Sample records for neat methanol flex

  1. A sandwich structured membrane for direct methanol fuel cells operating with neat methanol

    E-Print Network [OSTI]

    Zhao, Tianshou

    A sandwich structured membrane for direct methanol fuel cells operating with neat methanol Q.X. Wu i g h t s " A sandwich structured membrane for DMFCs operating with neat methanol is proposed. " The membrane offers better water management for DMFCs operating with neat methanol. " The sandwich structured

  2. Author's personal copy Modeling of a passive DMFC operating with neat methanol

    E-Print Network [OSTI]

    Zhao, Tianshou

    Author's personal copy Modeling of a passive DMFC operating with neat methanol W.W. Yang, T.S. Zhao 2011 Keywords: Fuel cells Direct methanol fuel cells Neat methanol Mass transport Model a b s t r a c t A mathematical model is developed to simulate the fundamental transport phenomena in a passive direct methanol

  3. Effect of the cathode gas diffusion layer on the water transport behavior and the performance of passive direct methanol fuel cells operating with neat methanol

    E-Print Network [OSTI]

    Zhao, Tianshou

    of passive direct methanol fuel cells operating with neat methanol Q.X. Wu, T.S. Zhao , W.W. Yang Department Direct methanol fuel cell Passive operation Neat methanol operation a b s t r a c t The passive operation of a direct methanol fuel cell with neat methanol requires the water that is pro- duced at the cathode

  4. Flex Fuel Vehicle Systems

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Flex Fuel Vehicle Systems * Bosch FFV Project Structure and Partners * Purpose of Work - Project Highlights * Barriers - Existing Flex Fuel Systems and Problems * Approach - Bosch...

  5. FlexEnergy

    Broader source: Energy.gov [DOE]

    Presentation—given at the Fall 2011 Federal Utility Partnership Working Group (FUPWG) meeting—provides a company overview of FlexEnergy, Inc.

  6. Effect of water concentration in the anode catalyst layer on the performance of direct methanol fuel cells operating

    E-Print Network [OSTI]

    Zhao, Tianshou

    Effect of water concentration in the anode catalyst layer on the performance of direct methanol fuel cells operating with neat methanol Q.X. Wu a , S.Y. Shen a , Y.L. He b , T.S. Zhao a cells Direct methanol fuel cells Neat methanol Water concentration a b s t r a c t This paper reports

  7. Surface Studies of Aqueous Methanol Solutions by Vibrational Broad Bandwidth Sum Frequency Generation Spectroscopy

    E-Print Network [OSTI]

    Surface Studies of Aqueous Methanol Solutions by Vibrational Broad Bandwidth Sum Frequency methanol (CH3OH) and aqueous methanol solutions were investigated using broad bandwidth sum frequency of methanol molecules at the air-liquid interfaces of neat methanol and aqueous methanol solutions. However

  8. Vehicle Certification Test Fuel and Ethanol Flex Fuel Quality...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Vehicle Certification Test Fuel and Ethanol Flex Fuel Quality Vehicle Certification Test Fuel and Ethanol Flex Fuel Quality Breakout Session 2: Frontiers and Horizons Session 2-B:...

  9. Methanol Reaction with Sulfuric Acid: A Vibrational Spectroscopic Study Lisa L. Van Loon and Heather C. Allen*

    E-Print Network [OSTI]

    Methanol Reaction with Sulfuric Acid: A Vibrational Spectroscopic Study Lisa L. Van Loon 43210 ReceiVed: May 27, 2004; In Final Form: August 19, 2004 The reaction between methanol and sulfuric peak in the 800 cm-1 region, not present in either the neat methanol or concentrated sulfuric acid

  10. Prediction of the Size Distributions of Methanol-Ethanol Clusters Detected in VUV Laser/Time-of-Flight Mass Spectrometry

    E-Print Network [OSTI]

    Goddard III, William A.

    Prediction of the Size Distributions of Methanol-Ethanol Clusters Detected in VUV Laser distributions and geometries of vapor clusters equilibrated with methanol-ethanol (Me-Et) liquid mixtures were distributions of vapor clusters equilibrated with liquids, ranging from neat alcohols1,2 to methanol-ethanol (Me

  11. Natural Gas Ethanol Flex-Fuel

    E-Print Network [OSTI]

    Natural Gas Propane Electric Ethanol Flex-Fuel Biodiesel Vehicle Buyer's Guide Clean Cities 2012 . . . . . . . . . . . . . . . . . . . . . . . . 4 About This Guide . . . . . . . . . . . . . . . . . . . 5 Compressed Natural Gas and emissions. Alternative fueling infrastructure is expanding in many regions, making natural gas, propane

  12. DC Students Flex Their Mental Muscles in Regional Science Bowl...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    DC Students Flex Their Mental Muscles in Regional Science Bowl Competition DC Students Flex Their Mental Muscles in Regional Science Bowl Competition February 23, 2015 - 3:12pm...

  13. Flex power perspectives of indirect power system control through...

    Open Energy Info (EERE)

    power perspectives of indirect power system control through dynamic power price (Smart Grid Project) Jump to: navigation, search Project Name Flex power perspectives of indirect...

  14. Method for making methanol

    DOE Patents [OSTI]

    Mednick, R. Lawrence (Roslyn Heights, NY); Blum, David B. (Wayne, NJ)

    1986-01-01T23:59:59.000Z

    Methanol is made in a liquid-phase methanol reactor by entraining a methanol-forming catalyst in an inert liquid and contacting said entrained catalyst with a synthesis gas comprising hydrogen and carbon monoxide.

  15. Method for making methanol

    DOE Patents [OSTI]

    Mednick, R. Lawrence (Roslyn Heights, NY); Blum, David B. (Wayne, NJ)

    1987-01-01T23:59:59.000Z

    Methanol is made in a liquid-phase methanol reactor by entraining a methanol-forming catalyst in an inert liquid and contacting said entrained catalyst with a synthesis gas comprising hydrogen and carbon monoxide.

  16. Flex Fuels Energy | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual SiteofEvaluating A PotentialJumpGermanFife Energy Park atFisia BabcockFlex Fuels Energy Jump

  17. UtiliFlex | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere IRaghuraji Agro IndustriesTown of Ladoga,planning methodologies and toolsoperation plansUtiliFlex Jump to:

  18. U-050: Adobe Flex SDK Input Validation Flaw Permits Cross-Site Scripting Attacks

    Broader source: Energy.gov [DOE]

    Flex applications created using the Flex SDK may not properly filter HTML code from user-supplied input before displaying the input.

  19. Development of an SI DI Ethanol Optimized Flex Fuel Engine Using...

    Broader source: Energy.gov (indexed) [DOE]

    Development of an SI DI Ethanol Optimized Flex Fuel Engine Using Advanced Valvetrain Development of an SI DI Ethanol Optimized Flex Fuel Engine Using Advanced Valvetrain...

  20. NEAT-IGERT Proposal C. THEMATIC BASIS FOR GROUP EFFORT

    E-Print Network [OSTI]

    Islam, M. Saif

    NEAT-IGERT Proposal C. THEMATIC BASIS FOR GROUP EFFORT The last decade has seen immense progress the research and teaching interests of fourteen investigators in seven different departments ranging from, to the actual structure and management of the group. The Ph.D.'s from this program will be well poised to embark

  1. Improved Flow-Field Structures for Direct Methanol Fuel Cells

    SciTech Connect (OSTI)

    Gurau, Bogdan

    2013-05-31T23:59:59.000Z

    The direct methanol fuel cell (DMFC) is ideal if high energy-density liquid fuels are required. Liquid fuels have advantages over compressed hydrogen including higher energy density and ease of handling. Although state-of-the-art DMFCs exhibit manageable degradation rates, excessive fuel crossover diminishes system energy and power density. Although use of dilute methanol mitigates crossover, the concomitant lowering of the gross fuel energy density (GFED) demands a complex balance-of-plant (BOP) that includes higher flow rates, external exhaust recirculation, etc. An alternative approach is redesign of the fuel delivery system to accommodate concentrated methanol. NuVant Systems Inc. (NuVant) will maximize the GFED by design and assembly of a DMFC that uses near neat methanol. The approach is to tune the diffusion of highly concentrated methanol (to the anode catalytic layer) to the back-diffusion of water formed at the cathode (i.e. in situ generation of dilute methanol at the anode layer). Crossover will be minimized without compromising the GFED by innovative integration of the anode flow-field and the diffusion layer. The integrated flow-field-diffusion-layers (IFDLs) will widen the current and potential DMFC operating ranges and enable the use of cathodes optimized for hydrogen-air fuel cells.

  2. DOE-Flex Bulletin-Worker Injury While on a DOE-Flex Arrangement |

    Office of Environmental Management (EM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 1112011AT&T,Office of Policy, OAPM |TRUJuly 29,of EnergyofRevised Finding ofFlex

  3. DOE-Flex Bulletin-Worker Injury While on a DOE-Flex Arrangement

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't Your Destiny:Revised Finding of No Significant Impact for Biomass CogenerationFlex Bulletin The

  4. DOE-Flex Bulletin-Worker Injury While on a DOE-Flex Arrangement |

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directed off Energy.gov. Are you0and Transparency, and MoreEnergyofDepartment of Energy DOE-Flex

  5. National Energy AudiT (NEAT) user`s manual

    SciTech Connect (OSTI)

    Krigger, J.K.; Adams, N. [Saturn Resource Management, Helena, MT (United States); Gettings, M. [Oak Ridge National Lab., TN (United States). Energy Div.

    1997-10-01T23:59:59.000Z

    Welcome to the US Department of Energy`s (DOE`s) energy auditing tool called ``NEAT``. NEAT, an acronym for National Energy AudiT, is a program for personal computers that was designed for use by local agencies in the Weatherization Assistance Program. It is an approved alternative audit that meets all auditing requirements set forth by the program as well as those anticipated from new regulations pertaining to waiver of the 40% materials requirements. NEAT is easy to use. It applies engineering and economic calculations to evaluate energy conservation measures for single-family, detached houses or small multifamily buildings. You can use it to rank measured for each individual house, or to establish a priority list of conservation measures for nearly identical housing types. NEAT was written for the Weatherization Assistance Program by Oak Ridge National Laboratory. Many buildings energy consumption algorithms are taken from Lawrence Berkeley Laboratory`s to the computerized Instrumented Residential Audit (CIRA), published in 1982 for the Department of energy. Equipment retrofit conservation measures are based on published reports on various heating retrofits. Heating and cooling system replacement conservation measures are based on the energy ratings of new heating and cooling equipment. The Weatherization Program anticipates that this computer-based energy audit will offer substantial performance improvements to many states who choose to incorporate it into their programs. When conservation measures are evaluated locally according to climate, fuel cost, measure cost, and existing house conditions, the Program will be closer to its goal of assuring the maximum return for every federal dollar spent.

  6. FlexGP : a scalable system for factored learning in the cloud

    E-Print Network [OSTI]

    Derby, Owen C

    2013-01-01T23:59:59.000Z

    This work presents FlexGP, a new system designed for scalable machine learning in the cloud. FlexGP presents a learner-agnostic, data-parallel approach to cloud-based distributed learning using existing single-machine ...

  7. Fact #718: March 12, 2012 Number of Flex-Fuel Models Offered...

    Energy Savers [EERE]

    Economy program for producing flex-fuel vehicles, which run on E-85, a blend of 85% ethanol and 15% gasoline, andor gasoline. Number of Flex Fuel Vehicle Models by...

  8. Methanol partial oxidation reformer

    DOE Patents [OSTI]

    Ahmed, Shabbir (Bolingbrook, IL); Kumar, Romesh (Naperville, IL); Krumpelt, Michael (Naperville, IL)

    1999-01-01T23:59:59.000Z

    A partial oxidation reformer comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell.

  9. Methanol partial oxidation reformer

    DOE Patents [OSTI]

    Ahmed, Shabbir (Bolingbrook, IL); Kumar, Romesh (Naperville, IL); Krumpelt, Michael (Naperville, IL)

    2001-01-01T23:59:59.000Z

    A partial oxidation reformer comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell.

  10. Methanol partial oxidation reformer

    DOE Patents [OSTI]

    Ahmed, S.; Kumar, R.; Krumpelt, M.

    1999-08-24T23:59:59.000Z

    A partial oxidation reformer is described comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell. 7 figs.

  11. Methanol partial oxidation reformer

    DOE Patents [OSTI]

    Ahmed, S.; Kumar, R.; Krumpelt, M.

    1999-08-17T23:59:59.000Z

    A partial oxidation reformer is described comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell. 7 figs.

  12. Conveyorized Photoresist Stripping Replacement for Flex Circuit Fabrication

    SciTech Connect (OSTI)

    Megan Donahue

    2009-02-24T23:59:59.000Z

    A replacement conveyorized photoresist stripping system was characterized to replace the ASI photoresist stripping system. This system uses the qualified ADF-25c chemistry for the fabrication of flex circuits, while the ASI uses the qualified potassium hydroxide chemistry. The stripping process removes photoresist, which is used to protect the copper traces being formed during the etch process.

  13. Synthesis of poly-(P-aryleneethynylene)s in neat water under aerobic conditions

    DOE Patents [OSTI]

    Kang, Youn K; Deria, Pravas; Therien, Michael J

    2012-10-16T23:59:59.000Z

    Provided are ethyne synthons comprising boron and related methods. Also provided are related water-soluble arylethynylene polymers capable of being synthesized in neat water under aerobic conditions.

  14. THE FURNACE COMBUSTION AND RADIATION CHARACTERISTICS OF METHANOL AND A METHANOL/COAL SLURRY

    E-Print Network [OSTI]

    Grosshandler, W.L.

    2010-01-01T23:59:59.000Z

    vol. ) in Methanol Furnace , 2 , . . . . . . . . , . , .Velocity Profiles in Methanol Furnace Temperature Profiles:to Pure Methanol . . . . . . . . . . . . , . . . . C02

  15. Produce syngas for methanol

    SciTech Connect (OSTI)

    Farina, G.L. (Foster Wheeler International Corp., Milan (IT))

    1992-03-01T23:59:59.000Z

    Combined reforming, in which an oxygen reforming reactor is added downstream from a conventional tubular reactor to produce syngas for methanol, achieves a substantial reduction in energy consumption with the least impact on the environment. This paper reports that the advantages of this process scheme are as follows: 8% to 10% reduction in the consumption of natural gas per ton of methanol, The size of the primary reformer is reduced, Reduction of syngas compression requirement due to increased syngas pressure, Reduced steam consumption, Production of syngas with the stoichiometric composition required by methanol synthesis. Synthesis gases for the production of methanol and synfuels are basically mixtures of hydrogen and carbon oxides. They have been produced from natural gas by steam reforming, autothermal reforming and noncatalytic partial oxidation.

  16. MTBE/methanol supply

    SciTech Connect (OSTI)

    Simmons, R.E.

    1986-05-01T23:59:59.000Z

    U.S. methanol production has become economically competitive with imports due to de-escalation of natural gas price from $3.07 mm Btu in January 1985 to $2.07 mm Btu by December 1985. This has reversed the earlier supply outlook when it appeared that additional methanol plants would shutdown due to low cost imports. Current gas cost in conjunction with projections for continued excess supply prompted DuPont to restart their 250 mm gpy plant at Beaumont, Texas. Other former producers are contemplating restarting idle units.

  17. Development of an SI DI Ethanol Optimized Flex Fuel Engine Using...

    Broader source: Energy.gov (indexed) [DOE]

    SI DI Ethanol Optimized Flex Fuel Engine Using Advanced Valvetrain Wayne Moore, Matt Foster, Kevin Hoyer, Keith Confer Delphi Advanced Powertrain DEER Conference September 29, 2010...

  18. 4, 125164, 2007 Methanol exchange

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    BGD 4, 125­164, 2007 Methanol exchange between grassland and the atmosphere A. Brunner et al. Title Discussions Biogeosciences Discussions is the access reviewed discussion forum of Biogeosciences Methanol (albrecht.neftel@art.admin.ch) 125 #12;BGD 4, 125­164, 2007 Methanol exchange between grassland

  19. The Development of Methanol Industry and Methanol Fuel in China

    SciTech Connect (OSTI)

    Li, W.Y.; Li, Z.; Xie, K.C. [Taiyuan University of Technology, Taiyuan (China)

    2009-07-01T23:59:59.000Z

    In 2007, China firmly established itself as the driver of the global methanol industry. The country became the world's largest methanol producer and consumer. The development of the methanol industry and methanol fuel in China is reviewed in this article. China is rich in coal but is short on oil and natural gas; unfortunately, transportation development will need more and more oil to provide the fuel. Methanol is becoming a dominant alternative fuel. China is showing the rest of the world how cleaner transportation fuels can be made from coal.

  20. Fuel Puddle Model and AFR Compensator for Gasoline-Ethanol Blends in Flex-Fuel Engines*

    E-Print Network [OSTI]

    Stefanopoulou, Anna

    Fuel Puddle Model and AFR Compensator for Gasoline-Ethanol Blends in Flex-Fuel Engines* Kyung for gasoline-ethanol blends is, thus, necessary for the purpose of air-to-fuel ratio control. In this paper, we- ration, air-to-fuel ratio control, gasoline-ethanol blend, flex-fuel vehicles I. INTRODUCTION Currently

  1. A Demonstration of FlexPref: Extensible Preference Evaluation Inside the DBMS Engine

    E-Print Network [OSTI]

    Mokbel, Mohamed F.

    A Demonstration of FlexPref: Extensible Preference Evaluation Inside the DBMS Engine Justin J This demonstration presents FlexPref, a framework imple- mented inside the DBMS query processor that enables effi, a fundamental issue is how we can realize each existing and future method inside a DBMS This work is supported

  2. The Methanol Economy Project

    SciTech Connect (OSTI)

    Olah, George; Prakash, G.K.

    2013-12-31T23:59:59.000Z

    The Methanol Economy Project is based on the concept of replacing fossil fuels with methanol generated either from renewable resources or abundant natural (shale) gas. The full methanol cycle was investigated in this project, from production of methanol through bromination of methane, bireforming of methane to syngas, CO{sub 2} capture using supported amines, co-electrolysis of CO{sub 2} and water to formate and syngas, decomposition of formate to CO{sub 2} and H{sub 2}, and use of formic acid in a direct formic acid fuel cell. Each of these projects achieved milestones and provided new insights into their respective fields. ? Direct electrophilic bromination of methane to methyl bromide followed by hydrolysis to yield methanol was investigated on a wide variety of catalyst systems, but hydrolysis proved impractical for large-scale industrial application. ? Bireforming the correct ratio of methane, CO{sub 2}, and water on a NiO / MgO catalyst yielded the right proportion of H{sub 2}:CO (2:1) and proved to be stable for at least 250 hours of operation at 400 psi (28 atm). ? CO{sub 2} capture utilizing supported polyethyleneimines yielded a system capable of adsorbing CO{sub 2} from the air and release at nominal temperatures with negligible amine leaching. ? CO{sub 2} electrolysis to formate and syngas showed considerable increases in rate and selectivity by performing the reaction in a high pressure flow electrolyzer. ? Formic acid was shown to decompose selectively to CO{sub 2} and H{sub 2} using either Ru or Ir based homogeneous catalysts. ? Direct formic acid fuel cells were also investigated and showed higher than 40% voltage efficiency using reduced loadings of precious metals. A technoeconomic analysis was conducted to assess the viability of taking each of these processes to the industrial scale by applying the data gathered during the experiments to approximations based on currently used industrial processes. Several of these processes show significant promise for industrial scale up and use towards improving our nation’s energy independence.

  3. Vacuum-Ultraviolet (VUV) Photoionization of Small Methanol and Methanol-Water Clusters

    E-Print Network [OSTI]

    Kostko, Oleg

    2008-01-01T23:59:59.000Z

    Table 1 Appearance energies for pure and protonated methanoland methanol-water clusters evaluated from photoionizationVUV) photoionization of small methanol and methanol-water

  4. Methanol-reinforced kraft pulping

    SciTech Connect (OSTI)

    Norman, E.; Olm, L.; Teder, A. (STFI, Stockholm (Sweden))

    1993-03-01T23:59:59.000Z

    The addition of methanol to a high-sulfidity kraft cook on Scandinavian softwood chips was studied under different process conditions. Delignification and the degradation of carbohydrates were accelerated, but the effect on delignification was greater. Thus, methanol addition improved selectivity. The positive effect of methanol could also be observed for modified kraft cooks having a leveled out alkali concentration and lower concentration of sodium ions and dissolved lignin at the end of the cook. Methanol addition had no discernible effect on pulp strength or on pulp bleachability.

  5. MTBE, methanol prices rise

    SciTech Connect (OSTI)

    Morris, G.D.L.; Cornitius, T.

    1995-12-20T23:59:59.000Z

    After several months of drifting lower in line with declining autumn gasoline prices, tabs for methyl tert-butyl ether (MTBE) have turned around. There has been no big demand surge, but consumers and traders are beginning to build up inventories in advance of a series of midwinter shutdowns and turnarounds by producers. Spot prices, which dropped as low as 75 cts/gal, have rebounded to 90 cts/gal fob. Eager for a positive glimmer, methanol producers posted a 3-cts/gal increase in contract prices this month. It marks the first upward idea since February. In that time contract prices have dropped 75% from $1.55/gal to 39 cts/gal. A hard winter has hit early in much of the US sending natural gas prices up sharply. At the same time, formaldehyde and acetic acid markets remain firm, and with MTBE rebounding, methanol producers feel entitled to a piece of the action. {open_quotes}I don`t buy into this claim that MTBE demand is up and I don`t think producers can justify even a 3-cts/gal increase,{close_quotes} says one. {open_quotes}There is nothing in the economy to warrant a run-up. Housing starts are weaker, and demand is down at least 80,000 bbl/day with the MTBE shutdown.{close_quotes}

  6. Osteoblast proliferation on neat and apatite-like calcium phosphate-coated titanium foam scaffolds

    E-Print Network [OSTI]

    Tas, A. Cuneyt

    Osteoblast proliferation on neat and apatite-like calcium phosphate-coated titanium foam scaffolds-bearing ability of lightweight titanium made it possible to be used as a biomaterial, especially in hip revision and fixation surgery. It was initially shown that sand-blasted or surface-roughened titanium implants had

  7. amine methanol, ether . Amine amine CO2

    E-Print Network [OSTI]

    Hong, Deog Ki

    IP [2012] 7 C O 2 (CO2) . CO2 amine methanol, ether . Amine amine CO2 CO2 .Amine CO2 (functional group) amine amine+ +promoter .Amine CO2 CO2 . . , methanol ether methanol, ether promoter CO2 CO2 H2S, COS CO2 . Methanol rectisol process, di-methylene ether polypropylene glycol selexol (-30oC) . CO2

  8. THE FURNACE COMBUSTION AND RADIATION CHARACTERISTICS OF METHANOL AND A METHANOL/COAL SLURRY

    E-Print Network [OSTI]

    Grosshandler, W.L.

    2010-01-01T23:59:59.000Z

    Predictions B. Methanol/Coal Slurry as the Fuel TemperatureMETHANOL METHANOL / COAL SLURRY j i Ali. @ i o N I. . , .PURE N METHANOL METHANOL I COAL SLURRY u o Obb~~ ~~~~~~~~~~~

  9. A flow field enabling operating direct methanol fuel cells with highly concentrated methanol

    E-Print Network [OSTI]

    Zhao, Tianshou

    A flow field enabling operating direct methanol fuel cells with highly concentrated methanol Q. Xu Available online 8 October 2010 Keywords: Fuel cells Direct methanol fuel cells Concentrated methanol Flow field a b s t r a c t In this work, an anode flow field that allows a direct methanol fuel cell (DMFC

  10. Analysis of Mass Transport of Methanol at the Anode of a Direct Methanol Fuel Cell

    E-Print Network [OSTI]

    Zhao, Tianshou

    Analysis of Mass Transport of Methanol at the Anode of a Direct Methanol Fuel Cell C. Xu,a Y. L. He transport of methanol at the anode of a direct methanol fuel cell DMFC and show that the overall mass current density of an in-house-fabricated DMFC with different flow fields for various methanol

  11. THE FURNACE COMBUSTION AND RADIATION CHARACTERISTICS OF METHANOL AND A METHANOL/COAL SLURRY

    E-Print Network [OSTI]

    Grosshandler, W.L.

    2010-01-01T23:59:59.000Z

    Spectral Intensity With 5% Coal (x ::: 86.9 cm) CalculatedPredictions B. Methanol/Coal Slurry as the Fuel TemperatureMethanol as the Fuel B. Methanol/Coal Slurry as the Fuel C.

  12. Rapid starting methanol reactor system

    DOE Patents [OSTI]

    Chludzinski, Paul J. (38 Berkshire St., Swampscott, MA 01907); Dantowitz, Philip (39 Nancy Ave., Peabody, MA 01960); McElroy, James F. (12 Old Cart Rd., Hamilton, MA 01936)

    1984-01-01T23:59:59.000Z

    The invention relates to a methanol-to-hydrogen cracking reactor for use with a fuel cell vehicular power plant. The system is particularly designed for rapid start-up of the catalytic methanol cracking reactor after an extended shut-down period, i.e., after the vehicular fuel cell power plant has been inoperative overnight. Rapid system start-up is accomplished by a combination of direct and indirect heating of the cracking catalyst. Initially, liquid methanol is burned with a stoichiometric or slightly lean air mixture in the combustion chamber of the reactor assembly. The hot combustion gas travels down a flue gas chamber in heat exchange relationship with the catalytic cracking chamber transferring heat across the catalyst chamber wall to heat the catalyst indirectly. The combustion gas is then diverted back through the catalyst bed to heat the catalyst pellets directly. When the cracking reactor temperature reaches operating temperature, methanol combustion is stopped and a hot gas valve is switched to route the flue gas overboard, with methanol being fed directly to the catalytic cracking reactor. Thereafter, the burner operates on excess hydrogen from the fuel cells.

  13. Vacuum-ultraviolet (VUV) photoionization of small methanol and methanol-water clusters

    E-Print Network [OSTI]

    Ahmed, Musahid

    2008-01-01T23:59:59.000Z

    cyclic trimer containing two methanol molecules and a waterTable 1 Appearance energies for pure and protonated methanoland methanol-water clusters evaluated from photoionization

  14. Desorption Kinetics of Methanol, Ethanol, and Water from Graphene...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Desorption Kinetics of Methanol, Ethanol, and Water from Graphene. Desorption Kinetics of Methanol, Ethanol, and Water from Graphene. Abstract: The desorption kinetics of methanol,...

  15. Methanol detection in M82

    E-Print Network [OSTI]

    S. Martín; J. Martín-Pintado; R. Mauersberger

    2006-03-07T23:59:59.000Z

    We present a multilevel study of the emission of methanol, detected for the first time in this galaxy, and discuss the origin of its emission. The high observed methanol abundance of a few 10^-9 can only be explained if injection of methanol from dust grains is taken into account. While the overall [CH3OH]/[NH3] ratio is much larger than observed towards other starbursts, the dense high excitation component shows a similar value to that found in NGC 253 and Maffei 2. Our observations suggest the molecular material in M 82 to be formed by dense warm cores, shielded from the UV radiation and similar to the molecular clouds in other starbursts, surrounded by a less dense photodissociated halo. The dense warm cores are likely the location of recent and future star formation within M 82.

  16. Distances to Galactic methanol masers

    E-Print Network [OSTI]

    K. L. J. Rygl; A. Brunthaler; K. M. Menten; M. J. Reid; H. J. van Langevelde

    2008-12-09T23:59:59.000Z

    We present the first EVN parallax measurements of 6.7 GHz methanol masers in star forming regions of the Galaxy. The 6.7 GHz methanol maser transition is a very valuable astrometric tool, for its large stability and confined velocity spread, which makes it ideal to measure proper motions and parallaxes. Eight well-studied massive star forming regions have been observed during five EVN sessions of 24 hours duration each and we present here preliminary results for five of them. We achieve accuracies of up to 51 $\\mu$as, which still have the potential to be proved by more ideal observational circumstances.

  17. Air Breathing Direct Methanol Fuel Cell

    DOE Patents [OSTI]

    Ren; Xiaoming (Los Alamos, NM)

    2003-07-22T23:59:59.000Z

    A method for activating a membrane electrode assembly for a direct methanol fuel cell is disclosed. The method comprises operating the fuel cell with humidified hydrogen as the fuel followed by running the fuel cell with methanol as the fuel.

  18. FLEX AND PINCH: A CASE STUDY OF WHOLE HAND INPUT DESIGN FOR VIRTUAL ENVIRONMENT INTERACTION

    E-Print Network [OSTI]

    Pattanaik, Sumanta N.

    FLEX AND PINCH: A CASE STUDY OF WHOLE HAND INPUT DESIGN FOR VIRTUAL ENVIRONMENT INTERACTION JOSEPH J. LAVIOLA JR. and ROBERT C. ZELEZNIK Brown University Site of the NSF Science and Technology Center. In this paper, we describe our Pinch Glove like input device which is used as a tool to augment bend

  19. TOLERANT ETHANOL ESTIMATION IN FLEX-FUEL VEHICLES DURING MAF SENSOR DRIFTS

    E-Print Network [OSTI]

    Stefanopoulou, Anna

    TOLERANT ETHANOL ESTIMATION IN FLEX-FUEL VEHICLES DURING MAF SENSOR DRIFTS Kyung-ho Ahn, Anna G Engineering Dearborn, Michigan 48121 ABSTRACT Flexible fuel vehicles (FFVs) can operate on a blend of ethanol on ethanol sensor installed in the vehicle fueling system, or on the ethanol- dependent air-to-fuel ratio

  20. 2010-01-0166 Ethanol Content Estimation in Flex Fuel Direct Injection

    E-Print Network [OSTI]

    Stefanopoulou, Anna

    2010-01-0166 Ethanol Content Estimation in Flex Fuel Direct Injection Engines Using In to estimate the ethanol content, which exploits the difference in stoi- chiometric air-to-fuel ratio (SAFR to large errors with mass air flow sensor bias and/or fuel injector shift. In this paper, an ethanol

  1. bepalingen_algemene_aard_studentassistent_UT-Flex_maart_2010 1 GENERAL PROVISIONS

    E-Print Network [OSTI]

    Twente, Universiteit

    the allowance monthly, together with the salary payment. 6. YEAR-END BONUS The year-end bonus is calculated-end bonus in the month of December. UT-flex pays out the bonus monthly, together with the salary payment. 7

  2. Automatic Parameter Identification in FlexRay based Automotive Communication Networks

    E-Print Network [OSTI]

    Automatic Parameter Identification in FlexRay based Automotive Communication Networks Eric-Triggered Architectures are being introduced in safety-critical automotive systems ("X-by-wire") to cope with the growing and explore its limitations. I. INTRODUCTION Nowadays most automotive innovations stem from elec- tronic

  3. Assessing the operational life of flexible printed boards intended for continuous flexing applications : a case study.

    SciTech Connect (OSTI)

    Beck, David Franklin

    2011-01-01T23:59:59.000Z

    Through the vehicle of a case study, this paper describes in detail how the guidance found in the suite of IPC (Association Connecting Electronics Industries) publications can be applied to develop a high level of design assurance that flexible printed boards intended for continuous flexing applications will satisfy specified lifetime requirements.

  4. Low Crossover of Methanol and Water Through Thin Membranes in Direct Methanol Fuel Cells

    E-Print Network [OSTI]

    Low Crossover of Methanol and Water Through Thin Membranes in Direct Methanol Fuel Cells Fuqiang State University, University Park, Pennsylvania 16802, USA Low crossover of both methanol and water through a polymer membrane in a direct methanol fuel cell DMFC is essential for using high concentration

  5. Time-resolved photoelectron imaging of large anionic methanol clusters: ,,Methanol...n

    E-Print Network [OSTI]

    Neumark, Daniel M.

    Time-resolved photoelectron imaging of large anionic methanol clusters: ,,Methanol...n - ,,nÈ145; published online 27 June 2007 The dynamics of an excess electron in size-selected methanol clusters electron6­11 and its cluster counterparts,12­18 water n - . The solvated electron in liquid methanol has

  6. Methanol Masers and Star Formation

    E-Print Network [OSTI]

    A. M. Sobolev; A. B. Ostrovskii; M. S. Kirsanova; O. V. Shelemei; M. A. Voronkov; A. V. Malyshev

    2006-01-12T23:59:59.000Z

    Methanol masers which are traditionally divided into two classes provide possibility to study important parts of the star forming regions: Class~II masers trace vicinities of the massive YSOs while class~I masers are likely to trace more distant parts of the outflows where newer stars can form. There are many methanol transitions which produce observed masers. This allows to use pumping analysis for estimation of the physical parameters in the maser formation regions and its environment, for the study of their evolution. Extensive surveys in different masing transitions allow to conclude on the values of the temperatures, densities, dust properties, etc. in the bulk of masing regions. Variability of the brightest masers is monitored during several years. In some cases it is probably caused by the changes of the dust temperature which follow variations in the brightness of the central YSO reflecting the character of the accretion process. A unified catalogue of the class II methanol masers consisting of more than 500 objects is compiled. Analysis of the data shows that: physical conditions within the usual maser source vary considerably; maser brightness is determined by parameters of some distinguished part of the object - maser formation region; class II methanol masers are formed not within the outflows but in the regions affected by their propagation. It is shown that the "near" solutions for the kinematic distances to the sources can be used for statistical analysis. The luminosity function of the 6.7 GHz methanol masers is constructed. It is shown that improvement of the sensitivity of surveys can increase number of detected maser sources considerably.

  7. 6, 39453963, 2006 Methanol inside aged

    E-Print Network [OSTI]

    ACPD 6, 3945­3963, 2006 Methanol inside aged tropical biomass burning plumes G. Dufour et al. Title Chemistry and Physics Discussions First space-borne measurements of methanol inside aged tropical biomass. Dufour (gaelle.dufour@lmd.polytechnique.fr) 3945 #12;ACPD 6, 3945­3963, 2006 Methanol inside aged

  8. Air breathing direct methanol fuel cell

    DOE Patents [OSTI]

    Ren, Xiaoming (Los Alamos, NM)

    2002-01-01T23:59:59.000Z

    An air breathing direct methanol fuel cell is provided with a membrane electrode assembly, a conductive anode assembly that is permeable to air and directly open to atmospheric air, and a conductive cathode assembly that is permeable to methanol and directly contacting a liquid methanol source.

  9. Micro Fuel Cells Direct Methanol Fuel Cells

    E-Print Network [OSTI]

    Micro Fuel Cells TM Direct Methanol Fuel Cells for Portable Power A Fuel Cell System Developer-17, 2002 Phoenix, Arizona #12;Micro Fuel Cells Direct Methanol Fuel Cells for Portable Power Outline (1 Energy Content (Wh) Volume(cm^3) Li-Ion Battery DMFC #12;Direct Methanol Fuel Cell Technology

  10. Enhanced methanol utilization in direct methanol fuel cell

    DOE Patents [OSTI]

    Ren, Xiaoming (Los Alamos, NM); Gottesfeld, Shimshon (Los Alamos, NM)

    2001-10-02T23:59:59.000Z

    The fuel utilization of a direct methanol fuel cell is enhanced for improved cell efficiency. Distribution plates at the anode and cathode of the fuel cell are configured to distribute reactants vertically and laterally uniformly over a catalyzed membrane surface of the fuel cell. A conductive sheet between the anode distribution plate and the anodic membrane surface forms a mass transport barrier to the methanol fuel that is large relative to a mass transport barrier for a gaseous hydrogen fuel cell. In a preferred embodiment, the distribution plate is a perforated corrugated sheet. The mass transport barrier may be conveniently increased by increasing the thickness of an anode conductive sheet adjacent the membrane surface of the fuel cell.

  11. Technical evaluation and assessment of CNG/LPG bi-fuel and flex-fuel vehicle viability

    SciTech Connect (OSTI)

    Sinor, J E [Sinor (J.E.) Consultants, Inc., Niwot, CO (United States)

    1994-05-01T23:59:59.000Z

    This report compares vehicles using compressed natural gas (CNG), liquefied petroleum gas (LPG), and combinations of the two in bi-fuel or flex-fuel configurations. Evidence shows that environmental and energy advantages can be gained by replacing two-fuel CNG/gasoline vehicles with two-fuel or flex-fuel systems to be economically competitive, it is necessary to develop a universal CNG/LPG pressure-regulator-injector and engine control module to switch from one tank to the other. For flex-fuel CNG/LPG designs, appropriate composition sensors, refueling pumps, fuel tanks, and vaporizers are necessary.

  12. Direct methanol fuel cell and system

    DOE Patents [OSTI]

    Wilson, Mahlon S. (Los Alamos, NM)

    2004-10-26T23:59:59.000Z

    A fuel cell having an anode and a cathode and a polymer electrolyte membrane located between anode and cathode gas diffusion backings uses a methanol vapor fuel supply. A permeable polymer electrolyte membrane having a permeability effective to sustain a carbon dioxide flux equivalent to at least 10 mA/cm.sup.2 provides for removal of carbon dioxide produced at the anode by reaction of methanol with water. Another aspect of the present invention includes a superabsorpent polymer material placed in proximity to the anode gas diffusion backing to hold liquid methanol or liquid methanol solution without wetting the anode gas diffusion backing so that methanol vapor from the liquid methanol or liquid methanol-water solution is supplied to the membrane.

  13. Emissions from two methanol-powered buses

    SciTech Connect (OSTI)

    Ullman, T.L.; Hare, C.T.; Baines, T.M.

    1986-01-01T23:59:59.000Z

    Emissions from the two methanol-powered buses used in the California Methanol Bus Demonstration have been characterized. The M.A.N. SU 240 bus is powered by M.A.N.'s D2566 FMUH methanol engine, and utilizes catalytic exhaust aftertreatment. The GMC RTS II 04 bus is powered by a first-generation DDAD 6V-92TA methanol engine without exhaust aftertreatment. Emissions of HC, CO, NO/subX/, unburned methanol, aldehydes, total particulates, and the soluble fraction of particulate were determined for both buses over steady-state and transient chassis dynamometer test cycles. Emission levels from the M.A.N. bus were considerably lower than those from the GMC bus, with the exception of NO/subX/. Comparison of emission levels from methanol-and diesel-powered buses indicates that substantial reductions in emissions are possible with careful implementation of methanol fueling.

  14. Methanol production method and system

    DOE Patents [OSTI]

    Chen, Michael J. (Darien, IL); Rathke, Jerome W. (Bolingbrook, IL)

    1984-01-01T23:59:59.000Z

    Ethanol is selectively produced from the reaction of methanol with carbon monoxide and hydrogen in the presence of a transition metal carbonyl catalyst. Methanol serves as a solvent and may be accompanied by a less volatile co-solvent. The solution includes the transition metal carbonyl catalysts and a basic metal salt such as an alkali metal or alkaline earth metal formate, carbonate or bicarbonate. A gas containing a high carbon monoxide to hydrogen ratio, as is present in a typical gasifer product, is contacted with the solution for the preferential production of ethanol with minimal water as a byproduct. Fractionation of the reaction solution provides substantially pure ethanol product and allows return of the catalysts for reuse.

  15. Design, fabrication, and testing of a three-dimensional, plastically-deformed, monolithic compliant HexFlex Nanomanipulator

    E-Print Network [OSTI]

    Korb, Samuel N. (Samuel Noaa), 1984-

    2004-01-01T23:59:59.000Z

    An experimental study was performed to investigate the possibility of incorporating plastic deformation into a precision compliant mechanism design. The particular application of a compliant HexFlex Nanomanipulator was ...

  16. E85, Flex-Fuel Vehicles, and AB 1493 Integrating biofuels into California's vehicular greenhouse gas regulations

    E-Print Network [OSTI]

    Kammen, Daniel M.

    E85, Flex-Fuel Vehicles, and AB 1493 Integrating biofuels into California's vehicular greenhouse.................................................................................................. 5 1.1.3 CALIFORNIA CLEAN FUELS PROGRAM ....................................... 6 1.1.5 AB 1007: THE ALTERNATIVE FUELS PLAN

  17. Semi-flexible gas-insulated transmission line using sandwiched discs for intermittent flexing joints

    DOE Patents [OSTI]

    Kommineni, P.R.

    1983-02-15T23:59:59.000Z

    A gas-insulated transmission line includes an outer sheath, an inner conductor, an insulating gas electrically insulating the inner conductor from the outer sheath, and insulating supports insulatably supporting the inner conductor within the outer sheath. The inner conductor is provided with flexibility by the use of main conductor sections which are joined together through a conductor hub section and flexible flexing elements. Stress shields are provided to control the electric field at the locations of the conductor hub sections where the insulating supports are contacting the inner conductor. The flexing elements are formed by sandwiching together, by fusing, a pair of thin hollow discs which are fixedly secured to both the main conductor sections and the conductor hub section. 4 figs.

  18. Semi-flexible gas-insulated transmission line using sandwiched discs for intermittent flexing joints

    DOE Patents [OSTI]

    Kommineni, Prasad R. (Westboro, MA)

    1983-02-15T23:59:59.000Z

    A gas-insulated transmission line includes an outer sheath, an inner conductor, an insulating gas electrically insulating the inner conductor from the outer sheath, and insulating supports insulatably supporting the inner conductor within the outer sheath. The inner conductor is provided with flexibility by the use of main conductor sections which are joined together through a conductor hub section and flexible flexing elements. Stress shields are provided to control the electric field at the locations of the conductor hub sections where the insulating supports are contacting the inner conductor. The flexing elements are formed by sandwiching together, by fusing, a pair of thin hollow discs which are fixedly secured to both the main conductor sections and the conductor hub section.

  19. Methods of conditioning direct methanol fuel cells

    DOE Patents [OSTI]

    Rice, Cynthia (Newington, CT); Ren, Xiaoming (Menands, NY); Gottesfeld, Shimshon (Niskayuna, NY)

    2005-11-08T23:59:59.000Z

    Methods for conditioning the membrane electrode assembly of a direct methanol fuel cell ("DMFC") are disclosed. In a first method, an electrical current of polarity opposite to that used in a functioning direct methanol fuel cell is passed through the anode surface of the membrane electrode assembly. In a second method, methanol is supplied to an anode surface of the membrane electrode assembly, allowed to cross over the polymer electrolyte membrane of the membrane electrode assembly to a cathode surface of the membrane electrode assembly, and an electrical current of polarity opposite to that in a functioning direct methanol fuel cell is drawn through the membrane electrode assembly, wherein methanol is oxidized at the cathode surface of the membrane electrode assembly while the catalyst on the anode surface is reduced. Surface oxides on the direct methanol fuel cell anode catalyst of the membrane electrode assembly are thereby reduced.

  20. Methanol in the L1551 Circumbinary Torus

    E-Print Network [OSTI]

    Glenn J. White; C. W. M. Fridlund; P. Bergman; A. Beardsmore; Rene Liseau; R. R. Phillips

    2006-09-25T23:59:59.000Z

    We report observations of gaseous methanol in an edge-on torus surrounding the young stellar object L1551 IRS5. The peaks in the torus are separated by ~ 10,000 AU from L1551 IRS5, and contain ~ 0.03 earth masses of cold methanol. We infer that the methanol abundance increases in the outer part of the torus, probably as a result of methanol evaporation from dust grain surfaces heated by the shock luminosity associated with the shocks associated with the jets of an externally located x-ray source. Any methanol released in such a cold environment will rapidly freeze again, spreading methanol throughout the circumbinary torus to nascent dust grains, planitesimals, and primitive bodies. These observations probe the initial chemical conditions of matter infalling onto the disk.

  1. Air breathing direct methanol fuel cell

    DOE Patents [OSTI]

    Ren, Xiaoming (Los Alamos, NM); Gottesfeld, Shimshon (Los Alamos, NM)

    2002-01-01T23:59:59.000Z

    An air breathing direct methanol fuel cell is provided with a membrane electrode assembly, a conductive anode assembly that is permeable to air and directly open to atmospheric air, and a conductive cathode assembly that is permeable to methanol and directly contacting a liquid methanol source. Water loss from the cell is minimized by making the conductive cathode assembly hydrophobic and the conductive anode assembly hydrophilic.

  2. Method of steam reforming methanol to hydrogen

    DOE Patents [OSTI]

    Beshty, Bahjat S. (Lower Makefield, PA)

    1990-01-01T23:59:59.000Z

    The production of hydrogen by the catalyzed steam reforming of methanol is accomplished using a reformer of greatly reduced size and cost wherein a mixture of water and methanol is superheated to the gaseous state at temperatures of about 800.degree. to about 1,100.degree. F. and then fed to a reformer in direct contact with the catalyst bed contained therein, whereby the heat for the endothermic steam reforming reaction is derived directly from the superheated steam/methanol mixture.

  3. Alternative Fuels Data Center: Methanol

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadapInactiveVisiting the TWP TWP RelatedCellulaseFuels and VehiclesMethanol to someone by

  4. Microbial community response to a release of neat ethanol onto residual hydrocarbons in a pilot-scale

    E-Print Network [OSTI]

    Alvarez, Pedro J.

    Microbial community response to a release of neat ethanol onto residual hydrocarbons in a pilot ethanol release (E100, 76 l) onto residual hydrocarbons in sandy soil was evaluated in a continuous-flow 8 shifts were assessed using quantitative real-time PCR analysis. High ethanol concentrations

  5. Recovery of methanol in an MTBE process

    SciTech Connect (OSTI)

    Whisenhunt, D.E.; Byers, G.L.; Hattiangadi, U.S.

    1988-05-31T23:59:59.000Z

    In a process for the manufacture of methyltertiarybutylether (MTBE) in which methanol and a mixture of C/sub 4/ hydrocarbons containing isobutylene are contacted in a reaction zone containing an ion-exchange resin catalyst under suitable conditions to effect the reaction of methanol and isobutylene to produce a reaction product containing MTBE, unreacted methanol, unreacted isobutylene and other C/sub 4/ hydrocarbons, the reaction product is introduced to a fractionation zone wherein it is separated into a bottoms product comprising essentially MTBE and an overhead product containing unreacted methanol, unreacted isobutylene, and other C/sub 4/ hydrocarbons, and the overhead product is introduced to an absorption zone wherein the methanol is absorbed; the improvement is described which comprises utilizing silica gel as adsorbent and regenerating the silica gel adsorbent in a closed loop by contacting the silica gel absorbent with a desorption gas stream at an elevated temperature for a sufficient period of time to remove absorbed methanol, cooling the effluent from the adsorption zone to condense desorbed methanol removing desorbed methanol from the system and recycling the desorption gas to the adsorption zone.

  6. Methanol from biomass via steam gasification

    SciTech Connect (OSTI)

    Coffman, J.A. [Wright-Malta Corp., Ballston Spa, NY (United States)

    1995-12-31T23:59:59.000Z

    R&D at Wright-Malta on gasification of biomass, and use of this gas in methanol synthesis, has now reached the stage where a demonstration plant is feasible. The gasifier has evolved into a long, slender, slightly declined, graded temperature stationary kiln, with a box beam rotor and twin piston feed. The methanol reactor is envisioned as a smaller, more declined, graded temperature, water-filled kiln, with a multi-pipe rotor. Input to the demo plant will be 100 tons/day of green (45% water) wood chips; output will be 11,000 gal/day of methanol and 7500 lbs/hr of steam. The over-all biomass to methanol system is tightly integrated in its mechanical design to take full advantage of the reactivity of biomass under a slow, steady, steamy pressurized cook, and the biomass pyrolysis and methanol synthesis exotherms. This is expected to yield good energy efficiency, environmental attractiveness, and economical operation.

  7. (Non) formation of methanol by direct hydrogenation of formate...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (Non) formation of methanol by direct hydrogenation of formate on copper catalysts. (Non) formation of methanol by direct hydrogenation of formate on copper catalysts. Abstract: We...

  8. A Theoretical Study of Methanol Oxidation Catalyzed by Isolated...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Methanol Oxidation Catalyzed by Isolated Vanadia Clusters Supported on the (101) Surface of Anatase. A Theoretical Study of Methanol Oxidation Catalyzed by Isolated Vanadia...

  9. Novel Approach to Advanced Direct Methanol Fuel Cell Anode Catalysts...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Approach to Advanced Direct Methanol Fuel Cell Anode Catalysts Novel Approach to Advanced Direct Methanol Fuel Cell Anode Catalysts Presented at the Department of Energy Fuel Cell...

  10. Novel Materials for High Efficiency Direct Methanol Fuel Cells...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Materials for High Efficiency Direct Methanol Fuel Cells Novel Materials for High Efficiency Direct Methanol Fuel Cells Presented at the Department of Energy Fuel Cell Projects...

  11. Bifunctional Anode Catalysts for Direct Methanol Fuel Cells....

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Anode Catalysts for Direct Methanol Fuel Cells. Bifunctional Anode Catalysts for Direct Methanol Fuel Cells. Abstract: Using the binding energy of OH* and CO* on close-packed...

  12. Capacity additions ease tight methanol supply

    SciTech Connect (OSTI)

    Greek, B.F. (C and EN, Houston, TX (US))

    1988-10-03T23:59:59.000Z

    Two menthanol plants now in operation - one in the U.S., the other in Chile - will boost global supplies of methanol more than 375 million gal annually. This large capacity addition and smaller expansions in other parts of the world will exceed demand growth during 1988 and 1989, easing the squeeze on supplies. As the result of increased supplies, methanol prices could slip slightly in the fourth quarter. They are more likely to decline next year, however. The two plants, which started up in August, are owned and operated by Tenneco Oil Co. Processing and Marketing and by Cape Horn Methanol (CHM). The Tenneco plant, located in Pasadena, Tex., was restarted after a shutdown in 1982 when prices for methanol were low. It now is running at full capacity of 125 million gal per year. The plant uses the low-pressure process technology of Lurgi, reportedly requiring for feedstock and energy between 100,000 and 125,000 cu ft of methane per gallon. Global trade in methanol smooths out the supply and demand inconsistencies. Surging methanol demand in the U.S. and in Western Europe has been met by imports from areas where methanol production is most economical - that is, where natural gas is readily available and has no other application as high in value. Canada, Chile, and Trinidad are examples of those areas.

  13. Total to withdraw from Qatar methanol - MTBE?

    SciTech Connect (OSTI)

    NONE

    1996-05-01T23:59:59.000Z

    Total is rumored to be withdrawing from the $700-million methanol and methyl tert-butyl ether (MTBE) Qatar Fuel Additives Co., (Qafac) project. The French company has a 12.5% stake in the project. Similar equity is held by three other foreign investors: Canada`s International Octane, Taiwan`s Chinese Petroleum Corp., and Lee Change Yung Chemical Industrial Corp. Total is said to want Qafac to concentrate on methanol only. The project involves plant unit sizes of 610,000 m.t./year of MTBE and 825,000 m.t./year of methanol. Total declines to comment.

  14. Methanol engine conversion feasibility study: Phase 1

    SciTech Connect (OSTI)

    Not Available

    1983-03-01T23:59:59.000Z

    This report documents the selection of the surface-assisted ignition technique to convert two-stroke Diesel-cycle engines to methanol fuel. This study was the first phase of the Florida Department of Transportation methanol bus engine development project. It determined both the feasibility and technical approach for converting Diesel-cycle engines to methanol fuel. State-of-the-art conversion options, associated fuel formulations, and anticipated performance were identified. Economic considerations and technical limitations were examined. The surface-assisted conversion was determined to be feasible and was recommended for hardware development.

  15. MINOR PLANET 2002 EX{sub 12} (=169P/NEAT) AND THE ALPHA CAPRICORNID SHOWER

    SciTech Connect (OSTI)

    Jenniskens, P. [SETI Institute, 515 N. Whisman Road, Mountain View, CA 94043 (United States); Vaubaillon, J. [I.M.C.C.E., Paris Observatory, 77 Av. Denfert Rochereau, 75014 Paris (France)], E-mail: Petrus.M.Jenniskens@nasa.gov

    2010-05-15T23:59:59.000Z

    Minor planet 2002 EX{sub 12} (=comet 169P/NEAT) is identified as the parent body of the alpha Capricornid shower, based on a good agreement in the calculated and observed direction and speed of the approaching meteoroids for ejecta 4500-5000 years ago. The meteoroids that come to within 0.05 AU of Earth's orbit show the correct radiant position, radiant drift, approach speed, radiant dispersion, duration of activity, and distribution of dust at the other node, but meteoroids ejected 5000 years ago by previously proposed parent bodies do not. A more recent formation epoch is excluded because not enough dust would have evolved into Earth's path. The total mass of the stream is about 9 x 10{sup 13} kg, similar to that of the remaining comet. Release of so much matter in a short period of time implies a major disruption of the comet at that time. The bulk of this matter still passes inside Earth's orbit, but will cross Earth's orbit 300 years from now. As a result, the alpha Capricornids are expected to become a major annual shower in 2220-2420 A.D., stronger than any current annual shower.

  16. Fabrication and long-wavelength characterization of neat and chemically modified graphene

    SciTech Connect (OSTI)

    Kalugin, Nikolai G. [Departments of Materials Engineering and Chemistry, New Mexico Tech, Socorro, NM 87801 (United States)

    2014-03-31T23:59:59.000Z

    Graphene, a single- or several layer-thick carbon, attracts significant research activity because of its exceptional material properties. Graphene is a promising material for optoelectronic applications. Neat graphene demonstrates potential as a material for long wavelength photodetectors working at elevated temperatures. Chemical modification of graphene opens up many new applications of this material in electronics, in new composite materials, and in new catalysts for different chemical processes. Chemical vapor deposition-grown large-area graphene can be successfully modified with the creation of benzyne attachments. The investigation of microwave properties is an important part of graphene research. Two variants of near-field long wavelength microscopy were found efficient with graphene. Measurements with a probe formed by an electrically open end of a 4 GHz half-lambda parallel-strip transmission line resonator allow the implementation of an electrodynamic model of graphene microwave impedance. The results of near-field scanning superconducting quantum interference device (SQUID) RF microscopy of graphite and graphene at 200 MHz shed light on mechanisms of AC graphene response: screening currents induced in graphene by an external RF magnetic field tend to localize near structural defects.

