Sample records for naturally occurring isotopes

  1. Existence of long-lived isomeric states in naturally-occurring neutron-deficient Th isotopes

    E-Print Network [OSTI]

    A. Marinov; I. Rodushkin; Y. Kashiv; L. Halicz; I. Segal; A. Pape; R. V. Gentry; H. W. Miller; D. Kolb; R. Brandt

    2006-05-10T23:59:59.000Z

    Evidence for the existence of long-lived neutron-deficient isotopes has been found in a study of naturally-occurring Th using iductively coupled plasma-sector field mass spectrometry. They are interpreted as belonging to the recently discovered class of long-lived high spin super- and hyperdeformed isomers.

  2. Characterization of naturally occurring porous media

    E-Print Network [OSTI]

    Riley, Robert Daniel

    1965-01-01T23:59:59.000Z

    characteristics of natural occur- ring porous media, The gR /K dimensionless ratio is related to the minimum water saturation in the reverse manner as is permeability. REFERENCES Wyllie, M. R. J. and M. B. Spangler: Application of Electrical Resistivity...: Resistivity of Brine-Saturated Sands in Relation to Pore Seometry. Cornell, D. snd D. L. Kstz: Flow of Sases through Consolidated Porous Media. Industrial and En ineeri hemietr (October 1953) Vo . 5, p. 21 5. Leverett, N, C. : Capillary Behavior...

  3. Introduction to naturally occurring radioactive material

    SciTech Connect (OSTI)

    Egidi, P.

    1997-08-01T23:59:59.000Z

    Naturally occurring radioactive material (NORM) is everywhere; we are exposed to it every day. It is found in our bodies, the food we eat, the places where we live and work, and in products we use. We are also bathed in a sea of natural radiation coming from the sun and deep space. Living systems have adapted to these levels of radiation and radioactivity. But some industrial practices involving natural resources concentrate these radionuclides to a degree that they may pose risk to humans and the environment if they are not controlled. Other activities, such as flying at high altitudes, expose us to elevated levels of NORM. This session will concentrate on diffuse sources of technologically-enhanced (TE) NORM, which are generally large-volume, low-activity waste streams produced by industries such as mineral mining, ore benefication, production of phosphate Fertilizers, water treatment and purification, and oil and gas production. The majority of radionuclides in TENORM are found in the uranium and thorium decay chains. Radium and its subsequent decay products (radon) are the principal radionuclides used in characterizing the redistribution of TENORM in the environment by human activity. We will briefly review other radionuclides occurring in nature (potassium and rubidium) that contribute primarily to background doses. TENORM is found in many waste streams; for example, scrap metal, sludges, slags, fluids, and is being discovered in industries traditionally not thought of as affected by radionuclide contamination. Not only the forms and volumes, but the levels of radioactivity in TENORM vary. Current discussions about the validity of the linear no dose threshold theory are central to the TENORM issue. TENORM is not regulated by the Atomic Energy Act or other Federal regulations. Control and regulation of TENORM is not consistent from industry to industry nor from state to state. Proposed regulations are moving from concentration-based standards to dose-based standards. So when is TENORM a problem? Where is it a problem? That depends on when, where, and whom you talk to! We will start by reviewing background radioactivity, then we will proceed to the geology, mobility, and variability of these radionuclides. We will then review some of the industrial sectors affected by TENORM, followed by a brief discussion on regulatory aspects of the issue.

  4. Naturally Occurring Radioactive Materials in Cargo at US Borders

    SciTech Connect (OSTI)

    Kouzes, Richard T.; Ely, James H.; Evans, John C.; Hensley, Walter K.; Lepel, Elwood A.; McDonald, Joseph C.; Schweppe, John E.; Siciliano, Edward R.; Strom, Daniel J.; Woodring, Mitchell L.

    2006-01-01T23:59:59.000Z

    In the U.S. and other countries, large numbers of vehicles pass through border crossings each day. The illicit movement of radioactive sources is a concern that has resulted in the installation of radiation detection and identification instruments at border crossing points. This activity is judged to be necessary because of the possibility of an act of terrorism involving a radioactive source that may include any number of dangerous radionuclides. The problem of detecting, identifying, and interdicting illicit radioactive sources is complicated by the fact that many materials present in cargo are somewhat radioactive. Some cargo contains naturally occurring radioactive material or technologically-enhanced naturally occurring radioactive material that may trigger radiation portal monitor alarms. Man-made radioactive sources, especially medical isotopes, are also frequently observed and produce alarms. Such nuisance alarms can be an operational limiting factor for screening of cargo at border crossings. Information about the nature of the radioactive materials in cargo that can interfere with the detection of radionuclides of concern is necessary. This paper provides such information for North American cargo, but the information may also be of use to border control officials in other countries. (PIET-43741-TM-361)

  5. Naturally occurring crystalline phases: analogues for radioactive waste forms

    SciTech Connect (OSTI)

    Haaker, R.F.; Ewing, R.C.

    1981-01-01T23:59:59.000Z

    Naturally occurring mineral analogues to crystalline phases that are constituents of crystalline radioactive waste forms provide a basis for comparison by which the long-term stability of these phases may be estimated. The crystal structures and the crystal chemistry of the following natural analogues are presented: baddeleyite, hematite, nepheline; pollucite, scheelite;sodalite, spinel, apatite, monazite, uraninite, hollandite-priderite, perovskite, and zirconolite. For each phase in geochemistry, occurrence, alteration and radiation effects are described. A selected bibliography for each phase is included.

  6. Natural mercury isotope variation in coal deposits and organic soils

    SciTech Connect (OSTI)

    Abir, Biswas; Joel D. Blum; Bridget A. Bergquist; Gerald J. Keeler; Zhouqing Xie [University of Michigan, Ann Arbor, MI (United States). Department of Geological Sciences

    2008-11-15T23:59:59.000Z

    There is a need to distinguish among sources of Hg to the atmosphere in order to more fully understand global Hg pollution. In this study we investigate whether coal deposits within the United States, China, and Russia-Kazakhstan, which are three of the five greatest coal-producing regions, have diagnostic Hg isotopic fingerprints that can be used to discriminate among Hg sources. We also investigate the Hg isotopic composition of modern organic soil horizons developed in areas distant from point sources of Hg in North America. Mercury stored in coal deposits displays a wide range of both mass dependent fractionation and mass independent fractionation. {delta}{sup 202}Hg varies in coals by 3{per_thousand} and {Delta}{sup 201}Hg varies by 0.9{per_thousand}. Combining these two Hg isotope signals results in what may be a unique isotopic 'fingerprint' for many coal deposits. Mass independent fractionation of mercury has been demonstrated to occur during photochemical reactions of mercury. This suggests that Hg found in most coal deposits was subjected to photochemical reduction near the Earth's surface prior to deposition. The similarity in MDF and MIF of modern organic soils and coals from North America suggests that Hg deposition from coal may have imprinted an isotopic signature on soils. This research offers a new tool for characterizing mercury inputs from natural and anthropogenic sources to the atmosphere and provides new insights into the geochemistry of mercury in coal and soils. 35 refs., 2 figs., 1 tab.

  7. Manufactured Home Testing in Simulated and Naturally Occurring High Winds

    SciTech Connect (OSTI)

    W. D. Richins; T. K. Larson

    2006-08-01T23:59:59.000Z

    A typical double-wide manufactured home was tested in simulated and naturally occurring high winds to understand structural behavior and improve performance during severe windstorms. Seven (7) lateral load tests were conducted on a double-wide manufactured home at a remote field test site in Wyoming. An extensive instrumentation package monitored the overall behavior of the home and collected data vital to validating computational software for the manufactured housing industry. The tests were designed to approach the design load of the home without causing structural damage, thus allowing the behavior of the home to be accessed when the home was later exposed to high winds (to 80-mph). The data generally show near-linear initial system response with significant non-linear behavior as the applied loads increase. Load transfer across the marriage line is primarily compression. Racking, while present, is very small. Interface slip and shear displacement along the marriage line are nearly insignificant. Horizontal global displacements reached 0.6 inch. These tests were designed primarily to collect data necessary to calibrate a desktop analysis and design software tool, MHTool, under development at the Idaho National Laboratory specifically for manufactured housing. Currently available analysis tools are, for the most part, based on methods developed for “stick built” structures and are inappropriate for manufactured homes. The special materials utilized in manufactured homes, such as rigid adhesives used in the connection of the sheathing materials to the studs, significantly alter the behavior of manufactured homes under lateral loads. Previous full scale tests of laterally loaded manufactured homes confirm the contention that conventional analysis methods are not applicable. System behavior dominates the structural action of manufactured homes and its prediction requires a three dimensional analysis of the complete unit, including tiedowns. This project was sponsored by the US Department of Energy, US Department of Housing and Urban Development, and the Manufactured Housing Institute. The results of this research can lead to savings in annual losses of life and property by providing validated information to enable the advancement of code requirements and by developing engineering software that can predict and optimize wind resistance.

  8. Absolute proof that hydrogen-antihydrogen oscillations occur in nature

    E-Print Network [OSTI]

    G. Van Hooydonk

    2005-08-07T23:59:59.000Z

    Detecting H-antiH oscillations is intimately connected with the existence of natural antiH. We detect natural H-antiH oscillations, generated by a classical spin-free Coulomb quantum gap, which we calculate analytically without any parameter. Oscillation times are much smaller than those predicted with the Standard Model. These unprecedented results also remove the so-called problem with matter-antimatter asymmetry in the Universe.

  9. USE OF NATURALLY-OCCURRING TRACERS TO MONITOR TWO-PHASE CONDITIONS...

    Open Energy Info (EERE)

    IN THE COSO EGS PROJECT Jump to: navigation, search OpenEI Reference LibraryAdd to library Conference Proceedings: USE OF NATURALLY-OCCURRING TRACERS TO MONITOR TWO-PHASE...

  10. Chlorine isotope investigation of natural attenuation of trichloroethene in an aerobic aquifer

    SciTech Connect (OSTI)

    Sturchio, N.C.; Heraty, L.J.; Huang, L.; Holt, B.D.; Abrajano, T.A. Jr. [Argonne National Lab., IL (United States)] [Argonne National Lab., IL (United States); Clausen, J.L. [Lockheed-Martin Energy Services, Inc., Kevil, KY (United States)] [Lockheed-Martin Energy Services, Inc., Kevil, KY (United States)

    1998-10-15T23:59:59.000Z

    Natural attenuation of chlorinated aliphatic hydrocarbons (CAHs) can be an important mechanism for groundwater remediation. It is difficult to determine the effectiveness of natural CAH attenuation from chemical analyses of groundwater samples because mixing, dispersion, and secondary reactions can mask the chemical evidence of attenuation. In this paper, the authors explore the application of stable chlorine isotope ratio measurements as a new tool for evaluating natural attenuation of CAHs. They report stable isotope ratios of chlorine in both trichloroethene (TCE) and inorganic chloride in groundwater from an aerobic aquifer beneath an extensively contaminated industrial site, the Paducah Gaseous Diffusion Plant in western Kentucky. Variations in the concentrations and chlorine isotope ratios of TCE and chloride in the groundwater are consistent with those expected from natural attenuation. These data support a model in which partial TCE degradation occurred in relatively impermeable, clay-rich sediments above the aquifer, and little or no further degradation of TCE occurred within the aquifer. A record of changing conditions within the TCE source area can be inferred from the spatial variation of chlorine isotope ratios for TCE and chloride within the plume.

  11. Polymers, both natural and synthetic, play an integral role in our daily lives. Naturally-occurring polymers include cellulose (mentioned in gun cotton demo), rubber, skin, hair,

    E-Print Network [OSTI]

    Weston, Ken

    . Naturally- occurring polymers include cellulose (mentioned in gun cotton demo), rubber, skin, hair, DNA, etc

  12. Roles of Naturally Occurring Bacteria in Controlling Iodine-129 Mobility in Subsurface Soils

    E-Print Network [OSTI]

    Li, Hsiu-Ping

    2012-10-19T23:59:59.000Z

    - to reactive intermediates. The aim of this study was to determine the influence of naturally occurring aerobic bacteria isolated from an 129I contaminated aquifer (F-area of the Savannah River Site, SC) on I- oxidation and OI formation. It was demonstrated...

  13. Lead isotopes in sediments of the Loire River (France): natural versus anthropogenic origin

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Lead isotopes in sediments of the Loire River (France): natural versus anthropogenic origin France) were investigated by means of lead isotopes determined on the labile sediment fraction, or acid-extractable matter (AEM). The combination of trace elements and lead isotopes allows deciphering the origin

  14. Naturally occurring, optically driven, cellular rotor J. A. Dharmadhikari, S. Roy, A. K. Dharmadhikari, S. Sharma, and D. Mathura)

    E-Print Network [OSTI]

    Sharma, Shobhona

    Naturally occurring, optically driven, cellular rotor J. A. Dharmadhikari, S. Roy, A. K 005, India (Received 10 June 2004; accepted 20 October 2004) We report the conversion of optical energy into mechanical energy by naturally occurring red blood cells (RBCs) placed in an optical trap

  15. Systems and methods for facilitating hydrogen storage using naturally occurring nanostructure assemblies

    DOE Patents [OSTI]

    Fliermans; , Carl B. (Augusta, GA)

    2012-08-07T23:59:59.000Z

    Some or all of the needs above can be addressed by embodiments of the invention. According to embodiments of the invention, systems and methods for facilitating hydrogen storage using naturally occurring nanostructure assemblies can be implemented. In one embodiment, a method for storing hydrogen can be provided. The method can include providing diatoms comprising diatomaceous earth or diatoms from a predefined culture. In addition, the method can include heating the diatoms in a sealed environment in the presence of at least one of titanium, a transition metal, or a noble metal to provide a porous hydrogen storage medium. Furthermore, the method can include exposing the porous hydrogen storage medium to hydrogen. In addition, the method can include storing at least a portion of the hydrogen in the porous hydrogen storage medium.

  16. Natural thorium isotopes in marine sediment core off Labuan port

    SciTech Connect (OSTI)

    Hafidz, B. Y.; Asnor, A. S.; Terence, R. C.; Mohamed, C. A. R. [School of Environmental and Natural Resource Sciences, Faculty of Science and Technology, Universiti Kebangsaan Malaysia 43600, Bangi, Selangor (Malaysia)

    2014-02-12T23:59:59.000Z

    Sediment core was collected from Labuan port and analyzed to determine the radioactivity of thorium (Th) isotopes. The objectives of this study are to determine the possible sources of Th isotopes at Labuan port and estimates the sedimentation rate based on {sup 228}Th/{sup 232}Th model. The results suggest the {sup 230}Th and {sup 232}Th might be originated from terrestrial sedimentary rock while {sup 228}Th originated by authigenic origin. High ratio value of {sup 230}Th/{sup 232}Th detected at the top surface sediment indicates the increasing of {sup 230}Th at the recent years which might be contributed from the anthropogenic sources. The sedimentation rate of core sediment from Labuan Port was successfully estimated by using {sup 228}Th/{sup 232}Th model. The result show high sedimentation rate with 4.67 cm/year indicates rapid deposition occurred at this study area due to the high physical activity at the Labuan port. By assume the constant sedimentation rate at this area; we estimated the age of 142 cm core sediment obtained from Labuan port is 32 years started from 1981 to 2012. This chronology will be used in forthcoming research to investigate the historical profile of anthropogenic activities affecting the Labuan port.

  17. Effects of naturally occurring coumarins on hepatic drug-metabolizing enzymes inmice

    SciTech Connect (OSTI)

    Kleiner, Heather E. [Department of Carcinogenesis, University of Texas M.D. Anderson Cancer Center, Science Park-Research Division, Park Road 1-C, Smithville, TX 78957 (United States)], E-mail: hklein@lsuhsc.edu; Xia, Xiaojun; Sonoda, Junichiro [Howard Hughes Medical Institute, Gene Expression Laboratory, Salk Institute for Biological Sciences, La Jolla, CA 92037 (United States); Zhang, Jun [Department of Molecular and Cellular Biology, Baylor College of Medicine, One Baylor Plaza, Houston, TX 77030 (United States); Pontius, Elizabeth; Abey, Jane [Department of Carcinogenesis, University of Texas M.D. Anderson Cancer Center, Science Park-Research Division, Park Road 1-C, Smithville, TX 78957 (United States); Evans, Ronald M. [Howard Hughes Medical Institute, Gene Expression Laboratory, Salk Institute for Biological Sciences, La Jolla, CA 92037 (United States); Moore, David D. [Department of Molecular and Cellular Biology, Baylor College of Medicine, One Baylor Plaza, Houston, TX 77030 (United States); DiGiovanni, John [Department of Carcinogenesis, University of Texas M.D. Anderson Cancer Center, Science Park-Research Division, Park Road 1-C, Smithville, TX 78957 (United States)

    2008-10-15T23:59:59.000Z

    Cytochromes P450 (P450s) and glutathione S-transferases (GSTs) constitute two important enzyme families involved in carcinogen metabolism. Generally, P450s play activation or detoxifying roles while GSTs act primarily as detoxifying enzymes. We previously demonstrated that oral administration of the linear furanocoumarins, isopimpinellin and imperatorin, modulated P450 and GST activities in various tissues of mice. The purpose of the present study was to compare a broader range of naturally occurring coumarins (simple coumarins, and furanocoumarins of the linear and angular type) for their abilities to modulate hepatic drug-metabolizing enzymes when administered orally to mice. We now report that all of the different coumarins tested (coumarin, limettin, auraptene, angelicin, bergamottin, imperatorin and isopimpinellin) induced hepatic GST activities, whereas the linear furanocoumarins possessed the greatest abilities to induce hepatic P450 activities, in particular P450 2B and 3A. In both cases, this corresponded to an increase in protein expression of the enzymes. Induction of P4502B10, 3A11, and 2C9 by xenobiotics often is a result of activation of the pregnane X receptor (PXR) and/or constitutive androstane receptor (CAR). Using a pregnane X receptor reporter system, our results demonstrated that isopimpinellin activated both PXR and its human ortholog SXR by recruiting coactivator SRC-1 in transfected cells. In CAR transfection assays, isopimpinellin counteracted the inhibitory effect of androstanol on full-length mCAR, a Gal4-mCAR ligand-binding domain fusion, and restored coactivator binding. Orally administered isopimpinellin induced hepatic mRNA expression of Cyp2b10, Cyp3a11, and GSTa in CAR(+/+) wild-type mice. In contrast, the induction of Cyp2b10 mRNA by isopimpinellin was attenuated in the CAR(-/-) mice, suggesting that isopimpinellin induces Cyp2b10 via the CAR receptor. Overall, the current data indicate that naturally occurring coumarins have diverse activities in terms of inducing various xenobiotic metabolizing enzymes based on their chemical structure.

  18. Isotope shifts of natural Sr+ measured by laser fluorescence in a sympathetically cooled Coulomb crystal

    E-Print Network [OSTI]

    Brice Dubost; Romain Dubessy; Benjamin Szymanski; Samuel Guibal; Jean-Pierre Likforman; Luca Guidoni

    2014-02-14T23:59:59.000Z

    We measured by laser spectroscopy the isotope shifts between naturally-occurring even-isotopes of strontium ions for both the $5s\\,\\,^2S_{1/2}\\to 5p\\,\\,^2P_{1/2}$ (violet) and the $4d\\,\\,^2D_{3/2}\\to 5p\\,\\,^2P_{1/2}$ (infrared) dipole-allowed optical transitions. Fluorescence spectra were taken by simultaneous measurements on a two-component Coulomb crystal in a linear Paul trap containing $10^3$--$10^4$ laser-cooled Sr$^+$ ions. The isotope shifts are extracted from the experimental spectra by fitting the data with the analytical solution of the optical Bloch equations describing a three-level atom in interaction with two laser beams. This technique allowed us to increase the precision with respect to previously reported data obtained by optogalvanic spectroscopy or fast atomic-beam techniques. The results for the $5s\\,\\,^2S_{1/2}\\to 5p\\,\\,^2P_{1/2}$ transition are $\

  19. Ra, a naturally occurring isotope of the 238 U-series with a

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    for counting, liquid scintillation, or mass spectrometry at comparable activities, the simple setup, low cost- fiber and is continuously transferred to a scintillation cham- 226 Ra determination via the rate of 222

  20. An overview of naturally occurring radioactive materials (NORM) in the petroleum industry

    SciTech Connect (OSTI)

    Smith, K.P.

    1992-12-01T23:59:59.000Z

    Oil and gas extraction and processing operations sometimes accumulate naturally occurring radioactive materials (NORM) at concentrations above normal in by-product waste streams. Results from NORM surveys indicate that radionuclide concentrations can be quite variable, ranging from undetectable to extremely high levels. To date, efforts to characterize the geographic distribution of NORM have been limited by poor statistical representation. In addition, the fate of NORM in the environment has not been fully defined, and few human health risk assessment have been conducted. Both the petroleum industry and regulators are becoming increasingly concerned about the presence of NORM. At present, most existing federal environmental regulations do not address oil and gas NORM, and only a few states have developed regulatory programs. Available data suggest that the occurrence of NORM (and associated health risks) is significant enough to warrant increased regulatory control. However, before these regulations can be developed, additional research is needed to (1) better characterize the occurrence and distribution of NORM throughout the industry, (2) quantify hazards posed by NORM to industry workers and the general public, and (3) develop effective waste treatment and minimization technologies that will lower the risk associated with NORM and reduce disposal costs.

  1. Regulatory Initiatives for Control and Release of Technologically Enhanced Naturally-Occurring Radioactive Materials

    SciTech Connect (OSTI)

    Egidi, P.V.

    1999-03-02T23:59:59.000Z

    Current drafts of proposed standards and suggested State regulations for control and release of technologically-enhanced naturally-occurring radioactive material (TENORM), and standards for release of volumetrically-contaminated material in the US are reviewed. These are compared to the recommendations of the International Atomic Energy Association (IAEA) Safety Series and the European Commission (EC) proposals. Past regulatory efforts with respect to TENORM in the US dealt primarily with oil-field related wastes. Currently, nine states (AK, GA, LA, MS, NM, OH, OR SC, TX) have specific regulations pertaining to TENORM, mostly based on uranium mill tailings cleanup criteria. The new US proposals are dose- or risk-based, as are the IAEA and EC recommendations, and are grounded in the linear no threshold hypothesis (LNT). TENORM wastes involve extremely large volumes, particularly scrap metal and mine wastes. Costs to control and dispose of these wastes can be considerable. The current debate over the validity of LNT at low doses and low dose rates is particularly germane to this discussion. Most standards setting organizations and regulatory agencies base their recommendations on the LNT. The US Environmental Protection Agency has released a draft Federal Guidance Report that recommends calculating health risks from low-level exposure to radionuclides based on the LNT. However, some scientific and professional organizations are openly questioning the validity of LNT and its basis for regulations, practices, and costs to society in general. It is not clear at this time how a non-linear regulatory scheme would be implemented.

  2. Roles of Naturally Occurring Bacteria in Controlling Iodine-129 Mobility in Subsurface Soils 

    E-Print Network [OSTI]

    Li, Hsiu-Ping

    2012-10-19T23:59:59.000Z

    129I is of major concern because of its biophilic nature, excessive inventory, long half-life (~16 million yrs), and high mobility in the natural environment that depends on its chemical speciation. Iodide (I-) has the ...

  3. ISOTOPES

    E-Print Network [OSTI]

    Lederer, C. Michael

    2013-01-01T23:59:59.000Z

    rare (0.017%) isotope 36s at enrichments of 70% at a price32). The enrichment of carbon isotopes by C02-carbamatesulfur isotopes by S02-NaHS03 exchange and the enrichment of

  4. Investigation of Naturally Occurring Radio Nuclides in Shir-kuh Granites

    SciTech Connect (OSTI)

    Mazarei, Mohammad Mehdi; Zarei, Mojtaba [Department of Science, Bushehr Branch, Islamic Azad University, City of Aalishahr, Bushehr Province, Iran P.O.Box: 7519619555 (Iran, Islamic Republic of)

    2011-12-26T23:59:59.000Z

    One of the principle natural radiation resources is Granite which can be dangerous for human because of its radiations. Based on this fact, in this research we attempt to specify the activity amount of these natural radio nuclides, existing in Shir-kuh Granite of Yazd state. To specify the activity amount of this natural radio nuclides, it has been applied the measurement method of Gamma spectroscopy using high purity Germanium (HPGe) detector.

  5. Sensitive Species and Natural Communities Known to Occur on the Picket Wire Canyonlands, Comanche

    E-Print Network [OSTI]

    ) as identified in the interim management plan for the area. The Natural Heritage Inventory was conducted in seven PNAs. 5. Perform initial ground surveys. 6. Conduct a survey of the PNA's and other habitats suitable the Natural Heritage Program developed preliminary conservation planning boundaries. In developing

  6. Existence of long-lived isotopes of a superheavy element in natural Au

    E-Print Network [OSTI]

    A. Marinov; I. Rodushkin; A. Pape; Y. Kashiv; D. Kolb; R. Brandt; R. V. Gentry; H. W. Miller; L. Halicz; I. Segal

    2007-02-25T23:59:59.000Z

    Evidence for the existence of long-lived isotopes with atomic mass numbers 261 and 265 and abundance of (1-10)x10$^{-10}$ relative to Au has been found in a study of natural Au using an inductively coupled plasma - sector field mass spectrometer. The measured masses fit the predictions made for the masses of $^{261}$Rg and $^{265}$Rg (Z=111) and for some isotopes of nearby elements. The possibility that these isotopes belong to the recently discovered class of long-lived high spin super- and hyperdeformed isomeric states is discussed.

  7. Sulphoraphane, a naturally occurring isothiocyanate induces apoptosis in breast cancer cells by targeting heat shock proteins

    SciTech Connect (OSTI)

    Sarkar, Ruma; Mukherjee, Sutapa [Department of Environmental Carcinogenesis and Toxicology, Chittaranjan National Cancer Institute, 37, SP Mukherjee Road, Kolkata 700 026 (India)] [Department of Environmental Carcinogenesis and Toxicology, Chittaranjan National Cancer Institute, 37, SP Mukherjee Road, Kolkata 700 026 (India); Biswas, Jaydip [Chittaranjan National Cancer Institute, 37, SP Mukherjee Road, Kolkata 700 026 (India)] [Chittaranjan National Cancer Institute, 37, SP Mukherjee Road, Kolkata 700 026 (India); Roy, Madhumita, E-mail: mitacnci@yahoo.co.in [Department of Environmental Carcinogenesis and Toxicology, Chittaranjan National Cancer Institute, 37, SP Mukherjee Road, Kolkata 700 026 (India)] [Department of Environmental Carcinogenesis and Toxicology, Chittaranjan National Cancer Institute, 37, SP Mukherjee Road, Kolkata 700 026 (India)

    2012-10-12T23:59:59.000Z

    Highlights: Black-Right-Pointing-Pointer HSPs (27, 70 and 90) and HSF1 are overexpressed in MCF-7 and MDA-MB-231 cells. Black-Right-Pointing-Pointer Sulphoraphane, a natural isothiocyanate inhibited HSPs and HSF1 expressions. Black-Right-Pointing-Pointer Inhibition of HSPs and HSF1 lead to regulation of apoptotic proteins. Black-Right-Pointing-Pointer Alteration of apoptotic proteins activate of caspases particularly caspase 3 and 9 leading to induction of apoptosis. Black-Right-Pointing-Pointer Alteration of apoptotic proteins induce caspases leading to induction of apoptosis. -- Abstract: Heat shock proteins (HSPs) are involved in protein folding, aggregation, transport and/or stabilization by acting as a molecular chaperone, leading to inhibition of apoptosis by both caspase dependent and/or independent pathways. HSPs are overexpressed in a wide range of human cancers and are implicated in tumor cell proliferation, differentiation, invasion and metastasis. HSPs particularly 27, 70, 90 and the transcription factor heat shock factor1 (HSF1) play key roles in the etiology of breast cancer and can be considered as potential therapeutic target. The present study was designed to investigate the role of sulphoraphane, a natural isothiocyanate on HSPs (27, 70, 90) and HSF1 in two different breast cancer cell lines MCF-7 and MDA-MB-231 cells expressing wild type and mutated p53 respectively, vis-a-vis in normal breast epithelial cell line MCF-12F. It was furthermore investigated whether modulation of HSPs and HSF1 could induce apoptosis in these cells by altering the expressions of p53, p21 and some apoptotic proteins like Bcl-2, Bax, Bid, Bad, Apaf-1 and AIF. Sulphoraphane was found to down-regulate the expressions of HSP70, 90 and HSF1, though the effect on HSP27 was not pronounced. Consequences of HSP inhibition was upregulation of p21 irrespective of p53 status. Bax, Bad, Apaf-1, AIF were upregulated followed by down-regulation of Bcl-2 and this effect was prominent in MCF-7 than in MDA-MB-231. However, very little change in the expression of Bid was observed. Alteration in Bcl-2 Bax ratio resulted in the release of cytochrome c from mitochondria and activation of caspases 3 and 9 which are in agreement with apoptotic index values. Sulphoraphane therefore can be regarded as a potent inducer of apoptosis due to HSP modulation in breast cancer cells.

  8. Naturally occurring hydrogen gas from a borehole on the western flank of Nemaha anticline in Kansas

    SciTech Connect (OSTI)

    Goebel, E.D.; Coveney, R.M. Jr.; Angino, E.E.; Zeller, E.

    1983-08-01T23:59:59.000Z

    Since August 1982, the CFA 1 Scott well in Sec. 20, T14S, R6E, Morris County, Kansas, located about 14 mi (23 km) south of Junction City, has yielded a gas composed of 50 +/- 10% free hydrogen, 50 +/- 10% nitrogen, and only traces of hydrocarbons. This analysis has been ascertained by gas chromatography and mass spectrography of samples taken over a period of 6 months. The reservoir rock is a Kinderhook sand from 2176 to 2196 ft (663 to 669m) depth. The gas samples analyzed are accumulating in the head space above a fluid level (salt water) of 1805 ft (550m) from a botton-hole depth of 2197 ft (670m). The Scott well is located on the western flank of the complexly faulted Nemaha anticline, updip from the central North American rift system and 30 mi (48 km) south of Riley County where serpentinized kimberlites occur. The geothermal gradient is 30/sup 0/C/km (87/sup 0/F/mi). Basement rock beneath the well is granite, probably overlying deeply buried magnetic rocks. No single mechanism is responsible solely for generating this H/sub 2/-rich gas from the Scott well; rather, a combination of fortuitous geologic and possibly biologic processes are contributing in various proportions to the production of the H/sub 2/ and N/sub 2/. Conceivably, the local geologic setting merely is circumstantial and unrelated to the genesis of the gases. However, in view of its spatial association with the central North American rift Zone, a major geologic feature with similarity to the East Pacific Rise, the Kansas gas occurrence warrants additional study.

  9. Upper limits for the existence of long-lived isotopes of roentgenium in natural gold

    SciTech Connect (OSTI)

    Dellinger, F.; Kutschera, W.; Forstner, O.; Golser, R.; Priller, A.; Steier, P.; Wallner, A.; Winkler, G. [University of Vienna, Faculty of Physics, Vienna Environmental Research Accelerator (VERA) Laboratory, Waehringer Strasse 17, A-1090 Wien (Austria)

    2011-01-15T23:59:59.000Z

    A sensitive search for isotopes of a superheavy element (SHE) in natural gold materials has been performed with accelerator mass spectrometry at the Vienna Environmental Research Accelerator, which is based on a 3-MV tandem accelerator. Because the most likely SHE in gold is roentgenium (Rg, Z = 111), the search concentrated on Rg isotopes. Two different mass regions were explored: (i) For the neutron-deficient isotopes {sup 261}Rg and {sup 265}Rg, abundance limits in gold of 3x10{sup -16} were reached (no events observed). This is in stark contrast to the findings of Marinov et al.[Int. J. Mod. Phys. E 18, 621 (2009)], who reported positive identification of these isotopes with inductively coupled plasma sector field mass spectrometry in the (1-10)x10{sup -10} abundance range. (ii) Theoretical models of SHEs predict a region of increased stability around the proton and neutron shell closures of Z = 114 and N = 184. We therefore investigated eight heavy Rg isotopes, {sup A}Rg, A = 289, 290, 291, 292, 293, 294, 295, and 296. For six isotopes no events were observed, setting limits also in the 10{sup -16} abundance range. For {sup 291}Rg and {sup 294}Rg we observed two and nine events, respectively, which results in an abundance in the 10{sup -15} range. However, pileup of a particularly strong background in these cases makes a positive identification as Rg isotopes--even after pileup correction--unlikely.

  10. Geochemical and Strontium Isotope Characterization of Produced Waters from Marcellus Shale Natural Gas Extraction

    SciTech Connect (OSTI)

    Elizabeth C. Chapman,† Rosemary C. Capo,† Brian W. Stewart,*,† Carl S. Kirby,‡ Richard W. Hammack,§

    2012-02-24T23:59:59.000Z

    Extraction of natural gas by hydraulic fracturing of the Middle Devonian Marcellus Shale, a major gas-bearing unit in the Appalachian Basin, results in significant quantities of produced water containing high total dissolved solids (TDS). We carried out a strontium (Sr) isotope investigation to determine the utility of Sr isotopes in identifying and quantifying the interaction of Marcellus Formation produced waters with other waters in the Appalachian Basin in the event of an accidental release, and to provide information about the source of the dissolved solids. Strontium isotopic ratios of Marcellus produced waters collected over a geographic range of ?375 km from southwestern to northeastern Pennsylvania define a relatively narrow set of values (?Sr SW = +13.8 to +41.6, where ?Sr SW is the deviation of the 87Sr/86Sr ratio from that of seawater in parts per 104); this isotopic range falls above that of Middle Devonian seawater, and is distinct from most western Pennsylvania acid mine drainage and Upper Devonian Venango Group oil and gas brines. The uniformity of the isotope ratios suggests a basin-wide source of dissolved solids with a component that is more radiogenic than seawater. Mixing models indicate that Sr isotope ratios can be used to sensitively differentiate between Marcellus Formation produced water and other potential sources of TDS into ground or surface waters.

  11. Geochemical and Strontium Isotope Characterization of Produced Waters from Marcellus Shale Natural Gas Extraction

    SciTech Connect (OSTI)

    Chapman, Elizabeth C; Capo, Rosemary C.; Stewart, Brian W.; Kirby, Carl S.; Hammack, Richard W.; Schroeder, Karl T.; Edenborn, Harry M.

    2012-03-20T23:59:59.000Z

    Extraction of natural gas by hydraulic fracturing of the Middle Devonian Marcellus Shale, a major gas-bearing unit in the Appalachian Basin, results in significant quantities of produced water containing high total dissolved solids (TDS). We carried out a strontium (Sr) isotope investigation to determine the utility of Sr isotopes in identifying and quantifying the interaction of Marcellus Formation produced waters with other waters in the Appalachian Basin in the event of an accidental release, and to provide information about the source of the dissolved solids. Strontium isotopic ratios of Marcellus produced waters collected over a geographic range of 375 km from southwestern to northeastern Pennsylvania define a relatively narrow set of values (?{sub Sr}{sup SW} = +13.8 to +41.6, where ?{sub Sr}{sup SW} is the deviation of the {sup 87}Sr/{sup 86}Sr ratio from that of seawater in parts per 10{sup 4}); this isotopic range falls above that of Middle Devonian seawater, and is distinct from most western Pennsylvania acid mine drainage and Upper Devonian Venango Group oil and gas brines. The uniformity of the isotope ratios suggests a basin-wide source of dissolved solids with a component that is more radiogenic than seawater. Mixing models indicate that Sr isotope ratios can be used to sensitively differentiate between Marcellus Formation produced water and other potential sources of TDS into ground or surface waters.

  12. Radiological Impact Associated to Technologically Enhanced Naturally Occurring Radioactive Materials (TENORM) from Coal-Fired Power Plants Emissions - 13436

    SciTech Connect (OSTI)

    Dinis, Maria de Lurdes; Fiuza, Antonio; Soeiro de Carvalho, Jose; Gois, Joaquim [Geo-Environment and Resources Research Centre (CIGAR), Porto University, Faculty of Engineering - FEUP, Rua Dr. Roberto Frias, 4200-465 Porto (Portugal)] [Geo-Environment and Resources Research Centre (CIGAR), Porto University, Faculty of Engineering - FEUP, Rua Dr. Roberto Frias, 4200-465 Porto (Portugal); Meira Castro, Ana Cristina [School of Engineering Polytechnic of Porto - ISEP, Rua Dr. Antonio Bernardino de Almeida, 431, 4200-072, Porto (Portugal)] [School of Engineering Polytechnic of Porto - ISEP, Rua Dr. Antonio Bernardino de Almeida, 431, 4200-072, Porto (Portugal)

    2013-07-01T23:59:59.000Z

    Certain materials used and produced in a wide range of non-nuclear industries contain enhanced activity concentrations of natural radionuclides. In particular, electricity production from coal is one of the major sources of increased human exposure to naturally occurring radioactive materials. A methodology was developed to assess the radiological impact due to natural radiation background. The developed research was applied to a specific case study, the Sines coal-fired power plant, located in the southwest coastline of Portugal. Gamma radiation measurements were carried out with two different instruments: a sodium iodide scintillation detector counter (SPP2 NF, Saphymo) and a gamma ray spectrometer with energy discrimination (Falcon 5000, Canberra). Two circular survey areas were defined within 20 km of the power plant. Forty relevant measurements points were established within the sampling area: 15 urban and 25 suburban locations. Additionally, ten more measurements points were defined, mostly at the 20-km area. The registered gamma radiation varies from 20 to 98.33 counts per seconds (c.p.s.) corresponding to an external gamma exposure rate variable between 87.70 and 431.19 nGy/h. The highest values were measured at locations near the power plant and those located in an area within the 6 and 20 km from the stacks. In situ gamma radiation measurements with energy discrimination identified natural emitting nuclides as well as their decay products (Pb-212, Pb-2142, Ra-226, Th-232, Ac-228, Th-234, Pa-234, U- 235, etc.). According to the results, an influence from the stacks emissions has been identified both qualitatively and quantitatively. The developed methodology accomplished the lack of data in what concerns to radiation rate in the vicinity of Sines coal-fired power plant and consequently the resulting exposure to the nearby population. (authors)

  13. Acetylation and glycation of fibrinogen in vitro occur at specific lysine residues in a concentration dependent manner: A mass spectrometric and isotope labeling study

    SciTech Connect (OSTI)

    Svensson, Jan, E-mail: jan.svensson@ki.se [Department of Molecular Medicine and Surgery, Karolinska Institutet, Karolinska University Hospital (Solna), SE-171 76 Stockholm (Sweden) [Department of Molecular Medicine and Surgery, Karolinska Institutet, Karolinska University Hospital (Solna), SE-171 76 Stockholm (Sweden); Karolinska Institutet, Department of Clinical Sciences, Danderyd Hospital, SE-182 88 Stockholm (Sweden); Bergman, Ann-Charlotte [Department of Molecular Medicine and Surgery, Karolinska Institutet, Karolinska University Hospital (Solna), SE-171 76 Stockholm (Sweden)] [Department of Molecular Medicine and Surgery, Karolinska Institutet, Karolinska University Hospital (Solna), SE-171 76 Stockholm (Sweden); Adamson, Ulf [Karolinska Institutet, Department of Clinical Sciences, Danderyd Hospital, SE-182 88 Stockholm (Sweden)] [Karolinska Institutet, Department of Clinical Sciences, Danderyd Hospital, SE-182 88 Stockholm (Sweden); Blombaeck, Margareta [Department of Molecular Medicine and Surgery, Karolinska Institutet, Karolinska University Hospital (Solna), SE-171 76 Stockholm (Sweden)] [Department of Molecular Medicine and Surgery, Karolinska Institutet, Karolinska University Hospital (Solna), SE-171 76 Stockholm (Sweden); Wallen, Hakan; Joerneskog, Gun [Karolinska Institutet, Department of Clinical Sciences, Danderyd Hospital, SE-182 88 Stockholm (Sweden)] [Karolinska Institutet, Department of Clinical Sciences, Danderyd Hospital, SE-182 88 Stockholm (Sweden)

    2012-05-04T23:59:59.000Z

    Highlights: Black-Right-Pointing-Pointer Fibrinogen was incubated in vitro with glucose or aspirin. Black-Right-Pointing-Pointer Acetylations and glycations were found at twelve lysine sites by mass spectrometry. Black-Right-Pointing-Pointer The labeling by aspirin and glucose occurred dose-dependently. Black-Right-Pointing-Pointer No competition between glucose and aspirin for binding to fibrinogen was found. -- Abstract: Aspirin may exert part of its antithrombotic effects through platelet-independent mechanisms. Diabetes is a condition in which the beneficial effects of aspirin are less prominent or absent - a phenomenon called 'aspirin resistance'. We investigated whether acetylation and glycation occur at specific sites in fibrinogen and if competition between glucose and aspirin in binding to fibrinogen occurs. Our hypothesis was that such competition might be one explanation to 'aspirin resistance' in diabetes. After incubation of fibrinogen in vitro with aspirin (0.8 mM, 24 h) or glucose (100 mM, 5-10 days), we found 12 modified sites with mass spectrometric techniques. Acetylations in the {alpha}-chain: {alpha}K191, {alpha}K208, {alpha}K224, {alpha}K429, {alpha}K457, {alpha}K539, {alpha}K562, in the {beta}-chain: {beta}K233, and in the {gamma}-chain: {gamma}K170 and {gamma}K273. Glycations were found at {beta}K133 and {gamma}K75, alternatively {gamma}K85. Notably, the lysine 539 is a site involved in FXIII-mediated cross-linking of fibrin. With isotope labeling in vitro, using [{sup 14}C-acetyl]salicylic acid and [{sup 14}C]glucose, a labeling of 0.013-0.084 and 0.12-0.5 mol of acetylated and glycated adduct/mol fibrinogen, respectively, was found for clinically (12.9-100 {mu}M aspirin) and physiologically (2-8 mM glucose) relevant plasma concentrations. No competition between acetylation and glycation could be demonstrated. Thus, fibrinogen is acetylated at several lysine residues, some of which are involved in the cross-linking of fibrinogen. This may mechanistically explain why aspirin facilitates fibrin degradation. We find no support for the idea that glycation of fibrin(ogen) interferes with acetylation of fibrinogen.

  14. Evolution of isotopic composition of reprocessed uranium during the multiple recycling in light water reactors with natural uranium feed

    SciTech Connect (OSTI)

    Smirnov, A. Yu., E-mail: a.y.smirnoff@rambler.ru; Sulaberidze, G. A. [National Research Nuclear University MEPhI (Russian Federation); Alekseev, P. N.; Dudnikov, A. A.; Nevinitsa, V. A., E-mail: neva@dhtp.kiae.ru; Proselkov, V. N.; Chibinyaev, A. V. [Russian Research Centre Kurchatov Institute (Russian Federation)

    2012-12-15T23:59:59.000Z

    A complex approach based on the consistent modeling of neutron-physics processes and processes of cascade separation of isotopes is applied for analyzing physical problems of the multiple usage of reprocessed uranium in the fuel cycle of light water reactors. A number of scenarios of multiple recycling of reprocessed uranium in light water reactors are considered. In the process, an excess absorption of neutrons by the {sup 236}U isotope is compensated by re-enrichment in the {sup 235}U isotope. Specific consumptions of natural uranium for re-enrichment of the reprocessed uranium depending on the content of the {sup 232}U isotope are obtained.

  15. Integrated Approach to Use Natural Chemical and Isotopic Tracers to Estimate Fracture Spacing and Surface Area in EGS Systems

    Broader source: Energy.gov [DOE]

    DOE Geothermal Peer Review 2010 - Presentation. This objective of this project is to develop an innovative approach to estimate fracture surface area and spacing through interpretation of signals of natural chemical and isotopic tracers.

  16. Isotopes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cnHigh SchoolIn12 Investigation Peer ReviewIronNuclear Physics » Isotopes

  17. New Colchicinoids from a Native Jordanian Meadow Saffron, Colchicum brachyphyllum: Isolation of the First Naturally Occurring Dextrorotatory

    E-Print Network [OSTI]

    Falkinham, Joseph

    of their toxic nature, and in Arabian writings of the tenth century, they were recommended for use in gout

  18. Characterization of the National Petroleum Reserve No. 3 (NPR-3) Site for Naturally Occurring Radioactive Material(NORM)

    SciTech Connect (OSTI)

    White, G.J; Rood, A.S.

    1999-01-21T23:59:59.000Z

    The National Petroleum Reserve No. 3 site (NPR-3) near Casper, Wyoming is being prepared for transfer to private industry. Remediation of the NPR-3 site has already begun in anticipation of this transfer. This document describes the characterization of the NPR-3 site for Naturally Occurring Radioactive Materials (NORM). Data generated on radionuclide concentrations and radon emanation may be used to determine disposal options and the need for remediation at this site. A preliminary gamma survey of the NPR-3 site was conducted to identify areas of potential NORM contamination. Based on these gamma surveys, two general areas of NORM contamination were found: the North Water Flood area and the BTP-10 produced water discharge steam. A maximum surface exposure rate of 120 {micro}R h{sup -1} was observed in the North Water Flood area, with the highest readings found along the drainage channel from the area. Exposure rates dropped to background quickly with increasing distance from the center of the drainage. The maximum observed exposure rate in the BTP-10 produced water drainage was 40 {micro}R h{sup -1}. Soil and sediment sampling were concentrated in these two areas. All samples were analyzed for concentration of {sup 226}Ra, {sup 228}Ra, and {sup 40}K. Maximum {sup 226}Ra concentrations observed in the samples collected were 46 pCi g{sup -1} for soil and 78 pCi g{sup -1} for sediment. Concentrations in most samples were considerably lower than these values. Radon emanation fraction was also measured for a randomly selected fraction of the samples. The mean Rn emanation fraction measured was 0.10, indicating that on average only 10 percent of the Rn produced is released from the medium. Based on the results of these analyses, NORM contamination at the NPR-3 site is minimal, and appears to be restricted to the two general areas sampled. Concentrations of NORM radionuclides found soils and sediments in these two locations do not justify remedial actions at present. However, continued discharge of NORM-contaminated produced waters from the BTP-10 area will likely result in the continued accumulation of NORM in sediment. It is therefore recommended that the sediments in the BTP-10 discharge stream be monitored periodically for NORM.

