Powered by Deep Web Technologies
Note: This page contains sample records for the topic "newable fuels oxygenates" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

Fuel Ethanol Oxygenate Production  

Gasoline and Diesel Fuel Update (EIA)

Product: Fuel Ethanol Methyl Tertiary Butyl Ether Merchant Plants Captive Plants Period-Unit: Monthly-Thousand Barrels Monthly-Thousand Barrels per Day Annual-Thousand Barrels Annual-Thousand Barrels per Day Product: Fuel Ethanol Methyl Tertiary Butyl Ether Merchant Plants Captive Plants Period-Unit: Monthly-Thousand Barrels Monthly-Thousand Barrels per Day Annual-Thousand Barrels Annual-Thousand Barrels per Day Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Show Data By: Product Area May-13 Jun-13 Jul-13 Aug-13 Sep-13 Oct-13 View History U.S. 27,197 26,722 26,923 26,320 25,564 27,995 1981-2013 East Coast (PADD 1) 628 784 836 842 527 636 2004-2013 Midwest (PADD 2) 25,209 24,689 24,786 24,186 23,810 26,040 2004-2013 Gulf Coast (PADD 3) 523 404 487 460 431 473 2004-2013 Rocky Mountain (PADD 4) 450 432 430 432 415 429 2004-2013 West Coast (PADD 5)

2

Advantages of Oxygenates Fuels over Gasoline in Direct Injection...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Advantages of Oxygenates Fuels over Gasoline in Direct Injection Spark Ignition Engines Advantages of Oxygenates Fuels over Gasoline in Direct Injection Spark Ignition Engines...

3

Oxygen Carriers for Solid Fuel Chemical Looping Combustion Process...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Oxygen Carriers for Solid Fuel Chemical Looping Combustion Process Regenerable Mixed Copper-Iron-Inert Support Oxygen Carriers National Energy Technology Laboratory Contact NETL...

4

Oxygenated fuels for clean heavy-duty diesel engines  

Science Journals Connector (OSTI)

For diesel engines, changing the fuel composition is an alternative route towards achieving lower emission levels. The potential of oxygenated fuels to significantly reduce particulate matter emissions has already been demonstrated earlier. In this study, this research has been extrapolated towards lower emission levels. Exhaust gas recirculation (EGR) was applied to a modern EURO-3-type HD diesel engine. Tests were done at different engine working points, with EGR-levels and start of fuel delivery timings set to give NOx emissions between 3.5 and 2.0 g/kWh with regular diesel fuel. Fourteen blends of a low-sulphur diesel fuel respectively of a gas-to-liquid synthetic diesel fuel with different oxygenates were tested. The corresponding fuel matrix covers a range of fuel oxygen mass fractions up to 15%. Results are presented and the impact of fuel oxygen mass fraction and Cetane Number are analysed and compared with results from previous research.

P.J.M. Frijters; R.S.G. Baert

2006-01-01T23:59:59.000Z

5

High-Velocity Oxygen Fuel Thermal Spray of Fe-Based Amorphous Alloy: a Numerical and Experimental Study  

E-Print Network [OSTI]

High-Velocity Oxygen Fuel Thermal Spray of Fe-Basedusing a high velocity oxygen fuel (HVOF) spray processstructure. [12] High velocity oxygen fuel (HVOF) thermal

Ajdelsztajn, L.; Dannenberg, J.; Lopez, J.; Yang, N.; Farmer, J.; Lavernia, E. J.

2009-01-01T23:59:59.000Z

6

Oxygen Hydration Mechanism for the Oxygen Reduction Reaction at Pt and Pd Fuel Cell Catalysts  

Science Journals Connector (OSTI)

Oxygen Hydration Mechanism for the Oxygen Reduction Reaction at Pt and Pd Fuel Cell Catalysts ... Catalytic Reactions on the Open-Edge Sites of Nitrogen-Doped Carbon Nanotubes as Cathode Catalyst for Hydrogen Fuel Cells ... Despite significant progress made the past decade on reducing the platinum catalyst loading in the PEMFC electrodes, further ... ...

Yao Sha; Ted H. Yu; Boris V. Merinov; Pezhman Shirvanian; William A. Goddard; III

2011-02-24T23:59:59.000Z

7

Catalytic ignition of fuel/oxygen/nitrogen mixtures over platinum  

SciTech Connect (OSTI)

Ignition of fuel/oxygen/nitrogen mixtures over platinum wire is experimentally studied by using microcalorimetry and by restricting the flow to the low Reynolds number range so that axisymmetry prevails. The fuels studied are propane, butane, propylene, ethylene, carbon monoxide, and hydrogen. Parameters investigated include flow velocity, fuel type and concentration, and oxygen concentration. The catalytic ignition temperatures of the various fuels are accurately determined over extensive ranges of fuel/oxygen/nitrogen concentrations. Results show two distinctly opposite ignition trends depending on the nature of the fuel. That is, the ignition temperature of lean propane/air and butane/air mixtures decreases as their fuel concentration is increased, while the reverse trend is observed for lean mixtures of propylene, ethylene, carbon monoxide, and hydrogen with air. Furthermore, the ignition of propane depends primarily on fuel concentration, while the ignition of carbon monoxide depends on fuel and oxygen concentrations to a comparable extent. These results are explained on the basis of hierarchical surface adsorption strengths of the different reactants in effecting catalytic ignition. Additional phenomena of interest are observed and discussed.

Cho, P.; Law, C.K.

1986-11-01T23:59:59.000Z

8

Oxygen electrode reaction in molten carbonate fuel cells  

SciTech Connect (OSTI)

Molten carbonate fuel cell system is a leading candidate for the utility power generation because of its high efficiency for fuel to AC power conversion, capability for an internal reforming, and a very low environmental impact. However, the performance of the molten carbonate fuel cell is limited by the oxygen reduction reaction and the cell life time is limited by the stability of the cathode material. An elucidation of oxygen reduction reaction in molten alkali carbonate is essential because overpotential losses in the molten carbonate fuel cell are considerably greater at the oxygen cathode than at the fuel anode. Oxygen reduction on a fully-immersed gold electrode in a lithium carbonate melt was investigated by electrochemical impedance spectroscopy and cyclic voltammetry to determine electrode kinetic and mass transfer parameters. The dependences of electrode kinetic and mass transfer parameters on gas composition and temperature were examined to determine the reaction orders and the activation energies. The results showed that oxygen reduction in a pure lithium carbonate melt occurs via the peroxide mechanism. A mass transfer parameter, D{sub O}{sup 1/2}C{sub O}, estimated by the cyclic voltammetry concurred with that calculated by the EIS technique. The temperature dependence of the exchange current density and the product D{sub O}{sup 1/2}C{sub O} were examined and the apparent activation energies were determined to be about 122 and 175 kJ/ mol, respectively.

Appleby, A.J.; White, R.E.

1992-07-07T23:59:59.000Z

9

IMPACT OF OXYGENATED FUEL ON DIESEL ENGINE PERFORMANCE AND EMISSIONS  

SciTech Connect (OSTI)

As evidenced by recent lawsuits brought against operators of large diesel truck fleets [1] and by the Consent Decree brought against the heavy-duty diesel manufacturers [2], the environmental and health effects of diesel engine emissions continue to be a significant concern. Reduction of diesel engine emissions has traditionally been achieved through a combination of fuel system, combustion chamber, and engine control modifications [3]. Catalytic aftertreatment has become common on modern diesel vehicles, with the predominant device being the diesel oxidation catalytic converter [3]. To enable advanced after-treatment devices and to directly reduce emissions, significant recent interest has focused on reformulation of diesel fuel, particularly the reduction of sulfur content. The EPA has man-dated that diesel fuel will have only 15 ppm sulfur content by 2007, with current diesel specifications requiring around 300 ppm [4]. Reduction of sulfur will permit sulfur-sensitive aftertreatment devices, continuously regenerating particulate traps, NOx control catalysts, and plasma assisted catalysts to be implemented on diesel vehicles [4]. Another method of reformulating diesel fuel to reduce emissions is to incorporate oxygen in the fuel, as was done in the reformulation of gasoline. The use of methyl tertiary butyl ether (MTBE) in reformulated gasoline has resulted in contamination of water resources across the country [5]. Nonetheless, by relying on the lessons learned from MTBE, oxygenation of diesel fuel may be accomplished without compromising water quality. Oxygenation of diesel fuel offers the possibility of reducing particulate matter emissions significantly, even for the current fleet of diesel vehicles. The mechanism by which oxygen content leads to particulate matter reductions is still under debate, but recent evidence shows clearly that ''smokeless'' engine operation is possible when the oxygen content of diesel fuel reaches roughly 38% by weight [6]. The potential improvements in energy efficiency within the transportation section, particularly in sport utility vehicles and light-duty trucks, that can be provided by deployment of diesel engines in passenger cars and trucks is a strong incentive to develop cleaner burning diesel engines and cleaner burning fuels for diesel engines. Thus, serious consideration of oxygenated diesel fuels is of significant practical interest and value to society. In the present work, a diesel fuel reformulating agent, CETANERTM, has been examined in a popular light-medium duty turbodiesel engine over a range of blending ratios. This additive is a mixture of glycol ethers and can be produced from dimethyl ether, which itself can be manufactured from synthesis gas using Air Products' Liquid Phase Dimethyl Ether (LPDME TM) technology. CETANERTM is a liquid, has an oxygen content of 36 wt.%, has a cetane number over 100 and is highly miscible in diesel fuel. This combination of physical and chemical properties makes CETANERTM an attractive agent for oxygenating diesel fuel. The present study considered CETANERTM ratios from 0 to 40 wt.% in a California Air Resources Board (CARB) specification diesel fuel. Particulate matter emissions, gaseous emissions and in-cylinder pressure traces were monitored over the AVL 8-Mode engine test protocol [7]. This paper presents the results from these measurements and discusses the implications of using high cetane number oxygenates in diesel fuel reformulation.

Boehman, Andre L.

2000-08-20T23:59:59.000Z

10

Characteristics of Exhaust Diesel Particles from Different Oxygenated Fuels  

Science Journals Connector (OSTI)

Characteristics of Exhaust Diesel Particles from Different Oxygenated Fuels ... The characteristic variations of exhaust particles were investigated on a light-duty diesel engine. ... This study was conducted on a 2005 model-year light-duty diesel engine that meets Chinese national stage III emission standards (equivalent to Euro III emission standards) without any exhaust control device. ...

Zhen Xu; Xinling Li; Chun Guan; Zhen Huang

2013-12-02T23:59:59.000Z

11

The performance of PEM fuel cells fed with oxygen through the free-convection mode  

E-Print Network [OSTI]

The performance of PEM fuel cells fed with oxygen through the free-convection mode Pei-Wen Li; accepted 27 September 2002 Abstract The feasibility and restrictions of feeding oxygen to a PEM fuel cell in the fuel cell. Experimental tests were conducted for one PEM fuel cell stack and two single PEM fuel cell

12

Novel New Oxygen Carriers for Chemical Looping Combustion of Solid Fuels  

Science Journals Connector (OSTI)

Novel New Oxygen Carriers for Chemical Looping Combustion of Solid Fuels ... A loop of chem. ... Energy Combust. ...

Yueying Fan; Ranjani Siriwardane

2014-02-21T23:59:59.000Z

13

Effect of Oxygenated Fuel on Combustion and Emissions in a Light-Duty Turbo Diesel Engine  

Science Journals Connector (OSTI)

The influence of fuel oxygen content on soot reduction in diesel engines is well-known. ... Fuel consumption was determined by weighing the fuel at the beginning and end of each test mode or each fuel blend through a Sartorius precision scale, with an accuracy of ±2 g. ... studies on effects of oxygenated fuels in conjunction with single and split fuel injections were conducted at high and low loads on a Caterpillar SCOTE DI diesel engine. ...

Juhun Song; Kraipat Cheenkachorn; Jinguo Wang; Joseph Perez; André L. Boehman; Philip John Young; Francis J. Waller

2002-01-15T23:59:59.000Z

14

Alkaline Microfluidic Hydrogen-Oxygen Fuel Cell as a Cathode Characterization Platform  

E-Print Network [OSTI]

Alkaline Microfluidic Hydrogen-Oxygen Fuel Cell as a Cathode Characterization Platform Fikile R of hydrogen H2 and oxygen O2 . Operating fuel cells in alkaline media, as opposed to acidic media, has on an alkaline microfluidic fuel cell for catalyst and electrode characterization. Its constantly refreshing

Kenis, Paul J. A.

15

Doped Graphene as a Material for Oxygen Reduction Reaction in Hydrogen Fuel Cells: A Computational Study  

E-Print Network [OSTI]

Doped Graphene as a Material for Oxygen Reduction Reaction in Hydrogen Fuel Cells: A Computational be used to make an efficient and relatively inexpensive graphene-based material for hydrogen fuel cells fuel cells for oxygen reduction at the cathode. In an attempt to find a cheap yet efficient catalyst

Krasheninnikov, Arkady V.

16

Hydrous oxide species as inhibitors of oxygen reduction at platinum activated fuel cell cathodes  

Science Journals Connector (OSTI)

The successful development of a methanol/air fuel cell requires optimum performance of the air/ oxygen cathode at about 0.8 V vs RHE. ... oxygen gas reduction on platinum (the best electrocatalyst for this reacti...

L. D. Burke; J. K. Casey; J. A. Morrissey…

1994-01-01T23:59:59.000Z

17

Oxygen diffusion in solid oxide fuel cell cathode and electrolyte materials: mechanistic insights from atomistic simulations  

E-Print Network [OSTI]

Oxygen diffusion in solid oxide fuel cell cathode and electrolyte materials: mechanistic insights to drive fast ionic transport. 1. Introduction The interest in Solid Oxide Fuel Cell (SOFC) technology. Current targets of cost and durability necessitate solid oxide fuel cells to operate in the intermediate

Yildiz, Bilge

18

Assessment of the use of oxygenated fuels on emissions and performance of a diesel engine  

Science Journals Connector (OSTI)

Abstract Requirements as torque, power, specific fuel consumption and emitted compounds are highly influenced by the chemical composition of the fuel being burned. Thus, the aim of this study was to assess the use of oxygenated fuels on emissions of NOx, CO, HC, CO2 and particle number and size distribution (11.5 diesel engine coupled to a dynamometer bench was used, where three types of fuels were employed, B5 (diesel with 5% of biodiesel); B5E6 (ternary composition containing 89% diesel, 5% of biodiesel and 6% of ethanol); and B100 (100% of biodiesel). The performance of a diesel engine was also evaluated to see the impact of the oxygenated fuels in this kind of engine. The use of ethanol with high latent heat of vaporization and low cetane number added to the binary blend (B5) shown an increase in the HC emissions and a reduction in \\{NOx\\} emissions when compared to B5. The use of pure biodiesel (B100) with high oxygen content showed a reduction in the HC emissions, but presented the highest emissions for both \\{NOx\\} and particle number of smaller diameter among the studied fuels. The use of more oxygenated fuels reduced the power output and increased the fuel consumption, but the exergy analysis showed that the energy efficiency of these fuels could be considered similar to the B5 fuel.

Lílian Lefol Nani Guarieiro; Egídio Teixeira de Almeida Guerreiro; Keize Katiane dos Santos Amparo; Victor Bonfim Manera; Ana Carla D. Regis; Aldenor Gomes Santos; Vitor P. Ferreira; Danilo J. Leão; Ednildo A. Torres; Jailson B. de Andrade

2014-01-01T23:59:59.000Z

19

Investigation of Coal Fueled Chemical Looping Combustion Using Fe3O4 as Oxygen Carrier  

Science Journals Connector (OSTI)

Chemical-looping combustion (CLC) is a novel combustion technique with CO2 separation. Magnetite (Fe3O4) was selected as the oxygen carrier and Shenhua coal (Inner Mongolia, China) as the fuel for this study. The...

Wenguo Xlang; Xiaoyan Sun; Sha Wangt…

2010-01-01T23:59:59.000Z

20

Hydrogen and oxygen permeation through Nafion 117 and XUS 13204.10 fuel cell membranes  

E-Print Network [OSTI]

HYDROGEN AND OXYGEN PERMEATION THROUGH NAFION 117 AND XUS 13204. 10 FUEL CELL MEMBRANES A Thesis by STEVEN RAY LEE Submitted to the Office of Graduate Studies of Texas AdrM University in partial fulfillment of the requirement for the degree... of MASTER OF SCIENCE August 1992 Major Subject Chemical Engineering HYDROGEN AND OXYGEN PERMEATION THROUGH NAFION 117 AND XUS 13204. 10 FUEL CELL MEMBRANES A Thesis by STEVEN RAY LEE Approved as to style and content by: Ralph E. White (Chair...

Lee, Steven Ray

1992-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "newable fuels oxygenates" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Recovery Act: Novel Oxygen Carriers for Coal-fueled Chemical Looping  

SciTech Connect (OSTI)

Chemical Looping Combustion (CLC) could totally negate the necessity of pure oxygen by using oxygen carriers for purification of CO{sub 2} stream during combustion. It splits the single fuel combustion reaction into two linked reactions using oxygen carriers. The two linked reactions are the oxidation of oxygen carriers in the air reactor using air, and the reduction of oxygen carriers in the fuel reactor using fuels (i.e. coal). Generally metal/metal oxides are used as oxygen carriers and operated in a cyclic mode. Chemical looping combustion significantly improves the energy conversion efficiency, in terms of the electricity generation, because it improves the reversibility of the fuel combustion process through two linked parallel processes, compared to the conventional combustion process, which is operated far away from its thermo-equilibrium. Under the current carbon-constraint environment, it has been a promising carbon capture technology in terms of fuel combustion for power generation. Its disadvantage is that it is less mature in terms of technological commercialization. In this DOE-funded project, accomplishment is made by developing a series of advanced copper-based oxygen carriers, with properties of the higher oxygen-transfer capability, a favorable thermodynamics to generate high purity of CO{sub 2}, the higher reactivity, the attrition-resistance, the thermal stability in red-ox cycles and the achievement of the auto-thermal heat balance. This will be achieved into three phases in three consecutive years. The selected oxygen carriers with final-determined formula were tested in a scaled-up 10kW coal-fueled chemical looping combustion facility. This scaled-up evaluation tests (2-day, 8-hour per day) indicated that, there was no tendency of agglomeration of copper-based oxygen carriers. Only trace-amount of coke or carbon deposits on the copper-based oxygen carriers in the fuel reactor. There was also no evidence to show the sulphidization of oxygen carriers in the system by using the high-sulfur-laden asphalt fuels. In all, the scaled-up test in 10 kW CLC facility demonstrated that the preparation method of copper-based oxygen carrier not only help to maintain its good reactivity, also largely minimize its agglomeration tendency.

Pan, Wei-Ping; Cao, Yan

2012-11-30T23:59:59.000Z

22

Method and apparatus for assessing distillate-fuel stability by oxygen overpressure  

SciTech Connect (OSTI)

Reactions leading to insoluble sediments formation in distillate fuel are accelerated by forcing oxygen into solution in the fuel at pressures of between about 90 and 110 psig and then stressing the fuel under conditions of accelerated storage at temperatures of between about 40 C to 100 C. The method then makes use of gravimetric determination of the total insoubles formed. The stability of the fuel over a period of time as well as its comparitive stability to other fuels can then be predicted from the amount of insolubles formed. The method can be carried out by using a specialized pressure vessel.

Hardy, D.R.; Beal, E.J.; Burnett, J.C.

1989-06-27T23:59:59.000Z

23

Mechanism for Oxygen Reduction Reaction on Pt3Ni Alloy Fuel Cell Boris V. Merinov,*,  

E-Print Network [OSTI]

, at the cathode of a polymer electrolyte membrane fuel cell (PEMFC) is a critical issue for commercial applicationMechanism for Oxygen Reduction Reaction on Pt3Ni Alloy Fuel Cell Cathode Yao Sha, Ted H. Yu, Boris of this type of fuel cells.1-4 The best current catalysts are Pt and Pt-based binary alloys, such as Pt3Ni.5

Goddard III, William A.

24

Mechanism for Oxygen Reduction Reaction on Pt3Ni Alloy Fuel Cell Cathode  

Science Journals Connector (OSTI)

The efficiency of the oxygen reduction reaction (ORR), 4H+ + 4e– + O2 ? 2H2O, at the cathode of a polymer electrolyte membrane fuel cell (PEMFC) is a critical issue for commercial application of this type of fuel cells. ... This agrees with the volcano-like trend for ORR catalysts,(7, 31, 32) when the activity first increases and then decreases as the catalyst d-band center shifts downward. ... Improved Non-Pt Alloys for the Oxygen Reduction Reaction at Fuel Cell Cathodes Predicted from Quantum Mechanics ...

Yao Sha; Ted H. Yu; Boris V. Merinov; Pezhman Shirvanian; William A. Goddard; III

2012-09-04T23:59:59.000Z

25

Oxygen Electrocatalysts for Water Electrolyzers and Reversible Fuel Cells: Status and Perspective  

SciTech Connect (OSTI)

Hydrogen production by electrochemical water electrolysis has received great attention as an alternative technology for energy conversion and storage. The oxygen electrode has a substantial effect on the performance and durability in water electrolyzers and reversible fuel cells because of its intrinsically slow kinetics for oxygen evolution/reduction and poor durability under harsh operating environments. To improve oxygen kinetics and durability of the electrode, extensive studies for highly active and stable oxygen electrocatalyst have been performed. However, due to the thermodynamic instability of transition metals in acidic media, noble metal compounds have been primarily utilized as electrocatalysts in water electrolyzers and reversible fuel cells. For water electrolyzer applications, single noble metal oxides such as ruthenium oxide and iridium oxide have been studied, and binary or ternary metal oxides have been developed to take synergestic effects of each component. On the other hand, a variety of bifunctional electrocatalysts with a combination of monofunctional electrocatalysts such as platinum for oxygen reduction and iridium oxide for oxygen evolution for reversible fuel cell applications have been mainly proposed. Practically, supported iridium oxide-on-platinum, its reverse type, and non-precious metal-supported platinum and iridium bifunctional electrocatalysts have been developed. Recent theoretical calculations and experimental studies in terms of water electrolysis and fuel cell technology suggest effective ways to cope with current major challenges of cost and durability of oxygen electrocatalysts for technical applications.

Park, Seh Kyu; Shao, Yuyan; Liu, Jun; Wang, Yong

2012-11-01T23:59:59.000Z

26

Oxygen electrode reaction in molten carbonate fuel cells. Final report, September 15, 1987--September 14, 1990  

SciTech Connect (OSTI)

Molten carbonate fuel cell system is a leading candidate for the utility power generation because of its high efficiency for fuel to AC power conversion, capability for an internal reforming, and a very low environmental impact. However, the performance of the molten carbonate fuel cell is limited by the oxygen reduction reaction and the cell life time is limited by the stability of the cathode material. An elucidation of oxygen reduction reaction in molten alkali carbonate is essential because overpotential losses in the molten carbonate fuel cell are considerably greater at the oxygen cathode than at the fuel anode. Oxygen reduction on a fully-immersed gold electrode in a lithium carbonate melt was investigated by electrochemical impedance spectroscopy and cyclic voltammetry to determine electrode kinetic and mass transfer parameters. The dependences of electrode kinetic and mass transfer parameters on gas composition and temperature were examined to determine the reaction orders and the activation energies. The results showed that oxygen reduction in a pure lithium carbonate melt occurs via the peroxide mechanism. A mass transfer parameter, D{sub O}{sup 1/2}C{sub O}, estimated by the cyclic voltammetry concurred with that calculated by the EIS technique. The temperature dependence of the exchange current density and the product D{sub O}{sup 1/2}C{sub O} were examined and the apparent activation energies were determined to be about 122 and 175 kJ/ mol, respectively.

Appleby, A.J.; White, R.E.

1992-07-07T23:59:59.000Z

27

Effects of altitude and fuel oxygen content on the performance of a high pressure common rail diesel engine  

Science Journals Connector (OSTI)

Abstract The change of intake oxygen content caused by altitude variation and the change of fuel oxygen content both affect the performance of diesel engines. In this paper, comparative experiments were performed on a high pressure common rail diesel engine fueled with pure diesel and biodiesel–ethanol–diesel (abbreviated as BED) blends with oxygen content of 2%, 2.5%, and 3.2% in mass percentage at different atmospheric pressures of 81 kPa, 90 kPa, and 100 kPa. Moreover, in order to study the effect of different fuel blends with the same oxygen content on the performance of the diesel engine, tests were conducted on the diesel engine fueled with the BED blend and a biodiesel–diesel (abbreviated as BD) blend at 81 kPa ambient pressure. The experimental results indicate that the influence of altitude variation on the full-load engine brake torque is not significant when the pure diesel fuel is used. With the increase of BED fuel oxygen content, the engine brake torque reduces. When the pure diesel fuel is used, with the increase of atmospheric pressure, the brake specific fuel consumption (BSFC) decreases. As the fuel oxygen content increases, there is no significant difference in brake specific fuel consumption of the BED blends. And the values of brake specific energy consumption (BSEC) gradually decrease. Soot emissions of the diesel engine decrease with the increase of atmospheric pressure and fuel oxygen content. The effect of soot emission reduction by increasing the oxygen content of the fuel is more significant than the effect of increasing atmospheric pressure. The effects of BD and BED fuels with basically the same oxygen content on the full-load performance, fuel economy, and soot emissions of the diesel engine are different. The BSFC and soot emissions of the BED fuel are lower than those of the BD fuel.

Shaohua Liu; Lizhong Shen; Yuhua Bi; Jilin Lei

2014-01-01T23:59:59.000Z

28

Chemical looping gasification of solid fuels using bimetallic oxygen carrier particles – Feasibility assessment and process simulations  

Science Journals Connector (OSTI)

Abstract The chemical looping gasification (CLG) process utilizes an iron-based oxygen carrier to convert carbonaceous fuels into hydrogen and electricity while capturing CO2. Although the process has the potential to be efficient and environmentally friendly, the activity of the iron-based oxygen carrier is relatively low, especially for solid fuel conversion. In the present study, we propose to incorporate a secondary oxygen carrying metal oxide, i.e. CuO, to the iron-based oxygen carrier. Using the “oxygen-uncoupling” characteristics of CuO, gaseous oxygen is released at a high temperature to promote the conversion of both Fe2O3 and coal. Experiments carried out using a Thermal-Gravimetric Analyzer (TGA) indicate that a bimetallic oxygen carrier consisting of a small amount (5% by weight) of CuO is more effective for coal char conversion when compared to oxygen carrier without copper addition. ASPEN Plus® simulations and mathematical modeling of the process indicate that the incorporation of a small amount of copper leads to increased hydrogen yield and process efficiency.

Feng He; Nathan Galinsky; Fanxing Li

2013-01-01T23:59:59.000Z

29

Oxygen Reactivity of Devolatilized Diesel Engine Particulates from Conventional and Biodiesel Fuels  

Science Journals Connector (OSTI)

Oxygen Reactivity of Devolatilized Diesel Engine Particulates from Conventional and Biodiesel Fuels ... Abatement of diesel particulates has led to an overall decrease in the fuel efficiency of diesel engines, and overcoming these losses has been one of the more challenging problems in exhaust aftertreatment. ... (16-18) Establishing a general physical basis for modeling diesel particulate oxidation is especially challenging because of the large variations in microscopic structure that it can have. ...

Andrea Strzelec; Todd J. Toops; C. Stuart Daw

2013-06-10T23:59:59.000Z

30

Comparison of the Impact of Intake Oxygen Enrichment and Fuel Oxygenation on Diesel Combustion and Emissions  

Science Journals Connector (OSTI)

turbocharged, Intercooler?(air-air), electronically?controlled?EGR with?actuator ... Fumigation into the intake surge tank was chosen to allow thorough mixing of the oxygen?air mixture through the subsequent components of the intake system, such as the air filter, turbocharger, and intercooler, before entering the intake manifold. ...

Juhun Song; Vince Zello; André L. Boehman; Francis J. Waller

2004-07-10T23:59:59.000Z

31

Mechanisms of Oxygen Reduction Reaction on Nitrogen-Doped Graphene for Fuel Cells  

Science Journals Connector (OSTI)

Mechanisms of Oxygen Reduction Reaction on Nitrogen-Doped Graphene for Fuel Cells ... At each step, the optimization structure was obtained, and adsorption energy for these molecules on the N-graphene was calculated. ... In this figure, for the first step, the reference energy state is the total energy of optimized N-graphene and OOH molecules. ...

Lipeng Zhang; Zhenhai Xia

2011-05-17T23:59:59.000Z

32

Effect of Microstructure of Nitrogen-Doped Graphene on Oxygen Reduction Activity in Fuel Cells  

Science Journals Connector (OSTI)

Effect of Microstructure of Nitrogen-Doped Graphene on Oxygen Reduction Activity in Fuel Cells ... The optimized structures for OOH, OOH+ or O2 adsorption (ads) to graphene were obtained through structural optimization calculations. ... Thus, to optimize the catalytic performance, materials structures should be controlled to have small N doping clusters in combination with material defects. ...

Lipeng Zhang; Jianbing Niu; Liming Dai; Zhenhai Xia

2012-04-10T23:59:59.000Z

33

A coupled-physics model for the vanadium oxygen fuel cell  

Science Journals Connector (OSTI)

Abstract A stationary two-dimensional model for the vanadium oxygen fuel cell is developed. The model consists of a single cell with two membranes, set up as of two half-cells and an intermediate chamber. The transport and balance of mass, momentum and charge are linked to the electrochemical reaction kinetics of the vanadium species and oxygen. The kinetic model for the cathode half-cell is extended by an empirical logistic function to describe the transient behavior of the half-cell. Additionally, experiments are conducted on a single vanadium oxygen fuel cell with 40 cm2 active membrane area. The experimental results are used to validate the simulation data. The effects of constant current discharging, polarization behavior and different flow rates on the cathode overpotential are studied by means of this model.

F.T. Wandschneider; M. Küttinger; J. Noack; P. Fischer; K. Pinkwart; J. Tübke; H. Nirschl

2014-01-01T23:59:59.000Z

34

Effect of oxygen on performance and mass transport in a single-cell thermionic fuel element  

SciTech Connect (OSTI)

The introduction of tracer amounts of oxygen into the interelectrode gap of a thermionic converter has been shown to improve converter performance. Excess oxygen, however, increases the loss rate of emitter material, reducing the converter performance and shortening its lifetime, owing to the increase in the effective emissivity of the electrodes, the change in the collector work function, and the deposition of emitter material oxides on spacers and insulators. In this paper, a model was developed, which calculated the emitter material loss rate, composition of the emitter material deposits on the collector surface and investigated the effect on performance of a single-cell Thermionic Fuel Element (TFE) in the presence of oxygen and cesium oxides in the interelectrode gap. The amount of oxygen and the cesium pressure in the interelectrode gap were varied parametrically and the TFE volt-ampere characteristics, and axial distributions of current density and emitter material loss rate along the TFE were calculated.

Paramonov, D.V.; El-Genk, M.S. [Univ. of New Mexico, Albuquerque, NM (United States)

1996-12-31T23:59:59.000Z

35

Method of controlling injection of oxygen into hydrogen-rich fuel cell feed stream  

DOE Patents [OSTI]

A method of operating a H.sub.2 --O.sub.2 fuel cell fueled by hydrogen-rich fuel stream containing CO. The CO content is reduced to acceptable levels by injecting oxygen into the fuel gas stream. The amount of oxygen injected is controlled in relation to the CO content of the fuel gas, by a control strategy that involves (a) determining the CO content of the fuel stream at a first injection rate, (b) increasing the O.sub.2 injection rate, (c) determining the CO content of the stream at the higher injection rate, (d) further increasing the O.sub.2 injection rate if the second measured CO content is lower than the first measured CO content or reducing the O.sub.2 injection rate if the second measured CO content is greater than the first measured CO content, and (e) repeating steps a-d as needed to optimize CO consumption and minimize H.sub.2 consumption.

Meltser, Mark Alexander (Pittsford, NY); Gutowski, Stanley (Pittsford, NY); Weisbrod, Kirk (Los Alamos, NM)

2001-01-01T23:59:59.000Z

36

CRC fuel rating program: road octane performance of oxygenates in 1982 model cars  

SciTech Connect (OSTI)

Because of the widespread interest in the use of alcohols and ethers as gasoline blending components, this program was conducted to evaluate the effects of several oxygenates on gasoline octane performance and to evaluate the effects of car design features such as engine and transmission type. Five oxygenates were evaluated at two nominal concentrations, 5 and 10 volume%, at both regular- and premium-grade octane levels: methanol (MeOH), ethanol (ETOH), isopropanol (IPA), tertiary butanol (TBA), and methyl tertiary butyl ether (MTBE). A blend of 5% MeOH and 5 percent TBA was also tested at both octane levels. Twenty-eight unleaded fuels, including four hydrocarbon fuels, two hydrocarbon fuels plus toluene, and twenty-two oxygenated fuels, were rated in duplicate in thirty-eight cars using the Modified Uniontown Technique (CRC Designation F-28-75 described in Appendix C), plus some additional instructions. All testing was done on chassis dynamometers. Ratings were obtained at full throttle with all thirty-eight cars, and at the most critical part-throttle condition (occurring with manifold vacuum of 4 in. Hg (13.5 kPa) or greater above the full-throttle vacuum) with nine cars.

Not Available

1985-07-01T23:59:59.000Z

37

Pt-Based Core–Shell Catalyst Architectures for Oxygen Fuel Cell Electrodes  

Science Journals Connector (OSTI)

Currently, platinum nanoparticles are the most used cathode electrode materials to catalyze the sluggish oxygen reduction reaction (ORR, O2 + 4 H+ + 4 e– ? 2 H2O) to water in PEMFC systems. ... The development of DFT-based theoretical predictions of efficient ORR catalysts provided progress in our understanding of ORR activity and yielded promising catalyst materials for fuel cell experimentalists. ... This work demonstrates the essential role of particle size and crossover hydrogen on the degrdn. of platinum polymer electrolyte membrane fuel cell (PEMFC) cathodes. ...

Mehtap Oezaslan; Frédéric Hasché; Peter Strasser

2013-09-12T23:59:59.000Z

38

Results of initial operation of the Jupiter Oxygen Corporation oxy-fuel 15 MWth burner test facility  

SciTech Connect (OSTI)

Jupiter Oxygen Corporation (JOC), in cooperation with the National Energy Technology Laboratory (NETL), constructed a 15 MWth oxy-fuel burner test facility with Integrated Pollutant Removal (IPRTM) to test high flame temperature oxy-fuel combustion and advanced carbon capture. Combustion protocols include baseline air firing with natural gas, oxygen and natural gas firing with and without flue gas recirculation, and oxygen and pulverized coal firing with flue gas recirculation. Testing focuses on characterizing burner performance, determining heat transfer characteristics, optimizing CO2 capture, and maximizing heat recovery, with an emphasis on data traceability to address retrofit of existing boilers by directly transforming burner systems to oxy-fuel firing.

Thomas Ochs, Danylo Oryshchyn, Rigel Woodside, Cathy Summers, Brian Patrick, Dietrich Gross, Mark Schoenfield, Thomas Weber and Dan O'Brien

2009-04-01T23:59:59.000Z

39

Challenges and Constraints of Using Oxygen Cathodes in Microbial Fuel Cells  

Science Journals Connector (OSTI)

Challenges and Constraints of Using Oxygen Cathodes in Microbial Fuel Cells ... The optimization of the cathode preparation (the choice of binder (5), the binder/catalyst ratio, the catalyst processing etc.) was beyond the scope of this study and should be the focus of further, technological investigations. ... Optimized cathode preparation procedures will most likely help increasing this factor and result in a further improved cathode performance at lower catalyst loads. ...

Feng Zhao; Falk Harnisch; Uwe Schröder; Fritz Scholz; Peter Bogdanoff; Iris Herrmann

2006-05-25T23:59:59.000Z

40

Zero Emission Power Plants Using Solid Oxide Fuel Cells and Oxygen Transport Membranes  

SciTech Connect (OSTI)

Siemens Westinghouse Power Corp. (SWPC) is engaged in the development of Solid Oxide Fuel Cell stationary power systems. SWPC has combined DOE Developmental funds with commercial customer funding to establish a record of successful SOFC field demonstration power systems of increasing size. SWPC will soon deploy the first unit of a newly developed 250 kWe Combined Heat Power System. It will generate electrical power at greater than 45% electrical efficiency. The SWPC SOFC power systems are equipped to operate on lower number hydrocarbon fuels such as pipeline natural gas, which is desulfurized within the SOFC power system. Because the system operates with a relatively high electrical efficiency, the CO2 emissions, {approx}1.0 lb CO2/ kW-hr, are low. Within the SOFC module the desulfurized fuel is utilized electrochemically and oxidized below the temperature for NOx generation. Therefore the NOx and SOx emissions for the SOFC power generation system are near negligible. The byproducts of the power generation from hydrocarbon fuels that are released into the environment are CO2 and water vapor. This forward looking DOE sponsored Vision 21 program is supporting the development of methods to capture and sequester the CO2, resulting in a Zero Emission power generation system. To accomplish this, SWPC is developing a SOFC module design, to be demonstrated in operating hardware, that will maintain separation of the fuel cell anode gas, consisting of H2, CO, H2O and CO2, from the vitiated air. That anode gas, the depleted fuel stream, containing less than 18% (H2 + CO), will be directed to an Oxygen Transport Membrane (OTM) Afterburner that is being developed by Praxair, Inc.. The OTM is supplied air and the depleted fuel. The OTM will selectively transport oxygen across the membrane to oxidize the remaining H2 and CO. The water vapor is then condensed from the totally 1.5.DOC oxidized fuel stream exiting the afterburner, leaving only the CO2 in gaseous form. That CO2 can then be compressed and sequestered, resulting in a Zero Emission power generation system operating on hydrocarbon fuel that adds only water vapor to the environment. Praxair has been developing oxygen separation systems based on dense walled, mixed electronic, oxygen ion conducting ceramics for a number of years. The oxygen separation membranes find applications in syngas production, high purity oxygen production and gas purification. In the SOFC afterburner application the chemical potential difference between the high temperature SOFC depleted fuel gas and the supplied air provides the driving force for oxygen transport. This permeated oxygen subsequently combusts the residual fuel in the SOFC exhaust. A number of experiments have been carried out in which simulated SOFC depleted fuel gas compositions and air have been supplied to either side of single OTM tubes in laboratory-scale reactors. The ceramic tubes are sealed into high temperature metallic housings which precludes mixing of the simulated SOFC depleted fuel and air streams. In early tests, although complete oxidation of the residual CO and H2 in the simulated SOFC depleted fuel was achieved, membrane performance degraded over time. The source of degradation was found to be contaminants in the simulated SOFC depleted fuel stream. Following removal of the contaminants, stable membrane performance has subsequently been demonstrated. In an ongoing test, the dried afterburner exhaust composition has been found to be stable at 99.2% CO2, 0.4% N2 and 0.6%O2 after 350 hours online. Discussion of these results is presented. A test of a longer, commercial demonstration size tube was performed in the SWPC test facility. A similar contamination of the simulated SOFC depleted fuel stream occurred and the performance degraded over time. A second test is being prepared. Siemens Westinghouse and Praxair are collaborating on the preliminary design of an OTM equipped Afterburner demonstration unit. The intent is to test the afterburner in conjunction with a reduced size SOFC test module that has the anode gas separati

Shockling, Larry A.; Huang, Keqin; Gilboy, Thomas E. (Siemens Westinghouse Power Corporation); Christie, G. Maxwell; Raybold, Troy M. (Praxair, Inc.)

2001-11-06T23:59:59.000Z

Note: This page contains sample records for the topic "newable fuels oxygenates" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Alarming Oxygen Depletion Caused by Hydrogen Combustion and Fuel Cells and their Resolution by Magnegas$^{TM}$  

E-Print Network [OSTI]

We recall that hydrogen combustion does resolve the environmental problems of fossil fuels due to excessive emission of carcinogenic substances and carbon dioxide. However, hydrogen combustion implies the permanent removal from our atmosphere of directly usable oxygen, a serious environmental problem called oxygen depletion, since the combustion turns oxygen into water whose separation to restore the original oxygen is prohibitive due to cost. We then show that a conceivable global use of hydrogen in complete replacement of fossil fuels would imply the permanent removal from our atmosphere of 2.8875x10^7 metric tons O_2/day. Fuel cells are briefly discussed to point out similarly serious environmental problems, again, for large uses. We propose the possibility of resolving these problems by upgrading hydrogen to the new combustible fuel called magnegas^TM, whose chemical structure is composed by the new chemical species of magnecules, whose energy content and other features are beyond the descriptive capaciti...

Santilli, R M

2000-01-01T23:59:59.000Z

42

Conversion of Mixed Oxygenates Generated from Synthesis Gas to Fuel Range Hydrocarbon  

SciTech Connect (OSTI)

The growing dependence in the U.S. on foreign crude oil supplies and increased concerns regarding greenhouse gas emission has generated considerable interest in research to develop renewable and environmentally friendly liquid hydrocarbon transportation fuels. One of the strategies for achieving this is to produce intermediate compounds such as alcohols and other simple oxygenates from biomass generated synthesis gas (mixture of carbon monoxide and hydrogen) and further convert them into liquid hydrocarbons. The focus of this research is to investigate the effects of mixed oxygenates intermediate product compositions on the conversion step to produce hydrocarbon liquids. A typical mixed oxygenate stream is expected to contain water (around 50%), alcohols, such as methanol and ethanol (around 35%), and smaller quantities of oxygenates such as acetaldehyde, acetic acid and ethyl acetate. However the ratio and the composition of the mixed oxygenate stream generated from synthesis gas vary significantly depending on the catalyst used and the process conditions. Zeolite catalyzed deoxygenation of methanol accompanied by chain growth is well understood under Methanol-to-Gasoline (MTG) like reaction conditions using an H-ZSM-5 zeolite as the catalyst6-8. Research has also been conducted to a limited extent in the past with higher alcohols, but not with other oxygenates present9-11. Also there has been little experimental investigation into mixtures containing substantial amounts of water. The latter is of particular interest because water separation from the hydrocarbon product would be less energy intensive than first removing it from the oxygenate intermediate stream prior to hydrocarbon synthesis, potentially reducing overall processing costs.

Ramasamy, Karthikeyan K.; Gerber, Mark A.; Lilga, Michael A.; Flake, Matthew D.

2012-08-19T23:59:59.000Z

43

Hybrid membrane/cryogenic separation of oxygen from air for use in the oxy-fuel process  

E-Print Network [OSTI]

and high temperature ion transport membranes. While polymeric membranes can produce oxygen enriched air of various concentrations, ion transport membranes can produce purities of close to 100%. Both membraHybrid membrane/cryogenic separation of oxygen from air for use in the oxy-fuel process Thomas

Struchtrup, Henning

44

Improved Non-Pt Alloys for the Oxygen Reduction Reaction at Fuel Cell Cathodes Predicted from Quantum Mechanics  

E-Print Network [OSTI]

the hypothesis that improved alloy catalysts for the oxygen reduction reaction (ORR) at fuel cell cathodes should catalysts for polymer electrolyte mem- brane fuel cell (PEMFC) than pure Pt, while maintaining or improving the surface under FC operating conditions.9 To determine new alloy candidates for PEMFC cathodes, we

Goddard III, William A.

45

A new continuous-flow process for catalytic conversion of glycerol to oxygenated fuel additive: Catalyst screening  

E-Print Network [OSTI]

: www.elsevier.com/locate/apenergy #12;1. Introduction The booming of biodiesel industry all over for the sustainability of biodiesel industry. In this regard, the fuel industry seems to be a suitable market whereA new continuous-flow process for catalytic conversion of glycerol to oxygenated fuel additive

Qin, Wensheng

46

Alarming Oxygen Depletion Caused by Hydrogen Combustion and Fuel Cells and their Resolution by Magnegas$^{TM}$  

E-Print Network [OSTI]

We recall that hydrogen combustion does resolve the environmental problems of fossil fuels due to excessive emission of carcinogenic substances and carbon dioxide. However, hydrogen combustion implies the permanent removal from our atmosphere of directly usable oxygen, a serious environmental problem called oxygen depletion, since the combustion turns oxygen into water whose separation to restore the original oxygen is prohibitive due to cost. We then show that a conceivable global use of hydrogen in complete replacement of fossil fuels would imply the permanent removal from our atmosphere of 2.8875x10^7 metric tons O_2/day. Fuel cells are briefly discussed to point out similarly serious environmental problems, again, for large uses. We propose the possibility of resolving these problems by upgrading hydrogen to the new combustible fuel called magnegas^TM, whose chemical structure is composed by the new chemical species of magnecules, whose energy content and other features are beyond the descriptive capacities of quantum chemistry. In fact, magnegas contains up to 50% hydrogen, while having combustion exhaust with: 1) a positive oxygen balance (releasing more oxygen in the exhaust than that used in the combustion); 2) no appreciable carcinogenic or toxic substances; 3) considerably reduced carbon dioxide as compared to fossil fuels; 4) considerably reduced nitrogen oxides; and 5) general reduction of pollutants in the exhaust up to 96% of current EPA standards.

R. M. Santilli

2000-09-04T23:59:59.000Z

47

Plant for producing an oxygen-containing additive as an ecologically beneficial component for liquid motor fuels  

DOE Patents [OSTI]

A plant for producing an oxygen-containing additive for liquid motor fuels comprises an anaerobic fermentation vessel, a gasholder, a system for removal of sulphuretted hydrogen, and a hotwell. The plant further comprises an aerobic fermentation vessel, a device for liquid substance pumping, a device for liquid aeration with an oxygen-containing gas, a removal system of solid mass residue after fermentation, a gas distribution device; a device for heavy gases utilization; a device for ammonia adsorption by water; a liquid-gas mixer; a cavity mixer, a system that serves superficial active and dispersant matters and a cooler; all of these being connected to each other by pipelines. The technical result being the implementation of a process for producing an oxygen containing additive, which after being added to liquid motor fuels, provides an ecologically beneficial component for motor fuels by ensuring the stability of composition fuel properties during long-term storage.

Siryk, Yury Paul; Balytski, Ivan Peter; Korolyov, Volodymyr George; Klishyn, Olexiy Nick; Lnianiy, Vitaly Nick; Lyakh, Yury Alex; Rogulin, Victor Valery

2013-04-30T23:59:59.000Z

48

ReaxFF Reactive Force Field for Solid Oxide Fuel Cell Systems with Application to Oxygen Ion Transport in Yttria-Stabilized Zirconia  

E-Print Network [OSTI]

ReaxFF Reactive Force Field for Solid Oxide Fuel Cell Systems with Application to Oxygen Ion through yttria-stabilized zirconia (YSZ) solid oxide fuel cell (SOFC) membranes. All parameters for Reax temperature, leading to applications as oxygen sensors and as membranes for high temperature solid oxide fuel

Goddard III, William A.

49

Solid oxide fuel cells having porous cathodes infiltrated with oxygen-reducing catalysts  

DOE Patents [OSTI]

Solid-oxide fuel cells include an electrolyte and an anode electrically coupled to a first surface of the electrolyte. A cathode is provided, which is electrically coupled to a second surface of the electrolyte. The cathode includes a porous backbone having a porosity in a range from about 20% to about 70%. The porous backbone contains a mixed ionic-electronic conductor (MIEC) of a first material infiltrated with an oxygen-reducing catalyst of a second material different from the first material.

Liu, Meilin; Liu, Ze; Liu, Mingfei; Nie, Lifang; Mebane, David Spencer; Wilson, Lane Curtis; Surdoval, Wayne

2014-08-12T23:59:59.000Z

50

Integrated production of fuel gas and oxygenated organic compounds from synthesis gas  

DOE Patents [OSTI]

An oxygenated organic liquid product and a fuel gas are produced from a portion of synthesis gas comprising hydrogen, carbon monoxide, carbon dioxide, and sulfur-containing compounds in a integrated feed treatment and catalytic reaction system. To prevent catalyst poisoning, the sulfur-containing compounds in the reactor feed are absorbed in a liquid comprising the reactor product, and the resulting sulfur-containing liquid is regenerated by stripping with untreated synthesis gas from the reactor. Stripping offgas is combined with the remaining synthesis gas to provide a fuel gas product. A portion of the regenerated liquid is used as makeup to the absorber and the remainder is withdrawn as a liquid product. The method is particularly useful for integration with a combined cycle coal gasification system utilizing a gas turbine for electric power generation.

