-dispersed Pt nanoparticles using a functionalized template route  

SciTech Connect (OSTI)

A stepwise method is described for the accurately controlled growth of Pt nanoparticles supported on ordered mesoporous carbons (Pt-OMC) by the nanocasting of carbon and metal precursors in the pore channels of mesoporous silicas functionalized with Si-H groups. Results obtained from N{sub 2} adsorption/desorption isotherms and transmission electron microscopy showed well-dispersed Pt nanoparticles (2-3 nm) on Pt-OMC with high surface area (837 m{sup 2} g{sup -1}) and regular pore channels (2.9 nm), which facilitate reactant/product diffusion. X-ray diffraction and X-ray photoelectron spectroscopy indicated that Pt nanoparticles in the Pt-OMC sample were mostly present in the metallic form of a face-centered cubic (fcc) crystalline structure. The Pt-OMC catalyst was found to have superior electrocatalytic properties during oxygen reduction reaction as compared to typical commercial electrocatalysts. - Graphical abstract: A novel procedure has been developed to synthesize ordered carbon mesoporous carbons (OMC) containing well-dispersed and highly electrocatalytic Pt nanoparticles (Pt-OMC) for oxygen reduction reaction. Highlights: > A novel method to incorporate nanosized Pt particles on nanostructure carbons. > Functionalized silica templates were used to control size and distribution of Pt nanoparticles. > Electrochemical measurements of oxygen reduction demonstrated high catalytic activity compared to common commercial catalysts.

Liu, Shou-Heng, E-mail: shliu@kuas.edu.tw [Department of Chemical and Materials Engineering, National Kaohsiung University of Applied Sciences, Kaohsiung 80778, Taiwan (China); Chen, Shih-Che [Department of Chemical and Materials Engineering, National Kaohsiung University of Applied Sciences, Kaohsiung 80778, Taiwan (China)

2011-09-15T23:59:59.000Z

450

Effect of Composition on the Solidification Behavior of Several Ni-Cr-Mo and Fe-Ni-Cr-Mo Alloys  

E-Print Network [OSTI]

simulate the solidifi- cation behavior of dissimilar welds made between AL-6XN and Ni-base filler metals.[3 differential thermal analysis (DTA) samples and welded specimens. This explains the in- variance of the amount of eutectic constituent observed in the microstructure in the welded and DTA conditions. Multicomponent

DuPont, John N.

451

Improved magnetoelectric performance of the Ni-P/Ni/Pb(Zr,TiO)3 cylindrical layered composites  

E-Print Network [OSTI]

) cylindrical layered magnetoelectric (ME) composites have been prepared by electroless deposition, and electroless deposition.9­12 Improving magnetoelectric device characteristics can be achieved by enhancing via magnetic flux concentration. Nickel is a kind of universal strong magnetic material, while Ni

Volinsky, Alex A.

452

Low-temperature magnetization in Ni-rich gamma-Ni100-x-yFexVy alloys  

E-Print Network [OSTI]

Detailed studies of the temperature dependence of the spontaneous magnetization have been made in eight different compositions of gamma-Ni100-x-yFexVy (4 less than or equal to x less than or equal to 17; 2 less than or equal to y less than or equal...

Chakraborty, S.; Mukherjee, GD; Rathnayaka, KDD; Naugle, Donald G.; Majumdar, AK.

2000-01-01T23:59:59.000Z

453

El Ni~no and La Ni~na: Causes and Global Consequences Michael J McPhaden  

E-Print Network [OSTI]

releases heat into the middle and upper troposphere. This heat provides a source of energy to drive global wind fields that extend El Ni~no's influence to remote parts of the planet. Altered circulation patterns produce droughts, floods, unusual storminess, heat waves, and other weather extremes that have

454

First-principles investigations of Ni3Al(111) and NiAl(110) surfaces at metal dusting conditions  

SciTech Connect (OSTI)

We investigate the structure and surface composition of the {gamma}{prime}-Ni{sub 3}Al(111) and {beta}-NiAl(110) alloy surfaces at conditions relevant for metal dusting corrosion related to catalytic steam reforming of natural gas. In regular service as protective coatings, nickel-aluminum alloys are protected by an oxide scale, but in case of oxide scale spallation, the alloy surface may be directly exposed to the reactive gas environment and vulnerable to metal dusting. By means of density functional theory and thermochemical calculations for both the Ni{sub 3}Al and NiAl surfaces, the conditions under which CO and OH adsorption is to be expected and under which it is inhibited, are mapped out. Because CO and OH are regarded as precursors for nucleating graphite or oxide on the surfaces, phase diagrams for the surfaces provide a simple description of their stability. Specifically, this study shows how the CO and OH coverages depend on the steam to carbon ratio (S/C) in the gas and thereby provide a ranking of the carbon limits on the different surface phases.

Saadi, Souheil

2011-03-01T23:59:59.000Z

455

Au microstructure and the functional properties of Ni/Au finishes on ceramic IC packages  

SciTech Connect (OSTI)

Ni/Au plated finishes used on thick-film metallized multilayer ceramic packages for integrated circuits must meet functional requirements such as bondability, sealability, and solderability. Their ability to do so is dependent, among other things, on the ability of the Au deposit to inhibit the grain boundary diffusion and subsequent surface oxidation of Ni. In this study, the relation between functional performance, Ni diffusionr ate, and Au microstructure was examined. Extent of Ni diffusion during heating was determined by Auger electron spectroscopy for several electrolytic and electroless Ni/Au finishing processes. Results were correlated with differences in Au microstructures determined by SEM, atomic force microscopy, and XRD.