  19. In-Situ Sampling and Characterization of Naturally Occurring Marine Methane Hydrate Using the D/V JOIDES Resolution

    SciTech Connect (OSTI)

    Frank R. Rack

    2006-09-20T23:59:59.000Z

    Cooperative Agreement DE-FC26-01NT41329 between Joint Oceanographic Institutions and DOE-NETL was divided into two phases based on successive proposals and negotiated statements of work pertaining to activities to sample and characterize methane hydrates on ODP Leg 204 (Phase 1) and on IODP Expedition 311 (Phase 2). The Phase 1 Final Report was submitted to DOE-NETL in April 2004. This report is the Phase 2 Final Report to DOE-NETL. The primary objectives of Phase 2 were to sample and characterize methane hydrates using the systems and capabilities of the D/V JOIDES Resolution during IODP Expedition 311, to enable scientists the opportunity to establish the mass and distribution of naturally occurring gas and gas hydrate at all relevant spatial and temporal scales, and to contribute to the DOE methane hydrate research and development effort. The goal of the work was to provide expanded measurement capabilities on the JOIDES Resolution for a dedicated hydrate cruise to the Cascadia continental margin off Vancouver Island, British Columbia, Canada (IODP Expedition 311) so that hydrate deposits in this region would be well characterized and technology development continued for hydrate research. IODP Expedition 311 shipboard activities on the JOIDES Resolution began on August 28 and were concluded on October 28, 2005. The statement of work for this project included three primary tasks: (1) research management oversight, provided by JOI; (2) mobilization, deployment and demobilization of pressure coring and core logging systems, through a subcontract with Geotek Ltd.; and, (3) mobilization, deployment and demobilization of a refrigerated container van that will be used for degassing of the Pressure Core Sampler and density logging of these pressure cores, through a subcontract with the Texas A&M Research Foundation (TAMRF). Additional small tasks that arose during the course of the research were included under these three primary tasks in consultation with the DOE-NETL Program Manager. All tasks outlined in the original statement of work were accomplished except for the deployment and use of the X-ray CT system under Subtask 2-2. This reduction in scope provided resources that were applied to other activities to support the overall project. Post-expedition analysis of results and report writing will continue beyond this reporting period, however, all field deployments associated with this project have been successfully concluded as of this writing.

  20. IN-SITU SAMPLING AND CHARACTERIZATION OF NATURALLY OCCURRING MARINE METHANE HYDRATE USING THE D/V JOIDES RESOLUTION

    SciTech Connect (OSTI)

    Rack, Frank R.; Dickens, Gerald; Ford, Kathryn; Schroeder, Derryl; Storms, Michael

    2002-08-01T23:59:59.000Z

    The primary accomplishment of the JOI Cooperative Agreement with DOE/NETL in this quarter was the preparation of tools and measurement systems for deployment, testing and use on ODP Leg 204, which will study hydrate deposits on Hydrate Ridge, offshore Oregon. Additional accomplishments were related to the postcruise evaluation of tools and measurements systems used on ODP Leg 201 along the Peru margin from January through March, 2002. The operational results from the use of the Pressure Core Sampler (PCS) tool and the PCS Gas Manifold on ODP Leg 201 are evaluated in this progress report in order to prepare for the upcoming deployments on ODP Leg 204 in July, 2002. The PCS was deployed 17 times during ODP Leg 201 and successfully retrieved cores from a broad range of lithologies and sediment depths along the Peru margin. Eleven deployments were entirely successful, collecting between 0.5 and 1.0 meters of sediment at greater than 75% of hydrostatic pressure. The PCS gas manifold was used in conjunction with the Pressure Core Sampler (PCS) throughout ODP Leg 201 to measure the total volume and composition of gases recovered in sediment cores associated with methane gas hydrates. The FUGRO Pressure Corer (FPC), one of the HYACE/HYACINTH pressure coring tools, was also deployed on the D/V JOIDES Resolution during ODP Legs 201 to field-test this coring system at three shallow-water sites located offshore Peru. The field-testing of these tools provides a corollary benefit to DOE/NETL at no cost to this project. The testing of these tools on the D/V JOIDES Resolution was negotiated as part of a cooperative agreement between JOI/ODP and the HYACINTH partners. The DVTP, DVTP-P, APC-methane, and APC-Temperature tools (ODP memory tools) were used extensively during ODP Leg 201. The data obtained from the successful deployments of these tools is still being evaluated by the scientists and engineers involved in this testing; however, preliminary results are presented in this report. An infrared-thermal imaging system (IR-TIS) was deployed for the first time on ODP Leg 201. This system was used to identify methane hydrate intervals in the recovered cores. Initial discussions of these experiments are provided in this report. This report is an overview of the field measurements made on recovered sediment cores and the downhole measurements made during ODP Leg 201. These results are currently being used to incorporate the ''lessons learned'' from these deployments to prepare for a dedicated ODP leg to study the characteristics of naturally-occurring hydrates in the subsurface environment of Hydrate Ridge, offshore Oregon during ODP Leg 204, which will take place from July through September, 2002.

  1. In-Situ Sampling and Characterization of Naturally Occurring Marine Methane Hydrate Using the D/V JOIDES Resolution

    SciTech Connect (OSTI)

    Frank Rack; ODP Leg 204 Shipboard Scientific Party

    2003-06-30T23:59:59.000Z

    The primary accomplishments of the JOI Cooperative Agreement with DOE/NETL in this quarter were that: (1) Frank Rack, Anne Trehu, and Tim Collett presented preliminary results and operational outcomes of ODP Leg 204 at the American Association of Petroleum Geologists annual meeting in Salt Lake City, UT; (2) several Leg 204 scientists participated in special hydrate sessions at the international EGS/AGU/EUG meeting in Nice, France and presented initial science results from the cruise, which included outcomes arising from this cooperative agreement; and, (3) postcruise evaluation of the data, tools and measurement systems that were used during ODP Leg 204 continued in the preparation of deliverables under this agreement. At the EGS/EUG/AGU meeting in Nice, France in April, Leg 204 Co-chiefs Anne Trehu and Gerhard Bohrmann, as well as ODP scientists Charlie Paull, Erwin Suess, and Jim Kennett, participated in a press conference on hydrates. The well-attended press conference entitled ''Gas Hydrates: Free methane found and controversy over the 'hydrate gun''' led to stories in Nature on-line and BBC radio, among others. There were six (6) oral and fifteen (15) poster presentations on ODP Leg 204 hydrate science at the EGS/AGU/EUG Meeting in Nice, France on April 6-11, 2003. This was a very strong showing at a meeting just over six month following the completion of the drilling cruise and highlighted many of the results of the leg, including the results obtained with instruments and equipment funded under this cooperative agreement. At the AAPG annual meeting in Salt Lake City, UT on May 11-14, 2003, Anne Trehu gave an oral presentation about the scientific results of Leg 204, and Frank Rack presented a poster outlining the operational and technical accomplishments. Work continued on analyzing data collected during ODP Leg 204 and preparing reports on the outcomes of Phase 1 projects as well as developing plans for Phase 2.

  2. In-Situ Sampling and Characterization of Naturally Occurring Marine Methane Hydrate Using the D/V JOIDES Resolution

    SciTech Connect (OSTI)

    Frank Rack; Gerhard Bohrmann; Anne Trehu; Michael Storms; Derryl Schroeder; ODP Leg 204 Shipboard Scientific Party

    2002-09-30T23:59:59.000Z

    The primary accomplishment of the JOI Cooperative Agreement with DOE/NETL in this quarter was the deployment of tools and measurement systems on ODP Leg 204 to study hydrate deposits on Hydrate Ridge, offshore Oregon from July through September, 2002. During Leg 204, we cored and logged 9 sites on the Oregon continental margin to determine the distribution and concentration of gas hydrates in an accretionary ridge and adjacent slope basin, investigate the mechanisms that transport methane and other gases into the gas hydrate stability zone (GHSZ), and obtain constraints on physical properties of hydrates in situ. A 3D seismic survey conducted in 2000 provided images of potential subsurface fluid conduits and indicated the position of the GHSZ throughout the survey region. After coring the first site, we acquired Logging-While-Drilling (LWD) data at all but one site to provide an overview of downhole physical properties. The LWD data confirmed the general position of key seismic stratigraphic horizons and yielded an initial estimate of hydrate concentration through the proxy of in situ electrical resistivity. These records proved to be of great value in planning subsequent coring. The second new hydrate proxy to be tested was infrared thermal imaging of cores on the catwalk as rapidly as possible after retrieval. The thermal images were used to identify hydrate samples and to map estimate the distribution and texture of hydrate within the cores. Geochemical analyses of interstitial waters and of headspace and void gases provide additional information on the distribution and concentration of hydrate within the stability zone, the origin and pathway of fluids into and through the GHSZ, and the rates at which the process of gas hydrate formation is occurring. Bio- and lithostratigraphic description of cores, measurement of physical properties, and in situ pressure core sampling and thermal measurements complement the data set, providing ground-truth tests of inferred physical and sedimentological properties. Among the most interesting preliminary results are: (1) the discovery that gas hydrates are distributed through a broad depth range within the GHSZ and that different physical and chemical proxies for hydrate distribution and concentration give generally consistent results; (2) evidence for the importance of sediment properties for controlling the migration of fluids in the accretionary complex; (3) geochemical indications that the gas hydrate system at Hydrate Ridge contains significant concentrations of higher order hydrocarbons and that fractionation and mixing signals will provide important constraints on gas hydrate dynamics; and (4) the discovery of very high chlorinity values that extend for at least 10 mbsf near the summit, indicating that hydrate formation here must be very rapid.

  3. Environmental effects of dredging: Naturally occurring levels of ammonia and sulfide in pore water: An assessment of the literature. Technical notes

    SciTech Connect (OSTI)

    NONE

    1995-05-01T23:59:59.000Z

    Ammonia and sulfide are natural constituents of sediment. Both are very toxic to aquatic organisms. Consequently, their presence may bias dredged material toxicity bioassays that are designed to evaluate the toxicity of persistent contaminants such as heavy metals and petroleum and chlorinated hydrocarbons. The purpose of this technical note is to summarize published information on sediment pore water ammonia and sulfide concentrations that occur in situ. In a subsequent technical note, this exposure information will be coupled with ammonia and sulfide toxicity data to estimate the potential influence of these constituents on dredged material toxicity bioassays.

  4. Geochemical evidence for possible natural migration of Marcellus Formation brine to

    E-Print Network [OSTI]

    Geochemical evidence for possible natural migration of Marcellus Formation brine to shallow possible migration of Marcellus brine through naturally occurring pathways. The occurrences of saline water, because of natural hydraulic connections to deeper formations. formation water isotopes Marcellus Shale

  5. Laser isotope separation by multiple photon absorption

    DOE Patents [OSTI]

    Robinson, C. Paul (Los Alamos, NM); Rockwood, Stephen D. (Los Alamos, NM); Jensen, Reed J. (Los Alamos, NM); Lyman, John L. (Los Alamos, NM); Aldridge, III, Jack P. (Los Alamos, NM)

    1987-01-01T23:59:59.000Z

    Multiple photon absorption from an intense beam of infrared laser light may be used to induce selective chemical reactions in molecular species which result in isotope separation or enrichment. The molecular species must have a sufficient density of vibrational states in its vibrational manifold that, is the presence of sufficiently intense infrared laser light tuned to selectively excite only those molecules containing a particular isotope, multiple photon absorption can occur. By this technique, for example, intense CO.sub.2 laser light may be used to highly enrich .sup.34 S in natural SF.sub.6 and .sup.11 B in natural BCl.sub.3.

  6. Laser isotope separation by multiple photon absorption

    DOE Patents [OSTI]

    Robinson, C.P.; Rockwood, S.D.; Jensen, R.J.; Lyman, J.L.; Aldridge, J.P. III.

    1987-04-07T23:59:59.000Z

    Multiple photon absorption from an intense beam of infrared laser light may be used to induce selective chemical reactions in molecular species which result in isotope separation or enrichment. The molecular species must have a sufficient density of vibrational states in its vibrational manifold that, is the presence of sufficiently intense infrared laser light tuned to selectively excite only those molecules containing a particular isotope, multiple photon absorption can occur. By this technique, for example, intense CO[sub 2] laser light may be used to highly enrich [sup 34]S in natural SF[sub 6] and [sup 11]B in natural BCl[sub 3]. 8 figs.

  7. Microscopic nature of the photon strength function: stable and unstable Ni and Sn isotopes

    E-Print Network [OSTI]

    Achakovskiy, Oleg; Goriely, Stephane; Kamerdzhiev, Sergei; Krewald, Siegfried; Voitenkov, Dmitriy

    2014-01-01T23:59:59.000Z

    The pygmy-dipole resonances and photon strength functions in stable and unstable Ni and Sn isotopes are calculated within the microscopic self-consistent version of the extended theory of finite fermi systems which includes the QRPA and phonon coupling effects and uses the known Skyrme forces SLy4. The pygmy dipole resonance in $^{72}Ni$ is predicted with the mean energy of 12.4 MeV and the energy-weighted sum rule exhausting 25.6\\% of the total strength. The microscopically obtained photon E1 strength functions are used to calculate nuclear reaction properties, i.e the radiative neutron capture cross section, gamma-ray spectra, and average radiative widths. Our main conclusion is that in all these quantities it is necessary to take the phonon coupling effects into account.

  8. Directed metalation of N,N-diethylbenzamides. Silylated benzamides for the synthesis of naturally occurring peri-methylanthraquinones and peri-methyl polycyclic aromatic hydrocarbons

    SciTech Connect (OSTI)

    Mills, R.J.; Snieckus, V. (Univ. of Waterloo, Ontario (Canada))

    1989-09-01T23:59:59.000Z

    Efficient methodologies based on directed ortho metalation, fluoride-induced carbodesilylation, and metal-halogen exchange processes (Scheme I) are reported for the synthesis of peri-methyl-substituted anthraquinone natural products 5 and polycyclic aromatic hydrocarbons 6, 7. Benzamide 8 (Scheme II) is converted in a one-pot sequence into the disilylated derivative 10, which upon metalation, condensation with 3,5-dimethoxybenzaldehyde, CsF desilylation, and TsOH cyclization leads to the key phthalide 11. Compound 11 is transformed into deoxyerythrolaccin tris(methyl ether) 5c, which has been previously converted into the natural product 5a. For the synthesis of erythrolaccin tetrakis(methyl ether) 5d, the silyl and bromo benzamides 14 and 15 (Scheme III) are condensed with 3,5-dimethoxybenzaldehyde by CsF-induced carbodesilylation and metal-halogen exchange expedients, respectively, to give the phthalide 16, which is transformed into the target anthraquinone 55d by methods identical with those used in 5c. Along similar lines, the synthesis of 11-methyl-7,12-benz(a)anthraquinone (6a, Scheme IV), 8-methyl-7,12-benz(a)anthraquinone (6b), and 10-methyl-9,14-dibenz(a,c)anthraquinone (7) is described.

  9. Water isotopes and the general circulation

    E-Print Network [OSTI]

    Noone, David

    is depleted. #12;Distillation: vapor and condensate Isotopic fractionation -35 -30 -25 -20 -15 -10 -5 0 5 0 0 of idealized isotopic fractionation Expression of isotopic fractionation in nature Attributing signals" 18 = (R/Rstandard-1)x1000 R = moles of H2 18O/moles of H2 16O #12;Isotopic fractionation Isotopic

  10. Determination of isotopic thorium in biological samples by combined alpha spectrometry and neutron activation analysis.

    SciTech Connect (OSTI)

    Glover, S. E. (Samuel E.)

    2003-01-01T23:59:59.000Z

    Thorium is a naturally occurring element for whom all isotopes are radioactive . Many of these isotopes are alpha emitting radionuclides, some of which have limits for inhalation lower than plutonium in current regulations . Neutron activation analysis can provide for the low-level determination of 232Th but can not determine other isotopes of dosimetric importance . Biological and environmental samples often have large quantities of materials which activate strongly, limiting the capabilities of instrumental neutron activiation analysis . This paper will discuss the application of a combined technique using alpha spectrometry and radiochemical neutron activiation analysis for the determination of isotopic thorium .

  11. Discovering Mercury Protein Modifications in Whole Proteomes Using Natural Isotope Distributions Observed in Liquid Chromatography-Tandem Mass Spectrometry

    SciTech Connect (OSTI)

    Polacco, Benjamin J.; Purvine, Samuel O.; Zink, Erika M.; LaVoie, Stephen P.; Lipton, Mary S.; Summers, Anne O.; Miller, Susan M.

    2011-08-01T23:59:59.000Z

    The identification of peptides that result from post-translational modifications is critical for understanding normal pathways of cellular regulation as well as identifying damage from, or exposures to xenobiotics, i.e. the exposome. However, because of their low abundance in proteomes, effective detection of modified peptides by mass spectrometry (MS) typically requires enrichment to eliminate false identifications. We present a new method for confidently identifying peptides with mercury (Hg)-containing adducts that is based on the influence of mercury’s seven stable isotopes on peptide isotope distributions detected by high-resolution MS. Using a pure protein and E. coli cultures exposed to phenyl mercuric acetate, we show the pattern of peak heights in isotope distributions from primary MS single scans efficiently identified Hg adducts in data from chromatographic separation coupled with tandem mass spectrometry with sensitivity and specificity greater than 90%. Isotope distributions are independent of peptide identifications based on peptide fragmentation (e.g. by SEQUEST), so both methods can be combined to eliminate false positives. Summing peptide isotope distributions across multiple scans improved specificity to 99.4% and sensitivity above 95%, affording identification of an unexpected Hg modification. We also illustrate the theoretical applicability of the method for detection of several less common elements including the essential element, selenium, as selenocysteine in peptides.

  12. Candidate processes for diluting the {sup 235}U isotope in weapons-capable highly enriched uranium

    SciTech Connect (OSTI)

    Snider, J.D.

    1996-02-01T23:59:59.000Z

    The United States Department of Energy (DOE) is evaluating options for rendering its surplus inventories of highly enriched uranium (HEU) incapable of being used to produce nuclear weapons. Weapons-capable HEU was earlier produced by enriching uranium in the fissile {sup 235}U isotope from its natural occurring 0.71 percent isotopic concentration to at least 20 percent isotopic concentration. Now, by diluting its concentration of the fissile {sup 235}U isotope in a uranium blending process, the weapons capability of HEU can be eliminated in a manner that is reversible only through isotope enrichment, and therefore, highly resistant to proliferation. To the extent that can be economically and technically justified, the down-blended uranium product will be made suitable for use as commercial reactor fuel. Such down-blended uranium product can also be disposed of as waste if chemical or isotopic impurities preclude its use as reactor fuel.

  13. Development of high through-put Sr isotope analysis for monitoring reservoir integrity for CO{sub 2} storage.

    SciTech Connect (OSTI)

    Wall, Andy; Jain, Jinesh; Stewart, Brian; Capo, Rosemary; Hakala, Alexandra J.; Hammack, Richard; Guthrie, George

    2012-01-01T23:59:59.000Z

    Recent innovations in multi-collector ICP-mass spectrometry (MC-ICP-MS) have allowed for rapid and precise measurements of isotope ratios in geological samples. Naturally occurring Sr isotopes has the potential for use in Monitoring, Verification, and Accounting (MVA) associated with geologic CO2 storage. Sr isotopes can be useful for: Sensitive tracking of brine migration; Determining seal rock leakage; Studying fluid/rock reactions. We have optimized separation chemistry procedures that will allow operators to prepare samples for Sr isotope analysis off site using rapid, low cost methods.

  14. Laser isotope separation

    DOE Patents [OSTI]

    Robinson, C. Paul (Los Alamos, NM); Jensen, Reed J. (Los Alamos, NM); Cotter, Theodore P. (Munich, DE); Boyer, Keith (Los Alamos, NM); Greiner, Norman R. (Los Alamos, NM)

    1988-01-01T23:59:59.000Z

    A process and apparatus for separating isotopes by selective excitation of isotopic species of a volatile compound by tuned laser light. A highly cooled gas of the volatile compound is produced in which the isotopic shift is sharpened and defined. Before substantial condensation occurs, the cooled gas is irradiated with laser light precisely tuned to a desired wavelength to selectively excite a particular isotopic species in the cooled gas. The laser light may impart sufficient energy to the excited species to cause it to undergo photolysis, photochemical reaction or even to photoionize. Alternatively, a two-photon irradiation may be applied to the cooled gas to induce photolysis, photochemical reaction or photoionization. The process is particularly applicable to the separation of isotopes of uranium.

  15. Photochemical isotope separation

    DOE Patents [OSTI]

    Robinson, C. Paul (Los Alamos, NM); Jensen, Reed J. (Los Alamos, NM); Cotter, Theodore P. (Los Alamos, NM); Greiner, Norman R. (Los Alamos, NM); Boyer, Keith (Los Alamos, NM)

    1987-01-01T23:59:59.000Z

    A process for separating isotopes by selective excitation of isotopic species of a volatile compound by tuned laser light. A highly cooled gas of the volatile compound is produced in which the isotopic shift is sharpened and defined. Before substantial condensation occurs, the cooled gas is irradiated with laser light precisely tuned to a desired wavelength to selectively excite a particular isotopic species in the cooled gas. The laser light may impart sufficient energy to the excited species to cause it to undergo photochemical reaction or even to photoionize. Alternatively, a two-photon irradiation may be applied to the cooled gas to induce photochemical reaction or photoionization. The process is particularly applicable to the separation of isotopes of uranium and plutonium.

  16. Photochemical isotope separation

    DOE Patents [OSTI]

    Robinson, C.P.; Jensen, R.J.; Cotter, T.P.; Greiner, N.R.; Boyer, K.

    1987-04-28T23:59:59.000Z

    A process is described for separating isotopes by selective excitation of isotopic species of a volatile compound by tuned laser light. A highly cooled gas of the volatile compound is produced in which the isotopic shift is sharpened and defined. Before substantial condensation occurs, the cooled gas is irradiated with laser light precisely tuned to a desired wavelength to selectively excite a particular isotopic species in the cooled gas. The laser light may impart sufficient energy to the excited species to cause it to undergo photochemical reaction or even to photoionize. Alternatively, a two-photon irradiation may be applied to the cooled gas to induce photochemical reaction or photoionization. The process is particularly applicable to the separation of isotopes of uranium and plutonium. 8 figs.

  17. Measurement of the cross sections for the production of the isotopes {sup 74}As, {sup 68}Ge, {sup 65}Zn, and {sup 60}Co from natural and enriched germanium irradiated with 100-MeV protons

    SciTech Connect (OSTI)

    Barabanov, I. R.; Bezrukov, L. B.; Gurentsov, V. I.; Zhuykov, B. L.; Kianovsky, S. V.; Kornoukhov, V. N.; Kohanuk, V. M.; Yanovich, E. A. [Russian Academy of Sciences, Institute for Nuclear Research (Russian Federation)

    2010-07-15T23:59:59.000Z

    The cross sections for the production of the radioactive isotopes {sup 74}As, {sup 68}Ge, {sup 65}Zn, and {sup 60}Co in metallic germanium irradiated with 100-MeV protons were measured, the experiments being performed both with germanium of natural isotopic composition and germanium enriched in the isotope {sup 76}Ge. The targets were irradiated with a proton beam at the facility for the production of radionuclides at the accelerator of the Institute for Nuclear Research (INR, Moscow). The data obtained will further be used to calculate the background of radioactive isotopes formed by nuclear cascades of cosmic-ray muons in new-generation experiments devoted to searches for the neutrinoless double-beta decay of {sup 76}Ge at underground laboratories.

  18. Measurements of Nucleon-Induced Fission Cross-Sections of Separated Tungsten Isotopes and Natural Tungsten in the 50-200 MeV Energy Region

    E-Print Network [OSTI]

    V. P. Eismont; N. P. Filatov; A. N. Smirnov; S. M. Soloviev; J. Blomgren; H. Conde; A. V. Prokofiev; S. G. Mashnik

    2005-07-07T23:59:59.000Z

    Neutron- and proton-induced fission cross-sections of separated isotopes of tungsten (182W, 183W, 184W, and 186W) and natural tungsten relative to 209Bi have been measured in the incident nucleon energy region 50-200 MeV using fission chambers based on thin-film breakdown counters (TFBC) at quasi-monoenergetic neutrons from the 7Li(p,n) reaction and at the proton beams of The Svedberg Laboratory (TSL), Uppsala University (Uppsala, Sweden). The preliminary experimental data are presented in comparison with the recent data for nuclei in the lead-bismuth region, as well as with predictions by the CEM03.01 event generator.

  19. Mechanistic studies using kinetic isotope effects

    E-Print Network [OSTI]

    Schulmeier, Brian E.

    1999-01-01T23:59:59.000Z

    Understanding reaction mechanisms is an important aspect of chemistry. A now convenient way to study reaction mechanisms is kinetic isotope effects at natural abundance. This technique circumvents the cumbersome methods of traditional isotope effect...

  20. Dispersal of Adult Culex Mosquitoes in an Urban West Nile Virus Hotspot: A Mark-Capture Study Incorporating Stable Isotope Enrichment of Natural Larval Habitats

    E-Print Network [OSTI]

    Hamer, Gabriel L.; Anderson, Tavis K.; Donovan, Danielle J.; Brawn, Jeffrey D.; Krebs, Bethany L.; Gardner, Allison M.; Ruiz, Marilyn O.; Brown, William M.; Kitron, Uriel D.; Newman, Christina M.; Goldberg, Tony L.; Walker, Edward D.

    2014-03-27T23:59:59.000Z

    Dispersal is a critical life history behavior for mosquitoes and is important for the spread of mosquito-borne disease. We implemented the first stable isotope mark-capture study to measure mosquito dispersal, focusing on Culex pipiens in southwest...

  1. Isotope separation by laser means

    DOE Patents [OSTI]

    Robinson, C. Paul (Los Alamos, NM); Jensen, Reed J. (Los Alamos, NM); Cotter, Theodore P. (Los Alamos, NM); Greiner, Norman R. (Los Alamos, NM); Boyer, Keith (Los Alamos, NM)

    1982-06-15T23:59:59.000Z

    A process for separating isotopes by selective excitation of isotopic species of a volatile compound by tuned laser light. A highly cooled gas of the volatile compound is produced in which the isotopic shift is sharpened and defined. Before substantial condensation occurs, the cooled gas is irradiated with laser light precisely tuned to a desired wavelength to selectively excite a particular isotopic species in the cooled gas. The laser light may impart sufficient energy to the excited species to cause it to undergo photochemical reaction or even to photoionize. Alternatively, a two-photon irradiation may be applied to the cooled gas to induce photochemical reaction or photoionization. The process is particularly applicable to the separation of isotopes of uranium and plutonium.

  2. Search for long-lived isomeric states in neutron-deficient thorium isotopes

    SciTech Connect (OSTI)

    Lachner, J.; Dillmann, I.; Faestermann, T.; Korschinek, G.; Poutivtsev, M.; Rugel, G. [Physik Department E12 and E15, Technische Universitaet Muenchen, D-85748 Garching (Germany)

    2008-12-15T23:59:59.000Z

    The discovery of naturally occurring long-lived isomeric states (t{sub 1/2}>10{sup 8} yr) in the neutron-deficient isotopes {sup 211,213,217,218}Th[A. Marinov et al., Phys. Rev. C 76, 021303(R) (2007)] was reexamined using accelerator mass spectrometry (AMS). Because AMS does not suffer from molecular isobaric background in the detection system, it is an extremely sensitive technique. Despite our up to two orders of magnitude higher sensitivity we cannot confirm the discoveries of neutron-deficient thorium isotopes and provide upper limits for their abundances.

  3. Search for long-lived isomeric states in neutron-deficient thorium isotopes

    E-Print Network [OSTI]

    J. Lachner; I. Dillmann; T. Faestermann; G. Korschinek; M. Poutivtsev; G. Rugel

    2009-07-01T23:59:59.000Z

    The discovery of naturally occurring long-lived isomeric states (t_1/2 > 10^8 yr) in the neutron-deficient isotopes 211,213,217,218Th [A. Marinov et al., Phys. Rev. C 76, 021303(R) (2007)] was reexamined using accelerator mass spectrometry (AMS). Because AMS does not suffer from molecular isobaric background in the detection system, it is an extremely sensitive technique. Despite our up to two orders of magnitude higher sensitivity we cannot confirm the discoveries of neutron-deficient thorium isotopes and provide upper limits for their abundances.

  4. from Isotope Production Facility

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cancer-fighting treatment gets boost from Isotope Production Facility April 13, 2012 Isotope Production Facility produces cancer-fighting actinium 2:32 Isotope cancer treatment...

  5. acfa isotope activation: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    N. Densmore a, Geosciences Websites Summary: -occur- ring radioactive isotopes such as uranium, and radium also have Maximum Contaminant Levels (MCL and 25 picoCuries per liter...

  6. Positive and inverse isotope effect on superconductivity

    E-Print Network [OSTI]

    Tian De Cao

    2009-09-04T23:59:59.000Z

    This article improves the BCS theory to include the inverse isotope effect on superconductivity. An affective model can be deduced from the model including electron-phonon interactions, and the phonon-induced attraction is simply and clearly explained on the electron Green function. The focus of this work is on how the positive or inverse isotope effect occurs in superconductors.

  7. Isotopically controlled semiconductors

    E-Print Network [OSTI]

    Haller, Eugene E.

    2006-01-01T23:59:59.000Z

    16 Isotopically Controlled Semiconductors Eugene E. Hallerof isotopically engineered semiconductors; for outstandingisotopically controlled semiconductor crystals. This article

  8. Selective photoionisation of lutetium isotopes

    SciTech Connect (OSTI)

    D'yachkov, Aleksei B; Kovalevich, S K; Labozin, Valerii P; Mironov, Sergei M; Panchenko, Vladislav Ya; Firsov, Valerii A; Tsvetkov, G O; Shatalova, G G [National Research Centre 'Kurchatov Institute', Moscow (Russian Federation)

    2012-10-31T23:59:59.000Z

    A three-stage laser photoionisation scheme intended for enriching the {sup 176}Lu isotope from natural lutetium was considered. An investigation was made of the hyperfine structure of the second excited state 5d6s7s {yields} {sup 4}D{sub 3/2} with an energy of 37194 cm{sup -1} and the autoionisation state with an energy of 53375 cm{sup -1} of the {sup 176}Lu and {sup 175}Lu isotopes. The total electron momentum of the autoionisation level and the constant A of hyperfine magnetic interaction were determined. Due to a small value of the isotopic shift between {sup 176}Lu and {sup 175}Lu, appreciable selectivity of their separation may be achieved with individual hyperfine structure components. The first tentative enrichment of the 176Lu isotope was performed to a concentration of 60 % - 70 %. (laser applications and other topics in quantum electronics)

  9. Stable Isotope Signatures for Microbial Forensics

    SciTech Connect (OSTI)

    Kreuzer, Helen W.

    2012-01-03T23:59:59.000Z

    The isotopic distribution of the atoms composing the molecules of microorganisms is a function of the substrates used by the organisms. The stable isotope content of an organism is fixed so long as no further substrate consumption and biosynthesis occurs, while the radioactive isotopic content decays over time. The distribution of stable isotopes of C, N, O and H in heterotrophic microorganisms is a direct function of the culture medium, and therefore the stable isotope composition can be used to associate samples with potential culture media and also with one another. The 14C content depends upon the 14C content, and therefore the age, of the organic components of the culture medium, as well as on the age of the culture itself. Stable isotope signatures can thus be used for sample matching, to associate cultures with specific growth media, and to predict characteristics of growth media.

  10. Atom trap trace analysis of krypton isotopes

    SciTech Connect (OSTI)

    Bailey, K.; Chen, C. Y.; Du, X.; Li, Y. M.; Lu, Z.-T.; O'Connor, T. P.; Young, L.

    1999-11-17T23:59:59.000Z

    A new method of ultrasensitive isotope trace analysis has been developed. This method, based on the technique of laser manipulation of neutral atoms, has been used to count individual {sup 85}Kr and {sup 81}Kr atoms present in a natural krypton gas sample with isotopic abundances in the range of 10{sup {minus}11} and 10{sup {minus}13}, respectively. This method is free of contamination from other isotopes and elements and can be applied to several different isotope tracers for a wide range of applications. The demonstrated detection efficiency is 1 x 10{sup {minus}7}. System improvements could increase the efficiency by many orders of magnitude.

  11. The plasma centrifuge: A compact, low cost, stable isotope separator. Phase 2 final technical report, September 15, 1991--September 14, 1995

    SciTech Connect (OSTI)

    Guss, W.

    1996-09-05T23:59:59.000Z

    Enriched stable isotopes are required for production of radionuclides as well as for research and diagnostic uses. Science Research Laboratory (SRL) has developed a plasma centrifuge for moderate throughput of enriched stable isotopes, such as {sup 13}C, {sup 17}O, {sup 18}O, and {sup 203}Tl, for medical as well as other applications. Dwindling isotope stocks have restricted the use of enriched isotopes and their associated labeled organic molecules in medical imaging to very few research facilities because of high costs of isotope separation. With the introduction of the plasma centrifuge separator, the cost per separated gram of even rarely occurring isotopes ({le} 1% natural abundance) is potentially many times lower than with other separation technologies (cryogenic distillation and calutrons). The centrifuge is a simple, robust, pulsed electrical discharge device that has successfully demonstrated isotope separation of small (mg) quantities of {sup 26}Mg. Based on the results of the Phase 2 program, modest enhancements to the power supplies and cooling systems, a centrifuge separator will have high repetition rate (60 pps) and high duty cycle (60%) to produce in one month kilogram quantities of highly enriched stable isotopes. The centrifuge may be used in stand-alone operation or could be used as a high-throughput pre-separation stage with calutrons providing the final separation.

  12. Nonequilibrium clumped isotope signals in microbial methane

    E-Print Network [OSTI]

    Wang, David T.

    Methane is a key component in the global carbon cycle with a wide range of anthropogenic and natural sources. Although isotopic compositions of methane have traditionally aided source identification, the abundance of its ...

  13. Stable Isotope Enrichment Capabilities at ORNL

    SciTech Connect (OSTI)

    Egle, Brian [ORNL; Aaron, W Scott [ORNL; Hart, Kevin J [ORNL

    2013-01-01T23:59:59.000Z

    The Oak Ridge National Laboratory (ORNL) and the US Department of Energy Nuclear Physics Program have built a high-resolution Electromagnetic Isotope Separator (EMIS) as a prototype for reestablishing a US based enrichment capability for stable isotopes. ORNL has over 60 years of experience providing enriched stable isotopes and related technical services to the international accelerator target community, as well as medical, research, industrial, national security, and other communities. ORNL is investigating the combined use of electromagnetic and gas centrifuge isotope separation technologies to provide research quantities (milligram to several kilograms) of enriched stable isotopes. In preparation for implementing a larger scale production facility, a 10 mA high-resolution EMIS prototype has been built and tested. Initial testing of the device has simultaneously collected greater than 98% enriched samples of all the molybdenum isotopes from natural abundance feedstock.

  14. Naturally Occurring Melanin Synthesis Regulators and Their Modes of Action

    E-Print Network [OSTI]

    Satooka, Hiroki

    2011-01-01T23:59:59.000Z

    were as follows; Deverosil ODS-UG-5 (Nomura Chemical, CO. ,were as follows; Deverosil ODS-UG-5 (Nomura Chemical, CO. ,were as follows; Develosil ODS-UG-5 (Nomura Chemical, CO. ,

  15. The Highly Cooperative Folding of Small Naturally Occurring Proteins Is

    E-Print Network [OSTI]

    Baker, David

    Varani,2,3 Tobin Sosnick,4 and David Baker3,5, * 1 Molecular and Cellular Biology Program 2 Department 60637, USA 5 Howard Hughes Medical Institute, University of Washington, Seattle, WA 98195, USA 6 Present, this is now possible for protein folding (Kuhlman and Baker, 2004). Protein structures are stabilized

  16. Naturally Occurring Melanin Synthesis Regulators and Their Modes of Action

    E-Print Network [OSTI]

    Satooka, Hiroki

    2011-01-01T23:59:59.000Z

    Kinetics of mushroom tyrosinase inhibition by quercetin. J.F. ; Garcia-Carmona, F. , Tyrosinase: a comprehensive reviewSharma, N. , Mushroom tyrosinase: Recent prospects. J. Agr.

  17. Isotopic constraints on off-site migration of landfill CH{sub 4}

    SciTech Connect (OSTI)

    Desrocher, S.; Lollar, B.S. [Univ. of Toronto, Ontario (Canada). Dept. of Geology

    1998-09-01T23:59:59.000Z

    Occurrences of CH{sub 4} in residential areas in the vicinity of the Beare Road landfill, Toronto, Canada, have raised public concern about potential off-site migration of CH{sub 4} from the landfill site. Carbon isotopic analysis of dissolved and gas phase CH{sub 4} at the Beare Road site, however, indicates that CH{sub 4} in the ground water systems in the vicinity of the landfill is related to naturally occurring microbial methanogenesis within these geologic units, rather than to contamination by landfill CH{sub 4}. CH{sub 4} gas in the landfill and landfill cover has {delta}{sup 13}C values typical of microbially produced gas. Concentrations of CH{sub 4} found in deep ground water in the Scarborough, Don, and Whitby Formations underlying the landfill are isotopically distinct from the landfill gases. They are isotopically and compositionally similar, however, to naturally occurring microbial CH{sub 4} identified in organic-rich glacial deposits throughout Ontario. The lack of any significant CH{sub 4} concentrations or concentration gradients in the upper tin zone between the landfill and the deep ground water aquifer is further evidence that no transport between the landfill and deep ground water is occurring.

  18. Comparison of isotopic transmutation modelling codes

    E-Print Network [OSTI]

    Beard, Carl Allen

    1990-01-01T23:59:59.000Z

    . Numerical solutions to the equations that govern isotopic transmutation can be obtained in several ways. Each method possesses a certain amount of intrinsic error which is inherent in the solution scheme, but which can also vary depending upon... of the removed nuclide if it falls between two long-lived isotopes, or by adding the initial concentration of the short-lived isotope to the first long-lived nuclide which occurs in the production chain. In this second case, the final contribution from...

  19. Isotope Science and Production

    E-Print Network [OSTI]

    Isotope Science and Production 35 years of experience in isotope production, processing, and applications. Llllll Committed to the safe and reliable production of radioisotopes, products, and services nuclear materials in trucks and cargo containers. Isotopes for Threat Reduction Isotope production at Los

  20. Stable isotope studies

    SciTech Connect (OSTI)

    Ishida, T.

    1992-01-01T23:59:59.000Z

    The research has been in four general areas: (1) correlation of isotope effects with molecular forces and molecular structures, (2) correlation of zero-point energy and its isotope effects with molecular structure and molecular forces, (3) vapor pressure isotope effects, and (4) fractionation of stable isotopes. 73 refs, 38 figs, 29 tabs.

  1. Detection of the Natural Alpha Decay of Tungsten

    E-Print Network [OSTI]

    C. Cozzini; G. Angloher; C. Bucci; F. von Feilitzsch; D. Hauff; S. Henry; Th. Jagemann; J. Jochum; H. Kraus; B. Majorovits; V. Mikhailik; J. Ninkovic; F. Petricca; W. Potzel; F. Proebst; Y. Ramachers; W. Rau; M. Razeti; W. Seidel; M. Stark; L. Stodolsky; A. J. B. Tolhurst; W. Westphal; H. Wulandari

    2004-10-26T23:59:59.000Z

    The natural alpha decay of 180W has been unambiguously detected for the first time. The alpha peak is found in a (gamma,beta and neutron)-free background spectrum. This has been achieved by the simultaneous measurement of phonon and light signals with the CRESST cryogenic detectors. A half-life of T1/2 = (1.8 +- 0.2) x 10^18 y and an energy release of Q = (2516.4 +- 1.1 (stat.) +- 1.2 (sys.)) keV have been measured. New limits are also set on the half-lives of the other naturally occurring tungsten isotopes.

  2. Augmenting real data with synthetic data: an application in assessing radio-isotope identification algorithms

    SciTech Connect (OSTI)

    Burr, Tom L [Los Alamos National Laboratory; Hamada, Michael [Los Alamos National Laboratory; Graves, Todd [Los Alamos National Laboratory; Myers, Steve [Los Alamos National Laboratory

    2008-01-01T23:59:59.000Z

    The performance of Radio-Isotope Identification (RIID) algorithms using gamma spectroscopy is increasingly important. For example, sensors at locations that screen for illicit nuclear material rely on isotope identification to resolve innocent nuisance alarms arising from naturally occurring radioactive material. Recent data collections for RIID testing consist of repeat measurements for each of several scenarios to test RIID algorithms. Efficient allocation of measurement resources requires an appropriate number of repeats for each scenario. To help allocate measurement resources in such data collections for RIID algorithm testing, we consider using only a few real repeats per scenario. In order to reduce uncertainty in the estimated RIID algorithm performance for each scenario, the potential merit of augmenting these real repeats with realistic synthetic repeats is also considered. Our results suggest that for the scenarios and algorithms considered, approximately 10 real repeats augmented with simulated repeats will result in an estimate having comparable uncertainty to the estimate based on using 60 real repeats.

  3. Coastal and Marine Nitrogen Sources Shift Isotopic Baselines in Pelagic Food Webs of the Gulf of Mexico

    E-Print Network [OSTI]

    Dorado, Samuel

    2012-07-16T23:59:59.000Z

    variability to the degree of freshwater influence. Published food web data from these two environments were then assessed to establish whether isotopic baseline shifts observed in our data occur at an ecosystem level. Isotope values of the POM...

  4. Carbon isotope ratios of organic compound fractions in oceanic suspended particles

    E-Print Network [OSTI]

    Hwang, Jeomshik; Druffel, Ellen R. M

    2006-01-01T23:59:59.000Z

    Radiocarbon evidence of fossil-carbon cycling in sediments1968), Metabolic fractionation of carbon isotopes in marineof particulate organic carbon using bomb 14 C, Nature,

  5. Chemical and isotopic characteristics of the coso east flank...

    Open Energy Info (EERE)

    and nature of the heat source Jump to: navigation, search OpenEI Reference LibraryAdd to library Conference Proceedings: Chemical and isotopic characteristics of the coso east...

  6. Hybrid isotope separation scheme

    DOE Patents [OSTI]

    Maya, J.

    1991-06-18T23:59:59.000Z

    A method is described for yielding selectively a desired enrichment in a specific isotope including the steps of inputting into a spinning chamber a gas from which a scavenger, radiating the gas with a wave length or frequency characteristic of the absorption of a particular isotope of the atomic or molecular gas, thereby inducing a photochemical reaction between the scavenger, and collecting the specific isotope-containing chemical by using a recombination surface or by a scooping apparatus. 2 figures.

  7. Hybrid isotope separation scheme

    DOE Patents [OSTI]

    Maya, Jakob (Brookline, MA)

    1991-01-01T23:59:59.000Z

    A method of yielding selectively a desired enrichment in a specific isotope including the steps of inputting into a spinning chamber a gas from which a scavenger, radiating the gas with a wave length or frequency characteristic of the absorption of a particular isotope of the atomic or molecular gas, thereby inducing a photochemical reaction between the scavenger, and collecting the specific isotope-containing chemical by using a recombination surface or by a scooping apparatus.

  8. Stable isotope enrichment

    ScienceCinema (OSTI)

    Egle, Brian

    2014-07-15T23:59:59.000Z

    Brian Egle is working to increase the nation's capacity to produce stable isotopes for use including medicine, industry and national security.

  9. Isotopically controlled semiconductors

    E-Print Network [OSTI]

    Haller, E.E.

    2004-01-01T23:59:59.000Z

    and phonons in semiconductors,” J. Non-Cryst. Solids 141 (LVM) Spectroscopy of Semiconductors,” Mat. Res. Soc. Symp.Isotopically Engineered Semiconductors – New Media for the

  10. Stable isotope enrichment

    SciTech Connect (OSTI)

    Egle, Brian

    2014-07-14T23:59:59.000Z

    Brian Egle is working to increase the nation's capacity to produce stable isotopes for use including medicine, industry and national security.

  11. Isotopically selective, Doppler-free, saturation spectroscopy of lutetium isotopes via resonance ionization mass spectrometry

    SciTech Connect (OSTI)

    Fearey, B.L.; Parent, D.C.; Keller, R.A.; Miller, C.M.

    1988-01-01T23:59:59.000Z

    A new technique utilizing RIMS to obtain very high resolution atomic spectra with isotopic selectivity has been demonstrated. This technique allows the precise determination of HF splitting constants, limited only by the transition's natural linewidth. In addition, it is also feasible with this technique to accurately determine atomic isotope shifts. The exact determination of HF component line positions provides data for isotopically selective ionization which, in turn, will increase RIMS' dynamic range. Future work includes the incorporation of a /open quotes/vibrating/close quotes/ mirror and the study of rarer isotopes, i.e., /sup 174/Lu, /sup 173/Lu, /sup 172/Lu, /sup 171/Lu, and possibly, /sup 170/Lu. 13 refs., 3 figs.

