Sample records for nasi sodium silicide

  1. Synthesis and design of silicide intermetallic materials

    SciTech Connect (OSTI)

    Petrovic, J.J.; Castro, R.G.; Butt, D.P.; Park, Y.; Hollis, K.J.; Kung, H.H.

    1998-11-01T23:59:59.000Z

    The overall objective of this program is to develop structural silicide-based materials with optimum combinations of elevated temperature strength/creep resistance, low temperature fracture toughness, and high temperature oxidation and corrosion resistance for applications of importance to the U.S. processing industry. A further objective is to develop silicide-based prototype industrial components. The ultimate aim of the program is to work with industry to transfer the structural silicide materials technology to the private sector in order to promote international competitiveness in the area of advanced high temperature materials and important applications in major energy-intensive U.S. processing industries.

  2. CX-000207: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    NaSi (Sodium Silicide) and Na-SG (Sodium Silica Gell) Powder Hydrogen Fuel CellsCX(s) Applied: B3.6Date: 11/23/2009Location(s): New YorkOffice(s): Energy Efficiency and Renewable Energy, Golden Field Office

  3. Kinetics and morphology of erbium silicide formation

    SciTech Connect (OSTI)

    Knapp, J.A.; Picraux, S.T.; Wu, C.S.; Lau, S.S.

    1985-11-15T23:59:59.000Z

    The growth kinetics and surface morphology of erbium silicide formation from Er layers on Si(100) substrates are examined using both fast e-beam annealing and furnace annealing. Very smooth erbium silicide layers have been grown using a line-source e beam to heat and react the Er overlayers with the substrate. This contrasts to the severe pitting observed when Er layers are reacted with Si in conventional furnace annealing. The pitting phenomenon can be explained by a thin contaminant layer at the interface between Er and Si. Our results suggest the contamination barrier is not due to oxygen, as usually assumed, but may be related to the presence of carbon. Rapid e-beam heating to reaction temperatures of approx.1200 K permits dispersion of the barrier layer before substantial silicide growth can occur, allowing smooth silicide growth. Heating to shorter times to just disperse the interface barrier allows uniform layer growth by subsequent furnace annealing and has permitted measurement of the kinetics of erbium silicide formation on crystalline Si. The reaction obeys (time)/sup 1//sup ///sup 2/ kinetics but is shown to be not totally diffusion limited by the ability to sustain multiple interface growth from a single Si source. The growth rates are nearly an order of magnitude slower for the Er/Si(100) interface than for the Er/amorphous-Si, but with a similar activation energy near 1.75 eV in both cases.

  4. High-Performance Thermoelectric Devices Based on Abundant Silicide...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Reports of methods to synthesize single-crystal and poly or nano- crystalline p- and n-type higher manganese silicides to reduce lattice thermal conductivity...

  5. Carbon or boron modified titanium silicide

    DOE Patents [OSTI]

    Thom, Andrew J. (Slater, IA); Akinc, Mufit (Ames, IA)

    1996-12-03T23:59:59.000Z

    A titanium silicide material based on Ti.sub.5 Si.sub.3 intermetallic compound exhibits substantially improved oxidative stability at elevated temperatures. In particular, carbon is added to a Ti.sub.5 Si.sub.3 base material in an amount (e.g. about 0.3 to about 3.6 weight % C) effective to impart substantially improved oxidative stability at elevated temperatures, such as about 1000.degree. C. Boron is added to a Ti.sub.5 Si.sub.3 base material in an amount (e.g. about 0.3 to about 3.3 weight % B) to this same end.

  6. Carbon or boron modified titanium silicide

    DOE Patents [OSTI]

    Thom, Andrew J. (Slater, IA); Akinc, Mufit (Ames, IA)

    1997-12-02T23:59:59.000Z

    A titanium silicide material based on Ti.sub.5 Si.sub.3 intermetallic compound exhibits substantially improved oxidative stability at elevated temperatures. In particular, carbon is added to a Ti.sub.5 Si.sub.3 base material in an amount (e.g. about 0.3 to about 3.6 weight % C) effective to impart substantially improved oxidative stability at elevated temperatures, such as about 1000.degree. C. Boron is added to a Ti.sub.5 Si.sub.3 base material in an amount (e.g. about 0.3 to about 3.3 weight % B) to this same end.

  7. Carbon or boron modified titanium silicide

    DOE Patents [OSTI]

    Thom, Andrew J. (Slater, IA); Akinc, Mufit (Ames, IA)

    1998-07-14T23:59:59.000Z

    A titanium silicide material based on Ti.sub.5 Si.sub.3 intermetallic compound exhibits substantially improved oxidative stability at elevated temperatures. In particular, carbon is added to a Ti.sub.5 Si.sub.3 base material in an amount (e.g. about 0.3 to about 3.6 weight % C) effective to impart substantially improved oxidative stability at elevated temperatures, such as about 1000.degree. C. Boron is added to a Ti.sub.5 Si.sub.3 base material in an amount (e.g. about 0.3 to about 3.3 weight % B) to this same end.

  8. Boron modified molybdenum silicide and products

    DOE Patents [OSTI]

    Meyer, Mitchell K. (Idaho Falls, ID); Akinc, Mufit (Ames, IA)

    1999-02-02T23:59:59.000Z

    A boron-modified molybdenum silicide material having the composition comprising about 80 to about 90 weight % Mo, about 10 to about 20 weight % Si, and about 0.1 to about 2 weight % B and a multiphase microstructure including Mo.sub.5 Si.sub.3 phase as at least one microstructural component effective to impart good high temperature creep resistance. The boron-modified molybdenum silicide material is fabricated into such products as electrical components, such as resistors and interconnects, that exhibit oxidation resistance to withstand high temperatures in service in air as a result of electrical power dissipation, electrical resistance heating elements that can withstand high temperatures in service in air and other oxygen-bearing atmospheres and can span greater distances than MoSi.sub.2 heating elements due to improved creep resistance, and high temperature structural members and other fabricated components that can withstand high temperatures in service in air or other oxygen-bearing atmospheres while retaining creep resistance associated with Mo.sub.5 Si.sub.3 for structural integrity.

  9. Boron modified molybdenum silicide and products

    DOE Patents [OSTI]

    Meyer, M.K.; Akinc, M.

    1999-02-02T23:59:59.000Z

    A boron-modified molybdenum silicide material is disclosed having the composition comprising about 80 to about 90 weight % Mo, about 10 to about 20 weight % Si, and about 0.1 to about 2 weight % B and a multiphase microstructure including Mo{sub 5}Si{sub 3} phase as at least one microstructural component effective to impart good high temperature creep resistance. The boron-modified molybdenum silicide material is fabricated into such products as electrical components, such as resistors and interconnects, that exhibit oxidation resistance to withstand high temperatures in service in air as a result of electrical power dissipation, electrical resistance heating elements that can withstand high temperatures in service in air and other oxygen-bearing atmospheres and can span greater distances than MoSi{sub 2} heating elements due to improved creep resistance, and high temperature structural members and other fabricated components that can withstand high temperatures in service in air or other oxygen-bearing atmospheres while retaining creep resistance associated with Mo{sub 5}Si{sub 3} for structural integrity. 7 figs.

  10. Epitaxial growth of rare-earth silicides on (111) Si

    SciTech Connect (OSTI)

    Knapp, J.A.; Picraux, S.T.

    1986-02-17T23:59:59.000Z

    Rapid heating with an electron beam has been used to react overlayers of rare-earth (RE) metals with (111) Si, forming epitaxial layers of silicides of Y, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu. Under conventional furnace annealing, forming such silicides on Si typically leads to rough, pitted surfaces. The use of fast beam heating not only results in a much smoother surface topology but also helps promote epitaxial growth on (111) Si in both solid and liquid phase reactions. These epitaxial silicides have a hexagonal RESi/sub approximately1.7/ structure (defected AlB/sub 2/ type). Their orientation with the Si substrate is (0001)parallel(111), with predicted lattice mismatches ranging from +0.83 to -2.55%.

  11. Simultaneous synthesis and densication of niobium silicide/niobium composites

    E-Print Network [OSTI]

    Paulino, Glaucio H.

    with or without subsequent self-propagating high-temperature synthesis (SHS) [9±11], and mechanical alloying sintering; Self-propagating high-tempera- ture synthesis Introduction Refractory metal silicides application as a high-temperature structural materials [1]. However, their brittleness at room temperature

  12. Fuel-cycle cost comparisons with oxide and silicide fuels

    SciTech Connect (OSTI)

    Matos, J.E.; Freese, K.E.

    1982-01-01T23:59:59.000Z

    This paper addresses fuel cycle cost comparisons for a generic 10 MW reactor with HEU aluminide fuel and with LEU oxide and silicide fuels in several fuel element geometries. The intention of this study is to provide a consistent assessment of various design options from a cost point of view. Fuel cycle cost benefits could result if a number of reactors were to utilize fuel elements with the same number or different numbers of the same standard fuel plate. Data are presented to quantify these potential cost benefits. This analysis shows that there are a number of fuel element designs using LEU oxide or silicide fuels that have either the same or lower total fuel cycle costs than the HEU design. Use of these fuels with the uranium densities considered requires that they are successfully demonstrated and licensed.

  13. Formation of low resistivity titanium silicide gates in semiconductor integrated circuits

    DOE Patents [OSTI]

    Ishida, Emi (Sunnyvale, CA)

    1999-08-10T23:59:59.000Z

    A method of forming a titanium silicide (69) includes the steps of forming a transistor having a source region (58), a drain region (60) and a gate structure (56) and forming a titanium layer (66) over the transistor. A first anneal is performed with a laser anneal at an energy level that causes the titanium layer (66) to react with the gate structure (56) to form a high resistivity titanium silicide phase (68) having substantially small grain sizes. The unreacted portions of the titanium layer (66) are removed and a second anneal is performed, thereby causing the high resistivity titanium silicide phase (68) to convert to a low resistivity titanium silicide phase (69). The small grain sizes obtained by the first anneal allow low resistivity titanium silicide phase (69) to be achieved at device geometries less than about 0.25 micron.

  14. High Current Effects in Silicide Films for Sub-0.25 pm VLSI Technologies

    E-Print Network [OSTI]

    to self-heating. Two physical parameters, B and h, associated with DC and pulsed current stress, have been current and self-heating effects [4,5] in these silicides. This paper will present important parameters

  15. Titanium Silicide Islands on Atomically Clean Si(100): Identifying Single Electron Tunneling Effects

    E-Print Network [OSTI]

    Joseph L. Tedesco; J. E. Rowe; Robert J. Nemanich

    2010-07-28T23:59:59.000Z

    Titanium silicide islands have been formed by the ultrahigh vacuum deposition of thin films of titanium (electron tunneling (SET) according to the orthodox model of SET. Some of the islands formed are small enough (diameter reliability of future devices.

  16. Effects of temperature dependent pre-amorphization implantation on NiPt silicide formation and thermal stability on Si(100)

    SciTech Connect (OSTI)

    Ozcan, Ahmet S.; Wall, Donald [IBM Semiconductor Research and Development Center, 2070 Route 52, Hopewell Junction, New York 12533 (United States)] [IBM Semiconductor Research and Development Center, 2070 Route 52, Hopewell Junction, New York 12533 (United States); Jordan-Sweet, Jean; Lavoie, Christian [IBM T. J. Watson Research Center, 1101 Kitchawan Road, Yorktown Heights, New York 10598 (United States)] [IBM T. J. Watson Research Center, 1101 Kitchawan Road, Yorktown Heights, New York 10598 (United States)

    2013-04-29T23:59:59.000Z

    Using temperature controlled Si and C ion implantation, we studied the effects of pre-amorphization implantation on NiPt alloy silicide phase formation. In situ synchrotron x-ray diffraction and resistance measurements were used to monitor phase and morphology evolution in silicide films. Results show that substrate amorphization strongly modulate the nucleation of silicide phases, regardless of implant species. However, morphological stability of the thin films is mainly enhanced by C addition, independently of the amorphization depth.

  17. Sodium Titanate Anodes for Sodium Ion Batteries

    E-Print Network [OSTI]

    Doeff, Marca M.

    2014-01-01T23:59:59.000Z

    for  Sodium  Ion  Batteries   One   of   the   challenges  of   sodium   ion   batteries   is   identification   of  for   use   in   batteries.   Our   recent   work   has  

  18. Thermal Analysis of a Uranium Silicide Miniplate Irradiation Experiment

    SciTech Connect (OSTI)

    Donna Post Guillen

    2009-09-01T23:59:59.000Z

    This paper outlines the thermal analysis for the irradiation of high density uranium-silicide (U3Si2 dispersed in an aluminum matrix and clad in aluminum) booster fuel for a Boosted Fast Flux Loop designed to provide fast neutron flux test capability in the ATR. The purpose of this experiment (designated as Gas Test Loop-1 [GTL-1]) is two-fold: (1) to assess the adequacy of the U3Si2/Al dispersion fuel and the aluminum alloy 6061 cladding, and (2) to verify stability of the fuel cladding boehmite pre-treatment at nominal power levels in the 430 to 615 W/cm2 (2.63 to 3.76 Btu/s•in2) range. The GTL-1 experiment relies on a difficult balance between achieving a high heat flux, yet keeping fuel centerline temperature below a specified maximum value throughout an entire operating cycle of the reactor. A detailed finite element model was constructed to calculate temperatures and heat flux levels and to reveal which experiment parameters place constraints on reactor operations. Analyses were performed to determine the bounding lobe power level at which the experiment could be safely irradiated, yet still provide meaningful data under nominal operating conditions. Then, simulations were conducted for nominal and bounding lobe power levels under steady-state and transient conditions with the experiment in the reactor. Reactivity changes due to a loss of commercial power with pump coast-down to emergency flow or a standard in-pile tube pump discharge break were evaluated. The time after shutdown for which the experiment can be adequately cooled by natural convection cooling was determined using a system thermal hydraulic model. An analysis was performed to establish the required in-reactor cooling time prior to removal of the experiment from the reactor. The inclusion of machining tolerances in the numerical model has a large effect on heat transfer.

  19. Rocket-propellant burn tests of silicide-coated niobium and tantalum

    SciTech Connect (OSTI)

    Curtis, P.G.; Krikorian, O.H.; Helm, F.H.

    1988-04-20T23:59:59.000Z

    Coatings designed to protect refractory metals in fire situations were tested on niobium and tantalum in a furnace and in a rocket-fuel flame. The best performance was obtained from Cr-Si-type silicide coatings applied by the pack-cementation process. The main mode of failure of the coated parts was corrosion by molten stainless steel rather than oxidation.

  20. High pressure studies on uranium and thorium silicide compounds: Experiment S. Yagoubi a,b,c,

    E-Print Network [OSTI]

    Svane, Axel Torstein

    High pressure studies on uranium and thorium silicide compounds: Experiment and theory S. Yagoubi a, USi3, as well as some non-stoichiometric phases presented in Table 1. Among the thoriumB-type) that a ferromagnetic ordering is reported, with TC = 127 K and a saturated moment of 0.1 lB [3]. Concerning the thorium

  1. Silicides for infrared surface plasmon resonance biosensors J. W. Cleary1

    E-Print Network [OSTI]

    Peale, Robert E.

    Silicides for infrared surface plasmon resonance biosensors J. W. Cleary1 , R. E. Peale1,2 , D, University of Central Florida, 4000 Central Florida Blvd., Orlando, FL 32816, U.S.A. 3 AFRL/RYHC, Sensors on silicon were evaluated as conducting hosts for surface plasmon polaritons (SPP) in proposed long-wave IR

  2. The new ternary silicide Gd5CoSi2 : structural, magnetic and magnetocaloric properties

    E-Print Network [OSTI]

    Boyer, Edmond

    compounds exhibiting such huge effect has exploded. Indeed, an MCE can be used in the magnetic refrigeration working efficiency for applications in magnetic refrigeration [2], [3] and [4]. In this viewThe new ternary silicide Gd5CoSi2 : structural, magnetic and magnetocaloric properties Mayer C

  3. Tungsten silicide and tungsten polycide anisotropic dry etch process for highly controlled dimensions and profiles

    E-Print Network [OSTI]

    Bashir, Rashid

    dimensions and profiles R. Bashir,a),b) A. E. Kabir,b) F. Hebert,c) and C. Brackenb) National Semiconductors. In many applications a spacer needs to be formed on the polycide sidewall Fig. 1 . Undesirable undercutting can re- sult in nonideal spacer formation for further device fabrica- tion. Tungsten silicide

  4. Sodium Titanates as Anodes for Sodium Ion Batteries

    E-Print Network [OSTI]

    Doeff, Marca M.

    2014-01-01T23:59:59.000Z

    Anodes  for  Sodium  Ion  Batteries   Marca  M.  Doeff,  dual   intercalation   batteries   based   on   sodium  future   of   sodium  ion  batteries  will  be  discussed  

  5. Pt silicide/poly-Si Schottky diodes as temperature sensors for bolometers

    E-Print Network [OSTI]

    Yuryev, V A; Chapnin, V A; Mironov, S A; Dubkov, V P; Uvarov, O V; Kalinushkin, V P; Senkov, V M; Nalivaiko, O Y; Novikau, A G; Gaiduk, P I

    2015-01-01T23:59:59.000Z

    Platinum silicide Schottky diodes formed on films of polycrystalline Si doped by phosphorus are demonstrated to be efficient and manufacturable CMOS-compatible temperature sensors for microbolometer detectors of radiation. Thin-film platinum silicide/poly-Si diodes have been produced by a CMOS-compatible process on artificial Si$_3$N$_4$/SiO$_2$/Si(001) substrates simulating the bolometer cells. Layer structure and phase composition of the original Pt/poly-Si films and the Pt silicide/poly-Si films synthesized by a low-temperature process have been studied by means of the scanning transmission electron microscopy; they have also been explored by means of the two-wavelength X-ray structural phase analysis and the X-ray photoelectron spectroscopy. Temperature coefficient of voltage for the forward current of a single diode is shown to reach the value of about $-$2%/$^{\\circ}$C in the temperature interval from 25 to 50$^{\\circ}$C.

  6. Microalloying of transition metal silicides by mechanical activation and field-activated reaction

    DOE Patents [OSTI]

    Munir, Zuhair A. (Davis, CA); Woolman, Joseph N. (Davis, CA); Petrovic, John J. (Los Alamos, NM)

    2003-09-02T23:59:59.000Z

    Alloys of transition metal suicides that contain one or more alloying elements are fabricated by a two-stage process involving mechanical activation as the first stage and densification and field-activated reaction as the second stage. Mechanical activation, preferably performed by high-energy planetary milling, results in the incorporation of atoms of the alloying element(s) into the crystal lattice of the transition metal, while the densification and field-activated reaction, preferably performed by spark plasma sintering, result in the formation of the alloyed transition metal silicide. Among the many advantages of the process are its ability to accommodate materials that are incompatible in other alloying methods.

  7. Kinetics of silicide formation over a wide range of heating rates spanning six orders of magnitude

    SciTech Connect (OSTI)

    Molina-Ruiz, Manel; Lopeandía, Aitor F.; Gonzalez-Silveira, Marta; Garcia, Gemma; Clavaguera-Mora, Maria T. [Grup de Nanomaterials i Microsistemes, Departament de Física, Universitat Autònoma de Barcelona, 08193 Bellaterra (Spain); Peral, Inma [ALBA Synchrotron Light Facility, 08290 Cerdanyola del Vallès (Spain); Rodríguez-Viejo, Javier, E-mail: javier.rodriguez@uab.cat [Grup de Nanomaterials i Microsistemes, Departament de Física, Universitat Autònoma de Barcelona, 08193 Bellaterra (Spain); MATGAS Research Centre, UAB Campus, 08193 Bellaterra (Spain)

    2014-07-07T23:59:59.000Z

    Kinetic processes involving intermediate phase formation are often assumed to follow an Arrhenius temperature dependence. This behavior is usually inferred from limited data over narrow temperature intervals, where the exponential dependence is generally fully satisfied. However, direct evidence over wide temperature intervals is experimentally challenging and data are scarce. Here, we report a study of silicide formation between a 12?nm film of palladium and 15?nm of amorphous silicon in a wide range of heating rates, spanning six orders of magnitude, from 0.1 to 10{sup 5?}K/s, or equivalently more than 300?K of variation in reaction temperature. The calorimetric traces exhibit several distinct exothermic events related to interdiffusion, nucleation of Pd{sub 2}Si, crystallization of amorphous silicon, and vertical growth of Pd{sub 2}Si. Interestingly, the thickness of the initial nucleation layer depends on the heating rate revealing enhanced mass diffusion at the fastest heating rates during the initial stages of the reaction. In spite of this, the formation of the silicide strictly follows an Arrhenius temperature dependence over the whole temperature interval explored. A kinetic model is used to fit the calorimetric data over the complete heating rate range. Calorimetry is complemented by structural analysis through transmission electron microscopy and both standard and in-situ synchrotron X-ray diffraction.

  8. Magnesium and Manganese Silicides For Efficient And Low Cost Thermo-Electric Power Generation

    SciTech Connect (OSTI)

    Trivedi, Sudhir B. [Brimrose Technology Corporation; Kutcher, Susan W. [Brimrose Technology Corporation; Rosemeier, Cory A. [Brimrose Technology Corporation; Mayers, David [Brimrose Technology Corporation; Singh, Jogender [Pennsylvania State University

    2013-12-02T23:59:59.000Z

    Thermoelectric Power Generation (TEPG) is the most efficient and commercially deployable power generation technology for harvesting wasted heat from such things as automobile exhausts, industrial furnaces, and incinerators, and converting it into usable electrical power. We investigated the materials magnesium silicide (Mg2Si) and manganese silicide (MnSi) for TEG. MgSi2 and MnSi are environmentally friendly, have constituent elements that are abundant in the earth's crust, non-toxic, lighter and cheaper. In Phase I, we successfully produced Mg2Si and MnSi material with good TE properties. We developed a novel technique to synthesize Mg2Si with good crystalline quality, which is normally very difficult due to high Mg vapor pressure and its corrosive nature. We produced n-type Mg2Si and p-type MnSi nanocomposite pellets using FAST. Measurements of resistivity and voltage under a temperature gradient indicated a Seebeck coefficient of roughly 120 V/K on average per leg, which is quite respectable. Results indicated however, that issues related to bonding resulted in high resistivity contacts. Determining a bonding process and bonding material that can provide ohmic contact from room temperature to the operating temperature is an essential part of successful device fabrication. Work continues in the development of a process for reproducibly obtaining low resistance electrical contacts.

  9. Submersible sodium pump

    DOE Patents [OSTI]

    Brynsvold, G.V.; Lopez, J.T.; Olich, E.E.; West, C.W.

    1989-11-21T23:59:59.000Z

    An electromagnetic submerged pump has an outer cylindrical stator with an inner cylindrical conductive core for the submerged pumping of sodium in the cylindrical interstitial volume defined between the stator and core. The cylindrical interstitial volume is typically vertically oriented, and defines an inlet at the bottom and an outlet at the top. The outer stator generates upwardly conveyed toroidal magnetic fields, which fields convey preferably from the bottom of the pump to the top of the pump liquid sodium in the cold leg of a sodium cooled nuclear reactor. The outer cylindrical stator has a vertically disposed duct surrounded by alternately stacked layers of coil units and laminates. 14 figs.

  10. FLOWSHEET EVALUATION FOR THE DISSOLVING AND NEUTRALIZATION OF SODIUM REACTOR EXPERIMENT USED NUCLEAR FUEL

    SciTech Connect (OSTI)

    Daniel, W. E.; Hansen, E. K.; Shehee, T. C.

    2012-10-30T23:59:59.000Z

    This report includes the literature review, hydrogen off-gas calculations, and hydrogen generation tests to determine that H-Canyon can safely dissolve the Sodium Reactor Experiment (SRE; thorium fuel), Ford Nuclear Reactor (FNR; aluminum alloy fuel), and Denmark Reactor (DR-3; silicide fuel, aluminum alloy fuel, and aluminum oxide fuel) assemblies in the L-Bundles with respect to the hydrogen levels in the projected peak off-gas rates. This is provided that the number of L-Bundles charged to the dissolver is controlled. Examination of SRE dissolution for potential issues has aided in predicting the optimal batching scenario. The calculations detailed in this report demonstrate that the FNR, SRE, and DR-3 used nuclear fuel (UNF) are bounded by MURR UNF and may be charged using the controls outlined for MURR dissolution in a prior report.

  11. Understanding and Improving High-Temperature Structural Properties of Metal-Silicide Intermetallics

    SciTech Connect (OSTI)

    Bruce S. Kang

    2005-10-10T23:59:59.000Z

    The objective of this project was to understand and improve high-temperature structural properties of metal-silicide intermetallic alloys. Through research collaboration between the research team at West Virginia University (WVU) and Dr. J.H. Schneibel at Oak Ridge National Laboratory (ORNL), molybdenum silicide alloys were developed at ORNL and evaluated at WVU through atomistic modeling analyses, thermo-mechanical tests, and metallurgical studies. In this study, molybdenum-based alloys were ductilized by dispersing MgAl2O4 or MgO spinel particles. The addition of spinel particles is hypothesized to getter impurities such as oxygen and nitrogen from the alloy matrix with the result of ductility improvement. The introduction of fine dispersions has also been postulated to improve ductility by acting as a dislocation source or reducing dislocation pile-ups at grain boundaries. The spinel particles, on the other hand, can also act as local notches or crack initiation sites, which is detrimental to the alloy mechanical properties. Optimization of material processing condition is important to develop the desirable molybdenum alloys with sufficient room-temperature ductility. Atomistic analyses were conducted to further understand the mechanism of ductility improvement of the molybdenum alloys and the results showed that trace amount of residual oxygen may be responsible for the brittle behavior of the as-cast Mo alloys. For the alloys studied, uniaxial tensile tests were conducted at different loading rates, and at room and elevated temperatures. Thermal cycling effect on the mechanical properties was also studied. Tensile tests for specimens subjected to either ten or twenty thermal cycles were conducted. For each test, a follow-up detailed fractography and microstructural analysis were carried out. The test results were correlated to the size, density, distribution of the spinel particles and processing time. Thermal expansion tests were carried out using thermo-mechanical analyzer (TMA). Results showed that the coefficient of thermal expansion (CTE) value decreases with the addition of spinel and silicide particles. Thermo-cycling tests showed that molybdenum alloy with 6% wt of spinel (MgAl2O4) developed microcracks which were caused by thermal expansion mismatch between the spinel particles and molybdenum matrix, as well as the processing conditions. Detailed post-mortem studies of microstructures and segregation of impurities to the oxide dispersion/Mo interfaces were conducted using x-ray diffraction (XRD), scanning electron microscopy (SEM), and energy dispersive spectroscopy (EDS).

  12. Titanate Anodes for Sodium Ion Batteries

    E-Print Network [OSTI]

    Doeff, Marca M.

    2014-01-01T23:59:59.000Z

    Anodes for Sodium Ion Batteries Identification of a suitabledevelopment of sodium ion batteries, because graphite, theanode for lithium ion batteries, does not undergo sodium

  13. Phase formation and morphological stability of ultrathin Ni-Co-Pt silicide films formed on Si(100)

    SciTech Connect (OSTI)

    Xu, Peng; Wu, Dongping, E-mail: dongpingwu@fudan.edu.cn [State Key Laboratory of ASIC and System, Fudan University, Shanghai 200433 (China); Kubart, Tomas; Gao, Xindong [Solid-State Electronics, The Ångström Laboratory, Uppsala University, P.O. Box 534, 75121 Uppsala (Sweden); Zhang, Shi-Li, E-mail: shili.zhang@angstrom.uu.se [State Key Laboratory of ASIC and System, Fudan University, Shanghai 200433, China and Solid-State Electronics, The Ångström Laboratory, Uppsala University, P.O. Box 534, 75121 Uppsala (Sweden)

    2014-05-15T23:59:59.000Z

    Ultrathin Ni, Co, and Pt films, each no more than 4?nm in thickness, as well as their various combinations are employed to investigate the competing growth of epitaxial Co{sub 1-y}Ni{sub y}Si{sub 2} films against polycrystalline Pt{sub 1-z}Ni{sub z}Si. The phase formation critically affects the morphological stability of the resulting silicide films, with the epitaxial films being superior to the polycrystalline ones. Any combination of those metals improves the morphological stability with reference to their parent individual metal silicide films. When Ni, Co, and Pt are all included, the precise initial location of Pt does little to affect the final phase formation in the silicide films and the epitaxial growth of Co{sub 1-x}Ni{sub x}Si{sub 2} films is always perturbed, in accordance to thermodynamics that shows a preferential formation of Pt{sub 1-z}Ni{sub z}Si over that of Co{sub 1-y}Ni{sub y}Si{sub 2}.

  14. Enhanced power factor of higher manganese silicide via melt spin synthesis method

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Shi, Xiaoya [Brookhaven National Lab. (BNL), Upton, NY (United States); Shi, Xun [Chinese Academy of Sciences, Shanghai (China); Li, Yulong [Chinese Academy of Sciences, Shanghai (China); He, Ying [Chinese Academy of Sciences, Shanghai (China); Chen, Lidong [Chinese Academy of Sciences, Shanghai (China); Li, Qiang [Brookhaven National Lab. (BNL), Upton, NY (United States)

    2014-12-28T23:59:59.000Z

    We report on the thermoelectric properties of the Higher Manganese Silicide MnSi?.?? (HMS) synthesized by means of a one-step non-equilibrium method. The ultrahigh cooling rate generated from the melt-spin technique is found to be effective in reducing second phases, which are inevitable during the traditional solid state diffusion processes. Aside from being detrimental to thermoelectric properties, second phases skew the revealing of the intrinsic properties of this class of materials, for example the optimal level of carrier concentration. With this melt-spin sample, we are able to formulate a simple model based on a single parabolic band that can well describe the carrier concentration dependence of the Seebeck coefficient and power factor of the data reported in the literature. An optimal carrier concentration around 5x10²? cm?³ at 300 K is predicted according to this model. The phase-pure melt-spin sample shows the largest power factor at high temperature, resulting in the highest zT value among the three samples in this paper. And the maximum value is superior to those reported in the literatures.

  15. Approaching the Minimum Thermal Conductivity in Rhenium-Substituted Higher Manganese Silicides

    SciTech Connect (OSTI)

    Chen, Xi [University of Texas at Austin] [University of Texas at Austin; Girard, S. N. [University of Wisconsin, Madison] [University of Wisconsin, Madison; Meng, F. [University of Wisconsin, Madison] [University of Wisconsin, Madison; Lara-Curzio, Edgar [ORNL] [ORNL; Jin, S [University of Wisconsin, Madison] [University of Wisconsin, Madison; Goodenough, J. B. [University of Texas at Austin] [University of Texas at Austin; Zhou, J. S. [University of Texas at Austin] [University of Texas at Austin; Shi, L [University of Texas at Austin] [University of Texas at Austin

    2014-01-01T23:59:59.000Z

    Higher manganese silicides (HMS) made of earth-abundant and non-toxic elements are regarded as promising p-type thermoelectric materials because their complex crystal structure results in low lattice thermal conductivity. It is shown here that the already low thermal conductivity of HMS can be reduced further to approach the minimum thermal conductivity via partial substitu- tion of Mn with heavier rhenium (Re) to increase point defect scattering. The solubility limit of Re in the obtained RexMn1 xSi1.8 is determined to be about x = 0.18. Elemental inhomogeneity and the formation of ReSi1.75 inclusions with 50 200 nm size are found within the HMS matrix. It is found that the power factor does not change markedly at low Re content of x 0.04 before it drops considerably at higher Re contents. Compared to pure HMS, the reduced lattice thermal conductivity in RexMn1 xSi1.8 results in a 25% increase of the peak figure of merit ZT to reach 0.57 0.08 at 800 K for x = 0.04. The suppressed thermal conductivity in the pure RexMn1 xSi1.8 can enable further investigations of the ZT limit of this system by exploring different impurity doping strategies to optimize the carrier concentration and power factor.

  16. Enhanced power factor of higher manganese silicide via melt spin synthesis method

    SciTech Connect (OSTI)

    Shi, Xiaoya [Brookhaven National Lab. (BNL), Upton, NY (United States); Shi, Xun [Chinese Academy of Sciences, Shanghai (China); Li, Yulong [Chinese Academy of Sciences, Shanghai (China); He, Ying [Chinese Academy of Sciences, Shanghai (China); Chen, Lidong [Chinese Academy of Sciences, Shanghai (China); Li, Qiang [Brookhaven National Lab. (BNL), Upton, NY (United States)

    2014-12-28T23:59:59.000Z

    We report on the thermoelectric properties of the Higher Manganese Silicide MnSi?.?? (HMS) synthesized by means of a one-step non-equilibrium method. The ultrahigh cooling rate generated from the melt-spin technique is found to be effective in reducing second phases, which are inevitable during the traditional solid state diffusion processes. Aside from being detrimental to thermoelectric properties, second phases skew the revealing of the intrinsic properties of this class of materials, for example the optimal level of carrier concentration. With this melt-spin sample, we are able to formulate a simple model based on a single parabolic band that can well describe the carrier concentration dependence of the Seebeck coefficient and power factor of the data reported in the literature. An optimal carrier concentration around 5x10²? cm?³ at 300 K is predicted according to this model. The phase-pure melt-spin sample shows the largest power factor at high temperature, resulting in the highest zT value among the three samples in this paper. And the maximum value is superior to those reported in the literatures.

  17. Enhanced power factor of higher manganese silicide via melt spin synthesis method

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Shi, Xiaoya; Shi, Xun; Li, Yulong; He, Ying; Chen, Lidong; Li, Qiang

    2014-12-28T23:59:59.000Z

    We report on the thermoelectric properties of the Higher Manganese Silicide MnSi?.?? (HMS) synthesized by means of a one-step non-equilibrium method. The ultrahigh cooling rate generated from the melt-spin technique is found to be effective in reducing second phases, which are inevitable during the traditional solid state diffusion processes. Aside from being detrimental to thermoelectric properties, second phases skew the revealing of the intrinsic properties of this class of materials, for example the optimal level of carrier concentration. With this melt-spin sample, we are able to formulate a simple model based on a single parabolic band that can well describemore »the carrier concentration dependence of the Seebeck coefficient and power factor of the data reported in the literature. An optimal carrier concentration around 5x10²? cm?³ at 300 K is predicted according to this model. The phase-pure melt-spin sample shows the largest power factor at high temperature, resulting in the highest zT value among the three samples in this paper. And the maximum value is superior to those reported in the literatures.« less

  18. ID-69 Sodium drain experiments

    SciTech Connect (OSTI)

    Johnston, D.C.

    1996-09-19T23:59:59.000Z

    This paper describes experiments to determine the sodium retention and drainage from the two key areas of an ID-69. This information is then used as the initiation point for guidelines of how to proceed with washing an ID-69 in the IEM Cell Sodium Removal System.

  19. Tables of thermodynamic properties of sodium

    SciTech Connect (OSTI)

    Fink, J.K.

    1982-06-01T23:59:59.000Z

    The thermodynamic properties of saturated sodium, superheated sodium, and subcooled sodium are tabulated as a function of temperature. The temperature ranges are 380 to 2508 K for saturated sodium, 500 to 2500 K for subcooled sodium, and 400 to 1600 K for superheated sodium. Tabulated thermodynamic properties are enthalpy, heat capacity, pressure, entropy, density, instantaneous thermal expansion coefficient, compressibility, and thermal pressure coefficient. Tables are given in SI units and cgs units.

  20. Titanate Anodes for Sodium Ion Batteries

    E-Print Network [OSTI]

    Doeff, Marca

    2014-01-01T23:59:59.000Z

    Company-v3832/Lithium-Ion-Batteries- Outlook-Alternative-Anodes for Sodium Ion Batteries Marca M. Doeff * , Jordirechargeable sodium ion batteries, particularly for large-

  1. Simulation of sodium boiling experiments with THERMIT sodium version

    E-Print Network [OSTI]

    Huh, Kang Yul

    1982-01-01T23:59:59.000Z

    Natural and forced convection experiments(SBTF and French) are simulated with the sodium version of the thermal-hydraulic computer code THERMIT. Simulation is done for the test secti- -on with the pressure-velocity boundary ...

  2. Ground beef shelf life assessment as influenced by sodium lactate, sodium propionate, sodium diacetate, and soy protein concentrate 

    E-Print Network [OSTI]

    Grones, Kelly Leann

    2000-01-01T23:59:59.000Z

    In phase I all-beef and soy-added ground beef patties containing sodium lactate, sodium propionate, and sodium diacetate at various levels and combinations were stored for nine months at -10°C. Upon cooking, the addition of sodium lactate increased...

  3. Effects of (Al,Ge) double doping on the thermoelectric properties of higher manganese silicides

    SciTech Connect (OSTI)

    Chen, Xi; Salta, Daniel; Zhang, Libin [Materials Science and Engineering Program, Texas Materials Institute, The University of Texas at Austin, Austin, Texas 78712 (United States); Weathers, Annie [Department of Mechanical Engineering, The University of Texas at Austin, Austin, Texas 78712 (United States); Zhou, Jianshi; Goodenough, John B.; Shi, Li [Materials Science and Engineering Program, Texas Materials Institute, The University of Texas at Austin, Austin, Texas 78712 (United States); Department of Mechanical Engineering, The University of Texas at Austin, Austin, Texas 78712 (United States)

    2013-11-07T23:59:59.000Z

    Experiments and analysis have been carried out to investigate the effects of Al and (Al,Ge) doping on the microstructure and thermoelectric properties of polycrystalline higher manganese silicide (HMS) samples, which were prepared by solid-state reaction, ball milling, and followed by spark plasma sintering. It has been found that Al doping effectively increases the hole concentration, which leads to an increase in the electrical conductivity and power factor. By introducing the second dopant Ge into Al-doped HMS, the electrical conductivity is increased, and the Seebeck coefficient is decreased as a result of further increased hole concentration. The peak power factor is found to occur at a hole concentration between 1.8?×?10{sup 21} and 2.2?×?10{sup 21}?cm{sup ?3} measured at room temperature. The (Al,Ge)-doped HMS samples show lower power factors owing to their higher hole concentrations. The mobility of Mn(Al{sub 0.0035}Ge{sub y}Si{sub 0.9965-y}){sub 1.8} with y?=?0.035 varies approximately as T{sup ?3/2} above 200?K, suggesting acoustic phonon scattering is the dominant scattering mechanism. The thermal conductivity of HMS does not change appreciably by Al or (Al,Ge) doping. The maximum ZT of (Al,Ge)-doped HMS is 0.57 at 823?K, which is similar to the highest value found in the Al-doped HMS samples. The ZT values were reduced in the Mn(Al{sub 0.0035}Ge{sub y}Si{sub 0.9965-y}){sub 1.8} samples with high Ge concentration of y?=?0.025 and 0.035, because of reduced power factor. In addition, a two-band model was employed to show that the hole contribution to the thermal conductivity dominates the bipolar and electron contributions for all samples from 300 to 823?K and accounts for about 12% of the total thermal conductivity at about 800?K.

  4. Equation of state of sodium

    SciTech Connect (OSTI)

    Fritz, J.N.; Olinger, B.

    1984-03-15T23:59:59.000Z

    The volume of sodium in the bcc structure was measured at 293 K to 9 GPa using a high pressure, x-ray diffraction technique. The compression of NaF was used as the pressure gauge. These data, the shock compression data of Rice and Bakanova et al., and the melting curve data of Luedemann and Kennedy, and Ivanov et al., are all used to establish a model for the equation of state of sodium.

  5. Surface-Driven Sodium Ion Energy Storage in Nanocellular Carbon...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Surface-Driven Sodium Ion Energy Storage in Nanocellular Carbon Foams. Surface-Driven Sodium Ion Energy Storage in Nanocellular Carbon Foams. Abstract: Sodium ion (Na+) batteries...

  6. anticoagulant sodium citrate: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    pressure-velocity boundary ... Huh, Kang Yul 1982-01-01 38 Ground beef shelf life assessment as influenced by sodium lactate, sodium propionate, sodium diacetate, and soy...

  7. Adsorption of Sodium Dodecyl Sulfate and Sodium Dodecyl Benzenesulfonate on Poly(Vinyl Chloride) Latexes

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Adsorption of Sodium Dodecyl Sulfate and Sodium Dodecyl Benzenesulfonate on Poly(Vinyl Chloride@cpe.fr #12;2 Abstract The adsorption of sodium dodecyl sulfate (SDS) and sodium dodecyl benzenesulfonate performed to determine the area per surfactant molecule at various temperatures (20-50ºC) and the adsorption

  8. Fire suppressing apparatus. [sodium fires

    DOE Patents [OSTI]

    Buttrey, K.E.

    1980-12-19T23:59:59.000Z

    Apparatus for smothering a liquid sodium fire comprises a pan, a perforated cover on the pan, and tubed depending from the cover and providing communication between the interior of the pan and the ambient atmosphere through the perforations in the cover. Liquid caught in the pan rises above the lower ends of the tubes and thus serves as a barrier which limits the amount of air entering the pan.

  9. Formation of nickel silicide and germanosilicide layers on Si(001), relaxed SiGe/Si(001), and strained Si/relaxed SiGe/Si(001) and effect of postthermal annealing

    SciTech Connect (OSTI)

    Ko, J.H.; Jang, C.H.; Kim, S.H.; Song, Y.-J.; Lee, N.E. [School of Advanced Materials Science and Engineering, Sungkyunkwan University, Suwon, Kyunggi-do 440-746, Korea and Center for Advanced Plasma Surface Technology, Sungkyunkwan University, Suwon, Kyunggi-do 440-746 (Korea, Republic of); Semiconductor Division, Electronics and Telecommunications Research Institute, Taejeon 305-700 (Korea, Republic of); School of Advanced Materials Science and Engineering, Sungkyunkwan University, Suwon, Kyunggi-do 440-746, Korea and Center for Advanced Plasma Surface Technology, Sungkyunkwan University, Suwon, Kyunggi-do 440-746 (Korea, Republic of)

    2006-07-15T23:59:59.000Z

    This study compared the formation of nickel silicide or germanosilicide layers on various SiGe based heterostructures as well as the effects of the different annealing schemes (one-step versus two-step annealing) on the morphological, structural, and electrical properties. Uniform nickel silicide or germanosilicide layers were first formed by rapid thermal annealing of various heterostructures. The two-step annealing process of the samples first at 400 deg. C (T{sub A1}) and subsequently at between 600 and 800 deg. C (T{sub A2}) led to an increase in the sheet resistance, which was attributed to the formation of a high-resistivity NiSi{sub 2} phase, the agglomeration of the silicide or germanosilicide layers, and the formation of an amorphous interlayer between the silicide or germanosilicide layers. The lower sheet resistance of the silicide or germanosilicide layers formed on the relaxed-Si{sub 1-x}Ge{sub x} (x=0.15)/Si(001) substrates by two-step annealing compared with that of the samples formed on the strained Si/relaxed SiGe/Si(001) and Si(001) was attributed to the suppression of the high-resistivity NiSi{sub 2} phase as well as the superior thermal stability of the germanosilicide layer formed on the relaxed Si{sub 1-x}Ge{sub x} (x=0.15)/Si(001). The amorphous interlayers formed in the samples annealed using two-step procedure appeared to suppress interface roughening between the silicide or germanosilicide and the SiGe layer presumably due to the reduced Ni and Ge diffusion rate. Here, an amorphous interlayer was formed, which was attributed to the large negative heat of mixing in Ni-Si-Ge systems during the phase transformation and grain growth.

  10. Electrolytic process to produce sodium hypochlorite using sodium ion conductive ceramic membranes

    DOE Patents [OSTI]

    Balagopal, Shekar; Malhotra, Vinod; Pendleton, Justin; Reid, Kathy Jo

    2012-09-18T23:59:59.000Z

    An electrochemical process for the production of sodium hypochlorite is disclosed. The process may potentially be used to produce sodium hypochlorite from seawater or low purity un-softened or NaCl-based salt solutions. The process utilizes a sodium ion conductive ceramic membrane, such as membranes based on NASICON-type materials, in an electrolytic cell. In the process, water is reduced at a cathode to form hydroxyl ions and hydrogen gas. Chloride ions from a sodium chloride solution are oxidized in the anolyte compartment to produce chlorine gas which reacts with water to produce hypochlorous and hydrochloric acid. Sodium ions are transported from the anolyte compartment to the catholyte compartment across the sodium ion conductive ceramic membrane. Sodium hydroxide is transported from the catholyte compartment to the anolyte compartment to produce sodium hypochlorite within the anolyte compartment.

  11. A layered sodium titanate as promising anode material for sodium ion batteries

    E-Print Network [OSTI]

    Wu, Di, S.M. Massachusetts Institute of Technology

    2014-01-01T23:59:59.000Z

    Sodium ion batteries have recently received great attention for large-scale energy applications because of the abundance and low cost of sodium source. Although some cathode materials with desirable electrochemical properties ...

  12. Sodium Titanate Anodes for Dual Intercalation Batteries

    E-Print Network [OSTI]

    Doeff, Marca M.

    2014-01-01T23:59:59.000Z

    for Dual Intercalation Batteries Lithium supply securityinterest in sodium-ion batteries. These devices operate muchsodium-ion or lithium-ion batteries that utilize them as

  13. M5Si3(M=Ti, Nb, Mo) Based Transition-Metal Silicides for High Temperature Applications

    SciTech Connect (OSTI)

    Zhihong Tang

    2007-12-01T23:59:59.000Z

    Transition metal silicides are being considered for future engine turbine components at temperatures up to 1600 C. Although significant improvement in high temperature strength, room temperature fracture toughness has been realized in the past decade, further improvement in oxidation resistance is needed. Oxidation mechanism of Ti{sub 5}Si{sub 3}-based alloys was investigated. Oxidation behavior of Ti{sub 5}Si{sub 3}-based alloy strongly depends on the atmosphere. Presence of Nitrogen alters the oxidation behavior of Ti{sub 5}Si{sub 3} by nucleation and growth of nitride subscale. Ti{sub 5}Si{sub 3.2} and Ti{sub 5}Si{sub 3}C{sub 0.5} alloys exhibited an excellent oxidation resistance in nitrogen bearing atmosphere due to limited dissolution of nitrogen and increased Si/Ti activity ratio. MoSi{sub 2} coating developed by pack cementation to protect Mo-based Mo-Si-B composites was found to be effective up to 1500 C. Shifting coating composition to T1+T2+Mo{sub 3}Si region showed the possibility to extend the coating lifetime above 1500 C by more than ten times via formation of slow growing Mo{sub 3}Si or T2 interlayer without sacrificing the oxidation resistance of the coating. The phase equilibria in the Nb-rich portion of Nb-B system has been evaluated experimentally using metallographic analysis and differential thermal analyzer (DTA). It was shown that Nb{sub ss} (solid solution) and NbB are the only two primary phases in the 0-40 at.% B composition range, and the eutectic reaction L {leftrightarrow} Nb{sub SS} + NbB was determined to occur at 2104 {+-} 5 C by DTA.

  14. In-Situ Method for Treating Residual Sodium

    DOE Patents [OSTI]

    Sherman, Steven R.; Henslee, S. Paul

    2005-07-19T23:59:59.000Z

    A unique process for deactivating residual sodium in Liquid Metal Fast Breeder Reactor (LMFBR) systems which uses humidified (but not saturated) carbon dioxide at ambient temperature and pressure to convert residual sodium into solid sodium bicarbonate.

  15. High-capacity hydrogen storage in lithium and sodium amidoboranes...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    capacity hydrogen storage in lithium and sodium amidoboranes. High-capacity hydrogen storage in lithium and sodium amidoboranes. Abstract: A substantial effort worldwide has been...

  16. SciTech Connect: Thermodynamic and transport properties of sodium...

    Office of Scientific and Technical Information (OSTI)

    of state calculations on thermophysical properties of sodium have been included in this critical assessment. Thermodynamic properties of sodium liquid and vapor that have been...

  17. A resting bottom sodium cooled fast reactor

    SciTech Connect (OSTI)

    Costes, D. [Consultant (France)

    2012-07-01T23:59:59.000Z

    This follows ICAPP 2011 paper 11059 'Fast Reactor with a Cold Bottom Vessel', on sodium cooled reactor vessels in thermal gradient, resting on soil. Sodium is frozen on vessel bottom plate, temperature increasing to the top. The vault cover rests on the safety vessel, the core diagrid welded to a toric collector forms a slab, supported by skirts resting on the bottom plate. Intermediate exchangers and pumps, fixed on the cover, plunge on the collector. At the vessel top, a skirt hanging from the cover plunges into sodium, leaving a thin circular slit partially filled by sodium covered by argon, providing leak-tightness and allowing vessel dilatation, as well as a radial relative holding due to sodium inertia. No 'air conditioning' at 400 deg. C is needed as for hanging vessels, and this allows a large economy. The sodium volume below the slab contains isolating refractory elements, stopping a hypothetical corium flow. The small gas volume around the vessel limits any LOCA. The liner cooling system of the concrete safety vessel may contribute to reactor cooling. The cold resting bottom vessel, proposed by the author for many years, could avoid the complete visual inspection required for hanging vessels. However, a double vessel, containing support skirts, would allow introduction of inspecting devices. Stress limiting thermal gradient is obtained by filling secondary sodium in the intermediate space. (authors)

  18. Kinetics of wet sodium vapor complex plasma

    SciTech Connect (OSTI)

    Mishra, S. K., E-mail: nishfeb@rediffmail.com [Institute for Plasma Research (IPR), Gandhinagar 382428 (India); Sodha, M. S. [Centre of Energy Studies, Indian Institute of Technology Delhi (IITD), New Delhi 110016 (India)] [Centre of Energy Studies, Indian Institute of Technology Delhi (IITD), New Delhi 110016 (India)

    2014-04-15T23:59:59.000Z

    In this paper, we have investigated the kinetics of wet (partially condensed) Sodium vapor, which comprises of electrons, ions, neutral atoms, and Sodium droplets (i) in thermal equilibrium and (ii) when irradiated by light. The formulation includes the balance of charge over the droplets, number balance of the plasma constituents, and energy balance of the electrons. In order to evaluate the droplet charge, a phenomenon for de-charging of the droplets, viz., evaporation of positive Sodium ions from the surface has been considered in addition to electron emission and electron/ion accretion. The analysis has been utilized to evaluate the steady state parameters of such complex plasmas (i) in thermal equilibrium and (ii) when irradiated; the results have been graphically illustrated. As a significant outcome irradiated, Sodium droplets are seen to acquire large positive potential, with consequent enhancement in the electron density.

  19. Radial power flattening in sodium fast reactors

    E-Print Network [OSTI]

    Krentz-Wee, Rebecca (Rebecca Elizabeth)

    2012-01-01T23:59:59.000Z

    In order to improve a new design for a uranium startup sodium cooled fast reactor which was proposed at MIT, this thesis evaluated radial power flattening by varying the fuel volume fraction at a fixed U-235 enrichment of ...

  20. Low-Pressure Sodium Lighting Basics

    Broader source: Energy.gov [DOE]

    Low-pressure sodium lighting provides more energy-efficient outdoor lighting than high-intensity discharge lighting, but it has very poor color rendition. Typical applications include highway and security lighting, where color is not important.

  1. Method and system for producing hydrogen using sodium ion separation membranes

    DOE Patents [OSTI]

    Bingham, Dennis N; Klingler, Kerry M; Turner, Terry D; Wilding, Bruce M; Frost, Lyman

    2013-05-21T23:59:59.000Z

    A method of producing hydrogen from sodium hydroxide and water is disclosed. The method comprises separating sodium from a first aqueous sodium hydroxide stream in a sodium ion separator, feeding the sodium produced in the sodium ion separator to a sodium reactor, reacting the sodium in the sodium reactor with water, and producing a second aqueous sodium hydroxide stream and hydrogen. The method may also comprise reusing the second aqueous sodium hydroxide stream by combining the second aqueous sodium hydroxide stream with the first aqueous sodium hydroxide stream. A system of producing hydrogen is also disclosed.

  2. Effects of sodium lactate and sodium propionate on the sensory, microbial, and chemical characteristics of fresh aerobically stored ground beef

    E-Print Network [OSTI]

    Eckert, Laura Anne

    1995-01-01T23:59:59.000Z

    Coarse ground beef was mixed with sodium lactate (0, 3, or 4%) alone or in combination with sodium propionate (0. 1 or 0. 2%). The mixtures were then re-ground and formed into hamburger patties, which were placed in Styrofoam meat trays and overwrapped... sodium lactate tended to be sweeter than control patties. Hamburger patties with sodium lactate were springier. more cohesive. and less crumbly than the control patties. Treatments containing 0. 2% sodium propionate were more juicy than the control...

  3. Method of making a sodium sulfur battery

    DOE Patents [OSTI]

    Elkins, P. E.

    1981-09-22T23:59:59.000Z

    A method of making a portion of a sodium sulfur battery is disclosed. The battery portion made is a portion of the container which defines the volume for the cathodic reactant materials which are sulfur and sodium polysulfide materials. The container portion is defined by an outer metal casing with a graphite liner contained therein, the graphite liner having a coating on its internal diameter for sealing off the porosity thereof. The steel outer container and graphite pipe are united by a method which insures that at the operating temperature of the battery, relatively low electrical resistance exists between the two materials because they are in intimate contact with one another. 3 figs.

  4. Sodium-tetravalent sulfur molten chloroaluminate cell

    DOE Patents [OSTI]

    Mamantov, Gleb (Knoxville, TN)

    1985-04-02T23:59:59.000Z

    A sodium-tetravalent sulfur molten chloroaluminate cell with a .beta."-alumina sodium ion conductor having a S-Al mole ratio of above about 0.15 in an acidic molten chloroaluminate cathode composition is disclosed. The cathode composition has an AlCl.sub.3 -NaCl mole percent ratio of above about 70-30 at theoretical full charge. The cell provides high energy densities at low temperatures and provides high energy densities and high power densities at moderate temperatures.

  5. Sodium hypochlorite Market | OpenEI Community

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnualProperty Edit with form HistoryRistmaSinosteel CorporationSocovoltaic Systems JumpSodiumSodium

  6. Sodium and sulfur release and recapture during black liquor burning

    SciTech Connect (OSTI)

    Frederick, W.J.; Iisa, K.; Wag, K.; Reis, V.V.; Boonsongsup, L.; Forssen, M.; Hupa, M.

    1995-08-01T23:59:59.000Z

    The objective of this study was to provide data on sulfur and sodium volatilization during black liquor burning, and on SO2 capture by solid sodium carbonate and sodium chloride. This data was interpreted and modeled into rate equations suitable for use in computational models for recovery boilers.

  7. Corrosion performance of advanced structural materials in sodium.

    SciTech Connect (OSTI)

    Natesan, K.; Momozaki, Y.; Li, M.; Rink, D.L. (Nuclear Engineering Division)

    2012-05-16T23:59:59.000Z

    This report gives a description of the activities in design, fabrication, construction, and assembling of a pumped sodium loop for the sodium compatibility studies on advanced structural materials. The work is the Argonne National Laboratory (ANL) portion of the effort on the work project entitled, 'Sodium Compatibility of Advanced Fast Reactor Materials,' and is a part of Advanced Materials Development within the Reactor Campaign. The objective of this project is to develop information on sodium corrosion compatibility of advanced materials being considered for sodium reactor applications. This report gives the status of the sodium pumped loop at Argonne National Laboratory, the specimen details, and the technical approach to evaluate the sodium compatibility of advanced structural alloys. This report is a deliverable from ANL in FY2010 (M2GAN10SF050302) under the work package G-AN10SF0503 'Sodium Compatibility of Advanced Fast Reactor Materials.' Two reports were issued in 2009 (Natesan and Meimei Li 2009, Natesan et al. 2009) which examined the thermodynamic and kinetic factors involved in the purity of liquid sodium coolant for sodium reactor applications as well as the design specifications for the ANL pumped loop for testing advanced structural materials. Available information was presented on solubility of several metallic and nonmetallic elements along with a discussion of the possible mechanisms for the accumulation of impurities in sodium. That report concluded that the solubility of many metals in sodium is low (<1 part per million) in the temperature range of interest in sodium reactors and such trace amounts would not impact the mechanical integrity of structural materials and components. The earlier report also analyzed the solubility and transport mechanisms of nonmetallic elements such as oxygen, nitrogen, carbon, and hydrogen in laboratory sodium loops and in reactor systems such as Experimental Breeder Reactor-II, Fast Flux Test Facility, and Clinch River Breeder Reactor. Among the nonmetallic elements discussed, oxygen is deemed controllable and its concentration in sodium can be maintained in sodium for long reactor life by using cold-trap method. It was concluded that among the cold-trap and getter-trap methods, the use of cold trap is sufficient to achieve oxygen concentration of the order of 1 part per million. Under these oxygen conditions in sodium, the corrosion performance of structural materials such as austenitic stainless steels and ferritic steels will be acceptable at a maximum core outlet sodium temperature of {approx}550 C. In the current sodium compatibility studies, the oxygen concentration in sodium will be controlled and maintained at {approx}1 ppm by controlling the cold trap temperature. The oxygen concentration in sodium in the forced convection sodium loop will be controlled and monitored by maintaining the cold trap temperature in the range of 120-150 C, which would result in oxygen concentration in the range of 1-2 ppm. Uniaxial tensile specimens are being exposed to flowing sodium and will be retrieved and analyzed for corrosion and post-exposure tensile properties. Advanced materials for sodium exposure include austenitic alloy HT-UPS and ferritic-martensitic steels modified 9Cr-1Mo and NF616. Among the nonmetallic elements in sodium, carbon was assessed to have the most influence on structural materials since carbon, as an impurity, is not amenable to control and maintenance by any of the simple purification methods. The dynamic equilibrium value for carbon in sodium systems is dependent on several factors, details of which were discussed in the earlier report. The current sodium compatibility studies will examine the role of carbon concentration in sodium on the carburization-decarburization of advanced structural materials at temperatures up to 650 C. Carbon will be added to the sodium by exposure of carbon-filled iron tubes, which over time will enable carbon to diffuse through iron and dissolve into sodium. The method enables addition of dissolved carbon (without carb

  8. Effects of sodium lactate and sodium propionate on the sensory, microbial, and chemical characteristics of fresh aerobically stored ground beef 

    E-Print Network [OSTI]

    Eckert, Laura Anne

    1995-01-01T23:59:59.000Z

    EFFECTS OF SODIUM LACTATE AND SODIUM PROPIONATE ON THE SENSORY, MICROBIAL, AND CHEMICAL CHARACTERISTICS OF FRESH AEROBICALLY STORED GROUND BEEF A Thesis by LAURA ANNE ECKERT Submitted to the Office of Graduate Studies of Texas A&M University... in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE December 1995 Major Subject: Food Science and Technology EFFECTS OF SODIUM LACTATE AND SODIUM PROPIONATE ON THE SENSORY, MICROBIAL, AND CHEMICAL CHARACTERISTICS OF FRESH...

  9. Cast Stone Formulation At Higher Sodium Concentrations

    SciTech Connect (OSTI)

    Fox, K. M.; Roberts, K. A.; Edwards, T. B.