Moore, Robert B. (Allentown, PA); Hegarty, William P. (State College, PA); Studer, David W. (Wescosville, PA); Tirados, Edward J. (Easton, PA)

1995-01-01T23:59:59.000Z

51

Effect of hydrogen on the oxygen embrittlement of beta-quenched Zircaloy-4 fuel cladding  

SciTech Connect (OSTI)

Zircaloy cladding embrittlement was evaluated from data derived from the postirradiation examination of 47 light-water reactor type fuel rods irradiated under postulated accident conditions. The Zircaloy-4 cladding showed rapid oxygenation of the/beta/-phase Zircaloy and hydriding in excess of the pretest characterization. Fuel rods operated with a cladding defect were embrittled to a greater extent than intact rods oxidized under similar conditions. A modified background prior/beta/-phase and precipitation of rim-/alpha/was typically observed in the failure region of breached rods. The fracture resistance of breached rods appears to be related to enhanced hydrogen absorption and its influence on both the/alpha/-phase transformation and /alpha/-morphology during rapid (approximately 100 K/s) quenching. refs 5.

Seiffert, S.L.

1982-01-01T23:59:59.000Z

52

Performance and Emissions of a Compression Ignition Engine Fueled with Diesel/Oxygenate Blends for Various Fuel Delivery Advance Angles  

Science Journals Connector (OSTI)

State Key Laboratory of Multiphase Flow in Power Engineering, Xi'an Jiaotong University, Xi'an, People's Republic of China ... In the application of pure oxygenated fuels, Fleisch et al.,1 Kapus and Ofner,2 and Sorenson and Mikkelsen3 have studied dimethyl ether (DME) in a modified diesel engine, and their results showed that the engine could achieve ultralow-emission prospects without a fundamental change in combustion systems. ... Although some previous work has revealed the characteristics of diesel/ethanol blends in a compression ignition engine (Satge de Caro et al.,14 Ali et al.15), there, however, is still much work that needs to be done in regard to the application of diesel/methanol blends in compression ignition engines, especially in clarifying the basic combustion and emission. ...

Zuohua Huang; Hongbing Lu; Deming Jiang; Ke Zeng; Bing Liu; Junqiang Zhang; Xibin Wang

2005-02-02T23:59:59.000Z

53

Efficient Oxygen Evolution Reaction Catalysts for Cell Reversal and Start/Stop Tolerance in Fuel Cells  

SciTech Connect (OSTI)

Minute amounts of ruthenium and iridium on platinum nanostructured thin films have been evaluated in an effort to reduce carbon corrosion and Pt dissolution during transient conditions in proton exchange membrane fuel cells. Electrochemical tests showed the catalysts had a remarkable oxygen evolution reaction (OER) activity, even greater than that of bulk, metallic thin films. Stability tests within a fuel cell environment showed that rapid Ru dissolution could be managed with the addition of Ir. Membrane electrode assemblies containing a Ru to Ir atomic ratio of 1:9 were evaluated under startup/shutdown and cell reversal conditions for OER catalyst loadings ranging from 1 to 10 g/cm2. These tests affirmed that electrode potentials can be controlled through the addition of OER catalysts without impacting the oxygen reduction reaction on the cathode or the hydrogen oxidation reaction on the anode. The morphology and chemical structure of the thin OER layers were characterized by scanning transmission electron microscopy and X-ray photoelectron spectroscopy in an effort to establish a correlation between interfacial properties and electrochemical behavior.

Atanasoski, Radoslav [3M Industrial Mineral Products; Atanasoska, Liliana [3M Industrial Mineral Products; Cullen, David A [ORNL

2013-01-01T23:59:59.000Z

54

Characteristics of Enzyme-Based Hydrogen Fuel Cells Using an Oxygen-Tolerant Hydrogenase as the Anodic Catalyst  

Science Journals Connector (OSTI)

In a fuel cell adaptable for variable fuel and oxidant supply, three limiting conditions were examined: (1) the anode and cathode separated by a Nafion membrane and 100% H2 and 100% O2 fed to the separate compartments, (2) a membrane-free mixed feed cell with a fuel-rich (96% H2) hydrogen/oxygen mixture, and (3) a membrane-free mixed feed cell with a fuel-weak (4% H2) hydrogen/air mixture. ... Enzymes permit diversification of fuels; conventional fuel cells are currently restricted to hydrogen or methanol, whereas enzymes can use biological fuels such as glucose or fructose. ... Thus, the second active anode jump-starts the first, inactivated anode, analogous to recharging the flat battery of one car with the live battery of another. ...

Annemarie F. Wait; Alison Parkin; Gregory M. Morley; Luciano dos Santos; Fraser A. Armstrong

2010-06-18T23:59:59.000Z

55

Effect of fuel gas composition in chemical-looping combustion with Ni-based oxygen carriers. 1. Fate of sulfur  

SciTech Connect (OSTI)

Chemical-looping combustion (CLC) has been suggested among the best alternatives to reduce the economic cost of CO{sub 2} capture using fuel gas because CO{sub 2} is inherently separated in the process. For gaseous fuels, natural gas, refinery gas, or syngas from coal gasification can be used. These fuels may contain different amounts of sulfur compounds, such as H{sub 2}S and COS. An experimental investigation of the fate of sulfur during CH{sub 4} combustion in a 500 W{sub th} CLC prototype using a Ni-based oxygen carrier has been carried out. The effect on the oxygen carrier behavior and combustion efficiency of several operating conditions such as temperature and H{sub 2}S concentration has been analyzed. Nickel sulfide, Ni3S{sub 2}, was formed at all operating conditions in the fuel reactor, which produced an oxygen carrier deactivation and lower combustion efficiencies. However, the oxygen carrier recovered their initial reactivity after certain time without sulfur addition. The sulfides were transported to the air reactor where SO{sub 2} was produced as final gas product. Agglomeration problems derived from the sulfides formation were never detected during continuous operation. Considering both operational and environmental aspects, fuels with sulfur contents below 100 vppm H{sub 2}S seem to be adequate to be used in an industrial CLC plant.

Garcia-Labiano, F.; de Diego, L.F.; Gayan, P.; Adanez, J.; Abad, A.; Dueso, C. [CSIC, Zaragoza (Spain)

2009-03-15T23:59:59.000Z

56

ZERO EMISSION POWER PLANTS USING SOLID OXIDE FUEL CELLS AND OXYGEN TRANSPORT MEMBRANES  

SciTech Connect (OSTI)

Over 16,700 hours of operational experience was gained for the Oxygen Transport Membrane (OTM) elements of the proposed SOFC/OTM zero-emission power generation concept. It was repeatedly demonstrated that OTMs with no additional oxidation catalysts were able to completely oxidize the remaining depleted fuel in a simulated SOFC anode exhaust at an O{sub 2} flux that met initial targets. In such cases, neither residual CO nor H{sub 2} were detected to the limits of the gas chromatograph (<10 ppm). Dried OTM afterburner exhaust streams contained up to 99.5% CO{sub 2}. Oxygen flux through modified OTMs was double or even triple that of the standard OTMs used for the majority of testing purposes. Both the standard and modified membranes in laboratory-scale and demonstration-sized formats exhibited stable performance over extended periods (2300 to 3500 hours or 3 to 5 months). Reactor contaminants, were determined to negatively impact OTM performance stability. A method of preventing OTM performance degradation was developed and proven to be effective. Information concerning OTM and seal reliability over extended periods and through various chemical and thermal shocks and cycles was also obtained. These findings were used to develop several conceptual designs for pilot (10 kWe) and commercial-scale (250 kWe) SOFC/OTM zero emission power generation systems.

G. Maxwell Christie; Troy M. Raybold

2003-06-10T23:59:59.000Z

57

Thermodynamic and kinetic studies of a catalytic process to convert glycerol into solketal as an oxygenated fuel additive  

E-Print Network [OSTI]

exchange resin Kinetics a b s t r a c t Glycerol is a byproduct of biodiesel industry and can be converted as an oxygenated fuel additive Malaya R. Nanda a , Zhongshun Yuan a , Wensheng Qin b , Hassan S. Ghaziaskar c was completely eliminated above 400 rpm. Moisture content demonstrated an adverse effect on the yield

Qin, Wensheng

58

Investigation of Combustion and Emission Characteristics of a Diesel Engine with Oxygenated Fuels and Thermal Barrier Coating  

Science Journals Connector (OSTI)

Investigation of Combustion and Emission Characteristics of a Diesel Engine with Oxygenated Fuels and Thermal Barrier Coating ... Exhaust gas emissions from diesel engines have become a serious problem to the researchers; therefore, a method of reduction of gas emission is needed. ... Their results show that the engine can achieve ultra-low emission without fundamental change to the combustion system. ...

P. Ramu; C. G. Saravanan

2009-01-07T23:59:59.000Z

59

Electroreduction of Oxygen in Polymer Electrolyte Fuel Cells by Activated Carbon Coated Cobalt Nanocrystallites Produced by Electric Arc Discharge  

Science Journals Connector (OSTI)

Electroreduction of Oxygen in Polymer Electrolyte Fuel Cells by Activated Carbon Coated Cobalt Nanocrystallites Produced by Electric Arc Discharge ... A recent review of the encapsulation of rare earth and iron group metals (Fe, Co, Ni) using electric arc discharge has been published by Saito. ... Nanotubes have been observed after activation of catalytically inactive carbon-coated Co nanocrystallites generated by electric arc discharge. ...

G. Lalande; D. Guay; J. P. Dodelet; S. A. Majetich; M. E. McHenry

1997-03-18T23:59:59.000Z

60

In-Cylinder Reaction Chemistry and Kinetics During Negative Valve Overlap Fuel Injection Under Low-Oxygen Conditions  

SciTech Connect (OSTI)

Fuel injection into the negative valve overlap (NVO) period is a common method for controlling combustion phasing in homogeneous charge compression ignition (HCCI) as well as other forms of advanced combustion. During this event, at least a portion of the fuel hydrocarbons can be converted to products containing significant levels of H2 and CO, as well as other short chain hydrocarbons by means of thermal cracking, water-gas shift, and partial oxidation reactions, depending on the availability of oxygen and the time-temperature-pressure history. The resulting products alter the autoignition properties of the combined fuel mixture for HCCI. Fuel-rich chemistry in a partial oxidation environment is also relevant to other high efficiency engine concepts (e.g., the dedicated EGR (D-EGR) concept from SWRI). In this study, we used a unique 6-stroke engine cycle to experimentally investigate the chemistry of a range of fuels injected during NVO under low oxygen conditions. Fuels investigated included iso-octane, iso-butanol, ethanol, and methanol. Products from NVO chemistry were highly dependent on fuel type and injection timing, with iso-octane producing less than 1.5% hydrogen and methanol producing more than 8%. We compare the experimental trends with CHEMKIN (single zone, 0-D model) predictions using multiple kinetic mechanisms available in the current literature. Our primary conclusion is that the kinetic mechanisms investigated are unable to accurately predict the magnitude and trends of major species we observed.

Kalaskar, Vickey B [ORNL] [ORNL; Szybist, James P [ORNL] [ORNL; Splitter, Derek A [ORNL] [ORNL; Pihl, Josh A [ORNL] [ORNL; Gao, Zhiming [ORNL] [ORNL; Daw, C Stuart [ORNL] [ORNL

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "newable fuels oxygenates" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Investigation of different manganese ores as oxygen carriers in chemical-looping combustion (CLC) for solid fuels  

Science Journals Connector (OSTI)

Abstract The chemical-looping combustion (CLC) process is a novel solution for efficient combustion with direct capture of carbon dioxide. The process uses a metal oxide as an oxygen carrier to transfer oxygen from an air to a fuel reactor, where the fuel reacts with the solid oxygen carrier. In this work, six different manganese ores are investigated as oxygen carriers for CLC application. The chemical-looping characteristics of the oxygen carriers were evaluated in a laboratory-scale fluidized-bed reactor in the temperature range of 900–970 °C during alternating reducing and oxidizing conditions. Three of the manganese ores showed a small oxygen release in inert environment between 850 and 950 °C. During reactivity tests, the gas yield with methane increased with the temperature and complete conversion of 50% CO in H2 was obtained for all of the ores. The rates of char gasification of two fuels, namely Mexican petroleum coke and Swedish wood char, were compared for the different manganese ores at 970 °C and with 50% H2O in N2 as fluidizing gas. Ilmenite and a manufactured Mn-oxide oxygen carrier consisting of Mn3O4 and MgO-stabilized ZrO2 as support were also included for comparison. The char gasification rate and the gas conversion were higher with the manganese ores and the Mn-oxide oxygen carrier compared to ilmenite. However, the higher reactivity of the manganese ores with H2 and the ensuing decrease in H2 inhibition for manganese ores is not sufficient to explain their higher rate of char gasification. Surface analysis of partially gasified petcoke particles in the presence of manganese ores showed formation of cavities and channels as well as a uniform distribution of potassium and sodium elements. The rate of char gasification also increased with the concentration of potassium and sodium impurities in the manganese ores. Thus the results suggest that the increased rate of char conversion for manganese ores is due to alkali-catalyzed steam gasification. The increase in rate of char gasification, in combination with potentially low costs of these materials suggests that manganese ores could be interesting materials for CLC with solid fuels.

Mehdi Arjmand; Henrik Leion; Tobias Mattisson; Anders Lyngfelt

2014-01-01T23:59:59.000Z

62

Effects of oxygenated fuel blends on carbonaceous particulate composition and particle size distributions from a stationary diesel engine  

Science Journals Connector (OSTI)

Abstract A systematic study was conducted to evaluate and compare the effects of blending five different oxygenated compounds, diglyme (DGM), palm oil methyl ester (PME), dimethyl carbonate (DMC), diethyl adipate (DEA) and butanol (Bu) with ultralow sulfur diesel (ULSD), on engine performance, particulate mass concentrations, organic (OC) and elemental (EC) carbon fractions of the particles and particle size distributions from a single cylinder, direct injection stationary diesel engine with the engine working at a constant engine speed and at three engine loads. A small increase in the brake specific fuel consumption (BSFC) and brake thermal efficiency (BTE) was observed with the use of oxygenates blended with ULSD. All five oxygenates were found to be effective at reducing particulate mass emissions at medium and high engine loads, with butanol being the most effective and DGM being the least effective. Analysis of the relative contribution of changes in the OC and EC emissions to the reduction of particulate matter indicated that under the same oxygen content, EC made a dominant contribution to the reduction of particulate mass. The results also indicated that reduction in both particle mass and number emissions was affected not only by the oxygen content, but also by the chemical structure and thermophysical properties of oxygenates as well as engine operating conditions.

Zhi-Hui Zhang; Rajasekhar Balasubramanian

2015-01-01T23:59:59.000Z

63

CO2?laser?induced deflagration of fuel/oxygen mixtures  

Science Journals Connector (OSTI)

Weakly focused pulsed?CO2?laser radiation has been examined as an ignition source for low?pressure (85–100 Torr) near?stoichiometric fuel/oxygen mixtures containing the following fuels: ethylene methyl fluoride methanol ethanol dimethyl ether p?dioxane n?propyl nitrate and iso?propyl nitrate. The data analysis includes characterization of the spatially dependent ir absorption in the test cell calculation of appropriate medium temperatures from the absorbed laser energy and correlation of observed ignition delay times t ig with the calculated temperatures. Effects of hydrodynamic motion on the pressure density and temperature profiles of the irradiated samples were modeled using a computer code for two?dimensional wave propagation. Code predictions are in accordance with experimental pressure?time histories obtained using a piezoelectric transducer. Minimum ignition temperatures ranged from 590 K for the iso?propyl nitrate/O2 system to 1645 K for CH3F/O2. The observed functional relationship between t ig and temperature T was generally of the form ln?t ig =A/T+B where A and B are constants. This relationship follows the form predicted by thermal and degenerate chain ignition theories viz. ln?t ig =E act/ R T+constant where E act corresponds to an overall activation energy. Using this relation derived activation energies are 86 57 42 47 ?40 13 and 12 kcal/mole for the CH3F/O2 CH3OCH3/O2 CH3OH/O2 C2H5OH/O2 C4H8O2/O2 n?propyl nitrate/O2 and iso?propyl nitrate/O2 mixtures respectively. These results are in reasonable agreement with available data from shock?tube and hot air stream injection techniques. In contrast an anomalous threshold?like effect was observed for laser ignition of C2H4/O2. The applicability of ignition schemes of this type to time?resolved kinetic spectroscopic studies is briefly discussed.

Wayne M. Trott

1983-01-01T23:59:59.000Z

64

CO/sub 2/-laser-induced deflagration of fuel/oxygen mixtures  

SciTech Connect (OSTI)

Weakly focused pulsed-CO/sub 2/-laser radiation has been examined as an ignition source for low-pressure (85--100 Torr), near-stoichiometric fuel/oxygen mixtures containing the following fuels: ethylene, methyl fluoride, methanol, ethanol, dimethyl ether, p-dioxane, n-propyl nitrate, and iso-propyl nitrate. The data analysis includes characterization of the spatially dependent ir absorption in the test cell, calculation of appropriate medium temperatures from the absorbed laser energy, and correlation of observed ignition delay times t/sub ig/ with the calculated temperatures. Effects of hydrodynamic motion on the pressure, density, and temperature profiles of the irradiated samples were modeled using a computer code for two-dimensional wave propagation. Code predictions are in accordance with experimental pressure-time histories obtained using a piezoelectric transducer. Minimum ignition temperatures ranged from 590 K for the iso-propyl nitrate/O/sub 2/ system to 1645 K for CH/sub 3/F/O/sub 2/. The observed functional relationship between t/sub ig/ and temperature T was generally of the form ln t/sub ig/ = A/T+B, where A and B are constants. This relationship follows the form predicted by thermal and degenerate chain ignition theories, viz., ln t/sub ig/ = E/sub act// RT+constant, where E/sub act/ corresponds to an overall activation energy. Using this relation, derived activation energies are 86, 57, 42, 47, approx.40, 13, and 12 kcal/mole for the CH/sub 3/F/O/sub 2/, CH/sub 3/OCH/sub 3//O/sub 2/, CH/sub 3/OH/O/sub 2/, C/sub 2/H/sub 5/OH/O/sub 2/, C/sub 4/H/sub 8/O/sub 2//O/sub 2/, n-propyl nitrate/O/sub 2/, and iso-propyl nitrate/O/sub 2/ mixtures, respectively. These results are in reasonable agreement with available data from shock-tube and hot air stream injection techniques. In contrast, an anomalous, threshold-like effect was observed for laser ignition of C/sub 2/H/sub 4//O/sub 2/. The applicability of ignition schemes of this type to time-resolved kinetic spectroscopic studies is briefly discussed.

Trott, W.M.

1983-01-01T23:59:59.000Z

65

Study of oxygen reduction mechanism on Ag modified1 Sm1.8Ce0.2CuO4 cathode for solid oxide fuel cell2  

E-Print Network [OSTI]

to oxygen dissociation and diffusion process.26 KEYWORDS: Solid oxide fuel cell; Silver infiltrationStudy of oxygen reduction mechanism on Ag modified1 Sm1.8Ce0.2CuO4 cathode for solid oxide fuel cell2 3 4 Li-Ping Sun1 -- Hui Zhao1 -- Qiang Li1 -- Li-Hua Huo1 -- Jean-Paul Viricelle*2 --5 Christophe

Paris-Sud XI, Université de

66

Phosphoric acid impurities in phosphoric acid fuel cell electrolytes. 2: Effects on the oxygen reduction reaction at platinum electrodes  

SciTech Connect (OSTI)

The effects of phosphorus acid additions on the oxygen reduction reaction at platinum electrodes in concentrated phosphoric acid were studied. The oxygen reduction currents decreased, and the Tafel slopes became more negative upon the addition of small concentrations of phosphorus acid. In addition,the phosphorus acid oxidation current tended to complete with the oxygen reduction current. These effects became more pronounced at higher phosphorus acid concentrations and at higher temperatures. Upon the addition of phosphorus acid the number of electrons involved in the oxygen reduction reaction decreased from a value close to four to a value approaching two, suggesting promotion of a two-electron reduction to peroxide. Therefore, in studies of the electrochemical reduction of oxygen in hot concentrated phosphoric acid or in fuel cell systems using hot concentrated phosphoric acid as electrolyte, it is recommended that precautions be taken against the inadvertent formation of the phosphorus acid. The removal of phosphorus acid from concentrated phosphoric acid by repeated potential cycling at 100 mV/s between + 0.5 and +1.50 V (vs. dynamic hydrogen electrode) was demonstrated.

Sugishima, Noboru; Hinatsu, J.T.; Foulkes, F.R. (Univ. of Toronto, Ontario (Canada). Dept. of Chemical Engineering and Applied Chemistry)

1994-12-01T23:59:59.000Z

67

Iron-Based Catalysts with Improved Oxygen Reduction Activity in Polymer Electrolyte Fuel Cells  

Science Journals Connector (OSTI)

...26 See supporting material on Science Online. 27 U. S. Department of Energy, Technical Plan: Fuel Cells, 2007 (www1.eere.energy.gov/hydrogenandfuelcells/mypp/pdfs/fuel_cells.pdf). 28 F. Charreteur , S. Ruggeri, F. Jaouen, J...

Michel Lefèvre; Eric Proietti; Frédéric Jaouen; Jean-Pol Dodelet

2009-04-03T23:59:59.000Z

68

Mechanism of oxygen reduction reaction on transition metal oxide catalysts for high temperature fuel cells  

E-Print Network [OSTI]

The solid oxide fuel cell (SOFC) with its high energy conversion efficiency, low emissions, silent operation and its ability to utilize commercial fuels has the potential to create a large impact on the energy landscape. ...

La O', Gerardo Jose Cordova

2008-01-01T23:59:59.000Z

69

Development of a Novel Oxygen Supply Process and its Integration with an Oxy-Fuel Coal-Fired Boiler  

SciTech Connect (OSTI)

BOC, the world's second largest industrial gas company, has developed a novel high temperature sorption based technology referred to as CAR (Cyclic Autothermal Recovery) for oxygen production and supply to oxy-fuel boilers with flue gas recycle. This technology is based on sorption and storage of oxygen in a fixed bed containing mixed ionic and electronic conductor materials. The objective of the proposed work was to construct a CAR PDU that was capable of producing 10-scfm of oxygen, using steam or recycled flue gas as the sweep gas, and install it in the Combustion Test Facility. The unit was designed and fabricated at BOC/The Linde Group, Murray Hill, New Jersey. The unit was then shipped to WRI where the site had been prepared for the unit by installation of air, carbon dioxide, natural gas, nitrogen, computer, electrical and infrastructure systems. Initial experiments with the PDU consisted of flowing air into both sides of the absorption systems and using the air heaters to ramp up the bed temperatures. The two beds were tested individually to operational temperatures up to 900 C in air. The cycling process was tested where gases are flowed alternatively from the top then bottom of the beds. The PDU unit behaved properly with respect to flow, pressure and heat during tests. The PDU was advanced to the point where oxygen production testing could begin and integration to the combustion test facility could occur.

None

2006-12-31T23:59:59.000Z

70

Oxygen reduction on carbon-supported platinum fuel-cell electrodes in H/sub 3/PO/sub 4/  

SciTech Connect (OSTI)

The reduction of oxygen on carbon supported fuel cell electrodes was investigated in phosphoric acid electrolytes in the concentration range of 85% to 101% and at temperatures from 25/sup 0/ to 180/sup 0/C. In purified acid the Tafel slope in the potential region of 0.7 to 0.9 V RHE is approx. 120 mV/decade and is invariant with temperature. The activation energy for oxygen reduction is between 8 kcal and 13 kcal/mole. In impure 101% electrolyte the Tafel slope increases from a value of 85 mV/decade at 80/sup 0/C to 105 mV/decade at 180/sup 0/C and the activation energy is 18.29 kcal/mole. The major discrepancies in the literature can be rationalized on the basis of impurity effects. In pure electrolytes, the kinetic parameters on smooth platinum and high area carbon supported platinum are the same.

McBreen, J.; Olender, H.; Srinivasan, S.

1981-01-01T23:59:59.000Z

71

E-Print Network 3.0 - alternative fuel oxygenates Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Laboratory, Chemical Sciences and Engineering Division, Fuel Cell Department Collection: Energy Storage, Conversion and Utilization 2 6-025 (O) The Joint International Conference...

72

Rate Analysis of Chemical-Looping with Oxygen Uncoupling (CLOU) for Solid Fuels  

Science Journals Connector (OSTI)

The present study is concerned with the rate analysis from reported batch fluidized bed CLOU experimental data of Mexican petcoke particles by a CuO/ZrO2 oxygen carrier. ... Analysis of the CLOU Experiments for Combustion of Mexican Petcoke(4, 5) ... A 45–60 fold increase in reaction rate has been reported of the carbon residue in petcoke when reacted with a CuO based oxygen carrier in CLOU experiments, compared to the CLC process with an iron based oxygen carrier in the temperature range 950–985 °C. ...

Asad H. Sahir; Hong Yong Sohn; Henrik Leion; JoAnn S. Lighty

2012-05-24T23:59:59.000Z

73

Performance of a low-cost iron ore as an oxygen carrier for Chemical Looping Combustion of gaseous fuels  

Science Journals Connector (OSTI)

Abstract This work evaluates the performance of an iron ore, mainly composed of Fe2O3, as an oxygen carrier (OC) for Chemical Looping Combustion (CLC) with gaseous fuels. The OC was characterized by TGA and evaluated in a continuous 500 Wth CLC unit, using CH4, syngas and a PSA off-gas as fuels. The OC was able to fully convert syngas at 880 °C. However, lower conversion rates were observed with methane-containing fuels. The addition of a Ni-based OC was evaluated in order to increase the reactivity of the OC with methane. In spite of this, an absence of catalytic effect was observed for the Ni-based OC. A deep analysis was carried out into the reasons for the absence of catalytic effect of the Ni-based OC. The performance of the iron ore with regard to attrition and fluidization behaviour was satisfactory throughout 50 h of hot operation in the continuous CLC plant. Thus, this low cost material is a suitable OC for gaseous fuels mainly composed of H2 and CO.

Miguel A. Pans; Pilar Gayán; Luis F. de Diego; Francisco García-Labiano; Alberto Abad; Juan Adánez.

2014-01-01T23:59:59.000Z

74

Activity and Evolution of Vapor Deposited Pt-Pd Oxygen Reduction Catalysts for Solid Acid Fuel Cells  

SciTech Connect (OSTI)

The performance of hydrogen fuel cells based on the crystalline solid proton conductor CsH2PO4 is circumscribed by the mass activity of platinum oxygen reduction catalysts in the cathode. Here we report on the first application of an alloy catalyst in a solid acid fuel cell, and demonstrate an activity 4.5 times greater than Pt at 0.8 V. These activity enhancements were obtained with platinum-palladium alloys that were vapor-deposited directly on CsH2PO4 at 210 C. Catalyst mass activity peaks at a composition of 84 at% Pd, though smaller activity enhancements are observed for catalyst compositions exceeding 50 at% Pd. Prior to fuel cell testing, Pd-rich catalysts display lattice parameter expansions of up to 2% due to the presence of interstitial carbon. After fuel cell testing, a Pt-Pd solid solution absent of lattice dilatation and depleted in carbon is recovered. The structural evolution of the catalysts is correlated with catalyst de-activation.

Papandrew, Alexander B [ORNL; Chisholm, Calum R [ORNL; Zecevic, strahinja [LiOx, Inc., Pasadena, California 91106, United States; Veith, Gabriel M [ORNL; Zawodzinski, Thomas A [ORNL

2013-01-01T23:59:59.000Z

75

Power Generation Capabilities of Microbial Fuel Cells with Different Oxygen Supplies in the Cathodic Chamber  

Science Journals Connector (OSTI)

Two microbial fuel cells (MFCs) inoculated with activated sludge ... whereas it was obtained by the photosynthesis of algae in the other. Electrogenic capabilities of both ... power output than the one with photo...

Der-Fong Juang; Chao-Hsien Lee; Shu-Chun Hsueh…

2012-06-01T23:59:59.000Z

76

Design Principles for Oxygen-Reduction Activity on Perovskite Oxide Catalysts for Fuel Cells and Metal-air Batteries  

SciTech Connect (OSTI)

The prohibitive cost and scarcity of the noble-metal catalysts needed for catalysing the oxygen reduction reaction (ORR) in fuel cells and metal-air batteries limit the commercialization of these clean-energy technologies. Identifying a catalyst design principle that links material properties to the catalytic activity can accelerate the search for highly active and abundant transition-metal-oxide catalysts to replace platinum. Here, we demonstrate that the ORR activity for oxide catalysts primarily correlates to {sigma}*-orbital (e{sub g}) occupation and the extent of B-site transition-metal-oxygen covalency, which serves as a secondary activity descriptor. Our findings reflect the critical influences of the {sigma}* orbital and metal-oxygen covalency on the competition between O{sub 2}{sup 2-}/OH{sup -} displacement and OH{sup -} regeneration on surface transition-metal ions as the rate-limiting steps of the ORR, and thus highlight the importance of electronic structure in controlling oxide catalytic activity.

J Suntivich; H Gasteiger; N Yabuuchi; H Nakanishi; J Goodenough; Y Shao-Horn

2011-12-31T23:59:59.000Z

77

\\{NOx\\} emission characteristics of fluidized bed combustion in atmospheres rich in oxygen and water vapor for high-nitrogen fuel  

Science Journals Connector (OSTI)

Abstract The present study examines the influence of water vapor in combustion atmosphere on \\{NOx\\} emission from oxygen-enriched combustion of air-dried distilled spirit lees and its char in a laboratory fluidized bed of 760 mm high and 68 mm in inner diameter. Steam was added into the fluidizing gas to vary the vapor content in the combustion atmosphere. At a combustion temperature of 950 °C and a steam-to-fuel mass ratio (S/F) of 0.5, the presence of water vapor reduced the \\{NOx\\} concentration in the flue gas for low O2 contents (?30 vol.%) in the combustion agent but increased the \\{NOx\\} emission for high O2 contents (?40 vol.%). The possible causes were clarified for this shift from suppression to promotion of fuel-N conversion into \\{NOx\\} with raising O2 concentration in the combustion agent. Varying temperature from 850 °C to 1150 °C resulted in a peak conversion of fuel-N to \\{NOx\\} in the temperature range of 950–1050 °C for all the tested O2 concentrations. Increasing the O2 concentration tended to lower the critical temperature corresponding to such a peak fuel-N conversion. Testing results also suggested that the presence of excessive water vapor in the combustion atmosphere would inhibit the release of fuel-N in the devolatilization stage and promote the formation of some reducing gases. In addition to the anticipated diluting effect, the steam addition also shortened the reaction time for homogeneous and heterogeneous \\{NOx\\} reduction by the reducing gases and char. It is postulated that the formation of OH radicals at high O2 content and high temperature could cause the observed increase in the \\{NOx\\} emission.

Chuanqiang Zhu; Shuyuan Liu; Huan Liu; Juan Yang; Xiaoxing Liu; Guangwen Xu

2015-01-01T23:59:59.000Z

78

Use of coal as fuel for chemical-looping combustion with Ni-based oxygen carrier  

SciTech Connect (OSTI)

Chemical-looping combustion is an indirect combustion technology with inherent separation of the greenhouse gas CO{sub 2}. The feasibility of using NiO as an oxygen carrier during chemical-looping combustion of coal has been investigated experimentally at 800-960{degree}C in the present work. The experiments were carried out in a fluidized bed, where the steam acted as the gasification-fluidization medium. Coal gasification and the reaction of oxygen carrier with the water gas take place simultaneously in the reactor. The oxygen carrier particles exhibit high reactivity above 900{degree}C, and the dry basis concentration of CO{sub 2} in the exit gas of the reactor is nearly 95%. The flue gas composition as a function of the reactor temperature and cyclic reduction number is discussed. At 800-960{degree}C, the dry basis concentration of CO{sub 2} in the flue gas presents a monotonously increasing trend, whereas the dry basis concentration of CO, H{sub 2}, and CH{sub 4} decreases monotonously. The concentrations of CO{sub 2}, CO, H{sub 2}, and CH{sub 4} in the flue gas as a function of cyclic reduction number present a para-curve characteristic at 900{degree}C. With the increase of cyclic reduction number, the dry basis concentration of CO{sub 2} decreases remarkably, while the dry basis concentrations of CO, H{sub 2}, and CH{sub 4} increase rapidly. Moreover, the peak value of H{sub 2} concentration is less than that of CO. The performance of the NiO-based oxygen carriers was also evaluated using an X-ray diffractometer and a scanning electron microscope to characterize the solid residues of oxygen carrier. The results indicate that NiO is one of the suitable oxygen carriers for chemical-looping combustion of coal.

Gao, Z.P.; Shen, L.H.; Xiao, J.; Qing, C.J.; Song, Q.L. [Southeast University, Nanjing (China). Thermoenergy Engineering Research Institute

2008-12-15T23:59:59.000Z

79

Reducing the Emission of Particles from a Diesel Engine by Adding an Oxygenate to the Fuel  

Science Journals Connector (OSTI)

A small reduction of the engine power was also observed; however, the net effect was nevertheless a reduction in the emission of CO2 per European stationary cycle. ... A general finding is that the reduction of particles seems to be linearly dependent on the oxygen content, and, thus, the blend with the highest oxygen content results in the highest reduction of particles (14?16). ... Measure ments of NOx, HC, and CO content were performed in accordance with the ESC test cycles and were repeated nine times when the engine was operating on EC-1 diesel and five times when the engine was operating on A-diesel. ...

Kent E. Nord; Dan Haupt

2005-07-09T23:59:59.000Z

80

Chemical-looping combustion of solid fuels in a 10 kW reactor system using natural minerals as oxygen carrier  

Science Journals Connector (OSTI)

Abstract Chemical-looping combustion (CLC) is an unmixed combustion concept where fuel and combustion air are kept separate by means of an oxygen carrier, and the CO2 capture is inherently achieved. This work presents findings from a continuously operated 10 kW pilot for solid fuels. Using petcoke as fuel, the following oxygen carriers are compared: (a) ilmenite, (b) ilmenite + lime, (c) manganese ore, and (d) manganese ore + lime. Compared to ilmenite, the use of manganese ore as oxygen carrier greatly enhanced the rate of gasification. By adding lime particles to the Mn ore, performance improved further. The addition of lime to ilmenite had a small beneficial effect on gas conversion and char gasification rate.

Carl Linderholm; Anders Lyngfelt; Cristina Dueso

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "newable fuels oxygenates" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Oxygen Reduction Kinetics on Electrodeposited PtCo as a Model Catalyst for Proton Exchange Membrane Fuel Cell Cathodes: Stability as a Function of PtCo Composition  

Science Journals Connector (OSTI)

Oxygen Reduction Kinetics on Electrodeposited PtCo as a Model Catalyst for Proton Exchange Membrane Fuel Cell Cathodes: Stability as a Function of PtCo Composition ... When the focus is at reducing cost and improving durability, the PEMFC cathode deserves special attention. ... (4-7) Mukerjee et al. investigated various Pt bimetallic alloys supported on carbon and found a 2?3-fold increase in the oxygen reduction reaction (ORR) activity for the alloy catalysts under PEMFC operating conditions. ...

Kaushik Jayasayee; Van Anh T. Dam; Tiny Verhoeven; Serdar Celebi; Frank A. de Bruijn

2009-11-02T23:59:59.000Z

82

Oxygen reduction in PEM fuel cell conditions: Heat-treated macrocycles and beyond  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

reduction in PEM fuel cell conditions: reduction in PEM fuel cell conditions: Heat-treated macrocycles and beyond J. P. Dodelet INRS-Énergie et Matériaux C. P. 1020, Varennes, Québec, Canada, J3X 1S2 dodelet@inrs-ener.uquebec.ca Collaborators Michel Lefèvre (INRS) Sébastien Marcotte (INRS) Frédéric Jaouen (Royal Inst. of Technology, Sweden) Prof. Patrick Bertrand (Université Catholique de Louvain, Belgium) Prof. Göran Lindbergh (Royal Inst. Of Technology, Sweden) New Orleans workshop March 21 03. DODELET, J. P. ; New Orleans, March 21, 03 1 PEM Fuel Cells Anode : 2 H 2 → 4 H + + 4 e - Electrolyte : Perfluorinated polymer - SO 3 H Cathode : O 2 + 4 H + + 4 e - → 2 H 2 O Acidic Medium ( pH ~ 1 ) Low Temperature Fuel Cell (80°C) ↓ Pt- based Anode and Cathode Catalysts Pt is not abundant and expensive

83

Solid Fuel - Oxygen Fired Combustion for Production of Nodular Reduced Iron to Reduce CO2 Emissions and Improve Energy Efficiencies  

SciTech Connect (OSTI)

The current trend in the steel industry is an increase in iron and steel produced in electric arc furnaces (EAF) and a gradual decline in conventional steelmaking from taconite pellets in blast furnaces. In order to expand the opportunities for the existing iron ore mines beyond their blast furnace customer base, a new material is needed to satisfy the market demands of the emerging steel industry while utilizing the existing infrastructure and materials handling capabilities. This demand creates opportunity to convert iron ore or other iron bearing materials to Nodular Reduced Iron (NRI) in a recently designed Linear Hearth Furnace (LHF). NRI is a metallized iron product containing 98.5 to 96.0% iron and 2.5 to 4% C. It is essentially a scrap substitute with little impurity that can be utilized in a variety of steelmaking processes, especially the electric arc furnace. The objective of this project was to focus on reducing the greenhouse gas emissions (GHG) through reducing the energy intensity using specialized combustion systems, increasing production and the use of biomass derived carbon sources in this process. This research examined the use of a solid fuel-oxygen fired combustion system and compared the results from this system with both oxygen-fuel and air-fuel combustion systems. The solid pulverized fuels tested included various coals and a bio-coal produced from woody biomass in a specially constructed pilot scale torrefaction reactor at the Coleraine Minerals Research Laboratory (CMRL). In addition to combustion, the application of bio-coal was also tested as a means to produce a reducing atmosphere during key points in the fusion process, and as a reducing agent for ore conversion to metallic iron to capture the advantage of its inherent reduced carbon footprint. The results from this study indicate that the approaches taken can reduce both greenhouse gas emissions and the associated energy intensity with the Linear Hearth Furnace process for converting iron ore to metallic iron nodules. Various types of coals including a bio-coal produced though torrefaction can result in production of NRI at reduced GHG levels. The process results coupled with earlier already reported developments indicate that this process technique should be evaluated at the next level in order to develop parameter information for full scale process design. Implementation of the process to full commercialization will require a full cost production analysis and comparison to other reduction technologies and iron production alternatives. The technical results verify that high quality NRI can be produced under various operating conditions at the pilot level.

Donald R. Fosnacht; Richard F. Kiesel; David W. Hendrickson; David J. Englund; Iwao Iwasaki; Rodney L. Bleifuss; Mathew A. Mlinar

2011-12-22T23:59:59.000Z

84

Iridium As Catalyst and Cocatalyst for Oxygen Evolution/Reduction in Acidic Polymer Electrolyte Membrane Electrolyzers and Fuel Cells  

Science Journals Connector (OSTI)

In this work, an overview of the application of Ir and Ir-containing catalysts for the OER in PEMWE anodes, for the ORR in PEMFC cathodes (both in acid medium), and for both OER and ORR in unit regenerative fuel cell (URFC) oxygen electrodes, is presented. ... Rotating disk electrode measurements confirmed that if formic acid was present, these Ir alloy catalysts could still catalyze a complete 4-electron transfer ORR from O2 to H2O, while the Pt/C catalyst could only catalyze a reaction contributed by both 2- and 4-electron transfer processes, producing both H2O2 and H2O. ... Moreover, acceptable stability of these catalysts at high potential in acid environment suits them to the requirements of cathode catalyst in PEMFC or DMFC. ...

Ermete Antolini

2014-03-19T23:59:59.000Z

85

Electrochemical Formation of a Pt/Zn Alloy and Its Use as a Catalyst for Oxygen Reduction Reaction in Fuel Cells  

Science Journals Connector (OSTI)

The oxygen reduction reaction (ORR) occurs on the cathode in a proton exchange membrane fuel cell (PEMFC). ... In addition to the MEAs containing Zn-modified cathodes, MEAs composed of untreated commercially available GDEs with identical catalyst loading and material specifications (i.e., ELAT carbon cloth, Electrochem Inc.) were also prepared in a similar manner and then investigated in a fuel cell testing configuration to evaluate comparatively the effect of the cathode Zn treatment on the fuel cell polarization curves. ... The history, status in recent expts., and prospects for Pt-alloy cathode catalysts are reviewed. ...

Aya Sode; Winton Li; Yanguo Yang; Phillip C. Wong; Elod Gyenge; Keith A. R. Mitchell; Dan Bizzotto

2006-04-12T23:59:59.000Z

86

Quantification of Fuel Oxygenate Ethers in Human Blood using Solid-Phase Microextraction Coupled with Gas Chromatography-High-Resolution Mass Spectrometry  

Science Journals Connector (OSTI)

......Because ofwater solubility, fuel oxygenate...toluene. When water supplies are contaminated...followed by gas chromatography-high-resolution...helium-sparged distilled water (26) to produce...blanks,and water standardsfor daily...column carrier gas for all analyses...using liquid nitrogen from Air Liq......

Lalith K. Silva; Clayton R. Wilburn; Michael A. Bonin; Mitchell M. Smith; Katherine A. Reese; David L. Ashley; Benjamin C. Blount

2008-05-01T23:59:59.000Z

87

Engineering Ralstonia eutropha for Production of Isobutanol (IBT) Motor Fuel from Carbon Dioxide, Hydrogen, and Oxygen Project Final Report  

SciTech Connect (OSTI)

This research project is a collaboration between the Sinskey laboratory at MIT and the Worden laboratory at Michigan State University. The goal of the project is to produce Isobutanol (IBT), a branched-chain alcohol that can serve as a drop-in transportation fuel, through the engineered microbial biosynthesis of Carbon Dioxide, Hydrogen, and Oxygen using a novel bioreactor. This final technical report presents the findings of both the biological engineering work at MIT that extended the native branched-chain amino acid pathway of the wild type Ralstonia eutropha H16 to perform this biosynthesis, as well as the unique design, modeling, and construction of a bioreactor for incompatible gasses at Michigan State that enabled the operational testing of the complete system. This 105 page technical report summarizing the three years of research includes 72 figures and 11 tables of findings. Ralstonia eutropha (also known as Cupriavidus necator) is a Gram-negative, facultatively chemolithoautotrophic bacteria. It has been the principle organism used for the study of polyhydroxybutyrate (PHB) polymer biosynthesis. The wild-type Ralstonia eutropha H16 produces PHB as an intracellular carbon storage material while under nutrient stress in the presence of excess carbon. Under this stress, it can accumulate approximately 80 % of its cell dry weight (CDW) as this intracellular polymer. With the restoration of the required nutrients, the cells are then able to catabolize this polymer. If extracted from the cell, this PHB polymer can be processed into biodegradable and biocompatible plastics, however for this research, it is the efficient metabolic pathway channeling the captured carbon that is of interest. R. eutropha is further unique in that it contains two carbon-fixation Calvin–Benson–Bassham cycle operons, two oxygen-tolerant hydrogenases, and several formate dehydrogenases. It has also been much studied for its ability in the presence of oxygen, to fix carbon dioxide into complex cellular molecules using the energy from hydrogen. In this research project, engineered strains of R. eutropha redirected the excess carbon from PHB storage into the production of isobutanol and 3-methyl-1-butanol (branched-chain higher alcohols). These branched-chain higher alcohols can be used directly as substitutes for fossil-based fuels and are seen as alternative biofuels to ethanol and biodiesel. Importantly, these alcohols have approximately 98 % of the energy content of gasoline, 17 % higher than the current gasoline additive ethanol, without impacting corn market production for feed or food. Unlike ethanol, these branched-chain alcohols have low vapor pressure, hygroscopicity, and water solubility, which make them readily compatible with the existing pipelines, gasoline pumps, and engines in our transportation infrastructure. While the use of alternative energies from solar, wind, geothermal, and hydroelectric has spread for stationary power applications, these energy sources cannot be effectively or efficiently employed in current or future transportation systems. With the ongoing concerns of fossil fuel availability and price stability over the long term, alternative biofuels like branched-chain higher alcohols hold promise as a suitable transportation fuel in the future. We showed in our research that various mutant strains of R. eutropha with isobutyraldehyde dehydrogenase activity, in combination with the overexpression of plasmid-borne, native branched-chain amino acid biosynthesis pathway genes and the overexpression of heterologous ketoisovalerate decarboxylase gene, would produce isobutanol and 3-methyl-1-butanol when initiated during nitrogen or phosphorus limitation. Early on, we isolated one mutant R. eutropha strain which produced over 180 mg/L branched-chain alcohols in flask culture while being more tolerant of isobutanol toxicity. After the targeted elimination of genes encoding several potential carbon sinks (ilvE, bkdAB, and aceE), the production titer of the improved to 270 mg/L isobutanol and 40 mg/L 3-methyl-1-butanol.

Sinskey, Anthony J. [MIT] [MIT; Worden, Robert Mark [Michigan State University MSU] [Michigan State University MSU; Brigham, Christopher [MIT] [MIT; Lu, Jingnan [MIT] [MIT; Quimby, John Westlake [MIT] [MIT; Gai, Claudia [MIT] [MIT; Speth, Daan [MIT] [MIT; Elliott, Sean [Boston University] [Boston University; Fei, John Qiang [MIT] [MIT; Bernardi, Amanda [MIT] [MIT; Li, Sophia [MIT] [MIT; Grunwald, Stephan [MIT] [MIT; Grousseau, Estelle [MIT] [MIT; Maiti, Soumen [MSU] [MSU; Liu, Chole [MSU] [MSU

2013-12-16T23:59:59.000Z

88

Emission of Oxygenated Polycyclic Aromatic Hydrocarbons from Indoor Solid Fuel Combustion  

Science Journals Connector (OSTI)

(17) The relatively high OPAH emissions from indoor burning can be explained by the different amount of oxygen supply resulting in lower combustion efficiencies and relatively high temperature in the enclosed residential stoves due to low heat loss. ... hydrocarbon (PAH) emission source in developing countries; however, PAH emission factor (EF) data for indoor crop residue combustion, particularly field-measured data, are scarce, leading to large uncertainties in emission inventories. ... Shen, G.; Wang, W.; Yang, Y.; Zhu, C.; Min, Y.; Xue, M.; Ding, J.; Li, W.; Wang, B.; Shen, H.; Wang, R.; Wang, X.; Tao, S.Emission factors and particulate matter size distribution of polycyclic aromatic hydrocarbons from residential coal combustions in rural Northern China Atmos. ...

Guofeng Shen; Shu Tao; Wei Wang; Yifeng Yang; Junnan Ding; Miao Xue; Yujia Min; Chen Zhu; Huizhong Shen; Wei Li; Bin Wang; Rong Wang; Wentao Wang; Xilong Wang; Armistead G. Russell

2011-03-04T23:59:59.000Z

89

Investigation of chemical looping combustion by solid fuels. 2. redox reaction kinetics and product characterization with coal, biomass, and solid waste as solid fuels and CuO as an oxygen carrier  

SciTech Connect (OSTI)

This paper is the second in a series of two on the investigation of the chemical looping combustion (CLC) of solid fuels. The first paper put forward the concept of the CLC of solid fuels using a circulating fluidized bed as a reactor and Cu-CuO as the oxygen carrier, which was based on an analysis of oxygen transfer capability, reaction enthalpy, and chemical equilibrium. In this second paper, we report the results of the evaluation of the reduction of CuO reduced by solid fuels such as coal and some other 'opportunity' solid fuels. Tests on the reduction of CuO by the selected solid fuels were conducted using simultaneous differential scanning calorimetry and thermogravimetric analysis, which simulates a microreactor. An attached mass spectrometer (MS) was used for the characterization of evolved gaseous products. The X-ray diffractometer (XRD) and scanning electron microscope (SEM) were used for the characterization of the solid residues. Results strongly supported the feasibility of CuO reduction by selected solid fuels. CuO can be fully converted into Cu in a reduction process, either in a direct path by solid fuels, which was verified by MS analysis under a N{sub 2} atmosphere, or in an indirect path by pyrolysis and gasification products of solid fuels in the reducer. No Cu{sub 2}O exists in reducing atmospheres, which was characterized by an XRD analysis and mass balance calculations. No carbon deposit was found on the surface of the reduced Cu, which was characterized by SEM analysis. CuO reduction by solid fuels can start at temperatures as low as approximately 500 C. Tests indicated that the solid fuels with higher reactivity (higher volatile matter) would be desirable for the development of the chemical looping combustion process of solid fuels, such as sub-bituminous Powder River Basin coal and solid waste and biomass. 4 refs., 12 figs., 3 tabs.

