National Library of Energy BETA

Sample records for naphthas lubricants waxes

  1. Gas chromatographic determination of residual solvents in lubricating oils and waxes

    SciTech Connect (OSTI)

    De Andrade Bruening, I.M.R.

    1983-10-01

    A direct gas-liquid chromatographic analysis of residual solvents is described, using tert-butylbenzene as an internal standard. The lube oils and waxes were prevented from contaminating the chromatographic column by injecting the samples directly into a precolumn containing a silicone stationary phase. The samples of lube oils and waxes were injected directly into the chromatographic column containing another stationary phase, 1,2,3-tris(2-cyanoethoxy)propane. (The waxy samples were dissolved in a light neutral oil). With proper operating conditions, analysis time was 7 min. The procedure has been applied in the control of a lube oil dewaxing plant; the chromatographic column showed no sign of deterioration after 1 h when the precolumn was removed. Known amounts of toluene and methylethyl ketone were added to the solvent-free lubricating oils and wax, and these mixtures were analyzed to evaluate the accuracy of the procedure. Precision and accuracy of these data are comparable to those of methods previously described. 1 figure, 1 table.

  2. Coal liquefaction process with increased naphtha yields

    DOE Patents [OSTI]

    Ryan, Daniel F.

    1986-01-01

    An improved process for liquefying solid carbonaceous materials wherein the solid carbonaceous material is slurried with a suitable solvent and then subjected to liquefaction at elevated temperature and pressure to produce a normally gaseous product, a normally liquid product and a normally solid product. The normally liquid product is further separated into a naphtha boiling range product, a solvent boiling range product and a vacuum gas-oil boiling range product. At least a portion of the solvent boiling-range product and the vacuum gas-oil boiling range product are then combined and passed to a hydrotreater where the mixture is hydrotreated at relatively severe hydrotreating conditions and the liquid product from the hydrotreater then passed to a catalytic cracker. In the catalytic cracker, the hydrotreater effluent is converted partially to a naphtha boiling range product and to a solvent boiling range product. The naphtha boiling range product is added to the naphtha boiling range product from coal liquefaction to thereby significantly increase the production of naphtha boiling range materials. At least a portion of the solvent boiling range product, on the other hand, is separately hydrogenated and used as solvent for the liquefaction. Use of this material as at least a portion of the solvent significantly reduces the amount of saturated materials in said solvent.

  3. Process for removing polymer-forming impurities from naphtha fraction

    DOE Patents [OSTI]

    Kowalczyk, Dennis C.; Bricklemyer, Bruce A.; Svoboda, Joseph J.

    1983-01-01

    Polymer precursor materials are vaporized without polymerization or are removed from a raw naphtha fraction by passing the raw naphtha to a vaporization zone (24) and vaporizing the naphtha in the presence of a wash oil while stripping with hot hydrogen to prevent polymer deposits in the equipment.

  4. Process for removing polymer-forming impurities from naphtha fraction

    DOE Patents [OSTI]

    Kowalczyk, D.C.; Bricklemyer, B.A.; Svoboda, J.J.

    1983-12-27

    Polymer precursor materials are vaporized without polymerization or are removed from a raw naphtha fraction by passing the raw naphtha to a vaporization zone and vaporizing the naphtha in the presence of a wash oil while stripping with hot hydrogen to prevent polymer deposits in the equipment. 2 figs.

  5. Analysis shows revamp route to naphtha feed

    SciTech Connect (OSTI)

    Aguilar, E.; Ortiz, C.H.; Arzate, E. )

    1988-11-21

    An existing ethylene plant was studied, using a computer-simulated flexibility analysis, to determine the changes required to convert one of the cracking furnaces from ethane feed to naphtha feed. The simulation determined the changes in flow rate, operating temperature, and steam/hydrocarbon ratio that would result from the liquid feed.

  6. Ionic Liquids as Novel Engine Lubricants or Lubricant Additives...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Engine Lubricants or Lubricant Additives Ionic Liquids as Novel Engine Lubricants or Lubricant Additives Bench test results showed that compared with fully-formulated engine oils, ...

  7. Tethered Lubricants

    SciTech Connect (OSTI)

    Archer, Lynden

    2010-09-15

    We have performed extensive experimental and theoretical studies of interfacial friction, relaxation dynamics, and thermodynamics of polymer chains tethered to points, planes, and particles. A key result from our tribology studies using lateral force microscopy (LFM) measurements of polydisperse brushes of linear and branched chains densely grafted to planar substrates is that there are exceedingly low friction coefficients for these systems. Specific project achievements include: (1) Synthesis of three-tiered lubricant films containing controlled amounts of free and pendent PDMS chains, and investigated the effect of their molecular weight and volume fraction on interfacial friction. (2.) Detailed studies of a family of hairy particles termed nanoscale organic hybrid materials (NOHMs) and demonstration of their use as lubricants.

  8. Lubricants for CFC alternates

    SciTech Connect (OSTI)

    Spauschus, H.O.

    1995-12-01

    With the recent development and introduction of environmentally preferred refrigerants as substitutes for HCFC`s, a number of new classes of companion compressor lubricants also have been offered. In contrast to the former compressor lubricants which were derived from petroleum based stocks, the new lubricants are synthetic products, initially designed to provide miscibilities and solubilities similar to the CFC/mineral oil predecessors. Rather than review the classes of lubricants being evaluated and used for different types of refrigeration machinery, this paper will address longer term benefits and challenges related to the introduction of synthetic compressor lubricants such as polyesters, polyolesters, polyalkalene glycols and polycarbonates. Within these families of synthetic fluids, large selections of chemical structures are available, each with unique physical and chemical properties. Of course all of the lubricants must meet general requirements of compressor oils with respect to flammability, pour point, volatility, toxicity, etc., but beyond these minimum requirements, there are technical options for tailoring lubricant structures to optimize certain lubricant (and thus lubricant/refrigerant) properties such as vapor pressure, solubility, viscosity, viscosity index, miscibility, moisture absorption, additive response and biodegradability. Basic studies to predict lubricant/refrigerant mixture properties based on chemical structure of the components are recommended. A number of practical challenges in the selection and application of new lubricants and new working fluids will be discussed including standards for bench screening tests and compressor tests, guidelines for lubricant handling during recovery and servicing of equipment and the potential for reprocessing compressor lubricants.

  9. High temperature lubricating process

    DOE Patents [OSTI]

    Taylor, R.W.; Shell, T.E.

    1979-10-04

    It has been difficult to provide adequate lubrication for load bearing, engine components when such engines are operating in excess of about 475/sup 0/C. The present invention is a process for providing a solid lubricant on a load bearing, solid surface, such as in an engine being operated at temperatures in excess of about 475/sup 0/C. The process comprises contacting and maintaining the following steps: a gas phase is provided which includes at least one component reactable in a temperature dependent reaction to form a solid lubricant; the gas phase is contacted with the load bearing surface; the load bearing surface is maintained at a temperature which causes reaction of the gas phase component and the formation of the solid lubricant; and the solid lubricant is formed directly on the load bearing surface. The method is particularly suitable for use with ceramic engines.

  10. High temperature lubricating process

    DOE Patents [OSTI]

    Taylor, Robert W.; Shell, Thomas E.

    1982-01-01

    It has been difficult to provide adaquate lubrication for load bearing, engine components when such engines are operating in excess of about 475.degree. C. The present invention is a process for providing a solid lubricant on a load bearing, solid surface (14), such as in an engine (10) being operated at temperatures in excess of about 475.degree. C. The process comprises contacting and maintaining steps. A gas phase (42) is provided which includes at least one component reactable in a temperature dependent reaction to form a solid lubricant. The gas phase is contacted with the load bearing surface. The load bearing surface is maintained at a temperature which causes reaction of the gas phase component and the formation of the solid lubricant. The solid lubricant is formed directly on the load bearing surface. The method is particularly suitable for use with ceramic engines.

  11. Rate enhancement for catalytic upgrading coal naphthas. Final of final technical progress report, July 1991--September 1994

    SciTech Connect (OSTI)

    Davis, B.H.

    1995-08-01

    The objective of this project is to remove sulfur, nitrogen, and oxygen from naphtha derived from coal liquefaction. The project is concerned with the development of hydrotreating catalysts. This period, a ruthenium sulfide catalyst has been studied.

  12. Friction, Wear, and Lubrication Technologies | Argonne National...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Erck Ali Erdemir Osman Eryilmaz Aaron Greco Projects Lubricants Advanced lubrication approaches that integrate fuel-efficient lubricants, low-friction materials and coatings...

  13. Methods to improve lubricity of fuels and lubricants

    DOE Patents [OSTI]

    Erdemir, Ali

    2009-06-16

    A method for providing lubricity in fuels and lubricants includes adding a boron compound to a fuel or lubricant to provide a boron-containing fuel or lubricant. The fuel or lubricant may contain a boron compound at a concentration between about 30 ppm and about 3,000 ppm and a sulfur concentration of less than about 500 ppm. A method of powering an engine to minimize wear, by burning a fuel containing boron compounds. The boron compounds include compound that provide boric acid and/or BO.sub.3 ions or monomers to the fuel or lubricant.

  14. Power system with an integrated lubrication circuit

    DOE Patents [OSTI]

    Hoff, Brian D.; Akasam, Sivaprasad; Algrain, Marcelo C.; Johnson, Kris W.; Lane, William H.

    2009-11-10

    A power system includes an engine having a first lubrication circuit and at least one auxiliary power unit having a second lubrication circuit. The first lubrication circuit is in fluid communication with the second lubrication circuit.

  15. Synthesis of new high performance lubricants and solid lubricants

    SciTech Connect (OSTI)

    Lagow, R.J.

    1993-04-01

    Synthesis and testing was begun on a number of new classes of lubricants: perfluoropolyethers (branching effects), perfluoromethylene oxide ethers, chlorine-substituted fluorocarbon polyethers, fluorine-containing branched ether lubricants, glycerine- based perfluoropolyesters, perfluoro epoxy ether chains, etc.

  16. Fluid lubricated bearing assembly

    DOE Patents [OSTI]

    Boorse, Henry A.; Boeker, Gilbert F.; Menke, John R.

    1976-01-01

    1. A support for a loaded rotatable shaft comprising in combination on a housing having a fluid-tight cavity encasing an end portion of said shaft, a thrust bearing near the open end of said cavity for supporting the axial thrust of said shaft, said thrust bearing comprising a thrust plate mounted in said housing and a thrust collar mounted on said shaft, said thrust plate having a central opening the peripheral portion of which is hermetically sealed to said housing at the open end of said cavity, and means for supplying a fluid lubricant to said thrust bearing, said thrust bearing having a lubricant-conducting path connecting said lubricant supplying means with the space between said thrust plate and collar intermediate the peripheries thereof, the surfaces of said plate and collar being constructed and arranged to inhibit radial flow of lubricant and, on rotation of said thrust collar, to draw lubricant through said path between the bearing surfaces and to increase the pressure therebetween and in said cavity and thereby exert a supporting force on said end portion of said shaft.

  17. Organophosphorus compounds as coke inhibitors during naphtha pyrolysis. Effect of benzyl diethyl phosphite and triphenylphosphine sulfide

    SciTech Connect (OSTI)

    Das, P.; Prasad, S.; Kunztu, D.

    1992-09-01

    This paper reports that significant reduction in the rate of coke formation during naphtha pyrolysis was achieved by adding benzyl diethyl phosphite or triphenylphosphine sulfide to the feed. Although the yield of carbon oxides was reduced, there was no effect of these additives on the hydrocarbon yields. Addition of these organophosphorus compounds significantly reduced the concentration of metals, such as iron, nickel, and chromium, incorporated in the coke. A previously proposed model for coke inhibition due to the formation of a passivating metal-phosphorus complex could satisfactorily correlate the data.

  18. Fluid lubricated bearing construction

    DOE Patents [OSTI]

    Dunning, John R.; Boorse, Henry A.; Boeker, Gilbert F.

    1976-01-01

    1. A fluid lubricated thrust bearing assembly comprising, in combination, a first bearing member having a plain bearing surface, a second bearing member having a bearing surface confronting the bearing surface of said first bearing member and provided with at least one spiral groove extending inwardly from the periphery of said second bearing member, one of said bearing members having an axial fluid-tight well, a source of fluid lubricant adjacent to the periphery of said second bearing member, and means for relatively rotating said bearing members to cause said lubricant to be drawn through said groove and to flow between said bearing surfaces, whereby a sufficient pressure is built up between said bearing surfaces and in said well to tend to separate said bearing surfaces.

  19. Lubrication with boric acid additives

    DOE Patents [OSTI]

    Erdemir, Ali

    2000-01-01

    Self-lubricating resin compositions including a boric acid additive and a synthetic polymer including those thermoset materials.

  20. Metal working lubricant compositions

    SciTech Connect (OSTI)

    Andress, H.J.; Davis, R.H.; Schick, J.W.

    1981-08-11

    A lubricant concentrate for use in metal processing comprises a sulfur compound such as a sulfurized olefin or sulfurized mineral oil and an ester prepared from a fatty acid having 12 to 40 carbon atoms or the dimer thereof or a polyalkenylsuccinic acid or anhydride and a hydroxyl-containing amine.

  1. Lubricant selection criteria and the tribological system

    SciTech Connect (OSTI)

    Lauer, D.A.

    1995-07-01

    Before the proper lubricant selection can be made, the tribological system must be identified to its fullest extent. This system includes the type of motion, speeds, temperatures, loads and the environment that is specific to the application. Once these parameters are identified, lubrication engineers or tribo-engineers can use their knowledge of the different lubricant chemistries to make a lubricant selection that will optimize the performance of the application. In addition to lubricant chemistry knowledge, the lubrication engineer also must analyze the application based on the identified tribological system. This analysis includes such topics as speed factors, elastohydrodynamic lubrication, extreme pressure lubrication, emergency lubrication and various special application requirements.

  2. "RSE Table N1.3. Relative Standard Errors for Table N1.3;...

    U.S. Energy Information Administration (EIA) Indexed Site

    (a)",0 " Special Naphthas (a)",0 " Waxes (a)",0 " Miscellaneous Nonfuel Products ... (a)",0 " Special Naphthas (a)",0 " Waxes (a)",0 " Miscellaneous Nonfuel Products ...

  3. Table N1.3. First Use of Energy for All Purposes (Fuel and...

    U.S. Energy Information Administration (EIA) Indexed Site

    " Special Naphthas (a)",163,0 " Waxes (a)",53,0 " Miscellaneous Nonfuel Products ... " Special Naphthas (a)",163,0 " Waxes (a)",53,0 " Miscellaneous Nonfuel Products ...

  4. Lubricant oil production: The proper marriage of process and catalyst technologies

    SciTech Connect (OSTI)

    Everett, G.L.; Suchanek, A.

    1996-12-01

    As the industry moves into the next millennium, higher product quality demands to meet the higher performance needs of modern engine technology and rising costs of traditional good quality lube crudes are driving lubricant base oil manufacturers to select hydroprocessing options versus traditional solvent refining techniques. This paper discusses how to properly select the best economic hydroprocessing technology necessary to produce high quality lubricant base oils and waxes. The economic success of such operations depends on the proper combination of process and catalyst technologies that maximizes yields of high quality products with minimum consumption of hydrogen resources and process utilities. This is particular true on the extreme end of the quality spectrum, namely, Very High Viscosity Index (VHVI) base oils and food grade white oils and waxes where there is no room for marginal product quality. Multiplicity of operations is also becoming more important as refiners try to upgrade their facilities with as little capital expense as possible, while at the same time, broaden their high valued product slate to recoup these expenses in the shortest possible payback period. Lyondell Licensing and Criterion Catalyst have put together an effective alliance based on years of development and commercial experience in both the process and catalyst areas to assist lubricant oil manufacturers in meeting these future challenges using as much existing equipment and infrastructure as is practical. Their experience will permit the proper fitting of the chemistry of hydroprocessing to make lubricant base oils to existing or new operations.

  5. Lubricant characterization by molecular simulation

    SciTech Connect (OSTI)

    Moore, J.D.; Cui, S.T.; Cummings, P.T.; Cochran, H.D.

    1997-12-01

    The authors have reported the calculation of the kinematic viscosity index of squalane from nonequilibrium molecular dynamics simulations. This represents the first accurate quantitative prediction of this measure of lubricant performance by molecular simulation. Using the same general alkane potential model, this computational approach offers the possibility of predicting the performance of potential lubricants prior to synthesis. Consequently, molecular simulation is poised to become an important tool for future lubricant development.

  6. Refinery Yield of Liquefied Refinery Gases

    U.S. Energy Information Administration (EIA) Indexed Site

    Refinery Yield (Percent) Product: Liquefied Refinery Gases Finished Motor Gasoline Finished Aviation Gasoline Kerosene-Type Jet Fuel Kerosene Distillate Fuel Oil Residual Fuel Oil Naphtha for Petrochemical Feedstock Use Other Oils for Petrochemical Feedstock Use Special Naphthas Lubricants Waxes Petroleum Coke Asphalt and Road Oil Still Gas Miscellaneous Products Processing Gain(-) or Loss(+) Period: Monthly Annual Download Series History Download Series History Definitions, Sources & Notes

  7. Ionic Liquids as Novel Engine Lubricants or Lubricant Additives |

    Broader source: Energy.gov (indexed) [DOE]

    Department of Energy Bench test results showed that compared with fully-formulated engine oils, selected low-viscosity ionic liquids, used as neat lubricants or basestock, produced significantly lower friction and engine wear PDF icon deer11_qu.pdf More Documents & Publications Ionic Liquids as Multifunctional Ashless Additives for Engine Lubrication

  8. Process for preparing lubricating oil from used waste lubricating oil

    DOE Patents [OSTI]

    Whisman, Marvin L.; Reynolds, James W.; Goetzinger, John W.; Cotton, Faye O.

    1978-01-01

    A re-refining process is described by which high-quality finished lubricating oils are prepared from used waste lubricating and crankcase oils. The used oils are stripped of water and low-boiling contaminants by vacuum distillation and then dissolved in a solvent of 1-butanol, 2-propanol and methylethyl ketone, which precipitates a sludge containing most of the solid and liquid contaminants, unspent additives, and oxidation products present in the used oil. After separating the purified oil-solvent mixture from the sludge and recovering the solvent for recycling, the purified oil is preferably fractional vacuum-distilled, forming lubricating oil distillate fractions which are then decolorized and deodorized to prepare blending stocks. The blending stocks are blended to obtain a lubricating oil base of appropriate viscosity before being mixed with an appropriate additive package to form the finished lubricating oil product.

  9. Separate lubricating system for marine propulsion device

    SciTech Connect (OSTI)

    Matsumoto, K.

    1986-02-25

    This patent describes a lubricating system for a two-cycle internal combustion engine. This system consists of a relatively large remotely positioned lubricant storage tank a relatively small lubricant delivery tank positioned in proximity to the engine for delivering lubricant to its lubricating system and means responsive to the level of lubricant in the delivery tank for transferring lubricant to maintain a predetermined level of lubricant in the delivery tank. The improvement consists of means for providing a warning signal when the level of lubricant in the storage tank falls below a predetermined amount. The means for providing the warning signal operate further to discontinue the transfer of lubricant from the storage tank to the delivery tank. There also is a manual override for operating the means for transferring lubricant from the storage tank to the delivery tank under operator control even when the warning signal has been activated.

  10. Coatings and films derived from clay/wax nanocomposites

    DOE Patents [OSTI]

    Chaiko, David J.; Leyva, Argentina A.

    2006-11-14

    The invention provides methods for making clay/wax nanocomposites and coatings and films of same with improved chemical resistance and gas barrier properties. The invention further provides methods for making and using emulsions of such clay/wax nanocomposites. Typically, an organophillic clay is combined with a wax or wax/polymer blend such that the cohesion energy of the clay matches that of the wax or wax/polymer blend. Suitable organophilic clays include mica and phyllosilicates that have been surface-treated with edge or edge and surface modifying agents. The resulting nanocomposites have applications as industrial coatings and in protective packaging.

  11. Method for lubricating contacting surfaces

    DOE Patents [OSTI]

    Dugger, Michael T.; Ohlhausen, James A.; Asay, David B.; Kim, Seong H.

    2011-12-06

    A method is provided for tribological lubrication of sliding contact surfaces, where two surfaces are in contact and in motion relative to each other, operating in a vapor-phase environment containing at least one alcohol compound at a concentration sufficiently high to provide one monolayer of coverage on at least one of the surfaces, where the alcohol compound continuously reacts at the surface to provide lubrication.

  12. U.S. Exports of Crude Oil and Petroleum Products

    U.S. Energy Information Administration (EIA) Indexed Site

    Use 1983-1992 Special Naphthas 36 37 49 1983-2012 Lubricants 62 68 75 73 67 73 1983-2015 Waxes 5 6 5 5 5 4 1983-2015 Petroleum Coke 449 499 503 524 541 537 1983-2015 Asphalt and ...

  13. U.S. Product Supplied for Crude Oil and Petroleum Products

    U.S. Energy Information Administration (EIA) Indexed Site

    Special Naphthas 14 12 8 52 55 55 1983-2015 Lubricants 131 125 114 121 126 135 1983-2015 Waxes 8 7 8 8 7 6 1983-2015 Petroleum Coke 376 361 360 354 347 351 1983-2015 Marketable 151 ...

  14. U.S. Exports of Crude Oil and Petroleum Products

    U.S. Energy Information Administration (EIA) Indexed Site

    ... Special Naphthas 13,037 13,586 17,847 1981-2012 Lubricants 22,576 24,927 27,326 26,697 24,495 26,474 1981-2015 Waxes 1,841 2,011 1,982 2,003 1,967 1,449 1981-2015 Petroleum Coke ...

  15. Wax Point Determinations Using Acoustic Resonance Spectroscopy

    SciTech Connect (OSTI)

    Bostick, D.T.; Jubin, R.T.; Schmidt, T.W.

    2001-06-01

    The thermodynamic characterization of the wax point of a given crude is essential in order to maintain flow conditions that prevent plugging of undersea pipelines. This report summarizes the efforts made towards applying an Acoustic Cavity Resonance Spectrometer (ACRS) to the determination of pressures and temperatures at which wax precipitates from crude. Phillips Petroleum Company, Inc., the CRADA participant, supplied the ACRS. The instrumentation was shipped to Dr. Thomas Schmidt of ORNL, the CRADA contractor, in May 2000 after preliminary software development performed under the guidance of Dr. Samuel Colgate and Dr. Evan House of the University of Florida, Gainesville, Fl. Upon receipt it became apparent that a number of modifications still needed to be made before the ACRS could be precisely and safely used for wax point measurements. This report reviews the sequence of alterations made to the ACRS, as well as defines the possible applications of the instrumentation once the modifications have been completed. The purpose of this Cooperative Research and Development Agreement (CRADA) between Phillips Petroleum Company, Inc. (Participant) and Lockheed Martin Energy Research Corporation (Contractor) was the measurement of the formation of solids in crude oils and petroleum products that are commonly transported through pipelines. This information is essential in the proper design, operation and maintenance of the petroleum pipeline system in the United States. Recently, new petroleum discoveries in the Gulf of Mexico have shown that there is a potential for plugging of undersea pipeline because of the precipitation of wax. It is important that the wax points of the expected crude oils be well characterized so that the production facilities for these new wells are capable of properly transporting the expected production. The goal of this work is to perform measurements of solids formation in crude oils and petroleum products supplied by the Participant. It is anticipated that these data will be used in the design of new production facilities and in the development of thermodynamic models that describe the behavior of wax-saturated petroleum.

  16. A NOVEL VAPOR-PHASE PROCESS FOR DEEP DESULFURIZATION OF NAPHTHA/DIESEL

    SciTech Connect (OSTI)

    B.S. Turk; R.P. Gupta; S.K. Gangwal

    2003-06-30

    Tier 2 regulations issued by the U.S. Environmental Protection Agency (EPA) require a substantial reduction in the sulfur content of gasoline. Similar regulations have been enacted for the sulfur level in on-road diesel and recently off-road diesel. The removal of this sulfur with existing and installed technology faces technical and economic challenges. These challenges created the opportunity for new emerging technologies. Research Triangle Institute (RTI) with subcontract support from Kellogg Brown & Root, Inc., (KBR) used this opportunity to develop RTI's transport reactor naphtha desulfurization (TReND) process. Starting with a simple conceptual process design and some laboratory results that showed promise, RTI initiated an accelerated research program for sorbent development, process development, and marketing and commercialization. Sorbent development has resulted in the identification of an active and attrition resistant sorbent that has been prepared in commercial equipment in 100 lb batches. Process development has demonstrated both the sulfur removal performance and regeneration potential of this sorbent. Process development has scaled up testing from small laboratory to pilot plant transport reactor testing. Testing in the transport reactor pilot plant has demonstrated the attrition resistance, selective sulfur removal activity, and regeneration activity of this sorbent material. Marketing and commercialization activities have shown with the existing information that the process has significant capital and operating cost benefits over existing and other emerging technologies. The market assessment and analysis provided valuable feedback about the testing and performance requirements for the technical development program. This market analysis also provided a list of potential candidates for hosting a demonstration unit. Although the narrow window of opportunity generated by the new sulfur regulations and the conservative nature of the refining industry slowed progress of the demonstration unit, negotiations with potential partners are proceeding for commercialization of this process.

  17. Engine lubrication circuit including two pumps

    DOE Patents [OSTI]

    Lane, William H.

    2006-10-03

    A lubrication pump coupled to the engine is sized such that the it can supply the engine with a predetermined flow volume as soon as the engine reaches a peak torque engine speed. In engines that operate predominately at speeds above the peak torque engine speed, the lubrication pump is often producing lubrication fluid in excess of the predetermined flow volume that is bypassed back to a lubrication fluid source. This arguably results in wasted power. In order to more efficiently lubricate an engine, a lubrication circuit includes a lubrication pump and a variable delivery pump. The lubrication pump is operably coupled to the engine, and the variable delivery pump is in communication with a pump output controller that is operable to vary a lubrication fluid output from the variable delivery pump as a function of at least one of engine speed and lubrication flow volume or system pressure. Thus, the lubrication pump can be sized to produce the predetermined flow volume at a speed range at which the engine predominately operates while the variable delivery pump can supplement lubrication fluid delivery from the lubrication pump at engine speeds below the predominant engine speed range.

  18. 2014 Annual Merit Review Results Report - Fuels & Lubricants...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuels & Lubricants Technologies 2014 Annual Merit Review Results Report - Fuels & Lubricants Technologies Merit review of DOE Vehicle Technologies research activities...

  19. Ionic Liquids as Novel Lubricants and /or Lubricant Additives

    SciTech Connect (OSTI)

    Qu, J.; Viola, M. B.

    2013-10-31

    This ORNL-GM CRADA developed ionic liquids (ILs) as novel lubricants or oil additives for engine lubrication. A new group of oil-miscible ILs have been designed and synthesized with high thermal stability, non-corrosiveness, excellent wettability, and most importantly effective anti-scuffing/anti-wear and friction reduction characteristics. Mechanistic analysis attributes the superior lubricating performance of IL additives to their physical and chemical interactions with metallic surfaces. Working with a leading lubricant formulation company, the team has successfully developed a prototype low-viscosity engine oil using a phosphonium-phosphate IL as an anti-wear additive. Tribological bench tests of the IL-additized formulated oil showed 20-33% lower friction in mixed and elastohydrodynamic lubrication and 38-92% lower wear in boundary lubrication when compared with commercial Mobil 1 and Mobil Clean 5W-30 engine oils. High-temperature, high load (HTHL) full-size engine tests confirmed the excellent anti-wear performance for the IL-additized engine oil. Sequence VID engine dynamometer tests demonstrated an improved fuel economy by >2% for this IL-additized engine oil benchmarked against the Mobil 1 5W-30 oil. In addition, accelerated catalyst aging tests suggest that the IL additive may potentially have less adverse impact on three-way catalysts compared to the conventional ZDDP. Follow-on research is needed for further development and optimization of IL chemistry and oil formulation to fully meet ILSAC GF-5 specifications and further enhance the automotive engine efficiency and durability.

  20. Top-of-Rail lubricant

    SciTech Connect (OSTI)

    Alzoubi, M. F.; Fenske, G. R.; Erck, R. A.; Boparai, A. S.

    2000-07-14

    Analysis of the volatile and semivolatile fractions collected after use of the TOR lubricant indicated that other than contaminants in the collection laboratory, no compounds on the EPA's Target Compound Lists (Tables 2 and 5) were detected in these fractions. The data of these qualitative analyses, given in the various tables in the text, indicate only the relative amounts of the tentatively identified compounds. The authors recommend that quantitative analysis be performed on the volatile and semivolatile fractions to allow confirmation of the tentatively identified compounds and to obtain absolute amounts of the detected compounds. Additionally, the semivolatile fraction should be analyzed by liquid chromatography/mass spectrometry to identify compounds that are not chromatographable under the temperature program used for determination of semivolatile compounds. Introducing the top-of-rail (TOR) lubricant into the wheel/rail interface results in a reduction of almost 60% of lateral friction force over the forces encountered under dry conditions. This reveals good potential for energy savings, as well as wear reduction, for railroad companies. In TOR lubrication, an increase in the angle of attack and axle load results in increased lateral friction and rate of lubricant consumption. The most efficient TOR lubricant quantity to be used in the wheel/rail interface must be calculated precisely according to the number of cars, axle loads, train speed, and angle of attack.

  1. Influence of rheological properties of a lubricant on power consumption and heat transfer in a hydrostatic lubricating layer

    SciTech Connect (OSTI)

    Yablonskii, V.O.; Tyabin, N.V.; Yashchuk, V.M.

    1995-06-01

    The influence of rheological properties of lubricants on power consumption for pumping the lubricant in a hydrostatic lubricating layer and heat transfer of the lubricant with the supporting surfaces of a bearing is studied.

  2. Method For Testing Properties Of Corrosive Lubricants

    DOE Patents [OSTI]

    Ohi, James; De La Cruz, Jose L.; Lacey, Paul I.

    2006-01-03

    A method of testing corrosive lubricating media using a wear testing apparatus without a mechanical seal. The wear testing apparatus and methods are effective for testing volatile corrosive lubricating media under pressure and at high temperatures.

  3. Tethered Lubricants for Small Systems

    SciTech Connect (OSTI)

    Lynden A. Archer

    2006-01-09

    The objective of this research project is two-fold. First, to fundamentally understand friction and relaxation dynamics of polymer chains near surfaces; and second, to develop novel self-lubricated substrates suitable for MEMS devices. During the three-year performance period of this study the PI and his students have shown using theory and experiments that systematic introduction of disorder into tethered lubricant coatings (e.g. by using self-assembled monolayer (SAM) mixtures or SAMs with nonlinear, branched architectures) can be used to significantly reduce the friction coefficient of a surface. They have also developed a simple procedure based on dielectric spectroscopy for quantifying the effect of surface disorder on molecular relaxation in lubricant coatings. Details of research accomplishments in each area of the project are described in the body of the report.

  4. Wax and hydrate control with electrical power

    SciTech Connect (OSTI)

    1997-08-01

    Electrical heating of subsea flowlines is an effective way to prevent wax and hydrate information, especially for long transportation distances and in low-temperature deep water. Systems are available for use in conjunction with bundles, pipe-in-pipe, and wet-thermal-insulation systems. These systems provide environmentally friendly fluid-temperature control without chemicals or flaring for pipeline depressurizing. Enhanced production is achieved because no time is lost by unnecessary depressurizing, pigging, heating-medium circulation, or removal of hydrate and wax blockages. The seabed temperature at 100-m and greater water depths may range from 7 to {minus}1.5 C, causing a rapid cooling of the hot well streams being transported in subsea flowlines. Under these supercooling conditions, vulnerable crude oils and multiphase compositions will deposit wax and asphalts; also the gas/water phase may freeze solid with hydrate particles. The paper discusses thermal-insulated flowlines, heat-loss compensation with electrical power, electrical power consumption and operation, and subsea electrical-power distribution system.

  5. USDOE Top-of-Rail Lubricant Project

    SciTech Connect (OSTI)

    Mohumad F. Alzoubi; George R. Fenske; Robert A. Erck; Amrit S. Boparai

    2002-02-01

    Lubrication of wheel/rail systems has been recognized for the last two decades as a very important issue for railroads. Energy savings and less friction and wear can be realized if a lubricant can be used at the wheel/rail interface. On the other hand, adverse influences are seen in operating and wear conditions if improper or excessive lubrication is used. Also, inefficiencies in lubrication need to be avoided for economic and environmental reasons. The top-of-rail (TOR) lubricant concept was developed by Texaco Corporation to lubricate wheels and rails effectively and efficiently. Tranergy Corporation has been developing its SENTRAEN 2000{trademark} lubrication system for the last ten years, and this revolutionary new high-tech on-board rail lubrication system promises to dramatically improve the energy efficiency, performance, safety, and track environment of railroads. The system is fully computer-controlled and ensures that all of the lubricant is consumed as the end of the train passes. Lubricant quantity dispensed is a function of grade, speed, curve, and axle load. Tranergy also has its LA4000{trademark} wheel and rail simulator, a lubrication and traction testing apparatus. The primary task of this project was collecting and analyzing the volatile and semivolatile compounds produced as the lubricant was used. The volatile organic compounds were collected by Carbotrap cartridges and analyzed by adsorption and gas chromatography/mass spectrometry (GC/MS). The semivolatile fraction was obtained by collecting liquid that dripped from the test wheel. The collected material was also analyzed by GC/MS. Both of these analyses were qualitative. The results indicated that in the volatile fraction, the only compounds on the Environmental Protection Agency's (EPA) Superfund List of Analytes detected were contaminants either in the room air or from other potential contamination sources in the laboratory. Similarly, in the semivolatile fraction none of the detected compounds are on the EPA's Superfund List of Analytes. The major compound in the semivolatile fraction is 1,2-propanediol, which was also found as the major component of the TOR lubricant before testing. Other compounds found in trace quantities either were present in the TOR lubricant or were small fragments from the polymeric component of the TOR lubricant. The second task for Argonne in this project was to investigate the effects of axle load, angle of attack, and quantity of lubricant on lateral friction forces, as well as the consumption time of the TOR lubricant. The second task was to collect and qualitatively identify any volatile and semivolatile compounds produced upon use of the TOR lubricant.

  6. Evaluation of Wax Deposition and Its Control During Production...

    Office of Scientific and Technical Information (OSTI)

    Title: Evaluation of Wax Deposition and Its Control During Production of Alaska North Slope Oils Due to increasing oil demand, oil companies are moving into arctic environments and ...

  7. Microbial production of wax esters from highly branched alkanes

    DOE Patents [OSTI]

    Bogan, William W.; Sullivan, Wendy R.; Paterek, James R.

    2005-02-01

    A microbial culture and method for producing wax esters using highly branched alkanes. In accordance with one embodiment, the highly branched alkane is squalane.

  8. Synthesis of new high performance lubricants and solid lubricants. Progress report, April 1992--March 1993

    SciTech Connect (OSTI)

    Lagow, R.J.

    1993-04-01

    Synthesis and testing was begun on a number of new classes of lubricants: perfluoropolyethers (branching effects), perfluoromethylene oxide ethers, chlorine-substituted fluorocarbon polyethers, fluorine-containing branched ether lubricants, glycerine- based perfluoropolyesters, perfluoro epoxy ether chains, etc.

  9. Water-based lubricants for metalworking

    SciTech Connect (OSTI)

    Shukla, D.S.; Jain, V.K.