    2014-02-28T23:59:59.000Z

    A low temperature waste form known as Cast Stone is being considered to provide supplemental Low Activity Waste (LAW) immobilization capacity for the Hanford site. Formulation of Cast Stone at high sodium concentrations is of interest since a significant reduction in the necessary volume of Cast Stone and subsequent disposal costs could be achieved if an acceptable waste form can be produced with a high sodium molarity salt solution combined with a high water to premix (or dry blend) ratio. The objectives of this study were to evaluate the factors involved with increasing the sodium concentration in Cast Stone, including production and performance properties and the retention and release of specific components of interest. Three factors were identified for the experimental matrix: the concentration of sodium in the simulated salt solution, the water to premix ratio, and the blast furnace slag portion of the premix. The salt solution simulants used in this study were formulated to represent the overall average waste composition. The cement, blast furnace slag, and fly ash were sourced from a supplier in the Hanford area in order to be representative. The test mixes were prepared in the laboratory and fresh properties were measured. Fresh density increased with increasing sodium molarity and with decreasing water to premix ratio, as expected given the individual densities of these components. Rheology measurements showed that all of the test mixes produced very fluid slurries. The fresh density and rheology data are of potential value in designing a future Cast Stone production facility. Standing water and density gradient testing showed that settling is not of particular concern for the high sodium compositions studied. Heat of hydration measurements may provide some insight into the reactions that occur within the test mixes, which may in turn be related to the properties and performance of the waste form. These measurements showed that increased sodium concentration in the salt solution reduced the time to peak heat flow, and reducing the amount of slag in the premix increased the time to peak heat flow. These observations may help to describe some of the cured properties of the samples, in particular the differences in compressive strength observed after 28 and 90 days of curing. Samples were cured for at least 28 days at ambient temperature in the laboratory prior to cured properties analyses. The low activity waste form for disposal at the Hanford Site is required to have a compressive strength of at least 500 psi. After 28 days of curing, several of the test mixes had mean compressive strengths that were below the 500 psi requirement. Higher sodium concentrations and higher water to premix ratios led to reduced compressive strength. Higher fly ash concentrations decreased the compressive strength after 28 days of curing. This may be explained in that the cementitious phases matured more quickly in the mixes with higher concentrations of slag, as evidenced by the data for the time to peak heat generation. All of the test mixes exhibited higher mean compressive strengths after 90 days of curing, with only one composition having a mean compressive strength of less than 500 psi. Leachability indices were determined for the test mixes for contaminants of interest. The leaching performance of the mixes evaluated in this study was not particularly sensitive to the factors used in the experimental design. This may be beneficial in demonstrating that the performance of the waste form is robust with respect to changes in the mix composition. The results of this study demonstrate the potential to achieve significantly higher waste loadings in Cast Stone and other low temperature, cementitious waste forms. Additional work is needed to elucidate the hydration mechanisms occurring in Cast Stone formulated with highly concentrated salt solutions since these reactions are responsible for determining the performance of the cured waste form. The thermal analyses completed in this study provide some preliminary insight, although the l

  10. Cast Stone Formulation At Higher Sodium Concentrations

    SciTech Connect (OSTI)

    Fox, K. M.; Roberts, K. A.; Edwards, T. B.

    2013-09-17T23:59:59.000Z

    A low temperature waste form known as Cast Stone is being considered to provide supplemental Low Activity Waste (LAW) immobilization capacity for the Hanford site. Formulation of Cast Stone at high sodium concentrations is of interest since a significant reduction in the necessary volume of Cast Stone and subsequent disposal costs could be achieved if an acceptable waste form can be produced with a high sodium molarity salt solution combined with a high water to premix (or dry blend) ratio. The objectives of this study were to evaluate the factors involved with increasing the sodium concentration in Cast Stone, including production and performance properties and the retention and release of specific components of interest. Three factors were identified for the experimental matrix: the concentration of sodium in the simulated salt solution, the water to premix ratio, and the blast furnace slag portion of the premix. The salt solution simulants used in this study were formulated to represent the overall average waste composition. The cement, blast furnace slag, and fly ash were sourced from a supplier in the Hanford area in order to be representative. The test mixes were prepared in the laboratory and fresh properties were measured. Fresh density increased with increasing sodium molarity and with decreasing water to premix ratio, as expected given the individual densities of these components. Rheology measurements showed that all of the test mixes produced very fluid slurries. The fresh density and rheology data are of potential value in designing a future Cast Stone production facility. Standing water and density gradient testing showed that settling is not of particular concern for the high sodium compositions studied. Heat of hydration measurements may provide some insight into the reactions that occur within the test mixes, which may in turn be related to the properties and performance of the waste form. These measurements showed that increased sodium concentration in the salt solution reduced the time to peak heat flow, and reducing the amount of slag in the premix increased the time to peak heat flow. These observations may help to describe some of the cured properties of the samples, in particular the differences in compressive strength observed after 28 and 90 days of curing. Samples were cured for at least 28 days at ambient temperature in the laboratory prior to cured properties analyses. The low activity waste form for disposal at the Hanford Site is required to have a compressive strength of at least 500 psi. After 28 days of curing, several of the test mixes had mean compressive strengths that were below the 500 psi requirement. Higher sodium concentrations and higher water to premix ratios led to reduced compressive strength. Higher fly ash concentrations decreased the compressive strength after 28 days of curing. This may be explained in that the cementitious phases matured more quickly in the mixes with higher concentrations of slag, as evidenced by the data for the time to peak heat generation. All of the test mixes exhibited higher mean compressive strengths after 90 days of curing, with only one composition having a mean compressive strength of less than 500 psi. Leach indices were determined for the test mixes for contaminants of interest. The leaching performance of the mixes evaluated in this study was not particularly sensitive to the factors used in the experimental design. This may be beneficial in demonstrating that the performance of the waste form is robust with respect to changes in the mix composition. The results of this study demonstrate the potential to achieve significantly higher waste loadings in Cast Stone and other low temperature, cementitious waste forms. Additional work is needed to elucidate the hydration mechanisms occurring in Cast Stone formulated with highly concentrated salt solutions since these reactions are responsible for determining the performance of the cured waste form. The thermal analyses completed in this study provide some preliminary insight, although the limited

  11. Cast Stone Formulation At Higher Sodium Concentrations

    SciTech Connect (OSTI)

    Fox, K. M.; Edwards, T. A.; Roberts, K. B.

    2013-10-02T23:59:59.000Z

    A low temperature waste form known as Cast Stone is being considered to provide supplemental Low Activity Waste (LAW) immobilization capacity for the Hanford site. Formulation of Cast Stone at high sodium concentrations is of interest since a significant reduction in the necessary volume of Cast Stone and subsequent disposal costs could be achieved if an acceptable waste form can be produced with a high sodium molarity salt solution combined with a high water to premix (or dry blend) ratio. The objectives of this study were to evaluate the factors involved with increasing the sodium concentration in Cast Stone, including production and performance properties and the retention and release of specific components of interest. Three factors were identified for the experimental matrix: the concentration of sodium in the simulated salt solution, the water to premix ratio, and the blast furnace slag portion of the premix. The salt solution simulants used in this study were formulated to represent the overall average waste composition. The cement, blast furnace slag, and fly ash were sourced from a supplier in the Hanford area in order to be representative. The test mixes were prepared in the laboratory and fresh properties were measured. Fresh density increased with increasing sodium molarity and with decreasing water to premix ratio, as expected given the individual densities of these components. Rheology measurements showed that all of the test mixes produced very fluid slurries. The fresh density and rheology data are of potential value in designing a future Cast Stone production facility. Standing water and density gradient testing showed that settling is not of particular concern for the high sodium compositions studied. Heat of hydration measurements may provide some insight into the reactions that occur within the test mixes, which may in turn be related to the properties and performance of the waste form. These measurements showed that increased sodium concentration in the salt solution reduced the time to peak heat flow, and reducing the amount of slag in the premix increased the time to peak heat flow. These observations may help to describe some of the cured properties of the samples, in particular the differences in compressive strength observed after 28 and 90 days of curing. Samples were cured for at least 28 days at ambient temperature in the laboratory prior to cured properties analyses. The low activity waste form for disposal at the Hanford Site is required to have a compressive strength of at least 500 psi. After 28 days of curing, several of the test mixes had mean compressive strengths that were below the 500 psi requirement. Higher sodium concentrations and higher water to premix ratios led to reduced compressive strength. Higher fly ash concentrations decreased the compressive strength after 28 days of curing. This may be explained in that the cementitious phases matured more quickly in the mixes with higher concentrations of slag, as evidenced by the data for the time to peak heat generation. All of the test mixes exhibited higher mean compressive strengths after 90 days of curing, with only one composition having a mean compressive strength of less than 500 psi. Leach indices were determined for the test mixes for contaminants of interest. The leaching performance of the mixes evaluated in this study was not particularly sensitive to the factors used in the experimental design. This may be beneficial in demonstrating that the performance of the waste form is robust with respect to changes in the mix composition. The results of this study demonstrate the potential to achieve significantly higher waste loadings in Cast Stone and other low temperature, cementitious waste forms. Additional work is needed to elucidate the hydration mechanisms occurring in Cast Stone formulated with highly concentrated salt solutions since these reactions are responsible for determining the performance of the cured waste form. The thermal analyses completed in this study provide some preliminary insight, although the limited

  12. Report on sodium compatibility of advanced structural materials.

    SciTech Connect (OSTI)

    Li, M.; Natesan, K.; Momozaki, Y.; Rink, D.L.; Soppet, W.K.; Listwan, J.T. (Nuclear Engineering Division)

    2012-07-09T23:59:59.000Z

    This report provides an update on the evaluation of sodium compatibility of advanced structural materials. The report is a deliverable (level 3) in FY11 (M3A11AN04030403), under the Work Package A-11AN040304, 'Sodium Compatibility of Advanced Structural Materials' performed by Argonne National Laboratory (ANL), as part of Advanced Structural Materials Program for the Advanced Reactor Concepts. This work package supports the advanced structural materials development by providing corrosion and tensile data from the standpoint of sodium compatibility of advanced structural alloys. The scope of work involves exposure of advanced structural alloys such as G92, mod.9Cr-1Mo (G91) ferritic-martensitic steels and HT-UPS austenitic stainless steels to a flowing sodium environment with controlled impurity concentrations. The exposed specimens are analyzed for their corrosion performance, microstructural changes, and tensile behavior. Previous reports examined the thermodynamic and kinetic factors involved in the purity of liquid sodium coolant for sodium reactor applications as well as the design, fabrication, and construction of a forced convection sodium loop for sodium compatibility studies of advanced materials. This report presents the results on corrosion performance, microstructure, and tensile properties of advanced ferritic-martensitic and austenitic alloys exposed to liquid sodium at 550 C for up to 2700 h and at 650 C for up to 5064 h in the forced convection sodium loop. The oxygen content of sodium was controlled by the cold-trapping method to achieve {approx}1 wppm oxygen level. Four alloys were examined, G92 in the normalized and tempered condition (H1 G92), G92 in the cold-rolled condition (H2 G92), G91 in the normalized and tempered condition, and hot-rolled HT-UPS. G91 was included as a reference to compare with advanced alloy, G92. It was found that all four alloys showed weight loss after sodium exposures at 550 and 650 C. The weight loss of the four alloys was comparable after sodium exposures at 550 C; the weight loss of ferritic-martensitic steels, G92 and G91 is more significant than that of austenitic stainless steel, HT-UPS after sodium exposures at 650 C. Sodium exposures up to 2700 h at 550 C had no significant influence on tensile properties, while sodium exposures up to 5064 h at 650 C dramatically lowered the tensile strengths of the four alloys. The ultimate tensile strength of H1 G92, H2 G92, and G91 ferritic-martensitic steels was reduced to as much as nearly half of its initial value after sodium exposures at 650 C. Though the uniform elongation was recovered to some extent, these three ferritic-martensitic steels showed considerable strain softening after sodium exposures. The yield stress of HT-UPS austenitic stainless steel increased, the ultimate tensile strength decreased, and the total elongation was reduced after sodium exposures at 650 C. The dynamic strain aging effect observed in the as-received HT-UPS specimens became less pronounced after sodium exposures at 650 C. Microstructural characterization of sodium-exposed specimens showed no appreciable surface deterioration or grain structure changes under an optical microscope, except for the H2 G92 steel, in which the martensite structure transformed to large grain ferrite after sodium exposures at 650 C. TEM observations of the sodium-exposed H2 G92 steel showed significant recrystallization after sodium exposure for 2700 h at 550 C, and transformation of martensite to ferrite and high density of precipitates in nearly dislocation-free matrix after sodium exposures at 650 C. Further microstructural analysis and evaluation of decarburization/carburization behavior is needed to understand the dramatic changes in the tensile strengths of advanced ferritic-martensitic and austenitic steels after sodium exposures at 650 C.

  13. The Sodium Content of Your Food.

    E-Print Network [OSTI]

    Anonymous,

    1982-01-01T23:59:59.000Z

    are usually processed without added salt. However, starchy vegetables such a s lima beans and peas frequently are sorted in brine before freezing. Frozen vegetables with added sauces, mushrooms or nuts are higher in sodium than plain varieties. Canned... ............................ Canned iced Powdaed. mn-flawred iced. sugarsweetened ......................... Low-calorie iced ....................... Thirst Quencher 1 cup 1 cup 1 cup 1 cup 1 cup 1 cup 1 cup 1 cup 1 cup 1 cup 1 cup 1 cup 1 cup 1 cup 8 fl oz Dairy...

  14. Efficacy of soluble sodium tripolyphosphate amendments for the...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of soluble sodium tripolyphosphate amendments for the in-situ immobilisation of uranium."Environmental Chemistry 4:293-300. Authors: DM Wellman EM Pierce MM Valenta...

  15. aqueous sodium sulfate: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    viscosity, 771, for PDMDAAC fractions in sodium chloride solutions by viscosity, size-exclusionchromatography, and light Dubin, Paul D. 32 Structure and Dynamics in Aqueous...

  16. Sodium fast reactor safety and licensing research plan. Volume II.

    SciTech Connect (OSTI)

    Ludewig, H. (Brokhaven National Laboratory, Upton, NY); Powers, D. A.; Hewson, John C.; LaChance, Jeffrey L.; Wright, A. (Argonne National Laboratory, Argonne, IL); Phillips, J.; Zeyen, R. (Institute for Energy Petten, Saint-Paul-lez-Durance, France); Clement, B. (IRSN/DPAM.SEMIC Bt 702, Saint-Paul-lez-Durance, France); Garner, Frank (Radiation Effects Consulting, Richland, WA); Walters, Leon (Advanced Reactor Concepts, Los Alamos, NM); Wright, Steve; Ott, Larry J. (Oak Ridge National Laboratory, Oak Ridge, TN); Suo-Anttila, Ahti Jorma; Denning, Richard (Ohio State University, Columbus, OH); Ohshima, Hiroyuki (Japan Atomic Energy Agency, Ibaraki, Japan); Ohno, S. (Japan Atomic Energy Agency, Ibaraki, Japan); Miyhara, S. (Japan Atomic Energy Agency, Ibaraki, Japan); Yacout, Abdellatif (Argonne National Laboratory, Argonne, IL); Farmer, M. (Argonne National Laboratory, Argonne, IL); Wade, D. (Argonne National Laboratory, Argonne, IL); Grandy, C. (Argonne National Laboratory, Argonne, IL); Schmidt, R.; Cahalen, J. (Argonne National Laboratory, Argonne, IL); Olivier, Tara Jean; Budnitz, R. (Lawrence Berkeley National Laboratory, Berkeley, CA); Tobita, Yoshiharu (Japan Atomic Energy Agency, Ibaraki, Japan); Serre, Frederic (Centre d'%C3%94etudes nucl%C3%94eaires de Cadarache, Cea, France); Natesan, Ken (Argonne National Laboratory, Argonne, IL); Carbajo, Juan J. (Oak Ridge National Laboratory, Oak Ridge, TN); Jeong, Hae-Yong (Korea Atomic Energy Research Institute, Daejeon, Korea); Wigeland, Roald (Idaho National Laboratory, Idaho Falls, ID); Corradini, Michael (University of Wisconsin-Madison, Madison, WI); Thomas, Justin (Argonne National Laboratory, Argonne, IL); Wei, Tom (Argonne National Laboratory, Argonne, IL); Sofu, Tanju (Argonne National Laboratory, Argonne, IL); Flanagan, George F. (Oak Ridge National Laboratory, Oak Ridge, TN); Bari, R. (Brokhaven National Laboratory, Upton, NY); Porter D. (Idaho National Laboratory, Idaho Falls, ID); Lambert, J. (Argonne National Laboratory, Argonne, IL); Hayes, S. (Idaho National Laboratory, Idaho Falls, ID); Sackett, J. (Idaho National Laboratory, Idaho Falls, ID); Denman, Matthew R.

    2012-05-01T23:59:59.000Z

    Expert panels comprised of subject matter experts identified at the U.S. National Laboratories (SNL, ANL, INL, ORNL, LBL, and BNL), universities (University of Wisconsin and Ohio State University), international agencies (IRSN, CEA, JAEA, KAERI, and JRC-IE) and private consultation companies (Radiation Effects Consulting) were assembled to perform a gap analysis for sodium fast reactor licensing. Expert-opinion elicitation was performed to qualitatively assess the current state of sodium fast reactor technologies. Five independent gap analyses were performed resulting in the following topical reports: (1) Accident Initiators and Sequences (i.e., Initiators/Sequences Technology Gap Analysis), (2) Sodium Technology Phenomena (i.e., Advanced Burner Reactor Sodium Technology Gap Analysis), (3) Fuels and Materials (i.e., Sodium Fast Reactor Fuels and Materials: Research Needs), (4) Source Term Characterization (i.e., Advanced Sodium Fast Reactor Accident Source Terms: Research Needs), and (5) Computer Codes and Models (i.e., Sodium Fast Reactor Gaps Analysis of Computer Codes and Models for Accident Analysis and Reactor Safety). Volume II of the Sodium Research Plan consolidates the five gap analysis reports produced by each expert panel, wherein the importance of the identified phenomena and necessities of further experimental research and code development were addressed. The findings from these five reports comprised the basis for the analysis in Sodium Fast Reactor Research Plan Volume I.

  17. Sodium cobalt bronze batteries and a method for making same

    DOE Patents [OSTI]

    Doeff, M.M.; Ma, Y.; Visco, S.J.; DeJonghe, L.

    1999-06-29T23:59:59.000Z

    A solid state secondary battery utilizing a low cost, environmentally sound, sodium cobalt bronze electrode is described. A method is provided for producing same. 11 figs.

  18. INITIATION OF DEGRADATION IN POLYCRYSTALLINE SODIUM-BETA ALUMINA ELECTROLYTES

    E-Print Network [OSTI]

    De Jonghe, L.C.

    2010-01-01T23:59:59.000Z

    boundaries. XBB 804 4130 2B Degradation initiation at 300 C,the Proceedings INITIATION OF DEGRADATION IN POLYCRYSTALLINEs w a m INITIATION OF DEGRADATION IN POLYCRYSTALLINE SODIUM-

  19. United States, France and Japan Increase Cooperation on Sodium...

    Broader source: Energy.gov (indexed) [DOE]

    together to establish design goals and high-level requirements for sodium-cooled fast reactor prototypes; identify common safety principles and key technical innovations to...

  20. Sodium dichromate expedited response action assessment

    SciTech Connect (OSTI)

    Not Available

    1993-09-01T23:59:59.000Z

    The US Environmental Protection Agency (EPA) and Washington Department of Ecology (Ecology) recommended that the US Department of Energy (DOE) perform an expedited response action (ERA) for the Sodium Dichromate Barrel Disposal Landfill. The ERA lead regulatory agency is Ecology and EPA is the support agency. The ERA was categorized as non-time-critical, which required preparation of an engineering evaluation and cost analysis (EE/CA). The EE/CA was included in the ERA proposal. The EE/CA is a rapid, focused evaluation of available technologies using specific screening factors to assess feasibility, appropriateness, and cost. The ERA goal is to reduce the potential for any contaminant migration from the landfill to the soil column, groundwater, and Columbia River. Since the Sodium Dichromate Barrel Disposal Landfill is the only waste site within the operable unit, the removal action may be the final remediation of the 100-IU-4 Operable Unit. This ERA process started in March 1992. The ERA proposal went through a parallel review process with Westinghouse Hanford Company (WHC), DOE Richland Operations (RL), EPA, Ecology, and a 30-day public comment period. Ecology and EPA issued an Action Agreement Memorandum in March 1993 (Appendix A). The memorandum directed excavation of all anomalies and disposal of the collected materials at the Hanford Site Central Landfill. Primary field activities were completed by the end of April 1993. Final waste disposal of a minor quantity of hazardous waste was completed in July 1993.

  1. SODIUM CYANIDE AS A FISH POISON Marine Biological Laboratory

    E-Print Network [OSTI]

    SODIUM CYANIDE AS A FISH POISON Marine Biological Laboratory APR 2 '^ 1958 WOODS HOLE, MASS CYANIDE AS A FISH POISON By W. R. Bridges Cooperative Fishery Research Laboratory Southern Illinois as a fish poison. At concentrations of 1 p. p.m. sodium cyanide and at a variety of temperature and p

  2. RESEARCH Open Access Half-molar sodium lactate infusion improves

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    RESEARCH Open Access Half-molar sodium lactate infusion improves cardiac performance in acute heart for the myocardium at rest and during stress. We tested the effects of half-molar sodium lactate infusion on cardiac by 1 ml/kg/h continuous infusion for 24 hours. The control group received only a 3 ml/kg bolus

  3. Low temperature sodium-beta battery

    DOE Patents [OSTI]

    Farmer, Joseph C

    2013-11-19T23:59:59.000Z

    A battery that will operate at ambient temperature or lower includes an enclosure, a current collector within the enclosure, an anode that will operate at ambient temperature or lower within the enclosure, a cathode that will operate at ambient temperature or lower within the enclosure, and a separator and electrolyte within the enclosure between the anode and the cathode. The anode is a sodium eutectic anode that will operate at ambient temperature or lower and is made of a material that is in a liquid state at ambient temperature or lower. The cathode is a low melting ion liquid cathode that will operate at ambient temperature or lower and is made of a material that is in a liquid state at ambient temperature or lower.

  4. Production of sodium-22 from proton irradiated aluminum

    DOE Patents [OSTI]

    Taylor, Wayne A. (Los Alamos, NM); Heaton, Richard C. (Los Alamos, NM); Jamriska, David J. (Los Alamos, NM)

    1996-01-01T23:59:59.000Z

    A process for selective separation of sodium-22 from a proton irradiated minum target including dissolving a proton irradiated aluminum target in hydrochloric acid to form a first solution including aluminum ions and sodium ions, separating a portion of the aluminum ions from the first solution by crystallization of an aluminum salt, contacting the remaining first solution with an anion exchange resin whereby ions selected from the group consisting of iron and copper are selectively absorbed by the anion exchange resin while aluminum ions and sodium ions remain in solution, contacting the solution with an cation exchange resin whereby aluminum ions and sodium ions are adsorbed by the cation exchange resin, and, contacting the cation exchange resin with an acid solution capable of selectively separating the adsorbed sodium ions from the cation exchange resin while aluminum ions remain adsorbed on the cation exchange resin is disclosed.

  5. Calcium and sodium bentonite for hydraulic containment applications

    SciTech Connect (OSTI)

    Gleason, M.H. [GeoSyntec Consultants, Columbia, MD (United States); Daniel, D.E. [Univ. of Illinois, Urbana, IL (United States). Dept. of Civil Engineering; Eykholt, G.R. [Univ. of Wisconsin, Madison, WI (United States). Dept. of Civil Engineering

    1997-05-01T23:59:59.000Z

    The hydraulic conductivity of calcium and sodium bentonites was investigated for sand-bentonite mixtures, a thin bentonite layer simulating a geosynthetic clay liner (GCL), and bentonite-cement mixtures simulating backfill for a vertical cutoff wall. The permeant liquids were tap water and distilled water containing 0.25 M calcium chloride. In general, the hydraulic performance of calcium bentonite was not significantly better than the performance of sodium bentonite for either the clay-amended sand or the GCL application, and was substantially worse than the performance of sodium bentonite in the bentonite-cement mixture. A drained angle of internal friction of 21{degree} was measured for calcium bentonite, compared to 10{degree} for sodium bentonite. Except for a larger drained shear strength, no advantage of calcium bentonite over sodium bentonite could be identified from the results of this study.

  6. Decommissioning of Experimental Breeder Reactor - II Complex, Post Sodium Draining

    SciTech Connect (OSTI)

    J. A. (Bart) Michelbacher; S. Paul Henslee; Collin J. Knight; Steven R. sherman

    2005-09-01T23:59:59.000Z

    The Experimental Breeder Reactor - II (EBR-II) was shutdown in September 1994 as mandated by the United States Department of Energy. This sodium-cooled reactor had been in service since 1964. The bulk sodium was drained from the primary and secondary systems and processed. Residual sodium remaining in the systems after draining was converted into sodium bicarbonate using humid carbon dioxide. This technique was tested at Argonne National Laboratory in Illinois under controlled conditions, then demonstrated on a larger scale by treating residual sodium within the EBR-II secondary cooling system, followed by the primary tank. This process, terminated in 2002, was used to place a layer of sodium bicarbonate over all exposed surfaces of sodium. Treatment of the remaining EBR-II sodium is governed by the Resource Conservation and Recovery Act (RCRA). The Idaho Department of Environmental Quality issued a RCRA Operating Permit in 2002, mandating that all hazardous materials be removed from EBR-II within a 10 year period, with the ability to extend the permit and treatment period for another 10 years. A preliminary plan has been formulated to remove the remaining sodium and NaK from the primary and secondary systems using moist carbon dioxide, steam and nitrogen, and a water flush. The moist carbon dioxide treatment was resumed in May 2004. As of August 2005, approximately 60% of the residual sodium within the EBR-II primary tank had been treated. This process will continue through the end of 2005, when it is forecast that the process will become increasingly ineffective. At that time, subsequent treatment processes will be planned and initiated. It should be noted that the processes and anticipated costs associated with these processes are preliminary. Detailed engineering has not been performed, and approval for these methods has not been obtained from the regulator or the sponsors.

  7. E-Print Network 3.0 - acetate sodium lactate Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    sodium-high lactate infusion'. Of course, it is easy to demonstrate that high lactate infusion... . Also, sodium-lactate infusion in humans ... Source: Ecole Polytechnique, Centre...

  8. Hazard categorization and classification for the sodium storage facility

    SciTech Connect (OSTI)

    Van Keuren, J.C.

    1994-08-30T23:59:59.000Z

    The Sodium Storage Facility is planned to be constructed in the 400 area for long term storage of sodium from the Fast Flux Test Facility (FFTF). It will contain four large sodium storage tanks. Three of the tanks have a capacity of 80,000 gallons of sodium each, and the fourth will hold 52,500 gallons. The tanks will be connected by piping with each other and to the FFTF. Sodium from the FFTF primary and secondary Heat Transport Systems (HTS), Interim Decay Storage (IDS), and the Fuel Storage Facility (FSF) will be transferred to the facility, and stored there in a frozen state pending final disposition. A Hazard Classification has been performed in order to evaluate the potential toxic consequences of a sodium fire according to the provisions of DOE Order 5481.1B. The conclusion of these evaluations is that the Sodium Storage Facility meets the requirements of the lowest Hazard Category, i.e., radiological facility, and the Hazard Classification is recommended to be moderate.

  9. Experimental investigations on sodium plugging in narrow flow channels.

    SciTech Connect (OSTI)

    Momozaki, Y.; Cho, D. H.; Sienicki, J. J.; Moisseytsev, A.; Nuclear Engineering Division

    2010-08-01T23:59:59.000Z

    A series of experiments was performed to investigate the potential for plugging of narrow flow channels of sodium by impurities (e.g., oxides). In the first phase of the experiments, clean sodium was circulated through the test sections simulating flow channels in a compact diffusion-bonded heat exchanger such as a printed circuit heat exchanger. The primary objective was to see if small channels whose cross sections are semicircles of 2, 4, and 6 mm in diameter are usable in liquid sodium applications where sodium purity is carefully controlled. It was concluded that the 2-mm channels, the smallest of the three, could be used in clean sodium systems at temperatures even as low as 100 to 110 C without plugging. In the second phase, sodium oxide was added to the loop, and the oxygen concentration in the liquid sodium was controlled by means of varying the cold-trap temperature. Intentional plugging was induced by creating a cold spot in the test sections, and the subsequent plugging behavior was observed. It was found that plugging in the 2-mm test section was initiated by lowering the cold spot temperature below the cold-trap temperature by 10 to 30 C. Unplugging of the plugged channels was accomplished by heating the affected test section.

  10. Risk Management for Sodium Fast Reactors.

    SciTech Connect (OSTI)

    Denman, Matthew R; Groth, Katrina; Cardoni, Jeffrey N; Wheeler, Timothy A.

    2015-01-01T23:59:59.000Z

    Accident management is an important component to maintaining risk at acceptable levels for all complex systems, such as nuclear power plants. With the introduction of self - correcting, or inherently safe, reactor designs the focus has shifted from management by operators to allowing the syste m's design to manage the accident. While inherently and passively safe designs are laudable, extreme boundary conditions can interfere with the design attributes which facilitate inherent safety , thus resulting in unanticipated and undesirable end states. This report examines an inherently safe and small sodium fast reactor experiencing a beyond design basis seismic event with the intend of exploring two issues : (1) can human intervention either improve or worsen the potential end states and (2) can a Bayes ian Network be constructed to infer the state of the reactor to inform (1). ACKNOWLEDGEMENTS The author s would like to acknowledge the U.S. Department of E nergy's Office of Nuclear Energy for funding this research through Work Package SR - 14SN100303 under the Advanced Reactor Concepts program. The authors also acknowledge the PRA teams at A rgonne N ational L aborator y , O ak R idge N ational L aborator y , and I daho N ational L aborator y for their continue d contributions to the advanced reactor PRA mission area.

  11. Sodium Ion Insertion in Hollow Carbon Nanowires for Battery Applicatio...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    B Schwenzer, J Xiao, Z Nie, LV Saraf, Z Yang, and J Liu.2012."Sodium Ion Insertion in Hollow Carbon Nanowires for Battery Applications."Nano Letters 12(7):37833787....

  12. Title of dissertation: HYDROMAGNETIC TURBULENT INSTABILITY IN LIQUID SODIUM

    E-Print Network [OSTI]

    Lathrop, Daniel P.

    ABSTRACT Title of dissertation: HYDROMAGNETIC TURBULENT INSTABILITY IN LIQUID SODIUM EXPERIMENTS Daniel R. Sisan, Doctor of Philosophy, 2004 Dissertation directed by: Professor Daniel P. Lathrop Department of Physics This dissertation describes the observation of magnetically-induced instabil- ities

  13. aged sodium borophosphate: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ultraviolet flux will produce a similar variation in the column of neutral sodium for a fixed mass flux and density. However, if the cold gas is in pressure equilibrium with a hot...

  14. Sodium-cooled Fast Reactor - Past and Future | Argonne National...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sodium-cooled Fast Reactor - Past and Future June 16, 2015 10:00AM to 11:00AM Presenter Taek K. Kim (NE), Principal Nuclear Engineer and Department Manager Location Building 205,...

  15. aluminum sodium chloride: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    made with either sodium chloride or potassium chloride. The addition of 75 or 150 porn N02 did not lower plate counts (P&0. 05... Kayfus, Timothy Jon 2012-06-07 47...

  16. aerated sodium chloride: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    made with either sodium chloride or potassium chloride. The addition of 75 or 150 porn N02 did not lower plate counts (P&0. 05... Kayfus, Timothy Jon 2012-06-07 39 Evaluation...

  17. aqueous sodium chloride: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    made with either sodium chloride or potassium chloride. The addition of 75 or 150 porn N02 did not lower plate counts (P&0. 05... Kayfus, Timothy Jon 2012-06-07 58 Systematic...

  18. acidified sodium chlorite: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Summary: In order to improve a new design for a uranium startup sodium cooled fast reactor which was proposed at MIT, this thesis evaluated radial power flattening by varying...

  19. Loop simulation capability for sodium-cooled systems

    E-Print Network [OSTI]

    Adekugbe, Oluwole A.

    1984-01-01T23:59:59.000Z

    A one-dimensional loop simulation capability has been implemented in the thermal-hydraulic analysis code, THERMIT-4E. This code had been used to simulate and investigate flow in test sections of experimental sodium loops ...

  20. Probabilistic transient analysis of fuel choices for sodium fast reactors

    E-Print Network [OSTI]

    Denman, Matthew R

    2011-01-01T23:59:59.000Z

    This thesis presents the implications of using a risk-informed licensing framework to inform the design of Sodium Fast Reactors. NUREG-1860, more commonly known as the Technology Neutral Framework (TNF), is a risk-informed ...

  1. Reactor protection system design alternatives for sodium fast reactors

    E-Print Network [OSTI]

    DeWitte, Jacob D. (Jacob Dominic)

    2011-01-01T23:59:59.000Z

    Historically, unprotected transients have been viewed as design basis events that can significantly challenge sodium-cooled fast reactors. The perceived potential consequences of a severe unprotected transient in a ...

  2. A Photoelectron Spectroscopic and Computational Study of Sodium...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The global minimum of Na3Au3 - has a bent-flake structure lying 0.077 eV below a more compact structure. The global minima of the sodium auride clusters are confirmed by the...

  3. SLAM: a sodium-limestone concrete ablation model

    SciTech Connect (OSTI)

    Suo-Anttila, A.J.

    1983-12-01T23:59:59.000Z

    SLAM is a three-region model, containing a pool (sodium and reaction debris) region, a dry (boundary layer and dehydrated concrete) region, and a wet (hydrated concrete) region. The model includes a solution to the mass, momentum, and energy equations in each region. A chemical kinetics model is included to provide heat sources due to chemical reactions between the sodium and the concrete. Both isolated model as well as integrated whole code evaluations have been made with good results. The chemical kinetics and water migration models were evaluated separately, with good results. Several small and large-scale sodium limestone concrete experiments were simulated with reasonable agreement between SLAM and the experimental results. The SLAM code was applied to investigate the effects of mixing, pool temperature, pool depth and fluidization. All these phenomena were found to be of significance in the predicted response of the sodium concrete interaction. Pool fluidization is predicted to be the most important variable in large scale interactions.

  4. Sodium bicarbonate and Alkaten as buffers in beef cattle diets

    E-Print Network [OSTI]

    Boerner, Benedict Joseph

    1985-01-01T23:59:59.000Z

    SODIUM BICARBONATE AND ALKATEN AS BUFFERS IN BEEF CATTLE DIETS A Thesis by BENED ICT JOSEP H BOERNER Submitted to the Graduate College of Texas A8M University im partial fulfillment of the requirements for the degree of MASTER OF SC IENCE... August 1985 Major Subject: Nutrition SODIUM BICARBONATE AND ALKATEN AS BUFFERS IN BEEF CATTLE DIETS A thesis by BENEDICT JOSEPH BOERNER Approved as to style and content by: Flo M. Byers (Chairma of Committee) ~r( Gerald T. Schelling (Member...

  5. The Salt or Sodium Chloride Content of Feeds

    E-Print Network [OSTI]

    Fraps, G. S. (George Stronach); Lomanitz, S. (Sebastian)

    1920-01-01T23:59:59.000Z

    1 EXAS AGRICULTURAL EXPERIMENT STATION AGRICULTURAL AND MECHANICAL COLLEGE OF TEXAS W. B. BIZZELL, Preeident BULLETIN NO. 271 OCTOBER, 1920 DIVISION OF CHEMISTRY THE SALT OR SODIUM CHLORIDE CONTENT OF FEEDS B. YOUNGBLOOD, DIRECTOK COLLEGE.... ............... Salt content of feecls.. ......... Salt content of mixed feeds.. ................... Summary ancl conclusions. Page. l1 [Blank Page in Original Bulletin] BULLETIN XO. 271. OCTOBE- '"On THE SALT OR SODIUM CHLORIDE CONTENT OF FEI The Texas feed...

  6. Classification : Original Article VOLTAGE-GATED SODIUM CHANNELS POTENTIATE THE INVASIVE

    E-Print Network [OSTI]

    Boyer, Edmond

    - gated sodium channels in non-small-cell lung cancer cell lines. Functional voltage-gated sodium channels cancerous cell lines H23, H460 and Calu-1 possess functional sodium channels while normal and weakly metastatic cell lines do not. While all the cell lines expressed mRNA for numerous sodium channel isoforms

  7. Advanced sodium fast reactor accident source terms : research needs.

    SciTech Connect (OSTI)

    Powers, Dana Auburn; Clement, Bernard [IRSN/DPAM.SEMIC Bt 702, Saint-Paul-lez-Durance, France; Denning, Richard [Ohio State University, Columbus, OH; Ohno, Shuji [Japan Atomic Energy Agency, Ibaraki, Japan; Zeyen, Roland [Institute for Energy Petten, Saint-Paul-lez-Durance, France

    2010-09-01T23:59:59.000Z

    An expert opinion elicitation has been used to evaluate phenomena that could affect releases of radionuclides during accidents at sodium-cooled fast reactors. The intent was to identify research needed to develop a mechanistic model of radionuclide release for licensing and risk assessment purposes. Experts from the USA, France, the European Union, and Japan identified phenomena that could affect the release of radionuclides under hypothesized accident conditions. They qualitatively evaluated the importance of these phenomena and the need for additional experimental research. The experts identified seven phenomena that are of high importance and have a high need for additional experimental research: High temperature release of radionuclides from fuel during an energetic eventEnergetic interactions between molten reactor fuel and sodium coolant and associated transfer of radionuclides from the fuel to the coolantEntrainment of fuel and sodium bond material during the depressurization of a fuel rod with breached claddingRates of radionuclide leaching from fuel by liquid sodiumSurface enrichment of sodium pools by dissolved and suspended radionuclidesThermal decomposition of sodium iodide in the containment atmosphereReactions of iodine species in the containment to form volatile organic iodides. Other issues of high importance were identified that might merit further research as development of the mechanistic model of radionuclide release progressed.

  8. publication 348-827 Sodium is a necessary part of our diet. Sodium helps our bodies keep the right

    E-Print Network [OSTI]

    Liskiewicz, Maciej

    amount of water, but we only need a little bit. The most common form of sodium is found in table salt-fashioned oatmeal Pasta and rice Peas, beans, and lentils Plain popcorn Pudding Seeds Unsalted nuts Whole

  9. Aluminum Zintl anion moieties within sodium aluminum clusters

    SciTech Connect (OSTI)

    Wang, Haopeng; Zhang, Xinxing; Ko, Yeon Jae; Grubisic, Andrej; Li, Xiang; Ganteför, Gerd; Bowen, Kit H., E-mail: AKandalam@wcupa.edu, E-mail: kiran@mcneese.edu, E-mail: kbowen@jhu.edu [Department of Chemistry, Johns Hopkins University, Baltimore, Maryland 21218 (United States); Schnöckel, Hansgeorg [Institute of Inorganic Chemistry, Karlsruhe Institute of Technology, 76128 Karlsruhe (Germany)] [Institute of Inorganic Chemistry, Karlsruhe Institute of Technology, 76128 Karlsruhe (Germany); Eichhorn, Bryan W. [Department of Chemistry, University of Maryland at College Park, College Park, Maryland 20742 (United States)] [Department of Chemistry, University of Maryland at College Park, College Park, Maryland 20742 (United States); Lee, Mal-Soon; Jena, P. [Department of Physics, Virginia Commonwealth University, Richmond, Virginia 23284 (United States)] [Department of Physics, Virginia Commonwealth University, Richmond, Virginia 23284 (United States); Kandalam, Anil K., E-mail: AKandalam@wcupa.edu, E-mail: kiran@mcneese.edu, E-mail: kbowen@jhu.edu [Department of Physics, West Chester University of Pennsylvania, West Chester, Pennsylvania 19383 (United States); Kiran, Boggavarapu, E-mail: AKandalam@wcupa.edu, E-mail: kiran@mcneese.edu, E-mail: kbowen@jhu.edu [Department of Chemistry, McNeese State University, Lake Charles, Louisiana 70609 (United States)] [Department of Chemistry, McNeese State University, Lake Charles, Louisiana 70609 (United States)

    2014-02-07T23:59:59.000Z

    Through a synergetic combination of anion photoelectron spectroscopy and density functional theory based calculations, we have established that aluminum moieties within selected sodium-aluminum clusters are Zintl anions. Sodium–aluminum cluster anions, Na{sub m}Al{sub n}{sup ?}, were generated in a pulsed arc discharge source. After mass selection, their photoelectron spectra were measured by a magnetic bottle, electron energy analyzer. Calculations on a select sub-set of stoichiometries provided geometric structures and full charge analyses for both cluster anions and their neutral cluster counterparts, as well as photodetachment transition energies (stick spectra), and fragment molecular orbital based correlation diagrams.

  10. The magnesium nutrition of cotton as influenced by sodium 

    E-Print Network [OSTI]

    Thenabadu, Mervyn Wellesly

    1964-01-01T23:59:59.000Z

    1964 Major Subject. Plant Physic logy THE MAGNESIUM NUTRITION OF COTTON AS INFLUENCED BY SODIUM A Thesis By MERVYN M. THENABADU Approved as to style and content by: Chairman of Commi. e Nun Head of Department Member Mem, er Member Member... REVIEW OF LITERATURE (a) Sodium as a plant nutrient (b) I'he role of magnesium in plant nutrition MATERIALS AND METHODS RESUL:S DISCUSSION 13 21 24 (a) The effect of treatments on grcwth and reproduction (b) The effect of treatments on the ccr...

  11. Method of Manufacturing Micro-Disperse Particles of Sodium Borohydride

    DOE Patents [OSTI]

    Kravitz, Stanley H. (Placitas, NM); Hecht, Andrew M. (Sandia Park, NM); Sylwester. Alan P. (Albuquerque, NM); Bell, Nelson S. (Albuquerque, NM)

    2008-09-23T23:59:59.000Z

    A compact solid source of hydrogen gas, where the gas is generated by contacting water with micro-disperse particles of sodium borohydride in the presence of a catalyst, such as cobalt or ruthenium. The micro-disperse particles can have a substantially uniform diameter of 1-10 microns, and preferably about 3-5 microns. Ruthenium or cobalt catalytic nanoparticles can be incorporated in the micro-disperse particles of sodium borohydride, which allows a rapid and complete reaction to occur without the problems associated with caking and scaling of the surface by the reactant product sodium metaborate. A closed loop water management system can be used to recycle wastewater from a PEM fuel cell to supply water for reacting with the micro-disperse particles of sodium borohydride in a compact hydrogen gas generator. Capillary forces can wick water from a water reservoir into a packed bed of micro-disperse fuel particles, eliminating the need for using an active pump.

  12. Method of generating hydrogen gas from sodium borohydride

    DOE Patents [OSTI]

    Kravitz, Stanley H. (Placitas, NM); Hecht, Andrew M. (Sandia Park, NM); Sylwester, Alan P. (Albuquerque, NM); Bell, Nelson S. (Albuquerque, NM)

    2007-12-11T23:59:59.000Z

    A compact solid source of hydrogen gas, where the gas is generated by contacting water with micro-disperse particles of sodium borohydride in the presence of a catalyst, such as cobalt or ruthenium. The micro-disperse particles can have a substantially uniform diameter of 1-10 microns, and preferably about 3-5 microns. Ruthenium or cobalt catalytic nanoparticles can be incorporated in the micro-disperse particles of sodium borohydride, which allows a rapid and complete reaction to occur without the problems associated with caking and scaling of the surface by the reactant product sodium metaborate. A closed loop water management system can be used to recycle wastewater from a PEM fuel cell to supply water for reacting with the micro-disperse particles of sodium borohydride in a compact hydrogen gas generator. Capillary forces can wick water from a water reservoir into a packed bed of micro-disperse fuel particles, eliminating the need for using an active pump.

  13. ORIGINAL RESEARCH Systematic family-wide analysis of sodium bicarbonate

    E-Print Network [OSTI]

    Hall, Randy A

    ORIGINAL RESEARCH Systematic family-wide analysis of sodium bicarbonate cotransporter NBCn1/SLC4A7/NBCn1 pulled down syntrophin c2 and con- versely GST/syntrophin c2 pulled down NBCn1. Moreover normally moves Na+ and HCO3 Ã? into cells and protects intracel- lular pH (pHi) from falling below normal

  14. Immobilization of sodium nitrate waste with polymers: Topical report

    SciTech Connect (OSTI)

    Franz, E.M.; Heiser, J.H. III; Colombo, P.

    1987-04-01T23:59:59.000Z

    This report describes the development of solidification systems for sodium nitrate waste. Sodium nitrate waste was solidified in the polymers polyethylene, polyester-styrene (PES), and water-extendible polyester-styrene (WEP). Evaluations were made of the properties of waste forms containing various amounts of sodium nitrate by leaching immersion in water, measuring compressive strengths and by the EPA Extraction Procedure. Results of the leaching test are presented as cumulative fraction leached (CFL), incremental leaching rate, and average leaching indices (LI). For waste forms containing 30 to 70 wt% sodium nitrate, the CFL ranged from 9.0 x 10/sup -3/ to 7.3 x 10/sup -1/ and the LI from 11 to 7.8. After ninety days immersion in water, the compressive strengths ranged from 720 psi to 2550 psi. The nitrate releases from these samples using the EPA Extraction Procedure were below 500 ppM. The nitrate releases from PES waste forms were similar to those from polyethylene waste forms at the same waste loadings. The compressive yield strengths, measured after ninety-day immersion in water, ranged between 2070 and 7710 psi. In the case of WEP waste forms, only 30 wt% loaded samples passed the immersion test. 23 refs., 24 figs., 12 tabs.

  15. Electrochemical Recovery of Sodium Hydroxide from Alkaline Salt Solution

    SciTech Connect (OSTI)

    Hobbs, D.T. [Westinghouse Savannah River Company, AIKEN, SC (United States); Edwards, T.B.

    1996-10-01T23:59:59.000Z

    A statistically designed set of tests determined the effects of current density, temperature, and the concentrations of nitrate/nitrite, hydroxide and aluminate on the recovery of sodium as sodium hydroxide (caustic) from solutions simulating those produced from the Savannah River Site (SRS) In-Tank Precipitation process. These tests included low nitrate and nitrite concentrations which would be produced by electrolytic nitrate/nitrite destruction. The tests used a two compartment electrochemical cell with a Nafion Type 324 ion-exchange membrane. Caustic was successfully recovered from the waste solutions. Evaluation of the testing results indicated that the transport of sodium across the membrane was not significantly affected by any of the varied parameters. The observed variance in the sodium flux is attributed to experimental errors and variations in the performance characteristics of individual pieces of the organic-based Nafion membrane.Additional testing is recommended to determine the maximum current density, to evaluate the chemical durability of the organic membrane as a function of current density and to compare the durability and performance characteristics of the organic-based Nafion membrane with that of other commercially available organic membranes and the inorganic class of membranes under development by Ceramatec and PNNL.

  16. Compatibility Assessment of Advanced Stainless Steels in Sodium

    SciTech Connect (OSTI)

    Pawel, Steven J [ORNL

    2012-01-01T23:59:59.000Z

    Type 316L stainless steel capsules containing commercially pure sodium and miniature tensile specimens of HT-UPS (austenitic, 14Cr-16Ni), NF-616 (ferritic/martensitic, 9Cr-2W-0.5Mo), or 316L (austenitic, 17Cr-10Ni-2Mo) stainless steel were exposed at 600 or 700 C for 100 and 400 h as a screening test for compatibility. Using weight change, tensile testing, and metallographic analysis, HT-UPS and 316L were found to be largely immune to changes resulting from sodium exposure, but NF-616 was found susceptible to substantial decarburization at 700 C. Subsequently, two thermal convection loops (TCLs) constructed of 316L and loaded with commercially pure sodium and miniature tensile specimens of HT-UPS and 316L were operated for 2000 h each one between 500 and 650 C, the other between 565 and 725 C at a flow rate of about 1.5 cm/s. Changes in specimen appearance, weight, and tensile properties were observed to be very minor in all cases, and there was no metallographic evidence of microstructure changes, composition gradients, or mass transfer resulting from prolonged exposure in a TCL. Thus, it appears that HT-UPS and 316L stainless steels are similarly compatible with commercially pure sodium under these exposure conditions.

  17. Gypsum and Polyacrylamide Soil Amendments Used With High Sodium Wastewater

    E-Print Network [OSTI]

    Gardiner, Duane

    and sodium. Two soil amendments were applied to plots furrowirrigated with wastewater. The amendments were gypsum (11 Mg ha-1), and PAM added to irrigation water at rates of 25 mg L-1 PAM applications were made during every irrigation and during every second...

  18. Laboratory-scale sodium-carbonate aggregate concrete interactions. [LMFBR

    SciTech Connect (OSTI)

    Westrich, H.R.; Stockman, H.W.; Suo-Anttila, A.

    1983-09-01T23:59:59.000Z

    A series of laboratory-scale experiments was made at 600/sup 0/C to identify the important heat-producing chemical reactions between sodium and carbonate aggregate concretes. Reactions between sodium and carbonate aggregate were found to be responsible for the bulk of heat production in sodium-concrete tests. Exothermic reactions were initiated at 580+-30/sup 0/C for limestone and dolostone aggregates as well as for hydrated limestone concrete, and at 540+-10/sup 0/C for dehydrated limestone concrete, but were ill-defined for dolostone concrete. Major reaction products included CaO, MgO, Na/sub 2/CO/sub 3/, Na/sub 2/O, NaOH, and elemental carbon. Sodium hydroxide, which forms when water is released from cement phases, causes slow erosion of the concrete with little heat production. The time-temperature profiles of these experiments have been modeled with a simplified version of the SLAM computer code, which has allowed derivation of chemical reaction rate coefficients.

  19. Agrin regulation of alpha3 sodium-potassium ATPase activity modulates cardiac myocyte contraction.

    E-Print Network [OSTI]

    2009-01-01T23:59:59.000Z

    in the U.S.A. Agrin Regulation of ? 3 Sodium-Potassiumis modulated by agrin regulation of ? 3 Na,K-ATPasegated sodium channels, capa- regulation of cardiac myocyte

  20. apical sodium-chloride cotransporter: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    g magnesium chloride, 3.24 g magnesium sulfate bromide, 34 mg strontium chloride, 22 mg boric acid, 4 mg sodium silicate, 2.4 mg sodium fluoride, 1.6 mg Bae, Jin-Woo 302 The...

  1. Method of and apparatus for removing silicon from a high temperature sodium coolant

    DOE Patents [OSTI]

    Yunker, W.H.; Christiansen, D.W.

    1983-11-25T23:59:59.000Z

    This patent discloses a method of and system for removing silicon from a high temperature liquid sodium coolant system for a nuclear reactor. The sodium is cooled to a temperature below the silicon saturation temperature and retained at such reduced temperature while inducing high turbulence into the sodium flow for promoting precipitation of silicon compounds and ultimate separation of silicon compound particles from the liquid sodium.

  2. Go No-Go Recommendation for Sodium Borohydride for On-Board Vehicular Hydrogen Storage

    Fuel Cell Technologies Publication and Product Library (EERE)

    Independent review panel recommendation for go/no go decision on use of hydrolysis of sodium borohydride for hydrogen storage.

  3. E-Print Network 3.0 - affecting sodium hypochlorite Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    -Partial list Chemical Incompatibilities Summary: hypochlorite, all oxidizing agents Carbon tetrachloride Sodium Chlorates Ammonium salts, acids, powdered metals... and...

  4. Teaching Sodium Fast Reactor Technology and Operation for the Present and Future Generations of SFR Users

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Teaching Sodium Fast Reactor Technology and Operation for the Present and Future Generations of SFR or development of sodium fast reactors and related experimental facilities. The sum of courses provided by CEA on sodium fast reactor design, technology, safety and operation experience, decommissioning aspects

  5. Ultracold Molecules from Ultracold Atoms: Interactions in Sodium and Lithium Gas

    E-Print Network [OSTI]

    Ultracold Molecules from Ultracold Atoms: Interactions in Sodium and Lithium Gas by Caleb from Ultracold Atoms: Interactions in Sodium and Lithium Gas by Caleb A Christensen Submitted of Philosophy Abstract The thesis presents results from experiments in which ultracold Sodium-6 and Lithium-23

  6. Synthesis of highly ordered mesoporous silica materials using sodium silicate and amphiphilic block copolymers

    E-Print Network [OSTI]

    Kim, Ji Man

    Synthesis of highly ordered mesoporous silica materials using sodium silicate and amphiphilic block) structures, using sodium silicate as the silica source and amphiphilic block copolymers as the structure of mesoporous silica material using nonionic surfac- tant and sodium silicate in the pH range 3­10.5. However

  7. The use of sodium and/or potassium lactate to extend shelf-life and reduce sodium levels in precooked beef systems 

    E-Print Network [OSTI]

    Pagach, Denise Ann

    1992-01-01T23:59:59.000Z

    of the requirements for the degree of MASTER OF SCIENCE May 1992 Major Subject: Food Science and Technology THE USE OF SODIUM AND/OR POTASSIUM LACTATE TO EXTEND SHELF-LIFE AND REDUCE SODIUM LEVELS IN PRECOOKED BEEF SYSTEMS A Thesis by DENISE ANN PAGACH... ABSTRACT The Use of Sodium and/or Potassium Lactate to Extend Shelf-Life and Reduce Sodium Levels in Precooked Beef Systems. (May 1992) Denise Ann Pagach, B. S. , Texas AdtM University Chair of Advisory Committee: Dr. R. K. Miller Concern for food...

  8. Clinch River breeder reactor sodium fire protection system design and development

    SciTech Connect (OSTI)

    Foster, K.W.; Boasso, C.J.; Kaushal, N.N.

    1984-04-13T23:59:59.000Z

    To assure the protection of the public and plant equipment, improbable accidents were hypothesized to form the basis for the design of safety systems. One such accident is the postulated failure of the Intermediate Heat Transfer System (IHTS) piping within the Steam Generator Building (SGB), resulting in a large-scale sodium fire. This paper discusses the design and development of plant features to reduce the consequences of the accident to acceptable levels. Additional design solutions were made to mitigate the sodium spray contribution to the accident scenario. Sodium spill tests demonstrated that large sodium leaks can be safely controlled in a sodium-cooled nuclear power plant.

  9. Cleaning Cesium Radionuclides from BN-350 Primary Sodium

    SciTech Connect (OSTI)

    Romanenko, O.G.; Allen, K.J.; Wachs, D.M.; Planchon, H.P.; Wells, P.B.; Michelbacher, J.A.; Nazarenko, P.; Dumchev, I.; Maev, V.; Zemtzev, B.; Tikhomirov, L.; Yakovlev, V.; Synkov, A

    2005-04-15T23:59:59.000Z

    This paper reports the successful design and operation of a system to remove highly radioactive cesium from the sodium coolant of the BN-350 reactor in Aktau, Kazakhstan. As an international effort between the United States and the Republic of Kazakhstan, a cesium-trapping system was jointly designed, fabricated, installed, and successfully operated. The results are significant for a number of reasons, including (a) a significant reduction of radioactivity levels of the BN-350 coolant and reactor surfaces, thereby reducing exposure to workers during shutdown operations; (b) demonstration of scientific ideas; and (c) the engineering application of effective cesium trap deployment for commercial-sized liquid-metal reactors. About 255 300 GBq (6900 Ci) of cesium was trapped, and the {sup 137}Cs specific activity in BN-350 primary sodium was decreased from 296 MBq/kg (8000 {mu}Ci/kg) to 0.37 MBq/kg (10 {mu}Ci/kg) by using seven cesium traps containing reticulated vitreous carbon (RVC) as the cesium adsorbent. Cesium trapping was accomplished by pumping sodium from the primary circuit, passing it through a block of RVC within each trap, and returning the cleaned sodium to the primary circuit. Both to predict and to analyze the behavior of the cesium traps in the BN-350 reactor primary circuit, a model was developed that satisfactorily describes the observed results of the cesium trapping. By using this model, thermodynamic parameters, such as the heat of adsorption of cesium atoms on RVC and on internal piping surfaces of the BN-350 reactor primary circuit, -22.7 and -5.0 kJ/mole, respectively, were extracted from the experimental data.

  10. Selective Adsorption of Sodium Aluminum Fluoride Salts from Molten Aluminum

    SciTech Connect (OSTI)

    Leonard S. Aubrey; Christine A. Boyle; Eddie M. Williams; David H. DeYoung; Dawid D. Smith; Feng Chi

    2007-08-16T23:59:59.000Z

    Aluminum is produced in electrolytic reduction cells where alumina feedstock is dissolved in molten cryolite (sodium aluminum fluoride) along with aluminum and calcium fluorides. The dissolved alumina is then reduced by electrolysis and the molten aluminum separates to the bottom of the cell. The reduction cell is periodically tapped to remove the molten aluminum. During the tapping process, some of the molten electrolyte (commonly referred as “bath” in the aluminum industry) is carried over with the molten aluminum and into the transfer crucible. The carryover of molten bath into the holding furnace can create significant operational problems in aluminum cast houses. Bath carryover can result in several problems. The most troublesome problem is sodium and calcium pickup in magnesium-bearing alloys. Magnesium alloying additions can result in Mg-Na and Mg-Ca exchange reactions with the molten bath, which results in the undesirable pickup of elemental sodium and calcium. This final report presents the findings of a project to evaluate removal of molten bath using a new and novel micro-porous filter media. The theory of selective adsorption or removal is based on interfacial surface energy differences of molten aluminum and bath on the micro-porous filter structure. This report describes the theory of the selective adsorption-filtration process, the development of suitable micro-porous filter media, and the operational results obtained with a micro-porous bed filtration system. The micro-porous filter media was found to very effectively remove molten sodium aluminum fluoride bath by the selective adsorption-filtration mechanism.

