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Sample records for napl non-aqueous phase

  1. Pore-scale analysis of solubilization and mobilization of trapped NAPL blobs in porous media 

    E-Print Network [OSTI]

    Yoon, Sun Hee

    2009-06-02

    NAPL (non-aqueous phase liquid) blob mobilization and solubilization models were developed to predict residual NAPL fate and describe flow dynamics of various displacing phases (water and surfactant foam). The models were ...

  2. Phase Stability of Multicomponent NAPLs Containing PAHs

    E-Print Network [OSTI]

    Peters, Catherine A.

    of a contaminant is dependent on its phase state. For solid phase contaminants in contact with water, the maximum aromatic hydrocarbons (PAHs), most of which are solids in pure form at ambient temperatures. Because any of contaminants such as coal tars. NAPL/aqueous phase equilibrium studies were conducted to demonstrate

  3. A Comparative Study of Solid and Liquid Non-Aqueous Phases for the Biodegradation of

    E-Print Network [OSTI]

    Daugulis, Andrew J.

    : gas treatment; hexane; liquid solvents; mass transfer limitations; solid polymers; two Groenestijn and Hesselink, 1993). Biological gas treatment methods are based on the natural abilityARTICLE A Comparative Study of Solid and Liquid Non-Aqueous Phases for the Biodegradation of Hexane

  4. Smouldering Combustion of Organic Liquids in Porous Media for Remediating NAPL-contaminated Soils 

    E-Print Network [OSTI]

    Pironi, Paolo

    2010-01-01

    This research investigated the potential of smouldering combustion to be employed as a remediation approach for soil contaminated by non-aqueous phase liquids (NAPLs). Small-scale (~15 cm), proof-of-concept experiments ...

  5. Method and device for removing a non-aqueous phase liquid from a groundwater system

    DOE Patents [OSTI]

    Looney, Brian B. (Aiken, SC); Rossabi, Joseph (Aiken, SC); Riha, Brian D. (Augusta, GA)

    2002-01-01

    A device for removing a non-aqueous phase liquid from a groundwater system includes a generally cylindrical push-rod defining an internal recess therein. The push-rod includes first and second end portions and an external liquid collection surface. A liquid collection member is detachably connected to the push-rod at one of the first and second end portions thereof. The method of the present invention for removing a non-aqueous phase liquid from a contaminated groundwater system includes providing a lance including an external hydrophobic liquid collection surface, an internal recess, and a collection chamber at the bottom end thereof. The lance is extended into the groundwater system such that the top end thereof remains above the ground surface. The liquid is then allowed to collect on the liquid collection surface, and flow downwardly by gravity into the collection chamber to be pumped upwardly through the internal recess in the lance.

  6. Numerical simulations of radon as an in situ partitioning tracer for quantifying NAPL

    E-Print Network [OSTI]

    Semprini, Lewis

    Numerical simulations of radon as an in situ partitioning tracer for quantifying NAPL contamination­pull partitioning tracer tests using radon-222 to quantify non- aqueous phase liquid contamination. J. Contam. Hydrol. 58, 129­146] of push­pull tests using radon as a naturally occurring partitioning tracer

  7. Refinement of the Kansas City Plant site conceptual model with respect to dense non-aqueous phase liquids (DNAPL)

    SciTech Connect (OSTI)

    Korte, N.E.; Hall, S.C.; Baker, J.L.

    1995-10-01

    This document presents a refinement of the site conceptual model with respect to dense non-aqueous phase liquid (DNAPL) at the US Department of Energy Kansas City Plant (KCP). This refinement was prompted by a review of the literature and the results of a limited study that was conducted to evaluate whether pools of DNAPL were present in contaminated locations at the KCP. The field study relied on the micropurge method of sample collection. This method has been demonstrated as a successful approach for obtaining discrete samples within a limited aquifer zone. Samples were collected at five locations across 5-ft well screens located at the base of the alluvial aquifer at the KCP. The hypothesis was that if pools of DNAPL were present, the dissolved concentration would increase with depth. Four wells with highly contaminated groundwater were selected for the test. Three of the wells were located in areas where DNAPL was suspected, and one where no DNAPL was believed to be present. The results demonstrated no discernible pattern with depth for the four wells tested. A review of the data in light of the available technical literature suggests that the fine-grained nature of the aquifer materials precludes the formation of pools. Instead, DNAPL is trapped as discontinuous ganglia that are probably widespread throughout the aquifer. The discontinuous nature of the DNAPL distribution prevents the collection of groundwater samples with concentrations approaching saturation. Furthermore, the results indicate that attempts to remediate the aquifer with conventional approaches will not result in restoration to pristine conditions because the tortuous groundwater flow paths will inhibit the efficiency of fluid-flow-based treatments.

  8. Non-aqueous electrolyte for lithium-ion battery

    DOE Patents [OSTI]

    Zhang, Lu; Zhang, Zhengcheng; Amine, Khalil

    2015-12-22

    An electrolyte including an alkali metal salt; a polar aprotic solvent; and a triazinane trione; wherein the electrolyte is substantially non-aqueous.

  9. Cross borehole induced polarization to detect subsurface NAPL at the Savannah River Site, South Carolina

    E-Print Network [OSTI]

    Lambert, Michael B. (Michael Brian), 1980-

    2003-01-01

    Spectral induced polarization measurements were acquired in six cross-borehole panels within four boreholes at the Savannah River Site. The investigation was performed to delineate the presence of dense non-aqueous phase ...

  10. Phenyl boron-based compounds as anion receptors for non-aqueous battery electrolytes

    DOE Patents [OSTI]

    Lee, Hung Sui (East Setauket, NY); Yang, Xiao-Qing (Port Jefferson Station, NY); McBreen, James (Bellport, NY); Sun, Xuehui (Middle Island, NY)

    2002-01-01

    Novel fluorinated boronate-based compounds which act as anion receptors in non-aqueous battery electrolytes are provided. When added to non-aqueous battery electrolytes, the fluorinated boronate-based compounds of the invention enhance ionic conductivity and cation transference number of non-aqueous electrolytes. The fluorinated boronate-based anion receptors include different fluorinated alkyl and aryl groups.

  11. Ribbon NAPL sampler. Innovative Technology Summary Report

    SciTech Connect (OSTI)

    None

    2000-04-01

    The FLUTE Hydrophobic Flexible Membrane is a sampling device that provides detailed delineation of Dense Nonaqueous Phase Liquids (DNAPL) in a borehole. It is deployed via a reusable nylon liner, with a hydrophobic ribbon impregnated with dye, that when converted into a borehole creates a tight contact with the walls of the borehole. When deployed, the ribbon will absorb the DNAPL that is in contact with the membrane causing a color change in the dye. Upon removal, the membrane is turned inside out and the ribbon is retrieved into the membrane. The ribbon is then removed and examined. The presence of DNAPL is indicated by brilliant red marks on the hydrophobic ribbon. Sections of ribbon can also be sent for laboratory analysis to identify the specific NAPL compounds that are present.

  12. Electric field induced birefringence in non-aqueous dispersions of mineral nanorods

    E-Print Network [OSTI]

    Alexis de la Cotte; Pascal Merzeau; Jong Wook Kim; Khalid Lahlil; Jean-Pierre Boilot; Thierry Gacoin; Eric Grelet

    2015-07-07

    Lanthanum phosphate (LaPO4) nanorods dispersed in the non-aqueous solvent of ethylene glycol form a system exhibiting large intrinsic birefringence, high colloidal stability and the ability to self-organize into liquid crystalline phases. In order to probe the electro-optical response of these rod dispersions we study here the electric-field-induced birefringence, also called Kerr effect, for a concentrated isotropic liquid state with an in-plane a.c. sinusoidal electric field, in conditions of directly applied (electrodes in contact with the sample) or externally applied (electrodes outside the sample cell) fields. Performing an analysis of the electric polarizability of our rod-like particles in the framework of Maxwell-Wagner-OKonski theory, we account quantitatively for the coupling between the induced steady-state birefringence and the electric field as a function of the voltage frequency for both sample geometries. The switching time of this non-aqueous transparent system has been measured, and combined with its high Kerr coefficients and its features of optically isotropic offstate and athermal phase behavior, this represents a promising proof-of-concept for the integration of anisotropic nanoparticle suspensions into a new generation of electro-optical devices.

  13. Non-aqueous electrolytes for lithium ion batteries

    DOE Patents [OSTI]

    Chen, Zonghai; Amine, Khalil

    2015-11-12

    The present invention is generally related to electrolytes containing anion receptor additives to enhance the power capability of lithium-ion batteries. The anion receptor of the present invention is a Lewis acid that can help to dissolve LiF in the passivation films of lithium-ion batteries. Accordingly, one aspect the invention provides electrolytes comprising a lithium salt; a polar aprotic solvent; and an anion receptor additive; and wherein the electrolyte solution is substantially non-aqueous. Further there are provided electrochemical devices employing the electrolyte and methods of making the electrolyte.

  14. Shear thickening in electrically stabilized non-aqueous colloidal suspensions

    E-Print Network [OSTI]

    Joachim Kaldasch; Bernhard Senge; Jozua Laven

    2012-07-11

    The authors previously introduced an activation model for the onset of shear thickening in electrically stabilized colloidal suspensions. It predicts that shear thickening occurs, when particles arranged along the compression axis in a sheared suspension do overcome the electrostatic repulsion at a critical shear stress, and are captured in the primary minimum of the DLVO interaction potential. A comparison with an experimental investigation on non-aqueous silica suspensions, carried out by Maranzano and Wagner, is performed. For particle systems that fall into the applicability range of the theory, a good coincidence between the experimental data and the model predictions can be found.

  15. NAPL Calculator - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMass map shines light on77 PAGEMissionStressMoveMuncrief Ames019NAPL Calculator

  16. Artists, Patrons, and Trust in Seventeenth-Century Naples: The Case of the Certosa di San Martino

    E-Print Network [OSTI]

    Napoli, J. Nicholas

    2012-01-01

    in Naples? ” In Good Government in Spanish Naples, edited byNaples? ,” in Good Government in Spanish Naples, edited bySpanish rule in Naples, and the opportunity for a changed government

  17. Ionic conductivity and exchange current density of non-aqueous lithium polysulfide electrolyte

    E-Print Network [OSTI]

    Pan, Menghsuan Sam

    2015-01-01

    Lithium-polysulfide flow batteries, which utilize the high solubility of lithium polysulfide in non-aqueous electrolytes to enable flowable electrodes, have high theoretical energy density and low raw materials cost. To ...

  18. From Propaganda to Science: Looking at the World of Academies in Early Seventeenth-century Naples

    E-Print Network [OSTI]

    Gianfrancesco, Lorenza

    2012-01-01

    Reale per Costantino Vitale, 1599. Imperiale, Giovanni.Elegia (Naples: Carlino & Vitale, 1608). For Sarrocchi’sdate in luce (Naples: Vitale, 1599). See Rimas De Lupercio I

  19. Secondary imbibition in NAPL-invaded mixed-wet sediments

    E-Print Network [OSTI]

    Patzek, Tadeusz W.

    Secondary imbibition in NAPL-invaded mixed-wet sediments Ahmed Al-Futaisia,b , Tad W. Patzekb to study the spontaneous and forced secondary imbibition of a NAPL-invaded sediment, as in the displacement-wet sediment, i.e., the receding contact angles are very small. However, depending on the surface mineralogy

  20. Naples, Maine: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History ViewMayo, Maryland:NPI Ventures Ltd Jump to: navigation,Naples, Maine: Energy Resources Jump to:

  1. A Non-Aqueous Reduction Process for Purifying 153Gd Produced in Natural Europium Targets

    SciTech Connect (OSTI)

    Johnsen, Amanda M.; Soderquist, Chuck Z.; McNamara, Bruce K.; Fisher, Darrell R.

    2013-08-01

    Gadolinium-153 is a low-energy gamma-emitter used in nuclear medicine imaging quality assurance. Produced in nuclear reactors using natural Eu2O3 targets, 153Gd is radiochemically separated from europium isotopes by europium reduction. However, conventional aqueous europium reduction produces hydrogen gas, a flammability hazard in radiological hot cells. We altered the traditional reduction method, using methanol as the process solvent to nearly eliminate hydrogen gas production. This new, non-aqueous reduction process demonstrates greater than 98% europium removal and gadolinium yields of 90%.

  2. Northeast Site Non-Aqueous Phase Liquids Interim Measures Progress Report April through June 2003

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-SessionsSouth DakotaRobbins and

  3. Northeast Site Non-Aqueous Phase Liquids Interim Measures Progress Report October through December 2002

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-SessionsSouth DakotaRobbins and700 GJO-2003-411-TAC GJO-PIN 13.5.1-1 Pinellas

  4. Northeast Site Non-Aqueous Phase Liquids Interim Measures Progress Report-January through March 2003

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-SessionsSouth DakotaRobbins and700 GJO-2003-411-TAC GJO-PIN 13.5.1-1

  5. The non-aqueous chemistry of uranium has been an active area of exploration in recent decades1,2

    E-Print Network [OSTI]

    Cai, Long

    The non-aqueous chemistry of uranium has been an active area of exploration in recent decades1 of the art of synthetic uranium chemistry should provide form to its future in catalysis, drawn from for uranium will be created in part by the quest of researchers to understand the properties and potential

  6. Shale gas and non-aqueous fracturing fluids: Opportunities and challenges for supercritical CO?

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Middleton, Richard S.; Carey, James William; Currier, Robert P.; Hyman, Jeffrey De'Haven; Kang, Qinjun; Karra, Satish; Jiménez-Martínez, Joaquín; Porter, Mark L.; Viswanathan, Hari S.

    2015-06-01

    Hydraulic fracturing of shale formations in the United States has led to a domestic energy boom. Currently, water is the only fracturing fluid regularly used in commercial shale oil and gas production. Industry and researchers are interested in non-aqueous working fluids due to their potential to increase production, reduce water requirements, and to minimize environmental impacts. Using a combination of new experimental and modeling data at multiple scales, we analyze the benefits and drawbacks of using CO? as a working fluid for shale gas production. We theorize and outline potential advantages of CO? including enhanced fracturing and fracture propagation, reductionmore »of flow-blocking mechanisms, increased desorption of methane adsorbed in organic-rich parts of the shale, and a reduction or elimination of the deep re-injection of flow-back water that has been linked to induced seismicity and other environmental concerns. We also examine likely disadvantages including costs and safety issues associated with handling large volumes of supercritical CO?. The advantages could have a significant impact over time leading to substantially increased gas production. In addition, if CO? proves to be an effective fracturing fluid, then shale gas formations could become a major utilization option for carbon sequestration.« less

  7. Highly Quantitative Electrochemical Characterization of Non-Aqueous Electrolytes & Solid Electrolyte Interphases

    SciTech Connect (OSTI)

    Sergiy V. Sazhin; Kevin L. Gering; Mason K. Harrup; Harry W. Rollins

    2012-10-01

    The methods to measure solid electrolyte interphase (SEI) electrochemical properties and SEI formation capability of non-aqueous electrolyte solutions are not adequately addressed in the literature. And yet, there is a strong demand in new electrolyte generations that promote stabilized SEIs and have an influence to resolve safety, calendar life and other limitations of Li-ion batteries. To fill this gap, in situ electrochemical approach with new descriptive criteria for highly quantitative characterization of SEI and electrolytes is proposed. These criteria are: SEI formation capacity, SEI corrosion rate, SEI maintenance rate, and SEI kinetic stability. These criteria are associated with battery parameters like irreversible capacity, self-discharge, shelf-life, power, etc. Therefore, they are especially useful for electrolyte development and standard fast screening, allowing a skillful approach to narrow down the search for the best electrolyte. The characterization protocol also allows retrieving information on interfacial resistance for SEI layers and the electrochemical window of electrolytes, the other important metrics of characterization. The method validation was done on electrolyte blends containing phosphazenes, developed at Idaho National Laboratory, as 1.2M LiPF6 [80 % EC-MEC (2:8) (v/v) + 20% Phosphazene variety] (v/v), which were targeted for safer electrolyte variations.

  8. Shale gas and non-aqueous fracturing fluids: Opportunities and challenges for supercritical CO?

    SciTech Connect (OSTI)

    Middleton, Richard S.; Carey, James William; Currier, Robert P.; Hyman, Jeffrey De'Haven; Kang, Qinjun; Karra, Satish; Jiménez-Martínez, Joaquín; Porter, Mark L.; Viswanathan, Hari S.

    2015-06-01

    Hydraulic fracturing of shale formations in the United States has led to a domestic energy boom. Currently, water is the only fracturing fluid regularly used in commercial shale oil and gas production. Industry and researchers are interested in non-aqueous working fluids due to their potential to increase production, reduce water requirements, and to minimize environmental impacts. Using a combination of new experimental and modeling data at multiple scales, we analyze the benefits and drawbacks of using CO? as a working fluid for shale gas production. We theorize and outline potential advantages of CO? including enhanced fracturing and fracture propagation, reduction of flow-blocking mechanisms, increased desorption of methane adsorbed in organic-rich parts of the shale, and a reduction or elimination of the deep re-injection of flow-back water that has been linked to induced seismicity and other environmental concerns. We also examine likely disadvantages including costs and safety issues associated with handling large volumes of supercritical CO?. The advantages could have a significant impact over time leading to substantially increased gas production. In addition, if CO? proves to be an effective fracturing fluid, then shale gas formations could become a major utilization option for carbon sequestration.

  9. EFFECT OF IMMISCIBLE LIQUID CONTAMINANTS ON P-WAVE TRANSMISSION THROUGH NATURAL AQUIFER SAMPLES

    E-Print Network [OSTI]

    Ajo-Franklin, Jonathan

    EFFECT OF IMMISCIBLE LIQUID CONTAMINANTS ON P-WAVE TRANSMISSION THROUGH NATURAL AQUIFER SAMPLES Jil the effect of non-aqueous phase liquid (NAPL) contaminants on P-wave velocity and attenuation attenuation, which may be due to lithology and/or contaminants (NAPL or gas phase). Intact core was obtained

  10. A Bayesian approach to integrate temporal data into probabilistic risk analysis of monitored NAPL remediation

    E-Print Network [OSTI]

    Bolster, Diogo

    A Bayesian approach to integrate temporal data into probabilistic risk analysis of monitored NAPL quantifying risks associated with the failure of such efforts. We conduct a probabilistic risk analysis (PRA

  11. Natural geological responses to anthropogenic alterations of the naples bay estuarine system 

    E-Print Network [OSTI]

    Fielder, Bryan Robert

    2009-05-15

    .1 Regional Geologic Setting....................................................................... 4 2.2 Environmental Setting ............................................................................. 5 2.3 Historical Anthropogenic Alterations... ............................................................... 19 4.2.2 Southern Naples Bay ............................................................... 20 4.2.3 Dollar Bay ............................................................................... 22 5. DISCUSSION...

  12. Quantitative Chromatographic Determination of Dissolved Elemental Sulfur in the Non-aqueous Electrolyte for Lithium-Sulfur Batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zheng, Dong; Yang, Xiao-Qing; Zhang, Xuran; Li, Chao; McKinnon, Meaghan E.; Sadok, Rachel G.; Qu, Deyu; Yu, Xiqian; Lee, Hung-Sui; Qu, Deyang

    2014-12-02

    A fast and reliable analytical method is reported for the quantitative determination of dissolved elemental sulfur in non-aqueous electrolytes for Li-S batteries. By using high performance liquid chromatography with a UV detector, the solubility of S in 12 different pure solvents and in 22 different electrolytes was determined. It was found that the solubility of elemental sulfur is dependent on the Lewis basicity, the polarity of solvents and the salt concentration in the electrolytes. In addition, the S content in the electrolyte recovered from a discharged Li-S battery was successfully determined by the proposed HPLC/UV method. Thus, the feasibility ofmore »the method to the online analysis for a Li-S battery is demonstrated. Interestingly, the S was found super-saturated in the electrolyte recovered from a discharged Li-S cell.« less

  13. Quantitative Chromatographic Determination of Dissolved Elemental Sulfur in the Non-aqueous Electrolyte for Lithium-Sulfur Batteries

    SciTech Connect (OSTI)

    Zheng, Dong [Univ. of Massachusetts, Boston, MA (United States). Dept. of Chemistry; Yang, Xiao-Qing [Brookhaven National Laboratory (BNL), Upton, NY (United States). Chemistry Dept.; Zhang, Xuran [Wuhan Univ. of Technology, Hubei (China); Dept. of Chemistry; Li, Chao [Univ. of Massachusetts, Boston, MA (United States). Dept. of Chemistry; McKinnon, Meaghan E. [Univ. of Massachusetts, Boston, MA (United States). Dept. of Chemistry; Sadok, Rachel G. [Univ. of Massachusetts, Boston, MA (United States). Dept. of Chemistry; Qu, Deyu [Wuhan Univ. of Technology, Hubei (China); Dept. of Chemistry; Yu, Xiqian [Brookhaven National Laboratory (BNL), Upton, NY (United States). Chemistry Dept.; Lee, Hung-Sui [Brookhaven National Laboratory (BNL), Upton, NY (United States). Chemistry Dept.; Qu, Deyang [Univ. of Massachusetts, Boston, MA (United States). Dept. of Chemistry

    2014-11-01

    A fast and reliable analytical method is reported for the quantitative determination of dissolved elemental sulfur in non-aqueous electrolytes for Li-S batteries. By using high performance liquid chromatography with a UV detector, the solubility of S in 12 different pure solvents and in 22 different electrolytes was determined. It was found that the solubility of elemental sulfur is dependent on the Lewis basicity, the polarity of solvents and the salt concentration in the electrolytes. In addition, the S content in the electrolyte recovered from a discharged Li-S battery was successfully determined by the proposed HPLC/UV method. Thus, the feasibility of the method to the online analysis for a Li-S battery is demonstrated. Interestingly, the S was found super-saturated in the electrolyte recovered from a discharged Li-S cell.

  14. Quantitative Chromatographic Determination of Dissolved Elemental Sulfur in the Non-aqueous Electrolyte for Lithium-Sulfur Batteries

    SciTech Connect (OSTI)

    Zheng, Dong; Yang, Xiao-Qing; Zhang, Xuran; Li, Chao; McKinnon, Meaghan E.; Sadok, Rachel G.; Qu, Deyu; Yu, Xiqian; Lee, Hung-Sui; Qu, Deyang

    2014-12-02

    A fast and reliable analytical method is reported for the quantitative determination of dissolved elemental sulfur in non-aqueous electrolytes for Li-S batteries. By using high performance liquid chromatography with a UV detector, the solubility of S in 12 different pure solvents and in 22 different electrolytes was determined. It was found that the solubility of elemental sulfur is dependent on the Lewis basicity, the polarity of solvents and the salt concentration in the electrolytes. In addition, the S content in the electrolyte recovered from a discharged Li-S battery was successfully determined by the proposed HPLC/UV method. Thus, the feasibility of the method to the online analysis for a Li-S battery is demonstrated. Interestingly, the S was found super-saturated in the electrolyte recovered from a discharged Li-S cell.

  15. Electrical conductivity in Li2O2 and its role in determining capacity limitations in non-aqueous Li-O2 batteries

    E-Print Network [OSTI]

    Thygesen, Kristian

    -O2 batteries V. Viswanathan, K. S. Thygesen, J. S. Hummelshøj, J. K. Nørskov, G. Girishkumar et al limitations in non-aqueous Li-O2 batteries V. Viswanathan,1 K. S. Thygesen,2 J. S. Hummelshøj,3 J. K. Nørskov energy density battery couple. Such cells, however, show sudden death at capacities far below

  16. Acoustic detection of Immiscible Liquids in Sand

    SciTech Connect (OSTI)

    Geller, Jil T.; Kowalsky, Michael B.; Seifert, Patricia K.; Nihei, Kurt T.

    1999-03-01

    Laboratory cross-well P-wave transmission at 90 kHz was measured in a 61 cm diameter by 76 cm tall water-saturated sand pack, before and after introducing a non-aqueous phase organic liquid (NAPL) (n-dodecane). In one experiment NAPL was introduced to form a lens trapped by a low permeability layer; a second experiment considered NAPL residual trapped behind the front of flowing NAPL. The NAPL caused significant changes in the travel time and amplitude of first arrivals, as well as the generation of diffracted waves arriving after the direct wave. The spatial variations in NAPL saturation obtained from excavation at the end of the experiment correlated well with the observed variations in the P-wave amplitudes and travel times. NAPL residual saturation changes from NAPL flow channels of 3 to 4% were detectable and the 40 to 80% NAPL saturation in the NAPL lens was clearly visible at acoustic frequencies. The results of these experiments demonstrate that small NAPL saturations may be more easily detected with amplitude rather than travel time data, but that the relationships between the amplitude changes and NAPL saturation maybe more complex than those for velocity.

  17. A Review of "Becoming Neapolitan. Citizen Culture in Baroque Naples" by John A. Marino 

    E-Print Network [OSTI]

    Litchfield, R. Burr

    2011-01-01

    the procession. Gradually the ?popular? elements were muted and the vitality of the feast of S. Giovanni dimmed. The lesson for ?becoming Neapolitan? from this interesting book is that Neapolitan society, as seen through its festivities, was becom- ing more... participa- tion.? This, with the final enfranchisement of the middle classes in the nineteenth century, was the lasting legacy of Baroque Naples: its plebeians were excluded. Catherine Gimelli Martin. Milton Among the Puritans: The Case for Historical...

  18. Non-aqueous, capillary electrophoretic separations of enantiomers with a charged cyclodextrin highly-soluble in organic solvents 

    E-Print Network [OSTI]

    Sanchez Vindas, Silvia Elena

    2005-11-01

    not be easily removed. Another limitation of this step is the technique used to determine the purity of heptakis (2, 3-O-diacetyl)-?-cyclodextrin, HDA-?CD. The fluoride present in the reaction mixture is not compatible with reversed-phase HPLC columns, so... percentage on HBMSi-?CD re-crystallizations found from the chromatograms for the mother liquors. Peak labels and chromatographic conditions as described in Figure II-2.............................. 25 II-5 Effect of the amount of solvent mixture to mass...

  19. Surface and Interfacial Properties of Nonaqueous-Phase Liquid Mixtures Released to the Subsurface at the Hanford Site

    SciTech Connect (OSTI)

    Nellis, Scott; Yoon, Hongkyu; Werth, Charlie; Oostrom, Martinus; Valocchi, Albert J.

    2009-05-01

    Surface and interfacial tensions that arise at the interface between different phases are key parameters affecting Nonaqueous Phase Liquid (NAPL) movement and redistribution in the vadose zone after spill events. In this study, the impact of major additive components on surface and interfacial tensions for organic mixtures and wastewater was investigated. Organic mixture and wastewater compositions are based upon carbon tetrachloride (CT) mixtures released at the Hanford site, where CT was discharged simultaneously with dibutyl butyl phosphonate (DBBP), tributyl phosphate (TBP), dibutyl phosphate (DBP), and a machining lard oil (LO). A considerable amount of wastewater consisting primarily of nitrates and metal salts was also discharged. The tension values measured in this study revealed that the addition of these additive components caused a significant lowering of the interfacial tension with water or wastewater and the surface tension of the wastewater phase in equilibrium with the organic mixtures, compared to pure CT, but had minimal effect on the surface tension of the NAPL itself. These results lead to large differences in spreading coefficients for several mixtures, where the additives caused both a higher (more spreading) initial spreading coefficient and a lower (less spreading) equilibrium spreading coefficient. This indicates that if these mixtures migrate into uncontaminated areas, they will tend to spread quickly, but form a higher residual NAPL saturation after equilibrium, as compared to pure CT. Over time, CT likely volatilizes more rapidly than other components in the originally disposed mixtures and the lard oil and phosphates would become more concentrated in the remaining NAPL, resulting in a lower interfacial tension for the mixture. Spreading coefficients are expected to increase and perhaps change the equilibrated organic mixtures from nonspreading to spreading in water-wetting porous media. These results show that the behavior of organic chemical mixtures should be accounted for in numerical flow and transport models.

  20. HYDROGEL TRACER BEADS: THE DEVELOPMENT, MODIFICATION, AND TESTING OF AN INNOVATIVE TRACER FOR BETTER UNDERSTANDING LNAPL TRANSPORT IN KARST AQUIFERS

    SciTech Connect (OSTI)

    Amanda Laskoskie, Harry M. Edenborn, and Dorothy J. Vesper

    2012-01-01

    The goal of this specific research task is to develop proxy tracers that mimic contaminant movement to better understand and predict contaminant fate and transport in karst aquifers. Hydrogel tracer beads are transported as a separate phase than water and can used as a proxy tracer to mimic the transport of non-aqueous phase liquids (NAPL). They can be constructed with different densities, sizes & chemical attributes. This poster describes the creation and optimization of the beads and the field testing of buoyant beads, including sampling, tracer analysis, and quantitative analysis. The buoyant beads are transported ahead of the dissolved solutes, suggesting that light NAPL (LNAPL) transport in karst may occur faster than predicted from traditional tracing techniques. The hydrogel beads were successful in illustrating this enhanced transport.

  1. Acoustically enhanced remediation of contaminated soils and ground water. Volume 1

    SciTech Connect (OSTI)

    1995-10-01

    The Phase 1 laboratory bench-scale investigation results have shown that acoustically enhanced remediation (AER) technology can significantly accelerate the ground water remediation of non-aqueous phase liquids (NAPLs) in unconsolidated soils. The testing also determined some of the acoustic parameters which maximize fluid and contaminant extraction rates. A technology merit and trade analysis identified the conditions under which AER could be successfully deployed in the field, and an analysis of existing acoustical sources and varying methods for their deployment found that AER technology can be successfully deployed in-situ. Current estimates of deployability indicate that a NAPL plume 150 ft in diameter can be readily remediated. This program focused on unconsolidated soils because of the large number of remediation sites located in this type of hydrogeologic setting throughout the nation. It also focused on NAPLs and low permeability soil because of the inherent difficult in the remediation of NAPLs and the significant time and cost impact caused by contaminated low permeability soils. This overall program is recommended for Phase 2 which will address the technology scaling requirements for a field scale test.

  2. Non-aqueous electrolyte for lithium-ion battery

    DOE Patents [OSTI]

    Zhang, Lu; Zhang, Zhengcheng; Amine, Khalil

    2014-04-15

    The present technology relates to stabilizing additives and electrolytes containing the same for use in electrochemical devices such as lithium ion batteries and capacitors. The stabilizing additives include triazinane triones and bicyclic compounds comprising succinic anhydride, such as compounds of Formulas I and II described herein.

  3. Non-aqueous liquid compositions comprising ion exchange polymers

    DOE Patents [OSTI]

    Kim, Yu Seung; Lee, Kwan-Soo; Rockward, Tommy Q. T.

    2013-03-12

    Compositions, and methods of making thereof, comprising from about 1% to about 5% of a perfluorinated sulfonic acid ionomer or a hydrocarbon-based ionomer; and from about 95% to about 99% of a solvent, said solvent consisting essentially of a polyol; wherein said composition is substantially free of water and wherein said ionomer is uniformly dispersed in said solvent.

  4. Non-aqueous liquid compositions comprising ion exchange polymers

    DOE Patents [OSTI]

    Kim, Yu Seung (Los Alamos, NM); Lee, Kwan-Soo (Blacksburg, VA); Rockward, Tommy Q. T. (Rio Rancho, NM)

    2011-07-19

    Compositions, and methods of making thereof, comprising from about 1% to about 5% of a perfluorinated sulfonic acid ionomer or a hydrocarbon-based ionomer; and from about 95% to about 99% of a solvent, said solvent consisting essentially of a polyol; wherein said composition is substantially free of water and wherein said ionomer is uniformly dispersed in said solvent.

  5. Non-aqueous electrolyte for high voltage rechargeable magnesium batteries

    DOE Patents [OSTI]

    Doe, Robert Ellis; Lane, George Hamilton; Jilek, Robert E; Hwang, Jaehee

    2015-02-10

    An electrolyte for use in electrochemical cells is provided. The properties of the electrolyte include high conductivity, high Coulombic efficiency, and an electrochemical window that can exceed 3.5 V vs. Mg/Mg.sup.+2. The use of the electrolyte promotes the electrochemical deposition and dissolution of Mg without the use of any Grignard reagents, other organometallic materials, tetraphenyl borate, or tetrachloroaluminate derived anions. Other Mg-containing electrolyte systems that are expected to be suitable for use in secondary batteries are also described.

  6. Fluorinated Arylboron Oxalate for Non-Aqueous Battery Electrolytes...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    when used together with electrolytes, produce a battery with improved conductivity, lithium ion transference, and SEI formation over those using BBARs alone. Applications and...

  7. JOURNAL OF ENVIRONMENTAL SCIENCE AND HEALTH Part A--Toxic/Hazardous Substances & Environmental Engineering

    E-Print Network [OSTI]

    Rockne, Karl J.

    be promising for in situ bioremediation following NAPL extraction. Key Words: Reductive dechlorination; Bioremediation; Ethyl lactate; Perchloroethene; Tetrachloroethene; Chloroethene; Green chemistry; Solvent- water aquifers and may exist as dense nonaqueous phase liquids (NAPLs) due to their higher density

  8. Methods Note/ NAPL Source Zone Depletion Model

    E-Print Network [OSTI]

    Barkan, Christopher P.L.

    industry. Among the petroleum hydrocarbon mixtures considered, the cleanup time of diesel fuel was much of Geomechanics, Sandia National Laboratories, P.O. Box 5800, MS 0735, Albuquerque, NM 87185-0735; (505) 284

  9. Phase Transitions

    E-Print Network [OSTI]

    Michael Creutz

    1997-08-25

    This is a set of notes on phase transitions and critical phenomena prepared to accompany my lectures for the RHIC '97 summer school, held at Brookhaven from July 6 to 16, 1997.

  10. Revised Arrangements for the Management of Solid and Non-Aqueous Radioactive Waste - 12452

    SciTech Connect (OSTI)

    Fullbrook, Michael; Walker, Johann; Macnab, Alec

    2012-07-01

    In 2010, Atomic Weapons Establishment (AWE) identified a requirement to implement revised management arrangements for the generation, storage and disposal of radioactive waste. A thorough review of the current arrangements/processes was undertaken which included both legal compliance requirements and the identification of business improvement opportunities. On completion of this review a suitable project team was established and in 2011 an integrated Radioactive Waste Management process was implemented throughout the business. Initial results have shown measurable improvements within Radioactive Waste management compliance, operator understanding and increased business efficiency. Through the development and implementation of the revised working arrangements AWE has been able to continue to demonstrate both legal compliance to its regulators along with business efficiency and effectiveness improvements. Simple to follow process maps have improved employees understanding of Radioactive Waste management requirements, provided them with easily accessible information and ensured the business operates in a single coherent manner. The implementation of a modern electronic data management system has ensured all waste related information is easily retrievable and appropriately maintained. The additional functions that have been built into the system have reduced the potential for human error and increased the overall efficiency of the Waste Management department through the use of the automated report generation functionality. (authors)

  11. Non-aqueous liquid compositions comprising ion exchange polymers reference to related application

    DOE Patents [OSTI]

    Kim; Yu Seung (Los Alamos, NM), Lee; Kwan-Soo (Los Alamos, NM), Rockward; Tommy Q. T. (Rio Rancho, NM)

    2012-08-07

    Compositions, and methods of making thereof, comprising from about 1% to about 5% of a perfluorinated sulfonic acid ionomer or a hydrocarbon-based ionomer; and from about 95% to about 99% of a solvent, said solvent consisting essentially of a polyol; wherein said composition is substantially free of water and wherein said ionomer is uniformly dispersed in said solvent.

  12. Charting the known chemical space for non-aqueous Lithium-air battery electrolyte solvents

    E-Print Network [OSTI]

    Husch, Tamara

    2015-01-01

    The Li-Air battery is a very promising candidate for powering future mobility, but finding a suitable electrolyte solvent for this technology turned out to be a major problem. We present a systematic computational investigation of the known chemical space for possible Li-Air electrolyte solvents. It is shown that the problem of finding better Li-Air electrolyte solvents is not only - as previously suggested - about maximizing Li+ and O2- solubilities, but about finding the optimal balance of these solubilities with the viscosity of the solvent. As our results also show that trial-and-error experiments on known chemicals are unlikely to succeed, full chemical sub-spaces for the most promising compound classes are investigated, and suggestions are made for further experiments. The proposed screening approach is transferable and robust and can readily be applied to optimize electrolytes for other electrochemical devices. It goes beyond the current state-of-the-art both in width (considering the number of compoun...

  13. Microscopic Insights into the Electrochemical Behavior of Non-aqueous Electrolytes in Supercapacitors

    SciTech Connect (OSTI)

    Jiang, Deen; Wu, Jianzhong

    2013-01-01

    Electric double-layer capacitors (EDLC) are electrical devices that store energy by adsorption of ionic species at the inner surface of porous electrodes. Compared with aqueous electrolytes, ionic liquid and organic electrolytes have the advantage of larger potential windows, making them attractive for the next generation of EDLC with superior energy and power densities. The performance of both ionic liquid and organic electrolyte EDLC hinges on the judicious selection of the electrode pore size and the electrolyte composition that requires a comprehension of the charging behavior from a microscopic view. In this perspective, we discuss predictions from the classical density functional theory (CDFT) on the dependence of the capacitance on the pore size for ionic-liquid and organic-electrolyte EDLC. CDFT is applicable to electrodes with the pore size ranging from that below the ionic dimensionality to mesoscopic scales, thus unique for investigating the electrochemical behavior of the confined electrolytes for EDLC applications.

  14. [info:lanl-repo/lareport/LA-UR-14-29299] Shale gas and non-aqueous

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield MunicipalTechnicalInformation4563 LLNL Small-scale Friction Sensitivityv b W r88fracturing fluids:

  15. Mixed phases during the phase transitions

    E-Print Network [OSTI]

    Tatsumi, Toshitaka; Maruyama, Toshiki

    2011-01-01

    Quest for a new form of matter inside compact stars compels us to examine the thermodynamical properties of the phase transitions. We closely consider the first-order phase transitions and the phase equilibrium on the basis of the Gibbs conditions, taking the liquid-gas phase transition in asymmetric nuclear matter as an example. Characteristic features of the mixed phase are figured out by solving the coupled equations for mean-fields and densities of constituent particles self-consistently within the Thomas-Fermi approximation. The mixed phase is inhomogeneous matter composed of two phases in equilibrium; it takes a crystalline structure with a unit of various geometrical shapes, inside of which one phase with a characteristic shape, called "pasta", is embedded in another phase by some volume fraction. This framework enables us to properly take into account the Coulomb interaction and the interface energy, and thereby sometimes we see the mechanical instability of the geometric structures of the mixed phase...

  16. Mass transfer and biodegradation of PAH compounds from coal tar. Quarterly technical report, January--March 1993

    SciTech Connect (OSTI)

    Ramaswami, A.; Ghoshal, S.; Luthy, R.G.

    1994-09-01

    This study examines the role of physico-chemical mass transfer processes on the rate of biotransformation of polycyclic aromatic hydrocarbon (PAH) compounds released from non-aqueous phase liquid (NAPL) coal tar present at residual saturation within a microporous medium. A simplified coupled dissolution-degradation model is developed that describes the concurrent mass transfer and biokinetic processes occurring in the system. Model results indicate that a dimensionless Damkohler number can be utilized to distinguish between systems that are mass transfer limited, and those that are limited by biological phenomena. The Damkohler number is estimated from independent laboratory experiments that measure the rates of aqueous phase dissolution and biodegradation of naphthalene from coal tar. Experimental data for Stroudsburg coal tar imbibed within 236 {mu}m diameter silica particles yield Damkohler numbers smaller than unity, indicating, for the particular system under study, that the overall rate of biotransformation of naphthalene is not limited by the mass transfer of naphthalene from coal tar to the bulk aqueous phase. There is a need for investigation of mass transfer for larger particles and/or other PAH compounds, and study of microbial rate-limiting phenomena including toxicity, inhibition and competitive substrate utilization.

  17. CrowdPhase: crowdsourcing the phase problem

    SciTech Connect (OSTI)

    Jorda, Julien; Sawaya, Michael R. [Institute for Genomics and Proteomics, 611 Charles Young Drive East, Los Angeles, CA 90095 (United States); Yeates, Todd O., E-mail: yeates@mbi.ucla.edu [Institute for Genomics and Proteomics, 611 Charles Young Drive East, Los Angeles, CA 90095 (United States); Molecular Biology Institute, 611 Charles Young Drive East, Los Angeles, CA 90095 (United States); University of California, 611 Charles Young Drive East, Los Angeles, CA 90095 (United States)

    2014-06-01

    The idea of attacking the phase problem by crowdsourcing is introduced. Using an interactive, multi-player, web-based system, participants work simultaneously to select phase sets that correspond to better electron-density maps in order to solve low-resolution phasing problems. The human mind innately excels at some complex tasks that are difficult to solve using computers alone. For complex problems amenable to parallelization, strategies can be developed to exploit human intelligence in a collective form: such approaches are sometimes referred to as ‘crowdsourcing’. Here, a first attempt at a crowdsourced approach for low-resolution ab initio phasing in macromolecular crystallography is proposed. A collaborative online game named CrowdPhase was designed, which relies on a human-powered genetic algorithm, where players control the selection mechanism during the evolutionary process. The algorithm starts from a population of ‘individuals’, each with a random genetic makeup, in this case a map prepared from a random set of phases, and tries to cause the population to evolve towards individuals with better phases based on Darwinian survival of the fittest. Players apply their pattern-recognition capabilities to evaluate the electron-density maps generated from these sets of phases and to select the fittest individuals. A user-friendly interface, a training stage and a competitive scoring system foster a network of well trained players who can guide the genetic algorithm towards better solutions from generation to generation via gameplay. CrowdPhase was applied to two synthetic low-resolution phasing puzzles and it was shown that players could successfully obtain phase sets in the 30° phase error range and corresponding molecular envelopes showing agreement with the low-resolution models. The successful preliminary studies suggest that with further development the crowdsourcing approach could fill a gap in current crystallographic methods by making it possible to extract meaningful information in cases where limited resolution might otherwise prevent initial phasing.

