Sample records for national coal production

  1. COAL PRODUCTION ISSUES TO BE STUDIED The National Commission on Energy Policy has recently commenced a

    E-Print Network [OSTI]

    COAL PRODUCTION ISSUES TO BE STUDIED The National Commission on Energy Policy has recently commenced a study on the challenges for expanded coal production in the United States, according to Sasha to 30 years, the production of coal will need to increase steadily from the current level of 1.2 billion

  2. National Coal Quality Inventory (NACQI)

    SciTech Connect (OSTI)

    Robert Finkelman

    2005-09-30T23:59:59.000Z

    The U.S. Geological Survey (USGS) conducted the National Coal Quality Inventory (NaCQI) between 1999 and 2005 to address a need for quality information on coals that will be mined during the next 20-30 years. Collaboration between the USGS, State geological surveys, universities, coal burning utilities, and the coal mining industry plus funding support from the Electric Power Research Institute (EPRI) and the U.S. Department of Energy (DOE) permitted collection and submittal of coal samples for analysis. The chemical data (proximate and ultimate analyses; major, minor and trace element concentrations) for 729 samples of raw or prepared coal, coal associated shale, and coal combustion products (fly ash, hopper ash, bottom ash and gypsum) from nine coal producing States are included. In addition, the project identified a new coal reference analytical standard, to be designated CWE-1 (West Elk Mine, Gunnison County, Colorado) that is a high-volatile-B or high-volatile-A bituminous coal with low contents of ash yield and sulfur, and very low, but detectable contents of chlorine, mercury and other trace elements.

  3. Coal production 1989

    SciTech Connect (OSTI)

    Not Available

    1990-11-29T23:59:59.000Z

    Coal Production 1989 provides comprehensive information about US coal production, the number of mines, prices, productivity, employment, reserves, and stocks to a wide audience including Congress, federal and state agencies, the coal industry, and the general public. 7 figs., 43 tabs.

  4. Coal Production 1992

    SciTech Connect (OSTI)

    Not Available

    1993-10-29T23:59:59.000Z

    Coal Production 1992 provides comprehensive information about US coal production, the number of mines, prices, productivity, employment, productive capacity, and recoverable reserves to a wide audience including Congress, Federal and State agencies, the coal industry, and the general public. In 1992, there were 3,439 active coal mining operations made up of all mines, preparation plants, and refuse operations. The data in Table 1 cover the 2,746 mines that produced coal, regardless of the amount of production, except for bituminous refuse mines. Tables 2 through 33 include data from the 2,852 mining operations that produced, processed, or prepared 10 thousand or more short tons of coal during the period, except for bituminous refuse, and includes preparation plants with 5 thousand or more employee hours. These mining operations accounted for over 99 percent of total US coal production and represented 83 percent of all US coal mining operations in 1992.

  5. Consensus Coal Production Forecast for

    E-Print Network [OSTI]

    Mohaghegh, Shahab

    Consensus Coal Production Forecast for West Virginia 2009-2030 Prepared for the West Virginia Summary 1 Recent Developments 2 Consensus Coal Production Forecast for West Virginia 10 Risks References 27 #12;W.Va. Consensus Coal Forecast Update 2009 iii List of Tables 1. W.Va. Coal Production

  6. National Coal Council Presentation/Prepared Remarks | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    National Coal Council PresentationPrepared Remarks National Coal Council PresentationPrepared Remarks National Coal Council PresentationPrepared Remarks More Documents &...

  7. National Coal celebrates its fifth anniversary

    SciTech Connect (OSTI)

    Fiscor, S.

    2008-06-15T23:59:59.000Z

    The growth and activities of the National Coal Corp since its formation in 2003 are described. 5 photos.

  8. Sandia National Laboratories: Clean Coal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ManagementClean Coal Clean Coal The term clean coal refers to a number of initiatives that seek to reduce or eliminate the hazardous emission or byproducts that result from using...

  9. PRODUCTION OF CARBON PRODUCTS USING A COAL EXTRACTION PROCESS

    SciTech Connect (OSTI)

    Dady Dadyburjor; Philip R. Biedler; Chong Chen; L. Mitchell Clendenin; Manoj Katakdaunde; Elliot B. Kennel; Nathan D. King; Liviu Magean; Peter G. Stansberry; Alfred H. Stiller; John W. Zondlo

    2004-08-31T23:59:59.000Z

    This Department of Energy National Energy Technology Laboratory sponsored project developed carbon products, using mildly hydrogenated solvents to extract the organic portion of coal to create synthetic pitches, cokes, carbon foam and carbon fibers. The focus of this effort was on development of lower cost solvents, milder hydrogenation conditions and improved yield in order to enable practical production of these products. This technology is needed because of the long-term decline in production of domestic feedstocks such as petroleum pitch and coal tar pitch. Currently, carbon products represents a market of roughly 5 million tons domestically, and 19 million tons worldwide. Carbon products are mainly derived from feedstocks such as petroleum pitch and coal tar pitch. The domestic supply of petroleum pitch is declining because of the rising price of liquid fuels, which has caused US refineries to maximize liquid fuel production. As a consequence, the long term trend has a decline in production of petroleum pitch over the past 20 years. The production of coal tar pitch, as in the case of petroleum pitch, has likewise declined significantly over the past two decades. Coal tar pitch is a byproduct of metallurgical grade coke (metcoke) production. In this industry, modern metcoke facilities are recycling coal tar as fuel in order to enhance energy efficiency and minimize environmental emissions. Metcoke production itself is dependent upon the production requirements for domestic steel. Hence, several metcoke ovens have been decommissioned over the past two decades and have not been replaced. As a consequence sources of coal tar are being taken off line and are not being replaced. The long-term trend is a reduction in coal tar pitch production. Thus import of feedstocks, mainly from Eastern Europe and China, is on the rise despite the relatively large transportation cost. To reverse this trend, a new process for producing carbon products is needed. The process must be economically competitive with current processes, and yet be environmentally friendly as well. The solvent extraction process developed uses mild hydrogenation of low cost oils to create powerful solvents that can dissolve the organic portion of coal. The insoluble portion, consisting mainly of mineral matter and fixed carbon, is removed via centrifugation or filtration, leaving a liquid solution of coal chemicals and solvent. This solution can be further refined via distillation to meet specifications for products such as synthetic pitches, cokes, carbon foam and fibers. The most economical process recycles 85% of the solvent, which itself is obtained as a low-cost byproduct from industrial processes such as coal tar or petroleum refining. Alternatively, processes have been developed that can recycle 100% of the solvent, avoiding any need for products derived from petroleum or coal tar.

  10. Coal Combustion Products Extension Program

    SciTech Connect (OSTI)

    Tarunjit S. Butalia; William E. Wolfe

    2006-01-11T23:59:59.000Z

    This final project report presents the activities and accomplishments of the ''Coal Combustion Products Extension Program'' conducted at The Ohio State University from August 1, 2000 to June 30, 2005 to advance the beneficial uses of coal combustion products (CCPs) in highway and construction, mine reclamation, agricultural, and manufacturing sectors. The objective of this technology transfer/research program at The Ohio State University was to promote the increased use of Ohio CCPs (fly ash, FGD material, bottom ash, and boiler slag) in applications that are technically sound, environmentally benign, and commercially competitive. The project objective was accomplished by housing the CCP Extension Program within The Ohio State University College of Engineering with support from the university Extension Service and The Ohio State University Research Foundation. Dr. Tarunjit S. Butalia, an internationally reputed CCP expert and registered professional engineer, was the program coordinator. The program coordinator acted as liaison among CCP stakeholders in the state, produced information sheets, provided expertise in the field to those who desired it, sponsored and co-sponsored seminars, meetings, and speaking at these events, and generally worked to promote knowledge about the productive and proper application of CCPs as useful raw materials. The major accomplishments of the program were: (1) Increase in FGD material utilization rate from 8% in 1997 to more than 20% in 2005, and an increase in overall CCP utilization rate of 21% in 1997 to just under 30% in 2005 for the State of Ohio. (2) Recognition as a ''voice of trust'' among Ohio and national CCP stakeholders (particularly regulatory agencies). (3) Establishment of a national and international reputation, especially for the use of FGD materials and fly ash in construction applications. It is recommended that to increase Ohio's CCP utilization rate from 30% in 2005 to 40% by 2010, the CCP Extension Program be expanded at OSU, with support from state and federal agencies, utilities, trade groups, and the university, to focus on the following four specific areas of promise: (a) Expanding use in proven areas (such as use of fly ash in concrete); (b) Removing or reducing regulatory and perceptual barriers to use (by working in collaboration with regulatory agencies); (c) Developing new or under-used large-volume market applications (such as structural fills); and (d) Placing greater emphasis on FGD byproducts utilization.

  11. Model documentation Coal Market Module of the National Energy Modeling System

    SciTech Connect (OSTI)

    NONE

    1996-04-30T23:59:59.000Z

    This report documents objectives and conceptual and methodological approach used in the development of the National Energy Modeling System (NEMS) Coal Market Module (CMM) used to develop the Annual Energy Outlook 1996 (AEO96). This report catalogues and describes the assumptions, methodology, estimation techniques, and source code of CMM`s three submodules: Coal Production Submodule, Coal Export Submodule, and Coal Distribution Submodule.

  12. Synthetic fuel production by indirect coal liquefaction

    E-Print Network [OSTI]

    and dimethyl ether) by indirect coal liquefaction (ICL). Gasification of coal pro- duces a synthesis gas by coal gasification. The principal con- stituents of ``syngas'' are carbon monoxide and hydrogen, which modern coal gasification facilities in operation to make hydrogen for ammonia production. Also

  13. Arrowhead Center: Coal Production and Regional Economic Growth Report Title: Coal Production and Regional Economic Growth

    E-Print Network [OSTI]

    Johnson, Eric E.

    Arrowhead Center: Coal Production and Regional Economic Growth Report Title: Coal Production@nmsu.edu #12;Arrowhead Center: Coal Production and Regional Economic Growth i Disclaimer This report States Government or any agency thereof. #12;Arrowhead Center: Coal Production and Regional Economic

  14. Consensus Coal Production And Price Forecast For

    E-Print Network [OSTI]

    Mohaghegh, Shahab

    Consensus Coal Production And Price Forecast For West Virginia: 2011 Update Prepared for the West December 2011 © Copyright 2011 WVU Research Corporation #12;#12;W.Va. Consensus Coal Forecast Update 2011 i Table of Contents Executive Summary 1 Recent Developments 3 Consensus Coal Production And Price Forecast

  15. Coal combustion products (CCPs

    Office of Environmental Management (EM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 1112011AT&T, Inc.'sEnergyTexas1. FeedstockCLEAN AIR ACTClosedfor Elementary School

  16. A study of coal production in Nigeria

    SciTech Connect (OSTI)

    Akarakiri, J.B.; Afonja, A.A.; Okejiri, E.C. (Obafemi Awolowo Univ., Lle-Lfe (Nigeria))

    1991-01-01T23:59:59.000Z

    The Nigerian coal industry was studied. The focus was on the problems which have caused low production output of coal. More specifically, the study examined the present techniques of coal production, the causes of low production of coal, the coal production policy as it affected this study, and proposed policy measures to address the findings. It was discovered that some of the limiting factors to coal production in Nigeria could be attributed to the lack of the following: (i) clear and specific production-demand targets set for coal in Nigeria; (ii) adequate technological capability to mechanize coal mining operations in Nigeria; (iii) venture capital to invest in coal production; (iv) poor infrastructural facilities for coal production such as mining, storage, transportation, etc. It was also discovered that the dissatisfaction of the miners with their conditions of service influenced production capacity negatively. These findings point to the reality that coal is unlikely to play a major role in the country's energy equation in the near future unless serious efforts are made to address the above issues.

  17. NETL Coal to Hydrogen Program National Energy Technology Laboratory

    E-Print Network [OSTI]

    /Hydrogen Production CCPI Technology Demonstrations (50/50) · Clear Skies · Reduced Carbon Intensity Clean Coal

  18. Production of Hydrogen from Underground Coal Gasification

    DOE Patents [OSTI]

    Upadhye, Ravindra S. (Pleasanton, CA)

    2008-10-07T23:59:59.000Z

    A system of obtaining hydrogen from a coal seam by providing a production well that extends into the coal seam; positioning a conduit in the production well leaving an annulus between the conduit and the coal gasification production well, the conduit having a wall; closing the annulus at the lower end to seal it from the coal gasification cavity and the syngas; providing at least a portion of the wall with a bifunctional membrane that serves the dual purpose of providing a catalyzing reaction and selectively allowing hydrogen to pass through the wall and into the annulus; and producing the hydrogen through the annulus.

  19. Low-rank-coal study national needs for resource development. Volume 1. Executive summary

    SciTech Connect (OSTI)

    Elliot, Dr., Martin A.; Hill, George R.; Jonakin, James; Crutchfield, Paul W.; Severson, Donald E.; White, David M.; Yeager, Kurt

    1980-11-01T23:59:59.000Z

    Low-rank coals - lignite and subbituminous - are those which have been subjected to the least amount of metamorphic change during the coal-forming process. As such, they retain greater fractions of moisture and volatile matter from the original peat material, and contain less fixed carbon, than the high-rank coals - bituminous and anthracite. The primary measure used to classify the lower ranks of coal is heating value. Other important characteristics which distinguish the low-rank coals from high-rank coals are discussed in this report. Low-rank coals represent a major, and largely untapped, energy resource for this country. Very extensive deposits of lignite and subbituminous coal exist in the western states, the Gulf coast, and Alaska. Major deposits of low-rank coal are also found in many other countries, most notably the USSR, Australia, Canada, and the central and eastern European nations. Worldwide coal statistics indicate that low-rank coals account for roughly one-third of the total resource and current production tonnages. This report recommends a comprehensive national research, development, and demonstration (RD and D) program to enhance the development of low-rank coals. The major conclusion of this study is that the unique properties of these coals affect the technologies for their extraction, preparation, direct use, and conversion and justify a separate focus on low-rank coals in the national RD and D efforts.

  20. Directory of coal production ownership, 1979

    SciTech Connect (OSTI)

    Thompson, B.

    1981-10-01T23:59:59.000Z

    Ownership patterns in the coal industry are highly complex. Many producers are diversified into other lines of activity. The pattern and extent of this diversification has varied through time. In the past, steel and nonferrous metals companies had major coal industry involvement. This is still true today. However, other types of enterprises have entered the industry de novo or through merger. Those of greatest significance in recent times have involved petroleum and particularly public utility companies. This report attempts to identify, as accurately as possible, production ownership patterns in the coal industry. The audience for this Directory is anyone who is interested in accurately tracing the ownership of coal companies to parent companies, or who is concerned about the structure of ownership in the US coal industry. This audience includes coal industry specialists, coal industry policy analysts, economists, financial analysts, and members of the investment community.

  1. Clean coal technology. Coal utilisation by-products

    SciTech Connect (OSTI)

    NONE

    2006-08-15T23:59:59.000Z

    The need to remove the bulk of ash contained in flue gas from coal-fired power plants coupled with increasingly strict environmental regulations in the USA result in increased generation of solid materials referred to as coal utilisation by-products, or CUBs. More than 40% of CUBs were sold or reused in the USA in 2004 compared to less than 25% in 1996. A goal of 50% utilization has been established for 2010. The American Coal Ash Association (ACCA) together with the US Department of Energy's Power Plant Improvement Initiative (PPPI) and Clean Coal Power Initiative (CCPI) sponsor a number of projects that promote CUB utilization. Several are mentioned in this report. Report sections are: Executive summary; Introduction; Where do CUBs come from?; Market analysis; DOE-sponsored CUB demonstrations; Examples of best-practice utilization of CUB materials; Factors limiting the use of CUBs; and Conclusions. 14 refs., 1 fig., 5 tabs., 14 photos.

  2. Coal production expansion: a selected bibliography

    SciTech Connect (OSTI)

    Grissom, M.C. (ed.)

    1980-07-01T23:59:59.000Z

    The expeditious and economic transport of coal from producing regions to consuming regions is essential to any policy designed to increase the use of coal as an energy source. Obtaining an optimal coal transportation system, including terminal facilities, is significant in providing US coal to its users in the United States and abroad. Rail, barge, truck, slurry pipeline, and ship are the modes used to move coal from the producer to the user. Transportation costs represent a large percentage of the delivered price. This bibliography includes 138 selected citations on coal export, transport, and production. The references are to reports from the Department of Energy and its contractors, reports from other government or private organizations, and journal articles, books, conference papers, and monographs from US originators. These citations and hundreds of additional citations on this subject are available for on-line searching and retrieval from the Technical Information Center's Energy Data Base using the DOE/RECON interactive system. Approximately 50,000 citations on coal and coal products are a part of this data base. Current additions to data base on this subject are announced monthly in Fossil Energy Update. DOE-sponsored work is also announced in Energy Research Abstracts. The citations in this publication are arranged in broad subject categories as shown in the table of contents. Five indexes are provided: Corporate, Author, Subject, Contract Number, and Report Number. Included as an appendix are some tables and figures from Energy Information Administration reports covering coal production and disposition.

  3. National Coal Council Meeting | Department of Energy

    Office of Environmental Management (EM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33Frequently Asked QuestionsDepartment of Energyof Energy U.S. Department ofNational Coal

  4. Coal ash by-product reutilization

    SciTech Connect (OSTI)

    Muncy, J. [Potomac Electric Power Co., Washington, DC (United States); Miller, B. [DYNA Corp., Upper Marlboro, MD (United States)

    1997-09-01T23:59:59.000Z

    Potomac Electric Power Company (PEPCO) has as part of its vision and value statement that, ``We are responsible stewards of environmental and corporate resources.`` With this moral imperative in mind, a project team was charged with initiating the Coal Pile Liner Project--installing a membrane liner under the existing coal storage pile at the Morgantown Generating Station. The existing coal yard facilities were constructed prior to the current environmental regulations, and it became necessary to upgrade the storage facilities to be environmentally friendly. The project team had two objectives in this project: (1) prevent coal pile leachate from entering the groundwater system; (2) test the viability of using coal ash by-products as an aggregate substitute for concrete applications. Both objectives were met, and two additional benefits were achieved as well: (1) the use of coal ash by-products as a coal liner produced significant cost savings to the project directly; (2) the use of coal ash by-products reduced plant operation and maintenance expenses.

  5. Coal Combustion By-Products (Maryland)

    Broader source: Energy.gov [DOE]

    The Department of the Environment is responsible for regulating fugitive air emissions from the transportation of coal combustion by-products and the permissible beneficial uses of these by...

  6. ccpi-multi-product-coal | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1 Industrial Carbon Capture and Storage Clean Coal Power Initiative Power Plant Improvement Initiative Clean Coal Technology Demonstration Program FutureGen Advanced Multi-Product...

  7. Underground coal gasification product quality parameters

    SciTech Connect (OSTI)

    Bruggink, P.R.; Davis, B.E.

    1981-01-01T23:59:59.000Z

    A simplified model is described which will indicate the economic value of the raw product gas from an experimental underground coal gasification test on a real-time basis in order to aid in the optimization of the process during the course of the test. The model relates the properties of the product gas and the injection gas to the cost of producing each of five potential commercial products. This model was utilized to evaluate data during the Gulf-DOE underground coal gasification test at Rawlins, Wyoming in the fall of 1981. 6 refs.

  8. Estimating coal production peak and trends of coal imports in China

    SciTech Connect (OSTI)

    Bo-qiang Lin; Jiang-hua Liu [Xiamen University, Xiamen (China). China Center for Energy Economics Research (CCEER)

    2010-01-15T23:59:59.000Z

    More than 20 countries in the world have already reached a maximum capacity in their coal production (peak coal production) such as Japan, the United Kingdom and Germany. China, home to the third largest coal reserves in the world, is the world's largest coal producer and consumer, making it part of the Big Six. At present, however, China's coal production has not yet reached its peak. In this article, logistic curves and Gaussian curves are used to predict China's coal peak and the results show that it will be between the late 2020s and the early 2030s. Based on the predictions of coal production and consumption, China's net coal import could be estimated for coming years. This article also analyzes the impact of China's net coal import on the international coal market, especially the Asian market, and on China's economic development and energy security. 16 refs., 5 figs., 6 tabs.

  9. Biological production of ethanol from coal

    SciTech Connect (OSTI)

    Not Available

    1992-12-01T23:59:59.000Z

    Due to the abundant supply of coal in the United States, significant research efforts have occurred over the past 15 years concerning the conversion of coal to liquid fuels. Researchers at the University of Arkansas have concentrated on a biological approach to coal liquefaction, starting with coal-derived synthesis gas as the raw material. Synthesis gas, a mixture of CO, H[sub 2], CO[sub 2], CH[sub 4] and sulfur gases, is first produced using traditional gasification techniques. The CO, CO[sub 2] and H[sub 2] are then converted to ethanol using a bacterial culture of Clostridium 1jungdahlii. Ethanol is the desired product if the resultant product stream is to be used as a liquid fuel. However, under normal operating conditions, the wild strain'' produces acetate in favor of ethanol in conjunction with growth in a 20:1 molar ratio. Research was performed to determine the conditions necessary to maximize not only the ratio of ethanol to acetate, but also to maximize the concentration of ethanol resulting in the product stream.

  10. Coal combustion products: trash or treasure?

    SciTech Connect (OSTI)

    Hansen, T.

    2006-07-15T23:59:59.000Z

    Coal combustion by-products can be a valuable resource to various industries. The American Coal Ash Association (ACAA) collects data on production and uses of coal combustion products (CCPs). 122.5 million tons of CCPs were produced in 2004. The article discusses the results of the ACCA's 2004 survey. Fly ash is predominantly used as a substitute for Portland cement; bottom ash for structural fill, embankments and paved road cases. Synthetic gypsum from the FGD process is commonly used in wallboard. Plant owners are only likely to have a buyer for a portion of their CCPs. Although sale of hot water (from Antelope Valley Station) from condensers for use in a fish farm to raise tilapia proved unviable, the Great Plains Synfuels Plant which manufactures natural gas from lignite produces a wide range of products including anhydrous ammonia, phenol, krypton, carbon dioxide (for enhanced oil recovery), tar oils and liquid nitrogen. ACCA's goal is to educate people about CCPs and how to make them into useful products, and market them, in order to reduce waste disposal and enhance revenue. The article lists members of the ACCA. 2 photos., 1 tab.

  11. Fluorine in coal and coal by-products

    SciTech Connect (OSTI)

    Robertson, J.D.; Wong, A.S.; Hower, J.C. [Univ. of Kentucky, Lexington, KY (United States)

    1994-12-31T23:59:59.000Z

    Fluorine occurs in awe amounts in most coals. It is typically associated with minerals of the apatite group, principally fluorapatite and clays, and with fluorite, tourmaline, topaz, amphiboles and micas. The average fluorine content of US coal is, according to the tabulation of Swanson, 74 {mu}g/g. In the United States, the lowest average fluorine concentration of 30 {mu}g/g is found in coals from Eastern Kentucky and the highest average value of 160 {mu}g/g is found in coals from Wyoming and New Mexico. The concentration range of fluorine in European coals is similar to that found in the US while the average fluorine content of Australian coals ranges from 15 to 500 {mu}g/g. We have determined the fluorine content in coal and fly ash standards by proton-induced gamma ray emission analysis (PIGE).

  12. CONSTRUCTION MATERIALS MADE WITH COAL COMBUSTION BY-PRODUCTS

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    ash and bottom ash are produced as by-products of coal-fired electricity generation. In many countriesCONSTRUCTION MATERIALS MADE WITH COAL COMBUSTION BY-PRODUCTS Lihua Wei*, Tarun R. Naik**, and Dean-Milwaukee, is being conducted to develop new low-cost construction materials primarily using coal combustion

  13. The methods of steam coals usage for coke production

    SciTech Connect (OSTI)

    Korobetskii, I.A.; Ismagilov, M.S.; Nazimov, S.A.; Sladkova, I.L.; Shudrikov, E.S.

    1998-07-01T23:59:59.000Z

    Nowadays, high volatile bituminous coals are broadly used for metallurgical coke production in Russia. The share of such coals in the coking blend is variable from 20 to 40% by weight. There are some large coal deposits in Kuznetskii basin which have coals with low caking tendency. The low caking properties of such coals limit of its application in the coking process. At the same time the usage of low caking coals for coke production would allow flexibility of the feedstock for coke production. Preliminary tests, carried out in COAL-C's lab has shown some differences in coal properties with dependence on the size distribution. That is why the separation of the well-caking fraction from petrographically heterogeneous coals and its further usage in coking process may be promising. Another way for low caking coals application in the coke industry is briquettes production from such coals. This method has been known for a very long time. It may be divided into two possible directions. First is a direct coking of briquettes from the low caking coals. Another way is by adding briquettes to coal blends in defined proportion and combined coking. The possibility of application of coal beneficiation methods mentioned above was investigated in present work.

  14. U. S. monthly coal production

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40 Buildingto17 34 44Year Jan Feb Mar Apr May Jun602 1,397 125 QL1. FloorspaceL3.3.

  15. Weekly Coal Production by State

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001)gasoline prices4 Oil demand expected toallBlender Net

  16. Model documentation, Coal Market Module of the National Energy Modeling System

    SciTech Connect (OSTI)

    NONE

    1998-01-01T23:59:59.000Z

    This report documents the objectives and the conceptual and methodological approach used in the development of the National Energy Modeling System`s (NEMS) Coal Market Module (CMM) used to develop the Annual Energy Outlook 1998 (AEO98). This report catalogues and describes the assumptions, methodology, estimation techniques, and source code of CMM`s two submodules. These are the Coal Production Submodule (CPS) and the Coal Distribution Submodule (CDS). CMM provides annual forecasts of prices, production, and consumption of coal for NEMS. In general, the CDS integrates the supply inputs from the CPS to satisfy demands for coal from exogenous demand models. The international area of the CDS forecasts annual world coal trade flows from major supply to major demand regions and provides annual forecasts of US coal exports for input to NEMS. Specifically, the CDS receives minemouth prices produced by the CPS, demand and other exogenous inputs from other NEMS components, and provides delivered coal prices and quantities to the NEMS economic sectors and regions.

  17. Coal industry annual 1997

    SciTech Connect (OSTI)

    NONE

    1998-12-01T23:59:59.000Z

    Coal Industry Annual 1997 provides comprehensive information about US coal production, number of mines, prices, productivity, employment, productive capacity, and recoverable reserves. US Coal production for 1997 and previous years is based on the annual survey EIA-7A, Coal Production Report. This report presents data on coal consumption, coal distribution, coal stocks, coal prices, and coal quality for Congress, Federal and State agencies, the coal industry, and the general public. Appendix A contains a compilation of coal statistics for the major coal-producing States. This report includes a national total coal consumption for nonutility power producers that are not in the manufacturing, agriculture, mining, construction, or commercial sectors. 14 figs., 145 tabs.

  18. EIA - Weekly U.S. Coal Production

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0 Year-1InformationDieselAnnual EnergyAlabama Table 1.Coal

  19. Hydrogen Production and Purification from Coal and Other Heavy Feedstocks Year 6 - Activity 1.4 - Development of a National Center for Hydrogen Technology

    SciTech Connect (OSTI)

    Dunham, Grant

    2012-03-15T23:59:59.000Z

    Air Products and Chemicals, Inc., is developing the sour pressure swing adsorption (PSA) technology which can be used to reject acid gas components (hydrogen sulfide [H{sub 2}S] and carbon dioxide [CO{sub 2}]) from sour syngas streams such as coal gasification syngas. In the current work, tests were conducted to investigate the impact of continuous exposure of real sour syngas and dilute levels of hydrochloric acid (HCl) and ammonia (NH{sub 3}) on the preferred adsorbent of that process. The results show a modest (~10%–15%) decrease in CO{sub 2} adsorption capacity after sour syngas exposure, as well as deposition of metals from carbonyl decomposition. Continuous exposure to HCl and NH{sub 3} yield a higher degree of CO{sub 2} capacity degradation (up to 25%). These tests represent worst-case approaches since the exposure is continuous and the HCl and NH{sub 3} levels are relatively high compare to an industrial sour syngas stream. Long-term PSA tests are needed to unequivocally evaluate the impact of cyclic exposure to these types of streams.

  20. Remediation of Abandoned Mines Using Coal Combustion By-Products

    E-Print Network [OSTI]

    Aydilek, Ahmet

    . Maryland has about 450 coal mines out of which only 50 are active and about 150 mines produce AMD RafalkoRemediation of Abandoned Mines Using Coal Combustion By-Products Sowmya Bulusu1 ; Ahmet H. Aydilek that occurs when pyrite that is present in abandoned coal mines comes in contact with oxygen and water, which

  1. Hydrogen production with coal using a pulverization device

    DOE Patents [OSTI]

    Paulson, Leland E. (Morgantown, WV)

    1989-01-01T23:59:59.000Z

    A method for producing hydrogen from coal is described wherein high temperature steam is brought into contact with coal in a pulverizer or fluid energy mill for effecting a steam-carbon reaction to provide for the generation of gaseous hydrogen. The high temperature steam is utilized to drive the coal particles into violent particle-to-particle contact for comminuting the particulates and thereby increasing the surface area of the coal particles for enhancing the productivity of the hydrogen.

  2. Production of coal-based fuels and value-added products: coal to liquids using petroleum refinery streams

    SciTech Connect (OSTI)

    Clifford, C.E.B.; Schobert, H.H. [Pennsylvania State University, PA (United States)

    2008-07-01T23:59:59.000Z

    We are studying several processes that utilize coal, coal-derived materials, or biomass in existing refining facilities. A major emphasis is the production of a coal-based replacement for JP-8 jet fuel. This fuel is very similar to Jet A and jet A-1 in commercial variation, so this work has significant carry-over into the private sector. We have been focusing on three processes that would be retrofitted into a refinery: (1) coal tar/refinery stream blending and hydro-treatment; (2) coal extraction using refinery streams followed by hydro-treatment; and (3) co-coking of coal blended with refinery streams. 4 figs., 5 tabs.

  3. Method of removal of sulfur from coal and petroleum products

    DOE Patents [OSTI]

    Verkade, John G. (Ames, IA); Mohan, Thyagarajan (Ames, IA); Angelici, Robert J. (Ames, IA)

    1995-01-01T23:59:59.000Z

    A method for the removal of sulfur from sulfur-bearing materials such as coal and petroleum products using organophosphine and organophosphite compounds is provided.

  4. Quality characterization of western Cretaceous coal from the Colorado Plateau as part of the U.S. Geological Survey's National Coal Resource Assessment Program

    SciTech Connect (OSTI)

    Affolter, R.H.; Brownfield, M.E.

    1999-07-01T23:59:59.000Z

    The goal of the Colorado Plateau Coal Assessment program is to provide an overview of the geologic setting, distribution, resources, and quality of Cretaceous coal in the Colorado Plateau. This assessment, which is part of the US Geological Survey's National Coal Resource Assessment Program, is different from previous coal assessments in that the major emphasis is placed on coals that are most likely to provide energy over the next few decades. The data is also being collected and stored in digital format that can be updated as new information becomes available. Environmental factors may eventually control how coal will be mined, and determine to what extent measures will be implemented to reduce trace element emissions. In the future, increased emphasis will also be placed on coal combustion products and the challenges of waste product disposal or utilization. Therefore, coal quality characterization is an important aspect of the coal assessment program in that it provides important data that will influence future utilization of this resource. The Colorado Plateau study is being completed in cooperation with the US Bureau of Land Management, US Forest Service, Arizona Geological Survey, Colorado Geological Survey, New Mexico Bureau of Mines and Mineral Resources, and the Utah Geological Survey. Restrictions on coal thickness and overburden will be applied to the resource calculations and the resources will be categorized by land ownership. In some areas these studies will also delineate areas where coal mining may be restricted because of land use, industrial, social, or environmental factors. Emphasis is being placed on areas where the coal is controlled by the Federal Government.

  5. PRODUCTION OF FOAMS, FIBERS AND PITCHES USING A COAL EXTRACTION PROCESS

    SciTech Connect (OSTI)

    Chong Chen; Elliot B. Kennel; Liviu Magean; Pete G. Stansberry; Alfred H. Stiller; John W. Zondlo

    2004-06-20T23:59:59.000Z

    This Department of Energy National Energy Technology Laboratory sponsored project developed processes for converting coal feedstocks to carbon products, including coal-derived pitch, coke foams and fibers based on solvent extraction processes. A key technology is the use of hydrogenation accomplished at elevated temperatures and pressures to obtain a synthetic coal pitch. Hydrogenation, or partial direct liquefaction of coal, is used to modify the properties of raw coal such that a molten synthetic pitch can be obtained. The amount of hydrogen required to produce a synthetic pitch is about an order of magnitude less than the amount required to produce synthetic crude oil. Hence the conditions for synthetic pitch production consume very little hydrogen and can be accomplished at substantially lower pressure. In the molten state, hot filtration or centrifugation can be used to separate dissolved coal chemicals from mineral matter and insolubles (inertinite), resulting in the production of a purified hydrocarbon pitch. Alternatively, if hydrogenation is not used, aromatic hydrocarbon liquids appropriate for use as precursors to carbon products can obtained by dissolving coal in a solvent. As in the case for partial direct liquefaction pitches, undissolved coal is removed via hot filtration or centrifugation. Excess solvent is boiled off and recovered. The resultant solid material, referred to as Solvent Extracted Carbon Ore or SECO, has been used successfully to produce artificial graphite and carbon foam.

  6. Indirect conversion of coal to methanol and gasoline: product price vs product slate

    SciTech Connect (OSTI)

    Wham, R.M.; McCracken, D.J.; Forrester, R.C. III

    1980-01-01T23:59:59.000Z

    The Oak Ridge National Laboratory (ORNL) conducts process analysis and engineering evaluation studies for the Department of Energy to provide, on a consistent basis, technical and economic assessments of processes and systems for coal conversion and utilization. Such assessments permit better understanding of the relative technical and economic potential of these processes. The objective of the work described here was to provide an assessment of the technical feasibility, economic competitiveness, and environmental acceptability of selected indirect coal liquefaction processes on a uniform, consistent, and impartial basis. Particular emphasis is placed on production of methanol as a principal product or methanol production for conversion to gasoline. Potential uses for the methanol are combustion in peaking-type turbines or blending with gasoline to yield motor fuel. Conversion of methanol to gasoline is accomplished through the use of the Mobil methanol-to-gasoline (MTG) process. Under the guidance of ORNL, Fluor Engineers and Constructors, Houston Division, prepared four conceptual process designs for indirect conversion of a Western subbituminous coal to either methanol or gasoline. The conceptual designs are based on the use of consistent technology for the core of the plant (gasification through methanol synthesis) with additional processing as necessary for production of different liquid products of interest. The bases for the conceptual designs are given. The case designations are: methanol production for turbine-grade fuel; methanol production for gasoline blending; gasoline production with coproduction of SNG; and gasoline production maximized.

  7. Imminence of peak in US coal production and overestimation of reserves

    E-Print Network [OSTI]

    Khare, Sanjay V.

    1 Imminence of peak in US coal production and overestimation of reserves Nathan G. F. Reaver, coal reserves, coal production forecast, peak coal, USA energy, non- linear fitting #12;3 1 fuels, coal, oil, and natural gas, it is coal that is the most carbon intensive (W. Moomaw, 2011). Due

  8. Model documentation coal market module of the National Energy Modeling System

    SciTech Connect (OSTI)

    NONE

    1995-03-01T23:59:59.000Z

    This report documents the approaches used in developing the Annual Energy Outlook 1995 (AEO95). This report catalogues and describes the assumptions, methodology, estimation techniques, and source code of the coal market module`s three submodules. These are the Coal Production Submodule (CPS), the Coal Export Submodule (CES), the Coal Expert Submodule (CES), and the Coal Distribution Submodule (CDS).

  9. Panel data analysis of U.S. coal productivity

    E-Print Network [OSTI]

    Stoker, Thomas M.

    2000-01-01T23:59:59.000Z

    We analyze labor productivity in coal mining in the United States using indices of productivity change associated with the concepts of panel data modeling. This approach is valuable when there is extensive heterogeneity ...

  10. Coalbed methane production enhancement by underground coal gasification

    SciTech Connect (OSTI)

    Hettema, M.H.H.; Wolf, K.H.A.A.; Neumann, B.V.

    1997-12-31T23:59:59.000Z

    The sub-surface of the Netherlands is generally underlain by coal-bearing Carboniferous strata at greater depths (at many places over 1,500 m). These coal seams are generally thinner than 3 meter, occur in groups (5--15) within several hundred meters and are often fairly continuous over many square kilometers. In many cases they have endured complex burial history, influencing their methane saturation. In certain particular geological settings, a high, maximum coalbed methane saturation, may be expected. Carboniferous/Permian coals in the Tianjin-region (China) show many similarities concerning geological settings, rank and composition. Economical coalbed methane production at greater depths is often obstructed by the (very) low permeabilities of the coal seams as with increasing depth the deformation of the coal reduces both its macro-porosity (the cleat system) and microporosity. Experiments in abandoned underground mines, as well as after underground coal gasification tests indicate ways to improve the prospects for coalbed methane production in originally tight coal reservoirs. High permeability areas can be created by the application of underground coal gasification of one of the coal seams of a multi-seam cycle with some 200 meter of coal bearing strata. The gasification of one of the coal seams transforms that seam over a certain area into a highly permeable bed, consisting of coal residues, ash and (thermally altered) roof rubble. Additionally, roof collapse and subsidence will destabilize the overburden. In conjunction this will permit a better coalbed methane production from the remaining surrounding parts of the coal seams. Moreover, the effects of subsidence will influence the stress patterns around the gasified seam and this improves the permeability over certain distances in the coal seams above and below. In this paper the effects of the combined underground coal gasification and coalbed methane production technique are regarded for a single injection well. Known geotechnical aspects are combined with results from laboratory experiments on compaction of thermally treated rubble. An axi-symmetric numerical model is used to determine the effects induced by the gasified coal seam. The calculation includes the rubble formation, rubble compaction and induced stress effects in the overlying strata. Subsequently the stress effects are related to changes in coal permeability, based on experimental results of McKee et al.

  11. COAL DERIVED MATRIX PITCHES FOR CARBON-CARBON COMPOSITE MANUFACTURE/PRODUCTION OF FIBERS AND COMPOSITES FROM COAL-BASED PRECURSORS

    SciTech Connect (OSTI)

    Peter G. Stansberry; John W. Zondlo

    2001-07-01T23:59:59.000Z

    The Consortium for premium Carbon Products from Coal, with funding from the US Department of Energy, National Energy Technology Laboratory continue with the development of innovative technologies that will allow coal or coal-derived feedstocks to be used in the production of value-added carbon materials. In addition to supporting eleven independent projects during budget period 3, three meetings were held at two separate locations for the membership. The first was held at Nemacolin Woodlands Resort on May 15-16, 2000. This was followed by two meetings at Penn State, a tutorial on August 11, 2000 and a technical progress meeting on October 26-27.

  12. Characterization of feed coal and coal combustion products from power plants in Indiana and Kentucky

    SciTech Connect (OSTI)

    Brownfield, M.E.; Affolter, R.H.; Cathcart, J.D.; O'Connor, J.T.; Brownfield, I.K.

    1999-07-01T23:59:59.000Z

    The US Geological Survey, Kentucky Geological Survey, and the University of Kentucky Center for Applied Energy Research are collaborating with Indiana and Kentucky utilities to determine the physical and chemical properties of feed coal and coal combustion products (CCP) from three coal-fired power plants. These three plants are designated as Units K1, K2, and I1 and burn high-, moderate-, and low-sulfur coals, respectively. Over 200 samples of feed coal and CCP were analyzed by various chemical and mineralogical methods to determine mode of occurrence and distribution of trace elements in the CCP. Generally, feed coals from all 3 Units contain mostly well-crystallized kaolinite and quartz. Comparatively, Unit K1 feed coals have higher amounts of carbonates, pyrite and sphalerite. Unit K2 feed coals contain higher kaolinite and illite/muscovite when compared to Unit K1 coals. Unit I1 feed coals contain beta-form quartz and alumino-phosphates with minor amounts of calcite, micas, anatase, and zircon when compared to K1 and K2 feed coals. Mineralogy of feed coals indicate that the coal sources for Units K1 and K2 are highly variable, with Unit K1 displaying the greatest mineralogic variability; Unit I1 feed coal however, displayed little mineralogic variation supporting a single source. Similarly, element contents of Units K1 and K2 feed coals show more variability than those of Unit I1. Fly ash samples from Units K1 and K2 consist mostly of glass, mullite, quartz, and spines group minerals. Minor amounts of illite/muscovite, sulfates, hematite, and corundum are also present. Spinel group minerals identified include magnetite, franklinite, magnesioferrite, trevorite, jacobisite, and zincochromite. Scanning Electron Microscope analysis reveals that most of the spinel minerals are dendritic intergrowths within aluminum silicate glass. Unit I1 fly ash samples contain glass, quartz, perovskite, lime, gehlenite, and apatite with minor amounts of periclase, anhydrite, carbonates, pyroxenes, and spinels. The abundant Ca mineral phases in the Unit I1 fly ashes are attributed to the presence of carbonate, clay and phosphate minerals in the coal.

  13. The value of coal combustion products: an economic assessment of CCP unitization for the US economy

    SciTech Connect (OSTI)

    Steward, A.

    2005-07-01T23:59:59.000Z

    The recently released study by the American Coal Council (ACC) on 'The Value of Coal Combustion Products' provides a detailed economic assessment of CCP utilization for US markets and the US economy. Over 125 million tons of CCPs are produced in the US each year. The projected growth in the nation's utility-coal industry will result in the production of even greater volumes of CCPs. The ACC study details: how CCPs are currently being utilized; what factors are affecting utilization growth; what are the economic benefits of avoiding disposal costs; what is the annual revenue potential of CCP utilization; what direct economic benefits in employment and tax revenues can be gained; and what indirect economic benefits are available for support industries, coal consumers and the building industry. 9 refs., 16 tabs.

  14. National Coal Council Meeting | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742Energy China 2015of 2005 attheMohammed Khan - TechnologyJanuaryUpcoming EventsNafeesaNatUPS

  15. BLACK THUNDER COAL MINE AND LOS ALAMOS NATIONAL LABORATORY EXPERIMENTAL STUDY

    E-Print Network [OSTI]

    BLACK THUNDER COAL MINE AND LOS ALAMOS NATIONAL LABORATORY EXPERIMENTAL STUDY OF SEISMIC ENERGY of Explosive Engineers, 2-5 Feb 97, Las Vegas, NV #12;BLACK THUNDER COAL MINE AND LOS ALAMOS NATIONAL and David Gross Thunder Basin Coal Company Post Office Box 406 Wright, Wyoming 82732 D. Craig Pearson

  16. Create a Consortium and Develop Premium Carbon Products from Coal

    SciTech Connect (OSTI)

    Frank Rusinko; John Andresen; Jennifer E. Hill; Harold H. Schobert; Bruce G. Miller

    2006-01-01T23:59:59.000Z

    The objective of these projects was to investigate alternative technologies for non-fuel uses of coal. Special emphasis was placed on developing premium carbon products from coal-derived feedstocks. A total of 14 projects, which are the 2003 Research Projects, are reported herein. These projects were categorized into three overall objectives. They are: (1) To explore new applications for the use of anthracite in order to improve its marketability; (2) To effectively minimize environmental damage caused by mercury emissions, CO{sub 2} emissions, and coal impounds; and (3) To continue to increase our understanding of coal properties and establish coal usage in non-fuel industries. Research was completed in laboratories throughout the United States. Most research was performed on a bench-scale level with the intent of scaling up if preliminary tests proved successful. These projects resulted in many potential applications for coal-derived feedstocks. These include: (1) Use of anthracite as a sorbent to capture CO{sub 2} emissions; (2) Use of anthracite-based carbon as a catalyst; (3) Use of processed anthracite in carbon electrodes and carbon black; (4) Use of raw coal refuse for producing activated carbon; (5) Reusable PACs to recycle captured mercury; (6) Use of combustion and gasification chars to capture mercury from coal-fired power plants; (7) Development of a synthetic coal tar enamel; (8) Use of alternative binder pitches in aluminum anodes; (9) Use of Solvent Extracted Carbon Ore (SECO) to fuel a carbon fuel cell; (10) Production of a low cost coal-derived turbostratic carbon powder for structural applications; (11) Production of high-value carbon fibers and foams via the co-processing of a low-cost coal extract pitch with well-dispersed carbon nanotubes; (12) Use of carbon from fly ash as metallurgical carbon; (13) Production of bulk carbon fiber for concrete reinforcement; and (14) Characterizing coal solvent extraction processes. Although some of the projects funded did not meet their original goals, the overall objectives of the CPCPC were completed as many new applications for coal-derived feedstocks have been researched. Future research in many of these areas is necessary before implementation into industry.

  17. Model documentation coal market module of the National Energy Modeling System

    SciTech Connect (OSTI)

    NONE

    1997-02-01T23:59:59.000Z

    This report documents the objectives and the conceptual and methodological approach used in the development of the Coal Production Submodule (CPS). It provides a description of the CPS for model analysts and the public. The Coal Market Module provides annual forecasts of prices, production, and consumption of coal.

  18. CHARACTERIZATION OF COAL COMBUSTION BY-PRODUCTS FOR THE RE-EVOLUTION OF MERCURY INTO ECOSYSTEMS

    SciTech Connect (OSTI)

    J.A. Withum; R.M. Statnick

    2001-09-01T23:59:59.000Z

    EPA and state environmental agencies are suggesting that mercury (Hg) in coal combustion by-products is re-emitted into local ecosystems by additional processing to final products (i.e., wallboard, etc.), by dissolution into groundwater, or by reactions with anaerobic bacteria. This perception may limit the opportunities to use coal combustion by-products in recycle/reuse applications. In this program, CONSOL Energy is conducting a comprehensive sampling and analytical program to address this concern. If the results of this work demonstrate that re-emissions of Hg from waste disposal and by-product utilization are over-stated, additional regulations regarding coal combustion, waste disposal, and waste material utilization will not be required. This will result in continued low energy cost that is beneficial to the national economy and stability of local economies that are dependent on coal. In this quarter, laboratory equipment was assembled and blank test runs were made, manufactured aggregate and spray dryer ash samples were collected and leached, and fly ash and FGD slurry samples from an Ohio bituminous coal-fired utility were collected for leaching.

  19. SYSTEM ANALYSIS OF NUCLEAR-ASSISTED SYNGAS PRODUCTION FROM COAL

    SciTech Connect (OSTI)

    E. A. Harvego; M. G. McKellar; J. E. O'Brien

    2008-09-01T23:59:59.000Z

    A system analysis has been performed to assess the efficiency and carbon utilization of a nuclear-assisted coal gasification process. The nuclear reactor is a high-temperature helium-cooled reactor that is used primarily to provide power for hydrogen production via high-temperature electrolysis. The supplemental hydrogen is mixed with the outlet stream from an oxygen-blown coal gasifier to produce a hydrogen-rich gas mixture, allowing most of the carbon dioxide to be converted into carbon monoxide, with enough excess hydrogen to produce a syngas product stream with a hydrogen/carbon monoxide molar ratio of about 2:1. Oxygen for the gasifier is also provided by the high-temperature electrolysis process. Results of the analysis predict 90.5% carbon utilization with a syngas production efficiency (defined as the ratio of the heating value of the produced syngas to the sum of the heating value of the coal plus the high-temperature reactor heat input) of 66.1% at a gasifier temperature of 1866 K for the high-moisture-content lignite coal considered. Usage of lower moisture coals such as bituminous can yield carbon utilization approaching 100% and 70% syngas production efficiency.

  20. Volcanic ash in feed coal and its influence on coal combustion products

    SciTech Connect (OSTI)

    Brownfield, M.E.; Affolter, R.H.; Cathcart, J.D.; Brownfield, I.K.; Hower, J.C.; Stricker, G.D.; O'Connor, J.T.

    2000-07-01T23:59:59.000Z

    The US Geological Survey and the University of Kentucky Center for Applied Energy Research are collaborating with an Indiana Utility to determine the physical and chemical properties of feed coal and coal combustion products (CCPs) from a coal-fired power plant. The plant utilizes a low-sulfur (.23--.47 weight percent S) coal from the Powder River Basin, Wyoming. Scanning Electron Microscope (SEM) and X-ray diffraction (XRD) analysis of feed coal samples identified two mineral suites. A primary suite (not authigenic) consisting of quartz (detrital and volcanic beta-form grains), biotite, and minor zircon and a secondary authigenic mineral suite containing calcite, alumino-phosphates (crandallite and gorceixite), kaolinite, quartz, anatase, barite, and pyrite. The authigenic minerals are attributed to air-fall and reworked volcanic ash that was deposited in peat-forming mires. The Powder River Basin feed coals contain higher amounts of Ba, Ca, Mg, Na, Sr, and P compared to other analyzed eastern coals. These elements are associated with alumino-phosphate, biotite, calcite, and clay minerals. The element associations are indicative of coal that incorporated volcanic ash during deposition. XRD analysis of CCPs revealed a predominance of glass, perovskite, lime, gehlenite, quartz, and phosphates with minor amounts of periclase, anhydrite, hematite, and spinel group minerals in the fly ash; and quartz, plagioclase (albite and anorthite), pyroxene (augite and fassaite), rhodonite, and akermanite in the bottom ash. Microprobe and SEM analysis of fly ash samples revealed quartz, zircon, monazite, euhedral laths of corundum with merrillite, hematite, dendritic spinels/ferrites, and rounded grains of wollastonite with periclase. The abundant Ca and Mg mineral phases in the fly ashes are related to the presence of carbonate, clay, and phosphate minerals in the feed coal. The Ca- and Mg-rich mineral phases in the CCPs can be attributed to volcanic minerals deposited in the peat-forming mire. Dissolution and alteration of these minerals occurred either in the peat-forming sate or during coalification/diagenesis contributing to the authigenic mineral suite. Additionally, detrital mineral input and epigenetic ground-water flow may have affected the geochemistry of the feed coal.

  1. Coal Combustion Products | Department of Energy

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directed offOCHCO OverviewAttachments4 Chairs Meeting - AprilEvents CleanSeattle, WAClosingClosure SitesCoal

  2. Coal Combustion Products | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't Your Destiny: Theof"Wave the White Flag" |Energysoil andClosure SitesCoal

  3. Hydrogen Production: Coal Gasification | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onYouTube YouTube Note: Since the.pdfBreaking of Blythe SolarContamination Detectorof EnergyCoal Gasification Hydrogen

  4. Ash reduction in clean coal spiral product circuits

    SciTech Connect (OSTI)

    Brodzik, P.

    2007-04-15T23:59:59.000Z

    The article describes the Derrick Corporation's Stack Sizer{trademark} technology for high capacity fine wet cleaning with long-lasting high open-area urethane screen panels. After field trials, a Stack Sizer fitted with a 100-micron urethane panel is currently processing approximately 40 stph of clean coal spiral product having about 20% ash at McCoy-Elkhorn's Bevin Branch coal preparation plant in Kentucky, USA. Product yield is about 32.5 short tons per hour with 10% ash. The material is then fed to screen bowl centrifuges for further processing. At Blue Diamond Coal's Leatherwood preparation plant similar Stacker Sizers are achieving the same results. 2 figs., 3 tabs., 2 photo.

  5. Production of jet fuels from coal-derived liquids

    SciTech Connect (OSTI)

    Johnson, R.W.; Zackro, W.C.; Czajkowski, G. (Allied-Signal, Inc., Des Plaines, IL (USA). Engineered Materials Research Center); Shah, P.P.; Kelly, A.P. (UOP, Inc., Des Plaines, IL (USA))

    1989-03-01T23:59:59.000Z

    The US Air Force is evaluating various feedstock sources of endothermic fuels. The technical feasibility of producing endothermic fuel from the naphtha by-product from Great Plains Gasification Plant in Beulah, North Dakota was evaluated. The capital and operating costs of deriving the fuel from coal naphtha were also estimated. The coal naphtha from Great Plains was successfully processed to remove sulfur, nitrogen and oxygen contaminants (UOP HD Unibon{reg sign} Hydrotreating) and then to saturate aromatic molecules (UOP AH Unibon{reg sign}). The AH Unibon product was fractionated to yield endothermic fuel candidates with less than 5% aromatics. The major cycloparaffins in the AH Unibon product were cyclohexane and methylcyclohexane. The production of endothermic fuel from the naphtha by-product stream was estimated to be cost competitive with existing technology. 17 figs., 23 tabs.

  6. State coal profiles, January 1994

    SciTech Connect (OSTI)

    Not Available

    1994-02-02T23:59:59.000Z

    The purpose of State Coal Profiles is to provide basic information about the deposits, production, and use of coal in each of the 27 States with coal production in 1992. Although considerable information on coal has been published on a national level, there is a lack of a uniform overview for the individual States. This report is intended to help fill that gap and also to serve as a framework for more detailed studies. While focusing on coal output, State Coal Profiles shows that the coal-producing States are major users of coal, together accounting for about three-fourths of total US coal consumption in 1992. Each coal-producing State is profiled with a description of its coal deposits and a discussion of the development of its coal industry. Estimates of coal reserves in 1992 are categorized by mining method and sulfur content. Trends, patterns, and other information concerning production, number of mines, miners, productivity, mine price of coal, disposition, and consumption of coal are detailed in statistical tables for selected years from 1980 through 1992. In addition, coal`s contribution to the State`s estimated total energy consumption is given for 1991, the latest year for which data are available. A US summary of all data is provided for comparing individual States with the Nation as a whole. Sources of information are given at the end of the tables.

  7. Lawrence Livermore National Laboratory Underground Coal Gasification project

    SciTech Connect (OSTI)

    Thorsness, C.B.; Britten, J.A.

    1989-10-15T23:59:59.000Z

    The Lawrence Livermore National Laboratory (LLNL) has been actively developing Underground Coal Gasification (UCG) technology for 15 years. The goal of the project has been to develop a fundamental technological understanding of UCG and foster the commercialization of the process. In striving to achieve this goal the LLNL project has carried out laboratory experiments, developed mathematical models, actively participated in technology transfer programs, and conducted field test experiments. As a result of this work the Controlled Retracting Injection Point (CRIP) concept was developed which helps insure optimum performance of an underground gasifier in a flat seam, and provides a means to produce multiple gasification cavities. The LLNL field work culminated in the Rocky Mountain I field test in which a gasifier using the CRIP technology generated gas of a quality equal to that of surface gasifiers. This last test and others preceding it have demonstrated beyond any reasonable doubt, that UCG is technically feasible in moderately thick coal seams at modest depths. 2 refs., 2 tabs.

  8. Integrated production/use of ultra low-ash coal, premium liquids and clean char

    SciTech Connect (OSTI)

    Kruse, C.W.

    1991-01-01T23:59:59.000Z

    This integrated, multi-product approach for utilizing Illinois coal starts with the production of ultra low-ash coal and then converts it to high-vale, coal-derived, products. The ultra low-ash coal is produced by solubilizing coal in a phenolic solvent under ChemCoal{trademark} process conditions, separating the coal solution from insoluble ash, and then precipitating the clean coal by dilution of the solvent with methanol. Two major products, liquids and low-ash char, are then produced by mild gasification of the low-ash coal. The low ash-char is further upgraded to activated char, and/or an oxidized activated char which has catalytic properties. Characterization of products at each stage is part of this project.

  9. Characterization of the chemical variation of feed coal and coal combustion products from a power plant utilizing low sulfur Powder River Basin coal

    SciTech Connect (OSTI)

    Affolter, R.H.; Brownfield, M.E.; Cathcart, J.D.; Brownfield, I.K.

    2000-07-01T23:59:59.000Z

    The US Geological Survey and the University of Kentucky Center for Applied Energy Research, in collaboration with an Indiana utility, are studying a coal-fired power plant burning Powder River Basin coal. This investigation involves a systematic study of the chemical and mineralogical characteristics of feed coal and coal combustion products (CCPs) from a 1,300-megawatt (MW) power unit. The main goal of this study is to characterize the temporal chemical variability of the feed coal, fly ash, and bottom ash by looking at the major-, minor-, and trace-element compositions and their associations with the feed coal mineralogy. Emphasis is also placed on the abundance and modes of occurrence of elements of potential environmental concern that may affect the utilization of these CCPs and coals.

  10. Imminence of peak in US coal production and overestimation of reserves Nathan G.F. Reaver a

    E-Print Network [OSTI]

    Khare, Sanjay V.

    Imminence of peak in US coal production and overestimation of reserves Nathan G.F. Reaver online 6 June 2014 Keywords: Logistic model Coal reserve Coal production forecast Peak coal USA energy Non-linear fitting Coal is the bulwark of US energy production making up about a third of all energy

  11. Biological production of ethanol from coal. Final report

    SciTech Connect (OSTI)

    Not Available

    1992-12-01T23:59:59.000Z

    Due to the abundant supply of coal in the United States, significant research efforts have occurred over the past 15 years concerning the conversion of coal to liquid fuels. Researchers at the University of Arkansas have concentrated on a biological approach to coal liquefaction, starting with coal-derived synthesis gas as the raw material. Synthesis gas, a mixture of CO, H{sub 2}, CO{sub 2}, CH{sub 4} and sulfur gases, is first produced using traditional gasification techniques. The CO, CO{sub 2} and H{sub 2} are then converted to ethanol using a bacterial culture of Clostridium 1jungdahlii. Ethanol is the desired product if the resultant product stream is to be used as a liquid fuel. However, under normal operating conditions, the ``wild strain`` produces acetate in favor of ethanol in conjunction with growth in a 20:1 molar ratio. Research was performed to determine the conditions necessary to maximize not only the ratio of ethanol to acetate, but also to maximize the concentration of ethanol resulting in the product stream.

  12. A novel coal feeder for production of low sulfur fuel

    SciTech Connect (OSTI)

    Khang, S.J.; Lin, L.; Keener, T.C.; Yeh, P.

    1991-01-01T23:59:59.000Z

    A dual-screw feeder was designed for desulfurization of coal. This reactor contains two screw tubes, the inner tube acting as a coal pyrolizer and the outer tube acting as a desulfurizer with hot calcined lime pellets or other renewable sorbent pellets. The objectives of this project is to study the feasibility of an advanced concept of desulfurization and possibly some denitrification in this coal feeder. In this year, two basic studies have been performed: (1) the desulfurization and (2) the denitrification due to mild pyrolysis. Specifically, the following tasks have been performed: (1) Setting up the Dual-Screw reactor, (2) Determination of the pyrolysis product and the sulfur distribution in char, tar and gas based on experimental data, (3) Study of the devolatilization, the desulfurization kinetics and the denitrification kinetics and obtaining the basic kinetic parameters, (4) Study of the sulfur removal efficiency of lime pellets fed into the outer tube of the dual-feeder reactor, (5) Study of the effect of the coal particle size on pyrolysis and desulfurization, (6) Study of the coal pyrolysis and desulfurization using a TGA(Thermal Gravimetric Analyzer).

  13. HTGR-INTEGRATED COAL TO LIQUIDS PRODUCTION ANALYSIS

    SciTech Connect (OSTI)

    Anastasia M Gandrik; Rick A Wood

    2010-10-01T23:59:59.000Z

    As part of the DOE’s Idaho National Laboratory (INL) nuclear energy development mission, the INL is leading a program to develop and design a high temperature gas-cooled reactor (HTGR), which has been selected as the base design for the Next Generation Nuclear Plant. Because an HTGR operates at a higher temperature, it can provide higher temperature process heat, more closely matched to chemical process temperatures, than a conventional light water reactor. Integrating HTGRs into conventional industrial processes would increase U.S. energy security and potentially reduce greenhouse gas emissions (GHG), particularly CO2. This paper focuses on the integration of HTGRs into a coal to liquids (CTL) process, for the production of synthetic diesel fuel, naphtha, and liquefied petroleum gas (LPG). The plant models for the CTL processes were developed using Aspen Plus. The models were constructed with plant production capacity set at 50,000 barrels per day of liquid products. Analysis of the conventional CTL case indicated a potential need for hydrogen supplementation from high temperature steam electrolysis (HTSE), with heat and power supplied by the HTGR. By supplementing the process with an external hydrogen source, the need to “shift” the syngas using conventional water-gas shift reactors was eliminated. HTGR electrical power generation efficiency was set at 40%, a reactor size of 600 MWth was specified, and it was assumed that heat in the form of hot helium could be delivered at a maximum temperature of 700°C to the processes. Results from the Aspen Plus model were used to perform a preliminary economic analysis and a life cycle emissions assessment. The following conclusions were drawn when evaluating the nuclear assisted CTL process against the conventional process: • 11 HTGRs (600 MWth each) are required to support production of a 50,000 barrel per day CTL facility. When compared to conventional CTL production, nuclear integration decreases coal consumption by 66% using electrolysis and nuclear power as the hydrogen source. In addition, nuclear integration decreases CO2 emissions by 84% if sequestration is assumed and 96% without sequestration, when compared to conventional CTL. • The preliminary economic assessment indicates that the incorporation of 11 HTGRs and the associated HTSEs impacts the expected return on investment, when compared to conventional CTL with or without sequestration. However, in a carbon constrained scenario, where CO2 emissions are taxed and sequestration is not an option, a reasonable CO2 tax would equate the economics of the nuclear assisted CTL case with the conventional CTL case. The economic results are preliminary, as they do not include economies of scale for multiple HTGRs and are based on an uncertain reactor cost estimate. Refinement of the HTGR cost estimate is currently underway. • To reduce well to wheel (WTW) GHG emissions below baseline (U.S. crude mix) or imported crude derived diesel, integration of an HTGR is necessary. WTW GHG emissions decrease 8% below baseline crude with nuclear assisted CTL. Even with CO2 sequestration, conventional CTL WTW GHG emissions are 24% higher than baseline crude emissions. • Current efforts are underway to investigate the incorporation of nuclear integrated steam methane reforming for the production of hydrogen, in place of HTSE. This will likely reduce the number of HTGRs required for the process.