  11. Rare-earth metal gallium silicides via the gallium self-flux method. Synthesis, crystal structures, and magnetic properties of RE(Ga1–xSix)? (RE=Y, La–Nd, Sm, Gd–Yb, Lu)

    SciTech Connect (OSTI)

    Darone, Gregory M.; Hmiel, Benjamin; Zhang, Jiliang [Department of Chemistry and Biochemistry, University of Delaware, Newark, Delaware 19716 (United States); Saha, Shanta; Kirshenbaum, Kevin; Greene, Richard; Paglione, Johnpierre [Department of Physics, University of Maryland, College Park, Maryland 20742 (United States); Bobev, Svilen, E-mail: bobev@udel.edu [Department of Chemistry and Biochemistry, University of Delaware, Newark, Delaware 19716 (United States)

    2013-05-01T23:59:59.000Z

    Fifteen ternary rare-earth metal gallium silicides have been synthesized using molten Ga as a molten flux. They have been structurally characterized by single-crystal and powder X-ray diffraction to form with three different structures—the early to mid-late rare-earth metals RE=La–Nd, Sm, Gd–Ho, Yb and Y form compounds with empirical formulae RE(GaxSi1–x)? (0.38?x?0.63), which crystallize with the tetragonal ?-ThSi? structure type (space group I4?/amd, No. 141; Pearson symbol tI12). The compounds of the late rare-earth crystallize with the orthorhombic ?-GdSi? structure type (space group Imma, No. 74; Pearson symbol oI12), with refined empirical formula REGaxSi2–x–y (RE=Ho, Er, Tm; 0.33?x?0.40, 0.10?y?0.18). LuGa?.?????Si?.????? crystallizes with the orthorhombic YbMn?.??Si?.?? structure type (space group Cmcm, No. 63; Pearson symbol oC24). Structural trends are reviewed and analyzed; the magnetic susceptibilities of the grown single-crystals are presented. - Graphical abstract: This article details the exploration of the RE–Ga–Si ternary system with the aim to systematically investigate the structural “boundaries” between the ?-ThSi? and ?-GdSi?-type structures, and studies of the magnetic properties of the newly synthesized single-crystalline materials. Highlights: • Light rare-earth gallium silicides crystallize in ?-ThSi? structure type. • Heavy rare-earth gallium silicides crystallize in ?-GdSi? structure type. • LuGaSi crystallizes in a defect variant of the YbMn?.??Si?.?? structure type.

  12. Sodium-Bearing Waste Treatment, Applied Technology Plan

    SciTech Connect (OSTI)

    Lance Lauerhass; Vince C. Maio; S. Kenneth Merrill; Arlin L. Olson; Keith J. Perry

    2003-06-01T23:59:59.000Z

    Settlement Agreement between the Department of Energy and the State of Idaho mandates treatment of sodium-bearing waste at the Idaho Nuclear Technology and Engineering Center within the Idaho National Engineering and Environmental Laboratory. One of the requirements of the Settlement Agreement is to complete treatment of sodium-bearing waste by December 31, 2012. Applied technology activities are required to provide the data necessary to complete conceptual design of four identified alternative processes and to select the preferred alternative. To provide a technically defensible path forward for the selection of a treatment process and for the collection of needed data, an applied technology plan is required. This document presents that plan, identifying key elements of the decision process and the steps necessary to obtain the required data in support of both the decision and the conceptual design. The Sodium-Bearing Waste Treatment Applied Technology Plan has been prepared to provide a description/roadmap of the treatment alternative selection process. The plan details the results of risk analyzes and the resulting prioritized uncertainties. It presents a high-level flow diagram governing the technology decision process, as well as detailed roadmaps for each technology. The roadmaps describe the technical steps necessary in obtaining data to quantify and reduce the technical uncertainties associated with each alternative treatment process. This plan also describes the final products that will be delivered to the Department of Energy Idaho Operations Office in support of the office's selection of the final treatment technology.

  13. Sodium Chloride interaction with solvated and crystalline cellulose : sodium ion affects the tetramer and fibril in aqueous solution

    E-Print Network [OSTI]

    Bellesia, Giovanni

    2013-01-01T23:59:59.000Z

    Inorganic salts are a natural component of biomass which have a significant effect on the product yields from a variety of biomass conversion processes. Understanding their effect on biomass at the microscopic level can help discover their mechanistic role. We present a study of the effect of aqueous sodium chloride (NaCl) on the largest component of biomass, cellulose, focused on the thermodynamic and structural effect of a sodium ion on the cellulose tetramer, and fibril. Replica exchange molecular dynamics simulations of a cellulose tetramer reveal a number of preferred cellulose-Na contacts and bridging positions. Large scale MD simulations on a model cellulose fibril find that Na+ perturbs the hydroxymethyl rotational state population and consequently disrupts the "native" hydrogen bonding network.

  14. High Sodium Simulant Testing To Support SB8 Sludge Preparation

    SciTech Connect (OSTI)

    Newell, J. D.

    2012-09-19T23:59:59.000Z

    Scoping studies were completed for high sodium simulant SRAT/SME cycles to determine any impact to CPC processing. Two SRAT/SME cycles were performed with simulant having sodium supernate concentration of 1.9M at 130% and 100% of the Koopman Minimum Acid requirement. Both of these failed to meet DWPF processing objectives related to nitrite destruction and hydrogen generation. Another set of SRAT/SME cycles were performed with simulant having a sodium supernate concentration of 1.6M at 130%, 125%, 110%, and 100% of the Koopman Minimum Acid requirement. Only the run at 110% met DWPF processing objectives. Neither simulant had a stoichiometric factor window of 30% between nitrite destruction and excessive hydrogen generation. Based on the 2M-110 results it was anticipated that the 2.5M stoichiometric window for processing would likely be smaller than from 110-130%, since it appeared that it would be necessary to increase the KMA factor by at least 10% above the minimum calculated requirement to achieve nitrite destruction due to the high oxalate content. The 2.5M-130 run exceeded the DWPF hydrogen limits in both the SRAT and SME cycle. Therefore, testing of this wash endpoint was halted. This wash endpoint with this minimum acid requirement and mercury-noble metal concentration profile appears to be something DWPF should not process due to an overly narrow window of stoichiometry. The 2M case was potentially processable in DWPF, but modifications would likely be needed in DWPF such as occasionally accepting SRAT batches with undestroyed nitrite for further acid addition and reprocessing, running near the bottom of the as yet ill-defined window of allowable stoichiometric factors, potentially extending the SRAT cycle to burn off unreacted formic acid before transferring to the SME cycle, and eliminating formic acid additions in the frit slurry.

  15. Modelling of ultrasonic propagation in turbulent liquid sodium with temperature gradient

    SciTech Connect (OSTI)

    Massacret, N. [CEA, DEN, Nuclear Technology Department, F-13108 Saint-Paul-Lez-Durance (France); Aix-Marseille Université, LMA UPR 7051 CNRS, site LCND, 13625 Aix-en-Provence (France); Moysan, J., E-mail: joseph.moysan@univ-amu.fr; Ploix, M. A.; Corneloup, G. [Aix-Marseille Université, LMA UPR 7051 CNRS, site LCND, 13625 Aix-en-Provence (France); Jeannot, J. P. [CEA, DEN, Nuclear Technology Department, F-13108 Saint-Paul-Lez-Durance (France)

    2014-05-28T23:59:59.000Z

    The use of ultrasonic instrumentation in sodium-cooled fast reactors requires to understand and to predict how ultrasonic waves can be deflected, slowed down or speeded up, depending on the thermo-hydraulic characteristics of the liquid sodium. These thermo-hydraulic characteristics are mainly the local temperature and flow speed of the sodium. In this study we show that ray theory can be used to simulate ultrasonic propagation in a medium similar to the core of a sodium-cooled fast reactor, in order to study ultrasonic instrumentation and prepare it installation and utilisation in the sodium of the nuclear reactor. A suitable model has been developed and a set of thermo-hydraulics data has been created, taking account of the particularities of the sodium flow. The results of these simulations are then analysed within the framework of acoustic thermometry, in order to determine which disturbance must be taken into account for the correct operation of the temperature measurement.

  16. Interaction Between Trace Metals, Sodium and Sorbents in Combustion.

    SciTech Connect (OSTI)

    Wendt, O.L.; Davis, S.

    1997-10-17T23:59:59.000Z

    The proposed research is directed at an understanding of how to exploit interactions between sodium, toxic metals and sorbents, in order to optimize sorbents injection procedures, which can be used to capture and transform these metals into environmentally benign forms. The research will use a 17kW downflow, laboratory combustor, to yield data that can be interpreted in terms of fundamental kinetic mechanisms. Metals to be considered are lead, cadmium, and arsenic. Sorbents will be kaolinite, bauxite, and limestone. The role of sulfur will also be determined.

  17. Practical features of illumination with high pressure sodium lamps

    SciTech Connect (OSTI)

    Corth, R.

    1983-06-01T23:59:59.000Z

    A number of concerns raised about the health effects of high pressure sodium lamps (HPS) are discussed. The notion of a ''natural'' human photic environment based on sunlight is disputed. Humans are better adapted to the ''greenish'' spectral composition of forest light than to direct sunlight. It is ironic that the artificial light source which has received the most disapproval, cool white flourescent lamp, has a spectral composition similar to that of forest light. HPS is also available in a full range of colors. Some successful examples of HPS--from North Division High School, in Milwaukee, Wisconsin, to museum exhibits at National Geographic in Washington--are listed.

  18. DRESDYN - A new facility for MHD experiments with liquid sodium

    E-Print Network [OSTI]

    Stefani, F; Gerbeth, G; Giesecke, A; Gundrum, Th; Steglich, C; Weier, T; Wustmann, B

    2012-01-01T23:59:59.000Z

    The DREsden Sodium facility for DYNamo and thermohydraulic studies (DRESDYN) is intended as a platform both for large scale experiments related to geo- and astrophysics as well as for experiments related to thermohydraulic and safety aspects of liquid metal batteries and liquid metal fast reactors. The most ambitious projects in the framework of DRESDYN are a homogeneous hydromagnetic dynamo driven solely by precession and a large Taylor-Couette type experiment for the combined investigation of the magnetorotational instability and the Tayler instability. In this paper we give a short summary about the ongoing preparations and delineate the next steps for the realization of DRESDYN.

  19. Fact Sheet: Sodium-Beta Batteries (October 2012)

    Office of Environmental Management (EM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 1112011AT&T,OfficeEnd ofEvaluations in Covered Facilities |List ofSodium-Beta Batteries

  20. Sodium hypochlorite Market Trends | OpenEI Community

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnualProperty Edit with form HistoryRistmaSinosteel CorporationSocovoltaic Systems JumpSodium

  1. Safe and Effective Deactivation of Metallic Sodium Filled Scrap and Cold Traps From Sodium-cooled Nuclear Reactor D and D - 12176

    SciTech Connect (OSTI)

    Nester, Dean [CH2M HILL Plateau Remediation Company - CHPRC (United States); Crocker, Ben [Commodore Advanced Sciences, Inc. (United States); Smart, Bill [IMPACT Services, Inc. (United States)

    2012-07-01T23:59:59.000Z

    As part of the Plateau Remediation Project at US Department of Energy's Hanford, Washington site, CH2M Hill Plateau Remediation Company (CHPRC) contracted with IMPACT Services, LLC to receive and deactivate approximately 28 cubic meters of sodium metal contaminated debris from two sodium-cooled research reactors (Enrico Fermi Unit 1 and the Fast Flux Test Facility) which had been stored at Hanford for over 25 years. CHPRC found an off-site team composed of IMPACT Services and Commodore Advanced Sciences, Inc., with the facilities and technological capabilities to safely and effectively perform deactivation of this sodium metal contaminated debris. IMPACT Services provided the licensed fixed facility and the logistical support required to receive, store, and manage the waste materials before treatment, and the characterization, manifesting, and return shipping of the cleaned material after treatment. They also provided a recycle outlet for the liquid sodium hydroxide byproduct resulting from removal of the sodium from reactor parts. Commodore Advanced Sciences, Inc. mobilized their patented AMANDA unit to the IMPACT Services site and operated the unit to perform the sodium removal process. Approximately 816 Kg of metallic sodium were removed and converted to sodium hydroxide, and the project was accomplished in 107 days, from receipt of the first shipment at the IMPACT Services facility to the last outgoing shipment of deactivated scrap metal. There were no safety incidents of any kind during the performance of this project. The AMANDA process has been demonstrated in this project to be both safe and effective for deactivation of sodium and NaK. It has also been used in other venues to treat other highly reactive alkali metals, such as lithium (Li), potassium (K), NaK and Cesium (Cs). (authors)

  2. Effect of Sodium on the Catalytic Properties of VOx/CeO2 Catalysts...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    dehydrogenation (ODH) of methanol. The effect of sodium on the surface structure, redox properties, and surface aciditybasicity of VOxCeO2 was investigated using hydrogen...

  3. EIS-0306: Treatment and Management of Sodium-Bonded Spent Nuclear Fuel

    Broader source: Energy.gov [DOE]

    DOE prepared a EIS that evaluated the potential environmental impacts of treatment and management of DOE-owned sodium bonded spent nuclear fuel.

  4. Sodium fast reactor safety and licensing research plan. Volume I.

    SciTech Connect (OSTI)

    Sofu, Tanju (Argonne National Laboratory, Argonne, IL); LaChance, Jeffrey L.; Bari, R. (Brokhaven National Laboratory Upton, NY); Wigeland, Roald (Idaho National Laboratory, Idaho Falls, ID); Denman, Matthew R.; Flanagan, George F. (Oak Ridge National Laboratory, Oak Ridge, TN)

    2012-05-01T23:59:59.000Z

    This report proposes potential research priorities for the Department of Energy (DOE) with the intent of improving the licensability of the Sodium Fast Reactor (SFR). In support of this project, five panels were tasked with identifying potential safety-related gaps in available information, data, and models needed to support the licensing of a SFR. The areas examined were sodium technology, accident sequences and initiators, source term characterization, codes and methods, and fuels and materials. It is the intent of this report to utilize a structured and transparent process that incorporates feedback from all interested stakeholders to suggest future funding priorities for the SFR research and development. While numerous gaps were identified, two cross-cutting gaps related to knowledge preservation were agreed upon by all panels and should be addressed in the near future. The first gap is a need to re-evaluate the current procedures for removing the Applied Technology designation from old documents. The second cross-cutting gap is the need for a robust Knowledge Management and Preservation system in all SFR research areas. Closure of these and the other identified gaps will require both a reprioritization of funding within DOE as well as a re-evaluation of existing bureaucratic procedures within the DOE associated with Applied Technology and Knowledge Management.

  5. REACTIONS OF SODIUM PEROXIDE WITH COMPONENTS OF LEGACY PLUTONIUM MATERIALS

    SciTech Connect (OSTI)

    Pierce, R.; Missimer, D.; Crowder, M.

    2011-10-04T23:59:59.000Z

    Plutonium oxide (PuO{sub 2}) calcined at >900 C resists dissolution in nitric acid (HNO{sub 3})-potassium fluoride (KF) solutions, a common method for their dissolution. The Savannah River National Laboratory (SRNL) has developed an alternate method for large samples of PuO{sub 2}-bearing materials using sodium peroxide (Na{sub 2}O{sub 2}) fusion as a pretreatment. The products of the reaction between Na{sub 2}O{sub 2} and PuO{sub 2} have been reported in the literature. As part of the SRNL development effort, additional data about the reaction between Na{sub 2}O{sub 2} and PuO{sub 2} were required. Also needed were data concerning the reaction of Na{sub 2}O{sub 2} with other components that may be present in the feed materials. Sodium peroxide was reacted with aluminum metal (Al), beryllium metal (Be), graphite, potassium chloride (KCl), magnesium chloride (MgCl{sub 2}), and calcium chloride (CaCl{sub 2}). The paper reports and discusses the reaction products of these and related compounds with Na{sub 2}O{sub 2}.

  6. Selection of materials for sodium fast reactor steam generators

    SciTech Connect (OSTI)

    Dubiez-Le Goff, S.; Garnier, S.; Gelineau, O. [AREVA (France); Dalle, F. [Commissariat a l'energie atomique et aux energies alternatives - CEA (France); Blat-Yrieix, M.; Augem, J. M. [Electricite de France - EDF (France)

    2012-07-01T23:59:59.000Z

    Sodium Fast Reactor (SFR) is considered in France as the most mature technology of the different Generation IV systems. In the short-term the designing work is focused on the identification of the potential tracks to demonstrate licensing capability, availability, in-service inspection capability and economical performance. In that frame materials selection for the major components, as the steam generator, is a particularly key point managed within a French Research and Development program launched by AREVA, CEA and EDF. The choice of the material for the steam generator is indeed complex because various aspects shall be considered like mechanical and thermal properties at high temperature, interaction with sodium on one side and water and steam on the other side, resistance to wastage, procurement, fabrication, weldability and ability for inspection and in-situ intervention. The following relevant options are evaluated: the modified 9Cr1Mo ferritic-martensitic grade and the Alloy 800 austenitic grade. The objective of this paper is to assess for both candidates their abilities to reach the current SFR needs regarding material design data, from AFCEN RCC-MRx Code in particular, compatibility with environments and manufacturability. (authors)

  7. Sequential Treatment by Ionizing Radiation and Sodium Arsenite Dramatically Accelerates TRAIL-Mediated Apoptosis of

    E-Print Network [OSTI]

    is critically important in the translocation of death receptor to the cell surface. Moreover, sodium arsenite and further down-regulates cFLIP levels in melanoma cells. We have evaluated the effects of sequentialSequential Treatment by Ionizing Radiation and Sodium Arsenite Dramatically Accelerates TRAIL

  8. Effect of sodium chloride concentration on the heat resistance and recovery of

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Effect of sodium chloride concentration on the heat resistance and recovery of Salmonella inhibitory effect in the recovery media. Keywords : Salmonella typhimurium, Sodium chloride, Heat treatment, but they also generate damaged cells. The ability of heated cells to survive depends on the recovery conditions

  9. Adsorption of Sodium Dodecyl Sulfate on Functionalized Graphene Measured by Conductometric Titration

    E-Print Network [OSTI]

    Aksay, Ilhan A.

    Adsorption of Sodium Dodecyl Sulfate on Functionalized Graphene Measured by Conductometric States ABSTRACT: We report on the adsorption of sodium dodecyl sulfate (SDS) onto functionalized graphene-to- oxygen ratio of 18, monolayer adsorption of SDS on FGS reaches full surface coverage by 12 M SDS

  10. Challenges and Innovative Technologies On Fuel Handling Systems for Future Sodium-Cooled Fast Reactors

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    , AREVA, and EDF have an extensive experience and significant expertise in sodium-cooled fast reactorsChallenges and Innovative Technologies On Fuel Handling Systems for Future Sodium-Cooled Fast Reactors Mathieu CHASSIGNET1;Ã , Sebastien DUMAS1 , Christophe PENIGOT1 , Ge´rard PRELE2 , Alain CAPITAINE2

  11. 4June2013 Page 1 of 8 Sodium Hydroxide (Pellets) SOP Standard Operating Procedures

    E-Print Network [OSTI]

    Cohen, Ronald C.

    4June2013 Page 1 of 8 Sodium Hydroxide (Pellets) SOP Standard Operating Procedures Strong Corrosives ­ Strong Bases (SB) Sodium Hydroxide (Pellets) PrintOH Form: pellets Color: white Melting point/freezing point: 318 °C (604 °F

  12. Atomistic structure of sodium and calcium silicate intergranular films in alumina

    E-Print Network [OSTI]

    Garofalini, Stephen H.

    Atomistic structure of sodium and calcium silicate intergranular films in alumina David A. Litton March 1998; accepted 21 October 1998) Sodium silicate intergranular films (IGF) in contact. The results were compared to previous simulations of calcium silicate and sol-gel silica IGF's in contact

  13. Volume 33, number 2 OPTICS COMMUNICATIONS May 1980 THE PROCESS OF ENERGY TRANSFER BETWEENEXCITED SODIUM ATOMS

    E-Print Network [OSTI]

    Stroud Jr., Carlos R.

    Volume 33, number 2 OPTICS COMMUNICATIONS May 1980 THE PROCESS OF ENERGY TRANSFER BETWEENEXCITED SODIUM ATOMS J. KRASINSKI, T. STACEWICZ Institute of Experimental Physics WarsawUniversity, 00681 Warsaw,Poland(nX) denotes the sodium atom in one of the higher excited states. The energy difference AE is supplied

  14. Sodium fast reactor fuels and materials : research needs.

    SciTech Connect (OSTI)

    Denman, Matthew R.; Porter, Douglas (Idaho National Laboratory, Idaho Falls, ID); Wright, Art (Argonne National Laboratory Argonne, IL); Lambert, John (Argonne National Laboratory Argonne, IL); Hayes, Steven (Idaho National Laboratory, Idaho Falls, ID); Natesan, Ken (Argonne National Laboratory Argonne, IL); Ott, Larry J. (Oak Ridge National Laboratory, Oak Ridge, TN); Garner, Frank (Radiation Effects Consulting. Richland, WA); Walters, Leon (Advanced Reactor Concepts, Idaho Falls, ID); Yacout, Abdellatif (Argonne National Laboratory Argonne, IL)

    2011-09-01T23:59:59.000Z

    An expert panel was assembled to identify gaps in fuels and materials research prior to licensing sodium cooled fast reactor (SFR) design. The expert panel considered both metal and oxide fuels, various cladding and duct materials, structural materials, fuel performance codes, fabrication capability and records, and transient behavior of fuel types. A methodology was developed to rate the relative importance of phenomena and properties both as to importance to a regulatory body and the maturity of the technology base. The technology base for fuels and cladding was divided into three regimes: information of high maturity under conservative operating conditions, information of low maturity under more aggressive operating conditions, and future design expectations where meager data exist.

  15. Sodium-Bearing Waste Treatment Alternatives Implementation Study

    SciTech Connect (OSTI)

    Charles M. Barnes; James B. Bosley; Clifford W. Olsen

    2004-07-01T23:59:59.000Z

    The purpose of this document is to discuss issues related to the implementation of each of the five down-selected INEEL/INTEC radioactive liquid waste (sodium-bearing waste - SBW) treatment alternatives and summarize information in three main areas of concern: process/technical, environmental permitting, and schedule. Major implementation options for each treatment alternative are also identified and briefly discussed. This report may touch upon, but purposely does not address in detail, issues that are programmatic in nature. Examples of these include how the SBW will be classified with respect to the Nuclear Waste Policy Act (NWPA), status of Waste Isolation Pilot Plant (WIPP) permits and waste storage availability, available funding for implementation, stakeholder issues, and State of Idaho Settlement Agreement milestones. It is assumed in this report that the SBW would be classified as a transuranic (TRU) waste suitable for disposal at WIPP, located in New Mexico, after appropriate treatment to meet transportation requirements and waste acceptance criteria (WAC).

  16. Feasibility Study for Vitrification of Sodium-Bearing Waste

    SciTech Connect (OSTI)

    J. J. Quigley; B. D. Raivo; S. O. Bates; S. M. Berry; D. N. Nishioka; P. J. Bunnell

    2000-09-01T23:59:59.000Z

    Treatment of sodium-bearing waste (SBW) at the Idaho Nuclear Technology and Engineering Center (INTEC) within the Idaho National Engineering and Environmental Laboratory is mandated under a Settlement Agreement between the Department of Energy and the State of Idaho. One of the requirements of the Settlement Agreement is the complete calcination (i.e., treatment) of all SBW by December 31, 2012. One of the proposed options for treatment of SBW is vitrification. This study will examine the viability of SBW vitrification. This study describes the process and facilities to treat the SBW, from beginning waste input from INTEC Tank Farm to the final waste forms. Schedules and cost estimates for construction and operation of a Vitrification Facility are included. The study includes a facility layout with drawings, process description and flow diagrams, and preliminary equipment requirements and layouts.

  17. Some aspects of materials development for sodium heated steam generators

    SciTech Connect (OSTI)

    Roy, P.; Spalaris, C.N.

    1980-10-01T23:59:59.000Z

    A development program was undertaken to support the materials selection for steam generator piping and IHX which are to be used in Liquid Metal Fast Breeder Reactors (LMFBR). Four major topics were reviewed, describing the results obtained as well as the direction of future tests. These topics are: carbon transport in sodium, effect of carbon loss/gain upon materials in the reactor Intermediate Heat Transport System (IHTS), corrosion fatigue and aqueous corrosion. The results support the initial assumptions made in specifying the use of 2-1/4Cr-1Mo as the construction material for the evaporator and superheater and Type 316 piping of the IHT system. Future direction of the experimental programs is to further verify the materials choice and to also obtain information which will be essential during the plant installation, operation and reliability of the components.

  18. Hybrid sodium heat pipe receivers for dish/Stirling systems

    SciTech Connect (OSTI)

    Laing, D.; Reusch, M. [Deutsche Forschungsanstalt fuer Luft- und Raumfahrt e.V., Stuttgart (Germany). Inst. fuer Technische Thermodynamik

    1997-12-31T23:59:59.000Z

    The design of a hybrid solar/gas heat pipe receiver for the SBP 9 kW dish/Stirling system using a United Stirling AB V160 Stirling engine and the results of on-sun testing in alternative and parallel mode will be reported. The receiver is designed to transfer a thermal power of 35 kW. The heat pipe operates at around 800 C, working fluid is sodium. Operational options are solar-only, gas augmented and gas-only mode. Also the design of a second generation hybrid heat pipe receiver currently developed under a EU-funded project, based on the experience gained with the first hybrid receiver, will be reported. This receiver is designed for the improved SPB/L. and C.-10 kW dish/Stirling system with the reworked SOLO V161 Stirling engine.

  19. Impact of Sodium Layer variations on the performance of the E-ELT MCAO module

    E-Print Network [OSTI]

    Schreiber, L; Arcidiacono, C; Pfrommer, T; Holzlöhner, R; Lombini, M; Hickson, P

    2015-01-01T23:59:59.000Z

    Multi-Conjugate Adaptive Optics systems based on sodium Laser Guide Stars may exploit Natural Guide Stars to solve intrinsic limitations of artificial beacons (tip-tilt indetermination and anisoplanatism) and to mitigate the impact of the sodium layer structure and variability. The sodium layer may also have transverse structures leading to differential effects among Laser Guide Stars. Starting from the analysis of the input perturbations related to the Sodium Layer variability, modeled directly on measured sodium layer profiles, we analyze, through a simplified end-to-end simulation code, the impact of the low/medium orders induced on global performance of the European Extremely Large Telescope Multi-Conjugate Adaptive Optics module MAORY.

  20. Sodium Heat Engine Development Program. Phase 1, Final report

    SciTech Connect (OSTI)

    Singh, J.P.; Kupperman, D.S.; Majumdar, S.; Dorris, S.; Gopalsami, N.; Dieckman, S.L.; Jaross, R.A.; Johnson, D.L.; Gregar, J.S.; Poeppel, R.B.; Raptis, A.C.; Valentin, R.A.

    1992-01-01T23:59:59.000Z

    The Sodium Heat Engine (SHE) is an efficient thermoelectric conversion device which directly generates electricity from a thermally regenerative electrochemical cell that relies on the unique conduction properties of {beta}{double_prime}-alumina solid electrolyte (BASE). Laboratory models of a variety of SHE devices have demonstrated the feasibility and efficiency of the system, engineering development of large prototype devices has been slowed by a series of materials and fabrication problems. Failure of the electrolyte tubes has been a recurring problem and a number of possible causes have been postulated. To address these issues, a two-phase engineering development program was undertaken. This report summarizes the final results of the first phase of the program, which included extensive materials characterization activities, a study of applicable nondestructive evaluation methods, an investigation of possible stress states that would contribute to fracture, and certain operational issues associated with the electromagnetic pumps used in the SHE prototype. Mechanical and microstructural evaluation of commercially obtained BASE tubes revealed that they should be adequate for SHE applications and that sodium exposure produced no appreciable deleterious strength effects. Processing activities to produce a more uniform and smaller grain size for the BASE tubes were completed using isostatic pressing, extrusion, and slip casting. Green tubes were sintered by conventional and microwave plasma methods. Of particular interest is the residual stress state in the BASE tubes, and both analysis and nondestructive evaluation methods were employed to evaluate these stresses. X-ray and neutron diffraction experiments were performed to determine the bulk residual stresses in commercially fabricated BASE tubes; however, tube-to-tube variations and variations among the various methods employed did not allow formulation of a definitive definition of the as-fabricated stress state.

  1. 105-DR Large Sodium Fire Facility closure plan. Revision 1

    SciTech Connect (OSTI)

    Not Available

    1993-05-01T23:59:59.000Z

    The Hanford Site, located northwest of the city of Richland, Washington, houses reactors, chemical-separation systems, and related facilities used for the production of special nuclear materials, and activities associated with nuclear energy development. The 105-DR Large Sodium Fire Facility (LSFF), which was in operation from about 1972 to 1986, was a research laboratory that occupied the former ventilation supply room on the southwest side of the 105-DR Reactor facility. The LSFF was established to provide a means of investigating fire and safety aspects associated with large sodium or other metal alkali fires in the liquid metal fast breeder reactor (LMFBR) facilities. The 105-DR Reactor facility was designed and built in the 1950`s and is located in the 100-D Area of the Hanford Site. The building housed the 105-DR defense reactor, which was shut down in 1964. The LSFF was initially used only for engineering-scale alkali metal reaction studies. In addition, the Fusion Safety Support Studies program sponsored intermediate-size safety reaction tests in the LSFF with lithium and lithium lead compounds. The facility has also been used to store and treat alkali metal waste, therefore the LSFF is subject to the regulatory requirements for the storage and treatment of dangerous waste. Closure will be conducted pursuant to the requirements of the Washington Administrative Code (WAC) 173-303-610. This closure plan presents a description of the facility, the history of waste managed, and the procedures that will be followed to close the LSFF as an Alkali Metal Treatment Facility. No future use of the LSFF is expected.

  2. Sodium-Beta Batteries for Grid-Scale Storage: Planar Sodium-Beta Batteries for Renewable Integration and Grid Applications

    SciTech Connect (OSTI)

    None

    2010-02-01T23:59:59.000Z

    Broad Funding Opportunity Announcement Project: EaglePicher is developing a sodium-beta alumina (Na-Beta) battery for grid-scale energy storage. High-temperature Na-Beta batteries are a promising grid-scale energy storage technology, but existing approaches are expensive and unreliable. EaglePicher has modified the shape of the traditional, tubular-shaped Na-Beta battery. It is using an inexpensive stacked design to improve performance at lower temperatures, leading to a less expensive overall storage technology. The new design greatly simplifies the manufacturing process for beta alumina membranes (a key enabling technology), providing a subsequent pathway to the production of scalable, modular batteries at half the cost of the existing tubular designs.

  3. Environmental, health, and safety issues of sodium-sulfur batteries for electric and hybrid vehicles

    SciTech Connect (OSTI)

    Hammel, C.J.

    1992-09-01T23:59:59.000Z

    This report examines the shipping regulations that govern the shipment of dangerous goods. Since the elemental sodium contained in both sodium-sulfur and sodium-metal-chloride batteries is classified as a dangerous good, and is listed on both the national and international hazardous materials listings, both national and international regulatory processes are considered in this report The interrelationships as well as the differences between the two processes are highlighted. It is important to note that the transport regulatory processes examined in this report are reviewed within the context of assessing the necessary steps needed to provide for the domestic and international transport of sodium-beta batteries. The need for such an assessment was determined by the Shipping Sub-Working Group (SSWG) of the EV Battery Readiness Working Group (Working Group), created in 1990. The Working Group was created to examine the regulatory issues pertaining to in-vehicle safety, shipping, and recycling of sodium-sulfur batteries, each of which is addressed by a sub-working group. The mission of the SSWG is to establish basic provisions that will ensure the safe and efficient transport of sodium-beta batteries. To support that end, a proposal to the UN Committee of Experts was prepared by the SSWG, with the goal of obtaining a proper shipping name and UN number for sodium-beta batteries and to establish the basic transport requirements for such batteries (see the appendix for the proposal as submitted). It is emphasized that because batteries are large articles containing elemental sodium and, in some cases, sulfur, there is no existing UN entry under which they can be classified and for which modal transport requirements, such as the use of packaging appropriate for such large articles, are provided for. It is for this reason that a specific UN entry for sodium-beta batteries is considered essential.

  4. Structure of rhenium-containing sodium borosilicate glass

    SciTech Connect (OSTI)

    Goel, Ashutosh; McCloy, John S.; Windisch, Charles F.; Riley, Brian J.; Schweiger, Michael J.; Rodriguez, Carmen P.; Ferreira, Jose M.

    2013-03-01T23:59:59.000Z

    A series of sodium borosilicate glasses were synthesized with increasing fractions of KReO4 or Re2O7, to 10000 ppm (1 mass%) target Re in glass, to assess the effects of large concentrations of rhenium on glass structure and to estimate the solubility of technetium, a radioactive component in typical low active waste nuclear waste glasses. Magic angle spinning nuclear magnetic resonance (MAS-NMR), Fourier transform infrared (FTIR) spectroscopy, and Raman spectroscopy were performed to characterize the glasses as a function of Re source additions. In general, silicon was found coordinated in a mixture of Q2 and Q3 structural units, while Al was 4-coordinated and B was largely 3-coordinate and partially 4-coordinated. The rhenium source did not appear to have significant effects on the glass structure. Thus, at the up to the concentrations that remain in dissolved in glass, ~3000 ppm Re by mass maximum. , the Re appeared to be neither a glass-former nor a strong glass modifier., Rhenium likely exists in isolated ReO4- anions in the interstices of the glass network, as evidenced by the polarized Raman spectrum of the Re glass in the absence of sulfate. Analogous to SO42-¬ in similar glasses, ReO4- is likely a network modifier and forms alkali salt phases on the surface and in the bulk glass above solubility.

  5. Sodium-bearing Waste Treatment Technology Evaluation Report

    SciTech Connect (OSTI)

    Charles M. Barnes; Arlin L. Olson; Dean D. Taylor

    2004-05-01T23:59:59.000Z

    Sodium-bearing waste (SBW) disposition is one of the U.S. Department of Energy (DOE) Idaho Operation Office’s (NE-ID) and State of Idaho’s top priorities at the Idaho National Engineering and Environmental Laboratory (INEEL). The INEEL has been working over the past several years to identify a treatment technology that meets NE-ID and regulatory treatment requirements, including consideration of stakeholder input. Many studies, including the High-Level Waste and Facilities Disposition Environmental Impact Statement (EIS), have resulted in the identification of five treatment alternatives that form a short list of perhaps the most appropriate technologies for the DOE to select from. The alternatives are (a) calcination with maximum achievable control technology (MACT) upgrade, (b) steam reforming, (c) cesium ion exchange (CsIX) with immobilization, (d) direct evaporation, and (e) vitrification. Each alternative has undergone some degree of applied technical development and preliminary process design over the past four years. This report presents a summary of the applied technology and process design activities performed through February 2004. The SBW issue and the five alternatives are described in Sections 2 and 3, respectively. Details of preliminary process design activities for three of the alternatives (steam reforming, CsIX, and direct evaporation) are presented in three appendices. A recent feasibility study provides the details for calcination. There have been no recent activities performed with regard to vitrification; that section summarizes and references previous work.

  6. Example Work Domain Analysis for a Reference Sodium Fast Reactor

    SciTech Connect (OSTI)

    Hugo, Jacques [Idaho National Lab. (INL), Idaho Falls, ID (United States); Oxstrand, Johanna [Idaho National Lab. (INL), Idaho Falls, ID (United States)

    2015-01-01T23:59:59.000Z

    The nuclear industry is currently designing and building a new generation of reactors that will include different structural, functional, and environmental aspects, all of which are likely to have a significant impact on the way these plants are operated. In order to meet economic and safety objectives, these new reactors will all use advanced technologies to some extent, including new materials and advanced digital instrumentation and control systems. New technologies will affect not only operational strategies, but will also require a new approach to how functions are allocated to humans or machines to ensure optimal performance. Uncertainty about the effect of large scale changes in plant design will remain until sound technical bases are developed for new operational concepts and strategies. Up-to-date models and guidance are required for the development of operational concepts for complex socio-technical systems. This report describes how the classical Work Domain Analysis method was adapted to develop operational concept frameworks for new plants. This adaptation of the method is better able to deal with the uncertainty and incomplete information typical of first-of-a-kind designs. Practical examples are provided of the systematic application of the method in the operational analysis of sodium-cooled reactors. Insights from this application and its utility are reviewed and arguments for the formal adoption of Work Domain Analysis as a value-added part of the Systems Engineering process are presented.

  7. EXTENDING SODIUM FAST REACTOR DRIVER FUEL USE TO HIGHER TEMPERATURES

    SciTech Connect (OSTI)

    Douglas L. Porter

    2011-02-01T23:59:59.000Z

    Calculations of potential sodium-cooled fast reactor fuel temperatures were performed to estimate the effects of increasing the outlet temperature of a given fast reactor design by increasing pin power, decreasing assembly flow, or increasing inlet temperature. Based upon experience in the U.S., both metal and mixed oxide (MOX) fuel types are discussed in terms of potential performance effects created by the increased operating temperatures. Assembly outlet temperatures of 600, 650 and 700 °C were used as goal temperatures. Fuel/cladding chemical interaction (FCCI) and fuel melting, as well as challenges to the mechanical integrity of the cladding material, were identified as the limiting phenomena. For example, starting with a recent 1000 MWth fast reactor design, raising the outlet temperature to 650 °C through pin power increase increased the MOX centerline temperature to more than 3300 °C and the metal fuel peak cladding temperature to more than 700 °C. These exceeded limitations to fuel performance; fuel melting was limiting for MOX and FCCI for metal fuel. Both could be alleviated by design ‘fixes’, such as using a barrier inside the cladding to minimize FCCI in the metal fuel, or using annular fuel in the case of MOX. Both would also require an advanced cladding material with improved stress rupture properties. While some of these are costly, the benefits of having a high-temperature reactor which can support hydrogen production, or other missions requiring high process heat may make the extra costs justified.

  8. Applying risk informed methodologies to improve the economics of sodium-cooled fast reactors

    E-Print Network [OSTI]

    Nitta, Christopher C

    2010-01-01T23:59:59.000Z

    In order to support the increasing demand for clean sustainable electricity production and for nuclear waste management, the Sodium-Cooled Fast Reactor (SFR) is being developed. The main drawback has been its high capital ...

  9. Development of a model to predict flow oscillations in low-flow sodium boiling

    E-Print Network [OSTI]

    Levin, Alan Edward

    1980-01-01T23:59:59.000Z

    An experimental and analytical program has been carried out in order to better understand the cause and effect of flow oscillations in boiling sodium systems. These oscillations have been noted in previous experiments with ...

  10. Chemically Bonded Phosphorus/Graphene Hybrid as a High Performance Anode for Sodium-Ion Batteries

    SciTech Connect (OSTI)

    Song, Jiangxuan; Yu, Zhaoxin; Gordin, Mikhail; Hu, Shilin; Yi, Ran; Tang, Duihai; Walter, Timothy; Regula, Michael; Choi, Daiwon; Li, Xiaolin; Manivannan, Ayyakkannu; Wang, Donghai

    2014-11-12T23:59:59.000Z

    Room temperature sodium-ion batteries are of great interest for high-energy-density energy storage systems because of low-cost, natural abundance of sodium. Here, we report a novel graphene nanosheets-wrapped phosphorus composite as an anode for high performance sodium-ion batteries though a facile ball-milling of red phosphorus and graphene nanosheets. Not only can the graphene nanosheets significantly improve the electrical conductivity, but they also serve as a buffer layer to accommodate the large volume change of phosphorus in the charge-discharge process. As a result, the graphene wrapped phosphorus composite anode delivers a high reversible capacity of 2077 mAh/g with excellent cycling stability (1700 mAh/g after 60 cycles) and high Coulombic efficiency (>98%). This simple synthesis approach and unique nanostructure can potentially extend to other electrode materials with unstable solid electrolyte interphases in sodium-ion batteries.

  11. Tools for supercritical carbon dioxide cycle analysis and the cycle's applicability to sodium fast reactors

    E-Print Network [OSTI]

    Ludington, Alexander R. (Alexander Rockwell)

    2009-01-01T23:59:59.000Z

    The Sodium-Cooled Fast Reactor (SFR) and the Supercritical Carbon Dioxide (S-C0?) Recompression cycle are two technologies that have the potential to impact the power generation landscape of the future. In order for their ...

  12. Characterization of Electrode Materials for Lithium Ion and Sodium Ion Batteries using Synchrotron Radiation Techniques

    E-Print Network [OSTI]

    Doeff, Marca M.

    2013-01-01T23:59:59.000Z

    Rechargeable Sodium-Ion Batteries: Potential Alternatives toCurrent Lithium-Ion Batteries. Adv. Energy Mater. 2 (2012):J. , Rojo, T. Na-ion Batteries, Recent Advances and Present

  13. The Beta-Neutrino Correlation in Sodium-21 and Other Nuclei

    E-Print Network [OSTI]

    Vetter, Paul A.; Abo-Shaeer, Jamil; Freedman, Stuart J.; Maruyama, Reina

    2008-01-01T23:59:59.000Z

    RIA?INTproc?abetanu THE BETA-NEUTRINO CORRELATION IN SODIUM-electrons shaken off in beta decay. High detection ef?ciencyTOF template spectra for beta decays to 21 Ne + , are shown

  14. Application of the Technology Neutral Framework to Sodium-­Cooled Fast Reactors

    E-Print Network [OSTI]

    Johnson, Brian C.

    Sodium cooled fast reactors (SFRs) are considered as a novel example to exercise the Technology Neutral Framework (TNF) proposed in NUREG-1860. One reason for considering SFRs is that they have historically had a licensing ...

  15. Review of Chemical Processes for the Synthesis of Sodium Borohydride Millennium Cell Inc.

    E-Print Network [OSTI]

    Review of Chemical Processes for the Synthesis of Sodium Borohydride Millennium Cell Inc. Prepared........................................................................................... 6 Methane (or Natural Gas) as Reducing Agent remained the same since it became commercial in the 1950s and is based on synthetic pathways developed

  16. Ultracold molecules from ultracold atoms : interactions in sodium and lithium gas

    E-Print Network [OSTI]

    Christensen, Caleb A

    2011-01-01T23:59:59.000Z

    The thesis presents results from experiments in which ultracold Sodium-6 and Lithium-23 atomic gases were studied near a Feshbach resonance at high magnetic fields. The enhanced interactions between atoms in the presence ...

  17. An Evaluation of the Annular Fuel and Bottle-Shaped Fuel Concepts for Sodium Fast Reactors

    E-Print Network [OSTI]

    Memmott, Matthew

    Two innovative fuel concepts, the internally and externally cooled annular fuel and the bottle-shaped fuel, were investigated with the goal of increasing the power density and reduce the pressure drop in the sodium-cooled ...

  18. Application of the technology neutral framework to sodium cooled fast reactors

    E-Print Network [OSTI]

    Johnson, Brian C. (Brian Carl)

    2010-01-01T23:59:59.000Z

    Sodium cooled fast reactors (SFRs) are considered as a novel example to exercise the Technology Neutral Framework (TNF) proposed in NUREG- 1860. One reason for considering SFRs is that they have historically had a licensing ...

  19. Sodium sulfate heptahydrate: a synchrotron energy-dispersive diffraction study of an elusive metastable hydrated salt 

    E-Print Network [OSTI]

    Hamilton, Andrea; Hall, Christopher

    2008-01-01T23:59:59.000Z

    We describe an unusual application of synchrotron energy-dispersive diffraction with hard X-rays to obtain structural information on metastable sodium sulfate heptahydrate. This hydrate was often mentioned in nineteenth ...

  20. Metal corrosion in a supercritical carbon dioxide - liquid sodium power cycle.

    SciTech Connect (OSTI)

    Moore, Robert Charles; Conboy, Thomas M.

    2012-02-01T23:59:59.000Z

    A liquid sodium cooled fast reactor coupled to a supercritical carbon dioxide Brayton power cycle is a promising combination for the next generation nuclear power production process. For optimum efficiency, a microchannel heat exchanger, constructed by diffusion bonding, can be used for heat transfer from the liquid sodium reactor coolant to the supercritical carbon dioxide. In this work, we have reviewed the literature on corrosion of metals in liquid sodium and carbon dioxide. The main conclusions are (1) pure, dry CO{sub 2} is virtually inert but can be highly corrosive in the presence of even ppm concentrations of water, (2) carburization and decarburization are very significant mechanism for corrosion in liquid sodium especially at high temperature and the mechanism is not well understood, and (3) very little information could be located on corrosion of diffusion bonded metals. Significantly more research is needed in all of these areas.

  1. Thermal-hydraulic analysis of innovative fuel configurations for the sodium fast reactor

    E-Print Network [OSTI]

    Memmott, Matthew J

    2009-01-01T23:59:59.000Z

    The sodium fast reactor (SFR) is currently being reconsidered as an instrument for actinide management throughout the world, thanks in part to international programs such as the Generation-IV and especially the Global ...

  2. Development of an improved sodium exposure test cell experiment for characterization of AMTEC electrode performance 

    E-Print Network [OSTI]

    Fiebig, Bradley Nelson

    1999-01-01T23:59:59.000Z

    An investigation into sources of inconsistencies in sodium exposure test cell (SETC) measurements, used to characterize AMTEC electrode performance, was conducted. Development of modifications to the SETC setup and operation ...

  3. Population strategies to decrease sodium intake : a global cost-effectiveness analysis

    E-Print Network [OSTI]

    Webb, Michael William, S.M. Massachusetts Institute of Technology

    2013-01-01T23:59:59.000Z

    Excessive sodium consumption is both prevalent and very costly in many countries around the world. Recent research has found that more than 90% of the world's adult population live in countries with mean intakes exceeding ...

  4. Process Flow Chart for Immobilizing of Radioactive High Concentration Sodium Hydroxide Product from the Sodium Processing Facility at the BN-350 Nuclear power plant in Aktau, Kazakhstan

    SciTech Connect (OSTI)

    Burkitbayev, M.; Omarova, K.; Tolebayev, T. [Ai-Farabi Kazakh National University, Chemical Faculty, Republic of Kazakhstan (Kazakhstan); Galkin, A. [KATEP Ltd., Republic of Kazakhstan (Kazakhstan); Bachilova, N. [NIISTROMPROEKT Ltd., Republic of Kazakhstan (Kazakhstan); Blynskiy, A. [Nuclear Technology Safety Centre, Republic of Kazakhstan (Kazakhstan); Maev, V. [MAEK-Kazatomprom Ltd., Republic of Kazakhstan (Kazakhstan); Wells, D. [NUKEM Limited- a member of the Freyssinet Group, Winfrith Technology Centre, Dorchester, Dorset (United Kingdom); Herrick, A. [NUKEM Limited- a member of the Freyssinet Group, Caithness (United Kingdom); Michelbacher, J. [Idaho National Laboratory, Idaho Falls (United States)

    2008-07-01T23:59:59.000Z

    This paper describes the results of a joint research investigations carried out by the group of Kazakhstan, British and American specialists in development of a new material for immobilization of radioactive 35% sodium hydroxide solutions from the sodium coolant processing facility of the BN-350 nuclear power plant. The resulting solid matrix product, termed geo-cement stone, is capable of isolating long lived radionuclides from the environment. The physico-mechanical properties of geo-cement stone have been investigated and the flow chart for its production verified in a full scale experiments. (author)

  5. Transport parameter determination and modeling of sodium and strontium plumes at the Idaho National Engineering Laboratory

    E-Print Network [OSTI]

    Londergan, John Thomas

    1987-01-01T23:59:59.000Z

    TRANSPORT PARAMETER DETERMINATION AND MODELING OF SODIUM AND STRONTIUM PLUMES AT THE IDAHO NATIONAL ENGINEERING LABORATORY A Thesis by JOHN THOMAS LONDERGAN Submitted to the Graduate College of Texas A&M University in partial fulfillment... of the requirements for the degree of MASTER OF SCIENCE May 1987 Major Subject: Geophysics TRANSPORT PARAMETER DETERMINATION AND MODELING OF SODIUM AND STRONTIUM PLUMES AT THE IDAHO NATIONAL ENGINEERING LABORATORY A Thesis by JOHN THOMAS LONDERGAN Approved...

  6. Sodium and potassium levels in the serum of acutely irradiated and non-irradiated rats

    E-Print Network [OSTI]

    Shepherd, David Preston

    1967-01-01T23:59:59.000Z

    SODIUM AND POTASSIUM LEVELS IN THE SERUM OF ACUTELY IRRADIATED AND NON-IRRADIATED RATS A Thesis By DAVID PRESTON SHEPHERD Submitted to the Graduate College of the Texas ARM University in partial fulfillment of the requirements for the degree... of MASTER OF SCIENCE August 1967 Major Subject: Zoology SODIUM AND POTASSIUM LEVELS IN THE SERUM OF ACUTELY IRRADIATED AND NON-IRRADIATED RATS A Thesis By DAVID PRESTON SHEPHERD Approved as to style and content by: (Chairman of Committee) (Head...

  7. Penetration mechanism and distribution gradients of sodium tripolyphosphate in peeled and deveined shrimp

    E-Print Network [OSTI]

    Tenhet, Vickie Lynn

    1979-01-01T23:59:59.000Z

    PENETRATION MECHANISM AND DISTRIBUTION GRADIENTS OF SODIUM TRIPOLYPHOSPHATE IN PEELED AND DEVEINED SHRIMP A Thesis by VICKIE LYNN TENHET Submitted to the Graduate College of Texas ASM University in partial fulfillment of the requirement... for the degree of MASTER OF SCIENCE December 1979 Major Subject: Food Science and Technology PENETRATION MECHANISM AND DISTRIBUTION GRADIENTS OF SODIUM TRIPOLYPHOSPHATE IN PEELED AND DEVEINED SHRIMP A Thesis by VICKIE LYNN TENHET Approved as to style...

  8. The effect of sodium chloride in the irrigation water on the growth of selected ornamental plants 

    E-Print Network [OSTI]

    Apps, Gary Edward

    1976-01-01T23:59:59.000Z

    THE EFFECT OF SODIUM CHLORIDE IN THE IRRIGATION WATER ON THE GROWTH OF SELECTED ORNAMENTAL PLANTS A Thesis by GARY EDWARD APPS Submitted to the Graduate College of Texas A6M University in partial fulfillment of the requirement for the degree... of MASTER OF SCIENCE December 1976 Major Subject: Floriculture THE EFFECT OF SODIUM CHLORIDE IN THE IRRIGATION WATER ON THE GROWTH OF SELECTED ORNAMENTAL PLANTS A Thesis by GARY EDWARD APPS Approved as to style and content by: (Chairman of Committee...

  9. The tolerance of two varieties of cotton to relatively high levels of sodium and magnesium 

    E-Print Network [OSTI]

    Parekh, Manhar C

    1969-01-01T23:59:59.000Z

    THE TO'ERANCE OF TNO VARIETIES OF COTTON TO RELATIVELY HIGH LEVELS OF SODIUM AND MAGNESIUM A Tnesis by Msnhar C. Parekh Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirements for the degree...) (Nember) (Nemb ) August 1969 ABSTRACT The Tolerance of Two Varieties of Cotton to Relatively High Levels of Sodium and Magnesium. (August 1969) Masher C. Parekh, B. S. , Gujarat University, Directed by: Dr. H. E. Joham An experiment was conducted...

  10. Solar-thermal Water Splitting Using the Sodium Manganese Oxide Process & Preliminary H2A Analysis

    SciTech Connect (OSTI)

    Todd M. Francis, Paul R. Lichty, Christopher Perkins, Melinda Tucker, Peter B. Kreider, Hans H. Funke, Allan Lewandowski, and Alan W. Weimer

    2012-10-24T23:59:59.000Z

    There are three primary reactions in the sodium manganese oxide high temperature water splitting cycle. In the first reaction, Mn2O3 is decomposed to MnO at 1,500°C and 50 psig. This reaction occurs in a high temperature solar reactor and has a heat of reaction of 173,212 J/mol. Hydrogen is produced in the next step of this cycle. This step occurs at 700°C and 1 atm in the presence of sodium hydroxide. Finally, water is added in the hydrolysis step, which removes NaOH and regenerates the original reactant, Mn2O3. The high temperature solar�driven step for decomposing Mn2O3 to MnO can be carried out to high conversion without major complication in an inert environment. The second step to produce H2 in the presence of sodium hydroxide is also straightforward and can be completed. The third step, the low temperature step to recover the sodium hydroxide is the most difficult. The amount of energy required to essentially distill water to recover sodium hydroxide is prohibitive and too costly. Methods must be found for lower cost recovery. This report provides information on the use of ZnO as an additive to improve the recovery of sodium hydroxide.

  11. An evaluation of neutralization for processing sodium-bearing liquid waste

    SciTech Connect (OSTI)

    Chipman, N.A.; Engelgau, G.O.; Berreth, J.R.

    1989-01-01T23:59:59.000Z

    This report addresses an alternative concept for potentially managing the sodium-bearing liquid waste generated at the Idaho Chemical Processing Plant from the current method of calcining a blend of sodium waste and high-level liquid waste. The concept is based on removing the radioactive components from sodium-bearing waste by neutralization and grouting the resulting low-level waste for on-site near-surface disposal. Solidifying the sodium waste as a remote-handled transuranic waste is not considered to be practical because of excessive costs and inability to dispose of the waste in a timely fashion. Although neutralization can remove most radioactive components to provide feed for a solidified low-level waste, and can reduce liquid inventories four to nine years more rapidly than the current practice of blending sodium-bearing liquid waste with first-cycle raffinite, the alternative will require major new facilities and will generate large volumes of low-level waste. Additional facility and operating costs are estimated to be at least $500 million above the current practice of blending and calcining. On-site, low-level waste disposal may be technically difficult and conflict which national and state policies. Therefore, it is recommended that the current practice of calcining a blend of sodium-bearing liquid waste and high-level liquid waste be continued to minimize overall cost and process complexities. 17 refs., 4 figs., 16 tabs.

  12. Synthesis and single crystal structure refinement of the one-layer hydrate of sodium brittle mica

    SciTech Connect (OSTI)

    Kalo, Hussein; Milius, Wolfgang [Lehrstuhl fuer Anorganische Chemie I, University of Bayreuth, D-95440 Bayreuth (Germany)] [Lehrstuhl fuer Anorganische Chemie I, University of Bayreuth, D-95440 Bayreuth (Germany); Braeu, Michael [BASF Construction Chemicals GmbH, 83308 Trostberg (Germany)] [BASF Construction Chemicals GmbH, 83308 Trostberg (Germany); Breu, Josef, E-mail: Josef.Breu@uni-bayreuth.de [Lehrstuhl fuer Anorganische Chemie I, University of Bayreuth, D-95440 Bayreuth (Germany)] [Lehrstuhl fuer Anorganische Chemie I, University of Bayreuth, D-95440 Bayreuth (Germany)

    2013-02-15T23:59:59.000Z

    A sodium brittle mica with the ideal composition [Na{sub 4}]{sup inter}[Mg{sub 6}]{sup oct}[Si{sub 4}Al{sub 4}]{sup tet}O{sub 20}F{sub 4} was synthesized via melt synthesis in a gas tight crucible. This mica is unusual inasmuch as the known mica structure holds only room for two interlayer cations per unit cell and inasmuch as it readily hydrates despite the high layer charge while ordinary micas and brittle micas are non-swelling. The crystal structure of one-layer hydrate sodium brittle mica was determined and refined from single crystal X-ray data. Interlayer cations reside at the center of the distorted hexagonal cavities and are coordinated by the three inner basal oxygen atoms. The coordination of the interlayer cation is completed by three interlayer water molecules residing at the center of the interlayer region. The relative position of adjacent 2:1-layers thus is fixed by these octahedrally coordinated interlayer cations. Pseudo-symmetry leads to extensive twinning. In total five twin operations generate the same environment for the interlayer species and are energetically degenerate. - Graphical abstract: The sodium brittle mica has been successfully synthesized by melt synthesis and the crystal structure of the one-layer hydrate of sodium brittle mica was determined from single crystal X-ray diffraction data. Highlights: Black-Right-Pointing-Pointer Melt synthesis yielded coarse grained sodium brittle mica which showed little disorder. Black-Right-Pointing-Pointer Sodium brittle mica hydrated completely to the state of one-layer hydrate. Black-Right-Pointing-Pointer Structure of one-layer hydrate of sodium brittle mica could therefore be determined and refined. Black-Right-Pointing-Pointer Arrangement of upper and lower tetrahedral sheet encompassing interlayer cation were clarified.

  13. Sustained Recycle in Light Water and Sodium-Cooled Reactors

    SciTech Connect (OSTI)

    Steven J. Piet; Samuel E. Bays; Michael A. Pope; Gilles J. Youinou

    2010-11-01T23:59:59.000Z

    From a physics standpoint, it is feasible to sustain recycle of used fuel in either thermal or fast reactors. This paper examines multi-recycle potential performance by considering three recycling approaches and calculating several fuel cycle parameters, including heat, gamma, and neutron emission of fresh fuel; radiotoxicity of waste; and uranium utilization. The first recycle approach is homogeneous mixed oxide (MOX) fuel assemblies in a light water reactor (LWR). The transuranic portion of the MOX was varied among Pu, NpPu, NpPuAm, or all-TRU. (All-TRU means all isotopes through Cf-252.) The Pu case was allowed to go to 10% Pu in fresh fuel, but when the minor actinides were included, the transuranic enrichment was kept below 8% to satisfy the expected void reactivity constraint. The uranium portion of the MOX was enriched uranium. That enrichment was increased (to as much as 6.5%) to keep the fuel critical for a typical LWR irradiation. The second approach uses heterogeneous inert matrix fuel (IMF) assemblies in an LWR - a mix of IMF and traditional UOX pins. The uranium-free IMF fuel pins were Pu, NpPu, NpPuAm, or all-TRU. The UOX pins were limited to 4.95% U-235 enrichment. The number of IMF pins was set so that the amount of TRU in discharged fuel from recycle N (from both IMF and UOX pins) was made into the new IMF pins for recycle N+1. Up to 60 of the 264 pins in a fuel assembly were IMF. The assembly-average TRU content was 1-6%. The third approach uses fast reactor oxide fuel in a sodium-cooled fast reactor with transuranic conversion ratio of 0.50 and 1.00. The transuranic conversion ratio is the production of transuranics divided by destruction of transuranics. The FR at CR=0.50 is similar to the CR for the MOX case. The fast reactor cases had a transuranic content of 33-38%, higher than IMF or MOX.