  18. Map-likelihood phasing

    SciTech Connect (OSTI)

    Terwilliger, Thomas C., E-mail: terwilliger@lanl.gov [Bioscience Division, Mail Stop M888, Los Alamos National Laboratory, Los Alamos, NM 87545 (United States)

    2001-12-01

    A map-likelihood function is described that can yield phase probabilities with very low model bias. The recently developed technique of maximum-likelihood density modification [Terwilliger (2000 ?), Acta Cryst. D56, 965–972] allows a calculation of phase probabilities based on the likelihood of the electron-density map to be carried out separately from the calculation of any prior phase probabilities. Here, it is shown that phase-probability distributions calculated from the map-likelihood function alone can be highly accurate and that they show minimal bias towards the phases used to initiate the calculation. Map-likelihood phase probabilities depend upon expected characteristics of the electron-density map, such as a defined solvent region and expected electron-density distributions within the solvent region and the region occupied by a macromolecule. In the simplest case, map-likelihood phase-probability distributions are largely based on the flatness of the solvent region. Though map-likelihood phases can be calculated without prior phase information, they are greatly enhanced by high-quality starting phases. This leads to the technique of prime-and-switch phasing for removing model bias. In prime-and-switch phasing, biased phases such as those from a model are used to prime or initiate map-likelihood phasing, then final phases are obtained from map-likelihood phasing alone. Map-likelihood phasing can be applied in cases with solvent content as low as 30%. Potential applications of map-likelihood phasing include unbiased phase calculation from molecular-replacement models, iterative model building, unbiased electron-density maps for cases where 2F{sub o} ? F{sub c} or ?{sub A}-weighted maps would currently be used, structure validation and ab initio phase determination from solvent masks, non-crystallographic symmetry or other knowledge about expected electron density.

  19. Digital quadrature phase detection

    DOE Patents [OSTI]

    Smith, James A. (Idaho Falls, ID); Johnson, John A. (Idaho Falls, ID)

    1992-01-01

    A system for detecting the phase of a frequency of phase modulated signal that includes digital quadrature sampling of the frequency or phase modulated signal at two times that are one quarter of a cycle of a reference signal apart, determination of the arctangent of the ratio of a first sampling of the frequency or phase modulated signal to the second sampling of the frequency or phase modulated signal, and a determination of quadrant in which the phase determination is increased by 2.pi. when the quadrant changes from the first quadrant to the fourth quadrant and decreased by 2.pi. when the quadrant changes from the fourth quadrant to the first quadrant whereby the absolute phase of the frequency or phase modulated signal can be determined using an arbitrary reference convention.

  20. Digital quadrature phase detection

    DOE Patents [OSTI]

    Smith, J.A.; Johnson, J.A.

    1992-05-26

    A system for detecting the phase of a frequency or phase modulated signal that includes digital quadrature sampling of the frequency or phase modulated signal at two times that are one quarter of a cycle of a reference signal apart, determination of the arctangent of the ratio of a first sampling of the frequency or phase modulated signal to the second sampling of the frequency or phase modulated signal, and a determination of quadrant in which the phase determination is increased by 2[pi] when the quadrant changes from the first quadrant to the fourth quadrant and decreased by 2[pi] when the quadrant changes from the fourth quadrant to the first quadrant whereby the absolute phase of the frequency or phase modulated signal can be determined using an arbitrary reference convention. 6 figs.

  1. Topological phase effects

    E-Print Network [OSTI]

    J. M. Robbins

    2010-09-10

    Quantum eigenstates undergoing cyclic changes acquire a phase factor of geometric origin. This phase, known as the Berry phase, or the geometric phase, has found applications in a wide range of disciplines throughout physics, including atomic and molecular physics, condensed matter physics, optics, and classical dynamics. In this article, the basic theory of the geometric phase is presented along with a number of representative applications. The article begins with an account of the geometric phase for cyclic adiabatic evolutions. An elementary derivation is given along with a worked example for two-state systems. The implications of time-reversal are explained, as is the fundamental connection between the geometric phase and energy level degeneracies. We also discuss methods of experimental observation. A brief account is given of geometric magnetism; this is a Lorenz-like force of geometric origin which appears in the dynamics of slow systems coupled to fast ones. A number of theoretical developments of the geometric phase are presented. These include an informal discussion of fibre bundles, and generalizations of the geometric phase to degenerate eigenstates (the nonabelian case) and to nonadiabatic evolution. There follows an account of applications. Manifestations in classical physics include the Hannay angle and kinematic geometric phases. Applications in optics concern polarization dynamics, including the theory and observation of Pancharatnam's phase. Applications in molecular physics include the molecular Aharonov-Bohm effect and nuclear magnetic resonance studies. In condensed matter physics, we discuss the role of the geometric phase in the theory of the quantum Hall effect.

  2. Stabilising the Blue Phases

    E-Print Network [OSTI]

    G. P. Alexander; J. M. Yeomans

    2006-09-22

    We present an investigation of the phase diagram of cholesteric liquid crystals within the framework of Landau - de Gennes theory. The free energy is modified to incorporate all three Frank elastic constants and to allow for a temperature dependent pitch in the cholesteric phase. It is found that the region of stability of the cubic blue phases depends significantly on the value of the elastic constants, being reduced when the bend elastic constant is larger than splay and when twist is smaller than the other two. Most dramatically we find a large increase in the region of stability of blue phase I, and a qualitative change in the phase diagram, in a system where the cholesteric phase displays helix inversion.

  3. Crystal phase identification

    DOE Patents [OSTI]

    Michael, Joseph R. (Albuquerque, NM); Goehner, Raymond P. (Albuquerque, NM); Schlienger, Max E. (Albuquerque, NM)

    2001-01-01

    A method and apparatus for determining the crystalline phase and crystalline characteristics of a sample. This invention provides a method and apparatus for unambiguously identifying and determining the crystalline phase and crystalline characteristics of a sample by using an electron beam generator, such as a scanning electron microscope, to obtain a backscattered electron Kikuchi pattern of a sample, and extracting crystallographic and composition data that is matched to database information to provide a quick and automatic method to identify crystalline phases.

  4. Flexoelectric blue phases

    E-Print Network [OSTI]

    G P Alexander; J M Yeomans

    2007-07-01

    We describe the occurence and properties of liquid crystal phases showing two dimensional splay and bend distortions which are stabilised by flexoelectric interactions. These phases are characterised by regions of locally double splayed order separated by topological defects and are thus highly analogous to the blue phases of cholesteric liquid crystals. We present a mean field analysis based upon the Landau--de Gennes Q-tensor theory and construct a phase diagram for flexoelectric structures using analytic and numerical results. We stress the similarities and discrepancies between the cholesteric and flexoelectric cases.

  5. Thermodynamically Stable Blue Phases

    E-Print Network [OSTI]

    F. Castles; S. M. Morris; E. M. Terentjev; H. J. Coles

    2011-01-28

    We show theoretically that flexoelectricity stabilizes blue phases in chiral liquid crystals. Induced internal polarization reduces the elastic energy cost of splay and bend deformations surrounding singular lines in the director field. The energy of regions of double twist is unchanged. This in turn reduces the free energy of the blue phase with respect to that of the chiral nematic phase, leading to stability over a wider temperature range. The theory explains the discovery of large temperature range blue phases in highly flexoelectric "bimesogenic" and "bent-core" materials, and predicts how this range may be increased further.

  6. Final Report Northeast Site Area B NAPL Remediation Project

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-SessionsSouth DakotaRobbins and Myers CoMadisonAMOCOELIkNATION ;.7,

  7. Microsoft Word - N0075800-NAPL April to June 04.doc

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-SessionsSouth DakotaRobbins and MyersHr. Anthony5-TAC U.S. Department

  8. Northeast Site Area A NAPL Remediation Final Report.doc

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-SessionsSouth DakotaRobbins and MyersHr.EvaluationJune~ofOF.+,-a-r&82-TAC

  9. A Phase Odyssey

    SciTech Connect (OSTI)

    Nugent, K.A.; Paganin, D.; Gureyev, T.E. (Melbourne)

    2009-01-06

    We are introduced to the effects of phase from the earliest days of our childhood, from the nursery rhyme above (or its less verbose for 'Twinkle, Twinkle Little Star') to the shimmer over a hot road and the network of bright lines at the bottom of a swimming pool. These are all manifestations of phase. And there are many more.

  10. UPVG phase 2 report

    SciTech Connect (OSTI)

    1995-08-01

    The Utility PhotoVoltaic Group (UPVG), supported by member dues and a grant from the US Department of Energy, has as its mission the acceleration of the use of cost-effective small-scale and emerging large-scale applications of photovoltaics for the benefit of electric utilities and their customers. Formed in October, 1992, with the support of the American Public Power Association, Edison Electric Institute, and the National Rural Electric Cooperative Association, the UPVG currently has 90 members from all sectors of the electric utility industry. The UPVG`s efforts as conceived were divided into four phases: Phase 0--program plan; Phase 1--organization and strategy development; Phase 2--creating market assurance; and Phase 3--higher volume purchases. The Phase 0 effort developed the program plan and was completed early in 1993. The Phase 1 goal was to develop the necessary background information and analysis to lead to a decision as to which strategies could be undertaken by utilities to promote greater understanding of PV markets and achieve increased volumes of PV purchases. This report provides the details of the UPVG`s Phase 2 efforts to initiate TEAM-UP, its multiyear, 50-MW hardware initiative.

  11. WATER RESOURCES RESEARCH, VOL. , NO. , PAGES 110, The Impact of Wettability Alteration on Two-Phase Flow

    E-Print Network [OSTI]

    Patzek, Tadeusz W.

    WATER RESOURCES RESEARCH, VOL. , NO. , PAGES 1­10, The Impact of Wettability Alteration on Two (NAPLs) and gases that co-exist with water in soils and rocks, is of fundamental interest to subsurface water management. Any prediction of temporal and spatial distributions of these fluids is sensitive

  12. pplane8 Phase Portraits

    E-Print Network [OSTI]

    2010-08-05

    pplane8 Phase Portraits. • The routine pplane8 is already loaded on all ITaP machines as standard software. (If you are using your own copy of MAtlAB you may ...

  13. 2006 European Association of Geoscientists & Engineers 253 Fresnel reflection coefficients for GPR-AVA analysis and

    E-Print Network [OSTI]

    Santos, Juan

    is the con- tamination of the subsoil with hydrocarbons. Contaminants may exist in the gas phase for GPR-AVA analysis and detection of seawater and NAPL contaminants José M. Carcione1* , Davide Gei1 for different interfaces in the subsoil: air/fresh-water, air/seawater, fresh-water/seawater, air/NAPL (non

  14. Electron microscope phase enhancement

    DOE Patents [OSTI]

    Jin, Jian; Glaeser, Robert M.

    2010-06-15

    A microfabricated electron phase shift element is used for modifying the phase characteristics of an electron beam passing though its center aperture, while not affecting the more divergent portion of an incident beam to selectively provide a ninety-degree phase shift to the unscattered beam in the back focal plan of the objective lens, in order to realize Zernike-type, in-focus phase contrast in an electron microscope. One application of the element is to increase the contrast of an electron microscope for viewing weakly scattering samples while in focus. Typical weakly scattering samples include biological samples such as macromolecules, or perhaps cells. Preliminary experimental images demonstrate that these devices do apply a ninety degree phase shift as expected. Electrostatic calculations have been used to determine that fringing fields in the region of the scattered electron beams will cause a negligible phase shift as long as the ratio of electrode length to the transverse feature-size aperture is about 5:1. Calculations are underway to determine the feasibility of aspect smaller aspect ratios of about 3:1 and about 2:1.

  15. Kinetic investigation of catalytic disproportionation of superoxide ions in the non-aqueous electrolyte used in Li-air batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wang, Qiang [Univ. of Massachusetts at Boston, Boston, MA (United States); Yang, Xiao -Qing [Brookhaven National Laboratory (BNL), Upton, NY (United States); Zheng, Doug [Univ. of Massachusetts at Boston, Boston, MA (United States); McKinnon, Meaghan E. [Univ. of Massachusetts at Boston, Boston, MA (United States); Qu, Deyang [Univ. of Massachusetts at Boston, Boston, MA (United States)

    2015-01-01

    Superoxide reacts with carbonate solvents in Li–air batteries. Tris(pentafluorophenyl)borane is found to catalyze a more rapid superoxide (O2-) disproportionation reaction than the reaction between superoxide and propylene carbonate (PC). With this catalysis, the negative impact of the reaction between the electrolyte and O2-produced by the O2 reduction can be minimized. A simple kinetic study using ESR spectroscopy was reported to determine reaction orders and rate constants for the reaction between PC and superoxide, and the disproportionation of superoxide catalyzed by Tris(pentafluorophenyl)borane and Li ions. The reactions are found to be first order and the rate constants are 0.033 s-1 M-1, 0.020 s-1 M-1and 0.67 s-1M-1 for reactions with PC, Li ion and Tris(pentafluorophenyl)borane, respectively.

  16. Literature search for the non-aqueous separation of zinc from fuel rod cladding. [After dissolution in liquid metal

    SciTech Connect (OSTI)

    Sandvig, R. L.; Dyer, S. J.; Lambert, G. A.; Baldwin, C. E.

    1980-06-21

    This report reviews the literature of processes for the nonaqueous separation of zinc from dissolved fuel assembly cladding. The processes considered were distillation, pyrochemical processing, and electrorefining. The last two techniques were only qualitatively surveyed while the first, distillation, was surveyed in detail. A survey of available literature from 1908 through 1978 on the distillation of zinc was performed. The literature search indicated that a zinc recovery rate in excess of 95% is possible; however, technical problems exist because of the high temperatures required and the corrosive nature of liquid zinc. The report includes a bibliography of the surveyed literature and a computer simulation of vapor pressures in binary systems. 129 references.

  17. Kinetic investigation of catalytic disproportionation of superoxide ions in the non-aqueous electrolyte used in Li-air batteries

    SciTech Connect (OSTI)

    Wang, Qiang; Yang, Xiao -Qing; Zheng, Doug; McKinnon, Meaghan E.; Qu, Deyang

    2014-10-28

    Superoxide reacts with carbonate solvents in Li–air batteries. Tris(pentafluorophenyl)borane is found to catalyze a more rapid superoxide (O2-) disproportionation reaction than the reaction between superoxide and propylene carbonate (PC). With this catalysis, the negative impact of the reaction between the electrolyte and O2-produced by the O2 reduction can be minimized. A simple kinetic study using ESR spectroscopy was reported to determine reaction orders and rate constants for the reaction between PC and superoxide, and the disproportionation of superoxide catalyzed by Tris(pentafluorophenyl)borane and Li ions. The reactions are found to be first order and the rate constants are 0.033 s-1 M-1, 0.020 s-1 M-1and 0.67 s-1M-1 for reactions with PC, Li ion and Tris(pentafluorophenyl)borane, respectively.

  18. Kinetic investigation of catalytic disproportionation of superoxide ions in the non-aqueous electrolyte used in Li-air batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wang, Qiang; Yang, Xiao -Qing; Zheng, Doug; McKinnon, Meaghan E.; Qu, Deyang

    2014-10-28

    Superoxide reacts with carbonate solvents in Li–air batteries. Tris(pentafluorophenyl)borane is found to catalyze a more rapid superoxide (O2-) disproportionation reaction than the reaction between superoxide and propylene carbonate (PC). With this catalysis, the negative impact of the reaction between the electrolyte and O2-produced by the O2 reduction can be minimized. A simple kinetic study using ESR spectroscopy was reported to determine reaction orders and rate constants for the reaction between PC and superoxide, and the disproportionation of superoxide catalyzed by Tris(pentafluorophenyl)borane and Li ions. The reactions are found to be first order and the rate constants are 0.033 s-1 M-1,more »0.020 s-1 M-1and 0.67 s-1M-1 for reactions with PC, Li ion and Tris(pentafluorophenyl)borane, respectively.« less

  19. Compatibility of Lithium Salts with Solvent of the Non-Aqueous Electrolyte in Li–O2 Batteries

    SciTech Connect (OSTI)

    Du, Peng; Lu, Jun; Lau, Kah Chun; Luo, Xiangyi; Bareno, Javier; Zhang, Xiaoyi; Ren, Yang; Zhang, Zhengcheng; Curtiss, Larry A.; Sun, Yang-Kook; Amine, Khalil

    2013-02-20

    The stability of lithium salts, especially in the presence of reduced oxygen species, O2 and H2O (even in a small amount), plays an important role in the cyclability and capacity of Li–O2 cells. This combined experimental and computational study provides evidence that the stability of the electrolyte used in Li–O2 cells strongly depends on the compatibility of lithium salts with solvent. In the case of the LiPF6–1NM3 electrolyte, the decomposition of LiPF6 occurs in the cell as evidenced by in situ XRD, FT-IR and XPS analysis, which triggers the decomposition of 1NM3 solvent due to formation of HF from the decomposition of LiPF6. These reactions lead to degradation of the electrolyte and cause poor cyclability of the cell. The same reactions are not observed when LiTFSI and LiCF3SO3 are used as the lithium salts in 1NM3 solvent, or LiPF6 is used in TEGDME solvent.

  20. Kinetic investigation of catalytic disproportionation of superoxide ions in the non-aqueous electrolyte used in Li–air batteries

    SciTech Connect (OSTI)

    Wang, Qiang; Zheng, Dong; McKinnon, Meaghan E.; Yang, Xiao -Qing; Qu, Deyang

    2014-10-28

    Superoxide reacts with carbonate solvents in Li–air batteries. Tris(pentafluorophenyl)borane is found to catalyze a more rapid superoxide (O2-) disproportionation reaction than the reaction between superoxide and propylene carbonate (PC). With this catalysis, the negative impact of the reaction between the electrolyte and O2-produced by the O2 reduction can be minimized. A simple kinetic study using ESR spectroscopy was reported to determine reaction orders and rate constants for the reaction between PC and superoxide, and the disproportionation of superoxide catalyzed by Tris(pentafluorophenyl)borane and Li ions. As a result, the reactions are found to be first order and the rate constants are 0.033 s-1 M-1, 0.020 s-1 M-1and 0.67 s-1M-1 for reactions with PC, Li ion and Tris(pentafluorophenyl)borane, respectively.

  1. Kinetic investigation of catalytic disproportionation of superoxide ions in the non-aqueous electrolyte used in Li–air batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wang, Qiang; Zheng, Dong; McKinnon, Meaghan E.; Yang, Xiao -Qing; Qu, Deyang

    2014-10-28

    Superoxide reacts with carbonate solvents in Li–air batteries. Tris(pentafluorophenyl)borane is found to catalyze a more rapid superoxide (O2-) disproportionation reaction than the reaction between superoxide and propylene carbonate (PC). With this catalysis, the negative impact of the reaction between the electrolyte and O2-produced by the O2 reduction can be minimized. A simple kinetic study using ESR spectroscopy was reported to determine reaction orders and rate constants for the reaction between PC and superoxide, and the disproportionation of superoxide catalyzed by Tris(pentafluorophenyl)borane and Li ions. As a result, the reactions are found to be first order and the rate constants aremore »0.033 s-1 M-1, 0.020 s-1 M-1and 0.67 s-1M-1 for reactions with PC, Li ion and Tris(pentafluorophenyl)borane, respectively.« less

  2. Electroweak phase transitions

    SciTech Connect (OSTI)

    Anderson, G.W.

    1991-09-16

    An analytic treatment of the one Higgs doublet, electroweak phase transition is given. The phase transition is first order, occurs by the nucleation of thin walled bubbles and completes at a temperature where the order parameter, {l_angle}{phi}{r_angle}{sub T} is significantly smaller than it is when the origin becomes absolutely unstable. The rate of anomalous baryon number violation is an exponentially function of {l_angle}{phi}{r_angle}{sub T}. In very minimal extensions of the standard model it is quite easy to increase {l_angle}{phi}{r_angle}{sub T} so that anomalous baryon number violation is suppressed after completion of the phase transition. Hence baryogenesis at the electroweak phase transition is tenable in minimal of the standard model. In some cases additional phase transitions are possible. For a light Higgs boson, when the top quark mass is sufficiently large, the state where the Higgs field has a vacuum expectation value {l_angle}{phi}{r_angle} = 246 GeV is not the true minimum of the Higgs potential. When this is the case, and when the top quark mass exceeds some critical value, thermal fluctuations in the early universe would have rendered the state {l_angle}{phi}{r_angle} = 246 GeV unstable. The requirement that the state {l_angle}{phi}{r_angle} = 246 GeV is sufficiently long lived constrains the masses of the Higgs boson and the top quark. Finally, we consider whether local phase transitions can be induced by heavy particles which act as seeds for deformations in the scalar field.

  3. Electroweak phase transitions

    SciTech Connect (OSTI)

    Anderson, G.W.

    1991-09-16

    An analytic treatment of the one Higgs doublet, electroweak phase transition is given. The phase transition is first order, occurs by the nucleation of thin walled bubbles and completes at a temperature where the order parameter, {l angle}{phi}{r angle}{sub T} is significantly smaller than it is when the origin becomes absolutely unstable. The rate of anomalous baryon number violation is an exponentially function of {l angle}{phi}{r angle}{sub T}. In very minimal extensions of the standard model it is quite easy to increase {l angle}{phi}{r angle}{sub T} so that anomalous baryon number violation is suppressed after completion of the phase transition. Hence baryogenesis at the electroweak phase transition is tenable in minimal of the standard model. In some cases additional phase transitions are possible. For a light Higgs boson, when the top quark mass is sufficiently large, the state where the Higgs field has a vacuum expectation value {l angle}{phi}{r angle} = 246 GeV is not the true minimum of the Higgs potential. When this is the case, and when the top quark mass exceeds some critical value, thermal fluctuations in the early universe would have rendered the state {l angle}{phi}{r angle} = 246 GeV unstable. The requirement that the state {l angle}{phi}{r angle} = 246 GeV is sufficiently long lived constrains the masses of the Higgs boson and the top quark. Finally, we consider whether local phase transitions can be induced by heavy particles which act as seeds for deformations in the scalar field.

  4. Linear phase compressive filter

    DOE Patents [OSTI]

    McEwan, T.E.

    1995-06-06

    A phase linear filter for soliton suppression is in the form of a laddered series of stages of non-commensurate low pass filters with each low pass filter having a series coupled inductance (L) and a reverse biased, voltage dependent varactor diode, to ground which acts as a variable capacitance (C). L and C values are set to levels which correspond to a linear or conventional phase linear filter. Inductance is mapped directly from that of an equivalent nonlinear transmission line and capacitance is mapped from the linear case using a large signal equivalent of a nonlinear transmission line. 2 figs.

  5. Phase change compositions

    DOE Patents [OSTI]

    Salyer, Ival O. (Dayton, OH); Griffen, Charles W. (Mason, OH)

    1986-01-01

    Compositions containing crystalline, long chain, alkyl hydrocarbons as phase change materials including cementitious compositions containing the alkyl hydrocarbons neat or in pellets or granules formed by incorporating the alkyl hydrocarbons in polymers or rubbers; and polymeric or elastomeric compositions containing alkyl hydrocarbons.

  6. Phase change compositions

    DOE Patents [OSTI]

    Salyer, Ival O. (Dayton, OH)

    1989-01-01

    Compositions containing crystalline, straight chain, alkyl hydrocarbons as phase change materials including cementitious compositions containing the alkyl hydrocarbons neat or in pellets or granules formed by incorporating the alkyl hydrocarbons in polymers or rubbers; and polymeric or elastomeric compositions containing alkyl hydrocarbons.

  7. Phase II Final Report

    SciTech Connect (OSTI)

    Schuknecht, Nate; White, David; Hoste, Graeme

    2014-09-11

    The SkyTrough DSP will advance the state-of-the-art in parabolic troughs for utility applications, with a larger aperture, higher operating temperature, and lower cost. The goal of this project was to develop a parabolic trough collector that enables solar electricity generation in the 2020 marketplace for a 216MWe nameplate baseload power plant. This plant requires an LCOE of 9¢/kWhe, given a capacity factor of 75%, a fossil fuel limit of 15%, a fossil fuel cost of $6.75/MMBtu, $25.00/kWht thermal storage cost, and a domestic installation corresponding to Daggett, CA. The result of our optimization was a trough design of larger aperture and operating temperature than has been fielded in large, utility scale parabolic trough applications: 7.6m width x 150m SCA length (1,118m2 aperture), with four 90mm diameter × 4.7m receivers per mirror module and an operating temperature of 500°C. The results from physical modeling in the System Advisory Model indicate that, for a capacity factor of 75%: The LCOE will be 8.87¢/kWhe. SkyFuel examined the design of almost every parabolic trough component from a perspective of load and performance at aperture areas from 500 to 2,900m2. Aperture-dependent design was combined with fixed quotations for similar parts from the commercialized SkyTrough product, and established an installed cost of $130/m2 in 2020. This project was conducted in two phases. Phase I was a preliminary design, culminating in an optimum trough size and further improvement of an advanced polymeric reflective material. This phase was completed in October of 2011. Phase II has been the detailed engineering design and component testing, which culminated in the fabrication and testing of a single mirror module. Phase II is complete, and this document presents a summary of the comprehensive work.

  8. Phase shifting interferometer

    DOE Patents [OSTI]

    Sommargren, G.E.

    1999-08-03

    An interferometer is disclosed which has the capability of measuring optical elements and systems with an accuracy of {lambda}/1000 where {lambda} is the wavelength of visible light. Whereas current interferometers employ a reference surface, which inherently limits the accuracy of the measurement to about {lambda}/50, this interferometer uses an essentially perfect spherical reference wavefront generated by the fundamental process of diffraction. Whereas current interferometers illuminate the optic to be tested with an aberrated wavefront which also limits the accuracy of the measurement, this interferometer uses an essentially perfect spherical measurement wavefront generated by the fundamental process of diffraction. This interferometer is adjustable to give unity fringe visibility, which maximizes the signal-to-noise, and has the means to introduce a controlled prescribed relative phase shift between the reference wavefront and the wavefront from the optics under test, which permits analysis of the interference fringe pattern using standard phase extraction algorithms. 11 figs.

  9. Phase shifting diffraction interferometer

    DOE Patents [OSTI]

    Sommargren, Gary E. (Santa Cruz, CA)

    1996-01-01

    An interferometer which has the capability of measuring optical elements and systems with an accuracy of .lambda./1000 where .lambda. is the wavelength of visible light. Whereas current interferometers employ a reference surface, which inherently limits the accuracy of the measurement to about .lambda./50, this interferometer uses an essentially perfect spherical reference wavefront generated by the fundamental process of diffraction. This interferometer is adjustable to give unity fringe visibility, which maximizes the signal-to-noise, and has the means to introduce a controlled prescribed relative phase shift between the reference wavefront and the wavefront from the optics under test, which permits analysis of the interference fringe pattern using standard phase extraction algorithms.

  10. Phase shifting interferometer

    DOE Patents [OSTI]

    Sommargren, Gary E. (Santa Cruz, CA)

    1999-01-01

    An interferometer which has the capability of measuring optical elements and systems with an accuracy of .lambda./1000 where .lambda. is the wavelength of visible light. Whereas current interferometers employ a reference surface, which inherently limits the accuracy of the measurement to about .lambda./50, this interferometer uses an essentially perfect spherical reference wavefront generated by the fundamental process of diffraction. Whereas current interferometers illuminate the optic to be tested with an aberrated wavefront which also limits the accuracy of the measurement, this interferometer uses an essentially perfect spherical measurement wavefront generated by the fundamental process of diffraction. This interferometer is adjustable to give unity fringe visibility, which maximizes the signal-to-noise, and has the means to introduce a controlled prescribed relative phase shift between the reference wavefront and the wavefront from the optics under test, which permits analysis of the interference fringe pattern using standard phase extraction algorithms.

  11. Phase shifting diffraction interferometer

    DOE Patents [OSTI]

    Sommargren, G.E.

    1996-08-29

    An interferometer which has the capability of measuring optical elements and systems with an accuracy of {lambda}/1000 where {lambda} is the wavelength of visible light. Whereas current interferometers employ a reference surface, which inherently limits the accuracy of the measurement to about {lambda}/50, this interferometer uses an essentially perfect spherical reference wavefront generated by the fundamental process of diffraction. This interferometer is adjustable to give unity fringe visibility, which maximizes the signal-to-noise, and has the means to introduce a controlled prescribed relative phase shift between the reference wavefront and the wavefront from the optics under test, which permits analysis of the interference fringe pattern using standard phase extraction algorithms. 8 figs.

  12. Solid phase extraction membrane

    DOE Patents [OSTI]

    Carlson, Kurt C [Nashville, TN; Langer, Roger L [Hudson, WI

    2002-11-05

    A wet-laid, porous solid phase extraction sheet material that contains both active particles and binder and that possesses excellent wet strength is described. The binder is present in a relatively small amount while the particles are present in a relatively large amount. The sheet material is sufficiently strong and flexible so as to be pleatable so that, for example, it can be used in a cartridge device.

  13. Phase Field Fracture Mechanics.

    SciTech Connect (OSTI)

    Robertson, Brett Anthony

    2015-11-01

    For this assignment, a newer technique of fracture mechanics using a phase field approach, will be examined and compared with experimental data for a bend test and a tension test. The software being used is Sierra Solid Mechanics, an implicit/explicit finite element code developed at Sandia National Labs in Albuquerque, New Mexico. The bend test experimental data was also obtained at Sandia Labs while the tension test data was found in a report online from Purdue University.

  14. Experimental and theoretical modeling of DNAPL transport in vertical fractured media

    E-Print Network [OSTI]

    Levy, Laurent Claude, 1973-

    2003-01-01

    In recent years, groundwater contamination by dense, non-aqueous phase liquids (DNAPLs) such as chlorinated solvents and polychlorinated biphenyls (PCBs) has become an important environmental concern in many industrialized ...

  15. A multi-component partitioning model to predict organic leaching from stabilized/solidified oily wastes 

    E-Print Network [OSTI]

    O'Cleirigh, Declan Ronan

    1997-01-01

    multi-component approach be taken to describe the partitioning between the aqueous and non-aqueous phases. The heterogeneous nature of these wastes precludes analysis of partitioning of all chemical species. Thus a pseudo-component model has been...

  16. Options Study - Phase II

    SciTech Connect (OSTI)

    R. Wigeland; T. Taiwo; M. Todosow; W. Halsey; J. Gehin

    2010-09-01

    The Options Study has been conducted for the purpose of evaluating the potential of alternative integrated nuclear fuel cycle options to favorably address the issues associated with a continuing or expanding use of nuclear power in the United States. The study produced information that can be used to inform decisions identifying potential directions for research and development on such fuel cycle options. An integrated nuclear fuel cycle option is defined in this study as including all aspects of the entire nuclear fuel cycle, from obtaining natural resources for fuel to the ultimate disposal of used nuclear fuel (UNF) or radioactive wastes. Issues such as nuclear waste management, especially the increasing inventory of used nuclear fuel, the current uncertainty about used fuel disposal, and the risk of nuclear weapons proliferation have contributed to the reluctance to expand the use of nuclear power, even though it is recognized that nuclear power is a safe and reliable method of producing electricity. In this Options Study, current, evolutionary, and revolutionary nuclear energy options were all considered, including the use of uranium and thorium, and both once-through and recycle approaches. Available information has been collected and reviewed in order to evaluate the ability of an option to clearly address the challenges associated with the current implementation and potential expansion of commercial nuclear power in the United States. This Options Study is a comprehensive consideration and review of fuel cycle and technology options, including those for disposal, and is not constrained by any limitations that may be imposed by economics, technical maturity, past policy, or speculated future conditions. This Phase II report is intended to be used in conjunction with the Phase I report, and much information in that report is not repeated here, although some information has been updated to reflect recent developments. The focus in this Options Study was to identify any nuclear fuel cycle technology or option that may result in a significant beneficial impact to the issues as compared to the current U.S. approach of once-through use of nuclear fuel in LWRs or similar reactors followed by direct disposal of UNF. This approach was taken because incremental differences may be difficult to clearly identify and justify due to the large uncertainties that can be associated with the specific causes of the issues. Phase II of this Options Study continued the review of nuclear fuel cycle options that was initiated and documented during Phase I, concentrating on reviewing and summarizing the potential of integrated nuclear fuel cycles. However, based on the reviews of previous studies and available data, it was not always possible to clearly determine sufficiently large differences between the various fuel cycle and technology options for some of the issues or evaluation measures, for example, in cases where only incremental differences with respect to the issues might be achieved regardless of the fuel cycle option or technologies being considered, or where differences were insufficient to clearly rise above the uncertainties.

  17. Proceedings of the TOUGH Symposium 2009

    E-Print Network [OSTI]

    Moridis, George J.

    2010-01-01

    for the gas saturation throughout the reservoir. The dry-NAPL phase saturations matched the reservoir exploration3. Gas saturation (S g ) in the reservoir as a function of

  18. Characterization of Instrumental Phase Stability

    E-Print Network [OSTI]

    D. Y. Kubo; T. R. Hunter; R. D. Christensen; P. I. Yamaguchi

    2007-04-17

    Atmospheric water vapor causes significant undesired phase fluctuations for the Submillimeter Array (SMA) interferometer, particularly in its highest frequency observing band of 690 GHz. One proposed solution to this atmospheric effect is to observe simultaneously at two separate frequency bands of 230 and 690 GHz. Although the phase fluctuations have a smaller magnitude at the lower frequency, they can be measured more accurately and on shorter timescales due to the greater sensitivity of the array to celestial point source calibrators at this frequency. In theory, we can measure the atmospheric phase fluctuations in the 230 GHz band, scale them appropriately with frequency, and apply them to the data in 690 band during the post-observation calibration process. The ultimate limit to this atmospheric phase calibration scheme will be set by the instrumental phase stability of the IF and LO systems. We describe the methodology and initial results of the phase stability characterization of the IF and LO systems.

  19. Digitally controlled distributed phase shifter

    DOE Patents [OSTI]

    Hietala, V.M.; Kravitz, S.H.; Vawter, G.A.

    1993-08-17

    A digitally controlled distributed phase shifter is comprised of N phase shifters. Digital control is achieved by using N binary length-weighted electrodes located on the top surface of a waveguide. A control terminal is attached to each electrode thereby allowing the application of a control signal. The control signal is either one or two discrete bias voltages. The application of the discrete bias voltages changes the modal index of a portion of the waveguide that corresponds to a length of the electrode to which the bias voltage is applied, thereby causing the phase to change through the underlying portion of the waveguide. The digitally controlled distributed phase shift network has a total phase shift comprised of the sum of the individual phase shifters.

  20. Phase Transitions in the Early Universe

    E-Print Network [OSTI]

    Wainwright, Carroll Livingston

    2013-01-01

    rapid change in the minimum caused by either the disappearance of the phase or a second- order phase transition.

  1. Method for aqueous phase reactions

    DOE Patents [OSTI]

    Elliott, Douglas C. (Richland, WA); Hart, Todd R. (Kennewick, WA)

    2000-01-01

    A method for converting liquid organic material in a mixture into a product utilizing a catalyst in the form of a plurality of porous particles wherein each particle is a support having nickel metal catalytic phase or reduced nickel deposited thereon in a first dispersed phase and an additional metal deposited onto the support in a second dispersed phase. The additional metal is effective in retarding or reducing agglomeration or sintering of the nickel metal catalytic phase without substantially affecting the catalytic activity, thereby increasing the life time of the catalyst.

  2. Phase Retrieval: Hubble and the

    E-Print Network [OSTI]

    Masci, Frank

    (Gerchberg-Saxton/Misell/Fienup) Gradient search (steepest descent, conjugate gradient, . . .) Damped least squares (Newton-Raphson) Neural network Linear programming Prescription retrieval Phase diversity etc

  3. Spinfluid Phase Transitions

    E-Print Network [OSTI]

    Marcus S. Cohen

    2009-07-10

    We start with the spinfluid: a nearly-homogeneous, 8-spinor medium, with small local eddies and twists. As it expends, these seed a raft of intersecting codimension-J singularities: a spinfoam. As this expands, the energy trapped in each (4-J) brane varies as the Jth power of the scale factor. Summing on J=(0,1,2,3,4) creates a quartic dilation potential with either 1 or 2 minima: preferred length and mass scales. The spinfoam expands forever with 1 minimum, but recontracts with 2. To quantize it, we take a canonical ensemble of spinfoams, immersed in a heat bath of vacuum spinors, whose microstates vastly outnumber the matter states. It's evolution is governed by a free energy which admits phase transitions at two critical scale, separated by a triple point.Their critical droplets correspond to the varieties of leptons and hadrons.We identify the first as inflation, the second as baryogenesis; and the heat bath of vacuum spinors as dark energy.

  4. Three phase downhole separator process

    DOE Patents [OSTI]

    Cognata, Louis John (Baytown, TX)

    2008-06-24

    Three Phase Downhole Separator Process (TPDSP) is a process which results in the separation of all three phases, (1) oil, (2) gas, and (3) water, at the downhole location in the well bore, water disposal injection downhole, and oil and gas production uphole.

  5. Two-phase flow studies

    SciTech Connect (OSTI)

    Hanold, R.J.

    1983-12-01

    The two-phase flow program is directed at understanding the hydrodynamics of two-phase flows. The two-phase flow regime is characterized by a series of flow patterns that are designated as bubble, slug, churn, and annular flow. Churn flow has received very little scientific attention. This lack of attention cannot be justified because calculations predict that the churn flow pattern will exist over a substantial portion of the two-phase flow zone in producing geothermal wells. The University of Houston is experimentally investigating the dynamics of churn flow and is measuring the holdup over the full range of flow space for which churn flow exists. These experiments are being conducted in an air/water vertical two-phase flow loop. Brown University has constructed and is operating a unique two-phase flow research facility specifically designed to address flow problems of relevance to the geothermal industry. An important feature of the facility is that it is dedicated to two-phase flow of a single substance (including evaporation and condensation) as opposed to the case of a two-component two-phase flow. This facility can be operated with horizontal or vertical test sections of constant diameter or with step changes in diameter to simulate a geothermal well profile.

  6. Holographic Competition of Phases and Superconductivity

    E-Print Network [OSTI]

    Kiritsis, Elias

    2015-01-01

    We use a holographic theory to model and study the competition of four phases: an antiferromagnetic phase, a superconducting phase, a metallic phase and a striped phase, using as control parameters temperature and a doping-like parameter. We analyse the various instabilities and determine the possible phases. One class of phase diagrams, that we analyse in detail, is similar to that of high-temperature superconductors as well as other strange metal materials.

  7. Liquid-phase compositions from vapor-phase analyses

    SciTech Connect (OSTI)

    Davis, W. Jr. ); Cochran, H.D. )

    1990-02-01

    Arsenic normally is not considered to be a contaminant. However, because arsenic was found in many cylinders of UF{sub 6}, including in corrosion products, a study was performed of the distribution of the two arsenic fluorides, AsF{sub 3} and AsF{sub 5}, between liquid and vapor phases. The results of the study pertain to condensation or vaporization of liquid UF{sub 6}. This study includes use of various experimental data plus many extrapolations necessitated by the meagerness of the experimental data. The results of this study provide additional support for the vapor-liquid equilibrium model of J.M. Prausnitz and his coworkers as a means of describing the distribution of various impurities between vapor and liquid phases of UF{sub 6}. Thus, it is concluded that AsF{sub 3} will tend to concentrate in the liquid phase but that the concentration of AsF{sub 5} in the vapor phase will exceed its liquid-phase concentration by a factor of about 7.5, which is in agreement with experimental data. Because the weight of the liquid phase in a condensation operation may be in the range of thousands of times that of the vapor phase, most of any AsF{sub 5} will be in the liquid phase in spite of this separation factor of 7.5. It may also be concluded that any arsenic fluorides fed into a uranium isotope separation plant will either travel with other low-molecular-weight gases or react with materials present in the plant. 25 refs., 3 figs., 6 tabs.

  8. SNMR pulse sequence phase cycling

    DOE Patents [OSTI]

    Walsh, David O; Grunewald, Elliot D

    2013-11-12

    Technologies applicable to SNMR pulse sequence phase cycling are disclosed, including SNMR acquisition apparatus and methods, SNMR processing apparatus and methods, and combinations thereof. SNMR acquisition may include transmitting two or more SNMR pulse sequences and applying a phase shift to a pulse in at least one of the pulse sequences, according to any of a variety cycling techniques. SNMR processing may include combining SNMR from a plurality of pulse sequences comprising pulses of different phases, so that desired signals are preserved and indesired signals are canceled.

  9. Gas-phase chemical dynamics

    SciTech Connect (OSTI)

    Weston, R.E. Jr.; Sears, T.J.; Preses, J.M. [Brookhaven National Laboratory, Upton, NY (United States)

    1993-12-01

    Research in this program is directed towards the spectroscopy of small free radicals and reactive molecules and the state-to-state dynamics of gas phase collision, energy transfer, and photodissociation phenomena. Work on several systems is summarized here.

  10. Multiobjective Optimization and Phase Transitions

    E-Print Network [OSTI]

    Seoane, Luís F

    2015-01-01

    Many complex systems obey to optimality conditions that are usually not simple. Conflicting traits often interact making a Multi Objective Optimization (MOO) approach necessary. Recent MOO research on complex systems report about the Pareto front (optimal designs implementing the best trade-off) in a qualitative manner. Meanwhile, research on traditional Simple Objective Optimization (SOO) often finds phase transitions and critical points. We summarize a robust framework that accounts for phase transitions located through SOO techniques and indicates what MOO features resolutely lead to phase transitions. These appear determined by the shape of the Pareto front, which at the same time is deeply related to the thermodynamic Gibbs surface. Indeed, thermodynamics can be written as an MOO from where its phase transitions can be parsimoniously derived; suggesting that the similarities between transitions in MOO-SOO and Statistical Mechanics go beyond mere coincidence.

  11. Polydispersity in Colloidal Phase Transitions 

    E-Print Network [OSTI]

    Fairhurst, David John

    I have studied the effects of polydispersity on the phase behaviour of suspensions of PMMA colloidal spheres on their own and in the presence of non-adsorbed polymer. I systematically explored the volume fraction-polydispersity ...

  12. Phase modulation in RF tag

    DOE Patents [OSTI]

    Carrender, Curtis Lee; Gilbert, Ronald W.

    2007-02-20

    A radio frequency (RF) communication system employs phase-modulated backscatter signals for RF communication from an RF tag to an interrogator. The interrogator transmits a continuous wave interrogation signal to the RF tag, which based on an information code stored in a memory, phase-modulates the interrogation signal to produce a backscatter response signal that is transmitted back to the interrogator. A phase modulator structure in the RF tag may include a switch coupled between an antenna and a quarter-wavelength stub; and a driver coupled between the memory and a control terminal of the switch. The driver is structured to produce a modulating signal corresponding to the information code, the modulating signal alternately opening and closing the switch to respectively decrease and increase the transmission path taken by the interrogation signal and thereby modulate the phase of the response signal. Alternatively, the phase modulator may include a diode coupled between the antenna and driver. The modulating signal from the driver modulates the capacitance of the diode, which modulates the phase of the response signal reflected by the diode and antenna.

  13. Giambattista Della Porta's Histrionic Science

    E-Print Network [OSTI]

    Kodera, Sergius

    2012-01-01

    libri XX. Naples: Carlino Vitale, [1589] 1611. _____. Magialibri XX (Naples: Carlino Vitale, [1589] 1611), 388: “Noi

  14. Gas-Phase IR Spectroscopy of Nucleobases

    E-Print Network [OSTI]

    de Vries, MS

    2015-01-01

    ionization spectroscopy of gas phase guanine: Evidence for2007) Imino tautomers of gas-phase guanine from mid-infraredAlkali Metal Cation Size on Gas Phase Conformation. J. Am.