  17. Methanol Maser Polarization in W3(OH)

    E-Print Network [OSTI]

    W. H. T. Vlemmings; L. Harvey-Smith; R. J. Cohen

    2006-06-13T23:59:59.000Z

    We present the first 6.7 GHz methanol maser linear polarization map of the extended filamentary maser structure around the compact HII region W3(OH). The methanol masers show linear polarization up to 8 per cent and the polarization angles indicate a magnetic field direction along the North-South maser structure. The polarization angles are consistent with those measured for the OH masers, taking into account external Faraday rotation toward W3(OH), and confirm that the OH and methanol masers are found in similar physical conditions. Additionally we discuss the Zeeman splitting of the 6.7 GHz methanol transition and present an upper limit of ~22 mG for the magnetic field strength in the maser region. The upper limit is fully consistent with the field strengths derived from OH maser Zeeman splitting.

  18. Homogeneous catalyst formulations for methanol production

    DOE Patents [OSTI]

    Mahajan, Devinder (Port Jefferson, NY); Sapienza, Richard S. (Shoreham, NY); Slegeir, William A. (Hampton Bays, NY); O'Hare, Thomas E. (Huntington Station, NY)

    1991-02-12T23:59:59.000Z

    There is disclosed synthesis of CH.sub.3 OH from carbon monoxide and hydrogen using an extremely active homogeneous catalyst for methanol synthesis directly from synthesis gas. The catalyst operates preferably between 100.degree.-150.degree. C. and preferably at 100-150 psia synthesis gas to produce methanol. Use can be made of syngas mixtures which contain considerable quantities of other gases, such as nitrogen, methane or excess hydrogen. The catalyst is composed of two components: (a) a transition metal carbonyl complex and (b) an alkoxide component. In the simplest formulation, component (a) is a complex of nickel tetracarbonyl and component (b) is methoxide (CH.sub.3 O.sup.-), both being dissolved in a methanol solvent system. The presence of a co-solvent such as p-dioxane, THF, polyalcohols, ethers, hydrocarbons, and crown ethers accelerates the methanol synthesis reaction.

  19. Homogeneous catalyst formulations for methanol production

    DOE Patents [OSTI]

    Mahajan, Devinder (Port Jefferson, NY); Sapienza, Richard S. (Shoreham, NY); Slegeir, William A. (Hampton Bays, NY); O'Hare, Thomas E. (Huntington Station, NY)

    1990-01-01T23:59:59.000Z

    There is disclosed synthesis of CH.sub.3 OH from carbon monoxide and hydrogen using an extremely active homogeneous catalyst for methanol synthesis directly from synthesis gas. The catalyst operates preferably between 100.degree.-150.degree. C. and preferably at 100-150 psia synthesis gas to produce methanol. Use can be made of syngas mixtures which contain considerable quantities of other gases, such as nitrogen, methane or excess hydrogen. The catalyst is composed of two components: (a) a transition metal carbonyl complex and (b) an alkoxide component. In the simplest formulation, component (a) is a complex of nickel tetracarbonyl and component (b) is methoxide (CH.sub.3 O.sup.13 ), both being dissolved in a methanol solvent system. The presence of a co-solvent such as p-dioxane, THF, polyalcohols, ethers, hydrocarbons, and crown ethers accelerates the methanol synthesis reaction.

  20. Mit Methanol iridiumkatalysiert C-C-Bindungen knpfen

    E-Print Network [OSTI]

    Meyer, Karsten

    Mit Methanol iridiumkatalysiert C-C-Bindungen knüpfen i Die Reaktivität von Methanol (1) beruht meist auf dem nucleophilen Sauerstoffatom. Obwohl Methanol industriell im Monsanto-Prozess carbo, dass Methanol iridiumkatalysiert leicht an Allene (2) addiert. Damit entstehen 2,2-disub- stituierte

  1. Vacuum-ultraviolet (VUV) photoionization of small methanol and methanol-water clusters

    SciTech Connect (OSTI)

    Ahmed, Musahid; Ahmed, Musahid; Wilson, Kevin R.; Belau, Leonid; Kostko, Oleg

    2008-05-12T23:59:59.000Z

    In this work we report on thevacuum-ultraviolet (VUV) photoionization of small methanol and methanol-water clusters. Clusters of methanol with water are generated via co-expansion of the gas phase constituents in a continuous supersonic jet expansion of methanol and water seeded in Ar. The resulting clusters are investigated by single photon ionization with tunable vacuumultraviolet synchrotron radiation and mass analyzed using reflectron mass spectrometry. Protonated methanol clusters of the form (CH3OH)nH + (n=1-12) dominate the mass spectrum below the ionization energy of the methanol monomer. With an increase in water concentration, small amounts of mixed clusters of the form (CH3OH)n(H2O)H + (n=2-11) are detected. The only unprotonated species observed in this work are the methanol monomer and dimer. Appearance energies are obtained from the photoionization efficiency (PIE) curves for CH3OH +, (CH 3OH)2 +, (CH3OH)nH + (n=1-9), and (CH 3OH)n(H2O)H + (n=2-9 ) as a function of photon energy. With an increase in the water content in the molecular beam, there is an enhancement of photoionization intensity for methanol dimer and protonated methanol monomer at threshold. These results are compared and contrasted to previous experimental observations.

  2. Vacuum-Ultraviolet (VUV) Photoionization of Small Methanol and Methanol-Water Clusters

    SciTech Connect (OSTI)

    Kostko, Oleg; Belau, Leonid; Wilson, Kevin R.; Ahmed, Musahid

    2008-04-24T23:59:59.000Z

    In this work, we report on the vacuum-ultraviolet (VUV) photoionization of small methanol and methanol-water clusters. Clusters of methanol with water are generated via co-expansion of the gas phase constituents in a continuous supersonic jet expansion of methanol and water seeded in Ar. The resulting clusters are investigated by single photon ionization with tunable vacuum-ultraviolet synchrotron radiation and mass analyzed using reflectron mass spectrometry. Protonated methanol clusters of the form (CH3OH)nH+(n = 1-12) dominate the mass spectrum below the ionization energy of the methanol monomer. With an increase in water concentration, small amounts of mixed clusters of the form (CH3OH n(H2O)H+ (n = 2-11) are detected. The only unprotonated species observed in this work are the methanol monomer and dimer. Appearance energies are obtained from the photoionization efficiency (PIE) curves for CH3OH+, (CH3OH)2+, (CH3OH)nH+ (n = 1-9), and (CH3OH)n(H2O)H+ (n = 2-9) as a function of photon energy. With an increasein the water content in the molecular beam, there is an enhancement of photoionization intensity for the methanol dimer and protonated methanol monomer at threshold. These results are compared and contrasted to previous experimental observations.

  3. Methanol-tolerant cathode catalyst composite for direct methanol fuel cells

    DOE Patents [OSTI]

    Zhu, Yimin (Los Alamos, NM); Zelenay, Piotr (Los Alamos, NM)

    2006-09-05T23:59:59.000Z

    A direct methanol fuel cell (DMFC) having a methanol fuel supply, oxidant supply, and its membrane electrode assembly (MEA) formed of an anode electrode and a cathode electrode with a membrane therebetween, a methanol oxidation catalyst adjacent the anode electrode and the membrane, an oxidant reduction catalyst adjacent the cathode electrode and the membrane, comprises an oxidant reduction catalyst layer of Pt.sub.3Cr/C so that oxidation at the cathode of methanol that crosses from the anode through the membrane to the cathode is reduced with a concomitant increase of net electrical potential at the cathode electrode.

  4. Methanol-Tolerant Cathode Catalyst Composite For Direct Methanol Fuel Cells

    DOE Patents [OSTI]

    Zhu, Yimin (Los Alamos, NM); Zelenay, Piotr (Los Alamos, NM)

    2006-03-21T23:59:59.000Z

    A direct methanol fuel cell (DMFC) having a methanol fuel supply, oxidant supply, and its membrane electrode assembly (MEA) formed of an anode electrode and a cathode electrode with a membrane therebetween, a methanol oxidation catalyst adjacent the anode electrode and the membrane, an oxidant reduction catalyst adjacent the cathode electrode and the membrane, comprises an oxidant reduction catalyst layer of a platinum-chromium alloy so that oxidation at the cathode of methanol that crosses from the anode through the membrane to the cathode is reduced with a concomitant increase of net electrical potential at the cathode electrode.

  5. Methanol plant ship: Appendix. Export trade information

    SciTech Connect (OSTI)

    Not Available

    1988-07-30T23:59:59.000Z

    The document is an appendix to the final report on a proposed methanol plant ship off of the coast of Trinidad. The document incorporates the results of the redetermination of capital required to implement the project. It also presents a revised cost analysis, with better accuracy, for the project. The projected operating revenues and revised expenses are also given. As a continuation of the information presented in the final report, the methanol market and proposed products are discussed in the report.

  6. Methanol synthesis in a trickle bed reactor

    E-Print Network [OSTI]

    Tjandra, Sinoto

    1992-01-01T23:59:59.000Z

    chemicals, which can not be synthesized directly and in high selectivity from synthesis gas (King and Grate, 1985). Methanol synthesis was first shown to be feasible by Mittash and Schneider (1913). In the 1920s, BASF introduced the first industrial... that illustrated a significant achievement in catalyst specificity because methanol is thermodynamically the least favorable product of all other products which can be synthesized from synthesis gas. The first industrial process developed by BASF in 1920s used a...

  7. WATER PRODUCTION IN COMETS 2001 Q4 (NEAT) AND 2002 T7 (LINEAR) DETERMINED FROM SOHO/SWAN OBSERVATIONS

    SciTech Connect (OSTI)

    Combi, M. R.; Lee, Y. [Department of Atmospheric, Oceanic and Space Sciences, University of Michigan, 2455 Hayward Street, Ann Arbor, MI 48109-2143 (United States); Maekinen, J. T. T. [Finnish Meteorological Institute, Box 503, SF-00101 Helsinki (Finland); Bertaux, J.-L.; Quemerais, E. [Centre National de la Recherche Scientifique, Service d'Aeronomie, BP3, 91371 Verrieres le Buisson Cedex (France)], E-mail: mcombi@umich.edu

    2009-06-15T23:59:59.000Z

    The SWAN all-sky camera on the Solar and Heliospheric Observatory (SOHO) spacecraft detected the hydrogen Lyman-alpha (Ly{alpha}) comae of comets 2001 Q4 NEAT and 2002 T7 LINEAR for large portions of their perihelion apparitions in 2003 and 2004. C/2001 Q4 NEAT was observed from 2003 September 14 through 2004 November 2, covering heliocentric distances from 3.23 AU before perihelion to 2.75 AU after, and C/2002 T7 LINEAR was observed from 2003 December 4 through 2004 August 6, covering heliocentric distances from 2.52 AU before perihelion to 2.09 AU after. We combined the full set of comet specific and full-sky observations and used our time-resolved model (TRM), which enables us to extract continuous values of the daily-average value of the water production rate throughout most of this entire period. The average power-law fit to the production rate variation of C/2001 Q4 NEAT with heliocentric distance, r, gives 3.5 x 10{sup 29} r {sup -1.7} and that for C/2002 T7 LINEAR gives 4.6 x 10{sup 29} r {sup -2.0}. Both comets show roughly a factor of 2 asymmetry in activity about perihelion, being more active before perihelion. C/2001 Q4 NEAT showed a production rate outburst about 30 days before perihelion (2004 April 15) and then a large extended increase above the nominal trend from 50 to 70 days after perihelion (2004 July 5-July 25)

  8. Technology and economics of gas utilization: Methanol

    SciTech Connect (OSTI)

    Seddon, D.

    1994-12-31T23:59:59.000Z

    The paper reviews the current and emerging technology for the conversion of natural gas into methanol and assesses its impact on the production economics. Technologies of potential use for offshore developments of large gas reserves or associated gas are discussed. New technologies for the production of methanol synthesis-gas, such as autothermal reforming and GHR technology, are described and the economic advantages over conventional steam reforming are quantified. New methanol synthesis technology, such as slurry phase reactors, are outlined but appear to offer little advantage over conventional technology for offshore gas utilization. The purification of methanol for fuel and chemical grade product is outlined and the cost of transport presented. The data presented gives an overview of the production costs for production of methanol from large gas reserves (> 1Tcf, 25--35PJ/a) and smaller scale reserves (10--20MMscfd, 4--10PJ/a). The variation of the production cost of methanol with gas price indicates that the gas price is the principal economic consideration. However, adoption of new technology will improve production economics by an amount equivalent to an incremental gas cost of about $0.5/GJ. For gas reserves of low development cost, the adoption of new technology is not a prerequisite to economic viability.

  9. Consistency in the Sum Frequency Generation Intensity and Phase Vibrational Spectra of the Air/Neat Water Interface

    SciTech Connect (OSTI)

    Feng, Ranran; Guo, Yuan; Lu, Rong; Velarde Ruiz Esparza, Luis A.; Wang, Hongfei

    2011-06-16T23:59:59.000Z

    Tremendous progresses have been made in quantitative understanding and interpretation of the hydrogen bonding and ordering structure at the air/water interface since the first sum-frequency generation vibrational spectroscopy (SFG-VS) measurement on the neat air/water interface by Q. Du et al. in 1993 (PRL, 70, 2312-2316, 1993.). However, there are still disagreements and controversies on the consistency between the different experiment measurements and the theoretical computational results. One critical problem lies in the inconsistency between the SFG-VS intensity measurements and the recently developed SFG-VS phase spectra measurements of the neat air/water interface, which has inspired various theoretical efforts trying to understand them. In this report, the reliability of the SFG-VS intensity spectra of the neat air/water interface is to be quantitatively examined, and the sources of possible inaccuracies in the SFG-VS phase spectral measurement is to be discussed based on the non-resonant SHG phase measurement results. The conclusion is that the SFG-VS intensity spectra data from different laboratories are now quantitatively converging and in agreement with each other, and the possible inaccuracies and inconsistencies in the SFG-VS phase spectra measurements need to be carefully examined against the properly corrected phase standard.

  10. Pd and Pd-Cu Alloy Deposited Nafion Membranes for Reduction of Methanol Crossover in Direct Methanol

    E-Print Network [OSTI]

    Zhao, Tianshou

    Pd and Pd-Cu Alloy Deposited Nafion Membranes for Reduction of Methanol Crossover in Direct Methanol Fuel Cells J. Prabhuram, T. S. Zhao,*,z Z. X. Liang, H. Yang, and C. W. Wong Department Kong, China To reduce methanol crossover in direct methanol fuel cells DMFCs , Nafion 115 membrane

  11. Far-ultraviolet observations of comet C/2001 Q4 (NEAT) with FIMS/SPEAR

    SciTech Connect (OSTI)

    Lim, Y.-M.; Min, K.-W. [Korea Advanced Institute of Science and Technology (KAIST), 291 Daehak-ro, Yuseong-gu, Daejeon 305-701 (Korea, Republic of); Feldman, P. D. [Department of Physics and Astronomy, Johns Hopkins University, 3400 North Charles Street, Baltimore, MD 21218 (United States); Han, W. [Korea Astronomy and Space Science Institute (KASI), 776 Daedeokdae-ro, Yuseong-gu, Daejeon 305-348 (Korea, Republic of); Edelstein, J., E-mail: ymlim@kaist.ac.kr [Space Sciences Laboratory, University of California, Berkeley, 7 Gauss Way, Berkeley, CA 94720 (United States)

    2014-02-01T23:59:59.000Z

    We present the results of far-ultraviolet observations of comet C/2001 Q4 (NEAT) that were made with the Far-Ultraviolet Imaging Spectrograph on board the Korean satellite STSAT-1. The observations were conducted in two campaigns during its perihelion approach between 2004 May 8 and 15. Based on the scanning mode observations in the wavelength band of 1400-1700 Å, we have constructed an image of the comet with an angular size of 5°×5°, which corresponds to the central coma region. Several important fluorescence emission lines were detected including S I multiplets at 1429 and 1479 Å, C I multiplets at 1561 and 1657 Å, and the CO A{sup 1}?-X{sup 1}?{sup +} Fourth Positive system; we have estimated the production rates of the corresponding species from the fluxes of these emission lines. The estimated production rate of CO was Q {sub CO} = (2.65 ± 0.63) × 10{sup 28} s{sup –1}, which is 6.2%-7.4% of the water production rate and is consistent with earlier predictions. The average carbon production rate was estimated to be Q{sub C} = ?1.59 × 10{sup 28} s{sup –1}, which is ?60% of the CO production rate. However, the observed carbon profile was steeper than that predicted using the two-component Haser model in the inner coma region, while it was consistent with the model in the outer region. The average sulfur production rate was Q{sub S} = (4.03±1.03) × 10{sup 27} s{sup –1}, which corresponds to ?1% of the water production rate.

  12. ESTIMATION OF ETHANOL CONTENT IN FLEX-FUEL VEHICLES USING AN EXHAUST GAS OXYGEN SENSOR: MODEL, TUNING AND SENSITIVITY

    E-Print Network [OSTI]

    Stefanopoulou, Anna

    ESTIMATION OF ETHANOL CONTENT IN FLEX-FUEL VEHICLES USING AN EXHAUST GAS OXYGEN SENSOR: MODEL periods of intense interest in using ethanol as an alternative fuel to petroleum-based gasoline and diesel derivatives. Currently available flexible fuel vehicles (FFVs) can operate on a blend of gasoline and ethanol

  13. Preferential oxidation of methanol and carbon monoxide for gas cleanup during methanol fuel processing

    SciTech Connect (OSTI)

    Birdsell, S.A.; Vanderborgh, N.E.; Inbody, M.A. [Los Alamos National Lab., NM (United States)

    1993-07-01T23:59:59.000Z

    Methanol fuel processing generates hydrogen for low-temperature, PEM fuel cell systems now being considered for transportation and other applications. Although liquid methanol fuel is convenient for this application, existing fuel processing techniques generate contaminants that degrade fuel cell performance. Through mathematical models and laboratory experiments chemical processing is described that removes CO and other contaminants from the anode feed stream.

  14. Electronic Effect in Methanol Dehydrogenation on Pt Surfaces: Potential Control during Methanol Electrooxidation

    E-Print Network [OSTI]

    Park, Byungwoo

    advanced insight into the design of an optimal catalyst as the anode for direct methanol fuel cells. SECTION: Energy Conversion and Storage; Energy and Charge Transport Fuel cells are promising alternative energy conversion. Polymer electrolyte membrane fuel cells (PEMFCs) and direct methanol fuel cells (DMFCs

  15. Design of Experiments to Determine Causes of Flex Cable Solder Wicking, Discoloration and Hole Location Defects

    SciTech Connect (OSTI)

    Wolfe, Larry

    2009-04-22T23:59:59.000Z

    Design of Experiments (DoE) were developed and performed in an effort to discover and resolve the causes of three different manufacturing issues; large panel voids after Hot Air Solder Leveling (HASL), cable hole locations out of tolerance after lamination and delamination/solder wicking around flat flex cable circuit lands after HASL. Results from a first DoE indicated large panel voids could be eliminated by removing the pre-HASL cleaning. It also revealed eliminating the pre-HASL bake would not be detrimental when using a hard press pad lamination stackup. A second DoE indicated a reduction in hard press pad stackup lamination pressure reduced panel stretch in the y axis approximately 70%. A third DoE illustrated increasing the pre-HASL bake temperature could reduce delamination/solder wicking when using a soft press pad lamination stackup.

  16. Falling MTBE demand bursts the methanol bubble

    SciTech Connect (OSTI)

    Wiesmann, G.; Cornitius, T.

    1995-03-01T23:59:59.000Z

    Methanol spot markets in Europe and the US have been hit hard by weakening demand from methyl tert-butyl ether (MTBE) producers. In Europe, spot prices for domestic T2 product have dropped to DM620-DM630/m.t. fob from early-January prices above DM800/m.t. and US spot prices have slipped to $1.05/gal fob from $1.35/gal. While chemical applications for methanol show sustained demand, sharp methanol hikes during 1994 have priced MTBE out of the gasoline-additive market. {open_quotes}We`ve learned an important lesson. We killed [MTBE] applications in the rest of the world,{close_quotes} says one European methanol producer. Even with methanol currently at DM620/m.t., another manufacturer points out, MTBE production costs still total $300/m.t., $30/m.t. more than MTBE spot prices. Since late 1994, Europe`s 3.3-million m.t./year MTBE production has been cut back 30%.

  17. Methanol from biomass via steam gasification

    SciTech Connect (OSTI)

    Coffman, J.A. [Wright-Malta Corp., Ballston Spa, NY (United States)

    1995-12-31T23:59:59.000Z

    R & D at Wright-Malta on gasification of biomass, and use of this gas in methanol synthesis, has now reached the stage where a demonstration plant is feasible. The gasifier has evolved into a long, slender, slightly declined, graded temperature series of stationary kiln sections, with box beam rotors and twin piston feed. The methanol reactor is envisioned as a smaller, more declined, graded temperature, water-filled stationary kiln, with a multi-pipe rotor. Input to the demo plant will be 100 tons/day of green (45% water) wood chips; output is projected at 11,000 gal/day of methanol and 7500 lbs/hr of steam. The over-all biomass to methanol system is tightly integrated in its mechanical design to take full advantage of the reactivity of biomass under a slow, steady, steamy pressurized cook, and the biomass pyrolysis and methanol synthesis exotherms. This is expected to yield good energy efficiency, environmental attractiveness, and economical operation.

  18. Comparison of Methanol Exposure Routes Reported to Texas Poison Control Centers

    E-Print Network [OSTI]

    Givens, Melissa; Kalbfleisch, Kristine; Bryson, Scott

    2008-01-01T23:59:59.000Z

    guidelines on the treatment of methanol poisoning, J ToxicolHantson PE, Acute methanol intoxication: physiopathology,The toxicity of inhaled methanol vapors, Crit Rev Toxicol.

  19. Methanol sensor operated in a passive mode

    DOE Patents [OSTI]

    Ren, Xiaoming (Los Alamos, NM); Gottesfeld, Shimshon (Los Alamos, NM)

    2002-01-01T23:59:59.000Z

    A sensor outputs a signal related to a concentration of methanol in an aqueous solution adjacent the sensor. A membrane electrode assembly (MEA) is included with an anode side and a cathode side. An anode current collector supports the anode side of the MEA and has a flow channel therethrough for flowing a stream of the aqueous solution and forms a physical barrier to control access of the methanol to the anode side of the MEA. A cathode current collector supports the cathode side of the MEA and is configured for air access to the cathode side of the MEA. A current sensor is connected to measure the current in a short circuit across the sensor electrodes to provide an output signal functionally related to the concentration of methanol in the aqueous solution.

  20. Thermally integrated staged methanol reformer and method

    DOE Patents [OSTI]

    Skala, Glenn William (Churchville, NY); Hart-Predmore, David James (Rochester, NY); Pettit, William Henry (Rochester, NY); Borup, Rodney Lynn (East Rochester, NY)

    2001-01-01T23:59:59.000Z

    A thermally integrated two-stage methanol reformer including a heat exchanger and first and second reactors colocated in a common housing in which a gaseous heat transfer medium circulates to carry heat from the heat exchanger into the reactors. The heat transfer medium comprises principally hydrogen, carbon dioxide, methanol vapor and water vapor formed in a first stage reforming reaction. A small portion of the circulating heat transfer medium is drawn off and reacted in a second stage reforming reaction which substantially completes the reaction of the methanol and water remaining in the drawn-off portion. Preferably, a PrOx reactor will be included in the housing upstream of the heat exchanger to supplement the heat provided by the heat exchanger.

  1. 37 GHz METHANOL MASERS : HORSEMEN OF THE APOCALYPSE FOR THE CLASS II METHANOL MASER PHASE?

    SciTech Connect (OSTI)

    Ellingsen, S. P.; Breen, S. L. [School of Mathematics and Physics, University of Tasmania, Private Bag 37, Hobart, TAS 7001 (Australia); Sobolev, A. M. [Astronomical Observatory, Ural Federal University, Lenin avenue 51, 620000 Ekaterinburg (Russian Federation); Voronkov, M. A.; Caswell, J. L. [CSIRO Astronomy and Space Science, Australia Telescope National Facility, P.O. Box 76, Epping, NSW 1710 (Australia); Lo, N., E-mail: Simon.Ellingsen@utas.edu.au [Departamento de Astronomia, Universidad de Chile, Camino El Observatorio 1515, Las Condes, Santiago, Casilla 36-D (Chile)

    2011-12-01T23:59:59.000Z

    We report the results of a search for class II methanol masers at 37.7, 38.3, and 38.5 GHz toward a sample of 70 high-mass star formation regions. We primarily searched toward regions known to show emission either from the 107 GHz class II methanol maser transition, or from the 6.035 GHz excited OH transition. We detected maser emission from 13 sources in the 37.7 GHz transition, eight of these being new detections. We detected maser emission from three sources in the 38 GHz transitions, one of which is a new detection. We find that 37.7 GHz methanol masers are only associated with the most luminous 6.7 and 12.2 GHz methanol maser sources, which in turn are hypothesized to be the oldest class II methanol sources. We suggest that the 37.7 GHz methanol masers are associated with a brief evolutionary phase (of 1000-4000 years) prior to the cessation of class II methanol maser activity in the associated high-mass star formation region.

  2. Methanex considers methanol, MTBE in Qatar

    SciTech Connect (OSTI)

    NONE

    1995-12-13T23:59:59.000Z

    CW has learned that Methanex Corp. is considering entering one of two methanol and methyl tert-butyl ether (MTBE) projects in Qatar. Executive v.p. Michael Wilson says that part of the company`s New Zealand plant could be moved to a site in Qatar, which would lower capital costs for the possible project by $75 million-$100 million. Both Qatar General Petroleum Corp. and Qatar Fuel Additives are developing methanol and MTBE projects at Umm Said, Qatar. Methanex says its goal is to ensure low-cost feedstocks.

  3. COMET 169P/NEAT(=2002 EX{sub 12}): THE PARENT BODY OF THE {alpha}-CAPRICORNID METEOROID STREAM

    SciTech Connect (OSTI)

    Kasuga, Toshihiro; Wiegert, Paul A. [Department of Physics and Astronomy, The University of Western Ontario, 1151 Richmond Street London, ON N6A 3K7 (Canada); Balam, David D., E-mail: tkasuga@uwo.c [Dominion Astrophysical Observatory, Herzberg Institute of Astrophysics, National Research Council Canada, Government of Canada, 5071 West Saanich Road, Victoria, BC (Canada)

    2010-12-15T23:59:59.000Z

    The Jupiter-family comet 169P/NEAT (previously known as asteroid 2002 EX{sub 12}) has a dynamical association with the {alpha}-Capricornid meteoroid stream. In this paper, we present photometric observations of comet 169P/NEAT to further investigate the physical characters of its disintegration state related to the stream. The comet shows a point-like surface brightness profile limiting contamination due to coma emission to {approx}4% at most, indicating no evidence of outgassing. An upper limit on the fraction of the surface that could be sublimating water ice of <10{sup -4} is obtained with an upper limit to the mass loss of {approx}10{sup -2} kg s{sup -1}. The effective radius of nucleus is found to be 2.3 {+-} 0.4 km. Red filter photometry yields a rotational period of 8.4096 {+-} 0.0012 hr, and the range of the amplitude 0.29 {+-} 0.02 mag is indicative of a moderately spherical shape having a projected axis ratio {approx}1.3. The comet shows redder colors than the Sun, being compatible with other dead comet candidates. The calculated lost mass per revolution is {approx}10{sup 9} kg. If it has sustained this mass loss over the estimated 5000 yr age of the {alpha}-Capricornid meteoroid stream, the total mass loss from 169P/NEAT ({approx}10{sup 13} kg) is consistent with the reported stream mass ({approx}10{sup 13}-10{sup 15} kg), suggesting that the stream is the product of steady disintegration of the parent at every return.

  4. Liquid phase methanol reactor staging process for the production of methanol

    DOE Patents [OSTI]

    Bonnell, Leo W. (Macungie, PA); Perka, Alan T. (Macungie, PA); Roberts, George W. (Emmaus, PA)

    1988-01-01T23:59:59.000Z

    The present invention is a process for the production of methanol from a syngas feed containing carbon monoxide, carbon dioxide and hydrogen. Basically, the process is the combination of two liquid phase methanol reactors into a staging process, such that each reactor is operated to favor a particular reaction mechanism. In the first reactor, the operation is controlled to favor the hydrogenation of carbon monoxide, and in the second reactor, the operation is controlled so as to favor the hydrogenation of carbon dioxide. This staging process results in substantial increases in methanol yield.

  5. Electron-Stimulated Reactions and O-2 Production in Methanol...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and O-2 Production in Methanol-Covered Amorphous Solid Water Films. Electron-Stimulated Reactions and O-2 Production in Methanol-Covered Amorphous Solid Water Films. Abstract: The...

  6. Experimental Investigation on the Interaction of Water and Methanol...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Investigation on the Interaction of Water and Methanol with Anatase-TiO2(101). Experimental Investigation on the Interaction of Water and Methanol with Anatase-TiO2(101). Abstract:...

  7. Site Competition During Coadsorption of Acetone with Methanol...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Site Competition During Coadsorption of Acetone with Methanol and Water on TiO2(110). Site Competition During Coadsorption of Acetone with Methanol and Water on TiO2(110)....

  8. Isotope effects in methanol synthesis and the reactivity of copper...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Isotope effects in methanol synthesis and the reactivity of copper formates on a CuSiO2 catalyst. Isotope effects in methanol synthesis and the reactivity of copper formates on a...

  9. Level Alignment of a Prototypical Photocatalytic System: Methanol...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Level Alignment of a Prototypical Photocatalytic System: Methanol on TiO2(110). Level Alignment of a Prototypical Photocatalytic System: Methanol on TiO2(110). Abstract:...

  10. From CO2 to Methanol via Novel Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    From CO2 to Methanol via Novel Nanocatalysts From CO2 to Methanol via Novel Nanocatalysts Print Wednesday, 03 December 2014 00:00 Researchers have found novel nanocatalysts that...

  11. Theoretical study of syngas hydrogenation to methanol on the...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    study of syngas hydrogenation to methanol on the polar Zn-terminated ZnO(0001) surface. Theoretical study of syngas hydrogenation to methanol on the polar Zn-terminated ZnO(0001)...

  12. Methanol Steam Reformer on a Silicon Wafer

    SciTech Connect (OSTI)

    Park, H; Malen, J; Piggott, T; Morse, J; Sopchak, D; Greif, R; Grigoropoulos, C; Havstad, M; Upadhye, R

    2004-04-15T23:59:59.000Z

    A study of the reforming rates, heat transfer and flow through a methanol reforming catalytic microreactor fabricated on a silicon wafer are presented. Comparison of computed and measured conversion efficiencies are shown to be favorable. Concepts for insulating the reactor while maintaining small overall size and starting operation from ambient temperature are analyzed.

  13. Methanol emission from low mass protostars

    E-Print Network [OSTI]

    S. Maret; C. Ceccarelli; A. G. G. M. Tielens; E. Caux; B. Lefloch; A. Faure; A. Castets; D. R. Flower

    2005-07-15T23:59:59.000Z

    We present observations of methanol lines in a sample of Class 0 low mass protostars. Using a 1-D radiative transfer model, we derive the abundances in the envelopes. In two sources of the sample, the observations can only be reproduced by the model if the methanol abundance is enhanced by about two order of magnitude in the inner hot region of the envelope. Two other sources show similar jumps, although at a lower confidence level. The observations for the other three sources are well reproduced with a constant abundance, but the presence of a jump cannot be ruled out. The observed methanol abundances in the warm gas around low mass protostars are orders of magnitude higher than gas phase chemistry models predict. Hence, in agreement with other evidences, this suggest that the high methanol abundance reflects recent evaporation of ices due to the heating by the newly formed star. The observed abundance ratios of CH3 OH, H2 CO, and CO are in good agreement with grain surface chemistry models. However, the absolute abundances are more difficult to reproduce and may point towards the presence of multiple ice components in these regions.

  14. Methanol production from Eucalyptus wood chips. Final report

    SciTech Connect (OSTI)

    Fishkind, H.H.

    1982-06-01T23:59:59.000Z

    This feasibility study includes all phases of methanol production from seedling to delivery of finished methanol. The study examines: production of 55 million, high quality, Eucalyptus seedlings through tissue culture; establishment of a Eucalyptus energy plantation on approximately 70,000 acres; engineering for a 100 million gallon-per-day methanol production facility; potential environmental impacts of the whole project; safety and health aspects of producing and using methanol; and development of site specific cost estimates.

  15. THE FURNACE COMBUSTION AND RADIATION CHARACTERISTICS OF METHANOL AND A METHANOL/COAL SLURRY

    E-Print Network [OSTI]

    Grosshandler, W.L.

    2010-01-01T23:59:59.000Z

    of NO and N02 in a Turbulent Propane/Air Di fusion Flame,"Fuel Methanol Ethanol Ethane Propane i so Octane n - Cetanestage of the secondary Propane, at A spark air line contains

  16. Isothermal vapor-liquid equilibria for methanol + ethanol + water, methanol + water, and ethanol + water

    SciTech Connect (OSTI)

    Kurihara, Kiyofumi; Takeda, Kouichi; Kojima, Kazuo [Nihon Univ., Tokyo (Japan). Dept. of Industrial Chemistry; Minoura, Tsuyoshi [Mitui Engineering and Shipbuilding Co., Ltd., Tokyo (Japan)

    1995-05-01T23:59:59.000Z

    Isothermal vapor-liquid equilibria were measured for the ternary system methanol + ethanol + water and its constituent binary systems of methanol + water and ethanol + water at 323.15, 328.15, and 333.15 K. The apparatus that was used made it possible to control the measured temperature and total pressure by computer. The experimental binary data were correlated by the NRTL equation. The ternary system was predicted using the binary NRTL parameters with good accuracy.

  17. Dissociative recombination of protonated methanol W. D. Geppert,*a

    E-Print Network [OSTI]

    Millar, Tom

    Dissociative recombination of protonated methanol W. D. Geppert,*a M. Hamberg,a R. D. Thomas,a F. O located in Stockholm, Sweden. Analysis of the data yielded the result that formation of methanol or deuterated methanol accounted for only 3 and 6% of the total rate in CH3OH2 + and CD3OD2 + , respectively

  18. Fuel Cells Bulletin February 2005 Effect of methanol

    E-Print Network [OSTI]

    Zhao, Tianshou

    FEATURE Fuel Cells Bulletin February 2005 12 Effect of methanol concentration on passive DMFC performance The direct methanol fuel cell (DMFC) has attracted extensive interest from scientists energy density of methanol (6100 W h/kg at 25°C) is much higher than that of gaseous fuels.[1­6] Recently

  19. Competition between vitrification and crystallization of methanol at high pressure

    E-Print Network [OSTI]

    Vos, Willem L.

    Competition between vitrification and crystallization of methanol at high pressure Marco J. P methanol at high pressure up to 33 GPa at room temperature with x-ray diffraction, optical polarization and vitrification is observed when methanol is superpressed beyond the freezing pressure of 3.5 GPa: between 5

  20. Homogeneous Catalysis Selective Oxidation of Methane to Methanol

    E-Print Network [OSTI]

    Goddard III, William A.

    Homogeneous Catalysis Selective Oxidation of Methane to Methanol Catalyzed, with CÀH Activation (generated by dissolution[6] of Au2O3) react with methane at 1808C to selectively generate methanol (as a mixture of the ester and methanol) in high yield (Table 1, entries 1 and 2). As expected, the irreversible

  1. Bimetallic Cluster Provides a Higher Activity Electrocatalyst for Methanol Oxidation*

    E-Print Network [OSTI]

    Weidner, John W.

    Bimetallic Cluster Provides a Higher Activity Electrocatalyst for Methanol Oxidation* Brenda L:Ru nanoparticles on carbon (PtRu/C) for use as an electrocatalyst for methanol oxidation. This bimetallic carbonyl support particles. Cyclic voltammo- grams of methanol oxidation from the two catalysts showed

  2. Methanol maser survey using the EVN Anna Bartkiewicz

    E-Print Network [OSTI]

    van Langevelde, Huib Jan

    Methanol maser survey using the EVN Anna Bartkiewicz Centre for Astronomy, Nicolaus Copernicus-mail: langevelde@jive.nl We present the results of a five year campaign observing 6.7 GHz methanol masers towards a new type of masers. We discuss the origin of elliptically shaped methanol masers in massive star

  3. First satellite observations of lower tropospheric ammonia and methanol

    E-Print Network [OSTI]

    First satellite observations of lower tropospheric ammonia and methanol Reinhard Beer,1 Mark W) and methanol (CH3OH), well above the normal background levels. This is the first time that these molecules have. Citation: Beer, R., et al. (2008), First satellite observations of lower tropospheric ammonia and methanol

  4. Adsorption of intact methanol on Ru,,0001... Pawel Gazdzicki,1

    E-Print Network [OSTI]

    Adsorption of intact methanol on Ru,,0001... Pawel Gazdzicki,1 Per Uvdal,2 and Peter Jakob1,a 1 the adsorption of methanol on the clean Ru 0001 surface at T 80 K. Thereby, clear evidence for intact adsorption upon adsorption of methanol on Ru 0001 , even at low temperatures, as well as partial recombinative

  5. Effects of Methanol on the Retinal Function of Juvenile Rats

    E-Print Network [OSTI]

    Casanova, Christian

    Effects of Methanol on the Retinal Function of Juvenile Rats C. Plaziac1 , P. Lachapelle2 , C Received 18 April 2002; accepted 22 July 2002 Abstract We have investigated the effect of methanol exposure recorded prior to and up to 72 h after the administration of methanol. Data were compared to a control

  6. Molecular Dynamics of Methanol Monocation (CH3OH+ ) in Strong

    E-Print Network [OSTI]

    Schlegel, H. Bernhard

    Molecular Dynamics of Methanol Monocation (CH3OH+ ) in Strong Laser Fields Bishnu Thapa and H surfaces of methanol neutral, monocation, and singlet and triplet dication were explored using the CBS in the presence of a 2.9 × 1014 W/cm2 800 nm laser field for methanol monocation on the ground state potential

  7. Structure of crystalline methanol at high pressure David R. Allan

    E-Print Network [OSTI]

    Vos, Willem L.

    Structure of crystalline methanol at high pressure David R. Allan Department of Physics structure, including all atomic positions, of methanol at high pressure and room temperature pressure of methanol is 3.5 GPa. In practice however, it is very easy to superpress the liquid phase

  8. NEAT, An Astrometric Telescope To Probe Planetary Systems Down To The Earth Mass Around Nearby Solar-Type Stars

    E-Print Network [OSTI]

    Malbet, F; Goullioud, R; Shao, M; Lagage, P -O; Cara, C; Durand, G; Feautrier, P; Jakobsson, B; Hinglais, E; Mercier, M

    2011-01-01T23:59:59.000Z

    The NEAT (Nearby Earth Astrometric Telescope) mission is a proposition submitted to ESA for its 2010 call for M-size mission. The main scientific goal is to detect and characterize planetary systems in an exhaustive way down to 1 Earth mass in the habitable zone and further away, around nearby stars for F, G, and K spectral types. This survey would provide the actual planetary masses, the full characterization of the orbits including their inclination, for all the components of the planetary system down to that mass limit. Extremely- high-precision astrometry, in space, can detect the dynamical effect due to even low mass orbiting planets on their central star, reaching those scientific goals. NEAT will continue the work performed by Hipparcos (1mas precision) and Gaia (7{\\mu}as aimed) by reaching a precision that is improved by two orders of magnitude (0.05{\\mu}as, 1{\\sigma} accuracy). The two modules of the payload, the telescope and the focal plane, must be placed 40m away leading to a formation flying opt...

  9. Manufacturing Cost Analysis for YSZ-Based FlexCells at Pilot and Full Scale Production Scales

    SciTech Connect (OSTI)

    Scott Swartz; Lora Thrun; Robin Kimbrell; Kellie Chenault

    2011-05-01T23:59:59.000Z

    Significant reductions in cell costs must be achieved in order to realize the full commercial potential of megawatt-scale SOFC power systems. The FlexCell designed by NexTech Materials is a scalable SOFC technology that offers particular advantages over competitive technologies. In this updated topical report, NexTech analyzes its FlexCell design and fabrication process to establish manufacturing costs at both pilot scale (10 MW/year) and full-scale (250 MW/year) production levels and benchmarks this against estimated anode supported cell costs at the 250 MW scale. This analysis will show that even with conservative assumptions for yield, materials usage, and cell power density, a cost of $35 per kilowatt can be achieved at high volume. Through advancements in cell size and membrane thickness, NexTech has identified paths for achieving cell manufacturing costs as low as $27 per kilowatt for its FlexCell technology. Also in this report, NexTech analyzes the impact of raw material costs on cell cost, showing the significant increases that result if target raw material costs cannot be achieved at this volume.

  10. A counter-charge layer in generalized solvents framework for electrical double layers in neat and hybrid ionic liquid electrolytes

    SciTech Connect (OSTI)

    Huang, Jingsong [ORNL; Feng, Guang [Clemson University; Sumpter, Bobby G [ORNL; Qiao, Rui [ORNL; Meunier, Vincent [ORNL

    2011-01-01T23:59:59.000Z

    Room-temperature ionic liquids (RTILs) have received significant attention as electrolytes due to a number of attractive properties such as their wide electrochemical windows. Since electrical double layers (EDLs) are the cornerstone for the applications of RTILs in electrochemical systems such as supercapacitors, it is important to develop an understanding of the structure capacitance relationships for these systems. Here we present a theoretical framework termed counter-charge layer in generalized solvents (CGS) for describing the structure and capacitance of the EDLs in neat RTILs and in RTILs mixed with different mass fractions of organic solvents. Within this framework, an EDL is made up of a counter-charge layer exactly balancing the electrode charge, and of polarized generalized solvents (in the form of layers of ion pairs, each of which has a zero net charge but has a dipole moment the ion pairs thus can be considered as a generalized solvent) consisting of all RTILs inside the system except the counter-ions in the counter-charge layer, together with solvent molecules if present. Several key features of the EDLs that originate from the strong ion ion correlation in RTILs, e.g., overscreening of electrode charge and alternating layering of counter-ions and co-ions, are explicitly incorporated into this framework. We show that the dielectric screening in EDLs is governed predominately by the polarization of generalized solvents (or ion pairs) in the EDL, and the capacitance of an EDL can be related to its microstructure with few a priori assumptions or simplifications. We use this framework to understand two interesting phenomena observed in molecular dynamics simulations of EDLs in a neat IL of 1-butyl-3- methylimidazolium tetrafluoroborate ([BMIM][BF4]) and in a mixture of [BMIM][BF4] and acetonitrile (ACN): (1) the capacitance of the EDLs in the [BMIM][BF4]/ACN mixture increases only slightly when the mass fraction of ACN in the mixture increases from zero to 50% although the dielectric constant of bulk ACN is more than two times higher than that of neat [BMIM][BF4]; (2) the capacitance of EDLs near negative electrodes (with BMIM+ ion as the counter-ion) is smaller than that near positive electrodes (with BF4as counter-ion) although the closest approaches of both ions to the electrode surface are nearly identical.

  11. METHANOL AS A TRACER OF FUNDAMENTAL CONSTANTS

    SciTech Connect (OSTI)

    Levshakov, S. A. [A. F. Ioffe Physical-Technical Institute, Saint Petersburg 194021 (Russian Federation); Kozlov, M. G. [Petersburg Nuclear Physics Institute, Gatchina 188300 (Russian Federation); Reimers, D., E-mail: lev@astro.ioffe.rssi.ru, E-mail: mgk@mf1309.spb.edu, E-mail: st2e101@hs.uni-hamburg.de [Hamburger Sternwarte, Universitaet Hamburg, Gojenbergsweg 112, D-21029 Hamburg (Germany)

    2011-09-01T23:59:59.000Z

    The methanol molecule CH{sub 3}OH has a complex microwave spectrum with a large number of very strong lines. This spectrum includes purely rotational transitions as well as transitions with contributions of the internal degree of freedom associated with the hindered rotation of the OH group. The latter takes place due to the tunneling of hydrogen through the potential barriers between three equivalent potential minima. Such transitions are highly sensitive to changes in the electron-to-proton mass ratio, {mu} = m{sub e}/m{sub p}, and have different responses to {mu}-variations. The highest sensitivity is found for the mixed rotation-tunneling transitions at low frequencies. Observing methanol lines provides more stringent limits on the hypothetical variation of {mu} than ammonia observation with the same velocity resolution. We show that the best-quality radio astronomical data on methanol maser lines constrain the variability of {mu} in the Milky Way at the level of |{Delta}{mu}/{mu}| < 28 x 10{sup -9} (1{sigma}) which is in line with the previously obtained ammonia result, |{Delta}{mu}/{mu}| < 29 x 10{sup -9} (1{sigma}). This estimate can be further improved if the rest frequencies of the CH{sub 3}OH microwave lines will be measured more accurately.

  12. ISyE 6664 Exam # 2 Please be neat and show all your work so that I can give you partial credit.

    E-Print Network [OSTI]

    Ayhan, Hayriye

    ISyE 6664 Exam # 2 Fall 2005 Name Please be neat and show all your work so that I can give you of r(si) = i units if the system occupies state si. If the decision maker decides to remain

  13. Activation of catalysts for synthesizing methanol from synthesis gas

    DOE Patents [OSTI]

    Blum, David B. (108 Tall Oaks Dr., Wayne, NJ 07470); Gelbein, Abraham P. (45 Headley Rd., Morristown, NJ 07960)

    1985-01-01T23:59:59.000Z

    A method for activating a methanol synthesis catalyst is disclosed. In this method, the catalyst is slurried in an inert liquid and is activated by a reducing gas stream. The activation step occurs in-situ. That is, it is conducted in the same reactor as is the subsequent step of synthesizing methanol from a methanol gas stream catalyzed by the activated catalyst still dispersed in a slurry.

  14. Improved Direct Methanol Fuel Cell Stack

    DOE Patents [OSTI]

    Wilson, Mahlon S. (Los Alamos, NM); Ramsey, John C. (Los Alamos, NM)

    2005-03-08T23:59:59.000Z

    A stack of direct methanol fuel cells exhibiting a circular footprint. A cathode and anode manifold, tie-bolt penetrations and tie-bolts are located within the circular footprint. Each fuel cell uses two graphite-based plates. One plate includes a cathode active area that is defined by serpentine channels connecting the inlet and outlet cathode manifold. The other plate includes an anode active area defined by serpentine channels connecting the inlet and outlet of the anode manifold, where the serpentine channels of the anode are orthogonal to the serpentine channels of the cathode. Located between the two plates is the fuel cell active region.

  15. advanced direct methanol: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to Direct Methanol Materials Science Websites Summary: increases the overall cost of the cell, reducing the fuel conversion efficiency. An alternative to H2): Application to...

  16. From CO2 to Methanol via Novel Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    From CO2 to Methanol via Novel Nanocatalysts Print Researchers have found novel nanocatalysts that lower the barrier to converting carbon dioxide (CO2)-an abundant greenhouse...

  17. Polyvinylidene Fluoride-Based Membranes for Direct Methanol Fuel...

    Broader source: Energy.gov (indexed) [DOE]

    "Fuel Cells for Portable Power." Polyvinylidene Fluoride-Based Membranes for Direct Methanol Fuel Cell Applications Webinar Slides More Documents & Publications Novel Materials...

  18. Methanol Observation of IRAS 19312+1950: A Possible New Type of Class I Methanol Masers

    E-Print Network [OSTI]

    Nakashima, Jun-ichi; Salii, Svetlana V; Zhang, Yong; Yung, Bosco H K; Deguchi, Shuji

    2015-01-01T23:59:59.000Z

    We report the result of a systematic methanol observation toward IRAS 19312+1950. The properties of the SiO, H2O and OH masers of this object are consistent with those of mass-losing evolved stars, but some other properties are difficult to explain in the standard scheme of stellar evolution in its late stage. Interestingly, a tentative detection of radio methanol lines was suggested toward this object by a previous observation. To date, there are no confirmed detections of methanol emission towards evolved stars, so investigation of this possible detection is important to better understand the circumstellar physical/chemical environment of IRAS 19312+1950. In this study, we systematically observed multiple methanol lines of IRAS 19312+1950 in the lambda=3mm, 7mm, and 13mm bands, and detected 6 lines including 4 thermal lines and 2 class I maser lines. We derived basic physical parameters including kinetic temperature and relative abundances by fitting a radiative transfer model. According to the derived exci...

  19. Methanol production from eucalyptus wood chips. Attachment IV. Health and safety aspects of the eucalypt biomass to methanol energy system

    SciTech Connect (OSTI)

    Fishkind, H.H.

    1982-06-01T23:59:59.000Z

    The basic eucalyptus-to-methanol energy process is described and possible health and safety risks are identified at all steps of the process. The toxicology and treatment for exposure to these substances are described and mitigating measures are proposed. The health and safety impacts and risks of the wood gasification/methanol synthesis system are compared to those of the coal liquefaction and conversion system. The scope of this report includes the health and safety risks of workers (1) in the laboratory and greenhouse, where eucalyptus seedlings are developed, (2) at the biomass plantation, where these seedlings are planted and mature trees harvested, (3) transporting these logs and chips to the refinery, (4) in the hammermill, where the logs and chips will be reduced to small particles, (5) in the methanol synthesis plant, where the wood particles will be converted to methanol, and (6) transporting and dispensing the methanol. Finally, the health and safety risks of consumers using methanol is discussed.

  20. Structural dynamics of hydrogen bonded methanol oligomers: Vibrational transient hole burning studies of spectral diffusion

    E-Print Network [OSTI]

    Fayer, Michael D.

    Structural dynamics of hydrogen bonded methanol oligomers: Vibrational transient hole burning resolved pump-probe experiments have been conducted on the deuterated hydroxyl stretch of methanol-d in a solution containing 0.8% methanol-d/23% methanol-h in carbon tetrachloride. Methanol-d molecules that both

  1. Communication China's growing methanol economy and its implications for energy

    E-Print Network [OSTI]

    Jackson, Robert B.

    but scarce oil and natural gas. Adapting to such limitations, it has developed a chemical industry, with the rest coming from natural gas (Peng, 2011). Methanol is commonly used to produce formaldehyde, methylCommunication China's growing methanol economy and its implications for energy and the environment

  2. The Arecibo Methanol Maser Galactic Plane Survey--I: Data

    E-Print Network [OSTI]

    Jagadheep D. Pandian; Paul F. Goldsmith; Avinash A. Deshpande

    2007-02-06T23:59:59.000Z

    We present the results of an unbiased survey for 6.7 GHz methanol masers in the Galactic plane carried out using the 305 m Arecibo radio telescope. A total of 18.2 square degrees was surveyed with uniform sampling at 35.2 deg methanol masers are clustered, reflecting the formation of massive stars in clusters.

  3. Synthesis of Methanol and Dimethyl Ether from Syngas over Pd...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Methanol and Dimethyl Ether from Syngas over PdZnOAl2O3 Catalysts. Synthesis of Methanol and Dimethyl Ether from Syngas over PdZnOAl2O3 Catalysts. Abstract: A PdZnOAl2O3...

  4. Importance of Diffusion in Methanol Photochemistry on TiO2(110...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Importance of Diffusion in Methanol Photochemistry on TiO2(110). Importance of Diffusion in Methanol Photochemistry on TiO2(110). Abstract: The photoactivity of methanol on the...

  5. Mechanistic Studies of Methanol Synthesis over Cu from CO/CO2...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of Methanol Synthesis over Cu from COCO2H2H2O Mixtures: the Source of C in Methanol and the Role of Water Mechanistic Studies of Methanol Synthesis over Cu from COCO2H2H2O...

  6. Understanding the effect of modifying elements in supported vanadia bilayered catalysts for methanol oxidation to formaldehyde

    E-Print Network [OSTI]

    Vining, William Collins

    2011-01-01T23:59:59.000Z

    Si Figure 1.1. Schematic of methanol oxidation over isolatedSiO 2 catalysts for methanol oxidation, 163-171, Copyright (rate constant at 550 K for methanol oxidation plotted versus

  7. Volume$3, number 3 CHEMICAL. PHYSICS LETTERS 1 Februrf 1978 INTERACTION OF METHANOL WITH RUTHENIUM

    E-Print Network [OSTI]

    Goodman, Wayne

    Volume$3, number 3 CHEMICAL. PHYSICS LETTERS 1 Februrf 1978 INTERACTION OF METHANOL WITH RUTHENIUM of methanol with a clean methods. Methanol dissociates upon adsorption at 300 K and yields Ha(g) and chemisorbed CO as the domiwt

  8. EFFECTS OF METAL-SUPPORT INTERACTIONS ON THE SYNTHESIS OF METHANOL OVER PALLADIUM

    E-Print Network [OSTI]

    Ryndin, Yu A.

    2013-01-01T23:59:59.000Z

    on the Synthesis of Methanol over Palladium by Yu. A.ABSTRACT The synthesis of methanol and other products fromThe specific activity for methanol synthesis decreased in

  9. Low temperature catalyst system for methanol production

    DOE Patents [OSTI]

    Sapienza, R.S.; Slegeir, W.A.; O'Hare, T.E.

