National Library of Energy BETA

Sample records for napl non-aqueous phase

  1. Non-Aqueous Phase Liquid Calculator

    Energy Science and Technology Software Center (OSTI)

    2004-02-19

    Non-Aqueous Phase Liquid or "NPAL" is a term that most environmental professionals are familiar with because NAPL has been recognized in the literature as a significant source of groundwater contamination. There are two types of NAPL: DNAPL and LNAPL. DNAPL is a ‘dense’ non-aqueous phase liquid. In this context, dense means having a density greater than water (1.0 kg/L). Trichloroethylene (TCE) and tetrachioroethylene (PCE) are examples of DNAPL compounds. A compound that is heaver thanmore » water means this type of NAPL will sink in an aquifer. Conversely, LNAPL is a ‘light’ non-aqueous phase liquid with a density less than water, and will float on top of the aquifer. Examples of LNAPL’s are benzene and toluene. LNAPL or DNAPL often manifest as a complex, multi-component mixture of organic compounds that can occur in environmental media. Complex multi-component mixtures distributed in soil pore-air, pore-water, soil particles and in free phase complicate residual saturation of single and multi component NAPL compounds in soil samples. The model output also includes estimates of the NAPL mass and volume and other physical and chemical properties that may be useful for characterization, modeling, and remedial system design and operation. The discovery of NAPL in the aquifer usually leads to a focused characterization for possible sources of NAPL in the vadose zone using a variety of innovative technologies and characterization methods. Often, the analytical data will indicated the presence of NAPL, yet, the NAPL will go unrecognized. Failure to recognize the NAPL can be attributed to the complicated processes of inter-media transfer or a general lack of knowledge about the physical characteristics of complex organic mixtures in environmental samples.« less

  2. Northeast Site Non-Aqueous Phase Liquids Interim Measures Progress Report April through June 2003

    Office of Legacy Management (LM)

    7-TAC GJO-PIN 13.5.1-1 U.S. Department of Energy Work Performed Under DOE Contract No. for the U.S. Department of Energy DE-AC13-02GJ79491 Approved for public release; distribution is unlimited. Pinellas Environmental Restoration Project Northeast Site Non-Aqueous Phase Liquids Interim Measures Progress Report April Through June 2003 July 2003 N0063400 GJO- 2003- 467- TAC GJO-PIN 13.5.1-1 Pinellas Environmental Restoration Project Northeast Site Non-Aqueous Phase Liquids Interim Measures

  3. Northeast Site Non-Aqueous Phase Liquids Interim Measures Progress Report-January through March 2003

    Office of Legacy Management (LM)

    4-TAC GJO-PIN 13.5.1-1 Pinellas Environmental Restoration Project January through March 2003 Northeast Site Non-Aqueous Phase Liquids Interim Measures Progress Report April 2003 Grand Junction Office U.S. Department of Energy Work Performed Under DOE Contract No. for the U.S. Department of Energy DE-AC13-02GJ79491 Approved for public release; distribution is unlimited. N0060900 GJO-2003-434-TAC GJO-PIN 13.5.1-1 Pinellas Environmental Restoration Project Northeast Site Non-Aqueous Phase Liquids

  4. Method and device for removing a non-aqueous phase liquid from a groundwater system

    DOE Patents [OSTI]

    Looney, Brian B. (Aiken, SC); Rossabi, Joseph (Aiken, SC); Riha, Brian D. (Augusta, GA)

    2002-01-01

    A device for removing a non-aqueous phase liquid from a groundwater system includes a generally cylindrical push-rod defining an internal recess therein. The push-rod includes first and second end portions and an external liquid collection surface. A liquid collection member is detachably connected to the push-rod at one of the first and second end portions thereof. The method of the present invention for removing a non-aqueous phase liquid from a contaminated groundwater system includes providing a lance including an external hydrophobic liquid collection surface, an internal recess, and a collection chamber at the bottom end thereof. The lance is extended into the groundwater system such that the top end thereof remains above the ground surface. The liquid is then allowed to collect on the liquid collection surface, and flow downwardly by gravity into the collection chamber to be pumped upwardly through the internal recess in the lance.

  5. Alkyl-bis(imidazolium) salts: a new amphiphile platform that forms thermotropic and non-aqueous lyotropic bicontinuous cubic phases

    SciTech Connect (OSTI)

    Robertson, LA; Schenkel, MR; Wiesenauer, BR; Gin, DL

    2013-01-01

    New ionic amphiphiles with a hexyl-bridged bis(imidazolium) headgroup; Br-, BF4-, or Tf2N- anions; and a long n-alkyl tail can form thermotropic bicontinuous cubic liquid crystal phases in neat form and/or lyotropic bicontinuous cubic phases with several non-aqueous solvents or water.

  6. Refinement of the Kansas City Plant site conceptual model with respect to dense non-aqueous phase liquids (DNAPL)

    SciTech Connect (OSTI)

    Korte, N.E.; Hall, S.C.; Baker, J.L.

    1995-10-01

    This document presents a refinement of the site conceptual model with respect to dense non-aqueous phase liquid (DNAPL) at the US Department of Energy Kansas City Plant (KCP). This refinement was prompted by a review of the literature and the results of a limited study that was conducted to evaluate whether pools of DNAPL were present in contaminated locations at the KCP. The field study relied on the micropurge method of sample collection. This method has been demonstrated as a successful approach for obtaining discrete samples within a limited aquifer zone. Samples were collected at five locations across 5-ft well screens located at the base of the alluvial aquifer at the KCP. The hypothesis was that if pools of DNAPL were present, the dissolved concentration would increase with depth. Four wells with highly contaminated groundwater were selected for the test. Three of the wells were located in areas where DNAPL was suspected, and one where no DNAPL was believed to be present. The results demonstrated no discernible pattern with depth for the four wells tested. A review of the data in light of the available technical literature suggests that the fine-grained nature of the aquifer materials precludes the formation of pools. Instead, DNAPL is trapped as discontinuous ganglia that are probably widespread throughout the aquifer. The discontinuous nature of the DNAPL distribution prevents the collection of groundwater samples with concentrations approaching saturation. Furthermore, the results indicate that attempts to remediate the aquifer with conventional approaches will not result in restoration to pristine conditions because the tortuous groundwater flow paths will inhibit the efficiency of fluid-flow-based treatments.

  7. Non-aqueous liquid compositions comprising ion exchange polymers...

    Office of Scientific and Technical Information (OSTI)

    Non-aqueous liquid compositions comprising ion exchange polymers Title: Non-aqueous liquid compositions comprising ion exchange polymers Compositions, and methods of making ...

  8. Niagara Air Quality Survey Report, 1987: Occidental Chemical Corporation, Niagara Falls, New York, USA, non-aqueous phase liquid (NAPL) incineration test. Report no. ARB-166-87-AR/SP

    SciTech Connect (OSTI)

    Bell, R.W.; DeBrou, G.

    1988-01-01

    An ambient air quality survey was conducted in the Niagara Falls area of Ontario from October 8-12, 1987 to provide on-site real-time screening for selected polychlorinated biphenyl congeners and other chlorinated organics at times when the Occidental Chemical Corporation was conducting tests at its liquid hazardous waste incineration facility in Niagara Falls, N.Y. During the incineration tests, the winds were such that the gaseous emissions from the Occidental facility were carried into the U.S. Since the monitoring units were restricted to the Canadian side of the Niagara River, only upwind air quality parameters could be measured.

  9. Inorganic rechargeable non-aqueous cell

    DOE Patents [OSTI]

    Bowden, William L. (Nashua, NH); Dey, Arabinda N. (Needham, MA)

    1985-05-07

    A totally inorganic non-aqueous rechargeable cell having an alkali or alkaline earth metal anode such as of lithium, a sulfur dioxide containing electrolyte and a discharging metal halide cathode, such as of CuCl.sub.2, CuBr.sub.2 and the like with said metal halide being substantially totally insoluble in SO.sub.2 and admixed with a conductive carbon material.

  10. NON-AQUEOUS DISSOLUTION OF MASSIVE PLUTONIUM

    DOE Patents [OSTI]

    Reavis, J.G.; Leary, J.A.; Walsh, K.A.

    1959-05-12

    A method is presented for obtaining non-aqueous solutions or plutonium from massive forms of the metal. In the present invention massive plutonium is added to a salt melt consisting of 10 to 40 weight per cent of sodium chloride and the balance zinc chloride. The plutonium reacts at about 800 deg C with the zinc chloride to form a salt bath of plutonium trichloride, sodium chloride, and metallic zinc. The zinc is separated from the salt melt by forcing the molten mixture through a Pyrex filter.

  11. Non-aqueous electrolyte for lithium-ion battery

    DOE Patents [OSTI]

    Zhang, Lu; Zhang, Zhengcheng; Amine, Khalil

    2015-12-22

    An electrolyte including an alkali metal salt; a polar aprotic solvent; and a triazinane trione; wherein the electrolyte is substantially non-aqueous.

  12. Non-aqueous liquid compositions comprising ion exchange polymers (Patent) |

    Office of Scientific and Technical Information (OSTI)

    DOEPatents Data Explorer Search Results Non-aqueous liquid compositions comprising ion exchange polymers Title: Non-aqueous liquid compositions comprising ion exchange polymers Compositions, and methods of making thereof, comprising from about 1% to about 5% of a perfluorinated sulfonic acid ionomer or a hydrocarbon-based ionomer; and from about 95% to about 99% of a solvent, said solvent consisting essentially of a polyol; wherein said composition is substantially free of water and wherein

  13. Naples, Maine: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Naples, Maine: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates 43.971739, -70.6092258 Show Map Loading map... "minzoom":false,"mappingservice":...

  14. Northeast Site Non-Aqueous Phase Liquids Interim Measures Progress...

    Office of Legacy Management (LM)

    ... The initial activities for remediation of Area B will start in Spring 2003. These activities will involve evaluation of the permitting and environmental compliance requirements and ...

  15. Anion receptor compounds for non-aqueous electrolytes

    DOE Patents [OSTI]

    Lee, Hung Sui; Yang, Xiao-Oing; McBreen, James

    2000-09-19

    A new family of aza-ether based compounds including linear, multi-branched and aza-crown ethers is provided. When added to non-aqueous battery electrolytes, the new family of aza-ether based compounds acts as neutral receptors to complex the anion moiety of the electrolyte salt thereby increasing the conductivity and the transference number of LI.sup.+ ion in alkali metal batteries.

  16. Phenyl boron-based compounds as anion receptors for non-aqueous battery electrolytes

    DOE Patents [OSTI]

    Lee, Hung Sui; Yang, Xiao-Qing; McBreen, James; Sun, Xuehui

    2002-01-01

    Novel fluorinated boronate-based compounds which act as anion receptors in non-aqueous battery electrolytes are provided. When added to non-aqueous battery electrolytes, the fluorinated boronate-based compounds of the invention enhance ionic conductivity and cation transference number of non-aqueous electrolytes. The fluorinated boronate-based anion receptors include different fluorinated alkyl and aryl groups.

  17. Non-aqueous electrolytes for lithium ion batteries

    DOE Patents [OSTI]

    Chen, Zonghai; Amine, Khalil

    2015-11-12

    The present invention is generally related to electrolytes containing anion receptor additives to enhance the power capability of lithium-ion batteries. The anion receptor of the present invention is a Lewis acid that can help to dissolve LiF in the passivation films of lithium-ion batteries. Accordingly, one aspect the invention provides electrolytes comprising a lithium salt; a polar aprotic solvent; and an anion receptor additive; and wherein the electrolyte solution is substantially non-aqueous. Further there are provided electrochemical devices employing the electrolyte and methods of making the electrolyte.

  18. Microsoft Word - N0075800-NAPL April to June 04.doc

    Office of Legacy Management (LM)

    April Through June 2004 July 2004 Work Performed Under DOE Contract No. for the U.S. Department of Energy Office of Legacy Management. DE-AC01-02GJ79491 Approved for public release; distribution is unlimited. Office of Legacy Management Office of Legacy Management Office of Legacy Management Office of Legacy Management DOE LM/ 6 2004 - - GJ 93 N0075800 DOE-LM/GJ693-2004 Pinellas Environmental Restoration Project Northeast Site Non-Aqueous Phase Liquids Interim Measures Progress Report April

  19. Non-aqueous electrolyte for lithium-ion battery

    DOE Patents [OSTI]

    Amine, Khalil; Zhang, Lu; Zhang, Zhengcheng

    2016-01-26

    A substantially non-aqueous electrolyte solution includes an alkali metal salt, a polar aprotic solvent, and an organophosphorus compound of Formula IA, IB, or IC: ##STR00001## where R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are each independently hydrogen, halogen, alkyl, alkenyl, alkynyl, cycloalkyl, aryl, heterocyclyl, heteroaryl, alkoxy, alkenoxy, alkynoxy, cycloalkoxy, aryloxy, heterocyclyloxy, heteroaryloxy, siloxyl, silyl, or organophosphatyl; R.sup.5 and R.sup.6 are each independently alkyl, alkenyl, alkynyl, cycloalkyl, aryl, heterocyclyl, or heteroaryl; R.sup.7 is ##STR00002## and R.sup.8, R.sup.9 and R.sup.10 are each independently alkyl, cycloalkyl, aryl, heterocyclyl, or heteroaryl; provided that if the organophosphorus compound is of Formula IB, then at least one of R.sup.5, and R.sup.6 are other than hydrogen, alkyl, or alkenyl; and if the organophosphorus compound is of Formula IC, then the electrolyte solution does not include 4-methylene-1,3-dioxolan-2-one or 4,5-dimethylene-1,3-dioxolan-2-one.

  20. Non-aqueous solution preparation of doped and undoped lixmnyoz

    DOE Patents [OSTI]

    Boyle, Timothy J.; Voigt, James A.

    1997-01-01

    A method for generation of phase-pure doped and undoped Li.sub.x Mn.sub.y O.sub.z precursors. The method of this invention uses organic solutions instead of aqueous solutions or nonsolution ball milling of dry powders to produce phase-pure precursors. These precursors can be used as cathodes for lithium-polymer electrolyte batteries. Dopants may be homogeneously incorporated to alter the characteristics of the powder.

  1. Microsoft Word - N0071600-NAPL-Oct to Dec.doc

    Office of Legacy Management (LM)

    6-TAC U.S. Department of Energy Pinellas Environmental Restoration Project Northeast Site Non-Aqueous Phase Liquids Interim Measure Progress Report October Through December 2003 January 2004 Work Performed Under DOE Contract No. for the U.S. Department of Energy Office of Legacy Management, Grand Junction, Colorado. DE-AC01-02GJ79491 Approved for public release; distribution is unlimited. Office of Legacy Management Office of Legacy Management Office of Legacy Management N0071600

  2. Non-aqueous spray drying as a route to ultrafine ceramic powders

    SciTech Connect (OSTI)

    Armor, J.N. ); Fanelli, A.J.; Marsh, G.M. ); Zambri, P.M. )

    1988-09-01

    Spray drying imparts unique powder handling features to a wide variety of dried products and is usually carried out in a heated air stream while feeding an aqueous suspension of some solid material. The present work, however, describes non-aqueous spray drying as a means of preparing fine powders of metal oxides. In this case an alcohol solvent was used in place of water and the slurry sprayed under an inert atmosphere. Using the non-aqueous technique, the product consists of distinct but loosely aggregated primary particles. Such materials have potential for use as catalysts or catalyst supports.

  3. U.S. DEPARTMENT OF ENERGY * SAVANNAH RIVER SITE * AIKEN * SC

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NAPL Calculator: (Non-aqueous Phase Liquid) An environmental engineer at the Savannah River Site has developed a software application that will determine if non-aqueous phase liquid (NAPL) contaminants are present in soil, groundwater, or soil vapor samples. The software will determine both the quantity and composition of NAPL chemicals in the samples based on the results of sample analysis. The software also computes important environmental engineering measures such as the residual saturation,

  4. Microsoft Word - N0074600-NAPL-Jan to March.doc

    Office of Legacy Management (LM)

    January Through March 2004 April 2004 Work Performed Under DOE Contract No. for the U.S. Department of Energy Office of Legacy Management. DE-AC01-02GJ79491 Approved for public release; distribution is unlimited. Office of Legacy Management Office of Legacy Management Office of Legacy Management Office of Legacy Management DOE LM/ 646 2004 - - GJ N0074600 DOE-LM/GJ646-2004 Pinellas Environmental Restoration Project Northeast Site Non-Aqueous Phase Liquids Interim Measures Progress Report January

  5. High voltage rechargeable magnesium batteries having a non-aqueous electrolyte

    DOE Patents [OSTI]

    Doe, Robert Ellis; Lane, George Hamilton; Jilek, Robert E.; Hwang, Jaehee

    2016-03-22

    A rechargable magnesium battery having an non-aqueous electrolyte is provided. The properties of the electrolyte include high conductivity, high Coulombic efficiency, and an electrochemical window that can exceed 3.5 V vs. Mg/Mg.sup.+2. The use of the electrolyte promotes the electrochemical deposition and dissolution of Mg without the use of any Grignard reagents, other organometallic materials, tetraphenyl borate, or tetrachloroaluminate derived anions. Other Mg-containing electrolyte systems that are expected to be suitable for use in secondary batteries are also described.

  6. Project Overview: Successful Field-Scale In Situ Thermal NAPL Remediation |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Project Overview: Successful Field-Scale In Situ Thermal NAPL Remediation Project Overview: Successful Field-Scale In Situ Thermal NAPL Remediation Paper presented at the Third International Conference on Oxidation and Reduction Technologies for Soil and Groundwater. October 2004, San Diego, California. Michael Butherus, David S. Ingle, Randall Juhlin, Joseph Daniel PDF icon Project Overview: Successful Field-Scale In Situ Thermal NAPL Remediation More Documents &

  7. Microsoft Word - DOE_RM_DM-#344133-v1-Final_NAPL_Quarterly_July...

    Office of Legacy Management (LM)

    ... for a similar treatment system at NAPL Area B (Figure 1). ... started, the average temperature in the subsurface inside ... concentrations remain low both inside and around the ...

  8. Final Report Northeast Site Area B NAPL Remediation Project

    Office of Legacy Management (LM)

    Northeast Site Area B NAPL Remediation Project at the Young - Rainey STAR Center Largo, Pinellas County, Florida April 2007 Office of Legacy Management DOE M/1457 2007 - -L Work Performed Under DOE Contract No. for the U.S. Department of Energy Office of Legacy Management. DE-AC01-02GJ79491 Approved for public release; distribution is unlimited. Office of Legacy Management Office of Legacy Management Office of Legacy Management U.S. Department of Energy This page intentionally left blank

  9. Highly Quantitative Electrochemical Characterization of Non-Aqueous Electrolytes & Solid Electrolyte Interphases

    SciTech Connect (OSTI)

    Sergiy V. Sazhin; Kevin L. Gering; Mason K. Harrup; Harry W. Rollins

    2012-10-01

    The methods to measure solid electrolyte interphase (SEI) electrochemical properties and SEI formation capability of non-aqueous electrolyte solutions are not adequately addressed in the literature. And yet, there is a strong demand in new electrolyte generations that promote stabilized SEIs and have an influence to resolve safety, calendar life and other limitations of Li-ion batteries. To fill this gap, in situ electrochemical approach with new descriptive criteria for highly quantitative characterization of SEI and electrolytes is proposed. These criteria are: SEI formation capacity, SEI corrosion rate, SEI maintenance rate, and SEI kinetic stability. These criteria are associated with battery parameters like irreversible capacity, self-discharge, shelf-life, power, etc. Therefore, they are especially useful for electrolyte development and standard fast screening, allowing a skillful approach to narrow down the search for the best electrolyte. The characterization protocol also allows retrieving information on interfacial resistance for SEI layers and the electrochemical window of electrolytes, the other important metrics of characterization. The method validation was done on electrolyte blends containing phosphazenes, developed at Idaho National Laboratory, as 1.2M LiPF6 [80 % EC-MEC (2:8) (v/v) + 20% Phosphazene variety] (v/v), which were targeted for safer electrolyte variations.

  10. Shale gas and non-aqueous fracturing fluids: Opportunities and challenges for supercritical CO₂

    SciTech Connect (OSTI)

    Middleton, Richard S.; Carey, James William; Currier, Robert P.; Hyman, Jeffrey De'Haven; Kang, Qinjun; Karra, Satish; Jiménez-Martínez, Joaquín; Porter, Mark L.; Viswanathan, Hari S.

    2015-06-01

    Hydraulic fracturing of shale formations in the United States has led to a domestic energy boom. Currently, water is the only fracturing fluid regularly used in commercial shale oil and gas production. Industry and researchers are interested in non-aqueous working fluids due to their potential to increase production, reduce water requirements, and to minimize environmental impacts. Using a combination of new experimental and modeling data at multiple scales, we analyze the benefits and drawbacks of using CO₂ as a working fluid for shale gas production. We theorize and outline potential advantages of CO₂ including enhanced fracturing and fracture propagation, reduction of flow-blocking mechanisms, increased desorption of methane adsorbed in organic-rich parts of the shale, and a reduction or elimination of the deep re-injection of flow-back water that has been linked to induced seismicity and other environmental concerns. We also examine likely disadvantages including costs and safety issues associated with handling large volumes of supercritical CO₂. The advantages could have a significant impact over time leading to substantially increased gas production. In addition, if CO₂ proves to be an effective fracturing fluid, then shale gas formations could become a major utilization option for carbon sequestration.

  11. Shale gas and non-aqueous fracturing fluids: Opportunities and challenges for supercritical CO₂

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Middleton, Richard S.; Carey, James William; Currier, Robert P.; Hyman, Jeffrey De'Haven; Kang, Qinjun; Karra, Satish; Jiménez-Martínez, Joaquín; Porter, Mark L.; Viswanathan, Hari S.

    2015-06-01

    Hydraulic fracturing of shale formations in the United States has led to a domestic energy boom. Currently, water is the only fracturing fluid regularly used in commercial shale oil and gas production. Industry and researchers are interested in non-aqueous working fluids due to their potential to increase production, reduce water requirements, and to minimize environmental impacts. Using a combination of new experimental and modeling data at multiple scales, we analyze the benefits and drawbacks of using CO₂ as a working fluid for shale gas production. We theorize and outline potential advantages of CO₂ including enhanced fracturing and fracture propagation, reductionmore » of flow-blocking mechanisms, increased desorption of methane adsorbed in organic-rich parts of the shale, and a reduction or elimination of the deep re-injection of flow-back water that has been linked to induced seismicity and other environmental concerns. We also examine likely disadvantages including costs and safety issues associated with handling large volumes of supercritical CO₂. The advantages could have a significant impact over time leading to substantially increased gas production. In addition, if CO₂ proves to be an effective fracturing fluid, then shale gas formations could become a major utilization option for carbon sequestration.« less

  12. Microsoft Word - DOE_RM_DM-#99768-v1-NAPL_Quarterly_Report_for_July-Sept_20ƒ

    Office of Legacy Management (LM)

    July Through September 2004 October 2004 Work Performed Under DOE Contract No. for the U.S. Department of Energy Office of Legacy Management. DE-AC01-02GJ79491 Approved for public release; distribution is unlimited. Office of Legacy Management Office of Legacy Management Office of Legacy Management Office of Legacy Management DOE LM/ 2004 - - GJ751 DOE-LM/GJ751-2004 Pinellas Environmental Restoration Project Northeast Site Non-Aqueous Phase Liquids Interim Measures Progress Report July through

  13. Microsoft Word - DOE_RM_DM-#345139-v1-NAPL_Quarterly_Oct-Dec...

    Office of Legacy Management (LM)

    ... for a similar treatment system at NAPL Area B (Figure 1). ... at or above the target temperature, while some areas ... concentrations remain low both U.S. Department of ...

  14. Quantitative Chromatographic Determination of Dissolved Elemental Sulfur in the Non-aqueous Electrolyte for Lithium-Sulfur Batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zheng, Dong; Yang, Xiao-Qing; Zhang, Xuran; Li, Chao; McKinnon, Meaghan E.; Sadok, Rachel G.; Qu, Deyu; Yu, Xiqian; Lee, Hung-Sui; Qu, Deyang

    2014-12-02

    A fast and reliable analytical method is reported for the quantitative determination of dissolved elemental sulfur in non-aqueous electrolytes for Li-S batteries. By using high performance liquid chromatography with a UV detector, the solubility of S in 12 different pure solvents and in 22 different electrolytes was determined. It was found that the solubility of elemental sulfur is dependent on the Lewis basicity, the polarity of solvents and the salt concentration in the electrolytes. In addition, the S content in the electrolyte recovered from a discharged Li-S battery was successfully determined by the proposed HPLC/UV method. Thus, the feasibility ofmore » the method to the online analysis for a Li-S battery is demonstrated. Interestingly, the S was found super-saturated in the electrolyte recovered from a discharged Li-S cell.« less

  15. Quantitative Chromatographic Determination of Dissolved Elemental Sulfur in the Non-aqueous Electrolyte for Lithium-Sulfur Batteries

    SciTech Connect (OSTI)

    Zheng, Dong; Yang, Xiao-Qing; Zhang, Xuran; Li, Chao; McKinnon, Meaghan E.; Sadok, Rachel G.; Qu, Deyu; Yu, Xiqian; Lee, Hung-Sui; Qu, Deyang

    2014-12-02

    A fast and reliable analytical method is reported for the quantitative determination of dissolved elemental sulfur in non-aqueous electrolytes for Li-S batteries. By using high performance liquid chromatography with a UV detector, the solubility of S in 12 different pure solvents and in 22 different electrolytes was determined. It was found that the solubility of elemental sulfur is dependent on the Lewis basicity, the polarity of solvents and the salt concentration in the electrolytes. In addition, the S content in the electrolyte recovered from a discharged Li-S battery was successfully determined by the proposed HPLC/UV method. Thus, the feasibility of the method to the online analysis for a Li-S battery is demonstrated. Interestingly, the S was found super-saturated in the electrolyte recovered from a discharged Li-S cell.

  16. Investigation of the Rechargeability of Li-O2 Batteries in Non-aqueous Electrolyte

    SciTech Connect (OSTI)

    Xiao, Jie; Hu, Jian Z.; Wang, Deyu; Hu, Dehong; Xu, Wu; Graff, Gordon L.; Nie, Zimin; Liu, Jun; Zhang, Jiguang

    2011-07-01

    In order to understand the nature of the limited cycle life and poor energy efficiency associated with the secondary Li-O2 batteries the discharge products of primary Li-O2 cells at different depth of discharge (DOD) are systematically analyzed in this work. It is revealed that if discharged to 2.0 V a small amount of Li2O2 coexist with Li2CO3 and RO-(C=O)-OLi) in alkyl carbonate-based electrolyte. Further discharging the air electrodes to below 2.0 V the amount of Li2CO3 and LiRCO3 increases significantly due to the severe electrolyte decomposition. There is no Li2O detected in this alkyl carbonate electrolyte regardless of DOD. It is also found that the alkyl carbonate based electrolyte begins to decompose at 4.0 V during charging under the combined influences from the high surface area carbon, the nickel metal current collector and the oxygen atmosphere. Accordingly the impedance of the Li-O2 cell continues to increase after each discharge and recharge process indicating a repeated plating of insoluble lithium salts on the carbon surface. Therefore the whole carbon electrode becomes completely insulated only after a few cycles and loses the function of providing active tri-phase regions for the Li-oxygen batteries.

  17. Shale gas and non-aqueous fracturing fluids: Opportunities and challenges for supercritical CO2

    SciTech Connect (OSTI)

    Middleton, Richard Stephen; Carey, James William; Currier, Robert Patrick; Hyman, Jeffrey De'Haven; Kang, Qinjun; Karra, Satish; Viswanathan, Hari S.; Porter, Mark L.; Martinez, Joaquin Jimenez

    2015-03-23

    In this study, hydraulic fracturing of shale formations in the United States has led to a domestic energy boom. Currently, water is the only fracturing fluid regularly used in commercial shale oil and gas production. Industry and researchers are interested in non-aqueous working fluids due to their potential to increase production, reduce water requirements, and to minimize environmental impacts. Using a combination of new experimental and modeling data at multiple scales, we analyze the benefits and drawbacks of using CO2 as a working fluid for shale gas production. We theorize and outline potential advantages of CO2 including enhanced fracturing and fracture propagation, reduction of flow-blocking mechanisms, increased desorption of methane adsorbed in organic-rich parts of the shale, and a reduction or elimination of the deep re-injection of flow-back water that has been linked to induced seismicity and other environmental concerns. We also examine likely disadvantages including costs and safety issues associated with handling large volumes of supercritical CO2. The advantages could have a significant impact over time leading to substantially increased gas production. In addition, if CO2 proves to be an effective fracturing fluid, then shale gas formations could become a major utilization option for carbon sequestration.

  18. Microsoft Word - San Diego 2004 ORT Conference paper_1.doc

    Energy Savers [EERE]

    presented at the Third International Conference on Oxidation and Reduction Technologies for Soil and Groundwater in San Diego, CA, on October 24-28, 2004 PROJECT OVERVIEW: SUCCESSFUL FIELD-SCALE IN SITU THERMAL NAPL REMEDIATION ABSTRACT: The U.S. Department of Energy (DOE) successfully completed a field-scale remediation to remove non-aqueous phase liquids (NAPLs) from the subsurface at the Northeast Site on the Young-Rainey Science, Technology, and Research (STAR) Center, Largo, Florida. The

  19. Microsoft Word - Submittal Letter for Recommendation 2016-01 Campaign Approach

    Office of Environmental Management (EM)

    presented at the Third International Conference on Oxidation and Reduction Technologies for Soil and Groundwater in San Diego, CA, on October 24-28, 2004 PROJECT OVERVIEW: SUCCESSFUL FIELD-SCALE IN SITU THERMAL NAPL REMEDIATION ABSTRACT: The U.S. Department of Energy (DOE) successfully completed a field-scale remediation to remove non-aqueous phase liquids (NAPLs) from the subsurface at the Northeast Site on the Young-Rainey Science, Technology, and Research (STAR) Center, Largo, Florida. The

  20. Non-aqueous solution preparation of doped and undoped Li{sub x}Mn{sub y}O{sub z}

    DOE Patents [OSTI]

    Boyle, T.J.; Voigt, J.A.

    1997-05-20

    A method is described for generation of phase-pure doped and undoped Li{sub x}Mn{sub y}O{sub z} precursors. The method of this invention uses organic solutions instead of aqueous solutions or nonsolution ball milling of dry powders to produce phase-pure precursors. These precursors can be used as cathodes for lithium-polymer electrolyte batteries. Dopants may be homogeneously incorporated to alter the characteristics of the powder. 1 fig.

  1. Surface and Interfacial Properties of Nonaqueous-Phase Liquid Mixtures Released to the Subsurface at the Hanford Site

    SciTech Connect (OSTI)

    Nellis, Scott; Yoon, Hongkyu; Werth, Charlie; Oostrom, Martinus; Valocchi, Albert J.

    2009-05-01

    Surface and interfacial tensions that arise at the interface between different phases are key parameters affecting Nonaqueous Phase Liquid (NAPL) movement and redistribution in the vadose zone after spill events. In this study, the impact of major additive components on surface and interfacial tensions for organic mixtures and wastewater was investigated. Organic mixture and wastewater compositions are based upon carbon tetrachloride (CT) mixtures released at the Hanford site, where CT was discharged simultaneously with dibutyl butyl phosphonate (DBBP), tributyl phosphate (TBP), dibutyl phosphate (DBP), and a machining lard oil (LO). A considerable amount of wastewater consisting primarily of nitrates and metal salts was also discharged. The tension values measured in this study revealed that the addition of these additive components caused a significant lowering of the interfacial tension with water or wastewater and the surface tension of the wastewater phase in equilibrium with the organic mixtures, compared to pure CT, but had minimal effect on the surface tension of the NAPL itself. These results lead to large differences in spreading coefficients for several mixtures, where the additives caused both a higher (more spreading) initial spreading coefficient and a lower (less spreading) equilibrium spreading coefficient. This indicates that if these mixtures migrate into uncontaminated areas, they will tend to spread quickly, but form a higher residual NAPL saturation after equilibrium, as compared to pure CT. Over time, CT likely volatilizes more rapidly than other components in the originally disposed mixtures and the lard oil and phosphates would become more concentrated in the remaining NAPL, resulting in a lower interfacial tension for the mixture. Spreading coefficients are expected to increase and perhaps change the equilibrated organic mixtures from nonspreading to spreading in water-wetting porous media. These results show that the behavior of organic chemical mixtures should be accounted for in numerical flow and transport models.

  2. HYDROGEL TRACER BEADS: THE DEVELOPMENT, MODIFICATION, AND TESTING OF AN INNOVATIVE TRACER FOR BETTER UNDERSTANDING LNAPL TRANSPORT IN KARST AQUIFERS

    SciTech Connect (OSTI)

    Amanda Laskoskie, Harry M. Edenborn, and Dorothy J. Vesper

    2012-01-01

    The goal of this specific research task is to develop proxy tracers that mimic contaminant movement to better understand and predict contaminant fate and transport in karst aquifers. Hydrogel tracer beads are transported as a separate phase than water and can used as a proxy tracer to mimic the transport of non-aqueous phase liquids (NAPL). They can be constructed with different densities, sizes & chemical attributes. This poster describes the creation and optimization of the beads and the field testing of buoyant beads, including sampling, tracer analysis, and quantitative analysis. The buoyant beads are transported ahead of the dissolved solutes, suggesting that light NAPL (LNAPL) transport in karst may occur faster than predicted from traditional tracing techniques. The hydrogel beads were successful in illustrating this enhanced transport.

  3. Acoustically enhanced remediation of contaminated soils and ground water. Volume 1

    SciTech Connect (OSTI)

    1995-10-01

    The Phase 1 laboratory bench-scale investigation results have shown that acoustically enhanced remediation (AER) technology can significantly accelerate the ground water remediation of non-aqueous phase liquids (NAPLs) in unconsolidated soils. The testing also determined some of the acoustic parameters which maximize fluid and contaminant extraction rates. A technology merit and trade analysis identified the conditions under which AER could be successfully deployed in the field, and an analysis of existing acoustical sources and varying methods for their deployment found that AER technology can be successfully deployed in-situ. Current estimates of deployability indicate that a NAPL plume 150 ft in diameter can be readily remediated. This program focused on unconsolidated soils because of the large number of remediation sites located in this type of hydrogeologic setting throughout the nation. It also focused on NAPLs and low permeability soil because of the inherent difficult in the remediation of NAPLs and the significant time and cost impact caused by contaminated low permeability soils. This overall program is recommended for Phase 2 which will address the technology scaling requirements for a field scale test.

  4. N0057000.doc

    Office of Legacy Management (LM)

    000 GJO- 2002-380- TAC GJO-PIN 13.5.1-1 Pinellas Environmental Restoration Project Northeast Site Non-Aqueous Phase Liquids Interim Measures Progress Report July through September 2002 October 2002 Prepared by U.S. Department of Energy Grand Junction Office Grand Junction, Colorado Work Performed Under DOE Contract Number DE-AC13-02GJ79491 Task Order Number ST03-107 Document Number N0057000 Contents DOE/Grand Junction Office Northeast Site NAPL Interim Measures Progress Report October 2002 Page

  5. Dynamic underground stripping to remediate a deep hydrocarbon spill

    SciTech Connect (OSTI)

    Yow, J.L. Jr.; Aines, R.D.; Newmark, R.L.

    1995-09-01

    Dynamic Underground Stripping is a combination of in situ steam injection, electrical resistance heating, and fluid extraction for rapid removal and recovery of subsurface contaminants such as solvents or fuels. Underground imaging and other measurement techniques monitor the system in situ for process control. Field tests at a deep gasoline spill at Lawrence Livermore National Laboratory recovered over 26,500 liters (7000 gallons) of gasoline during several months of field operations. Preliminary analysis of system cost and performance indicate that Dynamic Underground Stripping compares favorably with conventional pump-and-treat methods and vacuum extraction schemes for removing non-aqueous phase liquids (NAPLs) such as gasoline from deep subsurface plumes.

  6. NAPL Calculator - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Article) | SciTech Connect Journal Article: NANOFLUIDICS REVOLUTION: PROTECTING THE WORLD ONE DROP AT A TIME Citation Details In-Document Search Title: NANOFLUIDICS REVOLUTION: PROTECTING THE WORLD ONE DROP AT A TIME Nanofluidics is a technology that involves the transport of very small liquid samples, on the order of micro- or pico-liters, confined to nanoscale structures. Scientists at the Savannah River National Laboratory (SRNL) in collaboration with the University of South Carolina are

  7. Non-aqueous electrolyte for high voltage rechargeable magnesium batteries

    DOE Patents [OSTI]

    Doe, Robert Ellis; Lane, George Hamilton; Jilek, Robert E; Hwang, Jaehee

    2015-02-10

    An electrolyte for use in electrochemical cells is provided. The properties of the electrolyte include high conductivity, high Coulombic efficiency, and an electrochemical window that can exceed 3.5 V vs. Mg/Mg.sup.+2. The use of the electrolyte promotes the electrochemical deposition and dissolution of Mg without the use of any Grignard reagents, other organometallic materials, tetraphenyl borate, or tetrachloroaluminate derived anions. Other Mg-containing electrolyte systems that are expected to be suitable for use in secondary batteries are also described.

  8. Non-aqueous liquid compositions comprising ion exchange polymers

    DOE Patents [OSTI]

    Kim, Yu Seung; Lee, Kwan-Soo; Rockward, Tommy Q. T.

    2013-03-12

    Compositions, and methods of making thereof, comprising from about 1% to about 5% of a perfluorinated sulfonic acid ionomer or a hydrocarbon-based ionomer; and from about 95% to about 99% of a solvent, said solvent consisting essentially of a polyol; wherein said composition is substantially free of water and wherein said ionomer is uniformly dispersed in said solvent.

  9. Non-aqueous liquid compositions comprising ion exchange polymers

    DOE Patents [OSTI]

    Kim, Yu Seung; Lee, Kwan-Soo; Rockward, Tommy Q. T.

    2011-07-19

    Compositions, and methods of making thereof, comprising from about 1% to about 5% of a perfluorinated sulfonic acid ionomer or a hydrocarbon-based ionomer; and from about 95% to about 99% of a solvent, said solvent consisting essentially of a polyol; wherein said composition is substantially free of water and wherein said ionomer is uniformly dispersed in said solvent.

  10. Non-aqueous electrolytes for lithium ion batteries (Patent) ...

    Office of Scientific and Technical Information (OSTI)

    Further there are provided electrochemical devices employing the electrolyte and methods of making the electrolyte. Inventors: Chen, Zonghai ; Amine, Khalil Issue Date: 2015-11-12 ...

  11. Non-aqueous electrolyte for lithium-ion battery

    DOE Patents [OSTI]

    Zhang, Lu; Zhang, Zhengcheng; Amine, Khalil

    2014-04-15

    The present technology relates to stabilizing additives and electrolytes containing the same for use in electrochemical devices such as lithium ion batteries and capacitors. The stabilizing additives include triazinane triones and bicyclic compounds comprising succinic anhydride, such as compounds of Formulas I and II described herein.

  12. Superfund Record of Decision (EPA Region 2): Hooker-102nd Street Landfill, Niagara Falls, NY. (First remedial action), September 1990. Final report

    SciTech Connect (OSTI)

    Not Available

    1990-09-26

    The 22-acre Hooker-102nd Street site is a former industrial landfill in the city of Niagara Falls, Niagara County, New York. The site is adjacent to, and partially within the Niagara River's 100-year floodplain. These studies and the Remedial Investigation (RI) initiated in 1984, identified contamination in ground water, onsite and offsite soil, rivershore sediment, and within a storm sewer. Additionally, the presence of a leachate plume of non-aqueous phase liquids (NAPLs) was discovered emanating from the landfill area. The Record of Decision (ROD) is the final remedy which addresses all of the contaminated media. The primary contaminants of concern affecting the soil, sediment, and ground water are VOCs including benzene, TCE, and toluene; other organics including PCBs and phenols; and metals including arsenic.

  13. PHASE DETECTOR

    DOE Patents [OSTI]

    Kippenhan, D.O.

    1959-09-01

    A phase detector circuit is described for use at very high frequencies of the order of 50 megacycles. The detector circuit includes a pair of rectifiers inverted relative to each other. One voltage to be compared is applied to the two rectifiers in phase opposition and the other voltage to be compared is commonly applied to the two rectifiers. The two result:ng d-c voltages derived from the rectifiers are combined in phase opposition to produce a single d-c voltage having amplitude and polarity characteristics dependent upon the phase relation between the signals to be compared. Principal novelty resides in the employment of a half-wave transmission line to derive the phase opposing signals from the first voltage to be compared for application to the two rectifiers in place of the transformer commonly utilized for such purpose in phase detector circuits for operation at lower frequency.

  14. ARM - Measurement - Hydrometeor phase

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    : Hydrometeor phase Hydrometeor phase such as liquid ice or mixed phase Categories Cloud Properties Instruments The above measurement is considered scientifically relevant for the...