    1997-05-01

    Metalworking fluids currently constitute 17% of the total US industrial lubricant market. Market forces favor semisynthetic and synthetic formulations because they are more economical, and trends differ substantially from those of other lubricant markets as demand patterns shift. Lubricant manufacturers continue to reduce the use of mineral oil as a component in their formulations because synthetic and semisynthetic formulations are more cost-effective. The introduction of new engineering materials also has increased the demand for tailor-made lubricants in industrial applications. Synthetic and semisynthetic formulations are favored for cutting and metalworking applications because they perform better than the existing commercial product does. The literature strongly supports the development of environmentally friendly synthetic and semisynthetic metalworking lubricants that have longer useful lives, therefore decreasing the amount of fluid for disposal. Future lubricant formulations will focus on environmental issues, process compatibility, and worker health and safety. Biological control of fluids, in use and in disposal, will also draw attention.

  10. Vehicle Technologies Office: Lubricants | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuel Efficiency & Emissions » Vehicle Technologies Office: Lubricants Vehicle Technologies Office: Lubricants As most vehicles are on the road for more than 15 years before they are retired, investigating technologies that will improve today's vehicles is essential. Because 11.5 percent of fuel energy is consumed by engine friction, decreasing this friction through lubricants can lead to substantial improvements in the fuel economy of current vehicles, without needing to wait for the fleet

  11. Lubrication Systems Market : Mining & Mineral Processing Industry...

    Open Energy Info (EERE)

    Groeneveld Groep B.V., SKF AB, Bijur Delimon, Castrol-Lubecon, Changzhou Huali Hydraulic Lubrication Equipment Co., Ltd., Changhua Chen Ying Oil Machine Co., Ltd., Equipment...

  12. Biodiesel Impact on Engine Lubricant Oil Dilution

    Broader source: Energy.gov [DOE]

    Heavy-duty engine and light-duty vehicle experiments were conducted to investigate the potential for lubricant dilution by fuel during DPF regeneration events.

  13. Lubrication from mixture of boric acid with oils and greases

    DOE Patents [OSTI]

    Erdemir, A.

    1995-07-11

    Lubricating compositions are disclosed including crystalline boric acid and a base lubricant selected from oils, greases and the like. The lubricity of conventional oils and greases can also be improved by adding concentrates of boric acid.

  14. Lubrication from mixture of boric acid with oils and greases

    DOE Patents [OSTI]

    Erdemir, Ali

    1995-01-01

    Lubricating compositions including crystalline boric acid and a base lubricant selected from oils, greases and the like. The lubricity of conventional oils and greases can also be improved by adding concentrates of boric acid.

  15. Process for upgrading wax from Fischer-Tropsch synthesis

    DOE Patents [OSTI]

    Derr, Jr., W. Rodman; Garwood, William E.; Kuo, James C.; Leib, Tiberiu M.; Nace, Donald M.; Tabak, Samuel A.

    1987-01-01

    The waxy liquid phase of an oil suspension of Fischer-Tropsch catalyst containing dissolved wax is separated out and the wax is converted by hydrocracking, dewaxing or by catalytic cracking with a low activity catalyst to provide a highly olefinic product which may be further converted to premium quality gasoline and/or distillate fuel.

  16. Process for upgrading wax from Fischer-Tropsch synthesis

    DOE Patents [OSTI]

    Derr, W.R. Jr.; Garwood, W.E.; Kuo, J.C.; Leib, T.M.; Nace, D.M.; Tabak, S.A.

    1987-08-04

    The waxy liquid phase of an oil suspension of Fischer-Tropsch catalyst containing dissolved wax is separated out and the wax is converted by hydrocracking, dewaxing or by catalytic cracking with a low activity catalyst to provide a highly olefinic product which may be further converted to premium quality gasoline and/or distillate fuel. 2 figs.

  17. Collaborative Lubricating Oil Study on Emissions (CLOSE Project...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Collaborative Lubricating Oil Study on Emissions (CLOSE Project) Collaborative Lubricating Oil Study on Emissions (CLOSE) Project Lung Toxicity and ...

  18. Experimental and Theoretical Investigation of Lubricant and Additive...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Theoretical Investigation of Lubricant and Additive Effects on Engine Friction Experimental and Theoretical Investigation of Lubricant and Additive Effects on Engine Friction ...

  19. Lubricant Formulation and Consumption Effects on Diesel Exhaust...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Lubricant Formulation and Consumption Effects on Diesel Exhaust Ash Emissions: Lubricant Formulation and Consumption Effects on Diesel Exhaust Ash Emissions: 2005 Diesel Engine ...

  20. Friction Modeling for Lubricated Engine and Drivetrain Components...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Modeling for Lubricated Engine and Drivetrain Components Friction Modeling for Lubricated Engine and Drivetrain Components 2010 DOE Vehicle Technologies and Hydrogen Programs...

  1. Multi-component Nanoparticle Based Lubricant Additive to Improve...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Nanoparticle Based Lubricant Additive to Improve Efficiency and Durability in Engines Multi-component Nanoparticle Based Lubricant Additive to Improve Efficiency and ...

  2. Friction of Steel Sliding Under Boundary Lubrication Regime in...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Steel Sliding Under Boundary Lubrication Regime in Commercial Gear Oils at Elevated Temperatures Friction of Steel Sliding Under Boundary Lubrication Regime in Commercial Gear ...

  3. Lubricants - Pathway to Improving Fuel Efficiency of Legacy Fleet...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Lubricants - Pathway to Improving Fuel Efficiency of Legacy Fleet Vehicles Reviews recent studies on potential for low-viscosity lubricants and low-friction surfaces and additives ...

  4. Detailed Characterization of Lubricant-Derived Ash-Related Species...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Correlations Between Metallic Lubricant Additive Species in the Ring Pack and Ash Emissions and Their Dependence on Crankcase Oil Properties Lubricant Formulation and Consumption ...

  5. Lubricant-infused nanoparticulate coatings assembled by layer...

    Office of Scientific and Technical Information (OSTI)

    Lubricant-infused nanoparticulate coatings assembled by layer-by-layer deposition Title: Lubricant-infused nanoparticulate coatings assembled by layer-by-layer deposition ...

  6. Effects of Fuel Dilution with Biodiesel on Lubricant Acidity...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Effects of Fuel Dilution with Biodiesel on Lubricant Acidity, Oxidation and Corrosion Effects of Fuel Dilution with Biodiesel on Lubricant Acidity, Oxidation and Corrosion ...

  7. Vehicle Technologies Office: 2013 Fuel and Lubricant Technologies...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuel and Lubricant Technologies R&D Annual Progress Report Vehicle Technologies Office: 2013 Fuel and Lubricant Technologies R&D Annual Progress Report This report describes the ...

  8. Collaborative Lubricating Oil Study on Emissions (CLOSE Project...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CLOSE Project) Collaborative Lubricating Oil Study on Emissions (CLOSE Project) 2011 DOE ... More Documents & Publications Collaborative Lubricating Oil Study on Emissions (CLOSE ...

  9. 2013 Annual Merit Review Results Report - Fuels & Lubricants...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuels & Lubricants 2013 Annual Merit Review Results Report - Fuels & Lubricants Merit review of DOE Vehicle Technologies research activities 2013amr05.pdf More Documents &...

  10. Vehicle Technologies Office: 2012 Fuel and Lubricant Technologies...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    R&D Annual Progress Report The Fuel & Lubricant Technologies subprogram supports fuels and lubricants research and development (R&D) to provide vehicle users with...

  11. Large-Scale Manufacturing of Nanoparticle-Based Lubrication Additives...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Large-Scale Manufacturing of Nanoparticle-Based Lubrication Additives Large-Scale Manufacturing of Nanoparticle-Based Lubrication Additives PDF icon nanoparticulate-basedlubricati...

  12. Smart Surface and Lubrication Engineering show Promise for Gearbox...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Smart Surface and Lubrication Engineering show Promise for Gearbox Reliability Smart Surface and Lubrication Engineering show Promise for Gearbox Reliability May 20, 2011 - 1:10pm ...

  13. Offshore Lubricants Market Size | OpenEI Community

    Open Energy Info (EERE)

    Offshore Lubricants Market Size Home There are currently no posts in this category. Syndicate content...

  14. Offshore Lubricants Market Forecast | OpenEI Community

    Open Energy Info (EERE)

    Offshore Lubricants Market Forecast Home There are currently no posts in this category. Syndicate...

  15. Global Offshore Lubricants Market | OpenEI Community

    Open Energy Info (EERE)

    Global Offshore Lubricants Market Home There are currently no posts in this category. Syndicate content...

  16. Offshore Lubricants Market Analysis | OpenEI Community

    Open Energy Info (EERE)

    Offshore Lubricants Market Analysis Home There are currently no posts in this category. Syndicate...

  17. Double angle seal forming lubricant film

    DOE Patents [OSTI]

    Ernst, William D.

    1984-01-01

    A lubricated piston rod seal which inhibits gas leaking from a high pressure chamber on one side of the seal to a low pressure chamber on the other side of the seal. A liquid is supplied to the surface of the piston rod on the low pressure side of the seal. This liquid acts as lubricant for the seal and provides cooling for the rod. The seal, which can be a plastic, elastomer or other material with low elastic modulus, is designed to positively pump lubricant through the piston rod/seal interface in both directions when the piston rod is reciprocating. The capacity of the seal to pump lubricant from the low pressure side to the high pressure side is less than its capacity to pump lubricant from the high pressure side to the low pressure side which ensures that there is zero net flow of lubricant to the high pressure side of the seal. The film of lubricant between the seal and the rod minimizes any sliding contact and prevents the leakage of gas. Under static conditions gas leakage is prevented by direct contact between the seal and the rod.

  18. Thin film deposition behavior of lubricants as a function of temperature - Lubricant stability maps

    SciTech Connect (OSTI)

    Klaus, E.E.; Wang, J.C.; Duda, J.L. )

    1992-07-01

    The relative rates of evaporation and oxidative or thermal decomposition in lubricants are investigated experimentally at elevated temperatures. Thin films of lubricant are exposed to air at high temperatures, and attention is given to the amount of solid deposit rendered and the amount of evaporated material. The effects of volatility, oxidative stability, and thermal stability are assessed with the help of stability maps for liquid lubricants. The concept of fluid-stability maps based on deposit formation as a function of temperature is shown to be effective. At 200-425 C lubricant deposit formation in the presence of air is a function of lubricant volatility, oxidation rate, the rate of thermal degradation, and the effect of the bearing surface. Some materials are listed that can mitigate the effects of oxidation on lubricant performance which can be used for a range of aerospace applications. 16 refs.

  19. Canfield waxes poetic about superconductors | The Ames Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Canfield waxes poetic about superconductors An error occurred. Try watching this video on www.youtube.com, or enable JavaScript if it is disabled in your browser. When the editors...

  20. Elastohydrodynamic Lubrication with Polyolester Lubricants and HFC Refrigerants, Final Report, Volume 2

    SciTech Connect (OSTI)

    Gunsel, Selda; Pozebanchuk, Michael

    1999-04-01

    Lubrication properties of refrigeration lubricants were investigated in high pressure nonconforming contacts under different conditions of temperature, rolling speed, and refrigerant concentration. The program was based upon the recognition that the lubrication regime in refrigeration compressors is generally elastohydrodynamic or hydrodynamic, as determined by the operating conditions of the compressor and the properties of the lubricant. Depending on the compressor design, elastohydrodynamic lubrication conditions exist in many rolling and sliding elements of refrigeration compressors such as roller element bearings, gears, and rotors. The formation of an elastohydrodynamic film separating rubbing surfaces is important in preventing the wear and failure of compressor elements. It is, therefore, important to predict the elastohydrodynamic (EHD) performance of lubricants under realistic tribocontact renditions. This is, however, difficult as the lubricant properties that control film formation are critically dependent upon pressure and shear, and cannot be evaluated using conventional laboratory instruments. In this study, the elastohydrodynamic behavior of refrigeration lubricants with and without the presence of refrigerants was investigated using the ultrathin film EHD interferometry technique. This technique enables very thin films, down to less than 5 nm, to be measured accurately within an EHD contact under realistic conditions of temperature, shear, and pressure. The technique was adapted to the study of lubricant refrigerant mixtures. Film thickness measurements were obtained on refrigeration lubricants as a function of speed, temperature, and refrigerant concentration. The effects of lubricant viscosity, temperature, rolling speed, and refrigerant concentration on EHD film formation were investigated. From the film thickness measurements, effective pressure-viscosity coefficients were calculated. The lubricants studied in this project included two naphthenic mineral oils (NMO), four polyolesters (POE), and two polyvinyl ether (PVE) fluids. These fluids represented viscosity grades of ISO 32 and ISO 68 and are shown in a table. Refrigerants studied included R-22, R-134a, and R-410A. Film thickness measurements were conducted at 23 C, 45 C, and 65 C with refrigerant concentrations ranging from zero to 60% by weight.

  1. Low Reactivity SI Engine Lubricant Program | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Results showed that lubricant improvement allowed up to 4 degree improvement in spark advance at knock limited conditions resulting in potentially over 3 percent indicated efficiency improvement PDF icon deer11_alger.pdf More Documents & Publications Vehicle Technologies Office: 2014 Fuel and Lubricant Technologies R&D Annual Progress Report Fuel & Lubricant Technologies Ionic Liquids as Novel Engine Lubricants or Lubricant Additives

  2. Fuel & Lubricant Technologies | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    ft000_stork_2012_o.pdf More Documents & Publications Fuel & Lubricant Technologies Overview of the DOE Advanced Combustion Engine R&D Overview of DOE Advanced Combustion Engine R&D

  3. Advanced lubrication systems and materials. Final report

    SciTech Connect (OSTI)

    Hsu, S.

    1998-05-07

    This report described the work conducted at the National Institute of Standards and Technology under an interagency agreement signed in September 1992 between DOE and NIST for 5 years. The interagency agreement envisions continual funding from DOE to support the development of fuel efficient, low emission engine technologies in terms of lubrication, friction, and wear control encountered in the development of advanced transportation technologies. However, in 1994, the DOE office of transportation technologies was reorganized and the tribology program was dissolved. The work at NIST therefore continued at a low level without further funding from DOE. The work continued to support transportation technologies in the development of fuel efficient, low emission engine development. Under this program, significant progress has been made in advancing the state of the art of lubrication technology for advanced engine research and development. Some of the highlights are: (1) developed an advanced high temperature liquid lubricant capable of sustaining high temperatures in a prototype heat engine; (2) developed a novel liquid lubricant which potentially could lower the emission of heavy duty diesel engines; (3) developed lubricant chemistries for ceramics used in the heat engines; (4) developed application maps for ceramic lubricant chemistry combinations for design purpose; and (5) developed novel test methods to screen lubricant chemistries for automotive air-conditioning compressors lubricated by R-134a (Freon substitute). Most of these findings have been reported to the DOE program office through Argonne National Laboratory who manages the overall program. A list of those reports and a copy of the report submitted to the Argonne National Laboratory is attached in Appendix A. Additional reports have also been submitted separately to DOE program managers. These are attached in Appendix B.

  4. Fuel & Lubricant Technologies | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    6 addresses Malware, the Worst Passwords of 2013, and the Flat Stanley and Stop.Think.Connect. Campaign. PDF icon Cybersecurity Front Burner Newsletter Issue 16 More Documents & Publications April 2014 Cybersecurity Awareness Campaign - Malware FRONT BURNER - Issue 20

    vtpn06_fl_stork_2012_o.pdf More Documents & Publications Fuel & Lubricant Technologies Fuel & Lubricant Technologies R&D Overview of Fuels Technologies

  5. Lubricant analysis for gas turbine condition monitoring

    SciTech Connect (OSTI)

    Lukas, M.; Anderson, D.P.

    1997-10-01

    Analysis of used lubricating oil is a fast-evolving technique for predictive maintenance with any closed-loop lubricating system such as those in gas and steam turbines, diesel and gasoline engines, transmissions, gearboxes, compressors, pumps, bearings, and hydraulic systems. Based on analysis of periodic oil samples, a laboratory diagnostic report is sent to the personnel responsible for the equipment to warn of any possible problem or to make a specific maintenance recommendation. The entire process, from sample taking to the diagnostic report, should take less than 48 hours to be effective. These reports, when combined with statistical analysis and trending, can provide an insight to management personnel on the effectiveness of the program, efficiency of the maintenance department, repair status of equipment, recurring problems, and even information on the performance of different lubricants. Condition monitoring by oil analysis can be broken down into two categories: debris monitoring to measure the trace quantities of wear particles carried by the lubricant away from the wearing surfaces and lubricant condition monitoring to determine whether the lubricant itself is fit for service based on physical and chemical tests.

  6. Solubility modeling of refrigerant/lubricant mixtures

    SciTech Connect (OSTI)

    Michels, H.H.; Sienel, T.H.

    1996-12-31

    A general model for predicting the solubility properties of refrigerant/lubricant mixtures has been developed based on applicable theory for the excess Gibbs energy of non-ideal solutions. In our approach, flexible thermodynamic forms are chosen to describe the properties of both the gas and liquid phases of refrigerant/lubricant mixtures. After an extensive study of models for describing non-ideal liquid effects, the Wohl-suffix equations, which have been extensively utilized in the analysis of hydrocarbon mixtures, have been developed into a general form applicable to mixtures where one component is a POE lubricant. In the present study we have analyzed several POEs where structural and thermophysical property data were available. Data were also collected from several sources on the solubility of refrigerant/lubricant binary pairs. We have developed a computer code (NISC), based on the Wohl model, that predicts dew point or bubble point conditions over a wide range of composition and temperature. Our present analysis covers mixtures containing up to three refrigerant molecules and one lubricant. The present code can be used to analyze the properties of R-410a and R-407c in mixtures with a POE lubricant. Comparisons with other models, such as the Wilson or modified Wilson equations, indicate that the Wohl-suffix equations yield more reliable predictions for HFC/POE mixtures.

  7. Foaming characteristics of refigerant/lubricant mixtures

    SciTech Connect (OSTI)

    Goswami, D.Y.; Shah, D.O.; Jotshi, C.K.; Bhagwat, S.; Leung, M.; Gregory, A.

    1997-04-01

    The air-conditioning and refrigeration industry has moved to HFC refrigerants which have zero ozone depletion and low global warming potential due to regulations on CFC and HCFC refrigerants and concerns for the environment. The change in refrigerants has prompted the switch from mineral oil and alkylbenzene lubricants to polyolester-based lubricants. This change has also brought about a desire for lubricant, refrigerant and compressor manufacturers to understand the foaming properties of alternative refrigerant/ lubricant mixtures, as well as the mechanisms which affect these properties. The objectives of this investigation are to experimentally determine the foaming absorption and desorption rates of HFC and blended refrigerants in polyolester lubricant and to define the characteristics of the foam formed when the refrigerant leaves the refrigerant/ lubricant mixture after being exposed to a pressure drop. The refrigerants being examined include baseline refrigerants: CFC-12 (R-12) and HCFC-22 (R-22); alternative refrigerants: HFC-32 (R-32), R-125, R-134a, and R-143a; and blended refrigerants: R-404A, R-407C, and R-410A. The baseline refrigerants are tested with ISO 32 (Witco 3GS) and ISO 68 (4GS) mineral oils while the alternative and blended refrigerants are tested with two ISO 68 polyolesters (Witco SL68 and ICI RL68H).

  8. Compatibility of lubricant additives with HFC refrigerants and synthetic lubricants. Final report, Part 1

    SciTech Connect (OSTI)

    Cavestri, R.C.

    1997-07-01

    Part one of this research provides manufacturers of components of air-conditioning and refrigeration equipment with a useful list of lubricant additives, sources, functional properties and chemical species. The list in part one is comprised of domestic lubricant additive suppliers and the results of a literature search that was specifically targeted for additives reported to be useful in polyolester chemistry.

  9. Biocides for lubricant rancidity and biofouling prevention

    SciTech Connect (OSTI)

    Passman, F.J.

    1997-10-01

    Lubricant systems provide a good environment for microbial communities. Growing most abundantly on surfaces, microbes can change lubricant performance properties by selectively depleting functional additives. Moreover, microbial metabolites can stimulate corrosion and induce invert emulsion formation. The keys to microbial contamination control are good industrial hygiene, monitoring and timely treatment. There are more than 30 USEPA registered metalworking fluid biocides. Each has an application where it provides cost-effective protection. Biocides should be selected based on performance in a particular coolant and system. Most often, biocides with limited solubility in non-polar solvents work better in lubricants. Bench tests provide a relatively inexpensive method for evaluating alternative treatments. Bench test data need to be confirmed through field evaluations. Bioresistant additives that have no obvious functionality other than replacing registered biocides should be considered with care. Properly used as one component of a complete lubricant system management program, data-driven biocide use can extend lubricant life dramatically, reduce downtime and create a healthier work environment.

  10. Vehicle Technologies Office: 2014 Fuel and Lubricant Technologies...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Merit Review 2014: Ionic Liquids as Anti-Wear Additives for Next-Generation Low-Viscosity Fuel-Efficient Engine Lubricants Vehicle Technologies Office: 2012 Fuel and Lubricant ...

  11. Turbine engine lubricant foaming due to silicone basestock used in non-specification spline lubricant

    SciTech Connect (OSTI)

    Centers, P.W.

    1995-05-01

    Dependent upon molecular weight and distribution, concentration, temperature, air flow, and test details or field application, polydimethylsiloxane (PDMS) may be neutral, profoamant or antifoamant in polyolesters. This understanding was critical in the solution of a turbine engine lubrication system foaming problem occurring at several military locations. Suspect turbine engine-accessory gearbox assembly materials gathered from several sites were evaluated. One non-specification PDMS-based spline lubricant caused copious foaming of the lubricant at less than ten parts-per-million concentration, while a specification polymethyl-phenylsiloxane (PMPS)-based lubricant required a concentration nearly 2000 times greater to generate equivalent foam. Use of the profoamant PDMS spline lubricant was then prohibited. Since prohibition, foaming of turbine engine lubricants used in the particular application has not been reported. PMPS impact on foaming of ester lubricants is similar to a much more viscous PDMS attributed to the reduced interaction of PMPS in esters due to pendant phenyl structure of PMPS absent in PDMS. These data provide significant additional insight and methodology to investigate foaming tendencies of partially miscible silicone-ester and other fluid systems. 7 refs., 2 figs., 1 tab.

  12. EERE Success Story - Novel Engine Lubrication Anti-Wear Additives

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Demonstrate Improved Fuel Economy | Department of Energy Story - Novel Engine Lubrication Anti-Wear Additives Demonstrate Improved Fuel Economy EERE Success Story - Novel Engine Lubrication Anti-Wear Additives Demonstrate Improved Fuel Economy March 14, 2016 - 1:27pm Addthis EERE Success Story - Novel Engine Lubrication Anti-Wear Additives Demonstrate Improved Fuel Economy EERE Success Story - Novel Engine Lubrication Anti-Wear Additives Demonstrate Improved Fuel Economy EERE Success Story -

  13. Method for reclaiming waste lubricating oils

    DOE Patents [OSTI]

    Whisman, Marvin L.; Goetzinger, John W.; Cotton, Faye O.

    1978-01-01

    A method for purifying and reclaiming used lubricating oils containing additives such as detergents, antioxidants, corrosion inhibitors, extreme pressure agents and the like and other solid and liquid contaminants by preferably first vacuum distilling the used oil to remove water and low-boiling contaminants, and treating the dried oil with a solvent mixture of butanol, isopropanol and methylethyl ketone which causes the separation of a layer of sludge containing contaminants, unspent additives and oxidation products. After solvent recovery, the desludged oil is then subjected to conventional lubricating oil refining steps such as distillation followed by decolorization and deodorization.

  14. FY2013 Progress Report for Fuel & Lubricant Technologies

    SciTech Connect (OSTI)

    none,

    2014-02-01

    Annual progress report for Fuel & Lubricant Technologies. The Fuel & Lubricant Technologies Program supports fuels and lubricants research and development (R&D) to provide vehicle manufacturers and users with cost-competitive options that enable high fuel economy with low emissions, and contribute to petroleum displacement.

  15. Engine Lubricants: Trends and Challenges | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    This overview discusses how lubricant developers, lubricant marketers, and OEMs are working with the engine community to overcome performance challenges worldwide. PDF icon deer12_bansal.pdf More Documents & Publications Lubricants - Pathway to Improving Fuel Efficiency of Legacy Fleet Vehicles Vehicle Technologies Office Merit Review 2015: Engine Friction Reduction Technologies Vehicle Technologies Office Merit Review 2014: Engine Friction Reduction Technologies

  16. Lubricants or lubricant additives composed of ionic liquids containing ammonium cations

    DOE Patents [OSTI]

    Qu, Jun (Knoxville, TN) [Knoxville, TN; Truhan, Jr.,; John J. (Cookeville, TN) [Cookeville, TN; Dai, Sheng (Knoxville, TN) [Knoxville, TN; Luo, Huimin (Knoxville, TN) [Knoxville, TN; Blau, Peter J. (Knoxville, TN) [Knoxville, TN

    2010-07-13

    A lubricant or lubricant additive is an ionic liquid alkylammonium salt. The alkylammonium salt has the structure R.sub.xNH.sub.(4-x).sup.+,[F.sub.3C(CF.sub.2).sub.yS(O).sub.2].sub.2N.sup- .- where x is 1 to 3, R is independently C.sub.1 to C.sub.12 straight chain alkyl, branched chain alkyl, cycloalkyl, alkyl substituted cycloalkyl, cycloalkyl substituted alkyl, or, optionally, when x is greater than 1, two R groups comprise a cyclic structure including the nitrogen atom and 4 to 12 carbon atoms, and y is independently 0 to 11. The lubricant is effective for the lubrication of many surfaces including aluminum and ceramics surfaces.

  17. Exploring Low Emission Lubricants for Diesel Engines

    SciTech Connect (OSTI)

    Perez, J. M.

    2000-07-06

    A workshop to explore the technological issues involved with the removal of sulfur from lubricants and the development of low emission diesel engine oils was held in Scottsdale, Arizona, January 30 through February 1, 2000. It presented an overview of the current technology by means of panel discussions and technical presentations from industry, government, and academia.

  18. Full Life Wind Turbine Gearbox Lubricating Fluids

    SciTech Connect (OSTI)

    Lutz, Glenn A.; Jungk, Manfred; Bryant, Jonathan J.; Lauer, Rebecca S.; Chobot, Anthony; Mayer, Tyler; Palmer, Shane; Kauffman, Robert E.

    2012-02-28

    Industrial gear box lubricants typically are hydrocarbon based mineral oils with considerable amounts of additives to overcome the lack of base fluid properties like wear protection, oxidation stability, load carrying capacity, low temperature solidification and drop of viscosity at higher temperatures. For today's wind turbine gearboxes, the requirements are more severe and synthetic hydrocarbon oils are used to improve on this, but all such hydrocarbon based lubricants require significant amounts of Extreme Pressure (EP) additives to meet performance requirements. Perfluoropolyether (PFPE) fluids provide load carrying capacity as an inherent property. During the course of the project with the main tasks of 'Establish a Benchmark', 'Lubricant Evaluation', 'Full Scale Gearbox Trial' and 'Economic Evaluation', the PAO Reference oil exhibited significant changes after laboratory gear testing, in service operation in the field and full scale gearbox trial. Four hydrocarbon base oils were selected for comparison in the benchmarking exercise and showed variation with respect to meeting the requirements for the laboratory micro-pitting tests, while the PFPE fluid exceeded the requirements even with the material taken after the full scale gear box trial. This is remarkable for a lubricant without EP additives. Laboratory bearing tests performed on the PFPE fluids before and after the full scale gear box trial showed the results met requirements for the industry standard. The PFPE fluid successfully completed the full scale gear box test program which included baseline and progressive staged load testing. The evaluation of gears showed no micro-pitting or objectionable wear. By the final stage, lubricant film thickness had been reduced to just 21% of its original value, this was by design and resulted in a lambda ratio of well below 1. This test design scenario of a low lambda ratio is a very undesirable lubrication condition for real world but creates the ability to test the lubricating fluids performance under the most extreme conditions. The PAO Reference oil also passed its testing without any noticeable deterioration of the gear surface. However the PAO Reference oil was replaced midway through the progressive loading, as the lubricant was burned in an attempt to raise the sump temperature to the same levels as for the PFPE. Both materials experienced a decrease of viscosity during their respective run times. The viscosity index decreased for the PAO there while there was a slight increase for the PFPE. FZG laboratory gear tests and measurements of the drive motor's current during the full scale gear box trial were made to characterize the relative efficiency between the PFPE fluid and the PAO Reference oil. In the FZG laboratory efficiency test, the PFPE fluids show much higher churning losses due to their higher viscosity and density. The analysis seems to show that the efficiency correlates better to dynamic viscosity than any other of the measured metrics such as film thickness. In load stages where the load, speed and temperature are similar, the PFPE fluid has a greater film thickness and theoretical gear protection, but requires a larger current for the drive motor than the PAO. However in load stages where the film thickness is the same, the PFPE fluid's reduced dynamic viscosity gives it a slight efficiency advantage relative to the PAO reference oil. Ultimately, many factors such as temperature, rotational speed, and fluid viscosity combine in a complex fashion to influence the results. However, the PFPE's much lower change of viscosity with respect to temperature, allows variations in designing an optimum viscosity to balance efficiency versus gear protection. Economic analysis was done using Cost of Energy calculations. The results vary from 5.3% for a 'Likely Case' to 16.8% for a 'Best Case' scenario as potential cost improvement by using PFPE as the gearbox lubricating fluid. It is important to note the largest portion of savings comes in Levelized Replacement Cost, which is dictated by the assumption on gearb

  19. Use of Lubricants in the NIF

    SciTech Connect (OSTI)

    Gourdin, W; Biltoft, P

    2006-07-06

    There are two principal concerns that govern the use of lubricants in NIF: (1) Airborne molecular contaminants (AMCs)--AMCs are known to seriously degrade the performance of sol-gel coated optics. AMCs are produced by the slow outgassing of residues (non-volatile residues or ''NVRs'') of high molecular weight compounds left on surfaces. Lubricants, particularly hydrocarbon lubricants, are a primary source of such NVRs. (2) Particulates--Particulates that accumulate on optical surfaces can cause permanent physical damage when exposed to high energy density laser light. Lubricant residues exposed to high energy density light will pyrolyze or decompose and produce carbon particulates. The NIF Approved Materials Database lists several lubricants that have been tested for use in NIF environments. Many of these lubricants were tested according to MELs 99-006 (oven outgassing test) or 99-007 (vacuum outgassing test). In these tests, the change in percent transmission of light through a sol-gel coated optic placed next to the sample under evaluation is used as the diagnostic. Samples that cause less than 0.1% change in optical transmission are deemed suitable for use inside beam enclosures. This testing, however, addresses only the concern associated with AMCs. To assess the issue of particle generation, a flashlamp or ''aerosol'' test is used. In this test a sample with residues is subjected to intense light from the main amplifier flashlamps. The number density of particles per unit volume is measure after each flash. A measurement of an average of fewer than 1000 particles >0.5{micro}m in diameter produced per square foot of exposed surface per flash for each of the last ten flashes in a series of 60 flashes of light is deemed to be acceptable for polymers. A measurement of an average of fewer than 100 particles >0.5{micro}m in diameter produced per square foot of exposed surface per flash for each of the last ten flashes in a series of 60 flashes of light is deemed to be acceptable for metals.

  20. Ionic Liquids with Ammonium Cations as Lubricants or Additives

    SciTech Connect (OSTI)

    Qu, Jun; Blau, Peter Julian; Dai, Sheng; Luo, Huimin; Truhan, Jr., John J

    2006-01-01

    Friction and wear are estimated to cost 6% of the US gross national product, or around $700 billion annually. A new class of more effective lubricants could lead to huge energy savings. Limited recent literature has suggested potential for using room-temperature ionic liquids as lubricants, however only a few out of millions (or more) of species have been evaluated. Recent ORNL work discovered a new category of ionic liquids with ammonium cations that have demonstrated promising lubricating properties as net lubricants or lubricant additives, particularly in lubricating difficult-to-lubricate metals like aluminum. More than 30% friction reduction has been observed on ammonium-based ionic liquids compared to conventional hydrocarbon oils. The inherent polarity of ionic liquids is believed to provide strong adhesion to contact surfaces and form a boundary lubricating film leading to friction and wear reductions. Other advantages of ionic liquids include (1) negligible volatility, (2) high thermal stability, (3) non-flammability, and (4) better intrinsic properties that eliminate the necessity of many expensive lubricant additives. With very flexible molecular structures, this new class of lubricants, particularly ammonium-based ionic liquids, can be tailored to fit a big variety of applications including but not limited to bearings, combustion engines, MEMS, and metal forming.

  1. Yieldably mounted lubricant control assemblies for piston rods

    SciTech Connect (OSTI)

    Meijer, R.J.; Ziph, B. Godett, T.M.

    1986-04-01

    This patent describes an engine having a housing comprising a cylinder within which a piston reciprocates and a piston rod extending from the piston through a bore which extends in the housing from the cylinder to a crankcase and a lubricant control assembly which is disposed within the bore in cooperative arrangement with the piston rod and functions to separate the cylinder from the crankcase while allowing the piston rod to reciprocate axially through a lubricant control portion of the lubricant control assembly which is in forceful contact around the piston rod, the improvement which comprises a compliant housing for mounting the lubricant control assembly on the engine housing. The compliant housing is operatively disposed between the engine housing and the lubricant control portion to allow the lubricant control portion to be radially displaced with respect to the bore and thereby comply with radial displacement of the reciprocating piston rod while maintaining substantially full effectiveness of the lubricant control portion acting on the piston rod. The lubricant control assembly consists of a tubular part, means attaching the tubular part to the compliant housing such that the tubular part can comply with radial displacement of the reciprocating piston rod, and force-applying means acting between the tubular part and the lubricant control portion for urging the lubricant control portion into forceful contact around the reciprocating piston rod.

  2. NOVEL LUBRICANT ADDITIVES - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Find More Like This Return to Search NOVEL LUBRICANT ADDITIVES Argonne National Laboratory Contact ANL About This Technology <em>Upper, the functionalized nanostructures mixed with poly-alpha-olefin (PAO)-4 reduce friction as test temperature is raised. Lower, Friction coefficient remains unchanged at all test temperatures with PAO4 alone.&nbsp; </em><br /> Upper, the functionalized nanostructures mixed with poly-alpha-olefin (PAO)-4 reduce friction as test temperature is

  3. Effect of microwave radiation on Jayadhar cotton fibers: WAXS studies

    SciTech Connect (OSTI)

    Niranjana, A. R. Mahesh, S. S. Divakara, S. Somashekar, R.

    2014-04-24

    Thermal effect in the form of micro wave energy on Jayadhar cotton fiber has been investigated. Microstructural parameters have been estimated using wide angle x-ray scattering (WAXS) data and line profile analysis program developed by us. Physical properties like tensile strength are correlated with X-ray results. We observe that the microwave radiation do affect significantly many parameters and we have suggested a multivariate analysis of these parameters to arrive at a significant result.

  4. Characterization of Spray Lubricants for the Die Casting Process

    SciTech Connect (OSTI)

    Sabau, Adrian S

    2008-01-01

    During the die casting process, lubricants are sprayed in order to cool the dies and facilitate the ejection of the casting. The cooling effects of the die lubricant were investigated using Thermogravimetric analysis (TGA), heat flux sensors (HFS), and infrared imaging. The evolution of the heat flux and pictures taken using a high speed infrared camera revealed that lubricant application was a transient process. The short time response of the HFS allows the monitoring and data acquisition of the surface temperature and heat flux without additional data processing. A similar set of experiments was performed with deionized water in order to assess the lubricant effect. The high heat flux obtained at 300 C was attributed to the wetting and absorbant properties of the lubricant. Pictures of the spray cone and lubricant flow on the die were also used to explain the heat flux evolution.