Yan Cao; Bianca Casenas; Wei-Ping Pan [Western Kentucky University, Bowling Green, KY (United States). Institute for Combustion Science and Environmental Technology

2006-10-15T23:59:59.000Z

90

An investigation of steam production in chemical-looping combustion (CLC) and chemical-looping with oxygen uncoupling (CLOU) for solid fuels  

Science Journals Connector (OSTI)

Abstract Chemical-looping combustion (CLC) and chemical-looping with oxygen uncoupling (CLOU) are being actively explored as solid fuel combustion technologies that have the potential to facilitate CO2 capture. While CLC and CLOU have similarities operationally, there are some key differences. In particular, the CLC process requires a coal gasification step where coal is first broken down into a syngas with the use of steam or CO2. The resulting syngas is then oxidized with the metal oxide to release energy. In the CLOU process the metal oxide releases oxygen that combusts the solid fuel, resulting in a lower residence time, as the coal gasification reactions are avoided. The CLC and CLOU systems were modeled with ASPEN Plus at a 10 \\{MWth\\} scale, and the process streams were analyzed by ASPEN Energy Analyzer to determine the amount of industrial process steam that could be generated from CLC or CLOU. Both the air and fuel reactor were analyzed as two circulating fluidized beds, with metal oxide circulating between the two reactors. The air reactor, where metal oxide is oxidized, was fluidized with air. The fuel reactor, where the metal oxide is reduced, was fluidized with steam for CLC and recirculated CO2 for CLOU. It was identified that the CLOU process had the potential to produce more steam, approximately 7920 kg/hr, as compared to CLC (6910 kg/hr).

J.K. Dansie; A.H. Sahir; M.A. Hamilton; J.S. Lighty

2014-01-01T23:59:59.000Z

91

Oxygen Electrocatalysis on Epitaxial La[subscript 0.6]Sr[subscript 0.4]CoO[subscript 3-?] Perovskite Thin Films for Solid Oxide Fuel Cells  

E-Print Network [OSTI]

Hetero-structured interfaces of oxides, which can exhibit reactivity characteristics remarkably different from bulk oxides, are interesting systems to explore in search of highly active fuel cell catalysts for oxygen ...

Crumlin, Ethan J.

92

The effect of oxygen-to-fuel stoichiometry on coal ash fine-fragmentation mode formation mechanisms.  

SciTech Connect (OSTI)

Ash particles smaller than 2.5 {micro}m in diameter generated during pulverized coal combustion are difficult to capture and may pose greater harm to the environment and human health than the discharge of larger particles. Recent research efforts on coal ash formation have revealed a middle fine-fragment mode centered around 2 {micro}m. Formation of this middle or fine-fragment mode (FFM) is less well understood compared to larger coarse and smaller ultrafine ash. This study is part of an overall effort aimed at determining the key factors that impact the formation of FFM. This work examined the effects of oxygen-to-fuel stoichiometry (OFS). Pulverized Illinois No.6 bituminous coal was combusted and the ash generated was size segregated in a Dekati low pressure inertial impactor. The mass of each fraction was measured and the ash was analyzed using scanning electron microscopy (SEM) and X-ray microanalysis. The FFM ash types were classified based on the SEM images to evaluate the significant fine-fragment ash formation mechanisms and determine any possible link between stoichiometry and formation mechanism. From the particle size distributions (PSDs), the coarse mode appears unaffected by the change in OFS, however, the OFS 1.05 lowered the fraction of ultrafine ash in relation to the higher OFS settings, and appears to increase the portion of the FFM. An intermediate minimum was found in the FFM at 1.3 {micro}m for the 1.20 and 1.35 OFS tests but was not observed in the 1.05 OFS. SEM analysis also suggests that OFS may contribute to changing formation mechanisms.

Fix, G.; Seames, W. S.; Mann, M. D.; Benson, S. A.; Miller, D. J. (Materials Science Division); (Univ. of North Dakota)

2011-04-01T23:59:59.000Z

93

Contiguous Platinum Monolayer Oxygen Reduction Electrocatalysts on High-Stability Low-Cost Supports - DOE Hydrogen and Fuel Cells Program FY 2012 Annual Progress Report  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

7 7 FY 2012 Annual Progress Report DOE Hydrogen and Fuel Cells Program Radoslav Adzic (Primary Contact), Miomir Vukmirovic, Kotaro Sasaki, Jia Wang, Yang Shao-Horn 1 , Rachel O'Malley 2 Brookhaven National Laboratory (BNL), Bldg. 555 Upton, NY 11973-5000 Phone: (631) 344-4522 Email: adzic@bnl.gov DOE Manager HQ: Nancy Garland Phone: (202) 586-5673 Email: Nancy.Garland@ee.doe.gov Subcontractors: 1 Massachusetts Institute of Technology (MIT), Cambridge MA 2 Johnson Matthey Fuel Cells (JMFC), London, England Project Start Date: July 1, 2009 Project End Date: September 30, 2013 Fiscal Year (FY) 2012 Objectives Developing high-performance fuel cell electrocatalysts for the oxygen reduction reaction (ORR) comprising contiguous Pt monolayer (ML) on stable, inexpensive metal

94

Oxygen transport resistance correlated to liquid water saturation in the gas diffusion layer of PEM fuel cells  

E-Print Network [OSTI]

22 November 2013 Accepted 24 December 2013 Keywords: Fuel cells PEM Diffusion Saturation Neutron than 0.15 gPt kWÃ?1 will not be cost competitive. As a result, fuel cell researchers are exploring fuel cells Jon P. Owejan a,b, , Thomas A. Trabold c , Matthew M. Mench b a SUNY Alfred State College

Mench, Matthew M.

95

Platinum Monolayer Electrocatalysts for Oxygen Reduction Reaction...  

Broader source: Energy.gov (indexed) [DOE]

Platinum Monolayer Electrocatalysts for Oxygen Reduction Reaction Platinum Monolayer Electrocatalysts for Oxygen Reduction Reaction Presentation slides from the June 19, 2012, Fuel...

96

Multi-phase Multi-dimensional Analysis of PEM Fuel Cells with Carbon Monoxide Poisoning and Oxygen Bleeding.  

E-Print Network [OSTI]

??Polymer electrolyte membrane (PEM) fuel cells are promising alternative green power source for mobile, portable and stationary applications. However, their cost, durability, and performance are… (more)

Li, Yaqun

2010-01-01T23:59:59.000Z

97

Investigation of coal fueled chemical looping combustion using Fe3O4 as oxygen carrier: Influence of variables  

Science Journals Connector (OSTI)

Chemical-looping combustion (CLC) is a novel combustion technique with inherent CO2 separation. Magnetite (Fe3O4) was selected as the oxygen carrier. Shenhua coal (Inner Mongolia, China), straw coke and natural c...

Xiaoyan Sun; Wenguo Xiang; Sha Wang; Wendong Tian; Xiang Xu…

2010-06-01T23:59:59.000Z

98

Fuels  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Goals > Fuels Goals > Fuels XMAT for nuclear fuels XMAT is ideally suited to explore all of the radiation processes experienced by nuclear fuels.The high energy, heavy ion accleration capability (e.g., 250 MeV U) can produce bulk damage deep in the sample, achieving neutron type depths (~10 microns), beyond the range of surface sputtering effects. The APS X-rays are well matched to the ion beams, and are able to probe individual grains at similar penetrations depths. Damage rates to 25 displacements per atom per hour (DPA/hr), and doses >2500 DPA can be achieved. MORE» Fuels in LWRs are subjected to ~1 DPA per day High burn-up fuel can experience >2000 DPA. Traditional reactor tests by neutron irradiation require 3 years in a reactor and 1 year cool down. Conventional accelerators (>1 MeV/ion) are limited to <200-400 DPAs, and

99

Oxygen Reduction in PEM Fuel Cell Conditions: Heat-Treated Non-Precious Metal-N4 Macrocycles and Beyond  

Science Journals Connector (OSTI)

Traditionally, fossil fuels (coal, oil, gas) have been used to satisfy the world’s energy needs. However, these resources are not endless. For instance, at the present 2% growth in demand, the peak of world pe...

Jean-Pol Dodelet

2006-01-01T23:59:59.000Z

100

Routine Analysis of Oxygenates and Benzene in Retail Motor Fuel: A Survey by the State of Alabama  

Science Journals Connector (OSTI)

......alternative to Mideast oil dependency; fuel pumps carried the corn insignia and the message, "Buy American." This trend...conventional ASTM method. Approximate values. an existing wet-milling corn facility in Decatur, Alabama is considering an expansion......

Guy Vaughan Johnson

1987-02-01T23:59:59.000Z

Note: This page contains sample records for the topic "newable fuels oxygenates" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Pt Nanoparticle-Dispersed Graphene-Wrapped MWNT Composites As Oxygen Reduction Reaction Electrocatalyst in Proton Exchange Membrane Fuel Cell  

Science Journals Connector (OSTI)

The rapid devastation of nonrenewable energy sources demanded the development of alternative energy conversion devices such as fuel cells with high efficiency and environmental benignity. ... (1-3) The commercialization of proton exchange membrane fuel cell (PEMFC) is still not achieved because of the high cost of the electrocatalyst, platinum (Pt). ... Carbon supported electrocatalysts have been found to be effective in reducing the amount of platinum and enhancing the PEMFC performance. ...

S. S. Jyothirmayee Aravind; Sundara Ramaprabhu

2012-08-01T23:59:59.000Z

102

Influence of Chemical and Physical Properties of Activated Carbon Powders on Oxygen Reduction and Microbial Fuel Cell Performance  

E-Print Network [OSTI]

resource. Cathode materials can account for 47-75% of the MFC capital costs,5 and therefore it is important to choose less expensive materials as the cathode catalyst. Several catalysts have been considered for useInfluence of Chemical and Physical Properties of Activated Carbon Powders on Oxygen Reduction

103

Oxygen reduction on gas-diffusion electrodes for phosphoric acid fuel cells by a potential decay method  

SciTech Connect (OSTI)

The reduction of gaseous oxygen on carbon-supported platinum electrodes has been studied at 150 C with polarization and potential decay measurements. The electrolyte was either 100 weight percent phosphoric acid or that acid with a fluorinated additive, potassium perfluorohexanesulfonate (C{sub 6}F{sub 13}SO{sub 3}K). The pseudo-Tafel curves of the overpotential vs log (ii{sub L}/(i{sub L}{minus}i)) show a two-slope behavior, probably due to different adsorption mechanisms. The potential relaxations as functions of log (t+r) and log({minus}d{eta}/dt) have been plotted. The variations of these slopes and the dependence of the double-layer capacitance on the overpotential depended on the electrode manufacture and the kind of electrolyte (whether containing the fluorinated additive or not).

Li Qingfeng; Xiao Gang; Hjuler, H.A.; Berg, R.W.; Bjerrum, N.J. [Technical Univ. of Denmark, Lyngby (Denmark). Dept. of Chemistry

1995-10-01T23:59:59.000Z

104

Hazards Induced by Breach of Liquid Rocket Fuel Tanks: Conditions and Risks of Cryogenic Liquid Hydrogen-Oxygen Mixture Explosions  

E-Print Network [OSTI]

We analyze the data of purposeful rupture experiments with LOx and LH2 tanks, the Hydrogen-Oxygen Vertical Impact (HOVI) tests that were performed to clarify the ignition mechanisms, the explosive power of cryogenic H2/Ox mixtures under different conditions, and to elucidate the puzzling source of the initial formation of flames near the intertank section during the Challenger disaster. We carry out a physics-based analysis of general explosions scenarios for cryogenic gaseous H2/Ox mixtures and determine their realizability conditions, using the well-established simplified models from the detonation and deflagration theory. We study the features of aerosol H2/Ox mixture combustion and show, in particular, that aerosols intensify the deflagration flames and can induce detonation for any ignition mechanism. We propose a cavitation-induced mechanism of self-ignition of cryogenic H2/Ox mixtures that may be realized when gaseous H2 and Ox flows are mixed with a liquid Ox turbulent stream, as occurred in all HOVI ...

Osipov, Viatcheslav; Hafiychuk, Halyna; Ponizovskaya-Devine, Ekaterina; Smelyanskiy, Vadim; Mathias, Donovan; Lawrence, Scott; Werkheiser, Mary

2010-01-01T23:59:59.000Z

105

Direct Observation of the Oxygenated Species during Oxygen Reduction on a  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Direct Observation of the Oxygenated Species during Oxygen Reduction on a Direct Observation of the Oxygenated Species during Oxygen Reduction on a Platinum Fuel Cell Cathode Friday, December 20, 2013 Fuel Cell Figure 1 Figure 1. In situ x-ray spectroscopy identification and DFT simulations of oxygenated intermediates on a platinum fuel-cell cathode. The study shows that two types of hydroxyl intermediates (non-hydrated OH and hydrated OH) with distinct activities coexist on a fuel-cell cathode. The performance of polymer-electrolyte-membrane (PEM) fuel cells is limited by the reduction at the cathode of various oxygenated intermediates in the four-electron pathway of the oxygen reduction reaction. A research team led by SLAC scientists performed x-ray spectroscopy identification and DFT simulations of oxygenated intermediates on a platinum fuel-cell cathode

106

Oxygen ion conducting materials  

DOE Patents [OSTI]

An oxygen ion conducting ceramic oxide that has applications in industry including fuel cells, oxygen pumps, oxygen sensors, and separation membranes. The material is based on the idea that substituting a dopant into the host perovskite lattice of (La,Sr)MnO.sub.3 that prefers a coordination number lower than 6 will induce oxygen ion vacancies to form in the lattice. Because the oxygen ion conductivity of (La,Sr)MnO.sub.3 is low over a very large temperature range, the material exhibits a high overpotential when used. The inclusion of oxygen vacancies into the lattice by doping the material has been found to maintain the desirable properties of (La,Sr)MnO.sub.3, while significantly decreasing the experimentally observed overpotential.

Vaughey, John (Elmhurst, IL); Krumpelt, Michael (Naperville, IL); Wang, Xiaoping (Downers Grove, IL); Carter, J. David (Bolingbrook, IL)

2003-01-01T23:59:59.000Z

107

Mesoporous Pt–Co oxygen reduction reaction (ORR) catalysts for low temperature proton exchange membrane fuel cell synthesized by alternating sputtering  

Science Journals Connector (OSTI)

Abstract Mesoporous catalysts with enhanced oxygen reduction reaction (ORR) activity for PEM fuel cells are synthesized by alternating sputtering of Pt and Co onto gas diffusion layers with microporous layers. Co is acting as a template for synthesis of a porous Pt nanostructure. For such proposed Pt–Co catalysts the kinetic current in the ORR was found to be increased by a factor of up to 16 and the mass specific current in PEM single cells by a factor of up to 7. Co was found to be deposited at the grain boundary of the Pt layer and dissolves under acidic conditions resulting in a mesoporous Pt catalyst which is advantageous for gas diffusion catalysts. Microstructural and compositional parameters were optimised in order to obtain a high kinetic current and lower onset potential for the ORR. The most favourable Co layer thickness was determined to be 2 nm. The optimal Pt–Co catalyst can be synthesized by continuously varying the Pt layer thickness. The highest Pt mass activity was found at a layer thickness of 30.5 nm. Catalysts were characterised by SEM, EDX, electrochemical half cell and PEM single cell tests.

Gustav Sievers; Steffen Mueller; Antje Quade; Florian Steffen; Sven Jakubith; Angela Kruth; Volker Brueser

2014-01-01T23:59:59.000Z

108

Deactivation and Regeneration of Oxygen Reduction Reactivity on Double Perovskite Ba2Bi0.1Sc0.2Co1.7O6?x Cathode for Intermediate-Temperature Solid Oxide Fuel Cells  

Science Journals Connector (OSTI)

Deactivation and Regeneration of Oxygen Reduction Reactivity on Double Perovskite Ba2Bi0.1Sc0.2Co1.7O6?x Cathode for Intermediate-Temperature Solid Oxide Fuel Cells ... Most notably, cathodic polarization treatment, for example, current discharge from BBSC, can be utilized to recover the original ORR performance. ... After evaporation of water at 120 °C, a dark purple gel was recovered. ...

Wei Zhou; Jaka Sunarso; Julius Motuzas; Fengli Liang; Zhigang Chen; Lei Ge; Shaomin Liu; Anne Julbe; Zhonghua Zhu

2011-02-28T23:59:59.000Z

109

Kinetic determination of a highly reactive impregnated Fe2O3/Al2O3 oxygen carrier for use in gas-fueled Chemical Looping Combustion  

Science Journals Connector (OSTI)

Abstract The objective of this work was to determine the kinetic parameters for reduction and oxidation reactions of a highly reactive Fe-based oxygen carrier for use in Chemical Looping Combustion (CLC) of gaseous fuels containing CH4, CO and/or H2, e.g. natural gas, syngas and PSA-off gas. The oxygen carrier was prepared by impregnation of iron on alumina. The effect of both the temperature and gas concentration was analyzed in a thermogravimetric analyzer (TGA). The grain model with uniform conversion in the particle and reaction in grains following the shrinking core model (SCM) was used for kinetics determination. It was assumed that the reduction reactions were controlled by two different resistances: the reaction rate was controlled by chemical reaction in a first step, whereas the mechanism that controlled the reactions at higher conversion values was diffusion through the product layer around the grains. Furthermore, it was found that the reduction reaction mechanism was based on the interaction of Fe2O3 with Al2O3 in presence of the reacting gases to form FeAl2O4 as the only stable Fe-based phase. The reaction order values found for the reducing gases were 0.25, 0.3 and 0.6 for CH4, H2 and CO, respectively, and the activation energy took values of between 8 kJ mol?1 (for H2) and 66 kJ mol?1 (for CH4). With regard to oxidation kinetics, the reacting model assumed a reaction rate that was only controlled by chemical reaction. Values of 0.9 and 23 kJ mol?1 were found for reaction order and activation energy, respectively. Finally, the solids inventory needed in a CLC system was also estimated by considering kinetic parameters. The total solids inventory in the CLC unit took a minimum value of 150 kg MW?1 for CH4 combustion, which is a low value when compared to those of other Fe-based materials found in the literature.

A. Cabello; A. Abad; F. García-Labiano; P. Gayán; L.F. de Diego; J. Adánez

2014-01-01T23:59:59.000Z

110

Natural Ores as Oxygen Carriers in Chemical Looping Combustion  

Science Journals Connector (OSTI)

Natural Ores as Oxygen Carriers in Chemical Looping Combustion ... Chemical looping combustion (CLC) is a combustion technology that utilizes oxygen from oxygen carriers (OC), such as metal oxides, instead of air to combust fuels. ...

Hanjing Tian; Ranjani Siriwardane; Thomas Simonyi; James Poston

2013-01-02T23:59:59.000Z

111

Renewable Oxygenate Blending Effects on Gasoline Properties  

Science Journals Connector (OSTI)

Renewable Oxygenate Blending Effects on Gasoline Properties ... National Renewable Energy Laboratory, Golden, Colorado 80401, United States ... Energy Fuels, 2011, 25 (10), ...

Earl Christensen; Janet Yanowitz; Matthew Ratcliff; Robert L. McCormick

2011-08-16T23:59:59.000Z

112

Semi-pilot scale test for production of hydrogen-rich fuel gas from different wastes by means of a gasification and smelting process with oxygen multi-blowing  

Science Journals Connector (OSTI)

In Europe, most wastes are deposited in landfills, but a European Council directive has called for a 30% reduction of the landfill amount. Though the cement industry commonly burns waste as an alternative fuel together with fossil fuel (so-called waste co-incineration), it is necessary to reconsider this co-incineration from the viewpoints of sustainable development and cement quality. Gasification and smelting processes (GSPs) for waste can convert waste to slag and fuel gas, which can be used by the energy sector and industry, so these processes are desirable in that they provide wide social benefit. Considering its low environmental impact and good economic performance, a GSP that uses a one-process furnace and oxygen multi-blowing was tested on a semi-pilot scale (1.7 tons/day) to convert different wastes (municipal waste, plastic waste and refuse of polyvinyl chloride with a chlorine content of 48%) to slag and hydrogen-rich fuel gas. The results show that the techniques applied in this test increase the quality of the produced fuel gas, strictly control pollutants, and prolong the life of the plant. Furthermore, the tested GSP has the potential to be linked with a hydrogen-based system through its production of hydrogen-rich fuel gas.

R. Kikuchi; H. Sato; Y. Matsukura; T. Yamamoto

2005-01-01T23:59:59.000Z

113

A Comparison of Combustion and Emissions of Diesel Fuels and...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

A Comparison of Combustion and Emissions of Diesel Fuels and Oxygenated Fuels in a Modern DI Diesel Engine A Comparison of Combustion and Emissions of Diesel Fuels and Oxygenated...

114

Fuel Cells as Rechargeable Batteries  

Science Journals Connector (OSTI)

The combination of water electrolysis, storage of the produced hydrogen and oxygen and subsequent electrochemical recombination of the stored hydrogen and oxygen in a fuel cell provide the basis for a practical e...

J. Giner; A. Laconti

1996-01-01T23:59:59.000Z

115

E-Print Network 3.0 - activity peak oxygen Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Yttria-stabilized zirconia, a well known oxygen ion... including fuel cells, oxygen pumps, and chemical gas sensors because of a number of superior properties... such as heat...

116

Fuel Cells Get New BFF | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Fuel Cells Get New BFF Fuel Cells Get New BFF Artificial diamonds may lead to affordable, efficient fuel cells Oxygen (red spheres) migrates from one vacancy to another inside the...

117

Analysis and design of the internal mass transfer in oxygen-hydrogen fuel cell with a capillary membrane and with convective drainage of vaporous reaction products  

Science Journals Connector (OSTI)

The mechanism of mass transfer is analyzed by which water vapor drains convectively from an electrode-condenser system in a fuel cell with a capillary membrane. The problem of optimizing the mass-transfer para...

V. N. Serebryakov; M. V. Mel'nikov; V. S. Ovchinnikov…

1973-01-01T23:59:59.000Z

118

2009 Fuel Cell Market Report  

Fuel Cell Technologies Publication and Product Library (EERE)

Fuel cells are electrochemical devices that combine hydrogen and oxygen to produce electricity, water, and heat. Unlike batteries, fuel cells continuously generate electricity, as long as a source of

119

A survey of alternative oxygen production technologies  

Science Journals Connector (OSTI)

Utilization of the Martian atmosphere for the production of fuel and oxygen has been extensively studied. The baseline fuel production process is a Sabatier reactor which produces methane and water from carbon dioxide and hydrogen. The oxygen produced from the electrolysis of the water is only half of that needed for methane-based rocket propellant and additional oxygen is needed for breathing air fuel cells and other energy sources. Zirconia electrolysis cells for the direct reduction of CO 2 are being developed as an alternative means of producing oxygen but present many challenges for a large-scale oxygen production system. The very high operating temperatures and fragile nature of the cells coupled with fairly high operating voltages leave room for improvement. This paper will survey alternative oxygen production technologies present data on operating characteristics materials of construction and some preliminary laboratory results on attempts to implement each.

Dale E. Lueck; Clyde F. Parrish; William J. Buttner; Jan M. Surma

2001-01-01T23:59:59.000Z

120

Oxygenate Supply/Demand Balances  

Gasoline and Diesel Fuel Update (EIA)

Oxygenate Supply/Demand Oxygenate Supply/Demand Balances in the Short-Term Integrated Forecasting Model By Tancred C.M. Lidderdale This article first appeared in the Short-Term Energy Outlook Annual Supplement 1995, Energy Information Administration, DOE/EIA-0202(95) (Washington, DC, July 1995), pp. 33-42, 83-85. The regression results and historical data for production, inventories, and imports have been updated in this presentation. Contents * Introduction o Table 1. Oxygenate production capacity and demand * Oxygenate demand o Table 2. Estimated RFG demand share - mandated RFG areas, January 1998 * Fuel ethanol supply and demand balance o Table 3. Fuel ethanol annual statistics * MTBE supply and demand balance o Table 4. EIA MTBE annual statistics * Refinery balances

Note: This page contains sample records for the topic "newable fuels oxygenates" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Optimization of Oxygen Purity for Coal Conversion Energy Reduction  

E-Print Network [OSTI]

The conversion of coal into gaseous and liquid fuels and chemical feedstock will require large quantities of oxygen. This oxygen will be produced in large multi-train air separation plants which will consume about 350 kilowatt hours of energy...

Baker, C. R.; Pike, R. A.

1982-01-01T23:59:59.000Z

122

Quantification of Fuel Oxygenate Ethers in Human Blood using Solid-Phase Microextraction Coupled with Gas Chromatography-High-Resolution Mass Spectrometry  

Science Journals Connector (OSTI)

......which performsautomatedsample heating, SPME extraction, and GC injection...fibers were preconditioned by heating at 250~ for 2 h. Fuel oxy...accurate, the high purchase price of the HRMSand the high cost...Information Administration, Office of Oil and Gas. Petroleum Supply Monthly......

Lalith K. Silva; Clayton R. Wilburn; Michael A. Bonin; Mitchell M. Smith; Katherine A. Reese; David L. Ashley; Benjamin C. Blount

2008-05-01T23:59:59.000Z

123

Non-precious Co3O4 nano-rod electrocatalyst for oxygen reduction reaction in anion-exchange membrane fuel cells  

E-Print Network [OSTI]

Non-precious Co3O4 nano-rod electrocatalyst for oxygen reduction reaction in anion 2011 DOI: 10.1039/c1ee01431e We report preparation of carbon-supported Co3O4 electrocatalysts with nano that the non-precious Co3O4 electrocatalyst with the nano-rod structure ($12 nm in length and $5.1 nm

Zhao, Tianshou

124

Use of Oxygen Isotopic Exchange to Explore Catalytic Activity and the Mechanism of Oxygen Reduction on Oxides.  

E-Print Network [OSTI]

??The electrochemical performance of intermediate temperature solid oxide fuel cells is limited by high polarization losses incurred from the oxygen reduction reaction at the cathode.… (more)

Kan, Cynthia

2009-01-01T23:59:59.000Z

125

Chapter 3 - Fuels for Fuel Cells  

Science Journals Connector (OSTI)

Publisher Summary This chapter deals with various types of liquid fuels and the relevant chemical and physical properties of these fuels as a means of comparison to the fuels of the future. It gives an overview of the manufacture and properties of the common fuels as well as a description of various biofuels. A fuel mixture usually contains a wide range of organic compounds (usually hydrocarbons). The specific mixture of hydrocarbons gives a fuel its characteristic properties, such as boiling point, melting point, density, viscosity, and a host of other properties. Depending on the application (stationary, central power, remote, auxiliary, transportation, military, etc.), there are a wide range of conventional fuels, such as natural gas, liquefied petroleum gas, light distillates, methanol, ethanol, dimethyl ether, naphtha, gasoline, kerosene, jet fuels, diesel, and biodiesel, that could be used in reforming processes to produce hydrogen (or hydrogen-rich synthesis gas) to power fuel cells. Fossils fuels include gaseous fuels, gasoline, kerosene, diesel fuel, and jet fuels. Gaseous fuels include natural gas and liquefied petroleum gas. Types of gasoline include automotive gasoline, aviation gasoline, and gasohol. Some additives added into gasoline are antioxidants, corrosion inhibitors, demulsifiers, anti-icing, dyes and markers, drag reducers, and oxygenates.

James G. Speight

2011-01-01T23:59:59.000Z

126

Composite oxygen transport membrane  

DOE Patents [OSTI]

A method of producing a composite oxygen ion membrane and a composite oxygen ion membrane in which a porous fuel oxidation layer and a dense separation layer and optionally, a porous surface exchange layer are formed on a porous support from mixtures of (Ln.sub.1-xA.sub.x).sub.wCr.sub.1-yB.sub.yO.sub.3-.delta. and a doped zirconia. In the porous fuel oxidation layer and the optional porous surface exchange layer, A is Calcium and in the dense separation layer A is not Calcium and, preferably is Strontium. Preferred materials are (La.sub.0.8Ca.sub.0.2).sub.0.95Cr.sub.0.5Mn.sub.0.5O.sub.3-.delta. for the porous fuel oxidation and optional porous surface exchange layers and (La.sub.0.8Sr.sub.0.2).sub.0.95Cr.sub.0.5Fe.sub.0.5O.sub.3-.delta. for the dense separation layer. The use of such materials allows the membrane to sintered in air and without the use of pore formers to reduce membrane manufacturing costs. The use of materials, as described herein, for forming the porous layers have application for forming any type of porous structure, such as a catalyst support.

Christie, Gervase Maxwell; Lane, Jonathan A.

2014-08-05T23:59:59.000Z

127

Catalytic conversion of cellulose to liquid hydrocarbon fuels by progressive removal of oxygen to facilitate separation processes and achieve high selectivities  

DOE Patents [OSTI]

Described is a method to make liquid chemicals, such as functional intermediates, solvents, and liquid fuels from biomass-derived cellulose. The method is cascading; the product stream from an upstream reaction can be used as the feedstock in the next downstream reaction. The method includes the steps of deconstructing cellulose to yield a product mixture comprising levulinic acid and formic acid, converting the levulinic acid to .gamma.-valerolactone, and converting the .gamma.-valerolactone to pentanoic acid. Alternatively, the .gamma.-valerolactone can be converted to a mixture of n-butenes. The pentanoic acid so formed can be further reacted to yield a host of valuable products. For example, the pentanoic acid can be decarboxylated yield 1-butene or ketonized to yield 5-nonanone. The 5-nonanone can be hydrodeoxygenated to yield nonane, or 5-nonanone can be reduced to yield 5-nonanol. The 5-nonanol can be dehydrated to yield nonene, which can be dimerized to yield a mixture of C.sub.9 and C.sub.18 olefins, which can be hydrogenated to yield a mixture of alkanes. Alternatively, the nonene may be isomerized to yield a mixture of branched olefins, which can be hydrogenated to yield a mixture of branched alkanes. The mixture of n-butenes formed from .gamma.-valerolactone can also be subjected to isomerization and oligomerization to yield olefins in the gasoline, jet and Diesel fuel ranges.

Dumesic, James A. (Verona, WI); Ruiz, Juan Carlos Serrano (Madison, WI); West, Ryan M. (Madison, WI)

2012-04-03T23:59:59.000Z

128

Superfast oxygen exchange kinetics on highly epitaxial LaBaCo2O5+? thin films for intermediate temperature solid oxide fuel cells  

Science Journals Connector (OSTI)

Superfast chemical dynamics on highly epitaxial LaBaCo2O5+? (LBCO) heterostructures were systematically studied with symmetric half-cell LBCO/Gd0.2Ce0.8O2 (GCO):Y0.08Zr0.92O2 (YSZ)/LBCO heterostructures on (001) LaAlO3. The electrochemical impedance spectroscopy measurements reveal that the LBCO film electrodes have an ultralow polarization resistance as low as 0.11 ??cm2 at 600 °C in air a superfast surface exchange coefficient of 0.017 cm/s at 600° and an extremely low activation energy value of 0.49 eV. These excellent physical chemistry properties and superfast chemical dynamics on the highly epitaxial LBCO thin films are considered to be somewhat related to the structure entropy of the nano ordered oxygen vacancy structure.

Jian Liu; Gregory Collins; Ming Liu; Chonglin Chen

2013-01-01T23:59:59.000Z

129

OXYGEN TRANSPORT CERAMIC MEMBRANES  

SciTech Connect (OSTI)

Conversion of natural gas to liquid fuels and chemicals is a major goal for the Nation as it enters the 21st Century. Technically robust and economically viable processes are needed to capture the value of the vast reserves of natural gas on Alaska's North Slope, and wean the Nation from dependence on foreign petroleum sources. Technologies that are emerging to fulfill this need are all based syngas as an intermediate. Syngas (a mixture of hydrogen and carbon monoxide) is a fundamental building block from which chemicals and fuels can be derived. Lower cost syngas translates directly into more cost-competitive fuels and chemicals. The currently practiced commercial technology for making syngas is either steam methane reforming (SMR) or a two-step process involving cryogenic oxygen separation followed by natural gas partial oxidation (POX). These high-energy, capital-intensive processes do not always produce syngas at a cost that makes its derivatives competitive with current petroleum-based fuels and chemicals. This project has the following 6 main tasks: Task 1--Design, fabricate and evaluate ceramic to metal seals based on graded ceramic powder/metal braze joints. Task 2--Evaluate the effect of defect configuration on ceramic membrane conductivity and long term chemical and structural stability. Task 3--Determine materials mechanical properties under conditions of high temperatures and reactive atmospheres. Task 4--Evaluate phase stability and thermal expansion of candidate perovskite membranes and develop techniques to support these materials on porous metal structures. Task 5--Assess the microstructure of membrane materials to evaluate the effects of vacancy-impurity association, defect clusters, and vacancy-dopant association on the membrane performance and stability. Task 6--Measure kinetics of oxygen uptake and transport in ceramic membrane materials under commercially relevant conditions using isotope labeling techniques.

Dr. Sukumar Bandopadhyay; Dr. Nagendra Nagabhushana

2001-12-01T23:59:59.000Z

130

Hydrogen from Water in a Novel Recombinant Oxygen-Tolerant Cyanobacterial System - DOE Hydrogen and Fuel Cells Program FY 2012 Annual Progress Report  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

3 3 FY 2012 Annual Progress Report DOE Hydrogen and Fuel Cells Program Philip D. Weyman (Primary Contact), Isaac T. Yonemoto, Hamilton O. Smith J. Craig Venter Institute 10355 Science Center Dr. San Diego, CA 92121 Phone: (858) 200-1815 Email: pweyman@jcvi.org DOE Managers HQ: Eric Miller Phone: (202) 287-5829 Email: Eric.Miller@hq.doe.gov GO: Katie Randolph Phone: (720) 356-1759 Email: Katie.Randolph@go.doe.gov Contract Number: DE-FC36-05GO15027 National Laboratory Collaborators: * Karen Wawrousek, Scott Noble, Jianping Yu, and Pin-Ching Maness * National Renewable Energy Laboratory (NREL), Golden, CO Project Start Date: May 1, 2005 Project End Date: January 30, 2014

131

OXYGEN TRANSPORT CERAMIC MEMBRANES  

SciTech Connect (OSTI)

Conversion of natural gas to liquid fuels and chemicals is a major goal for the Nation as it enters the 21st Century. Technically robust and economically viable processes are needed to capture the value of the vast reserves of natural gas on Alaska's North Slope, and wean the Nation from dependence on foreign petroleum sources. Technologies that are emerging to fulfill this need are all based syngas as an intermediate. Syngas (a mixture of hydrogen and carbon monoxide) is a fundamental building block from which chemicals and fuels can be derived. Lower cost syngas translates directly into more cost-competitive fuels and chemicals. The currently practiced commercial technology for making syngas is either steam methane reforming (SMR) or a two-step process involving cryogenic oxygen separation followed by natural gas partial oxidation (POX). These high-energy, capital-intensive processes do not always produce syngas at a cost that makes its derivatives competitive with current petroleum-based fuels and chemicals.

Dr. Sukumar Bandopadhyay; Dr. Nagendra Nagabhushana

2002-01-01T23:59:59.000Z

132

Fossil Fuels Without CO2 Emissions  

Science Journals Connector (OSTI)

...oxygen, or by steam reforming of the fuel to yield...coal beds contain methane adsorbed on...oxygen, or by steam reforming of the...coal beds contain methane adsorbed on...to coal-bed methane production, these...

E. A. Parson; D. W. Keith

1998-11-06T23:59:59.000Z

133

Fuel Equivalence Ratio Imaging for Methane Jets  

Science Journals Connector (OSTI)

A 2-D fuel/oxygen equivalence ratio imaging system has been developed. The technique exploits the efficient quenching of the fluorescence of organic molecules by molecular oxygen in...

Ni, T Q; Melton, L A

1993-01-01T23:59:59.000Z

134

5, 1206712102, 2005 Alternative fuel  

E-Print Network [OSTI]

ACPD 5, 12067­12102, 2005 Alternative fuel blends and regional air quality J.-F. Vinuesa et al and Physics Discussions Impacts of using reformulated and oxygenated fuel blends on the regional air quality License. 12067 #12;ACPD 5, 12067­12102, 2005 Alternative fuel blends and regional air quality J

Paris-Sud XI, Université de

135

Using a dual plasma process to produce cobalt--polypyrrole catalysts for the oxygen reduction reaction in fuel cells -- part II: analysing the chemical structure of the films  

E-Print Network [OSTI]

The chemical structure of cobalt--polypyrrole -- produced by a dual plasma process -- is analysed by means of X-ray photoelectron spectroscopy (XPS), near edge X-ray absorption spectroscopy (NEXAFS), X-ray diffraction (XRD), energy-dispersive X-Ray spectroscopy (EDX) and extended x-ray absorption spectroscopy (EXAFS).It is shown that only nanoparticles of a size of 3\\,nm with the low temperature crystal structure of cobalt are present within the compound. Besides that, cobalt--nitrogen and carbon--oxygen structures are observed. Furthermore, more and more cobalt--nitrogen structures are produced when increasing the magnetron power. Linking the information on the chemical structure to the results about the catalytic activity of the films -- which are presented in part I of this contribution -- it is concluded that the cobalt--nitrogen structures are the probable catalytically active sites. The cobalt--nitrogen bond length is calculated as 2.09\\,\\AA\\ and the carbon--nitrogen bond length as 1.38\\,\\AA.

Walter, Christian; Vyalikh, Denis; Brüser, Volker; Quade, Antje; Weltmann, Klaus-Dieter; 10.1149/2.043209jes

2012-01-01T23:59:59.000Z

136

On some eigenvalue problems in fuel–cell dynamics  

Science Journals Connector (OSTI)

...arising from fuel-cell dynamics...production by fuel cells. This...code, yield solutions of the applied...Bailey and others air side (oxygen rich) fuel side (oxygen...stations run on fossil fuels. In general...the level of pollution is often much...

2003-01-01T23:59:59.000Z

137

Fuel Cell 101  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Fuel Cell 101 Fuel Cell 101 Don Hoffman Don Hoffman Ship Systems & Engineering Research Division March 2011 Distribution Statement A: Approved for public release; distribution is unlimited. Fuel Cell Operation * A Fuel Cell is an electrochemical power source * It supplies electricity by combining hydrogen and oxygen electrochemically without combustion. * It is configured like a battery with anode and cathode. * Unlike a battery, it does not run down or require recharging and will produce electricity and will produce electricity, heat and water as long as fuel is supplied. 2H + + 2e - O 2 + 2H + + 2e - 2H 2 O H 2 Distribution Statement A: Approved for public release; distribution is unlimited. 2 FUEL FUEL CONTROLS Fuel Cell System HEAT & WATER CLEAN CLEAN EXHAUST EXHAUST

138

Proceedings of the Lucerne Fuel Cell Forum 2006 European Solid Oxide Fuel Cell Forum, 3-7 July 2006  

E-Print Network [OSTI]

Proceedings of the Lucerne Fuel Cell Forum 2006 7th European Solid Oxide Fuel Cell Forum, 3-7 July Uncertainties in our understanding of the oxygen reduction mechanism (ORR) at solid oxide fuel cell (SOFC studies have shown that cathodic or anodic dc polarization of the solid oxide fuel cell oxygen electrodes

Yildiz, Bilge

139

Application of Exhaust Gas Fuel Reforming in Compression Ignition Engines Fueled by Diesel and Biodiesel Fuel Mixtures  

Science Journals Connector (OSTI)

In recent years, ester-based oxygenated fuels have been used in compression ignition engines in pure form or as an addition to diesel fuel. ... In hydrocarbon steam reforming (SR), high-temperature steam separates hydrogen from carbon atoms. ...

A. Tsolakis; A. Megaritis; M. L. Wyszynski

2003-09-19T23:59:59.000Z

140

Researchers Directly Observe Oxygen Signature in the Oxygen-evolving  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Researchers Directly Observe Oxygen Signature in the Researchers Directly Observe Oxygen Signature in the Oxygen-evolving Complex of Photosynthesis Arguably the most important chemical reaction on earth is the photosynthetic splitting of water to molecular oxygen by the Mn-containing oxygen-evolving complex (Mn-OEC) in the protein known as photosystem II (PSII). It is this reaction which has, over the course of some 3.8 billion years, gradually filled our atmosphere with O2 and consequently enabled and sustained the evolution of complex aerobic life. Coupled to the reduction of carbon dioxide, biological photosynthesis contributes foodstuffs for nutrition while recycling CO2 from the atmosphere and replacing it with O2. By utilizing sunlight to power these energy-requiring reactions, photosynthesis also serves as a model for addressing societal energy needs as we enter an era of diminishing fossil fuel resources and climate change. Understanding, at the molecular level, the dynamics and mechanisms behind photosynthesis is of fundamental importance and will prove critical to the future design of devices aimed at converting sunlight into electrochemical energy and transportable fuel.

Note: This page contains sample records for the topic "newable fuels oxygenates" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

2008 Fuel Cell Technologies Market Report  

Fuel Cell Technologies Publication and Product Library (EERE)

Fuel cells are electrochemical devices that combine hydrogen and oxygen to produce electricity, water, and heat. Unlike batteries, fuel cells continuously generate electricity, as long as a source of

142

How Fuel Cells Work  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

How Fuel Cells Work How Fuel Cells Work Diagram: How a PEM fuel cell works. 1. Hydrogen fuel is channeled through field flow plates to the anode on one side of the fuel cell, while oxygen from the air is channeled to the cathode on the other side of the cell. 2. At the anode, a platinum catalyst causes the hydrogen to split into positive hydrogen ions (protons) and negatively charged electrons. 3. The Polymer Electrolyte Membrane (PEM) allows only the positively charged ions to pass through it to the cathode. The negatively charged electrons must travel along an external circuit to the cathode, creating an electrical current. 4. At the cathode, the electrons and positively charged hydrogen ions combine with oxygen to form water, which flows out of the cell.

143

NREL: Learning - Fuel Cells  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Fuel Cells Fuel Cells Fuel cells and their ability to cleanly produce electricity from hydrogen and oxygen are what make hydrogen attractive as a "fuel" for transportation use particularly, but also as a general energy carrier for homes and other uses, and for storing and transporting otherwise intermittent renewable energy. Fuel cells function somewhat like a battery-with external fuel being supplied rather than stored electricity-to generate power by chemical reaction rather than combustion. Hydrogen fuel cells, for instance, feed hydrogen gas into an electrode that contains a catalyst, such as platinum, which helps to break up the hydrogen molecules into positively charged hydrogen ions and negatively charged electrons. The electrons flow from the electrode to a terminal that

144

Fuel cell arrangement  

DOE Patents [OSTI]

A fuel cell arrangement is provided wherein cylindrical cells of the solid oxide electrolyte type are arranged in planar arrays where the cells within a plane are parallel. Planes of cells are stacked with cells of adjacent planes perpendicular to one another. Air is provided to the interior of the cells through feed tubes which pass through a preheat chamber. Fuel is provided to the fuel cells through a channel in the center of the cell stack; the fuel then passes the exterior of the cells and combines with the oxygen-depleted air in the preheat chamber.

Isenberg, Arnold O. (Forest Hills Boro, PA)

1987-05-12T23:59:59.000Z

145

HISTORY | Fuel Cells  

Science Journals Connector (OSTI)

Together with the electric motor, dynamo, gas turbine, internal combustion engine, and the fused salt electrolysis of aluminum, the industrial revolution of the nineteenth century brought about the fuel cell – the silent or cold combustion of fossil fuels by the electrochemical oxidation with atmospheric oxygen to water and carbon dioxide. Wilhelm Ostwald, in 1894, emphasized the high efficiency and the nonpolluting properties of the direct conversion of chemical energy into electricity – in contrast to the then combination of steam engine and dynamo, which reached only about 10% efficiency. Direct coal fuel cells designed for the propulsion of ships, however, have not become a reality so far. Instead of fuel cells and batteries, internal combustion engines determined the nineteenth- and twentieth- century technological landscape. Against the background of the oil crisis and the long-term scarcity of natural gas, crude oil, and coal, new hopes have focused on fuel cell technology, which saw first early splendid applications during the space programs of the 1960s, in submarines since the 1980s, and in experimental zero-emission vehicles (ZEVs) since the 1990s. This article outlines (1) early insights about energy conversion: Grove's cell, direct conversion of coal and indirect fuel cells; (2) historical roots of alkaline fuel cells: the discovery of gas diffusion electrodes; low-pressure alkaline fuel cell conquer spacecrafts and submarines; (3) polymer electrolyte fuel cells: solid polymer technology, electric vehicles, direct methanol fuel-cell, stationary power systems and portable polymer electrolyte membrane fuel cell systems; (4) phosphoric acid fuel cell (PAFC): acid fuel cells, PAFC plants in Japan, gasoline fuel cells; and (5) high-temperature fuel cells: molten carbonate fuel cell and solid oxide fuel cell.

P. Kurzweil

2009-01-01T23:59:59.000Z

146

Regenerable Mixed Copper-Iron-Inert Support Oxygen Carriers  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Mixed Copper-Iron-Inert Support Oxygen Carriers Mixed Copper-Iron-Inert Support Oxygen Carriers for Solid Fuel Chemical Looping Combustion Process Contact NETL Technology Transfer Group techtransfer@netl.doe.gov December 2012 This patent-pending technology, "Regenerable Mixed Copper-Iron-Inert Support Oxygen Carriers for Solid Fuel Chemical Looping Combustion Process," provides a metal-oxide oxygen carrier for application in fuel combustion processes that use oxygen. This technology is available for licensing and/or further collaborative research with the U.S. Department of Energy's National Energy Technology Laboratory. Overview Patent Details U.S. Non-Provisional Patent Application No. 13/159,553; titled "Regenerable Mixed Copper-Iron-Inert Support Oxygen Carriers for Solid

147

Pool octanes via oxygenates  

SciTech Connect (OSTI)

Increasingly stringent antipollution regulations placed on automobile exhaust gases with consequent reduction or complete lead ban from motor gasoline result in octane shortage at many manufacturing sites. Attractive solutions to this problem, especially in conjunction with abundant methanol supplies, are the hydration and etherification of olefins contained in light product streams from cracking unit or produced by field gas dehydrogenation. A comparison is made between oxygenates octane-volume pool contributions and established refinery technologies. Process reviews for bulk manufacture of fuel-grade isopropanol (IPA), secondary butanol (SBA), tertiary butanol (TBA), methyl tertiary butyl ether (MTBE) and tertiary amyl methyl ether (TAME) are presented together with the characteristic investment and operating data. The implantation of these processes into a typical FCCU refinery complex with the resulting octane-pool improvement possibilities is descried.

Prezelj, M.

1987-09-01T23:59:59.000Z

148

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

Conventional wisdom says adding oxygen to a combustion system enhances product throughput, system efficiency, and, unless special care is taken, increases NOx emissions. This increase in NOx emissions is typically due to elevated flame temperatures associated with oxygen use leading to added thermal NOx formation. Innovative low flame temperature oxy-fuel burner designs have been developed and commercialized to minimize both thermal and fuel NOx formation for gas and oil fired industrial furnaces. To be effective these systems require close to 100% oxy-fuel combustion and the cost of oxygen is paid for by fuel savings and other benefits. For applications to coal-fired utility boilers at the current cost of oxygen, however, it is not economically feasible to use 100% oxygen for NOx control. In spite of this conventional wisdom, Praxair and its team members, in partnership with the US Department of Energy National Energy Technology Laboratory, have developed a novel way to use oxygen to reduce NOx emissions without resorting to complete oxy-fuel conversion. In this concept oxygen is added to the combustion process to enhance operation of a low NOx combustion system. Only a small fraction of combustion air is replaced with oxygen in the process. By selectively adding oxygen to a low NOx combustion system it is possible to reduce NOx emissions from nitrogen-containing fuels, including pulverized coal, while improving combustion characteristics such as unburned carbon. A combination of experimental work and modeling was used to define how well oxygen enhanced combustion could reduce NOx emissions. The results of this work suggest that small amounts of oxygen replacement can reduce the NOx emissions as compared to the air-alone system. NOx emissions significantly below 0.15 lbs/MMBtu were measured. Oxygen addition was also shown to reduce carbon in ash. Comparison of the costs of using oxygen for NOx control against competing technologies, such as SCR, show that this concept offers substantial savings over SCR and is an economically attractive alternative to purchasing NOx credits or installing other conventional technologies. In conjunction with the development of oxygen based low NOx technology, Praxair also worked on developing the economically enhancing oxygen transport membrane (OTM) technology which is ideally suited for integration with combustion systems to achieve further significant cost reductions and efficiency improvements. This OTM oxygen production technology is based on ceramic mixed conductor membranes that operate at high temperatures and can be operated in a pressure driven mode to separate oxygen with infinite selectivity and high flux. An OTM material was selected and characterized. OTM elements were successfully fabricated. A single tube OTM reactor was designed and assembled. Testing of dense OTM elements was conducted with promising oxygen flux results of 100% of target flux. However, based on current natural gas prices and stand-alone air separation processes, ceramic membranes do not offer an economic advantage for this application. Under a different DOE-NETL Cooperative Agreement, Praxair is continuing to develop oxygen transport membranes for the Advanced Boiler where the economics appear more attractive.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2004-04-01T23:59:59.000Z

149

Symposium on bioelectrochemistry of microorganisms. IV. Biochemical fuel cells.  