  15. Revised Arrangements for the Management of Solid and Non-Aqueous Radioactive Waste - 12452

    SciTech Connect (OSTI)

    Fullbrook, Michael; Walker, Johann; Macnab, Alec

    2012-07-01

    In 2010, Atomic Weapons Establishment (AWE) identified a requirement to implement revised management arrangements for the generation, storage and disposal of radioactive waste. A thorough review of the current arrangements/processes was undertaken which included both legal compliance requirements and the identification of business improvement opportunities. On completion of this review a suitable project team was established and in 2011 an integrated Radioactive Waste Management process was implemented throughout the business. Initial results have shown measurable improvements within Radioactive Waste management compliance, operator understanding and increased business efficiency. Through the development and implementation of the revised working arrangements AWE has been able to continue to demonstrate both legal compliance to its regulators along with business efficiency and effectiveness improvements. Simple to follow process maps have improved employees understanding of Radioactive Waste management requirements, provided them with easily accessible information and ensured the business operates in a single coherent manner. The implementation of a modern electronic data management system has ensured all waste related information is easily retrievable and appropriately maintained. The additional functions that have been built into the system have reduced the potential for human error and increased the overall efficiency of the Waste Management department through the use of the automated report generation functionality. (authors)

  16. Understanding the Initial Stages of Reversible Mg Deposition and Stripping in Inorganic Non-Aqueous Electrolytes

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Canepa, Pieremanuele; Gautam, Gopalakrishnan Sai; Malik, Rahul; Jayaraman, Saivenkataraman; Rong, Ziqin; Zavadil, Kevin R.; Persson, Kristin; Ceder, Gerbrand

    2015-04-08

    Multivalent (MV) battery architectures based on pairing a Mg metal anode with a high-voltage (~3 V) intercalation cathode offer a realistic design pathway toward significantly surpassing the energy storage performance of traditional Li-ion-based batteries, but there are currently only few electrolyte systems that support reversible Mg deposition. Using both static first-principles calculations and ab initio molecular dynamics, we perform a comprehensive adsorption study of several salt and solvent species at the interface of Mg metal with an electrolyte of Mg2+ and Cl–dissolved in liquid tetrahydrofuran (THF). Our findings not only provide a picture of the stable species at the interfacemore » but also explain how this system can support reversible Mg deposition, and as such, we provide insights in how to design other electrolytes for Mg plating and stripping. Furthermore, the active depositing species are identified to be (MgCl)+ monomers coordinated by THF, which exhibit preferential adsorption on Mg compared to possible passivating species (such as THF solvent or neutral MgCl2 complexes). We found that upon deposition, the energy to desolvate these adsorbed complexes and facilitate charge transfer is shown to be small (~61–46.2 kJ mol–1 to remove three THF from the strongest adsorbing complex), and the stable orientations of the adsorbed but desolvated (MgCl)+ complexes appear to be favorable for charge transfer. Finally, observations of Mg–Cl dissociation at the Mg surface at very low THF coordinations (0 and 1) suggest that deleterious Cl incorporation in the anode may occur upon plating. In the stripping process, this is beneficial by further facilitating the Mg removal reaction.« less

  17. A Pentafluorophenylboron Oxalate Additive in Non-aqueous Electrolytes 3 for Lithium Batteries

    SciTech Connect (OSTI)

    Yang, X.Q.; Li, L.F.; Lee, H.S.; Li, H.; Huang, X.J.

    2009-12-01

    A novel compound named pentafluorophenylboron oxalate (PFPBO) has been synthesized. PFPBO has a unique molecular structure containing a boron atom center with electron deficiency and an oxalate group. It is found that when PFPBO is used as additive, the solubility of lithium fluoride (LiF) or lithium oxide (Li{sub 2}O, Li{sub 2}O{sub 2}) in propylene carbonate (PC) and dimethyl carbonate (DMC) solvents can be increased dramatically. The new electrolytes show high ionic conductivity, high lithium ion transference number and good compatibility with LiMn{sub 2}O{sub 4} cathode and MCMB anode. PFPBO was synthesized with the designed structure to act as a bi-functional additive: boron-based anion receptor (BBAR) additive and stable solid electrolyte interphase (SEI) formation additive in PC-based electrolytes. The results show it does possess these two desired functionalities.

  18. Non-aqueous electrolyte for lithium-ion battery (Patent) | DOEPatents

    Office of Scientific and Technical Information (OSTI)

    Patent Number(s): 9,218,915 Application Number: 14196,840 Contract Number: W-31-109-ENG-38 Resource Relation: Patent File Date: 2014 Mar 04 Research Org: Chicago Operations ...

  19. Origin of electrochemical, structural and transport properties in non-aqueous zinc electrolytes

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Han, Sang -Don; Rajput, Nav Nidhi; Qu, Xiaohui; Pan, Baofei; He, Meinan; Ferrandon, Magali S.; Liao, Chen; Persson, Kristin A.; Burrell, Anthony K.

    2016-01-14

    Through coupled experimental analysis and computational techniques, we uncover the origin of anodic stability for a range of nonaqueous zinc electrolytes. By examination of electrochemical, structural, and transport properties of nonaqueous zinc electrolytes with varying concentrations, it is demonstrated that the acetonitrile Zn(TFSI)2, acetonitrile Zn(CF3SO3)2, and propylene carbonate Zn(TFSI)2 electrolytes can not only support highly reversible Zn deposition behavior on a Zn metal anode (≥99% of Coulombic efficiency), but also provide high anodic stability (up to ~3.8 V). The predicted anodic stability from DFT calculations is well in accordance with experimental results, and elucidates that the solvents play an importantmore » role in anodic stability of most electrolytes. Molecular dynamics (MD) simulations were used to understand the solvation structure (e.g., ion solvation and ionic association) and its effect on dynamics and transport properties (e.g., diffusion coefficient and ionic conductivity) of the electrolytes. Lastly, the combination of these techniques provides unprecedented insight into the origin of the electrochemical, structural, and transport properties in nonaqueous zinc electrolytes« less

  20. Non-aqueous liquid compositions comprising ion exchange polymers reference to related application

    DOE Patents [OSTI]

    Kim; Yu Seung , Lee; Kwan-Soo , Rockward; Tommy Q. T.

    2012-08-07

    Compositions, and methods of making thereof, comprising from about 1% to about 5% of a perfluorinated sulfonic acid ionomer or a hydrocarbon-based ionomer; and from about 95% to about 99% of a solvent, said solvent consisting essentially of a polyol; wherein said composition is substantially free of water and wherein said ionomer is uniformly dispersed in said solvent.

  1. Intermetallic negative electrodes for non-aqueous lithium cells and batteries

    DOE Patents [OSTI]

    Thackeray, Michael M.; Vaughey, John T.; Johnson, Christopher S.; Fransson, Linda M.; Edstrom, Ester Kristina; Henriksen, Gary

    2004-05-04

    A method of operating an electrochemical cell is disclosed. The cell has an intermetallic negative electrode of Cu.sub.6-x M.sub.x Sn.sub.5, wherein x is .ltoreq.3 and M is one or more metals including Si and a positive electrode containing Li in which Li is shuttled between the positive electrode and the negative electrode during charge and discharge to form a lithiated intermetallic negative electrode during charge. The voltage of the electrochemical cell is controlled during the charge portion of the charge-discharge cycles so that the potential of the lithiated intermetallic negative electrode in the fully charged electrochemical cell is less than 0.2 V but greater than 0 V versus metallic lithium.

  2. Microscopic Insights into the Electrochemical Behavior of Non-aqueous Electrolytes in Supercapacitors

    SciTech Connect (OSTI)

    Jiang, Deen; Wu, Jianzhong

    2013-01-01

    Electric double-layer capacitors (EDLC) are electrical devices that store energy by adsorption of ionic species at the inner surface of porous electrodes. Compared with aqueous electrolytes, ionic liquid and organic electrolytes have the advantage of larger potential windows, making them attractive for the next generation of EDLC with superior energy and power densities. The performance of both ionic liquid and organic electrolyte EDLC hinges on the judicious selection of the electrode pore size and the electrolyte composition that requires a comprehension of the charging behavior from a microscopic view. In this perspective, we discuss predictions from the classical density functional theory (CDFT) on the dependence of the capacitance on the pore size for ionic-liquid and organic-electrolyte EDLC. CDFT is applicable to electrodes with the pore size ranging from that below the ionic dimensionality to mesoscopic scales, thus unique for investigating the electrochemical behavior of the confined electrolytes for EDLC applications.

  3. Non-aqueous electrolyte for lithium-ion battery (Patent) | DOEPatents

    Office of Scientific and Technical Information (OSTI)

    and R.sup.4 are each independently hydrogen, halogen, alkyl, alkenyl, alkynyl, ... of R.sup.5, and R.sup.6 are other than hydrogen, alkyl, or alkenyl; and if the ...

  4. Non-aqueous electrolyte for lithium-ion battery (Patent) | DOEPatents

    Office of Scientific and Technical Information (OSTI)

    Inventors: Zhang, Lu ; Zhang, Zhengcheng ; Amine, Khalil Issue Date: 2014-04-15 OSTI Identifier: 1129197 Assignee: UChicago Argonne, LLC (Chicago, IL) ANL Patent Number(s): ...

  5. Liquid Catholyte Molecules for Non-aqueous Redox Flow Batteries - Joint

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Liquefied Natural Gas Liquefied Natural Gas Liquefied Natural Gas Natural gas plays a vital role in the U.S. energy supply and in achieving the nation's economic and environmental goals. One of several supply options involves increasing imports of liquefied natural gas (LNG) to ensure that American consumers have adequate supplies of natural gas for the future. Natural gas consumption in the United States is expected to increase slightly from about 24.3 trillion cubic feet (Tcf) in 2011 to 26.6

  6. Non-aqueous electrolyte for lithium-ion battery (Patent) | DOEPatents

    Office of Scientific and Technical Information (OSTI)

    States) Sponsoring Org: USDOE Country of Publication: United States Language: English Subject: 36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

  7. Understanding the Initial Stages of Reversible Mg Deposition and Stripping in Inorganic Non-Aqueous Electrolytes

    SciTech Connect (OSTI)

    Canepa, Pieremanuele; Gautam, Gopalakrishnan Sai; Malik, Rahul; Jayaraman, Saivenkataraman; Rong, Ziqin; Zavadil, Kevin R.; Persson, Kristin; Ceder, Gerbrand

    2015-04-08

    Multivalent (MV) battery architectures based on pairing a Mg metal anode with a high-voltage (~3 V) intercalation cathode offer a realistic design pathway toward significantly surpassing the energy storage performance of traditional Li-ion-based batteries, but there are currently only few electrolyte systems that support reversible Mg deposition. Using both static first-principles calculations and ab initio molecular dynamics, we perform a comprehensive adsorption study of several salt and solvent species at the interface of Mg metal with an electrolyte of Mg2+ and Cldissolved in liquid tetrahydrofuran (THF). Our findings not only provide a picture of the stable species at the interface but also explain how this system can support reversible Mg deposition, and as such, we provide insights in how to design other electrolytes for Mg plating and stripping. Furthermore, the active depositing species are identified to be (MgCl)+ monomers coordinated by THF, which exhibit preferential adsorption on Mg compared to possible passivating species (such as THF solvent or neutral MgCl2 complexes). We found that upon deposition, the energy to desolvate these adsorbed complexes and facilitate charge transfer is shown to be small (~6146.2 kJ mol1 to remove three THF from the strongest adsorbing complex), and the stable orientations of the adsorbed but desolvated (MgCl)+ complexes appear to be favorable for charge transfer. Finally, observations of MgCl dissociation at the Mg surface at very low THF coordinations (0 and 1) suggest that deleterious Cl incorporation in the anode may occur upon plating. In the stripping process, this is beneficial by further facilitating the Mg removal reaction.

  8. NGNP PHASE I REVIEW

    Broader source: Energy.gov (indexed) [DOE]

    NGNP PHASE I REVIEW NEAC REACTOR TECHNOLOGY SUBCOMMITTEE CURRENT STATUS DECEMBER 9, 2010 EPACT 2005 REQUIREMENTS * FIRST PROJECT PHASE REVIEW-On a determination by the Secretary...

  9. CrowdPhase: crowdsourcing the phase problem

    SciTech Connect (OSTI)

    Jorda, Julien; Sawaya, Michael R. [Institute for Genomics and Proteomics, 611 Charles Young Drive East, Los Angeles, CA 90095 (United States); Yeates, Todd O., E-mail: yeates@mbi.ucla.edu [Institute for Genomics and Proteomics, 611 Charles Young Drive East, Los Angeles, CA 90095 (United States); Molecular Biology Institute, 611 Charles Young Drive East, Los Angeles, CA 90095 (United States); University of California, 611 Charles Young Drive East, Los Angeles, CA 90095 (United States)

    2014-06-01

    The idea of attacking the phase problem by crowdsourcing is introduced. Using an interactive, multi-player, web-based system, participants work simultaneously to select phase sets that correspond to better electron-density maps in order to solve low-resolution phasing problems. The human mind innately excels at some complex tasks that are difficult to solve using computers alone. For complex problems amenable to parallelization, strategies can be developed to exploit human intelligence in a collective form: such approaches are sometimes referred to as crowdsourcing. Here, a first attempt at a crowdsourced approach for low-resolution ab initio phasing in macromolecular crystallography is proposed. A collaborative online game named CrowdPhase was designed, which relies on a human-powered genetic algorithm, where players control the selection mechanism during the evolutionary process. The algorithm starts from a population of individuals, each with a random genetic makeup, in this case a map prepared from a random set of phases, and tries to cause the population to evolve towards individuals with better phases based on Darwinian survival of the fittest. Players apply their pattern-recognition capabilities to evaluate the electron-density maps generated from these sets of phases and to select the fittest individuals. A user-friendly interface, a training stage and a competitive scoring system foster a network of well trained players who can guide the genetic algorithm towards better solutions from generation to generation via gameplay. CrowdPhase was applied to two synthetic low-resolution phasing puzzles and it was shown that players could successfully obtain phase sets in the 30 phase error range and corresponding molecular envelopes showing agreement with the low-resolution models. The successful preliminary studies suggest that with further development the crowdsourcing approach could fill a gap in current crystallographic methods by making it possible to extract meaningful information in cases where limited resolution might otherwise prevent initial phasing.

  10. Biotic and Abiotic Transformation of a Volatile Organics Plume in a Semi-Arid Vadose Zone

    SciTech Connect (OSTI)

    Studer, J.E.; Singletary, M.A.; Miller, D.R.

    1999-04-08

    An evaluation of biotic and abiotic attenuation processes potentially important to chlorinated and non-chlorinated volatile organic compound (VOC) fate and transport in the 148 meter thick vadose zone beneath the Chemical Waste Landfill (CWL) was conducted. A unique feature of this evaluation is the comparison of two estimates of VOC mass present in the soil gas, pore-water, and solid phases (but not including mass as non-aqueous phase liquid [NAPL]) of the vadose zone in 1993. One estimate, 1,800 kg, was obtained from vadose zone transport modeling that incorporated molecular diffusion and volatilization to the atmosphere, but not biotic or chemical processes. The other estimate, 2,120 kg, was obtained from the sum of VOC mass physically removed during soil vapor extraction and an estimate of VOC mass remaining in the vadose zone in 1998, both adjusted to exclude NAPL mass. This comparison indicates that biogeochemical processes were at best slightly important to historical VOC plume development. Some evidence of aerobic degradation of non-chlorinated VOCs and abiotic transformation of 1,1,1-Trichloroethane was identified. Despite potentially amenable site conditions, no evidence was found of cometabolic and anaerobic transformation pathways. Relying principally on soil-gas analytical results, an upper-bound estimate of 21% mass reduction due to natural biogeochemical processes was developed. Although available information for the CWL indicates that natural attenuation processes other than volatilization to the atmosphere did not effective y enhance groundwater protection, these processes could be important in significantly reducing groundwater contamination and exposure risks at other sites. More laboratory and field research is required to improve our collective ability to characterize and exploit natural VOC attenuation processes, especially with respect to the combination of relatively thick and dry vadose zones and chlorinated VOCs.

  11. Mass transfer and biodegradation of PAH compounds from coal tar. Quarterly technical report, January--March 1993

    SciTech Connect (OSTI)

    Ramaswami, A.; Ghoshal, S.; Luthy, R.G.

    1994-09-01

    This study examines the role of physico-chemical mass transfer processes on the rate of biotransformation of polycyclic aromatic hydrocarbon (PAH) compounds released from non-aqueous phase liquid (NAPL) coal tar present at residual saturation within a microporous medium. A simplified coupled dissolution-degradation model is developed that describes the concurrent mass transfer and biokinetic processes occurring in the system. Model results indicate that a dimensionless Damkohler number can be utilized to distinguish between systems that are mass transfer limited, and those that are limited by biological phenomena. The Damkohler number is estimated from independent laboratory experiments that measure the rates of aqueous phase dissolution and biodegradation of naphthalene from coal tar. Experimental data for Stroudsburg coal tar imbibed within 236 {mu}m diameter silica particles yield Damkohler numbers smaller than unity, indicating, for the particular system under study, that the overall rate of biotransformation of naphthalene is not limited by the mass transfer of naphthalene from coal tar to the bulk aqueous phase. There is a need for investigation of mass transfer for larger particles and/or other PAH compounds, and study of microbial rate-limiting phenomena including toxicity, inhibition and competitive substrate utilization.

  12. Digital quadrature phase detection

    DOE Patents [OSTI]

    Smith, J.A.; Johnson, J.A.

    1992-05-26

    A system for detecting the phase of a frequency or phase modulated signal that includes digital quadrature sampling of the frequency or phase modulated signal at two times that are one quarter of a cycle of a reference signal apart, determination of the arctangent of the ratio of a first sampling of the frequency or phase modulated signal to the second sampling of the frequency or phase modulated signal, and a determination of quadrant in which the phase determination is increased by 2[pi] when the quadrant changes from the first quadrant to the fourth quadrant and decreased by 2[pi] when the quadrant changes from the fourth quadrant to the first quadrant whereby the absolute phase of the frequency or phase modulated signal can be determined using an arbitrary reference convention. 6 figs.

  13. Digital quadrature phase detection

    DOE Patents [OSTI]

    Smith, James A.; Johnson, John A.

    1992-01-01

    A system for detecting the phase of a frequency of phase modulated signal that includes digital quadrature sampling of the frequency or phase modulated signal at two times that are one quarter of a cycle of a reference signal apart, determination of the arctangent of the ratio of a first sampling of the frequency or phase modulated signal to the second sampling of the frequency or phase modulated signal, and a determination of quadrant in which the phase determination is increased by 2.pi. when the quadrant changes from the first quadrant to the fourth quadrant and decreased by 2.pi. when the quadrant changes from the fourth quadrant to the first quadrant whereby the absolute phase of the frequency or phase modulated signal can be determined using an arbitrary reference convention.

  14. Cori Phase I

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    I Cori Phase I The Cori Phase 1 (also known as the "Cori Data Partition") system is based on Intel Haswell processors and provides approximately the same sustained application performance as Hopper (which was retired in Dec 2015). Cori Phase 1 has an almost identical programming environment to Edison with support for the Intel, Cray and GNU programming environments with the same Cray and Intel high performance math and scientific libraries. The Cori Phase 1 interconnect has the same

  15. Northeast Site Area A NAPL Remediation Final Report.doc

    Office of Legacy Management (LM)

    ... waste acceptance criteria, and appropriate ... in a waste management cost savings. 3. The base material of sand and crushed limestone was used to level low areas and ...

  16. Phase-field Modeling of Displacive Phase Transformations in Elasticall...

    Office of Scientific and Technical Information (OSTI)

    Phase-field Modeling of Displacive Phase Transformations in Elastically Anisotropic and Inhomogeneous Polycrystals Citation Details In-Document Search Title: Phase-field Modeling...

  17. Crystal phase identification

    DOE Patents [OSTI]

    Michael, Joseph R.; Goehner, Raymond P.; Schlienger, Max E.

    2001-01-01

    A method and apparatus for determining the crystalline phase and crystalline characteristics of a sample. This invention provides a method and apparatus for unambiguously identifying and determining the crystalline phase and crystalline characteristics of a sample by using an electron beam generator, such as a scanning electron microscope, to obtain a backscattered electron Kikuchi pattern of a sample, and extracting crystallographic and composition data that is matched to database information to provide a quick and automatic method to identify crystalline phases.

  18. The in-situ decontamination of sand and gravel aquifers by chemically enhanced solubilization of multiple-compound DNAPLs with surfactant solutions: Phase 1 -- Laboratory and pilot field-scale testing and Phase 2 -- Solubilization test and partitioning and interwell tracer tests. Final report

    SciTech Connect (OSTI)

    1997-10-24

    Laboratory, numerical simulation, and field studies have been conducted to assess the potential use of micellar-surfactant solutions to solubilize chlorinated solvents contaminating sand and gravel aquifers. Ninety-nine surfactants were screened for their ability to solubilize trichloroethene (TCE), perchloroethylene (PCE), and carbon tetrachloride (CTET). The field test was conducted in the alluvial aquifer which is located 20 to 30 meters beneath a vapor degreasing operation at Paducah Gaseous Diffusion Plant. This aquifer has become contaminated with TCE due to leakage of perhaps 40,000 liters of TCE, which has generated a plume of dissolved TCE extending throughout an area of approximately 3 km{sup 2} in the aquifer. Most of the TCE is believed to be present in the overlying lacustrine deposits and in the aquifer itself as a dense, non-aqueous phase liquid, or DNAPL. The objective of the field test was to assess the efficacy of the surfactant for in situ TCE solubilization. Although the test demonstrated that sorbitan monooleate was unsuitable as a solubilizer in this aquifer, the single-well test was demonstrated to be a viable method for the in situ testing of surfactants or cosolvents prior to proceeding to full-scale remediation.

  19. UPVG phase 2 report

    SciTech Connect (OSTI)

    1995-08-01

    The Utility PhotoVoltaic Group (UPVG), supported by member dues and a grant from the US Department of Energy, has as its mission the acceleration of the use of cost-effective small-scale and emerging large-scale applications of photovoltaics for the benefit of electric utilities and their customers. Formed in October, 1992, with the support of the American Public Power Association, Edison Electric Institute, and the National Rural Electric Cooperative Association, the UPVG currently has 90 members from all sectors of the electric utility industry. The UPVG`s efforts as conceived were divided into four phases: Phase 0--program plan; Phase 1--organization and strategy development; Phase 2--creating market assurance; and Phase 3--higher volume purchases. The Phase 0 effort developed the program plan and was completed early in 1993. The Phase 1 goal was to develop the necessary background information and analysis to lead to a decision as to which strategies could be undertaken by utilities to promote greater understanding of PV markets and achieve increased volumes of PV purchases. This report provides the details of the UPVG`s Phase 2 efforts to initiate TEAM-UP, its multiyear, 50-MW hardware initiative.

  20. ELECTRONIC PHASE CONTROL CIRCUIT

    DOE Patents [OSTI]

    Salisbury, J.D.; Klein, W.W.; Hansen, C.F.

    1959-04-21

    An electronic circuit is described for controlling the phase of radio frequency energy applied to a multicavity linear accelerator. In one application of the circuit two cavities are excited from a single radio frequency source, with one cavity directly coupled to the source and the other cavity coupled through a delay line of special construction. A phase detector provides a bipolar d-c output signal proportional to the difference in phase between the voltage in the two cavities. This d-c signal controls a bias supply which provides a d-c output for varying the capacitnce of voltage sensitive capacitors in the delay line. The over-all operation of the circuit is completely electronic, overcoming the time response limitations of the electromechanical control systems, and the relative phase relationship of the radio frequency voltages in the two caviiies is continuously controlled to effect particle acceleration.

  1. PHYSICAL SCIENCES, Physics Phase

    Office of Scientific and Technical Information (OSTI)

    SCIENCES, Physics Phase competition in trisected superconducting dome I. M. Vishik, 1, 2 M Hashimoto, 3 R.-H. He, 4 W. S. Lee, 1, 2 F. Schmitt, 1, 2 D. H. Lu, 3 R. G. Moore, 1...

  2. Electron microscope phase enhancement

    DOE Patents [OSTI]

    Jin, Jian; Glaeser, Robert M.

    2010-06-15

    A microfabricated electron phase shift element is used for modifying the phase characteristics of an electron beam passing though its center aperture, while not affecting the more divergent portion of an incident beam to selectively provide a ninety-degree phase shift to the unscattered beam in the back focal plan of the objective lens, in order to realize Zernike-type, in-focus phase contrast in an electron microscope. One application of the element is to increase the contrast of an electron microscope for viewing weakly scattering samples while in focus. Typical weakly scattering samples include biological samples such as macromolecules, or perhaps cells. Preliminary experimental images demonstrate that these devices do apply a ninety degree phase shift as expected. Electrostatic calculations have been used to determine that fringing fields in the region of the scattered electron beams will cause a negligible phase shift as long as the ratio of electrode length to the transverse feature-size aperture is about 5:1. Calculations are underway to determine the feasibility of aspect smaller aspect ratios of about 3:1 and about 2:1.

  3. Combustion 2000: Phase II

    SciTech Connect (OSTI)

    Unknown

    1999-11-01

    The goals of the program are to develop a coal-fired high performance power generation system (HIPPS) that is capable of: thermal efficiency (HHV) {ge} 47%; NOx, SOx, and particulates {le} 10% NSPS (New Source Performance Standard); coal providing {ge} 65% of heat input; all solid wastes benign; and cost of electricity {le} 90% of present plants. Phase 1, which began in 1992, focused on the analysis of various configurations of indirectly fired cycles and on technical assessments of alternative plant subsystems and components, including performance requirements, developmental status, design options, complexity and reliability, and capital and operating costs. Phase 1 also included preliminary R and D and the preparation of designs for HIPPS commercial plants approximately 300 MWe in size. This Phase, Phase 2, had as its initial objective the development of a complete design base for the construction and operation of a HIPPS prototype plant to be constructed in Phase 3. As part of a descoping initiative, the Phase 3 program has been eliminated and work related to the commercial plant design has been ended. The rescoped program retained a program of engineering research and development focusing on high temperature heat exchangers, e.g. HITAF development (Task 2); a rescoped Task 6 that is pertinent to Vision 21 objectives and focuses on advanced cycle analysis and optimization, integration of gas turbines into complex cycles, and repowering designs; and preparation of the Phase 2 Technical Report (Task 8). This rescoped program deleted all subsystem testing (Tasks 3, 4,and 5) and the development of a site-specific engineering design and test plan for the HIPPS prototype plant (Task 7). Work reported herein is from: Task 2.1 HITAF Combustors; Task 2.2 HITAF Air Heaters; and Task 6 HIPPS Commercial Plant Design Update.

  4. Literature search for the non-aqueous separation of zinc from fuel rod cladding. [After dissolution in liquid metal

    SciTech Connect (OSTI)

    Sandvig, R. L.; Dyer, S. J.; Lambert, G. A.; Baldwin, C. E.

    1980-06-21

    This report reviews the literature of processes for the nonaqueous separation of zinc from dissolved fuel assembly cladding. The processes considered were distillation, pyrochemical processing, and electrorefining. The last two techniques were only qualitatively surveyed while the first, distillation, was surveyed in detail. A survey of available literature from 1908 through 1978 on the distillation of zinc was performed. The literature search indicated that a zinc recovery rate in excess of 95% is possible; however, technical problems exist because of the high temperatures required and the corrosive nature of liquid zinc. The report includes a bibliography of the surveyed literature and a computer simulation of vapor pressures in binary systems. 129 references.

  5. Protein-style dynamical transition in a non-biological polymer and a non-aqueous solvent

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Mamontov, E.; Sharma, V. K.; Borreguero, J. M.; Tyagi, M.

    2016-03-15

    Using neutron scattering and molecular dynamics simulation, techniques most often associated with protein dynamical transition studies, we have investigated the microscopic dynamics of one of the most common polymers, polystyrene, which was exposed to toluene vapor, mimicking the process of protein hydration from water vapor. Polystyrene with adsorbed toluene is an example of a solvent-solute system, which, unlike biopolymers, is anhydrous and lacks hydrogen bonding. Nevertheless, it exhibits the essential traits of the dynamical transition in biomolecules, such as a specific dependence of the microscopic dynamics of both solvent and host on the temperature and the amount of solvent adsorbed.more » Ultimately, we conclude that the protein dynamical transition is a manifestation of a universal solvent-solute dynamical relationship, which is not specific to either biomolecules as solute, or aqueous media as solvent, or even a particular type of interactions between solvent and solute.« less

  6. Synthesis and studies of boron based anion receptors and their use in non-aqueous electrolytes for lithium batteries

    SciTech Connect (OSTI)

    Sun, X.; Yang, X.Q.; Lee, H.S.; McBreen, J.; Choi, L.S.

    1998-12-31

    A new family of anion receptors based on boron compounds has been synthesized. These compounds can be used as anion receptors in lithium battery electrolytes and can greatly increase solubility and ionic conductivities of various lithium salts, such as LiF, LiCl, CF{sub 3}COOLi and C{sub 2}F{sub 5}COOLi, in DME solutions. Near Edge X-ray Absorption Fine Structure (NEXAFS) spectroscopy studies show that Cl{sup {minus}} anions of LiCl are complexed with these compounds in DME solutions. The electrochemical stability of lithium salts and one of the boron compounds in deferent solvents was studied. For the first time, LiF has been successfully used as conducting salt in a novel electrolyte with this boron compound as an additive in DME. A rechargeable Li/LiMn{sub 2}O{sub 4} cell using this electrolyte was successfully cycled 51 times. However, the capacity fades with cycling due to decomposition of the solvent. The cycling performance of the battery was greatly improved by replacing DME with PC-EC-DMC as the solvent.

  7. Kinetic investigation of catalytic disproportionation of superoxide ions in the non-aqueous electrolyte used in Li-air batteries

    SciTech Connect (OSTI)

    Wang, Qiang; Yang, Xiao -Qing; Zheng, Doug; McKinnon, Meaghan E.; Qu, Deyang

    2014-10-28

    Superoxide reacts with carbonate solvents in Liair batteries. Tris(pentafluorophenyl)borane is found to catalyze a more rapid superoxide (O2-) disproportionation reaction than the reaction between superoxide and propylene carbonate (PC). With this catalysis, the negative impact of the reaction between the electrolyte and O2-produced by the O2 reduction can be minimized. A simple kinetic study using ESR spectroscopy was reported to determine reaction orders and rate constants for the reaction between PC and superoxide, and the disproportionation of superoxide catalyzed by Tris(pentafluorophenyl)borane and Li ions. The reactions are found to be first order and the rate constants are 0.033 s-1 M-1, 0.020 s-1 M-1and 0.67 s-1M-1 for reactions with PC, Li ion and Tris(pentafluorophenyl)borane, respectively.

  8. Kinetic investigation of catalytic disproportionation of superoxide ions in the non-aqueous electrolyte used in Liair batteries

    SciTech Connect (OSTI)

    Wang, Qiang; Zheng, Dong; McKinnon, Meaghan E.; Yang, Xiao -Qing; Qu, Deyang

    2014-10-28

    Superoxide reacts with carbonate solvents in Liair batteries. Tris(pentafluorophenyl)borane is found to catalyze a more rapid superoxide (O2-) disproportionation reaction than the reaction between superoxide and propylene carbonate (PC). With this catalysis, the negative impact of the reaction between the electrolyte and O2-produced by the O2 reduction can be minimized. A simple kinetic study using ESR spectroscopy was reported to determine reaction orders and rate constants for the reaction between PC and superoxide, and the disproportionation of superoxide catalyzed by Tris(pentafluorophenyl)borane and Li ions. As a result, the reactions are found to be first order and the rate constants are 0.033 s-1 M-1, 0.020 s-1 M-1and 0.67 s-1M-1 for reactions with PC, Li ion and Tris(pentafluorophenyl)borane, respectively.

  9. Compatibility of Lithium Salts with Solvent of the Non-Aqueous Electrolyte in LiO2 Batteries

    SciTech Connect (OSTI)

    Du, Peng; Lu, Jun; Lau, Kah Chun; Luo, Xiangyi; Bareno, Javier; Zhang, Xiaoyi; Ren, Yang; Zhang, Zhengcheng; Curtiss, Larry A.; Sun, Yang-Kook; Amine, Khalil

    2013-02-20

    The stability of lithium salts, especially in the presence of reduced oxygen species, O2 and H2O (even in a small amount), plays an important role in the cyclability and capacity of LiO2 cells. This combined experimental and computational study provides evidence that the stability of the electrolyte used in LiO2 cells strongly depends on the compatibility of lithium salts with solvent. In the case of the LiPF61NM3 electrolyte, the decomposition of LiPF6 occurs in the cell as evidenced by in situ XRD, FT-IR and XPS analysis, which triggers the decomposition of 1NM3 solvent due to formation of HF from the decomposition of LiPF6. These reactions lead to degradation of the electrolyte and cause poor cyclability of the cell. The same reactions are not observed when LiTFSI and LiCF3SO3 are used as the lithium salts in 1NM3 solvent, or LiPF6 is used in TEGDME solvent.

  10. Kinetic investigation of catalytic disproportionation of superoxide ions in the non-aqueous electrolyte used in Li-air batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wang, Qiang; Yang, Xiao -Qing; Zheng, Doug; McKinnon, Meaghan E.; Qu, Deyang

    2014-10-28

    Superoxide reacts with carbonate solvents in Liair batteries. Tris(pentafluorophenyl)borane is found to catalyze a more rapid superoxide (O2-) disproportionation reaction than the reaction between superoxide and propylene carbonate (PC). With this catalysis, the negative impact of the reaction between the electrolyte and O2-produced by the O2 reduction can be minimized. A simple kinetic study using ESR spectroscopy was reported to determine reaction orders and rate constants for the reaction between PC and superoxide, and the disproportionation of superoxide catalyzed by Tris(pentafluorophenyl)borane and Li ions. The reactions are found to be first order and the rate constants are 0.033 s-1 M-1,more0.020 s-1 M-1and 0.67 s-1M-1 for reactions with PC, Li ion and Tris(pentafluorophenyl)borane, respectively.less

  11. Kinetic investigation of catalytic disproportionation of superoxide ions in the non-aqueous electrolyte used in Li–air batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wang, Qiang; Zheng, Dong; McKinnon, Meaghan E.; Yang, Xiao -Qing; Qu, Deyang

    2014-10-28

    Superoxide reacts with carbonate solvents in Li–air batteries. Tris(pentafluorophenyl)borane is found to catalyze a more rapid superoxide (O2-) disproportionation reaction than the reaction between superoxide and propylene carbonate (PC). With this catalysis, the negative impact of the reaction between the electrolyte and O2-produced by the O2 reduction can be minimized. A simple kinetic study using ESR spectroscopy was reported to determine reaction orders and rate constants for the reaction between PC and superoxide, and the disproportionation of superoxide catalyzed by Tris(pentafluorophenyl)borane and Li ions. As a result, the reactions are found to be first order and the rate constants aremore » 0.033 s-1 M-1, 0.020 s-1 M-1and 0.67 s-1M-1 for reactions with PC, Li ion and Tris(pentafluorophenyl)borane, respectively.« less

  12. Linear phase compressive filter

    DOE Patents [OSTI]

    McEwan, Thomas E.

    1995-01-01

    A phase linear filter for soliton suppression is in the form of a laddered series of stages of non-commensurate low pass filters with each low pass filter having a series coupled inductance (L) and a reverse biased, voltage dependent varactor diode, to ground which acts as a variable capacitance (C). L and C values are set to levels which correspond to a linear or conventional phase linear filter. Inductance is mapped directly from that of an equivalent nonlinear transmission line and capacitance is mapped from the linear case using a large signal equivalent of a nonlinear transmission line.

  13. Linear phase compressive filter

    DOE Patents [OSTI]

    McEwan, T.E.

    1995-06-06

    A phase linear filter for soliton suppression is in the form of a laddered series of stages of non-commensurate low pass filters with each low pass filter having a series coupled inductance (L) and a reverse biased, voltage dependent varactor diode, to ground which acts as a variable capacitance (C). L and C values are set to levels which correspond to a linear or conventional phase linear filter. Inductance is mapped directly from that of an equivalent nonlinear transmission line and capacitance is mapped from the linear case using a large signal equivalent of a nonlinear transmission line. 2 figs.

  14. Cori Phase II

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    II Cori Phase II Cori Phase-2 system will be a Cray XC system based on the second generation of Intel® Xeon Phi(tm) Product Family, called Knights Landing (KNL) Many Integrated Core (MIC) Architecture. The system will have a sustained performance that is at least ten times that of the NERSC-6 "Hopper" system, based on a set of characteristic benchmarks. Some important characteristics of the system include: Knights Landing is a self-hosted architecture, not a co-processor, not an

  15. DELTA PHASE PLUTONIUM ALLOYS

    DOE Patents [OSTI]

    Cramer, E.M.; Ellinger, F.H.; Land. C.C.

    1960-03-22

    Delta-phase plutonium alloys were developed suitable for use as reactor fuels. The alloys consist of from 1 to 4 at.% zinc and the balance plutonium. The alloys have good neutronic, corrosion, and fabrication characteristics snd possess good dimensional characteristics throughout an operating temperature range from 300 to 490 deg C.

  16. Phase change compositions

    DOE Patents [OSTI]

    Salyer, Ival O.; Griffen, Charles W.

    1986-01-01

    Compositions containing crystalline, long chain, alkyl hydrocarbons as phase change materials including cementitious compositions containing the alkyl hydrocarbons neat or in pellets or granules formed by incorporating the alkyl hydrocarbons in polymers or rubbers; and polymeric or elastomeric compositions containing alkyl hydrocarbons.

  17. Phase change compositions

    DOE Patents [OSTI]

    Salyer, Ival O.

    1989-01-01

    Compositions containing crystalline, straight chain, alkyl hydrocarbons as phase change materials including cementitious compositions containing the alkyl hydrocarbons neat or in pellets or granules formed by incorporating the alkyl hydrocarbons in polymers or rubbers; and polymeric or elastomeric compositions containing alkyl hydrocarbons.

  18. Phase II Final Report

    SciTech Connect (OSTI)

    Schuknecht, Nate; White, David; Hoste, Graeme

    2014-09-11

    The SkyTrough DSP will advance the state-of-the-art in parabolic troughs for utility applications, with a larger aperture, higher operating temperature, and lower cost. The goal of this project was to develop a parabolic trough collector that enables solar electricity generation in the 2020 marketplace for a 216MWe nameplate baseload power plant. This plant requires an LCOE of 9¢/kWhe, given a capacity factor of 75%, a fossil fuel limit of 15%, a fossil fuel cost of $6.75/MMBtu, $25.00/kWht thermal storage cost, and a domestic installation corresponding to Daggett, CA. The result of our optimization was a trough design of larger aperture and operating temperature than has been fielded in large, utility scale parabolic trough applications: 7.6m width x 150m SCA length (1,118m2 aperture), with four 90mm diameter × 4.7m receivers per mirror module and an operating temperature of 500°C. The results from physical modeling in the System Advisory Model indicate that, for a capacity factor of 75%: The LCOE will be 8.87¢/kWhe. SkyFuel examined the design of almost every parabolic trough component from a perspective of load and performance at aperture areas from 500 to 2,900m2. Aperture-dependent design was combined with fixed quotations for similar parts from the commercialized SkyTrough product, and established an installed cost of $130/m2 in 2020. This project was conducted in two phases. Phase I was a preliminary design, culminating in an optimum trough size and further improvement of an advanced polymeric reflective material. This phase was completed in October of 2011. Phase II has been the detailed engineering design and component testing, which culminated in the fabrication and testing of a single mirror module. Phase II is complete, and this document presents a summary of the comprehensive work.

  19. Phase shifting interferometer

    DOE Patents [OSTI]

    Sommargren, Gary E.

    1999-01-01

    An interferometer which has the capability of measuring optical elements and systems with an accuracy of .lambda./1000 where .lambda. is the wavelength of visible light. Whereas current interferometers employ a reference surface, which inherently limits the accuracy of the measurement to about .lambda./50, this interferometer uses an essentially perfect spherical reference wavefront generated by the fundamental process of diffraction. Whereas current interferometers illuminate the optic to be tested with an aberrated wavefront which also limits the accuracy of the measurement, this interferometer uses an essentially perfect spherical measurement wavefront generated by the fundamental process of diffraction. This interferometer is adjustable to give unity fringe visibility, which maximizes the signal-to-noise, and has the means to introduce a controlled prescribed relative phase shift between the reference wavefront and the wavefront from the optics under test, which permits analysis of the interference fringe pattern using standard phase extraction algorithms.

  20. Phase shifting interferometer

    DOE Patents [OSTI]

    Sommargren, G.E.

    1999-08-03

    An interferometer is disclosed which has the capability of measuring optical elements and systems with an accuracy of {lambda}/1000 where {lambda} is the wavelength of visible light. Whereas current interferometers employ a reference surface, which inherently limits the accuracy of the measurement to about {lambda}/50, this interferometer uses an essentially perfect spherical reference wavefront generated by the fundamental process of diffraction. Whereas current interferometers illuminate the optic to be tested with an aberrated wavefront which also limits the accuracy of the measurement, this interferometer uses an essentially perfect spherical measurement wavefront generated by the fundamental process of diffraction. This interferometer is adjustable to give unity fringe visibility, which maximizes the signal-to-noise, and has the means to introduce a controlled prescribed relative phase shift between the reference wavefront and the wavefront from the optics under test, which permits analysis of the interference fringe pattern using standard phase extraction algorithms. 11 figs.

  1. Phase shifting diffraction interferometer

    DOE Patents [OSTI]

    Sommargren, Gary E.

    1996-01-01

    An interferometer which has the capability of measuring optical elements and systems with an accuracy of .lambda./1000 where .lambda. is the wavelength of visible light. Whereas current interferometers employ a reference surface, which inherently limits the accuracy of the measurement to about .lambda./50, this interferometer uses an essentially perfect spherical reference wavefront generated by the fundamental process of diffraction. This interferometer is adjustable to give unity fringe visibility, which maximizes the signal-to-noise, and has the means to introduce a controlled prescribed relative phase shift between the reference wavefront and the wavefront from the optics under test, which permits analysis of the interference fringe pattern using standard phase extraction algorithms.