  14. Biological production of ethanol from coal

    SciTech Connect (OSTI)

    Not Available

    1992-01-01T23:59:59.000Z

    Research is continuing in an attempt to increase both the ethanol concentration and product ratio using C. ljungdahlii. The purpose of this report is to present data utilizing a medium prepared especially for C. ljungdahlii. Medium development studies are presented, as well as reactor studies with the new medium in batch reactors. CSTRs and CSTRs with cell recycle. The use of this new medium has resulted in significant improvements in cell concentration, ethanol concentration and product ratio.

  15. RESEARCH ON CARBON PRODUCTS FROM COAL USING AN EXTRACTIVE PROCESS

    SciTech Connect (OSTI)

    Peter G. Stansberry; Alfred H. Stiller; John W. Zondlo; Chong Chen; Brian Bland; David Fenton

    2002-03-31T23:59:59.000Z

    This report presents the results of a one-year effort directed at the exploration of the use of coal as a feedstock for a variety of industrially-relevant carbon products. The work was basically divided into three focus areas. The first area dealt with the acquisition of laboratory equipment to aid in the analysis and characterization of both the raw coal and the coal-derived feedstocks. Improvements were also made on the coal-extraction pilot plant which will now allow larger quantities of feedstock to be produced. Mass and energy balances were also performed on the pilot plant in an attempt to evaluate the scale-up potential of the process. The second focus area dealt with exploring hydrogenation conditions specifically aimed at testing several less-expensive candidate hydrogen-donor solvents. Through a process of filtration and vacuum distillation, viable pitch products were produced and evaluated. Moreover, a recycle solvent was also isolated so that the overall solvent balance in the system could be maintained. The effect of variables such as gas pressure and gas atmosphere were evaluated. The pitch product was analyzed and showed low ash content, reasonable yield, good coking value and a coke with anisotropic optical texture. A unique plot of coke yield vs. pitch softening point was discovered to be independent of reaction conditions or hydrogen-donor solvent. The third area of research centered on the investigation of alternate extraction solvents and processing conditions for the solvent extraction step. A wide variety of solvents, co-solvents and enhancement additives were tested with varying degrees of success. For the extraction of raw coal, the efficacy of the alternate solvents when compared to the benchmark solvent, N-methyl pyrrolidone, was not good. However when the same coal was partially hydrogenated prior to solvent extraction, all solvents showed excellent results even for extractions performed at room temperature. Standard analyses of the extraction products indicated that they had the requisite properties of viable carbon-product precursors.

  16. CO2 gas production understanding above a partly flooded coal post-mining area

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    - The Westphalian deposit is constituted by numerous exploited coal seams of different thicknesses. These seamsCO2 gas production understanding above a partly flooded coal post-mining area Candice Lagnya, a former coal mining area. To understand the origin of this production, a borehole of 90 meters deep

  17. Assessment of underground coal gasification in bituminous coals: catalog of bituminous coals and site selection. Appendix A. National coal resource data system: Ecoal, Wcoal, and Bmalyt. Final report, Phase I. [Bituminous coal; by state; coal seam depth and thickness; identification

    SciTech Connect (OSTI)

    None

    1982-01-31T23:59:59.000Z

    Appendix A is a catalog of the bituminous coal in 29 states of the contiguous United States which contain identified bituminous coal resources.

  18. Low-rank coal oil agglomeration product and process

    DOE Patents [OSTI]

    Knudson, Curtis L. (Grand Forks, ND); Timpe, Ronald C. (Grand Forks, ND); Potas, Todd A. (Plymouth, MN); DeWall, Raymond A. (Grand Forks, ND); Musich, Mark A. (Grand Forks, ND)

    1992-01-01T23:59:59.000Z

    A selectively-sized, raw, low-rank coal is processed to produce a low ash and relative water-free agglomerate with an enhanced heating value and a hardness sufficient to produce a non-decrepitating, shippable fuel. The low-rank coal is treated, under high shear conditions, in the first stage to cause ash reduction and subsequent surface modification which is necessary to facilitate agglomerate formation. In the second stage the treated low-rank coal is contacted with bridging and binding oils under low shear conditions to produce agglomerates of selected size. The bridging and binding oils may be coal or petroleum derived. The process incorporates a thermal deoiling step whereby the bridging oil may be completely or partially recovered from the agglomerate; whereas, partial recovery of the bridging oil functions to leave as an agglomerate binder, the heavy constituents of the bridging oil. The recovered oil is suitable for recycling to the agglomeration step or can serve as a value-added product.

  19. Low-rank coal oil agglomeration product and process

    DOE Patents [OSTI]

    Knudson, C.L.; Timpe, R.C.; Potas, T.A.; DeWall, R.A.; Musich, M.A.

    1992-11-10T23:59:59.000Z

    A selectively-sized, raw, low-rank coal is processed to produce a low ash and relative water-free agglomerate with an enhanced heating value and a hardness sufficient to produce a non-degradable, shippable fuel. The low-rank coal is treated, under high shear conditions, in the first stage to cause ash reduction and subsequent surface modification which is necessary to facilitate agglomerate formation. In the second stage the treated low-rank coal is contacted with bridging and binding oils under low shear conditions to produce agglomerates of selected size. The bridging and binding oils may be coal or petroleum derived. The process incorporates a thermal deoiling step whereby the bridging oil may be completely or partially recovered from the agglomerate; whereas, partial recovery of the bridging oil functions to leave as an agglomerate binder, the heavy constituents of the bridging oil. The recovered oil is suitable for recycling to the agglomeration step or can serve as a value-added product.

  20. U.S. monthly coal production increases

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001)gasoline prices continueshort

  1. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    SciTech Connect (OSTI)

    Leslie R. Rudnick; Andre Boehman; Chunshan Song; Bruce Miller; John Andresen

    2004-09-17T23:59:59.000Z

    This report summarizes the accomplishments toward project goals during the first twelve months of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Coal samples have procured and are being assessed for cleaning prior to use in coking studies.

  2. REFINERY INTEGRATION OF BY-PRODUCTS FROM COAL-DERIVED JET FUELS

    SciTech Connect (OSTI)

    Leslie R. Rudnick; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2005-05-18T23:59:59.000Z

    This report summarizes the accomplishments toward project goals during the first six months of the second year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Coal samples have procured and are being assessed for cleaning prior to use in coking studies.

  3. REFINERY INTEGRATION OF BY-PRODUCTS FROM COAL-DERIVED JET FUELS

    SciTech Connect (OSTI)

    Leslie R. Rudnick; Andre Boehman; Chunshan Song; Bruce Miller; John Andresen

    2004-04-23T23:59:59.000Z

    This report summarizes the accomplishments toward project goals during the first six months of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Coal samples have procured and are being assessed for cleaning prior to use in coking studies.

  4. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    SciTech Connect (OSTI)

    Leslie R. Rudnick; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2005-11-17T23:59:59.000Z

    This report summarizes the accomplishments toward project goals during the first six months of the second year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Evaluations to assess the quality of coal based fuel oil are reported. Coal samples have procured and are being assessed for cleaning prior to use in coking studies.

  5. Estimating long-term world coal production with logit and probit transforms David Rutledge

    E-Print Network [OSTI]

    Weinreb, Sander

    from measurements of coal seams. We show that where the estimates based on reserves can be testedEstimating long-term world coal production with logit and probit transforms David Rutledge form 27 October 2010 Accepted 27 October 2010 Available online 4 November 2010 Keywords: Coal reserves

  6. Market assessment of environmental issues affecting coal use for Los Alamos National Laboratory

    SciTech Connect (OSTI)

    NONE

    1995-03-20T23:59:59.000Z

    This is a market assessment of environmental issues affecting coal use through 2020. It was prepared by Los Alamos National Laboratories for the Fossil Energy R&D Program. It is based on interviews of representatives of 8 coal, coal technology, electricity and environmental groups concerned with the future of energy and the environment. Interviewees generally agreed that the U.S. and other countries would continue to need to use coal into the middle of the next century. The size of the market for coal would be determined by the ability of coal and coal technologies to meet environmental requirements at costs that would compete with natural gas. Outside the U.S., three interviewees suggested that there is a market for low cost coal technologies that will reduce the environmental impact of coal use, particularly in developing countries that have few alternative sources of energy. The principal environmental concerns mentioned in these interviews were: efficiency and carbon, air toxics, and NO{sub x}. Several also mentioned potential modifications to the SO{sub x} standards, a fine particulate standard, bottom and fly ash, and methane from coalbeds.

  7. Product Characterization for Entrained Flow Coal/Biomass Co-Gasification

    SciTech Connect (OSTI)

    Shawn Maghzi; Ramanathan Subramanian; George Rizeq; Surinder Singh; John McDermott; Boris Eiteneer; David Ladd; Arturo Vazquez; Denise Anderson; Noel Bates

    2011-09-30T23:59:59.000Z

    The U.S. Department of Energyâ??s National Energy Technology Laboratory (DOE NETL) is exploring affordable technologies and processes to convert domestic coal and biomass resources to high-quality liquid hydrocarbon fuels. This interest is primarily motivated by the need to increase energy security and reduce greenhouse gas emissions in the United States. Gasification technologies represent clean, flexible and efficient conversion pathways to utilize coal and biomass resources. Substantial experience and knowledge had been developed worldwide on gasification of either coal or biomass. However, reliable data on effects of blending various biomass fuels with coal during gasification process and resulting syngas composition are lacking. In this project, GE Global Research performed a complete characterization of the gas, liquid and solid products that result from the co-gasification of coal/biomass mixtures. This work was performed using a bench-scale gasifier (BSG) and a pilot-scale entrained flow gasifier (EFG). This project focused on comprehensive characterization of the products from gasifying coal/biomass mixtures in a high-temperature, high-pressure entrained flow gasifier. Results from this project provide guidance on appropriate gas clean-up systems and optimization of operating parameters needed to develop and commercialize gasification technologies. GEâ??s bench-scale test facility provided the bulk of high-fidelity quantitative data under temperature, heating rate, and residence time conditions closely matching those of commercial oxygen-blown entrained flow gasifiers. Energy and Environmental Research Center (EERC) pilot-scale test facility provided focused high temperature and pressure tests at entrained flow gasifier conditions. Accurate matching of syngas time-temperature history during cooling ensured that complex species interactions including homogeneous and heterogeneous processes such as particle nucleation, coagulation, surface condensation, and gas-phase reactions were properly reproduced and lead to representative syngas composition at the syngas cooler outlet. The experimental work leveraged other ongoing GE R&D efforts such as biomass gasification and dry feeding systems projects. Experimental data obtained under this project were used to provide guidance on the appropriate clean-up system(s) and operating parameters to coal and biomass combinations beyond those evaluated under this project.

  8. Product Characterization for Entrained Flow Coal/Biomass Co-Gasification

    SciTech Connect (OSTI)

    Maghzi, Shawn; Subramanian, Ramanathan; Rizeq, George; Singh, Surinder; McDermott, John; Eiteneer, Boris; Ladd, David; Vazquez, Arturo; Anderson, Denise; Bates, Noel

    2011-09-30T23:59:59.000Z

    The U.S. Department of Energy‘s National Energy Technology Laboratory (DOE NETL) is exploring affordable technologies and processes to convert domestic coal and biomass resources to high-quality liquid hydrocarbon fuels. This interest is primarily motivated by the need to increase energy security and reduce greenhouse gas emissions in the United States. Gasification technologies represent clean, flexible and efficient conversion pathways to utilize coal and biomass resources. Substantial experience and knowledge had been developed worldwide on gasification of either coal or biomass. However, reliable data on effects of blending various biomass fuels with coal during gasification process and resulting syngas composition are lacking. In this project, GE Global Research performed a complete characterization of the gas, liquid and solid products that result from the co-gasification of coal/biomass mixtures. This work was performed using a bench-scale gasifier (BSG) and a pilot-scale entrained flow gasifier (EFG). This project focused on comprehensive characterization of the products from gasifying coal/biomass mixtures in a high-temperature, high-pressure entrained flow gasifier. Results from this project provide guidance on appropriate gas clean-up systems and optimization of operating parameters needed to develop and commercialize gasification technologies. GE‘s bench-scale test facility provided the bulk of high-fidelity quantitative data under temperature, heating rate, and residence time conditions closely matching those of commercial oxygen-blown entrained flow gasifiers. Energy and Environmental Research Center (EERC) pilot-scale test facility provided focused high temperature and pressure tests at entrained flow gasifier conditions. Accurate matching of syngas time-temperature history during cooling ensured that complex species interactions including homogeneous and heterogeneous processes such as particle nucleation, coagulation, surface condensation, and gas-phase reactions were properly reproduced and lead to representative syngas composition at the syngas cooler outlet. The experimental work leveraged other ongoing GE R&D efforts such as biomass gasification and dry feeding systems projects. Experimental data obtained under this project were used to provide guidance on the appropriate clean-up system(s) and operating parameters to coal and biomass combinations beyond those evaluated under this project.

  9. Steamship operator's thoughts on national dredging situation. [For coal-exporting ports

    SciTech Connect (OSTI)

    Hill, J.N.

    1983-01-01T23:59:59.000Z

    The present depths of US coal-exporting ports are inadequate to permit handling of large, economically-sized bulkers. Because of this, the relative appeal of US coal to importers is considerably lessened. Several solutions are offered: coal-slurry pipelines, draft-assisted delivery systems, land based top-off stations, top-off concept, and a national dredging program. Although the topping-off alternative seems to be a viable means of addressing the problem, it should not be thought of as the ANSWER, but rather as a logical, cost effective interim method. Both top-off and dredging are needed to effectively address this issue. The author concludes that no matter how difficult bringing about a national dredging program may be, it must be done, for only through dredging can we achieve full optimization of our market potential in coal export.

  10. The Clean Coal Technology Demonstration Program is a $5-billion national

    E-Print Network [OSTI]

    unknown authors

    commitment, cost-shared by the Government and the private sector, to demonstrate economic and environmentally sound methods for using our Nation's most abundant energy resource. The Program will foster the energy efficient use of the Nation's vast coal resource base. By doing so, the Program will contribute significantly to the long-term energy security of the United States, will further the Nation's objectives for a cleaner environment, and will improve its competitive standing in the international energy market. The first three Clean Coal Technology solicitations were issued in 1986, 1988,

  11. DEVELOPMENT OF CONTINUOUS SOLVENT EXTRACTION PROCESSES FOR COAL DERIVED CARBON PRODUCTS

    SciTech Connect (OSTI)

    Elliot B. Kennel; Chong Chen; Dady Dadyburjor; Liviu Magean; Peter G. Stansberry; Alfred H. Stiller; John W. Zondlo

    2005-07-13T23:59:59.000Z

    The purpose of this DOE-funded effort is to develop continuous processes for solvent extraction of coal for the production of carbon products. These carbon products include materials used in metals smelting, especially in the aluminum and steel industries, as well as porous carbon structural material referred to as ''carbon foam'' and carbon fibers. The Hydrotreatment Facility is being prepared for trials with coal liquids. Raw coal tar distillate trials have been carried out by heating coal tar in the holding tank in the Hydrotreatment Facility. The liquids are centrifuged to warm the system up in preparation for the coal liquids. The coal tar distillate is then recycled to keep the centrifuge hot. In this way, the product has been distilled such that a softening point of approximately 110 C is reached. Then an ash test is conducted.

  12. Assessment of underground coal gasification in bituminous coals: potential UCG products and markets. Final report, Phase I

    SciTech Connect (OSTI)

    None

    1982-01-31T23:59:59.000Z

    The following conclusions were drawn from the study: (1) The US will continue to require new sources of energy fuels and substitutes for petrochemical feedstocks into the foreseeable future. Most of this requirement will be met using coal. However, the cost of mining, transporting, cleaning, and preparing coal, disposing of ash or slag and scrubbing stack gases continues to rise; particularly, in the Eastern US where the need is greatest. UCG avoids these pitfalls and, as such, should be considered a viable alternative to the mining of deeper coals. (2) Of the two possible product gases LBG and MBG, MBG is the most versatile. (3) The most logical use for UCG product in the Eastern US is to generate power on-site using a combined-cycle or co-generation system. Either low or medium Btu gas (LBG or MBG) can be used. (4) UCG should be an option whenever surface gasification is considered; particularly, in areas where deeper, higher sulfur coal is located. (5) There are environmental and social benefits to use of UCG over surface gasification in the Eastern US. (6) A site could be chosen almost anywhere in the Illinois and Ohio area where amenable UCG coal has been determined due to the existence of existing transportation or transmission systems. (7) The technology needs to be demonstrated and the potential economic viability determined at a site in the East-North-Central US which has commercial quantities of amenable bituminous coal before utilities will show significant interest.

  13. Coal precursors for production of carbon and graphite products. Final report

    SciTech Connect (OSTI)

    Lewis, I.C.; Lewis, R.T.; Mayer, H.K. [Ucar Carbon Co., Inc., Parma, OH (United States)

    1996-04-08T23:59:59.000Z

    The main goal of this program was to demonstrate the utility of coal extracts from the West Virginia University (WVU) extraction process as suitable base raw materials for the carbon products encompassed by the Carbon Products Consortium (CPC) team. These include binder and impregnation pitches, Coke for graphite electrodes, Cokes for anodes and specialty graphite, matrices for C/C composites and raw material for mesophase pitch fibers. Previous work in this program has shown that the WVU coal extraction process coupled with hydrotreatment, does have the potential for achieving this objective. The current effort involved screening and evaluation of extracts produced by the WVU Group and recommending appropriate materials for scaleup for subsequent evaluation by Consortium Team members. The program involved an initial characterization of small-scale extracts using standard analytical methods and mesophase formation studies. This was followed by feedback to the WVU Group and to the CPC partners with recommendation of material for scaleup. Similar analytical and mesophase studies on some of the scaled-up extracts was performed. The activation of the coal extraction residues for the purpose of producing a useful active carbon was investigated. A further task was to fabricate a small graphite artifact using Coke derived from coal extract as the filler and the coal extract itself as a binder. The results of the studies are summarized in this report.

  14. CATALYTIC CONVERSION OF SOLVENT REFINED COAL TO LIQUID PRODUCTS

    E-Print Network [OSTI]

    Tanner, K.I.

    2010-01-01T23:59:59.000Z

    3-3. IH-NMR spectrum of Asphaltenes Soxhlet extracted fromThe Nature and Origin of Asphaltenes in Processed Coals,"Nature and Origin of Asphaltenes in Processed Coals - The

  15. Oxidation of Mercury in Products of Coal Combustion

    SciTech Connect (OSTI)

    Peter Walsh; Giang Tong; Neeles Bhopatkar; Thomas Gale; George Blankenship; Conrad Ingram; Selasi Blavo Tesfamariam Mehreteab; Victor Banjoko; Yohannes Ghirmazion; Heng Ban; April Sibley

    2009-09-14T23:59:59.000Z

    Laboratory measurements of mercury oxidation during selective catalytic reduction (SCR) of nitric oxide, simulation of pilot-scale measurements of mercury oxidation and adsorption by unburned carbon and fly ash, and synthesis of new materials for simultaneous oxidation and adsorption of mercury, were performed in support of the development of technology for control of mercury emissions from coal-fired boilers and furnaces. Conversion of gas-phase mercury from the elemental state to water-soluble oxidized form (HgCl{sub 2}) enables removal of mercury during wet flue gas desulfurization. The increase in mercury oxidation in a monolithic V{sub 2}O{sub 5}-WO{sub 3}/TiO{sub 2} SCR catalyst with increasing HCl at low levels of HCl (< 10 ppmv) and decrease in mercury oxidation with increasing NH{sub 3}/NO ratio during SCR were consistent with results of previous work by others. The most significant finding of the present work was the inhibition of mercury oxidation in the presence of CO during SCR of NO at low levels of HCl. In the presence of 2 ppmv HCl, expected in combustion products from some Powder River Basin coals, an increase in CO from 0 to 50 ppmv reduced the extent of mercury oxidation from 24 {+-} 3 to 1 {+-} 4%. Further increase in CO to 100 ppmv completely suppressed mercury oxidation. In the presence of 11-12 ppmv HCl, increasing CO from 0 to {approx}120 ppmv reduced mercury oxidation from {approx}70% to 50%. Conversion of SO{sub 2} to sulfate also decreased with increasing NH{sub 3}/NO ratio, but the effects of HCl and CO in flue gas on SO{sub 2} oxidation were unclear. Oxidation and adsorption of mercury by unburned carbon and fly ash enables mercury removal in a particulate control device. A chemical kinetic mechanism consisting of nine homogeneous and heterogeneous reactions for mercury oxidation and removal was developed to interpret pilot-scale measurements of mercury oxidation and adsorption by unburned carbon and fly ash in experiments at pilot scale, burning bituminous coals (Gale, 2006) and blends of bituminous coals with Powder River Basin coal (Gale, 2005). The removal of mercury by fly ash and unburned carbon in the flue gas from combustion of the bituminous coals and blends was reproduced with satisfactory accuracy by the model. The enhancement of mercury capture in the presence of calcium (Gale, 2005) explained a synergistic effect of blending on mercury removal across the baghouse. The extent of mercury oxidation, on the other hand, was not so well described by the simulation, because of oversensitivity of the oxidation process in the model to the concentration of unburned carbon. Combined catalysts and sorbents for oxidation and removal of mercury from flue gas at low temperature were based on surfactant-templated silicas containing a transition metal and an organic functional group. The presence of both metal ions and organic groups within the pore structure of the materials is expected to impart to them the ability to simultaneously oxidize elemental mercury and adsorb the resulting oxidized mercury. Twelve mesoporous organosilicate catalysts/sorbents were synthesized, with and without metals (manganese, titanium, vanadium) and organic functional groups (aminopropyl, chloropropyl, mercaptopropyl). Measurement of mercury oxidation and adsorption by the candidate materials remains for future work.

  16. Process for the production of fuel gas from coal

    DOE Patents [OSTI]

    Patel, Jitendra G. (Bolingbrook, IL); Sandstrom, William A. (Chicago, IL); Tarman, Paul B. (Elmhurst, IL)

    1982-01-01T23:59:59.000Z

    An improved apparatus and process for the conversion of hydrocarbonaceous materials, such as coal, to more valuable gaseous products in a fluidized bed gasification reaction and efficient withdrawal of agglomerated ash from the fluidized bed is disclosed. The improvements are obtained by introducing an oxygen containing gas into the bottom of the fluidized bed through a separate conduit positioned within the center of a nozzle adapted to agglomerate and withdraw the ash from the bottom of the fluidized bed. The conduit extends above the constricted center portion of the nozzle and preferably terminates within and does not extend from the nozzle. In addition to improving ash agglomeration and withdrawal, the present invention prevents sintering and clinkering of the ash in the fluidized bed and permits the efficient recycle of fine material recovered from the product gases by contacting the fines in the fluidized bed with the oxygen as it emanates from the conduit positioned within the withdrawal nozzle. Finally, the present method of oxygen introduction permits the efficient recycle of a portion of the product gases to the reaction zone to increase the reducing properties of the hot product gas.

  17. Production of High Quality Dust Control Foam to Minimize Moisture Addition to Coal

    E-Print Network [OSTI]

    Termine, F.; Jordan, S. T.

    PRODUCTION OF HIGH QUALITY DUST CONTROL FOAM TO MINIMIZE MOISTURE ADDITION TO COAL Frank Tenni ne Steve T. Jordan BETZ Laboratories, Trevose, PA Inc. ABSTRACT Foam is displacing wet suppression as the method of choice for controlling... fugitive emissions from coal. Coal treated by wet suppression consumes through moisture addition, a heat energy equivalent of 1 ton out of every 500 tons fired. The application of foam requires less than 10% of the moisture usually required for wet...

  18. DEVELOPMENT OF ACTIVATED CARBONS FROM COAL COMBUSTION BY-PRODUCTS

    SciTech Connect (OSTI)

    Harold H. Schobert; M. Mercedes Maroto-Valer; Zhe Lu

    2003-09-30T23:59:59.000Z

    The increasing role of coal as a source of energy in the 21st century will demand environmental and cost-effective strategies for the use of coal combustion by-products (CCBPs), mainly unburned carbon in fly ash. Unburned carbon is nowadays regarded as a waste product and its fate is mainly disposal, due to the present lack of efficient routes for its utilization. However, unburned carbon is a potential precursor for the production of adsorbent carbons, since it has gone through a devolatilization process while in the combustor, and therefore, only requires to be activated. Accordingly, the principal objective of this work was to characterize and utilize the unburned carbon in fly ash for the production of activated carbons. The unburned carbon samples were collected from different combustion systems, including pulverized utility boilers, a utility cyclone, a stoker, and a fluidized bed combustor. LOI (loss-on-ignition), proximate, ultimate, and petrographic analyses were conducted, and the surface areas of the samples were characterized by N2 adsorption isotherms at 77K. The LOIs of the unburned carbon samples varied between 21.79-84.52%. The proximate analyses showed that all the samples had very low moisture contents (0.17 to 3.39 wt %), while the volatile matter contents varied between 0.45 to 24.82 wt%. The elemental analyses show that all the unburned carbon samples consist mainly of carbon with very little hydrogen, nitrogen, sulfur and oxygen In addition, the potential use of unburned carbon as precursor for activated carbon (AC) was investigated. Activated carbons with specific surface area up to 1075m{sup 2}/g were produced from the unburned carbon. The porosity of the resultant activated carbons was related to the properties of the unburned carbon feedstock and the activation conditions used. It was found that not all the unburned carbon samples are equally suited for activation, and furthermore, their potential as activated carbons precursors could be inferred from their physical and chemical properties. The developed porosity of the activated carbon was a function of the oxygen content, porosity and H/C ratio of the parent unburned carbon feedstock. It was observed that extended activation times and high activation temperatures increased the porosity of the produced activated carbon at the expense of the solid yield. The development of activated carbon from unburned carbon in fly ash has been proven to be a success by this study in terms of the higher surface areas of the resultant activated carbons, which are comparable with commercial activated carbons. However, unburned carbon samples obtained from coal-fired power plants as by-product have high ash content, which is unwanted for the production of activated carbons. Therefore, the separation of unburned carbon from the fly ash is expected to be beneficial for the utilization of unburned carbon to produce activated carbons with low ash content.

  19. Kinetics of coal conversion to soluble products. Final technical report

    SciTech Connect (OSTI)

    Larsen, J.W.

    1994-04-12T23:59:59.000Z

    The objectives of this work are (1) to measure the kinetics of the conversion of coals to soluble products under model liquefaction conditions using GPS techniques to count the number of bonds broken; (2) to analyze these data using kinetic schemes based on the behavior of crosslinked macromolecular networks. The product was Soxhlet extracted with pyridine until the pyridine solution was clear. A gel permeation chromatogram of the pyridine soluble is shown in Figure 2A. The improved mass sensitive detector system requires only about 500 ng to acquire a chromatogram having fairly good S/N ratio. Apparently, no disturbance is caused by the remaining tetralin and naphthalene formed by dehydrogenation of tetralin. These seriously affect the lower molecular weight region when IR or UV detectors are used. It is a notable advantage of the mass sensitive detector that suitable adjustment of the nebulizer and of the evaporator completely suppressed the contribution of solvent to the chromatogram. The molecular weight distribution of liquefaction product appears to be almost unimodal if the small shoulder at the lower elution volume side is neglected.

  20. Coal exports and port development: a technical memorandum. [USA; Coal production and exports; 1945 to 1980

    SciTech Connect (OSTI)

    Not Available

    1981-04-01T23:59:59.000Z

    This technical memorandum addresses four major issues which are important to Federal policy debates currently before Congress: (1) estimating the potential US coal export market; (2) development of foreign trade policy; (3) the Federal role in dredging harbors; and (4) the outlook for alternative technologies. This analysis indicates that sizable increases in future US coal exports are achievable if the Federal Government and the private sector complement the efforts of each in encouraging these exports and if present trends are not drastically altered by developments in other exporting and importing countries. Without a coherent, positive policy, the United States could lose a substantial share of the future coal export market.

  1. Determining coal permeabilities through constant pressure production interference testing

    E-Print Network [OSTI]

    Schubarth, Stephen Kurt

    1983-01-01T23:59:59.000Z

    Kurt Schubarth, B. S. , Texas A&M Un1versity Chairman of Advisory Committee: Dr. Stephen A. Holditch The determination of format1on propert1es 1s important to the success of any underground coal gasification (UCG) project. There are many ways.... : "Hydrological Site Characterization for In-Situ Coal Gasification, " 6th Underground Coal Conversion Symposium, July 13-17, 1980. Schrider, L. A. and Jennings, J. W. : "An Underground Coal Gasification Experiment, Hanna, Wyoming, " 1974, SPE 4993. 3. van...

  2. Coal industry annual 1994

    SciTech Connect (OSTI)

    NONE

    1995-10-01T23:59:59.000Z

    This report presents data on coal consumption, distribution, coal stocks, quality, prices, coal production information, and emissions for a wide audience.

  3. Coal flow aids reduce coke plant operating costs and improve production rates

    SciTech Connect (OSTI)

    Bedard, R.A.; Bradacs, D.J.; Kluck, R.W.; Roe, D.C.; Ventresca, B.P.

    2005-06-01T23:59:59.000Z

    Chemical coal flow aids can provide many benefits to coke plants, including improved production rates, reduced maintenance and lower cleaning costs. This article discusses the mechanisms by which coal flow aids function and analyzes several successful case histories. 2 refs., 10 figs., 1 tab.

  4. Coal gasification power generation, and product market study. Topical report, March 1, 1995--March 31, 1996

    SciTech Connect (OSTI)

    Sheesley, D.; King, S.B.

    1998-12-31T23:59:59.000Z

    This Western Research Institute (WRI) project was part of a WRI Energy Resource Utilization Program to stimulate pilot-scale improved technologies projects to add value to coal resources in the Rocky Mountain region. The intent of this program is to assess the application potential of emerging technologies to western resources. The focus of this project is on a coal resource near the Wyoming/Colorado border, in Colorado. Energy Fuels Corporation/Kerr Coal Company operates a coal mine in Jackson County, Colorado. The coal produces 10,500 Btu/lb and has very low sulfur and ash contents. Kerr Coal Company is seeking advanced technology for alternate uses for this coal. This project was to have included a significant cost-share from the Kerr Coal Company ownership for a market survey of potential products and technical alternatives to be studied in the Rocky Mountain Region. The Energy Fuels Corporation/Kerr Coal Company and WRI originally proposed this work on a cost reimbursable basis. The total cost of the project was priced at $117,035. The Kerr Coal Company had scheduled at least $60,000.00 to be spent on market research for the project that never developed because of product market changes for the company. WRI and Kerr explored potential markets and new technologies for this resource. The first phase of this project as a preliminary study had studied fuel and nonfuel technical alternatives. Through related projects conducted at WRI, resource utilization was studied to find high-value materials that can be targeted for fuel and nonfuel use and eventually include other low-sulfur coals in the Rocky Mountain region. The six-month project work was spread over about a three-year period to observe, measure, and confirm over time-any trends in technology development that would lead to economic benefits in northern Colorado and southern Wyoming from coal gasification and power generation.

  5. WABASH RIVER INTEGRATED METHANOL AND POWER PRODUCTION FROM CLEAN COAL TECHNOLOGIES (IMPPCCT)

    SciTech Connect (OSTI)

    Albert Tsang

    2003-03-14T23:59:59.000Z

    The Wabash River Integrated Methanol and Power Production from Clean Coal Technologies (IMPPCCT) project is evaluating integrated electrical power generation and methanol production through clean coal technologies. The project is conducted by a multi-industry team lead by Gasification Engineering Corporation (GEC), and supported by Air Products and Chemicals, Inc., Dow Chemical Company, Dow Corning Corporation, Methanex Corporation, and Siemens Westinghouse Power Corporation. Three project phases are planned for execution, including: (1) Feasibility study and conceptual design for an integrated demonstration facility, and for fence-line commercial embodiment plants (CEP) operated at Dow Chemical or Dow Corning chemical plant locations (2) Research, development, and testing (RD&T) to define any technology gaps or critical design and integration issues (3) Engineering design and financing plan to install an integrated commercial demonstration facility at the existing Wabash River Energy Limited (WREL) plant in West Terre Haute, Indiana. The WREL facility is a project selected and co-funded under the Round IV of the United States Department of Energy's (DOE's) Clean Coal Technology Program. In this project, coal and/or other solid fuel feedstocks are gasified in an oxygen-blown, entrained-flow gasifier with continuous slag removal and a dry particulate removal system. The resulting product synthesis gas is used to fuel a combustion turbine generator whose exhaust is integrated with a heat recovery steam generator to drive a refurbished steam turbine generator. The gasifier uses technology initially developed by The Dow Chemical Company (the Destec Gasification Process), and now offered commercially by Global Energy, Inc., parent company of GEC and WREL, as the E-GAS{trademark} technology. In a joint effort with the DOE, a Cooperative Agreement was awarded under the Early Entrance Coproduction Plant (EECP) solicitation. GEC and an Industrial Consortium are investigating the use of synthesis gas produced by the E-GAS{trademark} technology in a coproduction environment to enhance the efficiency and productivity of solid fuel gasification combined cycle power plants. The objectives of this effort are to determine the feasibility of an EECP located at a specific site which produces some combination of electric power (or heat), fuels, and/or chemicals from synthesis gas derived from coal, or, coal in combination with some other carbonaceous feedstock. The project's intended result is to provide the necessary technical, economic, and environmental information that will be needed to move the EECP forward to detailed design, construction, and operation by industry. During the reporting period, effort continues on identifying potential technologies for removing contaminants from synthesis gas to the level required by methanol synthesis. A liquid phase Claus process and a direct sulfur oxidation process were evaluated. Preliminary discussion was held with interested parties on cooperating on RD&T in Phase II of the project. Also, significant progress was made during the period in the submission of project deliverables. A meeting was held at DOE's National Energy Technology Laboratory in Morgantown between GEC and the DOE IMPPCCT Project Manager on the status of the project, and reached an agreement on the best way to wrap up Phase I and transition into the Phase II RD&T. Potential projects for the Phase II, cost, and fund availability were also discussed.

  6. Coal-bed methane production in eastern Kansas: Its potential and restraints

    SciTech Connect (OSTI)

    Stoeckinger, B.T.

    1989-08-01T23:59:59.000Z

    In 1921 and again in 1988, workers demonstrated that the high volatile A and B coals of the Pennsylvanian Cherokee Group can be produced economically from vertically drilled holes, and that some of these coals have a gas content as high as 200 ft{sup 3}/ton. Detailed subsurface mapping on a county-by-county basis using geophysical logs shows the Weir coal seam to be the thickest (up to 6 ft thick) and to exist in numerous amoeba-shaped pockets covering several thousand acres. Lateral pinch-out into deltaic sands offers a conventional gas source. New attention to geophysical logging shows most coals have a negative SP response, high resistivities, and densities of 1.6 g/cm{sup 3}. Highly permeable coals cause lost circulation during drilling and thief zones during cementing, and they are the source of abundant unwanted salt water. Low-permeability coals can be recognized by their high fracture gradients, which are difficult to explain but are documented to exceed 2.2. Current successful completions use both limited-entry, small-volume nitrogen stimulations or an open hole below production casing. Subsurface coals are at normal Mid-Continent pressures and may be free of water. Initially, some wells flow naturally without pumping. Saltwater disposal is often helped by the need for water in nearby waterflood projects and the easy availability of state-approved saltwater disposal wells in Mississippi and Arbuckle carbonates. Recent attempts to recomplete coal zones in slim-hole completions are having mixed results. The major restraints to coal-bed methane production are restricted to low permeability of the coals and engineering problems, not to the availability or gas content of the coals.

  7. Sandia National Laboratories: hydrogen production

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    production High-Efficiency Solar Thermochemical Reactor for Hydrogen Production On July 9, 2014, in Center for Infrastructure Research and Innovation (CIRI), Concentrating Solar...

  8. Heat removal from high temperature tubular solid oxide fuel cells utilizing product gas from coal gasifiers.

    SciTech Connect (OSTI)

    Parkinson, W. J. (William Jerry),

    2003-01-01T23:59:59.000Z

    In this work we describe the results of a computer study used to investigate the practicality of several heat exchanger configurations that could be used to extract heat from tubular solid oxide fuel cells (SOFCs) . Two SOFC feed gas compositions were used in this study. They represent product gases from two different coal gasifier designs from the Zero Emission Coal study at Los Alamos National Laboratory . Both plant designs rely on the efficient use of the heat produced by the SOFCs . Both feed streams are relatively rich in hydrogen with a very small hydrocarbon content . One feed stream has a significant carbon monoxide content with a bit less hydrogen . Since neither stream has a significant hydrocarbon content, the common use of the endothermic reforming reaction to reduce the process heat is not possible for these feed streams . The process, the method, the computer code, and the results are presented as well as a discussion of the pros and cons of each configuration for each process .

  9. Process for forming coal compacts and product thereof

    DOE Patents [OSTI]

    Gunnink, Brett (Columbia, MO); Kanunar, Jayanth (Arlington, MA); Liang, Zhuoxiong (San Francisco, CA)

    2002-01-01T23:59:59.000Z

    A process for forming durable, mechanically strong compacts from coal particulates without use of a binder is disclosed. The process involves applying a compressive stress to a particulate feed comprising substantially water-saturated coal particles while the feed is heated to a final compaction temperature in excess of about 100.degree. C. The water present in the feed remains substantially in the liquid phase throughout the compact forming process. This is achieved by heating and compressing the particulate feed and cooling the formed compact at a pressure sufficient to prevent water present in the feed from boiling. The compacts produced by the process have a moisture content near their water saturation point. As a result, these compacts absorb little water and retain exceptional mechanical strength when immersed in high pressure water. The process can be used to form large, cylindrically-shaped compacts from coal particles (i.e., "coal logs") so that the coal can be transported in a hydraulic coal log pipeline.

  10. Synthesis gas production with an adjustable H{sub 2}/CO ratio through the coal gasification process: effects of coal ranks and methane addition

    SciTech Connect (OSTI)

    Yan Cao; Zhengyang Gao; Jing Jin; Hongchang Zhou; Marten Cohron; Houying Zhao; Hongying Liu; Weiping Pan [Western Kentucky University (WKU), Bowling Green, KY (United States). Institute for Combustion Science and Environmental Technology (ICSET)

    2008-05-15T23:59:59.000Z

    Direct production of synthesis gas using coal as a cheap feedstock is attractive but challenging due to its low H{sub 2}/CO ratio of generated synthesis gas. Three typical U.S. coals of different ranks were tested in a 2.5 in. coal gasifier to investigate their gasification reactivity and adjustability on H{sub 2}/CO ratio of generated synthesis gas with or without the addition of methane. Tests indicated that lower-rank coals (lignite and sub-bituminous) have higher gasification reactivity than bituminous coals. The coal gasification reactivity is correlated to its synthesis-gas yield and the total percentage of H{sub 2} and CO in the synthesis gas, but not to the H{sub 2}/CO ratio. The H{sub 2}/CO ratio of coal gasification was found to be correlated to the rank of coals, especially the H/C ratio of coals. Methane addition into the dense phase of the pyrolysis and gasification zone of the cogasification reactor could make the best use of methane in adjusting the H{sub 2}/CO ratio of the generated synthesis gas. The maximum methane conversion efficiency, which was likely correlated to its gasification reactivity, could be achieved by 70% on average for all tested coals. The actual catalytic effect of generated coal chars on methane conversion seemed coal-dependent. The coal-gasification process benefits from methane addition and subsequent conversion on the adjustment of the H{sub 2}/CO ratio of synthesis gas. The methane conversion process benefits from the use of coal chars due to their catalytic effects. This implies that there were likely synergistic effects on both. 25 refs., 3 figs., 3

  11. Powder River Basin coalbed methane: The USGS role in investigating this ultimate clean coal by-product

    SciTech Connect (OSTI)

    Stricker, G.D.; Flores, R.M.; Ochs, A.M.; Stanton, R.W.

    2000-07-01T23:59:59.000Z

    For the past few decades, the Fort Union Formation in the Powder River Basin has supplied the Nation with comparatively clean low ash and low sulfur coal. However, within the past few years, coalbed methane from the same Fort Union coal has become an important energy by-product. The recently completed US Geological Survey coal resource assessment of the Fort Union coal beds and zones in the northern Rocky Mountains and Great Plains (Fort Union Coal Assessment Team, 1999) has added useful information to coalbed methane exploration and development in the Powder River Basin in Wyoming and Montana. Coalbed methane exploration and development in the Powder River Basin has rapidly accelerated in the past three years. During this time more than 800 wells have been drilled and recent operator forecasts projected more than 5,000 additional wells to be drilled over the next few years. Development of shallow (less than 1,000 ft. deep) Fort Union coal-bed methane is confined to Campbell and Sheridan Counties, Wyoming, and Big Horn County, Montana. The purpose of this paper is to report on the US Geological Survey's role on a cooperative coalbed methane project with the US Bureau of Land Management (BLM), Wyoming Reservoir Management Group and several gas operators. This paper will also discuss the methodology that the USGS and the BLM will be utilizing for analysis and evaluation of coalbed methane reservoirs in the Powder River Basin. The USGS and BLM need additional information of coalbed methane reservoirs to accomplish their respective resource evaluation and management missions.

  12. ENHANCED COAL BED METHANE PRODUCTION AND SEQUESTRATION OF CO2 IN UNMINEABLE COAL SEAMS

    SciTech Connect (OSTI)

    William A. Williams

    2004-03-01T23:59:59.000Z

    The availability of clean, affordable energy is essential for the prosperity and security of the United States and the world in the 21st century. Emissions of carbon dioxide (CO{sub 2}) into the atmosphere are an inherent part of electricity generation, transportation, and industrial processes that rely on fossil fuels. These energy-related activities are responsible for more than 80 percent of the U.S. greenhouse gas emissions, and most of these emissions are CO{sub 2}. Over the last few decades, an increased concentration of CO{sub 2} in the earth's atmosphere has been observed. Carbon sequestration technology offers an approach to redirect CO{sub 2} emissions into sinks (e.g., geologic formations, oceans, soils and vegetation) and potentially stabilize future atmospheric CO{sub 2} levels. Coal seams are attractive CO{sub 2} sequestration sinks, due to their abundance and proximity to electricity-generation facilities. The recovery of marketable coalbed methane (CBM) provides a value-added stream, potentially reducing the cost to sequester CO{sub 2} gas. Much research is needed to evaluate this technology in terms of CO{sub 2} storage capacity, sequestration stability, commercial feasibility and overall economics. CONSOL Energy Inc., Research & Development (CONSOL), with support from the US DOE, has embarked on a seven-year program to construct and operate a coal bed sequestration site composed of a series of horizontally drilled wells that originate at the surface and extend through two overlying coal seams. Once completed, all of the wells will be used initially to drain CBM from both the upper (mineable) and lower (unmineable) coal seams. After sufficient depletion of the reservoir, centrally located wells in the lower coal seam will be converted from CBM drainage wells to CO{sub 2} injection ports. CO{sub 2} will be measured and injected into the lower unmineable coal seam while CBM continues to drain from both seams. In addition to metering all injected CO{sub 2} and recovered CBM, the program includes additional monitoring wells to further examine horizontal and vertical migration of CO{sub 2}. This is the fifth Technical Progress report for the project. Progress this period was focused on reclamation of the north access road and north well site, and development of revised drilling methods. This report provides a concise overview of project activities this period and plans for future work.

  13. Process for the production of ethylene and other hydrocarbons from coal

    DOE Patents [OSTI]

    Steinberg, Meyer (Huntington Station, NY); Fallon, Peter (East Moriches, NY)

    1986-01-01T23:59:59.000Z

    A process for the production of economically significant amounts of ethyl and other hydrocarbon compounds, such as benzene, from coal is disclosed wherein coal is reacted with methane at a temperature in the approximate range of 500.degree. C. to 1100.degree. C. at a partial pressure less than about 200 psig for a period of less than 10 seconds. Ethylene and other hydrocarbon compounds may be separated from the product stream so produced, and the methane recycled for further production of ethylene. In another embodiment, other compounds produced, such as by-product tars, may be burned to heat the recycled methane.

  14. Production cost and air emissions impacts of coal cycling in power systems with large-scale wind penetration

    E-Print Network [OSTI]

    Jaramillo, Paulina

    on dispatchable generating capacity, such as coal and natural gas power plants, which can be cycled in responseProduction cost and air emissions impacts of coal cycling in power systems with large-scale wind emissions impacts of coal cycling in power systems with large-scale wind penetration David Luke Oates

  15. ENHANCED COAL BED METHANE PRODUCTION AND SEQUESTRATION OF CO2 IN UNMINEABLE COAL SEAMS

    SciTech Connect (OSTI)

    Gary L. Cairns

    2002-10-01T23:59:59.000Z

    The availability of clean, affordable energy is essential for the prosperity and security of the United States and the world in the 21st century. Carbon dioxide (CO{sub 2}) emissions to the atmosphere are an inherent part of energy-related activities, such as electricity generation, transportation, and building systems. These energy-related activities are responsible for roughly 85% of the U.S. greenhouse gas emissions, and 95% of these emissions are dominated by CO{sub 2}. Over the last few decades, an increased concentration of CO{sub 2} in the earth's atmosphere has been observed. Many scientists believe greenhouse gases, particularly CO{sub 2}, trap heat in the earth's atmosphere. Carbon sequestration technology offers an approach to redirect CO{sub 2} emissions into sinks (e.g., geologic formations, oceans, soils, and vegetation) and potentially stabilize future atmospheric CO{sub 2} levels. Coal seams are attractive CO{sub 2} sequestration sinks, due to their abundance and proximity to electricity-generation facilities. The recovery of marketable coal bed methane (CBM) provides a value-added stream, reducing the cost to sequester CO{sub 2} gas. Much research is needed to evaluate this technology in terms of CO{sub 2} storage capacity, sequestration stability, commercial feasibility and overall economics. CONSOL Energy, with support from the U.S. DOE, is conducting a seven-year program to construct and operate a coal bed sequestration site composed of a series of horizontally drilled wells that originate at the surface and extend through overlying coal seams in the subsurface. Once completed, the wells will be used to initially drain CBM from both the upper (mineable) and lower (unmineable) coal seams. After sufficient depletion of the reservoir, centrally located wells in the lower coal seam will be converted from CBM drainage wells to CO{sub 2} injection ports. CO{sub 2} will be measured and injected into the lower unmineable coal seam while CBM continues to drain from both seams. In addition to metering all injected CO{sub 2} and CBM produced, the program includes a plan to monitor horizontal migration of CO{sub 2} within the lower seam. This is the second Technical Progress report for the project. Progress to date has been focused on pre-construction activities; in particular, attaining site approvals and securing property rights for the project. This report provides a concise overview of project activity this period and plans for future work. This is the second semi-annual Technical Progress report under the subject agreement. During this report period, progress was made in completing the environmental assessment report, securing land and coal rights, and evaluating drilling strategies. These aspects of the project are discussed in detail in this report.

  16. HYDROGEN PRODUCTION FOR FUEL CELLS VIA REFORMING COAL-DERIVED METHANOL

    SciTech Connect (OSTI)

    Paul A. Erickson

    2005-04-01T23:59:59.000Z

    Hydrogen can be produced from many feedstocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the sixth report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of January 1-March 31, 2005. This quarter saw progress in four areas. These areas are: (1) Autothermal reforming of coal derived methanol, (2) Catalyst deactivation, (3) Steam reformer transient response, and (4) Catalyst degradation with bluff bodies. All of the projects are proceeding on or slightly ahead of schedule.

  17. ENHANCED COAL BED METHANE PRODUCTION AND SEQUESTRATION OF CO2 IN UNMINEABLE COAL SEAMS

    SciTech Connect (OSTI)

    Gary L. Cairns

    2002-04-01T23:59:59.000Z

    This is the first Technical Progress report for the subject agreement. During the first six months of the project, progress was made in arranging participation by other CONSOL departments, identifying a prospective site, developing an environmental assessment report, and securing land and coal rights. In addition, correspondences were drafted in response to NETL inquiries. These aspects of the project are discussed in detail in this report.

  18. HYDROGEN PRODUCTION FOR FUEL CELLS VIA REFORMING COAL-DERIVED METHANOL

    SciTech Connect (OSTI)

    Paul A. Erickson

    2006-01-01T23:59:59.000Z

    Hydrogen can be produced from many feedstocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the ninth report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of October 1, 2005-December 31, 2005. This quarter saw progress in four areas. These areas are: (1) reformate purification, (2) heat transfer enhancement, (3) autothermal reforming coal-derived methanol degradation test; and (4) model development for fuel cell system integration. The project is on schedule and is now shifting towards the design of an integrated PEM fuel cell system capable of using the coal-derived product. This system includes a membrane clean up unit and a commercially available PEM fuel cell.

  19. The ADESORB Process for Economical Production of Sorbents for Mercury Removal from Coal Fired Power Plants

    SciTech Connect (OSTI)

    Robin Stewart

    2008-03-12T23:59:59.000Z

    The DOE's National Energy Technology Laboratory (NETL) currently manages the largest research program in the country for controlling coal-based mercury emissions. NETL has shown through various field test programs that the determination of cost-effective mercury control strategies is complex and highly coal- and plant-specific. However, one particular technology has the potential for widespread application: the injection of activated carbon upstream of either an electrostatic precipitator (ESP) or a fabric filter baghouse. This technology has potential application to the control of mercury emissions on all coal-fired power plants, even those with wet and dry scrubbers. This is a low capital cost technology in which the largest cost element is the cost of sorbents. Therefore, the obvious solutions for reducing the costs of mercury control must focus on either reducing the amount of sorbent needed or decreasing the cost of sorbent production. NETL has researched the economics and performance of novel sorbents and determined that there are alternatives to the commercial standard (NORIT DARCO{reg_sign} Hg) and that this is an area where significant technical improvements can still be made. In addition, a key barrier to the application of sorbent injection technology to the power industry is the availability of activated carbon production. Currently, about 450 million pounds ($250 million per year) of activated carbon is produced and used in the U.S. each year - primarily for purification of drinking water, food, and beverages. If activated carbon technology were to be applied to all 1,100 power plants, EPA and DOE estimate that it would require an additional $1-$2 billion per year, which would require increasing current capacity by a factor of two to eight. A new facility to produce activated carbon would cost approximately $250 million, would increase current U.S. production by nearly 25%, and could take four to five years to build. This means that there could be significant shortages in supply if response to new demand is not well-timed.

  20. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    SciTech Connect (OSTI)

    Caroline E. Burgess Clifford; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2006-05-17T23:59:59.000Z

    This report summarizes the accomplishments toward project goals during the first six months of the third year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. Characterization of the gasoline fuel indicates a dominance of single ring alkylcycloalkanes that have a low octane rating; however, blends containing these compounds do not have a negative effect upon gasoline when blended in refinery gasoline streams. Characterization of the diesel fuel indicates a dominance of 3-ring aromatics that have a low cetane value; however, these compounds do not have a negative effect upon diesel when blended in refinery diesel streams. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Combustion and characterization of fuel oil indicates that the fuel is somewhere in between a No. 4 and a No. 6 fuel oil. Emission testing indicates the fuel burns similarly to these two fuels, but trace metals for the coal-based material are different than petroleum-based fuel oils. Co-coking studies using cleaned coal are highly reproducible in the pilot-scale delayed coker. Evaluation of the coke by Alcoa, Inc. indicated that while the coke produced is of very good quality, the metals content of the carbon is still high in iron and silica. Coke is being evaluated for other possible uses. Methods to reduce metal content are being evaluated.

  1. Development of Continuous Solvent Extraction Processes for Coal Derived Carbon Products

    SciTech Connect (OSTI)

    Elliot B. Kennel

    2006-12-31T23:59:59.000Z

    This DOE NETL-sponsored effort seeks to develop continuous processes for producing carbon products from solvent-extracted coal. A key process step is removal of solids from liquefied coal. Three different processes were compared: gravity separation, centrifugation using a decanter-type Sharples Pennwalt centrifuge, and a Spinner-II centrifuge. The data suggest that extracts can be cleaned to as low as 0.5% ash level and probably lower using a combination of these techniques.

  2. Drunkard`s wash project: Coalbed methane production from Ferron coals in east-central Utah

    SciTech Connect (OSTI)

    Lemarre, R.A. [Texaco Exploration and Production, Inc., Denver, CO (United States); Burns, T.D. [River Gas Corporation, Northport, AL (United States)

    1996-12-31T23:59:59.000Z

    The Drunkard`s Wash Project produces dry, coalbed methane gas from coals within the Ferron Sandstone Member of the Mancos Shale. The project covers 120,000 acres on the western flank of the San Rafael Uplift in east-central Utah. Gas was first produced into the sales line in January 1993. The field is being developed on 160 acre spacing with 73 wells currently producing 32.2 MMCFD for an average of 437 MCFD/well. Thirty three of those wells have been producing for 32 months and now average 637 MCFD/well. Most of the wells show a classic coalbed methane negative decline curve with increasing gas rates as the reservoir pressure declines due to production of water. Daily water production is 14,500 BPD, for an average of 199 BWPD/well. Total coal thickness ranges from 7 ft. to 48 ft., with an average of 24 ft. The coals occur in 3 to 6 seams at depths of 1350 to 2450 ft. The coal rank is high volatile A&B bituminous. We can not yet see a correlation between total coal thickness and current production. All wells are cased and hydraulically stimulated and most require pumping units to handle the large volumes of water. However, 22 wells do not require pumps and flow unassisted to the surface. The structure consists of monoclinal westward dip. A thin tonstein layer in the bottom coal seam serves as an excellent datum for mapping. Enhanced production is encountered along a southwest-plunging nose that probably formed additional fracture permeability within the coals. Northeast-trending reverse faults with small displacement appear to compartmentalize the reservoir. The Ferron coals were deposited in a river-dominated deltaic system that prograded to the east and southeast during Turonian-Coniacian (Upper Cretaceous) time. The Ferron Sandstone Member represents an eastward-thinning elastic wedge that was deposited during regression of the Western Interior Cretaceous seaway.

  3. Co-pyrolysis of low rank coals and biomass: Product distributions

    SciTech Connect (OSTI)

    Soncini, Ryan M.; Means, Nicholas C.; Weiland, Nathan T.

    2013-10-01T23:59:59.000Z

    Pyrolysis and gasification of combined low rank coal and biomass feeds are the subject of much study in an effort to mitigate the production of green house gases from integrated gasification combined cycle (IGCC) systems. While co-feeding has the potential to reduce the net carbon footprint of commercial gasification operations, the effects of co-feeding on kinetics and product distributions requires study to ensure the success of this strategy. Southern yellow pine was pyrolyzed in a semi-batch type drop tube reactor with either Powder River Basin sub-bituminous coal or Mississippi lignite at several temperatures and feed ratios. Product gas composition of expected primary constituents (CO, CO{sub 2}, CH{sub 4}, H{sub 2}, H{sub 2}O, and C{sub 2}H{sub 4}) was determined by in-situ mass spectrometry while minor gaseous constituents were determined using a GC-MS. Product distributions are fit to linear functions of temperature, and quadratic functions of biomass fraction, for use in computational co-pyrolysis simulations. The results are shown to yield significant nonlinearities, particularly at higher temperatures and for lower ranked coals. The co-pyrolysis product distributions evolve more tar, and less char, CH{sub 4}, and C{sub 2}H{sub 4}, than an additive pyrolysis process would suggest. For lignite co-pyrolysis, CO and H{sub 2} production are also reduced. The data suggests that evolution of hydrogen from rapid pyrolysis of biomass prevents the crosslinking of fragmented aromatic structures during coal pyrolysis to produce tar, rather than secondary char and light gases. Finally, it is shown that, for the two coal types tested, co-pyrolysis synergies are more significant as coal rank decreases, likely because the initial structure in these coals contains larger pores and smaller clusters of aromatic structures which are more readily retained as tar in rapid co-pyrolysis.

  4. Lawrence Livermore National Laboratory underground coal gasification data base. [US DOE-supported field tests; data

    SciTech Connect (OSTI)

    Cena, R. J.; Thorsness, C. B.

    1981-08-21T23:59:59.000Z

    The Department of Energy has sponsored a number of field projects to determine the feasibility of converting the nation's vast coal reserves into a clean efficient energy source via underground coal gasification (UCG). Due to these tests, a significant data base of process information has developed covering a range of coal seams (flat subbituminous, deep flat bituminous and steeply dipping subbituminous) and processing techniques. A summary of all DOE-sponsored tests to data is shown. The development of UCG on a commercial scale requires involvement from both the public and private sectors. However, without detailed process information, accurate assessments of the commercial viability of UCG cannot be determined. To help overcome this problem the DOE has directed the Lawrence Livermore National Laboratory (LLNL) to develop a UCG data base containing raw and reduced process data from all DOE-sponsored field tests. It is our intent to make the data base available upon request to interested parties, to help them assess the true potential of UCG.

  5. DEVELOPMENT OF CONTINUOUS SOLVENT EXTRACTION PROCESSES FOR COAL DERIVED CARBON PRODUCTS

    SciTech Connect (OSTI)

    Dady B. Dadyburjor; Mark E. Heavner; Manoj Katakdaunde; Liviu Magean; J. Joshua Maybury; Alfred H. Stiller; Joseph M. Stoffa; John W. Zondlo

    2006-08-01T23:59:59.000Z

    The purpose of this DOE-funded effort is to develop continuous processes for solvent extraction of coal for the production of carbon products. The largest applications are those which support metals smelting, such as anodes for aluminum smelting and electrodes for arc furnaces. Other carbon products include materials used in creating fuels for the Direct Carbon Fuel Cell, and porous carbon structural material referred to as ''carbon foam'' and carbon fibers. During this reporting period, hydrotreatment of solvent was completed in preparation for pitch fabrication for graphite electrodes. Coal digestion has lagged but is expected to be complete by next quarter. Studies are reported on coal dissolution, pitch production, foam synthesis using physical blowing agents, and alternate coking techniques.

  6. National Comfort Products: Order (2010-SE-0307)

    Broader source: Energy.gov [DOE]

    DOE ordered National Comfort Products to pay an $8,000 civil penalty after finding NCP had failed to conduct the required testing to certify that certain models of central air conditioners comply with the applicable energy conservation standard.

  7. DEMONSTRATION OF THE VIABILITY AND EVALUATION OF PRODUCTION COSTS FOR BIOMASS-INFUSED COAL BRIQUETTES

    SciTech Connect (OSTI)

    Kamshad, Kourosh

    2013-12-31T23:59:59.000Z

    This report is the final reporting installment of the DOE project titled DEMONSTRATION OF THE VIABILITY AND EVALUATION OF PRODUCTION COSTS FOR BIOMASS-INFUSED COAL BRIQUETTES. This rerport includes a summary of the work completed to date including the experimental methods used to acheive the results, discussions, conclusions and implications of the final product delivered by the project.

  8. Production of High-Hydrogen Content Coal-Derived Liquids [Part 1 of 3

    SciTech Connect (OSTI)

    Stephen Bergin

    2011-03-30T23:59:59.000Z

    The primary goal of this project has been to evaluate and compare the effect of the intrinsic differences between cobalt (Co) and iron (Fe) catalysts for Fischer-Tropsch (FT) synthesis using coal-derived syngas. Crude oil, especially heavy, high-sulfur crude, is no longer the appropriate source for the additional, or marginal, amounts of middle-distillate fuels needed to meet growing US and world demand for diesel and jet fuels. Only about 1/3 of the marginal crude oil barrel can be made into diesel and jet fuels. The remaining 2/3 contributes further to global surpluses of by-products. FT can produce these needed marginal, low-sulfur middle-distillate fuels more efficiently, with less environmental impact, and from abundant US domestic resources. Cobalt FT catalyst is more efficient, and less expensive overall, than iron FT catalyst. Mechanisms of cobalt FT catalyst functioning, and poisoning, have been elucidated. Each of these primary findings is amplified by several secondary findings, and these are presented, and verified in detail. The most effective step the United States can take to begin building toward improved long-term national energy security, and to reduce dependence, over time, on imported crude oil from unfriendly and increasingly unstable areas of the world, is to begin producing additional, or marginal amounts of, middle-distillate-type fuels, such as ultralow sulfur diesel (ULSD) and jet fuel (not gasoline) from US domestic resources other than petroleum. FT synthesis of these middle distillate fuels offers the advantage of being able to use abundant and affordable US coal and biomass as the primary feedstocks. Use of the cobalt FT catalyst system has been shown conclusively to be more effective and less expensive than the use of iron FT catalyst with syngas derived from coal, or from coal and biomass combined. This finding is demonstrated in detail for the initial case of a relatively small FT plant of about 2000 barrels per day based upon coal and biomass. The primary feature of such a plant, in the current situation in which no commercial FT plants are operating in the US, is that it requires a relatively modest capital investment, meaning that such a plant could actually be built, operated, and replicated in the near term. This is in contrast to the several-billion dollar investment, and accompanying risk, that would be required for a plant of more than an order of magnitude greater capacity, which has been referred to in the technical literature on fuel production as the capacity required to be considered "commercial-scale." The effects of more than ten different potential poisons for cobalt FT catalyst have been studied extensively and in detail using laboratory continuous-stirred tank reactors (CSTRs) and bottled laboratory syngas "spiked" with precisely controlled amounts of the poisons, typically at the levels of 10s or 100s of parts per billion. This data set has been generated and interpreted by world-renowned experts on FT catalysis at the University of Kentucky Center for Applied Energy Research (UK-CAER), and has enabled unprecedented insight regarding the many molecular-scale mechanisms that can play a role in the "poisoning" of cobalt FT catalyst.