Winters, E.D.; Baxter, W.K. [Coors Electronic Package Co., Chattanooga, TN (United States); Braski, D.N.; Watkins, T.R. [Oak Ridge National Lab., TN (United States)

1995-12-31T23:59:59.000Z

456

A comparative study of magnetic behaviors in TbNi{sub 2}, TbMn{sub 2} and TbNi{sub 2}Mn  

SciTech Connect (OSTI)

All TbNi{sub 2}, TbMn{sub 2}, and TbNi{sub 2}Mn compounds exhibit the cubic Laves phase with AB{sub 2}-type structure in spite of the fact that the ratio of the Tb to transition-metal components in TbNi{sub 2}Mn is 1:3. Rietveld refinement indicates that in TbNi{sub 2}Mn the Mn atoms are distributed on both the A (8a) and B (16d) sites. The values of the lattice constants were measured to be a?=?14.348?Å (space group F-43?m), 7.618?Å, and 7.158?Å (space group Fd-3?m) for TbNi{sub 2}, TbMn{sub 2}, and TbNi{sub 2}Mn, respectively. The magnetic transition temperatures T{sub C} were found to be T{sub C}?=?38?K and T{sub C}?=?148?K for TbNi{sub 2} and TbNi{sub 2}Mn, respectively, while two magnetic phase transitions are detected for TbMn{sub 2} at T{sub 1}?=?20?K and T{sub 2}?=?49?K. Clear magnetic history effects in a low magnetic field are observed in TbMn{sub 2} and TbNi{sub 2}Mn. The magnetic entropy changes have been obtained.

Wang, J. L., E-mail: jianli@uow.edu.au [Institute for Superconductivity and Electronic Materials, University of Wollongong, Wollongong, NSW 2522 (Australia); Bragg Institute, ANSTO, Lucas Heights, NSW 2234 (Australia); Md Din, M. F.; Hong, F.; Cheng, Z. X.; Dou, S. X. [Institute for Superconductivity and Electronic Materials, University of Wollongong, Wollongong, NSW 2522 (Australia); Kennedy, S. J.; Studer, A. J. [Bragg Institute, ANSTO, Lucas Heights, NSW 2234 (Australia); Campbell, S. J. [School of Physical, Environmental and Mathematical Sciences, The University of New South Wales, Canberra, ACT 2600 (Australia); Wu, G. H. [Institute of Physics, Chinese Academy of Science, Beijing 100190 (China)

2014-05-07T23:59:59.000Z

457

(Electronic structure and reactivities of transition metal clusters)  

SciTech Connect (OSTI)

The following are reported: theoretical calculations (configuration interaction, relativistic effective core potentials, polyatomics, CASSCF); proposed theoretical studies (clusters of Cu, Ag, Au, Ni, Pt, Pd, Rh, Ir, Os, Ru; transition metal cluster ions; transition metal carbide clusters; bimetallic mixed transition metal clusters); reactivity studies on transition metal clusters (reactivity with H{sub 2}, C{sub 2}H{sub 4}, hydrocarbons; NO and CO chemisorption on surfaces). Computer facilities and codes to be used, are described. 192 refs, 13 figs.

Not Available

1992-01-01T23:59:59.000Z

458

Catalytic hydrodechlorination of industrial wastewater containing chlorinated hydrocarbons in a trickle bed reactor  

E-Print Network [OSTI]

reaction has long been applied in chemical synthesis and liquid organic waste decomposition, very little attention is devoted to direct treatment of chlorinated hydrocarbons in wastewater (aqueous) or contannnated groundwater with hydrogen. The main..., Trichlorobenzene m Benzene Catal sts Group VIII Metals (Pt, Pd, Rh, Ru, Os, Ir, Ni) Rare earth oxide of the Lanthanide series and metal of the Platinum u Supported Palladium catalyst Tem efature 80 - 2750C 400 - 600'C 170 C Pressure atm...

Leong, Chee Kong

1996-01-01T23:59:59.000Z

459

Mass-Transport-Limited Electrodeposition of High-Surface-Area Coatings for Surface Acoustic Wave Sensor Technology  

SciTech Connect (OSTI)

The sensitivity of surface acoustic wave (SAW) sensors has been enhanced by increasing the active surface area of these devices. Electrodepositions of Ni, Pd, and Pt in a mass-transport-limited mode with trace foreign metals yield highly dendritic crystal structures of uniform macroscopic thickness. The concentration of metal ions, supporting electrolyte, agitation, and additives greatly impact the crystal morphology of the deposit. This methodology can be used simply and economically to provide high-area films in selective regions.

Ricco, Antonio J.; Staton, Alan W.; Yelton, W. Graham

1999-06-10T23:59:59.000Z

460

Mass-Transport-Limited Electrodeposition of High-Surface-Area Coatings for Surface Acoustic Wave Sensor Technology  

SciTech Connect (OSTI)

The sensitivity of surface acoustic wave (SAW) sensors has been enhanced by increasing the active surface area of these devices, Electrodepositions of Ni, Pd, and Pt in a mass-transport-limited mode with trace foreign metals yield highly dendritic crystal structures of uniform macroscopic thickness. The concentration of metal ions, supporting electrolyte, agitation, and additives greatly impact the crystal morphology of the deposit. This methodology can be used simply and economically to provide high-area films in selective regions.

Ricco, A.J.; Staton, A.W.; Yelton, W.G.

1999-06-07T23:59:59.000Z

Note: This page contains sample records for the topic "ni pd pt" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Can $J/?$ suppression and $p_T$ broadening signal the deconfinement transition at RHIC?  

E-Print Network [OSTI]

We have analyzed the latest NA50 data on $J/\\psi$ suppression in Pb+Pb collisions at CERN SPS. It is shown that a QCD based nuclear absorption model, where $J/\\psi$'s are absorbed in nuclear medium could explain the latest NA50 data on the centrality dependence of the $J/\\psi$ over Drell-Yan ratio. The model also explains the NA50 data on $J/\\psi$ over minimum bias ratio and the $p_T$ broadening of $J/\\psi$'s. A QGP based threshold model where all the $J/\\psi$'s are suppressed above a threshold density, also explains the data sets with smeared threshold density. Even at RHIC energy, centrality dependence of $J/\\psi$ suppression or $p_T$ broadening could not distinguish between the two models.