  5. Lubricants - Pathway to Improving Fuel Efficiency of Legacy Fleet Vehicles

    Broader source: Energy.gov (indexed) [DOE]

    | Department of Energy Reviews recent studies on potential for low-viscosity lubricants and low-friction surfaces and additives to reduce fuel consumption, and impact of such approaches on other critical lubricant metrics PDF icon deer11_fenske.pdf More Documents & Publications Lubricants Activities Vehicle Technologies Office Merit Review 2014: DOE/DOD Parasitic Energy Loss Collaboration DOE/DOD Parasitic Energy Loss

  6. Collaborative Lubricating Oil Study on Emissions (CLOSE Project) |

    Broader source: Energy.gov (indexed) [DOE]

    Department of Energy 1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon ace046_lawson_2011_o.pdf More Documents & Publications Collaborative Lubricating Oil Study on Emissions (CLOSE Project) Collaborative Lubricating Oil Study on Emissions (CLOSE) Project Vehicle Technologies Office: 2012 Fuel and Lubricant Technologies R&D Annual Progress Report

  7. Collaborative Lubricating Oil Study on Emissions (CLOSE) Project |

    Broader source: Energy.gov (indexed) [DOE]

    Department of Energy Extensive chemical and physical characterization performed on emissions from normal and high emitting light-, medium-, and heavy-duty vehicles to evaluate relative contributions of fuel and lubricating oil on tailpipe emissions. PDF icon deer08_lawson.pdf More Documents & Publications Collaborative Lubricating Oil Study on Emissions (CLOSE Project) Collaborative Lubricating Oil Study on Emissions (CLOSE Project) The FreedomCAR & Vehicle Technologies Health

  8. Correlations Between Metallic Lubricant Additive Species in the Ring Pack

    Broader source: Energy.gov (indexed) [DOE]

    and Ash Emissions and Their Dependence on Crankcase Oil Properties | Department of Energy watson.pdf More Documents & Publications Examining Effects of Lubricant Composition in Engine Component Systems in Pursuit of Enhanced Efficiency under Environmental Constraints Reducing Lubricant Ash Impact on Exhaust Aftertreatment with a Oil Conditioning Filter Minimizing Lubricant-Ash Requirement and Impact on Emission Aftertreatment Systems via an Oil Conditioning Filter

  9. Auto/Steel Partnership: Hydroforming Materials and Lubricant...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AutoSteel Partnership: Hydroforming Materials and Lubricant Lightweight Rear Chassis ... FY 2008 Progress Report for Lightweighting Materials - 5. Automotive Metals-Steel FY 2009 ...

  10. Minimizing Lubricant-Ash Requirement and Impact on Emission Aftertreat...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Acidity, Oxidation and Corrosion Correlations Between Metallic Lubricant Additive Species in the Ring Pack and Ash Emissions and Their Dependence on Crankcase Oil Properties

  11. Correlations Between Metallic Lubricant Additive Species in the...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Dependence on Crankcase Oil Properties Correlations Between Metallic Lubricant Additive Species in the Ring Pack and Ash Emissions and Their Dependence on Crankcase Oil Properties ...

  12. Impact of Biodiesel on Ash Emissions and Lubricant Properties...

    Broader source: Energy.gov (indexed) [DOE]

    Effects of Fuel Dilution with Biodiesel on Lubricant Acidity, Oxidation and Corrosion Development of High Performance Heavy Duty Engine Oils Performance of Biofuels and Biofuel ...

  13. Natural Oils - The Next Generation of Diesel Engine Lubricants...

    Energy Savers [EERE]

    Oils - The Next Generation of Diesel Engine Lubricants? JOE PEREZ 1 & SHAWN WHITACRE 2 1 The ... TEST PURPOSE COMMENT BOSCH INJECTOR HIGH TEMPERATURE - HIGH SHEAR BOSCH INJECTOR SHEAR ...

  14. Characteristics and Effects of Lubricant Additive Chemistry and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Service Life and Vehicle Fuel Economy Characteristics and Effects of Lubricant Additive Chemistry and Exhaust Conditions on Diesel Particulate Filter Service Life and Vehicle ...

  15. Examining Effects of Lubricant Composition in Engine Component...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    (LFEEE) in Modern Internal Combustion Engines Vehicle Technologies Office: 2014 Fuel and Lubricant Technologies R&D Annual Progress Report Engine Friction Reduction Through ...

  16. Reducing Lubricant Ash Impact on Exhaust Aftertreatment with...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Filter Effects of Fuel Dilution with Biodiesel on Lubricant Acidity, Oxidation and Corrosion Future Engine Fluids Technologies: Durable, Fuel-Efficient, and Emissions-Friendly

  17. 2011 Annual Merit Review Results Report - Fuels & Lubricants...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    1amr05.pdf More Documents & Publications 2010 DOE EERE Vehicle Technologies Program Merit Review - Fuels Technologies 2011 Annual Merit Review Results Report - Fuels & Lubricants...

  18. Large-Scale Manufacturing of Nanoparticulate-Based Lubrication Additives

    SciTech Connect (OSTI)

    2009-06-01

    This factsheet describes a research project whose goal is to design, develop, manufacture, and scale up boron-based nanoparticulate lubrication additives.

  19. 2011 Annual Merit Review Results Report - Fuels & Lubricants...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2amr05.pdf More Documents & Publications 2011 Annual Merit Review Results Report - Fuels & Lubricants 2010 DOE EERE Vehicle Technologies Program Merit Review - Fuels Technologies...

  20. High-Performance Renewable Base Oils for Industrial Lubricants...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    When used in industrial lubricants of all types, Biosynthetic's oils achieved superior performance in many critical performance areas, including pour point, viscosity index, flash ...

  1. The Impact of Lubricant Formulation on the Performance of NOx...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Formulation on the Performance of NOx Adsorber Catalysts The Impact of Lubricant Formulation on the Performance of NOx Adsorber Catalysts PDF icon 2005deerwhitacre.pdf More ...

  2. A Novel Lubricant Formulation Strategy for 2% Fuel Efficiency...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    demonstration of temporary shear thinning On Track 3. Nanoparticles in Lubricants and Characterization GoNo-go Decision: no severe wear Completion 4. Model-Assisted Optimal...

  3. Vehicle Technologies Office Merit Review 2015: A Novel Lubricant...

    Office of Environmental Management (EM)

    through Surface Modification (Agreement ID:23284) Project ID:18518 Vehicle Technologies Office Merit Review 2014: Can hard coatings and lubricant anti-wear additives work together?...

  4. Natural Oils - The Next Generation of Diesel Engine Lubricants...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Reducing Lubricant Ash Impact on Exhaust Aftertreatment with a Oil Conditioning Filter Effect of Exhaust Gas Recirculation (EGR) on Diesel Engine Oil ...

  5. The role of polymer formation during vapor phase lubrication...

    Office of Scientific and Technical Information (OSTI)

    The lubrication of silicon surfaces with alcohol vapors has recently been demonstrated. ... The parent alcohol molecule pentanol, has molecular weight of 88amu, suggesting that ...

  6. Candle and candle wax containing metathesis and metathesis-like products

    DOE Patents [OSTI]

    Murphy, Timothy A; Tupy, Michael J; Abraham, Timothy W; Shafer, Andy

    2014-04-01

    A wax comprises a metathesis product and/or a product that resembles, at least in part, a product which may be formed from a metathesis reaction. The wax may be used to form articles, for example, candles (container candles, votive candles, and/or a pillar candles), crayons, fire logs, or tarts. The wax commonly includes other components in addition to the metathesis product.

  7. Candle and candle wax containing metathesis and metathesis-like products

    DOE Patents [OSTI]

    Murphy, Timothy A; Tupy, Michael J; Abraham, Timothy W; Shafer, Andy

    2014-12-16

    A wax comprises a metathesis product and/or a product that resembles, at least in part, a product which may be formed from a metathesis reaction. The wax may be used to form articles for example, candles (container candles, votive candles, and/or a pillar candles), crayons, fire logs or tarts. The wax commonly includes other components in addition to the metathesis product.

  8. Evaluation of Wax Deposition and Its Control During Production of Alaska North Slope Oils

    SciTech Connect (OSTI)

    Tao Zhu; Jack A. Walker; J. Liang

    2008-12-31

    Due to increasing oil demand, oil companies are moving into arctic environments and deep-water areas for oil production. In these regions of lower temperatures, wax deposits begin to form when the temperature in the wellbore falls below wax appearance temperature (WAT). This condition leads to reduced production rates and larger pressure drops. Wax problems in production wells are very costly due to production down time for removal of wax. Therefore, it is necessary to develop a solution to wax deposition. In order to develop a solution to wax deposition, it is essential to characterize the crude oil and study phase behavior properties. The main objective of this project was to characterize Alaskan North Slope crude oil and study the phase behavior, which was further used to develop a dynamic wax deposition model. This report summarizes the results of the various experimental studies. The subtasks completed during this study include measurement of density, molecular weight, viscosity, pour point, wax appearance temperature, wax content, rate of wax deposition using cold finger, compositional characterization of crude oil and wax obtained from wax content, gas-oil ratio, and phase behavior experiments including constant composition expansion and differential liberation. Also, included in this report is the development of a thermodynamic model to predict wax precipitation. From the experimental study of wax appearance temperature, it was found that wax can start to precipitate at temperatures as high as 40.6 C. The WAT obtained from cross-polar microscopy and viscometry was compared, and it was discovered that WAT from viscometry is overestimated. From the pour point experiment it was found that crude oil can cease to flow at a temperature of 12 C. From the experimental results of wax content, it is evident that the wax content in Alaskan North Slope crude oil can be as high as 28.57%. The highest gas-oil ratio for a live oil sample was observed to be 619.26 SCF/STB. The bubblepoint pressure for live oil samples varied between 1600 psi and 2100 psi. Wax precipitation is one of the most important phenomena in wax deposition and, hence, needs to be modeled. There are various models present in the literature. Won's model, which considers the wax phase as a non-ideal solution, and Pedersen's model, which considers the wax phase as an ideal solution, were compared. Comparison indicated that Pedersen's model gives better results, but the assumption of wax phase as an ideal solution is not realistic. Hence, Won's model was modified to consider different precipitation characteristics of the various constituents in the hydrocarbon fraction. The results obtained from the modified Won's model were compared with existing models, and it was found that predictions from the modified model are encouraging.

  9. Ionic Liquids as Novel Lubricants and Additives | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Presentation given at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August, 2007, Detroit, Michigan. Sponsored by the U.S. Department of Energy's (DOE) Office of FreedomCAR and Vehicle Technologies (OFCVT). PDF icon deer07_qu.pdf More Documents & Publications Ionic Liquids as Novel Engine Lubricants or Lubricant Additives

  10. FY 2012 Progress Report for Fuel & Lubricant Technologies

    SciTech Connect (OSTI)

    Stork, Kevin

    2013-06-28

    Annual progress report of the Fuel & Lubricant Technologies subprogram supporting fuels and lubricants research and development (R&D) to provide vehicle users with cost-competitive options that enable high fuel economy with low emissions, and contribute to petroleum displacement.

  11. Dry film lubricant for difficult drawing applications of galvanized steels

    SciTech Connect (OSTI)

    Wakano, Shigeru; Sakane, Tadashi; Hirose, Yozou . Iron and Steel Research Lab.); Matsuda, Naomichi; Onodera, Show . Oleo Chemicals Research Lab.)

    1993-09-01

    Press formability of metals sheets is considered to depend on surface lubricity, press forming condition and mechanical properties of the metal sheets. In Zn and Zn-alloy plated steel sheets with heavy coatings, surface lubricity is the most important property. This is because the low melting temperature and low hardness of the plated layer occasionally cause microscopic galling through deformation at the beads of dies which may, consequently, result in sheet breakage. Press formability of Zn and Zn-alloy plated steel sheets with heavy coating weight has been improved by the use of a high viscosity lubricant oil and a Fe-Zn alloy flash-plating on galvannealed steel. However, the use of high viscosity lubricant oils created problems with oil staining and removal before painting. An alloy flash plating results in appreciably higher production costs. This article describes the characteristics of a thin film dry lubricant, Super S-coat, as a new countermeasure, which will overcome these problems.

  12. Process for upgrading wax from Fischer-Tropsch synthesis

    SciTech Connect (OSTI)

    Derr, W.R. Jr.; Garwood, W.E.; Kuo, J.C.; Leib, T.M.; Nace, D.M.; Tabak, S.A.

    1987-08-04

    A processor is described for converting synthesis gas to liquid hydrocarbons comprising the steps of: (a) charging the synthesis gas to a Fischer-Tropsch synthesis conversion zone containing a catalyst providing CO reducing characteristics to produce a waxy hydrocarbon liquid; (b) separating hydrocarbon wax from the waxy liquid; (c) catalytically cracking the wax in a fluidized bed of acid crystalline zeolite at cracking temperature under process conditions requiring a supply of heat to effect cracking, producing olefinic liquid hydrocarbon crackate in the gasoline and distillate boiling range along with olefinic light gas; (d) recovering distillate range hydrocarbons from the liquid crackate; (e) further converting the olefinic gasoline range hydrocarbon crackate and olefinic light gas under oligomerization conditions in contact with a shape selective medium pore acid oligomerization catalyst to upgrade at least a portion of the olefinic crackate and olefinic light gas to distillate range hydrocarbon product and producing by-product light fuel gas; (f) separating the light fuel gas from step (e) and passing the light fuel gas to cracking step (c) to supply heat.

  13. System and method for the mitigation of paraffin wax deposition from crude oil by using ultrasonic waves

    DOE Patents [OSTI]

    Towler, Brian F. (Laramie, WY)

    2007-09-04

    A method for mitigating the deposition of wax on production tubing walls. The method comprises positioning at least one ultrasonic frequency generating device adjacent the production tubing walls and producing at least one ultrasonic frequency thereby disintegrating the wax and inhibiting the wax from attaching to the production tubing walls. A system for mitigating the deposition of wax on production tubing walls is also provided.

  14. Compressible pressure compensator within closed lubricant volume of an earth boring apparatus

    SciTech Connect (OSTI)

    Saxman, W. C.; Parker, L. J.

    1985-04-09

    A compressible pressure compensating member is disposed within a sealed lubricant volume enclosing a bearing and seal system of an earth boring apparatus. Lubricant is maintained within the volume by metal face seals so that both the bearing and the seal structure are lubricated thereby. As the lubricant expands, due to thermal expansion under use, the increased pressure is accommodated by compression of the compressible member so that no lubricant is expelled through the seals. When the lubricant cools and contracts, the compensator expands to maintain the lubricant volume at the initially filled level.

  15. Renewable Fuels and Lubricants Laboratory (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2014-08-01

    This fact sheet describes the Renewable Fuels and Lubricants (ReFUEL) Laboratory at the U.S. Department of Energy National Renewable Energy Laboratory (NREL) is a state-of-the-art research and testing facility for advanced fuels and vehicles. Research and development aims to improve vehicle efficiency and overcome barriers to the increased use of renewable diesel and other nonpetroleum-based fuels, such as biodiesel and synthetic diesel derived from biomass. The ReFUEL Laboratory features a chassis dynamometer for vehicle performance and emissions research, two engine dynamometer test cells for advanced fuels research, and precise emissions analysis equipment. As a complement to these capabilities, detailed studies of fuel properties, with a focus on ignition quality, are performed at NREL's Fuel Chemistry Laboratory.

  16. CVD method of forming self-lubricating composites

    DOE Patents [OSTI]

    Besmann, T.M.; Blau, P.J.; Lee, W.Y.; Bae, Y.W.

    1998-12-01

    An article having a multiphase composite lubricant coating of a hard refractory matrix phase of titanium nitride dispersed with particles of a solid lubricating phase of molybdenum disulfide is prepared by heating the article to temperatures between 350 and 850 C in a reaction vessel at a reduced pressure and passing a gaseous mixture of Ti((CH{sub 3}){sub 2}N){sub 4}, MoF{sub 6}, H{sub 2}S and NH{sub 3} over the heated article forming a multiphase composite lubricant coating on the article. 1 fig.

  17. CVD method of forming self-lubricating composites

    DOE Patents [OSTI]

    Besmann, Theodore M. (Oak Ridge, TN); Blau, Peter J. (Oak Ridge, TN); Lee, Woo Y. (Knoxville, TN); Bae, Yong W. (Oak Ridge, TN)

    1998-01-01

    An article having a multiphase composite lubricant coating of a hard refractory matrix phase of titanium nitride dispersed with particles of a solid lubricating phase of molybdenum disulfide is prepared by heating the article to temperatures between 350.degree. and 850.degree. C. in a reaction vessel at a reduced pressure and passing a gaseous mixture of Ti((CH.sub.3).sub.2 N).sub.4, MoF.sub.6, H.sub.2 S and NH.sub.3 over the heated article forming a multiphase composite lubricant coating on the article.

  18. Bubble column apparatus for separating wax from catalyst slurry

    DOE Patents [OSTI]

    Neathery, James K.; Davis, Burtron H.

    2004-07-13

    Novel methods and devices for production of liquid hydrocarbon products from gaseous reactants are disclosed. In one aspect, a method for separating a liquid hydrocarbon, typically a wax, from a catalyst containing slurry is provided, comprising passing the slurry through at least one downcomer extending from an overhead separation chamber and discharging into the bottom of a slurry bubble column reactor. The downcomer includes a cross-flow filtration element for separating a substantially particle-free liquid hydrocarbon for downstream processing. In another aspect, a method for promoting plug-flow movement in a recirculating slurry bubble column reactor is provided, comprising discharging the recirculating slurry into the reactor through at least one downcomer which terminates near the bottom of the reactor. Devices for accomplishing the above methods are also provided.

  19. Ionic Liquids as Multifunctional Ashless Additives for Engine Lubrication

    Broader source: Energy.gov [DOE]

    A group of oil-miscible ionic liquids has been developed by an ORNL-GM team as candidate lubricant additives with promising physical/chemical properties and potential multiple functionalities.

  20. Ionic Liquids as Multi-Functional Lubricant Additives to Enhance...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Vehicle Technologies Office Merit Review 2014: Ionic Liquids as Anti-Wear Additives for Next-Generation Low-Viscosity Fuel-Efficient Engine Lubricants Ionic Liquids as Novel Engine ...

  1. Renewable Fuels and Lubricants (ReFUEL) Laboratory

    SciTech Connect (OSTI)

    Not Available

    2004-08-01

    Fact sheet describing NREL's Renewable Fuels and Lubricants Laboratory (ReFUEL). ReFUEL is a world-class research and testing facility dedicated to future fuels and advanced heavy-duty vehicle research, located in Denver, Colorado.

  2. Ionic Liquids as Lubricants or Additives - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Industrial Technologies Industrial Technologies Find More Like This Return to Search Ionic Liquids as Lubricants or Additives Oak Ridge National Laboratory Contact ORNL About This Technology Technology Marketing SummaryNew ionic liquids invented at ORNL show great promise as lubricants for aluminum and steel in combustion engines, bearings, and microelectromechanical systems (MEMS). The ammonium-based ionic liquids are strongly adsorbant on contact surfaces, leading to a more than 30% friction

  3. Mechanistic aspects of vapor phase lubrication of silicon. (Conference) |

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect Mechanistic aspects of vapor phase lubrication of silicon. Citation Details In-Document Search Title: Mechanistic aspects of vapor phase lubrication of silicon. No abstract prepared. Authors: Dugger, Michael Thomas ; Dirk, Shawn M. ; Ohlhausen, James Anthony Publication Date: 2010-10-01 OSTI Identifier: 1028381 Report Number(s): SAND2010-7362C TRN: US201122%%249 DOE Contract Number: AC04-94AL85000 Resource Type: Conference Resource Relation: Conference: Proposed for

  4. NREL: Transportation Research - Renewable Fuels and Lubricants Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Renewable Fuels and Lubricants Laboratory Photo of a heavy-duty truck being driven on a chassis dynamometer. The heavy-duty chassis dynamometer at the ReFUEL Laboratory simulates on-road driving in a controlled laboratory setting. Photo by Dennis Schroeder, NREL NREL's Renewable Fuels and Lubricants (ReFUEL) Laboratory is a state-of-the-art research and testing facility for advanced fuels and vehicles. Research and development focuses on overcoming barriers to the increased use of renewable

  5. Experimental and Theoretical Investigation of Lubricant and Additive

    Broader source: Energy.gov (indexed) [DOE]

    Effects on Engine Friction | Department of Energy Combining data from motored engine friction, a theoretical engine model, a line friction contact rig, and a fired engine can provide better insight to lube oil and additive performance. PDF icon p-02_rohr.pdf More Documents & Publications Validation of a Small Engine Based Procedure for Studying Performance of Engine Lube Oils, Ionic Liquids as Lubricants and/or Lubricant Additives, Opportunities for Engine Friction Reduction and Durable

  6. Lubricant wear particle analysis by filter patch extraction

    SciTech Connect (OSTI)

    Smart, C.L.

    1996-07-01

    Lubricating Oil Analysis (LOA) has become an important part of a comprehensive Reliability Centered Maintenance (RCM) program. However, knowing the condition of the lubricant alone does not provide a complete description of equipment reliability. Condition monitoring for equipment can be accomplished through Wear Particle Analysis (WPA). This usually involves separating suspended materials and wear products from the lubricant by magnetic (ferrographic) means. This paper will present a simple, low-cost, alternate method of particle acquisition called Filter Patch Extraction (FPE). This method removes solids, regardless of their composition, from the lubricant by vacuum filtration and deposits them onto a filter for microscopic examination similar to that of analytical ferrography. A large filter pore size retains suspended materials and permits rapid filtration of large volumes of lubricant thereby increasing the accuracy of the wear and cleanliness profile that can be established for a given machine. Qualitative trending of equipment wear and lubricant system cleanliness are easily performed with FPE. Equipment condition is determined by then characterizing the metal particles which are recovered. Examined filters are easily archived in filter holders for future reference. Equipment for FPE is inexpensive and readily available. The technique is field-portable, allowing WPA to be performed on-site, eliminating delays with remote laboratories while building customer participation and support. There are numerous advantages for using FPE in a machine condition monitoring program.

  7. Development of Screenable Wax Coatings and Water-Based Pressure Sensitive Adhesives

    SciTech Connect (OSTI)

    2006-10-01

    This factsheet describes a research project whose goal is to design new formulations and production processes for water-based adhesives and wax coatings that can be easily screened from recycling operations.

  8. Current issues in natural gas lubrication

    SciTech Connect (OSTI)

    Reber, J.

    1997-10-01

    Because of the ability of natural gas to burn completely relatively easily, supplying excess oxygen to promote complete reactions is a viable alternative to catalysts. Hence, lean burn technology has a natural fit for this industry. Lube oil is not adversely affected by lean burn operation. There is a slight tendency to cause more oil nitration than oxidation, but the real difference is not significant. Operators may notice somewhat more varnish (caramel color) and less sludge (black) as a result. Because the fuel is burned more completely, there is less problem with fuel-derived oil contamination. Also because of the excess air in the combustion chamber, overall cylinder temperature is lower, causing less stress on the oil. Oil life is generally lengthened. One common misconception that lean burn engines require different lubricants may stem from a change at Waukesha Engine Division--Dresser Industries. Waukesha has changed its lube oil requirements for VHP 3521, 5115, 7042, 9390 GL turbocharged and lean burn model engines. The lube oil specification for these engines is 1% to 1.7% ash with the same 0.10% zinc maximum. This change is not because of the lean burn nature of these engines, rather it is because of drastically decreased lube oil consumption. With less oil consumption, less ash is carried to the critical exhaust valve seat area to prevent valve recession.

  9. Method of removing an immiscible lubricant from a refrigeration system and apparatus for same

    DOE Patents [OSTI]

    Spauschus, Hans O.; Starr, Thomas L.

    1999-01-01

    A method of separating an immiscible lubricant from a liquid refrigerant in a refrigerating system including a compressor, a condenser, an expansion device and an evaporator, wherein the expansion device is connected to the condenser by a liquid refrigerant flow line for liquid refrigerant and immiscible lubricant. The method comprising slowing the rate of flow of the liquid refrigerant and immiscible lubricant between the condenser and the expansion device such that the liquid refrigerant and the immiscible lubricant separate based upon differences in density. The method also comprises collecting the separated immiscible lubricant in a collection chamber in fluid communication with the separated immiscible lubricant. Apparatus for performing the method is also disclosed.

  10. Method to improve lubricity of low-sulfur diesel and gasoline fuels

    DOE Patents [OSTI]

    Erdemir, Ali

    2004-08-31

    A method for providing lubricity in fuels and lubricants includes adding a boron compound to a fuel or lubricant to provide a boron-containing fuel or lubricant. The fuel or lubricant may contain a boron compound at a concentration between about 30 ppm and about 3,000 ppm and a sulfur concentration of less than about 500 ppm. A method of powering an engine to minimize wear, by burning a fuel containing boron compounds. The boron compounds include compound that provide boric acid and/or BO.sub.3 ions or monomers to the fuel or lubricant.

  11. CRC handbook of lubrication. Theory and practice of tribology: Volume II: Theory and design

    SciTech Connect (OSTI)

    Booser, E.R.

    1984-01-01

    This handbook covers the general area of lubrication and tribology in all its facets: friction, wear lubricants (liquid, solid, and gas), greases, lubrication principles, applications to various mechanisms, design principles of devices incorporating lubrication, maintenance, lubrication scheduling, and standardized tests; as well as environmental problems and conservation. The information contained in these two volumes will aid in achieving effective lubrication for control of friction and wear, and is another step to improve understanding of the complex factors involved in tribology. Both metric and English units are provided throughout both volumes.

  12. Performance of MOV Stem Lubricants at Elevated Temperatures

    SciTech Connect (OSTI)

    DeWall, Kevin George; Nitzel, Michael Everett; Watkins, John Clifford

    2001-07-01

    This paper documents the results of recent tests sponsored by the U. S. Nuclear Regulatory Commission (NRC) and performed by the Idaho National Engineering and Environmental Laboratory (INEEL). These tests address the effectiveness of the lubricant used on the threaded portion of the valve stem, where the stem nut turns on the stem. Recent testing indicates that an elevated temperature environment can lead to significant increases in the friction coefficient at the stem/stem-nut interface. Most valve actuator qualification tests are performed at room temperature. Similarly, in-service tests are run at ambient plant temperatures, usually 70 to 100F. Since design conditions can lead to valve operating temperatures in the 200 to 300F range, it is important to know whether a temperature-induced increase in friction at the stem/stem-nut interface will prevent the required operation of critical valves. Lubricant aging is another phenomenon that might have deleterious effects on the thrust output of a valve actuator. Laboratory experience and field experience both indicate that after long periods in elevated temperature environments, the lubricants may lose their lubrication qualities. The scope of the current test program includes testing of five different lubricants on four different valve stems. Pending completion of the testing, results of the tests conducted using two of the four stems are discussed. The test series included collection of baseline data at room temperature, single step temperature tests where the temperature of the test setup was elevated directly to 250F, and step testing where the temperature was elevated in steps to 130, 190, and 250F, then returned to 70F. All greases tested showed evidence of physical change after elevated temperature tests. Except for one particular lubricant, all of the greases tested showed increased coefficients of friction at elevated temperatures. Numerous other preliminary conclusions are presented. Recommendations for future research in the area of aged valve stem lubricant performance at elevated temperatures are also presented.

  13. Rotary seal with enhanced lubrication and contaminant flushing

    DOE Patents [OSTI]

    Dietle, Lannie L.

    2000-01-01

    A resilient, ring shaped interference-type hydrodynamic rotary seal having waves on the lubricant side which provide increased film thickness and flushing action by creating contact pressure induced angulated restrictions formed by abrupt restrictive diverters. The angulated restrictions are defined by projecting ridges, corners at the trailing edge of the waves, or simply by use of a converging shape at the trailing edge of the waves which is more abrupt than the gently converging hydrodynamic inlet shape at the leading edge of the waves. The abrupt restrictive diverter performs two functions; a restricting function and a diverting function. The angulated restrictions cause a local film thickness restriction which produces a damming effect preventing a portion of the lubricant from leaking out of the dynamic sealing interface at the trailing edge of the wave, and results in a much thicker lubricant film thickness under the waves. This contributes to more film thickness in the remainder of the dynamic sealing interface toward the environment because film thickness tends to decay gradually rather than abruptly due to the relative stiffness of the seal material. Because of the angle of the abrupt restrictive diverter relative to the relative rotation direction, in conjunction with the restriction or damming effect, a strong diverting action is produced which pumps lubricant across the dynamic sealing interface toward the environment. The lubricant diversion is caused by the component of the rotational velocity tangent to the abrupt restrictive diverter. The component of rotational velocity normal to the abrupt restrictive diverter causes a portion of the lubricant film to be pumped past the abrupt restrictive diverter, thereby assuring adequate lubrication thereof.

  14. Process for producing biodiesel, lubricants, and fuel and lubricant additives in a critical fluid medium

    DOE Patents [OSTI]

    Ginosar, Daniel M.; Fox, Robert V.

    2005-05-03

    A process for producing alkyl esters useful in biofuels and lubricants by transesterifying glyceride- or esterifying free fatty acid-containing substances in a single critical phase medium is disclosed. The critical phase medium provides increased reaction rates, decreases the loss of catalyst or catalyst activity and improves the overall yield of desired product. The process involves the steps of dissolving an input glyceride- or free fatty acid-containing substance with an alcohol or water into a critical fluid medium; reacting the glyceride- or free fatty acid-containing substance with the alcohol or water input over either a solid or liquid acidic or basic catalyst and sequentially separating the products from each other and from the critical fluid medium, which critical fluid medium can then be recycled back in the process. The process significantly reduces the cost of producing additives or alternatives to automotive fuels and lubricants utilizing inexpensive glyceride- or free fatty acid-containing substances, such as animal fats, vegetable oils, rendered fats, and restaurant grease.

  15. Development of a bench scale test to evaluate lubricants for use with methanol-fueled engines

    SciTech Connect (OSTI)

    Shah, R.; Klaus, E.; Duda, J.L.

    1996-10-01

    In methanol-fueled diesel engines, the crankcase lubricant is used to lubricate both the engine and the fuel injector system. Crankcase lubricants including some designed for methanol-fueled engines are not completely compatible with the methanol fuel. In order to test the effect of methanol extraction on diesel engine lubricant performance, two extraction protocols were developed: one to simulate the fuel injector (1000 parts of methanol to one part of lubricant) and the other to simulate an extreme case of methanol contamination in the crank-case (one part of methanol to five parts of lubricant). The extracted samples of the lubricant were stripped to remove the methanol. The samples were then evaluated for changes in oxidative stability and lubricity. 12 refs., 3 figs., 8 tabs.

  16. Lubricant additives, friend or foe: What the equipment design engineer needs to know

    SciTech Connect (OSTI)

    Nixon, H.P.; Zantopulos, H.

    1995-10-01

    Lubricant formulations and lubricant additives have been slanted heavily toward protecting gear concentrated contacts from galling and wear. Much of the performance differentiation of these lubricants has been dependent on highly accelerated standardized laboratory testing. The area of contact fatigue has played a less important role in shaping lubricant formulations, but new test results for several commercially available gear lubricants suggest this area warrants a closer examination. The performance effects of fully and partially additized lubricants were studied using standard bearing industry rolling contact fatigue and wear testing procedures for tapered roller bearings. These test results indicate significant detrimental effects to wear, and fatigue life performance can occur with some additized lubricant formulations. Observations of functional surfaces, before and after testing, are made and examined for several lubricant formulations. The implications of these findings for equipment applications are discussed, and suggestions are made for ways to minimize or avoid potential detrimental performance effects. 10 refs., 11 figs., 3 tabs.

  17. Lubricant-Friendly, Superhard and Low-Friction Coatings by Design...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Lubricant-Friendly, Superhard and Low-Friction Coatings by Design Lubricant-Friendly, Superhard and Low-Friction Coatings by Design Superhard and low-friction coatings and surface ...

  18. U.S. Refinery Yield

    U.S. Energy Information Administration (EIA) Indexed Site

    Special Naphthas 0.2 0.2 0.3 0.3 0.3 0.2 1993-2015 Lubricants 1.1 1.1 1.0 1.0 1.0 1.1 1993-2015 Waxes 0.1 0.1 0.1 0.1 0.0 0.0 1993-2015 Petroleum Coke 5.3 5.5 5.5 5.5 5.4 5.3 ...

  19. Table Definitions, Sources, and Explanatory Notes

    Gasoline and Diesel Fuel Update (EIA)

    ... Liquefied Petroleum Gases (LPG) A group of hydrocarbon-based ... aviation gasoline, special naphthas, wax, petroleum ... It is used in steam-powered vessels in government service ...

  20. Vehicle Technologies Office: 2012 Fuel and Lubricant Technologies R&D

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Annual Progress Report | Department of Energy Fuel and Lubricant Technologies R&D Annual Progress Report Vehicle Technologies Office: 2012 Fuel and Lubricant Technologies R&D Annual Progress Report The Fuel & Lubricant Technologies subprogram supports fuels and lubricants research and development (R&D) to provide vehicle users with cost-competitive options that enable high fuel economy with low emissions, and contribute to petroleum displacement. PDF icon

  1. Vehicle Technologies Office: 2013 Fuel and Lubricant Technologies R&D

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Annual Progress Report | Department of Energy Fuel and Lubricant Technologies R&D Annual Progress Report Vehicle Technologies Office: 2013 Fuel and Lubricant Technologies R&D Annual Progress Report This report describes the progress made on the research and development projects funded by the Fuel and Lubricants subprogram in the Vehicle Technologies Office, as described on the Lubricants and Alternative Fuels pages. Past year's reports are listed on the Annual Progress Reports page.

  2. Few-Layer Graphene as a Dry Lubricant | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Few-Layer Graphene as a Dry Lubricant Technology available for licensing: Graphene layers act as a two-dimensional nanomaterial and form a conformal protective coating on sliding contact interfaces. These factors facilitate shear and slow down oxidation (tribo-corrosion), thus drastically reduce wear. Functions as a dry lubricant, reducing wear four-fold and friction six-fold Cost-competitive with oil-based lubricants; may replace oil-based lubricants in some applications PDF icon

  3. Effects of Fuel Dilution with Biodiesel on Lubricant Acidity, Oxidation and

    Broader source: Energy.gov (indexed) [DOE]

    Corrosion | Department of Energy In-cylinder fuel injection to produce rich exhaust for regeneration of lean NOx trap catalyst and diesel particulate filter results in substantial fuel dilution of lubricating oil cause changes of lubricating oil properties and scuffing of engine components. PDF icon deer08_watson.pdf More Documents & Publications Impact of Biodiesel on Ash Emissions and Lubricant Properties Affecting Fuel Economy and Engine Wear Reducing Lubricant Ash Impact on Exhaust

  4. Lubricants and greases: Properties and evaluation. (Latest citations from Fluidex). Published Search

    SciTech Connect (OSTI)

    1998-02-01

    The bibliography contains citations concerning a variety of lubricants, including synthetic oils and greases. Topics include properties characterization, additives, rheological studies, and uses. Bearing and gear lubricants are discussed, and lubricant testing methods are described. Some attention is given to specific applications in industry. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

  5. Lubricants and greases: Properties and evaluation. (Latest citations from FLUIDEX data base). Published Search

    SciTech Connect (OSTI)

    Not Available

    1992-08-01

    The bibliography contains citations concerning a variety of lubricants, including synthetic oils and greases. Topics include properties characterization, additives, rheological studies, and uses. Bearing and sea lubricants are discussed, and lubricant testing methods are described. Some attention is given to specific applications in industry. (Contains 250 citations and includes a subject term index and title list.)