  9. Production of High-Hydrogen Content Coal-Derived Liquids [Part 2 of 3

    SciTech Connect (OSTI)

    Stephen Bergin

    2011-03-30T23:59:59.000Z

    The primary goal of this project has been to evaluate and compare the effect of the intrinsic differences between cobalt (Co) and iron (Fe) catalysts for Fischer-Tropsch (FT) synthesis using coal-derived syngas. Crude oil, especially heavy, high-sulfur crude, is no longer the appropriate source for the additional, or marginal, amounts of middle-distillate fuels needed to meet growing US and world demand for diesel and jet fuels. Only about 1/3 of the marginal crude oil barrel can be made into diesel and jet fuels. The remaining 2/3 contributes further to global surpluses of by-products. FT can produce these needed marginal, low-sulfur middle-distillate fuels more efficiently, with less environmental impact, and from abundant US domestic resources. Cobalt FT catalyst is more efficient, and less expensive overall, than iron FT catalyst. Mechanisms of cobalt FT catalyst functioning, and poisoning, have been elucidated. Each of these primary findings is amplified by several secondary findings, and these are presented, and verified in detail. The most effective step the United States can take to begin building toward improved long-term national energy security, and to reduce dependence, over time, on imported crude oil from unfriendly and increasingly unstable areas of the world, is to begin producing additional, or marginal amounts of, middle-distillate-type fuels, such as ultralow sulfur diesel (ULSD) and jet fuel (not gasoline) from US domestic resources other than petroleum. FT synthesis of these middle distillate fuels offers the advantage of being able to use abundant and affordable US coal and biomass as the primary feedstocks. Use of the cobalt FT catalyst system has been shown conclusively to be more effective and less expensive than the use of iron FT catalyst with syngas derived from coal, or from coal and biomass combined. This finding is demonstrated in detail for the initial case of a relatively small FT plant of about 2000 barrels per day based upon coal and biomass. The primary feature of such a plant, in the current situation in which no commercial FT plants are operating in the US, is that it requires a relatively modest capital investment, meaning that such a plant could actually be built, operated, and replicated in the near term. This is in contrast to the several-billion dollar investment, and accompanying risk, that would be required for a plant of more than an order of magnitude greater capacity, which has been referred to in the technical literature on fuel production as the capacity required to be considered "commercial-scale." The effects of more than ten different potential poisons for cobalt FT catalyst have been studied extensively and in detail using laboratory continuous-stirred tank reactors (CSTRs) and bottled laboratory syngas "spiked" with precisely controlled amounts of the poisons, typically at the levels of 10s or 100s of parts per billion. This data set has been generated and interpreted by world-renowned experts on FT catalysis at the University of Kentucky Center for Applied Energy Research (UK-CAER), and has enabled unprecedented insight regarding the many molecular-scale mechanisms that can play a role in the "poisoning" of cobalt FT catalyst.

  10. Production of High-Hydrogen Content Coal-Derived Liquids [Part 3 of 3

    SciTech Connect (OSTI)

    Stephen Bergin

    2011-03-30T23:59:59.000Z

    The primary goal of this project has been to evaluate and compare the effect of the intrinsic differences between cobalt (Co) and iron (Fe) catalysts for Fischer-Tropsch (FT) synthesis using coal-derived syngas. Crude oil, especially heavy, high-sulfur crude, is no longer the appropriate source for the additional, or marginal, amounts of middle-distillate fuels needed to meet growing US and world demand for diesel and jet fuels. Only about 1/3 of the marginal crude oil barrel can be made into diesel and jet fuels. The remaining 2/3 contributes further to global surpluses of by-products. FT can produce these needed marginal, low-sulfur middle-distillate fuels more efficiently, with less environmental impact, and from abundant US domestic resources. Cobalt FT catalyst is more efficient, and less expensive overall, than iron FT catalyst. Mechanisms of cobalt FT catalyst functioning, and poisoning, have been elucidated. Each of these primary findings is amplified by several secondary findings, and these are presented, and verified in detail. The most effective step the United States can take to begin building toward improved long-term national energy security, and to reduce dependence, over time, on imported crude oil from unfriendly and increasingly unstable areas of the world, is to begin producing additional, or marginal amounts of, middle-distillate-type fuels, such as ultralow sulfur diesel (ULSD) and jet fuel (not gasoline) from US domestic resources other than petroleum. FT synthesis of these middle distillate fuels offers the advantage of being able to use abundant and affordable US coal and biomass as the primary feedstocks. Use of the cobalt FT catalyst system has been shown conclusively to be more effective and less expensive than the use of iron FT catalyst with syngas derived from coal, or from coal and biomass combined. This finding is demonstrated in detail for the initial case of a relatively small FT plant of about 2000 barrels per day based upon coal and biomass. The primary feature of such a plant, in the current situation in which no commercial FT plants are operating in the US, is that it requires a relatively modest capital investment, meaning that such a plant could actually be built, operated, and replicated in the near term. This is in contrast to the several-billion dollar investment, and accompanying risk, that would be required for a plant of more than an order of magnitude greater capacity, which has been referred to in the technical literature on fuel production as the capacity required to be considered "commercial-scale." The effects of more than ten different potential poisons for cobalt FT catalyst have been studied extensively and in detail using laboratory continuous-stirred tank reactors (CSTRs) and bottled laboratory syngas "spiked" with precisely controlled amounts of the poisons, typically at the levels of 10s or 100s of parts per billion. This data set has been generated and interpreted by world-renowned experts on FT catalysis at the University of Kentucky Center for Applied Energy Research (UK-CAER), and has enabled unprecedented insight regarding the many molecular-scale mechanisms that can play a role in the "poisoning" of cobalt FT catalyst.

  11. DEVELOPMENT OF CONTINUOUS SOLVENT EXTRACTION PROCESSES FOR COAL DERIVED CARBON PRODUCTS

    SciTech Connect (OSTI)

    Elliot B. Kennel; Stephen P. Carpenter; Dady Dadyburjor; Manoj Katakdaunde; Liviu Magean; Madhavi Nallani-Chakravartula; Peter G. Stansberry; Alfred H. Stiller; John W. Zondlo

    2006-03-27T23:59:59.000Z

    The purpose of this DOE-funded effort is to develop continuous processes for solvent extraction of coal for the production of carbon products. These carbon products include materials used in metals smelting, especially in the aluminum and steel industries, as well as porous carbon structural material referred to as ''carbon foam'' and carbon fibers. During this reporting period, efforts have focused on the development of continuous processes for hydrogenation as well as continuous production of carbon foam and coke.

  12. HYDROGEN PRODUCTION FOR FUEL CELLS VIA REFORMING COAL-DERIVED METHANOL

    SciTech Connect (OSTI)

    Paul A. Erickson

    2004-04-01T23:59:59.000Z

    Hydrogen can be produced from many feed stocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the second report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of January 1--March 31, 2004. This quarter saw progress in five areas. These areas are: (1) Internal and external evaluations of coal based methanol and the fuel cell grade baseline fuel; (2) Experimental investigations of heat and mass transfer enhancement methods by flow field manipulation; (3) Design and set up of the autothermal reactor; (4) Steam reformation of Coal Based Methanol; and (5) Initial catalyst degradation studies. All of the projects are proceeding on or slightly ahead of schedule.

  13. DEVELOPMENT OF CONTINUOUS SOLVENT EXTRACTION PROCESSES FOR COAL DERIVED CARBON PRODUCTS

    SciTech Connect (OSTI)

    Elliot B. Kennel; Chong Chen; Dady Dadyburjor; Liviu Magean; Peter G. Stansberry; Alfred H. Stiller; John W. Zondlo

    2005-04-13T23:59:59.000Z

    The purpose of this DOE-funded effort is to develop continuous processes for solvent extraction of coal for the production of carbon products. These carbon products include materials used in metals smelting, especially in the aluminum and steel industries, as well as porous carbon structural material referred to as ''carbon foam'' and carbon fibers. Table 1 provides an overview of the major markets for carbon products. Current sources of materials for these processes generally rely on petroleum distillation products or coal tar distillates obtained as a byproduct of metcoke production facilities. In the former case, the American materials industry, just as the energy industry, is dependent upon foreign sources of petroleum. In the latter case, metcoke production is decreasing every year due to the combined difficulties associated with poor economics and a significant environmental burden. Thus, a significant need exists for an environmentally clean process which can used domestically obtained raw materials and which can still be very competitive economically.

  14. Process development for production of coal/sorbent agglomerates

    SciTech Connect (OSTI)

    Rapp, D.M.; Lytle, J.M.; Hackley, K.C.; Moran, D.L.; Becvar, S. (Illinois State Geological Survey, Champaign, IL (USA)); Berger, R.L. (Illinois Univ., Urbana, IL (USA)); Griggs, K. (Army Construction Engineering Research Lab., Champaign, IL (USA))

    1991-01-01T23:59:59.000Z

    Current coal mining and processing procedures produce significant quantities of fine coal with limited marketability. The objective of this work is to pelletize these fines with a sulfur capturing sorbent such as calcium hydroxide to produce a fuel which will meet future sulfur dioxide emission levels. To decrease binder costs, carbonation, which is the reaction of calcium hydroxide with carbon dioxide in the presence of moisture to produce calcium carbonate, is being investigated as a method for improving pellet quality. The calcium carbonate formed acts as a cementitious matrix which improves pellet strength. In previous work utilizing IBC-106 from the Illinois Basin Coal Sample Program, carbonation was determined to be effective at significantly improving pellet compressive strength, impact and attrition resistance and weatherability. In combustion tests conducted at 850{degree}C, sulfur capture of 80% was achieved for pellets having 17.5% calcium hydroxide (a Ca/S ration of 2/1). In this years work, a flotation concentrate collected from an operating Illinois preparation plant is being used for testing. Results indicate carbonation significantly increases the compressive strength of pellets formed with 10% calcium hydroxide. 6 refs., 1 fig., 5 tabs.

  15. Process development for production of coal/sorbent agglomerates

    SciTech Connect (OSTI)

    Rapp, D.M.

    1991-01-01T23:59:59.000Z

    The goal of this work was to develop a process flow diagram to economically produce a clean-burning fuel from fine Illinois coal. To accomplish this, the process of pelletizing fine coal with calcium hydroxide, a sulfur capturing sorbent, was investigated. Carbonation, which is the reaction of calcium hydroxide with carbon dioxide (in the presence of moisture) to produce a bonding matrix of calcium carbonate, was investigated as a method for improving pellet quality and reducing binder costs. Proper moisture level is critical to allow the reaction to occur. If too much moisture is present in a pellet, the pore spaces are filled and carbon dioxide must diffuse through the water to reach the calcium hydroxide and react. This severely slows or stops the reaction. The ideal situation is when there is just enough moisture to coat the calcium hydroxide allowing for the reaction to proceed. The process has been successfully demonstrated on a pilot-scale as a method of hardening iron ore pellets (Imperato, 1966). Two potential combustion options are being considered for the coal/calcium hydroxide pellets: fluidized bed combustors and industrial stoker boilers.

  16. Integrated production/use of ultra low-ash coal, premium liquids and clean char. [Quarterly] report, December 1, 1991--February 29, 1992

    SciTech Connect (OSTI)

    Kruse, C.W. [Illinois State Geological Survey, Champaign, IL (United States)

    1992-08-01T23:59:59.000Z

    The first step in the integrated, mufti-product approach for utilizing Illinois coal is the production of ultra low-ash coal. Subsequent steps convert low-ash coal to high-value, coal-derived, products. The ultra low-ash coal is produced by solubilizing coal in a phenolic solvent under ChemCoal{trademark} process conditions, separating the coal solution from insoluble ash, and then precipitating the clean coal by dilution of the solvent with methanol. Two major products, liquids and low-ash char, are then produced by mild gasification of the low-ash coal. The low ash-char is further upgraded to activated char, and/or an oxidized activated char which has catalytic properties. Characterization of products at each stage is part of this project.

  17. ENCOAL Mild Coal Gasification Project

    SciTech Connect (OSTI)

    Not Available

    1992-02-01T23:59:59.000Z

    ENCOAL Corporation, a wholly-owned subsidiary of Shell Mining Company, is constructing a mild gasification demonstration plant at Triton Coal Company's Buckskin Mine near Gillette, Wyoming. The process, using Liquids From Coal (LFC) technology developed by Shell and SGI International, utilizes low-sulfur Powder River Basin Coal to produce two new fuels, Process Derived Fuel (PDF) and Coal Derived Liquids (CDL). The products, as alternative fuels sources, are expected to significantly reduce current sulfur emissions at industrial and utility boiler sites throughout the nation, thereby reducing pollutants causing acid rain.

  18. Coal Market Module of the National Energy Modeling System Model Documentation 2013

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40Coal Stocks at CommercialDecadeReservesYear JanDecade Year-0 Year-1EIA3QCoal

  19. An Industrial-Based Consortium to Develop Premium Carbon Products from Coal Final Report - Part 3

    SciTech Connect (OSTI)

    Miller, Bruce; Shea, Winton

    2010-12-31T23:59:59.000Z

    Since 1998, The Pennsylvania State University successfully managed the Consortium for Premium Carbon Products from Coal (CPCPC), which was a vehicle for industry-driven research on the promotion, development, and transfer of innovative technologies on premium carbon products from coal to the U.S. industry. The CPCPC was an initiative led by Penn State, its cocharter member West Virginia University (WVU), and the U.S. Department of Energy's (DOE) National Energy Technology Laboratory (NETL), who also provided the base funding for the program, with Penn State responsible for consortium management. CPCPC began in 1998 under DOE Cooperative Agreement No. DE-FC26-98FT40350. This agreement ended November 2004 but the CPCPC activity continued under cooperative agreement No. DE-FC26-03NT41874, which started October 1, 2003 and ended December 31, 2010. The objective of the second agreement was to continue the successful operation of the CPCPC. The CPCPC enjoyed tremendous success with its organizational structure, which included Penn State and WVU as charter members, numerous industrial affiliate members, and strategic university affiliate members together with NETL, forming a vibrant and creative team for innovative research in the area of transforming coal to carbon products. The key aspect of CPCPC was its industry-led council that selected proposals submitted by CPCPC members to ensure CPCPC target areas had strong industrial support. CPCPC had 58 member companies and universities engaged over the 7-year period of this contract. Members were from 17 states and five countries outside of the U.S. During this period, the CPCPC Executive Council selected 46 projects for funding. DOE/CPCPC provided $3.9 million in funding or an average of $564,000 per year. The total project costs were $5.45 million with $1.5 million, or ~28% of the total, provided by the members as cost share. Total average project size was $118,000 with $85,900 provided by DOE/CPCPC. In addition to the research, technology transfer/outreach was a large component of CPCPC's activities. Efficient technology transfer was critical for the deployment of new technologies into the field. CPCPC organized and hosted technology transfer meetings, tours, and tutorials, attended outreach conferences and workshops to represent CPCPC and attract new members, prepared and distributed reports and publications, and developed and maintained a Web site. The second contract ended December 31, 2010, and it is apparent that CPCPC positively impacted the carbon industry and coal research. Statistics and information were compiled to provide a comprehensive account of the impact the consortium had and the beneficial outcomes of many of the individual projects. Project fact sheet, success stories, and other project information were prepared. Two topical reports, a Synthesis report and a Web report, were prepared detailing this information.

  20. An Industrial-Based Consortium to Develop Premium Carbon Products from Coal Final Report - Part 4

    SciTech Connect (OSTI)

    Miller, Bruce; Shea, Winton

    2010-12-31T23:59:59.000Z

    Since 1998, The Pennsylvania State University successfully managed the Consortium for Premium Carbon Products from Coal (CPCPC), which was a vehicle for industry-driven research on the promotion, development, and transfer of innovative technologies on premium carbon products from coal to the U.S. industry. The CPCPC was an initiative led by Penn State, its cocharter member West Virginia University (WVU), and the U.S. Department of Energy's (DOE) National Energy Technology Laboratory (NETL), who also provided the base funding for the program, with Penn State responsible for consortium management. CPCPC began in 1998 under DOE Cooperative Agreement No. DE-FC26-98FT40350. This agreement ended November 2004 but the CPCPC activity continued under cooperative agreement No. DE-FC26-03NT41874, which started October 1, 2003 and ended December 31, 2010. The objective of the second agreement was to continue the successful operation of the CPCPC. The CPCPC enjoyed tremendous success with its organizational structure, which included Penn State and WVU as charter members, numerous industrial affiliate members, and strategic university affiliate members together with NETL, forming a vibrant and creative team for innovative research in the area of transforming coal to carbon products. The key aspect of CPCPC was its industry-led council that selected proposals submitted by CPCPC members to ensure CPCPC target areas had strong industrial support. CPCPC had 58 member companies and universities engaged over the 7-year period of this contract. Members were from 17 states and five countries outside of the U.S. During this period, the CPCPC Executive Council selected 46 projects for funding. DOE/CPCPC provided $3.9 million in funding or an average of $564,000 per year. The total project costs were $5.45 million with $1.5 million, or {approx}28% of the total, provided by the members as cost share. Total average project size was $118,000 with $85,900 provided by DOE/CPCPC. In addition to the research, technology transfer/outreach was a large component of CPCPC's activities. Efficient technology transfer was critical for the deployment of new technologies into the field. CPCPC organized and hosted technology transfer meetings, tours, and tutorials, attended outreach conferences and workshops to represent CPCPC and attract new members, prepared and distributed reports and publications, and developed and maintained a Web site. The second contract ended December 31, 2010, and it is apparent that CPCPC positively impacted the carbon industry and coal research. Statistics and information were compiled to provide a comprehensive account of the impact the consortium had and the beneficial outcomes of many of the individual projects. Project fact sheet, success stories, and other project information were prepared. Two topical reports, a Synthesis report and a Web report, were prepared detailing this information.

  1. An Industrial-Based Consortium to Develop Premium Carbon Products from Coal Final Report - Part 2

    SciTech Connect (OSTI)

    Miller, Bruce; Winton, Shea

    2010-12-31T23:59:59.000Z

    Since 1998, The Pennsylvania State University successfully managed the Consortium for Premium Carbon Products from Coal (CPCPC), which was a vehicle for industry-driven research on the promotion, development, and transfer of innovative technologies on premium carbon products from coal to the U.S. industry. The CPCPC was an initiative led by Penn State, its cocharter member West Virginia University (WVU), and the U.S. Department of Energy's (DOE) National Energy Technology Laboratory (NETL), who also provided the base funding for the program, with Penn State responsible for consortium management. CPCPC began in 1998 under DOE Cooperative Agreement No. DE-FC26-98FT40350. This agreement ended November 2004 but the CPCPC activity continued under cooperative agreement No. DE-FC26-03NT41874, which started October 1, 2003 and ended December 31, 2010. The objective of the second agreement was to continue the successful operation of the CPCPC. The CPCPC enjoyed tremendous success with its organizational structure, which included Penn State and WVU as charter members, numerous industrial affiliate members, and strategic university affiliate members together with NETL, forming a vibrant and creative team for innovative research in the area of transforming coal to carbon products. The key aspect of CPCPC was its industry-led council that selected proposals submitted by CPCPC members to ensure CPCPC target areas had strong industrial support. CPCPC had 58 member companies and universities engaged over the 7-year period of this contract. Members were from 17 states and five countries outside of the U.S. During this period, the CPCPC Executive Council selected 46 projects for funding. DOE/CPCPC provided $3.9 million in funding or an average of $564,000 per year. The total project costs were $5.45 million with $1.5 million, or ~28% of the total, provided by the members as cost share. Total average project size was $118,000 with $85,900 provided by DOE/CPCPC. In addition to the research, technology transfer/outreach was a large component of CPCPC's activities. Efficient technology transfer was critical for the deployment of new technologies into the field. CPCPC organized and hosted technology transfer meetings, tours, and tutorials, attended outreach conferences and workshops to represent CPCPC and attract new members, prepared and distributed reports and publications, and developed and maintained a Web site. The second contract ended December 31, 2010, and it is apparent that CPCPC positively impacted the carbon industry and coal research. Statistics and information were compiled to provide a comprehensive account of the impact the consortium had and the beneficial outcomes of many of the individual projects. Project fact sheet, success stories, and other project information were prepared. Two topical reports, a Synthesis report and a Web report, were prepared detailing this information.

  2. An Industrial-Based Consortium to Develop Premium Carbon Products from Coal Final Report - Part 5

    SciTech Connect (OSTI)

    Miller, Bruce; Shea, Winton

    2010-12-31T23:59:59.000Z

    Since 1998, The Pennsylvania State University successfully managed the Consortium for Premium Carbon Products from Coal (CPCPC), which was a vehicle for industry-driven research on the promotion, development, and transfer of innovative technologies on premium carbon products from coal to the U.S. industry. The CPCPC was an initiative led by Penn State, its cocharter member West Virginia University (WVU), and the U.S. Department of Energy's (DOE) National Energy Technology Laboratory (NETL), who also provided the base funding for the program, with Penn State responsible for consortium management. CPCPC began in 1998 under DOE Cooperative Agreement No. DE-FC26-98FT40350. This agreement ended November 2004 but the CPCPC activity continued under cooperative agreement No. DE-FC26-03NT41874, which started October 1, 2003 and ended December 31, 2010. The objective of the second agreement was to continue the successful operation of the CPCPC. The CPCPC enjoyed tremendous success with its organizational structure, which included Penn State and WVU as charter members, numerous industrial affiliate members, and strategic university affiliate members together with NETL, forming a vibrant and creative team for innovative research in the area of transforming coal to carbon products. The key aspect of CPCPC was its industry-led council that selected proposals submitted by CPCPC members to ensure CPCPC target areas had strong industrial support. CPCPC had 58 member companies and universities engaged over the 7-year period of this contract. Members were from 17 states and five countries outside of the U.S. During this period, the CPCPC Executive Council selected 46 projects for funding. DOE/CPCPC provided $3.9 million in funding or an average of $564,000 per year. The total project costs were $5.45 million with $1.5 million, or {approx}28% of the total, provided by the members as cost share. Total average project size was $118,000 with $85,900 provided by DOE/CPCPC. In addition to the research, technology transfer/outreach was a large component of CPCPC's activities. Efficient technology transfer was critical for the deployment of new technologies into the field. CPCPC organized and hosted technology transfer meetings, tours, and tutorials, attended outreach conferences and workshops to represent CPCPC and attract new members, prepared and distributed reports and publications, and developed and maintained a Web site. The second contract ended December 31, 2010, and it is apparent that CPCPC positively impacted the carbon industry and coal research. Statistics and information were compiled to provide a comprehensive account of the impact the consortium had and the beneficial outcomes of many of the individual projects. Project fact sheet, success stories, and other project information were prepared. Two topical reports, a Synthesis report and a Web report, were prepared detailing this information.

  3. An Industrial-Based Consortium to Develop Premium Carbon Products from Coal Final Report - Part 1

    SciTech Connect (OSTI)

    Miller, Bruce; Winton, Shea

    2010-12-31T23:59:59.000Z

    Since 1998, The Pennsylvania State University successfully managed the Consortium for Premium Carbon Products from Coal (CPCPC), which was a vehicle for industry-driven research on the promotion, development, and transfer of innovative technologies on premium carbon products from coal to the U.S. industry. The CPCPC was an initiative led by Penn State, its cocharter member West Virginia University (WVU), and the U.S. Department of Energy's (DOE) National Energy Technology Laboratory (NETL), who also provided the base funding for the program, with Penn State responsible for consortium management. CPCPC began in 1998 under DOE Cooperative Agreement No. DE-FC26-98FT40350. This agreement ended November 2004 but the CPCPC activity continued under cooperative agreement No. DE-FC26-03NT41874, which started October 1, 2003 and ended December 31, 2010. The objective of the second agreement was to continue the successful operation of the CPCPC. The CPCPC enjoyed tremendous success with its organizational structure, which included Penn State and WVU as charter members, numerous industrial affiliate members, and strategic university affiliate members together with NETL, forming a vibrant and creative team for innovative research in the area of transforming coal to carbon products. The key aspect of CPCPC was its industry-led council that selected proposals submitted by CPCPC members to ensure CPCPC target areas had strong industrial support. CPCPC had 58 member companies and universities engaged over the 7-year period of this contract. Members were from 17 states and five countries outside of the U.S. During this period, the CPCPC Executive Council selected 46 projects for funding. DOE/CPCPC provided $3.9 million in funding or an average of $564,000 per year. The total project costs were $5.45 million with $1.5 million, or ~28% of the total, provided by the members as cost share. Total average project size was $118,000 with $85,900 provided by DOE/CPCPC. In addition to the research, technology transfer/outreach was a large component of CPCPC's activities. Efficient technology transfer was critical for the deployment of new technologies into the field. CPCPC organized and hosted technology transfer meetings, tours, and tutorials, attended outreach conferences and workshops to represent CPCPC and attract new members, prepared and distributed reports and publications, and developed and maintained a Web site. The second contract ended December 31, 2010, and it is apparent that CPCPC positively impacted the carbon industry and coal research. Statistics and information were compiled to provide a comprehensive account of the impact the consortium had and the beneficial outcomes of many of the individual projects. Project fact sheet, success stories, and other project information were prepared. Two topical reports, a Synthesis report and a Web report, were prepared detailing this information.

  4. Production and screening of carbon products precursors from coal. Quarterly progress report, July 1, 1996--September 30, 1996

    SciTech Connect (OSTI)

    Zondlo, J.; Stiller, A.

    1996-10-25T23:59:59.000Z

    This quarterly report covers activities during the period from July 1, 1996 through September 30, 1996 on the development of carbon products precursor materials from coal. The first year of the project ended in February, 1996; however, the WVU research effort continued through August 14, 1997 on a no-cost extension of the original contract. PETC chose to exercise the option for continuation of the projects and $100,000 became available on August 9, 1996. The objective for year two is to focus on development of those carbon products from coal-based solvent extract precursors which have the greatest possibility for commercial success.

  5. UWM-CBU Concrete Materials Technology Series Program No. 71 Workshop on GREEN CONSTRUCTION MATERIALS USING COAL-COMBUSTION PRODUCTS

    E-Print Network [OSTI]

    Saldin, Dilano

    : Classification (Class F, Class C, Class N, and SDA & Clean-Coal Ash); Chemical Composition; PhysicalUWM-CBU Concrete Materials Technology Series Program No. 71 Workshop on GREEN CONSTRUCTION MATERIALS USING COAL-COMBUSTION PRODUCTS Center for By-Products Utilization NONPROFIT ORGANIZATION 3200

  6. Composition of the ozonolytic degradation products of the organic matter of Barzasskii sapromyxite coal

    SciTech Connect (OSTI)

    S.A. Semenova; Y.F.Patrakov [Russian Academy of Sciences, Kemerovo (Russian Federation). Institute of Coal and Coal Chemistry

    2009-04-15T23:59:59.000Z

    The ozonization of Barzasskii sapromyxite coal in chloroform and the composition of ozonolytic degradation products were studied. Water-insoluble high-molecular-weight products were predominant among the ozonization products. A half of water-soluble substances consisted of aliphatic C{sub 5}-C{sub 12} dicarboxylic acids and benzenedicarboxylic acid derivatives. Sapromyxite has been suggested as a substitute for crude petroleum in the manufacture of motor fuels.

  7. DEVELOPMENT OF CONTINUOUS SOLVENT EXTRACTION PROCESSES FOR COAL DERIVED CARBON PRODUCTS

    SciTech Connect (OSTI)

    Elliot B. Kennel; Stephen P. Carpenter; Dady Dadyburjor; Manoj Katakdaunde; Liviu Magean; Peter G. Stansberry; Alfred H. Stiller; John W. Zondlo

    2005-08-11T23:59:59.000Z

    The purpose of this DOE-funded effort is to develop continuous processes for solvent extraction of coal for the production of carbon products. These carbon products include materials used in metals smelting, especially in the aluminum and steel industries, as well as porous carbon structural material referred to as ''carbon foam'' and carbon fibers. During this reporting period, efforts have focused on the facility modifications for continuous hydrotreating, as well as developing improved protocols for producing synthetic pitches.

  8. Determining coal permeabilities through constant pressure production interference testing 

    E-Print Network [OSTI]

    Schubarth, Stephen Kurt

    1983-01-01T23:59:59.000Z

    Kurt Schubarth, B. S. , Texas A&M Un1versity Chairman of Advisory Committee: Dr. Stephen A. Holditch The determination of format1on propert1es 1s important to the success of any underground coal gasification (UCG) project. There are many ways... method of analysis for a mult1ple well test w1th a constant pressure source. The method is then verified by analyzing data generated from a numer1cal reservoir simulator. An analys1s of a hydrology test performed during the 1980 Texas ASM UCG project...

  9. Comparative Life-Cycle Air Emissions of Coal, Domestic Natural

    E-Print Network [OSTI]

    Jaramillo, Paulina

    come domestically from the production of synthetic natural gas (SNG) via coal gasification- methanation gasification technologies that use coal to produce SNG. This National Gasification Strategy callsComparative Life-Cycle Air Emissions of Coal, Domestic Natural Gas, LNG, and SNG for Electricity

  10. Microbial solubilization of coal

    DOE Patents [OSTI]

    Strandberg, G.W.; Lewis, S.N.

    1988-01-21T23:59:59.000Z

    The present invention relates to a cell-free preparation and process for the microbial solubilization of coal into solubilized coal products. More specifically, the present invention relates to bacterial solubilization of coal into solubilized coal products and a cell-free bacterial byproduct useful for solubilizing coal. 5 tabs.

  11. Impacts of new coal-using technologies on coal markets and electric utilities

    SciTech Connect (OSTI)

    Stauffer, C.H.

    1982-06-01T23:59:59.000Z

    ICF's Coal and Electric Utilities Model (CEUM) was used to make forecasts on the impact of new coal technologies and markets and utilities. The new technologies include the gasifier/ combined cycle (GCC), the atmospheric fluidized bed combustor (AFBC), and the retrofit of synthetic coal-fluids on advanced combined cycle capacity. National production by the year 2000 will increase slightly. Impact of technology will be negligible due to the offsetting effects of GCC (it uses less coal) and synthetic coal fluids. Regional production will increase in synthetic coal fluid regions, decrease in sulphur coal regions. In utilities, coal additions by GCC are favored in the east, by AFBC in the west. SO/sub 2/ emissions will start to decline in 1995, NOx emissions will continue to rise, but not as sharply. Overall costs of utilities are expected to fall slightly by the year 2010.

  12. Studies on the production of ultra-clean coal by alkali-acid leaching of low-grade coals

    SciTech Connect (OSTI)

    Nabeel, A.; Khan, T.A.; Sharma, D.K. [Jamia Millia Islamia, New Delhi (India). Dept. of Chemistry

    2009-07-01T23:59:59.000Z

    The use of low-grade coal in thermal power stations is leading to environmental pollution due to the generation of large amounts of fly ash, bottom ash, and CO{sub 2} besides other pollutants. It is therefore important to clean the coal before using it in thermal power stations, steel plants, or cement industries etc. Physical beneficiation of coal results in only limited cleaning of coal. The increasing environmental pollution problems from the use of coal have led to the development of clean coal technologies. In fact, the clean use of coal requires the cleaning of coal to ultra low ash contents, keeping environmental norms and problems in view and the ever-growing need to increase the efficiency of coal-based power generation. Therefore this requires the adaptation of chemical cleaning techniques for cleaning the coal to obtain ultra clean coal having ultra low ash contents. Presently the reaction conditions for chemical demineralization of low-grade coal using 20% aq NaOH treatment followed by 10% H{sub 2}SO{sub 4} leaching under reflux conditions have been optimized. In order to reduce the concentration of alkali and acid used in this process of chemical demineralization of low-grade coals, stepwise, i.e., three step process of chemical demineralization of coal using 1% or 5% aq NaOH treatment followed by 1% or 5% H{sub 2}SO{sub 4} leaching has been developed, which has shown good results in demineralization of low-grade coals. In order to conserve energy, the alkali-acid leaching of coal was also carried out at room temperature, which gave good results.

  13. Integrated production/use of ultra low-ash coal, premium liquids and clean char. Technical report, September 1, 1991--November 30, 1991

    SciTech Connect (OSTI)

    Kruse, C.W.

    1991-12-31T23:59:59.000Z

    This integrated, multi-product approach for utilizing Illinois coal starts with the production of ultra low-ash coal and then converts it to high-vale, coal-derived, products. The ultra low-ash coal is produced by solubilizing coal in a phenolic solvent under ChemCoal{trademark} process conditions, separating the coal solution from insoluble ash, and then precipitating the clean coal by dilution of the solvent with methanol. Two major products, liquids and low-ash char, are then produced by mild gasification of the low-ash coal. The low ash-char is further upgraded to activated char, and/or an oxidized activated char which has catalytic properties. Characterization of products at each stage is part of this project.

  14. Production of Hydrogen and Electricity from Coal with CO2 Capture

    E-Print Network [OSTI]

    1 Production of Hydrogen and Electricity from Coal with CO2 Capture Princeton University: Tom use (transportation and heating) responsible for ~2/3 of global CO2 emissions · CO2 capture energy carriers are needed: electricity and hydrogen. · If CO2 sequestration is viable, fossil fuel

  15. Occupational and traning requirements for expanded coal production (as of October 1980). [Forecasting to 1995

    SciTech Connect (OSTI)

    Not Available

    1982-04-01T23:59:59.000Z

    This study was initiated because of the anticipated rapid growth in trained personnel requirements in bituminous coal mining, and because the industry had already experienced significant problems in recruiting skilled manpower in the course of its employment expansion during the 1970's. Employment in bituminous coal mining is projected to nearly double, from 234,000 in 1977 to 456,000 in 1995, as the net result of a projected threefold increase in coal output to nearly 2.0 billion in 1995 and of an expected significant improvement in overall productivity. A large proportion of current coal mining employees are in occupations which require significant amounts of training for effective work performance. Employment growth to 1955 will be most rapid in those occupations requiring the greatest training or educational preparation. The new training infrastructure which has emerged to meet these needs includes both internal, company-operated training programs and those offered by various external providers. Among the latter are: Vocational schools, community colleges, and university extension departments; public agencies, such as MSHA and state mining departments; coal industry trade associations; and vendors or training consultant groups. The Conference Board survey of coal industry training programs, conducted in late 1979, was designed to provide comprehensive data on the scope of the coal industry's own training activities and on related training issues, based on a mail questionnaire survey addressed to all companies producing 300,000 or more tons per year. The training programs are described with emphasis on time changes, regional effects and implications for a coordinated plan.

  16. Technical support for the Ohio Coal Technology Program. Volume 1, Baseline of knowledge concerning by-product characteristics: Final report

    SciTech Connect (OSTI)

    Olfenbuttel, R.; Clark, S.; Helper, E.; Hinchee, R.; Kuntz, C.; Means, J.; Oxley, J.; Paisley, M.; Rogers, C.; Sheppard, W.; Smolak, L. [Battelle, Columbus, OH (United States)

    1989-08-28T23:59:59.000Z

    This report was prepared for the Ohio Coal Development Office (OCDO) under Grant Agreement No. CDO/R-88-LRl and comprises two volumes. Volume I presents data on the chemical, physical, and leaching characteristics of by-products from a wide variety of clean coal combustion processes. Volume II consists of a discussion of (a) process modification waste minimization opportunities and stabilization considerations; (b) research and development needs and issues relating to clean coal combustion technologies and by-products; (c) the market potential for reusing or recycling by-product materials; and (d) regulatory considerations relating to by-product disposal or reuse.

  17. UNDERGROUNG PLACEMENT OF COAL PROCESSING WASTE AND COAL COMBUSTION BY-PRODUCTS BASED PASTE BACKFILL FOR ENHANCED MINING ECONOMICS

    SciTech Connect (OSTI)

    Y.P. Chugh; D. Biswas; D. Deb

    2002-06-01T23:59:59.000Z

    This project has successfully demonstrated that the extraction ratio in a room-and-pillar panel at an Illinois mine can be increased from the current value of approximately 56% to about 64%, with backfilling done from the surface upon completion of all mining activities. This was achieved without significant ground control problems due to the increased extraction ratio. The mined-out areas were backfilled from the surface with gob, coal combustion by-products (CCBs), and fine coal processing waste (FCPW)-based paste backfill containing 65%-70% solids to minimize short-term and long-term surface deformations risk. This concept has the potential to increase mine productivity, reduce mining costs, manage large volumes of CCBs beneficially, and improve the miner's health, safety, and environment. Two injection holes were drilled over the demonstration panel to inject the paste backfill. Backfilling was started on August 11, 1999 through the first borehole. About 9,293 tons of paste backfill were injected through this borehole with a maximum flow distance of 300-ft underground. On September 27, 2000, backfilling operation was resumed through the second borehole with a mixture of F ash and FBC ash. A high-speed auger mixer (new technology) was used to mix solids with water. About 6,000 tons of paste backfill were injected underground through this hole. Underground backfilling using the ''Groutnet'' flow model was simulated. Studies indicate that grout flow over 300-foot distance is possible. Approximately 13,000 tons of grout may be pumped through a single hole. The effect of backfilling on the stability of the mine workings was analyzed using SIUPANEL.3D computer program and further verified using finite element analysis techniques. Stiffness of the backfill mix is most critical for enhancing the stability of mine workings. Mine openings do not have to be completely backfilled to enhance their stability. Backfill height of about 50% of the seam height is adequate to minimize surface deformations. Freeman United Coal Company performed engineering economic evaluation studies for commercialization. They found that the costs for underground management at the Crown III mine would be slightly higher than surface management at this time. The developed technologies have commercial potential but each site must be analyzed on its merit. The Company maintains significant interest in commercializing the technology.

  18. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    SciTech Connect (OSTI)

    Caroline E. Burgess Clifford; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2007-03-17T23:59:59.000Z

    This report summarizes the accomplishments toward project goals during the no cost extension period of the third year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts for a third round of testing, the use of a research gasoline engine to test coal-based gasoline, and modification of diesel engines for use in evaluating diesel produced in the project. At the pilot scale, the hydrotreating process was modified to separate the heavy components from the LCO and RCO fractions before hydrotreating in order to improve the performance of the catalysts in further processing. Hydrotreating and hydrogenation of the product has been completed, and due to removal of material before processing, yield of the jet fuel fraction has decreased relative to an increase in the gasoline fraction. Characterization of the gasoline fuel indicates a dominance of single ring alkylcycloalkanes that have a low octane rating; however, blends containing these compounds do not have a negative effect upon gasoline when blended in refinery gasoline streams. Characterization of the diesel fuel indicates a dominance of 3-ring aromatics that have a low cetane value; however, these compounds do not have a negative effect upon diesel when blended in refinery diesel streams. Both gasoline and diesel continue to be tested for combustion performance. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Activated carbons have proven useful to remove the heavy sulfur components, and unsupported Ni/Mo and Ni/Co catalysts have been very effective for hydrodesulfurization. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Combustion and characterization of the latest fuel oil (the high temperature fraction of RCO from the latest modification) indicates that the fraction is heavier than a No. 6 fuel oil. Combustion efficiency on our research boiler is {approx}63% for the heavy RCO fraction, lower than the combustion performance for previous co-coking fuel oils and No. 6 fuel oil. Emission testing indicates that the coal derived material has more trace metals related to coal than petroleum, as seen in previous runs. An additional coal has been procured and is being processed for the next series of delayed co-coking runs. The co-coking of the runs with the new coal have begun, with the coke yield similar to previous runs, but the gas yield is lower and the liquid yield is higher. Characterization of the products continues. Work continues on characterization of liquids and solids from co-coking of hydrotreated decant oils; liquid yields include more saturated and hydro- aromatics, while the coke quality varies depending on the conditions used. Pitch material is being generated from the heavy fraction of co-coking.

  19. Method for controlling boiling point distribution of coal liquefaction oil product

    DOE Patents [OSTI]

    Anderson, Raymond P. (Overland Park, KS); Schmalzer, David K. (Englewood, CO); Wright, Charles H. (Overland Park, KS)

    1982-12-21T23:59:59.000Z

    The relative ratio of heavy distillate to light distillate produced in a coal liquefaction process is continuously controlled by automatically and continuously controlling the ratio of heavy distillate to light distillate in a liquid solvent used to form the feed slurry to the coal liquefaction zone, and varying the weight ratio of heavy distillate to light distillate in the liquid solvent inversely with respect to the desired weight ratio of heavy distillate to light distillate in the distillate fuel oil product. The concentration of light distillate and heavy distillate in the liquid solvent is controlled by recycling predetermined amounts of light distillate and heavy distillate for admixture with feed coal to the process in accordance with the foregoing relationships.

  20. Method for controlling boiling point distribution of coal liquefaction oil product

    DOE Patents [OSTI]

    Anderson, R.P.; Schmalzer, D.K.; Wright, C.H.

    1982-12-21T23:59:59.000Z

    The relative ratio of heavy distillate to light distillate produced in a coal liquefaction process is continuously controlled by automatically and continuously controlling the ratio of heavy distillate to light distillate in a liquid solvent used to form the feed slurry to the coal liquefaction zone, and varying the weight ratio of heavy distillate to light distillate in the liquid solvent inversely with respect to the desired weight ratio of heavy distillate to light distillate in the distillate fuel oil product. The concentration of light distillate and heavy distillate in the liquid solvent is controlled by recycling predetermined amounts of light distillate and heavy distillate for admixture with feed coal to the process in accordance with the foregoing relationships. 3 figs.

  1. HYDROGEN PRODUCTION FOR FUEL CELLS VIA REFORMING COAL-DERIVED METHANOL

    SciTech Connect (OSTI)

    Paul A. Erickson

    2006-04-01T23:59:59.000Z

    Hydrogen can be produced from many feedstocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the tenth report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of January 1-March 31, 2006. This quarter saw progress in six areas. These areas are: (1) The effect of catalyst dimension on steam reforming, (2) Transient characteristics of autothermal reforming, (3) Rich and lean autothermal reformation startup, (4) Autothermal reformation degradation with coal derived methanol, (5) Reformate purification system, and (6) Fuel cell system integration. All of the projects are proceeding on or slightly ahead of schedule.

  2. Hydrogen Production for Fuel Cells Via Reforming Coal-Derived Methanol

    SciTech Connect (OSTI)

    Paul A. Erickson

    2005-06-30T23:59:59.000Z

    Hydrogen can be produced from many feedstocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the seventh report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of April 1-June 31, 2005. This quarter saw progress in these areas. These areas are: (1) Steam reformer transient response, (2) Heat transfer enhancement, (3) Catalyst degradation, (4) Catalyst degradation with bluff bodies, and (5) Autothermal reforming of coal-derived methanol. All of the projects are proceeding on or slightly ahead of schedule.

  3. Hydrogen Production for Fuel Cells Via Reforming Coal-Derived Methanol

    SciTech Connect (OSTI)

    Paul A. Erickson

    2004-06-30T23:59:59.000Z

    Hydrogen can be produced from many feed stocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the third report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of April 1-June 30, 2004. This quarter saw progress in five areas. These areas are: (1) External evaluation of coal based methanol and the fuel cell grade baseline fuel, (2) Design, set up and initial testing of the autothermal reactor, (3) Experiments to determine the axial and radial thermal profiles of the steam reformers, (4) Catalyst degradation studies, and (5) Experimental investigations of heat and mass transfer enhancement methods by flow field manipulation. All of the projects are proceeding on or slightly ahead of schedule.

  4. Chemical Fixation of CO2 in Coal Combustion Products and Recycling through Biosystems

    SciTech Connect (OSTI)

    C. Henry Copeland; Paul Pier; Samantha Whitehead; David Behel

    2002-09-30T23:59:59.000Z

    This Annual Technical Progress Report presents the principal results in enhanced growth of algae using coal combustion products as a catalyst to increase bicarbonate levels in solution. Optimal production of biomass depends on a number of factors. These factors include pH management, harvesting, and impact of auxiliary operations on the algae population. A number of experiments are presented which attempt to identify and characterize the impact of these factors.

  5. Hydrogen Production for Fuel Cells Via Reforming Coal-Derived Methanol

    SciTech Connect (OSTI)

    Paul A. Erickson

    2004-09-30T23:59:59.000Z

    Hydrogen can be produced from many feed stocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the fourth report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of July 1-Sept 30, 2004 along with a recap of progress from the start of the project on Oct 1, 2003 to Sept 30, 2004. All of the projects are proceeding on or slightly ahead of schedule. This year saw progress in several areas. These areas are: (1) External and internal evaluation of coal based methanol and a fuel cell grade baseline fuel, (2) Design set up and initial testing of three laboratory scale steam reformers, (3) Design, set up and initial testing of a laboratory scale autothermal reactor, (4) Hydrogen generation from coal-derived methanol using steam reformation, (5) Experiments to determine the axial and radial thermal profiles of the steam reformers, (6) Initial catalyst degradation studies with steam reformation and coal based methanol, and (7) Experimental investigations of heat and mass transfer enhancement methods by flow field manipulation. All of the projects are proceeding on or slightly ahead of schedule.

  6. Coal industry annual 1993

    SciTech Connect (OSTI)

    Not Available

    1994-12-06T23:59:59.000Z

    Coal Industry Annual 1993 replaces the publication Coal Production (DOE/FIA-0125). This report presents additional tables and expanded versions of tables previously presented in Coal Production, including production, number of mines, Productivity, employment, productive capacity, and recoverable reserves. This report also presents data on coal consumption, coal distribution, coal stocks, coal prices, coal quality, and emissions for a wide audience including the Congress, Federal and State agencies, the coal industry, and the general public. In addition, Appendix A contains a compilation of coal statistics for the major coal-producing States. This report does not include coal consumption data for nonutility Power Producers who are not in the manufacturing, agriculture, mining, construction, or commercial sectors. This consumption is estimated to be 5 million short tons in 1993.

  7. ENHANCED COAL BED METHANE PRODUCTION AND SEQUESTRATION OF CO2 IN UNMINEABLE COAL SEAMS

    SciTech Connect (OSTI)

    William A. Williams

    2004-10-01T23:59:59.000Z

    This is the sixth semi-annual Technical Progress report under the subject agreement. During this report period, progress was made on drilling the north, center, and south well sites. Water production commenced at the center and south well sites. New drilling plans were formulated for the last remaining well, which is in the Upper Freeport Seam at the north site. Core samples were submitted to laboratories for analytical testing. These aspects of the project are discussed in detail in this report.

  8. Process development for production of coal/sorbent agglomerates

    SciTech Connect (OSTI)

    Rapp, D.M.; Lytle, J.M.; Hackley, K.C.; Moran, D.L.; Becvar, S. (Illinois State Geological Survey, Champaign, IL (United States)); Berger, R.L. (Illinois Univ., Urbana, IL (United States)); Griggs, K. (Army Construction Engineering Research Lab., Champaign, IL (United States))

    1991-01-01T23:59:59.000Z

    The objective of this work is to pelletize these fines with a sulfur capturing sorbent such as calcium hydroxide to produce a fuel which will meet future sulfur dioxide emission levels. To decrease binder costs, carbonation, which is the reaction of calcium hydroxide with carbon dioxide in the presence of moisture to produce calcium carbonate, is being investigated as a method for improving pellet quality. The calcium carbonate formed acts as a cementitious matrix which improves pellet strength. Two potential combustion options are being considered -- fluidized bed combustors and industrial stoker boilers. During this quarter a pellet characterization test program was conducted using a fine coal (-28 mesh) concentrate collected from a southern Illinois preparation plant. Results indicate that carbonation produces significant improvements in compressive strength, impact and attrition resistance and weatherability. Also, 20 combustion tests were conducted on pellets formed with 0, 5 and 10% levels of calcium hydroxide (10% calcium hydroxide is a 2.3:1 Ca/S ratio for this sample). Tests were conducted at 850 and 1350 {degrees}C. Chemical analyses of the combustion residues are not yet complete so results will be reported next quarter. 8 refs., 7 tabs.

  9. PNNL Coal Gasification Research

    SciTech Connect (OSTI)

    Reid, Douglas J.; Cabe, James E.; Bearden, Mark D.

    2010-07-28T23:59:59.000Z

    This report explains the goals of PNNL in relation to coal gasification research. The long-term intent of this effort is to produce a syngas product for use by internal Pacific Northwest National Laboratory (PNNL) researchers in materials, catalysts, and instrumentation development. Future work on the project will focus on improving the reliability and performance of the gasifier, with a goal of continuous operation for 4 hours using coal feedstock. In addition, system modifications to increase operational flexibility and reliability or accommodate other fuel sources that can be used for syngas production could be useful.

  10. WABASH RIVER INTEGRATED METHANOL AND POWER PRODUCTION FROM CLEAN COAL TECHNOLOGIES (IMPPCCT)

    SciTech Connect (OSTI)

    Albert Tsang

    2003-03-14T23:59:59.000Z

    The Wabash River Integrated Methanol and Power Production from Clean Coal Technologies (IMPPCCT) project is evaluating integrated electrical power generation and methanol production through clean coal technologies. The project is conducted by a multi-industry team lead by Gasification Engineering Corporation (GEC), a company of Global Energy Inc., and supported by Air Products and Chemicals, Inc., Dow Chemical Company, Dow Corning Corporation, Methanex Corporation, and Siemens Westinghouse Power Corporation. Three project phases are planned for execution over several years, including: (1) Feasibility study and conceptual design for an integrated demonstration facility, and for fence-line commercial embodiment plants (CEP) operated at Dow Chemical or Dow Corning chemical plant locations (2) Research, development, and testing to define any technology gaps or critical design and integration issues (3) Engineering design and financing plan to install an integrated commercial demonstration facility at the existing Wabash River Energy Limited (WREL) plant in West Terre Haute, Indiana.

  11. Proceedings: 15th International American Coal Ash Association Symposium on Management and Use of Coal Combustion Products (CCPs): Building Partnerships for Sustainability

    SciTech Connect (OSTI)

    None

    2003-01-01T23:59:59.000Z

    Topics discussed at the 15th International American Coal Ash Association (ACAA) Symposium, ''Management and Use of Coal Combustion Products (CCPs),'' included fundamental CCP use, research, product marketing, applied research, CCP management and environmental issues, and commercial uses. There is a continuing international research interest in CCP use because of its commercial value and its environmental benefits, such as reducing greenhouse gas emissions, reducing landfill needs, and utilizing recycled materials instead of virgin materials. CCP use also can reduce disposal costs and generate revenue from CCP sales.

  12. Environmental-control considerations in the production and use of solvent-refined coal

    SciTech Connect (OSTI)

    Huang, H.S.

    1980-12-01T23:59:59.000Z

    This report presents the results of an environmental-control study of the solvent-refined-coal (SRC) process. The report complements a previous Argonne report: Assessment of Status of Technology for Solvent Refining of Coal (ANL/ECT-3, Appendix B). The current review separates discussion of environmental control into two broad sections: production of SRC fuels, both solid and liquid, and their utilization. Control technologies are briefly reviewed for the gas, liquid, and solid wastes generated by the production of SRC. For an SRC-I plant, producing solid product, potential waste streams are then identified and discussed in terms of applicable control technologies and promulgated EPA standards. The SRC-production section concludes with a discussion of the biological activity of certain products of an SRC-II plant, producing liquid fuel. The author summarizes recent experimental findings and recommends accelerated research at SRC plants to quantify the effects of biological activity and develop measures needed to reduce those effects. No unusual environmental-control problems have been detected in the combustion of SRC fuels. It is recommended, however, that more SRC combustion studies be made and that the solid and liquid fuels used in them be derived from a variety of parent coals. Such studies will establish the broad data base needed to demonstrate that SRC fuels burn efficiently within environmentally safe limits.

  13. Utilization ROLE OF COAL COMBUSTION

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    , materials left after combustion of coal in conventional and/ or advanced clean-coal technology combustors and advanced clean-coal technology combustors. This paper describes various coal combustion products produced (FGD) products from pulverized coal and advanced clean-coal technology combustors. Over 70% of the CCPs

  14. Hydrogen Production for Fuel Cells Via Reforming Coal-Derived Methanol

    SciTech Connect (OSTI)

    Paul A. Erickson

    2005-09-30T23:59:59.000Z

    Hydrogen can be produced from many feedstocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the eighth report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of October 1, 2004-September 30, 2005 and includes an entire review of the progress for year 2 of the project. This year saw progress in eight areas. These areas are: (1) steam reformer transient response, (2) steam reformer catalyst degradation, (3) steam reformer degradation tests using bluff bodies, (4) optimization of bluff bodies for steam reformation, (5) heat transfer enhancement, (6) autothermal reforming of coal derived methanol, (7) autothermal catalyst degradation, and (8) autothermal reformation with bluff bodies. The project is on schedule and is now shifting towards the design of an integrated PEM fuel cell system capable of using the coal-derived product. This system includes a membrane clean up unit and a commercially available PEM fuel cell.

  15. Production and Optimization of Direct Coal Liquefaction derived Low Carbon-Footprint Transportation Fuels

    SciTech Connect (OSTI)

    Steven Markovich

    2010-06-30T23:59:59.000Z

    This report summarizes works conducted under DOE Contract No. DE-FC26-05NT42448. The work scope was divided into two categories - (a) experimental program to pretreat and refine a coal derived syncrude sample to meet transportation fuels requirements; (b) system analysis of a commercial scale direct coal liquefaction facility. The coal syncrude was derived from a bituminous coal by Headwaters CTL, while the refining study was carried out under a subcontract to Axens North America. The system analysis included H{sub 2} production cost via six different options, conceptual process design, utilities requirements, CO{sub 2} emission and overall plant economy. As part of the system analysis, impact of various H{sub 2} production options was evaluated. For consistence the comparison was carried out using the DOE H2A model. However, assumptions in the model were updated using Headwaters database. Results of Tier 2 jet fuel specifications evaluation by the Fuels & Energy Branch, US Air Force Research Laboratory (AFRL/RZPF) located at Wright Patterson Air Force Base (Ohio) are also discussed in this report.

  16. Production of a pellet fuel from Illinois coal fines. Technical report, September 1--November 30, 1994

    SciTech Connect (OSTI)

    Rapp, D.; Lytle, J.; Berger, R.

    1994-12-31T23:59:59.000Z

    The primary goal of this research is to produce a pellet fuel from low-sulfur Illinois coal fines which could burn with emissions of less than 1.8 lbs SO{sub 2}/10{sup 6} Btu in stoker-fired boilers. The significance of 1.8 lbs SO{sub 2}/10{sup 6} Btu is that in the Chicago (9 counties) and St. Louis (2 counties) metropolitan areas, industrial users of coal currently must comply with this level of emissions. Stokers are an attractive market for pellets because pellets are well-suited for this application and because western coal is not a competitor in the stoker market. Compliance stoker fuels come from locations such as Kentucky and West Virginia and the price for fuels from these locations is high relative to the current price of Illinois coal. This market offers the most attractive near-term economic environment for commercialization of pelletization technology. For this effort, the authors will be investigating the use of fines from two Illinois mines which currently mine relatively low-sulfur reserves and that discard their fines fraction (minus 100 mesh). The research will involve investigation of multiple unit operations including column flotation, filtration and pellet production. The end result of the effort will allow for an evaluation of the commercial viability of the approach. This quarter pellet production work commenced and planning for collection and processing of a preparation plant fines fraction is underway.

  17. Coal liquefaction and hydrogenation

    DOE Patents [OSTI]

    Schindler, Harvey D. (Fair Lawn, NJ); Chen, James M. (Edison, NJ)

    1985-01-01T23:59:59.000Z

    Disclosed is a coal liquefaction process using two stages. The first stage liquefies the coal and maximizes the product while the second stage hydrocracks the remainder of the coal liquid to produce solvent.

  18. Coal-by-Rail: A Business-as-Usual Reference Case | Argonne National...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    proposed carbon emission standards reduce domestic coal use, the role of coal in the U.S. energy mix may be expected to decline. If such a decline were to occur, how would it...

  19. Environmental Analysis of the Coal-based Power Production with Amine-based Carbon Capture

    E-Print Network [OSTI]

    . Based on LCA methodology the study examines the operation of six coal power plants, which differ by the expected efficiency parameters for the year 2020: (1) Coal plant2005: pulverized coal power plant already operating in 2005 (2) Coal plant2010: pulverized coal power plant installed in 2010 (3) Coal plant2020

  20. ADVANCED MULTI-PRODUCT COAL UTILIZATION BY-PRODUCT PROCESSING PLANT

    SciTech Connect (OSTI)

    Robert Jewell; Thomas Robl; John Groppo

    2005-03-01T23:59:59.000Z

    The objective of the project is to build a multi-product ash beneficiation plant at Kentucky Utilities 2,200-MW Ghent Generating Station, located in Carroll County, Kentucky. This part of the study includes the examination of the feedstocks for the beneficiation plant. The ash, as produced by the plant, and that stored in the lower pond were examined. The ash produced by the plant was found to be highly variable as the plant consumes high and low sulfur bituminous coal, in Units 1 and 2 and a mixture of subbituminous and bituminous coal in Units 3 and 4. The ash produced reflected this consisting of an iron-rich ({approx}24%, Fe{sub 2}O{sub 3}), aluminum rich ({approx}29% Al{sub 2}O{sub 3}) and high calcium (6%-7%, CaO) ash, respectively. The LOI of the ash typically was in the range of 5.5% to 6.5%, but individual samples ranged from 1% to almost 9%. The lower pond at Ghent is a substantial body, covering more than 100 acres, with a volume that exceeds 200 million cubic feet. The sedimentation, stratigraphy and resource assessment of the in place ash was investigated with vibracoring and three-dimensional, computer-modeling techniques. Thirteen cores to depths reaching nearly 40 feet, were retrieved, logged in the field and transported to the lab for a series of analyses for particle size, loss on ignition, petrography, x-ray diffraction, and x-ray fluorescence. Collected data were processed using ArcViewGIS, Rockware, and Microsoft Excel to create three-dimensional, layered iso-grade maps, as well as stratigraphic columns and profiles, and reserve estimations. The ash in the pond was projected to exceed 7 million tons and contain over 1.5 million tons of coarse carbon, and 1.8 million tons of fine (<10 {micro}m) glassy pozzolanic material. The size, quality and consistency of the ponded material suggests that it is the better feedstock for the beneficiation plant.

  1. DEVELOPMENT OF CONTINUOUS SOLVENT EXTRACTION PROCESSES FOR COAL DERIVED CARBON PRODUCTS

    SciTech Connect (OSTI)

    Elliot B. Kennel; Philip L. Biedler; Chong Chen; Dady Dadyburjor; Liviu Magean; Peter G. Stansberry; Alfred H. Stiller; John W. Zondlo

    2005-04-13T23:59:59.000Z

    The purpose of this DOE-funded effort is to develop continuous processes for solvent extraction of coal for the production of carbon products. These carbon products include materials used in metals smelting, especially in the aluminum and steel industries, as well as porous carbon structural material referred to as ''carbon foam'' and carbon fibers. A process has been developed which results in high quality binder pitch suitable for use in graphite electrodes or carbon anodes. A detailed description of the protocol is given by Clendenin. Briefly, aromatic heavy oils are hydro-treated under mild conditions in order to increase their ability to dissolve coal. An example of an aromatic heavy oil is Koppers Carbon Black Base (CBB) oil. CBB oil has been found to be an effective solvent and acceptably low cost (i.e., significantly below the market price for binder pitch, or about $280 per ton at the time of this writing). It is also possible to use solvents derived from hydrotreated coal and avoid reliance on coke oven recovery products completely if so desired.

  2. Co-production of electricity and alternate fuels from coal. Final report, August 1995

    SciTech Connect (OSTI)

    NONE

    1995-12-31T23:59:59.000Z

    The Calderon process and its process development unit, PDU, were originally conceived to produce two useful products from a bituminous coal: a desulfurized medium BTU gas containing primarily CO, H{sub 2}, CH{sub 4}, CO{sub 2}, and H{sub 2}O; and a desulfurized low BTU gas containing these same constituents plus N{sub 2} from the air used to provide heat for the process through the combustion of a portion of the fuel. The process was viewed as a means for providing both a synthesis gas for liquid fuel production (perhaps CH{sub 3}OH, alternatively CH{sub 4} or NH{sub 3}) and a pressurized, low BTU fuel gas, for gas turbine based power generation. The Calderon coal process comprises three principle sections which perform the following functions: coal pyrolysis in a continuous, steady flow unit based on coke oven technology; air blown, slagging, coke gasification in a moving bed unit based on a blast furnace technology; and a novel, lime pebble based, product gas processing in which a variety of functions are accomplished including the cracking of hydrocarbons and the removal of sulfur, H{sub 2}S, and of particulates from both the medium and low BTU gases. The product gas processing unit, based on multiple moving beds, has also been conceived to regenerate the lime pebbles and recover sulfur as elemental S.