  15. Computational phase imaging based on intensity transport

    E-Print Network [OSTI]

    Waller, Laura A. (Laura Ann)

    2010-01-01

    Light is a wave, having both an amplitude and a phase. However, optical frequencies are too high to allow direct detection of phase; thus, our eyes and cameras see only real values - intensity. Phase carries important ...

  16. Thermodynamics of Blue Phases In Electric Fields

    E-Print Network [OSTI]

    O. Henrich; D. Marenduzzo; K. Stratford; M. E. Cates

    2010-03-04

    We present extensive numerical studies to determine the phase diagrams of cubic and hexagonal blue phases in an electric field. We confirm the earlier prediction that hexagonal phases, both 2 and 3 dimensional, are stabilized by a field, but we significantly refine the phase boundaries, which were previously estimated by means of a semi-analytical approximation. In particular, our simulations show that the blue phase I -- blue phase II transition at fixed chirality is largely unaffected by electric field, as observed experimentally.

  17. Phase II Planning for Niall Gaffney

    E-Print Network [OSTI]

    Phase II Planning for the HET Niall Gaffney March 6, 1997 #12;#12;Phase II Planning for the HET 3 ................................................................................................................................. 38 Plan Templates .............................................................................................................................................. 47 Example Plans

  18. Phase II Planning for Niall Gaffney

    E-Print Network [OSTI]

    Phase II Planning for the HET Niall Gaffney March 6, 1997 #12; #12; Phase II Planning for the HET 3 ................................................................................................................................. 38 Plan Templates .............................................................................................................................................. 47 Example Plans

  19. Phase Transformations in Confined Nanosystems

    SciTech Connect (OSTI)

    Shield, Jeffrey E.; Belashchenko, Kirill

    2014-04-29

    This project discovered that non-equilibrium structures, including chemically ordered structures not observed in bulk systems, form in isolated nanoscale systems. Further, a generalized model was developed that effectively explained the suppression of equilibrium phase transformations. This thermodynamic model considered the free energy decrease associated with the phase transformation was less than the increase in energy associated with the formation of an interphase interface, therefore inhibiting the phase transformation. A critical diameter exists where the system transitions to bulk behavior, and a generalized equation was formulated that successfully predicted this transition in the Fe-Au system. This provided and explains a new route to novel structures not possible in bulk systems. The structural characterization was accomplished using transmission electron microscopy in collaboration with Matthew Kramer of Ames Laboratory. The PI and graduate student visited Ames Laboratory several times a year to conduct the experiments.

  20. Filaments in the TGBA phase

    E-Print Network [OSTI]

    Lubor Lejcek; Vladimira Novotna; Milada Glogarova

    2015-08-28

    A model of filaments of the TGBA phase arising from the homeotropic smectic A phase and nucleating on the sample surface is proposed. The model is based on the concept of finite blocks of parallel smectic layers forming a helical structure. The blocks are surrounded by dislocation loops. The model describes the filament structure near the sample surface and explains the observed inclination of the filament axis with respect to the easy direction of the molecular anchoring on the surface. The model is based on the observations of filament textures of the TGBA phase in a new chiral liquid crystalline compound, but can be applied for forming of TGBA filaments in any compound. The compression modulus of the compound has been estimated using such parameters as anchoring energy, estimated from the field necessary to transform the structure into the homeotropic smectic A, and the observed filament width.

  1. Geometric phase in Stückelberg interferometry

    E-Print Network [OSTI]

    Lih-King Lim; Jean-Noël Fuchs; Gilles Montambaux

    2014-12-18

    We study the time evolution of a two-dimensional quantum particle exhibiting an energy spectrum, made of two bands, with two Dirac cones, as e.g. in the band structure of a honeycomb lattice. A force is applied such that the particle experiences two Landau-Zener transitions in succession. The adiabatic evolution between the two transitions leads to St\\"uckelberg interferences, due to two possible trajectories in energy space. In addition to well-known dynamical and Stokes phases, the interference pattern reveals a geometric phase which depends on the chirality (winding number) and the mass sign associated to each Dirac cone, as well as on the type of trajectory (parallel or diagonal with respect to the two cones) in parameter space. This geometric phase reveals the coupling between the bands encoded in the structure of the wavefunctions.

  2. Phases of chiral gauge theories

    SciTech Connect (OSTI)

    Appelquist, Thomas [Department of Physics, Yale University, New Haven, Conneticut 06520-8120 (United States)] [Department of Physics, Yale University, New Haven, Conneticut 06520-8120 (United States); Duan, Zhiyong [Department of Physics, Yale University, New Haven, Conneticut 06520-8120 (United States)] [Department of Physics, Yale University, New Haven, Conneticut 06520-8120 (United States); Sannino, Francesco [Department of Physics, Yale University, New Haven, Conneticut 06520-8120 (United States)] [Department of Physics, Yale University, New Haven, Conneticut 06520-8120 (United States)

    2000-06-15

    We discuss the behavior of two non-supersymmetric chiral SU(N) gauge theories, involving fermions in the symmetric and antisymmetric two-index tensor representations respectively. In addition to global anomaly matching, we employ a recently proposed inequality constraint on the number of effective low energy (massless) degrees of freedom of a theory, based on the thermodynamic free energy. Several possible zero temperature phases are consistent with the constraints. A simple picture for the phase structure emerges if these theories choose the phase, consistent with global anomaly matching, that minimizes the massless degree of freedom count defined through the free energy. This idea suggests that confinement with the preservation of the global symmetries through the formation of massless composite fermions is in general not preferred. While our discussion is restricted mainly to bilinear condensate formation, higher dimensional condensates are considered for one case. We conclude by commenting briefly on two related supersymmetric chiral theories. (c) 2000 The American Physical Society.

  3. Phase appearance or disappearance in two-phase flows

    E-Print Network [OSTI]

    Boyer, Edmond

    safety studies. In nuclear reactors, the appearance of vapor around the fuel rods interferes-phase flows. Such models have crucial importance in many industrial areas such as nuclear power plant safety in a large variety of industrial or natural systems involving boiling or condensing fluids, reacting flows

  4. Phase transitions in Ge-Sb phase change materials

    SciTech Connect (OSTI)

    Raoux, Simone; Virwani, Kumar; Hitzbleck, Martina; Salinga, Martin; Madan, Anita; Pinto, Teresa L.

    2009-03-15

    Thin films of the phase change material Ge-Sb with Ge concentrations between 7.3 and 81.1 at. % were deposited by cosputtering from elemental targets. Their crystallization behavior was studied using time-resolved x-ray diffraction, Auger electron spectroscopy, differential scanning calorimetry, x-ray reflectivity, profilometry, optical reflectivity, and resistivity versus temperature measurements. It was found that the crystallization temperature increases with Ge content. Calculations of the glass transition temperature (which is a lower limit for the crystallization temperature T{sub x}) also show an increase with Ge concentration closely tracking the measured values of T{sub x}. For low Ge content samples, Sb x-ray diffraction peaks occurred during a heating ramp at lower temperature than Ge diffraction peaks. The appearance of Ge peaks is related to Ge precipitation and agglomeration. For Ge concentrations of 59.3 at. % and higher, Sb and Ge peaks occurred at the same temperature. Upon crystallization, film mass density and optical reflectivity increase as well as electrical contrast (ratio of resistivity in amorphous phase to crystalline phase) all showed a maximum for the eutectic alloy (14.5 at. % Ge). For the alloy with 59.3 at. % Ge there was very little change in any of these parameters, while the alloy with 81.1 at. % Ge behaved opposite to a typical phase change alloy and showed reduced mass density and reflectivity and increased resistivity.

  5. Geometric phases in quantum information

    E-Print Network [OSTI]

    Erik Sjöqvist

    2015-03-16

    The rise of quantum information science has opened up a new venue for applications of the geometric phase (GP), as well as triggered new insights into its physical, mathematical, and conceptual nature. Here, we review this development by focusing on three main themes: the use of GPs to perform robust quantum computation, the development of GP concepts for mixed quantum states, and the discovery of a new type of topological phases for entangled quantum systems. We delineate the theoretical development as well as describe recent experiments related to GPs in the context of quantum information.

  6. Hydrodynamics and phases of flocks

    SciTech Connect (OSTI)

    Toner, John [Institute of Theoretical Science, Department of Physics, University of Oregon, Eugene, OR 97403-5203 (United States); Tu Yuhai [IBM T. J. Watson Research Center, P.O. Box 218, Yorktown Heights, NY 10598 (United States)]. E-mail: yuhai@us.ibm.com; Ramaswamy, Sriram [Centre for Condensed Matter Theory, Department of Physics, Indian Institute of Science, Bangalore 560012 (India)

    2005-07-01

    We review the past decade's theoretical and experimental studies of flocking: the collective, coherent motion of large numbers of self-propelled 'particles' (usually, but not always, living organisms). Like equilibrium condensed matter systems, flocks exhibit distinct 'phases' which can be classified by their symmetries. Indeed, the phases that have been theoretically studied to date each have exactly the same symmetry as some equilibrium phase (e.g., ferromagnets, liquid crystals). This analogy with equilibrium phases of matter continues in that all flocks in the same phase, regardless of their constituents, have the same 'hydrodynamic'-that is, long-length scale and long-time behavior, just as, e.g., all equilibrium fluids are described by the Navier-Stokes equations. Flocks are nonetheless very different from equilibrium systems, due to the intrinsically nonequilibrium self-propulsion of the constituent 'organisms'. This difference between flocks and equilibrium systems is most dramatically manifested in the ability of the simplest phase of a flock, in which all the organisms are, on average moving in the same direction (we call this a 'ferromagnetic' flock; we also use the terms 'vector-ordered' and 'polar-ordered' for this situation) to exist even in two dimensions (i.e., creatures moving on a plane), in defiance of the well-known Mermin-Wagner theorem of equilibrium statistical mechanics, which states that a continuous symmetry (in this case, rotation invariance, or the ability of the flock to fly in any direction) can not be spontaneously broken in a two-dimensional system with only short-ranged interactions. The 'nematic' phase of flocks, in which all the creatures move preferentially, or are simply oriented preferentially, along the same axis, but with equal probability of moving in either direction, also differs dramatically from its equilibrium counterpart (in this case, nematic liquid crystals). Specifically, it shows enormous number fluctuations, which actually grow with the number of organisms faster than the N 'law of large numbers' obeyed by virtually all other known systems. As for equilibrium systems, the hydrodynamic behavior of any phase of flocks is radically modified by additional conservation laws. One such law is conservation of momentum of the background fluid through which many flocks move, which gives rise to the 'hydrodynamic backflow' induced by the motion of a large flock through a fluid. We review the theoretical work on the effect of such background hydrodynamics on three phases of flocks-the ferromagnetic and nematic phases described above, and the disordered phase in which there is no order in the motion of the organisms. The most surprising prediction in this case is that 'ferromagnetic' motion is always unstable for low Reynolds-number suspensions. Experiments appear to have seen this instability, but a quantitative comparison is awaited. We conclude by suggesting further theoretical and experimental work to be done.

  7. HYPERBOLIC SYSTEMS OF THREE-PHASE FLOW

    E-Print Network [OSTI]

    Patzek, Tadeusz W.

    HYPERBOLIC SYSTEMS OF THREE-PHASE FLOW IN POROUS MEDIA Gordon Conference on Flow and Transport SINTEF IKT, Dept. Applied Mathematics, Norway #12;2 WHY THREE-PHASE FLOW + Three-phase flow is the rule: ! Exceptionally accurate, fast numerical solutions to realistic three-phase flows in porous media + Approach

  8. Entanglement in Topological Phases August 31, 2012

    E-Print Network [OSTI]

    California at Los Angles, University of

    they are invariant of the space- time metric. Topological phases are interesting and rele- vant because

  9. Reference Phase of Fresnel Zone Plates

    E-Print Network [OSTI]

    G. W. Webb

    2003-02-28

    The standard zone plate assumes that the shortest ray connecting a radiation source and a detection point has a phase of 0 deg thereby defining a reference phase. Here we examine the experimental consequences of varying this reference phase from 0 deg to 360 deg. It is concluded that reference phase is an intrinsic and useful property of zone plates.

  10. CO2 Capture and Regeneration at Low Temperatures: Novel Non-Aqueous CO2 Solvents and Capture Process with Substantially Reduced Energy Penalties

    SciTech Connect (OSTI)

    None

    2010-07-01

    IMPACCT Project: RTI is developing a solvent and process that could significantly reduce the temperature associated with regenerating solvent and CO2 captured from the exhaust gas of coal-fired power plants. Traditional CO2 removal processes using water-based solvents require significant amount of steam from power plants in order to regenerate the solvent so it can be reused after each reaction. RTI’s solvents can be better at absorbing CO2 than many water-based solvents, and are regenerated at lower temperatures using less steam. Thus, industrial heat that is normally too cool to re-use can be deployed for regeneration, rather than using high-value steam. This saves the power plant money, which results in increased cost savings for consumers.

  11. Rheology of cholesteric blue phases

    E-Print Network [OSTI]

    A. Dupuis; D. Marenduzzo; E. Orlandini; J. M. Yeomans

    2006-05-11

    Blue phases of cholesteric liquid crystals offer a spectacular example of naturally occurring disclination line networks. Here we numerically solve the hydrodynamic equations of motion to investigate the response of three types of blue phases to an imposed Poiseuille flow. We show that shear forces bend and twist and can unzip the disclination lines. Under gentle forcing the network opposes the flow and the apparent viscosity is significantly higher than that of an isotropic liquid. With increased forcing we find strong shear thinning corresponding to the disruption of the defect network. As the viscosity starts to drop, the imposed flow sets the network into motion. Disclinations break-up and re-form with their neighbours in the flow direction. This gives rise to oscillations in the time-dependent measurement of the average stress.

  12. Light-driven phase shifter

    DOE Patents [OSTI]

    Early, James W. (Los Alamos, NM)

    1990-01-01

    A light-driven phase shifter is provided for modulating a transmission light beam. A gaseous medium such as argon is provided with electron energy states excited to populate a metastable state. A tunable dye laser is selected with a wavelength effective to deplete the metastable electron state and may be intensity modulated. The dye laser is directed through the gaseous medium to define a first optical path having an index of refraction determined by the gaseous medium having a depleted metastable electron state. A transmission laser beam is also directed through the gaseous medium to define a second optical path at least partially coincident with the first optical path. The intensity of the dye laser beam may then be varied to phase modulate the transmission laser beam.

  13. Color Dynamics On Phase Space

    E-Print Network [OSTI]

    A. Bonasera

    2000-03-09

    We describe the properties of quark matter at zero temperature and finite baryon densities within microscopic Vlasov/molecular dynamics approaches. We use an inter-quark Richardson's potential consistent with the indications of Lattice QCD calculations. The color degrees of freedom are explicitly taken into account. We explicitly demonstrate that the Vlasov approach alone is insufficient in the hadronization region. In order to overcome this problem we prepare the initial condition for many events using molecular dynamics with frictional cooling and a Thomas-Fermi approximation to the Fermi motion. These events are averaged and propagated in time using the Vlasov approach. We find some evidence for a second order phase transition from nuclear to quark matter at high baryon densities. An order parameter suitable to describe the phase transition is discussed. At low densities the quark condensate into approximately color white clusters (nucleon).

  14. Fiber bundle phase conjugate mirror

    DOE Patents [OSTI]

    Ward, Benjamin G.

    2012-05-01

    An improved method and apparatus for passively conjugating the phases of a distorted wavefronts resulting from optical phase mismatch between elements of a fiber laser array are disclosed. A method for passively conjugating a distorted wavefront comprises the steps of: multiplexing a plurality of probe fibers and a bundle pump fiber in a fiber bundle array; passing the multiplexed output from the fiber bundle array through a collimating lens and into one portion of a non-linear medium; passing the output from a pump collection fiber through a focusing lens and into another portion of the non-linear medium so that the output from the pump collection fiber mixes with the multiplexed output from the fiber bundle; adjusting one or more degrees of freedom of one or more of the fiber bundle array, the collimating lens, the focusing lens, the non-linear medium, or the pump collection fiber to produce a standing wave in the non-linear medium.

  15. Disposal phase experimental program plan

    SciTech Connect (OSTI)

    1997-01-31

    The Waste Isolation Pilot Plant (WIPP) facility comprises surface and subsurface facilities, including a repository mined in a bedded salt formation at a depth of 2,150 feet. It has been developed to safely and permanently isolate transuranic (TRU) radioactive wastes in a deep geological disposal site. On April 12, 1996, the DOE submitted a revised Resource Conservation and Recovery Act (RCRA) Part B permit application to the New Mexico Environment Department (NMED). The DOE anticipates receiving an operating permit from the NMED; this permit is required prior to the start of disposal operations. On October 29, 1996, the DOE submitted a Compliance Certification Application (CCA) to the US Environmental Protection Agency (EPA) in accordance with the WIPP land Withdrawal Act (LWA) of 1992 (Public Law 102-579) as amended, and the requirements of Title 40 of the Code of Federal Regulations (40 CFR) Parts 191 and 194. The DOE plans to begin disposal operations at the WIPP in November 1997 following receipt of certification by the EPA. The disposal phase is expected to last for 35 years, and will include recertification activities no less than once every five years. This Disposal Phase Experimental Program (DPEP) Plan outlines the experimental program to be conducted during the first 5-year recertification period. It also forms the basis for longer-term activities to be carried out throughout the 35-year disposal phase. Once the WIPP has been shown to be in compliance with regulatory requirements, the disposal phase gives an opportunity to affirm the compliance status of the WIPP, enhance the operations of the WIPP and the national TRU system, and contribute to the resolution of national and international nuclear waste management technical needs. The WIPP is the first facility of its kind in the world. As such, it provides a unique opportunity to advance the technical state of the art for permanent disposal of long-lived radioactive wastes.

  16. Phase comparator apparatus and method

    DOE Patents [OSTI]

    Coffield, F.E.

    1985-02-01

    This invention finds especially useful application for interferometer measurements made in plasma fusion devices (e.g., for measuring the line integral of electron density in the plasma). Such interferometers typically use very high intermediate frequencies (e.g., on the order of 10 to 70 MHz) and therefore the phase comparison circuitry should be a high speed circuit with a linear transfer characteristic so as to accurately differentiate between small fractions of interference fringes.

  17. Final Report: Sensorpedia Phase 3

    SciTech Connect (OSTI)

    Gorman, Bryan L [ORNL; Resseguie, David R [ORNL

    2011-02-01

    This report is a summary of the Oak Ridge National Laboratory s (ORNL s) Phase 3 development of Sensorpedia, a sensor information sharing platform. Sensorpedia is ORNL s Wikipedia for Sensors. The overall goal of Sensorpedia is to enable global scale sensor information sharing for scientific research, national security and defense, public health and safety, emergency preparedness and response, and general community awareness and outreach.

  18. Phase change material storage heater

    DOE Patents [OSTI]

    Goswami, D. Yogi (Gainesville, FL); Hsieh, Chung K. (Gainesville, FL); Jotshi, Chand K. (Gainesville, FL); Klausner, James F. (Gainesville, FL)

    1997-01-01

    A storage heater for storing heat and for heating a fluid, such as water, has an enclosure defining a chamber therein. The chamber has a lower portion and an upper portion with a heating element being disposed within the enclosure. A tube through which the fluid flows has an inlet and an outlet, both being disposed outside of the enclosure, and has a portion interconnecting the inlet and the outlet that passes through the enclosure. A densely packed bed of phase change material pellets is disposed within the enclosure and is surrounded by a viscous liquid, such as propylene glycol. The viscous liquid is in thermal communication with the heating element, the phase change material pellets, and the tube and transfers heat from the heating element to the pellets and from the pellets to the tube. The viscous fluid has a viscosity so that the frictional pressure drop of the fluid in contact with the phase change material pellets substantially reduces vertical thermal convection in the fluid. As the fluid flows through the tube heat is transferred from the viscous liquid to the fluid flowing through the tube, thereby heating the fluid.

  19. QCD Phase Transitions, Volume 15

    SciTech Connect (OSTI)

    Schaefer, T.; Shuryak, E.

    1999-03-20

    The title of the workshop, ''The QCD Phase Transitions'', in fact happened to be too narrow for its real contents. It would be more accurate to say that it was devoted to different phases of QCD and QCD-related gauge theories, with strong emphasis on discussion of the underlying non-perturbative mechanisms which manifest themselves as all those phases. Before we go to specifics, let us emphasize one important aspect of the present status of non-perturbative Quantum Field Theory in general. It remains true that its studies do not get attention proportional to the intellectual challenge they deserve, and that the theorists working on it remain very fragmented. The efforts to create Theory of Everything including Quantum Gravity have attracted the lion share of attention and young talent. Nevertheless, in the last few years there was also a tremendous progress and even some shift of attention toward emphasis on the unity of non-perturbative phenomena. For example, we have seen some efforts to connect the lessons from recent progress in Supersymmetric theories with that in QCD, as derived from phenomenology and lattice. Another example is Maldacena conjecture and related development, which connect three things together, string theory, super-gravity and the (N=4) supersymmetric gauge theory. Although the progress mentioned is remarkable by itself, if we would listen to each other more we may have chance to strengthen the field and reach better understanding of the spectacular non-perturbative physics.

  20. Ponderomotive phase plate for transmission electron microscopes

    DOE Patents [OSTI]

    Reed, Bryan W. (Livermore, CA)

    2012-07-10

    A ponderomotive phase plate system and method for controllably producing highly tunable phase contrast transfer functions in a transmission electron microscope (TEM) for high resolution and biological phase contrast imaging. The system and method includes a laser source and a beam transport system to produce a focused laser crossover as a phase plate, so that a ponderomotive potential of the focused laser crossover produces a scattering-angle-dependent phase shift in the electrons of the post-sample electron beam corresponding to a desired phase contrast transfer function.

  1. Confined Cubic Blue Phases under Shear

    E-Print Network [OSTI]

    O. Henrich; K. Stratford; D. Marenduzzo; P. V. Coveney; M. E. Cates

    2012-03-14

    We study the behaviour of confined cubic blue phases under shear flow via lattice Boltzmann simulations. We focus on the two experimentally observed phases, blue phase I and blue phase II. The disinclination network of blue phase II continuously breaks and reforms under shear, leading to an oscillatory stress response in time. The oscillations are only regular for very thin samples. For thicker samples, the shear leads to a "stick-slip" motion of part of the network along the vorticity direction. Blue phase I responds very differently: its defect network undergoes seemingly chaotic rearrangements under shear, irrespective of system size.

  2. Experimental phasing for structure determination using membrane...

    Office of Scientific and Technical Information (OSTI)

    in the literature concerning the experimental heavy-atom phasing of membrane-protein structures where the crystals have been grown using the lipid cubic phase (in meso) method. In...

  3. Science Learning+: Phase 1 projects Science Learning+

    E-Print Network [OSTI]

    Rambaut, Andrew

    Science Learning+: Phase 1 projects Science Learning+ Phase 1 projects 2 December 2014 #12..............................................................................................................4 Youth access and equity in informal science learning: developing a research and practice agenda..................................................................................................5 Enhancing informal learning through citizen science..............................................6

  4. Phases of holographic d-wave superconductor

    E-Print Network [OSTI]

    Krikun, Alexander

    2015-01-01

    We study different phases in the holographic model of d-wave superconductor. These are described by solutions to the classical equations of motion found in different ansatze. Apart from the known homogeneous d-wave superconducting phase we find three new solutions. Two of them represent two distinct families of the spatially modulated solutions, which realize the charge density wave phases in the dual theory. The third one is the new homogeneous phase with nonzero anapole moment. These phases are relevant to the physics of cuprate high-Tc superconductor in pseudogap region. While the d-wave phase preserves translation, parity and time reversal symmetry, the striped phases break translations spontaneously. Parity and time-reversal are preserved when combined with discrete half-periodic shift of the wave. In anapole phase translation symmetry is preserved, but parity and time reversal are spontaneously broken. All of the considered solutions brake the global $U(1)$. Thermodynamical treatment shows that in the s...

  5. Phase Transitions in the Early Universe

    E-Print Network [OSTI]

    Wainwright, Carroll Livingston

    2013-01-01

    Phase Transitions in the Early Universe by Carroll L.and computation of early-Universe finite-temperature phaseM. S. Turner, “The Early universe,” Front. Phys. 69 (1990)

  6. PERFORMANCE ENHANCEMENT TECHNIQUES FOR PHASED LOGIC CIRCUITS

    E-Print Network [OSTI]

    Thornton, Mitchell

    , these mechanims have been added to Phased Logic circuits by ad-hoc and manual means that require a designers

  7. Vapor phase modifiers for oxidative coupling

    DOE Patents [OSTI]

    Warren, Barbara K. (Charleston, WV)

    1991-01-01

    Volatilized metal compounds retard vapor phase alkane conversion reactions in oxidative coupling processes that convert lower alkanes to higher hydrocarbons.

  8. Catalyst and method for aqueous phase reactions

    DOE Patents [OSTI]

    Elliott, Douglas C. (Richland, WA); Hart, Todd R. (Kennewick, WA)

    1999-01-01

    The present invention is a catalyst in the form of a plurality of porous particles wherein each particle is a support having nickel metal catalytic phase or reduced nickel deposited thereon in a first dispersed phase and an additional metal deposited onto the support in a second dispersed phase. The additional metal is effective in retarding or reducing agglomeration or sintering of the nickel metal catalytic phase without substantially affecting the catalytic activity, thereby increasing the life time of the catalyst.

  9. On ferrimagnetic phases in chiral Yukawa models

    E-Print Network [OSTI]

    J. L. Alonso; Ph. Boucaud; A. J. van der Sijs

    1995-03-07

    We discuss the phase structure of chiral Yukawa models in the mean-field approximation. In particular, we examine under which conditions a ferrimagnetic phase appears, by calculating the slopes of possible second order phase transition lines near a critical point. Our results contrast with some statements which appeared in the literature recently.

  10. Centrifuge workers study. Phase II, completion report

    SciTech Connect (OSTI)

    Wooten, H.D.

    1994-09-01

    Phase II of the Centrifuge Workers Study was a follow-up to the Phase I efforts. The Phase I results had indicated a higher risk than expected among centrifuge workers for developing bladder cancer when compared with the risk in the general population for developing this same type of cancer. However, no specific agent could be identified as the causative agent for these bladder cancers. As the Phase II Report states, Phase I had been limited to workers who had the greatest potential for exposure to substances used in the centrifuge process. Phase II was designed to expand the survey to evaluate the health of all employees who had ever worked in Centrifuge Program Departments 1330-1339 but who had not been interviewed in Phase I. Employees in analytical laboratories and maintenance departments who provided support services for the Centrifuge Program were also included in Phase II. In December 1989, the Oak Ridge Associated Universities (ORAU), now known as Oak Ridge Institute for Science and Education (ORISE), was contracted to conduct a follow-up study (Phase II). Phase H of the Centrifuge Workers Study expanded the survey to include all former centrifuge workers who were not included in Phase I. ORISE was chosen because they had performed the Phase I tasks and summarized the corresponding survey data therefrom.

  11. Geometric phases of water waves

    E-Print Network [OSTI]

    Francesco Fedele

    2014-08-08

    Recently, Banner et al. (2014) highlighted a new fundamental property of open ocean wave groups, the so-called crest slowdown. For linear narrowband waves, this is related to the geometric and dynamical phase velocities $U_d$ and $U_g$ associated with the parallel transport through the principal fiber bundle of the wave motion with $\\mathit{U}(1)$ symmetry. The theoretical predictions are shown to be in fair agreement with ocean field observations, from which the average crest speed $c=U_d+U_g$ with $c/U_d\\approx0.8$ and $U_{g}/U_d\\approx-0.2$.

  12. Reliability in the design phase

    SciTech Connect (OSTI)

    Siahpush, A.S.; Hills, S.W.; Pham, H. (EG and G Idaho, Inc., Idaho Falls, ID (United States)); Majumdar, D. (USDOE Idaho Field Office, Idaho Falls, ID (United States))

    1991-12-01

    A study was performed to determine the common methods and tools that are available to calculated or predict a system's reliability. A literature review and software survey are included. The desired product of this developmental work is a tool for the system designer to use in the early design phase so that the final design will achieve the desired system reliability without lengthy testing and rework. Three computer programs were written which provide the first attempt at fulfilling this need. The programs are described and a case study is presented for each one. This is a continuing effort which will be furthered in FY-1992. 10 refs.

  13. Reliability in the design phase

    SciTech Connect (OSTI)

    Siahpush, A.S.; Hills, S.W.; Pham, H. [EG and G Idaho, Inc., Idaho Falls, ID (United States); Majumdar, D. [USDOE Idaho Field Office, Idaho Falls, ID (United States)

    1991-12-01

    A study was performed to determine the common methods and tools that are available to calculated or predict a system`s reliability. A literature review and software survey are included. The desired product of this developmental work is a tool for the system designer to use in the early design phase so that the final design will achieve the desired system reliability without lengthy testing and rework. Three computer programs were written which provide the first attempt at fulfilling this need. The programs are described and a case study is presented for each one. This is a continuing effort which will be furthered in FY-1992. 10 refs.

  14. Solid phase microextraction field kit

    DOE Patents [OSTI]

    Nunes, Peter J.; Andresen, Brian D.

    2005-08-16

    A field kit for the collection, isolation and concentration of trace amounts of high explosives (HE), biological weapons (BW) and chemical weapons (CW) residues in air, soil, vegetation, swipe, and liquid samples. The field kit includes a number of Solid Phase Microextraction (SPME) fiber and syringe assemblies in a hermetically sealed transportation container or tubes which includes a sampling port, a number of extra SPME fiber and syringe assemblies, the fiber and syringe assemblies including a protective cap for the fiber, and an extractor for the protective cap, along with other items including spare parts, protective glove, and an instruction manual, all located in an airtight container.

  15. Three phase AC motor controller

    DOE Patents [OSTI]

    Vuckovich, Michael (Elizabeth, PA); Wright, Maynard K. (Bethel Park, PA); Burkett, John P. (South Huntington Township, Westmoreland County, PA)

    1984-03-20

    A motor controller for a three phase AC motor (10) which is adapted to operate bidirectionally from signals received either from a computer (30) or a manual control (32). The controller is comprised of digital logic circuit means which implement a forward and reverse command signal channel (27, 29) for the application of power through the forward and reverse power switching relays (16, 18, 20, 22). The digital logic elements are cross coupled to prevent activation of both channels simultaneously and each includes a plugging circuit (65, 67) for stopping the motor upon the removal of control signal applied to one of the two channels (27, 29) for a direction of rotation desired. Each plugging circuit (65, 67) includes a one-shot pulse signal generator (88, 102) which outputs a single pulse signal of predetermined pulsewidth which is adapted to inhibit further operation of the application of power in the channel which is being activated and to apply a reversal command signal to the other channel which provides a reversed phase application of power to the motor for a period defined by the pulse-width output of the one-shot signal generator to plug the motor (10) which will then be inoperative until another rotational command signal is applied to either of the two channels.

  16. Frequency spectrum analyzer with phase-lock

    DOE Patents [OSTI]

    Boland, Thomas J. (Idaho Falls, ID)

    1984-01-01

    A frequency-spectrum analyzer with phase-lock for analyzing the frequency and amplitude of an input signal is comprised of a voltage controlled oscillator (VCO) which is driven by a ramp generator, and a phase error detector circuit. The phase error detector circuit measures the difference in phase between the VCO and the input signal, and drives the VCO locking it in phase momentarily with the input signal. The input signal and the output of the VCO are fed into a correlator which transfers the input signal to a frequency domain, while providing an accurate absolute amplitude measurement of each frequency component of the input signal.

  17. Phase clustering and transition to phase synchronization in a large number of coupled nonlinear oscillators

    E-Print Network [OSTI]

    Lai, Ying-Cheng

    Phase clustering and transition to phase synchronization in a large number of coupled nonlinear received 22 November 2000; published 9 April 2001 The transition to phase synchronization in systems of average frequency marks the disappearance of one phase cluster 7 . In this Rapid Com- munication, we

  18. A Longitudinal Assessment of Sleep Timing, Circadian Phase, and Phase Angle of Entrainment across Human

    E-Print Network [OSTI]

    A Longitudinal Assessment of Sleep Timing, Circadian Phase, and Phase Angle of Entrainment across of this descriptive analysis was to examine sleep timing, circadian phase, and phase angle of entrainment across of Entrainment across Human Adolescence. PLoS ONE 9(11): e112199. doi:10.1371/journal.pone.0112199 Editor: Steven

  19. Electric field controlled emulsion phase contactor

    DOE Patents [OSTI]

    Scott, Timothy C. (Knoxville, TN)

    1995-01-01

    A system for contacting liquid phases comprising a column for transporting a liquid phase contacting system, the column having upper and lower regions. The upper region has a nozzle for introducing a dispersed phase and means for applying thereto a vertically oriented high intensity pulsed electric field. This electric field allows improved flow rates while shattering the dispersed phase into many micro-droplets upon exiting the nozzle to form a dispersion within a continuous phase. The lower region employs means for applying to the dispersed phase a horizontally oriented high intensity pulsed electric field so that the dispersed phase undergoes continuous coalescence and redispersion while being urged from side to side as it progresses through the system, increasing greatly the mass transfer opportunity.

  20. Electric field controlled emulsion phase contactor

    DOE Patents [OSTI]

    Scott, T.C.

    1995-01-31

    A system is described for contacting liquid phases comprising a column for transporting a liquid phase contacting system, the column having upper and lower regions. The upper region has a nozzle for introducing a dispersed phase and means for applying thereto a vertically oriented high intensity pulsed electric field. This electric field allows improved flow rates while shattering the dispersed phase into many micro-droplets upon exiting the nozzle to form a dispersion within a continuous phase. The lower region employs means for applying to the dispersed phase a horizontally oriented high intensity pulsed electric field so that the dispersed phase undergoes continuous coalescence and redispersion while being urged from side to side as it progresses through the system, increasing greatly the mass transfer opportunity. 5 figs.

  1. Flexoelectric switching in cholesteric blue phases

    E-Print Network [OSTI]

    A. Tiribocchi; M. E. Cates; G. Gonnella; D. Marenduzzo; E. Orlandini

    2013-03-25

    We present computer simulations of the response of a flexoelectric blue phase network, either in bulk or under confinement, to an applied field. We find a transition in the bulk between the blue phase I disclination network and a parallel array of disclinations along the direction of the applied field. Upon switching off the field, the system is unable to reconstruct the original blue phase but gets stuck in a metastable phase. Blue phase II is comparatively much less affected by the field. In confined samples, the anchoring at the walls and the geometry of the device lead to the stabilisation of further structures, including field-aligned disclination loops, splayed nematic patterns, and yet more metastable states. Our results are relevant to the understanding of the switching dynamics for a class of new, "superstable", blue phases which are composed of bimesogenic liquid crystals, as these materials combine anomalously large flexoelectric coefficients, and low or near-zero dielectric anisotropy.

  2. Pore-scale analysis of thermal remediation of NAPL-contaminated subsurface environments 

    E-Print Network [OSTI]

    Ahn, Min

    2009-05-15

    to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of DOCTOR OF PHILOSOPHY Approved by: Chair of Committee, Yavuz Corapcioglu Committee Members, Hamn-Ching Chen Hongbin Zhan Eyad... but also enhanced my insight of what water resources engineering is and what role we play as water resources engineers. I am very honored to be his student. I am also especially grateful to my committee members: Dr. Hongbin Zhan, Dr. Hamn-Ching Chen...

  3. Imaging the Angevin Patron Saint: Mary Magdalen in the Pipino Chapel in Naples

    E-Print Network [OSTI]

    Wilkins, Sarah S.

    2012-01-01

    by Cordelia Warr and Janis Elliot, 152-175. Malden: Wiley-by Cordelia Warr and Janis Elliot, 38-61. Malden: Wiley-Warr, Cordelia, and Janis Elliot, eds. Art and Architecture

  4. From Propaganda to Science: Looking at the World of Academies in Early Seventeenth-century Naples

    E-Print Network [OSTI]

    Gianfrancesco, Lorenza

    2012-01-01

    academica dell’incendio e terremoto di Somma fatta nell’academica dell’incendio e terremoto di Somma fatta nell’

  5. An experimental study of horizontal barrier formation and containment of NAPLs by gelling liquids 

    E-Print Network [OSTI]

    Durmusoglu, Ertan

    1997-01-01

    reductions will be carried out in the one-dimensional columns. After an impervious layer is produced, durability of the grouted porous media in the presence of typical contaminants will be investigated. The proposed research aims at the testing of techniques...

  6. Imaging the Angevin Patron Saint: Mary Magdalen in the Pipino Chapel in Naples

    E-Print Network [OSTI]

    Wilkins, Sarah S.

    2012-01-01

    Storico Italiano per il Medio Evo, l’U.M.R. Telemme et l’Storico Italiano per il Medio Evo, l’U.M.R. Telemme et l’

  7. 2014 FLORIDA TOMATO INSTITUTE PROGRAM The Ritz-Carlton Golf Resort, Naples, Florida

    E-Print Network [OSTI]

    Florida, University of

    climatic, hydrologic, and agronomic factors to phosphorous transport from plastic mulch beds - Sanjay

  8. Imaging the Angevin Patron Saint: Mary Magdalen in the Pipino Chapel in Naples

    E-Print Network [OSTI]

    Wilkins, Sarah S.

    2012-01-01

    39.1-4). The scope of the dedication is unclear, as it wasadopted the Magdalen dedication. This is generally supportedis skeptical of a general dedication to the Magdalen and is

  9. Microsoft Word - DOE_RM_DM-#100069-v1-NAPL_Quarterly_Oct-Dec_2004.DOC

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-SessionsSouth DakotaRobbins and MyersHr. Anthony V.How DisposalInterim1 U.S.

  10. Microsoft Word - DOE_RM_DM-#341474-v1-NAPL_Quarterly_April_-_June_2005.DOC

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-SessionsSouth DakotaRobbins and MyersHr. Anthony V.How DisposalInterim166 2005

  11. Microsoft Word - DOE_RM_DM-#345139-v1-NAPL_Quarterly_Oct-Dec_2005.DOC

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-SessionsSouth DakotaRobbins and MyersHr. Anthony V.How DisposalInterim1661 20055

  12. Microsoft Word - DOE_RM_DM-#350832-v1-NAPL_Quarterly_April-June_2006.DOC

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-SessionsSouth DakotaRobbins and MyersHr. Anthony V.HowJanuary through

  13. Microsoft Word - N0071600-NAPL-Oct to Dec.doc

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-SessionsSouth DakotaRobbins and MyersHr. Anthony5-TAC U.S. Department of

  14. Microsoft Word - N0074600-NAPL-Jan to March.doc

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-SessionsSouth DakotaRobbins and MyersHr. Anthony5-TAC U.S. Department ofJanuary

  15. Successful Field-Scale In Situ Thermal NAPL Remediation at the Young -

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LIST OF APPLICABLEStatutory Authority for anStudy: Algae CouldSubstanceRainey STAR

  16. Project Overview: Successful Field-Scale In Situ Thermal NAPL Remediation |

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on DeliciousMathematicsEnergyInterested PartiesBuildingBudget | DepartmentLogisticalProject Management

  17. Stationary phase deposition based on onium salts

    DOE Patents [OSTI]

    Wheeler, David R. (Albuquerque, NM); Lewis, Patrick R. (Albuquerque, NM); Dirk, Shawn M. (Albuquerque, NM); Trudell, Daniel E. (Albuquerque, NM)

    2008-01-01

    Onium salt chemistry can be used to deposit very uniform thickness stationary phases on the wall of a gas chromatography column. In particular, the stationary phase can be bonded to non-silicon based columns, especially microfabricated metal columns. Non-silicon microfabricated columns may be manufactured and processed at a fraction of the cost of silicon-based columns. In addition, the method can be used to phase-coat conventional capillary columns or silicon-based microfabricated columns.

  18. Environmental Effects on the Geometric Phase

    E-Print Network [OSTI]

    A. C. Günhan; S. Turgut; N. K. Pak

    2009-12-25

    The behavior of the geometric phase gained by a single spin-1/2 nucleus immersed into a thermal or a squeezed environment is investigated. Both the time dependence of the phase and its value at infinity are examined against several physical parameters. It is observed that for some intermediate ranges of the temperature and the coupling strength, the presence of squeezing enhances the geometric phase.

  19. OutageMapURL Phases Energy Services

    Open Energy Info (EERE)

    OutageMapURL Phases Energy Services County Electric Power Assn http outages county org A N Electric Coop Virginia AEP Generating Company https www aepaccount com zipr...

  20. Radiological Release Accident Investigation Report (Phase II...

    Broader source: Energy.gov (indexed) [DOE]

    Investigation Report (Phase II Report) More Documents & Publications Central Characterization Program (CCP) Los Alamos National Laboratory (LANL) Interface Document Oak Ridge...

  1. SUSY and the Electroweak Phase Transition

    E-Print Network [OSTI]

    Glennys R. Farrar; Marta Losada

    1996-12-12

    We analyze the effective 3 dimensional theory previously constructed for the MSSM and multi-Higgs models to determine the regions of parameter space in which the electroweak phase transition is sufficiently strong for a $B+L$ asymmetry to survive in the low temperature phase. We find that the inclusion of all supersymmetric scalars and all 1-loop corrections has the effect of enhancing the strength of the phase transition. Without a light stop or extension of the MSSM the phase transition is sufficiently first order only if the lightest Higgs mass $M_{h}\\lsi 70$ GeV and $tan\\beta\\lsi 1.75$.

  2. WIPP Radiological Relase Report Phase 2

    Office of Environmental Management (EM)

    Phase 2 Radiological Release Event at the Waste Isolation Pilot Plant, February 14, 2014 April 2015 Radiological Release Event at the Waste Isolation Pilot Plant Radiological...

  3. WIPP Radiological Release Report Phase 1

    Office of Environmental Management (EM)

    Phase 1 Radiological Release Event at the Waste Isolation Pilot Plant on February 14, 2014 April 2014 Radiological Release Event at the Waste Isolation Pilot Plant Radiological...

  4. Vapor phase modifiers for oxidative coupling

    DOE Patents [OSTI]

    Warren, B.K.

    1991-12-17

    Volatilized metal compounds are described which are capable of retarding vapor phase alkane conversion reactions in oxidative coupling processes that convert lower alkanes to higher hydrocarbons.