A. K. Chaudhuri

2005-06-24T23:59:59.000Z

462

A quasi-model-independent search for new high p{_}T physics at DO  

SciTech Connect (OSTI)

We present a new quasi-model-independent strategy (''Sleuth'') for searching for physics beyond the standard model. We define final states to be studied, and construct a rule that identifies a set of relevant variables for any particular final state. A novel algorithm searches for regions of excess in those variables and quantifies the significance of any detected excess. This strategy is applied to search for new high p{_}T physics in approximately 100 pb{sup -1} of proton-anti-proton collisions at sqrt(s) = 1.8 TeV collected by the D0 experiment during 1992-1996 at the Fermilab Tevatron. We systematically analyze many exclusive final states, and demonstrate sensitivity to a variety of models predicting new phenomena at the electroweak scale. No evidence of new high p{_}T physics is observed.

Knuteson, Bruce O.

2000-12-11T23:59:59.000Z

463

Fragile antiferromagnetism in the heavy-fermion compound YbBiPt  

SciTech Connect (OSTI)

We report results from neutron scattering experiments on single crystals of YbBiPt that demonstrate antiferromagnetic order characterized by a propagation vector, ?AFM = (121212), and ordered moments that align along the [1 1 1] direction of the cubic unit cell. We describe the scattering in terms of a two-Gaussian peak fit, which consists of a narrower component that appears below TN?0.4 K and corresponds to a magnetic correlation length of ?n? 80 Å, and a broad component that persists up to T?? 0.7 K and corresponds to antiferromagnetic correlations extending over ?b? 20 Å. Our results illustrate the fragile magnetic order present in YbBiPt and provide a path forward for microscopic investigations of the ground states and fluctuations associated with the purported quantum critical point in this heavy-fermion compound.

Ueland, Benjamin G. [Ames Laboratory; Kreyssig, Andreas [Ames Laboratory; Prokes, K. [Helmholtz-Zentrum Berlin fur Materialien und Energie; Lynn, J. W. [NIST Center for Neutron Research; Harriger, L. W. [NIST Center for Neutron Research; Pratt, D. K. [NIST Center for Neutron Research; Singh, D. K. [NIST Center for Neutron Research; Heitmann, T. W. [University of Missouri; Sauerbrei, Samantha [Ames Laboratory; Saunders, Scott M. [Ames Laboratory; Mun, E. D. [Ames Laboratory; Budko, Serguei L. [Ames Laboratory; McQueeney, Robert J. [Ames Laboratory; Canfield, Paul C. [Ames Laboratory; Goldman, Alan I. [Ames Laboratory

2014-05-08T23:59:59.000Z

464

Leading neutron energy and pT distributions in deep inelastic scattering and photoproduction at HERA  

E-Print Network [OSTI]

The production of energetic neutrons in $ep$ collisions has been studied with the ZEUS detector at HERA. The neutron energy and $p_T^2$ distributions were measured with a forward neutron calorimeter and tracker in a $40 \\pb^{-1}$ sample of inclusive deep inelastic scattering (DIS) data and a $6 \\pb^{-1}$ sample of photoproduction data. The neutron yield in photoproduction is suppressed relative to DIS for the lower neutron energies and the neutrons have a steeper $p_T^2$ distribution, consistent with the expectation from absorption models. The distributions are compared to HERA measurements of leading protons. The neutron energy and transverse-momentum distributions in DIS are compared to Monte Carlo simulations and to the predictions of particle exchange models. Models of pion exchange incorporating absorption and additional secondary meson exchanges give a good description of the data.

ZEUS Collaboration; S. Chekanov

2007-03-09T23:59:59.000Z

465

Ballistic magnetoresistance over 3000% in Ni nanocontacts at room temperature Harsh Deep Chopra* and Susan Z. Hua  

E-Print Network [OSTI]

. In the present study, the BMR measurements were made on Ni nanocontacts electrodeposited between Ni wires to electrodeposition of the Ni nanocontact, the Ni wires except for the region in the im- mediate vicinity of the tip a nickel sulfamate electro- lyte (pH 3.4). We used a cathode potential of 1.1 V ver- sus a saturated

Chopra, Harsh Deep

466

First principles study of effect of surface structure on chemical activity of Pt electrocatalysts in fuel cells  

E-Print Network [OSTI]

To facilitate commercialization of fuel cell systems as alternative energy device, the enhancement of Pt electrocatalysts activity is one of the most challenging issues. The first step to the solution is elucidating ...

Han, Byungchan

2008-01-01T23:59:59.000Z

467

CO Oxidation on Pt-Group Metals from Ultrahigh Vacuum to Near Atmospheric Pressures. 2. Palladium and Platinum  

E-Print Network [OSTI]

paper.1 Figure 1b shows the corresponding polarization modulation infrared reflection absorptionCO Oxidation on Pt-Group Metals from Ultrahigh Vacuum to Near Atmospheric Pressures. 2. Palladium

Goodman, Wayne

468

In situ Study of the Formation of Silicide Phases in Amorphous Ni-Si Mixed Layers  

SciTech Connect (OSTI)