  3. WABASH RIVER INTEGRATED METHANOL AND POWER PRODUCTION FROM CLEAN COAL TECHNOLOGIES (IMPPCCT)

    SciTech Connect (OSTI)

    Thomas Lynch

    2004-01-07T23:59:59.000Z

    The Wabash River Integrated Methanol and Power Production from Clean Coal Technologies (IMPPCCT) project is evaluating integrated electrical power generation and methanol production through clean coal technologies. The project is conducted by a multi-industry team lead previously by Gasification Engineering Corporation (GEC). The project is now under the leadership of ConocoPhillips Company (COP) after it acquired GEC and the E-Gas{trademark} gasification technology from Global Energy in July 2003. The Phase I of this project was supported by Air Products and Chemicals, Inc., Dow Chemical Company, Dow Corning Corporation, Methanex Corporation, and Siemens Westinghouse Power Corporation, while the Phase II is supported by Gas Technology Institute, TDA Research, Inc., and Nucon International, Inc. The two project phases planned for execution include: (1) Feasibility study and conceptual design for an integrated demonstration facility at Global Energy's existing Wabash River Energy Limited (WREL) plant in West Terre Haute, Indiana, and for a fence-line commercial embodiment plants (CEP) operated at Dow Chemical or Dow Corning chemical plant locations (2) Research, development, and testing (RD&T) to define any technology gaps or critical design and integration issues. The WREL facility was designed, constructed, and operated under a project selected and co-funded under the Round IV of the United States Department of Energy's (DOE's) Clean Coal Technology Program. In this project, coal and/or other solid fuel feedstocks are gasified in an oxygen-blown, entrained-flow gasifier with continuous slag removal and a dry particulate removal system. The resulting product synthesis gas is used to fuel a combustion turbine generator whose exhaust is integrated with a heat recovery steam generator to drive a refurbished steam turbine generator. The gasifier uses technology initially developed by The Dow Chemical Company (the Destec Gasification Process), and now acquired and offered commercially by COP as the E-GAS{trademark} technology. In a joint effort with the DOE, a Cooperative Agreement was awarded under the Early Entrance Coproduction Plant (EECP) solicitation. GEC, and now COP and the industrial partners are investigating the use of synthesis gas produced by the E-GAS{trademark} technology in a coproduction environment to enhance the efficiency and productivity of solid fuel gasification combined cycle power plants. The objectives of this effort are to determine the feasibility of an EECP located at a specific site which produces some combination of electric power (or heat), fuels, and/or chemicals from synthesis gas derived from coal, or, coal in combination with some other carbonaceous feedstock. The project's intended result is to provide the necessary technical, economic, and environmental information that will be needed to move the EECP forward to detailed design, construction, and operation by industry.

  4. Design of generic coal conversion facilities: Production of oxygenates from synthesis gas---A technology review

    SciTech Connect (OSTI)

    Not Available

    1991-10-01T23:59:59.000Z

    This report concentrates on the production of oxygenates from coal via gasification and indirect liquefaction. At the present the majority of oxygenate synthesis programs are at laboratory scale. Exceptions include commercial and demonstration scale plants for methanol and higher alcohols production, and ethers such as MTBE. Research and development work has concentrated on elucidating the fundamental transport and kinetic limitations governing various reactor configurations. But of equal or greater importance has been investigations into the optimal catalyst composition and process conditions for the production of various oxygenates.

  5. Advanced Multi-Product Coal Utilization By-Product Processing Plant

    SciTech Connect (OSTI)

    Thomas Robl; John Groppo

    2009-06-30T23:59:59.000Z

    The overall objective of this project is to design, construct, and operate an ash beneficiation facility that will generate several products from coal combustion ash stored in a utility ash pond. The site selected is LG&E's Ghent Station located in Carroll County, Kentucky. The specific site under consideration is the lower ash pond at Ghent, a closed landfill encompassing over 100 acres. Coring activities revealed that the pond contains over 7 million tons of ash, including over 1.5 million tons of coarse carbon and 1.8 million tons of fine (<10 {micro}m) glassy pozzolanic material. These potential products are primarily concentrated in the lower end of the pond adjacent to the outlet. A representative bulk sample was excavated for conducting laboratory-scale process testing while a composite 150 ton sample was also excavated for demonstration-scale testing at the Ghent site. A mobile demonstration plant with a design feed rate of 2.5 tph was constructed and hauled to the Ghent site to evaluate unit processes (i.e. primary classification, froth flotation, spiral concentration, secondary classification, etc.) on a continuous basis to determine appropriate scale-up data. Unit processes were configured into four different flowsheets and operated at a feed rate of 2.5 tph to verify continuous operating performance and generate bulk (1 to 2 tons) products for product testing. Cementitious products were evaluated for performance in mortar and concrete as well as cement manufacture process addition. All relevant data from the four flowsheets was compiled to compare product yields and quality while preliminary flowsheet designs were generated to determine throughputs, equipment size specifications and capital cost summaries. A detailed market study was completed to evaluate the potential markets for cementitious products. Results of the study revealed that the Ghent local fly ash market is currently oversupplied by more than 500,000 tpy and distant markets (i.e. Florida) are oversupplied as well. While the total US demand for ultrafine pozzolan is currently equal to demand, there is no reason to expect a significant increase in demand. Despite the technical merits identified in the pilot plant work with regard to beneficiating the entire pond ash stream, market developments in the Ohio River Valley area during 2006-2007 were not conducive to demonstrating the project at the scale proposed in the Cooperative Agreement. As a result, Cemex withdrew from the project in 2006 citing unfavorable local market conditions in the foreseeable future at the demonstration site. During the Budget Period 1 extensions provided by the DOE, CAER has contacted several other companies, including cement producers and ash marketing concerns for private cost share. Based on the prevailing demand-supply situation, these companies had expressed interest only in limited product lines, rather than the entire ash beneficiation product stream. Although CAER had generated interest in the technology, a financial commitment to proceed to Budget Period 2 could not be obtained from private companies. Furthermore, the prospects of any decisions being reached within a reasonable time frame were dim. Thus, CAER concurred with the DOE to conclude the project at the end of Budget Period 1, March 31, 2007. The activities presented in this report were carried out during the Cooperative Agreement period 08 November 2004 through 31 March 2007.

  6. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    SciTech Connect (OSTI)

    Caroline Clifford; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2008-03-31T23:59:59.000Z

    The final report summarizes the accomplishments toward project goals during length of the project. The goal of this project was to integrate coal into a refinery in order to produce coal-based jet fuel, with the major goal to examine the products other than jet fuel. These products are in the gasoline, diesel and fuel oil range and result from coal-based jet fuel production from an Air Force funded program. The main goal of Task 1 was the production of coal-based jet fuel and other products that would need to be utilized in other fuels or for non-fuel sources, using known refining technology. The gasoline, diesel fuel, and fuel oil were tested in other aspects of the project. Light cycle oil (LCO) and refined chemical oil (RCO) were blended, hydrotreated to removed sulfur, and hydrogenated, then fractionated in the original production of jet fuel. Two main approaches, taken during the project period, varied where the fractionation took place, in order to preserve the life of catalysts used, which includes (1) fractionation of the hydrotreated blend to remove sulfur and nitrogen, followed by a hydrogenation step of the lighter fraction, and (2) fractionation of the LCO and RCO before any hydrotreatment. Task 2 involved assessment of the impact of refinery integration of JP-900 production on gasoline and diesel fuel. Fuel properties, ignition characteristics and engine combustion of model fuels and fuel samples from pilot-scale production runs were characterized. The model fuels used to represent the coal-based fuel streams were blended into full-boiling range fuels to simulate the mixing of fuel streams within the refinery to create potential 'finished' fuels. The representative compounds of the coal-based gasoline were cyclohexane and methyl cyclohexane, and for the coal-base diesel fuel they were fluorine and phenanthrene. Both the octane number (ON) of the coal-based gasoline and the cetane number (CN) of the coal-based diesel were low, relative to commercial fuels ({approx}60 ON for coal-based gasoline and {approx}20 CN for coal-based diesel fuel). Therefore, the allowable range of blending levels was studied where the blend would achieve acceptable performance. However, in both cases of the coal-based fuels, their ignition characteristics may make them ideal fuels for advanced combustion strategies where lower ON and CN are desirable. Task 3 was designed to develop new approaches for producing ultra clean fuels and value-added chemicals from refinery streams involving coal as a part of the feedstock. It consisted of the following three parts: (1) desulfurization and denitrogenation which involves both new adsorption approach for selective removal of nitrogen and sulfur and new catalysts for more effective hydrotreating and the combination of adsorption denitrogenation with hydrodesulfurization; (2) saturation of two-ring aromatics that included new design of sulfur resistant noble-metal catalysts for hydrogenation of naphthalene and tetralin in middle distillate fuels, and (3) value-added chemicals from naphthalene and biphenyl, which aimed at developing value-added organic chemicals from refinery streams such as 2,6-dimethylnaphthalene and 4,4{prime}-dimethylbiphenyl as precursors to advanced polymer materials. Major advances were achieved in this project in designing the catalysts and sorbent materials, and in developing fundamental understanding. The objective of Task 4 was to evaluate the effect of introducing coal into an existing petroleum refinery on the fuel oil product, specifically trace element emissions. Activities performed to accomplish this objective included analyzing two petroleum-based commercial heavy fuel oils (i.e., No. 6 fuel oils) as baseline fuels and three co-processed fuel oils, characterizing the atomization performance of a No. 6 fuel oil, measuring the combustion performance and emissions of the five fuels, specifically major, minor, and trace elements when fired in a watertube boiler designed for natural gas/fuel oil, and determining the boiler performance when firing the five fuels. Two

  7. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    SciTech Connect (OSTI)

    Caroline E. Burgess Clifford; Andre' Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2006-09-17T23:59:59.000Z

    This report summarizes the accomplishments toward project goals during the second six months of the third year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts and examination of carbon material, the use of a research gasoline engine to test coal-based gasoline, and modification of diesel engines for use in evaluating diesel produced in the project. At the pilot scale, the hydrotreating process was modified to separate the heavy components from the LCO and RCO fractions before hydrotreating in order to improve the performance of the catalysts in further processing. Characterization of the gasoline fuel indicates a dominance of single ring alkylcycloalkanes that have a low octane rating; however, blends containing these compounds do not have a negative effect upon gasoline when blended in refinery gasoline streams. Characterization of the diesel fuel indicates a dominance of 3-ring aromatics that have a low cetane value; however, these compounds do not have a negative effect upon diesel when blended in refinery diesel streams. Both gasoline and diesel continue to be tested for combustion performance. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Activated carbons have proven useful to remove the heavy sulfur components, and unsupported Ni/Mo and Ni/Co catalysts have been very effective for hydrodesulfurization. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Combustion and characterization of the latest fuel oil (the high temperature fraction of RCO from the latest modification) indicates that the fraction is heavier than a No. 6 fuel oil. Combustion efficiency on our research boiler is {approx}63% for the heavy RCO fraction, lower than the combustion performance for previous co-coking fuel oils and No. 6 fuel oil. An additional coal has been procured and is being processed for the next series of delayed co-coking runs. Work continues on characterization of liquids and solids from co-coking of hydrotreated decant oils; liquid yields include more saturated and hydro- aromatics, while the coke quality varies depending on the conditions used. Pitch material is being generated from the heavy fraction of co-coking. Investigation of coal extraction as a method to produce RCO continues; the reactor modifications to filter the products hot and to do multi-stage extraction improve extraction yields from {approx}50 % to {approx}70%. Carbon characterization of co-cokes for use as various carbon artifacts continues.

  8. HYDROGEN PRODUCTION FOR FUEL CELLS VIA REFORMING COAL-DERIVED METHANOL

    SciTech Connect (OSTI)

    Paul A. Erickson

    2004-04-01T23:59:59.000Z

    Hydrogen can be produced from many feed stocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the first such report that will be submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of October 1--December 31, 2003. This quarter saw progress in three areas. These areas are: (1) Evaluations of coal based methanol and the fuel cell grade baseline fuel, (2) Design and set up of the autothermal reactor, as well as (3) Set up and data collection of baseline performance using the steam reformer. All of the projects are proceeding on schedule. During this quarter one conference paper was written that will be presented at the ASME Power 2004 conference in March 2004, which outlines the research direction and basis for looking at the coal to hydrogen pathway.

  9. Use of coal tar pitch and petroleum bitumen in the production of thermally expanded graphite (Short Communication)

    SciTech Connect (OSTI)

    T.P. Miloshenko; O.Yu. Fetisova; M.L. Shchipko; B.N. Kuznetsov [Russian Academy of Sciences, Krasnoyarsk (Russia). Institute of Chemistry and Chemical Technology

    2008-06-15T23:59:59.000Z

    The applicability of coal tar pitch and petroleum bitumen to the production of thermally expanded graphite was studied. The dependence of the coefficient of thermal expansion and the specific surface area on the amount of added substances was examined.

  10. Electricity production levelized costs for nuclear, gas and coal

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItem Not Found Item Not Found The itemAIR57451 CleanFOR IMMEDIATEDurable 19

  11. Life Cycle Assessment of Coal-fired Power Production

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItem Not Found Item Not Found TheHot electron dynamics in807 DE89 002669Life Cycle

  12. Metallic Membrane Materials Development for Hydrogen Production from Coal

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilAElectronicCurves | SciTechLagrange Multiplier Technique | SciTechDerived Syngas |

  13. UTILIZATION OF LOW NOx COAL COMBUSTION BY-PRODUCTS

    SciTech Connect (OSTI)

    A.M. HEIN; J.Y. HWANG; M.G. MCKIMPSON; R.C. GREENLUND; X. HUANG

    1998-10-01T23:59:59.000Z

    Potomac Electric Power Company (PEPCo) Class F fly ash is the first material to be worked on in this project. A head sample was taken and a screen analysis performed. Each size fraction was evaluated for LOI content. Table 1 shows the distribution of the as-received material by size and LOI content. From the data, 80% of the as-received material is finer than 400 mesh and the LOI content goes from high at coarse fractions and decreases to a low at the finest size fraction. SEM chemical analysis identified the as-received fly ash to mainly consist of silica (46%), aluminum oxide (21%), and iron in various forms (16%). The high iron content presents an extreme case as compared to other fly ash samples we have evaluated previously. Its effect on product testing applications could identify physical and chemical limitations as product testing progresses. Because of the high iron content, it was realized that magnetic separation would be incorporated into the early part of the pilot plant flowsheet to remove magnetic iron and, hopefully, reduce the total iron content. More analytical data will be presented in the next reporting period.

  14. Proceedings: 15th International American Coal Ash Association Symposium on Management and Use of Coal Combustion Products (CCPs): Building Partnerships for Sustainability

    SciTech Connect (OSTI)

    None

    2003-05-01T23:59:59.000Z

    The theme of the symposium is ''building partnerships for sustainability.'' Topics discussed at the 15th International Symposium on Management and Use of CCPs included fundamental coal combustion product (CCP) use research, product marketing, applied research, CCP management and environmental issues, and commercial uses. There is a continuing international research interest in CCP use because of the prospects of avoiding disposal costs, reducing greenhouse gas emissions, and generating revenue from CCP sales.

  15. Low-rank coal study : national needs for resource development. Volume 2. Resource characterization

    SciTech Connect (OSTI)

    Not Available

    1980-11-01T23:59:59.000Z

    Comprehensive data are presented on the quantity, quality, and distribution of low-rank coal (subbituminous and lignite) deposits in the United States. The major lignite-bearing areas are the Fort Union Region and the Gulf Lignite Region, with the predominant strippable reserves being in the states of North Dakota, Montana, and Texas. The largest subbituminous coal deposits are in the Powder River Region of Montana and Wyoming, The San Juan Basin of New Mexico, and in Northern Alaska. For each of the low-rank coal-bearing regions, descriptions are provided of the geology; strippable reserves; active and planned mines; classification of identified resources by depth, seam thickness, sulfur content, and ash content; overburden characteristics; aquifers; and coal properties and characteristics. Low-rank coals are distinguished from bituminous coals by unique chemical and physical properties that affect their behavior in extraction, utilization, or conversion processes. The most characteristic properties of the organic fraction of low-rank coals are the high inherent moisture and oxygen contents, and the correspondingly low heating value. Mineral matter (ash) contents and compositions of all coals are highly variable; however, low-rank coals tend to have a higher proportion of the alkali components CaO, MgO, and Na/sub 2/O. About 90% of the reserve base of US low-rank coal has less than one percent sulfur. Water resources in the major low-rank coal-bearing regions tend to have highly seasonal availabilities. Some areas appear to have ample water resources to support major new coal projects; in other areas such as Texas, water supplies may be constraining factor on development.

  16. European legislation in the United Kingdom: a threat to coal-fired power station product utilization?

    SciTech Connect (OSTI)

    Sear, K.A. [Quality Ash Association (United Kingdom)

    2006-07-01T23:59:59.000Z

    The author considers that the European Union has not taken the approach adopted in the USA where environmental regulators are keen to promote the use of coal-fired power station ash by-product and recycled materials. The United Kingdom has seen, with some dismay, the effects EU legislation is having on the ash industry. This article outlines only some of the problems being tackled. The Waste Framework Directive is difficult to interpret and fails to define critical aspects of the problem. This directive is discussed at some length in the article. A total of nine directives effect the operation of coal-fired power plant. Many are imprecise and open to interpretation and cause a deal of frustration, delays and confusion to the ash supplier and contractor. This is causing markets to suffer.

  17. UTILIZATION OF LOW NOx COAL COMBUSTION BY-PRODUCTS

    SciTech Connect (OSTI)

    None

    1999-07-01T23:59:59.000Z

    The project has switched focus this quarter from pilot plant operations to product testing. Last quarter extensive pilot plant work had occurred and testing objectives had been met. Also last quarter technology demonstrations were also performed for Potomac Electric Power, Virginia Power, and Wisconsin Electric. We had reported that groundbreaking for the PEPCo fly ash treatment facility was to begin in August. Recent conversations with the technology's licensee, Mineral Resource Technology, have resulted in changes. Long term contract negotiations between MRT and Potomac Electric Power have caused delays. Most recent estimates are that contract negotiations should be finished in August, detailed engineering is to begin in September, and groundbreaking to begin in early Spring. The commercialization of the technology is going forward, just not as fast as we or MRT had anticipated. As this is being written we have received inquiries from Plastics Technology Magazine about fly ash utilization in plastics. We are anticipating working with one of their editors to provide an upcoming article.

  18. Wabash River Integrated Methanol and Power Production from Clean Coal Technologies (IMPPCCT)

    SciTech Connect (OSTI)

    Conocophillips

    2007-09-30T23:59:59.000Z

    The Wabash River Integrated Methanol and Power Production from Clean Coal Technologies (IMPPCCT) project was established to evaluate integrated electrical power generation and methanol production through clean coal technologies. The project was under the leadership of ConocoPhillips Company (COP), after it acquired Gasification Engineering Corporation (GEC) and the E-Gas gasification technology from Global Energy Inc. in July 2003. The project has completed both Phase 1 and Phase 2 of development. The two project phases include the following: (1) Feasibility study and conceptual design for an integrated demonstration facility at SG Solutions LLC (SGS), previously the Wabash River Energy Limited, Gasification Facility located in West Terre Haute, Indiana, and for a fence-line commercial embodiment plant (CEP) operated at the Dow Chemical Company or Dow Corning Corporation chemical plant locations. (2) Research, development, and testing (RD&T) to define any technology gaps or critical design and integration issues. Phase 1 of this project was supported by a multi-industry team consisting of Air Products and Chemicals, Inc., The Dow Chemical Company, Dow Corning Corporation, Methanex Corporation, and Siemens Westinghouse Power Corporation, while Phase 2 was supported by Gas Technology Institute, TDA Research Inc., and Nucon International, Inc. The SGS integrated gasification combined cycle (IGCC) facility was designed, constructed, and operated under a project selected and co-funded under the Round IV of the United States Department of Energy's (DOE's) Clean Coal Technology Program. In this project, coal and/or other carbonaceous fuel feedstocks are gasified in an oxygen-blown, entrained-flow gasifier with continuous slag removal and a dry particulate removal system. The resulting product synthesis gas (syngas) is used to fuel a combustion turbine generator whose exhaust is integrated with a heat recovery steam generator to drive a refurbished steam turbine generator. The gasifier uses technology initially developed by The Dow Chemical Company (the Destec Gasification Process), and now acquired and offered commercially by COP as the E-Gas technology. In a joint effort with the DOE, a Cooperative Agreement was awarded under the Early Entrance Coproduction Plant (EECP) solicitation. GEC, and later COP and the industrial partners investigated the use of syngas produced by the E-Gas technology in a coproduction environment to enhance the efficiency and productivity of solid fuel gasification combined cycle power plants. The objectives of this effort were to determine the feasibility of an EECP located at a specific site which produces some combination of electric power (or heat), fuels, and/or chemicals from syngas derived from coal, or, coal in combination with some other carbonaceous feedstock. The intended result of the project was to provide the necessary technical, economic, and environmental information that would be needed to move the EECP forward to detailed design, construction, and operation by industry. The EECP study conducted in Phase 1 of the IMPPCCT Project confirmed that the concept for the integration of gasification-based (E-Gas) electricity generation from coal and/or petroleum coke and methanol production (Liquid Phase Methanol or LPMEOH{trademark}) processes was feasible for the coproduction of power and chemicals. The results indicated that while there were minimal integration issues that impact the deployment of an IMPPCCT CEP, the major concern was the removal of sulfur and other trace contaminants, which are known methanol catalyst poisons, from the syngas. However, economic concerns in the domestic methanol market which is driven by periodic low natural gas prices and cheap offshore supplies limit the commercial viability of this more capital intensive concept. The objective of Phase 2 was to conduct RD&T as outlined in the Phase 1 RD&T Plan to enhance the development and commercial acceptance of coproduction technology. Studies were designed to address the technical concerns that would mak

  19. DEVELOPMENT OF CONTINUOUS SOLVENT EXTRACTION PROCESSES FOR COAL DERIVED CARBON PRODUCTS

    SciTech Connect (OSTI)

    Elliot Kennel; Chong Chen; Dady Dadyburjor; Mark Heavner; Manoj Katakdaunde; Liviu Magean; James Mayberry; Alfred Stiller; Joseph Stoffa; Christopher Yurchick; John Zondlo

    2009-12-31T23:59:59.000Z

    This NETL sponsored effort seeks to develop continuous technologies for the production of carbon products, which may be thought of as the heavier products currently produced from refining of crude petroleum and coal tars obtained from metallurgical grade coke ovens. This effort took binder grade pitch, produced from liquefaction of West Virginia bituminous grade coal, all the way to commercial demonstration in a state of the art arc furnace. Other products, such as crude oil, anode grade coke and metallurgical grade coke were demonstrated successfully at the bench scale. The technology developed herein diverged from the previous state of the art in direct liquefaction (also referred to as the Bergius process), in two major respects. First, direct liquefaction was accomplished with less than a percent of hydrogen per unit mass of product, or about 3 pound per barrel or less. By contrast, other variants of the Bergius process require the use of 15 pounds or more of hydrogen per barrel, resulting in an inherent materials cost. Second, the conventional Bergius process requires high pressure, in the range of 1500 psig to 3000 psig. The WVU process variant has been carried out at pressures below 400 psig, a significant difference. Thanks mainly to DOE sponsorship, the WVU process has been licensed to a Canadian Company, Quantex Energy Inc, with a commercial demonstration unit plant scheduled to be erected in 2011.

  20. Coal-Biomass Feed and Gasification

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Coal-Biomass Feed and Gasification The Coal-Biomass Feed and Gasification Key Technology is advancing scientific knowledge of the production of liquid hydrocarbon fuels from coal...

  1. WABASH RIVER INTEGRATED METHANOL AND POWER PRODUCTION FROM CLEAN COAL TECHNOLOGIES (IMPPCCT)

    SciTech Connect (OSTI)

    Gary Harmond; Albert Tsang

    2003-03-14T23:59:59.000Z

    The Wabash River Integrated Methanol and Power Production from Clean Coal Technologies (IMPPCCT) project is evaluating integrated electrical power generation and methanol production through clean coal technologies. The project is conducted by a multi-industry team lead by Gasification Engineering Corporation (GEC), a company of Global Energy Inc., and supported by Air Products and Chemicals, Inc., Dow Chemical Company, Dow Corning Corporation, Methanex Corporation, and Siemens Westinghouse Power Corporation. Three project phases are planned for execution over a three year period, including: (1) Feasibility study and conceptual design for an integrated demonstration facility, and for fence-line commercial embodiment plants (CEP) operated at Dow Chemical or Dow Corning chemical plant locations (2) Research, development, and testing to define any technology gaps or critical design and integration issues (3) Engineering design and financing plan to install an integrated commercial demonstration facility at the existing Wabash River Energy Limited (WREL) plant in West Terre Haute, Indiana. The WREL facility is a project selected and co-funded under the Round IV of the U.S. Department of Energy's (DOE's) Clean Coal Technology Program. In this project, coal and/or other solid fuel feedstocks are gasified in an oxygen-blown, entrained-flow gasifier with continuous slag removal and a dry particulate removal system. The resulting product synthesis gas is used to fuel a combustion turbine generator whose exhaust is integrated with a heat recovery steam generator to drive a refurbished steam turbine generator. The gasifier uses technology initially developed by The Dow Chemical Company (the Destec Gasification Process), and now offered commercially by Global Energy, Inc., as the E-GAS{trademark} technology. In a joint effort with the DOE, a Cooperative Agreement was awarded under the Early Entrance Coproduction Plant (EECP) solicitation. GEC and an Industrial Consortium are investigating the use of synthesis gas produced by the E-GAS{trademark} technology in a coproduction environment to enhance the efficiency and productivity of solid fuel gasification combined cycle power plants. During the reporting period, various methods to remove low-level contaminants for the synthesis gas were reviewed. In addition, there was a transition of the project personnel for GEC which has slowed the production of the outstanding project reports.

  2. advanced multi-product coal: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Conversion and Utilization Websites Summary: Kumfer, ACERF Manager Consortium for Clean Coal Utilization Fly ash utilization Be a resourceADVANCED COAL & ENERGY RESEARCH...

  3. DEVELOPMENT OF CONTINUOUS SOLVENT EXTRACTION PROCESSES FOR COAL DERIVED CARBON PRODUCTS

    SciTech Connect (OSTI)

    Elliot B. Kennel; Quentin C. Berg; Stephen P. Carpenter; Dady Dadyburjor; Jason C. Hissam; Manoj Katakdaunde; Liviu Magean; Abha Saddawi; Alfred H. Stiller; John W. Zondlo

    2006-03-07T23:59:59.000Z

    The purpose of this DOE-funded effort is to develop continuous processes for solvent extraction of coal for the production of carbon products. The largest applications are those which support metals smelting, such as anodes for aluminum smelting and electrodes for arc furnaces. Other carbon products include materials used in creating fuels for the Direct Carbon Fuel Cell, metals smelting, especially in the aluminum and steel industries, as well as porous carbon structural material referred to as ''carbon foam'' and carbon fibers. During this reporting period, efforts have focused on the development of carbon electrodes for Direct Carbon Fuel Cells (DCFC), and on carbon foam composites used in ballistic armor, as well as the hydrotreatment of solvents used in the basic solvent extraction process. A major goal is the production of 1500 pounds of binder pitch, corresponding to about 3000 pounds of hydrotreated solvent.

  4. Resource Assessment & Production Testing for Coal Bed Methane in the Illinois Basin

    SciTech Connect (OSTI)

    Cortland Eble; James Drahovzal; David Morse; Ilham Demir; John Rupp; Maria Mastalerz; Wilfrido Solano

    2005-11-01T23:59:59.000Z

    In order to assess the economic coal bed methane potential of the Illinois Basin, the geological surveys of Illinois, Indiana and Kentucky performed a geological assessment of their respective parts of the Illinois Basin. A considerable effort went into generating cumulative coal thickness and bed structure maps to identify target areas for exploratory drilling. Following this, the first project well was drilled in White County, Illinois in October 2003. Eight additional wells were subsequently drilled in Indiana (3) and Kentucky (5) during 2004 and 2005. In addition, a five spot pilot completion program was started with three wells being completed. Gas contents were found to be variable, but generally higher than indicated by historical data. Gas contents of more than 300 scf/ton were recovered from one of the bore holes in Kentucky. Collectively, our findings indicate that the Illinois Basin represents a potentially large source of economic coal bed methane. Additional exploration will be required to refine gas contents and the economics of potential production.

  5. WABASH RIVER INTEGRATED METHANOL AND POWER PRODUCTION FROM CLEAN COAL TECHNOLOGIES (IMPPCCT)

    SciTech Connect (OSTI)

    Doug Strickland; Albert Tsang

    2002-10-14T23:59:59.000Z

    The Wabash River Integrated Methanol and Power Production from Clean Coal Technologies (IMPPCCT) project is evaluating integrated electrical power generation and methanol production through clean coal technologies. The project is conducted by a multi-industry team lead by Gasification Engineering Corporation (GEC), and supported by Air Products and Chemicals, Inc., Dow Chemical Company, Dow Corning Corporation, Methanex Corporation, and Siemens Westinghouse Power Corporation. Three project phases are planned for execution over a three year period, including: (1) Feasibility study and conceptual design for an integrated demonstration facility, and for fence-line commercial plants operated at Dow Chemical or Dow Corning chemical plant locations; (2) Research, development, and testing to define any technology gaps or critical design and integration issues; and (3) Engineering design and financing plan to install an integrated commercial demonstration facility at the existing Wabash River Energy Limited (WREL) plant in West Terre Haute, Indiana. This report describes management planning, work breakdown structure development, and feasibility study activities by the IMPPCCT consortium in support of the first project phase. Project planning activities have been completed, and a project timeline and task list has been generated. Requirements for an economic model to evaluate the West Terre Haute implementation and for other commercial implementations are being defined. Specifications for methanol product and availability of local feedstocks for potential commercial embodiment plant sites have been defined. The WREL facility is a project selected and co-funded under the fifth phase solicitation of the U.S. Department of Energy's Clean Coal Technology Program. In this project, coal and/or other solid fuel feedstocks are gasified in an oxygen-blown, entrained-flow gasifier with continuous slag removal and a dry particulate removal system. The resulting product synthesis gas is used to fuel a combustion turbine generator whose exhaust is integrated with a heat recovery steam generator to drive a refurbished steam turbine generator. The gasifier uses technology initially developed by The Dow Chemical Company (the Destec Gasification Process), and now offered commercially by Global Energy, Inc., as the E-GAS{trademark} technology. In a joint effort with the U.S. Department of Energy, working under a Cooperative Agreement Award from the ''Early Entrance Coproduction Plant'' (EECP) initiative, the GEC and an Industrial Consortia are investigating the application of synthesis gas from the E-GAS{trademark} technology to a coproduction environment to enhance the efficiency and productivity of solid fuel gasification combined cycle power plants. The objectives of this effort are to determine the feasibility of an EECP located at a specific site which produces some combination of electric power (or heat), fuels, and/or chemicals from synthesis gas derived from coal, or, coal in combination with some other carbonaceous feedstock. The project's intended result is to provide the necessary technical, economic, and environmental information that will be needed to move the EECP forward to detailed design, construction, and operation by industry.

  6. Washability of trace elements in product coals from Illinois mines. Technical report, 1 March--31 May 1994

    SciTech Connect (OSTI)

    Demir, I.; Ruch, R.R.; Harvey, R.D.; Steele, J.D.; Khan, S.

    1994-09-01T23:59:59.000Z

    Existing washability data on trace elements in Illinois coals were generated using float-sink methods, which are not applicable to modern froth flotation or column flotation processes. Particularly, there is a lack of washability data on product (as-shipped) coals from modern preparation plants. The goal of this project is to provide the needed trace element washability (release analysis) data on as-shipped Illinois coals using a froth flotation/release analysis (FF/RA) procedure. The results generated by this project will promote industrial utilization of Illinois coals and help assess the effect of new environmental requirements on the use of these coals in utility steam generation. During the third quarter, preparation and submission of all samples for chemical analysis were completed. Analyses of the samples produced by cleaning 34 as-shipped coals using FF/RA were completed for ash, moisture, S, heating value (BTU), and F, and some for Mn and oxide composition. The rest of the analytical work is in progress. The analytical data are being used to evaluate removal of ash, S, and trace elements from the as-shipped coals at the chosen flotation conditions and particles sizes. Available data on the FF/RA of five as-shipped coals at {minus}100, {minus}200, {minus}400 mesh sizes indicate that ash and F rejections increase with decreasing particle size. For the {minus}400 mesh tests, 70--90% of the ash and 35--74% of F were rejected at a BTU or combustibles recovery of 80%. One of the as-shipped coals was previously subjected to FF/RA tests at {minus}100 and {minus}400 mesh sizes to investigate mass balances achievable for the procedure. Preliminary results on ash and F contents of complete set of flotation products from the two tests indicate a mass balance of 95 to 100%.

  7. Coal Ash Behavior in Reducing Environments (CABRE) III Year 6 - Activity 1.10 - Development of a National Center for Hydrogen

    SciTech Connect (OSTI)

    Stanislowski, Joshua; Azenkeng, Alexander; McCollor, Donald; Galbreath, Kevin; Jensen, Robert; Lahr, Brent

    2012-03-31T23:59:59.000Z

    The Energy & Environmental Research Center (EERC) has been conducting research on gasification for six decades. One of the objectives of this gasification research has been to maximize carbon conversion and the water–gas shift process for optimal hydrogen production and syngas quality. This research focus and experience were a perfect fit for the National Center for Hydrogen Technology ® (NCHT®) Program at the EERC for improving all aspects of coal gasification, which ultimately aids in the production and purification of hydrogen. A consortia project was developed under the NCHT Program to develop an improved predictive model for ash formation and deposition under the project entitled “Coal Ash Behavior in Reducing Environments (CABRE) III: Development of the CABRE III Model.” The computer-based program is now applicable to the modeling of coal and ash behavior in both entrained-flow and fluidized-bed gasification systems to aid in overall gasification efficiency. This model represents a significant improvement over the CABRE II model and runs on a Microsoft Windows PC platform. The major achievements of the CABRE III model are partitioning of inorganic transformations between various phases for specific gas cleanup equipment; slag property predictions, including standard temperature–viscosity curves and slag flow and thickness; deposition rates in gasification cleanup equipment; provision for composition analysis for all input and output streams across all process equipment, including major elements and trace elements of interest; composition analysis of deposit streams for various deposit zones, including direct condensation on equipment surfaces (Zone A), homogeneous particulate deposition (Zone B), and entrained fly ash deposition (Zone C); and physical removal of ash in cyclones based on D50 cut points. Another new feature of the CABRE III model is a user-friendly interface and detailed reports that are easily exportable into Word documents, Excel spreadsheets, or as pdf files. The user interface provides stepwise guides with built-in checks for efficient entry of required input data on fuels of interest to allow a successful execution of the model. The model was developed with data from several fuels selected by the sponsors, including bituminous coal, subbituminous coal, lignite, and petroleum coke (petcoke). The data from these fuels were obtained using small pilot-scale entrained-flow and fluidized-bed gasifiers at the Energy & Environmental Research Center (EERC). The CABRE III model is expected to further advance the knowledge base for the NCHT® Program and, more importantly, allow for prediction of the slagging and fouling characteristics of fuels in reducing environments. The information obtained from this program will potentially also assist in maintaining prolonged gasifier operation free from failure or facilitate troubleshooting to minimize downtime in the event of a problem.

  8. Task 1.13 - Data Collection and Database Development for Clean Coal Technology By-Product Characteristics and Management Practices

    SciTech Connect (OSTI)

    Debra F. Pflughoeft-Hassett

    1998-02-01T23:59:59.000Z

    U.S. Department of Energy Federal Energy Technology Center-Morgantown (DOE FETC) efforts in the areas of fossil fuels and clean coal technology (CCT) have included involvement with both conventional and advanced process coal conversion by-products. In 1993, DOE submitted a Report to Congress on "Barriers to the Increased Utilization of Coal Combustion Desulfurization Byproducts by Governmental and Commercial Sectors" that provided an outline of activities to remove the barriers identified in the report. DOE charged itself with participation in this process, and the work proposed in this document facilitates DOE's response to its own recommendations for action. The work reflects DOE's commitment to the coal combustion by-product (CCB) industry, to the advancement of clean coal technology, and to cooperation with other government agencies. Information from DOE projects and commercial endeavors in fluidized-bed combustion (FBC) and coal gasification is the focus of this task. The primary goal is to provide an easily accessible compilation of characterization information on the by-products from these processes to government agencies and industry to facilitate sound regulatory and management decisions. Additional written documentation will facilitate the preparation of an updated final version of background information collected for DOE in preparation of the Report to Congress on barriers to CCB utilization.

  9. Proceedings of Office of Surface Mining Coal Combustion By-product Government/Regulatory Panel: University of Kentucky international ash utilization symposium

    SciTech Connect (OSTI)

    Vories, K.C. (ed.)

    2003-07-01T23:59:59.000Z

    Short papers are given on: the Coal Combustion Program (C2P2) (J. Glenn); regional environmental concerns with disposal of coal combustion wastes at mines (T. FitzGerald); power plant waste mine filling - an environmental perspective (L.G. Evans); utility industry perspective regarding coal combustion product management and regulation (J. Roewer); coal combustion products opportunities for beneficial use (D.C. Goss); state perspective on mine placement of coal combustion by-products (G.E. Conrad); Texas regulations provide for beneficial use of coal combustion ash (S.S. Ferguson); and the Surface Mining Control and Reclamation Act - a response to concerns about placement of CCBs at coal mine sites (K.C. Vories). The questions and answers are also included.

  10. Automated apparatus for solvent separation of a coal liquefaction product stream

    DOE Patents [OSTI]

    Schweighardt, Frank K. (Upper Macungie, PA)

    1985-01-01T23:59:59.000Z

    An automated apparatus for the solvent separation of a coal liquefaction product stream that operates continuously and unattended and eliminates potential errors resulting from subjectivity and the aging of the sample during analysis. In use of the apparatus, metered amounts of one or more solvents are passed sequentially through a filter containing the sample under the direction of a microprocessor control means. The mixture in the filter is agitated by means of ultrasonic cavitation for a timed period and the filtrate is collected. The filtrate of each solvent extraction is collected individually and the residue on the filter element is collected to complete the extraction process.

  11. TREATMENT OF METAL-LADEN HAZARDOUS WASTES WITH ADVANCED CLEAN COAL TECHNOLOGY BY-PRODUCTS

    SciTech Connect (OSTI)

    James T. Cobb, Jr.; Ronald D. Neufeld; Jana Agostini

    1999-05-10T23:59:59.000Z

    This fourteenth quarterly report describes work done during the fourteenth three-month period of the University of Pittsburgh's project on the ''Treatment of Metal-Laden Hazardous Wastes with Advanced Clean Coal Technology By-Products.'' This report describes the activities of the project team during the reporting period. The principal work has focused upon new laboratory evaluation of samples from Phase 1, discussions with MAX Environmental Technologies, Inc., on the field work of Phase 2, preparing presentations, and making and responding to two outside contacts.

  12. DEVELOPMENT OF CONTINUOUS SOLVENT EXTRACTION PROCESSES FOR COAL DERIVED CARBON PRODUCTS

    SciTech Connect (OSTI)

    Elliot B. Kennel; R. Michael Bergen; Stephen P. Carpenter; Dady Dadyburjor; Manoj Katakdaunde; Liviu Magean; Alfred H. Stiller; W. Morgan Summers; John W. Zondlo

    2006-05-12T23:59:59.000Z

    The purpose of this DOE-funded effort is to develop continuous processes for solvent extraction of coal for the production of carbon products. The largest applications are those which support metals smelting, such as anodes for aluminum smelting and electrodes for arc furnaces. Other carbon products include materials used in creating fuels for the Direct Carbon Fuel Cell, metals smelting, especially in the aluminum and steel industries, as well as porous carbon structural material referred to as ''carbon foam'' and carbon fibers. During this reporting period, coking and composite fabrication continued using coal-derived samples. These samples were tested in direct carbon fuel cells. Methodology was refined for determining the aromatic character of hydro treated liquid, based on Nuclear Magnetic Resonance (NMR) and Fourier Transform Infrared (FTIR). Tests at GrafTech International showed that binder pitches produced using the WVU solvent extraction protocol can result in acceptable graphite electrodes for use in arc furnaces. These tests were made at the pilot scale.

  13. Low-rank coal study: national needs for resource development. Volume 3. Technology evaluation

    SciTech Connect (OSTI)

    Not Available

    1980-11-01T23:59:59.000Z

    Technologies applicable to the development and use of low-rank coals are analyzed in order to identify specific needs for research, development, and demonstration (RD and D). Major sections of the report address the following technologies: extraction; transportation; preparation, handling and storage; conventional combustion and environmental control technology; gasification; liquefaction; and pyrolysis. Each of these sections contains an introduction and summary of the key issues with regard to subbituminous coal and lignite; description of all relevant technology, both existing and under development; a description of related environmental control technology; an evaluation of the effects of low-rank coal properties on the technology; and summaries of current commercial status of the technology and/or current RD and D projects relevant to low-rank coals.

  14. Process for the production of ethylene and other hydrocarbons from coal

    DOE Patents [OSTI]

    Steinberg, M.; Fallon, P.

    1984-02-15T23:59:59.000Z

    The subject invention comprises the steps of first reacting particulate coal with methane at a temperature in the approximate range of 500/sup 0/C to 1100/sup 0/C and at a partial pressure of methane of less than about 200 psig for a period of less than 10 seconds. More preferably, the method of the subject invention is carried out at a temperature of approximately 850/sup 0/C to 1000/sup 0/C and a pressure of 50 psig for a period of approximately 1.5 seconds. Surprisingly, it has been found that in the practice of the subject invention not only are commercially significant quantities of ethylene produced, namely yields in excess of 10% (percent carbon converted to product), along with economically significant quantities of-benzene and light oils, namely toluene and xylene, but also that there is little, if any, net consumption of methane in the reaction and possibly even a small net production. Since it is apparent that the carbonaceous solids or char remaining after the reaction is carried out may be burned to provide the necessary energy to carry out the process of the subject invention, it is apparent that the subject invention advantageously provides a method for the conversion of coal to economically significant quantities of ethylene, benzene and light oils while requiring only coal and, possibly, small amounts of make-up methane. Other objects and advantages of the subject invention will be apparent to those skilled in the art from a consideration of the attached drawings, the detailed description of the invention, and the experimental examples set forth below.

  15. Improving process performances in coal gasification for power and synfuel production

    SciTech Connect (OSTI)

    M. Sudiro; A. Bertucco; F. Ruggeri; M. Fontana [University of Padova, Milan (Italy). Italy and Foster Wheeler Italiana Spa

    2008-11-15T23:59:59.000Z

    This paper is aimed at developing process alternatives of conventional coal gasification. A number of possibilities are presented, simulated, and discussed in order to improve the process performances, to avoid the use of pure oxygen, and to reduce the overall CO{sub 2} emissions. The different process configurations considered include both power production, by means of an integrated gasification combined cycle (IGCC) plant, and synfuel production, by means of Fischer-Tropsch (FT) synthesis. The basic idea is to thermally couple a gasifier, fed with coal and steam, and a combustor where coal is burnt with air, thus overcoming the need of expensive pure oxygen as a feedstock. As a result, no or little nitrogen is present in the syngas produced by the gasifier; the required heat is transferred by using an inert solid as the carrier, which is circulated between the two modules. First, a thermodynamic study of the dual-bed gasification is carried out. Then a dual-bed gasification process is simulated by Aspen Plus, and the efficiency and overall CO{sub 2} emissions of the process are calculated and compared with a conventional gasification with oxygen. Eventually, the scheme with two reactors (gasifier-combustor) is coupled with an IGCC process. The simulation of this plant is compared with that of a conventional IGCC, where the gasifier is fed by high purity oxygen. According to the newly proposed configuration, the global plant efficiency increases by 27.9% and the CO{sub 2} emissions decrease by 21.8%, with respect to the performances of a conventional IGCC process. 29 refs., 7 figs., 5 tabs.

  16. CHARACTERIZATION OF COAL COMBUSTION BY-PRODUCTS FOR THE RE-EVOLUTION OF MERCURY INTO ECOSYSTEMS

    SciTech Connect (OSTI)

    J.A. Withum; J.E. Locke; S.C. Tseng

    2005-03-01T23:59:59.000Z

    There is concern that mercury (Hg) in coal combustion by-products might be emitted into the environment during processing to other products or after the disposal/landfill of these by-products. This perception may limit the opportunities to use coal combustion by-products in recycle/reuse applications and may result in additional, costly disposal regulations. In this program, CONSOL conducted a comprehensive sampling and analytical program to include ash, flue gas desulfurization (FGD) sludge, and coal combustion by-products. This work is necessary to help identify potential problems and solutions important to energy production from fossil fuels. The program objective was to evaluate the potential for mercury emissions by leaching or volatilization, to determine if mercury enters the water surrounding an active FGD disposal site and an active fly ash slurry impoundment site, and to provide data that will allow a scientific assessment of the issue. Toxicity Characteristic Leaching Procedure (TCLP) test results showed that mercury did not leach from coal, bottom ash, fly ash, spray dryer/fabric filter ash or forced oxidation gypsum (FOG) in amounts leading to concentrations greater than the detection limit of the TCLP method (1.0 ng/mL). Mercury was detected at very low concentrations in acidic leachates from all of the fixated and more than half of the unfixated FGD sludge samples, and one of the synthetic aggregate samples. Mercury was not detected in leachates from any sample when deionized water (DI water) was the leaching solution. Mercury did not leach from electrostatic precipitator (ESP) fly ash samples collected during activated carbon injection for mercury control in amounts greater than the detection limit of the TCLP method (1.0 ng/mL). Volatilization tests could not detect mercury loss from fly ash, spray dryer/fabric filter ash, unfixated FGD sludge, or forced oxidation gypsum; the mercury concentration of these samples all increased, possibly due to absorption from ambient surroundings. Mercury loss of 18-26% was detected after 3 and 6 months at 100 F and 140 F from samples of the fixated FGD sludge. Water samples were collected from existing ground water monitoring wells around an active FGD disposal site (8 wells) and an active fly ash slurry impoundment (14 wells). These were wells that the plants have installed to comply with ground water monitoring requirements of their permits. Mercury was not detected in any of the water samples collected from monitoring wells at either site. A literature review concluded that coal combustion byproducts can be disposed of in properly designed landfills that minimize the potentially negative impacts of water intrusion that carries dissolved organic matter (DOM). Dissolved organic matter and sulfate-reducing bacteria can promote the transformation of elemental or oxidized mercury into methyl mercury. The landfill should be properly designed and capped with clays or similar materials to minimize the wet-dry cycles that promote the release of methylmercury.

  17. Detailed analysis of feed and product asphaltenes in coal/bitumen co-processing

    SciTech Connect (OSTI)

    Selucky, M.L.; Bizzotto, D.; Manske, T. (Alberta Research Council, Devon (Canada))

    1989-04-01T23:59:59.000Z

    Asphaltenes, by definition, are a class of compounds from petroleum and bitumen, soluble in benzene, but insoluble in a non-polar solvent with surface tension of less than 25 dynes/cm{sup {minus}1}. The solvent originally used for asphaltene precipitation was n-pentane. Today, a host of standard procedures are available for the separation of asphaltenes. In a previous paper it was shown by combined GPC, TGA and ESR that the properties of the product asphaltene radical from coal/bitumen co-processing substantially differed from those of the radical from coal/anthracene oil reaction and were practically identical with the properties of asphaltenes derived from bitumen alone. Since this finding puts in question the most frequently used formulation of the reaction path in a co-processing reaction, a more detailed analysis of the feed and product asphaltenes was undertaken to shed more light on the scope and limitations of their analytical tools in elucidating asphaltenes chemistry. This paper describes the implementation of asphaltene analysis, using three related asphaltenes to demonstrate method sensitivity to structural differences.

  18. National FCEV Learning Demonstration: Winter 2011 Composite Data Products

    SciTech Connect (OSTI)

    Wipke, K.; Sprik, S.; Kurtz, J.; Ramsden, T.; Ainscough, C.; Saur, G.

    2012-01-01T23:59:59.000Z

    This presentation from the U.S. Department of Energy's National Renewable Energy Laboratory includes the composite data products produced in Winter 2011 as part of the National Fuel Cell Electric Vehicle (FCEV) Learning Demonstration.

  19. Production and screening of carbon products precursors from coal. Quarterly technical progress report and key personnel staffing report No. 6, April 1, 1996--June 30, 1996

    SciTech Connect (OSTI)

    NONE

    1996-07-01T23:59:59.000Z

    The main goal of this program is to demonstrate the utility of coal extracts from the West Virginia University (WVU) extraction process as suitable base raw materials for the carbon products encompassed by the Carbon Products Consortium (CPC) team. This quarterly report covers activities during the period from April 1, 1996 through June 30, 1996. The first year of the project ended in February, 1996; however, the WVU research effort has continued on a no-cost extension of the original contract. Samples have been supplied to CPC participants so they could conduct their portions of the project as contracted through ORNL. Progress reports are presented for the following tasks: project planning and administration; consortium administration and reporting; coal extraction; technical/economic evaluation of WVU extraction process; and technology transfer. Previous work has shown that the WVU coal extraction process coupled with hydrotreatment, does have the potential for producing suitable base raw materials for carbon products. Current effort, therefore, involved the screening and evaluation of extracts produced by the WVU Group and recommending appropriate materials for scaleup for subsequent evaluation by Consortium Team members. As part of this program, the activation of the coal extraction residues was investigated for the purpose of producing a useful active carbon. A further task, which was started towards the end of the program, was to fabricate a small graphite artifact using Coke derived from coal extract as the filler and the coal extract itself as a binder. The results of these studies are summarized in this report.

  20. Coal conversion siting on coal mined lands: water quality issues

    SciTech Connect (OSTI)

    Triegel, E.K.

    1980-01-01T23:59:59.000Z

    The siting of new technology coal conversion facilities on land disturbed by coal mining results in both environmental benefits and unique water quality issues. Proximity to mining reduces transportation requirements and restores disrupted land to productive use. Uncertainties may exist, however, in both understanding the existing site environment and assessing the impact of the new technology. Oak Ridge National Laboratory is currently assessing the water-related impacts of proposed coal conversion facilities located in areas disturbed by surface and underground coal mining. Past mining practices, leaving highly permeable and unstable fill, may affect the design and quality of data from monitoring programs. Current mining and dewatering, or past underground mining may alter groundwater or surface water flow patterns or affect solid waste disposal stability. Potential acid-forming material influences the siting of waste disposal areas and the design of grading operations. These and other problems are considered in relation to the uncertainties and potentially unique problems inherent in developing new technologies.

  1. DESULFURIZATION OF COAL MODEL COMPOUNDS AND COAL LIQUIDS

    E-Print Network [OSTI]

    Wrathall, James Anthony

    2011-01-01T23:59:59.000Z

    ~ - - - - - ' Gri~ing Feed Coal Slurry Feed Pump Filterused to heat a coal-solvent slurry up to the tempera- turePULVERIZED COAL DISSOLVER PRODUCT SLURRY L-. 5 TJ'OON , ~ (

  2. National Nuclear Security Administration Product Aids in Anthrax...

    National Nuclear Security Administration (NNSA)

    Product Aids in Anthrax Clean-up | National Nuclear Security Administration Facebook Twitter Youtube Flickr RSS People Mission Managing the Stockpile Preventing Proliferation...

  3. President Roosevelt Approves Production of Atomic Bomb | National...

    National Nuclear Security Administration (NNSA)

    Approves Production of Atomic Bomb | National Nuclear Security Administration Facebook Twitter Youtube Flickr RSS People Mission Managing the Stockpile Preventing Proliferation...

  4. Daniel Hoag Named NNSA Production Office Deputy Manager | National...

    National Nuclear Security Administration (NNSA)

    NNSA Production Office Deputy Manager | National Nuclear Security Administration Facebook Twitter Youtube Flickr RSS People Mission Managing the Stockpile Preventing Proliferation...

  5. Heavy metal leaching from coal fly ash amended container substrates during Syngonium production

    SciTech Connect (OSTI)

    Li, Q.S.; Chen, J.J.; Li, Y.C. [University of Florida, Apopka, FL (United States)

    2008-02-15T23:59:59.000Z

    Coal fly ash has been proposed to be an alternative to lime amendment and a nutrient source of container substrates for ornamental plant production. A great concern over this proposed beneficial use, however, is the potential contamination of surface and ground water by heavy metals. In this study, three fly ashes collected from Florida, Michigan, and North Carolina and a commercial dolomite were amended in a basal substrate. The formulated substrates were used to produce Syngonium podophyllum Schott 'Berry Allusion' in 15-cm diameter containers in a shaded greenhouse. Leachates from the containers were collected during the entire six months of plant production and analyzed for heavy metal concentrations. There were no detectable As, Cr, Hg, Pb, and Se in the leachates; Cd and Mo were only detected in few leachate samples. The metals constantly detected were Cu, Mn, Ni, and Zn. The total amounts of Cu, Mn, Ni, and Zn leached during the six-month production period were 95, 210, 44, and 337 {mu} g per container, indicating that such amounts in leachates may contribute little to contamination of surface and ground water. In addition, plant growth indices and fresh and dry weights of S. podophyllum 'Berry Allusion' produced from fly ash and dolomite-amended substrates were comparable except for the plants produced from the substrate amended with fly ash collected from Michigan which had reduced growth indices and fresh and dry weights. Thus, selected fly ashes can be alternatives to commercial dolomites as amendments to container substrates for ornamental plant production. The use of fly ashes as container substrate amendments should represent a new market for the beneficial use of this coal combustion byproduct.

  6. Clean coal technologies: Research, development, and demonstration program plan

    SciTech Connect (OSTI)

    Not Available

    1993-12-01T23:59:59.000Z

    The US Department of Energy, Office of Fossil Energy, has structured an integrated program for research, development, and demonstration of clean coal technologies that will enable the nation to use its plentiful domestic coal resources while meeting environmental quality requirements. The program provides the basis for making coal a low-cost, environmentally sound energy choice for electric power generation and fuels production. These programs are briefly described.

  7. Strontium Isotope Study of Coal Untilization By-products Interacting with Environmental Waters

    SciTech Connect (OSTI)

    Spivak-Birndorf, Lev J; Stewart, Brian W; Capo, Rosemary C; Chapman, Elizabeth C; Schroeder, Karl T; Brubaker, Tonya M

    2011-09-01T23:59:59.000Z

    Sequential leaching experiments on coal utilization by-products (CUB) were coupled with chemical and strontium (Sr) isotopic analyses to better understand the influence of coal type and combustion processes on CUB properties and the release of elements during interaction with environmental waters during disposal. Class C fly ash tended to release the highest quantity of minor and trace elements—including alkaline earth elements, sodium, chromium, copper, manganese, lead, titanium, and zinc—during sequential extraction, with bottom ash yielding the lowest. Strontium isotope ratios ({sup 87}Sr/{sup 86}Sr) in bulk-CUB samples (total dissolution of CUB) are generally higher in class F ash than in class C ash. Bulk-CUB ratios appear to be controlled by the geologic source of the mineral matter in the feed coal, and by Sr added during desulfurization treatments. Leachates of the CUB generally have Sr isotope ratios that are different than the bulk value, demonstrating that Sr was not isotopically homogenized during combustion. Variations in the Sr isotopic composition of CUB leachates were correlated with mobility of several major and trace elements; the data suggest that arsenic and lead are held in phases that contain the more radiogenic (high-{sup 87}Sr/{sup 86}Sr) component. A changing Sr isotope ratio of CUB-interacting waters in a disposal environment could forecast the release of certain strongly bound elements of environmental concern. This study lays the groundwork for the application of Sr isotopes as an environmental tracer for CUB–water interaction.

  8. Enhanced Renewable Methane Production System | Argonne National...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Enhanced Renewable Methane Production System Technology available for licensing: Enhanced renewable methane production system provides a low-cost process that accelerates...

  9. Sandia National Laboratories: Novel Nanoparticle Production Method...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    tiesCapabilitiesNovel Nanoparticle Production Method Could Lead to Better Lights, Lenses, Solar Cells Novel Nanoparticle Production Method Could Lead to Better Lights, Lenses,...

  10. Argonne National Laboratory-West, Former Production Workers Screening Projects (now known as the Idaho National Laboratory)

    Broader source: Energy.gov [DOE]

    Argonne National Laboratory-West, Former Production Workers Screening Projects (now known as the Idaho National Laboratory)

  11. Method and apparatus for the selective separation of gaseous coal gasification products by pressure swing adsorption

    DOE Patents [OSTI]

    Ghate, Madhav R. (Morgantown, WV); Yang, Ralph T. (Williamsville, NY)

    1987-01-01T23:59:59.000Z

    Bulk separation of the gaseous components of multi-component gases provided by the gasification of coal including hydrogen, carbon monoxide, methane, and acid gases (carbon dioxide plus hydrogen sulfide) are selectively adsorbed by a pressure swing adsorption technique using activated carbon, zeolite or a combination thereof as the adsorbent. By charging a column containing the adsorbent with a gas mixture and pressurizing the column to a pressure sufficient to cause the adsorption of the gases and then reducing the partial pressure of the contents of the column, the gases are selectively and sequentially desorbed. Hydrogen, the least absorbable gas of the gaseous mixture, is the first gas to be desorbed and is removed from the column in a co-current direction followed by the carbon monoxide, hydrogen and methane. With the pressure in the column reduced to about atmospheric pressure the column is evacuated in a countercurrent direction to remove the acid gases from the column. The present invention is particularly advantageous as a producer of high parity hydrogen from gaseous products of coal gasification and as an acid gas scrubber.

  12. Method and apparatus for the selective separation of gaseous coal gasification products by pressure swing adsorption

    DOE Patents [OSTI]

    Ghate, M.R.; Yang, R.T.

    1985-10-03T23:59:59.000Z

    Bulk separation of the gaseous components of multi-component gases provided by the gasification of coal including hydrogen, carbon monoxide, methane, and acid gases (carbon dioxide plus hydrogen sulfide) are selectively adsorbed by a pressure swing adsorption technique using activated carbon zeolite or a combination thereof as the adsorbent. By charging a column containing the adsorbent with a gas mixture and pressurizing the column to a pressure sufficient to cause the adsorption of the gases and then reducing the partial pressure of the contents of the column, the gases are selectively and sequentially desorbed. Hydrogen, the least absorbable gas of the gaseous mixture, is the first gas to be desorbed and is removed from the column in a co-current direction followed by the carbon monoxide, hydrogen and methane. With the pressure in the column reduced to about atmospheric pressure the column is evacuated in a countercurrent direction to remove the acid gases from the column. The present invention is particularly advantageous as a producer of high purity hydrogen from gaseous products of coal gasification and as an acid gas scrubber. 2 figs., 2 tabs.

  13. LOW-COST, HIGH-PERFORMANCE MATERIALS USING ILLINOIS COAL COMBUSTION BY-PRODUCTS

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    conventional and clean coal technologies. This project was primarily directed toward developing concrete, mineralogical, and microstructural properties. A clean coal ash is defined as the ash derived from SO2 control technologies. Based on these properties, two sources of both conventional and clean coal ashes were selected

  14. Achieving a production goal of 1 million B/D of coal liquids by 1990. [Impediments and constraints

    SciTech Connect (OSTI)

    Miller, Charles; LaRosa, Dr., P. J.; Coles, E. T.; Fein, H. L.; Petros, J. J.; Iyer, R. S.; Merritt, R. T.

    1980-03-01T23:59:59.000Z

    Under this contract, Bechtel analyzed the resource requirements and reviewed major obstacles to the daily production of several million barrels of synthetic coal liquids. Further, the study sought to identify the industry infrastructure needed to support the commercial readiness of the coal liquefaction process. A selected list of critical resource items and their domestic/international availability was developed and examined, and the impact of their supply on the various synthetic coal liquids programs was evaluated. The study approach was to develop representative, or generic, direct and indirect coal liquefaction conceptual designs from available technology and costs data. The generic processes were to employ technology that would be considered commercial by the mid- or late-1980s. The size of the generic construction mobilization was considered reasonable at the outset of the program. The product slate was directed toward unrefined liquid fuels rather than diesel oil or gasoline. The generic processes were to use a wide range of coals to permit siting in most coal-producing regions across the country. Because of the dearth of conceptual design data in the literature, Bechtel developed generic plant designs by using in-house design expertise. Bechtel assumed that because it is first generation technology, the indirect process will be used at the outset of the liquids program, and the direct process will be introduced two to four years later as a second generation technology. The products of either of these processes will be limited to boiler fuels and/or other liquid products which require further upgrading. Cost estimates were developed from equipment lists, as well as material and labor estimates, which enabled the determination of an order-of-magnitude cost estimate and target plant construction schedule for both processes.

  15. Novel Magnetically Fluidized Bed Reactor Development for the Looping Process: Coal to Hydrogen Production R&D

    SciTech Connect (OSTI)

    Mei, Renwei; Hahn, David; Klausner, James; Petrasch, Jorg; Mehdizadeh, Ayyoub; Allen, Kyle; Rahmatian, Nima; Stehle, Richard; Bobek, Mike; Al-Raqom, Fotouh; Greek, Ben; Li, Like; Chen, Chen; Singh, Abhishek; Takagi, Midori; Barde, Amey; Nili, Saman

    2013-09-30T23:59:59.000Z

    The coal to hydrogen project utilizes the iron/iron oxide looping process to produce high purity hydrogen. The input energy for the process is provided by syngas coming from gasification process of coal. The reaction pathways for this process have been studied and favorable conditions for energy efficient operation have been identified. The Magnetically Stabilized Porous Structure (MSPS) is invented. It is fabricated from iron and silica particles and its repeatable high performance has been demonstrated through many experiments under various conditions in thermogravimetric analyzer, a lab-scale reactor, and a large scale reactor. The chemical reaction kinetics for both oxidation and reduction steps has been investigated thoroughly inside MSPS as well as on the surface of very smooth iron rod. Hydrogen, CO, and syngas have been tested individually as the reducing agent in reduction step and their performance is compared. Syngas is found to be the most pragmatic reducing agent for the two-step water splitting process. The transport properties of MSPS including porosity, permeability, and effective thermal conductivity are determined based on high resolution 3D CT x-ray images obtained at Argonne National Laboratory and pore-level simulations using a lattice Boltzmann Equation (LBE)-based mesoscopic model developed during this investigation. The results of those measurements and simulations provide necessary inputs to the development of a reliable volume-averaging-based continuum model that is used to simulate the dynamics of the redox process in MSPS. Extensive efforts have been devoted to simulate the redox process in MSPS by developing a continuum model consist of various modules for conductive and radiative heat transfer, fluid flow, species transport, and reaction kinetics. Both the Lagrangian and Eulerian approaches for species transport of chemically reacting flow in porous media have been investigated and verified numerically. Both approaches lead to correct prediction of hydrogen production rates over a large range of experimental conditions in the laboratory scale reactor and the bench-scale reactor. In the economic analysis, a comparison of the hydrogen production plants using iron/iron oxide looping cycle and the conventional process has been presented. Plant configurations are developed for the iron/iron oxide looping cycle. The study suggests a higher electric power generation but a lower hydrogen production efficiency comparing with the conventional process. Additionally, it was shown that the price of H{sub 2} obtained from our reactor can be as low as $1.7/kg, which is 22% lower than the current price of the H{sub 2} obtained from reforming plants.