  14. Caustic Recycling Pilot Unit to Separate Sodium from LLW at Hanford Site - 12279

    SciTech Connect (OSTI)

    Pendleton, Justin; Bhavaraju, Sai; Priday, George; Desai, Aditya; Duffey, Kean; Balagopal, Shekar [Ceramatec Inc., Salt Lake City, UT 84119 (United States)

    2012-07-01T23:59:59.000Z

    As part of the Department of Energy (DOE) sponsored Advanced Remediation Technologies initiative, a scheme was developed to combine Continuous Sludge Leaching (CSL), Near-Tank Cesium Removal (NTCR), and Caustic Recycling Unit (CRU) using Ceramatec technology, into a single system known as the Pilot Near-Tank Treatment System (PNTTS). The Cesium (Cs) decontaminated effluent from the NTCR process will be sent to the caustic recycle process for recovery of the caustic which will be reused in another cycle of caustic leaching in the CSL process. Such an integrated mobile technology demonstration will give DOE the option to insert this process for sodium management at various sites in Hanford, and will minimize the addition of further sodium into the waste tanks. This allows for recycling of the caustic used to remove aluminum during sludge washing as a pretreatment step in the vitrification of radioactive waste which will decrease the Low Level Waste (LLW) volume by as much as 39%. The CRU pilot process was designed to recycle sodium in the form of pure sodium hydroxide. The basis for the design of the 1/4 scale pilot caustic recycling unit was to demonstrate the efficient operation of a larger scale system to recycle caustic from the NTCR effluent stream from the Parsons process. The CRU was designed to process 0.28 liter/minute of NTCR effluent, and generate 10 M concentration of 'usable' sodium hydroxide. The proposed process operates at 40 deg. C to provide additional aluminum solubility and then recover the sodium hydroxide to the point where the aluminum is saturated at 40 deg. C. A system was developed to safely separate and vent the gases generated during operation of the CRU with the production of 10 M sodium hydroxide. Caustic was produced at a rate between 1.9 to 9.3 kg/hr. The CRU was located inside an ISO container to allow for moving of the unit close to tank locations to process the LLW stream. Actual tests were conducted with the NTCR effluent simulant from the Parsons process in the CRU. The modular CRU is easily scalable as a standalone system for caustic recycling, or for NTTS integration or for use as an In-Tank Treatment System to process sodium bearing waste to meet LLW processing needs at the Hanford site. The standalone pilot operation of the CRU to recycle sodium from NTCR effluent places the technology demonstration at TRL level 6. Multiple operations were performed with the CRU to process up to 500 gallons of the NTCR effluent and demonstrate an efficient separation of up to 70 % of the sodium without solids precipitation while producing 10 M caustic. Batch mode operation was conducted to study the effects of chemistry variation, establish the processing rate, and optimize the process operating conditions to recycle caustic from the NTCR effluent. The performance of the CRU was monitored by tracking the density parameter to control the concentration of caustic produced. Different levels of sodium were separated in tests from the effluent at a fixed operating current density and temperature. The voltage of the modules remained stable during the unit operation which demonstrated steady operation to separate sodium from the NTCR effluent. The sodium transfer current efficiency was measured in testing based on the concentration of caustic produced. Measurements showed a current efficiency of 99.8% for sodium transfer from the NTCR effluent to make sodium hydroxide. The sodium and hydroxide contents of the anolyte (NTCR feed) and catholyte (caustic product) were measured before and after each batch test. In two separate batch tests, samples were taken at different levels of sodium separation and analyzed to determine the stability of the NTCR effluent after sodium separation. The stability characteristics and changes in physical and chemical properties of the NTCR effluent chemistry after separation of sodium hydroxide as a function of storage time were evaluated. Parameters such as level of precipitated alumina, total alkalinity, analysis of Al, Na, K, Cs, Fe, OH, nitrate, nitrite, total dissolved and

  15. Hemodynamic characterization of chronic bile duct-ligated rats: effect of pentobarbital sodium

    SciTech Connect (OSTI)

    Lee, S.S.; Girod, C.; Braillon, A.; Hadengue, A.; Lebrec, D.

    1986-08-01T23:59:59.000Z

    Systemic and splanchnic hemodynamics of the chronic bile duct-ligated rat were characterized by radioactive microspheres. Conscious and pentobarbital sodium-anesthetized, bile duct-ligated and sham-operated rats had cardiac output and regional organ blood flows determined. The conscious bile duct-ligated rat compared with the sham-operated showed a hyperdynamic circulation with an increased cardiac output and portal tributary blood flow. Pentobarbital sodium anesthesia induced marked hemodynamic changes in both sham-operated and bile duct-ligated rats. The latter group was especially sensitive to its effects; thus, comparison of cardiac output and portal tributary blood flow between anesthetized bile duct-ligated and sham-operated rats showed no significant differences. The authors conclude that the rat with cirrhosis due to chronic bile duct ligation is an excellent model for hemodynamic investigations but should be studied in the conscious state, since pentobarbital sodium anesthesia eliminated the hyperdynamic circulation.

  16. Development and application of modeling tools for sodium fast reactor inspection

    SciTech Connect (OSTI)

    Le Bourdais, Florian; Marchand, Benoît; Baronian, Vahan [CEA LIST, Centre de Saclay F-91191 Gif-sur-Yvette (France)

    2014-02-18T23:59:59.000Z

    To support the development of in-service inspection methods for the Advanced Sodium Test Reactor for Industrial Demonstration (ASTRID) project led by the French Atomic Energy Commission (CEA), several tools that allow situations specific to Sodium cooled Fast Reactors (SFR) to be modeled have been implemented in the CIVA software and exploited. This paper details specific applications and results obtained. For instance, a new specular reflection model allows the calculation of complex echoes from scattering structures inside the reactor vessel. EMAT transducer simulation models have been implemented to develop new transducers for sodium visualization and imaging. Guided wave analysis tools have been developed to permit defect detection in the vessel shell. Application examples and comparisons with experimental data are presented.

  17. GIF sodium fast reactor project R and D on safety and operation

    SciTech Connect (OSTI)

    Vasile, A.; Sofu, T.; Jeong, H. Y.; Sakai, T. [CEA DEN Cadarache, DER, 13108 Saint-Paul-Lez-Durance (France)

    2012-07-01T23:59:59.000Z

    The 'Safety and Operation' project is started in 2009 within the framework of Generation-IV International Forum (GIF) Sodium Fast Reactor (SFR) research and development program. In the safety area, the project involves R and D activities on phenomenological model development and experimental programs, conceptual studies in support of the design of safety provisions, preliminary assessment of safety systems, framework and methods for analysis of safety architecture. In the operation area, the project involves R and D activities on fast reactors safety tests and analysis of reactor operations, feedback from decommissioning, in-service inspection technique development, under-sodium viewing and sodium chemistry. This paper presents a summary of such activities and the main achievements. (authors)

  18. Design and development of a high-temperature sodium compatibility testing facility

    SciTech Connect (OSTI)

    Hvasta, M. G.; Nolet, B. K.; Anderson, M. H. [Univ. of Wisconsin-Madison, 1500 Engineering Dr., Madison - ERB 841, WI 53705 (United States)

    2012-07-01T23:59:59.000Z

    The use of advanced alloys within sodium-cooled fast reactors (SFRs) has been identified as a means of increasing plant efficiency and reducing construction costs. In particular, alloys such as NF-616, NF-709 and HT-UPS are promising because they exhibit greater strength than traditional structural materials such as 316-SS. However, almost nothing is known about the sodium compatibility of these new alloys. Therefore, research taking place at the Univ. of Wisconsin-Madison is focused on studying the effects of sodium corrosion on these materials under prototypic SFR operating conditions (600 [ deg. C], V Na=10 [m/s], C 0{approx} 1 [wppm]). This paper focuses on the design and construction of the testing facility with an emphasis on moving magnet pumps (MMPs). Corrosion data from a preliminary 500 [hr] natural convection test will also be presented. (authors)

  19. Sodium arsenite impairs insulin secretion and transcription in pancreatic {beta}-cells

    SciTech Connect (OSTI)

    Diaz-Villasenor, Andrea [Department of Genomic Medicine and Environmental Toxicology, Instituto de Investigaciones Biomedicas, Universidad Nacional Autonoma de Mexico (Mexico); Sanchez-Soto, M. Carmen [Department of Biophysics, Instituto de Fisiologia Celular, Universidad Nacional Autonoma de Mexico, Ciudad Universitaria, A.P. 70-253 Coyoacan, Mexico D.F. 04510 (Mexico); Cebrian, Mariano E. [Section of Environmental Toxicology, CINVESTAV, IPN, Mexico City (Mexico); Ostrosky-Wegman, Patricia [Department of Genomic Medicine and Environmental Toxicology, Instituto de Investigaciones Biomedicas, Universidad Nacional Autonoma de Mexico (Mexico); Hiriart, Marcia [Department of Biophysics, Instituto de Fisiologia Celular, Universidad Nacional Autonoma de Mexico, Ciudad Universitaria, A.P. 70-253 Coyoacan, Mexico D.F. 04510 (Mexico)]. E-mail: mhiriart@ifc.unam.mx

    2006-07-01T23:59:59.000Z

    Human studies have shown that chronic inorganic arsenic (iAs) exposure is associated with a high prevalence and incidence of type 2 diabetes. However, the mechanism(s) underlying this effect are not well understood, and practically, there is no information available on the effects of arsenic on pancreatic {beta}-cells functions. Thus, since insulin secreted by the pancreas plays a crucial role in maintaining glucose homeostasis, our aim was to determine if sodium arsenite impairs insulin secretion and mRNA expression in single adult rat pancreatic {beta}-cells. Cells were treated with 0.5, 1, 2, 5 and 10 {mu}M sodium arsenite and incubated for 72 and 144 h. The highest dose tested (10 {mu}M) decreased {beta}-cell viability, by 33% and 83%, respectively. Insulin secretion and mRNA expression were evaluated in the presence of 1 and 5 {mu}M sodium arsenite. Basal insulin secretion, in 5.6 mM glucose, was not significantly affected by 1 or 5 {mu}M treatment for 72 h, but basal secretion was reduced when cells were exposed to 5 {mu}M sodium arsenite for 144 h. On the other hand, insulin secretion in response to 15.6 mM glucose decreased with sodium arsenite in a dose-dependent manner in such a way that cells were no longer able to distinguish between different glucose concentrations. We also showed a significant decrease in insulin mRNA expression of cells exposed to 5 {mu}M sodium arsenite during 72 h. Our data suggest that arsenic may contribute to the development of diabetes mellitus by impairing pancreatic {beta}-cell functions, particularly insulin synthesis and secretion.

  20. Method of making a current collector for a sodium/sulfur battery

    DOE Patents [OSTI]

    Tischer, R.P.; Winterbottom, W.L.; Wroblowa, H.S.

    1987-03-10T23:59:59.000Z

    This specification is directed to a method of making a current collector for a sodium/sulfur battery. The current collector so-made is electronically conductive and resistant to corrosive attack by sulfur/polysulfide melts. The method includes the step of forming the current collector for the sodium/sulfur battery from a composite material formed of aluminum filled with electronically conductive fibers selected from the group of fibers consisting essentially of graphite fibers having a diameter up to 10 microns and silicon carbide fibers having a diameter in a range of 500--1,000 angstroms. 2 figs.

  1. Sodium and oxygen in Nigerian coals: Possible effects on ash fouling

    SciTech Connect (OSTI)

    Ewa, I.O.B.; Elegbe, S.B.; Adetunji, J. [Ahmadu Bello Univ., Zaria (Nigeria)

    1996-09-01T23:59:59.000Z

    Ash fouling during heat transfers in coal power-plants has been known to be an engineering problem caused by high sodium levels of the feed-coals. Instrumental Neutron Activation Analysis (INAA) was used in determining the concentration of some alkali elements (Na, Ca, Mg) associated with ash fouling for eight Nigerian coals mined at Onyeama, Ogbete, Enugu, Gombe, Okaba, Afikpo, Lafia and Asaba. Sodium levels were generally low (0.001-0.036%). Oxygen concentrations considered as an indicative measure of the wettability of each of the coals were determined. The possible effects of the concentration of these elements on ash fouling were discussed. 8 refs., 3 tabs.

  2. Method of making a current collector for a sodium/sulfur battery

    DOE Patents [OSTI]

    Tischer, Ragnar P. (Birmingham, MI); Winterbottom, Walter L. (Farmington Hills, MI); Wroblowa, Halina S. (West Bloomfield, MI)

    1987-01-01T23:59:59.000Z

    This specification is directed to a method of making a current collector (14) for a sodium/sulfur battery (10). The current collector so-made is electronically conductive and resistant to corrosive attack by sulfur/polysulfide melts. The method includes the step of forming the current collector for the sodium/sulfur battery from a composite material (16) formed of aluminum filled with electronically conductive fibers selected from the group of fibers consisting essentially of graphite fibers having a diameter up to 10 microns and silicon carbide fibers having a diameter in a range of 500-1000 angstroms.

  3. Draft Environmental Impact Statement for the Treatment and Management of Sodium-Bonded Spent Nuclear Fuel

    SciTech Connect (OSTI)

    N /A

    1999-07-30T23:59:59.000Z

    This document summarizes the U.S. Department of Energy's ''Draft Environmental Impact Statement for the Treatment and Management of Sodium-Bonded Spent Nuclear Fuel''. In addition to information concerning the background, purpose and need for the proposed action, and the National Environmental Policy Act process, this summary describes the characteristics of sodium-bonded spent nuclear fuel, the proposed treatment methods, the proposed facilities, the alternatives considered, and the environmental consequences of these alternatives. A glossary is included at the end to assist the reader with some of the technical terms used in this document.

  4. L-sodium lactate in cooked beef top rounds: differing levels of incorporation and cookery 

    E-Print Network [OSTI]

    Evans, Lori Leigh

    1992-01-01T23:59:59.000Z

    L-SODIUM LACTATE IN COOKED BEEF TOP ROUNDS; DIFFERING LEVELS OF INCORPORATION AND COOKERY A Thesis by LORI LEIGH EVANS Submitted to the Office of Graduate Studies of Texas A8 M University in partial fulfillment of the requirements... for the degree of MASTER OF SCIENCE May 1992 Major Subject: Animal Science L-SODIUM LACTATE IN COOKED BEEF TOP ROUNDS; DIFFERING LEVELS OF INCORPORATION AND COOKERY A Thesis by LORI LEIGH EVANS Approved as to style and content by: R. K. Miller (Chair...

  5. Preliminary analysis of patent trends for sodium/sulfur battery technology

    SciTech Connect (OSTI)

    Triplett, M.B.; Winter, C.; Ashton, W.B.

    1985-07-01T23:59:59.000Z

    This document summarizes development trends in sodium/sulfur battery technology based on data from US patents. Purpose of the study was to use the activity, timing and ownership of 285 US patents to identify and describe broad patterns of change in sodium/sulfur battery technology. The analysis was conducted using newly developed statistical and computer graphic techniques for describing technology development trends from patent data. This analysis suggests that for some technologies trends in patent data provide useful information for public and private R and D planning.

  6. Simplified modeling of liquid sodium medium with temperature and velocity gradient using real thermal-hydraulic data. Application to ultrasonic thermometry in sodium fast reactor

    SciTech Connect (OSTI)

    Massacret, N.; Jeannot, J. P. [DEN/DTN/STPA/LIET, CEA Cadarache, Saint Paul Lez Durance (France); Moysan, J.; Ploix, M. A.; Corneloup, G. [Aix-Marseille Univ, LMA UPR 7051 CNRS, site LCND, 13625 Aix-en-Provence (France)

    2013-01-25T23:59:59.000Z

    In the framework of the French R and D program for the Generation IV reactors and specifically for the sodium cooled fast reactors (SFR), studies are carried out on innovative instrumentation methods in order to improve safety and to simplify the monitoring of fundamental physical parameters during reactor operation. The aim of the present work is to develop an acoustic thermometry method to follow up the sodium temperature at the outlet of subassemblies. The medium is a turbulent flow of liquid sodium at 550 Degree-Sign C with temperature inhomogeneities. To understand the effect of disturbance created by this medium, numerical simulations are proposed. A ray tracing code has been developed with Matlab Copyright-Sign in order to predict acoustic paths in this medium. This complex medium is accurately described by thermal-hydraulic data which are issued from a simulation of a real experiment in Japan. The analysis of these results allows understanding the effects of medium inhomogeneities on the further thermometric acoustic measurement.

  7. Tin Anode for Sodium-Ion Batteries Using Natural Wood Fiber as a Mechanical Buffer and Electrolyte Reservoir

    E-Print Network [OSTI]

    Li, Teng

    Tin Anode for Sodium-Ion Batteries Using Natural Wood Fiber as a Mechanical Buffer and Electrolyte Information ABSTRACT: Sodium (Na)-ion batteries offer an attractive option for low cost grid scale storage due to the abundance of Na. Tin (Sn) is touted as a high capacity anode for Na-ion batteries with a high theoretical

  8. Nature and distribution of iron sites in a sodium silicate glass investigated by neutron diffraction and EPSR simulation

    E-Print Network [OSTI]

    Boyer, Edmond

    1 Nature and distribution of iron sites in a sodium silicate glass investigated by neutron distributed in the silicate network and shares corner with silicate tetrahedra. The existence of a majority, such as the increase of the elastic modulus of sodium silicate glasses with increasing Fe-concentration. Our data

  9. F POWER MEASUREMENT FOR GENERATION IV SODIUM FAST R. COULON, S. NORMAND, M. MICHEL, L. BARBOT, T. DOMENECH,

    E-Print Network [OSTI]

    Boyer, Edmond

    .F-84500 Bollène, France. ABSTRACT The Phénix nuclear power plant has been a French Sodium Fast Reactor the research of power tagging agents. Then, simulation study has been done to evaluate measurability using high20 F POWER MEASUREMENT FOR GENERATION IV SODIUM FAST REACTORS R. COULON, S. NORMAND, M. MICHEL, L

  10. PHYSICAL REVIEW B 84, 054203 (2011) Electrical and thermal conductivity of liquid sodium from first-principles calculations

    E-Print Network [OSTI]

    Alfè, Dario

    2011-01-01T23:59:59.000Z

    and technological point of view. For example, it is used as coolant in fast-breeding nuclear reactors, and in heatPHYSICAL REVIEW B 84, 054203 (2011) Electrical and thermal conductivity of liquid sodium from first on the electrical and thermal conductivity of liquid sodium at 400 K, calculated using density functional theory

  11. Structure and hydrogen dynamics of pure and Ti-doped sodium alanate Jorge iguez,1,2

    E-Print Network [OSTI]

    Yildirim, Taner

    Structure and hydrogen dynamics of pure and Ti-doped sodium alanate Jorge Íñiguez,1,2 T. Yildirim,1, Honolulu, Hawaii 96822, USA (Received 2 June 2004; published 3 August 2004) We have studied the structure, energetics, and dynamics of pure and Ti-doped sodium alanate NaAlH4 , focusing on the possibility

  12. Simultaneous measurement of the surface temperature and the release of atomic sodium from a burning black liquor droplet

    SciTech Connect (OSTI)

    Saw, Woei L.; Nathan, Graham J. [Centre for Energy Technology, The University of Adelaide, SA 5006 (Australia); School of Mechanical Engineering, The University of Adelaide (Australia); Ashman, Peter J.; Alwahabi, Zeyad T. [Centre for Energy Technology, The University of Adelaide, SA 5006 (Australia); School of Chemical Engineering, The University of Adelaide (Australia); Hupa, Mikko [Process Chemistry Centre, Aabo Akademi, Biskopsgatan 8 FI-20500 Aabo (Finland)

    2010-04-15T23:59:59.000Z

    Simultaneous measurement of the concentration of released atomic sodium, swelling, surface and internal temperature of a burning black liquor droplet under a fuel lean and rich condition has been demonstrated. Two-dimensional two-colour optical pyrometry was employed to determine the distribution of surface temperature and swelling of a burning black liquor droplet while planar laser-induced fluorescence (PLIF) was used to assess the temporal release of atomic sodium. The key findings of these studies are: (i) the concentration of atomic sodium released during the drying and devolatilisation stages was found to be correlated with the external surface area; and (ii) the insignificant presence of atomic sodium during the char consumption stage shows that sodium release is suppressed by the lower temperature and by the high CO{sub 2} content in and around the particle. (author)

  13. Multipolar plasmon modes of sodium sphere: constrain on the minimal sphere radius

    E-Print Network [OSTI]

    Multipolar plasmon modes of sodium sphere: constrain on the minimal sphere radius Krystyna Kolwas-668 Warsaw, Poland ABSTRACT We re-examine the usual expectations for multipolar plasmon modes of a simple the complex eigenfrequencies of plasmon modes can be attributed to the sphere of size larger than the minimum

  14. Room-temperature stationary sodium-ion batteries for large-scale electric energy storage

    E-Print Network [OSTI]

    Wang, Wei Hua

    Room-temperature stationary sodium-ion batteries for large-scale electric energy storage Huilin Pan attention particularly in large- scale electric energy storage applications for renewable energy and smart storage system in the near future. Broader context With the rapid development of renewable energy sources

  15. Mechanism and kinetics of a sodium-driven bacterial flagellar motor

    E-Print Network [OSTI]

    Berry, Richard

    Mechanism and kinetics of a sodium-driven bacterial flagellar motor Chien-Jung Loa,b , Yoshiyuki potential difference. It consists of an 50-nm rotor and up to 10 independent stators anchored to the cell of electrical and chemical potential. All 25 torque­speed curves had the same concave-down shape as fully

  16. determines the number of sodium spikes fired per event by individual cells (Maruta

    E-Print Network [OSTI]

    Oertner, Thomas

    determines the number of sodium spikes fired per event by individual cells (Maruta et al., 2007; Mathy et al., 2009) and may thereby mediate the direction and speed of learning in Purkinje cells (Mathy, apparently even down to the level of electrical synapses of the infe- rior olive (Lefler et al., 2014; Mathy

  17. indirect study, coal was oxidatively de-graded with sodium dichromate and the

    E-Print Network [OSTI]

    Howat, Ian M.

    indirect study, coal was oxidatively de- graded with sodium dichromate and the esterified products- vestigators concluded (17, p. 380) that "thiophene derivatives must be indige- nous to coal." The direct XANES conmpounds yielded spectra that bore little resemblance to the coal spec- trum. For example, simulations

  18. Voltage, stability and diffusion barrier differences between sodium-ion and lithium-ion intercalation materials

    E-Print Network [OSTI]

    Ceder, Gerbrand

    Voltage, stability and diffusion barrier differences between sodium-ion and lithium-ion-ion systems. Introduction Rechargeable lithium-ion (Li-ion) batteries1­4 have become a mainstay of the digital), much research has targeted the development and optimization of lithium-ion batteries, in particular

  19. Behavioral/Systems/Cognitive Sodium and Calcium Current-Mediated Pacemaker Neurons

    E-Print Network [OSTI]

    Del Negro, Christopher A.

    Behavioral/Systems/Cognitive Sodium and Calcium Current-Mediated Pacemaker Neurons and Respiratory excitability, which is inconsistent with a pacemaker-essential mechanism of respiratory rhythmogenesis evaluate here in the mamma- lian respiratory network. The cellular mechanisms that underlie respiratory

  20. Effect of lasalocid sodium on rumen fermentation and digestion in sheep

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Effect of lasalocid sodium on rumen fermentation and digestion in sheep P. THIVEND, J.-P. JOUANY Laboratoire de la Digestion des Ruminants, 1. N. R. A., Theix, 63122 Ceyrat France. Summary. Four adult sheep had taken place in the rumen bacterial population (table 3). Overall digestive utilization of organic

  1. Hazard categorization and baseline documentation for the Sodium Storage Facility. Revision 1

    SciTech Connect (OSTI)

    Bowman, B.R.

    1995-06-16T23:59:59.000Z

    Hazard Categorization evaluation has been performed in accordance with DOE-STD-1027 for the Sodium Storage Facility at FFTF and a determination of less than Category 3 or non-nuclear has been made. Hazard Baseline Documentation has been performed in accordance with DOE-EM-STD-5502 and a determination of ``Radiological Facility`` has been made.

  2. Development of an improved sodium exposure test cell experiment for characterization of AMTEC electrode performance

    E-Print Network [OSTI]

    Fiebig, Bradley Nelson

    1999-01-01T23:59:59.000Z

    are attached to each electrode band and tltreaded through electricaHy insulated feedthroughs at the flange, Thermocouples are placed at the hot end of the chamber and in the sodium pool. Figure 4. 'rhe electrode test sample with connecting leads in an SETC...

  3. The sodium tail of the Moon M. Matta a,b,*, S. Smith a,1

    E-Print Network [OSTI]

    Mendillo, Michael

    The sodium tail of the Moon M. Matta a,b,*, S. Smith a,1 , J. Baumgardner a,1 , J. Wilson a,1 , C was discovered soon after the 1998 Leonid meteor shower (Smith et al., 1999). On 19 November 1998, an all

  4. Predictors and outcome impact of perioperative serum sodium changes in a high risk population

    E-Print Network [OSTI]

    Klinck, J.; McNeill, L.; Di Angelantonio, E.; Menon, D.

    2014-01-01T23:59:59.000Z

    1 Predictors and outcome impact of perioperative serum sodium changes in a high risk population J Klinck 1 L McNeill 1 E Di Angelantonio 2 D Menon 1 1 Division of Perioperative Care, Box 93, Addenbrooke’s Hospital, Hills...

  5. Atomic-Layer-Deposition Oxide Nanoglue for Sodium Ion Batteries Xiaogang Han,,

    E-Print Network [OSTI]

    Li, Teng

    Atomic-Layer-Deposition Oxide Nanoglue for Sodium Ion Batteries Xiaogang Han,, Yang Liu,, Zheng Jia ABSTRACT: Atomic-layer-deposition (ALD) coatings have been increasingly used to improve battery performance/discharging. Battery tests in coin-cells further showed the ALD-Al2O3 coating remarkably boosts the cycling performance

  6. Ice iron/sodium film as cause for high noctilucent cloud radar reflectivity

    E-Print Network [OSTI]

    Bellan, Paul M.

    Ice iron/sodium film as cause for high noctilucent cloud radar reflectivity P. M. Bellan1 Received] Noctilucent clouds, tiny cold electrically charged ice grains located at about 85 km altitude, exhibit by assuming the ice grains are coated by a thin metal film; substantial evidence exists indicating

  7. Chemistry of Petroleum Crude Oil Deposits: Sodium Naphthenates 2009 NHMFL Science Highlight for NSF

    E-Print Network [OSTI]

    Weston, Ken

    Chemistry of Petroleum Crude Oil Deposits: Sodium Naphthenates 2009 NHMFL Science Highlight for NSF DMR-Award 0654118 Ion Cyclotron Resonance User Program Solid deposits and emulsions from crude oil can that contain carbons, hydrogens, and two oxygen atoms. #12;A major problem in oil production, both

  8. Equilibrium diagrams at 27 [degree]C of the water + sodium tungstate + dodecylamine chloride system

    SciTech Connect (OSTI)

    Dantas Neto, A.A.; Castro Dantas, T.N. de; Duarte, M.M.L.; Avelino, S. (Univ. Federal do Rio Grande do Norte, Natal (Brazil). Programa de Pos-Graduacao em Engenharia Quimica)

    1993-01-01T23:59:59.000Z

    Amines are usually used in extracting tungsten from scheelite. Dodecylamine chloride in kerosene and octanol was used as an extracting agent in order to establish the phase diagram at 27C for water + sodium tungstate + dodecylamine chloride. Acetone was used to prevent emulsion formation. This procedure made it possible to achieve better partition coefficients; however, there appears to be a saturation region.

  9. Original article Increased late sodium current in myocytes from a canine heart failure

    E-Print Network [OSTI]

    Kamp, Tim

    Original article Increased late sodium current in myocytes from a canine heart failure model and from failing human heart Carmen R. Valdivia, William W. Chu, Jielin Pu 1 , Jason D. Foell, Robert A December 2004 Abstract Electrophysiological remodeling of ion channels in heart failure causes action

  10. Sodium shortage as a constraint on the carbon cycle in an inland tropical rainforest

    E-Print Network [OSTI]

    Kaspari, Mike

    Sodium shortage as a constraint on the carbon cycle in an inland tropical rainforest Michael- composition of pure cellulose by up to 50%, compared with stream water alone. These effects emerged after 134). We provide experimental evidence that Na shortage slows the carbon cycle. Because 80% of global

  11. ALZHEIMER'S AMYLOID-BETA PEPTIDE INHIBITS SODIUM/CALCIUM EXCHANGE MEASURED IN RAT AND

    E-Print Network [OSTI]

    ALZHEIMER'S AMYLOID-BETA PEPTIDE INHIBITS SODIUM/CALCIUM EXCHANGE MEASURED IN RAT AND HUMAN BRAIN-beta1­40 (A 1­40) and A 25­35 reduced vesicular Ca2+ content. Both peptides produced a maximal reduction in Ca2+ content of approximately 50%. The peptides reduced Ca2+ content with similar potency and half

  12. Review of FY 2001 Development Work for Vitrification of Sodium Bearing Waste

    SciTech Connect (OSTI)

    Taylor, Dean Dalton; Barnes, Charles Marshall

    2002-09-01T23:59:59.000Z

    Treatment of sodium-bearing waste (SBW) at the Idaho Nuclear Technology and Engineering Center (INTEC) within the Idaho National Engineering and Environmental Laboratory is mandated by the Settlement Agreement between the Department of Energy and the State of Idaho. This report discusses significant findings from vitrification technology development during 2001 and their impacts on the design basis for SBW vitrification.

  13. Effects of amounts and types of sodium bicarbonate in wheat flour tortillas

    E-Print Network [OSTI]

    Garza Casso, Jessica Beatriz

    2007-04-25T23:59:59.000Z

    with slower acting acids (van Wazer 1961). Fast acting acids are used as a leavener themselves (Le Baw 1982). 11 The chemical reactions of leavening acids that will be used in this study are as follows: 1) Sodium aluminum sulfate (SAS), NaAl (SO 4 ) 2...

  14. Effects of Sodium Chloride Particles, Ozone, UV, and Relative Humidity on Atmospheric Corrosion of Silver

    E-Print Network [OSTI]

    Effects of Sodium Chloride Particles, Ozone, UV, and Relative Humidity on Atmospheric Corrosion The corrosion of Ag contaminated with NaCl particles in gaseous environments containing humidity and ozone analyzed using a coulometric reduction technique. The atmospheric corrosion of Ag was greatly accelerated

  15. CARACTRISTIQUES SPECTROSCOPIQUES DES TTRABENZOYLACTONATES-SODIUM D'EUROPIUM ET DE TERBIUM

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    415 CARACTÉRISTIQUES SPECTROSCOPIQUES DES TÉTRABENZOYLACÉTONATES-SODIUM D'EUROPIUM ET DE TERBIUM des ions d'europium, terbium ou lanthane. On étudie les différentes transitions moléculaires et caractéristiques du chélate d'europium qui a donné l'effet laser. Abstract. 2014 A four-ligand rare-earth chelate

  16. Effect of Sodium Carboxymethyl Celluloses on Water-catalyzed Self-degradation of 200-degree C-heated Alkali-Activated Cement

    SciTech Connect (OSTI)

    Sugama T.; Pyatina, T.

    2012-05-01T23:59:59.000Z

    We investigated the usefulness of sodium carboxymethyl celluloses (CMC) in promoting self-degradation of 200°C-heated sodium silicate-activated slag/Class C fly ash cementitious material after contact with water. CMC emitted two major volatile compounds, CO2 and acetic acid, creating a porous structure in cement. CMC also reacted with NaOH from sodium silicate to form three water-insensitive solid reaction products, disodium glycolate salt, sodium glucosidic salt, and sodium bicarbonate. Other water-sensitive solid reaction products, such as sodium polysilicate and sodium carbonate, were derived from hydrolysates of sodium silicate. Dissolution of these products upon contact with water generated heat that promoted cement’s self-degradation. Thus, CMC of high molecular weight rendered two important features to the water-catalyzed self-degradation of heated cement: One was the high heat energy generated in exothermic reactions in cement; the other was the introduction of extensive porosity into cement.

  17. Conceptual Design of a MEDE Treatment System for Sodium Bonded Fuel

    SciTech Connect (OSTI)

    Carl E. Baily; Karen A. Moore; Collin J. Knight; Peter B. Wells; Paul J. Petersen; Ali S. Siahpush; Matthew T. Weseman

    2008-05-01T23:59:59.000Z

    Unirradiated sodium bonded metal fuel and casting scrap material containing highly enriched uranium (HEU) is stored at the Materials and Fuels Complex (MFC) on the Idaho National Laboratory (INL). This material, which includes intact fuel assemblies and elements from the Fast Flux Test Facility (FFTF) and Experimental Breeder Reactor-II (EBR-II) reactors as well as scrap material from the casting of these fuels, has no current use under the terminated reactor programs for both facilities. The Department of Energy (DOE), under the Sodium-Bonded Spent Nuclear Fuel Treatment Record of Decision (ROD), has determined that this material could be prepared and transferred to an off-site facility for processing and eventual fabrication of fuel for commercial nuclear reactors. A plan is being developed to prepare, package and transfer this material to the DOE High Enriched Uranium Disposition Program Office (HDPO), located at the Y-12 National Security Complex in Oak Ridge, Tennessee. Disposition of the sodium bonded material will require separating the elemental sodium from the metallic uranium fuel. A sodium distillation process known as MEDE (Melt-Drain-Evaporate), will be used for the separation process. The casting scrap material needs to be sorted to remove any foreign material or fines that are not acceptable to the HDPO program. Once all elements have been cut and loaded into baskets, they are then loaded into an evaporation chamber as the first step in the MEDE process. The chamber will be sealed and the pressure reduced to approximately 200 mtorr. The chamber will then be heated as high as 650 ºC, causing the sodium to melt and then vaporize. The vapor phase sodium will be driven into an outlet line where it is condensed and drained into a receiver vessel. Once the evaporation operation is complete, the system is de-energized and returned to atmospheric pressure. This paper describes the MEDE process as well as a general overview of the furnace systems, as necessary, to complete the MEDE process.

  18. Final Environmental Impact Statement for the Treatment and Management of Sodium-Bonded Spent Nuclear Fuel

    SciTech Connect (OSTI)

    N /A

    2000-08-04T23:59:59.000Z

    DOE is responsible for the safe and efficient management of its sodium-bonded spent nuclear fuel. This fuel contains metallic sodium, a highly reactive material; metallic uranium, which is also reactive; and in some cases, highly enriched uranium. The presence of reactive materials could complicate the process of qualifying and licensing DOE's sodium-bonded spent nuclear fuel inventory for disposal in a geologic repository. Currently, more than 98 percent of this inventory is located at the Idaho National Engineering and Environmental Laboratory (INEEL), near Idaho Falls, Idaho. In addition, in a 1995 agreement with the State of Idaho, DOE committed to remove all spent nuclear fuel from Idaho by 2035. This EIS evaluates the potential environmental impacts associated with the treatment and management of sodium-bonded spent nuclear fuel in one or more facilities located at Argonne National Laboratory-West (ANL-W) at INEEL and either the F-Canyon or Building 105-L at the Savannah River Site (SRS) near Aiken, South Carolina. DOE has identified and assessed six proposed action alternatives in this EIS. These are: (1) electrometallurgical treatment of all fuel at ANL-W, (2) direct disposal of blanket fuel in high-integrity cans with the sodium removed at ANL-W, (3) plutonium-uranium extraction (PUREX) processing of blanket fuel at SRS, (4) melt and dilute processing of blanket fuel at ANL-W, (5) melt and dilute processing of blanket fuel at SRS, and (6) melt and dilute processing of all fuel at ANL-W. In addition, Alternatives 2 through 5 include the electrometallurgical treatment of driver fuel at ANL-W. Under the No Action Alternative, the EIS evaluates both the continued storage of sodium-bonded spent nuclear fuel until the development of a new treatment technology or direct disposal without treatment. Under all of the alternatives, the affected environment is primarily within 80 kilometers (50 miles) of spent nuclear fuel treatment facilities. Analyses indicate little difference in the environmental impacts among alternatives. DOE has identified electrometallurgical treatment as its Preferred Alternative for the treatment and management of all sodium-bonded spent nuclear fuel, except for the Fermi-1 blanket fuel. The No Action Alternative is preferred for the Fermi-1 blanket spent nuclear fuel.

  19. Assimilation and respiration of radioactive ethylene glycol, in the presence of high sodium chloride concentrations, by a sodium chloride requiring bacterium

    E-Print Network [OSTI]

    Gonzalez, Carlos Francisco

    1972-01-01T23:59:59.000Z

    and the contents distilled over into 5 ml of a 2X boric acid solution containing 3 ml of a O. l%%d ethanolic solution of methyl red and 5. 7 ml of a 0. 1X ethanolic 29 solution of brom cresol green. The samples were titrated, with 0. 1N HC1 using a... limits. Sodium requirement Effect of pH on growth Utilization of carbon sources. Respiration studies. Quantitation of ethylene glycol carbon Disappearance of. glucose and ammonia-nitrogen from cultures of Bacterium T-52. Possible pathways...

  20. Liquid-Metal Electrode to Enable Ultra-Low Temperature Sodium-Beta Alumina Batteries for Renewable Energy Storage

    SciTech Connect (OSTI)

    Lu, Xiaochuan; Li, Guosheng; Kim, Jin Yong; Mei, Donghai; Lemmon, John P.; Sprenkle, Vincent L.; Liu, Jun

    2014-08-01T23:59:59.000Z

    Metal electrodes have a high capacity for energy storage but have found limited applications in batteries because of dendrite formation and other problems. In this paper, we report a new alloying strategy that can significantly reduce the melting temperature and improve wetting with the electrolyte to allow the use of liquid metal as anode in sodium-beta alumina batteries (NBBs) at much lower temperatures (e.g., 95 to 175°C). Commercial NBBs such as sodium-sulfur (Na-S) battery and sodium-metal halide (ZEBRA) batteries typically operate at relatively high temperatures (e.g., 300-350°C) due to poor wettability of sodium on the surface of ?"-Al2O3. Our combined experimental and computational studies suggest that Na-Cs alloy can replace pure sodium as the anode material, which provides a significant improvement in wettability, particularly at lower temperatures (i.e., <200°C). Single cells with the Na-Cs alloy anode exhibit excellent cycling life over those with pure sodium anode at 175 and 150°C. The cells can even operate at 95°C, which is below the melting temperature of pure sodium. These results demonstrate that NBB can be operated at ultra lower temperatures with successfully solving the wetting issue. This work also suggests a new strategy to use liquid metal as the electrode materials for advanced batteries that can avoid the intrinsic safety issues associated with dendrite formation on the anode.

  1. Induction of apoptotic death and retardation of neuronal differentiation of human neural stem cells by sodium arsenite treatment

    SciTech Connect (OSTI)

    Ivanov, Vladimir N., E-mail: vni3@columbia.edu [Center for Radiological Research, Department of Radiation Oncology, College of Physicians and Surgeons, Columbia University, 630 West 168th Street, NY 10032 (United States); Hei, Tom K. [Center for Radiological Research, Department of Radiation Oncology, College of Physicians and Surgeons, Columbia University, 630 West 168th Street, NY 10032 (United States)

    2013-04-01T23:59:59.000Z

    Chronic arsenic toxicity is a global health problem that affects more than 100 million people worldwide. Long-term health effects of inorganic sodium arsenite in drinking water may result in skin, lung and liver cancers and in severe neurological abnormalities. We investigated in the present study whether sodium arsenite affects signaling pathways that control cell survival, proliferation and neuronal differentiation of human neural stem cells (NSC). We demonstrated that the critical signaling pathway, which was suppressed by sodium arsenite in NSC, was the protective PI3K–AKT pathway. Sodium arsenite (2–4 ?M) also caused down-regulation of Nanog, one of the key transcription factors that control pluripotency and self-renewal of stem cells. Mitochondrial damage and cytochrome-c release induced by sodium arsenite exposure was followed by initiation of the mitochondrial apoptotic pathway in NSC. Beside caspase-9 and caspase-3 inhibitors, suppression of JNK activity decreased levels of arsenite-induced apoptosis in NSC. Neuronal differentiation of NSC was substantially inhibited by sodium arsenite exposure. Overactivation of JNK1 and ERK1/2 and down-regulation of PI3K–AKT activity induced by sodium arsenite were critical factors that strongly affected neuronal differentiation. In conclusion, sodium arsenite exposure of human NSC induces the mitochondrial apoptotic pathway, which is substantially accelerated due to the simultaneous suppression of PI3K–AKT. Sodium arsenite also negatively affects neuronal differentiation of NSC through overactivation of MEK–ERK and suppression of PI3K–AKT. - Highlights: ? Arsenite induces the mitochondrial apoptotic pathway in human neural stem cells. ? Arsenite-induced apoptosis is strongly upregulated by suppression of PI3K–AKT. ? Arsenite-induced apoptosis is strongly down-regulated by inhibition of JNK–cJun. ? Arsenite negatively affects neuronal differentiation by inhibition of PI3K–AKT.

  2. Development of a neutronics calculation method for designing commercial type Japanese sodium-cooled fast reactor

    SciTech Connect (OSTI)

    Takeda, T.; Shimazu, Y.; Hibi, K.; Fujimura, K. [Research Inst. of Nuclear Engineering, Univ. of Fukui, 1cho-me 2gaiku 4, Kanawa-cho, Tsuruga-shi, Fukui 914-0055 (Japan)

    2012-07-01T23:59:59.000Z

    Under the R and D project to improve the modeling accuracy for the design of fast breeder reactors the authors are developing a neutronics calculation method for designing a large commercial type sodium- cooled fast reactor. The calculation method is established by taking into account the special features of the reactor such as the use of annular fuel pellet, inner duct tube in large fuel assemblies, large core. The Verification and Validation, and Uncertainty Qualification (V and V and UQ) of the calculation method is being performed by using measured data from the prototype FBR Monju. The results of this project will be used in the design and analysis of the commercial type demonstration FBR, known as the Japanese Sodium fast Reactor (JSFR). (authors)

  3. Sodium/sulfur battery engineering for stationary energy storage. Final report

    SciTech Connect (OSTI)

    Koenig, A.; Rasmussen, J. [Silent Power, Inc., Salt Lake City, UT (United States)

    1996-04-01T23:59:59.000Z

    The use of modular systems to distribute power using batteries to store off-peak energy and a state of the art power inverter is envisioned to offer important national benefits. A 4-year, cost- shared contract was performed to design and develop a modular, 300kVA/300-kWh system for utility and customer applications. Called Nas-P{sub AC}, this system uses advanced sodium/sulfur batteries and requires only about 20% of the space of a lead-acid-based system with a smaller energy content. Ten, 300-VDC, 40-kWh sodium/sulfur battery packs are accommodated behind a power conversion system envelope with integrated digital control. The resulting design facilities transportation, site selection, and deployment because the system is quiet and non-polluting, and can be located in proximity to the load. This report contains a detailed description of the design and supporting hardware development performed under this contract.

  4. Idaho Nuclear Technology and Engineering Center (INTEC) Sodium Bearing Waste - Waste Incidental to Reprocessing Determination

    SciTech Connect (OSTI)

    Jacobson, Victor Levon

    2002-08-01T23:59:59.000Z

    U.S. Department of Energy Manual 435.1-1, Radioactive Waste Management, Section I.1.C, requires that all radioactive waste subject to Department of Energy Order 435.1 be managed as high-level radioactive waste, transuranic waste, or low-level radioactive waste. Determining the radiological classification of the sodium-bearing waste currently in the Idaho Nuclear Technology and Engineering Center Tank Farm Facility inventory is important to its proper treatment and disposition. This report presents the technical basis for making the determination that the sodium-bearing waste is waste incidental to spent fuel reprocessing and should be managed as mixed transuranic waste. This report focuses on the radiological characteristics of the sodiumbearing waste. The report does not address characterization of the nonradiological, hazardous constituents of the waste in accordance with Resource Conservation and Recovery Act requirements.

  5. Two dimensional, two fluid model for sodium boiling in LMFBR fuel assemblies

    SciTech Connect (OSTI)

    Granziera, M.R.; Kazimi, M.S.

    1980-05-01T23:59:59.000Z

    A two dimensional numerical model for the simulation of sodium boiling transient was developed using the two fluid set of conservation equations. A semiimplicit numerical differencing scheme capable of handling the problems associated with the ill-posedness implied by the complex characteristic roots of the two fluid problems was used, which took advantage of the dumping effect of the exchange terms. Of particular interest in the development of the model was the identification of the numerical problems caused by the strong disparity between the axial and radial dimensions of fuel assemblies. A solution to this problem was found which uses the particular geometry of fuel assemblies to accelerate the convergence of the iterative technique used in the model. Three sodium boiling experiments were simulated with the model, with good agreement between the experimental results and the model predictions.

  6. Boiling behavior of sodium-potassium alloy in a bench-scale solar receiver

    SciTech Connect (OSTI)

    Moreno, J.B.; Andraka, C.E.; Moss, T.A.

    1992-01-01T23:59:59.000Z

    During 1989-90, a 75-kW{sub t} sodium reflux pool-boiler solar receiver was successfully demonstrated at Sandia National Laboratories. Significant features of this receiver include (1) boiling sodium as the heat transfer medium and (2) electric-discharge-machined (EDM) cavities as artificial nucleation sites to stabilize boiling. Since this first demonstration, design of a second-generation pool-boiler receiver that will bring the concept closer to commercialization has begun. For long life, the new receiver uses Haynes Alloy 230. For increased safety factors against film boiling and flooding, it has a refined shape and somewhat larger dimensions. To eliminate the need for trace heating, the receiver will boil the sodium-potassium alloy NaK-78 instead of sodium. To reduce manufacturing costs, it will use one of a number of alternatives to EDM cavities for stabilization of boiling. To control incipient-boiling superheats, especially during hot restarts, it will contain a small amount of inert gas. Before the new receiver design could be finalized, bench-scale tests of some of the proposed changes were necessary. A series of bench-scale pool boilers were built from Haynes Alloy 230 and filled with NaK-78. Various boiling-stabilizer candidates were incorporated into them, including laser-drilled cavities and a number of different sintered-powder-metal coatings. These bench-scale pool boilers have been operated at temperatures up to 750{degree}C, heated by quartz lamps with incident radiant fluxes up to 95 W/cm{sup 2}. The effects of various orientations and added gases have been studied. results of these studies are presented. 15 refs.

  7. Effect of maillard reaction on the functional properties of sodium caseinate

    E-Print Network [OSTI]

    Chia, Chien-Chun Allan

    1974-01-01T23:59:59.000Z

    EPPECT OP NAILLARD REACTION OK THE PUHCTIONAL PROPERTIES OP SODIUN CASEIEATE A Thesis Chien-Chun Allan Chia Submitted to the Graduate College of the Texas AkN University in partial fulfillment of the requirement for the degree of NASTER OP... SCIENCE December 1974 Nagor Subject: Pood Technology EFFECT OF NAILLARD REACTION ON THE FCNCTIONAL PROPERTIES OF SODIUM CASEINATE A Thesis Chien-Chun Allan Chia Approved as to sty'1 and content by: (Chairman of Committee) (Head of De ment) (Nember...

  8. Influence of coherent Raman scattering on coherent population trapping in atomic sodium vapor

    SciTech Connect (OSTI)

    Wong, Vincent; Bennink, Ryan S.; Marino, Alberto M.; Boyd, Robert W.; Stroud, C.R. Jr.; Narducci, F.A. [Institute of Optics, University of Rochester, Rochester, New York 14627 (United States); EO Sensors Division, Naval Air Systems Command, Patuxent River, Maryland 20670 (United States)

    2004-11-01T23:59:59.000Z

    We study how coherent Stokes and anti-Stokes Raman scattering influence coherent population trapping. In an experiment using an atomic sodium vapor cell we observe induced transparency, induced absorption, and gain features, all of subnatural linewidth. The electromagnetically induced resonance is a peak or a dip depending on which side of the optical transition the fields are tuned to, and thus whether coherent anti-Stokes Raman scattering or coherent Stokes Raman scattering is the dominant process.

  9. Fuel-sodium reaction product and its influence on breached, mixed-oxide fuel pins

    SciTech Connect (OSTI)

    Strain, R.V.; Bottcher, J.H. (Argonne National Lab., IL (United States)); Ukai, S.; Arii, Y. (Power Reactor and Nuclear Fuels Development Corp., Ibaraki-ken (Japan))

    1992-01-01T23:59:59.000Z

    The formation and consequences of fuel-sodium reaction product (FSRP) have been studied in experiments irradiated in Experimental Breeder Reactor II as part of a joint program between the U.S. Department of Energy and the Power Reactor and Nuclear Fuel Development Corporation of Japan. This paper describes observations on the parameters that most influence the extent of the formation of FSRP and the effects it has on the performance of the fuel pin during continued operation.

  10. Growth and bone development in weanling quarter horses fed diets supplemented with sodium zeolite-A

    E-Print Network [OSTI]

    Frey, Kimberly Suzanne

    1991-01-01T23:59:59.000Z

    ) possibly due to SZA's high ion-exchange capabilities (Roland, 1985; Miles, 1986); however, natural zeolites have not been shown to improve egg shell quality especially in diets low in calcium (Nakaue and Koelliker, 1981). This could be due...GROWTH AND BONE DEVELOPMENT IN WEANLING QUARTER HORSES FED DIETS SUPPLEMENTED WITH SODIUM ZEOLITE-A A Thesis by KIMBERLY SUZANNE FREY Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment...

  11. Phase 2 THOR Steam Reforming Tests for Sodium Bearing Waste Treatment

    SciTech Connect (OSTI)

    Nicholas R. Soelberg

    2004-01-01T23:59:59.000Z

    About one million gallons of acidic, hazardous, and radioactive sodium-bearing waste is stored in stainless steel tanks at the Idaho Nuclear Technology and Engineering Center (INTEC), which is a major operating facility of the Idaho National Engineering and Environmental Laboratory. Steam reforming is a candidate technology being investigated for converting the waste into a road ready waste form that can be shipped to the Waste Isolation Pilot Plant in New Mexico for interment. A steam reforming technology patented by Studsvik, Inc., and licensed to THOR Treatment Technologies has been tested in two phases using a Department of Energy-owned fluidized bed test system located at the Science Applications International Corporation (SAIC) Science and Technology Applications Research Center located in Idaho Falls, Idaho. The Phase 1 tests were reported earlier in 2003. The Phase 2 tests are reported here. For Phase 2, the process feed rate, stoichiometry, and chemistry were varied to identify and demonstrate process operation and product characteristics under different operating conditions. Two test series were performed. During the first series, the process chemistry was designed to produce a sodium carbonate product. The second series was designed to produce a more leach-resistant, mineralized sodium aluminosilicate product. The tests also demonstrated the performance of a MACT-compliant off-gas system.

  12. Under-sodium viewing technology for improvement of fast-reactor safeguards

    SciTech Connect (OSTI)

    Beddingfield, David H [Los Alamos National Laboratory; Gerhart, Jeremy J [Los Alamos National Laboratory; Kawakubo, Yoko [JAEA

    2009-01-01T23:59:59.000Z

    The current safeguards approach for fast reactors relies exclusively on maintenance of continuity of knowledge to track the movement of fuel assemblies through these facilities. The remote handling of fuel assemblies, the visual opacity of the liquid metal coolant. and the chemical reactivity of sodium all combine and result in significant limitations on the available options to verify fuel assembly identification numbers or the integrity of these assemblies. These limitations also serve to frustrate attempts to restore the continuity-of-knowledge in instances where the information is under a variety of scenarios. The technology of ultrasonic under-sodium viewing offers new options to the safeguards community for recovering continuity-of-knowledge and applying more traditional item accountancy to fast reactor facilities. We have performed a literature review to investigate the development of under-sodium viewing technologies. In this paper we will summarize our findings and report the state of development of this technology and we will present possible applications to the fast reactor system to improve the existing safeguards approach at these reactors and in future fast reactors.

  13. Intermediate-scale tests of sodium interactions with calcite and dolomite aggregate concretes. [LMFBR

    SciTech Connect (OSTI)

    Randich, E.; Acton, R.U.

    1983-09-01T23:59:59.000Z

    Two intermediate-scale tests were performed to compare the behavior of calcite and dolomite aggregate concretes when attacked by molten sodium. The tests were performed as part of an interlaboratory comparison between Sandia National Laboratories and Hanford Engineering Development Laboratories. Results of the tests at Sandia National Laboratories are reported here. The results show that both concretes exhibit similar exothermic reactions with molten sodium. The large difference in reaction vigor suggested by thermodynamic considerations of CO/sub 2/ release from calcite and dolomite was not realized. Penetration rates of 1.4 to 1.7 mm/min were observed for short periods of time with reaction zone temperatures in excess of 800/sup 0/C during the energetic attack. The penetration was not uniform over the entire sodium-concrete contact area. Rapid attack may be localized due to inhomogeneities in the concrete. The chemical reaction zone is less then one cm thick for the calcite concrete but is about seven cm thick for the dolomite concrete.

  14. Development of models for the two-dimensional, two-fluid code for sodium boiling NATOF-2D

    E-Print Network [OSTI]

    Zielinski, R. G.

    1981-01-01T23:59:59.000Z

    Several features were incorporated into NATOF-2D, a twodimensional, two fluid code developed at M.I.T. for the purpose of analysis of sodium boiling transients under LMFBR conditions. They include improved interfacial mass, ...

  15. Sodium Cooled Fast Reactors and the Pyro-Process: Conversion of Nuclear Waste into a Fuel Source

    E-Print Network [OSTI]

    Belanger, David P.

    1 Sodium Cooled Fast Reactors and the Pyro-Process: Conversion of Nuclear Waste into a Fuel Source renewed interest amongst the nuclear science community as the debate over nuclear waste has increased .................................................................................27 2.1.2 Waste Minimization

  16. Integrated fuel performance and thermal-hydraulic sub-channel models for analysis of sodium fast reactors

    E-Print Network [OSTI]

    Fricano, Joseph William

    2012-01-01T23:59:59.000Z

    Sodium Fast Reactors (SFR) show promise as an effective way to produce clean safe nuclear power while properly managing the fuel cycle. Accurate computer modeling is an important step in the design and eventual licensing ...

  17. A four-equation two-phase flow model for sodium boiling simulation of LMFBR fuel assemblies

    E-Print Network [OSTI]

    Schor, Andrei L.

    1982-01-01T23:59:59.000Z

    A three-dimensional numerical model for the simulation of sodium boiling transients has been developed. The model uses mixture mass and energy equations, while employing a separate momentum equation for each phase. Thermal ...

  18. Palladium-Catalyzed Cross-Coupling of Aryl Chlorides and Triflates with Sodium Cyanate: A Practical Synthesis of Unsymmetrical Ureas

    E-Print Network [OSTI]

    Fors, Brett P.

    An efficient method for palladium-catalyzed cross-coupling of aryl chlorides and triflates with sodium cyanate is reported. The protocol allows for the synthesis of unsymmetrical N,N?-di- and N,N,N?-trisubstituted ureas ...

  19. Modelling of thermo-mechanical and irradiation behavior of metallic and oxide fuels for sodium fast reactors

    E-Print Network [OSTI]

    Karahan, Aydin

    2009-01-01T23:59:59.000Z

    A robust and reliable code to model the irradiation behavior of metal and oxide fuels in sodium cooled fast reactors is developed. Modeling capability was enhanced by adopting a non-empirical mechanistic approach to the ...

  20. The feasibility of meeting the World Health Organization guidelines for sodium and potassium: a cross-national comparison study

    E-Print Network [OSTI]

    Drewnowski, Adam; Rehm, Colin D.; Maillot, Matthieu; Mendoza, Alfonso; Monsivais, Pablo

    2015-01-01T23:59:59.000Z

    of less frequently consumed potassium-rich foods, including beans, dark-green vegetables, dried fruits and fish. While simultaneously decreasing sodium and increasing potassium should be the long-term goal for populations, independently increasing...

  1. Evaluation of frankfurters formulated with potassium lactate and sodium diacetate and innocualted with Listeria monocytogenes before and after irradiation treatment 

    E-Print Network [OSTI]

    Knight, Timothy David

    2006-08-16T23:59:59.000Z

    Microbial safety and quality attributes were evaluated for frankfurters formulated with potassium lactate/sodium diacetate (0 or 3%) and inoculated with a four-strain Listeria monocytogenes cocktail before and after treatment with pasteurizing doses...

  2. Evaluation of frankfurters formulated with potassium lactate and sodium diacetate and innocualted with Listeria monocytogenes before and after irradiation treatment

    E-Print Network [OSTI]

    Knight, Timothy David

    2006-08-16T23:59:59.000Z

    the incorporation of lactate in combination with dipping frankfurters in various antimicrobial solutions. Nunez and others (2004a) investigated the effectiveness of potassium lactate in a frankfurter formulation at 3.3% in combination with dipping... throughout refrigerated storage (Nunez and others 2004b). Barmpalia and others (2004) used a combination of 1.8% sodium lactate and 0.25% sodium diacetate in frankfurters with dip solutions of 2.5% lactic or acetic acids. All treatments with lactate...

  3. Thermochemical cyclic system for decomposing H/sub 2/O and/or CO/sub 2/ by means of cerium-titanium-sodium-oxygen compounds

    DOE Patents [OSTI]

    Bamberger, C.E.

    1980-04-24T23:59:59.000Z

    A thermochemical closed cyclic process for the decomposition of water and/or carbon dioxide to hydrogen and/or carbon monoxide begins with the reaction of ceric oxide (CeO/sub 2/), titanium dioxide (TiO/sub 2/) and sodium titanate (Na/sub 2/TiO/sub 3/) to form sodium cerous titanate (NaCeTi/sub 2/O/sub 6/) and oxygen. Sodium cerous titanate (NaCeTi/sub 2/O/sub 6/) reacted with sodium carbonate (Na/sub 2/CO/sub 3/) in the presence of steam, produces hydrogen. The same reaction, in the absence of steam, produces carbon monoxide. The products, ceric oxide and sodium titanate, obtained in either case, are treated with carbon dioxide and water to produce ceric oxide, titanium dioxide, sodium titanate, and sodium bicarbonate. After dissolving sodium bicarbonate from the mixture in water, the remaining insoluble compounds are used as starting materials for a subsequent cycle. The sodium bicarbonate can be converted to sodium carbonate by heating and returned to the cycle.

  4. Probing the Failure Mechanism of SnO2 Nanowires for Sodium-ion Batteries

    SciTech Connect (OSTI)

    Gu, Meng; Kushima, Akihiro; Shao, Yuyan; Zhang, Jiguang; Liu, Jun; Browning, Nigel D.; Li, Ju; Wang, Chong M.

    2013-09-30T23:59:59.000Z

    Non-lithium metals such as sodium have attracted wide attention as a potential charge carrying ion for rechargeable batteries, performing the same role as lithium in lithium- ion batteries. As sodium and lithium have the same +1 charge, it is assumed that what has been learnt about the operation of lithium ion batteries can be transferred directly to sodium batteries. Using in-situ TEM, in combination with DFT calculations, we probed the structural and chemical evolution of SnO2 nanowire anodes in Na-ion batteries and compared them quantitatively with results from Li-ion batteries [Science 330 (2010) 1515]. Upon Na insertion into SnO2, a displacement reaction occurs, leading to the formation of amorphous NaxSn nanoparticles covered by crystalline Na2O shell. With further Na insertion, the NaxSn core crystallized into Na15Sn4 (x=3.75). Upon extraction of Na (desodiation), the NaxSn core transforms to Sn nanoparticles. Associated with a volume shrinkage, nanopores appear and metallic Sn particles are confined in hollow shells of Na2O, mimicking a peapod structure. These pores greatly increase electrical impedance, therefore naturally accounting for the poor cyclability of SnO2. DFT calculations indicate that Na+ diffuses 30 times slower than Li+ in SnO2, in agreement with in-situ TEM measurement. Insertion of Na can chemo-mechanically soften the reaction product to greater extent than in lithiation. Therefore, in contrast to the lithiation of SnO2, no dislocation plasticity was seen ahead of the sodiation front. This direct comparison of the results from Na and Li highlights the critical role of ionic size and electronic structure of different ionic species on the charge/discharge rate and failure mechanisms in these batteries.