  12. Discovery of the Tungsten Isotopes

    E-Print Network [OSTI]

    A. Fritsch; J. Q. Ginepro; M. Heim; A. Schuh; A. Shore; M. Thoennessen

    2009-03-25T23:59:59.000Z

    Thirty-five tungsten isotopes have so far been observed; the discovery of these isotopes is discussed. For each isotope a brief summary of the first refereed publication, including the production and identification method, is presented.

  13. Discovery of the Titanium Isotopes

    E-Print Network [OSTI]

    D. Meierfrankenfeld; M. Thoennessen

    2010-09-08T23:59:59.000Z

    Twentyfive titanium isotopes have so far been observed; the discovery of these isotopes is discussed. For each isotope a brief summary of the first refereed publication, including the production and identification method, is presented.

  14. Discovery of the Tin Isotopes

    E-Print Network [OSTI]

    S. Amos; M. Thoennessen

    2010-09-08T23:59:59.000Z

    Thirty-eight tin isotopes have so far been observed; the discovery of these isotopes is discussed. For each isotope a brief summary of the first refereed publication, including the production and identification method, is presented.

  15. Discovery of the tungsten isotopes

    SciTech Connect (OSTI)

    Fritsch, A.; Ginepro, J.Q.; Heim, M.; Schuh, A.; Shore, A. [National Superconducting Cyclotron Laboratory and Department of Physics and Astronomy, Michigan State University, East Lansing, MI 48824 (United States); Thoennessen, M. [National Superconducting Cyclotron Laboratory and Department of Physics and Astronomy, Michigan State University, East Lansing, MI 48824 (United States)], E-mail: thoennessen@nscl.msu.edu

    2010-05-15T23:59:59.000Z

    Thirty-five tungsten isotopes have been observed so far and the discovery of these isotopes is discussed here. For each isotope a brief summary of the first refereed publication, including the production and identification method, is presented.

  16. Discovery of the Tungsten Isotopes

    E-Print Network [OSTI]

    Fritsch, A; Heim, M; Schuh, A; Shore, A; Thoennessen, M

    2009-01-01T23:59:59.000Z

    Thirty-five tungsten isotopes have so far been observed; the discovery of these isotopes is discussed. For each isotope a brief summary of the first refereed publication, including the production and identification method, is presented.

  17. Coal fly ash interaction with environmental fluids: Geochemical and strontium isotope results from combined column and batch leaching experiments

    SciTech Connect (OSTI)

    Brubaker, Tonya M.; Stewart, Brian W.; Capo, Rosemary C.; Schroeder, Karl T.; Chapman, Elizabeth C.; Spivak-Birndorf, Lev J.; Vesper, Dorothy J.; Cardone, Carol R.; Rohar, Paul C.

    2013-05-01T23:59:59.000Z

    The major element and Sr isotope systematics and geochemistry of coal fly ash and its interactions with environmental waters were investigated using laboratory flow-through column leaching experiments (sodium carbonate, acetic acid, nitric acid) and sequential batch leaching experiments (water, acetic acid, hydrochloric acid). Column leaching of Class F fly ash samples shows rapid release of most major elements early in the leaching procedure, suggesting an association of these elements with soluble and surface bound phases. Delayed release of certain elements (e.g., Al, Fe, Si) signals gradual dissolution of more resistant silicate or glass phases as leaching continues. Strontium isotope results from both column and batch leaching experiments show a marked increase in {sup 87}Sr/{sup 86}Sr ratio with continued leaching, yielding a total range of values from 0.7107 to 0.7138. For comparison, the isotopic composition of fluid output from a fly ash impoundment in West Virginia falls in a narrow range around 0.7124. The experimental data suggest the presence of a more resistant, highly radiogenic silicate phase that survives the combustion process and is leached after the more soluble minerals are removed. Strontium isotopic homogenization of minerals in coal does not always occur during the combustion process, despite the high temperatures encountered in the boiler. Early-released Sr tends to be isotopically uniform; thus the Sr isotopic composition of fly ash could be distinguishable from other sources and is a useful tool for quantifying the possible contribution of fly ash leaching to the total dissolved load in natural surface and ground waters.

  18. (Carbon isotope fractionation inplants)

    SciTech Connect (OSTI)

    O'Leary, M.H.

    1990-01-01T23:59:59.000Z

    The objectives of this research are: To develop a theoretical and experimental framework for understanding isotope fractionations in plants; and to develop methods for using this isotope fractionation for understanding the dynamics of CO{sub 2} fixation in plants. Progress is described.

  19. Heavy-atom isotope effects on the acid-catalyzed hydrolysis of methyl benzoate

    SciTech Connect (OSTI)

    Marlier, J.F.; O'Leary, M.H.

    1981-05-08T23:59:59.000Z

    Results of the use of a previously reported technique of four-heavy atom isotope effects for study of the acid-catalyzed hydrolysis of methyl benzoate are reported. Ether oxygen and methyl carbon isotope effects on the reaction were measured by the usual natural-abundance isotope-ratio technique. The carbonyl oxygen isotope effect was measured by the pseudo-natural-abundance double-label method as was the carbonyl carbon isotope effect. The results led to the assumption that the hydrolysis of methyl benzoate proceeds by way of a tetrahedral intermediate. The small amount of oxygen exchange with the solvent that accompanies the hydrolysis indicated that it is intermediate formation rather than decomposition that is rate determining. The small magnitude of the observed carbon isotope effect on the acid-catalyzed hydrolysis of methyl benzoate compared to carbon isotope effects on other reactions of this compound indicate that the transition state is relatively reactant-like. (BLM)

  20. High-purity, isotopically enriched bulk silicon

    E-Print Network [OSTI]

    2004-01-01T23:59:59.000Z

    Russia. The stated isotope enrichments are summarized inenrichments >99% have been achieved for each isotope andthe enrichment is highest, are presented. isotope at. % nat.

  1. Atomic vapor laser isotope separation of lead-210 isotope

    DOE Patents [OSTI]

    Scheibner, K.F.; Haynam, C.A.; Johnson, M.A.; Worden, E.F.

    1999-08-31T23:59:59.000Z

    An isotopically selective laser process and apparatus for removal of Pb-210 from natural lead that involves a one-photon near-resonant, two-photon resonant excitation of one or more Rydberg levels, followed by field ionization and then electrostatic extraction. The wavelength to the near-resonant intermediate state is counter propagated with respect to the second wavelength required to populate the final Rydberg state. This scheme takes advantage of the large first excited state cross section, and only modest laser fluences are required. The non-resonant process helps to avoid two problems: first, stimulated Raman Gain due to the nearby F=3/2 hyperfine component of Pb-207 and, second, direct absorption of the first transition process light by Pb-207. 5 figs.

  2. Atomic vapor laser isotope separation of lead-210 isotope

    DOE Patents [OSTI]

    Scheibner, Karl F. (Tracy, CA); Haynam, Christopher A. (Pleasanton, CA); Johnson, Michael A. (Pleasanton, CA); Worden, Earl F. (Diablo, CA)

    1999-01-01T23:59:59.000Z

    An isotopically selective laser process and apparatus for removal of Pb-210 from natural lead that involves a one-photon near-resonant, two-photon resonant excitation of one or more Rydberg levels, followed by field ionization and then electrostatic extraction. The wavelength to the near-resonant intermediate state is counter propagated with respect to the second wavelength required to populate the final Rydberg state. This scheme takes advantage of the large first excited state cross section, and only modest laser fluences are required. The non-resonant process helps to avoid two problems: first, stimulated Raman Gain due to the nearby F=3/2 hyperfine component of Pb-207 and, second, direct absorption of the first transition process light by Pb-207.

  3. How low-energy fusion can occur

    E-Print Network [OSTI]

    B. Ivlev

    2012-12-04T23:59:59.000Z

    Fusion of two deuterons of room temperature energy is discussed. The nuclei are in vacuum with no connection to any external source (electric or magnetic field, illumination, surrounding matter, traps, etc.) which may accelerate them. The energy of two nuclei is conserved and remains small during the motion through the Coulomb barrier. The penetration through this barrier, which is the main obstacle for low-energy fusion, strongly depends on a form of the incident flux on the Coulomb center at large distances from it. In contrast to the usual scattering, the incident wave is not a single plane wave but the certain superposition of plane waves of the same energy and various directions, for example, a convergent conical wave. The wave function close to the Coulomb center is determined by a cusp caustic which is probed by de Broglie waves. The particle flux gets away from the cusp and moves to the Coulomb center providing a not small probability of fusion (cusp driven tunneling). Getting away from a caustic cusp also occurs in optics and acoustics.

  4. Evaluation of the isotopic equilibrium between lactate and pyruvate

    SciTech Connect (OSTI)

    Wolfe, R.R.; Jahoor, F.; Miyoshi, H. (Univ. of Texas Medical Branch, Galveston (USA))

    1988-04-01T23:59:59.000Z

    When an isotopic tracer is infused for the purpose of determining the rate of turnover or oxidation of a substrate, it is assumed that the resulting isotopic enrichment of the trace will reflect kinetics of only the pool of interest. However, this may not be the case when carbon-labeled lactate is infused, since rapid isotopic exchange with the intracellular pyruvate and alanine pools could potentially occur. Therefore the authors have determined the extent of isotopic exchange occurring during the infusion of (3-{sup 13}C)lactate into six anesthetized dogs. In the steady state, pyruvate enrichment was 91 {plus minus} 2.2% of the lactate enrichment, and alanine enrichment was 81 {plus minus} 3.3% of the pyruvate enrichment and 72 {plus minus} 2.6% of the lactate enrichment. In contrast, when (3-{sup 13}C)alanine was infused, pyruvate (and lactate) enrichment was 9.9% of the alanine enrichment. They therefore conclude that there is rapid isotopic equilibration between lactate and pyruvate but that interaction with alanine reflects the true metabolic flux rates, rather than isotopic exchange. Consequently, lactate kinetics, as traditionally determined, more accurately reflect whole body pyruvate kinetics.

  5. Transportation of medical isotopes

    SciTech Connect (OSTI)

    Nielsen, D.L.

    1997-11-19T23:59:59.000Z

    A Draft Technical Information Document (HNF-1855) is being prepared to evaluate proposed interim tritium and medical isotope production at the Fast Flux Test Facility (FFTF). This assessment examines the potential health and safety impacts of transportation operations associated with the production of medical isotopes. Incident-free and accidental impacts are assessed using bounding source terms for the shipment of nonradiological target materials to the Hanford Site, the shipment of irradiated targets from the FFTF to the 325 Building, and the shipment of medical isotope products from the 325 Building to medical distributors. The health and safety consequences to workers and the public from the incident-free transportation of targets and isotope products would be within acceptable levels. For transportation accidents, risks to works and the public also would be within acceptable levels. This assessment is based on best information available at this time. As the medical isotope program matures, this analysis will be revised, if necessary, to support development of a final revision to the Technical Information Document.

  6. Identification of the source of methane at a hazardous waste treatment facility using isotopic analysis

    SciTech Connect (OSTI)

    Hackley, K.C.; Liu, C.L. (Illinois State Geological Survey, Peabody, IL (United States)); Trainor, D.P. (Dames and Moore, Madison, WI (United States))

    1992-01-01T23:59:59.000Z

    Isotopic analyses have been used to determine the source of methane in subsurface sediments at a hazardous waste treatment facility in the Lake Calumet area of Chicago, Illinois. The study area is surrounded by landfills and other waste management operations and has a long history of waste disposal. The facility property consists of land constructed of approximately 15 feet of fill placed over lake sediments. The fill is underlain by successively older lacustrine and glacial till deposits to a maximum depth of approximately 80 feet. During a subsurface investigation of the site performed for a RCRA Facility Investigation of former solid waste management units (SWMUs) in the fill, significant quantities of methane were encountered in the natural deposits. Gas samples were collected from the headspace of 11 piezometers screened at depths of approximately 30, 40, and 50 feet beneath the surface. Methane concentrations up to 75% by volume were observed in some of the piezometers. Stable isotope analyses were completed on methane and associated CO[sub 2] separated from the gas samples. Radiocarbon (C-14) analyses were also completed on several of the samples. The delta C-13 results for the intermediate and deep zones are indicative of methane produced by microbial reduction of CO[sub 2]. The methane occurring in the shallow zone appears to be a mixture of methane from the intermediate zone and methane produced by microbial fermentation of naturally (nonanthropogenic) buried organic matter within the shallow lacustrine sediments. According to the isotopic and chemical results, the methane does not appear to be related to gas generation from nearby landfills or from organic wastes previously placed in the former facility SWMUs.

  7. Seasonal cycle of carbon dioxide and its isotopic composition in an urban atmosphere: Anthropogenic and biogenic effects

    E-Print Network [OSTI]

    Ehleringer, Jim

    and summer. The effects of gasoline combustion, natural gas combustion, and biogenic respiration of plants isotopic tracers. The calculations showed large contributions of natural gas combustion in the winter burning, and fossil fuel combustion impart carbon and oxygen isotope signals to the atmosphere that can

  8. Modeling atmospheric stable water isotopes and the potential for constraining cloud processes and

    E-Print Network [OSTI]

    a significant part of the observed offset from pure Rayleigh distillation. Isotope fields are shown cycle. These ratios are primarily affected by the fractionation occurring at changes of phase

  9. alpha particle-emitting isotopes: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    -occur- ring radioactive isotopes such as uranium, and radium also have Maximum Contaminant Levels (MCL and 25 picoCuries per liter (pCiL). Although activities were below the...

  10. 7, 1271512750, 2007 Hydrogen isotope

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    imply that there must be a very strong concomitant isotopic enrichment in the radical channel (CH2O + hACPD 7, 12715­12750, 2007 Hydrogen isotope fractionation in the photolysis of formaldehyde T. S a Creative Commons License. Atmospheric Chemistry and Physics Discussions Hydrogen isotope fractionation

  11. Isotopic studies of sources of uranium in sediments of the Ashtabula River, Ohio, U.S.A.

    SciTech Connect (OSTI)

    Ketterer, M.E.; Wetzel, W.C.; Layman, R.R.; Matisoff, G.; Bonniwell, E.C.

    2000-03-15T23:59:59.000Z

    Uranium contamination of anthropogenic origin has been identified in unconsolidated sediment of a 1.5 km portion of the Ashtabula River near its confluence with Lake Erie. Uranium concentrations as high as 188 {mu}g/g dry sediment are present. A small tributary of the Ashtabula River, Fields Brook, is the apparent point of origin of the uranium in the Ashtabula River sediments. {sup 137}Cs dating of a sediment core indicates that the U contamination occurred during the post-1964 time frame. The horizons of elevated U concentration also exhibit > 10x elevations in Zr, Nb, Hf, Ta, and W. {sup 238}U/{sup 235}U isotopic ratios indicate that the uranium is largely but not exclusively of natural composition. Distinct horizons of slightly {sup 235}U-depleted ({sup 238}U/{sup 235}U > 137.88) and slightly {sup 235}U-enriched ({sup 238}U/{sup 235}U < 137.88) uranium are also present. {sup 210}Pb activities and {sup 232}Th/{sup 230}Th isotopic measurements indicate that a significant portion of the uranium contains {sup 238}U daughters in approximate secular equilibrium. It is inferred that at least two distinct sources of anthropogenic U contamination exist: (a) discharges from the processing of enriched and depleted U metal by a DOE contractor facility and (B) U-bearing wastes from the production of TiO{sub 2} from limonite and associated minerals. These isotopic methodologies are potentially useful in settings where releases of nonnatural {sup 238}U/{sup 235}U composition materials and/or naturally occurring radioactive material (NORM) have taken place.

  12. Isotope Ratio Triangulation: A Method for Determining Uranium Isotope Ratios and Application to the Search for Uranium Isotope Anomalies in the Mineral Titanite 

    E-Print Network [OSTI]

    Hill, Joseph Roger

    2014-11-10T23:59:59.000Z

    -evaluation of the isotope ratio of “natural” uranium value used in geochronology has called into question both this value and its constancy in U-bearing minerals, most notably titanite, formed in high-temperature magmatic and metamorphic settings. A 233U-236U spike may...

  13. Rare Isotopes in Cosmic Explosions and Accelerators on Earth

    ScienceCinema (OSTI)

    Hendrik Schatz

    2010-01-08T23:59:59.000Z

    Rare isotopes are nature?s stepping stones to produce the heavy elements, and they are produced in large quantities in stellar explosions. Despite their fleeting existence, they shape the composition of the universe and the observable features of stellar explosions. The challenge for nuclear science is to produce and study the very same rare isotopes so as to understand the origin of the elements and a range of astronomical observations. I will review the progress that has been made to date in astronomy and nuclear physics, and the prospects of finally addressing many of the outstanding issues with the future Facility for Rare Isotope Beams (FRIB), which DOE will build at Michigan State University.

  14. Biogeochemistry of Isotopically-distinct Sources of Lead in a Former WWII Aerial Gunnery Range 

    E-Print Network [OSTI]

    McBee, Jayme M

    2014-01-08T23:59:59.000Z

    Isotopic composition and concentrations of Pb are used to identify sources of anthropogenic and natural Pb and to assess Pb bioavailability in soils and native plants at a former military installation that served as a WWII ...

  15. Biogeochemistry of Isotopically-distinct Sources of Lead in a Former WWII Aerial Gunnery Range

    E-Print Network [OSTI]

    McBee, Jayme M

    2014-01-08T23:59:59.000Z

    Isotopic composition and concentrations of Pb are used to identify sources of anthropogenic and natural Pb and to assess Pb bioavailability in soils and native plants at a former military installation that served as a WWII era aerial gunnery range...

  16. Descriptions of selected accidents that have occurred at nuclear reactor facilities

    SciTech Connect (OSTI)

    Bertini, H.W.

    1980-04-01T23:59:59.000Z

    This report was prepared at the request of the President's Commission on the Accident at Three Mile Island to provide the members of the Commission with some insight into the nature and significance of accidents that have occurred at nuclear reactor facilities in the past. Toward that end, this report presents a brief description of 44 accidents which have occurred throughout the world and which meet at least one of the severity criteria that were established.

  17. ISOTOPE METHODS IN HOMOGENEOUS CATALYSIS.

    SciTech Connect (OSTI)

    BULLOCK,R.M.; BENDER,B.R.

    2000-12-01T23:59:59.000Z

    The use of isotope labels has had a fundamentally important role in the determination of mechanisms of homogeneously catalyzed reactions. Mechanistic data is valuable since it can assist in the design and rational improvement of homogeneous catalysts. There are several ways to use isotopes in mechanistic chemistry. Isotopes can be introduced into controlled experiments and followed where they go or don't go; in this way, Libby, Calvin, Taube and others used isotopes to elucidate mechanistic pathways for very different, yet important chemistries. Another important isotope method is the study of kinetic isotope effects (KIEs) and equilibrium isotope effect (EIEs). Here the mere observation of where a label winds up is no longer enough - what matters is how much slower (or faster) a labeled molecule reacts than the unlabeled material. The most careti studies essentially involve the measurement of isotope fractionation between a reference ground state and the transition state. Thus kinetic isotope effects provide unique data unavailable from other methods, since information about the transition state of a reaction is obtained. Because getting an experimental glimpse of transition states is really tantamount to understanding catalysis, kinetic isotope effects are very powerful.

  18. A Comparison of Shell Model Results for Some properties of the Even-Even Ge Isotopes

    E-Print Network [OSTI]

    S. J. Q. Robinson; L. Zamick; Y. Y. Sharon

    2010-07-13T23:59:59.000Z

    In this work we examine two recent effective shell model interactions, JUN45 and JJ4B, that have been proposed for use in the $f_{5/2},p_{3/2}, p_{1/2}, g_{9/2}$ model space for both protons and neutrons. We calculate a number of quantities that did not enter into the fits undertaken to fix the parameters of both interactions. In particular we consider static quadrupole moments (Q's) of excited states of the even-even $^{70-76}$Ge isotopes, as well as the B(E2) values in these nuclei. (We have previously studied $^{70}$Zn isotopes using JJ4B.) Some striking disagreements between the JUN45 prediction and the experimental results had already been noted for the quadrupole moments of the $2_1^+$ states of these nuclei. We investigate whether these discrepancies also occur for the JJ4B interaction. Subsequently, we also apply both interactions to calculate the Q's of some more highly excited states and compare the two sets of predictions regarding the nature of the nuclear states under consideration. In order to gain insight into these more complex large-scale shell-model calculations, we examine the corresponding and much simpler single-j shell model calculations in the $g_{9/2}$ neutron shell.

  19. Laser isotope separation of erbium and other isotopes

    DOE Patents [OSTI]

    Haynam, Christopher A. (3035 Ferdale Ct., Pleasanton, CA 94566); Worden, Earl F. (117 Vereda del Ciervo, Diablo, CA 94528)

    1995-01-01T23:59:59.000Z

    Laser isotope separation is accomplished using at least two photoionization pathways of an isotope simultaneously, where each pathway comprises two or more transition steps. This separation method has been applied to the selective photoionization of erbium isotopes, particularly for the enrichment of .sup.167 Er. The hyperfine structure of .sup.167 Er was used to find two three-step photoionization pathways having a common upper energy level.

  20. Laser isotope separation of erbium and other isotopes

    DOE Patents [OSTI]

    Haynam, C.A.; Worden, E.F.

    1995-08-22T23:59:59.000Z

    Laser isotope separation is accomplished using at least two photoionization pathways of an isotope simultaneously, where each pathway comprises two or more transition steps. This separation method has been applied to the selective photoionization of erbium isotopes, particularly for the enrichment of {sup 167}Er. The hyperfine structure of {sup 167}Er was used to find two three-step photoionization pathways having a common upper energy level. 3 figs.

  1. Compilation of the Dakota Aquifer Project isotope data and publications: The Isotope Hydrology Program of the Isotope Sciences Division

    SciTech Connect (OSTI)

    Davisson, M.L.; Smith, D.K.; Hudson, G.B.; Niemeyer, S. [Lawrence Livermore National Lab., CA (United States); Macfarlane, P.A.; Whittemore, D.O. [Kansas Geological Survey, Lawrence, KS (United States)

    1995-01-01T23:59:59.000Z

    In FY92 the then Nuclear Chemistry Division embarked on a scientific collaboration with the Kansas Geological Survey (KGS) to characterize with isotope techniques groundwater of the Dakota Formation of Kansas. The Dakota Formation is a Cretaceous-aged marine sandstone hosting potable groundwater in most regions of Kansas whose use will serve to partially offset the severe overdraft problems in the overlying Ogallala Formation. The isotope characterization of the Dakota groundwater has generated data that delineates sources, ages, and subsurface controls on the water quality. Initial interpretations of the data have been published in abstract volumes of (1) the 1993 Geological Society of America National Meeting, (2) the 8th International Conference on Geochronology, Cosmochronology and Isotope Geology, and (3) the 1994 Dakota Aquifer Workshop and Clinic. Copies of all abstracts are included in this brief review. One report will focus on the sources and ages of the groundwater, and the other will focus on the subsurface controls on the natural water quality.

  2. Novel Isotope Effects and Organic Reaction Mechanisms

    E-Print Network [OSTI]

    Kelly, Kelmara K.

    2010-07-14T23:59:59.000Z

    to account for the observed isotope effects. In the dimerization of cyclopentadiene, novel "dynamic" isotope effects are observed on the 13C distribution in the product, and a method for the prediction of these isotope effects is developed here...

  3. Jet-like circulations occur in the `simple' geometries of gas planets and Earth's

    E-Print Network [OSTI]

    #12;Jet-like circulations occur in the `simple' geometries of gas planets and Earth's liquid The Jet Stream Conundrum Baldwin, Rhines, Huang & McIntyre, Nature 2007 #12;For Earth's oceans, density and jets Tracks of fast sea- surface drifters, Jakobsen 1994 #12;channels & atmospheres: PV stirring

  4. Isotope effect studies of the pyridoxal 5'-phosphate dependent histidine decarboxylase from Morganella morganii

    SciTech Connect (OSTI)

    Abell, L.M.; O'Leary, M.H.

    1988-08-09T23:59:59.000Z

    The pyridoxal 5'-phosphate dependent histidine decarboxylase from Morganella morganii shows a nitrogen isotope effect k/sup 14//k/sup 15/ = 0.9770 +/- 0.0021, a carbon isotope effect k/sup 12//k/sup 13/ = 1.0308 +/- 0.0006, and a carbon isotope effect for L-(..cap alpha..-/sup 2/H)histidine of 1.0333 +/- 0.0001 at pH 6.3, 37/sup 0/C. These results indicate that the overall decarboxylation rate is limited jointly by the rate of Schiff base interchange and by the rate of decarboxylation. Although the observed isotope effects are quite different from those for the analogous glutamate decarboxylase from Escherichia coli, the intrinsic isotope effects for the two enzymes are essentially the same. The difference in observed isotope effects occurs because of a roughly twofold difference in the partitioning of the pyridoxal 5'-phosphate-substrate Schiff base between decarboxylation and Schiff base interchange. The observed nitrogen isotope effect requires that the imine nitrogen in this Schiff base is protonated. Comparison of carbon isotope effects for deuteriated and undeuteriated substrates reveals that the deuterium isotope effect on the decarboxylation step is about 1.20; thus, in the transition state for the decarboxylation step, the carbon-carbon bond is about two-thirds broken.

  5. Chromatographic hydrogen isotope separation

    DOE Patents [OSTI]

    Aldridge, Frederick T. (Livermore, CA)

    1981-01-01T23:59:59.000Z

    Intermetallic compounds with the CaCu.sub.5 type of crystal structure, particularly LaNiCo.sub.4 and CaNi.sub.5, exhibit high separation factors and fast equilibrium times and therefore are useful for packing a chromatographic hydrogen isotope separation colum. The addition of an inert metal to dilute the hydride improves performance of the column. A large scale mutli-stage chromatographic separation process run as a secondary process off a hydrogen feedstream from an industrial plant which uses large volumes of hydrogen can produce large quantities of heavy water at an effective cost for use in heavy water reactors.

  6. ARM - Measurement - Isotope ratio

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadap Documentation TDMADAP : XDC documentationBarrow,ice particleSizegovMeasurementsIsotope ratio

  7. The marine biogeochemistry of zinc isotopes

    E-Print Network [OSTI]

    John, Seth G

    2007-01-01T23:59:59.000Z

    Zinc (Zn) stable isotopes can record information about important oceanographic processes. This thesis presents data on Zn isotopes in anthropogenic materials, hydrothermal fluids and minerals, cultured marine phytoplankton, ...

  8. Stable Isotope Fractionations in Biogeochemical Reactive Transport

    E-Print Network [OSTI]

    Druhan, Jennifer Lea

    2012-01-01T23:59:59.000Z

    characteristic of stable isotope enrichment. The values of !isotope ratios of sulfur in these sulfate samples demonstrated a clear enrichmentisotope ( 34 S) (Canfield, 2001). The characteristic enrichment

  9. Strategic Isotope Production | ornl.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Strategic Isotope Production SHARE Strategic Isotope Production Typical capsules used in the transport of 252Cf source material inside heavily shielded shipping casks. ORNL's...

  10. Isotopic Trends in Production of Superheavies

    SciTech Connect (OSTI)

    Antonenko, N.V. [Institut fuer Theoretische Physik der Justus-Liebig-Universitaet, D-35392 Giessen (Germany); Joint Institute for Nuclear Research, 141980 Dubna (Russian Federation); Adamian, G.G.; Zubov, A.S. [Joint Institute for Nuclear Research, 141980 Dubna (Russian Federation); Scheid, W. [Institut fuer Theoretische Physik der Justus-Liebig-Universitaet, D-35392 Giessen (Germany)

    2005-11-21T23:59:59.000Z

    The isotopic trends are discussed for cold and hot fusion reactions leading to superheavies. The possibilities of production of new isotopes in incomplete fusion reactions are treated.

  11. Isotope Research 229 Th production

    E-Print Network [OSTI]

    Isotope Research ­ 229 Th production We recently completed an ARRA-funded project of this type on 229 Th production reactions [Str11]. This long-lived isotope is important as a precursor to 225 Ac of accelerator production of 229 Th via the 230 Th(p,2n)229 Pa reaction. The 229 Pa decays primarily by electron

  12. Method of separating boron isotopes

    DOE Patents [OSTI]

    Jensen, Reed J. (Los Alamos, NM); Thorne, James M. (Provo, UT); Cluff, Coran L. (Provo, UT); Hayes, John K. (Salt Lake City, UT)

    1984-01-01T23:59:59.000Z

    A method of boron isotope enrichment involving the isotope preferential photolysis of (2-chloroethenyl)dichloroborane as the feed material. The photolysis can readily be achieved with CO.sub.2 laser radiation and using fluences significantly below those required to dissociate BCl.sub.3.

  13. Method of separating boron isotopes

    DOE Patents [OSTI]

    Jensen, R.J.; Thorne, J.M.; Cluff, C.L.

    1981-01-23T23:59:59.000Z

    A method of boron isotope enrichment involving the isotope preferential photolysis of (2-chloroethenyl)-dichloroborane as the feed material. The photolysis can readily by achieved with CO/sub 2/ laser radiation and using fluences significantly below those required to dissociate BCl/sub 3/.

  14. ON-BELT ANALYSIS OF MINERALS USING NATURALLY OCCURRING GAMMA RADIATION

    E-Print Network [OSTI]

    Huynh, Du

    of coal. Gamma ray spectra are collected every 900 seconds from a BGO detector with 1024 channels linearly collected with a BGO (Bis- muth Germanate) gamma ray detector, which collects emis- sions from Potassium (K is used to estimate linear drift in the detector. Index Terms-- Gamma ray detector, Poisson process

  15. Evaluation of naturally occurring parasitic Hymenoptera attacking silverleaf whitefly, Bemisia argentifolii in Texas

    E-Print Network [OSTI]

    Moomaw, Charles Philip

    1996-01-01T23:59:59.000Z

    be considered, should such be necessary. Texas parasitoid complex Faunistic surveys (C. Moomaw, M. Rose and J, B. Woolley, TAMU, College Station TX. , 1991-1994) suggest that five species of parasitic Hymenoptera attack the whitefly on cultivated crops...; Yokomi et al. 1990a). Geminivirus of tomato and cabbage appeared in 1989 (Brown A Costa 1992). The SWF is also a vector of cotton leaf crumple, cotton leaf curl, infectious yellows and squash leaf curl affecting a wide range of cultivated vegetable...

  16. DISTRIBUTION OF NATURALLY OCCURRING RADIONUCLIDES (U, Th) IN TIMAHDIT'S BLACK SHALE (MOROCCO)

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    focused on the use of Moroccan's black oil shales as the raw materials for production of a new type, 1991). These adsorbents were produced from oil shale, which is abundant in Morocco. The choice

  17. Daily Crime and Fire Log 12/12/13 Nature Case # Reported Occurred Location Disposition

    E-Print Network [OSTI]

    Stanford, Kyle

    Battery: Touch Person Intimately Agnst Will 13-1897 12/12/2013 14:08 12/5/2013 - 12/11/2013 Douglas Hospital Pending Battery On Person 13-1896 12/12/2013 09:43 12/12/2013 09:30 Building 3 - 1 North Pending/Etc Known Stolen Property 13-1885 12/9/2013 17:36 12/9/2013 17:41 Palo Verde Club House Rec Ctr Cleared

  18. In-situ remediation of naturally occurring radioactive materials with high-permeability hydraulic fracturing

    E-Print Network [OSTI]

    Demarchos, Andronikos Stavros

    1998-01-01T23:59:59.000Z

    in the petroleum industry, is the recommended technique. NORM are found throughout subterranean formations. Whenever fluids from petroleum or water reservoirs are produced NORM are present in varying quantities. NORM can only be sensed with radiation detectors...

  19. Characterization of Naturally Occurring Radioactive Material (NORM) in Oil and Gas Industry Equipment and Wastes

    SciTech Connect (OSTI)

    Rood, A.S.; White, G.J.

    1999-10-07T23:59:59.000Z

    This Sampling and Analysis (S and A) Plan was developed for the NORM Characterization Program, and describes the information to be gained through the program, how the required information is to be collected, and the anticipated form and content of the final data. The S and A Plan provides detailed procedures describing the work to be performed, how and why the work will be performed, and who will be responsible for conducting the various aspects of the work. The S and A Plan has been prepared with input from all parties involved with the program. Where appropriate, portions of the procedures described in the S and A Plan will be field tested by personnel of the Idaho National Engineering Laboratory (INEL) and the Grand Junction Project Office (GJPO), as well as representatives of the cosponsor organizations prior to their use in the field.

  20. . Liquid or solid particles suspended in the air . Some occur naturally, originating from

    E-Print Network [OSTI]

    McCready, Mark J.

    , absorption by particles and surrounding atmosphere causes net warming. . magnitude of cooling depends on size cooling may partially offset global warming due to CO2, etc. #12;. Alter warm, ice and mixed-phase cloud) . Aerosols produce more vivid sunsets . We are not sure whether aerosols are overall warming or cooling

  1. USE OF NATURALLY-OCCURRING TRACERS TO MONITOR TWO-PHASE CONDITIONS IN THE

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to:Ezfeedflag JumpID-fTri Global Energy LLC Place: Dallas,UGIURDBCOSO EGS PROJECT | Open Energy

  2. IUPAC Periodic Table of Isotopes for the Educational Community

    SciTech Connect (OSTI)

    Holden N. E.; Holden,N.E.; Coplen,T.B.

    2012-07-15T23:59:59.000Z

    John Dalton first proposed the concept of atomic weights of the elements in the first decade of the nineteenth century. These atomic weights of the chemical elements were thought of as constants of nature, similar to the speed of light. Dmitri Mendeleev arranged the atomic weights of the elements in ascending order of value and used the systematic variation of their chemical properties to produce his Periodic Table of the Elements in 1869. Measurement of atomic weight values became an important chemical activity for a century and a half. Theodore Richards received a Noble Prize for his work in this area. In 1913, Fredrick Soddy found a species of radium, which had an atomic weight value of 228, compared to the familiar radium gas value of 226. Soddy coined the term 'isotope' (Greek for 'in the same place') to account for this second atomic weight value in the radium position of the Periodic Table. Both of these isotopes of radium are radioactive. Radioactive isotopes are energetically unstable and will decay (disintegrate) over time. The time it takes for one half of a sample of a given radioactive isotope to decay is the half-life of that isotope. In addition to having different atomic weight values, radium-226 and radium-228 also have different half-life values. Around the same time as Soddy's work, J.J. Thomson (discoverer of the electron) identified two stable (non-radioactive) isotopes of the same element, neon. Over the next 40 years, the majority of the known chemical elements were found to have two or more stable (or long-lived radioactive isotopes that contribute significantly to the determination of the atomic weights of the elements).

  3. Significance of Isotopically Labile Organic Hydrogen in Thermal Maturation of Organic Matter

    SciTech Connect (OSTI)

    Arndt Schimmelmann; Maria Mastalerz

    2010-03-30T23:59:59.000Z

    Isotopically labile organic hydrogen in fossil fuels occupies chemical positions that participate in isotopic exchange and in chemical reactions during thermal maturation from kerogen to bitumen, oil and gas. Carbon-bound organic hydrogen is isotopically far less exchangeable than hydrogen bound to nitrogen, oxygen, or sulfur. We explore why organic hydrogen isotope ratios express a relationship with organic nitrogen isotope ratios in kerogen at low to moderate maturity. We develop and apply new techniques to utilize organic D/H ratios in organic matter fractions and on a molecular level as tools for exploration for fossil fuels and for paleoenvironmental research. The scope of our samples includes naturally and artificially matured substrates, such as coal, shale, oil and gas.

  4. Key changes in proteins occur in cyanobacteria | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    proteins occur in cyanobacteria Identification of redox-sensitive enzymes can enrich biofuel production research Overview of the chemical biology technique used by PNNL...

  5. Determining Planes Along Which Earthquakes Occur- Method of Applicatio...

    Open Energy Info (EERE)

    Along Which Earthquakes Occur- Method of Application to Earthquakes Accompanying Hydraulic Fracturing Jump to: navigation, search OpenEI Reference LibraryAdd to library...

  6. Chapter 5. Conclusion Uranium, a naturally occurring element, contributes to low levels of natural background radiation in the

    E-Print Network [OSTI]

    radium and the radioactive gas radon. Mining is the process by which mineral and metal bearing ores and price. This subeconomic ore is often stockpiled at the mine site for future exploitation under straddling the Four Corners where Utah, Colorado, New Mexico, and Arizona meet, though more than a dozen

  7. Apparatus and process for separating hydrogen isotopes

    DOE Patents [OSTI]

    Heung, Leung K; Sessions, Henry T; Xiao, Xin

    2013-06-25T23:59:59.000Z

    The apparatus and process for separating hydrogen isotopes is provided using dual columns, each column having an opposite hydrogen isotopic effect such that when a hydrogen isotope mixture feedstock is cycled between the two respective columns, two different hydrogen isotopes are separated from the feedstock.

  8. Method for laser induced isotope enrichment

    DOE Patents [OSTI]

    Pronko, Peter P.; Vanrompay, Paul A.; Zhang, Zhiyu

    2004-09-07T23:59:59.000Z

    Methods for separating isotopes or chemical species of an element and causing enrichment of a desired isotope or chemical species of an element utilizing laser ablation plasmas to modify or fabricate a material containing such isotopes or chemical species are provided. This invention may be used for a wide variety of materials which contain elements having different isotopes or chemical species.

  9. Compelling Research Opportunities using Isotopes

    SciTech Connect (OSTI)

    None

    2009-04-23T23:59:59.000Z

    Isotopes are vital to the science and technology base of the US economy. Isotopes, both stable and radioactive, are essential tools in the growing science, technology, engineering, and health enterprises of the 21st century. The scientific discoveries and associated advances made as a result of the availability of isotopes today span widely from medicine to biology, physics, chemistry, and a broad range of applications in environmental and material sciences. Isotope issues have become crucial aspects of homeland security. Isotopes are utilized in new resource development, in energy from bio-fuels, petrochemical and nuclear fuels, in drug discovery, health care therapies and diagnostics, in nutrition, in agriculture, and in many other areas. The development and production of isotope products unavailable or difficult to get commercially have been most recently the responsibility of the Department of Energy's Nuclear Energy program. The President's FY09 Budget request proposed the transfer of the Isotope Production program to the Department of Energy's Office of Science in Nuclear Physics and to rename it the National Isotope Production and Application program (NIPA). The transfer has now taken place with the signing of the 2009 appropriations bill. In preparation for this, the Nuclear Science Advisory Committee (NSAC) was requested to establish a standing subcommittee, the NSAC Isotope Subcommittee (NSACI), to advise the DOE Office of Nuclear Physics. The request came in the form of two charges: one, on setting research priorities in the short term for the most compelling opportunities from the vast array of disciplines that develop and use isotopes and two, on making a long term strategic plan for the NIPA program. This is the final report to address charge 1. NSACI membership is comprised of experts from the diverse research communities, industry, production, and homeland security. NSACI discussed research opportunities divided into three areas: (1) medicine, pharmaceuticals, and biology, (2) physical sciences and engineering, and (3) national security and other applications. In each area, compelling research opportunities were considered and the subcommittee as a whole determined the final priorities for research opportunities as the foundations for the recommendations. While it was challenging to prioritize across disciplines, our order of recommendations reflect the compelling research prioritization along with consideration of time urgency for action as well as various geopolitical market issues. Common observations to all areas of research include the needs for domestic availability of crucial stable and radioactive isotopes and the education of the skilled workforce that will develop new advances using isotopes in the future. The six recommendations of NSACI reflect these concerns and the compelling research opportunities for potential new discoveries. The science case for each of the recommendations is elaborated in the respective chapters.

  10. Electrochemical Isotope Effect and Lithium Isotope Separation Jay R. Black,

    E-Print Network [OSTI]

    Mcdonough, William F.

    results showing a large lithium isotope separation due to electrodeposition. The fractionation is tunable lithium were plated from solutions of 1 M LiClO4 in propylene carbonate (PC) on planar nickel electrodes

  11. Original article Hydraulic conductance of two co-occuring neotropical

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Original article Hydraulic conductance of two co-occuring neotropical understory shrubs December 1999) Abstract ­ Whole plant hydraulic conductance was measured for two co-occuring neotropical hydraulic con- ductance and leaf specific conducance in the drought-avoiding species, P. trigonum, than

  12. Quantum fluctuations and isotope effects in ab initio descriptions of water

    SciTech Connect (OSTI)

    Wang, Lu; Markland, Thomas E., E-mail: tmarkland@stanford.edu [Department of Chemistry, Stanford University, 333 Campus Drive, Stanford, California 94305 (United States); Ceriotti, Michele, E-mail: michele.ceriotti@epfl.ch [Laboratory of Computational Science and Modeling, École Polytechnique Fédérale de Lausanne, 1015 Lausanne (Switzerland)

    2014-09-14T23:59:59.000Z

    Isotope substitution is extensively used to investigate the microscopic behavior of hydrogen bonded systems such as liquid water. The changes in structure and stability of these systems upon isotope substitution arise entirely from the quantum mechanical nature of the nuclei. Here, we provide a fully ab initio determination of the isotope exchange free energy and fractionation ratio of hydrogen and deuterium in water treating exactly nuclear quantum effects and explicitly modeling the quantum nature of the electrons. This allows us to assess how quantum effects in water manifest as isotope effects, and unravel how the interplay between electronic exchange and correlation and nuclear quantum fluctuations determine the structure of the hydrogen bond in water.

  13. Novel hybrid isotope separation scheme and apparatus

    DOE Patents [OSTI]

    Maya, Jakob (Brookline, MA)

    1991-01-01T23:59:59.000Z

    A method of yielding selectively a desired enrichment in a specific isotope including the steps of inputting into a spinning chamber a gas from which the specific isotope is to be isolated, radiating the gas with frequencies characteristic of the absorption of a particular isotope of the atomic or molecular gas, thereby inducing a photoionization reaction of the desired isotope, and collecting the specific isotope ion by suitable ion collection means.

  14. Novel hybrid isotope separation scheme and apparatus

    DOE Patents [OSTI]

    Maya, J.

    1991-06-18T23:59:59.000Z

    A method is described for yielding selectively a desired enrichment in a specific isotope including the steps of inputting into a spinning chamber a gas from which the specific isotope is to be isolated, radiating the gas with frequencies characteristic of the absorption of a particular isotope of the atomic or molecular gas, thereby inducing a photoionization reaction of the desired isotope, and collecting the specific isotope ion by suitable ion collection means. 3 figures.

  15. Diffusion in silicon isotope heterostructures

    SciTech Connect (OSTI)

    Silvestri, Hughes Howland

    2004-05-14T23:59:59.000Z

    The simultaneous diffusion of Si and the dopants B, P, and As has been studied by the use of a multilayer structure of isotopically enriched Si. This structure, consisting of 5 pairs of 120 nm thick natural Si and {sup 28}Si enriched layers, enables the observation of {sup 30}Si self-diffusion from the natural layers into the {sup 28}Si enriched layers, as well as dopant diffusion from an implanted source in an amorphous Si cap layer, via Secondary Ion Mass Spectrometry (SIMS). The dopant diffusion created regions of the multilayer structure that were extrinsic at the diffusion temperatures. In these regions, the Fermi level shift due to the extrinsic condition altered the concentration and charge state of the native defects involved in the diffusion process, which affected the dopant and self-diffusion. The simultaneously recorded diffusion profiles enabled the modeling of the coupled dopant and self-diffusion. From the modeling of the simultaneous diffusion, the dopant diffusion mechanisms, the native defect charge states, and the self- and dopant diffusion coefficients can be determined. This information is necessary to enhance the physical modeling of dopant diffusion in Si. It is of particular interest to the modeling of future electronic Si devices, where the nanometer-scale features have created the need for precise physical models of atomic diffusion in Si. The modeling of the experimental profiles of simultaneous diffusion of B and Si under p-type extrinsic conditions revealed that both species are mediated by neutral and singly, positively charged Si self-interstitials. The diffusion of As and Si under extrinsic n-type conditions yielded a model consisting of the interstitialcy and vacancy mechanisms of diffusion via singly negatively charged self-interstitials and neutral vacancies. The simultaneous diffusion of P and Si has been modeled on the basis of neutral and singly negatively charged self-interstitials and neutral and singly positively charged P species. Additionally, the temperature dependence of the diffusion coefficient of Si in Ge was measured over the temperature range of 550 C to 900 C using a buried Si layer in an epitaxially grown Ge layer.

  16. Physics with isotopically controlled semiconductors

    SciTech Connect (OSTI)

    Haller, E. E., E-mail: eehaller@lbl.gov [University of California at Berkeley, Department of Materials Science and Engineering (United States)

    2010-07-15T23:59:59.000Z

    This paper is based on a tutorial presentation at the International Conference on Defects in Semiconductors (ICDS-25) held in Saint Petersburg, Russia in July 2009. The tutorial focused on a review of recent research involving isotopically controlled semiconductors. Studies with isotopically enriched semiconductor structures experienced a dramatic expansion at the end of the Cold War when significant quantities of enriched isotopes of elements forming semiconductors became available for worldwide collaborations. Isotopes of an element differ in nuclear mass, may have different nuclear spins and undergo different nuclear reactions. Among the latter, the capture of thermal neutrons which can lead to neutron transmutation doping, is the most prominent effect for semiconductors. Experimental and theoretical research exploiting the differences in all the properties has been conducted and will be illustrated with selected examples.

  17. Isotope production facility produces cancer-fighting actinium

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cancer therapy gets a boost from new isotope Isotope production facility produces cancer-fighting actinium A new medical isotope project shows promise for rapidly producing major...