  2. Phase shifting diffraction interferometer

    DOE Patents [OSTI]

    Sommargren, G.E.

    1996-08-29

    An interferometer which has the capability of measuring optical elements and systems with an accuracy of {lambda}/1000 where {lambda} is the wavelength of visible light. Whereas current interferometers employ a reference surface, which inherently limits the accuracy of the measurement to about {lambda}/50, this interferometer uses an essentially perfect spherical reference wavefront generated by the fundamental process of diffraction. This interferometer is adjustable to give unity fringe visibility, which maximizes the signal-to-noise, and has the means to introduce a controlled prescribed relative phase shift between the reference wavefront and the wavefront from the optics under test, which permits analysis of the interference fringe pattern using standard phase extraction algorithms. 8 figs.

  3. Solid phase extraction membrane

    DOE Patents [OSTI]

    Carlson, Kurt C [Nashville, TN; Langer, Roger L [Hudson, WI

    2002-11-05

    A wet-laid, porous solid phase extraction sheet material that contains both active particles and binder and that possesses excellent wet strength is described. The binder is present in a relatively small amount while the particles are present in a relatively large amount. The sheet material is sufficiently strong and flexible so as to be pleatable so that, for example, it can be used in a cartridge device.

  4. Gas-Phase Diagnostics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Phase Diagnostics - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs Advanced

  5. Phase Field Fracture Mechanics.

    SciTech Connect (OSTI)

    Robertson, Brett Anthony

    2015-11-01

    For this assignment, a newer technique of fracture mechanics using a phase field approach, will be examined and compared with experimental data for a bend test and a tension test. The software being used is Sierra Solid Mechanics, an implicit/explicit finite element code developed at Sandia National Labs in Albuquerque, New Mexico. The bend test experimental data was also obtained at Sandia Labs while the tension test data was found in a report online from Purdue University.

  6. Phase-field modeling of diffusional phase behaviors of solid...

    Office of Scientific and Technical Information (OSTI)

    case study of phase-separating LiXFePO4 electrode particles Citation Details In-Document ... case study of phase-separating LiXFePO4 electrode particles You are accessing a ...

  7. Phase-field Modeling of Displacive Phase Transformations in Elastically

    Office of Scientific and Technical Information (OSTI)

    Anisotropic and Inhomogeneous Polycrystals (Journal Article) | SciTech Connect Phase-field Modeling of Displacive Phase Transformations in Elastically Anisotropic and Inhomogeneous Polycrystals Citation Details In-Document Search Title: Phase-field Modeling of Displacive Phase Transformations in Elastically Anisotropic and Inhomogeneous Polycrystals Authors: Heo, T W ; Chen, L Q Publication Date: 2014-03-06 OSTI Identifier: 1169262 Report Number(s): LLNL-JRNL-651372 DOE Contract Number:

  8. Process for phase separation

    DOE Patents [OSTI]

    Comolli, Alfred G.

    1979-01-01

    This invention provides a continuous process for separating a gaseous phase from a hydrocarbon liquid containing carbonaceous particulates and gases. The liquid is fed to a cylindrical separator, with the gaseous phase being removed therefrom as an overhead product, whereas the hydrocarbon liquid and the particulates are withdrawn as a bottoms product. By feeding the liquid tangentially to the separator and maintaining a particulate-liquid slurry downward velocity of from about 0.01 to about 0.25 fps in the separator, a total solids weight percent in the slurry of from about 0.1 to about 30%, a slurry temperature of from about 550.degree. to about 900.degree. F., a slurry residence time in the separator of from about 30 to about 360 seconds, and a length/diameter ratio for the separator of from about 20/1 to about 50/1, so that the characterization factor, .alpha., defined as ##STR1## DOES NOT EXCEED ABOUT 48 (.degree.R sec.sup.2)/ft, the deposit of carbonaceous materials on the interior surface of the separator may be substantially eliminated.

  9. FORGE Phase Infographic | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    FORGE Phase Infographic FORGE Phase Infographic FORGE Phase Infographic More Documents & Publications FORGE Infographic FORGE Phase Infographic EERE Strategic Plan Infographic FORGE Phase Infographic Milford, Utah FORGE Map

  10. Helical Nanofilament Phases

    SciTech Connect (OSTI)

    L Hough; H Jung; D Kruerke; M Heberling; M Nakata; C Jones; D Chen; D Link; N Clark; et al.

    2011-12-31

    In the formation of chiral crystals, the tendency for twist in the orientation of neighboring molecules is incompatible with ordering into a lattice: Twist is expelled from planar layers at the expense of local strain. We report the ordered state of a neat material in which a local chiral structure is expressed as twisted layers, a state made possible by spatial limitation of layering to a periodic array of nanoscale filaments. Although made of achiral molecules, the layers in these filaments are twisted and rigorously homochiral - a broken symmetry. The precise structural definition achieved in filament self-assembly enables collective organization into arrays in which an additional broken symmetry - the appearance of macroscopic coherence of the filament twist-produces a liquid crystal phase of helically precessing layers.

  11. Tmvoc-React

    Energy Science and Technology Software Center (OSTI)

    2008-02-12

    The TMVOC-REACT simulator was generated by replacing the fluid and heat flow part, TOUGH2, in TOUGHREACT with TMVOC. Both programs have been distributed to the public through the US Department of Energy's Energy Science and Technology Software Center. TMVOC is a program for three-phase non-isothermal flows of multi-component hydrocarbon mixtures in variably saturated heterogeneous media. TMVOC was initially designed for studying subsurface contamination by volatile organic compounds (VOCs), such as hydrocarbon fuels and industrial solvents.more » It can model the one-, two-, or three-dimensional migration of non-aqueous phase liquids (NAPLs) through the unsaturated and saturated zones, the formation of an oil lens on the water table, the dissolution and subsequent transport of VOCs in groundwater, as well as the vaporization and migration of VOCs in the interstitial air of the unsaturated zone. TOUGHREACT is a numerical simulation program for chemically reactive nonisothermal flows of multiphase fluids in porous and fractured media. A variety of subsurface thermo-physical-chemical processes can be considered under a wide range of conditions of pressure, temperature, water saturation, ionic strength, pH and Eh. Intractions between mineral assemblages and fluids can occur under local equilibrium or kinetic rates. The gas phase can be chemically active. Precipitation and dissolution reactions can change formation porosity and permeability. The program can be applied to many geologic systems and environmental problems, including geothermal systems, diagenetic and weathering processes, subsurface waste disposal, aid mine drainage remediation, and contaminant transport.« less

  12. Phase-shifting point diffraction interferometer phase grating designs

    DOE Patents [OSTI]

    Naulleau, Patrick (Oakland, CA)

    2001-01-01

    Diffraction phase gratings are employed in phase-shifting point diffraction interferometers to improve the interferometric fringe contrast. The diffraction phase grating diffracts a zeroth-order diffraction of light at a first power level to the test-beam window of a mask that is positioned at the image plane and a first-order diffraction at a second power to the reference-beam pinhole. The diffraction phase grating is preferably selected to yield a desired ratio of the first power level to second power level.

  13. Solano Phase 3 | Open Energy Information

    Open Energy Info (EERE)

    Phase 3 Jump to: navigation, search Name Solano Phase 3 Facility Solano Phase 3 Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service Owner Sacramento...

  14. Tillamook Windfloat Phase 1 | Open Energy Information

    Open Energy Info (EERE)

    Windfloat Phase 1 Jump to: navigation, search Name Tillamook Windfloat Phase 1 Facility Tillamook Windfloat Phase 1 Sector Wind energy Facility Type Offshore Wind Facility Status...

  15. Cleveland Project Phase 2 | Open Energy Information

    Open Energy Info (EERE)

    Project Phase 2 Jump to: navigation, search Name Cleveland Project Phase 2 Facility Cleveland Project Phase 2 Sector Wind energy Facility Type Offshore Wind Facility Status...

  16. Windy Flats Phase III | Open Energy Information

    Open Energy Info (EERE)

    Phase III Jump to: navigation, search Name Windy Flats Phase III Facility Windy Flats Phase III Sector Wind energy Facility Type Commercial Scale Wind Facility Status Proposed...

  17. Digitally controlled distributed phase shifter

    DOE Patents [OSTI]

    Hietala, Vincent M. (Placitas, NM); Kravitz, Stanley H. (Placitas, NM); Vawter, Gregory A. (Albuquerque, NM)

    1993-01-01

    A digitally controlled distributed phase shifter is comprised of N phase shifters. Digital control is achieved by using N binary length-weighted electrodes located on the top surface of a waveguide. A control terminal is attached to each electrode thereby allowing the application of a control signal. The control signal is either one or two discrete bias voltages. The application of the discrete bias voltages changes the modal index of a portion of the waveguide that corresponds to a length of the electrode to which the bias voltage is applied, thereby causing the phase to change through the underlying portion of the waveguide. The digitally controlled distributed phase shift network has a total phase shift comprised of the sum of the individual phase shifters.

  18. Digitally controlled distributed phase shifter

    DOE Patents [OSTI]

    Hietala, V.M.; Kravitz, S.H.; Vawter, G.A.

    1993-08-17

    A digitally controlled distributed phase shifter is comprised of N phase shifters. Digital control is achieved by using N binary length-weighted electrodes located on the top surface of a waveguide. A control terminal is attached to each electrode thereby allowing the application of a control signal. The control signal is either one or two discrete bias voltages. The application of the discrete bias voltages changes the modal index of a portion of the waveguide that corresponds to a length of the electrode to which the bias voltage is applied, thereby causing the phase to change through the underlying portion of the waveguide. The digitally controlled distributed phase shift network has a total phase shift comprised of the sum of the individual phase shifters.

  19. Project Home Again Phase II

    SciTech Connect (OSTI)

    2010-01-30

    Phase II is a continuation of a charitable residential community project in New Orleans that builds affordable and energy efficient single detached residences that are storm resistant.

  20. Method for aqueous phase reactions

    DOE Patents [OSTI]

    Elliott, Douglas C.; Hart, Todd R.

    2000-01-01

    A method for converting liquid organic material in a mixture into a product utilizing a catalyst in the form of a plurality of porous particles wherein each particle is a support having nickel metal catalytic phase or reduced nickel deposited thereon in a first dispersed phase and an additional metal deposited onto the support in a second dispersed phase. The additional metal is effective in retarding or reducing agglomeration or sintering of the nickel metal catalytic phase without substantially affecting the catalytic activity, thereby increasing the life time of the catalyst.

  1. Phase-locked loop with controlled phase slippage

    DOE Patents [OSTI]

    Mestha, L.K.

    1994-03-29

    A system for synchronizing a first subsystem controlled by a changing frequency sweeping from a first frequency to a second frequency, with a second subsystem operating at a steady state second frequency is described. Trip plan parameters are calculated in advance to determine the phase relationship between the frequencies of the first subsystem and second subsystem in order to obtain synchronism at the end of the frequency sweep of the first subsystem. During the time in which the frequency of the first subsystem is sweeping from the first frequency to the second frequency, the phase locked system compares the actual phase difference with the trip plan phase difference and incrementally changes the sweep frequency in a manner so that phase lock is achieved when the first subsystem reaches a frequency substantially identical to that of the second subsystem. 10 figures.

  2. Phase-locked loop with controlled phase slippage

    DOE Patents [OSTI]

    Mestha, Lingappa K. (Cedar Hill, TX)

    1994-01-01

    A system for synchronizing a first subsystem controlled by a changing frequency sweeping from a first frequency to a second frequency, with a second subsystem operating at a steady state second frequency. Trip plan parameters are calculated in advance to determine the phase relationship between the frequencies of the first subsystem and second subsystem in order to obtain synchronism at the end of the frequency sweep of the first subsystem. During the time in which the frequency of the first subsystem is sweeping from the first frequency to the second frequency, the phase locked system compares the actual phase difference with the trip plan phase difference and incrementally changes the sweep frequency in a manner so that phase lock is achieved when the first subsystem reaches a frequency substantially identical to that of the second subsystem.

  3. Two-phase uninterruptible power supply

    SciTech Connect (OSTI)

    Severinsky, A.J.; Rajagopalan, S.

    1991-12-24

    This patent describes a two-phase AC power supply. It comprises AC systems; connectors; electric currents; and phase shift.

  4. Three phase downhole separator process

    DOE Patents [OSTI]

    Cognata, Louis John (Baytown, TX)

    2008-06-24

    Three Phase Downhole Separator Process (TPDSP) is a process which results in the separation of all three phases, (1) oil, (2) gas, and (3) water, at the downhole location in the well bore, water disposal injection downhole, and oil and gas production uphole.

  5. Phase-sensitive flow cytometer

    DOE Patents [OSTI]

    Steinkamp, John A.

    1993-01-01

    A phase-sensitive flow cytometer (FCM) provides additional FCM capability to use the fluorescence lifetime of one or more fluorochromes bound to single cells to provide additional information regarding the cells. The resulting fluorescence emission can be resolved into individual fluorescence signals if two fluorochromes are present or can be converted directly to a decay lifetime from a single fluorochrome. The excitation light for the fluorochromes is modulated to produce an amplitude modulated fluorescence pulse as the fluorochrome is excited in the FCM. The modulation signal also forms a reference signal that is phase-shifted a selected amount for subsequent mixing with the output modulated fluorescence intensity signal in phase-sensitive detection circuitry. The output from the phase-sensitive circuitry is then an individual resolved fluorochrome signal or a single fluorochrome decay lifetime, depending on the applied phase shifts.

  6. Phase-sensitive flow cytometer

    DOE Patents [OSTI]

    Steinkamp, J.A.

    1993-12-14

    A phase-sensitive flow cytometer (FCM) provides additional FCM capability to use the fluorescence lifetime of one or more fluorochromes bound to single cells to provide additional information regarding the cells. The resulting fluorescence emission can be resolved into individual fluorescence signals if two fluorochromes are present or can be converted directly to a decay lifetime from a single fluorochrome. The excitation light for the fluorochromes is modulated to produce an amplitude modulated fluorescence pulse as the fluorochrome is excited in the FCM. The modulation signal also forms a reference signal that is phase-shifted a selected amount for subsequent mixing with the output modulated fluorescence intensity signal in phase-sensitive detection circuitry. The output from the phase-sensitive circuitry is then an individual resolved fluorochrome signal or a single fluorochrome decay lifetime, depending on the applied phase shifts. 15 figures.

  7. Phase stable RF transport system

    DOE Patents [OSTI]

    Curtin, Michael T.; Natter, Eckard F.; Denney, Peter M.

    1992-01-01

    An RF transport system delivers a phase-stable RF signal to a load, such as an RF cavity of a charged particle accelerator. A circuit generates a calibration signal at an odd multiple frequency of the RF signal where the calibration signal is superimposed with the RF signal on a common cable that connects the RF signal with the load. Signal isolating diplexers are located at both the RF signal source end and load end of the common cable to enable the calibration to be inserted and extracted from the cable signals without any affect on the RF signal. Any phase shift in the calibration signal during traverse of the common cable is then functionally related to the phase shift in the RF signal. The calibration phase shift is used to control a phase shifter for the RF signal to maintain a stable RF signal at the load.

  8. Liquid-phase compositions from vapor-phase analyses

    SciTech Connect (OSTI)

    Davis, W. Jr. ); Cochran, H.D. )

    1990-02-01

    Arsenic normally is not considered to be a contaminant. However, because arsenic was found in many cylinders of UF{sub 6}, including in corrosion products, a study was performed of the distribution of the two arsenic fluorides, AsF{sub 3} and AsF{sub 5}, between liquid and vapor phases. The results of the study pertain to condensation or vaporization of liquid UF{sub 6}. This study includes use of various experimental data plus many extrapolations necessitated by the meagerness of the experimental data. The results of this study provide additional support for the vapor-liquid equilibrium model of J.M. Prausnitz and his coworkers as a means of describing the distribution of various impurities between vapor and liquid phases of UF{sub 6}. Thus, it is concluded that AsF{sub 3} will tend to concentrate in the liquid phase but that the concentration of AsF{sub 5} in the vapor phase will exceed its liquid-phase concentration by a factor of about 7.5, which is in agreement with experimental data. Because the weight of the liquid phase in a condensation operation may be in the range of thousands of times that of the vapor phase, most of any AsF{sub 5} will be in the liquid phase in spite of this separation factor of 7.5. It may also be concluded that any arsenic fluorides fed into a uranium isotope separation plant will either travel with other low-molecular-weight gases or react with materials present in the plant. 25 refs., 3 figs., 6 tabs.

  9. Phase space quantum mechanics - Direct

    SciTech Connect (OSTI)

    Nasiri, S.; Sobouti, Y.; Taati, F.

    2006-09-15

    Conventional approach to quantum mechanics in phase space (q,p), is to take the operator based quantum mechanics of Schroedinger, or an equivalent, and assign a c-number function in phase space to it. We propose to begin with a higher level of abstraction, in which the independence and the symmetric role of q and p is maintained throughout, and at once arrive at phase space state functions. Upon reduction to the q- or p-space the proposed formalism gives the conventional quantum mechanics, however, with a definite rule for ordering of factors of noncommuting observables. Further conceptual and practical merits of the formalism are demonstrated throughout the text.

  10. SNMR pulse sequence phase cycling

    DOE Patents [OSTI]

    Walsh, David O; Grunewald, Elliot D

    2013-11-12

    Technologies applicable to SNMR pulse sequence phase cycling are disclosed, including SNMR acquisition apparatus and methods, SNMR processing apparatus and methods, and combinations thereof. SNMR acquisition may include transmitting two or more SNMR pulse sequences and applying a phase shift to a pulse in at least one of the pulse sequences, according to any of a variety cycling techniques. SNMR processing may include combining SNMR from a plurality of pulse sequences comprising pulses of different phases, so that desired signals are preserved and indesired signals are canceled.

  11. Precision digital pulse phase generator

    DOE Patents [OSTI]

    McEwan, T.E.

    1996-10-08

    A timing generator comprises a crystal oscillator connected to provide an output reference pulse. A resistor-capacitor combination is connected to provide a variable-delay output pulse from an input connected to the crystal oscillator. A phase monitor is connected to provide duty-cycle representations of the reference and variable-delay output pulse phase. An operational amplifier drives a control voltage to the resistor-capacitor combination according to currents integrated from the phase monitor and injected into summing junctions. A digital-to-analog converter injects a control current into the summing junctions according to an input digital control code. A servo equilibrium results that provides a phase delay of the variable-delay output pulse to the output reference pulse that linearly depends on the input digital control code. 2 figs.

  12. Precision digital pulse phase generator

    DOE Patents [OSTI]

    McEwan, Thomas E.

    1996-01-01

    A timing generator comprises a crystal oscillator connected to provide an output reference pulse. A resistor-capacitor combination is connected to provide a variable-delay output pulse from an input connected to the crystal oscillator. A phase monitor is connected to provide duty-cycle representations of the reference and variable-delay output pulse phase. An operational amplifier drives a control voltage to the resistor-capacitor combination according to currents integrated from the phase monitor and injected into summing junctions. A digital-to-analog converter injects a control current into the summing junctions according to an input digital control code. A servo equilibrium results that provides a phase delay of the variable-delay output pulse to the output reference pulse that linearly depends on the input digital control code.

  13. APPARATUS FOR LIQUID PHASE EXTRACTION

    DOE Patents [OSTI]

    Hicks, T.R.; Lehman, H.R.; Rubin, B.

    1958-09-16

    operation is described. It comprises a tubular colunm having upper and lower enlarged terminal portions, and a constricted central section containing fluid dispersal packing. Pulsing means are coupled to the upper portion of the column. The inlet for the less dense phase is located above the inlet for the denser phase and both are positioned so that liquids enter the constricted packingfilled central section. The apparatos also includes an interfacing level control, and means fer sensing the level of the interface actuate apparatus for controlling the rate of flow of input or discharge. The outlet for the less dense phase is located in the upper packing free portion of the colunm and that of the denser phase in the lower portion.

  14. Gas-phase chemical dynamics

    SciTech Connect (OSTI)

    Weston, R.E. Jr.; Sears, T.J.; Preses, J.M.

    1993-12-01

    Research in this program is directed towards the spectroscopy of small free radicals and reactive molecules and the state-to-state dynamics of gas phase collision, energy transfer, and photodissociation phenomena. Work on several systems is summarized here.

  15. Reinforced ceramics employing discontinuous phases

    SciTech Connect (OSTI)

    Becher, P.F.

    1990-01-01

    The fracture toughness of ceramics can be improved by the incorporation of a variety of discontinuous reinforcing phases and microstructures. Observations of crack paths in these systems indicate that these reinforcing phases bridge the crack tip wake region. Recent developments in micromechanics toughening models applicable to such systems are discussed and compared with experimental observations. Because material parameters and microstructural characteristics are considered, the crack bridging models provide a means to optimize the toughening effects. 18 refs., 2 figs.

  16. Phase modulation in RF tag

    DOE Patents [OSTI]

    Carrender, Curtis Lee; Gilbert, Ronald W.

    2007-02-20

    A radio frequency (RF) communication system employs phase-modulated backscatter signals for RF communication from an RF tag to an interrogator. The interrogator transmits a continuous wave interrogation signal to the RF tag, which based on an information code stored in a memory, phase-modulates the interrogation signal to produce a backscatter response signal that is transmitted back to the interrogator. A phase modulator structure in the RF tag may include a switch coupled between an antenna and a quarter-wavelength stub; and a driver coupled between the memory and a control terminal of the switch. The driver is structured to produce a modulating signal corresponding to the information code, the modulating signal alternately opening and closing the switch to respectively decrease and increase the transmission path taken by the interrogation signal and thereby modulate the phase of the response signal. Alternatively, the phase modulator may include a diode coupled between the antenna and driver. The modulating signal from the driver modulates the capacitance of the diode, which modulates the phase of the response signal reflected by the diode and antenna.

  17. Phase-field Modeling of Nucleation in Solid-State Phase Transformation...

    Office of Scientific and Technical Information (OSTI)

    of Nucleation in Solid-State Phase Transformations Citation Details In-Document Search Title: Phase-field Modeling of Nucleation in Solid-State Phase Transformations You ...

  18. Phase-Locked Loop Noise Reduction via Phase Detector Implementation for Single-Phase Systems

    SciTech Connect (OSTI)

    Thacker, Timothy; Boroyevich, Dushan; Burgos, Rolando; Wang, Fei

    2011-01-01

    A crucial component of grid-connected converters is the phase-locked loop (PLL) control subsystem that tracks the grid voltage's frequency and phase angle. Therefore, accurate fast-responding PLLs for control and protection purposes are required to provide these measurements. This paper proposes a novel feedback mechanism for single-phase PLL phase detectors using the estimated phase angle. Ripple noise appearing in the estimated frequency, most commonly the second harmonic under phase-lock conditions, is reduced or eliminated without the use of low-pass filters, which can cause delays to occur and limits the overall performance of the PLL response to dynamic changes in the system. The proposed method has the capability to eliminate the noise ripple entirely and, under extreme line distortion conditions, can reduce the ripple by at least half. Other modifications implemented through frequency feedback are shown to decrease the settling time of the PLL up to 50%. Mathematical analyses with the simulated and experimental results are provided to confirm the validity of the proposed methods.

  19. Phase measurement system using a dithered clock

    DOE Patents [OSTI]

    Fairley, C.R.; Patterson, S.R.

    1991-05-28

    A phase measurement system is disclosed which measures the phase shift between two signals by dithering a clock signal and averaging a plurality of measurements of the phase differences between the two signals. 8 figures.

  20. Phase measurement system using a dithered clock

    DOE Patents [OSTI]

    Fairley, Christopher R.; Patterson, Steven R.

    1991-01-01

    A phase measurement system which measures the phase shift between two signals by dithering a clock signal and averaging a plurality of measurements of the phase differences between the two signals.

  1. Property:Project Phase | Open Energy Information

    Open Energy Info (EERE)

    Showing 25 pages using this property. (previous 25) (next 25) M MHK Projects40MW Lewis project + Phase 2 MHK ProjectsADM 3 + Phase ? MHK ProjectsADM 4 + Phase ? MHK...

  2. Phase Transformations in Confined Nanosystems

    SciTech Connect (OSTI)

    Shield, Jeffrey E.; Belashchenko, Kirill

    2014-04-29

    This project discovered that non-equilibrium structures, including chemically ordered structures not observed in bulk systems, form in isolated nanoscale systems. Further, a generalized model was developed that effectively explained the suppression of equilibrium phase transformations. This thermodynamic model considered the free energy decrease associated with the phase transformation was less than the increase in energy associated with the formation of an interphase interface, therefore inhibiting the phase transformation. A critical diameter exists where the system transitions to bulk behavior, and a generalized equation was formulated that successfully predicted this transition in the Fe-Au system. This provided and explains a new route to novel structures not possible in bulk systems. The structural characterization was accomplished using transmission electron microscopy in collaboration with Matthew Kramer of Ames Laboratory. The PI and graduate student visited Ames Laboratory several times a year to conduct the experiments.

  3. Phase transitions in Ge-Sb phase change materials

    SciTech Connect (OSTI)

    Raoux, Simone; Virwani, Kumar; Hitzbleck, Martina; Salinga, Martin; Madan, Anita; Pinto, Teresa L.

    2009-03-15

    Thin films of the phase change material Ge-Sb with Ge concentrations between 7.3 and 81.1 at. % were deposited by cosputtering from elemental targets. Their crystallization behavior was studied using time-resolved x-ray diffraction, Auger electron spectroscopy, differential scanning calorimetry, x-ray reflectivity, profilometry, optical reflectivity, and resistivity versus temperature measurements. It was found that the crystallization temperature increases with Ge content. Calculations of the glass transition temperature (which is a lower limit for the crystallization temperature T{sub x}) also show an increase with Ge concentration closely tracking the measured values of T{sub x}. For low Ge content samples, Sb x-ray diffraction peaks occurred during a heating ramp at lower temperature than Ge diffraction peaks. The appearance of Ge peaks is related to Ge precipitation and agglomeration. For Ge concentrations of 59.3 at. % and higher, Sb and Ge peaks occurred at the same temperature. Upon crystallization, film mass density and optical reflectivity increase as well as electrical contrast (ratio of resistivity in amorphous phase to crystalline phase) all showed a maximum for the eutectic alloy (14.5 at. % Ge). For the alloy with 59.3 at. % Ge there was very little change in any of these parameters, while the alloy with 81.1 at. % Ge behaved opposite to a typical phase change alloy and showed reduced mass density and reflectivity and increased resistivity.

  4. 3 Phases Energy Services | Open Energy Information

    Open Energy Info (EERE)

    Phases Energy Services Jump to: navigation, search Name: 3 Phases Energy Services Place: California Phone Number: 310.939.1283 Website: 3phasesrenewables.comindex.ht Outage...

  5. Loraine Phase 1 | Open Energy Information

    Open Energy Info (EERE)

    1 Jump to: navigation, search Name Loraine Phase 1 Facility Loraine Phase 1 Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service Owner Third Planet...

  6. Apex Offshore Phase 1 | Open Energy Information

    Open Energy Info (EERE)

    1 Jump to: navigation, search Name Apex Offshore Phase 1 Facility Apex Offshore Phase 1 Sector Wind energy Facility Type Offshore Wind Facility Status Proposed Owner Apex Wind...

  7. Apex Offshore Phase 2 | Open Energy Information

    Open Energy Info (EERE)

    2 Jump to: navigation, search Name Apex Offshore Phase 2 Facility Apex Offshore Phase 2 Sector Wind energy Facility Type Offshore Wind Facility Status Proposed Owner Apex Wind...

  8. Loraine Phase 2 | Open Energy Information

    Open Energy Info (EERE)

    2 Jump to: navigation, search Name Loraine Phase 2 Facility Loraine Phase 2 Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service Owner Third Planet...

  9. Laser Crystallization of Phase Change Material

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Geoffrey Campbell is the Principal Investigator for Laser Crystallization of Phase Change Material LLNL BES Programs Highlight Laser Crystallization of Phase Change Material False ...

  10. Structural Phase Transition and Photoluminescence Properties...

    Office of Scientific and Technical Information (OSTI)

    Phase Transition and Photoluminescence Properties of YF3:Eu3+ Nanocrystals under High Pressure Citation Details In-Document Search Title: Structural Phase Transition and ...

  11. InterPhases Research | Open Energy Information

    Open Energy Info (EERE)

    InterPhases Research Jump to: navigation, search Name: InterPhases Research Place: Westlake Village, California Zip: 91361 Sector: Solar Product: US-based developer of copper...

  12. Next Phase Studios Architects | Open Energy Information

    Open Energy Info (EERE)

    Jump to: navigation, search Name: Next Phase Studios Architects Place: Boston, MA Website: www.nextphasestudiosarchitects References: Next Phase Studios Architects1...

  13. Helical phase inflation (Journal Article) | DOE PAGES

    Office of Scientific and Technical Information (OSTI)

    Helical phase inflation Title: Helical phase inflation Authors: Li, Tianjun ; Li, Zhijin ; Nanopoulos, Dimitri V. Publication Date: 2015-03-10 OSTI Identifier: 1180615 Grant...

  14. Experimental signatures of phase interference and subfemtosecond...

    Office of Scientific and Technical Information (OSTI)

    Experimental signatures of phase interference and subfemtosecond time dynamics on the ... Title: Experimental signatures of phase interference and subfemtosecond time dynamics on ...

  15. Cationic Phospholipids Forming Cubic Phases: Lipoplex Structure...

    Office of Scientific and Technical Information (OSTI)

    Cationic Phospholipids Forming Cubic Phases: Lipoplex Structure and Transfection Efficiency Citation Details In-Document Search Title: Cationic Phospholipids Forming Cubic Phases: ...

  16. Shock dynamics of phase diagrams

    SciTech Connect (OSTI)

    Moro, Antonio

    2014-04-15

    A thermodynamic phase transition denotes a drastic change of state of a physical system due to a continuous change of thermodynamic variables, as for instance pressure and temperature. The classical van der Waals equation of state is the simplest model that predicts the occurrence of a critical point associated with the gasliquid phase transition. Nevertheless, below the critical temperature theoretical predictions of the van der Waals theory significantly depart from the observed physical behaviour. We develop a novel approach to classical thermodynamics based on the solution of Maxwell relations for a generalised family of nonlocal entropy functions. This theory provides an exact mathematical description of discontinuities of the order parameter within the phase transition region, it explains the universal form of the equations of state and the occurrence of triple points in terms of the dynamics of nonlinear shock wave fronts. -- Highlights: A new generalisation of van der Waals equation of state. Description of phase transitions in terms of shock dynamics of state curves. Proof of the universality of equations of state for a general class of models. Interpretation of triple points as confluence of classical shock waves. Correspondence table between thermodynamics and nonlinear conservation laws.

  17. Phase and birefringence aberration correction

    DOE Patents [OSTI]

    Bowers, M.; Hankla, A.

    1996-07-09

    A Brillouin enhanced four wave mixing phase conjugate mirror corrects phase aberrations of a coherent electromagnetic beam and birefringence induced upon that beam. The stimulated Brillouin scattering (SBS) phase conjugation technique is augmented to include Brillouin enhanced four wave mixing (BEFWM). A seed beam is generated by a main oscillator which arrives at the phase conjugate cell before the signal beams in order to initiate the Brillouin effect. The signal beam which is being amplified through the amplifier chain is split into two perpendicularly polarized beams. One of the two beams is chosen to be the same polarization as some component of the seed beam, the other orthogonal to the first. The polarization of the orthogonal beam is then rotated 90{degree} such that it is parallel to the other signal beam. The three beams are then focused into cell containing a medium capable of Brillouin excitation. The two signal beams are focused such that they cross the seed beam path before their respective beam waists in order to achieve BEFWM or the two signal beams are focused to a point or points contained within the focused cone angle of the seed beam to achieve seeded SBS, and thus negate the effects of all birefringent and material aberrations in the system. 5 figs.

  18. Phase and birefringence aberration correction

    DOE Patents [OSTI]

    Bowers, Mark; Hankla, Allen

    1996-01-01

    A Brillouin enhanced four wave mixing phase conjugate mirror corrects phase aberrations of a coherent electromagnetic beam and birefringence induced upon that beam. The stimulated Brillouin scattering (SBS) phase conjugation technique is augmented to include Brillouin enhanced four wave mixing (BEFWM). A seed beam is generated by a main oscillator which arrives at the phase conjugate cell before the signal beams in order to initiate the Brillouin effect. The signal beam which is being amplified through the amplifier chain is split into two perpendicularly polarized beams. One of the two beams is chosen to be the same polarization as some component of the seed beam, the other orthogonal to the first. The polarization of the orthogonal beam is then rotated 90.degree. such that it is parallel to the other signal beam. The three beams are then focused into cell containing a medium capable of Brillouin excitation. The two signal beams are focused such that they cross the seed beam path before their respective beam waists in order to achieve BEFWM or the two signal beams are focused to a point or points contained within the focused cone angle of the seed beam to achieve seeded SBS, and thus negate the effects of all birefringent and material aberrations in the system.

  19. Nanostructures having crystalline and amorphous phases

    DOE Patents [OSTI]

    Mao, Samuel S; Chen, Xiaobo

    2015-04-28

    The present invention includes a nanostructure, a method of making thereof, and a method of photocatalysis. In one embodiment, the nanostructure includes a crystalline phase and an amorphous phase in contact with the crystalline phase. Each of the crystalline and amorphous phases has at least one dimension on a nanometer scale. In another embodiment, the nanostructure includes a nanoparticle comprising a crystalline phase and an amorphous phase. The amorphous phase is in a selected amount. In another embodiment, the nanostructure includes crystalline titanium dioxide and amorphous titanium dioxide in contact with the crystalline titanium dioxide. Each of the crystalline and amorphous titanium dioxide has at least one dimension on a nanometer scale.

  20. Category:GEA Development Phases | Open Energy Information

    Open Energy Info (EERE)

    this category, out of 5 total. G Property:GEADevelopmentPhase P Phase I - Resource Procurement and Identification Phase II - Resource Exploration and Confirmation Phase III -...

  1. Fiber bundle phase conjugate mirror

    DOE Patents [OSTI]

    Ward, Benjamin G.

    2012-05-01

    An improved method and apparatus for passively conjugating the phases of a distorted wavefronts resulting from optical phase mismatch between elements of a fiber laser array are disclosed. A method for passively conjugating a distorted wavefront comprises the steps of: multiplexing a plurality of probe fibers and a bundle pump fiber in a fiber bundle array; passing the multiplexed output from the fiber bundle array through a collimating lens and into one portion of a non-linear medium; passing the output from a pump collection fiber through a focusing lens and into another portion of the non-linear medium so that the output from the pump collection fiber mixes with the multiplexed output from the fiber bundle; adjusting one or more degrees of freedom of one or more of the fiber bundle array, the collimating lens, the focusing lens, the non-linear medium, or the pump collection fiber to produce a standing wave in the non-linear medium.

  2. Agent review phase one report.

    SciTech Connect (OSTI)

    Zubelewicz, Alex Tadeusz; Davis, Christopher Edward; Bauer, Travis LaDell

    2009-12-01

    This report summarizes the findings for phase one of the agent review and discusses the review methods and results. The phase one review identified a short list of agent systems that would prove most useful in the service architecture of an information management, analysis, and retrieval system. Reviewers evaluated open-source and commercial multi-agent systems and scored them based upon viability, uniqueness, ease of development, ease of deployment, and ease of integration with other products. Based on these criteria, reviewers identified the ten most appropriate systems. The report also mentions several systems that reviewers deemed noteworthy for the ideas they implement, even if those systems are not the best choices for information management purposes.

  3. Light-driven phase shifter

    DOE Patents [OSTI]

    Early, James W. (Los Alamos, NM)

    1990-01-01

    A light-driven phase shifter is provided for modulating a transmission light beam. A gaseous medium such as argon is provided with electron energy states excited to populate a metastable state. A tunable dye laser is selected with a wavelength effective to deplete the metastable electron state and may be intensity modulated. The dye laser is directed through the gaseous medium to define a first optical path having an index of refraction determined by the gaseous medium having a depleted metastable electron state. A transmission laser beam is also directed through the gaseous medium to define a second optical path at least partially coincident with the first optical path. The intensity of the dye laser beam may then be varied to phase modulate the transmission laser beam.

  4. Disposal phase experimental program plan

    SciTech Connect (OSTI)

    1997-01-31

    The Waste Isolation Pilot Plant (WIPP) facility comprises surface and subsurface facilities, including a repository mined in a bedded salt formation at a depth of 2,150 feet. It has been developed to safely and permanently isolate transuranic (TRU) radioactive wastes in a deep geological disposal site. On April 12, 1996, the DOE submitted a revised Resource Conservation and Recovery Act (RCRA) Part B permit application to the New Mexico Environment Department (NMED). The DOE anticipates receiving an operating permit from the NMED; this permit is required prior to the start of disposal operations. On October 29, 1996, the DOE submitted a Compliance Certification Application (CCA) to the US Environmental Protection Agency (EPA) in accordance with the WIPP land Withdrawal Act (LWA) of 1992 (Public Law 102-579) as amended, and the requirements of Title 40 of the Code of Federal Regulations (40 CFR) Parts 191 and 194. The DOE plans to begin disposal operations at the WIPP in November 1997 following receipt of certification by the EPA. The disposal phase is expected to last for 35 years, and will include recertification activities no less than once every five years. This Disposal Phase Experimental Program (DPEP) Plan outlines the experimental program to be conducted during the first 5-year recertification period. It also forms the basis for longer-term activities to be carried out throughout the 35-year disposal phase. Once the WIPP has been shown to be in compliance with regulatory requirements, the disposal phase gives an opportunity to affirm the compliance status of the WIPP, enhance the operations of the WIPP and the national TRU system, and contribute to the resolution of national and international nuclear waste management technical needs. The WIPP is the first facility of its kind in the world. As such, it provides a unique opportunity to advance the technical state of the art for permanent disposal of long-lived radioactive wastes.

  5. Phase comparator apparatus and method

    DOE Patents [OSTI]

    Coffield, F.E.

    1985-02-01

    This invention finds especially useful application for interferometer measurements made in plasma fusion devices (e.g., for measuring the line integral of electron density in the plasma). Such interferometers typically use very high intermediate frequencies (e.g., on the order of 10 to 70 MHz) and therefore the phase comparison circuitry should be a high speed circuit with a linear transfer characteristic so as to accurately differentiate between small fractions of interference fringes.

  6. Phase change material storage heater

    DOE Patents [OSTI]

    Goswami, D. Yogi; Hsieh, Chung K.; Jotshi, Chand K.; Klausner, James F.

    1997-01-01

    A storage heater for storing heat and for heating a fluid, such as water, has an enclosure defining a chamber therein. The chamber has a lower portion and an upper portion with a heating element being disposed within the enclosure. A tube through which the fluid flows has an inlet and an outlet, both being disposed outside of the enclosure, and has a portion interconnecting the inlet and the outlet that passes through the enclosure. A densely packed bed of phase change material pellets is disposed within the enclosure and is surrounded by a viscous liquid, such as propylene glycol. The viscous liquid is in thermal communication with the heating element, the phase change material pellets, and the tube and transfers heat from the heating element to the pellets and from the pellets to the tube. The viscous fluid has a viscosity so that the frictional pressure drop of the fluid in contact with the phase change material pellets substantially reduces vertical thermal convection in the fluid. As the fluid flows through the tube heat is transferred from the viscous liquid to the fluid flowing through the tube, thereby heating the fluid.

  7. QCD Phase Transitions, Volume 15

    SciTech Connect (OSTI)

    Schaefer, T.; Shuryak, E.

    1999-03-20

    The title of the workshop, ''The QCD Phase Transitions'', in fact happened to be too narrow for its real contents. It would be more accurate to say that it was devoted to different phases of QCD and QCD-related gauge theories, with strong emphasis on discussion of the underlying non-perturbative mechanisms which manifest themselves as all those phases. Before we go to specifics, let us emphasize one important aspect of the present status of non-perturbative Quantum Field Theory in general. It remains true that its studies do not get attention proportional to the intellectual challenge they deserve, and that the theorists working on it remain very fragmented. The efforts to create Theory of Everything including Quantum Gravity have attracted the lion share of attention and young talent. Nevertheless, in the last few years there was also a tremendous progress and even some shift of attention toward emphasis on the unity of non-perturbative phenomena. For example, we have seen some efforts to connect the lessons from recent progress in Supersymmetric theories with that in QCD, as derived from phenomenology and lattice. Another example is Maldacena conjecture and related development, which connect three things together, string theory, super-gravity and the (N=4) supersymmetric gauge theory. Although the progress mentioned is remarkable by itself, if we would listen to each other more we may have chance to strengthen the field and reach better understanding of the spectacular non-perturbative physics.

  8. CO2 Capture and Regeneration at Low Temperatures: Novel Non-Aqueous CO2 Solvents and Capture Process with Substantially Reduced Energy Penalties

    SciTech Connect (OSTI)

    None

    2010-07-01

    IMPACCT Project: RTI is developing a solvent and process that could significantly reduce the temperature associated with regenerating solvent and CO2 captured from the exhaust gas of coal-fired power plants. Traditional CO2 removal processes using water-based solvents require significant amount of steam from power plants in order to regenerate the solvent so it can be reused after each reaction. RTIs solvents can be better at absorbing CO2 than many water-based solvents, and are regenerated at lower temperatures using less steam. Thus, industrial heat that is normally too cool to re-use can be deployed for regeneration, rather than using high-value steam. This saves the power plant money, which results in increased cost savings for consumers.