  5. X-ray phase-contrast methods

    SciTech Connect (OSTI)

    Lider, V. V., E-mail: lider@ns.crys.ras.ru; Kovalchuk, M. V. [Russian Academy of Sciences, Shubnikov Institute of Crystallography (Russian Federation)] [Russian Academy of Sciences, Shubnikov Institute of Crystallography (Russian Federation)

    2013-11-15

    This review is devoted to a comparative description of the methods for forming X-ray phase-contrast images of weakly absorbing (phase) objects. These include the crystal interferometer method, the Talbot interferometer method, diffraction-enhanced X-ray imaging, and the in-line method. The potential of their practical application in various fields of science and technology is discussed. The publications on the development and optimization of X-ray phase-contrast methods and the experimental study of phase objects are analyzed.

  6. Geometric phases in a scattering process

    SciTech Connect (OSTI)

    Liu, H. D.; Yi, X. X. [School of Physics and Optoelectronic Technology, Dalian University of Technology, Dalian 116024 (China)

    2011-08-15

    The study of geometric phase in quantum mechanics has so far been confined to discrete (or continuous) spectra and trace-preserving evolutions. By considering only the transmission channel, a scattering process with internal degrees of freedom is neither a discrete spectrum problem nor a trace-preserving process. We explore the geometric phase in the scattering process by taking only the transmission process into account. We find that the geometric phase can be calculated by the same method as in unitary evolution. The interference visibility depends on the transmission amplitude. The dependence of the geometric phase on the barrier strength and the spin-spin coupling constant is also presented and discussed.

  7. Double acting stirling engine phase control

    SciTech Connect (OSTI)

    Berchowitz, David M.

    1983-01-01

    A mechanical device for effecting a phase change between the expansion and compression volumes of a double-acting Stirling engine uses helical elements which produce opposite rotation of a pair of crankpins when a control rod is moved, so the phase between two pairs of pistons is changed by +.psi. and the phase between the other two pairs of pistons is changed by -.psi.. The phase can change beyond .psi.=90.degree. at which regenerative braking and then reversal of engine rotation occurs.

  8. SYNCHEM feasibility report: Phase 1

    SciTech Connect (OSTI)

    Not Available

    1995-01-01

    Several Czech and US companies have entered into a development agreement for the purposes of determining the technical and economic feasibility and overall financeability of an integrated gasification combined cycle (IGCC) regional energy facility to be located adjacent to the Chemopetrol refinery in Litvinov, Czech Republic. The Project would use a feedstock comprised of coal supplied by Doly a upravny Komorany s.p. (DUK) coal mining company and mined from the Most/Litvinov area together with high sulfur residual oils from the Chemopetrol refinery. When gasified together with oxygen from an Air Products air separation plant, and based on an average yearly consumption of 2,100K metric tons per year of coal (as delivered) and 630K tonnes per year of oil, approximately 11 million normal cubic meters per day of syngas will be produced. At its current projected design capacity, when combusted in two General Electric advanced technology Frame 9FA gas turbines, the Project will produce approximately 690MW of electric power; 250 metric tons/hour of steam for process; and 135 thermal equivalent MW of district heat. The Feasibility Phase efforts described in this report indicate the real possibility for a successful and profitable IGCC Project for the Czech Republic. It is therefore incumbent upon all the Project Participants to review and evaluate the information contained herein such that a go/no-go decision can be reached by early next year.

  9. Transient liquid phase ceramic bonding

    DOE Patents [OSTI]

    Glaeser, Andreas M. (Berkeley, CA)

    1994-01-01

    Ceramics are joined to themselves or to metals using a transient liquid phase method employing three layers, one of which is a refractory metal, ceramic or alloy. The refractory layer is placed between two metal layers, each of which has a lower melting point than the refractory layer. The three layers are pressed between the two articles to be bonded to form an assembly. The assembly is heated to a bonding temperature at which the refractory layer remains solid, but the two metal layers melt to form a liquid. The refractory layer reacts with the surrounding liquid and a single solid bonding layer is eventually formed. The layers may be designed to react completely with each other and form refractory intermetallic bonding layers. Impurities incorporated into the refractory metal may react with the metal layers to form refractory compounds. Another method for joining ceramic articles employs a ceramic interlayer sandwiched between two metal layers. In alternative embodiments, the metal layers may include sublayers. A method is also provided for joining two ceramic articles using a single interlayer. An alternate bonding method provides a refractory-metal oxide interlayer placed adjacent to a strong oxide former. Aluminum or aluminum alloys are joined together using metal interlayers.

  10. On-demand generation of aqueous two-phase microdroplets with reversible phase transitions

    SciTech Connect (OSTI)

    Boreyko, Jonathan B [ORNL; Mruetusatorn, Prachya [ORNL; Retterer, Scott T [ORNL; Collier, Pat [ORNL

    2013-01-01

    Aqueous two-phase systems contained entirely within microdroplets enable a bottom-up approach to mimicking the dynamic microcompartmentation of biomaterial that naturally occurs within the cytoplasm of cells. Here, we demonstrate the on-demand generation of femtolitre aqueous two-phase droplets within a microfluidic oil channel. Gated pressure pulses were used to generate individual, stationary two-phase microdroplets with a well-defined time zero for carrying out controlled and sequential phase transformations over time. Reversible phase transitions between single-phase, two-phase, and core-shell microgel states were obtained via evaporation-induced dehydration and on-demand water rehydration. In contrast to other microfluidic aqueous two-phase droplets, which require continuous flows and high-frequency droplet formation, our system enables the controlled isolation and reversible transformation of a single microdroplet and is expected to be useful for future studies in dynamic microcompartmentation and affinity partitioning.

  11. Phase-field modeling of the beta to omega phase transformation...

    Office of Scientific and Technical Information (OSTI)

    Phase-field modeling of the beta to omega phase transformation in Zr-Nb alloys Authors: Yeddu, Hemantha Kumar 1 ; Lookman, Turab 1 + Show Author Affiliations Los Alamos...

  12. Master Thesis Phase-field Modeling of

    E-Print Network [OSTI]

    Cambridge, University of

    University of Science and Technology 2010 #12;II Phase-field Modeling of Crystal Growth during-field Modeling of Crystal Growth during Deformation Department of Ferrous Technology (Computational MetallurgyI Master Thesis Phase-field Modeling of Crystal Growth during Deformation Tan Xu

  13. Gas-Phase Spectroscopy of Biomolecular

    E-Print Network [OSTI]

    de Vries, Mattanjah S.

    Gas-Phase Spectroscopy of Biomolecular Building Blocks Mattanjah S. de Vries1 and Pavel Hobza2 1, REMPI, computational chemistry, spectral hole burning, jet cooling Abstract Gas-phase spectroscopy lends. In recent years, we have seen enormous progress in the study of biomolecular building blocks in the gas

  14. Phase Transition Behavior: from Decision to Optimization

    E-Print Network [OSTI]

    Walsh, Toby

    Phase Transition Behavior: from Decision to Optimization John Slaney Australian National University, therefore, that insights into decision problems gained by studying phase transition behavior could be useful is a rapid increase in problem diÆculty. The random 2-Sat transition is continuous (or \\2nd order

  15. Quantum Phase Transitions in a Finite System

    E-Print Network [OSTI]

    A. Leviatan

    2006-12-05

    A general procedure for studying finite-N effects in quantum phase transitions of finite systems is presented and applied to the critical-point dynamics of nuclei undergoing a shape-phase transition of second-order (continuous), and of first-order with an arbitrary barrier.

  16. Renewable Energy Transmission Initiative Phase 1A

    E-Print Network [OSTI]

    Renewable Energy Transmission Initiative Phase 1A DRAFT REPORT MARCH 2008 RETI-1000-2008-001-D #12;RETI Stakeholder Steering Committee Renewable Energy Transmission Initiative Phase 1A DRAFT REPORT B are registered trademarks of Black & Veatch Holding Company #12;RETI Stakeholder Steering Committee Renewable

  17. A low phase noise ring oscillator phase-locked loop for wireless applications

    E-Print Network [OSTI]

    Weltin-Wu, Colin

    2005-01-01

    This thesis describes the circuit level design of a 900MHz [Sigma][Detta] ring oscillator based phase-locked loop using 0.35[mu]m technology. Multiple phase noise theories are considered giving insight into low phase-noise ...

  18. Phase transitions in ZN gauge theory and twisted ZN topological phases

    E-Print Network [OSTI]

    Barkeshli, Maissam

    We find a series of non-Abelian topological phases that are separated from the deconfined phase of Z[subscript N] gauge theory by a continuous quantum phase transition. These non-Abelian states, which we refer to as the ...

  19. IT/Nano IFF Scientific Report 2007 Nanoscale Phase Transitions in Phase

    E-Print Network [OSTI]

    IT/Nano · IFF Scientific Report 2007 158 I 159 Nanoscale Phase Transitions in Phase Change, and phase change (PC) materials are familiar to us as rewritable media (CD-RW, DVD- RW, DVD-RAM). Recently commercially available DVD-RW stor- age devices and DVD-RAM, are based on films of alloys of Ge, Sb, and Te

  20. A 100 MHz MEMS SiBAR Phase Modulator for Quadrature Phase Shift Keying

    E-Print Network [OSTI]

    Ayazi, Farrokh

    A 100 MHz MEMS SiBAR Phase Modulator for Quadrature Phase Shift Keying Logan Sorenson and Farrokh of a MEMS resonator to form the basic component of a switchless quadrature phase shift keying (QPSK) scheme. INTRODUCTION In recent years, microelectromechanical systems (MEMS)- based solutions have gained acceptance

  1. Nonlinear multiferroic phase shifters for microwave frequencies

    SciTech Connect (OSTI)

    Ustinov, Alexey B.; Kalinikos, Boris A. [Department of Physical Electronics and Technology, St. Petersburg Electrotechnical University, St. Petersburg 197376 (Russian Federation); Srinivasan, G. [Department of Physics, Oakland University, Rochester, Michigan 48309 (United States)

    2014-02-03

    A nonlinear microwave phase shifter based on a planar multiferroic composite has been studied. The multiferroic structure is fabricated in the form of a bilayer consisting of yttrium iron garnet and barium strontium titanate. The principle of operation of the device is based on the linear and nonlinear control of the phase shift of the hybrid spin-electromagnetic waves propagating in the bilayer. The linear control is realized with magnetic and electric fields. The nonlinear control is provided by the input power of microwave signal. The device showed a nonlinear phase shift up to 250°, electric field induced phase shift up to 330°, and magnetic field induced phase shift of more than 180°.

  2. High harmonic phase in molecular nitrogen

    SciTech Connect (OSTI)

    McFarland, Brian K.

    2009-10-17

    Electronic structure in atoms and molecules modulates the amplitude and phase of high harmonic generation (HHG). We report measurements of the high harmonic spectral amplitude and phase in N{sub 2}. The phase is measured interferometrically by beating the N{sub 2} harmonics with those of an Ar reference oscillator in a gas mixture. A rapid phase shift of 0.2{pi} is observed in the vicinity of the HHG spectral minimum, where a shift of {pi} had been presumed [J. Itatani et al., Nature 432, 867 (2004)]. We compare the phase measurements to a simulation of the HHG recombination step in N{sub 2} that is based on a simple interference model. The results of the simulation suggest that modifications beyond the simple interference model are needed to explain HHG spectra in molecules.

  3. Topological phases with long-range interactions

    E-Print Network [OSTI]

    Gong, Zhe-Xuan; Hu, Anzi; Wall, Michael L; Foss-Feig, Michael; Gorshkov, Alexey V

    2015-01-01

    Topological phases of matter are primarily studied in quantum many-body systems with short-range interactions. Whether various topological phases can survive in the presence of long-range interactions, however, is largely unknown. Here we show that a paradigmatic example of a symmetry-protected topological phase, the Haldane phase of an antiferromagnetic spin-1 chain, surprisingly remains intact in the presence of arbitrarily slowly decaying power-law interactions. The influence of long-range interactions on the topological order is largely quantitative, and we expect similar results for more general systems. Our conclusions are based on large-scale matrix-product-state simulations and two complementary effective-field-theory calculations. The striking agreement between the numerical and analytical results rules out finite-size effects. The topological phase considered here should be experimentally observable in a recently developed trapped-ion quantum simulator.

  4. Topological phases with long-range interactions

    E-Print Network [OSTI]

    Zhe-Xuan Gong; Mohammad F. Maghrebi; Anzi Hu; Michael L. Wall; Michael Foss-Feig; Alexey V. Gorshkov

    2015-05-12

    Topological phases of matter are primarily studied in quantum many-body systems with short-range interactions. Whether various topological phases can survive in the presence of long-range interactions, however, is largely unknown. Here we show that a paradigmatic example of a symmetry-protected topological phase, the Haldane phase of an antiferromagnetic spin-1 chain, surprisingly remains intact in the presence of arbitrarily slowly decaying power-law interactions. The influence of long-range interactions on the topological order is largely quantitative, and we expect similar results for more general systems. Our conclusions are based on large-scale matrix-product-state simulations and two complementary effective-field-theory calculations. The striking agreement between the numerical and analytical results rules out finite-size effects. The topological phase considered here should be experimentally observable in a recently developed trapped-ion quantum simulator.

  5. Analysis and design of some new single phase to three phase static converters 

    E-Print Network [OSTI]

    Rahman, Ashek

    1991-01-01

    , single phase source. In a wide variety of applications three phase ac motors are chosen over single phase ac motors because of their superior performance charactestics. In rural electric systems the cost of bringing three phase power to remote location... the phasor diagram of the mput voltage I;20 and 1;, ic8 Where 8 is the phase shift angle between the voltages 1; and 10, , i From Fig 12 (b) the input current I, is given by. 1, 0 ? 0;, 0/8 yX, (2. 1) The real power P, flowing from the ac mains...

  6. Fourier phase analysis in radio-interferometry

    E-Print Network [OSTI]

    Francois Levrier; Edith Falgarone; Francois Viallefond

    2006-06-09

    Most statistical tools used to characterize the complex structures of the interstellar medium can be related to the power spectrum, and therefore to the Fourier amplitudes of the observed fields. To tap into the vast amount of information contained in the Fourier phases, one may consider the probability distribution function (PDF) of phase increments, and the related concepts of phase entropy and phase structure quantity. We use these ideas here with the purpose of assessing the ability of radio-interferometers to detect and recover this information. By comparing current arrays such as the VLA and Plateau de Bure to the future ALMA instrument, we show that the latter is definitely needed to achieve significant detection of phase structure, and that it will do so even in the presence of a fair amount of atmospheric phase fluctuations. We also show that ALMA will be able to recover the actual "amount'' of phase structure in the noise-free case, if multiple configurations are used.

  7. Numerical Results for the Blue Phases

    E-Print Network [OSTI]

    G. P. Alexander; J. M. Yeomans

    2009-06-04

    We review recent numerical work investigating the equilibrium phase diagram, and the dynamics, of the cholesteric blue phases. In equilibrium numerical results confirm the predictions of the classic analytical theories, and extend them to incorporate different values of the elastic constants, or the effects of an applied electric field. There is a striking increase in the stability of blue phase I in systems where the cholesteric undergoes helical sense inversion, and the anomalous electrostriction observed in this phase is reproduced. Solving the equations of motion allows us to present results for the phase transition kinetics of blue phase I under dielectric or flexoelectric coupling to an applied electric field. We also present simulations of the blue phases in a flow field, showing how the disclination network acts to oppose the flow. The results are based on the Landau-de Gennes exapnsion of the liquid crystal free energy: that such a simple and elegant theory can predict such complex and subtle physical behaviour is remarkable.

  8. A Phase-Field Model for Phase Transformations in Glass-Forming Alloys

    SciTech Connect (OSTI)

    Wang, Tao; Napolitano, Ralph E.

    2012-03-24

    A phase-field model is proposed for phase transformations in glass-forming alloys. The glass transition is introduced as a structural relaxation, and the competition between the glass and crystalline phases is investigated. The simulations are performed for Cu-Zr alloys, employing thermodynamic and kinetic parameters derived from reported thermodynamic modeling and molecular dynamics simulation results,[1–3] respectively. Four distinct phase fields are treated with a multi-phase-field approach, representing the liquid/glass, Cu10Zr7, CuZr, and CuZr2 phases. In addition, a continuum-field method is applied to the liquid to accommodate the liquid–glass transformation. The combined phase-field approach is used to investigate the glass formation tendency, and critical cooling rates are estimated and compared with the reported experimental values.

  9. Comprehensive phase characterization of crystalline and amorphous phases of a Class F fly ash

    SciTech Connect (OSTI)

    Chancey, Ryan T.; Stutzman, Paul; Juenger, Maria C.G.; Fowler, David W.

    2010-01-15

    A comprehensive approach to qualitative and quantitative characterization of crystalline and amorphous constituent phases of a largely heterogeneous Class F fly ash is presented. Traditionally, fly ash composition is expressed as bulk elemental oxide content, generally determined by X-ray fluorescence spectroscopy. However, such analysis does not discern between relatively inert crystalline phases and highly reactive amorphous phases of similar elemental composition. X-ray diffraction was used to identify the crystalline phases present in the fly ash, and the Rietveld quantitative phase analysis method was applied to determine the relative proportion of each of these phases. A synergistic method of X-ray powder diffraction, scanning electron microscopy, energy dispersive spectroscopy, and multispectral image analysis was developed to identify and quantify the amorphous phases present in the fly ash.

  10. Slow dynamics of a colloidal lamellar phase

    E-Print Network [OSTI]

    Doru Constantin; Patrick Davidson; Éric Freyssingeas; Anders Madsen

    2015-04-06

    We used x-ray photon correlation spectroscopy to study the dynamics in the lamellar phase of a platelet suspension as a function of the particle concentration. We measured the collective diffusion coefficient along the director of the phase, over length scales down to the interparticle distance, and quantified the hydrodynamic interaction between the particles. This interaction sets in with increasing concentration and can be described qualitatively by a simplified model. No change in the microscopic structure or dynamics is observed at the transition between the fluid and the gel-like lamellar phases.

  11. Bistable defect structures in blue phase devices

    E-Print Network [OSTI]

    A. Tiribocchi; G. Gonnella; D. Marenduzzo; E. Orlandini; F. Salvadore

    2011-10-28

    Blue phases (BPs) are liquid crystals made up by networks of defects, or disclination lines. While existing phase diagrams show a striking variety of competing metastable topologies for these networks, very little is known as to how to kinetically reach a target structure, or how to switch from one to the other, which is of paramount importance for devices. We theoretically identify two confined blue phase I systems in which by applying an appropriate series of electric field it is possible to select one of two bistable defect patterns. Our results may be used to realise new generation and fast switching energy-saving bistable devices in ultrathin surface treated BPI wafers.

  12. Phase 2, Solid waste retrieval strategy

    SciTech Connect (OSTI)

    Johnson, D.M.

    1994-09-29

    Solid TRU retrieval, Phase 1 is scheduled to commence operation in 1998 at 218W-4C-T01 and complete recovery of the waste containers in 2001. Phase 2 Retrieval will recover the remaining buried TRU waste to be retrieved and provide the preliminary characterization by non-destructive means to allow interim storage until processing for disposal. This document reports on researching the characterization documents to determine the types of wastes to be retrieved and where located, waste configurations, conditions, and required methods for retrieval. Also included are discussions of wastes encompassed by Phase 2 for which there are valid reasons to not retrieve.

  13. Quantum gravitational optics: the induced phase

    E-Print Network [OSTI]

    N. Ahmadi; M. Nouri-Zonoz

    2007-03-26

    The geometrical approximation of the extended Maxwell equation in curved spacetime incorporating interactions induced by the vacuum polarization effects is considered. Taking into account these QED interactions and employing the analogy between eikonal equation in geometrical optics and Hamilton-Jacobi equation for the particle motion, we study the phase structure of the modified theory. There is a complicated, local induced phase which is believed to be responsible for the modification of the classical picture of light ray. The main features of QGO could be obtained through the study of this induced phase. We discuss initial principles in conventional and modified geometrical optics and compare the results.

  14. Fermion Path Integrals And Topological Phases

    E-Print Network [OSTI]

    Witten, Edward

    2015-01-01

    Symmetry-protected topological (SPT) phases of matter have been interpreted in terms of anomalies, and it has been expected that a similar picture should hold for SPT phases with fermions. Here, we describe in detail what this picture means for phases of quantum matter that can be understood via band theory and free fermions. The main examples we consider are time-reversal invariant topological insulators and superconductors in 2 or 3 space dimensions. Along the way, we clarify the precise meaning of the statement that in the bulk of a 3d topological insulator, the electromagnetic $\\theta$-angle is equal to $\\pi$.

  15. Phase Behavior of Alkanes in Shale Nanopores 

    E-Print Network [OSTI]

    Rahmani Didar, Behnaz

    2015-05-01

    and sorption densities in few PVT conditions. Many outstanding questions exist such as the concept of fluid pressure in confinement, multi-component fluid sorption and phase behavior/transition in confinement and the effect of pore type, geometry...

  16. Metamorphosis: Phases of UF{sub 6}

    SciTech Connect (OSTI)

    Dyer, R.H. [Department of Energy, Oak Ridge, TN (United States)

    1991-12-31

    A 15-minute videotape is presented. The subject matter is 150 grams of UF{sub 6} sealed in a glass tube. Close-up views show the UF{sub 6} as phase changes are effected by the addition or removal of heat from the closed system. The solid-to-liquid transition is shown as heat is added, both slowly and rapidly. The solid phases which result from freezing and from desublimation are contrasted. In the solid state, uranium hexafluoride is a nearly-white, dense crystalline solid. The appearance of this solid depends on whether it is formed by freezing from the liquid or by desublimation from the vapor phase. If frozen from the liquid, the solid particles take the form of irregularly shaped coarse grains, while the solid product of desublimation tends to be a rather formless mass without individually distinguishable particles. The changes in state are presented in terms of the UF{sub 6} phase diagram.

  17. Nuclear Concrete Materials Database Phase I Development

    SciTech Connect (OSTI)

    Ren, Weiju; Naus, Dan J

    2012-05-01

    The FY 2011 accomplishments in Phase I development of the Nuclear Concrete Materials Database to support the Light Water Reactor Sustainability Program are summarized. The database has been developed using the ORNL materials database infrastructure established for the Gen IV Materials Handbook to achieve cost reduction and development efficiency. In this Phase I development, the database has been successfully designed and constructed to manage documents in the Portable Document Format generated from the Structural Materials Handbook that contains nuclear concrete materials data and related information. The completion of the Phase I database has established a solid foundation for Phase II development, in which a digital database will be designed and constructed to manage nuclear concrete materials data in various digitized formats to facilitate electronic and mathematical processing for analysis, modeling, and design applications.

  18. Quantum Phase Transition in a Graphene Model

    E-Print Network [OSTI]

    Simon Hands; Costas Strouthos

    2008-08-20

    We present results for the equation of state of a graphene-like model in an effort to understand the properties of its quantum phase transition. The N_f fermion species interact through a three dimensional instantaneous Coulomb potential. Since there are no reliable analytical tools that work for all values of N_f and the coupling constant g, we rely on Monte Carlo simulations to calculate the critical properties of the model near the phase transition. We consider the four-component formulation for the fermion fields, which arises naturally as the continuum limit of the staggered fermion construction in (2+1) dimensions. In the limit of infinitely strong Coulomb interaction, the system undergoes a quantum phase transition at a critical number of fermion species N_fc ~ 4.7. We also calculate the values of the critical exponents at the quantum phase transition.

  19. Conceptual Phase Structural Design Tool for Microsatellites

    E-Print Network [OSTI]

    McLinko, Ryan (Ryan M.)

    2011-01-01

    Gaining traction or momentum in the conceptual design phase for a complex system can be an arduous and daunting process, whether the complex system being designed is a satellite, airplane, car, or one of countless other ...

  20. A multivariate phase distribution and its estimation

    E-Print Network [OSTI]

    Charles F. Cadieu; Kilian Koepsell

    2009-06-21

    Circular variables such as phase or orientation have received considerable attention throughout the scientific and engineering communities and have recently been quite prominent in the field of neuroscience. While many analytic techniques have used phase as an effective representation, there has been little work on techniques that capture the joint statistics of multiple phase variables. In this paper we introduce a distribution that captures empirically observed pair-wise phase relationships. Importantly, we have developed a computationally efficient and accurate technique for estimating the parameters of this distribution from data. We show that the algorithm performs well in high-dimensions (d=100), and in cases with limited data (as few as 100 samples per dimension). We also demonstrate how this technique can be applied to electrocorticography (ECoG) recordings to investigate the coupling of brain areas during different behavioral states. This distribution and estimation technique can be broadly applied to any setting that produces multiple circular variables.

  1. Primordial Density Fluctuations in Phase Coupling Gravity

    E-Print Network [OSTI]

    C. E. M. Batista; M. Schiffer

    1996-01-10

    In this paper we study the evolution of density perturbations in the framework of Phase Coupling Gravity theory at the very early universe. We show that these perturbation display an exponential-like behaviour.

  2. Synthesis of alloys with controlled phase structure

    DOE Patents [OSTI]

    Guthrie, Stephen Everett (Livermore, CA); Thomas, George John (Livermore, CA); Bauer, Walter (Livermore, CA); Yang, Nancy Yuan Chi (Lafayette, CA)

    1999-04-20

    A method for preparing controlled phase alloys useful for engineering and hydrogen storage applications. This novel method avoids melting the constituents by employing vapor transport, in a hydrogen atmosphere, of an active metal constituent, having a high vapor pressure at temperatures .apprxeq.300 C. and its subsequent condensation on and reaction with the other constituent (substrate) of an alloy thereby forming a controlled phase alloy and preferably a single phase alloy. It is preferred that the substrate material be a metal powder such that diffusion of the active metal constituent, preferably magnesium, and reaction therewith can be completed within a reasonable time and at temperatures .apprxeq.300 C. thereby avoiding undesirable effects such as sintering, local compositional inhomogeneities, segregation, and formation of unwanted second phases such as intermetallic compounds.

  3. Synthesis of alloys with controlled phase structure

    DOE Patents [OSTI]

    Guthrie, S.E.; Thomas, G.J.; Bauer, W.; Yang, N.Y.C.

    1999-04-20

    A method is described for preparing controlled phase alloys useful for engineering and hydrogen storage applications. This novel method avoids melting the constituents by employing vapor transport, in a hydrogen atmosphere, of an active metal constituent, having a high vapor pressure at temperatures {approx_equal}300 C and its subsequent condensation on and reaction with the other constituent (substrate) of an alloy thereby forming a controlled phase alloy and preferably a single phase alloy. It is preferred that the substrate material be a metal powder such that diffusion of the active metal constituent, preferably magnesium, and reaction therewith can be completed within a reasonable time and at temperatures {approx_equal}300 C thereby avoiding undesirable effects such as sintering, local compositional inhomogeneities, segregation, and formation of unwanted second phases such as intermetallic compounds. 4 figs.

  4. Fresnel phase plates as reconfigurable microfluidic lenses

    E-Print Network [OSTI]

    Tsikata, Sedina, 1981-

    2004-01-01

    In this study, Fresnel phase plates were tested as reconfigurable lenses. The lenses were constructed from a Fresnel pattern which was transferred to a silicon substrate via photolithography. A layer of PDMS was spin-coated ...

  5. Phase Selectively Soluble Polystyrene-Supported Organocatalysts 

    E-Print Network [OSTI]

    Khamatnurova, Tatyana

    2014-08-10

    Alkane phase selectively soluble poly(4-alkylstyrene) supports have been developed. 4-Methyl-, 4-tert-butyl, 4-dodecyl-, and 4-octadecylstyrene were copolymerized with 5-10 mol % of 4-chloromethylstyrene to afford co- and ...

  6. Acoustic resonance phase locked photoacoustic spectrometer

    DOE Patents [OSTI]

    Pilgrim, Jeffrey S.; Bomse, David S.; Silver, Joel A.

    2003-08-19

    A photoacoustic spectroscopy method and apparatus for maintaining an acoustic source frequency on a sample cell resonance frequency comprising: providing an acoustic source to the sample cell to generate a photoacoustic signal, the acoustic source having a source frequency; continuously measuring detection phase of the photoacoustic signal with respect to source frequency or a harmonic thereof; and employing the measured detection phase to provide magnitude and direction for correcting the source frequency to the resonance frequency.

  7. Optimum phase space probabilities from quantum tomography

    SciTech Connect (OSTI)

    Roy, Arunabha S.; Roy, S. M.

    2014-01-15

    We determine a positive normalised phase space probability distribution P with minimum mean square fractional deviation from the Wigner distribution W. The minimum deviation, an invariant under phase space rotations, is a quantitative measure of the quantumness of the state. The positive distribution closest to W will be useful in quantum mechanics and in time frequency analysis. The position-momentum correlations given by the distribution can be tested experimentally in quantum optics.

  8. An extended phase space for Quantum Mechanics

    E-Print Network [OSTI]

    C. Lopez

    2015-09-23

    The standard formulation of Quantum Mechanics violates locality of interactions and the action reaction principle. An alternative formulation in an extended phase space could preserve both principles, but Bell's theorems show that a distribution of probability in a space of local variables can not reproduce the quantum correlations. An extended phase space is defined in an alternative formulation of Quantum Mechanics. Quantum states are represented by a complex va\\-lued distribution of amplitude, so that Bell's theorems do not apply.

  9. Phase-sensitive X-ray imager

    DOE Patents [OSTI]

    Baker, Kevin Louis

    2013-01-08

    X-ray phase sensitive wave-front sensor techniques are detailed that are capable of measuring the entire two-dimensional x-ray electric field, both the amplitude and phase, with a single measurement. These Hartmann sensing and 2-D Shear interferometry wave-front sensors do not require a temporally coherent source and are therefore compatible with x-ray tubes and also with laser-produced or x-pinch x-ray sources.

  10. Analysis of Nuclear Quantum Phase Transitions

    SciTech Connect (OSTI)

    Li, Z. P.; Meng, J.; Niksic, T.; Vretenar, D.; Lalazissis, G. A.; Ring, P.

    2009-08-26

    A microscopic analysis, based on nuclear energy density functionals, is presented for shape phase transitions in Nd isotopes. Low-lying excitation spectra and transition probabilities are calculated starting from a five-dimensional Hamiltonian, with parameters determined by constrained relativistic mean-field calculations for triaxial shapes. The results reproduce available data, and show that there is an abrupt change of structure at N = 90, that corresponds to a first-order quantum phase transition between spherical and axially deformed shapes.

  11. Topological phases reviewed: The Aharonov Bohm, Aharonov Casher, and He McKellar Wilkens phases

    SciTech Connect (OSTI)

    McKellar, B. H. J. [ARC Centre of Excellence for Particle Physics at the Terrascale, School of Physics, University of Melbourne (Australia); He, X-G. [Department of Physics, National Taiwan University, Taipei, Taiwan (China); Klein, A. G. [School of Physics, University of Melbourne (Australia)

    2014-03-05

    There are three topological phases related to electromagnetic interactions in quantum mechanics: 1. The Aharonov Bohm phase acquired when a charged particle encircles a magnetic field but travels through a field free region. 2. The Aharonov Casher phase acquired when a magnetic dipole encircles electric charges but travels through a charge free region. 3. The He McKellar Wilkens phase acquired when an electric dipole encircles magnetic charges but travels through a charge free region. We review the conditions under which these phases are indeed topological and their experimental realisation. Because the He McKellar Wilkens phase has been recently observed we pay particular attention to how the basic concept of 'an electric dipole encircles magnetic charges' was realised experimentally, and discuss possible future experimental realisations.

  12. Quantum phase communication channels in the presence of static and dynamical phase diffusion

    E-Print Network [OSTI]

    Jacopo Trapani; Berihu Teklu; Stefano Olivares; Matteo G. A. Paris

    2015-05-12

    We address quantum communication channels based on phase modulation of coherent states and analyze in details the effects of static and dynamical (stochastic) phase diffusion. We evaluate mutual information for an ideal phase receiver and for a covariant phase-space-based receiver, and compare their performances by varying the number of symbols in the alphabet and/or the overall energy of the channel. Our results show that phase communication channels are generally robust against phase noise, especially for large alphabets in the low energy regime. In the presence of dynamical (non-Markovian) noise the mutual information is preserved by the time correlation of the environment, and when the noise spectra is detuned with respect to the information carrier, revivals of mutual information appears.

  13. MICROSTRUCTURE AND PROPERTIES OF DUAL PHASE STEELS CONTAINING FINE PRECIPITATES

    E-Print Network [OSTI]

    Gau, J.S.

    2014-01-01

    and Properties of Dual-Phase Steels, R. A. Kot and J. W.of Niobium Microalloyed Dual- Phase Steel, MetallurgicalAND PROPERTIES OF DUAL PHASE STEELS CONTAINING FINE

  14. Surface Tension between Kaon Condensate and Normal Nuclear Matter Phase

    E-Print Network [OSTI]

    Michael B. Christiansen; Norman K. Glendenning; Jurgen Schaffner-Bielich

    2000-03-20

    We calculate for the first time the surface tension and curvature coefficient of a first order phase transition between two possible phases of cold nuclear matter, a normal nuclear matter phase in equilibrium with a kaon condensed phase, at densities a few times the saturation density. We find the surface tension is proportional to the difference in energy density between the two phases squared. Furthermore, we show the consequences for the geometrical structures of the mixed phase region in a neutron star.

  15. Smart Grid Cybersecurity: Job Performance Model Report and Phase...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cybersecurity: Job Performance Model Report and Phase 1 Overview (August 2012) Smart Grid Cybersecurity: Job Performance Model Report and Phase 1 Overview (August 2012) In the...

  16. The Advanced Collaborative Emissions Study (ACES):Phase 3 | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    (ACES):Phase 3 The Advanced Collaborative Emissions Study (ACES):Phase 3 A chronic rat inhalation study with periodic health measurements is conducted on the representative 2007...

  17. Advanced Collaborative Emissions Study (ACES): Phase 2 Status...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    : Phase 2 Status Report Advanced Collaborative Emissions Study (ACES): Phase 2 Status Report Discusses status of ACES, a cooperative multi-party effort to characterize emissions...

  18. Phase Discrimination through Oxidant Selection for Iron Oxide...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Phase Discrimination through Oxidant Selection for Iron Oxide Ultrathin Films Home > Research > ANSER Research Highlights > Phase Discrimination through Oxidant Selection for Iron...

  19. Project Profile: Innovative Phase Change Thermal Energy Storage...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Phase Change Thermal Energy Storage Solution for Baseload Power Project Profile: Innovative Phase Change Thermal Energy Storage Solution for Baseload Power Infinia logo Infinia,...

  20. Demonstration of a Variable Phase Turbine Power System for Low...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Demonstration of a Variable Phase Turbine Power System for Low Temperature Geothermal Resources Demonstration of a Variable Phase Turbine Power System for Low Temperature...

  1. Advanced Envelope Research for Factory Built Housing, Phase 3...

    Office of Environmental Management (EM)

    Advanced Envelope Research for Factory Built Housing, Phase 3-Design Development and Prototyping Advanced Envelope Research for Factory Built Housing, Phase 3-Design Development...

  2. Funding Phases for Small Business Innovation Research and Small...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Phases for Small Business Innovation Research and Small Business Technology Transfer Programs Funding Phases for Small Business Innovation Research and Small Business Technology...

  3. Fractional Topological Phases and Broken Time-Reversal Symmetry...

    Office of Scientific and Technical Information (OSTI)

    Fractional Topological Phases and Broken Time-Reversal Symmetry in Strained Graphene Prev Next Title: Fractional Topological Phases and Broken Time-Reversal Symmetry in...

  4. Stabilizing Topological Phases in Graphene via Random Adsorption...

    Office of Scientific and Technical Information (OSTI)

    Stabilizing Topological Phases in Graphene via Random Adsorption Prev Next Title: Stabilizing Topological Phases in Graphene via Random Adsorption Authors: Jiang, Hua ; Qiao,...

  5. Unbalanced edge modes and topological phase transition in gated...

    Office of Scientific and Technical Information (OSTI)

    Unbalanced edge modes and topological phase transition in gated trilayer graphene Prev Next Title: Unbalanced edge modes and topological phase transition in gated trilayer...

  6. Building America Webinar: Results from Phased Deep Retrofits...

    Energy Savers [EERE]

    Building America Webinar: Results from Phased Deep Retrofits in Florida Building America Webinar: Results from Phased Deep Retrofits in Florida This presentation by Danny Parker is...

  7. Building America Webinar: Opportunities to Apply Phase Change...

    Energy Savers [EERE]

    Opportunities to Apply Phase Change Materials to Building Enclosures Building America Webinar: Opportunities to Apply Phase Change Materials to Building Enclosures This webinar,...

  8. Intercomparison of model simulations of mixed-phase clouds observed...

    Office of Scientific and Technical Information (OSTI)

    Title: Intercomparison of model simulations of mixed-phase clouds observed during the ARM Mixed-Phase Arctic Cloud Experiment. Part I: Single layer cloud Results are presented...

  9. Hysteresis, phase transitions, and dangerous transients in electrical...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Hysteresis, phase transitions, and dangerous transients in electrical power distribution systems Citation Details In-Document Search Title: Hysteresis, phase...

  10. Energy stable schemes and numerical simulations of two phase ...

    E-Print Network [OSTI]

    Title: Energy stable schemes and numerical simulations of two phase complex fluids by the phase-field method Abstact: We present an energetic variational ...

  11. Energy Department Announces Project Selections in First Phase...

    Energy Savers [EERE]

    Project Selections in First Phase of Cutting-Edge Enhanced Geothermal Systems Effort Energy Department Announces Project Selections in First Phase of Cutting-Edge Enhanced...

  12. Energy Department Announces Up to $31 Million for Initial Phases...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Up to 31 Million for Initial Phases of Enhanced Geothermal Systems Field Observatory Energy Department Announces Up to 31 Million for Initial Phases of Enhanced Geothermal...

  13. Factors Affecting HCCI Combustion Phasing for Fuels with Single...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Affecting HCCI Combustion Phasing for Fuels with Single- and Dual-Stage Chemistry Factors Affecting HCCI Combustion Phasing for Fuels with Single- and Dual-Stage Chemistry 2004...

  14. SPIDERS Phase 2 Fort Carson Technology Transition Consolidated...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Carson Technology Transition Consolidated Report SPIDERS Phase 2 Fort Carson Technology Transition Consolidated Report Final program public report for phase 2 summarizes the key...

  15. Probabilistic Modeling and Phase 2 Decision Making at the West...

    Office of Environmental Management (EM)

    and Phase 2 Decision Making at the West Valley Demonstration Project and the Western New York Nuclear Service Center Probabilistic Modeling and Phase 2 Decision Making at the...

  16. High performance Zintl phase TE materials with embedded nanoparticles...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Zintl phase TE materials with embedded nanoparticles Performance of zintl phase thermoelectric materials with embedded particles are evaluated shakouri.pdf More Documents &...

  17. The role of polymer formation during vapor phase lubrication...

    Office of Scientific and Technical Information (OSTI)

    The role of polymer formation during vapor phase lubrication of silicon. Citation Details In-Document Search Title: The role of polymer formation during vapor phase lubrication of...

  18. Nuclear chiral dynamics and phases of QCD

    E-Print Network [OSTI]

    Wolfram Weise

    2012-01-04

    This presentation starts with a brief review of our current picture of QCD phases, derived from lattice QCD thermodynamics and from models based on the symmetries and symmetry breaking patterns of QCD. Typical approaches widely used in this context are the PNJL and chiral quark-meson models. It is pointed out, however, that the modeling of the phase diagram in terms of quarks as quasiparticles misses important and well known nuclear physics constraints. In the hadronic phase of QCD governed by confinement and spontaneously broken chiral symmetry, in-medium chiral effective field theory is the appropriate framework, with pions and nucleons as active degrees of freedom. Nuclear chiral thermodynamics is outlined and the liquid-gas phase transition is described. The density and temperature dependence of the chiral condensate is deduced. As a consequence of two- and three-body correlations in the nuclear medium, no tendency towards a first-order chiral phase transition is found at least up to twice the baryon density of normal nuclear matter and up to temperatures of about 100 MeV. Isospin-asymmetric nuclear matter and neutron matter are also discussed. An outlook is given on new tightened constraints for the equation-of-state of cold and highly compressed matter as implied by a recently observed two-solar-mass neutron star.

  19. Switching dynamics in cholesteric blue phases

    E-Print Network [OSTI]

    A. Tiribocchi; G. Gonnella; D. Marenduzzo; E. Orlandini

    2011-03-30

    Blue phases are networks of disclination lines, which occur in cholesteric liquid crystals near the transition to the isotropic phase. They have recently been used for the new generation of fast switching liquid crystal displays. Here we study numerically the steady states and switching hydrodynamics of blue phase I (BPI) and blue phase II (BPII) cells subjected to an electric field. When the field is on, there are three regimes: for very weak fields (and strong anchoring at the boundaries) the blue phases are almost unaffected, for intermediate fields the disclinations twist (for BPI) and unzip (for BPII), whereas for very large voltages the network dissolves in the bulk of the cell. Interestingly, we find that a BPII cell can recover its original structure when the field is switched off, whereas a BPI cell is found to be trapped more easily into metastable configurations. The kinetic pathways followed during switching on and off entails dramatic reorganisation of the disclination networks. We also discuss the effect of changing the director field anchoring at the boundary planes and of varying the direction of the applied field.

  20. Phases of New Physics in the CMB

    E-Print Network [OSTI]

    Daniel Baumann; Daniel Green; Joel Meyers; Benjamin Wallisch

    2015-08-26

    Fluctuations in the cosmic neutrino background are known to produce a phase shift in the acoustic peaks of the cosmic microwave background. It is through the sensitivity to this effect that the recent CMB data has provided a robust detection of free-streaming neutrinos. In this paper, we revisit the phase shift of the CMB anisotropy spectrum as a probe of new physics. The phase shift is particularly interesting because its physical origin is strongly constrained by the analytic properties of the Green's function of the gravitational potential. For adiabatic fluctuations, a phase shift requires modes that propagate faster than the speed of fluctuations in the photon-baryon plasma. This possibility is realized by free-streaming relativistic particles, such as neutrinos or other forms of dark radiation. Alternatively, a phase shift can arise from isocurvature fluctuations. We present simple models to illustrate each of these effects. We then provide observational constraints from the Planck temperature and polarization data on additional forms of radiation. We also forecast the capabilities of future CMB Stage IV experiments. Whenever possible, we give analytic interpretations of our results.