  5. Chemical bath deposition and characterization of electrochromic thin films of sodium vanadium bronzes

    SciTech Connect (OSTI)

    Najdoski, Metodija, E-mail: metonajd@yahoo.com [Institute of Chemistry, Faculty of Natural Sciences and Mathematics, Sts. Cyril and Methodius University, POB 162, Arhimedova 5, 1000 Skopje, Republic of Macedonia (Macedonia, The Former Yugoslav Republic of)] [Institute of Chemistry, Faculty of Natural Sciences and Mathematics, Sts. Cyril and Methodius University, POB 162, Arhimedova 5, 1000 Skopje, Republic of Macedonia (Macedonia, The Former Yugoslav Republic of); Koleva, Violeta [Institute of General and Inorganic Chemistry, Bulgarian Academy of Sciences, 1113 Sofia (Bulgaria)] [Institute of General and Inorganic Chemistry, Bulgarian Academy of Sciences, 1113 Sofia (Bulgaria); Demiri, Sani [Institute of Chemistry, Faculty of Natural Sciences and Mathematics, Sts. Cyril and Methodius University, POB 162, Arhimedova 5, 1000 Skopje, Republic of Macedonia (Macedonia, The Former Yugoslav Republic of)] [Institute of Chemistry, Faculty of Natural Sciences and Mathematics, Sts. Cyril and Methodius University, POB 162, Arhimedova 5, 1000 Skopje, Republic of Macedonia (Macedonia, The Former Yugoslav Republic of)

    2012-03-15T23:59:59.000Z

    Highlights: Black-Right-Pointing-Pointer We report a new chemical bath method for the deposition of vanadium bronze thin films. Black-Right-Pointing-Pointer The films are phase mixture of NaV{sub 6}O{sub 15} and Na{sub 1.1}V{sub 3}O{sub 7.9} with 10.58% lattice water. Black-Right-Pointing-Pointer The as-deposited vanadium bronze films exhibit two-step electrochromism. Black-Right-Pointing-Pointer They change their yellow-orange color to green and then from green to blue color. Black-Right-Pointing-Pointer The method allows the preparation of films on substrates with low melting point. -- Abstract: Thin yellow-orange films of sodium vanadium oxide bronzes have been prepared from a sodium-vanadium solution (1:1) at 75 Degree-Sign C and pH = 3. The composition, structure and morphology of the films have been studied by XRD, IR spectroscopy, TG and SEM-EDX analyses. It has been established that the prepared films are a phase mixture of hydrated NaV{sub 6}O{sub 15} (predominant component) and Na{sub 1.1}V{sub 3}O{sub 7.9} with total water content of 10.58%. The sodium vanadium bronze thin films exhibit two-step electrochromism followed by color change from yellow-orange to green, and then from green to blue. The cyclic voltammetry measurements on the as-deposited and annealed vanadium bronze films reveal the existence of different oxidation/reduction vanadium sites which make these films suitable for electrochromic devices. The annealing of the films at 400 Degree-Sign C changes the composition, optical and electrochemical properties.

  6. Feed Composition for Sodium-Bearing Waste Treatment Process, Rev. 3

    SciTech Connect (OSTI)

    Barnes, Charles Marshall

    2003-09-01T23:59:59.000Z

    Treatment of sodium-bearing waste (SBW) at the Idaho Nuclear Technology and Engineering Center (INTEC) within the Idaho National Engineering and Environmental Laboratory is mandated by a Settlement Agreement between the Department of Energy and the State of Idaho. One of the requirements of the Settlement Agreement is to complete treatment of SBW by December 31, 2012. To support both design and development studies for the SBW treatment process, detailed feed compositions are needed. This report contains the expected compositions of these feed streams and the sources and methods used in obtaining these compositions.

  7. Pre-Decisional Sodium Bearing Waste Technology Development Roadmap FY-01 Update

    SciTech Connect (OSTI)

    Mc Dannel, Gary Eidson

    2001-09-01T23:59:59.000Z

    This report provides an update to the Sodium Bearing Waste (SBW) Technology Development Roadmap generated a year ago. It outlines progress made to date and near-term plans for the technology development work necessary to support processing SBW. In addition, it serves as a transition document to the Risk Management Plan (RMP) required by the Project per DOE Order 413.3, “Program and Project Management for the Acquisition of Capital Assets.” Technical uncertainties have been identified as design basis elements (DBEs) and captured in a technical baseline database. As the risks are discovered, assessed, and mitigated, the status of the DBEs in the database will be updated and tracked to closure.

  8. Tracers for monitoring the activity of sodium/glucose cotransporters in health and disease

    DOE Patents [OSTI]

    Wright, Ernest M; Barrio, Jorge R; Hirayama, Bruce A; Kepe, Vladimir

    2014-09-30T23:59:59.000Z

    Radiolabeled tracers for sodium/glucose cotransporters (SGLTs), their synthesis, and their use are provided. The tracers are methyl or ethyl pyranosides having an equatorial hydroxyl group at carbon-2 and a C 1 preferred conformation, radiolabeled with .sup.18F, .sup.123I, or .sup.124I, or free hexoses radiolabeled with .sup.18F, .sup.123I, or .sup.124. Also provided are in vivo and in vitro techniques for using these and other tracers as analytical and diagnostic tools to study glucose transport, in health and disease, and to evaluate therapeutic interventions.

  9. Galvanic corrosion of structural aluminum coupled with mild steel in a dilute sodium dichromate electrolyte

    E-Print Network [OSTI]

    Ford, Robert Franklin

    1970-01-01T23:59:59.000Z

    -steel couple with a large cathode-to-anode area ratio in seawater were not available; however, a sacrificial anode cathodic protection system approx- imates this test and may be used for comparison. The coulomb capacity of an Alcoa CB-75 anode is 700 ampere... the forty-day test period: tap water solution ? 2. 37 ampere-hours sodium dicnroma e solution - 3. 88 ampere hours Du Pont solution ? 6. 47 ampere-hours seawater - 38 amr ere-hours distilled water ? . 05 ampere-hours The coulomb capacity...

  10. The substitution of sodium for calcium in the mineral nutrition of cotton

    E-Print Network [OSTI]

    Whitenberg, David Calvin

    1959-01-01T23:59:59.000Z

    the -Ca series, while sodium chloride was added at a concentration of ten millirqoles per liter to the +Na series. With the beginning of treatments, the water absorption of the plants was measured daily, and one complete replication was harvested... amount of water on the fifth and sixth days. At that time all of the other plants appeared to be in good condition. No water was absorbed by the -Ca -Na Stoneville plants after the sixth day, and by the ninth day they were permanently wilted. Wilting...

  11. Neutronic/Thermalhydraulic Coupling Technigues for Sodium Cooled Fast Reactor Simulations

    SciTech Connect (OSTI)

    Jean Ragusa; Andrew Siegel; Jean-Michel Ruggieri

    2010-09-28T23:59:59.000Z

    The objective of this project was to test new coupling algorithms and enable efficient and scalable multi-physics simulations of advanced nuclear reactors, with considerations regarding the implementation of such algorithms in massively parallel environments. Numerical tests were carried out to verify the proposed approach and the examples included some reactor transients. The project was directly related to the Sodium Fast Reactor program element of the Generation IV Nuclear Energy Systems Initiative and the Advanced Fuel cycle Initiative, and, supported the requirement of high-fidelity simulation as a mean of achieving the goals of the presidential Global Nuclear Energy Partnership (GNEP) vision.

  12. Effects of dietary potassium and sodium on magnesium and potassium balance in lambs 

    E-Print Network [OSTI]

    Poe, Julie Hamilton

    1984-01-01T23:59:59.000Z

    of magnesium oxide and trace mineralized salt with either molasses, cottonseed meal, dry sugarcane or steamed bone meal was consumed by lactating beef cows at a significantly (P), 05) higher level than magnesium oxide and trace mineralized salt (1:1) alone...EFFECTS OF DIETARY POTASSIUM AND SODIUM ON MAGNESIUM AND POTASSIUM BALANCE IN LAMBS A Thesis by JULIE HAMILTON POE Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER...

  13. Galvanic corrosion of structural aluminum coupled with mild steel in a dilute sodium dichromate electrolyte 

    E-Print Network [OSTI]

    Ford, Robert Franklin

    1970-01-01T23:59:59.000Z

    or the requirement for' the deqr, e of MASTER OF SCIl-NCI= Jaruary IgiO Major Sub ect: Civii I. ngineering GALVANIC CORROSION GF STRUCTURAI. ALUMINUM COUPLED WITH MILD STI:EL IN A DILUTE SODIUii DICIIROMA1'E ELECTROLTTE A Thesis ROBERT FRANKLIN FORD, JR.... Approved as to style and content by: + ~J Co-Chairman of Commii:t C Co-Chair n of Committe~e Member+ I Head of D=p rtm t) Januar; IDIO ABSTRACT Calvanic Corrosion of Structural Aluminum Coup'led with Mild Steel in a Dilute Sodium Dichromate...

  14. Fact Sheet: Sodium-Beta Batteries (October 2012) | Department of Energy

    Office of Environmental Management (EM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 1112011AT&T,OfficeEnd ofEvaluations in Covered Facilities |List ofSodium-Beta

  15. Fact Sheet: Sodium-ion Battery for Grid-level Applications (August 2013) |

    Office of Environmental Management (EM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 1112011AT&T,OfficeEnd ofEvaluations in Covered Facilities |List ofSodium-BetaDepartment of

  16. Thermal analysis for fuel handling system for sodium cooled reactor considering minor actinide-bearing metal fuel.

    SciTech Connect (OSTI)

    Chikazawa, Y.; Grandy, C.; Nuclear Engineering Division

    2009-03-01T23:59:59.000Z

    The Advanced Burner Reactor (ABR) is one of the components of the Global Nuclear Energy Partnership (GNEP) used to close the fuel cycle. ABR is a sodium-cooled fast reactor that is used to consume transuranic elements resulting from the reprocessing of light water reactor spent nuclear fuel. ABR-1000 [1000 MW(thermal)] is a fast reactor concept created at Argonne National Laboratory to be used as a reference concept for various future trade-offs. ABR-1000 meets the GNEP goals although it uses what is considered base sodium fast reactor technology for its systems and components. One of the considerations of any fast reactor plant concept is the ability to perform fuel-handling operations with new and spent fast reactor fuel. The transmutation fuel proposed as the ABR fuel has a very little experience base, and thus, this paper investigates a fuel-handling concept and potential issues of handling fast reactor fuel containing minor actinides. In this study, two thermal analyses supporting a conceptual design study on the ABR-1000 fuel-handling system were carried out. One analysis investigated passive dry spent fuel storage, and the other analysis investigated a fresh fuel shipping cask. Passive dry storage can be made suitable for the ABR-1000 spent fuel storage with sodium-bonded metal fuel. The thermal analysis shows that spent fast reactor fuel with a decay heat of 2 kW or less can be stored passively in a helium atmosphere. The 2-kW value seems to be a reasonable and practical level, and a combination of reasonably-sized in-sodium storage followed by passive dry storage could be a candidate for spent fuel storage for the next-generation sodium-cooled reactor with sodium-bonded metal fuel. Requirements for the shipping casks for minor actinide-bearing fuel with a high decay heat level are also discussed in this paper. The shipping cask for fresh sodium-cooled-reactor fuel should be a dry type to reduce the reaction between residual moisture on fresh fuel and the sodium coolant. The cladding temperature requirement is maintained below the creep temperature limit to avoid any damage before core installation. The thermal analysis shows that a helium gas-filled cask can accommodate ABR-1000 fresh minor actinide-bearing fuel with 700-W decay heat. The above analysis results revealed the overall requirement for minor actinide-bearing metal fuel handling. The information is thought to be helpful in the design of the ABR-1000 and future sodium-cooled-reactor fuel-handling system.

  17. Effect of Sodium on the Catalytic Properties of VOx/CeO2 Catalysts for Oxidative Dehydrogenation of Methanol

    SciTech Connect (OSTI)

    Li, Yan; Wei, Zhehao; Sun, Junming; Gao, Feng; Peden, Charles HF; Wang, Yong

    2013-03-21T23:59:59.000Z

    A series of VOx/CeO2 catalysts with various sodium loadings (Na/V ratio from 0 to 1) has been studied for oxidative dehydrogenation (ODH) of methanol. The effect of sodium on the surface structure, redox properties, and surface acidity/basicity of VOx/CeO2 was investigated using hydrogen temperature-programmed reduction (H2-TPR), Raman spectroscopy, and Diffuse Reflectance Infrared Fourier Transform spectroscopy (DRIFT). The experimental results indicate that the effect of sodium on VOx/CeO2 is highly dependent on the Na/V ratio. At a low Na/V ratio (Na/V<0.25), sodium addition only slightly decreases the redox properties of VOx/CeO2 and has little effect on its activity and selectivity to formaldehyde, even though the Brönsted acidity is almost completely eliminated at a Na/V ratio of 0.25. At a high Na/V ratio (Na/V>0.25), sodium addition greatly alters the nature of the active sites by V-O-Ce bond cleavage and V-O-Na bond formation, leading to significantly reduced activity of the VOx/CeO2 catalysts. At Na/V>0.25, the selectivity to formaldehyde also decreases with increasing Na/V ratio due to: (1) the suppressed reducibility of VOx, and (2) increased basicity leading to increased CO2.

  18. Experimental Development and Demonstration of Ultrasonic Measurement Diagnostics for Sodium Fast Reactor Thermal-hydraulics

    SciTech Connect (OSTI)

    Tokuhiro, Akira; Jones, Byron

    2013-09-13T23:59:59.000Z

    This research project will address some of the principal technology issues related to sodium-cooled fast reactors (SFR), primarily the development and demonstration of ultrasonic measurement diagnostics linked to effective thermal convective sensing under normatl and off-normal conditions. Sodium is well-suited as a heat transfer medium for the SFR. However, because it is chemically reactive and optically opaque, it presents engineering accessibility constraints relative to operations and maintenance (O&M) and in-service inspection (ISI) technologies that are currently used for light water reactors. Thus, there are limited sensing options for conducting thermohydraulic measurements under normal conditions and off-normal events (maintenance, unanticipated events). Acoustic methods, primarily ultrasonics, are a key measurement technology with applications in non-destructive testing, component imaging, thermometry, and velocimetry. THis project would have yielded a better quantitative and qualitative understanding of the thermohydraulic condition of solium under varied flow conditions. THe scope of work will evaluate and demonstrate ultrasonic technologies and define instrumentation options for the SFR.

  19. Testing of inductively coupled Eddy current position sensor of diverse safety rod in sodium

    SciTech Connect (OSTI)

    Vijayashree, R.; Veeraswamy, R.; Nashine, B. K.; Dash, S. K.; Sharma, P.; Rajan, K. K.; Vijayakumar, G.; Rao, C. B.; Sosamma, S.; Kalyanasundaram, P. [Indira Gandhi Centre for Atomic Research, Dept. of Atomic Energy, Kalpakkam - 603 102 (India)

    2011-07-01T23:59:59.000Z

    Prototype Fast Breeder Reactor (PFBR) is 500 MWe sodium cooled reactor under construction at Kalpakkam (India)). To improve the reliability of shutdown, Diverse Safety Rods (DSRs) are used in-addition to normal Control and Safety rods. During reactor operating condition, the DSR is parked above the active core and held in its top position by an electromagnet. In the event of a scram signal from the safety logic, the electromagnet holding the DSR is de-energised. Hence the DSR is released into the active core and at the end of travel DSR gets deposited in its bottom position. Because of the mechanical constraints, hard wired connectivity is not permitted from the DSR subassembly to the instrumentation outside the reactor. Hence an inductively coupled Eddy Current Position Sensor (ECPS) has been conceptualized to detect that the DSR has reached its bottom most position and to measure the drop time. Results of feasibility study on laboratory model have been reported earlier. Testing of a 1:1 scale engineering model of ECPS is reported in this paper. Results obtained from the high temperature sodium testing of ECPS indicate a clearly measurable change in pick up voltage with sensitivity of 11 % at 675 Hz. The ECPS is in advanced stage of implementation in DSRDM of PFBR. (authors)

  20. Enhancement of the inherent self-protection of the fast sodium reactor cores with oxide fuel

    SciTech Connect (OSTI)

    Eliseev, V.A.; Malisheva, I.V.; Matveev, V.I.; Egorov, A.V.; Maslov, P.A. [SSC RF - IPPE, Obninsk, Kaluga region (Russian Federation)

    2013-07-01T23:59:59.000Z

    With the development and research into the generation IV fast sodium reactors, great attention is paid to the enhancement of the core inherent self-protection characteristics. One of the problems dealt here is connected with the reduction of the reactivity margin so that the control rods running should not result in the core overheating and melting. In this paper we consider the possibilities of improving the core of BN-1200 with oxide fuel by a known method of introducing an axial fertile layer into the core. But unlike earlier studies this paper looks at the possibility of using such a layer not only for improving breeding, but also for reducing sodium void reactivity effect (SVRE). This proposed improvement of the BN-1200 core does not solve the problem of strong interference in control and protection system (CPS) rods of BN-1200, but they reduce significantly the reactivity margin for burn-up compensation. This helps compensate all the reactivity balances in the improved core configurations without violating constraints on SVRE value.

  1. Further Investigations of the Effect of Replacing Lithium by Sodium on Lithium Silicate Scintillating Glass Efficiency

    SciTech Connect (OSTI)

    Bliss, Mary; Aker, Pamela M.; Windisch, Charles F.

    2012-02-15T23:59:59.000Z

    Ce3+ doped lithium (6Li) silicate glasses are thermal neutron detectors. Prior work showed that when sodium (Na) is substituted for Li the scintillation efficiency, under beta particle stimulation, increased and then decreased as the sodium (Na) content was increased [1]. When all the 6Li was replaced by Na no scintillation was observed. Raman spectra, acquired using a visible excitation source provided no evidence of anomalous behavior. SEM microscopy did show some phase separation, but there was no obvious correlation with the scintillation efficiency. We have reexamined these glass samples using deep UV Raman excitation which reduces fluorescence interference. The newly acquired spectra show evidence of phase separation in the glasses. Specifically we see a peak at 800 cm-1 Raman shift which can be assigned to a vitreous silica moiety that results from phase separation. There is a strong correlation between this peak's area, the scintillation efficiency, and the Na content. The observed trend suggests that phase separation enhances scintillation and addition of Na reduces the amount of phase separation. We also see evidence of at least two defect structures that can be tentatively assigned to a three-membered ring structure and an oxygen vacancy. The latter is fairly strongly correlated with enhanced scintillation efficiency.

  2. Synthesis and radiosensitization properties of hydrogen peroxide and sodium hyaluronate complex

    SciTech Connect (OSTI)

    Rosli, Nur Ratasha Alia Md.; Mohamed, Faizal; Heng, Cheong Kai; Rahman, Irman Abdul; Ahmad, Ainee Fatimah; Mohamad, Hur Munawar Kabir [School of Applied Physics, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 UKM, Bangi, Selangor (Malaysia)

    2014-09-03T23:59:59.000Z

    Cancer cells which are large in size are resistant towards radiation therapy due to the presence of large amount of anti-oxidative enzymes and hypoxic cancer cells. Thus radiosensitizer agents have been developed to enhance the therapeutic effect of radiotherapy by increasing the sensitivity of these cancer cells towards radiation. This study is conducted to investigate the radiosensitization properties of radiosensitizer complex containing hydrogen peroxide and sodium hyaluronate. Combination with sodium hyaluronate may decrease reactivity of hydrogen peroxide but maintain the oxygen concentration needed for radiosensitizing effect. HepG2 cancer cells are cultured as the mean of test subject. Cancer cell samples which are targeted and not targeted with these radiosensitizers are irradiated with 2Gy single fractionated dose. Results obtained shows that the cancer cells which are not targeted with radiosensitizers has a cell viability of 98.80±0.37% after a time interval of 48 hours and has even repopulated over 100% after a 72 hour time interval. This shows that the cancer cells are resistant towards radiation. However, when the cancer cells are targeted with radiosensitizers prior to irradiation, there is a reduction of cell viability by 25.50±10.81% and 10.30±5.10% at time intervals of 48 and 72 hours respectively. This indicates that through the use of these radiosensitizers, cancer cells are more sensitive towards radiation.

  3. Neutronic Assessment of Transmutation Target Compositions in Heterogeneous Sodium Fast Reactor Geometries

    SciTech Connect (OSTI)

    Samuel E. Bays; Rodolfo M. Ferrer; Michael A. Pope; Benoit Forget; Mehdi Asgari

    2008-02-01T23:59:59.000Z

    The sodium fast reactor is under consideration for consuming the transuranic waste in the spent nuclear fuel generated by light water reactors. This work is concerned with specialized target assemblies for an oxide-fueled sodium fast reactor that are designed exclusively for burning the americium and higher mass actinide component of light water reactor spent nuclear fuel (SNF). The associated gamma and neutron radioactivity, as well as thermal heat, associated with decay of these actinides may significantly complicate fuel handling and fabrication of recycled fast reactor fuel. The objective of using targets is to isolate in a smaller number of assemblies these concentrations of higher actinides, thus reducing the volume of fuel having more rigorous handling requirements or a more complicated fabrication process. This is in contrast to homogeneous recycle where all recycled actinides are distributed among all fuel assemblies. Several heterogeneous core geometries were evaluated to determine the fewest target assemblies required to burn these actinides without violating a set of established fuel performance criteria. The DIF3D/REBUS code from Argonne National Laboratory was used to perform the core physics and accompanying fuel cycle calculations in support of this work. Using the REBUS code, each core design was evaluated at the equilibrium cycle condition.

  4. Selecting the suitable dopants: electronic structures of transition metal and rare earth doped thermoelectric sodium cobaltate

    E-Print Network [OSTI]

    Assadi, M H N; Yu, A B

    2012-01-01T23:59:59.000Z

    Engineered Na0.75CoO2 is considered a prime candidate to achieve high efficiency thermoelectric systems to regenerate electricity from waste heat. In this work, three elements with outmost electronic configurations, (1) an open d shell (Ni), (2) a closed d shell (Zn), and (3) an half fill f shell (Eu) with a maximum unpaired electrons, were selected to outline the dopants' effects on electronic and crystallographic structures of Na0.75CoO2. Systematic ab initio density functional calculations showed that the formation energy of these dopants was found to be lowest when residing on sodium layer and ranked as -1.1 eV, 0.44 eV and 3.44 eV for Eu, Ni and Zn respectively. Furthermore Ni was also found to be stable when substituting Co ion. As these results show great harmony with existing experimental data, they provide new insights into the fundamental principle of dopant selection for manipulating the physical properties in the development of high performance sodium cobaltate based thermoelectric materials.

  5. Calibration of the On-Line Aerosol Monitor (OLAM) with ammonium chloride and sodium chloride aerosols

    SciTech Connect (OSTI)

    Brockmann, J.E.; Lucero, D.A.; Romero, T. [Sandia National Labs., Albuquerque, NM (United States); Pentecost, G. [Idaho National Engineering Lab., Idaho Falls, ID (United States)

    1993-12-01T23:59:59.000Z

    The On-Line Aerosol Monitor (OLAM) is a light attenuation device designed and built at the Idaho National Engineering Laboratory (INEL) by EG&G Idaho. Its purpose is to provide an on-line indication of aerosol concentration in the PHEBUS-FP tests. It does this by measuring the attenuation of a light beam across a tube through which an aerosol is flowing. The OLAM does not inherently give an absolute response and must be calibrated. A calibration has been performed at Sandia National Laboratories` (SNL) Sandia Aerosol Research Laboratory (SARL) and the results are described here. Ammonium chloride and sodium chloride calibration aerosols are used for the calibration and the data for the sodium chloride aerosol is well described by a model presented in this report. Detectable instrument response is seen over a range of 0.1 cm{sup 3} of particulate material per m{sup 3} of gas to 10 cm{sup 3} of particulate material per m{sup 3} of gas.

  6. Final report-passive safety optimization in liquid sodium-cooled reactors.

    SciTech Connect (OSTI)

    Cahalana, J. E.; Hahn, D.; Nuclear Engineering Division; Korea Atomic Energy Research Inst.

    2007-08-13T23:59:59.000Z

    This report summarizes the results of a three-year collaboration between Argonne National Laboratory (ANL) and the Korea Atomic Energy Research Institute (KAERI) to identify and quantify the performance of innovative design features in metallic-fueled, sodium-cooled fast reactor designs. The objective of the work was to establish the reliability and safety margin enhancements provided by design innovations offering significant potential for construction, maintenance, and operating cost reductions. The project goal was accomplished with a combination of advanced model development (Task 1), analysis of innovative design and safety features (Tasks 2 and 3), and planning of key safety experiments (Task 4). Task 1--Computational Methods for Analysis of Passive Safety Design Features: An advanced three-dimensional subassembly thermal-hydraulic model was developed jointly and implemented in ANL and KAERI computer codes. The objective of the model development effort was to provide a high-accuracy capability to predict fuel, cladding, coolant, and structural temperatures in reactor fuel subassemblies, and thereby reduce the uncertainties associated with lower fidelity models previously used for safety and design analysis. The project included model formulation, implementation, and verification by application to available reactor tests performed at EBR-II. Task 2--Comparative Analysis and Evaluation of Innovative Design Features: Integrated safety assessments of innovative liquid metal reactor designs were performed to quantify the performance of inherent safety features. The objective of the analysis effort was to identify the potential safety margin enhancements possible in a sodium-cooled, metal-fueled reactor design by use of passive safety mechanisms to mitigate low-probability accident consequences. The project included baseline analyses using state-of-the-art computational models and advanced analyses using the new model developed in Task 1. Task 3--Safety Implications of Advanced Technology Power Conversion and Design Innovations and Simplifications: Investigations of supercritical CO{sub 2} gas turbine Brayton cycles coupled to the sodium-cooled reactors and innovative concepts for sodium-to-CO{sub 2} heat exchangers were performed to discover new designs for high efficiency electricity production. The objective of the analyses was to characterize the design and safety performance of equipment needed to implement the new power cycle. The project included considerations of heat transfer and power conversion systems arrangements and evaluations of systems performance. Task 4--Post Accident Heat Removal and In-Vessel Retention: Test plans were developed to evaluate (1) freezing and plugging of molten metallic fuel in subassembly geometry, (2) retention of metallic fuel core melt debris within reactor vessel structures, and (3) consequences of intermixing of high pressure CO{sub 2} and sodium. The objective of the test plan development was to provide planning for measurements of data needed to characterize the consequences of very low probability accident sequences unique to metallic fuel and CO{sub 2} Brayton power cycles. The project produced three test plans ready for execution.

  7. Supercritical Carbon Dioxide Brayton Cycle Energy Conversion for Sodium-Cooled Fast Reactors/Advanced Burner Reactors

    SciTech Connect (OSTI)

    Sienicki, James J.; Moisseytsev, Anton; Cho, Dae H.; Momozaki, Yoichi; Kilsdonk, Dennis J.; Haglund, Robert C.; Reed, Claude B.; Farmer, Mitchell T. [Argonne National Laboratory 9700 South Cass Avenue, Argonne, Illinois 60439 (United States)

    2007-07-01T23:59:59.000Z

    An optimized supercritical carbon dioxide (S-CO{sub 2}) Brayton cycle power converter has been developed for the 100 MWe (250 MWt) Advanced Burner Test Reactor (ABTR) eliminating the potential for sodium-water reactions and achieving a small power converter and turbine generator building. Cycle and plant efficiencies of 39.1 and 38.3 %, respectively, are calculated for the ABTR core outlet temperature of 510 deg. C. The ABTR S-CO{sub 2} Brayton cycle will incorporate Printed Circuit Heat Exchanger{sup TM} units in the Na-to-CO{sub 2} heat exchangers, high and low temperature recuperators, and cooler. A new sodium test facility is being completed to investigate the potential for transient plugging of narrow sodium channels typical of a Na-to-CO{sub 2} heat exchanger under postulated off-normal or accident conditions. (authors)

  8. Calcium-Mediated Regulation of Proton-Coupled Sodium Transport - Final Report

    SciTech Connect (OSTI)

    Schumaker, Karen S [Professor] [Professor

    2013-10-24T23:59:59.000Z

    The long-term goal of our experiments was to understand mechanisms that regulate energy coupling by ion currents in plants. Activities of living organisms require chemical, mechanical, osmotic or electrical work, the energy for which is supplied by metabolism. Adenosine triphosphate (ATP) has long been recognized as the universal energy currency, with metabolism supporting the synthesis of ATP and the hydrolysis of ATP being used for the subsequent work. However, ATP is not the only energy currency in living organisms. A second and very different energy currency links metabolism to work by the movement of ions passing from one side of a membrane to the other. These ion currents play a major role in energy capture and they support a range of physiological processes from the active transport of nutrients to the spatial control of growth and development. In Arabidopsis thaliana (Arabidopsis), the activity of a plasma membrane Na+/H+ exchanger, SALT OVERLY SENSITIVE1 (SOS1), is essential for regulation of sodium ion homeostasis during plant growth in saline conditions. Mutations in SOS1 result in severely reduced seedling growth in the presence of salt compared to the growth of wild type. SOS1 is a secondary active transporter coupling movement of sodium ions out of the cell using energy stored in the transplasma membrane proton gradient, thereby preventing the build-up of toxic levels of sodium in the cytosol. SOS1 is regulated by complexes containing the SOS2 and CALCINEURIN B-LIKE10 (CBL10) or SOS3 proteins. CBL10 and SOS3 (also identified as CBL4) encode EF-hand calcium sensors that interact physically with and activate SOS2, a serine/threonine protein kinase. The CBL10/SOS2 or SOS3/SOS2 complexes then activate SOS1 Na+/H+ exchange activity. We completed our studies to understand how SOS1 activity is regulated. Specifically, we asked: (1) how does CBL10 regulate SOS1 activity? (2) What role do two putative CBL10-interacting proteins play in SOS1 regulation? (3) Are there differences in the regulation and/or activity of SOS1 in plants differing in their adaptation to salinity?

  9. The effect of potassium lactate and sodium diacetate on the microbial, sensory, color and chemical characteristics of vacuum-packaged beef top loin steaks 

    E-Print Network [OSTI]

    Anwar, Najia

    2000-01-01T23:59:59.000Z

    Beef strip loins were injected with potassium lactate (1.5, 2.0, and 2.5%), sodium diacetate (0.1%), and combination of sodium diacetate (0.1%) with 1.5 or 2.0% potassium lactate. Top loin steaks were vacuum-packaged and stored for up to 49 days...

  10. Malignant hyperthermia-like reaction in a family with a sodium channel mutation at residue 1306

    SciTech Connect (OSTI)

    Vita, G.M.; Jedlicka, A.E.; Levitt, R.C. [Johns Hopkins Medical Institute, Baltimore, MD (United States)] [and others

    1994-09-01T23:59:59.000Z

    Malignant hyperthermia susceptibility (MHS) is an autosomal dominant, hypermetabolic disorder, triggered by potent inhalational anesthetics. We have previously suggeste the skeletal muscle sodium channel {alpha}-subunit (SCN4A) as a gene candidate to explain some forms of MHS. To evaluate this gene for mutations that might lead to a MHS-like episode, we amplified genomic DNA by PCR and used SSCP to screen each exon. We studied multiple MHS families which may be linked to this gene. The proband and a sibling from one of these families suspected of having MHS experienced trismus and body rigidity after induction of anesthesia. The caffiene and halothane contracture test proved diagnostic in these individuals and EMG studies suggested a form of myotomia. A mutation co-segregating with the myotonia/MHS phenotype was found in the region of exon 22.

  11. Energy savings with solid-state ballasted high-pressure sodium lamps

    SciTech Connect (OSTI)

    Verderber, R.R.; Morse, O.

    1981-04-01T23:59:59.000Z

    The performance of three types of solid-state ballasts used to operate high-pressure sodium lamps is discussed. Each type of solid-state ballast has been designed to operate an HPS lamp of a different wattage (150, 200, and 400 watts). The performance of these ballasts compared to standard core-coil ballasts operating the same HPS lamps shows that system efficiency improves as much as 17%. The solid-state ballasted HPS system also demonstrates excellent regulation with respect to input voltage and output power. These new ballasts can dim the HPS lamps and reduce flicker from more than 60% to less than 3%. Refitting street lighting with these new HPS systims provides an attractive return on initial capital investment.

  12. RELY: A reliability modeling system for analysis of sodium-sulfur battery configurations

    SciTech Connect (OSTI)

    Hostick, C.J.; Huber, H.D.; Doggett, W.H.; Dirks, J.A.; Dovey, J.F.; Grinde, R.B.; Littlefield, J.S.; Cuta, F.M.

    1987-06-01T23:59:59.000Z

    In support of the Office of Energy Storage and Distribution of the US Department of Energy (DOE), Pacific Northwest Laboratory has produced a microcomputer-based software package, called RELY, to assess the impact of sodium-sulfur cell reliability on constant current discharge battery performance. The Fortran-based software operates on IBM microcomputers and IBM-compatibles that have a minimum of 512K of internal memory. The software package has three models that provide the following: (1) a description of the failure distribution parameters used to model cell failure, (2) a Monte Carlo simulation of battery life, and (3) a detailed discharge model for a user-specified battery discharge cycle. 6 refs., 31 figs., 4 tabs.

  13. R and D program for core instrumentation improvements devoted for French sodium fast reactors

    SciTech Connect (OSTI)

    Jeannot, J. P.; Rodriguez, G.; Jammes, C.; Bernardin, B.; Portier, J. L.; Jadot, F. [Commissariat a l'Energie Atomique, Saint-Paul-lez-Durance, 13108 (France); Maire, S.; Verrier, D. [Advanced Projects and Decommissioning Div. Plant Sector AREVA NP - NEPL-FT, Lyon, 69000 (France); Loisy, F. [EDF - EDF R and D STEP Dept., 6 Quai Watier, Chatou, 78401 (France); Prele, G. [EDF, Generation/Nuclear Engineering, Basic Design Dept., Villeurbanne, 69628 (France)

    2011-07-01T23:59:59.000Z

    Under the framework of French R and D studies for Generation IV reactors and more specifically for sodium-cooled fast reactors (SFR); the CEA, EDF and AREVA have launched a joint coordinated research programme. This paper deals with the R and D sets out to achieve better inspection, maintenance, availability and decommissioning. In particular the instrumentation requirements for core monitoring and detection in the case of accidental events. Requirements mainly involve diversifying the means of protection and improving instrumentation performance in terms of responsiveness and sensitivity. Operation feedback from the Phenix and Superphenix prototype reactors and studies, carried out within the scope of the EFR projects, has been used to define the needs for instrumentation enhancement. (authors)

  14. Thermal Response of the Hybrid Loop-Pool Design for Sodium Cooled Faster Reactors

    SciTech Connect (OSTI)

    Zhang, Hongbin; Zhao, Haihua; Davis, Cliff

    2008-09-01T23:59:59.000Z

    An innovative hybrid loop-pool design for the sodium cooled fast reactor (SFR) has been recently proposed with the primary objective of achieving cost reduction and safety enhancement. With the hybrid loop-pool design, closed primary loops are immersed in a secondary buffer tank. This design takes advantage of features from conventional both pool and loop designs to further improve economics and safety. This paper will briefly introduce the hybrid loop-pool design concept and present the calculated thermal responses for unproctected (without reactor scram) loss of forced circulation (ULOF) transients using RELAP5-3D. The analyses examine both the inherent reactivity shutdown capability and decay heat removal performance by passive safety systems.

  15. Process Options Description for Vitrification Flowsheet Model of INEEL Sodium Bearing Waste

    SciTech Connect (OSTI)

    Nichols, Todd Travis; Taylor, Dean Dalton; Lauerhass, Lance; Barnes, Charles Marshall

    2001-02-01T23:59:59.000Z

    The purpose of this document is to provide the technical information to Savannah River Site (SRS) personnel that is required for the development of a basic steady-state process simulation of the vitrification treatment train of sodium bearing waste (SBW) at Idaho National Engineering and nvironmental Laboratory (INEEL). INEEL considers simulation to have an important role in the integration/optimization of treatment process trains for the High Level Waste (HLW) Program. This project involves a joint Technical Task Plan (TTP ID77WT31, Subtask C) between SRS and INEEL. The work scope of simulation is different at the two sites. This document addresses only the treatment of SBW at INEEL. The simulation model(s) is to be built by SRS for INEEL in FY-2001.

  16. Fuel-sodium reaction product formation in breached mixed-oxide fuel

    SciTech Connect (OSTI)

    Bottcher, J.H.; Lambert, J.D.B.; Strain, R.V.; Ukai, S.; Shibahara, S.

    1988-01-01T23:59:59.000Z

    The run-beyond-cladding-breach (RBCB) operation of mixed-oxide LMR fuel pins has been studied for six years in the Experimental Breeder Reactor-II (EBR-II) as part of a joint program between the US Department of Energy and the Power Reactor and Nuclear Fuel Development Corporation of Japan. The formation of fuel-sodium reaction product (FSRP), Na/sub 3/MO/sub 4/, where M = U/sub 1-y/Pu/sub y/, in the outer fuel regions is the major phenomenon governing RBCB behavior. It increases fuel volume, decreases fuel stoichiometry, modifies fission-product distributions, and alters thermal performance of a pin. This paper describes the morphology of Na/sub 3/MO/sub 4/ observed in 5.84-mm diameter pins covering a variety of conditions and RBCB times up to 150 EFPD's. 8 refs., 1 fig.

  17. Fiber-optic, anti-cycling, high pressure sodium street light control. Final technical progress report

    SciTech Connect (OSTI)

    NONE

    1995-05-01T23:59:59.000Z

    This is the Final Technical Progress Report on a project to develop and market a Fiber-Optic Anti-Cycling High Pressure Sodium Street Light Control. The field test units are now being made with a single vertical PC board design and contains a computer-on-a-chip or PROM IC to take the place of the majority of the components previously contained on the upper logic board. This will reduce the final costs of the unit when it is in production and increase the control`s flexibility. The authors have finished the soft tooling and have made the 400 plastic cases for the field test units. The new configuration of the cases entails a simplified design of the control shell which will have the lenses cast in place. The shell and base plastics are now finished and in final assembly awaiting the completion of the PC boards.

  18. Minor Actinide Recycle in Sodium Cooled Fast Reactors Using Heterogeneous Targets

    SciTech Connect (OSTI)

    Samuel Bays; Pavel Medvedev; Michael Pope; Rodolfo Ferrer; Benoit Forget; Mehdi Asgari

    2009-04-01T23:59:59.000Z

    This paper investigates the plausible design of transmutation target assemblies for minor actinides (MA) in Sodium Fast Reactors (SFR). A heterogeneous recycling strategy is investigated, whereby after each reactor pass, un-burned MAs from the targets are blended with MAs produced by the driver fuel and additional MAs from Spent Nuclear Fuel (SNF). A design iteration methodology was adopted for customizing the core design, target assembly design and matrix composition design. The overall design was constrained against allowable peak or maximum in-core performances. While respecting these criteria, the overall design was adjusted to reduce the total number of assemblies fabricated per refueling cycle. It was found that an inert metal-hydride MA-Zr-Hx target matrix gave the highest transmutation efficiency, thus allowing for the least number of targets to be fabricated per reactor cycle.

  19. Crystalline, liquid crystalline, and isotropic phases of sodium deoxycholate in water

    SciTech Connect (OSTI)

    Su, Ziyang; Luthra, Suman; Krzyzaniak, Joseph F.; Agra-Kooijman, Dena M.; Kumar, Satyendra; Byrn, Stephen R.; Shalaev, Evgenyi Y. (Pfizer); (Purdue); (Kent)

    2012-09-06T23:59:59.000Z

    Sodium deoxycholate (NaDC) is an important example of bile salts, representing systems with complex phase behavior involving both crystalline and mesophase structures. In this study, properties of NaDC-water mixtures were evaluated as a function of composition and temperature via X-ray diffraction with synchrotron (sXRD) and laboratory radiation sources, water sorption, polarized light, hot-stage microscopy, and freezing-point osmometry. Several phases were detected depending on the composition and temperature, including isotropic solution phase, liquid crystalline (LC) phase, crystalline hydrate, and ice. The LC phase was identified as hexagonal structure by sXRD, with up to 14 high-order reflections detected. The crystalline phase was found to be nonstoichiometric hydrate, based on XRD and water sorption data. The phase diagram of NaDC-water system has been refined based on both results of this study and other reports in literature.

  20. Effect of sodium monofluorophosphate treatment on microstructure and frost salt scaling durability of slag cement paste

    SciTech Connect (OSTI)

    Copuroglu, O. [Delft University of Technology, Faculty of CiTG, Micromechanics Laboratory (MICROLAB) (Netherlands)]. E-mail: o.copuroglu@citg.tudelft.nl; Fraaij, A.L.A. [Delft University of Technology, Faculty of CiTG, Materials Science and Sustainable Construction (Netherlands); Bijen, J.M.J.M. [Delft University of Technology, Faculty of CiTG, Materials Science and Sustainable Construction (Netherlands)

    2006-08-15T23:59:59.000Z

    Sodium-monofluorophosphate (Na-MFP) is currently in use as a surface applied corrosion inhibitor in the concrete industry. Its basic mechanism is to protect the passive layer of the reinforcement steel against disruption due to carbonation. Carbonation is known as the most detrimental environmental effect on blast furnace slag cement (BFSC) concrete with respect to frost salt scaling. In this paper the effect of Na-MFP on the microstructure and frost salt scaling resistance of carbonated BFSC paste is presented. The results of electron microscopy, mercury intrusion porosimetry (MIP) and X-ray diffraction (XRD) are discussed. It is found that the treatment modifies the microstructure and improves the resistance of carbonated BFSC paste against frost salt attack.

  1. Energetics of ion competition in the DEKA selectivity filter of neuronal sodium channels

    E-Print Network [OSTI]

    D. Boda; G. Leaf; J. Fonseca; B. Eisenberg

    2015-04-03T23:59:59.000Z

    The energetics of ionic selectivity in the neuronal sodium channels is studied. A simple model constructed for the selectivity filter of the channel is used. The selectivity filter of this channel type contains aspartate (D), glutamate (E), lysine (K), and alanine (A) residues (the DEKA locus). We use Grand Canonical Monte Carlo simulations to compute equilibrium binding selectivity in the selectivity filter and to obtain various terms of the excess chemical potential from a particle insertion procedure based on Widom's method. We show that K$^{+}$ ions in competition with Na$^{+}$ are efficiently excluded from the selectivity filter due to entropic hard sphere exclusion. The dielectric constant of protein has no effect on this selectivity. Ca$^{2+}$ ions, on the other hand, are excluded from the filter due to a free energetic penalty which is enhanced by the low dielectric constant of protein.

  2. Measurement of sodium-argon cluster ion recombination by coherent microwave scattering

    SciTech Connect (OSTI)

    Wu Yue; Sawyer, Jordan; Zhang Zhili [Mechanical, Aerospace and Biomedical Engineering, University of Tennessee, Knoxville Tennessee 37996 (United States); Shneider, Mikhail N. [Mechanical and Aerospace Engineering, Princeton University, Princeton, New Jersey 08544 (United States); Viggiano, Albert A. [Air Force Research Laboratory, Space Vehicles Directorate, Kirtland Air Force Base, New Mexico 87117 (United States)

    2012-03-12T23:59:59.000Z

    This present work demonstrates a non-intrusive measurement of the rate constant for sodium-argon cluster ions (Na{sup +}{center_dot}Ar) recombining with electrons. The measurements begin with resonance enhanced multi-photon ionization of the Na followed by coherent microwave scattering (radar) to monitor the plasma density. The Na{sup +}{center_dot}Ar adduct was formed in a three-body reaction. The plasma decay due to recombination reactions was monitored as a function of time and modeled to determine the rate constant. At 473 K, the rate constant is 1.8{sub -0.5}{sup +0.7}x10{sup -6}cm{sup 3}/s in an argon buffer at 100 Torr and initial Na number density of 5.5 x 10{sup 10} cm{sup -3}.

  3. Sensitivity Analysis of Reprocessing Cooling Times on Light Water Reactor and Sodium Fast Reactor Fuel Cycles

    SciTech Connect (OSTI)

    R. M. Ferrer; S. Bays; M. Pope

    2008-04-01T23:59:59.000Z

    The purpose of this study is to quantify the effects of variations of the Light Water Reactor (LWR) Spent Nuclear Fuel (SNF) and fast reactor reprocessing cooling time on a Sodium Fast Reactor (SFR) assuming a single-tier fuel cycle scenario. The results from this study show the effects of different cooling times on the SFR’s transuranic (TRU) conversion ratio (CR) and transuranic fuel enrichment. Also, the decay heat, gamma heat and neutron emission of the SFR’s fresh fuel charge were evaluated. A 1000 MWth commercial-scale SFR design was selected as the baseline in this study. Both metal and oxide CR=0.50 SFR designs are investigated.

  4. Near fifty percent sodium substituted lanthanum manganites—A potential magnetic refrigerant for room temperature applications

    SciTech Connect (OSTI)

    Sethulakshmi, N.; Anantharaman, M. R., E-mail: mraiyer@yahoo.com [Department of Physics, Cochin University of Science and Technology, Cochin 682022, Kerala (India); Al-Omari, I. A. [Department of Physics, Sultan Qaboos University, PC 123 Muscat, Sultanate of Oman (Oman); Suresh, K. G. [Department of Physics, Indian Institute of Technology Bombay, Powai, Mumbai 400076 (India)

    2014-03-03T23:59:59.000Z

    Nearly half of lanthanum sites in lanthanum manganites were substituted with monovalent ion-sodium and the compound possessed distorted orthorhombic structure. Ferromagnetic ordering at 300?K and the magnetic isotherms at different temperature ranges were analyzed for estimating magnetic entropy variation. Magnetic entropy change of 1.5?J·kg{sup ?1}·K{sup ?1} was observed near 300?K. An appreciable magnetocaloric effect was also observed for a wide range of temperatures near 300?K for small magnetic field variation. Heat capacity was measured for temperatures lower than 300?K and the adiabatic temperature change increases with increase in temperature with a maximum of 0.62?K at 280?K.

  5. The effect of sodium chloride on the dissolution of calcium silicate hydrate gels

    SciTech Connect (OSTI)

    Hill, J. [UK Nirex Limited, Curie Avenue, Harwell, Didcot Oxfordshire, OX11 0RH (United Kingdom)]. E-mail: joanne.hill@nirex.co.uk; Harris, A.W. [UK Nirex Limited, Curie Avenue, Harwell, Didcot Oxfordshire, OX11 0RH (United Kingdom); Manning, M. [Formerly AEA Technology, Building 220, Harwell, Didcot Oxfordshire, OX11 0RA (United Kingdom); Chambers, A. [Serco Assurance, Building 150, Harwell International Business Centre, Didcot, Oxfordshire, OX11 0RA (United Kingdom); Swanton, S.W. [Serco Assurance, Building 150, Harwell International Business Centre, Didcot, Oxfordshire, OX11 0RA (United Kingdom)

    2006-07-01T23:59:59.000Z

    The use of cement based materials will be widespread in the long-term management of radioactive materials in the United Kingdom. One of the applications could be the Nirex reference vault backfill (NRVB) as an engineered barrier within a deep geological repository. NRVB confers alkaline conditions, which would provide a robust chemical barrier through the control of the solubility of some key radionuclides, enhanced sorption and minimised corrosion of steel containers. An understanding of the dissolution of C-S-H gels in cement under the appropriate conditions (e.g., saline groundwaters) is necessary to demonstrate the expected evolution of the chemistry over time and to provide sufficient cement to buffer the porewater conditions for the required time. A programme of experimental work has been undertaken to investigate C-S-H gel dissolution behaviour in sodium chloride solutions and the effect of calcium/silicon ratio (C/S), temperature and cation type on this behaviour. Reductions in calcium concentration and pH values were observed with samples equilibrated at 45 deg. C compared to those prepared at 25 deg. C. The effect of salt cation type on salt-concentration dependence of the dissolution of C-S-H gels was investigated by the addition of lithium or potassium chloride in place of sodium chloride for gels with a C/S of 1.0 and 1.8. With a C/S of 1.0, similar increases in dissolved calcium concentration with increasing ionic strength were recorded for the different salts. However, at a C/S of 1.8, anomalously high calcium concentrations were observed in the presence of lithium.

  6. Sodium reflux pool-boiler solar receiver on-sun test results

    SciTech Connect (OSTI)

    Andraka, C E; Moreno, J B; Diver, R B; Moss, T A [Oak Ridge National Lab., TN (United States)] [Oak Ridge National Lab., TN (United States)

    1992-06-01T23:59:59.000Z

    The efficient operation of a Stirling engine requires the application of a high heat flux to the relatively small area occupied by the heater head tubes. Previous attempts to couple solar energy to Stirling engines generally involved directly illuminating the heater head tubes with concentrated sunlight. In this study, operation of a 75-kW{sub t} sodium reflux pool-boiler solar receiver has been demonstrated and its performance characterized on Sandia's nominal 75-kW{sub t} parabolic-dish concentrator, using a cold-water gas-gap calorimeter to simulate Stirling engine operation. The pool boiler (and more generally liquid-metal reflux receivers) supplies heat to the engine in the form of latent heat released from condensation of the metal vapor on the heater head tubes. The advantages of the pool boiler include uniform tube temperature, leading to longer life and higher temperature available to the engine, and decoupling of the design of the solar absorber from the engine heater head. The two-phase system allows high input thermal flux, reducing the receiver size and losses, therefore improving system efficiency. The receiver thermal efficiency was about 90% when operated at full power and 800{degree}C. Stable sodium boiling was promoted by the addition of 35 equally spaced artificial cavities in the wetted absorber surface. High incipient boiling superheats following cloud transients were suppressed passively by the addition of small amounts of xenon gas to the receiver volume. Stable boiling without excessive incipient boiling superheats was observed under all operating conditions. The receiver developed a leak during performance evaluation, terminating the testing after accumulating about 50 hours on sun. The receiver design is reported here along with test results including transient operations, steady-state performance evaluation, operation at various temperatures, infrared thermography, x-ray studies of the boiling behavior, and a postmortem analysis.

  7. Influence of misonidazole on the radiation response of murine tumors of different size: possible artifacts caused by pentobarbital sodium anesthesia

    SciTech Connect (OSTI)

    Wondergem, J.; Haveman, J.; van der Schueren, E.; van den Hoeven, H.; Breur, K.

    1981-06-01T23:59:59.000Z

    The radiosensitivity of a transplantable murine adenocarcinoma decreased with increasing tumor volume. In unanesthetized mice this phenomenon (based on the effect of the hypoxic cell sensitizer misonidazole), in the range of volumes studied, can largely be explained by the appearance of hypoxic cells in the tumor during growth. The use of pentobarbital sodium during irradiation is confiremd to be a disturbing factor, as it may increase the hypoxic cell fraction in the tumors. No evidence was found for a direct radiochemical protection because of pentobarbital sodium. The radioprotective effect of the anesthetic could only be demonstrated in conditions where there is already a fraction of hypoxic cells; no influence of the anesthesia was found in small tumors in which the fraction of hypoxic cells was relatively small. This may account for the previously conflicting data on the influence of pentobarbital sodium anesthesia. The vascularization of larger tumors is apparently inferior to smaller tumors and this has important repercussions in the case of anesthesia. Changes in blood flow induced by pentobarbital sodium in larger tumors cause an insufficient oxygenation and hence acute hypoxia.

  8. tude d'un changeur contre-courant gaz-gouttes de chlorure de sodium en cours de cristallisation

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    énergie électrique ou mécanique dans une turbine à gaz. Ceci nécessite que la température de sortie du gaz189 Étude d'un échangeur à contre-courant gaz-gouttes de chlorure de sodium en cours de'échangeur contre-courant entre un gaz et un sel fondu est présenté. L'énergie du gaz est directement convertie en

  9. Phosphatidylinositol 4-Phosphate 5-Kinase Reduces Cell Surface Expression of the Epithelial Sodium Channel (ENaC)

    E-Print Network [OSTI]

    Weisz, Ora A.

    Phosphatidylinositol 4-Phosphate 5-Kinase Reduces Cell Surface Expression of the Epithelial Sodium levels and reduced apical surface expression of ENaC in CCD cells, down-regulating amiloride- sensitive Channel (ENaC) in Cultured Collecting Duct Cells* Received for publication,May 14, 2007, and in revised

  10. Inhibition of Sodium/Proton Exchange by a Rab-GTPase-activating Protein Regulates Endosomal Traffic in Yeast*

    E-Print Network [OSTI]

    Rao, Rajini

    Inhibition of Sodium/Proton Exchange by a Rab-GTPase-activating Protein Regulates Endosomal Traffic- boxypeptidase Y to the cell surface. We conclude that Gyp6 is a negative regulator of Nhx1-dependent traffick and down- stream events in the PVC to Golgi pathway. Our findings provide a possible molecular link between

  11. Facilitated transport of sodium or potassium chloride across vesicle membranes using a ditopic salt-binding macrobicycle

    E-Print Network [OSTI]

    Smith, Bradley D.

    Facilitated transport of sodium or potassium chloride across vesicle membranes using a ditopic salt or potassium chloride as a contact ion-pair, is shown to effect- ively transport either salt across vesicle membranes. Sig- nificant transport is observed even when the transporter : phospholipid ratio is as low as 1

  12. Mercury Lamps Recycling Fluorescent light-tubes, compact fluorescent bulbs, mercury and sodium vapor lamps, ultraviolet and

    E-Print Network [OSTI]

    Baker, Chris I.

    Mercury Lamps Recycling Fluorescent light-tubes, compact fluorescent bulbs, mercury and sodium labeled for shipment to a recycling plant for mercury, glass and aluminum recovery. The beneficial re can be recycled infinitely without losing its purity or strength. While the primary end product

  13. Soil microbe Bacillus subtilis (GB03) induces biomass accumulation and salt tolerance with lower sodium accumulation in wheat

    E-Print Network [OSTI]

    Paré, Paul W.

    Soil microbe Bacillus subtilis (GB03) induces biomass accumulation and salt tolerance with lower sodium accumulation in wheat Jin-Lin ZhangA,B,E , Mina AzizB , Yan QiaoC , Qing-Qiang HanA , Jing Li to promote biomass accumulation and increase salt tolerance was investigated in wheat (Triticum aestivum

  14. Stable aqueous dispersions of graphitic nanoplatelets via the reduction of exfoliated graphite oxide in the presence of poly(sodium

    E-Print Network [OSTI]

    Stable aqueous dispersions of graphitic nanoplatelets via the reduction of exfoliated graphite be prepared via an exfoliation/in-situ reduction of graphite oxide in the presence of poly(sodium 4 prepare graphite nanoplatelets via the chemical reduction of exfoliated graphite oxide nanoplatelets

  15. Sodium iron hexacyanoferrate with high Na content as a Na-rich cathode material for Na-ion batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Guo, Ya [Brookhaven National Lab. (BNL), Upton, NY (United States); Yu, Xiqian [Brookhaven National Lab. (BNL), Upton, NY (United States); You, Ya [Chinese Academy of Sciences (CAS), Beijing (China). Inst. of Chemistry; Yin, Yaxia [Brookhaven National Lab. (BNL), Upton, NY (United States); Nam, Kyung -Wan [Brookhaven National Lab. (BNL), Upton, NY (United States)

    2015-01-01T23:59:59.000Z

    Owing to the worldwide abundance and low-cost of Na, room-temperature Na-ion batteries are emerging as attractive energy storage systems for large-scale grids. Increasing the Na content in cathode material is one of the effective ways to achieve high energy density. Prussian blue and its analogues (PBAs) are promising Na-rich cathode materials since they can theoretically store two Na ions per formula. However, increasing the Na content in PBAs cathode materials is a big challenge in the current. Here we show that sodium iron hexacyanoferrate with high Na content could be obtained by simply controlling the reducing agent and reaction atmosphere during synthesis. The Na content can reach as high as 1.63 per formula, which is the highest value for sodium iron hexacyanoferrate. This Na-rich sodium iron hexacyanoferrate demonstrates a high specific capacity of 150 mA h g-1 and remarkable cycling performance with 90% capacity retention after 200 cycles. Furthermore, the Na intercalation/de-intercalation mechanism is systematically studied by in situ Raman, X-ray diffraction and X-ray absorption spectroscopy analysis for the first time. The Na-rich sodium iron hexacyanoferrate could function as a plenteous Na reservoir and has great potential as a cathode material toward practical Na-ion batteries.

  16. Dynamics of cavitation bubble induced by 193 nm ArF excimer laser in concentrated sodium chloride solutions

    E-Print Network [OSTI]

    Palanker, Daniel

    of pulsed lasers for ablation, drilling, and cutting of soft tissues in liquid environments are accompaniedDynamics of cavitation bubble induced by 193 nm ArF excimer laser in concentrated sodium chloride solutions Igor Turovets and Daniel Palanker Laser Center, Hadassah University Hospital, P.O. Box 12000

  17. Physiological responses to training and racing in two year-old Quarter Horses fed Sodium Zeolite A

    E-Print Network [OSTI]

    Reynolds, Judith Amy Lundgren

    1993-01-01T23:59:59.000Z

    Fifty-three Quarter Horse yearlings were fed 0, .92, 1.86 or 2.80% Sodium Zeolite A (SZA) in the total diet. Beginning at approximately 18 mo of age, the horses were trained to ride, conditioned and run in nine match races--three races each at 274...