In this paper, we investigated Ni silicide phase formation when Si is added within an as deposited 50 nm Ni film. A series of 22 samples with a Si content varying from 0 to 50 at.% was prepared and systematically investigated with in situ x-ray diffraction. The inert oxide substrate was used to identify the phases which first crystallize in an amorphous Ni-Si mixture of a given concentration. The noncongruent silicides Ni{sub 3}Si and Ni{sub 3}Si{sub 2} are never observed to crystallize readily out of the mixture. A remarkable observation is the initial crystallization at low temperature of a hexagonal Ni-silicide, observed over a broad mixed layer composition [35-49%Si]; this hexagonal phase nucleates readily as a single phase [39-47%Si] or together with Ni{sub 2}Si [35-38%Si] or NiSi [49%Si]. This low-temperature phase is related to the high temperature {theta}-phase, but covers a wide composition range up to 47%Si. For the same Ni-Si films deposited on Si(100), the initial nucleation of the Ni(Si) mixture is similar as for the samples deposited on SiO{sub 2}, such that the complex sequence of metal-rich Ni-silicide phases typically observed during Ni/Si reactions is modified. For samples containing more than 21%Si, a simpler sequential phase formation was observed upon annealing. From pole figures, the phase formation sequence was observed to have a significant influence on the texture of the technologically relevant NiSi phase. For mixture composition ranging from 38% to 43%Si, the initial transient {theta}-phase appears extremely textured on Si(100). The observed transient appearance of a hexagonal phase is of importance in understanding the phase formation mechanisms in the Ni-Si system.

Van Bockstael, C.; Detavernier, C; Van Meirhaeghe, R; Jordan-Sweet, J; Lavoie, C

2009-01-01T23:59:59.000Z

469

The influence of thermal treatment on the preparation of PMN and PMN-PT thin films  

SciTech Connect (OSTI)

Ferroelectric thin films belong to a class of materials with great technological importance in optic fibers, microelectromechanical systems, and microprocessors and computers memories. The (1-x)PbMg{sub 1/3}Nb{sub 2/3}O{sub 3}(x)PbTiO{sub 3} (PMN-PT) thin films, with x=0, 0.1, 0.35 and 0.5, were prepared by Pechini's process and deposited by spin-coating on Si(100), Pt/Ti/SiO{sub 2}/Si(100) and quartz substrates. The goal of the present paper is to verify the thermal treatment influence on the perovskite phase formation, which is desirable for these applications. The phase formation was analyzed by X-ray diffraction. The film's surface was characterized by atomic force microscopy to analyze the roughness and the homogeneity. The results of this study indicate that the optimum conditions for obtaining the perovskite phase using a Pt/Ti/SiO{sub 2}/Si(100) substrate, were drying each deposited layer at 140 deg. C (heating plate), and a final thermal treatment at 600 deg. C for 3 h in a closed system with a lead-rich atmosphere.

Spagnol, P.D.; Valadares, L.F.; Varela, J.A.; Bertochi, M.A.Z

2003-03-15T23:59:59.000Z

470

13-03-09 9:37 PMModernity, the Cold War, and New Whig Histories of Ideas, Pt. 2 | Ether Wave Propaganda Page 1 of 4http://etherwave.wordpress.com/2012/10/21/modernity-the-cold-war-and-new-whig-histories-of-ideas-pt-2/  

E-Print Network [OSTI]

13-03-09 9:37 PMModernity, the Cold War, and New Whig Histories of Ideas, Pt. 2 | Ether Wave Propaganda Page 1 of 4http://etherwave.wordpress.com/2012/10/21/modernity-the-cold-war-and-new-whig-histories-of-ideas-pt-2/ Modernity, the Cold War, and New Whig Histories of Ideas, Pt. 2 October 21, 2012 Posted

Solovey, Mark

471

12-11-24 7:47 PMModernity, the Cold War, and New Whig Histories of Ideas, Pt. 3 Ether Wave Propaganda Page 1 of 6http://etherwave.wordpress.com/2012/11/17/modernity-the-cold-war-and-new-whig-histories-of-ideas-pt-3/  

E-Print Network [OSTI]

12-11-24 7:47 PMModernity, the Cold War, and New Whig Histories of Ideas, Pt. 3 « Ether Wave Propaganda Page 1 of 6http://etherwave.wordpress.com/2012/11/17/modernity-the-cold-war-and-new-whig-histories-of-ideas-pt-3/ Modernity, the Cold War, and New Whig Histories of Ideas, Pt. 3 November 17, 2012 Posted

Solovey, Mark

472

13-03-09 9:32 PMModernity, the Cold War, and New Whig Histories of Ideas, Pt. 1 | Ether Wave Propaganda Page 1 of 6http://etherwave.wordpress.com/2012/09/22/modernity-the-cold-war-and-new-whig-histories-of-ideas-pt-1/  

E-Print Network [OSTI]

13-03-09 9:32 PMModernity, the Cold War, and New Whig Histories of Ideas, Pt. 1 | Ether Wave Propaganda Page 1 of 6http://etherwave.wordpress.com/2012/09/22/modernity-the-cold-war-and-new-whig-histories-of-ideas-pt-1/ Modernity, the Cold War, and New Whig Histories of Ideas, Pt. 1 September 22, 2012 Posted

Solovey, Mark

473

High Permeability Ternary Palladium Alloy Membranes with Improved Sulfur and Halide Tolerances  

SciTech Connect (OSTI)