  16. Sandia National Laboratories: increase annual electricity production

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    & Events, Partnership, Renewable Energy, Solar, Solar Newsletter SolarReserve is testing engineering units at the National Solar Thermal Test Facility (NSTTF) operated by Sandia....

  17. Productivity and Firm Selection: Intra-National and International Trade.

    E-Print Network [OSTI]

    Sussex, University of

    Productivity and Firm Selection: Intra-National and International Trade. Gregory Corcos (NHH) Firm Selection: Intra- vs International Trade April 23, 2007 1 / 35 #12;Overview Objective: Quantify the productivity gains from inter- and intra-national trade. What we do in this paper: model the effect of trade

  18. Environmental chamber measurements of mercury flux from coal utilization by-products

    SciTech Connect (OSTI)

    Pekney, N.J.; Martello, D.V.; Schroeder, K.T.; Granite, E.J.

    2009-05-01T23:59:59.000Z

    An environmental chamber was constructed to measure the mercury flux from coal utilization by-product (CUB) samples. Samples of fly ash, FGD gypsum, and wallboard made from FGD gypsum were tested under both dark and illuminated conditions with or without the addition of water to the sample. Mercury releases varied widely, with 7-day experiment averages ranging from -6.8 to 73 ng/m2 h for the fly ash samples and -5.2 to 335 ng/m2 h for the FGD/wallboard samples. Initial mercury content, fly ash type, and light exposure had no observable consistent effects on the mercury flux. For the fly ash samples, the effect of a mercury control technology was to decrease the emission. For three of the four pairs of FGD gypsum and wallboard samples, the wallboard sample released less (or absorbed more) mercury than the gypsum.

  19. Sandia National Laboratories: Solar Thermochemical Hydrogen Production

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in Materials & Components Compatibility Hydrogen Behavior Quantitative Risk Assessment Hydrogen Infrastructure Solar Thermochemical Hydrogen Production Market Transformation...

  20. ASPEN simulation of the SNG production process in an indirect coal-liquefaction plant

    SciTech Connect (OSTI)

    Bistline, J E; Shafer, T B

    1982-08-01T23:59:59.000Z

    The synthetic natural gas (SNG) production process (methanation, CO-shift, and hydrogen removal) in an indirect coal-liquefaction plant was simulated using the Advanced System for Process Engineering (ASPEN). The simulation of the methanation unit agreed to within 12% of Fluor's design for converting carbon monoxide and carbon dioxide. A parametric study examined the effect of four important operating parameters on product composition, process thermal efficiency, and outlet temperature from the second methanation reactor. The molar split of gas feed to the CO-shift unit before methanation was varied from 0.2 to 0.6; variations of molar recycle ratio (0.01 - 0.67), molar steam-to-feed ratio (0.04 - 0.19), and feed temperature (478 - 533 K, 400-500/sup 0/F) to the first methanation reactor were also studied. A 50%-lower split improved thermal efficiency by 6%, but the mole % hydrogen and carbon monoxide in the product SNG required to meet pipeline-quality standards and temperature constraints were not met. Increasing the steam-to-feed ratio from 0.04 to 0.19 improved product quality but decreased thermal efficiency by 8%. By decreasing the feed temperature from 533 to 477 K (500 to 400/sup 0/F), product specifications and temperature constraints were met with no effect on thermal efficiency. However, it may be impractical to operate the reactor at 477 K (400/sup 0/F) because the kinetics are too slow. Increasing the recycle ratio from 0.4 to 0.67 had no effect on thermal efficiency, and temperature constraints and product specifications were met. The SNG production process should be optimized at recycle ratios above 0.67.

  1. The use of synchrotron radiation for the analysis of coal combustion products

    SciTech Connect (OSTI)

    Manowitz, B.; Gordon, B.

    1992-05-01T23:59:59.000Z

    An understanding of the chemical composition of such slags under boiler operating conditions and as function of the mineral composition of various coals is the ultimate goal of this program. The experiment involves scanning through the K- or L-shell absorption edge of the element in question. The structure of the absorption edge, consisting of transitions to unoccupied molecular levels, can be compared to those of model compounds for identification. The relative position of the absorption edge can yield information regarding the oxidation state of the element. This portion is the X-ray Absorption Near Edge Structure (XANES) portion of the spectrum. The Extended X-ray Absorption Fine Structure (EXFAS) region, extending from about 60 eV above the absorption edge, represents scattering from neighboring constituents and can be used to determine the coordination number of coordination distance of a specific element from its neighboring atoms. The best source of excitation energy for these experiments is an electron storage ring emitting synchrotron radiation (SR). The National Synchrotron Light Source (NSLS) at Brookhaven National Laboratory is a 2.5 GeV storage ring and emits a continuous spectrum of x rays to an energy of about 30 keV. Beam line X-19A is dedicated to XANES and EXAFS and is being adapted to the performance of this investigation.

  2. Sandia National Laboratories: maximize energy production

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    maximize energy production Solar Glare Hazard Analysis Tool Available for Download On March 13, 2014, in Energy, News, News & Events, Photovoltaic, Renewable Energy, Solar, Solar...

  3. Sandia National Laboratories: improve labor productivity

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    labor productivity Fabrication of AMI Demonstration Blade Begun On September 10, 2013, in Energy, News, News & Events, Partnership, Renewable Energy, Wind Energy The Advanced...

  4. Use of resin-bearing wastes from coke and coal chemicals production at the Novokuznetsk Metallurgical Combine

    SciTech Connect (OSTI)

    Kul'kova, T.N.; Yablochkin, N.V.; Gal'chenko, A.I.; Karyakina, E.A.; Litvinova, V.A.; Gorbach, D.A.

    2007-03-15T23:59:59.000Z

    The coke and coal chemicals plant at the Novokuznetsk Metallurgical Combine is making trial use of a technology that recycles waste products in 'tar ponds.' Specialists from the Ekomash company have installed a recycling unit in one area of the plant's dump, the unit including an inclined conveyor with a steam heater and a receiving hopper The coal preparation shop receives the wastes in a heated bin, where a screw mixes the wastes with pail of the charge for the coking ovens. The mixture subsequently travels along a moving conveyor belt together with the rest of the charge materials. The addition of up to 2% resin-bearing waste materials to the coal charge has not had any significant effect on the strength properties of the coke.

  5. A novel coal feeder for production of low sulfur fuel. Annual technical progress report, October 1, 1990--October 1, 1991

    SciTech Connect (OSTI)

    Khang, S.J.; Lin, L.; Keener, T.C.; Yeh, P.

    1991-12-31T23:59:59.000Z

    A dual-screw feeder was designed for desulfurization of coal. This reactor contains two screw tubes, the inner tube acting as a coal pyrolizer and the outer tube acting as a desulfurizer with hot calcined lime pellets or other renewable sorbent pellets. The objectives of this project is to study the feasibility of an advanced concept of desulfurization and possibly some denitrification in this coal feeder. In this year, two basic studies have been performed: (1) the desulfurization and (2) the denitrification due to mild pyrolysis. Specifically, the following tasks have been performed: (1) Setting up the Dual-Screw reactor, (2) Determination of the pyrolysis product and the sulfur distribution in char, tar and gas based on experimental data, (3) Study of the devolatilization, the desulfurization kinetics and the denitrification kinetics and obtaining the basic kinetic parameters, (4) Study of the sulfur removal efficiency of lime pellets fed into the outer tube of the dual-feeder reactor, (5) Study of the effect of the coal particle size on pyrolysis and desulfurization, (6) Study of the coal pyrolysis and desulfurization using a TGA(Thermal Gravimetric Analyzer).

  6. Mercury and Air Toxic Element Impacts of Coal Combustion By-Product Disposal and Utilizaton

    SciTech Connect (OSTI)

    David Hassett; Loreal Heebink; Debra Pflughoeft-Hassett; Tera Buckley; Erick Zacher; Mei Xin; Mae Sexauer Gustin; Rob Jung

    2007-03-31T23:59:59.000Z

    The University of North Dakota Energy & Environmental Research Center (EERC) conducted a multiyear study to evaluate the impact of mercury and other air toxic elements (ATEs) on the management of coal combustion by-products (CCBs). The ATEs evaluated in this project were arsenic, cadmium, chromium, lead, nickel, and selenium. The study included laboratory tasks to develop measurement techniques for mercury and ATE releases, sample characterization, and release experiments. A field task was also performed to measure mercury releases at a field site. Samples of fly ash and flue gas desulfurization (FGD) materials were collected preferentially from full-scale coal-fired power plants operating both without and with mercury control technologies in place. In some cases, samples from pilot- and bench-scale emission control tests were included in the laboratory studies. Several sets of 'paired' baseline and test fly ash and FGD materials collected during full-scale mercury emission control tests were also included in laboratory evaluations. Samples from mercury emission control tests all contained activated carbon (AC) and some also incorporated a sorbent-enhancing agent (EA). Laboratory release experiments focused on measuring releases of mercury under conditions designed to simulate CCB exposure to water, ambient-temperature air, elevated temperatures, and microbes in both wet and dry conditions. Results of laboratory evaluations indicated that: (1) Mercury and sometimes selenium are collected with AC used for mercury emission control and, therefore, present at higher concentrations than samples collected without mercury emission controls present. (2) Mercury is stable on CCBs collected from systems both without and with mercury emission controls present under most conditions tested, with the exception of vapor-phase releases of mercury exposed to elevated temperatures. (3) The presence of carbon either from added AC or from unburned coal can result in mercury being sorbed onto the CCB when exposed to ambient-temperature air. The environmental performance of the mercury captured on AC used as a sorbent for mercury emission control technologies indicated that current CCB management options will continue to be sufficiently protective of the environment, with the potential exception of exposure to elevated temperatures. The environmental performance of the other ATEs investigated indicated that current management options will be appropriate to the CCBs produced using AC in mercury emission controls.

  7. The economical production of alcohol fuels from coal-derived synthesis gas: Case studies, design, and economics

    SciTech Connect (OSTI)

    NONE

    1995-10-01T23:59:59.000Z

    This project is a combination of process simulation and catalyst development aimed at identifying the most economical method for converting coal to syngas to linear higher alcohols to be used as oxygenated fuel additives. There are two tasks. The goal of Task 1 is to discover, study, and evaluate novel heterogeneous catalytic systems for the production of oxygenated fuel enhancers from synthesis gas, and to explore, analytically and on the bench scale, novel reactor and process concepts for use in converting syngas to liquid fuel products. The goal of Task 2 is to simulate, by computer, energy efficient and economically efficient processes for converting coal to energy (fuel alcohols and/or power). The primary focus is to convert syngas to fuel alcohols. This report contains results from Task 2. The first step for Task 2 was to develop computer simulations of alternative coal to syngas to linear higher alcohol processes, to evaluate and compare the economics and energy efficiency of these alternative processes, and to make a preliminary determination as to the most attractive process configuration. A benefit of this approach is that simulations will be debugged and available for use when Task 1 results are available. Seven cases were developed using different gasifier technologies, different methods for altering the H{sub 2}/CO ratio of the syngas to the desired 1.1/1, and with the higher alcohol fuel additives as primary products and as by-products of a power generation facility. Texaco, Shell, and Lurgi gasifier designs were used to test gasifying coal. Steam reforming of natural gas, sour gas shift conversion, or pressure swing adsorption were used to alter the H{sub 2}/CO ratio of the syngas. In addition, a case using only natural gas was prepared to compare coal and natural gas as a source of syngas.

  8. Hydrogen production by high-temperature steam gasification of biomass and coal

    SciTech Connect (OSTI)

    Kriengsak, S.N.; Buczynski, R.; Gmurczyk, J.; Gupta, A.K. [University of Maryland, College Park, MD (United States). Dept. of Mechanical Engineering

    2009-04-15T23:59:59.000Z

    High-temperature steam gasification of paper, yellow pine woodchips, and Pittsburgh bituminous coal was investigated in a batch-type flow reactor at temperatures in the range of 700 to 1,200{sup o}C at two different ratios of steam to feedstock molar ratios. Hydrogen yield of 54.7% for paper, 60.2% for woodchips, and 57.8% for coal was achieved on a dry basis, with a steam flow rate of 6.3 g/min at steam temperature of 1,200{sup o}C. Yield of both the hydrogen and carbon monoxide increased while carbon dioxide and methane decreased with the increase in gasification temperature. A 10-fold reduction in tar residue was obtained at high-temperature steam gasification, compared to low temperatures. Steam and gasification temperature affects the composition of the syngas produced. Higher steam-to-feedstock molar ratio had negligible effect on the amount of hydrogen produced in the syngas in the fixed-batch type of reactor. Gasification temperature can be used to control the amounts of hydrogen or methane produced from the gasification process. This also provides mean to control the ratio of hydrogen to CO in the syngas, which can then be processed to produce liquid hydrocarbon fuel since the liquid fuel production requires an optimum ratio between hydrogen and CO. The syngas produced can be further processed to produce pure hydrogen. Biomass fuels are good source of renewable fuels to produce hydrogen or liquid fuels using controlled steam gasification.

  9. (Basic properties of coals and other solids)

    SciTech Connect (OSTI)

    Not Available

    1991-11-25T23:59:59.000Z

    This report discusses basic properties of bituminous, subbituminous, and lignite coals. Properties of coal liquids are also investigated. Heats of immersion in strong acids are found for Pittsburgh {number sign}8, Illinois {number sign}6, and Wyodak coals. Production of coal liquids by distillation is discussed. Heats of titration of coal liquids and coal slurries are reported. (VC)

  10. NNSA Production Office | National Nuclear Security Administration

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilA Approved:AdministrationAnalysis andB -Reports| National Nuclear Security

  11. Coal data: A reference

    SciTech Connect (OSTI)

    Not Available

    1995-02-01T23:59:59.000Z

    This report, Coal Data: A Reference, summarizes basic information on the mining and use of coal, an important source of energy in the US. This report is written for a general audience. The goal is to cover basic material and strike a reasonable compromise between overly generalized statements and detailed analyses. The section ``Supplemental Figures and Tables`` contains statistics, graphs, maps, and other illustrations that show trends, patterns, geographic locations, and similar coal-related information. The section ``Coal Terminology and Related Information`` provides additional information about terms mentioned in the text and introduces some new terms. The last edition of Coal Data: A Reference was published in 1991. The present edition contains updated data as well as expanded reviews and additional information. Added to the text are discussions of coal quality, coal prices, unions, and strikes. The appendix has been expanded to provide statistics on a variety of additional topics, such as: trends in coal production and royalties from Federal and Indian coal leases, hours worked and earnings for coal mine employment, railroad coal shipments and revenues, waterborne coal traffic, coal export loading terminals, utility coal combustion byproducts, and trace elements in coal. The information in this report has been gleaned mainly from the sources in the bibliography. The reader interested in going beyond the scope of this report should consult these sources. The statistics are largely from reports published by the Energy Information Administration.

  12. The directory of United States coal & technology export resources. Profiles of domestic US corporations, associations and public entities, nationwide, which offer products or services suitable for export, relating to coal and its utilization

    SciTech Connect (OSTI)

    Not Available

    1994-01-01T23:59:59.000Z

    The purpose of this directory is to provide a listing of available U.S. coal and coal related resources to potential purchasers of those resources abroad. The directory lists business entities within the US which offer coal related resources, products and services for sale on the international market. Each listing is intended to describe the particular business niche or range of product and/or services offered by a particular company. The listing provides addresses, telephones, and telex/fax for key staff in each company committed to the facilitation of international trade. The content of each listing has been formulated especially for this directory and reflects data current as of the date of this edition. The directory listings are divided into four primary classifications: coal resources; technology resources; support services; and financing and resource packaging. The first three of which are subdivided as follows: Coal Resources -- coal derivatives, coal exporters, and coal mining; Technology Resources -- advanced utilization, architects and engineers, boiler equipment, emissions control and waste disposal systems, facility construction, mining equipment, power generation systems, technical publications, and transport equipment; Support Services -- coal transport, facility operations, freight forwarders, sampling services and equipment, and technical consultants. Listings for the directory were solicited on the basis of this industry breakdown. Each of the four sections of this directory begins with a matrix illustrating which companies fall within the particular subclassifications specific to that main classification. A general alphabetical index of companies and an index by product/service classification are provided following the last section of the directory.

  13. High conversion of coal to transportation fuels for the future with low HC gas production. Progress report, October 1, 1995--December 31, 1995

    SciTech Connect (OSTI)

    Wiser, W.H.; Oblad, A.G.

    1996-01-01T23:59:59.000Z

    Experimental coal liquefaction studies conducted in a batch microreactor in our laboratory have demonstrated potential for high conversions of coal to liquids with low yields of hydrocarbon (HC) gases, hence a small consumption of hydrogen in the primary liquefaction step. Ratios of liquids/HC gases as high as 30/1, at liquid yields as high as 82% of the coal by weight, have been achieved. The principal objective of this work is to examine how nearly we may approach these results in a continuous-flow system, at a size sufficient to evaluate the process concept for production of transportation fuels from coal.

  14. Forecasting long-term gas production of dewatered coal seams and fractured gas shales

    SciTech Connect (OSTI)

    Spivey, J.P.; Semmelbeck, M.E.

    1995-12-31T23:59:59.000Z

    Production decline curves are routinely used by engineers to predict the future performance of oil and gas wells. Because the results of decline curve predictions are used for calculating asset value and estimating future revenue, they are one of the most important tools reservoir engineers use. There are numerous variations on the basic exponential or hyperbolic decline analysis method. Fetkovitch and other have extended the decline curve analysis method to handle gas wells properly and to be able to estimate reservoir properties from the analysis of these data. However, there has been considerable drilling activity in the last 10 years into unconventional reservoirs whose wells do not follow the traditional production decline characteristic shapes. Among these problem reservoirs are coalbed methane and fractured shale reservoirs. A procedure is presented which allows forecasting long range performance of dewatered coal and fractured gas shale reservoirs having nonlinear adsorption isotherms, using constant pressure solutions to the flow equation for slightly compressible liquids. A correlation is presented to show the range of applicability of this procedure.

  15. CHEMICAL FIXATION OF CO2 IN COAL COMBUSTION PRODUCTS AND RECYCLING THROUGH BIOSYSTEMS

    SciTech Connect (OSTI)

    C. Henry Copeland; Paul Pier; Samantha Whitehead; Paul Enlow; Richard Strickland; David Behel

    2003-12-15T23:59:59.000Z

    This Annual Technical Progress Report presents the principle results in enhanced growth of algae using coal combustion products as a catalyst to increase bicarbonate levels in solution. A co-current reactor is present that increases the gas phase to bicarbonate transfer rate by a factor of five to nine. The bicarbonate concentration at a given pH is approximately double that obtained using a control column of similar construction. Algae growth experiments were performed under laboratory conditions to obtain baseline production rates and to perfect experimental methods. The final product of this initial phase in algae production is presented. Algal growth can be limited by several factors, including the level of bicarbonate available for photosynthesis, the pH of the growth solution, nutrient levels, and the size of the cell population, which determines the available space for additional growth. In order to supply additional CO2 to increase photosynthesis and algal biomass production, fly ash reactor has been demonstrated to increase the available CO2 in solution above the limits that are achievable with dissolved gas alone. The amount of dissolved CO2 can be used to control pH for optimum growth. Periodic harvesting of algae can be used to maintain algae in the exponential, rapid growth phase. An 800 liter scale up demonstrated that larger scale production is possible. The larger experiment demonstrated that indirect addition of CO2 is feasible and produces significantly less stress on the algal system. With better harvesting methods, nutrient management, and carbon dioxide management, an annual biomass harvest of about 9,000 metric tons per square kilometer (36 MT per acre) appears to be feasible. To sequester carbon, the algal biomass needs to be placed in a permanent location. If drying is undesirable, the biomass will eventually begin to aerobically decompose. It was demonstrated that algal biomass is a suitable feed to an anaerobic digester to produce methane. The remaining carbonaceous material is essentially bio-inactive and is permanently sequestered. The feasibility of using algae to convert carbon dioxide to a biomass has been demonstrated. This biomass provides a sustainable means to produce methane, ethanol, and/or bio diesel. The first application of concept demonstrated by the project could be to use algal biomass production to capture carbon dioxide associated with ethanol production.

  16. Research needs and data acquisition to apply US technology to foreign coals: Annual report, July 1, 1986-June 30, 1987. [Production and consumption of each indexed country

    SciTech Connect (OSTI)

    Joseph, S.; Kulkarni, A.; Saluja, J.

    1987-01-01T23:59:59.000Z

    Extensive data on the coal resources, characteristics, demand and supply, coal production and plans for coal utilization to meet the energy needs in the countries of the Pacific Basin and Asia have been gathered. Two databases have been prepared based on this information which are compatible with the database on domestic coals available at NCTDC, PETC on coal resources and characteristics. Coal technologies and coal preparation methods currently in use in the Pacific Basin and Asia have also been addressed. In the second phase of this project, an assessment of the information obtained will be conducted and, wherever possible, this data will be compared with domestic data on coals and coal conversion practices so as to highlight similarities or differences. High quality and useful data will be enumerated in the form of graphs, tables and matrices for quick review. Conclusions from this data will depict work areas of potential mutual interest and areas of technology transfer. US products and services which can be exported will be emphasized.

  17. Advanced Multi-Product Coal Utilization By-Product Processing Plant

    SciTech Connect (OSTI)

    John Groppo; Thomas Robl

    2006-09-30T23:59:59.000Z

    The objective of the project is to build a multi-product ash beneficiation plant at Kentucky Utilities 2,200-MW Ghent Generating Station, located in Carroll County, Kentucky. This part of the study includes an investigation of the secondary classification characteristics of the ash feedstock excavated from the lower ash pond at Ghent Station.

  18. DOE's Former Rocky Flats Weapons Production Site to Become National...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Flats nuclear weapons production site to the Department of the Interior's (DOI) U.S. Fish and Wildlife Service (FWS) for use as a National Wildlife Refuge. After more than a...

  19. Black Thunder Coal Mine and Los Alamos National Laboratory experimental study of seismic energy generated by large scale mine blasting

    SciTech Connect (OSTI)

    Martin, R.L.; Gross, D. [Thunder Basin Coal Co., Wright, WY (United States); Pearson, D.C.; Stump, B.W. [Los Alamos National Lab., NM (United States); Anderson, D.P. [Southern Methodist Univ., Dallas, TX (United States). Dept. of Geological Sciences

    1996-12-31T23:59:59.000Z

    In an attempt to better understand the impact that large mining shots will have on verifying compliance with the international, worldwide, Comprehensive Test Ban Treaty (CTBT, no nuclear explosion tests), a series of seismic and videographic experiments has been conducted during the past two years at the Black Thunder Coal Mine. Personnel from the mine and Los Alamos National Laboratory have cooperated closely to design and perform experiments to produce results with mutual benefit to both organizations. This paper summarizes the activities, highlighting the unique results of each. Topics which were covered in these experiments include: (1) synthesis of seismic, videographic, acoustic, and computer modeling data to improve understanding of shot performance and phenomenology; (2) development of computer generated visualizations of observed blasting techniques; (3) documentation of azimuthal variations in radiation of seismic energy from overburden casting shots; (4) identification of, as yet unexplained, out of sequence, simultaneous detonation in some shots using seismic and videographic techniques; (5) comparison of local (0.1 to 15 kilometer range) and regional (100 to 2,000 kilometer range) seismic measurements leading to determine of the relationship between local and regional seismic amplitude to explosive yield for overburden cast, coal bulking and single fired explosions; and (6) determination of the types of mining shots triggering the prototype International Monitoring System for the CTBT.

  20. Process for the production and recovery of fuel values from coal

    DOE Patents [OSTI]

    Sass, Allan (Los Angeles, CA); McCarthy, Harry E. (Golden, CO); Kaufman, Paul R. (North Canton, OH); Finney, Clement S. (Claremont, CA)

    1982-01-01T23:59:59.000Z

    A method of pyrolyzing and desulfurizing coal in a transport reactor to recover volatile fuel values and hydrogen by heating particulate coal entrained in a carrier gas substantially free of oxygen to a pyrolysis temperature in a zone within three seconds.

  1. Advanced Multi-Product Coal Utilization By-Product Processing Plant

    SciTech Connect (OSTI)

    Thomas Robl; John Groppo

    2005-09-01T23:59:59.000Z

    The objective of the project is to build a multi-product ash beneficiation plant at Kentucky Utilities 2,200-MW Ghent Generating Station, located in Carroll County, Kentucky. This part of the study includes the examination of the feedstocks for the beneficiation plant. The ash, as produced by the plant, and that stored in the lower pond were examined. A mobile demonstration unit has been designed and constructed for field demonstration. The demonstration unit was hauled to the test site on trailers that were place on a test pad located adjacent to the ash pond and re-assembled. The continuous test unit will be operated at the Ghent site and will evaluate three processing configurations while producing sufficient products to facilitate thorough product testing. The test unit incorporates all of the unit processes that will be used in the commercial design and is self sufficient with respect to water, electricity and processing capabilities. Representative feed ash for the operation of the filed testing unit was excavated from a location within the lower ash pond determined from coring activities. Approximately 150 tons of ash was excavated and pre-screened to remove +3/8 inch material that could cause plugging problems during operation of the demonstration unit.

  2. RESOURCE ASSESSMENT & PRODUCTION TESTING FOR COAL BED METHANE IN THE ILLINOIS BASIN

    SciTech Connect (OSTI)

    Cortland Eble; James Drahovzal; David Morse; Ilham Demir; John Rupp; Maria Mastalerz; Wilfrido Solano

    2004-06-01T23:59:59.000Z

    The geological surveys of Illinois, Indiana and Kentucky have completed the initial geologic assessment of their respective parts of the Illinois Basin. Cumulative thickness maps have been generated and target areas for drilling have been selected. The first well in the Illinois area of the Illinois Basin coal bed methane project was drilled in White County, Illinois in October 2003. This well was cored in the major coal interval from the Danville to the Davis Coals and provided a broad spectrum of samples for further analyses. Sixteen coal samples and three black shale samples were taken from these cores for canister desorption tests and were the subject of analyses that were completed over the following months, including desorbed gas volume, gas chemical and isotope composition, coal proximate, calorific content and sulfur analyses. Drilling programs in Indiana and Kentucky are expected to begin shortly.

  3. Sandia National Laboratories: Products and Services

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItemResearch > TheNuclearHomeland and NuclearReport PartnershipsNews

  4. Weapons production | Y-12 National Security Complex

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del SolStrengthening aTurbulenceUtilizeRural PublicRatesAbout UsWeapons ProgramWeapons

  5. Production Technology | National Nuclear Security Administration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Science (SC)IntegratedSpeedingTechnical News, informationPriorityPetroleum Survey

  6. Coal-Derived Warm Syngas Purification and CO2 Capture-Assisted Methane Production

    SciTech Connect (OSTI)

    Dagle, Robert A.; King, David L.; Li, Xiaohong S.; Xing, Rong; Spies, Kurt A.; Zhu, Yunhua; Rainbolt, James E.; Li, Liyu; Braunberger, B.

    2014-10-31T23:59:59.000Z

    Gasifier-derived syngas from coal has many applications in the area of catalytic transformation to fuels and chemicals. Raw syngas must be treated to remove a number of impurities that would otherwise poison the synthesis catalysts. Inorganic impurities include alkali salts, chloride, sulfur compounds, heavy metals, ammonia, and various P, As, Sb, and Se- containing compounds. Systems comprising multiple sorbent and catalytic beds have been developed for the removal of impurities from gasified coal using a warm cleanup approach. This approach has the potential to be more economic than the currently available acid gas removal (AGR) approaches and improves upon currently available processes that do not provide the level of impurity removal that is required for catalytic synthesis application. Gasification also lends itself much more readily to the capture of CO2, important in the regulation and control of greenhouse gas emissions. CO2 capture material was developed and in this study was demonstrated to assist in methane production from the purified syngas. Simultaneous CO2 sorption enhances the CO methanation reaction through relaxation of thermodynamic constraint, thus providing economic benefit rather than simply consisting of an add-on cost for carbon capture and release. Molten and pre-molten LiNaKCO3 can promote MgO and MgO-based double salts to capture CO2 with high cycling capacity. A stable cycling CO2 capacity up to 13 mmol/g was demonstrated. This capture material was specifically developed in this study to operate in the same temperature range and therefore integrate effectively with warm gas cleanup and methane synthesis. By combining syngas methanation, water-gas-shift, and CO2 sorption in a single reactor, single pass yield to methane of 99% was demonstrated at 10 bar and 330oC when using a 20 wt% Ni/MgAl2O4 catalyst and a molten-phase promoted MgO-based sorbent. Under model feed conditions both the sorbent and catalyst exhibited favorable stability after multiple test cycles. The cleanup for warm gas cleanup of inorganics was broken down into three major steps: chloride removal, sulfur removal, and the removal for a multitude of trace metal contaminants. Na2CO3 was found to optimally remove chlorides at an operating temperature of 450ºC. For sulfur removal two regenerable ZnO beds are used for bulk H2S removal at 450ºC (<5 ppm S) and a non-regenerable ZnO bed for H2S polishing at 300ºC (<40 ppb S). It was also found that sulfur from COS could be adsorbed (to levels below our detection limit of 40 ppb) in the presence of water that leads to no detectable slip of H2S. Finally, a sorbent material comprising of Cu and Ni was found to be effective in removing trace metal impurities such as AsH3 and PH3 when operating at 300ºC. Proof-of-concept of the integrated cleanup process was demonstrated with gasifier-generated syngas produced at the Western Research Institute using Wyoming Decker Coal. When operating with a ~1 SLPM feed, multiple inorganic contaminant removal sorbents and a tar-reforming bed was able to remove the vast majority of contaminants from the raw syngas. A tar-reforming catalyst was employed due to the production of tars generated from the gasifier used in this particular study. It is envisioned that in a real application a commercial scale gasifier operating at a higher temperature would produce lesser amount of tar. Continuous operation of a poison-sensitive copper-based WGS catalyst located downstream from the cleanup steps resulted in successful demonstration. ?

  7. Advanced Multi-Product Coal Utilization By-Product Processing Plant

    SciTech Connect (OSTI)

    Andrew Jackura; John Groppo; Thomas Robl

    2006-12-31T23:59:59.000Z

    The objective of the project is to build a multi-product ash beneficiation plant at Kentucky Utilities 2,200-MW Ghent Generating Station, located in Carroll County, Kentucky. This part of the study includes an investigation of the secondary classification characteristics of the ash feedstock excavated from the lower ash pond at Ghent Station. The market study for the products of the processing plant (Subtask 1.6), conducted by Cemex, is reported herein. The study incorporated simplifying assumptions and focused only on pozzolan and ultra fine fly ash (UFFA). It found that the market for pozzolan in the Ghent area was oversupplied, with resultant poor pricing structure. Reachable export markets for the Ghent pozzolan market were mostly locally served with the exception of Florida. It was concluded that a beneficiated material for that market may be at a long term disadvantage. The market for the UFFA was more complex as this material would compete with other beneficiated ash and potential metakaolin and silica fume as well. The study concluded that this market represented about 100,000 tons of sales per year and, although lucrative, represented a widely dispersed niche market.

  8. DURABILITY EVALUATION AND PRODUCTION OF MANUFACTURED AGGREGATES FROM COAL COMBUSTION BY-PRODUCTS

    SciTech Connect (OSTI)

    M. M. Wu

    2005-02-01T23:59:59.000Z

    Under the cooperative agreement with DOE, the Research and Development Department of CONSOL Energy (CONSOL R&D), teamed with Universal Aggregates, LLC, to conduct a systematic study of the durability of aggregates manufactured using a variety of flue gas desulfurization (FGD), fluidized-bed combustion (FBC) and fly ash specimens with different chemical and physical properties and under different freeze/thaw, wet/dry and long-term natural weathering conditions. The objectives of the study are to establish the relationships among the durability and characteristics of FGD material, FBC ash and fly ash, and to identify the causes of durability problems, and, ultimately, to increase the utilization of FGD material, FBC ash and fly ash as a construction material. Manufactured aggregates made from FGD material, FBC ash and fly ash, and products made from those manufactured aggregates were used in the study. The project is divided into the following activities: sample collection and characterization; characterization and preparation of manufactured aggregates; determination of durability characteristics of manufactured aggregates; preparation and determination of durability characteristics of manufactured aggregate products; and data evaluation and reporting.

  9. TREATMENT OF METAL-LADEN HAZARDOUS WASTES WITH ADVANCED CLEAN COAL TECHNOLOGY BY-PRODUCTS

    SciTech Connect (OSTI)

    James T. Cobb, Jr.

    2003-09-12T23:59:59.000Z

    Metal-laden wastes can be stabilized and solidified using advanced clean coal technology by-products (CCTBs)--fluid bed combustor ash and spray drier solids. These utility-generated treatment chemicals are available for purchase through brokers, and commercial applications of this process are being practiced by treaters of metal-laden hazardous waste. A complex of regulations governs this industry, and sensitivities to this complex has discouraged public documentation of treatment of metal-laden hazardous wastes with CCTBs. This report provides a comprehensive public documentation of laboratory studies that show the efficacy of the stabilization and solidification of metal-laden hazardous wastes--such as lead-contaminated soils and sandblast residues--through treatment with CCTBs. It then describes the extensive efforts that were made to obtain the permits allowing a commercial hazardous waste treater to utilize CCTBs as treatment chemicals and to install the equipment required to do so. It concludes with the effect of this lengthy process on the ability of the treatment company to realize the practical, physical outcome of this effort, leading to premature termination of the project.

  10. Speciation and Attenuation of Arsenic and Selenium at Coal Combustion By-Product Management Facilities

    SciTech Connect (OSTI)

    K. Ladwig

    2005-12-31T23:59:59.000Z

    The overall objective of this project was to evaluate the impact of key constituents captured from power plant air streams (principally arsenic and selenium) on the disposal and utilization of coal combustion products (CCPs). Specific objectives of the project were: (1) to develop a comprehensive database of field leachate concentrations at a wide range of CCP management sites, including speciation of arsenic and selenium, and low-detection limit analyses for mercury; (2) to perform detailed evaluations of the release and attenuation of arsenic species at three CCP sites; and (3) to perform detailed evaluations of the release and attenuation of selenium species at three CCP sites. Each of these objectives was accomplished using a combination of field sampling and laboratory analysis and experimentation. All of the methods used and results obtained are contained in this report. For ease of use, the report is subdivided into three parts. Volume 1 contains methods and results for the field leachate characterization. Volume 2 contains methods and results for arsenic adsorption. Volume 3 contains methods and results for selenium adsorption.

  11. Evaluating voluntary measures with treatment spillovers: the case of coal combustion products partnership - article no. 36

    SciTech Connect (OSTI)

    Lange, I. [University of Stirling, Stirling (United Kingdom)

    2009-07-01T23:59:59.000Z

    Voluntary measures have traditionally been evaluated using a similar framework regardless of their structure. The framework assumes that the measure provides partners with a treatment (information, research support, etc.) that will not be transferred to non-partners. In this framework, a voluntary measure is said to be worthwhile if differences are significant between the behavior of partners and non-partners, correcting for the potential endogeneity of becoming a partner. However, voluntary measures take many different forms, some of which are expected to have transfers to non-partners (spillovers). The Coal Combustion Products Partnership (C2P2) is a U.S. voluntary program with a structure that is likely to provide treatment spillovers to non-partners. This paper evaluates C2P2 and tests whether treatment spillovers are affecting non-partners' behavior. Results are consistent with a program that would traditionally be considered unsuccessful, but the consideration of treatment spillovers makes it consistent with a successful program.

  12. Advanced Multi-Product Coal Utilization By-Product Processing Plant

    SciTech Connect (OSTI)

    Thomas Robl; John Groppo

    2007-03-31T23:59:59.000Z

    The objective of the project is to build a multi-product ash beneficiation plant at Kentucky Utilities 2,200-MW Ghent Generating Station, located in Carroll County, Kentucky. Phase 1 was completed successfully, but the project did not continue on to Phase 2 due to withdrawal of CEMEX from the project. Attempts at replacing CEMEX were not successful. Problematic to the continuation of the project was its location in the Ohio Valley which is oversupplied and has low prices for fly ash and the change in CEMEX priorities due to merger and acquisitions. Thus, CAER concurred with the DOE to conclude the project at the end of Budget Period 1, March 31, 2007.

  13. Economic Evaluation of By-Product Power/Co-Generation Systems for Industrial Plants with Fluidized-Bed Coal Burning Facilities

    E-Print Network [OSTI]

    Mesko, J. E.

    1980-01-01T23:59:59.000Z

    Economic analysis of the construction and operation of by-product electric power and steam/power cogeneration systems in coal fired fluidized-bed steam cycles, located at individual industrial sites analyzed by the author, is being presented...

  14. Survey of government assistance for the world's hard-coal industries

    SciTech Connect (OSTI)

    Neme, L.A.; Yancik, J.J.

    1989-05-01T23:59:59.000Z

    This report investigates the existence and use of subsidies and incentives that foreign nations give their coal industries. Of particular interest are those aids that promote and facilitate the export of coal. A survey of hard coal producing countries was conducted to compile, and quantify if possible, direct and indirect financial aids given by governments for the purposes of maintaining, expanding or creating an indigenous coal industry and facilitating exports. The survey found that government measures commonly used to maintain, expand or create coal production include deficit operating grants, capital grants, preferential loan credits, labor and tax benefits, and export marketing assistance. Typical measures used to guarantee and protect domestic coal markets are long-term supply agreements, price supports, government purchases, tariffs, import licenses, and quotas. Common types of financial assistance provided by governments that do not benefit current coal production or use are research and development funds, environmental grants for restoring past mined lands, and payments to unemployed miners.

  15. Utilization of coal mine methane for methanol and SCP production. Topical report, May 5, 1995--March 4, 1996

    SciTech Connect (OSTI)

    NONE

    1998-12-31T23:59:59.000Z

    The feasibility of utilizing a biological process to reduce methane emissions from coal mines and to produce valuable single cell protein (SCP) and/or methanol as a product has been demonstrated. The quantities of coal mine methane from vent gas, gob wells, premining wells and abandoned mines have been determined in order to define the potential for utilizing mine gases as a resource. It is estimated that 300 MMCFD of methane is produced in the United States at a typical concentration of 0.2-0.6 percent in ventilation air. Of this total, almost 20 percent is produced from the four Jim Walter Resources (JWR) mines, which are located in very gassy coal seams. Worldwide vent gas production is estimated at 1 BCFD. Gob gas methane production in the U.S. is estimated to be 38 MMCFD. Very little gob gas is produced outside the U.S. In addition, it is estimated that abandoned mines may generate as much as 90 MMCFD of methane. In order to make a significant impact on coal mine methane emissions, technology which is able to utilize dilute vent gases as a resource must be developed. Purification of the methane from the vent gases would be very expensive and impractical. Therefore, the process application must be able to use a dilute methane stream. Biological conversion of this dilute methane (as well as the more concentrated gob gases) to produce single cell protein (SCP) and/or methanol has been demonstrated in the Bioengineering Resources, Inc. (BRI) laboratories. SCP is used as an animal feed supplement, which commands a high price, about $0.11 per pound.

  16. Help for declining natural gas production seen in the unconventional sources of natural gas. [Eastern shales, tight sands, coal beds, geopressured zones

    SciTech Connect (OSTI)

    Staats, E.B.

    1980-01-10T23:59:59.000Z

    Oil imports could be reduced and domestic gas production increased if additional gas production is obtained from four unconventional resources-eastern Devonian shales, tight sands, coal beds, and geopressured zones. Gas produced from these resources can help maintain overall production levels as supplies from conventional gas sources gradually decline. The eastern shales and western sands are the chief potential contributors in the near term. Further demonstrations of coal bed methane's recovery feasibility could improve the prospects for its production while future geopressured methane production remains speculative at this time.

  17. High conversion of coal to transportation fuels for the future with low HC gas production. Progress report No. 5, October 1, 1993--December 31, 1993

    SciTech Connect (OSTI)

    Wiser, W.H.; Oblad, A.G.

    1994-05-01T23:59:59.000Z

    An announced objective of the Department of Energy in funding this work, and other current research in coal liquefaction, is to produce a synthetic crude from coal at a cost lower than $30.00 per barrel. A second objective, reflecting a recent change in direction in the synthetic fuels effort of DOE, is to produce a fuel which is low in aromatics, yet of sufficiently high octane number for use in the gasoline-burning transportation vehicles of today. To meet this second objective, research was proposed, and funding awarded, for conversion of the highly-aromatic liquid product from coal conversion to a product high in isoparaffins, which compounds in the gasoline range exhibit a high octane number. Experimental coal liquefaction studies conducted in a batch microreactor in the authors laboratory have demonstrated potential for high conversions of coal to liquids with low yields of hydrocarbon (HC) gases, hence small consumption of hydrogen in the primary liquefaction step. Ratios of liquids/HC gases as high as 30/1, at liquid yields as high as 82% of the coal by weight, have been achieved. The principal objective of this work is to examine how nearly such results may be approached in a continuous-flow system, at a size sufficient to evaluate the process concept for production of transportation fuels from coal.

  18. China's Coal: Demand, Constraints, and Externalities

    E-Print Network [OSTI]

    Aden, Nathaniel

    2010-01-01T23:59:59.000Z

    raising transportation oil demand. Growing internationalcoal by wire could reduce oil demand by stemming coal roadEastern oil production. The rapid growth of coal demand

  19. Utility Generation and Clean Coal Technology (Indiana)

    Broader source: Energy.gov [DOE]

    This statute establishes the state's support and incentives for the development of new energy production and generating facilities implementing advanced clean coal technology, such as coal...

  20. Production of carbon molecular sieves from Illinois coal. [Quarterly] technical report, March 1, 1993--May 31, 1993

    SciTech Connect (OSTI)

    Lizzio, A.A.; Rostam-Abadi, M. [Illinois State Geological Survey, Champaign, IL (United States)

    1993-09-01T23:59:59.000Z

    Carbon molecular sieves (CMS) have become an increasingly important class of adsorbents for use in gas separation and recover processes. The overall objective of this project is to determine whether Illinois Basin coals are suitable feedstocks for the production of CMS and to evaluate the potential application of these products in commercial gas separation processes. In Phase I of this project, gram quantities of char were prepared from Illinois coal in a fixed-bed reactor under a wide range of pyrolysis and activation conditions. Chars having surface areas of 1500--2100 m{sup 2}/g were produced by chemical activation using potassium hydroxide (KOH) as the activant. These high surface area chars had more than twice the adsorption capacity of commercial molecular sieves. The kinetics of adsorption of various gases, e.g., N{sub 2}, O{sub 2}, CO{sub 2}, CH{sub 4}, CO and H{sub 2}, on these chars at 25{degrees}C was determined. Several chars showed good potential for efficient O{sub 2}/N{sub 2}, CO{sub 2}/CH{sub 4} and CH{sub 4}/H{sub 2} separation; both a high adsorption capacity and selectivity were achieved. The full potential of these materials in commercial gas separations has yet to be realized. In Phase II of this project, larger quantities of char are being prepared from Illinois coal in a batch fluidized-bed reactor and in a continuous rotary tube kiln.

  1. AISI/DOE Technology Roadmap Program: A Technology of Low Coal Rate and High Productivity of RHF Ironmaking

    SciTech Connect (OSTI)

    Wei-Kao Lu

    2002-09-15T23:59:59.000Z

    An economical and environment-friendly ironmaking process based on heating the chemiexecy self-sufficient green balls of iron ore and coal in a hearth furnace is being developed with financial support from AISI members and DOE. DRI, which is hot (1400 C), dense (3.2 g/cm) and of high degree of metallization (95%), has been produced in laboratory and in a pilot plant in Genoa, Italy. Products of such quality have been made from American and Brazilian ores, BOF sludge, EAF dust/BOF sludge mixtures and millscale. The removal of zinc and lead from green balls by this process is essentially complete. In comparison with typical blast furnace operation, the new technology with a melter would have a lower total coal rate by 200kg.THM. The elimination of cokemaking and high temperature agglomeration steps, and a simpler gas handling system would lead to lower capital and operating costs. In comparison with commercial RHF practice it is different in atmosphere (fully oxidized at 1600 to 1650 C), in bed height (120 mm instead of 20-25 mm) and in pellet composition (much less coal but of higher VM). The combined effect leads to three times higher furnace productivity, lower coal consumption and superior DRI quality. The risk of re-oxidation (slag formation) and dusty operation are practiexecy eliminated. The process is stable, tolerant and independent of the size, shape and movement of the hearth. However, materials handling (e.g., discharge of hot DRI) and the exact energy savings have to be established in a larger furnace, straight or rotary, and in a continuous mode of operation.

  2. Washability of trace elements in product coals from Illinois mines. Technical report, 1 December 1993--28 February 1994

    SciTech Connect (OSTI)

    Demir, I.; Ruch, R.R.; Harvey, R.D.; Steele, J.D.; Khan, S. [Illinois State Geological Survey, Champaign, IL (United States)

    1994-06-01T23:59:59.000Z

    The existing trace element washability data on Illinois coals are based on float-sink methods, and these data are not applicable to modern froth flotation or column flotation processes. Particularly, there is a lack of washability data on samples from modern preparation plants, as well as other product (as-shipped) coals. The goal of this project is to provide the needed trace element washability data on as-shipped coals that were collected during 1992--1993 from Illinois mines. During the second quarter, froth flotation/release analysis (FF/RA) tests on 34 project samples were completed at {minus}100, {minus}200, and {minus}400 mesh particle sizes. Products from the FF/RA tests were analyzed for ash, moisture, and some for total S and heating value (BTU), and the resulting data are being used to construct a series of washability curves. For example, these curves can show variation in BTU or combustible recovery as a function of the amount of ash or S rejected. Composite samples, each having 80% of the total BTU (or combustibles), were prepared for the {minus}100 and {minus}200 mesh FF/RA tests and submitted for trace element analysis. The composite samples for the {minus}400 mesh FF/RA tests will be submitted soon, and the analytical results are expected to be available in 3--4 months. The trace element data on the composite samples will indicate the potential for the removal of each element from the coals at the chosen flotation conditions and particle sizes.

  3. Coal recovery process

    DOE Patents [OSTI]

    Good, Robert J. (Grand Island, NY); Badgujar, Mohan (Williamsville, NY)

    1992-01-01T23:59:59.000Z

    A method for the beneficiation of coal by selective agglomeration and the beneficiated coal product thereof is disclosed wherein coal, comprising impurities, is comminuted to a particle size sufficient to allow impurities contained therein to disperse in water, an aqueous slurry is formed with the comminuted coal particles, treated with a compound, such as a polysaccharide and/or disaccharide, to increase the relative hydrophilicity of hydrophilic components, and thereafter the slurry is treated with sufficient liquid agglomerant to form a coagulum comprising reduced impurity coal.

  4. Evaluation of Phytoremediation of Coal Bed Methane Product Water and Waters of Quality Similar to that Associated with Coal Bed Methane Reserves of the Powder River Basin, Montana and Wyoming

    SciTech Connect (OSTI)

    James Bauder

    2008-09-30T23:59:59.000Z

    U.S. emphasis on domestic energy independence, along with advances in knowledge of vast biogenically sourced coalbed methane reserves at relatively shallow sub-surface depths with the Powder River Basin, has resulted in rapid expansion of the coalbed methane industry in Wyoming and Montana. Techniques have recently been developed which constitute relatively efficient drilling and methane gas recovery and extraction techniques. However, this relatively efficient recovery requires aggressive reduction of hydrostatic pressure within water-saturated coal formations where the methane is trapped. Water removed from the coal formation during pumping is typically moderately saline and sodium-bicarbonate rich, and managed as an industrial waste product. Current approaches to coalbed methane product water management include: surface spreading on rangeland landscapes, managed irrigation of agricultural crop lands, direct discharge to ephermeral channels, permitted discharge of treated and untreated water to perennial streams, evaporation, subsurface injection at either shallow or deep depths. A Department of Energy-National Energy Technology Laboratory funded research award involved the investigation and assessment of: (1) phytoremediation as a water management technique for waste water produced in association with coalbed methane gas extraction; (2) feasibility of commercial-scale, low-impact industrial water treatment technologies for the reduction of salinity and sodicity in coalbed methane gas extraction by-product water; and (3) interactions of coalbed methane extraction by-product water with landscapes, vegetation, and water resources of the Powder River Basin. Prospective, greenhouse studies of salt tolerance and water use potential of indigenous, riparian vegetation species in saline-sodic environments confirmed the hypothesis that species such as Prairie cordgrass, Baltic rush, American bulrush, and Nuttall's alkaligrass will thrive in saline-sodic environments when water supplies sourced from coalbed methane extraction are plentiful. Constructed wetlands, planted to native, salt tolerant species demonstrated potential to utilize substantial volumes of coalbed methane product water, although plant community transitions to mono-culture and limited diversity communities is a likely consequence over time. Additionally, selected, cultured forage quality barley varieties and native plant species such as Quail bush, 4-wing saltbush, and seaside barley are capable of sustainable, high quality livestock forage production, when irrigated with coalbed methane product water sourced from the Powder River Basin. A consequence of long-term plant water use which was enumerated is elevated salinity and sodicity concentrations within soil and shallow alluvial groundwater into which coalbed methane product water might drain. The most significant conclusion of these investigations was the understanding that phytoremediation is not a viable, effective technique for management of coalbed methane product water under the present circumstances of produced water within the Powder River Basin. Phytoremediation is likely an effective approach to sodium and salt removal from salt-impaired sites after product water discharges are discontinued and site reclamation is desired. Coalbed methane product water of the Powder River Basin is most frequently impaired with respect to beneficial use quality by elevated sodicity, a water quality constituent which can cause swelling, slaking, and dispersion of smectite-dominated clay soils, such as commonly occurring within the Powder River Basin. To address this issue, a commercial-scale fluid-bed, cationic resin exchange treatment process and prototype operating treatment plant was developed and beta-tested by Drake Water Technologies under subcontract to this award. Drake Water Technologies secured U.S. Patent No. 7,368,059-B2, 'Method for removal of benevolent cations from contaminated water', a beta Drake Process Unit (DPU) was developed and deployed for operation in the Powder River Basin. First year operatio

  5. Opportunities in underground coal gasification

    SciTech Connect (OSTI)

    Bloomstran, M.A.; Davis, B.E.

    1984-06-01T23:59:59.000Z

    A review is presented of the results obtained on DOE-sponsored field tests of underground coal gasification in steeply-dipping beds at Rawlins, Wyoming. The coal gas composition, process parameters, and process economics are described. Steeply-dipping coal resources, which are not economically mineable using conventional coal mining methods, are identified and potential markets for underground coal gasification products are discussed. It is concluded that in-situ gasification in steeply-dipping deposits should be considered for commercialization.

  6. Design Concepts for Co-Production of Power, Fuels & Chemicals Via Coal/Biomass Mixtures

    SciTech Connect (OSTI)

    Rao, A. D.; Chen, Q.; Samuelsen, G. S.

    2012-09-30T23:59:59.000Z

    The overall goal of the program is to develop design concepts, incorporating advanced technologies in areas such as oxygen production, feed systems, gas cleanup, component separations and gas turbines, for integrated and economically viable coal and biomass fed gasification facilities equipped with carbon capture and storage for the following scenarios: (i) coproduction of power along with hydrogen, (ii) coproduction of power along with fuels, (iii) coproduction of power along with petrochemicals, and (iv) coproduction of power along with agricultural chemicals. To achieve this goal, specifically the following objectives are met in this proposed project: (i) identify advanced technology options and innovative preliminary design concepts that synergistically integrate plant subsections, (ii) develop steady state system simulations to predict plant efficiency and environmental signature, (iii) develop plant cost estimates by capacity factoring major subsystems or by major equipment items where required, and then capital, operating and maintenance cost estimates, and (iv) perform techno- economic analyses for the above described coproduction facilities. Thermal efficiencies for the electricity only cases with 90% carbon capture are 38.26% and 36.76% (HHV basis) with the bituminous and the lignite feedstocks respectively. For the coproduction cases (where 50% of the energy exported is in the form of electricity), the electrical efficiency, as expected, is highest for the hydrogen coproduction cases while lowest for the higher alcohols (ethanol) coproduction cases. The electrical efficiencies for Fischer-Tropsch coproduction cases are slightly higher than those for the methanol coproduction cases but it should be noted that the methanol (as well as the higher alcohol) coproduction cases produce the finished coproduct while the Fischer-Tropsch coproduction cases produce a coproduct that requires further processing in a refinery. The cross comparison of the thermal performance between the various coproduct cases is further complicated by the fact that the carbon footprint is not the same when carbon leaving with the coproduct are accounted for. The economic analysis and demand for a particular coproduct in the market place is a more meaningful comparison of the various coproduction scenarios. The first year cost of electricity calculated for the bituminous coal is $102.9/MWh while that for the lignite is $108.1/MWh. The calculated cost of hydrogen ranged from $1.42/kg to $2.77/kg depending on the feedstock, which is lower than the DOE announced hydrogen cost goal of $3.00/kg in July 14, 2005. Methanol cost ranged from $345/MT to $617/MT, while the market price is around $450/MT. For Fischer-Tropsch liquids, the calculated cost ranged from $65/bbl to $112/bbl, which is comparable to the current market price of crude oil at around $100/bbl. It should be noted, however, that F-T liquids contain no sulfur and nitrogen compounds. The calculated cost of alcohol ranged from $4.37/gal to $5.43/gal, while it ranged from $2.20/gal to $3.70/gal in a DOE funded study conducted by Louisiana State University. The Louisiana State University study consisted of a significantly larger plant than our study and benefited from economies of scale. When the plant size in our study is scaled up to similar size as in the Louisiana State University study, cost of alcohol is then reduced to a range of $3.24/gal to $4.28/gal, which is comparable. Urea cost ranged from $307/MT to $428/MT, while the market price is around $480/MT.

  7. Categorical Exclusion Determinations: National Energy Technology...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Exclusion Determination Advancing Coal Catalytic Gasification to Promote Optimum Syngas Production CX(s) Applied: B3.6 Date: 41884 Location(s): Utah Offices(s): National...

  8. DESULFURIZATION OF COAL MODEL COMPOUNDS AND COAL LIQUIDS

    E-Print Network [OSTI]

    Wrathall, James Anthony

    2011-01-01T23:59:59.000Z

    of coal sulfur K-T gasification process SRC I process U. S.flow sheet of a K-T coal gasification complex for producingProduction via K-T Gasification" © CEP Aug. 78. Feed

  9. Coal sector profile

    SciTech Connect (OSTI)

    Not Available

    1990-06-05T23:59:59.000Z

    Coal is our largest domestic energy resource with recoverable reserves estimated at 268 billion short tons or 5.896 quads Btu equivalent. This is approximately 95 percent of US fossil energy resources. It is relatively inexpensive to mine, and on a per Btu basis it is generally much less costly to produce than other energy sources. Its chief drawbacks are the environmental, health and safety concerns that must be addressed in its production and consumption. Historically, coal has played a major role in US energy markets. Coal fueled the railroads, heated the homes, powered the factories. and provided the raw materials for steel-making. In 1920, coal supplied over three times the amount of energy of oil, gas, and hydro combined. From 1920 until the mid 1970s, coal production remained fairly constant at 400 to 600 million short tons a year. Rapid increases in overall energy demands, which began during and after World War II were mostly met by oil and gas. By the mid 1940s, coal represented only half of total energy consumption in the US. In fact, post-war coal production, which had risen in support of the war effort and the postwar Marshall plan, decreased approximately 25 percent between 1945 and 1960. Coal demand in the post-war era up until the 1970s was characterized by increasing coal use by the electric utilities but decreasing coal use in many other markets (e.g., rail transportation). The oil price shocks of the 1970s, combined with natural gas shortages and problems with nuclear power, returned coal to a position of prominence. The greatly expanded use of coal was seen as a key building block in US energy strategies of the 1970s. Coal production increased from 613 million short tons per year in 1970 to 950 million short tons in 1988, up over 50 percent.

  10. Production and screening of carbon products precursors from coal. Quarterly technical progress report and key personnel staffing report No. 3, July 1, 1995--Sepember 30, 1995

    SciTech Connect (OSTI)

    NONE

    1995-10-01T23:59:59.000Z

    Tasks 1 and 2 involve preparation of a Project Management Plan and establishment of a Participants Agreement/Proprietary Information Agreement for members of the Carbon Products Consortium (CPC). These tasks are now complete. Task 3 is to provide a series of samples of solvent extracted coal to the CPC participants and to incorporate their feedback and suggestions into subsequent samples. As of September 30, 1995, UCAR has received two rounds of samples; Koppers has received one round of samples; ALCOA and AMOCO have not yet specified the types of samples they wish to receive; FMI has received one round of samples and has requested a rather large, five kilogram, sample of coal extracts to do multiple impregnation on a large carbon fiber preform. There are extensive communications between the WVU research team and the five industrial partners. Task 4, cooperation with MITRE on their preparation of an economic analysis of the solvent extraction, is complete. Task 5, Technology Transfer, is an on going endeavor with research team meetings, general CPC meetings, presentations of conference papers, and submission of required reports. The CPC is finally functioning as it has been envisioned, i.e., with the WVU solvent extracted coal materials being evaluated by several companies as precursor for their individual product lines. The companies are comparing the WVU materials with commercially available pitches and cokes.

  11. International, National, and Virginia Trends

    E-Print Network [OSTI]

    .............................................................................................................1 Global Coal Production and Consumption Trends ...................................................2.S. Electricity Generation....................................................................................15 U.S. Coal Consumption

  12. Integrated production/use of ultra low-ash coal, premium liquids and clean char. Final technical report, September 1, 1991--August 31, 1992

    SciTech Connect (OSTI)

    Kruse, C.W.; Carlson, S.L. [Illinois State Geological Survey, Champaign, IL (United States); Snoeyink, V.L.; Feizoulof, C.; Assanis; Syrimis, M. [Illinois Univ., Urbana (United States); Fatemi, S.M. [Amoco, Naperville, IL (United States)

    1992-12-31T23:59:59.000Z

    The objective of this research is to invert the conventional scale of values for products of coal utilization processes by making coal chars (carbons) that, because of their unique properties, are the most valuable materials in the product slate. A unique type of coal-derived carbon studied in this project is oxidized activated coal char having both adsorptive and catalyst properties. Major program elements were (a) preparation and characterization of materials (b) characterization of carbons and catalyst testing (c) completion of diesel engine testing of low-ash coal and (d) initiation of a two-year adsorption study. Materials prepared were (a) two low-ash coal samples one via ChemCoal processing of IBC-109 and the other by acid dissolution of IBC-109`s mineral matter, (b) coal char (MG char), (c) activated low-ash carbon (AC), (d) oxidized activated carbon (OAC). Amoco continued its support with state-of-the art analytical capabilities and development of catalyst testing procedures. Diesel engine tests were made with low ash coal dispersed in diesel fuel at solid loadings of 20% and 35%. The slurry was successfully burned in cylinder 2 of a two-cylinder diesel engine, after modifications of the engine`s fuel injection system. The higher speed proved to be more favorable but the slurry burned with a slightly improved thermal and combustion efficiency at both speeds with respect to diesel fuel alone. Adsorption studies included preparation of seven base-line carbon samples and their characterization, including their N{sub 2} BET surface areas and apparent densities. Paranitrophenol (PNP) adsorption isotherms were determined for the six controls. Oxidation of carbon with nitric acid decreases activated carbon`s PNP adsorption capacity while air oxidation increases adsorption capacity.

  13. Integrated production/use of ultra low-ash coal, premium liquids and clean char. Technical report, March 1, 1992--May 31, 1992

    SciTech Connect (OSTI)

    Kruse, C.W.; Carlson, S.L. [Illinois State Geological Survey, Champaign, IL (United States); Snoeyink, V.L.; Feizoulof, C.; Assanis, D.N.; Syrimis, M. [Illinois Univ., Urbana, IL (United States); Fatemi, S.M. [Amoco Research Center, Naperville, IL (United States)

    1992-10-01T23:59:59.000Z

    The first step in the envisioned integrated, multi-product approach for utilizing Illinois coal is the production of ultra low-ash coal. Subsequent steps would convert low-ash coal to high-value products through mild gasification, char activation, and oxidation reactions. Approximately eight pounds of low-ash coal has been obtained from the crude reactor slurry produced for us at the University of North Dakota Energy and Environmental Research Center (UNDEERC). After treatment to remove the remaining meta-cresol, this material will be subjected to mild gasification. Low-ash mild gasification char will be activated and a catalyst surface will be added by oxidation. A 20% coal: 80% diesel fuel slurry was tested in cylinder two of a two-cylinder, diesel engine after the necessary modifications in the engine`s fuel injection system were made. Four tests indicated that the coal successfully substitutes for diesel fuel in the slurry. The fuel burns in the cylinder, with slightly improved thermal and combustion efficiency. The tests were performed at 1800 rpm and 2200 rpm and 75% load. The change in the surface properties of Calgon F-400 commercial activated carbon caused by several treatments were examined by X-ray Photoelectron Spectroscopy (XPS).