  6. Sliding contacts: Wear and lubrication. (Latest citations from the NTIS data base). Published Search

    SciTech Connect (OSTI)

    Not Available

    1992-10-01

    The bibliography contains citations concerning friction wear and the behavior and properties of sliding and sliding-roll contact lubricants. Topics include lubrication mechanism descriptions, failure reduction of mechanical components for specific contacts, and lubricant performance evaluations. Both electrical and mechanical contact applications are presented. (Contains 250 citations and includes a subject term index and title list.)

  7. Frictional anisotropy under boundary lubrication: effect of surface texture.

    SciTech Connect (OSTI)

    Ajayi, O. O.; Erck, R. A.; Lorenzo-Martin, C.; Fenske, G. R.; Energy Systems

    2009-06-15

    The friction coefficient was measured under boundary lubrication with a ball-on-flat contact configuration in unidirectional sliding. The ball was smooth and hardened 52100 steel. Discs were made from case-carburized and hardened 4620, annealed 1080, and 1018 steels with directionally ground surfaces. A synthetic lubricant of stock polyalphaolefin was used for testing. During testing with each material, a frictional spike was observed whenever the ball slid parallel to the grinding ridge on the disc surface. The average friction coefficient for all tests was about 0.1, which is typical for the boundary lubrication regime. The magnitude of the frictional spikes, which reached as high as a friction coefficient of 0.25, and their persistence depended on the hardness of the disc surface. On the basis of elastohydrodynamic theory, coupled with the observation of severe plastic deformation on the ridges parallel to the sliding direction, the frictional spike could be due to localized plastic deformation on the disc surface at locations of minimal thickness for the lubricant fluid film. This hypothesis was further supported by lack of frictional spikes in tests using discs coated with a thin film of diamond-like carbon, in which plastic deformation is minimal.

  8. Fuel, lubricant and additive effects in combustion chamber deposit formation

    SciTech Connect (OSTI)

    Kelemen, S.R.; Homan, H.S.

    1996-10-01

    CCD causes octane requirement increase (ORI) and can potentially contributes to exhaust emissions and combustion chamber deposit interference (CCDI). Experiments were conducted to identify the separate fuel, lubricant and additive contributions to the amount and composition of CCD. CCD originates from multiple sources. Gasoline hydrocarbon components, gasoline additives, engine lubricant, and atmospheric nitrogen contribute to CCD in different ways. With some fuels the engine lubricant is the main contributor to CCD and this is shown by the high ash level in the CCD. For other fuels CCD is predominantly organic. Significant amounts of nitrogen were found in the CCD even when the fuel and lubricant were nitrogen free. The pyrolysis reactivity of different CCDs was studied to gain an understanding about the transformations that potentially happen over longer times and lower temperatures on the combustion chamber walls. In all cases during mild pyrolysis (375{degrees}C) there was a substantial increase in the level of aromatic carbon and a decrease in the level of organic oxygen. The largest increases in the amount of aromatic carbon occurred for CCDs that were the least aromatic.

  9. GAMMA IRRADIATION TESTING OF MONTAN WAX FOR USE IN WASTE MANAGEMENT SYSTEMS

    SciTech Connect (OSTI)

    SOO,P.; HEISER,J.; HART,A.

    1996-09-08

    A field demonstration was funded by the US Department of Energy (DOE) to quantify the potential use of montan wax as a subsurface barrier material for nuclear waste management applications. As part of that demonstration, a study was completed to address some of the characteristics of the wax. Of particular interest is its resistance to chemical and structural changes that would influence its integrity as a barrier to minimize the migration of contaminants from their storage or disposal locations. Properties that were evaluated included hardness, melting point, molecular weight, and biodegradation as a function of gamma radiation dose. Based on the data obtained to date the wax is extremely resistant to radiation-induced change. Coupled with low permeability, the material shows promise as a subsurface barrier material.

  10. Use of Textured Surfaces to Mitigate Sliding Friction and Wear of Lubricated and Non-Lubricated Contacts

    SciTech Connect (OSTI)

    Blau, Peter Julian

    2012-03-01

    If properly employed, the placement of three-dimensional feature patterns, also referred to as textures, on relatively-moving, load-bearing surfaces can be beneficial to their friction and wear characteristics. For example, geometric patterns can function as lubricant supply channels or depressions in which to trap debris. They can also alter lubricant flow in a manner that produces thicker load-bearing films locally. Considering the area occupied by solid areas and spaces, textures also change the load distribution on surfaces. At least ten different attributes of textures can be specified, and their combinations offer wide latitude in surface engineering. By employing directional machining and grinding procedures, texturing has been used on bearings and seals for well over a half century, and the size scales of texturing vary widely. This report summarizes past work on the texturing of load-bearing surfaces, including past research on laser surface dimpling of ceramics done at ORNL. Textured surfaces generally show most pronounced effects when they are used in conformal or nearly conformal contacts, like that in face seals. Combining textures with other forms of surface modification and lubrication methods can offer additional benefits in surface engineering for tribology. As the literature and past work at ORNL shows, texturing does not always provide benefits. Rather, the selected pattern and arrangement of features must be matched to characteristics of the proposed application, bearing materials, and lubricants.

  11. Wax barrier for use with in situ processes for treating formations

    DOE Patents [OSTI]

    Vinegar, Harold J.; Carter, Ernest E.; Son, Jaime Santos; Bai, Taixu; Khoda Verdian, Mohamad Fereydoon

    2010-04-27

    Methods for forming a barrier around at least a portion of a treatment area in a subsurface formation are described herein. A material including wax may be introduced into one or more wellbores. The material introduced into two or more wells may mix in the formation and congeal to form a barrier to fluid flow.

  12. Self-lubricating carbon nanotube reinforced nickel matrix composites

    SciTech Connect (OSTI)

    Scharf, T. W.; Neira, A.; Hwang, J. Y.; Banerjee, R.; Tiley, J.

    2009-07-01

    Nickel (Ni)--multiwalled carbon nanotube (CNT) composites have been processed in a monolithic form using the laser-engineered net shape (LENS) processing technique. Auger electron spectroscopy maps determined that the nanotubes were well dispersed and bonded in the nickel matrix and no interfacial chemical reaction products were determined in the as-synthesized composites. Mechanisms of solid lubrication have been investigated by micro-Raman spectroscopy spatial mapping of the worn surfaces to determine the formation of tribochemical products. The Ni-CNT composites exhibit a self-lubricating behavior, forming an in situ, low interfacial shear strength graphitic film during sliding, resulting in a decrease in friction coefficient compared to pure Ni.

  13. Preliminary Results of Cleaning Process for Lubricant Contamination

    SciTech Connect (OSTI)

    Eisenmann, D.; Brasche, L.; Lopez, R.

    2006-03-06

    Fluorescent penetrant inspection (FPI) is widely used for aviation and other components for surface-breaking crack detection. As with all inspection methods, adherence to the process parameters is critical to the successful detection of defects. Prior to FPI, components are cleaned using a variety of cleaning methods which are selected based on the alloy and the soil types which must be removed. It is also important that the cleaning process not adversely affect the FPI process. There are a variety of lubricants and surface coatings used in the aviation industry which must be removed prior to FPI. To assess the effectiveness of typical cleaning processes on removal of these contaminants, a study was initiated at an airline overhaul facility. Initial results of the cleaning study for lubricant contamination in nickel, titanium and aluminum alloys will be presented.

  14. Lubricant Formulation and Consumption Effects on Diesel Exhaust Ash

    Broader source: Energy.gov (indexed) [DOE]

    Emissions: | Department of Energy 5 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters PDF icon 2005_deer_plumley.pdf More Documents & Publications Detailed Characterization of Lubricant-Derived Ash-Related Species in Diesel Exhaust and Aftertreatment Systems Unraveling DPF Degradation using Chemical Tracers and Opportunities for Extending Filter Life Key Parameters Affecting DPF Performance Degradation and Impact on Lifetime Fuel Economy

  15. Hydrodynamically Lubricated Rotary Shaft Having Twist Resistant Geometry

    DOE Patents [OSTI]

    Dietle, Lannie; Gobeli, Jeffrey D.

    1993-07-27

    A hydrodynamically lubricated squeeze packing type rotary shaft with a cross-sectional geometry suitable for pressurized lubricant retention is provided which, in the preferred embodiment, incorporates a protuberant static sealing interface that, compared to prior art, dramatically improves the exclusionary action of the dynamic sealing interface in low pressure and unpressurized applications by achieving symmetrical deformation of the seal at the static and dynamic sealing interfaces. In abrasive environments, the improved exclusionary action results in a dramatic reduction of seal and shaft wear, compared to prior art, and provides a significant increase in seal life. The invention also increases seal life by making higher levels of initial compression possible, compared to prior art, without compromising hydrodynamic lubrication; this added compression makes the seal more tolerant of compression set, abrasive wear, mechanical misalignment, dynamic runout, and manufacturing tolerances, and also makes hydrodynamic seals with smaller cross-sections more practical. In alternate embodiments, the benefits enumerated above are achieved by cooperative configurations of the seal and the gland which achieve symmetrical deformation of the seal at the static and dynamic sealing interfaces. The seal may also be configured such that predetermined radial compression deforms it to a desired operative configuration, even through symmetrical deformation is lacking.

  16. Method of removing an immiscible lubricant from a refrigeration system and apparatus for same

    DOE Patents [OSTI]

    Spauschus, H.O.; Starr, T.L.

    1999-03-30

    A method is described for separating an immiscible lubricant from a liquid refrigerant in a refrigerating system including a compressor, a condenser, an expansion device and an evaporator, wherein the expansion device is connected to the condenser by a liquid refrigerant flow line for liquid refrigerant and immiscible lubricant. The method comprising slowing the rate of flow of the liquid refrigerant and immiscible lubricant between the condenser and the expansion device such that the liquid refrigerant and the immiscible lubricant separate based upon differences in density. The method also comprises collecting the separated immiscible lubricant in a collection chamber in fluid communication with the separated immiscible lubricant. Apparatus for performing the method is also disclosed. 3 figs.

  17. Research into Oil-based Colloidal-Graphite Lubricants for Forging of Al-based Alloys

    SciTech Connect (OSTI)

    Petrov, A.; Petrov, P.; Petrov, M.

    2011-05-04

    The presented paper describes the topical problem in metal forging production. It deals with the choice of an optimal lubricant for forging of Al-based alloys. Within the scope of the paper, the properties of several oil-based colloidal-graphite lubricants were investigated. The physicochemical and technological properties of these lubricants are presented. It was found that physicochemical properties of lubricant compositions have an influence on friction coefficient value and quality of forgings.The ring compression method was used to estimate the friction coefficient value. Hydraulic press was used for the test. The comparative analysis of the investigated lubricants was carried out. The forging quality was estimated on the basis of production test. The practical recommendations were given to choose an optimal oil-based colloidal-graphite lubricant for isothermal forging of Al-based alloy.

  18. Overview of DOE Fuel & Lubricant Technologies R&D | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuel & Lubricant Technologies R&D Overview of DOE Fuel & Lubricant Technologies R&D 2010 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C. PDF icon ft000_stork_2010_o.pdf More Documents & Publications Overview of DOE Fuel Technologies R&D Overview of Fuels Technologies Fuels & Lubricants

  19. The role of polymer formation during vapor phase lubrication of silicon.

    Office of Scientific and Technical Information (OSTI)

    (Conference) | SciTech Connect The role of polymer formation during vapor phase lubrication of silicon. Citation Details In-Document Search Title: The role of polymer formation during vapor phase lubrication of silicon. The lubrication of silicon surfaces with alcohol vapors has recently been demonstrated. With a sufficient concentration of pentanol vapor present, sliding of a silica ball on an oxidized silicon wafer can proceed with no measurable wear. The initial results of time-of-flight

  20. Offshore Lubricants to Exhibit 7.07% CAGR from 2014 to 2020 Due...

    Open Energy Info (EERE)

    segmented the global offshore lubricants market into gear oil, grease, engine oil, hydraulic oil, and others (such as circulating oil, turbine oil, and compressor oil). Among...

  1. Vehicle Technologies Office Merit Review 2015: A Novel Lubricant Formulation Scheme for 2% Fuel Efficiency Improvement

    Broader source: Energy.gov [DOE]

    Presentation given by Northwestern University at 2015 DOE Hydrogen and Fuel Cells Program and vehicle technologies office annual merit review and peer evaluation meeting about a novel lubricant...

  2. Impact of Lubricant Formulation on the Performance of NOx Adsorber Catalysts (Presentation)

    SciTech Connect (OSTI)

    Whitacre, S. D.

    2005-08-25

    Discusses the impact of lubricant formulation on the performance of oxides of nitrogen (NOx) Adsorber Catalysts, including background/motivation for study, experimental design, and results.

  3. The Impact of Lubricant on Emissions from a Medium-Duty Diesel...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Lubricant Formulation and Consumption Effects on Diesel Exhaust Ash Emissions: Fuels for Advanced CIDI Engines and Fuel Cells: 2000 Annual Progress ...

  4. Vehicle Technologies Office: 2014 Fuel and Lubricant Technologies R&D Annual Progress Report

    Broader source: Energy.gov [DOE]

    This report describes the progress made on the research and development projects funded by the Fuel and Lubricants subprogram in the Vehicle Technologies Office in 2014.

  5. Separation of Fischer-Tropsch Wax Products from Ultrafine Iron Catalyst Particles

    SciTech Connect (OSTI)

    James K. Neathery; Gary Jacobs; Amitava Sarkar; Adam Crawford; Burtron H. Davis

    2006-09-30

    In the previous reporting period, modifications were completed for integrating a continuous wax filtration system for a 4 liter slurry bubble column reactor. During the current reporting period, a shakedown of the system was completed. Several problems were encountered with the progressive cavity pump used to circulate the wax/catalyst slurry though the cross-flow filter element and reactor. During the activation of the catalyst with elevated temperature (> 270 C) the elastomer pump stator released sulfur thereby totally deactivating the iron-based catalyst. Difficulties in maintaining an acceptable leak rate from the pump seal and stator housing were also encountered. Consequently, the system leak rate exceeded the expected production rate of wax; therefore, no online filtration could be accomplished. Work continued regarding the characterization of ultra-fine catalyst structures. The effect of carbidation on the morphology of iron hydroxide oxide particles was the focus of the study during this reporting period. Oxidation of Fe (II) sulfate results in predominantly {gamma}-FeOOH particles which have a rod-shaped (nano-needles) crystalline structure. Carbidation of the prepared {gamma}-FeOOH with CO at atmospheric pressure produced iron carbides with spherical layered structure. HRTEM and EDS analysis revealed that carbidation of {gamma}-FeOOH particles changes the initial nano-needles morphology and generates ultrafine carbide particles with irregular spherical shape.

  6. Antioxidants and stabilizers for lubricants and fuels. (Latest citations from the NTIS bibliographic database). Published Search

    SciTech Connect (OSTI)

    1995-05-01

    The bibliography contains citations concerning the design, manufacture, and evaluation of antioxidants and stabilizers used in lubricants and fuels. The synthesis, stability, degradation, and storage life of lubricant and fuel additives are discussed. Additives used in jet engine, turbine, natural-gas, and coal-water fuels are examined. (Contains a minimum of 129 citations and includes a subject term index and title list.)

  7. Measurement of solubility, viscosity, and density of R-410A refrigerant/lubricant mixtures

    SciTech Connect (OSTI)

    Cavestri, R.C.; Schafer, W.R.

    2000-07-01

    Measurements of the refrigerant vapor/liquid lubricant equilibrium viscosity reduction of four polyolester lubricants, viscosity grades 32 and 68 ISO VG, with the refrigerant R-410A were taken between {minus}13 F and 257 F and up to 700 psia. A high and low miscibility grade polyolester was analyzed for each viscosity. The viscosity, density, and composition of the solubilized gas mixture in solution with the lubricant was obtained with constant gas vapor composition in the viscometer head space. This refrigerant has a very small temperature glide but is considered a zeotropic blend nonetheless. The fractionation data presented were obtained from individual isothermal measurements. The isotherm for each temperature detailed the composition of the equilibrium gas fractionation of R-32 and R-125 in the lubricant, mixed vapor pressure, concentration of the total mixed blend (percent by weight) in the lubricant, and viscosity in centipoise (cP) and centistokes (cSt).

  8. Real-time determination of lubricant concentrations dissolved in alternative refrigerants

    SciTech Connect (OSTI)

    Cavestri, R.C.; Schafer, W.R.

    1999-07-01

    A methodology was developed and used to measure both polyolester lubricant concentrations in solution with R-134a and R-407C and mineral oils in solution with R-123. This method is unaffected by changes in pressure, temperature, refrigerant type, and lubricant type. The concentration of dissolved lubricant was measured in three alternative refrigerants with two different synthetic polyolesters and two different mineral oils over a temperature range of 68 F (20 C) to 140 F (60 C) and a concentration range of 0 to 6% w/w. The evaluation methods included density, viscosity, and high-pressure liquid chromatography (HPLC). Measurements of viscosity and density were performed on an oscillating body viscometer. Lubricant concentrations determined by HPLC compared favorably with the ASHRAE Standard 41.1 method (ASHRAE 1984). Circulating lubricant, miscible and immiscible, concentration in identical R-407C operating systems was also measured to demonstrate the practical application of the test method.

  9. On-Line Measurement of Lubricant Film Thickness Using Ultrasonic Reflection Coefficients

    SciTech Connect (OSTI)

    Drinkwater, B.W.; Dwyer-Joyce, R.S.; Harper, P.

    2004-02-26

    The ultrasonic reflectivity of a lubricant layer between two solid bodies depends on the ultrasonic frequency, the acoustic properties of the liquid and solid, and the layer thickness. In this paper, ultrasonic reflectivity measurements are used as a method for determining the thickness of lubricating films in bearing systems. An ultrasonic transducer is positioned on the outside of a bearing shell such that the wave is focused on the lubricant film layer. For a particular lubricant film the reflected pulse is processed to give a reflection coefficient spectrum. The lubricant film thickness is then obtained from either the layer stiffness or the resonant frequency. The method has been validated using static fluid wedges and the elastohydrodynamic film formed between a ball sliding on a flat. Film thickness values in the range 50-500 nm were recorded which agreed well with theoretical film formation predictions.

  10. Fabrics coated with lubricated nanostructures display robust omniphobicity

    SciTech Connect (OSTI)

    Shillingford, Cicely; MacCallum, Noah; Wong, Tak -Sing; Kim, Philseok; Aizenberg, Joanna

    2013-12-11

    The development of a stain-resistant and pressure-stable textile is desirable for consumer and industrial applications alike, yet it remains a challenge that current technologies have been unable to fully address. Traditional superhydrophobic surfaces, inspired by the lotus plant, are characterized by two main components: hydrophobic chemical functionalization and surface roughness. While this approach produces water-resistant surfaces, these materials have critical weaknesses that hinder their practical utility, in particular as robust stain-free fabrics. For example, traditional superhydrophobic surfaces fail (i.e., become stained) when exposed to low-surface-tension liquids, under pressure when impacted by a high-velocity stream of water (e.g., rain), and when exposed to physical forces such as abrasion and twisting. We have recently introduced slippery lubricant-infused porous surfaces (SLIPS), a self-healing, pressure-tolerant and omniphobic surface, to address these issues. However we present the rational design and optimization of nanostructured lubricant-infused fabrics and demonstrate markedly improved performance over traditional superhydrophobic textile treatments: SLIPS-functionalized cotton and polyester fabrics exhibit decreased contact angle hysteresis and sliding angles, omni-repellent properties against various fluids including polar and nonpolar liquids, pressure tolerance and mechanical robustness, all of which are not readily achievable with the state-of-the-art superhydrophobic coatings.

  11. Fabrics coated with lubricated nanostructures display robust omniphobicity

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Shillingford, Cicely; MacCallum, Noah; Wong, Tak -Sing; Kim, Philseok; Aizenberg, Joanna

    2013-12-11

    The development of a stain-resistant and pressure-stable textile is desirable for consumer and industrial applications alike, yet it remains a challenge that current technologies have been unable to fully address. Traditional superhydrophobic surfaces, inspired by the lotus plant, are characterized by two main components: hydrophobic chemical functionalization and surface roughness. While this approach produces water-resistant surfaces, these materials have critical weaknesses that hinder their practical utility, in particular as robust stain-free fabrics. For example, traditional superhydrophobic surfaces fail (i.e., become stained) when exposed to low-surface-tension liquids, under pressure when impacted by a high-velocity stream of water (e.g., rain), and whenmore » exposed to physical forces such as abrasion and twisting. We have recently introduced slippery lubricant-infused porous surfaces (SLIPS), a self-healing, pressure-tolerant and omniphobic surface, to address these issues. However we present the rational design and optimization of nanostructured lubricant-infused fabrics and demonstrate markedly improved performance over traditional superhydrophobic textile treatments: SLIPS-functionalized cotton and polyester fabrics exhibit decreased contact angle hysteresis and sliding angles, omni-repellent properties against various fluids including polar and nonpolar liquids, pressure tolerance and mechanical robustness, all of which are not readily achievable with the state-of-the-art superhydrophobic coatings.« less

  12. Fabrics coated with lubricated nanostructures display robust omniphobicity

    SciTech Connect (OSTI)

    Shillingford, C; MacCallum, N; Wong, TS; Kim, P; Aizenberg, J

    2013-12-11

    The development of a stain-resistant and pressure-stable textile is desirable for consumer and industrial applications alike, yet it remains a challenge that current technologies have been unable to fully address. Traditional superhydrophobic surfaces, inspired by the lotus plant, are characterized by two main components: hydrophobic chemical functionalization and surface roughness. While this approach produces water-resistant surfaces, these materials have critical weaknesses that hinder their practical utility, in particular as robust stain-free fabrics. For example, traditional superhydrophobic surfaces fail (i.e., become stained) when exposed to low-surface-tension liquids, under pressure when impacted by a high-velocity stream of water (e. g., rain), and when exposed to physical forces such as abrasion and twisting. We have recently introduced slippery lubricant-infused porous surfaces (SLIPS), a self-healing, pressure-tolerant and omniphobic surface, to address these issues. Herein we present the rational design and optimization of nanostructured lubricant-infused fabrics and demonstrate markedly improved performance over traditional superhydrophobic textile treatments: SLIPS-functionalized cotton and polyester fabrics exhibit decreased contact angle hysteresis and sliding angles, omni-repellent properties against various fluids including polar and nonpolar liquids, pressure tolerance and mechanical robustness, all of which are not readily achievable with the state-of-the-art superhydrophobic coatings.

  13. Renewable Fuels and Lubricants (ReFUEL) Laboratory (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2012-03-01

    This fact sheet describes the Renewable Fuels and Lubricants (ReFUEL) Laboratory at the U.S. Department of Energy National Renewable Energy Laboratory (NREL) is a state-of-the-art research and testing facility for advanced fuels and vehicles. Research and development aims to improve vehicle efficiency and overcome barriers to the increased use of renewable diesel and other nonpetroleum-based fuels, such as biodiesel and synthetic diesel derived from biomass. The ReFUEL Laboratory features a chassis dynamometer for vehicle performance and emissions research, two engine dynamometer test cells for advanced fuels research, and precise emissions analysis equipment. As a complement to these capabilities, detailed studies of fuel properties, with a focus on ignition quality, are performed at NREL's Fuel Chemistry Laboratory.

  14. System for lubrication of a brake air compressor associated with a turbocharged internal combustion engine

    SciTech Connect (OSTI)

    Spencer, J.C.

    1992-10-13

    This patent describes a system for use with a vehicle which includes a turbocharged internal combustion engine having a lubricating system wherein lubricating oil from an engine oil reservoir is circulated within the engine and also to and from an associated brake system air compressor which supplies compressed air for operation of the vehicle air braking system. This patent describes improvement in passing supercharged air to an oil crankcase of the air compressor to cause lubricating oil to drain therefrom and return to the engine oil reservoir.

  15. Low severity upgrading of F-T waxes with solid superacids. Quarterly report

    SciTech Connect (OSTI)

    Tierney, J.W.; Wender, I.

    1992-12-31

    To avoid methane production in F-T synthesis on Fe catalysts, efforts are being made on conversion of synthesis gas to high molecular weight hydrocarbons, such as waxes. Strong acidity of sulfated zirconium oxides, ZrO{sub 2}/SO{sub 4}, is being used to pretreat long-chain paraffins with carbon numbers greater than n-C{sub 32}. Progress during this period is reported on reactivity of Pt/ZrO{sub 2}/SO{sub 4} for hydrocracking n-C{sub 32} and on effects of hydride donor solvent on hydrocracking of n-C{sub 32}. 5 figs.

  16. Low severity upgrading of F-T waxes with solid superacids

    SciTech Connect (OSTI)

    Tierney, J.W.; Wender, I.

    1992-01-01

    To avoid methane production in F-T synthesis on Fe catalysts, efforts are being made on conversion of synthesis gas to high molecular weight hydrocarbons, such as waxes. Strong acidity of sulfated zirconium oxides, ZrO[sub 2]/SO[sub 4], is being used to pretreat long-chain paraffins with carbon numbers greater than n-C[sub 32]. Progress during this period is reported on reactivity of Pt/ZrO[sub 2]/SO[sub 4] for hydrocracking n-C[sub 32] and on effects of hydride donor solvent on hydrocracking of n-C[sub 32]. 5 figs.

  17. Low severity upgrading of F-T waxes with solid superacids. Final report

    SciTech Connect (OSTI)

    Wender, I.; Tierney, J.W.

    1995-09-30

    The use of solid acids, especially Pt/ZrO{sub 2}/SO{sub 4}, to convert long chain alkanes and Fischer-Tropsch waxes to liquid fuels under mild reaction conditions was explored in this work. Anion and/or hydrogenation metal modified zirconium oxides were synthesized, characterized, and tested for hydrocracking and hydroisomerization. of model compounds, chiefly with n-hexadecane. The relationship between catalytic activity and acidic character of the bifunctional Pt/ZrO{sub 2}/SO{sub 4} catalyst was investigated.

  18. Lubrication of polysilicon micromechanisms with self-assembled monolayers

    SciTech Connect (OSTI)

    Srinivasan, U.; Foster, J.D.; Habib, U.; Howe, R.T.; Maboudian, R.; Senft, D.C.; Dugger, M.T.

    1998-06-01

    Here, the authors report on the lubricating effects of self-assembled monolayers (SAMs) on MEMS by measuring static and dynamic friction with two polysilicon surface- micromachined devices. The first test structure is used to study friction between laterally sliding surfaces and with the second, friction between vertical sidewalls can be investigated. Both devices are SAM-coated following the sacrificial oxide etch and the microstructures emerge released and dry from the final water rinse. The coefficient of static friction, {mu}{sub s} was found to decrease from 2.1 {+-} 0.8 for the SiO{sub 2} coating to 0.11 {+-} 0.01 and 0.10 {+-} 0.01 for films derived from octadecyltrichloro-silane (OTS) and 1H,1H,2H,2H-perfluorodecyl-trichlorosilane (FDTS). Both OTS and FDTS SAM-coated structures exhibit dynamic coefficients of friction, {mu}{sub d} of 0.08 {+-} 0.01. These values were found to be independent of the apparent contact area, and remain unchanged after 1 million impacts at 5.6 {micro}N (17 kPa), indicating that these SAMs continue to act as boundary lubricants despite repeated impacts. Measurements during sliding friction from the sidewall friction testing structure give comparable initial {mu}{sub d} values of 0.02 at a contact pressure of 84 MPa. After 15 million wear cycles, {mu}{sub d} was found to rise to 0.27. Wear of the contacting surfaces was examined by SEM. Standard deviations in the {mu} data for SAM treatments indicate uniform coating coverage.

  19. Development of high temperature solid lubricant coatings. Final report, 15 August 1997--14 August 1998

    SciTech Connect (OSTI)

    Bhattacharya, R.S.; Keller, S.

    1999-01-29

    The primary research objective of this work was to develop a solid lubricant coating that can function over a broad temperature range. The approach investigated consisted of developing adaptive lubricant coating from materials that undergo chemical change with increasing temperature by reacting together and with the environment. To test this approach, UES and Cleveland State University have conducted experiments to form cesium oxythiotungstate, a high temperature lubricant, on Inconel 718 surface from composite coatings of cesium tungstate and tungsten sulfide. The coatings were deposited by RF sputtering and characterized by X-ray Photoelectron Spectroscopy (XPS). The results indicate that sulfur escapes from the composite coating upon exposure to temperature above 5000C in air. Thus, the desired adaptive lubricant phase, cesium oxythiotungstate could not be formed. However, cesium oxythiotungstate phase has been found to form upon annealing at high temperature in vacuum. The friction coefficients of sputtered cesium oxythiotungstate and cesium tungstate coatings have been measured.

  20. Compatibility of refrigerants and lubricants with electrical sheet insulation under retrofit conditions

    SciTech Connect (OSTI)

    Doerr, R.G.; Waite, T.D.

    1996-11-01

    To determine whether exposure to the original refrigerant/mineral oil would affect compatibility of sheet insulation with alternative refrigerant/lubricant after retrofit, sheet insulation was exposed at elevated temperature to the original refrigerant and mineral oil for 500 hours, followed by exposure to the alternative refrigerant and lubricant for 500 hours. Most of the sheet insulation materials exposed to the alternative refrigerant and lubricant (after an initial exposure to the original refrigerant and mineral oil) appeared to be compatible with the alternative refrigerant and lubricant. The only concern was delamination and blistering of the sheet insulation containing Nomex, especially after removal of absorbed refrigerant at high temperature. This was attributed to incompatibility of the adhesive and not to the Nomex itself. Embrittlement of the polyethylene terephthalate (PET) sheet was initially observed, but 2048 subsequent tests under extremely dry conditions showed that embrittlement of the PET materials was attributed to moisture present during the exposure.

  1. High temperature solid lubricant materials for heavy duty and advanced heat engines

    SciTech Connect (OSTI)

    DellaCorte, C.; Wood, J.C.

    1994-10-01

    Advanced engine designs incorporate higher mechanical and thermal loading to achieve efficiency improvements. This approach often leads to higher operating temperatures of critical sliding elements (e.g. piston ring/cylinder wall contacts and valve guides) which compromise the use of conventional and even advanced synthetic liquid lubricants. For these applications solid lubricants must be considered. Several novel solid lubricant composites and coatings designated PS/PM200 have been employed to dry and marginally oil lubricated contacts in advanced heat engines. These applications include cylinder kits of heavy duty diesels, and high temperature sterling engines, sidewall seals of rotary engines and various exhaust valve and exhaust component applications. The following paper describes the tribological and thermophysical properties of these tribomaterials and reviews the results of applying them to engine applications. Other potential tribological materials and applications are also discussed with particular emphasis to heavy duty and advanced heat engines.

  2. SEPARATION OF FISCHER-TROPSCH WAX FROM CATALYST BY SUPERCRITICAL EXTRACTION

    SciTech Connect (OSTI)

    Patrick C. Joyce; Mark C. Thies

    1999-03-31

    The objective of this research project was to evaluate the potential of supercritical fluid (SCF) extraction for the recovery and fractionation of the wax product from the slurry bubble column (SBC) reactor of the Fischer-Tropsch (F-T) process. The wax, comprised mostly of branched and linear alkanes with a broad molecular weight distribution up to C{sub 100}, is to be extracted with a hydrocarbon solvent that has a critical temperature near the operating temperature of the SBC reactor, i.e., 200-300 C. Aspen Plus{trademark} was used to perform process simulation studies on the proposed extraction process, with Redlich-Kwong-Soave (RKS) being used for the thermodynamic property model. In summary, we have made comprehensive VLE measurements for short alkane + long alkane systems over a wide range of pressures and temperatures, dramatically increasing the amount of high-quality data available for these simple, yet highly relevant systems. In addition, our work has demonstrated that, surprisingly, no current thermodynamic model can adequately predict VLE behavior for these systems. Thus, process simulations (such as those for our proposed SCF extraction process) that incorporate these systems can currently only give results that are qualitative at best. Although significant progress has been made in the past decade, more experimental and theoretical work remain to be done before the phase equilibria of asymmetric alkane mixtures can be predicted with confidence.

  3. Separation of Fischer-Tropsch Wax Products from Ultrafine Iron Catalyst Particles

    SciTech Connect (OSTI)

    James K. Neathery; Gary Jacobs; Amitava Sarkar; Burtron H. Davis

    2006-03-31

    The morphological and chemical nature of ultrafine iron catalyst particles (3-5 nm diameters) during activation/FTS was studied by HRTEM, EELS, and Moessbauer spectroscopy. With the progress of FTS, the carbide re-oxidized to magnetite and catalyst activity gradually decreased. The growth of oxide phase continued and average particle size also increased simultaneously. The phase transformation occurred in a ''growing oxide core'' manner with different nano-zones. The nano-range carbide particles did not show fragmentation or attrition as generally observed in micrometer range particles. Nevertheless, when the dimension of particles reached the micrometer range, the crystalline carbide phase appeared to be sprouted on the surface of magnetite single crystal. In the previous reporting period, a design and operating philosophy was developed for an integrated wax filtration system for a 4 liter slurry bubble column reactor to be used in Phase II of this research program. During the current reporting period, we have started construction of the new filtration system and began modifications to the 4 liter slurry bubble column reactor (SBCR) reactor. The system will utilize a primary wax separation device followed by a Pall Accusep or Membralox ceramic cross-flow membrane. As of this writing, the unit is nearly complete except for the modification of a moyno-type pump; the pump was shipped to the manufacturer to install a special leak-free, high pressure seal.

  4. Renewable Fuels and Lubricants Laboratory (Fact Sheet), NREL (National Renewable Energy Laboratory)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Renewable Fuels and Lubricants Laboratory State-of-the-Art Fuel and Vehicle Testing The Renewable Fuels and Lubricants (ReFUEL) Laboratory at the U.S. Department of Energy's National Renewable Energy Laboratory (NREL) is a state-of-the-art research and testing facility for advanced fuels and vehicles. Research and development aims to improve efficiency of conventional gasoline-powered vehicles and overcome barriers to the increased use of renewable diesel and other nonpetroleum-based fuels, such

  5. Detailed Characterization of Lubricant-Derived Ash-Related Species in

    Broader source: Energy.gov (indexed) [DOE]

    Diesel Exhaust and Aftertreatment Systems | Department of Energy Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and Fuel Partnership and 21st Century Truck Programs. PDF icon 2006_deer_sappok.pdf More Documents & Publications Lubricant Formulation and Consumption Effects on Diesel Exhaust Ash Emissions: Correlations Between Metallic Lubricant Additive Species in the Ring Pack and Ash Emissions and Their Dependence on

  6. Ionic Liquids as Novel Lubricants and Additives for Diesel Engine Applications

    SciTech Connect (OSTI)

    Qu, Jun; Blau, Peter Julian; Dai, Sheng; Luo, Huimin; Meyer III, Harry M

    2009-01-01

    The lubricating properties of two ionic liquids with the same anion but different cations, one ammonium IL [C8H17]3NH.Tf2N and one imidazolium IL C10mim.Tf2N, were evaluated both in neat form and as oil additives. Experiments were conducted using a standardized reciprocating sliding test using a segment of a Cr-plated diesel engine piston ring against a grey cast iron flat specimen with simulated honing marks as on the engine cylinder liner. The selected ionic liquids were benchmarked against conventional hydrocarbon oils. Substantial friction and wear reductions, up to 55% and 34%, respectively, were achieved for the neat ionic liquids compared to a fully-formulated 15W40 engine oil. Adding 5 vol% ILs into mineral oil has demonstrated significant improvement in the lubricity. One blend even outperformed the 15W40 engine oil with 9% lower friction and 34% less wear. Lubrication regime modeling, worn surface morphology examination, and surface chemical analysis were conducted to help understand the lubricating mechanisms for ionic liquids. Results suggest great potential for using ionic liquids as base lubricants or lubricant additives for diesel engine applications.