  1. Phase Transformations in Binary Colloidal Monolayers

    E-Print Network [OSTI]

    Ye Yang; Lin Fu; Catherine Marcoux; Joshua E. S. Socolar; Patrick Charbonneau; Benjamin B. Yellen

    2015-02-10

    Phase transformations can be difficult to characterize at the microscopic level due to the inability to directly observe individual atomic motions. Model colloidal systems, by contrast, permit the direct observation of individual particle dynamics and of collective rearrangements, which allows for real-space characterization of phase transitions. Here, we study a quasi-two-dimensional, binary colloidal alloy that exhibits liquid-solid and solid-solid phase transitions, focusing on the kinetics of a diffusionless transformation between two crystal phases. Experiments are conducted on a monolayer of magnetic and nonmagnetic spheres suspended in a thin layer of ferrofluid and exposed to a tunable magnetic field. A theoretical model of hard spheres with point dipoles at their centers is used to guide the choice of experimental parameters and characterize the underlying materials physics. When the applied field is normal to the fluid layer, a checkerboard crystal forms; when the angle between the field and the normal is sufficiently large, a striped crystal assembles. As the field is slowly tilted away from the normal, we find that the transformation pathway between the two phases depends strongly on crystal orientation, field strength, and degree of confinement of the monolayer. In some cases, the pathway occurs by smooth magnetostrictive shear, while in others it involves the sudden formation of martensitic plates.

  2. Cummins Power Generation SECA Phase 1

    SciTech Connect (OSTI)

    Charles Vesely

    2007-08-17

    The following report documents the progress of the Cummins Power Generation (CPG) SECA Phase 1 SOFC development and final testing under the U.S. Department of Energy Solid State Energy Conversion Alliance (SECA) contract DE-FC26-01NT41244. This report overviews and summarizes CPG and partner research development leading to successful demonstration of the SECA Phase 1 objectives and significant progress towards SOFC commercialization. Significant Phase 1 Milestones: (1) Demonstrated: (a) Operation meeting Phase 1 requirements on commercial natural gas. (b) LPG and Natural Gas CPOX fuel reformers. (c) SOFC systems on dry CPOX reformate. (c) Steam reformed Natural Gas operation. (d) Successful start-up and shut-down of SOFC system without inert gas purge. (e) Utility of stack simulators as a tool for developing balance of plant systems. (2) Developed: (a) Low cost balance of plant concepts and compatible systems designs. (b) Identified low cost, high volume components for balance of plant systems. (c) Demonstrated high efficiency SOFC output power conditioning. (d) Demonstrated SOFC control strategies and tuning methods. The Phase 1 performance test was carried out at the Cummins Power Generation facility in Minneapolis, Minnesota starting on October 2, 2006. Performance testing was successfully completed on January 4, 2007 including the necessary steady-state, transient, efficiency, and peak power operation tests.

  3. A new phase in palladium hydride technology

    SciTech Connect (OSTI)

    Walters, R.T.

    1991-01-01

    Two plateaux are observed in both the absorption and desorption isotherms of palladium hydride. For the absorption isotherm, a change in plateau pressure is observed at a hydrogen-to-metal (H/M) ratio of about 0.35 for all temperatures studied. For the desorption isotherm, the change in plateau pressure appears to be a function of temperature, ranging from an H/M ratio of 0.18 at 80{degrees}C to 0.3 at 140{degrees}C. These data are interpreted as being experimentally observed boundaries to an equilibrium phase line located in the miscibility gap of the palladium/hydrogen phase diagram. This new phase does not appear to be a stoichiometric compounds, but rather its composition seems to vary with temperature. 6 refs., 4 figs.

  4. A new phase in palladium hydride technology

    SciTech Connect (OSTI)

    Walters, R.T.

    1991-12-31

    Two plateaux are observed in both the absorption and desorption isotherms of palladium hydride. For the absorption isotherm, a change in plateau pressure is observed at a hydrogen-to-metal (H/M) ratio of about 0.35 for all temperatures studied. For the desorption isotherm, the change in plateau pressure appears to be a function of temperature, ranging from an H/M ratio of 0.18 at 80{degrees}C to 0.3 at 140{degrees}C. These data are interpreted as being experimentally observed boundaries to an equilibrium phase line located in the miscibility gap of the palladium/hydrogen phase diagram. This new phase does not appear to be a stoichiometric compounds, but rather its composition seems to vary with temperature. 6 refs., 4 figs.

  5. Theory and modelling of nanocarbon phase stability.

    SciTech Connect (OSTI)

    Barnard, A. S.

    2006-01-01

    The transformation of nanodiamonds into carbon-onions (and vice versa) has been observed experimentally and has been modeled computationally at various levels of sophistication. Also, several analytical theories have been derived to describe the size, temperature and pressure dependence of this phase transition. However, in most cases a pure carbon-onion or nanodiamond is not the final product. More often than not an intermediary is formed, known as a bucky-diamond, with a diamond-like core encased in an onion-like shell. This has prompted a number of studies investigating the relative stability of nanodiamonds, bucky-diamonds, carbon-onions and fullerenes, in various size regimes. Presented here is a review outlining results of numerous theoretical studies examining the phase diagrams and phase stability of carbon nanoparticles, to clarify the complicated relationship between fullerenic and diamond structures at the nanoscale.

  6. Phase transitions in Pareto optimal complex networks

    E-Print Network [OSTI]

    Seoane, Luís F

    2015-01-01

    The organization of interactions in complex systems can be described by networks connecting different units. These graphs are useful representations of the local and global complexity of the underlying systems. The origin of their topological structure can be diverse, resulting from different mechanisms including multiplicative processes and optimization. In spatial networks or in graphs where cost constraints are at work, as it occurs in a plethora of situations from power grids to the wiring of neurons in the brain, optimization plays an important part in shaping their organization. In this paper we study network designs resulting from a Pareto optimization process, where different simultaneous constraints are the targets of selection. We analyze three variations on a problem finding phase transitions of different kinds. Distinct phases are associated to different arrangements of the connections; but the need of drastic topological changes does not determine the presence, nor the nature of the phase transit...

  7. Phase Segregation in Polystyrene?Polylactide Blends

    SciTech Connect (OSTI)

    Leung, Bonnie; Hitchcock, Adam; Brash, John; Scholl, Andreas; Doran, Andrew

    2010-06-09

    Spun-cast films of polystyrene (PS) blended with polylactide (PLA) were visualized and characterized using atomic force microscopy (AFM) and synchrotron-based X-ray photoemission electron microscopy (X-PEEM). The composition of the two polymers in these systems was determined by quantitative chemical analysis of near-edge X-ray absorption signals recorded with X-PEEM. The surface morphology depends on the ratio of the two components, the total polymer concentration, and the temperature of vacuum annealing. For most of the blends examined, PS is the continuous phase with PLA existing in discrete domains or segregated to the air?polymer interface. Phase segregation was improved with further annealing. A phase inversion occurred when films of a 40:60 PS:PLA blend (0.7 wt percent loading) were annealed above the glass transition temperature (Tg) of PLA.

  8. The Phase Transition of Dark Energy

    E-Print Network [OSTI]

    Wei Wang; Yuanxing Gui; Ying Shao

    2006-12-05

    Considering that the universe is filled with the nonrelativistic matter and dark energy and each component is respectively satisfied with its conservation condition in the absence of their interaction, we give the change rate of the fractional density and the density of dark energy from the conservation condition. It is clear that the fractional density of dark energy will monotonously increase and gradually become the dominating contribution to the universe as the redshift becomes low. Combining the evolutional trend of the state equation of dark energy and the change rate of the density of dark energy we find that the density of dark energy will decrease up to a minimum and whereafter it will increase again as the redshift becomes low. This can be regarded as the phase transition of dark energy from the quintessence phase to the phantom phase.

  9. Wind Turbine Drivetrain Condition Monitoring During GRC Phase 1 and Phase 2 Testing

    SciTech Connect (OSTI)

    Sheng, S.; Link, H.; LaCava, W.; van Dam, J.; McNiff, B.; Veers, P.; Keller, J.; Butterfield, S.; Oyague, F.

    2011-10-01

    This report will present the wind turbine drivetrain condition monitoring (CM) research conducted under the phase 1 and phase 2 Gearbox Reliability Collaborative (GRC) tests. The rationale and approach for this drivetrain CM research, investigated CM systems, test configuration and results, and a discussion on challenges in wind turbine drivetrain CM and future research and development areas, will be presented.

  10. Phase-field modeling of three-phase electrode microstructures in solid oxide fuel cells

    E-Print Network [OSTI]

    Chen, Long-Qing

    Phase-field modeling of three-phase electrode microstructures in solid oxide fuel cells Qun Li, mechanical deformation, and heterogeneous damage accumulation in solid oxide fuel cell anodes J. Appl. Phys oxide fuel cell/gas turbine cycle J. Renewable Sustainable Energy 4, 043115 (2012) Electric

  11. Genotoxicity of complex chemical mixtures 

    E-Print Network [OSTI]

    Phillips, Tracie Denise

    2009-05-15

    non-aqueous phase liquid from a wood treatment plant was separated into acid (AF), base (BF) and neutral fractions (NF). The NF was further enriched using column chromatography to produce a polychlorinated dinbenzo-p-dioxin (PCDD) and a polycyclic...

  12. Development of Chemical Model to Predict the Interactions between Supercritical CO2and Fluid, and Rocks in EGS Reservoirs

    Broader source: Energy.gov [DOE]

    This project will develop a chemical model, based on existing models and databases, that is capable of simulating chemical reactions between supercritical (SC) CO2 and Enhanced Geothermal System (EGS) reservoir rocks of various compositions in aqueous, non-aqueous and 2-phase environments.

  13. Wave Packets in Discrete Quantum Phase Space

    E-Print Network [OSTI]

    Jang Young Bang; Micheal S Berger

    2008-11-06

    The properties of quantum mechanics with a discrete phase space are studied. The minimum uncertainty states are found, and these states become the Gaussian wave packets in the continuum limit. With a suitably chosen Hamiltonian that gives free particle motion in the continuum limit, it is found that full or approximate periodic time evolution can result. This represents an example of revivals of wave packets that in the continuum limit is the familiar free particle motion on a line. Finally we examine the uncertainty principle for discrete phase space and obtain the correction terms to the continuum case.

  14. SLUDGE BATCH 6 PHASE II FLOWSHEET SIMULATIONS

    SciTech Connect (OSTI)

    Koopman, D.; Best, D.

    2010-03-30

    Two Sludge Receipt and Adjustment Tank (SRAT) runs were used to demonstrate that a fairly wide window of acid stoichiometry was available for processing SB6 Phase II flowsheet simulant (Tank 40 simulant) while still meeting the dual goals of acceptable nitrate destruction and controlled hydrogen generation. Phase II was an intermediate flowsheet study for the projected composition of Tank 40 after transfer of SB6/Tank 51 sludge to the heel of SB5. The composition was based on August 2009 projections. A window of about 50% in total acid was found between acceptable nitrite destruction and excessive hydrogen generation.

  15. Flexoelectric polarization in the biaxial nematic phase

    E-Print Network [OSTI]

    A. Kapanowski

    2009-10-14

    The dipole flexoelectric (FE) polarization in liquid crystals is derived in the thermodynamic limit at small distortions and small density. General microscopic expressions for the FE coefficients are obtained in the case of the uniaxial and biaxial nematic phases composed of C_2v molecules. The expressions involve the one-particle distribution function and the potential energy of two-body short-range interactions. In the case of the biaxial nematic phase, six basic deformations produce FE polarization but there are only five independent FE coefficients.

  16. Magnetic properties of two-phase superconductors

    E-Print Network [OSTI]

    E. Di Grezia; S. Esposito; G. Salesi

    2007-09-17

    We have recently proposed a theoretical model for superconductors endowed with two distinct superconducting phases, described by two scalar order parameters which condensate at different critical temperatures. On analyzing the magnetic behavior of such systems, we have found some observable differences with respect to the case of ordinary Ginzburg-Landau superconductors. In particular, at low temperature the London penetration length is strongly reduced and the Ginzburg-Landau parameter k becomes a function of temperature. By contrast, in the temperature region between the two phase transitions k is constant and the system is a type-I or a type-II superconductor depending on the ratio between the critical temperatures.

  17. Phase diagram of dilute cosmic matter

    E-Print Network [OSTI]

    Yoritaka Iwata

    2012-02-21

    Enhancement of nuclear pasta formation due to multi-nucleus simultaneous collision is presented based on time-dependent density functional calculations with periodic boundary condition. This calculation corresponds to the situation with density lower than the known low-density existence limit of the nuclear pasta phase. In order to evaluate the contribution from three-nucleus simultaneous collisions inside the cosmic matter, the possibility of multi-nucleus simultaneous collisions is examined by a systematic Monte-Carlo calculation, and the mean free path of a nucleus is obtained. Consequently the low-density existence limit of the nuclear pasta phase is formed to be lower than believed up to now.

  18. Bubble Free Energy in Cosmological Phase Transitions

    E-Print Network [OSTI]

    J. Ignatius

    1993-01-07

    Free energy as a function of temperature and the bubble radius is determined for spherical bubbles created in cosmological first order phase transitions. The phase transition is assumed to be driven by an order parameter (e.g. a Higgs field) with quartic potential. The definition of the bubble radius and the corresponding generalized, curvature-dependent surface tensions are discussed. In the free energy expansion in powers of the inverse radius, the coefficients of the curvature term and the constant term are also calculated.

  19. Ohio Hydropower Potential Inventory Phase I report

    SciTech Connect (OSTI)

    Not Available

    1981-12-01

    The dams researched in the Ohio Department of Natural Resources (ODNR) files were those contained in a list of Ohio dams provided by the ODNR. The result of this file research is a list of 997 dams contained herein that tabulates information on hydraulic head, stream flow, drainage area, and usage. This listing indicated that all but 137 of the 997 dams can be eliminated from consideration for Phase II research. The second phase would be required to further identify which of the 137 dams might have viable hydroelectric potential and define their basic hydroelectric parameters.

  20. Michael Rupen EVLA Phase II Definition Aug 23 25, 2001.

    E-Print Network [OSTI]

    Groppi, Christopher

    Michael Rupen EVLA Phase II Definition Meeting Aug 23 ­ 25, 2001. 1 EVLA Phase II Scientific Overview Michael P. Rupen #12;Michael Rupen EVLA Phase II Definition Meeting Aug 23 ­ 25, 2001. 2 New the resolution · Always available! #12;Michael Rupen EVLA Phase II Definition Meeting Aug 23 ­ 25, 2001. 3 NMA

  1. Feed-forward digital phase and amplitude correction system

    DOE Patents [OSTI]

    Yu, D.U.L.; Conway, P.H.

    1994-11-15

    Phase and amplitude modifications in repeatable RF pulses at the output of a high power pulsed microwave amplifier are made utilizing a digital feed-forward correction system. A controlled amount of the output power is coupled to a correction system for processing of phase and amplitude information. The correction system comprises circuitry to compare the detected phase and amplitude with the desired phase and amplitude, respectively, and a digitally programmable phase shifter and attenuator and digital logic circuitry to control the phase shifter and attenuator. The phase and amplitude of subsequent are modified by output signals from the correction system. 11 figs.

  2. Feed-forward digital phase and amplitude correction system

    DOE Patents [OSTI]

    Yu, David U. L. (Rancho Palos Verdes, CA); Conway, Patrick H. (Rancho Palos Verdes, CA)

    1994-01-01

    Phase and amplitude modifications in repeatable RF pulses at the output of a high power pulsed microwave amplifier are made utilizing a digital feed-forward correction system. A controlled amount of the output power is coupled to a correction system for processing of phase and amplitude information. The correction system comprises circuitry to compare the detected phase and amplitude with the desired phase and amplitude, respectively, and a digitally programmable phase shifter and attenuator and digital logic circuitry to control the phase shifter and attenuator. The Phase and amplitude of subsequent are modified by output signals from the correction system.

  3. Phase correction system for automatic focusing of synthetic aperture radar

    DOE Patents [OSTI]

    Eichel, Paul H. (Albuquerque, NM); Ghiglia, Dennis C. (Placitas, NM); Jakowatz, Jr., Charles V. (Albuquerque, NM)

    1990-01-01

    A phase gradient autofocus system for use in synthetic aperture imaging accurately compensates for arbitrary phase errors in each imaged frame by locating highlighted areas and determining the phase disturbance or image spread associated with each of these highlight areas. An estimate of the image spread for each highlighted area in a line in the case of one dimensional processing or in a sector, in the case of two-dimensional processing, is determined. The phase error is determined using phase gradient processing. The phase error is then removed from the uncorrected image and the process is iteratively performed to substantially eliminate phase errors which can degrade the image.

  4. Method and apparatus for optical phase error correction

    DOE Patents [OSTI]

    DeRose, Christopher; Bender, Daniel A.

    2014-09-02

    The phase value of a phase-sensitive optical device, which includes an optical transport region, is modified by laser processing. At least a portion of the optical transport region is exposed to a laser beam such that the phase value is changed from a first phase value to a second phase value, where the second phase value is different from the first phase value. The portion of the optical transport region that is exposed to the laser beam can be a surface of the optical transport region or a portion of the volume of the optical transport region. In an embodiment of the invention, the phase value of the optical device is corrected by laser processing. At least a portion of the optical transport region is exposed to a laser beam until the phase value of the optical device is within a specified tolerance of a target phase value.

  5. Dynamically Reconfiguring through Phase Detection on FPGA

    E-Print Network [OSTI]

    Giorgi, Roberto

    -grained reconfiguration that can be reconfigured to adapt to the applications' behavior. We use MicroBlaze as a general-purpose reconfiguration on the FPGA. KEYWORDS: RECONFIGURABLE; HARDWARE; PHASE CLASSIFICATION 1. Introduction Nowadays adapt to the application needs for obtaining more efficiency. The problem is how to dynamically monitor

  6. Fast Code-Phase Alignment of GPS

    E-Print Network [OSTI]

    Diessel, Oliver

    and corresponding device size for which energy usage is minimized. I. INTRODUCTION The basis for the new GPSFast Code-Phase Alignment of GPS Signals Using Virtex-4 FPGAs Usama Malik, Oliver Diessel School@cse.unsw.edu.au, odiessel@cse.unsw.edu.au Andrew G Dempster School of Surveying and Spatial Information Systems University

  7. Critical point analysis of phase envelope diagram

    SciTech Connect (OSTI)

    Soetikno, Darmadi; Siagian, Ucok W. R.; Kusdiantara, Rudy Puspita, Dila Sidarto, Kuntjoro A. Soewono, Edy; Gunawan, Agus Y.

    2014-03-24

    Phase diagram or phase envelope is a relation between temperature and pressure that shows the condition of equilibria between the different phases of chemical compounds, mixture of compounds, and solutions. Phase diagram is an important issue in chemical thermodynamics and hydrocarbon reservoir. It is very useful for process simulation, hydrocarbon reactor design, and petroleum engineering studies. It is constructed from the bubble line, dew line, and critical point. Bubble line and dew line are composed of bubble points and dew points, respectively. Bubble point is the first point at which the gas is formed when a liquid is heated. Meanwhile, dew point is the first point where the liquid is formed when the gas is cooled. Critical point is the point where all of the properties of gases and liquids are equal, such as temperature, pressure, amount of substance, and others. Critical point is very useful in fuel processing and dissolution of certain chemicals. Here in this paper, we will show the critical point analytically. Then, it will be compared with numerical calculations of Peng-Robinson equation by using Newton-Raphson method. As case studies, several hydrocarbon mixtures are simulated using by Matlab.

  8. Pancharatnam Phase and Photon Polarization Optics

    E-Print Network [OSTI]

    S. C. Tiwari

    2006-02-04

    Parallel transport of a vector around a closed curve on the surface of a sphere leads to a direction holonomy which can be related with a geometric phase that is equal to the solid angle subtended by the closed curve. Since Pancharatnam phase is half of the solid angle subtended by the polarization cycle on the Poincare sphere, quantum parallel transport law takes recourse o spin-half wave function to obtain this result. A critique is offered on this factor of half anomaly in the geometric phase, and a natural resolution using Riemann sphere polarization representation is suggested. It is argued that spin angular momentum of photon is fundamental in polarization optics, and new insights are gained based on the hypothesis that two helicity states correspond to two distinct species of photon. This approach leads to the concept of a physical Poincare sphere: nonlinearity and jumps in the Pancharatnam phase find a simple physical explanation while novel features pertaining to the discrete and pulsating sphere are predicted. Paired photon spin zero structure of unpolarized light is also discussed. An outline of possible experimental tests is presented.

  9. Phased Contrast X-Ray Imaging

    ScienceCinema (OSTI)

    Erin Miller

    2012-12-31

    The Pacific Northwest National Laboratory is developing a range of technologies to broaden the field of explosives detection. Phased contrast X-ray imaging, which uses silicon gratings to detect distortions in the X-ray wave front, may be applicable to mail or luggage scanning for explosives; it can also be used in detecting other contraband, small-parts inspection, or materials characterization.

  10. Alcohol Transportation Fuels Demonstration Program. Phase 1

    SciTech Connect (OSTI)

    Kinoshita, C.M. [ed.

    1990-12-31

    Hawaii has abundant natural energy resources, especially biomass, that could be used to produce alternative fuels for ground transportation and electricity. This report summarizes activities performed during 1988 to June 1991 in the first phase of the Alcohol Transportation Fuels Demonstration Program. The Alcohol Transportation Fuels Demonstration Program was funded initially by the Energy Division of the State of Hawaii`s Department of Business, Economic Development and Tourism, and then by the US Department of Energy. This program was intended to support the transition to an altemative transportation fuel, methanol, by demonstrating the use of methanol fuel and methanol-fueled vehicles, and solving the problems associated with that fuel. Specific objectives include surveying renewable energy resources and ground transportation in Hawaii; installing a model methanol fueling station; demonstrating a methanol-fueled fleet of (spark-ignition engine) vehicles; evaluating modification strategies for methanol-fueled diesel engines and fuel additives; and investigating the transition to methanol fueling. All major objectives of Phase I were met (survey of local renewable resources and ground transportation, installation of methanol refueling station, fleet demonstration, diesel engine modification and additive evaluation, and dissemination of information on alternative fueling), and some specific problems (e.g., relating to methanol fuel contamination during handling and refueling) were identified and solved. Several key issues emerging from Phase I (e.g., methanol corrosion, flame luminosity, and methanol-transition technoeconomics) were recommended as topics for follow-on research in subsequent phases of this program.

  11. Polyolefin composites containing a phase change material

    DOE Patents [OSTI]

    Salyer, Ival O. (Dayton, OH)

    1991-01-01

    A composite useful in thermal energy storage, said composite being formed of a polyolefin matrix having a phase change material such as a crystalline alkyl hydrocarbon incorporated therein, said polyolefin being thermally form stable; the composite is useful in forming pellets, sheets or fibers having thermal energy storage characteristics; methods for forming the composite are also disclosed.

  12. Comment on "Asymptotic Phase for Stochastic Oscillators"

    E-Print Network [OSTI]

    Peter J. Thomas; Benjamin Lindner

    2015-04-06

    In his Comment [arXiv:1501.02126 (2015)] on our recent paper [Phys. Rev. Lett., v. 113, 254101 (2014)], Pikovsky compares two methods for defining the "phase" of a stochastic oscillator. We reply to his Comment by showing that neither method can unambiguously identify a unique system of isochrons, when multiple oscillations coexist in the same system.

  13. Laboratory microfusion capability study. Phase II report

    SciTech Connect (OSTI)

    Not Available

    1993-05-01

    The purpose of this study is to elucidate the issues involved in developing a Laboratory Microfusion Capability (LMC) which is the major objective of the Inertial Confinement Fusion (ICF) program within the purview of the Department of Energy`s Defense Programs. The study was initiated to support a number of DOE management needs: to provide insight for the evolution of the ICF program; to afford guidance to the ICF laboratories in planning their research and development programs; to inform Congress and others of the details and implications of the LMC; to identify criteria for selection of a concept for the Laboratory Microfusion Facility and to develop a coordinated plan for the realization of an LMC. As originally proposed, the LMC study was divided into two phases. The first phase identifies the purpose and potential utility of the LMC, the regime of its performance parameters, driver independent design issues and requirements, its development goals and requirements, and associated technical, management, staffing, environmental, and other developmental and operational issues. The second phase addresses driver-dependent issues such as specific design, range of performance capabilities, and cost. The study includes four driver options; the neodymium-glass solid state laser, the krypton fluoride excimer gas laser, the light-ion accelerator, and the heavy-ion induction linear accelerator. The results of the Phase II study are described in the present report.

  14. Kinetics of silica-phase transitions

    SciTech Connect (OSTI)

    Duffy, C.J.

    1993-07-01

    In addition to the stable silica polymorph quartz, several metastable silica phases are present in Yucca Mountain. The conversion of these phases to quartz is accompanied by volume reduction and a decrease in the aqueous silica activity, which may destabilize clinoptilolite and mordenite. The primary reaction sequence for the silica phases is from opal or glass to disordered opal-CT, followed by ordering of the opal-CT and finally by the crystallization of quartz. The ordering of opal-CT takes place in the solid state, whereas the conversion of opal-CT takes place through dissolution-reprecipitation involving the aqueous phase. It is proposed that the rate of conversion of opal-CT to quartz is controlled by diffusion of defects out of a disordered surface layer formed on the crystallizing quartz. The reaction rates are observed to be dependent on temperature, pressure, degree of supersaturation, and pH. Rate equations selected from the literature appear to be consistent with observations at Yucca Mountain.

  15. TWRS Privatization Phase 1 Master Site Plan

    SciTech Connect (OSTI)

    PARAZIN, R.J.

    1999-08-16

    This document provides a reference for the development of the Tank Waste Remediation System (TWRS) Privatization Phase I site (former Grout Disposal Compound) and the upgrades and extension to the site of the 200 East Area inter- and intra-area roads and various utilities.

  16. Phase change thermal energy storage material

    DOE Patents [OSTI]

    Benson, David K. (Golden, CO); Burrows, Richard W. (Conifer, CO)

    1987-01-01

    A thermal energy storge composition is disclosed. The composition comprises a non-chloride hydrate having a phase change transition temperature in the range of 70.degree.-95.degree. F. and a latent heat of transformation of at least about 35 calories/gram.

  17. Phase Transformations in Cast Duplex Stainless Steels

    SciTech Connect (OSTI)

    Yoon-Jun Kim

    2004-12-19

    Duplex stainless steels (DSS) constitute both ferrite and austenite as a matrix. Such a microstructure confers a high corrosion resistance with favorable mechanical properties. However, intermetallic phases such as {sigma} and {chi} can also form during casting or high-temperature processing and can degrade the properties of the DSS. This research was initiated to develop time-temperature-transformation (TTT) and continuous-cooling-transformation (CCT) diagrams of two types of cast duplex stainless steels, CD3MN (Fe-22Cr-5Ni-Mo-N) and CD3MWCuN (Fe-25Cr-7Ni-Mo-W-Cu-N), in order to understand the time and temperature ranges for intermetallic phase formation. The alloys were heat treated isothermally or under controlled cooling conditions and then characterized using conventional metallographic methods that included tint etching, and also using electron microscopy (SEM, TEM) and wavelength dispersive spectroscopy (WDS). The kinetics of intermetallic-phase ({sigma} + {chi}) formation were analyzed using the Johnson-Mehl-Avrami (MA) equation in the case of isothermal transformations and a modified form of this equation in the case of continuous cooling transformations. The rate of intermetallic-phase formation was found to be much faster in CD3MWCuN than CD3MN due mainly to differences in the major alloying contents such as Cr, Ni and Mo. To examine in more detail the effects of these elements of the phase stabilities; a series of eight steel castings was designed with the Cr, Ni and Mo contents systematically varied with respect to the nominal composition of CD3MN. The effects of varying the contents of alloying additions on the formation of intermetallic phases were also studied computationally using the commercial thermodynamic software package, Thermo-Calc. In general, {sigma} was stabilized with increasing Cr addition and {chi} by increasing Mo addition. However, a delicate balance among Ni and other minor elements such as N and Si also exists. Phase equilibria in DSS can be affected by local composition fluctuations in the cast alloy. This may cause discrepancy between thermodynamic prediction and experimental observation.

  18. Phase Startup Initiative Phases 3 and 4 Test Plan and Test Specification ( OCRWM)

    SciTech Connect (OSTI)

    PAJUNEN, A.L.; LANGEVIN, M.J.

    2000-08-07

    Construction for the Spent Nuclear Fuel (SNF) Project facilities is continuing per the Level III Baseline Schedule, and installation of the Fuel Retrieval System (FRS) and Integrated Water Treatment System (IWTS) in K West Basin is now complete. In order to accelerate the project, a phased start up strategy to initiate testing of the FRS and IWTS early in the overall project schedule was proposed (Williams 1999). Wilkinson (1999) expands the definition of the original proposal into four functional testing phases of the Phased Startup Initiative (PSI). Phases 1 and 2 are based on performing functional tests using dummy fuel. This test plan provides overall guidance for Phase 3 and 4 tests, which are performed using actual irradiated N fuel assemblies. The overall objective of the Phase 3 and 4 testing is to verify how the FRS and IWTS respond while processing actual fuel. Conducting these tests early in the project schedule will allow identification and resolution of equipment and process problems before they become activities on the start-up critical path. The specific objectives of this test plan are to: Define the Phase 3 and 4 test scope for the FRS and IWTS; Provide detailed test requirements that can be used to write the specific test procedures; Define data required and measurements to be taken. Where existing methods to obtain these do not exist, enough detail will be provided to define required additional equipment; and Define specific test objectives and acceptance criteria.

  19. Preliminary Phase Field Computational Model Development

    SciTech Connect (OSTI)

    Li, Yulan; Hu, Shenyang Y.; Xu, Ke; Suter, Jonathan D.; McCloy, John S.; Johnson, Bradley R.; Ramuhalli, Pradeep

    2014-12-15

    This interim report presents progress towards the development of meso-scale models of magnetic behavior that incorporate microstructural information. Modeling magnetic signatures in irradiated materials with complex microstructures (such as structural steels) is a significant challenge. The complexity is addressed incrementally, using the monocrystalline Fe (i.e., ferrite) film as model systems to develop and validate initial models, followed by polycrystalline Fe films, and by more complicated and representative alloys. In addition, the modeling incrementally addresses inclusion of other major phases (e.g., martensite, austenite), minor magnetic phases (e.g., carbides, FeCr precipitates), and minor nonmagnetic phases (e.g., Cu precipitates, voids). The focus of the magnetic modeling is on phase-field models. The models are based on the numerical solution to the Landau-Lifshitz-Gilbert equation. From the computational standpoint, phase-field modeling allows the simulation of large enough systems that relevant defect structures and their effects on functional properties like magnetism can be simulated. To date, two phase-field models have been generated in support of this work. First, a bulk iron model with periodic boundary conditions was generated as a proof-of-concept to investigate major loop effects of single versus polycrystalline bulk iron and effects of single non-magnetic defects. More recently, to support the experimental program herein using iron thin films, a new model was generated that uses finite boundary conditions representing surfaces and edges. This model has provided key insights into the domain structures observed in magnetic force microscopy (MFM) measurements. Simulation results for single crystal thin-film iron indicate the feasibility of the model for determining magnetic domain wall thickness and mobility in an externally applied field. Because the phase-field model dimensions are limited relative to the size of most specimens used in experiments, special experimental methods were devised to create similar boundary conditions in the iron films. Preliminary MFM studies conducted on single and polycrystalline iron films with small sub-areas created with focused ion beam have correlated quite well qualitatively with phase-field simulations. However, phase-field model dimensions are still small relative to experiments thus far. We are in the process of increasing the size of the models and decreasing specimen size so both have identical dimensions. Ongoing research is focused on validation of the phase-field model. Validation is being accomplished through comparison with experimentally obtained MFM images (in progress), and planned measurements of major hysteresis loops and first order reversal curves. Extrapolation of simulation sizes to represent a more stochastic bulk-like system will require sampling of various simulations (i.e., with single non-magnetic defect, single magnetic defect, single grain boundary, single dislocation, etc.) with distributions of input parameters. These outputs can then be compared to laboratory magnetic measurements and ultimately to simulate magnetic Barkhausen noise signals.

  20. The Pegg-Barnett Formalism and Covariant Phase Observables

    E-Print Network [OSTI]

    Pekka Lahti; Juha-Pekka Pellonpaa

    2001-06-15

    We compare the Pegg-Barnett (PB) formalism with the covariant phase observable approach to the problem of quantum phase and show that PB-formalism gives essentially the same results as the canonical (covariant) phase observable. We also show that PB-formalism can be extended to cover all covariant phase observables including the covariant phase observable arising from the angle margin of the Husimi Q-function.

  1. The effect of distributors on two-phase and three-phase flows in vertical columns 

    E-Print Network [OSTI]

    Ouyang, Chie-Jan Paul

    1982-01-01

    ) - U1C (1 - E'g)/6'1 where g is the void fraction. For two-phase flow, the area fractions are related by equation 4. Substituting equation 4 into equation 3, the reduced form f' or the drift flux is obtained, Vd ? U (1- 6 ) ? Ulg The drift flux... appropriate: THE EFFECT OF DISTRIBUTORS ON TWO-PHASE AND THREE-PHASE FLOWS IN VERTICAL COLUMNS A Thesis by CHIE-JAN PAUL OUYANG Approved as to sty1e and content by: Chairm of Committee Member M mber Head of Dep rtment May 1982 ABS TRACT The Effect...

  2. THE MONOCLINIC PHASE IN PZT: NEW LIGHT ON MORPHOTROPIC PHASE BOUNDARIES

    SciTech Connect (OSTI)

    NOHEDA,B.; GONZALO,J.A.; GUO,R.; PARK,S.E.; CROSS,L.E.; COX,D.E.; SHIRANE,G.

    2000-03-09

    A summary of the work recently carried out on the morphotropic phase boundary (MPB) of PZT is presented. By means of x-ray powder diffraction on ceramic samples of excellent quality, the MPB has been successfully characterized by changing temperature in a series of closely spaced compositions. As a result, an unexpected monoclinic phase has been found to exist in between the well-known tetragonal and rhombohedral PZT phases. A detailed structural analysis, together with the investigation of the field effect in this region of compositions, have led to an important advance in understanding the mechanisms responsible for the physical properties of PZT as well as other piezoelectric materials with similar morphotropic phase boundaries.

  3. Photochemical Phase Transition versus Photochemical Phase Separation Xia Tong, Guang Wang, and Yue Zhao*

    E-Print Network [OSTI]

    Zhao, Yue

    - mophores in developing new photoactive materials. When used as dopants in liquid crystals (LCs phases, while the bent shape of the cis isomer is incompatible with them, which, in the case of nematic

  4. Estimation of 3-phase separation K-value using laboratory 3-phase separation tests 

    E-Print Network [OSTI]

    Billman, Albert Leo

    1989-01-01

    Mixtures Using n-Heptane. 8. Three-Phase K-Values for the Pressure Range From 0 psig to 1, 000 psig for 5 Component Mixtures Using n-Heptane. 9. Three-Phase K-Values for the Temperature Range From 25D F to 5DD F for All Mixtures Using n-Octane. 33 34... 35 X1 LIST OF FIGURES (Cont. ) F&g. Page 10. Three-Phase K-Values for the Pressure Range From 0 psig to 1, 000 psig for All Mixtures Using n-Octane. 36 11. Three-Phase K-Values for the Temperature Range From 250 F to 500 F for All Mixtures...

  5. Percolation behavior of diffusionally evolved two-phase systems simulated using phase field methods

    E-Print Network [OSTI]

    Brunini, Victor Eric

    2008-01-01

    Percolation is an important phenomenon that dramatically affects the properties of many multi-phase materials. As such, significant prior work has been done to investigate the percolation threshold and critical scaling ...

  6. Phase change based cooling for high burst mode heat loads with temperature regulation above the phase change temperature

    DOE Patents [OSTI]

    The United States of America as represented by the United States Department of Energy (Washington, DC)

    2009-12-15

    An apparatus and method for transferring thermal energy from a heat load is disclosed. In particular, use of a phase change material and specific flow designs enables cooling with temperature regulation well above the fusion temperature of the phase change material for medium and high heat loads from devices operated intermittently (in burst mode). Exemplary heat loads include burst mode lasers and laser diodes, flight avionics, and high power space instruments. Thermal energy is transferred from the heat load to liquid phase change material from a phase change material reservoir. The liquid phase change material is split into two flows. Thermal energy is transferred from the first flow via a phase change material heat sink. The second flow bypasses the phase change material heat sink and joins with liquid phase change material exiting from the phase change material heat sink. The combined liquid phase change material is returned to the liquid phase change material reservoir. The ratio of bypass flow to flow into the phase change material heat sink can be varied to adjust the temperature of the liquid phase change material returned to the liquid phase change material reservoir. Varying the flowrate and temperature of the liquid phase change material presented to the heat load determines the magnitude of thermal energy transferred from the heat load.

  7. Phased Startup Initiative Phases 3 and 4 Test Plan and Test Specification (OCRWM)

    SciTech Connect (OSTI)

    PITNER, A.L.

    2000-02-28

    Construction for the Spent Nuclear Fuel (SNF) Project facilities is continuing per the Level III Baseline Schedule, and installation of the Fuel Retrieval System (FRS) and Integrated Water Treatment System (IWTS) in K West Basin is now complete. In order to accelerate the project, a phased start up strategy to initiate testing of the FRS and IWTS early in the overall project schedule was proposed (Williams 1999). Wilkinson (1999) expands the definition of the original proposal into four functional testing phases of the Phased Startup Initiative (PSI). Phases 1 and 2 are based on performing functional tests using dummy fuel. These tests are described in separate planning documents. This test plan provides overall guidance for Phase 3 and 4 tests, which are performed using actual irradiated N fuel assemblies. The overall objective of the Phase 3 and 4 testing is to verify how the FRS and IWTS respond while processing actual fuel. Conducting these tests early in the project schedule will allow identification and resolution of equipment and process problems before they become activities on the start-up critical path. The specific objectives of this test plan are to: (1) Define the test scope for the FRS and IWTS; (2) Provide detailed test requirements that can be used to write the specific test procedures; (3) Define data required and measurements to be taken. Where existing methods to obtain these do not exist, enough detail will be provided to define required additional equipment; and (4) Define specific test objectives and acceptance criteria.

  8. Phase contrast portal imaging using synchrotron radiation

    SciTech Connect (OSTI)

    Umetani, K.; Kondoh, T.

    2014-07-15

    Microbeam radiation therapy is an experimental form of radiation treatment with great potential to improve the treatment of many types of cancer. We applied a synchrotron radiation phase contrast technique to portal imaging to improve targeting accuracy for microbeam radiation therapy in experiments using small animals. An X-ray imaging detector was installed 6.0 m downstream from an object to produce a high-contrast edge enhancement effect in propagation-based phase contrast imaging. Images of a mouse head sample were obtained using therapeutic white synchrotron radiation with a mean beam energy of 130 keV. Compared to conventional portal images, remarkably clear images of bones surrounding the cerebrum were acquired in an air environment for positioning brain lesions with respect to the skull structure without confusion with overlapping surface structures.

  9. Sensitivity to perturbations and quantum phase transitions

    E-Print Network [OSTI]

    D. A. Wisniacki; A. Roncaglia

    2013-05-15

    The local density of states or its Fourier transform, usually called fidelity amplitude, are important measures of quantum irreversibility due to imperfect evolution. In this Rapid Communication we study both quantities in a paradigmatic many body system, the Dicke Hamiltonian, where a single-mode bosonic field interacts with an ensemble of N two-level atoms. This model exhibits a quantum phase transition in the thermodynamic limit, while for finite instances the system undergoes a transition from quasi-integrability to quantum chaotic. We show that the width of the local density of states clearly points out the imprints of the transition from integrability to chaos but no trace remains of the quantum phase transition. The connection with the decay of the fidelity amplitude is also established.

  10. On Affine Fusion and the Phase Model

    E-Print Network [OSTI]

    Mark A. Walton

    2012-11-15

    A brief review is given of the integrable realization of affine fusion discovered recently by Korff and Stroppel. They showed that the affine fusion of the $su(n)$ Wess-Zumino-Novikov-Witten (WZNW) conformal field theories appears in a simple integrable system known as the phase model. The Yang-Baxter equation leads to the construction of commuting operators as Schur polynomials, with noncommuting hopping operators as arguments. The algebraic Bethe ansatz diagonalizes them, revealing a connection to the modular S matrix and fusion of the $su(n)$ WZNW model. The noncommutative Schur polynomials play roles similar to those of the primary field operators in the corresponding WZNW model. In particular, their 3-point functions are the $su(n)$ fusion multiplicities. We show here how the new phase model realization of affine fusion makes obvious the existence of threshold levels, and how it accommodates higher-genus fusion.

  11. Silicotitanate molecular sieve and condensed phases

    DOE Patents [OSTI]

    Nenoff, Tina M. (Albuquerque, NM); Nyman, May D. (Albuquerque, NM)

    2002-01-01

    A new microporous crystalline molecular sieve material having the formula Cs.sub.3 TiSi.sub.3 O.sub.95.cndot.3H.sub.2 O and its hydrothermally condensed phase, Cs.sub.2 TiSi.sub.6 O.sub.15, are disclosed. The microporous material can adsorb divalent ions of radionuclides or other industrial metals such as chromium, nickel, lead, copper, cobalt, zinc, cadmium, barium, and mercury, from aqueous or hydrocarbon solutions. The adsorbed metal ions can be leached out for recovery purposes or the microporous material can be hydrothermally condensed to a radiation resistant, structurally and chemically stable phase which can serve as a storage waste form for radionuclides.

  12. Phased Demolition of an Occupied Facility

    SciTech Connect (OSTI)

    Brede, Lawrence M.; Lauterbach, Merl J.; Witt, Brandon W.; McCague, James [Bechtel Jacobs Co., LLC, P.O. Box 4699, Oak Ridge, Tennessee 37831 (United States)

    2008-01-15

    The U.S. government constructed the K-1401 facility in the late 1940's as a support building for various projects supporting the uranium gaseous diffusion process. In 2004 the U.S. Department of Energy authorized Bechtel Jacobs Company, LLC (BJC) to decontaminate and demolish the facility. The K-1401 facility was used for a variety of industrial purposes supporting the gaseous diffusion process. Many different substances were used to support these processes over the years and as a result different parts of the facility were contaminated with fluorine, chlorine trifluoride, uranium and technetium radiological contamination, asbestos, and mercury. The total facility area is 46,015 m{sup 2} (495,000 sf) including a 6,800 m{sup 2} basement (73,200 sf). In addition to the contamination areas in the facility, a large portion was leased to businesses for re-industrialization when the D and D activities began. The work scope associated with the facility included purging and steam cleaning the former fluorine and chlorine trifluoride systems, decontaminating loose radiologically contaminated and mercury spill areas, dismantling former radiological lines contaminated with uranium oxide compounds and technetium, abating all asbestos containing material, and demolishing the facility. These various situations contributed to the challenge of successfully conducting D and D tasks on the facility. In order to efficiently utilize the work force, demolition equipment, and waste hauling trucks the normal approach of decontaminating the facility of the hazardous materials, and then conducting demolition in series required a project schedule of five years, which is not cost effective. The entire project was planned with continuous demolition as the goal end state. As a result, the first activities, Phase 1, required to prepare sections for demolition, including steam cleaning fluorine and chlorine trifluoride process lines in basement and facility asbestos abatement, were conducted while the tenants who were leasing floor space in the facility moved out. Upon completion of this phase the facility was turned over to the demolition project and the most hazardous materials were removed from the facility. Phase 2 activities included removing the process gas lines from sections C/D/E while decontaminating and preparing sections A and B for demolition. Demolition preparation activities include removing transit siding and universal waste from the area. Phase 3 began with demolition activities in sections A and B1 while continuing process gas line removal from sections C/D/E, as well as conducting demolition preparation activities to these sections. Area B was split into two sections, allowing demolition activities to occur in section B1 while personnel could still access the upper floor in sections C, D, and E. Once demolition began in section B2, personnel entry was only authorized in the basement. This timeline initiated phase 4, and the project completed cleaning the process components from the basement while section B2 demolition began. The final phase, phase 5, began once the basement was cleared. Final demolition activities began on sections C, D, E, and the basement. This material will ship for disposal and is scheduled for completion during FY07. Because the project was able to successfully phase demolition activities, the total facility demolition schedule was reduced by half to 2-1/2 years. The project was able to move portions of the demolition schedule from working in series to working in parallel, allowing the job to deliver facility demolition debris to ship for disposal 'just in time' as the facility was demolished.