Science Journals Connector (OSTI)

...photosynthesis of algae. A possible ad...a few of the bio-fuel cells will be considered...hydrogen- oxygen fuel cell. Pt electrodes...coated with marine algae developed more cathodic...Similarly, the algae yield oxygen which...with conventional fuel cells or solar cells...

K Lewis

1966-03-01T23:59:59.000Z

150

Cerium Oxide Promoted Iron-based Oxygen Carrier for Chemical Looping Combustion  

Science Journals Connector (OSTI)

Cerium Oxide Promoted Iron-based Oxygen Carrier for Chemical Looping Combustion ... It entails the use of an oxygen carrier (OC), usually a metal oxide, to provide oxygen for combusting fuels in a fuel reactor (FR) and then the reoxidization of the OC in a separate air reactor (AR). ... Preprints of Symposia - American Chemical Society, Division of Fuel Chemistry (2004), 49 (2), 815-816 CODEN: PSADFZ; ISSN:1521-4648. ...

Fang Liu; Liangyong Chen; James K. Neathery; Kozo Saito; Kunlei Liu

2014-10-01T23:59:59.000Z

151

Testing Oxygen Reduction Reaction Activity with the Rotating Disc Electrode Technique  

Broader source: Energy.gov [DOE]

Presentation slides from the Fuel Cell Technologies Office webinar, Testing Oxygen Reduction Reaction Activity with the Rotating Disc Electrode Technique, held March 12, 2013.

152

Webinar: Testing Oxygen Reduction Reaction Activity with the Rotating Disc Electrode Technique  

Broader source: Energy.gov [DOE]

Video recording of the Fuel Cell Technologies Office webinar, Testing Oxygen Reduction Reaction Activity with the Rotating Disc Electrode Technique, originally presented on March 12, 2013.

153

Sewage sludge ash as an alternative low-cost oxygen carrier for chemical looping combustion  

Science Journals Connector (OSTI)

In this paper, novel low-cost oxygen carriers containing Fe2O3 are evaluated for use in chemical looping combustion. Sewage sludge ashes and reference samples were...2...) fuel and a solid fuel (hard coal) were t...

Ewelina Ksepko

2014-06-01T23:59:59.000Z

154

High-Performance Electrocatalysts for Oxygen Reduction Derived from Polyaniline, Iron, and Cobalt  

Science Journals Connector (OSTI)

...especially in the fuel cell cathode...G. Popov B. N. , Development of high performance...A new fuel cell cathode catalyst...high-area carbon as an electrocatalyst for oxygen reduction...Laboratory-Directed Research and Development Program. Microscopy...

Gang Wu; Karren L. More; Christina M. Johnston; Piotr Zelenay

2011-04-22T23:59:59.000Z

155

Vehicle Technologies Office Merit Review 2014: Intake Air Oxygen Sensor  

Broader source: Energy.gov [DOE]

Presentation given by Robert Bosch at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about intake air oxygen sensors.

156

Definition: Fuel cell | Open Energy Information  

Open Energy Info (EERE)

Fuel cell Fuel cell Jump to: navigation, search Dictionary.png Fuel cell An electrochemical device that converts chemical energy directly into electricity. View on Wikipedia Wikipedia Definition A fuel cell is a device that converts the chemical energy from a fuel into electricity through a chemical reaction with oxygen or another oxidizing agent. Hydrogen is the most common fuel, but hydrocarbons such as natural gas and alcohols like methanol are sometimes used. Fuel cells are different from batteries in that they require a constant source of fuel and oxygen/air to sustain the chemical reaction; however, fuel cells can produce electricity continually for as long as these inputs are supplied. In 1838, German physicist Christian Friedrich Schönbein invented the first

157

Ambient pressure fuel cell system  

DOE Patents [OSTI]

An ambient pressure fuel cell system is provided with a fuel cell stack formed from a plurality of fuel cells having membrane/electrode assemblies (MEAs) that are hydrated with liquid water and bipolar plates with anode and cathode sides for distributing hydrogen fuel gas and water to a first side of each one of the MEAs and air with reactant oxygen gas to a second side of each one of the MEAs. A pump supplies liquid water to the fuel cells. A recirculating system may be used to return unused hydrogen fuel gas to the stack. A near-ambient pressure blower blows air through the fuel cell stack in excess of reaction stoichiometric amounts to react with the hydrogen fuel gas.

Wilson, Mahlon S. (Los Alamos, NM)

2000-01-01T23:59:59.000Z

158

Alternative Fuels Data Center: Biogas  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Biogas to someone by Biogas to someone by E-mail Share Alternative Fuels Data Center: Biogas on Facebook Tweet about Alternative Fuels Data Center: Biogas on Twitter Bookmark Alternative Fuels Data Center: Biogas on Google Bookmark Alternative Fuels Data Center: Biogas on Delicious Rank Alternative Fuels Data Center: Biogas on Digg Find More places to share Alternative Fuels Data Center: Biogas on AddThis.com... More in this section... Biobutanol Drop-In Biofuels Methanol P-Series Renewable Natural Gas xTL Fuels Renewable Natural Gas (Biogas) Biogas-also known as biomethane, swamp gas, landfill gas, or digester gas-is the gaseous product of anaerobic digestion (decomposition without oxygen) of organic matter. In addition to providing electricity and heat, biogas is useful as a vehicle fuel. When processed to purity standards,

159

Oxygen Limitation within a Bacterial Aggregate  

Science Journals Connector (OSTI)

...standard deviation of the average of cells exposed to 2...and Doring G. 2002. Effects of reduced mucus oxygen...Lewandowski Z. 1994. Effects of biofilm structures...Dietrich LE , Okegbe C, Price-Whelan A, Sakhtah...capability. Energy Fuels 20 :1565-1571. doi...

Aimee K. Wessel; Talha A. Arshad; Mignon Fitzpatrick; Jodi L. Connell; Roger T. Bonnecaze; Jason B. Shear; Marvin Whiteley

2014-04-01T23:59:59.000Z

160

Fuel Cells: Just a Dream - or Future Reality | Department of...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Cells: Just a Dream - or Future Reality Fuel Cells: Just a Dream - or Future Reality Presentation about tuning activity and stability of precious metal catalysts for the oxygen...

Note: This page contains sample records for the topic "newable fuels oxygenates" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Fuel Cells (Project FC-041): DOE Hydrogen Program 2011 Annual...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

approach for oxygen reduction reaction (ORR) catalysis is advantageous for both DMFC and hydrogen fuel cells. Question 1: Relevance to overall U.S. Department of Energy objectives...

162

Artificial oxygen transport protein  

DOE Patents [OSTI]

This invention provides heme-containing peptides capable of binding molecular oxygen at room temperature. These compounds may be useful in the absorption of molecular oxygen from molecular oxygen-containing atmospheres. Also included in the invention are methods for treating an oxygen transport deficiency in a mammal.

Dutton, P. Leslie

2014-09-30T23:59:59.000Z

163

Laser Shearographic Testing of Foam Insulation on Cryogenic Fuel Tanks  

Science Journals Connector (OSTI)

The Centaur is a high-energy rocket used as a second stage to the Atlas launch vehicle. The Centaur is cryogenically fueled, using liquid hydrogen and liquid oxygen, and requires insulation to prevent fuel boi...

Douglas D. Burleigh; James E. Engel…

1993-01-01T23:59:59.000Z

164

Controlled air injection for a fuel cell system  

DOE Patents [OSTI]

A method and apparatus for injecting oxygen into a fuel cell reformate stream to reduce the level of carbon monoxide while preserving the level of hydrogen in a fuel cell system.

Fronk, Matthew H. (Honeove Falls, NY)

2002-01-01T23:59:59.000Z

165

Fuel cell power supply with oxidant and fuel gas switching  

DOE Patents [OSTI]

This invention relates to a fuel cell vehicular power plant. Fuel for the fuel stack is supplied by a hydrocarbon (methanol) catalytic cracking reactor and CO shift reactor. A water electrolysis subsystem is associated with the stack. During low power operation part of the fuel cell power is used to electrolyze water with hydrogen and oxygen electrolysis products being stored in pressure vessels. During peak power intervals, viz, during acceleration or start-up, pure oxygen and pure hydrogen from the pressure vessel are supplied as the reaction gases to the cathodes and anodes in place of air and methanol reformate. This allows the fuel cell stack to be sized for normal low power/air operation but with a peak power capacity several times greater than that for normal operation.

McElroy, James F. (Hamilton, MA); Chludzinski, Paul J. (Swampscott, MA); Dantowitz, Philip (Peabody, MA)

1987-01-01T23:59:59.000Z

166

Fuel cell power supply with oxidant and fuel gas switching  

DOE Patents [OSTI]

This invention relates to a fuel cell vehicular power plant. Fuel for the fuel stack is supplied by a hydrocarbon (methanol) catalytic cracking reactor and CO shift reactor. A water electrolysis subsystem is associated with the stack. During low power operation part of the fuel cell power is used to electrolyze water with hydrogen and oxygen electrolysis products being stored in pressure vessels. During peak power intervals, viz, during acceleration or start-up, pure oxygen and pure hydrogen from the pressure vessel are supplied as the reaction gases to the cathodes and anodes in place of air and methanol reformate. This allows the fuel cell stack to be sized for normal low power/air operation but with a peak power capacity several times greater than that for normal operation. 2 figs.

McElroy, J.F.; Chludzinski, P.J.; Dantowitz, P.

1987-04-14T23:59:59.000Z

167

Calling All Fuel Cells | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Calling All Fuel Cells Calling All Fuel Cells Calling All Fuel Cells December 7, 2012 - 4:31pm Addthis Altergy had more than 60 fuel cells in the immediate Hurricane Sandy disaster area that acted as backup power for cell phone towers. | Photo courtesy of Altergy. Altergy had more than 60 fuel cells in the immediate Hurricane Sandy disaster area that acted as backup power for cell phone towers. | Photo courtesy of Altergy. Sunita Satyapal Program Manager, Hydrogen & Fuel Cell Technology Program What is a fuel cell? A fuel cell is a device that uses a fuel and oxygen to create electricity by an electrochemical process. A fuel cell can provide energy for systems as large as a utility power station and as small as a laptop computer. During Hurricane Sandy, fuel cells were instrumental in providing backup

168

Calling All Fuel Cells | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Calling All Fuel Cells Calling All Fuel Cells Calling All Fuel Cells December 7, 2012 - 4:31pm Addthis Altergy had more than 60 fuel cells in the immediate Hurricane Sandy disaster area that acted as backup power for cell phone towers. | Photo courtesy of Altergy. Altergy had more than 60 fuel cells in the immediate Hurricane Sandy disaster area that acted as backup power for cell phone towers. | Photo courtesy of Altergy. Sunita Satyapal Program Manager, Hydrogen & Fuel Cell Technology Program What is a fuel cell? A fuel cell is a device that uses a fuel and oxygen to create electricity by an electrochemical process. A fuel cell can provide energy for systems as large as a utility power station and as small as a laptop computer. During Hurricane Sandy, fuel cells were instrumental in providing backup

169

Generating Potable Water from Fuel Cell Technology Juan E. Tibaquir  

E-Print Network [OSTI]

with hydrogen economy scenario. 4. Research Approach and Results Survey of fuel cell water ASU lab fuel cell Capacity (kW) 5 ­ 150 5 ­ 250 5 50 ­ 1100 100 ­ 2000 100 ­ 250 PEM Fuel cell Oxygen (From air) Hydrogen Implications of Using water from Fuel Cells in a Hydrogen Economy · Hydrogen as an energy and water carrier

Keller, Arturo A.

170

Method for providing oxygen ion vacancies in lanthanide oxides  

DOE Patents [OSTI]

A method for desulfurization of fuel gases resulting from the incomplete combustion of sulfur containing hydrocarbons whereby the gases are treated with lanthanide oxides containing large numbers of oxygen-ion vacancies providing ionic porosity which enhances the ability of the lanthanide oxides to react more rapidly and completely with the sulfur in the fuel gases whereby the sulfur in such gases is reduced to low levels suitable for fuels for firing into boilers of power plants generating electricity with steam turbine driven generators, gas turbines, fuel cells and precursors for liquid fuels such as methanol and the like.

Kay, D. Alan R. (4305 Lakeshore Rd., Burlington, CA); Wilson, William G. (820 Harden Dr., Pittsburgh, PA 15229)

1989-12-05T23:59:59.000Z

171

Oxygen tolerance of an in silico-designed bioinspired hydrogen-evolving catalyst in water  

Science Journals Connector (OSTI)

...highly exothermic. The overall free-energy reduction is 113.9 kcal/mol for the combined O 2...overpotential for oxygen reduction at a fuel-cell cathode . J Phys Chem B 108 : 17886...Overpotential for Oxygen Reduction at a Fuel-Cell cathode. J. Phys Chem B 108...

Patrick H.-L. Sit; Roberto Car; Morrel H. Cohen; Annabella Selloni

2013-01-01T23:59:59.000Z

172

Alternative Fuels Data Center: Alternative Fuel and Fueling Infrastructure  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Fuel and Fuel and Fueling Infrastructure Incentives to someone by E-mail Share Alternative Fuels Data Center: Alternative Fuel and Fueling Infrastructure Incentives on Facebook Tweet about Alternative Fuels Data Center: Alternative Fuel and Fueling Infrastructure Incentives on Twitter Bookmark Alternative Fuels Data Center: Alternative Fuel and Fueling Infrastructure Incentives on Google Bookmark Alternative Fuels Data Center: Alternative Fuel and Fueling Infrastructure Incentives on Delicious Rank Alternative Fuels Data Center: Alternative Fuel and Fueling Infrastructure Incentives on Digg Find More places to share Alternative Fuels Data Center: Alternative Fuel and Fueling Infrastructure Incentives on AddThis.com... More in this section... Federal State Advanced Search

173

Alternative Fuels Data Center: Alternative Fuel Vehicle (AFV) and Fueling  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Fuel Fuel Vehicle (AFV) and Fueling Infrastructure Loans to someone by E-mail Share Alternative Fuels Data Center: Alternative Fuel Vehicle (AFV) and Fueling Infrastructure Loans on Facebook Tweet about Alternative Fuels Data Center: Alternative Fuel Vehicle (AFV) and Fueling Infrastructure Loans on Twitter Bookmark Alternative Fuels Data Center: Alternative Fuel Vehicle (AFV) and Fueling Infrastructure Loans on Google Bookmark Alternative Fuels Data Center: Alternative Fuel Vehicle (AFV) and Fueling Infrastructure Loans on Delicious Rank Alternative Fuels Data Center: Alternative Fuel Vehicle (AFV) and Fueling Infrastructure Loans on Digg Find More places to share Alternative Fuels Data Center: Alternative Fuel Vehicle (AFV) and Fueling Infrastructure Loans on AddThis.com...

174

Covalency in Metal-Oxygen Multiple Bonds Evaluated Using Oxygen...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Covalency in Metal-Oxygen Multiple Bonds Evaluated Using Oxygen K-edge Spectroscopy and Electronic Structure Theory . Covalency in Metal-Oxygen Multiple Bonds Evaluated Using...

175

Thermochemical Modeling of the Uranium-Cerium-Oxygen System  

SciTech Connect (OSTI)

The objective of the Fuel Cycle R&D Program, Advanced Fuels campaign is to provide the research and development necessary to develop low loss, high quality nuclear fuels for ultra-high burnup reactor operation. Primary work in this area will be focused on the ceramic and metallic fuel systems. The goal of the current work is to enhance the understanding of ceramic nuclear fuel thermochemistry to support fuel research and development efforts. The thermochemical behavior of oxide nuclear fuel under irradiation is dependent on the oxygen to metal ratio (O:M). In fluorite-structured fuel, the actinide metal cation is bonded with {approx}2 oxygen atoms on a crystal lattice and as the metal atoms fission, fission fragments and free oxygen are created. The resulting fission fragments will contain some oxide forming elements, however these are insufficient to bind to all the liberated oxygen and therefore, there is an average increase in O:M with fuel burnup. Some of the fission products also form species that will migrate to and react with the cladding surface in a phenomenon known as Fuel Clad Chemical Interaction (FCCI). Cladding corrosion is life-limiting so it is desirable to understand influencing factors, such as oxide thermochemistry, which can be used to guide the design and fabrication of higher burn up fuel. A phased oxide fuel thermochemical model development effort is underway within the Advanced Fuels Campaign. First models of binary oxide systems are developed. For nuclear fuel system this means U-O and transuranic systems such as Pu-O, Np-O and Am-O. Next, the binary systems will be combined to form pseudobinary systems such as U-Pu-O, etc. The model development effort requires the use of data to allow optimization based on known thermochemical parameters as a function of composition and temperature. Available data is mined from the literature and supplemented by experimental work as needed. Due to the difficulty of performing fuel fabrication development with actinide materials, fundamental studies with uranium are performed using surrogate materials as stand-ins for transuranic elements. In most cases, cerium can be used as a suitable substitute for plutonium when performing O:M and sintering kinetics studies because of identical valence states. Differences exist between the magnitude of reported thermodynamic data of (U,Pu)O{sub x} and (U,Ce)O{sub x}, however the change in oxygen potential versus O:M follows the same trend for both systems. Cerium is also a major fission product element, and thus understanding its behavior in fuel is an important issue as well.

Voit, Stewart L [ORNL; Besmann, Theodore M [ORNL

2010-10-01T23:59:59.000Z

176

Oxygen enriched fireflooding  

SciTech Connect (OSTI)

Both pure oxygen and enriched air have been considered in fireflooding for enhanced oil recovery. Laboratory and field testing have conclusively shown that oxygen is practical and cost effective for this application. For reservoirs that require a large volume of high pressure gas, oxygen is cheaper than air simply based on compression costs. Additional process benefits with oxygen include: Faster Oil Production; Lower Injection Pressure; Greater Well Spacing; Increased Carbon Dioxide Partial Pressure; Lower Gas-to-Oil Ratios; and Purer Produced Gas. These features provide a compelling case for oxygen, once the safety and materials compatibility issues are properly addressed.

Shahani, G.H.; Gunardson, H.H. [Air Products and Chemicals, Allentown, PA (United States)

1995-02-01T23:59:59.000Z

177

Alternative Fuels Data Center: Alternative Fuel Use and Alternative Fuel  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Fuel Use Fuel Use and Alternative Fuel Vehicle (AFV) Acquisition Requirements to someone by E-mail Share Alternative Fuels Data Center: Alternative Fuel Use and Alternative Fuel Vehicle (AFV) Acquisition Requirements on Facebook Tweet about Alternative Fuels Data Center: Alternative Fuel Use and Alternative Fuel Vehicle (AFV) Acquisition Requirements on Twitter Bookmark Alternative Fuels Data Center: Alternative Fuel Use and Alternative Fuel Vehicle (AFV) Acquisition Requirements on Google Bookmark Alternative Fuels Data Center: Alternative Fuel Use and Alternative Fuel Vehicle (AFV) Acquisition Requirements on Delicious Rank Alternative Fuels Data Center: Alternative Fuel Use and Alternative Fuel Vehicle (AFV) Acquisition Requirements on Digg Find More places to share Alternative Fuels Data Center: Alternative

178

Alternative Fuels Data Center: Alternative Fuel Vehicle (AFV) and Fueling  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Fuel Fuel Vehicle (AFV) and Fueling Infrastructure Grants and Loans to someone by E-mail Share Alternative Fuels Data Center: Alternative Fuel Vehicle (AFV) and Fueling Infrastructure Grants and Loans on Facebook Tweet about Alternative Fuels Data Center: Alternative Fuel Vehicle (AFV) and Fueling Infrastructure Grants and Loans on Twitter Bookmark Alternative Fuels Data Center: Alternative Fuel Vehicle (AFV) and Fueling Infrastructure Grants and Loans on Google Bookmark Alternative Fuels Data Center: Alternative Fuel Vehicle (AFV) and Fueling Infrastructure Grants and Loans on Delicious Rank Alternative Fuels Data Center: Alternative Fuel Vehicle (AFV) and Fueling Infrastructure Grants and Loans on Digg Find More places to share Alternative Fuels Data Center: Alternative

179

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

hydrogen Go hydrogen Go Hydrogen-stations Hydrogen Fueling Station Locations by State Hydrogen-stations View Map Graph Hydrogen_li_by_state Hydrogen Incentives and Laws, by State Hydrogen_li_by_state View Map Graph Generated_thumb20130810-31804-1c5lrlb Commuter Responses to the 2008 Oil Price Spike Generated_thumb20130810-31804-1c5lrlb Ways that workers changed their commutes in response to high gasoline prices Last update May 2012 View Graph Graph Download Data Generated_thumb20130810-31804-f64ffe U.S. Consumption of Ethanol and MTBE Oxygenates Generated_thumb20130810-31804-f64ffe Trend of ethanol and MTBE consumption as oxygenates and gasohol blends from 1992-2009 Last update February 2012 View Graph Graph Download Data Generated_thumb20130810-31804-14nv4j5 AFV Acquisitions by Regulated Fleets (by Fuel Type)

180

Fuel cell electric power production  

DOE Patents [OSTI]

A process for generating electricity from a fuel cell includes generating a hydrogen-rich gas as the fuel for the fuel cell by treating a hydrocarbon feed, which may be a normally liquid feed, in an autothermal reformer utilizing a first monolithic catalyst zone having palladium and platinum catalytic components therein and a second, platinum group metal steam reforming catalyst. Air is used as the oxidant in the hydrocarbon reforming zone and a low oxygen to carbon ratio is maintained to control the amount of dilution of the hydrogen-rich gas with nitrogen of the air without sustaining an insupportable amount of carbon deposition on the catalyst. Anode vent gas may be utilized as the fuel to preheat the inlet stream to the reformer. The fuel cell and the reformer are preferably operated at elevated pressures, up to about a pressure of 150 psia for the fuel cell.

Hwang, Herng-Shinn (Livingston, NJ); Heck, Ronald M. (Frenchtown, NJ); Yarrington, Robert M. (Westfield, NJ)

1985-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "newable fuels oxygenates" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

PUBLISHED ONLINE: 19 AUGUST 2012 | DOI: 10.1038/NMAT3393 Probing oxygen vacancy concentration and  

E-Print Network [OSTI]

concentration and homogeneity in solid-oxide fuel-cell cathode materials on the subunit-cell level Young-Min Kim * Oxygen vacancy distributions and dynamics directly control the operation of solid-oxide fuel cells solid-oxide fuel cells, gas sensors and electrochemical pumps that operate by directing and control

Pennycook, Steve

182

Instructions for use Role of Cerium Oxide in the Enhancement of Activity for the Oxygen  

E-Print Network [OSTI]

activity for various fuel cell reactions, such as the hydrogen oxidation reaction (HOR),4 oxygen reduction. Recently, CeOx has been also utilized as a cocatalyst with Pt catalyst for ORR in PEM fuel cells.17 at the Pt oxide formation potential. INTRODUCTION Fuel cells, especially polymer electrolyte membrane (PEM

Tsunogai, Urumu

183

Fuel pin  

DOE Patents [OSTI]

A fuel pin for a liquid metal nuclear reactor is provided. The fuel pin includes a generally cylindrical cladding member with metallic fuel material disposed therein. At least a portion of the fuel material extends radially outwardly to the inner diameter of the cladding member to promote efficient transfer of heat to the reactor coolant system. The fuel material defines at least one void space therein to facilitate swelling of the fuel material during fission.

Christiansen, D.W.; Karnesky, R.A.; Leggett, R.D.; Baker, R.B.

1987-11-24T23:59:59.000Z

184

Alternative Fuels Data Center: Alternative Fuel Vehicle (AFV) and Fueling  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

and Fueling Infrastructure Funding and Technical Assistance and Fueling Infrastructure Funding and Technical Assistance to someone by E-mail Share Alternative Fuels Data Center: Alternative Fuel Vehicle (AFV) and Fueling Infrastructure Funding and Technical Assistance on Facebook Tweet about Alternative Fuels Data Center: Alternative Fuel Vehicle (AFV) and Fueling Infrastructure Funding and Technical Assistance on Twitter Bookmark Alternative Fuels Data Center: Alternative Fuel Vehicle (AFV) and Fueling Infrastructure Funding and Technical Assistance on Google Bookmark Alternative Fuels Data Center: Alternative Fuel Vehicle (AFV) and Fueling Infrastructure Funding and Technical Assistance on Delicious Rank Alternative Fuels Data Center: Alternative Fuel Vehicle (AFV) and Fueling Infrastructure Funding and Technical Assistance on Digg

185

Fuel System and Fuel Measurement  

Science Journals Connector (OSTI)

Fuel management provides optimal solutions to reduce fuel consumption. Merchant vessels, such as container ships, drive at a reduced speed to save fuel since the reduction of the speed from...?1 lowers consumption

Michael Palocz-Andresen

2013-01-01T23:59:59.000Z

186

AIR POLLUTION: Diesel Fuel Culprits  

Science Journals Connector (OSTI)

AIR POLLUTION: Diesel Fuel Culprits ... Low-molecular-weight components aren't necessarily the true culprits of diesel fuel pollution, although they do contribute to it, according to Hertha Skala, assistant director of research, and her coworkers F. G. Padrta and P. C. Samson at Universal Oil Products. ... At the first national symposium on heterogeneous catalysis for control of air pollution, sponsored by Philadelphia's Franklin Institute, Mrs. Skala identified five different classes of oxygenated hydrocarbons found over the full molecular-weight range of diesel fuel components. ...

1968-12-02T23:59:59.000Z

187

Hydrogen & Fuel Cells - Fuel Cell - Polymer Electrolyte  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Polymer Electrolyte Fuel Cell Research Polymer Electrolyte Fuel Cell Research Xiaoping Wang measures the stability of a platinum cathode electrocatalyst. Xiaoping Wang measures the stability of a platinum cathode electrocatalyst. One of the main barriers to the commercialization of polymer electrolyte fuel cell (PEFC) systems, especially for automotive use, is the high cost of the platinum electrocatalysts. Aside from the cost of the precious metal, concern has also been raised over the adequacy of the world supply of platinum, if fuel cell vehicles were to make a significant penetration into the global automotive fleet. At Argonne, chemists are working toward the development of low-cost nonplatinum electrocatalysts for the oxygen reduction reaction--durable materials that would be stable in the fuel

188

Alternative Fuels and Chemicals From Synthesis Gas  

SciTech Connect (OSTI)

The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

none

1998-07-01T23:59:59.000Z

189

Alternative fuels and chemicals from synthesis gas  

SciTech Connect (OSTI)

The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

Unknown

1998-08-01T23:59:59.000Z

190

ALTERNATIVE FUELS AND CHEMICALS FROM SYNTHESIS GAS  

SciTech Connect (OSTI)

The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

Unknown

1999-01-01T23:59:59.000Z

191

ALTERNATIVE FUELS AND CHEMICALS FROM SYNTHESIS GAS  

SciTech Connect (OSTI)

The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

Unknown

1998-01-01T23:59:59.000Z

192

ALTERNATIVE FUELS AND CHEMICALS FROM SYNTHESIS GAS  

SciTech Connect (OSTI)

The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

Unknown

2000-10-01T23:59:59.000Z

193

Exergy analysis of PEM fuel cells for marine applications  

Science Journals Connector (OSTI)

Fuel cells have a promising potential use in stationary and mobile power generation systems, as well as in automotive, aerospace or marine industries. At present, the main field of marine applications of fuel cells is submarines. Hydrogen/oxygen polymer electrolyte membrane (PEM) fuel cells are commonly used in this field. Storage of oxygen in liquid form is the optimal solution. Hydrogen can be stored in carbon-nanofibres or metallic hydrides, for example, or in liquid fuels, as alcohols, with further generation of the hydrogen required on-board. The objective of this study is to perform an exergetic analysis of two possibilities of using PEM fuel cells on surface ships and submarines: hydrogen/oxygen PEM fuel cells fed with hydrogen generated by reforming of methanol, and Direct Methanol Fuel Cells directly fed with liquid methanol. To do this, exergy losses and exergetic efficiencies are calculated for both configurations at selected optimal operation points.

T.J. Leo; J.A. Durango; E. Navarro

2010-01-01T23:59:59.000Z

194

Reformulated diesel fuel and method  

DOE Patents [OSTI]

A method for mathematically identifying at least one diesel fuel suitable for combustion in an automotive diesel engine with significantly reduced emissions and producible from known petroleum blendstocks using known refining processes, including the use of cetane additives (ignition improvers) and oxygenated compounds.

McAdams, Hiramie T [Carrollton, IL; Crawford, Robert W [Tucson, AZ; Hadder, Gerald R [Oak Ridge, TN; McNutt, Barry D [Arlington, VA

2006-08-22T23:59:59.000Z

195

Biodiesel Fuel Property Effects on Particulate Matter Reactivity  

SciTech Connect (OSTI)

Controlling diesel particulate emissions to meet the 2007 U.S. standard requires the use of a diesel particulate filter (DPF). The reactivity of soot, or the carbon fraction of particulate matter, in the DPF and the kinetics of soot oxidation are important in achieving better control of aftertreatment devices. Studies showed that biodiesel in the fuel can increase soot reactivity. This study therefore investigated which biodiesel fuel properties impact reactivity. Three fuel properties of interest included fuel oxygen content and functionality, fuel aromatic content, and the presence of alkali metals. To determine fuel effects on soot reactivity, the performance of a catalyzed DPF was measured with different test fuels through engine testing and thermo-gravimetric analysis. Results showed no dependence on the aromatic content or the presence of alkali metals in the fuel. The presence and form of fuel oxygen was the dominant contributor to faster DPF regeneration times and soot reactivity.

Williams, A.; Black, S.; McCormick, R. L.

2010-06-01T23:59:59.000Z

196

Alternative Fuels Data Center: Alternative Fuel and Special Fuel  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Fuel and Fuel and Special Fuel Definitions to someone by E-mail Share Alternative Fuels Data Center: Alternative Fuel and Special Fuel Definitions on Facebook Tweet about Alternative Fuels Data Center: Alternative Fuel and Special Fuel Definitions on Twitter Bookmark Alternative Fuels Data Center: Alternative Fuel and Special Fuel Definitions on Google Bookmark Alternative Fuels Data Center: Alternative Fuel and Special Fuel Definitions on Delicious Rank Alternative Fuels Data Center: Alternative Fuel and Special Fuel Definitions on Digg Find More places to share Alternative Fuels Data Center: Alternative Fuel and Special Fuel Definitions on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Alternative Fuel and Special Fuel Definitions

197

Alternative Fuels Data Center: Alternative Fuel Motor Carrier Fuel Tax  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Fuel Motor Fuel Motor Carrier Fuel Tax to someone by E-mail Share Alternative Fuels Data Center: Alternative Fuel Motor Carrier Fuel Tax on Facebook Tweet about Alternative Fuels Data Center: Alternative Fuel Motor Carrier Fuel Tax on Twitter Bookmark Alternative Fuels Data Center: Alternative Fuel Motor Carrier Fuel Tax on Google Bookmark Alternative Fuels Data Center: Alternative Fuel Motor Carrier Fuel Tax on Delicious Rank Alternative Fuels Data Center: Alternative Fuel Motor Carrier Fuel Tax on Digg Find More places to share Alternative Fuels Data Center: Alternative Fuel Motor Carrier Fuel Tax on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Alternative Fuel Motor Carrier Fuel Tax Effective January 1, 2014, a person who operates a commercial motor vehicle

198

Microstructured Hydrogen Fuel Cells  

Science Journals Connector (OSTI)

Micro fuel cells ; Polymer electrolyte membrane fuel cells ; Proton exchange membrane fuel cells ...

Luc G. Frechette

2014-05-01T23:59:59.000Z

199

Alternative Fuels Data Center: Alternative Fuel Definition  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Fuel Fuel Definition to someone by E-mail Share Alternative Fuels Data Center: Alternative Fuel Definition on Facebook Tweet about Alternative Fuels Data Center: Alternative Fuel Definition on Twitter Bookmark Alternative Fuels Data Center: Alternative Fuel Definition on Google Bookmark Alternative Fuels Data Center: Alternative Fuel Definition on Delicious Rank Alternative Fuels Data Center: Alternative Fuel Definition on Digg Find More places to share Alternative Fuels Data Center: Alternative Fuel Definition on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Alternative Fuel Definition The definition of an alternative fuel includes natural gas, liquefied petroleum gas, electricity, hydrogen, fuel mixtures containing not less

200

Alternative Fuels Data Center: Ethanol Fueling Stations  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Fueling Fueling Stations to someone by E-mail Share Alternative Fuels Data Center: Ethanol Fueling Stations on Facebook Tweet about Alternative Fuels Data Center: Ethanol Fueling Stations on Twitter Bookmark Alternative Fuels Data Center: Ethanol Fueling Stations on Google Bookmark Alternative Fuels Data Center: Ethanol Fueling Stations on Delicious Rank Alternative Fuels Data Center: Ethanol Fueling Stations on Digg Find More places to share Alternative Fuels Data Center: Ethanol Fueling Stations on AddThis.com... More in this section... Ethanol Basics Benefits & Considerations Stations Locations Infrastructure Development Vehicles Laws & Incentives Ethanol Fueling Stations Photo of an ethanol fueling station. Thousands of ethanol fueling stations are available in the United States.

Note: This page contains sample records for the topic "newable fuels oxygenates" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Alternative Fuels Data Center: Alternative Fuel Promotion  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Alternative Fuel Alternative Fuel Promotion to someone by E-mail Share Alternative Fuels Data Center: Alternative Fuel Promotion on Facebook Tweet about Alternative Fuels Data Center: Alternative Fuel Promotion on Twitter Bookmark Alternative Fuels Data Center: Alternative Fuel Promotion on Google Bookmark Alternative Fuels Data Center: Alternative Fuel Promotion on Delicious Rank Alternative Fuels Data Center: Alternative Fuel Promotion on Digg Find More places to share Alternative Fuels Data Center: Alternative Fuel Promotion on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Alternative Fuel Promotion The Missouri Alternative Fuels Commission (Commission) promotes the continued production and use of alternative transportation fuels in

202

Alternative Fuels Data Center: Hydrogen Fueling Stations  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Fueling Fueling Stations to someone by E-mail Share Alternative Fuels Data Center: Hydrogen Fueling Stations on Facebook Tweet about Alternative Fuels Data Center: Hydrogen Fueling Stations on Twitter Bookmark Alternative Fuels Data Center: Hydrogen Fueling Stations on Google Bookmark Alternative Fuels Data Center: Hydrogen Fueling Stations on Delicious Rank Alternative Fuels Data Center: Hydrogen Fueling Stations on Digg Find More places to share Alternative Fuels Data Center: Hydrogen Fueling Stations on AddThis.com... More in this section... Hydrogen Basics Benefits & Considerations Stations Locations Infrastructure Development Vehicles Laws & Incentives Hydrogen Fueling Stations Photo of a hydrogen fueling station. A handful of hydrogen fueling stations are available in the United States

203

Alternative Fuels Data Center: Biodiesel Fueling Stations  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Fueling Fueling Stations to someone by E-mail Share Alternative Fuels Data Center: Biodiesel Fueling Stations on Facebook Tweet about Alternative Fuels Data Center: Biodiesel Fueling Stations on Twitter Bookmark Alternative Fuels Data Center: Biodiesel Fueling Stations on Google Bookmark Alternative Fuels Data Center: Biodiesel Fueling Stations on Delicious Rank Alternative Fuels Data Center: Biodiesel Fueling Stations on Digg Find More places to share Alternative Fuels Data Center: Biodiesel Fueling Stations on AddThis.com... More in this section... Biodiesel Basics Benefits & Considerations Stations Locations Infrastructure Development Vehicles Laws & Incentives Biodiesel Fueling Stations Photo of a biodiesel fueling station. Hundreds of biodiesel fueling stations are available in the United States.

204

Ethanol Fuel Basics | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Ethanol Fuel Basics Ethanol Fuel Basics Ethanol Fuel Basics July 30, 2013 - 12:00pm Addthis biomass in beekers Ethanol is a renewable fuel made from various plant materials, which collectively are called "biomass." Ethanol contains the same chemical compound (C2H5OH) found in alcoholic beverages. Studies have estimated that ethanol and other biofuels could replace 30% or more of U.S. gasoline demand by 2030. Nearly half of U.S. gasoline contains ethanol in a low-level blend to oxygenate the fuel and reduce air pollution. Ethanol is also increasingly available in E85, an alternative fuel that can be used in flexible fuel vehicles. Several steps are required to make ethanol available as a vehicle fuel. Biomass feedstocks are grown and transported to ethanol production

205

Fuel Cell Technologies Office: Glossary  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Glossary Glossary This glossary contains terms and acronyms related to hydrogen and fuel cell technologies. A B C D E F G H I J K L M N O P Q R S T U V W X Y Z - Acronyms A AC Generator (or Alternator) An electric device that produces an electric current that reverses direction many times per second. Also called a synchronous generator. Adsorption The adhesion of the molecules of gases, dissolved substances, or liquids to the surface of the solids or liquids with which they are in contact. Air The mixture of oxygen, nitrogen, and other gases that, with varying amounts of water vapor, forms the atmosphere of the earth. Alkaline Fuel Cell (AFC) A type of hydrogen/oxygen fuel cell in which the electrolyte is concentrated potassium hydroxide (KOH) and the hydroxide ions (OH-) are transported from the cathode to the anode.

206

SYNTHESIS, CHARACTERIZATION AND PERFORMANCE TESTING OF PT- BASED ELECTROCATALYSTS FOR LOW TEMPERATURE PEM FUEL CELLS.  

E-Print Network [OSTI]

??The oxygen reduction reaction (ORR) activity on the cathode plays a significant role in deciding the overall performance of proton exchange membrane (PEM) fuel cells.… (more)

Gong, Yanming

2008-01-01T23:59:59.000Z

207

Modeling Low-Platinum-Loading Effects in Fuel-Cell Catalyst Layers  

E-Print Network [OSTI]

Energy, Office of Hydrogen, Fuel Cell, and Infrastructureof fuel cell reaction with respect to hydrogen referencefuel-cell conditions and CL structures, the ORR oxygen reaction order is around 0.8 (referenced to an imaginary hydrogen

Yoon, Wonseok

2013-01-01T23:59:59.000Z

208

Alternative Fuels Data Center: Alternative Fuel Vehicle (AFV) and Fueling  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Alternative Fuel Alternative Fuel Vehicle (AFV) and Fueling Infrastructure Loans to someone by E-mail Share Alternative Fuels Data Center: Alternative Fuel Vehicle (AFV) and Fueling Infrastructure Loans on Facebook Tweet about Alternative Fuels Data Center: Alternative Fuel Vehicle (AFV) and Fueling Infrastructure Loans on Twitter Bookmark Alternative Fuels Data Center: Alternative Fuel Vehicle (AFV) and Fueling Infrastructure Loans on Google Bookmark Alternative Fuels Data Center: Alternative Fuel Vehicle (AFV) and Fueling Infrastructure Loans on Delicious Rank Alternative Fuels Data Center: Alternative Fuel Vehicle (AFV) and Fueling Infrastructure Loans on Digg Find More places to share Alternative Fuels Data Center: Alternative Fuel Vehicle (AFV) and Fueling Infrastructure Loans on AddThis.com...

209

Alternative Fuels Data Center: Alternative Fuel Vehicle (AFV) and Fueling  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Alternative Fuel Alternative Fuel Vehicle (AFV) and Fueling Infrastructure Grants to someone by E-mail Share Alternative Fuels Data Center: Alternative Fuel Vehicle (AFV) and Fueling Infrastructure Grants on Facebook Tweet about Alternative Fuels Data Center: Alternative Fuel Vehicle (AFV) and Fueling Infrastructure Grants on Twitter Bookmark Alternative Fuels Data Center: Alternative Fuel Vehicle (AFV) and Fueling Infrastructure Grants on Google Bookmark Alternative Fuels Data Center: Alternative Fuel Vehicle (AFV) and Fueling Infrastructure Grants on Delicious Rank Alternative Fuels Data Center: Alternative Fuel Vehicle (AFV) and Fueling Infrastructure Grants on Digg Find More places to share Alternative Fuels Data Center: Alternative Fuel Vehicle (AFV) and Fueling Infrastructure Grants on AddThis.com...

210

Alternative Fuels Data Center: Alternative Fuel Vehicle (AFV) and Fueling  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Alternative Fuel Alternative Fuel Vehicle (AFV) and Fueling Infrastructure Tax Credit to someone by E-mail Share Alternative Fuels Data Center: Alternative Fuel Vehicle (AFV) and Fueling Infrastructure Tax Credit on Facebook Tweet about Alternative Fuels Data Center: Alternative Fuel Vehicle (AFV) and Fueling Infrastructure Tax Credit on Twitter Bookmark Alternative Fuels Data Center: Alternative Fuel Vehicle (AFV) and Fueling Infrastructure Tax Credit on Google Bookmark Alternative Fuels Data Center: Alternative Fuel Vehicle (AFV) and Fueling Infrastructure Tax Credit on Delicious Rank Alternative Fuels Data Center: Alternative Fuel Vehicle (AFV) and Fueling Infrastructure Tax Credit on Digg Find More places to share Alternative Fuels Data Center: Alternative Fuel Vehicle (AFV) and Fueling Infrastructure Tax Credit on AddThis.com...

211

Alternative Fuels Data Center: Alternative Fuel and Alternative Fuel  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Alternative Fuel and Alternative Fuel and Alternative Fuel Vehicle (AFV) Fund to someone by E-mail Share Alternative Fuels Data Center: Alternative Fuel and Alternative Fuel Vehicle (AFV) Fund on Facebook Tweet about Alternative Fuels Data Center: Alternative Fuel and Alternative Fuel Vehicle (AFV) Fund on Twitter Bookmark Alternative Fuels Data Center: Alternative Fuel and Alternative Fuel Vehicle (AFV) Fund on Google Bookmark Alternative Fuels Data Center: Alternative Fuel and Alternative Fuel Vehicle (AFV) Fund on Delicious Rank Alternative Fuels Data Center: Alternative Fuel and Alternative Fuel Vehicle (AFV) Fund on Digg Find More places to share Alternative Fuels Data Center: Alternative Fuel and Alternative Fuel Vehicle (AFV) Fund on AddThis.com... More in this section...

212

Alternative Fuels Data Center: Alternative Fuel and Alternative Fuel  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Fuel and Fuel and Alternative Fuel Vehicle (AFV) Tax Exemption to someone by E-mail Share Alternative Fuels Data Center: Alternative Fuel and Alternative Fuel Vehicle (AFV) Tax Exemption on Facebook Tweet about Alternative Fuels Data Center: Alternative Fuel and Alternative Fuel Vehicle (AFV) Tax Exemption on Twitter Bookmark Alternative Fuels Data Center: Alternative Fuel and Alternative Fuel Vehicle (AFV) Tax Exemption on Google Bookmark Alternative Fuels Data Center: Alternative Fuel and Alternative Fuel Vehicle (AFV) Tax Exemption on Delicious Rank Alternative Fuels Data Center: Alternative Fuel and Alternative Fuel Vehicle (AFV) Tax Exemption on Digg Find More places to share Alternative Fuels Data Center: Alternative Fuel and Alternative Fuel Vehicle (AFV) Tax Exemption on AddThis.com...

213

Plants making oxygen  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Plants making oxygen Plants making oxygen Name: Doug Status: N/A Age: N/A Location: N/A Country: N/A Date: Around 1993 Question: How many plants are needed to make enough oxygen for one person for one hour? We are experimenting with Anacharis plants. Replies: The problem can be solved when broken down into smaller questions: 1. How much oxygen does a person need in an hour? 2. How much oxygen does a plant produce in an hour? 3. Based on the above, how many plants will provide the oxygen needs of the person for the hour? Here is the solution to the first question: A resting, healthy adult on an average, cool day breathes in about 53 liters of oxygen per hour. An average, resting, health adult breathes in about 500 mL of air per breath. This is called the normal tidal volume. Now, 150 mL of this air will go to non- functioning areas of the lung, called the "dead space." The average breath rate for this average person is 12 breaths per minute. So, the amount of air breathed in by the person which is available for use is 12 x (500 mL -150 mL) = 4,200 mL/minute. Multiply by 60 to get 252,000 mL/hour. That is, every hour, the person will breathe in 252 L of air. Now, on an average, cool, clear day, only 21% of that air is oxygen. So, 21% of 252 L is 53 L. So, in an hour, the person breathes in about 53 L of oxygen.

214

Algae for Oxygen  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Algae for Oxygen Algae for Oxygen Name: Pam Burkardt Status: N/A Age: N/A Location: N/A Country: N/A Date: N/A Question: Hi, I am Pam Burkardt, a seventh grader at Fox Chapel School. I have a question on algae. I read somewhere that someday people might take bath tubs full of algae onto spaceships to provide oxygen for the crew. How much oxygen does algae give off, is this really possible? Replies: I think that most of the oxygen in the atmosphere comes in fact from one-celled plants in the oceans, like algae. They are likely to produce a lot of oxygen per unit weight because they don't have non-photosynthesizing bark, roots, branches, etc., nor (I think) a major dormant period like temperate-zone plants. The cost of space travel at present is dominated by the expense of heaving weight up into Earth orbit (it costs very little extra to send it to the Moon, for example, or Mars). For missions of short duration the weight of the compressed oxygen you need to carry is less than the weight of algae, water and extra plumbing you'd need to carry if you relied on algae to produce your oxygen. The important use of green plants would be in very long duration space flight (years) or permanent inhabitation of worlds like the Moon, where you need an unlimited supply of oxygen. Now if you want to fantasize, Venus' atmosphere is almost all carbon dioxide. Suppose you dropped a whole lot of specially gene-tailored one-celled plants into the atmosphere (not the surface, it's too hot). Why then they might eat up all the carbon dioxide and produce a breathable atmosphere. The "greenhouse effect" would go away, and Venus would become a nice habitable if tropical world only 50 million miles away.

215

Dilute Oxygen Combustion Phase IV Final Report  

SciTech Connect (OSTI)

Novel furnace designs based on Dilute Oxygen Combustion (DOC) technology were developed under subcontract by Techint Technologies, Coraopolis, PA, to fully exploit the energy and environmental capabilities of DOC technology and to provide a competitive offering for new furnace construction opportunities. Capital cost, fuel, oxygen and utility costs, NOx emissions, oxide scaling performance, and maintenance requirements were compared for five DOC-based designs and three conventional air5-fired designs using a 10-year net present value calculation. A furnace direct completely with DOC burners offers low capital cost, low fuel rate, and minimal NOx emissions. However, these benefits do not offset the cost of oxygen and a full DOC-fired furnace is projected to cost $1.30 per ton more to operate than a conventional air-fired furnace. The incremental cost of the improved NOx performance is roughly $6/lb NOx, compared with an estimated $3/lb. NOx for equ8pping a conventional furnace with selective catalytic reduction (SCCR) technology. A furnace fired with DOC burners in the heating zone and ambient temperature (cold) air-fired burners in the soak zone offers low capital cost with less oxygen consumption. However, the improvement in fuel rate is not as great as the full DOC-fired design, and the DOC-cold soak design is also projected to cost $1.30 per ton more to operate than a conventional air-fired furnace. The NOx improvement with the DOC-cold soak design is also not as great as the full DOC fired design, and the incremental cost of the improved NOx performance is nearly $9/lb NOx. These results indicate that a DOC-based furnace design will not be generally competitive with conventional technology for new furnace construction under current market conditions. Fuel prices of $7/MMBtu or oxygen prices of $23/ton are needed to make the DOC furnace economics favorable. Niche applications may exist, particularly where access to capital is limited or floor space limitations are critical. DOC technology will continue to have a highly competitive role in retrofit applications requiring increases in furnace productivity.