  9. Ponderomotive phase plate for transmission electron microscopes

    DOE Patents [OSTI]

    Reed, Bryan W. (Livermore, CA)

    2012-07-10

    A ponderomotive phase plate system and method for controllably producing highly tunable phase contrast transfer functions in a transmission electron microscope (TEM) for high resolution and biological phase contrast imaging. The system and method includes a laser source and a beam transport system to produce a focused laser crossover as a phase plate, so that a ponderomotive potential of the focused laser crossover produces a scattering-angle-dependent phase shift in the electrons of the post-sample electron beam corresponding to a desired phase contrast transfer function.

  10. Solid phase microextraction field kit

    DOE Patents [OSTI]

    Nunes, Peter J.; Andresen, Brian D.

    2005-08-16

    A field kit for the collection, isolation and concentration of trace amounts of high explosives (HE), biological weapons (BW) and chemical weapons (CW) residues in air, soil, vegetation, swipe, and liquid samples. The field kit includes a number of Solid Phase Microextraction (SPME) fiber and syringe assemblies in a hermetically sealed transportation container or tubes which includes a sampling port, a number of extra SPME fiber and syringe assemblies, the fiber and syringe assemblies including a protective cap for the fiber, and an extractor for the protective cap, along with other items including spare parts, protective glove, and an instruction manual, all located in an airtight container.

  11. Phase Stability, Crystal Structure, and Thermoelectric Properties...

    Office of Scientific and Technical Information (OSTI)

    Phase Stability, Crystal Structure, and Thermoelectric Properties of Cu12Sb4S13xSex Solid Solutions Citation Details In-Document Search Title: Phase Stability, Crystal Structure, ...

  12. GRED III Phase II | Open Energy Information

    Open Energy Info (EERE)

    2010 DOI Not Provided Check for DOI availability: http:crossref.org Online Internet link for GRED III Phase II Citation Bernie Karl. 2010. GRED III Phase II. p....

  13. Edison Phase I Hours Used

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Edison Phase I Hours Used Edison Phase I Hours Used Edison Usage Chart Edison Usage Chart Date Hours Used (in millions) Percent of Maximum Possible (24 hours/day) 06/23/2013 0.226 88.6 06/22/2013 0.239 93.9 06/21/2013 0.248 97.1 06/20/2013 0.240 94.0 06/19/2013 0.233 91.3 06/18/2013 0.245 96.0 06/17/2013 0.251 98.4 06/16/2013 0.243 95.3 06/15/2013 0.245 95.9 06/14/2013 0.246 96.5 06/13/2013 0.240 94.1 06/12/2013 0.128 50.4 06/11/2013 0.215 84.5 06/10/2013 0.225 88.4 06/09/2013 0.228 89.6

  14. Three phase AC motor controller

    DOE Patents [OSTI]

    Vuckovich, Michael; Wright, Maynard K.; Burkett, John P.

    1984-03-20

    A motor controller for a three phase AC motor (10) which is adapted to operate bidirectionally from signals received either from a computer (30) or a manual control (32). The controller is comprised of digital logic circuit means which implement a forward and reverse command signal channel (27, 29) for the application of power through the forward and reverse power switching relays (16, 18, 20, 22). The digital logic elements are cross coupled to prevent activation of both channels simultaneously and each includes a plugging circuit (65, 67) for stopping the motor upon the removal of control signal applied to one of the two channels (27, 29) for a direction of rotation desired. Each plugging circuit (65, 67) includes a one-shot pulse signal generator (88, 102) which outputs a single pulse signal of predetermined pulsewidth which is adapted to inhibit further operation of the application of power in the channel which is being activated and to apply a reversal command signal to the other channel which provides a reversed phase application of power to the motor for a period defined by the pulse-width output of the one-shot signal generator to plug the motor (10) which will then be inoperative until another rotational command signal is applied to either of the two channels.

  15. Vapor phase modifiers for oxidative coupling

    DOE Patents [OSTI]

    Warren, Barbara K.

    1991-01-01

    Volatilized metal compounds retard vapor phase alkane conversion reactions in oxidative coupling processes that convert lower alkanes to higher hydrocarbons.

  16. Catalyst and method for aqueous phase reactions

    DOE Patents [OSTI]

    Elliott, Douglas C.; Hart, Todd R.

    1999-01-01

    The present invention is a catalyst in the form of a plurality of porous particles wherein each particle is a support having nickel metal catalytic phase or reduced nickel deposited thereon in a first dispersed phase and an additional metal deposited onto the support in a second dispersed phase. The additional metal is effective in retarding or reducing agglomeration or sintering of the nickel metal catalytic phase without substantially affecting the catalytic activity, thereby increasing the life time of the catalyst.

  17. Microsoft Word - DOE_RM_DM-#350832-v1-NAPL_Quarterly_April-June...

    Office of Legacy Management (LM)

    area began. Cool down operations consisted of continued extraction of vapor and ground water, with the goal of cooling the subsurface to below 100 C. Extended heating of...

  18. Successful Field-Scale In Situ Thermal NAPL Remediation at the Young- Rainey STAR Center

    Broader source: Energy.gov [DOE]

    Proceedings of the Fourth International Conference on Remediation of Chlorinated and Recalcitrant Compounds.May 2004, Monterey, California.Randall Juhlin, Michael Butherus, Joseph Daniel, David S....

  19. Microsoft Word - DOE_RM_DM-#100069-v1-NAPL_Quarterly_Oct-Dec...

    Office of Legacy Management (LM)

    ... These data demonstrate that concentrations remain low both ... at a slightly elevated temperature 20 months after active ... Piping and wellhead fabrication and treatment system ...

  20. Microsoft Word - DOE_RM_DM-#341474-v1-NAPL_Quarterly_April_-...

    Office of Legacy Management (LM)

    ... concentrations remain low both inside and around the ... although the subsurface temperature remains slightly ... Page 3 Photo 1. Surface Treatment System During ...

  1. Microsoft Word - DOE_RM_DM-#102768-v1-NAPL_Quarterly_Report_Jan...

    Office of Legacy Management (LM)

    ... concentrations remain low both inside and around the ... although the subsurface temperature remains slightly ... of the following. The treatment system will be tested at ...

  2. Centrifuge workers study. Phase II, completion report

    SciTech Connect (OSTI)

    Wooten, H.D.

    1994-09-01

    Phase II of the Centrifuge Workers Study was a follow-up to the Phase I efforts. The Phase I results had indicated a higher risk than expected among centrifuge workers for developing bladder cancer when compared with the risk in the general population for developing this same type of cancer. However, no specific agent could be identified as the causative agent for these bladder cancers. As the Phase II Report states, Phase I had been limited to workers who had the greatest potential for exposure to substances used in the centrifuge process. Phase II was designed to expand the survey to evaluate the health of all employees who had ever worked in Centrifuge Program Departments 1330-1339 but who had not been interviewed in Phase I. Employees in analytical laboratories and maintenance departments who provided support services for the Centrifuge Program were also included in Phase II. In December 1989, the Oak Ridge Associated Universities (ORAU), now known as Oak Ridge Institute for Science and Education (ORISE), was contracted to conduct a follow-up study (Phase II). Phase H of the Centrifuge Workers Study expanded the survey to include all former centrifuge workers who were not included in Phase I. ORISE was chosen because they had performed the Phase I tasks and summarized the corresponding survey data therefrom.

  3. Frequency spectrum analyzer with phase-lock

    DOE Patents [OSTI]

    Boland, Thomas J.

    1984-01-01

    A frequency-spectrum analyzer with phase-lock for analyzing the frequency and amplitude of an input signal is comprised of a voltage controlled oscillator (VCO) which is driven by a ramp generator, and a phase error detector circuit. The phase error detector circuit measures the difference in phase between the VCO and the input signal, and drives the VCO locking it in phase momentarily with the input signal. The input signal and the output of the VCO are fed into a correlator which transfers the input signal to a frequency domain, while providing an accurate absolute amplitude measurement of each frequency component of the input signal.

  4. Two phase titanium aluminide alloy

    DOE Patents [OSTI]

    Deevi, Seetharama C.; Liu, C. T.

    2001-01-01

    A two-phase titanic aluminide alloy having a lamellar microstructure with little intercolony structures. The alloy can include fine particles such as boride particles at colony boundaries and/or grain boundary equiaxed structures. The alloy can include alloying additions such as .ltoreq.10 at % W, Nb and/or Mo. The alloy can be free of Cr, V, Mn, Cu and/or Ni and can include, in atomic %, 45 to 55% Ti, 40 to 50% Al, 1 to 5% Nb, 0.3 to 2% W, up to 1% Mo and 0.1 to 0.3% B. In weight %, the alloy can include 57 to 60% Ti, 30 to 32% Al, 4 to 9% Nb, up to 2% Mo, 2 to 8% W and 0.02 to 0.08% B.

  5. Electric field controlled emulsion phase contactor

    DOE Patents [OSTI]

    Scott, T.C.

    1995-01-31

    A system is described for contacting liquid phases comprising a column for transporting a liquid phase contacting system, the column having upper and lower regions. The upper region has a nozzle for introducing a dispersed phase and means for applying thereto a vertically oriented high intensity pulsed electric field. This electric field allows improved flow rates while shattering the dispersed phase into many micro-droplets upon exiting the nozzle to form a dispersion within a continuous phase. The lower region employs means for applying to the dispersed phase a horizontally oriented high intensity pulsed electric field so that the dispersed phase undergoes continuous coalescence and redispersion while being urged from side to side as it progresses through the system, increasing greatly the mass transfer opportunity. 5 figs.

  6. Electric field controlled emulsion phase contactor

    DOE Patents [OSTI]

    Scott, Timothy C.

    1995-01-01

    A system for contacting liquid phases comprising a column for transporting a liquid phase contacting system, the column having upper and lower regions. The upper region has a nozzle for introducing a dispersed phase and means for applying thereto a vertically oriented high intensity pulsed electric field. This electric field allows improved flow rates while shattering the dispersed phase into many micro-droplets upon exiting the nozzle to form a dispersion within a continuous phase. The lower region employs means for applying to the dispersed phase a horizontally oriented high intensity pulsed electric field so that the dispersed phase undergoes continuous coalescence and redispersion while being urged from side to side as it progresses through the system, increasing greatly the mass transfer opportunity.

  7. Funding Phases for Small Business Innovation Research and Small...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Phases for Small Business Innovation Research and Small Business Technology Transfer ... Only recipients of Phase I awards may compete for Phase II funding. Should result in a ...

  8. Property:GeothermalDevelopmentPhases | Open Energy Information

    Open Energy Info (EERE)

    GeothermalDevelopmentPhases Jump to: navigation, search Property Name GeothermalDevelopmentPhases Property Type Page Pages using the property "GeothermalDevelopmentPhases" Showing...

  9. Launching the Next Phase of the Better Buildings Neighborhood...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Launching the Next Phase of the Better Buildings Neighborhood Program Launching the Next Phase of the Better Buildings Neighborhood Program Launching the Next Phase of the Better...

  10. High performance Zintl phase TE materials with embedded nanoparticles...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Zintl phase TE materials with embedded nanoparticles High performance Zintl phase TE materials with embedded nanoparticles Performance of zintl phase thermoelectric ...

  11. SPIDERS Phase 2 Fort Carson Technology Transition Consolidated...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    SPIDERS Phase 2 Fort Carson Technology Transition Consolidated Report SPIDERS Phase 2 Fort Carson Technology Transition Consolidated Report Final program public report for phase 2 ...

  12. Condon Wind Project phase II | Open Energy Information

    Open Energy Info (EERE)

    Project phase II Jump to: navigation, search Name Condon Wind Project phase II Facility Condon Wind Project phase II Sector Wind energy Facility Type Commercial Scale Wind Facility...

  13. Photovoltaic manufacturing technology, Phase 1

    SciTech Connect (OSTI)

    Not Available

    1992-10-01

    This report describes subcontracted research by the Chronar Corporation, prepared by Advanced Photovoltaic Systems, Inc. (APS) for Phase 1 of the Photovoltaic Manufacturing Technology Development project. Amorphous silicon is chosen as the PV technology that Chronar Corporation and APS believe offers the greatest potential for manufacturing improvements, which, in turn, will result in significant cost reductions and performance improvements in photovoltaic products. The APS Eureka'' facility was chosen as the manufacturing system that can offer the possibility of achieving these production enhancements. The relationship of the Eureka'' facility to Chronar's batch'' plants is discussed. Five key areas are also identified that could meet the objectives of manufacturing potential that could lead to improved performance, reduced manufacturing costs, and significantly increased production. The projected long-term potential benefits of these areas are discussed, as well as problems that may impede the achievement of the hoped-for developments. A significant number of the problems discussed are of a generic nature and could be of general interest to the industry. The final section of this document addresses the cost and time estimates for achieving the solutions to the problems discussed earlier. Emphasis is placed on the number, type, and cost of the human resources required for the project.

  14. Liquid-phase chromatography detector

    DOE Patents [OSTI]

    Voigtman, Edward G.; Winefordner, James D.; Jurgensen, Arthur R.

    1983-01-01

    A liquid-phase chromatography detector comprising a flow cell having an inlet tubular conduit for receiving a liquid chromatographic effluent and discharging it as a flowing columnar stream onto a vertically adjustable receiving surface spaced apart from and located vertically below and in close proximity to the discharge end of the tubular conduit; a receiver adapted to receive liquid overflowing from the receiving surface; an exit conduit for continuously removing liquid from the receiver; a light source for focussing fluorescence-producing light pulses on the flowing columnar stream as it passes from the outlet of the conduit to the receiving surface and a fluorescence detector to detect the produced fluorescence; a source of light pulse for producing acoustic waves in the columnar stream as it passes from the conduit outlet to the receiving surface; and a piezoelectric transducer adapted to detect those waves; and a source of bias voltage applied to the inlet tubular conduit and adapted to produce ionization of the liquid flowing through the flow cell so as to produce photocurrents therein and an electrical system to detect and record the photocurrents. This system is useful in separating and detecting individual chemical compounds from mixtures thereof.

  15. Liquid-phase chromatography detector

    DOE Patents [OSTI]

    Voigtman, E.G.; Winefordner, J.D.; Jurgensen, A.R.

    1983-11-08

    A liquid-phase chromatography detector comprises a flow cell having an inlet tubular conduit for receiving a liquid chromatographic effluent and discharging it as a flowing columnar stream onto a vertically adjustable receiving surface spaced apart from and located vertically below and in close proximity to the discharge end of the tubular conduit; a receiver adapted to receive liquid overflowing from the receiving surface; an exit conduit for continuously removing liquid from the receiver; a light source for focusing fluorescence-producing light pulses on the flowing columnar stream as it passes from the outlet of the conduit to the receiving surface and a fluorescence detector to detect the produced fluorescence; a source of light pulse for producing acoustic waves in the columnar stream as it passes from the conduit outlet to the receiving surface; and a piezoelectric transducer adapted to detect those waves; and a source of bias voltage applied to the inlet tubular conduit and adapted to produce ionization of the liquid flowing through the flow cell so as to produce photocurrents therein and an electrical system to detect and record the photocurrents. This system is useful in separating and detecting individual chemical compounds from mixtures thereof. 5 figs.

  16. Transient liquid phase ceramic bonding

    DOE Patents [OSTI]

    Glaeser, Andreas M. (Berkeley, CA)

    1994-01-01

    Ceramics are joined to themselves or to metals using a transient liquid phase method employing three layers, one of which is a refractory metal, ceramic or alloy. The refractory layer is placed between two metal layers, each of which has a lower melting point than the refractory layer. The three layers are pressed between the two articles to be bonded to form an assembly. The assembly is heated to a bonding temperature at which the refractory layer remains solid, but the two metal layers melt to form a liquid. The refractory layer reacts with the surrounding liquid and a single solid bonding layer is eventually formed. The layers may be designed to react completely with each other and form refractory intermetallic bonding layers. Impurities incorporated into the refractory metal may react with the metal layers to form refractory compounds. Another method for joining ceramic articles employs a ceramic interlayer sandwiched between two metal layers. In alternative embodiments, the metal layers may include sublayers. A method is also provided for joining two ceramic articles using a single interlayer. An alternate bonding method provides a refractory-metal oxide interlayer placed adjacent to a strong oxide former. Aluminum or aluminum alloys are joined together using metal interlayers.

  17. SYNCHEM feasibility report: Phase 1

    SciTech Connect (OSTI)

    Not Available

    1995-01-01

    Several Czech and US companies have entered into a development agreement for the purposes of determining the technical and economic feasibility and overall financeability of an integrated gasification combined cycle (IGCC) regional energy facility to be located adjacent to the Chemopetrol refinery in Litvinov, Czech Republic. The Project would use a feedstock comprised of coal supplied by Doly a upravny Komorany s.p. (DUK) coal mining company and mined from the Most/Litvinov area together with high sulfur residual oils from the Chemopetrol refinery. When gasified together with oxygen from an Air Products air separation plant, and based on an average yearly consumption of 2,100K metric tons per year of coal (as delivered) and 630K tonnes per year of oil, approximately 11 million normal cubic meters per day of syngas will be produced. At its current projected design capacity, when combusted in two General Electric advanced technology Frame 9FA gas turbines, the Project will produce approximately 690MW of electric power; 250 metric tons/hour of steam for process; and 135 thermal equivalent MW of district heat. The Feasibility Phase efforts described in this report indicate the real possibility for a successful and profitable IGCC Project for the Czech Republic. It is therefore incumbent upon all the Project Participants to review and evaluate the information contained herein such that a go/no-go decision can be reached by early next year.

  18. Magnetic Phases in Dense Quark Matter

    SciTech Connect (OSTI)

    Incera, Vivian de la

    2007-10-26

    In this paper I discuss the magnetic phases of the three-flavor color superconductor. These phases can take place at different field strengths in a highly dense quark system. Given that the best natural candidates for the realization of color superconductivity are the extremely dense cores of neutron stars, which typically have very large magnetic fields, the magnetic phases here discussed could have implications for the physics of these compact objects.

  19. In-line phase shift tomosynthesis

    SciTech Connect (OSTI)

    Hammonds, Jeffrey C.; Price, Ronald R.; Pickens, David R.; Donnelly, Edwin F.

    2013-08-15

    Purpose: The purpose of this work is to (1) demonstrate laboratory measurements of phase shift images derived from in-line phase-contrast radiographs using the attenuation-partition based algorithm (APBA) of Yan et al.[Opt. Express 18(15), 1607416089 (2010)], (2) verify that the APBA reconstructed images obey the linearity principle, and (3) reconstruct tomosynthesis phase shift images from a collection of angularly sampled planar phase shift images.Methods: An unmodified, commercially available cabinet x-ray system (Faxitron LX-60) was used in this experiment. This system contains a tungsten anode x-ray tube with a nominal focal spot size of 10 ?m. The digital detector uses CsI/CMOS with a pixel size of 50 50 ?m. The phantoms used consisted of one acrylic plate, two polystyrene plates, and a habanero pepper. Tomosynthesis images were reconstructed from 51 images acquired over a 25 arc. All phase shift images were reconstructed using the APBA.Results: Image contrast derived from the planar phase shift image of an acrylic plate of uniform thickness exceeded the contrast of the traditional attenuation image by an approximate factor of two. Comparison of the planar phase shift images from a single, uniform thickness polystyrene plate with two polystyrene plates demonstrated an approximate linearity of the estimated phase shift with plate thickness (?1600 rad vs ?2970 rad). Tomographic phase shift images of the habanero pepper exhibited acceptable spatial resolution and contrast comparable to the corresponding attenuation image.Conclusions: This work demonstrated the feasibility of laboratory-based phase shift tomosynthesis and suggests that phase shift imaging could potentially provide a new imaging biomarker. Further investigation will be needed to determine if phase shift contrast will be able to provide new tissue contrast information or improved clinical performance.

  20. Stationary phase deposition based on onium salts

    DOE Patents [OSTI]

    Wheeler, David R.; Lewis, Patrick R.; Dirk, Shawn M.; Trudell, Daniel E.

    2008-01-01

    Onium salt chemistry can be used to deposit very uniform thickness stationary phases on the wall of a gas chromatography column. In particular, the stationary phase can be bonded to non-silicon based columns, especially microfabricated metal columns. Non-silicon microfabricated columns may be manufactured and processed at a fraction of the cost of silicon-based columns. In addition, the method can be used to phase-coat conventional capillary columns or silicon-based microfabricated columns.

  1. Phase distribution in complex geometry conduits

    SciTech Connect (OSTI)

    Lahey, R.T. Jr.; Lopez de Bertodano, M.; Jones, O.C. Jr.

    1992-12-31

    Some of the most important and challenging problems in two-phase flow today have to do with the understanding and prediction of multidimensional phenomena, in particular, lateral phase distribution in both simple and complex geometry conduits. A prior review paper summarized the state-of-the-art in the understanding of phase distribution phenomena, and the ability to perform mechanistic multidimensional predictions. The purpose of this paper is to update that review, with particular emphasis on complex geometry conduit predictive capabilities.

  2. Geometric phases in a scattering process

    SciTech Connect (OSTI)

    Liu, H. D.; Yi, X. X. [School of Physics and Optoelectronic Technology, Dalian University of Technology, Dalian 116024 (China)

    2011-08-15

    The study of geometric phase in quantum mechanics has so far been confined to discrete (or continuous) spectra and trace-preserving evolutions. By considering only the transmission channel, a scattering process with internal degrees of freedom is neither a discrete spectrum problem nor a trace-preserving process. We explore the geometric phase in the scattering process by taking only the transmission process into account. We find that the geometric phase can be calculated by the same method as in unitary evolution. The interference visibility depends on the transmission amplitude. The dependence of the geometric phase on the barrier strength and the spin-spin coupling constant is also presented and discussed.

  3. IDC Re-Engineering Phase 2 Glossary.

    SciTech Connect (OSTI)

    Young, Christopher J.; Harris, James M.

    2016-01-01

    This document contains the glossary of terms used for the IDC Re-Engineering Phase 2 project. This version was created for Iteration E1.

  4. Liquid phase sintering of silicon carbide

    DOE Patents [OSTI]

    Cutler, R.A.; Virkar, A.V.; Hurford, A.C.

    1989-05-09

    Liquid phase sintering is used to densify silicon carbide based ceramics using a compound comprising a rare earth oxide and aluminum oxide to form liquids at temperatures in excess of 1,600 C. The resulting sintered ceramic body has a density greater than 95% of its theoretical density and hardness in excess of 23 GPa. Boron and carbon are not needed to promote densification and silicon carbide powder with an average particle size of greater than one micron can be densified via the liquid phase process. The sintered ceramic bodies made by the present invention are fine grained and have secondary phases resulting from the liquid phase. 4 figs.

  5. OutageMapURL Phases Energy Services

    Open Energy Info (EERE)

    OutageMapURL Phases Energy Services County Electric Power Assn http outages county org A N Electric Coop Virginia AEP Generating Company https www aepaccount com zipr...

  6. Titanium ? - ? phase transformation pathway and a predicted...

    Office of Scientific and Technical Information (OSTI)

    Titanium - phase transformation pathway and a predicted metastable structure Citation Details In-Document Search This content will become publicly available on January 14,...

  7. Phase 1 of Edison Arrives at NERSC

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Phase 1 of Edison Arrives at NERSC Phase 1 of Edison Arrives at NERSC November 27, 2012 Photo by Roy Kaltschmidt, Berkeley Lab Phase 1 of NERSC's newest supercomputer, named Edison, was delivered on November 27, 2012. The architecture is a Cray XC30 ("Cascade") and it will be installed in two phases. When it is fully installed in 2013, Edison will have a peak performance of more than 2 petaflops (1015 floating point operations per second). The integrated storage system will have more

  8. Vapor phase modifiers for oxidative coupling

    DOE Patents [OSTI]

    Warren, B.K.

    1991-12-17

    Volatilized metal compounds are described which are capable of retarding vapor phase alkane conversion reactions in oxidative coupling processes that convert lower alkanes to higher hydrocarbons.

  9. Double acting stirling engine phase control

    DOE Patents [OSTI]

    Berchowitz, David M.

    1983-01-01

    A mechanical device for effecting a phase change between the expansion and compression volumes of a double-acting Stirling engine uses helical elements which produce opposite rotation of a pair of crankpins when a control rod is moved, so the phase between two pairs of pistons is changed by +.psi. and the phase between the other two pairs of pistons is changed by -.psi.. The phase can change beyond .psi.=90.degree. at which regenerative braking and then reversal of engine rotation occurs.

  10. Phase-field modeling of diffusional phase behaviors of solid surfaces: A

    Office of Scientific and Technical Information (OSTI)

    case study of phase-separating LiXFePO4 electrode particles (Journal Article) | SciTech Connect diffusional phase behaviors of solid surfaces: A case study of phase-separating LiXFePO4 electrode particles Citation Details In-Document Search Title: Phase-field modeling of diffusional phase behaviors of solid surfaces: A case study of phase-separating LiXFePO4 electrode particles Authors: Heo, T W ; Chen, L Q ; Wood, B C Publication Date: 2014-12-15 OSTI Identifier: 1251071 Report Number(s):

  11. Phase-field modeling of the beta to omega phase transformation in Zr-Nb

    Office of Scientific and Technical Information (OSTI)

    alloys (Journal Article) | SciTech Connect Phase-field modeling of the beta to omega phase transformation in Zr-Nb alloys Citation Details In-Document Search Title: Phase-field modeling of the beta to omega phase transformation in Zr-Nb alloys A three-dimensional elastoplastic phase-field model is developed, using the finite element method (FEM), for modeling the athermal beta to omega phase transformation in Zr-Nb alloys by including plastic deformation and strain hardening of the material.

  12. Phase-field modeling of the beta to omega phase transformation in Zr-Nb

    Office of Scientific and Technical Information (OSTI)

    alloys (Journal Article) | SciTech Connect Phase-field modeling of the beta to omega phase transformation in Zr-Nb alloys Citation Details In-Document Search Title: Phase-field modeling of the beta to omega phase transformation in Zr-Nb alloys A three-dimensional elastoplastic phase-field model is developed, using the Finite Element Method (FEM), for modeling the athermal beta to omega phase transformation in Zr-Nb alloys by including plastic deformation and strain hardening of the material.

  13. High harmonic phase in molecular nitrogen

    SciTech Connect (OSTI)

    McFarland, Brian K.

    2009-10-17

    Electronic structure in atoms and molecules modulates the amplitude and phase of high harmonic generation (HHG). We report measurements of the high harmonic spectral amplitude and phase in N{sub 2}. The phase is measured interferometrically by beating the N{sub 2} harmonics with those of an Ar reference oscillator in a gas mixture. A rapid phase shift of 0.2{pi} is observed in the vicinity of the HHG spectral minimum, where a shift of {pi} had been presumed [J. Itatani et al., Nature 432, 867 (2004)]. We compare the phase measurements to a simulation of the HHG recombination step in N{sub 2} that is based on a simple interference model. The results of the simulation suggest that modifications beyond the simple interference model are needed to explain HHG spectra in molecules.

  14. SYNCHROTRON RADIO FREQUENCY PHASE CONTROL SYSTEM

    DOE Patents [OSTI]

    Plotkin, M.; Raka, E.C.; Snyder, H.S.

    1963-05-01

    A system for canceling varying phase changes introduced by connecting cables and control equipment in an alternating gradient synchrotron is presented. In a specific synchrotron embodiment twelve spaced accelerating stations for the proton bunches are utilized. In order to ensure that the protons receive their boost or kick at the exact instant necessary it is necessary to compensate for phase changes occurring in the r-f circuitry over the wide range of frequencies dictated by the accelerated velocities of the proton bunches. A constant beat frequency is utilized to transfer the r-f control signals through the cables and control equipment to render the phase shift constant and readily compensable. (AEC)

  15. Gas-phase propane fuel delivery system

    SciTech Connect (OSTI)

    Clements, J.

    1991-04-30

    This patent describes a gas-phase fuel delivery system for delivering a vapor phase fuel independent of exterior temperatures. It comprises:a storage tank for storing a volume of fuel; a regulator in fluid communication with the tank for receiving fuel from the tank and for outputting the fuel in a vapor phase; a pressure sensor in fluid communication with the tank for monitoring pressure within the tank, the pressure sensor being operative to generate a pump enable signal when the pressure within the tank is less than a predetermined threshold; a pump in fluid communication with the tank.

  16. Laser Phase Errors in Seeded FELs

    SciTech Connect (OSTI)

    Ratner, D.; Fry, A.; Stupakov, G.; White, W.; /SLAC

    2012-03-28

    Harmonic seeding of free electron lasers has attracted significant attention from the promise of transform-limited pulses in the soft X-ray region. Harmonic multiplication schemes extend seeding to shorter wavelengths, but also amplify the spectral phase errors of the initial seed laser, and may degrade the pulse quality. In this paper we consider the effect of seed laser phase errors in high gain harmonic generation and echo-enabled harmonic generation. We use simulations to confirm analytical results for the case of linearly chirped seed lasers, and extend the results for arbitrary seed laser envelope and phase.

  17. Phase 2, Solid waste retrieval strategy

    SciTech Connect (OSTI)

    Johnson, D.M.

    1994-09-29

    Solid TRU retrieval, Phase 1 is scheduled to commence operation in 1998 at 218W-4C-T01 and complete recovery of the waste containers in 2001. Phase 2 Retrieval will recover the remaining buried TRU waste to be retrieved and provide the preliminary characterization by non-destructive means to allow interim storage until processing for disposal. This document reports on researching the characterization documents to determine the types of wastes to be retrieved and where located, waste configurations, conditions, and required methods for retrieval. Also included are discussions of wastes encompassed by Phase 2 for which there are valid reasons to not retrieve.

  18. Comprehensive phase characterization of crystalline and amorphous phases of a Class F fly ash

    SciTech Connect (OSTI)

    Chancey, Ryan T.; Stutzman, Paul; Juenger, Maria C.G.; Fowler, David W.

    2010-01-15

    A comprehensive approach to qualitative and quantitative characterization of crystalline and amorphous constituent phases of a largely heterogeneous Class F fly ash is presented. Traditionally, fly ash composition is expressed as bulk elemental oxide content, generally determined by X-ray fluorescence spectroscopy. However, such analysis does not discern between relatively inert crystalline phases and highly reactive amorphous phases of similar elemental composition. X-ray diffraction was used to identify the crystalline phases present in the fly ash, and the Rietveld quantitative phase analysis method was applied to determine the relative proportion of each of these phases. A synergistic method of X-ray powder diffraction, scanning electron microscopy, energy dispersive spectroscopy, and multispectral image analysis was developed to identify and quantify the amorphous phases present in the fly ash.

  19. Nuclear Concrete Materials Database Phase I Development

    SciTech Connect (OSTI)

    Ren, Weiju; Naus, Dan J

    2012-05-01

    The FY 2011 accomplishments in Phase I development of the Nuclear Concrete Materials Database to support the Light Water Reactor Sustainability Program are summarized. The database has been developed using the ORNL materials database infrastructure established for the Gen IV Materials Handbook to achieve cost reduction and development efficiency. In this Phase I development, the database has been successfully designed and constructed to manage documents in the Portable Document Format generated from the Structural Materials Handbook that contains nuclear concrete materials data and related information. The completion of the Phase I database has established a solid foundation for Phase II development, in which a digital database will be designed and constructed to manage nuclear concrete materials data in various digitized formats to facilitate electronic and mathematical processing for analysis, modeling, and design applications.

  20. Ponderomotive phase plate for transmission electron microscopes...

    Office of Scientific and Technical Information (OSTI)

    The system and method includes a laser source and a beam transport system to produce a focused laser crossover as a phase plate, so that a ponderomotive potential of the focused ...

  1. Synthesis of alloys with controlled phase structure

    DOE Patents [OSTI]

    Guthrie, S.E.; Thomas, G.J.; Bauer, W.; Yang, N.Y.C.

    1999-04-20

    A method is described for preparing controlled phase alloys useful for engineering and hydrogen storage applications. This novel method avoids melting the constituents by employing vapor transport, in a hydrogen atmosphere, of an active metal constituent, having a high vapor pressure at temperatures {approx_equal}300 C and its subsequent condensation on and reaction with the other constituent (substrate) of an alloy thereby forming a controlled phase alloy and preferably a single phase alloy. It is preferred that the substrate material be a metal powder such that diffusion of the active metal constituent, preferably magnesium, and reaction therewith can be completed within a reasonable time and at temperatures {approx_equal}300 C thereby avoiding undesirable effects such as sintering, local compositional inhomogeneities, segregation, and formation of unwanted second phases such as intermetallic compounds. 4 figs.

  2. Synthesis of alloys with controlled phase structure

    DOE Patents [OSTI]

    Guthrie, Stephen Everett; Thomas, George John; Bauer, Walter; Yang, Nancy Yuan Chi

    1999-04-20

    A method for preparing controlled phase alloys useful for engineering and hydrogen storage applications. This novel method avoids melting the constituents by employing vapor transport, in a hydrogen atmosphere, of an active metal constituent, having a high vapor pressure at temperatures .apprxeq.300 C. and its subsequent condensation on and reaction with the other constituent (substrate) of an alloy thereby forming a controlled phase alloy and preferably a single phase alloy. It is preferred that the substrate material be a metal powder such that diffusion of the active metal constituent, preferably magnesium, and reaction therewith can be completed within a reasonable time and at temperatures .apprxeq.300 C. thereby avoiding undesirable effects such as sintering, local compositional inhomogeneities, segregation, and formation of unwanted second phases such as intermetallic compounds.

  3. Experimental phasing for structure determination using membrane...

    Office of Scientific and Technical Information (OSTI)

    Here, a four-year campaign aimed at phasing the in meso structure of the integral membrane diacylglycerol kinase (DgkA) from Escherichia coli is reported. Heavy-atom labelling of ...

  4. The geometric phase controls ultracold chemistry

    SciTech Connect (OSTI)

    Kendrick, B. K.; Hazra, Jisha; Balakrishnan, N.

    2015-07-30

    In this study, the geometric phase is shown to control the outcome of an ultracold chemical reaction. The control is a direct consequence of the sign change on the interference term between two scattering pathways (direct and looping), which contribute to the reactive collision process in the presence of a conical intersection (point of degeneracy between two BornOppenheimer electronic potential energy surfaces). The unique properties of the ultracold energy regime lead to an effective quantization of the scattering phase shift enabling maximum constructive or destructive interference between the two pathways. By taking the O + OH ? H + O2 reaction as an illustrative example, it is shown that inclusion of the geometric phase modifies ultracold reaction rates by nearly two orders of magnitude. Interesting experimental control possibilities include the application of external electric and magnetic fields that might be used to exploit the geometric phase effect reported here and experimentally switch on or off the reactivity.

  5. Ice in Arctic Mixed-phase Stratocumulus

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ice Nuclei Recycling in the Maintenance of Cloud Ice in Arctic Mixed-phase Stratocumulus For original submission and image(s), see ARM Research Highlights http:www.arm.gov...

  6. Clustering versus non-clustering phase synchronizations

    SciTech Connect (OSTI)

    Liu, Shuai; University of Chinese Academy of Sciences, Beijing 100049 ; Zhan, Meng

    2014-03-15

    Clustering phase synchronization (CPS) is a common scenario to the global phase synchronization of coupled dynamical systems. In this work, a novel scenario, the non-clustering phase synchronization (NPS), is reported. It is found that coupled systems do not transit to the global synchronization until a certain sufficiently large coupling is attained, and there is no clustering prior to the global synchronization. To reveal the relationship between CPS and NPS, we further analyze the noise effect on coupled phase oscillators and find that the coupled oscillator system can change from CPS to NPS with the increase of noise intensity or system disorder. These findings are expected to shed light on the mechanism of various intriguing self-organized behaviors in coupled systems.

  7. Metamorphosis: Phases of UF{sub 6}

    SciTech Connect (OSTI)

    Dyer, R.H.

    1991-12-31

    A 15-minute videotape is presented. The subject matter is 150 grams of UF{sub 6} sealed in a glass tube. Close-up views show the UF{sub 6} as phase changes are effected by the addition or removal of heat from the closed system. The solid-to-liquid transition is shown as heat is added, both slowly and rapidly. The solid phases which result from freezing and from desublimation are contrasted. In the solid state, uranium hexafluoride is a nearly-white, dense crystalline solid. The appearance of this solid depends on whether it is formed by freezing from the liquid or by desublimation from the vapor phase. If frozen from the liquid, the solid particles take the form of irregularly shaped coarse grains, while the solid product of desublimation tends to be a rather formless mass without individually distinguishable particles. The changes in state are presented in terms of the UF{sub 6} phase diagram.

  8. Phase measurements of EUV mask defects

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Claus, Rene A.; Wang, Yow-Gwo; Wojdyla, Antoine; Benk, Markus P.; Goldberg, Kenneth A.; Neureuther, Andrew R.; Naulleau, Patrick P.; Waller, Laura

    2015-02-22

    Extreme Ultraviolet (EUV) Lithography mask defects were examined on the actinic mask imaging system, SHARP, at Lawrence Berkeley National Laboratory. Also, a quantitative phase retrieval algorithm based on the Weak Object Transfer Function was applied to the measured through-focus aerial images to examine the amplitude and phase of the defects. The accuracy of the algorithm was demonstrated by comparing the results of measurements using a phase contrast zone plate and a standard zone plate. Using partially coherent illumination to measure frequencies that would otherwise fall outside the numerical aperture (NA), it was shown that some defects are smaller than themore » conventional resolution of the microscope. We found that the programmed defects of various sizes were measured and shown to have both an amplitude and a phase component that the algorithm is able to recover.« less

  9. DOE - NNSA/NFO -- FRMAC Response Phases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Phases NNSA/NFO Language Options U.S. DOE/NNSA - Nevada Field Office Federal Radiological Monitoring and Assessment Center Response Phases Consequence Management Home Team (CMHT) PDF icon CMHT Brochure (pdf, 2 MB) The Consequence Management Home Team (CMHT) functions as a virtual extension of the FRMAC when a full FRMAC has not yet been, or will not be, deployed. The same products and assistance are available in CMHT as with a full FRMAC with the exception of field monitoring capabilities.

  10. Optimum phase space probabilities from quantum tomography

    SciTech Connect (OSTI)

    Roy, Arunabha S.; Roy, S. M.

    2014-01-15

    We determine a positive normalised phase space probability distribution P with minimum mean square fractional deviation from the Wigner distribution W. The minimum deviation, an invariant under phase space rotations, is a quantitative measure of the quantumness of the state. The positive distribution closest to W will be useful in quantum mechanics and in time frequency analysis. The position-momentum correlations given by the distribution can be tested experimentally in quantum optics.

  11. Analysis of Nuclear Quantum Phase Transitions

    SciTech Connect (OSTI)

    Li, Z. P.; Meng, J.; Niksic, T.; Vretenar, D.; Lalazissis, G. A.; Ring, P.

    2009-08-26

    A microscopic analysis, based on nuclear energy density functionals, is presented for shape phase transitions in Nd isotopes. Low-lying excitation spectra and transition probabilities are calculated starting from a five-dimensional Hamiltonian, with parameters determined by constrained relativistic mean-field calculations for triaxial shapes. The results reproduce available data, and show that there is an abrupt change of structure at N = 90, that corresponds to a first-order quantum phase transition between spherical and axially deformed shapes.

  12. Acoustic resonance phase locked photoacoustic spectrometer

    DOE Patents [OSTI]

    Pilgrim, Jeffrey S.; Bomse, David S.; Silver, Joel A.

    2003-08-19

    A photoacoustic spectroscopy method and apparatus for maintaining an acoustic source frequency on a sample cell resonance frequency comprising: providing an acoustic source to the sample cell to generate a photoacoustic signal, the acoustic source having a source frequency; continuously measuring detection phase of the photoacoustic signal with respect to source frequency or a harmonic thereof; and employing the measured detection phase to provide magnitude and direction for correcting the source frequency to the resonance frequency.

  13. Phase-sensitive X-ray imager

    DOE Patents [OSTI]

    Baker, Kevin Louis

    2013-01-08

    X-ray phase sensitive wave-front sensor techniques are detailed that are capable of measuring the entire two-dimensional x-ray electric field, both the amplitude and phase, with a single measurement. These Hartmann sensing and 2-D Shear interferometry wave-front sensors do not require a temporally coherent source and are therefore compatible with x-ray tubes and also with laser-produced or x-pinch x-ray sources.