The project team consisting of Southwest Research Institute{reg_sign} (SwRI{reg_sign}), Georgia Institute of Technology (GT), the Colorado School of Mines (CSM), TDA Research, and IdaTech LLC was focused on developing a robust, poison-tolerant, hydrogen selective free standing membrane to produce clean hydrogen. The project completed on schedule and on budget with SwRI, GT, CSM, TDA and IdaTech all operating independently and concurrently. GT has developed a robust platform for performing extensive DFT calculations for H in bulk palladium (Pd), binary alloys, and ternary alloys of Pd. Binary alloys investigated included Pd96M4 where M = Li, Na, Mg, Al, Si, Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ga, Y, Zr, Nb, Mo, Tc, Ru, Rh, Ag, Cd, In, Sn, Sb, Te, Hf, Ta, W, Re, Os, Ir, Pt, Au, Tl, Pb, Bi, Ce, Sm, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu. They have also performed a series of calculations on Pd{sub 70}Cu{sub 26}Ag{sub 4}, Pd{sub 70}Cu{sub 26}Au{sub 4}, Pd{sub 70}Cu{sub 26}Ni{sub 4}, Pd{sub 70}Cu{sub 26}Pt{sub 4}, and Pd{sub 70}Cu{sub 26}Y{sub 4}. SwRI deposited and released over 160 foils of binary and ternary Pd alloys. There was considerable work on characterizing and improving the durability of the deposited foils using new alloy compositions, post annealing and ion bombardment. The 10 and 25 {micro}m thick films were sent to CSM, TDA and IdaTech for characterization and permeation testing. CSM conducted over 60 pure gas permeation tests with SwRI binary and ternary alloy membranes. To date the PdAu and PdAuPt membranes have exhibited the best performance at temperatures in the range of 423-773 C and their performance correlates well with the predictions from GT. TDA completed testing under the Department of Energy (DOE) WGS conditions on over 16 membranes. Of particular interest are the PdAuPt alloys that exhibited only a 20% drop in flux when sulfur was added to the gas mixture and the flux was completely recovered when the sulfur flow was stopped. IdaTech tested binary and ternary membranes on a simulated flue gas stream and experienced significant difficulty in mounting and testing the sputter deposited membranes. IdaTech was able to successfully test PdAu and PdAuPt membranes and saw similar sulfur tolerance to what TDA found. The Program met all the deliverables on schedule and on budget. Over ten presentations at national and international conferences were made, four papers were published (two in progress) in technical journals, and three students (2 at GT and 1 at CSM) completed their doctorates using results generated during the course of the program. The three major findings of program were; (1) the DFT modeling was verified as a predictive tool for the permeability of Pd based ternary alloys, (2) while magnetron sputtering is useful in precisely fabricating binary and ternary alloys, the mechanical durability of membranes fabricated using this technique are inferior compared to cold rolled membranes and this preparation method is currently not ready for industrial environments, (3) based on both modeling and experimental verification in pure gas and mixed gas environments PdAu and PdAuPt alloys were found to have the combination of the highest permeability and tolerance to sulfur.

K. Coulter

2010-12-31T23:59:59.000Z

474

Nonlinear transport in quasi-one-dimensional Nb{sub 2}PdS{sub 5} nanowires  

SciTech Connect (OSTI)

Nb{sub 2}PdS{sub 5} is a newly discovered quasi-one-dimensional (quasi-1D) superconductor with a high upper critical field along the chain direction. Here, we report the size-dependent electronic properties of Nb{sub 2}PdS{sub 5} nanowires obtained by ultrasonically cleaving the bulk crystals. The nanowires exhibit a superconductor to insulator transition as the cross-sectional area decreases. Moreover, for the thinner nanowires with insulating state, the transport properties exhibit a power-law dependence on both temperature and bias voltage at an intermediate temperature (<30?K), followed by a conduction saturation below 10?K. We found that such an apparent power-law behavior can be described by the extended variable range hopping theory developed recently for the multichannel quasi-1D systems, where the localization of electrons is expected to be dominant instead of the Luttinger liquid nature.

Ning, Wei; Yu, Hongyan; Wang, Ning; Han, Yuyan; Yang, Jiyong; Du, Haifeng; Zhang, Changjin [High Magnetic Field Laboratory, Chinese Academy of Sciences, Hefei 230031, Anhui (China); Liu, Yequn [Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001 (China); Yang, Kun [National High Magnetic Field Laboratory, Florida State University, Tallahassee, Florida 32306-4005 (United States); Tian, Mingliang, E-mail: tianml@hmfl.ac.cn; Zhang, Yuheng [High Magnetic Field Laboratory, Chinese Academy of Sciences, Hefei 230031, Anhui (China); Collaborative Innovation Center of Advanced Microstructures, Nanjing 210093 (China)

2014-10-27T23:59:59.000Z

475

Novel electrolyte chemistries for Mg-Ni rechargeable batteries.  

SciTech Connect (OSTI)

Commercial hybrid electric vehicles (HEV) and battery electric vehicles (BEV) serve as means to reduce the nation's dependence on oil. Current electric vehicles use relatively heavy nickel metal hydride (Ni-MH) rechargeable batteries. Li-ion rechargeable batteries have been developed extensively as the replacement; however, the high cost and safety concerns are still issues to be resolved before large-scale production. In this study, we propose a new highly conductive solid polymer electrolyte for Mg-Ni high electrochemical capacity batteries. The traditional corrosive alkaline aqueous electrolyte (KOH) is replaced with a dry polymer with conductivity on the order of 10{sup -2} S/cm, as measured by impedance spectroscopy. Several potential novel polymer and polymer composite candidates are presented with the best-performing electrolyte results for full cell testing and cycling.

Garcia-Diaz, Brenda (Savannah River National Laboratory); Kane, Marie; Au, Ming (Savannah River National Laboratory)

2010-10-01T23:59:59.000Z

476

Solar fuels : integration of molecular catalysts with p-type semiconductor photocathode  

E-Print Network [OSTI]

on hydrogenated Pd and Pt electrode at 200 mV overpotentialor hydrogenated Pd. All of these electrodes are good proton

Kumar, Bhupendra

2012-01-01T23:59:59.000Z

477

A study of the anodic polarization behavior of Zr(50)Cu(40-x)Al(10)Pd(x) BMG with scanning Auger microanalysis  

SciTech Connect (OSTI)

The anodic-polarization behaviors of Zr50Cu40-XAl10PdX (x = 0 and 7 atomic %) BMGs were investigated in 0.6 M NaCl electrolytes. Initial anodic polarization of both alloys yielded regions where small increases in the applied potential induced significant increases in the current density. Continued polarization of both BMGs resulted in diffusion controlled regimes. However, the limiting diffusion current density of Zr50Cu33Al10Pd7 was higher than that of Zr50Cu40Al10. Scanning Auger microanalysis was used to investigate the oxide formed during polarization and to analyze the chemistry within corrosion pits. The pits formed on both BMGs were enriched with Cu and Cl. Corrosion pits on Zr50Cu33Al10Pd7 were additionally enriched with Pd. A corrosion mechanism relating to the formation of CuCl and Cu2O is proposed based on both the polarization and microanalysis results.