  18. Isotope Tracer Studies of Diffusion in Sillicates and of Geological Transport Processes Using Actinide Elements

    SciTech Connect (OSTI)

    Wasserburg, Gerald J

    2008-07-31T23:59:59.000Z

    The objectives were directed toward understanding the transport of chemical species in nature, with particular emphasis on aqueous transport in solution, in colloids, and on particles. Major improvements in measuring ultra-low concentrations of rare elements were achieved. We focused on two areas of studies: (1) Field, laboratory, and theoretical studies of the transport and deposition of U, Th isotopes and their daughter products in natural systems; and (2) Study of calcium isotope fractionation effects in marine carbonates and in carbonates precipitated in the laboratory, under controlled temperature, pH, and rates of precipitation. A major study of isotopic fractionation of Ca during calcite growth from solution has been completed and published. It was found that the isotopic shifts widely reported in the literature and attributed to biological processes are in fact due to a small equilibrium fractionation factor that is suppressed by supersaturation of the solution. These effects were demonstrated in the laboratory and with consideration of the solution conditions in natural systems, where [Ca{sup 2+}] >> [CO{sub 3}{sup 2-}] + [HCO{sub 3}{sup -}]. The controlling rate is not the diffusion of Ca, as was earlier proposed, but rather the rate of supply of [CO{sub 3}{sup 2-}] ions to the interface. This now opens the issues of isotopic fractionation of many elements to a more physical-chemical approach. The isotopic composition of Ca {Delta}({sup 44}Ca/{sup 40}Ca) in calcite crystals has been determined relative to that in the parent solutions by TIMS using a double spike. Solutions were exposed to an atmosphere of NH{sub 3} and CO{sub 2}, provided by the decomposition of (NH4)2CO3. Alkalinity, pH, and concentrations of CO{sub 3}{sup 2-}, HCO{sub 3}{sup -}, and CO{sub 2} in solution were determined. The procedures permitted us to determine {Delta}({sup 44}Ca/{sup 40}Ca) over a range of pH conditions, with the associated ranges of alkalinity. Two solutions with greatly different Ca concentrations were used, but, in all cases, the condition [Ca] >> [CO{sub 3}{sup 2-}] was met. A wide range in {Delta}({sup 44}Ca/{sup 40}Ca) was found for the calcite crystals, extending from 0.04 {+-} 0.13 to -1.34 {+-} 0.15 {per_thousand}, generally anticorrelating with the amount of Ca removed from the solution. The results show that {Delta}({sup 44}Ca/{sup 40}Ca) is a linear function of the saturation state of the solution with respect to calcite ({Omega}). The two parameters are very well correlated over a wide range in {Omega} for each solution with a given [Ca]. Solutions, which were vigorously stirred, showed a much smaller range in {Delta}({sup 44}Ca/{sup 40}Ca) and gave values of -0.42 {+-} 0.14 {per_thousand}, with the largest effect at low {Omega}. It is concluded that the diffusive flow of CO{sub 3}{sup 2-} into the immediate neighborhood of the crystal-solution interface is the rate-controlling mechanism and that diffusive transport of Ca{sup 2+} is not a significant factor. The data are simply explained by the assumptions that: (a) the immediate interface of the crystal and the solution is at equilibrium with {Delta}({sup 44}Ca/{sup 40}Ca) {approx} -1.5 {+-} 0.25 {per_thousand}, and (b) diffusive inflow of CO{sub 3}{sup 2-} causes supersaturation, thus precipitating Ca from the regions, exterior to the narrow zone of equilibrium. We consider this model to be a plausible explanation of the available data reported in the literature. The well-resolved but small and regular isotope fractionation shifts in Ca are thus not related to the diffusion of very large hydrated Ca complexes, but rather due to the ready availability of Ca in the general neighborhood of the crystal solution interface. The largest isotopic shift which occurs is a small equilibrium effect which is then subdued by supersaturation precipitation for solutions where [Ca{sup 2+}] >> [CO{sub 3}{sup 2-}] + [HCO{sub 3}{sup -}]. It is shown that there is a clear temperature dependence of the net isotopic shifts, which is simply due to changes in {Omega}

  19. Isotope Specific Remediation Media and Systems - 13614

    SciTech Connect (OSTI)

    Denton, Mark S.; Mertz, Joshua L. [Kurion, Inc. Oak Ridge, Tennessee 37831 (United States)] [Kurion, Inc. Oak Ridge, Tennessee 37831 (United States); Morita, Keisuke [Japan Atomic Energy Agency, Tokai Research and Development Center, Fukushima Project Team, Tokai-mura, Ibaraki-ken, 319-1195 (Japan)] [Japan Atomic Energy Agency, Tokai Research and Development Center, Fukushima Project Team, Tokai-mura, Ibaraki-ken, 319-1195 (Japan)

    2013-07-01T23:59:59.000Z

    On March 11, 2011, now two years ago, the magnitude 9.0 Great East Japan earthquake, Tohoku, hit off the Fukushima coast of Japan. While, of course, most of the outcome of this unprecedented natural and manmade disaster was a negative, both in Japan and worldwide, there have been some extremely invaluable lessons learned and new emergency recovery technologies and systems developed. As always, the mother of invention is necessity. Among these developments has been the development and full-scale implementation of proven isotope specific media (ISMs) with the intent of surgically removing specific hazardous isotopes for the purpose of minimizing dose to workers and the environment. The first such ISMs to be deployed at the Fukushima site were those removing cesium (Cs-137) and iodine (I-129). Since deployment on June 17, 2011, along with treated cooling water recycle, some 70% of the curies in the building liquid wastes have been removed by the Kurion system alone. The current levels of cesium are now only 2% of the original levels. Such an unprecedented, 'external cooling system' not only allowed the eventual cold shut down of the reactors in mid-December, 2011, but has allowed workers to concentrate on the cleanup of other areas of the site. Water treatment will continue for quite some time due to continued leakage into the buildings and the eventual goal of cleaning up the reactors and fuel pools themselves. With the cesium removal now in routine operation, other isotopes of concern are likely to become priorities. One such isotope is that of strontium, and yttrium (Sr-90 and Y-90), which is still at original levels causing further dose issues as well as impediments to discharge of the treated waste waters. For over a year now, a new synthetic strontium specific media has been under development and testing both in our licensed facility in Oak Ridge, Tennessee, but also in confirmatory tests by the Japan Atomic Energy Agency (JAEA) in Japan for Tokyo Electric Power Company (TEPCO). The tests have proven quite successful, even in high salt conditions, and, with loading and dose calculations being completed, will be proposed to add to the existing cesium system. There is no doubt, as high gamma isotopes are removed, other recalcitrant isotopes such as this will require innovative removal media, systems and techniques. Also coming out of this international effort are other ISM media and systems that can be applied more broadly to both Commercial Nuclear Power Plants (NPPs) as well as in Department of Energy (DOE) applications. This cesium and strontium specific media has further been successfully tested in 2012 at a Magnox station in the UK. The resulting proposed mitigation systems for pond and vault cleanup look quite promising. An extremely unusual ISM for carbon 14 (C-14), nickel (Ni-63) and cesium (Cs-137) has been developed for Diablo Canyon NPP for dose reduction testing in their fuel pool. These media will be deployed in Submersible Media Filter (SMF) and Submersible Columns (SC) systems adapted to standard Tri-Nuclear{sup R} housings common in the U.S. and UK. External Vessel Systems (mini-Fukushima) have also been developed as a second mitigation system for D and D and outages. Finally, technetium (Tc- 99) specific media developed for the Waste Treatment Plant (WTP) recycle or condensate (secondary) waste streams (WM 2011) are being further perfected and tested for At-Tank Tc-99 removal, as well as At Tank Cs media. In addition to the on-going media development, systems for deploying such media have developed over the last year and are in laboratory- and full-scale testing. These systems include the fore mentioned Submersible Media Filters (SMF), Submersible Columns (SC) and external pilot- and full-scale, lead-lag, canister systems. This paper will include the media development and testing, as well as that of the deployment systems themselves. (authors)

  20. Nickel isotopes in stellar matter

    E-Print Network [OSTI]

    Jameel-Un Nabi

    2014-08-19T23:59:59.000Z

    Isotopes of nickel play a key role during the silicon burning phase up to the presupernova phase of massive stars. Electron capture rates on these nickel isotopes are also important during the phase of core contraction. I present here the microscopic calculation of ground and excited states Gamow-Teller (GT) strength distributions for key nickel isotopes. The calculation is performed within the frame-work of pn-QRPA model. A judicious choice of model parameters, specially of the Gamow-Teller strength parameters and the deformation parameter, resulted in a much improved calculation of GT strength functions. The excited state GT distributions are much different from the corresponding ground-state distributions resulting in a failure of the Brink's hypothesis. The electron capture and positron decay rates on nickel isotopes are also calculated within the framework of pn-QRPA model relevant to the presupernova evolution of massive stars. The electron capture rates on odd-A isotopes of nickel are shown to have dominant contributions from parent excited states during as early as silicon burning phases. Comparison is being made with the large scale shell model calculation. During the silicon burning phases of massive stars the electron capture rates on $^{57,59}$Ni are around an order of magnitude bigger than shell model rates and can bear consequences for core-collapse simulators.

  1. Chromium Isotope Fractionation During Reduction of Cr(VI) Under Saturated Flow Conditions

    SciTech Connect (OSTI)

    Jamieson-Hanes, Julia H.; Gibson, Blair D.; Lindsay, Matthew B.J.; Kim, Yeongkyoo; Ptacek, Carol J.; Blowes, David W. (Waterloo); (Kyungpook National University)

    2012-10-25T23:59:59.000Z

    Chromium isotopes are potentially useful indicators of Cr(VI) reduction reactions in groundwater flow systems; however, the influence of transport on Cr isotope fractionation has not been fully examined. Laboratory batch and column experiments were conducted to evaluate isotopic fractionation of Cr during Cr(VI) reduction under both static and controlled flow conditions. Organic carbon was used to reduce Cr(VI) in simulated groundwater containing 20 mg L{sup -1} Cr(VI) in both batch and column experiments. Isotope measurements were performed on dissolved Cr on samples from the batch experiments, and on effluent and profile samples from the column experiment. Analysis of the residual solid-phase materials by scanning electron microscopy (SEM) and by X-ray absorption near edge structure (XANES) spectroscopy confirmed association of Cr(III) with organic carbon in the column solids. Decreases in dissolved Cr(VI) concentrations were coupled with increases in {delta}{sup 53}Cr, indicating that Cr isotope enrichment occurred during reduction of Cr(VI). The {delta}{sup 53}Cr data from the column experiment was fit by linear regression yielding a fractionation factor ({alpha}) of 0.9979, whereas the batch experiments exhibited Rayleigh-type isotope fractionation ({alpha} = 0.9965). The linear characteristic of the column {delta}{sup 53}Cr data may reflect the contribution of transport on Cr isotope fractionation.

  2. Advancement of isotope separation for the production of reference standards

    SciTech Connect (OSTI)

    Jared Horkley; Christopher McGrath; Andrew Edwards; Gaven Knighton; Kevin Carney; Jacob Davies; James Sommers; Jeffrey Giglio

    2012-03-01T23:59:59.000Z

    Idaho National Laboratory (INL) operates a mass separator that is currently producing high purity isotopes for use as internal standards for high precision isotope dilution mass spectrometry (IDMS). In 2008, INL began the revival of the vintage 1970’s era instrument. Advancements thus far include the successful upgrading and development of system components such as the vacuum system, power supplies, ion-producing components, and beam detection equipment. Progress has been made in the separation and collection of isotopic species including those of Ar, Kr, Xe, Sr, and Ba. Particular focuses on ion source improvements and developments have proven successful with demonstrated output beam currents of over 10 micro-amps 138Ba and 350nA 134Ba from a natural abundance source charge (approximately 2.4 percent 134Ba). In order to increase production and collection of relatively high quantities (mg levels) of pure isotopes, several advancements have been made in ion source designs, source material introduction, and beam detection and collection. These advancements and future developments will be presented.

  3. Natural Resources Protection Act (Maine)

    Broader source: Energy.gov [DOE]

    Maine's Department of Environmental Protection requires permits for most activities that occur in a protected natural resource area or adjacent to water resources such as rivers or wetlands. An ...

  4. Online Catalog of Isotope Products from DOE's National Isotope Development Center

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    The National Isotope Development Center (NIDC) interfaces with the User Community and manages the coordination of isotope production across the facilities and business operations involved in the production, sale, and distribution of isotopes. A virtual center, the NIDC is funded by the Isotope Development and Production for Research and Applications (IDPRA) subprogram of the Office of Nuclear Physics in the U.S. Department of Energy Office of Science. The Isotope subprogram supports the production, and the development of production techniques of radioactive and stable isotopes that are in short supply for research and applications. Isotopes are high-priority commodities of strategic importance for the Nation and are essential for energy, medical, and national security applications and for basic research; a goal of the program is to make critical isotopes more readily available to meet domestic U.S. needs. This subprogram is steward of the Isotope Production Facility (IPF) at Los Alamos National Laboratory (LANL), the Brookhaven Linear Isotope Producer (BLIP) facility at BNL, and hot cell facilities for processing isotopes at ORNL, BNL and LANL. The subprogram also coordinates and supports isotope production at a suite of university, national laboratory, and commercial accelerator and reactor facilities throughout the Nation to promote a reliable supply of domestic isotopes. The National Isotope Development Center (NIDC) at ORNL coordinates isotope production across the many facilities and manages the business operations of the sale and distribution of isotopes.

  5. Isotope Development & Production | Nuclear Science | ORNL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Medical Radioisotope Radiochemical Separation & Processing Strategic Isotope Production Super Heavy Element Discovery Nuclear Security Science & Technology Nuclear Systems...

  6. Isotopic Analysis of Uranium in NIST SRM Glass by Femtosecond Laser Ablation

    SciTech Connect (OSTI)

    Duffin, Andrew M.; Hart, Garret L.; Hanlen, Richard C.; Eiden, Gregory C.

    2013-05-19T23:59:59.000Z

    We employed femtosecond Laser Ablation Multicollector Inductively Coupled Mass Spectrometry for the 11 determination of uranium isotope ratios in a series of standard reference material glasses (NIST 610, 612, 614, and 12 616). This uranium concentration in this series of SRM glasses is a combination of isotopically natural uranium in 13 the materials used to make the glass matrix and isotopically depleted uranium added to increase the uranium 14 elemental concentration across the series. Results for NIST 610 are in excellent agreement with literature values. 15 However, other than atom percent 235U, little information is available for the remaining glasses. We present atom 16 percent and isotope ratios for 234U, 235U, 236U, and 238U for all four glasses. Our results show deviations from the 17 certificate values for the atom percent 235U, indicating the need for further examination of the uranium isotopes in 18 NIST 610-616. Our results are fully consistent with a two isotopic component mixing between the depleted 19 uranium spike and natural uranium in the bulk glass.

  7. Improving Home Automation by Discovering Regularly Occurring Device Usage Patterns

    E-Print Network [OSTI]

    Cook, Diane J.

    Improving Home Automation by Discovering Regularly Occurring Device Usage Patterns Edwin O in an environment can be mined to discover significant patterns, which an intelligent agent could use to automate of two prediction algorithms, thus demonstrating multiple uses for a home automation system. Finally, we

  8. accident excursion occurring: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    accident excursion occurring First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Annual Report of Railroad...

  9. Ultimate Isotope Precision for Carbonates Thermo Scientific

    E-Print Network [OSTI]

    Lachniet, Matthew S.

    Ultimate Isotope Precision for Carbonates Thermo Scientific KIEL IV Carbonate Device Part of Thermo integration cycle Ultimate Isotope Precision for Carbonates The Thermo Scientific KIEL IV Carbonate DeviceV Thermo Scientific MAT 253 or the 3-kV DELTA V isotope ratio mass spectrometer meets the requirements

  10. Isotope Cancer Treatment Research at LANL

    ScienceCinema (OSTI)

    Weidner, John; Nortier, Meiring

    2014-06-02T23:59:59.000Z

    Los Alamos National Laboratory has produced medical isotopes for diagnostic and imaging purposes for more than 30 years. Now LANL researchers have branched out into isotope cancer treatment studies. New results show that an accelerator-based approach can produce clinical trial quantities of actinium-225, an isotope that has promise as a way to kill tumors without damaging surrounding healthy cells.

  11. On the Alpha Activity of Natural Tungsten Isotopes

    E-Print Network [OSTI]

    F. A. Danevich A; A. Sh. Georgadze A; V. V. Kobychev A; S. S. Nagorny A; A. S. Nikolaiko A; W

    The indication for the ? decay of 180W with a half-life T ? 1/2 =1.1+0.8 ?0.4(stat)±0.3(syst)×1018 yr has been observed for the first time with the help of the super-low background 116CdWO4 crystal scintillators. In conservative approach the lower limit on half-life of 180W has been established as T ? 1/2 (180W) ? 0.7×1018 yr at 90 % C.L. Besides, new T ? 1/2 bounds were set for ? decay of

  12. Integrated Approach to Use Natural Chemical and Isotopic Tracers...

    Broader source: Energy.gov (indexed) [DOE]

    * Reservoir Sustainability - Barrier M: Long-term sustainability - Partners: NA - Acknowledgement: Ormat Technologies, Inc. (core samples) Project Overview 3 | US DOE Geothermal...

  13. Problems and prospects in future applications of stable isotopes in the life sciences and medicine

    SciTech Connect (OSTI)

    Matwiyoff, N.A.; Unkefer, C.J.; Walker, T.E.

    1982-01-01T23:59:59.000Z

    In the last decade, there has been a resurgence of interest in the use of stable isotopes of carbon, oxygen, and nitrogen in the life sciences and medicine fueled by the increased availability of the isotopes and isotopically labeled compounds and of instruments for their detection. Accelerated development of /sup 13/C, /sup 15/N, and /sup 17/ /sup 18/O can be expected in the future for studies of drug bioavailability, nutrition and body protein economy, viability of organs for transplant, and for non-invasive tests of metabolic diseases and dysfunctions. These accelerated developments depend on continued improvements in nmr and ms instrumentation and in methods for the synthesis of isotopically labeled compounds. The main part of this paper explores the possibilities of biosynthesis for the selective enrichment of natural products, especially amino acids, with /sup 13/C.

  14. Metallic beam development for the Facility for Rare Isotope Beam

    SciTech Connect (OSTI)

    Machicoane, Guillaume, E-mail: machicoa@nscl.msu.edu; Cole, Dallas; Leitner, Daniela; Neben, Derek; Tobos, Larry [Facility for Rare Isotope Beam, Michigan State University, East Lansing, Michigan 48824 (United States)] [Facility for Rare Isotope Beam, Michigan State University, East Lansing, Michigan 48824 (United States)

    2014-02-15T23:59:59.000Z

    The Facility for Rare Isotope Beams (FRIB) at Michigan State University (MSU) will accelerate a primary ion beam to energies beyond 200 MeV/u using a superconducting RF linac and will reach a maximum beam power of 400 kW on the fragmentation target. The beam intensity needed from the ECR ion source is expected to be between 0.4 and 0.5 emA for most medium mass to heavy mass elements. Adding to the challenge of reaching the required intensity, an expanded list of primary beams of interest has been established based on the production rate and the number of isotope beams that could be produced with FRIB. We report here on the development done for some of the beam in the list including mercury (natural), molybdenum ({sup 98}Mo), and selenium ({sup 82}Ser)

  15. Shape coexistence and evolution in neutron-deficient krypton isotopes

    E-Print Network [OSTI]

    Z. J. Bai; X. M. Fu; C. F. Jiao; F. R. Xu

    2015-03-31T23:59:59.000Z

    Total Routhian Surface (TRS) calculations have been performed to investigate shape coexistence and evolution in neutron-deficient krypton isotopes ${}^{72,74,76}$Kr. The ground-state shape is found to change from oblate in ${}^{72}$Kr to prolate in ${}^{74,76}$Kr, in agreement with experimental data. Quadrupole deformations of the ground states and coexisting $0^{+}_{2}$ states as well as excitation energies of the latter are also well reproduced. While the general agreement between calculated moments of inertia and those deduced from observed spectra confirms the prolate nature of the low-lying yrast states of all three isotopes (except the ground state of ${}^{72}$Kr), the deviation at low spins suggests significant shape mixing. The role of triaxiality in describing shape coexistence and evolution in these nuclei is finally discussed.

  16. Development of Halide and Oxy-Halides for Isotopic Separations

    SciTech Connect (OSTI)

    Leigh R. Martin; Aaron T. Johnson; Jana Pfeiffer; Martha R. Finck

    2014-10-01T23:59:59.000Z

    The goal of this project was to synthesize a volatile form of Np for introduction into mass spectrometers at INL. Volatile solids of the 5f elements are typically those of the halides (e.g. UF6), however fluorine is highly corrosive to the sensitive internal components of the mass separator, and the other volatile halides exist as several different stable isotopes in nature. However, iodide is both mono-isotopic and volatile, and as such presents an avenue for creation of a form of Np suitable for introduction into the mass separator. To accomplish this goal, the technical work in the project sought to establish a novel synthetic route for the conversion NpO2+ (dissolved in nitric acid) to NpI3 and NpI4.

  17. 98 NATURE CLIMATE CHANGE | VOL 1 | MAY 2011 | www.nature.com/natureclimatechange news & views

    E-Print Network [OSTI]

    Lockwood, Mike

    that changes in solar output must be responsible for large changes in climate. This thinking neglects a key of the solar atmosphere (derived from historic geomagnetic data or from cosmogenic isotopes in ice cores by -- the solar surface on millennial and shorter timescales. Almost all the changes that do occur

  18. Heat distribution by natural convection

    SciTech Connect (OSTI)

    Balcomb, J.D.

    1985-01-01T23:59:59.000Z

    Natural convection can provide adequate heat distribution in many situtations that arise in buildings. This is appropriate, for example, in passive solar buildings where some rooms tend to be more strongly solar heated than others or to reduce the number of heating units required in a building. Natural airflow and heat transport through doorways and other internal building apertures is predictable and can be accounted for in the design. The nature of natural convection is described, and a design chart is presented appropriate to a simple, single-doorway situation. Natural convective loops that can occur in buildings are described and a few design guidelines are presented.

  19. Radioactive Mineral Occurences in Nevada | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere I GeothermalPotentialBiopowerSolidGenerationMethodInformationeNevadaRadioactive Mineral Occurences in

  20. The Role of Isotopes in Monitoring Water Quality Impacts Associated with Shale Gas Drilling

    E-Print Network [OSTI]

    Wang, Z. Jane

    The Role of Isotopes in Monitoring Water Quality Impacts Associated with Shale Gas Drilling Methane contamination is usually due to natural causes; however, it can also be the result of drilling activities, including shale gas drilling. Monitoring techniques exist for detecting methane and, in some cases

  1. JOURNAL OF PETROLOGY VOLUME 39 NUMBER 1 PAGES 125154 1998 Chemical and Isotopic Composition of Lavas

    E-Print Network [OSTI]

    Stern, Robert J.

    of the Mariana Trough extension axis. The source, reflecting the arc-like nature of the source region and isotopic compositions of igneous rocks the mantle. `True' back-arc basin basalts are generated upwelling in mature ex-basalts in the south which become increasingly similar to arc lavas tensional

  2. Analysis of hydrogen isotope mixtures

    DOE Patents [OSTI]

    Villa-Aleman, Eliel (Aiken, SC)

    1994-01-01T23:59:59.000Z

    An apparatus and method for determining the concentrations of hydrogen isotopes in a sample. Hydrogen in the sample is separated from other elements using a filter selectively permeable to hydrogen. Then the hydrogen is condensed onto a cold finger or cryopump. The cold finger is rotated as pulsed laser energy vaporizes a portion of the condensed hydrogen, forming a packet of molecular hydrogen. The desorbed hydrogen is ionized and admitted into a mass spectrometer for analysis.

  3. Resolutions of Problems that Occurred in SPEAR3 Magnet Production

    SciTech Connect (OSTI)

    Li, Nanyang

    2005-05-27T23:59:59.000Z

    Some problems occurred during the SPEAR3 magnet production at IHEP, China. It was very hard to find resolution from existing knowledge of those problems. It was possible that similar problems might have happen in building accelerator magnet in other institutes before, but they were not addressed in public papers. These problems were discussed and solved by engineers from both SLAC and IHEP after conducting certain experiments. Traditionally, the magnet design and measurement data have been always well documented and addressed in papers, but the production experiences have not been recorded adequately. It is the goal of this paper to record the problems and their resolutions during SPEAR3 magnet production at IHEP China, which will certainly benefit future magnet projects.

  4. Influence of liquid structure on diffusive isotope separation in molten silicates and aqueous solutions

    SciTech Connect (OSTI)

    Watkins, J.M.; DePaolo, D.J.; Ryerson, F.J.; Peterson, B.

    2011-03-01T23:59:59.000Z

    Molecular diffusion in natural volcanic liquids discriminates between isotopes of major ions (e.g., Fe, Mg, Ca, and Li). Although isotope separation by diffusion is expected on theoretical grounds, the dependence on mass is highly variable for different elements and in different media. Silicate liquid diffusion experiments using simple liquid compositions were carried out to further probe the compositional dependence of diffusive isotopic discrimination and its relationship to liquid structure. Two diffusion couples consisting of the mineral constituents anorthite (CaAl{sub 2}Si{sub 2}O{sub 8}; denoted AN), albite (NaAlSi{sub 3}O{sub 8}; denoted AB), and diopside (CaMgSi{sub 2}O{sub 6}; denoted DI) were held at 1450°C for 2 h and then quenched to ambient pressure and temperature. Major-element as well as Ca and Mg isotope profiles were measured on the recovered quenched glasses. In both experiments, Ca diffuses rapidly with respect to Si. In the AB–AN experiment, D{sub Ca}/D{sub Si} ~ 20 and the efficiency of isotope separation for Ca is much greater than in natural liquid experiments where D{sub Ca}/D{sub Si} ~ 1. In the AB–DI experiment, D{sub Ca}/D{sub Si} ~ 6 and the efficiency of isotope separation is between that of the natural liquid experiments and the AB–AN experiment. In the AB–DI experiment, D{sub Mg}/D{sub Si} ~ 1 and the efficiency of isotope separation for Mg is smaller than it is for Ca yet similar to that observed for Mg in natural liquids. The results from the experiments reported here, in combination with results from natural volcanic liquids, show clearly that the efficiency of diffusive separation of Ca isotopes is systematically related to the solvent-normalized diffusivity—the ratio of the diffusivity of the cation (D{sub Ca}) to the diffusivity of silicon (D{sub Si}). The results on Ca isotopes are consistent with available data on Fe, Li, and Mg isotopes in silicate liquids, when considered in terms of the parameter D{sub cation}/D{sub Si}. Cations diffusing in aqueous solutions display a similar relationship between isotopic separation efficiency and D{sub cation} =D{sub H 2 O} , although the efficiencies are smaller than in silicate liquids. Our empirical relationship provides a tool for predicting the magnitude of diffusive isotopic effects in many geologic environments and a basis for a more comprehensive theory of isotope separation in liquid solutions. We present a conceptual model for the relationship between diffusivity and liquid structure that is consistent with available data.

  5. The bound coherent neutron scattering length of the oxygen isotopes

    SciTech Connect (OSTI)

    Fischer, Henry E [Institut Laue-Langevin (ILL); Simonson, J Michael {Mike} [ORNL; Neuefeind, Joerg C [ORNL; Lemmel, Hartmut [Technical University Vienna; Rauch, Helmut [E141 Atominstitut der Österreichischen Universitäten,; Zeidler, Anita [University of Bath; Salmon, Phil [University of Bath

    2012-01-01T23:59:59.000Z

    The technique of neutron interferometry was used to measure the bound coherent neutron scattering length bcoh of the oxygen isotopes 17O and 18O. From the measured difference in optical path between two water samples, either H2 17O or H2 18O versus H2 natO, where nat denotes the natural isotopic composition, we obtain bcoh , 17O = 5.867(4) fm and bcoh , 18O = 6.009(5) fm, based on the accurately known value of bcoh , natO = 5.805(4) fm which is equal to bcoh , 16O within the experimental uncertainty. Our results for bcoh , 17O and bcoh , 18O differ appreciably from the standard tabulated values of 5.6(5) fm and 5.84(7) fm, respectively. In particular, our measured scattering length contrast of 0.204(3) fm between 18O and natO is nearly a factor of 6 greater than the tabulated value, which renders feasible neutron diffraction experiments using 18O isotope substitution and thereby offers new possibilites for measuring the partial structure factors of oxygen-containing compounds, such as water.

  6. Stable Isotope Protocols: Sampling and Sample Processing

    E-Print Network [OSTI]

    Levin, Lisa A; Currin, Carolyn

    2012-01-01T23:59:59.000Z

    plants, benthic microalgae [BMI], benthic macroalgae) andin a dessicator, prior to analysis. A.2 Benthic microalgaeBenthic microalgae (BMI) can be collected for isotope

  7. EIS-0249: Medical Isotopes Production Project

    Broader source: Energy.gov [DOE]

    This EIS evaluates the potential environmental impacts of a proposal to establish a production capability for molybdenum-99 (Mo-99) and related medical isotopes.

  8. Integration of Nontraditional Isotopic Systems Into Reaction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Water-Rock Interaction, and Impacts of Water Chemistry on Reservoir Sustainability Integration of Nontraditional Isotopic Systems Into Reaction-Transport Models of EGS For...

  9. Stable Isotope Fractionations in Biogeochemical Reactive Transport

    E-Print Network [OSTI]

    Druhan, Jennifer Lea

    2012-01-01T23:59:59.000Z

    34 S fractionation . Summary A mesoscale study of isotopicion exchange and ! 44 Ca . A mesoscale study of isotopicmodeling and ! 34 S . A mesoscale study of isotopic

  10. Method for isotope enrichment by photoinduced chemiionization

    DOE Patents [OSTI]

    Dubrin, James W. (Walnut Creek, CA)

    1985-01-01T23:59:59.000Z

    Isotope enrichment, particularly .sup.235 U enrichment, is achieved by irradiating an isotopically mixed vapor feed with radiant energy at a wavelength or wavelengths chosen to selectively excite the species containing a desired isotope to a predetermined energy level. The vapor feed if simultaneously reacted with an atomic or molecular reactant species capable of preferentially transforming the excited species into an ionic product by a chemiionization reaction. The ionic product, enriched in the desired isotope, is electrostatically or electromagnetically extracted from the reaction system.

  11. Chlorophylls - natural solar cells

    E-Print Network [OSTI]

    Jantschi, Lorentz; Balan, Mugur C; Sestras, Radu E

    2011-01-01T23:59:59.000Z

    A molecular modeling study was conducted on a series of six natural occurring chlorophylls. Quantum chemistry calculated orbital energies were used to estimate frequency of transitions between occupied molecular orbital and unoccupied molecular orbital energy levels of chlorophyll molecules in vivo conditions in standard (ASTMG173) environmental conditions. Obtained results are in good agreement with energies necessary to fix the Magnesium atom by chlorophyll molecules and with occurrence of chlorophylls in living vegetal organisms.

  12. O isotopic composition of CaCO3 measured by continuous ow isotope ratio mass spectrometry

    E-Print Network [OSTI]

    d13 C and d18 O isotopic composition of CaCO3 measured by continuous ¯ow isotope ratio mass. This new method streamlines the classical phosphoric acid/calcium carbonate (H3PO4/CaCO3) reaction method XL continuous flow isotope ratio mass spectrometer. Conditions for which the H3PO4/CaCO3 reaction

  13. Discovery of Isotopes of Elements with Z $\\ge$ 100

    E-Print Network [OSTI]

    M. Thoennessen

    2012-03-09T23:59:59.000Z

    Currently, 163 isotopes of elements with Z $\\ge$ 100 have been observed and the discovery of these isotopes is discussed here. For each isotope a brief synopsis of the first refereed publication, including the production and identification method, is presented.

  14. Gamma Spectrum from Neutron Capture on Tungsten Isotopes

    E-Print Network [OSTI]

    Hurst, Aaron

    2011-01-01T23:59:59.000Z

    FROM NEUTRON CAPTURE ON TUNGSTEN ISOTOPES A. M. HURST ?1,2 ,capture on the stable tungsten isotopes is presented, withknown decay schemes of the tungsten isotopes from neutron

  15. Natural air motion in passive buildings

    SciTech Connect (OSTI)

    Balcomb, J.D.; Jones, G.F.

    1985-01-01T23:59:59.000Z

    The nature of natural convection is described, and a design chart is presented appropriate to a simple, single-doorway situation. Natural convective loops that can occur in buildings are described and a few experimental results are presented. Observations of stratification are discussed, similitude experiments are described, and the beginnings of a complete-system mathematical model are presented.

  16. 99.996 %{sup 12}C films isotopically enriched and deposited in situ

    SciTech Connect (OSTI)

    Dwyer, K. J. [Department of Materials Science and Engineering, University of Maryland, College Park, Maryland 20740 (United States) [Department of Materials Science and Engineering, University of Maryland, College Park, Maryland 20740 (United States); National Institute of Standards and Technology, Gaithersburg, Maryland 20899-8423 (United States); Pomeroy, J. M.; Simons, D. S. [National Institute of Standards and Technology, Gaithersburg, Maryland 20899-8423 (United States)] [National Institute of Standards and Technology, Gaithersburg, Maryland 20899-8423 (United States)

    2013-06-24T23:59:59.000Z

    Ionizing natural abundance carbon dioxide gas, we extract and mass select the ions, depositing thin films isotopically enriched to 99.9961(4) %{sup 12}C as measured by secondary ion mass spectrometry (SIMS). In solid state quantum information, coherence times of nitrogen-vacancy (NV) centers in {sup 12}C enriched diamond exceeding milliseconds demonstrate the viability of NV centers as qubits, motivating improved isotopic enrichment. NV centers in diamond are particularly attractive qubit candidates due to the optical accessibility of the spin states. We present SIMS analysis and cross-sectional scanning electron microscopy of {sup 12}C enriched thin film samples grown with this method.

  17. Solvent dependence of the carbon kinetic isotope effect on the decarboxylation of 4-pyridylacetic acid. A model for enzymatic decarboxylations

    SciTech Connect (OSTI)

    Marlier, J.F.; O'Leary, M.H.

    1986-08-06T23:59:59.000Z

    Carbon kinetic isotope effects have been measured for the decarboxylation of 4-pyridylacetic acid in pure water and in water-dioxane mixtures at 25/sup 0/C. The isotope effects are k/sup 12//k/sup 13/ = 1.064 in 75% dioxane, 1.060 in 50% dioxane, 1.056 in 25% dioxane, and 1.057 in pure water. The decrease in kinetic isotope effect parallels a more dramatic 4000-fold decrease in the observed first-order rate constant on going from 75% dioxane to pure water. No solvent isotope effect is observed in 50% water/dioxane, and as expected, the carbon isotope effect is the same in 50% D/sub 2/O/dioxane as in 50% H/sub 2/O/dioxane. The reaction appears to occur in a single step, without appreciable proton movement. The variation in rate is attributed to variations in the degree of transition-state solvation with only very small changes in ground-state effects and in the degree of carbon-carbon bond breaking in the transition state. These results indicate that the magnitudes of isotope effects observed in model reactions in H/sub 2/O are an appropriate model for magnitudes of isotope effects in enzymatic decarboxylations.

  18. Tropical Pacific nutrient dynamics in the modern and pleistocene ocean : insights from the nitrogen isotope system

    E-Print Network [OSTI]

    Rafter, Patrick Anthony

    2009-01-01T23:59:59.000Z

    nitrogen isotopes, an enrichment that is conventionallyisotopes upon denitrification also imparts a strong isotopic enrichment

  19. Solubility trapping in formation water as dominant CO2 sink in natural gas fields

    E-Print Network [OSTI]

    Haszeldine, Stuart

    LETTERS Solubility trapping in formation water as dominant CO2 sink in natural gas fields Stuart M removal in nine natural gas fields in North America, China and Europe, using noble gas and carbon isotope tracers. The natural gas fields investigated in our study are dominated by a CO2 phase and provide

  20. Geochemical and carbon isotopic studies of crude oil destruction, bitumen precipitation, and sulfate reduction in the deep Smackover Formation

    SciTech Connect (OSTI)

    Sassen, R. (Louisiana State Univ., Baton Rouge (USA))

    1988-01-01T23:59:59.000Z

    Crude oil generated by the Lower Smackover source facies migrated to Upper Smackover reservoirs where slow thermal cracking of crude oil resulted in the formation of gas-condensate and late solid bitumen. Ultimately, only pyrobitumen, methane, and nonhydrocarbon gases including hydrogen sulfide persist in the deepest Smackover reservoirs. The carbon isotopic compositions of crude oils became heavier during crude oil destruction. The carbon isotopic compositions of asphaltenes, NSO-compounds, and saturated hydrocarbons in late solid bitumen and the Lower Smackover source facies became isotopically lighter during crude oil destruction. It is suggested that some isotopically-light components from crude oils were incorporated in late solid bitumen by reactions involving thermochemical sulfate reduction. Thermochemical sulfate reduction and crude oil destruction occurred over a long span of geologic time at temperatures in the 120-150C range.

  1. Spatial periphery of lithium isotopes

    SciTech Connect (OSTI)

    Galanina, L. I., E-mail: galan_lidiya@mail.ru; Zelenskaja, N. S. [Moscow State University, Skobeltsyn Institute of Nuclear Physics (Russian Federation)

    2013-12-15T23:59:59.000Z

    The spatial structure of lithium isotopes is studied with the aid of the charge-exchange and (t, p) reactions on lithium nuclei. It is shown that an excited isobaric-analog state of {sup 6}Li (0{sup +}, 3.56MeV) has a halo structure formed by a proton and a neutron, that, in the {sup 9}Li nucleus, there is virtually no neutron halo, and that {sup 11}Li is a Borromean nucleus formed by a {sup 9}Li core and a two-neutron halo manifesting itself in cigar-like and dineutron configurations.

  2. Isotopic Scaling in Nuclear Reactions

    E-Print Network [OSTI]

    M. B. Tsang; W. A. Friedman; C. K. Gelbke; W. G. Lynch; G. Verde; H. Xu

    2001-03-26T23:59:59.000Z

    A three parameter scaling relationship between isotopic distributions for elements with Z$\\leq 8$ has been observed that allows a simple description of the dependence of such distributions on the overall isospin of the system. This scaling law (termed iso-scaling) applies for a variety of reaction mechanisms that are dominated by phase space, including evaporation, multifragmentation and deeply inelastic scattering. The origins of this scaling behavior for the various reaction mechanisms are explained. For multifragmentation processes, the systematics is influenced by the density dependence of the asymmetry term of the equation of state.

  3. Stable carbon and nitrogen isotope enrichment in primate tissues

    E-Print Network [OSTI]

    Crowley, Brooke E.; Carter, Melinda L.; Karpanty, Sarah M.; Zihlman, Adrienne L.; Koch, Paul L.; Dominy, Nathaniel J.

    2010-01-01T23:59:59.000Z

    carbon and nitrogen isotope enrichment in primate tissuesfactor (a) and isotope enrichment values (e), which provideisotope values from different modern primate tissues. Additionally, using these mean apparent enrichment

  4. CRAD, Engineering - Oak Ridge National Laboratory High Flux Isotope...

    Broader source: Energy.gov (indexed) [DOE]

    Engineering - Oak Ridge National Laboratory High Flux Isotope Reactor Contractor ORR CRAD, Engineering - Oak Ridge National Laboratory High Flux Isotope Reactor Contractor ORR...

  5. CRAD, Engineering - Oak Ridge National Laboratory High Flux Isotope...

    Broader source: Energy.gov (indexed) [DOE]

    Oak Ridge National Laboratory High Flux Isotope Reactor CRAD, Engineering - Oak Ridge National Laboratory High Flux Isotope Reactor February 2007 A section of Appendix C to DOE G...

  6. aluminium isotopes: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CERN Preprints Summary: Currently, 31 actinium, 31 thorium, 28 protactinium, and 23 uranium isotopes have so far been observed; the discovery of these isotopes is discussed. For...

  7. americium isotopes: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CERN Preprints Summary: Currently, 31 actinium, 31 thorium, 28 protactinium, and 23 uranium isotopes have so far been observed; the discovery of these isotopes is discussed. For...

  8. activated bismuth isotopes: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CERN Preprints Summary: Currently, 31 actinium, 31 thorium, 28 protactinium, and 23 uranium isotopes have so far been observed; the discovery of these isotopes is discussed. For...

  9. astatine isotopes: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CERN Preprints Summary: Currently, 31 actinium, 31 thorium, 28 protactinium, and 23 uranium isotopes have so far been observed; the discovery of these isotopes is discussed. For...

  10. A Helium Isotope Perspective On The Dixie Valley, Nevada, Hydrothermal...

    Open Energy Info (EERE)

    Helium Isotope Perspective On The Dixie Valley, Nevada, Hydrothermal System Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: A Helium Isotope...

  11. Isotopic Analysis- Fluid At Dixie Valley Geothermal Area (Kennedy...

    Open Energy Info (EERE)

    geothermal resources with deep, fault hosted permeable fluid flow pathways and the helium Isotopic composition of the surface fluids. The authors suggest that helium isotopes...

  12. Fractionation of Oxygen Isotopes in Phosphate during its Interactions...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fractionation of Oxygen Isotopes in Phosphate during its Interactions with Iron Oxides. Fractionation of Oxygen Isotopes in Phosphate during its Interactions with Iron Oxides....

  13. applied isotope techniques: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    M. 22 Applied Radiation and Isotopes 55 (2001) 707713 Bronchial dosimeter for radon progeny Biology and Medicine Websites Summary: Applied Radiation and Isotopes 55 (2001)...

  14. Advanced Mass Spectrometers for Hydrogen Isotope Analyses

    SciTech Connect (OSTI)

    Chastagner, P.

    2001-08-01T23:59:59.000Z

    This report is a summary of the results of a joint Savannah River Laboratory (SRL) - Savannah River Plant (SRP) ''Hydrogen Isotope Mass Spectrometer Evaluation Program''. The program was undertaken to evaluate two prototype hydrogen isotope mass spectrometers and obtain sufficient data to permit SRP personnel to specify the mass spectrometers to replace obsolete instruments.

  15. MARK E. CONRAD Center for Isotope Geochemistry

    E-Print Network [OSTI]

    Ajo-Franklin, Jonathan

    with stable isotopes, fate and transport of groundwater contaminants, vadose zone hydrology, metal uptake by lichens, paleoclimatic patterns in California and stable isotope systematics of clay minerals. Geologist of gold property in the Mother Lode of California. Exploration Geologist (Anaconda Minerals Company; 6

  16. The Quest for the Heaviest Uranium Isotope

    E-Print Network [OSTI]

    S. Schramm; D. Gridnev; D. V. Tarasov; V. N. Tarasov; W. Greiner

    2012-01-17T23:59:59.000Z

    We study Uranium isotopes and surrounding elements at very large neutron number excess. Relativistic mean field and Skyrme-type approaches with different parametrizations are used in the study. Most models show clear indications for isotopes that are stable with respect to neutron emission far beyond N=184 up to the range of around N=258.

  17. Isotope separation by selective photodissociation of glyoxal

    DOE Patents [OSTI]

    Marling, John B. (Pleasanton, CA)

    1976-01-01T23:59:59.000Z

    Dissociation products, mainly formaldehyde and carbon monoxide, enriched in a desired isotope of carbon, oxygen, or hydrogen are obtained by the selective photodissociation of glyoxal wherein glyoxal is subjected to electromagnetic radiation of a predetermined wavelength such that photon absorption excites and induces dissociation of only those molecules of glyoxal containing the desired isotope.

  18. [Carbon isotope fractionation inplants]. Final report

    SciTech Connect (OSTI)

    O`Leary, M.H.

    1990-12-31T23:59:59.000Z

    The objectives of this research are: To develop a theoretical and experimental framework for understanding isotope fractionations in plants; and to develop methods for using this isotope fractionation for understanding the dynamics of CO{sub 2} fixation in plants. Progress is described.

  19. Atomic-scale characterization of germanium isotopic multilayers by atom probe tomography

    SciTech Connect (OSTI)

    Shimizu, Y.; Takamizawa, H.; Toyama, T.; Inoue, K.; Nagai, Y. [Oarai Center, Institute for Materials Research, Tohoku University, 2145-2 Narita, Oarai, Ibaraki 311-1313 (Japan); Kawamura, Y.; Uematsu, M.; Itoh, K. M. [School of Fundamental Science and Technology, Keio University, 3-14-1 Hiyoshi, Kohoku-ku, Yokohama 223-8522 (Japan); Haller, E. E. [University of California at Berkeley and Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, California 94720 (United States)

    2013-01-14T23:59:59.000Z

    We report comparison of the interfacial sharpness characterization of germanium (Ge) isotopic multilayers between laser-assisted atom probe tomography (APT) and secondary ion mass spectrometry (SIMS). An alternating stack of 8-nm-thick naturally available Ge layers and 8-nm-thick isotopically enriched {sup 70}Ge layers was prepared on a Ge(100) substrate by molecular beam epitaxy. The APT mass spectra consist of clearly resolved peaks of five stable Ge isotopes ({sup 70}Ge, {sup 72}Ge, {sup 73}Ge, {sup 74}Ge, and {sup 76}Ge). The degree of intermixing at the interfaces between adjacent layers was determined by APT to be around 0.8 {+-} 0.1 nm which was much sharper than that obtained by SIMS.

  20. Stable isotopic investigations of in situ bioremediation of chlorinated organic solvents. 1997 annual progress report

    SciTech Connect (OSTI)

    Sturchio, N.C.