  7. Thermal reactivity of mixtures of VDDT lubricant and simulated Hanford Tank 241-SY-101 waste

    SciTech Connect (OSTI)

    Scheele, R.D.; Panisko, F.E.; Sell, R.L.

    1996-09-01

    To predict whether the Polywater G lubricant residue remaining in the velocity, density, and temperature tree (VDTT) and the waste in Tank 241-SY-101 (101SY) will be chemically compatible with wastes in 101SY when two VDTTs are removed from 101SY, the Pacific Northwest National Laboratory measured the thermal reaction sensitivity of the lubricant residue. This residue is a simulated 101SY waste containing the organic surrogate trisodium hydroxyethyl-ethylenediaminetriacetate (Na{sub 3}HEDTA) and two simulated potential waste and lubricant residue mixtures containing 10 and 90 percent lubricant residue. These studies using accelerating rate calorimetry found that the residue did not react at a rate exceeding 0.1 J/min/g mixture up to 190 degrees C with simulated 101SY waste containing Na{sub 3}HEDTA as the organic surrogate. Also, the dried lubricant residue did not decompose exothermically at a rate exceeding 0.1 J/min/g. Using guidelines used by the chemical industry, these results indicate that the lubricant residue should not react as a significant rate with the waste in 101SY when added to the waste at 60 degrees C or when the mixture cools to the waste`s temperature of 48 degrees C.

  8. Aging model for solid lubricants used in weapon stronglinks: tribological performance and hardware review

    SciTech Connect (OSTI)

    Dugger, M.T.; Peebles, D.E.; Sorroche, E.H.; Varga, K.S.; Bryan, R.M.

    1997-09-01

    The solid lubricant used most extensively in strong links throughout the enduring stockpile contains MoS{sub 2}, which is known to react with oxygen and water vapor resulting in a change in the material`s friction and wear behavior. The authors have examined the frictional behavior of this lubricant as a function of oxidation, in support of efforts to quantify the impact of changes in the material on the dynamic behavior of the MC2969 strong link. Their results show that the friction response of oxidized lubricant is strongly influenced by the amount of burnishing performed on the lubricant after deposition. Low levels of burnish leave a thick film, of which only the near surface degrades during oxidation. Rapid wear of the oxidized material leaves a surface whose properties are the same as non-oxidized material. Higher levels of burnish leave a thinner film of lubricant such that the entire film may be oxidized. The friction coefficient on this surface reaches a steady state value greater than that of non oxidized material. In addition to these fundamental differences in steady state behavior, they have shown that the initial friction coefficient on oxidized surfaces is related to the amount of sulfide converted to sulfate, regardless of the oxidation conditions used. Measurements on parts returned from the stockpile show that the friction behavior of aged hardware is consistent with the behavior observed on controlled substrates containing thin lubricant films.

  9. Laser-induced short time scale thermal chemistry of perfluoropolyether lubricant films

    SciTech Connect (OSTI)

    Heller, J.; Mate, C.J.; Poon, C.C.; Tam, A.C.

    1999-11-09

    The authors investigate the effect of heating a perfluoropolyether lubricant film in a localized area for relatively short time periods using laser irradiation versus conventional oven heating. These experiments help provide understanding on how flash temperatures generated at frictional contacts affect the thermal chemistry of lubricant films. In these experiments, a CO{sub 2} laser heats a 50 {micro}m wide area of a silicon wafer for time periods ranging from 0.1 to 60 s. The surface temperature within the heated area (up to 280 C in these experiments) is monitored with a second laser by measuring the change in reflectivity near the center of the heated area. A major difference observed for laser heating compared to oven heating is that the effective evaporation rate is orders of magnitude higher for laser heating. If the lubricant film is heated for sufficiently long enough time at high temperatures, the authors are able to observe thermal bonding of the lubricant via its alcohol end groups to the silicon oxide surface, followed by thermal decomposition of the lubricant molecules. After laser heating, the authors are able to observe the diffusion of lubricant back into the localized heated area using a combination of optical microscopy and imaging ellipsometry.

  10. Advanced Petroleum-Based Fuels--Diesel Emissions Control Project (APBF-DEC): Lubricants Project, Phase 1 Summary, July 2004

    SciTech Connect (OSTI)

    Not Available

    2004-07-01

    The Advanced Petroleum Based Fuels-Diesel Emission Control project is a government/industry collaborative project to identify the optimal combinations of low-sulfur diesel fuels, lubricants, diesel engines, and emission control systems to meet projected emission standards for the 2004-2010 time period. This summary describes the results of the first phase of the lubricants study investigating the impact on lubricant formulation on engine-out emissions.

  11. Friction of different monolayer lubricants in MEMs interfaces.

    SciTech Connect (OSTI)

    Carpick, Robert W. (University of Wisconsin, Madison, WI); Street, Mark D.; Ashurst, William Robert; Corwin, Alex David

    2006-01-01

    This report details results from our last year of work (FY2005) on friction in MEMS as funded by the Campaign 6 program for the Microscale Friction project. We have applied different monolayers to a sensitive MEMS friction tester called the nanotractor. The nanotractor is also a useful actuator that can travel {+-}100 {micro}m in 40 nm steps, and is being considered for several MEMS applications. With this tester, we can find static and dynamic coefficients of friction. We can also quantify deviations from Amontons' and Coulomb's friction laws. Because of the huge surface-to-volume ratio at the microscale, surface properties such as adhesion and friction can dominate device performance, and therefore such deviations are important to quantify and understand. We find that static and dynamic friction depend on the monolayer lubricant applied. The friction data can be modeled with a non-zero adhesion force, which represents a deviation from Amontons' Law. Further, we show preliminary data indicating that the adhesion force depends not only on the monolayer, but also on the normal load applied. Finally, we also observe slip deflections before the transition from static to dynamic friction, and find that they depend on the monolayer.

  12. Separation of Fischer-Tropsch Wax Products from Ultrafine Iron Catalyst Particles

    SciTech Connect (OSTI)

    James K. Neathery; Gary Jacobs; Amitava Sarkar; Burtron H. Davis

    2005-09-30

    In this reporting period, a study of ultra-fine iron catalyst filtration was initiated to study the behavior of ultra-fine particles during the separation of Fischer-Tropsch Synthesis (FTS) liquids filtration. The overall focus of the program is with slurry-phase FTS in slurry bubble column reactor systems. Hydrocarbon products must be separated from catalyst particles before being removed from the reactor system. An efficient wax product/catalyst separation system is a key factor for optimizing operating costs for iron-based slurry-phase FTS. Previous work has focused on catalyst particle attrition and the formation of ultra-fine iron carbide and/or carbon particles. With the current study, we are investigating how the filtration properties are affected by these chemical and physical changes of the catalyst slurry during activation/synthesis. The change of particle size during the slurry-phase FTS has monitored by withdrawing catalyst sample at different TOS. The measurement of dimension of the HRTEM images of samples showed a tremendous growth of the particles. Carbon rims of thickness 3-6 nm around the particles were observed. This growth in particle size was not due to carbon deposition on the catalyst. A conceptual design and operating philosophy was developed for an integrated wax filtration system for a 4 liter slurry bubble column reactor to be used in Phase II of this research program. The system will utilize a primary inertial hydroclone followed by a Pall Accusep cross-flow membrane. Provisions for cleaned permeate back-pulsing will be included to as a flux maintenance measure.

  13. MIL-L-87177 and CLT:X-10 Lubricants Improve Electrical Connector Fretting Corrosion Behavior

    SciTech Connect (OSTI)

    AUKLAND,NEIL R.; HANLON,JAMES T.

    1999-10-12

    We have conducted a fretting research project using MIL-L-87177 and CLT: X-10 lubricants on Nano-miniature connectors. When they were fretted without lubricant, individual connectors first exceeded our 0.5 ohm failure criteria from 2,341 to 45,238 fretting cycles. With additional fretting, their contact resistance increased to more than 100,000 ohms. Unmodified MIL-L-87177 lubricant delayed the onset of first failure to between 430,000 and over 20,000,000 fretting cycles. MIL-L-87177 modified by addition of Teflon powder delayed first failure to beyond 5 million fretting cycles. Best results were obtained when Teflon was used and also when both the straight and modified lubricants were poured into and then out of the connector. CLT: X-10 lubricant delayed the onset of first failure to beyond 55 million cycles in one test where a failure was actually observed and to beyond 20 million cycles in another that was terminated without failure. CLT: X-10 recovered an unlubricated connector driven deeply into failure, with six failed pins recovering immediately and four more recovering during an additional 420 thousand fretting cycles. MIL-L-87177 was not able to recover a connector under similar conditions.

  14. Compatibility of refrigerants and lubricants with motor materials under retrofit conditions

    SciTech Connect (OSTI)

    Doerr, R.; Waite, T.

    1995-01-12

    Motor materials were exposed to original refrigerants R-11, R-12, R-22 and R-502 in the presence of mineral oil for 500 hours. These same materials were then exposed to alternative refrigerants R-123, R-134a, R-407C (R-32/R-125/R-134a) and R-404A (R-125/R-143a/R-134a), respectively, in the presence of the appropriate lubricant for 500 hours. As a control, some samples were exposed to the original refrigerant/mineral oil for a total of 1,000 hours. These tests were conducted to determine whether exposure to the original refrigerant/mineral oil would affect compatibility of the motor materials with the alternative refrigerant/lubricant after retrofit. Motor materials exposed to the alternative refrigerant and lubricant (after an initial exposure to the original refrigerant and mineral oil) appeared to be compatible with the alternative refrigerant and lubricant. The only concerns were embrittlement of the polyethylene terephthalate (PET) sheet and sleeving insulations, and delamination and blistering of the Nomex sheet insulation in the R-22, R-502, and R-12. Embrittlement of the PET materials was attributed to moisture present during the exposure. Separation of the 475 varnish from metal surfaces in the R-123 was also a concern. The sheet and sleeving insulations were affected by the original refrigerant/mineral oil to a greater extent than by the alternative refrigerant and lubricant.

  15. Compatibility of manufacturing process fluids with R-134a and polyolester lubricant. Final report

    SciTech Connect (OSTI)

    Cavestri, R.C.; Schooley, D.L.

    1996-07-01

    This report includes a broad list of processing fluids that are known to be used to manufacture air conditioning and refrigeration products. Sixty-four process fluids from this list were selected for compatibility studies with R-134a and ICI EMKARATE RL32H (32 ISO) polyolester lubricant. Solutions or suspensions of the process fluid residues in polyolester lubricant were heated for 14 days at 175{degrees}C (347{degrees}F) in evacuated sealed glass tubes containing only valve steel coupons. Miscibility tests were performed at 90 wt.% R-134a, 10 wt.% polyolester lubricant with process fluid residue contaminate and were scanned in 10{degrees}C (18{degrees}F) increments over a temperature range of ambient to -40{degrees}C (-40{degrees}F). Any sign of turbidity, haze formation or oil separation was considered the immiscibility point.

  16. Identification of tribological research and development needs for lubrication of advanced heat engines

    SciTech Connect (OSTI)

    Fehrenbacher, L.L.; Levinson, T.M.

    1985-09-01

    The continuous evolution of higher power density propulsion systems has always fueled the search for materials and lubricants with improved thermal and/or durability characteristics. Tribology of the upper cylinder region is the major technology roadblock in the path of the adiabatic diesel engine which has an energy reduction potential that exceeds that of all other engine development types. This tribology assessment resulted in the following major conclusions: a low friction and a low wear seal between the ring belt and cylinder bore are the most critical tribology functions in the diesel combustion chamber; development of solid lubrication systems will not satisfy the simultaneous low friction and low wear requirements in the upper cylinder area; development of separate upper cylinder liquid lubrication systems offers the most attractive design alternative for meeting the operational goals of future ''minimum cooled'' diesel engines.

  17. Testing of nuclear grade lubricants and their effects on A540 B24 and A193 B7 bolting materials

    SciTech Connect (OSTI)

    Czajkowski, C.J.

    1985-01-01

    An investigation was performed on eleven commonly used lubricants by the nuclear power industry. The investigation included EDS analysis of the lubricants, notched-tensile constant extension rate testing of bolting materials with the lubricants, frictional testing of the lubricants and weight loss testing of a bonded solid film lubricant. The report generally concludes that there is a significant amount of variance in the mechanical properties of common bolting materials; that MoS/sub 2/ can hydrolyze to form H/sub 2/S at 100/sup 0/C and cause stress corrosion cracking (SCC) of bolting materials, and that the use of copper-containing lubricants can be potentially detrimental to high strength steels in an aqueous environment. Additionally, the testing of various lubricants disclosed that some lubricants contain potentially detrimental elements (e.g. S, Sb) which can promote SCC of the common bolting materials. One of the most significant findings of this report is the observation that both A193 B7 and A540 B24 bolting materials are susceptible to transgranular stress corrosion cracking in demineralized H/sub 2/O at 280/sup 0/C in notched tensile tests.

  18. Accelerated screening methods for determining chemical and thermal stability of refrigerant-lubricant mixtures, Part II: Experimental comparison and verification of methods. Volume 2, In situ conductivity data

    SciTech Connect (OSTI)

    Kauffman, R.

    1995-09-01

    Data are presented for the accelerated screening methods for determining chemical and thermal stability of refrigerant-lubricant mixtures.

  19. Effects of temperature on desiccant catalysis of refrigerant and lubricant decomposition. Final report

    SciTech Connect (OSTI)

    Rohatgi, N.D.T.

    1998-06-01

    Accelerated aging at high temperatures (149 C) for short aging times (28 days) is effective in screening the compatibility of different materials in refrigeration systems. However, in actual applications temperatures are usually lower and operating times much longer. Therefore plots to allow for interpolation or extrapolation of experimental data to actual operating conditions are needed. In the current study, aging of refrigerant/lubricant/desiccant/metal systems was conducted at five different temperatures, and for each temperature at four different aging times. The data collected from this study provided plots relating refrigerant or lubricant decomposition to aging time, aging temperature, and type of desiccant, which can be used for interpolation or extrapolation.

  20. In situ measurement of the bonded film thickness of Z-Tetraol lubricant on magnetic recording media

    SciTech Connect (OSTI)

    Zhu Lei; Li Feng

    2010-10-15

    Currently, the bonded film thickness of perfluoropolyether lubricant on top of magnetic recording media is measured by a two-step process. First, the media disk has to be rinsed thoroughly using a fluorocarbon solvent (for instance, Vetrel) to remove the mobile lubricant. Second, the thickness of the remaining lubricant on the media surface which is regarded as the bonded lubricant thickness is then measured either by Fourier transform infrared spectroscopy (FTIR) or electron spectroscopy for chemical analysis. As the total lubricant thickness approaches single molecular dimension ({approx}10 A), current methods face tremendous challenge on the accuracy and sensitivity of the measurement. We studied the spectral characteristics responding to the lubricant bonding with the carbon overcoat by the time-of-flight secondary ion mass spectra and proposed to use the peak area ratio (C{sub 3}H{sub 2}F/C{sub 3}H{sub 5}O and C{sub 4}H{sub 10}O/C{sub 3}H{sub 6}O{sub 2}) to characterize the bonded Z-Tetraol lubricant that produces a direct bonded lubricant thickness measurement without the need to remove the mobile lubricant with a solvent. After taking the background signal of disks prior to bonding by UV irradiation into account, this method becomes independent of the total lubricant thickness as well as shows good correlation linearity (R{sup 2{approx}}87%) with the current FTIR method for the ratio of C{sub 4}H{sub 10}O/C{sub 3}H{sub 6}O{sub 2}.

  1. Simultaneous wireline operations from a floating rig with a subsea lubricator

    SciTech Connect (OSTI)

    Hopper, C.T. )

    1990-08-01

    In 1987, and extensive wireline program was completed on two subsea wells in the highlander field in the central North Sea with a subsea lubricator deployed from a drilling rig that was drilling and working over adjacent wells. This paper reports how working on two wells concurrently is a way to reduce the operating costs of a subsea development significantly.

  2. Gas-lubricated seal for sealing between a piston and a cylinder wall

    DOE Patents [OSTI]

    Hoult, David P.

    1985-01-01

    A piston-cylinder seal uses gas for a lubricant and has a runner supported on a gapless structure and placed in the space between the piston and the cylinder wall. The runner is deformed elastically under the influence of the operating pressures to follow and compensate for variations in the piston-cylinder fit and maintain a seal.

  3. Gas-lubricated seal for sealing between a piston and a cylinder wall

    DOE Patents [OSTI]

    Hoult, D.P.

    1985-09-10

    A piston-cylinder seal uses gas for a lubricant and has a runner supported on a gapless structure and placed in the space between the piston and the cylinder wall. The runner is deformed elastically under the influence of the operating pressures to follow and compensate for variations in the piston-cylinder fit and maintain a seal. 4 figs.

  4. Engine having a high pressure hydraulic system and low pressure lubricating system

    DOE Patents [OSTI]

    Bartley, Bradley E.; Blass, James R.; Gibson, Dennis H.

    2000-01-01

    An engine includes a high pressure hydraulic system having a high pressure pump and at least one hydraulically-actuated device attached to an engine housing. A low pressure engine lubricating system is attached to the engine housing and includes a circulation conduit fluidly connected to an outlet from the high pressure pump.

  5. Collaborative Lubricating Oil Study on Emissions: November 28, 2006 - March 31, 2011

    SciTech Connect (OSTI)

    Carroll, J. N.; Khalek, I. A.; Smith, L. R.; Fujita, E.; Zielinska, B.

    2011-10-01

    The Collaborative Lubricating Oil Study on Emissions (CLOSE) project was a pilot investigation of how fuels and crankcase lubricants contribute to the formation of particulate matter (PM) and semi-volatile organic compounds (SVOC) in vehicle exhaust. As limited vehicles were tested, results are not representative of the whole on-road fleet. Long-term effects were not investigated. Pairs of vehicles (one normal PM emitting, one high-PM emitting) from four categories were selected: light-duty (LD) gasoline cars, medium-duty (MD) diesel trucks, heavy-duty (HD) natural-gas-fueled buses, and HD diesel buses. HD vehicles procured did not exhibit higher PM emissions, and thus were labeled high mileage (HM). Fuels evaluated were non-ethanol gasoline (E0), 10 percent ethanol (E10), conventional low-sulfur TxLED diesel, 20% biodiesel (B20), and natural gas. Temperature effects (20 degrees F, 72 degrees F) were evaluated on LD and MD vehicles. Lubricating oil vintage effects (fresh and aged) were evaluated on all vehicles. LD and MD vehicles were operated on a dynamometer over the California Unified Driving Cycle, while HD vehicles followed the Heavy Duty Urban Dynamometer Driving Schedule. Regulated and unregulated emissions were measured. Chemical markers from the unregulated emissions measurements and a tracer were utilized to estimate the lubricant contribution to PM.

  6. MEMS Lubrication by In-Situ Tribochemical Reactions From the Vapor Phase.

    SciTech Connect (OSTI)

    Dugger, Michael T.; Asay, David B.; Kim, Seong H.

    2008-01-01

    Vapor Phase Lubrication (VPL) of silicon surfaces with pentanol has been demonstrated. Two potential show stoppers with respect to application of this approach to real MEMS devices have been investigated. Water vapor was found to reduce the effectiveness of VPL with alcohol for a given alcohol concentration, but the basic reaction mechanism observed in water-free environments is still active, and devices operated much longer in mixed alcohol and water vapor environments than with chemisorbed monolayer lubricants alone. Complex MEMS gear trains were successfully lubricated with alcohol vapors, resulting in a factor of 104 improvement in operating life without failure. Complex devices could be made to fail if operated at much higher frequencies than previously used, and there is some evidence that the observed failure is due to accumulation of reaction products at deeply buried interfaces. However, if hypothetical reaction mechanisms involving heated surfaces are valid, then the failures observed at high frequency may not be relevant to operation at normal frequencies. Therefore, this work demonstrates that VPL is a viable approach for complex MEMS devices in conventional packages. Further study of the VPL reaction mechanisms are recommended so that the vapor composition may be optimized for low friction and for different substrate materials with potential application to conventionally fabricated, metal alloy parts in weapons systems. Reaction kinetics should be studied to define effective lubrication regimes as a function of the partial pressure of the vapor phase constituent, interfacial shear rate, substrate composition, and temperature.

  7. Novel pathways for fuels and lubricants from biomass optimized using life-cycle greenhouse gas assessment

    SciTech Connect (OSTI)

    Balakrishnan, Madhesan; Sacia, Eric R.; Sreekumar, Sanil; Gunbas, Gorkem; Gokhale, Amit A.; Scown, Corinne D.; Toste, F. Dean; Bell, Alexis T.

    2015-06-08

    Decarbonizing the transportation sector is critical to achieving global climate change mitigation. Although biofuels will play an important role in conventional gasoline and diesel applications, bioderived solutions are particularly important in jet fuels and lubricants, for which no other viable renewable alternatives exist. Producing compounds for jet fuel and lubricant base oil applications often requires upgrading fermentation products, such as alcohols and ketones, to reach the appropriate molecular-weight range. Ketones possess both electrophilic and nucleophilic functionality, which allows them to be used as building blocks similar to alkenes and aromatics in a petroleum refining complex. Here, we develop a method for selectively upgrading biomass-derived alkyl methyl ketones with >95% yields into trimer condensates, which can then be hydrodeoxygenated in near-quantitative yields to give a new class of cycloalkane compounds. The basic chemistry developed here can be tailored for aviation fuels as well as lubricants by changing the production strategy. We demonstrate that a sugarcane biorefinery could use natural synergies between various routes to produce a mixture of lubricant base oils and jet fuels that achieve net life-cycle greenhouse gas savings of up to 80%.

  8. Novel pathways for fuels and lubricants from biomass optimized using life-cycle greenhouse gas assessment

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Balakrishnan, Madhesan; Sacia, Eric R.; Sreekumar, Sanil; Gunbas, Gorkem; Gokhale, Amit A.; Scown, Corinne D.; Toste, F. Dean; Bell, Alexis T.

    2015-06-08

    Decarbonizing the transportation sector is critical to achieving global climate change mitigation. Although biofuels will play an important role in conventional gasoline and diesel applications, bioderived solutions are particularly important in jet fuels and lubricants, for which no other viable renewable alternatives exist. Producing compounds for jet fuel and lubricant base oil applications often requires upgrading fermentation products, such as alcohols and ketones, to reach the appropriate molecular-weight range. Ketones possess both electrophilic and nucleophilic functionality, which allows them to be used as building blocks similar to alkenes and aromatics in a petroleum refining complex. Here, we develop a methodmore » for selectively upgrading biomass-derived alkyl methyl ketones with >95% yields into trimer condensates, which can then be hydrodeoxygenated in near-quantitative yields to give a new class of cycloalkane compounds. The basic chemistry developed here can be tailored for aviation fuels as well as lubricants by changing the production strategy. We demonstrate that a sugarcane biorefinery could use natural synergies between various routes to produce a mixture of lubricant base oils and jet fuels that achieve net life-cycle greenhouse gas savings of up to 80%.« less

  9. MIL-L-87177 Lubricant Bulletproofs Connectors Against Chemical and Fretting Corrosion

    SciTech Connect (OSTI)

    HANLON, JAMES T.; DE MARQUIS, VIRGINIA K.; TAYLOR, RONALD DEAN

    2002-05-01

    Electrical connectors corrode. Even our best SA and MC connectors finished with 50 to 100 microinches of gold over 50 to 100 microinches of nickel corrode. This work started because some, but not all, lots of connectors held in KC stores for a decade had been destroyed by pore corrosion (chemical corrosion). We have identified a MIL-L-87177 lubricant that absolutely stops chemical corrosion on SA connectors, even in the most severe environments. For commercial connectors which typically have thinner plating thicknesses, not only does the lubricant significantly retard effects of chemical corrosion, but also it greatly prolongs the fretting life. This report highlights the initial development history and use of the lubricant at Bell Labs and AT&T, and the Battelle studies and the USAF experience that lead to its deployment to stop dangerous connector corrosion on the F-16. We report the Sandia, HFM&T and Battelle development work, connector qualification, and material compatibility studies that demonstrate its usefulness and safety on JTA and WR systems. We will be applying MIL-L-87177 Connector Lubricant to all new connectors that go into KC stores. We recommend that it be applied to connectors on newly built cables and equipment as well as material that recycles through manufacturing locations from the field.

  10. Accelerated aging of solid lubricants for the W76-1 TSL : effects of polymer outgassing.

    SciTech Connect (OSTI)

    Dugger, Michael Thomas; Wallace, William O.; Huffman, Elizabeth M.

    2006-09-01

    The behavior of MoS{sub 2} lubricants intended for the W76-1 TSL was evaluated after 17 and 82 thermal cycles, each lasting seven days and including a low temperature of -35 C and a high temperature of 93 C, in a sealed container containing organic materials. The MoS{sub 2} was applied by tumbling with MoS{sub 2} powder and steel pins (harperized), or by spraying with a resin binder (AS Mix). Surface composition measurements indicated an uptake of carbon and silicon on the lubricant surfaces after aging. Oxidation of the MoS{sub 2} on harperized coupons, where enough MoS{sub 2} was present at the surface to result in significant Mo and S concentrations, was found to be minimal for the thermal cycles in an atmosphere of primarily nitrogen. Bare steel surfaces showed a reduction in friction for exposed coupons compared to control coupons stored in nitrogen, at least for the initial cycles of sliding until the adsorbed contaminants were worn away. Lubricated surfaces showed no more than a ten percent increase in steady-state friction coefficient after exposure. Initial coefficient of friction was up to 250 percent higher than steady-state for AS Mix films on H950 coupons after 82 thermal cycles. However, the friction coefficient exhibited by lubricated coupons was never greater than 0.25, and more often less than 0.15, even after the accelerated aging exposures.

  11. Mechanical face seals: Lubrication and wear resistance. (Latest citations from FLUIDEX data base). Published Search

    SciTech Connect (OSTI)

    Not Available

    1992-08-01

    The bibliography contains citations concerning the design, development and applications of mechanical face seals relative to antifriction behavior, improved materials, lubricant effects, and accelerated model wear tests. Performance evaluations in mining, gas turbine engines, and pumps are included. (Contains 250 citations and includes a subject term index and title list.)

  12. WAXS fat subtraction model to estimate differential linear scattering coefficients of fatless breast tissue: Phantom materials evaluation

    SciTech Connect (OSTI)

    Tang, Robert Y.; Laamanen, Curtis McDonald, Nancy; LeClair, Robert J.

    2014-05-15

    Purpose: Develop a method to subtract fat tissue contributions to wide-angle x-ray scatter (WAXS) signals of breast biopsies in order to estimate the differential linear scattering coefficients ?{sub s} of fatless tissue. Cancerous and fibroglandular tissue can then be compared independent of fat content. In this work phantom materials with known compositions were used to test the efficacy of the WAXS subtraction model. Methods: Each sample 5 mm in diameter and 5 mm thick was interrogated by a 50 kV 2.7 mm diameter beam for 3 min. A 25 mm{sup 2} by 1 mm thick CdTe detector allowed measurements of a portion of the ? = 6 scattered field. A scatter technique provided means to estimate the incident spectrum N{sub 0}(E) needed in the calculations of ?{sub s}[x(E, ?)] where x is the momentum transfer argument. Values of ?{sup }{sub s} for composite phantoms consisting of three plastic layers were estimated and compared to the values obtained via the sum ?{sup }{sub s}{sup ?}(x)=?{sub 1}?{sub s1}(x)+?{sub 2}?{sub s2}(x)+?{sub 3}?{sub s3}(x), where ?{sub i} is the fractional volume of the ith plastic component. Water, polystyrene, and a volume mixture of 0.6 water + 0.4 polystyrene labelled as fibphan were chosen to mimic cancer, fat, and fibroglandular tissue, respectively. A WAXS subtraction model was used to remove the polystyrene signal from tissue composite phantoms so that the ?{sub s} of water and fibphan could be estimated. Although the composite samples were layered, simulations were performed to test the models under nonlayered conditions. Results: The well known ?{sub s} signal of water was reproduced effectively between 0.5 < x < 1.6 nm{sup ?1}. The ?{sup }{sub s} obtained for the heterogeneous samples agreed with ?{sup }{sub s}{sup ?}. Polystyrene signals were subtracted successfully from composite phantoms. The simulations validated the usefulness of the WAXS models for nonlayered biopsies. Conclusions: The methodology to measure ?{sub s} of homogeneous samples was quantitatively accurate. Simple WAXS models predicted the probabilities for specific x-ray scattering to occur from heterogeneous biopsies. The fat subtraction model can allow ?{sub s} signals of breast cancer and fibroglandular tissue to be compared without the effects of fat provided there is an independent measurement of the fat volume fraction ?{sub f}. Future work will consist of devising a quantitative x-ray digital imaging method to estimate ?{sub f} in ex vivo breast samples.

  13. Performance requirements and case histories for a specialized industrial gear lubricant for use in underground coal mining

    SciTech Connect (OSTI)

    Hart, M.D.

    1993-12-31

    The recent release of a new gear lubricant specification by an original equipment manufacturer from the mining industry is an indication that the need for a new specification is recognized in other segments of the mining industry. unfortunately, this new specification appears too ambitious in at least one of it`s performance requirements and not ambitious enough in some of it`s other requirements. This new specification requires that the lubricant be able to emulsify 50% (by volume) water for at least 24 hours. It is technically difficult to achieve this goal and at the same time retain some of the other properties that are essential to the success of a specialized lubricant for underground mining applications. The ability to maintain excellent anti-wear and extreme pressure performance even when water and solid contamination is present is one such property. This effort to incorporate contamination tolerance into a gear lubricant specification should be applauded but it also needs to be recognized that any new gear lubricant specification that attempts to do so should be based on and evolved from existing specialized gear lubricants. A review of the data presented leads to the conclusion that there needs to be a better benchmark available to insure that the enclosed gear lubricants used in underground mining will provide the best service possible. It is more than a matter of upgrading the US Steel 224 lubricant specification. A new enclosed gear lubricant benchmark specification which deals with the important contamination issues that are found in the mining environment is needed.

  14. Separation of Fischer-Tropsch wax from catalyst using supercritical fluid extraction. Quarterly technical progress report, April 1, 1996--June 30, 1996

    SciTech Connect (OSTI)

    Joyce, P.C.; Thies, M.C.

    1996-11-01

    The objective of this research project is to evaluate the potential of SCF extraction for separating the catalyst slurry of a Fischer- Tropsch (F-T) slurry bubble column (SBC) reactor into two fractions: (1) a catalyst-free wax containing less than 10 ppm particulate matter and (2) a concentrated catalyst slurry that is ready for recycle or regeneration. The wax will be extracted with a hydrocarbon solvent that has a critical temperature near the operating temperature of the SBC reactor, i.e., 200-300{degrees}C. Initial work is being performed using n-hexane as the solvent. The success of the project depends on two major factors. First, the supercritical solvent must be able to dissolve the F-T wax; furthermore, this must be accomplished without entraining the solid catalyst. Second, the extraction must be controlled so as not to favor the removal of the low molecular weight wax compounds, i.e., a constant carbon-number distribution of the alkanes in the wax slurry must be maintained at steady-state column operation. To implement our objectives, the following task structure is being implemented: Task 1 equilibrium solubility measurements; Task 2 thermodynamic modeling; and Task 3 process design studies. Progress reports are presented for each task.

  15. Advanced Petroleum-Based Fuels -- Diesel Emissions Control Project (APBF-DEC): Lubricants Project, Phase 2 Final Report

    SciTech Connect (OSTI)

    Not Available

    2006-06-01

    This report summarizes the results of the second phase of a lubricants project, which investigated the impact of engine oil formulation on diesel vehicle emissions and the performance of a nitrogen oxide adsorber catalyst (NAC).

  16. Vapor-liquid equilibria for an R134a/lubricant mixture: Measurements and equation-of-state modeling

    SciTech Connect (OSTI)

    Huber, M.L.; Holcomb, C.D.; Outcalt, S.L.; Elliott, J.R.

    2000-07-01

    The authors measured bubble point pressures and coexisting liquid densities for two mixtures of R-134a and a polyolester (POE) lubricant. The mass fraction of the lubricant was approximately 9% and 12%, and the temperature ranged from 280 K to 355 K. The authors used the Elliott, Suresh, and Donohue (ESD) equation of state to model the bubble point pressure data. The bubble point pressures were represented with an average absolute deviation of 2.5%. A binary interaction parameter reduced the deviation to 1.4%. The authors also applied the ESD model to other R-134a/POE lubricant data in the literature. As the concentration of the lubricant increased, the performance of the model deteriorated markedly. However, the use of a single binary interaction parameter reduced the deviations significantly.

  17. Separation of Fischer-Tropsch wax from catalyst by supercritical extraction. Quarterly progress report, October 1, 1996--December 31, 1996

    SciTech Connect (OSTI)

    Joyce, P.C.; Thies, M.C.

    1997-01-01

    One of the major objectives of this research project is to predict the phase behavior of model wax compounds in dense supercritical fluids such as hexane. Because initial results with the SAFT equation have been less promising than expected, the group at North Carolina State University has focused their recent attention on cubic equations of state, in particular the Peng-Robinson and Soave-Redlich-Kwong versions. The focus of this work has been on developing correlations that can be used to predict binary interaction parameters (i.e., k{sub ij}s) for a given binary wax-solvent system. As a first step, k{sub ij}s were first calculated from experimental data on systems containing alkanes between nC{sub 4} and nC{sub 23} at temperatures between 25 and 357{degrees} C. Attempts were then made to correlate these parameters with specific pure component properties of the alkanes of interest. Reasonably good agreement between experimental and predicted k{sub ij}s was found using a correlation that incorporates both temperature and the molecular size of the alkanes. As phase equilibrium data becomes available for higher molecular weight model wax compounds, the ability of the correlation to handle such systems will need to be tested. The phase equilibrium apparatus is currently undergoing modifications that will allow the system to run components that are solids at ambient temperatures. Some problems are still being resolved, as the heavy component tends to precipitate in the sample lines. Modifications have been made that should allow the system to operate reliably.

  18. Non-Newtonian temperature and pressure effects of a lubricant slurry in a rotating hydrostatic step bearing

    SciTech Connect (OSTI)

    Peterson, J.; Finn, W.E.; Dareing, D.W. |

    1994-10-01

    The purpose of this research was to investigate the pressure and temperature effects of graphite powder lubricant when added to a Newtonian carrier fluid and applied in a rotating hydrostatic step bearing. Temperature and pressure profiles were determined both analytically and experimentally. The rheological behavior of the non-Newtonian lubricant was modeled using a power law model previously shown to approximate experimental data for this fluid. Ethylene glycol was used as the Newtonian lubricant, providing a check on the test apparatus and a base line for comparison with the non-Newtonian graphite slurry. Data revealed a temperature increase with bearing rotational speed for both fluids and compared favorably with the mathematical predictions. A significantly higher temperature rise was seen in the non- Newtonian lubricant due to the higher shear rates. The pressure profile was not directly dependent on bearing rotational speed in the mathematical model, but experimental data demonstrated a reduction in pressure at higher rotation speeds. This loss was greater for the non-Newtonian lubricant and attributed to temperature dependence of power law constants. It was concluded that the effects of operating speed and temperature on a non-Newtonian lubricant should be considered as well as their greater load-carrying capacity.

  19. Reliability of excess-flow check-valves in turbine lubrication systems

    SciTech Connect (OSTI)

    Dundas, R.E.