    1984-04-20T23:59:59.000Z

    This patent discloses a catalyst and process useful at low temperatures (150/sup 0/C) and preferably in the range 80 to 120/sup 0/C used in the production of methanol from carbon monoxide and hydrogen. The catalyst components are used in slurry form and comprise (1) a complex reducing agent derived from the component structure NaH-ROH-M(OAc)/sub 2/ where M is selected from the group consisting of Ni, Pd, and Co and R is a lower alkyl group containing 1 to 6 carbon atoms and (2) a metal carbonyl of a group VI (Mo, Cr, W) metal. For the first component, Nic is preferred (where M = Ni and R = tertiary amyl). For the second component, Mo(CO)/sub 6/ is preferred. The mixture is subjected to a conditioning or activating step under temperature and pressure, similar to the parameters given above, to afford the active catalyst.

  10. Mobil plans methanol plant in Nigeria

    SciTech Connect (OSTI)

    Alperowicz, N.

    1992-08-12T23:59:59.000Z

    Mobil Chemical (Houston) is in discussions with Nigerian National Petroleum Corp. (NNPC; Lagos) on a joint venture methanol plant at Port Harcourt, Nigeria. The U.S. firm has invited process owners to submit proposals for a 1-million m.t./year unit and hopes to select the technology by the end of this year. Three proposals have been submitted: Lurgi, offering its own low-pressure process; John Brown/Davy, with the ICI process; and M.W. Kellogg, proposing its own technology. Shareholding in the joint venture is yet to be decided, but it is likely to be a 50/50 tie-up. Marketing of Mobil's share or of the entire tonnage would be handled by Mobil Petrochemical International (Brussels). The plant could be onstream in late 1996.

  11. Low temperature catalysts for methanol production

    DOE Patents [OSTI]

    Sapienza, R.S.; Slegeir, W.A.; O'Hare, T.E.; Mahajan, D.

    1986-09-30T23:59:59.000Z

    A catalyst and process useful at low temperatures (below about 160 C) and preferably in the range 80--120 C used in the production of methanol from carbon monoxide and hydrogen are disclosed. The catalyst is used in slurry form and comprises a complex reducing agent derived from the component structure NaH--RONa-M(OAc)[sub 2] where M is selected from the group consisting of Ni, Pd, and Co and R is a lower alkyl group containing 1--6 carbon atoms. This catalyst is preferably used alone but is also effective in combination with a metal carbonyl of a group VI (Mo, Cr, W) metal. The preferred catalyst precursor is Nic (where M = Ni and R = tertiary amyl). Mo(CO)[sub 6] is the preferred metal carbonyl if such component is used. The catalyst is subjected to a conditioning or activating step under temperature and pressure, similar to the parameters given above, to afford the active catalyst.

  12. Role of Water in Methanol Photochemistry on Rutile TiO2(110)...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    methanol photochemistry or thermal decomposition of methanol to methoxy. However, terminal OH groups (OHt), prepared by coadsorption of water and oxygen atoms, thermally...

  13. Methanol synthesis using a catalyst combination of alkali or alkaline earth salts and reduced copper chromite for methanol synthesis

    DOE Patents [OSTI]

    Tierney, John W. (Pittsburgh, PA); Wender, Irving (Pittsburgh, PA); Palekar, Vishwesh M. (Pittsburgh, PA)

    1993-01-01T23:59:59.000Z

    The present invention relates to a novel route for the synthesis of methanol, and more specifically to the production of methanol by contacting synthesis gas under relatively mild conditions in a slurry phase with a catalyst combination comprising reduced copper chromite and basic alkali salts or alkaline earth salts. The present invention allows the synthesis of methanol to occur in the temperature range of approximately 100.degree.-160.degree. C. and the pressure range of 40-65 atm. The process produces methanol with up to 90% syngas conversion per pass and up to 95% methanol selectivity. The only major by-product is a small amount of easily separated methyl formate. Very small amounts of water, carbon dioxide and dimethyl ether are also produced. The present catalyst combination also is capable of tolerating fluctuations in the H.sub.2 /CO ratio without major deleterious effect on the reaction rate. Furthermore, carbon dioxide and water are also tolerated without substantial catalyst deactivation.

  14. ALTERNATIVE FUEL VEHICLE (AFV) INFORMATION Over 98% of the U-M auto passenger fleet is flex fuel vehicles (FFV). A FFV is capable of operating on

    E-Print Network [OSTI]

    Kirschner, Denise

    ALTERNATIVE FUEL VEHICLE (AFV) INFORMATION Over 98% of the U-M auto passenger fleet is flex fuel of both. FFV's are equipped with an engine and fuel system designed specifically to be compatible with ethanol's chemical properties. FFV's qualify as alternative fuel vehicles under the Energy Policy Act

  15. The production of methanol by the Brookhaven National Laboratory process

    SciTech Connect (OSTI)

    Miller, D.B.; Williams, J.J.; Johnson, A.R.

    1990-11-01T23:59:59.000Z

    The purpose of this study was to develop a capital cost estimate and methanol production costs for a new methanol process under development at the Brookhaven National Laboratory (BNL). The cost of fuel delivered to the US Gulf Coast is compared with fuel produced by a conventional methanol process and a liquefied natural gas (LNG) process. The new methanol process is made possible by the development of a new liquid phase catalyst. The new liquid catalyst system can convert synthesis gas almost completely to methanol in a SINGLE pass through the methanol synthesis reactor. This catalyst system reduces synthesis reaction temperatures from about 260{degree}C to about 100{degree}C, permitting isothermal synthesis conditions, in contrast to the temperature gradients in currently available pelleted, solid catalysts. Natural gas feedstock can be processed at pressures under 250 psia. Since nitrogen in the synthesis gas can be tolerated, the autothermal reforming step (combination of partial oxidation and steam reforming over a nickel catalyst) uses preheated air rather than oxygen. However, even with nitrogen present, the volume of gas fed to the reactor can still be smaller than the volume of gas that must be circulated in a conventional reactor, which operates with low conversions and requires high recycle volumes. The characteristics of the BNL system permits a major improvement in methanol plant design and economics. 11 figs., 15 tabs.

  16. Novel Materials for High Efficiency Direct Methanol Fuel Cells

    SciTech Connect (OSTI)

    Carson, Stephen; Mountz, David; He, Wensheng; Zhang, Tao

    2013-12-31T23:59:59.000Z

    Direct methanol fuel cell membranes were developed using blends of different polyelectrolytes with PVDF. The membranes showed complex relationships between polyelectrolyte chemistry, morphology, and processing. Although the PVDF grade was found to have little effect on the membrane permselectivity, it does impact membrane conductivity and methanol permeation values. Other factors, such as varying the polyelectrolyte polarity, using varying crosslinking agents, and adjusting the equivalent weight of the membranes impacted methanol permeation, permselectivity, and areal resistance. We now understand, within the scope of the project work completed, how these inter-related performance properties can be tailored to achieve a balance of performance.

  17. ICI and Penspen in Nigerian and Qatari methanol deals

    SciTech Connect (OSTI)

    Alperowicz, N.

    1992-03-11T23:59:59.000Z

    The U.K. consulting and engineering company Penspen Ltd. (London) has signed a second joint venture agreement in Qatar and has selected the ICI (London) methanol process. The technology will also be used in a world-scale methanol plant in Nigeria that Penspen is helping to set up. Under the first agreement, signed on January 1 with Qatar General Petroleum Corp. (QGPC), a 50/50 venture is being formed to build a $370-million, 2,000-m.t./day methanol plant at Umm Said. ICI will provide its low-pressure technology and help market 75% of the output. Completion is due late 1994.

  18. Low temperature catalysts for methanol production

    DOE Patents [OSTI]

    Sapienza, R.S.; Slegeir, W.A.; O'Hare, T.E.; Mahajan, D.

    1985-03-12T23:59:59.000Z

    A catalyst and process useful at low temperatures (below about 160/sup 0/C) and preferably in the range 80 to 120/sup 0/C used in the production of methanol from carbon monoxide and hydrogen is disclosed. The catalyst is used in slurry form and comprises a complex reducing agent derived from the component structure NaH-RONa-M(OAc)/sub 2/ where M is selected from the group consisting of Ni, Pd, and Co and R is a lower alkyl group containing 1 to 6 carbon atoms. This catalyst is preferably used alone but is also effective in combination with a metal carbonyl of a group VI (Mo, Cr, W) metal. The preferred catalyst precursor is Nic (where M = Ni and R = tertiary amyl). Mo(CO)/sub 6/ is the preferred metal carbonyl if such component is used. The catalyst is subjected to a conditioning or activating step under temperature and pressure, similar to the parameters given above, to afford the active catalyst.

  19. Low temperature catalysts for methanol production

    DOE Patents [OSTI]

    Sapienza, Richard S. (1 Miller Ave., Shoreham, NY 11786); Slegeir, William A. (7 Florence Rd., Hampton Bays, NY 11946); O'Hare, Thomas E. (11 Geiger Pl., Huntington Station, NY 11746); Mahajan, Devinder (14 Locust Ct., Selden, NY 11784)

    1986-01-01T23:59:59.000Z

    A catalyst and process useful at low temperatures (below about 160.degree. C.) and preferably in the range 80.degree.-120.degree. C. used in the production of methanol from carbon monoxide and hydrogen is disclosed. The catalyst is used in slurry form and comprises a complex reducing agent derived from the component structure NaH--RONa--M(OAc).sub.2 where M is selected from the group consisting of Ni, Pd, and Co and R is a lower alkyl group containing 1-6 carbon atoms. This catalyst is preferably used alone but is also effective in combination with a metal carbonyl of a group VI (Mo, Cr, W) metal. The preferred catalyst precursor is Nic (where M=Ni and R=tertiary amyl). Mo(CO).sub.6 is the preferred metal carbonyl if such component is used. The catalyst is subjected to a conditioning or activating step under temperature and pressure, similar to the parameters given above, to afford the active catalyst.

  20. Low temperature catalysts for methanol production

    DOE Patents [OSTI]

    Sapienza, R.S.; Slegeir, W.A.; O'Hare, T.E.; Mahajan, D.

    1986-10-28T23:59:59.000Z

    A catalyst and process useful at low temperatures (below about 160 C) and preferably in the range 80--120 C used in the production of methanol from carbon monoxide and hydrogen are disclosed. The catalyst is used in slurry form and comprises a complex reducing agent derived from the component structure NaH--RONa-M(OAc)[sub 2] where M is selected from the group consisting of Ni, Pd, and Co and R is a lower alkyl group containing 1-6 carbon atoms. This catalyst is preferably used alone but is also effective in combination with a metal carbonyl of a group VI (Mo, Cr, W) metal. The preferred catalyst precursor is NiC (where M = Ni and R = tertiary amyl). Mo(CO)[sub 6] is the preferred metal carbonyl if such component is used. The catalyst is subjected to a conditioning or activating step under temperature and pressure, similar to the parameters given above, to afford the active catalyst.

  1. Coadsorption of methanol and isobutene on HY zeolite

    SciTech Connect (OSTI)

    Kogelbauer, A.; Goodwin, J.G. Jr. [Univ. of Pittsburgh, PA (United States); Lercher, J.A. [Univ. of Twente, Enschede (Netherlands)

    1995-05-25T23:59:59.000Z

    In order to develop a better understanding of methyl tert-butyl ether (MTBE) synthesis on zeolites, the coadsorption of methanol and isobutene on HY zeolite was investigated using IR spectroscopy. Initial adsorption of isobutene alone at 35{degree}C led to rapid oligomerization yielding strongly bound oligomers. The subsequent coadsorption of methanol did not induce any changes in the zeolite-adsorbate complexes. TPD following the coadsorption showed that the Bronsted acid sites could be restored by temperature treatment above approximately 300{degree}C. When methanol was adsorbed first and isobutene was subsequently coadsorbed, MTBE was formed even at 35{degree}C on the catalyst surface. MTBE desorbed easily at a temperature of 70{degree}C, restoring a major fraction of the Bronsted acid sites. Methanol was concluded to decrease the probability of oligomerization by effectively competing for the acid sites. 34 refs., 6 figs.

  2. Methanol plant ship: implementation study. Export trade information

    SciTech Connect (OSTI)

    Not Available

    1988-07-30T23:59:59.000Z

    The study compiled the economic, commercial and financing requirements of a floating plant ship with a production capacity of 3,000 tons of methanol a day. The raw material for the methanol production would be supplied from a natural gas reserve off the coast of Trinidad. The report has a separate section for each aspect of the plant ship project, such as methanol storage; logistics of transporting methanol to the United States; the required sub-sea installation to bring natural gas to the plant ship; and plant ship design and equipment. It gives a detailed description of a proposed organizational structure and its tax consequences. The project's financial requirements and economic impact are examined. The environmental consequences and other operator issues are analyzed. Tables and figures accompany the report.

  3. Evaluation of reformed methanol as an automotive engine fuel

    E-Print Network [OSTI]

    McCall, David M

    1983-01-01T23:59:59.000Z

    coal, oil shale, tar sands, and renewable resources [12], of which there are abundant supplies. Also, methanol could be distributed through the present fuel distribution network with some minor modifications. Hydrogen has also be investi- gated...

  4. Is Methanol the Transportation Fuel of the Future?

    E-Print Network [OSTI]

    Sperling, Daniel; DeLuchi, Mark A.

    1989-01-01T23:59:59.000Z

    in the U.S. were coal, oil shale, and biomass. Natural gas (produced from coal and oil shale, methanol produced frommethanol was rated below oil shale and other coal-liquid

  5. Characterization of Microexplosion Phenomena of Methanol-Glycerol Mixtures 

    E-Print Network [OSTI]

    Fan, Ge-Yi

    2014-07-17T23:59:59.000Z

    emissions even when combusting glycerol-based mixtures. In this research, microexplosion phenomena of methanol-in-glycerol mixtures have been studied using a high speed camera and an acoustic sensor system. A Fast Fourier Transform (FFT) algorithm has been...

  6. THE METHANOL MASER EMISSION IN W51 C.J. PHILLIPS1

    E-Print Network [OSTI]

    van Langevelde, Huib Jan

    THE METHANOL MASER EMISSION IN W51 C.J. PHILLIPS1 and H.J. VAN LANGEVELDE2 1 CSIRO; E-mail: chris.7-GHz methanol maser emission towards W51. In the W51 Main region, the bulk of the methanol is offset from an UCHII region. This probably indicates the methanol emission arises at the interface

  7. Mechanistic Studies of Methanol Oxidation to Formaldehyde on Isolated Vanadate Sites Supported on MCM-48

    E-Print Network [OSTI]

    Bell, Alexis T.

    Mechanistic Studies of Methanol Oxidation to Formaldehyde on Isolated Vanadate Sites Supported-1462 ReceiVed: August 16, 2006; In Final Form: October 10, 2006 The mechanism of methanol oxidation. Methanol reacts reversibly, at a ratio of approximately 1 methanol per V, with one V-O-Si to produce both V

  8. Ultrafast Carrier Dynamics in Exfoliated and Functionalized Calcium Niobate Nanosheets in Water and Methanol

    E-Print Network [OSTI]

    Osterloh, Frank

    and Methanol Elizabeth C. Carroll, Owen C. Compton, Dorte Madsen, Frank E. Osterloh, and Delmar S. Larsen-order kinetics on a sub-nanosecond time scale that depended on the nanosheet size. Methanol was used and methanol solutions. Methanol is known as an efficient sacrificial electron donor for layered metal oxide

  9. Theoretical characterization of the hydrogen-bond interaction of diacetamide with water and methanol

    E-Print Network [OSTI]

    Nguyen, Minh Tho

    and methanol Minh Tho Nguyen, Natalie Leroux and The re` se Zeegers-Huyskens* Department of Chemistry formed from interaction of diacetamide with water and methanol. In both water and methanol complexes/6-31G** level being [44 kJ mol~1 for the water complex and [48 kJ mol~1 for the methanol complex

  10. 6.7 GHZ METHANOL MASERS: PROPERTIES, ASSOCIATIONS AND TRACERS OF GALACTIC

    E-Print Network [OSTI]

    Richardson Jr., James E.

    6.7 GHZ METHANOL MASERS: PROPERTIES, ASSOCIATIONS AND TRACERS OF GALACTIC STRUCTURE A Dissertation Jagadheep Dhanasekara Pandian ALL RIGHTS RESERVED #12;6.7 GHZ METHANOL MASERS: PROPERTIES, ASSOCIATIONS transition of methanol is the strongest of methanol masers, and is the second strongest maser transition ever

  11. Modeling the thermal deformation of TATB-based explosives. Part 1: Thermal expansion of “neat-pressed” polycrystalline TATB

    SciTech Connect (OSTI)

    Luscher, Darby J. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2014-05-08T23:59:59.000Z

    We detail a modeling approach to simulate the anisotropic thermal expansion of polycrystalline (1,3,5-triamino-2,4,6-trinitrobenzene) TATB-based explosives that utilizes microstructural information including porosity, crystal aspect ratio, and processing-induced texture. This report, the first in a series, focuses on nonlinear thermal expansion of “neat-pressed” polycrystalline TATB specimens which do not contain any binder; additional complexities related to polymeric binder and irreversible ratcheting behavior are briefly discussed, however detailed investigation of these aspects are deferred to subsequent reports. In this work we have, for the first time, developed a mesoscale continuum model relating the thermal expansion of polycrystal TATB specimens to their microstructural characteristics. A self-consistent homogenization procedure is used to relate macroscopic thermoelastic response to the constitutive behavior of single-crystal TATB. The model includes a representation of grain aspect ratio, porosity, and crystallographic texture attributed to the consolidation process. A quantitative model is proposed to describe the evolution of preferred orientation of graphitic planes in TATB during consolidation and an algorithm constructed to develop a discrete representation of the associated orientation distribution function. Analytical and numerical solutions using this model are shown to produce textures consistent with previous measurements and characterization for isostatic and uniaxial “die-pressed” specimens. Predicted thermal strain versus temperature for textured specimens are shown to be in agreement with corresponding experimental measurements. Using the developed modeling approach, several simulations have been run to investigate the influence of microstructure on macroscopic thermal expansion behavior. Results from these simulations are used to identify qualitative trends. Implications of the identified trends are discussed in the context of thermal deformation of engineered components whose consolidation process is generally more complex than isostatic or die-pressed specimens. Finally, an envisioned application of the modeling approach to simulating thermal expansion of weapon systems and components is outlined along with necessary future work to introduce the effects of binder and ratcheting behavior. Key conclusions from this work include the following. Both porosity and grain aspect ratio have an influence on the thermal expansion of polycrystal TATB considering realistic material variability. Thepreferred orientation of the single crystal TATB [001] poles within a polycrystal gives rise to pronounced anisotropy of the macroscopic thermal expansion. The extent of this preferred orientation depends on the magnitude of deformation, and consequently, is expected to vary spatially throughout manufactured components much like porosity. The modeling approach presented here has utility toward bringing spatially variable microstructural features into macroscale system engineering modelsAbstract Not Provided

  12. Oxidation of Methanol on 2nd and 3rd Row Group VIII Transition Metals (Pt, Ir, Os, Pd, Rh, and Ru): Application to Direct Methanol

    E-Print Network [OSTI]

    Goddard III, William A.

    Oxidation of Methanol on 2nd and 3rd Row Group VIII Transition Metals (Pt, Ir, Os, Pd, Rh, and Ru): Application to Direct Methanol Fuel Cells Jeremy Kua and William A. Goddard III* Contribution from functional theory (B3LYP)], we calculated the 13 most likely intermediate species for methanol oxidation

  13. Catalytic gasification of bagasse for the production of methanol

    SciTech Connect (OSTI)

    Baker, E.G.; Brown, M.D.; Robertus, R.J.

    1985-10-01T23:59:59.000Z

    The purpose of the study was to evaluate the technical and economic feasibility of catalytic gasification of bagasse to produce methanol. In previous studies, a catalytic steam gasification process was developed which converted wood to methanol synthesis gas in one step using nickel based catalysts in a fluid-bed gasifier. Tests in a nominal 1 ton/day process development unit (PDU) gasifier with these same catalysts showed bagasse to be a good feedstock for fluid-bed gasifiers, but the catalysts deactivated quite rapidly in the presence of bagasse. Laboratory catalyst screening tests showed K/sub 2/CO/sub 3/ doped on the bagasse to be a promising catalyst for converting bagasse to methanol synthesis gas. PDU tests with 10 wt % K/sub 2/CO/sub 3/ doped on bagasse showed the technical feasibility of this type of catalyst on a larger scale. A high quality synthesis gas was produced and carbon conversion to gas was high. The gasifier was successfully operated without forming agglomerates of catalyst, ash, and char in the gasifier. There was no loss of activity throughout the runs because catalysts is continually added with the bagasse. Laboratory tests showed about 80% of the potassium carbonate could be recovered and recycled with a simple water wash. An economic evaluation of the process for converting bagasse to methanol showed the required selling price of methanol to be significantly higher than the current market price of methanol. Several factors make this current evaluaton using bagasse as a feedstock less favorable: (1) capital costs are higher due to inflation and some extra costs required to use bagasse, (2) smaller plant sizes were considered so economies of scale are lost, and (3) the market price of methanol in the US has fallen 44% in the last six months. 24 refs., 14 figs., 16 tabs.

  14. Author's personal copy Characteristics of water transport through the membrane in

    E-Print Network [OSTI]

    Zhao, Tianshou

    fuel cells operating with neat methanol Q.X. Wu, T.S. Zhao* Department of Mechanical Engineering Accepted 27 January 2011 Available online 5 March 2011 Keywords: Fuel cell Direct methanol fuel cell Neat-methanol methanol fuel cell (DMFC) operating with neat methanol can be supplied by diffusion from the cathode

  15. Investigation of a FAST-OrcaFlex Coupling Module for Integrating Turbine and Mooring Dynamics of Offshore Floating Wind Turbines: Preprint

    SciTech Connect (OSTI)

    Masciola, M.; Robertson, A.; Jonkman, J.; Driscoll, F.

    2011-10-01T23:59:59.000Z

    To enable offshore floating wind turbine design, the following are required: accurate modeling of the wind turbine structural dynamics, aerodynamics, platform hydrodynamics, a mooring system, and control algorithms. Mooring and anchor design can appreciably affect the dynamic response of offshore wind platforms that are subject to environmental loads. From an engineering perspective, system behavior and line loads must be studied well to ensure the overall design is fit for the intended purpose. FAST (Fatigue, Aerodynamics, Structures and Turbulence) is a comprehensive simulation tool used for modeling land-based and offshore wind turbines. In the case of a floating turbine, continuous cable theory is used to emulate mooring line dynamics. Higher modeling fidelity can be gained through the use of finite element mooring theory. This can be achieved through the FASTlink coupling module, which couples FAST with OrcaFlex, a commercial simulation tool used for modeling mooring line dynamics. In this application, FAST is responsible for capturing the aerodynamic loads and flexure of the wind turbine and its tower, and OrcaFlex models the mooring line and hydrodynamic effects below the water surface. This paper investigates the accuracy and stability of the FAST/OrcaFlex coupling operation.

  16. Bifunctional Anode Catalysts for Direct Methanol Fuel Cells

    SciTech Connect (OSTI)

    Rossmeisl, Jan; Ferrin, Peter A.; Tritsaris, Georgios A.; Nilekar, Anand U.; Koh, Shirlaine; Bae, Sang Eun; Brankovic, Stanko R.; Strasser, Peter; Mavrikakis, Manos

    2012-06-13T23:59:59.000Z

    Using the binding energy of OH* and CO* on close-packed surfaces as reactivity descriptors, we screen bulk and surface alloy catalysts for methanol electro-oxidation activity. Using these two descriptors, we illustrate that a good methanol electro-oxidation catalyst must have three key properties: (1) the ability to activate methanol, (2) the ability to activate water, and (3) the ability to react off surface intermediates (such as CO* and OH*). Based on this analysis, an alloy catalyst made up of Cu and Pt should have a synergistic effect facilitating the activity towards methanol electro-oxidation. Using these two reactivity descriptors, a surface PtCu3 alloy is proposed to have the best catalytic properties of the Pt–Cu model catalysts tested, similar to those of a Pt–Ru bulk alloy. To validate the model, experiments on a Pt(111) surface modified with different amounts of Cu adatoms are performed. Adding Cu to a Pt(111) surface increases the methanol oxidation current by more than a factor of three, supporting our theoretical predictions for improved electrocatalysts.

  17. Clustering Dynamics in Water/Methanol Mixtures: A Nuclear Magnetic Resonance Study at 205 K < T < 295 K

    E-Print Network [OSTI]

    Stanley, H. Eugene

    Clustering Dynamics in Water/Methanol Mixtures: A Nuclear Magnetic Resonance Study at 205 K functional groups in water/methanol mixtures at different methanol molar fractions (XMeOH ) 0, 0.04, 0.1, 0 in the mixtures, at all the methanol molar fractions, are faster than those of pure water and methanol because

  18. Perovskite anode electrocatalysis for direct methanol fuel cells

    SciTech Connect (OSTI)

    White, J.H.; Sammells, A.F. (Eltron Research, Inc., Boulder, CO (United States))

    1993-08-01T23:59:59.000Z

    This investigation explores direct methanol fuel cells incorporating perovskite anode electrocatalysts. Preliminary electrochemical performance was addressed following incorporation of electrocatalysts into polymer electrolyte (Nafion 417) fuel cells. Perovskite electrocatalysts demonstrating activity towards direct methanol oxidation during cyclic voltammetry measurements included, respectively, SrRu[sub 0.5]Pt[sub 0.5]O[sub 3], SrRu[sub 0.5]Pd[sub 0.5]O[sub 3], SrPdO[sub 3], SmCoO[sub 3], SrRuO[sub 3], La[sub 0.8]Ce[sub 0.2]CoC[sub 3],SrCo[sub 0.5]Ti[sub 0.5]O[sub 3], and La[sub 0.8]Sr[sub 0.2]CoO[sub 3] where SrRu[sub 0.5]Pt[sub 0.5]P[sub 3] gave methanol oxidation currents up to 28 mA/cm[sup 2] at 0.45 V vs. SCE. Correlations were found between electrocatalyst solid-state and thermodynamic parameters corresponding to, respectively, molecular electronic polarizability, the optical dielectric constant, the perovskite spin-only magnetic moment, the number of d-electrons in perovskite A and B lattice sites, and the average metal-oxygen binding energy for the perovskite lattice, and corresponding fuel cell performance. This may have future merit for the prediction of new electrocatalyst family members for promoting direct methanol oxidation. Methanol diffusion from anode to cathode compartments appears to be a major obstacle to the development of polymer electrolyte methanol fuel cells.

  19. Environmental information volume: Liquid Phase Methanol (LPMEOH{trademark}) project

    SciTech Connect (OSTI)

    NONE

    1996-05-01T23:59:59.000Z

    The purpose of this project is to demonstrate the commercial viability of the Liquid Phase Methanol Process using coal-derived synthesis gas, a mixture of hydrogen and carbon monoxide. This report describes the proposed actions, alternative to the proposed action, the existing environment at the coal gasification plant at Kingsport, Tennessee, environmental impacts, regulatory requirements, offsite fuel testing, and DME addition to methanol production. Appendices include the air permit application, solid waste permits, water permit, existing air permits, agency correspondence, and Eastman and Air Products literature.

  20. Single-cell protein from methanol with Enterobacter aerogenes

    SciTech Connect (OSTI)

    Gnan, S.O.; Abodreheba, A.O.

    1987-02-20T23:59:59.000Z

    An identified Enterobacter aerogenes utilizing methanol as a sole carbon source was studied for the optimization of biomass production and the reduction of its nucleic acid content. Results indicated that the highest yield and conversion were obtained at 0.5% methanol. The addition of seawater as a source of trace elements has an adverse effect. However, the addition of urea as source of nitrogen enhanced the growth of E. aerogenes. Heat shock at 60 degrees C for one minute followed by incubation at 50 degrees C for 2 hours caused 72.6% reduction in the nucleic acid. 12 references.

  1. An Investigation of Different Methods of Fabricating Membrane Electrode Assemblies for Methanol Fuel Cells

    E-Print Network [OSTI]

    Hall, Kwame (Kwame J.)

    2009-01-01T23:59:59.000Z

    Methanol fuel cells are electrochemical conversion devices that produce electricity from methanol fuel. The current process of fabricating membrane electrode assemblies (MEAs) is tedious and if it is not sufficiently ...

  2. Imaging Adsorbate O-H Bond Cleavage: Methanol on TiO2(110). ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    O-H Bond Cleavage: Methanol on TiO2(110). Abstract: We investigated methanol adsorption and dissociation on bridge-bonded oxygen vacancies of TiO2(110) (1×1) surface...

  3. A Comparative Study of the Adsorption of Water and Methanol in...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of the Adsorption of Water and Methanol in Zeolite BEA: A Molecular Simulation Study. A Comparative Study of the Adsorption of Water and Methanol in Zeolite BEA: A Molecular...

  4. Active Oxygen Vacancy Site for Methanol Synthesis from CO2 Hydrogenati...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Oxygen Vacancy Site for Methanol Synthesis from CO2 Hydrogenation on In2O3(110): A DFT Study. Active Oxygen Vacancy Site for Methanol Synthesis from CO2 Hydrogenation on...

  5. Supplementary Information for Methanol as a sensitive probe for spatial and temporal variations of the

    E-Print Network [OSTI]

    Supplementary Information for Methanol as a sensitive probe for spatial and temporal variations.757 0.68(5) Table I. Methanol (12 CH16 3 OH) maser transitions and accurate rest frequencies taken from

  6. PdZnAl Catalysts for the Reactions of Water-Gas-Shift, Methanol...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    PdZnAl Catalysts for the Reactions of Water-Gas-Shift, Methanol Steam Reforming, and Reverse-Water-Gas-Shift. PdZnAl Catalysts for the Reactions of Water-Gas-Shift, Methanol Steam...

  7. Direct Methanol Fuel Cell Experimental and Model Validation Study

    E-Print Network [OSTI]

    Wang, Chao-Yang

    Direct Methanol Fuel Cell Experimental and Model Validation Study M. Mench, J. Scott, S. Thynell boundary Fuel cell performance Current density distribution measurements Conclusions #12;3 Method, flow rate, species inlet and fuel cell temperature, and humidity. Transparent polycarbonate windows

  8. Discovery of two new methanol masers in NGC 7538

    E-Print Network [OSTI]

    M. Pestalozzi; V. Minier; F. Motte; J. Conway

    2006-01-20T23:59:59.000Z

    Context: NGC7538 is known to host a 6.7 and 12.2GHz methanol maser cospatial with a Ultra Compact (UC) HII region, IRS1. Aims: We report on the serendipitous discovery of two additional 6.7GHz methanol masers in the same region, not associated with IRS1. Methods: Interferometry maser positions are compared with recent single-dish and interferometry continuum observations. Results: The positions of the masers agree to high accuracy with the 1.2mm continuum peak emission in NGC7538 IRS9 and NGC7538 S. This clear association is also confirmed by the positional agreement of the masers with existing high resolution continuum observations at cm and/or mm wavelengths. Conclusions: Making use of the established strong relation between methanol masers and high-mass star formation, we claim that we have accurately positioned the high-mass protostars within the regions where they are detected. The variety of objects hosting a 6.7GHz methanol maser in NGC7538 shows that this emission probably traces different evolutionary stages within the protostellar phase.

  9. Methanol market slowly tightens as Brazil starts soaking up material

    SciTech Connect (OSTI)

    Young, I.

    1992-11-25T23:59:59.000Z

    Although the US methanol market's response to mandated oxygen requirements in reformulated gasoline has been disappointing, the European market has surprisingly been tightening in recent weeks and looks set for a price rise in first-quarter 1993. The tightness is being felt mainly in the Mediterranean market, where the Libyan methanol plant is running at only 70% because of problems with gas feedstock supplies. More significantly, the Brazilian government has now given the go-ahead for a yearlong extension on imports of methanol for use as an ethanol replacement in fuel blending. The new authorization sets a monthly import limit of 48,000 m.t. during that period. Libya is an important supplier of methanol to the Brazilian market and has already shipped about 20,000 m.t. since the authorization was given. Another major supplier to Brazil is Russia, from its two giant 750,000-m.t./year plants at Gubakha and Tomsk. The material is shipped from the terminal at Yuzhnyy on the Black Sea, in Ukrainian territory since the collapse of the Soviet Union.

  10. Process Design and Integration of Shale Gas to Methanol 

    E-Print Network [OSTI]

    Ehlinger, Victoria M.

    2013-02-04T23:59:59.000Z

    pathways for the production of methanol from shale gas. The composition of the shale gas feedstock is assumed to come from the Barnett Shale Play located near Fort Worth, Texas, which is currently the most active shale gas play in the US. Process...

  11. Novel Approach to Advanced Direct Methanol Fuel Cell Anode Catalysts (Presentation)

    SciTech Connect (OSTI)

    Dinh, H.; Gennett, T.

    2010-06-11T23:59:59.000Z

    This presentation is a summary of a Novel Approach to Advanced Direct Methanol Fuel Cell Anode Catalysts.

  12. Isobaric vapor-liquid equilibria for methanol + ethanol + water and the three constituent binary systems

    SciTech Connect (OSTI)

    Kurihara, Kiyofumi; Nakamichi, Mikiyoshi; Kojima, Kazuo (Nihon Univ., Tokyo (Japan). Dept. of Industrial Chemistry)

    1993-07-01T23:59:59.000Z

    Vapor-liquid equilibrium data for methanol + ethanol + water and its three constituent binary systems methanol + ethanol, ethanol + water, and methanol + water were measured at 101.3 kPa using a liquid-vapor ebullition-type equilibrium still. The experimental binary data were correlated by the NRTL equation. The ternary system methanol + ethanol + water was predicted by means of the binary NRTL parameters with good accuracy.

  13. Complete Quantitative online Analysis of Methanol Electrooxidation Prod-ucts via Electron Impact and Electrospray Ionization Mass Spectrometry

    E-Print Network [OSTI]

    Pfeifer, Holger

    1 Complete Quantitative online Analysis of Methanol Electrooxidation Prod- ucts via Electron Impact for application in energy re- lated electrocatalysis is demonstrated using continuous methanol oxidation over

  14. A New Reference Correlation for the Viscosity of Methanol Hong Wei Xiang,a...

    E-Print Network [OSTI]

    Magee, Joseph W.

    A New Reference Correlation for the Viscosity of Methanol Hong Wei Xiang,a... Arno Laesecke for the viscosity of methanol is presented that is valid over the entire fluid region, including vapor, liquid coefficient is developed from experimental data and applied to methanol. The high-density contribution

  15. Structure of liquid and glassy methanol confined in cylindrical pores Denis Morineau1,2

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Structure of liquid and glassy methanol confined in cylindrical pores Denis Morineau1,2 , Régis scattering analysis of the density and the static structure factor of confined methanol at various and D=35 Å. A change of the thermal expansivity of confined methanol at low temperature is the signature

  16. Tropospheric methanol observations from space: retrieval1 evaluation and constraints on the seasonality of biogenic2

    E-Print Network [OSTI]

    Meskhidze, Nicholas

    1 Tropospheric methanol observations from space: retrieval1 evaluation and constraints Information1 2 3 #12; 3 1 FigureS1.Comparison of TES, IASI and airborne methanol measurements using GEOS-Chem as2 an intercomparison platform. Methanol abundance as modeled by GEOS-Chem (base-case3 simulation

  17. Journal of Power Sources 167 (2007) 265271 Simultaneous oxygen-reduction and methanol-oxidation reactions

    E-Print Network [OSTI]

    Zhao, Tianshou

    2007-01-01T23:59:59.000Z

    Journal of Power Sources 167 (2007) 265­271 Simultaneous oxygen-reduction and methanol-reduction reaction (ORR) and methanol- oxidation reaction (MOR) at the cathode of a DMFC. Good agreements between a significant poisoning effect on the ORR by the presence of methanol at the cathode. The results also indicated

  18. Department of Energy and Mineral Engineering Spring 2012 BP Methanol Separation

    E-Print Network [OSTI]

    Demirel, Melik C.

    PENNSTATE Department of Energy and Mineral Engineering Spring 2012 BP ­ Methanol Separation issues in the well heads. To counteract this problem, methanol is injected into the produced water stream at the well site. Methanol, however, is toxic to humans, animals, and plants, and must be removed before

  19. Global budget of methanol: Constraints from atmospheric observations Daniel J. Jacob,1

    E-Print Network [OSTI]

    Li, Qinbin

    Global budget of methanol: Constraints from atmospheric observations Daniel J. Jacob,1 Brendan D of atmospheric methanol to examine the consistency between observed atmospheric concentrations and current of methanol in the model is 7 days; gas-phase oxidation by OH accounts for 63% of the global sink, dry

  20. Performance modeling and cell design for high concentration methanol fuel cells

    E-Print Network [OSTI]

    Chapter 50 Performance modeling and cell design for high concentration methanol fuel cells C. E The direct methanol fuel cell (DMFC) has become a lead- ing contender to replace the lithium-ion (Li density of liquid methanol (CH3OH) fuel is 4800 Wh l-1 , whereas the theoretical energy density of Li

  1. Methane-to-Methanol Conversion by Gas-Phase Transition Metal Oxide Cations: Experiment and Theory

    E-Print Network [OSTI]

    Metz, Ricardo B.

    Methane-to-Methanol Conversion by Gas-Phase Transition Metal Oxide Cations: Experiment and Theory-phase transition metal oxide cations can convert methane to methanol. Methane activation by MO+ is discussed such as methanol has attracted great experimental and theoretical interest due to its importance as an industrial

  2. Performance and endurance of a high temperature PEM fuel cell operated on methanol reformate

    E-Print Network [OSTI]

    Kær, Søren Knudsen

    Performance and endurance of a high temperature PEM fuel cell operated on methanol reformate Samuel September 2014 Available online xxx Keywords: High temperature PEM Fuel cell Methanol Impedance spectroscopy a b s t r a c t This paper analyzes the effects of methanol and water vapor on the performance

  3. Effect of Transient Hydrogen Evolution/Oxidation Reactions on the OCV of Direct Methanol Fuel Cells

    E-Print Network [OSTI]

    Zhao, Tianshou

    Effect of Transient Hydrogen Evolution/Oxidation Reactions on the OCV of Direct Methanol Fuel Cells of a direct methanol fuel cell DMFC was observed to undergo an overshoot before it stabilized during. Available electronically August 16, 2005. Direct methanol fuel cells DMFCs are considered as a hopeful

  4. PPPL-3457 PPPL-3457 Broadening and Shifting of the Methanol 119 m Gain Line

    E-Print Network [OSTI]

    PPPL-3457 PPPL-3457 UC-70 Broadening and Shifting of the Methanol 119 µm Gain Line of Linear and Shifting of the Methanol 119 mm Gain Line of Linear and Circular Polarization by Collision with Chiral handedness of a circularly polarized probe. The broadening of the 119 mm line of the methanol molecule

  5. Three-Dimensional Simulations of Liquid Feed Direct Methanol Wenpeng Liu*,a

    E-Print Network [OSTI]

    Three-Dimensional Simulations of Liquid Feed Direct Methanol Fuel Cells Wenpeng Liu*,a and Chao that performance and design of a liquid feed direct methanol fuel cell DMFC is controlled not only by electrochemical kinetics and methanol crossover but also by water transport and by their complex interactions

  6. Quantifying global terrestrial methanol emissions using1 observations from the TES satellite sensor2

    E-Print Network [OSTI]

    Meskhidze, Nicholas

    1 Quantifying global terrestrial methanol emissions using1 observations from the TES Figure S1. December-January-Febuary (DJF, top) and June-July-August (JJA, bottom) biogenic3 methanol 1 Figure S4. Regions employed for quantifying terrestrial methanol fluxes (red) and for2

  7. The effect of methanol concentration on the performance of a passive DMFC

    E-Print Network [OSTI]

    Zhao, Tianshou

    The effect of methanol concentration on the performance of a passive DMFC J.G. Liu, T.S. Zhao *, R-breathing liquid feed direct methanol fuel cell (DMFC), with no external pumps or other auxiliary devices, was designed, fabricated and tested with different methanol concentrations. It was found that the cell

  8. Methanol adsorbates on the DMFC cathode and their effect on the cell performance

    E-Print Network [OSTI]

    Zhao, Tianshou

    Methanol adsorbates on the DMFC cathode and their effect on the cell performance J. Prabhuram, T in the performance of a direct methanol fuel cell (DMFC) occurred after the cell had been operated at a higher temperature with higher methanol concentrations as compared with the polarization data collected under

  9. Methanol, acetaldehyde, and acetone in the surface waters of the Atlantic Ocean

    E-Print Network [OSTI]

    Arnold, Steve

    Methanol, acetaldehyde, and acetone in the surface waters of the Atlantic Ocean Rachael Beale,1; revised 12 June 2013; accepted 16 July 2013; published 16 October 2013. [1] Oceanic methanol, acetaldehyde to Chile (49 N to 39 S) in 2009. Methanol (48­361 nM) and acetone (2­24 nM) varied over the track

  10. Correlating Catalytic Methanol Oxidation with the Structure and Oxidation State of Size-Selected Pt Nanoparticles

    E-Print Network [OSTI]

    Kik, Pieter

    Correlating Catalytic Methanol Oxidation with the Structure and Oxidation State of Size-Selected Pt nanoparticles (NPs) prepared by micelle encapsulation and supported on -Al2O3 during the oxidation of methanol the pretreatment. KEYWORDS: platinum, methanol oxidation, operando, XAFS, EXAFS, XANES, alumina, nanoparticle, size

  11. Discovery of molecular hydrogen line emission associated with methanol maser emission

    E-Print Network [OSTI]

    Ashley, Michael C. B.

    Discovery of molecular hydrogen line emission associated with methanol maser emission J.-K. Lee March 9 A B S T R AC T We report the discovery of H2 line emission associated with 6.67-GHz methanol emission was found associated with an ultracompact H II region IRAS 14567­5846 and isolated methanol maser

  12. PoS(IXEVNSymposium)036 Mapping the Milky Way structure with methanol and

    E-Print Network [OSTI]

    Brunthaler, Andreas

    PoS(IXEVNSymposium)036 Mapping the Milky Way structure with methanol and water masers Luca VLBA and VERA results in measuring trigonometric parallaxes of methanol and water maser sourcesS(IXEVNSymposium)036 Mapping the Milky Way structure with methanol and water masers Luca Moscadelli 1. Introduction

  13. Electronic spectroscopy of intermediates involved in the conversion of methane to methanol by FeO

    E-Print Network [OSTI]

    Metz, Ricardo B.

    Electronic spectroscopy of intermediates involved in the conversion of methane to methanol by Fe.1063/1.1448489 I. INTRODUCTION The direct oxidation of methane to an easily transport- able liquid such as methanol process and as the simplest model for alkane oxidation.1,2 Although no direct, efficient methane­methanol

  14. Development of high-power electrodes for a liquid-feed direct methanol fuel cell

    E-Print Network [OSTI]

    Development of high-power electrodes for a liquid-feed direct methanol fuel cell C. Lim, C.Y. Wang for a liquid-feed direct methanol fuel cell (DMFC) were fabricated by using a novel method of modi®ed Na.V. All rights reserved. Keywords: Direct methanol fuel cells; Membrane-electrode assembly (MEA); Polymer

  15. Mechanism of O2 Activation and Methanol Production by (Di(2-pyridyl)methanesulfonate)PtII

    E-Print Network [OSTI]

    Goddard III, William A.

    Mechanism of O2 Activation and Methanol Production by (Di(2- pyridyl)methanesulfonate)PtII Me observed for the SN2 functionalization to form methanol by two isomeric (dpms)PtIV Me(OH)2 complexes, one conversion of methane to methanol at low temper- ature is crucial for transportation of shale gas produced

  16. Molecular Dynamics of Methylamine, Methanol, and Methyl Fluoride Cations in Intense 7 Micron Laser Fields

    E-Print Network [OSTI]

    Schlegel, H. Bernhard

    Molecular Dynamics of Methylamine, Methanol, and Methyl Fluoride Cations in Intense 7 Micron Laser of methylamine (CH3NH2 + ), methanol (CH3OH+ ), and methyl fluoride (CH3F+ ) cations by short, intense laser 7 m laser pulses. This work is motivated by recent studies of methanol cations by Yamanouchi and co

  17. Partial oxidation of methanol over highly dispersed vanadia supported on silica SBA-15

    E-Print Network [OSTI]

    Bell, Alexis T.

    Partial oxidation of methanol over highly dispersed vanadia supported on silica SBA-15 C. Hessa 2005; accepted 6 August 2005 The partial oxidation of methanol to formaldehyde (FA) was studied over vanadia partly agglomerates into vanadia crystallites during methanol oxidation. KEY WORDS: supported

  18. Molecular Hydrogen from Methanol Maser Sources { Out ow from the Earliest Stage of Star Formation?

    E-Print Network [OSTI]

    Burton, Michael

    Molecular Hydrogen from Methanol Maser Sources { Out ow from the Earliest Stage of Star Formation in its natal molecular cloud. The strong methanol maser transition 5 1 { 6 0 A + at 6.7 GHz has also been that methanol maser emission usually occurs in massive star forming regions but away from the UCHII regions

  19. Passive film-induced stress and mechanical properties of a-Ti in methanol solution

    E-Print Network [OSTI]

    Volinsky, Alex A.

    Passive film-induced stress and mechanical properties of a-Ti in methanol solution Zhi Qin and film mechanical properties on a-Ti in methanol solution with varying water content was investigated. Film-induced stress in the methanol solution was measured by the flow stress differential method

  20. PoS(IXEVNSymposium)039 EVN observations of the methanol masers in Cep A

    E-Print Network [OSTI]

    van Langevelde, Huib Jan

    PoS(IXEVNSymposium)039 EVN observations of the methanol masers in Cep A Karl Torstensson Leiden observations of the 6.7 GHz methanol maser in the high mass star-forming re- gion Cepheus A. The maser emission field of the methanol masers shows an infall sig- nature rather than a rotation signature. We present

  1. Dramatic Reduction of Water Crossover in Direct Methanol Fuel Cells by Cathode Humidification

    E-Print Network [OSTI]

    concentration methanol fuel cells, the water transport coefficient through the membrane must be reducedDramatic Reduction of Water Crossover in Direct Methanol Fuel Cells by Cathode Humidification much higher than 60°C and in active air-flowing direct methanol fuel cell systems with high power

  2. Dislocations, Plasticity and Metal Forming: Proceedings of PLASTICITY'03: The Tenth International Symposium on Plasticity and its Current Applications, A.A. Khan, R. Kazmi and J. Zhou (eds.). Maryland: NEAT Press.

    E-Print Network [OSTI]

    Aubertin, Michel

    Dislocations, Plasticity and Metal Forming: Proceedings of PLASTICITY'03: The Tenth International Symposium on Plasticity and its Current Applications, A.A. Khan, R. Kazmi and J. Zhou (eds.). Maryland: NEAT Press. 570 A UNIFIED MULTIAXIAL FORMULATION TO DESCRIBE YIELDING, PLASTIC POTENTIAL, AND LIMIT STATES

  3. Methanol production from eucalyptus wood chips. Attachment V. The Florida eucalyptus energy farm: environmental impacts

    SciTech Connect (OSTI)

    Fishkind, H.H.

    1982-06-01T23:59:59.000Z

    The overall environmental impact of the eucalyptus to methanol energy system in Florida is assessed. The environmental impacts associated with the following steps of the process are considered: (1) the greenhouse and laboratory; (2) the eucalyptus plantation; (3) transporting the mature logs; (4) the hammermill; and (5) the methanol synthesis plant. Next, the environmental effects of methanol as an undiluted motor fuel, methanol as a gasoline blend, and gasoline as motor fuels are compared. Finally, the environmental effects of the eucalypt gasification/methanol synthesis system are compared to the coal liquefaction and conversion system.

  4. Emissions characterization of two methanol-fueled transit buses. Final report, April-September 1985

    SciTech Connect (OSTI)

    Ullman, T.L.; Hare, C.T.

    1986-02-01T23:59:59.000Z

    Exhaust emissions from the two methanol-powered buses used in the California Methanol Bus Demonstration have been characterized. The M.A.N. SU 240 bus is powered by M.A.N.'s D2566 FMUH methanol engine, and utilizes catalytic exhaust aftertreatment. The GMC RTS II 04 bus is powered by a first-generation DDAD 6V-92TA methanol engine without exhaust aftertreatment. Emissions of HC, CO, NO, unburned methanol, aldehydes, total particulates, and soluble fraction of particulate were determined for both buses over steady-state and transient chassis dynamometer test cycles. Emission levels from the M.A.N. bus were considerably lower than those from the GMC bus, with the exception of NO. Comparison of emission levels from methanol- and diesel-powered buses indicates that substantial reduction in emissions (especially particulate and NO) are possible with careful implementation of methanol fueling.

  5. High specific power, direct methanol fuel cell stack

    DOE Patents [OSTI]

    Ramsey, John C. (Los Alamos, NM); Wilson, Mahlon S. (Los Alamos, NM)

    2007-05-08T23:59:59.000Z

    The present invention is a fuel cell stack including at least one direct methanol fuel cell. A cathode manifold is used to convey ambient air to each fuel cell, and an anode manifold is used to convey liquid methanol fuel to each fuel cell. Tie-bolt penetrations and tie-bolts are spaced evenly around the perimeter to hold the fuel cell stack together. Each fuel cell uses two graphite-based plates. One plate includes a cathode active area that is defined by serpentine channels connecting the inlet manifold with an integral flow restrictor to the outlet manifold. The other plate includes an anode active area defined by serpentine channels connecting the inlet and outlet of the anode manifold. Located between the two plates is the fuel cell active region.

  6. Methanol Along the Path from Envelope to Protoplanetary Disc

    E-Print Network [OSTI]

    Drozdovskaya, Maria N; Visser, Ruud; Harsono, Daniel; van Dishoeck, Ewine F

    2014-01-01T23:59:59.000Z

    Interstellar methanol is considered to be a parent species of larger, more complex organic molecules. A physicochemical simulation of infalling parcels of matter is performed for a low-mass star-forming system to trace the chemical evolution from cloud to disc. An axisymmetric 2D semi-analytic model generates the time-dependent density and velocity distributions, and full continuum radiative transfer is performed to calculate the dust temperature and the UV radiation field at each position as a function of time. A comprehensive gas-grain chemical network is employed to compute the chemical abundances along infall trajectories. Two physical scenarios are studied, one in which the dominant disc growth mechanism is viscous spreading, and another in which continuous infall of matter prevails. The results show that the infall path influences the abundance of methanol entering each type of disc, ranging from complete loss of methanol to an enhancement by a factor of > 1 relative to the prestellar phase. Critical ch...

  7. Vapor-liquid equilibria for methanol + tetraethylene glycol dimethyl ether

    SciTech Connect (OSTI)

    Esteve, X.; Chaudhari, S.K.; Coronas, A. [Univ. Rovira i Virgili, Tarragona (Spain). Dept. of Electrical and Mechanical Engineering

    1995-11-01T23:59:59.000Z

    Vapor-liquid equilibrium (P-T-x) for the methanol + tetraethylene glycol dimethyl ether binary system were obtained by the static method in the range of temperatures from 293.15 to 423.15 K at 10 K intervals. The modified vapor pressure apparatus used is described. The Kuczynsky method was used to calculate the liquid and vapor composition and the activity coefficients of methanol from the initial composition of the sample and the measured pressure and temperature. The results were correlated by the NRTL and UNIQUAC temperature dependent activity coefficient models. This system shows nearly ideal behavior at 323.15 K, but positive deviations from ideality at lower temperatures and negative deviations at higher temperatures are observed. The activity coefficients become more negative with the increase in temperature and mole fraction of methanol. The excess molar enthalpy using the Gibss-Helmholtz equation and the NRTL and UNIQUAC parameters were calculated at 303.15 K and compared with experimental data. This binary system shows promise as a working pair for high-temperature heat pump applications.

  8. Unbiased water and methanol maser surveys of NGC 1333

    SciTech Connect (OSTI)

    Lyo, A-Ran; Kim, Jongsoo; Byun, Do-Young; Lee, Ho-Gyu, E-mail: arl@kasi.re.kr [Korea Astronomy and Space Science Institute, 776, Daedeokdae-ro Yuseong-gu, Daejeon 305-348 (Korea, Republic of)

    2014-11-01T23:59:59.000Z

    We present the results of unbiased 22 GHz H{sub 2}O water and 44 GHz class I CH{sub 3}OH methanol maser surveys in the central 7' × 10' area of NGC 1333 and two additional mapping observations of a 22 GHz water maser in a ?3' × 3' area of the IRAS4A region. In the 22 GHz water maser survey of NGC 1333 with a sensitivity of ? ? 0.3 Jy, we confirmed the detection of masers toward H{sub 2}O(B) in the region of HH 7-11 and IRAS4B. We also detected new water masers located ?20'' away in the western direction of IRAS4B or ?25'' away in the southern direction of IRAS4A. We could not, however, find young stellar objects or molecular outflows associated with them. They showed two different velocity components of ?0 and ?16 km s{sup –1}, which are blue- and redshifted relative to the adopted systemic velocity of ?7 km s{sup –1} for NGC 1333. They also showed time variabilities in both intensity and velocity from multi-epoch observations and an anti-correlation between the intensities of the blue- and redshifted velocity components. We suggest that the unidentified power source of these masers might be found in the earliest evolutionary stage of star formation, before the onset of molecular outflows. Finding this kind of water maser is only possible through an unbiased blind survey. In the 44 GHz methanol maser survey with a sensitivity of ? ? 0.5 Jy, we confirmed masers toward IRAS4A2 and the eastern shock region of IRAS2A. Both sources are also detected in 95 and 132 GHz methanol maser lines. In addition, we had new detections of methanol masers at 95 and 132 GHz toward IRAS4B. In terms of the isotropic luminosity, we detected methanol maser sources brighter than ?5 × 10{sup 25} erg s{sup –1} from our unbiased survey.