    1997-01-01T23:59:59.000Z

    'The author has made significant progress in developing innovative methods for investigating the mechanism and extent of in situ bioremediation of chlorinated organic solvents. These methods use precise isotopic ratio measurements of chlorine and carbon in reactant and product species in laboratory experiments and in materials from field demonstration sites. Specific tasks completed during FY 1997 include: (1) refinement and publication of a new analytical method for precise determination of chlorine and carbon isotope ratios in chlorinated volatile organic compounds; (2) laboratory experiments involving biological degradation of chlorinated solvents in liquid cultures and soil columns; and (3) use of chlorine and carbon isotope ratios to investigate natural attenuation of trichloroethene at the Paducah Gaseous Diffusion Plant. This work can have immediate impact because it will provide the fundamental basis for a new and cost-effective means of evaluating and monitoring the effectiveness of in situ bioremediation schemes for chlorinated organic solvents in soils, vadose horizons, and groundwater plumes.'

  1. ISOTOPES

    E-Print Network [OSTI]

    Lederer, C. Michael

    2013-01-01T23:59:59.000Z

    constructed to enrich liquid UF6 slightly as feed for thej) b. Optimum a. s: .X. UF6 feed, (kg per year) XBL 7912 -

  2. ISOTOPES

    E-Print Network [OSTI]

    Lederer, C. Michael

    2013-01-01T23:59:59.000Z

    lithium hydroxide (56, 14), A plant utilizing this reaction to produce 1000 kg per year of 99.99% 7Li at a price

  3. ISOTOPES

    E-Print Network [OSTI]

    Lederer, C. Michael

    2013-01-01T23:59:59.000Z

    §fissile materials in fast breeder reactors currently underwater reactor, FBR = fast breeder reactor. The band belowinc 1 udes heavy-water reactors, fast breeders, and 11

  4. ISOTOPES

    E-Print Network [OSTI]

    Lederer, C. Michael

    2013-01-01T23:59:59.000Z

    1978). United States Gas Centrifuge Program for 72. Energy~~;h)radius in a gas centrifuge with va 400 m/s. P 0 and U68,14) of a gas centrifuge with radius = 0.09145 m, length=

  5. ISOTOPES

    E-Print Network [OSTI]

    Lederer, C. Michael

    2013-01-01T23:59:59.000Z

    the columns used to separate UF5, which had a separativeof uranium by dissociation of UF5, by multiple vibrational

  6. Comparison of LaBr3:Ce and NaI(Tl) Scintillators for Radio-Isotope Identification Devices

    SciTech Connect (OSTI)

    Milbrath, Brian D.; Choate, Bethany J.; Fast, Jim E.; Hensley, Walter K.; Kouzes, Richard T.; Schweppe, John E.

    2006-07-31T23:59:59.000Z

    Lanthanum halide (LaBr3:Ce) scintillators offer significantly better resolution (<3 percent at 662 kilo-electron volt [keV]) relative to sodium iodide (NaI(Tl)) and have recently become commercially available in sizes large enough for the hand-held radio-isotope identification device (RIID) market. There are drawbacks to lanthanum halide detectors, however. These include internal radioactivity that contributes to spectral counts and a low-energy response that can cause detector resolution to be lower than that of NaI(Tl) below 100 keV. To study the potential of this new material for RIIDs, we performed a series of measurements comparing a 1.5?1.5 inch LaBr?3:Ce detector with an Exploranium GR 135 RIID, which contains a 1.5-2.2 inch NaI(Tl) detector. Measurements were taken for short time frames, as typifies RIID usage. Measurements included examples of naturally occurring radioactive material (NORM), typically found in cargo, and special nuclear materials. Some measurements were noncontact, involving short distances or cargo shielding scenarios. To facilitate direct comparison, spectra from the different detectors were analyzed with the same isotope identification software (ORTEC ScintiVision TM). In general, the LaBr3:Ce detector was able to find more peaks and find them faster than the NaI(Tl) detector. To the same level of significance, the LaBr3:Ce detector was usually two to three times faster. The notable exception was for 40K containing NORM where interfering internal contamination in the LaBr3:Ce detector exist. NaI(Tl) consistently outperformed LaBr3:Ce for this important isotope. LaBr3:Ce currently costs much more than NaI(Tl), though this cost-difference is expected to diminish (but not completely) with time. As is true of all detectors, LaBr3:Ce will need to be gain-stabilized for RIID applications. This could possibly be done using the internal contaminants themselves. It is the experience of the authors that peak finding software in RIIDs needs to be improved, regardless of the detector material.

  7. Isotopic composition of Silurian seawater

    SciTech Connect (OSTI)

    Knauth, L.P.; Kealy, S.; Larimer, S.

    1985-01-01T23:59:59.000Z

    Direct isotopic analyses of 21 samples of the Silurian hydrosphere preserved as fluid inclusions in Silurian halite deposits in the Michigan Basin Salina Group yield delta/sup 18/O, deltaD ranging from 0.2 to +5.9 and -26 to -73, respectively. delta/sup 18/O has the same range as observed for modern halite facies evaporite waters and is a few per thousand higher than 100 analyses of fluid inclusions in Permian halite. deltaD is about 20 to 30 per thousand lower than modern and Permian examples. The trajectory of evaporating seawater on a deltaD-delta/sup 18/O diagram initially has a positive slope of 3-6, but hooks strongly downward to negative values, the shape of the hook depending upon humidity. Halite begins to precipitate at delta values similar to those observed for the most /sup 18/O rich fluid inclusions. Subsequent evaporation yields progressively more negative delta values as observed for the fluid inclusions. The fluid inclusion data can be readily explained in terms of evaporating seawater and are consistent with the degree of evaporation deduced from measured bromide profiles. These data are strongly inconsistent with arguments that Silurian seawater was 5.5 per thousand depleted in /sup 18/O. delta/sup 18/O for evaporite waters is systematically related to that of seawater, and does not show a -5.5 per thousand shift in the Silurian, even allowing for variables which affect the isotope evaporation trajectory. The lower deltaD may indicate a component of gypsum dehydration waters or may suggest a D-depleted Silurian hydrosphere.

  8. responses to environmental changes that are significantly more abrupt than those that would occur in nature. A

    E-Print Network [OSTI]

    Kaspari, Mike

    to a different growth chamber after every five weeks, and the appropriate [CO2] was re-set. Plants were watered weeks. At harvest, soil was collected using a 10-cm diameter corer. This soil core was then used to trap colonization26 . The total length of fungal hyphae was determined after extraction from a subsample of soil

  9. Received 20 Feb 2014 | Accepted 27 May 2014 | Published 24 Jun 2014 Naturally occurring tumours in the basal

    E-Print Network [OSTI]

    cesta 54, HR-10000 Zagreb, Croatia. 3 Catholic University of Croatia, Ilica 242, HR-10000 Zagreb, Croatia. 4 Zoological Institute of Russian Academy of Sciences, Universitetskaya emb. 1, 199034 St

  10. Bisphosphonates and Bone diseases: past, present and future Bisphosphonates are stable analogues of the naturally-occuring inorganic

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    involving excessive bone resorption which include post-menopausal osteoporosis, Paget's disease of bone

  11. NATURE|Vol 437|29 September 2005 NEWS & VIEWS (as occurred in the 1960s compared with the

    E-Print Network [OSTI]

    Elowitz, Michael

    -levelcircuitry.Similarassays,applied in yeast and the bacterium Escherichia coli, have detected both sources of noise and shown how: achieving a better understanding of that variability is one of the next challenges in marine biogeochemistry

  12. IN-SITU SAMPLING AND CHARACTERIZATION OF NATURALLY OCCURRING MARINE METHANE HYDRATE USING THE D/V JOIDES RESOLUTION

    SciTech Connect (OSTI)

    Frank R. Rack; Peter Schultheiss; Melanie Holland

    2005-01-01T23:59:59.000Z

    The primary accomplishments of the JOI Cooperative Agreement with DOE/NETL in this quarter were that: (1) follow-up logging of pressure cores containing hydrate-bearing sediment; and (2) opening of some of these cores to establish ground-truth understanding. The follow-up measurements made on pressure cores in storage are part of a hydrate geriatric study related to ODP Leg 204. These activities are described in detail in Appendices A and B of this report. Work also continued on developing plans for Phase 2 of this cooperative agreement based on evolving plans to schedule a scientific ocean drilling expedition to study marine methane hydrates along the Cascadia margin, in the NE Pacific as part of the Integrated Ocean Drilling Program (IODP) using the R/V JOIDES Resolution.

  13. In-Situ Sampling and Characterization of Naturally Occuring Marine Methane Hydrate Using the D/V JOIDES Resolution

    SciTech Connect (OSTI)

    Frank Rack; Gilles Guerin; David Goldberg; ODP Leg 204 Shipboard Scientific Party

    2003-12-31T23:59:59.000Z

    The primary accomplishments of the JOI Cooperative Agreement with DOE/NETL in this quarter were that: (1) Leg 204 scientific party members presented preliminary results and operational outcomes of ODP Leg 204 at the American Geophysical Union Fall meeting, which was held in San Francisco, CA; and, (2) a report was prepared by Dr. Gilles Guerin and David Goldberg from Lamont-Doherty Earth Observatory of Columbia University on their postcruise evaluation of the data, tools and measurement systems that were used for vertical seismic profiling (VSP) experiments during ODP Leg 204. The VSP report is provided herein. Intermediate in scale and resolution between the borehole data and the 3-D seismic surveys, the Vertical Seismic Profiles (VSP) carried during Leg 204 were aimed at defining the gas hydrate distribution on hydrate ridge, and refining the signature of gas hydrate in the seismic data. VSP surveys were attempted at five sites, following completion of the conventional logging operations. Bad hole conditions and operational difficulties did not allow to record any data in hole 1245E, but vertical and constant offset VSP were successful in holes 1244E, 1247B and 1250F, and walk-away VSP were successfully completed in holes 1244E, 1250F and 1251H. Three different tools were used for these surveys. The vertical VSP provided the opportunity to calculate interval velocity that could be compared and validated with the sonic logs in the same wells. The interval velocity profiles in Holes 1244E and 1247B are in very good agreement with the sonic logs. Information about the Leg 204 presentations at the AGU meeting are included in a separate Topical Report, which has been provided to DOE/NETL in addition to this Quarterly Report. Work continued on analyzing data collected during ODP Leg 204 and preparing reports on the outcomes of Phase 1 projects as well as developing plans for Phase 2.

  14. In-Situ Sampling and Characterization of Naturally Occurring Marine Methane Hydrate Using the D/V JOIDES Resolution

    SciTech Connect (OSTI)

    Frank Rack; Peter Schultheiss; IODP Expedition 311 Scientific Party

    2005-12-31T23:59:59.000Z

    The primary accomplishments of the JOI Cooperative Agreement with DOE/NETL in this quarter were the implementation of a scientific ocean drilling expedition to study marine methane hydrates along the Cascadia margin, in the NE Pacific as part of Integrated Ocean Drilling Program (IODP) Expedition 311 using the R/V JOIDES Resolution and the deployment of all required equipment and personnel to provide the required services during this expedition. IODP Expedition 311 shipboard activities on the JOIDES Resolution began on August 28 and were concluded on October 28, 2005. New ODP Pressure Coring System (PCS) aluminum autoclave chambers were fabricated prior to the expedition. During the expedition, 16 PCS autoclaves containing pressure cores were X-rayed before and after depressurization using a modified Geotek MSCL-P (multi-sensor core logger-pressure) system. These PCS cores were density scanned using the MSCL-V (multi-sensor core logger-vertical) during depressurization to monitor gas evolution. The MSCL-V was set up in a 20-foot-long refrigerated container provided by Texas A&M University through the JOI contract with TAMRF. IODP Expedition 311 was the first time that PCS cores were examined before (using X-ray), during (using MSCL-V gamma density) and after (using X-ray) degassing to determine the actual volume and distribution of sediment and gas hydrate in the pressurized core, which will be important for more accurate determination of mass balances between sediment, gas, gas hydrate, and fluids in the samples collected. Geotek, Ltd was awarded a contract by JOI to provide equipment and personnel to perform pressure coring and related work on IODP Expedition 311 (Cascadia Margin Gas Hydrates). Geotek, Ltd. provided an automated track for use with JOI's infrared camera systems. Four auxiliary monitors showed infrared core images in real time to aid hydrate identification and sampling. Images were collected from 185 cores during the expedition and processed to provide continuous core temperature data. The HYACINTH pressure coring tools, subsystems, and core logging systems were mobilized to Astoria, Oregon. Both HYACINTH pressure coring tools, the HRC (HYACE Rotary Corer) and the FPC (Fugro Pressure Corer) were mobilized and used during the expedition. Two HYACINTH engineers supervised the use of the tools and five good pressure cores were obtained. Velocity, density and X-ray linear scanning data were collected from these cores at near in situ pressure using the MSCL-P system. Dr. Barry Freifeld from Lawrence Berkeley National Laboratory provided an X-ray source and detector for X-ray imaging of pressure cores and helped Geotek with the design and mobilization of the MSCL-P system. Pressure core handling, transfer, and logging was performed in a refrigerated 20-foot container supplied by Geotek, Ltd. After scanning, the pressure cores were stored for on-shore analysis in aluminum barrels. Additional studies were conducted at the Pacific Geoscience Center (PGC), where a shore based laboratory was established after Expedition 311.

  15. In-Situ Sampling and Characterization of Naturally Occurring Marine Methane Hydrate Using the D/V JOIDES Resolution

    SciTech Connect (OSTI)

    Frank Rack

    2001-12-31T23:59:59.000Z

    The primary accomplishments during the first quarter were to mobilize materials and supplies to meet the deployment schedule for equipment and activities, as proposed under the DOE/NETL cooperative agreement with JOI, with initial testing and use of specialized tools and equipment on Ocean Drilling Program (ODP) Leg 201. As a requirement of the award, two copies of a technical feasibility report entitled ''Preliminary Evaluation of Existing Pressure/Temperature Coring Systems'' were delivered to DOE/NETL on October 22, 2001. The report was written to provide a discussion of the availability and compatibility of the four existing pressure coring devices in existence. Most of these systems are available for use by JOI/ODP aboard the D/V JOIDES Resolution, via purchase, lease, modification, etc. and the proposed capabilities to upgrade existing devices or systems for use on other platforms. In addition, the report provided a discussion of the compatibility of each existing coring device in conjunction with the use of the other coring devices, such as the advanced piston coring (APC) system used by ODP. Based on an evaluation of the JOI report, the DOE/NETL Program Manager William Gwilliam provided a ''Go'' decision to JOI for the further development of the ODP Pressure Coring System (PCS) and PCS Gas Manifold. During the reporting period negotiations were conducted with various potential subcontractors and vendors to establish the specific cost-sharing arrangements and work breakdown necessary to definitize the terms of the DOE/NETL cooperative agreement with JOI. The discussions were communicated with the DOE/NETL Program Manager, William Gwilliam, to keep NETL closely informed about events as this project evolved. A series of meetings were also held with ODP engineers, technical staff, and to plan for the implementation of the various tasks outlined in the JOI proposal to DOE for deployment during ODP Legs 201 and 204. These meetings helped to answer numerous unresolved questions and establish a firm timetable of remaining activities that needed to be accomplished by January 28, 2002, when ODP Leg 201 will begin.

  16. Crime and Fire Log Nature Case No. Date/Time Reported Date/Time Occurred Location Disposition

    E-Print Network [OSTI]

    Loudon, Catherine

    /27/2011 1023 W Peltason Dr, Irvine Inactive 12/27/2011 Battery On Person 11-1409 12/24/2011 21:30 12/24/2011 22/30/2011 - 12/10/2011 6322 Verano Rd, Irvine Inactive 12/11/2011 Battery On Person 11-1369 12/10/2011 01:34 12/10/2011 01:33 - 12/10/2011 International Peace House Pending Grand Theft:Money/Prop/Etc $950+ 11-1366 12

  17. In-Situ Sampling and Characterization of Naturally Occurring Marine Methane Hydrate Using the D/V JOIDES Resolution

    SciTech Connect (OSTI)

    Frank Rack

    2005-06-30T23:59:59.000Z

    The primary accomplishments of the JOI Cooperative Agreement with DOE/NETL in this quarter were to refine budgets and operational plans for Phase 2 of this cooperative agreement based on the scheduling of a scientific ocean drilling expedition to study marine methane hydrates along the Cascadia margin, in the NE Pacific as part of the Integrated Ocean Drilling Program (IODP) using the R/V JOIDES Resolution. The proposed statement of work for Phase 2 will include three primary tasks: (1) research management oversight, provided by JOI; (2) mobilization, deployment and demobilization of pressure coring and core logging systems, through a subcontract with Geotek Ltd., who will work with Fugro and Lawrence Berkeley National Laboratory to accomplish some of the subtasks; and, (3) mobilization, deployment and demobilization of a refrigerated container van that will be used for degassing of the Pressure Core Sampler and density logging of these pressure cores, through a subcontract with the Texas A&M Research Foundation (TAMRF). More details about these tasks are provided in the following sections of this report. The appendices to this report contain a copy of the scientific prospectus for the upcoming IODP Expedition 311 (Cascadia Margin Hydrates), which provides details of operational and scientific planning for this expedition.

  18. Lab 2: Mineral Lab notes. Minerals are inorganic, solid, naturally occurring substances that have a characteristic chemical compositions,

    E-Print Network [OSTI]

    Li, X. Rong

    a characteristic chemical compositions, distinctive physical properties, and crystalline structures. Chemical is silicon dioxide SiO2; the mineral galena is an ore of lead, and its chemical formula is PbS, a lead sulfide; and the mineral calcite, which is used as an antacid and in fertilizers, is calcium carbonate Ca

  19. IN-SITU SAMPLING AND CHARACTERIZATION OF NATURALLY OCCURRING MARINE METHANE HYDRATE USING THE D/V JOIDES RESOLUTION

    SciTech Connect (OSTI)

    Frank R. Rack; Tim Francis; Peter Schultheiss; Philip E. Long; Barry M. Freifeld

    2005-04-01T23:59:59.000Z

    The primary activities accomplished during this quarter were continued efforts to develop plans for Phase 2 of this cooperative agreement based on the evolving operational planning for IODP Expedition 311, which will use the JOIDES Resolution to study marine methane hydrates along the Cascadia margin, offshore Vancouver Island. IODP Expedition 311 has been designed to further constrain the models for the formation of marine gas hydrate in subduction zone accretionary prisms. The objectives include characterizing the deep origin of the methane, its upward transport, its incorporation in gas hydrate, and its subsequent loss to the seafloor. The main attention of this expedition is on the widespread seafloor-parallel layer of dispersed gas hydrate located just above the base of the predicted stability field. In a gas hydrate formation model, methane is carried upward through regional sediment or small-scale fracture permeability, driven by the tectonic consolidation of the accretionary prism. The upward moving methane is incorporated into the gas hydrate clathrate as it enters the methane hydrate stability zone. Also important is the focusing of a portion of the upward methane flux into localized plumes or channels to form concentrations of near-seafloor gas hydrate. The amount of gas hydrate in local concentrations near the seafloor is especially important for understanding the response of marine gas hydrate to climate change. The expedition includes coring and downhole measurements at five sites across the Northern Cascadia accretionary prism. The sites will track the history of methane in an accretionary prism from (1) its production by mainly microbiological processes over a thick sediment vertical extent, (2) its upward transport through regional or locally focused fluid flow, (3) its incorporation in the regional hydrate layer above the BSR or in local concentrations at or near the seafloor, (4) methane loss from the hydrate by upward diffusion, and (5) methane oxidation and incorporation in seafloor carbonate, or expulsion to the ocean. This expedition builds on the previous Cascadia gas hydrate drilling of ODP Leg 146 and on more recent ODP Leg 204 off Oregon. Important experiments being considered for DOE/NETL funding as part of the JOI cooperative agreement include, (1) Logging-While-Drilling/Measurements-While-Drilling (LWD/MWD), (2) Pressure Core Sampling (PCS/HYACINTH) of gas hydrate, and fluid recovery under in situ conditions, (3) X-ray CT logging of whole cores under in situ conditions, and (4) Infrared thermal imaging of whole round cores to map temperature variations resulting from the presence of hydrate. Preliminary budget estimates have been made for each of these tasks and discussions are ongoing with DOE/NETL program managers to develop a final plan that can be implemented within the constraints of the available funding and logistical considerations.

  20. In-Situ Sampling and Characterization of Naturally Occurring Marine Methane Hydrate Using the D/V JOIDES Resolution

    SciTech Connect (OSTI)

    Frank R. Rack; ODP Leg 204 Shipboard Scientific Party

    2004-09-30T23:59:59.000Z

    The primary accomplishments of the JOI Cooperative Agreement with DOE/NETL in this quarter were that: (1) postcruise evaluation of the data, tools and measurement systems that were used during ODP Leg 204 continued in the preparation of deliverables under this agreement. Work continued on analyzing data collected during ODP Leg 204 and preparing reports on the outcomes of Phase 1 projects as well as developing plans for Phase 2.

  1. IN-SITU SAMPLING AND CHARACTERIZATION OF NATURALLY OCCURRING MARINE METHANE HYDRATE USING THE D/V JOIDES RESOLUTION

    SciTech Connect (OSTI)

    Frank R. Rack

    2004-05-01T23:59:59.000Z

    The primary accomplishments of the JOI Cooperative Agreement with DOE/NETL in this quarter were that: (1) Frank Rack presented preliminary results and operational outcomes of ODP Leg 204 at the DOE/NETL project review and two made two presentations at the ChevronTexaco Gulf of Mexico Hydrate JIP meeting, which were both held in Westminster, CO; and, (2) postcruise evaluation of the data, tools and measurement systems that were used during ODP Leg 204 continued in the preparation of deliverables under this agreement. Work continued on analyzing data collected during ODP Leg 204 and preparing reports on the outcomes of Phase 1 projects as well as developing plans for Phase 2.

  2. In-Situ Sampling and Characterization of Naturally Occurring Marine Methane Hydrate Using the D/V JOIDES Resolution

    SciTech Connect (OSTI)

    Frank Rack; Michael Storms; Derryl Schroeder; Brandon Dugan; Peter Schultheiss; ODP Leg 204 Shipboard Scientific Party

    2002-12-31T23:59:59.000Z

    The primary accomplishments of the JOI Cooperative Agreement with DOE/NETL in this quarter were (1) the preliminary postcruise evaluation of the tools and measurement systems that were used during ODP Leg 204 to study hydrate deposits on Hydrate Ridge, offshore Oregon from July through September 2002; and (2) the preliminary study of the hydrate-bearing core samples preserved in pressure vessels and in liquid nitrogen cryofreezers, which are now stored at the ODP Gulf Coast Repository in College Station, TX. During ODP Leg 204, several newly modified downhole tools were deployed to better characterize the subsurface lithologies and environments hosting microbial populations and gas hydrates. A preliminary review of the use of these tools is provided herein. The DVTP, DVTP-P, APC-methane, and APC-Temperature tools (ODP memory tools) were used extensively and successfully during ODP Leg 204 aboard the D/V JOIDES Resolution. These systems provided a strong operational capability for characterizing the in situ properties of methane hydrates in subsurface environments on Hydrate Ridge during ODP Leg 204. Pressure was also measured during a trial run of the Fugro piezoprobe, which operates on similar principles as the DVTP-P. The final report describing the deployments of the Fugro Piezoprobe is provided in Appendix A of this report. A preliminary analysis and comparison between the piezoprobe and DVTP-P tools is provided in Appendix B of this report. Finally, a series of additional holes were cored at the crest of Hydrate Ridge (Site 1249) specifically geared toward the rapid recovery and preservation of hydrate samples as part of a hydrate geriatric study partially funded by the Department of Energy (DOE). In addition, the preliminary results from gamma density non-invasive imaging of the cores preserved in pressure vessels are provided in Appendix C of this report. An initial visual inspection of the samples stored in liquid nitrogen is provided in Appendix D of this report.

  3. In-Situ Sampling and Characterization of Naturally Occurring Marine Methane Hydrate Using the D/V JOIDES Resolution

    SciTech Connect (OSTI)

    Frank Rack; ODP Leg 204 Shipboard Scientific Party

    2004-06-30T23:59:59.000Z

    The primary accomplishments of the JOI Cooperative Agreement with DOE/NETL in this quarter were that: (1) post-cruise evaluation of the data, tools and measurement systems that were used during ODP Leg 204 continued in the preparation of deliverables under this agreement. Work continued on analyzing data collected during ODP Leg 204 and preparing reports on the outcomes of Phase 1 projects as well as developing plans for Phase 2.

  4. In-Situ Sampling and Characterization of Naturally Occurring Marine Methane Hydrate Using the D/V JOIDES Resolution

    SciTech Connect (OSTI)

    Frank Rack; Derryl Schroeder; Michael Storms; ODP Leg 201 Shipboard Scientific Party

    2001-03-31T23:59:59.000Z

    The primary accomplishments of the JOI Cooperative Agreement with DOE/NETL in this quarter were the deployment of tools and measurement systems for testing on ODP Leg 201, which is intended to study hydrate deposits on the Peru margin as part of other scientific investigations. Additional accomplishments were related to the continuing evolution of tools and measurements systems in preparation for deployment on ODP Leg 204, Hydrate Ridge, offshore Oregon in July 2002. The design for PCS Gas Manifold was finalized and parts were procured to assemble the gas manifold and deploy this system with the Pressure Core Sampler (PCS) tool on ODP Leg 201. The PCS was deployed 17 times during ODP Leg 201 and successfully retrieved cores from a broad range of lithologies and sediment depths along the Peru margin. Eleven deployments were entirely successful, collecting between 0.5 and 1.0 meters of sediment at greater than 75% of hydrostatic pressure. The PCS gas manifold was used in conjunction with the Pressure Core Sampler (PCS) throughout ODP Leg 201 to measure the total volume and composition of gases recovered in sediment cores associated with methane hydrates. The results of these deployments will be the subject of a future progress report. The FUGRO Pressure Corer (FPC), one of the HYACE/HYACINTH pressure coring tools, and two FUGRO engineers were deployed on the D/V JOIDES Resolution during ODP Legs 201 to field-test this coring system at sites located offshore Peru. The HYACINTH project is a European Union (EU) funded effort to develop tools to characterize methane hydrate and measure physical properties under in-situ conditions. The field-testing of these tools provides a corollary benefit to DOE/NETL at no cost to this project. The opportunity to test these tools on the D/V JOIDES Resolution was negotiated as part of a cooperative agreement between JOI/ODP and the HYACINTH partners. The DVTP, DVTP-P, APC-methane, and APC-Temperature tools (ODP memory tools) were deployed onboard the R/V JOIDES Resolution and used extensively during ODP Leg 201. Preliminary results indicate successful deployments of these tools. An infrared-thermal imaging system (IR-TIS) was delivered to JOI/ODP for testing and use on ODP Leg 201 to identify methane hydrate intervals in the recovered cores. The results of these experiments will be the subject of a future progress report. This report presents an overview of the primary methods used for deploying the ODP memory tools and PCS on ODP Leg 201 and the preliminary operational results of this leg. Discussions regarding the laboratory analysis of the recovered cores and downhole measurements made during these deployments will be covered in a future progress report.

  5. Liquid Fuels and Natural Gas in the Americas

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    materials) D 6751. Biofuels: Liquid fuels and blending components produced from biomass feedstocks, used primarily for transportation. Bitumen: A naturally occurring viscous...

  6. COMMENTS ON ANOMALOUS EFFECTS IN CHARGING OF PD POWDERS WITH HIGH DENSITY HYDROGEN ISOTOPES

    SciTech Connect (OSTI)

    Shanahan, K.

    2009-10-01T23:59:59.000Z

    In Kitamura, et al, Pd-containing materials are exposed to isotopes of hydrogen and anomalous results obtained. These are claimed to be a replication of another experiment conducted by Arata and Zhang. Erroneous basic assumptions are pointed out herein that alter the derived conclusions significantly. The final conclusion is that the reported results are likely normal chemistry combined with noise. Thus the claim to have proven that cold fusion is occurring in these systems is both premature and unlikely.

  7. Theory of the helium isotope shift

    E-Print Network [OSTI]

    Yerokhin, Vladimir A

    2015-01-01T23:59:59.000Z

    Theory of the isotope shift of the centroid energies of light few-electron atoms is reviewed. Numerical results are presented for the isotope shift of the $2^3P$-$2^3S$ and $2^1S$-$2^3S$ transition energies of $^3$He and $^4$He. By comparing theoretical predictions for the isotope shift with the experimental results, the difference of the squares of the nuclear charge radii of $^3$He and $^4$He, $\\delta R^2$, is determined with high accuracy.

  8. Mimicking Nature

    E-Print Network [OSTI]

    Wythe, Kathy

    2007-01-01T23:59:59.000Z

    into lakes and rivers, and the impact different water management decisions could have. ?We?re trying to mimic nature,? said Dr. Jeff Arnold, research leader and agricultural engineer for the Grassland Soil and Water Research Laboratory in Temple, part..., director of Texas A&M University?s Spatial Sciences Laboratory and professor in the Departments of Ecosystem Science and MIMICKING NATURE Computer model helps manage nation?s, world?s waters #2; Management, and Biological and Agricultural Engineering...

  9. Naturalness redux

    E-Print Network [OSTI]

    Marco Fabbrichesi; Alfredo Urbano

    2015-04-21T23:59:59.000Z

    The idea of naturalness, as originally conceived, refers only to the finite renormalization of the Higgs boson mass induced by the introduction of heavier states. In this respect, naturalness is still a powerful heuristic principle in model building beyond the standard model whenever new massive states are coupled to the Higgs field. The most compelling case is provided by the generation of neutrino masses. In this paper we confront this problem from a new perspective. The right-handed sector responsible for the seesaw mechanism---which introduces a large energy threshold above the electroweak scale---is made supersymmetric to comply with naturalness while the standard model is left unchanged and non-supersymmetric. Cancellations necessary to the naturalness requirement break down only at two loops, thus offering the possibility to increase the right-handed neutrino mass scale up to one order of magnitude above the usual values allowed by naturalness. If also the weak boson sector of the standard model is made supersymmetric, cancellations break down at three loops and the scale of new physics can be further raised. In the type-I seesaw, this implementation provides right-handed neutrino masses that are natural and at the same time large enough to give rise to baryogenesis (via leptogenesis). The model contains a dark matter candidate and distinctive new physics in the leptonic sector.

  10. Helium isotopes in historical lavas from Mount Vesuvius Comment on `Noble gas isotopic ratios from historical lavas

    E-Print Network [OSTI]

    Graham, David W.

    Discussion Helium isotopes in historical lavas from Mount Vesuvius Comment on `Noble gas isotopic. Introduction Helium isotope results recently published by Tedesco et al. [1] appear to show a decrease in 3 He. Results Helium isotope results from our laboratory are reported in Table 1. The 3 He/4 He ratio has been

  11. Filter for isotopic alteration of mercury vapor

    DOE Patents [OSTI]

    Grossman, Mark W. (Belmont, MA); George, William A. (Gloucestor, MA)

    1989-01-01T23:59:59.000Z

    A filter for enriching the .sup.196 Hg content of mercury, including a reactor, a low pressure electric discharge lamp containing a fill of mercury and an inert gas. A filter is arranged concentrically around the lamp. The reactor is arranged around said filter, whereby radiation from said lamp passes through the filter and into said reactor. The lamp, the filter and the reactor are formed of quartz, and are transparent to ultraviolet light. The .sup.196 Hg concentration in the mercury fill is less than that which is present in naturally occurring mercury, that is less than about 0.146 atomic weight percent. Hydrogen is also included in the fill and serves as a quenching gas in the filter, the hydrogen also serving to prevent disposition of a dark coating on the interior of the filter.

  12. Degradation of Isotopic Lactate and Acetate

    E-Print Network [OSTI]

    Aronoff, S.

    2010-01-01T23:59:59.000Z

    prescribed, BaC03 from the degradation of Ba acetnte co~~above procedure by the degradation of sjnthetic radio-lacticNo. W-7405-Eng o -48 DEGRADATION OF ISOTOPIC LACTATE AND

  13. The Isotopic Abundances of Magnesium in Stars

    E-Print Network [OSTI]

    Pamela Gay; David L. Lambert

    1999-11-11T23:59:59.000Z

    Isotopic abundance ratios 24^Mg:25^Mg:26^Mg are derived for 20 stars from high- resolution spectra of the MgH A-X 0-0 band at 5140AA. With the exception of the weak g-band giant HR 1299, the stars are dwarfs that sample the metallicity range -1.8 < [Fe/H] <0.0. The abundance of 25^Mg amd 26^Mg relative to the dominant isotope 24^Mg decreases with decreasing [Fe/H] in fair accord with predictions from a recent model of galactic chemical evolution in which the Mg isotopes are synthesised by massive stars. Several stars appear especially enriched in the heavier Mg isotopes suggesting contamination by material from the envelopes of intermediate-mass AGB stars.

  14. A SUPERCONDUCTING-SOLENOID ISOTOPE SPECTROMETER

    E-Print Network [OSTI]

    O'Donnell, Tom

    A SUPERCONDUCTING-SOLENOID ISOTOPE SPECTROMETER FOR PRODUCTION OF NEUTRON-RICH NUCLEI ( 136 Xe Superconducting Cyclotron Laboratory's weekly \\Green Sheet," 30 July 1999 #12; c Thomas W. O'Donnell 2000 All

  15. Carbon isotope fractionation in autotrophic Chromatium

    E-Print Network [OSTI]

    Wong, William Wai-Lun

    1974-01-01T23:59:59.000Z

    CARSON ISOTOPE FRACTIONATION IN AUTOTPOPHIC CHROYATIUN A Thesis 'JILLIAJJ J JAI LJJN BONG Submitted to the Graduate College of Texas A&H University in partial fulfillment of the requirenent for the degree of PLASTER OF SCIENCE August 1974...) August 1974 ABSTRACT Carbon Isotope Fractionation in Autotrophic Chromatium (August 1974) blilliam Wai-Lun Wang, B. S. , Texas Lutheran College Co-Chairmen of Advisory Committee: Dr. Isilliam N. Sackett Dr. Chauncey P. . Benedict Bacterial cells...

  16. Mass Parameterizations and Predictions of Isotopic Observables

    E-Print Network [OSTI]

    S. R. Souza; P. Danielewicz; S. Das Gupta; R. Donangelo; W. A. Friedman; W. G. Lynch; W. P. Tan; M. B. Tsang

    2003-03-24T23:59:59.000Z

    We discuss the accuracy of mass models for extrapolating to very asymmetric nuclei and the impact of such extrapolations on the predictions of isotopic observables in multifragmentation. We obtain improved mass predictions by incorporating measured masses and extrapolating to unmeasured masses with a mass formula that includes surface symmetry and Coulomb terms. We find that using accurate masses has a significant impact on the predicted isotopic observables.

  17. ISO/GUM UNCERTAINTIES AND CIAAW (UNCERTAINTY TREATMENT FOR RECOMMENDED ATOMIC WEIGHTS AND ISOTOPIC ABUNDANCES)

    SciTech Connect (OSTI)

    HOLDEN,N.E.

    2007-07-23T23:59:59.000Z

    The International Organization for Standardization (ISO) has published a Guide to the expression of Uncertainty in Measurement (GUM). The IUPAC Commission on Isotopic Abundance and Atomic Weight (CIAAW) began attaching uncertainty limits to their recommended values about forty years ago. CIAAW's method for determining and assigning uncertainties has evolved over time. We trace this evolution to their present method and their effort to incorporate the basic ISO/GUM procedures into evaluations of these uncertainties. We discuss some dilemma the CIAAW faces in their present method and whether it is consistent with the application of the ISO/GUM rules. We discuss the attempt to incorporate variations in measured isotope ratios, due to natural fractionation, into the ISO/GUM system. We make some observations about the inconsistent treatment in the incorporation of natural variations into recommended data and uncertainties. A recommendation for expressing atomic weight values using a tabulated range of values for various chemical elements is discussed.

  18. Using stable lead isotopes to trace heavy metal contamination sources in sediments of Xiangjiang and Lishui Rivers in China

    E-Print Network [OSTI]

    Hu, Qinhong "Max"

    Using stable lead isotopes to trace heavy metal contamination sources in sediments of Xiangjiang higher than natural values, suggesting the contaminations of heavy metals from extensive ore such as Hunan province is rich in mineral resources including non-ferrous metals (Zaw et al., 2007). Many kinds

  19. Thorium isotopes as tracers of particles dynamics and deep water circulation in the Indian sector of the

    E-Print Network [OSTI]

    Coppola, Laurent

    decay of the natural Uranium­Thorium radioactive decay series (U­Th). Isotopes of soluble U (238 U.elsevier.com/locate/marchem #12;230 Th, respectively). In seawater, 234 Th and 230 Th are removed from the water column

  20. Ion desolvation as a mechanism for kinetic isotope fractionation in aqueous systems

    E-Print Network [OSTI]

    Hofmann, A.E.

    2014-01-01T23:59:59.000Z

    equilibrium light?isotope  enrichment is a key unknown in of light?isotope  enrichment  during  precipitation.  possible light? isotope enrichment from diffusion?limited 

  1. NATIONAL USES AND NEEDS FOR SEPARATED STABLE ISOTOPES IN PHYSICS, CHEMISTRY, AND GEOSCIENCE RESEARCH

    E-Print Network [OSTI]

    Zisman, M.S.

    2010-01-01T23:59:59.000Z

    of purchasing a low-enrichment isotope and having it furtherfour main areas: of isotopes, marginal enrichment and a highthe allowing isotope much interest enrichment into play, in

  2. Oxygen isotope fractionation in the vacuum ultraviolet photodissociation of carbon monoxide: Wavelength, pressure and temperature dependency.

    E-Print Network [OSTI]

    Chakraborty, Subrata

    2013-01-01T23:59:59.000Z

    Oxygen isotope fractionation in the vacuum ultravioletmeasurement of the associated oxygen isotopic composition ofwavelength dependency of the oxygen isotopic composition in

  3. Natural Predator

    E-Print Network [OSTI]

    Wythe, Kathy

    2006-01-01T23:59:59.000Z

    tx H2O | pg. 10 Natural Predator Story by Kathy Wythe Natural Predator Foreign beetle shows promise for controlling saltcedar In the northern part of the Texas Panhandle andalong the West Texas banks of the Colorado andPecos rivers, Texas... scientists are successfully intro- ducing a foreign beetle to help control an invasive and exotic water-thirsty plant. Saltcedar, or Tamarix, was introduced to the western United States in the 1800s from central Asia as an ornamental tree and planted...

  4. Determination of the theoretical feasibility for the transmutation of europium isotopes from high flux isotope reactor control cylinders

    SciTech Connect (OSTI)

    Elam, K.R.; Reich, W.J.

    1995-09-01T23:59:59.000Z

    The High Flux Isotope Reactor (HFIR) at the Oak Ridge National Laboratory (ORNL) is a 100 MWth light-water research reactor designed and built in the 1960s primarily for the production of transuranic isotopes. The HFIR is equipped with two concentric cylindrical blade assemblies, known as control cylinders, that are used to control reactor power. These control cylinders, which become highly radioactive from neutron exposure, are periodically replaced as part of the normal operation of the reactor. The highly radioactive region of the control cylinders is composed of europium oxide in an aluminum matrix. The spent HFIR control cylinders have historically been emplaced in the ORNL Waste Area Grouping (WAG) 6. The control cylinders pose a potential radiological hazard due to the long lived radiotoxic europium isotopes {sup 152}Eu, {sup 154}Eu, and {sup 155}Eu. In a 1991 health evaluation of WAG 6 (ERD 1991) it was shown that these cylinders were a major component of the total radioactivity in WAG 6 and posed a potential exposure hazard to the public in some of the postulated assessment scenarios. These health evaluations, though preliminary and conservative in nature, illustrate the incentive to investigate methods for permanent destruction of the europium radionuclides. When the cost of removing the control cylinders from WAG 6, performing chemical separations and irradiating the material in HFIR are factored in, the option of leaving the control cylinders in place for decay must be considered. Other options, such as construction of an engineered barrier around the disposal silos to reduce the chance of migration, should also be analyzed.

  5. CORROSION—A NATURAL BUT CONTROLLABLE PROCESS

    E-Print Network [OSTI]

    Gretchen A. Jacobson

    Corrosion is a naturally occurring phenomenon commonly defined as the deterioration of a substance (usually a metal) or its properties because of a reaction with its environment. [1] Like other natural hazards such as earthquakes or severe weather disturbances, corrosion can cause dangerous

  6. Isotopic generator for bismuth-212 and lead-212 from radium

    DOE Patents [OSTI]

    Atcher, Robert W. (Kensington, MD); Friedman, Arnold M. (Park Forest, IL); Hines, John (Glen Ellyn, IL)

    1987-01-01T23:59:59.000Z

    A method and apparatus for providing radionuclides of bismuth-212 and lead-212. Thorium-228 and carrier solution starting material is input to a radiologically contained portion of an isotopic generator system, and radium-224 is separated from thorium-228 which is retained by a strongly basic anion exchange column. The separated radium-224 is transferred to an accessible, strongly acidic cationic exchange column. The cationic column retains the radium-224, and natural radioactive decay generates bismuth-212 and lead-212. The cationic exchange column can also be separated from the contained portion of the system and utilized without the extraordinary safety measures necessary in the contained portion. Furthermore, the cationic exchange column provides over a relatively long time period the short lived lead-212 and bismuth-212 radionuclides which are useful for a variety of medical therapies.

  7. Resolving the stellar sources of isotopically rare presolar silicate grains through Mg and Fe isotopic analyses

    SciTech Connect (OSTI)

    Nguyen, Ann N.; Messenger, Scott, E-mail: lan-anh.n.nguyen@nasa.gov [Robert M. Walker Laboratory for Space Science, Astromaterials Research and Exploration Science Directorate, NASA Johnson Space Center, Houston, TX 77058 (United States)

    2014-04-01T23:59:59.000Z

    We conducted multi-element isotopic analyses of 11 presolar silicate grains from the Acfer 094 meteorite having unusual O isotopic compositions. Eight grains are {sup 18}O-rich, one is {sup 16}O-rich, and two are extremely {sup 17}O-rich. We constrained the grains' stellar sources by measuring their Si and Mg isotopic ratios, and also the {sup 54}Fe/{sup 56}Fe and {sup 57}Fe/{sup 56}Fe ratios for five grains. The Mg and Fe isotopic measurements were conducted after surrounding matrix grains were removed for more accurate ratios. Most of the {sup 18}O-rich silicates had anomalous Mg isotopic ratios, and their combined isotopic constraints are consistent with origins in low-mass Type II supernovae (SNe II) rather than high-metallicity stars. The isotopic ratios of the {sup 16}O-rich silicate are also consistent with an SN origin. Mixing small amounts of interior stellar material with the stellar envelope replicated all measured isotopic ratios except for {sup 29}Si/{sup 28}Si and {sup 54}Fe/{sup 56}Fe in some grains. The {sup 29}Si/{sup 28}Si ratios of all SN-derived grains are matched by doubling the {sup 29}Si yield in the Ne- and Si-burning zones. The {sup 54}Fe/{sup 56}Fe ratios of the grains imply elemental fractionation in the Si/S zone, or introduction of isotopically solar Fe by secondary processing. The two highly {sup 17}O-rich silicates exhibited significant {sup 25}Mg and/or {sup 26}Mg enrichments and their isotopic ratios are best explained by strong dilution of 1.15 M {sub ?} CO nova matter. We estimate that ?12% and 1% of presolar silicates have SN and nova origins, respectively, similar to presolar SiC and oxides. This implies that asymptotic giant branch stars are the dominant dust producers in the galaxy.

  8. Natural Gas Regulatory Policy: Current Issues

    E-Print Network [OSTI]

    Watkins, G.

    NATURAL GAS REGULATORY roLICY: CURRENT ISSUES G. GAIL WATKINS Railroad Commission of Texas Austin, Texas ABSTRACT Many changes have occurred in recent months in both federal and state natural gas regulation. Those changes have increased... the options of industrial energy consumers for purchasing and moving natural gas. This panel viII discuss important developments in federal and state regulatory arenas and their impacts on purchasing options. Among the issues discussed viII be: 1...

  9. Natural Product Biosynthesis: Friend or Foe? From Anti-tumor Agent to Disease Causation

    E-Print Network [OSTI]

    Foulke-Abel, Jennifer

    2012-02-14T23:59:59.000Z

    compounds to a fermentation culture, isolating the natural product, and examining isotopic signal attenuation by NMR. Corre and Lowden first used isotopically-labeled precursor compound feeding to monitor biosynthetic incorporation at specific atom... an optimal fermentation system capable of consistent azinomycin B production. Final conditions implemented dehydrated agar plates, a two stage starter culture, and a minimal fermentation media to achieve steady production.31 This optimized method allowed...

  10. Design, construction, and operation of a laboratory scale reactor for the production of high-purity, isotopically enriched bulk silicon

    E-Print Network [OSTI]

    Ager III, J.W.; Beeman, J.W.; Hansen, W.L.; Haller, E.E.

    2004-01-01T23:59:59.000Z

    Russia. The stated isotope enrichments are summarized inenrichments >99% have been achieved for each isotope and

  11. Atomic line emission analyzer for hydrogen isotopes

    DOE Patents [OSTI]

    Kronberg, J.W.

    1991-05-08T23:59:59.000Z

    Apparatus for isotopic analysis of hydrogen comprises a low pressure chamber into which a sample of hydrogen is introduced and then exposed to an electrical discharge to excite the electrons of the hydrogen atoms to higher energy states and thereby cause the emission of light on the return to lower energy states, a Fresnel prism made at least in part of a material anomalously dispersive to the wavelengths of interest for dispersing the emitted light, and a photodiode array for receiving the dispersed light. The light emitted by the sample is filtered to pass only the desired wavelengths, such as one of the lines of the Balmer series for hydrogen, the wavelengths of which differ slightly from one isotope to another. The output of the photodiode array is processed to determine the relative amounts of each isotope present in the sample. Additionally, the sample itself may be recovered using, a metal hydride.