    1996-12-31

    Reliability studies on excess-flow check valves installed in a gas turbine lubrication system for prevention of spray fires subsequent to fracture or separation of lube lines were conducted. Fault-tree analyses are presented for the case of failure of a valve to close when called upon by separation of a downstream line, as well as for the case of accidental closure during normal operation, leading to interruption of lubricating oil flow to a bearing. The probabilities of either of these occurrences are evaluated. The results of a statistical analysis of accidental closure of excess-flow check valves in commercial airplanes in the period 1986--91 are also given, as well as a summary of reliability studies on the use of these valves in residential gas installations, conducted under the sponsorship of the Gas Research Institute.

  20. Tribocharging phenomena in hard disk amorphous carbon coatings with and without perfluoropolyether lubricants

    SciTech Connect (OSTI)

    van den Oetelaar, Ronald J.A.; Xu, Lei; Ogletree, D. Frank; Salmeron, Miquel; Tang, Hung; Gui, Jing

    2000-08-01

    Scanning polarization force microscopy was used to study changes in surface potential (tribocharging) caused by the contact between a tungsten carbide tip and the amorphous carbon coating of a hard disk,both when bare and when covered with Zdol-TX lubricant. The surface potential change produced by tip contact decays with time at a rate that is strongly dependent on lubricant coverage, and on the presence of oxygen and water vapor in the environment. Two different charging mechanisms are proposed. One involves chemical modification of the surface by removal of oxygen bound to the surface. This gives rise to a potential change that decays with time. Another mechanism involves trapping of charge in states within the energy gap of the insulating carbon film. The potential change due to this trapped charge does not decay over periods much greater than 1 hour.

  1. Lubricant return comparison of naphthenic and polyol ester oils in R-134a household refrigeration applications

    SciTech Connect (OSTI)

    Reyes-Gavilan, J.L.; Flak, G.T.; Tritcak, T.R.

    1996-12-31

    This paper presents mineral oils and polyol esters as possible lubricant options for domestic refrigeration applications employing R-134a as the heat exchange fluid. A performance comparison, based on data presented, is made between the mineral oils and polyol esters evaluated. To more closely examine lubricant return with N-70 and R-134a and ensure that the oil is not contributing to any deterioration in efficiency due to its accumulation in evaporators, a special test unit was designed with a difficult oil return configuration and its performance carefully monitored. Oil return with a hydrofluorocarbon-miscible polyol ester, R-133-O was also evaluated in this setup and its performance results compared to those obtained with the naphthenic refrigeration oil.

  2. Effects of Water in Synthetic Lubricant Systems and Clathrate Formation: A Literature Search and Review

    SciTech Connect (OSTI)

    Rohatgi, Ngoc Dung T.

    2001-08-08

    An extensive literature search and a confidential survey were critically analyzed to determine the effects of water on the stability of hydrofluorocarbon/synthetic lubricant systems and to identify key areas requiring further investigation. Following are highlights from the analysis: Clathrate hydrates are solid solutions formed when water molecules are linked through hydrogen bonding creating cavities that can enclose various guest molecules from hydrate formers, such as hydrofluorocarbons R-32, R-125, R-134a, R-407C and R-410A. The four methods for preventing clathrate formation were drying the gas, heating it, reducing its pressure, or using inhibitors. The hydrolysis of polyolester lubricants was mostly acid-catalyzed and its reaction rate constant typically followed the Arrhenius equation of an activated process. Hydrolytic stability improved with hindered molecular structures, and with the presence of acid catcher additives and desiccants. Water vapor can effect the adsorption of long-chain fatty acids and the chemistry of formation of protective oxide film. However, these effects on lubrication can be either positive or negative. Fifty to sixty percent of the moisture injected into an air-conditioning system remained in the refrigerant and the rest mixed with the compressor oil. In an automotive air-conditioning system using R-134a, ice would form at 0 C evaporating temperature when the water content in the vapor refrigerant on the low-pressure side was more than 350 ppm. Moisture would cause the embrittlement of polyethylene terephthalate and the hydrolysis of polyesters, but would reduce the effect of amine additives on fluoroelastomer rubbers. The reactions of water with refrigerants and lubricants would cause formicary and large-pit corrosion in copper tubes, as well as copper plating and sludge formation. Moreover, blockage of capillary tubes increased rapidly in the presence of water. Twenty-four companies responded to the survey. From the responses, the water concentrations specified and expected for different refrigerant/lubricant systems varied depending on the products, their capacities and applications, and also on the companies. Among the problems associated with high moisture level, lubricant breakdown was of greatest concern, followed by acid formation, compressor failure and expansion valve sticking. The following research topics are suggested: 1. The air-conditioning and refrigeration industry needs to measure and record the water content and total acid number of the lubricant of newly installed systems as well as operating systems that are shutdown for service or repair. The reason for the shutdown needs to be documented. A database can then be established to correlate water content with type and cause of breakdown. 2. Detailed studies on the distribution of water in refrigeration and air-conditioning systems should be conducted to pinpoint problem areas associated with free water. 3. Research is needed to validate the current theories and mechanisms of formicary corrosion. Corrosion inhibitors need to be developed. 4. The conditions for clathrate formation and decomposition of other alternative refrigerants, such as R-23, R-41, R-116, R-125, R-143a, R-404A and R-507C, and water should be determined to avoid possible problems associated with tube plugging. The mechanism by which water facilitates or hinders lubrication needs to be studied.

  3. Synergistic Effects Between Phosphonium-Alkylphosphate Ionic Liquids and Zinc Dialkyldithiophosphate (ZDDP) as Lubricant Additives

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Qu, Jun; Barnhill, William C.; Luo, Huimin; Meyer, III, Harry M.; Leonard, Donovan N.; Landauer, Alexander K.; Kheireddin, Bassem; Gao, Hong; Papke, Brian L; Dai, Sheng

    2015-07-14

    Unique synergistic effects between phosphonium-alkylphosphate ionic liquids and zinc dialkyldithiophosphate (ZDDP) are discovered when used together as lubricant additives, resulting in significant friction and wear reduction along with distinct tribofilm composition and mechanical properties. The synergism is attributed to the 30-70× higher-than-nominal concentrations of hypothetical new compounds (via anion exchange between IL and ZDDP) on the fluid surface/interface.

  4. Near Zero Friction from Nanoscale Lubricants | U.S. DOE Office of Science

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (SC) Near Zero Friction from Nanoscale Lubricants Advanced Scientific Computing Research (ASCR) ASCR Home About Research Facilities Science Highlights Benefits of ASCR Funding Opportunities Advanced Scientific Computing Advisory Committee (ASCAC) Community Resources Contact Information Advanced Scientific Computing Research U.S. Department of Energy SC-21/Germantown Building 1000 Independence Ave., SW Washington, DC 20585 P: (301) 903-7486 F: (301) 903-4846 E: Email Us More Information »

  5. Near Zero Friction from Nanoscale Lubricants | U.S. DOE Office of Science

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (SC) Near Zero Friction from Nanoscale Lubricants Basic Energy Sciences (BES) BES Home About Research Facilities Science Highlights Benefits of BES Funding Opportunities Basic Energy Sciences Advisory Committee (BESAC) Community Resources Contact Information Basic Energy Sciences U.S. Department of Energy SC-22/Germantown Building 1000 Independence Ave., SW Washington, DC 20585 P: (301) 903-3081 F: (301) 903-6594 E: Email Us More Information » 10.01.15 Near Zero Friction from Nanoscale

  6. Synergistic Effects Between Phosphonium-Alkylphosphate Ionic Liquids and Zinc Dialkyldithiophosphate (ZDDP) as Lubricant Additives

    SciTech Connect (OSTI)

    Qu, Jun; Barnhill, William C.; Luo, Huimin; Meyer, III, Harry M.; Leonard, Donovan N.; Landauer, Alexander K.; Kheireddin, Bassem; Gao, Hong; Papke, Brian L; Dai, Sheng

    2015-07-14

    Unique synergistic effects between phosphonium-alkylphosphate ionic liquids and zinc dialkyldithiophosphate (ZDDP) are discovered when used together as lubricant additives, resulting in significant friction and wear reduction along with distinct tribofilm composition and mechanical properties. The synergism is attributed to the 30-70 higher-than-nominal concentrations of hypothetical new compounds (via anion exchange between IL and ZDDP) on the fluid surface/interface.

  7. Controlled Experiments on the Effects of Lubricant/Additive (Low-Ash,

    Broader source: Energy.gov (indexed) [DOE]

    Ashless) Characteristics on DPF Degradation | Department of Energy Effects of lubricant additive chemistries and exhaust conditions on ash properties affecting diesel particulate filter performance. Comparison of ash characteristics such as packing density and elemental composition in field and laboratory aged DPFs. PDF icon deer08_sappok.pdf More Documents & Publications Key Parameters Affecting DPF Performance Degradation and Impact on Lifetime Fuel Economy Characteristics and Effects

  8. The role of polymer formation during vapor phase lubrication of silicon.

    SciTech Connect (OSTI)

    Dugger, Michael Thomas; Dirk, Shawn M.; Ohlhausen, James Anthony

    2010-10-01

    The lubrication of silicon surfaces with alcohol vapors has recently been demonstrated. With a sufficient concentration of pentanol vapor present, sliding of a silica ball on an oxidized silicon wafer can proceed with no measurable wear. The initial results of time-of-flight secondary ion mass spectrometry (ToF-SIMS) analysis of wear surfaces revealed a reaction product having thickness on the order of a monolayer, and with an ion spectrum that included fragments having molecular weights of 200 or more that occurred only inside the wear tracks. The parent alcohol molecule pentanol, has molecular weight of 88amu, suggesting that reactions of adsorbed alcohols on the wearing surfaces allowed polymerization of the alcohols to form higher molecular weight species. In addition to pin-on-disk studies, lubrication of silicon surfaces with pentanol vapors has also been demonstrated using MicroElectroMechanical Systems (MEMS) devices. Recent investigations of the reaction mechanisms of the alcohol molecules with the oxidized silicon surfaces have shown that wearless sliding requires a concentration of the alcohol vapor that is dependent upon the contact stress during sliding, with higher stress requiring a greater concentration of alcohol. Different vapor precursors including those with acid functionality, olefins, and methyl termination also produce polymeric reaction products, and can lubricate the silica surfaces. Doping the operating environment with oxygen was found to quench the formation of the polymeric reaction product, and demonstrates that polymer formation is not necessary for wearless sliding.

  9. Effects of star-shape poly(alkyl methacrylate) arm uniformity on lubricant properties

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Robinson, Joshua W.; Qu, Jun; Erck, Robert; Cosimbescu, Lelia; Zhou, Yan

    2016-03-29

    Star-shaped poly(alkyl methacrylate)s (PAMAs) were prepared and blended into an additive-free engine oil to assess the structure property relationship between macromolecular structure and lubricant performance. These additives were designed with a comparable number of repeating units per arm and the number of arms was varied between 3 and 6. Well-defined star-shaped PAMAs were synthesized by atom transfer radical polymerization (ATRP) via a core-first strategy from multi-functional headgroups. Observations of the polymer-oil blends suggest that stars with less than four arms are favorable as a viscosity index improver (VII), and molecular weight dominates viscosity-related effects over other structural features. Star-shaped PAMAs,more » as oil additives, effectively reduce the friction coefficient in both mixed and boundary lubrication regime. Several analogs outperformed commercial VIIs in both viscosity and friction performance. Furthermore, increased wear rates were observed for these star-shaped PAMAs in the boundary lubrication regime suggesting pressure-sensitive conformations may exist.« less

  10. Post Irradiation Evaluation of Thermal Control Coatings and Solid Lubricants to Support Fission Surface Power Systems

    SciTech Connect (OSTI)

    Bowman, Cheryl L.; Jaworske, Donald A.; Stanford, Malcolm K.; Persinger, Justin A.; Khorsandi, Behrooz; Blue, Thomas E.

    2007-01-30

    The development of a nuclear power system for space missions, such as the Jupiter Icy Moons Orbiter or a lunar outpost, requires substantially more compact reactor design than conventional terrestrial systems. In order to minimize shielding requirements and hence system weight, the radiation tolerance of component materials within the power conversion and heat rejection systems must be defined. Two classes of coatings, thermal control paints and solid lubricants, were identified as material systems for which limited radiation hardness information was available. Screening studies were designed to explore candidate coatings under a predominately fast neutron spectrum. The Ohio State Research Reactor Facility staff performed irradiation in a well characterized, mixed energy spectrum and performed post irradiation analysis of representative coatings for thermal control and solid lubricant applications. Thermal control paints were evaluated for 1 MeV equivalent fluences from 1013 to 1015 n/cm2. No optical degradation was noted although some adhesive degradation was found at higher fluence levels. Solid lubricant coatings were evaluated for 1 MeV equivalent fluences from 1015 to 1016 n/cm2 with coating adhesion and flexibility used for post irradiation evaluation screening. The exposures studied did not lead to obvious property degradation indicating the coatings would have survived the radiation environment for the previously proposed Jupiter mission. The results are also applicable to space power development programs such as fission surface power for future lunar and Mars missions.

  11. Oil-Miscible and Non-Corrosive Phosphonium Ionic Liquids as Candidate Lubricant Additives

    SciTech Connect (OSTI)

    Yu, Bo; Bansal, Dinesh G; Qu, Jun; Sun, Xiaoqi; Luo, Huimin; Dai, Sheng; Blau, Peter Julian; Bunting, Bruce G; Mordukhovich, Gregory; Smolenski, Donald

    2012-01-01

    Ionic liquids (ILs) have been receiving considerable attention from the lubricants industry as potential friction and wear-reducing additives, but their solubility in oils is an issue. Unlike most ionic liquids that are insoluble in non-polar hydrocarbon oils, this study reports phosphonium-based ILs (PP-ILs) that are fully miscible with both mineral oil-based and synthetic lubricants. Both the cation and anion in quaternary structures, long alkyl chains, and capability of pairing the cation and the anion via a H-O bond are hypothesized to improve the compatibility between ions and neutral oil molecules. The measured viscosities of the oil-IL blends agree well with the Refutas equation that is for solutions containing multiple components. High thermal stability and non-corrosiveness were observed for the PP-ILs. Effective friction reduction and anti-wear functionality have been demonstrated in tribological tests when adding 5 wt% of a PP-IL into a base oil, suggesting potential applications for using the oil-miscible PP-ILs as lubricant additives.

  12. A method to estimate the fractional fat volume within a ROI of a breast biopsy for WAXS applications: Animal tissue evaluation

    SciTech Connect (OSTI)

    Tang, Robert Y.; McDonald, Nancy Laamanen, Curtis; LeClair, Robert J.

    2014-11-01

    Purpose: To develop a method to estimate the mean fractional volume of fat (?{sup }{sub fat}) within a region of interest (ROI) of a tissue sample for wide-angle x-ray scatter (WAXS) applications. A scatter signal from the ROI was obtained and use of ?{sup }{sub fat} in a WAXS fat subtraction model provided a way to estimate the differential linear scattering coefficient ?{sub s} of the remaining fatless tissue. Methods: The efficacy of the method was tested using animal tissue from a local butcher shop. Formalin fixed samples, 5 mm in diameter 4 mm thick, were prepared. The two main tissue types were fat and meat (fibrous). Pure as well as composite samples consisting of a mixture of the two tissue types were analyzed. For the latter samples, ?{sub fat} for the tissue columns of interest were extracted from corresponding pixels in CCD digital x-ray images using a calibration curve. The means ?{sup }{sub fat} were then calculated for use in a WAXS fat subtraction model. For the WAXS measurements, the samples were interrogated with a 2.7 mm diameter 50 kV beam and the 6 scattered photons were detected with a CdTe detector subtending a solid angle of 7.75 10{sup ?5} sr. Using the scatter spectrum, an estimate of the incident spectrum, and a scatter model, ?{sub s} was determined for the tissue in the ROI. For the composite samples, a WAXS fat subtraction model was used to estimate the ?{sub s} of the fibrous tissue in the ROI. This signal was compared to ?{sub s} of fibrous tissue obtained using a pure fibrous sample. Results: For chicken and beef composites, ?{sup }{sub fat}=0.330.05 and 0.32 0.05, respectively. The subtractions of these fat components from the WAXS composite signals provided estimates of ?{sub s} for chicken and beef fibrous tissue. The differences between the estimates and ?{sub s} of fibrous obtained with a pure sample were calculated as a function of the momentum transfer x. A t-test showed that the mean of the differences did not vary from zero in a statistically significant way thereby validating the methods. Conclusions: The methodology to estimate ?{sup }{sub fat} in a ROI of a tissue sample via CCD x-ray imaging was quantitatively accurate. The WAXS fat subtraction model allowed ?{sub s} of fibrous tissue to be obtained from a ROI which had some fat. The fat estimation method coupled with the WAXS models can be used to compare ?{sub s} coefficients of fibroglandular and cancerous breast tissue.

  13. US Synthetic Corp (TRL 4 Component)- The Development of Open, Water Lubricated Polycrystalline Diamond Thrust Bearings for use in Marine Hydrokinetic (MHK) Energy Machines

    Broader source: Energy.gov [DOE]

    US Synthetic Corp (TRL 4 Component) - The Development of Open, Water Lubricated Polycrystalline Diamond Thrust Bearings for use in Marine Hydrokinetic (MHK) Energy Machines

  14. Synthesis of monodispersed ZnAl{sub 2}O{sub 4} nanoparticles and their tribology properties as lubricant additives

    SciTech Connect (OSTI)

    Song, Xiaoyun; Zheng, Shaohua; Zhang, Jun; Li, Wei; Chen, Qiang; Cao, Bingqiang

    2012-12-15

    Graphical abstract: Display Omitted Highlights: ? The preparation of ZnAl{sub 2}O{sub 4} nanoparticles was realized by hydrothermal method. ? After surface modification, ZnAl{sub 2}O{sub 4} nanoparticles of narrow size distribution can disperse in lubricating oil stably. ? The modified ZnAl{sub 2}O{sub 4} nanoparticles as lubricating oil additives exhibit good tribology properties. -- Abstract: Monodispersed spherical zinc aluminate spinel (ZnAl{sub 2}O{sub 4}) nanoparticles were synthesized via a solvothermal method and modified by oleic acid in cyclohexanol solution. The nanoparticles were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM) and infrared spectrum (IR). The dispersion ability of nanoparticles in lubricant oil was measured with optical absorbance spectrum. The results show that the modified nanoparticles are nearly monodispersed and can stably disperse in lubricant oil. The tribological properties of the ZnAl{sub 2}O{sub 4} nanoparticles as an additive in lubricant oil were evaluated with four-ball test and thrust-ring test. For comparison, ZnO and Al{sub 2}O{sub 3} nanoparticles as additive in lubricant oil were also tested respectively. The results show that ZnAl{sub 2}O{sub 4} nanoparticles exhibit better tribology properties in terms of anti-wear and anti-friction than ZnO or Al{sub 2}O{sub 3} nanoparticles. The anti-friction and anti-wear mechanisms were discussed and the lubricating effect of ZnAl{sub 2}O{sub 4} nanoparticles can be attributed to nano-bearings effect and tribo-sintering mechanism.

  15. Heat transfer of R-134a in single-tube spray evaporation including lubricant effects and enhanced surface results

    SciTech Connect (OSTI)

    Moeykens, S.A.; Huebsch, W.W.; Pate, M.B.

    1995-08-01

    Single-tube spray evaporation experimental tests were conducted in order to evaluate the average wall heat transfer coefficients for seven different commercially available tubes. Liquid film supply rates were held constant in order to evaluate the effects of the enhancement on shell-side heat transfer under similar conditions. Because the spray evaporation phenomenon is so different from pool boiling, both condensation-type and evaporation-type enhanced surfaces were evaluated. A comparison of the results for all of the tubes showed that the enhanced condensation surfaces performed better than the enhanced boiling surfaces. In addition, the 26-fpi surface tested marginally better than the 40-fpi surface. Small concentrations of a polyol-ester lubricant cause a foaming effect that increases the heat transfer performance. This tendency was seen with both 32-cs and 68-cs polyol-ester oils. The 68-cs lubricant was tested at concentrations of 0.0, 0.5, 1.0, 3.0, and 5.0 with the W-40 fpi and Tu-Cii surfaces. Results with this lubricant show the performance continues to increase through the 3% concentration for most of the heat flux range tested At the upper end of the range tested, the 1.0% mass fraction yielded the best performance. The 32-cs lubricant generated trends similar to those of the 68-cs lubricant. Lubricant concentrations of 1.0%, 2.0%, and 3.0% were evaluated with plain, W-40 fpi, and Tu-Cii surfaces. The 2.0% concentration, not the 1.0 %, generated the best performance at the highest heat flux tested. This difference must be attributed to the difference in the lubricant viscosity.

  16. Materials Compatibility and Lubricants Research on CFC-refrigerant substitutes. Quarterly MCLR Program technical progress report, July 1--September 30, 1995

    SciTech Connect (OSTI)

    Szymurski, S.R.; Hourahan, G.C.; Godwin, D.S.; Amrane, K.

    1995-10-01

    The Materials Compatibility and Lubricants Research (MCLR) program supports critical research to accelerate the introduction of CFC and HCFC refrigerant substitutes. The MCLR program addresses refrigerant and lubricant properties and materials compatibility. The primary elements of the work include data collection and dissemination, materials compatibility testing, and methods development. This report summarizes the research conducted during the third quarter of calendar year 1995 on the following projects: Thermophysical properties of HCFC alternatives; Compatibility of manufacturing process fluids with HFC refrigerants and ester lubricants; Compatibility of motor materials used in air-conditioning for retrofits with alternative refrigerants and lubricants; Compatibility of lubricant additives with HFC refrigerants and synthetic lubricants; Products of motor burnouts; Accelerated test methods for predicting the life of motor materials exposed to refrigerant-lubricant mixtures; Investigation of flushing and clean-out methods; Investigation into the fractionation of refrigerant blends; Lean flammability limits as a fundamental refrigerant property; Effect of selected contaminants in AC and R equipment; Study of foaming characteristics; Study of lubricant circulation in systems; Evaluation of HFC-245ca for commercial use in low pressure chillers; Infrared analysis of refrigerant mixtures; Refrigerant database; Refrigerant toxicity survey; Thermophysical properties of HFC-32, HFC-123, HCFC-124 and HFC-125; Thermophysical properties of HFC-143a and HFC-152a; Theoretical evaluations of R-22 alternative fluids; Chemical and thermal stability of refrigerant-lubricant mixtures with metals; Miscibility of lubricants with refrigerants; Viscosity, solubility and density measurements of refrigerant-lubricant mixtures; Electrohydrodynamic enhancement of pool and in-tube boiling of alternative refrigerants; Accelerated screening methods; and more.

  17. Time-Resolved SAXS/WAXS Study of the Phase Behavior and Microstructural Evolution of Drug/PEG Solid Dispersions

    SciTech Connect (OSTI)

    Zhu, Qing; Harris, Michael T.; Taylor, Lynne S.

    2013-03-07

    Simultaneous small-angle X-ray scattering/wide-angle X-ray scattering (SAXS/WAXS) was employed to elucidate the physical state and location of various small molecule drugs blended with polyethylene glycol (PEG), as well as the time dependent microstructural evolution of the systems. Samples were prepared by comelting physical mixtures of the drug and PEG, followed by solidification at 25 C. The model drugs selected encompassed a wide variety of physicochemical properties in terms of crystallization tendency and potential for interaction with PEG. It was observed that compounds which crystallized rapidly and had weak interactions with PEG tended to be excluded from the interlamellar region of the PEG matrix. In contrast, drugs which had favorable interactions with PEG were incorporated into the interlamellar regions of the polymer up until the point at which the drug crystallized whereby phase separation occurred. These factors are likely to impact the effectiveness of drug/PEG systems as drug delivery systems.

  18. Health assessment for Vogel Paint and Wax, Maurice, Sioux County, Iowa, Region 7. CERCLIS No. IAD980630487. Final report

    SciTech Connect (OSTI)

    Not Available

    1989-04-29

    The Vogel Paint and Wax National Priority List site is situated in northwest Iowa in Sioux County. Contaminants found at the site consist of heavy metals (particularly cadmium, chromium, lead, and mercury) and volatile organic compounds (benzene, ethylbenzene, methyl ethyl ketone, toluene, and xylene). Two towns, Maurice and Struble, and the Southern Sioux County Rural Water System well field are located within three miles of the site, and two families live within 1600 feet of the waste-disposal site. Environmental pathways include contaminated soil and ground water, as well as potential surface water and air contamination. Although there does not appear to be any immediate public health threat, the site is of potential health concern because of the possibility for further off-site migration of contaminants into the ground water aquifer and for direct on-site contact.

  19. A comparison of the heat transfer and pressure drop performance of R-134a-lubricant mixtures in different diameter smooth tubes and micro-fin tubes

    SciTech Connect (OSTI)

    Eckels, S.J.; Doerr, T.M.; Pate, M.B.

    1998-10-01

    The average heat transfer coefficients and pressure drops during evaporation and condensation are reported for mixtures of R-134a and an ester lubricant in tubes of 12.7 mm (1/2 in.) outer diameter. The objective of this paper is to evaluate the performance of the R-134a-lubricant mixtures in these tubes and determine the performance benefits of the micro-fin tube. The performance benefits of the tubes with 12.7 mm (1/2 in.) outer diameter are compared to those of smaller tubes with 9.52 mm (3/8 in.) outer diameter. The lubricant used was a 169 SUS penta erythritol ester mixed-acid lubricant. The lubricant concentration was varied from 0--5.1% in the mixture. The average heat transfer coefficients in the 12.7 mm (1/2 in.) micro-fin tube were 50--150% higher than those for the 12.7 mm (1/2 in.) smooth tube, while pressure drops in the micro-fin tube were 5% to 50% higher than in the smooth tube. The addition of lubricant degraded the average heat transfer coefficients in all cases except during evaporation at low lubricant concentrations. Pressure drops were always increased with the addition of lubricant. The experimental results also indicate that tube diameter has some effect on the performance benefits of the micro-fin tube over that of the smooth tube.

  20. Transparency and damage tolerance of patternable omniphobic lubricated surfaces based on inverse colloidal monolayers

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Vogel, Nicolas; Belisle, Rebecca A.; Hatton, Benjamin; Wong, Tak-Sing; Aizenberg, Joanna

    2013-07-31

    A transparent coating that repels a wide variety of liquids, prevents staining, is capable of self-repair and is robust towards mechanical damage can have a broad technological impact, from solar cell coatings to self-cleaning optical devices. Here we employ colloidal templating to design transparent, nanoporous surface structures. A lubricant can be firmly locked into the structures and, owing to its fluidic nature, forms a defect-free, self-healing interface that eliminates the pinning of a second liquid applied to its surface, leading to efficient liquid repellency, prevention of adsorption of liquid-borne contaminants, and reduction of ice adhesion strength. We further show howmore » this method can be applied to locally pattern the repellent character of the substrate, thus opening opportunities to spatially confine any simple or complex fluids. The coating is highly defect-tolerant due to its interconnected, honeycomb wall structure, and repellency prevails after the application of strong shear forces and mechanical damage. The regularity of the coating allows us to understand and predict the stability or failure of repellency as a function of lubricant layer thickness and defect distribution based on a simple geometric model.« less

  1. Lubricating bacteria model for the growth of bacterial colonies exposed to ultraviolet radiation

    SciTech Connect (OSTI)

    Zhang Shengli; Zhang Lei; Liang Run; Zhang Erhu; Liu Yachao; Zhao Shumin

    2005-11-01

    In this paper, we study the morphological transition of bacterial colonies exposed to ultraviolet radiation by modifying the bacteria model proposed by Delprato et al. Our model considers four factors: the lubricant fluid generated by bacterial colonies, a chemotaxis initiated by the ultraviolet radiation, the intensity of the ultraviolet radiation, and the bacteria's two-stage destruction rate with given radiation intensities. Using this modified model, we simulate the ringlike pattern formation of the bacterial colony exposed to uniform ultraviolet radiation. The following is shown. (1) Without the UV radiation the colony forms a disklike pattern and reaches a constant front velocity. (2) After the radiation is switched on, the bacterial population migrates to the edge of the colony and forms a ringlike pattern. As the intensity of the UV radiation is increased the ring forms faster and the outer velocity of the colony decreases. (3) For higher radiation intensities the total population decreases, while for lower intensities the total population increases initially at a small rate and then decreases. (4) After the UV radiation is switched off, the bacterial population grows both outward as well as into the inner region, and the colony's outer front velocity recovers to a constant value. All these results agree well with the experimental observations [Phys. Rev. Lett. 87, 158102 (2001)]. Along with the chemotaxis, we find that lubricant fluid and the two-stage destruction rate are critical to the dynamics of the growth of the bacterial colony when exposed to UV radiation, and these were not previously considered.

  2. Transparency and damage tolerance of patternable omniphobic lubricated surfaces based on inverse colloidal monolayers

    SciTech Connect (OSTI)

    Vogel, N; Belisle, RA; Hatton, B; Wong, TS; Aizenberg, J

    2013-07-31

    A transparent coating that repels a wide variety of liquids, prevents staining, is capable of self-repair and is robust towards mechanical damage can have a broad technological impact, from solar cell coatings to self-cleaning optical devices. Here we employ colloidal templating to design transparent, nanoporous surface structures. A lubricant can be firmly locked into the structures and, owing to its fluidic nature, forms a defect-free, self-healing interface that eliminates the pinning of a second liquid applied to its surface, leading to efficient liquid repellency, prevention of adsorption of liquid-borne contaminants, and reduction of ice adhesion strength. We further show how this method can be applied to locally pattern the repellent character of the substrate, thus opening opportunities to spatially confine any simple or complex fluids. The coating is highly defect-tolerant due to its interconnected, honeycomb wall structure, and repellency prevails after the application of strong shear forces and mechanical damage. The regularity of the coating allows us to understand and predict the stability or failure of repellency as a function of lubricant layer thickness and defect distribution based on a simple geometric model.

  3. Lubricants Activities

    Broader source: Energy.gov [DOE]

    2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  4. Anti-Wear Performance and Mechanism of an Oil-Miscible Ionic Liquid as a Lubricant Additive

    SciTech Connect (OSTI)

    Qu, Jun; Bansal, Dinesh G; Yu, Bo; Howe, Jane Y; Luo, Huimin; Dai, Sheng; Li, Huaqing; Blau, Peter Julian; Bunting, Bruce G; Mordukhovich, Gregory; Smolenski, Donald

    2012-01-01

    An ionic liquid (IL) trihexyltetradecylphosphonium bis(2-ethylhexyl) phosphate has been investigated as a potential anti-wear lubricant additive. Unlike most other ILs that have very low solubility in non-polar fluids, this IL is fully miscible with various hydrocarbon oils. In addition, it is thermally stable up to 347 oC, showed no corrosive attack to cast iron in ambient environment, and has excellent wettability on solid surfaces (e.g., contact angle on cast iron <8o). Most importantly, this phosphonium-based IL has demonstrated effective anti-scuffing and anti-wear characteristics when blended with lubricating oils. For example, a 5 wt.% addition into a synthetic base oil eliminated the scuffing failure experienced by the neat oil and, as a result, reduced the friction coefficient by 60% and the wear rate by three orders of magnitude. A synergistic effect on wear protection was observed with the current anti-wear additive when added into a fully-formulated engine oil. Nanostructure examination and composition analysis revealed a tribo-boundary film and subsurface plastic deformation zone for the metallic surface lubricated by the IL-containing lubricants. This protective boundary film is believed to be responsible for the IL s anti-scuffing and anti-wear functionality.

  5. Does the Use of Diamond-Like Carbon Coating and Organophosphate Lubricant Additive Together Cause Excessive Tribochemical Material Removal?

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhou, Yan; Leonard, Donovan N.; Meyer, Harry M.; Luo, Huimin; Qu, Jun

    2015-08-22

    We observe unexpected wear increase on a steel surface that rubbed against diamond-like carbon (DLC) coatings only when lubricated by phosphate-based antiwear additives. Contrary to the literature hypothesis of a competition between zinc dialkyldithiophosphate produced tribofilms and DLC-induced carbon transfer, here a new wear mechanism based on carbon-catalyzed tribochemical interactions supported by surface characterization is proposed

  6. Study of fractionation of refrigerant blends in contact with lubricants and measurement of the solubility, density, and viscosity

    SciTech Connect (OSTI)

    Cavestri, R.C.; Falconi, E.A.

    1999-07-01

    The fractionation of two refrigerant blends was studied using the gas equilibrium method. The amount of fractionation was measured by maintaining a constant composition of the refrigerant gas vapor over the lubricant, which was equal in composition to the liquid refrigerant gas blend introduced into the viscometer. Specifically, the concentration of the dissolved refrigerant gas in the lubricant ranges from 0.6% to 78% by weight in the specified temperature range of {minus}25 C to 125 C and within the highest test pressure of 500 psia (3.45 MPa). The polyolester chosen for this study was a 32 ISO VG complex branched acid pentaerythritol product. Smoothed graphical data presented were obtained from individual isothermal measurements. These individual isothermal measurement temperatures detail the composition of the equilibrium gas fractionation of R-32 and R-134a in the lubricant, mixed vapor pressure, concentration of the total mixed blend as percent by weight in the lubricant and viscosity in centipoise (cP) and centistokes (cSt). The raw data are presented in a smoothed graphical form based on a fixed vapor composition.

  7. Effect of lubricant on spray evaporation heat transfer performance of R-134a and R-22 in tube bundles

    SciTech Connect (OSTI)

    Moeykens, S.A.; Pate, M.B.

    1996-11-01

    This study evaluates the effects of lubricant on spray evaporation heat transfer performance. Tests were conducted with refrigerant R-134a and triangular-pitch tube bundles made from enhanced-condensation, enhanced-boiling, low-finned, and plain-surface tubes. A 340-SUS polyol-ester (POE) oil was used for the R-134a testing because this lubricant is being integrated into industry for use with this refrigerant. Refrigerant was sprayed onto the tube bundles with low-pressure-drop, wide-angle nozzles located directly above the bundle. Collector testing was conducted with both R-134a and R-22 to determine the percentage of refrigerant contacting the tue bundle. It was found that small concentrations of the polyol-ester lubricant yielded significant improvement in the heat transfer performance of R-134a. The shell-side heat transfer coefficient was more dependent on lubricant concentration than on film-feed supply rate within the range of the respective parameters evaluated in this study. As expected, pure R-22 results show higher heat transfer coefficients than those obtained with pure R-134a at the same saturation temperature of 2.0 C (35.6 F).

  8. Lubricating system for thermal medium delivery parts in a gas turbine

    DOE Patents [OSTI]

    Mashey, Thomas Charles (Coxsackie, NY)

    2002-01-01

    Cooling steam delivery tubes extend axially along the outer rim of a gas turbine rotor for supplying cooling steam to and returning spent cooling steam from the turbine buckets. Because of the high friction forces at the interface of the tubes and supporting elements due to rotor rotation, a low coefficient of friction coating is provided at the interface of the tubes and support elements. On each surface, a first coating of a cobalt-based alloy is sprayed onto the surface at high temperature. A portion of the first coating is machined off to provide a smooth, hard surface. A second ceramic-based solid film lubricant is sprayed onto the first coating. By reducing the resistance to axial displacement of the tubes relative to the supporting elements due to thermal expansion, the service life of the tubes is substantially extended.