  14. Coal liquefaction quenching process

    DOE Patents [OSTI]

    Thorogood, Robert M. (Macungie, PA); Yeh, Chung-Liang (Bethlehem, PA); Donath, Ernest E. (St. Croix, VI)

    1983-01-01T23:59:59.000Z

    There is described an improved coal liquefaction quenching process which prevents the formation of coke with a minimum reduction of thermal efficiency of the coal liquefaction process. In the process, the rapid cooling of the liquid/solid products of the coal liquefaction reaction is performed without the cooling of the associated vapor stream to thereby prevent formation of coke and the occurrence of retrograde reactions. The rapid cooling is achieved by recycling a subcooled portion of the liquid/solid mixture to the lower section of a phase separator that separates the vapor from the liquid/solid products leaving the coal reactor.

  15. Hydrogen from Coal Edward Schmetz

    E-Print Network [OSTI]

    Turbines Carbon Capture & Sequestration Carbon Capture & Sequestration The Hydrogen from Coal Program Cells, Turbines, and Carbon Capture & Sequestration #12;Production Goal for Hydrogen from Coal Central Separation System PSA Membrane Membrane Carbon Sequestration Yes (87%) Yes (100%) Yes (100%) Hydrogen

  16. 2009 Coal Age Buyers Guide

    SciTech Connect (OSTI)

    NONE

    2009-07-15T23:59:59.000Z

    The buyers guide lists more than 1200 companies mainly based in the USA, that provide equipment and services to US coal mines and coal preparation plants. The guide is subdivided by product categories.

  17. Low-rank coal study: national needs for resource development. Volume 6. Peat

    SciTech Connect (OSTI)

    Not Available

    1980-11-01T23:59:59.000Z

    The requirements and potential for development of US peat resources for energy use are reviewed. Factors analyzed include the occurrence and properties of major peat deposits; technologies for extraction, dewatering, preparation, combustion, and conversion of peat to solid, liquid, or gaseous fuels; environmental, regulatory, and market constraints; and research, development, and demonstration (RD and D) needs. Based on a review of existing research efforts, recommendations are made for a comprehensive national RD and D program to enhance the use of peat as an energy source.

  18. Design manual for management of solid by-products from advanced coal technologies

    SciTech Connect (OSTI)

    NONE

    1994-10-01T23:59:59.000Z

    Developing coal conversion technologies face major obstacles in byproduct management. This project has developed several management strategies based on field trials of small-scale landfills in an earlier phase of the project, as well as on published/unpublished sources detailing regulatory issues, current industry practice, and reuse opportunities. Field testing, which forms the basis for several of the disposal alternatives presented in this design manual, was limited to byproducts from Ca-based dry SO{sub 2} control technologies, circulating fluidized bed combustion ash, and bubbling bed fluidized bed combustion ash. Data on byproducts from other advanced coal technologies and on reuse opportunities are drawn from other sources (citations following Chapter 3). Field results from the 5 test cases examined under this project, together with results from other ongoing research, provide a basis for predictive modeling of long-term performance of some advanced coal byproducts on exposure to ambient environment. This manual is intended to provide a reference database and development plan for designing, permitting, and operating facilities where advanced coal technology byproducts are managed.

  19. Production of carbon molecular sieves from Illinois coal. [Quarterly] technical report, December 1, 1993--February 28, 1994

    SciTech Connect (OSTI)

    Lizzio, A.A.; Rostam-Abadi, M. [Illinois State Geological Survey, Champaign, IL (United States); Vyas, S.N. [Indian Institute of Technology, Bombay (India)

    1994-06-01T23:59:59.000Z

    Carbon molecular sieves (CMS) have become an increasingly important class of adsorbents for use in gas separation and recovery processes. The overall objective of this project is to determine whether Illinois coal is a suitable feedstock for the production of CMS and to evaluate the potential application of the products in commercial gas separation processes. In Phase I of this project, gram quantities of char were produced from IBC-102 coal in a fixed-bed reactor under a wide range of pyrolysis and activation conditions. The kinetics of adsorption of various gases, i.e., O{sub 2}, N{sub 2}, CO{sub 2}, CH{sub 4} and H{sub 2}, on these chars at 25{degree}C was studied. Several chars showed good potential for efficient O{sub 2}/N{sub 2}, CO{sub 2}/CH{sub 4}, CO{sub 2}H{sub 2} and CH{sub 4}/H{sub 2} separation; both high adsorption capacities and selectivities were achieved. The full potential of these materials in commercial gas separations has yet to be realized. In Phase II, the optimal char preparation conditions determined in Phase I are applied to production of larger quantities of CMS in a batch fluidized-bed reactor (FBR) and a continuous rotary tube kiln (RTFK).

  20. Environmental externalities: An ASEAN application to coal-based power generation. [Association of South East Asian Nations (ASEAN)

    SciTech Connect (OSTI)

    Szpunar, C.B.; Gillette, J.L.

    1992-06-01T23:59:59.000Z

    Significant benefits to human health that result from emissions control programs may justify the costs of pollution control policies. Many scientists, economists, risk analysts, and policymakers believe that comparisons of the benefits with the costs of pollution control demonstrate that the US stationary source, air emissions control program is justified. This justification is based upon pronounced benefits to human health, especially from controlling suspended particulates and sulfur compounds. Market decisions are usually made on the basis of a consideration of traditional costs such as capital, operating and maintenance, fuel costs, and fixed charges. Social costs, which could be significant, are not incorporated explicitly into such decisions. These social costs could result in a net reduction in the welfare of individuals, and of society as a whole. Because these social costs and their effects are not represented in the price of energy, individual have no way to explicitly value them; hence, they remain unaccounted for in market decisions. By accounting for external costs, the selection of energy sources and production of energy products can lead to and equilibrium, where the total cost of energy and energy products, together with resulting social costs, can be brought to an economic minimum. The concept of an air emissions control program is of interest to the ASEAN countries (Brunei, Indonesia, Malaysia, the Philippines, Singapore, and Thailand) and their governments, especially if such a program could be justified in cost-benefit terms and shown to be directly applicable to ASEAN conditions. It is the intent of the effort described herein to demonstrate that technical options are available to control emissions from coal-based, electric power plants and that that costs of these options may be justified in cost-benefit terms.

  1. Barriers to the increased utilization of coal combustion/desulfurization by-products by government and commercial sectors - Update 1998

    SciTech Connect (OSTI)

    Pflughoeft-Hassett, D.F.; Sondreal, E.A.; Steadman, E.N.; Eylands, K.E.; Dockter, B.A.

    1999-07-01T23:59:59.000Z

    The following conclusions are drawn from the information presented in this report: (1) Joint efforts by industry and government focused on meeting RTC recommendations for reduction/removal of barriers have met with some success. The most notable of these are the changes in regulations related to CCB utilization by individual states. Regionally or nationally consistent state regulation of CCB utilization would further reduce regulatory barriers. (2) Technology changes will continue to be driven by the CAAA, and emission control technologies are expected to continue to impact the type and properties of CCBs generated. As a result, continued RD and D will be needed to learn how to utilize new and changing CCBs in environmentally safe, technically sound, and economically advantageous ways. Clean coal technology CCBs offer a new challenge because of the high volumes expected to be generated and the different characteristics of these CCBs compared to those of conventional CCBs. (3) Industry and government have developed the RD and D infrastructure to address the technical aspects of developing and testing new CCB utilization applications, but this work as well as constant quality control/quality assurance testing needs to be continued to address both industry wide issues and issues related to specific materials, regions, or users. (4) Concerns raised by environmental groups and the public will continue to provide environmental and technical challenges to the CCB industry. It is anticipated that the use of CCBs in mining applications, agriculture, structural fills, and other land applications will continue to be controversial and will require case-by-case technical and environmental information to be developed. The best use of this information will be in the development of generic regulations specifically addressing the use of CCBs in these different types of CCB applications. (5) The development of federal procurement guidelines under Executive Order 12873 titled ''Federal Acquisition, Recycling and Waste Prevention,'' in October 1993 was a positive step toward getting CCBs accepted in the marketplace. Industry needs to continue to work with EPA to develop additional procurement guidelines for products containing CCBs--and to take advantage of existing guidelines to encourage the use of CCBs in high-profile projects. (6) Accelerated progress toward increased utilization of CCBs can be made only if there is an increased financial commitment and technical effort by industry and government. The framework for this has been set by the successful cooperation of industry and government under DOE leadership. Cooperation should continue, with DOE fulfilling its lead role established in the RTC. It is clear that the RTC recommendations continue to have validity with respect to increasing CCB utilization and continue to provide guidance to industry and government agencies.

  2. An Industrial-Based Consortium to Develop Premium Carbon Products from Coal, Annual Progress Report, October 1, 2005 through September 30, 2006

    SciTech Connect (OSTI)

    Bruce G. Miller

    2006-09-29T23:59:59.000Z

    Since 1998, The Pennsylvania State University has been successfully managing the Consortium for Premium Carbon Products from Coal (CPCPC), which is a vehicle for industry-driven research on the promotion, development, and transfer of innovative technology on premium carbon produces from coal to the U.S. industry. The CPCPC is an initiative being led by Penn State, its co-charter member West Virginia University (WVU), and the U.S. Department of Energy's (DOE) National Energy Technology Laboratory (NETL), who also provides the base funding for the program, with Penn State responsible for consortium management. CPCPC began in 1998 under DOE Cooperative Agreement No. DE-FC26-98FT40350. This agreement ended November 2004 but the CPCPC activity has continued under the present cooperative agreement, No. DE-FC26-03NT41874, which started October 1, 2003. The objective of the second agreement is to continue the successful operation of the CPCPC. The CPCPC has enjoyed tremendous success with its organizational structure, that includes Penn State and WVU as charter members, numerous industrial affiliate members, and strategic university affiliate members together with NETL, forming a vibrant and creative team for innovative research in the area of transforming coal to carbon products. The key aspect of CPCPC is its industry-led council that selects proposals submitted by CPCPC members to ensure CPCPC target areas have strong industrial support. Base funding for the selected projects is provided by NETL with matching funds from industry. At the annual funding meeting held in October 2003, ten projects were selected for funding. Subcontracts were let from Penn State to the subcontractors on March 1, 2004. Nine of the ten 2004 projects were completed during the previous annual reporting period and their final reports were submitted with the previous annual report (i.e., 10/01/04-09/30/05). The final report for the remaining project, which was submitted during this reporting period (i.e., 10/01/05-09/30/06), is attached. At the annual funding meeting held in November 2004, eleven projects were selected for funding. Subcontracts were let from Penn State to the subcontractors on March 1, 2005. Three additional projects were selected for funding during the April 2005 tutorial/funding meeting. Subcontracts were let from Penn State to the subcontractors on July 1, 2005. Of these fourteen 2005 projects, eleven have been completed and the final reports are attached. An annual funding meeting was held in November 2005 and the council selected five projects for funding. Subcontracts were let from Penn State to the subcontractors on March 1, 2006, except for one that started October 1, 2006.

  3. An Industrial-Based Consortium to Develop Premium Carbon Products from Coal, Annual Progress Report, October 1, 2004 through September 30, 2005

    SciTech Connect (OSTI)

    Miller, Bruce G

    2006-03-01T23:59:59.000Z

    Since 1998, The Pennsylvania State University (PSU) has been successfully operating the Consortium for Premium Carbon Products from Coal (CPCPC), which is a vehicle for industry-driven research on the promotion, development, and transfer of innovative technology on premium carbon produces from coal to the U.S. industry. The CPCPC is an initiative being led by PSU, its co-charter member West Virginia University (WVU), and the U.S. Department of Energy's (DOE) National Energy Technology Laboratory (NETL), who also provides the base funding for the program, with PSU responsible for consortium management. CPCPC began in 1998 under DOE Cooperative Agreement No. DE-FC26-98FT40350. This agreement ended November 2004 but the CPCPC activity has continued under the present cooperative agreement, No. DE-FC26-03NT41874, which started October 1, 2003. The objective of the second agreement is to continue the successful operation of the CPCPC. The CPCPC has enjoyed tremendous success with its organizational structure, that includes PSU and WVU as charter members, numerous industrial affiliate members, and strategic university affiliate members together with NETL, forming a vibrant and creative team for innovative research in the area of transforming coal to carbon products. The key aspect of CPCPC is its industry-led council that selects proposals submitted by CPCPC members to ensure CPCPC target areas have strong industrial support. A second contract was executed with DOE NETL starting in October 2003 to continue the activities of CPCPC. An annual funding meeting was held in October 2003 and the council selected ten projects for funding. Base funding for the projects is provided by NETL with matching funds from industry. Subcontracts were let from Penn State to the subcontractors on March 1, 2004. Nine of the ten projects have been completed and the final reports for these 2004 projects are attached. An annual funding meeting was held in November 2004 and the council selected eleven projects for funding. Subcontracts were let from Penn State to the subcontractors on March 1, 2005. Three additional projects were selected for funding during the April 2005 tutorial/funding meeting. Subcontracts were let from Penn State to the subcontractors on July 1, 2005.

  4. Production of carbon molecular sieves from Illinois coal. Final technical report, 1 September, 1992--31 August 1993

    SciTech Connect (OSTI)

    Lizzio, A.A.; Rostam-Abadi, M. [Illinois State Geological Survey, Champaign, IL (United States)

    1993-12-31T23:59:59.000Z

    Carbon molecular sieves (CMS) have become an increasingly important class of adsorbents for use in gas separation and recovery processes. The overall objective of this project is to determine whether Illinois Basin coals are a suitable feedstock for the production of CMS and to evaluate the potential application of these products in commercial gas separation processes. In Phase 1 of this project, gram quantities of char were prepared from Illinois coal in a fixed-bed reactor under a wide range of pyrolysis and activation conditions. Chars having surface areas of 1,500--2,100 m{sup 2}/g were produced by chemical activation using potassium hydroxide (KOH) as the chemical activant. These high surface area (HSA) chars had more than twice the adsorption capacity of commercial molecular sieves. The kinetics of adsorption of various gases, e.g., O{sub 2}, N{sub 2}, CO{sub 2}, CH{sub 4}, and H{sub 2}, on these chars at 25 C was determined. Several chars showed good potential for efficient O{sub 2}/N{sub 2}, CO{sub 2}/CH{sub 4} and CH{sub 4}/H{sub 2} separation. In Phase 2 of this project, larger quantities of char are being prepared from Illinois coal in a batch fluidized-bed reactor and in a continuous rotary tube kiln. The ability of these chars to separate binary gas mixtures is tested in an adsorption column/gas chromatography system. Oxygen and nitrogen breakthrough curves obtained for selected chars were compared to those of a commercial zeolite. Selected chars were subjected to a nitric acid oxidation treatment. The air separation capability of nitric acid treated char was strongly dependent on the outgassing conditions used prior to an O{sub 2}/N{sub 2} adsorption experiment. An outgassing temperature of 130--160 C produced chars with the most favorable air separation properties. 61 refs.

  5. Clean and Secure Energy from Coal

    SciTech Connect (OSTI)

    Smith, Philip; Davies, Lincoln; Kelly, Kerry; Lighty, JoAnn; Reitze, Arnold; Silcox, Geoffrey; Uchitel, Kirsten; Wendt, Jost; Whitty, Kevin

    2014-08-31T23:59:59.000Z

    The University of Utah, through their Institute for Clean and Secure Energy (ICSE), performed research to utilize the vast energy stored in our domestic coal resources and to do so in a manner that will capture CO2 from combustion from stationary power generation. The research was organized around the theme of validation and uncertainty quantification (V/UQ) through tightly coupled simulation and experimental designs and through the integration of legal, environment, economics and policy issues. The project included the following tasks: • Oxy-Coal Combustion – To ultimately produce predictive capability with quantified uncertainty bounds for pilot-scale, single-burner, oxy-coal operation. • High-Pressure, Entrained-Flow Coal Gasification – To ultimately provide a simulation tool for industrial entrained-flow integrated gasification combined cycle (IGCC) gasifier with quantified uncertainty. • Chemical Looping Combustion (CLC) – To develop a new carbon-capture technology for coal through CLC and to transfer this technology to industry through a numerical simulation tool with quantified uncertainty bounds. • Underground Coal Thermal Treatment – To explore the potential for creating new in-situ technologies for production of synthetic natural gas (SNG) from deep coal deposits and to demonstrate this in a new laboratory-scale reactor. • Mercury Control – To understand the effect of oxy-firing on the fate of mercury. • Environmental, Legal, and Policy Issues – To address the legal and policy issues associated with carbon management strategies in order to assess the appropriate role of these technologies in our evolving national energy portfolio. • Validation/Uncertainty Quantification for Large Eddy Simulations of the Heat Flux in the Tangentially Fired Oxy-Coal Alstom Boiler Simulation Facility – To produce predictive capability with quantified uncertainty bounds for the heat flux in commercial-scale, tangentially fired, oxy-coal boilers.

  6. Method for the desulfurization of hot product gases from coal gasifier

    DOE Patents [OSTI]

    Grindley, Thomas (Morgantown, WV)

    1988-01-01T23:59:59.000Z

    The gasification of sulfur-bearing coal produces a synthesis gas which contains a considerable concentration of sulfur compounds especially hydrogen sulfide that renders the synthesis gas environmentally unacceptable unless the concentration of the sulfur compounds is significantly reduced. To provide for such a reduction in the sulfur compounds a calcium compound is added to the gasifier with the coal to provide some sulfur absorption. The synthesis gas from the gasifier contains sulfur compounds and is passed through an external bed of a regenerable solid absorbent, preferably zinc ferrite, for essentially completed desulfurizing the hot synthesis gas. This absorbent is, in turn, periodically or continuously regenerated by passing a mixture of steam and air or oxygen through the bed for converting absorbed hydrogen sulfide to sulfur dioxide. The resulting tail gas containing sulfur dioxide and steam is injected into the gasifier where the sulfur dioxide is converted by the calcium compound into a stable form of sulfur such as calcium sulfate.

  7. Description of Wyoming coal fields and seam analyses

    SciTech Connect (OSTI)

    Glass, G.B.

    1983-01-01T23:59:59.000Z

    Introductory material describe coal-bearing areas, coal-bearing rocks, and the structural geology of coal-bearing areas, discussing coal rank, proximate analyses, sulfur content, heat value, trace elements, carbonizing properties, coking coal, coking operations, in-situ gasification, coal mining, and production. The paper then gives descriptions of the coal seams with proximate analyses, where available, located in the following areas: Powder River coal basin, Green River region, Hanna field, Hams Fork coal region, and Bighorn coal basin. Very brief descriptions are given of the Wind River coal basin, Jackson Hole coal field, Black Hills coal region, Rock Creek coal field, and Goshen Hole coal field. Finally coal resources, production, and reserves are discussed. 76 references.

  8. Clean coal technology demonstration program: Program update 1996-97

    SciTech Connect (OSTI)

    NONE

    1997-10-01T23:59:59.000Z

    The Clean Coal Technology Demonstration Program (known as the CCT Program) reached a significant milestone in 1996 with the completion of 20 of the 39 active projects. The CCT Program is responding to a need to demonstrate and deploy a portfolio of technologies that will assure the U.S. recoverable coal reserves of 297 billion tons could continue to supply the nation`s energy needs economically and in a manner that meets the nation`s environmental objectives. This portfolio of technologies includes environmental control devices that contributed to meeting the accords on transboundary air pollution recommended by the Special Envoys on Acid Rain in 1986. Operational, technical, environmental, and economic performance information and data are now flowing from highly efficient, low-emission, advanced power generation technologies that will enable coal to retain its prominent role into the next millennium. Further, advanced technologies are emerging that will enhance the competitive use of coal in the industrial sector, such as in steelmaking. Coal processing technologies will enable the entire coal resource base to be used while complying with environmental requirements. These technologies are producing products used by utilities and industrial processes. The capability to coproduce products, such as liquid and solid fuels, electricity, and chemicals, is being demonstrated at a commercial scale by projects in the CCT Program. In summary, this portfolio of technologies is satisfying the national need to maintain a multifuel energy mix in which coal is a key component because of its low-cost, availability, and abundant supply within the nation`s borders.

  9. ENCOAL Mild Coal Gasification Project. Annual report, October 1990--September 1991

    SciTech Connect (OSTI)

    Not Available

    1992-02-01T23:59:59.000Z

    ENCOAL Corporation, a wholly-owned subsidiary of Shell Mining Company, is constructing a mild gasification demonstration plant at Triton Coal Company`s Buckskin Mine near Gillette, Wyoming. The process, using Liquids From Coal (LFC) technology developed by Shell and SGI International, utilizes low-sulfur Powder River Basin Coal to produce two new fuels, Process Derived Fuel (PDF) and Coal Derived Liquids (CDL). The products, as alternative fuels sources, are expected to significantly reduce current sulfur emissions at industrial and utility boiler sites throughout the nation, thereby reducing pollutants causing acid rain.

  10. Lawrence Livermore National Laboratory Working Reference Material Production Pla

    SciTech Connect (OSTI)

    Amy Wong; Denise Thronas; Robert Marshall

    1998-11-04T23:59:59.000Z

    This Lawrence Livermore National Laboratory (LLNL) Working Reference Material Production Plan was written for LLNL by the Los Alamos National Laboratory to address key elements of producing seven Pu-diatomaceous earth NDA Working Reference Materials (WRMS). These WRMS contain low burnup Pu ranging in mass from 0.1 grams to 68 grams. The composite Pu mass of the seven WRMS was designed to approximate the maximum TRU allowable loading of 200 grams Pu. This document serves two purposes: first, it defines all the operations required to meet the LLNL Statement of Work quality objectives, and second, it provides a record of the production and certification of the WRMS. Guidance provided in ASTM Standard Guide C1128-89 was used to ensure that this Plan addressed all the required elements for producing and certifying Working Reference Materials. The Production Plan was written to provide a general description of the processes, steps, files, quality control, and certification measures that were taken to produce the WRMS. The Plan identifies the files where detailed procedures, data, quality control, and certification documentation and forms are retained. The Production Plan is organized into three parts: a) an initial section describing the preparation and characterization of the Pu02 and diatomaceous earth materials, b) middle sections describing the loading, encapsulation, and measurement on the encapsulated WRMS, and c) final sections describing the calculations of the Pu, Am, and alpha activity for the WRMS and the uncertainties associated with these quantities.

  11. Integrated production/use of ultra low-ash coal, premium liquids and clean char. Interim final technical report, 1 September, 1992--31 August, 1993

    SciTech Connect (OSTI)

    Kruse, C.W.; Carlson, S.L. [Illinois State Geological Survey, Champaign, IL (United States); Fatemi, M. [Amoco Research Center, Naperville, IL (United States); Snoeyink, V.L.; Feizoulof, C.A. [Univ. of Illinois, Urbana, IL (United States); Klavetter, E. [Sandia National Labs., Albuquerque, NM (United States)

    1993-12-31T23:59:59.000Z

    The ultimate objective of this project is to attain high-value, coal-derived products, especially varieties of char, from Illinois coal. The chars (carbons) made in this study, because of their special properties, could become the marketable materials having the highest value in the product set. Tests this quarter followed up on an unexpected correlation of surface properties of a variety of oxidized carbons with adsorption phenomena. Additional oxidized carbons were made at the ISGS and tests to establish the reproducibility of results were begun. Work will be continued through December on a no-cost extension.

  12. SUBTASK 3.11 – PRODUCTION OF CBTL-BASED JET FUELS FROM BIOMASS-BASED FEEDSTOCKS AND MONTANA COAL

    SciTech Connect (OSTI)

    Sharma, Ramesh

    2014-06-01T23:59:59.000Z

    The Energy & Environmental Research Center (EERC), in partnership with the U.S. Department of Energy (DOE) and Accelergy Corporation, an advanced fuels developer with technologies exclusively licensed from Exxon Mobil, undertook Subtask 3.11 to use a recently installed bench-scale direct coal liquefaction (DCL) system capable of converting 45 pounds/hour of pulverized, dried coal to a liquid suitable for upgrading to fuels and/or chemicals. The process involves liquefaction of Rosebud mine coal (Montana coal) coupled with an upgrading scheme to produce a naphthenic fuel. The upgrading comprises catalytic hydrotreating and saturation to produce naphthenic fuel. A synthetic jet fuel was prepared by blending equal volumes of naphthenic fuel with similar aliphatic fuel derived from biomass and 11 volume % of aromatic hydrocarbons. The synthetic fuel was tested using standard ASTM International techniques to determine compliance with JP-8 fuel. The composite fuel thus produced not only meets but exceeds the military aviation fuel-screening criteria. A 500-milliliter synthetic jet fuel sample which met internal screening criteria was submitted to the Air Force Research Laboratory (AFRL) at Wright–Patterson Air Force Base, Dayton, Ohio, for evaluation. The sample was confirmed by AFRL to be in compliance with U.S. Air Force-prescribed alternative aviation fuel initial screening criteria. The results show that this fuel meets or exceeds the key specification parameters for JP-8, a petroleum-based jet fuel widely used by the U.S. military. JP-8 specifications include parameters such as freeze point, density, flash point, and others; all of which were met by the EERC fuel sample. The fuel also exceeds the thermal stability specification of JP-8 fuel as determined by the quartz crystalline microbalance (QCM) test also performed at an independent laboratory as well as AFRL. This means that the EERC fuel looks and acts identically to petroleum-derived jet fuel and can be used interchangeably without any special requirements and thus provides a pathway to energy security to the U.S. military and the entire nation. This subtask was funded through the EERC–DOE Joint Program on Research and Development for Fossil Energy-Related Resources Cooperative Agreement No. DE-FC26- 08NT43291. Nonfederal funding was provided by Accelergy Corporation.

  13. Development of a Hydrogasification Process for Co-Production of Substitute Natural Gas (SNG) and Electric Power from Western Coals

    SciTech Connect (OSTI)

    Sun, Xiaolei; Rink, Nancy

    2011-04-30T23:59:59.000Z

    This report presents the results of the research and development conducted on an Advanced Hydrogasification Process (AHP) conceived and developed by Arizona Public Service Company (APS) under U.S. Department of Energy (DOE) contract: DE-FC26-06NT42759 for Substitute Natural Gas (SNG) production from western coal. A double-wall (i.e., a hydrogasification contained within a pressure shell) down-flow hydrogasification reactor was designed, engineered, constructed, commissioned and operated by APS, Phoenix, AZ. The reactor is ASME-certified under Section VIII with a rating of 1150 pounds per square inch gage (psig) maximum allowable working pressure at 1950 degrees Fahrenheit ({degrees}F). The reaction zone had a 1.75 inch inner diameter and 13 feet length. The initial testing of a sub-bituminous coal demonstrated ~ 50% carbon conversion and ~10% methane yield in the product gas under 1625{degrees}F, 1000 psig pressure, with a 11 seconds (s) residence time, and 0.4 hydrogen-to-coal mass ratio. Liquid by-products mainly contained Benzene, Toluene, Xylene (BTX) and tar. Char collected from the bottom of the reactor had 9000-British thermal units per pound (Btu/lb) heating value. A three-dimensional (3D) computational fluid dynamic model simulation of the hydrodynamics around the reactor head was utilized to design the nozzles for injecting the hydrogen into the gasifier to optimize gas-solid mixing to achieve improved carbon conversion. The report also presents the evaluation of using algae for carbon dioxide (CO{sub 2}) management and biofuel production. Nannochloropsis, Selenastrum and Scenedesmus were determined to be the best algae strains for the project purpose and were studied in an outdoor system which included a 6-meter (6M) radius cultivator with a total surface area of 113 square meters (m{sup 2}) and a total culture volume between 10,000 to 15,000 liters (L); a CO{sub 2} on-demand feeding system; an on-line data collection system for temperature, pH, Photosynthetically Activate Radiation (PAR) and dissolved oxygen (DO); and a ~2 gallons per minute (gpm) algae culture dewatering system. Among the three algae strains, Scenedesmus showed the most tolerance to temperature and irradiance conditions in Phoenix and the best self-settling characteristics. Experimental findings and operational strategies determined through these tests guided the operation of the algae cultivation system for the scale-up study. Effect of power plant flue gas, especially heavy metals, on algae growth and biomass adsorption were evaluated as well.

  14. Large-block experiments in underground coal gasification

    SciTech Connect (OSTI)

    Not Available

    1982-11-01T23:59:59.000Z

    A major objective of the nation's energy program is to develop processes for cleanly producing fuels from coal. One of the more promising of these is underground coal gasification (UCG). If successful, UCG would quadruple recoverable U.S. coal reserves. Under the sponsorship of the Department of Energy (DOE), Lawrence Livermore National Laboratory (LLNL) performed an early series of UCG field experiments from 1976 through 1979. The Hoe Creek series of tests were designed to develop the basic technology of UCG at low cost. The experiments were conducted in a 7.6-m thick subbituminous coal seam at a relatively shallow depth of 48 m at a site near Gillette, Wyoming. On the basis of the Hoe Creek results, more extensive field experiments were designed to establish the feasibility of UCG for commercial gas production under a variety of gasification conditions. Concepts and practices in UCG are described, and results of the field tests are summarized.

  15. NETL: Coal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItemResearch > The EnergyCenterDioxide CaptureSee the Foundry'sMcGuireNETLCareersCoal

  16. Production of low sulfur binder pitich from high-sulfur Illinois coals. Quarterly report, 1 March 1995--31 May 1995

    SciTech Connect (OSTI)

    Knight, R.A.

    1995-12-31T23:59:59.000Z

    The objective of this project is to produce electrode binder pitch with sulfur content below 0.6 wt% from high-sulfur Illinois coal mild gasification liquids. Previously, flash thermocracking (FTC) was used to successfully upgrade the properties of mild gasification pitch, yielding a suitable blending stock for use as a binder in the production of carbon electrodes for the aluminum industry. However, in pitches from high-sulfur (4%) Illinois coal, the pitch sulfur content (2%) was still higher than preferred. In this project two approaches to sulfur reduction are being explored in conjunction with FTC: (1) the use of a moderate-sulfur (1.2%) Illinois coal as mild gasification feedstock, and (2) direct biodesulfurization of the liquids from high-sulfur coal prior to FTC. In Case 1, the liquids are being produced by mild gasification of IBC-109 coal in a bench-scale fluidized-bed reactor, followed by distillation to isolate the crude pitch. In Case 2, biodesulfurization with Rhodococcus Rhodochrous IGTS8 biocatalyst is being performed on crude pitch obtained from Illinois No. 6 coal tests conducted in the IGT MILDGAS PRU in 1990. Following preparation of the crude pitches, pitch upgrading experiments are being conducted in a continuous FTC reactor constructed in previous ICCI-sponsored studies. This quarter, mild gasification of IBC-109 coal was completed, producing 450 g of coal liquids, which were then distilled to recover 329 g of Case 1 crude pitch. Next month, the pitch will be subjected to FTC treatment and evaluated. Biodesulfurization experiments were performed on Case 2 pitch dispersed in l-undecanol, resulting in sulfur reductions of 15.1 to 21.4%. This was marginally lower than the 24.8% desulfurization obtained in l-dodecanol, but separation of pitch from the dispersant was facilitated by the greater volatility of l-undecanol.

  17. Methods for the speciation and determination of arsenic and selenium in coal combustion products

    SciTech Connect (OSTI)

    Schabron, J.F.; Hart, B.K.; Niss, N.D.; Brown, T.H.

    1991-11-01T23:59:59.000Z

    Methods of sample preparation for the determination of total selenium, and selenite, selenate, arsenite, and arsenate in coal fly ash materials were evaluated. The measurement methods use atomic spectroscopy for the determination of total concentrations and ion chromatography (IC) for the determination of individual ionic species. Sample preparation procedures which minimize the loss or alteration of the species of interest was explored and defined. The utility of the sample preparation methods can be sample dependent, so caution is advised in their use. IC conditions were established for the determination in extract solutions of selenite, selenate, arsenite, and arsenate with minimal interference from common anions.

  18. Further investigation of the impact of the co-combustion of tire-derived fuel and petroleum coke on the petrology and chemistry of coal combustion products

    SciTech Connect (OSTI)

    Hower, J.C.; Robertson, J.D.; Elswick, E.R.; Roberts, J.M.; Brandsteder, K.; Trimble, A.S.; Mardon, S.M. [University of Kentucky, Lexington, KY (United States). Center for Applied Energy Research

    2007-07-01T23:59:59.000Z

    A Kentucky cyclone-fired unit burns coal and tire-derived fuel, sometimes in combination with petroleum coke. A parallel pulverized combustion (pc) unit at the same plant burns the same coal, without the added fuels. The petrology, chemistry, and sulfur isotope distribution in the fuel and resulting combustion products was investigated for several configurations of the fuel blend. Zinc and Cd in the combustion products are primarily contributed from the tire-derived fuel, the V and Ni are primarily from the petroleum coke, and the As and Hg are probably largely from the coal. The sulfur isotope distribution in the cyclone unit is complicated due to the varying fuel sources. The electrostatic precipitator (ESP) array in the pc unit shows a subtle trend towards heavier S isotopic ratios in the cooler end of the ESP.

  19. Production of carbon molecular sieves from Illinois coal; [Quarterly] technical report, September 1, 1993--November 30, 1993

    SciTech Connect (OSTI)

    Lizzio, A.A.; Rostam-Abadi, M. [Illinois State Geological Survey, Champaign, IL (United States); Vyas, S.N. [Indian Institute of Technology, Bombay (India)

    1994-03-01T23:59:59.000Z

    Carbon molecular sieves (CMS) have become an increasingly important class of adsorbents for use in gas separation and recovery processes. The overall objective of this project is to determine whether Illinois Basin coal is a suitable feedstock for the production of CMS and to evaluate the potential application of these products in commercial gas separation processes. In Phase I of this project, gram quantities of char were produced from IBC-102 coal in a fixed-bed reactor under a wide range of pyrolysis and activation conditions. Chars having surface areas. of 1500--2100 m{sup 2}/g were produced by chemical activation using potassium hydroxide as the activant. These high surface area chars had more than twice the adsorption capacity of commercial molecular sieves. The kinetics of adsorption of various gases, i.e., O{sub 2}, N{sub 2}, CO{sub 2}, CH{sub 4} and H{sub 2} on these chars at 25{degree}C was studied. Several chars showed good potential for efficient O{sub 2}/N{sub 2}, CO{sub 2}/CH{sub 4}, CO{sub 2}/H{sub 2} and CH{sub 4}/H{sub 2} separation; both high adsorption capacities and selectivities were achieved. The full potential of these materials in commercial gas separations has yet to be realized. In Phase II, the optimal preparation conditions determined in Phase I will be applied to production of larger quantities of CMS in a batch fluidized-bed reactor (FBR) and continuous rotary tube kiln (RTK).

  20. Neutron generator production mission in a national laboratory.

    SciTech Connect (OSTI)

    Pope, Larry E.

    2007-08-01T23:59:59.000Z

    In the late 1980's the Department of Energy (DOE) faced a future budget shortfall. By the spring of 1991, the DOE had decided to manage this problem by closing three production plants and moving production capabilities to other existing DOE sites. As part of these closings, the mission assignment for fabrication of War Reserve (WR) neutron generators (NGs) was transferred from the Pinellas Plant (PP) in Florida to Sandia National Laboratories, New Mexico (SNL/NM). The DOE directive called for the last WR NG to be fabricated at the PP before the end of September 1994 and the first WR NG to be in bonded stores at SNL/NM by October 1999. Sandia National Laboratories successfully managed three significant changes to project scope and schedule and completed their portion of the Reconfiguration Project on time and within budget. The PP was closed in October 1995. War Reserve NGs produced at SNL/NM were in bonded stores by October 1999. The costs of the move were recovered in just less than five years of NG production at SNL/NM, and the annual savings today (in 1995 dollars) is $47 million.

  1. Effect of coal and coke qualities on blast furnace injection and productivity at Taranto

    SciTech Connect (OSTI)

    Salvatore, E.; Calcagni, M. [ILVA, Taranto (Italy); Eichinger, F.; Rafi, M.

    1995-12-01T23:59:59.000Z

    Injection rates at Taranto blast furnaces Nos. 2 and 4, for more than 16 months, was maintained above 175 kg/thm. Monthly average injection rate for two months stabilized above 190 kg/thm. This performance was possible due to the very high combined availabilities of Taranto blast furnaces and the KST injection system. Based upon this experience the quantitative relationships between coke/coal and blast furnace operational parameters were studied and are shown graphically. During this period due to coke quality changes, injection rate had to be reduced. The effect of using coke breeze in coke/ferrous charge as well as coal blend was also evaluated. Permeability of the furnace was found to be directly affected by O{sub 2} enrichment level, while at a high PCI rate no correlation between actual change in coke quality and permeability could be established. The future of PCI technology lies in better understanding of relationships between material specifications and blast furnace parameters of which permeability is of prime importance.

  2. National Microalgae Biofuel Production Potential and Resource Demand

    SciTech Connect (OSTI)

    Wigmosta, Mark S.; Coleman, Andre M.; Skaggs, Richard; Huesemann, Michael H.; Lane, Leonard J.

    2011-04-14T23:59:59.000Z

    Microalgae continue to receive global attention as a potential sustainable "energy crop" for biofuel production. An important step to realizing the potential of algae is quantifying the demands commercial-scale algal biofuel production will place on water and land resources. We present a high-resolution national resource and oil production assessment that brings to bear fundamental research questions of where open pond microalgae production can occur, how much land and water resource is required, and how much energy is produced. Our study suggests under current technology microalgae have the potential to generate 220 billion liters/year of oil, equivalent to 48% of current U.S. petroleum imports for transportation fuels. However, this level of production would require 5.5% of the land area in the conterminous U.S., and nearly three times the volume of water currently used for irrigated agriculture, averaging 1,421 L water per L of oil. Optimizing the selection of locations for microalgae production based on water use efficiency can greatly reduce total water demand. For example, focusing on locations along the Gulf Coast, Southeastern Seaboard, and areas adjacent to the Great Lakes, shows a 75% reduction in water demand to 350 L per L of oil produced with a 67% reduction in land use. These optimized locations have the potential to generate an oil volume equivalent to 17% of imports for transportation fuels, equal to the Energy Independence and Security Act year 2022 "advanced biofuels" production target, and utilizing some 25% of the current irrigation consumptive water demand for the U. S. These results suggest that, with proper planning, adequate land and water are available to meet a significant portion of the U.S. renewable fuel goals.

  3. All Composite Data Products: National FCEV Learning Demonstration With Updates Through October 5, 2011

    SciTech Connect (OSTI)

    Wipke, K.; Sprik, S.; Kurtz, J.; Ramsden, T.; Ainscough, C.; Saur, G.

    2011-11-01T23:59:59.000Z

    This technical presentation describes all composite data products: national FCEV learning demonstration with updates through October 5, 2011

  4. Coal-oil slurry preparation

    DOE Patents [OSTI]

    Tao, John C. (Perkiomenville, PA)

    1983-01-01T23:59:59.000Z

    A pumpable slurry of pulverized coal in a coal-derived hydrocarbon oil carrier which slurry is useful as a low-ash, low-sulfur clean fuel, is produced from a high sulfur-containing coal. The initial pulverized coal is separated by gravity differentiation into (1) a high density refuse fraction containing the major portion of non-coal mineral products and sulfur, (2) a lowest density fraction of low sulfur content and (3) a middlings fraction of intermediate sulfur and ash content. The refuse fraction (1) is gasified by partial combustion producing a crude gas product from which a hydrogen stream is separated for use in hydrogenative liquefaction of the middlings fraction (3). The lowest density fraction (2) is mixed with the liquefied coal product to provide the desired fuel slurry. Preferably there is also separately recovered from the coal liquefaction LPG and pipeline gas.

  5. High conversion of coal to transportation fuels for the future with low HC gas production. Progress report No. 14, January 1--March 31, 1996

    SciTech Connect (OSTI)

    Wiser, W.H.; Oblad, A.G.

    1996-04-01T23:59:59.000Z

    The objective of this project is to produce a synthetic crude from coal at a cost lower than $30.00 per barrel (Task A). A second objective, reflecting a recent change in direction in the synthetic fuels effort of DOE, is to produce a fuel which is low in aromatics, yet of sufficiently high octane number for use in the gasoline- burning transportation vehicles of today. To meet this second objective, research was proposed, and funding awarded, for conversion of the highly-aromatic liquid product from coal conversion to a product high in isoparaffins, which compounds in the gasoline range exhibit a high octane number (Task B). Experimental coal liquefaction studies conducted in a batch microreactor in our laboratory have demonstrated potential for high conversions of coal to liquids with low yields of hydrocarbon (HC) gases, hence small consumption of hydrogen in the primary liquefaction step. Ratios of liquids/HC gases as high as 30/1, at liquid yields as high as 82% of the coal by weight, have been achieved. The principal objective of this work is to examine how nearly we may approach these results in a continuous- flow system, at a size sufficient to evaluate the process concept for production of transportation fuels from coal. A continuous system has been constructed and operated, with a one-half inch inside diameter (ID) tube as the reaction vessel. As the work in this project proceeded toward its conclusion, an unexpected benefit was discovered. As the residence times were decreased to values of 10 seconds or less, ratios of liquids/HC gases of 20/1 or higher were achieved. But very importantly, it was discovered that the chemical reactions which produce the primary liquids can be carried to high conversions at pressures much lower than reported, and indeed required, in the processes at longer times.

  6. Nel (2004), “Clean Coal Conversion Options using Fischer-Tropsch

    E-Print Network [OSTI]

    Andre ? P. Steynberg; Herman G. Nel

    facilities producing these products individually. There may be good strategic reasons to use clean coal

  7. Effects of stress-dependent permeability on methane production from deep coal seams

    SciTech Connect (OSTI)

    McKee, C.R.; Bell, G.J.; Bumb, A.C.

    1984-05-01T23:59:59.000Z

    Methane resources are frequently associated with deeply buried coal seams which are also saturated with water; therefore, knowledge of their hydrologic properties is essential. As the formation pressure is lowered during dewatering, permeability may decline by one to two orders of magnitude. Theoretical relationships have been developed which fit laboratory data well for porosity and permeability as a function of effective stress. It was discovered that for practical purposes permeability is a function only of effective stress and the ratio of initial fracture porosity to matrix compressibility (fracture closure pressure). An approximate analytical solution for well testing has been obtained using the model developed. A new method for pump test analysis is then proposed.

  8. Coal | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onYouTube YouTube Note: Since the YouTube platformBuildingCoal Combustion Products Coal Combustion ProductsCoal to

  9. Coal liquefaction process

    DOE Patents [OSTI]

    Skinner, Ronald W. (Allentown, PA); Tao, John C. (Perkiomenville, PA); Znaimer, Samuel (Vancouver, CA)

    1985-01-01T23:59:59.000Z

    This invention relates to an improved process for the production of liquid carbonaceous fuels and solvents from carbonaceous solid fuels, especially coal. The claimed improved process includes the hydrocracking of the light SRC mixed with a suitable hydrocracker solvent. The recycle of the resulting hydrocracked product, after separation and distillation, is used to produce a solvent for the hydrocracking of the light solvent refined coal.

  10. Technical support for the Ohio Clean Coal Technology Program. Volume 2, Baseline of knowledge concerning process modification opportunities, research needs, by-product market potential, and regulatory requirements: Final report

    SciTech Connect (OSTI)

    Olfenbuttel, R.; Clark, S.; Helper, E.; Hinchee, R.; Kuntz, C.; Means, J.; Oxley, J.; Paisley, M.; Rogers, C.; Sheppard, W.; Smolak, L. [Battelle, Columbus, OH (United States)

    1989-08-28T23:59:59.000Z

    This report was prepared for the Ohio Coal Development Office (OCDO) under Grant Agreement No. CDO/R-88-LR1 and comprises two volumes. Volume 1 presents data on the chemical, physical, and leaching characteristics of by-products from a wide variety of clean coal combustion processes. Volume 2 consists of a discussion of (a) process modification waste minimization opportunities and stabilization considerations; (b) research and development needs and issues relating to clean coal combustion technologies and by-products; (c) the market potential for reusing or recycling by-product materials; and (d) regulatory considerations relating to by-product disposal or reuse.

  11. Low-rank coal research

    SciTech Connect (OSTI)

    Weber, G. F.; Laudal, D. L.

    1989-01-01T23:59:59.000Z

    This work is a compilation of reports on ongoing research at the University of North Dakota. Topics include: Control Technology and Coal Preparation Research (SO{sub x}/NO{sub x} control, waste management), Advanced Research and Technology Development (turbine combustion phenomena, combustion inorganic transformation, coal/char reactivity, liquefaction reactivity of low-rank coals, gasification ash and slag characterization, fine particulate emissions), Combustion Research (fluidized bed combustion, beneficiation of low-rank coals, combustion characterization of low-rank coal fuels, diesel utilization of low-rank coals), Liquefaction Research (low-rank coal direct liquefaction), and Gasification Research (hydrogen production from low-rank coals, advanced wastewater treatment, mild gasification, color and residual COD removal from Synfuel wastewaters, Great Plains Gasification Plant, gasifier optimization).

  12. Coal resources of Kyrgyzstan

    SciTech Connect (OSTI)

    Landis, E.R.; Bostick, N.H.; Gluskoter, H.J.; Johnson, E.A. [Geological Survey, Denver, CO (United States); Harrison, C.D. [CQ Inc., Homer City, PA (United States); Huber, D.W.

    1995-12-31T23:59:59.000Z

    The rugged, mountainous country of Kyrgyzstan contains about one-half of the known coal resources of central Asia (a geographic and economic region that also includes Uzbekistan, Tadjikistan and Turkmenistan). Coal of Jurassic age is present in eight regions in Kyrgyzstan in at least 64 different named localities. Significant coal occurrences of about the same age are present in the central Asian countries of Kazakhstan, China, and Russia. Separation of the coal-bearing rocks into individual deposits results more than earth movements before and during formation of the present-day mountains and basins of the country than from deposition in separate basins.Separation was further abetted by deep erosion and removal of the coal-bearing rocks from many areas, followed by covering of the remaining coal-bearing rocks by sands and gravels of Cenozoic age. The total resources of coal in Kyrgyzstan have been reported as about 30 billion tons. In some of the reported localities, the coal resources are known and adequately explored. In other parts of the republic, the coal resources are inadequately understood or largely unexplored. The resource and reserve inventory of Kyrgyzstan is at best incomplete; for some purposes, such as short-term local and long-range national planning, it may be inadequate. Less than 8% of the total estimated resources are categorized as recoverable reserves, and the amount that is economically recoverable is unknown. The coal is largely of subbituminous and high-volatile C bituminous rank, most has low and medium ash and sulfur contents, and coals of higher rank (some with coking qualities) are present in one region. It is recommended that appropriate analyses and tests be made during planning for utilization.

  13. After record sales and production, international met markets plummet

    SciTech Connect (OSTI)

    Buchsbaum, L.

    2009-03-15T23:59:59.000Z

    After surging in 2007 and most of 2008, both the demand and the pricing for coal collapsed in 2008's final quarter. The article discusses last year's market and gives some predictions on 2009's production and prices. The National Mining Association predicts that production of coking coal will fall 11% due to plunging demand for steel. 4 photos.

  14. Production of low-sulfur binder pitch from high-sulfur Illinois coals. Technical report, December 1, 1994--February 28, 1995

    SciTech Connect (OSTI)

    Knight, R.A.

    1996-03-01T23:59:59.000Z

    The objective of this project is to produce electrode binder pitch with sulfur content below 0.6 wt% from high-sulfur Illinois coal mild gasification liquids. In previous ICCI projects at IGT, flash thermocracking (FTC) was used to successfully upgrade the properties of mild gasification pitch, yielding a suitable blending stock for use as a binder in the production of carbon electrodes for the aluminum industry. However, in pitches from high-sulfur (4%) Illinois coal, the pitch sulfur content is still unacceptably high at 2%. In this project, two approaches to sulfur reduction are being explored in conjunction with FTC: (1) the use of conventionally cleaned coal with low ({approximately}1%) sulfur as a mild gasification feedstock, and (2) direct biodesulfurization of the liquids prior to FTC. In Case 1, the crude pitch is being produced by mild gasification of IBC-109 coal in an existing IGT bench-scale reactor, followed by distillation to isolate the crude pitch. In Case 2, the crude pitch for biodesulfurization was obtained from Illinois No. 6 coal tests conducted in the IGT mild gasification PRU in 1990. Biodesulfurization is to be performed by contacting the pitch with Rhodococcus Rhodochrous IGTS8 biocatalyst. Following preparation of the crude pitches, pitch upgrading experiments are to be conducted in a continuous FTC reactor constructed in previous ICCI-sponsored studies. The finished pitch is then characterized for physical and chemical properties (density, softening point, QI, TI, coking value, and elemental composition), and compared to typical specifications for binder pitches.

  15. Quality Guidelines for Energy System Studies: Detailed Coal Specificat...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Baseline for Fossil Energy Plants, Volume 1: Bituminous Coal and Natural Gas to Electricity, Revision 2 CO2 Capture Ready Coal Power Plants Assessment of Hydrogen Production...

  16. appalachian coal mining: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mines Using Coal Combustion By-Products Engineering Websites Summary: subject headings: Remedial action; Acid mine water; Mines; Coals; Recycling; Maryland; Fly ashRemediation of...

  17. abandoned coal mines: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Coal Combustion By-Products Engineering Websites Summary: subject headings: Remedial action; Acid mine water; Mines; Coals; Recycling; Maryland; Fly ashRemediation of...

  18. australian coal mining: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Coal Combustion By-Products Engineering Websites Summary: subject headings: Remedial action; Acid mine water; Mines; Coals; Recycling; Maryland; Fly ashRemediation of...

  19. african coal mining: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Coal Combustion By-Products Engineering Websites Summary: subject headings: Remedial action; Acid mine water; Mines; Coals; Recycling; Maryland; Fly ashRemediation of...

  20. Assessment of underground coal gasification in bituminous coals. Volume I. Executive summary. Final report

    SciTech Connect (OSTI)

    None

    1981-01-01T23:59:59.000Z

    This report describes the bituminous coal resources of the United States, identifies those resources which are potentially amenable to Underground Coal Gasification (UCG), identifies products and markets in the vicinity of selected target areas, identifies UCG concepts, describes the state of the art of UCG in bituminous coal, and presents three R and D programs for development of the technology to the point of commercial viability. Of the 670 billion tons of bituminous coal remaining in-place as identified by the National Coal Data System, 32.2 billion tons or 4.8% of the total are potentially amenable to UCG technology. The identified amenable resource was located in ten states: Alabama, Colorado, Illinois, Kentucky, New Mexico, Ohio, Oklahoma, Utah, Virginia, and West Virginia. The principal criteria which eliminated 87.3% of the resource was the minimum thickness (42 inches). Three R and D programs were developed using three different concepts at two different sites. Open Borehole, Hydraulic Fracture, and Electrolinking concepts were developed. The total program costs for each concept were not significantly different. The study concludes that much of the historical information based on UCG in bituminous coals is not usable due to the poor siting of the early field tests and a lack of adequate diagnostic equipment. This information gap requires that much of the early work be redone in view of the much improved understanding of the role of geology and hydrology in the process and the recent development of analytical tools and methods.

  1. Iron catalyzed coal liquefaction process

    DOE Patents [OSTI]

    Garg, Diwakar (Macungie, PA); Givens, Edwin N. (Bethlehem, PA)

    1983-01-01T23:59:59.000Z

    A process is described for the solvent refining of coal into a gas product, a liquid product and a normally solid dissolved product. Particulate coal and a unique co-catalyst system are suspended in a coal solvent and processed in a coal liquefaction reactor, preferably an ebullated bed reactor. The co-catalyst system comprises a combination of a stoichiometric excess of iron oxide and pyrite which reduce predominantly to active iron sulfide catalysts in the reaction zone. This catalyst system results in increased catalytic activity with attendant improved coal conversion and enhanced oil product distribution as well as reduced sulfide effluent. Iron oxide is used in a stoichiometric excess of that required to react with sulfur indigenous to the feed coal and that produced during reduction of the pyrite catalyst to iron sulfide.

  2. The economical production of alcohol fuels from coal-derived synthesis gas. Quarterly technical progress report No. 5, October 1, 1992--December 31, 1992

    SciTech Connect (OSTI)

    Not Available

    1993-01-01T23:59:59.000Z

    Two base case flow sheets have now been prepared. In the first, which was originally presented in TPR4, a Texaco gasifier is used. Natural gas is also burned in sufficient quantity to increase the hydrogen to carbon monoxide ratio of the synthesis gas to the required value of 1. 1 for alcohol synthesis. Acid gas clean up and sulfur removal are accomplished using the Rectisol process followed by the Claus and Beavon processes. About 10% of the synthesis gas is sent to a power generation unit in order to produce electric power, with the remaining 90% used for alcohol synthesis. For this process, the estimated installed cost is $474.2 mm. The estimated annual operating costs are $64.5 MM. At a price of alcohol fuels in the vicinity of $1. 00/gal, the pay back period for construction of this plant is about four years. The details of this case, called Base Case 1, are presented in Appendix 1. The second base case, called Base Case 2, also has a detailed description and explanation in Appendix 1. In Base Case 2, a Lurgi Gasifier is used. The motivation for using a Lurgi Gasifier is that it runs at a lower temperature and pressure and, therefore, produces by-products such as coal liquids which can be sold. Based upon the economics of joint production, discussed in Technical Progress Report 4, this is a necessity. Since synthesis gas from natural gas is always less expensive to produce than from coal, then alcohol fuels will always be less expensive to produce from natural gas than from coal. Therefore, the only way to make coal- derived alcohol fuels economically competitive is to decrease the cost of production of coal-derived synthesis gas. one method for accomplishing this is to sell the by-products from the gasification step. The details of this strategy are discussed in Appendix 3.

  3. An SAIC Report Prepared for The Indiana Center for Coal Technology

    E-Print Network [OSTI]

    Fernández-Juricic, Esteban

    ....................................................................................................................... 15 1.6.2 Implement advanced clean coal technologies for production of energy products ........ 15

  4. Coal as a conventional source of methane: A review and analysis of 50 wells in two production areas in the Black Warrior Basin of Alabama

    SciTech Connect (OSTI)

    Dunn, B.W.

    1984-05-01T23:59:59.000Z

    This paper presents a review of the actual production, sales, and economic data from two production areas with 52 wells developed by a joint coal industry'gas industry effort owned equally by Jim Walter Resources, Inc. (JWR), a subsidiary of Jim Walter Corporation of Tampa, Florida and Enhanced Energy Resources, Inc. (EER), a subsidiary of Kaneb Services, Inc. of Houston, Texas. The unique reservoir characteristics of the coal environment are described in brief, a comparison of actual methane production from coal with computer model predictions is presented, and the capital and operating costs are discussed with specific emphasis on the economic results. This information differs from similar previous work in that economic vitality is now apparent whereas previous inquiries were essentially restricted to the technical reservoir engineering characteristics and the physical capability of coal to desorb (produce) methane. There are a number of published papers on this important technical aspect several of which are references for this presentation. Production Area I (31 well production area) has been generating an operating profit for the past 21 months. Profits have increased substantially in the past year as a result of the completion of an 8'' transmission line and reduced operating costs. Initial production commenced in late 1979. A five well pilot project was evaluated for approximately two years before commercial development commenced in late 1981. A total of 31 wells were drilled by mid-1982. First sales commenced in February of 1982. Production Area II drilling commenced in January of 1983 with initial sales in March of 1983. The economic viability is demonstrated based on actual operating profits over the past twentyone months and current experience with respect to improvements in operational techniques and costs. These data are a

  5. Coal in China

    SciTech Connect (OSTI)

    Minchener, A.J. [IEA Clean Coal Centre, London (United Kingdom)

    2005-07-01T23:59:59.000Z

    The article gives an overview of the production and use of coal in China, for power generation and in other sectors. Coal use for power generation was 850 million tonnes in 2003 and 800 million tonnes in the non-power sector. The majority of power will continue to be produced from coal, with a trend towards new larger pulverised coal fired units and introduction of circulating fluidised bed combustors. Stricter regulations are forcing introduction of improved pollution control technologies. It seems likely that China will need international finance to supplement private and state investment to carry out a programme to develop and apply clean coal technologies. The author concludes that there is evidence of a market economy being established but there is a need to resolve inconsistencies with the planned aspects of the economy and that additional policies are needed in certain sectors to achieve sustainable development. 1 ref., 2 figs., 2 tabs.

  6. Proceedings, twenty-five annual international Pittsburgh coal conference

    SciTech Connect (OSTI)

    NONE

    2008-07-01T23:59:59.000Z

    The conference theme was 'coal - energy, environment and sustainable development'. The topics covered energy and environmental issues, and technologies related to coal and its byproducts. These included: gasification, hydrogen from coal, combustion technologies, coal production and preparation, synthesis of liquid fuels, gas turbines and fuel cells for synthesis gas and hydrogen applications, coal chemistry and geosciences, global climate change, underground coal gasification, environmental control technologies, and coal utilization byproducts.

  7. Isotope production potential at Sandia National Laboratories: Product, waste, packaging, and transportation

    SciTech Connect (OSTI)

    Trennel, A.J.

    1995-12-31T23:59:59.000Z

    The U.S. Congress directed the U.S. Department of Energy to establish a domestic source of molybdenum-99, an essential isotope used in nuclear medicine and radiopharmacology. An Environmental Impact Statement for production of {sup 99}Mo at one of four candidate sites is being prepared. As one of the candidate sites, Sandia National Laboratories is developing the Isotope Production Project. Using federally approved processes and procedures now owned by the U.S. Department of Energy, and existing facilities that would be modified to meet the production requirements, the Sandia National Laboratories` Isotope Project would manufacture up to 30 percent of the U.S. market, with the capacity to meet 100 percent of the domestic need if necessary. This paper provides a brief overview of the facility, equipment, and processes required to produce isotopes. Packaging and transportation issues affecting both product and waste are addressed, and the storage and disposal of the four low-level radioactive waste types generated by the production program are considered. Recommendations for future development are provided.

  8. Feasibility study of medical isotope production at Sandia National Laboratories

    SciTech Connect (OSTI)

    Massey, C.D.; Miller, D.L.; Carson, S.D. [Sandia National Labs., Albuquerque, NM (United States). Environmental Regulatory Assessment Dept.] [and others

    1995-12-01T23:59:59.000Z

    In late 1994, Sandia National Laboratories in Albuquerque, New Mexico, (SNL/NM), was instructed by the Department of Energy (DOE) Isotope Production and Distribution Program (IPDP) to examine the feasibility of producing medically useful radioisotopes using the Annular Core Research Reactor (ACRR) and the Hot Cell Facility (HCF). Los Alamos National Laboratory (LANL) would be expected to supply the targets to be irradiated in the ACRR. The intent of DOE would be to provide a capability to satisfy the North American health care system demand for {sup 99}Mo, the parent of {sup 99m}Tc, in the event of an interruption in the current Canadian supply. {sup 99m}Tc is used in 70 to 80% of all nuclear medicine procedures in the US. The goal of the SNL/NM study effort is to determine the physical plant capability, infrastructure, and staffing necessary to meet the North American need for {sup 99}Mo and to identify and examine all issues with potential for environmental impact.

  9. Energy, Environmental, and Economic Analyses of Design Concepts for the Co-Production of Fuels and Chemicals with Electricity via Co-Gasification of Coal and Biomass

    SciTech Connect (OSTI)

    Eric Larson; Robert Williams; Thomas Kreutz; Ilkka Hannula; Andrea Lanzini; Guangjian Liu

    2012-03-11T23:59:59.000Z

    The overall objective of this project was to quantify the energy, environmental, and economic performance of industrial facilities that would coproduce electricity and transportation fuels or chemicals from a mixture of coal and biomass via co-gasification in a single pressurized, oxygen-blown, entrained-flow gasifier, with capture and storage of CO{sub 2} (CCS). The work sought to identify plant designs with promising (Nth plant) economics, superior environmental footprints, and the potential to be deployed at scale as a means for simultaneously achieving enhanced energy security and deep reductions in U.S. GHG emissions in the coming decades. Designs included systems using primarily already-commercialized component technologies, which may have the potential for near-term deployment at scale, as well as systems incorporating some advanced technologies at various stages of R&D. All of the coproduction designs have the common attribute of producing some electricity and also of capturing CO{sub 2} for storage. For each of the co-product pairs detailed process mass and energy simulations (using Aspen Plus software) were developed for a set of alternative process configurations, on the basis of which lifecycle greenhouse gas emissions, Nth plant economic performance, and other characteristics were evaluated for each configuration. In developing each set of process configurations, focused attention was given to understanding the influence of biomass input fraction and electricity output fraction. Self-consistent evaluations were also carried out for gasification-based reference systems producing only electricity from coal, including integrated gasification combined cycle (IGCC) and integrated gasification solid-oxide fuel cell (IGFC) systems. The reason biomass is considered as a co-feed with coal in cases when gasoline or olefins are co-produced with electricity is to help reduce lifecycle greenhouse gas (GHG) emissions for these systems. Storing biomass-derived CO{sub 2} underground represents negative CO{sub 2} emissions if the biomass is grown sustainably (i.e., if one ton of new biomass growth replaces each ton consumed), and this offsets positive CO{sub 2} emissions associated with the coal used in these systems. Different coal:biomass input ratios will produce different net lifecycle greenhouse gas (GHG) emissions for these systems, which is the reason that attention in our analysis was given to the impact of the biomass input fraction. In the case of systems that produce only products with no carbon content, namely electricity, ammonia and hydrogen, only coal was considered as a feedstock because it is possible in theory to essentially fully decarbonize such products by capturing all of the coal-derived CO{sub 2} during the production process.

  10. Coal competition: prospects for the 1980s

    SciTech Connect (OSTI)

    Not Available

    1981-03-01T23:59:59.000Z

    This report consists of 10 chapters which present an historical overview of coal and the part it has played as an energy source in the economic growth of the United States from prior to World War II through 1978. Chapter titles are: definition of coals, coal mining; types of coal mines; mining methods; mining work force; development of coal; mine ownership; production; consumption; prices; exports; and imports. (DMC)

  11. advanced coal preparation: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... 15 1.6.2 Implement advanced clean coal technologies for production of energy products ... 15 An SAIC Report Prepared...