  9. The Neo-Flex LCD Arm is the perfect accessory to add flexibility to your LCD monitor or TV. Sleek and streamlined, it frees up desk space and allows you

    E-Print Network [OSTI]

    Saskatchewan, University of

    The Neo-Flex LCD Arm is the perfect accessory to add flexibility to your LCD monitor or TV. Sleek lifting the LCD with the other hand. Then position the LCD where you want it and release the button. It. Highlights · Great value at a great price · Easily position your LCD or TV for maximum comfort

  10. Direct Methanol Fuel Cell Corporation DMFCC | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand JumpConceptual Model,DOE FacilityDimondale, Michigan: Energy Resources Jump to:1999) |Methanol Fuel

  11. air-breathing direct methanol: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to Direct Methanol Materials Science Websites Summary: increases the overall cost of the cell, reducing the fuel conversion efficiency. An alternative to H2): Application to...

  12. Indirect conversion of coal to methanol and gasoline: product price vs product slate

    SciTech Connect (OSTI)

    Wham, R.M.; McCracken, D.J.; Forrester, R.C. III

    1980-01-01T23:59:59.000Z

    The Oak Ridge National Laboratory (ORNL) conducts process analysis and engineering evaluation studies for the Department of Energy to provide, on a consistent basis, technical and economic assessments of processes and systems for coal conversion and utilization. Such assessments permit better understanding of the relative technical and economic potential of these processes. The objective of the work described here was to provide an assessment of the technical feasibility, economic competitiveness, and environmental acceptability of selected indirect coal liquefaction processes on a uniform, consistent, and impartial basis. Particular emphasis is placed on production of methanol as a principal product or methanol production for conversion to gasoline. Potential uses for the methanol are combustion in peaking-type turbines or blending with gasoline to yield motor fuel. Conversion of methanol to gasoline is accomplished through the use of the Mobil methanol-to-gasoline (MTG) process. Under the guidance of ORNL, Fluor Engineers and Constructors, Houston Division, prepared four conceptual process designs for indirect conversion of a Western subbituminous coal to either methanol or gasoline. The conceptual designs are based on the use of consistent technology for the core of the plant (gasification through methanol synthesis) with additional processing as necessary for production of different liquid products of interest. The bases for the conceptual designs are given. The case designations are: methanol production for turbine-grade fuel; methanol production for gasoline blending; gasoline production with coproduction of SNG; and gasoline production maximized.

  13. Liquid-liquid equilibrium of cyclohexane-n-hexane-methanol mixtures; Effect of water content

    SciTech Connect (OSTI)

    Alessi, P.; Fermeglia, M.; Kikic, I. (Istituto di Chimica Applicata e Industriale, University of Trieste, via Valerio 2, I-34127 Trieste (IT))

    1989-04-01T23:59:59.000Z

    Experimental liquid-liquid equilibrium data for the ternary system cyclohexane-n-hexane-methanol and for the binary systems n-hexane-methanol and cyclohexane-methanol are presented over a temperature range from 284 to 298{Kappa} at pressure of 0.1 MPa. Attention is given to the effect of the purity of methanol as far as the water content is concerned. The data are correlated by means of excess Gibbs energy models (NRTL and UNIQUAC), and the binary interaction parameters are reported.

  14. Catalytic decomposition of methanol at various temperatures and several liquid hourly space velocities

    E-Print Network [OSTI]

    Gupta, Yashpal Satyapal

    1975-01-01T23:59:59.000Z

    to quantitatively analyze the products of the reactions. Based on the results obtained, a scheme is presented by which methanol can be converted to a gaseous fuel consisting of dimethyl ether (50K), carbon monoxide ( 16 . 67K) and hyrdogen (33 . 33K) . Dedicated... is produced by catalytically dehydrating methanol over a y-alumina catalyst to produce dimethyl ether and dehydrogenating methanol to CO and H& over a methanol synthesis catalyst and then mixing these gases in the proportion of 50% dimethyl ether, 33. 33K...

  15. H-D Substitution in Interstellar Solid Methanol: A Key Route for D Enrichment

    E-Print Network [OSTI]

    Akihiro Nagaoka; Naoki Watanabe; Akira Kouchi

    2005-03-28T23:59:59.000Z

    Deuterium enrichment of interstellar methanol is reproduced experimentally for the first time via grain-surface H-D substitution in solid methanol at an atomic D/H ratio of 0.1. Although previous gas-grain models successfully reproduce the deuterium enrichments observed in interstellar methanol molecules (D/H of up to 0.4, compared to the cosmic ratio of $\\sim 10^{-5})$, the models exclusively focus on deuterium fractionation resulting from the successive addition of atomic hydrogen/deuterium on CO. The mechanism proposed here represents a key route for deuterium enrichment that reproduces the high observed abundances of deuterated methanol, including multiple deuterations.

  16. STATISTICAL PROPERTIES OF 12.2 GHz METHANOL MASERS ASSOCIATED WITH A COMPLETE SAMPLE OF 6.7 GHz METHANOL MASERS

    SciTech Connect (OSTI)

    Breen, S. L.; Caswell, J. L.; Green, J. A.; Voronkov, M. A. [CSIRO Astronomy and Space Science, P.O. Box 76, Epping, NSW 1710 (Australia); Ellingsen, S. P. [School of Mathematics and Physics, University of Tasmania, Private Bag 37, Hobart, Tasmania 7001 (Australia); Fuller, G. A.; Quinn, L. J.; Avison, A., E-mail: Shari.Breen@csiro.au [Jodrell Bank Centre for Astrophysics, Alan Turing Building, School of Physics and Astronomy, University of Manchester, Manchester M13 9PL (United Kingdom)

    2011-06-01T23:59:59.000Z

    We present definitive detection statistics for 12.2 GHz methanol masers toward a complete sample of 6.7 GHz methanol masers detected in the Methanol Multibeam survey south of declination -20{sup 0}. In total, we detect 250 12.2 GHz methanol masers toward 580 6.7 GHz methanol masers. This equates to a detection rate of 43.1%, which is lower than that of previous significant searches of comparable sensitivity. Both the velocity ranges and the flux densities of the target 6.7 GHz sources surpass that of their 12.2 GHz companion in almost all cases. Eighty percent of the detected 12.2 GHz methanol maser peaks are coincident in velocity with the 6.7 GHz maser peak. Our data support an evolutionary scenario whereby the 12.2 GHz sources are associated with a somewhat later evolutionary stage than the 6.7 GHz sources devoid of this transition. Furthermore, we find that the 6.7 GHz and 12.2 GHz methanol sources increase in luminosity as they evolve. In addition to this, evidence for an increase in velocity range with evolution is presented. This implies that it is not only the luminosity but also the volume of gas conducive to the different maser transitions that increases as the sources evolve. Comparison with GLIMPSE mid-infrared sources has revealed a coincidence rate between the locations of the 6.7 GHz methanol masers and GLIMPSE point sources similar to that achieved in previous studies. Overall, the properties of the GLIMPSE sources with and without 12.2 GHz counterparts are similar. There is a higher 12.2 GHz detection rate toward those 6.7 GHz methanol masers that are coincident with extended green objects.

  17. Desorption Kinetics of Methanol, Ethanol, and Water from Graphene

    SciTech Connect (OSTI)

    Smith, R. Scott; Matthiesen, Jesper; Kay, Bruce D.

    2014-09-18T23:59:59.000Z

    The desorption kinetics of methanol, ethanol, and water from graphene covered Pt(111) are investigated. The temperature programmed desorption (TPD) spectra for both methanol and ethanol have well-resolved first, second, third, and multilayer layer desorption peaks. The alignment of the leading edges is consistent with zero-order desorption kinetics from all layers. In contrast, for water the first and second layers are not resolved. At low water coverages (< 1 ML) the initial desorption leading edges are aligned but then fall out of alignment at higher temperatures. For thicker water layers (10 to 100 ML), the desorption leading edges are in alignment throughout the desorption of the film. The coverage dependence of the desorption behavoir suggests that at low water coverages the non-alignment of the desorption leading edges is due to water dewetting from the graphene substrate. Kinetic simulations reveal that the experimental results are consistent with zero-order desorption. The simulations also show that fractional order desorption kinetics would be readily apparent in the experimental TPD spectra.

  18. Solid-state thermal behavior and stability studies of theophylline-citric acid cocrystals prepared by neat cogrinding or thermal treatment

    SciTech Connect (OSTI)

    Hsu, Po-Chun; Lin, Hong-Liang [Department of Biotechnology, Yuanpei University, Hsin Chu, Taiwan (China); Wang, Shun-Li, E-mail: wangshunli@mail.ncyu.edu.tw [Department of Applied Chemistry, National Chia Yi University, Chia Yi, Taiwan (China); Lin, Shan-Yang, E-mail: sylin@mail.ypu.edu.tw [Department of Biotechnology, Yuanpei University, Hsin Chu, Taiwan (China)

    2012-08-15T23:59:59.000Z

    To investigate the thermal behavior of cocrystal formed between anhydrous theophylline (TP) and anhydrous citric acid (CA) by neat manual cogrinding or thermal treatment, DSC and FTIR microspectroscopy with curve-fitting analysis were applied. The physical mixture and 60-min ground mixture were stored at 55{+-}0.5 Degree-Sign C/40{+-}2% RH condition to determine their stability behavior. Typical TP-CA cocrystals were prepared by slow solvent evaporation method. Results indicate that the cogrinding process could gradually induce the cocrystal formation between TP and CA. The IR spectral peak shift from 3495 to 3512 cm{sup -1} and the stepwise appearance of several new IR peaks at 1731, 1712, 1676, 1651, 1557 and 1265 cm{sup -1} with cogrinding time suggest that the mechanism of TP-CA cocrystal formation was evidenced by interacting TP with CA through the intermolecular O-H{center_dot}{center_dot}{center_dot}O hydrogen bonding. The stability of 60-min ground mixture of TP-CA was confirmed at 55{+-}0.5 Degree-Sign C/40{+-}2% RH condition over a storage time of 60 days. - Garphical abstract: Cogrinding, thermal and solvent-evaporation methods might easily induce the theophylline-citric acid cocrystal formation. Highlights: Black-Right-Pointing-Pointer Cogrinding process could gradually induce the cocrystal formation between TP and CA. Black-Right-Pointing-Pointer The TP-CA cocrystal was formed through the intermolecular O-H{center_dot}{center_dot}{center_dot}O hydrogen bonding. Black-Right-Pointing-Pointer The 60-min TP-CA ground mixture was similar to the solvent-evaporated cocrystal. Black-Right-Pointing-Pointer The thermal-induced TP-CA cocrystal formation was confirmed by pre-heating the physical mixture to 152 Degree-Sign C. Black-Right-Pointing-Pointer The 60-min TP-CA ground mixture was stable at accelerated condition over a storage time of 60 days.

  19. Methanol Reformer System Modeling and Control using an Adaptive Neuro-Fuzzy Inference System approach

    E-Print Network [OSTI]

    Andreasen, Søren Juhl

    Methanol Reformer System Modeling and Control using an Adaptive Neuro-Fuzzy Inference System East, Denmark Introduction This work presents a control strategy for a reformed methanol fuel cell system, which uses a reformer to produce hydrogen for a HTPEM fuel cell. Such systems can advantageously

  20. Control of a methanol reformer system using an Adaptive NeuroFuzzy Inference System approach

    E-Print Network [OSTI]

    Andreasen, Søren Juhl

    Control of a methanol reformer system using an Adaptive NeuroFuzzy Inference System approach, Denmark Introduction This work presents a stoichiometry control strategy for a reformed methanol fuel cell system, which uses a reformer to produce hydrogen for an HTPEM fuel cell. One such system is the Serenus

  1. Control and experimental characterization of ap methanol reformer for a 350W HTPEM FC system

    E-Print Network [OSTI]

    Kolaei, Alireza Rezania

    Control and experimental characterization of ap methanol reformer for a 350W HTPEM FC system Søren@et.aau.dk 33 #12;From prototype to commercial product dk 4 www.serenergy.dk #12;Integrated methanol reformerC Reformer temperature 200-300oC System parameters Weight 13.7 kg Volume 27 L sja@et.aau.dk 5 #12

  2. Experimental Observations in the Morita Baylis-Hillman Reaction in Methanol

    E-Print Network [OSTI]

    Plata, Robert Erik

    2013-05-22T23:59:59.000Z

    -energy profile for a Morita Baylis-Hillman reaction in methanol. Although the majority of this dissertation will be about the Morita Baylis-Hillman reaction in methanol, it could not have been fully accomplished without having to study the Morita Baylis...

  3. APPLICATION OF MEMS TECHNOLOGY TO MICRO DIRECT METHANOL FUEL CELL Xiaowei Liu*

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    APPLICATION OF MEMS TECHNOLOGY TO MICRO DIRECT METHANOL FUEL CELL Xiaowei Liu* , Chunguang Suo, email: lxw@hit.edu.cn) ABSTRACT In view of micro fuel cells, the silicon processes are employed for microfabrication of the micro direct methanol fuel cell (DMFC). Using the MEMS technology we have successfully made

  4. Design of Extraction Column Methanol Recovery System for the TAME Reactive Distillation Process

    E-Print Network [OSTI]

    Al-Arfaj, Muhammad A.

    Design of Extraction Column Methanol Recovery System for the TAME Reactive Distillation Process system for TAME reactive distillation process using extraction column with water as a solvent. The design distillation column which was optimized to recover methanol and recycle water to the extraction column. Other

  5. Hydrogen Bond Dissociation and Reformation in Methanol Oligomers Following Hydroxyl Stretch Relaxation

    E-Print Network [OSTI]

    Fayer, Michael D.

    Hydrogen Bond Dissociation and Reformation in Methanol Oligomers Following Hydroxyl Stretch, 2002 Vibrational relaxation and hydrogen bond dynamics in methanol-d dissolved in CCl4 have been-d molecules both accepting and donating hydrogen bonds at 2500 cm-1 . Following vibrational relaxation

  6. The Reactivity Limit for Methanol Oxidation on Platinum/Ruthenium Catalysts

    E-Print Network [OSTI]

    The Reactivity Limit for Methanol Oxidation on Platinum/Ruthenium Catalysts A. Wieckowski 0.5 1.0 1.5 2.0 2.5 3.0 Pt/Ru Decorated (UIUC) PtRu Alloy (JM) E = 0.4 V Oxidation in 0.5 M Methanol

  7. Methanol masers : Reliable tracers of the early stages of high-mass star formation

    E-Print Network [OSTI]

    S. P. Ellingsen

    2005-10-07T23:59:59.000Z

    The GLIMPSE and MSX surveys have been used to examine the mid-infrared properties of a statistically complete sample of 6.7 GHz methanol masers. The GLIMPSE point sources associated with methanol masers are clearly distinguished from the majority, typically having extremely red mid-infrared colors, similar to those expected of low-mass class 0 young stellar objects. The intensity of the GLIMPSE sources associated with methanol masers is typically 4 magnitudes brighter at 8.0 micron than at 3.6 micron. Targeted searches towards GLIMPSE point sources with [3.6]-[4.5] > 1.3 and an 8.0 micron magnitude less than 10 will detect more than 80% of class II methanol masers. Many of the methanol masers are associated with sources within infrared dark clouds (IRDC) which are believed to mark regions where high-mass star formation is in its very early stages. The presence of class II methanol masers in a significant fraction of IRDC suggests that high-mass star formation is common in these regions. Different maser species are thought to trace different evolutionary phases of the high-mass star formation process. Comparison of the properties of the GLIMPSE sources associated with class II methanol masers and other maser species shows interesting trends, consistent with class I methanol masers tracing a generally earlier evolutionary phase and OH masers tracing a later evolutionary phase.

  8. A novel electrode architecture for passive direct methanol fuel cells R. Chen, T.S. Zhao *

    E-Print Network [OSTI]

    Zhao, Tianshou

    A novel electrode architecture for passive direct methanol fuel cells R. Chen, T.S. Zhao 6 November 2006 Abstract The supply of cathode reactants in a passive direct methanol fuel cell: Fuel cell; Passive DMFC; Metal foam; Mass transfer resistance; Cell performance; Oxygen transport 1

  9. Electrochimica Acta 52 (2006) 14091416 Optimization of cathode catalyst layer for direct methanol fuel cells

    E-Print Network [OSTI]

    2006-01-01T23:59:59.000Z

    methanol fuel cells (DMFCs) features a large thickness and mass transport loss due to higher Pt loading electrolyte fuel cells, as a result of an optimum balance of proton transport and oxygen diffusion. Different rights reserved. Keywords: Direct methanol fuel cell; Cathode; Catalyst layer; Porosity distribution

  10. Experimental Observations in the Morita Baylis-Hillman Reaction in Methanol 

    E-Print Network [OSTI]

    Plata, Robert Erik

    2013-05-22T23:59:59.000Z

    -energy profile for a Morita Baylis-Hillman reaction in methanol. Although the majority of this dissertation will be about the Morita Baylis-Hillman reaction in methanol, it could not have been fully accomplished without having to study the Morita Baylis...

  11. Spectroscopy and dynamics of mixtures of water with acetone, acetonitrile, and methanol

    E-Print Network [OSTI]

    Spectroscopy and dynamics of mixtures of water with acetone, acetonitrile, and methanol Dean S mixtures of water with acetone, acetonitrile, and methanol over their entire range of compositions have and acetonitrile mixtures. Spatial distribution functions are reported for the acetone/water system. © 2000

  12. Methanol masers as tools to study high-mass star formation

    E-Print Network [OSTI]

    Michele Pestalozzi

    2007-04-23T23:59:59.000Z

    In this contribution I will attempt to show that the study of galactic 6.7 and 12.2GHz methanol masers themselves, as opposed to the use of methanol masers as signposts, can yield important conclusions contributing to the understanding of high-mass star formation. Due to their exclusive association with star formation, methanol masers are the best tools to do this, and their large number allows to probe the entire Galaxy. In particular I will focus on the determination of the luminosity function of methanol masers and on the determination of an unambiguous signature for a circumstellar masing disc seen edge-on. Finally I will try to point out some future fields of research in the study of methanol masers.

  13. Investigation of the flame speeds of propane/methanol gas mixtures

    SciTech Connect (OSTI)

    Foote, K.L.; Villareal, J.

    1985-05-02T23:59:59.000Z

    A series of tests was conducted in an acoustically tuned flame tube in order to determine the laminar burning velocities in air of various propane/methanol gas mixtures. The experimental method is explained in detail, along with the tabular results. A 90% propane, 10% methanol mixture is shown to have a maximum burning velocity of 40.8 cm/s. A 65% propane, 35% methanol mixture has a maximum velocity of 41.8 cm/s. These maximum flame speeds are shown to be about the same as that of pure propane by the same method. Gulder has found evidence that the presence of methanol in some hydrocarbon fuels may actually inhibit combustion, but we see no apparent modifications in the combustion of propane when mixed with methanol.

  14. Modeling of the anode side of a direct methanol fuel cell with analytical solutions

    E-Print Network [OSTI]

    Mosquera, Martín A

    2010-01-01T23:59:59.000Z

    In this work, analytical solutions were derived (for any methanol oxidation reaction order) for the profiles of methanol concentration and proton current density by assuming diffusion mass transport mechanism, Tafel kinetics, and fast proton transport in the anodic catalyst layer of a direct methanol fuel cell. An expression for the Thiele modulus that allows to express the anodic overpotential as a function of the cell current, and kinetic and mass transfer parameters was obtained. For high cell current densities, it was found that the Thiele modulus ($\\phi^2$) varies quadratically with cell current density; yielding a simple correlation between anodic overpotential and cell current density. Analytical solutions were derived for the profiles of both local methanol concentration in the catalyst layer and local anodic current density in the catalyst layer. Under the assumptions of the model presented here, in general, the local methanol concentration in the catalyst layer cannot be expressed as an explicit fun...

  15. Methanol synthesis using a catalyst combination of alkali or alkaline earth salts and reduced copper chromite

    DOE Patents [OSTI]

    Tierney, John W. (Pittsburgh, PA); Wender, Irving (Pittsburgh, PA); Palekar, Vishwesh M. (Pittsburgh, PA)

    1995-01-01T23:59:59.000Z

    The present invention relates to a novel route for the synthesis of methanol, and more specifically to the production of methanol by contacting synthesis gas under relatively mild conditions in a slurry phase with a catalyst combination comprising reduced copper chromite and basic alkali salts or alkaline earth salts. The present invention allows the synthesis of methanol to occur in the temperature range of approximately 100.degree.-160.degree. C. and the pressure range of 40-65 atm. The process produces methanol with up to 90% syngas conversion per pass and up to 95% methanol selectivity. The only major by-product is a small amount of easily separated methyl formate. Very small amounts of water, carbon dioxide and dimethyl ether are also produced. The present catalyst combination also is capable of tolerating fluctuations in the H.sub.2 /CO ratio without major deleterious effect on the reaction rate. Furthermore, carbon dioxide and water are also tolerated without substantial catalyst deactivation.

  16. Methanol synthesis using a catalyst combination of alkali or alkaline earth salts and reduced copper chromite

    DOE Patents [OSTI]

    Tierney, J.W.; Wender, I.; Palekar, V.M.

    1995-01-24T23:59:59.000Z

    The present invention relates to a novel route for the synthesis of methanol, and more specifically to the production of methanol by contacting synthesis gas under relatively mild conditions in a slurry phase with a catalyst combination comprising reduced copper chromite and basic alkali salts or alkaline earth salts. The present invention allows the synthesis of methanol to occur in the temperature range of approximately 100--160 C and the pressure range of 40--65 atm. The process produces methanol with up to 90% syngas conversion per pass and up to 95% methanol selectivity. The only major by-product is a small amount of easily separated methyl formate. Very small amounts of water, carbon dioxide and dimethyl ether are also produced. The present catalyst combination also is capable of tolerating fluctuations in the H[sub 2]/CO ratio without major deleterious effect on the reaction rate. Furthermore, carbon dioxide and water are also tolerated without substantial catalyst deactivation.

  17. Supporting information Figure S1: Pump-rePump-Probe kinetics of peridinin in methanol. Peridinin was excited at

    E-Print Network [OSTI]

    van Stokkum, Ivo

    Supporting information Figure S1: Pump-rePump-Probe kinetics of peridinin in methanol. Peridinin spectra (black lines) measured after excitation of peridinin in methanol at 400 nm and dumping at 3 ps

  18. Electron-Stimulated Reactions and O-2 Production in Methanol-Covered Amorphous Solid Water Films

    SciTech Connect (OSTI)

    Akin, Minta C.; Petrik, Nikolay G.; Kimmel, Gregory A.

    2009-03-14T23:59:59.000Z

    The low-energy, electron-stimulated desorption (ESD) of molecular products from amorphous solid water (ASW) films capped with methanol is investigated versus methanol coverage (0 - 4 x 1015 cm-2) at 50 K using 100 eV incident electrons. The major ESD products from a monolayer of methanol on ASW are quite similar to the ESD products from bulk methanol film: H2, CH4, H2O, C2H6, CO, CH2O, and CH3OH. For 40 ML ASW films, the molecular oxygen, hydrogen, and water ESD yields from the ASW are suppressed with increasing methanol coverage, while the CH3OH ESD yield increases proportionally to the methanol coverage. The suppression of the water ESD products by methanol is consistent with the non-thermal reactions occurring preferentially at or near the ASW/vacuum interface and not in the interior of the film. The water and molecular hydrogen ESD yields from the water layer decrease exponentially with the methanol cap coverage with 1/e constants of ~ 0.6 x 1015 cm-2 and 1.6 x 1015 cm-2, respectively. In contrast, the O2 ESD from the water layer is very efficiently quenched by small amounts of methanol (1/e ~ 6.5 x 1013 cm-2). The rapid suppression of O2 production by small amounts of methanol is due to reactions between CH3OH and the precursors for the O2 - mainly OH radicals. A kinetic model for the O2 ESD which semi-quantitatively accounts for the observations is presented.

  19. Detection of 6.7 GHz methanol absorption towards hot corinos

    E-Print Network [OSTI]

    J. D. Pandian; S. Leurini; K. M. Menten; A. Belloche; P. F. Goldsmith

    2008-08-14T23:59:59.000Z

    Methanol masers at 6.7 GHz have been found exclusively towards high-mass star forming regions. Recently, some Class 0 protostars have been found to display conditions similar to what are found in hot cores that are associated with massive star formation. These hot corino sources have densities, gas temperatures, and methanol abundances that are adequate for exciting strong 6.7 GHz maser emission. This raises the question of whether 6.7 GHz methanol masers can be found in both hot corinos and massive star forming regions, and if not, whether thermal methanol emission can be detected. We searched for the 6.7 GHz methanol line towards five hot corino sources in the Perseus region using the Arecibo radio telescope. To constrain the excitation conditions of methanol, we observed thermal submillimeter lines of methanol in the NGC1333-IRAS 4 region with the APEX telescope. We did not detect 6.7 GHz emission in any of the sources, but found absorption against the cosmic microwave background in NGC1333-IRAS 4A and NGC1333-IRAS 4B. Using a large velocity gradient analysis, we modeled the excitation of methanol over a wide range of physical parameters, and verify that the 6.7 GHz line is indeed strongly anti-inverted for densities lower than 10^6 cm^-3. We used the submillimeter observations of methanol to verify the predictions of our model for IRAS 4A by comparison with other CH3OH transitions. Our results indicate that the methanol observations from the APEX and Arecibo telescopes are consistent with dense (n ~ 10^6 cm^-3), cold (T ~ 15-30 K) gas. The lack of maser emission in hot corinos and low-mass protostellar objects in general may be due to densities that are much higher than the quenching density in the region where the radiation field is conducive to maser pumping.

  20. Direct Methanol Fuel Cell Prototype Demonstration for Consumer Electronics Applications

    SciTech Connect (OSTI)

    Carlstrom, Charles, M., Jr.

    2009-07-07T23:59:59.000Z

    This report is the final technical report for DOE Program DE-FC36-04GO14301 titled “Direct Methanol Fuel Cell Prototype Demonstration for Consumer Electronics Applications”. Due to the public nature of this report some of the content reported in confidential reports and meetings to the DOE is not covered in detail in this report and some of the content has been normalized to not show actual values. There is a comparison of the projects accomplishments with the objectives, an overview of some of the key subsystem work, and a review of the three levels of prototypes demonstrated during the program. There is also a description of the eventual commercial product and market this work is leading towards. The work completed under this program has significantly increased the understanding of how Direct Methanol Fuel Cells (DMFC) can be deployed successfully to power consumer electronic devices. The prototype testing has demonstrated the benefits a direct methanol fuel cell system has over batteries typically used for powering consumer electronic devices. Three generations of prototypes have been developed and tested for performance, robustness and life. The technologies researched and utilized in the fuel cell stack and related subsystems for these prototypes are leveraged from advances in other industries such as the hydrogen fueled PEM fuel cell industry. The work under this program advanced the state of the art of direct methanol fuel cells. The system developed by MTI micro fuel cells aided by this program differs significantly from conventional DMFC designs and offers compelling advantages in the areas of performance, life, size, and simplicity. The program has progressed as planned resulting in the completion of the scope of work and available funding in December 2008. All 18 of the final P3 prototypes builds have been tested and the results showed significant improvements over P2 prototypes in build yield, initial performance, and durability. The systems have demonstrated robust operation when tested at various orientations, temperatures, and humidity levels. Durability testing has progressed significantly over the course of the program. MEA, engine, and system level steady state testing has demonstrated degradation rates acceptable for initial product introduction. Test duration of over 5000 hrs has been achieved at both the MEA and breadboard system level. P3 level prototype life testing on engines (stacks with reactant conditioning) showed degradation rates comparable to carefully constructed lab fixtures. This was a major improvement over the P2 and P1 engine designs, which exhibited substantial reductions in life and performance between the lab cell and the actual engine. Over the course of the work on the P3 technology set, a platform approach was taken to the system design. By working in this direction, a number of product iterations with substantial market potential were identified. Although the main effort has been the development of a prototype charger for consumer electronic devices, multiple other product concepts were developed during the program showing the wide variety of potential applications.

  1. Control and experimental characterization of a methanol reformer for a 350WControl and experimental characterization of a methanol reformer for a 350Wp high temperature polymer electrolyte membrane fuel cell systemhigh temperature polymer electrolyte memb

    E-Print Network [OSTI]

    Berning, Torsten

    Control and experimental characterization of a methanol reformer for a 350WControl and experimental characterization of a methanol reformer for a 350Wp high temperature polymer electrolyte membrane fuel cell, 9220 Aalborg East, Denmarkp gy gy g y pp g Introd ction Steam reforming of methanol for a HTPEM f el

  2. Identification of the Active Species in Photochemical Hole Scavenging Reactions of Methanol on TiO2

    SciTech Connect (OSTI)

    Shen, Mingmin; Henderson, Michael A.

    2011-11-03T23:59:59.000Z

    Molecular and dissociative methanol adsorption species were prepared on rutile TiO2(110) surfaces to study photocatalytic oxidation of methanol in ultrahigh vacuum (UHV) using temperature-programmed desorption (TPD). Adsorbed methoxy groups (CH3O-) were found to be the photoactive form of adsorbed methanol converted to adsorbed formaldehyde and a surface OH group by hole-mediated C-H bond cleavage. These results suggest that adsorbed methoxy is the effective hole scavenger in photochemical reactions involving methanol.

  3. Recovery Act: Advanced Direct Methanol Fuel Cell for Mobile Computing

    SciTech Connect (OSTI)

    Fletcher, James H. [University of North Florida; Cox, Philip [University of North Florida; Harrington, William J [University of North Florida; Campbell, Joseph L [University of North Florida

    2013-09-03T23:59:59.000Z

    ABSTRACT Project Title: Recovery Act: Advanced Direct Methanol Fuel Cell for Mobile Computing PROJECT OBJECTIVE The objective of the project was to advance portable fuel cell system technology towards the commercial targets of power density, energy density and lifetime. These targets were laid out in the DOE’s R&D roadmap to develop an advanced direct methanol fuel cell power supply that meets commercial entry requirements. Such a power supply will enable mobile computers to operate non-stop, unplugged from the wall power outlet, by using the high energy density of methanol fuel contained in a replaceable fuel cartridge. Specifically this project focused on balance-of-plant component integration and miniaturization, as well as extensive component, subassembly and integrated system durability and validation testing. This design has resulted in a pre-production power supply design and a prototype that meet the rigorous demands of consumer electronic applications. PROJECT TASKS The proposed work plan was designed to meet the project objectives, which corresponded directly with the objectives outlined in the Funding Opportunity Announcement: To engineer the fuel cell balance-of-plant and packaging to meet the needs of consumer electronic systems, specifically at power levels required for mobile computing. UNF used existing balance-of-plant component technologies developed under its current US Army CERDEC project, as well as a previous DOE project completed by PolyFuel, to further refine them to both miniaturize and integrate their functionality to increase the system power density and energy density. Benefits of UNF’s novel passive water recycling MEA (membrane electrode assembly) and the simplified system architecture it enabled formed the foundation of the design approach. The package design was hardened to address orientation independence, shock, vibration, and environmental requirements. Fuel cartridge and fuel subsystems were improved to ensure effective fuel containment. PROJECT OVERVIEW The University of North Florida (UNF), with project partner the University of Florida, recently completed the Department of Energy (DOE) project entitled “Advanced Direct Methanol Fuel Cell for Mobile Computing”. The primary objective of the project was to advance portable fuel cell system technology towards the commercial targets as laid out in the DOE R&D roadmap by developing a 20-watt, direct methanol fuel cell (DMFC), portable power supply based on the UNF innovative “passive water recovery” MEA. Extensive component, sub-system, and system development and testing was undertaken to meet the rigorous demands of the consumer electronic application. Numerous brassboard (nonpackaged) systems were developed to optimize the integration process and facilitating control algorithm development. The culmination of the development effort was a fully-integrated, DMFC, power supply (referred to as DP4). The project goals were 40 W/kg for specific power, 55 W/l for power density, and 575 Whr/l for energy density. It should be noted that the specific power and power density were for the power section only, and did not include the hybrid battery. The energy density is based on three, 200 ml, fuel cartridges, and also did not include the hybrid battery. The results show that the DP4 system configured without the methanol concentration sensor exceeded all performance goals, achieving 41.5 W/kg for specific power, 55.3 W/l for power density, and 623 Whr/l for energy density. During the project, the DOE revised its technical targets, and the definition of many of these targets, for the portable power application. With this revision, specific power, power density, specific energy (Whr/kg), and energy density are based on the total system, including fuel tank, fuel, and hybridization battery. Fuel capacity is not defined, but the same value is required for all calculations. Test data showed that the DP4 exceeded all 2011 Technical Status values; for example, the DP4 energy density was 373 Whr/l versus the DOE 2011 status of 200 Whr/l. For the

  4. Experimental Evaluation of a Pt-based Heat Exchanger Methanol Reformer for a HTPEM Fuel Cell Stack

    E-Print Network [OSTI]

    Berning, Torsten

    Experimental Evaluation of a Pt-based Heat Exchanger Methanol Reformer for a HTPEM Fuel Cell Stack as e.g. methanol as the hydrogen carrier and reforming it to a hydrogen rich gas can solve some of these storage issues. The work presented here examines the use of a heat exchanger methanol reformer for use

  5. 976 JOURNAL OF MICROELECTROMECHANICAL SYSTEMS, VOL. 15, NO. 4, AUGUST 2006 Methanol Steam Reformer on a Silicon Wafer

    E-Print Network [OSTI]

    Malen, Jonathan A.

    976 JOURNAL OF MICROELECTROMECHANICAL SYSTEMS, VOL. 15, NO. 4, AUGUST 2006 Methanol Steam Reformer of the reforming rates, heat transfer and flow through a methanol reforming catalytic microreactor fabri- cated is achieved through on-chip resis- tive heaters, whereby methanol steam reforming reactions were studied over

  6. In Proc of Direct Methanol Fuel Cell Symposium, 199th Electrochem.l Soc. Mtg, Washington DC, 3/01.

    E-Print Network [OSTI]

    Wang, Chao-Yang

    In Proc of Direct Methanol Fuel Cell Symposium, 199th Electrochem.l Soc. Mtg, Washington DC, 3/01. MATHEMATICAL MODELING OF LIQUID-FEED DIRECT METHANOL FUEL CELLS Z. H. Wang and C. Y. Wang Electrochemical methanol fuel cells (DMFC). Diffusion and convection of both gas and liquid phases are considered

  7. Journal of Power Sources 164 (2007) 189195 Modeling water transport in liquid feed direct methanol fuel cells

    E-Print Network [OSTI]

    2007-01-01T23:59:59.000Z

    Journal of Power Sources 164 (2007) 189­195 Modeling water transport in liquid feed direct methanol management in direct methanol fuel cells (DMFCs) is very critical and complicated because of many interacting rights reserved. Keywords: Direct methanol fuel cell; Water transport; Mathematical modeling; Three

  8. The role of specific solvent modes in the non-radiative relaxation of an excess electron in methanol

    E-Print Network [OSTI]

    in methanol A.A. Mosyak, O.V. Prezhdo1 , P.J. Rossky* Department of Chemistry and Biochemistry, University electronic excited state of an excess electron in methanol. Compared to water, we find that the presence in methanol. The first solvation shell dominates the electronic coupling, most strongly through rotational

  9. Methanol as a Sensitive Probe for Spatial and Temporal Variations of the Proton-to-Electron Mass Ratio

    E-Print Network [OSTI]

    Methanol as a Sensitive Probe for Spatial and Temporal Variations of the Proton-to-Electron Mass, corresponding to the 51 ! 60Aþ and 20 ! 3À1E transitions in methanol (CH3OH), respectively, are among transitions in the ground state of methanol to a variation of the proton-to- electron mass ratio. We show

  10. Effect of surface composition of Pt-Au alloy cathode catalyst on the performance of direct methanol fuel cells

    E-Print Network [OSTI]

    Zhao, Tianshou

    Effect of surface composition of Pt-Au alloy cathode catalyst on the performance of direct methanol 2010 Available online 12 June 2010 Keywords: Fuel cell Direct methanol fuel cell Catalyst Active Site Pt-Au alloy a b s t r a c t A pure Pt cathode catalyst in direct methanol fuel cells is not only

  11. Uptake and Surface Reaction of Methanol by Sulfuric Acid Solutions Investigated by Vibrational Sum Frequency Generation and Raman Spectroscopies

    E-Print Network [OSTI]

    Uptake and Surface Reaction of Methanol by Sulfuric Acid Solutions Investigated by Vibrational SumVised Manuscript ReceiVed: June 4, 2008 The uptake of methanol at the air-liquid interface of 0-96.5 wt % sulfuric methanol and H2SO4 to form methyl hydrogen sulfate. The surface is saturated with the methyl species after

  12. arXiv:0812.0905v2[astro-ph]9Dec2008 Distances to Galactic methanol masers

    E-Print Network [OSTI]

    van Langevelde, Huib Jan

    arXiv:0812.0905v2[astro-ph]9Dec2008 Distances to Galactic methanol masers Kazi L. J. Rygl Max parallax measurements of 6.7 GHz methanol masers in star forming regions of the Galaxy. The 6.7 GHz methanol maser transition is a very valuable astrometric tool, for its large stability and confined

  13. arXiv:1102.0854v1[astro-ph.GA]4Feb2011 Studies of methanol maser rings

    E-Print Network [OSTI]

    De Buizer, James Michael

    arXiv:1102.0854v1[astro-ph.GA]4Feb2011 Studies of methanol maser rings Anna Bartkiewicz, Marian present the results of studies of a new class of 6.7 GHz methanol maser sources with a ring- like emission-like distribution of methanol maser spots. Using the Gemini telescopes we found mid-infrared (MIR) counterparts

  14. Digestion of milk protein and methanol-grown bacteria protein in the preruminant calf. II. Amino acid composition of

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Digestion of milk protein and methanol-grown bacteria protein in the preruminant calf. II. Amino of milk and of methanol-grown bacteria in the terminal small intestine and the hindgut of the preruminant exclusively by skim-milk powder ; 50.5 p. 100 of the protein of the bacte- ria diet was supplied by methanol

  15. arXiv:0812.0905v1[astro-ph]4Dec2008 Distances to Galactic methanol masers

    E-Print Network [OSTI]

    Brunthaler, Andreas

    arXiv:0812.0905v1[astro-ph]4Dec2008 Distances to Galactic methanol masers Kazi L. J. Rygl£ Max parallax measurements of 6.7 GHz methanol masers in star forming regions of the Galaxy. The 6.7 GHz methanol maser transition is a very valuable astrometric tool, for its large stability and confined

  16. Mass transport phenomena in direct methanol fuel cells T.S. Zhao*, C. Xu, R. Chen, W.W. Yang

    E-Print Network [OSTI]

    Zhao, Tianshou

    Mass transport phenomena in direct methanol fuel cells T.S. Zhao*, C. Xu, R. Chen, W.W. Yang January 2009 Available online 20 February 2009 Keywords: Fuel cell Direct methanol fuel cell Mass cells ­ direct methanol fuel cells (DMFCs). We present a comprehensive review of the state

  17. Mechanistic Studies of Methanol Oxidation to Formaldehyde on Isolated Vanadate Sites Supported on High Surface Area Anatase

    E-Print Network [OSTI]

    Bell, Alexis T.

    Mechanistic Studies of Methanol Oxidation to Formaldehyde on Isolated Vanadate Sites Supported for methanol oxidation on both TiO2 and V/TiO2 was investigated using temperature- programmed experiments/TiO2 sample consists predominantly of isolated VO4 units after calcination. Methanol was found

  18. Interaction of methanol and water on MgO,,100... studied by ultraviolet photoelectron and metastable impact electron spectroscopies

    E-Print Network [OSTI]

    Goodman, Wayne

    Interaction of methanol and water on MgO,,100... studied by ultraviolet photoelectron; accepted 27 October 1998 The coadsorption of methanol (CH3OH) and water (D2O) on the MgO 100 /Mo 100 photoelectron spectroscopy UPS HeI , and by thermal programmed desorption TPD . Methanol wets the MgO surface

  19. Mechanistic Studies of Methanol Oxidation to Formaldehyde on Isolated Vanadate Sites Supported on High Surface Area Zirconia

    E-Print Network [OSTI]

    Bell, Alexis T.

    Mechanistic Studies of Methanol Oxidation to Formaldehyde on Isolated Vanadate Sites Supported, California 94720-1462 ReceiVed: NoVember 20, 2007; In Final Form: February 6, 2008 The oxidation of methanol that the vanadium is present as isolated VO4 units in a distorted tetrahedral geometry. Methanol was found to adsorb

  20. Effects of Methanol on the Thermodynamics of Iron(III) [Tetrakis(pentafluorophenyl)]porphyrin Chloride Dissociation and the

    E-Print Network [OSTI]

    Bell, Alexis T.

    Effects of Methanol on the Thermodynamics of Iron(III) [Tetrakis in acetonitrile but is catalytically active if the solvent contains methanol. It was suggested that the precursor to the active species is (F20TPP)Fe(OCH3) in methanol-containing solvents. The present study was aimed

  1. Water and Methanol Adsorption on MgO(100)/Mo(100) Studied by Electron Spectroscopies and Thermal Programmed Desorption

    E-Print Network [OSTI]

    Goodman, Wayne

    Water and Methanol Adsorption on MgO(100)/Mo(100) Studied by Electron Spectroscopies and Thermal, 2000 The adsorption of methanol (CH3OH) and water (D2O) on the MgO(100)/Mo(100) surface at 100 K has covered MgO(100)/Mo(100) surface. On the other hand, the formation of a methanol multilayer desorption

  2. Detection of a methanol megamaser in a major-merger galaxy

    E-Print Network [OSTI]

    Chen, Xi; Baan, Willem A; Qiao, Hai-Hua; Li, Juan; An, Tao; Breen, Shari L

    2015-01-01T23:59:59.000Z

    We have detected emission from both the 4_{-1}-3_{0} E (36.2~GHz) class I and 7_{-2}-8_{-1} E (37.7~GHz) class II methanol transitions towards the centre of the closest ultra-luminous infrared galaxy Arp 220. The emission in both the methanol transitions show narrow spectral features and have luminosities approximately 8 orders of magnitude stronger than that observed from typical class I methanol masers observed in Galactic star formation regions. The emission is also orders of magnitude stronger than the expected intensity of thermal emission from these transitions and based on these findings we suggest that the emission from the two transitions are masers. These observations provides the first detection of a methanol megamaser in the 36.2 and 37.7 GHz transitions and represents only the second detection of a methanol megamaser, following the recent report of an 84 GHz methanol megamaser in NGC1068. We find the methanol megamasers are significantly offset from the nuclear region and arise towards regions wh...

  3. Test method for the measurement of methanol emissions from stationary sources

    SciTech Connect (OSTI)

    Pate, B.A.; Peterson, M.R.; Rickman, E.E.; Jayanty, R.K.M.

    1994-05-01T23:59:59.000Z

    Methanol was designated under Title III of the Clean Air Act Amendments of 1990 as a pollutant to be regulated. A test method has been developed for the measurement of methanol emissions from stationary sources. The methanol sampling train (MST) consists of a glass-lined heated probe, two condensate knockout traps, and three sorbent cartridges packed with Anasorb 747. The Anasorb samples were desorbed with a 1:1 mixture of carbon disulfide and N,N-dimethylformamide. All samples were analyzed by gas chromatography with flame ionization detection. Following laboratory testing, field tests of the MST and the National Council of the Paper Industry for Air and Stream Improvement (NCASI) sampling method for methanol were conducted at two pulp and paper mills. In accordance with EPA Methol 301, two pairs of trains were run in parallel for six runs, collecting a total of 24 samples by each method. During each run, half of the trains were spiked with a known amount of methanol. The sampling location at the first test was an inlet vent to a softwood bleach plant scrubber where the methanol concentration was about 30 ppm. A second field test was conducted at the vent of a black liquor oxidation tank where the methanol concentration was about 350 ppm. Samples were shown to be stable for at least 2 weeks after collection.

  4. A 95 GHz CLASS I METHANOL MASER SURVEY TOWARD GLIMPSE EXTENDED GREEN OBJECTS (EGOs)

    SciTech Connect (OSTI)

    Chen Xi; Shen Zhiqiang; Gan Conggui [Key Laboratory for Research in Galaxies and Cosmology, Shanghai Astronomical Observatory, Chinese Academy of Sciences, Shanghai 200030 (China); Ellingsen, Simon P.; Titmarsh, Anita, E-mail: chenxi@shao.ac.cn [School of Mathematics and Physics, University of Tasmania, Hobart, Tasmania (Australia)

    2011-09-01T23:59:59.000Z

    We report the results of a systematic survey for 95 GHz class I methanol masers toward a new sample of 192 massive young stellar object candidates associated with ongoing outflows (known as extended green objects or EGOs) identified from the Spitzer Galactic Legacy Infrared Mid-Plane Survey Extraordinaire (GLIMPSE) survey. The observations were made with the Australia Telescope National Facility (ATNF) Mopra 22 m radio telescope and resulted in the detection of 105 new 95 GHz class I methanol masers. For 92 of the sources our observations provide the first identification of a class I maser transition associated with these objects (i.e., they are new class I methanol maser sources). Our survey proves that there is indeed a high detection rate (55%) of class I methanol masers toward EGOs. Comparison of the GLIMPSE point sources associated with EGOs with and without class I methanol maser detections shows that they have similar mid-IR colors, with the majority meeting the color selection criteria -0.6 < [5.8]-[8.0] < 1.4 and 0.5 < [3.6]-[4.5] < 4.0. Investigations of the Infrared Array Camera and Multiband Imaging Photometer for Spitzer 24 {mu}m colors and the associated millimeter dust clump properties (mass and density) of the EGOs for the sub-samples based on the class of methanol masers they are associated with suggest that the stellar mass range associated with class I methanol masers extends to lower masses than for class II methanol masers, or alternatively class I methanol masers may be associated with more than one evolutionary phase during the formation of a high-mass star.

  5. THE ROLE OF METHANOL IN THE CRYSTALLIZATION OF TITAN'S PRIMORDIAL OCEAN

    SciTech Connect (OSTI)

    Deschamps, Frederic [Institute of Geophysics, Swiss Federal Institute of Technology Zurich, 8092 Zurich (Switzerland); Mousis, Olivier [Universite de Franche-Comte, Institut UTINAM, CNRS/INSU, UMR 6213, 25030 Besancon Cedex (France); Sanchez-Valle, Carmen [Institute of Geochemistry and Petrology, Swiss Federal Institute of Technology Zurich, 8092 Zurich (Switzerland); Lunine, Jonathan I., E-mail: frederic.deschamps@erdw.ethz.c [Dipartimento di Fisica, Universita degli Studi di Roma 'Tor Vergata', Rome (Italy)

    2010-12-01T23:59:59.000Z

    A key parameter that controls the crystallization of primordial oceans in large icy moons is the presence of anti-freeze compounds, which may have maintained primordial oceans over the age of the solar system. Here we investigate the influence of methanol, a possible anti-freeze candidate, on the crystallization of Titan's primordial ocean. Using a thermodynamic model of the solar nebula and assuming a plausible composition of its initial gas phase, we first calculate the condensation sequence of ices in Saturn's feeding zone, and show that in Titan's building blocks methanol can have a mass fraction of {approx}4 wt% relative to water, i.e., methanol can be up to four times more abundant than ammonia. We then combine available data on the phase diagram of the water-methanol system and scaling laws derived from thermal convection to estimate the influence of methanol on the dynamics of the outer ice I shell and on the heat transfer through this layer. For a fraction of methanol consistent with the building blocks composition we determined, the vigor of convection in the ice I shell is strongly reduced. The effect of 5 wt% methanol is equivalent to that of 3 wt% ammonia. Thus, if methanol is present in the primordial ocean of Titan, the crystallization may stop, and a sub-surface ocean may be maintained between the ice I and high-pressure ice layers. A preliminary estimate indicates that the presence of 4 wt% methanol and 1 wt% ammonia may result in an ocean of thickness at least 90 km.

  6. Alumina catalysts for reduction of NOx from methanol fueled diesel engine

    SciTech Connect (OSTI)

    Yamamoto, Toshiro; Noda, Akira; Sakamoto, Takashi; Sato, Yoshio [Ministry of Transport of Japan, Kumamoto (Japan)

    1996-09-01T23:59:59.000Z

    NOx selective reducing catalysts are expected to be used for lean-burn gasoline engines and diesel engines as an effective NOx reduction measure. The authors are interested in the combination of methanol, as a reducing agent, and alumina catalyst, and have considered the NOx reduction method using effectively much unburned methanol. In this report, in order to investigate the effect of NOx reduction by the alumina catalyst, the experiment was carried out by feeding the actual exhaust gas from the methanol engine into the alumina catalyst. As a result, it was confirmed that, without addition of any other reducing agents into the exhaust gas, the alumina catalyst has activity to reduce NOx.

  7. Catalytic conversion of methanol to low molecular weight olefins in a fluidized bed reactor

    E-Print Network [OSTI]

    Garza Tobias, Ricardo

    1983-01-01T23:59:59.000Z

    the production of methane, CO, and CO, . Also methanol conversion to coke was increased with temperature. The space velocity was a significant variable in determining the final product distribution and also in the rate of coke formation. The olefins... in the feed and catalyst age on propane yields, T~430'C (Methanol-DME conversion was greater than 95% on all experiments except 313 where it was 73%) The effect of dilution in the feed and catalyst age on the methane yields, T 430'C (Methanol...

  8. The environment of the strongest galactic methanol maser

    E-Print Network [OSTI]

    Sanna, A; Carrasco-Gonzalez, C; Reid, M J; Ellingsen, S P; Brunthaler, A; Moscadelli, L; Cesaroni, R; Krishnan, V

    2015-01-01T23:59:59.000Z

    The high-mass star-forming site G009.62-00.20E hosts the 6.7 GHz methanol maser source with the greatest flux density in the Galaxy which has been flaring periodically over the last ten years. We performed high-resolution astrometric measurements of the CH3OH, H2O, and OH maser emission and 7 mm continuum in the region. The radio continuum emission was resolved in two sources separated by 1300 AU. The CH3OH maser cloudlets are distributed along two north-south ridges of emission to the east and west of the strongest radio continuum component. This component likely pinpoints a massive young stellar object which heats up its dusty envelope, providing a constant IR pumping for the Class II CH3OH maser transitions. We suggest that the periodic maser activity may be accounted for by an independent, pulsating, IR radiation field provided by a bloated protostar in the vicinity of the brightest masers. We also report about the discovery of an elliptical distribution of CH3OH maser emission in the region of periodic v...

  9. SHAPE SELECTIVE NANOCATALYSTS FOR DIRECT METHANOL FUEL CELL APPLICATIONS

    SciTech Connect (OSTI)

    Murph, S.

    2012-09-12T23:59:59.000Z

    While gold and platinum have long been recognized for their beauty and value, researchers at the Savannah River National Laboratory (SRNL) are working on the nano-level to use these elements for creative solutions to our nation's energy and security needs. Multiinterdisciplinary teams consisting of chemists, materials scientists, physicists, computational scientists, and engineers are exploring unchartered territories with shape-selective nanocatalysts for the development of novel, cost effective and environmentally friendly energy solutions to meet global energy needs. This nanotechnology is vital, particularly as it relates to fuel cells.SRNL researchers have taken process, chemical, and materials discoveries and translated them for technological solution and deployment. The group has developed state-of-the art shape-selective core-shell-alloy-type gold-platinum nanostructures with outstanding catalytic capabilities that address many of the shortcomings of the Direct Methanol Fuel Cell (DMFC). The newly developed nanostructures not only busted the performance of the platinum catalyst, but also reduced the material cost and overall weight of the fuel cell.

  10. An Experimental Investigation of Microexplosion in Emulsified Vegetable-Methanol Blend

    E-Print Network [OSTI]

    Nam, Hyungseok

    2012-07-16T23:59:59.000Z

    of shock waves characteristic of explosions at larger scales. However, little is known about how emulsion composition and droplet size affect the micro-explosion process. Through this research, methanol-in-vegetable oil emulsion has been studied from...

  11. WATER AND METHANOL MASER ACTIVITIES IN THE NGC 2024 FIR 6 REGION

    SciTech Connect (OSTI)

    Choi, Minho; Kang, Miju; Byun, Do-Young [Korea Astronomy and Space Science Institute, 776 Daedeokdaero, Yuseong, Daejeon 305-348 (Korea, Republic of); Lee, Jeong-Eun, E-mail: minho@kasi.re.kr [Department of Astronomy and Space Science, Kyung Hee University, Yongin, Gyeonggi 446-701 (Korea, Republic of)

    2012-11-10T23:59:59.000Z

    The NGC 2024 FIR 6 region was observed in the water maser line at 22 GHz and the methanol class I maser lines at 44, 95, and 133 GHz. The water maser spectra displayed several velocity components and month-scale time variabilities. Most of the velocity components may be associated with FIR 6n, while one component was associated with FIR 4. A typical lifetime of the water maser velocity components is about eight months. The components showed velocity fluctuations with a typical drift rate of about 0.01 km s{sup -1} day{sup -1}. The methanol class I masers were detected toward FIR 6. The methanol emission is confined within a narrow range around the systemic velocity of the FIR 6 cloud core. The methanol masers suggest the existence of shocks driven by either the expanding H II region of FIR 6c or the outflow of FIR 6n.

  12. Methanol Synthesis from CO2 Hydrogenation over a Pd4/In2O3 Model...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Synthesis from CO2 Hydrogenation over a Pd4In2O3 Model Catalyst: A Combined DFT and Kinetic Study. Methanol Synthesis from CO2 Hydrogenation over a Pd4In2O3 Model Catalyst: A...