  14. PROJECT SELECTIONS FOR DOE PHASE III XLERATOR SMALL BUSINESS PROGRAM |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy PROJECT SELECTIONS FOR DOE PHASE III XLERATOR SMALL BUSINESS PROGRAM PROJECT SELECTIONS FOR DOE PHASE III XLERATOR SMALL BUSINESS PROGRAM PDF icon SBIR_Phase_III.pdf More Documents & Publications SBIR_Phase_III.pdf PROJECT SELECTIONS FOR DOE PHASE III XLERATOR SMALL BUSINESS PROGRAM - pg 3 Albany HTS Power Cable

  15. Phase-field Modeling of Nucleation in Solid-State Phase Transformations

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect Phase-field Modeling of Nucleation in Solid-State Phase Transformations Citation Details In-Document Search Title: Phase-field Modeling of Nucleation in Solid-State Phase Transformations Authors: Heo, T W ; Chen, L Q Publication Date: 2014-02-19 OSTI Identifier: 1212137 Report Number(s): LLNL-JRNL-650216 DOE Contract Number: DE-AC52-07NA27344 Resource Type: Journal Article Resource Relation: Journal Name: JOM, vol. 66, no. 8, June 25, 2014, pp. 1520

  16. Cummins Power Generation SECA Phase 1

    SciTech Connect (OSTI)

    Charles Vesely

    2007-08-17

    The following report documents the progress of the Cummins Power Generation (CPG) SECA Phase 1 SOFC development and final testing under the U.S. Department of Energy Solid State Energy Conversion Alliance (SECA) contract DE-FC26-01NT41244. This report overviews and summarizes CPG and partner research development leading to successful demonstration of the SECA Phase 1 objectives and significant progress towards SOFC commercialization. Significant Phase 1 Milestones: (1) Demonstrated: (a) Operation meeting Phase 1 requirements on commercial natural gas. (b) LPG and Natural Gas CPOX fuel reformers. (c) SOFC systems on dry CPOX reformate. (c) Steam reformed Natural Gas operation. (d) Successful start-up and shut-down of SOFC system without inert gas purge. (e) Utility of stack simulators as a tool for developing balance of plant systems. (2) Developed: (a) Low cost balance of plant concepts and compatible systems designs. (b) Identified low cost, high volume components for balance of plant systems. (c) Demonstrated high efficiency SOFC output power conditioning. (d) Demonstrated SOFC control strategies and tuning methods. The Phase 1 performance test was carried out at the Cummins Power Generation facility in Minneapolis, Minnesota starting on October 2, 2006. Performance testing was successfully completed on January 4, 2007 including the necessary steady-state, transient, efficiency, and peak power operation tests.

  17. Phase relationship in coal ash corrosion products

    SciTech Connect (OSTI)

    Kalmanovitch, D.

    1996-12-31

    The corrosion of heat transfer surfaces in coal-fired utility boilers is a major concern to the efficient operation of these units. Despite the importance of the corrosion there has been limited research on the relationship between the ash components on the tube surface and the interactions and reactions between the various components and the steel surface. Mechanisms such as molten phase corrosion, sulfidation, and high temperature oxidation have been identified as leading to extensive wastage oftube metal. However, while the corrosion process can be identified using techniques such as metallography and x-ray diffraction there is limited insight into the role ofthe coal mineralogy and ash deposits on the surface in the corrosion process. This paper describes research into the formation of molten or sernimolten phases within ash deposits which are associated with corrosion of superheater and reheater fireside surfaces. For example, the phases potassium pyrosulfate (K{sub 2}S{sub 2}O{sub 7}) and potassium aluminum sulfate (K{sub 2}Al{sub 2}SO{sub 7}) have been determined by x-ray diffraction to be present in deposits where fireside corrosion has occurred. However, both these phases are not directly derived from coal minerals or the common matrix observed in ash deposits. The examination of the reactions and interactions within deposits which result in the formation of these and other phases associated with corrosion will be discussed in the paper.

  18. Phase relationships in coal ash corrosion products

    SciTech Connect (OSTI)

    Kalmanovitch, D.

    1996-10-01

    The corrosion of heat transfer surfaces in coal-fired utility boilers is a major concern to the efficient operation of these units. Despite the importance of the corrosion there has been limited research on the relationship between the ash components on the tube surface and the interactions and reactions between the various components and the steel surface. Mechanisms such as molten phase corrosion, sulfidation, and high temperature oxidation have been identified as leading to extensive wastage of tube metal. This paper describes research into the formation of molten or semimolten phases within ash deposits which are associated with corrosion of superheater and reheater fireside surfaces. For example, the phases potassium pyrosulfate (K{sub 2}S{sub 2}O{sub 7}) and potassium aluminum sulfate (K{sub 2}Al{sub 2}SO{sub 7}) have been determined by x-ray diffraction to be present in deposits where fireside corrosion has occurred. However, both these phases are not directly derived from coal minerals or the common matrix observed in ash deposits. The examination of the reactions and interactions within deposits which result a the formation of these and other phases associated with corrosion will be discussed in the paper.

  19. Brigantine OffshoreMW Phase 1 | Open Energy Information

    Open Energy Info (EERE)

    Brigantine OffshoreMW Phase 1 Jump to: navigation, search Name Brigantine OffshoreMW Phase 1 Facility Brigantine OffshoreMW Phase 1 Sector Wind energy Facility Type Offshore Wind...

  20. Nine Canyon Wind Farm Phase II | Open Energy Information

    Open Energy Info (EERE)

    Farm Phase II Jump to: navigation, search Name Nine Canyon Wind Farm Phase II Facility Nine Canyon Wind Farm Phase II Sector Wind energy Facility Type Commercial Scale Wind...

  1. I 95 Landfill Phase II Biomass Facility | Open Energy Information

    Open Energy Info (EERE)

    I 95 Landfill Phase II Biomass Facility Jump to: navigation, search Name I 95 Landfill Phase II Biomass Facility Facility I 95 Landfill Phase II Sector Biomass Facility Type...

  2. Phase-1 of NERSC's Cray Edison System Has Arrived

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Phase-1 of NERSC's Cray Edison System Has Arrived Phase-1 of NERSC's Cray Edison System Has Arrived November 28, 2012 by Francesca Verdier Phase-1 of the new Edison system, a Cray...

  3. All Users Now Enabled on Edison Phase 2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Users Now Enabled on Edison Phase 2 All Users Now Enabled on Edison Phase 2 August 30, 2013 by Francesca Verdier All user accounts have been enabled on the second phase of Edison,...

  4. Reverse phase transformation of martensite to austenite in stainless...

    Office of Scientific and Technical Information (OSTI)

    steels: a 3D phase-field study Citation Details In-Document Search Title: Reverse phase transformation of martensite to austenite in stainless steels: a 3D phase-field ...

  5. Kibby Mountain Phase I Wind Farm | Open Energy Information

    Open Energy Info (EERE)

    Kibby Mountain Phase I Wind Farm Jump to: navigation, search Name Kibby Mountain Phase I Wind Farm Facility Kibby Mountain Phase I Sector Wind energy Facility Type Commercial Scale...

  6. Experimental phasing for structure determination using membrane-protein

    Office of Scientific and Technical Information (OSTI)

    crystals grown by the lipid cubic phase method (Journal Article) | SciTech Connect Experimental phasing for structure determination using membrane-protein crystals grown by the lipid cubic phase method Citation Details In-Document Search Title: Experimental phasing for structure determination using membrane-protein crystals grown by the lipid cubic phase method Very little information is available in the literature concerning the experimental heavy-atom phasing of membrane-protein structures

  7. Innovative Phase Change Thermal Energy Storage Solution for Baseload Power

    Office of Scientific and Technical Information (OSTI)

    Phase 1 Final Report (Technical Report) | SciTech Connect SciTech Connect Search Results Technical Report: Innovative Phase Change Thermal Energy Storage Solution for Baseload Power Phase 1 Final Report Citation Details In-Document Search Title: Innovative Phase Change Thermal Energy Storage Solution for Baseload Power Phase 1 Final Report The primary purpose of this project is to develop and validate an innovative, scalable phase change salt thermal energy storage (TES) system that can

  8. Ponderomotive phase plate for transmission electron microscopes (Patent) |

    Office of Scientific and Technical Information (OSTI)

    DOEPatents Ponderomotive phase plate for transmission electron microscopes Title: Ponderomotive phase plate for transmission electron microscopes A ponderomotive phase plate system and method for controllably producing highly tunable phase contrast transfer functions in a transmission electron microscope (TEM) for high resolution and biological phase contrast imaging. The system and method includes a laser source and a beam transport system to produce a focused laser crossover as a phase

  9. Theory and modelling of nanocarbon phase stability.

    SciTech Connect (OSTI)

    Barnard, A. S.

    2006-01-01

    The transformation of nanodiamonds into carbon-onions (and vice versa) has been observed experimentally and has been modeled computationally at various levels of sophistication. Also, several analytical theories have been derived to describe the size, temperature and pressure dependence of this phase transition. However, in most cases a pure carbon-onion or nanodiamond is not the final product. More often than not an intermediary is formed, known as a bucky-diamond, with a diamond-like core encased in an onion-like shell. This has prompted a number of studies investigating the relative stability of nanodiamonds, bucky-diamonds, carbon-onions and fullerenes, in various size regimes. Presented here is a review outlining results of numerous theoretical studies examining the phase diagrams and phase stability of carbon nanoparticles, to clarify the complicated relationship between fullerenic and diamond structures at the nanoscale.

  10. A new phase in palladium hydride technology

    SciTech Connect (OSTI)

    Walters, R.T.

    1991-12-31

    Two plateaux are observed in both the absorption and desorption isotherms of palladium hydride. For the absorption isotherm, a change in plateau pressure is observed at a hydrogen-to-metal (H/M) ratio of about 0.35 for all temperatures studied. For the desorption isotherm, the change in plateau pressure appears to be a function of temperature, ranging from an H/M ratio of 0.18 at 80{degrees}C to 0.3 at 140{degrees}C. These data are interpreted as being experimentally observed boundaries to an equilibrium phase line located in the miscibility gap of the palladium/hydrogen phase diagram. This new phase does not appear to be a stoichiometric compounds, but rather its composition seems to vary with temperature. 6 refs., 4 figs.

  11. A new phase in palladium hydride technology

    SciTech Connect (OSTI)

    Walters, R.T.

    1991-01-01

    Two plateaux are observed in both the absorption and desorption isotherms of palladium hydride. For the absorption isotherm, a change in plateau pressure is observed at a hydrogen-to-metal (H/M) ratio of about 0.35 for all temperatures studied. For the desorption isotherm, the change in plateau pressure appears to be a function of temperature, ranging from an H/M ratio of 0.18 at 80{degrees}C to 0.3 at 140{degrees}C. These data are interpreted as being experimentally observed boundaries to an equilibrium phase line located in the miscibility gap of the palladium/hydrogen phase diagram. This new phase does not appear to be a stoichiometric compounds, but rather its composition seems to vary with temperature. 6 refs., 4 figs.

  12. Phase contrast in high resolution electron microscopy

    DOE Patents [OSTI]

    Rose, H.H.

    1975-09-23

    This patent relates to a device for developing a phase contrast signal for a scanning transmission electron microscope. The lens system of the microscope is operated in a condition of defocus so that predictable alternate concentric regions of high and low electron density exist in the cone of illumination. Two phase detectors are placed beneath the object inside the cone of illumination, with the first detector having the form of a zone plate, each of its rings covering alternate regions of either higher or lower electron density. The second detector is so configured that it covers the regions of electron density not covered by the first detector. Each detector measures the number of electrons incident thereon and the signal developed by the first detector is subtracted from the signal developed by the record detector to provide a phase contrast signal. (auth)

  13. Phase Segregation in Polystyrene?Polylactide Blends

    SciTech Connect (OSTI)

    Leung, Bonnie; Hitchcock, Adam; Brash, John; Scholl, Andreas; Doran, Andrew

    2010-06-09

    Spun-cast films of polystyrene (PS) blended with polylactide (PLA) were visualized and characterized using atomic force microscopy (AFM) and synchrotron-based X-ray photoemission electron microscopy (X-PEEM). The composition of the two polymers in these systems was determined by quantitative chemical analysis of near-edge X-ray absorption signals recorded with X-PEEM. The surface morphology depends on the ratio of the two components, the total polymer concentration, and the temperature of vacuum annealing. For most of the blends examined, PS is the continuous phase with PLA existing in discrete domains or segregated to the air?polymer interface. Phase segregation was improved with further annealing. A phase inversion occurred when films of a 40:60 PS:PLA blend (0.7 wt percent loading) were annealed above the glass transition temperature (Tg) of PLA.

  14. Towards a Characterization of Arctic Mixed-Phase Clouds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    manual classification of cloud phase. Using collocated cloud radar and depolarization lidar observations, it is shown that mixed-phase conditions have a high correlation with a...

  15. Phase coexistence and transformations in field-cooled ternary...

    Office of Scientific and Technical Information (OSTI)

    Phase coexistence and transformations in field-cooled ternary piezoelectric single ... Title: Phase coexistence and transformations in field-cooled ternary piezoelectric single ...

  16. Microstructural Effects on Void Nucleation in Single-Phase Copper...

    Office of Scientific and Technical Information (OSTI)

    in Single-Phase Copper Polycrystals Citation Details In-Document Search Title: Microstructural Effects on Void Nucleation in Single-Phase Copper Polycrystals You are ...

  17. 3 Phases Energy Services LLC | Open Energy Information

    Open Energy Info (EERE)

    Phases Energy Services LLC Jump to: navigation, search Name: 3 Phases Energy Services LLC Place: San Francisco, California Zip: CA 94129 Product: San Francisco-based developer &...

  18. Multiyear Program Plan Template - Phase II Guidance | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Multiyear Program Plan Template - Phase II Guidance Multiyear Program Plan Template - Phase II Guidance EERE template and guidance for program managers to develop multiyear plans, ...

  19. DOE Awards Two Small Business Innovation Research Phase II Grants...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Two Small Business Innovation Research Phase II Grants for Solid-State Lighting Technology DOE Awards Two Small Business Innovation Research Phase II Grants for Solid-State ...

  20. Giant Nonhysteretic Responses of Two-Phase Nanostructured Alloys...

    Office of Scientific and Technical Information (OSTI)

    Giant Nonhysteretic Responses of Two-Phase Nanostructured Alloys Citation Details In-Document Search Title: Giant Nonhysteretic Responses of Two-Phase Nanostructured Alloys ...

  1. Phase II Accident Investigation Board Briefing | Department of...

    Office of Environmental Management (EM)

    Phase II Accident Investigation Board Briefing Phase II Accident Investigation Board Briefing Topic: Ted Wyka DOE, Provided a Brief on the Findings in the WIPP Accident ...

  2. Kotzebue Wind Project Phase II & III | Open Energy Information

    Open Energy Info (EERE)

    II & III Jump to: navigation, search Name Kotzebue Wind Project Phase II & III Facility Kotzebue Wind Project Phase II & III Sector Wind energy Facility Type Commercial Scale Wind...

  3. Victory Gardens Phase IV Wind Farm II | Open Energy Information

    Open Energy Info (EERE)

    II Jump to: navigation, search Name Victory Gardens Phase IV Wind Farm II Facility Victory Gardens- Phase IV Sector Wind energy Facility Type Commercial Scale Wind Facility Status...

  4. Emittance and Phase Space Exchange (Conference) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Emittance and Phase Space Exchange Citation Details In-Document Search Title: Emittance and Phase Space Exchange You are accessing a document from the Department of Energy's ...

  5. Emittance and phase space exchange for advanced beam manipulation...

    Office of Scientific and Technical Information (OSTI)

    Emittance and phase space exchange for advanced beam manipulation and diagnostics Citation Details In-Document Search Title: Emittance and phase space exchange for advanced beam ...

  6. Emittance and Phase Space Exchange for Advanced Beam Manipulation...

    Office of Scientific and Technical Information (OSTI)

    Emittance and Phase Space Exchange for Advanced Beam Manipulation and Diagnostics Citation Details In-Document Search Title: Emittance and Phase Space Exchange for Advanced Beam ...

  7. Project Profile: Innovative Application of Maintenance-Free Phase...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Innovative Application of Maintenance-Free Phase-Change Thermal Energy Storage for Dish Systems Project Profile: Innovative Application of Maintenance-Free Phase-Change Thermal ...

  8. Factors Affecting HCCI Combustion Phasing for Fuels with Single...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Affecting HCCI Combustion Phasing for Fuels with Single- and Dual-Stage Chemistry Factors Affecting HCCI Combustion Phasing for Fuels with Single- and Dual-Stage Chemistry 2004 ...

  9. Stabilizing Topological Phases in Graphene via Random Adsorption...

    Office of Scientific and Technical Information (OSTI)

    Stabilizing Topological Phases in Graphene via Random Adsorption Title: Stabilizing Topological Phases in Graphene via Random Adsorption Authors: Jiang, Hua ; Qiao, Zhenhua ; Liu, ...

  10. Materials Engineering and Scale Up of Fluid Phase Chemical Hydrogen...

    Office of Scientific and Technical Information (OSTI)

    Fluid Phase Chemical Hydrogen Storage for Automotive Applications Citation Details In-Document Search Title: Materials Engineering and Scale Up of Fluid Phase Chemical Hydrogen ...

  11. Phase transitions in ferroic and multiferroic materials (Conference...

    Office of Scientific and Technical Information (OSTI)

    Phase transitions in ferroic and multiferroic materials Citation Details In-Document Search Title: Phase transitions in ferroic and multiferroic materials You are accessing a...

  12. Phase Diagram and Electronic Structure of Praseodymium and Plutonium...

    Office of Scientific and Technical Information (OSTI)

    Phase Diagram and Electronic Structure of Praseodymium and Plutonium Citation Details In-Document Search Title: Phase Diagram and Electronic Structure of Praseodymium and Plutonium...

  13. ?-tin?Imma?sh Phase Transitions of Germanium (Journal Article...

    Office of Scientific and Technical Information (OSTI)

    DOE PAGES Search Results Publisher's Accepted Manuscript: -tinImmash Phase Transitions of Germanium Prev Next Title: -tinImmash Phase Transitions of Germanium...

  14. Phase Diagram and Electronic Structure of Praseodymium and Plutonium...

    Office of Scientific and Technical Information (OSTI)

    Published Article: Phase Diagram and Electronic Structure of Praseodymium and Plutonium Prev Next Title: Phase Diagram and Electronic Structure of Praseodymium and Plutonium...

  15. PROJECT SELECTIONS FOR DOE PHASE III XLERATOR SMALL BUSINESS...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    PROJECT SELECTIONS FOR DOE PHASE III XLERATOR SMALL BUSINESS PROGRAM PROJECT SELECTIONS FOR DOE PHASE III XLERATOR SMALL BUSINESS PROGRAM PDF icon SBIRPhaseIII.pdf More Documents...

  16. Phase transitions in ferroic and multiferroic materials (Conference...

    Office of Scientific and Technical Information (OSTI)

    Phase transitions in ferroic and multiferroic materials Citation Details In-Document Search Title: Phase transitions in ferroic and multiferroic materials Authors: Saxena, Avadh B...

  17. Demonstration of a Variable Phase Turbine Power System for Low...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Demonstration of a Variable Phase Turbine Power System for Low Temperature Geothermal Resources Demonstration of a Variable Phase Turbine Power System for Low Temperature ...

  18. Repeat-until-success cubic phase gate for universal continuous...

    Office of Scientific and Technical Information (OSTI)

    phase gate for universal continuous-variable quantum computation Citation Details In-Document Search Title: Repeat-until-success cubic phase gate for universal ...

  19. Smart Grid Cybersecurity: Job Performance Model Report and Phase...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cybersecurity: Job Performance Model Report and Phase 1 Overview (August 2012) Smart Grid Cybersecurity: Job Performance Model Report and Phase 1 Overview (August 2012) In the ...

  20. Energy Department Announces Winner of Final Phase of Smart Grid...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Winner of Final Phase of Smart Grid Data Access Funding Opportunity Energy Department Announces Winner of Final Phase of Smart Grid Data Access Funding Opportunity December 19, ...

  1. Quasiparticle random-phase approximation with interactions from...

    Office of Scientific and Technical Information (OSTI)

    Quasiparticle random-phase approximation with interactions from the Similarity Renormalization Group Citation Details In-Document Search Title: Quasiparticle random-phase ...

  2. Miscibility gap closure, interface morphology, and phase microstructur...

    Office of Scientific and Technical Information (OSTI)

    Miscibility gap closure, interface morphology, and phase microstructure of 3D LixFePO4 ... Title: Miscibility gap closure, interface morphology, and phase microstructure of 3D ...

  3. Innovative Application of Maintenance-Free Phase-Change Thermal...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Application of Maintenance-Free Phase-Change Thermal Energy Storage for Dish Engine Solar Power Generation Innovative Application of Maintenance-Free Phase-Change Thermal Energy ...

  4. Phase 2 Report: Oahu Wind Integration and Transmission Study...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Phase 2 Report: Oahu Wind Integration and Transmission Study (OWITS); Hawaiian Islands Transmission Interconnection Project Phase 2 Report: Oahu Wind Integration and Transmission ...

  5. High Performance Zintl Phase TE Materials with Embedded Particles...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Presents results from embedding nanoparticles in magnesium silicide alloy matrix ... Zintl Phase Materials with Embedded Nanoparticles High performance Zintl phase TE ...

  6. Innovative Phase hange Thermal Energy Storage Solution for Baseload...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Phase hange Thermal Energy Storage Solution for Baseload Power Innovative Phase hange Thermal Energy Storage Solution for Baseload Power This presentation was delivered at the ...

  7. Metallic Composites Phase-Change Materials for High-Temperature...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Metallic Composites Phase-Change Materials for High-Temperature Thermal Energy Storage Metallic Composites Phase-Change Materials for High-Temperature Thermal Energy Storage This ...

  8. Project Profile: Innovative Phase Change Thermal Energy Storage...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Phase Change Thermal Energy Storage Solution for Baseload Power Project Profile: Innovative Phase Change Thermal Energy Storage Solution for Baseload Power Infinia logo Infinia, ...

  9. Project Profile: Indirect, Dual-Media, Phase Changing Material...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Indirect, Dual-Media, Phase Changing Material Modular Thermal Energy Storage System Project Profile: Indirect, Dual-Media, Phase Changing Material Modular Thermal Energy Storage ...

  10. Using Encapsulated Phase Change Material for Thermal Energy Storage...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Encapsulated Phase Change Material for Thermal Energy Storage for Baseload CSP Using Encapsulated Phase Change Material for Thermal Energy Storage for Baseload CSP This ...

  11. Fractional Topological Phases and Broken Time-Reversal Symmetry...

    Office of Scientific and Technical Information (OSTI)

    Fractional Topological Phases and Broken Time-Reversal Symmetry in Strained Graphene Title: Fractional Topological Phases and Broken Time-Reversal Symmetry in Strained Graphene ...

  12. Unbalanced edge modes and topological phase transition in gated...

    Office of Scientific and Technical Information (OSTI)

    Unbalanced edge modes and topological phase transition in gated trilayer graphene Title: Unbalanced edge modes and topological phase transition in gated trilayer graphene Authors: ...

  13. Surface plasmon sensing of gas phase contaminants using optical...

    Office of Scientific and Technical Information (OSTI)

    Surface plasmon sensing of gas phase contaminants using optical fiber. Citation Details In-Document Search Title: Surface plasmon sensing of gas phase contaminants using optical ...

  14. Study of Stationary Phase Metabolism Via Isotopomer Analysis...

    Office of Scientific and Technical Information (OSTI)

    production of many commercially important secondary metabolites occurs during stationary phase, and methods to measure metabolic flux during this growth phase would be valuable. ...

  15. FY2017 SBIR/EERE Phase I Awardees

    Broader source: Energy.gov [DOE]

    View the current portfolio of 2017 Phase I Small Business Innovation Research EERE awardees below. Learn more about the program phases.

  16. Hysteresis, phase transitions, and dangerous transients in electrical...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Hysteresis, phase transitions, and dangerous transients in electrical power distribution systems Citation Details In-Document Search Title: Hysteresis, phase ...

  17. Solano Wind Project- phase II | Open Energy Information

    Open Energy Info (EERE)

    search Name Solano Wind Project- phase II Facility Solano Wind Project- phase II Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service Owner...

  18. Milford Wind Corridor Phase I (GE Energy) | Open Energy Information

    Open Energy Info (EERE)

    I (GE Energy) Jump to: navigation, search Name Milford Wind Corridor Phase I (GE Energy) Facility Milford Wind Corridor Phase I (GE Energy) Sector Wind energy Facility Type...

  19. Milford Wind Corridor Phase II | Open Energy Information

    Open Energy Info (EERE)

    II Jump to: navigation, search Name Milford Wind Corridor Phase II Facility Milford Wind Corridor Phase II Sector Wind energy Facility Type Commercial Scale Wind Facility Status In...

  20. Milford Wind Corridor Phase I (Clipper) Wind Farm | Open Energy...

    Open Energy Info (EERE)

    Clipper) Wind Farm Jump to: navigation, search Name Milford Wind Corridor Phase I (Clipper) Wind Farm Facility Milford Wind Corridor Phase I (Clipper) Sector Wind energy Facility...

  1. Fluctuations, Phase Transitions, and Latent Heat in Short Diblock...

    Office of Scientific and Technical Information (OSTI)

    Phase Transitions, and Latent Heat in Short Diblock Copolymers: Comparison of Experiment, Simulation, and Theory Citation Details In-Document Search Title: Fluctuations, Phase...

  2. Phase Discrimination through Oxidant Selection for Iron Oxide...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Phase Discrimination through Oxidant Selection for Iron Oxide Ultrathin Films Home > Research > ANSER Research Highlights > Phase Discrimination through Oxidant Selection for Iron...

  3. FY2016 SBIR\\EERE Phase I Award Selections

    Broader source: Energy.gov [DOE]

    View the current portfolio of 2016 Phase I Small Business Innovation Research EERE awardees below. Learn more about the program phases.

  4. High-pressure Raman spectroscopy of phase change materials (Journal...

    Office of Scientific and Technical Information (OSTI)

    Title: High-pressure Raman spectroscopy of phase change materials We used high-pressure Raman spectroscopy to study the evolution of vibrational frequencies of the phase change ...

  5. Hydrodesulfurization catalyst by Chevrel phase compounds

    DOE Patents [OSTI]

    McCarty, K.F.; Schrader, G.L.

    1985-05-20

    A process is disclosed for the hydrodesulfurization of sulfur-containing hydrocarbon fuel with reduced ternary molybdenum sulfides, known as Chevrel phase compounds. Chevrel phase compounds of the general composition M/sub x/Mo/sub 6/S/sub 8/, with M being Ho, Pb, Sn, Ag, In, Cu, Fe, Ni, or Co, were found to have hydrodesulfurization activities comparable to model unpromoted and cobalt-promoted MoS/sub 2/ catalysts. The most active catalysts were the ''large'' cation compounds (Ho, Pb, Sn), and the least active catalysts were the ''small'' cation compounds (Cu, Fe, Ni, Co.).

  6. Hydrodesulfurization catalysis by Chevrel phase compounds

    DOE Patents [OSTI]

    McCarty, Kevin F. (Livermore, CA); Schrader, Glenn L. (Ames, IA)

    1985-12-24

    A process is disclosed for the hydrodesulfurization of sulfur-containing hydrocarbon fuel with reduced ternary molybdenum sulfides, known as Chevrel phase compounds. Chevrel phase compounds of the general composition M.sub.x Mo.sub.6 S.sub.8, with M being Ho, Pb, Sn, Ag, In, Cu, Fe, Ni, or Co, were found to have hydrodesulfurization activities comparable to model unpromoted and cobalt-promoted MoS.sub.2 catalysts. The most active catalysts were the "large" cation compounds (Ho, Pb, Sn), and the least active catalysts were the "small" cation compounds (Cu, Fe, Ni, Co.).

  7. SLUDGE BATCH 6 PHASE II FLOWSHEET SIMULATIONS

    SciTech Connect (OSTI)

    Koopman, D.; Best, D.

    2010-03-30

    Two Sludge Receipt and Adjustment Tank (SRAT) runs were used to demonstrate that a fairly wide window of acid stoichiometry was available for processing SB6 Phase II flowsheet simulant (Tank 40 simulant) while still meeting the dual goals of acceptable nitrate destruction and controlled hydrogen generation. Phase II was an intermediate flowsheet study for the projected composition of Tank 40 after transfer of SB6/Tank 51 sludge to the heel of SB5. The composition was based on August 2009 projections. A window of about 50% in total acid was found between acceptable nitrite destruction and excessive hydrogen generation.

  8. Receptors useful for gas phase chemical sensing

    DOE Patents [OSTI]

    Jaworski, Justyn W; Lee, Seung-Wuk; Majumdar, Arunava; Raorane, Digvijay A

    2015-02-17

    The invention provides for a receptor, capable of binding to a target molecule, linked to a hygroscopic polymer or hydrogel; and the use of this receptor in a device for detecting the target molecule in a gaseous and/or liquid phase. The invention also provides for a method for detecting the presence of a target molecule in the gas phase using the device. In particular, the receptor can be a peptide capable of binding a 2,4,6-trinitrotoluene (TNT) or 2,4,-dinitrotoluene (DNT).

  9. A Controlled Phase Transition | Jefferson Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A Controlled Phase Transition A Controlled Phase Transition August 20, 2013 Since May 18, 2012, CEBAF has not accelerated an electron. In fact, for a significant fraction of that time the accelerator, as such, did not exist. Magnets were removed from the tunnel to be refurbished and upgraded to accommodate higher 12 GeV beam energies. This was done by adding a fourth leg of steel return yoke to existing C-frame magnets. Several of the dipole arcs were completed during the six-month shutdown in

  10. Ohio Hydropower Potential Inventory Phase I report

    SciTech Connect (OSTI)

    Not Available

    1981-12-01

    The dams researched in the Ohio Department of Natural Resources (ODNR) files were those contained in a list of Ohio dams provided by the ODNR. The result of this file research is a list of 997 dams contained herein that tabulates information on hydraulic head, stream flow, drainage area, and usage. This listing indicated that all but 137 of the 997 dams can be eliminated from consideration for Phase II research. The second phase would be required to further identify which of the 137 dams might have viable hydroelectric potential and define their basic hydroelectric parameters.

  11. Cori Phase 1 for Edison Users

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Users Cori Phase 1 for Edison Users Running jobs on Cori is similar to running jobs on Edison except for the processor, memory, and batch scheduler. Cori uses a new batch scheduler, SLURM. Edison used Torque/Moab batch scheduler until Nov 30, 2015. Cori Phase 1 has a total of 1630 compute nodes, 32 cores per node, each node has two sockets, each socket is populated with a 16-core Intel "Haswell" processor at 2.3 GHz. Edison has a total of 24 cores per node, each node has two sockets,

  12. Wind Turbine Drivetrain Condition Monitoring During GRC Phase 1 and Phase 2 Testing

    SciTech Connect (OSTI)

    Sheng, S.; Link, H.; LaCava, W.; van Dam, J.; McNiff, B.; Veers, P.; Keller, J.; Butterfield, S.; Oyague, F.

    2011-10-01

    This report will present the wind turbine drivetrain condition monitoring (CM) research conducted under the phase 1 and phase 2 Gearbox Reliability Collaborative (GRC) tests. The rationale and approach for this drivetrain CM research, investigated CM systems, test configuration and results, and a discussion on challenges in wind turbine drivetrain CM and future research and development areas, will be presented.

  13. Study of phase I NOx control: Lessons learned for phase II NOx control strategies

    SciTech Connect (OSTI)

    Myers, B.

    1996-12-31

    Title IV of the Clean Air Act Amendments of 1990 (CAAA) is concerned with lowering the levels of acid rain in the USA. One of the contributions to acid rain is nitric oxides referred to as NO{sub x}. Title IV seeks NO{sub x} reductions from two groupings of utility steam generators. The first group, known as Phase I, was to have their reductions made by January 1, 1996. The purpose of this paper is to look back at Phase I to see what one can learn for use in Phase II compliance planning. Phase II units are scheduled to be in compliance by January 1, 2000. As such, this paper looks to answer four questions about Phase I units.

  14. Polyolefin composites containing a phase change material

    DOE Patents [OSTI]

    Salyer, Ival O. (Dayton, OH)

    1991-01-01

    A composite useful in thermal energy storage, said composite being formed of a polyolefin matrix having a phase change material such as a crystalline alkyl hydrocarbon incorporated therein, said polyolefin being thermally form stable; the composite is useful in forming pellets, sheets or fibers having thermal energy storage characteristics; methods for forming the composite are also disclosed.

  15. The geometric phase controls ultracold chemistry

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kendrick, B. K.; Hazra, Jisha; Balakrishnan, N.

    2015-07-30

    In this study, the geometric phase is shown to control the outcome of an ultracold chemical reaction. The control is a direct consequence of the sign change on the interference term between two scattering pathways (direct and looping), which contribute to the reactive collision process in the presence of a conical intersection (point of degeneracy between two Born–Oppenheimer electronic potential energy surfaces). The unique properties of the ultracold energy regime lead to an effective quantization of the scattering phase shift enabling maximum constructive or destructive interference between the two pathways. By taking the O + OH → H + O2more » reaction as an illustrative example, it is shown that inclusion of the geometric phase modifies ultracold reaction rates by nearly two orders of magnitude. Interesting experimental control possibilities include the application of external electric and magnetic fields that might be used to exploit the geometric phase effect reported here and experimentally switch on or off the reactivity.« less

  16. Critical point analysis of phase envelope diagram

    SciTech Connect (OSTI)

    Soetikno, Darmadi; Siagian, Ucok W. R.; Kusdiantara, Rudy Puspita, Dila Sidarto, Kuntjoro A. Soewono, Edy; Gunawan, Agus Y.

    2014-03-24

    Phase diagram or phase envelope is a relation between temperature and pressure that shows the condition of equilibria between the different phases of chemical compounds, mixture of compounds, and solutions. Phase diagram is an important issue in chemical thermodynamics and hydrocarbon reservoir. It is very useful for process simulation, hydrocarbon reactor design, and petroleum engineering studies. It is constructed from the bubble line, dew line, and critical point. Bubble line and dew line are composed of bubble points and dew points, respectively. Bubble point is the first point at which the gas is formed when a liquid is heated. Meanwhile, dew point is the first point where the liquid is formed when the gas is cooled. Critical point is the point where all of the properties of gases and liquids are equal, such as temperature, pressure, amount of substance, and others. Critical point is very useful in fuel processing and dissolution of certain chemicals. Here in this paper, we will show the critical point analytically. Then, it will be compared with numerical calculations of Peng-Robinson equation by using Newton-Raphson method. As case studies, several hydrocarbon mixtures are simulated using by Matlab.

  17. Kinetics of silica-phase transitions

    SciTech Connect (OSTI)

    Duffy, C.J.

    1993-07-01

    In addition to the stable silica polymorph quartz, several metastable silica phases are present in Yucca Mountain. The conversion of these phases to quartz is accompanied by volume reduction and a decrease in the aqueous silica activity, which may destabilize clinoptilolite and mordenite. The primary reaction sequence for the silica phases is from opal or glass to disordered opal-CT, followed by ordering of the opal-CT and finally by the crystallization of quartz. The ordering of opal-CT takes place in the solid state, whereas the conversion of opal-CT takes place through dissolution-reprecipitation involving the aqueous phase. It is proposed that the rate of conversion of opal-CT to quartz is controlled by diffusion of defects out of a disordered surface layer formed on the crystallizing quartz. The reaction rates are observed to be dependent on temperature, pressure, degree of supersaturation, and pH. Rate equations selected from the literature appear to be consistent with observations at Yucca Mountain.

  18. Phased Contrast X-Ray Imaging

    ScienceCinema (OSTI)

    Erin Miller

    2012-12-31

    The Pacific Northwest National Laboratory is developing a range of technologies to broaden the field of explosives detection. Phased contrast X-ray imaging, which uses silicon gratings to detect distortions in the X-ray wave front, may be applicable to mail or luggage scanning for explosives; it can also be used in detecting other contraband, small-parts inspection, or materials characterization.

  19. TWRS Privatization Phase 1 Master Site Plan

    SciTech Connect (OSTI)

    PARAZIN, R.J.

    1999-08-16

    This document provides a reference for the development of the Tank Waste Remediation System (TWRS) Privatization Phase I site (former Grout Disposal Compound) and the upgrades and extension to the site of the 200 East Area inter- and intra-area roads and various utilities.

  20. Dry phase reactor for generating medical isotopes

    DOE Patents [OSTI]

    Mackie, Thomas Rockwell; Heltemes, Thad Alexander

    2016-05-03

    An apparatus for generating medical isotopes provides for the irradiation of dry-phase, granular uranium compounds which are then dissolved in a solvent for separation of the medical isotope from the irradiated compound. Once the medical isotope is removed, the dissolved compound may be reconstituted in dry granular form for repeated irradiation.

  1. Phase change thermal energy storage material

    DOE Patents [OSTI]

    Benson, David K.; Burrows, Richard W.

    1987-01-01

    A thermal energy storge composition is disclosed. The composition comprises a non-chloride hydrate having a phase change transition temperature in the range of 70.degree.-95.degree. F. and a latent heat of transformation of at least about 35 calories/gram.

  2. Phase Transformations in Cast Duplex Stainless Steels

    SciTech Connect (OSTI)

    Yoon-Jun Kim

    2004-12-19

    Duplex stainless steels (DSS) constitute both ferrite and austenite as a matrix. Such a microstructure confers a high corrosion resistance with favorable mechanical properties. However, intermetallic phases such as {sigma} and {chi} can also form during casting or high-temperature processing and can degrade the properties of the DSS. This research was initiated to develop time-temperature-transformation (TTT) and continuous-cooling-transformation (CCT) diagrams of two types of cast duplex stainless steels, CD3MN (Fe-22Cr-5Ni-Mo-N) and CD3MWCuN (Fe-25Cr-7Ni-Mo-W-Cu-N), in order to understand the time and temperature ranges for intermetallic phase formation. The alloys were heat treated isothermally or under controlled cooling conditions and then characterized using conventional metallographic methods that included tint etching, and also using electron microscopy (SEM, TEM) and wavelength dispersive spectroscopy (WDS). The kinetics of intermetallic-phase ({sigma} + {chi}) formation were analyzed using the Johnson-Mehl-Avrami (MA) equation in the case of isothermal transformations and a modified form of this equation in the case of continuous cooling transformations. The rate of intermetallic-phase formation was found to be much faster in CD3MWCuN than CD3MN due mainly to differences in the major alloying contents such as Cr, Ni and Mo. To examine in more detail the effects of these elements of the phase stabilities; a series of eight steel castings was designed with the Cr, Ni and Mo contents systematically varied with respect to the nominal composition of CD3MN. The effects of varying the contents of alloying additions on the formation of intermetallic phases were also studied computationally using the commercial thermodynamic software package, Thermo-Calc. In general, {sigma} was stabilized with increasing Cr addition and {chi} by increasing Mo addition. However, a delicate balance among Ni and other minor elements such as N and Si also exists. Phase equilibria in DSS can be affected by local composition fluctuations in the cast alloy. This may cause discrepancy between thermodynamic prediction and experimental observation.

  3. Preliminary Phase Field Computational Model Development

    SciTech Connect (OSTI)

    Li, Yulan; Hu, Shenyang Y.; Xu, Ke; Suter, Jonathan D.; McCloy, John S.; Johnson, Bradley R.; Ramuhalli, Pradeep

    2014-12-15

    This interim report presents progress towards the development of meso-scale models of magnetic behavior that incorporate microstructural information. Modeling magnetic signatures in irradiated materials with complex microstructures (such as structural steels) is a significant challenge. The complexity is addressed incrementally, using the monocrystalline Fe (i.e., ferrite) film as model systems to develop and validate initial models, followed by polycrystalline Fe films, and by more complicated and representative alloys. In addition, the modeling incrementally addresses inclusion of other major phases (e.g., martensite, austenite), minor magnetic phases (e.g., carbides, FeCr precipitates), and minor nonmagnetic phases (e.g., Cu precipitates, voids). The focus of the magnetic modeling is on phase-field models. The models are based on the numerical solution to the Landau-Lifshitz-Gilbert equation. From the computational standpoint, phase-field modeling allows the simulation of large enough systems that relevant defect structures and their effects on functional properties like magnetism can be simulated. To date, two phase-field models have been generated in support of this work. First, a bulk iron model with periodic boundary conditions was generated as a proof-of-concept to investigate major loop effects of single versus polycrystalline bulk iron and effects of single non-magnetic defects. More recently, to support the experimental program herein using iron thin films, a new model was generated that uses finite boundary conditions representing surfaces and edges. This model has provided key insights into the domain structures observed in magnetic force microscopy (MFM) measurements. Simulation results for single crystal thin-film iron indicate the feasibility of the model for determining magnetic domain wall thickness and mobility in an externally applied field. Because the phase-field model dimensions are limited relative to the size of most specimens used in experiments, special experimental methods were devised to create similar boundary conditions in the iron films. Preliminary MFM studies conducted on single and polycrystalline iron films with small sub-areas created with focused ion beam have correlated quite well qualitatively with phase-field simulations. However, phase-field model dimensions are still small relative to experiments thus far. We are in the process of increasing the size of the models and decreasing specimen size so both have identical dimensions. Ongoing research is focused on validation of the phase-field model. Validation is being accomplished through comparison with experimentally obtained MFM images (in progress), and planned measurements of major hysteresis loops and first order reversal curves. Extrapolation of simulation sizes to represent a more stochastic bulk-like system will require sampling of various simulations (i.e., with single non-magnetic defect, single magnetic defect, single grain boundary, single dislocation, etc.) with distributions of input parameters. These outputs can then be compared to laboratory magnetic measurements and ultimately to simulate magnetic Barkhausen noise signals.

  4. Dilute Oxygen Combustion - Phase 3 Report

    SciTech Connect (OSTI)

    Riley, Michael F.