  12. The economical production of alcohol fuels from coal-derived synthesis gas. Quarterly technical progress report Number 8, 1 July, 1993--30 September, 1993

    SciTech Connect (OSTI)

    Not Available

    1993-10-01T23:59:59.000Z

    Task 1, the preparation of catalyst materials, is proceeding actively. At WVU, catalysts based on Mo are being prepared using a variety of approaches to alter the oxidation state and environment of the Mo. At UCC and P, copper-based zinc chromite spinel catalysts will be prepared and tested. The modeling of the alcohol-synthesis reaction in a membrane reactor is proceeding actively. Under standard conditions, pressure drop in the membrane reactor has been shown to be negligible. In Task 2, base case designs had previously been completed with a Texaco gasifier. Now, similar designs have been completed using the Shell gasifier. A comparison of the payback periods or production cost of these plants shows significant differences among the base cases. However, a natural gas only design, prepared for comparison purposes, gives a lower payback period or production cost. Since the alcohol synthesis portion of the above processes is the same, the best way to make coal-derived higher alcohols more attractive economically than natural gas-derived higher alcohols is by making coal-derived syngas less expensive than natural gas-derived syngas. The maximum economically feasible capacity for a higher alcohol plant from coal-derived syngas appears to be 32 MM bbl/yr. This is based on consideration of regional coal supply in the eastern US, coal transportation, and regional product demand. The benefits of economics of scale are illustrated for the base case designs. A value for higher alcohol blends has been determined by appropriate combination of RVP, octane number, and oxygen content, using MTBE as a reference. This analysis suggests that the high RVP of methanol in combination with its higher water solubility make higher alcohols more valuable than methanol.

  13. DRAFT ENVIRONMENTAL ASSESSMENT FOR THE NATIONAL CENTER FOR NATURAL PRODUCTS RESEARCH

    E-Print Network [OSTI]

    Tchumper, Gregory S.

    DRAFT ENVIRONMENTAL ASSESSMENT FOR THE NATIONAL CENTER FOR NATURAL PRODUCTS RESEARCH PHASE II BLANK #12;ENVIRONMENTAL ASSESSMENT FOR THE NATIONAL CENTER FOR NATURAL PRODUCTS RESEARCH PHASE II EXECUTIVE SUMMARY This Environmental Assessment (EA) has been prepared in accordance with the National

  14. Biological production of ethanol from coal. [Quarterly technical report], December 22, 1991--March 21, 1992

    SciTech Connect (OSTI)

    Not Available

    1992-07-01T23:59:59.000Z

    Research is continuing in an attempt to increase both the ethanol concentration and product ratio using C. ljungdahlii. The purpose of this report is to present data utilizing a medium prepared especially for C. ljungdahlii. Medium development studies are presented, as well as reactor studies with the new medium in batch reactors. CSTRs and CSTRs with cell recycle. The use of this new medium has resulted in significant improvements in cell concentration, ethanol concentration and product ratio.

  15. Coal pump

    DOE Patents [OSTI]

    Bonin, John H. (Sunnyvale, CA); Meyer, John W. (Palo Alto, CA); Daniel, Jr., Arnold D. (Alameda County, CA)

    1983-01-01T23:59:59.000Z

    A device for pressurizing pulverized coal and circulating a carrier gas is disclosed. This device has utility in a coal gasification process and eliminates the need for a separate collection hopper and eliminates the separate compressor.

  16. Coal liquefaction process

    DOE Patents [OSTI]

    Wright, C.H.

    1986-02-11T23:59:59.000Z

    A process is described for the liquefaction of coal wherein raw feed coal is dissolved in recycle solvent with a slurry containing recycle coal minerals in the presence of added hydrogen at elevated temperature and pressure. The highest boiling distillable dissolved liquid fraction is obtained from a vacuum distillation zone and is entirely recycled to extinction. Lower boiling distillable dissolved liquid is removed in vapor phase from the dissolver zone and passed without purification and essentially without reduction in pressure to a catalytic hydrogenation zone where it is converted to an essentially colorless liquid product boiling in the transportation fuel range. 1 fig.

  17. Coal liquefaction process

    DOE Patents [OSTI]

    Wright, Charles H. (Overland Park, KS)

    1986-01-01T23:59:59.000Z

    A process for the liquefaction of coal wherein raw feed coal is dissolved in recycle solvent with a slurry containing recycle coal minerals in the presence of added hydrogen at elevated temperature and pressure. The highest boiling distillable dissolved liquid fraction is obtained from a vacuum distillation zone and is entirely recycled to extinction. Lower boiling distillable dissolved liquid is removed in vapor phase from the dissolver zone and passed without purification and essentially without reduction in pressure to a catalytic hydrogenation zone where it is converted to an essentially colorless liquid product boiling in the transportation fuel range.

  18. Quarterly coal report

    SciTech Connect (OSTI)

    Young, P.

    1996-05-01T23:59:59.000Z

    The Quarterly Coal Report (QCR) provides comprehensive information about U.S. coal production, distribution, exports, imports, receipts, prices, consumption, and stocks to a wide audience, including Congress, Federal and State agencies, the coal industry, and the general public. Coke production, consumption, distribution, imports, and exports data are also provided. The data presented in the QCR are collected and published by the Energy Information Administration (EIA) to fulfill data collection and dissemination responsibilities as specified in the Federal Energy Administration Act of 1974 (Public Law 93-275), as amended. This report presents detailed quarterly data for October through December 1995 and aggregated quarterly historical data for 1987 through the third quarter of 1995. Appendix A displays, from 1987 on, detailed quarterly historical coal imports data, as specified in Section 202 of the Energy Policy and Conservation Amendments Act of 1985 (Public Law 99-58). Appendix B gives selected quarterly tables converted to metric tons.

  19. Biological production of ethanol from coal. Task 4 report, Continuous reactor studies

    SciTech Connect (OSTI)

    Not Available

    1992-10-01T23:59:59.000Z

    The production of ethanol from synthesis gas by the anaerobic bacterium C. ljungdahlii has been demonstrated in continuous stirred tank reactors (CSTRs), CSTRs with cell recycle and trickle bed reactors. Various liquid media were utilized in these studies including basal medium, basal media with 1/2 B-vitamins and no yeast extract and a medium specifically designed for the growth of C. ljungdahlii in the CSTR. Ethanol production was successful in each of the three reactor types, although trickle bed operation with C. ljungdahlii was not as good as with the stirred tank reactors. Operation in the CSTR with cell recycle was particularly promising, producing 47 g/L ethanol with only minor concentrations of the by-product acetate.

  20. Comparison of coal tars generated by pyrolysis of Hanna coal and UCG (underground coal gasification) Hanna IVB coal tars

    SciTech Connect (OSTI)

    Barbour, F.A.; Cummings, R.E.

    1986-04-01T23:59:59.000Z

    The compositions of coal tars produced by laboratory and pilot scale apparatus have been compared to those produced during underground coal gasification (UCG) experiments at Hanna, Wyoming. Four coal tars were generated by pyrolysis using the block reactor and the laboratory reference retort, and a fifth coal tar was composited from products produced by UCG. Coal tars were separated into chemically defined fractions and were characterized by gas chromatography. Specific compounds were not identified, but rather fingerprinting or compound-type profiling was used for identifying similarities and differences in the product tars. This permitted the evaluation of the different methods of tar production with respect to one another. The UCG coal tars appeared to have undergone more secondary cracking than the pyrolytic products. The coal tar products from the laboratory reference retort appear to be more indicative of the coal's chemical structure. Products from the block reactor contained lesser amounts of the lighter boiling material. In addition there is organic sulfur contamination as indicated by the large amount of sulfur present in the product tar from the block reactor. 11 refs., 16 figs., 11 tabs.

  1. Long-Term Demonstration of Hydrogen Production from Coal at Elevated

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cnHigh SchoolIn12electron 9 5Let usNucleartearingLong

  2. Abrasion and Erosion testing of Materials used in Power Production from Coal

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItem Not Found Item Not Found The itemAIR SEPARATION BYAbrasion and Erosion Testing of

  3. The production of methanol by the Brookhaven National Laboratory process

    SciTech Connect (OSTI)

    Miller, D.B.; Williams, J.J.; Johnson, A.R.

    1990-11-01T23:59:59.000Z

    The purpose of this study was to develop a capital cost estimate and methanol production costs for a new methanol process under development at the Brookhaven National Laboratory (BNL). The cost of fuel delivered to the US Gulf Coast is compared with fuel produced by a conventional methanol process and a liquefied natural gas (LNG) process. The new methanol process is made possible by the development of a new liquid phase catalyst. The new liquid catalyst system can convert synthesis gas almost completely to methanol in a SINGLE pass through the methanol synthesis reactor. This catalyst system reduces synthesis reaction temperatures from about 260{degree}C to about 100{degree}C, permitting isothermal synthesis conditions, in contrast to the temperature gradients in currently available pelleted, solid catalysts. Natural gas feedstock can be processed at pressures under 250 psia. Since nitrogen in the synthesis gas can be tolerated, the autothermal reforming step (combination of partial oxidation and steam reforming over a nickel catalyst) uses preheated air rather than oxygen. However, even with nitrogen present, the volume of gas fed to the reactor can still be smaller than the volume of gas that must be circulated in a conventional reactor, which operates with low conversions and requires high recycle volumes. The characteristics of the BNL system permits a major improvement in methanol plant design and economics. 11 figs., 15 tabs.

  4. Canada's coal industry: full swing ahead

    SciTech Connect (OSTI)

    Stone, K. [Natural Resources Canada (Canada). Minerals and Metals Sector

    2007-03-15T23:59:59.000Z

    The article presents facts and figures about Canada's coal industry in 2006 including production, exports, imports, mines in operation, the Genesee 3 coal-fired generation unit, the Dodds-Roundhill Gasification Project, and new coal mine development plans. The outlook for 2007 is positive, with coal production expected to increase from 67 Mt in 2006 to 70 Mt in 2007 and exports expected to increase from 28 Mt in 2006 to 30 Mt in 2007.

  5. National FCEV Learning Demonstration: All Composite Data Products...

    Broader source: Energy.gov (indexed) [DOE]

    Vehicle (FCEV) Learning Demonstration. 54021.pdf More Documents & Publications Controlled Hydrogen Fleet & Infrastructure Analysis National Hydrogen Learning Demonstration Status...

  6. Molybdenum-99 Isotope Production Preparation at Sandia National Laboratories

    SciTech Connect (OSTI)

    Carson, S.D.; Longley, S.W.; McDonald, M.J.; Parma, E.J.; Vernon, M.E.

    1998-10-07T23:59:59.000Z

    `Q&c M. J. McDonald, S. D. Carson, S. W. Longley, E. J. Parma, M. E. Vern `~ I@ .,., Sandia National Laboratories*, P. .0. Box 5800, Albuquerque, NM, 8 W? 1$ tl?;:q `f. (3 . 8 /'~ Abstract This report was prepared as an account of work sponsored byanagency of the United States Government. Neither the United States Government nor any agency thereof, nor any of their employees, make any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference herein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise does not necessarily constitute or imply its endorsement, recommendation, or favoring by the United States Government or any agency thereof. The views and opinions of authors expressed herein do not necessarily state or reflect those of the United States Government or any agency thereof. loading on the Cintichem targets. These tests were designed to gain process knowledge prior to processing an irradiated target. The chemical separation tests were performed in a fime hood During cold testing, several tests were performed on individual components of the process to complete, a series of `hot' tests was designed to process irradiated targets. These were designed to optimize the process, identify problems prior to processing higher inventory targets, and to the shielded containment box (SCB). Table 1 is a summary of the tests performed prior to the Test Target Power Post irradiation Total inventory 99M0 inventory (kW)/ Irradiation decay (hrs) (TBq*) /decay (TBq)/decay Time (hrs) inventory (TBq) inventory(TBq) in the processing boxes as color comparisons. Product quality control testing was conducted for all the tests and the results were compared to The production process generates a high activity acidic liquid waste. Several waste stabilization processing box. The cement, in addition to stabilizing the waste, neutralized the waste resulting The processing hardware and fixtures were developed in parallel to the cold tests and tested in a that expected during processing. During processing, precautions will be taken to minimize the Island incident. The facility consisted of shielded glove boxes, unshielded glove box lines and the the facility for production operations; the glove box lines and shielded glove boxes, all the new configuration will have six windows, four extraction boxes and a waste packaging box on the shielding. The walls and windows of the processing boxes will have the equivalent 150 of the purification box will be considerably less than the processing boxes with dose being from only `gMo. The increased wall thickness will reduce the dose levels to boxes will have under the box transport systems to move material into and out of the boxes. prior to FDA requiring process validation and, consequently, had not pertlormed a process

  7. Investigation of the carbon dioxide sorption capacity and structural deformation of coal

    SciTech Connect (OSTI)

    Hur, Tae-Bong; Fazio, James; Romanov, Vyacheslav; Harbert, William

    2010-01-01T23:59:59.000Z

    Due to increasing atmospheric CO2 concentrations causing the global energy and environmental crises, geological sequestration of carbon dioxide is now being actively considered as an attractive option to mitigate greenhouse gas emissions. One of the important strategies is to use deep unminable coal seams, for those generally contain significant quantities of coal bed methane that can be recovered by CO2 injection through enhanced coal bed natural gas production, as a method to safely store CO2. It has been well known that the adsorbing CO2 molecules introduce structural deformation, such as distortion, shrinkage, or swelling, of the adsorbent of coal organic matrix. The accurate investigations of CO2 sorption capacity as well as of adsorption behavior need to be performed under the conditions that coals deform. The U.S. Department of Energy-National Energy Technology Laboratory and Regional University Alliance are conducting carbon dioxide sorption isotherm experiments by using manometric analysis method for estimation of CO2 sorption capacity of various coal samples and are constructing a gravimetric apparatus which has a visual window cell. The gravimetric apparatus improves the accuracy of carbon dioxide sorption capacity and provides feasibility for the observation of structural deformation of coal sample while carbon dioxide molecules interact with coal organic matrix. The CO2 sorption isotherm measurements have been conducted for moist and dried samples of the Central Appalachian Basin (Russell County, VA) coal seam, received from the SECARB partnership, at the temperature of 55 C.

  8. BIMETALLIC NANOCATALYSTS IN MESOPOROUS SILICA FOR HYDROGEN PRODUCTION FROM COAL-DERIVED FUELS

    SciTech Connect (OSTI)

    Kuila, Debasish; Ilias, Shamsuddin

    2013-02-13T23:59:59.000Z

    In steam reforming reactions (SRRs) of alkanes and alcohols to produce H{sub 2}, noble metals such as platinum (Pt) and palladium (Pd) are extensively used as catalyst. These metals are expensive; so, to reduce noble-metal loading, bi-metallic nanocatalysts containing non-noble metals in MCM-41 (Mobil Composition of Material No. 41, a mesoporous material) as a support material with high-surface area were synthesized using one-pot hydrothermal procedure with a surfactant such as cetyltrimethylammonium bromide (CTAB) as a template. Bi-metallic nanocatalysts of Pd-Ni and Pd-Co with varying metal loadings in MCM-41 were characterized by x-ray diffraction (XRD), N{sub 2} adsorption, and Transmission electron microscopy (TEM) techniques. The BET surface area of MCM-41 (~1000 m{sup 2}/g) containing metal nanoparticles decreases with the increase in metal loading. The FTIR studies confirm strong interaction between Si-O-M (M = Pd, Ni, Co) units and successful inclusion of metal into the mesoporous silica matrix. The catalyst activities were examined in steam reforming of methanol (SRM) reactions to produce hydrogen. Reference tests using catalysts containing individual metals (Pd, Ni and Co) were also performed to investigate the effect of the bimetallic system on the catalytic behavior in the SRM reactions. The bimetallic system remarkably improves the hydrogen selectivity, methanol conversion and stability of the catalyst. The results are consistent with a synergistic behavior for the Pd-Ni-bimetallic system. The performance, durability and thermal stability of the Pd-Ni/MCM-41 and Pd-Co/MCM-41 suggest that these materials may be promising catalysts for hydrogen production from biofuels. A part of this work for synthesis and characterization of Pd-Ni-MCM-41 and its activity for SRM reactions has been published (“Development of Mesoporous Silica Encapsulated Pd-Ni Nanocatalyst for Hydrogen Production” in “Production and Purification of Ultraclean Transportation Fuels”; Hu, Y., et al.; ACS Symposium Series; American Chemical Society: Washington, DC, 2011.)

  9. Coal slurries: An environmental bonus

    SciTech Connect (OSTI)

    Basta, N.; Moore, S.; Ondrey, G.

    1994-05-01T23:59:59.000Z

    Developers and promoters of coal-water slurries and similar CWF (coal-water fuel) technologies have had a hard time winning converts since they unveiled their first commercial processes in the 1970s. The economic appeal of such processes, marginal at best, varies with the price of oil. Nevertheless, the technology is percolating, as geopolitics and environmental pressures drive new processes. Such fuels are becoming increasingly important to coal-rich, oil-poor nations such as China, as they attempt to build an onshore fuel supply. Meanwhile, improvements are changing the way coal-fired processes are viewed. Where air pollution regulations once discouraged the use of coal fuels, new coal processes have been developed that cut nitrous oxides (NOx) emissions and provide a use for coal fines, previously viewed as waste. The latest developments in the field were all on display at the 19th International Technical Conference on Coal Utilization and Fuel Systems, held in Clearwater, Fla., on March 21--24. At this annual meeting, sponsored by the Coal and Slurry Technology Association, (Washington, D.C.) and the Pittsburgh Energy Technology Center of the US Dept. of Energy (PETC), some 200 visitors from around the work gathered to discuss the latest developments in coal slurry utilization--new and improved processes, and onstream plants. This paper presents highlights from the conference.

  10. Pyrolysis of coal

    DOE Patents [OSTI]

    Babu, Suresh P. (Willow Springs, IL); Bair, Wilford G. (Morton Grove, IL)

    1992-01-01T23:59:59.000Z

    A method for mild gasification of crushed coal in a single vertical elongated reaction vessel providing a fluidized bed reaction zone, a freeboard reaction zone, and an entrained reaction zone within the single vessel. Feed coal and gas may be fed separately to each of these reaction zones to provide different reaction temperatures and conditions in each reaction zone. The reactor and process of this invention provides for the complete utilization of a coal supply for gasification including utilization of caking and non-caking or agglomerating feeds in the same reactor. The products may be adjusted to provide significantly greater product economic value, especially with respect to desired production of char having high surface area.

  11. Robust Low-Cost Water-Gas Shift Membrane Reactor for High-Purity Hydrogen Production form Coal-Derived Syngas

    SciTech Connect (OSTI)

    James Torkelson; Neng Ye; Zhijiang Li; Decio Coutinho; Mark Fokema

    2008-05-31T23:59:59.000Z

    This report details work performed in an effort to develop a low-cost, robust water gas shift membrane reactor to convert coal-derived syngas into high purity hydrogen. A sulfur- and halide-tolerant water gas shift catalyst and a sulfur-tolerant dense metallic hydrogen-permeable membrane were developed. The materials were integrated into a water gas shift membrane reactor in order to demonstrate the production of >99.97% pure hydrogen from a simulated coal-derived syngas stream containing 2000 ppm hydrogen sulfide. The objectives of the program were to (1) develop a contaminant-tolerant water gas shift catalyst that is able to achieve equilibrium carbon monoxide conversion at high space velocity and low steam to carbon monoxide ratio, (2) develop a contaminant-tolerant hydrogen-permeable membrane with a higher permeability than palladium, (3) demonstrate 1 L/h purified hydrogen production from coal-derived syngas in an integrated catalytic membrane reactor, and (4) conduct a cost analysis of the developed technology.

  12. [Basic properties of coals and other solids]. Eighth quarterly report, [September--November 1991

    SciTech Connect (OSTI)

    Not Available

    1991-11-25T23:59:59.000Z

    This report discusses basic properties of bituminous, subbituminous, and lignite coals. Properties of coal liquids are also investigated. Heats of immersion in strong acids are found for Pittsburgh {number_sign}8, Illinois {number_sign}6, and Wyodak coals. Production of coal liquids by distillation is discussed. Heats of titration of coal liquids and coal slurries are reported. (VC)

  13. Solidification/stabilization of toxic metal wastes using coke and coal combustion by-products

    SciTech Connect (OSTI)

    Vempati, R.K.; Mollah, M.Y.A.; Chinthala, A.K.; Cocke, D.L. [Lamar Univ., Beaumont, TX (United States)] [Lamar Univ., Beaumont, TX (United States); Beeghly, J.H. [Dravo Lime, Pittsburgh, PA (United States)] [Dravo Lime, Pittsburgh, PA (United States)

    1995-12-31T23:59:59.000Z

    A study has been conducted to evaluate the potential of a special rubber waste, NISCO Cyclone Ash (NCA), which contains substantial calcium oxide and calcium sulfites/sulfates for solidification/stabilization (S/S) of toxic metal wastes. The mineralogical compositions of the NCA and a class ``C`` fly ash have been characterized by X-ray diffraction (XRD). Hydrated mixtures of these wastes have been examined by XRD and found to form ettringite. Low concentrations of As (15 {micro}g ml{sup {minus}1}), Ba (500 {micro}g ml{sup {minus}1}), Pb (15 {micro}g ml{sup {minus}1}), and Zn (1,000 {micro}g ml{sup {minus}1}) were added to these hydrated mixtures and found to be successfully immobilized and solidified, as determined by the Toxicity Characteristic Leaching Procedure (TCLP). In addition, the mineralogy, chemistry and leaching characteristics of these combined waste products and their interactions with toxic metals are discussed.

  14. Review of China's Low-Carbon City Initiative and Developments in the Coal Industry

    E-Print Network [OSTI]

    Fridley, David

    2014-01-01T23:59:59.000Z

    the slowing growth in coking coal production after 2005,the relative share of coking coal has continued to declinein domestic production of coking coal can be linked to the

  15. NETL: Coal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Major Demonstrations Major Demonstrations Since 1985, we have helped fund commercial-scale clean coal technology demonstration projects. ICCS | CCPI | PPII | CCTDP | FutureGen...

  16. Advanced Coal Wind Hybrid: Economic Analysis

    SciTech Connect (OSTI)

    Phadke, Amol; Goldman, Charles; Larson, Doug; Carr, Tom; Rath, Larry; Balash, Peter; Yih-Huei, Wan

    2008-11-28T23:59:59.000Z

    Growing concern over climate change is prompting new thinking about the technologies used to generate electricity. In the future, it is possible that new government policies on greenhouse gas emissions may favor electric generation technology options that release zero or low levels of carbon emissions. The Western U.S. has abundant wind and coal resources. In a world with carbon constraints, the future of coal for new electrical generation is likely to depend on the development and successful application of new clean coal technologies with near zero carbon emissions. This scoping study explores the economic and technical feasibility of combining wind farms with advanced coal generation facilities and operating them as a single generation complex in the Western US. The key questions examined are whether an advanced coal-wind hybrid (ACWH) facility provides sufficient advantages through improvements to the utilization of transmission lines and the capability to firm up variable wind generation for delivery to load centers to compete effectively with other supply-side alternatives in terms of project economics and emissions footprint. The study was conducted by an Analysis Team that consists of staff from the Lawrence Berkeley National Laboratory (LBNL), National Energy Technology Laboratory (NETL), National Renewable Energy Laboratory (NREL), and Western Interstate Energy Board (WIEB). We conducted a screening level analysis of the economic competitiveness and technical feasibility of ACWH generation options located in Wyoming that would supply electricity to load centers in California, Arizona or Nevada. Figure ES-1 is a simple stylized representation of the configuration of the ACWH options. The ACWH consists of a 3,000 MW coal gasification combined cycle power plant equipped with carbon capture and sequestration (G+CC+CCS plant), a fuel production or syngas storage facility, and a 1,500 MW wind plant. The ACWH project is connected to load centers by a 3,000 MW transmission line. In the G+CC+CCS plant, coal is gasified into syngas and CO{sub 2} (which is captured). The syngas is burned in the combined cycle plant to produce electricity. The ACWH facility is operated in such a way that the transmission line is always utilized at its full capacity by backing down the combined cycle (CC) power generation units to accommodate wind generation. Operating the ACWH facility in this manner results in a constant power delivery of 3,000 MW to the load centers, in effect firming-up the wind generation at the project site.

  17. Partial Oxidation Gas Turbine for Power and Hydrogen Co-Production from Coal-Derived Fuel in Industrial Applications

    SciTech Connect (OSTI)

    Joseph Rabovitser

    2009-06-30T23:59:59.000Z

    The report presents a feasibility study of a new type of gas turbine. A partial oxidation gas turbine (POGT) shows potential for really high efficiency power generation and ultra low emissions. There are two main features that distinguish a POGT from a conventional gas turbine. These are associated with the design arrangement and the thermodynamic processes used in operation. A primary design difference of the POGT is utilization of a non?catalytic partial oxidation reactor (POR) in place of a conventional combustor. Another important distinction is that a much smaller compressor is required, one that typically supplies less than half of the air flow required in a conventional gas turbine. From an operational and thermodynamic point of view a key distinguishing feature is that the working fluid, fuel gas provided by the OR, has a much higher specific heat than lean combustion products and more energy per unit mass of fluid can be extracted by the POGT expander than in the conventional systems. The POGT exhaust stream contains unreacted fuel that can be combusted in different bottoming ycle or used as syngas for hydrogen or other chemicals production. POGT studies include feasibility design for conversion a conventional turbine to POGT duty, and system analyses of POGT based units for production of power solely, and combined production of power and yngas/hydrogen for different applications. Retrofit design study was completed for three engines, SGT 800, SGT 400, and SGT 100, and includes: replacing the combustor with the POR, compressor downsizing for about 50% design flow rate, generator replacement with 60 90% ower output increase, and overall unit integration, and extensive testing. POGT performances for four turbines with power output up to 350 MW in POGT mode were calculated. With a POGT as the topping cycle for power generation systems, the power output from the POGT ould be increased up to 90% compared to conventional engine keeping hot section temperatures, pressures, and volumetric flows practically identical. In POGT mode, the turbine specific power (turbine net power per lb mass flow from expander exhaust) is twice the value of the onventional turbine. POGT based IGCC plant conceptual design was developed and major components have been identified. Fuel flexible fluid bed gasifier, and novel POGT unit are the key components of the 100 MW IGCC plant for co producing electricity, hydrogen and/or yngas. Plant performances were calculated for bituminous coal and oxygen blown versions. Various POGT based, natural gas fueled systems for production of electricity only, coproduction of electricity and hydrogen, and co production of electricity and syngas for gas to liquid and hemical processes were developed and evaluated. Performance calculations for several versions of these systems were conducted. 64.6 % LHV efficiency for fuel to electricity in combined cycle was achieved. Such a high efficiency arise from using of syngas from POGT exhaust s a fuel that can provide required temperature level for superheated steam generation in HRSG, as well as combustion air preheating. Studies of POGT materials and combustion instabilities in POR were conducted and results reported. Preliminary market assessment was performed, and recommendations for POGT systems applications in oil industry were defined. POGT technology is ready to proceed to the engineering prototype stage, which is recommended.

  18. Centrifuge treatment of coal tar

    SciTech Connect (OSTI)

    L.A. Kazak; V.Z. Kaidalov; L.F. Syrova; O.S. Miroshnichenko; A.S. Minakov [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    New technology is required for the removal of water and heavy fractions from regular coal tar. Centrifuges offer the best option. Purification of coal tar by means of centrifuges at OAO NLMK permits the production of pitch coke or electrode pitch that complies with current standards.

  19. Coal Combustion Science quarterly progress report, April--June 1990

    SciTech Connect (OSTI)

    Hardesty, D.R. (ed.); Baxter, L.L.; Fletcher, T.H.; Mitchell, R.E.

    1990-11-01T23:59:59.000Z

    This document provides a quarterly status report of the Coal Combustion Science Program that is being conducted at the Combustion, Research Facility, Sandia National Laboratories, Livermore, California. Coal devolatilization, coal char combustion, and fate of mineral matter during coal combustion. 56 refs., 25 figs., 13 tabs.

  20. Online Catalog of Isotope Products from DOE's National Isotope Development Center

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    The National Isotope Development Center (NIDC) interfaces with the User Community and manages the coordination of isotope production across the facilities and business operations involved in the production, sale, and distribution of isotopes. A virtual center, the NIDC is funded by the Isotope Development and Production for Research and Applications (IDPRA) subprogram of the Office of Nuclear Physics in the U.S. Department of Energy Office of Science. The Isotope subprogram supports the production, and the development of production techniques of radioactive and stable isotopes that are in short supply for research and applications. Isotopes are high-priority commodities of strategic importance for the Nation and are essential for energy, medical, and national security applications and for basic research; a goal of the program is to make critical isotopes more readily available to meet domestic U.S. needs. This subprogram is steward of the Isotope Production Facility (IPF) at Los Alamos National Laboratory (LANL), the Brookhaven Linear Isotope Producer (BLIP) facility at BNL, and hot cell facilities for processing isotopes at ORNL, BNL and LANL. The subprogram also coordinates and supports isotope production at a suite of university, national laboratory, and commercial accelerator and reactor facilities throughout the Nation to promote a reliable supply of domestic isotopes. The National Isotope Development Center (NIDC) at ORNL coordinates isotope production across the many facilities and manages the business operations of the sale and distribution of isotopes.

  1. Energy Center Center for Coal Technology Research

    E-Print Network [OSTI]

    Fernández-Juricic, Esteban

    Energy Center Center for Coal Technology Research http://www.purdue.edu/dp/energy/CCTR/ Consumption Production Gasification Power Plants Coking Liquid Fuels Environment Oxyfuels Byproducts Legislation, 500 Central Drive West Lafayette, IN 47907-2022 #12;INDIANA COAL REPORT 2009 Center for Coal

  2. Integrated coal cleaning, liquefaction, and gasification process

    DOE Patents [OSTI]

    Chervenak, Michael C. (Pennington, NJ)

    1980-01-01T23:59:59.000Z

    Coal is finely ground and cleaned so as to preferentially remove denser ash-containing particles along with some coal. The resulting cleaned coal portion having reduced ash content is then fed to a coal hydrogenation system for the production of desirable hydrocarbon gases and liquid products. The remaining ash-enriched coal portion is gasified to produce a synthesis gas, the ash is removed from the gasifier usually as slag, and the synthesis gas is shift converted with steam and purified to produce the high purity hydrogen needed in the coal hydrogenation system. This overall process increases the utilization of as-mined coal, reduces the problems associated with ash in the liquefaction-hydrogenation system, and permits a desirable simplification of a liquids-solids separation step otherwise required in the coal hydrogenation system.

  3. Clean Coal Technology Programs: Program Update 2009

    SciTech Connect (OSTI)

    None

    2009-10-01T23:59:59.000Z

    The purpose of the Clean Coal Technology Programs: Program Update 2009 is to provide an updated status of the U.S. Department of Energy (DOE) commercial-scale demonstrations of clean coal technologies (CCT). These demonstrations have been performed under the Clean Coal Technology Demonstration Program (CCTDP), the Power Plant Improvement Initiative (PPII), and the Clean Coal Power Initiative (CCPI). Program Update 2009 provides: (1) a discussion of the role of clean coal technology demonstrations in improving the nation’s energy security and reliability, while protecting the environment using the nation’s most abundant energy resource—coal; (2) a summary of the funding and costs of the demonstrations; and (3) an overview of the technologies being demonstrated, along with fact sheets for projects that are active, recently completed, or recently discontinued.

  4. By-Products Utilization

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    -Milwaukee, P.O. Box 784, Milwaukee, WI 53201 d Project Manager, Illinois Clean Coal Institute * Director UWM products containing clean coal ash compared to conventional coal ash. Utilization of clean coal ash is much products that utilize clean coal ash. With increasing federal regulations on power plant emissions, finding

  5. EIA - Coal Distribution

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40Coal Stocks at1,066,688 760,877 951,322 1,381,127byForms What'sAnnual Coal

  6. Coal-Producing Region

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadapInactiveVisiting the TWPSuccessAlamosCharacterization2Climate, OceanPublicationandCoal Coal.

  7. Quarterly coal report, January--March 1998

    SciTech Connect (OSTI)

    Young, P.

    1998-08-01T23:59:59.000Z

    The Quarterly Coal Report (QCR) provides comprehensive information about US coal production, distribution, exports, imports, receipts, prices, consumption, and stocks to a wide audience, including Congress, Federal and State agencies, the coal industry, and the general public. Coke production, consumption, distribution, imports, and exports data are also provided. This report presents detailed quarterly data for January through March 1998 and aggregated quarterly historical data for 1992 through the fourth quarter of 1997. Appendix A displays, from 1992 on, detailed quarterly historical coal imports data. To provide a complete picture of coal supply and demand in the United States, historical information has been integrated in this report. 58 tabs.

  8. Quarterly coal report, October--December 1996

    SciTech Connect (OSTI)

    NONE

    1997-05-01T23:59:59.000Z

    The Quarterly Coal Report (QCR) provides comprehensive information about US coal production, distribution, exports, imports, receipts, prices, consumption, and stocks to a wide audience, including Congress, Federal and State agencies, the coal industry, and the general public. Coke production, consumption, distribution, imports, and exports data are also provided. This report presents detailed quarterly data for October through December 1996 and aggregated quarterly historical data for 1990 through the third quarter of 1996. Appendix A displays, from 1988 on, detailed quarterly historical coal imports data. To provide a complete picture of coal supply and demand in the US, historical information has been integrated in this report. 8 figs., 72 tabs.

  9. Statistical review of coal in Canada, 1997

    SciTech Connect (OSTI)

    Not Available

    1999-01-01T23:59:59.000Z

    The paper presents an annual review of the coal industry, including production, exports and imports, and consumption. An overview is given, followed by more detailed statistical data for the current year and preceding decade (supply and demand, value and volume of supply by province, coal production by class or province, exports by destination, coal consumed in power generation by province, electrical energy production by fuel type, domestic demand for primary energy by type).

  10. Western Coal/Great Lakes Alternative export-coal conference

    SciTech Connect (OSTI)

    Not Available

    1981-01-01T23:59:59.000Z

    This conference dealt with using the Great Lakes/St. Lawrence Seaway as an alternative to the East and Gulf Coasts for the exporting of coal to Europe and the potential for a piece of the European market for the subbituminous coals of Montana and Wyoming. The topics discussed included: government policies on coal exports; the coal reserves of Montana; cost of rail transport from Western mines to Lake Superior; the planning, design, and operation of the Superior Midwest Energy Terminal at Superior, Wisconsin; direct transfer of coal from self-unloading lakers to large ocean vessels; concept of total transportation from mines to users; disadvantage of a nine month season on the Great Lakes; costs of maritime transport of coal through the Great Lakes to Europe; facilities at the ice-free, deep water port at Sept Iles; the use of Western coals from an environmental and economic viewpoint; the properties of Western coal and factors affecting its use; the feasibility of a slurry pipeline from the Powder River Basin to Lake Superior; a systems analysis of the complete hydraulic transport of coal from the mine to users in Europe; the performance of the COJA mill-burner for the combustion of superfine coal; demand for steam coal in Western Europe; and the effect the New Source Performance Standards will have on the production and use of Western coal. A separate abstract was prepared for each of the 19 papers for the Energy Data Base (EDB); 17 will appear in Energy Research Abstracts (ERA) and 11 in Energy Abstracts for Policy Analysis (EAPA). (CKK)

  11. Studies on design of a process for organo-refining of coal to obtain super clean coal

    SciTech Connect (OSTI)

    Sharma, C.S.; Sharma, D.K. [Indian Inst. of Tech., New Delhi (India). Centre for Energy Studies

    1999-08-01T23:59:59.000Z

    Organo-refining of coal results in refining the coal to obtain super clean coal and residual coal. Super clean coal may be used to obtain value added chemicals, products, and cleaner fuels from coal. In the present work, studies on the design of a semicontinuous process for organo-refining of one ton of coal have been made. The results are reported. This is only a cursory attempt for the design, and further studies may be required for designing this process for use in the development of a scaled-up process of organo-refining of coal.

  12. Hanford, WA Selected as Plutonium Production Facility | National Nuclear

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilA groupTubahq.na.gov Office ofDepartment ofrAdministrationNational|HSEMC

  13. Trace-element geochemistry of coal resource development related to environmental quality and health

    SciTech Connect (OSTI)

    Not Available

    1980-01-01T23:59:59.000Z

    This report assesses for decision makers and those involved in coal resource development the environmental and health impacts of trace-element effects arising from significant increases in the use of coal, unless unusual precautions are invoked. Increasing demands for energy and the pressing need for decreased dependence of the United States on imported oil require greater use of coal to meet the nation's energy needs during the next decade. If coal production and consumption are increased at a greatly accelerated rate, concern arises over the release, mobilization, transportation, distribution, and assimilation of certain trace elements, with possible adverse effects on the environment and human health. It is, therefore, important to understand their geochemical pathways from coal and rocks via air, water, and soil to plants, animals, and ultimately humans, and their relation to health and disease. To address this problem, the Panel on Trace Element Geochemistry of Coal Resource Development Related to Health (PECH) was established. Certain assumptions were made by the Panel to highlight the central issues of trace elements and health and to avoid unwarranted duplication of other studies. Based on the charge to the Panel and these assumptions, this report describes the amounts and distribution of trace elements related to the coal source; the various methods of coal extraction, preparation, transportation, and use; and the disposal or recycling of the remaining residues or wastes. The known or projected health effects are discussed at the end of each section.

  14. Evaluation of coal minerals and metal residues as coal-liquefaction catalysts. Final report

    SciTech Connect (OSTI)

    Garg, D.; Givens, E. N.; Schweighardt, F. K.; Tarrer, A. R.; Guin, J. A.; Curtis, C. W.; Huang, W. J.; Shridharani, K.; Clinton, J. H.

    1982-02-01T23:59:59.000Z

    The catalytic activity of various minerals, metallic wastes, and transition metals was investigated in the liquefaction of various coals. The effects of coal type, process variables, coal cleaning, catalyst addition mode, solvent quality, and solvent modification on coal conversion and oil production were also studied. Coal conversion and oil production improved significantly by the addition of pyrite, reduced pyrite, speculite, red mud, flue dust, zinc sulfide, and various transition metal compounds. Impregnation and molecular dispersion of iron gave higher oil production than particulate incorporation of iron. However, the mode of molybdenum addition was inconsequential. Oil production increased considerably both by adding a stoichiometric mixture of iron oxide and pyrite and by simultaneous impregnation of coal with iron and molybdenum. Hydrogenation activity of disposable catalysts decreased sharply in the presence of nitrogen compounds. The removal of heteroatoms from process solvent improved thermal as well as catalytic coal liquefaction. The improvement in oil production was very dramatic with a catalyst.

  15. Method of operating a two-stage coal gasifier

    DOE Patents [OSTI]

    Tanca, Michael C. (Tariffville, CT)

    1982-01-01T23:59:59.000Z

    A method of operating an entrained flow coal gasifier (10) via a two-stage gasification process. A portion of the coal (18) to be gasified is combusted in a combustion zone (30) with near stoichiometric air to generate combustion products. The combustion products are conveyed from the combustion zone into a reduction zone (32) wherein additional coal is injected into the combustion products to react with the combustion products to form a combustible gas. The additional coal is injected into the reduction zone as a mixture (60) consisting of coal and steam, preferably with a coal-to-steam weight ratio of approximately ten to one.

  16. Integrated two-stage coal liquefaction process

    DOE Patents [OSTI]

    Bronfenbrenner, James C. (Allentown, PA); Skinner, Ronald W. (Allentown, PA); Znaimer, Samuel (Vancouver, CA)

    1985-01-01T23:59:59.000Z

    This invention relates to an improved two-stage process for the production of liquid carbonaceous fuels and solvents from carbonaceous solid fuels, especially coal.

  17. Quarterly coal report, January--March 1996

    SciTech Connect (OSTI)

    NONE

    1996-08-01T23:59:59.000Z

    This report presents detailed quarterly data for March 1996 and historical data for 1988 through 1995 on coal production, distribution, imports and exports, prices, consumption, and stocks.

  18. Production of low-sulfur binder pitch from high-sulfur Illinois coals. Technical report, September 1--November 30, 1994

    SciTech Connect (OSTI)

    Knight, R.A. [Inst. of Gas Technology, Chicago, IL (United States)

    1994-12-31T23:59:59.000Z

    The objective of this project is to produce electrode binder pitch with sulfur content below 0.6 wt% from high-sulfur Illinois coal mild gasification liquids. In this project, two approaches to sulfur reduction are being explored in conjunction with thermocracking: (1) the use of conventionally cleaned coal with low ({approximately}1%) sulfur as a mild gasification feedstock, and (2) direct biodesulfurization of the liquids prior to thermocracking. In Case 1, the crude pitch is being produced by mild gasification of IBC-109 coal in an existing IGT bench-scale reactor, followed by distillation of the scrubbing solvent and light-to-middle oils to isolate the crude pitch. In Case 2, the crude pitch for biodesulfurization is the same material previously studied, which was obtained from Illinois No. 6 coal tests conducted in the IGT mild gasification PRU in 1990. Biodesulfurization is to be performed by contacting the pitch with Rhodococcus Rhodochrous either as live cultures or in the form of concentrated biocatalyst. Following preparation of the crude pitches, pitch upgrading experiments are to be conducted in a continuous flash thermocracker (FTC) constructed in previous ICCI-sponsored studies. The finished pitch is then characterized for physical and chemical properties (density, softening point, QI, TI, coking value, and elemental composition), and compared to typical specifications for binder pitches. This quarter, 45 kg of IBC-109 coal was obtained and sized to 40 x 80 mesh for mild gasification. Laboratory experiments were conducted to identify means of dispersing or emulsifying pitch in water to render is accessible to biocatalysts, and exploratory desulfurization tests on one-gram pitch samples were begun.

  19. China's Coal: Demand, Constraints, and Externalities

    SciTech Connect (OSTI)

    Aden, Nathaniel; Fridley, David; Zheng, Nina

    2009-07-01T23:59:59.000Z

    This study analyzes China's coal industry by focusing on four related areas. First, data are reviewed to identify the major drivers of historical and future coal demand. Second, resource constraints and transport bottlenecks are analyzed to evaluate demand and growth scenarios. The third area assesses the physical requirements of substituting coal demand growth with other primary energy forms. Finally, the study examines the carbon- and environmental implications of China's past and future coal consumption. There are three sections that address these areas by identifying particular characteristics of China's coal industry, quantifying factors driving demand, and analyzing supply scenarios: (1) reviews the range of Chinese and international estimates of remaining coal reserves and resources as well as key characteristics of China's coal industry including historical production, resource requirements, and prices; (2) quantifies the largest drivers of coal usage to produce a bottom-up reference projection of 2025 coal demand; and (3) analyzes coal supply constraints, substitution options, and environmental externalities. Finally, the last section presents conclusions on the role of coal in China's ongoing energy and economic development. China has been, is, and will continue to be a coal-powered economy. In 2007 Chinese coal production contained more energy than total Middle Eastern oil production. The rapid growth of coal demand after 2001 created supply strains and bottlenecks that raise questions about sustainability. Urbanization, heavy industrial growth, and increasing per-capita income are the primary interrelated drivers of rising coal usage. In 2007, the power sector, iron and steel, and cement production accounted for 66% of coal consumption. Power generation is becoming more efficient, but even extensive roll-out of the highest efficiency units would save only 14% of projected 2025 coal demand for the power sector. A new wedge of future coal consumption is likely to come from the burgeoning coal-liquefaction and chemicals industries. If coal to chemicals capacity reaches 70 million tonnes and coal-to-liquids capacity reaches 60 million tonnes, coal feedstock requirements would add an additional 450 million tonnes by 2025. Even with more efficient growth among these drivers, China's annual coal demand is expected to reach 3.9 to 4.3 billion tonnes by 2025. Central government support for nuclear and renewable energy has not reversed China's growing dependence on coal for primary energy. Substitution is a matter of scale: offsetting one year of recent coal demand growth of 200 million tonnes would require 107 billion cubic meters of natural gas (compared to 2007 growth of 13 BCM), 48 GW of nuclear (compared to 2007 growth of 2 GW), or 86 GW of hydropower capacity (compared to 2007 growth of 16 GW). Ongoing dependence on coal reduces China's ability to mitigate carbon dioxide emissions growth. If coal demand remains on a high growth path, carbon dioxide emissions from coal combustion alone would exceed total US energy-related carbon emissions by 2010. Within China's coal-dominated energy system, domestic transportation has emerged as the largest bottleneck for coal industry growth and is likely to remain a constraint to further expansion. China has a low proportion of high-quality reserves, but is producing its best coal first. Declining quality will further strain production and transport capacity. Furthermore, transporting coal to users has overloaded the train system and dramatically increased truck use, raising transportation oil demand. Growing international imports have helped to offset domestic transport bottlenecks. In the long term, import demand is likely to exceed 200 million tonnes by 2025, significantly impacting regional markets.

  20. 1 INTRODUCTION Appalachian coal recovered during mining fre-

    E-Print Network [OSTI]

    of Appalachian underground coal mining (Newman 2003). Storage of coal processing waste is limited to above ground- ground room-and-pillar or longwall coal production do not allow for the separation of waste during coal. Such an analysis requires the ability to predict potential surface ground movements, both vertical (i

  1. The Key Coal Producers ONLINE SUPPORTING MATERIALS to

    E-Print Network [OSTI]

    Patzek, Tadeusz W.

    The Key Coal Producers ONLINE SUPPORTING MATERIALS to A Global Coal Production Forecast with Multi's most important coal-producing area is North-Central China. The provinces of Inner Mongolia, Ningxia, Shaanxi and Shanxi together accounted for 83 percent of China's proven coal reserves in 2000, and Shanxi

  2. Assessment of coal bed gas prospects

    SciTech Connect (OSTI)

    Moore, T.R. [Phillips Petroleum Co., Bartlesville, OK (United States)

    1996-12-31T23:59:59.000Z

    Coal bed gas is an often overlooked source of clean, methane-rich, H{sub 2}S-free natural gas. The economic development of coal bed gas requires a knowledge of coal gas reservoir characteristics and certain necessary departures from conventional evaluation, drilling, completion, and production practices. In many ways coal seam reservoirs are truly unconventional. Most coals sufficient rank have generated large volumes of gas that may be retained depth in varying amounts through adsorption. Coal gas production can take place only when the reservoir pressure is reduced sufficiently to allow the gas to desorb. Gas flow to the well bore takes place through a hierarchy of natural fractures, not the relatively impermeable coal matrix. Economic production is dependent upon critical factors intrinsic to the reservoir, including coal petrology, gas content, internal formation stratigraphy, fracture distribution, hydrogeology, in situ stress conditions, initial reservoir pressure and pressure regime, and the presence or absence of a {open_quote}free{close_quotes} gas saturation. Further, the coal bed reservoir is readily subject to formation damage through improper drilling, completion, or production techniques. This presentation will review the data types critical to the assessment of any coal seam gas prospect, suggest an outline method for screening such prospects, and point out some possible pitfalls to be considered in any coal bed gas development project.

  3. Coal: Energy for the future

    SciTech Connect (OSTI)

    NONE

    1995-05-01T23:59:59.000Z

    This report was prepared in response to a request by the US Department of energy (DOE). The principal objectives of the study were to assess the current DOE coal program vis-a-vis the provisions of the Energy Policy Act of 1992 (EPACT), and to recommend the emphasis and priorities that DOE should consider in updating its strategic plan for coal. A strategic plan for research, development, demonstration, and commercialization (RDD and C) activities for coal should be based on assumptions regarding the future supply and price of competing energy sources, the demand for products manufactured from these sources, technological opportunities, and the need to control the environmental impact of waste streams. These factors change with time. Accordingly, the committee generated strategic planning scenarios for three time periods: near-term, 1995--2005; mid-term, 2006--2020; and, long-term, 2021--2040. The report is divided into the following chapters: executive summary; introduction and scope of the study; overview of US DOE programs and planning; trends and issues for future coal use; the strategic planning framework; coal preparation, coal liquid mixtures, and coal bed methane recovery; clean fuels and specialty products from coal; electric power generation; technology demonstration and commercialization; advanced research programs; conclusions and recommendations; appendices; and glossary. 174 refs.

  4. Respiratory disease in Utah coal miners

    SciTech Connect (OSTI)

    Rom, W.N.; Kanner, R.E.; Renzetti, A.D. Jr.; Shigeoka, J.W.; Barkman, H.W.; Nichols, M.; Turner, W.A.; Coleman, M.; Wright, W.E.

    1981-04-01T23:59:59.000Z

    Two hundred forty-two Utah underground coal miners volunteered to participate in a respiratory disease study. They were an older group (mean, 56 years of age) and had spent a mean of 29 years in the coal-mining industry. The prevalence of chronic bronchitis was 57%, and that of coal worker's pneumoconiosis, 25%; only one worker had progressive massive fibrosis. Significant impairment of pulmonary function was found among those with a history of cigarette smoking. Chronic bronchitis or coal worker's penumoconiosis among nonsmokers did not impair pulmonary function. There was a significant association among the nonsmokers between increasing exposure to coal dust and coal worker's pneumoconiosis, but not for changes in pulmonary function. Coal mine dust had a significant influence in causing the symptom complex of chronic cough and sputum production, and coal worker's pneumoconiosis.

  5. Respiratory disease in Utah coal miners

    SciTech Connect (OSTI)

    Rom, W.N.; Kanner, R.E.; Renzetti, A.D. Jr.; Shigeoka, J.W.; Barkman, H.W.; Nichols, M.; Turner, W.A.; Coleman, M.; Wright, W.E.

    1981-04-01T23:59:59.000Z

    Two hundred forty-two Utah underground coal miners volunteered to participate in a respiratory disease study. They were an older group (mean, 56 years of age) and had spent a mean of 29 years in the coal-mining industry. The prevalence of chronic bronchitis was 57%, and that of coal worker's pneumoconiosis, 25%; only one worker had progressive massive fibrosis. Significant impairment of pulmonary function was found among those with a history of cigarette smoking. Chronic bronchitis or coal worker's pneumoconiosis among nonsmokers did not impair pulmonary function. There was a significant association among the nonsmokers between increasing exposure to coal dust and coal worker's pneumoconiosis, but not for changes in pulmonary function. Coal mine dust had a significant influence in causing the symptom complex of chronic cough and sputum production, and coal worker's pneumoconiosis.

  6. Hydrothermally treated coals for pulverized coal injection. Technical progress report, April 1995--June 1995

    SciTech Connect (OSTI)

    Walsh, D.E.; Rao, P.D.; Ogunsola, O.; Lin, H.K.

    1995-07-01T23:59:59.000Z

    This project is investigating the suitability of hydrothermally dried low-rank coals for pulverized fuel injection into blast furnaces in order to reduce coke consumption. Coal samples from the Beluga coal field and Usibelli Coal Mine, Alaska, are being used for the study. Crushed coal samples were hydrothermally treated at three temperatures, 275, 300 and 325{degrees}C, for residence times ranging from 10 to 120 minutes. Products have been characterized to determine their suitability for pulverized coal injection. Characterization includes proximate and ultimate analyses, vitrinite reflectance, TGA reactivity and thermochemical modeling. A literature survey has been conducted.

  7. Physics-Based GOES Satellite Product for Use in NREL's National Solar Radiation Database: Preprint

    SciTech Connect (OSTI)

    Sengupta, M.; Habte, A.; Gotseff, P.; Weekley, A.; Lopez, A.; Molling, C.; Heidinger, A.

    2014-07-01T23:59:59.000Z

    The National Renewable Energy Laboratory (NREL), University of Wisconsin, and National Oceanic Atmospheric Administration are collaborating to investigate the integration of the Satellite Algorithm for Shortwave Radiation Budget (SASRAB) products into future versions of NREL's 4-km by 4-km gridded National Solar Radiation Database (NSRDB). This paper describes a method to select an improved clear-sky model that could replace the current SASRAB global horizontal irradiance and direct normal irradiances reported during clear-sky conditions.

  8. All Composite Data Products: National FCEV Learning Demonstration With Updates Through January 18, 2012

    SciTech Connect (OSTI)

    Wipke, K.; Sprik, S.; Kurtz, J.; Ramsden, T.; Ainscough, C.; Saur, G.

    2012-01-01T23:59:59.000Z

    This presentation from the U.S. Department of Energy's National Renewable Energy Laboratory includes all the composite data products produced to date (with updates through January 18, 2012) as part of the National Fuel Cell Electric Vehicle (FCEV) Learning Demonstration.

  9. National FCEV Learning Demonstration: Spring 2011 All Composite Data Products With Updates Through March 29, 2011

    SciTech Connect (OSTI)

    Wipke, K.; Sprik, S.; Kurtz, J.; Ramsden, T.

    2011-04-01T23:59:59.000Z

    This presentation from the U.S. Department of Energy's National Renewable Energy Laboratory includes all the composite data products produced to date (with updates through March 29, 2011) as part of the National Fuel Cell Electric Vehicle (FCEV) Learning Demonstration.

  10. Production development and utilization of Zimmer Station wet FGD by-products. Final report. Volume 4, A laboratory study conducted in fulfillment of Phase 2, Objective 1 titled: Inhibition of acid production in coal refuse amended with calcium sulfite and calcium sulfate - containing FGD solids

    SciTech Connect (OSTI)

    none,

    1998-06-30T23:59:59.000Z

    Control of S02 emission from coal combustion requires desulfurization of coal before its combustion to produce coal refuse. Alternatively, gaseous emissions from coal combustion may be scrubbed to yield flue gas desulfurization (FGD) by-products that include calcium sulfite (CaSO3?0.5H2O or simply CaS03). Acid production in coal refuse due to pyrite oxidation and disposal of large amounts of FGD can cause environmental degradation. Addition of CaS03 and CaS03-containing FGD to coal refuse may reduce the amounts of oxygen and ferric ion available to oxidize pyrite because the sulfite moiety in CaS03 is a strong reductant and thus may mitigate acid production in coal refuse. In Chapter 1, it was shown that CaS03 efficiently scavenged dissolved oxygen and ferric ion in water under the conditions commonly encountered in a coal refuse disposal environment. In the presence ofCaS03, the concentration of dissolved oxygen in water exposed to the atmosphere declined to below 0.01 mg L"1 at pH <8.0. In Chapter 2, it was demonstrated that CaS03 prevented a pH drop in coal refuse slurry when 0.2 gCaS03 was added to a 2% fresh coal refuse slurry every three days. Calcium sulfite also inhibited acid leaching from fresh coal refuse in bench-scale columns under controlled conditions. During the initial 13 weeks of leaching, the total amounts of titratable acidity, soluble H\\ Fe, and Al from CaS03-treated refuse (6.4 gin 50 g fresh coal refuse) were only 26%,10%, 32%, and 39% of those of the control columns, respectively. A combination of CaS03 with CaC03 or fly ash enhanced the inhibitory effect of CaS03 on acid leaching. Calcium sulfite-containing FGD which combined CaS03, CaC03, fly ash, and gypsum showed a much stronger inhibitory effect on acid leaching than CaS03 alone. This combination effect was partially due to the positive interaction of CaS03 with CaC03 and fly ash on inhibition of acid leaching. In Chapter 3, CaS03-containing FGD was found to inhibit acid leaching from both fresh and aged coal refuse in large scale columns under simulated field conditions. During 39 weeks of leaching, the reduction of leachate acidity and Fe concentration and the increase ofleachate pH were significant (p <0.05) for the 22% FGD treatment with a linear response to increasing FGD rates (0%, 5.5%, 11%, and 22%). I conclude that CaS03 and CaS03-containing FGD have the ability to inhibit acid production in coal refuse and the inhibitory effect shown in this experiment is likely to occur under field conditions. Thus, the research results present a potential new method for mitigation of acid production in coal refuse and another beneficial utilization of FGD by-products.

  11. Hydroliquefaction of coal

    DOE Patents [OSTI]

    Sze, Morgan C. (Upper Montclair, NJ); Schindler, Harvey D. (Fairlawn, NJ)

    1982-01-01T23:59:59.000Z

    Coal is catalytically hydroliquefied by passing coal dispersed in a liquefaction solvent and hydrogen upwardly through a plurality of parallel expanded catalyst beds, in a single reactor, in separate streams, each having a cross-sectional flow area of no greater than 255 inches square, with each of the streams through each of the catalyst beds having a length and a liquid and gas superficial velocity to maintain an expanded catalyst bed and provide a Peclet Number of at least 3. If recycle is employed, the ratio of recycle to total feed (coal and liquefaction solvent) is no greater than 2:1, based on volume. Such conditions provide for improved selectivity to liquid product to thereby reduce hydrogen consumption. The plurality of beds are formed by partitions in the reactor.

  12. Techno-Economic Analysis of Scalable Coal-based Fuel Cells

    SciTech Connect (OSTI)

    Chuang, Steven

    2014-08-31T23:59:59.000Z

    Researchers at The University of Akron (UA) have demonstrated the technical feasibility of a laboratory coal fuel cell that can economically convert high sulfur coal into electricity with near zero negative environmental impact. Scaling up this coal fuel cell technology to the megawatt scale for the nation’s electric power supply requires two key elements: (i) developing the manufacturing technology for the components of the coal-based fuel cell, and (ii) long term testing of a kW scale fuel cell pilot plant. This project was expected to develop a scalable coal fuel cell manufacturing process through testing, demonstrating the feasibility of building a large-scale coal fuel cell power plant. We have developed a reproducible tape casting technique for the mass production of the planner fuel cells. Low cost interconnect and cathode current collector material was identified and current collection was improved. In addition, this study has demonstrated that electrochemical oxidation of carbon can take place on the Ni anode surface and the CO and CO2 product produced can further react with carbon to initiate the secondary reactions. One important secondary reaction is the reaction of carbon with CO2 to produce CO. We found CO and carbon can be electrochemically oxidized simultaneously inside of the anode porous structure and on the surface of anode for producing electricity. Since CH4 produced from coal during high temperature injection of coal into the anode chamber can cause severe deactivation of Ni-anode, we have studied how CH4 can interact with CO2 to produce in the anode chamber. CO produced was found able to inhibit coking and allow the rate of anode deactivation to be decreased. An injection system was developed to inject the solid carbon and coal fuels without bringing air into the anode chamber. Five planner fuel cells connected in a series configuration and tested. Extensive studies on the planner fuels and stack revealed that the planner fuel cell stack is not suitable for operation with carbon and coal fuels due to lack of mechanical strength and difficulty in sealing. We have developed scalable processes for manufacturing of process for planner and tubular cells. Our studies suggested that tubular cell stack could be the only option for scaling up the coal-based fuel cell. Although the direct feeding of coal into fuel cell can significantly simplify the fuel cell system, the durability of the fuel cell needs to be further improved before scaling up. We are developing a tubular fuel cell stack with a coal injection and a CO2 recycling unit.