Riley, M.F.

2003-04-30T23:59:59.000Z

216

Alternative Fuels Data Center: Alternative Fuel Vehicle (AFV) and Fueling  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Fueling Infrastructure Grants to someone by E-mail Fueling Infrastructure Grants to someone by E-mail Share Alternative Fuels Data Center: Alternative Fuel Vehicle (AFV) and Fueling Infrastructure Grants on Facebook Tweet about Alternative Fuels Data Center: Alternative Fuel Vehicle (AFV) and Fueling Infrastructure Grants on Twitter Bookmark Alternative Fuels Data Center: Alternative Fuel Vehicle (AFV) and Fueling Infrastructure Grants on Google Bookmark Alternative Fuels Data Center: Alternative Fuel Vehicle (AFV) and Fueling Infrastructure Grants on Delicious Rank Alternative Fuels Data Center: Alternative Fuel Vehicle (AFV) and Fueling Infrastructure Grants on Digg Find More places to share Alternative Fuels Data Center: Alternative Fuel Vehicle (AFV) and Fueling Infrastructure Grants on AddThis.com...

217

OXYGEN TRANSPORT CERAMIC MEMBRANES  

SciTech Connect (OSTI)

In the present quarter, oxygen transport perovskite ceramic membranes are evaluated for strength and fracture in oxygen gradient conditions. Oxygen gradients are created in tubular membranes by insulating the inner surface from the reducing environment by platinum foils. Fracture in these test conditions is observed to have a gradient in trans and inter-granular fracture as opposed to pure trans-granular fracture observed in homogeneous conditions. Fracture gradients are reasoned to be due to oxygen gradient set up in the membrane, variation in stoichiometry across the thickness and due to varying decomposition of the parent perovskite. The studies are useful in predicting fracture criterion in actual reactor conditions and in understanding the initial evolution of fracture processes.

Dr. Sukumar Bandopadhyay; Dr. Nagendra Nagabhushana

2002-07-01T23:59:59.000Z

218

Modification of Gold Catalysis withModification of Gold Catalysis with Aluminum Phosphate for OxygenAluminum Phosphate for Oxygen--Reduction ReactionReduction Reaction  

E-Print Network [OSTI]

Ford Toshiba Samsung Byungwoo Park's Group #12;Scheme of Fuel Cells Load e- e- Hydrogen Methanol + Water (DMFC· Morphology of Au/AlPO4 Nanocomposite Catalyst · Oxygen Reduction Activity ­ Hydrogen Peroxide Intermediate to Gold Seoul National University Yejun Park et al. 22Byungwoo Park's Group #12;Applications of Fuel Cells

Park, Byungwoo

219

Experimental Research of the Oxygen-Enriched Combustion of Sewage Sludge and Coal in CFB  

Science Journals Connector (OSTI)

Sewage sludge is the by-products of sewage treatment, and it is a fuel of high moisture, high ash and low caloric. Oxygen-enriched combustion technology is one of the new and clean coal combustion technologies...

S. W. Xin; X. F. Lu; H. Z. Liu

2010-01-01T23:59:59.000Z

220

Determination of Hydrocarbons Types and Oxygenates in Motor Gasoline: A Comparative Study by Different Analytical Techniques  

Science Journals Connector (OSTI)

Various standard and published methods based on chromatographic and spectroscopic techniques are routinely used for hydrocarbon types (aromatics, olefins, oxygenates, etc.) in gasoline range fuel products for the assessment of product quality monitoring (...

V. Bansal; G. J. Krishna; A. P. Singh; A. K. Gupta; A. S. Sarpal

2007-12-04T23:59:59.000Z

Note: This page contains sample records for the topic "newable fuels oxygenates" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Size Influence on the Oxygen Reduction Reaction Activity and Instability of Supported Pt Nanoparticles  

E-Print Network [OSTI]

Size-dependent oxygen reduction reaction activity (ORR) and instability of Pt nanoparticles is of great importance in proton exchange membrane fuel cell applications. In this study, the size-dependence of ORR activity on ...

Sheng, Wenchao

222

Detonations in Hydrocarbon Fuel Blends J.M. Austin and J.E. Shepherd  

E-Print Network [OSTI]

.3), nitrogen dilutions (fuel-oxygen to fuel-air), and initial pressures (20-130 kPa). The cell widths of the JP to be comparable. The addition of lower molecular weight fuels (hydrogen, acetylene, ethylene, 1 #12;and carbon, but addition of more than about 75 % (by fuel mass) carbon monoxide results in a significant increase in cell

Low, Steven H.

223

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

Increased environmental regulations will require utility boilers to reduce NO{sub x} emissions to less than 0.15lb/MMBtu in the near term. Conventional technologies such as Selective Catalytic Reduction (SCR) and Selective Non-Catalytic Reduction (SNCR) are unable to achieve these lowered emission levels without substantially higher costs and major operating problems. Oxygen enhanced combustion is a novel technology that allows utilities to meet the NO{sub x} emission requirements without the operational problems that occur with SCR and SNCR. Furthermore, oxygen enhanced combustion can achieve these NO{sub x} limits at costs lower than conventional technologies. The objective of this program is to demonstrate the use of oxygen enhanced combustion as a technical and economical method of meeting the EPA State Implementation Plan for NO{sub x} reduction to less than 0.15lb/MMBtu for a wide range of boilers and coal. The oxygen enhanced coal combustion program (Task 1) focused this quarter on the specific objective of exploration of the impact of oxygen enrichment on NO{sub x} formation utilizing small-scale combustors for parametric testing. Research efforts toward understanding any limitations to the applicability of the technology to different burners and fuels such as different types of coal are underway. The objective of the oxygen transport membrane (OTM) materials development program (Task 2.1) is to ascertain a suitable material composition that can be fabricated into dense tubes capable of producing the target oxygen flux under the operating conditions. This requires that the material have sufficient oxygen permeation resulting from high oxygen ion conductivity, high electronic conductivity and high oxygen surface exchange rate. The OTM element development program (Task 2.2) objective is to develop, fabricate and characterize OTM elements for laboratory and pilot reactors utilizing quality control parameters to ensure reproducibility and superior performance. A specific goal is to achieve a material that will sinter to desired density without compromising other variables such as reaction to binder systems or phase purity. Oxygen-enhanced combustion requires a facility which is capable of supplying high purity oxygen (>99.5%) at low costs. This goal can be achieved through the thermal integration of high temperature air separation with ceramic OTM. The objective of the OTM process development program (Task 2.3) is to demonstrate successfully the program objectives on a lab-scale single OTM tube reactor under process conditions comparable to those of an optimum large-scale oxygen facility. This quarterly technical progress report will summarize work accomplished for the Program through the first quarter April--June 2000 in the following task areas: Task 1 Oxygen Enhanced Coal Combustion; Task 2 Oxygen Transport Membranes; and Task 4 Program Management.

Lawrence E. Bool; Jack C. Chen; David R. Thompson

2000-07-01T23:59:59.000Z

224

Annular feed air breathing fuel cell stack  

DOE Patents [OSTI]

A stack of polymer electrolyte fuel cells is formed from a plurality of unit cells where each unit cell includes fuel cell components defining a periphery and distributed along a common axis, where the fuel cell components include a polymer electrolyte membrane, an anode and a cathode contacting opposite sides of the membrane, and fuel and oxygen flow fields contacting the anode and the cathode, respectively, wherein the components define an annular region therethrough along the axis. A fuel distribution manifold within the annular region is connected to deliver fuel to the fuel flow field in each of the unit cells. The fuel distribution manifold is formed from a hydrophilic-like material to redistribute water produced by fuel and oxygen reacting at the cathode. In a particular embodiment, a single bolt through the annular region clamps the unit cells together. In another embodiment, separator plates between individual unit cells have an extended radial dimension to function as cooling fins for maintaining the operating temperature of the fuel cell stack.

Wilson, Mahlon S. (Los Alamos, NM); Neutzler, Jay K. (Peoria, AZ)

1997-01-01T23:59:59.000Z

225

Synthetic Fuel  

ScienceCinema (OSTI)

Two global energy priorities today are finding environmentally friendly alternatives to fossil fuels, and reducing greenhouse gass Two global energy priorities today are finding environmentally friendly alternatives to fossil fuels, and reducing greenhous

Idaho National Laboratory - Steve Herring, Jim O'Brien, Carl Stoots

2010-01-08T23:59:59.000Z

226

Dilute Oxygen Combustion Phase I Final Report  

SciTech Connect (OSTI)

A novel burner, in which fuel (natural gas) and oxidant (oxygen or air) are separately injected into a furnace, shows promise for achieving very low nitrogen oxide(s) (NOx) emissions for commercial furnace applications. The dilute oxygen combustion (DOC) burner achieves very low NOx through in-furnace dilution of the oxidant stream prior to combustion, resulting in low flame temperatures, thus inhibiting thermal NOx production. The results of a fundamental and applied research effort on the development of the DOC burner are presented. In addition, the results of a market survey detailing the potential commercial impact of the DOC system are disclosed. The fundamental aspects of the burner development project involved examining the flame characteristics of a natural gas turbulent jet in a high-temperature (~1366 K) oxidant (7-27% O2 vol. wet). Specifically, the mass entrainment rate, the flame lift-off height, the velocity field and major species field of the jet were evaluated as a function of surrounding-gas temperature and composition. The measured entrainment rate of the fuel jet decreased with increasing oxygen content in the surrounding high-temperature oxidant, and was well represented by the d+ scaling correlation found in the literature. The measured flame lift-off height decreased with increasing oxygen content and increasing temperature of the surrounding gas. An increase in surrounding-gas oxygen content and/or temperature inhibited the velocity decay within the jet periphery as a function of axial distance as compared to isothermal turbulent jets. However, the velocity measurements were only broadly represented by the d+ scaling correlation. Several DOC burner configurations were tested in a laboratory-scale furnace at a nominal firing rate of 185 kW (~0.63 MMBtu/h). The flue gas composition was recorded as a function of furnace nitrogen content, furnace temperature, burner geometric arrangement, firing rate, and fuel injection velocity. NOx emissions increased with increasing furnace nitrogen content and furnace temperature, but remained relatively insensitive to variations in fuel injection velocity and firing rate. NOx emissions below 5-10-3 g/MJ (10 ppm-air equivalent at 3% O2 dry) were obtained for furnace temperatures below 1533 K (2300°F) and furnace nitrogen levels between 1 and 40%. CO emissions were typically low (<35 ppm). Detailed in-furnace species measurements revealed the importance of the interior furnace circulation patterns, as influenced by fuel and oxidant injection schemes, on pollutant emissions. The combustion stability traits of several DOC burner arrangements were ascertained through furnace pressure measurements, wit6h increased stability occurring as furnace temperature increased and as the separation distance between fuel and oxidant inputs decreased. Based on current market conditions, oxy-fuel conversion of batch steel reheat furnaces with a DOC burner is justified on the basis of lower utility costs alone. However, conversion of continuous steel reheat furnaces, which are responsible for most steel production, required additional economic incentives, such as further fuel savings, increased furnace productivity, or emission credits.

Ryan, H.M.; Riley, M.F.; Kobayashi, H.

1997-10-31T23:59:59.000Z

227

Dilute Oxygen Combustion Phase 2 Final Report  

SciTech Connect (OSTI)

A novel burner, in which fuel (natural gas) and oxidant (oxygen or air) are separately injected into a furnace, shows promise for achieving very low nitrogen oxide(s) (NOx) emissions for commercial furnace applications. The dilute oxygen combustion (DOC) burner achieves very low NOx through in-furnace dilution of the oxidant stream prior to combustion, resulting in low flame temperatures, thus inhibiting thermal NOx production. The results of a fundamental and applied research effort on the development of the DOC burner are presented. In addition, the results of a market survey detailing the potential commercial impact of the DOC system are disclosed. The fundamental aspects of the burner development project involved examining the flame characteristics of a natural gas turbulent jet in a high-temperature (~1366 K) oxidant (7-27% O2 vol. wet). Specifically, the mass entrainment rate, the flame lift-off height, the velocity field and major species field of the jet were evaluated as a function of surrounding-gas temperature and composition. The measured entrainment rate of the fuel jet decreased with increasing oxygen content in the surrounding high-temperature oxidant, and was well represented by the d+ scaling correlation found in the literature. The measured flame lift-off height decreased with increasing oxygen content and increasing temperature of the surrounding gas. An increase in surrounding-gas oxygen content and/or temperature inhibited the velocity decay within the jet periphery as a function of axial distance as compared to isothermal turbulent jets. However, the velocity measurements were only broadly represented by the d+ scaling correlation. Several DOC burner configurations were tested in a laboratory-scale furnace at a nominal firing rate of 185 kW (~0.63 MMBtu/h). The flue gas composition was recorded as a function of furnace nitrogen content, furnace temperature, burner geometric arrangement, firing rate, and fuel injection velocity. NOx emissions increased with increasing furnace nitrogen content and furnace temperature, but remained relatively insensitive to variations in fuel injection velocity and firing rate. NOx emissions below 5-10-3 g/MJ (10 ppm-air equivalent at 3% O2 dry) were obtained for furnace temperatures below 1533 K (2300?F) and furnace nitrogen levels between 1 and 40%. CO emissions were typically low (<35 ppm). Detailed in-furnace species measurements revealed the importance of the interior furnace circulation patterns, as influenced by fuel and oxidant injection schemes, on pollutant emissions. The combustion stability traits of several DOC burner arrangements were ascertained through furnace pressure measurements, wit6h increased stability occurring as furnace temperature increased and as the separation distance between fuel and oxidant inputs decreased. Based on current market conditions, oxy-fuel conversion of batch steel reheat furnaces with a DOC burner is justified on the basis of lower utility costs alone. However, conversion of continuous steel reheat furnaces, which are responsible for most steel production, required additional economic incentives, such as further fuel savings, increased furnace productivity, or emission credits.

Ryan, H.M.; Riley, M.F.; Kobayashi, H.

2005-09-30T23:59:59.000Z

228

Dilute oxygen combustion. Phase I report  

SciTech Connect (OSTI)

A novel burner, in which fuel (natural gas) and oxidant (oxygen or air) are separately injected into a furnace, shows promise for achieving very low nitrogen oxide(s) (NO{sub x}) emissions for commercial furnace applications. The dilute oxygen combustion (DOC) burner achieves very low NO{sub x} through in-furnace dilution of the oxidant stream prior to combustion, resulting in low flame temperatures, thus inhibiting thermal NO{sub x} production. The results of a fundamental and applied research effort on the development of the DOC burner are presented. In addition, the results of a market survey detailing the potential commercial impact of the DOC system are disclosed. The fundamental aspects of the burner development project involved examining the flame characteristics of a natural gas turbulent jet in a high-temperature ({approximately}1366 K) oxidant (7-27% O{sub 2} vol. wet). Specifically, the mass entrainment rate, the flame lift-off height, the velocity field and major species field of the jet were evaluated as a function of surrounding-gas temperature and composition. The measured entrainment rate of the fuel jet decreased with increasing oxygen content in the surrounding high-temperature oxidant, and was well represented by the d{sup +} scaling correlation found in the literature. The measured flame lift-off height decreased with increasing oxygen content and increasing temperature of the surrounding gas. An increase in surrounding-gas oxygen content and/or temperature inhibited the velocity decay within the jet periphery as a function of axial distance as compared to isothermal turbulent jets. However, the velocity measurements were only broadly represented by the d{sup +} scaling correlation. Several DOC burner configurations were tested in a laboratory-scale furnace at a nominal firing rate of 185 kW ({approximately}0.63 MMBtu/h). The flue gas composition was recorded as a function of furnace nitrogen content, furnace temperature, burner geometric arrangement, firing rate, and fuel injection velocity. NO{sub x} emissions increased with increasing furnace nitrogen content and furnace temperature, but remained relatively insensitive to variations in fuel injection velocity and firing rate. NO{sub x} emissions below 5{times}10{sup -3} g/MJ (10 ppm-air equivalent at 3% O{sub 2} dry) were obtained for furnace temperatures below 1533 K (2300{degree}F) and furnace nitrogen levels between 1 and 40%. CO emissions were typically low (<35 ppm). Detailed in- furnace species measurements revealed the importance of the interior furnace circulation patterns, as influenced by fuel and oxidant injection schemes, on pollutant emissions. The combustion stability traits of several DOC burner arrangements were ascertained through furnace pressure measurements, with increased stability occurring as furnace temperature increased and as the separation distance between fuel and oxidant inputs decreased. Based on current market conditions, oxy-fuel conversion of batch steel reheat furnaces with a DOC burner is justified on the basis of utility costs alone. However, conversion of continuous steel reheat furnaces, which are responsible for most steel production, requires additional economic incentives, such as further fuel savings, increased furnace productivity, or emission credits.

NONE

1997-10-01T23:59:59.000Z

229

NETL: Gasification - Development of Ion-Transport Membrane Oxygen  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Feed Systems Feed Systems Recovery Act: Development of Ion-Transport Membrane Oxygen Technology for Integration in IGCC and Other Advanced Power Generation Systems Air Products and Chemicals, Inc. Project Number: FC26-98FT40343 Project Description Air Products and Chemicals, Inc. is developing, scaling-up, and demonstrating a novel air separation technology for large-scale production of oxygen (O2) at costs that are approximately one-third lower than conventional cryogenic plants. An Ion Transport Membrane (ITM) Oxygen plant co-produces power and oxygen. A phased technology RD&D effort is underway to demonstrate all necessary technical and economic requirements for scale-up and industrial commercialization. The ITM Oxygen production technology is a radically different approach to producing high-quality tonnage oxygen and to enhance the performance of integrated gasification combined cycle and other advanced power generation systems. Instead of cooling air to cryogenic temperatures, oxygen is extracted from air at temperatures synergistic with power production operations. Process engineering and economic evaluations of integrated gasification combined cycle (IGCC) power plants comparing ITM Oxygen with a state-of-the-art cryogenic air separation unit are aimed to show that the installed capital cost of the air separation unit and the installed capital of IGCC facility are significantly lower compared to conventional technologies, while improving power plant output and efficiency. The use of low-cost oxygen in combustion processes would provide cost-effective emission reduction and carbon management opportunities. ITM Oxygen is an enabling module for future plants for producing coal derived shifted synthesis gas (a mixture of hydrogen [H2] and carbon dioxide [CO2]) ultimately for producing clean energy and fuels. Oxygen-intensive industries such as steel, glass, non-ferrous metallurgy, refineries, and pulp and paper may also realize cost and productivity benefits as a result of employing ITM Oxygen.

230

NETL: Turbines - Oxy-Fuel Turbines  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Oxy-Fuel Turbines Oxy-Fuel Turbines Oxy-fuel combustion potentially can be used in plants based on both conventional and advanced technology. Studies have shown that plants equipped with oxy-fuel systems could reach nominal efficiencies in the 30 percent range with today's steam turbines when fueled with natural gas and when capturing the CO2. With anticipated advances in gasification, oxygen separation, and steam turbine technology, plants using oxy-fuel systems are expected to achieve efficiencies in the mid-40 percent range, with near-100 percent CO2 capture and near-zero NOx emissions. By 2012: In the near-term, efforts are focused on the development of oxy- fuel turbine and combustor technologies for highly efficient (50-60 percent), near-zero emissions, coal-based power systems

231

Bimetallic Fe–Ni Oxygen Carriers for Chemical Looping Combustion  

Science Journals Connector (OSTI)

(2-4) In CLC (schematic in Figure 1), a fuel is combusted in a fuel reactor (“reducer”) in contact with an oxygen carrier (typically a metal oxide). ... After combustion of the fuel, the reduced metal is then transferred to the air reactor (“oxidizer”) where it is reoxidized by air, and then circulated back to the reducer to close the material “loop”. ... Son, S. R.; Kim, S. D.Chemical-looping combustion with NiO and Fe2O3 in a thermobalance and circulating fluidized bed reactor with double loops Ind. Eng. ...

Saurabh Bhavsar; Götz Veser

2013-05-20T23:59:59.000Z

232

Jupiter Oxygen Corporation/Albany Research Center Crada Progress Report, September  

SciTech Connect (OSTI)

The Albany Research Center (ARC) has developed a new Integrated Pollutant Removal (IPR) process for fossil-fueled boilers. Pursuant to a cooperative research and development agreement (CRADA) with Jupiter Oxygen Corporation, ARC currently is studying the IPR process as applied to the oxygen fuel technology developed by Jupiter. As discussed further below, these two new technologies are complementary. This interim report summarizes the study results to date and outlines the potential activities under the next phase of the CRADA with Jupiter.

Turner, Paul C.; Schoenfield, Mark (Jupiter Oxygen Corp.)

2004-09-13T23:59:59.000Z

233

Natural Ores as Oxygen Carriers in Chemical Looping Combustion  

SciTech Connect (OSTI)

Chemical looping combustion (CLC) is a combustion technology that utilizes oxygen from oxygen carriers (OC), such as metal oxides, instead of air to combust fuels. The use of natural minerals as oxygen carriers has advantages, such as lower cost and availability. Eight materials, based on copper or iron oxides, were selected for screening tests of CLC processes using coal and methane as fuels. Thermogravimetric experiments and bench-scale fixed-bed reactor tests were conducted to investigate the oxygen transfer capacity, reaction kinetics, and stability during cyclic reduction/oxidation reaction. Most natural minerals showed lower combustion capacity than pure CuO/Fe{sub 2}O{sub 3} due to low-concentrations of active oxide species in minerals. In coal CLC, chryscolla (Cu-based), magnetite, and limonite (Fe-based) demonstrated better reaction performances than other materials. The addition of steam improved the coal CLC performance when using natural ores because of the steam gasification of coal and the subsequent reaction of gaseous fuels with active oxide species in the natural ores. In methane CLC, chryscolla, hematite, and limonite demonstrated excellent reactivity and stability in 50-cycle thermogravimetric analysis tests. Fe{sub 2}O{sub 3}-based ores possess greater oxygen utilization but require an activation period before achieving full performance in methane CLC. Particle agglomeration issues associated with the application of natural ores in CLC processes were also studied by scanning electron microscopy (SEM).

Tian, Hanjing; Siriwardane, Ranjani; Simonyi, Thomas; Poston, James

2013-08-01T23:59:59.000Z

234

Alternative Fuels Data Center: Alternative Fueling Infrastructure  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Alternative Fueling Alternative Fueling Infrastructure Development to someone by E-mail Share Alternative Fuels Data Center: Alternative Fueling Infrastructure Development on Facebook Tweet about Alternative Fuels Data Center: Alternative Fueling Infrastructure Development on Twitter Bookmark Alternative Fuels Data Center: Alternative Fueling Infrastructure Development on Google Bookmark Alternative Fuels Data Center: Alternative Fueling Infrastructure Development on Delicious Rank Alternative Fuels Data Center: Alternative Fueling Infrastructure Development on Digg Find More places to share Alternative Fuels Data Center: Alternative Fueling Infrastructure Development on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type

235

Alternative Fuels Data Center: Emerging Fuels  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Emerging Fuels Emerging Fuels Printable Version Share this resource Send a link to Alternative Fuels Data Center: Emerging Fuels to someone by E-mail Share Alternative Fuels Data Center: Emerging Fuels on Facebook Tweet about Alternative Fuels Data Center: Emerging Fuels on Twitter Bookmark Alternative Fuels Data Center: Emerging Fuels on Google Bookmark Alternative Fuels Data Center: Emerging Fuels on Delicious Rank Alternative Fuels Data Center: Emerging Fuels on Digg Find More places to share Alternative Fuels Data Center: Emerging Fuels on AddThis.com... More in this section... Biobutanol Drop-In Biofuels Methanol P-Series Renewable Natural Gas xTL Fuels Emerging Alternative Fuels Several emerging alternative fuels are under development or already developed and may be available in the United States. These fuels may

236

Interaction of mineral matter of coal with oxygen carriers in chemical-looping combustion (CLC)  

Science Journals Connector (OSTI)

Abstract The chemical-looping combustion (CLC) and chemical-looping with oxygen uncoupling (CLOU) processes are novel solutions for efficient combustion with direct separation of carbon dioxide. These processes use a metal oxide as an oxygen carrier to transfer oxygen from an air to a fuel reactor, where the fuel reacts with the solid oxygen carrier. When utilizing coal in CLC, the oxygen carrier particles could be affected through interaction with the ash-forming mineral matter found in coal, causing deactivation and/or agglomeration. In this work, possible interactions between minerals commonly encountered in coal and several promising oxygen carriers that are currently under investigation for their use in CLC are studied by both experiment and thermodynamic equilibrium calculations. Possible interaction was studied for both highly reducing and oxidizing conditions at 900 °C. Under highly reducing conditions pyrite was found to have by far the most deteriorating effect on the oxygen carrier particles, as the sulfur in the pyrite reacted with the oxygen carrier to form sulfides. Quartz and clay minerals were found to have a rather low influence on the oxygen carriers. Out of the oxygen carriers investigated, CuO/MgAl2O4 and the Mn3O4/ZrO2 oxygen carriers tended to be quite reactive towards mineral matter whereas ilmenite has been shown to be the most robust oxygen carrier. Although sulfur can clearly deactivate Ni, Cu and Mn based oxygen carriers under sub-stoichiometric conditions, when the fuel is converted fully to CO2 and H2O, sulfides are only expected for Ni-based oxygen carriers.

Martin Keller; Mehdi Arjmand; Henrik Leion; Tobias Mattisson

2014-01-01T23:59:59.000Z

237

Solar energy: Hydrogen and oxygen  

Science Journals Connector (OSTI)

Solar energy: Hydrogen and oxygen ... Demonstrating the electrolysis of water with solar energy. ...

John J. Farrell

1982-01-01T23:59:59.000Z

238

Fuel Cells  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Fuel Cells Fuel Cells Converting chemical energy of hydrogenated fuels into electricity Project Description Invented in 1839, fuels cells powered the Gemini and Apollo space missions, as well as the space shuttle. Although fuel cells have been successfully used in such applications, they have proven difficult to make more cost-effective and durable for commercial applications, particularly for the rigors of daily transportation. Since the 1970s, scientists at Los Alamos have managed to make various scientific breakthroughs that have contributed to the development of modern fuel cell systems. Specific efforts include the following: * Finding alternative and more cost-effective catalysts than platinum. * Enhancing the durability of fuel cells by developing advanced materials and

239

Optical oxygen concentration monitor  

DOE Patents [OSTI]

A system for measuring and monitoring the concentration of oxygen uses as a light source an argon discharge lamp, which inherently emits light with a spectral line that is close to one of oxygen`s A-band absorption lines. In a preferred embodiment, the argon line is split into sets of components of shorter and longer wavelengths by a magnetic field of approximately 2,000 Gauss that is parallel to the light propagation from the lamp. The longer wavelength components are centered on an absorption line of oxygen and thus readily absorbed, and the shorter wavelength components are moved away from that line and minimally absorbed. A polarization modulator alternately selects the set of the longer wavelength, or upshifted, components or the set of the shorter wavelength, or downshifted, components and passes the selected set to an environment of interest. After transmission over a path through that environment, the transmitted optical flux of the argon line varies as a result of the differential absorption. The system then determines the concentration of oxygen in the environment based on the changes in the transmitted optical flux between the two sets of components. In alternative embodiments modulation is achieved by selectively reversing the polarity of the magnetic field or by selectively supplying the magnetic field to either the emitting plasma of the lamp or the environment of interest. 4 figs.

Kebabian, P.

1997-07-22T23:59:59.000Z

240

Flexible-Fuel Vehicle Basics | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Flexible-Fuel Vehicle Basics Flexible-Fuel Vehicle Basics Flexible-Fuel Vehicle Basics August 20, 2013 - 9:05am Addthis Photo of a gray van with 'E85 Ethanol' written on the side. Flexible fuel vehicles (FFVs) are capable of operating on gasoline, E85 (85% ethanol, 15% gasoline), or a mixture of both. There are almost 8 million flexible fuel vehicles on U.S. roads today, but many FFV owners don't know their vehicle is one. Unlike natural gas vehicles and propane bi-fuel vehicles, flexible fuel vehicles contain one fueling system, which is made up of ethanol-compatible components and is set to accommodate the higher oxygen content of E85. E85 should only be used in ethanol-capable FFVs. For more information, read Flexible Fuel Vehicles: Powered by a Renewable American Fuel. Download Adobe Reader.

Note: This page contains sample records for the topic "newable fuels oxygenates" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Generator configuration for solid oxide fuel cells  

DOE Patents [OSTI]

Disclosed are improvements in a solid oxide fuel cell generator 1 having a multiplicity of electrically connected solid oxide fuel cells 2, where a fuel gas is passed over one side of said cells and an oxygen-containing gas is passed over the other side of said cells resulting in the generation of heat and electricity. The improvements comprise arranging the cells in the configuration of a circle, a spiral, or folded rows within a cylindrical generator, and modifying the flow rate, oxygen concentration, and/or temperature of the oxygen-containing gases that flow to those cells that are at the periphery of the generator relative to those cells that are at the center of the generator. In these ways, a more uniform temperature is obtained throughout the generator.

Reichner, Philip (Plum Boro, PA)

1989-01-01T23:59:59.000Z

242

Oxygen in Underwater Cave  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Oxygen in Underwater Cave Oxygen in Underwater Cave Name: Natalie Status: student Grade: 9-12 Location: HI Country: USA Date: Spring 2011 Question: Is it possible for there to be free oxygen in an underwater cave? If it is, then how does it work? Replies: Yes it is possible as I have personally experienced. If the cave roof rises to a level above the water, air dissolved in the water will slowly out gas until the water is at the same level at all places. A pocket of breathable air will form. In many caves the roof dips below water level in one place but it above it on both sides. Think of a U shaped tube where the bottom of the U is blocked by water. This is called a siphon and I have passed through many of these to find breathable air on the other side. R. W. "Bob" Avakian Oklahoma State Univ. Inst. of Technology

243

Fuel cells, batteries, and the development of electrochemistry  

Science Journals Connector (OSTI)

The first practical breakthrough was achieved in 1958 when the English engineer Francis Th. Bacon (1904–1992) built the first large power unit (5 kW) with hydrogen/oxygen fuel cells [14...]. In order to accelerat...

Vladimir S. Bagotsky

2011-07-01T23:59:59.000Z

244

Microfluidic Hydrogen Fuel Cell with a Liquid Electrolyte  

Science Journals Connector (OSTI)

We report the design and characterization of a microfluidic hydrogen fuel cell with a flowing sulfuric acid solution instead of a Nafion membrane as the electrolyte. We studied the effect of cell resistance, hydrogen and oxygen flow rates, and electrolyte ...

Ranga S. Jayashree; Michael Mitchell; Dilip Natarajan; Larry J. Markoski; Paul J. A. Kenis

2007-05-19T23:59:59.000Z

245

Conversion of raw carbonaceous fuels  

DOE Patents [OSTI]

Three configurations for an electrochemical cell are utilized to generate electric power from the reaction of oxygen or air with porous plates or particulates of carbon, arranged such that waste heat from the electrochemical cells is allowed to flow upwards through a storage chamber or port containing raw carbonaceous fuel. These configurations allow combining the separate processes of devolatilization, pyrolysis and electrochemical conversion of carbon to electric power into a single unit process, fed with raw fuel and exhausting high BTU gases, electric power, and substantially pure CO.sub.2 during operation.

Cooper, John F. (Oakland, CA)

2007-08-07T23:59:59.000Z

246

Dilute Oxygen Combustion - Phase 3 Report  

SciTech Connect (OSTI)

Dilute Oxygen Combustion (DOC) burners have been successfully installed and operated in the reheat furnace at Auburn Steel Co., Inc., Auburn, NY, under Phase 3 of the Dilute Oxygen Combustion project. Two new preheat zones were created employing a total of eight 6.5 MMBtu/hr capacity burners. The preheat zones provide a 30 percent increase in maximum furnace production rate, from 75 tph to 100 tph. The fuel rate is essentially unchanged, with the fuel savings expected from oxy-fuel combustion being offset by higher flue gas temperatures. When allowance is made for the high nitrogen level and high gas phase temperature in the furnace, measured NOx emissions are in line with laboratory data on DOC burners developed in Phase 1 of the project. Burner performance has been good, and there have been no operating or maintenance problems. The DOC system continues to be used as part of Auburn Steel's standard reheat furnace practice. High gas phase temperature is a result of the high firing density needed to achieve high production rates, and little opportunity exists for improvement in that area. However, fuel and NOx performance can be improved by further conversion on furnace zones to DOC burners, which will lower furnace nitrogen levels. Major obstacles are cost and concern about increased formation of oxide scale on the steel. Oxide scale formation may be enhanced by exposure of the steel to higher concentrations of oxidizing gas components (primarily products of combustion) in the higher temperature zones of the furnace. Phase 4 of the DOC project will examine the rate of oxide scale formation in these higher temperature zones and develop countermeasures that will allow DOC burners to be used successfully in these furnace zones.

Riley, Michael F.

2000-05-31T23:59:59.000Z

247

Dilute Oxygen Combustion Phase 3 Final Report  

SciTech Connect (OSTI)

Dilute Oxygen Combustion (DOC) burners have been successfully installed and operated in the reheat furnace at Auburn Steel Co., Inc., Auburn, NY, under Phase 3 of the Dilute Oxygen Combustion project. Two new preheat zones were created employing a total of eight 6.5 MMBtu/hr capacity burners. The preheat zones provide a 30 percent increase in maximum furnace production rate, from 75 tph to 100 tph. The fuel rate is essentially unchanged, with the fuel savings expected from oxy-fuel combustion being offset by higher flue gas temperatures. When allowance is made for the high nitrogen level and high gas phase temperature in the furnace, measured NOx emissions are in line with laboratory data on DOC burners developed in Phase 1 of the project. Burner performance has been good and there have been no operating or maintenance problems. The DOC system continues to be used as part of Auburn Steel?s standard reheat furnace practice. High gas phase temperature is a result of the high firing density needed to achieve high production rates, and little opportunity exists for improvement in that area. However, fuel and NOx performance can be improved by further conversion of furnace zones to DOC burners, which will lower furnace nitrogen levels. Major obstacles are cost and concern about increased formation of oxide scale on the steel. Oxide scale formation may be enhanced by exposure of the steel to higher concentrations of oxidizing gas components (primarily products of combustion) in the higher temperature zones of the furnace. Phase 4 of the DOC project will examine the rate of oxide scale formation in these higher temperature zones and develop countermeasures that will allow DOC burners to be used successfully in these furnace zones.

Riley, M.F.; Ryan, H.M.

2000-05-31T23:59:59.000Z

248

PROPOSITION DE SUJET DE THESE Fundamental study of oxygen exchange and diffusion in cathode  

E-Print Network [OSTI]

materials for fuel cells G. Dezanneau, in collaboration with G. Geneste (CEA) Fuel cells are electrochemical devices that allow the conversion of hydrogen into electricity and heat. One of the main limitations factor for the cell efficiency. This efficiency is basically driven by the oxygen exchange and diffusion

Bezerianos, Anastasia

249

Novel Membranes and Processes for Oxygen Enrichment  

SciTech Connect (OSTI)

The overall goal of this project is to develop a membrane process that produces air containing 25-35% oxygen, at a cost of $25-40/ton of equivalent pure oxygen (EPO2). Oxygen-enriched air at such a low cost will allow existing air-fueled furnaces to be converted economically to oxygen-enriched furnaces, which in turn will improve the economic and energy efficiency of combustion processes significantly, and reduce the cost of CO{sub 2} capture and sequestration from flue gases throughout the U.S. manufacturing industries. During the 12-month Concept Definition project: We identified a series of perfluoropolymers (PFPs) with promising oxygen/nitrogen separation properties, which were successfully made into thin film composite membranes. The membranes showed oxygen permeance as high as 1,200 gpu and oxygen/nitrogen selectivity of 3.0, and the permeance and selectivity were stable over the time period tested (60 days). We successfully scaled up the production of high-flux PFP-based membranes, using MTR's commercial coaters. Two bench-scale spiral-wound modules with countercurrent designs were made and parametric tests were performed to understand the effect of feed flow rate and pressure, permeate pressure and sweep flow rate on the membrane module separation properties. At various operating conditions that modeled potential industrial operating conditions, the module separation properties were similar to the pure-gas separation properties in the membrane stamps. We also identified and synthesized new polymers [including polymers of intrinsic microporosity (PIMs) and polyimides] with higher oxygen/nitrogen selectivity (3.5-5.0) than the PFPs, and made these polymers into thin film composite membranes. However, these membranes were susceptible to severe aging; pure-gas permeance decreased nearly six-fold within two weeks, making them impractical for industrial applications of oxygen enrichment. We tested the effect of oxygen-enriched air on NO{sub x} emissions using a Bloom baffle burner at GTI. The results are positive and confirm that oxygen-enriched combustion can be carried out without producing higher levels of NOx than normal air firing, if lancing of combustion air is used and the excess air levels are controlled. A simple economic study shows that the membrane processes can produce O{sub 2} at less than $40/ton EPO{sub 2} and an energy cost of 1.1-1.5 MMBtu/ton EPO{sub 2}, which are very favorable compared with conventional technologies such as cryogenics and vacuum pressure swing adsorption processes. The benefits of integrated membrane processes/combustion process trains have been evaluated, and show good savings in process costs and energy consumption, as well as reduced CO{sub 2} emissions. For example, if air containing 30% oxygen is used in natural gas furnaces, the net natural gas savings are an estimated 18% at a burner temperature of 2,500 F, and 32% at a burner temperature of 3,000 F. With a 20% market penetration of membrane-based oxygen-enriched combustion in all combustion processes by 2020, the energy savings would be 414-736 TBtu/y in the U.S. The comparable net cost savings are estimated at $1.2-2.1 billion per year by 2020, calculated as the value of fuel savings subtracted from the cost of oxygen production. The fuel savings of 18%-32% by the membrane/oxygen-enriched combustion corresponds to an 18%-32% reduction in CO{sub 2} emissions, or 23-40 MM ton/y less CO{sub 2} from natural gas-fired furnaces by 2020. In summary, results from this project (Concept Definition phase) are highly promising and clearly demonstrate that membrane processes can produce oxygen-enriched air in a low cost manner that will lower operating costs and energy consumption in industrial combustion processes. Future work will focus on proof-of-concept bench-scale demonstration in the laboratory.

Lin, Haiqing

2011-11-15T23:59:59.000Z

250

Fuel Cells  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Materials Science » Materials Science » Fuel Cells Fuel Cells Research into alternative forms of energy, especially energy security, is one of the major national security imperatives of this century. Get Expertise Melissa Fox Applied Energy Email Catherine Padro Sensors & Electrochemical Devices Email Fernando Garzon Sensors & Electrochemical Devices Email Piotr Zelenay Sensors & Electrochemical Devices Email Rod Borup Sensors & Electrochemical Devices Email Karen E. Kippen Experimental Physical Sciences Email Like a battery, a fuel cell consists of two electrodes separated by an electrolyte-in polymer electrolyte fuel cells, the separator is made of a thin polymeric membrane. Unlike a battery, a fuel cell does not need recharging-it continues to produce electricity as long as fuel flows

251

Optimization of the Cathode Catalyst Layer Composition of a PEM Fuel Cell Using a Novel 2-Step Preparation Method.  

E-Print Network [OSTI]

??For good performance and high durability PEM fuel cells run at high water saturation levels. However, excess liquid water generated by the oxygen reduction reaction… (more)

Friedmann, Roland

2009-01-01T23:59:59.000Z

252

Alternative Fuels Data Center: Fuel Prices  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Vehicles Vehicles Printable Version Share this resource Send a link to Alternative Fuels Data Center: Fuel Prices to someone by E-mail Share Alternative Fuels Data Center: Fuel Prices on Facebook Tweet about Alternative Fuels Data Center: Fuel Prices on Twitter Bookmark Alternative Fuels Data Center: Fuel Prices on Google Bookmark Alternative Fuels Data Center: Fuel Prices on Delicious Rank Alternative Fuels Data Center: Fuel Prices on Digg Find More places to share Alternative Fuels Data Center: Fuel Prices on AddThis.com... Fuel Prices As gasoline prices increase, alternative fuels appeal more to vehicle fleet managers and consumers. Like gasoline, alternative fuel prices can fluctuate based on location, time of year, and political climate. Alternative Fuel Price Report

253

Alternative Fuels Data Center: Alternative Fuel License  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Fuel Fuel License to someone by E-mail Share Alternative Fuels Data Center: Alternative Fuel License on Facebook Tweet about Alternative Fuels Data Center: Alternative Fuel License on Twitter Bookmark Alternative Fuels Data Center: Alternative Fuel License on Google Bookmark Alternative Fuels Data Center: Alternative Fuel License on Delicious Rank Alternative Fuels Data Center: Alternative Fuel License on Digg Find More places to share Alternative Fuels Data Center: Alternative Fuel License on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Alternative Fuel License Any person acting as an alternative fuels dealer must hold a valid alternative fuel license and certificate from the Wisconsin Department of Administration. Except for alternative fuels that a dealer delivers into a

254

Alternative Fuels Data Center: Alternative Fuel License  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Fuel Fuel License to someone by E-mail Share Alternative Fuels Data Center: Alternative Fuel License on Facebook Tweet about Alternative Fuels Data Center: Alternative Fuel License on Twitter Bookmark Alternative Fuels Data Center: Alternative Fuel License on Google Bookmark Alternative Fuels Data Center: Alternative Fuel License on Delicious Rank Alternative Fuels Data Center: Alternative Fuel License on Digg Find More places to share Alternative Fuels Data Center: Alternative Fuel License on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Alternative Fuel License Alternative fuel providers, bulk users, and retailers, or any person who fuels an alternative fuel vehicle from a private source that does not pay

255

Fuel Cells  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Fuel Cells Fuel Cells The Solid State Energy Conversion Alliance (SECA) program is responsible for coordinating Federal efforts to facilitate development of a commercially relevant and robust solid oxide fuel cell (SOFC) system. Specific objectives include achieving an efficiency of greater than 60 percent, meeting a stack cost target of $175 per kW, and demonstrating lifetime performance degradation of less than 0.2 percent per

256

OXYGEN TRANSPORT CERAMIC MEMBRANES  

SciTech Connect (OSTI)

In the present quarter, the possibility of using a more complex interfacial engineering approach to the development of reliable and stable oxygen transport perovskite ceramic membranes/metal seals is discussed. Experiments are presented and ceramic/metal interactions are characterized. Crack growth and fracture toughness of the membrane in the reducing conditions are also discussed. Future work regarding this approach is proposed are evaluated for strength and fracture in oxygen gradient conditions. Oxygen gradients are created in tubular membranes by insulating the inner surface from the reducing environment by platinum foils. Fracture in these test conditions is observed to have a gradient in trans and inter-granular fracture as opposed to pure trans-granular fracture observed in homogeneous conditions. Fracture gradients are reasoned to be due to oxygen gradient set up in the membrane, variation in stoichiometry across the thickness and due to varying decomposition of the parent perovskite. The studies are useful in predicting fracture criterion in actual reactor conditions and in understanding the initial evolution of fracture processes.

Dr. Sukumar Bandopadhyay; Dr. Nagendra Nagabhushana

2003-01-01T23:59:59.000Z

257

Optical oxygen concentration monitor  

DOE Patents [OSTI]

A system for measuring and monitoring the concentration of oxygen uses as a light source an argon discharge lamp, which inherently emits light with a spectral line that is close to one of oxygen's A-band absorption lines. In a preferred embodiment, the argon line is split into sets of components of shorter and longer wavelengths by a magnetic field of approximately 2000 Gauss that is parallel to the light propagation from the lamp. The longer wavelength components are centered on an absorption line of oxygen and thus readily absorbed, and the shorter wavelength components are moved away from that line and minimally absorbed. A polarization modulator alternately selects the set of the longer wavelength, or upshifted, components or the set of the shorter wavelength, or downshifted, components and passes the selected set to an environment of interest. After transmission over a path through that environment, the transmitted optical flux of the argon line varies as a result of the differential absorption. The system then determines the concentration of oxygen in the environment based on the changes in the transmitted optical flux between the two sets of components. In alternative embodiments modulation is achieved by selectively reversing the polarity of the magnetic field or by selectively supplying the magnetic field to either the emitting plasma of the lamp or the environment of interest.

Kebabian, Paul (Acton, MA)

1997-01-01T23:59:59.000Z

258

Contiguous Platinum Monolayer Oxygen Reduction Electrocatalysts on High-Stability-Low-Cost Supports  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Contiguous Platinum Monolayer Oxygen Reduction Contiguous Platinum Monolayer Oxygen Reduction Electrocatalysts on High-Stability-Low-Cost Supports Co-PIs: Jia Wang, Miomir Vukmirovic, Kotaro Sasaki, Brookhaven National Laboratory Yang Shao-Horn Massachusetts Institute of Technology Rachel O'Malley, David Thompsett, Sarah Ball, Graham Hard Johnson Matthey Fuel Cells Radoslav Adzic Brookhaven National Laboratory DOE Projects Kickoff Meeting September 30 , 2009 2 Project Overview Project Overview 1. Objectives: Objectives: Developing high performance fuel cell electrocatalysts for the oxygen reduction reaction (ORR) comprising contiguous Pt monolayer Pt monolayer on stable, inexpensive metal or alloy nanorods, nanowires, nanobars and

259

Extended Platinum Nanotubes as Fuel Cell Catalysts  

SciTech Connect (OSTI)

Energy consumption has relied principally on fossil fuels as an energy source; fuel cells, however, can provide a clean and sustainable alternative, an answer to the depletion and climate change concerns of fossil fuels. Within proton exchange membrane fuel cells, high catalyst cost and poor durability limit the commercial viability of the device. Recently, platinum nanotubes (PtNTs) were studied as durable, active catalysts, providing a platform to meet US Department of Energy vehicular activity targets.[1] Porous PtNTs were developed to increase nanotube surface area, improving mass activity for oxygen reduction without sacrificing durability.[2] Subsurface platinum was then replaced with palladium, forming platinum-coated palladium nanotubes.[3] By forming a core shell structure, platinum utilization was increased, reducing catalyst cost. Alternative substrates have also been examined, modifying platinum surface facets and increasing oxygen reduction specific activity. Through modification of the PtNT platform, catalyst limitations can be reduced, ensuring a commercially viable device.

Alia, S.; Pivovar, B. S.; Yan, Y.

2012-01-01T23:59:59.000Z

260

Alternative fuels  

SciTech Connect (OSTI)

This paper presents the preliminary results of a review, of the experiences of Brazil, Canada, and New Zealand, which have implemented programs to encourage the use of alternative motor fuels. It will also discuss the results of a separate completed review of the Department of Energy's (DOE) progress in implementing the Alternative Motor Fuels Act of 1988. The act calls for, among other things, the federal government to use alternative-fueled vehicles in its fleet. The Persian Gulf War, environmental concerns, and the administration's National Energy Strategy have greatly heightened interest in the use of alternative fuels in this country.

Not Available

1991-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "newable fuels oxygenates" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Fuel Cells  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Fuel Cells The Solid State Energy Conversion Alliance (SECA) program is responsible for coordinating Federal efforts to facilitate development of a commercially relevant and robust...

262

Chapter 7 - Chemical-looping processes for fuel-flexible combustion and fuel production  

Science Journals Connector (OSTI)

Abstract Chemical-Looping Combustion (CLC) is a rapidly emerging technology for clean combustion of fossil and renewable fuels. In CLC, the combustion of a fuel is broken down into two, spatially separated steps: The oxidation of fuel in contact with an ‘oxygen carrier’ (typically a metal oxide), and the subsequent reoxidation of the carrier with air. CLC thus produces sequestration-ready CO2 streams with only minor efficiency penalties for CO2 capture. While recent interest in chemical looping was almost exclusively focused on combustion, the underlying reaction engineering principle forms a flexible platform for fuel conversion with a long history in chemical engineering. This chapter gives a brief review of the status of chemical-looping processes for fuel conversion, focused predominantly on reforming and partial oxidation of fossil and renewable fuels and on the impact of fuel composition on combustion.