  13. Tunable hyperbolic metamaterials utilizing phase change heterostructures

    SciTech Connect (OSTI)

    Krishnamoorthy, Harish N. S.; Menon, Vinod M.; Zhou, You; Ramanathan, Shriram; Narimanov, Evgenii

    2014-03-24

    We present a metal-free tunable anisotropic metamaterial where the iso-frequency surface is tuned from elliptical to hyperbolic dispersion by exploiting the metal-insulator phase transition in the correlated material vanadium dioxide (VO{sub 2}). Using VO{sub 2}-TiO{sub 2} heterostructures, we demonstrate the transition in the effective dielectric constant parallel to the layers to undergo a sign change from positive to negative as the VO{sub 2} undergoes the phase transition. The possibility to tune the iso-frequency surface in real time using external perturbations such as temperature, voltage, or optical pulses creates new avenues for controlling light-matter interaction.

  14. Phase Structure of Higher Spin Black Holes

    E-Print Network [OSTI]

    Abhishek Chowdhury; Arunabha Saha

    2015-02-12

    We revisit the study of the phase structure of higher spin black holes carried out in arXiv$:1210.0284$ using the "canonical formalism". In particular we study the low as well as high temperature regimes. We show that the Hawking-Page transition takes place in the low temperature regime. The thermodynamically favoured phase changes from conical surplus to black holes and then again to conical surplus as we increase temperature. We then show that in the high temperature regime the diagonal embedding gives the appropriate description. We also give a map between the parameters of the theory near the IR and UV fixed points. This makes the "good" solutions near one end map to the "bad" solutions near the other end and vice versa.

  15. Associative memory in phasing neuron networks

    SciTech Connect (OSTI)

    Nair, Niketh S [ORNL; Bochove, Erik J. [United States Air Force Research Laboratory, Kirtland Air Force Base; Braiman, Yehuda [ORNL

    2014-01-01

    We studied pattern formation in a network of coupled Hindmarsh-Rose model neurons and introduced a new model for associative memory retrieval using networks of Kuramoto oscillators. Hindmarsh-Rose Neural Networks can exhibit a rich set of collective dynamics that can be controlled by their connectivity. Specifically, we showed an instance of Hebb's rule where spiking was correlated with network topology. Based on this, we presented a simple model of associative memory in coupled phase oscillators.

  16. ISDSN Sensor System Phase One Test Report

    SciTech Connect (OSTI)

    Gail Heath

    2011-09-01

    This Phase 1 Test Report documents the test activities and results completed for the Idaho National Laboratory (INL) sensor systems that will be deployed in the meso-scale test bed (MSTB) at Florida International University (FIU), as outlined in the ISDSN-MSTB Test Plan. This report captures the sensor system configuration tested; test parameters, testing procedure, any noted changes from the implementation plan, acquired test data sets, and processed results.

  17. Fidelity Decay for Phase Space Displacements

    E-Print Network [OSTI]

    Diego V. Bevilaqua; Eric J. Heller

    2004-09-03

    In this letter we analyse the behavior of fidelity decay under a very specific kind of perturbation: phase space displacements. Under these perturbations, systems will decay following the Lyapunov regime only. Others universal regimes discussed in the literature are not presented in this case; instead, for small values of the perturbation we observe quantum freeze of the fidelity. We also show that it is possible to connect this result with the incoherent neutron scattering problem

  18. Matrix Product States and Quantum Phase Transitions

    E-Print Network [OSTI]

    K. Heshami; S. Raeisi

    2009-09-16

    We have developed a new approach based on matrix product representations of ground states to study Quantum Phase Transitions (QPT). As confirmation of the power of our approach we have analytically analyzed the XXZ spin-one chain with uniaxial single-ion-type anisotropy and our results compare favourably with previous numerical studies. In addition, our description lets to know which part of parameters space of the Hamiltonian is most likely to be exactly solvable.

  19. Bistability in Interstellar Gas-Phase Chemistry

    E-Print Network [OSTI]

    Gai I. Boger; Amiel Sternberg

    2006-01-16

    We present an analysis of "bistability" in gas-phase chemical models of dark interstellar clouds. We identify the chemical mechanisms that allow high- and low-ionization solutions to the chemical rate-equations to coexist. We derive simple analytic scaling relations for the gas densities and ionization rates for which the chemistry becomes bistable. We explain why bistability is sensitive to the H3+ dissociative recombination rate coefficient, and why it is damped by gas-grain neutralization.

  20. Industrial waste needs assessment. Phase 1

    SciTech Connect (OSTI)

    Radel, R.J.; Willis, M.P.

    1993-10-01

    In January of 1992 a team was put together to begin the process of assessing the industrial waste needs of the Tennessee Valley. The team consisted of representatives from the various TVA Resource Group organizations. This initial team recommended as a starting point in the process a two-phase market research effort. A second team was then commissioned to conduct the first phase of this market research effort. The first phase of that marketing effort is now complete. This report contains an analysis of the data obtained through interviews of more than 168 individuals representing a similar number of organizations. A total of 37 TVA Resource Group employees were involved in the contact process from various organizations. In addition, the appendices provide summaries of the data used in designing the process and the reports of the Contact Coordinators (who were responsible for a series of visits). As a result of the data analysis, the Review Team makes the following recommendations: 1. Publish this report and distribute to the new management within TVA Resource Group as well as to all those participating as contacts, visitors, and contact coordinators. 2. The Resource Group management team, or management teams within each of the respective organizations within Resource Group, appoint Phase 2 assessement teams for as many of the problem areas listed in Table III as seem appropriate. We further recommend that, where possible, cross-organizational teams be used to examine individual problem areas. 3. Make this report available within Generating and Customer Groups, especially to the Customer Service Centers. 4. Establish a process to continue follow up with each of the contacts made in this assessment.

  1. QCD PHASE TRANSITIONS-VOLUME 15.

    SciTech Connect (OSTI)

    SCHAFER,T.

    1998-11-04

    The title of the workshop, ''The QCD Phase Transitions'', in fact happened to be too narrow for its real contents. It would be more accurate to say that it was devoted to different phases of QCD and QCD-related gauge theories, with strong emphasis on discussion of the underlying non-perturbative mechanisms which manifest themselves as all those phases. Before we go to specifics, let us emphasize one important aspect of the present status of non-perturbative Quantum Field Theory in general. It remains true that its studies do not get attention proportional to the intellectual challenge they deserve, and that the theorists working on it remain very fragmented. The efforts to create Theory of Everything including Quantum Gravity have attracted the lion share of attention and young talent. Nevertheless, in the last few years there was also a tremendous progress and even some shift of attention toward emphasis on the unity of non-perturbative phenomena. For example, we have seen some. efforts to connect the lessons from recent progress in Supersymmetric theories with that in QCD, as derived from phenomenology and lattice. Another example is Maldacena conjecture and related development, which connect three things together, string theory, super-gravity and the (N=4) supersymmetric gauge theory. Although the progress mentioned is remarkable by itself, if we would listen to each other more we may have chance to strengthen the field and reach better understanding of the spectacular non-perturbative physics.

  2. "Phase freezeout" in isentropically expanding matter

    E-Print Network [OSTI]

    Iosilevskiy, Igor

    2014-01-01

    Features of isentropic expansion of warm dense matter (WDM) created by intense energy fluxes (strong shock compression or instant isochoric heating by laser or heavy ions) are under discussion in situation when ($i$) -- thermodynamic trajectory of such expansion crosses binodal of liquid-gas phase transition, and ($ii$) -- expansion within the two-phase region is going along equilibrium branch (not metastable one) of the two-phase mixture isentrope. It is known in the plane case that because of break in the expansion isentrope at binodal point (in $P-V$ plane) i.e. jump of sound velocity in this point, there appears extended zone ("boiling layer") of uniformity in expanding material with constant thermodynamic and kinematic parameters. It corresponds just to the state on this binodal of boiling liquid. The point is that because of self-similarity of such expansion (in plane case) this boiling layer contains finite and fixed part of whole expanding material. This property makes it possible (at least formally) ...

  3. New Phase-Integral Method Platform Function

    E-Print Network [OSTI]

    S. Yngve; B. Thidé

    2009-12-30

    The phase-integral method (PIM) is an asymptotic method of the geometrical optics or semi-classical type for solving approximately, but in many cases very accurately, a wide class of differential equations in physics. Unlike the related (J)WKB method, the higher-order corrections in the PIM can be generated from a generic, unspecified base function, providing added symmetry and flexibility. However, with the conventional approach of using the next-to-lowest (third) order correction to the integrand in the phase integral as a platform for calculating higher (fifth, seventh, ninth,...) order corrections, the higher-order calculations very often become quite complicated. We therefore introduce a new platform function, which considerably simplifies the calculation of the third-order contribution for a wide range of problems. We also present directly integrable conditions for the phase integral, which so far seem to have gone unnoticed. For a large number of observables, our analysis makes a clearer distinction between physical and, in a sense, unphysical contributions.

  4. The (magnetized) effective QCD phase diagram

    E-Print Network [OSTI]

    Alejandro Ayala

    2015-09-02

    I present the highlights of a recent study of the effective QCD phase diagram on the temperature T and quark chemical potential mu plane, where the strong interactions are modeled using the linear sigma model coupled to quarks. The phase transition line is found from the effective potential at finite T and mu taking into account the plasma screening effects. We find the location of the critical end point (CEP) to be (mu^CEP/T_c,T^CEP/T_c) \\sim (1.2,0.8), where T_c is the (pseudo)critical temperature for the crossover phase transition at vanishing mu. This location lies within the region found by lattice inspired calculations. Since the linear sigma model does not exhibit confinement, I argue that the location is due to the proper treatment of the plasma screening effects and not to the size of the confining scale. I also comment on the extension of this study to determine the dependence of the CEP's location on the strength of an external magnetic field.

  5. A possible relation between leptogenesis and PMNS phases

    E-Print Network [OSTI]

    Kim, Jihn E

    2016-01-01

    The CP phase relevant in the leptogenesis is related to the PMNS phase in case only one CP phase appears in the full theory. Thus, the CP phase is introduced by spontaneous CP violation at a high energy scale toward realizing the successful Kobayashi-Maskawa electroweak CP violation. This phase is in a complex vacuum expectation value of a standard model singlet field. We find new $W$ boson exchange diagrams for leptogenesis. Assuming that the lightest (intermediate scale) Majorana lepton $N_0$ dominates the lepton asymmetry, the lepton asymmetry and the PMNS phase are related.

  6. The role of phase instabilities in the early material response...

    Office of Scientific and Technical Information (OSTI)

    The role of phase instabilities in the early material response during laser-induced breakdown in bulk fused silica Citation Details In-Document Search Title: The role of phase...

  7. Gas-phase electron diffraction studies of unstable molecules 

    E-Print Network [OSTI]

    Noble-Eddy, Robert

    2009-01-01

    Gas-phase electron diffraction (GED) is the only viable technique for the accurate structural study of gas-phase molecules that contain more than ~10 atoms. Recent advances in Edinburgh have made it possible to study ...

  8. Phase II Smart Grid Data Access Funding Opportunity Winner Announced...

    Office of Environmental Management (EM)

    Phase II Smart Grid Data Access Funding Opportunity Winner Announced Phase II Smart Grid Data Access Funding Opportunity Winner Announced January 8, 2014 - 12:00am Addthis The...

  9. RADIO FREQUENCY PHASE IN THE FEL SECTION OF A TBA

    E-Print Network [OSTI]

    Kuenning, R.W.

    2008-01-01

    Amplitude Control of the Radio Frequency Wave in the Two-Madison, WI, August 21-27, 1986 RADIO FREQUENCY PHASE IN THEAC03-76SF00098 LBL- 223Pl RADIO FREQUENCY PHASE IN THE FEL

  10. Directing acoustic radiation using a phased array of piezoelectric transmitters

    E-Print Network [OSTI]

    Rodgers, Daniel Michael

    2010-01-01

    This thesis presents an acoustic phased array system utilizing piezoelectric transducers. The system is capable of operating at arbitrary frequencies into the low megahertz range, with a trade-off between phase accuracy ...

  11. Dynamic Phase Filtering with Integrated Optical Ring Resonators 

    E-Print Network [OSTI]

    Adams, Donald Benjamin

    2011-10-21

    Coherent optical signal processing systems typically require dynamic, low-loss phase changes of an optical signal. Waveform generation employing phase modulation is an important application area. In particular, laser radar systems have been shown...

  12. An economical single to three phase converter for induction motors 

    E-Print Network [OSTI]

    Di Zerega, Philp Van Uytandaele

    1994-01-01

    There are several different types of single to three phase converters for induction motors available today. However, many of the presently available phase converters suffer from disadvantages such as high cost or low performance. An economical...

  13. Causes And Effects Of Phase Transitions In Highway Traffic

    E-Print Network [OSTI]

    Daganzo, C. F.; Cassidy, M. J.; Bertini, R. L.

    1997-01-01

    incidents were ruled out as causes of the queues describedof California at Berkeley Causes and Effects of Phase8 December 1997 ISSN 0192 4095 Causes and Effects of Phase

  14. A phase-field study of ternary multiphase microstructures

    E-Print Network [OSTI]

    Cogswell, Daniel A. (Daniel Aaron)

    2010-01-01

    A diffuse-interface model for microstructures with an arbitrary number of components and phases was developed from basic thermodynamic and kinetic principles and applied to the study of ternary eutectic phase transformations. ...

  15. DECOUPLED ENERGY STABLE SCHEMES FOR A PHASE-FIELD ...

    E-Print Network [OSTI]

    2014-04-24

    Phase-field, two-phase flow, Navier-Stokes, variable density, stability, energy stable ... The third objective is to validate this model and the proposed numerical schemes through careful ... with a thin, smooth transition region of width O(?).

  16. Computation of the one-dimensional unwrapped phase

    E-Print Network [OSTI]

    Karam, Zahi Nadim

    2006-01-01

    In this thesis, the computation of the unwrapped phase of the discrete-time Fourier transform (DTFT) of a one-dimensional finite-length signal is explored. The phase of the DTFT is not unique, and may contain integer ...

  17. Kinetic and Performance Studies of the Regeneration Phase of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Studies of the Regeneration Phase of Model PtRhBa NOx Traps for Design and Optimization Kinetic and Performance Studies of the Regeneration Phase of Model PtRhBa NOx...

  18. The Western Wind and Solar Integration Study Phase 2

    Office of Energy Efficiency and Renewable Energy (EERE)

    Greg Brinkman will present the results of the Western Wind and Solar Integration Study (WWSIS), Phase 2. This study, which follows the first phase of WWSIS, focuses on potential emissions and wear...

  19. Geometric phase of a qubit driven by a phase noise laser under non-Markovian dynamics

    SciTech Connect (OSTI)

    Berrada, K.

    2014-01-15

    Robustness of the geometric phase (GP) with respect to the environmental effects is a basic condition for an effective quantum computation. Here, we study quantitatively the GP of a two-level atom system driven by a phase noise laser under non-Markovian dynamics in terms of different parameters involved in the whole system. We find that with the change of the damping coupling, the GP is very sensitive to its properties exhibiting long collapse and revival phenomena, which play a significant role in enhancing the stabilization and control of the system dynamics. Moreover, we show that the GP can be considered as a tool for testing and characterizing the nature of the qubit–environment coupling. Due to the significance of how a system is quantum correlated with its environment in the construction of a scalable quantum computer, the entanglement dynamics between the qubit with its environment under external classical noise is evaluated and investigated during the time evolution. -- Highlights: •Geometric phase under noise phase laser. •Dynamics of the geometric phase under non-Markovian dynamics in the presence of classical noise. •Solution of master equation of the system in terms atomic inversion. •Nonlocal correlation between the system and its environment under non-Markovianity.

  20. Unconventional transformation of spin Dirac phase across a topological quantum phase transition

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Xu, Su -Yang; Neupane, Madhab; Belopolski, Ilya; Liu, Chang; Alidoust, Nasser; Bian, Guang; Jia, Shuang; Landolt, Gabriel; Slomski, Batosz; Dil, J. Hugo; et al

    2015-04-17

    The topology of a topological material can be encoded in its surface states. These surface states can only be removed by a bulk topological quantum phase transition into a trivial phase. Here we use photoemission spectroscopy to image the formation of protected surface states in a topological insulator as we chemically tune the system through a topological transition. Surprisingly, we discover an exotic spin-momentum locked, gapped surface state in the trivial phase that shares many important properties with the actual topological surface state in anticipation of the change of topology. Using a spin-resolved measurement, we show that apart from amore »surface bandgap these states develop spin textures similar to the topological surface states well before the transition. Our results provide a general paradigm for understanding how surface states in topological phases arise from a quantum phase transition and are suggestive for the future realization of Weyl arcs, condensed matter supersymmetry and other fascinating phenomena in the vicinity of a quantum criticality.« less

  1. Dual-phase Cr-Ta alloys for structural applications

    DOE Patents [OSTI]

    Liu, Chain T. (Oak Ridge, TN); Brady, Michael P. (Oak Ridge, TN); Zhu, Jiahong (Knoxville, TN); Tortorelli, Peter F. (Knoxville, TN)

    2001-01-01

    Dual phase alloys of chromium containing 2 to 11 atomic percent tantalum with minor amounts of Mo, Cr, Ti, Y, La, Cr, Si and Ge are disclosed. These alloys contain two phases including Laves phase and Cr-rich solid solution in either eutectic structures or dispersed Laves phase particles in the Cr-rich solid solution matrix. The alloys have superior mechanical properties at high temperature and good oxidation resistance when heated to above 1000.degree. C. in air.

  2. Optomechanical entanglement in the presence of laser phase noise

    SciTech Connect (OSTI)

    Ghobadi, R. [Institute for Quantum Information Science and Department of Physics and Astronomy, University of Calgary, Calgary, Alberta, T2N 1N4 (Canada); Department of Physics, Sharif University of Technology, Tehran (Iran, Islamic Republic of); Bahrampour, A. R. [Department of Physics, Sharif University of Technology, Tehran (Iran, Islamic Republic of); Simon, C. [Institute for Quantum Information Science and Department of Physics and Astronomy, University of Calgary, Calgary, Alberta, T2N 1N4 (Canada)

    2011-12-15

    We study the simplest optomechanical system in the presence of laser phase noise (LPN) using the covariance matrix formalism. We show that for any LPN model with a finite correlation time, the destructive effect of the phase noise is especially strong in the bistable regime. This explains why ground-state cooling is still possible in the presence of phase noise, as it happens far away from the bistable regime. We also show that the optomechanical entanglement is strongly affected by phase noise.

  3. Opportunities to Apply Phase Change Materials to Building Enclosures...

    Energy Savers [EERE]

    Documents & Publications Building America Webinar: Opportunities to Apply Phase Change Materials to Building Enclosures 2011 Residential Energy Efficiency Technical Update...

  4. INTERMEDIATE PHASES IN MIXED NEMATIC/HEISENBERG SPINMODELS

    E-Print Network [OSTI]

    at sufficiently low tem­ peratures. For example, the ``head'' and ``tail'' ends of the molecules may have­zero but the spontaneous magnetization is zero while at low temperatures, these systems exhibit magnetization. This paper, in dimension d â?? 3, a low temperature phase was established. This phase, called the nematic phase

  5. Noise-induced transitions vs. noise-induced phase transitions

    E-Print Network [OSTI]

    Toral, Raúl

    Noise-induced transitions vs. noise-induced phase transitions Raul Toral IFISC (Instituto de Física the field of noise-induced phase transitions, emphasizing the main differences with the phase-induced transitions and showing that they appear in different systems. I will show that a noise-induced transition can

  6. Generalized simulated tempering for exploring strong phase transitions Jaegil Kima

    E-Print Network [OSTI]

    Straub, John E.

    rapid convergence. Accelerated tunneling transitions with a comprehensive sampling for phaseGeneralized simulated tempering for exploring strong phase transitions Jaegil Kima and John E to the exploration of first-order phase transition systems characterized by the backbending or S

  7. Phase-space localization: Topological aspects of quantum chaos

    SciTech Connect (OSTI)

    Leboeuf, P. (Division de Physique Theorique, Institut de Physique Nucleire, 91406 Orsay CEDEX (France)); Kurchan, J. (Nuclear Physics Department, Weizmann Institute of Science, Rehovot 76100 (Israel)); Feingold, M. (Lawrence Berkeley Laboratory, University of California, Berkeley, CA (USA) Department of Physics, University of California, Berkeley, CA (USA)); Arovas, D.P. (Department of Physics, B-019, University of California at San Diego, La Jolla, CA (USA))

    1990-12-17

    We study quantized classically chaotic maps on a toroidal two-diensional phase space. A discrete, topological criterion for phase-space localization is presented. To each eigenfunction an integer is associated, analogous to a quantized Hall conductivity, which when nonzero reflects phase-space delocalization. A model system is studied, and a correspondence between delocalization and chaotic classical dynamics is discussed.

  8. Density-Enthalpy Phase Diagram 0D Boiler Simulation

    E-Print Network [OSTI]

    Vuik, Kees

    Density-Enthalpy Phase Diagram 0D Boiler Simulation Finite Element Method Further Research Finite Transitions #12;Density-Enthalpy Phase Diagram 0D Boiler Simulation Finite Element Method Further Research;Density-Enthalpy Phase Diagram 0D Boiler Simulation Finite Element Method Further Research Goal

  9. TWO-PHASE FLOW TURBINE FOR COGENERATION, GEOTHERMAL,

    E-Print Network [OSTI]

    TWO-PHASE FLOW TURBINE FOR COGENERATION, GEOTHERMAL, SOLAR AND OTHER APPLICATIONS Prepared For REPORT (FAR) TWO-PHASE FLOW TURBINE FOR COGENERATION, GEOTHERMAL, SOLAR AND OTHER APPLICATIONS EISG://www.energy.ca.gov/research/index.html. #12;Page 1 Two-Phase Flow Turbine For Cogeneration, Geothermal, Solar And Other Applications EISG

  10. Phase control of intermittency in dynamical systems Samuel Zambrano,1

    E-Print Network [OSTI]

    Rey Juan Carlos, Universidad

    Phase control of intermittency in dynamical systems Samuel Zambrano,1 Inés P. Mariño,1 Francesco has been proved in periodically driven chaotic systems is phase control of chaos 10 that the intermittency at an interior crisis in a dynamical system can be controlled by a phase control scheme. We give

  11. PHASE-REFERENCED STELLAR INTERFEROMETRY AT THE PALOMAR TESTBED INTERFEROMETER

    E-Print Network [OSTI]

    PHASE-REFERENCED STELLAR INTERFEROMETRY AT THE PALOMAR TESTBED INTERFEROMETER Benjamin F. Lane implementation and testing of phase referencing at the Palomar Testbed Interferometer. A new instrument) to allow an accurate measurement of the fringe phase and, thus, to allow fringe tracking. At the Palomar

  12. Phase Retrieval for Fresnel Measurements Using a Shearlet Sparsity Constraint

    E-Print Network [OSTI]

    Plonka, Gerlind

    Phase Retrieval for Fresnel Measurements Using a Shearlet Sparsity Constraint Stefan Loock Gerlind Plonka March 25, 2014 Abstract We consider the problem of phase retrieval in the Fresnel regime be used for phase reconstruction with Fresnel data. As it turns out, the shearlet sparsity constraint

  13. Simple, Broadband Relative Phase Measurement of Intermodulation Products

    E-Print Network [OSTI]

    Simple, Broadband Relative Phase Measurement of Intermodulation Products Aaron Walker, Michael, several methods have been developed to measure the relative phase of nonlinear products generated during DUT, but was used in [2] to measure the phase of intermodulation products in two-tone excitation

  14. CLIMATE STUDY Phase II: MU Student Services Providers Survey

    E-Print Network [OSTI]

    Taylor, Jerry

    MU CAMPUS CLIMATE STUDY VOLUME 2 Phase II: MU Student Services Providers Survey Phase III: MU CAMPUS CLIMATE STUDY: PHASES II ­ IV Over the past three years, members of the University of Missouri-Columbia (MU) have participated in the MU Campus Climate Study for Underrepresented Groups conducted by a team

  15. Newberry Volcano EGS Demonstration - Phase I Results

    SciTech Connect (OSTI)

    William L. Osborn, Susan Petty, Trenton T. Cladouhos, Joe Iovenitti, Laura Nofziger, Owen Callahan, Douglas S. Perry and Paul L. Stern

    2011-10-23

    Phase I of the Newberry Volcano Enhanced Geothermal System (EGS) Demonstration included permitting, community outreach, seismic hazards analysis, initial microseismic array deployment and calibration, final MSA design, site characterization, and stimulation planning. The multi-disciplinary Phase I site characterization supports stimulation planning and regulatory permitting, as well as addressing public concerns including water usage and induced seismicity. A review of the project'Ã?Â?Ã?Â?s water usage plan by an independent hydrology consultant found no expected impacts to local stakeholders, and recommended additional monitoring procedures. The IEA Protocol for Induced Seismicity Associated with Enhanced Geothermal Systems was applied to assess site conditions, properly inform stakeholders, and develop a comprehensive mitigation plan. Analysis of precision LiDAR elevation maps has concluded that there is no evidence of recent faulting near the target well. A borehole televiewer image log of the well bore revealed over three hundred fractures and predicted stress orientations. No natural, background seismicity has been identified in a review of historic data, or in more than seven months of seismic data recorded on an array of seven seismometers operating around the target well. A seismic hazards and induced seismicity risk assessment by an independent consultant concluded that the Demonstration would contribute no additional risk to residents of the nearest town of La Pine, Oregon. In Phase II of the demonstration, an existing deep hot well, NWG 55-29, will be stimulated using hydroshearing techniques to create an EGS reservoir. The Newberry Volcano EGS Demonstration is allowing geothermal industry and academic experts to develop, validate and enhance geoscience and engineering techniques, and other procedures essential to the expansion of EGS throughout the country. Successful development will demonstrate to the American public that EGS can play a significant role in reducing foreign energy dependence, and provide clean, renewable, baseload geothermal power generation in the State of Oregon.

  16. Transuranic (TRU) Waste Phase I Retrieval Plan

    SciTech Connect (OSTI)

    MCDONALD, K.M.

    1999-08-27

    Phase I retrieval of post-1970 TRU wastes from burial ground 218-W-4C can be done in a safe, efficient, and cost-effective manner. Initiating TRU retrieval by retrieving uncovered drums from Trenches 1, 20, and 29, will allow retrieval to begin under the current SWBG safety authorization basis. The retrieval of buried drums from Trenches 1, 4, 20, and 29, which will require excavation, will commence once the uncovered drum are retrieved. This phased approach allows safety analysis for drum venting and drum module excavation to be completed and approved before the excavation proceeds. In addition, the lessons learned and the operational experience gained from the retrieval of uncovered drums can be applied to the more complicated retrieval of the buried drums. Precedents that have been set at SRS and LANL to perform retrieval without a trench cover, in the open air, should be followed. Open-air retrieval will result in significant cost savings over the original plans for Phase I retrieval (Project W-113). Based on LANL and SRS experience, open-air retrieval will have no adverse impacts to the environment or to the health and safety of workers or the public. Assaying the waste in the SWBG using a mobile assay system, will result in additional cost savings. It is expected that up to 50% of the suspect-TRU wastes will assay as LLW, allowing those waste to remain disposed of in the SWBG. Further processing, with its associated costs, will only occur to the portion of the waste that is verified to be TRU. Retrieval should be done, to the extent possible, under the current SWBG safety authorization basis as a normal part of SWBG operations. The use of existing personnel and existing procedures should be optimized. By working retrieval campaigns, typically during the slow months, it is easier to coordinate the availability of necessary operations personnel, and it is easier to coordinate the availability of a mobile assay vendor.

  17. WIPP Radiological Relase Report Phase 2

    Office of Environmental Management (EM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirley Ann Jackson About Us ShirleyU.S. DRIVE Vehicle Technologies Office:Vote Phase 2 Radiological

  18. WIPP Radiological Release Report Phase 1

    Office of Environmental Management (EM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirley Ann Jackson About Us ShirleyU.S. DRIVE Vehicle Technologies Office:Vote Phase 2 Radiological

  19. Neurton Damage and MAX Phase Ternary Compounds

    SciTech Connect (OSTI)

    Barsoum, Michael; Hoffman, Elizabeth; Sindelar, Robert; Garcua-Duaz, Brenda; Kohse, Gordon

    2014-06-17

    The Demands of Gen IV nuclear power plants for long service life under neutron radiation at high temperature are severe. Advanced materials that would withstand high temperatures (up to 1000+ C) to high doses in a neutron field would be ideal for reactor internal structures and would add to the long service life and reliability of the reactors. The objective of this work is to investigate the resonse of a new class of machinable, conductive, layered, ternary transition metal carbides and nitrides - the so-called MAX phases - to low and moderate neutron dose levels.

  20. Gas phase thermochemistry of organogermanium compounds

    SciTech Connect (OSTI)

    Engel, J.P.

    1993-12-07

    A variety of silyl- and alkyl-germylene precursors have been synthesized and subsequently pyrolyzed in the gas phase. Arrhenius parameters were obtained employing a pulsed-stirred flow reactor for these unimolecular decompositions. These precursors are divided into two major categories by mechanism of germylene extrusion: {alpha}-elimination precursors and germylacetylenes. The extrusion of germylenes from germylacetylene precursors is of primary interest. A mechanism is proposed employing a germacyclopropene intermediate. Evidence supporting this mechanism is presented. In the process of exploring germylacetylenes as germylene precursors, an apparent dyatropic rearrangement between germanium and silicon was observed. This rearrangement was subsequently explored.

  1. Toroidal Precession as a Geometric Phase

    SciTech Connect (OSTI)

    J.W. Burby and H. Qin

    2012-09-26

    Toroidal precession is commonly understood as the orbit-averaged toroidal drift of guiding centers in axisymmetric and quasisymmetric configurations. We give a new, more natural description of precession as a geometric phase effect. In particular, we show that the precession angle arises as the holonomy of a guiding center's poloidal trajectory relative to a principal connection. The fact that this description is physically appropriate is borne out with new, manifestly coordinate-independent expressions for the precession angle that apply to all types of orbits in tokamaks and quasisymmetric stellarators alike. We then describe how these expressions may be fruitfully employed in numerical calculations of precession.

  2. Synthesis of highly phase pure BSCCO superconductors

    DOE Patents [OSTI]

    Dorris, Stephen E. (La Grange Park, IL); Poeppel, Roger B. (Glen Ellyn, IL); Prorok, Barton C. (Harrisville, PA); Lanagan, Michael T. (Woodridge, IL); Maroni, Victor A. (Naperville, IL)

    1995-01-01

    An article and method of manufacture of (Bi, Pb)-Sr-Ca-Cu-O superconductor. The superconductor is manufactured by preparing a first powdered mixture of bismuth oxide, lead oxide, strontium carbonate, calcium carbonate and copper oxide. A second powdered mixture is then prepared of strontium carbonate, calcium carbonate and copper oxide. The mixtures are calcined separately with the two mixtures then combined. The resulting combined mixture is then subjected to a powder in tube deformation and thermal processing to produce a substantially phase pure (Bi, Pb)-Sr-Ca-Cu-O superconductor.

  3. Dry powder mixes comprising phase change materials

    DOE Patents [OSTI]

    Salyer, I.O.

    1995-12-26

    A free flowing, conformable powder-like mix of silica particles and a phase change material (PCM) is provided. The silica particles have a critical size of about 0.005 to about 0.025 microns and the PCM must be added to the silica in an amount of 75% or less PCM per combined weight of silica and PCM. The powder-like mix can be used in tableware items, medical wraps, tree wraps, garments, quilts and blankets, and particularly in applications for heat protection for heat sensitive items, such as aircraft flight recorders, and for preventing brake fade in automobiles, buses, trucks and aircraft. 3 figs.

  4. Synthesis of highly phase pure BSCCO superconductors

    DOE Patents [OSTI]

    Dorris, S.E.; Poeppel, R.B.; Prorok, B.C.; Lanagan, M.T.; Maroni, V.A.

    1995-11-21

    An article and method of manufacture (Bi, Pb)-Sr-Ca-Cu-O superconductor are disclosed. The superconductor is manufactured by preparing a first powdered mixture of bismuth oxide, lead oxide, strontium carbonate, calcium carbonate and copper oxide. A second powdered mixture is then prepared of strontium carbonate, calcium carbonate and copper oxide. The mixtures are calcined separately with the two mixtures then combined. The resulting combined mixture is then subjected to a powder in tube deformation and thermal processing to produce a substantially phase pure (Bi, Pb)-Sr-Ca-Cu-O superconductor. 5 figs.

  5. Deconfinement phase transition and the quark condensate

    E-Print Network [OSTI]

    Christian S. Fischer

    2009-07-27

    We study the dual quark condensate as a signal for the confinement-deconfinement phase transition of QCD. This order parameter for center symmetry has been defined recently by Bilgici et al. within the framework of lattice QCD. In this work we determine the ordinary and the dual quark condensate with functional methods using a formulation of the Dyson-Schwinger equations for the quark propagator on a torus. The temperature dependence of these condensates serves to investigate the interplay between the chiral and deconfinement transitions of quenched QCD.

  6. SRP Baseline Hydrogeologic Investigation, Phase 3

    SciTech Connect (OSTI)

    Bledsoe, H.W.

    1988-08-01

    The SRP Baseline Hydrogeologic Investigation was implemented for the purpose of updating and improving the knowledge and understanding of the hydrogeologic systems underlying the SRP site. Phase III, which is discussed in this report, includes the drilling of 7 deep coreholes (sites P-24 through P-30) and the installation of 53 observation wells ranging in depth from approximately 50 ft to more than 970 ft below the ground surface. In addition to the collection of geologic cores for lithologic and stratigraphic study, samples were also collected for the determination of physical characteristics of the sediments and for the identification of microorganisms.

  7. Relativistic Random Phase Approximation At Finite Temperature

    SciTech Connect (OSTI)

    Niu, Y. F.; Paar, N.; Vretenar, D.; Meng, J.

    2009-08-26

    The fully self-consistent finite temperature relativistic random phase approximation (FTRRPA) has been established in the single-nucleon basis of the temperature dependent Dirac-Hartree model (FTDH) based on effective Lagrangian with density dependent meson-nucleon couplings. Illustrative calculations in the FTRRPA framework show the evolution of multipole responses of {sup 132}Sn with temperature. With increased temperature, in both monopole and dipole strength distributions additional transitions appear in the low energy region due to the new opened particle-particle and hole-hole transition channels.

  8. Performance testing the Phase 2 HDR reservoir

    SciTech Connect (OSTI)

    Ponden, R.F.; Dreesen, D.S. ); Thomson, J.C. )

    1991-01-01

    The geothermal energy program at the Los Alamos National Laboratory is directed toward developing the Hot Dry Rock (HDR) technology as an alternate energy source. Positive results have been obtained in previous circulation tests of HDR reservoirs at the Laboratory's test site in Fenton Hill, New Mexico. There still remains however, the need to demonstrate that adequate geothermal energy can be extracted in an efficient manner to support commercial power production. This year, the Laboratory will begin a circulation test of its Phase 2, reservoir. The objectives of this test are to characterize steady-state power production and long-term reservoir performance. 6 refs., 2 figs., 3 tabs.

  9. Characterizing Arctic Mixed-phase Cloud Structure

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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  10. Geothermal Development Phases | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History View New PagesSustainable UrbanKentucky:Bore Technologies Inc Jump to: navigation, searchPhases

  11. Slice Straw Proposal (slice/phase2)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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  12. Solano Phase 3 | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmental Jump to:EA EIS ReportEurope GmbH JumpSlough HeatMccoy GeothermalSolaicxSolanoPhase 3

  13. 3 Phases Energy Services | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmental Jump to:EAand Dalton Jump to:Wylie,Information Skord, Et15: Leases7 CCRePhases

  14. Geothermal Development Phases | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIXsource History View New Pages Recent Changes All SpecialGeothermal Development Phases

  15. Phase 1 of Edison Arrives at NERSC

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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  16. Phase 2 CASL Unlimited Access Report Outline

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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  17. Phase 2 CASL Unlimited Access Report Outline

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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  18. Phase 2 CASL Unlimited Access Report Outline

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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  19. Phase 2 CASL Unlimited Access Report Outline

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformationJesseworkSURVEYI/OPerformance and DebuggingPeterof Petroleum4Phase

  20. Sandia Energy - Gas-Phase Diagnostics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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  1. Geometric phase for collinear conical intersections. I. Geometric phase angle and vector potentials

    SciTech Connect (OSTI)

    Li Xuan [Homer L. Dodge Department of Physics and Astronomy, University of Oklahoma, Norman, Oklahoma 73019 (United States); Department of Chemistry, The University of British Columbia, Vancouver, British Columbia V6T 1Z1 (Canada); Brue, Daniel A.; Blandon, Juan D.; Parker, Gregory A. [Homer L. Dodge Department of Physics and Astronomy, University of Oklahoma, Norman, Oklahoma 73019 (United States); Kendrick, Brian K. [Theoretical Division (T-1, MS B268), Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States)

    2011-02-14

    We present a method for properly treating collinear conical intersections in triatomic systems. The general vector potential (gauge theory) approach for including the geometric phase effects associated with collinear conical intersections in hyperspherical coordinates is presented. The current study develops an introductory method in the treatment of collinear conical intersections by using the phase angle method. The geometric phase angle, {eta}, in terms of purely internal coordinates is derived using the example of a spin-aligned quartet lithium triatomic system. A numerical fit and thus an analytical form for the associated vector potentials are explicitly derived for this triatomic A{sub 3} system. The application of this methodology to AB{sub 2} and ABC systems is also discussed.

  2. Irreversible altering of crystalline phase of phase-change Ge-Sb thin films

    SciTech Connect (OSTI)

    Krusin-Elbaum, L.; Shakhvorostov, D.; Cabral, C. Jr.; Raoux, S.; Jordan-Sweet, J. L.

    2010-03-22

    The stability of the crystalline phase of binary phase-change Ge{sub x}Sb{sub 1-x} films is investigated over a wide range of Ge content. From Raman spectroscopy we find the Ge-Sb crystalline structure irreversibly altered after exposure to a laser beam. We show that with increasing beam intensity/temperature Ge agglomerates and precipitates out in the amount growing with x. A simple empirical relation links Ge precipitation temperature T{sub Ge}{sup p} to the rate of change dT{sub cryst}/dx of crystallization, with the precipitation easiest on the mid-range x plateau, where T{sub cryst} is nearly constant. Our findings point to a preferable 15% < or approx. x < 50% window, that may achieve the desired cycling/archival properties of a phase-change cell.

  3. Understanding Optimization Phase Interactions to Reduce the Phase Order Search Space

    E-Print Network [OSTI]

    Jantz, Michael

    2010-07-30

    to Reduce the Phase Order Search Space 30 5.3.2 Copy Propagation to Reduce the Phase Order Search Space 34 5.3.3 Combining Register Remapping and Copy Propagation . . 36 5.4 Eliminating False Register Dependence on Real Architectures . . 37 5.4.1 Reducing...-orthogonal use of registers affects register-remapped code . . 33 5.7 Effect of copy propagation (512 registers) . . . . . . . . . . . . . . 35 5.8 Effect of register remapping with copy propagation (512 registers) 36 5.9 Effect of copy propagation (16 registers...

  4. GEOPHYSICS, VOL. 58, NO. 9 (SEPTEMBER 1993); P. 1324-1334, 9 FIGS. 2-D phase unwrapping and phase aliasing

    E-Print Network [OSTI]

    Spagnolini, Umberto

    principal values (PV) and the amount of phase infor- mation is independent of any integer multiple of added to the PV phase. However, to be useful for linear processing, this PV phase has to be unwrapped satisfactory results. The quality of 2-D unwrapping depends on the strategy adopted for the 1-D slicing

  5. THERMAL DESIGN METHODOLOGY FOR LOW FLOW RATE SINGLE-PHASE AND TWO-PHASE MICRO-CHANNEL HEAT SINKS

    E-Print Network [OSTI]

    Qu, Weilin

    THERMAL DESIGN METHODOLOGY FOR LOW FLOW RATE SINGLE-PHASE AND TWO-PHASE MICRO-CHANNEL HEAT SINKS-phase micro- channel heat sinks under a fixed liquid coolant flow rate. The parameters relevant to heat sink-channel dimensions corresponding to the prescribed dissipative heat flux and liquid coolant flow rate. Heat sink

  6. A phase-field method for 3D simulation of two-phase heat transfer , H. Babaee a

    E-Print Network [OSTI]

    Dong, Suchuan "Steven"

    A phase-field method for 3D simulation of two-phase heat transfer X. Zheng a , H. Babaee a , S s t r a c t We formulate new multi-phase convective heat transfer equations by combining the three for convergence in time/space including a conjugate heat transfer problem and also for a realistic tran- sient

  7. Memory Optimization for Phase-field Simulations

    SciTech Connect (OSTI)

    Derek Gaston; John Peterson; Andrew Slaughter; Cody Permann; David Andrs

    2014-08-01

    Phase-field simulations are computationally and memory intensive applications. Many of the phase-field simulations being conducted in support of NEAMS were not capable of running on “normal clusters” with 2-4GB of RAM per core, and instead required specialized “big-memory” clusters with 64GB per core. To address this issue, the MOOSE team developed a new Python-based utility called MemoryLogger, and applied it to locate, diagnose, and eradicate memory bottlenecks within the MOOSE framework. MemoryLogger allows for a better understanding of the memory usage of an application being run in parallel across a cluster. Memory usage information is captured for every individual process in a parallel job, and communicated to the head node of the cluster. Console text output from the application itself is automatically matched with this memory usage information to produce a detailed picture of memory usage over time, making it straightforward to identify the subroutines which contribute most to the application’s peak memory usage. The information produced by the MemoryLogger quickly and effectively narrows the search for memory optimizations to the most data-intensive parts of the simulation.