  12. Atomic line emission analyzer for hydrogen isotopes

    DOE Patents [OSTI]

    Kronberg, James W. (108 Independent Blvd., Aiken, SC 29801)

    1993-01-01T23:59:59.000Z

    Apparatus for isotopic analysis of hydrogen comprises a low pressure chamber into which a sample of hydrogen is introduced and then exposed to an electrical discharge to excite the electrons of the hydrogen atoms to higher energy states and thereby cause the emission of light on the return to lower energy states, a Fresnel prism made at least in part of a material anomalously dispersive to the wavelengths of interest for dispersing the emitted light, and a photodiode array for receiving the dispersed light. The light emitted by the sample is filtered to pass only the desired wavelengths, such as one of the lines of the Balmer series for hydrogen, the wavelengths of which differ slightly from one isotope to another. The output of the photodiode array is processed to determine the relative amounts of each isotope present in the sample. Additionally, the sample itself may be recovered using a metal hydride.

  13. Apparatus for separating and recovering hydrogen isotopes

    DOE Patents [OSTI]

    Heung, Leung K. (Aiken, SC)

    1994-01-01T23:59:59.000Z

    An apparatus for recovering hydrogen and separating its isotopes. The apparatus includes a housing bearing at least a fluid inlet and a fluid outlet. A baffle is disposed within the housing, attached thereto by a bracket. A hollow conduit is coiled about the baffle, in spaced relation to the baffle and the housing. The coiled conduit is at least partially filled with a hydride. The hydride can be heated to a high temperature and cooled to a low temperature quickly by circulating a heat transfer fluid in the housing. The spacing between the baffle and the housing maximizes the heat exchange rate between the fluid in the housing and the hydride in the conduit. The apparatus can be used to recover hydrogen isotopes (protium, deuterium and tritium) from gaseous mixtures, or to separate hydrogen isotopes from each other.

  14. Atomic line emission analyzer for hydrogen isotopes

    DOE Patents [OSTI]

    Kronberg, J.W.

    1993-03-30T23:59:59.000Z

    Apparatus for isotopic analysis of hydrogen comprises a low pressure chamber into which a sample of hydrogen is introduced and then exposed to an electrical discharge to excite the electrons of the hydrogen atoms to higher energy states and thereby cause the emission of light on the return to lower energy states, a Fresnel prism made at least in part of a material anomalously dispersive to the wavelengths of interest for dispersing the emitted light, and a photodiode array for receiving the dispersed light. The light emitted by the sample is filtered to pass only the desired wavelengths, such as one of the lines of the Balmer series for hydrogen, the wavelengths of which differ slightly from one isotope to another. The output of the photodiode array is processed to determine the relative amounts of each isotope present in the sample. Additionally, the sample itself may be recovered using a metal hydride.

  15. Isotope effects in methanol synthesis and the reactivity of copper...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Isotope effects in methanol synthesis and the reactivity of copper formates on a CuSiO2 catalyst. Isotope effects in methanol synthesis and the reactivity of copper formates on a...

  16. Hydrogen isotope fractionation during lipid biosynthesis by Haloarcula marismortui

    E-Print Network [OSTI]

    Hydrogen isotope fractionation during lipid biosynthesis by Haloarcula marismortui Sitindra S studied the controls on the fractionation of hydrogen isotopes during lipid biosynthesis by Haloarcula marismortui, a halophilic archaea, in pure culture experiments by varying organic substrate, the hydrogen

  17. Oxygen isotope records of carboniferous seasonality on the Russian platform

    E-Print Network [OSTI]

    Wang, Huayu

    1998-01-01T23:59:59.000Z

    Seven isotopic and eight trace element (TE) profiles across shell growth lines are presented, based on over 1000 stable isotope and electron microprobe analyses on six brachiopod shells (Gigantoproductus), to quantify seasonal temperature change...

  18. Physiology of multiple sulfur isotope fractionation during microbial sulfate reduction

    E-Print Network [OSTI]

    Sim, Min Sub

    2012-01-01T23:59:59.000Z

    Microbial sulfate reduction (MSR) utilizes sulfate as an electron acceptor and produces sulfide that is depleted in heavy isotopes of sulfur relative to starting sulfate. The fractionation of S-isotopes is commonly used ...

  19. Delayed neutron measurements from fast fission of actinide waste isotopes

    E-Print Network [OSTI]

    Charlton, William S.

    1997-01-01T23:59:59.000Z

    A study was performed to determine the delayed neutron emission properties from fast fission of several actinide waste isotopes. The specific isotopes evaluated were U-235, Np-237, and Am-243. A calculational technique based on the microscopic...

  20. High Flux Isotope Reactor named Nuclear Historic Landmark | ornl...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    High Flux Isotope Reactor named Nuclear Historic Landmark The High Flux Isotope Reactor vessel at Oak Ridge National Laboratory resides in a pool of water illuminated by the blue...

  1. Isotopic Analysis- Rock At Valles Caldera - Sulphur Springs Geothermal...

    Open Energy Info (EERE)

    navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Isotopic Analysis- Rock At Valles Caldera - Sulphur Springs Geothermal Area (Phillips, 2004)...

  2. Isotopic Analysis At Lassen Volcanic National Park Area (Janik...

    Open Energy Info (EERE)

    navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Isotopic Analysis At Lassen Volcanic National Park Area (Janik & Mclaren, 2010) Exploration Activity...

  3. Isotopic Analysis- Rock At Valles Caldera - Sulphur Springs Geothermal...

    Open Energy Info (EERE)

    navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Isotopic Analysis- Rock At Valles Caldera - Sulphur Springs Geothermal Area (Ito & Tanaka, 1995)...

  4. Isotopic Analysis- Rock At Valles Caldera - Sulphur Springs Area...

    Open Energy Info (EERE)

    navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Isotopic Analysis- Rock At Valles Caldera - Sulphur Springs Area (Ito & Tanaka, 1995) Exploration...

  5. Isotopic Analysis At Valles Caldera - Redondo Geothermal Area...

    Open Energy Info (EERE)

    navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Isotopic Analysis At Valles Caldera - Redondo Geothermal Area (Phillips, 2004) Exploration Activity...

  6. Stable carbon and nitrogen isotope enrichment in primate tissues

    E-Print Network [OSTI]

    Crowley, Brooke E.; Carter, Melinda L.; Karpanty, Sarah M.; Zihlman, Adrienne L.; Koch, Paul L.; Dominy, Nathaniel J.

    2010-01-01T23:59:59.000Z

    of sample treatment and diagenesis on the isotopic integrityHare PE (1986) Effects of diagenesis on strontium, carbon,

  7. Isotopic abundance in atom trap trace analysis

    DOE Patents [OSTI]

    Lu, Zheng-Tian; Hu, Shiu-Ming; Jiang, Wei; Mueller, Peter

    2014-03-18T23:59:59.000Z

    A method and system for detecting ratios and amounts of isotopes of noble gases. The method and system is constructed to be able to measure noble gas isotopes in water and ice, which helps reveal the geological age of the samples and understand their movements. The method and system uses a combination of a cooled discharge source, a beam collimator, a beam slower and magneto-optic trap with a laser to apply resonance frequency energy to the noble gas to be quenched and detected.

  8. Isotope Research Materials Laboratory | ornl.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cnHigh SchoolIn12 Investigation Peer ReviewIron isIsIsotope ProgramIsotope

  9. Isotope effect evidence for the zinc hydroxide mechanism of carbonic anhydrase catalyst

    SciTech Connect (OSTI)

    Paneth, P.; O'Leary, M.H.

    1987-03-24T23:59:59.000Z

    The carbon kinetic isotope effect on the enzymatic dehydration of HCO/sub 3//sup -/ ion is k/sup 12//k/sup 13/ = 1.011 and is independent, within experimental error, of the addition of sucrose, substitution of D/sub 2/O for H/sub 2/O, and substitution of enzyme-bound Zn/sup 2 +/ by Co/sup 2 +/. These results are consistent with a ping-pong mechanism in which proton transfer between enzyme and solvent is separated from HCO/sub 3//sup -/ dehydration. For the dehydration half-reaction, diffusional processes are severalfold faster than dehydration, and the rate-determining step is the dehydration itself. The intrinsic isotope effect is approximately 1.011, indicating that hydration of CO/sub 2/ occurs by reaction of zinc-bound OH/sup -/, rather than zinc-bound H/sub 2/O.

  10. Isotope effect evidence for the zinc hydroxide mechanism of carbonic anhydrase catalysis

    SciTech Connect (OSTI)

    Paneth, P.; O'Leary, M.H.

    1987-03-24T23:59:59.000Z

    The carbon kinetic isotope effect on the enzymatic dehydration of HCO/sub 3/- ion is k12/k13 = 1.011 and is independent, within experimental error, of the addition of sucrose, substitution of D/sub 2/O for H/sub 2/O, and substitution of enzyme-bound Zn/sup 2 +/ by Co/sup 2 +/. These results are consistent with a ping-pong mechanism in which proton transfer between enzyme and solvent is separated from HCO/sub 3/- dehydration. For the dehydration half-reaction, diffusional processes are severalfold faster than dehydration, and the rate-determining step is the dehydration itself. The intrinsic isotope effect is approximately 1.011, indicating that hydration of CO/sub 2/ occurs by reaction of zinc-bound OH-, rather than zinc-bound H/sub 2/O.

  11. Hydrogen isotope fractionation during lipid biosynthesis by Tetrahymena thermophila

    E-Print Network [OSTI]

    Hydrogen isotope fractionation during lipid biosynthesis by Tetrahymena thermophila Sitindra S Accepted 7 September 2013 Available online 16 September 2013 a b s t r a c t Hydrogen isotope ratio values from recording the hydrogen isotope composition of ambient water, dD values of lipids also depend

  12. ORIGINAL RESEARCH Hydrogen and carbon isotope fractionation during

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    , enrichment in 13 C of untransformed CH3Cl was also observed, and similar isotope enrichment factors (e) of ÀORIGINAL RESEARCH Hydrogen and carbon isotope fractionation during degradation of chloromethane-Meitner-Weg 1, 55128 Mainz, Germany Keywords Carbon isotope fractionation, chloromethane biodegradation

  13. Research Article Peculiarities in the stable isotope composition of organisms

    E-Print Network [OSTI]

    Rasmussen, Joseph

    that dietary N content can affect trophic level 15 N enrichment. The anomalies in stable isotope concen; dietary N; 15 N enrichment. Introduction Over the last decade, stable isotopes have been used inResearch Article Peculiarities in the stable isotope composition of organisms from an alpine lake

  14. Discovery of the actinium, thorium, protactinium, and uranium isotopes

    E-Print Network [OSTI]

    C. Fry; M. Thoennessen

    2012-03-06T23:59:59.000Z

    Currently, 31 actinium, 31 thorium, 28 protactinium, and 23 uranium isotopes have so far been observed; the discovery of these isotopes is discussed. For each isotope a brief summary of the first refereed publication, including the production and identification method, is presented.

  15. Discovery of dysprosium, holmium, erbium, thulium, and ytterbium isotopes

    SciTech Connect (OSTI)

    Fry, C.; Thoennessen, M., E-mail: thoennessen@nscl.msu.edu

    2013-09-15T23:59:59.000Z

    Currently, thirty-one dysprosium, thirty-two holmium, thirty-two erbium, thirty-three thulium, and thirty-one ytterbium isotopes have been observed and the discovery of these isotopes is described here. For each isotope a brief synopsis of the first refereed publication, including the production and identification method, is presented.

  16. Discovery of palladium, antimony, tellurium, iodine, and xenon isotopes

    SciTech Connect (OSTI)

    Kathawa, J.; Fry, C.; Thoennessen, M., E-mail: thoennessen@nscl.msu.edu

    2013-01-15T23:59:59.000Z

    Currently, thirty-eight palladium, thirty-eight antimony, thirty-nine tellurium, thirty-eight iodine, and forty xenon isotopes have been observed and the discovery of these isotopes is described here. For each isotope a brief synopsis of the first refereed publication, including the production and identification method, is presented.

  17. Discovery of the astatine, radon, francium, and radium isotopes

    SciTech Connect (OSTI)

    Fry, C.; Thoennessen, M., E-mail: thoennessen@nscl.msu.edu

    2013-09-15T23:59:59.000Z

    Thirty-nine astatine, thirty-nine radon, thirty-five francium, and thirty-four radium isotopes have so far been observed; the discovery of these isotopes is described. For each isotope a brief summary of the first refereed publication, including the production and identification method, is presented.

  18. Discovery of samarium, europium, gadolinium, and terbium isotopes

    SciTech Connect (OSTI)

    May, E.; Thoennessen, M., E-mail: thoennessen@nscl.msu.edu

    2013-01-15T23:59:59.000Z

    Currently, thirty-four samarium, thirty-four europium, thirty-one gadolinium, and thirty-one terbium isotopes have been observed and the discovery of these isotopes is described here. For each isotope a brief synopsis of the first refereed publication, including the production and identification method, is presented.

  19. Discovery of Yttrium, Zirconium, Niobium, Technetium, and Ruthenium Isotopes

    E-Print Network [OSTI]

    A. Nystrom; M. Thoennessen

    2011-02-11T23:59:59.000Z

    Currently, thirty-four yttrium, thirty-five zirconium, thirty-four niobium, thirty-five technetium, and thirty-eight ruthenium isotopes have been observed and the discovery of these isotopes is discussed here. For each isotope a brief synopsis of the first refereed publication, including the production and identification method, is presented.

  20. Discovery of Yttrium, Zirconium, Niobium, Technetium, and Ruthenium Isotopes

    E-Print Network [OSTI]

    Nystrom, A

    2011-01-01T23:59:59.000Z

    Currently, thirty-four yttrium, thirty-five zirconium, thirty-four niobium, thirty-five technetium, and thirty-eight ruthenium isotopes have been observed and the discovery of these isotopes is discussed here. For each isotope a brief synopsis of the first refereed publication, including the production and identification method, is presented.

  1. Discovery of Scandium, Titanium, Mercury, and Einsteinium Isotopes

    E-Print Network [OSTI]

    D. Meierfrankenfeld; A. Bury; M. Thoennessen

    2010-09-08T23:59:59.000Z

    Currently, twenty-three scandium, twenty-five titanium, forty mercury and seventeen einsteinium isotopes have been observed and the discovery of these isotopes is discussed here. For each isotope a brief synopsis of the first refereed publication, including the production and identification method, is presented.

  2. Discovery of Samarium, Europium, Gadolinium, and Terbium Isotopes

    E-Print Network [OSTI]

    E. May; M. Thoennessen

    2012-01-19T23:59:59.000Z

    Currently, thirty-four samarium, thirty-four europium, thirty-one gadolinium, and thirty-one terbium isotopes have been observed and the discovery of these isotopes is discussed here. For each isotope a brief synopsis of the first refereed publication, including the production and identification method, is presented.

  3. Discovery of Samarium, Europium, Gadolinium, and Terbium Isotopes

    E-Print Network [OSTI]

    May, E

    2012-01-01T23:59:59.000Z

    Currently, thirty-four samarium, thirty-four europium, thirty-one gadolinium, and thirty-one terbium isotopes have been observed and the discovery of these isotopes is discussed here. For each isotope a brief synopsis of the first refereed publication, including the production and identification method, is presented.

  4. Natural gas monthly, February 1998

    SciTech Connect (OSTI)

    NONE

    1998-02-01T23:59:59.000Z

    This issue of the Natural Gas Monthly (NGM) presents the most recent estimates of natural gas data from the Energy Information Administration. Estimates extend through February 1998 for many data series, and through November 1997 for most natural gas prices. Highlights of the natural gas data contained in this issue are: Preliminary estimates for January and February 1998 show that dry natural gas production, net imports, and consumption are all within 1 percent of their levels in 1997. Warmer-than-normal weather in recent months has resulted in lower consumption of natural gas by the residential sector and lower net withdrawals of gas from under round storage facilities compared with a year ago. This has resulted in an estimate of the amount of working gas in storage at the end of February 1998 that is 18 percent higher than in February 1997. The national average natural gas wellhead price is estimated to be $3.05 per thousand cubic feet in November 1997, 7 percent higher than in October. The cumulative average wellhead price for January through November 1997 is estimated to be $2.42 per thousand cubic feet, 17 percent above that of the same period in 1996. This price increase is far less than 36-percent rise that occurred between 1995 and 1996. 6 figs., 26 tabs.

  5. Isotope effect in the photochemical decomposition of CO{sub 2} (ice) by Lyman-{alpha} radiation

    SciTech Connect (OSTI)

    Yuan Chunqing; Yates, John T. Jr. [Department of Chemistry, University of Virginia, Charlottesville, Virginia 22904 (United States)

    2013-04-21T23:59:59.000Z

    The photochemical decomposition of CO{sub 2}(ice) at 75 K by Lyman-{alpha} radiation (10.2 eV) has been studied using transmission infrared spectroscopy. An isotope effect in the decomposition of the CO{sub 2} molecule in the ice has been discovered, favoring {sup 12}CO{sub 2} photodecomposition over {sup 13}CO{sub 2} by about 10%. The effect is caused by electronic energy transfer from the excited CO{sub 2} molecule to the ice matrix, which favors quenching of the heavier electronically-excited {sup 13}CO{sub 2} molecule over {sup 12}CO{sub 2}. The effect is similar to the Menzel-Gomer-Redhead isotope effect in desorption from adsorbed molecules on surfaces when electronically excited. An enhancement of the rate of formation of lattice-trapped CO and CO{sub 3} species is observed for the photolysis of the {sup 12}CO{sub 2} molecule compared to the {sup 13}CO{sub 2} molecule in the ice. Only 0.5% of the primary photoexcitation results in O-CO bond dissociation to produce trapped-CO and trapped-CO{sub 3} product molecules and the majority of the electronically-excited CO{sub 2} molecules return to the ground state. Here either vibrational relaxation occurs (majority process) or desorption of CO{sub 2} occurs (minority process) from highly vibrationally-excited CO{sub 2} molecules in the ice. The observation of the {sup 12}C/{sup 13}C isotope effect in the Lyman-{alpha} induced photodecomposition of CO{sub 2} (ice) suggests that over astronomical time scales the isotope enrichment effect may distort historical information derived from isotope ratios in space wherever photochemistry can occur.

  6. Laser Isotope Enrichment for Medical and Industrial Applications

    SciTech Connect (OSTI)

    Leonard Bond

    2006-07-01T23:59:59.000Z

    Laser Isotope Enrichment for Medical and Industrial Applications by Jeff Eerkens (University of Missouri), Jay Kunze (Idaho State University), and Leonard Bond (Idaho National Laboratory) The principal isotope enrichment business in the world is the enrichment of uranium for commercial power reactor fuels. However, there are a number of other needs for separated isotopes. Some examples are: 1) Pure isotopic targets for irradiation to produce medical radioisotopes. 2) Pure isotopes for semiconductors. 3) Low neutron capture isotopes for various uses in nuclear reactors. 4) Isotopes for industrial tracer/identification applications. Examples of interest to medicine are targets to produce radio-isotopes such as S-33, Mo-98, Mo-100, W-186, Sn-112; while for MRI diagnostics, the non-radioactive Xe-129 isotope is wanted. For super-semiconductor applications some desired industrial isotopes are Si-28, Ga-69, Ge-74, Se-80, Te-128, etc. An example of a low cross section isotope for use in reactors is Zn-68 as a corrosion inhibitor material in nuclear reactor primary systems. Neutron activation of Ar isotopes is of interest in industrial tracer and diagnostic applications (e.g. oil-logging). . In the past few years there has been a sufficient supply of isotopes in common demand, because of huge Russian stockpiles produced with old electromagnetic and centrifuge separators previously used for uranium enrichment. Production of specialized isotopes in the USA has been largely accomplished using old ”calutrons” (electromagnetic separators) at Oak Ridge National Laboratory. These methods of separating isotopes are rather energy inefficient. Use of lasers for isotope separation has been considered for many decades. None of the proposed methods have attained sufficient proof of principal status to be economically attractive to pursue commercially. Some of the authors have succeeded in separating sulfur isotopes using a rather new and different method, known as condensation repression. In this scheme a gas, of the selected isotopes for enrichment, is irradiated with a laser at a particular wavelength that would excite only one of the isotopes. The entire gas is subject to low temperatures sufficient to cause condensation on a cold surface. Those molecules in the gas that the laser excited are not as likely to condense as are the unexcited molecules. Hence the gas drawn out of the system will be enriched in the isotope that was excited by the laser. We have evaluated the relative energy required in this process if applied on a commercial scale. We estimate the energy required for laser isotope enrichment is about 20% of that required in centrifuge separations, and 2% of that required by use of "calutrons".

  7. A review of stable water isotopeA review of stable water isotope modellingmodelling

    E-Print Network [OSTI]

    Sturm, Christophe "Kristof"

    fractionation · Kinetic fractionation 2. Modelling the stable water isotope cycle · Rayleigh distillation model Institution of Oceanography) Harald SODEMANN (Norwegian Institute for Air Research) Kristof 18Ovapour=-40 18Oocean=0 18Osnow=-3018Orain=-2 Equilibrium fractionationEquilibrium fractionation

  8. O Isotopic Composition of CaCO3 Measured by Continuous Flow Isotope Ratio Mass Spectrometry: Statistical Evaluation and

    E-Print Network [OSTI]

    d13 C and d18 O Isotopic Composition of CaCO3 Measured by Continuous Flow Isotope Ratio Mass method streamlines the classical phosphoric acid ­ calcium carbonate (H3 PO4 ­ CaCO3 ) reaction method XL continuous flow isotope ratio mass spectrometer. Conditions for which the H3 PO4 ­ CaCO3 reaction

  9. Review of hydrogen isotope permeability through materials

    SciTech Connect (OSTI)

    Steward, S.A.

    1983-08-15T23:59:59.000Z

    This report is the first part of a comprehensive summary of the literature on hydrogen isotope permeability through materials that do not readily form hydrides. While we mainly focus on pure metals with low permeabilities because of their importance to tritium containment, we also give data on higher-permeability materials such as iron, nickel, steels, and glasses.

  10. Trace Element and Isotopic Fluxes/ Subducted Slab

    E-Print Network [OSTI]

    Bebout, Gray E.

    3.20.7.2.1 Devolatilization 34 3.20.7.2.2 Boron and lithium isotopes 35 3.20.7.3 Carbon and Nitrogen forearcs. In addi- tion, subduction erosion from the forearc hanging walls can impact geochemical evolut

  11. 5, 547577, 2008 Isotope hydrology of

    E-Print Network [OSTI]

    Boyer, Edmond

    HESSD 5, 547­577, 2008 Isotope hydrology of cave dripwaters L. Fuller et al. Title Page Abstract.hydrol-earth-syst-sci-discuss.net/5/547/2008/ © Author(s) 2008. This work is licensed under a Creative Commons License. Hydrology and Earth System Sciences Discussions Papers published in Hydrology and Earth System Sciences Discussions

  12. Radioactive isotopes in Danish drinking water

    E-Print Network [OSTI]

    Radioactive isotopes in Danish drinking water Sven P. Nielsen Risø National Laboratory Working OF INVESTIGATION 11 3 DESCRIPTION OF INVESTIGATION 12 4 RADIOACTIVITY IN DRINKING WATER 13 5 SAMPLING 15 6 27 #12;4 #12;5 Preface This project for investigation of radioactivity in drinking water shall

  13. Atomic-vapor-laser isotope separation

    SciTech Connect (OSTI)

    Davis, J.I.

    1982-10-01T23:59:59.000Z

    This paper gives a brief history of the scientific considerations leading to the development of laser isotope separation (LIS) processes. The close relationship of LIS to the broader field of laser-induced chemical processes is evaluated in terms of physical criteria to achieve an efficient production process. Atomic-vapor LIS processes under development at Livermore are reviwed. 8 figures.

  14. Isotope-labeled immunoassays without radiation waste

    E-Print Network [OSTI]

    Hammock, Bruce D.

    of California, Davis, CA 95616; and Center for Accelerator Mass Spectrometry, Lawrence Livermore National, such as liquid scintillation counting (LSC) and autoradiography, use the radiation generated in the isotope in areas such as environmental monitoring and food analysis. Accelerator mass spectrometry (AMS) developed

  15. Use of plutonium isotope activity ratios in dating recent sediments. [/sup 238/Pu//sup 239/Pu + /sup 240/Pu

    SciTech Connect (OSTI)

    Beasley, T. M.

    1982-01-01T23:59:59.000Z

    The majority of plutonium presently in the biosphere has come from the testing of nuclear devices. In the early 1950s, the Pu-238/239+240 activity ratio of fallout debris was > 0.04; in the more extensive test series of 1961 to 1962, the Pu-238/239+240 activity ratios were quite consistent at 0.02 to 0.03 and maximum fallout delivery occurred in mid-1963. A significant perturbation in Pu isotope activity ratios occurred in mid-1966 with the deposition of Pu-238 from the SNAP-9A reentry and burn-up. Recently deposited sediments have recorded these events and where accumulation rates are rapid (> 1 cm/y), changes in Pu isotope activity ratios can be used as a geochronological tool.

  16. NATURAL GAS MARKET ASSESSMENT

    E-Print Network [OSTI]

    CALIFORNIA ENERGY COMMISSION NATURAL GAS MARKET ASSESSMENT PRELIMINARY RESULTS In Support.................................................................................... 6 Chapter 2: Natural Gas Demand.................................................................................................. 10 Chapter 3: Natural Gas Supply

  17. Stable carbon isotope ratio of polycyclic aromatic hydrocarbons (PAHs) in the environment: validation of isolation and stable carbon isotope analysis methods

    E-Print Network [OSTI]

    Kim, Moon Koo

    2004-11-15T23:59:59.000Z

    , purification and compound specific isotope analysis methods were developed to accurately measure the stable carbon isotope ratio of individual PAHs. Development of the method included improving accuracy and precision of the isotopic measurement by producing...

  18. Natural Dynamics for Combinatorial Optimization

    E-Print Network [OSTI]

    Ovchinnikov, Igor V

    2015-01-01T23:59:59.000Z

    Stochastic and or natural dynamical systems (DSs) are dominated by sudden nonlinear processes such as neuroavalanches, gamma-ray bursts, solar flares, earthquakes etc. that exhibit scale-free statistics. These behaviors also occur in many nanosystems. On phase diagrams, these DSs belong to a finite-width phase that separates the phases of thermodynamic equilibrium and ordinary chaotic dynamics, and that is known under such names as intermittency, noise-induced chaos, and self-organized criticality. Within the recently formulated approximation-free cohomological theory of stochastic differential equations, the noise-induced chaos can be roughly interpreted as a noise-induced overlap between regular (integrable) and chaotic (non-integrable) deterministic dynamics so that DSs in this phase inherit the properties of the both. Here, we analyze this unique set of properties and conclude that such DSs must be the most efficient natural optimizers. Based on this understanding, we propose the method of the natural dyn...

  19. Importance of the Equlibrium Node in Preventing the Voltage Collapse Occurs in the Wind Power System

    E-Print Network [OSTI]

    Lavaei, Javad

    Importance of the Equlibrium Node in Preventing the Voltage Collapse Occurs in the Wind Power collapse will occurs in a wind power system is discussed next. The method of power flow calculation is the specific analysis of a given simplified wind power system. Keywords--voltage collapse; Newton

  20. Diffusional exchange of isotopes in a metal hydride sphere.

    SciTech Connect (OSTI)

    Wolfer, Wilhelm G.; Hamilton, John C.; James, Scott Carlton

    2011-04-01T23:59:59.000Z

    This report describes the Spherical Particle Exchange Model (SPEM), which simulates exchange of one hydrogen isotope by another hydrogen isotope in a spherical metal hydride particle. This is one of the fundamental physical processes during isotope exchange in a bed of spherical metal particles and is thus one of the key components in any comprehensive physics-based model of exchange. There are two important physical processes in the model. One is the entropy of mixing between the two isotopes; the entropy of mixing is increased by having both isotopes randomly placed at interstitial sites on the lattice and thus impedes the exchange process. The other physical process is the elastic interaction between isotope atoms on the lattice. The elastic interaction is the cause for {beta}-phase formation and is independent of the isotope species. In this report the coupled diffusion equations for two isotopes in the {beta}-phase hydride are solved. A key concept is that the diffusion of one isotope depends not only on its concentration gradient, but also on the concentration gradient of the other isotope. Diffusion rate constants and the chemical potentials for deuterium and hydrogen in the {beta}-phase hydride are reviewed because these quantities are essential for an accurate model of the diffusion process. Finally, a summary of some of the predictions from the SPEM model are provided.

  1. Far Infrared Conductivity of Charge Density Wave Materials and the Oxygen Isotope Effect in High-T{sub c}

    E-Print Network [OSTI]

    Creager, W.N.

    2009-01-01T23:59:59.000Z

    determined. With 180 isotope enrichments of approximatelyand consistent 180 isotope enrichments of approximately 80%.enrichment, 0.90; the same group has reported oxygen isotope

  2. Optically pumped isotopic ammonia laser system

    DOE Patents [OSTI]

    Buchwald, Melvin I. (Santa Fe, NM); Jones, Claude R. (Los Alamos, NM); Nelson, Leonard Y. (Seattle, WA)

    1982-01-01T23:59:59.000Z

    An optically pumped isotopic ammonia laser system which is capable of producing a plurality of frequencies in the middle infrared spectral region. Two optical pumping mechanisms are disclosed, i.e., pumping on R(J) and lasing on P(J) in response to enhancement of rotational cascade lasing including stimulated Raman effects, and, pumping on R(J) and lasing on P(J+2). The disclosed apparatus for optical pumping include a hole coupled cavity and a grating coupled cavity.

  3. Concerning the Facility for Rare Isotope Beams

    ScienceCinema (OSTI)

    Symons, James

    2013-05-29T23:59:59.000Z

    James Symons, Nuclear Science Division Director at Lawrence Berkeley Lab, and Daniela Leitner, head of operations at Berkeley Lab's 88-Inch Cyclotron, discuss major contributions to the new Facility for Rare Isotope Beams (FRIB) at Michigan State University, including ion source, which will based on the VENUS source built for the 88-Inch Cyclotron, and the GRETA gamma-ray detector now under construction there.

  4. Hydrogen isotope separation utilizing bulk getters

    DOE Patents [OSTI]

    Knize, Randall J. (Los Angeles, CA); Cecchi, Joseph L. (Lawrenceville, NJ)

    1990-01-01T23:59:59.000Z

    Tritium and deuterium are separated from a gaseous mixture thereof, derived from a nuclear fusion reactor or some other source, by providing a casing with a bulk getter therein for absorbing the gaseous mixture to produce an initial loading of the getter, partially desorbing the getter to produce a desorbed mixture which is tritium-enriched, pumping the desorbed mixture into a separate container, the remaining gaseous loading in the getter being deuterium-enriched, desorbing the getter to a substantially greater extent to produce a deuterium-enriched gaseous mixture, and removing the deuterium-enriched mixture into another container. The bulk getter may comprise a zirconium-aluminum alloy, or a zirconium-vanadium-iron alloy. The partial desorption may reduce the loading by approximately fifty percent. The basic procedure may be extended to produce a multistage isotope separator, including at least one additional bulk getter into which the tritium-enriched mixture is absorbed. The second getter is then partially desorbed to produce a desorbed mixture which is further tritium-enriched. The last-mentioned mixture is then removed from the container for the second getter, which is then desorbed to a substantially greater extent to produce a desorbed mixture which is deuterium-enriched. The last-mentioned mixture is then removed so that the cycle can be continued and repeated. The method of isotope separation is also applicable to other hydrogen isotopes, in that the method can be employed for separating either deuterium or tritium from normal hydrogen.

  5. Hydrogen isotope separation utilizing bulk getters

    DOE Patents [OSTI]

    Knize, Randall J. (Los Angeles, CA); Cecchi, Joseph L. (Lawrenceville, NJ)

    1991-01-01T23:59:59.000Z

    Tritium and deuterium are separated from a gaseous mixture thereof, derived from a nuclear fusion reactor or some other source, by providing a casing with a bulk getter therein for absorbing the gaseous mixture to produce an initial loading of the getter, partially desorbing the getter to produce a desorbed mixture which is tritium-enriched, pumping the desorbed mixture into a separate container, the remaining gaseous loading in the getter being deuterium-enriched, desorbing the getter to a substantially greater extent to produce a deuterium-enriched gaseous mixture, and removing the deuterium-enriched mixture into another container. The bulk getter may comprise a zirconium-aluminum alloy, or a zirconium-vanadium-iron alloy. The partial desorption may reduce the loading by approximately fifty percent. The basic procedure may be extended to produce a multistage isotope separator, including at least one additional bulk getter into which the tritium-enriched mixture is absorbed. The second getter is then partially desorbed to produce a desorbed mixture which is further tritium-enriched. The last-mentioned mixture is then removed from the container for the second getter, which is then desorbed to a substantially greater extent to produce a desorbed mixture which is deuterium-enriched. The last-mentioned mixture is then removed so that the cycle can be continued and repeated. The method of isotope separation is also applicable to other hydrogen isotopes, in that the method can be employed for separating either deuterium or tritium from normal hydrogen.

  6. FILTR: Flash Isotope Library and Training Resource

    SciTech Connect (OSTI)

    Campbell, D; Trombino, D

    2007-07-26T23:59:59.000Z

    The subject of radiation detection is replete with complex concepts and challenging nomenclature. Furthermore, a daunting variety of radioactive isotopes may be encountered during the routine operation of a radiation detector. Individuals tasked with searching for illicit sources of radiation must remain vigilant while navigating through more frequently encountered mundane and legitimate radioactive sources. The Flash Isotope Library and Training Resource (FILTR) is being developed as an easily accessible and intuitive reference tool to manage the high volume of complex information required for this task. FILTR is an extended version of the Primary Utility for Nuclear Terminology (PUNT) software developed by the Counter Measures Test Beds group at Lawrence Livermore National Laboratory for the United States Secret Service. Authored in the Flash multimedia development environment, FILTR contains detailed information on potentially encountered isotopes as well as training on radiation and operational procedures. Reference material is organized to present critical information quickly while facilitating more in-depth investigation through an intuitive interface and engaging content. FILTR is being developed for a diverse audience of law enforcement organizations and government agencies and a wide range of skill sets from expert analysts to officers whose primary role is not radiation detection. Additionally, the wide compatibility of Flash content will allow FILTR to be readily accessible through the growing number of multi-media enabled electronic devices, including PDAs and cellular phones.

  7. Hydrogen isotope separation utilizing bulk getters

    DOE Patents [OSTI]

    Knize, R.J.; Cecchi, J.L.

    1991-08-20T23:59:59.000Z

    Tritium and deuterium are separated from a gaseous mixture thereof, derived from a nuclear fusion reactor or some other source, by providing a casing with a bulk getter therein for absorbing the gaseous mixture to produce an initial loading of the getter, partially desorbing the getter to produce a desorbed mixture which is tritium-enriched, pumping the desorbed mixture into a separate container, the remaining gaseous loading in the getter being deuterium-enriched, desorbing the getter to a substantially greater extent to produce a deuterium-enriched gaseous mixture, and removing the deuterium-enriched mixture into another container. The bulk getter may comprise a zirconium-aluminum alloy, or a zirconium-vanadium-iron alloy. The partial desorption may reduce the loading by approximately fifty percent. The basic procedure may be extended to produce a multistage isotope separator, including at least one additional bulk getter into which the tritium-enriched mixture is absorbed. The second getter is then partially desorbed to produce a desorbed mixture which is further tritium-enriched. The last-mentioned mixture is then removed from the container for the second getter, which is then desorbed to a substantially greater extent to produce a desorbed mixture which is deuterium-enriched. The last-mentioned mixture is then removed so that the cycle can be continued and repeated. The method of isotope separation is also applicable to other hydrogen isotopes, in that the method can be employed for separating either deuterium or tritium from normal hydrogen. 4 figures.

  8. Stable isotope fractionation by thermal diffusion through partially molten wet and dry silicate rocks

    E-Print Network [OSTI]

    Bindeman, Ilya N.

    isotope redistribution by thermal diffusion leading to enrichment of light isotopes at the hot endStable isotope fractionation by thermal diffusion through partially molten wet and dry silicate 2012 Editor: T.M. Harrison Keywords: thermal diffusion hydrogen isotope separation oxygen isotopes

  9. Conditions under which cracks occur in modified 13% chromium steel in wet hydrogen sulfide environments

    SciTech Connect (OSTI)

    Hara, T.; Asahi, H.

    2000-05-01T23:59:59.000Z

    Occurrence of cracks in an API 13% Cr steel, modified 13% Cr steel, and duplex stainless steel were compared in various wet, mild hydrogen sulfide (H{sub 2}S) environments. The conditions under which cracks occurred in the modified 13% Cr steel in oil and gas production environments were made clear. No cracks occurred if pH > depassivation pH (pH{sub d}) and redox potential of sulfur (E{sub S(red/ax)}) < pitting potential (V{sub c}). Hydrogen embrittlement-type cracks occurred in pH > Ph{sub d} and E{sub S(red/ax)} > V{sub c}. The pH inside the pit decreased drastically and hydrogen embrittlement occurred. Cracks of the hydrogen embrittlement type occurred if pH < pH{sub d} and threshold hydrogen concentration under which cracks occur (H{sub th}) < hydrogen concentration in steel (H{sub 0}). No cracks occurred if pH < pH{sub d} and H{sub th} > H{sub 0}.

  10. Isotope shifts in francium isotopes Fr 206 - 213 and Fr 221

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Collister, R.; Gwinner, G.; Tandecki, M.; Behr, J. A.; Pearson, M. R.; Zhang, J.; Orozco, L. A.; Aubin, S.; Gomez, E.; FrPNC Collaboration

    2014-11-01T23:59:59.000Z

    We present the isotope shifts of the 7s1/2 to 7p1/2 transition for francium isotopes ²???²¹³Fr with reference to ²²¹Fr collected from two experimental periods. The shifts are measured on a sample of atoms prepared within a magneto-optical trap by a fast sweep of radio-frequency sidebands applied to a carrier laser. King plot analysis, which includes literature values for 7s1/2 to 7p3/2 isotope shifts, provides a field shift constant ratio of 1.0520(10) and a difference between the specific mass shift constants of 170(100) GHz amu between the D? and D? transitions, of sufficient precision to differentiate between ab initio calculations.

  11. Climate change deduced from isotopes in tree rings

    SciTech Connect (OSTI)

    Pendall, E.G.; Leavitt, S.W.

    1997-11-01T23:59:59.000Z

    This paper describes the theory of carbon, hydrogen, and oxygen isotopic signatures in cellulose for the purpose of paleoclimatic reconstruction. Mechanisms governing tree ring cellulose isotopic variability are investigated, and applications to the southwestern United States are delineated. A monitoring program of pinyon trees and comparison to climatic parameters is briefly described. Variables measured included deviations in hydrogen and oxygen-18 isotopic composition in precipitation, soil water, stem and leaf water, and atmospheric vapor. Water from phloem tissue was found to be isotopically identical to the xylem sap, suggesting that cellulose precursors can exchange isotopically with source water before cellulose is made in the trunk, thus removing most of the isotopic signal from the leaves. Overall results suggest that, on arid sites in the southwestern US receiving adequate summer rain, a precipitation seasonality signal may be recorded. 21 refs., 2 figs.

  12. CAN GALACTIC CHEMICAL EVOLUTION EXPLAIN THE OXYGEN ISOTOPIC VARIATIONS IN THE SOLAR SYSTEM?

    SciTech Connect (OSTI)

    Lugaro, Maria [Monash Centre for Astrophysics (MoCA), Building 28, Monash University, Clayton, VIC 3800 (Australia); Liffman, Kurt [CSIRO/MSE, P.O. Box 56, Highett, VIC 3190 (Australia); Ireland, Trevor R. [Planetary Science Institute and Research School of Earth Sciences, Australian National University, Canberra, ACT 0200 (Australia); Maddison, Sarah T., E-mail: maria.lugaro@monash.edu [Centre for Astrophysics and Supercomputing, Swinburne University, H39, P.O. Box 218, Hawthorn, VIC 3122 (Australia)

    2012-11-01T23:59:59.000Z

    A number of objects in primitive meteorites have oxygen isotopic compositions that place them on a distinct, mass-independent fractionation line with a slope of one on a three-isotope plot. The most popular model for describing how this fractionation arose assumes that CO self-shielding produced {sup 16}O-rich CO and {sup 16}O-poor H{sub 2}O, where the H{sub 2}O subsequently combined with interstellar dust to form relatively {sup 16}O-poor solids within the solar nebula. Another model for creating the different reservoirs of {sup 16}O-rich gas and {sup 16}O-poor solids suggests that these reservoirs were produced by Galactic chemical evolution (GCE) if the solar system dust component was somewhat younger than the gas component and both components were lying on the line of slope one in the O three-isotope plot. We argue that GCE is not the cause of mass-independent fractionation of the oxygen isotopes in the solar system. The GCE scenario is in contradiction with observations of the {sup 18}O/{sup 17}O ratios in nearby molecular clouds and young stellar objects. It is very unlikely for GCE to produce a line of slope one when considering the effect of incomplete mixing of stellar ejecta in the interstellar medium. Furthermore, the assumption that the solar system dust was younger than the gas requires unusual timescales or the existence of an important stardust component that is not theoretically expected to occur nor has been identified to date.

  13. System and method for high precision isotope ratio destructive analysis

    DOE Patents [OSTI]

    Bushaw, Bruce A; Anheier, Norman C; Phillips, Jon R

    2013-07-02T23:59:59.000Z

    A system and process are disclosed that provide high accuracy and high precision destructive analysis measurements for isotope ratio determination of relative isotope abundance distributions in liquids, solids, and particulate samples. The invention utilizes a collinear probe beam to interrogate a laser ablated plume. This invention provides enhanced single-shot detection sensitivity approaching the femtogram range, and isotope ratios that can be determined at approximately 1% or better precision and accuracy (relative standard deviation).

  14. Fractal Nature of Solar Interior

    E-Print Network [OSTI]

    Koushik Ghosh; Probhas Raychaudhuri

    2006-05-04T23:59:59.000Z

    Fractal method has been studied to understand the irregular and chaotic nature of any physical structure. Conventionally it is suggested that the solar interior is rigid in nature. Since solar neutrino flux is the indicator of the interior solar structure it is natural to study the solar neutrino flux source to find if the nuclear energy generation inside the sun is fractal in nature or not. At present there exist five solar neutrino experiments to detect neutrinos from the sun which can suggest which type of nuclear energy generation occurs inside the sun. Since we know that the solar atmosphere is irregular in nature many authors have studied this irregular nature by fractal analysis. In this regard we have studied solar neutrino flux data from 1) Homestake detector during the period from March, 1970 to April, 1994; 2) SAGE detector during the period from 1st January, 1990 to 31st December, 2000; 3) SAGE detector during the period from April, 1998 to December, 2001; 4) GALLEX detector during the period from May, 1991 to January, 1997; 5) GNO detector during the period from May, 1998 to December, 2001; 6) GALLEX-GNO detector (combined data) from May, 1991 to December, 2001; 7) average of the data from GNO and SAGE detectors during the period from May, 1998 to December, 2001; 8) 5-day-long samples from Super-Kamiokande-I detector during the period from June, 1996 to July,2001; 9) 10-day-long samples from Super-Kamiokande-I detector during the period from June,1996 to July,2001 and 10) 45-day-long samples from Super-Kamiokande-I detector during the period from June,1996 to July,2001 by fractal analysis and we have arrived at the conclusion that the solar neutrino flux data are fractal in nature.

  15. Enriched Stable Isotope Materials and Chemistry | ornl.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Chemistry SHARE Enriched Stable Isotope Materials and Chemistry Reductiondistillation of calcium-48 metal valued at over 900,000. An inventory of 2,300 batches of...

  16. Copper isotope fractionation in acid mine drainage. | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in acid mine drainage. Abstract: We surveyed the Cu isotopic composition of primary minerals and stream water affected by acid mine drainage in a mineralized watershed located in...

  17. actinium isotopes including: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Topic Index 1 Discovery of the actinium, thorium, protactinium, and uranium isotopes CERN Preprints Summary: Currently, 31 actinium, 31 thorium, 28 protactinium, and 23 uranium...

  18. actinium isotopes: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Topic Index 1 Discovery of the actinium, thorium, protactinium, and uranium isotopes CERN Preprints Summary: Currently, 31 actinium, 31 thorium, 28 protactinium, and 23 uranium...

  19. Isotopic Analysis- Fluid At Roosevelt Hot Springs Geothermal...

    Open Energy Info (EERE)

    Details Location Roosevelt Hot Springs Geothermal Area Exploration Technique Isotopic Analysis- Fluid Activity Date 1981 - 1981 Usefulness useful DOE-funding Unknown Exploration...

  20. Isotopic Analysis- Fluid At Indian Valley Hot Springs Geothermal...

    Open Energy Info (EERE)

    Activity: Isotopic Analysis- Fluid At Indian Valley Hot Springs Geothermal Area (1990) Exploration Activity Details Location Indian Valley Hot Springs Geothermal Area...

  1. Helium isotopes in geothermal systems- Iceland, The Geysers,...

    Open Energy Info (EERE)

    Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: Helium isotopes in geothermal systems- Iceland, The Geysers, Raft River and Steamboat Springs...

  2. Isotopic Analysis At Nw Basin & Range Region (Kennedy & Van Soest...

    Open Energy Info (EERE)

    useful regional reconnaissance DOE-funding Unknown Notes The correspondence of helium isotope ratios and active transtensional deformation indicates a deformation-enhanced...