Saurabh Bhavsar; Michelle Najera; Amey More; Götz Veser

2014-01-01T23:59:59.000Z

263

Oxygenate Supply/Demand Balances in the Short-Term Integrated Forecasting Model (Released in the STEO March 1998)  

Reports and Publications (EIA)

The blending of oxygenates, such as fuel ethanol and methyl tertiary butyl ether (MTBE), into motor gasoline has increased dramatically in the last few years because of the oxygenated and reformulated gasoline programs. Because of the significant role oxygenates now have in petroleum product markets, the Short-Term Integrated Forecasting System (STIFS) was revised to include supply and demand balances for fuel ethanol and MTBE. The STIFS model is used for producing forecasts in the Short-Term Energy Outlook. A review of the historical data sources and forecasting methodology for oxygenate production, imports, inventories, and demand is presented in this report.

1998-01-01T23:59:59.000Z

264

Alternative Fuels Data Center: Electricity Fuel Basics  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Electricity Fuel Electricity Fuel Basics to someone by E-mail Share Alternative Fuels Data Center: Electricity Fuel Basics on Facebook Tweet about Alternative Fuels Data Center: Electricity Fuel Basics on Twitter Bookmark Alternative Fuels Data Center: Electricity Fuel Basics on Google Bookmark Alternative Fuels Data Center: Electricity Fuel Basics on Delicious Rank Alternative Fuels Data Center: Electricity Fuel Basics on Digg Find More places to share Alternative Fuels Data Center: Electricity Fuel Basics on AddThis.com... More in this section... Electricity Basics Production & Distribution Research & Development Related Links Benefits & Considerations Stations Vehicles Laws & Incentives Electricity Fuel Basics Photo of a plug-in hybrid vehicle fueling. Electricity is considered an alternative fuel under the Energy Policy Act

265

Alternative Fuels Data Center: Alternative Fuel Definition  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Alternative Fuel Alternative Fuel Definition to someone by E-mail Share Alternative Fuels Data Center: Alternative Fuel Definition on Facebook Tweet about Alternative Fuels Data Center: Alternative Fuel Definition on Twitter Bookmark Alternative Fuels Data Center: Alternative Fuel Definition on Google Bookmark Alternative Fuels Data Center: Alternative Fuel Definition on Delicious Rank Alternative Fuels Data Center: Alternative Fuel Definition on Digg Find More places to share Alternative Fuels Data Center: Alternative Fuel Definition on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Alternative Fuel Definition The following fuels are defined as alternative fuels by the Energy Policy Act (EPAct) of 1992: pure methanol, ethanol, and other alcohols; blends of

266

Alternative Fuels Data Center: Alternative Fuels Tax  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Fuels Tax Fuels Tax to someone by E-mail Share Alternative Fuels Data Center: Alternative Fuels Tax on Facebook Tweet about Alternative Fuels Data Center: Alternative Fuels Tax on Twitter Bookmark Alternative Fuels Data Center: Alternative Fuels Tax on Google Bookmark Alternative Fuels Data Center: Alternative Fuels Tax on Delicious Rank Alternative Fuels Data Center: Alternative Fuels Tax on Digg Find More places to share Alternative Fuels Data Center: Alternative Fuels Tax on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Alternative Fuels Tax A state excise tax is imposed on the use of alternative fuels. Alternative fuels include liquefied petroleum gas (LPG or propane), compressed natural gas (CNG), and liquefied natural gas (LNG). The current tax rates are as

267

Alternative Fuels Data Center: Renewable Fuel Standard  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Renewable Fuel Renewable Fuel Standard to someone by E-mail Share Alternative Fuels Data Center: Renewable Fuel Standard on Facebook Tweet about Alternative Fuels Data Center: Renewable Fuel Standard on Twitter Bookmark Alternative Fuels Data Center: Renewable Fuel Standard on Google Bookmark Alternative Fuels Data Center: Renewable Fuel Standard on Delicious Rank Alternative Fuels Data Center: Renewable Fuel Standard on Digg Find More places to share Alternative Fuels Data Center: Renewable Fuel Standard on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Renewable Fuel Standard RFS Volumes by Year Enlarge illustration The Renewable Fuel Standard (RFS) is a federal program that requires transportation fuel sold in the U.S. to contain a minimum volume of

268

Alternative Fuels Data Center: Alternative Fuels Tax  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Alternative Fuels Tax Alternative Fuels Tax to someone by E-mail Share Alternative Fuels Data Center: Alternative Fuels Tax on Facebook Tweet about Alternative Fuels Data Center: Alternative Fuels Tax on Twitter Bookmark Alternative Fuels Data Center: Alternative Fuels Tax on Google Bookmark Alternative Fuels Data Center: Alternative Fuels Tax on Delicious Rank Alternative Fuels Data Center: Alternative Fuels Tax on Digg Find More places to share Alternative Fuels Data Center: Alternative Fuels Tax on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Alternative Fuels Tax Excise taxes on alternative fuels are imposed on a gasoline gallon equivalent basis. The tax rate for each alternative fuel type is based on the number of motor vehicles licensed in the state that use the specific

269

Alternative Fuels Data Center: Alternative Fuel Loans  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Fuel Loans Fuel Loans to someone by E-mail Share Alternative Fuels Data Center: Alternative Fuel Loans on Facebook Tweet about Alternative Fuels Data Center: Alternative Fuel Loans on Twitter Bookmark Alternative Fuels Data Center: Alternative Fuel Loans on Google Bookmark Alternative Fuels Data Center: Alternative Fuel Loans on Delicious Rank Alternative Fuels Data Center: Alternative Fuel Loans on Digg Find More places to share Alternative Fuels Data Center: Alternative Fuel Loans on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Alternative Fuel Loans The Oregon Department of Energy administers the State Energy Loan Program (SELP) which offers low-interest loans for qualified projects. Eligible alternative fuel projects include fuel production facilities, dedicated

270

Alternative Fuels Data Center: Alternative Fuels Tax  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Fuels Tax Fuels Tax to someone by E-mail Share Alternative Fuels Data Center: Alternative Fuels Tax on Facebook Tweet about Alternative Fuels Data Center: Alternative Fuels Tax on Twitter Bookmark Alternative Fuels Data Center: Alternative Fuels Tax on Google Bookmark Alternative Fuels Data Center: Alternative Fuels Tax on Delicious Rank Alternative Fuels Data Center: Alternative Fuels Tax on Digg Find More places to share Alternative Fuels Data Center: Alternative Fuels Tax on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Alternative Fuels Tax Alternative fuels are subject to an excise tax at a rate of $0.205 per gasoline gallon equivalent, with a variable component equal to at least 5% of the average wholesale price of the fuel. (Reference Senate Bill 454,

271

Alternative Fuels Data Center: Alternative Fuels Tax  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Fuels Tax Fuels Tax to someone by E-mail Share Alternative Fuels Data Center: Alternative Fuels Tax on Facebook Tweet about Alternative Fuels Data Center: Alternative Fuels Tax on Twitter Bookmark Alternative Fuels Data Center: Alternative Fuels Tax on Google Bookmark Alternative Fuels Data Center: Alternative Fuels Tax on Delicious Rank Alternative Fuels Data Center: Alternative Fuels Tax on Digg Find More places to share Alternative Fuels Data Center: Alternative Fuels Tax on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Alternative Fuels Tax The excise tax imposed on an alternative fuel distributed in New Mexico is $0.12 per gallon. Alternative fuels subject to the excise tax include liquefied petroleum gas (or propane), compressed natural gas, and liquefied

272

Alternative Fuels Data Center: Alternative Fuel Tax  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Alternative Fuel Tax Alternative Fuel Tax to someone by E-mail Share Alternative Fuels Data Center: Alternative Fuel Tax on Facebook Tweet about Alternative Fuels Data Center: Alternative Fuel Tax on Twitter Bookmark Alternative Fuels Data Center: Alternative Fuel Tax on Google Bookmark Alternative Fuels Data Center: Alternative Fuel Tax on Delicious Rank Alternative Fuels Data Center: Alternative Fuel Tax on Digg Find More places to share Alternative Fuels Data Center: Alternative Fuel Tax on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Alternative Fuel Tax The Minnesota Department of Revenue imposes an excise tax on the first licensed distributor that receives E85 fuel products in the state and on distributors, special fuel dealers, or bulk purchasers of other alternative

273

Characteristics of Knock in Hydrogen-Oxygen-Argon SI Engine  

SciTech Connect (OSTI)

A promising approach for improving the efficiency of internal combustion engines is to employ a working fluid with a high specific heat ratio such as the noble gas argon. Moreover, all harmful emissions are eliminated when the intake charge is composed of oxygen, nonreactive argon, and hydrogen fuel. Previous research demonstrated indicated thermal efficiencies greater than 45% at 5.5 compression ratio in engines operating with hydrogen, oxygen, and argon. However, knock limits spark advance and increasing the efficiency further. Conditions under which knock occurs in such engines differs from typical gasoline fueled engines. In-cylinder temperatures using hydrogen-oxygen-argon are higher due to the high specific heat ratio and pressures are lower because of the low compression ratio. Better understanding of knock under these conditions can lead to operating strategies that inhibit knock and allow operation closer to the knock limit. In this work we compare knock with a hydrogen, oxygen, and argon mixture to that of air-gasoline mixtures in a variable compression ratio cooperative fuels research (CFR) engine. The focus is on stability of knocking phenomena, as well as, amplitude and frequency of the resulting pressure waves.

Killingsworth, N; Rapp, V; Flowers, D; Aceves, S; Chen, J; Dibble, R

2010-02-23T23:59:59.000Z

274

Measuring oxygen reduction/evolution reactions on the nanoscale  

SciTech Connect (OSTI)

The efficiency of fuel cells and metal-air batteries is significantly limited by the activation of oxygen reduction and evolution reactions (ORR/OER). Despite the well-recognized role of oxygen reaction kinetics on the viability of energy technologies, the governing mechanisms remain elusive and until now addressable only by macroscopic studies. This lack of nanoscale understanding precludes optimization of material architecture. Here we report direct measurements of oxygen reduction/evolution reactions and oxygen vacancy diffusion on oxygen-ion conductive solid surfaces with sub-10 nanometer resolution. In electrochemical strain microscopy (ESM), the biased scanning probe microscopy tip acts as a moving, electrocatalytically active probe exploring local electrochemical activity. The probe concentrates an electric field in a nanometer-scale volume of material, and bias-induced, picometer-level surface displacements provide information on local electrochemical processes. Systematic mapping of oxygen activity on bare and Pt-functionalized yttria-stabilized zirconia (YSZ) surfaces is demonstrated. This approach allows directly visualization of ORR/OER activation process at the triple-phase boundary, and can be extended to broad spectrum of oxygen-conductive and electrocatalytic materials.

Kalinin, Sergei V [ORNL; Jesse, Stephen [ORNL; Kumar, Amit [ORNL; Morozovska, A. N. [National Academy of Science of Ukraine, Kiev, Ukraine; Ciucci, Francesco [Harvard-Smithsonian Center for Astrophysics

2011-01-01T23:59:59.000Z

275

Fuel Research  

Science Journals Connector (OSTI)

... FUEL research was discussed by Sir Harry McGowan, who succeeds Sir William Larke as president of the Institute of Fuel, in ... has a ragged front, and new knowledge is continually changing relative national positions. Sir Harry McGowan referred to the domestic use of raw coal, which is still preferred to ...

1934-11-24T23:59:59.000Z

276

EFFECT OF FUEL IMPURITIES ON FUEL CELL PERFORMANCE AND DURABILITY  

SciTech Connect (OSTI)

A fuel cell is an electrochemical energy conversion device that produces electricity during the combination of hydrogen and oxygen to produce water. Proton exchange membranes fuel cells are favored for portable applications as well as stationary ones due to their high power density, low operating temperature, and low corrosion of components. In real life operation, the use of pure fuel and oxidant gases results in an impractical system. A more realistic and cost efficient approach is the use of air as an oxidant gas and hydrogen from hydrogen carriers (i.e., ammonia, hydrocarbons, hydrides). However, trace impurities arising from different hydrogen sources and production increases the degradation of the fuel cell. These impurities include carbon monoxide, ammonia, sulfur, hydrocarbons, and halogen compounds. The International Organization for Standardization (ISO) has set maximum limits for trace impurities in the hydrogen stream; however fuel cell data is needed to validate the assumption that at those levels the impurities will cause no degradation. This report summarizes the effect of selected contaminants tested at SRNL at ISO levels. Runs at ISO proposed concentration levels show that model hydrocarbon compound such as tetrahydrofuran can cause serious degradation. However, the degradation is only temporary as when the impurity is removed from the hydrogen stream the performance completely recovers. Other molecules at the ISO concentration levels such as ammonia don't show effects on the fuel cell performance. On the other hand carbon monoxide and perchloroethylene shows major degradation and the system can only be recovered by following recovery procedures.

Colon-Mercado, H.

2010-09-28T23:59:59.000Z

277

Alcohol-based fuels from syngases. [Alkanol fuels  

SciTech Connect (OSTI)

Explains how a mixture of methanol and C/sub 2/-C/sub 6/ saturated alcohols (Alkanol fuel) has the potential for providing a gasoline-blending stock superior to that of straight-run methanol or ethanol. Summarizes the technical and economic advantages of producing and utilizing Alkanol fuels. Although methanol is cheaper, Alkanols represent a higher-quality fuel product with lower-oxygen content and higher hydrogen content. Increasing the methanol content of the Alkanol mixture has the potential to reduce the Alkanols cost of production to the equivalent of that of methanol on a constant heating value basis. The optimal composition will depend on production costs as well as on the properties of Alkanol mixtures necessary to generate a premium, synthetic transportation fuel. The Mobil M-Gasoline Process is an alternative route to converting methanol to synthetic transportation fuels. Concludes that development of the Alkanols Process is in its early stages and further work needs to be done in identifying and solving potential technical bottlenecks related to catalyst stability/selectivity and recovery of water-free Alkanol fuel mixtures. Current work is involved in the study of the performance and stability of several catalyst candidates utilizing a slurry reaction system and in the identification of optimal compositions of Alkanols for use as gasoline blending stocks.

Greene, M.I.

1982-08-01T23:59:59.000Z

278

High pressure oxygen furnace  

DOE Patents [OSTI]

A high temperature high pressure oxygen furnace having a hybrid partially externally heated construction is disclosed. A metallic bar fabricated from an alloy having a composition of at least 45% nickel, 15% chrome, and 10% tungsten is utilized, the preferred alloy including 55% nickel, 22% chrome, 14% tungsten, 2% molybdenum, 3% iron (maximum) and 5% cobalt (maximum). The disclosed alloy is fabricated into 11/4 inch bar stock and has a length of about 17 inches. This bar stock is gun drilled for over 16 inches of its length with 0.400 inch aperture to define a closed high temperature, high pressure oxygen chamber. The opposite and closed end of the bar is provided with a small support aperture into which both a support and a thermocouple can be inserted. The closed end of the gun drilled bar is inserted into an oven, preferably heated by standard nickel chrome electrical elements and having a heavily insulated exterior. 5 figs.

Morris, D.E.

1992-07-14T23:59:59.000Z

279

High pressure oxygen furnace  

DOE Patents [OSTI]

A high temperature high pressure oxygen furnace having a hybrid partially externally heated construction is disclosed. A metallic bar fabricated from an alloy having a composition of at least 45% nickel, 15% chrome, and 10% tungsten is utilized (the preferred alloy including 55% nickel, 22% chrome, 14% tungsten, 2% molybdenum, 3% iron (maximum) and 5% cobalt (maximum). The disclosed alloy is fabricated into 11/4 inch bar stock and has a length of about 17 inches. This bar stock is gun drilled for over 16 inches of its length with 0.400 inch aperture to define a closed high temperature, high pressure oxygen chamber. The opposite and closed end of the bar is provided with a small support aperture into which both a support and a thermocouple can be inserted. The closed end of the gun drilled bar is inserted into an oven, preferably heated by standard nickel chrome electrical elements and having a heavily insulated exterior.

Morris, Donald E. (Kensington, CA)

1992-01-01T23:59:59.000Z

280

Alternative Fuels Data Center: Renewable Fuels Assessment  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Renewable Fuels Renewable Fuels Assessment to someone by E-mail Share Alternative Fuels Data Center: Renewable Fuels Assessment on Facebook Tweet about Alternative Fuels Data Center: Renewable Fuels Assessment on Twitter Bookmark Alternative Fuels Data Center: Renewable Fuels Assessment on Google Bookmark Alternative Fuels Data Center: Renewable Fuels Assessment on Delicious Rank Alternative Fuels Data Center: Renewable Fuels Assessment on Digg Find More places to share Alternative Fuels Data Center: Renewable Fuels Assessment on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Renewable Fuels Assessment The U.S. Department of Defense (DOD) prepared a report, Opportunities for DOD Use of Alternative and Renewable Fuels, on the use and potential use of

Note: This page contains sample records for the topic "newable fuels oxygenates" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Alternative Fuels Data Center: Biodiesel Fuel Basics  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Fuel Basics Fuel Basics to someone by E-mail Share Alternative Fuels Data Center: Biodiesel Fuel Basics on Facebook Tweet about Alternative Fuels Data Center: Biodiesel Fuel Basics on Twitter Bookmark Alternative Fuels Data Center: Biodiesel Fuel Basics on Google Bookmark Alternative Fuels Data Center: Biodiesel Fuel Basics on Delicious Rank Alternative Fuels Data Center: Biodiesel Fuel Basics on Digg Find More places to share Alternative Fuels Data Center: Biodiesel Fuel Basics on AddThis.com... More in this section... Biodiesel Basics Blends Production & Distribution Specifications Related Links Benefits & Considerations Stations Vehicles Laws & Incentives Biodiesel Fuel Basics Related Information National Biofuels Action Plan Biodiesel is a domestically produced, renewable fuel that can be

282

Alternative Fuels Data Center: Renewable Fuel Standard  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Renewable Fuel Renewable Fuel Standard to someone by E-mail Share Alternative Fuels Data Center: Renewable Fuel Standard on Facebook Tweet about Alternative Fuels Data Center: Renewable Fuel Standard on Twitter Bookmark Alternative Fuels Data Center: Renewable Fuel Standard on Google Bookmark Alternative Fuels Data Center: Renewable Fuel Standard on Delicious Rank Alternative Fuels Data Center: Renewable Fuel Standard on Digg Find More places to share Alternative Fuels Data Center: Renewable Fuel Standard on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Renewable Fuel Standard At least 2% of all diesel fuel sold in Washington must be biodiesel or renewable diesel. This requirement will increase to 5% 180 days after the

283

Alternative Fuels Data Center: Biodiesel Fuel Use  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Biodiesel Fuel Use to Biodiesel Fuel Use to someone by E-mail Share Alternative Fuels Data Center: Biodiesel Fuel Use on Facebook Tweet about Alternative Fuels Data Center: Biodiesel Fuel Use on Twitter Bookmark Alternative Fuels Data Center: Biodiesel Fuel Use on Google Bookmark Alternative Fuels Data Center: Biodiesel Fuel Use on Delicious Rank Alternative Fuels Data Center: Biodiesel Fuel Use on Digg Find More places to share Alternative Fuels Data Center: Biodiesel Fuel Use on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Biodiesel Fuel Use The Iowa Department of Transportation (IDOT) may purchase biodiesel for use in IDOT vehicles through the biodiesel fuel revolving fund created in the state treasury. The fund consists of money received from the sale of Energy

284

Alternative Fuels Data Center: Alternative Fuel Tax  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Fuel Tax Fuel Tax to someone by E-mail Share Alternative Fuels Data Center: Alternative Fuel Tax on Facebook Tweet about Alternative Fuels Data Center: Alternative Fuel Tax on Twitter Bookmark Alternative Fuels Data Center: Alternative Fuel Tax on Google Bookmark Alternative Fuels Data Center: Alternative Fuel Tax on Delicious Rank Alternative Fuels Data Center: Alternative Fuel Tax on Digg Find More places to share Alternative Fuels Data Center: Alternative Fuel Tax on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Alternative Fuel Tax Special fuels, including biodiesel, biodiesel blends, biomass-based diesel, biomass-based diesel blends, and liquefied natural gas, have a reduced tax rate of $0.27 per gallon. Liquefied petroleum gas (LPG or propane) and

285

Alternative Fuels Data Center: Special Fuel Tax  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Special Fuel Tax to Special Fuel Tax to someone by E-mail Share Alternative Fuels Data Center: Special Fuel Tax on Facebook Tweet about Alternative Fuels Data Center: Special Fuel Tax on Twitter Bookmark Alternative Fuels Data Center: Special Fuel Tax on Google Bookmark Alternative Fuels Data Center: Special Fuel Tax on Delicious Rank Alternative Fuels Data Center: Special Fuel Tax on Digg Find More places to share Alternative Fuels Data Center: Special Fuel Tax on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Special Fuel Tax Effective January 1, 2014, certain special fuels sold or used to propel motor vehicles are subject to a license tax. Liquefied natural gas is subject to a tax of $0.16 per diesel gallon equivalent. Compressed natural

286

Alternative Fuels Data Center: Ethanol Fuel Basics  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Fuel Basics to Fuel Basics to someone by E-mail Share Alternative Fuels Data Center: Ethanol Fuel Basics on Facebook Tweet about Alternative Fuels Data Center: Ethanol Fuel Basics on Twitter Bookmark Alternative Fuels Data Center: Ethanol Fuel Basics on Google Bookmark Alternative Fuels Data Center: Ethanol Fuel Basics on Delicious Rank Alternative Fuels Data Center: Ethanol Fuel Basics on Digg Find More places to share Alternative Fuels Data Center: Ethanol Fuel Basics on AddThis.com... More in this section... Ethanol Basics Blends Specifications Production & Distribution Feedstocks Related Links Benefits & Considerations Stations Vehicles Laws & Incentives Ethanol Fuel Basics Related Information National Biofuels Action Plan Ethanol is a renewable fuel made from various plant materials collectively

287

Alternative Fuels Data Center: Biodiesel Fuel Use  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Fuel Use to Fuel Use to someone by E-mail Share Alternative Fuels Data Center: Biodiesel Fuel Use on Facebook Tweet about Alternative Fuels Data Center: Biodiesel Fuel Use on Twitter Bookmark Alternative Fuels Data Center: Biodiesel Fuel Use on Google Bookmark Alternative Fuels Data Center: Biodiesel Fuel Use on Delicious Rank Alternative Fuels Data Center: Biodiesel Fuel Use on Digg Find More places to share Alternative Fuels Data Center: Biodiesel Fuel Use on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Biodiesel Fuel Use The South Dakota Department of Transportation and employees using state diesel vehicles must stock and use fuel blends containing a minimum of 2% biodiesel (B2) that meets or exceeds the most current ASTM specification

288

Alternative Fuels Data Center: Hydrogen Fuel Specifications  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Hydrogen Fuel Hydrogen Fuel Specifications to someone by E-mail Share Alternative Fuels Data Center: Hydrogen Fuel Specifications on Facebook Tweet about Alternative Fuels Data Center: Hydrogen Fuel Specifications on Twitter Bookmark Alternative Fuels Data Center: Hydrogen Fuel Specifications on Google Bookmark Alternative Fuels Data Center: Hydrogen Fuel Specifications on Delicious Rank Alternative Fuels Data Center: Hydrogen Fuel Specifications on Digg Find More places to share Alternative Fuels Data Center: Hydrogen Fuel Specifications on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Hydrogen Fuel Specifications The California Department of Food and Agriculture, Division of Measurement Standards (DMS) established interim specifications for hydrogen fuels for

289

Alternative Fuels Data Center: Flexible Fuel Vehicles  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Ethanol Ethanol Printable Version Share this resource Send a link to Alternative Fuels Data Center: Flexible Fuel Vehicles to someone by E-mail Share Alternative Fuels Data Center: Flexible Fuel Vehicles on Facebook Tweet about Alternative Fuels Data Center: Flexible Fuel Vehicles on Twitter Bookmark Alternative Fuels Data Center: Flexible Fuel Vehicles on Google Bookmark Alternative Fuels Data Center: Flexible Fuel Vehicles on Delicious Rank Alternative Fuels Data Center: Flexible Fuel Vehicles on Digg Find More places to share Alternative Fuels Data Center: Flexible Fuel Vehicles on AddThis.com... More in this section... Ethanol Basics Benefits & Considerations Stations Vehicles Availability Conversions Emissions Laws & Incentives Flexible Fuel Vehicles Photo of a flexible fuel vehicle.

290

Alternative Fuels Data Center: Alternative Fuel Use  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Fuel Use Fuel Use to someone by E-mail Share Alternative Fuels Data Center: Alternative Fuel Use on Facebook Tweet about Alternative Fuels Data Center: Alternative Fuel Use on Twitter Bookmark Alternative Fuels Data Center: Alternative Fuel Use on Google Bookmark Alternative Fuels Data Center: Alternative Fuel Use on Delicious Rank Alternative Fuels Data Center: Alternative Fuel Use on Digg Find More places to share Alternative Fuels Data Center: Alternative Fuel Use on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Alternative Fuel Use All state employees operating flexible fuel or diesel vehicles as part of the state fleet must use E85 or biodiesel blends whenever reasonably available. Additionally, the Nebraska Transportation Services Bureau and

291

Alternative Fuels Data Center: Alternative Fuels Tax  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Fuels Tax Fuels Tax to someone by E-mail Share Alternative Fuels Data Center: Alternative Fuels Tax on Facebook Tweet about Alternative Fuels Data Center: Alternative Fuels Tax on Twitter Bookmark Alternative Fuels Data Center: Alternative Fuels Tax on Google Bookmark Alternative Fuels Data Center: Alternative Fuels Tax on Delicious Rank Alternative Fuels Data Center: Alternative Fuels Tax on Digg Find More places to share Alternative Fuels Data Center: Alternative Fuels Tax on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Alternative Fuels Tax Alternative fuels used to propel vehicles of any kind on public highways are taxed at a rate determined on a gasoline gallon equivalent basis. The tax rates are posted in the Pennsylvania Bulletin. (Reference Title 75

292

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. In the previous research, the reference point of oxygen occupancy was determined and verified. In the current research, the oxygen occupancy was investigated at 1200 C as a function of oxygen activity and compared with that at 1000 C. The cause of bumps at about 200 C was also investigated by using different heating and cooling rates during TGA. The fracture toughness of LSFT and dual phase membranes at room temperature is an important mechanical property. Vicker's indentation method was used to evaluate this toughness. Through this technique, a K{sub Ic} (Mode-I Fracture Toughness) value is attained by means of semi-empirical correlations between the indentation load and the length of the cracks emanating from the corresponding Vickers indentation impression. In the present investigation, crack propagation behavior was extensively analyzed in order to understand the strengthening mechanisms involved in the non-transforming La based ceramic composites. Cracks were generated using Vicker's indenter and used to identify and evaluate the toughening mechanisms involved. Preliminary results of an electron microscopy study of the origin of the slow kinetics on reduction of ferrites have been obtained. The slow kinetics appear to be related to a non-equilibrium reduction pathway that initially results in the formation of iron particles. At long times, equilibrium can be reestablished with recovery of the perovskite phase. Modeling of the isotopic transients on operating membranes (LSCrF-2828 at 900 C) and a ''frozen'' isotope profile have been analyzed in conjunction with a 1-D model to reveal the gradient in oxygen diffusivity through the membrane under conditions of high chemical gradients.

S. Bandopadhyay; T. Nithyanantham; X.-D Zhou; Y-W. Sin; H.U. Anderson; Alan Jacobson; C.A. Mims

2005-08-01T23:59:59.000Z

293

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. The in situ electrical conductivity and Seebeck coefficient measurements were made on LSFT at 1000 and 1200 C over the oxygen activity range from air to 10{sup -15} atm. The electrical conductivity measurements exhibited a p to n type transition at an oxygen activity of 1 x 10{sup -10} at 1000 C and 1 x 10{sup -6} at 1200 C. Thermogravimetric studies were also carried out over the same oxygen activities and temperatures. Based on the results of these measurements, the chemical and mechanical stability range of LSFT were determined and defect structure was established. The studies on the fracture toughness of the LSFT and dual phase membranes exposed to air and N{sub 2} at 1000 C was done and the XRD and SEM analysis of the specimens were carried out to understand the structural and microstructural changes. The membranes that are exposed to high temperatures at an inert and a reactive atmosphere undergo many structural and chemical changes which affect the mechanical properties. A complete transformation of fracture behavior was observed in the N{sub 2} treated LSFT samples. Further results to investigate the origin of the slow kinetics on reduction of ferrites have been obtained. The slow kinetics appear to be related to a non-equilibrium reduction pathway that initially results in the formation of iron particles. At long times, equilibrium can be reestablished with recovery of the perovskite phase. Recent results on transient kinetic data are presented. The 2-D modeling of oxygen movement has been undertaken in order to fit isotope data. The model is used to study ''frozen'' profiles in patterned or composite membranes.

S. Bandopadhyay; T. Nithyanantham; X.-D Zhou; Y-W. Sin; H.U. Anderson; Alan Jacobson; C.A. Mims

2005-02-01T23:59:59.000Z

294

Oxygen abundances in the most oxygen-rich spiral galaxies  

E-Print Network [OSTI]

Oxygen abundances in the spiral galaxies expected to be richest in oxygen are estimated. The new abundance determinations are based on the recently discovered ff-relation between auroral and nebular oxygen line fluxes in HII regions. We find that the maximum gas-phase oxygen abundance in the central regions of spiral galaxies is 12+log(O/H)~8.75. This value is significantly lower than the previously accepted value. The central oxygen abundance in the Milky Way is similar to that in other large spirals.

L. S. Pilyugin; T. X. Thuan; J. M. Vilchez

2006-01-06T23:59:59.000Z

295

Oxygen Concentration Microgradients for Cell Culture  

E-Print Network [OSTI]

The Chemotactic Effect of Oxygen on Bacteria,” J. Pathol.Measurement and Control of Oxygen Levels in MicrofluidicA Microfabricated Electrochemical Oxygen Generator for High-

Park, Jaehyun

2010-01-01T23:59:59.000Z

296

California Fuel Cell Partnership: Alternative Fuels Research  

Broader source: Energy.gov [DOE]

This presentation by Chris White of the California Fuel Cell Partnership provides information about alternative fuels research.

297

Kinetics of oxygen reduction at IrO{sub 2}-coated titanium electrode in alkaline solution  

SciTech Connect (OSTI)

Oxygen reduction is an industrially important electrochemical reaction, for fuel cells, electrochemical caustic concentrators, air depolarized cathodes, metal-air batteries, and oxidant production. Oxygen reduction at IrO{sub 2}-coated titanium electrodes fabricated by thermal decomposition was investigated by employing cyclic voltammetry and rotating-disk electrode techniques. Cyclic voltammetric results indicated that oxygen reduction begins during the Ir(III)/Ir(IV) transition on an IrO{sub 2} electrode. On the basis of measurements using a rotating disk electrode together with polarization curves, Tafel slopes, and stoichiometric number determinations, a mechanism for oxygen reduction on an IrO{sub 2}-coated titanium electrode is proposed.

Chang, C.C.; Wen, T.C. [National Cheng Kung Univ., Tainan (Taiwan, Province of China). Dept. of Chemical Engineering

1996-05-01T23:59:59.000Z

298

Fuel Processing Valri Lightner  

E-Print Network [OSTI]

, ORNL, NETL #12;Accomplishments · Demonstrated in the lab an advanced fuel flexible fuel processor

299

Epitaxial oxygen sponges as low temperature catalysts | ornl.gov  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Functional Materials for Energy Functional Materials for Energy Epitaxial oxygen sponges as low temperature catalysts September 10, 2013 Crystal structure of SrCoO2.5 superimposed on a scanning transmission electron microscopy image of an epitaxially stabilized oxygen sponge. Fast and reversible redox reactions at considerably reduced temperatures are achieved by epitaxial stabilization of multivalent transition metal oxides. This illustrates the unprecedented potential of complex oxides for oxide-ionics, where oxidation state changes are used for energy generation, storage and electrochemical sensing. Thermomechanical degradation reduces the overall performance and lifetime of many perovskite oxides undergoing reversible redox reactions, such as those found in solid oxide fuel cells, rechargeable batteries,

300

Oxygen Transport Membranes  

SciTech Connect (OSTI)

The focus of this research was to develop new membrane materials by synthesizing different compounds and determining their defect structures, crystallographic structures and electrical properties. In addition to measuring electrical conductivity, oxygen vacancy concentration was also evaluated using thermogravimetry, Neutron diffraction and Moessbauer Spectroscopy. The reducing conditions (CO{sub 2}/CO/H{sub 2} gas mixtures with steam) as encountered in a reactor environment can be expected to have significant influence on the mechanical properties of the oxides membranes. Various La based materials with and without Ti were selected as candidate membrane materials for OTM. The maximum electrical conductivity of LSF in air as a function of temperature was achieved at < 600 C and depends on the concentration of Sr (acceptor dopant). Oxygen occupancy in LSF was estimated using Neutron diffractometry and Moessbauer Spectroscopy by measuring magnetic moment changes depending on the Fe{sup 3+} and Fe{sup 4+} ratio. After extensive studies of candidate materials, lanthanum ferrites (LSF and LSFT) were selected as the favored materials for the oxygen transport membrane (OTM). LSF is a very good material for an OTM because of its high electronic and oxygen ionic conductivity if long term stability and mechanical strength are improved. LSFT not only exhibits p-type behavior in the high oxygen activity regime, but also has n-type conduction in reducing atmospheres. Higher concentrations of oxygen vacancies in the low oxygen activity regime may improve the performance of LSFT as an OTM. The hole concentration is related to the difference in the acceptor and donor concentration by the relation p = [Sr'{sub La}]-[Ti{sm_bullet}{sub Fe}]. The chemical formulation predicts that the hole concentration is, p = 0.8-0.45 or 0.35. Experimental measurements indicated that p is about {approx} 0.35. The activation energy of conduction is 0.2 eV which implies that LSCF conducts via the small polaron conduction mechanism. Scanning transmission electron microscopy (STEM) and electron energy loss spectroscopy (EELS) were used to develop strategies to detect and characterize vacancy creation, dopant segregations and defect association in the oxygen conducting membrane material. The pO{sub 2} and temperature dependence of the conductivity, non-stoichiometry and thermal-expansion behavior of compositions with increasing complexity of substitution on the perovskite A and B sites were studied. Studies with the perovskite structure show anomalous behavior at low oxygen partial pressures (<10{sup -5} atm). The anomalies are due to non-equilibrium effects and can be avoided by using very strict criteria for the attainment of equilibrium. The slowness of the oxygen equilibration kinetics arises from two different mechanisms. In the first, a two phase region occurs between an oxygen vacancy ordered phase such as brownmillerite SrFeO{sub 2.5} and perovskite SrFeO{sub 3-x}. The slow kinetics is associated with crossing the two phase region. The width of the miscibility gap decreases with increasing temperature and consequently the effect is less pronounced at higher temperature. The preferred kinetic pathway to reduction of perovskite ferrites when the vacancy concentration corresponds to the formation of significant concentrations of Fe{sup 2+} is via the formation of a Ruddlesden-Popper (RP) phases as clearly observed in the case of La{sub 0.5}Sr{sub 0.5}FeO{sub 3-x} where LaSrFeO{sub 4} is found together with Fe. In more complex compositions, such as LSFTO, iron or iron rich phases are observed locally with no evidence for the presence of discrete RP phase. Fracture strength of tubular perovskite membranes was determined in air and in reducing atmospheric conditions. The strength of the membrane decreased with temperature and severity of reducing conditions although the strength distribution (Weibull parameter, m) was relatively unaltered. Surface and volume dominated the fracture origins and the overall fracture was purely transgranular. The dual phas

S. Bandopadhyay

2008-08-30T23:59:59.000Z

Note: This page contains sample records for the topic "newable fuels oxygenates" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. Thermogravimetric analysis (TGA) was carried out on La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} to investigate oxygen deficiency ({delta}) of the sample. The TGA was performed in a controlled atmosphere using oxygen, argon, carbon monoxide and carbon dioxide with adjustable gas flow rates. In this experiment, the weight loss and gain of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} was directly measured by TGA. The weight change of the sample was evaluated at between 600 and 1250 C in air or 1000 C as a function of oxygen partial pressure. The oxygen deficiencies calculated from TGA data as a function of oxygen activity and temperature will be estimated and compared with that from neutron diffraction measurement in air. The LSFT and LSFT/CGO membranes were fabricated from the powder obtained from Praxair Specialty Ceramics. The sintered membranes were subjected to microstructure analysis and hardness analysis. The LSFT membrane is composed of fine grains with two kinds of grain morphology. The grain size distribution was characterized using image analysis. In LSFT/CGO membrane a lot of grain pullout was observed from the less dense, porous phase. The hardness of the LSFT and dual phase membranes were studied at various loads. The hardness values obtained from the cross section of the membranes were also compared to that of the values obtained from the surface. An electrochemical cell has been designed and built for measurements of the Seebeck coefficient as a function of temperature and pressure. Measurements on La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} as a function of temperature an oxygen partial pressure are reported. Further analysis of the dilatometry data obtained previously is presented. A series of isotope transients under air separation mode (small gradient) were completed on the membrane of LSCrF-2828 at 900 C. Low pO{sub 2} atmospheres based on with CO-CO{sub 2} mixtures have also been admitted to the delivery side of the LSCrF-2828 membrane to produce the gradients which exist under syngas generation conditions. The CO-CO{sub 2} mixtures have normal isotopic {sup 18}O abundances. The evolution of {sup 18}O on the delivery side in these experiments after an {sup 18}O pulse on the air side reveals a wealth of information about the oxygen transport processes.

S. Bandopadhyay; N. Nagabhushana; T. Nithyanantham; X.-D Zhou; Y-W. Sin; H.U. Anderson; Alan Jacobson; C.A. Mims

2005-02-01T23:59:59.000Z

302

Alternative Fuels Data Center: Renewable Fuels Mandate  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Renewable Fuels Renewable Fuels Mandate to someone by E-mail Share Alternative Fuels Data Center: Renewable Fuels Mandate on Facebook Tweet about Alternative Fuels Data Center: Renewable Fuels Mandate on Twitter Bookmark Alternative Fuels Data Center: Renewable Fuels Mandate on Google Bookmark Alternative Fuels Data Center: Renewable Fuels Mandate on Delicious Rank Alternative Fuels Data Center: Renewable Fuels Mandate on Digg Find More places to share Alternative Fuels Data Center: Renewable Fuels Mandate on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Renewable Fuels Mandate All gasoline sold in the state must be blended with 10% ethanol (E10). Gasoline with an octane rating of 91 or above is exempt from this mandate,

303

Alternative Fuels Data Center: Renewable Fuels Promotion  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Renewable Fuels Renewable Fuels Promotion to someone by E-mail Share Alternative Fuels Data Center: Renewable Fuels Promotion on Facebook Tweet about Alternative Fuels Data Center: Renewable Fuels Promotion on Twitter Bookmark Alternative Fuels Data Center: Renewable Fuels Promotion on Google Bookmark Alternative Fuels Data Center: Renewable Fuels Promotion on Delicious Rank Alternative Fuels Data Center: Renewable Fuels Promotion on Digg Find More places to share Alternative Fuels Data Center: Renewable Fuels Promotion on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Renewable Fuels Promotion Recognizing that biofuels such as ethanol and biodiesel will be an important part of the state's energy economy and advanced research in

304

Alternative Fuels Data Center: Fuel Quality Standards  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Fuel Quality Standards Fuel Quality Standards to someone by E-mail Share Alternative Fuels Data Center: Fuel Quality Standards on Facebook Tweet about Alternative Fuels Data Center: Fuel Quality Standards on Twitter Bookmark Alternative Fuels Data Center: Fuel Quality Standards on Google Bookmark Alternative Fuels Data Center: Fuel Quality Standards on Delicious Rank Alternative Fuels Data Center: Fuel Quality Standards on Digg Find More places to share Alternative Fuels Data Center: Fuel Quality Standards on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Fuel Quality Standards The South Dakota Department of Public Safety may promulgate rules establishing: Standards for the maximum volume percentages of ethanol and methanol

305

Alternative Fuels Data Center: Renewable Fuels Mandate  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Renewable Fuels Renewable Fuels Mandate to someone by E-mail Share Alternative Fuels Data Center: Renewable Fuels Mandate on Facebook Tweet about Alternative Fuels Data Center: Renewable Fuels Mandate on Twitter Bookmark Alternative Fuels Data Center: Renewable Fuels Mandate on Google Bookmark Alternative Fuels Data Center: Renewable Fuels Mandate on Delicious Rank Alternative Fuels Data Center: Renewable Fuels Mandate on Digg Find More places to share Alternative Fuels Data Center: Renewable Fuels Mandate on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Renewable Fuels Mandate One year after in-state production has reached 350 million gallons of cellulosic ethanol and sustained this volume for three months, all gasoline

306

Alternative Fuels Data Center: Alternative Fuels Promotion  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Alternative Fuels Alternative Fuels Promotion to someone by E-mail Share Alternative Fuels Data Center: Alternative Fuels Promotion on Facebook Tweet about Alternative Fuels Data Center: Alternative Fuels Promotion on Twitter Bookmark Alternative Fuels Data Center: Alternative Fuels Promotion on Google Bookmark Alternative Fuels Data Center: Alternative Fuels Promotion on Delicious Rank Alternative Fuels Data Center: Alternative Fuels Promotion on Digg Find More places to share Alternative Fuels Data Center: Alternative Fuels Promotion on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Alternative Fuels Promotion The state of Hawaii has signed a memorandum of understanding (MOU) with the U.S. Department of Energy to collaborate to produce 70% of the state's

307

Alternative Fuels Data Center: Alternative Fuel Tax  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Alternative Fuel Tax Alternative Fuel Tax to someone by E-mail Share Alternative Fuels Data Center: Alternative Fuel Tax on Facebook Tweet about Alternative Fuels Data Center: Alternative Fuel Tax on Twitter Bookmark Alternative Fuels Data Center: Alternative Fuel Tax on Google Bookmark Alternative Fuels Data Center: Alternative Fuel Tax on Delicious Rank Alternative Fuels Data Center: Alternative Fuel Tax on Digg Find More places to share Alternative Fuels Data Center: Alternative Fuel Tax on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Alternative Fuel Tax The excise tax imposed on compressed natural gas (CNG), liquefied natural gas (LNG), and liquefied petroleum gas (LPG or propane) used to operate a vehicle can be paid through an annual flat rate sticker tax based on the

308

Alternative Fuels Data Center: Renewable Fuel Promotion  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Renewable Fuel Renewable Fuel Promotion to someone by E-mail Share Alternative Fuels Data Center: Renewable Fuel Promotion on Facebook Tweet about Alternative Fuels Data Center: Renewable Fuel Promotion on Twitter Bookmark Alternative Fuels Data Center: Renewable Fuel Promotion on Google Bookmark Alternative Fuels Data Center: Renewable Fuel Promotion on Delicious Rank Alternative Fuels Data Center: Renewable Fuel Promotion on Digg Find More places to share Alternative Fuels Data Center: Renewable Fuel Promotion on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Renewable Fuel Promotion The Texas Bioenergy Policy Council and the Texas Bioenergy Research Committee were established to promote the goal of making biofuels a

309

Alternative Fuels Data Center: Renewable Fuel Standard  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Renewable Fuel Renewable Fuel Standard to someone by E-mail Share Alternative Fuels Data Center: Renewable Fuel Standard on Facebook Tweet about Alternative Fuels Data Center: Renewable Fuel Standard on Twitter Bookmark Alternative Fuels Data Center: Renewable Fuel Standard on Google Bookmark Alternative Fuels Data Center: Renewable Fuel Standard on Delicious Rank Alternative Fuels Data Center: Renewable Fuel Standard on Digg Find More places to share Alternative Fuels Data Center: Renewable Fuel Standard on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Renewable Fuel Standard Within six months following the point at which monthly production of denatured ethanol produced in Louisiana equals or exceeds a minimum annualized production volume of 50 million gallons, at least 2% of the

310

Alternative Fuels Data Center: Alternative Fuel Tax  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Fuel Tax Fuel Tax to someone by E-mail Share Alternative Fuels Data Center: Alternative Fuel Tax on Facebook Tweet about Alternative Fuels Data Center: Alternative Fuel Tax on Twitter Bookmark Alternative Fuels Data Center: Alternative Fuel Tax on Google Bookmark Alternative Fuels Data Center: Alternative Fuel Tax on Delicious Rank Alternative Fuels Data Center: Alternative Fuel Tax on Digg Find More places to share Alternative Fuels Data Center: Alternative Fuel Tax on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Alternative Fuel Tax The state road tax for vehicles that operate on propane (liquefied petroleum gas, or LPG) or natural gas is paid through the purchase of an annual flat fee sticker, and the amount is based on the vehicle's gross

311

Alternative Fuels Data Center: Propane Fueling Stations  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Stations to someone by E-mail Stations to someone by E-mail Share Alternative Fuels Data Center: Propane Fueling Stations on Facebook Tweet about Alternative Fuels Data Center: Propane Fueling Stations on Twitter Bookmark Alternative Fuels Data Center: Propane Fueling Stations on Google Bookmark Alternative Fuels Data Center: Propane Fueling Stations on Delicious Rank Alternative Fuels Data Center: Propane Fueling Stations on Digg Find More places to share Alternative Fuels Data Center: Propane Fueling Stations on AddThis.com... More in this section... Propane Basics Benefits & Considerations Stations Locations Infrastructure Development Vehicles Laws & Incentives Propane Fueling Stations Photo of a liquefied petroleum gas fueling station. Thousands of liquefied petroleum gas (propane) fueling stations are

312

Alternative Fuels Data Center: Alternative Fuel Study  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Alternative Fuel Study Alternative Fuel Study to someone by E-mail Share Alternative Fuels Data Center: Alternative Fuel Study on Facebook Tweet about Alternative Fuels Data Center: Alternative Fuel Study on Twitter Bookmark Alternative Fuels Data Center: Alternative Fuel Study on Google Bookmark Alternative Fuels Data Center: Alternative Fuel Study on Delicious Rank Alternative Fuels Data Center: Alternative Fuel Study on Digg Find More places to share Alternative Fuels Data Center: Alternative Fuel Study on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Alternative Fuel Study As directed by the Nevada Legislature, the Legislative Commission (Commission) conducted an interim study in 2011 concerning the production and use of energy in the state. The study included information on the use

313

FUEL CELLS – DIRECT ALCOHOL FUEL CELLS | Direct Ethylene Glycol Fuel Cells  

Science Journals Connector (OSTI)

Direct ethylene glycol fuel cells, in which the oxidation of ethylene glycol and the reduction of oxygen take place at the anode and the cathode, respectively, are promising candidates as electric power sources of portable devices such as the cellular phone and the laptop computer. The advantages of ethylene glycol are high activity, high energy density, low volatility, and high boiling point compared with other organic fuels such as methanol and ethanol. In this article, the construction of direct ethylene glycol fuel cells, the electrooxidation of ethylene glycol in acid and alkaline solutions, cathode catalysts, and operating conditions such as temperature, pH of the electrolytes, and the concentration of ethylene glycol are described.

Z. Ogumi; K. Miyazaki

2009-01-01T23:59:59.000Z

314

Fuels - Biodiesel  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

* Biodiesel * Biodiesel * Butanol * Ethanol * Hydrogen * Natural Gas * Fischer-Tropsch Batteries Cross-Cutting Assessments Engines GREET Hybrid Electric Vehicles Hydrogen & Fuel Cells Materials Modeling, Simulation & Software Plug-In Hybrid Electric Vehicles PSAT Smart Grid Student Competitions Transportation Research and Analysis Computing Center Working With Argonne Contact TTRDC Clean Diesel Fuels Background Reducing our country's dependence on foreign oil and the rising costs of crude oil are primary reasons for a renewed interest in alternative fuels for the transportation sector. Stringent emissions regulations and public concern about mobile sources of air pollution provide additional incentives to develop fuels that generate fewer emissions, potentially reducing the need for sophisticated, expensive exhaust after-treatment devices.

315

Nuclear Fuels  

Science Journals Connector (OSTI)

The core of a nuclear reactor is composed of a controlled critical configuration of a fissile material, which in strict a sense is the fuel. This fissile material is contained in a matrix, normally a ceramic c...

Rudy J. M. Konings; Thierry Wiss…

2011-01-01T23:59:59.000Z

316

Fuel economizer  

SciTech Connect (OSTI)

A fuel economizer device for use with an internal combustion engine fitted with a carburetor is disclosed. The fuel economizer includes a plate member which is mounted between the carburetor and the intake portion of the intake manifold. The plate member further has at least one aperture formed therein. One tube is inserted through the at least one aperture in the plate member. The one tube extends longitudinally in the passage of the intake manifold from the intake portion toward the exit portion thereof. The one tube concentrates the mixture of fuel and air from the carburetor and conveys the mixture of fuel and air to a point adjacent but spaced away from the inlet port of the internal combustion engine.