  18. Small angle neutron scattering study of deuterated sodium dodecylsulfate micellization in dilute poly((2edimethylamino)ethyl methacrylate) solutions

    E-Print Network [OSTI]

    Kofinas, Peter

    Small angle neutron scattering study of deuterated sodium dodecylsulfate micellization in dilute 2010 Keywords: Poly((2edimethylamino)ethyl methacrylate) Micelle Small angle neutron scattering a b angle neutron scattering. We found three transitions of the poly ((2edimethylamino)ethyl methacrylate

  19. Sodium iron hexacyanoferrate with high Na content as a Na-rich cathode material for Na-ion batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Guo, Ya; Yu, Xiqian; You, Ya; Yin, Yaxia; Nam, Kyung -Wan

    2015-01-01T23:59:59.000Z

    Owing to the worldwide abundance and low-cost of Na, room-temperature Na-ion batteries are emerging as attractive energy storage systems for large-scale grids. Increasing the Na content in cathode material is one of the effective ways to achieve high energy density. Prussian blue and its analogues (PBAs) are promising Na-rich cathode materials since they can theoretically store two Na ions per formula. However, increasing the Na content in PBAs cathode materials is a big challenge in the current. Here we show that sodium iron hexacyanoferrate with high Na content could be obtained by simply controlling the reducing agent and reaction atmospheremore »during synthesis. The Na content can reach as high as 1.63 per formula, which is the highest value for sodium iron hexacyanoferrate. This Na-rich sodium iron hexacyanoferrate demonstrates a high specific capacity of 150 mA h g-1 and remarkable cycling performance with 90% capacity retention after 200 cycles. Furthermore, the Na intercalation/de-intercalation mechanism is systematically studied by in situ Raman, X-ray diffraction and X-ray absorption spectroscopy analysis for the first time. The Na-rich sodium iron hexacyanoferrate could function as a plenteous Na reservoir and has great potential as a cathode material toward practical Na-ion batteries.« less

  20. Sodium dodecyl benzene sulfonate-assisted synthesis through a hydrothermal reaction

    SciTech Connect (OSTI)

    Sobhani, Azam [Department of Inorganic Chemistry, Faculty of Chemistry, University of Kashan, Kashan, P.O. Box 87317–51167, Islamic Republic of Iran (Iran, Islamic Republic of)] [Department of Inorganic Chemistry, Faculty of Chemistry, University of Kashan, Kashan, P.O. Box 87317–51167, Islamic Republic of Iran (Iran, Islamic Republic of); Salavati-Niasari, Masoud, E-mail: salavati@kashanu.ac.ir [Department of Inorganic Chemistry, Faculty of Chemistry, University of Kashan, Kashan, P.O. Box 87317–51167, Islamic Republic of Iran (Iran, Islamic Republic of) [Department of Inorganic Chemistry, Faculty of Chemistry, University of Kashan, Kashan, P.O. Box 87317–51167, Islamic Republic of Iran (Iran, Islamic Republic of); Institute of Nano Science and Nano Technology, University of Kashan, Kashan, P.O. Box 87317–51167, Islamic Republic of Iran (Iran, Islamic Republic of)

    2012-08-15T23:59:59.000Z

    Graphical abstract: Reaction of a SeCl{sub 4} aqueous solution with a NiCl{sub 2}·6H{sub 2}O aqueous solution in presence of sodium dodecyl benzene sulfonate (SDBS) as capping agent and hydrazine (N{sub 2}H{sub 4}·H{sub 2}O) as reductant, produces nanosized nickel selenide through a hydrothermal method. The effect of temperature, reaction time and amounts of reductant on the morphology, particle sizes of NiSe nanostructures has been investigated. Highlights: ? NiSe nanostructures were synthesized by hydrothermal method. ? A novel Se source was used to synthesize NiSe. ? SDBS as capping agent plays a crucial role on the morphology of products. ? A mixture of Ni{sub 3}Se{sub 2} and NiSe was prepared in the presence of 2 ml hydrazine. ? A pure phase of NiSe was prepared in the presence of 4 or 6 ml hydrazine. -- Abstract: The effects of the anionic surfactant on the morphology, size and crystallization of NiSe precipitated from NiCl{sub 2}·6H{sub 2}O and SeCl{sub 4} in presence of hydrazine (N{sub 2}H{sub 4}·H{sub 2}O) as reductant were investigated. The products have been successfully synthesized in presence of sodium dodecyl benzene sulfonate (SDBS) as surfactant via an improved hydrothermal route. A variety of synthesis parameters, such as reaction time and temperature, capping agent and amount of reducing agent have a significant effect on the particle size, phase purity and morphology of the obtained products. The sample size became bigger with decreasing reaction temperature and increasing reaction time. In the presence of 2 ml hydrazine, the samples were found to be the mixture of Ni{sub 3}Se{sub 2} and NiSe. With increasing the reaction time and amount of hydrazine a pure phase of hexagonal NiSe was obtained. X-ray diffraction analysis (XRD), scanning electron microscope (SEM) and transmission electron microscopy (TEM) images indicate phase, particle size and morphology of the products. Chemical composition and purity of the products were characterized by X-ray energy dispersive spectroscopy (EDS). Photoluminescence (PL) was used to study the optical properties of NiSe samples.

  1. americium silicides: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    circuits, CMOS, critical path, CV, dynamic CMOS circuit design, floating body effect (FBE), fully depleted, microprocessor, partially depleted, race, short channel Sung Bae...

  2. High-Performance Thermoelectric Devices Based on Abundant Silicide...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Development of high-performance thermoelectric devices for vehicle waste heat recovery will include fundamental research to use abundant promising low-cost thermoelectric...

  3. atomized uranium silicide: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    conditions on the atomic nucleus surface are discussed as well. R. Tsekov 2014-06-18 38 Depleted Uranium Technical Brief Environmental Sciences and Ecology Websites Summary: and...

  4. High-Performance Thermoelectric Devices Based on Abundant Silicide

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport(Fact Sheet), GeothermalGridHYDROGEND D e e p p a a r r tEnergyAmericaMaterials

  5. High-Performance Thermoelectric Devices Based on Abundant Silicide

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport(Fact Sheet), GeothermalGridHYDROGEND D e e p p a a r r

  6. Phase 2 TWR Steam Reforming Test for Sodium-Bearing Waste Treatment

    SciTech Connect (OSTI)

    Nicholas R. Soelberg; Doug Marshall; Dean Taylor; Steven Bates

    2004-01-01T23:59:59.000Z

    About one million gallons of acidic, hazardous, and radioactive sodium-bearing waste (SBW) is stored in stainless steel tanks a the Idaho Nuclear Technology and Engineering Center (INTEC), which is a major operating facility of the Idaho National Engineering and Environmental Laboratory (INEEL). Steam reforming is a candidate technology being investigated for converting the SBW into a road ready waste form that can be shipped to the Waste Isolation Pilot Plant in New Mexico for interment. Fluidized bed steam reforming technology, licensed to ThermoChem Waste Remediation, LLC (TWR) by Manufacturing Technology Conversion International, was tested in two phases using an INEEL (Department of Energy) fluidized bed test system located at the Science Applications International Corporation (SAIC) Science and Technology Applications Research Center in Idaho Falls, Idaho. The Phase 1 tests were reported earlier. The Phase 2 tests are reported here. For Phase 2, the process feed rate, reductant stoichiometry, and process temperature were varied to identify and demonstrate how the process might be optimized to improve operation and product characteristics. The first week of testing was devoted primarily to process chemistry and the second week was devoted more toward bed stability and particle size control.

  7. Deformation mechanisms during nanoindentation of sodium borosilicate glasses of nuclear interest

    SciTech Connect (OSTI)

    Kilymis, D. A.; Delaye, J.-M., E-mail: jean-marc.delaye@cea.fr [CEA Marcoule, DEN/DTCD, Service d’Etude et Comportement des Matériaux de Conditionnement, BP17171 30207 Bagnols-sur-Cèze Cedex (France)

    2014-07-07T23:59:59.000Z

    In this paper we analyze results of Molecular Dynamics simulations of Vickers nanoindentation, performed for sodium borosilicate glasses of interest in the nuclear industry. Three glasses have been studied in their pristine form, as well as a disordered one that is analogous to the real irradiated glass. We focused in the behavior of the glass during the nanoindentation in order to reveal the mechanisms of deformation and how they are affected by microstructural characteristics. Results have shown a strong dependence on the SiO{sub 2} content of the glass, which promotes densification due to the open structure of SiO{sub 4} tetrahedra and also due to the strength of Si-O bonds. Densification for the glasses is primarily expressed by the relative decrease of the Si-O-Si and Si-O-B angles, indicating rotation of the structural units and decrease of free volume. The increase of alkali content on the other hand results to higher plasticity of the matrix and increased shear flow. The most important effect on the deformation mechanism of the disordered glasses is that of the highly depolymerized network that will also induce shear flow and, in combination with the increased free volume, will result in the decreased hardness of these glasses, as has been previously observed.

  8. Saturated Sodium Chloride Solution under an External Static Electric Field: a Molecular Dynamics Study

    E-Print Network [OSTI]

    Gan Ren; Yanting Wang

    2015-05-02T23:59:59.000Z

    The behavior of saturated aqueous sodium chloride solutions under a constant external electric field (E) was studied by molecular dynamics (MD) simulation. Our dynamic MD simulations have indicated that the irreversible nucleation process towards crystallization is accelerated by a moderate E, but retarded or even prohibited under a stronger E, which can be understood by the competition between self-diffusion and drift motion. The former increases with E resulting in the acceleration of the nucleation process, and the latter tears oppositely charged ions more apart under a stronger E leading to the deceleration of nucleation. Moreover, our steady-state MD simulations have indicated that a first-order phase transition happens in saturated solutions only when the applied E is below a certain threshold Ec, and the ratio of crystallized ions does not change with the electric field. The magnitude of Ec increases with concentration, because larger clusters are easy to form in a more concentrated solution and require a stronger E to dissociate them.

  9. Development and Testing of an Americium/Lanthanide Separation Flowsheet Using Sodium Bismuthate

    SciTech Connect (OSTI)

    Jack Law; Bruce Mincher; Troy Garn; Mitchell Greenhalgh; Nicholas Schmitt; Veronica Rutledge

    2014-04-01T23:59:59.000Z

    The separation of Am from the lanthanides and curium is a key step in proposed advanced fuel cycle scenarios. The partitioning and transmutation of Am is desirable to minimize the long-term heat load of material interred in a future high-level waste repository. A separation process amenable to process scale-up remains elusive. Given only subtle chemistry differences within and between the ions of the trivalent actinide and lanthanide series this separation is challenging ; however, higher oxidation states of americium can be prepared using sodium bismuthate and separated via solvent extraction using diamylamylphosphonate (DAAP) extraction. Among the other trivalent metals only Ce is also oxidized and extracted. Due to the long-term instability of Am(VI) , the loaded organic phase is readily selectively stripped to partition the actinide to a new acidic aqueous phase. Batch extraction distribution ratio measurements were used to design a flowsheet to accomplish this separation. Additionally, crossflow filtration was investigated as a method to filter the bismuthate solids from the feed solution prior to extraction. Results of the filtration studies, flowsheet development work and flowsheet performance testing using a centrifugal contactor are detailed.

  10. Status of advanced fuel candidates for Sodium Fast Reactor within the Generation IV International Forum

    SciTech Connect (OSTI)

    F. Delage; J. Carmack; C. B. Lee; T. Mizuno; M. Pelletier; J. Somers

    2013-10-01T23:59:59.000Z

    The main challenge for fuels for future Sodium Fast Reactor systems is the development and qualification of a nuclear fuel sub-assembly which meets the Generation IV International Forum goals. The Advanced Fuel project investigates high burn-up minor actinide bearing fuels as well as claddings and wrappers to withstand high neutron doses and temperatures. The R&D outcome of national and collaborative programs has been collected and shared between the AF project members in order to review the capability of sub-assembly material and fuel candidates, to identify the issues and select the viable options. Based on historical experience and knowledge, both oxide and metal fuels emerge as primary options to meet the performance and the reliability goals of Generation IV SFR systems. There is a significant positive experience on carbide fuels but major issues remain to be overcome: strong in-pile swelling, atmosphere required for fabrication as well as Pu and Am losses. The irradiation performance database for nitride fuels is limited with longer term R&D activities still required. The promising core material candidates are Ferritic/Martensitic (F/M) and Oxide Dispersed Strengthened (ODS) steels.

  11. Comparative analysis of thorium and uranium fuel for transuranic recycle in a sodium cooled Fast Reactor

    SciTech Connect (OSTI)

    C. Fiorina; N. E. Stauff; F. Franceschini; M. T. Wenner; A. Stanculescu; T. K. Kim; A. Cammi; M. E. Ricotti; R. N. Hill; T. A. Taiwo; M. Salvatores

    2013-12-01T23:59:59.000Z

    The present paper compares the reactor physics and transmutation performance of sodium-cooled Fast Reactors (FRs) for TRansUranic (TRU) burning with thorium (Th) or uranium (U) as fertile materials. The 1000 MWt Toshiba-Westinghouse Advanced Recycling Reactor (ARR) conceptual core has been used as benchmark for the comparison. Both burner and breakeven configurations sustained or started with a TRU supply, and assuming full actinide homogeneous recycle strategy, have been developed. State-of-the-art core physics tools have been employed to establish fuel inventory and reactor physics performances for equilibrium and transition cycles. Results show that Th fosters large improvements in the reactivity coefficients associated with coolant expansion and voiding, which enhances safety margins and, for a burner design, can be traded for maximizing the TRU burning rate. A trade-off of Th compared to U is the significantly larger fuel inventory required to achieve a breakeven design, which entails additional blankets at the detriment of core compactness as well as fuel manufacturing and separation requirements. The gamma field generated by the progeny of U-232 in the U bred from Th challenges fuel handling and manufacturing, but in case of full recycle, the high contents of Am and Cm in the transmutation fuel impose remote fuel operations regardless of the presence of U-232.

  12. Conceptual design of a sodium sulfur cell for US electric-van batteries

    SciTech Connect (OSTI)

    Binden, P.J. [Beta Power, Inc., Wayne, PA (United States)

    1993-05-01T23:59:59.000Z

    A conceptual design of an advanced sodium/sulfur cell for US electric-van applications has been completed. The important design factors included specific physical and electrical requirements, service life, manufacturability, thermal management, and safety. The capacity of this cell is approximately the same as that for the ``PB`` cell being developed by Silent Power Limited (10 Ah). The new cell offers a 50% improvement in energy capacity and nearly a 100% improvement in peak power over the existing PB cells. A battery constructed with such cells would significantly exceed the USABC`s mid-term performance specifications. In addition, a similar cell and battery design effort was completed for an advanced passenger car application. A battery using the van cell would have nearly 3 times the energy compared to lead-acid batteries, yet weigh 40% less; a present-day battery using a cell specifically designed for this car would provide 50% more energy in a package 60% smaller and 50% lighter.

  13. A 100 MWe advanced sodium-cooled fast reactor core concept

    SciTech Connect (OSTI)

    Kim, T. K.; Grandy, C.; Hill, R. N. [Argonne National Laboratory, 9700 S. Cass Avenue, Argonne, IL 60439 (United States)

    2012-07-01T23:59:59.000Z

    An Advanced sodium-cooled Fast Reactor core concept (AFR-100) was developed targeting a small electrical grid to be transportable to the plant site and operable for a long time without frequent refueling. The reactor power rating was strategically decided to be 100 MWe, and the core barrel diameter was limited to 3.0 m for transportability. The design parameters were determined by relaxing the peak fast fluence limit and bulk coolant outlet temperature to beyond irradiation experience assuming that advanced cladding and structural materials developed under US-DOE programs would be available when the AFR-100 is deployed. With a de-rated power density and U-Zr binary metallic fuel, the AFR-100 can maintain criticality for 30 years without refueling. The average discharge burnup of 101 MWd/kg is comparable to conventional design values, but the peak discharge fast fluence of {approx}6x10{sup 23} neutrons/cm{sup 2} is beyond the current irradiation experiences with HT-9 cladding. The evaluated reactivity coefficients provide sufficient negative feedbacks and the reactivity control systems provide sufficient shutdown margins. The integral reactivity parameters obtained from quasi-static reactivity balance analysis indicate that the AFR-100 meets the sufficient conditions for acceptable asymptotic core outlet temperature following postulated unprotected accidents. Additionally, the AFR-100 has sufficient thermal margins by grouping the fuel assemblies into eight orifice zones. (authors)

  14. Sodium bromide electron-extraction layers for polymer bulk-heterojunction solar cells

    SciTech Connect (OSTI)

    Gao, Zhi; Qu, Bo, E-mail: bqu@pku.edu.cn; Xiao, Lixin; Chen, Zhijian [State Key Laboratory for Artificial Microstructures and Mesoscopic Physics, Department of Physics, Peking University, Beijing 100871 (China) [State Key Laboratory for Artificial Microstructures and Mesoscopic Physics, Department of Physics, Peking University, Beijing 100871 (China); New Display Device and System Integration Collaborative Innovation Center of the West Coast of the Taiwan Strait, Fuzhou 350002 (China); Zhang, Lipei [State Key Laboratory for Artificial Microstructures and Mesoscopic Physics, Department of Physics, Peking University, Beijing 100871 (China)] [State Key Laboratory for Artificial Microstructures and Mesoscopic Physics, Department of Physics, Peking University, Beijing 100871 (China); Gong, Qihuang [State Key Laboratory for Artificial Microstructures and Mesoscopic Physics, Department of Physics, Peking University, Beijing 100871 (China) [State Key Laboratory for Artificial Microstructures and Mesoscopic Physics, Department of Physics, Peking University, Beijing 100871 (China); Collaborative Innovation Center of Quantum Matter, Beijing 100871 (China)

    2014-03-10T23:59:59.000Z

    Inexpensive and non-toxic sodium bromide (NaBr) was introduced into polymer solar cells (PSCs) as the cathode buffer layer (CBL) and the electron extraction characteristics of the NaBr CBL were investigated in detail. The PSCs based on NaBr CBL with different thicknesses (i.e., 0?nm, 0.5?nm, 1?nm, and 1.5?nm) were prepared and studied. The optimal thickness of NaBr was 1?nm according to the photovoltaic data of PSCs. The open-circuit voltage (V{sub oc}), short-circuit current density (J{sub sc}), fill factor (FF), and power conversion efficiency (PCE) of the PSC with 1?nm NaBr were evaluated to be 0.58?V, 7.36?mA/cm{sup 2}, 0.63, and 2.70%, respectively, which were comparable to those of the reference device with the commonly used LiF. The optimized photovoltaic performance of PSC with 1?nm NaBr was ascribed to the improved electron transport and extraction capability of 1?nm NaBr in PSCs. In addition, the NaBr CBL could prevent the diffusion of oxygen and water vapor into the active layer and prolong the lifetime of the devices to some extent. Therefore, NaBr layer could be considered as a promising non-toxic CBL for PSCs in future.

  15. Process Options Description for Vitrification Flowsheet Model of INEEL Sodium Bearing Waste

    SciTech Connect (OSTI)

    Nichols, T.T.; Taylor, D.D.; Lauerhass, L.; Barnes, C.M.

    2002-02-21T23:59:59.000Z

    The technical information required for the development of a basic steady-state process simulation of the vitrification treatment train of sodium bearing waste (SBW) at Idaho National Engineering and Environmental Laboratory (INEEL) is presented. The objective of the modeling effort is to provide the predictive capability required to optimize an entire treatment train and assess system-wide impacts of local changes at individual unit operations, with the aim of reducing the schedule and cost of future process/facility design efforts. All the information required a priori for engineers to construct and link unit operation modules in a commercial software simulator to represent the alternative treatment trains is presented. The information is of a mid- to high-level nature and consists of the following: (1) a description of twenty-four specific unit operations--their operating conditions and constraints, primary species and key outputs, and the initial modeling approaches that will be used in the first year of the simulation's development; (2) three potential configurations of the unit operations (trains) and their interdependencies via stream connections; and (3) representative stream compositional makeups.

  16. Nanostructured bilayered vanadium oxide electrodes for rechargeable sodium-ion batteries.

    SciTech Connect (OSTI)

    Tepavcevic, S.; Xiong, H.; Stamenkovic, V.R.; Zuo, X.; Balasubramanian, M.; Prakapenka, V.B.; Johnson, C.S.; Rajh, T. (Accelerator Systems Division (APS)); ( CNM); ( MSD); (University of Chicago)

    2012-01-01T23:59:59.000Z

    Tailoring nanoarchitecture of materials offers unprecedented opportunities in utilization of their functional properties. Nanostructures of vanadium oxide, synthesized by electrochemical deposition, are studied as a cathode material for rechargeable Na-ion batteries. Ex situ and in situ synchrotron characterizations revealed the presence of an electrochemically responsive bilayered structure with adjustable intralayer spacing that accommodates intercalation of Na{sup +} ions. Sodium intake induces organization of overall structure with appearance of both long- and short-range order, while deintercalation is accompanied with the loss of long-range order, whereas short-range order is preserved. Nanostructured electrodes achieve theoretical reversible capacity for Na{sub 2}V{sub 2}O{sub 5} stoichiometry of 250 mAh/g. The stability evaluation during charge-discharge cycles at room temperature revealed an efficient 3 V cathode material with superb performance: energy density of {approx}760 Wh/kg and power density of 1200 W/kg. These results demonstrate feasibility of development of the ambient temperature Na-ion rechargeable batteries by employment of electrodes with tailored nanoarchitectures.

  17. Sodium and Oxygen Abundances in the Open Cluster NGC 6791 from APOGEE H-Band Spectroscopy

    E-Print Network [OSTI]

    Cunha, Katia; Johnson, Jennifer A; Bergemann, Maria; Meszaros, Szabolcs; Shetrone, Matthew D; Souto, Diogo; Prieto, Carlos Allende; Schiavon, Ricardo P; Frinchaboy, Peter; Zasowski, Gail; Bizyaev, Dmitry; Holtzman, Jon; Perez, Ana E Garcia; Majewski, Steven R; Nidever, David; Beers, Timothy; Carrera, Ricardo; Geisler, Doug; Gunn, James; Hearty, Fred; Ivans, Inese; Martell, Sarah; Pinsonneault, Marc; Schneider, Donald P; Sobeck, Jennifer; Stello, Dennis; Stassun, Keivan G; Skrutskie, Michael; Wilson, John C

    2014-01-01T23:59:59.000Z

    The open cluster NGC 6791 is among the oldest, most massive and metal-rich open clusters in the Galaxy. High-resolution $H$-band spectra from the Apache Point Observatory Galactic Evolution Experiment (APOGEE) of 11 red giants in NGC 6791 are analyzed for their chemical abundances of iron, oxygen, and sodium. The abundances of these three elements are found to be homogeneous (with abundance dispersions at the level of $\\sim$ 0.05 - 0.07 dex) in these cluster red giants, which span much of the red-giant branch (T$_{\\rm eff}$ $\\sim$ 3500K - 4600K), and include two red-clump giants. From the infrared spectra, this cluster is confirmed to be among the most metal-rich clusters in the Galaxy ($$ = 0.34 $\\pm$ 0.06), and is found to have a roughly solar value of [O/Fe] and slightly enhanced [Na/Fe]. Non-LTE calculations for the studied Na I lines in the APOGEE spectral region ($\\lambda$16373.86\\AA\\ and $\\lambda$16388.85\\AA) indicate only small departures from LTE ($\\leq$ 0.04 dex) for the parameter range and metallic...

  18. On the Criticality Safety of Transuranic Sodium Fast Reactor Fuel Transport Casks

    SciTech Connect (OSTI)

    Samuel Bays; Ayodeji Alajo

    2010-05-01T23:59:59.000Z

    This work addresses the neutronic performance and criticality safety issues of transport casks for fuel pertaining to low conversion ratio sodium cooled fast reactors, conventionally known as Advanced Burner Reactors. The criticality of a one, three, seven and 19-assembly cask capacity is presented. Both dry “helium” and flooded “water” filled casks are considered. No credit for fuel burnup or fission products was assumed. As many as possible of the conservatisms used in licensing light water reactor universal transport casks were incorporated into this SFR cask criticality design and analysis. It was found that at 7-assemblies or more, adding moderator to the SFR cask increases criticality margin. Also, removal of MAs from the fuel increases criticality margin of dry casks and takes a slight amount of margin away for wet casks. Assuming credit for borated fuel tube liners, this design analysis suggests that as many as 19 assemblies can be loaded in a cask if limited purely by criticality safety. If no credit for boron is assumed, the cask could possibly hold seven assemblies if low conversion ratio fast reactor grade fuel and not breeder reactor grade fuel is assumed. The analysis showed that there is a need for new cask designs for fast reactors spent fuel transportation. There is a potential of modifying existing transportation cask design as the starting point for fast reactor spent fuel transportation.

  19. Sodium spray and jet fire model development within the CONTAIN-LMR code

    SciTech Connect (OSTI)

    Scholtyssek, W. [Kernforschungszentrum Karlsruhe GmbH (Germany). Inst. fuer Neutronenphysik und Reaktortechnik; Murata, K.K. [Sandia National Labs., Albuquerque, NM (United States)

    1993-12-31T23:59:59.000Z

    An assessment was made of the sodium spray fire model implemented in the CONTAIN code. The original droplet burn model, which was based on the NACOM code, was improved in several aspects, especially concerning evaluation of the droplet burning rate, reaction chemistry and heat balance, spray geometry and droplet motion, and consistency with CONTAIN standards of gas property evaluation. An additional droplet burning model based on a proposal by Krolikowski was made available to include the effect of the chemical equilibrium conditions at the flame temperature. The models were validated against single-droplet burn experiments as well as spray and jet fire experiments. Reasonable agreement was found between the two burn models and experimental data. When the gas temperature in the burning compartment reaches high values, the Krolikowski model seems to be preferable. Critical parameters for spray fire evaluation were found to be the spray characterization, especially the droplet size, which largely determines the burning efficiency, and heat transfer conditions at the interface between the atmosphere and structures, which controls the thermal hydraulic behavior in the burn compartment.

  20. Spectrally resolved detection of sodium in the atmosphere of HD189733b with the HARPS spectrograph

    E-Print Network [OSTI]

    Wyttenbach, A; Lovis, C; Udry, S; Pepe, F

    2015-01-01T23:59:59.000Z

    Atmospheric properties of exoplanets can be constrained with transit spectroscopy. The signature of atomic sodium NaI, known to be present above the clouds, is a powerful probe of the upper atmosphere, where it can be best detected and characterized at high spectral resolution. Our goal is to obtain a high-resolution transit spectrum of HD189733b in the region around the resonance doublet of NaI at 589 nm, to characterize the absorption signature previously detected from space at low resolution. We analyze archival transit data of HD189733b obtained with the HARPS spectrograph. We retrieve the transit spectrum and light curve of the planet, implementing corrections for telluric contamination and planetary orbital motion. We spectrally resolve the NaI D doublet and measure line contrasts of $0.64\\pm0.07\\%$ (D2) and $0.40\\pm0.07\\%$ (D1) and FWHMs of $0.52\\pm0.08~\\AA$. This corresponds to a detection at the 10-$\\sigma$ level of excess of absorption of $0.32\\pm0.03\\%$ in a passband of $2\\times0.75\\ \\AA$ centered ...

  1. Effects of phosphorus on corrosion resistance of electroless nickel in 50% sodium hydroxide

    SciTech Connect (OSTI)

    Zeller, R.L. III (Occidental Chemical Corp., Grand Island, NY (United States)); Salvati, L. (Abbott Labs., Abbott Park, IL (United States))

    1994-06-01T23:59:59.000Z

    Nickel (Ni) and electroless nickel (EN) coatings are used extensively in caustic soda (NaOH) service. The corrosion resistance of an EN coating is dependent upon phosphorus (P) content, but not in the trend expected. High-phosphorus EN (HPEN) coatings have poorer corrosion resistance in hot, concentrated sodium hydroxide (NaOH) than low-phosphorus (LPEN) and medium-phosphorus (MPEN) coatings, which have a corrosion resistance comparable to Ni. The purpose of this work was to quantify the effect of P in EN coatings on their corrosion resistance in 50% NaOH at room temperature (RT). Electrochemical techniques were used to investigate the corrosion processes. X-ray photoelectron spectroscopy (XPS) was used to characterize coating surfaces. Very low corrosion rates ([<=] [mu]m/y) were measured for all coatings. It was proposed that the detrimental effect of P in EN coatings exposed to a concentrated NaOH environment was a result of the higher solubility of nickel phosphate (Ni[sub 3][PO[sub 4

  2. Design, fabrication, and testing of a sodium evaporator for the STM4-120 kinematic Stirling engine

    SciTech Connect (OSTI)

    Rawlinson, K.S.; Adkins, D.R.

    1995-05-01T23:59:59.000Z

    This report describes the development and testing of a compact heat-pipe heat exchanger kW(e) designed to transfer thermal energy from hot combustion gases to the heater tubes of a 25-kW(e) Stirling engine. In this system, sodium evaporates from a surface that is heated by a stream of hot gases. The liquid metal then condenses on the heater tubes of a Stirling engine, where energy is transferred to the engine`s helium working fluid. Tests on a prototype unit illustrated that a compact (8 cm {times} 13 cm {times} 16 cm) sodium evaporator can routinely transfer 15 kW(t) of energy at an operating vapor temperature of 760 C. Four of these prototype units were eventually used to power a 25-kW(e) Stirling engine system. Design details and test results from the prototype unit are presented in this report.

  3. Potential-induced degradation in solar cells: Electronic structure and diffusion mechanism of sodium in stacking faults of silicon

    SciTech Connect (OSTI)

    Ziebarth, Benedikt, E-mail: Benedikt.Ziebarth@iwm.fraunhofer.de; Gumbsch, Peter [Fraunhofer Institut für Werkstoffmechanik IWM, Wöhlerstr. 11, 79108 Freiburg (Germany); Karlsruher Institut für Technologie, Institut für Ausgewandte Materialien (IAM-ZBS), Engelbert-Arnold-Str. 4, 76131 Karlsruhe (Germany); Mrovec, Matous; Elsässer, Christian [Fraunhofer Institut für Werkstoffmechanik IWM, Wöhlerstr. 11, 79108 Freiburg (Germany)

    2014-09-07T23:59:59.000Z

    Sodium decorated stacking faults (SFs) were recently identified as the primary cause of potential-induced degradation in silicon (Si) solar-cells due to local electrical short-circuiting of the p-n junctions. In the present study, we investigate these defects by first principles calculations based on density functional theory in order to elucidate their structural, thermodynamic, and electronic properties. Our calculations show that the presence of sodium (Na) atoms leads to a substantial elongation of the Si-Si bonds across the SF, and the coverage and continuity of the Na layer strongly affect the diffusion behavior of Na within the SF. An analysis of the electronic structure reveals that the presence of Na in the SF gives rise to partially occupied defect levels within the Si band gap that participate in electrical conduction along the SF.

  4. Surface studies on aluminized and thermally oxidized superalloy 690 substrates interacted with simulated nuclear waste and sodium borosilicate melt

    SciTech Connect (OSTI)

    Yusufali, C., E-mail: yusuf@barc.gov.in; Sengupta, P.; Dutta, R. S.; Dey, G. K. [Materials Science Division, Bhabha Atomic Research Centre, Trombay, Mumbai-400085 (India); Kshirsagar, R. J. [High Pressure and Synchrotron Radiation Physics Division, Bhabha Atomic Research Centre, Trombay, Mumbai-400085 (India); Mishra, R. K.; Kaushik, C. P. [Waste Management Division, Bhabha Atomic Research Centre, Trombay, Mumbai-400085 (India)

    2014-04-24T23:59:59.000Z

    Aluminized and thermally oxidized Ni-Cr-Fe based superalloy 690 substrates with Al{sub 2}O{sub 3} layer on top have been exposed in nitrate based environment (simulated high level nuclear liquid waste) at 373 K for 216 hours and sodium borosilicate melt at 1248 K for 192 hours. The surfaces of exposed samples have been characterized by using Electron probe micro-analyzer (EPMA). Elemental X-ray mapping on coated specimen that exposed in simulated nuclear waste solution revealed that the surface is enriched with Ni, Cr and Al. X-ray mapping on surface of the specimen that interacted with sodium borosilicate melt indicated that the surface is composed of Al, Fe, Ni and Cr.

  5. Technical Review Report for the Justification for Shipment of Sodium-Bonded Carbide Fuel Pins in the T-3 Cask

    SciTech Connect (OSTI)

    West, M; DiSabatino, A

    2008-01-04T23:59:59.000Z

    This report documents the review of the Fluor Submittal (hereafter, the Submittal), prepared by Savannah River Packaging Technology (SRPT) of Savannah River National Laboratory (SRNL), at the request of the Department of Energy's (DOE) Richland Operations Office, for the shipment of unirradiated and irradiated sodium-bonded carbide fuel pins. The sodium-bonded carbide fuel pins are currently stored at the Fast Flux Test Facility (FFTF) awaiting shipment to Idaho National Laboratory (INL). Normally, modified contents are included into the next revision of the SARP. However, the contents, identified to be shipped from FFTF to Idaho National Laboratory, are a one-way shipment of 18 irradiated fuel pins and 7 unirradiated fuel pins, where the irradiated and unirradiated fuel pins are shipped separately, and can be authorized with a letter amendment to the existing Certificate of Compliance (CoC).

  6. High Magnetic Shear Gain in a Liquid Sodium Stable Couette Flow Experiment: A Prelude to an {alpha}-{Omega} Dynamo

    SciTech Connect (OSTI)

    Colgate, Stirling A. [T-2, MS B-227, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Department of Physics, New Mexico Institute of Mining and Technology, Socorro, New Mexico 87801 (United States); Beckley, Howard; Si, Jiahe; Martinic, Joe; Westpfahl, David; Slutz, James; Westrom, Cebastian; Klein, Brianna; Schendel, Paul; Scharle, Cletus; McKinney, Travis; Ginanni, Rocky; Bentley, Ian; Mickey, Timothy; Ferrel, Regnar [Department of Physics, New Mexico Institute of Mining and Technology, Socorro, New Mexico 87801 (United States); Li, Hui; Pariev, Vladimir [T-2, MS B-227, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Finn, John [T-5, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States)

    2011-04-29T23:59:59.000Z

    The {Omega} phase of the liquid sodium {alpha}-{Omega} dynamo experiment at New Mexico Institute of Mining and Technology in cooperation with Los Alamos National Laboratory has demonstrated a high toroidal field B{sub {phi}} that is {approx_equal}8xB{sub r}, where B{sub r} is the radial component of an applied poloidal magnetic field. This enhanced toroidal field is produced by the rotational shear in stable Couette flow within liquid sodium at a magnetic Reynolds number Rm{approx_equal}120. Small turbulence in stable Taylor-Couette flow is caused by Ekman flow at the end walls, which causes an estimated turbulence energy fraction of ({delta}v/v){sup 2{approx}}10{sup -3}.

  7. High magnetic shear gain in a liquid sodium stable couette flow experiment A prelude to an alpha - omega dynamo

    SciTech Connect (OSTI)

    Colgate, Stirling [Los Alamos National Laboratory; Li, Jui [Los Alamos National Laboratory; Finn, John [Los Alamos National Laboratory; Pariev, Vladimir [Los Alamos National Laboratory; Beckley, Howard [NM INSTIT. OF MINING AND TECH; Si, Jiahe [NM INSTIT. OF MINING AND TECH.; Martinic, Joe [NM INSTIT. OF MINING AND TECH.; Westpfahl, David [NM INSTIT. OF TECH.; Slutz, James [NM INSTIT. OF MINING AND TECH.; Westrom, Zeb [NM INSTIT. OF TECH.; Klein, Brianna [NM INSTIT. OF MINING AND TECH.

    2010-11-08T23:59:59.000Z

    The {Omega}-phase of the liquid sodium {alpha}-{Omega} dynamo experiment at NMIMT in cooperation with LANL has successfully demonstrated the production of a high toroidal field, B{sub {phi}} {approx_equal} 8 x B{sub r} from the radial component of an applied poloidal magnetic field, B{sub r}. This enhanced toroidal field is produced by rotational shear in stable Couette Row within liquid sodium at Rm {approx_equal} 120. The small turbulence in stable Taylor-Couette Row is caused by Ekman Row where ({delta}v/v){sup 2} {approx} 10{sup -3}. This high {Omega}-gain in low turbulence flow contrasts with a smaller {Omega}-gain in higher turbulence, Helmholtz-unstable shear flows. This result supports the ansatz that large scale astrophysical magnetic fields are created within semi-coherent large scale motions in which turbulence plays a diffusive role that enables magnetic flux linkage.

  8. Chromosome aberrations and mutations in sorghum induced by dimethyl-sulfoxide, ethylmethane-sulfonate, sodium fluoride and colchicine

    E-Print Network [OSTI]

    Chung, Seudy

    1968-01-01T23:59:59.000Z

    Aberrations and Mutations in Sorghum Induced by Dimethyl-gul fuaide, Ethylsnthana-Sulfonate, Sodium Pluorida and Colchicine. (August 1NS) Sandy Chucg, S. gc. , (Agronomy) Taiuan Prorincial Chungking University, Xainan China; H. gc. (Genetics) Tones Ah... by the various cbosdcal ccnhinstions. The various characteristics of dimethyl sulfonide affects in animal calla hsvo been studied by many investigators. polga ~ fl. (1949) first reported the protective action of glycerol against tha sdvsxsa affect of fressing...

  9. An investigation of the physical and numerical foundations of two-fluid representation of sodium boiling with applications to LMFBR experiments

    E-Print Network [OSTI]

    No, Hee Cheon

    1983-01-01T23:59:59.000Z

    This work involves the development of physical models for the constitutive relations of a two-fuid, three-dimensional sodium boiling code, THERMIT-6S. The code is equipped with a fluid conduction model, a fuel pin model, ...

  10. Sodium channel diversity in the vestibular ganglion : evidence for Nav?1.5-like and Nav?1.8-like currents

    E-Print Network [OSTI]

    Liu, Xiao-Ping, Ph. D. Massachusetts Institute of Technology

    2012-01-01T23:59:59.000Z

    Voltage-gated sodium (Nav) channels are diverse, comprising nine known mammalian subunits, which are classified pharmacologically into tetrodotoxin-sensitive (TTX-S) and tetrodotoxin-insensitive (TTX-1) categories. The ...

  11. Transport Pathways and Enhancement Mechanisms within Localized and Non-Localized Transport Regions in Skin Treated with Low-Frequency Sonophoresis and Sodium Lauryl Sulfate

    E-Print Network [OSTI]

    Polat, Baris E.

    Recent advances in transdermal drug delivery utilizing low-frequency sonophoresis (LFS) and sodium lauryl sulfate (SLS) have revealed that skin permeability enhancement is not homogenous across the skin surface. Instead, ...

  12. Effects of sodium lactate on the microbiological, chemical and color attributes of cooked, vacuum-packaged beef stored at various temperatures 

    E-Print Network [OSTI]

    Bigner, Marnie Elizabeth

    1993-01-01T23:59:59.000Z

    EFFECTS OF SODIUM LACTATE ON THE MICROBIOLOGICAL, CHEMICAL AND COLOR ATTRIBUTES OF COOKED, VACUUM- PACKAGED BEEF STORFD AT VARIOUS TEMPERATURES A Thesis hv MARNIE ELIZABFTH BIGNER Submitted to the Office of Graduate Studies of Texas ARM... University in partial fulfillment of the requirements for the degree MASTFRS OF SCII=. NCE August I')')3 Major Subject: Food Science and Technology EFFECT OF SODIUM LACTATE ON THE MICROBIOLOGICAL, CHEMICAL AND COLOR ATI'RIBUTES OF COOKED, VACUUM...

  13. The effect of modifications of dietary fat, fiber and sodium with magnesium deficiency on serum lipids and minerals, tissue and femur minerals and femur load force 

    E-Print Network [OSTI]

    Howe, Cathlyn Ann

    1992-01-01T23:59:59.000Z

    THE EFFECT OF MODIFICATIONS OF DIETARY FAT, FIBER AND SODIUM WITH MAGNESIUM DEFICIENCY ON SERUM LIPIDS AND MINERALS, TISSUE AND FEMUR MINERALS AND FEMUR LOAD FORCE A Thesis by CATHLYN ANN HOWE "Submitted to the Office of Graduate Studies oz..." Texas A&M University partial fulfillment of the requirements for the degree of MASTER OF SCIENCE December 1992 Major Subject: Nutrition THE EFFECTS OF MODIFICATIONS OF DIETARY FAT, FIBER AND SODIUM WITH MAGNESIUM DEFICIENCY ON SERUM LIPIDS...

  14. THE SUITABILITY OF SODIUM PEROXIDE FUSION FOR PRODUCTION-SCALE PLUTONIUM PROCESSING OPERATIONS

    SciTech Connect (OSTI)

    Pierce, R.; Edwards, T.

    2010-10-26T23:59:59.000Z

    Sodium peroxide (Na{sub 2}O{sub 2}) fusion is a method that offers significant benefits to the processing of high-fired plutonium oxide (PuO{sub 2}) materials. Those benefits include reduction in dissolution cycle time, decrease in residual solids, and reduction of the potential for generation of a flammable gas mixture during dissolution. Implementation of Na{sub 2}O{sub 2} fusion may also increase the PuO{sub 2} throughput in the HB-Line dissolving lines. To fuse a material, Na{sub 2}O{sub 2} is mixed with the feed material in a crucible and heated to 600-700 C. For low-fired and high-fired PuO{sub 2}, Na{sub 2}O{sub 2} reacts with PuO{sub 2} to form a compound that readily dissolves in ambient-temperature nitric acid without the use of potassium fluoride. The Savannah River National Laboratory (SRNL) demonstrated the feasibility of Na{sub 2}O{sub 2} fusion and subsequent dissolution for the processing of high-fired PuO{sub 2} materials in HB-Line. Testing evaluated critical dissolution characteristics and defined preliminary process parameters. Based on experimental measurements, a dissolution cycle can be complete in less than one hour, compared to the current processing time of 6-10 hours for solution heating and dissolution. Final Pu concentrations of 30-35 g/L were produced without the formation of precipitates in the final solution.

  15. Start-up fuel and power flattening of sodium-cooled candle core

    SciTech Connect (OSTI)

    Takaki, Naoyuki; Sagawa, Yu; Umino, Akitake [Department of Nuclear Safety Engineering, Tokyo City University 1-28-1 Tamazutsumi, Setagaya, Tokyo 158-8557 (Japan); Sekimoto, Hiroshi [University of California, Berkeley, CA 94720 (United States)

    2013-07-01T23:59:59.000Z

    The hard neutron spectrum and unique power shape of CANDLE enable its distinctive performances such as achieving high burnup more than 30% and exempting necessity of both enrichment and reprocessing. On the other hand, they also cause several challenging problems. One is how the initial fuel can be prepared to start up the first CANDLE reactor because the equilibrium fuel composition that enables stable CANDLE burning is complex both in axial and radial directions. Another prominent problem is high radial power peaking factor that worsens averaged burnup, namely resource utilization factor in once-through mode and shorten the life time of structure materials. The purposes of this study are to solve these two problems. Several ideas for core configurations and startup fuel using single enrichment uranium and iron as a substitute of fission products are studied. As a result, it is found that low enriched uranium is applicable to ignite the core but all concepts examined here exceeded heat limits. Adjustment in enrichment and height of active and burnt zone is opened for future work. Sodium duct assemblies and thorium fuel assemblies loaded in the center region are studied as measures to reduce radial power peaking factor. Replacing 37 fuels by thorium fuel assemblies in the zeroth to third row provides well-balanced performance with flattened radial power distribution. The CANDLE core loaded with natural uranium in the outer and thorium in the center region achieved 35.6% of averaged burnup and 7.0 years of cladding life time owing to mitigated local fast neutron irradiation at the center. Using thorium with natural or depleted uranium in CANDLE reactor is also beneficial to diversifying fission resource and extending available term of fission energy without expansion of needs for enrichment and reprocessing.

  16. Effect of Sodium Sulfide on Ni-Containing Carbon Monoxide Dehydrogenases

    SciTech Connect (OSTI)

    Jian Feng; Paul A. Lindahl

    2004-07-28T23:59:59.000Z

    OAK-B135 The structure of the active-site C-cluster in CO dehydrogenase from Carboxythermus hydrogenoformans includes a {mu}{sup 2}-sulfide ion bridged to the Ni and unique Fe, while the same cluster in enzymes from Rhodospirillum rubrum (CODH{sub Rr}) and Moorella thermoacetica (CODH{sub Mt}) lack this ion. This difference was investigated by exploring the effects of sodium sulfide on activity and spectral properties. Sulfide partially inhibited the CO oxidation activity of CODH{sub Rr} and generated a lag prior to steady-state. CODH{sub Mt} was inhibited similarly but without a lag. Adding sulfide to CODH{sub Mt} in the C{sub red1} state caused the g{sub av} = 1.82 EPR signal to decline and new features to appear, including one with g = 1.95, 1.85 and (1.70 or 1.62). Removing sulfide caused the g{sub av} = 1.82 signal to reappear and activity to recover. Sulfide did not affect the g{sub av} = 1.86 signal from the C{sub red2} state. A model was developed in which sulfide binds reversibly to C{sub red1}, inhibiting catalysis. Reducing this adduct causes sulfide to dissociate, C{sub red2} to develop, and activity to recover. Using this model, apparent K{sub I} values are 40 {+-} 10 nM for CODH{sub Rr} and 60 {+-} 30 {micro}M for CODH{sub Mt}. Effects of sulfide are analogous to those of other anions, including the substrate hydroxyl group, suggesting that these ions also bridge the Ni and unique Fe. This proposed arrangement raises the possibility that CO binding labilizes the bridging hydroxyl and increases its nucleophilic tendency towards attacking Ni-bound carbonyl.

  17. Sodium fast reactor gaps analysis of computer codes and models for accident analysis and reactor safety.

    SciTech Connect (OSTI)

    Carbajo, Juan (Oak Ridge National Laboratory, Oak Ridge, TN); Jeong, Hae-Yong (Korea Atomic Energy Research Institute, Daejeon, Korea); Wigeland, Roald (Idaho National Laboratory, Idaho Falls, ID); Corradini, Michael (University of Wisconsin, Madison, WI); Schmidt, Rodney Cannon; Thomas, Justin (Argonne National Laboratory, Argonne, IL); Wei, Tom (Argonne National Laboratory, Argonne, IL); Sofu, Tanju (Argonne National Laboratory, Argonne, IL); Ludewig, Hans (Brookhaven National Laboratory, Upton, NY); Tobita, Yoshiharu (Japan Atomic Energy Agency, Ibaraki-ken, Japan); Ohshima, Hiroyuki (Japan Atomic Energy Agency, Ibaraki-ken, Japan); Serre, Frederic (Centre d'%C3%94etudes nucl%C3%94eaires de Cadarache %3CU%2B2013%3E CEA, France)

    2011-06-01T23:59:59.000Z

    This report summarizes the results of an expert-opinion elicitation activity designed to qualitatively assess the status and capabilities of currently available computer codes and models for accident analysis and reactor safety calculations of advanced sodium fast reactors, and identify important gaps. The twelve-member panel consisted of representatives from five U.S. National Laboratories (SNL, ANL, INL, ORNL, and BNL), the University of Wisconsin, the KAERI, the JAEA, and the CEA. The major portion of this elicitation activity occurred during a two-day meeting held on Aug. 10-11, 2010 at Argonne National Laboratory. There were two primary objectives of this work: (1) Identify computer codes currently available for SFR accident analysis and reactor safety calculations; and (2) Assess the status and capability of current US computer codes to adequately model the required accident scenarios and associated phenomena, and identify important gaps. During the review, panel members identified over 60 computer codes that are currently available in the international community to perform different aspects of SFR safety analysis for various event scenarios and accident categories. A brief description of each of these codes together with references (when available) is provided. An adaptation of the Predictive Capability Maturity Model (PCMM) for computational modeling and simulation is described for use in this work. The panel's assessment of the available US codes is presented in the form of nine tables, organized into groups of three for each of three risk categories considered: anticipated operational occurrences (AOOs), design basis accidents (DBA), and beyond design basis accidents (BDBA). A set of summary conclusions are drawn from the results obtained. At the highest level, the panel judged that current US code capabilities are adequate for licensing given reasonable margins, but expressed concern that US code development activities had stagnated and that the experienced user-base and the experimental validation base was decaying away quickly.

  18. Environmental, health, and safety issues of sodium-sulfur batteries for electric and hybrid vehicles

    SciTech Connect (OSTI)

    Corbus, D.

    1992-09-01T23:59:59.000Z

    Recycling and disposal of spent sodium-sulfur (Na/S) batteries are important issues that must be addressed as part of the commercialization process of Na/S battery-powered electric vehicles. The use of Na/S batteries in electric vehicles will result in significant environmental benefits, and the disposal of spent batteries should not detract from those benefits. In the United States, waste disposal is regulated under the Resource Conservation and Recovery Act (RCRA). Understanding these regulations will help in selecting recycling and disposal processes for Na/S batteries that are environmentally acceptable and cost effective. Treatment processes for spent Na/S battery wastes are in the beginning stages of development, so a final evaluation of the impact of RCRA regulations on these treatment processes is not possible. The objectives of tills report on battery recycling and disposal are as follows: Provide an overview of RCRA regulations and requirements as they apply to Na/S battery recycling and disposal so that battery developers can understand what is required of them to comply with these regulations; Analyze existing RCRA regulations for recycling and disposal and anticipated trends in these regulations and perform a preliminary regulatory analysis for potential battery disposal and recycling processes. This report assumes that long-term Na/S battery disposal processes will be capable of handling large quantities of spent batteries. The term disposal includes treatment processes that may incorporate recycling of battery constituents. The environmental regulations analyzed in this report are limited to US regulations. This report gives an overview of RCRA and discusses RCRA regulations governing Na/S battery disposal and a preliminary regulatory analysis for Na/S battery disposal.

  19. THE OXYGEN VERSUS SODIUM (ANTI)CORRELATION(S) IN {omega} Cen

    SciTech Connect (OSTI)

    D'Antona, F.; Ventura, P. [INAF-Osservatorio di Roma, via Frascati 33, I-00040 Monteporzio (Italy); D'Ercole, A. [INAF-Osservatorio di Bologna, via Ranzani, 1, I-40127 Bologna (Italy); Marino, A. F. [Max-Planck-Institut fuer Astrophysik, Garching (Germany); Milone, A. P. [IAC-Instituto de Astrofisica de Canarias and Department of Astrophysics, University of La Laguna, VIa Lactea s/n, E-38200 La Laguna, Tenerife, Canary Islands (Spain); Vesperini, E., E-mail: francesca.dantona@oa-roma.inaf.it, E-mail: paolo.ventura@oa-roma.inaf.it, E-mail: annibale.dercole@oabo.inaf.it, E-mail: amarino@MPA-Garching.MPG.DE, E-mail: milone@iac.es, E-mail: vesperin@physics.drexel.edu [Department of Physics, Drexel University, Philadelphia, PA 19104 (United States)

    2011-07-20T23:59:59.000Z

    Recent examination of large samples of {omega} Cen giants shows that, as in mono-metallic globular clusters, sodium versus oxygen anticorrelation is present within each subset of stars with iron content in the range -1.9 {approx}< [Fe/H] {approx}< -1.3. These findings suggest that, while the second generation formation history in {omega} Cen is more complex than that of mono-metallic clusters, it shares some key steps with those simpler clusters. In addition, the giants in the range -1.3 < [Fe/H] {approx}< -0.7 show a direct O-Na correlation, at moderately low O, but Na up to 20 times solar. These peculiar Na abundances are not shared by stars in other environments often assumed to undergo a similar chemical evolution, such as in the field of the Sagittarius dwarf galaxy. These O and Na abundances match well the yields of the massive asymptotic giant branch (AGB) stars in the same range of metallicity, suggesting that the stars at [Fe/H] > -1.3 in {omega} Cen are likely to have formed directly from the pure ejecta of massive AGBs of the same metallicities. This is possible if the massive AGBs of [Fe/H] > -1.3 in the progenitor system evolve when all the pristine gas surrounding the cluster has been exhausted by the previous star formation events, or the protocluster interaction with the Galaxy caused the loss of a significant fraction of its mass, or of its dark matter halo, and the supernova ejecta have been able to clear the gas out of the system. The absence of dilution in the relatively metal-rich populations lends further support to a scenario of the formation of second generation stars in cooling flows from massive AGB progenitors. We suggest that the entire formation of {omega} Cen took place in a few 10{sup 8} yr, and discuss the problem of a prompt formation of s-process elements.

  20. Sodium Tetradecyl Sulphate Direct Intralesional Sclerotherapy of Venous Malformations of the Vulva and Vagina: Report of Five Cases

    SciTech Connect (OSTI)

    Krokidis, Miltiadis, E-mail: mkrokidis@hotmail.com [Guy's and St. Thomas' NHS Trust, Department of Radiology (United Kingdom); Venetucci, Pietro [University Hospital 'Federico II', Department of Cardiovascular and Interventional Radiology (Italy); Hatzidakis, Adam [Medical School of Crete (Greece); Iaccarino, Vittorio [University Hospital 'Federico II', Department of Cardiovascular and Interventional Radiology (Italy)

    2011-02-15T23:59:59.000Z

    We report five cases of female patients affected by symptomatic focal external genital venous malformations treated with percutaneous direct intralesional injection of sodium tetradecyl sulphate (STS). All patients were referred because of discomfort and pain when sexual intercourse was attempted. Direct sclerotherapy with 3% STS was performed on a day-hospital basis with the patient under local anesthesia. Complete resolution of the symptoms was achieved in all cases. No major adverse effects were reported. Direct intralesional sclerotherapy with STS may be considered a safe and effective method for the treatment of female external genital malformation without the necessity of general anesthesia for pain control.

  1. Interactions between trace metals, sodium and sorbents in combustion. Quarterly report No. 4, July 1, 1995--September 30, 1995

    SciTech Connect (OSTI)

    Wendt, J.O.L.; Davis, S.

    1995-10-15T23:59:59.000Z

    The proposed research is directed at an understanding of how to exploit interactions between sodium, toxic metals and sorbents, in order to optimize sorbents injection procedures, which can be used to capture and transform these metals into environmentally benign forms. The research will use a 17kW downflow, laboratory combustor, to yield data that can be interpreted in terms of fundamental kinetic mechanisms. Metals to be considered are lead, cadmium, and arsenic. Sorbents will be kaolinite, bauxite, and limestone. The role of sulfur will also be determined.

  2. Modification of alkaline pulping to facilitate the isolation of aliphatic acids. Part 1. Sodium hydroxide pretreatment of pine wood

    SciTech Connect (OSTI)

    Alen, R.; Niemelae, K.; Sjoestroem, E.

    1984-01-01T23:59:59.000Z

    Pretreating pine chips (Pinus sylvestris) with sodium hydroxide prior to the alkaline delignification kraft, kraft-anthraquinone, and soda-anthraquinone) can facilitate the recovery of the carbohydrate degradation products from alkaline pulping liquors. Under suitable pretreatment conditions large amounts of carbohydrate degradation products (alipahtic acids) were formed relative to lignin. The lignin fraction was composed of comparatively low-molecular-weight fragments. Although the delignification was considerably retarded and the yield (based on wood) was decreased by 1-3%, the properties of the resulting pulp were essentially maintained despite pretreatment. Finally, data are given for the composition of aliphatic acids in liquors resulting from pretreatments.

  3. Adding sodium hydroxide to study metal removal in a stream affected by acid mine drainage. Forest Service research paper

    SciTech Connect (OSTI)

    Amacher, M.C.; Brown, R.W.; Kotubi-Amacher, J.; Willis, A.

    1993-06-01T23:59:59.000Z

    Fisher Creek, a stream affected by acid mine drainage in the Beartooth Mountains of Montana, was studied to determine the extent to which copper and zinc would be removed from stream water when pH was increased by a pulse of sodium hydroxide. As stream pH increased, copper and zinc were rapidly and completely removed from stream water by adsorption or coprecipitation with freshly precipitated hydrous ferric oxide. In practice, the best way of increasing the pH of streams impacted by acid mine drainage would be to increase the alkalinity of tributaries by lining their channels with limestone rock.

  4. Evaluation of Homogeneous Options: Effects of Minor Actinide Exclusion from Single and Double Tier Recycle in Sodium Fast Reactors

    SciTech Connect (OSTI)

    R. M. Ferrer; S. Bays; M. Pope

    2008-03-01T23:59:59.000Z

    The Systems Analysis Campaign under the Global Nuclear Energy Partnership (GNEP) has requested the fuel cycle analysis group at the Idaho National Laboratory (INL) to analyze and provide isotopic data for four scenarios in which different strategies for Minor Actinides (MA) management are investigated. A 1000 MWth commercial-scale Sodium Fast Reactor (SFR) design was selected as the baseline in this scenario study. Two transuranic (TRU) conversion ratios, defined as the ratio of the amount of TRU produced over the TRU destroyed in the reactor core, along with different fuel-types were investigated.

  5. Interactions between trace metals, sodium and sorbents in combustion. Quarterly report No. 3, April 1, 1995--June 30, 1995

    SciTech Connect (OSTI)

    Wendt, J.O.L.

    1995-09-06T23:59:59.000Z

    The proposed research is directed at an understanding of how to exploit interactions between sodium, toxic metals and sorbents, in order to optimize sorbents injection procedures, which can be used to capture and transform these metals into environmentally benign forms. The research will use a 17kW downflow, laboratory combustor, to yield data that can be interpreted in terms of fundamental kinetic mechanisms. Metals to be considered are lead, cadmium, and arsenic. Sorbents will be kaolinite, bauxite, and limestone. The role of sulfur will also be determined.

  6. Metal and Ceramic Thin Film Growth by Reaction of Alkali Metals with Metal Halides: A New Route for

    E-Print Network [OSTI]

    Zachariah, Michael R.

    or metal oxide ceramic films are easily formed by the introduction of nitrogen or oxygen gases the precursors of sodium metal vapor, titanium tetrachloride (the limiting reagent), and either Ar or N2 gas, salt-free titanium (Ti), titanium nitride (TiN), and titanium silicide (TixSiy) thin films have been

  7. Ti-substituted tunnel-type Na0.44MnO2 oxide as a negative electrode for aqueous sodium-ion batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wang, Yuesheng [Chinese Academy of Sciences (CAS), Beijing (China). Inst. of High Energy Physics (IHEP); Liu, Jue [Brookhaven National Lab. (BNL), Upton, NY (United States); Lee, Byungju [Seoul National Univ. (Korea, Republic of); Qiao, Ruimin [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source; Yang, Zhenzhong [Chinese Academy of Sciences (CAS), Beijing (China). Inst. of High Energy Physics (IHEP); Xu, Shuyin [Chinese Academy of Sciences (CAS), Beijing (China). Inst. of High Energy Physics (IHEP); Yu, Xiqian [Brookhaven National Lab. (BNL), Upton, NY (United States)] (ORCID:000000018513518X); Gu, Lin [Chinese Academy of Sciences (CAS), Beijing (China). Inst. of High Energy Physics (IHEP); Hu, Yong-Sheng [Chinese Academy of Sciences (CAS), Beijing (China). Inst. of High Energy Physics (IHEP)] (ORCID:0000000284306474); Yang, Wanli [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source] (ORCID:0000000306668063); Kang, Kisuk [Seoul National Univ. (Korea, Republic of); Li, Hong [Chinese Academy of Sciences (CAS), Beijing (China). Inst. of High Energy Physics (IHEP)] (ORCID:000000028659086X); Yang, Xiao-Qing [Brookhaven National Lab. (BNL), Upton, NY (United States); Chen, Liquan [Chinese Academy of Sciences (CAS), Beijing (China). Inst. of High Energy Physics (IHEP); Huang, Xuejie [Chinese Academy of Sciences (CAS), Beijing (China). Inst. of High Energy Physics (IHEP)

    2015-03-25T23:59:59.000Z

    The aqueous sodium-ion battery system is a safe and low-cost solution for large-scale energy storage, due to the abundance of sodium and inexpensive aqueous electrolytes. Although several positive electrode materials, e.g., Na0.44MnO2, were proposed, few negative electrode materials, e.g., activated carbon and NaTi2(PO4)3, are available. Here we show that Ti-substituted Na0.44MnO2 (Na0.44[Mn1-xTix]O2) with tunnel structure can be used as a negative electrode material for aqueous sodium-ion batteries. This material exhibits superior cyclability even without the special treatment of oxygen removal from the aqueous solution. Atomic-scale characterizations based on spherical aberration-corrected electron microscopy and ab initio calculations are utilized to accurately identify the Ti substitution sites and sodium storage mechanism. Ti substitution tunes the charge ordering property and reaction pathway, significantly smoothing the discharge/charge profiles and lowering the storage voltage. Both the fundamental understanding and practical demonstrations suggest that Na0.44[Mn1-xTix]O2 is a promising negative electrode material for aqueous sodium-ion batteries.