Green, Brandice [ORNL; Meyer III, Harry M [ORNL; Benson, Roberto S [ORNL; Yokoyama, Y [Institute for Materials Research; Liaw, Peter K [University of Tennessee, Knoxville (UTK); Liu, Chain T [ORNL

2008-01-01T23:59:59.000Z

478

Sources of stress gradients in electrodeposited Ni MEMS.  

SciTech Connect (OSTI)

The ability of future integrated metal-semiconductor micro-systems such as RF MEMS to perform highly complex functions will depend on developing freestanding metal structures that offer improved conductivity and reflectivity over polysilicon structures. For example, metal-based RF MEMS technology could replace the bulky RF system presently used in communications, navigation, and avionics systems. However, stress gradients that induce warpage of active components have prevented the implementation of this technology. Figure 1, is an interference micrograph image of a series of cantilever beams fabricated from electrodeposited Ni. The curvature in the beams was the result of stress gradients intrinsic to the electrodeposition process. To study the sources of the stress in electrodeposition of Ni we have incorporated a wafer curvature based stress sensor, the multibeam optical stress sensor, into an electrodeposition cell. We have determined that there are two regions of stress induced by electrodepositing Ni from a sulfamate-based bath (Fig 2). The stress evolution during the first region, 0-1000{angstrom}, was determined to be dependent only on the substrate material (Au vs. Cu), whereas the stress evolution during the second region, >1000{angstrom}, was highly dependent on the deposition conditions. In this region, the stress varied from +0.5 GPa to -0.5GPa, depending solely on the deposition rate. We examined four likely sources for the compressive intrinsic stress, i.e. reduction in tensile stress, and determined that only the adatom diffusion into grain boundaries model of Sheldon, et al. could account for the observed compressive stress. In the presentation, we shall discuss the compressive stress generation mechanisms considered and the ramifications of these results on fabrication of electrodeposited Ni for MEMS applications.

Hearne, Sean Joseph; Floro, Jerrold Anthony; Dyck, Christopher William

2004-06-01T23:59:59.000Z

479

Density changes in amorphous Pd{sub 80}Si{sub 20} during low temperature ion irradiation  

SciTech Connect (OSTI)

Density changes in amorphous Pd{sub 80}Si{sub 20} during ion irradiation below 100K were detected by in situ HVEM measurements of the changes in specimen length as a function of ion fluence. A decrease in mass density as a function of the ion fluence was observed. The saturation value of the change in mass density was determined to be approximately -1.2%.

Schumacher, G.; Birtcher, R.C.; Rehn, L.E.

1994-11-01T23:59:59.000Z

480

Structural and electronic properties of Au{sub n?x}Pt{sub x} (n = 2–14; x ? n) clusters: The density functional theory investigation  

SciTech Connect (OSTI)

The structural evolutions and electronic properties of bimetallic Au{sub n–x}Pt{sub x} (n = 2–14; x ? n) clusters are investigated by using the density functional theory (DFT) with the generalized gradient approximation (GGA). The monatomic doping Au{sub n–1}Pt clusters are emphasized and compared with the corresponding pristine Au{sub n} clusters. The results reveal that the planar configurations are favored for both Au{sub n–1}Pt and Au{sub n} clusters with size up to n = 13, and the former often employ the substitution patterns based on the structures of the latter. The most stable clusters are Au{sub 6} and Au{sub 6}Pt, which adopt regular planar triangle (D{sub 3h}) and hexagon-ring (D{sub 6h}) structures and can be regarded as the preferential building units in designing large clusters. For Pt-rich bimetallic clusters, their structures can be obtained from the substitution of Pt atoms by Au atoms from the Pt{sub n} structures, where Pt atoms assemble together and occupy the center yet Au atoms prefer the apex positions showing a segregation effect. With respect to pristine Au clusters, Au{sub n}Pt clusters exhibit somewhat weaker and less pronounced odd-even oscillations in the highest occupied and lowest unoccupied molecular-orbital gaps (HOMO-LUMO gap), electron affinity (EA), and ionization potential (IP) due to the partially released electron pairing effect. The analyses of electronic structure indicate that Pt atoms in AuPt clusters would delocalize their one 6s and one 5d electrons to contribute the electronic shell closure. The sp-d hybridizations as well as the d-d interactions between the host Au and dopant Pt atoms result in the enhanced stabilities of AuPt clusters.

Yuan, H. K.; Kuang, A. L.; Tian, C. L.; Chen, H., E-mail: chenh@swu.edu.cn [School of Physical Science and Technology, Southwest University, Chongqing, 400715 (China)

2014-03-15T23:59:59.000Z

Note: This page contains sample records for the topic "ni pd pt" from the National Library of EnergyBeta (NLEBeta).
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481

Magnetic field-induced phase transformation and variant reorientation in Ni2MnGa and NiMnCoIn magnetic shape memory alloys  

E-Print Network [OSTI]

The purpose of this work is to reveal the governing mechanisms responsible for the magnetic field-induced i) martensite reorientation in Ni2MnGa single crystals, ii) stress-assisted phase transformation in Ni2MnGa single crystals and iii) phase...