  9. Lubricant-infused micro/nano-structured surfaces with tunable dynamic omniphobicity at high temperatures

    SciTech Connect (OSTI)

    Daniel, D; Mankin, MN; Belisle, RA; Wong, TS; Aizenberg, J

    2013-06-10

    Omniphobic surfaces that can repel fluids at temperatures higher than 100 degrees C are rare. Most state-of-the-art liquid-repellent materials are based on the lotus effect, where a thin air layer is maintained throughout micro/nanotextures leading to high mobility of liquids. However, such behavior eventually fails at elevated temperatures when the surface tension of test liquids decreases significantly. Here, we demonstrate a class of lubricant-infused structured surfaces that can maintain a robust omniphobic state even for low-surface-tension liquids at temperatures up to at least 200 degrees C. We also demonstrate how liquid mobility on such surfaces can be tuned by a factor of 1000. (C) 2013 Author(s).

  10. Effects of self-assembled monolayer and PFPE lubricant on wear characteristics of flat silicon tips.

    SciTech Connect (OSTI)

    Kim, H. J.; Jang, C. E.; Kim, D. E.; Kim, Y. K.; Choa, S. H.; Hong, S.; Materials Science Division; Yonsei Univ.; Samsung Adv. Inst. Science and Technology; Seoul National Univ. of Technology

    2009-01-01

    The effects of self-assembled monolayer (SAM) and perfluoropolyether (PFPE) lubricant on the wear characteristics of flat silicon tips were investigated. The wear test consisted of sliding the silicon tips fabricated on a flat silicon specimen against SAM and PFPE (Z-tetraol) coated silicon (100) wafer. The tips were slid at a low speed for about 15 km under an applied load of 39.2 {micro}N. The wear volume of the tip was obtained by measuring the tip profile using an Atomic Force Microscope (AFM). It was found that the coatings were effective in reducing the wear of the tips by an order of magnitude from 10{sup -6} to 10{sup -7}.

  11. Lubricant-infused micro/nano-structured surfaces with tunable dynamic omniphobicity at high temperatures

    SciTech Connect (OSTI)

    Daniel, Daniel; Max, Mankin N.; Belisle, Rebecca A.; Wong, Tak-Sing; Aizenberg, Joanna

    2013-06-12

    Omniphobic surfaces that can repel fluids at temperatures higher than 100 #2;C are rare. Most stateof- the-art liquid-repellent materials are based on the lotus effect, where a thin air layer is maintained throughout micro/nanotextures leading to high mobility of liquids. However, such behavior eventually fails at elevated temperatures when the surface tension of test liquids decreases significantly. Here, we demonstrate a class of lubricant-infused structured surfaces that can maintain a robust omniphobic state even for low-surface-tension liquids at temperatures up to at least 200 #2;C. We also demonstrate how liquid mobility on such surfaces can be tuned by a factor of 1000.

  12. Superfund Record of Decision (EPA Region 7): Vogel Paint and Wax, Maurice, IA. (First remedial action), September 1989. Final report

    SciTech Connect (OSTI)

    Not Available

    1989-09-20

    The Vogel Paint and Wax (VPW) site is an approximately two-acre disposal area two miles southwest of the town of Maurice, in Sioux County, Iowa. Adjacent land uses are primarily agricultural; however, several private residences are within one-quarter mile of the site. A surficial sand and gravel aquifer underlies the site and supplies nearby private wells and the Southern Sioux County Rural Water System, located a mile and one half southeast of the site. Paint sludge, resins, solvents, and other paint-manufacturing wastes were disposed of at the site between 1971 and 1979. VPW records indicate that approximately 43,000 gallons of aliphatic and aromatic hydrocarbons and 6,000 pounds of metals waste were buried at the site. The primary contaminants of concern affecting the soil and ground water are VOCs including benzene, toluene, and xylenes; and metals including chromium and lead. The selected remedial action for this site includes excavation of contaminated soil and separation of solid and liquid wastes; onsite bioremediation of 3,000 cubic yards of the contaminated soil in a fully contained surface impoundment unit, or onsite thermal treatment if soil contains high metal content; and stabilization of treated soil, if necessary to prevent leaching of metals, followed by disposal in the excavated area.

  13. Scuffing initiation in metals sliding against copper under non-lubricated conditions

    SciTech Connect (OSTI)

    Kovalchenko, A M; Blau, Peter Julian; Qu, Jun; Danyluk, S

    2011-01-01

    Metallic components in sliding contact are sometimes subjected to high-loads with little or no lubrication. Such starved conditions can lead to a phenomenon called scuffing. Various definitions exist for this term, but in the present case, three criteria were used to signal its onset: changes in friction, vibrations, and noise, coupled with surface examination. On this basis, scuffing initiation was determined for seven technically pure metals (Al, Mo, Nb, Ta, Ti, W, Cu) and stainless steel, all rubbing against Cu. A flat-ended pin-on-disk test configuration was used with normal loads of 1-3 N, and with step-wise increases in sliding speed from 0.16 to 2.56 m/s. Al was only weakly resistant to scuffing, presumably due to its solubility in Cu, its high ductility and its relatively low elastic modulus. Niobium provided satisfactory sliding behavior at low speeds and loads, presumably due to protective oxides; however, it scuffed at higher loads when the oxide broke through. Stainless steel, Mo, and Ta had higher friction coefficients than Al and Nb, presumably because the relatively high strengths of the former prevented severe wear even when their oxide films failed. Like Al, Ti scuffs on Cu, probably because of its high relative solubility; however, Ti's higher elastic modulus resists the more severe forms of surface damage than does Al. Of all the materials slid against Cu, W displayed the least scuffing, even under maximum speed and load. Tungsten's negligible solubility in Cu may have reduced its adhesion, and W's high elastic modulus resisted shear-deformation, even at high frictional heating. Self-mated Cu couple scuffed when the speed was increased. The oxides on the Cu surface serve as solid lubricant avoiding scuffing at lower speeds.

  14. Heat transfer coefficients and pressure drops for R-134a and an ester lubricant mixture in a smooth tube and a micro-fin tube

    SciTech Connect (OSTI)

    Eckels, S.J.; Doerr, T.M.; Pate, M.B.

    1998-10-01

    This paper reports average heat transfer coefficients and pressure drops during the evaporation and condensation of mixtures of R-134a and a 150 SUS penta erythritol ester branched-acid lubricant. The smooth tube and micro-fin tube tested in this study had outer diameters of 9.52 mm (3/8 in.). The micro-fin tube had 60 fins, a fin height of 0.2 mm (0.008 in), and a spiral angle of 18{degree}. The objective of this study is to evaluate the effectiveness of the micro-fin tube with R-134a and to determine the effect of circulating lubricant. The experimental results show that the micro-fin tube has distinct performance advantages over the smooth tube. For example, the average heat transfer coefficients during evaporation and condensation in the micro-fin tube were 50--200% higher than those for the smooth tube, while the average pressure drops were on average only 10--50% higher. The experimental results indicate that the presence of a lubricant degrades the average heat transfer coefficients during both evaporation and condensation at high lubricant concentrations. Pressure drops during evaporation increased with the addition of a lubricant in both tubes. For condensation, pressure drops were unaffected by the addition of a lubricant.

  15. Accelerated screening methods for determining chemical and thermal stability of refreigerant-lubricant mixtures. Part II: Experimental comparison and verification of methods. Final report, volume I

    SciTech Connect (OSTI)

    Kauffman, R.

    1995-09-01

    The research reported herein was performed to develop an accelerated screening method for determining the chemical and thermal stabilities of refrigerant/lubricant mixtures. The developed screening method was designed to be safe and to produce accelerated stability rankings that are in agreement with the rankings determined by the current test, Sealed Glass Tube Method to Test the Chemical Stability of Material for Use Within Refrigerant Systems, ANSI/ASHRAE Method 97-1989. The accelerated screening test developed was designed to be independent of refrigerant and lubricant compositions and to be used with a wide variety of construction materials. The studied refrigerants included CFC-11, CFC-12, HCFC-22, HFC-134a, and HFC-32/HFC-134a (zeotrope 30:70 by weight). The studied lubricants were selected from the chemical classes of mineral oil, alkylbenzene oil, polyglycols, and polyolesters. The work reported herein was performed in three phases. In the first phase, previously identified thermal analytical techniques were evaluated for development into an accelerated screening method for refrigerant/lubricant mixtures. The identified thermal analytical techniques used in situ measurements of color, temperature, or conductivity to monitor the degradation of the heated refrigerant/lubricant mixtures. The identified thermal analytical techniques also used catalysts such as ferric fluoride to accelerate the degradation of the heated refrigerant/lubricant mixtures. The thermal analytical technique employing in situ conductivity measurements was determined to be the most suitable for development into an accelerated screening method.

  16. Tribological properties of self-lubricating NiAl/Mo-based composites containing AgVO{sub 3} nanowires

    SciTech Connect (OSTI)

    Liu, Eryong; Gao, Yimin; Bai, Yaping; Yi, Gewen; Wang, Wenzhen; Zeng, Zhixiang; Jia, Junhong

    2014-11-15

    Silver vanadate (AgVO{sub 3}) nanowires were synthesized by hydrothermal method and self-lubricating NiAl/Mo-AgVO{sub 3} composites were fabricated by powder metallurgy technique. The composition and microstructure of NiAl/Mo-based composites were characterized and the tribological properties were investigated from room temperature to 900 C. The results showed that NiAl/Mo-based composites were consisted of nanocrystalline B2 ordered NiAl matrix, Al{sub 2}O{sub 3}, Mo{sub 2}C, metallic Ag and vanadium oxide phase. The appearance of metallic Ag and vanadium oxide phase can be attributed to the decomposition of AgVO{sub 3} during sintering. Wear testing results confirmed that NiAl/Mo-based composites have excellent tribological properties over a wide temperature range. For example, the friction coefficient and wear rate of NiAl/Mo-based composites containing AgVO{sub 3} were significantly lower than the composites containing only metallic Mo or AgVO{sub 3} lubricant when the temperature is above 300 C, which can be attributed to the synergistic lubricating action of metallic Mo and AgVO{sub 3} lubricants. Furthermore, Raman results indicated that the composition on the worn surface of NiAl-based composites was self-adjusted after wear testing at different temperatures. For example, Ag{sub 3}VO{sub 4} and Fe{sub 3}O{sub 4} lubricants were responsible for the improvement of tribological properties at 500 C, AgVO{sub 3}, Ag{sub 3}VO{sub 4} and molybdate for 700 C, and AgVO{sub 3} and molybdate for 900 C of NiAl-based composites with the addition of metallic Mo and AgVO{sub 3}. - Highlights: NiAl/Mo-AgVO{sub 3} nanocomposites were prepared by mechanical alloying and sintering. AgVO{sub 3} decomposed to metallic Ag and vanadium oxide during the sintering process. NiAl/Mo-AgVO{sub 3} exhibited superior tribological properties at a board temperature range. Phase composition on the worn surface was varied with temperatures. Self-adjusted action was responsible for the improvement of tribological properties.

  17. New Generation of MoSx Based Solid Lubricant Coatings: Recent Developments and Applications

    SciTech Connect (OSTI)

    Haider, Julfikar; Hashmi, M. S. J.

    2011-01-17

    In recent times, there is a growing interest in applying Molybdenum disulphide (MoS{sub x}) solid lubricant coatings on components to improve the tribological performance (i.e. lower friction coefficient and wear rate). The tribological performance of MoS{sub x} coating is strongly dependent on coating properties and tribological environment. MoS{sub x} coatings are highly successful in certain applications such as in space/vacuum technology, but its effectiveness is questioned in other terrestrial applications such as in cutting tool industry due to its lower hardness and poor oxidation resistance leading to shorter life. In order to circumvent this drawback, the paper identifies that current research is being concentrated on developing MoS{sub x} based coatings using three different approaches: (1) Metal or compound addition in MoS{sub x} coating (2)MoS{sub x} layer on hard coating and (3)MoS{sub x} addition in hard coating matrix. Although the primary objective is same in all three cases, the third approach is considered to be more effective in improving the tribological properties of the coating. Finally, the potential applications of MoS{sub x} based coatings in different industrial sectors have been briefly outlined.

  18. Lubricant-Infused Nanoparticulate Coatings Assembled by Layer-by-Layer Deposition

    SciTech Connect (OSTI)

    Sunny, S; Vogel, N; Howell, C; Vu, TL; Aizenberg, J

    2014-09-01

    Omniphobic coatings are designed to repel a wide range of liquids without leaving stains on the surface. A practical coating should exhibit stable repellency, show no interference with color or transparency of the underlying substrate and, ideally, be deposited in a simple process on arbitrarily shaped surfaces. We use layer-by-layer (LbL) deposition of negatively charged silica nanoparticles and positively charged polyelectrolytes to create nanoscale surface structures that are further surface-functionalized with fluorinated silanes and infiltrated with fluorinated oil, forming a smooth, highly repellent coating on surfaces of different materials and shapes. We show that four or more LbL cycles introduce sufficient surface roughness to effectively immobilize the lubricant into the nanoporous coating and provide a stable liquid interface that repels water, low-surface-tension liquids and complex fluids. The absence of hierarchical structures and the small size of the silica nanoparticles enables complete transparency of the coating, with light transmittance exceeding that of normal glass. The coating is mechanically robust, maintains its repellency after exposure to continuous flow for several days and prevents adsorption of streptavidin as a model protein. The LbL process is conceptually simple, of low cost, environmentally benign, scalable, automatable and therefore may present an efficient synthetic route to non-fouling materials.

  19. Rolling contact fatigue in high vacuum using ion plated nickel-copper-silver solid lubrication

    SciTech Connect (OSTI)

    Danyluk, Mike; Dhingra, Anoop

    2011-01-15

    Ion plated, nickel-copper-silver coated steel ball bearings that were tested in rolling contact fatigue (RCF) experiments in high vacuum are presented in this article. ANSI T5 ball bearings were coated with approximately 10 nm of nickel-copper followed by 100 nm of silver using a dc ion plating process. The balls were then tested for RCF in vacuum in the 10{sup -7} Torr range at 130 Hz rotational speed and at 4.1 GPa Hertzian contact stress. The significance of this work is in the extension of RCF testing to an ultrahigh vacuum (UHV) application using silver as a lubricant instead of oil. The effects of pressure and voltage on the ion plating process were also investigated using scanning electron microscopy and RCF life testing in UHV. Test results with a ball size of 5/16 in. in UHV show that deposition at voltages greater than 2.5 kV shortens the RCF life and introduces a unique failure mode. Voltage and pressure fluctuations during the deposition process result in significant thickness monitor measurement errors as well. A regulator control scheme that minimizes the process pressure overshoot is also simulated.

  20. Probing the molecular design of hyper-branched aryl polyesters towards lubricant applications

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Robinson, Joshua W.; Zhou, Yan; Bhattacharya, Priyanka; Erck, Robert; Qu, Jun; Bays, J. Timothy; Cosimbescu, Lelia

    2016-01-05

    We report novel polymeric materials that may be used as viscosity index improvers (VII) for lubricant applications. Our efforts included probing the comb-burst hyper-branched aryl polyester architecture for beneficial viscosity and friction behavior when utilized as an additive in a group I oil. The monomer was designed as to undergo polymerization via polycondensation within the architectural construct (AB2), typical of hyperbranched polymers. The monomer design was comprised of aliphatic arms (12 or 16 methylenes) to provide the necessary lipophilicity to achieve solubility in a non-polar medium. Once polymerized, via catalyst and heat, the surface alcohols were functionalized with fatty acidsmore » (lauric and palmitic). Controlling the aliphatic nature of the internal arms and peripheral end-groups provided four unique flexible polymer designs. Changing the reaction time and concentration provided opportunities to investigate the influence of molecular weight and branching density on oil-solubility, viscosity, and friction. Oil-solubility was found to decrease with fewer internal carbons, but the number of internal carbons appears to have little influence on the bulk solution viscosity. Increased branching and degree of polymerization, and thus molecular weight, were found to reduce the solubility of these systems in the base oil. At concentrations of 2 wt % in a group I base oil, these polymer additives demonstrated improved viscosity index and reduced friction coefficient, validating the basic approach.« less

  1. Generation of defects in model lubricant monolayers and their contribution to energy dissipation in friction

    SciTech Connect (OSTI)

    Salmeron, Miquel

    2000-06-15

    The structural, mechanical (friction) and spectroscopic properties of model lubricant films made of self-assembled and Langmuir-Blodgett monolayers on quartz, mica and gold have been investigated with atomic force microscopy, surface forces apparatus and sum frequency generation. In these films, the molecules tend to form densely packed structures, with the alkane chains mostly vertical and parallel to each other. The SFG results suggest that under moderate pressures of a few tens of MPa, the methyl end group of the alkane chains is rotated to accommodate a terminal gauche distortion. The molecule,however, retains its upright close packed structure with a lattice periodicity when ordered, which can be resolved by AFM. At pressures above 0.1 GPa, changes in the form of collective molecular tilts take place that lower the height of the monolayer. Only certain angles of tilt are allowed that are explained by the interlocking of methylene units in neighboring chains. The discrete angular tilts are accompanied by increases in friction. A model based on the van derWaals attractive energy between chains is used to explain the stability of the films and to estimate the cohesive energy changes during tilt and, from that, the increases in friction force.

  2. Lubricant-infused nanoparticulate coatings assembled by layer-by-layer deposition

    SciTech Connect (OSTI)

    Sunny, Steffi; Vogel, Nicolas; Howell, Caitlin; Vu, Thy L.; Aizenberg, Joanna

    2014-09-01

    Omniphobic coatings are designed to repel a wide range of liquids without leaving stains on the surface. A practical coating should exhibit stable repellency, show no interference with color or transparency of the underlying substrate and, ideally, be deposited in a simple process on arbitrarily shaped surfaces. We use layer-by-layer (LbL) deposition of negatively charged silica nanoparticles and positively charged polyelectrolytes to create nanoscale surface structures that are further surface-functionalized with fluorinated silanes and infiltrated with fluorinated oil, forming a smooth, highly repellent coating on surfaces of different materials and shapes. We show that four or more LbL cycles introduce sufficient surface roughness to effectively immobilize the lubricant into the nanoporous coating and provide a stable liquid interface that repels water, low-surface-tension liquids and complex fluids. The absence of hierarchical structures and the small size of the silica nanoparticles enables complete transparency of the coating, with light transmittance exceeding that of normal glass. The coating is mechanically robust, maintains its repellency after exposure to continuous flow for several days and prevents adsorption of streptavidin as a model protein. As a result, the LbL process is conceptually simple, of low cost, environmentally benign, scalable, automatable and therefore may present an efficient synthetic route to non-fouling materials.

  3. Cold starting capabilities of petroleum and syntehetic lubricants in heavy-duty diesel engines

    SciTech Connect (OSTI)

    Margeson, M.A.; Belmesch, B.J. )

    1989-01-01

    The objective of the work described in this paper was to compare the cold weather starting ability of diesel engines lubricated with SAE 15W-40 petroleum and SAE 5W-30 synthetic motor oil. Laboratory bench tests were used to compare rhelogical features such as borderline pumping temperature and cold cranking simulator profiles. A cold box provided a well controlled environment in which cranking and starting studies were carried out on the two oils in a turbocharged diesel engine. The SAE 5W-30 synthetic exhibited higher cranking speeds, lower starter amperage draw and immediate oil pressure readings when compared to the SAE l5W-40 petroleum. The SAE 5W-30 synthetic oil was safely started at {minus} l0 {sup 0}F oil temperature without auxiliary heaters. The comparative cylinder turbocharged diesel engines representing conditions commonly found in the commercial and off-highway sectors, These studies indicate that combining high capacity cold cranking amperage batteries, high pressure ether aid injection, and SAE 5W-30 synthetic oil resulted in a system that safely starts diesel engines down to actual oil temperatures of at least {minus} 10 {sup 0}F.

  4. Lubricant-infused nanoparticulate coatings assembled by layer-by-layer deposition

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sunny, Steffi; Vogel, Nicolas; Howell, Caitlin; Vu, Thy L.; Aizenberg, Joanna

    2014-09-01

    Omniphobic coatings are designed to repel a wide range of liquids without leaving stains on the surface. A practical coating should exhibit stable repellency, show no interference with color or transparency of the underlying substrate and, ideally, be deposited in a simple process on arbitrarily shaped surfaces. We use layer-by-layer (LbL) deposition of negatively charged silica nanoparticles and positively charged polyelectrolytes to create nanoscale surface structures that are further surface-functionalized with fluorinated silanes and infiltrated with fluorinated oil, forming a smooth, highly repellent coating on surfaces of different materials and shapes. We show that four or more LbL cycles introducemore » sufficient surface roughness to effectively immobilize the lubricant into the nanoporous coating and provide a stable liquid interface that repels water, low-surface-tension liquids and complex fluids. The absence of hierarchical structures and the small size of the silica nanoparticles enables complete transparency of the coating, with light transmittance exceeding that of normal glass. The coating is mechanically robust, maintains its repellency after exposure to continuous flow for several days and prevents adsorption of streptavidin as a model protein. As a result, the LbL process is conceptually simple, of low cost, environmentally benign, scalable, automatable and therefore may present an efficient synthetic route to non-fouling materials.« less

  5. " Row: NAICS Codes (3-Digit Only); Column...

    U.S. Energy Information Administration (EIA) Indexed Site

    ... and raw" "material inputs for the production of nonenergy products (i.e., asphalt, waxes," "lubricants, and solvents) and feedstock consumption at adjoining petrochemical" ...

  6. Structure-Property Relationships of Polymer Brushes in Restricted Geometries and their Utilization as Ultra-Low Lubricants

    SciTech Connect (OSTI)

    Kuhl, Tonya Lynn; Faller, Roland

    2015-09-28

    Though polymer films are widely used to modify or tailor the physical, chemical and mechanical properties of interfaces in both solid and liquid systems, the rational design of interface- or surface-active polymer modifiers has been hampered by a lack of information about the behavior and structure-property relationships of this class of molecules. This is especially true for systems in which the role of the polymer is to modify the interaction between two solid surfaces in intimate contact and under load, to cause them to be mechanically coupled (e.g. to promote adhesion and wetting) or to minimize their interaction (e.g. lubrication, colloidal stabilization, etc.). Detailed structural information on these systems has largely been precluded by the many difficulties and challenges associated with direct experimental measurements of polymer structure in these geometries. As a result, many practitioners have been forced to employ indirect measurements or rely wholly on theoretical modeling. This has resulted in an incomplete understanding of the structure-property relationships, which are relied upon for the rational design of improved polymer modifiers. Over the course of this current research program, we made direct measurements of the structure of polymers at the interface between two solid surfaces under confinement and elucidated the fundamental physics behind these phenomena using atomistic and coarse grained simulations. The research has potential to lead to new lubricants and wear reducing agents to improve efficiency.

  7. Influence of steel type on the propensity for tribochemical wear in boundary lubrication with a wind turbine gear oil

    SciTech Connect (OSTI)

    Evans, Ryan D.; Doll, Gary L.; Hager, C H; Howe, Jane Y

    2010-01-01

    Tribochemical wear may occur at the interface between a surface and a lubricant as a result of chemical and mechanical interactions in a tribological contact. Understanding the onset of tribochemical wear damage on component surfaces requires the use of high resolution techniques such as transmission electron microscopy (TEM). In this study, two steel types, case carburized AISI 3310 and through-hardened AISI 52100, were wear tested using a ball-on-disk rolling/sliding contact tribometer in fully formulated commercial wind turbine gearbox oil under boundary lubrication conditions with 10% slip. With the exception of steel type, all other test conditions were held constant. Conventional tribofilm analysis in the wear tracks was performed using X-ray photoelectron spectroscopy, and no significant composition differences were detected in the tribofilms for the different steel disk types. However, TEM analysis revealed significant tribochemical wear differences between the two steel types at multiple length scales, from the near-surface material microstructure (depth < 500 nm) to the tribofilm nanostructure. Nanometer-scale interfacial cracking and surface particle detachment was observed for the AISI 52100 case, whereas the tribofilm/substrate interface was abrupt and undamaged for the AISI 3310 case. Differences in tribofilm structure, including the location and orientation of MoS{sub 2} single sheet inclusions, were observed as a function of steel type as well. It is suggested that the tribochemical wear modes observed in these experiments may be origins of macroscopic surface-initiated damage such as micropitting in bearings and gears.

  8. Study of lubricant circulation in HVAC systems. Volume 1: Description of technical effort and results; Final technical report, March 1995--April 1996

    SciTech Connect (OSTI)

    Biancardi, F.R.; Michels, H.H.; Sienel, T.H.; Pandy, D.R.

    1996-10-01

    The purpose of this program was to conduct experimental and analytical efforts to determine lubricant circulation characteristics of new HFC/POE pairs and HFC/mineral oil pairs in a representative central residential HVAC system and to compare their behavior with the traditional HCFC-22/mineral oil (refrigerant/lubricant) pair. A dynamic test facility was designed and built to conduct the experimental efforts. This facility provided a unique capability to visually and physically measure oil circulation rates, on-line, in operating systems. A unique on-line ultraviolet-based measurement device was used to obtain detailed data on the rate and level of lubricant oil circulated within the operating heat pump system. The experimental and analytical data developed during the program are presented as a function of vapor velocity, refrigerant/lubricant viscosity, system features and equipment. Both visual observations and instrumentation were used to understand ``worst case`` oil circulation situations. This report is presented in two volumes. Volume 1 contains a complete description of the program scope, objective, test results summary, conclusions, description of test facility and recommendations for future effort. Volume 2 contains all of the program test data essentially as taken from the laboratory dynamic test facility during the sequence of runs.

  9. Biodiesel Impact on Engine Lubricant Dilution During Active Regeneration of Aftertreatment Systems

    SciTech Connect (OSTI)

    He, X.; Williams, A.; Christensen, E.; Burton, J.; McCormick, R.

    2011-12-01

    Experiments were conducted with ultra low sulfur diesel (ULSD) and 20% biodiesel blends (B20) to compare lube oil dilution levels and lubricant properties for systems using late in-cylinder fuel injection for aftertreatment regeneration. Lube oil dilution was measured by gas chromatography (GC) following ASTM method D3524 to measure diesel content, by Fourier transform infrared (FTIR) spectrometry following a modified ASTM method D7371 to measure biodiesel content, and by a newly developed back-flush GC method that simultaneously measures both diesel and biodiesel. Heavy-duty (HD) engine testing was conducted on a 2008 6.7L Cummins ISB equipped with a diesel oxidation catalyst (DOC) and diesel particle filter (DPF). Stage one of engine testing consisted of 10 consecutive repeats of a forced DPF regeneration event. This continuous operation with late in-cylinder fuel injection served as a method to accelerate lube-oil dilution. Stage two consisted of 16 hours of normal engine operation over a transient test cycle, which created an opportunity for any accumulated fuel in the oil sump to evaporate. Light duty (LD) vehicle testing was conducted on a 2010 VW Jetta equipped with DOC, DPF and a NOx storage catalyst (NSC). Vehicle testing comprised approximately 4,000 miles of operation on a mileage-accumulation dynamometer (MAD) using the U.S. Environmental Protection Agency's Highway Fuel Economy Cycle because of the relatively low engine oil and exhaust temperatures, and high DPF regeneration frequency of this cycle relative to other cycles examined. Comparison of the lube oil dilution analysis methods suggests that D3524 does not measure dilution by biodiesel. The new back-flush GC method provided analysis for both diesel and biodiesel, in a shorter time and with lower detection limit. Thus all lube oil dilution results in this paper are based on this method. Analysis of the HD lube-oil samples showed only 1.5% to 1.6% fuel dilution for both fuels during continuous operation under DPF regeneration events. During the second stage of HD testing, the ULSD lube-oil dilution levels fell from 1.5% to 0.8%, while for B20, lube-oil dilution levels fell from 1.6% to 1.0%, but the fuel in the oil was 36% biodiesel. For the LD vehicle tests, the frequency of DPF regeneration events was observed to be the same for both ULSD and B20. No significant difference between the two fuels' estimated soot loading was detected by the engine control unit (ECU), although a 23% slower rate of increase in differential pressure across DPF was observed with B20. It appears that the ECU estimated soot loading is based on the engine map, not taking advantage of the lower engine-out particulate matter from the use of biodiesel. After 4,000 miles of LD vehicle operation with ULSD, fuel dilution in the lube-oil samples showed total dilution levels of 4.1% diesel. After 4,000 miles of operation with B20, total fuel in oil dilution levels were 6.7% consisting of 3.6% diesel fuel and 3.1% biodiesel. Extrapolation to the 10,000-mile oil drain interval with B20 suggests that the total fuel content in the oil could reach 12%, compared to 5% for operation on ULSD. Analysis of the oil samples also included measurement of total acid number, total base number, viscosity, soot, metals and wear scar; however, little difference in these parameters was noted.

  10. In-tube heat transfer and pressure drop of R-134a and ester lubricant mixtures in a smooth tube and a micro-fin tube. Part 1: Evaporation

    SciTech Connect (OSTI)

    Eckels, S.J.; Doerr, T.M.; Pate, M.B.

    1994-12-31

    In-tube heat transfer coefficients and pressure drops during evaporation are reported for mixtures of refrigerant R-134a and a penta erythritol ester mixed-acid lubricant. The ester lubricant was tested at viscosities of 169 SUS and 369 SUS over a lubricant concentration range of 0% to 5% in both a smooth tube and a micro-fine tube. The average saturation temperature used was 1 C (33.8 F). Measurements were taken for the refrigerant-lubricant mixture over a mass flux range of 85 kg/m{sup 2}{center_dot}s (62,700 lb/ft{sup 2}{center_dot}h) to 375 kg/m{sup 2}{center_dot}s (276,640 lb/ft{sup 2}{center_dot}h) in test tubes with an outer diameter of 9.52 mm (3/8 in.). Heat transfer coefficients during evaporation increased at low concentrations of the 169-SUS ester lubricant and then dropped off at high lubricant concentrations in both the smooth tube and the micro-fin tube. The higher viscosity 369-SUS lubricant decreased the heat transfer coefficients in both tubes over the range of lubricant concentrations tested. Pressure drops during evaporation increased in both the smooth tube and the micro-fin tube with the addition of ester lubricant of either viscosity. The heat transfer coefficients for the micro-fin tube were 100% to 50% higher than those for the smooth tube, with the higher values occurring at low mass fluxes. Pressure drops in the micro-fin tube were 10% to 20% higher than those in the smooth tube.

  11. Additive for lubricants and hydrocarbon fuels comprising reaction products of olefins, sulfur, hydrogen sulfide and nitrogen containing polymeric compounds

    SciTech Connect (OSTI)

    Horodysky, A.G.; Law, D.A.

    1987-04-28

    A process is described for making an additive for lubricant compositions comprising co-reacting: a monoolefin selected from the group consisting of butenes, propenes, pentenes, and mixtures of two or more thereof; sulfur; hydrogen sulfide; polymeric nitrogen-containing compound selected from the group consisting of succinimides, amides, imides, polyoxyazoline polymers and alkyl imidazoline compounds; and a catalytic amount of an amine selected from the group consisting of polyethylene amines and hydroxyl-containing amines; at a temperature between about 130/sup 0/C and about 200/sup 0/C and a pressure of about 0 psig to about 900 psig, the reactants being reacted in a molar ratio of olefin, polymeric nitrogen-containing compound, and hydrogen sulfide to sulfur of 2 to 0.5, 0.001 to 0.4, and 0.5 to 0.7, respectively, and the concentration of amine being between 0.5 and 10 percent of the total weight of reactants.

  12. Third-Party Evaluation of Petro Tex Hydrocarbons, LLC, ReGen Lubricating Oil Re-refining Process

    SciTech Connect (OSTI)

    Compere, A L; Griffith, William {Bill} L

    2009-04-01

    This report presents an assessment of market, energy impact, and utility of the PetroTex Hydrocarbons, LLC., ReGen process for re-refining used lubricating oil to produce Group I, II, and III base oils, diesel fuel, and asphalt. PetroTex Hydrocarbons, LLC., has performed extensive pilot scale evaluations, computer simulations, and market studies of this process and is presently evaluating construction of a 23 million gallon per year industrial-scale plant. PetroTex has obtained a 30 acre site in the Texas Industries RailPark in Midlothian Texas. The environmental and civil engineering assessments of the site are completed, and the company has been granted a special use permit from the City of Midlothian and air emissions permits for the Texas Commission on Environmental Quality.

  13. The Development of Open Water-lubricated Polycrystalline Diamond (PCD) Thrust Bearings for Use in Marine Hydrokinetic (MHK) Energy Machines

    SciTech Connect (OSTI)

    Cooley, Craig, H.; Khonsari, Michael,, M; Lingwall, Brent

    2012-11-28

    Polycrstalline diamond (PCD) bearings were designed, fabricated and tested for marine-hydro-kinetic (MHK) application. Bearing efficiency and life were evaluated using the US Synthetic bearing test facility. Three iterations of design, build and test were conducted to arrive at the best bearing design. In addition life testing that simulated the starting and stopping and the loading of real MHK applications were performed. Results showed polycrystalline diamond bearings are well suited for MHK applications and that diamond bearing technology is TRL4 ready. Based on life tests results bearing life is estimated to be at least 11.5 years. A calculation method for evaluating the performance of diamond bearings of round geometry was also investigated and developed. Finally, as part of this effort test bearings were supplied free of charge to the University of Alaska for further evaluation. The University of Alaska test program will subject the diamond bearings to sediment laden lubricating fluid.

  14. CHARACTERIZATION AND TRIBOLOGICAL EVALUATION OF 1-BENZYL-3-METHYLIMIDAZOLIUM BIS(TRIFLUOROMETHYLSULFONYL)IMIDE AS NEAT LUBRICANT AND OIL ADDITIVE

    SciTech Connect (OSTI)

    Bansal, Dinesh G; Qu, Jun; Yu, Bo; Luo, Huimin; Dai, Sheng; Bunting, Bruce G; Blau, Peter Julian; Mordukhovich, Gregory; Smolenski, Donald

    2011-01-01

    Selected physical and chemical properties and tribological data for a newly-developed, imidazolium-based ionic liquid (IL) are presented. The IL is soluble in the SAE 5W-30 oil up to a certain weight percentage, and is as a promising candidate for use in lubrication applications, either in its neat version or as an oil additive. Characterization of the IL included dynamic viscosity at different temperatures, corrosion effects on cast iron cylinder liners, and thermal stability analysis. The tribological performance was evaluated using a reciprocating ring-on-liner test arrangement. When used in neat version this IL demonstrated friction coefficient comparable to a fully formulated engine oil, and when used as an oil additive it produced less wear.