  8. Ti-substituted tunnel-type Na0.44MnO2 oxide as a negative electrode for aqueous sodium-ion batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wang, Yuesheng; Liu, Jue; Lee, Byungju; Qiao, Ruimin; Yang, Zhenzhong; Xu, Shuyin; Yu, Xiqian; Gu, Lin; Hu, Yong-Sheng; Yang, Wanli; et al

    2015-03-25T23:59:59.000Z

    The aqueous sodium-ion battery system is a safe and low-cost solution for large-scale energy storage, due to the abundance of sodium and inexpensive aqueous electrolytes. Although several positive electrode materials, e.g., Na0.44MnO2, were proposed, few negative electrode materials, e.g., activated carbon and NaTi2(PO4)3, are available. Here we show that Ti-substituted Na0.44MnO2 (Na0.44[Mn1-xTix]O2) with tunnel structure can be used as a negative electrode material for aqueous sodium-ion batteries. This material exhibits superior cyclability even without the special treatment of oxygen removal from the aqueous solution. Atomic-scale characterizations based on spherical aberration-corrected electron microscopy and ab initio calculations are utilized to accuratelymore »identify the Ti substitution sites and sodium storage mechanism. Ti substitution tunes the charge ordering property and reaction pathway, significantly smoothing the discharge/charge profiles and lowering the storage voltage. Both the fundamental understanding and practical demonstrations suggest that Na0.44[Mn1-xTix]O2 is a promising negative electrode material for aqueous sodium-ion batteries.« less

  9. An electrochemical cell for in operando studies of lithium/sodium batteries using a conventional x-ray powder diffractometer

    SciTech Connect (OSTI)

    Shen, Yanbin; Pedersen, Erik E.; Christensen, Mogens; Iversen, Bo B., E-mail: bo@chem.au.dk [Center for Materials Crystallography, Department of Chemistry and iNANO, Aarhus University, Aarhus (Denmark)

    2014-10-15T23:59:59.000Z

    An electrochemical cell has been designed for powder X-ray diffraction studies of lithium ion batteries (LIB) and sodium ion batteries (SIB) in operando with high time resolution using a conventional powder X-ray diffractometer. The cell allows for studies of both anode and cathode electrode materials in reflection mode. The cell design closely mimics that of standard battery testing coin cells and allows obtaining powder X-ray diffraction patterns under representative electrochemical conditions. In addition, the cell uses graphite as the X-ray window instead of beryllium, and it is easy to operate and maintain. Test examples on lithium insertion/extraction in two spinel-type LIB electrode materials (Li{sub 4}Ti{sub 5}O{sub 12} anode and LiMn{sub 2}O{sub 4} cathode) are presented as well as first results on sodium extraction from a layered SIB cathode material (Na{sub 0.84}Fe{sub 0.56}Mn{sub 0.44}O{sub 2})

  10. Laboratory performance testing of an extruded bitumen containing a surrogate, sodium nitrate-based, low-level aqueous waste

    SciTech Connect (OSTI)

    Mattus, A.J.; Kaczmarsky, M.M.

    1986-12-15T23:59:59.000Z

    Laboratory results of a comprehensive, regulatory performance test program, utilizing an extruded bitumen and a surrogate, sodium nitrate-based waste, have been compiled at the Oak Ridge National Laboratory (ORNL). Using a 53 millimeter, Werner and Pfleiderer extruder, operated by personnel of WasteChem Corporation of Paramus, New Jersey, laboratory-scale, molded samples of type three, air blown bitumen were prepared for laboratory performance testing. A surrogate, low-level, mixed liquid waste, formulated to represent an actual on-site waste at ORNL, containing about 30 wt % sodium nitrate, in addition to eight heavy metals, cold cesium and strontium was utilized. Samples tested contained three levels of waste loading: that is, forty, fifty and sixty wt % salt. Performance test results include the ninety day ANS 16.1 leach test, with leach indices reported for all cations and anions, in addition to the EP Toxicity test, at all levels of waste loading. Additionally, test results presented also include the unconfined compressive strength and surface morphology utilizing scanning electron microscopy. Data presented include correlations between waste form loading and test results, in addition to their relationship to regulatory performance requirements.

  11. The development of a realistic source term for sodium-cooled fast reactors : assessment of current status and future needs.

    SciTech Connect (OSTI)

    LaChance, Jeffrey L.; Phillips, Jesse; Parma, Edward J., Jr.; Olivier, Tara Jean; Middleton, Bobby D.

    2011-06-01T23:59:59.000Z

    Sodium-cooled fast reactors (SFRs) continue to be proposed and designed throughout the United States and the world. Although the number of SFRs actually operating has declined substantially since the 1980s, a significant interest in advancing these types of reactor systems remains. Of the many issues associated with the development and deployment of SFRs, one of high regulatory importance is the source term to be used in the siting of the reactor. A substantial amount of modeling and experimental work has been performed over the past four decades on accident analysis, sodium coolant behavior, and radionuclide release for SFRs. The objective of this report is to aid in determining the gaps and issues related to the development of a realistic, mechanistically derived source term for SFRs. This report will allow the reader to become familiar with the severe accident source term concept and gain a broad understanding of the current status of the models and experimental work. Further, this report will allow insight into future work, in terms of both model development and experimental validation, which is necessary in order to develop a realistic source term for SFRs.

  12. Recovery Act - Demonstration of Sodium Ion Battery for Grid Level Applications

    SciTech Connect (OSTI)

    Wiley, Ted; Whitacre, Jay; Eshoo, Michael; Noland, James; Campbell, Williams; Spears, Christopher

    2012-08-31T23:59:59.000Z

    Aquion Energy received a $5.179 million cooperative research agreement under the Department of Energyâ??s Smart Grid Demonstration Program â?? Demonstration of Promising Energy Storage Technologies (Program Area 2.5) of FOA DE-FOE-0000036. The main objective of this project was to demonstrate Aquionâ??s low cost, grid-scale, ambient temperature sodium ion energy storage device. The centerpiece of the technology is a novel hybrid energy storage chemistry that has been proven in a laboratory environment. The objective was to translate these groundbreaking results from the small-batch, small-cell test environment to the pilot scale to enable significant numbers of multiple ampere-hour cells to be manufactured and assembled into test batteries. Aquion developed a proof of concept demonstration unit that showed similar performance and major cost improvement over existing technologies. Beyond minimizing cell and system cost, Aquion built a technology that is safe, environmentally benign and durable over many thousands of cycles as used in a variety of grid support roles. As outlined in the Program documents, the original goals of the project were to demonstrate a unit that: 1. Has a projected capital cost of less than $250/kWh at the pack level 2. A deep discharge cycle life of > 10,000 cycles 3. A volumetric energy density of >20 kWh/m3 4. Projected calendar life of over 10 years 5. A device that contains no hazardous materials and retains best in class safety characteristics. Through the course of this project Aquion developed its aqueous electrolyte electrochemical energy storage device to the point where large demonstration units (> 10 kWh) were able to function in grid-supporting functions detailed by their collaborators. Aquionâ??s final deliverable was an ~15 kWh system that has the ability to perform medium to long duration (> 2 hours) charge and discharge functions approaching 95% DC-DC efficiency. The system has functioned, and continues to function as predicted with no indication that it will not tolerate well beyond 10 calendar years and 10,000 cycles. It has been in continuous operation for more than 1 year with 1,000 cycles (of varying depth of discharge, including 100% depth of discharge) and no identifiable degradation to the system. The final thick electrode cell structure has shown an energy density of 25 kWh/m3 at a five hour (or greater) discharge time. The primary chemistry has remained non-toxic, containing no acids or other corrosive chemicals, and the battery units have passed numerous safety tests, including flame resistance testing. These tests have verified the claim that the device is safe to use and contains no hazardous materials. Current projections show costs at the pack level to offer best in class value and are competitive with lead-acid batteries, factoring in LCOE.

  13. Converting Simulated Sodium-bearing Waste into a Single Solid Waste Form by Evaporation: Laboratory- and Pilot-Scale Test Results on Recycling Evaporator Overheads

    SciTech Connect (OSTI)

    Griffith, D.; D. L. Griffith; R. J. Kirkham; L. G. Olson; S. J. Losinski

    2004-01-01T23:59:59.000Z

    Conversion of Idaho National Engineering and Environmental Laboratory radioactive sodium-bearing waste into a single solid waste form by evaporation was demonstrated in both flask-scale and pilot-scale agitated thin film evaporator tests. A sodium-bearing waste simulant was adjusted to represent an evaporator feed in which the acid from the distillate is concentrated, neutralized, and recycled back through the evaporator. The advantage to this flowsheet is that a single remote-handled transuranic waste form is produced in the evaporator bottoms without the generation of any low-level mixed secondary waste. However, use of a recycle flowsheet in sodium-bearing waste evaporation results in a 50% increase in remote-handled transuranic volume in comparison to a non-recycle flowsheet.

  14. FeO0.7F1.3/C Nanocomposite as a High-Capacity Cathode Material for Sodium-Ion Batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhou, Yong-Ning [Brookhaven National Laboratory, Department of Chemistry, Uptown, NY (United States); Sina, Masha [Rutgers Univ., Materials and Engineering, Piscataway, NJ (United States); Pereira, Nathalie [Rutgers Univ., Energy Storage Research Group (ESRG), Piscataway, NJ (United States); Yu, Xiquian [Brookhaven National Laboratory, Department of Chemistry, Uptown, NY (United States); Amatucci, Glenn G. [Rutgers Univ., Energy Storage Research Group (ESRG), Piscataway, NJ (United States); Yang, Xiao-Qing [Brookhaven National Laboratory, Department of Chemistry, Uptown, NY (United States); Cosandey, Frederic [Rutgers Univ., Materials and Engineering, Piscataway, NJ (United States); Nam, Kyung-Wan [Dongguk University-Seoul (Korea, Republic of). Dept. of Energy and Materials Engineering

    2015-02-01T23:59:59.000Z

    Searching high capacity cathode materials is one of the most important fields of the research and development of sodium-ion batteries (SIBs). Here, we report a FeO0.7F1.3/C nanocomposite synthesized via a solution process as a new cathode material for SIBs. This material exhibits a high initial discharge capacity of 496 mAh g-1 in a sodium cell at 50 °C. From the 3rd to 50th cycle, the capacity fading is only 0.14% per cycle (from 388 mAh g-1 at 3rd the cycle to 360 mAh g-1 at the 50th cycle), demonstrating superior cyclability. A high energy density of 650 Wh kg-1 is obtained at the material level. The reaction mechanism studies of FeO0.7F1.3/C with sodium show a hybridized mechanism of both intercalation and conversion reaction.

  15. The effect of different dietary ratios of sodium and chloride on the physiological responses of lactating dairy cattle in hot weather 

    E-Print Network [OSTI]

    Grant, Pamela Ann

    1980-01-01T23:59:59.000Z

    THE EFFECT OF DIFFERENT DIETARY RATIOS OF SODIUM AND CHLORIDE ON THE PHYSIOLOGICAL RESPONSES OF LACTATING DAIRY CATTLE IN HOT WEATHER A Thesis by PAMELA ANN GRANT Submitted to the Graduate College of Texas A8cM Univers' ty in partial... fulfillme'nt of the requirement for the degree of MASTER OF SCIENCE May 1980 Major Subject: Animal Nutrition THE EFFECT OF DIFFERENT DIETARY RATIOS OF SODIUM AND CHLORIDE ON THE PHYSIOLOGICAL RESPONSES OF LACTATING DAIRY CATTLE IN HOT WEATHER A Thesis...

  16. Interactions between trace metals, sodium and sorbents in combustion. Quarterly report No. 5, October 1, 1995--December 30, 1995

    SciTech Connect (OSTI)

    Wendt, J.O.L.; Davis, S.

    1996-06-01T23:59:59.000Z

    The proposed research is directed at an understanding of how to exploit interactions between sodium, toxic metals and sorbents, in order to optimize sorbents injection procedures,which can be used to capture and transform these metals into environmentally benign forms. The research will use a 17kW downflow, laboratory combustor, to yield data that can be interpreted in terms of fundamental kinetic mechanisms. Metals to be considered are lead, cadmium, and arsenic. Sorbents will be kaolinite, bauxite, and limestone. The role of sulfur will also be determined. The research is divided into the following five tasks: (1) combustor modifications; (2) screening experiments; (3) mechanisms; (4) applications and (5) mathematical modelling. Accomplishments for this past quarter are briefly described for tasks 1 and 2.

  17. Application of GRS method to evaluation of uncertainties of calculation parameters of perspective sodium-cooled fast reactor

    SciTech Connect (OSTI)

    Peregudov, A.; Andrianova, O.; Raskach, K.; Tsibulya, A. [Inst. for Physics and Power Engineering, Bondarenko Square 1, Obninsk 244033, Kaluga Region (Russian Federation)

    2012-07-01T23:59:59.000Z

    A number of recent studies have been devoted to the estimation of errors of reactor calculation parameters by the GRS (Generation Random Sampled) method. This method is based on direct sampling input data resulting in formation of random sets of input parameters which are used for multiple calculations. Once these calculations are performed, statistical processing of the calculation results is carried out to determine the mean value and the variance of each calculation parameter of interest. In our study this method is used for estimation of errors of calculation parameters (K{sub eff}, power density, dose rate) of a perspective sodium-cooled fast reactor. Neutron transport calculations were performed by the nodal diffusion code TRIGEX and Monte Carlo code MMK. (authors)

  18. Sorbent selection and design considerations for uranium trapping. [H-151 alumina, XF-100 alumina, F-1 alumina, sodium fluoride

    SciTech Connect (OSTI)

    Schultz, R.M.; Hobbs, W.E.; Norton, J.L.; Stephenson, M.J.

    1981-07-01T23:59:59.000Z

    The efficient removal of UF/sub 6/ from effluent streams can be accomplished through the selection of the best solid sorbent and the implementation of good design principles. Pressure losses, sorbent capacity, reaction kinetics, sorbent regeneration/uranium recovery requirements and the effects of other system components are the performance factors which are summarized. The commonly used uranium trapping materials highlighted are sodium fluoride, H-151 alumina, XF-100 alumina, and F-1 alumina. Sorbent selection and trap design have to be made on a case-by-case basis but the theoretical modeling studies and the evaluation of the performance factors presented can be used as a guide for other chemical trap applications.

  19. Suppression of fine-structure splitting and oscillator strength of sodium D-line in a Debye plasma

    SciTech Connect (OSTI)

    Basu, Joyee, E-mail: joyeebasu@yahoo.com; Ray, Debasis, E-mail: ray.debasis@gmail.com [Department of Physics, Bengal Engineering and Science University, Shibpur, Howrah, West Bengal 711 103 (India)] [Department of Physics, Bengal Engineering and Science University, Shibpur, Howrah, West Bengal 711 103 (India)

    2014-01-15T23:59:59.000Z

    We investigate theoretically the influence of static plasma screening on relativistic spin-orbit interaction-induced fine-structure splitting of the D-line doublet arising from the transitions 3p{sub 1/2}–3s{sub 1/2} and 3p{sub 3/2}–3s{sub 1/2} of the valence electron of a sodium atom embedded in a model plasma environment. The many-electron atomic problem is formulated first as an effective one-electron problem in which the interaction between the optically active valence electron and the atomic ion core is represented by an accurate parametric model potential including core-polarization correction, and then the plasma effect on the atomic system is simulated by the Debye-screening model for the valence-core interaction. It is observed that the magnitude of spin-orbit energy shift reduces for both the upper component 3p{sub 3/2} and the lower component 3p{sub 1/2} with increasing plasma screening strength, thereby reducing the spin-orbit energy separation between these two components as the screening becomes stronger. As a consequence, the magnitude of fine-structure splitting between the D{sub 1} and D{sub 2} line energies of sodium drops significantly with stronger plasma screening. The optical (absorption) oscillator strength for 3s ? 3p transition is seen to reduce with stronger screening and this leads to a screening-induced gradual suppression of the 3p ? 3s spontaneous decay rate.

  20. An Analysis of Methanol and Hydrogen Production via High-Temperature Electrolysis Using the Sodium Cooled Advanced Fast Reactor

    SciTech Connect (OSTI)

    Shannon M. Bragg-Sitton; Richard D. Boardman; Robert S. Cherry; Wesley R. Deason; Michael G. McKellar

    2014-03-01T23:59:59.000Z

    Integration of an advanced, sodium-cooled fast spectrum reactor into nuclear hybrid energy system (NHES) architectures is the focus of the present study. A techno-economic evaluation of several conceptual system designs was performed for the integration of a sodium-cooled Advanced Fast Reactor (AFR) with the electric grid in conjunction with wind-generated electricity. Cases in which excess thermal and electrical energy would be reapportioned within an integrated energy system to a chemical plant are presented. The process applications evaluated include hydrogen production via high temperature steam electrolysis and methanol production via steam methane reforming to produce carbon monoxide and hydrogen which feed a methanol synthesis reactor. Three power cycles were considered for integration with the AFR, including subcritical and supercritical Rankine cycles and a modified supercritical carbon dioxide modified Brayton cycle. The thermal efficiencies of all of the modeled power conversions units were greater than 40%. A thermal efficiency of 42% was adopted in economic studies because two of the cycles either performed at that level or could potentially do so (subcritical Rankine and S-CO2 Brayton). Each of the evaluated hybrid architectures would be technically feasible but would demonstrate a different internal rate of return (IRR) as a function of multiple parameters; all evaluated configurations showed a positive IRR. As expected, integration of an AFR with a chemical plant increases the IRR when “must-take” wind-generated electricity is added to the energy system. Additional dynamic system analyses are recommended to draw detailed conclusions on the feasibility and economic benefits associated with AFR-hybrid energy system operation.

  1. The PDZ Domain Protein PICK1 and the Sodium Channel BNaC1 Interact and Localize at Mechanosensory Terminals of Dorsal Root

    E-Print Network [OSTI]

    Corey, David P.

    The PDZ Domain Protein PICK1 and the Sodium Channel BNaC1 Interact and Localize at Mechanosensory) in a yeast two-hybrid screen. We show by two-hybrid assays, glutathione S-transfer- ase pull-down assays Purkinje neu- rons, localizing to their dendrites and cell bodies. There- fore, PICK1 interacts with BNa

  2. Isotope loss from exhaled moisture and correlation of multifrequency bioelectrical impedance to body fluid compartments measured by intravenous deuterium oxide and sodium bromide dilution in dogs

    E-Print Network [OSTI]

    Witten, Tiffani Tipton

    2000-01-01T23:59:59.000Z

    for this route of isotope loss was necessary. Sodium bromide concentrations at 90 minutes and 180 minutes were tested for statistical equivalency to determine if NaBr had equilibrated by 90 minutes. Finally, impedance measured with electrodes separated by 2...

  3. The following values were studied : pH, water retention ability, coloring, transformation yield, amount of residual nitrite, and distributior of sodium chloride in the finished product.

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    The following values were studied : pH, water retention ability, coloring, transformation yield, amount of residual nitrite, and distributior of sodium chloride in the finished product. As a general sampling sites, lard weight, coloration index, and water retention ability in fresh ham. Values obtained

  4. Nuclear spin relaxation of sodium cations in bacteriophage Pf1 solutions D. N. Sobieski, N. R. Krueger, S. Vyas,a

    E-Print Network [OSTI]

    Augustine, Mathew P.

    Nuclear spin relaxation of sodium cations in bacteriophage Pf1 solutions D. N. Sobieski, N. R The nuclear magnetic resonance NMR spectra for the I=3/2 23 Na cation dissolved into filamentous bacteriophage the 23 Na nuclear quadrupole moment and the electric field gradient produced by the negatively charged Pf

  5. Hazardous Materials Verification and Limited Characterization Report on Sodium and Caustic Residuals in Materials and Fuel Complex Facilities MFC-799/799A

    SciTech Connect (OSTI)

    Gary Mecham

    2010-08-01T23:59:59.000Z

    This report is a companion to the Facilities Condition and Hazard Assessment for Materials and Fuel Complex Sodium Processing Facilities MFC-799/799A and Nuclear Calibration Laboratory MFC-770C (referred to as the Facilities Condition and Hazards Assessment). This report specifically responds to the requirement of Section 9.2, Item 6, of the Facilities Condition and Hazards Assessment to provide an updated assessment and verification of the residual hazardous materials remaining in the Sodium Processing Facilities processing system. The hazardous materials of concern are sodium and sodium hydroxide (caustic). The information supplied in this report supports the end-point objectives identified in the Transition Plan for Multiple Facilities at the Materials and Fuels Complex, Advanced Test Reactor, Central Facilities Area, and Power Burst Facility, as well as the deactivation and decommissioning critical decision milestone 1, as specified in U.S. Department of Energy Guide 413.3-8, “Environmental Management Cleanup Projects.” Using a tailored approach and based on information obtained through a combination of process knowledge, emergency management hazardous assessment documentation, and visual inspection, this report provides sufficient detail regarding the quantity of hazardous materials for the purposes of facility transfer; it also provides that further characterization/verification of these materials is unnecessary.

  6. Testing and Disposal Strategy for Secondary Wastes from Vitrification of Sodium-Bearing Waste at Idaho Nuclear Technology and Engineering Center

    SciTech Connect (OSTI)

    Herbst, Alan K.

    2002-01-02T23:59:59.000Z

    The Idaho National Engineering and Environmental Laboratory (INEEL) is considering vitrification to process liquid sodium-bearing waste. Preliminary studies were completed to evaluate the potential secondary wastes comprise acidic and caustic scrubber solutions, HEPA filters, activated carbon, and ion exchange media. Possible treatment methods, waste forms, and disposal sites are evaluated from radiological and mercury contamination estimates.

  7. Testing and Disposal Strategy for Secondary Wastes from Vitrification of Sodium-Bearing Waste at the Idaho Nuclear Technology and Engineering Center

    SciTech Connect (OSTI)

    Herbst, Alan Keith

    2002-01-01T23:59:59.000Z

    The Idaho National Engineering and Environmental Laboratory (INEEL) is considering vitrification to process liquid sodium-bearing waste. Preliminary studies were completed to evaluate the potential secondary wastes comprise acidic and caustic scrubber solutions, HEPA filters, activated carbon, and ion exchange media. Possible treatment methods, waste forms, and disposal sites are evaluated from radiological and mercury contamination estimates.

  8. ELSEVIER Journal ofNon-CrystallineSolids208 (1996)267-276 An XPS study of iron sodium silicate glass surfaces

    E-Print Network [OSTI]

    Mekki, Abdelkarim

    silicate glass surfaces A. Mekki a,b, D. Holland a,*, C.F. McConville a, M. Salim b a Department of Physics of the local structure of silicate, germanate, and phosphate-based glasses [1-4]. Iron sodium silicate glasses. For silicate glasses, however, Fe 2+ exhibits a higher solubility and ionic diffusion than Fe 3+, suggesting

  9. Standard test method for evaluating stress-corrosion cracking of stainless alloys with different nickel content in boiling acidified sodium chloride solution

    E-Print Network [OSTI]

    American Society for Testing and Materials. Philadelphia

    2000-01-01T23:59:59.000Z

    1.1 This test method describes a procedure for conducting stress-corrosion cracking tests in an acidified boiling sodium chloride solution. This test method is performed in 25% (by mass ) sodium chloride acidified to pH 1.5 with phosphoric acid. This test method is concerned primarily with the test solution and glassware, although a specific style of U-bend test specimen is suggested. 1.2 This test method is designed to provide better correlation with chemical process industry experience for stainless steels than the more severe boiling magnesium chloride test of Practice G36. Some stainless steels which have provided satisfactory service in many environments readily crack in Practice G36, but have not cracked during interlaboratory testing using this sodium chloride test method. 1.3 This boiling sodium chloride test method was used in an interlaboratory test program to evaluate wrought stainless steels, including duplex (ferrite-austenite) stainless and an alloy with up to about 33% nickel. It may also b...

  10. Evaluation of Heterogeneous Options: Effects of MgO versus UO2 Matrix Selection for Minor Actinide Targets in a Sodium Fast Reactor

    SciTech Connect (OSTI)

    M. Pope; S. Bays; R. Ferrer

    2008-03-01T23:59:59.000Z

    The primary focus of this work was to compare MgO with UO2 as target matrix material options for burning minor actinides in a transmutation target within a sodium fast reactor. This analysis compared the transmutation performance of target assemblies having UO2 matrix to those having specifically MgO inert matrix.

  11. Hormonal adaptation to the stresses imposed upon sodium balance by pregnancy and lactation in the Yanomama Indians: a culture without salt

    SciTech Connect (OSTI)

    Oliver, W.J.; Neel, J.V.; Grekin, R.J.; Cohen, E.L.

    1981-01-01T23:59:59.000Z

    The Yanomama Indians of northern Brazil and southern Venezuela have been identified as a no salt culture. In this study, data were obtained to determine in this population the adjustments of sodium-related hormones to the stresses imposed upon sodium balance by pregnancy and prolonged lactation. Controls against the possibility that findings in the Yanomama were ethnic rather than dietary were provided by similar observations in the Guaymi Indians of Panama, who have free access to salt. Urinary concentrations of sodium were approximately 1 mEq/l in male and female Yanomama, with 24-h excretion rates in the males averaging 1 mEq, similar to our prior observations. The pregnant Yanomama had exceeding high urinary concentrations of aldosterone. These were associated with higher plasma renin activities and serum aldosterone concentrations than in all other subjects. Although pregnant Guaymi had elevations of serum and urinary aldosterone, these were significantly lower (p < 0.001) than those of the Yanomama. Prolonged lactation in the Yanomama was associated with elevation of plasma renin activity and serum and urinary aldosterone concentration compared with the Guaymi, but were not higher than those in nonlactating Yanomama females. The findings suggest that pregnancy in a salt-poor environment is associated with an exaggerated augmentation of hormonal responses that enhance positive sodium balance.

  12. Unique properties of ?-NaFeO{sub 2}: De-intercalation of sodium via hydrolysis and the intercalation of guest molecules into the extract solution

    SciTech Connect (OSTI)

    Monyoncho, Evans; Bissessur, Rabin, E-mail: rabissessur@upei.ca

    2013-07-15T23:59:59.000Z

    Graphical abstract: - Highlights: • Facile de-intercalating Na from NaFeO2. • Formation of layered sodium hydrogen carbonate hydrate. • Intercalation chemistry on layered sodium hydrogen carbonate hydrate. - Abstract: We report on a versatile method for the de-intercalation of Na from ?-NaFeO{sub 2} by using water to produce ?-Na{sub 1?x}FeO{sub 2}, where x ? 1. This de-intercalation technique provides an excellent route to ion exchange Na with other metal ions in ?-NaFeO{sub 2}. The hydrolysis mechanism is provided. We show that the extracted solution captures CO{sub 2} from the atmosphere leading to the formation of sodium hydrogen carbonate hydrate crystals. The lamellar structure of the hydrate crystals was confirmed by powder X-ray diffraction, and were found Na-deficient via elemental analysis. Intercalation of guest molecules such as polymers, alcohols, and inorganic ions into the gallery space of the newly formed sodium hydrogen carbonate hydrate crystals was demonstrated by the use of powder X-ray diffraction technique. The reported materials were also characterized by Mössbauer spectroscopy, thermogravimetric analysis, differential scanning calorimetry, infrared spectroscopy, X-ray photoelectron spectroscopy, and scanning electron microscopy.

  13. Realization of Bose-Einstein condensates in lower dimensions Bose-Einstein condensates of sodium atoms have been prepared in optical and

    E-Print Network [OSTI]

    Realization of Bose-Einstein condensates in lower dimensions Bose-Einstein condensates of sodium dimensions exceeds the interaction energy between atoms. This realized condensates of lower dimensionality [1]. In anisotropic traps, a primary indicator of crossing the transition temperature for Bose- Einstein condensation

  14. Pyroprocessing of oxidized sodium-bonded fast reactor fuel - An experimental study of treatment options for degraded EBR-II fuel

    SciTech Connect (OSTI)

    Hermann, S.D.; Gese, N.J. [Separations Department, Idaho National Laboratory, P.O. Box 1625, Idaho Falls, ID 83415 (United States); Wurth, L.A. [Zinc Air Inc., 5314-A US Hwy 2 West, Columbia Falls, MT 59912 (United States)

    2013-07-01T23:59:59.000Z

    An experimental study was conducted to assess pyrochemical treatment options for degraded EBR-II fuel. As oxidized material, the degraded fuel would need to be converted back to metal to enable electrorefining within an existing electro-metallurgical treatment process. A lithium-based electrolytic reduction process was studied to assess the efficacy of converting oxide materials to metal with a particular focus on the impact of zirconium oxide and sodium oxide on this process. Bench-scale electrolytic reduction experiments were performed in LiCl-Li{sub 2}O at 650 C. degrees with combinations of manganese oxide (used as a surrogate for uranium oxide), zirconium oxide, and sodium oxide. In the absence of zirconium or sodium oxide, the electrolytic reduction of MnO showed nearly complete conversion to metal. The electrolytic reduction of a blend of MnO-ZrO{sub 2} in LiCl - 1 wt% Li{sub 2}O showed substantial reduction of manganese, but only 8.5% of the zirconium was found in the metal phase. The electrolytic reduction of the same blend of MnO-ZrO{sub 2} in LiCl - 1 wt% Li{sub 2}O - 6.2 wt% Na{sub 2}O showed substantial reduction of manganese, but zirconium reduction was even less at 2.4%. This study concluded that ZrO{sub 2} cannot be substantially reduced to metal in an electrolytic reduction system with LiCl - 1 wt% Li{sub 2}O at 650 C. degrees due to the perceived preferential formation of lithium zirconate. This study also identified a possible interference that sodium oxide may have on the same system by introducing a parasitic and cyclic reaction of dissolved sodium metal between oxidation at the anode and reduction at the cathode. When applied to oxidized sodium-bonded EBR-II fuel (e.g., U-10Zr), the prescribed electrolytic reduction system would not be expected to substantially reduce zirconium oxide, and the accumulation of sodium in the electrolyte could interfere with the reduction of uranium oxide, or at least render it less efficient.

  15. Sodium to sodium carbonate conversion process

    DOE Patents [OSTI]

    Herrmann, S.D.

    1997-10-14T23:59:59.000Z

    A method is described for converting radioactive alkali metal into a low level disposable solid waste material. The radioactive alkali metal is atomized and introduced into an aqueous caustic solution having caustic present in the range of from about 20 wt % to about 70 wt % to convert the radioactive alkali metal to a radioactive alkali metal hydroxide. The aqueous caustic containing radioactive alkali metal hydroxide and CO{sub 2} are introduced into a thin film evaporator with the CO{sub 2} present in an amount greater than required to convert the alkali metal hydroxide to a radioactive alkali metal carbonate, and thereafter the radioactive alkali metal carbonate is separated from the thin film evaporator as a dry powder. Hydroxide solutions containing toxic metal hydroxide including one or more metal ions of Sb, As, Ba, Be, Cd, Cr, Pb, Hg, Ni, Se, Ag and Tl can be converted into a low level non-hazardous waste using the thin film evaporator of the invention. 3 figs.

  16. Sodium to sodium carbonate conversion process

    DOE Patents [OSTI]

    Herrmann, Steven D. (Idaho Falls, ID)

    1997-01-01T23:59:59.000Z

    A method of converting radioactive alkali metal into a low level disposable solid waste material. The radioactive alkali metal is atomized and introduced into an aqueous caustic solution having caustic present in the range of from about 20 wt % to about 70 wt % to convert the radioactive alkali metal to a radioactive alkali metal hydroxide. The aqueous caustic containing radioactive alkali metal hydroxide and CO.sub.2 are introduced into a thin film evaporator with the CO.sub.2 present in an amount greater than required to convert the alkali metal hydroxide to a radioactive alkali metal carbonate, and thereafter the radioactive alkali metal carbonate is separated from the thin film evaporator as a dry powder. Hydroxide solutions containing toxic metal hydroxide including one or more metal ions of Sb, As, Ba, Be, Cd, Cr, Pb, Hg, Ni, Se, Ag and T1 can be converted into a low level non-hazardous waste using the thin film evaporator of the invention.

  17. Investigation of plant control strategies for the supercritical C0{sub 2}Brayton cycle for a sodium-cooled fast reactor using the plant dynamics code.

    SciTech Connect (OSTI)

    Moisseytsev, A.; Sienicki, J. (Nuclear Engineering Division)

    2011-04-12T23:59:59.000Z

    The development of a control strategy for the supercritical CO{sub 2} (S-CO{sub 2}) Brayton cycle has been extended to the investigation of alternate control strategies for a Sodium-Cooled Fast Reactor (SFR) nuclear power plant incorporating a S-CO{sub 2} Brayton cycle power converter. The SFR assumed is the 400 MWe (1000 MWt) ABR-1000 preconceptual design incorporating metallic fuel. Three alternative idealized schemes for controlling the reactor side of the plant in combination with the existing automatic control strategy for the S-CO{sub 2} Brayton cycle are explored using the ANL Plant Dynamics Code together with the SAS4A/SASSYS-1 Liquid Metal Reactor (LMR) Analysis Code System coupled together using the iterative coupling formulation previously developed and implemented into the Plant Dynamics Code. The first option assumes that the reactor side can be ideally controlled through movement of control rods and changing the speeds of both the primary and intermediate coolant system sodium pumps such that the intermediate sodium flow rate and inlet temperature to the sodium-to-CO{sub 2} heat exchanger (RHX) remain unvarying while the intermediate sodium outlet temperature changes as the load demand from the electric grid changes and the S-CO{sub 2} cycle conditions adjust according to the S-CO{sub 2} cycle control strategy. For this option, the reactor plant follows an assumed change in load demand from 100 to 0 % nominal at 5 % reduction per minute in a suitable fashion. The second option allows the reactor core power and primary and intermediate coolant system sodium pump flow rates to change autonomously in response to the strong reactivity feedbacks of the metallic fueled core and assumed constant pump torques representing unchanging output from the pump electric motors. The plant behavior to the assumed load demand reduction is surprising close to that calculated for the first option. The only negative result observed is a slight increase in the intermediate inlet sodium temperatures by about 10 C. This temperature rise could presumably be precluded or significantly reduced through fine adjustment of the control rods and pump motors. The third option assumes that the reactor core power and primary and intermediate system flow rates are ideally reduced linearly in a programmed fashion that instantaneously matches the prescribed load demand. The calculated behavior of this idealized case reveals a number of difficulties because the control strategy for the S-CO{sub 2} cycle overcools the reactor potentially resulting in the calculation of sodium bulk freezing and the onset of sodium boiling. The results show that autonomous SFR operation may be viable for the particular assumed load change transient and deserves further investigation for other transients and postulated accidents.

  18. Impact of Fission Products Impurity on the Plutonium Content of Metal- and Oxide- Fuels in Sodium Cooled Fast Reactors

    SciTech Connect (OSTI)

    Hikaru Hiruta; Gilles Youinou

    2013-09-01T23:59:59.000Z

    This short report presents the neutronic analysis to evaluate the impact of fission product impurity on the Pu content of Sodium-cooled Fast Reactor (SFR) metal- and oxide- fuel fabrication. The similar work has been previously done for PWR MOX fuel [1]. The analysis will be performed based on the assumption that the separation of the fission products (FP) during the reprocessing of UOX spent nuclear fuel assemblies is not perfect and that, consequently, a certain amount of FP goes into the Pu stream used to fabricate SFR fuels. Only non-gaseous FPs have been considered (see the list of 176 isotopes considered in the calculations in Appendix 1 of Reference 1). Throughout of this report, we define the mixture of Pu and FPs as PuFP. The main objective of this analysis is to quantify the increase of the Pu content of SFR fuels necessary to maintain the same average burnup at discharge independently of the amount of FP in the Pu stream, i.e. independently of the PuFP composition. The FP losses are considered element-independent, i.e., for example, 1% of FP losses mean that 1% of all non-gaseous FP leak into the Pu stream.

  19. Ionic strength dependence of the oxidation of SO2 by H2O2 in sodium chloride particles

    SciTech Connect (OSTI)

    Ali, Hashim M.; Iedema, Martin J.; Yu, Xiao-Ying; Cowin, James P.

    2014-06-20T23:59:59.000Z

    The reaction of sulfur dioxide and hydrogen peroxide in the presence of deliquesced (>75% RH) sodium particles was studied by utilizing a crossflow-mini reactor. The reaction kinetics was followed by observing chloride depletion in particles by computer-controlled scanning electron microscope with energy dispersive X-ray analysis, namely SEM/EDX. The reactions take place in concentrated mixed salt brine aerosols, for which no complete kinetic equilibrium data previously existed. We measured the Henry’s law solubility of H2O2 to close that gap. We also calculated the reaction rate as the particle transforms continuously from concentrated NaCl brine to eventually a mixed NaHSO4 plus H2SO4 brine solution. The reaction rate of the SO2 oxidation by H2O2 was found to be influenced by the change in ionic strength as the particle undergoes compositional transformation, following closely the dependence of the third order rate constant on ionic strength as predicted rates using previously established rate equations. This is the first study that has measured the ionic strength dependence of sulfate formation (in non-aqueous media) from oxidation of mixed salt brine aerosols in the presence of H2O2. It also gives the first report of the Henry’s law constant of H2O2 dependence on ionic strength.

  20. SN 2011A: an low-luminosity interacting transient, with a double plateau and strong sodium absorption

    E-Print Network [OSTI]

    de Jaeger, T; Pignata, G; Hamuy, M; Kankare, E; Stritzinger, M D; Benetti, S; Bufano, F; Elias-Rosa, N; Folatelli, G; Förster, F; González-Gaitán, S; Gutiérrez, C P; Inserra, C; Kotak, R; Lira, P; Morrell, N; Taddia, F; Tomasella, L

    2015-01-01T23:59:59.000Z

    We present optical photometry and spectroscopy of the optical transient SN 2011A. Our data spans 140 days after discovery including $BVRIu'g'r'i'z'$ photometry and 11 epochs of optical spectroscopy. Originally classified as a type IIn supernova (SN IIn) due to the presence of narrow H$\\alpha$ emission, this object shows exceptional characteristics. Firstly, the light curve shows a double plateau; a property only observed before in the impostor SN 1997bs. Secondly, SN 2011A has a very low luminosity ($M_{V}=-15.72$), placing it between normal luminous SNe IIn and SN impostors. Thirdly, SN 2011A shows low velocity and high equivalent width absorption close to the sodium doublet, which increases with time and is most likely of circumstellar origin. This evolution is also accompanied by a change of line profile; when the absorption becomes stronger, a P-Cygni profile appears. We discuss SN 2011A in the context of interacting SNe IIn and SN impostors, which appears to confirm the uniqueness of this transient. Whil...

  1. D10 experiment: coolability of UO/sub 2/ debris in sodium with downward heat removal. [LMFBR

    SciTech Connect (OSTI)

    Mitchell, G.W.; Ottinger, C.A.; Meister, H.

    1984-12-01T23:59:59.000Z

    The LMFBR Debris Coolability Program at Sandia National Laboratories investigates the coolability of particle beds which may form following a severe accident involving core disassembly in a nuclear reactor. The D series experiments utilize fission heating of fully enriched UO/sub 2/ particles submerged in sodium to realistically simulate decay heating. The D10 experiment is the first in the series to study the effects of bottom cooling of the debris that could be provided in an actual accident condition by structural materials onto which the debris might settle. Additionally, the D10 experiment was designed to achieve maximum temperatures in the debris approaching the melting point of UO/sub 2/. The experiment was successfully operated for over 50 hours and investigated downward heat removal in a packed bed at specific powers of 0.16 to 0.58 W/g. Dryout in the debris was achieved at powers from 0.42 to 0.58 W/g. Channels were induced in the bed and channeled bed dryout was achieved at powers of 1.06 to 1.77 W/g. Maximum temperatures in excess of 2500/sup 0/C were attained.

  2. Baseline Flowsheet Generation for the Treatment and Disposal of Idaho National Engineering and Environmental Laboratory Sodium Bearing Waste

    SciTech Connect (OSTI)

    Barnes, C.M.; Lauerhass, L.; Olson, A.L.; Taylor, D.D.; Valentine, J.H.; Lockie, K.A. (DOE- ID)

    2002-01-16T23:59:59.000Z

    The High-Level Waste (HLW) Program at the Idaho National Engineering and Environmental Laboratory (INEEL) must implement technologies and processes to treat and qualify radioactive wastes located at the Idaho Nuclear Technology and Engineering Center (INTEC) for permanent disposal. This paper describes the approach and accomplishments to date for completing development of a baseline vitrification treatment flowsheet for sodium-bearing waste (SBW), including development of a relational database used to manage the associated process assumptions. A process baseline has been developed that includes process requirements, basis and assumptions, process flow diagrams, a process description, and a mass balance. In the absence of actual process or experimental results, mass and energy balance data for certain process steps are based on assumptions. Identification, documentation, validation, and overall management of the flowsheet assumptions are critical to ensuring an integrated, focused program. The INEEL HLW Program initially used a roadmapping methodology, developed through the INEEL Environmental Management Integration Program, to identify, document, and assess the uncertainty and risk associated with the SBW flowsheet process assumptions. However, the mass balance assumptions, process configuration and requirements should be accessible to all program participants. This need resulted in the creation of a relational database that provides formal documentation and tracking of the programmatic uncertainties related to the SBW flowsheet.

  3. Baseline Flowsheet Generation for the Treatment and Disposal of Idaho National Engineering and Environmental Laboratory Sodium Bearing Waste

    SciTech Connect (OSTI)

    Barnes, Charles Marshall; Lauerhass, Lance; Olson, Arlin Leland; Taylor, Dean Dalton; Valentine, James Henry; Lockie, Keith Andrew

    2002-02-01T23:59:59.000Z

    The High-Level Waste (HLW) Program at the Idaho National Engineering and Environmental Laboratory (INEEL) must implement technologies and processes to treat and qualify radioactive wastes located at the Idaho Nuclear Technology and Engineering Center (INTEC) for permanent disposal. This paper describes the approach and accomplishments to date for completing development of a baseline vitrification treatment flowsheet for sodium-bearing waste (SBW), including development of a relational database used to manage the associated process assumptions. A process baseline has been developed that includes process requirements, basis and assumptions, process flow diagrams, a process description, and a mass balance. In the absence of actual process or experimental results, mass and energy balance data for certain process steps are based on assumptions. Identification, documentation, validation, and overall management of the flowsheet assumptions are critical to ensuring an integrated, focused program. The INEEL HLW Program initially used a roadmapping methodology, developed through the INEEL Environmental Management Integration Program, to identify, document, and assess the uncertainty and risk associated with the SBW flowsheet process assumptions. However, the mass balance assumptions, process configuration and requirements should be accessible to all program participants. This need resulted in the creation of a relational database that provides formal documentation and tracking of the programmatic uncertainties related to the SBW flowsheet.

  4. Coolability of stratified UO/sub 2/ debris in sodium with downward heat removal: The D13 experiment

    SciTech Connect (OSTI)

    Ottinger, C.A.; Mitchell, G.W.; Reed, A.W.; Meister, H.

    1987-03-01T23:59:59.000Z

    The LMFBR Debris Coolability Program at Sandia National Laboratories investigates the coolability of particle beds that may form following a severe accident involving core disassembly in a nuclear reactor. The D series experiments utilize fission heating of fully enriched UO/sub 2/ particles submerged in sodium to realistically simulate decay heating. The D13 experiment is the first in the series to study the effects of bottom cooling of stratified debris, which could be provided in an actual accident condition by structural materials onto which the debris might settle. Additionally, the D13 experiment was designed to achieve maximum temperatures in the debris approaching the melting point of UO/sub 2/. The experiment was operated for over 40 hours and investigated downward heat removal at specific powers of 0.22 to 2.58 W/g. Channeled dryout in the debris was achieved at powers from 0.94 to 2.58 W/g. Maximum temperatures approaching 2700/sup 0/C were attained. Bottom heat removal was up to 750 kW/m/sup 2/ as compared to 450 kW/m/sup 2/ in the D10 experiment.

  5. X-ray Absorption Measurements on Nickel Cathode of Sodium-beta Alumina batteries: Fe-Ni-CI Chemical Associations

    SciTech Connect (OSTI)

    Bowden, Mark E.; Alvine, Kyle J.; Fulton, John L.; Lemmon, John P.; Lu, Xiaochuan; Webb-Robertson, Bobbie-Jo M.; Heald, Steve M.; Balasubramanian, Mahalingam; Mortensen, Devon R.; Seidler, Gerald T.; Hess, Nancy J.

    2014-02-01T23:59:59.000Z

    Sections of Na-Al-NiCl2 cathodes from sodium-beta alumina ZEBRA batteries have been characterized with X-ray fluorescence mapping, and XANES measurements to probe the microstructure, elemental correlation, and chemical speciation after voltage cycling. Cycling was performed under identical load conditions at either 240 or 280 °C operating temperature and subsequently quenched in either the charged or discharged state. X-ray fluorescence mapping and XANES measurements were made adjacent to the current collector and ?"-Al2O3 solid electrolyte interfaces to detect possible gradients in chemical properties across the cathode. An FeS additive, introduced during battery synthesis, was found to be present as either Fe metal or an Fe(II) chloride in all cathode samples. X-ray fluorescence mapping reveals an operating temperature and charge-state dependent spatial correlation between Fe, Ni, and Cl concentration. XANES measurements indicate that both Ni and Fe are chemically reactive and shift between metallic and chloride phases in the charged and discharged states, respectively. However the percentage of chemically active Ni and Fe is significantly less in the cell operated at lower temperature. Additionally, the cathode appeared chemically homogeneous at the scale of our X-ray measurements.

  6. Calcium H & K and sodium D absorption induced by the interstellar and circumgalactic media of the Milky Way

    E-Print Network [OSTI]

    Murga, Maria; Ménard, Brice; Lan, Ting-Wen

    2015-01-01T23:59:59.000Z

    We map out calcium II & sodium I absorption (Fraunhofer H, K & D lines) induced by both the interstellar medium and the circumgalactic medium of the Milky Way. Our measurements cover more than $9000$ deg$^2$ and make use of about $300,000$ extragalactic spectra from the Sloan Digital Sky Survey. We present absorption maps for these two species and then compare their distributions to those of neutral hydrogen and dust. We show that the abundance of Na I with respect to neutral hydrogen stays roughly constant in different environments, while that of Ca II decreases with hydrogen column density. Studying how these tracers vary as a function of velocity, we show that, on average, the N(Na I)/N(Ca II) ratio decreases at higher velocity with respect to the local standard of rest, similar to the local Routly-Spitzer effect but seen on Galactic scale. We show that it is likely caused by higher gas/dust density at lower velocity. Finally, we show that Galactic Ca II and Na I absorption needs to be taken into a...

  7. Influence of fat levels, nonmeat proteins, salt, sodium tripolyphosphate and temperature on the chemical, physical and sensory properties of frankfurter-type sausages

    E-Print Network [OSTI]

    Gilchrist, Caleb Llewellyn

    1987-01-01T23:59:59.000Z

    potential which is necessary for nerve impulses, muscle function and cellular utilization of many metabolic components Salt is the principle agent that aids in extraction of salt-soluble proteins and promotes protein swelling as well as and encapsulation...INFLUENCE OF FAT LEVELS, NONMEAT PROTEINS, SALT, SODIUM TRIPOLYPHOSPHATE AND TEMPERATURE ON THE CHEMICAL, PHYSICAL AND SENSORY PROPERTIES OF FRANKFURTER-TYPE SAUSAGES A Thesis by CALEB LLEWELLYN GILCHRIST Submitted to the Graduate College...

  8. ALUMINUM REMOVAL AND SODIUM HYDROXIDE REGENERATION FROM HANFORD TANK WASTE BY LITHIUM HYDROTALCITE PRECIPITATION SUMMARY OF PRIOR LAB-SCALE TESTING

    SciTech Connect (OSTI)

    SAMS TL; GUILLOT S

    2011-01-27T23:59:59.000Z

    Scoping laboratory scale tests were performed at the Chemical Engineering Department of the Georgia Institute of Technology (Georgia Tech), and the Hanford 222-S Laboratory, involving double-shell tank (DST) and single-shell tank (SST) Hanford waste simulants. These tests established the viability of the Lithium Hydrotalcite precipitation process as a solution to remove aluminum and recycle sodium hydroxide from the Hanford tank waste, and set the basis of a validation test campaign to demonstrate a Technology Readiness Level of 3.

  9. An experimental investigation of the effect of sodium chloride on talc solubility and complexing of aqueous magnesium in supercritical hydrothermal fluids 

    E-Print Network [OSTI]

    Grabman, Kenneth Bryan

    1989-01-01T23:59:59.000Z

    AN EXPERIMENTAL INVESTIGATION OF THE EFFECT OF SODIUM CHLORIDE ON TALC SOLUBILITY AND COMPLEXING OF AQUEOUS MAGNESIUM IN SUPERCRITICAL HYDROTHERMAL FLUIDS A Thesis by KENNETH BRYAN GRABMAN Submitted to the Office of Graduate Studies of Texas... MAGNESIUM IN SUPERCRITICAL HYDROTHERMAL FLUIDS A Thesis by KENNETH BRYAN GRABMAN Approved as to style and content by: ~A. Robert K. Popp (Ch of Commi ee) Andrew Haj sh, Jr. (Member) Brann J son (Me ) J Span (Head o Department) December 1989...

  10. Study of the reactivity of sodium compounds and Ca(OH){sub 2} towards SO{sub 2} and NO{sub x}

    SciTech Connect (OSTI)

    Mocke, K.; Stejskalova, K.; Bach, P. [J. Heyrovsky Institute of Physical Chemistry, Prague (Czechoslovakia)] [and others

    1995-06-01T23:59:59.000Z

    The J.Heyrovsky Institute of Physical Chemistry (IPC) has conducted a detailed basic research under contract to Solvay Company (Belgium) to examine the reactivity of solid substances towards acid gases (SO{sub 2},NO{sub x}) with the aim to find the best conditions for their efficient removal. The reactivity of different sodium compounds (sodium bicarbonate, active soda, sodium carbonate monohydrate, dense soda ash) and Ca(OH){sub 2} was examined in the reaction with sulphur dioxide in a broad range of experimental variables (temperature, gas composition). The reactivity of selected samples was investigated also in the reactions with gaseous mixtures containing SO{sub 2} and NO{sub x} in the dependence on temperature, SO{sub 2}/NO{sub x}, and NO/NO{sub 2} ratios and the hydrodynamic regime of the fixed bed flow reactor. Further, ESCA and SEM methods were used for the identification of solid reaction products and their evolution as a function of reaction parameters. It is shown that in the case of NaHCO{sub 3} precursor it is possible to achieve in average at least a 90 % SO{sub 2} and simultaneously an almost 50 % NO{sub x} removal. The results obtained are very promising with respect to the NaHCO{sub 3} utilization especially for the purification of waste gases from incinerators and power plants.

  11. DURABILITY TESTING OF FLUIDIZED BED STEAM REFORMER WASTE FORMS FOR SODIUM BEARING WASTE AT IDAHO NATIONAL LABORATORY

    SciTech Connect (OSTI)

    Crawford, C; Carol Jantzen, C

    2007-08-27T23:59:59.000Z

    Fluidized Bed Steam Reforming (FBSR) processing of Sodium Bearing Waste simulants was performed in December 2006 by THOR{sup sm} Treatment Technologies LLC (TTT) The testing was performed at the Hazen Research Inc. (HRI) pilot plant facilities in Golden, CO. FBSR products from these pilot tests on simulated waste representative of the SBW at the Idaho Nuclear Technology and Engineering Center (INTEC) were subsequently transferred to the Savannah River National Laboratory (SRNL) for characterization and leach testing. Four as-received Denitration and Mineralization Reformer (DMR) granular/powder samples and four High Temperature Filter (HTF) powder samples were received by SRNL. FBSR DMR samples had been taken from the ''active'' bed, while the HTF samples were the fines collected as carryover from the DMR. The process operated at high fluidizing velocities during the mineralization test such that nearly all of the product collected was from the HTF. Active bed samples were collected from the DMR to monitor bed particle size distribution. Characterization of these crystalline powder samples shows that they are primarily Al, Na and Si, with > 1 wt% Ca, Fe and K. The DMR samples contained less than 1 wt% carbon and the HTF samples ranged from 13 to 26 wt% carbon. X-ray diffraction analyses show that the DMR samples contained significant quantities of the Al{sub 2}O{sub 3} startup bed. The DMR samples became progressively lower in starting bed alumina with major Na/Al/Si crystalline phases (nepheline and sodium aluminosilicate) present as cumulative bed turnover occurred but 100% bed turnover was not achieved. The HTF samples also contained these major crystalline phases. Durability testing of the DMR and HTF samples using the ASTM C1285 Product Consistency Test (PCT) 7-day leach test at 90 C was performed along with several reference glass samples. Comparison of the normalized leach rates for the various DMR and HTF components was made with the reference glasses and the Low Activity Waste (LAW) specification for the Hanford Waste Treatment and Vitrification Plant (WTP). Normalized releases from the DMR and HTF samples were all less than 1 g/m{sup 2}. For comparison, normalized release from the High-Level Waste (HLW) benchmark Environmental Assessment (EA) glass for Si, Li, Na and B ranges from 2 to 8 g/m{sup 2}. The normalized release specification for LAW glass for the Hanford WTP is 2 g/m{sup 2}. The Toxicity Characteristic Leach Test (TCLP) was performed on DMR and HTF as received samples and the tests showed that these products meet the criteria for the EPA RCRA Universal Treatment Standards for all of the constituents contained in the starting simulants such as Cr, Pb and Hg (RCRA characteristically hazardous metals) and Ni and Zn (RCRA metals required for listed wastes).

  12. A High Temperature (400 to 650oC) Secondary Storage Battery Based on Liquid Sodium and Potassium Anodes

    SciTech Connect (OSTI)

    Tao, Greg; Weber, Neill

    2007-06-08T23:59:59.000Z

    This STTR Phase I research program was on the development of high temperature (400 to 650 C), secondary batteries with roundtrip efficiency > 90% for integration with a 3 to 10 kW solid oxide fuel cell (SOFC) system. In fulfillment of this objective, advanced planar high temperature rechargeable batteries, comprised of an alkali metal ion conducting, highly refractory, beta'' alumina solid electrolyte (BASE) sandwiched between liquid sodium (or potassium) anode and liquid metal salt cathode, were developed at MSRI. The batteries have been successfully demonstrated at a working temperature as high as 600 C. To our knowledge, so far no work has been reported in the literature on planar rechargeable batteries based on BASE, and results obtained in Phase I for the very first time demonstrated the viability of planar batteries, though relatively low temperature tubular-based sodium-sulfur batteries and ZEBRA batteries have been actively developed by very limited non U.S. companies. The results of this Phase I work have fulfilled all the goals and stated objectives, and the achievements showed much promise for further, substantial improvements in battery design and performance. The important results of Phase I are briefly described in what follows: (1) Both Na-BASE and K-BASE discs and tubes have been successfully fabricated using MSRI's patented vapor phase process. Ionic conductivity measurements showed that Na-BASE had higher ionic conductivity than K-BASE, consistence with the literature. At 500 C, Na-BASE conductivity is 0.36 S/cm, which is more than 20 times higher than 8YSZ electrolyte used for SOFC at 800 C. The activation energy is 22.58 kJ/mol. (2) CuCl{sub 2}, FeCl{sub 2}, ZnCl{sub 2}, and AgCl were identified as suitable salts for Na/metal salt or K/metal salt electrochemical couples based on thermochemical data. Further open circuit voltage measurements matched those deduced from the thermochemical data. (3) Tubular cells with CuCl{sub 2} as the cathode and Na as the anode were constructed. However, it was discovered that CuCl{sub 2} was somewhat corrosive and dissolved iron, an element of the cathode compartment. Since protective coating technology was beyond this Phase I work scope, no further work on the CuCl{sub 2} cathode was pursued in Phase I. Notwithstanding, due to its very high OCV and high specific energy, CuCl{sub 2} cathode is a very attractive possibility for a battery capable of delivering higher specific energy with higher voltage. Further investigation of the Na-CuCl{sub 2} battery can be done by using suitable metal coating technologies developed at MSRI for high temperature applications. (4) In Phase I, FeCl{sub 2} and ZnCl{sub 2} were finalized as the potential cathodes for Na-metal salt batteries for delivering high specific energies. Planar Na-FeCl{sub 2} and Na-ZnCl{sub 2} cells were designed, constructed, and tested between 350 and 600 C. Investigation of charge/discharge characteristics showed they were the most promising batteries. Charge/discharge cycles were performed as many as 27 times, and charge/discharge current was as high as 500 mA. No failure was detected after 50 hours testing. (5) Three-cell planar stacks were designed, constructed, and evaluated. Preliminary tests showed further investigation was needed for optimization. (6) Freeze-thaw survival was remarkably good for planar BASE discs fabricated by MSRI's patented vapor phase process.

  13. Work Domain Analysis of a Predecessor Sodium-cooled Reactor as Baseline for AdvSMR Operational Concepts

    SciTech Connect (OSTI)

    Ronald Farris; David Gertman; Jacques Hugo

    2014-03-01T23:59:59.000Z

    This report presents the results of the Work Domain Analysis for the Experimental Breeder Reactor (EBR-II). This is part of the phase of the research designed to incorporate Cognitive Work Analysis in the development of a framework for the formalization of an Operational Concept (OpsCon) for Advanced Small Modular Reactors (AdvSMRs). For a new AdvSMR design, information obtained through Cognitive Work Analysis, combined with human performance criteria, can and should be used in during the operational phase of a plant to assess the crew performance aspects associated with identified AdvSMR operational concepts. The main objective of this phase was to develop an analytical and descriptive framework that will help systems and human factors engineers to understand the design and operational requirements of the emerging generation of small, advanced, multi-modular reactors. Using EBR-II as a predecessor to emerging sodium-cooled reactor designs required the application of a method suitable to the structured and systematic analysis of the plant to assist in identifying key features of the work associated with it and to clarify the operational and other constraints. The analysis included the identification and description of operating scenarios that were considered characteristic of this type of nuclear power plant. This is an invaluable aspect of Operational Concept development since it typically reveals aspects of future plant configurations that will have an impact on operations. These include, for example, the effect of core design, different coolants, reactor-to-power conversion unit ratios, modular plant layout, modular versus central control rooms, plant siting, and many more. Multi-modular plants in particular are expected to have a significant impact on overall OpsCon in general, and human performance in particular. To support unconventional modes of operation, the modern control room of a multi-module plant would typically require advanced HSIs that would provide sophisticated operational information visualization, coupled with adaptive automation schemes and operator support systems to reduce complexity. These all have to be mapped at some point to human performance requirements. The EBR-II results will be used as a baseline that will be extrapolated in the extended Cognitive Work Analysis phase to the analysis of a selected advanced sodium-cooled SMR design as a way to establish non-conventional operational concepts. The Work Domain Analysis results achieved during this phase have not only established an organizing and analytical framework for describing existing sociotechnical systems, but have also indicated that the method is particularly suited to the analysis of prospective and immature designs. The results of the EBR-II Work Domain Analysis have indicated that the methodology is scientifically sound and generalizable to any operating environment.