Karaca, Haluk Ersin

2009-05-15T23:59:59.000Z

482

The significant effect of the thickness of Ni film on the performance of the Ni/Au Ohmic contact to p-GaN  

SciTech Connect (OSTI)

The significant effect of the thickness of Ni film on the performance of the Ohmic contact of Ni/Au to p-GaN is studied. The Ni/Au metal films with thickness of 15/50?nm on p-GaN led to better electrical characteristics, showing a lower specific contact resistivity after annealing in the presence of oxygen. Both the formation of a NiO layer and the evolution of metal structure on the sample surface and at the interface with p-GaN were checked by transmission electron microscopy and energy-dispersive x-ray spectroscopy. The experimental results indicate that a too thin Ni film cannot form enough NiO to decrease the barrier height and get Ohmic contact to p-GaN, while a too thick Ni film will transform into too thick NiO cover on the sample surface and thus will also deteriorate the electrical conductivity of sample.

Li, X. J.; Zhao, D. G., E-mail: dgzhao@red.semi.ac.cn; Jiang, D. S.; Liu, Z. S.; Chen, P.; Zhu, J. J.; Le, L. C.; Yang, J.; He, X. G. [State Key Laboratory on Integrated Optoelectronics, Institute of Semiconductors, Chinese Academy of Science, P.O. Box 912, Beijing 100083 (China); Zhang, S. M.; Zhang, B. S.; Liu, J. P. [Suzhou Institute of Nano-tech and Nano-bionics, Chinese Academy of Sciences, Suzhou 215123 (China); Yang, H. [State Key Laboratory on Integrated Optoelectronics, Institute of Semiconductors, Chinese Academy of Science, P.O. Box 912, Beijing 100083 (China); Suzhou Institute of Nano-tech and Nano-bionics, Chinese Academy of Sciences, Suzhou 215123 (China)

2014-10-28T23:59:59.000Z

483

Phase Evolution in the Pd-Ag-CuO Air Braze Filler Metal Alloy System  

SciTech Connect (OSTI)

Palladium was added as a ternary component to a series of copper oxide-silver alloys in an effort to increase the use temperature of these materials for potential ceramic air brazing applications. Phase equilibria in the ternary Pd-Ag-CuO system were investigated via differential scanning calorimetry (DSC) and a series of quenching experiments. Presented here are the latest findings on this system and a construction of the corresponding ternary phase diagram for low-to-moderate additions of palladium. The analysis included samples with higher palladium additions than were studied in the past, as well as an analysis of the composition-temperature trends in the Ag-CuO miscibility gap with palladium addition. It was found that the addition of palladium increases the solidus and liquidus and caused three phase zones to appear as expected by the phase rule. Furthermore, the palladium additions cause the miscibility gap boundary extending from the former binary eutectic to shift to lower silver-to-copper ratios.

Darsell, Jens T.; Weil, K. Scott

2006-08-01T23:59:59.000Z

484

Q-dependence of the spin fluctuations in the intermediate valence compound CePd3  

SciTech Connect (OSTI)

We report inelastic neutron scattering experiments on a single crystal of the intermediate valence compound CePd3. At 300 K the magnetic scattering is quasielastic, with half-width G = 23 meV, and is independent of momentum transfer Q. At low temperature, the Q-averaged magnetic spectrum is inelastic, exhibiting a broad peak centered near E-max = 55 meV. These results, together with the temperature dependence of the susceptibility, 4f occupation number, and specific heat, can be fit by the Kondo/Anderson impurity model. The low temperature scattering near Emax, however, shows significant variations with Q, reflecting the coherence of the 4f lattice. The intensity is maximal at (1/2, 1/2, 0), intermediate at (1/2, 0, 0) and (0, 0, 0), and weak at (1/2, 1/2, 1/2). We discuss this Q-dependence in terms of current ideas about coherence in heavy fermion systems.

Fanelli, V. R.; Lawrence, J. M.; Goremychkin, E. A.; Osborn, R.; Bauer, E. D.; McClellan, K. J.; Thompson, J. D.; Booth, C. H.; Christianson, A. D.; Riseborough, P. S.

2014-06-25T23:59:59.000Z

485

Superconductivity and Physical Properties of CaPd2Ge2 Single Crystals  

SciTech Connect (OSTI)

We present the superconducting and normal state properties of CaPd2Ge2 single crystals investigated by magnetic susceptibility ?, isothermal magnetization M, heat capacity Cp, in-plane electrical resistivity ? and London penetration depth ? versus temperature T and magnetic field H measurements. Bulk superconductivity is inferred from the ?(T) and Cp(T) data. The ?(T) data exhibit metallic behavior and a superconducting transition with Tc onset = 1.98 K and zero resistivity at Tc 0 = 1.67 K. The ?(T) reveals the onset of superconductivity at 2.0 K. For T > 2.0 K, the ?(T) and M(H) are weakly anisotropic paramagnetic with ?ab > ?c. The Cp(T) data confirm the bulk superconductivity below Tc = 1.69(3) K. The superconducting state electronic heat capacity is analyzed within the framework of a single-band ?-model of BCS superconductivity and various normal and superconducting state parameters are estimated. Within the ?-model, the Cp(T) data and the ab plane ?(T) data consistently indicate a moderately anisotropic s-wave gap with ?(0)/kBTc ? 1.6, somewhat smaller than the BCS value of 1.764. The relationship of the heat capacity jump at Tc and the penetration depth measurement to the anisotropy in the s-wave gap is discussed.