  3. Isotopic Analysis At Northern Basin & Range Region (Kennedy ...

    Open Energy Info (EERE)

    useful regional reconnaissance DOE-funding Unknown Notes The correspondence of helium isotope ratios and active transtensional deformation indicates a deformation-enhanced...

  4. Isotopic Analysis At Central Nevada Seismic Zone Region (Kennedy...

    Open Energy Info (EERE)

    useful regional reconnaissance DOE-funding Unknown Notes The correspondence of helium isotope ratios and active transtensional deformation indicates a deformation-enhanced...

  5. Isotopic Analysis At Walker-Lane Transitional Zone Region (Kennedy...

    Open Energy Info (EERE)

    useful regional reconnaissance DOE-funding Unknown Notes The correspondence of helium isotope ratios and active transtensional deformation indicates a deformation-enhanced...

  6. Isotopic Analysis- Fluid At Long Valley Caldera Geothermal Area...

    Open Energy Info (EERE)

    Farrar, Et Al., 2003) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Isotopic Analysis- Fluid At Long Valley Caldera Geothermal Area (Farrar, Et...

  7. Sulfur Isotopes as Indicators of Amended Bacterial Sulfate Reduction...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of Amended Bacterial Sulfate Reduction Processes Influencing Field Scale Uranium Bioremediation. Sulfur Isotopes as Indicators of Amended Bacterial Sulfate Reduction Processes...

  8. anomalous isotope effect: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the following recombination Reid, Scott A. 4 Anomalous quantum and isotope effects in water clusters: Physical phenomenon, model artifact, or bad approximation? CERN Preprints...

  9. Geothermal reservoir temperatures estimated from the oxygen isotope...

    Open Energy Info (EERE)

    reservoir temperatures estimated from the oxygen isotope compositions of dissolved sulfate and water from hot springs and shallow drillholes Jump to: navigation, search OpenEI...

  10. Geothermal Reservoir Temperatures Estimated from the Oxygen Isotope...

    Open Energy Info (EERE)

    Temperatures Estimated from the Oxygen Isotope Compositions of Dissolved Sulfate and Water from Hot Springs and Shallow Drillholes Jump to: navigation, search OpenEI Reference...

  11. An Oxygen Isotope Study Of Silicates In The Larderello Geothermal...

    Open Energy Info (EERE)

    Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: An Oxygen Isotope Study Of Silicates In The Larderello Geothermal Field, Italy Abstract...

  12. Chemical And Isotopic Investigation Of Warm Springs Associated...

    Open Energy Info (EERE)

    water (high TDS, > 5000 mgl). Deviations from the meteoric water line are the result of rock-water isotopic exchange, mixing or evaporation. Fluid source regions and residence...

  13. Hydrogeological And Isotopic Survey Of Geothermal Fields In The...

    Open Energy Info (EERE)

    Hydrogeological And Isotopic Survey Of Geothermal Fields In The Buyuk Menderes Graben, Turkey Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article:...

  14. Isotopic Analysis At Long Valley Caldera Geothermal Area (Evans...

    Open Energy Info (EERE)

    Isotopic Analysis At Long Valley Caldera Geothermal Area (Evans, Et Al., 2002) Exploration Activity Details Location Long Valley Caldera Geothermal Area Exploration Technique...

  15. Isotopic Analysis- Fluid At Long Valley Caldera Geothermal Area...

    Open Energy Info (EERE)

    Gerlach, 1983) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Isotopic Analysis- Fluid At Long Valley Caldera Geothermal Area (Taylor & Gerlach,...

  16. Oxygen And Carbon Isotope Ratios Of Hydrothermal Minerals From...

    Open Energy Info (EERE)

    Oxygen And Carbon Isotope Ratios Of Hydrothermal Minerals From Yellowstone Drill Cores Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: Oxygen...

  17. Isotopic Composition of Carbon in Fluids from the Long Valley...

    Open Energy Info (EERE)

    Isotopic Composition of Carbon in Fluids from the Long Valley Geothermal System, California, In- Proceedings of the Second Workshop on Hydrologic and Geochemical Monitoring in the...

  18. Mantle Helium And Carbon Isotopes In Separation Creek Geothermal...

    Open Energy Info (EERE)

    Mantle Helium And Carbon Isotopes In Separation Creek Geothermal Springs, Three Sisters Area, Central Oregon- Evidence For Renewed Volcanic Activity Or A Long Term Steady State...

  19. antimony isotopes: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1 Hartmut Bracht 258 Late Pleistocene C4 Plant Dominance and Summer Rainfall in the Southwestern United States from Isotopic Study of Herbivore Teeth Geosciences Websites Summary:...

  20. Stable carbon and nitrogen isotope enrichment in primate tissues

    E-Print Network [OSTI]

    Crowley, Brooke E.; Carter, Melinda L.; Karpanty, Sarah M.; Zihlman, Adrienne L.; Koch, Paul L.; Dominy, Nathaniel J.

    2010-01-01T23:59:59.000Z

    and nitrogen isotope enrichment in primate tissues Brooke E.and nitrogen apparent enrichment (e*) values ± one standardexplored the apparent enrichment (e*) between bone collagen

  1. Hyperfiltration-induced fractionation of lithium isotopes in geologic systems. Progress report, April 1, 1991--December 1, 1991

    SciTech Connect (OSTI)

    Fritz, S.J.

    1992-01-01T23:59:59.000Z

    Effective modeling of hyperfiltration-induced fractionation of lithium isotopes is hindered by a lack of data on aqueous diffusion coefficients of {sup 6}Li{sup +} and {sup 7}Li{sup +}. Several experiments were conducted this past year on yielded a value for the ratio of diffusion coefficients between {sup D6}Li+Cl{minus}/{sup D7}Li+Cl{minus}. A 0.9450 M LiCl solution was placed within sealed dialysis tubing and osmoted against a kilogram of deionized water at 22C. Osmotic equilibrium occurred at 143 minutes, and the ratio of {omega}{sup 6}Li{sup +}Cl{minus}/{omega}{sup 7}Li+Cl{minus} was measured to be 1.011. Because this experimental value is close to the square root of the mass ratio between {sup 7}LiCl and {sup 6}LiCl (1.012), Graham`s Law may be a convenient way to calculate such ratios for aqueous diffusion coefficients of individual isotopic components. In evolution of this closed-system osmotic cell as a function of time, Li isotopic ratios of beaker and bag solutions exhibit a minimum and a maximum before the {sup 6}Li/{sup 7}Li ratios of both solutions assume the inevitable asymptotic approach toward isotopic equilibrium. Max difference in {sup 6}Li/{sup 7}Li ratio between beaker and bag solution was 0.00156 {plus_minus} 0.00015.

  2. Contamination Cross-contamination occurs when bacteria, or "germs," are moved from one food to another.

    E-Print Network [OSTI]

    Combat Cross Contamination Cross-contamination occurs when bacteria, or "germs," are moved from one food to another. To combat cross-contamination, keep foods SEPARATE!! At the grocery store, keep raw

  3. Viscosities of natural gases at high pressures and high temperatures

    E-Print Network [OSTI]

    Viswanathan, Anup

    2007-09-17T23:59:59.000Z

    Estimation of viscosities of naturally occurring petroleum gases provides the information needed to accurately work out reservoir-engineering problems. Existing models for viscosity prediction are limited by data, especially at high pressures...

  4. Natural ventilation possibilities for buildings in the United States

    E-Print Network [OSTI]

    Dean, Brian N. (Brian Nathan), 1974-

    2001-01-01T23:59:59.000Z

    In the United States, many of the commercial buildings built in the last few decades are completely mechanically air conditioned, without the capability to use natural ventilation. This habit has occurred in building designs ...

  5. Oxygen isotope fractionation in the vacuum ultraviolet photodissociation of carbon monoxide: Wavelength, pressure and temperature dependency.

    E-Print Network [OSTI]

    Chakraborty, Subrata

    2013-01-01T23:59:59.000Z

    The extent of heavy isotope enrichment (? 17 O and ? 18 O)range of the heavy isotope enrichment (? 17 O and ? 18 O) isThe extent of heavy isotope enrichment (? 17 O and ? 18 O)

  6. A Mass Spectrometry Study of Isotope Separation in the Laser Plume

    E-Print Network [OSTI]

    Suen, Timothy Wu

    2012-01-01T23:59:59.000Z

    Zhang, and J. A. Nees, “Isotope Enrichment in Laser-AblationA. Naik, “Comment on “Isotope Enrichment in Laser-AblationP. Pronko, “Isotope separation and enrichment by ultrafast

  7. GEOCHEMISTRY AND ISOTOPE HYDROLOGY OF GROUNDWATERS IN THE STRIPA GRANITE RESULTS AND PRELIMINARY INTERPRETATION

    E-Print Network [OSTI]

    Fritz, P.

    2011-01-01T23:59:59.000Z

    S. Italy). In Isotope Hydrology, IAEA Symposium. Sm-129/53,isotopic variations in hydrology. At. Energy Rev. 14: 621-70 GEOCHEMISTRY AND ISOTOPE HYDROLOGY OF GROUNDWATERS IN THE

  8. Comparison of atmospheric hydrology over convective continental regions using water vapor isotope measurements from space

    E-Print Network [OSTI]

    . Correlation analysis shows that mixing with boundary layer air, enhanced isotopic fractionation during precipitation, and subsiding air parcels contribute to intraseasonal isotopic variability. These local controls distillation in a Lagrangrian framework underestimates the observed isotopic depletion during the monsoons

  9. Chemical and Isotopic Evidence of Steam Upflow and Partial Condensation in Los Azufres Reservoir

    SciTech Connect (OSTI)

    Nieva, D.; Verma, M.; Santoyo, E.; Barragan, R.M.; Portugal, E.; Ortiz, J.; Quijano, J.L.

    1987-01-20T23:59:59.000Z

    Data of chemical and isotopic composition of fluids from Los Azufres wells, collected over a two year period, provide evidence of a process of upward flow and partial condensation of steam in the reservoir, which explains part of the previously reported heterogeneity in isotopic composition of the liquid phase (Nieva et al, 1983). For the southern part of the field, a direct correlation is found between chloride and oxygen-18 concentrations, and an inverse correlation between these parameters and deuterium and carbon dioxide concentrations in the liquid phase of the reservoir. Chloride ion concentrations increase gradually from ca 660 ppm in the production zones of shallow wells to ca 1900 ppm in the case of deep wells. This observation agrees with predictions based on the well-known model for vapor dominated systems of White et al (1971). For the northern part of the field the same correlations are observed, except for the deuterium concentration which in this case correlates directly with oxygen-18. It is concluded that the same process of steam upflow occurs in the northern section but that some other process — perhaps a mixture with other hydrothermal fluid — is also occurring. 3 tabs., 16 refs., 8 figs.

  10. Teaching About Nature's Nuclear Reactors

    E-Print Network [OSTI]

    Herndon, J M

    2005-01-01T23:59:59.000Z

    Naturally occurring nuclear reactors existed in uranium deposits on Earth long before Enrico Fermi built the first man-made nuclear reactor beneath Staggs Field in 1942. In the story of their discovery, there are important lessons to be learned about scientific inquiry and scientific discovery. Now, there is evidence to suggest that the Earth's magnetic field and Jupiter's atmospheric turbulence are driven by planetary-scale nuclear reactors. The subject of planetocentric nuclear fission reactors can be a jumping off point for stimulating classroom discussions about the nature and implications of planetary energy sources and about the geomagnetic field. But more importantly, the subject can help to bring into focus the importance of discussing, debating, and challenging current thinking in a variety of areas.

  11. nature methods | VOL.6 NO.9 | SEPTEMBER 2009 | 631 research highlights

    E-Print Network [OSTI]

    Cai, Long

    the antioxidant lycopene by optimizing the biosynthetic pathway. Wang, H.H. et al. Nature 460, 894­898 (2009 of kinases in a cell lysate by monitoring the phosphorylation of 90 synthetic known peptide substrates via mass spectrometry, using heavy isotope­labeled versions of the peptides as internal quantitative

  12. Nitrous Oxide and Molecular Nitrogen Isotopic Compositions and Aerosol Optical Properties: Experiments and Observations Relevant to Planetary Atmospheres

    E-Print Network [OSTI]

    Croteau, Philip Louis

    2010-01-01T23:59:59.000Z

    Stratospheric enrichment, isotope-budgets and the 17O-18Olead to enrichments or depletions in the isotope ratios of

  13. Apparatus for isotopic alteration of mercury vapor

    DOE Patents [OSTI]

    Grossman, Mark W. (Belmont, MA); George, William A. (Gloucester, MA); Marcucci, Rudolph V. (Danvers, MA)

    1988-01-01T23:59:59.000Z

    An apparatus for enriching the isotopic Hg content of mercury is provided. The apparatus includes a reactor, a low pressure electric discharge lamp containing a fill including mercury and an inert gas. A filter is arranged concentrically around the lamp. In a preferred embodiment, constant mercury pressure is maintained in the filter by means of a water-cooled tube that depends from it, the tube having a drop of mercury disposed in it. The reactor is arranged around the filter, whereby radiation from said lamp passes through the filter and into said reactor. The lamp, the filter and the reactor are formed of a material which is transparent to ultraviolet light.

  14. Laser-assisted isotope separation of tritium

    DOE Patents [OSTI]

    Herman, Irving P. (Castro Valley, CA); Marling, Jack B. (Livermore, CA)

    1983-01-01T23:59:59.000Z

    Methods for laser-assisted isotope separation of tritium, using infrared multiple photon dissociation of tritium-bearing products in the gas phase. One such process involves the steps of (1) catalytic exchange of a deuterium-bearing molecule XYD with tritiated water DTO from sources such as a heavy water fission reactor, to produce the tritium-bearing working molecules XYT and (2) photoselective dissociation of XYT to form a tritium-rich product. By an analogous procedure, tritium is separated from tritium-bearing materials that contain predominately hydrogen such as a light water coolant from fission or fusion reactors.

  15. Strategic Isotope Production | ornl.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over Our Instagram Secretary900Steep SlopeStochastic WeeklyStoresStrategic Isotope

  16. Isotope Program Transportation | Department of Energy

    Office of Environmental Management (EM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 1112011 Strategic2 OPAM Flash2011-12Approvedof EnergyWorld Design Challenge |Is aIsotope

  17. Regulation of natural monopolies

    E-Print Network [OSTI]

    Joskow, Paul L.

    2005-01-01T23:59:59.000Z

    This chapter provides a comprehensive overview of the theoretical and empirical literature on the regulation of natural monopolies. It covers alternative definitions of natural monopoly, regulatory goals, alternative ...

  18. Natural Gas Monthly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    other liquids including biofuels and natural gas liquids. Natural Gas Exploration and reserves, storage, imports and exports, production, prices, sales. Electricity Sales, revenue...

  19. Borrowing Nature's Polymers

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Borrowing Nature's Polymers 1663 Los Alamos science and technology magazine Latest Issue:January 2015 All Issues submit Borrowing Nature's Polymers Los Alamos scientists are...

  20. Natural Resources Districts (Nebraska)

    Broader source: Energy.gov [DOE]

    This statute establishes Natural Resources District, encompassing all of the area of the state, to conserve, protect, develop, and manage Nebraska's natural resources. These districts replace and...

  1. Historical Natural Gas Annual

    U.S. Energy Information Administration (EIA) Indexed Site

    8 The Historical Natural Gas Annual contains historical information on supply and disposition of natural gas at the national, regional, and State level as well as prices at...

  2. Natural Gas Rules (Louisiana)

    Broader source: Energy.gov [DOE]

    The Louisiana Department of Natural Resources administers the rules that govern natural gas exploration and extraction in the state. DNR works with the Louisiana Department of Environmental...

  3. Historical Natural Gas Annual

    U.S. Energy Information Administration (EIA) Indexed Site

    6 The Historical Natural Gas Annual contains historical information on supply and disposition of natural gas at the national, regional, and State level as well as prices at...

  4. Historical Natural Gas Annual

    U.S. Energy Information Administration (EIA) Indexed Site

    7 The Historical Natural Gas Annual contains historical information on supply and disposition of natural gas at the national, regional, and State level as well as prices at...

  5. alpha-particle-emitting isotope 259db: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CERN Preprints Summary: Currently, 31 actinium, 31 thorium, 28 protactinium, and 23 uranium isotopes have so far been observed; the discovery of these isotopes is discussed. For...

  6. alpha-active iridium isotopes: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CERN Preprints Summary: Currently, 31 actinium, 31 thorium, 28 protactinium, and 23 uranium isotopes have so far been observed; the discovery of these isotopes is discussed. For...

  7. Enriched Background Isotope Study (EBIS) Litter reciprocal transplant studies to understand sources, transport and

    E-Print Network [OSTI]

    1 Enriched Background Isotope Study (EBIS) Litter reciprocal transplant studies to understand were removed from this archived version.] #12;3 Enriched Background Isotope Study (EBIS): Litter

  8. Natural gas monthly, March 1999

    SciTech Connect (OSTI)

    NONE

    1999-03-01T23:59:59.000Z

    This issue of the Natural Gas Monthly contains estimates for March 1999 for many natural gas data series at the national level. Estimates of national natural gas prices are available through December 1998 for most series. Highlights of the data contained in this issue are listed below. Preliminary data indicate that the national average wellhead price for 1998 declined to 16% from the previous year ($1.96 compared to $2.32 per thousand cubic feet). At the end of March, the end of the 1998--1999 heating season, the level of working gas in underground natural gas storage facilities is estimated to be 1,354 billion cubic feet, 169 billion cubic feet higher than at the end of March 1998. Gas consumption during the first 3 months of 1999 is estimated to have been 179 billion cubic feet higher than in the same period in 1998. Most of this increase (133 billion cubic feet) occurred in the residential sector due to the cooler temperatures in January and February compared to the same months last year. According to the National Weather Service, heating degree days in January 1999 were 15% greater than the previous year while February recorded a 5% increase.

  9. The Valles natural analogue project

    SciTech Connect (OSTI)

    Stockman, H.; Krumhansl, J.; Ho, C. [Sandia National Labs., Albuquerque, NM (United States); McConnell, V. [Alaska Univ., Fairbanks, AK (United States). Geophysical Inst.

    1994-12-01T23:59:59.000Z

    The contact between an obsidian flow and a steep-walled tuff canyon was examined as an analogue for a highlevel waste repository. The analogue site is located in the Valles Caldera in New Mexico, where a massive obsidian flow filled a paleocanyon in the Battleship Rock tuff. The obsidian flow provided a heat source, analogous to waste panels or an igneous intrusion in a repository, and caused evaporation and migration of water. The tuff and obsidian samples were analyzed for major and trace elements and mineralogy by INAA, XRF, X-ray diffraction; and scanning electron microscopy and electron microprobe. Samples were also analyzed for D/H and {sup 39}Ar/{sup 4O} isotopic composition. Overall,the effects of the heating event seem to have been slight and limited to the tuff nearest the contact. There is some evidence of devitrification and migration of volatiles in the tuff within 10 meters of the contact, but variations in major and trace element chemistry are small and difficult to distinguish from the natural (pre-heating) variability of the rocks.

  10. Global Natural Gas Market Trends, 2. edition

    SciTech Connect (OSTI)

    NONE

    2007-07-15T23:59:59.000Z

    The report provides an overview of major trends occurring in the natural gas industry and includes a concise look at the drivers behind recent rapid growth in gas usage and the challenges faced in meeting that growth. Topics covered include: an overview of Natural Gas including its history, the current market environment, and its future market potential; an analysis of the overarching trends that are driving a need for change in the Natural Gas industry; a description of new technologies being developed to increase production of Natural Gas; an evaluation of the potential of unconventional Natural Gas sources to supply the market; a review of new transportation methods to get Natural Gas from producing to consuming countries; a description of new storage technologies to support the increasing demand for peak gas; an analysis of the coming changes in global Natural Gas flows; an evaluation of new applications for Natural Gas and their impact on market sectors; and, an overview of Natural Gas trading concepts and recent changes in financial markets.

  11. Neutron Stimulated Emission Computed Tomography of Stable Isotopes

    E-Print Network [OSTI]

    on the development of a new molecular imaging technique using inelastic scattering of fast neutrons. Earlier studies characteristic gamma photons through inelastic scattering of an external neutron beam. These stable isotopes canNeutron Stimulated Emission Computed Tomography of Stable Isotopes Carey E. Floyd Jr.*ab , Calvin

  12. Hydrochemical and isotopic effects associated with petroleum fuel biodegradation pathways

    E-Print Network [OSTI]

    Sheffield, University of

    hydrocarbons and residual electron acceptors have been used to deduce BTEX and MTBE degradation pathways. Benzene and MTBE persist into the denitrification zone, with carbon isotope enrichment of benzene-enrichment of residual benzene gives an apparent e value of Ã?0.66x. MTBE shows no significant isotopic enrichment (d13 C

  13. Quantifying intrapopulation variability in stable isotope data for Spotted Seatrout

    E-Print Network [OSTI]

    111 Quantifying intrapopulation variability in stable isotope data for Spotted Seatrout (Cynoscion of the National Marine Fisheries Service, NOAA. Abstract--Stable isotope (SI) values of carbon (13C) and nitrogen patterns of enrichment in fish caught from coastal to off- shore sites and as a function of fish size

  14. Boron isotope application for tracing sources of contamination in groundwater.

    E-Print Network [OSTI]

    Kasher, Roni

    Boron isotope application for tracing sources of contamination in groundwater. Abstract: Boron isotope composition and concentration of sewage effluent and pristine and contaminated groundwater from sodium perborate as a bleaching agent in detergents, leads to an enrichment of boron in wastewaters

  15. Lithium Isotope History of Cenozoic Seawater: Changes in Silicate Weathering

    E-Print Network [OSTI]

    Paytan, Adina

    Lithium Isotope History of Cenozoic Seawater: Changes in Silicate Weathering and Reverse Weathering 70 Ma · Overview of the Marine Lithium Cycle · Analytical Challenges · 68 Million Year Seawater Lithium Isotope Record (Forams) · Interpretation Standard: NIST L-SVEC Li (SRM 8545) #12;100 Ma Climate

  16. Packed bed reactor for photochemical sup 196 Hg isotope separation

    SciTech Connect (OSTI)

    Grossman, M.W.; Speer, R.

    1992-03-03T23:59:59.000Z

    This patent describes a photochemical reactor useful for the isotopic enrichment of a predetermined isotope of mercury comprising a reactor cell and a monoisotopic light source It comprises: a plurality of transparent, straight reactor cell tubes disposed axially within the internal volume of the reactor cell to increase the surface area thereof for production deposition.

  17. RADIOGENIC ISOTOPES: TRACERS OF PAST OCEAN CIRCULATION AND EROSIONAL INPUT

    E-Print Network [OSTI]

    Jellinek, Mark

    of Earth Sciences Institute for Isotope Geology and Mineral Resources Eidgeno¨ssische Technische Hochschule the global mixing time of the ocean (Nd, Pb, Hf, and, in addition, Be). Their isotopic composition global ocean circulation system is largely driven by the sinking of cold, saline (and therefore dense

  18. atmospheric carbon isotope: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    atmospheric carbon isotope First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Carbon isotope...

  19. aves carbon isotopes: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    aves carbon isotopes First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 1, 393412, 2004 Carbon isotope...

  20. Nitrogen isotope effects on glutamate decarboxylase from Escherichia coli

    SciTech Connect (OSTI)

    Abell, L.M.; O'Leary, M.H.

    1988-05-03T23:59:59.000Z

    The nitrogen isotope effect on the decarboxylation of glutamic acid by glutamate decarboxylase from Escherichia coli has been measured by comparison of the isotopic composition of the amino nitrogen of the product ..gamma..-aminobutyric acid isolated after 10-20% reaction with that of the starting glutamic acid. At pH 4.7, 37 /sup 0/C, the isotope effect is k/sup 14//k/sup 15/ = 0.9855 +/- 0.0006 when compared to unprotonated glutamic acid. Interpretation of this result requires knowledge of the equilibrium nitrogen isotope effect for Schiff base formation. This equilibrium isotope effect is K/sup 14//K/sup 15/ - 0.9824 for the formation of the unprotonated Schiff base between unprotonated valine and salicylaldehyde. Analysis of the nitrogen isotope effect on decarboxylation of glutamic acid and of the previously measured carbon isotope effect on this same reaction shows that decarboxylation and Schiff base formation are jointly rate limiting. The enzyme-bound Schiff base between glutamate and pyridoxal 5'-phosphate partitions approximately 2:1 between decarboxylation and return to the starting state. The nitrogen isotope effect also reveals that the Schiff base nitrogen is protonated in this intermediate.

  1. Quantum fluctuations and isotope effects in ab initio descriptions of water

    E-Print Network [OSTI]

    Lu Wang; Michele Ceriotti; Thomas E. Markland

    2014-06-24T23:59:59.000Z

    Nuclear quantum effects, such as zero-point energy and tunneling, cause significant changes to the structure and dynamics of hydrogen bonded systems such as liquid water. However, due to the current inability to simulate liquid water using an exact description of its electronic structure, the interplay between nuclear and electronic quantum effects remains unclear. Here we use simulations that incorporate the quantum mechanical nature of both the nuclei and electrons to provide a fully ab initio determination of the particle quantum kinetic energies, free energy change upon exchanging hydrogen for deuterium and the isotope fractionation ratio in water. These properties, which selectively probe the quantum nature of the nuclear degrees of freedom, allow us to make direct comparison to recent experiments and elucidate how electronic exchange and correlation and nuclear quantum fluctuations determine the structure of the hydrogen bond in water.

  2. Monte Carlo uncertainty reliability and isotope production calculations for a fast reactor

    SciTech Connect (OSTI)

    Miles, T.L.

    1992-01-01T23:59:59.000Z

    Statistical uncertainties in Monte Carlo calculations are typically determined by the first and second moments of the tally. For certain types of calculations, there is concern that the uncertainty estimate is significantly non-conservative. This is typically seen in reactor eigenvalue problems where the uncertainty estimate is aggravated by the generation-to-generation fission source. It has been speculated that optimization of the random walk, through biasing techniques, may increase the non-conservative nature of the uncertainty estimate. A series of calculations are documented here which quantify the reliability of the Monte Carlo Neutron and Photon (MCNP) mean and uncertainty estimates by comparing these estimates to the true mean. These calculations were made with a liquid metal fast reactor model, but every effort was made to isolate the statistical nature of the uncertainty estimates so that the analysis of the reliability of the MCNP estimates should be relevant for small thermal reactors as well. Also, preliminary reactor physics calculations for two different special isotope production test assemblies for irradiation in the Fast Flux Test Facility (FFTF) were performed using MCNP and are documented here. The effect of an yttrium-hydride moderator to tailor the neutron flux incident on the targets to maximize isotope production for different designs in different locations within the reactor is discussed. These calculations also demonstrate the useful application of MCNP in design iterations by utilizing many of the codes features.

  3. Process for recovery of daughter isotopes from a source material

    DOE Patents [OSTI]

    Tranter, Troy J.; Todd, Terry A.; Lewis, Leroy C.; Henscheid, Joseph P.

    2005-10-04T23:59:59.000Z

    The invention includes a method of separating isotopes from a mixture containing at least two isotopes in a solution. A first isotope is precipitated and is collected from the solution. A daughter isotope is generated and collected from the first isotope. The invention includes a method of producing an actinium-225/bismuth-213 product from a material containing thorium-229 and thorium-232. A solution is formed containing nitric acid and the material and iodate is added to form a thorium iodate precipitate. A supernatant is separated from the thorium iodate precipitate and a second volume of nitric acid is added to the precipitate. The precipitate is stored and a decay product comprising actinium-225 and bismuth-213 is generated in the second volume of nitric acid which is then separated from the thorium iodate precipitate, filtered, and treated using at least one chromatographic procedure. The invention also includes a system for producing an actinium-225/bismuth-213 product.

  4. A proposed standard on medical isotope production in fission reactors

    SciTech Connect (OSTI)

    Schenter, R. E. [Smart Bullets Inc., 2521 SW Luradel Street, Portland, OR 97219 (United States); Brown, G. J. [Ozarks Medical Center, Cancer Treatment Center, Shaw Medical Building, 1111 Kentucky Avenue, West Plains, MO 65775 (United States); Holden, C. S. [Thorenco LLC, 369 Pine Street, San Francisco, CA 94104 (United States)

    2006-07-01T23:59:59.000Z

    Authors Robert E. Sehenter, Garry Brown and Charles S. Holden argue that a Standard for 'Medical Isotope Production' is needed. Medical isotopes are becoming major components of application for the diagnosis and treatment of all the major diseases including all forms of cancer, heart disease, arthritis, Alzheimer's, among others. Current nuclear data to perform calculations is incomplete, dated or imprecise or otherwise flawed for many isotopes that could have significant applications in medicine. Improved data files will assist computational analyses to design means and methods for improved isotope production techniques in the fission reactor systems. Initial focus of the Standard is expected to be on neutron cross section and branching data for both fast and thermal reactor systems. Evaluated and reviewed tables giving thermal capture cross sections and resonance integrals for the major target and product medical isotopes would be the expected 'first start' for the 'Standard Working Group'. (authors)

  5. $\\beta$-decay of key titanium isotopes in stellar environment

    E-Print Network [OSTI]

    Nabi, Jameel-Un; 10.1142/S0218301311018174

    2011-01-01T23:59:59.000Z

    Amongst iron regime nuclei, $\\beta$-decay rates on titanium isotopes are considered to be important during the late phases of evolution of massive stars. The key $\\beta$-decay isotopes during presupernova evolution were searched from available literature and a microscopic calculation of the decay rates were performed using the proton-neutron quasiparticle random phase approximation (pn-QRPA) theory. As per earlier simulation results electron capture and $\\beta$-decay on certain isotopes of titanium are considered to be important for the presupernova evolution of massive stars. Earlier the stellar electron capture rates and neutrino energy loss rates due to relevant titanium isotopes were presented. In this paper we finally present the $\\beta$-decay rates of key titanium isotopes in stellar environment. The results are also compared against previous calculations. The pn-QRPA $\\beta$-decay rates are bigger at high stellar temperatures and smaller at high stellar densities compared to the large scale shell model...

  6. Global Security, Medical Isotopes, and Nuclear Science

    SciTech Connect (OSTI)

    Ahle, L E

    2007-09-17T23:59:59.000Z

    Over the past century basic nuclear science research has led to the use of radioactive isotopes into a wide variety of applications that touch our lives everyday. Some are obvious, such as isotopes for medical diagnostics and treatment. Others are less so, such as National/Global security issues. And some we take for granted, like the small amount of 241Am that is in every smoke detector. At the beginning of this century, we are in a position where the prevalence and importance of some applications of nuclear science are pushing the basic nuclear science community for improved models and nuclear data. Yet, at the same time, the push by the basic nuclear science community to study nuclei that are farther and farther away from stability also offer new opportunities for many applications. This talk will look at several global security applications of nuclear science, summarizing current R&D and need for improved nuclear data It will also look at how applications of nuclear science, such as to medicine, will benefit from the push for more and more powerful radioactive ion beam facilities.

  7. Analysis of Elemental and Isotopic Composition of a Substance Obtained in Experiments on Energy Concentration in a Solid-State Superdense Plasma

    E-Print Network [OSTI]

    S. V. Adamenko; A. S. Adamenko

    2003-04-23T23:59:59.000Z

    We present the results of the experimental study on synthesis of a wide range of isotopes in a superdense plasma. The initial conditions necessary for plasma bunch formation were provided by specially organized coherent impact on a solid target with a total energy up to 1 kJ. More than 4000 shots were performed with various targets made of light, medium, and heavy elements. Subsequent analysis of the products of the target explosion reveals the presence of a wide range of elements absent in the initial materials. Elements with nuclei three and more times heavier than the nucleus of the target main element are detected in the products. The isotopic composition of the produced elements significantly differs from the natural one. The presence of unknown superheavy elements at the border of the periodic table and beyond it was detected by several different spectroscopic methods of elemental and isotopic analyzes.

  8. Natural Gas Exploration

    E-Print Network [OSTI]

    Boyer, Elizabeth W.

    . Exploration and extraction of natural gas from the Marcellus shale is a potentially valuable economic stimulus for landowners. You might be wondering how the nation's economic situation is affecting the market for naturalNatural Gas Exploration: A Landowners Guide to Financial Management Natural Gas Exploration

  9. Research Highlights Nature Nanotechnology

    E-Print Network [OSTI]

    Müller, Markus

    © 2009 APS Research Highlights Nature Nanotechnology Published online: 17 July 2009 | doi:10 perfect fluid. Phys. Rev. Lett. 103, 025301 (2009). | Article |1. Nature Nanotechnology ISSN 1748 : Nature Nanotechnology http://www.nature.com/nnano/reshigh/2009/0709/full/nnano.2009.222.html 1 of 1 18

  10. Strontium isotope quantification of siderite, brine and acid mine drainage contributions to abandoned gas well discharges in the Appalachian Plateau

    SciTech Connect (OSTI)

    Chapman, Elizabeth C.; Capo, Rosemary C.; Stewart, Brian W.; Hedin, Robert S.; Weaver, Theodore J.; Edenborn, Harry M.

    2013-04-01T23:59:59.000Z

    Unplugged abandoned oil and gas wells in the Appalachian region can serve as conduits for the movement of waters impacted by fossil fuel extraction. Strontium isotope and geochemical analysis indicate that artesian discharges of water with high total dissolved solids (TDS) from a series of gas wells in western Pennsylvania result from the infiltration of acidic, low Fe (Fe < 10 mg/L) coal mine drainage (AMD) into shallow, siderite (iron carbonate)-cemented sandstone aquifers. The acidity from the AMD promotes dissolution of the carbonate, and metal- and sulfate-contaminated waters rise to the surface through compromised abandoned gas well casings. Strontium isotope mixing models suggest that neither upward migration of oil and gas brines from Devonian reservoirs associated with the wells nor dissolution of abundant nodular siderite present in the mine spoil through which recharge water percolates contribute significantly to the artesian gas well discharges. Natural Sr isotope composition can be a sensitive tool in the characterization of complex groundwater interactions and can be used to distinguish between inputs from deep and shallow contamination sources, as well as between groundwater and mineralogically similar but stratigraphically distinct rock units. This is of particular relevance to regions such as the Appalachian Basin, where a legacy of coal, oil and gas exploration is coupled with ongoing and future natural gas drilling into deep reservoirs.

  11. New species of Mycosphaerella occurring on Eucalyptus leaves in Indonesia and Africa

    E-Print Network [OSTI]

    781 New species of Mycosphaerella occurring on Eucalyptus leaves in Indonesia and Africa P.W. Crous and M.J. Wingfield Ahstract:Although Africa and Indonesia have not been particularly well surveyed Eucalyptus leaves from Indonesia. The former species is of particular interest, because its anamorph

  12. Spike-timing dependent plasticity Spike order determines if potentiation or depression occurs [Poo98].

    E-Print Network [OSTI]

    Boahen, Kwabena

    in dendritic spines of pyramidal cells (L2/3, somatosensory cortex) does not predict the occurence of LTP or LTD. In this imaging experiment, the change relative to baseline of a Ca-sensitive green flourescent dye (DG) was normalized by a Ca-insensitive red flourescent dye (R) to account for differences

  13. Catastrophic Collapse Can Occur without Early Warning: Examples of Silent Catastrophes in Structured Ecological

    E-Print Network [OSTI]

    Roos, André M. de

    of the eigenvectors of the system. Our results demonstrate that claims on the universality of early warning signalsCatastrophic Collapse Can Occur without Early Warning: Examples of Silent Catastrophes Abstract Catastrophic and sudden collapses of ecosystems are sometimes preceded by early warning signals

  14. Mineralization of Decalcified Bone Occurs Under Cell Culture Conditions and Requires Bovine Serum But Not Cells

    E-Print Network [OSTI]

    Price, Paul A.

    Mineralization of Decalcified Bone Occurs Under Cell Culture Conditions and Requires Bovine Serum mineralization in the absence of cells. For this model, we utilized EDTA- decalcified new-born rat tibias with the cartilaginous ends intact, allowing us to visually determine the spec- ificity of mineralization within the bone

  15. C6H5Br+ f C6H5 + + Br Occurs via Orbiting Transition State

    E-Print Network [OSTI]

    Kim, Myung Soo

    -analyzed ion kinetic energy spectrometry. The rate constant and kinetic energy release distribution have been at high internal energy. The completely loose transition state model, namely the reaction occurring via compared with theoretical calculations. The rate-energy data available over 6 orders of magnitude in time

  16. between the nucleus and cytoplasm occurs through large macromolecular structures, the nuclear pores. Quantitative

    E-Print Network [OSTI]

    Forbes, Douglass

    the cytoplasm. Together these are assem- bled at points of fusion between the inner and outer nuclear membranes363 between the nucleus and cytoplasm occurs through large macromolecular structures, the nuclear pores. Quantitative scanning transmission electron microscopy has estimated the mass of a nuclear pore

  17. Tuesday, 31 July, 2012 Rapid radiation belt losses occurring during high speed solar wind stream1

    E-Print Network [OSTI]

    Otago, University of

    Tuesday, 31 July, 2012 1 Rapid radiation belt losses occurring during high speed solar wind stream1 Raita11 Sodankylä Geophysical Observatory, University of Oulu, Sodankylä, Finland12 Abstract. Recent geomagnetic disturbances triggered by the arrival of a Solar14 Wind Stream Interface (SWSI). In the current

  18. Obesity is defined as an excess accumulation of adipose tissue. It occurs in mammalian

    E-Print Network [OSTI]

    Cai, Long

    Obesity is defined as an excess accumulation of adipose tissue. It occurs in mammalian species when, obesity is now at epidemic proportions in the developed world1 , as well as in many developing countries2 . The links between obesity, type 2 diabetes and cardiovascular diseases have long been appreciated. However

  19. 2 Bainitic Ferrite The growth of pearlite occurs at a common transformation front with the

    E-Print Network [OSTI]

    Cambridge, University of

    2 Bainitic Ferrite The growth of pearlite occurs at a common transformation front with the austenite. The growth of the ferrite and cementite phases is coupled and their compositions are complementary since the carbon which cannot be accommodated by the ferrite is incorporated into the cementite

  20. Endophytic and canker-associated Botryosphaeriaceae occurring on non-native Eucalyptus and native Myrtaceae

    E-Print Network [OSTI]

    Endophytic and canker-associated Botryosphaeriaceae occurring on non-native Eucalyptus and native to identify the Botryosphaeriaceae species present as endophytes or associated with cankers in both introduced is a very diverse group of fungi that includes endophytes and plant pathogens of trees and plants (Alves et

  1. Movement of oxygen from the atmosphere to the mitochondria occurs via several convective and diffusive steps

    E-Print Network [OSTI]

    Bennett, Albert F.

    4111 Movement of oxygen from the atmosphere to the mitochondria occurs via several convective and diffusive steps (Weibel et al., 1981). In mammals, maximal rate of oxygen consumption (VOmax) is not limited by any one step of the oxygen cascade; rather limitations to VOmax are distributed across all steps

  2. Fuel-related accidents occur across the country at the rate of more than one per

    E-Print Network [OSTI]

    Minnesota, University of

    Fuel-related accidents occur across the country at the rate of more than one per week. Fuel exhaustion, fuel starvation, or the failure to switch tanks at the correct time caused 120 accidents in 2002, these and other problems can be avoided with proper fueling procedures. RESPONSIBILITY STARTS WITH THE AIRPORT

  3. "Climate change is sure to occur in some form." The study of climate impacts notes

    E-Print Network [OSTI]

    "Climate change is sure to occur in some form." 1 #12;The study of climate impacts notes how scientists generally agree that humans are changing the climate, and that if we continue pumping carbon we learn from past climate variations? How can we best adapt to climate change? This report attempts

  4. Xylem cavitation caused by drought and freezing stress in four co-occurring Juniperus species

    E-Print Network [OSTI]

    Jackson, Robert B.

    Xylem cavitation caused by drought and freezing stress in four co-occurring Juniperus species: 10.1111/j.1399-3054.2006.00644.x Previous studies indicate that conifers are vulnerable to cavitation cavitation, along with wood density, conduit reinforcement, trac- heid diameter, and hydraulic conductivity

  5. Natural gas monthly

    SciTech Connect (OSTI)

    NONE

    1998-01-01T23:59:59.000Z

    The Natural Gas Monthly highlights activities, events, and analyses of interest to public and private sector organizations associated with the natural gas industry. Volume and price data are presented each month for natural gas production, distribution, consumption, and interstate pipeline activities. Producer-related activities and underground storage data are also reported. From time to time, the Natural Gas Monthly features articles designed to assist readers in using and interpreting natural gas information.

  6. Midcontinent rift volcanism in the Lake Superior region: Sr, Nd, and Pb isotopic evidence for a mantle plume origin

    SciTech Connect (OSTI)

    Nicholson, S.W. (Geological Survey, Reston, VA (USA) Univ. of Minnesota, MN (USA)); Shirey, S.B. (Carnegie Institution of Washington, DC (USA))

    1990-07-10T23:59:59.000Z

    Between 1091 and 1098 Ma, most of a 15- to 20-km thickness of dominantly tholeiitic basalt erupted in the Midcontinent Rift System of the Lake Superior region, North American. The Portage Lake Volcanics in Michigan, which are the youngest MRS flood basalts, fall into distinctly high- and low-TiO{sub 2} types having different liquid lines of descent. Incompatible trace elements in both types of tholeiites are enriched compared to depleted or primitive mantle (La/Yb = 4.3-5.3; Th/Ta = 2.12-2.16; Zr/Y = 4.3-4.4), and both basalt types are isotopically indistinguishable. Sr, Nd, and Pb isotopic compositions of the Portage Lake tholeiites have {sup 87}Sr/{sup 86}Sr{sub i} {approx}0.7038, {epsilon}{sub Nd(1095 Ma)} {approx}0 {plus minus} 2, and {mu}{sub 1} {approx}8.2. Model ages with respect to a depleted mantle source (T{sub DM}) average about 1950-2100 Ma. Portage Lake rhyolits fall into two groups. Type I rhyolites have Nd and Pb isotopic characteristics ({epsilon}{sub Nd(1095 Ma)} {approx}0 to {minus}4.7; {mu}{sub 1} {approx}8.2-7.8) consistent with contamination of tholeiitic rocks by 5-10% Archean crust. The one type II rhyolite analyzed has Nd and Pb isotopic compositions ({epsilon}{sub Nd(1095 Ma)} {approx}{minus}13 to {minus}16; {mu}{sub 1} {approx}7.6-7.7) which are consistent with partial melting of Archean crust. Early Proterozoic crust was not a major contaminant of MRS rocks in the Lake Superior region. Most reported Nd and Pb isotopic compositions of MRS tholeiites from the main stage of volcanism in the Lake Superior region and of the Duluth Complex are comparable to the Nd and Pb isotopic data for Portage lake tholeiites. The isotopic enrichment of the MRS source compared to depleted mantle is striking and must have occurred at least 700 m.y. before 1100 Ma.

  7. Natural Gamma Emitters after a Selective Chemical Separation of a TENORM residue: Preliminary Results

    SciTech Connect (OSTI)

    Alves de Freitas, Antonio; Abrao, Alcidio [Centro de Quimica e do Meio Ambiente (Brazil); Godoy dos Santos, Adir Janete; Pecequilo, Brigitte Roxana Soreanu [Centro de Metrologia das Radiacoes Instituto de Pesquisas Energeticas e Nucleares Av. Prof. Lineu Prestes, 2242-Cidade Universitaria-Zip Code 05508-000 Sao Paulo-SP (Brazil)

    2008-08-07T23:59:59.000Z

    An analytical procedure was established in order to obtain selective fractions containing radium isotopes ({sup 228}Ra), thorium ({sup 232}Th), and rare earths from RETOTER (REsiduo de TOrio e TErras Raras), a solid residue rich in rare earth elements, thorium isotopes and small amount of natural uranium generated from the operation of a thorium pilot plant for purification and production of pure thorium nitrate at IPEN -CNEN/SP. The paper presents preliminary results of {sup 228}Ra, {sup 226}Ra, {sup 238}U, {sup 210}Pb, and {sup 40}K concentrations in the selective fractions and total residue determined by high-resolution gamma spectroscopy, considering radioactive equilibrium of the samples.

  8. Temperature dependence of carbon isotope fractionation in CAM plants

    SciTech Connect (OSTI)

    Deleens, E.; Treichel, I.; O'Leary, M.H.

    1985-09-01T23:59:59.000Z

    The carbon isotope fractionation associated with nocturnal malic acid synthesis in Kalanchoe daigremontiana and Bryophyllum tubiflorum was calculated from the isotopic composition of carbon-4 of malic acid, after appropriate corrections. In the lowest temperature treatment (17/sup 0/C nights, 23/sup 0/C days), the isotope fractionation for both plants is -4% per thousand (that is, malate is enriched in /sup 13/C relative to the atmosphere). For K. daigremontiana, the isotope fractionation decreases with increasing temperature, becoming approximately 0% per thousand at 27/sup 0/C/33/sup 0/C. Detailed analysis of temperature effects on the isotope fractionation indicates that stomatal aperture decreases with increasing temperature and carboxylation capacity increases. For B. tubiflorum, the temperature dependence of the isotope fractionation is smaller and is principally attributed to the normal temperature dependences of the rates of diffusion and carboxylation steps. The small change in the isotopic composition of remaining malic acid in both species which is observed during deacidification indicates that malate release, rather than decarboxylation, is rate limiting in the deacidification process. 28 references, 1 figure, 4 tables.