  13. Conversion of methanol to light olefins on SAPO-34: kinetic modeling and reactor design

    E-Print Network [OSTI]

    Al Wahabi, Saeed M. H.

    2005-02-17T23:59:59.000Z

    design of an MTO reactor, accounting for the strong exothermicity of the process. Multi-bed adiabatic and fluidized bed technologies show good potential for the industrial process for the conversion of methanol into olefins....

  14. A KINETIC S'FUDY OF METHANOL SYNTHESIS IN A SLURRY REACTOR USING

    Office of Scientific and Technical Information (OSTI)

    Of Advisory Committee: Dr. A. Akgerrnan A kinetic model that describes the methanol production rate over a CuOZnOA120 3 catalyst (United Catalyst L-951) at typical industrial...

  15. First VLBI observations of methanol maser polarisation, in G339.88-1.2

    E-Print Network [OSTI]

    R. Dodson

    2008-04-14T23:59:59.000Z

    We investigate class II methanol masers and the environment in which they form with the Long Baseline Array (LBA). Using full polarisation VLBI, we're able to measure the magnetic field directions so as to distinguish between the two main models of the environment in which methanol masers form: disks or shocks. We present polarised images of the methanol maser source G339.88-1.2, made with the LBA at 6.7-GHz. With these first polarisation maps made with the LBA, which successfully reproduce observations with the ATCA confirming the new AIPS code, a new technique for Southern VLBI is opened. The magnetic field directions found are inconstant with methanol masers arising in disks for the majority of the emission.

  16. The molecular environment of massive star forming cores associated with Class II methanol maser emission

    E-Print Network [OSTI]

    S. N. Longmore; M. G. Burton; P. J. Barnes; T. Wong; C. R. Purcell; J. Ott

    2007-04-13T23:59:59.000Z

    Methanol maser emission has proven to be an excellent signpost of regions undergoing massive star formation (MSF). To investigate their role as an evolutionary tracer, we have recently completed a large observing program with the ATCA to derive the dynamical and physical properties of molecular/ionised gas towards a sample of MSF regions traced by 6.7 GHz methanol maser emission. We find that the molecular gas in many of these regions breaks up into multiple sub-clumps which we separate into groups based on their association with/without methanol maser and cm continuum emission. The temperature and dynamic state of the molecular gas is markedly different between the groups. Based on these differences, we attempt to assess the evolutionary state of the cores in the groups and thus investigate the role of class II methanol masers as a tracer of MSF.

  17. Design of high-ionic conductivity electrodes for direct methanol fuel cells

    E-Print Network [OSTI]

    Schrauth, Anthony J

    2011-01-01T23:59:59.000Z

    Carbon-supported porous electrodes are used in low-temperature fuel cells to provide maximum catalyst surface area, while taking up little volume and using minimum catalyst material. In Direct Methanol Fuel Cells (DMFCs), ...

  18. Two-phase microfluidics, heat and mass transport in direct methanol fuel cells

    E-Print Network [OSTI]

    CHAPTER 9 Two-phase microfluidics, heat and mass transport in direct methanol fuel cells G. Lu & C, including two-phase microfluidics, heat and mass transport. We explain how the better understanding

  19. Electrochimica Acta 52 (2007) 52665271 Effect of methanol crossover on the cathode behavior of a DMFC

    E-Print Network [OSTI]

    Zhao, Tianshou

    2007-01-01T23:59:59.000Z

    of methanol crossover on the cathode behavior. Open circuit potentials, cyclic voltammetry profiles, polarization curves and electrochemical impedance spectroscopy (EIS), resulting from the oxygen reduction measurements indicated that both current and open circuit potential of the electrode exhibited significant

  20. An Experimental Investigation of Microexplosion in Emulsified Vegetable-Methanol Blend 

    E-Print Network [OSTI]

    Nam, Hyungseok

    2012-07-16T23:59:59.000Z

    of shock waves characteristic of explosions at larger scales. However, little is known about how emulsion composition and droplet size affect the micro-explosion process. Through this research, methanol-in-vegetable oil emulsion has been studied from...

  1. Methane Oxidation to Methanol without CO2 Emission: Catalysis by Atomic Negative Ions

    E-Print Network [OSTI]

    Tesfamichael, Aron; Felfli, Zineb; Msezane, Alfred Z

    2014-01-01T23:59:59.000Z

    The catalytic activities of the atomic Y-, Ru-, At-, In-, Pd-, Ag-, Pt-, and Os- ions have been investigated theoretically using the atomic Au- ion as the benchmark for the selective partial oxidation of methane to methanol without CO2 emission. Dispersion-corrected density-functional theory has been used for the investigation. From the energy barrier calculations and the thermodynamics of the reactions, we conclude that the catalytic effect of the atomic Ag-, At-, Ru-, and Os- ions is higher than that of the atomic Au- ion catalysis of CH4 conversion to methanol. By controlling the temperature around 290K (Os-), 300K (Ag-), 310K (At-), 320K (Ru-) and 325K (Au-) methane can be completely oxidized to methanol without the emission of CO2. We conclude by recommending the investigation of the catalytic activities of combinations of the above negative ions for significant enhancement of the selective partial oxidation of methane to methanol.

  2. Methanol Dehydrogenation and Oxidation on Pt(111) in Alkaline Jacob S. Spendelow, Jason D. Goodpaster, Paul J. A. Kenis, and Andrzej Wieckowski*

    E-Print Network [OSTI]

    Kenis, Paul J. A.

    Methanol Dehydrogenation and Oxidation on Pt(111) in Alkaline Solutions Jacob S. Spendelow, Jason D, and oxidation of methanol on Pt(111) in alkaline solutions has been examined from a fundamental mechanistic.COhasbeenconfirmedasthemainpoisoningspecies,affectingtherateofmethanoldehydrogenation primarily through repulsive interactions with methanol dehydrogenation intermediates. At direct methanol

  3. Computational study of ion distributions at the air/liquid methanol interface

    SciTech Connect (OSTI)

    Sun, Xiuquan; Wick, Collin D.; Dang, Liem X.

    2011-06-16T23:59:59.000Z

    Molecular dynamic simulations with polarizable potentials were performed to systematically investigate the distribution of NaCl, NaBr, NaI, and SrCl2 at the air/liquid methanol interface. The density profiles indicated that there is no substantial enhancement of anions at the interface for the NaX systems in contrast to what was observed at the air/aqueous interface. The surfactant-like shape of the larger more polarizable halide anions is compensated by the surfactant nature of methanol itself. As a result, methanol hydroxy groups strongly interacted with one side of polarizable anions, in which their induced dipole points, and methanol methyl groups were more likely to be found near the positive pole of anion induced dipoles. Furthermore, salts were found to disrupt the surface structure of methanol, reducing the observed enhancement of methyl groups at the outer edge of the air/liquid methanol interface. With the additional of salts to methanol, the computed surface potentials increased, which is in contrast to what is observed in corresponding aqueous systems, where the surface potential decreases with the addition of salts. Both of these trends have been indirectly observed with experiments. This was found to be due to the propensity of anions for the air/water interface that is not present at the air/liquid methanol interface. This work was supported by the US Department of Energy Basic Energy Sciences' Chemical Sciences, Geosciences & Biosciences Division. Pacific Northwest National Laboratory is operated by Battelle for the US Department of Energy.

  4. A SEARCH FOR 95 GHz CLASS I METHANOL MASERS IN MOLECULAR OUTFLOWS

    SciTech Connect (OSTI)

    Gan, Cong-Gui; Chen, Xi; Shen, Zhi-Qiang [Key Laboratory for Research in Galaxies and Cosmology, Shanghai Astronomical Observatory, Chinese Academy of Sciences, 80 Nandan RD, Shanghai 200030 (China)] [Key Laboratory for Research in Galaxies and Cosmology, Shanghai Astronomical Observatory, Chinese Academy of Sciences, 80 Nandan RD, Shanghai 200030 (China); Xu, Ye; Ju, Bing-Gang, E-mail: cggan@shao.ac.cn [Key Laboratory of Radio Astronomy, Chinese Academy of Sciences (China)] [Key Laboratory of Radio Astronomy, Chinese Academy of Sciences (China)

    2013-01-20T23:59:59.000Z

    We have observed a sample of 288 molecular outflow sources including 123 high-mass and 165 low-mass sources in order to search for class I methanol masers at the 95 GHz transition and to investigate the relationship between outflow characteristics and class I methanol maser emission with the Purple Mountain Observatory 13.7 m radio telescope. Our survey detected 62 sources with 95 GHz methanol masers above a 3{sigma} detection limit, which includes 47 high-mass sources and 15 low-mass sources. Therefore, the detection rate is 38% for high-mass outflow sources and 9% for low-mass outflow sources, suggesting that class I methanol masers are relatively easily excited in high-mass sources. There are 37 newly detected 95 GHz methanol masers (including 27 high-mass and 10 low-mass sources), 19 of which are newly identified (i.e., first identification) class I methanol masers (including 13 high-mass and 6 low-mass sources). A statistical analysis of the distributions of maser detections with the outflow parameters reveals that the maser detection efficiency increases with the outflow properties (e.g., mass, momentum, kinetic energy, mechanical luminosity of outflows, etc.). Systematic investigations of the relationships between the intrinsic luminosity of methanol masers and the outflow properties (including mass, momentum, kinetic energy, bolometric luminosity, and mass-loss rate of the central stellar sources) indicate a positive correlation. This further supports the theory that class I methanol masers are collisionally pumped and associated with shocks when outflows interact with the surrounding ambient medium.

  5. Development of microprocessor control for a V-6 engine fueled by prevaporized methanol

    E-Print Network [OSTI]

    Schneider, Donald F.

    1985-01-01T23:59:59.000Z

    DEVELOPMENT OF MICROPROCESSOR CONTROL FOR A V 6 ENGINE FUELED BY PREVAPORIZED METHANOL A Thesis by DONALD F. SCHNEIDER Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirements for the degree... of MASTER OF SCIENCE August 19SS Major Subject: Chemical Engineering DEVELOPMENT OF MICROPROCESSOR CONTROL FOR A V 6 ENGINE FUELED BY PREVAPORIZED METHANOL A Thesis by DONALD F. SCHNEIDER Approved as to style and content by: JP& r~ R. R. Davison...

  6. Conversion of synthesis gas and methanol to hydrocarbons using zeolite catalysts

    E-Print Network [OSTI]

    Matthews, Michael Anthony

    1984-01-01T23:59:59.000Z

    and dimethyl ether to hydrocarbons on ZSM-5. Kikuchu et al. (1984) report that the activity of ZSM-5 for methanol conversion decreased, but olefin selectivity increased, with decreasing alumina content. Relatively little information has been published... and oxygenates (methanol and dimethyl ether). Relatively little gaseous olefins were formed. The effect of the ZSM-5 support was to greatly reduce methane formation and to completely eliminate oxygenates. Table 1 Conversion of Synthesis Gas Over ZSM-5...

  7. Selective enrichment of a methanol-utilizing consortium using pulp & paper mill waste streams

    SciTech Connect (OSTI)

    Gregory R. Mockos; William A. Smith; Frank J. Loge; David N. Thompson

    2007-04-01T23:59:59.000Z

    Efficient utilization of carbon inputs is critical to the economic viability of the current forest products sector. Input carbon losses occur in various locations within a pulp mill, including losses as volatile organics and wastewater . Opportunities exist to capture this carbon in the form of value-added products such as biodegradable polymers. Waste activated sludge from a pulp mill wastewater facility was enriched for 80 days for a methanol-utilizing consortium with the goal of using this consortium to produce biopolymers from methanol-rich pulp mill waste streams. Five enrichment conditions were utilized: three high-methanol streams from the kraft mill foul condensate system, one methanol-amended stream from the mill wastewater plant, and one methanol-only enrichment. Enrichment reactors were operated aerobically in sequencing batch mode at neutral pH and 25°C with a hydraulic residence time and a solids retention time of four days. Non-enriched waste activated sludge did not consume methanol or reduce chemical oxygen demand. With enrichment, however, the chemical oxygen demand reduction over 24 hour feed/decant cycles ranged from 79 to 89 %, and methanol concentrations dropped below method detection limits. Neither the non-enriched waste activated sludge nor any of the enrichment cultures accumulated polyhydroxyalkanoates (PHAs) under conditions of nitrogen sufficiency. Similarly, the non-enriched waste activated sludge did not accumulate PHAs under nitrogen limited conditions. By contrast, enriched cultures accumulated PHAs to nearly 14% on a dry weight basis under nitrogen limited conditions. This indicates that selectively-enriched pulp mill waste activated sludge can serve as an inoculum for PHA production from methanol-rich pulp mill effluents.

  8. How do methanol masers manage to appear in the youngest star vicinities and isolated molecular clumps?

    E-Print Network [OSTI]

    A. M. Sobolev; D. M. Cragg; S. P. Ellingsen; M. J. Gaylard; S. Goedhart; C. Henkel; M. S. Kirsanova; A. B. Ostrovskii; N. V. Pankratova; O. V. Shelemei; D. J. van der Walt; T. S. Vasyunina; M. A. Voronkov

    2007-06-21T23:59:59.000Z

    General characteristics of methanol (CH3OH) maser emission are summarized. It is shown that methanol maser sources are concentrated in the spiral arms. Most of the methanol maser sources from the Perseus arm are associated with embedded stellar clusters and a considerable portion is situated close to compact HII regions. Almost 1/3 of the Perseus Arm sources lie at the edges of optically identified HII regions which means that massive star formation in the Perseus Arm is to a great extent triggered by local phenomena. A multiline analysis of the methanol masers allows us to determine the physical parameters in the regions of maser formation. Maser modelling shows that class II methanol masers can be pumped by the radiation of the warm dust as well as by free-free emission of a hypercompact region hcHII with a turnover frequency exceeding 100 GHz. Methanol masers of both classes can reside in the vicinity of hcHIIs. Modelling shows that periodic changes of maser fluxes can be reproduced by variations of the dust temperature by a few percent which may be caused by variations in the brightness of the central young stellar object reflecting the character of the accretion process. Sensitive observations have shown that the masers with low flux densities can still have considerable amplification factors. The analysis of class I maser surveys allows us to identify four distinct regimes that differ by the series of their brightest lines.

  9. Methanol production from eucalyptus wood chips. Attachment III. Florida's eucalyptus energy farm and methanol refinery: the background environment

    SciTech Connect (OSTI)

    Fishkind, H.H.

    1982-04-01T23:59:59.000Z

    A wide array of general background information is presented on the Central Florida area in which the eucalyptus energy plantation and methanol refinery will be located. Five counties in Central Florida may be affected by the project, DeSoto, Hardee, Hillsborough, Manatee, and Polk. The human resources of the area are reviewed. Included are overviews of population demographic and economic trends. Land use patterns and the transportation are system described, and the region's archeological and recreational resources are evaluated. The region's air quality is emphasized. The overall climate is described along with noise and air shed properties. An analysis of the region's water resources is included. Ground water is discussed first followed by an analysis of surface water. Then the overall quality and water supply/demand balance for the area is evaluated. An overview of the region's biota is presented. Included here are discussions of the general ecosystems in Central Florida, and an analysis of areas with important biological significance. Finally, land resources are examined.

  10. Mechanism of Methanol Synthesis on Cu through CO2 and CO Hydrogenation

    SciTech Connect (OSTI)

    Grabow, Lars C.; Mavrikakis, Manos

    2011-03-04T23:59:59.000Z

    We present a comprehensive mean-field microkinetic model for the methanol synthesis and water-gas-shift (WGS) reactions that includes novel reaction intermediates, such as formic acid (HCOOH) and hydroxymethoxy (CH?O?) and allows for the formation of formic acid (HCOOH), formaldehyde (CH?O), and methyl formate (HCOOCH?) as byproducts. All input model parameters were initially derived from periodic, self-consistent, GGA-PW91 density functional theory calculations on the Cu(111) surface and subsequently fitted to published experimentalmethanol synthesis rate data, which were collected under realistic conditions on a commercial Cu/ZnO/Al?O? catalyst. We find that the WGS reaction follows the carboxyl (COOH)-mediated path and that both CO and CO? hydrogenation pathways are active for methanol synthesis. Under typical industrial methanol synthesis conditions, CO? hydrogenation is responsible for ?2/3 of the methanol produced. The intermediates of the CO? pathway for methanol synthesis include HCOO*, HCOOH*, CH?O?*, CH?O*, and CH?O*. The formation of formate (HCOO*) from CO?* and H* on Cu(111) does not involve an intermediate carbonate (CO?*) species, and hydrogenation of HCOO* leads to HCOOH* instead of dioxymethylene (H?CO?*). The effect of CO is not only promotional; CO* is also hydrogenated in significant amounts to HCO*, CH?O *, CH?O*, and CH?OH*. We considered two possibilities for CO promotion: (a) removal of OH* via COOH* to form CO? and hydrogen (WGS), and (b) CO-assisted hydrogenation of various surface intermediates, with HCO* being the H-donor. Only the former mechanism contributes to methanol formation, but its effect is small compared with that of direct CO hydrogenation to methanol. Overall, methanol synthesis rates are limited by methoxy (CH?O*) formation at low CO?/(CO+CO?) ratios and by CH?O* hydrogenation in CO?-rich feeds. CH?O* hydrogenation is the common slow step for both the CO and the CO? methanol synthesis routes; the relative contribution of each route is determined by their respective slow steps HCO*+H*?CH?O*+* and HCOOH*+H*?CH?O?*+* as well as by feed composition and reaction conditions. An analysis of the fitted parameters for a commercial Cu/ZnO/Al?O? catalyst suggests that a more open Cu surface, for example, Cu(110), Cu(100), and Cu(211) partially covered by oxygen, may provide a better model for the active site of methanol synthesis, but our studies cannot exclude a synergistic effect with the ZnO support.

  11. Importance of Diffusion in Methanol Photochemistry on TiO2(110)

    SciTech Connect (OSTI)

    Shen, Mingmin; Acharya, Danda P.; Dohnalek, Zdenek; Henderson, Michael A.

    2012-12-06T23:59:59.000Z

    The photoactivity of methanol on the rutile TiO2(110) surface is shown to depend on the ability of methanol to diffuse on the surface and find sites active for its thermal dissociation to methoxy. Temperature programmed desorption (TPD) results show that the extent of methanol photodecomposition to formaldehyde is negligible on the clean TiO2(110) surface at 100 K due to a scarcity of sites that can convert (photoinactive) methanol to (photoactive) methoxy. The extent of photoactivity at 100 K significantly increases when methanol is coadsorbed with oxygen, however only those molecules able to adsorb near (next to) a coadsorbed oxygen species are active. Preannealing coadsorbed methanol and oxygen to above 200 K prior to UV irradiation results in a significant increase in photoactivity. Scanning tunneling microscopy (STM) images clearly show that the advent of increased photoactivity in TPD correlates with the onset of methanol diffusion along the surface’s Ti4+ rows at ~200 K. These results demonstrate that optimizing thermal processes (such as diffusion or proton transfer reactions) can be critical to maximizing photocatalytic reactivity on TiO2 surfaces. This work was supported by the US Department of Energy, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences & Biosciences. Pacific Northwest National Laboratory (PNNL) is a multiprogram national laboratory operated for DOE by Battelle under contract DEAC05-76RL01830. The research was performed using EMSL, a national scientific user facility sponsored by the Department of Energy's Office of Biological and Environmental Research and located at Pacific Northwest National Laboratory.

  12. Role of Water in Methanol Photochemistry on Rutile TiO2(110)

    SciTech Connect (OSTI)

    Shen, Mingmin; Henderson, Michael A.

    2012-08-07T23:59:59.000Z

    Photochemistry of the molecularly and dissociatively adsorbed forms of methanol on the vacuum-annealed rutile TiO2(110) surface was explored using temperature programmed desorption (TPD), both with and without coadsorbed water. Methoxy, and not methanol, was confirmed as the photochemically active form of adsorbed methanol on this surface. UV irradiation of methoxy-covered TiO2(110) lead to depletion of the methoxy coverage and formation of formaldehyde and a surface OH group. Coadsorbed water did not promote either molecular methanol photochemistry or thermal decomposition of methanol to methoxy. However, terminal OH groups (OHt), prepared by coadsorption of water and oxygen atoms, thermally converted molecularly adsorbed methanol to methoxy at 120 K, thus enabling photoactivity. While chemisorbed water molecules had no influence on methoxy photochemistry, water molecules hydrogen-bonded in the second layer to bridging oxygen (Obr) sites inhibited the methoxy photodecomposition to formaldehyde. From this we conclude that Obr sites accept protons from the hole-mediated conversion of methoxy to formaldehyde. These results provide new fundamental understanding of the hole-scavenging role of methanol in photochemical processes on TiO2-based materials and how water influences this photochemistry. This work was supported by the US Department of Energy, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences & Biosciences. Pacific Northwest National Laboratory (PNNL) is a multiprogram national laboratory operated for DOE by Battelle under contract DEAC05-76RL01830. The research was performed using EMSL, a national scientific user facility sponsored by the Department of Energy's Office of Biological and Environmental Research and located at Pacific Northwest National Laboratory.

  13. Research Module: Scheme 2A. N-Benzylation Using Benzyl Bromide 63 Scheme 2 Part A: Redissolve in Methanol

    E-Print Network [OSTI]

    Jasperse, Craig P.

    in Methanol 1. Turn hot plate to 5. 2. To the flask with your product 3 from Scheme 1, attach a condener with gentle water flow. 3. Add 15 mL of methanol. · For 4-methoxy compoud 3c, you may need to add 20 mL of methanol, since the 4-methoxy substrates is probably less soluble. 4. Heat the mixture on the hot plate

  14. Case Files of the California Poison Control System, San Francisco Division: Blue Thunder Ingestion: Methanol, Nitromethane, and Elevated Creatinine

    E-Print Network [OSTI]

    Ngo, Adeline Su-Yin; Rowley, Freda; Olson, Kent R.

    2010-01-01T23:59:59.000Z

    San Francisco Division: Blue Thunder Ingestion: Methanol,by consuming vodka and “ Blue Thunder”, a fuel for radio-controlled car fuels such as “Blue Thunder”, the primary

  15. Microbial Community Changes in Response to Ethanol or Methanol Amendments for U(VI) Reduction

    SciTech Connect (OSTI)

    Vishnivetskaya, Tatiana A [ORNL; Brandt, Craig C [ORNL; Madden, Andrew [University of Oklahoma, Norman; Drake, Meghan M [ORNL; Kostka, Joel [Florida State University; Akob, Denise M. [Florida State University; Kusel, Kirsten [Friedrich Schiller University Jena, Jena Germany; Palumbo, Anthony Vito [ORNL

    2010-01-01T23:59:59.000Z

    Microbial community responses to ethanol, methanol and methanol + humics amendments in relationship to uranium bioremediation were studied in laboratory microcosm experiments using sediments and ground water from a uranium-contaminated site in Oak Ridge, Tennessee. Ethanol addition always resulted in uranium reduction at rate of 0.8-1.0 mol l-1 d-1 while methanol addition did so occasionally at rate 0.95 mol l-1 d-1. The type of carbon source added, the duration of incubation, and the sampling site influenced the bacterial community structure upon incubation. Analysis of 16S rRNA gene clone libraries indicated (1) bacterial communities found in ethanol- and methanol-amended samples with U(VI) reduction were similar due to presence of -Proteobacteria, and -Proteobacteria (members of the families Burkholderiaceae, Comamonadaceae, Oxalobacteraceae, and Rhodocyclaceae); (2) methanol-amended samples without U(VI) reduction exhibited the lowest diversity and the bacterial community contained 69.2-92.8% of the family Methylophilaceae; and (3) the addition of humics resulted in an increase of phylogenetic diversity of -Proteobacteria (Rodoferax, Polaromonas, Janthinobacterium, Methylophilales, unclassified) and Firmicutes (Desulfosporosinus, Clostridium).

  16. Comparative Density Functional Study of Methanol Decomposition on Cu4 and Co4 Clusters

    SciTech Connect (OSTI)

    Mehmood, Faisal; Greeley, Jeffrey P.; Zapol, Peter; Curtiss, Larry A.

    2010-11-18T23:59:59.000Z

    A density functional theory study of the decomposition of methanol on Cu4 and Co4 clusters is presented. The reaction intermediates and activation barriers have been determined for reaction steps to form H2 and CO. For both clusters, methanol decomposition initiated by C-H and O-H bond breaking was investigated. In the case of a Cu4 cluster, methanol dehydrogenation through hydroxymethyl (CH2OH), hydroxymethylene (CHOH), formyl (CHO), and carbon monoxide (CO) is found to be slightly more favorable. For a Co4 cluster, the dehydrogenation pathway through methoxy (CH3O) and formaldehyde (CH2O) is slightly more favorable. Each of these pathways results in formation of CO and H2. The Co cluster pathway is very favorable thermodynamically and kinetically for dehydrogenation. However, since CO binds strongly, it is likely to poison methanol decomposition to H2 and CO at low temperatures. In contrast, for the Cu cluster, CO poisoning is not likely to be a problem since it does not bind strongly, but the dehydrogenation steps are not energetically favorable. Pathways involving C-O bond cleavage are even less energetically favorable. The results are compared to our previous study of methanol decomposition on Pd4 and Pd8 clusters. Finally, all reaction energy changes and transition state energies, including those for the Pd clusters, are related in a linear, Broensted-Evans-Polanyi plot.

  17. 6.7GHz Methanol Maser Associated Outflows: An evolutionary sequence

    E-Print Network [OSTI]

    de Villiers, H M; Thompson, M A; Urquhart, J S; Breen, S L; Burton, M G; Ellingsen, S P; Fuller, G A; Pestalozzi, M; Voronkov, M A; Ward-Thompson, D

    2015-01-01T23:59:59.000Z

    We present a continuing study of a sample 44 molecular outflows, observed in 13CO lines, closely associated with 6.7GHz methanol masers, hence called Methanol Maser Associated Outflows (MMAOs). We compare MMAO properties with those of outflows from other surveys in the literature. In general, MMAOs follow similar trends, but show a deficit in number at low masses and momenta, with a corresponding higher fraction at the high end of the distributions. A similar trend is seen for the dynamical timescales of MMAOs. We argue that the lack of relatively low mass and young flows in MMAOs is due to the inherent selection-bias in the sample, i.e. its direct association with 6.7GHz methanol masers. This implies that methanol masers must switch on after the onset of outflows (hence accretion), and not before a sufficient abundance of methanol is liberated from icy dust mantles. Consequently the average dynamical age of MMAOs is older than for the general population of molecular outflows. We propose an adjusted evolution...

  18. Direct methanol fuel cells for transportation applications. Quarterly technical report, June 1996--September 1996

    SciTech Connect (OSTI)

    Fuller, T.F.; Kunz, H.R.; Moore, R.

    1996-11-01T23:59:59.000Z

    The purpose of this research and development effort is to advance the performance and viability of direct methanol fuel cell technology for light-duty transportation applications. For fuel cells to be an attractive alternative to conventional automotive power plants, the fuel cell stack combined with the fuel processor and ancillary systems must be competitive in terms of both performance and costs. A major advantage for the direct methanol fuel cell is that a fuel processor is not required. A direct methanol fuel cell has the potential of satisfying the demanding requirements for transportation applications, such as rapid start-up and rapid refueling. The preliminary goals of this effort are: (1) 310 W/l, (2) 445 W/kg, and (3) potential manufacturing costs of $48/kW. In the twelve month period for phase 1, the following critical areas will be investigated: (1) an improved proton-exchange membrane that is more impermeable to methanol, (2) improved cathode catalysts, and (3) advanced anode catalysts. In addition, these components will be combined to form membrane-electrode assemblies (MEA`s) and evaluated in subscale tests. Finally a conceptual design and program plan will be developed for the construction of a 5 kW direct methanol stack in phase II of the program.

  19. Application of the Kellogg reforming exchanger system to large scale methanol plants

    SciTech Connect (OSTI)

    Joshi, G.; Schneider, R.V. III [M.W. Kellogg Co., Houston, TX (United States)

    1995-12-31T23:59:59.000Z

    In a majority of existing methanol production facilities, synthesis gas is furnished typically by a tubular fired steam reformer which uses natural gas as a feedstock. When one considers all synthesis gas produced from both ammonia and methanol plants, well over 80% is produced in a conventional reforming furnace. Steam reforming in a conventional sense, however, requires a considerable investment in both capital equipment and on-going maintenance and further, the use of such a unit operation will require heat recovery in the form of steam which forces the hand of the designer with respect to machinery driver selection. The authors have investigated alternatives to the coinventional approach with a view towards developing a process for methanol production that would be hopefully less expensive to construct, easier to operate and more reliable over the course of long term operation. In this paper, the authors present an alternative methanol plant process based on Kellogg`s proprietary reforming exchanger system (KRES). The flowsheet presented herein is for a 1500 MTPD facility that will produce US Federal Grade AA + methanol and will be compared on an economic basis to a conventional plant with respect to investment requirements and expected energy efficiency.

  20. PHYSICAL CONDITIONS AROUND 6.7 GHz METHANOL MASERS. I. AMMONIA

    SciTech Connect (OSTI)

    Pandian, J. D. [Institute for Astronomy, University of Hawaii, 2680 Woodlawn Dr., Honolulu, HI 96822 (United States); Wyrowski, F.; Menten, K. M., E-mail: jagadheep@iist.ac.in [Max-Planck-Institut fuer Radioastronomie, Auf dem Huegel 69, 53121 Bonn (Germany)

    2012-07-01T23:59:59.000Z

    Methanol masers at 6.7 GHz are known to be tracers of high-mass star formation in our Galaxy. In this paper, we study the large-scale physical conditions in the star-forming clumps/cores associated with 6.7 GHz methanol masers using observations of the (1, 1), (2, 2), and (3, 3) inversion transitions of ammonia with the Effelsberg telescope. The gas kinetic temperature is found to be higher than in infrared dark clouds, highlighting the relatively evolved nature of the maser sources. Other than a weak correlation between maser luminosity and the ammonia line width, we do not find any differences between low- and high-luminosity methanol masers.

  1. A high-sensitivity 6.7 GHz methanol maser survey toward H2O sources

    E-Print Network [OSTI]

    Y. Xu; J. J. Li; K. Hachisuka; J. D. Pandian; K. M. Menten; C. Henkel

    2008-03-16T23:59:59.000Z

    We present the results of a high sensitivity survey for 6.7 GHz methanol masers towards 22 GHz water maser using the 100 m Efflesberg telescope. A total of 89 sources were observed and 10 new methanol masers were detected. The new detections are relatively faint with peak flux densities between 0.5 and 4.0 Jy. A nil detection rate from low-mass star forming regions enhances the conclusion that the masers are only associated with massive star formation. Even the faintest methanol maser in our survey, with a luminosity of 1.1 $10^{-9} L_\\odot$ is associated with massive stars as inferred from its infrared luminosity.

  2. Process for the conversion of carbonaceous feedstocks to particulate carbon and methanol

    DOE Patents [OSTI]

    Steinberg, Meyer (Melville, NY); Grohse, Edward W. (Port Jefferson, NY)

    1995-01-01T23:59:59.000Z

    A process for the production of a pollutant-free particulate carbon (i.e., a substantially ash-, sulfur- and nitrogen-free carbon) from carbonaceous feedstocks. The basic process involves de-oxygenating one of the gas streams formed in a cyclic hydropyrolysis-methane pyrolysis process in order to improve conversion of the initial carbonaceous feedstock. De-oxygenation is effected by catalytically converting carbon monoxide, carbon dioxide, and hydrogen contained in one of the pyrolysis gas streams, preferably the latter, to a methanol co-product. There are thus produced two products whose use is known per se, viz., a substantially pollutant-free particulate carbon black and methanol. These products may be admixed in the form of a liquid slurry of carbon black in methanol.

  3. Detection of Class I Methanol (CH3OH) Maser Candidates in Supernova Remnants

    E-Print Network [OSTI]

    Pihlström, Y M; Frail, D A; Claussen, M J; Mesler, R A; McEwen, B C

    2013-01-01T23:59:59.000Z

    We have used the Karl G. Jansky Very Large Array (VLA) to search for 36 GHz and 44 GHz methanol (CH3OH) lines in a sample of 21 Galactic supernova remnants (SNRs). Mainly the regions of the SNRs with 1720 MHz OH masers were observed. Despite the limited spatial extent covered in our search, methanol masers were detected in both G1.4-0.1 and W28. Additional masers were found in SgrAEast. More than 40 masers were found in G1.4-0.1 which we deduce are due to interactions between the SNR and at least two separate molecular clouds. The six masers in W28 are associated with the molecular cloud that is also associated with the OH maser excitation. We discuss the possibility that the methanol maser may be more numerous in SNRs than the OH maser, but harder to detect due to observational constraints.

  4. Process for the conversion of carbonaceous feedstocks to particulate carbon and methanol

    DOE Patents [OSTI]

    Steinberg, M.; Grohse, E.W.

    1995-06-27T23:59:59.000Z

    A process is described for the production of a pollutant-free particulate carbon (i.e., a substantially ash-, sulfur- and nitrogen-free carbon) from carbonaceous feedstocks. The basic process involves de-oxygenating one of the gas streams formed in a cyclic hydropyrolysis-methane pyrolysis process in order to improve conversion of the initial carbonaceous feedstock. De-oxygenation is effected by catalytically converting carbon monoxide, carbon dioxide, and hydrogen contained in one of the pyrolysis gas streams, preferably the latter, to a methanol co-product. There are thus produced two products whose use is known per se, viz., a substantially pollutant-free particulate carbon black and methanol. These products may be admixed in the form of a liquid slurry of carbon black in methanol. 3 figs.

  5. A Search for 6.7 GHz Methanol Masers in M33

    E-Print Network [OSTI]

    P. F. Goldsmith; J. D. Pandian; A. A. Deshpande

    2007-10-09T23:59:59.000Z

    We report the negative results from a search for 6.7 GHz methanol masers in the nearby spiral galaxy M33. We observed 14 GMCs in the central 4 kpc of the Galaxy, and found 3 sigma upper limits to the flux density of ~9 mJy in spectral channels having a velocity width of 0.069 km/s. By velocity shifting and combining the spectra from the positions observed, we obtain an effective 3sigma upper limit on the average emission of ~1mJy in a 0.25 km/s channel. These limits lie significantly below what we would expect based on our estimates of the methanol maser luminosity function in the Milky Way. The most likely explanation for the absence of detectable methanol masers appears to be the metallicity of M33, which is modestly less than that of the Milky Way.

  6. Vapor-liquid equilibria for the system benzene-thiophene-methanol

    SciTech Connect (OSTI)

    Triday, J.O.; Rodriguez, P.

    1985-01-01T23:59:59.000Z

    Isothermal vapor pressure data over the whole range of composition were obtained for the system benzene-thiophene-methanol. Data were taken at temperatures of 35, 40, and 45 /sup 0/C by using a static equilibrium cell. The systems benzene-methanol and thiophene-methanol are highly nonideal, while the system benzene-thiophene shows a very small deviation from ideality. The models suggested by Wilson and by Renon and Prausnitz (NRTL) and the modified equation of Abrams and Prausnitz (UNIQUAC) were used in the reduction of data. Physical parameters of these equations obtained from the binary data were used to predict the ternary system. The Wilson equation gives the best fit for the binary as well as the ternary data. Also, this equation gives the best prediction for the ternary system.

  7. HYDROGEN PRODUCTION FOR FUEL CELLS VIA REFORMING COAL-DERIVED METHANOL

    SciTech Connect (OSTI)

    Paul A. Erickson

    2004-04-01T23:59:59.000Z

    Hydrogen can be produced from many feed stocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the second report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of January 1--March 31, 2004. This quarter saw progress in five areas. These areas are: (1) Internal and external evaluations of coal based methanol and the fuel cell grade baseline fuel; (2) Experimental investigations of heat and mass transfer enhancement methods by flow field manipulation; (3) Design and set up of the autothermal reactor; (4) Steam reformation of Coal Based Methanol; and (5) Initial catalyst degradation studies. All of the projects are proceeding on or slightly ahead of schedule.

  8. Detection of class I methanol (CH{sub 3}OH) maser candidates in supernova remnants

    SciTech Connect (OSTI)

    Pihlström, Y. M.; Mesler, R. A.; McEwen, B. C. [Department of Physics and Astronomy, University of New Mexico, MSC07 4220, Albuquerque, NM 87131 (United States); Sjouwerman, L. O.; Frail, D. A.; Claussen, M. J., E-mail: ylva@unm.edu [National Radio Astronomy Observatory, P.O. Box 0, Lopezville Road 1001, Socorro, NM 87801 (United States)

    2014-04-01T23:59:59.000Z

    We have used the Karl G. Jansky Very Large Array to search for 36 GHz and 44 GHz methanol (CH{sub 3}OH) lines in a sample of 21 Galactic supernova remnants (SNRs). Mainly the regions of the SNRs with 1720 MHz OH masers were observed. Despite the limited spatial extent covered in our search, methanol masers were detected in both G1.4–0.1 and W28. Additional masers were found in Sgr A East. More than 40 masers were found in G1.4–0.1, which we deduce are due to interactions between the SNR and at least two separate molecular clouds. The six masers in W28 are associated with the molecular cloud that is also associated with the OH maser excitation. We discuss the possibility that the methanol maser may be more numerous in SNRs than the OH maser, but harder to detect due to observational constraints.

  9. WIDESPREAD METHANOL EMISSION FROM THE GALACTIC CENTER: THE ROLE OF COSMIC RAYS

    SciTech Connect (OSTI)

    Yusef-Zadeh, F.; Royster, M. [Department of Physics and Astronomy and Center for Interdisciplinary Exploration and Research in Astrophysics (CIERA), Northwestern University, Evanston, IL 60208 (United States); Cotton, W. [National Radio Astronomy Observatory, Charlottesville, VA 22903 (United States); Viti, S. [Department of Physics and Astronomy, University College London, Gower St. London, WCIE 6BT (United Kingdom); Wardle, M. [Department of Physics and Astronomy, Macquarie University, Sydney NSW 2109 (Australia)

    2013-02-20T23:59:59.000Z

    We report the discovery of a widespread population of collisionally excited methanol J = 4{sub -1} to 3{sub 0} E sources at 36.2 GHz from the inner 66' Multiplication-Sign 18' (160 Multiplication-Sign 43 pc) of the Galactic center. This spectral feature was imaged with a spectral resolution of 16.6 km s{sup -1} taken from 41 channels of a Very Large Array continuum survey of the Galactic center region. The revelation of 356 methanol sources, most of which are maser candidates, suggests a large abundance of methanol in the gas phase in the Galactic center region. There is also spatial and kinematic correlation between SiO (2-1) and CH{sub 3}OH emission from four Galactic center clouds: the +50 and +20 km s{sup -1} clouds and G0.13-0.13 and G0.25 + 0.01. The enhanced abundance of methanol is accounted for in terms of induced photodesorption by cosmic rays as they travel through a molecular core, collide, dissociate, ionize, and excite Lyman Werner transitions of H{sub 2}. A time-dependent chemical model in which cosmic rays drive the chemistry of the gas predicts CH{sub 3}OH abundance of 10{sup -8} to 10{sup -7} on a chemical timescale of 5 Multiplication-Sign 10{sup 4} to 5 Multiplication-Sign 10{sup 5} years. The average methanol abundance produced by the release of methanol from grain surfaces is consistent with the available data.

  10. Preparation of silver nanoparticles/graphene nanosheets as a catalyst for electrochemical oxidation of methanol

    SciTech Connect (OSTI)

    Han, Kun; Miao, Peng; Tang, Yuguo, E-mail: tangyg@sibet.ac.cn [Suzhou Institute of Biomedical Engineering and Technology, Chinese Academy of Sciences, Suzhou 215163 (China); University of Chinese Academy of Sciences, Beijing 100049 (China); Tong, Hui; Zhu, Xiaoli [Laboratory of Biosensing Technology, School of Life Sciences, Shanghai University, Shanghai 200444 (China); Liu, Tao; Cheng, Wenbo [Suzhou Institute of Biomedical Engineering and Technology, Chinese Academy of Sciences, Suzhou 215163 (China)

    2014-02-03T23:59:59.000Z

    In this report, silver nanoparticles (AgNPs) decorated graphene nanosheets have been prepared based on the reduction of Ag ions by hydroquinone, and their catalytic performance towards the electrochemical oxidation of methanol is investigated. The synthesis of the nano-composite is confirmed by transmission electron microscope measurements and UV-vis absorption spectra. Excellent electrocatalytic performance of the material is demonstrated by cyclic voltammograms. This material also contributes to the low peak potential of methanol oxidation compared with most of the other materials.

  11. (Non) formation of methanol by direct hydrogenation of formate on copper catalysts

    SciTech Connect (OSTI)

    Yang, Yong; Mims, Charles A.; Disselkamp, Robert S.; Kwak, Ja Hun; Peden, Charles HF; Campbell, C. T.

    2010-10-14T23:59:59.000Z

    We have attempted to hydrogenate adsorbed formate species on copper catalysts to probe the importance of this postulated mechanistic step in methanol synthesis. Surface formate coverages up to 0.25 were produced at temperatures between 413K and 453K on supported (Cu/SiO2) copper and unsupported copper catalysts. The adlayers were produced by various methods including (1) steady state catalytic conditions in CO2-H2 (3:1, 6 bar) atmospheres, and (2) by exposure of the catalysts to formic acid. As reported in earlier work, the catalytic surface at steady state contains bidentate formate species with coverages up to saturation levels of ~ 0.25 at the low temperatures of this study. The reactivity of these formate adlayers was investigated at relevant reaction temperatures in atmospheres containing up to 6 bar H2 partial pressure by simultaneous mass spectrometry (MS) and infrared (IR) spectroscopy measurements. The yield of methanol during the attempted hydrogenation (“titration”) of these adlayers was insignificant (<0.2 mol % of the formate adlayer) even in dry hydrogen partial pressures up to 6 bar. Hydrogen titration of formate species produced from formic acid also failed to produce significant quantities of methanol, and attempted titration in gases consisting of CO-hydrogen mixtures or dry CO2 were also unproductive. The formate decomposition kinetics, measured by IR, were also unaffected by these changes in the gas composition. Similar experiments on unsupported copper also failed to show any methanol. From these results, we conclude that methanol synthesis on copper cannot result from the direct hydrogenation of (bidentate) formate species in simple steps involving adsorbed H species alone. Furthermore, experiments performed on both supported (Cu/SiO2) and unsupported copper catalysts gave similar results implying that the methanol synthesis reaction mechanism only involves metal surface chemistry. Pre-exposure of the bidentate formate adlayer to oxidation by O2 or N2O produces a change to a monodentate configuration. Attempted titration of this monodentate formate/O coadsorbed layer in dry hydrogen produces significant quantities of methanol, although decomposition of formate to carbon dioxide and hydrogen remains the dominant reaction pathway. Simultaneous production of water is also observed during this titration as the copper surface is re-reduced. These results indicate that co-adsorbates related to surface oxygen or water-derived species may be critical to methanol production on copper, perhaps assisting in the hydrogenation of adsorbed formate to adsorbed methoxyl.

  12. Liquid phase low temperature method for production of methanol from synthesis gas and catalyst formulations therefor

    DOE Patents [OSTI]

    Mahajan, Devinder

    2005-07-26T23:59:59.000Z

    The invention provides a homogenous catalyst for the production of methanol from purified synthesis gas at low temperature and low pressure which includes a transition metal capable of forming transition metal complexes with coordinating ligands and an alkoxide, the catalyst dissolved in a methanol solvent system, provided the transition metal complex is not transition metal carbonyl. The coordinating ligands can be selected from the group consisting of N-donor ligands, P-donor ligands, O-donor ligands, C-donor ligands, halogens and mixtures thereof.

  13. Ring shaped 6.7 GHz methanol maser emission around a young high-mass star

    E-Print Network [OSTI]

    A. Bartkiewicz; M. Szymczak; H. J. van Langevelde

    2005-09-21T23:59:59.000Z

    We report on EVN imaging of the 6.7 GHz methanol maser emission from the candidate high-mass protostar G23.657-0.127. The masers originate in a nearly circular ring of 127 mas radius and 12 mas width. The ring structure points at a central exciting object which characteristics are typical for a young massive star; its bolometric luminosity is estimated to be methanol masers originate in a spherical bubble or in a rotating disc seen nearly face-on.

  14. HYDROGEN PRODUCTION FOR FUEL CELLS VIA REFORMING COAL-DERIVED METHANOL

    SciTech Connect (OSTI)

    Paul A. Erickson

    2005-04-01T23:59:59.000Z

    Hydrogen can be produced from many feedstocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the sixth report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of January 1-March 31, 2005. This quarter saw progress in four areas. These areas are: (1) Autothermal reforming of coal derived methanol, (2) Catalyst deactivation, (3) Steam reformer transient response, and (4) Catalyst degradation with bluff bodies. All of the projects are proceeding on or slightly ahead of schedule.

  15. 12.2-GHz methanol maser MMB follow-up catalogue - III. Longitude range 10 to 20 degrees

    E-Print Network [OSTI]

    Breen, Shari; Caswell, James; Green, James; Voronkov, Maxim; Avison, Adam; Fuller, Gary; Quinn, Lyshia; Titmarsh, Anita

    2013-01-01T23:59:59.000Z

    We present the third instalment of a series of catalogues presenting 12.2-GHz methanol maser observations made towards each of the 6.7-GHz methanol masers detected in the Methanol Multibeam (MMB) Survey. The current portion of the catalogue includes the Galactic longitude region 10 to 20 degrees, where we detect 47 12.2-GHz methanol masers towards 99 6.7-GHz targets. We compare the occurrence of 12.2-GHz methanol masers with water maser emission, for which all 6.7-GHz methanol masers in the 6 to 20 degrees longitude range have now been searched. We suggest that the water masers follow a more complicated evolutionary scenario than has been found for the methanol and OH masers, likely due to their different pumping mechanisms. Comparisons of the 6.7-GHz methanol to OH maser peak flux density ratio and the luminosity of the associated 12.2-GHz sources suggests that the 12.2-GHz maser luminosity begins to decline around the time that an OH maser becomes detectable.

  16. Mathematical Modeling of Liquid-Feed Direct Methanol Fuel Z. H. Wang* and C. Y. Wang*,z

    E-Print Network [OSTI]

    Mathematical Modeling of Liquid-Feed Direct Methanol Fuel Cells Z. H. Wang* and C. Y. Wang for liquid-feed direct methanol fuel cells DMFC . In addition to the anode and cathode electrochemical electronically March 4, 2003. Fuel cells promise to replace the internal combustion engine in transportation due

  17. Properties of a soft-core model of methanol: An integral equation theory and computer simulation study

    SciTech Connect (OSTI)

    Huš, Matej; Urbic, Tomaz, E-mail: tomaz.urbic@fkkt.uni-lj.si [Department of Chemistry and Chemical Technology, University of Ljubljana, Chair of Physical Chemistry, Ve?na pot 113, SI-1000 Ljubljana (Slovenia); Munaò, Gianmarco [Dipartimento di Fisica e di Scienze della Terra, Università degli Studi di Messina, Viale F. Stagno d'Alcontres 31, 98166 Messina (Italy)

    2014-10-28T23:59:59.000Z

    Thermodynamic and structural properties of a coarse-grained model of methanol are examined by Monte Carlo simulations and reference interaction site model (RISM) integral equation theory. Methanol particles are described as dimers formed from an apolar Lennard-Jones sphere, mimicking the methyl group, and a sphere with a core-softened potential as the hydroxyl group. Different closure approximations of the RISM theory are compared and discussed. The liquid structure of methanol is investigated by calculating site-site radial distribution functions and static structure factors for a wide range of temperatures and densities. Results obtained show a good agreement between RISM and Monte Carlo simulations. The phase behavior of methanol is investigated by employing different thermodynamic routes for the calculation of the RISM free energy, drawing gas-liquid coexistence curves that match the simulation data. Preliminary indications for a putative second critical point between two different liquid phases of methanol are also discussed.

  18. Flex Debit Card Your employer

    E-Print Network [OSTI]

    Fraden, Seth

    such as medical devices, eyeglasses, contact lenses, bandages, co-pays and deductibles. Q A Q A Q A Q A Q A What

  19. Flex Schedule | GE Global Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville Power AdministrationField8,Dist.New MexicoFinancingProofWorking Outside the Box Click to email

  20. Accurate Computer Simulation of Phase Equilibrium for Complex Fluid Mixtures. Application to Binaries Involving Isobutene, Methanol, Methyl tert-Butyl Ether, and

    E-Print Network [OSTI]

    Lisal, Martin

    to Binaries Involving Isobutene, Methanol, Methyl tert-Butyl Ether, and n-Butane Martin Li´sal,*,, William R + methyl tert-butyl ether (MTBE) and the binaries formed by methanol with isobutene, MTBE, and n

  1. Gasoline from Wood via Integrated Gasification, Synthesis, and Methanol-to-Gasoline Technologies

    SciTech Connect (OSTI)

    Phillips, S. D.; Tarud, J. K.; Biddy, M. J.; Dutta, A.

    2011-01-01T23:59:59.000Z

    This report documents the National Renewable Energy Laboratory's (NREL's) assessment of the feasibility of making gasoline via the methanol-to-gasoline route using syngas from a 2,000 dry metric tonne/day (2,205 U.S. ton/day) biomass-fed facility. A new technoeconomic model was developed in Aspen Plus for this study, based on the model developed for NREL's thermochemical ethanol design report (Phillips et al. 2007). The necessary process changes were incorporated into a biomass-to-gasoline model using a methanol synthesis operation followed by conversion, upgrading, and finishing to gasoline. Using a methodology similar to that used in previous NREL design reports and a feedstock cost of $50.70/dry ton ($55.89/dry metric tonne), the estimated plant gate price is $16.60/MMBtu ($15.73/GJ) (U.S. $2007) for gasoline and liquefied petroleum gas (LPG) produced from biomass via gasification of wood, methanol synthesis, and the methanol-to-gasoline process. The corresponding unit prices for gasoline and LPG are $1.95/gallon ($0.52/liter) and $1.53/gallon ($0.40/liter) with yields of 55.1 and 9.3 gallons per U.S. ton of dry biomass (229.9 and 38.8 liters per metric tonne of dry biomass), respectively.

  2. To improve the transient performance of methanol evaporator and SMR reformer with TECs.

    E-Print Network [OSTI]

    Berning, Torsten

    . · To reduce heat loss inside methanol evaporator during system startup. · Using TEG heat recovery waste heat is still exhausted unused. And by now, they still cannot get rid of large Li-ion batteries during working condition fluctuating. In this work, possibly useful waste heat from a HTPEMFC system

  3. DISCOVERY OF THE FIRST METHANOL (CH [subscript 3] OH) MASER IN THE ANDROMEDA GALAXY (M31)

    E-Print Network [OSTI]

    Sjouwerman, Loránt O.

    We present the first detection of a 6.7 GHz Class II methanol (CH[subscript 3]OH) maser in the Andromeda galaxy (M31). The CH[subscript 3]OH maser was found in a VLA survey during the fall of 2009. We have confirmed the ...

  4. The nature of the methanol maser ring G23.657-00.127

    E-Print Network [OSTI]

    A. Bartkiewicz; A. Brunthaler; M. Szymczak; H. J. van Langevelde; M. J. Reid

    2008-09-11T23:59:59.000Z

    Methanol masers are associated with young high-mass stars and are an important tool for investigating the process of massive star formation. The recently discovered methanol maser ring in G23.657-00.127 provides an excellent ``laboratory'' for a detailed study of the nature and physical origin of methanol maser emission, as well as parallax and proper motion measurements. Multi-epoch observations of the 12.2 GHz methanol maser line from the ring were conducted using the Very Long Baseline Array. Interferometric observations with milliarcsecond resolution enabled us to track single maser spots in great detail over a period of 2 years. We have determined the trigonometric parallax of G23.657-00.127 to be 0.313+/-0.039 mas, giving a distance of 3.19{+0.46}{-0.35} kpc. The proper motion of the source indicates that it is moving with the same circular velocity as the LSR, but it shows a large peculiar motion of about 35 km/s toward the Galactic center.

  5. The Arecibo Methanol Maser Galactic Plane Survey - II: Statistical and Multi-wavelength Counterpart Analysis

    E-Print Network [OSTI]

    Jagadheep D. Pandian; Paul F. Goldsmith

    2007-08-23T23:59:59.000Z

    We present an analysis of the properties of the 6.7 GHz methanol maser sample detected in the Arecibo Methanol Maser Galactic Plane Survey. The distribution of the masers in the Galaxy, and statistics of their multi-wavelength counterparts is consistent with the hypothesis of 6.7 GHz maser emission being associated with massive young stellar objects. Using the detection statistics of our survey, we estimate the minimum number of methanol masers in the Galaxy to be 1275. The l-v diagram of the sample shows the tangent point of the Carina-Sagittarius spiral arm to be around 49.6 degrees, and suggests occurrence of massive star formation along the extension of the Crux-Scutum arm. A Gaussian component analysis of the maser spectra shows the mean line-width to be 0.38 km/s which is more than a factor of two larger than what has been reported in the literature. We also find no evidence that faint methanol masers have different properties than those of their bright counterparts.