  8. Holographic Superconductors in a Cohesive Phase

    E-Print Network [OSTI]

    Francesco Aprile

    2012-09-12

    We consider a four-dimensional N=2 gauged supergravity coupled to matter fields. The model is obtained by a U(1) gauging of a charged hypermultiplet and therefore it is suitable for the study of holographic superconductivity. The potential has a topologically flat direction and the parameter running on this "moduli space" labels the new superconducting black holes. Zero temperature solutions are constructed and the phase diagram of the theory is studied. The model has rich dynamics. The retrograde condensate is just a special case in the new class of black holes. The calculation of the entanglement entropy makes manifest the properties of a generic solution and the superconductor at zero temperature is in a confined cohesive phase. The parameter running on the topologically flat direction is a marginal coupling in the dual field theory. We prove this statement by considering the way double trace deformations are treated in the AdS/CFT correspondence. Finally, we comment on a possible connection, in the context of gauge/gravity dualities, between the geometry of the scalar manifold in N=2 supergravity models and the space of marginal deformations of the dual field theory.

  9. Wetting and phase separation in soft adhesion

    E-Print Network [OSTI]

    K. E. Jensen; R. Sarfati; R. W. Style; R. Boltyanskiy; A. Chakrabarti; M. K. Chaudhury; E. R. Dufresne

    2015-07-22

    In the classic theory of solid adhesion, surface energy drives deformation to increase contact area while bulk elasticity opposes it. Recently, solid surface stress has been shown also to play an important role in opposing deformation of soft materials. This suggests that the contact line in soft adhesion should mimic that of a liquid droplet, with a contact angle determined by surface tensions. Consistent with this hypothesis, we observe a contact angle of a soft silicone substrate on rigid silica spheres that depends on the surface functionalization but not the sphere size. However, to satisfy this wetting condition without a divergent elastic stress, the gel separates from its solvent near the contact line. This creates a four-phase contact zone with two additional contact lines hidden below the surface of the substrate. While the geometries of these contact lines are independent of the size of the sphere, the volume of the phase-separated region is not, but rather depends on the indentation volume. These results indicate that theories of adhesion of soft gels need to account for both the compressibility of the gel network and a non-zero surface stress between the gel and its solvent.

  10. HYTEST Phase I Facility Commissioning and Modeling

    SciTech Connect (OSTI)

    Lee P. Shunn; Richard D. Boardman; Shane J. Cherry; Craig G. Rieger

    2009-09-01

    The purpose of this document is to report the first year accomplishments of two coordinated Laboratory Directed Research and Development (LDRD) projects that utilize a hybrid energy testing laboratory that couples various reactors to investigate system reactance behavior. This work is the first phase of a series of hybrid energy research and testing stations - referred to hereafter as HYTEST facilities – that are planned for construction and operation at the Idaho National Laboratory (INL). A HYTEST Phase I facility was set up and commissioned in Bay 9 of the Bonneville County Technology Center (BCTC). The purpose of this facility is to utilize the hydrogen and oxygen that is produced by the High Temperature Steam Electrolysis test reactors operating in Bay 9 to support the investigation of kinetic phenomena and transient response of integrated reactor components. This facility provides a convenient scale for conducting scoping tests of new reaction concepts, materials performance, new instruments, and real-time data collection and manipulation for advance process controls. An enclosed reactor module was assembled and connected to a new ventilation system equipped with a variable-speed exhaust blower to mitigate hazardous gas exposures, as well as contract with hot surfaces. The module was equipped with a hydrogen gas pump and receiver tank to supply high quality hydrogen to chemical reactors located in the hood.

  11. Economical realization of phase covariant devices in arbitrary dimensions

    E-Print Network [OSTI]

    Francesco Buscemi; Giacomo Mauro D'Ariano; Chiara Macchiavello

    2006-06-14

    We describe a unified framework of phase covariant multi user quantum transformations for d-dimensional quantum systems. We derive the optimal phase covariant cloning and transposition tranformations for multi phase states. We show that for some particular relations between the input and output number of copies they correspond to economical tranformations, which can be achieved without the need of auxiliary systems. We prove a relation between the optimal phase covariant cloning and transposition maps, and optimal estimation of multiple phases for equatorial states.

  12. Phasing of Debuncher Stochastic Cooling Transverse Systems

    SciTech Connect (OSTI)

    Pasquinelli, Ralph; /Fermilab

    2000-03-09

    With the higher frequency of the cooling systems in the Debuncher, a modified method of making transfer functions has been developed for transverse systems. (Measuring of the momentum systems is unchanged.) Speed in making the measurements is critical, as the beam tends to decelerate due to vacuum lifetime. In the 4-8 GHz band, the harmonics in the Debuncher are 6,700 to 13,400 times the revolution frequency. Every Hertz change in revolution frequency is multiplied by this harmonic number and becomes a frequency measurement error, which is an appreciable percent of the momentum width of the beam. It was originally thought that a momentum cooling system would be phased first so that the beam could be kept from drifting in revolution frequency. As it turned out, the momentum cooling was so effective (even with the gain turned down) that the momentum width normalized to fo became less than one Hertz on the Schottky pickup. A beam this narrow requires very precise measurement of tune and revolution frequency. It was difficult to get repeatable results. For initial measuring of the transverse arrays, relative phase and delay is all that is required, so the measurement settings outlined below will suffice. Once all input and output arrays are phased, a more precise measurement of all pickups to all kickers can be done with more points and both upper and lower side bands, as in figure 1. Settings on the network analyzer were adjusted for maximum measurement speed. Data is not analyzed until a complete set of measurements is taken. Start and stop frequencies should be chosen to be just slightly wider than the band being measured. For transverse systems, select betatron USB for the measurement type. This will make the measurement two times faster. Select 101 for the number of points, sweep time of 5 seconds, IF bandwidth 30 Hz, averages = 1. It is important during the phasing to continually measure the revolution frequency and beam width of the beam for transverse systems. Beam width is defined as the 3 dB bandwidth of the momentum Schottky divided by 127 (the harmonic of the Schottky pickup in the Debuncher.) Every three to five minutes, the beam drifts enough to make a significant change in the data. Knowing the revolution frequency and beam width to 0.5 Hz is important. If the beam width exceeds 10 Hz, the quality of the measurement will be impaired. Large beam widths can be caused by excessive forward proton beam current. There are also signs that the front-end amplifiers saturate with beam currents above several hundred microamps. The cooling systems were designed to be very sensitive, (that's why the front end is at liquid helium temperature) so a hundred microamps will go a long way. It should be possible to phase the systems with Pbars as a signal to noise ratio of 30 dB was observed with 100 microamps of beam current.

  13. Phase transition of holographic entanglement entropy in massive gravity

    E-Print Network [OSTI]

    Zeng, Xiao-Xiong; Li, Li-Fang

    2015-01-01

    The phase structure of holographic entanglement entropy is studied in massive gravity for the quantum systems with finite and infinite volumes, which in the bulk is dual to calculate the minimal surface area for a black hole and black brane respectively. In the entanglement entropy$-$temperature plane, we find for both the black hole and black brane there is a Van der Waals-like phase transition as the case in thermal entropy$-$temperature plane. That is, there is a first order phase transition for the small charge and a second order phase transition at the critical charge. For the first order phase transition, the equal area law is checked and for the second order phase transition, the critical exponent of the heat capacity is obtained. All the results show that the phase structure of holographic entanglement entropy is the same as that of thermal entropy regardless of the volume of the spacetime on the boundary.

  14. Phase Behavior of a Family of Truncated Hard Cubes

    E-Print Network [OSTI]

    Anjan P. Gantapara; Joost de Graaf; René van Roij; Marjolein Dijkstra

    2014-12-08

    In continuation of our work in [A.P. Gantapara et al., Phys. Rev. Lett. 111, 015501 (2013)], we investigate here the thermodynamic phase behavior of a family of truncated hard cubes, for which the shape evolves smoothly from a cube via a cuboctahedron to an octahedron. We used Monte Carlo simulations and free-energy calculations to establish the full phase diagram. This phase diagram exhibits a remarkable richness in crystal and mesophase structures, depending sensitively on the precise particle shape. In addition, we examined in detail the nature of the plastic crystal (rotator) phases that appear for intermediate densities and levels of truncation. Our results allow us to probe the relation between phase behavior and building-block shape and to further the understanding of rotator phases. Furthermore, the phase diagram presented here should prove instrumental for guiding future experimental studies on similarly-haped nanoparticles and the creation of new materials.

  15. Method of using an electric field controlled emulsion phase contactor

    DOE Patents [OSTI]

    Scott, T.C.

    1993-11-16

    A system is described for contacting liquid phases comprising a column for transporting a liquid phase contacting system, the column having upper and lower regions. The upper region has a nozzle for introducing a dispersed phase and means for applying thereto a vertically oriented high intensity pulsed electric field. This electric field allows improved flow rates while shattering the dispersed phase into many micro-droplets upon exiting the nozzle to form a dispersion within a continuous phase. The lower region employs means for applying to the dispersed phase a horizontally oriented high intensity pulsed electric field so that the dispersed phase undergoes continuous coalescence and redispersion while being urged from side to side as it progresses through the system, increasing greatly the mass transfer opportunity. 5 figures.

  16. Phase diagram of the five-vertex model

    SciTech Connect (OSTI)

    Gulacsi, M. (Scuola Internazionale Superiore di Studi Avanzati, Strada Costiera 11, Miramare, 34014 Trieste (Italy) Theory Division, Los Alamos National Laboratory, MS-B262, Los Alamos, New Mexico 87545 (United States)); Van Beijeren, H. (Institute for Theoretical Physics, University of Utrecht (Netherlands)); Levi, A.C. (Scuola Internazionale Superiore di Studi Avanzati, Strada Costiera 11, Miramare, 34014 Trieste (Italy) Universita di Genova, Dipartimento di Fisica, 16146 Genova (Italy))

    1993-04-01

    Within the ice-type models, the solution of the five-vertex model is obtained with the use of the Bethe ansatz. Since the allowed number of vertex types is odd, the arrow-reversal symmetry of the system is broken by construction. Due to this, the exact solution obtained and the phase diagram are very different from those of the symmetric six-vertex model. A connection to the asymmetric six-vertex model (of which the five-vertex model is an extreme case) is made. The different regions of the phase diagram are described and the transitions between them are analyzed. Several aspects of the phase diagram are unusual, i.e., the ordered phases (both ferroelectric and antiferroelectric) are frozen-in phases and the disordered phase is replaced by a ferrielectric phase. In the free-fermion case, the known results of the modified KDP model are recovered.

  17. Method of using an electric field controlled emulsion phase contactor

    DOE Patents [OSTI]

    Scott, Timothy C. (Knoxville, TN)

    1993-01-01

    A system for contacting liquid phases comprising a column for transporting a liquid phase contacting system, the column having upper and lower regions. The upper region has a nozzle for introducing a dispersed phase and means for applying thereto a vertically oriented high intensity pulsed electric field. This electric field allows improved flow rates while shattering the dispersed phase into many micro-droplets upon exiting the nozzle to form a dispersion within a continuous phase. The lower region employs means for applying to the dispersed phase a horizontally oriented high intensity pulsed electric field so that the dispersed phase undergoes continuous coalescence and redispersion while being urged from side to side as it progresses through the system, increasing greatly the mass transfer opportunity.

  18. Phase-field modeling of the beta to omega phase transformation in Zr–Nb alloys

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yeddu, Hemantha Kumar; Lookman, Turab

    2015-05-01

    A three-dimensional elastoplastic phase-field model is developed, using the Finite Element Method (FEM), for modeling the athermal beta to omega phase transformation in Zr–Nb alloys by including plastic deformation and strain hardening of the material. The microstructure evolution during athermal transformation as well as under different stress states, e.g. uni-axial tensile and compressive, bi-axial tensile and compressive, shear and tri-axial loadings, is studied. The effects of plasticity, stress states and the stress loading direction on the microstructure evolution as well as on the mechanical properties are studied. The input data corresponding to a Zr – 8 at.% Nb alloy aremore »acquired from experimental studies as well as by using the CALPHAD method. Our simulations show that the four different omega variants grow as ellipsoidal shaped particles. Our results show that due to stress relaxation, the athermal phase transformation occurs slightly more readily in the presence of plasticity compared to that in its absence. The evolution of omega phase is different under different stress states, which leads to the differences in the mechanical properties of the material. The variant selection mechanism, i.e. formation of different variants under different stress loading directions, is also nicely captured by our model.« less

  19. Experimental and computational studies of hydrodynamics in three-phase and two-phase fluidized beds

    SciTech Connect (OSTI)

    Bahary, M.

    1994-12-01

    The objective of the present study was to investigate the hydrodynamics of three-phase fluidized beds, their rheology, and experimentally verify a predictive three fluid hydrodynamic model developed at the Illinois Institute of Technology, Chicago. The recent reviews show that there exist no such models in the literature. The IIT hydrodynamic model computes the phase velocities and the volume fractions of gas, liquid, and particulate phases. Model verification involves a comparison of these computed velocities and volume fractions to experimental values. In this thesis, a three fluid model is presented. The input into the model can be particulate viscosities either measured with a Brookfield viscometer or derived using the mathematical techniques of kinetic theory of granular flows pioneered by Savage and others. The computer simulation of a three-phase fluidized bed in an asymmetric mode qualitatively predicts the gas, liquid and solid hold-ups (volume fractions) and flow patterns in the industrially important churn-turbulent (bubbly coalesced) regimes. The computations in a fluidized bed with a symmetric distributor incorrectly showed no bubble coalescence. A combination of X-ray and {gamma}-ray densitometers was used to measure the solids and the liquid volume fractions in a two dimensional bed in the bubble coalesced regime. There is a good agreement between the theory for an asymmetric distributor and the experiments.

  20. Formation of binary phase gratings in photopolymer-liquid crystal composites by a surface-controlled anisotropic phase separation

    SciTech Connect (OSTI)

    Park, Jae-Hong; Khoo, Iam Choon; Yu, Chang-Jae; Jung, Min-Sik; Lee, Sin-Doo [216 Electrical Engineering East, Pennsylvania State University, University Park, Pennsylvania 16802 (United States); School of Electrical Engineering no. 32, Seoul National University, Kwanak P.O. Box 34, Seoul 151-600 (Korea, Republic of)

    2005-01-10

    We report on formation of binary phase gratings in photopolymer-liquid crystal (PLC) composites using a surface-controlled phase separation method. The binary nature of the PLC phase gratings is produced by employing a single step photo-ablation through an amplitude photomask which precisely controls the interfacial interactions between the LC and the photopolymer on the alignment layer. A subsequent illumination of the ultraviolet light onto the whole PLC promotes an anisotropic phase separation resulting in the formation of distinct binary patterns for the PLC structure. The electrically tunable diffraction properties of the binary phase gratings are presented.

  1. Development of a Front Tracking Method for Two-Phase Micromixing...

    Office of Scientific and Technical Information (OSTI)

    properties of the two-phase mixture in terms of droplets, filaments, and other structures which emerge as a dispersed phase embedded into a continuous phase. Such a...

  2. SBIR and STTR: Topics, FY 2015 Phase I Release 2 | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Phase I Release 2 Small Business Innovation Research (SBIR) and Small Business Technology Transfer (STTR) Programs: Topics, FY 2015, Phase I, Release 2. EERE FY 2015 Phase I...

  3. EFFECTS OF MORPHOLOGY ON THE MECHANICAL BEHAVIOR OF DUAL PHASE Fe/Si/C STEELS

    E-Print Network [OSTI]

    Kim, N.J.

    2012-01-01

    and ductility in dual phase steels. However, it seems thatmechanical behavior of dual phase steels. ACKNOWLEDGEMENTSL INTRODUCTION Dual phase steels whose structures consist of

  4. Mechanical properties and microstructures of dual phase steels containing silicon, aluminum and molybdenum

    E-Print Network [OSTI]

    Neill, Thomas John O'

    2011-01-01

    AND MICROSTRUCTURES OF DUAL PHASE STEELS CONTAINING SILICON,and Microstructures of Dual Phase Steels Containing Silicon,microstructures of selected dual-phase steels in which the

  5. Thermodynamic Relationships for Bulk Crystalline and Liquid Phases in the Phase-Field Crystal Model

    E-Print Network [OSTI]

    Victor W. L. Chan; Nirand Pisutha-Arnond; Katsuyo Thornton

    2015-02-06

    We present thermodynamic relationships between the free energy of the phase-field crystal (PFC) model and thermodynamic state variables for bulk phases under hydrostatic pressure. This relationship is derived based on the thermodynamic formalism for crystalline solids of Larch\\'e and Cahn [Larch\\'e and Cahn, Acta Metallurgica, Vol. 21, 1051 (1973)]. We apply the relationship to examine the thermodynamic processes associated with varying the input parameters of the PFC model: temperature, lattice spacing, and the average value of the PFC order parameter, $\\bar{n}$. The equilibrium conditions between bulk crystalline solid and liquid phases are imposed on the thermodynamic relationships for the PFC model to obtain a procedure for determining solid-liquid phase coexistence. The resulting procedure is found to be in agreement with the method commonly used in the PFC community, justifying the use of the common-tangent construction to determine solid-liquid phase coexistence in the PFC model. Finally, we apply the procedure to an eighth-order-fit (EOF) PFC model that has been parameterized to body-centered-cubic ($bcc$) Fe [Jaatinen et al., Physical Review E 80, 031602 (2009)] to demonstrate the procedure as well as to develop physical intuition about the PFC input parameters. We demonstrate that the EOF-PFC model parameterization does not predict stable $bcc$ structures with positive vacancy densities. This result suggests an alternative parameterization of the PFC model, which requires the primary peak position of the two-body direct correlation function to shift as a function of $\\bar{n}$.

  6. Investigation of the phase-locking behavior by utilizing self-phase- and cross-phase-modulation in cubic susceptibility medium: Theory and experiment

    SciTech Connect (OSTI)

    Zhao Liang; Sun Junqiang [College of Optoelectronic Science and Engineering, Wuhan National Laboratory for Optoelectronics, Huazhong University of Science and Technology, Wuhan 430074 (China)

    2010-12-15

    A phase-locking approach for two individual lasing fields has been theoretically proposed and experimentally demonstrated by exploiting the nonlinearity in a highly nonlinear fiber. A closed form expression describing the phase difference is derived from the robust coupled-wave equations, and the theoretical analysis indicates that phase synchronization is possible as long as the condition of low-efficiency multiple four-wave mixing associated with the strong strength of the self-phase-modulation and cross-phase-modulation is satisfied. The phase-locking phenomenon is verified by means of assessing the quality of the autocorrelation traces and the radiofrequency spectra for the beat-note signal. Finally, the authors investigate the phase stability by monitoring the stability of the beat-note signal as a function of different injected powers. Discussions on phase-locking technique could be expected to be helpful in interpreting the coexistence and competition of various nonlinearity in the fiber and widely applied to the optical communication systems.

  7. Atomic-scale evolution of modulated phases at the ferroelectric-antiferroelectric morphotropic phase boundary controlled by flexoelectric interaction

    SciTech Connect (OSTI)

    Borisevich, Albina Y; Eliseev, Eugene; Morozovska, A. N.; Cheng, Ching-Jung; Lin, Jiunn-Yuan; Chu, Ying-Hao; Kan, Daisuke; Takeuchi, Ichiro; Valanoor, Nagarajan V; Kalinin, Sergei V

    2012-01-01

    Physical and structural origins of morphotropic phase boundaries (MPBs) in ferroics remain elusive despite decades of studies. The leading competing theories employ either low symmetry bridging phases or adaptive phases with nanoscale textures to describe different subsets of the macroscopic data, while the decisive atomic-scale information has so far been missing. We report direct atomically-resolved mapping of polarization and structure order parameter fields in Sm-doped BiFeO3 system and their evolution as the system approaches MPB. We further show that both the experimental phase diagram and the phase evolution observed by STEM can be explained by taking into account flexoelectric interaction, which renders the effective domain wall energy negative, thus stabilizing modulated phases in the vicinity of the MPB. Our study highlights the importance of local order parameter mapping at the atomic scale and establishes a hitherto unobserved physical origin of spatially modulated phases existing in the vicinity of the MPB.

  8. The QCD phase diagram from analytic continuation

    E-Print Network [OSTI]

    Bellwied, R; Fodor, Z; Günther, J; Katz, S D; Ratti, C; Szabo, K K

    2015-01-01

    We present the crossover line between the quark gluon plasma and the hadron gas phases for small real chemical potentials. First we determine the effect of imaginary values of the chemical potential on the transition temperature using lattice QCD simulations. Then we use various formulas to perform an analytic continuation to real values of the baryo-chemical potential. Our data set maintains strangeness neutrality to match the conditions of heavy ion physics. The systematic errors are under control up to $\\mu_B\\approx 300$ MeV. For the curvature of the transition line we find that there is an approximate agreement between values from three different observables: the chiral susceptibility, chiral condensate and strange quark susceptibility. The continuum extrapolation is based on $N_t=$ 10, 12 and 16 lattices. By combining the analysis for these three observables we find, for the curvature, the value $\\kappa = 0.0149 \\pm 0.0021$.

  9. Noise in phase-preserving linear amplifiers

    SciTech Connect (OSTI)

    Pandey, Shashank; Jiang, Zhang; Combes, Joshua; Caves, Carlton M.

    2014-12-04

    The purpose of a phase-preserving linear amplifier is to make a small signal larger, so that it can be perceived by instruments incapable of resolving the original signal, while sacrificing as little as possible in signal-to-noise. Quantum mechanics limits how well this can be done: the noise added by the amplifier, referred to the input, must be at least half a quantum at the operating frequency. This well-known quantum limit only constrains the second moments of the added noise. Here we provide the quantum constraints on the entire distribution of added noise: any phasepreserving linear amplifier is equivalent to a parametric amplifier with a physical state ? for the ancillary mode; ? determines the properties of the added noise.

  10. Fourier Analytic Approach to Phase Estimation

    E-Print Network [OSTI]

    Hiroshi Imai; Masahito Hayashi

    2008-10-31

    For a unified analysis on the phase estimation, we focus on the limiting distribution. It is shown that the limiting distribution can be given by the absolute square of the Fourier transform of $L^2$ function whose support belongs to $[-1,1]$. Using this relation, we study the relation between the variance of the limiting distribution and its tail probability. As our result, we prove that the protocol minimizing the asymptotic variance does not minimize the tail probability. Depending on the width of interval, we derive the estimation protocol minimizing the tail probability out of a given interval. Such an optimal protocol is given by a prolate spheroidal wave function which often appears in wavelet or time-limited Fourier analysis. Also, the minimum confidence interval is derived with the framework of interval estimation that assures a given confidence coefficient.

  11. A Phased Array Approach to Rock Blasting

    SciTech Connect (OSTI)

    Leslie Gertsch; Jason Baird

    2006-07-01

    A series of laboratory-scale simultaneous two-hole shots was performed in a rock simulant (mortar) to record the shock wave interference patterns produced in the material. The purpose of the project as a whole was to evaluate the usefulness of phased array techniques of blast design, using new high-precision delay technology. Despite high-speed photography, however, we were unable to detect the passage of the shock waves through the samples to determine how well they matched the expected interaction geometry. The follow-up mine-scale tests were therefore not conducted. Nevertheless, pattern analysis of the vectors that would be formed by positive interference of the shockwaves from multiple charges in an ideal continuous, homogeneous, isotropic medium indicate the potential for powerful control of blast design, given precise characterization of the target rock mass.

  12. Phase-shifting point diffraction interferometer

    DOE Patents [OSTI]

    Medecki, H.

    1998-11-10

    Disclosed is a point diffraction interferometer for evaluating the quality of a test optic. In operation, the point diffraction interferometer includes a source of radiation, the test optic, a beam divider, a reference wave pinhole located at an image plane downstream from the test optic, and a detector for detecting an interference pattern produced between a reference wave emitted by the pinhole and a test wave emitted from the test optic. The beam divider produces separate reference and test beams which focus at different laterally separated positions on the image plane. The reference wave pinhole is placed at a region of high intensity (e.g., the focal point) for the reference beam. This allows reference wave to be produced at a relatively high intensity. Also, the beam divider may include elements for phase shifting one or both of the reference and test beams. 8 figs.

  13. Phase-shifting point diffraction interferometer

    DOE Patents [OSTI]

    Medecki, Hector (Berkeley, CA)

    1998-01-01

    Disclosed is a point diffraction interferometer for evaluating the quality of a test optic. In operation, the point diffraction interferometer includes a source of radiation, the test optic, a beam divider, a reference wave pinhole located at an image plane downstream from the test optic, and a detector for detecting an interference pattern produced between a reference wave emitted by the pinhole and a test wave emitted from the test optic. The beam divider produces separate reference and test beams which focus at different laterally separated positions on the image plane. The reference wave pinhole is placed at a region of high intensity (e.g., the focal point) for the reference beam. This allows reference wave to be produced at a relatively high intensity. Also, the beam divider may include elements for phase shifting one or both of the reference and test beams.

  14. Phases and Structures of Interstellar Gas

    E-Print Network [OSTI]

    B. Elmegreen

    1999-06-12

    The thermal and chemical phases of the cool component of interstellar gas are discussed. Variations with galactocentric radius and from galaxy to galaxy are mostly the result of changes in the ambient interstellar pressure and radiation field. Interstellar structure that is hierarchical or fractal in the cloudy parts and has large and connected empty regions between these clouds is probably the result of turbulence. Such structure opens up the disk to the transmission of OB star light into the halo, and it provides for a diffuse ionized component that tapers away gradually from each dense HII region. Fractal cloud structure may also produce the cloud and clump mass functions, and perhaps even the star cluster mass function.

  15. Method for dissolving delta-phase plutonium

    DOE Patents [OSTI]

    Karraker, David G. (1600 Sherwood Pl., SE., Aiken, SC 29801)

    1992-01-01

    A process for dissolving plutonium, and in particular, delta-phase plutonium. The process includes heating a mixture of nitric acid, hydroxylammonium nitrate (HAN) and potassium fluoride to a temperature between 40.degree. and 70.degree. C., then immersing the metal in the mixture. Preferably, the nitric acid has a concentration of not more than 2M, the HAN approximately 0.66M, and the potassium fluoride 0.1M. Additionally, a small amount of sulfamic acid, such as 0.1M can be added to assure stability of the HAN in the presence of nitric acid. The oxide layer that forms on plutonium metal may be removed with a non-oxidizing acid as a pre-treatment step.

  16. Dry powder mixes comprising phase change materials

    DOE Patents [OSTI]

    Salyer, Ival O. (Dayton, OH)

    1994-01-01

    Free flowing, conformable powder-like mix of silica particles and a phase change material (PCM) is provided. The silica particles have a critical size of about 0.005 to about 0.025 microns and the PCM must be added to the silica in an amount of 75% or less PCM per combined weight of silica and PCM. The powder-like mix can be used in tableware items, medical wraps, tree wraps, garments, quilts and blankets, and in cementitious compositions of the type in which it is beneficial to use a PCM material. The silica-PCM mix can also be admixed with soil to provide a soil warming effect and placed about a tree, flower, or shrub.

  17. Phase I Report: DARPA Exoskeleton Program

    SciTech Connect (OSTI)

    Jansen, J.F.

    2004-01-21

    The Defense Advanced Research Projects Agency (DARPA) inaugurated a program addressing research and development for an Exoskeleton for Human Performance Augmentation in FY!2001. A team consisting of Oak Ridge National Laboratory, the prime contractor, AeroVironment, Inc., the Army Research Laboratory, the University of Minnesota, and the Virginia Polytechnic Institute has recently completed an 18-month Phase I effort in support of this DARPA program. The Phase I effort focused on the development and proof-of-concept demonstrations for key enabling technologies, laying the foundation for subsequently building and demonstrating a prototype exoskeleton. The overall approach was driven by the need to optimize energy efficiency while providing a system that augmented the operator in as transparent manner as possible (non-impeding). These needs led to the evolution of two key distinguishing features of this team's approach. The first is the ''no knee contact'' concept. This concept is dependent on a unique Cartesian-based control scheme that uses force sensing at the foot and backpack attachments to allow the exoskeleton to closely follow the operator while avoiding the difficulty of connecting and sensing position at the knee. The second is an emphasis on energy efficiency manifested by an energetic, power, actuation and controls approach designed to enhance energy efficiency as well as a reconfigurable kinematic structure that provides a non-anthropomorphic configuration to support an energy saving long-range march/transport mode. The enabling technologies addressed in the first phase were controls and sensing, the soft tissue interface between the machine and the operator, the power system, and actuation. The controller approach was implemented and demonstrated on a test stand with an actual operator. Control stability, low operator fatigue, force amplification and the human interface were all successfully demonstrated, validating the controls approach. A unique, lightweight, low profile, multi-axis foot sensor (an integral element of the controls approach) was designed, fabricated, and its performance verified. A preliminary conceptual design of the human coupling and soft tissue interface, based on biomechanics research has been developed along with a test plan to support an iterative design process. The power system concept, a fuel cell hybrid power supply using chemical generated hydrogen, was successfully demonstrated and shown to be able to efficiently meet both steady-state and transient peak loads. Two actuator approaches, a piezoelectric actuator, with theoretical high power densities and an approach based on a high-performance, high-speed electric motor driving a miniature hydraulic pump have been investigated. The first shows great potential but will require further research before reaching that promise. The other approach has been modeled and simulated and shown to provide the possibility for significant energy savings (>30%) and improved power densities in comparison to conventional hydraulics. Biomechanics analysis and testing were also performed in support of these enabling technologies, to provide a basis for design criteria. An analysis was performed to determine baseline data for initial mechanical design and power supply sizing. Testing conducted to evaluate boot sole thickness found that thickness increases up to two inches could be accommodated without significant impact on human factors issues. This 18-month long Phase I effort has evaluated key enabling technologies and demonstrated advances in these technologies that have significantly increased the likelihood of building a functional prototype exoskeleton.

  18. Dry powder mixes comprising phase change materials

    DOE Patents [OSTI]

    Salyer, I.O.

    1993-05-18

    Free flowing, conformable powder-like mix of silica particles and a phase change material (p.c.m.) is disclosed. The silica particles have a critical size of about 7[times]10[sup [minus]3] to about 7[times]10[sup [minus]2] microns and the p.c.m. must be added to the silica in an amount of 80 wt. % or less p.c.m. per combined weight of silica and p.c.m. The powder-like mix can be used in tableware items, medical wraps, tree wraps, garments, quilts and blankets, and in cementitious compositions of the type in which it is beneficial to use a p.c.m. material. The silica-p.c.m. mix can also be admixed with soil to provide a soil warming effect and placed about a tree, flower, or shrub.

  19. Dry powder mixes comprising phase change materials

    DOE Patents [OSTI]

    Salyer, I.O.

    1994-02-01

    Free flowing, conformable powder-like mix of silica particles and a phase change material (PCM) is provided. The silica particles have a critical size of about 0.005 to about 0.025 microns and the PCM must be added to the silica in an amount of 75% or less PCM per combined weight of silica and PCM. The powder-like mix can be used in tableware items, medical wraps, tree wraps, garments, quilts and blankets, and in cementitious compositions of the type in which it is beneficial to use a PCM material. The silica-PCM mix can also be admixed with soil to provide a soil warming effect and placed about a tree, flower, or shrub. 2 figures.

  20. Dry powder mixes comprising phase change materials

    DOE Patents [OSTI]

    Salyer, I.O.

    1992-04-21

    A free flowing, conformable powder-like mix of silica particles and a phase change material (p.c.m.) is disclosed. The silica particles have a critical size of about 7 [times] 10[sup [minus]3] to about 7 [times] 10[sup [minus]2] microns and the pcm must be added to the silica in an amount of 80 wt. % or less pcm per combined weight of silica and pcm. The powder-like mix can be used in tableware items, medical wraps, tree wraps, garments, quilts and blankets, and in cementitious compositions of the type in which it is beneficial to use a pcm material. The silica-pcm mix can also be admixed with soil to provide a soil warming effect and placed about a tree, flower, or shrub. 9 figs.

  1. Transuranic (TRU) Waste Phase I Retrieval Plan

    SciTech Connect (OSTI)

    MCDONALD, K.M.

    2000-09-28

    From 1970 to 1987, TRU and suspect TRU wastes at Hanford were placed in the SWBG. At the time of placement in the SWBG these wastes were not regulated under existing Resource Conservation and Recovery Act (RCRA) regulations, since they were generated and disposed of prior to the effective date of RCRA at the Hanford Site (1987). From the standpoint of DOE Order 5820.2A1, the TRU wastes are considered retrievably stored, and current plans are to retrieve these wastes for shipment to WIPP for disposal. This plan provides a strategy for the Phase I retrieval that meets the intent of TPA milestone M-91 and Project W-113, and incorporates the lessons learned during TRU retrieval campaigns at Hanford, LANL, and SRS. As in the original Project W-113 plans, the current plan calls for examination of approximately 10,000 suspect-TRU drums located in the 218-W-4C burial ground followed by the retrieval of those drums verified to contain TRU waste. Unlike the older plan, however, this plan proposes an open-air retrieval scenario similar to those used for TRU drum retrieval at LANL and SRS. Phase I retrieval consists of the activities associated with the assessment of approximately 10,000 55-gallon drums of suspect TRU-waste in burial ground 218-W-4C and the retrieval of those drums verified to contain TRU waste. Four of the trenches in 218-W-4C (Trenches 1, 4, 20, and 29) are prime candidates for Phase I retrieval because they contain large numbers of suspect TRU drums, stacked from 2 to 5 drums high, on an asphalt pad. In fact, three of the trenches (Trenches 1 , 20, and 29) contain waste that has not been covered with soil, and about 1500 drums can be retrieved without excavation. The other three trenches in 218-W-4C (Trenches 7, 19, and 24) are not candidates for Phase I retrieval because they contain significant numbers of boxes. Drums will be retrieved from the four candidate trenches, checked for structural integrity, overpacked, if necessary, and assayed at the burial ground. A mobile assay system will be used to determine if the drum is LLW (Le., contains <100 nCi/g). LLW will remain disposed of in the 218-W-4C Burial Ground. TRU waste will be retrieved and staged in the burial ground until it can be shipped to the CWC. The TRU drums will be stored at the CWC until they can be moved to WRAP. The WRAP facility will prepare the waste for shipment to WIPP for final disposal. For planning purposes, approximately 50% of the 10,000 drums have been estimated to contain LLW.

  2. Solid phase microextraction device using aerogel

    DOE Patents [OSTI]

    Miller, Fred S.; Andresen, Brian D.

    2005-06-14

    A sample collection substrate of aerogel and/or xerogel materials bound to a support structure is used as a solid phase microextraction (SPME) device. The xerogels and aerogels may be organic or inorganic and doped with metals or other compounds to target specific chemical analytes. The support structure is typically formed of a glass fiber or a metal wire (stainless steel or kovar). The devices are made by applying gel solution to the support structures and drying the solution to form aerogel or xerogel. Aerogel particles may be attached to the wet layer before drying to increase sample collection surface area. These devices are robust, stable in fields of high radiation, and highly effective at collecting gas and liquid samples while maintaining superior mechanical and thermal stability during routine use. Aerogel SPME devices are advantageous for use in GC/MS analyses due to their lack of interfering background and tolerance of GC thermal cycling.

  3. Does Sex Induce a Phase Transition?

    E-Print Network [OSTI]

    de Oliveira, P M C; Stauffer, D; Cebrat, S; Pekalski, A; 10.1140/epjb/e2008-00229-3

    2009-01-01

    We discovered a dynamic phase transition induced by sexual reproduction. The dynamics is a pure Darwinian rule with both fundamental ingredients to drive evolution: 1) random mutations and crossings which act in the sense of increasing the entropy (or diversity); and 2) selection which acts in the opposite sense by limiting the entropy explosion. Selection wins this competition if mutations performed at birth are few enough. By slowly increasing the average number m of mutations, however, the population suddenly undergoes a mutational degradation precisely at a transition point mc. Above this point, the "bad" alleles spread over the genetic pool of the population, overcoming the selection pressure. Individuals become selectively alike, and evolution stops. Only below this point, m < mc, evolutionary life is possible. The finite-size-scaling behaviour of this transition is exhibited for large enough "chromosome" lengths L. One important and surprising observation is the L-independence of the transition curv...

  4. Benchmark On Sensitivity Calculation (Phase III)

    SciTech Connect (OSTI)

    Ivanova, Tatiana [IRSN; Laville, Cedric [IRSN; Dyrda, James [Atomic Weapons Establishment; Mennerdahl, Dennis [E. Mennerdahl Systems; Golovko, Yury [Institute of Physics and Power Engineering (IPPE), Obninsk, Russia; Raskach, Kirill [Institute of Physics and Power Engineering (IPPE), Obninsk, Russia; Tsiboulia, Anatoly [Institute of Physics and Power Engineering (IPPE), Obninsk, Russia; Lee, Gil Soo [Korea Institute of Nuclear Safety (KINS); Woo, Sweng-Woong [Korea Institute of Nuclear Safety (KINS); Bidaud, Adrien [Labratoire de Physique Subatomique et de Cosmolo-gie (LPSC); Patel, Amrit [NRC; Bledsoe, Keith C [ORNL; Rearden, Bradley T [ORNL; Gulliford, J. [OECD Nuclear Energy Agency

    2012-01-01

    The sensitivities of the keff eigenvalue to neutron cross sections have become commonly used in similarity studies and as part of the validation algorithm for criticality safety assessments. To test calculations of the sensitivity coefficients, a benchmark study (Phase III) has been established by the OECD-NEA/WPNCS/EG UACSA (Expert Group on Uncertainty Analysis for Criticality Safety Assessment). This paper presents some sensitivity results generated by the benchmark participants using various computational tools based upon different computational methods: SCALE/TSUNAMI-3D and -1D, MONK, APOLLO2-MORET 5, DRAGON-SUSD3D and MMKKENO. The study demonstrates the performance of the tools. It also illustrates how model simplifications impact the sensitivity results and demonstrates the importance of 'implicit' (self-shielding) sensitivities. This work has been a useful step towards verification of the existing and developed sensitivity analysis methods.

  5. Combined Experiment Phase 1. Final report

    SciTech Connect (OSTI)

    Butterfield, C.P.; Musial, W.P.; Simms, D.A.

    1992-10-01

    How does wind tunnel airfoil data differ from the airfoil performance on an operating horizontal axis wind turbine (HAWT)? The National Renewable Energy laboratory has been conducting a comprehensive test program focused on answering this question and understanding the basic fluid mechanics of rotating HAWT stall aerodynamics. The basic approach was to instrument a wind rotor, using an airfoil that was well documented by wind tunnel tests, and measure operating pressure distributions on the rotating blade. Based an the integrated values of the pressure data, airfoil performance coefficients were obtained, and comparisons were made between the rotating data and the wind tunnel data. Care was taken to the aerodynamic and geometric differences between the rotating and the wind tunnel models. This is the first of two reports describing the Combined Experiment Program and its results. This Phase I report covers background information such as test setup and instrumentation. It also includes wind tunnel test results and roughness testing.

  6. Dry powder mixes comprising phase change materials

    DOE Patents [OSTI]

    Salyer, I.O.

    1993-10-19

    Free flowing, conformable powder-like mix of silica particles and a phase change material (pcm) is disclosed. The silica particles have a critical size of about 7[times]10[sup [minus]3] to about 7[times]10[sup [minus]2] microns and the pcm must be added to the silica in an amount of 80 wt. % or less pcm per combined weight of silica and pcm. The powder-like mix can be used in tableware items, medical wraps, tree wraps, garments, quilts and blankets, and in cementitious compositions of the type in which it is beneficial to use a pcm material. The silica-pcm mix can also be admixed with soil to provide a soil warming effect and placed about a tree, flower, or shrub. 10 figures.

  7. Monitoring of vapor phase polycyclic aromatic hydrocarbons

    DOE Patents [OSTI]

    Vo-Dinh, Tuan; Hajaligol, Mohammad R.

    2004-06-01

    An apparatus for monitoring vapor phase polycyclic aromatic hydrocarbons in a high-temperature environment has an excitation source producing electromagnetic radiation, an optical path having an optical probe optically communicating the electromagnetic radiation received at a proximal end to a distal end, a spectrometer or polychromator, a detector, and a positioner coupled to the first optical path. The positioner can slidably move the distal end of the optical probe to maintain the distal end position with respect to an area of a material undergoing combustion. The emitted wavelength can be directed to a detector in a single optical probe 180.degree. backscattered configuration, in a dual optical probe 180.degree. backscattered configuration or in a dual optical probe 90.degree. side scattered configuration. The apparatus can be used to monitor an emitted wavelength of energy from a polycyclic aromatic hydrocarbon as it fluoresces in a high temperature environment.

  8. Long Time Evolution of Phase Oscillator Systems

    E-Print Network [OSTI]

    Edward Ott; Thomas M. Antonsen

    2009-04-16

    It is shown, under weak conditions, that the dynamical evolution of an important class of large systems of globally coupled, heterogeneous frequency, phase oscillators is, in an appropriate physical sense, time-asymptotically attracted toward a reduced manifold of system states. This manifold, which is invariant under the system evolution, was previously known and used to facilitate the discovery of attractors and bifurcations of such systems. The result of this paper establishes that attractors for the order parameter dynamics obtained by restriction to this reduced manifold are, in fact, the only such attractors of the full system. Thus all long time dynamical behavior of the order parameters of these systems can be obtained by restriction to the reduced manifold.

  9. Artists, Patrons, and Trust in Seventeenth-Century Naples: The Case of the Certosa di San Martino

    E-Print Network [OSTI]

    Napoli, J. Nicholas

    2012-01-01

    Emerging Unharmed from the Furnace. It is mentioned byEmerging Unharmed from the Furnace (Fig. 4), painted for theEmerging Unharmed from the Furnace (1647, a commission given

  10. Artists, Patrons, and Trust in Seventeenth-Century Naples: The Case of the Certosa di San Martino

    E-Print Network [OSTI]

    Napoli, J. Nicholas

    2012-01-01

    B. Jordan. Ex. cat. , Kimbell Art Museum, Fort Worth, 1982.B. Jordan, ex. cat. , Kimbell Art Museum, Fort Worth, 1982 (

  11. Public Happiness as the Wealth of Nations: The Rise of Political Economy in Naples in a Comparative Perspective

    E-Print Network [OSTI]

    Sabetti, Filippo

    2012-01-01

    Inediti. Milan: Giuffre’. Vitale, Marco 2001. “Startingsciences (Pecchio quoted in Vitale 2001: 131, and also in

  12. Artists, Patrons, and Trust in Seventeenth-Century Naples: The Case of the Certosa di San Martino

    E-Print Network [OSTI]

    Napoli, J. Nicholas

    2012-01-01

    of the local painter Filippo Vitale and sister of Pacecco delaw to the painter Filippo Vitale and brother-in-law to the

  13. Microsoft Word - DOE_RM_DM-#102768-v1-NAPL_Quarterly_Report_Jan-March_2005.ƒ

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-SessionsSouth DakotaRobbins and MyersHr. Anthony V.How DisposalInterim16 U.S.