Zwierzelewski, V.F.

1984-06-26T23:59:59.000Z

317

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

Ti doping on La{sub 1-x}Sr{sub x}FeO{sub 3-{delta}} (LSF) tends to increase the oxygen equilibration kinetics of LSF in lower oxygen activity environment because of the high valence state of Ti. However, the addition of Ti decreases the total conductivity because the acceptor ([Sr{prime}{sub La}]) is compensated by the donor ([Ti{sub Fe}{sup {sm_bullet}}]) which decreases the carrier concentration. The properties of La{sub 0.2}Sr{sub 0.8}Fe{sub 1-x}Ti{sub x}O{sub 3-{delta}} (LSFT, x = 0.45) have been experimentally and theoretically investigated to elucidate (1) the dependence of oxygen occupancy and electrochemical properties on temperature and oxygen activity by thermogravimetric analysis (TGA) and (2) the electrical conductivity and carrier concentration by Seebeck coefficient and electrical measurements. In the present study, dual phase (La{sub 0.2}Sr{sub 0.8}Fe{sub 0.6}Ti{sub 0.4}O{sub 3-{delta}}/Ce{sub 0.9}Gd{sub 0.1}O{sub 2-{delta}}) membranes have been evaluated for structural properties such as hardness, fracture toughness and flexural strength. The effect of high temperature and slightly reducing atmosphere on the structural properties of the membranes was studied. The flexural strength of the membrane decreases upon exposure to slightly reducing conditions at 1000 C. The as-received and post-fractured membranes were characterized using XRD, SEM and TG-DTA to understand the fracture mechanisms. Changes in structural properties of the composite were sought to be correlated with the physiochemical features of the two-phases. We have reviewed the electrical conductivity data and stoichiometry data for La{sub 0.2}Sr{sub 0.8}Cr{sub 0.2}Fe{sub 0.8}O{sub 3-{delta}} some of which was reported previously. Electrical conductivity data for La{sub 0.2}Sr{sub 0.8}Cr{sub 0.2}Fe{sub 0.8}O{sub 3-{delta}} (LSCrF) were obtained in the temperature range, 752 {approx} 1055 C and in the pO{sub 2} range, 10{sup -18} {approx} 0.5 atm. The slope of the plot of log {sigma} vs. log pO{sub 2} is {approx} 1/5 in the p-type region, pO{sub 2} = 10{sup -5} {approx} 10{sup -1} atm. The pO{sub 2} at which the p-n transition is observed increases with increasing temperature. The activation energy for ionic conduction was estimated to be 0.86 eV from an Arrhenius plot of the minimum conductivity vs. reciprocal temperature. At temperatures below 940 C, a plateau in the conductivity isotherm suggests the presence of a two-phase region. Most likely, phase separation occurs to form a mixture of a perovskite phase and an oxygen vacancy ordered phase related to brownmillerite. Additional data for the oxygen non stoichiometry are presented.

S. Bandopadhyay; T. Nithyanantham

2006-12-31T23:59:59.000Z

318

Oxygen reduction at the platinum/Nafion{reg_sign} interface: Electrode kinetics and mass transport  

SciTech Connect (OSTI)

Research in solid polymer electrolyte fuel cells is gaining momentum because of the prospects of attaining high energy efficiencies and power densities, essential for transportation and space applications. The most advanced solid polymer electrolytes for these fuel cells are the perfluorosulfonate ionomers (PFSIs) such as duPont`s Naflon and the Dow PFSIs. The high oxygen solubility, chemical stability, proton conductivity and permselectivity exhibited by Naflon and the Dow PFSI`s make them ideal candidates as electrolytes for fuel cells. Furthermore, the minimal anion adsorption on electrodes from fluorinated acids enhances oxygen reduction kinetics. The primary objectives of this work were to determine the concentration and diffusion coefficient of oxygen in Naflon, and the electrode kinetic parameters for the reduction of oxygen at the Pt/Nafion interface under totally solid-state conditions. Cyclic voltammetric and potentiostatic transient measurements were made at the Pt/Nafion interface. Slow sweep voltammograms yielded Tafel parameters for oxygen reduction. From the two-section Tafel, plot, the calculated exchange current densities were found to be higher than those obtained at any other Pt/acid interface. From an analysis of the transients, the values of oxygen solubility and diffusion coefficient in Naflon were determined. Electrochemical impedance spectroscopic (EIS) investigations were then used to study oxygen reduction under lower humidfication conditions. EIS clearly permits the discrimination of electrode kinetics, mass transport of O{sub 2} and the electrical characteristics of the membrane. A temperature-dependence study in the range of 30{degrees}C to 80{degrees}C yielded the activation energy for oxygen reduction at the Pt/Naflon interface. The diffusion coefficient of oxygen in Nafion increases with temperature while its solubility decreases. the pressure-dependence of oxygen reduction kinetics shows that the reaction order of oxygen is unity.

Parthasarathy, A.

1992-12-31T23:59:59.000Z

319

Study on Degradation of Solid Oxide Fuel Cell With Pure Ni Anode Zhenjun Jiaoa  

E-Print Network [OSTI]

Study on Degradation of Solid Oxide Fuel Cell With Pure Ni Anode Zhenjun Jiaoa , Naoki Shikazonoa Solid oxide fuel cell (SOFC) has attracted more and more attentions in the last few decades hydrogen as a fuel and pure oxygen as an oxidant. Anode-reference static current method, with a current

Kasagi, Nobuhide

320

Method for producing electricity from a fuel cell having solid-oxide ionic electrolyte  

DOE Patents [OSTI]

Stabilized quadrivalent cation oxide electrolytes are employed in fuel cells at elevated temperatures with a carbon and/or hydrogen containing fuel anode and an oxygen cathode. The fuel cell is operated at elevated temperatures with conductive metallic coatings as electrodes and desirably having the electrolyte surface blackened. Of particular interest as the quadrivalent oxide is zirconia.

Mason, David M. (Los Altos, CA)

1984-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "newable fuels oxygenates" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Growth of Pt nanoparticle for proton-exchange-membrane fuel cells by  

E-Print Network [OSTI]

at anode side of a polymer electrolyte membrane (PEM) fuel cell. With a Pt loading of 25 g-Pt/cm2 , current, PEM fuel cell, Mass specific power density, Electrochemical active surface area, Oxygen reduction PEMFC Growth of Pt nanoparticle for proton-exchange-membrane fuel cells

322

A DC-DC Converter-Based PEM Fuel Cell System Emulator  

E-Print Network [OSTI]

). If hydrogen is produced from clean energy sources, this makes fuel cells an attractive and clean alternative reactor where hydrogen (or reformed gas) and oxygen (or air) are fed at the inlet of the fuel cell stack still impose some drawbacks: the cost of fuel cell system tests are expensive (e.g., hydrogen

Boyer, Edmond

323

Oxygen Release and Oxidation Rates of MgAl2O4-Supported CuO Oxygen Carrier for Chemical-Looping Combustion with Oxygen Uncoupling (CLOU)  

Science Journals Connector (OSTI)

The choice of wood char was made after comparing the oxygen concentration in the reactor’s exit stream, using different solid fuels and taking advantage of the high reactivity of the wood char, compared to other available fuels (e.g., coal or petcoke). ... The required solids inventory in the fuel reactor obtained here is lower than a previously reported investigation for a 40 wt?% CuO on ZrO2 support using petcoke as fuel (120–200 kg MWth–1)(34) and a recent study of continuous operation using a spray-dried 60 wt?% CuO on MgAl2O4 support (235 kg MWth–1 at 960 °C),(22) but is in close agreement with the values obtained by Adánez-Rubio et al.(48) for the spray-dried 60 wt?% CuO on MgAl2O4 support (39 kg MWth–1 at 930 °C). ... data of Mexican petcoke particles by a CuO/ZrO2 oxygen carrier. ...

Mehdi Arjmand; Martin Keller; Henrik Leion; Tobias Mattisson; Anders Lyngfelt

2012-10-03T23:59:59.000Z

324

Estimating Query Difficulty for News Prediction Retrieval Nattiya Kanhabua  

E-Print Network [OSTI]

-genomic society? When can re- newable energy replace fossil fuels? These questions commonly This is a corrected will happen in the eurozone after the financial crisis? How will health care change in the post lives including an energy crisis, the global financial crisis, poli- tics, health care, science

325

use of renewable en-ergy options generally  

E-Print Network [OSTI]

or security risks. Re- newables can thus be used to diversify exist- ing utility resource portfolios electricity (i.e., kWhs) from nuclear and fossil fuel plants appears to solar energy, or bio- mass energy. As a result, most utilities may not purchase wind energy, methods to estimate these costs. Some have shown

Delaware, University of

326

Stabilization of Platinum Nanoparticle Electrocatalysts for Oxygen...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Platinum Nanoparticle Electrocatalysts for Oxygen Reduction Using Poly(diallyldimethylammonium chloride). Stabilization of Platinum Nanoparticle Electrocatalysts for Oxygen...

327

Alternative Fuels Data Center: Alternative Fuel Definition  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Definition to someone by E-mail Definition to someone by E-mail Share Alternative Fuels Data Center: Alternative Fuel Definition on Facebook Tweet about Alternative Fuels Data Center: Alternative Fuel Definition on Twitter Bookmark Alternative Fuels Data Center: Alternative Fuel Definition on Google Bookmark Alternative Fuels Data Center: Alternative Fuel Definition on Delicious Rank Alternative Fuels Data Center: Alternative Fuel Definition on Digg Find More places to share Alternative Fuels Data Center: Alternative Fuel Definition on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Alternative Fuel Definition Alternative fuel is defined as compressed natural gas, propane, ethanol, or any mixture containing 85% or more ethanol (E85) with gasoline or other

328

OXYGEN TRANSPORT CERAMIC MEMBRANES  

SciTech Connect (OSTI)

This is the third quarterly report on oxygen Transport Ceramic Membranes. In the following, the report describes the progress made by our university partners in Tasks 1 through 6, experimental apparatus that was designed and built for various tasks of this project, thermodynamic calculations, where applicable and work planned for the future. (Task 1) Design, fabricate and evaluate ceramic to metal seals based on graded ceramic powder/metal braze joints. (Task 2) Evaluate the effect of defect configuration on ceramic membrane conductivity and long term chemical and structural stability. (Task 3) Determine materials mechanical properties under conditions of high temperatures and reactive atmospheres. (Task 4) Evaluate phase stability and thermal expansion of candidate perovskite membranes and develop techniques to support these materials on porous metal structures. (Task 5) Assess the microstructure of membrane materials to evaluate the effects of vacancy-impurity association, defect clusters, and vacancy-dopant association on the membrane performance and stability. (Task 6) Measure kinetics of oxygen uptake and transport in ceramic membrane materials under commercially relevant conditions using isotope labeling techniques.

Dr. Sukumar Bandopadhyay; Dr. Nagendra Nagabhushana

2000-10-01T23:59:59.000Z

329

OXYGEN ABUNDANCES IN CEPHEIDS  

SciTech Connect (OSTI)

Oxygen abundances in later-type stars, and intermediate-mass stars in particular, are usually determined from the [O I] line at 630.0 nm, and to a lesser extent, from the O I triplet at 615.7 nm. The near-IR triplets at 777.4 nm and 844.6 nm are strong in these stars and generally do not suffer from severe blending with other species. However, these latter two triplets suffer from strong non-local thermodynamic equilibrium (NLTE) effects and thus see limited use in abundance analyses. In this paper, we derive oxygen abundances in a large sample of Cepheids using the near-IR triplets from an NLTE analysis, and compare those abundances to values derived from a local thermodynamic equilibrium (LTE) analysis of the [O I] 630.0 nm line and the O I 615.7 nm triplet as well as LTE abundances for the 777.4 nm triplet. All of these lines suffer from line strength problems making them sensitive to either measurement complications (weak lines) or to line saturation difficulties (strong lines). Upon this realization, the LTE results for the [O I] lines and the O I 615.7 nm triplet are in adequate agreement with the abundance from the NLTE analysis of the near-IR triplets.

Luck, R. E.; Andrievsky, S. M. [Department of Astronomy, Case Western Reserve University, 10900 Euclid Avenue, Cleveland, OH 44106-7215 (United States); Korotin, S. N.; Kovtyukh, V. V., E-mail: luck@fafnir.astr.cwru.edu, E-mail: serkor@skyline.od.ua, E-mail: val@deneb1.odessa.ua, E-mail: scan@deneb1.odessa.ua [Department of Astronomy and Astronomical Observatory, Odessa National University, Isaac Newton Institute of Chile, Odessa Branch, Shevchenko Park, 65014 Odessa (Ukraine)

2013-07-01T23:59:59.000Z

330

Nanostructured catalysts for cathodes of oxygen-hydrogen fuel cells  

Science Journals Connector (OSTI)

Bimetallic catalysts platinum-cobalt, platinum-chromium, and platinum-tungsten, deposited onto highly dispersed carbon black from complex cluster-type compounds of corresponding metals with a 1: 1 atomic ratio...

V. A. Grinberg; T. L. Kulova; N. A. Maiorova…

2007-01-01T23:59:59.000Z

331

Stationary Fuel Cells: Overview of Hydrogen and Fuel Cell Activities...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Stationary Fuel Cells: Overview of Hydrogen and Fuel Cell Activities Stationary Fuel Cells: Overview of Hydrogen and Fuel Cell Activities Presentation covers stationary fuel cells...

332

Fuel Cell Technologies Overview: 2011 Fuel Cell Seminar | Department...  

Broader source: Energy.gov (indexed) [DOE]

Fuel Cell Technologies Overview: 2011 Fuel Cell Seminar Fuel Cell Technologies Overview: 2011 Fuel Cell Seminar Presentation by Sunita Satyapal at the Fuel Cell Seminar on November...

333

Fuel Cell Technologies Overview: 2011 Fuel Cell Seminar | Department...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Overview: 2011 Fuel Cell Seminar Fuel Cell Technologies Overview: 2011 Fuel Cell Seminar Presentation by Sunita Satyapal at the Fuel Cell Seminar on November 1, 2011. Fuel Cell...

334

Fuel Processing Valri Lightner  

E-Print Network [OSTI]

of Hydrogen · Fuel Processors for PEM Fuel Cells Nuvera Fuel Cells, Inc. GE Catalytica ANL PNNL University-Board Fuel Processing Barriers $35/kW Fuel Processor $10/kW Fuel Cell Power Systems $45/kW by 2010 BARRIERS · Fuel processor start-up/ transient operation · Durability · Cost · Emissions and environmental issues

335

Method for converting hydrocarbon fuel into hydrogen gas and carbon dioxide  

DOE Patents [OSTI]

A method for converting hydrocarbon fuel into hydrogen gas and carbon dioxide within a reformer 10 is disclosed. According to the method, a stream including an oxygen-containing gas is directed adjacent to a first vessel 18 and the oxygen-containing gas is heated. A stream including unburned fuel is introduced into the oxygen-containing gas stream to form a mixture including oxygen-containing gas and fuel. The mixture of oxygen-containing gas and unburned fuel is directed tangentially into a partial oxidation reaction zone 24 within the first vessel 18. The mixture of oxygen-containing gas and fuel is further directed through the partial oxidation reaction zone 24 to produce a heated reformate stream including hydrogen gas and carbon monoxide. Steam may also be mixed with the oxygen-containing gas and fuel, and the reformate stream from the partial oxidation reaction zone 24 directed into a steam reforming zone 26. High- and low-temperature shift reaction zones 64,76 may be employed for further fuel processing.

Clawson, Lawrence G. (Dover, MA); Mitchell, William L. (Belmont, MA); Bentley, Jeffrey M. (Westford, MA); Thijssen, Johannes H. J. (Cambridge, MA)

2000-01-01T23:59:59.000Z

336

CRADA Final Report: Ionically Conductive Membranes Oxygen Separation  

SciTech Connect (OSTI)

Scientists at the Lawrence Berkeley National Laboratory (LBNL) in a collaborative effort with Praxair Corporation developed a bench-top oxygen separation unit capable of producing ultra-high purity oxygen from air. The device is based on thin-film electrolyte technology developed at LBNL as part of a solid oxide fuel cell program. The two teams first demonstrated the concept using planar ceramic disks followed by the development of tubular ceramic structures for the bench-top unit. The highly successful CRADA met all technical milestones on time and on budget. Due to the success of this program the industrial partner and the team at LBNL submitted a grant proposal for further development of the unit to the Advanced Technology Program administered by the National Institute of Standar~s. This proposal was selected for funding, and now the two teams are developing a precommercial oxygen separation unit under a 3-year, $6 million dollar program.

Visco, Steven J.

2001-10-29T23:59:59.000Z

337

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. In this report, in situ neutron diffraction was used to characterize the chemical and structural properties of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} (here after as L2SF55T) specimen, which was subject to measurements of neutron diffraction from room temperature to 900 C. It was found that space group of R3c yielded a better refinement than a cubic structure of Pm3m. Oxygen occupancy was nearly 3 in the region from room temperature to 700 C, above which the occupancy decreased due to oxygen loss. Dense OTM bars provided by Praxair were loaded to fracture at varying stress rates. Studies were done at room temperature in air and at 1000 C in a specified environment to evaluate slow crack growth behavior. The X-Ray data and fracture mechanisms points to non-equilibrium decomposition of the LSFCO OTM membrane. The non-equilibrium conditions could probably be due to the nature of the applied stress field (stressing rates) and leads to transition in crystal structures and increased kinetics of decomposition. The formations of a Brownmillerite or Sr2Fe2O5 type structures, which are orthorhombic are attributed to the ordering of oxygen vacancies. The cubic to orthorhombic transitions leads to 2.6% increase in strains and thus residual stresses generated could influence the fracture behavior of the OTM membrane. Continued investigations on the thermodynamic properties (stability and phase-separation behavior) and total conductivity of prototype membrane materials were carried out. The data are needed together with the kinetic information to develop a complete model for the membrane transport. Previously characterization, stoichiometry and conductivity measurements for samples of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} were reported. In this report, measurements of the chemical and thermal expansion as a function of temperature and p{sub O2} are described.

S. Bandopadhyay; N. Nagabhushana; X.-D Zhou; Q. Cai; J. Yang; W.B. Yelon; W.J. James; H.U. Anderson; Alan Jacobson; C.A. Mims

2004-05-01T23:59:59.000Z

338

Reforming of fuel inside fuel cell generator  

DOE Patents [OSTI]

Disclosed is an improved method of reforming a gaseous reformable fuel within a solid oxide fuel cell generator, wherein the solid oxide fuel cell generator has a plurality of individual fuel cells in a refractory container, the fuel cells generating a partially spent fuel stream and a partially spent oxidant stream. The partially spent fuel stream is divided into two streams, spent fuel stream I and spent fuel stream II. Spent fuel stream I is burned with the partially spent oxidant stream inside the refractory container to produce an exhaust stream. The exhaust stream is divided into two streams, exhaust stream I and exhaust stream II, and exhaust stream I is vented. Exhaust stream II is mixed with spent fuel stream II to form a recycle stream. The recycle stream is mixed with the gaseous reformable fuel within the refractory container to form a fuel stream which is supplied to the fuel cells. Also disclosed is an improved apparatus which permits the reforming of a reformable gaseous fuel within such a solid oxide fuel cell generator. The apparatus comprises a mixing chamber within the refractory container, means for diverting a portion of the partially spent fuel stream to the mixing chamber, means for diverting a portion of exhaust gas to the mixing chamber where it is mixed with the portion of the partially spent fuel stream to form a recycle stream, means for injecting the reformable gaseous fuel into the recycle stream, and means for circulating the recycle stream back to the fuel cells.

Grimble, Ralph E. (Finleyville, PA)

1988-01-01T23:59:59.000Z

339

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

motor fuel containing at least 10% alcohol) or alternative fuels whenever feasible and cost effective. DOA must place a list of gasohol and alternative fueling station locations...

340

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

special fuels. Special fuels include compressed and liquefied natural gas, liquefied petroleum gas (propane), hydrogen, and fuel suitable for use in diesel engines. In addition,...

Note: This page contains sample records for the topic "newable fuels oxygenates" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

alternative fuel vehicles (AFVs) capable of operating on natural gas or liquefied petroleum gas (propane), or bi-fuel vehicles capable of operating on conventional fuel or...

342

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Use and Fuel-Efficient Vehicle Requirements State-owned vehicle fleets must implement petroleum displacement plans to increase the use of alternative fuels and fuel-efficient...

343

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

and Special Fuel Definitions The definition of alternative fuel includes liquefied petroleum gas (propane). Special fuel is defined as all combustible gases and liquids that are...

344

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Renewable Fuel Labeling Requirement Biodiesel, biobutanol, and ethanol blend dispensers must be affixed with decals identifying the type of fuel blend. If fuel blends containing...

345

Saving Fuel, Reducing Emissions  

E-Print Network [OSTI]

would in turn lower PHEV fuel costs and make them morestretches from fossil-fuel- powered conventional vehiclesbraking, as do Saving Fuel, Reducing Emissions Making Plug-

Kammen, Daniel M.; Arons, Samuel M.; Lemoine, Derek M.; Hummel, Holmes

2009-01-01T23:59:59.000Z

346

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

and alternative fuel vehicles; promotes the development, sale, distribution, and consumption of alternative fuels; promotes the development and use of alternative fuel vehicles...

347

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

providers to install biofuel fueling facilities. Fueling facilities include storage tanks and fuel pumps dedicated to dispensing E85 and biodiesel blends of 20% (B20). TDOT...

348

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

interest in the qualified property. Renewable fuel is defined as a fuel produced from biomass that is used to replace or reduce conventional fuel use. (Reference Florida Statutes...

349

Alternative Fuel Vehicle Resources  

Broader source: Energy.gov [DOE]

Alternative fuel vehicles use fuel types other than petroleum and include such fuels as electricity, ethanol, biodiesel, natural gas, hydrogen, and propane. Compared to petroleum, these...

350

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Alternative Fuel Grants and Rebates The Arkansas Alternative Fuels Development Program (Program) provides grants to alternative fuel producers, feedstock processors, and...

351

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Fuel Exclusivity Contract Regulation Motor fuel franchise dealers may obtain alternative fuels from a supplier other than a franchise distributor. Any franchise provision that...

352

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Hydrogen Production and Retail Requirements All hydrogen fuel produced and sold in Michigan must meet state fuel quality requirements. Any retailer offering hydrogen fuel for sale...

353

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

that operate using at least 90% alternative fuel. Eligible alternative fuels include electricity, propane, natural gas, or hydrogen fuel. Medium-duty hybrid electric vehicles also...

354

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Fuels Promotion and Information The Center for Alternative Fuels (Center) promotes alternative fuels as viable energy sources in the state. The Center must assess the...

355

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Fuel Definition The following fuels are defined as alternative fuels by the Energy Policy Act (EPAct) of 1992: pure methanol, ethanol, and other alcohols; blends of 85%...

356

Low Carbon Fuel Standards  

E-Print Network [OSTI]

in 1990. These many alternative-fuel initiatives failed tolow-cost, low-carbon alternative fuels would thrive. Theto introduce low-carbon alternative fuels. Former Federal

Sperling, Dan; Yeh, Sonia

2009-01-01T23:59:59.000Z

357

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Alternative Fuels Labeling Requirement Retailers must display ratings on fueling pumps that are consistent with the percentage by volume of the alternative fuel being dispensed....

358

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

is defined as a renewable transportation fuel, transportation fuel additive, heating oil, or jet fuel that meets the definition of either biodiesel or non-ester renewable...

359

BWR oxygen control demonstration program  

SciTech Connect (OSTI)

A number of cracks have occurred recently in certain BWR piping systems. The operating environment associated with oxidizing species such as oxygen and hydrogen peroxide is considered one of the factors in the mechanism of cracking. In April 1976, NWT Corporation was contracted to perform a BWR oxygen control demonstration program. Means for reducing reactor water oxygen and hydrogen peroxide concentrations during startup and shutdown transients were defined and demonstrated at Vermont Yankee and Browns Ferry Unit 3. Results of the demonstrations and an analytical review of impacts of major system variables on oxygen transients are discussed herein.

Pearl, W.L.; Kassen, W.R.; Sawochka, S.G.

1981-05-01T23:59:59.000Z

360

Oxygen to the core  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

1-01 1-01 For immediate release: 01/10/2013 | NR-13-01-01 Oxygen to the core Anne M Stark, LLNL, (925) 422-9799, stark8@llnl.gov Printer-friendly An artist's conception of Earth's inner and outer core. LIVERMORE, Calif. -- An international collaboration including researchers from Lawrence Livermore National Laboratory has discovered that the Earth's core formed under more oxidizing conditions than previously proposed. Through a series of laser-heated diamond anvil cell experiments at high pressure (350,000 to 700,000 atmospheres of pressure) and temperatures (5,120 to 7,460 degrees Fahrenheit), the team demonstrated that the depletion of siderophile (also known as "iron loving") elements can be produced by core formation under more oxidizing conditions than earlier

Note: This page contains sample records for the topic "newable fuels oxygenates" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

OXYGEN TRANSPORT CERAMIC MEMBRANES  

SciTech Connect (OSTI)

This report covers the following tasks: Task 1--Design, fabricate and evaluate ceramic to metal seals based on graded ceramic powder/metal braze joints; Task 2--Evaluate the effect of defect configuration on ceramic membrane conductivity and long term chemical and structural stability; Task 3--Determine materials mechanical properties under conditions of high temperatures and reactive atmospheres; Task 4--Evaluate phase stability and thermal expansion of candidate perovskite membranes and develop techniques to support these materials on porous metal structures; Task 5--Assess the microstructure of membrane materials to evaluate the effects of vacancy-impurity association, defect clusters, and vacancy-dopant association on the membrane performance and stability; and Task 6--Measure kinetics of oxygen uptake and transport in ceramic membrane materials under commercially relevant conditions using isotope labeling techniques.

Dr. Sukumar Bandopadhyay; Dr. Nagendra Nagabhushana

2002-04-01T23:59:59.000Z

362

Alternative Fuels Data Center: Alternative Fuel Vehicle Acquisition and  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Fuel Fuel Vehicle Acquisition and Alternative Fuel Use Requirements to someone by E-mail Share Alternative Fuels Data Center: Alternative Fuel Vehicle Acquisition and Alternative Fuel Use Requirements on Facebook Tweet about Alternative Fuels Data Center: Alternative Fuel Vehicle Acquisition and Alternative Fuel Use Requirements on Twitter Bookmark Alternative Fuels Data Center: Alternative Fuel Vehicle Acquisition and Alternative Fuel Use Requirements on Google Bookmark Alternative Fuels Data Center: Alternative Fuel Vehicle Acquisition and Alternative Fuel Use Requirements on Delicious Rank Alternative Fuels Data Center: Alternative Fuel Vehicle Acquisition and Alternative Fuel Use Requirements on Digg Find More places to share Alternative Fuels Data Center: Alternative

363

Summary report : universal fuel processor.  

SciTech Connect (OSTI)

The United States produces only about 1/3 of the more than 20 million barrels of petroleum that it consumes daily. Oil imports into the country are roughly equivalent to the amount consumed in the transportation sector. Hence the nation in general, and the transportation sector in particular, is vulnerable to supply disruptions and price shocks. The situation is anticipated to worsen as the competition for limited global supplies increases and oil-rich nations become increasingly willing to manipulate the markets for this resource as a means to achieve political ends. The goal of this project was the development and improvement of technologies and the knowledge base necessary to produce and qualify a universal fuel from diverse feedstocks readily available in North America and elsewhere (e.g. petroleum, natural gas, coal, biomass) as a prudent and positive step towards mitigating this vulnerability. Three major focus areas, feedstock transformation, fuel formulation, and fuel characterization, were identified and each was addressed. The specific activities summarized herein were identified in consultation with industry to set the stage for collaboration. Two activities were undertaken in the area of feedstock transformation. The first activity focused on understanding the chemistry and operation of autothermal reforming, with an emphasis on understanding, and therefore preventing, soot formation. The second activity was focused on improving the economics of oxygen production, particularly for smaller operations, by integrating membrane separations with pressure swing adsorption. In the fuel formulation area, the chemistry of converting small molecules readily produced from syngas directly to fuels was examined. Consistent with the advice from industry, this activity avoided working on improving known approaches, giving it an exploratory flavor. Finally, the fuel characterization task focused on providing a direct and quantifiable comparison of diesel fuel and JP-8.

Coker, Eric Nicholas; Rice, Steven F. (Sandia National Laboratories, Livermore, CA); Kemp, Richard Alan; Stewart, Constantine A.; Miller, James Edward; Cornelius, Christopher James; Staiger, Chad Lynn; Pickett, Lyle M. (Sandia National Laboratories, Livermore, CA)

2008-01-01T23:59:59.000Z

364

Novel Reactor Design for Solid Fuel Chemical Looping Combustion  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Novel Reactor Design for Solid Fuel Novel Reactor Design for Solid Fuel Chemical Looping Combustion Opportunity Research is active on the patent pending technology, titled "Apparatus and Method for Solid Fuel Chemical Looping Combustion." This technology is available for licensing and/or further collaborative research from the U.S. Department of Energy's National Energy Technology Laboratory. Overview The removal of CO2 from power plants is challenging because existing methods to separate CO2 from the gas mixture requires a significant fraction of the power plant output. Chemical-looping combustion (CLC) is a novel technology that utilizes a metal oxide oxygen carrier to transport oxygen to the fuel thereby avoiding direct contact between fuel and air. The use of CLC has the advantages of reducing the energy penalty while

365

Preferential Use of an Anode as an Electron Acceptor by an Acidophilic Bacterium in the Presence of Oxygen  

Science Journals Connector (OSTI)

...microbial fuel cell development, in which bacteria...separated from the cathode compartment, generally...of the microbial electrocatalyst (5, 8, 30...for the further development of microbial fuel...oxygen reduction cathodes. Biosens. Bioelectron...cells and their development. Biosens. Bioelectron...

Moustafa Malki; Antonio L. De Lacey; Nuria Rodríguez; Ricardo Amils; Victor M. Fernandez

2008-05-16T23:59:59.000Z

366

Chemical looping combustion of biomass-derived syngas using ceria-supported oxygen carriers  

Science Journals Connector (OSTI)

Abstract Cu, Ni and Fe oxides supported on ceria were investigated for their performance as oxygen carriers during the chemical looping combustion of biomass-derived syngas. A complex gas mixture containing CO, H2, CO2, CH4 and other hydrocarbons was used to simulate the complex fuel gas environment derived from biomass gasification. Results show that the transfer of the stored oxygen into oxidants for the supported Cu and Ni oxides at 800 °C for the combustion of syngas was effective (>85%). The unsupported Cu oxide showed high oxygen carrying capacity but particle sintering was observed at 800 °C. A reaction temperature of 950 °C was required for the supported Fe oxides to transfer the stored oxygen into oxidants effectively. Also, for the complex fuel gas environment, the supported Ni oxide was somewhat effective in reforming CH4 and other light hydrocarbons into CO, which may have benefits for the reduction of tar produced during biomass pyrolysis.

H.B. Huang; L. Aisyah; P.J. Ashman; Y.C. Leung; C.W. Kwong

2013-01-01T23:59:59.000Z

367

Fuel Cells & Alternative Fuels | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Cells & Alternative Fuels Fuel Cells & Alternative Fuels Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and...

368

Evaluation of Fuel Properties of Butanol?Biodiesel?Diesel Blends and Their Impact on Engine Performance and Emissions  

Science Journals Connector (OSTI)

Values of specific fuel consumption of engine when fueled with different blends and pure diesel at different speeds are shown in Figure 4. ... Chandra, R.; Kumar, R. Fuel properties of some stable alcohol?diesel microemulsions for their use in compression ignition engines Energy Fuels 2007, 21, 3410– 3414 ... Liu, B.; Huang, Z.; Miao, H.; Di, Y.; Jiang, D.; Zeng, K. Combustion and emissions of a DI diesel engine fuelled with diesel?oxygenate blends Fuel 2008, 87, 2691– 2697 ...

Rakhi N. Mehta; Mousumi Chakraborty; Pinakeswar Mahanta; Parimal A. Parikh

2010-07-15T23:59:59.000Z

369

Method And Apparatus For Converting Hydrocarbon Fuel Into Hydrogen Gas And Carbon Dioxide  

DOE Patents [OSTI]

A hydrocarbon fuel reforming method is disclosed suitable for producing synthesis hydrogen gas from reactions with hydrocarbons fuels, oxygen, and steam. A first mixture of an oxygen-containing gas and a first fuel is directed into a first tube 108 to produce a first reaction reformate. A second mixture of steam and a second fuel is directed into a second tube 116 annularly disposed about the first tube 108 to produce a second reaction reformate. The first and second reaction reformates are then directed into a reforming zone 144 and subject to a catalytic reforming reaction. In another aspect of the method, a first fuel is combusted with an oxygen-containing gas in a first zone 108 to produce a reformate stream, while a second fuel under steam reforming in a second zone 116. Heat energy from the first zone 108 is transferred to the second zone 116.

Clawson, Lawrence G. (Dover, MA); Mitchell, William L. (Belmont, MA); Bentley, Jeffrey M. (Westford, MA); Thijssen, Johannes H. J. (Cambridge, MA)

2001-03-27T23:59:59.000Z

370

An oxygenating additive for improving the performance and emission characteristics of marine diesel engines  

Science Journals Connector (OSTI)

Diesel engines provide the major power sources for marine transportation and contribute to the prosperity of the worldwide economy. However, the emissions from diesel engines also seriously threaten the environment and are considered one of the major sources of air pollution. The pollutants emitted from marine vessels are confirmed to cause the ecological environmental problems such as the ozone layer destruction, enhancement of the greenhouse effect, and acid rain, etc. Marine diesel engine emissions such as particulate matter and black smoke carry carcinogen components that significantly impact the health of human beings. Investigations on reducing pollutants, in particular particulate matter and nitrogen oxides are critical to human health, welfare and continued prosperity. The addition of an oxygenating agent into fuel oil is one of the possible approaches for reducing this problem because of the obvious fuel oil constituent influences on engine emission characteristics. Ethylene glycol monoacetate was found to be a promising candidate primarily due to its low poison and oxygen-rich composition properties. In this experimental study ethylene glycol monoacetate was mixed with diesel fuel in various proportions to prepare oxygenated diesel fuel. A four-cylinder diesel engine was used to test the engine performance and emission characteristics. The influences of ethylene glycol monoacetate ration to diesel oil, inlet air temperature and humidity parameters on the engine’s speed and torque were considered. The experimental results show that an increase in the inlet air temperature caused an increase in brake specific fuel consumption (BSFC), carbon monoxide, carbon dioxide emission, and exhaust gas temperature, while decreasing the excess air, oxygen and nitrogen oxide emission concentrations. Increasing the inlet air humidity increased the carbon monoxide concentration while the decreased excess air, oxygen and nitrogen oxide emission concentrations. In addition, increasing ethylene glycol monoacetate ratio in the diesel fuel caused an increase in the BSFC while the excess air and oxygen emission concentrations decreased.

C.-Y. Lin; J.-C. Huang

2003-01-01T23:59:59.000Z

371

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Diesel Fuel Blend Tax Exemption The biodiesel or ethanol portion of blended fuel containing taxable diesel is exempt from the diesel fuel tax. The biodiesel or ethanol fuel blend...

372

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

fuels include liquid non-petroleum based fuel that can be placed in motor vehicle fuel tanks and used to operate on-road vehicles, including all forms of fuel commonly or...

373

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

fuel blends of at least 20% biodiesel fuel or that mix fuel from separate storage tanks and allow the user to select the percentage of renewable fuel. The maximum credit...

374

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

License Alternative fuel providers, bulk users, and retailers, or any person who fuels an alternative fuel vehicle from a private source that does not pay the alternative fuels tax...

375

Investigation of a Canadian Ilmenite as an Oxygen Carrier for Chemical Looping Combustion  

Science Journals Connector (OSTI)

CLC uses an oxygen carrier (OC), usually a metal oxide, to provide oxygen for combusting fuel without the presence of nitrogen from air. ... Chemical-Looping Combustion with NiO and Fe2O3 in a Thermobalance and Circulating Fluidized Bed Reactor with Double Loops ... Application of Fe2O3-Al2O3 Composite Particles as Solid Looping Material of the Chemical-Loop Combustor ...

Fang Liu; Yi Zhang; Liangyong Chen; Dali Qian; James K. Neathery; Saito Kozo; Kunlei Liu

2013-09-23T23:59:59.000Z

376

Alternative Fuels Data Center: Alternative Fuel Vehicle (AFV) Acquisition,  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Fuel Fuel Vehicle (AFV) Acquisition, Fuel Use, and Emissions Reductions Requirements to someone by E-mail Share Alternative Fuels Data Center: Alternative Fuel Vehicle (AFV) Acquisition, Fuel Use, and Emissions Reductions Requirements on Facebook Tweet about Alternative Fuels Data Center: Alternative Fuel Vehicle (AFV) Acquisition, Fuel Use, and Emissions Reductions Requirements on Twitter Bookmark Alternative Fuels Data Center: Alternative Fuel Vehicle (AFV) Acquisition, Fuel Use, and Emissions Reductions Requirements on Google Bookmark Alternative Fuels Data Center: Alternative Fuel Vehicle (AFV) Acquisition, Fuel Use, and Emissions Reductions Requirements on Delicious Rank Alternative Fuels Data Center: Alternative Fuel Vehicle (AFV) Acquisition, Fuel Use, and Emissions Reductions Requirements on Digg

377

Fuel reforming for fuel cell application.  

E-Print Network [OSTI]

??Fossil fuels, such as natural gas, petroleum, and coal are currently the primary source of energy that drives the world economy. However, fossil fuel is… (more)

Hung, Tak Cheong

2006-01-01T23:59:59.000Z

378

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. In this report, Moessbauer spectroscopy was used to study the local environmentals of LSFT with various level of oxygen deficiency. Ionic valence state, magnetic interaction and influence of Ti on superexchange are discussed Stable crack growth studies on Dense OTM bars provided by Praxair were done at elevated temperature, pressure and elevated conditions. Post-fracture X-ray data of the OTM fractured at 1000 C in environment were refined by FullProf code and results indicate a distortion of the parent cubic perovskite to orthorhombic structure with reduced symmetry. TGA-DTA studies on the post-fracture samples also indicated residual effect arising from the thermal and stress history of the samples. An electrochemical cell has been designed and built for measurements of the Seebeck coefficient as a function of temperature and pressure. The initial measurements on La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} are reported. Neutron diffraction measurements of the same composition are in agreement with both the stoichiometry and the kinetic behavior observed in coulometric titration measurements. A series of isotope transients under air separation mode (small gradient) were completed on the membrane of LSCrF-2828 at 900 C. Low pO{sub 2} atmospheres based on with CO-CO{sub 2} mixtures have also been admitted to the delivery side of the LSCrF-2828 membrane to produce the gradients which exist under syngas generation conditions. The COCO{sub 2} mixtures have normal isotopic {sup 18}O abundances. The evolution of {sup 18}O on the delivery side in these experiments after an {sup 18}O pulse on the air side reveals a wealth of information about the oxygen transport processes.

S. Bandopadhyay; N. Nagabhushana; X.-D Zhou; Q. Cai; J. Yang; W.B. Yelon; W.J. James; H.U. Anderson; Alan Jacobson; C.A. Mims

2004-10-01T23:59:59.000Z

379

Process for alternately steam reforming sulfur containing hydrocarbons that vary in oxygen content  

SciTech Connect (OSTI)

In the hydrotreating and steam reforming of an oxygen and sulfur bearing hydrocarbon fuel, the oxygen is first removed in an oxidizer containing a bed of platinum catalyst, the inlet temperature being well below 1000/sup 0/F and preferably on the order of 300/sup 0/F. The sulfur in the fuel does not harm the oxidizer catalyst and may be removed downstream by known hydrodesulfurization techniques prior to reforming. A process is described for removing oxygen from an oxygen and sulfur bearing hydrocarbon fuel, such as peak shared natural gas, upstream in the process so that sulfur can be removed later. The fuel and some hydrogen are introduced into an oxidizer at a temperature of 350/sup 0/F or less down to the minimum ignition temperature. The oxidizer consists of a platinum bed catalyst which catalyzes the oxidation of the oxygen to water with accompanying heat release to raise the exit gas temperature to less than 650/sup 0/F. The temperature desorbs the sulfur from the catalyst, and the exit gases are passed downstream to nickel subsulfide or molybdenum desfulfide catalysts where the hydrosulfurization process takes place. (BLM)

Lesieur, R.R.; Setzer, H.J.; Hawkins, J.R.

1980-01-01T23:59:59.000Z

380

MTBE, Oxygenates, and Motor Gasoline  

Gasoline and Diesel Fuel Update (EIA)

MTBE, Oxygenates, and MTBE, Oxygenates, and Motor Gasoline Contents * Introduction * Federal gasoline product quality regulations * What are oxygenates? * Who gets gasoline with oxygenates? * Which areas get MTBE? * How much has been invested in MTBE production capacity? * What does new Ethanol capacity cost? * What would an MTBE ban cost? * On-line information resources * Endnotes * Summary of revisions to this analysis Introduction The blending of methyl tertiary butyl ether (MTBE) into motor gasoline has increased dramatically since it was first produced 20 years ago. MTBE usage grew in the early 1980's in response to octane demand resulting initially from the phaseout of lead from gasoline and later from rising demand for premium gasoline. The oxygenated gasoline program stimulated an

Note: This page contains sample records for the topic "newable fuels oxygenates" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Plants and Night Oxygen Production  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Plants and Night Oxygen Production Plants and Night Oxygen Production Name: Ashar Status: other Grade: other Location: Outside U.S. Country: India Date: Winter 2011-2012 Question: I would like to know if there are any plants which produces oxygen at night (without photosynthesis). I was told by a friend that Holy Basil (Ocimum tenuiflorum) produces oxygen even at night and I'm not convinced. I would like to get confirmation from experts. Replies: Some plants (particularly those of dry regions, e.g., deserts) only open their stomates at night to avoid drying out to intake CO2 (and output O2) (CAM photosynthesis) http://en.wikipedia.org/wiki/Crassulacean_acid_metabolism Sincerely, Anthony R. Brach, PhD Missouri Botanical Garden Bringing oxygen producing plants into your home is a way to mimic the healthy lifestyle factors of longevity in humans from the longest lived cultures.

382

Oxygen detection using evanescent fields  

DOE Patents [OSTI]

An apparatus and method for the detection of oxygen using optical fiber based evanescent light absorption. Methylene blue was immobilized using a sol-gel process on a portion of the exterior surface of an optical fiber for which the cladding has been removed, thereby forming an optical oxygen sensor. When light is directed through the optical fiber, transmitted light intensity varies as a result of changes in the absorption of evanescent light by the methylene blue in response to the oxygen concentration to which the sensor is exposed. The sensor was found to have a linear response to oxygen concentration on a semi-logarithmic scale within the oxygen concentration range between 0.6% and 20.9%, a response time and a recovery time of about 3 s, ant to exhibit good reversibility and repeatability. An increase in temperature from 21.degree. C. to 35.degree. C. does not affect the net absorption of the sensor.

Duan, Yixiang (Los Alamos, NM); Cao, Weenqing (Los Alamos, NM)

2007-08-28T23:59:59.000Z

383

Unique Configuration of a Nitrogen-Doped Graphene Nanoribbon: Potential Applications to Semiconductor and Hydrogen Fuel Cell  

Science Journals Connector (OSTI)

Unique Configuration of a Nitrogen-Doped Graphene Nanoribbon: Potential Applications to Semiconductor and Hydrogen Fuel Cell ... Further examination on oxygen adsorption at NTSG reveals high electrocatalytic activity of NTSG in oxygen reduction reaction, indicating that this nitrogen-doped graphene material could be used as a potential catalyst for hydrogen fuel cells. ... (48) One recent theoretical work has also disclosed that the nitrogen-doped fullerene could be used as a potential catalyst for hydrogen fuel cells. ...

Hong Zheng; Jia-jia Zheng; Ling He; Xiang Zhao

2014-09-22T23:59:59.000Z

384

Mass, energy, and exergy balance analysis of chemical looping with oxygen uncoupling (CLOU) process  

Science Journals Connector (OSTI)

Abstract Chemical looping with oxygen uncoupling (CLOU) is a promising concept for efficient combustion of solid fuels with an inherent capture of the greenhouse gas CO 2 . This paper presents a CLOU process scheme with stoichiometric mass, energy, and exergy balances. A CLOU reactor system using medium volatile bituminous coal as fuel and silica-supported CuO as an oxygen carrier is analyzed. The analysis includes the estimation of various design and operational parameters, thermal considerations, and evaluation of the overall performance. The operation of a reactor system of two interacting circulating fluidized beds (CFBs) is greatly influenced by the hydrodynamics. For the CuO oxygen carrier, the hydrodynamic operating range appeared feasible considering the maximum solid circulation rates in current CFB boilers. Depending upon the reactor temperatures, oxygen carrier inventories of 400–680 kg/MW in the system were found necessary for stoichiometric combustion of the fuel. The temperature difference between the reactors should not exceed 50 °C, as otherwise, problems may arise with the heat balance. Exergetic efficiencies in the range of 63–70% were obtained for different combinations of relevant design parameters. It is evident that the possible operating conditions in the system are closely related to the properties of the chosen oxygen carrier. However, the calculation procedure and design criteria presented here are applicable to any oxygen carrier to be used in the process.

Petteri Peltola; Tero Tynjälä; Jouni Ritvanen; Timo Hyppänen

2014-01-01T23:59:59.000Z

385

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and initial studies on newer composition of Ti doped LSF. Dense OTM bars provided by Praxair were loaded to fracture at varying stress rates. Studies were done at room temperature in air and at 1000 C in a specified environment to evaluate slow crack growth behavior. In addition, studies were also begun to obtain reliable estimates of fracture toughness and stable crack growth in specific environments. Newer composition of Ti doped LSF membranes were characterized by neutron diffraction analysis. Quench studies indicated an apparent correlation between the unit cell volume and oxygen occupancy. The studies however, indicated an anomaly of increasing Fe/Ti ratio with change in heat treatment. Ti doped LSF was also characterized for stoichiometry as a function of temp and pO{sub 2}. The non stoichiometry parameter {delta} was observed to increase almost linearly on lowering pO{sub 2} until a ideal stoichiometric composition of {delta} = 0.175 was approached.

S. Bandopadhyay; N. Nagabhushana; X.-D Zhou; W.B. Yelon; H.U. Anderson; Alan Jacobson; C.A. Mims

2004-02-01T23:59:59.000Z

386

Low Oxygen Environments in Chesapeake Bay  

E-Print Network [OSTI]

Low Oxygen Environments in Chesapeake Bay Jeremy Testa Chesapeake Biological Laboratory University of Maryland Center for Environmental Science Why we care about low oxygen? What causes low oxygen? Where and When does Chesapeake Bay lose oxygen? #12;#12;Hypoxia and Chesapeake Animals Low dissolved oxygen

Boynton, Walter R.

387

Turing Water into Hydrogen Fuel  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Turning Water into Turning Water into Hydrogen Fuel Turning Water into Hydrogen Fuel New method creates highly reactive catalytic surface, packed with hydroxyl species May 15, 2012 | Tags: Franklin, Materials Science NERSC Contact: Linda Vu, lvu@lbl.gov, +1 510 495 2402 PNNL Contacts: Loel Kathmann, Loel.Kathmann@pnnl.gov, +1 509 371 6068 Artwork from this catalysis research graced the cover of Physical Chemistry Chemical Physics. Image reproduced by permission of Dr Igor Lyubinetsky and the PCCP Owner Societies from Phys. Chem. Chem. Phys. 2012. Build a surface of titanium and oxygen atoms arranged just so, coat with water, and add sunshine. What do you get? In theory, energy-rich hydrogen produced by photolysis-a process by which water molecules placed on a catalytic surface and exposed to sunlight (electromagnetic radiation) are

388

Fuel cell integrated with steam reformer  

SciTech Connect (OSTI)

A process is described of providing a continuous supply of hydrogen fuel to a fuel cell system. The system comprises a heat exchanger, a burner, a catalytic reactor containing a catalyst bed for catalyzing the production of hydrogen from a gaseous mixture of water and methanol and a fuel cell comprised of a fuel electrode, an oxygen electrode and an electrolyte disposed therebetween. The process comprises: passing a gaseous mixture consisting essentially of water and methanol to the heat exchanger to heat the mixture to a superheated state, the temperature and composition of the superheated mixture being sufficient to supply at least about 90% of the heat required for reforming the methanol contained in the mixture by condensation.