  6. Photoelectrochemical hydrogen production from water/ methanol decomposition using Ag/TiO2 nanocomposite

    E-Print Network [OSTI]

    coal and gasoline [3]. Moreover, hydrogen can be used in fuel cells to generate electricity, or directly as a transportation fuel [4]. Hydrogen can be generated from hydrocarbons and water resourcesPhotoelectrochemical hydrogen production from water/ methanol decomposition using Ag/TiO2

  7. Hydrogen Production for Fuel Cells Via Reforming Coal-Derived Methanol

    SciTech Connect (OSTI)

    Paul A. Erickson

    2004-09-30T23:59:59.000Z

    Hydrogen can be produced from many feed stocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the fourth report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of July 1-Sept 30, 2004 along with a recap of progress from the start of the project on Oct 1, 2003 to Sept 30, 2004. All of the projects are proceeding on or slightly ahead of schedule. This year saw progress in several areas. These areas are: (1) External and internal evaluation of coal based methanol and a fuel cell grade baseline fuel, (2) Design set up and initial testing of three laboratory scale steam reformers, (3) Design, set up and initial testing of a laboratory scale autothermal reactor, (4) Hydrogen generation from coal-derived methanol using steam reformation, (5) Experiments to determine the axial and radial thermal profiles of the steam reformers, (6) Initial catalyst degradation studies with steam reformation and coal based methanol, and (7) Experimental investigations of heat and mass transfer enhancement methods by flow field manipulation. All of the projects are proceeding on or slightly ahead of schedule.

  8. Towards the optimal integrated production of biodiesel with internal recycling of methanol

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    of CO2 is performed by means of PSA and the syngas is fed to the methanol synthesis reactor. The most traditional is similar to the one that produces syngas from natural gas or coal, which can] . In order to generate the syngas out of the glycerol, a number of recent studies have evaluated

  9. Author's personal copy Methanol oxidation in nanostructured platinum/cerium-phosphate thin films

    E-Print Network [OSTI]

    Park, Byungwoo

    rights reserved. 1. Introduction Direct methanol fuel cells (DMFCs) have been considered to be one chosen metals in low-temperature fuel cells. However, it is hard to avoid CO adsorption on a bare Pt and optimize several types of catalysts [1]. Pure platinum as an anode catalyst is one of the most frequently

  10. Layer-by-layer Assembly of Nanobrick Wall Ultrathin Transparent Gas Barrier Films

    E-Print Network [OSTI]

    Priolo, Morgan Alexander

    2012-07-16T23:59:59.000Z

    to cracking when flexed, require special, non-ambient processing environments, and can involve complex fabrication when layered with polymers. The addition of clay into polymers can enhance barrier properties relative to the neat polymer; however...

  11. 10 to 70% methanol in 50 mM KH2PO4 over 25 min, 10 ml/min, monitor at 380 nm). Next, the HPLC-

    E-Print Network [OSTI]

    Gao, Jinming

    10 to 70% methanol in 50 mM KH2PO4 over 25 min, 10 ml/min, monitor at 380 nm). Next, the HPLC- purified mixture was desalted on the same column (methanol was removed on a rotary evaporator, and the sample loaded in H2O and eluted with 90% methanol) and lyophilized, yielding the purified Nvoc

  12. Hydrogen production from methanol decomposition over Pt/Al2O3 and ceria promoted Pt/Al2O3 catalysts

    E-Print Network [OSTI]

    Gulari, Erdogan

    Hydrogen production from methanol decomposition over Pt/Al2O3 and ceria promoted Pt/Al2O3 catalysts-based catalysts in the production of hydrogen from methanol through catalytic decomposition rights reserved. Keywords: Methanol decomposition; Pt/alumina; Ceria; Hydrogen; PEM fuel cell 1

  13. EXPERIMENTAL STUDY OF A DIRECT METHANOL FUEL CELL M. M. Mench, S. Boslet, S. Thynell, J. Scott, and C.Y. Wang

    E-Print Network [OSTI]

    Wang, Chao-Yang

    EXPERIMENTAL STUDY OF A DIRECT METHANOL FUEL CELL M. M. Mench, S. Boslet, S. Thynell, J. Scott The Pennsylvania State University University Park, PA 16802 In this investigation, two 50cm2 direct methanol fuel in this area. INTRODUCTION The liquid-fed direct methanol fuel cell (DMFC) has received enormous interest

  14. Dissociative Chemisorption of Methanol on Ge(100) Sung-Soo Bae, Do Hwan Kim,, Ansoon Kim,, Soon Jung Jung, Suklyun Hong,*, and

    E-Print Network [OSTI]

    Kim, Sehun

    Dissociative Chemisorption of Methanol on Ge(100) Sung-Soo Bae, Do Hwan Kim,, Ansoon Kim,,§ Soon of methanol (CH3OH) on Ge(100) surface has been studied using ultrahigh vacuum scanning tunneling microscopy-resolution experimental STM shows that methanol undergoes O-H bond dissociative adsorption on a single Ge-Ge dimer

  15. A High-Yield, Liquid-Phase Approach for the Partial Oxidation of Methane to Methanol using SO3 as the Oxidant

    E-Print Network [OSTI]

    Bell, Alexis T.

    A High-Yield, Liquid-Phase Approach for the Partial Oxidation of Methane to Methanol using SO3 approach for producing methanol from methane in a three-step, liquid phase process is reported is hydrolyzed in the presence of an organic solvent, to produce an organic phase con- taining methanol

  16. An experimental and theoretical investigation of the structure and reactivity of bilayered VOx/TiOx/SiO2 catalysts for methanol oxidation

    E-Print Network [OSTI]

    Bell, Alexis

    /TiOx/SiO2 catalysts for methanol oxidation William C. Vining, Anthony Goodrow, Jennifer Strunk, Alexis T Accepted 22 December 2009 Available online 2 February 2010 Keywords: Vanadia Silica Titania Methanol vanadia surface density (0.7 V/nm2 ), the turnover frequency for methanol oxidation to formaldehyde

  17. Site Competition During Coadsorption of Acetone with Methanol and Water on TiO2(110)

    SciTech Connect (OSTI)

    Shen, Mingmin; Henderson, Michael A.

    2011-08-02T23:59:59.000Z

    The competitive interaction between acetone and two solvent molecules (methanol and water) for surface sites on rutile TiO2(110) was studied using temperature programmed desorption (TPD). On a vacuum reduced TiO2(110) surface, which possessed ~5% oxygen vacancy sites, excess methanol displaced preadsorbed acetone molecules to weakly bound and physisorbed desorption states below 200 K, whereas acetone was stabilized to 250 K against displacement by methanol on an oxidized surface through formation of an acetone-diolate species. These behaviors of acetone differ from the competitive interactions between acetone and water in that acetone is less susceptible to displacement by water. Examination of acetone+methanol and acetone+water multilayer combinations shows that acetone is more compatible in water-ice films than in methanol-ice films, presumably because water has greater potential as a hydrogen-bond donor than does methanol. Acetone molecules displaced from the TiO2(110) surface by water are more likely to be retained in the near-surface region, having a greater opportunity to revisit the surface, than when methanol is used as a coadsorbate. This work was supported by the US Department of Energy Basic Energy Sciences' Chemical Sciences, Geosciences & Biosciences Division. Pacific Northwest National Laboratory is operated by Battelle for the US Department of Energy.

  18. Associations of water and methanol masers at milli-arcsec angular resolution in two high-mass young stellar objects

    E-Print Network [OSTI]

    C. Goddi; L. Moscadelli; A. Sanna; R. Cesaroni; V. Minier

    2006-10-16T23:59:59.000Z

    Most previous high-angular (methanol masers. While high-angular resolution observations have clarified that water masers originate from shocks associated with protostellar jets, different environments have been proposed in several sources to explain the origin of methanol masers. Tha aim of the paper is to investigate the nature of the methanol maser birthplace in SFRs and the association between the water and methanol maser emission in the same young stellar object. We have conducted phase-reference Very Long Baseline Interferometry (VLBI) observations of water and methanol masers toward two high-mass SFRs, Sh 2-255 IR and AFGL 5142. In Sh 2-255 IR water masers are aligned along a direction close to the orientation of the molecular outflow observed on angular scales of 1-10 arcsec, tracing possibly the disk-wind emerging from the disk atmosphere. In AFGL 5142 water masers trace expansion at the base of a protostellar jet, whilst methanol masers are more probably tracing infalling than outflowing gas. The results for AFGL 5142 suggest that water and methanol masers trace different kinematic structures in the circumstellar gas.

  19. A Theoretical Study of Methanol Synthesis from CO(2) Hydrogenation on Metal-doped Cu(111) Surfaces

    SciTech Connect (OSTI)

    Liu P.; Yang, Y.; White, M.G.

    2012-01-12T23:59:59.000Z

    Density functional theory (DFT) calculations and Kinetic Monte Carlo (KMC) simulations were employed to investigate the methanol synthesis reaction from CO{sub 2} hydrogenation (CO{sub 2} + 3H{sub 2} {yields} CH{sub 3}OH + H{sub 2}O) on metal-doped Cu(111) surfaces. Both the formate pathway and the reverse water-gas shift (RWGS) reaction followed by a CO hydrogenation pathway (RWGS + CO-Hydro) were considered in the study. Our calculations showed that the overall methanol yield increased in the sequence: Au/Cu(111) < Cu(111) < Pd/Cu(111) < Rh/Cu(111) < Pt/Cu(111) < Ni/Cu(111). On Au/Cu(111) and Cu(111), the formate pathway dominates the methanol production. Doping Au does not help the methanol synthesis on Cu(111). Pd, Rh, Pt, and Ni are able to promote the methanol production on Cu(111), where the conversion via the RWGS + CO-Hydro pathway is much faster than that via the formate pathway. Further kinetic analysis revealed that the methanol yield on Cu(111) was controlled by three factors: the dioxomethylene hydrogenation barrier, the CO binding energy, and the CO hydrogenation barrier. Accordingly, two possible descriptors are identified which can be used to describe the catalytic activity of Cu-based catalysts toward methanol synthesis. One is the activation barrier of dioxomethylene hydrogenation, and the other is the CO binding energy. An ideal Cu-based catalyst for the methanol synthesis via CO{sub 2} hydrogenation should be able to hydrogenate dioxomethylene easily and bond CO moderately, being strong enough to favor the desired CO hydrogenation rather than CO desorption but weak enough to prevent CO poisoning. In this way, the methanol production via both the formate and the RWGS + CO-Hydro pathways can be facilitated.

  20. Commercial-Scale Demonstration of the Liquid Phase Methanol (LPMEOTH) Process

    SciTech Connect (OSTI)

    None

    1998-12-21T23:59:59.000Z

    The Liquid Phase Methanol (LPMEOW) Demonstration Project at Kingsport, Tennessee, is a $213.7 million cooperative agreement between the U.S. Department of Energy (DOE) and Air Products Liquid Phase Conversion Company, L.P. (the Partnership) to produce methanol from coal-derived synthesis gas (syngas). Air Products and Chemicals, Inc. (Air Products) and Eastman Chemical Company (Eastman) formed the Partnership to execute the Demonstration Project. The LPMEOI-P Process Demonstration Unit was built at a site located at the Eastman coal-to-chemicals complex in Kingsport. During this quarter, initial planning and procurement work continued on the seven project sites which have been accepted for participation in the off-site, product-use test program. Approximately 12,000 gallons of fuel-grade methanol (98+ wt% methanol, 4 wt% water) produced during operation on carbon monoxide (CO)-rich syngas at the LPMEOW Demonstration Unit was loaded into trailers and shipped off-site for Mure product-use testing. At one of the projects, three buses have been tested on chemical-grade methanol and on fhel-grade methanol from the LPMEOW Demonstration Project. During the reporting period, planning for a proof-of-concept test run of the Liquid Phase Dimethyl Ether (LPDME~ Process at the Alternative Fuels Development Unit (AFDU) in LaPorte, TX continued. The commercial catalyst manufacturer (Calsicat) has prepared the first batch of dehydration catalyst in large-scale equipment. Air Products will test a sample of this material in the laboratory autoclave. Catalyst activity, as defined by the ratio of the rate constant at any point in time to the rate constant for freshly reduced catalyst (as determined in the laborato~ autoclave), was monitored for the initial extended operation at the lower initial reactor operating temperature of 235oC. At this condition, the decrease in catalyst activity with time from the period 20 December 1997 through 27 January 1998 occurred at a rate of 1.0% per day, which represented a significant improvement over the 3.4Yi per day decline measured during the initial six weeks of operation in April and May of 1997. The deactivation rate also improved from the longer-term rate of 1.6% per day calculated throughout the summer and autumn of 1997.

  1. COMMERCIAL-SCALE DEMONSTRATION OF THE LIQUID PHASE METHANOL (LPMEOH) PROCESS

    SciTech Connect (OSTI)

    E.C. Heydorn; B.W. Diamond; R.D. Lilly

    2003-06-01T23:59:59.000Z

    This project, which was sponsored by the U.S. Department of Energy (DOE) under the Clean Coal Technology Program to demonstrate the production of methanol from coal-derived synthesis gas (syngas), has completed the 69-month operating phase of the program. The purpose of this Final Report for the ''Commercial-Scale Demonstration of the Liquid Phase Methanol (LPMEOH{trademark}) Process'' is to provide the public with details on the performance and economics of the technology. The LPMEOH{trademark} Demonstration Project was a $213.7 million cooperative agreement between the DOE and Air Products Liquid Phase Conversion Company, L.P. (the Partnership). The DOE's cost share was $92,708,370 with the remaining funds coming from the Partnership. The LPMEOH{trademark} demonstration unit is located at the Eastman Chemical Company (Eastman) chemicals-from-coal complex in Kingsport, Tennessee. The technology was the product of a cooperative development effort by Air Products and Chemicals, Inc. (Air Products) and DOE in a program that started in 1981. Developed to enhance electric power generation using integrated gasification combined cycle (IGCC) technology, the LPMEOH{trademark} Process is ideally suited for directly processing gases produced by modern coal gasifiers. Originally tested at the Alternative Fuels Development Unit (AFDU), a small, DOE-owned process development facility in LaPorte, Texas, the technology provides several improvements essential for the economic coproduction of methanol and electricity directly from gasified coal. This liquid phase process suspends fine catalyst particles in an inert liquid, forming a slurry. The slurry dissipates the heat of the chemical reaction away from the catalyst surface, protecting the catalyst, and allowing the methanol synthesis reaction to proceed at higher rates. The LPMEOH{trademark} Demonstration Project accomplished the objectives set out in the Cooperative Agreement with DOE for this Clean Coal Technology project. Overall plant availability (defined as the percentage of time that the LPMEOH{trademark} demonstration unit was able to operate, with the exclusion of scheduled outages) was 97.5%, and the longest operating run without interruption of any kind was 94 days. Over 103.9 million gallons of methanol was produced; Eastman accepted all of the available methanol for use in the production of methyl acetate, and ultimately cellulose acetate and acetic acid.

  2. MAJOR STRUCTURES OF THE INNER GALAXY DELINEATED BY 6.7 GHz METHANOL MASERS

    SciTech Connect (OSTI)

    Green, J. A.; Caswell, J. L.; McClure-Griffiths, N. M.; Breen, S. L.; Voronkov, M. A. [CSIRO Astronomy and Space Science, Australia Telescope National Facility, P.O. Box 76, Epping, NSW 1710 (Australia); Avison, A.; Fuller, G. A.; Gray, M. D. [Jodrell Bank Centre for Astrophysics, Alan Turing Building, University of Manchester, Manchester, M13 9PL (United Kingdom); Burton, M. G. [School of Physics, University of New South Wales, Sydney, NSW 2052 (Australia); Ellingsen, S. P. [School of Mathematics and Physics, University of Tasmania, Private Bag 37, Hobart, TAS 7001 (Australia); Pestalozzi, M. [INAF/IFSI, via del Fosso del Cabaliere 100, I-00133 Roma (Italy); Thompson, M. A. [Centre for Astrophysics Research, Science and Technology Research Institute, University of Hertfordshire, College Lane, Hatfield, AL10 9AB (United Kingdom)

    2011-05-20T23:59:59.000Z

    We explore the longitude-velocity distribution of 6.7 GHz methanol masers in the context of the inner structure of our Galaxy. We analyze the correlation in velocities within this distribution and identify density enhancements indicating large-scale regions of enhanced star formation. These are interpreted as the starting points of the spiral arms and the interaction of the Galactic bar with the 3 kpc arms. The methanol masers support the presence of a long thin bar with a 45{sup 0} orientation. Signatures of the full 3 kpc arm structure are seen, including a prominent tangent at approximately -22{sup 0} Galactic longitude. We compare this distribution with existing models of the gas dynamics of our Galaxy. The 3 kpc arm structure appears likely to correspond to the radius of corotation resonance of the bar, with the bar on its inner surface and the starting points of the spiral arms on its outer surface.

  3. HYDROGEN PRODUCTION FOR FUEL CELLS VIA REFORMING COAL-DERIVED METHANOL

    SciTech Connect (OSTI)

    Paul A. Erickson

    2006-04-01T23:59:59.000Z

    Hydrogen can be produced from many feedstocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the tenth report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of January 1-March 31, 2006. This quarter saw progress in six areas. These areas are: (1) The effect of catalyst dimension on steam reforming, (2) Transient characteristics of autothermal reforming, (3) Rich and lean autothermal reformation startup, (4) Autothermal reformation degradation with coal derived methanol, (5) Reformate purification system, and (6) Fuel cell system integration. All of the projects are proceeding on or slightly ahead of schedule.

  4. Hydrogen Production for Fuel Cells Via Reforming Coal-Derived Methanol

    SciTech Connect (OSTI)

    Paul A. Erickson

    2005-06-30T23:59:59.000Z

    Hydrogen can be produced from many feedstocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the seventh report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of April 1-June 31, 2005. This quarter saw progress in these areas. These areas are: (1) Steam reformer transient response, (2) Heat transfer enhancement, (3) Catalyst degradation, (4) Catalyst degradation with bluff bodies, and (5) Autothermal reforming of coal-derived methanol. All of the projects are proceeding on or slightly ahead of schedule.

  5. Hydrogen Production for Fuel Cells Via Reforming Coal-Derived Methanol

    SciTech Connect (OSTI)

    Paul A. Erickson

    2004-06-30T23:59:59.000Z

    Hydrogen can be produced from many feed stocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the third report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of April 1-June 30, 2004. This quarter saw progress in five areas. These areas are: (1) External evaluation of coal based methanol and the fuel cell grade baseline fuel, (2) Design, set up and initial testing of the autothermal reactor, (3) Experiments to determine the axial and radial thermal profiles of the steam reformers, (4) Catalyst degradation studies, and (5) Experimental investigations of heat and mass transfer enhancement methods by flow field manipulation. All of the projects are proceeding on or slightly ahead of schedule.

  6. HYDROGEN PRODUCTION FOR FUEL CELLS VIA REFORMING COAL-DERIVED METHANOL

    SciTech Connect (OSTI)

    Paul A. Erickson

    2006-01-01T23:59:59.000Z

    Hydrogen can be produced from many feedstocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the ninth report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of October 1, 2005-December 31, 2005. This quarter saw progress in four areas. These areas are: (1) reformate purification, (2) heat transfer enhancement, (3) autothermal reforming coal-derived methanol degradation test; and (4) model development for fuel cell system integration. The project is on schedule and is now shifting towards the design of an integrated PEM fuel cell system capable of using the coal-derived product. This system includes a membrane clean up unit and a commercially available PEM fuel cell.

  7. WABASH RIVER INTEGRATED METHANOL AND POWER PRODUCTION FROM CLEAN COAL TECHNOLOGIES (IMPPCCT)

    SciTech Connect (OSTI)

    Albert Tsang

    2003-03-14T23:59:59.000Z

    The Wabash River Integrated Methanol and Power Production from Clean Coal Technologies (IMPPCCT) project is evaluating integrated electrical power generation and methanol production through clean coal technologies. The project is conducted by a multi-industry team lead by Gasification Engineering Corporation (GEC), a company of Global Energy Inc., and supported by Air Products and Chemicals, Inc., Dow Chemical Company, Dow Corning Corporation, Methanex Corporation, and Siemens Westinghouse Power Corporation. Three project phases are planned for execution over several years, including: (1) Feasibility study and conceptual design for an integrated demonstration facility, and for fence-line commercial embodiment plants (CEP) operated at Dow Chemical or Dow Corning chemical plant locations (2) Research, development, and testing to define any technology gaps or critical design and integration issues (3) Engineering design and financing plan to install an integrated commercial demonstration facility at the existing Wabash River Energy Limited (WREL) plant in West Terre Haute, Indiana.

  8. Prediction of Transport Properties by Molecular Simulation: Methanol and Ethanol and their mixture

    E-Print Network [OSTI]

    Guevara-Carrion, Gabriela; Vrabec, Jadran; Hasse, Hans

    2009-01-01T23:59:59.000Z

    Transport properties of liquid methanol and ethanol are predicted by molecular dynamics simulation. The molecular models for the alcohols are rigid, non-polarizable and of united-atom type. They were developed in preceding work using experimental vapor-liquid equilibrium data only. Self- and Maxwell-Stefan diffusion coefficients as well as the shear viscosity of methanol, ethanol and their binary mixture are determined using equilibrium molecular dynamics and the Green-Kubo formalism. Non-equilibrium molecular dynamics is used for predicting the thermal conductivity of the two pure substances. The transport properties of the fluids are calculated over a wide temperature range at ambient pressure and compared with experimental and simulation data from the literature. Overall, a very good agreement with the experiment is found. For instance, the self-diffusion coefficient and the shear viscosity are predicted with average deviations of less 8% for the pure alcohols and 12% for the mixture. The predicted thermal...

  9. The 6.7-GHz and 25-GHz methanol masers in OMC-1

    E-Print Network [OSTI]

    M. A. Voronkov; A. M. Sobolev; S. P. Ellingsen; A. B. Ostrovskii

    2005-07-02T23:59:59.000Z

    The Australia Telescope Compact Array (ATCA) has been used to search for methanol maser emission at 6.7 GHz towards OMC-1. Two features peaking at 7.2 km/s and -1.1 km/s have been detected. The former has at least two components close in both velocity and position. It is located south-east of the Orion Kleinmann-Low (Orion-KL) nebula in the region of outflow traced by the 25-GHz methanol masers and the 95-GHz methanol emission. It is shown by modelling that in contrast to the widespread opinion that simultaneous masing of methanol transitions of different classes is impossible there are conditions for which simultaneous masing of the class II transition at 6.7-GHz and some class I transitions (e.g. the series at 25 GHz) is possible. A relevant example is provided, in which the pumping occurs via the first torsionally excited state and is driven by radiation of the dust intermixed with the gas in the cloud. In this regime the dust temperature is significantly lower (T is about 60 K) than in the case of bright 6.7-GHz masers (T>150 K). The narrow spectral feature at -1.1 km/s has a brightness temperature greater than about 1400 K, which suggests that it is probably a maser. It emanates from the Orion South region and is probably associated with the approaching part of outflow seen in CO. The 25-GHz maser associated with OMC-1 was observed quasi-simultaneously with the 6.7-GHz observations. No 25-GHz emission associated with the -1.1 km/s 6.7 GHz feature towards Orion South was detected.

  10. CANDIDATES FOR THE YOUNG STELLAR OUTFLOWS: WATER AND METHANOL MASERS FROM YOUNG STELLAR OBJECTS

    SciTech Connect (OSTI)

    Lim, Wanggi; Lyo, A-Ran; Kim, Kee-Tae; Byun, Do-Young [Korea Astronomy and Space Science Institute, Daedeok Street 776, Yuseong-Gu, 305-348 Daejeon (Korea, Republic of)

    2012-11-01T23:59:59.000Z

    We conducted simultaneous 22 GHz water maser and 44 GHz class I methanol maser surveys of newly identified 282 H{sub 2} emission features from the 2.122 {mu}m H{sub 2} narrowband image survey in the Galactic plane (UWISH2 project) using Korean VLBI Network 21 m radio telescopes. We detected 16 and 13 new water and methanol maser sources, respectively. This result indicates that at least {approx}5% of the H{sub 2} emission features originate from young stellar objects (YSOs) that are in the right physical condition to produce the water and methanol masers. The masers are closely related to the current outflow activities in the Galactic plane. The power sources of these 23 diffused/collimated H{sub 2} emission features (six sources are detected for both masers) are likely to be intermediate- to high-mass YSOs, based on a comparison with the maser luminosities of other well-studied YSOs. Both maser velocities are mostly close to their own systemic velocities within {approx}<5 km s{sup -1}, even though water masers generally show larger variabilities in the intensity, velocity, and shape than methanol masers. We also discovered three new water maser sources with high-velocity components: {approx}25 km s{sup -1} redshifted CMHO 019, {approx}50 km s{sup -1} blueshifted CMHO 132, and {approx}120 km s{sup -1} blueshifted CMHO 182. In particular, we propose that the dominant blueshifted water maser of CHMO 182 can be a unique laboratory for the study of the high-mass young stellar jet and its acceleration.

  11. Methanol synthesis on ZnO(0001{sup ¯}). IV. Reaction mechanisms and electronic structure

    SciTech Connect (OSTI)

    Frenzel, Johannes, E-mail: johannes.frenzel@theochem.rub.de; Marx, Dominik [Lehrstuhl für Theoretische Chemie, Ruhr-Universität Bochum, 44780 Bochum (Germany)

    2014-09-28T23:59:59.000Z

    Methanol synthesis from CO and H{sub 2} over ZnO, which requires high temperatures and high pressures giving rise to a complex interplay of physical and chemical processes over this heterogeneous catalyst surface, is investigated using ab initio simulations. The redox properties of the surrounding gas phase are known to directly impact on the catalyst properties and thus, set the overall catalytic reactivity of this easily reducible oxide material. In Paper III of our series [J. Kiss, J. Frenzel, N. N. Nair, B. Meyer, and D. Marx, J. Chem. Phys. 134, 064710 (2011)] we have qualitatively shown that for the partially hydroxylated and defective ZnO(0001{sup ¯}) surface there exists an intricate network of surface chemical reactions. In the present study, we employ advanced molecular dynamics techniques to resolve in detail this reaction network in terms of elementary steps on the defective surface, which is in stepwise equilibrium with the gas phase. The two individual reduction steps were investigated by ab initio metadynamics sampling of free energy landscapes in three-dimensional reaction subspaces. By also sampling adsorption and desorption processes and thus molecular species that are in the gas phase but close to the surface, our approach successfully generated several alternative pathways of methanol synthesis. The obtained results suggest an Eley-Rideal mechanism for both reduction steps, thus involving “near-surface” molecules from the gas phase, to give methanol preferentially over a strongly reduced catalyst surface, while important side reactions are of Langmuir-Hinshelwood type. Catalyst re-reduction by H{sub 2} stemming from the gas phase is a crucial process after each reduction step in order to maintain the catalyst's activity toward methanol formation and to close the catalytic cycle in some reaction channels. Furthermore, the role of oxygen vacancies, side reactions, and spectator species is investigated and mechanistic details are discussed based on extensive electronic structure analysis.

  12. Commercial-Scale Demonstration of the Liquid Phase methanol (LPMEOH) Process A DOE Assessment

    SciTech Connect (OSTI)

    National Energy Technology Laboratory

    2003-10-27T23:59:59.000Z

    The U.S. Department of Energy (DOE) Clean Coal Technology (CCT) Program seeks to offer the energy marketplace more efficient and environmentally benign coal utilization technology options by demonstrating them in industrial settings. This document is a DOE post-project assessment (PPA) of one of the projects selected in Round III of the CCT Program, the commercial-scale demonstration of the Liquid Phase Methanol (LPMEOH{trademark}) Process, initially described in a Report to Congress by DOE in 1992. Methanol is an important, large-volume chemical with many uses. The desire to demonstrate a new process for the production of methanol from coal, prompted Air Products and Chemicals, Inc. (Air Products) to submit a proposal to DOE. In October 1992, DOE awarded a cooperative agreement to Air Products to conduct this project. In March 1995, this cooperative agreement was transferred to Air Products Liquid Phase Conversion Company, L.P. (the Partnership), a partnership between Air Products and Eastman Chemical Company (Eastman). DOE provided 43 percent of the total project funding of $213.7 million. Operation of the LPMEOH Demonstration Unit, which is sited at Eastman's chemicals-from-coal complex in Kingsport, Tennessee, commenced in April 1997. Although operation of the CCT project was completed in December 2002, Eastman continues to operate the LPMEOH Demonstration Unit for the production of methanol. The independent evaluation contained herein is based primarily on information from Volume 2 of the project's Final Report (Air Products Liquid Phase Conversion Co., L.P. 2003), as well as other references cited.

  13. Technoeconomic Comparison of Biofuels: Ethanol, Methanol, and Gasoline from Gasification of Woody Residues (Presentation)

    SciTech Connect (OSTI)

    Tarud, J.; Phillips, S.

    2011-08-01T23:59:59.000Z

    This presentation provides a technoeconomic comparison of three biofuels - ethanol, methanol, and gasoline - produced by gasification of woody biomass residues. The presentation includes a brief discussion of the three fuels evaluated; discussion of equivalent feedstock and front end processes; discussion of back end processes for each fuel; process comparisons of efficiencies, yields, and water usage; and economic assumptions and results, including a plant gate price (PGP) for each fuel.

  14. SiO Outflow Signatures Toward Massive Young Stellar Objects with Linearly Distributed Methanol Masers

    E-Print Network [OSTI]

    J. M. De Buizer; R. O. Redman; S. N. Longmore; J. Caswell; P. A. Feldman

    2008-10-27T23:59:59.000Z

    Methanol masers are often found in linear distributions, and it has been hypothesized that these masers are tracing circumstellar accretion disks around young massive stars. However, recent observations in H2 emission have shown what appear to be outflows at similar angles to the maser distribution angles, not perpendicular as expected in the maser-disk scenario. The main motivation behind the observations presented here is to determine from the presence and morphology of an independent outflow tracer, namely SiO, if there are indeed outflows present in these regions and if they are consistent or inconsistent with the maser-disk hypothesis. For ten sources with H2 emission we obtained JCMT single dish SiO (6-5) observations to search for the presence of this outflow indicator. We followed up those observations with ATCA interferometric mapping of the SiO emission in the (2-1) line in six sources. The JCMT observations yielded a detection in the SiO (6-5) line in nine of the ten sources. All of the sources with bright SiO lines display broad line wings indicative of outflow. A subset of the sources observed with the JCMT have methanol maser velocities significantly offset from their parent cloud velocities, supporting the idea that the masers in these sources are likely not associated with circumstellar disks. The ATCA maps of the SiO emission show five of the six sources do indeed have SiO outflows. The spatial orientations of the outflows are not consistent with the methanol masers delineating disk orientations. Overall, the observations presented here seem to provide further evidence against the hypothesis that linearly distributed methanol masers generally trace the orientations of circumstellar disks around massive young stars.

  15. Multiple Time-Scale Behaviour and Network Dynamics in Liquid Methanol

    E-Print Network [OSTI]

    Ruchi Sharma; Charusita Chakravarty

    2008-11-11T23:59:59.000Z

    Canonical ensemble molecular dynamics simulations of liquid methanol, modeled using a rigid-body, pair-additive potential, are used to compute static distributions and temporal correlations of tagged molecule potential energies as a means of characterising the liquid state dynamics. The static distribution of tagged molecule potential energies shows a clear multimodal structure with three distinct peaks, similar to those observed previously in water and liquid silica. The multimodality is shown to originate from electrostatic effects, but not from local, hydrogen-bond interactions. An interesting outcome of this study is the remarkable similarity in the tagged potential energy power spectra of methanol, water and silica, despite the differences in the underlying interactions and the dimensionality of the network. All three liquids show a distinct multiple time scale (MTS) regime with a 1/f dependence with a clear positive correlation between the scaling exponent alpha and the diffusivity. The low-frequency limit of the MTS regime is determined by the frequency of crossover to white noise behaviour which occurs at approximately 0.1 cm{-1} in the case of methanol under standard temperature and pressure conditions. The power spectral regime above 200 cm{-1} in all three systems is dominated by resonances due to localised vibrations, such as librations. The correlation between $\\alpha$ and the diffusivity in all three liquids appears to be related to the strength of the coupling between the localised motions and the larger length/time-scale network reorganizations. Thus the time scales associated with network reorganization dynamics appear to be qualitatively similar in these systems, despite the fact that water and silica both display diffusional anomalies but methanol does not.

  16. The Australia Telescope campaign to study southern class I methanol masers

    E-Print Network [OSTI]

    M. A. Voronkov; K. J. Brooks; A. M. Sobolev; S. P. Ellingsen; A. B. Ostrovskii; J. L. Caswell

    2007-05-02T23:59:59.000Z

    The Australia Telescope Compact Array (ATCA) and the Mopra facility have been used to search for new southern class I methanol masers at 9.9, 25 (J=5) and 104 GHz, which are thought to trace more energetic conditions in the interface regions of molecular outflows, than the widespread class I masers at 44 and 95 GHz. One source shows a clear outflow association.

  17. Isobaric vapor-liquid equilibria of methanol + 1-octanol and ethanol + 1-octanol mixtures

    SciTech Connect (OSTI)

    Arce, A.; Blanco, A.; Soto, A.; Tojo, J. [Univ. of Santiago de Compostela (Spain). Chemical Engineering Dept.

    1995-07-01T23:59:59.000Z

    Isobaric vapor-liquid equilibrium data for methanol + 1-octanol and ethanol + 1-octanol have been measured at 101.325 kPa. The results were checked for thermodynamic consistency using Fredenslund et al.`s test, correlated using Wilson, NRTL, and UNIQUAC equations for the liquid phase activity coefficients, and compared with the predictions of the ASOG, UNIFAC, and modified UNIFAC group contribution methods.

  18. Total pressure measurements for pentane + methanol + ethanol at 303. 15 K

    SciTech Connect (OSTI)

    Reimers, J.L.; Bhethanabotla, V.R.; Campbell, S.W. (Dept. of Chemical Engineering, Univ. of South Florida, Tampa, FL (US))

    1992-01-01T23:59:59.000Z

    In this paper total pressure is reported as a function of liquid-phase composition for pentane + methanol + ethanol at 303.15 K. The data were reduced using Barker's method. The excess Gibbs energy of the liquid phase is represented by a rational function obtained by making an empirical modification to the nonrandom two-liquid (NRTL) equation. The resulting fit to the data is superior to that obtained using a previous representation based on a modified Margules equation.

  19. The nature and formation of coke in the reaction of methanol to hydrocarbons over chabazite 

    E-Print Network [OSTI]

    McLaughlin, Kenneth Woot

    1983-01-01T23:59:59.000Z

    45 Figure 9. Relationship between enhanced coke formation with increasing yields of paraffins and diminishing yields of olefins 46 Figure 10. Gas chromatogram of the concentrated carbon tetrachloride extract of spent catalyst pellets . . . 49...THE NATURE ABD FORMATION OF COKE IB THE REACTIOB OF METHANOL TO HIDROCARBOBS OVER CHABAZITE A Thesis KENNETH WOOT MCLAUGHLLN Submitted to the Graduate College of Texas AAM Univers ty partial. fulfillment nf the req~nt fo~he degree of MASTER...

  20. The nature and formation of coke in the reaction of methanol to hydrocarbons over chabazite

    E-Print Network [OSTI]

    McLaughlin, Kenneth Woot

    1983-01-01T23:59:59.000Z

    involves the nature of the step whereby methanol and dimethyl ether (DME), both lacking B -hydrogens, undergo dehydration to form olefins. Chang and Silvestri argued against the formation of a primary methyl carbonium ion as an intermediate based... went on to propose the formation of the primary olefins from dimethyl ether via a trimethyl oxonium ion which is illustrated in Figure 5. The Stevens type rearrangement involving the methyl shift produces the first C-0 bond and has been suggested...

  1. Mechanistic Studies of Methanol Synthesis over Cu from CO/CO2/H2/H2O Mixtures: the Source of C in Methanol and the Role of Water

    SciTech Connect (OSTI)

    Yang, Yong; Mims, Charles A.; Mei, Donghai; Peden, Charles HF; Campbell, Charles T.

    2013-02-01T23:59:59.000Z

    The low temperature (403 – 453K) conversions of CO:hydrogen and CO2:hydrogen mixtures (6 bar total pressure) to methanol over copper catalysts are both assisted by the presence of small amounts of water (mole fraction ~0.04%-0.5%). For CO2:hydrogen reaction mixtures, the water product from both methanol synthesis and reverse water gas shift serves to initiate both reactions in an autocatalytic manner. In the case of CO:D2 mixtures, very little methanol is produced until small amounts of water are added. The effect of water on methanol production is more immediate than in CO2:D2, yet the steady state rates are similar. Tracer experiments in 13CO:12CO2:hydrogen (with or without added water), show that the dominant source of C in the methanol product gradually shifts from CO2 to CO as the temperature is lowered. Cu-bound formate, the major IR visible surface species under CO2:hydrogen, is not visible in CO:moist hydrogen. Though formate is visible in the tracer experiments, the symmetric stretch is absent. These results, in conjunction with recent DFT calculations on Cu(111), point to carboxyl as a common intermediate for both methanol synthesis and reverse water gas shift, with formate playing a spectator co-adsorbate role.

  2. EXPANDED VERY LARGE ARRAY DETECTION OF 36.2 GHz CLASS I METHANOL MASERS IN SAGITTARIUS A

    E-Print Network [OSTI]

    Sjouwerman, Loránt O.

    We report on the interferometric detection of 36.2 GHz Class I methanol emission with the new 27-40 GHz Ka-band receivers available on the Expanded Very Large Array (EVLA). The brightness temperatures of the interferometric ...

  3. Vibrational relaxation of the free terminal hydroxyl stretch in methanol oligomers: Indirect pathway to hydrogen bond breaking

    E-Print Network [OSTI]

    Fayer, Michael D.

    Vibrational relaxation of methanol-d MeOD in carbon tetrachloride has been investigated via ultrafast infrared such as carbon tetrachloride (CCl4) or alkanes. Unlike water, which is only sparingly soluble in nonpolar

  4. TUNING OF SIZE AND SHAPE OF AU-PT NANOCATALYST FOR DIRECT METHANOL FUEL CELLS

    SciTech Connect (OSTI)

    Murph, S.

    2011-04-20T23:59:59.000Z

    In this paper, we report the precise control of the size, shape and surface morphology of Au-Pt nanocatalysts (cubes, blocks, octahedrons and dogbones) synthesized via a seed-mediated approach. Gold 'seeds' of different aspect ratios (1 to 4.2), grown by a silver-assisted approach, were used as templates for high-yield production of novel Au-Pt nanocatalysts at a low temperature (40 C). Characterization by electron microscopy (SEM, TEM, HRTEM), energy dispersive X-ray analysis (EDX), UV-Vis spectroscopy, zeta-potential (surface charge), atomic force microscopy (AFM), X-ray photoelectron spectroscopy (XPS) and inductively coupled plasma mass spectrometry (ICP-MS) were used to better understand their physico-chemical properties, preferred reactivities and underlying nanoparticle growth mechanism. A rotating disk electrode was used to evaluate the Au-Pt nanocatalysts electrochemical performance in the oxygen reduction reaction (ORR) and the methanol oxidation reaction (MOR) of direct methanol fuel cells. The results indicate the Au-Pt dogbones are partially and in some cases completely unaffected by methanol poisoning during the evaluation of the ORR. The ORR performance of the octahedron particles in the absence of MeOH is superior to that of the Au-Pt dogbones and Pt-black, however its performance is affected by the presence of MeOH.

  5. Level Alignment of a Prototypical Photocatalytic System: Methanol on TiO2(110)

    SciTech Connect (OSTI)

    Migani, Annapaola; Mowbray, Duncan J.; Iacomino, Amilcare; Zhao, Jin; Petek, Hrvoje

    2013-08-07T23:59:59.000Z

    Photocatalytic activity depends on the optimal alignment of electronic levels at the molecule? semiconductor interface. Establishing the level alignment experimentally is complicated by the uncertain chemical identity of the surface species. We address the assignment of the occupied and empty electronic levels for the prototypical photocatalytic system consisting of methanol on a rutile TiO2(110) surface. Using many-body quasiparticle (QP) techniques, we show that the frontier levels measured in UV photoelectron and two-photon photoemission spectroscopy experiments can be assigned to molecularly chemisorbed methanol rather than its dissociated product, the methoxy species. We find that the highest occupied molecular orbital of the methoxy species is much closer to the valence band maximum, suggesting why it is more photocatalytically active than the methanol molecule. We develop a general semiquantitative model for predicting many-body QP energies based on the electronic screening within the bulk, molecular, or vacuum regions of the wave functions at molecule?semiconductor interfaces.

  6. Photodissociation of organic molecules in star-forming regions, III. Methanol

    E-Print Network [OSTI]

    S. Pilling; R. Neves; A. C. F. Santos; H. M. Boechat-Roberty

    2006-12-15T23:59:59.000Z

    The presence of methyl alcohol or methanol (CH$_3$OH) in several astrophysical environments has been characterized by its high abundance that depends on both the production rate and the destruction rate. In the present work, the photoionization and photodissociation processes of methanol have been experimentally studied, employing soft X-ray photons (100-310 eV) from a toroidal grating monochromator (TGM) beamline of the Brazilian Synchrotron Light Laboratory (LNLS). Mass spectra were obtained using the photoelectron photoion coincidence (PEPICO) method. Kinetic energy distribution and abundances for each ionic fragment have been obtained from the analysis of the corresponding peak shapes in the mass spectra. Absolute photoionization and photodissociation cross sections were also determined. We have found, among the channels leading to ionization, about 11-16% of CH$_3$OH survive the soft X-rays photons. This behavior, together with an efficient formation pathways, may be associated with the high column density observed in star-forming regions. The three main photodissociation pathways are represented by COH$^+$ (or HCO$^+$) ion release (with ejection of H$_2$ + H), the dissociation via C-O bond rupture (with strong charge retention preferentially on the methyl fragment) and the ejection of a single energetic (2-4 eV) proton. Since methanol is very abundant in star forming regions, the produced protons could be an alternative route to molecular hydrogenation or a trigger for secondary dissociation processes or even to promote extra heating of the environment.

  7. Proton exchange membrane materials for the advancement of direct methanol fuel-cell technology

    DOE Patents [OSTI]

    Cornelius, Christopher J. (Albuquerque, NM)

    2006-04-04T23:59:59.000Z

    A new class of hybrid organic-inorganic materials, and methods of synthesis, that can be used as a proton exchange membrane in a direct methanol fuel cell. In contrast with Nafion.RTM. PEM materials, which have random sulfonation, the new class of materials have ordered sulfonation achieved through self-assembly of alternating polyimide segments of different molecular weights comprising, for example, highly sulfonated hydrophilic PDA-DASA polyimide segment alternating with an unsulfonated hydrophobic 6FDA-DAS polyimide segment. An inorganic phase, e.g., 0.5 5 wt % TEOS, can be incorporated in the sulfonated polyimide copolymer to further improve its properties. The new materials exhibit reduced swelling when exposed to water, increased thermal stability, and decreased O.sub.2 and H.sub.2 gas permeability, while retaining proton conductivities similar to Nafion.RTM.. These improved properties may allow direct methanol fuel cells to operate at higher temperatures and with higher efficiencies due to reduced methanol crossover.

  8. Cold flow tudy of a fluidized bed reactor for catalytic conversion of methanol to low molecular weight hydrocarbons

    E-Print Network [OSTI]

    Mehta, Shirish Ramniklal

    1982-01-01T23:59:59.000Z

    COLD FLOW STUDY OF A FLUIDIZED BED REACTOR FOR CATALYTIC CONVERSION OF METHANOL TO LOW MOLECULAR WEIGHT HYDROCAREONS A Thesis by SHIRISH RAMNIKLAL MEHTA Submitted to the Graduate College of Texas A&M University in partial fulfilment... of the requirement for the degree of MASTER OF SCIENCE March 1982 Major Subject: Chemical Engineering COLD FLOW STUDY OF A FLUIDIZED BED REACTOR FOR CATALYTIC CONVERSION OF METHANOL TO LOW MOLECULAR WEIGHT HYDROCARBON A Thesis by SHIRISH RAMNIKLAL MEHTA...

  9. EXPANDED VERY LARGE ARRAY DETECTION OF 36.2 GHz CLASS I METHANOL MASERS IN SAGITTARIUS A

    SciTech Connect (OSTI)

    Sjouwerman, Lorant O. [National Radio Astronomy Observatory, P.O. Box O, Socorro, NM 87801 (United States); Pihlstroem, Ylva M. [Department of Physics and Astronomy, University of New Mexico, 800 Yale Boulevard NE, Albuquerque, NM 87131 (United States); Fish, Vincent L. [Massachusetts Institute of Technology, Haystack Observatory, Route 40, Westford, MA 01886 (United States)], E-mail: lsjouwerman@nrao.edu, E-mail: ylva@unm.edu, E-mail: vfish@haystack.mit.edu

    2010-02-20T23:59:59.000Z

    We report on the interferometric detection of 36.2 GHz Class I methanol emission with the new 27-40 GHz Ka-band receivers available on the Expanded Very Large Array (EVLA). The brightness temperatures of the interferometric 36 GHz detections unambiguously indicate for the first time that the emission is maser emission. The 36 GHz methanol masers are not co-spatial with 1720 MHz OH masers, indicating that the two species trace different shocks. The 36 GHz and 44 GHz methanol masers, which are collisionally pumped, do not necessarily co-exist and may trace different methanol gas. The methanol masers seem correlated with NH{sub 3}(3,3) density peaks. We favor an explanation in which the 36 GHz Class I methanol masers outline regions of cloud-cloud collisions, perhaps just before the onset of the formation of individual massive stars. The transition of the Very Large Array (VLA) to the EVLA is well under way, and these detections demonstrate the bright future of this completely renewed instrument.

  10. A Comparative Study of the Adsorption of Water and Methanol in Zeolite BEA: A Molecular Simulation Study

    SciTech Connect (OSTI)

    Nguyen, Van T.; Nguyen, Phuong T.; Dang, Liem X.; Mei, Donghai; Wick, Collin D.; Do, Duong D.

    2014-09-15T23:59:59.000Z

    Grand Canonical Monte Carlo (GCMC) simulations were carried out to study the equilibrium adsorption concentration of methanol and water in all-silica zeolite BEA over the wide temperature and pressure ranges. For both water and methanol, their adsorptive capacity increases with increasing pressure and decreasing temperature. The onset of methanol adsorption occurs at much lower pressures than water adsorption at all temperatures. Our GCMC simulation results also indicate that the adsorption isotherms of methanol exhibit a gradual change with pressure while water adsorption shows a sharp first-order phase transition at low temperatures. To explore the effects of Si/Al ratio on adsorption, a series of GCMC simulations of water and methanol adsorption in zeolites HBEA with Si/Al=7, 15, 31, 63 were performed. As the Si/Al ratio decreases, the onsets of both water and methanol adsorption dramatically shift to lower pressures. The type V isotherm obtained for water adsorption in hydrophobic BEA progressively changes to type I isotherm with decreasing Si/Al ratio in hydrophilic HBEA. This work was supported by the US Department of Energy, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences & Biosciences. Pacific Northwest National Laboratory (PNNL) is a multiprogram national laboratory operated for DOE by Battelle.

  11. Wabash River Integrated Methanol and Power Production from Clean Coal Technologies (IMPPCCT)

    SciTech Connect (OSTI)

    Conocophillips

    2007-09-30T23:59:59.000Z

    The Wabash River Integrated Methanol and Power Production from Clean Coal Technologies (IMPPCCT) project was established to evaluate integrated electrical power generation and methanol production through clean coal technologies. The project was under the leadership of ConocoPhillips Company (COP), after it acquired Gasification Engineering Corporation (GEC) and the E-Gas gasification technology from Global Energy Inc. in July 2003. The project has completed both Phase 1 and Phase 2 of development. The two project phases include the following: (1) Feasibility study and conceptual design for an integrated demonstration facility at SG Solutions LLC (SGS), previously the Wabash River Energy Limited, Gasification Facility located in West Terre Haute, Indiana, and for a fence-line commercial embodiment plant (CEP) operated at the Dow Chemical Company or Dow Corning Corporation chemical plant locations. (2) Research, development, and testing (RD&T) to define any technology gaps or critical design and integration issues. Phase 1 of this project was supported by a multi-industry team consisting of Air Products and Chemicals, Inc., The Dow Chemical Company, Dow Corning Corporation, Methanex Corporation, and Siemens Westinghouse Power Corporation, while Phase 2 was supported by Gas Technology Institute, TDA Research Inc., and Nucon International, Inc. The SGS integrated gasification combined cycle (IGCC) facility was designed, constructed, and operated under a project selected and co-funded under the Round IV of the United States Department of Energy's (DOE's) Clean Coal Technology Program. In this project, coal and/or other carbonaceous fuel feedstocks are gasified in an oxygen-blown, entrained-flow gasifier with continuous slag removal and a dry particulate removal system. The resulting product synthesis gas (syngas) is used to fuel a combustion turbine generator whose exhaust is integrated with a heat recovery steam generator to drive a refurbished steam turbine generator. The gasifier uses technology initially developed by The Dow Chemical Company (the Destec Gasification Process), and now acquired and offered commercially by COP as the E-Gas technology. In a joint effort with the DOE, a Cooperative Agreement was awarded under the Early Entrance Coproduction Plant (EECP) solicitation. GEC, and later COP and the industrial partners investigated the use of syngas produced by the E-Gas technology in a coproduction environment to enhance the efficiency and productivity of solid fuel gasification combined cycle power plants. The objectives of this effort were to determine the feasibility of an EECP located at a specific site which produces some combination of electric power (or heat), fuels, and/or chemicals from syngas derived from coal, or, coal in combination with some other carbonaceous feedstock. The intended result of the project was to provide the necessary technical, economic, and environmental information that would be needed to move the EECP forward to detailed design, construction, and operation by industry. The EECP study conducted in Phase 1 of the IMPPCCT Project confirmed that the concept for the integration of gasification-based (E-Gas) electricity generation from coal and/or petroleum coke and methanol production (Liquid Phase Methanol or LPMEOH{trademark}) processes was feasible for the coproduction of power and chemicals. The results indicated that while there were minimal integration issues that impact the deployment of an IMPPCCT CEP, the major concern was the removal of sulfur and other trace contaminants, which are known methanol catalyst poisons, from the syngas. However, economic concerns in the domestic methanol market which is driven by periodic low natural gas prices and cheap offshore supplies limit the commercial viability of this more capital intensive concept. The objective of Phase 2 was to conduct RD&T as outlined in the Phase 1 RD&T Plan to enhance the development and commercial acceptance of coproduction technology. Studies were designed to address the technical concerns that would mak

  12. Commercial-Scale Demonstration of the Liquid Phase Methanol (LOMEOH(TM)) Process

    SciTech Connect (OSTI)

    None

    1996-03-31T23:59:59.000Z

    The Liquid Phase Methanol (LPMEOEP") Demonstration Project at K.ingsport, Tennessee, is a $213.7 million cooperative agreement between the U.S. Department of Energy (DOE) and Air Products Liquid Phase Conversion Company, L, P. (the Partnership). The LPMEOHY Process Demonstration Unit is being built at a site located at the Eastman Chemical Company (Eastman) complex in Kingsport. On 4 October 1994, Air Products and Chemicals, Inc. (Air Products) and signed the agreements that would form the Partnership, secure the demonstration site, and provide the financial commitment and overall project management for the project. These partnership agreements became effective on 15 March 1995, when DOE authorized the commencement of Budget Period No. 2 (Mod. AO08 to the Cooperative Agreement). The Partnership has subcontracted with Air Products to provide the overall management of the project, and to act as the primary interface with DOE. As subcontractor to the Partnership, Air Products will also provide the engineering design, procurement, construction, and commissioning of the LPMEOHTM Process Demonstration Unit, and will provide the technical and engineering supervision needed to conduct the operational testing program required as part of the project. As subcontractor to Air Products, Eastman will be responsible for operation of the LPMEOHTM Process Demonstration Unit, and for the interconnection and supply of synthesis gas, utilities, product storage, and other needed sewices. The project involves the construction of an 80,000 gallons per day (260 tons-per-day (TPD)) methanol unit utilizing coal-derived synthesis gas fi-om Eastman's integrated coal gasification facility. The new equipment consists of synthesis gas feed preparation and compression facilities, the liquid phase reactor and auxiliaries, product distillation facilities, and utilities. The technology to be demonstrated is the product of a cooperative development effort by Air Products and DOE in a program that started in 1981. Developed to enhance electric power generation using integrated gasification combined cycle (IGCC) technology, the LPMEOHTM process is ideally suited for directly processing gases produced by modern day coal gasifiers. Originally tested at a small 3,200 gallons per day, DOE-owned experimental unit in LaPorte, Texas, the technology provides several improvements essential for the economic coproduction of methanol and electricity directly from gasified coal. This liquid phase process suspends fine catalyst particles in an inert liquid, forming a slurry. The slurry dissipates the heat of the chemical reaction away from the catalyst surface, protecting the catalyst and allowing the methanol synthesis reaction to proceed at higher rates.

  13. Salt effect on the isobaric vapor-liquid equilibrium of the methyl acetate + methanol system

    SciTech Connect (OSTI)

    Iliuta, M.C.; Thyrion, F.C. [Louvain Univ., Louvain-la-Neuve (Belgium). Chemical Engineering Inst.] [Louvain Univ., Louvain-la-Neuve (Belgium). Chemical Engineering Inst.; Landauer, O.M. [Univ. Politehnica Bucharest (Romania)] [Univ. Politehnica Bucharest (Romania)

    1996-07-01T23:59:59.000Z

    The effect of sodium thiocyanate at constant salt mole fraction from 0.01 to 0.05 and at saturation on the vapor-liquid equilibrium (VLE) of methyl acetate + methanol has been studied at 101.32 kPa using a modified Othmer equilibrium still. The salt exhibited both salting-in and salting-out effects on the methyl acetate, the azeotrope being eliminated at saturation. The results were correlated using the extended UNIQUAC model of Sander et al. and the electrolytic NRTL model of Mock et al.