  14. SOLIDIFICATION OF THE HANFORD LAW WASTE STREAM PRODUCED AS A RESULT OF NEAR-TANK CONTINUOUS SLUDGE LEACHING AND SODIUM HYDROXIDE RECOVERY

    SciTech Connect (OSTI)

    Reigel, M.; Johnson, F.; Crawford, C.; Jantzen, C.

    2011-09-20T23:59:59.000Z

    The U.S. Department of Energy (DOE), Office of River Protection (ORP), is responsible for the remediation and stabilization of the Hanford Site tank farms, including 53 million gallons of highly radioactive mixed wasted waste contained in 177 underground tanks. The plan calls for all waste retrieved from the tanks to be transferred to the Waste Treatment Plant (WTP). The WTP will consist of three primary facilities including pretreatment facilities for Low Activity Waste (LAW) to remove aluminum, chromium and other solids and radioisotopes that are undesirable in the High Level Waste (HLW) stream. Removal of aluminum from HLW sludge can be accomplished through continuous sludge leaching of the aluminum from the HLW sludge as sodium aluminate; however, this process will introduce a significant amount of sodium hydroxide into the waste stream and consequently will increase the volume of waste to be dispositioned. A sodium recovery process is needed to remove the sodium hydroxide and recycle it back to the aluminum dissolution process. The resulting LAW waste stream has a high concentration of aluminum and sodium and will require alternative immobilization methods. Five waste forms were evaluated for immobilization of LAW at Hanford after the sodium recovery process. The waste forms considered for these two waste streams include low temperature processes (Saltstone/Cast stone and geopolymers), intermediate temperature processes (steam reforming and phosphate glasses) and high temperature processes (vitrification). These immobilization methods and the waste forms produced were evaluated for (1) compliance with the Performance Assessment (PA) requirements for disposal at the IDF, (2) waste form volume (waste loading), and (3) compatibility with the tank farms and systems. The iron phosphate glasses tested using the product consistency test had normalized release rates lower than the waste form requirements although the CCC glasses had higher release rates than the quenched glasses. However, the waste form failed to meet the vapor hydration test criteria listed in the WTP contract. In addition, the waste loading in the phosphate glasses were not as high as other candidate waste forms. Vitrification of HLW waste as borosilicate glass is a proven process; however the HLW and LAW streams at Hanford can vary significantly from waste currently being immobilized. The ccc glasses show lower release rates for B and Na than the quenched glasses and all glasses meet the acceptance criterion of < 4 g/L. Glass samples spiked with Re{sub 2}O{sub 7} also passed the PCT test. However, further vapor hydration testing must be performed since all the samples cracked and the test could not be performed. The waste loading of the iron phosphate and borosilicate glasses are approximately 20 and 25% respectively. The steam reforming process produced the predicted waste form for both the high and low aluminate waste streams. The predicted waste loadings for the monolithic samples is approximately 39%, which is higher than the glass waste forms; however, at the time of this report, no monolithic samples were made and therefore compliance with the PA cannot be determined. The waste loading in the geopolymer is approximately 40% but can vary with the sodium hydroxide content in the waste stream. Initial geopolymer mixes revealed compressive strengths that are greater than 500 psi for the low aluminate mixes and less than 500 psi for the high aluminate mixes. Further work testing needs to be performed to formulate a geopolymer waste form made using a high aluminate salt solution. A cementitious waste form has the advantage that the process is performed at ambient conditions and is a proven process currently in use for LAW disposal. The Saltstone/Cast Stone formulated using low and high aluminate salt solutions retained at least 97% of the Re that was added to the mix as a dopant. While this data is promising, additional leaching testing must be performed to show compliance with the PA. Compressive strength tests must also be performed on the Cast Ston

  15. The potential reproductive, neurobehavioral and systemic effects of soluble sodium tungstate exposure in Sprague-Dawley rats

    SciTech Connect (OSTI)

    McInturf, S.M. [Naval Medical Research Unit at Dayton (NAMRU), Wright Patterson Air Force Base, OH (United States); Bekkedal, M.Y.V. [Two Steps Forward, LLC, Sun Prairie, WI (United States); Wilfong, E. [U.S. Naval Academy, 572M Holloway Road, Annapolis, MD (United States); Arfsten, D. [Navy Drug Screening Laboratory P.O. Box 113, Naval Air Station Jacksonville, FL (United States); Chapman, G. [Naval Medical Research Unit at Dayton (NAMRU), Wright Patterson Air Force Base, OH (United States); Gunasekar, P.G., E-mail: palur.gunasekar@wpafb.af.mil [Naval Medical Research Unit at Dayton (NAMRU), Wright Patterson Air Force Base, OH (United States)

    2011-07-15T23:59:59.000Z

    The debate on tungsten (W) is fostered by its continuous usage in military munitions. Reports demonstrate W solubilizes in soil and can migrate into drinking water supplies and, therefore, is a potential health risk to humans. This study evaluated the reproductive, systemic and neurobehavioral effects of sodium tungstate (NaW) in rats following 70 days of daily pre-and postnatal exposure via oral gavage to 5, 62.5 and 125 mg/kg/day of NaW through mating, gestation and weaning (PND 0-20). Daily administration of NaW produced no overt evidence of toxicity and had no apparent effect on mating success or offspring physical development. Distress vocalizations were elevated in F{sub 1} offspring from the high dose group, whereas righting reflex showed unexpected sex differences where males demonstrated faster righting than females; however, the effects were not dose-dependent. Locomotor activity was affected in both low and high-dose groups of F{sub 1} females. Low-dose group showed increased distance traveled, more time in ambulatory movements and less time in stereotypic behavior than controls or high dose animals. The high-dose group had more time in stereotypical movements than controls, and less time resting than controls and the lowest exposure group. Maternal retrieval was not affected by NaW exposure. Tungsten analysis showed a systemic distribution of NaW in both parents and offspring, with preferential uptake within the immune organs, including the femur, spleen and thymus. Histopathological evidence suggested no severe chronic injury or loss of function in these organs. However, the heart showed histological lesions, histiocytic inflammation from minimal to mild with cardiomyocyte degeneration and necrosis in several P{sub 0} animals of 125 mg NaW dose group. The result of this study suggests that pre and postnatal exposure to NaW may produce subtle neurobehavioral effects in offspring related to motor activity and emotionality.

  16. Quantification of Kinetic Rate Law Parameters of Uranium Release from Sodium Autunite as a Function of Aqueous Bicarbonate Concentrations

    SciTech Connect (OSTI)

    Gudavalli, Ravi; Katsenovich, Yelena; Wellman, Dawn M.; Lagos, Leonel; Tansel, Berrin

    2013-09-05T23:59:59.000Z

    ABSTRACT: Hydrogen carbonate is one of the most significant components within the uranium geochemical cycle. In aqueous solutions, hydrogen carbonate forms strong complexes with uranium. As such, aqueous bicarbonate may significantly increase the rate of uranium release from uranium minerals. Quantifying the relationship of aqueous hydrogen carbonate solutions to the rate of uranium release during dissolution is critical to understanding the long-term fate of uranium within the environment. Single-pass flow-through (SPTF) experiments were conducted to estimate the rate of uranium release from Na meta-autunite as a function of bicarbonate solutions (0.0005-0.003 M) under the pH range of 6-11 and temperatures of 5-60oC. Consistent with the results of previous investigation, the rate of uranium release from sodium autunite exhibited minimal dependency on temperature; but were strongly dependent on pH and increasing concentrations of bicarbonate solutions. Most notably at pH 7, the rate of uranium release exhibited 370 fold increases relative to the rate of uranium release in the absence of bicarbonate. However, the effect of increasing concentrations of bicarbonate solutions on the release of uranium was significantly less under higher pH conditions. It is postulated that at high pH values, surface sites are saturated with carbonate, thus the addition of more bicarbonate would have less effect on uranium release. Results indicate the activation energies were unaffected by temperature and bicarbonate concentration variations, but were strongly dependent on pH conditions. As pH increased from 6 to 11, activation energy values were observed to decrease from 29.94 kJ mol-1 to 13.07 kJ mol-1. The calculated activation energies suggest a surface controlled dissolution mechanism.

  17. Investigation of alternative layouts for the supercritical carbon dioxide Brayton cycle for a sodium-cooled fast reactor.

    SciTech Connect (OSTI)

    Moisseytsev, A.; Sienicki, J. J. (Nuclear Engineering Division)

    2009-07-01T23:59:59.000Z

    Analyses of supercritical carbon dioxide (S-CO{sub 2}) Brayton cycle performance have largely settled on the recompression supercritical cycle (or Feher cycle) incorporating a flow split between the main compressor downstream of heat rejection, a recompressing compressor providing direct compression without heat rejection, and high and low temperature recuperators to raise the effectiveness of recuperation and the cycle efficiency. Alternative cycle layouts have been previously examined by Angelino (Politecnico, Milan), by MIT (Dostal, Hejzlar, and Driscoll), and possibly others but not for sodium-cooled fast reactors (SFRs) operating at relatively low core outlet temperature. Thus, the present authors could not be sure that the recompression cycle is an optimal arrangement for application to the SFR. To ensure that an advantageous alternative layout has not been overlooked, several alternative cycle layouts have been investigated for a S-CO{sub 2} Brayton cycle coupled to the Advanced Burner Test Reactor (ABTR) SFR preconceptual design having a 510 C core outlet temperature and a 470 C turbine inlet temperature to determine if they provide any benefit in cycle performance (e.g., enhanced cycle efficiency). No such benefits were identified, consistent with the previous examinations, such that attention was devoted to optimizing the recompression supercritical cycle. The effects of optimizing the cycle minimum temperature and pressure are investigated including minimum temperatures and/or pressures below the critical values. It is found that improvements in the cycle efficiency of 1% or greater relative to previous analyses which arbitrarily fixed the minimum temperature and pressure can be realized through an optimal choice of the combination of the minimum cycle temperature and pressure (e.g., for a fixed minimum temperature there is an optimal minimum pressure). However, this leads to a requirement for a larger cooler for heat rejection which may impact the tradeoff between efficiency and capital cost. In addition, for minimum temperatures below the critical temperature, a lower heat sink temperature is required the availability of which is dependent upon the climate at the specific plant site.

  18. Integrated dry NO{sub x}/SO{sub 2} emissions control system sodium-based dry sorbent injection test report. Test period: August 4, 1993--July 29, 1995

    SciTech Connect (OSTI)

    Smith, R.A.; Shimoto, G.H.; Muzio, L.J. [Fossil Energy Research Corp., Laguna Hills, CA (United States)] [Fossil Energy Research Corp., Laguna Hills, CA (United States); Hunt, T. [Public Service Co. of Colorado, Denver, CO (United States)] [Public Service Co. of Colorado, Denver, CO (United States)

    1997-04-01T23:59:59.000Z

    The project goal is to demonstrate up to 70% reductions in NOx and SO{sub 2} emissions through the integration of: (1) down-fired low-NOx burners with overfire air; (2) Selective Non-Catalytic Reduction (SNCR) for additional NOx removal; and (3) dry sorbent injection and duct humidification for SO{sub 2} removal. This report documents the sixth phase of the test program, where the performance of dry sorbent injection with sodium compounds was evaluated as a SO{sub 2} removal technique. Dry sorbent injection was performed in-duct downstream of the air heater (ahead of the fabric filter), as well as at a higher temperature location between the economizer and air heater. Two sodium compounds were evaluated during this phase of testing: sodium sesquicarbonate and sodium bicarbonate. In-duct sodium injection with low levels of humidification was also investigated. This sixth test phase was primarily focused on a parametric investigation of sorbent type and feed rate, although boiler load and sorbent preparation parameters were also varied.

  19. Bulk measurement of copper and sodium content in CuIn(0.7)Ga(0.3)Se(2) (CIGS) solar cells with nanosecond pulse length laser induced breakdown spectroscopy (LIBS)

    E-Print Network [OSTI]

    Kowalczyk, Jeremy M D; DeAngelis, Alexander; Kaneshiro, Jess; Mallory, Stewart A; Chang, Yuancheng; Gaillard, Nicolas

    2013-01-01T23:59:59.000Z

    In this work, we show that laser induced breakdown spectroscopy (LIBS) with a nanosecond pulse laser can be used to measure the copper and sodium content of CuIn(0.7)Ga(0.3)Se(2) (CIGS) thin film solar cells on molybdenum. This method has four significant advantages over methods currently being employed: the method is inexpensive, measurements can be taken in times on the order of one second, without high vacuum, and at distances up to 5 meters or more. The final two points allow for in-line monitoring of device fabrication in laboratory or industrial environments. Specifically, we report a linear relationship between the copper and sodium spectral lines from LIBS and the atomic fraction of copper and sodium measured via secondary ion mass spectroscopy (SIMS), discuss the ablation process of this material with a nanosecond pulse laser compared to shorter pulse duration lasers, and examine the depth resolution of nanosecond pulse LIBS.

  20. SaltRx HT -Scoring Sheet A1. 0.1 M Bis-Tris Propane pH 7.0, 1.8 M Sodium Acetate pH 7.0

    E-Print Network [OSTI]

    Hill, Chris

    SaltRx HT - Scoring Sheet A1. 0.1 M Bis-Tris Propane pH 7.0, 1.8 M Sodium Acetate pH 7.0 A2. 0.1 M Bis-Tris Propane pH 7.0, 2.8 M Sodium Acetate pH 7.0 A3. 0.1 M Sodium Acetate pH 4.6, 1.5 M Ammonium Chloride A4. 0.1 M Bis-Tris Propane pH 7.0, 1.5 M Ammonium Chloride A5. 0.1 M Tris pH 8.5, 1.5 M Ammonium

  1. Radical-anions of aromatic compounds. VII. Reaction of the products from the reduction of nitrobenzene by sodium with isopropyl and tert-butyl iodides

    SciTech Connect (OSTI)

    Danilova, N.K.; Shteingarts, V.D.

    1986-09-20T23:59:59.000Z

    The reaction of the products from the reduction of nitrobenzene by one and two equivalents of sodium with isopropyl iodide leads to the formation of N,O-diisopropylphenylhydroxylamine, while the reaction with tert-butyl iodide leads to p-(tert-butyl)nitrobenzene. Such a change in the nature of the reaction product in the transition from the primary and secondary alkyl halides to the tertiary alkyl halides clearly results from a change in the S/sub N/2 mechanism to the S/sub RN/1 mechanism, involving transfer of an electron from the radical-anion or dianion of nitrobenzene to the alkyl halide. The formation of considerable amounts of azoxybenzene in the reaction with tert-butyl iodide shows that the dianion and, to a lesser degree, the radical-anion of nitrobenzene exhibit basic characteristics.

  2. A domain-specific analysis system for examining nuclear reactor simulation data for light-water and sodium-cooled fast reactors

    E-Print Network [OSTI]

    Billings, Jay Jay; Hull, S Forest; Lingerfelt, Eric J; Wojtowicz, Anna

    2014-01-01T23:59:59.000Z

    Building a new generation of fission reactors in the United States presents many technical and regulatory challenges. One important challenge is the need to share and present results from new high-fidelity, high-performance simulations in an easily usable way. Since modern multiscale, multi-physics simulations can generate petabytes of data, they will require the development of new techniques and methods to reduce the data to familiar quantities of interest (e.g., pin powers, temperatures) with a more reasonable resolution and size. Furthermore, some of the results from these simulations may be new quantities for which visualization and analysis techniques are not immediately available in the community and need to be developed. This paper describes a new system for managing high-performance simulation results in a domain-specific way that naturally exposes quantities of interest for light water and sodium-cooled fast reactors. It describes requirements to build such a system and the technical challenges faced...

  3. Evaluation on double-wall-tube residual stress distribution of sodium-heated steam generator by neutron diffraction and numerical analysis

    SciTech Connect (OSTI)

    Kisohara, N. [Advanced Nuclear System Research and Development Directorate, Japan Atomic Energy Agency (Japan); Suzuki, H.; Akita, K. [Quantum Beam Science Directorate, Japan Atomic Energy Agency (Japan); Kasahara, N. [Dept. of Nuclear Engineering and Management, Univ. of Tokyo (Japan)

    2012-07-01T23:59:59.000Z

    A double-wall-tube is nominated for the steam generator heat transfer tube of future sodium fast reactors (SFRs) in Japan, to decrease the possibility of sodium/water reaction. The double-wall-tube consists of an inner tube and an outer tube, and they are mechanically contacted to keep the heat transfer of the interface between the inner and outer tubes by their residual stress. During long term SG operation, the contact stress at the interface gradually falls down due to stress relaxation. This phenomenon might increase the thermal resistance of the interface and degrade the tube heat transfer performance. The contact stress relaxation can be predicted by numerical analysis, and the analysis requires the data of the initial residual stress distributions in the tubes. However, unclear initial residual stress distributions prevent precious relaxation evaluation. In order to resolve this issue, a neutron diffraction method was employed to reveal the tri-axial (radius, hoop and longitudinal) initial residual stress distributions in the double-wall-tube. Strain gauges also were used to evaluate the contact stress. The measurement results were analyzed using a JAEA's structural computer code to determine the initial residual stress distributions. Based on the stress distributions, the structural computer code has predicted the transition of the relaxation and the decrease of the contact stress. The radial and longitudinal temperature distributions in the tubes were input to the structural analysis model. Since the radial thermal expansion difference between the inner (colder) and outer (hotter) tube reduces the contact stress and the tube inside steam pressure contributes to increasing it, the analytical model also took these effects into consideration. It has been conduced that the inner and outer tubes are contacted with sufficient stresses during the plant life time, and that effective heat transfer degradation dose not occur in the double-wall-tube SG. (authors)

  4. A novel, single-isomer, sulfated cyclodextrin for use as a chiral resolving agent in capillary electrophoresis: the sodium salt of octakis(2,3-di-O-methyl-6-O-sulfo)-?-cyclodextrin

    E-Print Network [OSTI]

    Busby, Michael Brent

    2002-01-01T23:59:59.000Z

    A novel, single-isomer, sulfated cyclodextrin, the sodium salt of octakis(2,3-di-O-methyl-6-O-sulfo)cyclomaltooctaose (ODMS) was used as a chiral resolving agent in both aqueous and non-aqueous chiral mediated electrophoretic separation of a large...

  5. The use of zirconium hydride blankets in a minor actinide/thorium burner sodium-cooled reactor for void coefficient control with particular reference to UK's plutonium disposition problem

    E-Print Network [OSTI]

    Arias, Francisco J.; Parks, Geoffrey T.

    2015-04-21T23:59:59.000Z

    The use of zirconium hydride (Th–ZrH1.6) blankets in a thorium-fuelled sodium-cooled reactor for void reactivity control with particular reference to UK's plutonium disposition problem is proposed and considered. It is shown that, with the use...

  6. The Effect of Processing Parameters on the Thermoelectric Properties of Magnesium Silicide

    E-Print Network [OSTI]

    Fong, Anthony

    2012-01-01T23:59:59.000Z

    W. Engelmann. J. C. A. Peltier, “Nouvelles expériences surmaterials: the Seebeck, Peltier, and Thomson effects. Theof thermoelectrics is called the Peltier effect named after

  7. The Effect of Processing Parameters on the Thermoelectric Properties of Magnesium Silicide

    E-Print Network [OSTI]

    Fong, Anthony

    2012-01-01T23:59:59.000Z

    no. 12, p. 5119, 2004. T. M. Tritt, “Electrical and Thermal23–20. J. Martin, T. Tritt, and C. Uher, “High temperatureis fairly straightforward. Tritt describes a setup in which

  8. Systematic study of LPCVD refractory metal/silicide interconnect materials for very large scale integrated circuits

    SciTech Connect (OSTI)

    Nowrozi, M.F.

    1988-01-01T23:59:59.000Z

    Recently, refractory materials have been proposed as a strong alternative to poly-silicon and aluminum alloys as metallization systems for Very Large Scale Integrated (VLSI) circuits because of their improved performance at smaller Integrated Circuit (IC) feature size and higher interconnect current densities. However, processing and reliability problems associated with the use of refractory materials have limited their widespread acceptance. The hot-wall low-pressure chemical vapor deposition (LPCVD) of Mo and W from their respective hexacarbonyl sources has been studied as a potential remedy to such problems, in addition to providing the potential for higher throughput and better step coverage. Using deposition chemistries based on carbonyl sources, Mo and W deposits were characterized with respect to their electrical, mechanical, structural, and chemical properties as well as their compatibility with conventional IC processing. Excellent film step coverage and uniformity were obtained by low-temperature (300-350 C) deposition at pressures of 400-600 mTorr. As-deposited films were observed to be amorphous, with a resistivity of 250 and 350 microohm-cm for Mo and W, respectively.

  9. Unique composition niobium-silicide alloy, plasma melted for the Air Force as part of

    E-Print Network [OSTI]

    and laser beam welding (both continuous wave and pulsed), precision arc welding, brazing, plasma spraying synthesis and colloidal processing; laser and microwave processing; process modeling; and microstructural

  10. Progress on Searching Optimal Thermal Spray Parameters for Magnesium Silicide Gaosheng Fu1

    E-Print Network [OSTI]

    Zuo, Lei

    ] and Tani[8] used spark plasma sintering and got maximum ZT of 0.86 at 862K with Bi doped Mg2Si] and Tamura et al. [10]. Melt- spinning followed by spark plasma synthesis (SPS) or hot pressing has been used coatings prepared by Atmospheric Plasma Spray (APS), and Vacuum Plasma Spray (VPS) are presented. Seebeck

  11. Combined SO sub 2 /NO sub x control using ferrouster dot EDTA and a secondary additive in a lime-based aqueous scrubber system. [Sodium ascorbate

    SciTech Connect (OSTI)

    Mendelsohn, M.H.; Livengood, C.D.; Harkness, J.B.L.

    1991-01-01T23:59:59.000Z

    Integration of NO{sub x} control into existing flue-gas desulfurization (FGD) systems addresses site-specific control requirements while minimizing retrofit difficulties. Argonne has studied the use of the metal-chelate additives, such as ferrous{center dot}EDTA in various wet FGD chemistries, to promote combined SO{sub 2}/NO{sub x} scrubbing. A major process problem is oxidation of the iron to the ferric species, leading to a significant decrease in NO{sub x}-removal capability. Argonne discovered a class of organic compounds that, when used with ferrous{center dot}EDTA in a sodium carbonate chemistry, could maintain high levels of NO{sub x} removal. However, those antioxidant/reducing agents are not effective in a lime-based chemistry, and a broader investigation of antioxidants was initiated. This paper discusses results of that investigation, which found a practical antioxidant/reducing agent capable of maintaining NO{sub x} removals of about 50% (compared with about 15% without the agent) in a lime-based FGD chemistry with FE(II){center dot}EDTA. 5 refs., 10 figs.

  12. EVIDENCE FOR A MILD STEEPENING AND BOTTOM-HEAVY INITIAL MASS FUNCTION IN MASSIVE GALAXIES FROM SODIUM AND TITANIUM-OXIDE INDICATORS

    SciTech Connect (OSTI)

    Spiniello, C.; Trager, S. C.; Koopmans, L. V. E.; Chen, Y. P. [Kapteyn Institute, University of Groningen, P.O. Box 800, 9700 AV Groningen (Netherlands)

    2012-07-10T23:59:59.000Z

    We measure equivalent widths (EWs)-focusing on two unique features (NaI and TiO{sub 2}) of low-mass stars ({approx}< 0.3 M{sub Sun })-for luminous red galaxy spectra from the Sloan Digital Sky Survey (SDSS) and X-Shooter Lens Survey (XLENS) in order to study the low-mass end of the initial mass function (IMF). We compare these EWs to those derived from simple stellar population models computed with different IMFs, ages, [{alpha}/Fe], and elemental abundances. We find that models are able to simultaneously reproduce the observed NaD {lambda}5895 and Na I {lambda}8190 features for lower-mass ({approx}{sigma}{sub *}) early-type galaxies (ETGs) but deviate increasingly for more massive ETGs, due to strongly mismatching NaD EWs. The TiO{sub 2} {lambda}6230 and the Na I {lambda}8190 features together appear to be a powerful IMF diagnostic, with age and metallicity effects orthogonal to the effect of IMF. We find that both features correlate strongly with galaxy velocity dispersion. The XLENS ETG (SDSS J0912+0029) and an SDSS ETG (SDSS J0041-0914) appear to require both an extreme dwarf-rich IMF and a high sodium enhancement ([Na/Fe] = +0.4). In addition, lensing constraints on the total mass of the XLENS system within its Einstein radius limit a bottom-heavy IMF with a power-law slope to x {<=} 3.0 at the 90% CL. We conclude that NaI and TiO features, in comparison with state-of-the-art simple stellar population models, suggest a mildly steepening IMF from Salpeter (dn/dm {proportional_to} m {sup -x} with x = 2.35) to x Almost-Equal-To 3.0 for ETGs in the range {sigma} = 200-335 km s{sup -1}.

  13. Environmental, health, and safety issues of sodium-sulfur batteries for electric and hybrid vehicles. Volume 2, Battery recycling and disposal

    SciTech Connect (OSTI)

    Corbus, D.

    1992-09-01T23:59:59.000Z

    Recycling and disposal of spent sodium-sulfur (Na/S) batteries are important issues that must be addressed as part of the commercialization process of Na/S battery-powered electric vehicles. The use of Na/S batteries in electric vehicles will result in significant environmental benefits, and the disposal of spent batteries should not detract from those benefits. In the United States, waste disposal is regulated under the Resource Conservation and Recovery Act (RCRA). Understanding these regulations will help in selecting recycling and disposal processes for Na/S batteries that are environmentally acceptable and cost effective. Treatment processes for spent Na/S battery wastes are in the beginning stages of development, so a final evaluation of the impact of RCRA regulations on these treatment processes is not possible. The objectives of tills report on battery recycling and disposal are as follows: Provide an overview of RCRA regulations and requirements as they apply to Na/S battery recycling and disposal so that battery developers can understand what is required of them to comply with these regulations; Analyze existing RCRA regulations for recycling and disposal and anticipated trends in these regulations and perform a preliminary regulatory analysis for potential battery disposal and recycling processes. This report assumes that long-term Na/S battery disposal processes will be capable of handling large quantities of spent batteries. The term disposal includes treatment processes that may incorporate recycling of battery constituents. The environmental regulations analyzed in this report are limited to US regulations. This report gives an overview of RCRA and discusses RCRA regulations governing Na/S battery disposal and a preliminary regulatory analysis for Na/S battery disposal.

  14. Internal-integral sodium return line for sodium heat engine

    DOE Patents [OSTI]

    Hunt, Thomas K. (Ann Arbor, MI)

    1985-01-01T23:59:59.000Z

    A thermoelectric generator device which converts heat energy to electrical energy. An alkali metal is used with a solid electrolyte and a portion of the return line for the alkali metal is located within the generator vacuum space.

  15. Thermophysical Properties of Sodium Nitrate and Sodium Chloride

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItem Not Found Item Not Found The item youThe Discovery ofTechnology used in

  16. Sodium heat engine electrical feedthrough

    DOE Patents [OSTI]

    Weber, Neill (Dearborn, MI)

    1985-01-01T23:59:59.000Z

    A thermoelectric generator device which converts heat energy to electrical energy. An alkali metal is used with a solid electrolyte and a hermetically sealed feedthrough structure.

  17. Sodium heat engine electrical feedthrough

    DOE Patents [OSTI]

    Weber, N.

    1985-03-19T23:59:59.000Z

    A thermoelectric generator device which converts heat energy to electrical energy is disclosed. An alkali metal is used with a solid electrolyte and a hermetically sealed feedthrough structure. 4 figs.

  18. Sodium Battery | GE Global Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del Sol HomeFacebookScholarship Fund3Biology| Nationalof EnergyMitch Soderberg!

  19. Solid State Nuclear Magnetic Resonance Investigation of Polymer Backbone Dynamics in Poly(Ethylene Oxide) Based Lithium and Sodium Polyether-ester-sulfonate Ionomers

    SciTech Connect (OSTI)

    Roach, David J. [Penn State Univ., State College, PA (United States). Dept. of Chemistry; Dou, Shichen [Penn State Univ., State College, PA (United States). Dept. of Materials Science and Engineering; Colby, Ralph H. [Penn State Univ., State College, PA (United States). Dept. of Materials Science and Engineering; Mueller, Karl T. [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Penn State Univ., State College, PA (United States). Dept. of Chemistry

    2013-05-21T23:59:59.000Z

    Polymer backbone dynamics of single ion conducting poly(ethylene oxide) (PEO)-based ionomer samples with low glass transition temperatures (Tg) have been investigated using solid-state nuclear magnetic resonance (NMR). Experiments detecting 13C with 1H decoupling under magic angle spinning (MAS) conditions identified the different components of the polymer backbone (PEO spacer and isophthalate groups) and their relative mobilities for a suite of lithium- and sodium-containing ionomer samples with varying cation contents. Variable temperature (203-373 K) 1H-13C cross-polarization MAS (CP-MAS) experiments also provided qualitative assessment of the differences in the motions of the polymer backbone components as a function of cation content and identity. Each of the main backbone components exhibit distinct motions, following the trends expected for motional characteristics based on earlier Quasi Elastic Neutron Scattering and 1H spin-lattice relaxation rate measurements. Previous 1H and 7Li spin-lattice relaxation measurements focused on both the polymer backbone and cation motion on the nanosecond timescale. The studies presented here assess the slower timescale motion of the polymer backbone allowing for a more comprehensive understanding of the polymer dynamics. The temperature dependences of 13C linewidths were used to both qualitatively and quantitatively examine the effects of cation content and identity on PEO spacer mobility. Variable contact time 1H-13C CP-MAS experiments were used to further assess the motions of the polymer backbone on the microsecond timescale. The motion of the PEO spacer, reported via the rate of magnetization transfer from 1H to 13C nuclei, becomes similar for T ? 1.1 Tg in all ionic samples, indicating that at similar elevated reduced temperatures the motions of the polymer backbones on the microsecond timescale become insensitive to ion interactions. These results present an improved picture, beyond those of previous findings, for the dependence of backbone dynamics on cation density (and here, cation identity as well) in these amorphous PEO-based ionomer systems.

  20. Testing to evaluate the suitability of waste forms developed for electrometallurgically treated spent sodium-bonded nuclear fuel for disposal in the Yucca Mountain reporsitory.

    SciTech Connect (OSTI)

    Ebert, W. E.

    2006-01-31T23:59:59.000Z

    The results of laboratory testing and modeling activities conducted to support the development of waste forms to immobilize wastes generated during the electrometallurgical treatment of spent sodium-bonded nuclear fuel and their qualification for disposal in the federal high-level radioactive waste repository are summarized in this report. Tests and analyses were conducted to address issues related to the chemical, physical, and radiological properties of the waste forms relevant to qualification. These include the effects of composition and thermal treatments on the phase stability, radiation effects, and methods for monitoring product consistency. Other tests were conducted to characterize the degradation and radionuclide release behaviors of the ceramic waste form (CWF) used to immobilize waste salt and the metallic waste form (MWF) used to immobilize metallic wastes and to develop models for calculating the release of radionuclides over long times under repository-relevant conditions. Most radionuclides are contained in the binder glass phase of the CWF and in the intermetallic phase of the MWF. The release of radionuclides from the CWF is controlled by the dissolution rate of the binder glass, which can be tracked using the same degradation model that is used for high-level radioactive waste (HLW) glass. Model parameters measured for the aqueous dissolution of the binder glass are used to model the release of radionuclides from a CWF under all water-contact conditions. The release of radionuclides from the MWF is element-specific, but the release of U occurs the fastest under most test conditions. The fastest released constituent was used to represent all radionuclides in model development. An empirical aqueous degradation model was developed to describe the dependence of the radionuclide release rate from a MWF on time, pH, temperature, and the Cl{sup -} concentration. The models for radionuclide release from the CWF and MWF are both bounded by the HLW glass degradation model developed for use in repository licensing, and HLW glass can be used as a surrogate for both CWF and MWF in performance assessment calculations. Test results indicate that the radionuclide release from CWF and MWF is adequately described by other relevant performance assessment models, such as the models for the solution chemistries in breached waste packages, dissolved concentration limits, and the formation of radionuclide-bearing colloids.

  1. Integrated Design and Manufacturing of Thermoelectric Generator...

    Office of Environmental Management (EM)

    High-Performance Thermoelectric Devices Based on Abundant Silicide Materials for Vehicle Waste Heat Recovery High-Performance Thermoelectric Devices Based on Abundant Silicide...

  2. Neutron diffraction study at 37 K of sodium triaqua(ethylenediaminetetraacetato)samarate(III) pentahydrate, Na[Sm(C10H12N2O8)(H2O)3].5H2O

    E-Print Network [OSTI]

    Engel, D. W.; Takusagawa, Fusao; Koetzle, T. F.

    1984-01-01T23:59:59.000Z

    at 37 K of Sodium Triaqua(ethylenediamine- tetraacetato)samarate(III) Pentahydrate, Na[Sm(C10H12N2O8)(H2O)3].5H2O* BY DENNIS W . ENGEL*|* Physics Department, University of Durban- Westville, Private Bag X54001, Durban 4000, South Africa AND FUSAO... by © 1984 International Union of Crystallography 1688 Na[Sm(C10H12N2O8)(H2O)3].5H2O Hoard, Lee & Lind (1965) and Lee (1967). The authors reported the structures of KLa/1.8H20 and NaTM.8H20 by X-ray diffraction. A further X-ray determination...

  3. Proceedings of the NEACRP/IAEA Specialists meeting on the international comparison calculation of a large sodium-cooled fast breeder reactor at Argonne National Laboratory on February 7-9, 1978

    SciTech Connect (OSTI)

    LeSage, L.G.; McKnight, R.D.; Wade, D.C.; Freese, K.E.; Collins, P.J.

    1980-08-01T23:59:59.000Z

    The results of an international comparison calculation of a large (1250 MWe) LMFBR benchmark model are presented and discussed. Eight reactor configurations were calculated. Parameters included with the comparison were: eigenvalue, k/sub infinity/, neutron balance data, breeding reaction rate ratios, reactivity worths, central control rod worth, regional sodium void reactivity, core Doppler and effective delayed neutron fraction. Ten countries participated in the comparison, and sixteen solutions were contributed. The discussion focuses on the variation in parameter values, the degree of consistency among the various parameters and solutions, and the identification of unexpected results. The results are displayed and discussed both by individual participants and by groupings of participants (e.g., results from adjusted data sets versus non-adjusted data sets).

  4. Co silicide formation on SiGeC/Si and SiGe/Si layers R. A. Donatona)

    E-Print Network [OSTI]

    on the total strain energy in the layer and restricts the applications where high Ge concentrations are needed spectrometry, secondary ion mass spectroscopy SIMS , and four point probe for sheet resistance measure- ments

  5. Vertically Grown Multiwalled Carbon Nanotube Anode and Nickel Silicide Integrated High Performance Microsized (1.25 L) Microbial

    E-Print Network [OSTI]

    Microsized (1.25 L) Microbial Fuel Cell Justine E. Mink,,§ Jhonathan P. Rojas,,§ Bruce E. Logan, and Muhammad, Pennsylvania 16802, United States *S Supporting Information ABSTRACT: Microbial fuel cells (MFCs to more efficiently shuttle electrons from the anode out of the device. KEYWORDS: Microbial fuel cell

  6. Phase Transformation for the Large-Scale Synthesis and Assembly via Welding of Metal Silicide Nanowires for Thermoelectric Applications

    E-Print Network [OSTI]

    Kang, Yongmin

    2014-11-10T23:59:59.000Z

    potential application in thermoelectrics,22, 42 microelectronics,71, 72 lithium ion batteries,73, 74 light emitting diodes,75 solar cells,76 and bio/chemical sensors.77 There are various ways to synthesis of silicon nanowires. The most commonly used...

  7. Phase Transformation for the Large-Scale Synthesis and Assembly via Welding of Metal Silicide Nanowires for Thermoelectric Applications 

    E-Print Network [OSTI]

    Kang, Yongmin

    2014-11-10T23:59:59.000Z

    was engineered. Experimentation performed indicated that 20 to 300 nm-thick, 5 to 20 µm-long silicon nanowires obtained by electroless etching can be phase transformed into polycrystalline Mg2Si nanowires by reacting them with magnesium supplied via the vapor...

  8. Iron silicide formation at different layers of (Fe/Si){sub 3} multilayered structures determined by conversion electron Mössbauer spectroscopy

    SciTech Connect (OSTI)

    Badía-Romano, L., E-mail: lbadia@unizar.es; Bartolomé, J. [Departamento de Física de la Materia Condensada, Instituto de Ciencia de Materiales de Aragón, CSIC-Universidad de Zaragoza, E-50009 Zaragoza (Spain); Rubín, J. [Departamento de Ciencia y Tecnología de Materiales y Fluidos, Instituto de Ciencia de Materiales de Aragón, CSIC-Universidad de Zaragoza, E-50018 Zaragoza (Spain); Magén, C. [Laboratorio de Microscopías Avanzadas (LMA), Instituto de Nanociencia de Aragón (INA), Universidad de Zaragoza, E-50018 Zaragoza (Spain); Bürgler, D. E. [Peter Grünberg Institut (PGI-6), Forschungszentrum Jülich GmbH, D-52425 Jülich (Germany)

    2014-07-14T23:59:59.000Z

    The morphology and the quantitative composition of the Fe-Si interface layer forming at each Fe layer of a (Fe/Si){sub 3} multilayer have been determined by means of conversion electron Mössbauer spectroscopy (CEMS) and high-resolution transmission electron microscopy (HRTEM). For the CEMS measurements, each layer was selected by depositing the Mössbauer active {sup 57}Fe isotope with 95% enrichment. Samples with Fe layers of nominal thickness d{sub Fe}?=?2.6?nm and Si spacers of d{sub Si}?=?1.5?nm were prepared by thermal evaporation onto a GaAs(001) substrate with an intermediate Ag(001) buffer layer. HRTEM images showed that Si layers grow amorphous and the epitaxial growth of the Fe is good only for the first deposited layer. The CEMS spectra show that at all Fe/Si and Si/Fe interfaces a paramagnetic c-Fe{sub 1?x}Si phase is formed, which contains 16% of the nominal Fe deposited in the Fe layer. The bottom Fe layer, which is in contact with the Ag buffer, also contains ?-Fe and an Fe{sub 1?x}Si{sub x} alloy that cannot be attributed to a single phase. In contrast, the other two layers only comprise an Fe{sub 1?x}Si{sub x} alloy with a Si concentration of ?0.15, but no ?-Fe.

  9. Reorientation of the ‘free OH’ group in the top-most layer of air/water interface of sodium fluoride aqueous solution probed with sum-frequency generation vibrational spectroscopy

    SciTech Connect (OSTI)

    Feng, Ran-Ran; Guo, Yuan; Wang, Hongfei

    2014-09-17T23:59:59.000Z

    Many experimental and theoretical studies have established the specific anion, as well as cation effects on the hydrogen-bond structures at the air/water interface of electrolyte solutions. However, the ion effects on the top-most layer of the air/water interface, which is signified by the non-hydrogen-bonded so-called ‘free O-H’ group, has not been discussed or studied. In this report, we present the measurement of changes of the orientational angle of the ‘free O-H’ group at the air/water interface of the sodium fluoride (NaF) solutions at different concentrations using the interface selective sum-frequency generation vibrational spectroscopy (SFG-VS) in the ssp and ppp polarizations. The polarization dependent SFG-VS results show that the average tilt angle of the ‘free O-H’ changes from about 35.3 degrees ± 0.5 degrees to 43.4 degrees ± 2.1degrees as the NaF concentration increase from 0 to 0.94M (nearly saturated). Such tilt angle change is around the axis of the other O-H group of the same water molecule at the top-most layer at the air/water interface that is hydrogen-bonded to the water molecules below the top-most layer. These results provide quantitative molecular details of the ion effects of the NaF salt on the structure of the water molecules at the top-most layer of the air/water interfacial, even though both the Na+ cation and the F- anion are believed to be among the most excluded ions from the air/water interface.

  10. Terrestrial Planet Atmospheres. The Moon's Sodium Atmosphere

    E-Print Network [OSTI]

    Walter, Frederick M.

    ;Origins of Atmospheres · Outgassing ­ Volcanoes expel water, CO2, N2, H2S, SO2 removed by the Fme convecFon reaches deserts #12;Water and Ice Clouds #12;H2SO4

  11. Titanate Anodes for Sodium Ion Batteries

    E-Print Network [OSTI]

    Doeff, Marca

    2014-01-01T23:59:59.000Z

    13. D. A. Stevens, J. R. Dahn, J. Electrochem. Soc. 147,Xia, M. N. Obravac, J. R. Dahn, Electrochem. and Sol. State

  12. Acid/Base Recovery From Sodium Sulfate

    E-Print Network [OSTI]

    Niksa, M. J.

    this valuable Internal resource. ELTECH has a proven record In the development of lon't-life anodes for use in acid sulfate solutions, and in providing high performance electrolytic generators. II. INTRODUCTION Closing The Loop On Sulfate Gains Public...-s~e costs can be Inslgn~lcant but outside and fill expense is rising exponentially as our landfills run out of room. Even "no-eost" disposal represems a waste of purchased resources. Current chemical costs (caustic soda and sulfuric acid) to make...

  13. OpenEI Community - Sodium hypochlorite Market

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to: navigation, searchOfRoseConcernsCompany Oil and GasOff thedriving dataHighlights

  14. Link between optical spectra, crystal-field parameters, and local environments of Eu{sup 3+} ions in Eu{sub 2}O{sub 3}-doped sodium disilicate glass

    SciTech Connect (OSTI)

    Qin, T.; Mountjoy, G.; Afify, N. D. [School of Physical Sciences, University of Kent, Canterbury CT2 7NH (United Kingdom); Reid, M. F. [Department of Physics and Astronomy and MacDiarmid Institute for Advanced Materials and Nanotechnology, University of Canterbury, Christchurch 8140 (New Zealand); Yeung, Y. Y. [Department of Science and Environmental Studies, Hong Kong Institute of Education, 10 Lo Ping Road, Tai Po, New Territories, Hong Kong (Hong Kong); Speghini, A.; Bettinelli, M. [Laboratorio di Chimica dello Stato Solido, DB, Universita di Verona, INSTM, UdR Verona, I-37134 Verona (Italy)

    2011-09-01T23:59:59.000Z

    Rare-earth-doped glasses are key materials for optical technology due to the luminescent properties of 4f{sup n} ions. The crystal-field model describes the effect of local environment on transitions between 4f electrons. We present a detailed modeling study of the optical spectra of sodium disilicate glass, 33Na{sub 2}O{center_dot}67SiO{sub 2}, doped with 0.2% and 1.0 mol%Eu{sub 2}O{sub 3}. This study uses very large molecular dynamics models with up to 100 Eu{sup 3+} ions, the superposition model for covalent and overlap effects on crystal-field parameters, and realistic values for homogeneous linewidth broadening. The simulated spectra are in reasonable agreement with experiment. The trends in {sup 7} F{sub J} energy levels across different Eu{sup 3+} ion sites have been examined and a very detailed analysis is presented that looks at how features of the spectra are related to features of the local environment of Eu{sup 3+} ions. Increasing the crystal-field strength S{sub total} causes the {sup 7} F{sub 0} energy level to decrease and causes the splitting of {sup 7} F{sub J} manifolds to increase, and this is due to increasing mixing of 4f wave functions. To a reasonable approximation the crystal-field strength components S{sub k} depend on angular positions of ligands independently of distances to ligands. The former are seen to be more significant in determining S{sub k}, which are closely related to the rotationally invariant bond-orientational order parameters Q{sub k}. The values of S{sub 2} are approximately linear in Q{sub 2}, and the values of Q{sub 2} are higher for fivefold than sixfold coordinated rare-earth ions. These results can be of importance for efforts to enhance the local environment of rare-earth ions in oxide glasses for optical applications.

  15. PHYSICAL REVIEW B 83, 165409 (2011) Coverage-dependent self-organized ordering of Co-and Ti-silicide nanoislands

    E-Print Network [OSTI]

    Rabani, Eran

    2011-01-01T23:59:59.000Z

    cells, lasers, modulators, detectors, and data storage devices.1­5 One of the most attractive ways nanostructures such as quantum dots (QDs) and wires on semiconductor surfaces has been a focus of interest and deposited material (likely to affect the nanostructure's shape and faceting), substrate temperature (may

  16. Revealing lithium-silicide phase transformations in nano-structured silicon based lithium ion batteries via in-situ NMR spectroscopy

    E-Print Network [OSTI]

    Ogata, K.; Salager, E.; Kerr, C. J.; Fraser, A. E.; Ducati, C.; Morris, A. J.; Hofmann, S.; Grey, C. P.

    2014-02-03T23:59:59.000Z

    Nano-structured silicon anodes are attractive alternatives to graphitic carbons in rechargeable Li-ion batteries, owing to their extremely high capacities. Despite their advantages, numerous issues remain to be addressed, the most basic being...

  17. Database Design Appendix B, app2.tex This file is c 1977 and 1983 by McGraw-Hill and c 1986, 2001 by Gio Wiederhold.

    E-Print Network [OSTI]

    Wiederhold, Gio

    , and NASIS. Kim79 surveyed relational DBMS' and Wiederhold82 includes descriptions of distributed DBMS ACCENT R National Information DEC10/20 Com DBMS slc rel stq 1981 Syst, Cupertino CA sch ADABAS software ag IBM360/370 Com DBMS hlc stq sch 1971 Darmstadt FRG Siemens drf cip pri rec Atre80 ADEPT System Dev

  18. Hydrogen peroxide modified sodium titanates with improved sorption capabilities

    DOE Patents [OSTI]

    Nyman, May D. (Albuquerque, NM); Hobbs, David T. (North Augusta, SC)

    2009-02-24T23:59:59.000Z

    The sorption capabilities (e.g., kinetics, selectivity, capacity) of the baseline monosodium titanate (MST) sorbent material currently being used to sequester Sr-90 and alpha-emitting radioisotopes at the Savannah River Site are significantly improved when treated with hydrogen peroxide; either during the original synthesis of MST, or, as a post-treatment step after the MST has been synthesized. It is expected that these peroxide-modified MST sorbent materials will have significantly improved sorption capabilities for non-radioactive cations found in industrial processes and waste streams.

  19. advanced sodium cooled: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in industrial cooling systems Michael R. Muller and Michael B. Muller Center for Advanced Energy Systems Rutgers University Piscataway, NJ 08854 Abstract Industrial cooling remains...

  20. Sodium storage facility trace heat system design description

    SciTech Connect (OSTI)

    Jones, D.D.

    1997-06-12T23:59:59.000Z

    This document describes the SSF PLC Ladder Logic, Cross references, and the software that was used to control the amount of power applied to the SSF Trace Heated components.

  1. INITIATION OF DEGRADATION IN POLYCRYSTALLINE SODIUM-BETA ALUMINA ELECTROLYTES

    E-Print Network [OSTI]

    De Jonghe, L.C.

    2010-01-01T23:59:59.000Z

    of Energy, under Contract W-7405-Eng-48. References R. D.Energy under Contract W-7405-ENG-48 mum # ms MWHfflI , s w a

  2. Development of sodium silicate adhesives for electrical steel bonding

    E-Print Network [OSTI]

    Marks, Jordan (Jordan Christine)

    2014-01-01T23:59:59.000Z

    Inorganic adhesives have several benefits over traditional joining methods for joining electrical steels used in magnetic cores of numerous industrial applications. As insulators with very high melting temperatures, the ...

  3. aluminum calcium sodium: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the pores Paris-Sud XI, Universit de 380 2009 SIMULIA Customer Conference 1 Aluminum Bottle Forming Simulation with Abaqus Engineering Websites Summary: 2009 SIMULIA Customer...

  4. Methodology for Life Testing of Refractory Metal / Sodium Heat Pipes

    SciTech Connect (OSTI)

    Martin, James J.; Reid, Robert S. [Marshall Space Flight Center, National Aeronautics and Space Administration, Huntsville, Alabama, 35812 (United States)

    2006-07-01T23:59:59.000Z

    This work establishes an approach to generate carefully controlled data to find heat pipe operating life with material-fluid combinations capable of extended operation. To accomplish this goal acceleration is required to compress 10 years of operational life into 3 years of laboratory testing through a combination of increased temperature and mass fluence. Specific test series have been identified, based on American Society for Testing and Materials (ASTM) specifications, to investigate long-term corrosion rates. The refractory metal selected for demonstration purposes is a molybdenum-44.5% rhenium alloy formed by powder metallurgy. The heat pipes each have an annular crescent wick formed by hot isostatic pressing of molybdenum-rhenium wire mesh. The heat pipes are filled by vacuum distillation with purity sampling of the completed assembly. Round-the-clock heat pipe tests with 6-month destructive and non-destructive inspection intervals are conducted to identify the onset and level of corrosion. Non-contact techniques are employed to provide power to the evaporator (radio frequency induction heating at 1 to 5 kW per heat pipe) and calorimetry at the condenser (static gas gap coupled water cooled calorimeter). The planned operating temperature range extends from 1123 to 1323 K. Accomplishments before project cancellation included successful development of the heat pipe wick fabrication technique, establishment of all engineering designs, baseline operational test requirements, and procurement/assembly of supporting test hardware systems. (authors)

  5. An investigation of pinch instabilities in solid sodium plasmas

    E-Print Network [OSTI]

    Henson, Robert Maurice

    1962-01-01T23:59:59.000Z

    e ie ene nacho|9 fox ylaxxDa con~ fine+sax, X'he meehoniea hg which bhs magnexie fiel@ Czaye a ylaemo otal he szyXBinee hp conBMGFinQ G chargse yaz'iiols aov9, ng in n CFOG vezas magnslio field zi The foxes cn hhs pazhiclo io given bp hho chars q...

  6. alkaline sodium borohydride: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (p ? 0.001). This was consistent with the stronger mixing characteristics of the hard wheats seen in water or saline mixograms but Andrew S. Ross 251 Characterization of the...

  7. antifouling compounds sodium: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (ICP-MS). The elements are listed in Table 1. These elements can also be determined in uranyl nitrate hexahydrate (UNH), uranium hexafluoride (UF6), triuranium octoxide (U3O8)...

  8. DYNAMOACTION,BETWEEN NUMERICAL EXPERIMENTS AND LIQUID SODIUM DEVICES

    E-Print Network [OSTI]

    Guermond, Jean-Luc

    or of the geomagnetic field. To get closer to the real MHD problems, new de­ signs of experimental devices and new or long magnetic cycles. After presenting the energetic considerations of the experimental dy­ namo convenient for cylindrical geometry (Section 5). 2. Turbulence and energetics of a fluid dynamo

  9. SLOW DEGRADATION AND ELECTRON INJECTION IN SODIUM-B ALUMINAS

    E-Print Network [OSTI]

    De Jonghe, Lutgard C.

    2013-01-01T23:59:59.000Z

    transfer of 703 XBB 804 4126 Degradation of sulfur side ofsilver staining. The degradation layer becomes more uniformMaterials Science SLOW DEGRADATION AND ELECTRON INJECTION IN

  10. acute sodium overload: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Conclusions 12;Approach admission control of first request using token bucket based policers no control of following requests on same persistent connection...

  11. SLOW DEGRADATION AND ELECTRON INJECTION IN SODIUM-B ALUMINAS

    E-Print Network [OSTI]

    De Jonghe, Lutgard C.

    2013-01-01T23:59:59.000Z

    S. Mitoff of the General Electric Research and Developmentobtained from the General Electric Research and Development

  12. Effect of Particle Size on Hydrogen Release from Sodium Alanate

    E-Print Network [OSTI]

    Ceder, Gerbrand

    temperature range ( 40 to 85 °C)1 for automotive fuel cells. Materials that thermodynamically re- lease · NaH · aluminum · Al · hydrogen storage · cluster expansion · nanoparticle · density functional theory

  13. aqueous sodium hydroxide: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    a range of renewable energy solutions including water splitting and rechargeable metal-air batteries. Here, we report the synthesis of ultrathin nickel iron layered double...

  14. THERMODYNAMIC AND TRANSPORT PROPERTIES OF SODIUM LIQUID AND VAPOR

    E-Print Network [OSTI]

    Kemner, Ken

    . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4 1.1 Enthalpy and Heat Capacity . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12 1.1.2 Heat Capacity . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13 Heat Capacity at Constant Pressure, CP . . . . . . . . . . . . . . . . . . . . . . . . 13 Heat

  15. acid sodium salt: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and spot selling price of various carboxylic acids. 1-3 Names used for biomass feedstocks. . 1-4 2-1 Sample processing. Rinsing scheme for precipitated solids. 12 3-1...

  16. acid sodium salts: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and spot selling price of various carboxylic acids. 1-3 Names used for biomass feedstocks. . 1-4 2-1 Sample processing. Rinsing scheme for precipitated solids. 12 3-1...

  17. acute sodium loading: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of sector 78 1. The estimate of the helium inventory, a prerequisite for the heat load calculation, is also presented. Heat loads to the cold mass are evaluated from the...

  18. The magnesium nutrition of cotton as influenced by sodium

    E-Print Network [OSTI]

    Thenabadu, Mervyn Wellesly

    1964-01-01T23:59:59.000Z

    -oa:, cld c:t. r. p alit ir a. clans as inrluenced ty siagnesium ard s jiL I . -'?'g"rs f:ct:o" pi ants at weekls lr ti rvdls as it' flL1 reed oy Htdg;1. S1L'm dl. d s 'dium R eld ls. ? chlcr opr yl contet t 1;. inrlu?. . ced ty magnesium ard sc... 1 . au=? as ol m R La=. te carctencio cnt?nt c:r ir. flu reed by maga siu?m arid sc edt. S o LU'm 615 . be distr ibu" c rr c f day - Ld ccttcr pl Cd 10rs li. l;':LSS? Ci 30 at' s distr ibu7 ic. . cf 6G-day olo cct cn radgr. esrum ar. d...

  19. Review of the Sodium Bearing Waste Treatment Project - Integrated...

    Office of Environmental Management (EM)

    DOE Idaho Operations Office D-ORR DOE Operational Readiness Review DSA Documented Safety Analysis EM Office of Environmental Management GAC Granulated Activated Carbon HEPA...

  20. Review of the Sodium Bearing Waste Treatment Project - Integrated...

    Office of Environmental Management (EM)

    DMR Denitration Mineralization Reformer DOE U.S. Department of Energy DSA Documented Safety Analysis EAL Emergency Action Level ECC Emergency Communications Center EOC Emergency...

  1. ascorbic acid sodium: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    stable thermodynamically and hydration free energies obtained Yu, Fangqun 338 ANTIBODY PURIFICATION USING CAPRYLIC ACID In mildly acidic conditions, the addition of short-chain...

  2. aluminum sodium sulfate: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (Chair... Balasubramanian, Rajasekaran 1991-01-01 232 The corrosion of aluminum in boric acid solutions Texas A&M University - TxSpace Summary: THE CORROSION OF ALUMINUM IN...

  3. Water content and morphology of sodium chloride aerosol particles

    E-Print Network [OSTI]

    Weis, David D.; Ewing, George E.

    1999-09-20T23:59:59.000Z

    2 for explanation) were obtained by bypassing the diffusion dryer (dashed line). The aerosol cell is 12 cm in length. path length of 12 cm and an inside diameter of 2.5 cm. The ends were sealed with silicon windows having a 30 min wedge (Infrared... of the FTIR spectrometer such that the focus point of the IR beam was near the center of the cell. The laser window and light trap were also sealed to the cell with O-rings and clamps but were used for an experiment that is not re- ported here. IR spectra...

  4. Original article Effects of sodium chloride salinity on root growth

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    either 50 or 250 mM NaCl. Both moderate and high salinity treatment strongly altered root elongation. In contrast, specific respiration of roots was unaffected by the moderate salinity treatment while ecosystems [11].The effects of snow melt have been documented for wetland ecosystems [14] but

  5. Generation IV International Forum Signs Agreement to Collaborate on Sodium

    Office of Environmental Management (EM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 1112011 Strategic2 OPAM Flash2011-12 OPAMGeneral Guidance on NEPA General GuidanceDepartment

  6. EIS-0287: Notice of Preferred Sodium Bearing Waste Treatment Technology |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't Your Destiny:Revised Finding of98-F,-SA-01: Supplement AnalysisDepartment of Energy

  7. OpenEI Community - Sodium hypochlorite Market Research

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to: navigation, searchOfRoseConcernsCompany Oil and GasOff thedriving dataHighlights

  8. OpenEI Community - Sodium hypochlorite Market Share

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to: navigation, searchOfRoseConcernsCompany Oil and GasOff thedriving dataHighlights

  9. OpenEI Community - Sodium hypochlorite Market Size

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to: navigation, searchOfRoseConcernsCompany Oil and GasOff thedriving dataHighlights

  10. OpenEI Community - Sodium hypochlorite Market Trends

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to: navigation, searchOfRoseConcernsCompany Oil and GasOff thedriving dataHighlights

  11. Sodium Bearing Waste Treatment Project � Countdown to Startup

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over Our Instagram Secretary Moniz9MorganYou are hereValue ofSocioeconomic procurementFor

  12. Remedial Action Certification Docket - Sodium Reactor Experiment (SRE)

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilA group currentBradleyTableSelling7 AugustAFRICAN3u ;;;:: A' 3 ct' RIDGE

  13. Sodium hypochlorite Market Research | OpenEI Community

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnualProperty Edit with form HistoryRistmaSinosteel CorporationSocovoltaic Systems Jump

  14. Sodium hypochlorite Market Share | OpenEI Community

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnualProperty Edit with form HistoryRistmaSinosteel CorporationSocovoltaic Systems Jump

  15. Sodium hypochlorite Market Size | OpenEI Community

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnualProperty Edit with form HistoryRistmaSinosteel CorporationSocovoltaic Systems Jump

  16. Low-temperature Sodium-Beta Battery - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cnHigh SchoolIn12electron 9November 6, 2014 PNGC,Low-TemperatureBiomass

  17. Idaho Site Obtains Patent for Nuclear Reactor Sodium Cleanup Treatment |

    Office of Environmental Management (EM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 1112011 Strategic2 OPAM Flash2011-12Approved on 24 JulyE, EXEMPTION| Department

  18. Independent Oversight Assessment, Idaho Cleanup Project Sodium Bearing

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

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  19. Independent Oversight Review, Sodium Bearing Waste Treatment Project -

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport(Fact Sheet),EnergyImprovement ofDecemberPlateau RemediationofFacility -2012

  20. Independent Oversight Review, Sodium Bearing Waste Treatment Project -

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport(Fact Sheet),EnergyImprovement ofDecemberPlateau RemediationofFacility