    2000-05-31

    Dilute Oxygen Combustion (DOC) burners have been successfully installed and operated in the reheat furnace at Auburn Steel Co., Inc., Auburn, NY, under Phase 3 of the Dilute Oxygen Combustion project. Two new preheat zones were created employing a total of eight 6.5 MMBtu/hr capacity burners. The preheat zones provide a 30 percent increase in maximum furnace production rate, from 75 tph to 100 tph. The fuel rate is essentially unchanged, with the fuel savings expected from oxy-fuel combustion being offset by higher flue gas temperatures. When allowance is made for the high nitrogen level and high gas phase temperature in the furnace, measured NOx emissions are in line with laboratory data on DOC burners developed in Phase 1 of the project. Burner performance has been good, and there have been no operating or maintenance problems. The DOC system continues to be used as part of Auburn Steel's standard reheat furnace practice. High gas phase temperature is a result of the high firing density needed to achieve high production rates, and little opportunity exists for improvement in that area. However, fuel and NOx performance can be improved by further conversion on furnace zones to DOC burners, which will lower furnace nitrogen levels. Major obstacles are cost and concern about increased formation of oxide scale on the steel. Oxide scale formation may be enhanced by exposure of the steel to higher concentrations of oxidizing gas components (primarily products of combustion) in the higher temperature zones of the furnace. Phase 4 of the DOC project will examine the rate of oxide scale formation in these higher temperature zones and develop countermeasures that will allow DOC burners to be used successfully in these furnace zones.

  5. Dilute Oxygen Combustion Phase 3 Final Report

    SciTech Connect (OSTI)

    Riley, M.F.; Ryan, H.M.

    2000-05-31

    Dilute Oxygen Combustion (DOC) burners have been successfully installed and operated in the reheat furnace at Auburn Steel Co., Inc., Auburn, NY, under Phase 3 of the Dilute Oxygen Combustion project. Two new preheat zones were created employing a total of eight 6.5 MMBtu/hr capacity burners. The preheat zones provide a 30 percent increase in maximum furnace production rate, from 75 tph to 100 tph. The fuel rate is essentially unchanged, with the fuel savings expected from oxy-fuel combustion being offset by higher flue gas temperatures. When allowance is made for the high nitrogen level and high gas phase temperature in the furnace, measured NOx emissions are in line with laboratory data on DOC burners developed in Phase 1 of the project. Burner performance has been good and there have been no operating or maintenance problems. The DOC system continues to be used as part of Auburn Steel?s standard reheat furnace practice. High gas phase temperature is a result of the high firing density needed to achieve high production rates, and little opportunity exists for improvement in that area. However, fuel and NOx performance can be improved by further conversion of furnace zones to DOC burners, which will lower furnace nitrogen levels. Major obstacles are cost and concern about increased formation of oxide scale on the steel. Oxide scale formation may be enhanced by exposure of the steel to higher concentrations of oxidizing gas components (primarily products of combustion) in the higher temperature zones of the furnace. Phase 4 of the DOC project will examine the rate of oxide scale formation in these higher temperature zones and develop countermeasures that will allow DOC burners to be used successfully in these furnace zones.

  6. Phase Behavior of Neat Triblock Copolymers and Copolymer/Homopolymer Blends Near Network Phase Windows

    SciTech Connect (OSTI)

    M Tureau; L Rong; B Hsiao; T Epps

    2011-12-31

    The phase behavior of poly(isoprene-b-styrene-b-methyl methacrylate) (ISM) copolymers near the styrene-rich network phase window was examined through the use of neat triblock copolymers and copolymer/homopolymer blends. Both end-block and middle-block blending protocols were employed using poly(isoprene) (PI), poly(methyl methacrylate) (PMMA), and poly(styrene) (PS) homopolymers. Blended specimens exhibited phase transformations to well-ordered nanostructures (at homopolymer loadings up to 26 vol % of the total blend volume). Morphological consistency between neat and blended specimens was established at various locations in the ISM phase space. Copolymer/homopolymer blending permitted the refinement of lamellar, hexagonally packed cylinder, and disordered melt phase boundaries as well as the identification of double gyroid (Q{sup 230}), alternating gyroid (Q{sup 214}), and orthorhombic (O{sup 70}) network regimes. Additionally, the experimental phase diagram exhibited similar trends to those found in a theoretical ABC triblock copolymer phase diagram with symmetric interactions and statistical segments lengths generated by Tyler et al.

  7. High performance Zintl phase TE materials with embedded nanoparticles |

    Broader source: Energy.gov (indexed) [DOE]

    Department of Energy Performance of zintl phase thermoelectric materials with embedded particles are evaluated PDF icon shakouri.pdf More Documents & Publications High performance Zintl phase TE materials with embedded nanoparticles High Performance Zintl Phase TE Materials with Embedded Particles Thermoelectrics Partnership: High Performance Thermoelectric Waste Heat Recovery System Based on Zintl Phase Materials with Embedded Nanoparticles

  8. Two-phase anaerobic digestion of screened dairy manure

    SciTech Connect (OSTI)

    Lo, K.V.; Liao, P.H.

    1985-01-01

    The paper describes the operating results of a two-phase process that separate the acid-phase and methane-phase digestion of screened dairy manure under mesophilic temperature. Acidogenesis pretreatment prior to the methanogenic fixed-film reactor phase resulted in a significant increase in methane yield.

  9. Note: Phase retrieval method for analyzing single-phase displacement interferometry data

    SciTech Connect (OSTI)

    Chen, X. H.; Zeng, X. L.; Fan, D.; Liu, Q. C.; Bie, B. X.; Zhou, X. M. Luo, S. N.

    2014-02-15

    We present a phase retrieval method (PRM) for analyzing single-phase displacement interferometry measurements on rapidly changing velocity histories, including photon Doppler velocimetry (PDV). PRM identifies the peaks and valleys as well as zero-crossing points in a PDV time series, performs normalization and extracts point-by-point phase and thus velocity information. PRM does not require a wide time window as in sliding window Fourier transformation, and thus improves the effective temporal resolution. This method is implemented in analyzing PDV data obtained from gas gun experiments, and validated against simultaneous measurements with velocity interferometer system for any reflector.

  10. Phase correction system for automatic focusing of synthetic aperture radar

    DOE Patents [OSTI]

    Eichel, Paul H. (Albuquerque, NM); Ghiglia, Dennis C. (Placitas, NM); Jakowatz, Jr., Charles V. (Albuquerque, NM)

    1990-01-01

    A phase gradient autofocus system for use in synthetic aperture imaging accurately compensates for arbitrary phase errors in each imaged frame by locating highlighted areas and determining the phase disturbance or image spread associated with each of these highlight areas. An estimate of the image spread for each highlighted area in a line in the case of one dimensional processing or in a sector, in the case of two-dimensional processing, is determined. The phase error is determined using phase gradient processing. The phase error is then removed from the uncorrected image and the process is iteratively performed to substantially eliminate phase errors which can degrade the image.

  11. Feed-forward digital phase and amplitude correction system

    DOE Patents [OSTI]

    Yu, David U. L.; Conway, Patrick H.

    1994-01-01

    Phase and amplitude modifications in repeatable RF pulses at the output of a high power pulsed microwave amplifier are made utilizing a digital feed-forward correction system. A controlled amount of the output power is coupled to a correction system for processing of phase and amplitude information. The correction system comprises circuitry to compare the detected phase and amplitude with the desired phase and amplitude, respectively, and a digitally programmable phase shifter and attenuator and digital logic circuitry to control the phase shifter and attenuator. The Phase and amplitude of subsequent are modified by output signals from the correction system.

  12. Feed-forward digital phase and amplitude correction system

    DOE Patents [OSTI]

    Yu, D.U.L.; Conway, P.H.

    1994-11-15

    Phase and amplitude modifications in repeatable RF pulses at the output of a high power pulsed microwave amplifier are made utilizing a digital feed-forward correction system. A controlled amount of the output power is coupled to a correction system for processing of phase and amplitude information. The correction system comprises circuitry to compare the detected phase and amplitude with the desired phase and amplitude, respectively, and a digitally programmable phase shifter and attenuator and digital logic circuitry to control the phase shifter and attenuator. The phase and amplitude of subsequent are modified by output signals from the correction system. 11 figs.

  13. Method and apparatus for optical phase error correction

    DOE Patents [OSTI]

    DeRose, Christopher; Bender, Daniel A.

    2014-09-02

    The phase value of a phase-sensitive optical device, which includes an optical transport region, is modified by laser processing. At least a portion of the optical transport region is exposed to a laser beam such that the phase value is changed from a first phase value to a second phase value, where the second phase value is different from the first phase value. The portion of the optical transport region that is exposed to the laser beam can be a surface of the optical transport region or a portion of the volume of the optical transport region. In an embodiment of the invention, the phase value of the optical device is corrected by laser processing. At least a portion of the optical transport region is exposed to a laser beam until the phase value of the optical device is within a specified tolerance of a target phase value.

  14. Helical Phase Inflation and Monodromy in Supergravity Theory (Journal

    Office of Scientific and Technical Information (OSTI)

    Article) | SciTech Connect Helical Phase Inflation and Monodromy in Supergravity Theory Citation Details In-Document Search Title: Helical Phase Inflation and Monodromy in Supergravity Theory We study helical phase inflation which realizes "monodromy inflation" in supergravity theory. In the model, inflation is driven by the phase component of a complex field whose potential possesses helicoid structure. We construct phase monodromy based on explicitly breaking global U ( 1 )

  15. Phase Field model elucidates competing thermodynamic effects on

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nuclear Weapons Life Cycle Phase 6.X Process The Phase 6.x Process is based on the original Joint Nuclear Weapons Life Cycle Process, which includes Phases 1 through 7 and covers all phases of a weapon's life from initial feasibility studies and design through development, production, maintenance, deployment, retirement, and dismantlement. These traditional phases were established by the Department of Defense and the Department of Energy who share responsibility for all U.S nuclear weapons.

  16. Phase 6.X Process | National Nuclear Security Administration

    National Nuclear Security Administration (NNSA)

    Nuclear Weapons Life Cycle Phase 6.X Process The Phase 6.x Process is based on the original Joint Nuclear Weapons Life Cycle Process, which includes Phases 1 through 7 and covers all phases of a weapon's life from initial feasibility studies and design through development, production, maintenance, deployment, retirement, and dismantlement. These traditional phases were established by the Department of Defense and the Department of Energy who share responsibility for all U.S nuclear weapons.

  17. THE MONOCLINIC PHASE IN PZT: NEW LIGHT ON MORPHOTROPIC PHASE BOUNDARIES

    SciTech Connect (OSTI)

    NOHEDA,B.; GONZALO,J.A.; GUO,R.; PARK,S.E.; CROSS,L.E.; COX,D.E.; SHIRANE,G.

    2000-03-09

    A summary of the work recently carried out on the morphotropic phase boundary (MPB) of PZT is presented. By means of x-ray powder diffraction on ceramic samples of excellent quality, the MPB has been successfully characterized by changing temperature in a series of closely spaced compositions. As a result, an unexpected monoclinic phase has been found to exist in between the well-known tetragonal and rhombohedral PZT phases. A detailed structural analysis, together with the investigation of the field effect in this region of compositions, have led to an important advance in understanding the mechanisms responsible for the physical properties of PZT as well as other piezoelectric materials with similar morphotropic phase boundaries.

  18. Dynamic failure in two-phase materials

    SciTech Connect (OSTI)

    Fensin, S. J.; Walker, E. K.; Cerreta, E. K.; Trujillo, C. P.; Martinez, D. T.; Gray, G. T.

    2015-12-21

    Previous experimental research has shown that microstructural features such as interfaces, inclusions, vacancies, and heterogeneities can all act as voidnucleation sites. However, it is not well understood how important these interfaces are to damage evolution and failure as a function of the surrounding parentmaterials. In this work, we present results on three different polycrystallinematerials: (1) Cu, (2) Cu-24 wt. %Ag, and (3) Cu-15 wt. %Nb which were studied to probe the influence of bi-metal interfaces onvoidnucleation and growth. These materials were chosen due to the range of difference in structure and bulk properties between the two phases. The initial results suggest that when there are significant differences between the bulk properties (for example: stacking fault energy, melting temperature, etc.) the type of interface between the two parent materials does not principally control the damage nucleation and growth process. Rather, it is the “weaker” material that dictates the dynamic spall strength of the overall two-phase material.

  19. Silicotitanate molecular sieve and condensed phases

    DOE Patents [OSTI]

    Nenoff, Tina M. (Albuquerque, NM); Nyman, May D. (Albuquerque, NM)

    2002-01-01

    A new microporous crystalline molecular sieve material having the formula Cs.sub.3 TiSi.sub.3 O.sub.95.cndot.3H.sub.2 O and its hydrothermally condensed phase, Cs.sub.2 TiSi.sub.6 O.sub.15, are disclosed. The microporous material can adsorb divalent ions of radionuclides or other industrial metals such as chromium, nickel, lead, copper, cobalt, zinc, cadmium, barium, and mercury, from aqueous or hydrocarbon solutions. The adsorbed metal ions can be leached out for recovery purposes or the microporous material can be hydrothermally condensed to a radiation resistant, structurally and chemically stable phase which can serve as a storage waste form for radionuclides.

  20. Tunable hyperbolic metamaterials utilizing phase change heterostructures

    SciTech Connect (OSTI)

    Krishnamoorthy, Harish N. S.; Menon, Vinod M.; Zhou, You; Ramanathan, Shriram; Narimanov, Evgenii

    2014-03-24

    We present a metal-free tunable anisotropic metamaterial where the iso-frequency surface is tuned from elliptical to hyperbolic dispersion by exploiting the metal-insulator phase transition in the correlated material vanadium dioxide (VO{sub 2}). Using VO{sub 2}-TiO{sub 2} heterostructures, we demonstrate the transition in the effective dielectric constant parallel to the layers to undergo a sign change from positive to negative as the VO{sub 2} undergoes the phase transition. The possibility to tune the iso-frequency surface in real time using external perturbations such as temperature, voltage, or optical pulses creates new avenues for controlling light-matter interaction.

  1. Phase contrast portal imaging using synchrotron radiation

    SciTech Connect (OSTI)

    Umetani, K.; Kondoh, T.

    2014-07-15

    Microbeam radiation therapy is an experimental form of radiation treatment with great potential to improve the treatment of many types of cancer. We applied a synchrotron radiation phase contrast technique to portal imaging to improve targeting accuracy for microbeam radiation therapy in experiments using small animals. An X-ray imaging detector was installed 6.0 m downstream from an object to produce a high-contrast edge enhancement effect in propagation-based phase contrast imaging. Images of a mouse head sample were obtained using therapeutic white synchrotron radiation with a mean beam energy of 130 keV. Compared to conventional portal images, remarkably clear images of bones surrounding the cerebrum were acquired in an air environment for positioning brain lesions with respect to the skull structure without confusion with overlapping surface structures.

  2. ISDSN Sensor System Phase One Test Report

    SciTech Connect (OSTI)

    Gail Heath

    2011-09-01

    This Phase 1 Test Report documents the test activities and results completed for the Idaho National Laboratory (INL) sensor systems that will be deployed in the meso-scale test bed (MSTB) at Florida International University (FIU), as outlined in the ISDSN-MSTB Test Plan. This report captures the sensor system configuration tested; test parameters, testing procedure, any noted changes from the implementation plan, acquired test data sets, and processed results.

  3. Fundemental Academic Training Instructor's Guide Phase 1

    Energy Savers [EERE]

    Part 3 of 9 Radiological Control Technician Training Fundamental Academic Training Instructor's Guide Phase I Coordinated and Conducted for the Office of Health, Safety and Security U.S. Department of Energy DOE-HDBK-1122-2009 Radiological Control Technician Instructor's Guide 1.01- ii This page intentionally left blank. DOE-HDBK-1122-2009 Radiological Control Technician Instructor's Guide 1.01- iii Table of Contents Page Module 1.01 Basic Mathematics and

  4. Industrial waste needs assessment. Phase 1

    SciTech Connect (OSTI)

    Radel, R.J.; Willis, M.P.

    1993-10-01

    In January of 1992 a team was put together to begin the process of assessing the industrial waste needs of the Tennessee Valley. The team consisted of representatives from the various TVA Resource Group organizations. This initial team recommended as a starting point in the process a two-phase market research effort. A second team was then commissioned to conduct the first phase of this market research effort. The first phase of that marketing effort is now complete. This report contains an analysis of the data obtained through interviews of more than 168 individuals representing a similar number of organizations. A total of 37 TVA Resource Group employees were involved in the contact process from various organizations. In addition, the appendices provide summaries of the data used in designing the process and the reports of the Contact Coordinators (who were responsible for a series of visits). As a result of the data analysis, the Review Team makes the following recommendations: 1. Publish this report and distribute to the new management within TVA Resource Group as well as to all those participating as contacts, visitors, and contact coordinators. 2. The Resource Group management team, or management teams within each of the respective organizations within Resource Group, appoint Phase 2 assessement teams for as many of the problem areas listed in Table III as seem appropriate. We further recommend that, where possible, cross-organizational teams be used to examine individual problem areas. 3. Make this report available within Generating and Customer Groups, especially to the Customer Service Centers. 4. Establish a process to continue follow up with each of the contacts made in this assessment.

  5. Phase transitions and elementary-particle physics

    SciTech Connect (OSTI)

    Creutz, M.

    1981-01-01

    The reason physicists have recently taken an intense interest in the statistical mechanics of certain lattice models is reviewed. Phase transitions in these systems are of direct relevance to whether the gauge theory of interacting quarks and gluons can prevent the quark as appearing as a free isolated object. Monte Carlo simulation techniques have given the strongest evidence for the confinement phenomenon and are beginning to make numerical predictions in strong interaction physics.

  6. Multiyear Program Plan Template - Phase II Guidance

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Multiyear Program Plan Template Phase II Guidance June 30, 2006 Foreword: The Purpose and Value of a Multiyear Program Plan Multiyear Program Plans (MYPPs) are intended primarily to serve as operational guides for programs to manage their activities and as a source of information to help EERE management identify clear linkages between key program activities and progress toward goals. It is understood, however, that they are also read by a broad group of program stakeholders and may serve other

  7. IDC Reengineering Phase 2 Project Scope.

    SciTech Connect (OSTI)

    Harris, James M.

    2015-02-01

    This report provides a brief description of the scope of the IDC Reengineering Phase 2 project. It describes the goals and objectives of reengineering, the system definition, and the technical scope of the system. REVISIONS Version Date Author/Team Revision Description Authorized by 1.0 9/25/2014 SNL IDC Reengineering Team Unlimited Release for I2 M. Harris 1.1 28/01/2015 IDC Reengineering Team Align with previous IDC scope document E. Tomuta

  8. Associative memory in phasing neuron networks

    SciTech Connect (OSTI)

    Nair, Niketh S; Bochove, Erik J.; Braiman, Yehuda

    2014-01-01

    We studied pattern formation in a network of coupled Hindmarsh-Rose model neurons and introduced a new model for associative memory retrieval using networks of Kuramoto oscillators. Hindmarsh-Rose Neural Networks can exhibit a rich set of collective dynamics that can be controlled by their connectivity. Specifically, we showed an instance of Hebb's rule where spiking was correlated with network topology. Based on this, we presented a simple model of associative memory in coupled phase oscillators.

  9. The dynamics of two-phase (gas

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    dynamics of two-phase (gas/ liquid) bubbly flows are complex: bubbles deform and disperse; large latent heats and heat capacity differ- entials influence local boiling; and relatively small changes in heated surface temperatures yield order of magnitude changes in boiling com- plexity. Because the local void vol- ume has a direct feedback effect on reactor neutron flux and fuel rod power production, prediction of local boiling rates and bulk boiling effects in nuclear reactors is key in achiev-

  10. Late-time cosmological phase transitions

    SciTech Connect (OSTI)

    Schramm, D.N. Fermi National Accelerator Lab., Batavia, IL )

    1990-11-01

    It is shown that the potential galaxy formation and large-scale structure problems of objects existing at high redshifts (Z {approx gt} 5), structures existing on scales of 100M pc as well as velocity flows on such scales, and minimal microwave anisotropies ({Delta}T/T) {approx lt} 10{sup {minus}5} can be solved if the seeds needed to generate structure form in a vacuum phase transition after decoupling. It is argued that the basic physics of such a phase transition is no more exotic than that utilized in the more traditional GUT scale phase transitions, and that, just as in the GUT case, significant random gaussian fluctuations and/or topological defects can form. Scale lengths of {approximately}100M pc for large-scale structure as well as {approximately}1 M pc for galaxy formation occur naturally. Possible support for new physics that might be associated with such a late-time transition comes from the preliminary results of the SAGE solar neutrino experiment, implying neutrino flavor mixing with values similar to those required for a late-time transition. It is also noted that a see-saw model for the neutrino masses might also imply a tau neutrino mass that is an ideal hot dark matter candidate. However, in general either hot or cold dark matter can be consistent with a late-time transition. 47 refs., 2 figs.

  11. 2-Phase Fluid Flow & Heat Transport

    Energy Science and Technology Software Center (OSTI)

    1993-03-13

    GEOTHER is a three-dimensional, geothermal reservoir simulation code. The model describes heat transport and flow of a single component, two-phase fluid in porous media. It is based on the continuity equations for steam and water, which are reduced to two nonlinear partial differential equations in which the dependent variables are fluid pressure and enthalpy. GEOTHER can be used to simulate the fluid-thermal interaction in rock that can be approximated by a porous media representation. Itmorecan simulate heat transport and the flow of compressed water, two-phase mixtures, and superheated steam in porous media over a temperature range of 10 to 300 degrees C. In addition, it can treat the conversion from single to two-phase flow, and vice versa. It can be used for evaluation of a near repository spatial scale and a time scale of a few years to thousands of years. The model can be used to investigate temperature and fluid pressure changes in response to thermal loading by waste materials.less

  12. QCD PHASE TRANSITIONS-VOLUME 15.

    SciTech Connect (OSTI)

    SCHAFER,T.

    1998-11-04

    The title of the workshop, ''The QCD Phase Transitions'', in fact happened to be too narrow for its real contents. It would be more accurate to say that it was devoted to different phases of QCD and QCD-related gauge theories, with strong emphasis on discussion of the underlying non-perturbative mechanisms which manifest themselves as all those phases. Before we go to specifics, let us emphasize one important aspect of the present status of non-perturbative Quantum Field Theory in general. It remains true that its studies do not get attention proportional to the intellectual challenge they deserve, and that the theorists working on it remain very fragmented. The efforts to create Theory of Everything including Quantum Gravity have attracted the lion share of attention and young talent. Nevertheless, in the last few years there was also a tremendous progress and even some shift of attention toward emphasis on the unity of non-perturbative phenomena. For example, we have seen some. efforts to connect the lessons from recent progress in Supersymmetric theories with that in QCD, as derived from phenomenology and lattice. Another example is Maldacena conjecture and related development, which connect three things together, string theory, super-gravity and the (N=4) supersymmetric gauge theory. Although the progress mentioned is remarkable by itself, if we would listen to each other more we may have chance to strengthen the field and reach better understanding of the spectacular non-perturbative physics.

  13. 2-Phase Fluid Flow & Heat Transport

    Energy Science and Technology Software Center (OSTI)

    1993-03-13

    GEOTHER is a three-dimensional, geothermal reservoir simulation code. The model describes heat transport and flow of a single component, two-phase fluid in porous media. It is based on the continuity equations for steam and water, which are reduced to two nonlinear partial differential equations in which the dependent variables are fluid pressure and enthalpy. GEOTHER can be used to simulate the fluid-thermal interaction in rock that can be approximated by a porous media representation. Itmore » can simulate heat transport and the flow of compressed water, two-phase mixtures, and superheated steam in porous media over a temperature range of 10 to 300 degrees C. In addition, it can treat the conversion from single to two-phase flow, and vice versa. It can be used for evaluation of a near repository spatial scale and a time scale of a few years to thousands of years. The model can be used to investigate temperature and fluid pressure changes in response to thermal loading by waste materials.« less

  14. Phase change based cooling for high burst mode heat loads with temperature regulation above the phase change temperature

    DOE Patents [OSTI]

    The United States of America as represented by the United States Department of Energy

    2009-12-15

    An apparatus and method for transferring thermal energy from a heat load is disclosed. In particular, use of a phase change material and specific flow designs enables cooling with temperature regulation well above the fusion temperature of the phase change material for medium and high heat loads from devices operated intermittently (in burst mode). Exemplary heat loads include burst mode lasers and laser diodes, flight avionics, and high power space instruments. Thermal energy is transferred from the heat load to liquid phase change material from a phase change material reservoir. The liquid phase change material is split into two flows. Thermal energy is transferred from the first flow via a phase change material heat sink. The second flow bypasses the phase change material heat sink and joins with liquid phase change material exiting from the phase change material heat sink. The combined liquid phase change material is returned to the liquid phase change material reservoir. The ratio of bypass flow to flow into the phase change material heat sink can be varied to adjust the temperature of the liquid phase change material returned to the liquid phase change material reservoir. Varying the flowrate and temperature of the liquid phase change material presented to the heat load determines the magnitude of thermal energy transferred from the heat load.

  15. Unconventional transformation of spin Dirac phase across a topological quantum phase transition

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Xu, Su -Yang; Neupane, Madhab; Belopolski, Ilya; Liu, Chang; Alidoust, Nasser; Bian, Guang; Jia, Shuang; Landolt, Gabriel; Slomski, Batosz; Dil, J. Hugo; et al

    2015-04-17

    The topology of a topological material can be encoded in its surface states. These surface states can only be removed by a bulk topological quantum phase transition into a trivial phase. Here we use photoemission spectroscopy to image the formation of protected surface states in a topological insulator as we chemically tune the system through a topological transition. Surprisingly, we discover an exotic spin-momentum locked, gapped surface state in the trivial phase that shares many important properties with the actual topological surface state in anticipation of the change of topology. Using a spin-resolved measurement, we show that apart from amore » surface bandgap these states develop spin textures similar to the topological surface states well before the transition. Our results provide a general paradigm for understanding how surface states in topological phases arise from a quantum phase transition and are suggestive for the future realization of Weyl arcs, condensed matter supersymmetry and other fascinating phenomena in the vicinity of a quantum criticality.« less

  16. Geometric phase of a qubit driven by a phase noise laser under non-Markovian dynamics

    SciTech Connect (OSTI)

    Berrada, K.

    2014-01-15

    Robustness of the geometric phase (GP) with respect to the environmental effects is a basic condition for an effective quantum computation. Here, we study quantitatively the GP of a two-level atom system driven by a phase noise laser under non-Markovian dynamics in terms of different parameters involved in the whole system. We find that with the change of the damping coupling, the GP is very sensitive to its properties exhibiting long collapse and revival phenomena, which play a significant role in enhancing the stabilization and control of the system dynamics. Moreover, we show that the GP can be considered as a tool for testing and characterizing the nature of the qubitenvironment coupling. Due to the significance of how a system is quantum correlated with its environment in the construction of a scalable quantum computer, the entanglement dynamics between the qubit with its environment under external classical noise is evaluated and investigated during the time evolution. -- Highlights: Geometric phase under noise phase laser. Dynamics of the geometric phase under non-Markovian dynamics in the presence of classical noise. Solution of master equation of the system in terms atomic inversion. Nonlocal correlation between the system and its environment under non-Markovianity.

  17. Newberry Volcano EGS Demonstration - Phase I Results

    SciTech Connect (OSTI)

    William L. Osborn, Susan Petty, Trenton T. Cladouhos, Joe Iovenitti, Laura Nofziger, Owen Callahan, Douglas S. Perry and Paul L. Stern

    2011-10-23

    Phase I of the Newberry Volcano Enhanced Geothermal System (EGS) Demonstration included permitting, community outreach, seismic hazards analysis, initial microseismic array deployment and calibration, final MSA design, site characterization, and stimulation planning. The multi-disciplinary Phase I site characterization supports stimulation planning and regulatory permitting, as well as addressing public concerns including water usage and induced seismicity. A review of the project'™s water usage plan by an independent hydrology consultant found no expected impacts to local stakeholders, and recommended additional monitoring procedures. The IEA Protocol for Induced Seismicity Associated with Enhanced Geothermal Systems was applied to assess site conditions, properly inform stakeholders, and develop a comprehensive mitigation plan. Analysis of precision LiDAR elevation maps has concluded that there is no evidence of recent faulting near the target well. A borehole televiewer image log of the well bore revealed over three hundred fractures and predicted stress orientations. No natural, background seismicity has been identified in a review of historic data, or in more than seven months of seismic data recorded on an array of seven seismometers operating around the target well. A seismic hazards and induced seismicity risk assessment by an independent consultant concluded that the Demonstration would contribute no additional risk to residents of the nearest town of La Pine, Oregon. In Phase II of the demonstration, an existing deep hot well, NWG 55-29, will be stimulated using hydroshearing techniques to create an EGS reservoir. The Newberry Volcano EGS Demonstration is allowing geothermal industry and academic experts to develop, validate and enhance geoscience and engineering techniques, and other procedures essential to the expansion of EGS throughout the country. Successful development will demonstrate to the American public that EGS can play a significant role in reducing foreign energy dependence, and provide clean, renewable, baseload geothermal power generation in the State of Oregon.

  18. Transuranic (TRU) Waste Phase I Retrieval Plan

    SciTech Connect (OSTI)

    MCDONALD, K.M.

    1999-08-27

    Phase I retrieval of post-1970 TRU wastes from burial ground 218-W-4C can be done in a safe, efficient, and cost-effective manner. Initiating TRU retrieval by retrieving uncovered drums from Trenches 1, 20, and 29, will allow retrieval to begin under the current SWBG safety authorization basis. The retrieval of buried drums from Trenches 1, 4, 20, and 29, which will require excavation, will commence once the uncovered drum are retrieved. This phased approach allows safety analysis for drum venting and drum module excavation to be completed and approved before the excavation proceeds. In addition, the lessons learned and the operational experience gained from the retrieval of uncovered drums can be applied to the more complicated retrieval of the buried drums. Precedents that have been set at SRS and LANL to perform retrieval without a trench cover, in the open air, should be followed. Open-air retrieval will result in significant cost savings over the original plans for Phase I retrieval (Project W-113). Based on LANL and SRS experience, open-air retrieval will have no adverse impacts to the environment or to the health and safety of workers or the public. Assaying the waste in the SWBG using a mobile assay system, will result in additional cost savings. It is expected that up to 50% of the suspect-TRU wastes will assay as LLW, allowing those waste to remain disposed of in the SWBG. Further processing, with its associated costs, will only occur to the portion of the waste that is verified to be TRU. Retrieval should be done, to the extent possible, under the current SWBG safety authorization basis as a normal part of SWBG operations. The use of existing personnel and existing procedures should be optimized. By working retrieval campaigns, typically during the slow months, it is easier to coordinate the availability of necessary operations personnel, and it is easier to coordinate the availability of a mobile assay vendor.

  19. Nonisothermal Two-Phase Porous Flow

    Energy Science and Technology Software Center (OSTI)

    1992-02-21

    NORIA is a finite element program that simultaneously solves four nonlinear parabolic, partial differential equations that describe the transport of water, water vapor, air, and energy through partially saturated porous media. NORIA is designed for the analysis of two-dimensional, non-isothermal, unsaturated porous flow problems. Nearly all material properties, such as permeability, can either be set to constant values or defined as functions of the dependent and independent variables by user-supplied subroutines. The gas phase ismore » taken to be ideal. NORIA is intended to solve nonisothermal problems in which large gradients are expected in the gas pressure.« less

  20. Performance testing the Phase 2 HDR reservoir

    SciTech Connect (OSTI)

    Ponden, R.F.; Dreesen, D.S. ); Thomson, J.C. )

    1991-01-01

    The geothermal energy program at the Los Alamos National Laboratory is directed toward developing the Hot Dry Rock (HDR) technology as an alternate energy source. Positive results have been obtained in previous circulation tests of HDR reservoirs at the Laboratory's test site in Fenton Hill, New Mexico. There still remains however, the need to demonstrate that adequate geothermal energy can be extracted in an efficient manner to support commercial power production. This year, the Laboratory will begin a circulation test of its Phase 2, reservoir. The objectives of this test are to characterize steady-state power production and long-term reservoir performance. 6 refs., 2 figs., 3 tabs.

  1. Fundemental Academic Training Study Guide Phase 1

    Energy Savers [EERE]

    Module 1.01 Basic Mathematics and Algebra Study Guide Part 4 of 9 Radiological Control Technician Training Fundamental Academic Training Study Guide Phase I Coordinated and Conducted for the Office of Health, Safety and Security U.S. Department of Energy DOE-HDBK-1122-2009 Module 1.01 Basic Mathematics and Algebra Study Guide 1.01-ii This page intentionally left blank. DOE-HDBK-1122-2009 Module 1.01 Basic Mathematics and Algebra Study Guide 1.01-iii Table of Contents Page Module 1.01 Basic

  2. Gas phase thermochemistry of organogermanium compounds

    SciTech Connect (OSTI)

    Engel, J.P.

    1993-12-07

    A variety of silyl- and alkyl-germylene precursors have been synthesized and subsequently pyrolyzed in the gas phase. Arrhenius parameters were obtained employing a pulsed-stirred flow reactor for these unimolecular decompositions. These precursors are divided into two major categories by mechanism of germylene extrusion: {alpha}-elimination precursors and germylacetylenes. The extrusion of germylenes from germylacetylene precursors is of primary interest. A mechanism is proposed employing a germacyclopropene intermediate. Evidence supporting this mechanism is presented. In the process of exploring germylacetylenes as germylene precursors, an apparent dyatropic rearrangement between germanium and silicon was observed. This rearrangement was subsequently explored.

  3. Synthesis of highly phase pure BSCCO superconductors

    DOE Patents [OSTI]

    Dorris, Stephen E.; Poeppel, Roger B.; Prorok, Barton C.; Lanagan, Michael T.; Maroni, Victor A.

    1995-01-01

    An article and method of manufacture of (Bi, Pb)-Sr-Ca-Cu-O superconductor. The superconductor is manufactured by preparing a first powdered mixture of bismuth oxide, lead oxide, strontium carbonate, calcium carbonate and copper oxide. A second powdered mixture is then prepared of strontium carbonate, calcium carbonate and copper oxide. The mixtures are calcined separately with the two mixtures then combined. The resulting combined mixture is then subjected to a powder in tube deformation and thermal processing to produce a substantially phase pure (Bi, Pb)-Sr-Ca-Cu-O superconductor.

  4. Synthesis of highly phase pure BSCCO superconductors

    DOE Patents [OSTI]

    Dorris, S.E.; Poeppel, R.B.; Prorok, B.C.; Lanagan, M.T.; Maroni, V.A.

    1995-11-21

    An article and method of manufacture (Bi, Pb)-Sr-Ca-Cu-O superconductor are disclosed. The superconductor is manufactured by preparing a first powdered mixture of bismuth oxide, lead oxide, strontium carbonate, calcium carbonate and copper oxide. A second powdered mixture is then prepared of strontium carbonate, calcium carbonate and copper oxide. The mixtures are calcined separately with the two mixtures then combined. The resulting combined mixture is then subjected to a powder in tube deformation and thermal processing to produce a substantially phase pure (Bi, Pb)-Sr-Ca-Cu-O superconductor. 5 figs.

  5. Toroidal Precession as a Geometric Phase

    SciTech Connect (OSTI)

    J.W. Burby and H. Qin

    2012-09-26

    Toroidal precession is commonly understood as the orbit-averaged toroidal drift of guiding centers in axisymmetric and quasisymmetric configurations. We give a new, more natural description of precession as a geometric phase effect. In particular, we show that the precession angle arises as the holonomy of a guiding center's poloidal trajectory relative to a principal connection. The fact that this description is physically appropriate is borne out with new, manifestly coordinate-independent expressions for the precession angle that apply to all types of orbits in tokamaks and quasisymmetric stellarators alike. We then describe how these expressions may be fruitfully employed in numerical calculations of precession.

  6. Relativistic Random Phase Approximation At Finite Temperature

    SciTech Connect (OSTI)

    Niu, Y. F.; Paar, N.; Vretenar, D.; Meng, J.

    2009-08-26

    The fully self-consistent finite temperature relativistic random phase approximation (FTRRPA) has been established in the single-nucleon basis of the temperature dependent Dirac-Hartree model (FTDH) based on effective Lagrangian with density dependent meson-nucleon couplings. Illustrative calculations in the FTRRPA framework show the evolution of multipole responses of {sup 132}Sn with temperature. With increased temperature, in both monopole and dipole strength distributions additional transitions appear in the low energy region due to the new opened particle-particle and hole-hole transition channels.

  7. Neutron Damage and MAX Phase Ternary Compounds

    SciTech Connect (OSTI)

    Barsoum, Michael; Hoffman, Elizabeth; Sindelar, Robert; Garcua-Duaz, Brenda; Kohse, Gordon

    2014-06-17

    The Demands of Gen IV nuclear power plants for long service life under neutron radiation at high temperature are severe. Advanced materials that would withstand high temperatures (up to 1000+ C) to high doses in a neutron field would be ideal for reactor internal structures and would add to the long service life and reliability of the reactors. The objective of this work is to investigate the response of a new class of machinable, conductive, layered, ternary transition metal carbides and nitrides - the so-called MAX phases - to low and moderate neutron dose levels.

  8. Dry powder mixes comprising phase change materials

    DOE Patents [OSTI]

    Salyer, I.O.

    1994-12-06

    A free flowing, conformable powder-like mix of silica particles and a phase change material (PCM) is provided. The silica particles have a critical size of about 0.005 to about 0.025 microns and the PCM must be added to the silica in an amount of 75% or less PCM per combined weight of silica and PCM. The powder-like mix can be used in tableware items, medical wraps, tree wraps, garments, quilts and blankets, and particularly in applications for heat protection for heat sensitive items, such as aircraft flight recorders, and for preventing brake fade in automobiles, buses, trucks and aircraft. 3 figures.

  9. Dry powder mixes comprising phase change materials

    DOE Patents [OSTI]

    Salyer, Ival O.

    1994-01-01

    A free flowing, conformable powder-like mix of silica particles and a phase change material (PCM) is provided. The silica particles have a critical size of about 0.005 to about 0.025 microns and the PCM must be added to the silica in an amount of 75% or less PCM per combined weight of silica and PCM. The powder-like mix can be used in tableware items, medical wraps, tree wraps, garments, quilts and blankets, and particularly in applications for heat protection for heat sensitive items, such as aircraft flight recorders, and for preventing brake fade in automobiles, buses, trucks and aircraft.

  10. Dry powder mixes comprising phase change materials

    DOE Patents [OSTI]

    Salyer, I.O.

    1995-12-26

    A free flowing, conformable powder-like mix of silica particles and a phase change material (PCM) is provided. The silica particles have a critical size of about 0.005 to about 0.025 microns and the PCM must be added to the silica in an amount of 75% or less PCM per combined weight of silica and PCM. The powder-like mix can be used in tableware items, medical wraps, tree wraps, garments, quilts and blankets, and particularly in applications for heat protection for heat sensitive items, such as aircraft flight recorders, and for preventing brake fade in automobiles, buses, trucks and aircraft. 3 figs.

  11. Dry powder mixes comprising phase change materials

    DOE Patents [OSTI]

    Salyer, Ival O.

    1995-01-01

    A free flowing, conformable powder-like mix of silica particles and a phase change material (PCM) is provided. The silica particles have a critical size of about 0.005 to about 0.025 microns and the PCM must be added to the silica in an amount of 75% or less PCM per combined weight of silica and PCM. The powder-like mix can be used in tableware items, medical wraps, tree wraps, garments, quilts and blankets, and particularly in applications for heat protection for heat sensitive items, such as aircraft flight recorders, and for preventing brake fade in automobiles, buses, trucks and aircraft.

  12. Irreversible altering of crystalline phase of phase-change Ge-Sb thin films

    SciTech Connect (OSTI)

    Krusin-Elbaum, L.; Shakhvorostov, D.; Cabral, C. Jr.; Raoux, S.; Jordan-Sweet, J. L.

    2010-03-22

    The stability of the crystalline phase of binary phase-change Ge{sub x}Sb{sub 1-x} films is investigated over a wide range of Ge content. From Raman spectroscopy we find the Ge-Sb crystalline structure irreversibly altered after exposure to a laser beam. We show that with increasing beam intensity/temperature Ge agglomerates and precipitates out in the amount growing with x. A simple empirical relation links Ge precipitation temperature T{sub Ge}{sup p} to the rate of change dT{sub cryst}/dx of crystallization, with the precipitation easiest on the mid-range x plateau, where T{sub cryst} is nearly constant. Our findings point to a preferable 15% < or approx. x < 50% window, that may achieve the desired cycling/archival properties of a phase-change cell.

  13. Geometric phase for collinear conical intersections. I. Geometric phase angle and vector potentials

    SciTech Connect (OSTI)

    Li Xuan; Brue, Daniel A.; Blandon, Juan D.; Parker, Gregory A.; Kendrick, Brian K.

    2011-02-14

    We present a method for properly treating collinear conical intersections in triatomic systems. The general vector potential (gauge theory) approach for including the geometric phase effects associated with collinear conical intersections in hyperspherical coordinates is presented. The current study develops an introductory method in the treatment of collinear conical intersections by using the phase angle method. The geometric phase angle, {eta}, in terms of purely internal coordinates is derived using the example of a spin-aligned quartet lithium triatomic system. A numerical fit and thus an analytical form for the associated vector potentials are explicitly derived for this triatomic A{sub 3} system. The application of this methodology to AB{sub 2} and ABC systems is also discussed.

  14. Brigantine OffshoreMW Phase 2 | Open Energy Information

    Open Energy Info (EERE)

    2 Jump to: navigation, search Name Brigantine OffshoreMW Phase 2 Facility Brigantine OffshoreMW Phase 2 Sector Wind energy Facility Type Offshore Wind Facility Status Proposed...

  15. Western Renewable Energy Zones-Phase 1 Report | Department of...

    Energy Savers [EERE]

    Renewable Energy Zones-Phase 1 Report Western Renewable Energy Zones-Phase 1 Report In June 2006, the Western Governors'Association published "Clean Energy, a Strong Economy and a ...