  14. NEAT-IGERT Proposal E. OTHER RESEARCH

    E-Print Network [OSTI]

    Islam, M. Saif

    and understanding of their properties, there are still many aspects of the synthesis and materials chemistry students working on the synthesis of organic / inorganic nanoparticle films will have the opportunity, via issues associated with this chemical behavior of this fine material to help Granite Rock find uses

  15. National Energy Audit (NEAT) | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere I Geothermal Pwer PlantMunhall, Pennsylvania: EnergyEnergy Information Conference of State

  16. Synthesis of Methanol and Dimethyl Ether from Syngas over Pd/ZnO/Al2O3 Catalysts

    SciTech Connect (OSTI)

    Lebarbier, Vanessa MC; Dagle, Robert A.; Kovarik, Libor; Lizarazo Adarme, Jair A.; King, David L.; Palo, Daniel R.

    2012-10-01T23:59:59.000Z

    A Pd/ZnO/Al2O3 catalyst was developed for the synthesis of methanol and dimethyl ether (DME) from syngas. Studied were temperatures of operation ranging from 250°C to 380°C. High temperatures (e.g. 380°C) are necessary when combining methanol and DME synthesis with a methanol to gasoline (MTG) process in a single reactor bed. A commercial Cu/ZnO/Al2O3 catalyst, utilized industrially for the synthesis of methanol at 220-280°C, suffers from a rapid deactivation when the reaction is conducted at high temperature (>320°C). On the contrary, a Pd/ZnO/Al2O3 catalyst was found to be highly stable for methanol and DME synthesis at 380°C. The Pd/ZnO/Al2O3 catalyst was thus further investigated for methanol and DME synthesis at P=34-69 bars, T= 250-380°C, GHSV= 5 000-18 000 h-1, and molar feeds H2/CO= 1, 2, and 3. Selectivity to DME increased with decreasing operating temperature, and increasing operating pressure. Increased GHSV’s and H2/CO syngas feed ratios also enhanced DME selectivity. Undesirable CH4 formation was observed, however, can be minimized through choice of process conditions and by catalyst design. By studying the effect of the Pd loading and the Pd:Zn molar ratio the formulation of the Pd/ZnO/Al2O3 catalyst was optimized. A catalyst with 5% Pd and a Pd:Zn molar ratio of 0.25:1 has been identified as the preferred catalyst. Results indicate that PdZn particles are more active than Pdº particles for the synthesis of methanol and less active for CH4 formation. A correlation between DME selectivity and the concentration of acid sites of the catalysts has been established. Hence, two types of sites are required for the direct conversion of syngas to DME: 1) PdZn particles are active for the synthesis of methanol from syngas, and 2) acid sites which are active for the conversion of methanol to DME. Additionally, CO2 formation was problematic as PdZn was found to be active for the water-gas-shift (WGS) reaction, under all the conditions evaluated.

  17. Molecular Mechanism of the Adsorption Process of an Iodide Anion into Liquid-Vapor Interfaces of Water-Methanol Mixtures

    SciTech Connect (OSTI)

    Annapureddy, Harsha V.; Dang, Liem X.

    2012-12-07T23:59:59.000Z

    To enhance our understanding of the molecular mechanism of ion adsorption to the interface of mixtures, we systematically carried out a free energy calculations study involving the transport of an iodide anion across the interface of a water-methanol mixture. Many body affects are taken into account to describe the interactions among the species. The surface propensities of I- at interfaces of pure water and methanol are well understood. In contrast, detailed knowledge of the molecular level adsorption process of I- at aqueous mixture interfaces has not been reported. In this paper, we explore how this phenomenon will be affected for mixed solvents with varying compositions of water and methanol. Our potential of mean force study as function of varying compositions indicated that I- adsorption free energies decrease from pure water to pure methanol but not linearly with the concentration of methanol. We analyze the computed density profiles and hydration numbers as a function of concentrations and ion positions with respect to the interface to further explain the observed phenomenon. This work was supported by the U.S. Department of Energy (DOE), Office of Basic Energy Sciences (BES), Division of Chemical Sciences, Geosciences, and Biosciences. Pacific Northwest National Laboratory is a multiprogram national laboratory operated for DOE by Battelle. The calculations were carried out using computer resources provided by BES.

  18. Multibeam Maser Survey of methanol and excited OH in the Magellanic Clouds: new detections and maser abundance estimates

    E-Print Network [OSTI]

    J. A. Green; J. L. Caswell; G. A. Fuller; S. L. Breen; K. Brooks; M. G. Burton; A. Chrysostomou; J. Cox; P. J. Diamond; S. P. Ellingsen; M. D. Gray; M. G. Hoare; M. R. W. Masheder; N. McClure-Griffiths; M. Pestalozzi; C. Phillips; L. Quinn; M. A. Thompson; M. Voronkov; A. Walsh; D. Ward-Thompson; D. Wong-McSweeney; J. A. Yates; R. J. Cohen

    2008-01-02T23:59:59.000Z

    We present the results of the first complete survey of the Large and Small Magellanic Clouds for 6668-MHz methanol and 6035-MHz excited-state hydroxyl masers. In addition to the survey, higher-sensitivity targeted searches towards known star-formation regions were conducted. The observations yielded the discovery of a fourth 6668-MHz methanol maser in the Large Magellanic Cloud (LMC), found towards the star-forming region N160a, and a second 6035-MHz excited-state hydroxyl maser, found towards N157a. We have also re-observed the three previously known 6668-MHz methanol masers and the single 6035-MHz hydroxyl maser. We failed to detect emission from either transition in the Small Magellanic Cloud. All observations were initially made using the Methanol Multibeam (MMB) survey receiver on the 64-m Parkes telescope as part of the MMB project and accurate positions have been measured with the Australia Telescope Compact Array (ATCA). We compare the maser populations in the Magellanic Clouds with those of our Galaxy and discuss their implications for the relative rates of massive star-formation, heavy metal abundance, and the abundance of complex molecules. The LMC maser populations are demonstrated to be smaller than their Milky Way counterparts. Methanol masers are under-abundant by a factor of ~45, whilst hydroxyl and water masers are a factor of ~10 less abundant than our Galaxy.

  19. Site-site memory equation approach in study of density/pressure dependence of translational diffusion coefficient and rotational relaxation time of polar molecular solutions: acetonitrile in water, methanol in water, and methanol in acetonitrile

    E-Print Network [OSTI]

    Kobryn, A E; Hirata, F

    2005-01-01T23:59:59.000Z

    We present results of theoretical study and numerical calculation of the dynamics of molecular liquids based on combination of the memory equation formalism and the reference interaction site model - RISM. Memory equations for the site-site intermediate scattering functions are studied in the mode-coupling approximation for the first order memory kernels, while equilibrium properties such as site-site static structure factors are deduced from RISM. The results include the temperature-density(pressure) dependence of translational diffusion coefficients D and orientational relaxation times t for acetonitrile in water, methanol in water and methanol in acetonitrile, all in the limit of infinite dilution. Calculations are performed over the range of temperatures and densities employing the SPC/E model for water and optimized site-site potentials for acetonitrile and methanol. The theory is able to reproduce qualitatively all main features of temperature and density dependences of D and t observed in real and comp...

  20. Comparison of Bond Scission Sequence of Methanol on Tungsten Monocarbide and Pt-Modified Tungsten Monocarbide

    SciTech Connect (OSTI)

    Liu, P.; Stottlemyer, A.L.; Chen, J.G.

    2010-09-14T23:59:59.000Z

    The ability to control the bond scission sequence of O-H, C-H, and C-O bonds is of critical importance in the effective utilization of oxygenate molecules, such as in reforming reactions and in alcohol fuel cells. In the current study, we use methanol as a probe molecule to demonstrate the possibility to control the decomposition pathways by supporting monolayer coverage of Pt on a tungsten monocarbide (WC) surface. Density functional theory (DFT) results reveal that on the WC and Pt/WC surfaces CH{sub 3}OH decomposes via O-H bond scission to form the methoxy (*CH{sub 3} O) intermediate. The subsequent decomposition of methoxy on the WC surface occurs through the C-O bond scission to form *CH{sub 3}, which reacts with surface *H to produce CH{sub 4}. In contrast, the decomposition of methoxy on the Pt/WC surface favors the C-H bond scission to produce *CH{sub 2} O, which prevents the formation of the *CH{sub 3} species and leads to the formation of a *CO intermediate through subsequent deprotonation steps. The DFT predictions are validated using temperature programmed desorption to quantify the gas-phase product yields and high resolution electron energy loss spectroscopy to determine the surface intermediates from methanol decomposition on Pt, WC, and Pt/WC surfaces.

  1. Commercial-Scale Demonstration of the Liquid Phase Methanol (LPMEOH(TM)) Process

    SciTech Connect (OSTI)

    None

    1996-12-31T23:59:59.000Z

    The Liquid Phase Methanol (LPMEOH(TM)) Demonstration Project at Kingsport, Tennessee, is a $213.7 million cooperative agreement between the U.S. Department of Energy (DOE) and Air Products Liquid Phase Conversion Company, L.P. (the Partnership). The LPMEOIWM Process Demonstration Unit is being built at a site located at the Eastman Chemical Company (Eastman) complex in Kingsport. During this quarter, the Cooperative Agreement was modified (Mod AO11) on 8 October 1996, authorizing the transition born Budget Period No. 2 (Design and Construction) to the . final Budget Period (Commissioning, Start-up, and Operation), A draft Topical Report on Process Economics Studies concludes that methanol coproduction with integrated gasification combined cycle (IGCC) electric power utilizing the LPMEOW process technology, will be competitive in serving local market needs. Planning for a proof-of- concept test run of the liquid phase dimethyl ether (DME) process at the LaPorte Alternative Fuels Development Unit (AFDU) was recommended; and a deeision to proceed is pending. Construction (Task 2.2) is 97'Mo complete, asof31 December 1996. Completion of pipe pressure testing has taken longer than expected. This will delay completion of construction by about three weeks. Commissioning activities (Task 2.3) commenced in mid-October of 1996, and the demonstration unit is scheduled to be mechanically complete on 24 January 1997.

  2. Mid-Infrared Source Multiplicity within Hot Molecular Cores traced by Methanol Masers

    E-Print Network [OSTI]

    S. N. Longmore; M. G. Burton; V. Minier; A. J. Walsh

    2006-04-12T23:59:59.000Z

    We present high resolution, mid-infrared images toward three hot molecular cores signposted by methanol maser emission; G173.49+2.42 (S231, S233IR), G188.95+0.89 (S252, AFGL-5180) and G192.60-0.05 (S255IR). Each of the cores was targeted with Michelle on Gemini North using 5 filters from 7.9 to 18.5 microns. We find each contains both large regions of extended emission and multiple, luminous point sources which, from their extremely red colours (F[18.5]/F[7.9] >= 3), appear to be embedded young stellar objects. The closest angular separations of the point sources in the three regions are 0.79, 1.00 and 3.33 arcseconds corresponding to linear separations of 1,700, 1,800 and 6,000AU respectively. The methanol maser emission is found closest to the brightest MIR point source (within the assumed 1 arcsecond pointing accuracy). Mass and luminosity estimates for the sources range from 3-22 Msol and 50-40,000 Lsol. Assuming the MIR sources are embedded objects and the observed gas mass provides the bulk of the reservoir from which the stars formed, it is difficult to generate the observed distributions for the most massive cluster members from the gas in the cores using a standard form of the IMF.

  3. Analysis of depolarization ratios of ClNO{sub 2} dissolved in methanol

    SciTech Connect (OSTI)

    Trimithioti, Marilena; Hayes, Sophia C., E-mail: shayes@ucy.ac.cy [Department of Chemistry, University of Cyprus, P.O. Box 20537, 1678, Nicosia (Cyprus); Akimov, Alexey V. [Department of Chemistry, University of Rochester, Rochester, New York 14627 (United States) [Department of Chemistry, University of Rochester, Rochester, New York 14627 (United States); Department of Chemistry, Brookhaven National Laboratory, Upton, New York 11973 (United States); Prezhdo, Oleg V. [Department of Chemistry, University of Rochester, Rochester, New York 14627 (United States)] [Department of Chemistry, University of Rochester, Rochester, New York 14627 (United States)

    2014-01-07T23:59:59.000Z

    A detailed analysis of the resonance Raman depolarization ratio dispersion curve for the N–O symmetric stretch of nitryl chloride in methanol at excitation wavelengths spanning the D absorption band is presented. The depolarization ratios are modeled using the time-dependent formalism for Raman scattering with contributions from two excited states (2{sup 1}A{sub 1} and 3{sup 1}B{sub 1}), which are taken as linearly dissociative along the Cl–N coordinate. The analysis focuses on the interplay between different types of broadening revealing the importance of inhomogenous broadening in determining the relative contributions of the two electronic transitions. We find that the transition dipole moment (M) for 2{sup 1}A{sub 1} is greater than for 3{sup 1}B{sub 1}, in agreement with gas phase calculations in the literature [A. Lesar, M. Hdoscek, M. Muhlhauser, and S. D. Peyerimhoff, Chem. Phys. Lett. 383, 84 (2004)]. However, we find that the polarity of the solvent influences the excited state energetics, leading to a reversal in the ordering of these two states with 3{sup 1}B{sub 1} shifting to lower energies. Molecular dynamics simulations along with linear response and ab initio calculations support the evidence extracted from resonance Raman intensity analysis, providing insights on ClNO{sub 2} electronic structure, solvation effects in methanol, and the source of broadening, emphasizing the importance of a contribution from inhomogeneous linewidth.

  4. HYDROGEN PRODUCTION FOR FUEL CELLS VIA REFORMING COAL-DERIVED METHANOL

    SciTech Connect (OSTI)

    Paul A. Erickson

    2004-04-01T23:59:59.000Z

    Hydrogen can be produced from many feed stocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the first such report that will be submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of October 1--December 31, 2003. This quarter saw progress in three areas. These areas are: (1) Evaluations of coal based methanol and the fuel cell grade baseline fuel, (2) Design and set up of the autothermal reactor, as well as (3) Set up and data collection of baseline performance using the steam reformer. All of the projects are proceeding on schedule. During this quarter one conference paper was written that will be presented at the ASME Power 2004 conference in March 2004, which outlines the research direction and basis for looking at the coal to hydrogen pathway.

  5. Hydrogen Production for Fuel Cells Via Reforming Coal-Derived Methanol

    SciTech Connect (OSTI)

    Paul A. Erickson

    2005-09-30T23:59:59.000Z

    Hydrogen can be produced from many feedstocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the eighth report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of October 1, 2004-September 30, 2005 and includes an entire review of the progress for year 2 of the project. This year saw progress in eight areas. These areas are: (1) steam reformer transient response, (2) steam reformer catalyst degradation, (3) steam reformer degradation tests using bluff bodies, (4) optimization of bluff bodies for steam reformation, (5) heat transfer enhancement, (6) autothermal reforming of coal derived methanol, (7) autothermal catalyst degradation, and (8) autothermal reformation with bluff bodies. The project is on schedule and is now shifting towards the design of an integrated PEM fuel cell system capable of using the coal-derived product. This system includes a membrane clean up unit and a commercially available PEM fuel cell.

  6. Trends in Methanol Decomposition on Transition Metal Alloy Clusters from Scaling and Brønsted–Evans–Polanyi Relationships

    SciTech Connect (OSTI)

    Mehmood, Faisal; Rankin, Rees B.; Greeley, Jeffrey P.; Curtiss, Larry A.

    2012-05-15T23:59:59.000Z

    A combination of ?rst principles Density Functional Theory calculations and thermochemical scaling relationships are employed to estimate the thermochemistry and kinetics of methanol decomposition on unsupported subnanometer metal clusters. The approach uses binding energies of various atomic and molecular species, determined on the pure metal clusters, to develop scaling relationships that are then further used to estimate the methanol decomposition thermodynamics for a series of pure and bimetallic clusters with four atoms per cluster. Additionally, activation energy barriers are estimated from Brønsted–Evans–Polanyi plots relating transition and ?nal state energies on these clusters. The energetic results are combined with a simple, microkineticallyinspired rate expression to estimate reaction rates as a function of important catalytic descriptors, including the carbon and atomic oxygen binding energies to the clusters. Based on these analyses, several alloy clusters are identi?ed as promising candidates for the methanol decomposition reaction.

  7. Mixing it up - Measuring diffusion in supercooled liquid solutions of methanol and ethanol at temperatures near the glass transition

    SciTech Connect (OSTI)

    Matthiesen, Jesper; Smith, R. Scott; Kay, Bruce D.

    2011-03-17T23:59:59.000Z

    Do liquid mixtures, cooled to temperatures below their freezing point, behave as normal liquids? We address this question using nanoscale films of methanol and ethanol supercooled liquid solutions of varying composition (7 -93% methanol) at temperatures near their glass transition,Tg. The permeation of Kr through these films is used to determine the diffusivities of the supercooled liquid mixtures. We find that the temperature dependent diffusivities of the mixtures are well-fit by a Vogel-Fulcher-Tamman equation indicating that the mixtures exhibit fragile behavior at temperatures just above their Tg. Further, for a given temperature, the composition dependent diffusivity is well-fit by a Vignes-type equation, i.e. the diffusivity of any mixture can be predicted using an exponential weighting of the diffusion of the pure methanol and ethanol diffusivities. These results show that deeply supercooled liquid mixtures can be used to provide valuable insight into the properties of normal liquid mixtures.

  8. DISCOVERY OF THE FIRST METHANOL (CH{sub 3}OH) MASER IN THE ANDROMEDA GALAXY (M31)

    SciTech Connect (OSTI)

    Sjouwerman, Lorant O.; Murray, Claire E. [National Radio Astronomy Observatory, P.O. Box 0, Lopezville Rd. 1001, Socorro, NM 87801 (United States); Pihlstroem, Ylva M. [Department of Physics and Astronomy, University of New Mexico, MSC07 4220, Albuquerque, NM 87131 (United States); Fish, Vincent L. [Massachusetts Institute of Technology, Haystack Observatory, Route 40, Westford, MA 01886 (United States); Araya, Esteban D., E-mail: lsjouwer@nrao.ed [Physics Department, Western Illinois University, 1 University Circle, Macomb, IL 61455 (United States)

    2010-12-01T23:59:59.000Z

    We present the first detection of a 6.7 GHz Class II methanol (CH{sub 3}OH) maser in the Andromeda galaxy (M31). The CH{sub 3}OH maser was found in a VLA survey during the fall of 2009. We have confirmed the methanol maser with the new EVLA, in operation since 2010 March, but were unsuccessful in detecting a water maser at this location. A direct application for this methanol maser is the determination of the proper motion of M31, such as was previously obtained with water masers in M33 and IC10. Unraveling the three-dimensional velocity of M31 would solve for the biggest unknown in the modeling of the dynamics and evolution of the Local Group of galaxies.

  9. Simultaneous MS-IR Studies of Surface Formate Reactivity Under Methanol Synthesis Conditions on Cu/SiO2

    SciTech Connect (OSTI)

    Yang, Yong; Mims, Charles A.; Disselkamp, Robert S.; Peden, Charles HF; Campbell, C. T.

    2009-06-09T23:59:59.000Z

    The coverages and surface lifetimes of copper-bound formates on Cu/SiO2 catalysts, and the steady-state rates of reverse water-gas shift and methanol synthesis have been measured simultaneously by mass (MS) and infrared (IR) spectroscopies under a variety of elevated pressure conditions at temperatures between 140 and 160°C. DCOO lifetimes under steady state catalytic conditions in CO2:D2 atmospheres were measured by 12C – 13C isotope transients (SSITKA). The values range from 220s at 160°C to 660s at 140°C. The catalytic rates of both reverse water gas shift (RWGS) and methanol synthesis are ~100-fold slower than this formate removal rate back to CO2+1/2 H2, and thus they do not significantly influence the formate lifetime or coverage at steady state. The formate coverage is instead determined by formate’s rapid production / decomposition equilibrium with gas phase CO2+H2. The results are consistent with formate being an intermediate in methanol synthesis, but with the rate-controlling step being after formate production (for example, its further hydrogenation to methoxy). A 2-3 fold shorter life time (faster decomposition rate) was observed for formate under reactions conditions when both D2 and CO2 are present than in pure Ar or D2+Ar alone, attributed to effects of coadsorbates (produced in D2 and CO2) on adsorbed formate reaction pathways. The carbon which appears in the methanol product spends a longer time on the surface than the formate species, 1.8 times as long at 140°C. The additional delay on the surface is attributed in part to readsorption of methanol on the catalyst, thus obscuring the mechanistic link between formate and methanol.

  10. A 95 GHz CLASS I METHANOL MASER SURVEY TOWARD A SAMPLE OF GLIMPSE POINT SOURCES ASSOCIATED WITH BGPS CLUMPS

    SciTech Connect (OSTI)

    Chen Xi; Gan Conggui; Shen Zhiqiang; An Tao [Key Laboratory for Research in Galaxies and Cosmology, Shanghai Astronomical Observatory, Chinese Academy of Sciences, Shanghai 200030 (China); Ellingsen, Simon P. [School of Mathematics and Physics, University of Tasmania, Hobart, Tasmania (Australia); He Jinhua [National Astronomical Observatories/Yunnan Observatory, Chinese Academy of Sciences, Kunming 650011 (China); Xu Ye; Sun Yan; Ju Binggang, E-mail: chenxi@shao.ac.cn [Purple Mountain Observatory, Chinese Academy of Sciences, Nanjing 210008 (China)

    2012-05-01T23:59:59.000Z

    We report a survey with the Purple Mountain Observatory 13.7 m radio telescope for class I methanol masers from the 95 GHz (8{sub 0}-7{sub 1} A{sup +}) transition. Two hundred and fourteen target sources were selected by combining information from both the Spitzer GLIMPSE and 1.1 mm Bolocam Galactic Plane Survey (BGPS) catalogs. The observed sources satisfy the GLIMPSE mid-IR criteria of [3.6]-[4.5] > 1.3, [3.6]-[5.8] > 2.5, [3.6]-[8.0] > 2.5 and 8.0 {mu}m mag less than 10; they also have an associated 1.1 mm BGPS source. Class I methanol maser emission was detected in 63 sources, corresponding to a detection rate of 29% for this survey. For the majority of detections (43), this is the first identification of class I methanol masers associated with these sources. We show that the intensity of the class I methanol maser emission is not closely related to mid-IR intensity or the colors of the GLIMPSE point sources; however, it is closely correlated with properties (mass and beam-averaged column density) of the BGPS sources. Comparison of measures of star formation activity for the BGPS sources with and without class I methanol masers indicates that the sources with class I methanol masers usually have higher column density and larger flux density than those without them. Our results predict that the criteria log (S{sub int}) {<=} -38.0 + 1.72log (N{sup beam}{sub H{sub 2}}) and log (N{sub H{sub 2}{sup beam}}){>=}22.1, which utilizes both the integrated flux density (S{sub int}) and beam-averaged column density (N{sub H{sub 2}{sup beam}}) of the BGPS sources, are very efficient for selecting sources likely to have an associated class I methanol maser. Our expectation is that searches using these criteria will detect 90% of the predicted number of class I methanol masers from the full BGPS catalog ({approx}1000), and that they will do so with a high detection efficiency ({approx}75%).

  11. Fundamental Studies of Methanol Synthesis from CO2 Hydrogenation on Cu(111), Cu Clusters, and Cu/ZnO(000?)

    SciTech Connect (OSTI)

    Liu, P.; Yang, Y.; Evans, J.; Rodriguez, J.A.; White, M.G.

    2010-06-21T23:59:59.000Z

    A combination of experimental and theoretical methods were employed to investigate the synthesis of methanolvia CO{sub 2}hydrogenation (CO{sub 2} + 3H{sub 2} {yields} CH{sub 3}OH + H{sub 2}O) on Cu(111) and Cunanoparticle surfaces. High pressure reactivity studies show that Cunanoparticles supported on a ZnO(000{bar 1}) single crystal exhibit a higher catalytic activity than the Cu(111) planar surface. Complementary density functional theory (DFT) calculations of methanol synthesis were also performed for a Cu(111) surface and unsupported Cu{sub 29} nanoparticles, and the results support a higher activity for Cu nanoparticles. The DFT calculations show that methanol synthesis on Cu surfaces proceeds through a formate intermediate and the overall reaction rate is limited by both formate and dioxomethylene hydrogenation. Moreover, the superior activity of the nanoparticle is associated with its fluxionality and the presence of low-coordinated Cu sites, which stabilize the key intermediates, e.g. formate and dioxomethylene, and lower the barrier for the rate-limiting hydrogenation process. The reverse water-gas-shift (RWGS) reaction (CO{sub 2} + H{sub 2} {yields} CO + H{sub 2}O) was experimentally observed to compete with methanol synthesis and was also considered in our DFT calculations. In agreement with experiment, the rate of the RWGS reaction on Cu nanoparticles is estimated to be 2 orders of magnitude faster than methanol synthesis at T = 573 K. The experiments and calculations also indicate that CO produced by the fast RWGS reaction does not undergo subsequent hydrogenation to methanol, but instead simply accumulates as a product. Methanol production from CO hydrogenation via the RWGS pathway is hindered by the first hydrogenation of CO to formyl, which is not stable and prefers to dissociate into CO and H atoms on Cu. Our calculated results suggest that the methanol yield over Cu-based catalysts could be improved by adding dopants or promoters which are able to stabilize formyl species or facilitate the hydrogenation of formate and dioxomethylene. the RWGS pathway is hindered by the first hydrogenation of CO to formyl, which is not stable and prefers to dissociate into CO and H atoms on Cu. Our calculated results suggest that the methanol yield over Cu-based catalysts could be improved by adding dopants or promoters which are able to stabilize formyl species or facilitate the hydrogenation of formate and dioxomethylene.

  12. *sja@iet.aau.dkwww.iet.aau.dk Initial experiments with a Pt based heat exchanger methanol reformer for a HTPEM fuel cell system

    E-Print Network [OSTI]

    Andreasen, Søren Juhl

    *sja@iet.aau.dkwww.iet.aau.dk Initial experiments with a Pt based heat exchanger methanol reformer, Pontoppidanstræde 101, 9220 Aalborg East, Denmark Motivation Methanol Reformer Test Conclusions The use of a liquid reformed hydro- carbon as fuel for fuel cells can redu- ce fuel storage volume considerably. The PBI

  13. An Electro-osmotic Fuel Pump for Direct Methanol Fuel Cells C. R. Buie, D. Kim, S. Litster, and J. G. Santiagoz

    E-Print Network [OSTI]

    Santiago, Juan G.

    An Electro-osmotic Fuel Pump for Direct Methanol Fuel Cells C. R. Buie, D. Kim, S. Litster, and J cell DMFC integrated with an electro-osmotic EO pump for methanol delivery. Electro-osmotic pumps, an electro-osmotic pump is realized from a commercially available porous glass frit. We characterize a custom

  14. Resonant ion-dip infrared spectroscopy of benzene(methanol)m clusters R. Nathaniel Pribble, Fredrick C. Hagemeister, and Timothy S. Zwiera)

    E-Print Network [OSTI]

    Zwier, Timothy S.

    Resonant ion-dip infrared spectroscopy of benzene­(methanol)m clusters with m 1­6 R. Nathaniel bonding between benzene and methanol. The m 2 spectrum features two strong transitions at 3506 and 3605 cm in the absence of benzene, is redshifted by 76 cm 1 due to a strengthened hydrogen bond. In benzene­ CH3OH 3

  15. Periodicity in Class II methanol masers in high mass star forming regions

    E-Print Network [OSTI]

    Goedhart, S; Gaylard, M J; van der Walt, D J

    2013-01-01T23:59:59.000Z

    We report the results of 10 years of monitoring of six regularly varying 6.7 GHz methanol masers using the Hartebeesthoek 26m telescope. Observations were done at intervals of 1--2 weeks, with faster sampling during flaring episodes. Four of the sources were also monitored at 12.2 GHz and show correlated variations. We find the Lomb-Scargle periodogram to be the most sensitive method to search for periodicity but possibly prone to false detections. Periods range from 132.8 days (with 26 cycles observed) to 509 days (with 7 cycles observed). Five of the sources show arguably periodic variations, while G331.13-0.24 shows strong periodicity in one peak, with large and variable delays in other peaks.

  16. Gas phase synthesis of MTBE from methanol and isobutene over dealuminated zeolites

    SciTech Connect (OSTI)

    Collignon, F.; Mariani, M.; Moreno, S.; Remy, M.; Poncelet, G. [Universite Catholique de Louvain (Belgium)] [Universite Catholique de Louvain (Belgium)

    1997-02-01T23:59:59.000Z

    Gas phase synthesis of MTBE from methanol and isobutene has been investigated over different zeolites. It is shown that bulk Si/Al ratio has a marked influence on the formation of MTBE. H-beta zeolite was found to be as active as acid Amberlyst-15 (reference catalyst), and noticeably superior to non- and dealuminated forms of H-Y, H-ZSM-5, zeolite omega, and H-mordenites. Screening test results obtained over other catalysts (SAPOs and pillared clays) are briefly commented. The contribution of the external surface of the zeolites to the reaction is discussed. In the case of H-Y zeolites, it is shown that extra framework Al species ({sup 27}Al NMR signal at 30 ppm) have a detrimental effect on the reaction. 64 refs., 12 figs., 3 tabs.

  17. New processes to recovery methanol and remove oxygenates from Valero MTBE unit

    SciTech Connect (OSTI)

    Hillen, P.; Clemmons, J.

    1987-01-01T23:59:59.000Z

    The refiner today has to evaluate every available option to increase octane in the gasoline pool to make up for the loss in octane created by lead phase down. Production of MTBE is one of the most attractive options. MTBE is produced by selectivity reacting isobutylene with methanol. Valero Refining's refinery at Corpus Christie, Texas (formerly Saber Refining) is one of the most modern refineries built in the last decade to upgrade resids. As part of the gasoline upgrading Valero had built a Butamer Unit to convert normal butane to isobutane upstream of their HF Alkylation Unit. In 1984 as an ongoing optimization of its operations, Valero Refining evaluated various processes to enable it to increase the octane output, and decided to build an MTBE unit. Valero selected the MTBE process licensed by Arco Technology, Inc. and contracted with Jacobs Engineering Group, Inc., Houston, Texas to provide detailed engineering and procurement services.

  18. Catalyst inks and method of application for direct methanol fuel cells

    DOE Patents [OSTI]

    Zelenay, Piotr (Los Alamos, NM); Davey, John (Los Alamos, NM); Ren, Xiaoming (Los Alamos, NM); Gottesfeld, Shimshon (Los Alamos, NM); Thomas, Sharon C. (Vancouver, CA)

    2004-02-24T23:59:59.000Z

    Inks are formulated for forming anode and cathode catalyst layers and applied to anode and cathode sides of a membrane for a direct methanol fuel cell. The inks comprise a Pt catalyst for the cathode and a Pt--Ru catalyst for the anode, purified water in an amount 4 to 20 times that of the catalyst by weight, and a perfluorosulfonic acid ionomer in an amount effective to provide an ionomer content in the anode and cathode surfaces of 20% to 80% by volume. The inks are prepared in a two-step process while cooling and agitating the solutions. The final solution is placed in a cooler and continuously agitated while spraying the solution over the anode or cathode surface of the membrane as determined by the catalyst content.

  19. Commercial-Scale Demonstration of the Liquid Phase Methanol (LPMEOH(TM)) Process

    SciTech Connect (OSTI)

    None

    1997-06-30T23:59:59.000Z

    The Liquid Phase Methanol (LPMEOHTM) Demonstration Project at Kingsport, Tennessee, is a $213.7 million cooperative agreement between the U.S. Department of Energy (DOE) and Air Products Liquid Phase Conversion Company, L.P. (the Partnership). Air Products and Chemicals, Inc. (Air Products) and Eastman Chemical Company (Eastman) formed the Partnership to execute the Demonstration Project. The LPMEOIYM Process Demonstration Unit was built at a site located at the Eastman complex in Kingsport. During this quarter, comments from the DOE on the Topical Report "Economic Analysis - LPMEOHTM Process as an Add-on to IGCC for Coproduction" were received. A recommendation to continue with design verification testing for the coproduction of dimethyl ether (DIME) and methanol was made. DME design verification testing studies show the liquid phase DME (LPDME) process will have a significant economic advantage for the coproduction of DME for local markets. An LPDME catalyst system with reasonable long-term activity and stability is being developed. A recommendation document summarizing catalyst targets, experimental results, and the corresponding economics for a commercially successful LPDME catalyst was issued on 30 June 1997. The off-site, product-use test plan was updated in June of 1997. During this quarter, Acurex Environmental Corporation and Air Products screened proposals for this task by the likelihood of the projects to proceed and the timing for the initial methanol requirement. Eight sites from the list have met these criteria. The formal submission of the eight projects for review and concurrence by the DOE will be made during the next reporting period. The site paving and final painting were completed in May of 1997. Start-up activities were completed during the reporting period, and the initial methanol production from the demonstration unit occurred on 02 April 1997. The first extended stable operation at the nameplate capacity of 80,000 gallons per day (260 tons per day) took place on 06 April 1997. Pressure drop and resistance coefficient across the gas sparger at the bottom of the reactor increased over this initial operating period. The demonstration unit was shut down from 08 May -17 June 1997 as part of a scheduled complex outage for the Kingsport site. During this outage, the gas sparger was removed, cleaned, and reinstalled. After completion of other maintenance activities, the demonstration unit was restarted, and maintained stable operation through the remainder of the reporting period. Again, the gas sparger showed an increase in pressure drop and resistance since the restart, although not as rapidly as during the April-May operation. Fresh oil was introduced online for the first time to a new flush connection on the gas inlet line to the reactov the flush lowered the pressure drop by 1 psi. However, the effects were temporary, and the sparger resistance coefficient continued to increase. Additional flushing with both fresh oil and entrained slurry recovered in the cyclone and secondary oil knock-out drum will be attempted in order to stabilize the sparger resistance coefficient.

  20. Methanol as a Sensitive Probe for Spatial and Temporal Variations of the Proton-to-Electron Mass Ratio

    SciTech Connect (OSTI)

    Jansen, Paul; Ubachs, Wim; Bethlem, Hendrick L. [Institute for Lasers, Life and Biophotonics, VU University Amsterdam, De Boelelaan 1081, 1081 HV Amsterdam (Netherlands); Xu Lihong [Department of Physics and Centre for Laser, Atomic, and Molecular Sciences, University of New Brunswick, Saint John, New Brunswick E2L 4L5 (Canada); Kleiner, Isabelle [Laboratoire Interuniversitaire des Systemes Atmospheriques (LISA), CNRS UMR 7583 et Universites Paris 7 et Paris Est, 61 avenue du General de Gaulle, 94010 Creteil Cedex (France)

    2011-03-11T23:59:59.000Z

    The 6.7 and 12.2 GHz masers, corresponding to the 5{sub 1}{yields}6{sub 0}A{sup +} and 2{sub 0}{yields}3{sub -1}E transitions in methanol (CH{sub 3}OH), respectively, are among the brightest radio objects in the sky. We present calculations for the sensitivity of these and other transitions in the ground state of methanol to a variation of the proton-to-electron mass ratio. We show that the sensitivity is greatly enhanced due to a cancellation of energies associated with the hindered internal rotation and the overall rotation of the molecule. We find sensitivities of K{sub {mu}=}-42 and K{sub {mu}=}-33, for the 5{sub 1}{yields}6{sub 0}A{sup +} and 2{sub 0}{yields}3{sub -1}E transitions, respectively. The sensitivities of other transitions in the different isotopologues of methanol range from -88 to 330. This makes methanol a sensitive probe for spatial and temporal variations of the proton-to-electron mass ratio.

  1. A MERLIN Study of 6 GHz Excited-state OH & 6.7 GHz Methanol Masers in ON1

    E-Print Network [OSTI]

    J. A. Green; A. M. S. Richards; W. H. T. Vlemmings; P. Diamond; R. J. Cohen

    2007-09-05T23:59:59.000Z

    MERLIN observations of 6.668-GHz methanol and both 6.031- and 6.035-GHz hydroxyl (OH) emission from the massive star-formation region ON1 are presented. These are the first methanol observations made in full polarization using 5 antennas of MERLIN, giving high resolution and sensitivity to extended emission. Maser features are found to lie at the southern edge of the ultra-compact HII region, following the known distribution of ground-state OH masers. The masers cover a region ~1 arcsec in extent, lying perpendicular to the H13CO+ bipolar outflow. Excited-state OH emission demonstrates consistent polarization angles across the strongest linearly polarized features which are parallel to the overall distribution. The linear polarizations vary between 10.0 and 18.5 per cent, with an average polarization angle of -60 deg +/- 28 deg. The strongest 6.668-GHz methanol features provide an upper limit to linear polarization of ~1 per cent. Zeeman splitting of OH shows magnetic fields between -1.1 to -5.8 mG, and a tentative methanol magnetic field strength of -18 mG is measured.

  2. Design and Control of High Temperature PEM Fuel Cell Systems using Methanol Reformers with Air or Liquid Heat Integration

    E-Print Network [OSTI]

    Berning, Torsten

    of burner temperature and the aspects of implementing advanced modeling based control approaches using], auxiliary and uninterruptible power systems [13, 14, 15, 16, 17, 18, 19]. Polymer electrolyte membrane fuelDesign and Control of High Temperature PEM Fuel Cell Systems using Methanol Reformers with Air

  3. Corrosion, Passivation, and the Effect of Water Addition on an n-GaAs(100)/Methanol Photoelectrochemical Cell

    E-Print Network [OSTI]

    Richmond, Geraldine L.

    Corrosion, Passivation, and the Effect of Water Addition on an n-GaAs(100)/Methanol of corrosion of the cell on the PL-V profile is examined in detail. It is found that the inclusion of the redox couple gives some protection from corrosion, but the addition of a small amount of water

  4. Liquid-liquid equilibria of water + methanol + 1-octanol and water + ethanol + 1-octanol at various temperatures

    SciTech Connect (OSTI)

    Arce, A.; Blanco, A.; Souza, P.; Vidal, I. (Univ. of Santiago de Compostela (Spain). Dept. of Chemical Engineering)

    1994-04-01T23:59:59.000Z

    This study is part of a wider program of research on the recovery of light alcohols from dilute aqueous solutions using high molecular weight solvents. The authors report liquid-liquid equilibrium data and binodal curves for the systems water + methanol + 1-octanol and water + ethanol + 1-octanol at 25, 35, and 45 C. The data were fitted to the NRTL and UNIQUAC equations.

  5. Refractive indices, densities, and excess properties for binary mixtures containing methanol, ethanol, 1,2-ethanediol, and 2-methoxyethanol

    SciTech Connect (OSTI)

    Albuquerque, L.; Ventura, C.; Goncalves, R. [Univ. of Lisbon, Lisboa (Portugal). Dept. of Chemistry] [Univ. of Lisbon, Lisboa (Portugal). Dept. of Chemistry

    1996-07-01T23:59:59.000Z

    Measurements of refractive index and density were performed for the six binary solvent mixtures containing methanol, ethanol, 1,2-ethanediol, and 2-methoxyethanol, over the entire composition range, at 298.15 K. From these results, the excess refractive indices and the excess molar volumes were calculated and fitted to the Redlich-Kister equation.

  6. A comparative density functional study of methanol decomposition on Cu{sub 4} and Co{sub 4} clusters.

    SciTech Connect (OSTI)

    Mehmood, F.; Greeley, J.; Zapol, P.; Curtiss, L. A.

    2010-08-12T23:59:59.000Z

    A density functional theory study of the decomposition of methanol on Cu{sub 4} and Co{sub 4} clusters is presented. The reaction intermediates and activation barriers have been determined for reaction steps to form H{sub 2} and CO. For both clusters, methanol decomposition initiated by C-H and O-H bond breaking was investigated. In the case of a Cu{sub 4} cluster, methanol dehydrogenation through hydroxymethyl (CH{sub 2}OH), hydroxymethylene (CHOH), formyl (CHO), and carbon monoxide (CO) is found to be slightly more favorable. For a Co{sub 4} cluster, the dehydrogenation pathway through methoxy (CH{sub 3}O) and formaldehyde (CH{sub 2}O) is slightly more favorable. Each of these pathways results in formation of CO and H{sub 2}. The Co cluster pathway is very favorable thermodynamically and kinetically for dehydrogenation. However, since CO binds strongly, it is likely to poison methanol decomposition to H{sub 2} and CO at low temperatures. In contrast, for the Cu cluster, CO poisoning is not likely to be a problem since it does not bind strongly, but the dehydrogenation steps are not energetically favorable. Pathways involving C-O bond cleavage are even less energetically favorable. The results are compared to our previous study of methanol decomposition on Pd{sub 4} and Pd{sub 8} clusters. Finally, all reaction energy changes and transition state energies, including those for the Pd clusters, are related in a linear, Broensted?Evans?Polanyi plot.

  7. Mid-Infrared Observations of Methanol Masers and Massive Star Forming Regions A. J. Walsh 1;2 , F. Bertoldi 1 , M. G. Burton 2 and T. Nikola 2;3

    E-Print Network [OSTI]

    Burton, Michael

    Mid-Infrared Observations of Methanol Masers and Massive Star Forming Regions A. J. Walsh 1;2 , F methanol masers and massive star forma- tion, Walsh et al. (1997, MNRAS, 291, 261; 1998 MNRAS, 301, 640; 1999, MNRAS, in preparation) surveyed 276 IRAS sources for 6.7 GHz methanol maser and 6.7 GHz and 8

  8. Mon. Not. R. Astron. Soc. 000, 000--000 (0000) Printed 18 March 1997 (MN L a T E X style file v1.3) Studies of Ultracompact HII Regions I. Methanol Maser

    E-Print Network [OSTI]

    Burton, Michael

    .3) Studies of Ultracompact HII Regions ­ I. Methanol Maser Survey of IRAS Selected Sources A. J. Walsh, 1 A for 6.669GHz methanol maser emission from a sample of 535 IRAS selected candidates. A total of 201 candidates exhibit methanol emission. These sources have been used, in conjunction with previously identified

  9. MODELLING A CIRCUMSTELLAR DISC TRACED BY METHANOL MASERS. M. R. Pestalozzi, School of Physics, Astronomy and Mathematics, Univ. of Hertfordshire, AL9 10AB Hatfield, UK (michele@star.herts.ac.uk), M. Elitzur, Univ. of

    E-Print Network [OSTI]

    De Buizer, James Michael

    MODELLING A CIRCUMSTELLAR DISC TRACED BY METHANOL MASERS. M. R. Pestalozzi, School of Physics-Planck Institut f¨ur Radioastronomie, Bonn, Germany. We present the accurate modelling of one methanol maser in which many methanol masers have been detected and mark different objects (see Poster by V. Minier et al

  10. Single-Step Syngas-to-Distillates (S2D) Synthesis via Methanol and Dimethyl Ether Intermediates: Final Report

    SciTech Connect (OSTI)

    Dagle, Robert A.; Lebarbier, Vanessa MC; Lizarazo Adarme, Jair A.; King, David L.; Zhu, Yunhua; Gray, Michel J.; Jones, Susanne B.; Biddy, Mary J.; Hallen, Richard T.; Wang, Yong; White, James F.; Holladay, Johnathan E.; Palo, Daniel R.

    2013-11-26T23:59:59.000Z

    The objective of the work was to enhance price-competitive, synthesis gas (syngas)-based production of transportation fuels that are directly compatible with the existing vehicle fleet (i.e., vehicles fueled by gasoline, diesel, jet fuel, etc.). To accomplish this, modifications to the traditional methanol-to-gasoline (MTG) process were investigated. In this study, we investigated direct conversion of syngas to distillates using methanol and dimethyl ether intermediates. For this application, a Pd/ZnO/Al2O3 (PdZnAl) catalyst previously developed for methanol steam reforming was evaluated. The PdZnAl catalyst was shown to be far superior to a conventional copper-based methanol catalyst when operated at relatively high temperatures (i.e., >300°C), which is necessary for MTG-type applications. Catalytic performance was evaluated through parametric studies. Process conditions such as temperature, pressure, gas-hour-space velocity, and syngas feed ratio (i.e., hydrogen:carbon monoxide) were investigated. PdZnAl catalyst formulation also was optimized to maximize conversion and selectivity to methanol and dimethyl ether while suppressing methane formation. Thus, a PdZn/Al2O3 catalyst optimized for methanol and dimethyl ether formation was developed through combined catalytic material and process parameter exploration. However, even after compositional optimization, a significant amount of undesirable carbon dioxide was produced (formed via the water-gas-shift reaction), and some degree of methane formation could not be completely avoided. Pd/ZnO/Al2O3 used in combination with ZSM-5 was investigated for direct syngas-to-distillates conversion. High conversion was achieved as thermodynamic constraints are alleviated when methanol and dimethyl are intermediates for hydrocarbon formation. When methanol and/or dimethyl ether are products formed separately, equilibrium restrictions occur. Thermodynamic relaxation also enables the use of lower operating pressures than what would be allowed for methanol synthesis alone. Aromatic-rich hydrocarbon liquid (C5+), containing a significant amount of methylated benzenes, was produced under these conditions. However, selectivity control to liquid hydrocarbons was difficult to achieve. Carbon dioxide and methane formation was problematic. Furthermore, saturation of the olefinic intermediates formed in the zeolite, and necessary for gasoline production, occurred over PdZnAl. Thus, yield to desirable hydrocarbon liquid product was limited. Evaluation of other oxygenate-producing catalysts could possibly lead to future advances. Potential exists with discovery of other types of catalysts that suppress carbon dioxide and light hydrocarbon formation. Comparative techno-economics for a single-step syngas-to-distillates process and a more conventional MTG-type process were investigated. Results suggest operating and capital cost savings could only modestly be achieved, given future improvements to catalyst performance. Sensitivity analysis indicated that increased single-pass yield to hydrocarbon liquid is a primary need for this process to achieve cost competiveness.

  11. WABASH RIVER INTEGRATED METHANOL AND POWER PRODUCTION FROM CLEAN COAL TECHNOLOGIES (IMPPCCT)

    SciTech Connect (OSTI)

    Doug Strickland; Albert Tsang

    2002-10-14T23:59:59.000Z

    The Wabash River Integrated Methanol and Power Production from Clean Coal Technologies (IMPPCCT) project is evaluating integrated electrical power generation and methanol production through clean coal technologies. The project is conducted by a multi-industry team lead by Gasification Engineering Corporation (GEC), and supported by Air Products and Chemicals, Inc., Dow Chemical Company, Dow Corning Corporation, Methanex Corporation, and Siemens Westinghouse Power Corporation. Three project phases are planned for execution over a three year period, including: (1) Feasibility study and conceptual design for an integrated demonstration facility, and for fence-line commercial plants operated at Dow Chemical or Dow Corning chemical plant locations; (2) Research, development, and testing to define any technology gaps or critical design and integration issues; and (3) Engineering design and financing plan to install an integrated commercial demonstration facility at the existing Wabash River Energy Limited (WREL) plant in West Terre Haute, Indiana. This report describes management planning, work breakdown structure development, and feasibility study activities by the IMPPCCT consortium in support of the first project phase. Project planning activities have been completed, and a project timeline and task list has been generated. Requirements for an economic model to evaluate the West Terre Haute implementation and for other commercial implementations are being defined. Specifications for methanol product and availability of local feedstocks for potential commercial embodiment plant sites have been defined. The WREL facility is a project selected and co-funded under the fifth phase solicitation of the U.S. Department of Energy's Clean Coal Technology Program. In this project, coal and/or other solid fuel feedstocks are gasified in an oxygen-blown, entrained-flow gasifier with continuous slag removal and a dry particulate removal system. The resulting product synthesis gas is used to fuel a combustion turbine generator whose exhaust is integrated with a heat recovery steam generator to drive a refurbished steam turbine generator. The gasifier uses technology initially developed by The Dow Chemical Company (the Destec Gasification Process), and now offered commercially by Global Energy, Inc., as the E-GAS{trademark} technology. In a joint effort with the U.S. Department of Energy, working under a Cooperative Agreement Award from the ''Early Entrance Coproduction Plant'' (EECP) initiative, the GEC and an Industrial Consortia are investigating the application of synthesis gas from the E-GAS{trademark} technology to a coproduction environment to enhance the efficiency and productivity of solid fuel gasification combined cycle power plants. The objectives of this effort are to determine the feasibility of an EECP located at a specific site which produces some combination of electric power (or heat), fuels, and/or chemicals from synthesis gas derived from coal, or, coal in combination with some other carbonaceous feedstock. The project's intended result is to provide the necessary technical, economic, and environmental information that will be needed to move the EECP forward to detailed design, construction, and operation by industry.

  12. WABASH RIVER INTEGRATED METHANOL AND POWER PRODUCTION FROM CLEAN COAL TECHNOLOGIES (IMPPCCT)

    SciTech Connect (OSTI)

    Albert Tsang

    2003-03-14T23:59:59.000Z

    The Wabash River Integrated Methanol and Power Production from Clean Coal Technologies (IMPPCCT) project is evaluating integrated electrical power generation and methanol production through clean coal technologies. The project is conducted by a multi-industry team lead by Gasification Engineering Corporation (GEC), and supported by Air Products and Chemicals, Inc., Dow Chemical Company, Dow Corning Corporation, Methanex Corporation, and Siemens Westinghouse Power Corporation. Three project phases are planned for execution, including: (1) Feasibility study and conceptual design for an integrated demonstration facility, and for fence-line commercial embodiment plants (CEP) operated at Dow Chemical or Dow Corning chemical plant locations (2) Research, development, and testing (RD&T) to define any technology gaps or critical design and integration issues (3) Engineering design and financing plan to install an integrated commercial demonstration facility at the existing Wabash River Energy Limited (WREL) plant in West Terre Haute, Indiana. The WREL facility is a project selected and co-funded under the Round IV of the United States Department of Energy's (DOE's) Clean Coal Technology Program. In this project, coal and/or other solid fuel feedstocks are gasified in an oxygen-blown, entrained-flow gasifier with continuous slag removal and a dry particulate removal system. The resulting product synthesis gas is used to fuel a combustion turbine generator whose exhaust is integrated with a heat recovery steam generator to drive a refurbished steam turbine generator. The gasifier uses technology initially developed by The Dow Chemical Company (the Destec Gasification Process), and now offered commercially by Global Energy, Inc., parent company of GEC and WREL, as the E-GAS{trademark} technology. In a joint effort with the DOE, a Cooperative Agreement was awarded under the Early Entrance Coproduction Plant (EECP) solicitation. GEC and an Industrial Consortium are investigating the use of synthesis gas produced by the E-GAS{trademark} technology in a coproduction environment to enhance the efficiency and productivity of solid fuel gasification combined cycle power plants. The objectives of this effort are to determine the feasibility of an EECP located at a specific site which produces some combination of electric power (or heat), fuels, and/or chemicals from synthesis gas derived from coal, or, coal in combination with some other carbonaceous feedstock. The project's intended result is to provide the necessary technical, economic, and environmental information that will be needed to move the EECP forward to detailed design, construction, and operation by industry. During the reporting period, effort continues on identifying potential technologies for removing contaminants from synthesis gas to the level required by methanol synthesis. A liquid phase Claus process and a direct sulfur oxidation process were evaluated. Preliminary discussion was held with interested parties on cooperating on RD&T in Phase II of the project. Also, significant progress was made during the period in the submission of project deliverables. A meeting was held at DOE's National Energy Technology Laboratory in Morgantown between GEC and the DOE IMPPCCT Project Manager on the status of the project, and reached an agreement on the best way to wrap up Phase I and transition into the Phase II RD&T. Potential projects for the Phase II, cost, and fund availability were also discussed.

  13. A role for glutathione, independent of oxidative stress, in the developmental toxicity of methanol

    SciTech Connect (OSTI)

    Siu, Michelle T.; Shapiro, Aaron M. [Division of Biomolecular Sciences, Faculty of Pharmacy, University of Toronto, Toronto, Ontario (Canada); Wiley, Michael J. [Division of Anatomy, Faculty of Medicine, University of Toronto, Toronto, Ontario (Canada); Wells, Peter G., E-mail: pg.wells@utoronto.ca [Division of Biomolecular Sciences, Faculty of Pharmacy, University of Toronto, Toronto, Ontario (Canada); Department of Pharmacology and Toxicology, Faculty of Medicine, University of Toronto, Toronto, Ontario (Canada)

    2013-12-15T23:59:59.000Z

    Oxidative stress and reactive oxygen species (ROS) have been implicated in the teratogenicity of methanol (MeOH) in rodents, both in vivo and in embryo culture. We explored the ROS hypothesis further in vivo in pregnant C57BL/6J mice. Following maternal treatment with a teratogenic dose of MeOH, 4 g/kg via intraperitoneal (ip) injection on gestational day (GD) 12, there was no increase 6 h later in embryonic ROS formation, measured by 2?,7?-dichlorodihydrofluorescin diacetate (DCFH-DA) fluorescence, despite an increase observed with the positive control ethanol (EtOH), nor was there an increase in embryonic oxidatively damaged DNA, quantified as 8-oxo-2?-deoxyguanosine (8-oxodG) formation. MeOH teratogenicity (primarily ophthalmic anomalies, cleft palate) also was not altered by pre- and post-treatment with varying doses of the free radical spin trapping agent alpha-phenyl-N-tert-butylnitrone (PBN). In contrast, pretreatment with L-buthionine-(S,R)-sulfoximine (BSO), an inhibitor of glutathione (GSH) synthesis, depleted maternal hepatic and embryonic GSH, and enhanced some new anomalies (micrognathia, agnathia, short snout, fused digits, cleft lip, low set ears), but not the most common teratogenic effects of MeOH (ophthalmic anomalies, cleft palate) in this strain. These results suggest that ROS did not contribute to the teratogenic effects of MeOH in this in vivo mouse model, in contrast to results in embryo culture from our laboratory, and that the protective effect of GSH in this model may arise from its role as a cofactor for formaldehyde dehydrogenase in the detoxification of formaldehyde. - Highlights: • In vivo, a free radical scavenger did not block methanol (MeOH) teratogenesis. • MeOH did not increase embryonic reactive oxygen species formation or DNA oxidation. • MeOH teratogenesis was enhanced by glutathione (GSH) depletion. • GSH may protect as the cofactor for formaldehyde dehydrogenase (ADH3). • Formaldehyde may be a ROS-independent proximate teratogenic species in vivo.