Beshty, B.S.; Whelan, J.A.

1987-06-02T23:59:59.000Z

389

Cover and startup gas supply system for solid oxide fuel cell generator  

DOE Patents [OSTI]

A cover and startup gas supply system for a solid oxide fuel cell power generator is disclosed. Hydrocarbon fuel, such as natural gas or diesel fuel, and oxygen-containing gas are supplied to a burner. Combustion gas exiting the burner is cooled prior to delivery to the solid oxide fuel cell. The system mixes the combusted hydrocarbon fuel constituents with hydrogen which is preferably stored in solid form to obtain a non-explosive gas mixture. The system may be used to provide both non-explosive cover gas and hydrogen-rich startup gas to the fuel cell.

Singh, Prabhakar (Export, PA); George, Raymond A. (Pittsburgh, PA)

1999-01-01T23:59:59.000Z

390

Cover and startup gas supply system for solid oxide fuel cell generator  

DOE Patents [OSTI]

A cover and startup gas supply system for a solid oxide fuel cell power generator is disclosed. Hydrocarbon fuel, such as natural gas or diesel fuel, and oxygen-containing gas are supplied to a burner. Combustion gas exiting the burner is cooled prior to delivery to the solid oxide fuel cell. The system mixes the combusted hydrocarbon fuel constituents with hydrogen which is preferably stored in solid form to obtain a non-explosive gas mixture. The system may be used to provide both non-explosive cover gas and hydrogen-rich startup gas to the fuel cell. 4 figs.

Singh, P.; George, R.A.

1999-07-27T23:59:59.000Z

391

Fuel mixture stratification as a method for improving homogeneous charge compression ignition engine operation  

DOE Patents [OSTI]

A method for slowing the heat-release rate in homogeneous charge compression ignition ("HCCI") engines that allows operation without excessive knock at higher engine loads than are possible with conventional HCCI. This method comprises injecting a fuel charge in a manner that creates a stratified fuel charge in the engine cylinder to provide a range of fuel concentrations in the in-cylinder gases (typically with enough oxygen for complete combustion) using a fuel with two-stage ignition fuel having appropriate cool-flame chemistry so that regions of different fuel concentrations autoignite sequentially.

Dec, John E. (Livermore, CA); Sjoberg, Carl-Magnus G. (Livermore, CA)

2006-10-31T23:59:59.000Z

392

Degradation of solid oxide fuel cell metallic interconnects in fuels containing sulfur  

SciTech Connect (OSTI)

Hydrogen is the main fuel for all types of fuel cells except direct methanol fuel cells. Hydrogen can be generated from all manner of fossil fuels, including coal, natural gas, diesel, gasoline, other hydrocarbons, and oxygenates (e.g., methanol, ethanol, butanol, etc.). Impurities in the fuel can cause significant performance problems and sulfur, in particular, can decrease the cell performance of fuel cells, including solid oxide fuel cells (SOFC). In the SOFC, the high (800-1000°C) operating temperature yields advantages (e.g., internal fuel reforming) and disadvantages (e.g., material selection and degradation problems). Significant progress in reducing the operating temperature of the SOFC from ~1000 ºC to ~750 ºC may allow less expensive metallic materials to be used for interconnects and as balance of plant (BOP) materials. This paper provides insight on the material performance of nickel, ferritic steels, and nickel-based alloys in fuels containing sulfur, primarily in the form of H2S, and seeks to quantify the extent of possible degradation due to sulfur in the gas stream.

Ziomek-Moroz, M.; Hawk, Jeffrey A.

2005-01-01T23:59:59.000Z

393

Proton Conductor based Solid Oxide Fuel Cells Ceramatec, Inc., Salt Lake City, UT 84119  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

based Solid Oxide Fuel Cells based Solid Oxide Fuel Cells Ceramatec, Inc., Salt Lake City, UT 84119 S. (Elango) Elangovan, Joseph Hartvigsen, Insoo Bay, and Feng Zhao High efficiency operation is one of the primary attractions to use solid oxide fuel cells as the energy conversion device. High efficiency requires maximizing of the product of operating voltage and fuel utilization. The maximum possible operating voltage however is limited by the Nernst potential near the fuel exhaust. In oxygen conducting electrolyte based fuel cells (O-SOFC) as the fuel utilization increases, the Nernst potential continues to decrease with the dilution of fuel by the reaction products. In contrast, in a proton conducting electrolyte based fuel cell (P-SOFC) the reaction product is formed on the cathode side allowing for high operating voltage at high fuel

394

Frostbite Theater - Liquid Oxygen vs. Liquid Nitrogen - Liquid Oxygen and  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Cells vs. Liquid Nitrogen! Cells vs. Liquid Nitrogen! Previous Video (Cells vs. Liquid Nitrogen!) Frostbite Theater Main Index Next Video (Paramagnetism) Paramagnetism Liquid Oxygen and Fire! What happens when nitrogen and oxygen are exposed to fire? [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: And this is a test tube of liquid nitrogen! Steve: And this is a test tube of liquid oxygen! Joanna: Let's see what happens when nitrogen and oxygen are exposed to fire. Steve: Fire?! Joanna: Yeah! Steve: Really?! Joanna: Why not! Steve: Okay! Joanna: As nitrogen boils, it changes into nitrogen gas. Because it's so cold, it's denser than the air in the room. The test tube fills up with

395

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. In the current research, the electrical conductivity and Seebeck coefficient were measured as a function of temperature in air. Based on these measurements, the charge carrier concentration, net acceptor dopant concentration, activation energy of conduction and mobility were estimated. The studies on the fracture toughness of the LSFT and dual phase membranes at room temperature have been completed and reported previously. The membranes that are exposed to high temperatures at an inert and a reactive atmosphere undergo many structural and chemical changes which affects the mechanical properties. To study the effect of temperature on the membranes when exposed to an inert environment, the membranes (LAFT and Dual phase) were heat treated at 1000 C in air and N{sub 2} atmosphere and hardness and fracture toughness of the membranes were studied after the treatment. The indentation method was used to find the fracture toughness and the effect of the heat treatment on the mechanical properties of the membranes. Further results on the investigation of the origin of the slow kinetics on reduction of ferrites have been obtained. The slow kinetics appears to be related to a non-equilibrium reduction pathway that initially results in the formation of iron particles. At long times, equilibrium can be reestablished with recovery of the perovskite phase. 2-D modeling of oxygen movement has been undertaken in order to fit isotope data. The model will serve to study ''frozen'' profiles in patterned or composite membranes.

S. Bandopadhyay; T. Nithyanantham; X.-D Zhou; Y-W. Sin; H.U. Anderson; Alan Jacobson; C.A. Mims

2005-11-01T23:59:59.000Z

396

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

In the present quarter, experiments are presented on ceramic/metal interactions of Zirconia/ Ni-B-Si system and with a thin Ti coating deposited on zirconia surface. Existing facilities were modified for evaluation of environmental assisted slow crack growth and creep in flexural mode. Processing of perovskites of LSC, LSF and LSCF composition were continued for evaluation of mechanical properties as a function of environment. These studies in parallel to those on the LSFCO composition is expect to yield important information on questions such as the role of cation segregation and the stability of the perovskite structure on crack initiation vs. crack growth. Studies have been continued on the La{sub 1-x}Sr{sub x}FeO{sub 3-d} composition using neutron diffraction and TGA studies. A transition from p-type to n-type of conductor was observed at relative low pO{sub 2}, at which the majority carriers changed from the holes to electrons because of the valence state decreases in Fe due to the further loss of oxygen. Investigation on the thermodynamic properties of the membrane materials are continued to develop a complete model for the membrane transport. Data obtained at 850 C show that the stoichiometry in La{sub 0.2}Sr{sub 0.8}Fe{sub 0.8}Cr{sub 0.2}O{sub 3-x} vary from {approx}2.85 to 2.6 over the pressure range studied. From the stoichiometry a lower limit of 2.6 corresponding to the reduction of all Fe{sup 4+} to Fe{sup 3+} and no reduction of Cr{sup 3+} is expected.

S. Bandopadhyay; N. Nagabhushana

2003-08-07T23:59:59.000Z

397

Coal based fuels, fuel systems and alternative fuels  

SciTech Connect (OSTI)

The introduction of coal based fuel systems such as coal/air and coal water mixtures was an attempt to minimize the use of heavy fuel oils in large scale power generation processes. This need was based on forecasts of fuel reserves and future pricing of fuel oils, therefore economic considerations predominated over environmental benefits, if any, which could result from widespread use of these fuels. Coal continued as the major fuel used in the power generation industry and combustion systems were developed to minimize gaseous emissions, such as NOx. Increasing availability of natural gas led to consideration of its use in combination with coal in fuel systems involving combined cycle or topping cycle operations. Dual fuel coal natural gas operations also offered the possibility of improved performance in comparison to 100% coal based fuel systems. Economic considerations have more recently looked at emulsification of heavy residual liquid fuels for consumption in power generation boiler and Orimulsion has emerged as a prime example of this alternative fuel technology. The paper will discuss some aspects of the burner technology related to the application of these various coal based fuels, fuel systems and alternative fuels in the power generation industry.

Allen, J.W.; Beal, P.R.

1998-07-01T23:59:59.000Z

398

Coal based fuels, fuel systems and alternative fuels  

SciTech Connect (OSTI)

The introduction of coal based fuel systems such as coal/air and coal water mixtures was an attempt to minimise the use of heavy fuel oils in large scale power generation processes. This need was based on forecasts of fuel reserves and future pricing of fuel oils, therefore economic considerations predominated over environmental benefits, if any, which could result from widespread use of these fuels. Coal continued as the major fuel used in the power generation industry and combustion systems were developed to minimise gaseous emissions, such as NO{sub x}. Increasing availability of natural gas led to consideration of its use in combination with coal in fuel systems involving combined cycle or topping cycle operations. Dual fuel coal natural gas operations also offered the possibility of improved performance in comparison to 100% coal based fuel systems. Economic considerations have more recently looked at emulsification of heavy residual liquid fuels for consumption in power generation boiler and Orimulsion has emerged as a prime example of this alternative fuel technology. The next sections of the paper will discuss some aspects of the burner technology related to the application of these various coal based fuels, fuel systems and alternative fuels in the power generation industry.

Allen, J.W.; Beal, P.R. [ABB Combustion Services Limited, Derby (United Kingdom)

1998-04-01T23:59:59.000Z

399

CONTROL-ORIENTED MODELING OF A SOLID-OXIDE FUEL CELL STACK USING AN LPV MODEL STRUCTURE  

E-Print Network [OSTI]

CONTROL-ORIENTED MODELING OF A SOLID-OXIDE FUEL CELL STACK USING AN LPV MODEL STRUCTURE Borhan M dynamic model of a solid oxide fuel cell stack. Using a detailed physical model as a starting point, we (usually air) on the cathode side. Solid-oxide fuel cells (SOFCs) utilize a ceramic oxygen-ion conducting

Sanandaji, Borhan M.

400

Oxygen transfer in the implant environment  

E-Print Network [OSTI]

Temperature dependence of oxygen diffusion and consumptionRN. Influence of temperature on oxygen diffusion in hamster341-347, 1988. Cox ME. Oxygen Diffusion in Poly(dimethyl

Goor, Jared Braden

2007-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "newable fuels oxygenates" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

OXYGEN DIFFUSION IN UO2-x  

E-Print Network [OSTI]

~ K.C. K:i.m, "Oxygen Diffusion in Hypostoichiometricsystem for enriching uo 2 in oxygen-18 or for stoichiometry+nal of Nuclear Materials OXYGEN DIFFUSION IN U0 2 _:x K.C.

Kim, K.C.

2013-01-01T23:59:59.000Z

402

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Tools Tools Printable Version Share this resource Send a link to Alternative Fuels Data Center to someone by E-mail Share Alternative Fuels Data Center on Facebook Tweet about Alternative Fuels Data Center on Twitter Bookmark Alternative Fuels Data Center on Google Bookmark Alternative Fuels Data Center on Delicious Rank Alternative Fuels Data Center on Digg Find More places to share Alternative Fuels Data Center on AddThis.com... Fuel Properties Search Fuel Properties Comparison Create a custom chart comparing fuel properties and characteristics for multiple fuels. Select the fuel and properties of interest. Select Fuels Clear all All Fuels Gasoline Diesel (No. 2) Biodiesel Compressed Natural Gas (CNG) Electricity Ethanol Hydrogen Liquefied Natural Gas (LNG) Propane (LPG)

403

Fuel cell generating plant  

SciTech Connect (OSTI)

This paper discusses a fuel cell generating plant. It comprises a compressed fuel supply; a fuel cell system including fuel conditioning apparatus and fuel cells; a main fuel conduit for conveying fuel from the fuel supply to the fuel cell system; a turbo compressor having a turbine receiving exhaust products from the fuel cell system and a compressor for compressing air; a main air conduit for conveying air from the compressor to the fuel cell system; an auxiliary burner having a primary burner and a pilot; an auxiliary air conduit for conveying air from the compressed fuel supply to the auxiliary burner; an auxiliary exhaust conduit for conveying exhaust products from the auxiliary burner to the turbine; a check valve located between the fuel supply and the pilot; and a gas accumulator in the auxiliary fuel conduit located between the check valve and the pilot.

Sanderson, R.A.

1990-11-27T23:59:59.000Z

404

PRIMARY RESEARCH PAPER Water column oxygen demand and sediment oxygen flux  

E-Print Network [OSTI]

PRIMARY RESEARCH PAPER Water column oxygen demand and sediment oxygen flux: patterns of oxygen dissolved oxygen (DO) levels often occur during summer in tidal creeks along the southeastern coast of the USA. We analyzed rates of oxygen loss as water-column biochemical oxygen demand (BOD5) and sediment

Mallin, Michael

405

Power Management for Alleviation of the Impact on PEM Fuel Cell due to Load Fluctuation  

Science Journals Connector (OSTI)

Transient impact on fuel cell system due to stack current fluctuation sometimes causes severe degradation of some performances such as voltage variation, oxygen starvation, anode/cathode pressure disturbance, membrane dryout and voltage reversal. As ...

Guidong Liu; Wensheng Yu; Zhishou Tu

2006-10-01T23:59:59.000Z

406

Development of thin CsHSO4 membrane electrode assemblies for electrolysis and fuel cell applications.  

E-Print Network [OSTI]

??In this work the use of the solid acid CsHSO4 as an electrolyte in a hydrogen/oxygen fuel cell or the disassociation of water into hydrogen… (more)

Ecklund-Mitchell, Lars E

2008-01-01T23:59:59.000Z

407

DEVELOPMENT OF FUEL AND VALUE-ADDED CHEMICALS FROM PYROLYSIS OF WOOD/WASTE PLASTIC MIXTURE.  

E-Print Network [OSTI]

??Highly oxygenated compounds in bio-oil produce negative properties that have hampered fuel development. Copyrolysis with plastics has increased hydrogen content in past research. Py-GC/MS analyses… (more)

Bhattacharya, Priyanka

2008-01-01T23:59:59.000Z

408

Thermochemical conversion of fuels into hydrogen-containing gas using recuperative heat of internal combustion engines  

Science Journals Connector (OSTI)

The problem of the thermochemical recuperation of heat from the exhaust gases of internal combustion engines (ICEs) as a method of ... the steam conversion of oxygen-containing fuels into syngas were developed, a...

V. A. Kirillov; A. B. Shigarov; N. A. Kuzin…

2013-09-01T23:59:59.000Z

409

Power from marine sediment fuel cells: the influence of anode material  

Science Journals Connector (OSTI)

An abundant supply of fuel is available in marine sediments, in the form of oxidisable organic...?3.... Micro-organisms limited by oxygen supplied by overlying sea water can create potential differences of up to ...

K. Scott; I. Cotlarciuc; D. Hall; J. B. Lakeman…

2008-09-01T23:59:59.000Z

410

Pattern recognition monitoring of PEM fuel cell  

DOE Patents [OSTI]

The CO-concentration in the H.sub.2 feed stream to a PEM fuel cell stack is monitored by measuring current and voltage behavior patterns from an auxiliary cell attached to the end of the stack. The auxiliary cell is connected to the same oxygen and hydrogen feed manifolds that supply the stack, and discharges through a constant load. Pattern recognition software compares the current and voltage patterns from the auxiliary cell to current and voltage signature determined from a reference cell similar to the auxiliary cell and operated under controlled conditions over a wide range of CO-concentrations in the H.sub.2 fuel stream.

Meltser, Mark Alexander (Pittsford, NY)

1999-01-01T23:59:59.000Z

411

Pattern recognition monitoring of PEM fuel cell  

DOE Patents [OSTI]

The CO-concentration in the H{sub 2} feed stream to a PEM fuel cell stack is monitored by measuring current and voltage behavior patterns from an auxiliary cell attached to the end of the stack. The auxiliary cell is connected to the same oxygen and hydrogen feed manifolds that supply the stack, and discharges through a constant load. Pattern recognition software compares the current and voltage patterns from the auxiliary cell to current and voltage signature determined from a reference cell similar to the auxiliary cell and operated under controlled conditions over a wide range of CO-concentrations in the H{sub 2} fuel stream. 4 figs.

Meltser, M.A.

1999-08-31T23:59:59.000Z

412

LMFBR fuel component costs  

SciTech Connect (OSTI)

A significant portion of the cost of fabricating LMFBR fuels is in the non-fuel components such as fuel pin cladding, fuel assembly ducts and end fittings. The contribution of these to fuel fabrication costs, based on FFTF experience and extrapolated to large LMFBR fuel loadings, is discussed. The extrapolation considers the expected effects of LMFBR development programs in progress on non-fuel component costs.

Epperson, E.M.; Borisch, R.R.; Rice, L.H.

1981-10-29T23:59:59.000Z

413

9, 140, 2009 Oxygenated organic  

E-Print Network [OSTI]

resulted in three fossil fuel combustion type factors, one biomass burning factor, and one mixed main factors representing soot, secondary, and biomass burning type spectra. PMF of FTIR spectra15 or processed factor. The fossil fuel combustion type factors were found to have the largest contributions to OM

Russell, Lynn

414

Alternative Fuels Data Center: Flexible Fuel Vehicle Conversions  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Conversions to someone by E-mail Share Alternative Fuels Data Center: Flexible Fuel Vehicle Conversions on Facebook Tweet about Alternative Fuels Data Center: Flexible Fuel Vehicle...

415

Vehicle Certification Test Fuel and Ethanol Flex Fuel Quality...  

Broader source: Energy.gov (indexed) [DOE]

Vehicle Certification Test Fuel and Ethanol Flex Fuel Quality Vehicle Certification Test Fuel and Ethanol Flex Fuel Quality Breakout Session 2: Frontiers and Horizons Session 2-B:...

416

Texas Hydrogen Highway - Fuel Cell Hybrid Bus and Fueling Infrastructu...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Texas Hydrogen Highway - Fuel Cell Hybrid Bus and Fueling Infrastructure Technology Showcase Texas Hydrogen Highway - Fuel Cell Hybrid Bus and Fueling Infrastructure Technology...

417

Light Duty Fuel Cell Electric Vehicle Hydrogen Fueling Protocol...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Light Duty Fuel Cell Electric Vehicle Hydrogen Fueling Protocol Light Duty Fuel Cell Electric Vehicle Hydrogen Fueling Protocol Download the webinar slides from the U.S. Department...

418

Hydrogen and Fuel Cell Technologies Update: 2010 Fuel Cell Seminar...  

Broader source: Energy.gov (indexed) [DOE]

Hydrogen and Fuel Cell Technologies Update: 2010 Fuel Cell Seminar and Exposition Hydrogen and Fuel Cell Technologies Update: 2010 Fuel Cell Seminar and Exposition Presentation by...

419

Flexible Fuel Vehicles: Providing a Renewable Fuel Choice, Vehicle...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Flexible Fuel Vehicles: Providing a Renewable Fuel Choice, Vehicle Technologies Program (VTP) (Fact Sheet) Flexible Fuel Vehicles: Providing a Renewable Fuel Choice, Vehicle...

420

DOE Fuel Cell Technologies Office: 2013 Fuel Cell Seminar and...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

DOE Fuel Cell Technologies Office: 2013 Fuel Cell Seminar and Energy Exposition DOE Fuel Cell Technologies Office: 2013 Fuel Cell Seminar and Energy Exposition Overview of DOE's...

Note: This page contains sample records for the topic "newable fuels oxygenates" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

DOE Fuel Cell Technologies Office Record 13012: Fuel Cell System...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Fuel Cell Technologies Office Record 13012: Fuel Cell System Cost - 2013 DOE Fuel Cell Technologies Office Record 13012: Fuel Cell System Cost - 2013 This program record from the...

422

Polycyclic Aromatic Triptycenes: Oxygen Substitution Cyclization Strategies  

E-Print Network [OSTI]

The cyclization and planarization of polycyclic aromatic hydrocarbons with concomitant oxygen substitution was achieved through acid catalyzed transetherification and oxygen-radical reactions. The triptycene scaffold ...

VanVeller, Brett

423

Electrocatalytic Reactivity for Oxygen Reduction of Palladium...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Reactivity for Oxygen Reduction of Palladium-Modified Carbon Nanotubes Synthesized in Supercritical Fluid. Electrocatalytic Reactivity for Oxygen Reduction of Palladium-Modified...

424

Angling chromium to let oxygen through | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

which enable facile oxygen anion diffusion at low temperature. Brighter spheres are strontium ions; less-bright spheres are chromium ions. Oxygen anions are barely visible, and...

425

Extracorporeal membrane oxygenation promotes long chain fatty...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

membrane oxygenation promotes long chain fatty acid oxidation in the immature swine heart in vivo. Extracorporeal membrane oxygenation promotes long chain fatty acid oxidation...

426

OXYGEN DIFFUSION IN HYPOSTOICHIOMETRIC URANIUM DIOXIDE  

E-Print Network [OSTI]

Research Division OXYGEN DIFFUSION IN HYPOSTOICHIOMETRIC11905 -DISCLAIMER - OXYGEN DIFFUSION IN HYPOSTOICHIOMETRICc o n e e n i g woroxygen self-diffusion coefficient

Kim, Kee Chul

2010-01-01T23:59:59.000Z

427

Formation, characterization and reactivity of adsorbed oxygen...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Formation, characterization and reactivity of adsorbed oxygen on BaOPt(111). Formation, characterization and reactivity of adsorbed oxygen on BaOPt(111). Abstract: The formation...

428

It's Elemental - The Element Oxygen  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Nitrogen Nitrogen Previous Element (Nitrogen) The Periodic Table of Elements Next Element (Fluorine) Fluorine The Element Oxygen [Click for Isotope Data] 8 O Oxygen 15.9994 Atomic Number: 8 Atomic Weight: 15.9994 Melting Point: 54.36 K (-218.79°C or -361.82°F) Boiling Point: 90.20 K (-182.95°C or -297.31°F) Density: 0.001429 grams per cubic centimeter Phase at Room Temperature: Gas Element Classification: Non-metal Period Number: 2 Group Number: 16 Group Name: Chalcogen What's in a name? From the greek words oxys and genes, which together mean "acid forming." Say what? Oxygen is pronounced as OK-si-jen. History and Uses: Oxygen had been produced by several chemists prior to its discovery in 1774, but they failed to recognize it as a distinct element. Joseph

429

The System Boron—Oxygen  

Science Journals Connector (OSTI)

This presentation covers the years 1985 to 1988 and, in part, to 1992. It continues the previous discussion of the system boron—oxygen in “Boron Compounds” 3rd Suppl. Vol. 2, 1987, pp. 1/184, and earlier liter...

Gert Heller

1993-01-01T23:59:59.000Z

430

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

The present quarterly report describes some of the initial studies on newer compositions and also includes newer approaches to address various materials issues such as in metal-ceramic sealing. The current quarter's research has also focused on developing a comprehensive reliability model for predicting the structural behavior of the membranes in realistic conditions. In parallel to industry provided compositions, models membranes have been evaluated in varying environment. Of importance is the behavior of flaws and generation of new flaws aiding in fracture. Fracture mechanics parameters such as crack tip stresses are generated to characterize the influence of environment. Room temperature slow crack growth studies have also been initiated in industry provided compositions. The electrical conductivity and defect chemistry of an A site deficient compound (La{sub 0.55}Sr{sub 0.35}FeO{sub 3}) was studied. A higher conductivity was observed for La{sub 0.55}Sr{sub 0.35}FeO{sub 3} than that of La{sub 0.60}Sr{sub 0.40}FeO{sub 3} and La{sub 0.80}Sr{sub 0.20}FeO{sub 3}. Defect chemistry analysis showed that it was primarily contributed by a higher carrier concentration in La{sub 0.55}Sr{sub 0.35}FeO{sub 3}. Moreover, the ability for oxygen vacancy generation is much higher in La{sub 0.55}Sr{sub 0.35}FeO{sub 3} as well, which indicates a lower bonding strength between Fe-O and a possible higher catalytic activity for La{sub 0.55}Sr{sub 0.35}FeO{sub 3}. The program continued to investigate the thermodynamic properties (stability and phase separation behavior) and total conductivity of prototype membrane materials. The data are needed together with the kinetic information to develop a complete model for the membrane transport. Previous report listed initial measurements on a sample of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-x} prepared in-house by Praxair. Subsequently, a second sample of powder from a larger batch of sample were characterized and compared with the results from the previous batch.

S. Bandopadhyay; N. Nagabhushana; Thomas W. Eagar; Harold R. Larson; Raymundo Arroyave; X.-D Zhou; Y.-W. Shin; H.U. Anderson; Nigel Browning; Alan Jacobson; C.A. Mims

2003-11-01T23:59:59.000Z

431

Effects of Concentration, Crystal Structure, Magnetism, and Electronic Structure Method on First-Principles Oxygen Vacancy Formation Energy Trends in Perovskites  

Science Journals Connector (OSTI)

Systematic prediction of the redox reaction energetics of large sets of 3d transition metal oxides is imperative to the selection of oxygen carrier candidates in applications ranging from chemical looping to solid oxide fuel cell (SOFC) cathode design. In ...

Matthew T. Curnan; John R. Kitchin

2014-11-25T23:59:59.000Z

432

Reactivity of a CaSO4-oxygen carrier in chemical-looping combustion of methane in a fixed bed reactor  

Science Journals Connector (OSTI)

Chemical-looping combustion (CLC) is a promising technology for the combustion of gas or solid fuel with efficient...2. A reactivity study of CaSO4 oxygen carrier in CLC of methane was conducted in a laboratory s...

Qilei Song; Rui Xiao; Zhongyi Deng; Laihong Shen…

2009-03-01T23:59:59.000Z

433

Fuel cells: A handbook (Revision 3)  

SciTech Connect (OSTI)

Fuel cells are electrochemical devices that convert the chemical energy of reaction directly into electrical energy. In a typical fuel cell, gaseous fuels are fed continuously to the anode (negative electrode) compartment and an oxidant (i.e., oxygen from air) is fed continuously to the cathode (positive electrode) compartment; the electrochemical reactions take place at the electrodes to produce an electric current. A fuel cell, although having similar components and several characteristics, differs from a typical battery in several respects. The battery is an energy storage device, that is, the maximum energy that is available is determined by the amount of chemical reactant stored within the battery itself. Thus, the battery will cease to produce electrical energy when the chemical reactants are consumed (i.e., discharged). In a secondary battery, the reactants are regenerated by recharging, which involves putting energy into the battery from an external source. The fuel cell, on the other hand, is an energy conversion device which theoretically has the capability of producing electrical energy for as long as the fuel and oxidant are supplied to the electrodes. In reality, degradation or malfunction of components limits the practical operating life of fuel cells.

Hirschenhofer, J.H.; Stauffer, D.B.; Engleman, R.R.

1994-01-01T23:59:59.000Z

434

Fuel cells for extraterrestrial and terrestrial applications  

SciTech Connect (OSTI)

The fuel cell is a nineteenth century invention and a twentieth century technology development. Due to the high power and energy density, high efficiency, reliability, and production of pure water, hydrogen-oxygen fuel cell systems have no competition as auxiliary power sources for space vehicles. The alkaline fuel cell system is a well developed and proven technology for this application. The solid polymer electrolyte system may be its future competitor. The energy crisis of 1973 stimulated research, development and demonstration of the phosphoric acid, molten carbonate, solid oxide and solid polymer electrolyte fuel cell systems using natural gas, petroleum or coal derived hydrogen (and carbon monoxide for the high temperature systems) for terrestrial applications. The direct methanol-air fuel cell is still an electrochemist's dream. Though considerable technological advances have been made, the present price of crude oil, and the high capital costs and limited lifetime of fuel cell systems impede their terrestrial applications in the developed countries. Conversely, the potential for lower capital costs of labor intensive manufacturing processes and the relatively higher fossil fuel prices make these systems more attractive for such applications in the developing countries. 11 refs.

Srinivasan, S.

1987-01-01T23:59:59.000Z

435

Chemical Kinetic Modeling of Fuels  

Broader source: Energy.gov (indexed) [DOE]

petroleum based fuels * Non-petroleum based fuels: - Biodiesel and new generation biofuels - Fischer-Tropsch (F-T) fuels - Oil sand derived fuels Reduce mechanisms for...

436

Fuel Cell Links  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Fuel Cell Links Fuel Cell Links The links below are provided as additional resources for fuel-cell-related information. Most of the linked sites are not part of, nor affiliated with, fueleconomy.gov. We do not endorse or vouch for the accuracy of the information found on such sites. Fuel Cell Vehicles and Manufacturers Chevrolet General Motors press release about the Chevrolet Fuel Cell Equinox Ford Ford overview of their hydrogen fuel cell vehicles Honda FCX Clarity official site Hyundai Hyundai press release announcing the upcoming Tucson Fuel Cell Mercedes-Benz Ener-G-Force Fuel-cell-powered concept SUV Nissan Nissan TeRRA concept SUV Toyota Overview of Toyota fuel cell technology Hydrogen- and Fuel-Cell-Related Information and Tools Fuel Cell Vehicles Brief overview of fuel cell vehicles provided by DOE's Alternative Fuels Data Center (AFDC)

437

Fuel Guide Economy  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

1 1 MODEL YEAR 2000 FUEL ECONOMY LEADERS IN POPULAR VEHICLE CLASSES Listed below are the vehicles with the highest fuel economy for the most popular classes, including both automatic and manual transmissions and gasoline and diesel vehicles. Please be aware that many of these vehicles come in a range of engine sizes and trim lines, resulting in different fuel economy values. Check the fuel economy guide or the fuel economy sticker on new vehicles to find the values for a particular version of a vehicle. CONTENTS MODEL YEAR 2000 FUEL ECONOMY LEADERS ................. 1 HOW TO USE THIS GUIDE ..................................................... 2 FUEL ECONOMY AND YOUR ANNUAL FUEL COSTS .......... 3 WHY FUEL ECONOMY IS IMPORTANT .................................

438

Subtask 3.12 - Oxygen-Fired CFBC  

SciTech Connect (OSTI)

Traditionally, air is used as the source of oxygen for firing a combustion system. A fully oxygen-fired circulating fluidized-bed combustion (CFBC) system would result in the production of a flue gas stream consisting of mostly carbon dioxide and water. The concentrated carbon dioxide stream would be available for sequestering or other purposes. Temperatures in an oxygen-blown CFBC system would be controlled by a combination of flue gas recycle, solids recirculation, and by appropriately sizing and locating the amount of heat-transfer surface required. Flue gas recycle provides the additional gas required for adequate fluidization and circulation of solids replacing the nitrogen that would be present in an air-blown system. The amount of flue gas recycle will determine how much of the remaining heat from the coal combustion will have to be removed. If the amount of flue gas recycle required by increasing solids recirculation and oxygen staging is limited, introducing the pure oxygen at multiple locations in the combustor to result in a more even temperature profile should result in a more compact system, thus reducing initial capital costs for construction. The overall efficiency of the process should be greater than that of an air-blown system since less fuel is required for the creation of the same amount of energy. The Energy & Environmental Research Center (EERC) is in a unique position to advance this technology. It has a world-class CFBC pilot plant, has experience with firing a wide range of fuels in our air-fired CFBC pilot plant, has prior experience with oxygen-firing a slagging furnace system in a pulverized coal-fired mode with a bituminous coal, and has all of the components required for oxygen-firing right next to the CFBC pilot plant already in place. An engineering study was performed to identify methods, an overall appropriate configuration, and an operating strategy for a fully oxygen-fired CFBC pilot plant by: (1) developing a plan to optimize the amount of flue gas recycle required to control bed temperature; (2) determining how to best utilize the heat-transfer surfaces in a CFBC pilot plant, such as increased external bed surface, to more beneficially use increased solids recycle; (3) identifying appropriate methods for staged addition of the oxygen/recycled flue gas streams to maintain a good temperature profile in the combustor; and (4) determining the level of effort required to convert the EERC CFBC pilot plant to one that is oxygen-blown. The EERC additionally used its experience to consider what would be required for firing a wide range of fuels from biomass to low-rank coals to high-rank coals and petroleum cokes. These proposed modifications will be performed based upon obtaining the required funding.

Douglas Hajicek; Mark Musich; Ann Henderson

2007-02-28T23:59:59.000Z

439

Fuels options conference  

SciTech Connect (OSTI)

The proceedings of the Fuels Options Conference held May 9-10, 1995 in Atlanta, Georgia are presented. Twenty-three papers were presented at the conference that dealt with fuels outlook; unconventional fuels; fuel specification, purchasing, and contracting; and waste fuels applications. A separate abstract was prepared for each paper for inclusion in the Energy Science and Technology Database.

NONE

1995-09-01T23:59:59.000Z

440

Water column oxygen demand and sediment oxygen flux: patterns of oxygen depletion in tidal creeks  

Science Journals Connector (OSTI)

Five study sites were chosen in Futch Creek, Hewletts Creek and Pages Creek,...1). Sites were chosen to reflect a range in the values of dissolved oxygen levels, chlorophyll a concentrations and nutrient (nitroge...

Tara A. MacPherson; Lawrence B. Cahoon; Michael A. Mallin

2007-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "newable fuels oxygenates" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. In this report, in situ neutron diffraction was used to characterize the chemical and structural properties of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} (here after as L2SF55T) specimen, which was subject to measurements of neutron diffraction from room temperature to 900 C in N{sub 2}. Space group of R3c was found to result in a better refinement and is used in this study. The difference for crystal structure, lattice parameters and local crystal chemistry for LSFT nearly unchanged when gas environment switched from air to N{sub 2}. Stable crack growth studies on Dense OTM bars provided by Praxair were done at room temperature in air. A bridge-compression fixture was fabricated to achieve stable pre-cracks from Vickers indents. Post fracture evaluation indicated stable crack growth from the indent and a regime of fast fracture. Post-fracture X-ray data of the OTM fractured at 1000 C in environment were refined by FullProf code and results indicate a distortion of the parent cubic perovskite to orthorhombic structure with reduced symmetry. TGA-DTA studies on the post-fracture samples also indicated residual effect arising from the thermal and stress history of the samples. The thermal and chemical expansion of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} were studied at 800 {le} T {le} 1000 C and at {approx} 1 x 10{sup -15} {le} pO{sub 2} {le} 0.21 atm. The thermal expansion coefficient of the sample was calculated from the dilatometric analysis in the temperature range between room temperature and 1200 C in air. A series of isotope transients under air separation mode (small gradient) were completed on the membrane of LSCrF-2828 at 900 C. Low pO{sub 2} atmospheres based on with CO-CO{sub 2} mixtures have also been admitted to the delivery side of the LSCrF-2828 membrane to produce the gradients which exist under syngas generation conditions. The CO-CO{sub 2} mixtures have normal isotopic {sup 18}O abundances. The evolution of {sup 18}O on the delivery side in these experiments after an {sup 18}O pulse on the air side reveals a wealth of information about the oxygen transport processes.

S. Bandopadhyay; N. Nagabhushana; X.-D Zhou; Q. Cai; J. Yang; W.B. Yelon; W.J. James; H.U. Anderson; Alan Jacobson; C.A. Mims

2004-05-01T23:59:59.000Z

442

Alternative Fuels Data Center: Alternative Fueling Infrastructure Grants  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Alternative Fueling Alternative Fueling Infrastructure Grants to someone by E-mail Share Alternative Fuels Data Center: Alternative Fueling Infrastructure Grants on Facebook Tweet about Alternative Fuels Data Center: Alternative Fueling Infrastructure Grants on Twitter Bookmark Alternative Fuels Data Center: Alternative Fueling Infrastructure Grants on Google Bookmark Alternative Fuels Data Center: Alternative Fueling Infrastructure Grants on Delicious Rank Alternative Fuels Data Center: Alternative Fueling Infrastructure Grants on Digg Find More places to share Alternative Fuels Data Center: Alternative Fueling Infrastructure Grants on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Alternative Fueling Infrastructure Grants

443

Alternative Fuels Data Center: Alternative Fuel Vehicle Replacement Grants  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Alternative Fuel Alternative Fuel Vehicle Replacement Grants to someone by E-mail Share Alternative Fuels Data Center: Alternative Fuel Vehicle Replacement Grants on Facebook Tweet about Alternative Fuels Data Center: Alternative Fuel Vehicle Replacement Grants on Twitter Bookmark Alternative Fuels Data Center: Alternative Fuel Vehicle Replacement Grants on Google Bookmark Alternative Fuels Data Center: Alternative Fuel Vehicle Replacement Grants on Delicious Rank Alternative Fuels Data Center: Alternative Fuel Vehicle Replacement Grants on Digg Find More places to share Alternative Fuels Data Center: Alternative Fuel Vehicle Replacement Grants on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Alternative Fuel Vehicle Replacement Grants

444

Alternative Fuels Data Center: Alternative Fuel Vehicle (AFV) Conversion  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Alternative Fuel Alternative Fuel Vehicle (AFV) Conversion to someone by E-mail Share Alternative Fuels Data Center: Alternative Fuel Vehicle (AFV) Conversion on Facebook Tweet about Alternative Fuels Data Center: Alternative Fuel Vehicle (AFV) Conversion on Twitter Bookmark Alternative Fuels Data Center: Alternative Fuel Vehicle (AFV) Conversion on Google Bookmark Alternative Fuels Data Center: Alternative Fuel Vehicle (AFV) Conversion on Delicious Rank Alternative Fuels Data Center: Alternative Fuel Vehicle (AFV) Conversion on Digg Find More places to share Alternative Fuels Data Center: Alternative Fuel Vehicle (AFV) Conversion on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Alternative Fuel Vehicle (AFV) Conversion

445

Alternative Fuels Data Center: Alternative Fueling Infrastructure Tax  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Fueling Fueling Infrastructure Tax Credit to someone by E-mail Share Alternative Fuels Data Center: Alternative Fueling Infrastructure Tax Credit on Facebook Tweet about Alternative Fuels Data Center: Alternative Fueling Infrastructure Tax Credit on Twitter Bookmark Alternative Fuels Data Center: Alternative Fueling Infrastructure Tax Credit on Google Bookmark Alternative Fuels Data Center: Alternative Fueling Infrastructure Tax Credit on Delicious Rank Alternative Fuels Data Center: Alternative Fueling Infrastructure Tax Credit on Digg Find More places to share Alternative Fuels Data Center: Alternative Fueling Infrastructure Tax Credit on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Alternative Fueling Infrastructure Tax Credit

446

Alternative Fuels Data Center: Alternative Fuel Vehicle Labeling  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Alternative Fuel Alternative Fuel Vehicle Labeling Requirement to someone by E-mail Share Alternative Fuels Data Center: Alternative Fuel Vehicle Labeling Requirement on Facebook Tweet about Alternative Fuels Data Center: Alternative Fuel Vehicle Labeling Requirement on Twitter Bookmark Alternative Fuels Data Center: Alternative Fuel Vehicle Labeling Requirement on Google Bookmark Alternative Fuels Data Center: Alternative Fuel Vehicle Labeling Requirement on Delicious Rank Alternative Fuels Data Center: Alternative Fuel Vehicle Labeling Requirement on Digg Find More places to share Alternative Fuels Data Center: Alternative Fuel Vehicle Labeling Requirement on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Alternative Fuel Vehicle Labeling Requirement

447

Alternative Fuels Data Center: Biofuel Fueling Infrastructure Tax Credit  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Biofuel Fueling Biofuel Fueling Infrastructure Tax Credit to someone by E-mail Share Alternative Fuels Data Center: Biofuel Fueling Infrastructure Tax Credit on Facebook Tweet about Alternative Fuels Data Center: Biofuel Fueling Infrastructure Tax Credit on Twitter Bookmark Alternative Fuels Data Center: Biofuel Fueling Infrastructure Tax Credit on Google Bookmark Alternative Fuels Data Center: Biofuel Fueling Infrastructure Tax Credit on Delicious Rank Alternative Fuels Data Center: Biofuel Fueling Infrastructure Tax Credit on Digg Find More places to share Alternative Fuels Data Center: Biofuel Fueling Infrastructure Tax Credit on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Biofuel Fueling Infrastructure Tax Credit

448

Alternative Fuels Data Center: Alternative Fuels Promotion and Information  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Fuels Fuels Promotion and Information to someone by E-mail Share Alternative Fuels Data Center: Alternative Fuels Promotion and Information on Facebook Tweet about Alternative Fuels Data Center: Alternative Fuels Promotion and Information on Twitter Bookmark Alternative Fuels Data Center: Alternative Fuels Promotion and Information on Google Bookmark Alternative Fuels Data Center: Alternative Fuels Promotion and Information on Delicious Rank Alternative Fuels Data Center: Alternative Fuels Promotion and Information on Digg Find More places to share Alternative Fuels Data Center: Alternative Fuels Promotion and Information on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Alternative Fuels Promotion and Information

449

Alternative Fuels Data Center: Ethanol Fuel Blend Dispensing Regulations  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Ethanol Fuel Blend Ethanol Fuel Blend Dispensing Regulations to someone by E-mail Share Alternative Fuels Data Center: Ethanol Fuel Blend Dispensing Regulations on Facebook Tweet about Alternative Fuels Data Center: Ethanol Fuel Blend Dispensing Regulations on Twitter Bookmark Alternative Fuels Data Center: Ethanol Fuel Blend Dispensing Regulations on Google Bookmark Alternative Fuels Data Center: Ethanol Fuel Blend Dispensing Regulations on Delicious Rank Alternative Fuels Data Center: Ethanol Fuel Blend Dispensing Regulations on Digg Find More places to share Alternative Fuels Data Center: Ethanol Fuel Blend Dispensing Regulations on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Ethanol Fuel Blend Dispensing Regulations

450

Alternative Fuels Data Center: Alternative Fuels Taxation Study Commission  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Fuels Fuels Taxation Study Commission to someone by E-mail Share Alternative Fuels Data Center: Alternative Fuels Taxation Study Commission on Facebook Tweet about Alternative Fuels Data Center: Alternative Fuels Taxation Study Commission on Twitter Bookmark Alternative Fuels Data Center: Alternative Fuels Taxation Study Commission on Google Bookmark Alternative Fuels Data Center: Alternative Fuels Taxation Study Commission on Delicious Rank Alternative Fuels Data Center: Alternative Fuels Taxation Study Commission on Digg Find More places to share Alternative Fuels Data Center: Alternative Fuels Taxation Study Commission on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Alternative Fuels Taxation Study Commission

451

Alternative Fuels Data Center: Alternative Fueling Infrastructure Tax  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Alternative Fueling Alternative Fueling Infrastructure Tax Credit to someone by E-mail Share Alternative Fuels Data Center: Alternative Fueling Infrastructure Tax Credit on Facebook Tweet about Alternative Fuels Data Center: Alternative Fueling Infrastructure Tax Credit on Twitter Bookmark Alternative Fuels Data Center: Alternative Fueling Infrastructure Tax Credit on Google Bookmark Alternative Fuels Data Center: Alternative Fueling Infrastructure Tax Credit on Delicious Rank Alternative Fuels Data Center: Alternative Fueling Infrastructure Tax Credit on Digg Find More places to share Alternative Fuels Data Center: Alternative Fueling Infrastructure Tax Credit on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Alternative Fueling Infrastructure Tax Credit

452

Alternative Fuels Data Center: Alternative Fuel and Conversion Definitions  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Alternative Fuel and Alternative Fuel and Conversion Definitions to someone by E-mail Share Alternative Fuels Data Center: Alternative Fuel and Conversion Definitions on Facebook Tweet about Alternative Fuels Data Center: Alternative Fuel and Conversion Definitions on Twitter Bookmark Alternative Fuels Data Center: Alternative Fuel and Conversion Definitions on Google Bookmark Alternative Fuels Data Center: Alternative Fuel and Conversion Definitions on Delicious Rank Alternative Fuels Data Center: Alternative Fuel and Conversion Definitions on Digg Find More places to share Alternative Fuels Data Center: Alternative Fuel and Conversion Definitions on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Alternative Fuel and Conversion Definitions

453

Alternative Fuels Data Center: Ethanol Flexible Fuel Vehicle Conversions  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Ethanol Flexible Fuel Ethanol Flexible Fuel Vehicle Conversions to someone by E-mail Share Alternative Fuels Data Center: Ethanol Flexible Fuel Vehicle Conversions on Facebook Tweet about Alternative Fuels Data Center: Ethanol Flexible Fuel Vehicle Conversions on Twitter Bookmark Alternative Fuels Data Center: Ethanol Flexible Fuel Vehicle Conversions on Google Bookmark Alternative Fuels Data Center: Ethanol Flexible Fuel Vehicle Conversions on Delicious Rank Alternative Fuels Data Center: Ethanol Flexible Fuel Vehicle Conversions on Digg Find More places to share Alternative Fuels Data Center: Ethanol Flexible Fuel Vehicle Conversions on AddThis.com... Ethanol Flexible Fuel Vehicle Conversions Updated July 29, 2011 Rising gasoline prices and concerns about climate change have greatly

454

Alternative Fuels Data Center: Alternative Fuel Production Subsidy  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Fuel Fuel Production Subsidy Prohibition to someone by E-mail Share Alternative Fuels Data Center: Alternative Fuel Production Subsidy Prohibition on Facebook Tweet about Alternative Fuels Data Center: Alternative Fuel Production Subsidy Prohibition on Twitter Bookmark Alternative Fuels Data Center: Alternative Fuel Production Subsidy Prohibition on Google Bookmark Alternative Fuels Data Center: Alternative Fuel Production Subsidy Prohibition on Delicious Rank Alternative Fuels Data Center: Alternative Fuel Production Subsidy Prohibition on Digg Find More places to share Alternative Fuels Data Center: Alternative Fuel Production Subsidy Prohibition on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Alternative Fuel Production Subsidy Prohibition

455

Alternative Fuels Data Center: Alternative Fueling Infrastructure Tax  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Fueling Fueling Infrastructure Tax Credit to someone by E-mail Share Alternative Fuels Data Center: Alternative Fueling Infrastructure Tax Credit on Facebook Tweet about Alternative Fuels Data Center: Alternative Fueling Infrastructure Tax Credit on Twitter Bookmark Alternative Fuels Data Center: Alternative Fueling Infrastructure Tax Credit on Google Bookmark Alternative Fuels Data Center: Alternative Fueling Infrastructure Tax Credit on Delicious Rank Alternative Fuels Data Center: Alternative Fueling Infrastructure Tax Credit on Digg Find More places to share Alternative Fuels Data Center: Alternative Fueling Infrastructure Tax Credit on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Alternative Fueling Infrastructure Tax Credit

456

Alternative Fuels Data Center: Alternative Fuel Infrastructure Tax Credit  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Alternative Fuel Alternative Fuel Infrastructure Tax Credit to someone by E-mail Share Alternative Fuels Data Center: Alternative Fuel Infrastructure Tax Credit on Facebook Tweet about Alternative Fuels Data Center: Alternative Fuel Infrastructure Tax Credit on Twitter Bookmark Alternative Fuels Data Center: Alternative Fuel Infrastructure Tax Credit on Google Bookmark Alternative Fuels Data Center: Alternative Fuel Infrastructure Tax Credit on Delicious Rank Alternative Fuels Data Center: Alternative Fuel Infrastructure Tax Credit on Digg Find More places to share Alternative Fuels Data Center: Alternative Fuel Infrastructure Tax Credit on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Alternative Fuel Infrastructure Tax Credit

457