  9. The JET Hydrogen-Oxygen Recombination Sensor – A Safety Device for Hydrogen Isotope Processing Systems

    E-Print Network [OSTI]

    The JET Hydrogen-Oxygen Recombination Sensor – A Safety Device for Hydrogen Isotope Processing Systems

  10. Assessment of shock effects on amphibole water contents and hydrogen isotope compositions: 2. Kaersutitic

    E-Print Network [OSTI]

    Stewart, Sarah T.

    to the experimental kaersutite compositions, means the measured hydrogen isotope enrichments are likely minima. The measured (minimum) levels of hydrogen isotope enrichment are relevant to the hydrogen isotope variabilityAssessment of shock effects on amphibole water contents and hydrogen isotope compositions: 2

  11. A coupled isotope tracer method to characterize input water to lakes

    E-Print Network [OSTI]

    Edwards, Thomas W.D.

    of input waters after accounting for the effects of secondary evaporative isotopic enrichment. As shownA coupled isotope tracer method to characterize input water to lakes Yi Yi a,*, Bronwyn E. Brock in revised form 7 November 2007; accepted 9 November 2007 KEYWORDS Water isotope tracers; Isotope hydrology

  12. ORIGINAL PAPER Crystal scale anatomy of a dying supervolcano: an isotope

    E-Print Network [OSTI]

    Bindeman, Ilya N.

    determined by ion microprobe, and sanidine Pb isotope ratios determined by laser ablation, to investigate

  13. Glaciation, aridification, and carbon sequestration in the Permo-Carboniferous: The isotopic record from low latitudes

    E-Print Network [OSTI]

    Grossman, Ethan L.

    Glaciation, aridification, and carbon sequestration in the Permo-Carboniferous: The isotopic record and carbon sequestration in the Late Paleozoic, we have compiled new and published oxygen and carbon isotopic Carboniferous Stable isotopes Carbon cycling Brachiopods To evaluate the isotopic record of climate change

  14. Scoping assessment on medical isotope production at the Fast Flux Test Facility

    SciTech Connect (OSTI)

    Scott, S.W.

    1997-08-29T23:59:59.000Z

    The Scoping Assessment addresses the need for medical isotope production and the capability of the Fast Flux Test Facility to provide such isotopes. Included in the discussion are types of isotopes used in radiopharmaceuticals, which types of cancers are targets, and in what way isotopes provide treatment and/or pain relief for patients.

  15. The influence of kinetics on the oxygen isotope composition of calcium carbonate

    E-Print Network [OSTI]

    Watkins, Jim

    The influence of kinetics on the oxygen isotope composition of calcium carbonate James M. Watkins a and calcium carbonate. Although oxygen isotope separation is expected on theoretical grounds, the temperature on equilibrium fractionation of oxygen isotopes between calcium carbonate and water. Equili- brium oxygen isotope

  16. Standard practice for the ion exchange separation of uranium and plutonium prior to isotopic analysis

    E-Print Network [OSTI]

    American Society for Testing and Materials. Philadelphia

    2008-01-01T23:59:59.000Z

    Standard practice for the ion exchange separation of uranium and plutonium prior to isotopic analysis

  17. Preservation of seawater Sr and Nd isotopes in fossil sh teeth: bad news and good news

    E-Print Network [OSTI]

    Martin, Ellen

    system, our Nd concentration data, combined with published isotopic and rare earth element data, suggest on the global seawater Sr isotope curve. For Sites 1090, 757, and 807 Sr isotopic values of the pore fluids Nd isotopic compositions from the time of deposition. Ã? 2004 Elsevier B.V. All rights reserved

  18. Giant Quadrupole-Resonance in Ni Isotopes

    E-Print Network [OSTI]

    Youngblood, David H.; Lui, YW; Garg, U.; Peterson, R. J.

    1992-01-01T23:59:59.000Z

    PHYSICAL REVIEW C VOLUME 45, NUMBER 5 MAY 1992 Giant quadrupole resonance in Ni isotopes D. H. Youngblood and Y.-%. Lui Texas A&M UniUersity, College Station, Texas 77843 U. Garg University of Notre Dame, South Bend, Indiana 46556 R. J...R )' 0.53 0.68 0.69 0.78 E2 EWSR (%) 58+12 76+14 78+14 90+16 Cp 0.80+0.04 0.84+0.04 0.82+0. 12 1.05+0. 10 2174 YOUNGBLOOD, LUI, GARG, AND PETERSON 45 1000 100 60Ni(n, n') E = 129 MeV 1 000 100 58Ni(n, n') 10 10 100 z' 1000 64Ni...

  19. Cryomodule Design for the Rare Isotope Accelerator

    SciTech Connect (OSTI)

    Grimm, Terry; Hartung, Walter; Johnson, M.; York, Richard; Kneisel, Peter; Turlington, Larry

    2003-05-01T23:59:59.000Z

    The Rare Isotope Accelerator (RIA) driver linac will produce >400 MeV/u proton through uranium beams using many types of superconducting accelerating cavities such as quarter wave, spoke, and elliptical cavities. A cryomodule design that can accommodate all of the superconducting cavity and magnet types is presented. Alignment of the cold mass uses a titanium rail system, which minimizes cryomodule size, and decreases both the tunnel cross-section and length. The titanium rail is supported from the top vacuum plate by an adjustable trilink, which is similar to existing Michigan State University magnet technology. A prototype cryomodule is under construction for testing 805 MHz, v/c=0.47, sixcell niobium cavities in realistic operating conditions. Details of the design and progress to date are presented.

  20. Shell model description of Ge isotopes

    E-Print Network [OSTI]

    J. G. Hirsch; P. C. Srivastava

    2012-04-12T23:59:59.000Z

    A shell model study of the low energy region of the spectra in Ge isotopes for $38\\leq N\\leq 50$ is presented, analyzing the excitation energies, quadrupole moments, $B(E2)$ values and occupation numbers. The theoretical results have been compared with the available experimental data. The shell model calculations have been performed employing three different effective interactions and valence spaces.We have used two effective shell model interactions, JUN45 and jj44b, for the valence space $f_{5/2} \\, p \\,g_{9/2}$ without truncation. To include the proton subshell $f_{7/2}$ in valence space we have employed the $fpg$ effective interaction due to Sorlin {\\it et al.}, with $^{48}$Ca as a core and a truncation in the number of excited particles.

  1. Compact hydrogen/helium isotope mass spectrometer

    DOE Patents [OSTI]

    Funsten, Herbert O. (Los Alamos, NM); McComas, David J. (Los Alamos, NM); Scime, Earl E. (Morgantown, WV)

    1996-01-01T23:59:59.000Z

    The compact hydrogen and helium isotope mass spectrometer of the present invention combines low mass-resolution ion mass spectrometry and beam-foil interaction technology to unambiguously detect and quantify deuterium (D), tritium (T), hydrogen molecule (H.sub.2, HD, D.sub.2, HT, DT, and T.sub.2), .sup.3 He, and .sup.4 He concentrations and concentration variations. The spectrometer provides real-time, high sensitivity, and high accuracy measurements. Currently, no fieldable D or molecular speciation detectors exist. Furthermore, the present spectrometer has a significant advantage over traditional T detectors: no confusion of the measurements by other beta-emitters, and complete separation of atomic and molecular species of equivalent atomic mass (e.g., HD and .sup.3 He).

  2. Photonuclear Reaction Cross Sections for Gallium Isotopes

    E-Print Network [OSTI]

    Serkan Akkoyun; Tuncay Bayram

    2014-09-08T23:59:59.000Z

    The photon induced reactions which are named as photonuclear reactions have a great importance in many field of nuclear, radiation physics and related fields. Since we have planned to perform photonuclear reaction on gallium target with bremmstrahlung photons from clinical linear accelerator in the future, the cross-sections of neutron (photo-neutron ({\\gamma},xn)) and proton (photo-proton ({\\gamma},xn)) productions after photon activation have been calculated by using TALYS 1.2 computer code in this study. The target nucleus has been considered gallium which has two stable isotopes, 69Ga and 71Ga. According to the results, we have seen that the calculations are in harmony in the limited literature values. Furthermore, the pre-equilibrium and compound process contributions to the total cross-section have been investigated.

  3. Chemical and isotopic determination from complex spectra

    SciTech Connect (OSTI)

    Zardecki, A.; Strittmatter, R.B.

    1995-07-01T23:59:59.000Z

    Challenges for proliferation detection include remote, high- sensitivity detection of chemical effluents from suspect facilities and enhanced detection sensitivity for nuclear material. Both the identification of chemical effluents with lidar and enhanced nuclear material detection from radiation sensors involve determining constituents from complex spectra. In this paper, we extend techniques used to analyze time series to the analysis of spectral data. Pattern identification methods are applied to spectral data for domains where standard matrix inversion may not be suitable because of detection statistics. We use a feed-forward, back-propagation neural network in which the nodes of the input layer are fed with the observed spectral data. The nodes of the output layer contain the identification and concentration of the isotope or chemical effluent the sensor is to identify. We will discuss the neural network architecture, together with preliminary results obtained from the training process.

  4. How are greenhouse gases related to agriculture? Greenhouse gases such as carbon dioxide occur

    E-Print Network [OSTI]

    levels are causing Earth's average global temperature to rise. Consequently, we experience changes States. How will climate change affect Michigan field crop agriculture? Global warming is likely to bring naturally in the atmosphere and keep the Earth warm, allowing us to survive on Earth. Over the last 200

  5. Isotope and Nuclear Chemistry Division annual report, FY 1983

    SciTech Connect (OSTI)

    Heiken, J.H.; Lindberg, H.A. (eds.)

    1984-05-01T23:59:59.000Z

    This report describes progress in the major research and development programs carried out in FY 1983 by the Isotope and Nuclear Chemistry Division. It covers radiochemical diagnostics of weapons tests; weapons radiochemical diagnostics research and development; other unclassified weapons research; stable and radioactive isotope production, separation, and applications (including biomedical applications); element and isotope transport and fixation; actinide and transition metal chemistry; structural chemistry, spectroscopy, and applications; nuclear structure and reactions; irradiation facilities; advanced analytical techniques; development and applications; atmospheric chemistry and transport; and earth and planetary processes.

  6. Isotopic mass-dependence of noble gas diffusion coefficients inwater

    SciTech Connect (OSTI)

    Bourg, I.C.; Sposito, G.

    2007-06-25T23:59:59.000Z

    Noble gas isotopes are used extensively as tracers inhydrologic and paleoclimatic studies. These applications requireknowledge of the isotopic mass (m) dependence of noble gas diffusioncoefficients in water (D), which has not been measured but is estimatedusing experimental D-values for the major isotopes along with an untestedrelationship from kinetic theory, D prop m-0.5. We applied moleculardynamics methods to determine the mass dependence of D for four noblegases at 298 K, finding that D prop m-beta with beta<0.2, whichrefutes the kinetic theory model underlying all currentapplications.

  7. Impact of source terms on distances to which reactor accident consequences occur

    SciTech Connect (OSTI)

    Ostmeyer, R.M.

    1982-01-01T23:59:59.000Z

    Estimates of the distances over which reactor accident consequences might occur are important for development of siting criteria and for emergency response planning. This paper summarizes the results of a series of CRAC2 calculations performed to estimate these distances. Because of the current controversy concerning the magnitude of source terms for severe accidents, the impact of source term reductions upon distance estimates is also examined.

  8. Fluctuations in Species-Level Protein Expression Occur during Element and Nutrient Cycling in the Subsurface

    SciTech Connect (OSTI)

    Wilkins, Michael J.; Wrighton, Kelly C.; Nicora, Carrie D.; Williams, Kenneth H.; McCue, Lee Ann; Handley, Kim M.; Miller, C. S.; Giloteaux, L.; Montgomery, A. P.; Lovley, Derek R.; Banfield, Jillian F.; Long, Philip E.; Lipton, Mary S.

    2013-03-05T23:59:59.000Z

    While microbial activities in environmental systems play a key role in the utilization and cycling of essential elements and compounds, microbial activity and growth frequently fluctuates in response to environmental stimuli and perturbations. To investigate these fluctuations within a saturated aquifer system, we monitored a carbon-stimulated in situ Geobacter population while iron reduction was occurring, using 16S rRNA abundances and high-resolution tandem mass spectrometry proteome measurements. Following carbon amendment, 16S rRNA analysis of temporally separated samples revealed the rapid enrichment of Geobacter-like environmental strains with strong similarity to G. bemidjiensis. Tandem mass spectrometry proteomics measurements suggest high carbon flux through Geobacter respiratory pathways, and the synthesis of anapleurotic four carbon compounds from acetyl-CoA via pyruvate ferredoxin oxidoreductase activity. Across a 40-day period where Fe(III) reduction was occurring, fluctuations in protein expression reflected changes in anabolic versus catabolic reactions, with increased levels of biosynthesis occurring soon after acetate arrival in the aquifer. In addition, localized shifts in nutrient limitation were inferred based on expression of nitrogenase enzymes and phosphate uptake proteins. These temporal data offer the first example of differing microbial protein expression associated with changing geochemical conditions in a subsurface environment.

  9. Measurement of positional isotope exchange rates in enzyme catalyzed reactions by fast atom bombardment mass spectrometry

    E-Print Network [OSTI]

    Hilscher, Larry Wayne

    1985-01-01T23:59:59.000Z

    A Synthetas e Positional Isotope Exchange with Argininosuccinate Synthetas e Fast Atom Bombardment Mass Spectrometry 31 P Nuclear Magnetic Resonance RESULTS Page 16 17 19 20 21 21 22 23 Positional Isotope Exchange with Acetyl CoA Synthetase... Positional Isotope Exchange with Argininosuccinate Synth etas e DISCUSSICN 23 27 30 Positional Isotope Exchange with Acetyl CoA Synthetase . Pcsitional Isotope Exchange with Argininosuccinate Synthetase RFZERENCES 30 VITA LIST OF SCHEMES Page...

  10. Natural gas annual 1996

    SciTech Connect (OSTI)

    NONE

    1997-09-01T23:59:59.000Z

    This document provides information on the supply and disposition of natural gas to a wide audience. The 1996 data are presented in a sequence that follows natural gas from it`s production to it`s end use.

  11. Nature/Culture/Seawater

    E-Print Network [OSTI]

    Helmreich, Stefan

    This essay considers seawater as a substance and symbol in anthropological and social theory. Seawater has occupied an ambiguous place with respect to anthropological categories of nature and culture. Seawater as nature ...

  12. Supervisory Natural Gas Analyst

    Broader source: Energy.gov [DOE]

    The Department of Energys Office of Fossil Energy, Office of Oil and Natural Gas, Office of Oil and Gas Global Security and Supply (FE) is responsible for regulating natural gas imports and exports...

  13. Natural gas annual 1995

    SciTech Connect (OSTI)

    NONE

    1996-11-01T23:59:59.000Z

    The Natural Gas Annual provides information on the supply and disposition of natural gas to a wide audience including industry, consumers, Federal and State agencies, and educational institutions. The 1995 data are presented in a sequence that follows natural gas (including supplemental supplies) from its production to its end use. This is followed by tables summarizing natural gas supply and disposition from 1991 to 1995 for each Census Division and each State. Annual historical data are shown at the national level.

  14. Natural Resources Research Institute

    E-Print Network [OSTI]

    Netoff, Theoden

    /Loll ThermoWood Hybrid Poplars Peat A boost for the peat industry Value in Minnesota peat deposits Natural che

  15. Natural gas annual 1994

    SciTech Connect (OSTI)

    NONE

    1995-11-17T23:59:59.000Z

    The Natural Gas Annual provides information on the supply and disposition of natural gas to a wide audience including industry, consumers, Federal and State agencies, and educational institutions. The 1994 data are presented in a sequence that follows natural gas (including supplemental supplies) from its production to its end use. This is followed by tables summarizing natural gas supply and disposition from 1990 to 1994 for each Census Division and each State. Annual historical data are shown at the national level.

  16. FAST-RESPONSE ISOTOPIC ALPHA CONTINUOUS AIR MONITOR (CAM)

    SciTech Connect (OSTI)

    Keith D. Patch

    2000-04-28T23:59:59.000Z

    The objective of this effort is to develop and test a novel Continuous Air Monitor (CAM) instrument for monitoring alpha-emitting radionuclides, using a technology that can be applied to Continuous Emission Monitoring (CEM) of thermal treatment system off gas streams. The CAM instrument will have very high alpha spectral resolution and provide real-time, on-line monitoring suitable for alerting workers of high concentrations of alpha-emitting radionuclides in the ambient air and for improved control of decontamination, dismantlement, and air emission control equipment. Base Phase I involves the design, development, and preliminary testing of a laboratory-scale instrument. Testing will initially be conducted using naturally-occurring radon progeny in ambient air. In the Optional Phase II, the Base Phase I instrument will be critically evaluated at the Lovelace Respiratory Research Institute (LRRI) with characterized plutonium aerosols; then an improved instrument will be built and field-tested at a suitable DOE site.

  17. The marine geochemistry of iron and iron isotopes

    E-Print Network [OSTI]

    Bergquist, Bridget A., 1973-

    2004-01-01T23:59:59.000Z

    This thesis addressed questions about the Fe cycle by measuring detailed profiles and transects of Fe species in the ocean and also by exploring the use of a new tracer of Fe, Fe isotopic fractionation. In the subtropical ...

  18. acid selective isotope: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Bchner; Grard Trnec; Jacques Vigu 2006-11-17 20 LACK OF CORRELATION BETWEEN GOUT AND THE INCORPORATION OF ISOTOPIC FORMATE INTO URIC ACID CiteSeer Summary: Certain...

  19. Recovery of enriched stable isotopes in radionuclide production

    SciTech Connect (OSTI)

    Razbash, A.A.; Sevastyanov, Yu.G.; Polyakov, O.N.; Krasnov, N.N.; Konyakhin, N.A.; Tolstouhov, Yu.V.; Maklachkov, A.G. [Cyclotron Co. Ltd., Obninsk (Russian Federation)

    1994-12-31T23:59:59.000Z

    The wide application of radionuclides in different fields of science and industry demanded an increase of their production. One of the ways to increase the radionuclide production on present cyclotrons is the use of the targets from enriched stable isotopes. This allows one to raise the productivity in some cases by two or more times and to increase radionuclidic purity. It should be noted, however, that enriched stable isotopes are very expensive. Therefore it is advisable to use such raw materials more than once. In the last ten years, The authors have used stable isotopes extensively for making of targets. Zinc-67 and zinc-68, cadmium-111 and cadmium-112, nickel-58, silver-109, thallium-203 have been employed for the production of gallium-67, indium-111, cobalt-57, cadmium-109 and thallium-201, respectively. The technique for the recovery of enriched stable isotopes has been developed. In this report the schemes of the recovering processes are presented.

  20. Isotopic Effect on Ion Mobility and Separation of Isotopomers...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Effect on Ion Mobility and Separation of Isotopomers by High-Field Ion Mobility Spectrometry . Isotopic Effect on Ion Mobility and Separation of Isotopomers by High-Field Ion...

  1. Evidence of magnetic isotope effects during thermochemical sulfate reduction

    E-Print Network [OSTI]

    Oduro, Harry D.

    Thermochemical sulfate reduction experiments with simple amino acid and dilute concentrations of sulfate reveal significant degrees of mass-independent sulfur isotope fractionation. Enrichments of up to 13‰ for [superscript ...

  2. Global isotopic signatures of oceanic island basalts / by

    E-Print Network [OSTI]

    Oschmann, Lynn A

    1991-01-01T23:59:59.000Z

    Sr, Nd and Pb isotopic analyses of 477 samples representing 30 islands or island groups, 3 seamounts or seamount chains, 2 oceanic ridges and 1 oceanic plateau [for a total of 36 geographic features] are compiled to form ...

  3. The Nonactinide Isotope and Sealed Sources Management Group

    SciTech Connect (OSTI)

    Low, J. L.; Polansky, G. F.; Parks, D. L.

    2002-02-27T23:59:59.000Z

    The Nonactinide Isotope and Sealed Sources Management Group (NISSMG) is sponsored by the Department of Energy (DOE) Office of Environmental Management and managed by Albuquerque Operations Office (DOE/AL) to serve as a complex-wide resource for the management of DOE-owned Nonactinide Isotope and Sealed Source (NISS) materials. NISS materials are defined as including: any isotope in sealed sources or standards; and isotopes, regardless of form, with atomic number less than 90. The NISSMG assists DOE sites with the storage, reuse, disposition, transportation, and processing of these materials. The NISSMG has focused its efforts to date at DOE closure sites due to the immediacy of their problems. Recently, these efforts were broadened to include closure facilities at non-closure sites. Eventually, the NISSMG plans to make its resources available to all DOE sites. This paper documents the lessons learned in managing NISS materials at DOE sites to date.

  4. argon isotope analysis: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1.1 This is a quantitative test method applicable to determining the mass percent of uranium isotopes in uranium hexafluoride (UF6) samples with 235U concentrations between 0.1...

  5. Reactor production of sup 252 Cf and transcurium isotopes

    SciTech Connect (OSTI)

    Alexander, C.W.; Halperin, J.; Walker, R.L.; Bigelow, J.E.

    1990-01-01T23:59:59.000Z

    Berkelium, californium, einsteinium, and fermium are currently produced in the High Flux Isotope Reactor (HFIR) and recovered in the Radiochemical Engineering Development Center (REDC) at the Oak Ridge National Laboratory (ORNL). All the isotopes are used for research. In addition, {sup 252}Cf, {sup 253}Es, and {sup 255}Fm have been considered or are used for industrial or medical applications. ORNL is the sole producer of these transcurium isotopes in the western world. A wide range of actinide samples were irradiated in special test assemblies at the Fast Flux Test Facility (FFTF) at Hanford, Washington. The purpose of the experiments was to evaluate the usefulness of the two-group flux model for transmutations in the special assemblies with an eventual goal of determining the feasibility of producing macro amounts of transcurium isotopes in the FFTF. Preliminary results from the production of {sup 254g}Es from {sup 252}Cf will be discussed. 14 refs., 5 tabs.

  6. Helium Isotopes in Geothermal and Volcanic Gases of the Western...

    Open Energy Info (EERE)

    Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: Helium Isotopes in Geothermal and Volcanic Gases of the Western United States, II. Long...

  7. Helium Isotopes In Geothermal And Volcanic Gases Of The Western...

    Open Energy Info (EERE)

    Helium Isotopes In Geothermal And Volcanic Gases Of The Western United States, I, Regional Variability And Magmatic Origin Jump to: navigation, search OpenEI Reference LibraryAdd...

  8. Isotopic Analysis- Gas At Long Valley Caldera Geothermal Area...

    Open Energy Info (EERE)

    in a fumarole on the north side of Mammoth Mountain from 1989-1990, during which time helium isotope values increased from 3.6 x Ra to 5.5 x Ra from July to October 1989, and then...

  9. Regional And Local Trends In Helium Isotopes, Basin And Range...

    Open Energy Info (EERE)

    And Local Trends In Helium Isotopes, Basin And Range Province, Western North America- Evidence For Deep Permeable Pathways Jump to: navigation, search OpenEI Reference LibraryAdd...

  10. Isotopic Analysis- Gas At Long Valley Caldera Geothermal Area...

    Open Energy Info (EERE)

    in Menlo Park, CA. Gas samples collected in the copper tubes were analyzed for their helium isotope contents by B.M. Kennedy at the University of California at Berkeley, CA....

  11. Isotopic studies of the environmental chemistry of lead 

    E-Print Network [OSTI]

    Sugden, Carol Louise

    Lead emitted into the environment, primarily from the combustion of leaded petrol and industrial activities, such as metal smelting and coal burning, retains the isotopic signature of the ores from which it is derived. Accordingly, it is possible...

  12. FY09 PROGRESS: MULTI-ISOTOPE PROCESS (MIP) MONITOR

    SciTech Connect (OSTI)

    Schwantes, Jon M.; Orton, Christopher R.; Fraga, Carlos G.; Christensen, Richard; Laspe, Amy R.; Ward, Rebecca M.

    2009-10-18T23:59:59.000Z

    Model and experimental estimates of the Multi-Isotope Process Monitor performance for determining burnup after dissolution and acid concentration during solvent extraction steps during reprocessing of spent nuclear fuel are presented.

  13. Isotope Geochemistry of Thermal and Nonthermal Waters in the...

    Open Energy Info (EERE)

    geothermal fluids display a positive oxygen 18 shift of not less than 2 because of rock-water isotopic exchange at 220-300C. The Valles geothermal system is capped by a...

  14. Chemical and light-stable isotope characteristics of waters from...

    Open Energy Info (EERE)

    light-stable isotope characteristics of waters from the raft river geothermal area and environs, Cassia County, Idaho, Box Elder county, Utah Jump to: navigation, search OpenEI...

  15. RESOLUTION OF URANIUM ISOTOPES WITH KINETIC PHOSPHORESCENCE ANALYSIS

    SciTech Connect (OSTI)

    Miley, Sarah M.; Hylden, Anne T.; Friese, Judah I.

    2013-04-01T23:59:59.000Z

    This study was conducted to test the ability of the Chemchek™ Kinetic Phosphorescence Analyzer Model KPA-11 with an auto-sampler to resolve the difference in phosphorescent decay rates of several different uranium isotopes, and therefore identify the uranium isotope ratios present in a sample. Kinetic phosphorescence analysis (KPA) is a technique that provides rapid, accurate, and precise determination of uranium concentration in aqueous solutions. Utilizing a pulsed-laser source to excite an aqueous solution of uranium, this technique measures the phosphorescent emission intensity over time to determine the phosphorescence decay profile. The phosphorescence intensity at the onset of decay is proportional to the uranium concentration in the sample. Calibration with uranium standards results in the accurate determination of actual concentration of the sample. Different isotopes of uranium, however, have unique properties which should result in different phosphorescence decay rates seen via KPA. Results show that a KPA is capable of resolving uranium isotopes.

  16. New isotope measurement could alter history of early solar system...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    from star dust several billion years ago. Some of this dust was formed in giant supernovae explosions which supplied most of our heavy elements. One of these is the isotope...

  17. Process for exchanging hydrogen isotopes between gaseous hydrogen and water

    DOE Patents [OSTI]

    Hindin, Saul G. (Mendham, NJ); Roberts, George W. (Westfield, NJ)

    1980-08-12T23:59:59.000Z

    A process for exchanging isotopes of hydrogen, particularly tritium, between gaseous hydrogen and water is provided whereby gaseous hydrogen depeleted in tritium and liquid or gaseous water containing tritium are reacted in the presence of a metallic catalyst.

  18. Surface-cycling of rhenium and its isotopes

    E-Print Network [OSTI]

    Miller, Christian Alexander

    2009-01-01T23:59:59.000Z

    The application of elemental and isotopic metal palaeoredox tracers to the geologic past rests on an understanding of modern metal cycles. This study reevaluates the surface-cycling of Mo and Re in near-surface reservoirs. ...

  19. abundance isotopic: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    24 Abundances and Isotope Ratios in the Magellanic Clouds: The Star Forming Environment of N113 Astrophysics (arXiv) Summary: With the goal of deriving the physical and...

  20. Textural, chemical and isotopic insights into the nature and behaviour of metamorphic monazite

    E-Print Network [OSTI]

    Gibson, Dan

    thermal ionisation mass spectrometry (ID-TIMS) U­Pb age data commonly recorded from a single rock sample from the Himalaya of Pakistan are examined. Each sample exhibits an age dispersion of between 1; Zoning; Metamorphism; Laser ablation; Plasma-source mass spectrometry 1. Introductio

  1. Isotope Production at the Hanford Site in Richland, Washington

    SciTech Connect (OSTI)

    Ammoniums

    1999-06-01T23:59:59.000Z

    This report was prepared in response to a request from the Nuclear Energy Research Advisory Committee (NERAC) subcommittee on ''Long-Term Isotope Research and Production Plans.'' The NERAC subcommittee has asked for a reply to a number of questions regarding (1) ''How well does the Department of Energy (DOE) infrastructure sme the need for commercial and medical isotopes?'' and (2) ''What should be the long-term role of the federal government in providing commercial and medical isotopes?' Our report addresses the questions raised by the NERAC subcommittee, and especially the 10 issues that were raised under the first of the above questions (see Appendix). These issues are related to the isotope products offered by the DOE Isotope Production Sites, the capabilities and condition of the facilities used to produce these products, the management of the isotope production programs at DOE laboratories, and the customer service record of the DOE Isotope Production sites. An important component of our report is a description of the Fast Flux Test Facility (FFTF) reactor at the Hbford Site and the future plans for its utilization as a source of radioisotopes needed by nuclear medicine physicians, by researchers, and by customers in the commercial sector. In response to the second question raised by the NERAC subcommittee, it is our firm belief that the supply of isotopes provided by DOE for medical, industrial, and research applications must be strengthened in the near future. Many of the radioisotopes currently used for medical diagnosis and therapy of cancer and other diseases are imported from Canada, Europe, and Asia. This situation places the control of isotope availability, quality, and pricing in the hands of non-U.S. suppliers. It is our opinion that the needs of the U.S. customers for isotopes and isotope products are not being adequately served, and that the DOE infrastructure and facilities devoted to the supply of these products must be improved This perception forms one of the fundamental bases for our proposal that the FFTF, which is currently in a standby condition, be reactivated to supply nuclear services and products such as radioisotopes needed by the U.S. medical, industrial, and research communities.

  2. Isotopic Anomalies in CP Stars: Helium, Mercury, Platinum, and Calcium

    E-Print Network [OSTI]

    C. R. Cowley; S. Hubrig; F. Castelli

    2007-11-15T23:59:59.000Z

    We review the classical observational results for isotopic abundance variations for several elements in CP stars. We concentrate on the "newest" anomaly, in calcium. The cosmically very rare isotope, Ca-48 can rival and even dominate the more common, alpha nuclide, Ca-40. Relevant examples are found in the hot, non-magnetic HgMn stars, and the field horizontal-branch star, Feige 86. The calcium anomaly is also present in cool, magnetic stars, including the notorious HD 101065, Przybylski's star.

  3. Isotopic dilution and solvent effect studies using raman difference spectroscopy

    E-Print Network [OSTI]

    Johnson, Andrew Norman

    1984-01-01T23:59:59.000Z

    ISOTOPIC DILUTION AND SOLVENT EFFECT STUDIES USING RAMAN DIFFERENCE SPECTROSCOPY A Thesis by ANDREW NORMAN JOHNSON Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER... OF SCIENCE August 1984 Major Subject: Chemistry ISOTOPIC DILUTION AND SOLVENT EFFECT STUDIES USING RAMAN DIFFERENCE SPECTROSCOPY A Thesis by ANDREW NORMAN JOHNSON Approved as to style and content by: Jaan Laane (Chairman of Committee) J. . Bevan...

  4. Stable isotopes in late Pennsylvanian brachiopods: stratigraphic and paleoenvironmental implications

    E-Print Network [OSTI]

    Zhang, Chuanlun

    1989-01-01T23:59:59.000Z

    STABLE ISOTOPES IN LATE PENNSYLVANIAN BRACHIOPODS: STRATIGRAPHIC AND PALEOENVIRONMENTAL IMPLICATIONS A Thesis by CHUANLUN ZHANG Submitted to the Office of Graduate Studies of Texas A%M University in partial fulfillment of the requirements... for the degree of MASTER OF SCIENCE December 1989 Major Subject: Geology Stable Isotopes in Late Pennsylvanian Brachiopods: Stratigraphic and Paleoenvironmental Implications A Thesis by CHUANLUN ZHANG Approved as to the style and content by: Ethan L...

  5. Separation of the isotopes of boron by chemical exchange reactions

    DOE Patents [OSTI]

    McCandless, F.P.; Herbst, R.S.

    1995-05-30T23:59:59.000Z

    The isotopes of boron, {sup 10}B and {sup 11}B, are separated by means of a gas-liquid chemical exchange reaction involving the isotopic equilibrium between gaseous BF{sub 3} and a liquid BF{sub 3} donor molecular addition complex formed between BF{sub 3} gas and a donor chosen from the group consisting of: nitromethane, acetone, methyl isobutyl ketone, or diisobutyl ketone. 1 Fig.

  6. Nuclear Resonance Fluorescence and Isotopic Mapping of Containers

    SciTech Connect (OSTI)

    Johnson, M S; McNabb, D P

    2008-08-08T23:59:59.000Z

    National security programs have expressed interest in developing systems to isotopically map shipping containers, fuel assemblies, and waste barrels for various materials including special nuclear material (SNM). Current radiographic systems offer little more than an ambiguous density silhouette of a container's contents. In this paper we will present a system being developed at LLNL to isotopically map containers using the nuclear resonance fluorescence (NRF) method. Recent experimental measurements on NRF strengths in SNM are discussed.

  7. An evaluation of the mixing and oxygen transfer occurring in a deep aeration basin

    E-Print Network [OSTI]

    Andrews, Donald Craig

    1981-01-01T23:59:59.000Z

    -ci~cuiting. JJ 0 0 cl aa 0 al la all M Li 0 0 0 M Y :tl 0 C g IJ Ul 0i 0 aa M aa Ql C Vl Cl 0 0 0 0 0 0 C2 M 18 However, the design of the basin must be considered. In settling basins and some aer ati. on basins, this is the case... aeration of tap water, (b) steady state aeration of tap water, (c) steady state oxidation of sulf ite solution, and (d) steady state aer ation of activated sludge. Today most aerator testing either occurs with non-steady state ae. ation of tap water...

  8. Proton magnetic resonance studies of the chemical shifts occurring in propionic acid-dioxane solutions

    E-Print Network [OSTI]

    Oldham, William J. Bryan

    1958-01-01T23:59:59.000Z

    , Nxperimentaliy Gutowsky 1'ound S to be a linear function of Pl, Howevers Bhar end Lindstrom(I~ found deviations from the linear de- pendence g1ven in Gutowsky's report, These deviat1ons occur in the range of 5Q of acid by volume. The shift does not decrease... lines are displayed as the f10IlL is swept through 'the resonant value Since it was desire4 to find if the cheaical shift is tesperature de pendent~ 1t vas decided to neasure the shift at two tenperatures, One of those vas to be roc' tenperatuze...

  9. Proton magnetic resonance studies of the chemical shifts occurring in propionic acid-dioxane solutions 

    E-Print Network [OSTI]

    Oldham, William J. Bryan

    1958-01-01T23:59:59.000Z

    , Nxperimentaliy Gutowsky 1'ound S to be a linear function of Pl, Howevers Bhar end Lindstrom(I~ found deviations from the linear de- pendence g1ven in Gutowsky's report, These deviat1ons occur in the range of 5Q of acid by volume. The shift does not decrease... lines are displayed as the f10IlL is swept through 'the resonant value Since it was desire4 to find if the cheaical shift is tesperature de pendent~ 1t vas decided to neasure the shift at two tenperatures, One of those vas to be roc' tenperatuze...

  10. D/H isotope ratios of kerogen, bitumen, oil, and water in hydrous pyrolysis of source rocks containing kerogen types I, II, IIS, and III

    SciTech Connect (OSTI)

    Schimmelmann, A.; Lewan, M.D.; Wintsch, R.P.

    1999-11-01T23:59:59.000Z

    Immature source rock chips containing different types of kerogen (I,II,IIS,III) were artificially matured in isotopically distinct waters by hydrous pyrolysis and by pyrolysis in supercritical water. Converging isotopic trends of inorganic (water) and organic (kerogen, bitumen, oil) hydrogen with increasing time and temperature document that water-derived hydrogen is added to or exchanged with organic hydrogen, or both, during chemical reactions that take place during thermal maturation. Isotopic mass-balance calculations show that, depending on temperature (310--381 C), time (12--144h), and source rock type, between ca. 45 and 79% of carbon-bound hydrogen in kerogen is derived from water. Estimates for bitumen and oil range slightly lower, with oil-hydrogen being least affected by water-derived hydrogen. Comparative hydrous pyrolyses of immature source rocks at 330 C for 72h show that hydrogen in kerogen, bitumen, and expelled oil/wax ranks from most to least isotopically influenced by water-derived hydrogen in the order IIS {gt} II {approximately} III {gt} I. Pyrolysis of source rock containing type II kerogen in supercritical water at 381 C for 12 h yields isotopic results that are similar to those from hydrous pyrolysis at 250 C for 72 h or 330 C for 133 h. Bulk hydrogen in kerogen contains several percent of isotopically labile hydrogen that exchanges fast and reversibly with hydrogen in water vapor at 115 C. The isotopic equilibration of labile hydrogen in kerogen with isotopic standard water vapors significantly reduces the analytical uncertainty of D/H ratios when compared with simple D/H determination of bulk hydrogen in kerogen. If extrapolation of their results from hydrous pyrolysis is permitted to natural thermal maturation at lower temperatures, the authors suggest that organic D/H ratios of fossil fuels in contact with formation water are typically altered during chemical reactions, but that D/H ratios of generated hydrocarbons are subsequently little or not affected by exchange with water hydrogen at typical reservoir conditions over geologic time. It will be difficult to utilize D/H ratios of thermally mature bulk or fractions or organic matter to quantitatively reconstruct isotopic aspects of paleoclimate and paleoenvironment. Hope resides in compound-specific D/H ratio of thermally stable, extractable biomarkers (molecular fossils) that are less susceptible to hydrogen exchange with water-derived hydrogen.

  11. Proton radii of Be, B, and C isotopes

    E-Print Network [OSTI]

    Yoshiko Kanada-En'yo

    2014-11-04T23:59:59.000Z

    We investigate the neutron number $(N)$ dependence of root mean square radii of point proton distribution (proton radii) of Be, B, and C isotopes with the theoretical method of variation after spin-parity projection in the framework of antisymmetrized molecular dynamics (AMD). The proton radii in Be and B isotopes changes rapidly as $N$ increases, reflecting the cluster structure change along the isotope chains, whereas, those in C isotopes show a weak $N$ dependence because of the stable proton structure in nuclei with $Z=6$. In neutron-rich Be and B isotopes, the proton radii are remarkably increased by the enhancement of the two-center cluster structure in the prolately deformed neutron structure. We compare the $N$ dependence of the calculated proton radii with the experimental ones reduced from the charge radii determined by isotope shift and those deduced from the charge changing interaction cross section. It is found that the $N$ dependence of proton radii can be a probe to clarify enhancement and weakening of cluster structures.

  12. EIA - Natural Gas Pipeline Network - Largest Natural Gas Pipeline...

    U.S. Energy Information Administration (EIA) Indexed Site

    Interstate Pipelines Table About U.S. Natural Gas Pipelines - Transporting Natural Gas based on data through 20072008 with selected updates Thirty Largest U.S. Interstate Natural...

  13. Lithium isotopic systematics of A-type granites and their mafic enclaves: Further constraints on the Li isotopic composition of the continental crust

    E-Print Network [OSTI]

    Mcdonough, William F.

    Lithium isotopic systematics of A-type granites and their mafic enclaves: Further constraints form 6 February 2009 Accepted 15 February 2009 Editor: D.B. Dingwell Keywords: Lithium isotopes A-type granite Mafic enclave Continental crust Lithium concentrations and isotopic compositions of 39 A

  14. Extraction of gadolinium from high flux isotope reactor control plates. [Alternative method

    SciTech Connect (OSTI)

    Kohring, M.W.

    1987-04-01T23:59:59.000Z

    Gadolinium-153 is an important radioisotope used in the diagnosis of various bone disorders. Recent medical and technical developments in the detection and cure of osteoporosis, a bone disease affecting an estimated 50 million people, have greatly increased the demand for this isotope. The Oak Ridge National Laboratory (ORNL) has produced /sup 153/Gd since 1980 primarily through the irradiation of a natural europium-oxide powder followed by the chemical separation of the gadolinium fraction from the europium material. Due to the higher demand for /sup 153/Gd, an alternative production method to supplement this process has been investigated. This process involves the extraction of gadolinium from the europium-bearing region of highly radioactive, spent control plates used at the High Flux Isotope Reactor (HFIR) with a subsequent re-irradiation of the extracted material for the production of the /sup 153/Gd. Based on the results of experimental and calculational analyses, up to 25 grams of valuable gadolinium (greater than or equal to60% enriched in /sup 152/Gd) resides in the europium-bearing region of the HFIR control components of which 70% is recoverable. At a specific activity yield of 40 curies of /sup 153/Gd for each gram of gadolinium re-irradiated, 700 one-curie sources can be produced from each control plate assayed.

  15. Shock-Wave Heating Model for Chondrule Formation: Prevention of Isotopic Fractionation

    E-Print Network [OSTI]

    Hitoshi Miura; Taishi Nakamoto

    2006-07-03T23:59:59.000Z

    Chondrules are considered to have much information on dust particles and processes in the solar nebula. It is naturally expected that protoplanetary disks observed in present star forming regions have similar dust particles and processes, so study of chondrule formation may provide us great information on the formation of the planetary systems. Evaporation during chondrule melting may have resulted in depletion of volatile elements in chondrules. However, no evidence for a large degree of heavy-isotope enrichment has been reported in chondrules. In order to meet this observed constraint, the rapid heating rate at temperatures below the silicate solidus is required to suppress the isotopic fractionation. We have developed a new shock-wave heating model taking into account the radiative transfer of the dust thermal continuum emission and the line emission of gas molecules and calculated the thermal history of chondrules. We have found that optically-thin shock waves for the thermal continuum emission from dust particles can meet the rapid heating constraint, because the dust thermal emission does not keep the dust particles high temperature for a long time in the pre-shock region and dust particles are abruptly heated by the gas drag heating in the post-shock region. We have also derived the upper limit of optical depth of the pre-shock region using the radiative diffusion approximation, above which the rapid heating constraint is not satisfied. It is about 1 - 10.

  16. Natural materials for carbon capture.

    SciTech Connect (OSTI)

    Myshakin, Evgeniy M. (National Energy Technology Laboratory, Pittsburgh, PA); Romanov, Vyacheslav N. (National Energy Technology Laboratory, Pittsburgh, PA); Cygan, Randall Timothy

    2010-11-01T23:59:59.000Z

    Naturally occurring clay minerals provide a distinctive material for carbon capture and carbon dioxide sequestration. Swelling clay minerals, such as the smectite variety, possess an aluminosilicate structure that is controlled by low-charge layers that readily expand to accommodate water molecules and, potentially, carbon dioxide. Recent experimental studies have demonstrated the efficacy of intercalating carbon dioxide in the interlayer of layered clays but little is known about the molecular mechanisms of the process and the extent of carbon capture as a function of clay charge and structure. A series of molecular dynamics simulations and vibrational analyses have been completed to assess the molecular interactions associated with incorporation of CO2 in the interlayer of montmorillonite clay and to help validate the models with experimental observation.

  17. The new economics of the electric power industry and some implication for the natural gas industry

    SciTech Connect (OSTI)

    Hall, G.R. [Putnam, Hayes & Bartlett, Washington, DC (United States)

    1995-12-31T23:59:59.000Z

    The current restructuring of the natural gas industry and its regulation have important implications for the natural gas industry. Some of these implications are positive, some negative. As in all situations of change and uncertainty, look before you leap, is good advice to those in the natural gas industry seeking to take advantage of the opportunities created by the startling changes that are occurring.

  18. Pena blanca natural analogue project: summary of activities

    SciTech Connect (OSTI)

    Levy, Schon S [Los Alamos National Laboratory; Goldstein, Steven J [Los Alamos National Laboratory; Abdel - Fattah, Amr I [Los Alamos National Laboratory

    2010-12-08T23:59:59.000Z

    The inactive Nopal I uranium mine in silicic tuff north of Chihuahua City, Chihuahua, Mexico, was studied as a natural analogue for an underground nuclear-waste repository in the unsaturated zone. Site stratigraphy was confirmed from new drill core. Datafrom site studies include chemical and isotopic compositions of saturated- and unsaturated-zone waters. A partial geochronology of uranium enrichment and mineralization was established. Evidence pertinent to uranium-series transport in the soil zone and changing redox conditions was collected. The investigations contributed to preliminary, scoping-level performance assessment modeling.

  19. Pena Blanca Natural Analogue Project: Summary of activities

    SciTech Connect (OSTI)

    Levy, S.; Goldstein, S.; Dobson, P.F.; Goodell, P.; Ku, T.-L.; Abdel-Fattah, A.; Saulnier, G.; Fayek, M.; de la Garza, R.

    2011-02-01T23:59:59.000Z

    The inactive Nopal I uranium mine in silicic tuff north of Chihuahua City, Chihuahua, Mexico, was studied as a natural analogue for an underground nuclear-waste repository in the unsaturated zone. Site stratigraphy was confirmed from new drill cores. Data from site studies include chemical and isotopic compositions of saturated- and unsaturated-zone waters. A partial geochronology of uranium enrichment and mineralization was established. Evidence pertinent to uranium-series transport in the soil zone and changing redox conditions was collected. The investigations contributed to preliminary, scoping-level performance assessment modeling.

  20. New Mexico Center for Isotopes in Medicine

    SciTech Connect (OSTI)

    Burchiel, Scott W.

    2012-12-13T23:59:59.000Z

    The purpose of the New Mexico Center for Isotopes in Medicine (NMCIM) is to support research, education and service missions of the UNM College of Pharmacy Radiopharmaceutical Sciences Program (COP RSP) and the Cancer Research and Treatment Center (CRTC). NMCIM developed and coordinated unique translational research in cancer radioimaging and radiotherapy agents based on novel molecules developed at UNM and elsewhere. NMCIM was the primary interface for novel radioisotopes and radiochemistries developed at the Los Alamos National Laboratory (LANL) for SPECT/PET imaging and therapy. NMCIM coordinated the use of the small animal imaging facility with the CRTC provided support services to assist investigators in their studies. NMCIM developed education and training programs that benefited professional, graduate, and postdoctoral students that utilized its unique facilities and technologies. UNM COP RSP has been active in writing research and training grants, as well as supporting contract research with industrial partners. The ultimate goal of NMCIM is to bring new radiopharmaceutical imaging and therapeutic agents into clinical trials that will benefit the health and well being of cancer and other patients in New Mexico and the U.S.