  16. Intercomparison of model simulations of mixed-phase clouds observed...

    Office of Scientific and Technical Information (OSTI)

    Intercomparison of model simulations of mixed-phase clouds observed during the ARM Mixed-Phase Arctic Cloud Experiment. Part I: Single layer cloud Citation Details In-Document ...

  17. The role of phase instabilities in the early material response...

    Office of Scientific and Technical Information (OSTI)

    The role of phase instabilities in the early material response during laser-induced breakdown in bulk fused silica Citation Details In-Document Search Title: The role of phase...

  18. PROJECT SELECTIONS FOR DOE PHASE III XLERATOR SMALL BUSINESS...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    PROJECT SELECTIONS FOR DOE PHASE III XLERATOR SMALL BUSINESS PROGRAM - pg 3 PROJECT SELECTIONS FOR DOE PHASE III XLERATOR SMALL BUSINESS PROGRAM - pg 3 PDF icon sbirphase3pg3.pdf...

  19. Phase Discrimination through Oxidant Selection for Iron Oxide Ultrathin

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Films | ANSER Center | Argonne-Northwestern National Laboratory Phase Discrimination through Oxidant Selection for Iron Oxide Ultrathin Films Home > Research > ANSER Research Highlights > Phase Discrimination through Oxidant Selection for Iron Oxide Ultrathin Films

  20. Advanced Envelope Research for Factory Built Housing, Phase 3...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    This work is part of a four-phase, multi-year ... methods for building high performance wall systems. Phase 2 focused on the development ... further in the research - stud walls with ...

  1. Kinetic and Performance Studies of the Regeneration Phase of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Phase of Model PtRhBa NOx Traps for Design and Optimization Kinetic and Performance Studies of the Regeneration Phase of Model PtRhBa NOx Traps for Design and ...

  2. Two-Phase Mass Flow Measurement Using Noise Analysis (Conference...

    Office of Scientific and Technical Information (OSTI)

    Two-Phase Mass Flow Measurement Using Noise Analysis Citation Details In-Document Search Title: Two-Phase Mass Flow Measurement Using Noise Analysis You are accessing a document ...

  3. The Western Wind and Solar Integration Study Phase 2

    Broader source: Energy.gov [DOE]

    Greg Brinkman will present the results of the Western Wind and Solar Integration Study (WWSIS), Phase 2. This study, which follows the first phase of WWSIS, focuses on potential emissions and wear...

  4. Magnetostructural phase transformations in Tb 1-x Mn 2 (Journal...

    Office of Scientific and Technical Information (OSTI)

    Magnetostructural phase transformations in Tb 1-x Mn 2 Citation Details In-Document Search Title: Magnetostructural phase transformations in Tb 1-x Mn 2 You are accessing a ...

  5. dual-phase-ceramic-asu | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Pre-Combustion Carbon Dioxide Capture by a New Dual-Phase Ceramic Carbonate Membrane Reactor Project No.: DE-FE0000470 Arizona State University is developing a dual-phase,...

  6. HYTEST Phase I Facility Commissioning and Modeling

    SciTech Connect (OSTI)

    Lee P. Shunn; Richard D. Boardman; Shane J. Cherry; Craig G. Rieger

    2009-09-01

    The purpose of this document is to report the first year accomplishments of two coordinated Laboratory Directed Research and Development (LDRD) projects that utilize a hybrid energy testing laboratory that couples various reactors to investigate system reactance behavior. This work is the first phase of a series of hybrid energy research and testing stations - referred to hereafter as HYTEST facilities – that are planned for construction and operation at the Idaho National Laboratory (INL). A HYTEST Phase I facility was set up and commissioned in Bay 9 of the Bonneville County Technology Center (BCTC). The purpose of this facility is to utilize the hydrogen and oxygen that is produced by the High Temperature Steam Electrolysis test reactors operating in Bay 9 to support the investigation of kinetic phenomena and transient response of integrated reactor components. This facility provides a convenient scale for conducting scoping tests of new reaction concepts, materials performance, new instruments, and real-time data collection and manipulation for advance process controls. An enclosed reactor module was assembled and connected to a new ventilation system equipped with a variable-speed exhaust blower to mitigate hazardous gas exposures, as well as contract with hot surfaces. The module was equipped with a hydrogen gas pump and receiver tank to supply high quality hydrogen to chemical reactors located in the hood.

  7. Memory Optimization for Phase-field Simulations

    SciTech Connect (OSTI)

    Derek Gaston; John Peterson; Andrew Slaughter; Cody Permann; David Andrs

    2014-08-01

    Phase-field simulations are computationally and memory intensive applications. Many of the phase-field simulations being conducted in support of NEAMS were not capable of running on “normal clusters” with 2-4GB of RAM per core, and instead required specialized “big-memory” clusters with 64GB per core. To address this issue, the MOOSE team developed a new Python-based utility called MemoryLogger, and applied it to locate, diagnose, and eradicate memory bottlenecks within the MOOSE framework. MemoryLogger allows for a better understanding of the memory usage of an application being run in parallel across a cluster. Memory usage information is captured for every individual process in a parallel job, and communicated to the head node of the cluster. Console text output from the application itself is automatically matched with this memory usage information to produce a detailed picture of memory usage over time, making it straightforward to identify the subroutines which contribute most to the application’s peak memory usage. The information produced by the MemoryLogger quickly and effectively narrows the search for memory optimizations to the most data-intensive parts of the simulation.

  8. Dynamic failure in two-phase materials

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Fensin, S. J.; Walker, E. K.; Cerreta, E. K.; Trujillo, C. P.; Martinez, D. T.; Gray, G. T.

    2015-12-21

    Previous experimental research has shown that microstructural features such as interfaces, inclusions, vacancies, and heterogeneities can all act as voidnucleation sites. However, it is not well understood how important these interfaces are to damage evolution and failure as a function of the surrounding parentmaterials. In this work, we present results on three different polycrystallinematerials: (1) Cu, (2) Cu-24 wt. %Ag, and (3) Cu-15 wt. %Nb which were studied to probe the influence of bi-metal interfaces onvoidnucleation and growth. These materials were chosen due to the range of difference in structure and bulk properties between the two phases. The initial resultsmore » suggest that when there are significant differences between the bulk properties (for example: stacking fault energy, melting temperature, etc.) the type of interface between the two parent materials does not principally control the damage nucleation and growth process. Rather, it is the “weaker” material that dictates the dynamic spall strength of the overall two-phase material.« less

  9. Emittance and Phase Space Exchange for Advanced Beam Manipulation and

    Office of Scientific and Technical Information (OSTI)

    Diagnostics (Journal Article) | SciTech Connect Phase Space Exchange for Advanced Beam Manipulation and Diagnostics Citation Details In-Document Search Title: Emittance and Phase Space Exchange for Advanced Beam Manipulation and Diagnostics Alternative chicane-type beam lines are proposed for exact emittance exchange between transverse phase space (x,x') and longitudinal phase space (z,{delta}), where x is the transverse position, x' is the transverse divergence, and z and {delta} are

  10. Gravitational waves from phase transitions at the electroweak scale and

    Office of Scientific and Technical Information (OSTI)

    beyond (Journal Article) | SciTech Connect waves from phase transitions at the electroweak scale and beyond Citation Details In-Document Search Title: Gravitational waves from phase transitions at the electroweak scale and beyond If there was a first-order phase transition in the early universe, there should be an associated stochastic background of gravitational waves. In this paper, we point out that the characteristic frequency of the spectrum due to phase transitions which took place in

  11. Dual-phase Cr-Ta alloys for structural applications

    DOE Patents [OSTI]

    Liu, Chain T.; Brady, Michael P.; Zhu, Jiahong; Tortorelli, Peter F.

    2001-01-01

    Dual phase alloys of chromium containing 2 to 11 atomic percent tantalum with minor amounts of Mo, Cr, Ti, Y, La, Cr, Si and Ge are disclosed. These alloys contain two phases including Laves phase and Cr-rich solid solution in either eutectic structures or dispersed Laves phase particles in the Cr-rich solid solution matrix. The alloys have superior mechanical properties at high temperature and good oxidation resistance when heated to above 1000.degree. C. in air.

  12. SBIR and STTR: Topics, FY 2015 Phase I Release 2

    Broader source: Energy.gov [DOE]

    Small Business Innovation Research (SBIR) and Small Business Technology Transfer (STTR) Programs: Topics, FY 2015, Phase I, Release 2.

  13. Condensed Phase and Interfacial Molecular Science | U.S. DOE...

    Office of Science (SC) Website

    Condensed Phase and Interfacial Molecular Science Chemical Sciences, Geosciences, & ... emphasizes molecular understanding of chemical, physical, and electron-driven processes ...

  14. Propane-induced biodegradation of vapor phase trichloroethylene (Journal

    Office of Scientific and Technical Information (OSTI)

    Article) | SciTech Connect Propane-induced biodegradation of vapor phase trichloroethylene Citation Details In-Document Search Title: Propane-induced biodegradation of vapor phase trichloroethylene Microbial degradation of trichloroethylene (TCE) has been demonstrated under aerobic conditions with propane. The primary objective of this research was to evaluate the feasibility of introducing a vapor phase form of TCE in the presence of propane to batch bioreactors containing a liquid phase

  15. Launching the Next Phase of the Better Buildings Neighborhood Program |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Launching the Next Phase of the Better Buildings Neighborhood Program Launching the Next Phase of the Better Buildings Neighborhood Program Launching the Next Phase of the Better Buildings Neighborhood Program, April 30, 2013. Next step options for BBNP partners. PDF icon Launching the Next Phase of BBNP More Documents & Publications Home Performance with ENERGY STAR - 2014 BTO Peer Review Better Buildings Residential Program - 2014 BTO Peer Review Home Performance

  16. Play Fairway Analysis Phase II Selections | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Phase II Selections Play Fairway Analysis Phase II Selections Play Fairway Analysis Phase II Selections The U.S. Department of Energy (DOE) Geothermal Technologies Office (GTO) announces the selection of six projects to continue with Phase II Play Fairway Analysis (PFA) activities. The GTO will award $4.1 million additional funding to six of the eleven projects from the 2014 PFA Funding Opportunity. The concept of PFA is being used to identify prospective geothermal resources in areas with no

  17. Final Report Phase II: Performance Evaluation of Permeable Reactive

    Energy Savers [EERE]

    Barriers and Potential for Rejuvenation by Chemical Flushing | Department of Energy Report Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing Final Report Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing Final Report Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing PDF icon Final Report Phase II:

  18. Nickel/ruthenium catalyst and method for aqueous phase reactions

    DOE Patents [OSTI]

    Elliott, Douglas C.; Sealock, John L.

    1998-01-01

    A method of hydrogenation using a catalyst in the form of a plurality of porous particles wherein each particle is a support having nickel metal catalytic phase or reduced nickel deposited thereon in a first dispersed phase and an additional ruthenium metal deposited onto the support in a second dispersed phase. The additional ruthenium metal is effective in retarding or reducing agglomeration or sintering of the nickel metal catalytic phase thereby increasing the life time of the catalyst during hydrogenation reactions.

  19. Attachment 1: DOE Phased Retirement Implementation Plan Purpose:

    Energy Savers [EERE]

    1: DOE Phased Retirement Implementation Plan Purpose: Phased retirement is designed to assist agencies with knowledge management and continuity of operations in the short term. Although the main purpose is to enhance the mentoring and training of the employees who will be filling the positions or taking on duties of more experienced retiring employees, phased retirement may also be used to provide employees with the opportunity to share experiences across Departmental elements. Phased retirement

  20. Phasing of Debuncher Stochastic Cooling Transverse Systems

    SciTech Connect (OSTI)

    Pasquinelli, Ralph; /Fermilab

    2000-03-09

    With the higher frequency of the cooling systems in the Debuncher, a modified method of making transfer functions has been developed for transverse systems. (Measuring of the momentum systems is unchanged.) Speed in making the measurements is critical, as the beam tends to decelerate due to vacuum lifetime. In the 4-8 GHz band, the harmonics in the Debuncher are 6,700 to 13,400 times the revolution frequency. Every Hertz change in revolution frequency is multiplied by this harmonic number and becomes a frequency measurement error, which is an appreciable percent of the momentum width of the beam. It was originally thought that a momentum cooling system would be phased first so that the beam could be kept from drifting in revolution frequency. As it turned out, the momentum cooling was so effective (even with the gain turned down) that the momentum width normalized to fo became less than one Hertz on the Schottky pickup. A beam this narrow requires very precise measurement of tune and revolution frequency. It was difficult to get repeatable results. For initial measuring of the transverse arrays, relative phase and delay is all that is required, so the measurement settings outlined below will suffice. Once all input and output arrays are phased, a more precise measurement of all pickups to all kickers can be done with more points and both upper and lower side bands, as in figure 1. Settings on the network analyzer were adjusted for maximum measurement speed. Data is not analyzed until a complete set of measurements is taken. Start and stop frequencies should be chosen to be just slightly wider than the band being measured. For transverse systems, select betatron USB for the measurement type. This will make the measurement two times faster. Select 101 for the number of points, sweep time of 5 seconds, IF bandwidth 30 Hz, averages = 1. It is important during the phasing to continually measure the revolution frequency and beam width of the beam for transverse systems. Beam width is defined as the 3 dB bandwidth of the momentum Schottky divided by 127 (the harmonic of the Schottky pickup in the Debuncher.) Every three to five minutes, the beam drifts enough to make a significant change in the data. Knowing the revolution frequency and beam width to 0.5 Hz is important. If the beam width exceeds 10 Hz, the quality of the measurement will be impaired. Large beam widths can be caused by excessive forward proton beam current. There are also signs that the front-end amplifiers saturate with beam currents above several hundred microamps. The cooling systems were designed to be very sensitive, (that's why the front end is at liquid helium temperature) so a hundred microamps will go a long way. It should be possible to phase the systems with Pbars as a signal to noise ratio of 30 dB was observed with 100 microamps of beam current.

  1. Phase-space localization: Topological aspects of quantum chaos

    SciTech Connect (OSTI)

    Leboeuf, P. (Division de Physique Theorique, Institut de Physique Nucleire, 91406 Orsay CEDEX (France)); Kurchan, J. (Nuclear Physics Department, Weizmann Institute of Science, Rehovot 76100 (Israel)); Feingold, M. (Lawrence Berkeley Laboratory, University of California, Berkeley, CA (USA) Department of Physics, University of California, Berkeley, CA (USA)); Arovas, D.P. (Department of Physics, B-019, University of California at San Diego, La Jolla, CA (USA))

    1990-12-17

    We study quantized classically chaotic maps on a toroidal two-diensional phase space. A discrete, topological criterion for phase-space localization is presented. To each eigenfunction an integer is associated, analogous to a quantized Hall conductivity, which when nonzero reflects phase-space delocalization. A model system is studied, and a correspondence between delocalization and chaotic classical dynamics is discussed.

  2. Phase-field modeling of the beta to omega phase transformation in Zr–Nb alloys

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yeddu, Hemantha Kumar; Lookman, Turab

    2015-05-01

    A three-dimensional elastoplastic phase-field model is developed, using the Finite Element Method (FEM), for modeling the athermal beta to omega phase transformation in Zr–Nb alloys by including plastic deformation and strain hardening of the material. The microstructure evolution during athermal transformation as well as under different stress states, e.g. uni-axial tensile and compressive, bi-axial tensile and compressive, shear and tri-axial loadings, is studied. The effects of plasticity, stress states and the stress loading direction on the microstructure evolution as well as on the mechanical properties are studied. The input data corresponding to a Zr – 8 at.% Nb alloy aremore » acquired from experimental studies as well as by using the CALPHAD method. Our simulations show that the four different omega variants grow as ellipsoidal shaped particles. Our results show that due to stress relaxation, the athermal phase transformation occurs slightly more readily in the presence of plasticity compared to that in its absence. The evolution of omega phase is different under different stress states, which leads to the differences in the mechanical properties of the material. The variant selection mechanism, i.e. formation of different variants under different stress loading directions, is also nicely captured by our model.« less

  3. Asymptotic geometric phase and purity for phase qubit dispersively coupled to lossy LC circuit

    SciTech Connect (OSTI)

    Mohamed, A.-B.A.; Obada, A.-S.F.

    2011-09-15

    Analytical descriptions of the geometric phases (GPs) for the total system and subsystems are studied for a current biased Josephson phase qubit strongly coupled to a lossy LC circuit in the dispersive limit. It is found that, the GP and purity depend on the damping parameter which leads to the phenomenon of GP death. Coherence parameter delays the phenomenon of a regular sequence of deaths and births of the GP. The asymptotic behavior of the GP and the purity for the qubit-LC resonator state closely follow that for the qubit state, but however, for the LC circuit these asymptotic values are equal to zero. - Highlights: > The model of a current biased Josephson phase qubit, strongly coupled to loss LC circuit, is considered. > Analytical descriptions of the geometric phase (GP) of this model, in the dispersive limit, are studied. > The GP and purity depend on the dissipation which leads to the GP death phenomenon. > Coherence parameter delays the phenomenon of a regular sequence of deaths and births of the GP.

  4. Emittance and Phase Space Exchange (Conference) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Emittance and Phase Space Exchange Citation Details In-Document Search Title: Emittance and Phase Space Exchange Alternative chicane-type beam lines are proposed for exact emittance exchange between horizontal phase space (x; x{prime}) and longitudinal phase space (z; {delta}). Methods to achieve exact phase space exchanges, i.e. mapping x to z, x{prime} to {delta}, z to x and {delta} to x{prime} are suggested. Methods to mitigate the thick-lens effect of the transverse cavity on emittance

  5. Reverse phase transformation of martensite to austenite in stainless

    Office of Scientific and Technical Information (OSTI)

    steels: a 3D phase-field study (Journal Article) | SciTech Connect Reverse phase transformation of martensite to austenite in stainless steels: a 3D phase-field study Citation Details In-Document Search Title: Reverse phase transformation of martensite to austenite in stainless steels: a 3D phase-field study Authors: Yeddu, Hemantha K. [1] ; Lookman, Turab [1] ; Saxena, Avadh B. [1] + Show Author Affiliations Los Alamos National Laboratory Publication Date: 2014-08-19 OSTI Identifier:

  6. Revenue phase-in plans equal deferred taxable income

    SciTech Connect (OSTI)

    Beck, D.E.

    1994-04-01

    Recently, utilities seeking rate increases have submitted innovative petitions for phase-in rate relief to state regulators. According to the Edison Electric Institute, the industry has seen almost 80 phase-in rate orders issued nation-wide in the last six years. For financial reporting purposes, deferred revenues under phase-in plans must be recognized as current income in the first year of the phase-in. The Internal Revenue Service (IRS) at the Industry Coordinator level, however, recently accepted the position that deferred phase-in revenues accrued for book purposes are not immediately taxable income to the utility.

  7. Solid phase microextraction device using aerogel

    DOE Patents [OSTI]

    Miller, Fred S.; Andresen, Brian D.

    2005-06-14

    A sample collection substrate of aerogel and/or xerogel materials bound to a support structure is used as a solid phase microextraction (SPME) device. The xerogels and aerogels may be organic or inorganic and doped with metals or other compounds to target specific chemical analytes. The support structure is typically formed of a glass fiber or a metal wire (stainless steel or kovar). The devices are made by applying gel solution to the support structures and drying the solution to form aerogel or xerogel. Aerogel particles may be attached to the wet layer before drying to increase sample collection surface area. These devices are robust, stable in fields of high radiation, and highly effective at collecting gas and liquid samples while maintaining superior mechanical and thermal stability during routine use. Aerogel SPME devices are advantageous for use in GC/MS analyses due to their lack of interfering background and tolerance of GC thermal cycling.

  8. Monitoring of vapor phase polycyclic aromatic hydrocarbons

    DOE Patents [OSTI]

    Vo-Dinh, Tuan; Hajaligol, Mohammad R.

    2004-06-01

    An apparatus for monitoring vapor phase polycyclic aromatic hydrocarbons in a high-temperature environment has an excitation source producing electromagnetic radiation, an optical path having an optical probe optically communicating the electromagnetic radiation received at a proximal end to a distal end, a spectrometer or polychromator, a detector, and a positioner coupled to the first optical path. The positioner can slidably move the distal end of the optical probe to maintain the distal end position with respect to an area of a material undergoing combustion. The emitted wavelength can be directed to a detector in a single optical probe 180.degree. backscattered configuration, in a dual optical probe 180.degree. backscattered configuration or in a dual optical probe 90.degree. side scattered configuration. The apparatus can be used to monitor an emitted wavelength of energy from a polycyclic aromatic hydrocarbon as it fluoresces in a high temperature environment.

  9. Noise in phase-preserving linear amplifiers

    SciTech Connect (OSTI)

    Pandey, Shashank; Jiang, Zhang; Combes, Joshua; Caves, Carlton M.

    2014-12-04

    The purpose of a phase-preserving linear amplifier is to make a small signal larger, so that it can be perceived by instruments incapable of resolving the original signal, while sacrificing as little as possible in signal-to-noise. Quantum mechanics limits how well this can be done: the noise added by the amplifier, referred to the input, must be at least half a quantum at the operating frequency. This well-known quantum limit only constrains the second moments of the added noise. Here we provide the quantum constraints on the entire distribution of added noise: any phasepreserving linear amplifier is equivalent to a parametric amplifier with a physical state ? for the ancillary mode; ? determines the properties of the added noise.

  10. Low Noise Borehole Triaxial Seismometer Phase II

    SciTech Connect (OSTI)

    Kerr, James D; McClung, David W

    2006-11-06

    This report describes the preliminary design and the effort to date of Phase II of a Low Noise Borehole Triaxial Seismometer for use in networks of seismic stations for monitoring underground nuclear explosions. The design uses the latest technology of broadband seismic instrumentation. Each parameter of the seismometer is defined in terms of the known physical limits of the parameter. These limits are defined by the commercially available components, and the physical size constraints. A theoretical design is proposed, and a preliminary prototype model of the proposed instrument has been built. This prototype used the sensor module of the KS2000. The installation equipment (hole locks, etc.) has been designed and one unit has been installed in a borehole. The final design of the sensors and electronics and leveling mechanism is in process. Noise testing is scheduled for the last quarter of 2006.

  11. SEISMIC MODELING ENGINES PHASE 1 FINAL REPORT

    SciTech Connect (OSTI)

    BRUCE P. MARION

    2006-02-09

    Seismic modeling is a core component of petroleum exploration and production today. Potential applications include modeling the influence of dip on anisotropic migration; source/receiver placement in deviated-well three-dimensional surveys for vertical seismic profiling (VSP); and the generation of realistic data sets for testing contractor-supplied migration algorithms or for interpreting AVO (amplitude variation with offset) responses. This project was designed to extend the use of a finite-difference modeling package, developed at Lawrence Berkeley Laboratories, to the advanced applications needed by industry. The approach included a realistic, easy-to-use 2-D modeling package for the desktop of the practicing geophysicist. The feasibility of providing a wide-ranging set of seismic modeling engines was fully demonstrated in Phase I. The technical focus was on adding variable gridding in both the horizontal and vertical directions, incorporating attenuation, improving absorbing boundary conditions and adding the optional coefficient finite difference methods.

  12. Phase-shifting point diffraction interferometer

    DOE Patents [OSTI]

    Medecki, Hector

    1998-01-01

    Disclosed is a point diffraction interferometer for evaluating the quality of a test optic. In operation, the point diffraction interferometer includes a source of radiation, the test optic, a beam divider, a reference wave pinhole located at an image plane downstream from the test optic, and a detector for detecting an interference pattern produced between a reference wave emitted by the pinhole and a test wave emitted from the test optic. The beam divider produces separate reference and test beams which focus at different laterally separated positions on the image plane. The reference wave pinhole is placed at a region of high intensity (e.g., the focal point) for the reference beam. This allows reference wave to be produced at a relatively high intensity. Also, the beam divider may include elements for phase shifting one or both of the reference and test beams.

  13. Phase-shifting point diffraction interferometer

    DOE Patents [OSTI]

    Medecki, H.

    1998-11-10

    Disclosed is a point diffraction interferometer for evaluating the quality of a test optic. In operation, the point diffraction interferometer includes a source of radiation, the test optic, a beam divider, a reference wave pinhole located at an image plane downstream from the test optic, and a detector for detecting an interference pattern produced between a reference wave emitted by the pinhole and a test wave emitted from the test optic. The beam divider produces separate reference and test beams which focus at different laterally separated positions on the image plane. The reference wave pinhole is placed at a region of high intensity (e.g., the focal point) for the reference beam. This allows reference wave to be produced at a relatively high intensity. Also, the beam divider may include elements for phase shifting one or both of the reference and test beams. 8 figs.

  14. Linkage of PRA models. Phase 1, Results

    SciTech Connect (OSTI)

    Smith, C.L.; Knudsen, J.K.; Kelly, D.L.

    1995-12-01

    The goal of the Phase I work of the ``Linkage of PRA Models`` project was to postulate methods of providing guidance for US Nuclear Regulator Commission (NRC) personnel on the selection and usage of probabilistic risk assessment (PRA) models that are best suited to the analysis they are performing. In particular, methods and associated features are provided for (a) the selection of an appropriate PRA model for a particular analysis, (b) complementary evaluation tools for the analysis, and (c) a PRA model cross-referencing method. As part of this work, three areas adjoining ``linking`` analyses to PRA models were investigated: (a) the PRA models that are currently available, (b) the various types of analyses that are performed within the NRC, and (c) the difficulty in trying to provide a ``generic`` classification scheme to groups plants based upon a particular plant attribute.

  15. Method for dissolving delta-phase plutonium

    DOE Patents [OSTI]

    Karraker, David G.

    1992-01-01

    A process for dissolving plutonium, and in particular, delta-phase plutonium. The process includes heating a mixture of nitric acid, hydroxylammonium nitrate (HAN) and potassium fluoride to a temperature between 40.degree. and 70.degree. C., then immersing the metal in the mixture. Preferably, the nitric acid has a concentration of not more than 2M, the HAN approximately 0.66M, and the potassium fluoride 0.1M. Additionally, a small amount of sulfamic acid, such as 0.1M can be added to assure stability of the HAN in the presence of nitric acid. The oxide layer that forms on plutonium metal may be removed with a non-oxidizing acid as a pre-treatment step.

  16. Combined Experiment Phase 1. Final report

    SciTech Connect (OSTI)

    Butterfield, C.P.; Musial, W.P.; Simms, D.A.

    1992-10-01

    How does wind tunnel airfoil data differ from the airfoil performance on an operating horizontal axis wind turbine (HAWT)? The National Renewable Energy laboratory has been conducting a comprehensive test program focused on answering this question and understanding the basic fluid mechanics of rotating HAWT stall aerodynamics. The basic approach was to instrument a wind rotor, using an airfoil that was well documented by wind tunnel tests, and measure operating pressure distributions on the rotating blade. Based an the integrated values of the pressure data, airfoil performance coefficients were obtained, and comparisons were made between the rotating data and the wind tunnel data. Care was taken to the aerodynamic and geometric differences between the rotating and the wind tunnel models. This is the first of two reports describing the Combined Experiment Program and its results. This Phase I report covers background information such as test setup and instrumentation. It also includes wind tunnel test results and roughness testing.

  17. Dry powder mixes comprising phase change materials

    DOE Patents [OSTI]

    Salyer, I.O.

    1993-10-19

    Free flowing, conformable powder-like mix of silica particles and a phase change material (pcm) is disclosed. The silica particles have a critical size of about 7[times]10[sup [minus]3] to about 7[times]10[sup [minus]2] microns and the pcm must be added to the silica in an amount of 80 wt. % or less pcm per combined weight of silica and pcm. The powder-like mix can be used in tableware items, medical wraps, tree wraps, garments, quilts and blankets, and in cementitious compositions of the type in which it is beneficial to use a pcm material. The silica-pcm mix can also be admixed with soil to provide a soil warming effect and placed about a tree, flower, or shrub. 10 figures.

  18. Dry powder mixes comprising phase change materials

    DOE Patents [OSTI]

    Salyer, I.O.

    1993-05-18

    Free flowing, conformable powder-like mix of silica particles and a phase change material (p.c.m.) is disclosed. The silica particles have a critical size of about 7[times]10[sup [minus]3] to about 7[times]10[sup [minus]2] microns and the p.c.m. must be added to the silica in an amount of 80 wt. % or less p.c.m. per combined weight of silica and p.c.m. The powder-like mix can be used in tableware items, medical wraps, tree wraps, garments, quilts and blankets, and in cementitious compositions of the type in which it is beneficial to use a p.c.m. material. The silica-p.c.m. mix can also be admixed with soil to provide a soil warming effect and placed about a tree, flower, or shrub.

  19. Dry powder mixes comprising phase change materials

    DOE Patents [OSTI]

    Salyer, Ival O.

    1993-01-01

    Free flowing, conformable powder-like mix of silica particles and a phase change material (p.c.m.) is disclosed. The silica particles have a critical size of about 7.times.10.sup.-3 to about 7.times.10.sup.-2 microns and the pcm must be added to the silica in an amount of 80 wt. % or less pcm per combined weight of silica and pcm. The powder-like mix can be used in tableware items, medical wraps, tree wraps, garmets, quilts and blankets, and in cementitious compositions of the type in which it is beneficial to use a pcm material. The silica-pcm mix can also be admixed with soil to provide a soil warming effect and placed about a tree, flower, or shrub.

  20. Dry powder mixes comprising phase change materials

    DOE Patents [OSTI]

    Salyer, I.O.

    1992-04-21

    A free flowing, conformable powder-like mix of silica particles and a phase change material (p.c.m.) is disclosed. The silica particles have a critical size of about 7 [times] 10[sup [minus]3] to about 7 [times] 10[sup [minus]2] microns and the pcm must be added to the silica in an amount of 80 wt. % or less pcm per combined weight of silica and pcm. The powder-like mix can be used in tableware items, medical wraps, tree wraps, garments, quilts and blankets, and in cementitious compositions of the type in which it is beneficial to use a pcm material. The silica-pcm mix can also be admixed with soil to provide a soil warming effect and placed about a tree, flower, or shrub. 9 figs.

  1. Dry powder mixes comprising phase change materials

    DOE Patents [OSTI]

    Salyer, Ival O.

    1993-01-01

    Free flowing, conformable powder-like mix of silica particles and a phase change material (p.c.m.) is disclosed. The silica particles have a critical size of about 7.times.10.sup.-3 to about 7.times.10.sup.-2 microns and the pcm must be added to the silica in an amount of 80 wt. % or less pcm per combined weight of silica and pcm. The powder-like mix can be used in tableware items, medical wraps, tree wraps, garments, quilts and blankets, and in cementitious compositions of the type in which it is beneficial to use a pcm material. The silica-pcm mix can also be admixed with soil to provide a soil warming effect and placed about a tree, flower, or shrub.

  2. Dry powder mixes comprising phase change materials

    DOE Patents [OSTI]

    Salyer, I.O.

    1994-02-01

    Free flowing, conformable powder-like mix of silica particles and a phase change material (PCM) is provided. The silica particles have a critical size of about 0.005 to about 0.025 microns and the PCM must be added to the silica in an amount of 75% or less PCM per combined weight of silica and PCM. The powder-like mix can be used in tableware items, medical wraps, tree wraps, garments, quilts and blankets, and in cementitious compositions of the type in which it is beneficial to use a PCM material. The silica-PCM mix can also be admixed with soil to provide a soil warming effect and placed about a tree, flower, or shrub. 2 figures.

  3. Dry powder mixes comprising phase change materials

    DOE Patents [OSTI]

    Salyer, Ival O.

    1994-01-01

    Free flowing, conformable powder-like mix of silica particles and a phase change material (PCM) is provided. The silica particles have a critical size of about 0.005 to about 0.025 microns and the PCM must be added to the silica in an amount of 75% or less PCM per combined weight of silica and PCM. The powder-like mix can be used in tableware items, medical wraps, tree wraps, garments, quilts and blankets, and in cementitious compositions of the type in which it is beneficial to use a PCM material. The silica-PCM mix can also be admixed with soil to provide a soil warming effect and placed about a tree, flower, or shrub.

  4. Dry powder mixes comprising phase change materials

    DOE Patents [OSTI]

    Salyer, Ival O.

    1992-01-01

    Free flowing, conformable powder-like mix of silica particles and a phase change material (p.c.m.) is disclosed. The silica particles have a critical size of about 7.times.10.sup.-3 to about 7.times.10.sup.-2 microns and the pcm must be added to the silica in an amount of 80 wt. % or less pcm per combined weight of silica and pcm. The powder-like mix can be used in tableware items, medical wraps, tree wraps, garments, quilts and blankets, and in cementitious compositions of the type in which it is beneficial to use a pcm material. The silica-pcm mix can also be admixed with soil to provide a soil warming effect and placed about a tree, flower, or shrub.

  5. Transuranic (TRU) Waste Phase I Retrieval Plan

    SciTech Connect (OSTI)

    MCDONALD, K.M.

    2000-09-28

    From 1970 to 1987, TRU and suspect TRU wastes at Hanford were placed in the SWBG. At the time of placement in the SWBG these wastes were not regulated under existing Resource Conservation and Recovery Act (RCRA) regulations, since they were generated and disposed of prior to the effective date of RCRA at the Hanford Site (1987). From the standpoint of DOE Order 5820.2A1, the TRU wastes are considered retrievably stored, and current plans are to retrieve these wastes for shipment to WIPP for disposal. This plan provides a strategy for the Phase I retrieval that meets the intent of TPA milestone M-91 and Project W-113, and incorporates the lessons learned during TRU retrieval campaigns at Hanford, LANL, and SRS. As in the original Project W-113 plans, the current plan calls for examination of approximately 10,000 suspect-TRU drums located in the 218-W-4C burial ground followed by the retrieval of those drums verified to contain TRU waste. Unlike the older plan, however, this plan proposes an open-air retrieval scenario similar to those used for TRU drum retrieval at LANL and SRS. Phase I retrieval consists of the activities associated with the assessment of approximately 10,000 55-gallon drums of suspect TRU-waste in burial ground 218-W-4C and the retrieval of those drums verified to contain TRU waste. Four of the trenches in 218-W-4C (Trenches 1, 4, 20, and 29) are prime candidates for Phase I retrieval because they contain large numbers of suspect TRU drums, stacked from 2 to 5 drums high, on an asphalt pad. In fact, three of the trenches (Trenches 1 , 20, and 29) contain waste that has not been covered with soil, and about 1500 drums can be retrieved without excavation. The other three trenches in 218-W-4C (Trenches 7, 19, and 24) are not candidates for Phase I retrieval because they contain significant numbers of boxes. Drums will be retrieved from the four candidate trenches, checked for structural integrity, overpacked, if necessary, and assayed at the burial ground. A mobile assay system will be used to determine if the drum is LLW (Le., contains <100 nCi/g). LLW will remain disposed of in the 218-W-4C Burial Ground. TRU waste will be retrieved and staged in the burial ground until it can be shipped to the CWC. The TRU drums will be stored at the CWC until they can be moved to WRAP. The WRAP facility will prepare the waste for shipment to WIPP for final disposal. For planning purposes, approximately 50% of the 10,000 drums have been estimated to contain LLW.

  6. Offline solid phase microextraction sampling system

    DOE Patents [OSTI]

    Harvey, Chris A.

    2008-12-16

    An offline solid phase microextraction (SPME) sampling apparatus for enabling SPME samples to be taken a number of times from a previously collected fluid sample (e.g. sample atmosphere) stored in a fused silica lined bottle which keeps volatile organics in the fluid sample stable for weeks at a time. The offline SPME sampling apparatus has a hollow body surrounding a sampling chamber, with multiple ports through which a portion of a previously collected fluid sample may be (a) released into the sampling chamber, (b) SPME sampled to collect analytes for subsequent GC analysis, and (c) flushed/purged using a fluidically connected vacuum source and purging fluid source to prepare the sampling chamber for additional SPME samplings of the same original fluid sample, such as may have been collected in situ from a headspace.

  7. Phase I Report: DARPA Exoskeleton Program

    SciTech Connect (OSTI)

    Jansen, J.F.

    2004-01-21

    The Defense Advanced Research Projects Agency (DARPA) inaugurated a program addressing research and development for an Exoskeleton for Human Performance Augmentation in FY!2001. A team consisting of Oak Ridge National Laboratory, the prime contractor, AeroVironment, Inc., the Army Research Laboratory, the University of Minnesota, and the Virginia Polytechnic Institute has recently completed an 18-month Phase I effort in support of this DARPA program. The Phase I effort focused on the development and proof-of-concept demonstrations for key enabling technologies, laying the foundation for subsequently building and demonstrating a prototype exoskeleton. The overall approach was driven by the need to optimize energy efficiency while providing a system that augmented the operator in as transparent manner as possible (non-impeding). These needs led to the evolution of two key distinguishing features of this team's approach. The first is the ''no knee contact'' concept. This concept is dependent on a unique Cartesian-based control scheme that uses force sensing at the foot and backpack attachments to allow the exoskeleton to closely follow the operator while avoiding the difficulty of connecting and sensing position at the knee. The second is an emphasis on energy efficiency manifested by an energetic, power, actuation and controls approach designed to enhance energy efficiency as well as a reconfigurable kinematic structure that provides a non-anthropomorphic configuration to support an energy saving long-range march/transport mode. The enabling technologies addressed in the first phase were controls and sensing, the soft tissue interface between the machine and the operator, the power system, and actuation. The controller approach was implemented and demonstrated on a test stand with an actual operator. Control stability, low operator fatigue, force amplification and the human interface were all successfully demonstrated, validating the controls approach. A unique, lightweight, low profile, multi-axis foot sensor (an integral element of the controls approach) was designed, fabricated, and its performance verified. A preliminary conceptual design of the human coupling and soft tissue interface, based on biomechanics research has been developed along with a test plan to support an iterative design process. The power system concept, a fuel cell hybrid power supply using chemical generated hydrogen, was successfully demonstrated and shown to be able to efficiently meet both steady-state and transient peak loads. Two actuator approaches, a piezoelectric actuator, with theoretical high power densities and an approach based on a high-performance, high-speed electric motor driving a miniature hydraulic pump have been investigated. The first shows great potential but will require further research before reaching that promise. The other approach has been modeled and simulated and shown to provide the possibility for significant energy savings (>30%) and improved power densities in comparison to conventional hydraulics. Biomechanics analysis and testing were also performed in support of these enabling technologies, to provide a basis for design criteria. An analysis was performed to determine baseline data for initial mechanical design and power supply sizing. Testing conducted to evaluate boot sole thickness found that thickness increases up to two inches could be accommodated without significant impact on human factors issues. This 18-month long Phase I effort has evaluated key enabling technologies and demonstrated advances in these technologies that have significantly increased the likelihood of building a functional prototype exoskeleton.

  8. Phase Chemistry of Tank Sludge Residual Components

    SciTech Connect (OSTI)

    KRUMHANSL,JAMES L.; LIU,JUN; NAGY,KATHRYN L.; BRADY,PATRICK V.

    1999-11-29

    We are attempting to understand the solid phase chemistry of the high level nuclear waste (HLW) stored in tanks at Hanford. Because this waste is compositionally complex, our approach is to study experimentally the aging dynamics of simplified systems whose bulk chemistry approximates that of the tank sludges. After a basic understanding of these dynamics has been attained we plan to increase the compositional complexities one component at a time, in order to assess the influence of each component. Results will allow for reliable prediction of sludge phase chemistry over a range of sludge compositions. Iron and aluminum comprise the bulk of most HLW sludges, so we chose to begin by studying the behavior of iron-aluminum systems. Fe/Al ratios were chosen to approximate those relevant to the solutions that produced the sludge. Aluminum and iron concentrations in the various process fluids are summarized and compared to our experimental starting solutions in Table 1 (process solution data from Krumhansl, personal communication, 1998). Our low aluminum experiments serve as direct analogues to both Bismuth Phosphate and low-Fe PUREX waste. Cornell and Giovanoli (1985) found that, in a pure iron system at 70 C, a 10-fold or even 50-fold increase in suspension concentration had only very slight effects on the final aged products. Since our experiments have similar Al/Fe ratios to some high Fe-PUREX process solutions our results are probably relevant to those wastes as well. However, our results may not apply to the high-Fe and high-Al PUREX wastes, as discussed below. The high Al experiments were designed specifically to simulate REDOX waste.

  9. Method of using an electric field controlled emulsion phase contactor

    DOE Patents [OSTI]

    Scott, T.C.

    1993-11-16

    A system is described for contacting liquid phases comprising a column for transporting a liquid phase contacting system, the column having upper and lower regions. The upper region has a nozzle for introducing a dispersed phase and means for applying thereto a vertically oriented high intensity pulsed electric field. This electric field allows improved flow rates while shattering the dispersed phase into many micro-droplets upon exiting the nozzle to form a dispersion within a continuous phase. The lower region employs means for applying to the dispersed phase a horizontally oriented high intensity pulsed electric field so that the dispersed phase undergoes continuous coalescence and redispersion while being urged from side to side as it progresses through the system, increasing greatly the mass transfer opportunity. 5 figures.

  10. Method of using an electric field controlled emulsion phase contactor

    DOE Patents [OSTI]

    Scott, Timothy C.

    1993-01-01

    A system for contacting liquid phases comprising a column for transporting a liquid phase contacting system, the column having upper and lower regions. The upper region has a nozzle for introducing a dispersed phase and means for applying thereto a vertically oriented high intensity pulsed electric field. This electric field allows improved flow rates while shattering the dispersed phase into many micro-droplets upon exiting the nozzle to form a dispersion within a continuous phase. The lower region employs means for applying to the dispersed phase a horizontally oriented high intensity pulsed electric field so that the dispersed phase undergoes continuous coalescence and redispersion while being urged from side to side as it progresses through the system, increasing greatly the mass transfer opportunity.