  14. Microsoft Word - DOE_RM_DM-#344133-v1-Final_NAPL_Quarterly_July-Sept_2005.Dƒ

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-SessionsSouth DakotaRobbins and MyersHr. Anthony V.How DisposalInterim1661 2005

  15. Microsoft Word - DOE_RM_DM-#99768-v1-NAPL_Quarterly_Report_for_July-Sept_20ƒ

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-SessionsSouth DakotaRobbins and MyersHr. Anthony V.HowJanuary2004 - - GJ749July

  16. Atomic Structure and Phase Transformations in Pu Alloys

    SciTech Connect (OSTI)

    Schwartz, A J; Cynn, H; Blobaum, K M; Wall, M A; Moore, K T; Evans, W J; Farber, D L; Jeffries, J R; Massalski, T B

    2008-04-28

    Plutonium and plutonium-based alloys containing Al or Ga exhibit numerous phases with crystal structures ranging from simple monoclinic to face-centered cubic. Only recently, however, has there been increased convergence in the actinides community on the details of the equilibrium form of the phase diagrams. Practically speaking, while the phase diagrams that represent the stability of the fcc {delta}-phase field at room temperature are generally applicable, it is also recognized that Pu and its alloys are never truly in thermodynamic equilibrium because of self-irradiation effects, primarily from the alpha decay of Pu isotopes. This article covers past and current research on several properties of Pu and Pu-(Al or Ga) alloys and their connections to the crystal structure and the microstructure. We review the consequences of radioactive decay, the recent advances in understanding the electronic structure, the current research on phase transformations and their relations to phase diagrams and phase stability, the nature of the isothermal martensitic {delta} {yields} {alpha}{prime} transformation, and the pressure-induced transformations in the {delta}-phase alloys. New data are also presented on the structures and phase transformations observed in these materials following the application of pressure, including the formation of transition phases.

  17. Helical Phase Inflation and Monodromy in Supergravity Theory

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Li, Tianjun; Li, Zhijin; Nanopoulos, Dimitri V.

    2015-01-01

    We study helical phase inflation which realizes “monodromy inflation” in supergravity theory. In the model, inflation is driven by the phase component of a complex field whose potential possesses helicoid structure. We construct phase monodromy based on explicitly breaking global U ( 1 ) symmetry in the superpotential. By integrating out heavy fields, the phase monodromy from single complex scalar field is realized and the model fulfills natural inflation. The phase-axion alignment is achieved from explicitly symmetry breaking and gives super-Planckian phase decay constant. The F -term scalarmore »potential provides strong field stabilization for all the scalars except inflaton, which is protected by the approximate global U ( 1 ) symmetry. Besides, we show that helical phase inflation can be naturally realized in no-scale supergravity with S U ( 2,1 ) / S U ( 2 ) × U ( 1 ) symmetry since the supergravity setup needed for phase monodromy is automatically provided in the no-scale Kähler potential. We also demonstrate that helical phase inflation can be reduced to another well-known supergravity inflation model with shift symmetry. Helical phase inflation is free from the UV-sensitivity problem although there is super-Planckian field excursion, and it suggests that inflation can be effectively studied based on supersymmetric field theory while a UV-completed framework is not prerequisite. « less

  18. Improving experimental phases for strong reflections prior to density modification

    SciTech Connect (OSTI)

    Uervirojnangkoorn, Monarin [University of Lübeck, Ratzeburger Allee 160, 23538 Lübeck (Germany); University of Lübeck, Ratzeburger Allee 160, 23538 Lübeck (Germany); Hilgenfeld, Rolf, E-mail: hilgenfeld@biochem.uni-luebeck.de [University of Lübeck, Ratzeburger Allee 160, 23538 Lübeck (Germany); Chinese Academy of Sciences, 555 Zu Chong Zhi Road, Shanghai 201203, People’s Republic of (China); Terwilliger, Thomas C. [Los Alamos National Laboratory, Los Alamos, NM 87545 (United States); Read, Randy J. [University of Cambridge, Cambridge CB2 0XY (United Kingdom); University of Lübeck, Ratzeburger Allee 160, 23538 Lübeck (Germany)

    2013-10-01

    A genetic algorithm has been developed to optimize the phases of the strongest reflections in SIR/SAD data. This is shown to facilitate density modification and model building in several test cases. Experimental phasing of diffraction data from macromolecular crystals involves deriving phase probability distributions. These distributions are often bimodal, making their weighted average, the centroid phase, improbable, so that electron-density maps computed using centroid phases are often non-interpretable. Density modification brings in information about the characteristics of electron density in protein crystals. In successful cases, this allows a choice between the modes in the phase probability distributions, and the maps can cross the borderline between non-interpretable and interpretable. Based on the suggestions by Vekhter [Vekhter (2005 ?), Acta Cryst. D61, 899–902], the impact of identifying optimized phases for a small number of strong reflections prior to the density-modification process was investigated while using the centroid phase as a starting point for the remaining reflections. A genetic algorithm was developed that optimizes the quality of such phases using the skewness of the density map as a target function. Phases optimized in this way are then used in density modification. In most of the tests, the resulting maps were of higher quality than maps generated from the original centroid phases. In one of the test cases, the new method sufficiently improved a marginal set of experimental SAD phases to enable successful map interpretation. A computer program, SISA, has been developed to apply this method for phase improvement in macromolecular crystallography.

  19. Phase plate technology for laser marking of magnetic discs

    DOE Patents [OSTI]

    Neuman, B.; Honig, J.; Hackel, L.; Dane, C.B.; Dixit, S.

    1998-10-27

    An advanced design for a phase plate enables the distribution of spots in arbitrarily shaped patterns with very high uniformity and with a continuously or near-continuously varying phase pattern. A continuous phase pattern eliminates large phase jumps typically expected in a grating that provides arbitrary shapes. Large phase jumps increase scattered light outside of the desired pattern, reduce efficiency and can make the grating difficult to manufacture. When manufacturing capabilities preclude producing a fully continuous grating, the present design can be easily adapted to minimize manufacturing errors and maintain high efficiencies. This continuous grating is significantly more efficient than previously described Dammann gratings, offers much more flexibility in generating spot patterns and is easier to manufacture and replicate than a multi-level phase grating. 3 figs.

  20. Scale and electroweak first-order phase transitions

    E-Print Network [OSTI]

    Jisuke Kubo; Masatoshi Yamada

    2015-09-07

    We consider phase transitions in the standard model (SM) without the Higgs mass term, which is coupled through a Higgs portal term to an SM singlet, classically scale-invariant gauge sector with SM singlet scalar fields. At lower energies the gauge-invariant scalar bilinear in the hidden sector forms a condensate, dynamically creating a robust energy scale, which is transmitted through the Higgs portal term to the SM sector. A scale phase transition is a transition between phases with zero and nonzero condensates. An interplay between the EW and scale phase transitions is therefore expected. We find that in a certain parameter space both the electroweak (EW) and scale phase transitions can be a strong first-order phase transition. The result is obtained by means of an effective theory for the condensation of scalar bilinear in the mean field approximation.

  1. Magnetic Nanorods Confined in a Lamellar Lyotropic Phase

    E-Print Network [OSTI]

    Keevin Béneut; Doru Constantin; Patrick Davidson; Arnaud Dessombz; Corinne Chanéac

    2015-04-11

    The dilute lamellar phase of the nonionic surfactant C$_{12}$EO$_5$ was doped with goethite (iron oxide) nanorods up to a fraction of 5 vol. %. The interaction between the inclusions and the host phase was studied by polarized optical microscopy (with or without an applied magnetic field) and by small-angle X-ray scattering. We find that, when the orientation of the nanorods is modified using the magnetic field, the texture of the lamellar phase changes accordingly; one can thus induce a homeotropic-planar reorientation transition. On the other hand, the lamellar phase induces an attractive interaction between the nanorods. In more concentrated lamellar phases (under stronger confinement) the particles form aggregates. This behavior is not encountered for a similar system doped with spherical particles, emphasizing the role of particle shape in the interaction between doping particles and the host phase.

  2. How do rewritable DVDs work? Optical properties of phase-change materials

    E-Print Network [OSTI]

    Botti, Silvana

    questions for Phase Change Materials optimization Local structural changes upon amorphization Optical questions for Phase Change Materials optimization Outline 1 Introduction to Phase Change Materials (PCMs) 2 Open questions for Phase Change Materials optimization Local structural changes upon amorphization

  3. FGD systems: What utilities chose in phase 1 and what they might choose in phase 2

    SciTech Connect (OSTI)

    South, D.W.; Bailey, K.A.

    1995-07-01

    Title IV (acid rain) of the Clean Air Act Amendments of 1990 is imposing new limitations on the emission of sulfur dioxide (SO{sub 2}) and nitrogen oxides (NO{sub x}) from electric power plants. The Act requires utilities to develop compliance plans to reduce these emissions, and indications are that these plans will dramatically alter traditional operating procedures. A key provision of the SO{sub 2} control program defined in Title IV is the creation of a system of emission allowances, with utilities having, the option of complying by adjusting system emissions and allowance holdings. The central focus of this paper is the identification of sulfur dioxide (SO{sub 2}) control options being implemented by the electric utility industry, current compliance trends, synergistic control issues and a discussion of the implications of Phase I decisions for Phase II.

  4. Non-Equilibrium Phase Transition in Rapidly Expanding Matter

    E-Print Network [OSTI]

    I. N. Mishustin

    1999-04-29

    Non-equilibrium features of a first order phase transition from the quark-gluon plasma to a hadronic gas in relativistic heavy-ion collisions are discussed. It is demonstrated that strong collective expansion may lead to the fragmentation of the plasma phase into droplets surrounded by undersaturated hadronic gas. Subsequent hadronization of droplets will generate strong non-statistical fluctuations in the hadron rapidity distribution in individual events. The strongest fluctuations are expected in the vicinity of the phase transition threshold.

  5. Geometric Phase and Chiral Anomaly in Path Integral Formulation

    E-Print Network [OSTI]

    Kazuo Fujikawa

    2007-11-16

    All the geometric phases, adiabatic and non-adiabatic, are formulated in a unified manner in the second quantized path integral formulation. The exact hidden local symmetry inherent in the Schr\\"{o}dinger equation defines the holonomy. All the geometric phases are shown to be topologically trivial. The geometric phases are briefly compared to the chiral anomaly which is naturally formulated in the path integral.

  6. Discovery of a metastable Al20Sm4 phase

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ye, Z.; Zhang, F.; Sun, Y.; Mendelev, M. I.; Ott, R. T.; Park, E.; Besser, M. F.; Kramer, M. J.; Ding, Z.; Wang, C. -Z.; et al

    2015-03-09

    In this study, we present an efficient genetic algorithm, integrated with experimental diffraction data, to solve a nanoscale metastable Al20Sm4 phase that evolves during crystallization of an amorphous magnetron sputtered Al90Sm10 alloy. The excellent match between calculated and experimental X-ray diffraction patterns confirms an accurate description of this metastable phase. Molecular dynamic simulations of crystal growth from the liquid phase predict the formation of disordered defects in the devitrified crystal.

  7. 2-D weighted least-squares phase unwrapping

    DOE Patents [OSTI]

    Ghiglia, Dennis C. (Placitas, NM); Romero, Louis A. (Albuquerque, NM)

    1995-01-01

    Weighted values of interferometric signals are unwrapped by determining the least squares solution of phase unwrapping for unweighted values of the interferometric signals; and then determining the least squares solution of phase unwrapping for weighted values of the interferometric signals by preconditioned conjugate gradient methods using the unweighted solutions as preconditioning values. An output is provided that is representative of the least squares solution of phase unwrapping for weighted values of the interferometric signals.

  8. The effects of two-phase flow on streaming potentials 

    E-Print Network [OSTI]

    Estrada, Cecilia

    1993-01-01

    a porous media via a pressure gradient. It is expected that a second fluid phase will enhance the streaming potential values. The enhancement occurs as the percentage of electrically non- conducting phase increases and/or as the fluid velocity...-conducting phase an enhancement range of . 4 to 1. 93 was observed. Existing theory for the enhancement of streaming potentials was used to model the experimental results, The theoretical equation has a hydrodynamic resistance factor, W, that is determined from...

  9. Coherent optical monolithic phased-array antenna steering system

    DOE Patents [OSTI]

    Hietala, Vincent M. (Placitas, NM); Kravitz, Stanley H. (Placitas, NM); Vawter, Gregory A. (Albuquerque, NM)

    1994-01-01

    An optical-based RF beam steering system for phased-array antennas comprising a photonic integrated circuit (PIC). The system is based on optical heterodyning employed to produce microwave phase shifting by a monolithic PIC constructed entirely of passive components. Microwave power and control signal distribution to the antenna is accomplished by optical fiber, permitting physical separation of the PIC and its control functions from the antenna. The system reduces size, weight, complexity, and cost of phased-array antenna systems.

  10. Quantum phase transition of condensed bosons in optical lattices

    E-Print Network [OSTI]

    Jun-Jun Liang; J. -Q. Liang; W. -M. Liu

    2004-03-23

    In this paper we study the superfluid-Mott-insulator phase transition of ultracold dilute gas of bosonic atoms in an optical lattice by means of Green function method and Bogliubov transformation as well. The superfluid- Mott-insulator phase transition condition is determined by the energy-band structure with an obvious interpretation of the transition mechanism. Moreover the superfluid phase is explained explicitly from the energy spectrum derived in terms of Bogliubov approach.

  11. 2-D weighted least-squares phase unwrapping

    DOE Patents [OSTI]

    Ghiglia, D.C.; Romero, L.A.

    1995-06-13

    Weighted values of interferometric signals are unwrapped by determining the least squares solution of phase unwrapping for unweighted values of the interferometric signals; and then determining the least squares solution of phase unwrapping for weighted values of the interferometric signals by preconditioned conjugate gradient methods using the unweighted solutions as preconditioning values. An output is provided that is representative of the least squares solution of phase unwrapping for weighted values of the interferometric signals. 6 figs.

  12. Mechanics of Metals with Phase Changes

    SciTech Connect (OSTI)

    Lashley, J.C.

    2001-01-01

    New experimental data is presented on some exotic metals that exhibit phase changes at cryogenic temperatures. The types of phase changes that were detected in the specific heat data range from martensitic (diffusion less) transitions to superconducting transitions. In addition, the charge density wave (CDW) state in uranium metal was detected in the specific heat. Specific-heat measurements were made in zero-magnetic field using an apparatus capable of obtaining temperatures as low as 0.4 K. Calibration performed on this apparatus, using a single-crystal copper sample, show its accuracy to be 0.50%, while the resolution was better than 0.1%. Our measurements demonstrate that similar high precision and accurate specific-heat measurements can be obtained on milligram-scale samples. In Chapters 2 and 3, specific-heat measurements are presented for the B2 (CsCl structure) alloy AuZn and for {alpha}-uranium (orthorhombic symmetry). The AuZn alloy exhibits a continuous transition at 64.75 K and an entropy of transition of ({Delta}S{sub tr}) 2.02 J K{sup {minus}1} mol{sup {minus}1}. Calculation of the Debye temperature, by extrapolating of the high temperature phase elastic constants to T = 0 K yields a value of 207 K ({+-}2 K), in favorable agreement with the calorimetric value of 219 K ({+-}0.50 K), despite the intervening martensitic transition. Reported results for single-crystal {alpha}-U show a low-temperature limiting {Theta}{sub D} of 256 K ({+-}0.50 K) and four low-temperature anomalies: a superconducting transition below 1 K, an electronic transition at 22 K, and two anomalies at 38 K and at 42 K indicative of the CDW state. In order to continue the study of the actinide series of elements, a program was initiated to first purify and then grow single crystals of plutonium. Accordingly, the focus of Chapters 4 through 6 will be a description of plutonium sample preparation. In this program plutonium metal was purified via zone refining, using a levitated molten zone to minimize the introduction of impurities. Several impurities were reduced to levels below that of instrument detection limits. Results indicate that six sequential zone refining passes are required to obtain metal with 130 ppm total impurities (excluding N, O, F, Cl, and Br). Small single crystals with a volume of 1 mm{sup 3} were grown of {delta}-plutonium by a strain-anneal technique. The values obtained for the critical strain in the strain-anneal experiments are in favorable agreement with values obtained by other researches using loading methods other than biaxial loading.

  13. CONVERSION EXTRACTION DESULFURIZATION (CED) PHASE III

    SciTech Connect (OSTI)

    James Boltz

    2005-03-01

    This project was undertaken to refine the Conversion Extraction Desulfurization (CED) technology to efficiently and economically remove sulfur from diesel fuel to levels below 15-ppm. CED is considered a generic term covering all desulfurization processes that involve oxidation and extraction. The CED process first extracts a fraction of the sulfur from the diesel, then selectively oxidizes the remaining sulfur compounds, and finally extracts these oxidized materials. The Department of Energy (DOE) awarded Petro Star Inc. a contract to fund Phase III of the CED process development. Phase III consisted of testing a continuous-flow process, optimization of the process steps, design of a pilot plant, and completion of a market study for licensing the process. Petro Star and the Degussa Corporation in coordination with Koch Modular Process Systems (KMPS) tested six key process steps in a 7.6-centimeter (cm) (3.0-inch) inside diameter (ID) column at gas oil feed rates of 7.8 to 93.3 liters per hour (l/h) (2.1 to 24.6 gallons per hour). The team verified the technical feasibility with respect to hydraulics for each unit operation tested and successfully demonstrated pre-extraction and solvent recovery distillation. Test operations conducted at KMPS demonstrated that the oxidation reaction converted a maximum of 97% of the thiophenes. The CED Process Development Team demonstrated that CED technology is capable of reducing the sulfur content of light atmospheric gas oil from 5,000-ppm to less than 15-ppm within the laboratory scale. In continuous flow trials, the CED process consistently produced fuel with approximately 20-ppm of sulfur. The process economics study calculated an estimated process cost of $5.70 per product barrel. The Kline Company performed a marketing study to evaluate the possibility of licensing the CED technology. Kline concluded that only 13 refineries harbored opportunity for the CED process. The Kline study and the research team's discussions with prospective refineries led to the conclusion that there were not likely prospects for the licensing of the CED process.

  14. FY 2014 Phase II Release 2+ EERE Awards

    Office of Energy Efficiency and Renewable Energy (EERE)

    FY 2014 Phase II Release 2+ EERE Awards, from the U.S. Department of Energy, Small Business Innovation Research (SBIR) program.

  15. Attachment 1: DOE Phased Retirement Implementation Plan Purpose...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Plan Purpose: Phased retirement is designed to assist agencies with knowledge management and continuity of operations in the short term. Although the main purpose is to...

  16. New nano-mechanical plasmonic phase modulator offers electronics...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    nano-mechanical plasmonic phase modulator offers electronics potential April 3, 2015 Tweet EmailPrint By using standard semiconductor manufacturing equipment, a team of scientists...

  17. Two-Phase Cooling Technology for Power Electronics with Novel...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Electronics with Novel Coolants Two-Phase Cooling Technology for Power Electronics with Novel Coolants 2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program...

  18. Hybrid Fiber Reinforced Concrete Incorporated With Phase Change Material

    E-Print Network [OSTI]

    Chuang, Chia-So

    2015-01-01

    characterization and thermal stability." Solar Energycharacterization and thermal stability." Solar Energythermal performance of shape-stabilized phase change material floor used in passive solar buildings." Energy and

  19. Equations of state and phase diagrams of hydrogen isotopes

    SciTech Connect (OSTI)

    Urlin, V. D.

    2013-11-15

    A new form of the semiempirical equation of state proposed for the liquid phase of hydrogen isotopes is based on the assumption that its structure is formed by cells some of which contain hydrogen molecules and others contain hydrogen atoms. The values of parameters in the equations of state of the solid (molecular and atomic) phases as well as of the liquid phase of hydrogen isotopes (protium and deuterium) are determined. Phase diagrams, shock adiabats, isentropes, isotherms, and the electrical conductivity of compressed hydrogen are calculated. Comparison of the results of calculations with available experimental data in a wide pressure range demonstrates satisfactory coincidence.

  20. Phase-space jets drive transport and anomalous resistivity (Journal...

    Office of Scientific and Technical Information (OSTI)

    transport and anomalous resistivity In the presence of wave dissipation, phase-space structures spontaneously emerge in nonlinear Vlasov dynamics. These structures include not only...

  1. Selective gas adsorption and unique phase transition properties...

    Office of Scientific and Technical Information (OSTI)

    Selective gas adsorption and unique phase transition properties in a stable magnesium metal-organic framework constructed from infinite metal chains Citation Details In-Document...

  2. Small Business Innovation Research (SBIR) FY 2014 Phase I topics...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    truck for waste hauling applications. The fuel cells should be those that operate on hydrogen fuel. In Phase II DOE will seek new applications for projects that demonstrate...

  3. DOE Awards Two Small Business Innovation Research Phase II Grants...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    sbir. The Phase II awards related to SSL are listed below: Recipient: Physical Optics Corporation (POC) Title: Highly Efficient Organic Light-Emitting Devices for General...

  4. Phase 1 of the Advanced Collaborative Emissions Study (ACES)...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    1 of the Advanced Collaborative Emissions Study (ACES): Highlights of Project Finding Phase 1 of the Advanced Collaborative Emissions Study (ACES): Highlights of Project Finding...

  5. Topological phase diagram and saddle point singularity in a tunable...

    Office of Scientific and Technical Information (OSTI)

    Topological phase diagram and saddle point singularity in a tunable topological crystalline insulator Citation Details In-Document Search This content will become publicly...

  6. Mesoscale modeling of phase transition dynamics of thermoresponsive polymers

    E-Print Network [OSTI]

    Li, Zhen; Li, Xuejin; Karniadakis, George Em

    2015-01-01

    We present a non-isothermal mesoscopic model for investigation of the phase transition dynamics of thermoresponsive polymers. Since this model conserves energy in the simulations, it is able to correctly capture not only the transient behavior of polymer precipitation from solvent, but also the energy variation associated with the phase transition process. Simulations provide dynamic details of the thermally induced phase transition and confirm two different mechanisms dominating the phase transition dynamics. A shift of endothermic peak with concentration is observed and the underlying mechanism is explored.

  7. Renaturing Membrane Proteins in the Lipid Cubic Phase, a Nanoporous...

    Office of Scientific and Technical Information (OSTI)

    Renaturing Membrane Proteins in the Lipid Cubic Phase, a Nanoporous Membrane Mimetic Citation Details In-Document Search Title: Renaturing Membrane Proteins in the Lipid Cubic...

  8. Freezing and phase separation of self-propelled disks

    E-Print Network [OSTI]

    Yaouen Fily; Silke Henkes; M. Cristina Marchetti

    2013-09-15

    We study numerically a model of non-aligning self-propelled particles interacting through steric repulsion, which was recently shown to exhibit active phase separation in two dimensions in the absence of any attractive interaction or breaking of the orientational symmetry. We construct a phase diagram in terms of activity and packing fraction and identify three distinct regimes: a homogeneous liquid with anomalous cluster size distribution, a phase-separated state both at high and at low density, and a frozen phase. We provide a physical interpretation of the various regimes and develop scaling arguments for the boundaries separating them.

  9. Phase Structure and Instability Problem in Color Superconductivity

    E-Print Network [OSTI]

    Kenji Fukushima

    2005-10-22

    We address the phase structure of color superconducting quark matter at high quark density. Under the electric and color neutrality conditions there appear various phases as a result of the Fermi surface mismatch among different quark flavors induced by finite strange quark mass; the color-flavor locked (CFL) phase where quarks are all energy gapped, the u-quark superconducting (uSC) phase where u-quarks are paired with either d- or s-quarks, the d-quark superconducting (dSC) phase that is the d-quark analogue of the uSC phase, the two-flavor superconducting (2SC) phase where u- and d-quarks are paired, and the unpaired quark matter (UQM) that is normal quark matter without pairing. Besides these possibilities, when the Fermi surface mismatch is large enough to surpass the gap energy, the gapless superconducting phases are expected. We focus our discussion on the chromomagnetic instability problem related to the gapless CFL (gCFL) onset and explore the instability regions on the phase diagram as a function of the temperature and the quark chemical potential. We sketch how to reach stable physical states inside the instability regions.

  10. Major Effects in the Thermodynamics of Detonation Products: Phase...

    Office of Scientific and Technical Information (OSTI)

    Major Effects in the Thermodynamics of Detonation Products: Phase Segregation versus Ionic Dissociation Citation Details In-Document Search Title: Major Effects in the...

  11. Benchmarking of Multiparticle Phase Scan and Acceptance Scan...

    Office of Scientific and Technical Information (OSTI)

    of Multiparticle Phase Scan and Acceptance Scan techniques for the Spallation Neutron Source linac Citation Details In-Document Search Title: Benchmarking of Multiparticle...

  12. Publisher's Note: Phase effects from the general neutrino Yukawa...

    Office of Scientific and Technical Information (OSTI)

    Publisher's Note: Phase effects from the general neutrino Yukawa matrix on lepton flavor violation Phys. Rev. D 72, 055012 (2005) Citation Details In-Document Search Title:...

  13. Final Report: Enhanced Geothermal Systems Technology Phase II...

    Open Energy Info (EERE)

    Final Report: Enhanced Geothermal Systems Technology Phase II: Animas Valley, New Mexico Jump to: navigation, search OpenEI Reference LibraryAdd to library Report: Final Report:...

  14. Is Fresnel Optics Quantum Mechanics in Phase Space?

    E-Print Network [OSTI]

    O. Crasser; H. Mack; W. P. Schleich

    2004-02-17

    We formulate and argue in favor of the following conjecture: There exists an intimate connection between Wigner's quantum mechanical phase space distribution function and classical Fresnel optics.

  15. Mass-Conserved Phase Field Models for Binary Fluids

    E-Print Network [OSTI]

    2012-07-13

    phase field models [6, 7]. It arises naturally as a model for multiphase fluid mixtures. 37 should the entropic and mixing energy of the mixture system be known.

  16. Intercomparison of the Cloud Water Phase among Global Climate Models

    SciTech Connect (OSTI)

    Komurcu, Muge; Storelvmo, Trude; Tan, Ivy; Lohmann, U.; Yun, Yuxing; Penner, Joyce E.; Wang, Yong; Liu, Xiaohong; Takemura, T.

    2014-03-27

    Mixed-phase clouds (clouds that consist of both cloud droplets and ice crystals) are frequently present in the Earth’s atmosphere and influence the Earth’s energy budget through their radiative properties, which are highly dependent on the cloud water phase. In this study, the phase partitioning of cloud water is compared among six global climate models (GCMs) and with Cloud and Aerosol Lidar with Orthogonal Polarization retrievals. It is found that the GCMs predict vastly different distributions of cloud phase for a given temperature, and none of them are capable of reproducing the spatial distribution or magnitude of the observed phase partitioning. While some GCMs produced liquid water paths comparable to satellite observations, they all failed to preserve sufficient liquid water at mixed-phase cloud temperatures. Our results suggest that validating GCMs using only the vertically integrated water contents could lead to amplified differences in cloud radiative feedback. The sensitivity of the simulated cloud phase in GCMs to the choice of heterogeneous ice nucleation parameterization is also investigated. The response to a change in ice nucleation is quite different for each GCM, and the implementation of the same ice nucleation parameterization in all models does not reduce the spread in simulated phase among GCMs. The results suggest that processes subsequent to ice nucleation are at least as important in determining phase and should be the focus of future studies aimed at understanding and reducing differences among the models.

  17. Asymptotic and uncertainty analyses of a phase field model for...

    Office of Scientific and Technical Information (OSTI)

    Asymptotic and uncertainty analyses of a phase field model for void formation under irradiation Citation Details In-Document Search Title: Asymptotic and uncertainty analyses of a...

  18. Emittance and Phase Space Exchange for Advanced Beam Manipulation...

    Office of Scientific and Technical Information (OSTI)

    Title: Emittance and Phase Space Exchange for Advanced Beam Manipulation and Diagnostics Alternative chicane-type beam lines are proposed for exact emittance exchange between...

  19. MICROSTRUCTURE AND PROPERTIES OF DUAL PHASE STEELS CONTAINING FINE PRECIPITATES

    E-Print Network [OSTI]

    Gau, J.S.

    2014-01-01

    phase steels subjected to intercritical annealing followedphase steels sub- jected to intercritical annealing followedof steels fast quenched after intercritical annealing is a

  20. A Reversible Crystallinity-Preserving Phase Transition in Metal...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Reversible Crystallinity-Preserving Phase Transition in Metal-Organic Frameworks: Discovery, Mechanistic Studies, and Potential Applications Previous Next List Liu, Dahuan; Liu,...

  1. FY 2014 Phase I Release 2 EERE Awards

    Office of Energy Efficiency and Renewable Energy (EERE)

    FY 2014 Phase I Release 2 EERE Awards, from the U.S. Department of Energy, Small Business Innovation Research (SBIR) program.

  2. Reverse phase transformation of martensite to austenite in stainless...

    Office of Scientific and Technical Information (OSTI)

    of martensite to austenite in stainless steels: a 3D phase-field study Authors: Yeddu, Hemantha K. 1 ; Lookman, Turab 1 ; Saxena, Avadh B. 1 + Show Author...

  3. Enthalpy and mass flowrate measurements for two-phase geothermal...

    Open Energy Info (EERE)

    Enthalpy and mass flowrate measurements for two-phase geothermal production by Tracer dilution techniques Jump to: navigation, search OpenEI Reference LibraryAdd to library...

  4. Improved beam smoothing with SSD using generalized phase modulation

    SciTech Connect (OSTI)

    Rothenberg, J.E.

    1997-01-01

    The smoothing of the spatial illumination of an inertial confinement fusion target is examined by its spatial frequency content. It is found that the smoothing by spectral dispersion method, although efficient for glass lasers, can yield poor smoothing at low spatial frequency. The dependence of the smoothed spatial spectrum on the characteristics of phase modulation and dispersion is examined for both sinusoidal and more general phase modulation. It is shown that smoothing with non-sinusoidal phase modulation can result in spatial spectra which are substantially identical to that obtained with the induced spatial incoherence or similar method where random phase plates are present in both methods and identical beam divergence is assumed.

  5. Population estimates for Phase 1: Hanford Environmental Dose Reconstruction Project

    SciTech Connect (OSTI)

    Beck, D.M.; Erickson, A.R.; Harkreader, S.A.

    1992-03-01

    This report summarizes the population estimates of Phase I of the Hanford Environmental Dose Reconstruction (HEDR) Project. These estimates were used to develop preliminary dose estimates.

  6. Structural phase transitions on the nanoscale: The crucial pattern in the phase-change materials Ge2Sb2Te5 and GeTe

    E-Print Network [OSTI]

    Structural phase transitions on the nanoscale: The crucial pattern in the phase-change materials Ge and computer memory, but the structure of the amorphous phases and the nature of the phase transition of types A Ge and Sb and B Te , an "ABAB square." The rapid amorphous-to-crystalline phase change

  7. Characterization of transuranium actinide alloy phase diagrams

    SciTech Connect (OSTI)

    Gibson, J.K.; Haire, R.G.; Gensini, M.M. [Oak Ridge National Lab., TN (United States); Ogawa, T. [Japan Atomic Energy Research Inst., Tokai (Japan)

    1994-05-02

    Alloys of Np have been studied less than those,of the neighboring elements, U and Pu; the higher actinides have received even less attention. Recent interest in {sup 237}Np, {sup 241}Am and other actinide isotopes as significant, long-lived and highly radiotoxic nuclear waste components, and particularly the roles of metallic materials new handling/separations and remediation technologies, demands that this paucity of information concerning alloy behaviors be addressed. An additional interest in these arises from the possibility of revealing fundamental properties and bonding interactions, which would further characterize the unique electronic structures (e.g., 5f electrons) of the actinide elements. The small empirical knowledge basis presently available for understanding and modeling the alloying behavior of Np is summarized here, with emphasis on our recent results for the Np-Am, Np-Zr and Np-Fe phase diag rams. In view of the limited experimental data base for neptunium and the transplutonium metals, the value of semi-empirical intermetallic bonding models for predicting actinide alloy thermodynamics is evaluated.

  8. CERES progress report: Phases 1 and 2

    SciTech Connect (OSTI)

    Dannevik, W.P.; Ambrosiano, J.; Kercher, J.; Penner, J.E.; Emanuel, W.

    1994-05-27

    The CERES project represents a long-term commitment of LLNL`s Global Climate Research Division to the EPA. The goal is to build an Earth System Model (ESM) with the ability in the near future to assist EPA in carrying out its responsibilities in the environmental policy and assessment arena, with particular emphasis on the terrestrial ecosystem components of the Earth system. There are two complementary aspects of the CERES development plan. The first is to provide a computational framework and modeling infrastructure for ESM development. The goal is to create an ``open architecture`` enabling submodels from different research groups studying terrestrial ecosystems to become part of a fully-coupled model of the Earth`s climate system. The second goal is to contribute fundamentally to understanding of the terrestrial component of the Earth system by developing advanced models. During this first phase of the CERES project, these two activities have been somewhat separate; the software engineering and framework building activity having been done in parallel with terrestrial model development. These two activities are merging as the framework becomes more mature, with robust software tools, and with a growing complement of tuned and benchmarked submodels and as the ecosystem models become fully incorporated into the ESM modeling framework. Two appendices contain the following papers: (1) ``Research Recommendations to the EPA in Support of Earth System Modeling Activities,`` LLNL CERES project report; and (2) ``Progress Report on Terrestrial Model Development: Research in Support of the CERES Earth System Modeling Project,`` LLNL CERES project report.

  9. Scaling Analysis of Nanowire Phase Change Memory

    E-Print Network [OSTI]

    Liu, Jie; Anantram, M P

    2013-01-01

    This letter analyzes the scaling property of nanowire (NW) phase change memory (PCM) using analytic and numerical methods. The scaling scenarios of the three widely-used NW PCM peration schemes (constant electric field, voltage, and current) are studied and compared. It is shown that if the device size is downscaled by a factor of 1/k (k>1), the peration energy (current) will be reduced by more than k3 (k) times, and the operation speed will be increased by k2 times. It is also shown that more than 90% of operation energy is wasted as thermal flux into substrate and electrodes. We predict that, if the wasted thermal flux is effectively reduced by heat confinement technologies, the energy consumed per RESET operation can be decreased from about 1 pJ to less than 100 fJ. It is shown that reducing NW aspect ratio (AR) helps decreasing PCM energy consumption. It is revealed that cross-cell thermal proximity disturbance is counter-intuitively alleviated by scaling, leading to a desirable scaling scenario.

  10. Phase II Final Scientific/Technical Report

    SciTech Connect (OSTI)

    Grigg, Reid; McPherson, Brian; Lee, Rober

    2011-08-01

    The Southwest Regional Partnership on Carbon Sequestration (SWP) one of seven regional partnerships sponsored by the U.S. Department of Energy (USDOE) carried out five field pilot tests in its Phase II Carbon Sequestration Demonstration effort, to validate the most promising sequestration technologies and infrastructure concepts, including three geologic pilot tests and two terrestrial pilot programs. This field testing demonstrated the efficacy of proposed sequestration technologies to reduce or offset greenhouse gas emissions in the region. Risk mitigation, optimization of monitoring, verification, and accounting (MVA) protocols, and effective outreach and communication were additional critical goals of these field validation tests. The program included geologic pilot tests located in Utah, New Mexico, Texas, and a region-wide terrestrial analysis. Each geologic sequestration test site was intended to include injection of a minimum of ~75,000 tons/year CO{sub 2}, with minimum injection duration of one year. These pilots represent medium- scale validation tests in sinks that host capacity for possible larger-scale sequestration operations in the future. These validation tests also demonstrated a broad variety of carbon sink targets and multiple value-added benefits, including testing of enhanced oil recovery and sequestration, enhanced coalbed methane production and a geologic sequestration test combined with a local terrestrial sequestration pilot. A regional terrestrial sequestration demonstration was also carried out, with a focus on improved terrestrial MVA methods and reporting approaches specific for the Southwest region.

  11. Booster Applications Facility report, Phase 2

    SciTech Connect (OSTI)

    Thieberger, P. [ed.

    1991-06-01

    This report summarizes studies and planning performed by Brookhaven National Laboratory (BNL) personnel at the request of NASA for the design, construction and operation of experimental areas and facilities for utilization of ion beams from the BNL Booster synchrotron particle accelerator. These facilities would be primarily utilized to simulate space radiation for radiobiological research, shielding studies and detector calibrations. The feasibility of such a project has been established, preliminary designs and cost estimates have been developed and a formal proposal can be submitted pending DOE concurrence. The main body of this report consists of the material presented by BNL during the meeting with a NASA appointed Panel on December 10 and 11, 1990. The individual speakers have provided brief summaries of their talks and explanations of their figures. In addition there are two appendices. One, contains detailed discussion of the shared mode of operation and the corresponding beam compatibility tables. The second appendix contains cost estimate details. An executive summary on budgets and schedules has been added, containing possible phased construction and outfitting scenarios and the corresponding expense and commitment profiles as well as new operational cost estimates. Material contained in the executive summary reflects the correction of some errors and new studies performed in response to the NASA Panel suggestions.

  12. A comparison of observables for solid-solid phase transitions

    SciTech Connect (OSTI)

    Smilowitz, Laura B [Los Alamos National Laboratory; Henson, Bryan F [Los Alamos National Laboratory; Romero, Jerry J [Los Alamos National Laboratory

    2009-01-01

    The study of solid-solid phase transformations is hindered by the difficulty of finding a volumetric probe to use as a progress variable. Solids are typically optically opaque and heterogeneous. Over the past several years, second harmonic generation (SHG) has been used as a kinetic probe for a solid-solid phase transition in which the initial and final phases have different symmetries. Bulk generation of SHG is allowed by symmetry only in noncentrosymmetric crystallographic space groups. For the organic energetic nitramine octahydro-1,3 ,5,7 -tetranitro-1,3 ,5,7 -tatrazocine (HMX), the beta phase is centro symmetric (space group P2{sub 1}/c) and the delta phase iS noncentrosymmetric (space group P6{sub 1}22) making SHG an extremely sensitive, essentially zero background probe of the phase change progress. We have used SHG as a tool to follow the progress of the transformation from beta to delta phase during the solid-solid transformation. However, kinetic models of the transformation derived using different observables from several other groups have differed, showing later onset for the phase change and faster progression to completion. In this work, we have intercompared several techniques to understand these differences. The three techniques discussed are second harmonic generation, Raman spectroscopy, and differential scanning calorimetry (DSC). The progress of the beta to delta phase transition in HMX observed with each of these different probes will be discussed and advantages and disadvantages of each technique described. This paper compares several different observables for use in measuring the kinetics of solid-solid phase transitions. Relative advantages and disadvantages for each technique are described and a direct comparison of results is made for the beta to delta polymorphic phase transition of the energetic nitramine, octahydro-1,3,5,7-tetranitro-1,3,5,7-tatrazocine.

  13. Development of dense-phase pneumatic transport of coal

    SciTech Connect (OSTI)

    Horisaka, S.; Ikemiya, H.; Kajiwara, T. [Sumitomo Metal Industries, Ltd., Kashima, Ibaraki (Japan)

    1996-12-31

    Dense phase pneumatic transport system has been developed to reduce entrained particles as is seen in the belt conveyor system. High mass flow rate and dense phase (Loading ratio = 50--100kg-coal/kg-N{sub 2}) transport has been achieved by applying this plug flow system to pneumatic conveying of coal (Average particle diameter = 2.5 mm).

  14. High voltage fault current limiter having immersed phase coils

    DOE Patents [OSTI]

    Darmann, Francis Anthony

    2014-04-22

    A fault current limiter including: a ferromagnetic circuit formed from a ferromagnetic material and including at least a first limb, and a second limb; a saturation mechanism surrounding a limb for magnetically saturating the ferromagnetic material; a phase coil wound around a second limb; a dielectric fluid surrounding the phase coil; a gaseous atmosphere surrounding the saturation mechanism.

  15. SHORT COMMUNICATION Gas-Phase Separations of Protease Digests

    E-Print Network [OSTI]

    Clemmer, David E.

    SHORT COMMUNICATION Gas-Phase Separations of Protease Digests Stephen J. Valentine, Anne E University, Bloomington, Indiana, USA A mixture of peptides from a complete tryptic digest of ubiquitin has and identify peptides from a tryptic digest of ubiquitin. The mixture was electrosprayed into the gas phase

  16. Modelling and Analysis of Phase Variation in Bacterial Colony Growth

    E-Print Network [OSTI]

    Gilbert, David

    Modelling and Analysis of Phase Variation in Bacterial Colony Growth Ovidiu P^arvu1 , David Gilbert, Brandenburg University of Technology monika.heiner@informatik.tu-cottbus.de 3 Harbin Institute of Technology case study, namely phase variation patterning in bacterial colony growth, forming circular colonies

  17. Geometric phases for corotating elliptical vortex patches B. N. Shashikantha)

    E-Print Network [OSTI]

    Shashikanth, Banavara N.

    of an infinitely long rectilinear vortex tube of area A whose vorticity distribution is invariant along the lengthGeometric phases for corotating elliptical vortex patches B. N. Shashikantha) Control and Dynamical September 2000 We describe a geometric phase that arises when two elliptical vortex patches co- rotate

  18. Phase of atmospheric secondary organic material affects its reactivity

    E-Print Network [OSTI]

    of the reactivity of atmospheric SOM particles. atmospheric chemistry chemical aging organic aerosol collectionPhase of atmospheric secondary organic material affects its reactivity Mikinori Kuwata and Scot T of atmospheric organic particles among solid, semisolid, and liquid phases is of keen current scientific interest

  19. Optics of spin-1 particles from gravity-induced phases

    E-Print Network [OSTI]

    G. Papini; G. Scarpetta; A. Feoli; G. Lambiase

    2007-11-19

    The Maxwell and Maxwell-de Rham equations can be solved exactly to first order in an external gravitational field. The gravitational background induces phases in the wave functions of spin-1 particles. These phases yield the optics of the particles without requiring any thin lens approximation.

  20. Disordering transitions in vortex matter: peak effect and phase diagram

    E-Print Network [OSTI]

    Scalettar, Richard T.

    Disordering transitions in vortex matter: peak effect and phase diagram C.J. Olson a,*, C- order nature of this transition. In YBCO a rapid increase in Jc as a function of magnetic field vortex phase diagram as a function of magnetic field and temperature. For increasing field or temperature