Anand, V K [Ames Laboratory; Kim, Hyunsoo [Ames Laboratory; Tanatar, Makariy A [Ames Laboratory; Prozorov, Ruslan [Ames Laboratory; Johnston, David C [Ames Laboratory

2014-10-08T23:59:59.000Z

486

Facile approach to prepare hollow core–shell NiO microspherers for supercapacitor electrodes  

SciTech Connect (OSTI)

A facile lamellar template method (see image) has been developed for the preparation of uniform hollow core–shell structure NiO (HCS–NiO) with a nanoarchitectured wall structure. The prepared NiO was found to be highly crystalline in uniform microstructures with high specific surface area and pore volume. The results indicated that ethanol interacted with trisodium citrate played an important role for the formation of hollow core–shell spheres. On the basis of the analysis of the composition and the morphology, a possible formation mechanism was investigated. NiO microspheres with hollow core–shell showed excellent capacitive properties. The exceptional cyclic, structural and electrochemical stability with ?95% coulombic efficiency, and very low ESR value from impedance measurements promised good utility value of hollow core–shell NiO material in fabricating a wide range of high-performance electrochemical supercapacitors. - The hollow core–shell NiO was prepared with a facile lamellar template method. The prepared NiO show higher capacitance, lower ion diffusion resistance and better electroactive surface utilization for Faradaic reactions. - Highlights: • Formation of hollow core–shell NiO via a novel and facile precipitation route. • Exhibited uniform feature sizes and high surface area of hollow core–shell NiO. • Synthesized NiO has high specific capacitance ( 448 F g{sup 1}) and very low ESR value. • Increased 20% of long life cycles capability after 500 charge–discharge cycles.

Han, Dandan [Key Laboratory of Superlight Materials and Surface Technology, Ministry of Education, Harbin Engineering University, Harbin 150001 (China); College of Chemistry and Pharmaceutical Engineering, Jilin Institute of Chemical Technology, Jilin 132022 (China); Xu, Pengcheng [College of Chemistry and Pharmaceutical Engineering, Jilin Institute of Chemical Technology, Jilin 132022 (China); Jing, Xiaoyan [Key Laboratory of Superlight Materials and Surface Technology, Ministry of Education, Harbin Engineering University, Harbin 150001 (China); Wang, Jun, E-mail: zhqw1888@sohu.com [Key Laboratory of Superlight Materials and Surface Technology, Ministry of Education, Harbin Engineering University, Harbin 150001 (China); Institute of Advanced Marine Materials, Harbin Engineering University, Harbin 150001 (China); Song, Dalei; Liu, Jingyuan; Zhang, Milin [Key Laboratory of Superlight Materials and Surface Technology, Ministry of Education, Harbin Engineering University, Harbin 150001 (China)

2013-07-15T23:59:59.000Z

487

Electronic structure of Co-Ni-Ga Heusler alloys studied by resonant photoemission  

SciTech Connect (OSTI)

The electronic structures of Co{sub 2.01}Ni{sub 1.05}Ga{sub 0.94} and Co{sub 1.76}Ni{sub 1.46}Ga{sub 0.78} Heusler alloys have been investigated by resonant photoemission spectroscopy across the 3p-3d transition of Co and Ni. For the Ni excess composition Co{sub 1.76}Ni{sub 1.46}Ga{sub 0.78}, the valence band peak shows a shift of 0.25 eV as compared to the near stoichiometric composition Co{sub 2.01}N1{sub 1.05}Ga{sub 0.94}. Also an enhancement is observed in the Ni related satellite features in the valence band for the Ni excess composition. Due to hybridization of Co and Ni 3d states in these systems, the Co and Ni 3p-3d resonance energies are found to be higher as compared to Co and Ni metals. Theoretical first principle calculation is performed to understand the features in the valence band and the shape of the resonance profile.

Baral, Madhusmita, E-mail: madhusmita@rrcat.gov.in; Banik, Soma, E-mail: madhusmita@rrcat.gov.in; Ganguli, Tapas, E-mail: madhusmita@rrcat.gov.in; Chakrabarti, Aparna, E-mail: madhusmita@rrcat.gov.in; Deb, S. K. [Indus Synchrotrons Utilization Division, Raja Ramanna Centre for Advanced Technology, Indore-452013 (India); Thamizhavel, A. [Tata Institute of Fundamental Research, Homi Bhabha Road, Colaba, Mumbai 400005 (India); Wadikar, Avinash; Phase, D. M. [UGC-DAE Consortium for Scientific Research, University Campus, Khandwa Road, Indore-452017 (India)

2014-04-24T23:59:59.000Z

488

Proton spectroscopy of 48Ni, 46Fe, and 44Cr  

E-Print Network [OSTI]

Results of decay spectroscopy on nuclei in vicinity of the doubly magic 48Ni are presented. The measurements were performed with a Time Projection Chamber with optical readout which records tracks of ions and protons in the gaseous volume. Six decays of 48Ni including four events of two-proton ground-state radioactivity were recorded. An advanced reconstruction procedure yielded the 2p decay energy for 48Ni of Q2p = 1.29(4) MeV. In addition, the energy spectra of \\b{eta}-delayed protons emitted in the decays of 44Cr and 46Fe, as well as half-lives and branching ratios were determined. The results were found to be consistent with the previous measurements made with Si detectors. A new proton line in the decay of 44Cr corresponding to the decay energy of 760 keV is reported. The first evidence for the \\b{eta}2p decay of 46 Fe, based on one clear event, is shown.

M. Pomorski; M. Pfützner; W. Dominik; R. Grzywacz; A. Stolz; T. Baumann; J. S. Berryman; H. Czyrkowski; R. D?browski; A. Fija?kowska; T. Ginter; J. Johnson; G. Kami?ski; N. Larson; S. N. Liddick; M. Madurga; C. Mazzocchi; S. Mianowski; K. Miernik; D. Miller; S. Paulauskas; J. Pereira; K. P. Rykaczewski; S. Suchyta

2014-07-06T23:59:59.000Z