  13. Welcome to the NNSA Production Office | National Nuclear Security

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilA groupTuba City,EnrichedSupplemental Directives |andAbout UsAdministration

  14. Isotope production agreement benefits medical patients | National Nuclear

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilA groupTubahq.na.gov Office ofDepartmentAdministrationto SubmitIND|

  15. KCP celebrates production milestone at new facility | National Nuclear

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilA groupTubahq.na.gov OfficeAdministration Field Office hosts leadership

  16. KCP highlights first part production | National Nuclear Security

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilA groupTubahq.na.gov OfficeAdministration Field Office hosts

  17. Livermore team awarded for hydrogen production research | National Nuclear

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilA groupTubahq.na.govSecurity Administration Leader,

  18. NNSA Production Office tops Feds Feed Families campaign goal | National

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilA Approved: 5-13-14 FEDERAL EMPLOYEE OCCUPATIONAL SAFETY AND HEALTHN N E E W W

  19. Tennessee: Oak Ridge National Laboratory Optimizes Carbon Fiber Production,

    Office of Environmental Management (EM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33Frequently AskedEnergyIssuesEnergy Solar Decathlon DOE-HDBK-1046-2008 August 2008Battery,

  20. Robbins named NNSA Production Office Deputy Manager | Y-12 National

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Scienceand Requirements RecentlyElectronicResources Resources About1

  1. Daniel Hoag Named NNSA Production Office Deputy Manager | National Nuclear

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilA Approved: 5-13-14Russianvolunteer |At.<ENDMENT/MODIFICATIONAs the

  2. NNSA Production Office Open for Business | National Nuclear Security

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilA Approved:AdministrationAnalysis andB -Reports

  3. Outlook and Challenges for Chinese Coal

    SciTech Connect (OSTI)

    Aden, Nathaniel T.; Fridley, David G.; Zheng, Nina

    2008-06-20T23:59:59.000Z

    China has been, is, and will continue to be a coal-powered economy. The rapid growth of coal demand since 2001 has created deepening strains and bottlenecks that raise questions about supply security. Although China's coal is 'plentiful,' published academic and policy analyses indicate that peak production will likely occur between 2016 and 2029. Given the current economic growth trajectory, domestic production constraints will lead to a coal gap that is not likely to be filled with imports. Urbanization, heavy industry growth, and increasing per-capita consumption are the primary drivers of rising coal usage. In 2006, the power sector, iron and steel, and cement accounted for 71% of coal consumption. Power generation is becoming more efficient, but even extensive roll-out of the highest efficiency units could save only 14% of projected 2025 coal demand. If China follows Japan, steel production would peak by 2015; cement is likely to follow a similar trajectory. A fourth wedge of future coal consumption is likely to come from the burgeoning coal-liquefaction and chemicals industries. New demand from coal-to-liquids and coal-to-chemicals may add 450 million tonnes of coal demand by 2025. Efficient growth among these drivers indicates that China's annual coal demand will reach 4.2 to 4.7 billion tonnes by 2025. Central government support for nuclear and renewable energy has not been able to reduce China's growing dependence on coal for primary energy. Few substitution options exist: offsetting one year of recent coal demand growth would require over 107 billion cubic meters of natural gas, 48 GW of nuclear, or 86 GW of hydropower capacity. While these alternatives will continue to grow, the scale of development using existing technologies will be insufficient to substitute significant coal demand before 2025. The central role of heavy industry in GDP growth and the difficulty of substituting other fuels suggest that coal consumption is inextricably entwined with China's economy in its current mode of growth. Ongoing dependence on coal reduces China's ability to mitigate carbon dioxide emissions growth. If coal demand remains on its current growth path, carbon dioxide emissions from coal combustion alone would exceed total US energy-related carbon emissions by 2010. Broadening awareness of the environmental costs of coal mining, transport, and combustion is raising the pressure on Chinese policy makers to find alternative energy sources. Within China's coal-dominated energy system, domestic transportation has emerged as the largest bottleneck for coal industry growth and is likely to remain a constraint to further expansion. China is short of high-quality reserves, but is producing its best coal first. Declining quality will further strain production and transport. Transporting coal to users has overloaded the train system and dramatically increased truck use, raising transport oil demand. Growing international imports have helped to offset domestic transport bottlenecks. In the long term, import demand is likely to exceed 200 mt by 2025, significantly impacting regional markets. The looming coal gap threatens to derail China's growth path, possibly undermining political, economic, and social stability. High coal prices and domestic shortages will have regional and global effects. Regarding China's role as a global manufacturing center, a domestic coal gap will increase prices and constrain growth. Within the Asia-Pacific region, China's coal gap is likely to bring about increased competition with other coal-importing countries including Japan, South Korea, Taiwan, and India. As with petroleum, China may respond with a government-supported 'going-out' strategy of resource acquisition and vertical integration. Given its population and growing resource constraints, China may favor energy security, competitiveness, and local environmental protection over global climate change mitigation. The possibility of a large coal gap suggests that Chinese and international policy makers should maximize institutional and financial support

  4. Quarterly Coal Report, July--September 1994

    SciTech Connect (OSTI)

    Not Available

    1995-02-01T23:59:59.000Z

    The Quarterly Coal Report (QCR) provides comprehensive information about US coal production, distribution, exports, imports, receipts, prices, consumption, and stocks to a wide audience, including Congress, Federal and State agencies, the coal industry, and the general public. Coke production, consumption, distribution, imports, and exports data are also provided. This report presents detailed quarterly data for July through September 1994 and aggregated quarterly historical data for 1986 through the second quarter of 1994. Appendix A displays, from 1986 on, detailed quarterly historical coal imports data, as specified in Section 202 of the Energy Policy and Conservation Amendments Act of 1985 (Public Law 99-58). Appendix B gives selected quarterly tables converted to metric tons. To provide a complete picture of coal supply and demand in the United States, historical information has been integrated in this report. Additional historical data can also be found in the following EIA publications : Annual Energy Review 1993 (DOE/EIA-0384(93)), Monthly Energy Review (DOE/EIA-0035), and Coal Data: A Reference (DOE/EIA-0064(90)). The historical data in this report are collected by the EIA in three quarterly coal surveys (coal consumption at manufacturing plants, coal distribution, and coal consumption at coke plants), one annual coal production survey, and two monthly surveys of electric utilities. All data shown for 1993 and previous years are final. Data for 1994 are preliminary.

  5. Process development for production of coal/sorbent agglomerates. Final technical report, September 1, 1990--August 31, 1991

    SciTech Connect (OSTI)

    Rapp, D.M.

    1991-12-31T23:59:59.000Z

    The goal of this work was to develop a process flow diagram to economically produce a clean-burning fuel from fine Illinois coal. To accomplish this, the process of pelletizing fine coal with calcium hydroxide, a sulfur capturing sorbent, was investigated. Carbonation, which is the reaction of calcium hydroxide with carbon dioxide (in the presence of moisture) to produce a bonding matrix of calcium carbonate, was investigated as a method for improving pellet quality and reducing binder costs. Proper moisture level is critical to allow the reaction to occur. If too much moisture is present in a pellet, the pore spaces are filled and carbon dioxide must diffuse through the water to reach the calcium hydroxide and react. This severely slows or stops the reaction. The ideal situation is when there is just enough moisture to coat the calcium hydroxide allowing for the reaction to proceed. The process has been successfully demonstrated on a pilot-scale as a method of hardening iron ore pellets (Imperato, 1966). Two potential combustion options are being considered for the coal/calcium hydroxide pellets: fluidized bed combustors and industrial stoker boilers.

  6. The ENCOAL Mild Coal Gasification Project, A DOE Assessment

    SciTech Connect (OSTI)

    National Energy Technology Laboratory

    2002-03-15T23:59:59.000Z

    This report is a post-project assessment of the ENCOAL{reg_sign} Mild Coal Gasification Project, which was selected under Round III of the U.S. Department of Energy (DOE) Clean Coal Technology (CCT) Demonstration Program. The CCT Demonstration Program is a government and industry cofunded technology development effort to demonstrate a new generation of innovative coal utilization processes in a series of commercial-scale facilities. The ENCOAL{reg_sign} Corporation, a wholly-owned subsidiary of Bluegrass Coal Development Company (formerly SMC Mining Company), which is a subsidiary of Ziegler Coal Holding Company, submitted an application to the DOE in August 1989, soliciting joint funding of the project in the third round of the CCT Program. The project was selected by DOE in December 1989, and the Cooperative Agreement (CA) was approved in September 1990. Construction, commissioning, and start-up of the ENCOAL{reg_sign} mild coal gasification facility was completed in June 1992. In October 1994, ENCOAL{reg_sign} was granted a two-year extension of the CA with the DOE, that carried through to September 17, 1996. ENCOAL{reg_sign} was then granted a six-month, no-cost extension through March 17, 1997. Overall, DOE provided 50 percent of the total project cost of $90,664,000. ENCOAL{reg_sign} operated the 1,000-ton-per-day mild gasification demonstration plant at Triton Coal Company's Buckskin Mine near Gillette, Wyoming, for over four years. The process, using Liquids From Coal (LFC{trademark}) technology originally developed by SMC Mining Company and SGI International, utilizes low-sulfur Powder River Basin (PRB) coal to produce two new fuels, Process-Derived Fuel (PDF{trademark}) and Coal-Derived Liquids (CDL{trademark}). The products, as alternative fuel sources, are capable of significantly lowering current sulfur emissions at industrial and utility boiler sites throughout the nation thus reducing pollutants causing acid rain. In support of this overall objective, the following goals were established for the ENCOAL{reg_sign} Project: Provide sufficient quantity of products for full-scale test burns; Develop data for the design of future commercial plants; Demonstrate plant and process performance; Provide capital and O&M cost data; and Support future LFC{trademark} technology licensing efforts. Each of these goals has been met and exceeded. The plant has been in operation for nearly 5 years, during which the LFC{trademark} process has been demonstrated and refined. Fuels were made, successfully burned, and a commercial-scale plant is now under contract for design and construction.

  7. World coal demand grows and Australia meets the need

    SciTech Connect (OSTI)

    Fiscor, S.

    2007-02-15T23:59:59.000Z

    The article quotes world thermal coal exports and imports figures for 2005 and forecast figures for 2006 and 2007, and world metallurgical coal consumption, production, imports and exports figures for 2004-2007, from the Australian Bureau of Agriculture and Resource Economics (ABARE) 2006 Commodity Report. Australia exports a little more than 75% of its coal and it accounts for nearly 30% of the seaborne coal trade. Transportation constraints prevent some Australian coal producers form achieving full potential. The article also reports on 2006 production figures from and some new projects at the following Australian coal companies: BHP Billton, Xstrata Coal, Rio Tinto Coal Australia, Coal & Allied, Anglo Coal Australia, Peabody/Excel and Wesfarmers. 2 tabs.

  8. Climate Prediction Center Products in Support of National Security Mike Halpert, Deputy Director, Climate Prediction Center

    E-Print Network [OSTI]

    Miami, University of

    Climate Prediction Center Products in Support of National Security Mike Halpert, Deputy Director, Climate Prediction Center 5200 Auth Rd. Camp Springs, MD 20746 301-763-8000 x7535 Mike.Halpert@noaa.gov The Climate Prediction Center (CPC) delivers climate prediction, monitoring, and diagnostic products

  9. Quarterly coal report, July--September 1997

    SciTech Connect (OSTI)

    NONE

    1998-02-01T23:59:59.000Z

    The Quarterly Coal Report (QCR) provides comprehensive information about US coal production, distribution, exports, imports, receipts, prices, consumption, and stocks. Coke production consumption, distribution, imports, and exports data are also provided. This report presents detailed quarterly data for July through September 1997 and aggregated quarterly historical data for 1991 through the second quarter of 1997. Appendix A displays, from 1991 on, detailed quarterly historical coal imports data. 72 tabs.

  10. Quarterly coal report, July--September 1998

    SciTech Connect (OSTI)

    NONE

    1999-02-01T23:59:59.000Z

    The Quarterly Coal Report (QCR) provides comprehensive information about US coal production, distribution, exports, imports, receipts, prices, consumption, and stocks to a wide audience, including Congress, Federal and State agencies, the coal industry, and the general public. Coke production, consumption, distribution, imports, and exports data are also provided. This report presents detailed quarterly data for July through September 1998 and aggregated quarterly historical data for 1992 through the second quarter of 1998. 58 tabs.

  11. By-Products Utilization

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    -Products Utilization E-mail: ymchun@uwm.edu and F. D. Botha Project Manager, Illinois Clean Coal Institute 5776 Coal, University of Wisconsin-Milwaukee, Milwaukee, WI, USA. 4 Project Manager, Illinois Clean Coal Institute

  12. By-Products Utilization

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    combustion by-products #12;3 generated by using both conventional and clean-coal technologies. A clean-coal that obtained from clean-coal technology, are not utilized in cast-concrete masonry products (bricks, blocksCenter for By-Products Utilization RECENT ADVANCES IN RECYCLING CLEAN- COAL ASH By Tarun R. Naik

  13. By-Products Utilization

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    of coal fly ash, coal bottom ash, and used foundry sand in concrete, bricks, blocks, and8 paving stones, Wisconsin. She is involved in management,11 disposal, and sale of coal-combustion by-products. She alsoCenter for By-Products Utilization UNDER-UTILIZED COAL-COMBUSTION PRODUCTS IN PERMEABLE ROADWAY

  14. By-Products Utilization

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    -fired power plants derive energy by burning coal in their furnaces. These power plants generally use either. The by-product materials include coal combustion by-products, wood ash, pulp and paper industry by recycling and research needs are discussed. #12;3 2.0 MATERIALS 2.1 COAL-COMBUSTION BY-PRODUCTS Coal

  15. By-Products Utilization

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    combustion by-products (such as clean-coal ash) from power plants. Maximum recycling of such by- products regulations and increasing use of low-grade coal, the number of coal-fired power plants with flue gasCenter for By-Products Utilization USE OF CLEAN-COAL ASH FOR MANAGING ASR By Zichao Wu and Tarun R

  16. A SUMMARY OF COAL IN THE FORT UNION FORMATION (TERTIARY), BIGHORN BASIN,

    E-Print Network [OSTI]

    Chapter SB A SUMMARY OF COAL IN THE FORT UNION FORMATION (TERTIARY), BIGHORN BASIN, WYOMING assessment of selected Tertiary coal beds and zones in the Northern RockyMountains and Great Plains region, U...........................................................................................................................SB-1 Coal Production History

  17. COAL LIQUEFACTION STUDIES USING PHOSPHORIC ACID AT MODERATE TEMPERATURES AND PRESSURES

    E-Print Network [OSTI]

    McLean, J.B.

    2010-01-01T23:59:59.000Z

    1976. Cox, John 1. , urCatalysts for Coal Conversion", fromUiClean Fuels from Coal", IGT Symposium, Sept. 10-14, 1974.Derived from Solvent Refined Coal Conversion Products", SRI

  18. EIS-0004: Coal Loan Guarantee Program (P.L. 94-163)

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy prepared this EIS to address the potential impacts of implementing the Coal Loan Guarantee Program to encourage the production of low and high sulfur coal by small underground coal producers.

  19. Zero emission coal

    SciTech Connect (OSTI)

    Ziock, H.; Lackner, K.

    2000-08-01T23:59:59.000Z

    We discuss a novel, emission-free process for producing hydrogen or electricity from coal. Even though we focus on coal, the basic design is compatible with any carbonaceous fuel. The process uses cyclical carbonation of calcium oxide to promote the production of hydrogen from carbon and water. The carbonation of the calcium oxide removes carbon dioxide from the reaction products and provides the additional energy necessary to complete hydrogen production without additional combustion of carbon. The calcination of the resulting calcium carbonate is accomplished using the high temperature waste heat from solid oxide fuel cells (SOFC), which generate electricity from hydrogen fuel. Converting waste heat back to useful chemical energy allows the process to achieve very high conversion efficiency from fuel energy to electrical energy. As the process is essentially closed-loop, the process is able to achieve zero emissions if the concentrated exhaust stream of CO{sub 2} is sequestered. Carbon dioxide disposal is accomplished by the production of magnesium carbonate from ultramafic rock. The end products of the sequestration process are stable naturally occurring minerals. Sufficient rich ultramafic deposits exist to easily handle all the world's coal.

  20. By-Products Utilization

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    plants are the major source of generation of electricity. Coal-fired power plants derive energy by burning coal in their furnaces. These power plants generally use either pulverized coal-fired furnaces. 2.0 MATERIALS 2.1 COAL-COMBUSTION BY-PRODUCTS In most of the countries coal- fired thermal power

  1. Clean coal technology programs: program update 2006

    SciTech Connect (OSTI)

    NONE

    2006-09-15T23:59:59.000Z

    The purpose of the Clean Coal Technology Programs: Program Update 2006 is to provide an updated status of the DOE commercial-scale demonstrations of clean coal technologies (CCTs). These demonstrations are performed under the Clean Coal Technology Demonstration Program (CCTDP), the Power Plant Improvement Initiative (PPII) and the Clean Coal Power Initiative (CCPI). Program Update 2006 provides 1) a discussion of the role of clean coal technology demonstrations in improving the nation's energy security and reliability, while protecting the environment using the nation's most abundant energy resource - coal; 2) a summary of the funding and costs of the demonstrations; and 3) an overview of the technologies being demonstrated, with fact sheets for demonstration projects that are active, recently completed, withdrawn or ended, including status as of June 30 2006. 4 apps.

  2. Review of a Proposed Quarterly Coal Publication

    SciTech Connect (OSTI)

    Not Available

    1981-01-01T23:59:59.000Z

    This Review of a Proposed Quartery Coal Publication contains findings and recommendations regarding the content of a new summary Energy Information Administration (EIA) coal and coke publication entitled The Quarterly Coal Review (QCR). It is divided into five sections: results of interviews with selected EIA data users; identification of major functions of the coal and coke industries; analysis of coal and coke data collection activities; evaluation of issues conerning data presentation including recommendations for the content of the proposed QCR; and comparison of the proposed QCR with other EIA publications. Major findings and recommendations are as follows: (1) User interviews indicate a definite need for a compehensive publication that would support analyses and examine economic, supply and demand trends in the coal industry; (2) the organization of the publication should reflect the natural order of activities of the coal and coke industries. Based on an analysis of the industries, these functions are: production, stocks, imports, exports, distribution, and consumption; (3) current EIA coal and coke surveys collect sufficient data to provide a summary of the coal and coke industries on a quarterly basis; (4) coal and coke data should be presented separately. Coke data could be presented as an appendix; (5) three geographic aggregations are recommended in the QCR. These are: US total, coal producing districts, and state; (6) coal consumption data should be consolidated into four major consumer categories: electric utilities, coke plants, other industrial, and residential commercial; (7) several EIA publications could be eliminated by the proposed QCR.

  3. Coal ash utilization in India

    SciTech Connect (OSTI)

    Michalski, S.R.; Brendel, G.F.; Gray, R.E. [GAI Consultants, Inc., Pittsburgh, PA (United States)

    1998-12-31T23:59:59.000Z

    This paper describes methods of coal combustion product (CCP) management successfully employed in the US and considers their potential application in India. India produces about 66 million tons per year (mty) of coal ash from the combustion of 220 mty of domestically produced coal, the average ash content being about 30--40 percent as opposed to an average ash content of less than 10 percent in the US In other words, India produces coal ash at about triple the rate of the US. Currently, 95 percent of this ash is sluiced into slurry ponds, many located near urban centers and consuming vast areas of premium land. Indian coal-fired generating capacity is expected to triple in the next ten years, which will dramatically increase ash production. Advanced coal cleaning technology may help reduce this amount, but not significantly. Currently India utilizes two percent of the CCP`s produced with the remainder being disposed of primarily in large impoundments. The US utilizes about 25 percent of its coal ash with the remainder primarily being disposed of in nearly equal amounts between dry landfills and impoundments. There is an urgent need for India to improve its ash management practice and to develop efficient and environmentally sound disposal procedures as well as high volume ash uses in ash haulback to the coalfields. In addition, utilization should include: reclamation, structural fill, flowable backfill and road base.

  4. Development of a Hydrogasification Process for Co-Production of Substitute Natural Gas (SNG) and Electric Power from Western Coals-Phase I

    SciTech Connect (OSTI)

    Raymond Hobbs

    2007-05-31T23:59:59.000Z

    The Advanced Hydrogasification Process (AHP)--conversion of coal to methane--is being developed through NETL with a DOE Grant and has successfully completed its first phase of development. The results so far are encouraging and have led to commitment by DOE/NETL to begin a second phase--bench scale reactor vessel testing, expanded engineering analysis and economic perspective review. During the next decade new means of generating electricity, and other forms of energy, will be introduced. The members of the AHP Team envision a need for expanded sources of natural gas or substitutes for natural gas, to fuel power generating plants. The initial work the team has completed on a process to use hydrogen to convert coal to methane (pipeline ready gas) shows promising potential. The Team has intentionally slanted its efforts toward the needs of US electric utilities, particularly on fuels that can be used near urban centers where the greatest need for new electric generation is found. The process, as it has evolved, would produce methane from coal by adding hydrogen. The process appears to be efficient using western coals for conversion to a highly sought after fuel with significantly reduced CO{sub 2} emissions. Utilities have a natural interest in the preservation of their industry, which will require a dramatic reduction in stack emissions and an increase in sustainable technologies. Utilities tend to rank long-term stable supplies of fuel higher than most industries and are willing to trade some ratio of cost for stability. The need for sustainability, stability and environmentally compatible production are key drivers in the formation and progression of the AHP development. In Phase II, the team will add a focus on water conservation to determine how the basic gasification process can be best integrated with all the plant components to minimize water consumption during SNG production. The process allows for several CO{sub 2} reduction options including consumption of the CO{sub 2} in the original process as converted to methane. The process could under another option avoid emissions following the conversion to SNG through an adjunct algae conversion process. The algae would then be converted to fuels or other products. An additional application of the algae process at the end use natural gas fired plant could further reduce emissions. The APS team fully recognizes the competition facing the process from natural gas and imported liquid natural gas. While we expect those resources to set the price for methane in the near-term, the team's work to date indicates that the AHP process can be commercially competitive, with the added benefit of assuring long-term energy supplies from North American resources. Conversion of coal to a more readily transportable fuel that can be employed near load centers with an overall reduction of greenhouses gases is edging closer to reality.

  5. Quarterly coal report, April--June 1993

    SciTech Connect (OSTI)

    Not Available

    1993-11-26T23:59:59.000Z

    In the second quarter of 1993, the United States produced 235 million short tons of coal. This brought the total for the first half of 1993 to 477 million short tons, a decrease of 4 percent (21 million short tons) from the amount produced during the first half of 1992. The decrease was due to a 26-million-short-ton decline in production east of the Mississippi River, which was partially offset by a 5-million-short-ton increase in coal production west of the Mississippi River. Compared with the first 6 months of 1992, all States east of the Mississippi River had lower coal production levels, led by West Virginia and Illinois, which produced 9 million short tons and 7 million short tons less coal, respectively. The principal reasons for the drop in coal output for the first 6 months of 1993 compared to a year earlier were: a decrease in demand for US coal in foreign markets, particularly the steam coal markets; a draw-down of electric utility coal stocks to meet the increase in demand for coal-fired electricity generation; and a lower producer/distributor stock build-up. Distribution of US coal in the first half of 1993 was 15 million short tons lower than in the first half of 1992, with 13 million short tons less distributed to overseas markets and 2 million short tons less distributed to domestic markets.

  6. DESULFURIZATION OF COAL MODEL COMPOUNDS AND COAL LIQUIDS

    E-Print Network [OSTI]

    Wrathall, James Anthony

    2011-01-01T23:59:59.000Z

    Pollutants Associated With Coal Combustion. • E.P.A.Control Guidelines for Coal-Derived Pollutants .Forms of Sulfur in Coal • . . . . Coal Desulfurization

  7. Quarterly coal report, April--June, 1998

    SciTech Connect (OSTI)

    NONE

    1998-11-01T23:59:59.000Z

    The Quarterly Coal Report (QCR) provides comprehensive information about US coal production, distribution, exports, imports, receipts, prices, consumption, and stocks to a wide audience, including Congress, Federal and State agencies, the coal industry, and the general public. Coke production, consumption, distribution, imports, and exports data are also provided. This report presents detailed quarterly data for April through June 1998 and aggregated quarterly historical data for 1992 through the first quarter of 1998. Appendix A displays, from 1992 on, detailed quarterly historical coal imports data. 58 tabs.

  8. Quarterly coal report, April--June 1997

    SciTech Connect (OSTI)

    NONE

    1997-11-01T23:59:59.000Z

    The Quarterly Coal Report (QCR) provides comprehensive information about US coal production, distribution, exports, imports, receipts, prices, consumption, and stocks to a wide audience. Coke production, consumption, distribution, imports, and exports data are also provided. This report presents detailed quarterly data for April through June 1997 and aggregated quarterly historical data for 1991 through the first quarter of 1997. Appendix A displays, from 1991 on, detailed quarterly historical coal imports data. Appendix B gives selected quarterly tables converted to metric tons. To provide a complete picture of coal supply and demand in the US, historical information has been integrated in this report. 8 figs., 73 tabs.

  9. Utilization of Illinois coal gasification slags for production of ultra-lightweight aggregates. Final technical report, September 1, 1992--August 31, 1993

    SciTech Connect (OSTI)

    Choudhry, V. [Praxis Engineers, Inc., Milpitas, CA (United States); Zimmerle, T. [Silbrico Corp. (United States)

    1993-12-31T23:59:59.000Z

    This research was aimed at testing and developing the expansion potential of solid residues (slag) from gasification of Illinois coals to manufacture ultra-lightweight aggregates (ULWA). Conventional ULWAs are manufactured by pyroprocessing perlite or vermiculite ores and have unit weights in the 5--12 lb/ ft{sup 3} range. These materials sell for approximately $200/ton ($1.00/ft{sup 3}) and have numerous applications. The incentive for this effort was based on previous experimental results in which lightweight aggregates (LWA) with unit weights of 25--55 lb/ft{sup 3} were produced from Illinois slag using a direct-fired furnace. In this program, bench-scale expansion tests conducted with two Illinois coal slags resulted in product unit weights of 12 and 18.5 lb/ ft{sup 3}, thus confirming the feasibility of producing ULWA from Illinois slags. During initial pilot vertical shaft furnace test runs, two Illinois slags were expanded to generate products with unit weights of 12.5--26.5 and 20--52 lb/ ft{sup 3}. Further attempts to lower the product unit weights resulted in fusion of the slag. This problem could be overcome by methods including surface treatment of the slag, blending the slag with other materials, or utilization of indirect firing methods. To lower the product unit weights, an indirect-fired horizontal shaft furnace was used and products with unit weights of 12.4--52.0 lb/ft{sup 3} were generated, thus indicating that this method can be used to produce a wide range of expanded products. A large batch of expanded slag was produced using an 18-in. diameter x 12-ft long indirect-fired pilot furnace. A sample from this batch was characterized. Specimens of insulating concrete made from expanded slag had a unit weight 43.3 lb/ft{sup 3} and thermal conductivity of 1.34 Btu-in./h/ft{sup 2}/{degrees}F. This compares well with a value of 1. 2 Btu-in./h/ft{sup 2}/{degrees}F for insulating concrete of a similar weight made from perlite, as per ASTM C 332-82.

  10. Coals and coal requirements for the COREX process

    SciTech Connect (OSTI)

    Heckmann, H. [Deutsche Voest-Alpine Industrieanlagenbau GmbH, Duesseldorf (Germany)

    1996-12-31T23:59:59.000Z

    The utilization of non met coals for production of liquid hot metal was the motivation for the development of the COREX Process by VAI/DVAI during the 70`s. Like the conventional ironmaking route (coke oven/blast furnace) it is based on coal as source of energy and reduction medium. However, in difference to blast furnace, coal can be used directly without the necessary prestep of cokemaking. Coking ability of coals therefore is no prerequisite of suitability. Meanwhile the COREX Process is on its way to become established in ironmaking industry. COREX Plants at ISCOR, Pretoria/South Africa and POSCO Pohang/Korea, being in operation and those which will be started up during the next years comprise already an annual coal consumption capacity of approx. 5 Mio. tonnes mtr., which is a magnitude attracting the interest of industrial coal suppliers. The increasing importance of COREX as a comparable new technology forms also a demand for information regarding process requirements for raw material, especially coal, which is intended to be met here.

  11. Treatment of metal-laden hazardous wastes with advanced clean coal technology by-products. Quartery report, August 1994--November 1994

    SciTech Connect (OSTI)

    NONE

    1994-12-01T23:59:59.000Z

    This first quarterly report describes work during the first three months of the University of Pittsburgh`s (Pitt`s) project on the {open_quotes}Treatment of Metal-Laden Hazardous Wastes with Advanced Clean Coal Technology By-Products.{close_quotes} Participating with Pitt on this project are Dravo Lime Company (DLC), Mill Service, Inc. (MSO and the Center for Hazardous Materials Research (CHMR)). The report states the goals of the project - both general and specific - and then describes the activities of the project team during the reporting period. All of this work has been organizational and developmental in nature. No data has yet been collected. Technical details and data will appear for the first time in the second quarterly report and be the major topic of subsequent reports.

  12. Quarterly coal report, April 1996--June 1996

    SciTech Connect (OSTI)

    NONE

    1996-11-01T23:59:59.000Z

    This report provides information about U.S. coal production, distribution; exports, imports, prices, consumption, and stocks. Data on coke production is also provided. This report presents data for April 1996 thru June 1996.

  13. Developing the Sandia National Laboratories transportation infrastructure for isotope products and wastes

    SciTech Connect (OSTI)

    Trennel, A.J.

    1997-11-01T23:59:59.000Z

    The US Department of Energy (DOE) plans to establish a medical isotope project that would ensure a reliable domestic supply of molybdenum-99 ({sup 99}Mo) and related medical isotopes (Iodine-125, Iodine-131, and Xenon-133). The Department`s plan for production will modify the Annular Core Research Reactor (ACRR) and associated hot cell facility at Sandia National Laboratories (SNL)/New Mexico and the Chemistry and Metallurgy Research facility at Los Alamos National Laboratory (LANL). Transportation activities associated with such production is discussed.

  14. USE OF COAL DRYING TO REDUCE WATER CONSUMED IN PULVERIZED COAL POWER PLANTS

    SciTech Connect (OSTI)

    Edward Levy; Nenad Sarunac; Harun Bilirgen; Wei Zhang

    2005-04-01T23:59:59.000Z

    This is the ninth Quarterly Report for this project. The background and technical justification for the project are described, including potential benefits of reducing fuel moisture using power plant waste heat, prior to firing the coal in a pulverized coal boiler. During this last Quarter, comparative analyses were performed for lignite and PRB coals to determine how unit performance varies with coal product moisture. Results are given showing how the coal product moisture level and coal rank affect parameters such as boiler efficiency, station service power needed for fans and pulverizers and net unit heat rate. Results are also given for the effects of coal drying on cooling tower makeup water and comparisons are made between makeup water savings for various times of the year.

  15. RESEARCH & DEVELOPMENT TO PREPARE AND CHARACTERIZE ROBUST COAL/BIOMASS MIXTURES FOR DIRECT CO-FEEDING INTO GASIFICATION SYSTEMS

    SciTech Connect (OSTI)

    Felix, Larry; Farthing, William; Hoekman, S. Kent

    2014-12-31T23:59:59.000Z

    This project was initiated on October 1, 2010 and utilizes equipment and research supported by the Department of Energy, National Energy Technology Laboratory, under Award Number DE- FE0005349. It is also based upon previous work supported by the Department of Energy, National Energy Technology Laboratory, under Award Numbers DOE-DE-FG36-01GOl1082, DE-FG36-02G012011 or DE-EE0000272. The overall goal of the work performed was to demonstrate and assess the economic viability of fast hydrothermal carbonization (HTC) for transforming lignocellulosic biomass into a densified, friable fuel to gasify like coal that can be easily blended with ground coal and coal fines and then be formed into robust, weather-resistant pellets and briquettes. The specific objectives of the project include: • Demonstration of the continuous production of a uniform densified and formed feedstock from loblolly pine (a lignocellulosic, short rotation woody crop) in a hydrothermal carbonization (HTC) process development unit (PDU). • Demonstration that finely divided bituminous coal and HTC loblolly pine can be blended to form 90/10 and 70/30 weight-percent mixtures of coal and HTC biomass for further processing by pelletization and briquetting equipment to form robust weather resistant pellets and/or briquettes suitable for transportation and long term storage. • Characterization of the coal-biomass pellets and briquettes to quantify their physical properties (e.g. flow properties, homogeneity, moisture content, particle size and shape), bulk physical properties (e.g. compressibility, heat transfer and friability) and assess their suitability for use as fuels for commercially-available coal gasifiers. • Perform economic analyses using Aspen-based process simulations to determine the costs for deploying and operating HTC processing facilities for the production of robust coal/biomass fuels suitable for fueling commercially-available coal-fired gasifiers. This Final Project Scientific/Technical Report discusses and documents the project work required to meet each of these objectives.

  16. Annual bulletin of coal statistics for Europe-1983. [Europe, Canada, USA, USSR

    SciTech Connect (OSTI)

    Not Available

    1985-01-01T23:59:59.000Z

    This is a series of statistical tables documenting the production, trade, and consumption of coal in Europe, Canada, the United States, and the Soviet Union. Balance sheets of solid forms of energy are provided for hard coal, patent fuel, and coke; and for brown coal, brown coal briquettes, and brown coal coke. Data are provided on hard coal mines and on brown coal mines for production, employment and productivity of labor. Other tables list imports of solid fuels by country, exports of solid fuels by country, and world production of solid fuels.

  17. By-Products Utilization

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    clean coal technology, are not extensively utilized in the cast concrete masonry products (bricks both conventional and clean coal technologies. A clean coal ash is defined as the ash derived from SO2Center for By-Products Utilization USE OF CLASS F FLY ASH AND CLEAN-COAL ASH BLENDS FOR CAST

  18. By-Products Utilization

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    Fellow at the UWM-CBU. His research interests include the use of coal fly ash, coal bottom ash, and used in management, disposal, and sale of coal-combustion by-Center for By-Products Utilization USE OF UNDER-UTILIZED COAL- COMBUSTION PRODUCTS IN PERMEABLE

  19. By-Products Utilization

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    combustion by-products are generated due to the combustion of coal in coal-fired electric power plants as carbon from unburnt coal, fire polished sand, thin-walled hollow spheres and their fragments, magnetic of HVFA concrete to establish mixture proportions for commercial production. #12;INTRODUCTION Coal

  20. By-Products Utilization

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    Center for By-Products Utilization HIGH-STRENGTH HVFA CONCRETE CONTAINING CLEAN COAL ASH By Tarun R #12;1 HIGH-STRENGTH HVFA CONCRETE CONTAINING CLEAN COAL ASH By Tarun R. Naik, Shiw S. Singh, and Bruce for manufacture of cement-based products using ashes generated from combustion of high-sulfur coals. A clean coal

  1. By-Products Utilization

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    Center for By-Products Utilization CLEAN COAL BY-PRODUCTS UTILIZATION IN ROADWAY, EMBANKMENTS-fueled plants, particularly use of eastern coals, has lead to the use of clean coal and using advanced sulfur dioxide control technologies. Figure 1 shows clean coal technology benefits(2) . In 1977, the concept

  2. Process for treating moisture laden coal fines

    DOE Patents [OSTI]

    Davis, Burl E. (New Kensington, PA); Henry, Raymond M. (Gibsonia, PA); Trivett, Gordon S. (South Surrey, CA); Albaugh, Edgar W. (Birmingham, AL)

    1993-01-01T23:59:59.000Z

    A process is provided for making a free flowing granular product from moisture laden caked coal fines, such as wet cake, by mixing a water immiscible substance, such as oil, with the caked coal, preferably under low shear forces for a period of time sufficient to produce a plurality of free flowing granules. Each granule is preferably comprised of a dry appearing admixture of one or more coal particle, 2-50% by weight water and the water immiscible substance.

  3. Utilization of coal associated minerals. Quarterly report No. 11, April 1-June 30, 1980

    SciTech Connect (OSTI)

    Slonaker, J. F.; Akers, D. J.; Alderman, J. K.

    1980-08-29T23:59:59.000Z

    The purpose of this research program is to examine the effects of coal mineral materials on coal waste by-product utilization and to investigate new and improved methods for the utilization of waste by-products from cleaning, combustion and conversion processing of coal. The intermediate objectives include: (1) the examination of the effects of cleaning, gasification and combustion on coal mineral materials; and (2) the changes which occur in the coal wastes as a result of both form and distribution of mineral materials in feed coals in conjunction with the coal treatment effects resulting from coal cleaning or either gasification or combustion.

  4. Underground Coal Thermal Treatment

    SciTech Connect (OSTI)

    P. Smith; M. Deo; E. Eddings; A. Sarofim; K. Gueishen; M. Hradisky; K. Kelly; P. Mandalaparty; H. Zhang

    2011-10-30T23:59:59.000Z

    The long-term objective of this work is to develop a transformational energy production technology by insitu thermal treatment of a coal seam for the production of substitute natural gas (SNG) while leaving much of the coalâ??s carbon in the ground. This process converts coal to a high-efficiency, low-GHG emitting gas fuel. It holds the potential of providing environmentally acceptable access to previously unusable coal resources. This topical report discusses the development of experimental capabilities, the collection of available data, and the development of simulation tools to obtain process thermo-chemical and geo-thermal parameters in preparation for the eventual demonstration in a coal seam. It also includes experimental and modeling studies of CO{sub 2} sequestration. Efforts focused on: â?¢ Constructing a suite of three different coal pyrolysis reactors. These reactors offer the ability to gather heat transfer, mass transfer and kinetic data during coal pyrolysis under conditions that mimic in situ conditions (Subtask 6.1). â?¢ Studying the operational parameters for various underground thermal treatment processes for oil shale and coal and completing a design matrix analysis for the underground coal thermal treatment (UCTT). This analysis yielded recommendations for terms of targeted coal rank, well orientation, rubblization, presence of oxygen, temperature, pressure, and heating sources (Subtask 6.2). â?¢ Developing capabilities for simulating UCTT, including modifying the geometry as well as the solution algorithm to achieve long simulation times in a rubblized coal bed by resolving the convective channels occurring in the representative domain (Subtask 6.3). â?¢ Studying the reactive behavior of carbon dioxide (CO{sub 2}) with limestone, sandstone, arkose (a more complex sandstone) and peridotite, including mineralogical changes and brine chemistry for the different initial rock compositions (Subtask 6.4). Arkose exhibited the highest tendency of participating in mineral reactions, which can be attributed to the geochemical complexity of its initial mineral assemblage. In experiments with limestone, continuous dissolution was observed with the release of CO{sub 2} gas, indicated by the increasing pressure in the reactor (formation of a gas chamber). This occurred due to the lack of any source of alkali to buffer the solution. Arkose has the geochemical complexity for permanent sequestration of CO{sub 2} as carbonates and is also relatively abundant. The effect of including NH{sub 3} in the injected gas stream was also investigated in this study. Precipitation of calcite and trace amounts of ammonium zeolites was observed. A batch geochemical model was developed using Geochemists Workbench (GWB). Degassing effect in the experiments was corrected using the sliding fugacity model in GWB. Experimental and simulation results were compared and a reasonable agreement between the two was observed.

  5. Potential for Coal-to-Liquids Conversion in the U.S.-Resource Base

    E-Print Network [OSTI]

    Patzek, Tadeusz W.

    Potential for Coal-to-Liquids Conversion in the U.S.-Resource Base Gregory D. Croft1 and Tad W the multi-Hubbert curve analysis to coal production in the United States, we demonstrate that anthracite production of this highest-rank coal. The pro- duction of bituminous coal from existing mines is about 80

  6. Clean Coal Technology Demonstration Program: Project fact sheets 2000, status as of June 30, 2000

    SciTech Connect (OSTI)

    NONE

    2000-09-01T23:59:59.000Z

    The Clean Coal Technology Demonstration Program (CCT Program), a model of government and industry cooperation, responds to the Department of Energy's (DOE) mission to foster a secure and reliable energy system that is environmentally and economically sustainable. The CCT Program represents an investment of over $5.2 billion in advanced coal-based technology, with industry and state governments providing an unprecedented 66 percent of the funding. With 26 of the 38 active projects having completed operations, the CCT Program has yielded clean coal technologies (CCTs) that are capable of meeting existing and emerging environmental regulations and competing in a deregulated electric power marketplace. The CCT Program is providing a portfolio of technologies that will assure that U.S. recoverable coal reserves of 274 billion tons can continue to supply the nation's energy needs economically and in an environmentally sound manner. As the nation embarks on a new millennium, many of the clean coal technologies have realized commercial application. Industry stands ready to respond to the energy and environmental demands of the 21st century, both domestically and internationally, For existing power plants, there are cost-effective environmental control devices to control sulfur dioxide (S02), nitrogen oxides (NO,), and particulate matter (PM). Also ready is a new generation of technologies that can produce electricity and other commodities, such as steam and synthetic gas, and provide efficiencies and environmental performance responsive to global climate change concerns. The CCT Program took a pollution prevention approach as well, demonstrating technologies that remove pollutants or their precursors from coal-based fuels before combustion. Finally, new technologies were introduced into the major coal-based industries, such as steel production, to enhance environmental performance. Thanks in part to the CCT Program, coal--abundant, secure, and economical--can continue in its role as a key component in the U.S. and world energy markets. The CCT Program also has global importance in providing clean, efficient coal-based technology to a burgeoning energy market in developing countries largely dependent on coal. Based on 1997 data, world energy consumption is expected to increase 60 percent by 2020, with almost half of the energy increment occurring in developing Asia (including China and India). By 2020, energy consumption in developing Asia is projected to surpass consumption in North America. The energy form contributing most to the growth is electricity, as developing Asia establishes its energy infrastructure. Coal, the predominant indigenous fuel, in that region will be the fuel of choice in electricity production. The CCTs offer a means to mitigate potential environmental problems associated with unprecedented energy growth, and to enhance the U.S. economy through foreign equipment sales and engineering services.

  7. Fluidized-bed bioreactor process for the microbial solubiliztion of coal

    DOE Patents [OSTI]

    Scott, Charles D. (Oak Ridge, TN); Strandberg, Gerald W. (Farragut, TN)

    1989-01-01T23:59:59.000Z

    A fluidized-bed bioreactor system for the conversion of coal into microbially solubilized coal products. The fluidized-bed bioreactor continuously or periodically receives coal and bio-reactants and provides for the production of microbially solubilized coal products in an economical and efficient manner. An oxidation pretreatment process for rendering coal uniformly and more readily susceptible to microbial solubilization may be employed with the fluidized-bed bioreactor.

  8. Fluidized-bed bioreactor system for the microbial solubilization of coal

    DOE Patents [OSTI]

    Scott, C.D.; Strandberg, G.W.

    1987-09-14T23:59:59.000Z

    A fluidized-bed bioreactor system for the conversion of coal into microbially solubilized coal products. The fluidized-bed bioreactor continuously or periodically receives coal and bio-reactants and provides for the production of microbially solubilized coal products in an economical and efficient manner. An oxidation pretreatment process for rendering coal uniformly and more readily susceptible to microbial solubilization may be employed with the fluidized-bed bioreactor. 2 figs.

  9. Fixed-bed bioreactor system for the microbial solubilization of coal

    DOE Patents [OSTI]

    Scott, C.D.; Strandberg, G.W.

    1987-09-14T23:59:59.000Z

    A fixed-bed bioreactor system for the conversion of coal into microbially solubilized coal products. The fixed-bed bioreactor continuously or periodically receives coal and bio-reactants and provides for the large scale production of microbially solubilized coal products in an economical and efficient manner. An oxidation pretreatment process for rendering coal uniformly and more readily susceptible to microbial solubilization may be employed with the fixed-bed bioreactor. 1 fig., 1 tab.

  10. Cleantech: Innovative Lab Partnership Reduces Emissions from Coal

    Broader source: Energy.gov [DOE]

    Learn how the National Energy Technology Laboratory is working to reduce the emission of pollutants from existing coal-fired power plants.

  11. Supporting Information for: A Global Comparison of National Biodiesel Production Potentials

    E-Print Network [OSTI]

    Wisconsin at Madison, University of

    Supporting Information for: A Global Comparison of National Biodiesel Production Potentials Matt Biodiesel Potential · Table S.2: Variables Used in Calculating Biodiesel Volumes and Prices · Figure S.3: U) · Table S.5: Well-Managed Vegetable Oil Yields · Table S.6: A Complete List of Absolute Biodiesel

  12. Coal Industry Annual 1995

    SciTech Connect (OSTI)

    NONE

    1996-10-01T23:59:59.000Z

    This report presents data on coal consumption, coal distribution, coal stocks, coal prices, coal quality, and emissions for Congress, Federal and State agencies, the coal industry, and the general public. Appendix A contains a compilation of coal statistics for the major coal-producing States. This report does not include coal consumption data for nonutility power producers that are not in the manufacturing, agriculture, mining, construction, or commercial sectors. Consumption for nonutility power producers not included in this report is estimated to be 21 million short tons for 1995.

  13. Coal industry annual 1996

    SciTech Connect (OSTI)

    NONE

    1997-11-01T23:59:59.000Z

    This report presents data on coal consumption, coal distribution, coal stocks, coal prices, and coal quality, and emissions for Congress, Federal and State agencies, the coal industry, and the general public. Appendix A contains a compilation of coal statistics for the major coal-producing States.This report does not include coal consumption data for nonutility power producers that are not in the manufacturing, agriculture, mining, construction, or commercial sectors. Consumption for nonutility power producers not included in this report is estimated to be 24 million short tons for 1996. 14 figs., 145 tabs.

  14. Sustainable Transportation Fuels from Natural Gas (H{sub 2}), Coal and Biomass

    SciTech Connect (OSTI)

    Huffman, Gerald

    2012-12-31T23:59:59.000Z

    This research program is focused primarily on the conversion of coal, natural gas (i.e., methane), and biomass to liquid fuels by Fischer-Tropsch synthesis (FTS), with minimum production of carbon dioxide. A complementary topic also under investigation is the development of novel processes for the production of hydrogen with very low to zero production of CO{sub 2}. This is in response to the nation?s urgent need for a secure and environmentally friendly domestic source of liquid fuels. The carbon neutrality of biomass is beneficial in meeting this goal. Several additional novel approaches to limiting carbon dioxide emissions are also being explored.

  15. Thermal-Hydrological Sensitivity Analysis of Underground Coal Gasification

    SciTech Connect (OSTI)

    Buscheck, T A; Hao, Y; Morris, J P; Burton, E A

    2009-10-05T23:59:59.000Z

    This paper presents recent work from an ongoing project at Lawrence Livermore National Laboratory (LLNL) to develop a set of predictive tools for cavity/combustion-zone growth and to gain quantitative understanding of the processes and conditions (natural and engineered) affecting underground coal gasification (UCG). We discuss the application of coupled thermal-hydrologic simulation capabilities required for predicting UCG cavity growth, as well as for predicting potential environmental consequences of UCG operations. Simulation of UCG cavity evolution involves coupled thermal-hydrological-chemical-mechanical (THCM) processes in the host coal and adjoining rockmass (cap and bedrock). To represent these processes, the NUFT (Nonisothermal Unsaturated-saturated Flow and Transport) code is being customized to address the influence of coal combustion on the heating of the host coal and adjoining rock mass, and the resulting thermal-hydrological response in the host coal/rock. As described in a companion paper (Morris et al. 2009), the ability to model the influence of mechanical processes (spallation and cavity collapse) on UCG cavity evolution is being developed at LLNL with the use of the LDEC (Livermore Distinct Element Code) code. A methodology is also being developed (Morris et al. 2009) to interface the results of the NUFT and LDEC codes to simulate the interaction of mechanical and thermal-hydrological behavior in the host coal/rock, which influences UCG cavity growth. Conditions in the UCG cavity and combustion zone are strongly influenced by water influx, which is controlled by permeability of the host coal/rock and the difference between hydrostatic and cavity pressure. In this paper, we focus on thermal-hydrological processes, examining the relationship between combustion-driven heat generation, convective and conductive heat flow, and water influx, and examine how the thermal and hydrologic properties of the host coal/rock influence those relationships. Specifically, we conducted a parameter sensitivity analysis of the influence of thermal and hydrological properties of the host coal, caprock, and bedrock on cavity temperature and steam production.

  16. ENCOAL mild coal gasification demonstration project. Annual report, October 1994--September 1995

    SciTech Connect (OSTI)

    NONE

    1996-01-01T23:59:59.000Z

    This document is the combination of the fourth quarter report (July - September 1995) and the 1995 annual report for the ENCOAL project. The following pages include the background and process description for the project, brief summaries of the accomplishments for the first three quarters, and a detailed fourth quarter report. Its purpose is to convey the accomplishments and current progress of the project. ENCOAL Corporation, a wholly-owned subsidiary of SMC Mining Company (formerly Shell Mining company, now owned by Zeigler Coal Holding Company), has completed the construction and start-up of a mild gasification demonstration plant at Triton Coal Company`s Buckskin Mine near Gillette, Wyoming. The process, using Liquids From Coal (LFC) technology developed by SMC and SGI International, utilizes low-sulfur Powder River Basis coal to produce two new fuels, Process Derived Fuel (PDF) and Coal Derived Liquids (CDL). The products, as alternative fuels sources, are expected to significantly lower current sulfur emissions at industrial and utility boiler sites throughout the nation, thereby reducing pollutants causing acid rain. In the LFC technology, coal is first deeply dried to remove water physically. The temperature is further raised in a second stage which results in decomposition reactions that form the new products. This chemical decomposition (mild gasification) creates gases by cracking reactions from the feed coal. The chemically altered solids are cooled and further processed to make PDF. The gases are cooled, condensing liquids as CDL, and the residual gases are burned in the process for heat. The process release for the ENCOAL plant predicted that one ton of feed coal would yield roughly {1/2} ton of PDF and {1/2} barrel of CDL. By varying plant running conditions, however, it has since been learned that the actual CDL recovery rate may be as much as 15% to 20% above the projections.

  17. Clean coal

    SciTech Connect (OSTI)

    Liang-Shih Fan; Fanxing Li [Ohio State University, OH (United States). Dept. of Chemical and Biomolecular Engineering

    2006-07-15T23:59:59.000Z

    The article describes the physics-based techniques that are helping in clean coal conversion processes. The major challenge is to find a cost- effective way to remove carbon dioxide from the flue gas of power plants. One industrially proven method is to dissolve CO{sub 2} in the solvent monoethanolamine (MEA) at a temperature of 38{sup o}C and then release it from the solvent in another unit when heated to 150{sup o}C. This produces CO{sub 2} ready for sequestration. Research is in progress with alternative solvents that require less energy. Another technique is to use enriched oxygen in place of air in the combustion process which produces CO{sub 2} ready for sequestration. A process that is more attractive from an energy management viewpoint is to gasify coal so that it is partially oxidized, producing a fuel while consuming significantly less oxygen. Several IGCC schemes are in operation which produce syngas for use as a feedstock, in addition to electricity and hydrogen. These schemes are costly as they require an air separation unit. Novel approaches to coal gasification based on 'membrane separation' or chemical looping could reduce the costs significantly while effectively capturing carbon dioxide. 1 ref., 2 figs., 1 photo.

  18. Waste Processing To Support {sup 99}Mo Production at Sandia National Laboratories

    SciTech Connect (OSTI)

    Longley, Susan; Carson, Susan; McDonald, Marion

    1997-06-01T23:59:59.000Z

    As part of the Isotope Production Program at Sandia National Laboratories New Mexico (SNL/NM), procedures are being finalized for the production of {sup 99}Mo from the irradiation of {sup 235}U-coated stainless steel targets at the Technical Area (TA) V reactor and hot cell facilities. Methods have been identified and tested for the management of the non-product (waste) material as the final step in the production process. These methods were developed utilizing the waste material from a series of cold and hot tests, beginning with depleted uranium powder and culminating with a test involving an irradiated {sup 235}U target with an initial fission product inventory of approximately 18,000 Ci at the end of the irradiation cycle.

  19. Carbon Dioxide Sequestration in Geologic Coal Formations

    SciTech Connect (OSTI)

    None

    2001-09-30T23:59:59.000Z

    BP Corporation North America, Inc. (BP) currently operates a nitrogen enhanced recovery project for coal bed methane at the Tiffany Field in the San Juan Basin, Colorado. The project is the largest and most significant of its kind wherein gas is injected into a coal seam to recover methane by competitive adsorption and stripping. The Idaho National Engineering and Environmental Laboratory (INEEL) and BP both recognize that this process also holds significant promise for the sequestration of carbon dioxide, a greenhouse gas, while economically enhancing the recovery of methane from coal. BP proposes to conduct a CO2 injection pilot at the tiffany Field to assess CO2 sequestration potential in coal. For its part the INEEL will analyze information from this pilot with the intent to define the Co2 sequestration capacity of coal and its ultimate role in ameliorating the adverse effects of global warming on the nation and the world.

  20. Hoe Creek experiments: LLNL's underground coal-gasification project in Wyoming

    SciTech Connect (OSTI)

    Stephens, D.R.

    1981-10-01T23:59:59.000Z

    Under the sponsorship of the US Department of Energy and predecessor organizations, the Lawrence Livermore National Laboratory carried out a laboratory program and three field, underground coal gasification tests near Gillette, Wyoming. This report summarizes that work. Three methods of linking or connecting injection and production wells were used for the UCG field tests: Hoe Creek No. 1 employed explosive fracturing, Hoe Creek No. 2 featured use of reverse combustion, and directional drilling was used for the Hoe Creek No. 3. The Gas Research Institute cosponsored the latter test. Laboratory experiments and modeling, together with a laboratory and field environment program, are necessary adjuncts to the field program. Explosive fracturing in coal was simulated using computer models and laboratory tests. We developed a relationship of total inelastic strains to permeability, which we used to design and interpret a coal outcrop, explosive fracturing experiment at Kemmerer, Wyoming. Coal gasification was also simulated in laboratory experiments and with computer models. The primary aim has been to predict and correlate reaction, thermal-front propagation rates, and product gas composition as a function of bed properties and process operating conditions. Energy recovery in the form of produced gas and liquids amounted to 73% of the energy in the consumed coal. There were essentially no losses to the subsurface formation. The greatest energy loss was in steam production.

  1. Present coal potential of Turkey and coal usage in electricity generation

    SciTech Connect (OSTI)

    Yilmaz, A.O. [Karadeniz Technical University, Trabzon (Turkey). Mining Engineering Department

    2009-07-01T23:59:59.000Z

    Total coal reserve (hard coal + lignite) in the world is 984 billion tons. While hard coal constitutes 52% of the total reserve, lignite constitutes 48% of it. Turkey has only 0.1% of world hard coal reserve and 1.5% of world lignite reserves. Turkey has 9th order in lignite reserve, 8th order in lignite production, and 12th order in total coal (hard coal and lignite) consumption. While hard coal production meets only 13% of its consumption, lignite production meets lignite consumption in Turkey. Sixty-five percent of produced hard coal and 78% of produced lignite are used for electricity generation. Lignites are generally used for electricity generation due to their low quality. As of 2003, total installed capacity of Turkey was 35,587 MW, 19% (6,774 MW) of which is produced from coal-based thermal power plants. Recently, use of natural gas in electricity generation has increased. While the share of coal in electricity generation was about 50% for 1986, it is replaced by natural gas today.

  2. DESULFURIZATION OF COAL MODEL COMPOUNDS AND COAL LIQUIDS

    E-Print Network [OSTI]

    Wrathall, James Anthony

    2011-01-01T23:59:59.000Z

    flow sheet of a K-T coal gasification complex for producingslag or bottom ash, coal gasification, or coal liquefactionCoal (Ref. 46). COAL PREPARATION GASIFICATION 3 K·T GASI FI

  3. Coal Bed Methane Primer

    SciTech Connect (OSTI)

    Dan Arthur; Bruce Langhus; Jon Seekins

    2005-05-25T23:59:59.000Z

    During the second half of the 1990's Coal Bed Methane (CBM) production increased dramatically nationwide to represent a significant new source of income and natural gas for many independent and established producers. Matching these soaring production rates during this period was a heightened public awareness of environmental concerns. These concerns left unexplained and under-addressed have created a significant growth in public involvement generating literally thousands of unfocused project comments for various regional NEPA efforts resulting in the delayed development of public and fee lands. The accelerating interest in CBM development coupled to the growth in public involvement has prompted the conceptualization of this project for the development of a CBM Primer. The Primer is designed to serve as a summary document, which introduces and encapsulates information pertinent to the development of Coal Bed Methane (CBM), including focused discussions of coal deposits, methane as a natural formed gas, split mineral estates, development techniques, operational issues, producing methods, applicable regulatory frameworks, land and resource management, mitigation measures, preparation of project plans, data availability, Indian Trust issues and relevant environmental technologies. An important aspect of gaining access to federal, state, tribal, or fee lands involves education of a broad array of stakeholders, including land and mineral owners, regulators, conservationists, tribal governments, special interest groups, and numerous others that could be impacted by the development of coal bed methane. Perhaps the most crucial aspect of successfully developing CBM resources is stakeholder education. Currently, an inconsistent picture of CBM exists. There is a significant lack of understanding on the parts of nearly all stakeholders, including industry, government, special interest groups, and land owners. It is envisioned the Primer would being used by a variety of stakeholders to present a consistent and complete synopsis of the key issues involved with CBM. In light of the numerous CBM NEPA documents under development this Primer could be used to support various public scoping meetings and required public hearings throughout the Western States in the coming years.

  4. Quarterly coal report, April--June 1990

    SciTech Connect (OSTI)

    Not Available

    1990-11-02T23:59:59.000Z

    The Quarterly Coal Report provides comprehensive information about US coal production, exports, imports, receipts, consumption, and stocks to a wide audience, including Congress, Federal and State agencies, the coal industry, and the general public. This issue presents detailed quarterly data for April 1990 through June 1990, aggregated quarterly historical data for 1982 through the second quarter of 1990, and aggregated annual historical data for 1960 through 1989 and projected data for selected years from 1995 through 2010. To provide a complete picture of coal supply and demand in the United States, historical information and forecasts have been integrated in this report. 7 figs., 37 tabs.

  5. Continuing consolidation in the coal industry

    SciTech Connect (OSTI)

    Gaalaas, T. [Pace Global Energy Services LLC (United States)

    2006-08-15T23:59:59.000Z

    Extensive consolidation has occurred in the coal industry over the past decade. The greatest degree of consolidation has occurred in Northern Appalachia, the Illinois Basin, and the Wyoming portion of the Powder River Basin (PRB), which are the coal supply regions where most observers expect the greatest growth in coal production over the next decade. In addition to reducing the number of alternative suppliers, high level of concentration also tend to result in higher prices, more volatile spot markets, and lower levels of reliability. Therefore, coal-fired generators purchasing in these regions need to respond proactively and strategically to these market trends. 2 figs.

  6. Coal liquefaction process with enhanced process solvent

    DOE Patents [OSTI]

    Givens, Edwin N. (Bethlehem, PA); Kang, Dohee (Macungie, PA)

    1984-01-01T23:59:59.000Z

    In an improved coal liquefaction process, including a critical solvent deashing stage, high value product recovery is improved and enhanced process-derived solvent is provided by recycling second separator underflow in the critical solvent deashing stage to the coal slurry mix, for inclusion in the process solvent pool.

  7. Improved catalysts for carbon and coal gasification

    DOE Patents [OSTI]

    McKee, D.W.; Spiro, C.L.; Kosky, P.G.

    1984-05-25T23:59:59.000Z

    This invention relates to improved catalysts for carbon and coal gasification and improved processes for catalytic coal gasification for the production of methane. The catalyst is composed of at least two alkali metal salts and a particulate carbonaceous substrate or carrier is used. 10 figures, 2 tables.

  8. DERAILMENT IN WYOMING (2005) http://www.bigcountry.coop/coal.html

    E-Print Network [OSTI]

    Tesfatsion, Leigh

    2005-01-01T23:59:59.000Z

    Mountains to the west had begun to thaw. Icy water and coal dust merged into a thick, dirty slurry and oozed1 DERAILMENT IN WYOMING (2005) http://www.bigcountry.coop/coal.html [Johnson, 2005] Steven Johnson bottleneck in shipments from the nation's most important vein of low-sulfur coal has cut into coal supplies

  9. Coal is a combustible sedimentary rock and a valuable economic resource. During the Pennsylvanian Period

    E-Print Network [OSTI]

    Polly, David

    Coal is a combustible sedimentary rock and a valuable economic resource. During the Pennsylvanian of years produced the bituminous coals currently found in southwestern Indiana. Bituminous coals in Indiana currently ranks as the seventh-largest coal-producing state in the nation and has an estimated 17.57 billion

  10. Environmental data energy technology characterizations: coal

    SciTech Connect (OSTI)

    Not Available

    1980-04-01T23:59:59.000Z

    This document describes the activities leading to the conversion of coal to electricity. Specifically, the activities consist of coal mining and beneficiation, coal transport, electric power generation, and power transmission. To enhance the usefulness of the material presented, resource requirements, energy products, and residuals for each activity area are normalized in terms of 10/sup 12/ Btus of energy produced. Thus, the total effect of producing electricity from coal can be determined by combining the residuals associated with the appropriate activity areas. Emissions from the coal cycle are highly dependent upon the type of coal consumed as well as the control technology assigned to the activity area. Each area is assumed to be equipped with currently available control technologies that meet environmental regulations. The conventional boiler, for example, has an electrostatic precipitator and a flue gas desulfurization scrubber. While this results in the removal of most of the particulate matter and sulfur dioxide in the flue gas stream, it creates other new environmental residuals -- solid waste, sludge, and ash. There are many different types of mined coal. For informational purposes, two types from two major producing regions, the East and the West, are characterized here. The eastern coal is typical of the Northern Appalachian coal district with a high sulfur and heat content. The western coal, from the Powder River Basin, has much less sulfur, but also has a substantially lower heating value.

  11. Coal combustion science

    SciTech Connect (OSTI)

    Hardesty, D.R. (ed.); Baxter, L.L.; Fletcher, T.H.; Mitchell, R.E.

    1990-11-01T23:59:59.000Z

    The objective of this activity is to support the Office of Fossil Energy in executing research on coal combustion science. This activity consists of basic research on coal combustion that supports both the Pittsburgh Energy Technology Center (PETC) Direct Utilization Advanced Research and Technology Development Program, and the International Energy Agency (IEA) Coal Combustion Science Project. Specific tasks include: coal devolatilization, coal char combustion, and fate of mineral matter during coal combustion. 91 refs., 40 figs., 9 tabs.

  12. Coal distribution, January--June 1991

    SciTech Connect (OSTI)

    Not Available

    1991-10-21T23:59:59.000Z

    The Coal Distribution report provides information on coal production, distribution, and stocks in the United States to a wide audience including Congress, Federal and State agencies, the coal industry, and the general public. The data in this report are collected and published by the Energy Information Administration (EIA) to fulfill its data collection and dissemination responsibilities as specified in the Federal Energy Administration Act of 1974 (Public Law 93-275, Sections 5 and 13, as amended). This issue presents information for January through June 1991. Coal distribution data are shown (in Tables 1--34) by coal-producing Sate of origin, consumer use, method of transportation, and State of destination. All data in this report were collected by the EIA on Form EIA-6, Coal Distribution Report.'' A copy of the form and the instructions for filing appear in Appendix B. All data in this report for 1991 are preliminary. Data for previous years are final. 6 figs., 34 tabs.

  13. Rail Coal Transportation Rates

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122Commercial ConsumersThousand CubicCubic Feet) Yeara 436 EnergyAssemblyOrderCoal

  14. By Coal Destination State

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40Coal Stocks at CommercialDecade Year-0Proved Reserves (Billion0.060 U.S. Energy

  15. By Coal Destination State

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40Coal Stocks at CommercialDecade Year-0Proved Reserves (Billion0.060 U.S. Energy0

  16. By Coal Destination State

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40Coal Stocks at CommercialDecade Year-0Proved Reserves (Billion0.060 U.S. Energy00

  17. By Coal Destination State

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40Coal Stocks at CommercialDecade Year-0Proved Reserves (Billion0.060 U.S.

  18. By Coal Destination State

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40Coal Stocks at CommercialDecade Year-0Proved Reserves (Billion0.060 U.S.1 U.S.

  19. By Coal Destination State

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40Coal Stocks at CommercialDecade Year-0Proved Reserves (Billion0.060 U.S.1 U.S.1

  20. By Coal Destination State

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40Coal Stocks at CommercialDecade Year-0Proved Reserves (Billion0.060 U.S.1 U.S.11