  11. Method for identifying and probing phase transitions in materials

    DOE Patents [OSTI]

    Asay, Blaine W. (Los Alamos, NM); Henson, Bryan F. (Los Alamos, NM); Sander, Robert K. (Los Alamos, NM); Robinson, Jeanne M. (Los Alamos, NM); Son, Steven F. (Los Alamos, NM); Dickson, Peter M. (Los Alamos, NM)

    2002-01-01

    The present invention includes a method for identifying and probing phase transitions in materials. A polymorphic material capable of existing in at least one non-centrosymmetric phase is interrogated with a beam of laser light at a chosen wavelength and frequency. A phase transition is induced in the material while it is interrogated. The intensity of light scattered by the material and having a wavelength equal to one half the wavelength of the interrogating laser light is detected. If the phase transition results in the production of a non-centrosymmetric phase, the intensity of this scattered light increases; if the phase transition results in the disappearance of a non-centrosymmetric phase, the intensity of this scattered light decreases.

  12. Structures of two intermediate phases between the B1 and B2 phases of PbS under high pressure

    SciTech Connect (OSTI)

    Li, Yanchun E-mail: liuj@ihep.ac.cn; Lin, Chuanlong; Li, Xiaodong; Liu, Jing E-mail: liuj@ihep.ac.cn; Xu, Jian; Li, Gong

    2014-12-15

    The structural transitions of PbS were investigated at pressures up to 50 GPa using synchrotron powder and single crystal X-ray diffraction (XRD) methods in diamond anvil cells. We found two intermediate phases between the B1 phase under atmospheric pressure and the B2 phase at 21.1 GPa, which is different to previous reports. The structures of these two intermediate phases were indexed as B27 and B33, respectively. Their structural parameters were investigated using density functional theory (DFT) calculations. Our results provide a new insight into understanding the transition pathway between the B1 and B2 phases in PbS.

  13. CX-010312: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Dense Non-Aqueous Phase Liquid (DNAPL) Characterization at the M-Area Settling Basin Western Sector Treatment System (WSTS) CX(s) Applied: B3.1 Date: 04/26/2013 Location(s): South Carolina Offices(s): Savannah River Operations Office

  14. Development of Chemical Model to Predict the Interactions between Supercritical CO2and Fluid, and Rocks in EGS Reservoirs

    Broader source: Energy.gov [DOE]

    This project will develop a chemical model, based on existing models and databases, that is capable of simulating chemical reactions between supercritical (SC) CO2 and Enhanced Geothermal System (EGS) reservoir rocks of various compositions in aqueous, non-aqueous and 2-phase environments.

  15. Atomic-scale evolution of modulated phases at the ferroelectric-antiferroelectric morphotropic phase boundary controlled by flexoelectric interaction

    SciTech Connect (OSTI)

    Borisevich, Albina Y; Eliseev, Eugene; Morozovska, A. N.; Cheng, Ching-Jung; Lin, Jiunn-Yuan; Chu, Ying-Hao; Kan, Daisuke; Takeuchi, Ichiro; Valanoor, Nagarajan V; Kalinin, Sergei V

    2012-01-01

    Physical and structural origins of morphotropic phase boundaries (MPBs) in ferroics remain elusive despite decades of studies. The leading competing theories employ either low symmetry bridging phases or adaptive phases with nanoscale textures to describe different subsets of the macroscopic data, while the decisive atomic-scale information has so far been missing. We report direct atomically-resolved mapping of polarization and structure order parameter fields in Sm-doped BiFeO3 system and their evolution as the system approaches MPB. We further show that both the experimental phase diagram and the phase evolution observed by STEM can be explained by taking into account flexoelectric interaction, which renders the effective domain wall energy negative, thus stabilizing modulated phases in the vicinity of the MPB. Our study highlights the importance of local order parameter mapping at the atomic scale and establishes a hitherto unobserved physical origin of spatially modulated phases existing in the vicinity of the MPB.

  16. Atomic Structure and Phase Transformations in Pu Alloys

    SciTech Connect (OSTI)

    Schwartz, A J; Cynn, H; Blobaum, K M; Wall, M A; Moore, K T; Evans, W J; Farber, D L; Jeffries, J R; Massalski, T B

    2008-04-28

    Plutonium and plutonium-based alloys containing Al or Ga exhibit numerous phases with crystal structures ranging from simple monoclinic to face-centered cubic. Only recently, however, has there been increased convergence in the actinides community on the details of the equilibrium form of the phase diagrams. Practically speaking, while the phase diagrams that represent the stability of the fcc {delta}-phase field at room temperature are generally applicable, it is also recognized that Pu and its alloys are never truly in thermodynamic equilibrium because of self-irradiation effects, primarily from the alpha decay of Pu isotopes. This article covers past and current research on several properties of Pu and Pu-(Al or Ga) alloys and their connections to the crystal structure and the microstructure. We review the consequences of radioactive decay, the recent advances in understanding the electronic structure, the current research on phase transformations and their relations to phase diagrams and phase stability, the nature of the isothermal martensitic {delta} {yields} {alpha}{prime} transformation, and the pressure-induced transformations in the {delta}-phase alloys. New data are also presented on the structures and phase transformations observed in these materials following the application of pressure, including the formation of transition phases.

  17. Helical Phase Inflation and Monodromy in Supergravity Theory

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Li, Tianjun; Li, Zhijin; Nanopoulos, Dimitri V.

    2015-01-01

    We smore » tudy helical phase inflation which realizes “monodromy inflation” in supergravity theory. In the model, inflation is driven by the phase component of a complex field whose potential possesses helicoid structure. We construct phase monodromy based on explicitly breaking global U ( 1 ) symmetry in the superpotential. By integrating out heavy fields, the phase monodromy from single complex scalar field is realized and the model fulfills natural inflation. The phase-axion alignment is achieved from explicitly symmetry breaking and gives super-Planckian phase decay constant. The F -term scalar potential provides strong field stabilization for all the scalars except inflaton, which is protected by the approximate global U ( 1 ) symmetry. Besides, we show that helical phase inflation can be naturally realized in no-scale supergravity with S U ( 2,1 ) / S U ( 2 ) × U ( 1 ) symmetry since the supergravity setup needed for phase monodromy is automatically provided in the no-scale Kähler potential. We also demonstrate that helical phase inflation can be reduced to another well-known supergravity inflation model with shift symmetry. Helical phase inflation is free from the UV-sensitivity problem although there is super-Planckian field excursion, and it suggests that inflation can be effectively studied based on supersymmetric field theory while a UV-completed framework is not prerequisite.« less

  18. CONVERSION EXTRACTION DESULFURIZATION (CED) PHASE III

    SciTech Connect (OSTI)

    James Boltz

    2005-03-01

    This project was undertaken to refine the Conversion Extraction Desulfurization (CED) technology to efficiently and economically remove sulfur from diesel fuel to levels below 15-ppm. CED is considered a generic term covering all desulfurization processes that involve oxidation and extraction. The CED process first extracts a fraction of the sulfur from the diesel, then selectively oxidizes the remaining sulfur compounds, and finally extracts these oxidized materials. The Department of Energy (DOE) awarded Petro Star Inc. a contract to fund Phase III of the CED process development. Phase III consisted of testing a continuous-flow process, optimization of the process steps, design of a pilot plant, and completion of a market study for licensing the process. Petro Star and the Degussa Corporation in coordination with Koch Modular Process Systems (KMPS) tested six key process steps in a 7.6-centimeter (cm) (3.0-inch) inside diameter (ID) column at gas oil feed rates of 7.8 to 93.3 liters per hour (l/h) (2.1 to 24.6 gallons per hour). The team verified the technical feasibility with respect to hydraulics for each unit operation tested and successfully demonstrated pre-extraction and solvent recovery distillation. Test operations conducted at KMPS demonstrated that the oxidation reaction converted a maximum of 97% of the thiophenes. The CED Process Development Team demonstrated that CED technology is capable of reducing the sulfur content of light atmospheric gas oil from 5,000-ppm to less than 15-ppm within the laboratory scale. In continuous flow trials, the CED process consistently produced fuel with approximately 20-ppm of sulfur. The process economics study calculated an estimated process cost of $5.70 per product barrel. The Kline Company performed a marketing study to evaluate the possibility of licensing the CED technology. Kline concluded that only 13 refineries harbored opportunity for the CED process. The Kline study and the research team's discussions with prospective refineries led to the conclusion that there were not likely prospects for the licensing of the CED process.

  19. Intermittent Renewable Management Pilot Phase 2

    SciTech Connect (OSTI)

    Kiliccote, Sila; Homan, Gregory; Anderson, Robert; Hernandez, John

    2015-04-01

    The Intermittent Renewable Management Pilot - Phase 2 (IRM2) was designed to study the feasibility of demand-side resources to participate into the California Independent System Operator (CAISO) wholesale market as proxy demand resources (PDR). The pilot study focused on understanding the issues related with direct participation of third-parties and customers including customer acceptance; market transformation challenges (wholesale market, technology); technical and operational feasibility; and value to the rate payers, DR resource owners and the utility on providing an enabling mechanism for DR resources into the wholesale markets. The customer had the option of committing to either three contiguous hour blocks for 24 days or six contiguous hours for 12 days a month with day-ahead notification that aligned with the CAISO integrated forward market. As a result of their being available, the customer was paid $10/ kilowatt (kW)-month for capacity in addition to CAISO energy settlements. The participants were limited to no more than a 2 megawatt (MW) capacity with a six-month commitment. Four participants successfully engaged in the pilot. In this report, we provide the description of the pilot, participant performance results, costs and value to participants as well as outline some of the issues encountered through the pilot. Results show that participants chose to participate with storage and the value of CAISO settlements were significantly lower than the capacity payments provided by the utility as incentive payments. In addition, this pilot revealed issues both on the participant side and system operations side. These issues are summarized in the report.The Intermittent Renewable Management Pilot - Phase 2 (IRM2) was designed to study the feasibility of demand-side resources to participate into the California Independent System Operator (CAISO) wholesale market as proxy demand resources (PDR). The pilot study focused on understanding the issues related with direct participation of third-parties and customers including customer acceptance; market transformation challenges (wholesale market, technology); technical and operational feasibility; and value to the rate payers, DR resource owners and the utility on providing an enabling mechanism for DR resources into the wholesale markets.

  20. Clean Air Act Title IV: Lessons learned from Phase I; getting ready for Phase II

    SciTech Connect (OSTI)

    Miller, M.J.

    1997-12-31

    The 1990 Clean Air Act Amendments have required significant reductions in SO{sub 2} and NO{sub x} emissions from fossil fuel-fired power plants in the US. This paper examines some of the key technical lessons learned in Phase I following retrofit of low NO{sub x} systems, FGD systems, and continuous emissions monitors. Some of the key problems encountered have been waterwall wastage as a result of low NO{sub x} burner retrofits; high LOI (carbon) ash as a result of low NO{sub x} operation; high O&M costs associated with CEMs; and the heat rate discrepancy which has arisen between CEMs and conventional heat rate calculations. As Phase II approaches, EPRI and the electric utility industry are investigating improvements in FGD systems (e.g., clear liquor scrubbing), advances in NO{sub x} control technologies, more robust CEM systems, and tools to help in the technology decision-making process.

  1. Phase II Final Scientific/Technical Report

    SciTech Connect (OSTI)

    Grigg, Reid; McPherson, Brian; Lee, Rober

    2011-08-01

    The Southwest Regional Partnership on Carbon Sequestration (SWP) one of seven regional partnerships sponsored by the U.S. Department of Energy (USDOE) carried out five field pilot tests in its Phase II Carbon Sequestration Demonstration effort, to validate the most promising sequestration technologies and infrastructure concepts, including three geologic pilot tests and two terrestrial pilot programs. This field testing demonstrated the efficacy of proposed sequestration technologies to reduce or offset greenhouse gas emissions in the region. Risk mitigation, optimization of monitoring, verification, and accounting (MVA) protocols, and effective outreach and communication were additional critical goals of these field validation tests. The program included geologic pilot tests located in Utah, New Mexico, Texas, and a region-wide terrestrial analysis. Each geologic sequestration test site was intended to include injection of a minimum of ~75,000 tons/year CO{sub 2}, with minimum injection duration of one year. These pilots represent medium- scale validation tests in sinks that host capacity for possible larger-scale sequestration operations in the future. These validation tests also demonstrated a broad variety of carbon sink targets and multiple value-added benefits, including testing of enhanced oil recovery and sequestration, enhanced coalbed methane production and a geologic sequestration test combined with a local terrestrial sequestration pilot. A regional terrestrial sequestration demonstration was also carried out, with a focus on improved terrestrial MVA methods and reporting approaches specific for the Southwest region.

  2. CERES progress report: Phases 1 and 2

    SciTech Connect (OSTI)

    Dannevik, W.P.; Ambrosiano, J.; Kercher, J.; Penner, J.E.; Emanuel, W.

    1994-05-27

    The CERES project represents a long-term commitment of LLNL`s Global Climate Research Division to the EPA. The goal is to build an Earth System Model (ESM) with the ability in the near future to assist EPA in carrying out its responsibilities in the environmental policy and assessment arena, with particular emphasis on the terrestrial ecosystem components of the Earth system. There are two complementary aspects of the CERES development plan. The first is to provide a computational framework and modeling infrastructure for ESM development. The goal is to create an ``open architecture`` enabling submodels from different research groups studying terrestrial ecosystems to become part of a fully-coupled model of the Earth`s climate system. The second goal is to contribute fundamentally to understanding of the terrestrial component of the Earth system by developing advanced models. During this first phase of the CERES project, these two activities have been somewhat separate; the software engineering and framework building activity having been done in parallel with terrestrial model development. These two activities are merging as the framework becomes more mature, with robust software tools, and with a growing complement of tuned and benchmarked submodels and as the ecosystem models become fully incorporated into the ESM modeling framework. Two appendices contain the following papers: (1) ``Research Recommendations to the EPA in Support of Earth System Modeling Activities,`` LLNL CERES project report; and (2) ``Progress Report on Terrestrial Model Development: Research in Support of the CERES Earth System Modeling Project,`` LLNL CERES project report.

  3. Safety Analysis Report Update Program: Overview and Phase 1 implementation

    SciTech Connect (OSTI)

    Not Available

    1991-08-01

    During FY 1989, the DOE-Oak Ridge Operations (ORO) office formed joint Operating Contractor/DOE-ORO organizations to address safety analysis related issues. The Safety Analysis Report Working Group (SARWG) took on the task of developing a strategy to address the issue of updating SARs to today's standards. The resulting SAR Update Program was approved by the Safety Analysis Report Management Group (SARMG) and on November 6, 1989, was accepted by the senior management of DOE-ORO, and its operating contractors, including Martin Marietta Energy Systems, Inc. This SAR Update Program consists of five phases: Phase 0 -- continued operation evaluations; Phase 1 -- hazard classification and qualitative analysis; Phase 1A -- updated operational safety requirements; Phase 2 -- quantitative accident analysis; and, Phase 3 -- complete DOE-approved SARs. 8 refs., 17 figs., 6 tabs.

  4. Anomalous compression behavior of germanium during phase transformation

    SciTech Connect (OSTI)

    Yan, Xiaozhi; Tan, Dayong; Ren, Xiangting; Yang, Wenge E-mail: duanweihe@scu.edu.cn; He, Duanwei E-mail: duanweihe@scu.edu.cn; Mao, Ho-Kwang

    2015-04-27

    In this article, we present the abnormal compression and plastic behavior of germanium during the pressure-induced cubic diamond to β-tin structure transition. Between 8.6 GPa and 13.8 GPa, in which pressure range both phases are co-existing, first softening and followed by hardening for both phases were observed via synchrotron x-ray diffraction and Raman spectroscopy. These unusual behaviors can be interpreted as the volume misfit between different phases. Following Eshelby, the strain energy density reaches the maximum in the middle of the transition zone, where the switch happens from softening to hardening. Insight into these mechanical properties during phase transformation is relevant for the understanding of plasticity and compressibility of crystal materials when different phases coexist during a phase transition.

  5. Phase plate technology for laser marking of magnetic discs

    DOE Patents [OSTI]

    Neuman, B.; Honig, J.; Hackel, L.; Dane, C.B.; Dixit, S.

    1998-10-27

    An advanced design for a phase plate enables the distribution of spots in arbitrarily shaped patterns with very high uniformity and with a continuously or near-continuously varying phase pattern. A continuous phase pattern eliminates large phase jumps typically expected in a grating that provides arbitrary shapes. Large phase jumps increase scattered light outside of the desired pattern, reduce efficiency and can make the grating difficult to manufacture. When manufacturing capabilities preclude producing a fully continuous grating, the present design can be easily adapted to minimize manufacturing errors and maintain high efficiencies. This continuous grating is significantly more efficient than previously described Dammann gratings, offers much more flexibility in generating spot patterns and is easier to manufacture and replicate than a multi-level phase grating. 3 figs.

  6. Phase plate technology for laser marking of magnetic discs

    DOE Patents [OSTI]

    Neuman, Bill; Honig, John; Hackel, Lloyd; Dane, C. Brent; Dixit, Shamasundar

    1998-01-01

    An advanced design for a phase plate enables the distribution of spots in arbitrarily shaped patterns with very high uniformity and with a continuously or near-continuously varying phase pattern. A continuous phase pattern eliminates large phase jumps typically expected in a grating that provides arbitrary shapes. Large phase jumps increase scattered light outside of the desired pattern, reduce efficiency and can make the grating difficult to manufacture. When manufacturing capabilities preclude producing a fully continuous grating, the present design can be easily adapted to minimize manufacturing errors and maintain high efficiencies. This continuous grating is significantly more efficient than previously described Dammann gratings, offers much more flexibility in generating spot patterns and is easier to manufacture and replicate than a multi-level phase grating.

  7. K Basins Sludge Treatment Project Phase 1 | Department of Energy

    Energy Savers [EERE]

    Project Phase 1 K Basins Sludge Treatment Project Phase 1 Full Document and Summary Versions are available for download PDF icon K Basins Sludge Treatment Project Phase 1 More Documents & Publications Compilation of TRA Summaries Independent Activity Report, Richland Operations Office - April 2011 Enterprise Assessments, Review of the Hanford Site Sludge Treatment Project Engineered Container Retrieval and Transfer System Preliminary Documented Safety Analysis, Revision 00 - April 2015

  8. Evaluation of Mixed-Phase Cloud Microphysics Parameterizations with the

    Office of Scientific and Technical Information (OSTI)

    NCAR Single Column Climate Model (SCAM) and ARM Observations (Technical Report) | SciTech Connect SciTech Connect Search Results Technical Report: Evaluation of Mixed-Phase Cloud Microphysics Parameterizations with the NCAR Single Column Climate Model (SCAM) and ARM Observations Citation Details In-Document Search Title: Evaluation of Mixed-Phase Cloud Microphysics Parameterizations with the NCAR Single Column Climate Model (SCAM) and ARM Observations Mixed-phase stratus clouds are

  9. General properties of the gravitational wave spectrum from phase

    Office of Scientific and Technical Information (OSTI)

    transitions (Journal Article) | SciTech Connect General properties of the gravitational wave spectrum from phase transitions Citation Details In-Document Search Title: General properties of the gravitational wave spectrum from phase transitions In this paper we discuss some general aspects of the gravitational wave background arising from postinflationary short-lasting cosmological events such as phase transitions. We concentrate on the physics which determines the shape and the peak

  10. Federal ESPC Process Phase 1: Acquisition Planning | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    1: Acquisition Planning Federal ESPC Process Phase 1: Acquisition Planning During phase 1 of the energy savings performance contract (ESPC) process, the agency contacts a Federal Energy Management Program (FEMP) federal project executive who helps educate the agency about procurement steps that are unique to ESPCs. Phase 1 at a Glance Step 1: Agency Contacts a Federal Project Executive Step 2: Agency Considers Procurement Requirements Step 3: Agency Develops a Plan of Action for the Project

  11. Microstructure, Phase Formation, and Stress of Reactively-Deposited Metal

    Office of Scientific and Technical Information (OSTI)

    Hydride Thin Films (Technical Report) | SciTech Connect Microstructure, Phase Formation, and Stress of Reactively-Deposited Metal Hydride Thin Films Citation Details In-Document Search Title: Microstructure, Phase Formation, and Stress of Reactively-Deposited Metal Hydride Thin Films This document summarizes research of reactively deposited metal hydride thin films and their properties. Reactive deposition processes are of interest, because desired stoichiometric phases are created in a

  12. Modeling non-equilibrium phase transitions in isentropically compressed Bi

    Office of Scientific and Technical Information (OSTI)

    (Conference) | SciTech Connect Conference: Modeling non-equilibrium phase transitions in isentropically compressed Bi Citation Details In-Document Search Title: Modeling non-equilibrium phase transitions in isentropically compressed Bi We report here on modeling of non-equilibrium phase transitions in Bi samples isentropically compressed to 120 GPa by a ramped drive, which is produced using the Janus laser. In the experiments, the Bi samples are attached to windows of LiF or sapphire, and

  13. Two Phase Transitions Make a High-Temperature Superconductor

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Two Phase Transitions Make a High-Temperature Superconductor Two Phase Transitions Make a High-Temperature Superconductor Print Wednesday, 30 November 2011 00:00 Superconductivity-conceptually remarkable and practically revolutionary-is a quantum phenomenon in which bound electron pairs flow through a material in perfect synchrony, without friction. Conventional superconducting materials reach this state via a single thermal phase transition at a critical temperature (Tc). It was generally

  14. Solid Phase Characterization of Solids Recovered from Failed Sluicer Arm

    Office of Scientific and Technical Information (OSTI)

    (Technical Report) | SciTech Connect Solid Phase Characterization of Solids Recovered from Failed Sluicer Arm Citation Details In-Document Search Title: Solid Phase Characterization of Solids Recovered from Failed Sluicer Arm The Enclosure to this memo discusses the solid phase characterization of a solid sample that was retrieved from the single-shell Tank 241-C-111 extended reach sluicer #2. This sluicer, removed from riser #3 on September 25, 2014, was found to have approximately 0.4

  15. Coherent optical monolithic phased-array antenna steering system

    DOE Patents [OSTI]

    Hietala, Vincent M.; Kravitz, Stanley H.; Vawter, Gregory A.

    1994-01-01

    An optical-based RF beam steering system for phased-array antennas comprising a photonic integrated circuit (PIC). The system is based on optical heterodyning employed to produce microwave phase shifting by a monolithic PIC constructed entirely of passive components. Microwave power and control signal distribution to the antenna is accomplished by optical fiber, permitting physical separation of the PIC and its control functions from the antenna. The system reduces size, weight, complexity, and cost of phased-array antenna systems.

  16. Nonaqueous-Phase Liquid Characterization and Post-Remediation Verification

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Sampling | Department of Energy Nonaqueous-Phase Liquid Characterization and Post-Remediation Verification Sampling Nonaqueous-Phase Liquid Characterization and Post-Remediation Verification Sampling Proceedings of the Fourth International Conference on Remediation of Chlorinated and Recalcitrant Compounds. May 2004, Monterey, California. Charles Tabor, Randall Juhlin, Paul Darr, Julian Caballero, Joseph Daniel, David Ingle PDF icon Nonaqueous-Phase Liquid Characterization and

  17. Funding Phases for Small Business Innovation Research and Small Business

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Technology Transfer Programs | Department of Energy Phases for Small Business Innovation Research and Small Business Technology Transfer Programs Funding Phases for Small Business Innovation Research and Small Business Technology Transfer Programs The Office of Energy Efficiency and Renewable Energy's Small Business Innovation Research (SBIR) and Small Business Technology Transfer (STTR) grants follow a funding ladder similar to that of clean energy technology investors. Phase I funding

  18. 2-D weighted least-squares phase unwrapping

    DOE Patents [OSTI]

    Ghiglia, D.C.; Romero, L.A.

    1995-06-13

    Weighted values of interferometric signals are unwrapped by determining the least squares solution of phase unwrapping for unweighted values of the interferometric signals; and then determining the least squares solution of phase unwrapping for weighted values of the interferometric signals by preconditioned conjugate gradient methods using the unweighted solutions as preconditioning values. An output is provided that is representative of the least squares solution of phase unwrapping for weighted values of the interferometric signals. 6 figs.

  19. 2-D weighted least-squares phase unwrapping

    DOE Patents [OSTI]

    Ghiglia, Dennis C.; Romero, Louis A.

    1995-01-01

    Weighted values of interferometric signals are unwrapped by determining the least squares solution of phase unwrapping for unweighted values of the interferometric signals; and then determining the least squares solution of phase unwrapping for weighted values of the interferometric signals by preconditioned conjugate gradient methods using the unweighted solutions as preconditioning values. An output is provided that is representative of the least squares solution of phase unwrapping for weighted values of the interferometric signals.

  20. Cationic Phospholipids Forming Cubic Phases: Lipoplex Structure and

    Office of Scientific and Technical Information (OSTI)

    Transfection Efficiency (Journal Article) | SciTech Connect Cationic Phospholipids Forming Cubic Phases: Lipoplex Structure and Transfection Efficiency Citation Details In-Document Search Title: Cationic Phospholipids Forming Cubic Phases: Lipoplex Structure and Transfection Efficiency The transfection activity and the phase behavior of two novel cationic O-alkyl-phosphatidylcholines, 1,2-dioleoyl-sn-glycero-3-hexylphosphocholine (C6-DOPC) and 1,2-dierucoyl-sn-glycero-3-ethylphosphocholine

  1. Confined martensitic phase transformation kinetics and lattice dynamics in

    Office of Scientific and Technical Information (OSTI)

    Ni-Co-Fe-Ga shape memory alloys (Journal Article) | SciTech Connect Confined martensitic phase transformation kinetics and lattice dynamics in Ni-Co-Fe-Ga shape memory alloys Citation Details In-Document Search Title: Confined martensitic phase transformation kinetics and lattice dynamics in Ni-Co-Fe-Ga shape memory alloys Here we describe insights into the phase transformation kinetics and lattice dynamics associated with the newly discovered confined martensitic transformation, which are

  2. Cubic Phases in Phosphatidylcholine-Cholesterol Mixtures: Cholesterol as

    Office of Scientific and Technical Information (OSTI)

    Membrane 'Fusogen' (Journal Article) | SciTech Connect Cubic Phases in Phosphatidylcholine-Cholesterol Mixtures: Cholesterol as Membrane 'Fusogen' Citation Details In-Document Search Title: Cubic Phases in Phosphatidylcholine-Cholesterol Mixtures: Cholesterol as Membrane 'Fusogen' X-ray diffraction reveals that mixtures of some unsaturated phosphatidylcholines (PCs) with cholesterol (Chol) readily form inverted bicontinuous cubic phases that are stable under physiological conditions. This

  3. Controlling phase separation of binary Bose-Einstein condensates via

    Office of Scientific and Technical Information (OSTI)

    mixed-spin-channel Feshbach resonance (Journal Article) | SciTech Connect Controlling phase separation of binary Bose-Einstein condensates via mixed-spin-channel Feshbach resonance Citation Details In-Document Search Title: Controlling phase separation of binary Bose-Einstein condensates via mixed-spin-channel Feshbach resonance We investigate controlled phase separation of a binary Bose-Einstein condensate in the proximity of a mixed-spin-channel Feshbach resonance in the |F=1,m{sub

  4. Gravitational waves from global second order phase transitions

    SciTech Connect (OSTI)

    Jr, John T. Giblin; Price, Larry R.; Siemens, Xavier; Vlcek, Brian E-mail: larryp@caltech.edu E-mail: bvlcek@uwm.edu

    2012-11-01

    Global second-order phase transitions are expected to produce scale-invariant gravitational wave spectra. In this manuscript we explore the dynamics of a symmetry-breaking phase transition using lattice simulations. We explicitly calculate the stochastic gravitational wave background produced during the transition and subsequent self-ordering phase. We comment on this signal as it compares to the scale-invariant spectrum produced during inflation.

  5. Etched-multilayer phase shifting masks for EUV lithography

    DOE Patents [OSTI]

    Chapman, Henry N.; Taylor, John S.

    2005-04-05

    A method is disclosed for the implementation of phase shifting masks for EUV lithography. The method involves directly etching material away from the multilayer coating of the mask, to cause a refractive phase shift in the mask. By etching into the multilayer (for example, by reactive ion etching), rather than depositing extra material on the top of the multilayer, there will be minimal absorption loss associated with the phase shift.

  6. Opportunities to Apply Phase Change Materials to Building Enclosures

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Webinar | Department of Energy Opportunities to Apply Phase Change Materials to Building Enclosures Webinar Opportunities to Apply Phase Change Materials to Building Enclosures Webinar Slides from the Building America webinar on November 11, 2011. PDF icon webinar_pcm_enclosures_20111111.pdf More Documents & Publications Building America Webinar: Opportunities to Apply Phase Change Materials to Building Enclosures 2011 Residential Energy Efficiency Technical Update Meeting Summary

  7. DOE Commercial Building Energy Asset Score: Software Development for Phase

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    II Building Types | Department of Energy Score: Software Development for Phase II Building Types DOE Commercial Building Energy Asset Score: Software Development for Phase II Building Types DOE Commercial Building Energy Asset Score: Software Development for Phase II Building Types PDF icon asset_score_assumptions_july_2013.pdf More Documents & Publications Weekend/Weekday Ozone Study in the South Coast Air Basin Users Perspective on Advanced Fuel Cell Bus Technology In Plane

  8. Discovery of a metastable Al20Sm4 phase

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ye, Z.; Zhang, F.; Sun, Y.; Mendelev, M. I.; Ott, R. T.; Park, E.; Besser, M. F.; Kramer, M. J.; Ding, Z.; Wang, C. -Z.; et al

    2015-03-09

    In this study, we present an efficient genetic algorithm, integrated with experimental diffraction data, to solve a nanoscale metastable Al20Sm4 phase that evolves during crystallization of an amorphous magnetron sputtered Al90Sm10 alloy. The excellent match between calculated and experimental X-ray diffraction patterns confirms an accurate description of this metastable phase. Molecular dynamic simulations of crystal growth from the liquid phase predict the formation of disordered defects in the devitrified crystal.

  9. Computer Simulations Indicate Calcium Carbonate Has a Dense Liquid Phase

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Computer Simulations Indicate Calcium Carbonate Has a Dense Liquid Phase Computer Simulations Indicate Calcium Carbonate Has a Dense Liquid Phase Berkeley Lab research could help scientists predict how carbon is stored underground August 22, 2013 Dan Krotz 510-486-4019 dakrotz@lbl.gov red2.jpg Artistic rendition of liquid-liquid separation in a supersaturated calcium carbonate solution. New research suggests that a dense liquid phase (shown in red in the background and in full atomistic detail

  10. Surface plasmon sensing of gas phase contaminants using optical fiber.

    Office of Scientific and Technical Information (OSTI)

    (Technical Report) | SciTech Connect Surface plasmon sensing of gas phase contaminants using optical fiber. Citation Details In-Document Search Title: Surface plasmon sensing of gas phase contaminants using optical fiber. Fiber-optic gas phase surface plasmon resonance (SPR) detection of several contaminant gases of interest to state-of-health monitoring in high-consequence sealed systems has been demonstrated. These contaminant gases include H{sub 2}, H{sub 2}S, and moisture using a

  11. Building America Webinar: Opportunities to Apply Phase Change Materials to

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Building Enclosures | Department of Energy to Apply Phase Change Materials to Building Enclosures Building America Webinar: Opportunities to Apply Phase Change Materials to Building Enclosures This webinar, presented by research team Fraunhofer Center for Sustainable Energy Systems (CSE), reviewed basic physical characteristics and thermal properties of phase change materials (PCMs) and provided guidance on how to effectively apply PCMs in buildings in the United States. File

  12. Quantum phase transition of condensed bosons in optical lattices

    SciTech Connect (OSTI)

    Liang Junjun; Liang, J.-Q.; Liu, W.-M.

    2003-10-01

    In this paper we study the superfluid-Mott-insulator phase transition of ultracold dilute gas of bosonic atoms in an optical lattice by means of Green function method and Bogliubov transformation as well. The superfluid-Mott-insulator phase transition condition is determined by the energy-band structure with an obvious interpretation of the transition mechanism. Moreover the superfluid phase is explained explicitly from the energy spectrum derived in terms of Bogliubov approach.

  13. Liquid-Phase Deposition of Silicon Nanocrystal Films - Energy...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Liquid-Phase Deposition of Silicon Nanocrystal Films University of Minnesota DOE Grant Recipients Contact GRANT About This Technology Technology Marketing Summary Silicon ...

  14. A High Resolution Hydrometer Phase Classifier Based on Analysis...

    Office of Scientific and Technical Information (OSTI)

    Satellite-based retrievals of cloudmore phase in high latitudes are often hindered by the highly reflecting ice-covered ground and persistent temperature inversions. From the ...

  15. Evaluation of Mixed-Phase Cloud Microphysics Parameterizations...

    Office of Scientific and Technical Information (OSTI)

    the partitioning of condensed water into liquid droplets and ice crystals in these Arctic clouds, which affect modeled cloud phase, cloud lifetime and radiative properties. ...

  16. Inverse Pm3(-)n cubic micellar lyotropic phases from zwitterionic...

    Office of Scientific and Technical Information (OSTI)

    Inverse Pm3(-)n cubic micellar lyotropic phases from zwitterionic triazolium gemini surfactants Citation Details In-Document Search Title: Inverse Pm3(-)n cubic micellar lyotropic...

  17. Accident Investigation Report Phase II | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    On March 4, 2014, an Accident Investigation Board (the Board) was appointed by Matthew ... appointed an Accident Investigation Board to complete the investigation (Phase 2). ...

  18. Attachment 1: DOE Phased Retirement Implementation Plan Purpose...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Plan Purpose: Phased retirement is designed to assist agencies with knowledge management and continuity of operations in the short term. Although the main purpose is to ...

  19. Phase 1 of the Advanced Collaborative Emissions Study (ACES)...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    1 of the Advanced Collaborative Emissions Study (ACES): Highlights of Project Finding Phase 1 of the Advanced Collaborative Emissions Study (ACES): Highlights of Project Finding ...

  20. Equations of state and phase diagrams of hydrogen isotopes

    SciTech Connect (OSTI)

    Urlin, V. D.

    2013-11-15

    A new form of the semiempirical equation of state proposed for the liquid phase of hydrogen isotopes is based on the assumption that its structure is formed by cells some of which contain hydrogen molecules and others contain hydrogen atoms. The values of parameters in the equations of state of the solid (molecular and atomic) phases as well as of the liquid phase of hydrogen isotopes (protium and deuterium) are determined. Phase diagrams, shock adiabats, isentropes, isotherms, and the electrical conductivity of compressed hydrogen are calculated. Comparison of the results of calculations with available experimental data in a wide pressure range demonstrates satisfactory coincidence.

  1. Metallic phase change material thermal storage for Dish Stirling...

    Office of Scientific and Technical Information (OSTI)

    Citation Details In-Document Search Title: Metallic phase ... This paper reports current findings in the area of ... Type: Accepted Manuscript Journal Name: Energy Procedia ...

  2. Sandia Energy - SPIDERS Completed Its Phase 1 Operational Demonstratio...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Grid Integration News & Events Research & Capabilities SMART Grid Energy Assurance Microgrid SPIDERS Completed Its Phase 1 Operational Demonstration in Late January Previous...

  3. Exploiting large non-isomorphous differences for phase determination...

    Office of Scientific and Technical Information (OSTI)

    complex Citation Details In-Document Search Title: Exploiting large non-isomorphous differences for phase determination of a G-segment invertase-DNA complex Authors: ...

  4. Phase I - Resource Procurement and Identification | Open Energy...

    Open Energy Info (EERE)

    time of reporting and further indicate the presence of a commercially viable geothermal reservoir. 2. Transmission Development Criteria For a project to be considered a Phase I...

  5. Building America Webinar: Opportunities to Apply Phase Change...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Building America Webinar: Opportunities to Apply Phase Change Materials to Building Enclosures This webinar, presented by research team Fraunhofer Center for Sustainable Energy ...

  6. Final Report: Enhanced Geothermal Systems Technology Phase II...

    Open Energy Info (EERE)

    Systems Technology Phase II: Animas Valley, New Mexico Authors R.A. Cunniff and R.L. Bowers Published Lightning Dock Geothermal, Inc. Technical Report, 2003 DOI Not...

  7. Two Phase Transitions Make a High-Temperature Superconductor

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Two Phase Transitions Make a High-Temperature Superconductor Print Superconductivity-conceptually remarkable and practically revolutionary-is a quantum phenomenon in which bound...

  8. Digital optical phase conjugation of fluorescence in turbid tissue

    SciTech Connect (OSTI)

    Vellekoop, Ivo M.; Cui Meng; Yang Changhuei

    2012-08-20

    We demonstrate a method for phase conjugating fluorescence. Our method, called reference free digital optical phase conjugation, can conjugate extremely weak, incoherent optical signals. It was used to phase conjugate fluorescent light originating from a bead covered with 0.5 mm of light-scattering tissue. The phase conjugated beam refocuses onto the bead and causes a local increase of over two orders of magnitude in the light intensity. Potential applications are in imaging, optical trapping, and targeted photochemical activation inside turbid tissue.

  9. Direct Spectroscopic Evidence for Phase Competition between the...

    Office of Scientific and Technical Information (OSTI)

    Direct Spectroscopic Evidence for Phase Competition between the Pseudogap and ... Visit OSTI to utilize additional information resources in energy science and technology. A ...

  10. Non-equilibrium chemical partitioning calculation for phase transforma...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and time dependent phase selection. The calculation programs were developed in C++ and fortran. In this program, we will integrate the existing calculation programs. Research area:...

  11. Synthesis and Engineering Materials Properties of Fluid Phase...

    Office of Scientific and Technical Information (OSTI)

    Chemical Hydrogen Storage Materials for Automotive Applications Citation Details In-Document Search Title: Synthesis and Engineering Materials Properties of Fluid Phase Chemical ...

  12. Phase development in conventional and active belite cement pastes...

    Office of Scientific and Technical Information (OSTI)

    and chemical constraints Citation Details In-Document Search Title: Phase development in conventional and active belite cement pastes by Rietveld analysis and chemical ...

  13. Used Fuel Disposition Campaign Phase I Ring Compression Testing...

    Energy Savers [EERE]

    Phase I Ring Compression Testing of High Burnup Cladding Used Fuel Disposition Campaign ... of the technical basis for extended storage and transportation of high-burnup fuel. ...

  14. Discrete phase space based on finite fields (Journal Article...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Discrete phase space based on finite fields Citation Details In-Document ... OSTI Identifier: 20649890 Resource Type: Journal Article Resource Relation: Journal Name: ...

  15. Integrated thermal treatment system sudy: Phase 2, Results

    SciTech Connect (OSTI)

    Feizollahi, F.; Quapp, W.J.

    1995-08-01

    This report presents the second phase of a study on thermal treatment technologies. The study consists of a systematic assessment of nineteen thermal treatment alternatives for the contact-handled mixed low-level waste (MLLW) currently stored in the US Department of Energy complex. The treatment alternatives consist of widely varying technologies for safely destroying the hazardous organic components, reducing the volume, and preparing for final disposal of the MLLW. The alternatives considered in Phase 2 were innovative thermal treatments with nine types of primary processing units. Other variations in the study examined the effect of combustion gas, air pollution control system design, and stabilization technology for the treatment residues. The Phase 1 study, the results of which have been published as an interim report, examined ten initial thermal treatment alternatives. The Phase 2 systems were evaluated in essentially the same manner as the Phase 2 systems. The assumptions and methods were the same as for the Phase 1 study. The quantities, and physical and chemical compositions, of the input waste used in he Phase 2 systems differ from those in the Phase 1 systems, which were based on a preliminary waste input database developed at the onset of the Integrated Thermal Treatment System study. The inventory database used in the Phase 2 study incorporates the latest US Department of Energy information. All systems, both primary treatment systems and subsystem inputs, have now been evaluated using the same waste input (2,927 lb/hr).

  16. Selective gas adsorption and unique phase transition properties...

    Office of Scientific and Technical Information (OSTI)

    Selective gas adsorption and unique phase transition properties in a stable magnesium metal-organic framework constructed from infinite metal chains Citation Details In-Document...

  17. Phase 3 Developments Investments LLC | Open Energy Information

    Open Energy Info (EERE)

    Product: provides services to agricultural customers related to renewable energy and bio-based products. References: Phase 3 Developments & Investments LLC1 This article is a...

  18. A Reversible Crystallinity-Preserving Phase Transition in Metal...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Reversible Crystallinity-Preserving Phase Transition in Metal-Organic Frameworks: Discovery, Mechanistic Studies, and Potential Applications Previous Next List Liu, Dahuan; Liu,...

  19. Zero interface tensions at the deconfining phase transition for...

    Office of Scientific and Technical Information (OSTI)

    gauge theory Citation Details In-Document Search Title: Zero interface tensions at the deconfining phase transition for a matrix model of a SU() gauge theory Authors: ...

  20. The application of taylor weighting, digital phase shifters,...

    Office of Scientific and Technical Information (OSTI)

    Language: English Subject: 47 OTHER INSTRUMENTATION; ANTENNAS; APERTURES; DESIGN; PERFORMANCE; RADAR; DATA TRANSMISSION Phased array antennas.; Array processors.; Antennas.-Testing...