  14. WABASH RIVER INTEGRATED METHANOL AND POWER PRODUCTION FROM CLEAN COAL TECHNOLOGIES (IMPPCCT)

    SciTech Connect (OSTI)

    Thomas Lynch

    2004-01-07T23:59:59.000Z

    The Wabash River Integrated Methanol and Power Production from Clean Coal Technologies (IMPPCCT) project is evaluating integrated electrical power generation and methanol production through clean coal technologies. The project is conducted by a multi-industry team lead previously by Gasification Engineering Corporation (GEC). The project is now under the leadership of ConocoPhillips Company (COP) after it acquired GEC and the E-Gas{trademark} gasification technology from Global Energy in July 2003. The Phase I of this project was supported by Air Products and Chemicals, Inc., Dow Chemical Company, Dow Corning Corporation, Methanex Corporation, and Siemens Westinghouse Power Corporation, while the Phase II is supported by Gas Technology Institute, TDA Research, Inc., and Nucon International, Inc. The two project phases planned for execution include: (1) Feasibility study and conceptual design for an integrated demonstration facility at Global Energy's existing Wabash River Energy Limited (WREL) plant in West Terre Haute, Indiana, and for a fence-line commercial embodiment plants (CEP) operated at Dow Chemical or Dow Corning chemical plant locations (2) Research, development, and testing (RD&T) to define any technology gaps or critical design and integration issues. The WREL facility was designed, constructed, and operated under a project selected and co-funded under the Round IV of the United States Department of Energy's (DOE's) Clean Coal Technology Program. In this project, coal and/or other solid fuel feedstocks are gasified in an oxygen-blown, entrained-flow gasifier with continuous slag removal and a dry particulate removal system. The resulting product synthesis gas is used to fuel a combustion turbine generator whose exhaust is integrated with a heat recovery steam generator to drive a refurbished steam turbine generator. The gasifier uses technology initially developed by The Dow Chemical Company (the Destec Gasification Process), and now acquired and offered commercially by COP as the E-GAS{trademark} technology. In a joint effort with the DOE, a Cooperative Agreement was awarded under the Early Entrance Coproduction Plant (EECP) solicitation. GEC, and now COP and the industrial partners are investigating the use of synthesis gas produced by the E-GAS{trademark} technology in a coproduction environment to enhance the efficiency and productivity of solid fuel gasification combined cycle power plants. The objectives of this effort are to determine the feasibility of an EECP located at a specific site which produces some combination of electric power (or heat), fuels, and/or chemicals from synthesis gas derived from coal, or, coal in combination with some other carbonaceous feedstock. The project's intended result is to provide the necessary technical, economic, and environmental information that will be needed to move the EECP forward to detailed design, construction, and operation by industry.

  15. WABASH RIVER INTEGRATED METHANOL AND POWER PRODUCTION FROM CLEAN COAL TECHNOLOGIES (IMPPCCT)

    SciTech Connect (OSTI)

    Gary Harmond; Albert Tsang

    2003-03-14T23:59:59.000Z

    The Wabash River Integrated Methanol and Power Production from Clean Coal Technologies (IMPPCCT) project is evaluating integrated electrical power generation and methanol production through clean coal technologies. The project is conducted by a multi-industry team lead by Gasification Engineering Corporation (GEC), a company of Global Energy Inc., and supported by Air Products and Chemicals, Inc., Dow Chemical Company, Dow Corning Corporation, Methanex Corporation, and Siemens Westinghouse Power Corporation. Three project phases are planned for execution over a three year period, including: (1) Feasibility study and conceptual design for an integrated demonstration facility, and for fence-line commercial embodiment plants (CEP) operated at Dow Chemical or Dow Corning chemical plant locations (2) Research, development, and testing to define any technology gaps or critical design and integration issues (3) Engineering design and financing plan to install an integrated commercial demonstration facility at the existing Wabash River Energy Limited (WREL) plant in West Terre Haute, Indiana. The WREL facility is a project selected and co-funded under the Round IV of the U.S. Department of Energy's (DOE's) Clean Coal Technology Program. In this project, coal and/or other solid fuel feedstocks are gasified in an oxygen-blown, entrained-flow gasifier with continuous slag removal and a dry particulate removal system. The resulting product synthesis gas is used to fuel a combustion turbine generator whose exhaust is integrated with a heat recovery steam generator to drive a refurbished steam turbine generator. The gasifier uses technology initially developed by The Dow Chemical Company (the Destec Gasification Process), and now offered commercially by Global Energy, Inc., as the E-GAS{trademark} technology. In a joint effort with the DOE, a Cooperative Agreement was awarded under the Early Entrance Coproduction Plant (EECP) solicitation. GEC and an Industrial Consortium are investigating the use of synthesis gas produced by the E-GAS{trademark} technology in a coproduction environment to enhance the efficiency and productivity of solid fuel gasification combined cycle power plants. During the reporting period, various methods to remove low-level contaminants for the synthesis gas were reviewed. In addition, there was a transition of the project personnel for GEC which has slowed the production of the outstanding project reports.

  16. Synthesis of Pt{sub 3}Sn alloy nanoparticles and their catalysis for electro-oxidation of CO and methanol.

    SciTech Connect (OSTI)

    Liu, Y.; Li, D.; Stamenkovic, V. R.; Soled, S.; Henao, J. D.; Sun, S. (Materials Science Division); (Brown Univ.); (Exxon Mobil Res. Eng. Co.)

    2011-11-04T23:59:59.000Z

    Monodisperse Pt{sub 3}Sn alloy nanoparticles (NPs) were synthesized by a controlled coreduction of Pt(II) acetylacetonate and Sn(II) acetylacetonate at 180-280 C in 1-octadecene. In the synthesis, oleylamine was used as a reducing agent, and oleylamine/oleic acid served as surfactants. The sizes of the Pt{sub 3}Sn NPs were tuned from 4 to 7 nm by controlling the metal salt injection temperatures from 180 to 240 C. These monodisperse Pt3Sn NPs were highly active for CO and methanol oxidation in 0.1 M HClO{sub 4} solutions, and their activity and stability could be further improved by a postsynthesis thermal treatment at 400 C in Ar + 5% H{sub 2} for 1 h. They are promising as a practical catalyst for CO and methanol oxidation reactions in polymer electrolyte membrane fuel cell conditions.

  17. Communication: Towards the binding energy and vibrational red shift of the simplest organic hydrogen bond: Harmonic constraints for methanol dimer

    SciTech Connect (OSTI)

    Heger, Matthias; Suhm, Martin A.; Mata, Ricardo A., E-mail: rmata@gwdg.de [Georg-August-Universität Göttingen, Institut für Physikalische Chemie, Tammannstr. 6, 37077 Göttingen (Germany)

    2014-09-14T23:59:59.000Z

    The discrepancy between experimental and harmonically predicted shifts of the OH stretching fundamental of methanol upon hydrogen bonding to a second methanol unit is too large to be blamed mostly on diagonal and off-diagonal anharmonicity corrections. It is shown that a decisive contribution comes from post-MP2 electron correlation effects, which appear not to be captured by any of the popular density functionals. We also identify that the major deficiency is in the description of the donor OH bond. Together with estimates for the electronic and harmonically zero-point corrected dimer binding energies, this work provides essential constraints for a quantitative description of this simple hydrogen bond. The spectroscopic dissociation energy is predicted to be larger than 18 kJ/mol and the harmonic OH-stretching fundamental shifts by about ?121 cm{sup ?1} upon dimerization, somewhat more than in the anharmonic experiment (?111 cm{sup ?1})

  18. Pressure dependence of diffusion coefficient and orientational relaxation time for acetonitrile and methanol in water: DRISM/mode-coupling study

    E-Print Network [OSTI]

    Kobryn, A E; Hirata, F

    2005-01-01T23:59:59.000Z

    We present results of theoretical description and numerical calculation of the dynamics of molecular liquids based on the Reference Interaction Site Model / Mode-Coupling Theory. They include the temperature-pressure(density) dependence of the translational diffusion coefficients and orientational relaxation times for acetonitrile and methanol in water at infinite dilution. Anomalous behavior, i.e. the increase in mobility with density, is observed for the orientational relaxation time of methanol, while acetonitrile does not show any deviations from the usual. This effect is in qualitative agreement with the recent data of MD simulation and with experimental measurements, which tells us that presented theory is a good candidate to explain such kind of anomalies from the microscopical point of view and with the connection to the structure of the molecules.

  19. Methanol Fractionation of Softwood Kraft Lignin: Impact on the Lignin Properties

    SciTech Connect (OSTI)

    Saito, Tomonori [ORNL] [ORNL; Perkins, Joshua H [ORNL] [ORNL; Vautard, Frederic [ORNL] [ORNL; Meyer III, Harry M [ORNL] [ORNL; Messman, Jamie M [ORNL] [ORNL; Tolnai, Balazs [ORNL] [ORNL; Naskar, Amit K [ORNL] [ORNL

    2014-01-01T23:59:59.000Z

    The development of technologies to tune lignin properties for high-performance lignin-based materials is crucial for the utilization of lignin in various applications. Here, the effect of methanol (MeOH) fractionation on the molecular weight, molecular weight distribution, glass transition temperature (Tg), thermal decomposition, and chemical structure of lignin were investigated. Repeated MeOH fractionation of softwood Kraft lignin successfully removed the low-molecular-weight fraction. The separated high-molecular-weight lignin showed a Tg of 211 C and a char yield of 47%, much higher than those of asreceived lignin (Tg 153 C, char yield 41%). The MeOH-soluble fraction of lignin showed an increased low-molecular-weight fraction and a lower Tg (117 C) and char yield (32%). The amount of low-molecular-weight fraction showed a quantitative correlation with both 1/Tg and char yield in a linear regression. This study demonstrated the efficient purification or fractionation technology for lignin; it also established a theoretical and empirical correlation between the physical characteristics of fractionated lignins.

  20. Commercial-Scale Demonstration of the Liquid Phase Methanol (LPMEOH(TM)) Process

    SciTech Connect (OSTI)

    None

    1997-09-30T23:59:59.000Z

    The Liquid Phase Methanol (LPMEOH) Demonstration Project at Kingsport, Tennessee, is a $213.7 million cooperative agreement between the U.S. Department of Energy (DOE) and Air Products Liquid Phase Conversion Company, L.P. (the Partnership). Ak Products and Chemicals, Inc. (Air Products) and Eastman Chemical Company (Eastman) formed the Partnership to execute the Demonstration Project. The LPMEOITM Process Demonstration Unit was built at a site located at the Eastman complex in Kingsport. During this reporting period, DOE accepted the recommendation to continue with dimethyl ether (DME) design verification testing (DVT). DME design verification testing studies show the liquid phase DME (LPDME) process will have a significant economic advantage for the coproduction of DME for local markets. An LPDME catalyst system with reasonable long-term activity and stzibility is being developed. Planning for a proof-of-concept test run at the LaPorte Alternative Fuels Development Unit (AFDU) was recommended. DOE issued a letter dated 31 July 1997 accepting the recommendation to continue design verification testing. In order to allow for scale-up of the manufacturing technique for the dehydration catalyst from the pilot plant to the commercial scale, the time required to produce the catalyst to the AFDU has slipped. The new estimated delivery date is 01 June 1998.

  1. Discovery of four periodic methanol masers and updated light curve for a further one

    E-Print Network [OSTI]

    Szymczak, M; Bartkiewicz, A

    2015-01-01T23:59:59.000Z

    We report the discovery of 6.7 GHz methanol maser periodic flares in four massive star forming regions and the updated light curve for the known periodic source G22.357+0.066. The observations were carried out with the Torun 32 m radio telescope between June 2009 and April 2014. Flux density variations with period of 120 to 245 d were detected for some or all spectral features. A variability pattern with a fast rise and relatively slow fall on time-scale of 30-60 d dominated. A reverse pattern was observed for some features of G22.357+0.066, while sinusoidal-like variations were detected in G25.411+0.105. A weak burst lasting ~520 d with the velocity drift of 0.24 km/s/yr occurred in G22.357+0.066. For three sources for which high resolution maps are available, we found that the features with periodic behaviour are separated by more than 500 au from those without any periodicity. This suggests that the maser flares are not triggered by large-scale homogeneous variations in either the background seed photon fl...

  2. Commercial-scale demonstration of the Liquid Phase Methanol process. Technical progress report number 8, April 1--June 30, 1996

    SciTech Connect (OSTI)

    NONE

    1996-12-31T23:59:59.000Z

    The project involves the construction of an 80,000 gallon per day (260 tons per day (TPD)) methanol unit utilizing coal-derived synthesis gas from Eastman`s integrated coal gasification facility. The new equipment consists of synthesis gas feed preparation and compression facilities, the liquid phase reactor and auxiliaries, product distillation facilities, and utilities. The technology to be demonstrated is the product of a cooperative development effort by Air Products and DOE in a program that started in 1981. Developed to enhance electric power generation using integrated gasification combined cycle (IGCC) technology, the LPMEOH{trademark} process is ideally suited for directly processing gases produced by modern-day coal gasifiers. Originally tested at a small (10 TPD), DOE-owned experimental unit in LaPorte, Texas, the technology provides several improvements essential for the economic coproduction of methanol and electricity directly from gasified coal. This liquid phase process suspends fine catalyst particles in an inert liquid, forming a slurry. The slurry dissipates the heat of the chemical reaction away from the catalyst surface, protecting the catalyst and allowing the methanol synthesis reaction to proceed at higher rates. At the Eastman complex, the technology is being integrated with existing coal-gasifiers. A carefully developed test plan will allow operations at Eastman to simulate electricity demand load-following in coal-based IGCC facilities. The operations will also demonstrate the enhanced stability and heat dissipation of the conversion process, its reliable on/off operation, and its ability to produce methanol as a clean liquid fuel without additional upgrading.

  3. First images of 6.7-GHz methanol masers in DR21(OH) and DR21(OH)N

    E-Print Network [OSTI]

    L. Harvey-Smith; R. Soria-Ruiz; A. Duarte-Cabral; R. J. Cohen

    2007-11-18T23:59:59.000Z

    The first images of 6.7-GHz methanol masers in the massive star-forming regions DR21(OH) and DR21(OH)N are presented. By measuring the shapes, radial velocities and polarization properties of these masers it is possible to map out the structure, kinematics and magnetic fields in the molecular gas that surrounds newly-formed massive stars. The intrinsic angular resolution of the observations was 43 mas (~100 AU at the distance of DR21), but structures far smaller than this were revealed by employing a non-standard mapping technique. This technique was used in an attempt to identify the physical structure (e.g. disc, outflow, shock) associated with the methanol masers. Two distinct star-forming centres were identified. In DR21(OH) the masers had a linear morphology, and the individual maser spots each displayed an internal velocity gradient in the same direction as the large-scale structure. They were detected at the same position as the OH 1.7-GHz ground-state masers, close to the centre of an outflow traced by CO and class I methanol masers. The shape and velocity gradients of the masers suggests that they probably delineate a shock. In DR21(OH)N the methanol masers trace an arc with a double-peaked profile and a complex velocity gradient. This velocity gradient closely resembles that of a Keplerian disc. The masers in the arc are 4.5% linearly polarized, with a polarization angle that indicates that the magnetic field direction is roughly perpendicular to the large-scale magnetic field in the region (indicated by lower angular resolution measurements of the CO and dust polarization). The suitability of channel-by-channel centroid mapping is discussed as an improved and viable means to maximise the information gained from the data.

  4. First-Principles Study on the Origin of the Different Selectivities for Methanol Steam Reforming on Cu(111) and Pd(111)

    E-Print Network [OSTI]

    Li, Weixue

    First-Principles Study on the Origin of the Different Selectivities for Methanol Steam Reforming-up,14 but formation of hot spots in the reactor may give rise to sintering of the catalysts.3

  5. Study of Adsorption of Methanol in an Activated Carbon and Carbon Nanotube Matrix for Use in a Solar Based Refrigeration Cycle

    E-Print Network [OSTI]

    Sambath, Srivaths

    2012-07-16T23:59:59.000Z

    This thesis seeks to investigate the adsorption capabilities of activated carbon and carbon nanotubes. The adsorption of methanol on both of these substances was tested for their application in a solar based refrigeration cycle. Research on carbon...

  6. Study of Adsorption of Methanol in an Activated Carbon and Carbon Nanotube Matrix for Use in a Solar Based Refrigeration Cycle 

    E-Print Network [OSTI]

    Sambath, Srivaths

    2012-07-16T23:59:59.000Z

    This thesis seeks to investigate the adsorption capabilities of activated carbon and carbon nanotubes. The adsorption of methanol on both of these substances was tested for their application in a solar based refrigeration cycle. Research on carbon...

  7. FIRST COSMOLOGICAL CONSTRAINTS ON THE PROTON-TO-ELECTRON MASS RATIO FROM OBSERVATIONS OF ROTATIONAL TRANSITIONS OF METHANOL

    SciTech Connect (OSTI)

    Ellingsen, S. P.; Lovell, J. E. J. [School of Mathematics and Physics, University of Tasmania, Private Bag 37, Hobart, TAS 7001 (Australia); Voronkov, M. A.; Breen, S. L., E-mail: Simon.Ellingsen@utas.edu.au [CSIRO Astronomy and Space Science, Australia Telescope National Facility, P.O. Box 76, Epping, NSW 1710 (Australia)

    2012-03-15T23:59:59.000Z

    We have used the Australia Telescope Compact Array to measure the absorption from the 2{sub 0} {yields} 3{sub -1} E 12.2 GHz transition of methanol toward the z = 0.89 lensing galaxy in the PKS B1830-211 gravitational lens system. Comparison of the velocity of the main absorption feature with the published absorption spectrum from the 1{sub 0} {yields} 2{sub -1} E transition of methanol shows that they differ by -0.6 {+-} 1.6 km s{sup -1}. We can use these observations to constrain the changes in the proton-to-electron mass ratio {mu} from z = 0.89 to the present to 0.8 {+-} 2.1 Multiplication-Sign 10{sup -7}. This result is consistent, and of similar precision to recent observations at z = 0.68 achieved through comparison of a variety of rotational and inversion transitions, and approximately a factor of two better than previous constraints obtained in this source. Future more sensitive observations that incorporate additional rotational methanol transitions offer the prospect of improving current results by a factor of 5-10.

  8. A multi-transition molecular line study of candidate massive young stellar objects associated with methanol masers

    E-Print Network [OSTI]

    M. Szymczak; A. Bartkiewicz; A. M. S. Richards

    2007-04-10T23:59:59.000Z

    We characterize the molecular environment of candidate massive young stellar objects (MYSOs) signposted by methanol masers. Single pixel observations of 10 transitions of HCO^+, CO and CS isotopomers were carried out, using the IRAM 30m telescope. We studied a sample of 28 targets for which the 6.7GHz maser emission positions are known with a sub-arcsecond accuracy. The systemic velocity inferred from the optically thin lines agrees within 3km/s with the central velocity of the maser emission for most of the sources. About 64% of the sources show line wings in one or more transitions of CO, HCO^+ and CS species, indicating the presence of molecular outflows. Comparison of the widths of line wings and methanol maser emission suggests that the 6.7GHz maser line traces the environment of MYSO of various kinematic regimes. Therefore conditions conducive for the methanol maser can exist in the inner parts of molecular clouds or circumstellar discs as well as in the outer parts associated with molecular outflows. Calculations of the physical conditions based on the CO and HCO^+ lines and the CS line intensity ratios refine the input parameters for maser models.

  9. Insight into methanol synthesis from CO2 hydrogenation on Cu(111): Complex reaction network and the effects of H2O

    SciTech Connect (OSTI)

    Zhao, Yafan; Yang, Yong; Mims, Charles A.; Peden, Charles HF; Li, Jun; Mei, Donghai

    2011-05-31T23:59:59.000Z

    Methanol synthesis from CO2 hydrogenation on supported Cu catalysts is of considerable importance in the chemical and energy industries. Although extensive experimental and theoretical efforts have been carried out in the past decades, the most fundamental questions such as the reaction mechanisms and the key reaction intermediates are still in debate. In the present work, a comprehensive reaction network for CO2 hydrogenation to methanol on Cu(111) was studied using periodic density functional theory (DFT) calculations. All of the elementary reaction steps in the reaction network were identified in an unbiased way with the dimer method. Our calculation results show that methanol synthesis from direct hydrogenation of formate on Cu(111) is not feasible due to the high activation barriers for some of the elementary steps. Instead, we find that CO2 hydrogenation to hydrocarboxyl (trans-COOH) is kinetically more favorable than formate in the presence of H2O via a unique proton transfer mechanism. The trans-COOH is then converted into hydroxymethylidyne (COH) via dihydroxycarbene (COHOH) intermediates, followed by three consecutive hydrogenation steps to form hydroxymethylene (HCOH), hydroxymethyl (H2COH), and methanol. This is consistent with recent experimental observations [1], which indicate that direct hydrogenation of formate will not produce methanol under dry hydrogen conditions. Thus, both experiment and computational modeling clearly demonstrate the important role of trace amounts of water in methanol synthesis from CO2 hydrogenation on Cu catalysts. The proposed methanol synthesis route on Cu(111) not only provides new insights into methanol synthesis chemistry, but also demonstrates again that spectroscopically observed surface species are often not critical reaction intermediates but rather spectator species. Pacific Northwest National Laboratory is operated by Battelle for the US Department of Energy.

  10. Vapor-liquid equilibrium data at 298. 15 K for binary systems containing methyl acetate or methanol with 2-methoxyethanol or 2-ethoxyethanol

    SciTech Connect (OSTI)

    Martin, M.C.; Cocero, M.J.; Mato, F.B. (Univ. de Valladolid (Spain))

    1994-07-01T23:59:59.000Z

    Isothermal vapor-liquid equilibria were measured at 298.15 K for the systems containing methyl acetate or methanol with 2-methoxyethanol or 2-ethoxyethanol. Mixtures containing methanol show a behavior close to ideal, while those containing methyl acetate exhibit positive deviations from ideality and satisfy the Redlich-Kister thermodynamic consistency test. The liquid-phase activity coefficients were fitted by using the van Laar, Wilson, NRTL, and NRTL-m (a modified NRTL equation) equations.

  11. Commercial-Scale Demonstration of the Liquid Phase Methanol (LPMEOH) Process

    SciTech Connect (OSTI)

    None

    1998-12-21T23:59:59.000Z

    he Liquid Phase Methanol (LPMEOW) Demonstration Project at Kingsport Tennessee, is a $213.7 million cooperative agreement between the U.S. Department of Energy (DOE) and Air Products Liquid Phase Conversion Company, L.P. (the Partnership) to produce methanol from coal-derived synthesis gas (syngas). Air Products and Chemicals, Inc. (Air Products) and Eastman Chemical Company (Eastman) formed the Partnership to execute the Demonstration Project. The LPMEOEP Process Demonstration Unit was built at a site located at the Eastman coal-to-chemicals complex in Kingsport. The LPMEOHW Demonstration Facility completed its first year of operation on 02 April 1998. The LPMEOW Demonstration Facility also completed the longest continuous operating run (65 days) on 21 April 1998. Catalyst activity, as defined by the ratio of the rate constant at any point in time to the rate constant for freshly reduced catalyst (as determined in the laboratory autoclave), was monitored throughout the reporting period. During a six-week test at a reactor temperature of 225oC and Balanced Gas flowrate of 700 KSCFH, the rate of decline in catalyst activity was steady at 0.29-0.36% per day. During a second one-month test at a reactor temperature of 220oC and a Balanced Gas flowrate of 550-600 KSCFH, the rate of decline in catalyst activity was 0.4% per day, which matched the pefiorrnance at 225"C, as well as the 4-month proof-of-concept run at the LaPorte AFDU in 1988/89. Beginning on 08 May 1998, the LPMEOW Reactor temperature was increased to 235oC, which was the operating temperature tier the December 1997 restart with the fresh charge of catalyst (50'Yo of design loading). The flowrate of the primary syngas feed stream (Balanced Gas) was also increased to 700-750 KSCFH. During two stable operating periods between 08 May and 09 June 1998, the average catalyst deactivation rate was 0.8% per day. Due to the scatter of the statistical analysis of the results, this test was extended to better quanti& the catalyst aging behavior. During the reporting perio~ two batches of fresh catalyst were activated and transferred to the reactor (on 02 April and 20 June 1998). The weight of catalyst in the LPMEOW Reactor has reached 80% of the design value. At the end of the reporting period, a step-change in the pressure-drop profile within the LPMEOW Reactor and an increase in the pressure of the steam system which provides cooling to the LPMEOW Reactor were observed. No change in the calculated activity of the catalyst was detected during either of these transients. These parameters will be monitored closely for any additional changes.

  12. DOE-FLEX: DOE's Telework Program

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2013-02-11T23:59:59.000Z

    The order establishes the requirements and responsibilities for the Departments telework program. Cancels DOE N 314.1.

  13. DOE-FLEX: DOE's Telework Program

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2011-07-05T23:59:59.000Z

    The directive establishes the requirements and responsibilities for the Department’s telework program. Canceled by DOE O 314.1.

  14. Flex-flame burner and combustion method

    DOE Patents [OSTI]

    Soupos, Vasilios (Chicago, IL); Zelepouga, Serguei (Hoffman Estates, IL); Rue, David M. (Chicago, IL); Abbasi, Hamid A. (Naperville, IL)

    2010-08-24T23:59:59.000Z

    A combustion method and apparatus which produce a hybrid flame for heating metals and metal alloys, which hybrid flame has the characteristic of having an oxidant-lean portion proximate the metal or metal alloy and having an oxidant-rich portion disposed above the oxidant lean portion. This hybrid flame is produced by introducing fuel and primary combustion oxidant into the furnace chamber containing the metal or metal alloy in a substoichiometric ratio to produce a fuel-rich flame and by introducing a secondary combustion oxidant into the furnace chamber above the fuel-rich flame in a manner whereby mixing of the secondary combustion oxidant with the fuel-rich flame is delayed for a portion of the length of the flame.

  15. Flex Fuel Optimized SI and HCCI Engine

    Broader source: Energy.gov (indexed) [DOE]

    - FY 12 439,489 Recipient (up to date): Chrysler: 270.3K estimated (labor, prototype engine and parts) MSU: 235.6K (in-kind) Barriers - Lack of modeling capability for...

  16. Flex Fuel Optimized SI and HCCI Engine

    Broader source: Energy.gov (indexed) [DOE]

    FY 12 280,463439,489 Recipient (up to date): Chrysler: 262.105K (labor, prototype engine and parts) MSU: 123K (in-kind) Barriers - Lack of modeling capability for...

  17. Flex Fuel Optimized SI and HCCI Engine

    Broader source: Energy.gov (indexed) [DOE]

    12 439,489 Barriers - Target: Demonstrate a SI and HCCI dual combustion mode engine for a blend of gasoline and E85 for the best fuel economy - Development of a cost...

  18. Flex Fuel Optimized SI and HCCI Engine

    Broader source: Energy.gov (indexed) [DOE]

    - FY 12 439,489 Recipient (up to date): Chrysler: 108.5K labor, one prototype engine and an extra head MSU: 73K (in-kind) Barriers - Lack of modeling capability for...

  19. Flex Fuel Optimized SI and HCCI Engine

    SciTech Connect (OSTI)

    Zhu, Guoming; Schock, Harold; Yang, Xiaojian; Huisjen, Andrew; Stuecken, Tom; Moran, Kevin; Zhen, Ron; Zhang, Shupeng

    2013-09-30T23:59:59.000Z

    The central objective of the proposed work is to demonstrate an HCCI (homogeneous charge compression ignition) capable SI (spark ignited) engine that is capable of fast and smooth mode transition between SI and HCCI combustion modes. The model-based control technique was used to develop and validate the proposed control strategy for the fast and smooth combustion mode transition based upon the developed control-oriented engine; and an HCCI capable SI engine was designed and constructed using production ready two-step valve-train with electrical variable valve timing actuating system. Finally, smooth combustion mode transition was demonstrated on a metal engine within eight engine cycles. The Chrysler turbocharged 2.0L I4 direct injection engine was selected as the base engine for the project and the engine was modified to fit the two-step valve with electrical variable valve timing actuating system. To develop the model-based control strategy for stable HCCI combustion and smooth combustion mode transition between SI and HCCI combustion, a control-oriented real-time engine model was developed and implemented into the MSU HIL (hardware-in-the-loop) simulation environment. The developed model was used to study the engine actuating system requirement for the smooth and fast combustion mode transition and to develop the proposed mode transition control strategy. Finally, a single cylinder optical engine was designed and fabricated for studying the HCCI combustion characteristics. Optical engine combustion tests were conducted in both SI and HCCI combustion modes and the test results were used to calibrate the developed control-oriented engine model. Intensive GT-Power simulations were conducted to determine the optimal valve lift (high and low) and the cam phasing range. Delphi was selected to be the supplier for the two-step valve-train and Denso to be the electrical variable valve timing system supplier. A test bench was constructed to develop control strategies for the electrical variable valve timing (VVT) actuating system and satisfactory electrical VVT responses were obtained. Target engine control system was designed and fabricated at MSU for both single-cylinder optical and multi-cylinder metal engines. Finally, the developed control-oriented engine model was successfully implemented into the HIL simulation environment. The Chrysler 2.0L I4 DI engine was modified to fit the two-step vale with electrical variable valve timing actuating system. A used prototype engine was used as the base engine and the cylinder head was modified for the two-step valve with electrical VVT actuating system. Engine validation tests indicated that cylinder #3 has very high blow-by and it cannot be reduced with new pistons and rings. Due to the time constraint, it was decided to convert the four-cylinder engine into a single cylinder engine by blocking both intake and exhaust ports of the unused cylinders. The model-based combustion mode transition control algorithm was developed in the MSU HIL simulation environment and the Simulink based control strategy was implemented into the target engine controller. With both single-cylinder metal engine and control strategy ready, stable HCCI combustion was achived with COV of 2.1% Motoring tests were conducted to validate the actuator transient operations including valve lift, electrical variable valve timing, electronic throttle, multiple spark and injection controls. After the actuator operations were confirmed, 15-cycle smooth combustion mode transition from SI to HCCI combustion was achieved; and fast 8-cycle smooth combustion mode transition followed. With a fast electrical variable valve timing actuator, the number of engine cycles required for mode transition can be reduced down to five. It was also found that the combustion mode transition is sensitive to the charge air and engine coolant temperatures and regulating the corresponding temperatures to the target levels during the combustion mode transition is the key for a smooth combustion mode transition. As a summary, the proposed combust

  20. Flex Fuel Optimized SI and HCCI Engine

    Broader source: Energy.gov [DOE]

    2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  1. Global Flex Group Inc | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to: navigation, search OpenEI Reference LibraryAdd toWell2008)Information

  2. DOE-FLEX: DOE's Telework Program

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2012-04-25T23:59:59.000Z

    The JM proposes to establish the notice as an Order. The directive is required by the Telework Enhancement Act (TEA) of 2010.

  3. Oxford FlexAL SOP Introduction

    E-Print Network [OSTI]

    Reif, Rafael

    Chamber 1 from the drop down menu. Adjust the process temperature using the Table Heater setting. #12 and click OK. #12;The recipe steps will be displayed on the screen. Click on the Repeat Step

  4. Flex Fuel Vehicle Systems | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport inEnergy0.pdf Flash2010-60.pdf2 DOE Hydrogen and Fuel Cells Program and1

  5. Flex Fuel Vehicle Systems | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport inEnergy0.pdf Flash2010-60.pdf2 DOE Hydrogen and Fuel Cells Program and12009

  6. Deployment of FlexCHP System

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onYouTube YouTube Note: Since the YouTube| DepartmentStatementDepartment of EnergyHydropower Technologies28, 2010

  7. Indiana Flex Fuels LLC | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual SiteofEvaluatingGroup | OpenHunan Runhua NewSmallholder Systems (SAMPLES)IndianOil

  8. Reformers for the production of hydrogen from methanol and alternative fuels for fuel cell powered vehicles

    SciTech Connect (OSTI)

    Kumar, R.; Ahmed, S.; Krumpelt, M.; Myles, K.M.

    1992-08-01T23:59:59.000Z

    The objective of this study was (i) to assess the present state of technology of reformers that convert methanol (or other alternative fuels) to a hydrogen-rich gas mixture for use in a fuel cell, and (ii) to identify the R&D needs for developing reformers for transportation applications. Steam reforming and partial oxidation are the two basic types of fuel reforming processes. The former is endothermic while the latter is exothermic. Reformers are therefore typically designed as heat exchange systems, and the variety of designs used includes shell-and-tube, packed bed, annular, plate, and cyclic bed types. Catalysts used include noble metals and oxides of Cu, Zn, Cr, Al, Ni, and La. For transportation applications a reformer must be compact, lightweight, and rugged. It must also be capable of rapid start-up and good dynamic performance responsive to fluctuating loads. A partial oxidation reformer is likely to be better than a steam reformer based on these considerations, although its fuel conversion efficiency is expected to be lower than that of a steam reformer. A steam reformer better lends itself to thermal integration with the fuel cell system; however, the thermal independence of the reformer from the fuel cell stack is likely to yield much better dynamic performance of the reformer and the fuel cell propulsion power system. For both steam reforming and partial oxidation reforming, research is needed to develop compact, fast start-up, and dynamically responsive reformers. For transportation applications, steam reformers are likely to prove best for fuel cell/battery hybrid power systems, and partial oxidation reformers are likely to be the choice for stand-alone fuel cell power systems.

  9. Reformers for the production of hydrogen from methanol and alternative fuels for fuel cell powered vehicles

    SciTech Connect (OSTI)

    Kumar, R.; Ahmed, S.; Krumpelt, M.; Myles, K.M.

    1992-08-01T23:59:59.000Z

    The objective of this study was (i) to assess the present state of technology of reformers that convert methanol (or other alternative fuels) to a hydrogen-rich gas mixture for use in a fuel cell, and (ii) to identify the R D needs for developing reformers for transportation applications. Steam reforming and partial oxidation are the two basic types of fuel reforming processes. The former is endothermic while the latter is exothermic. Reformers are therefore typically designed as heat exchange systems, and the variety of designs used includes shell-and-tube, packed bed, annular, plate, and cyclic bed types. Catalysts used include noble metals and oxides of Cu, Zn, Cr, Al, Ni, and La. For transportation applications a reformer must be compact, lightweight, and rugged. It must also be capable of rapid start-up and good dynamic performance responsive to fluctuating loads. A partial oxidation reformer is likely to be better than a steam reformer based on these considerations, although its fuel conversion efficiency is expected to be lower than that of a steam reformer. A steam reformer better lends itself to thermal integration with the fuel cell system; however, the thermal independence of the reformer from the fuel cell stack is likely to yield much better dynamic performance of the reformer and the fuel cell propulsion power system. For both steam reforming and partial oxidation reforming, research is needed to develop compact, fast start-up, and dynamically responsive reformers. For transportation applications, steam reformers are likely to prove best for fuel cell/battery hybrid power systems, and partial oxidation reformers are likely to be the choice for stand-alone fuel cell power systems.

  10. Liquid Phase Methanol LaPorte Process Development Unit: Modification, operation, and support studies

    SciTech Connect (OSTI)

    Not Available

    1990-08-31T23:59:59.000Z

    A gas phase and a slurry phase radioactive tracer study was performed on the 12 ton/day Liquid Phase Methanol (LPMEOH) Process Development Unit (PDU) in LaPorte, Texas. To study the gas phase mixing characteristics, a radioactive argon tracer was injected into the feed gas and residence time distribution was generated by measuring the response at the reactor outlet. Radioactive manganese oxide powder was independently injected into the reactor to measure the slurry phase mixing characteristics. A tanks-in-series model and an axial dispersion model were applied to the data to characterize the mixing in the reactor. From the axial dispersion model, a translation to the number of CSTR's (continuous stirred tank reactors) was made for comparison purposes with the first analysis. Dispersion correlations currently available in the literature were also compared. The tanks-in-series analysis is a simpler model whose results are easily interpreted. However, it does have a few drawbacks; among them, the lack of a reliable method for scaleup of a reactor and no direct correlation between mixing in the slurry and gas phases. The dispersion model allows the mixing in the gas and slurry phases to be characterized separately while including the effects of phase transfer. This analysis offers a means for combining the gas and slurry phase dispersion models into an effective dispersion coefficient, which, in turn, can be related to an equivalent number of tanks-in-series. The dispersion methods reported are recommended for scaleup of a reactor system. 24 refs., 18 figs., 8 tabs.

  11. Mechanistic study of methanol synthesis from CO? and H? on a modified model Mo?S? cluster

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Liu, Cheng [Yangzhou Univ., Yangzhou, Jiangsu (China); Liu, Ping [Brookhaven National Lab. (BNL), Upton, NY (United States)

    2015-02-06T23:59:59.000Z

    We report the methanol synthesis from CO? and H? on metal (M = K, Ti, Co, Rh, Ni, and Cu)-modified model Mo?S? catalyst using density functional theory (DFT). The results show that the catalytic behavior of a Mo?S? cluster is changed significantly due to the modifiers, via the electron transfer from M to Mo?S? and therefore the reduction of the Mo cation (ligand effect) and the direct participation of M in the reaction (ensemble effect) to promote some elementary steps. With the most positively charged modifier, the ligand effect in the case of K-Mo?S? is the most obvious among the systems studied; however it cannot compete with the ensemble effect, which plays a dominate role in determining activity via the electrostatic attraction in particular to stabilize the CHxOy species adsorbed at the Mo sites of Mo?S?. In comparison, the ligand effect is weaker and the ensemble effect is more important when the other modifiers are used. In addition, the modifiers also vary the optimal reaction pathway for methanol synthesis on Mo?S?, ranging from the reverse water-gas shift (RWGS) + CO hydrogenation as that of Mo?S? to the formate pathway. Finally, K is able to accelerate the methanol synthesis on Mo?S? the most; while the promotion by Rh is relatively small. Using the modifiers like Ti, Co, Ni, and Cu, the activity of Mo?S? is decreased instead. The relative stability between *HCOO and *HOCO is identified as a descriptor to capture the variation in mechanism and scales well with the estimated activity. Our study not only provides better understanding of the reaction mechanism and actives on the modified Mo?S?, but also predicts some possible candidates, which can be used a promoter to facilitate the CH?OH synthesis on Mo sulfides.

  12. Mechanistic study of methanol synthesis from CO? and H? on a modified model Mo?S? cluster

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Liu, Cheng; Liu, Ping

    2015-02-06T23:59:59.000Z

    We report the methanol synthesis from CO? and H? on metal (M = K, Ti, Co, Rh, Ni, and Cu)-modified model Mo?S? catalyst using density functional theory (DFT). The results show that the catalytic behavior of a Mo?S? cluster is changed significantly due to the modifiers, via the electron transfer from M to Mo?S? and therefore the reduction of the Mo cation (ligand effect) and the direct participation of M in the reaction (ensemble effect) to promote some elementary steps. With the most positively charged modifier, the ligand effect in the case of K-Mo?S? is the most obvious among themore »systems studied; however it cannot compete with the ensemble effect, which plays a dominate role in determining activity via the electrostatic attraction in particular to stabilize the CHxOy species adsorbed at the Mo sites of Mo?S?. In comparison, the ligand effect is weaker and the ensemble effect is more important when the other modifiers are used. In addition, the modifiers also vary the optimal reaction pathway for methanol synthesis on Mo?S?, ranging from the reverse water-gas shift (RWGS) + CO hydrogenation as that of Mo?S? to the formate pathway. Finally, K is able to accelerate the methanol synthesis on Mo?S? the most; while the promotion by Rh is relatively small. Using the modifiers like Ti, Co, Ni, and Cu, the activity of Mo?S? is decreased instead. The relative stability between *HCOO and *HOCO is identified as a descriptor to capture the variation in mechanism and scales well with the estimated activity. Our study not only provides better understanding of the reaction mechanism and actives on the modified Mo?S?, but also predicts some possible candidates, which can be used a promoter to facilitate the CH?OH synthesis on Mo sulfides.« less

  13. Conversion of methane to higher hydrocarbons (Biomimetic catalysis of the conversion of methane to methanol). Final report

    SciTech Connect (OSTI)

    Watkins, B.E.; Taylor, R.T.; Satcher, J.H. [and others

    1993-09-01T23:59:59.000Z

    In addition to inorganic catalysts that react with methane, it is well-known that a select group of aerobic soil/water bacteria called methanotrophs can efficiently and selectively utilize methane as the sole source of their energy and carbon for cellular growth. The first reaction in this metabolic pathway is catalyzed by the enzyme methane monooxygenase (MMO) forming methanol. Methanol is a technology important product from this partial oxidation of methane since it can be easily converted to liquid hydrocarbon transportation fuels (gasoline), used directly as a liquid fuel or fuel additive itself, or serve as a feedstock for chemicals production. This naturally occurring biocatalyst (MMO) is accomplishing a technologically important transformation (methane directly to methanol) for which there is currently no analogous chemical (non-biological) process. The authors approach has been to use the biocatalyst, MMO, as the initial focus in the development of discrete chemical catalysts (biomimetic complexes) for methane conversion. The advantage of this approach is that it exploits a biocatalytic system already performing a desired transformation of methane. In addition, this approach generated needed new experimental information on catalyst structure and function in order to develop new catalysts rationally and systematically. The first task is a comparative mechanistic, biochemical, and spectroscopic investigation of MMO enzyme systems. This work was directed at developing a description of the structure and function of the catalytically active sites in sufficient detail to generate a biomimetic material. The second task involves the synthesis, characterization, and chemical reactions of discrete complexes that mimic the enzymatic active site. These complexes were synthesized based on their best current understanding of the MMO active site structure.

  14. Theoretical study of syngas hydrogenation to methanol on the polar Zn-terminated ZnO(0001) surface

    SciTech Connect (OSTI)

    Zhao, Ya-Fan; Rousseau, Roger J.; Li, Jun; Mei, Donghai

    2012-08-02T23:59:59.000Z

    Methanol synthesis from syngas (CO/CO2/H2) hydrogenation on the perfect Zn–terminated polar ZnO(0001) surface have been investigated using periodic density functional theory calculations. Our results show that direct CO2 hydrogenation to methanol on the perfect ZnO(0001) surface is unlikely because in the presence of surface atomic H and O the highly stable formate (HCOO) and carbonate (CO3) readily produced from CO2 with low barriers 0.11 and 0.09 eV will eventually accumulate and block the active sites of the ZnO(0001) surface. In contrast, methanol synthesis from CO hydrogenation is thermodynamically and kinetically feasible on the perfect ZnO(0001) surface. CO can be consecutively hydrogenated into formyl (HCO), formaldehyde (H2CO), methoxy (H3CO) intermediates, leading to the final formation of methanol (H3COH). The reaction route via hydroxymethyl (H2COH) intermediate, a previously proposed species on the defected O–terminated ZnO( ) surface, is kinetically inhibited on the perfect ZnO(0001) surface. The rate-determining step in the consecutive CO hydrogenation route is the hydrogenation of H3CO to H3COH. We also note that this last hydrogenation step is pronouncedly facilitated in the presence of water by lowering the activation barrier from 1.02 to 0.55 eV. This work was supported by the U.S. Department of Energy Office of Basic Energy Sciences, Division of Chemical Sciences, Biosciences and Geosciences, and performed at EMSL, a national scientific user facility sponsored by the Department of Energy’s Office of Biological and Environmental Research located at Pacific Northwest National Laboratory (PNNL). Computational resources were provided at EMSL and the National Energy Research Scientific Computing Center at Lawrence Berkeley National Laboratory. J. Li and Y.-F. Zhao were also financially supported by the National Natural Science Foundation of China (Nos. 20933003 and 91026003) and the National Basic Research Program of China (No. 2011CB932400). Y.-F. Zhao acknowledges the fellowship from PNNL.

  15. Tungsten carbide/porous carbon composite as superior support for platinum catalyst toward methanol electro-oxidation

    SciTech Connect (OSTI)

    Jiang, Liming [School of Chemical Engineering and Technology, Harbin Institute of Technology, Harbin 150001 (China); Fu, Honggang, E-mail: fuhg@vip.sina.com [School of Chemical Engineering and Technology, Harbin Institute of Technology, Harbin 150001 (China); Key Laboratory of Functional Inorganic Material Chemistry, Heilongjiang University, Harbin 150080 (China); Wang, Lei; Mu, Guang; Jiang, Baojiang; Zhou, Wei; Wang, Ruihong [Key Laboratory of Functional Inorganic Material Chemistry, Heilongjiang University, Harbin 150080 (China)

    2014-01-01T23:59:59.000Z

    Graphical abstract: The WC nanoparticles are well dispersed in the carbon matrix. The size of WC nanoparticles is about 30 nm. It can be concluded that tungsten carbide and carbon composite was successfully prepared by the present synthesis conditions. - Highlights: • The WC/PC composite with high specific surface area was prepared by a simple way. • The Pt/WC/PC catalyst has superior performance toward methanol electro-oxidation. • The current density for methanol electro-oxidation is as high as 595.93 A g{sup ?1} Pt. • The Pt/WC/PC catalyst shows better durability and stronger CO electro-oxidation. • The performance of Pt/WC/PC is superior to the commercial Pt/C (JM) catalyst. - Abstract: Tungsten carbide/porous carbon (WC/PC) composites have been successfully synthesized through a surfactant assisted evaporation-induced-assembly method, followed by a thermal treatment process. In particular, WC/PC-35-1000 composite with tungsten content of 35% synthesized at the carbonized temperature of 1000 °C, exhibited a specific surface area (S{sub BET}) of 457.92 m{sup 2} g{sup ?1}. After loading Pt nanoparticles (NPs), the obtained Pt/WC/PC-35-1000 catalyst exhibits the highest unit mass electroactivity (595.93 A g{sup ?1} Pt) toward methanol electro-oxidation, which is about 2.6 times as that of the commercial Pt/C (JM) catalyst. Furthermore, the Pt/WC/PC-35-1000 catalyst displays much stronger resistance to CO poisoning and better durability toward methanol electrooxidation compared with the commercial Pt/C (JM) catalyst. The high electrocatalytic activity, strong poison-resistivity and good stability of Pt/WC/PC-35-1000 catalyst are attributed to the porous structures and high specific surface area of WC/PC support could facilitate the rapid mass transportation. Moreover, synergistic effect between WC and Pt NPs is favorable to the higher catalytic performance.

  16. Molecular modeling of the morphology and transport properties of two direct methanol fuel cell membranes: phenylated sulfonated poly(ether ether ketone ketone) versus Nafion

    SciTech Connect (OSTI)

    Devanathan, Ramaswami; Idupulapati, Nagesh B.; Dupuis, Michel

    2012-08-14T23:59:59.000Z

    We have used molecular dynamics simulations to examine membrane morphology and the transport of water, methanol and hydronium in phenylated sulfonated poly ether ether ketone ketone (Ph-SPEEKK) and Nafion membranes at 360 K for a range of hydration levels. At comparable hydration levels, the pore diameter is smaller, the sulfonate groups are more closely packed, the hydronium ions are more strongly bound to sulfonate groups, and the diffusion of water and hydronium is slower in Ph-SPEEKK relative to the corresponding properties in Nafion. The aromatic carbon backbone of Ph-SPEEKK is less hydrophobic than the fluorocarbon backbone of Nafion. Water network percolation occurs at a hydration level ({lambda}) of {approx}8 H{sub 2}O/SO{sub 3}{sup -}. At {lambda} = 20, water, methanol and hydronium diffusion coefficients were 1.4 x 10{sup -5}, 0.6 x 10{sup -5} and 0.2 x 10{sup -5} cm{sup 2}/s, respectively. The pore network in Ph-SPEEKK evolves dynamically and develops wide pores for {lambda} > 20, which leads to a jump in methanol crossover and ion transport. This study demonstrates the potential of aromatic membranes as low-cost challengers to Nafion for direct methanol fuel cell applications and the need to develop innovative strategies to combat methanol crossover at high hydration levels.

  17. Alkali or alkaline earth metal promoted catalyst and a process for methanol synthesis using alkali or alkaline earth metals as promoters

    DOE Patents [OSTI]

    Tierney, John W. (Pittsburgh, PA); Wender, Irving (Pittsburgh, PA); Palekar, Vishwesh M. (Pittsburgh, PA)

    1995-01-01T23:59:59.000Z

    The present invention relates to a novel route for the synthesis of methanol, and more specifically to the production of methanol by contacting synthesis gas under relatively mild conditions in a slurry phase with a heterogeneous catalyst comprising reduced copper chromite impregnated with an alkali or alkaline earth metal. There is thus no need to add a separate alkali or alkaline earth compound. The present invention allows the synthesis of methanol to occur in the temperature range of approximately 100.degree.-160.degree. C. and the pressure range of 40-65 atm. The process produces methanol with up to 90% syngas conversion per pass and up to 95% methanol selectivity. The only major by-product is a small amount of easily separated methyl formate. Very small amounts of water, carbon dioxide and dimethyl ether are also produced. The present catalyst combination also is capable of tolerating fluctuations in the H.sub.2 /CO ratio without major deleterious effect on the reaction rate. Furthermore, carbon dioxide and water are also tolerated without substantial catalyst deactivation.

  18. Alkali or alkaline earth metal promoted catalyst and a process for methanol synthesis using alkali or alkaline earth metals as promoters

    DOE Patents [OSTI]

    Tierney, J.W.; Wender, I.; Palekar, V.M.

    1995-01-31T23:59:59.000Z

    The present invention relates to a novel route for the synthesis of methanol, and more specifically to the production of methanol by contacting synthesis gas under relatively mild conditions in a slurry phase with a heterogeneous catalyst comprising reduced copper chromite impregnated with an alkali or alkaline earth metal. There is thus no need to add a separate alkali or alkaline earth compound. The present invention allows the synthesis of methanol to occur in the temperature range of approximately 100--160 C and the pressure range of 40--65 atm. The process produces methanol with up to 90% syngas conversion per pass and up to 95% methanol selectivity. The only major by-product is a small amount of easily separated methyl formate. Very small amounts of water, carbon dioxide and dimethyl ether are also produced. The present catalyst combination also is capable of tolerating fluctuations in the H[sub 2]/CO ratio without major deleterious effect on the reaction rate. Furthermore, carbon dioxide and water are also tolerated without substantial catalyst deactivation.

  19. Development of vanadium-phosphate catalysts for methanol production by selective oxidation of methane. Quarterly technical progress report 10, July 1, 1995--September 31, 1995

    SciTech Connect (OSTI)

    McCormick, R.L.

    1995-12-07T23:59:59.000Z

    This document is the tenth quarterly technical progress report under Contract No. DE-AC22-92PC92110 {open_quotes}Development of Vanadium-Phosphate Catalysts for Methanol Production by Selective Oxidation of Methane{close_quotes}. Activities focused on testing of additional modified and promoted catalysts and characterization of these materials. Attempts at improving the sensitivity of our GC based analytical systems were also made with some success. Methanol oxidation studies were initiated. These results are reported. Specific accomplishments include: (1) Methane oxidation testing of a suite of catalysts promoted with most of the first row transition metals was completed. Several of these materials produced low, difficult to quantify yields of formaldehyde. (2) Characterization of these materials by XRD and FTIR was performed with the goal of correlating activity and selectivity with catalyst properties. (3) We began to characterize catalysts prepared via modified synthesis methods designed to enhance acidity using TGA measurements of acetonitrile chemisorption and methanol dehydration to dimethyl ether as a test reaction. (4) A catalyst prepared in the presence of naphthalene methanol as a structural disrupter was tested for activity in methane oxidation. It was found that this material produced low yields of formaldehyde which were difficult to quantify. (5) Preparation of catalysts with no Bronsted acid sites. This was accomplished by replacement of exchangeable protons with potassium, and (6) Methanol oxidation studies were initiated to provide an indication of catalyst activity for decomposition of this desired product and as a method of characterizing the catalyst surface.

  20. FORMALDEHYDE AND METHANOL DEUTERATION IN PROTOSTARS: FOSSILS FROM A PAST FAST HIGH-DENSITY PRE-COLLAPSE PHASE

    SciTech Connect (OSTI)

    Taquet, V.; Ceccarelli, C.; Kahane, C. [UJF-Grenoble 1/CNRS-INSU, Institut de Planetologie et d'Astrophysique de Grenoble (IPAG) UMR 5274, F-38041 Grenoble (France)

    2012-03-20T23:59:59.000Z

    Extremely high deuteration of several molecules has been observed around low-mass protostars for a decade. Among them, formaldehyde and methanol present particularly high deuteration, with observations of abundant doubly and triply deuterated forms. Both species are thought to be mainly formed on interstellar grains during the low-temperature and dense pre-collapse phase by H and D atom additions on the iced CO. We present here a theoretical study of the formaldehyde and methanol deuteration obtained with our gas-grain model, GRAINOBLE. This model takes into account the multilayer nature of the mantle and explores the robustness of the results against the uncertainties of poorly constrained chemical and surface model parameters. The comparison of the model predictions with the observations leads to two major results: (1) the observed high deuteration is obtained during the last phase of the pre-collapse stage, when the density reaches {approx}5 Multiplication-Sign 10{sup 6} cm{sup -3}, and this phase is fast, lasting only several thousands years; and (2) D and H abstraction and substitution reactions are crucial in making up the observed deuteration ratios. This work shows the power of chemical composition as a tool to reconstruct the past history of protostars.