  15. Influence of lubricant oil on heat transfer performance of refrigerant flow boiling inside small diameter tubes. Part II: Correlations

    SciTech Connect (OSTI)

    Wei, Wenjian; Ding, Guoliang; Hu, Haitao; Wang, Kaijian

    2007-10-15

    The predictive ability of the available state-of-the-art heat transfer correlations of refrigerant-oil mixture is evaluated with the present experiment data of small tubes with inside diameter of 6.34 mm and 2.50 mm. Most of these correlations can be used to predict the heat transfer coefficient of 6.34 mm tube, but none of them can predict heat transfer coefficient of 2.50 mm tube satisfactorily. A new correlation of two-phase heat transfer multiplier with local properties of refrigerant-oil mixture is developed. This correlation approaches the actual physical mechanism of flow boiling heat transfer of refrigerant-oil mixture and can reflect the actual co-existing conditions of refrigerant and lubricant oil. More than 90% of the experiment data of both test tubes have less than {+-}20% deviation from the prediction values of the new correlations. (author)

  16. Large-scale Manufacturing of Nanoparticulate-based Lubrication Additives for Improved Energy Efficiency and Reduced Emissions

    SciTech Connect (OSTI)

    Erdemir, Ali

    2013-09-26

    This project was funded under the Department of Energy (DOE) Lab Call on Nanomanufacturing for Energy Efficiency and was directed toward the development of novel boron-based nanocolloidal lubrication additives for improving the friction and wear performance of machine components in a wide range of industrial and transportation applications. Argonne's research team concentrated on the scientific and technical aspects of the project, using a range of state-of-the art analytical and tribological test facilities. Argonne has extensive past experience and expertise in working with boron-based solid and liquid lubrication additives, and has intellectual property ownership of several. There were two industrial collaborators in this project: Ashland Oil (represented by its Valvoline subsidiary) and Primet Precision Materials, Inc. (a leading nanomaterials company). There was also a sub-contract with the University of Arkansas. The major objectives of the project were to develop novel boron-based nanocolloidal lubrication additives and to optimize and verify their performance under boundary-lubricated sliding conditions. The project also tackled problems related to colloidal dispersion, larger-scale manufacturing and blending of nano-additives with base carrier oils. Other important issues dealt with in the project were determination of the optimum size and concentration of the particles and compatibility with various base fluids and/or additives. Boron-based particulate additives considered in this project included boric acid (H{sub 3}BO{sub 3}), hexagonal boron nitride (h-BN), boron oxide, and borax. As part of this project, we also explored a hybrid MoS{sub 2} + boric acid formulation approach for more effective lubrication and reported the results. The major motivation behind this work was to reduce energy losses related to friction and wear in a wide spectrum of mechanical systems and thereby reduce our dependence on imported oil. Growing concern over greenhouse gas emissions was also a major reason. The transportation sector alone consumes about 13 million barrels of crude oil per day (nearly 60% of which is imported) and is responsible for about 30% of the CO{sub 2} emission. When we consider manufacturing and other energy-intensive industrial processes, the amount of petroleum being consumed due to friction and wear reaches more than 20 million barrels per day (from official energy statistics, U.S. Energy Information Administration). Frequent remanufacturing and/or replacement of worn parts due to friction-, wear-, and scuffing-related degradations also consume significant amounts of energy and give rise to additional CO{sub 2} emission. Overall, the total annual cost of friction- and wear-related energy and material losses is estimated to be rather significant (i.e., as much as 5% of the gross national products of highly industrialized nations). It is projected that more than half of the total friction- and wear-related energy losses can be recovered by developing and implementing advanced friction and wear control technologies. In transportation vehicles alone, 10% to 15% of the fuel energy is spent to overcome friction. If we can cut down the friction- and wear-related energy losses by half, then we can potentially save up to 1.5 million barrels of petroleum per day. Also, less friction and wear would mean less energy consumption as well as less carbon emissions and hazardous byproducts being generated and released to the environment. New and more robust anti-friction and -wear control technologies may thus have a significant positive impact on improving the efficiency and environmental cleanliness of the current legacy fleet and future transportation systems. Effective control of friction in other industrial sectors such as manufacturing, power generation, mining and oil exploration, and agricultural and earthmoving machinery may bring more energy savings. Therefore, this project was timely and responsive to the energy and environmental objectives of DOE and our nation. In this project, most of the boron-based materials with known and potential anti-friction and -wear properties have been manufactured as colloidal additives and tested for their effectiveness in controlling friction and wear. Unlike other anti-friction and -wear additives, which consist of zinc, molybdenum, sulfur, phosphorus, and even chlorine, lubricious boron compounds considered in this project are made of boron, oxygen, nitrogen, and hydrogen, which are more environmentally benign. Among others, boric acid is a natural mineral (known in mineralogy as "sassolite"). Based on our earlier exploratory research, it was found to offer the best overall prospect in terms of performance improvements, environmental friendliness, and ease of manufacturing and, hence, cost effectiveness. Hexagonal boron nitride and borax also offered good prospects for improving the tribological properties of lubricated sliding surfaces. Boron oxide particles were found to be rather hard and somewhat abrasive and, hence, were not considered beyond the initial screening studies. In our bench-top tribological evaluation, we also demonstrated that those additives which worked well with engine oils could work equally well with very common gear oils. When added at appropriate concentrations, such gear oils were found to provide significant resistance to micropitting and scuffing failures in bench-top tribological test systems. Their traction coefficients were also reduced substantially and their scuffing limits were improved considerably. Such impressive tribological behavior of boron-based additives may have been due to their high chemical affinities to interact with sliding contact surfaces and to form slick and protective boundary films. Indeed, our surface studies have confirmed that most of the boron-based nanoparticulate additives prepared in our project possess a strong tendency to form a boron-rich boundary film on sliding contact surfaces. It is believed that the formation of such slick and highly durable boundary films is perhaps one of the fundamental reasons for their superior anti-friction, -wear, and -scuffing performance. Boron-based additives developed under this project have shown potential to reduce or replace the uses of environmentally unsafe sulfur- and phosphorus-bearing anti-wear and friction additives, such as zinc dialkyl dithiophosphate (ZDDP) and molybdenum dialkyl dithiocarbamate (MoDTC), in current lubricating oils. Because ZDDP and MoDTC were suspected of adversely impacting the performance of after-treatment catalysts in current engines, the Environmental Protection Agency (EPA) and other regulatory agencies are demanding that the concentrations of these catalysts in current oils be curtailed drastically. The boron-based nano-additives developed in this project may help reduce the use of ZDDP and MoDTC additives and, hence, help ease the poisoning effects on after-treatment catalysts. When used as lubricity additives, these boron additives can chemically interact with sliding or contacting surfaces and form a protective and slick boundary film, which can, in turn, help reduce friction and wear and increase resistance to scuffing. In the cases of traditional anti-friction and -wear additives mentioned, such protective boundary films result from phosphorus, sulfur, and other elements in the additive package, and again they have been under increased scrutiny in recent years, mainly because of their adverse effects on after-treatment devices. Overall, the boron-based nano-additive technology of this project was shown to hold promise for a broad range of industrial and transportation applications where lower friction and higher resistance to wear and scuffing are needed. Due to more stringent operating conditions of modern machinery, rolling, rotating, and sliding components have been failing to meet the projected lifetimes, mainly because of failures related to mechanical wear, corrosion, and scuffing. The novel boron-based additive technology developed under this project may help such machine components to function reliably by cutting down the friction and wear losses and by increasing resistance to scuffing.

  17. Development of Modified Pag (Polyalkylene Glycol) High VI High Fuel Efficient Lubricant for LDV Applications

    SciTech Connect (OSTI)

    Gangopadhyay, Arup; McWatt, D. G.; Zdrodowski, R. J.; Liu, Zak; Elie, Larry; Simko, S. J.; Erdemir, Ali; Ramirez, Giovanni; Cuthbert, J.; Hock, E. D.

    2015-09-30

    Engine oils play a critical role in friction reduction. Improvements in engine oil technology steadily improved fuel economy as the industry moved through ILSAC GF-1 to GF-5 specifications. These improvements were influenced by changes in base oil chemistry, development of new friction modifiers and their treat levels, and the total additive package consisting of various other components. However, the improvements are incremental and further fuel consumption reduction opportunities are becoming more challenging. Polyalkylene glycol (PAG) based engine oils are being explored as a step forward for significant fuel consumption reduction. Although PAG fluids are used in many industrial applications, its application as an engine oil has been explored in a limited way. The objective of this project is to deep dive in exploring the applicability of PAG technology in engine oil, understanding the benefits, and limitations, elucidating the mechanism(s) for friction benefits, if any, and finally recommending how to address any limitations. The project was designed in four steps, starting with selection of lubricant technology, followed by friction and wear evaluations in laboratory bench tests which are relatively simple and inexpensive and also served as a screener for further evaluation. Selected formulations were chosen for more complex engine component level tests i.e., motored valvetrain friction and wear, piston ring friction using a motored single cylinder, and motored engine tests. A couple of formulations were further selected based on component level tests for engine dyno tests i.e., Sequence VID (ASTM D6709) for fuel economy, Sequence IVA (ASTM D6891) for valvetrain wear, and Sequence VG (ASTM D6593) for sludge and varnish protection. These are some of the industry standard tests required for qualifying engine oils. Out of these tests, a single PAG oil was selected for chassis roll dynamometer tests for fuel economy and emission measurements using FTP (Federal Test Procedure) metro/highway cycles. Five different PAG chemistries were selected by varying the starting alcohol, the oxide monomers (ethylene oxide, propylene oxide, or butylene oxide), capped or uncapped, homopolymer or random copolymer. All formulations contained a proprietary additive package and one which contained additional antiwear and friction modifier additives. Laboratory bench tests (Pin-on-Disk, High Frequency Reciprocating Rig (HFRR), Block-on-Ring, Mini-Traction Machine (MTM) identified formulations having friction, wear, and load carrying characteristics similar to or better than baseline GF-5 SAE 5W-20 oil. Motored valvetrain and motored piston ring friction tests showed nearly 50% friction reduction for some of the PAG formulations compared to GF-5 SAE 5W-20 oil. Motored engine tests showed up to 15% friction benefit over GF-5 SAE 5W-20 oil. It was observed that friction benefits are more related to PAG base oil chemistry than their lower viscosity compared to GF-5 SAE 5W-20 oil. Analysis of wear surfaces from laboratory bench tests and bucket tappets from motored valvetrain tests confirmed the presence of PAG molecules. The adsorption of these polar molecules is believed to be reason for friction reduction. However, the wear surfaces also had thin tribo-film derived from additive components. The tribo-film consisting of phosphates, sulfides, and molybdenum disulfide (when molybdenum additive was present) were observed for both GF-5 SAE 5W-20 and PAG fluids. However, when using PAG fluids, motored valvetrain tests showed high initial wear, which is believed to be due to delay in protective tribo-film formation. After the initial wear, the wear rate of PAG fluids was comparable to GF-5 SAE 5W-20 oil. The PAG oil containing additional antiwear and friction reducing additives showed low initial wear as expected. However, when this oil was evaluated in Sequence IVA test, it showed initially low wear comparable to GF-5 oil but wear accelerated with oil aging indicating rapid deterioration of additive components. ASTM Sequence VG test showed good sludge protection capability but failed to meet varnish rating for GF-5 requirement. Chassis roll dynamometer tests with PAG oil 15-1 showed about 1% fuel economy benefit over GF-5 SAE 5W-20 oil in EPA city cycles only and when the oil was slightly aged (500 miles). No fuel economy benefits could be observed in combined EPA metro/highway cycles. Also, no fuel economy benefit could be observed with continued (500- 10000 miles) oil aging. However, the emission level was comparable to the reference oil and was within EPA limits. Analysis of the PAG oil following tests showed low iron content although additive components were significantly degraded. The results indicate that PAG fluids have significant friction reduction potential but there are challenges with wear and varnish protection capabilities. These limitations are primarily because the selected additive components were chosen to provide a fluid with no metal content that forms little or no sulphated ash. Significant development work is needed to identify additive components compatible with PAG chemistry including their solubility in PAG oil. Miscibility of PAG fluids with mineral base oil is another challenge for oil change service. There is PAG chemistry (oil soluble PAG, OSP) which is soluble in mineral oils but the formulation explored in this investigation did not show significant friction reduction in motored engine tests. Again, highlighting the need for additive development for specific PAG chemistry. The thermal oxidation behavior of these oils has not been explored in this investigation and needs attention.

  18. Determination of the tribological fundamentals of solid lubricated ceramics. Volume 2. Appendices A through O. Final report, 9 Sep 85-16 Sep 89

    SciTech Connect (OSTI)

    Gardos, M.N.

    1991-09-01

    The goals, structure and highlights of a recently completed multiyear/multinational research program are described. The main driving force behind this effort was the aim to advance the technology base so engineers can design, build and operate solid lubricated ceramic tribocomponents in extreme environments. Specially designed friction and wear testers were employed to perform well-defined model experiments on single crystal and polycrystalline ceramics and solid lubricants. The research led to discoveries such as (1) a lubricious oxide with the shear strength of molybdenum disulfide in vacuum, (2) CVD diamond films with low friction and extraordinarily low wear, (3) intercalated graphites with high tribothermal resistance in vacuum and in air, and (4) a wear equation for silicon nitride ceramics.

  19. Influence of process parameters on rolling-contact-fatigue life of ion plated nickel-copper-silver lubrication

    SciTech Connect (OSTI)

    Danyluk, Mike; Dhingra, Anoop

    2012-05-15

    In this paper, we present a connection between argon ion flux, element-mixing, and rolling contact fatigue (RCF) life of a thin film nickel-copper-silver lubricant on ball bearings. The film is deposited on the balls using an ion plating process and tested for RCF in high vacuum. The ion flux is measured using a Langmuir probe and the plane stress within the film during deposition is calculated using a thin film model. Experiments reveal that there is an inverse relationship between ion flux and RCF life for most deposition voltage and pressure combinations tested, specifically, 15.5-18.5 mTorr and 1.5-3.5 kV. For voltages up to 2.5 kV, RCF life decreases as ion flux increases due to increased compressive stress within the film, reaching as high as 2.6 GPa. For voltages between 2.5 and 3.5 kV, interlayer mixing of nickel and copper with the silver layer reduces RCF life due to contamination, even as ion flux and corresponding film compressive stress are reduced. A Monte Carlo-based simulation tool, SRIM is used to track collision cascades of the argon ions and metal atoms within the coating layers. At process voltages above 2.5 kV we observe elemental mixing of copper and nickel with the silver layer using Auger electron spectroscopy of coated steel and Si{sub 3}N{sub 4} balls. The authors conclude that an ion flux greater than 5.0 x 10{sup 14} cm{sup -2} s{sup -1} leads to reduced RCF life due to high film stress. In addition, process voltages greater than 2.5 kV also reduce RCF life due to contamination and interlayer mixing of nickel and copper within the silver layer.

  20. Oxygen Diffusion Enables Anti-Wear Boundary Film Formation on Titanium Surfaces in Zinc-Dialkyl-Dithiophosphate (ZDDP)-Containing Lubricants

    SciTech Connect (OSTI)

    Qu, Jun; Blau, Peter Julian; Howe, Jane Y; Meyer III, Harry M

    2009-01-01

    This paper reports a wear reduction by up to six orders of magnitude for Ti-6Al-4V alloy when treated by an oxygen diffusion (OD) process and subsequently tested in a zinc-dialkyl-dithiophosphate (ZDDP)-containing lubricant. In addition to case hardening, it is discovered that OD enables the formation of an anti-wear boundary film on the titanium surface. Transmission electron microscopy and surface chemical analyses revealed that this boundary film has a two-layer structure comprising an amorphous oxide interlayer and a ZDDP-based top film with complex compounds.

  1. NOVEL LUBRICANT ADDITIVES

    Energy Innovation Portal (Marketing Summaries) [EERE]

    2013-07-16

    , JohnWiley and Sons 2008.; Matsumoto, N.,Mistry, K., Kim, J.H., Eryilmaz, O. L., Erdemir, A., Kinoshita, H. and Ohmae, N...

  2. Boundary Layer Lubrication Mechanisms

    Broader source: Energy.gov [DOE]

    2010 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C.

  3. Boundary Layer Lubrication

    Broader source: Energy.gov [DOE]

    2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C.

  4. Lubricated boride surfaces

    DOE Patents [OSTI]

    Erdemir, A.; Bindal, C.; Fenske, G.R.

    1998-11-24

    Ultralow friction properties are available through the annealation and subsequent cooling of various boron-containing substrates, articles and/or components. 16 figs.

  5. Lubricated boride surfaces

    DOE Patents [OSTI]

    Erdemir, Ali; Bindal, Cuma; Fenske, G. R.

    1998-01-01

    Ultralow friction properties available through the annealation and subsequent cooling of various boron-containing substrates, articles and/or components.

  6. Feasibility of observing small differences in friction mean effective pressure between different lubricating oil formations using small, single-cylinder motored engine rig

    SciTech Connect (OSTI)

    Rohr, William F.; Nguyen, Ke; Bunting, Bruce G.; Qu, Jun

    2015-09-01

    Here, the feasibility of using a motored single-cylinder 517 cc diesel engine to observe small frictional differences between oil formulations is investigated. Friction mean effective pressure (FMEP) is measured and compared for an SAE 10W-30 and an SAE 5W-20 oil in three stages of production: base oil, commercial oil without a friction and wear reducing additive, and fully formulated commercial oil. In addition, a commercial SAE 5W-30 engine oil is investigated. Friction mean effective pressure is plotted versus oil dynamic viscosity to compare the lubricant FMEP at a given viscosity. Linear regressions and average friction mean effective pressure are used as a secondary means of comparing FMEP for the various oil formulations. Differences between the oils are observed with the base oil having higher friction at a given viscosity but a lower average FMEP due to the temperature distribution of the test and lower viscosities reached by the base oil. The commercial oil is shown to have both a higher FMEP at a given viscosity and a higher average FMEP than the commercial oil without a friction and wear reducing additive. The increase in friction for the oil without a friction and wear reduction additive indicates that the operational regime of the engine may be out of the bounds of the optimal regime for the additive or that the additive is more optimized for wear reduction. Results show that it is feasible to observe small differences in FMEP between lubricating oil formulations using a small, single-cylinder motored engine.

  7. Feasibility of observing small differences in friction mean effective pressure between different lubricating oil formations using small, single-cylinder motored engine rig

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Rohr, William F.; Nguyen, Ke; Bunting, Bruce G.; Qu, Jun

    2015-09-01

    Here, the feasibility of using a motored single-cylinder 517 cc diesel engine to observe small frictional differences between oil formulations is investigated. Friction mean effective pressure (FMEP) is measured and compared for an SAE 10W-30 and an SAE 5W-20 oil in three stages of production: base oil, commercial oil without a friction and wear reducing additive, and fully formulated commercial oil. In addition, a commercial SAE 5W-30 engine oil is investigated. Friction mean effective pressure is plotted versus oil dynamic viscosity to compare the lubricant FMEP at a given viscosity. Linear regressions and average friction mean effective pressure are usedmore » as a secondary means of comparing FMEP for the various oil formulations. Differences between the oils are observed with the base oil having higher friction at a given viscosity but a lower average FMEP due to the temperature distribution of the test and lower viscosities reached by the base oil. The commercial oil is shown to have both a higher FMEP at a given viscosity and a higher average FMEP than the commercial oil without a friction and wear reducing additive. The increase in friction for the oil without a friction and wear reduction additive indicates that the operational regime of the engine may be out of the bounds of the optimal regime for the additive or that the additive is more optimized for wear reduction. Results show that it is feasible to observe small differences in FMEP between lubricating oil formulations using a small, single-cylinder motored engine.« less

  8. The tribology of PS212 coatings and PM212 composites for the lubrication of titanium 6A1-4V components of a Stirling engine space power system

    SciTech Connect (OSTI)

    Sliney, H.E.; Dellacorte, C.; Lukaszewicz, V. |

    1995-07-01

    The Stirling space power machine incorporates a linear alternator to generate electrical power. The alternator is a reciprocating device that is driven by a solar or nuclear-powered Stirling engine. The power piston and cylinder are made of titanium 6A1-4V (Ti6-4) alloy, and are designed to be lubricated by a hydrodynamically-generated gas film. Rubbing occurs during starts and stops and there is a possibility of an occasional high speed rub. Since titanium is known to have a severe galling tendency in sliding contacts, a `backup,` self-lubricating coating on the cylinder and/or the piston is needed. This report describes the results of a research program to study the lubrication of Ti6-4 with the following chromium carbide based materials: plasma-sprayed PS212 coatings and sintered PM212 counterfaces. Program objectives are to achieve adherent coatings on Ti6-4 and to measure the friction and wear characteristics of the following sliding combinations under conditions simulative of the Stirling-driven space power linear alternator: Ti6-4/Ti6-4 baseline, Ti6-4/PS212 coated Ti6-4, and Ps212 coated Ti6-4/PM212

  9. Bataan naphtha cracker project. Final report prepared for PNOC Petrochemical Development Corporation (PPDC). Export trade information

    SciTech Connect (OSTI)

    1997-05-01

    The study, conducted by Chem Systems, was funded by the U.S. Trade and Development agency. The final report determines the feasibility of an ethylene/polyethylene facility in the Philippines. The study is divided into the following sections: (1) Executive Summary; (2) Technical Description; (3) Implementation Plan; (4) Feasibility Study; (5) Licensor Status; (6) Recommended Contract Principles; (7) Recommended Olefins Pricing Basis; (8) Clarifications/Discussion of Issues; (9) Appendix.

  10. Fuels & Lubricants R&D

    Broader source: Energy.gov [DOE]

    2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Vehicle Technologies Plenary

  11. Table 1.15 Non-Combustion Use of Fossil Fuels, 1980-2011

    U.S. Energy Information Administration (EIA) Indexed Site

    5 Non-Combustion Use of Fossil Fuels, 1980-2011 Year Petroleum Products Natural Gas 4 Coal Total Percent of Total Energy Consumption Asphalt and Road Oil Liquefied Petroleum Gases 1 Lubricants Petro- chemical Feedstocks 2 Petroleum Coke Special Naphthas Other 3 Total Physical Units 5<//td> 1980 145 230 58 253 14 [R] 37 58 795 [R] 639 2.4 [ – –] [ – –] 1981 125 229 56 216 15 [R] 27 54 722 [R] 518 [R] 2.1 [ – –] [ – –] 1982 125 256 51 157 15 [R] 25 48 678 [R] 448 [R] 1.4 [ – –] [

  12. Word Pro - Untitled1

    U.S. Energy Information Administration (EIA) Indexed Site

    Table 1.15 Non-Combustion Use of Fossil Fuels, Selected Years, 1980-2011 Year Petroleum Products Natural Gas 4 Coal Total Percent of Total Energy Consumption Asphalt and Road Oil Liquefied Petroleum Gases 1 Lubricants Petro- chemical Feedstocks 2 Petroleum Coke Special Naphthas Other 3 Total Physical Units 5 1980 145 230 58 253 R 14 37 58 R 795 639 2.4 - - - - 1985 156 R 278 53 144 R 16 30 41 R 719 500 1.1 - - - - 1990 176 R 373 60 199 20 20 39 R 887 R 567 .6 - - - - 1991 162 R 426 53 203 17 17

  13. Regulatory impact analysis for the petroleum refineries neshap. Draft report

    SciTech Connect (OSTI)

    Not Available

    1994-07-01

    The report analyzes the regulatory impacts of the Petroleum Refinery National Emission Standard for Hazardous Air Pollutants (NESHAP), which is being promulgated under Section 112 of the Clean Air Act Amendments of 1990 (CCA). This emission standard would regulate the emissions of certain hazardous air pollutants (HAPs) from petroleum refineries. The petroleum refineries industry group includes any facility engaged in the production of motor gasoline, naphthas, kerosene, jet fuels, distillate fuel oils, residual fuel oils, lubricants, or other products made from crude oil or unfinished petroleum derivatives. The report analyzes the impact that regulatory action is likely to have on the petroleum refining industry.

  14. U.S. Imports of Crude Oil and Petroleum Products

    U.S. Energy Information Administration (EIA) Indexed Site

    ... Lubricants 35 27 27 21 33 33 1981-2016 Waxes 8 6 4 3 5 5 1981-2016 Petroleum Coke 13 17 6 1 2 2 1984-2016 Asphalt and Road Oil 29 33 24 19 22 32 1981-2016 Miscellaneous Products 0 ...

  15. fuels and lubricants | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    may increasingly be from non-conventional sources including, but not milted to, heavy crude, oil sands, shale oil, and coal, as well as renewable resources such as biomass, ...

  16. National Agricultural-Based Lubricants (NABL) Center

    SciTech Connect (OSTI)

    Honary, Lou

    2013-09-30

    This project, while defined as a one year project from September 30, 2012 – September 30, 2013, was a continuation of a number of tasks that were defined in previous years. Those tasks were performed and were finalized in this period. The UNI-NABL Center, which has been in operation in various forms since 1991, has closed its facilities since September 2013 and will be phasing out in June 2014. This report covers the individual tasks that were identified in the previous reports and provides closure to each task in its final stage.

  17. Research on Fuels & Lubricants | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    3 DEER Conference Presentation: Penn State University, Tribology Group, Chemical Engineering Dept. PDF icon 2003deerperez.pdf More Documents & Publications Alternative Fuels ...

  18. Fuel & Lubricant Technologies R&D

    Broader source: Energy.gov [DOE]

    2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  19. Understanding diesel engine lubrication at low temperature

    SciTech Connect (OSTI)

    Smith, M.F. Jr.

    1990-01-01

    This paper reports on oil pumpability in passenger car gasoline engines that was well-characterized by an ASTM program and by individual researchers in the 1970's and early 1980's. oil pumpability in diesel engines however, was not investigated to any significant extent until the mid-1980's. This study was initiated to define the performance of several commercial viscosity modifiers in different formulations containing 3 detergent-inhibitor (DI) additive packages and 4 basestock types. The test oils were run at {minus}18{degrees} C (0{degrees} F) in a Cummins NTC-400 diesel engine. The results, when statistically analyzed, indicated that a new, second generation olefin copolymer (OCP) viscosity modifier has better performance that a first generation OCP and, furthermore, had performance equal to a polymethacrylate (PMA) viscosity modifier. The analysis also showed that one DI/base stock combination had a significant effect on performance. The apparent shear rate of the oil in the pump inlet tube was calculated from the oil pump flow rate measured at idle speed at low temperature and the pump inlet tube diameter. The shear rate and oil viscosity were used to estimate the shear stress in the pump inlet tube. The shear stress level of the engine is 56% higher than the Mini-Rotary Viscometer (MRV). Hence, the current MRV procedure is rheologically unsuitable to predict pumpability in a large diesel engine. A new device was developed for measuring the oil film thickness in the turbocharge bearing and noting the time when a full oil film is formed. Results indicate that a full oil film occurs almost immediately, well before any oil pressure is observed at the turbocharge inlet. Residual oil remaining in the bearing after shutdown may account of this observation. The oil film maintained its thickness both before, and after the first indication of oil pressure. More work is needed to study this effect.

  20. Boundary Layer Lubrication Mechanisms | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Maya Payne Smart Former Writer for Energy Empowers, EERE Constructed from 1931 to 1933, the U.S. Post Office and Courthouse in Boston created quite a buzz with its Art Deco design. A departure from the Classical Revival style popular among federal buildings of the time, its aluminum windows, unadorned granite and limestone base and stepped parapets illustrated its modernity. But over time, the building once hailed for its forward-thinking design grew weary and only an overhaul could restore its

  1. Fabrics coated with lubricated nanostructures display robust...

    Office of Scientific and Technical Information (OSTI)

    GrantContract Number: AR0000326 Type: Accepted Manuscript Journal Name: Nanotechnology (Print) Additional Journal Information: Journal Name: Nanotechnology (Print); Journal ...

  2. Fuel and Lubricant Effects | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    11 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon ft001_bunting_2011_o.pdf More Documents & Publications APBF Effects on Combustion APBF Effects on Combustion Response of Oil Sands Derived Fuels in Diesel HCCI Operation

  3. MHK Projects/Wax Lake Outlet | Open Energy Information

    Open Energy Info (EERE)

    *MHK TechnologiesSmarTurbine Project Licensing FERC License Docket Number P-14254 Environmental Monitoring and Mitigation Efforts See Tethys << Return to the MHK database...

  4. Evaluation of Wax Deposition and its Control during Production...

    Office of Scientific and Technical Information (OSTI)

    ... of the modified model to account for change in heat capacity during the ... A.K.M., J.Nighswander, and N.Joshi, "A Systematic Approach for Characterizing Hydrocarbon ...

  5. EARLY ENTRANCE COPRODUCTION PLANT

    SciTech Connect (OSTI)

    Fred D. Brent; Lalit Shah; Earl Berry; Charles H. Schrader; John Anderson; J. Erwin; Matthew G. Banks; Terry L. Ullman

    2004-01-12

    The overall objective of this project is the three phase development of an Early Entrance Coproduction Plant (EECP) which uses petroleum coke to produce at least one product from at least two of the following three categories: (1) electric power (or heat), (2) fuels, and (3) chemicals using ChevronTexaco's proprietary gasification technology. The objective of Phase I is to determine the feasibility and define the concept for the EECP located at a specific site; develop a Research, Development, and Testing (RD&T) Plan to mitigate technical risks and barriers; and prepare a Preliminary Project Financing Plan. The objective of Phase II is to implement the work as outlined in the Phase I RD&T Plan to enhance the development and commercial acceptance of coproduction technology. The objective of Phase III is to develop an engineering design package and a financing and testing plan for an EECP located at a specific site. The project's intended result is to provide the necessary technical, economic, and environmental information needed by industry to move the EECP forward to detailed design, construction, and operation. The partners in this project are Texaco Energy Systems LLC or TES (a subsidiary of ChevronTexaco), General Electric (GE), Praxair, and Kellogg Brown & Root (KBR) in addition to the U.S. Department of Energy (DOE). TES is providing gasification technology and Fischer-Tropsch (F-T) technology developed by Rentech, GE is providing combustion turbine technology, Praxair is providing air separation technology, and KBR is providing engineering. Each of the EECP subsystems was assessed for technical risks and barriers. A plan was developed to mitigate the identified risks (Phase II RD&T Plan, October 2000). Phase II RD&T Task 2.6 identified as potential technical risks to the EECP the fuel/engine performance and emissions of the F-T diesel fuel products. Hydrotreating the neat F-T diesel product reduces potentially reactive olefins, oxygenates, and acids levels and alleviates corrosion and fuel stability concerns. Future coproduction plants can maximize valuable transportation diesel by hydrocracking the F-T Synthesis wax product to diesel and naphtha. The upgraded neat F-T diesel, hydrotreater F-T diesel, and hydrocracker F-T diesel products would be final blending components in transportation diesel fuel. Phase II RD&T Task 2.6 successfully carried out fuel lubricity property testing, fuel response to lubricity additives, and hot-start transient emission tests on a neat F-T diesel product, a hydrocracker F-T diesel product, a blend of hydrotreater and hydrocracker F-T diesel products, and a Tier II California Air Resources Board (CARB)-like diesel reference fuel. Only the neat F-T diesel passed lubricity inspection without additive while the remaining three fuel candidates passed with conventional additive treatment. Hot-start transient emission tests were conducted on the four fuels in accordance with the U.S. Environmental Protection Agency (EPA) Federal Test Procedure (FTP) specified in Code of Federal Regulations, Title 40, Part 86, and Subpart N on a rebuilt 1991 Detroit Diesel Corporation Series 60 heavy-duty diesel engine. Neat F-T diesel fuel reduced oxides of nitrogen (NO{sub x}), total particulate (PM), hydrocarbons (HC), carbon monoxide (CO), and the Soluble Organic Fraction (SOF) by 4.5%, 31%, 50%, 29%, and 35%, respectively, compared to the Tier II CARB-like diesel. The hydrocracker F-T diesel product and a blend of hydrocracker and hydrotreater F-T diesel products also reduced NO{sub x}, PM, HC, CO and SOF by 13%, 16% to 17%, 38% to 63%, 17% to 21% and 21% to 39% compared to the Tier II CARB-like diesel. The fuel/engine performance and emissions of the three F-T diesel fuels exceed the performance of a Tier II CARB-like diesel. Phase II RD&T Task 2.6 successfully met the lubricity property testing and F-T diesel fuel hot-start transient emissions test objectives. The results of the testing help mitigate potential economic risks on obtaining a premium price for the F-T diesel fuel in the marketplace. The F-T diesel fuel superior properties of low sulfur, low aromatics, and high cetane resulted in lower emissions yields if compared to conventional diesel fuels.

  6. --No Title--

    U.S. Energy Information Administration (EIA) Indexed Site

    | | | | | | | | | | | | Geographic Area | Aviation | Naphtha- | Kerosene- | Propane Month | Gasoline | Type | Type | (Consumer | |...

  7. EARLY ENTRANCE COPRODUCTION PLANT

    SciTech Connect (OSTI)

    Fred D. Brent; Lalit Shah; Earl Berry; Charles H. Schrader; John Anderson; Ming He; James F. Stevens; Centha A. Davis; Michael Henley; Jerome Mayer; Harry Tsang; Jimell Erwin; Jennifer Adams; Michael Tillman; Chris Taylor; Marjan J. Roos; Robert F. Earhart

    2004-01-27

    The overall objective of this project is the three phase development of an Early Entrance Coproduction Plant (EECP) which uses petroleum coke to produce at least one product from at least two of the following three categories: (1) electric power (or heat), (2) fuels, and (3) chemicals using ChevronTexaco's proprietary gasification technology. The objective of Phase I is to determine the feasibility and define the concept for the EECP located at a specific site; develop a Research, Development, and Testing (RD&T) Plan to mitigate technical risks and barriers; and prepare a Preliminary Project Financing Plan. The objective of Phase II is to implement the work as outlined in the Phase I RD&T Plan to enhance the development and commercial acceptance of coproduction technology. The objective of Phase III is to develop an engineering design package and a financing and testing plan for an EECP located at a specific site. The project's intended result is to provide the necessary technical, economic, and environmental information needed by industry to move the EECP forward to detailed design, construction, and operation. The partners in this project are Texaco Energy Systems LLC or TES (a subsidiary of ChevronTexaco), General Electric (GE), Praxair, and Kellogg Brown & Root (KBR) in addition to the U.S. Department of Energy (DOE). TES is providing gasification technology and Fischer-Tropsch (F-T) technology developed by Rentech, GE is providing combustion turbine technology, Praxair is providing air separation technology, and KBR is providing engineering. Each of the EECP subsystems was assessed for technical risks and barriers. A plan was developed to mitigate the identified risks (Phase II RD&T Plan, October 2000). The potential technical and economic risks to the EECP from Task 2.5 can be mitigated by demonstrating that the end-use products derived from the upgrading of the F-T synthesis total liquid product can meet or exceed current specifications for the manufacture of ethylene and propylene chemicals from F-T naphtha, for the generation of hydrogen from F-T naphtha to power fuel cells, for direct blending of F-T diesels into transportation fuels, for the conversion of F-T heavy product wax to transportation fuels, and the conversion of F-T Heavy product wax to a valuable high melting point food-grade specialty wax product. Product evaluations conducted under Task 2.5 of Phase II successfully mitigated the above technical and economic risks to the EECP with the development of product yields and product qualities for the production of chemicals, transportation fuels, and specialty food-grade waxes from the F-T synthesis products.

  8. Friction Modeling for Lubricated Engine and Drivetrain Components

    Broader source: Energy.gov [DOE]

    2010 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C.

  9. Turkey Marine Lubricants Market is Expected to Reach USD 177...

    Open Energy Info (EERE)

    are primarily categorized into seven different applications including engine oils, hydraulic oils, grease, turbine oils, gear oils, compressor oils and heat transfer fluids....

  10. EERE Success Story - Novel Engine Lubrication Anti-Wear Additives...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... If successful, this remarkable technology could potentially save the United States tens of millions of barrels of oil annually. The Vehicle Technologies Office (VTO) supports ...

  11. Collaborative Lubricating Oil Study on Emissions (CLOSE Project)

    Broader source: Energy.gov [DOE]

    2010 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C.

  12. Controlled Experiments on the Effects of Lubricant/Additive ...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Comparison of ash characteristics such as packing density and elemental composition in field and laboratory aged DPFs. PDF icon deer08sappok.pdf More Documents & Publications Key ...

  13. Large-Scale Manufacturing of Nanoparticle-Based Lubrication Additives

    Broader source: Energy.gov [DOE]

    Fact Sheet About Development of Boron-Based Nanolubrication Additives for Improved Energy Efficiency and Reduced Emissions

  14. Transparency and damage tolerance of patternable omniphobic lubricated...

    Office of Scientific and Technical Information (OSTI)

    broad technological impact, from solar cell coatings to self-cleaning optical devices. ... The coating is highly defect-tolerant due to its interconnected, honeycomb wall structure, and ...

  15. 2013 Annual Merit Review Results Report - Fuels & Lubricants

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... has high impact and has provided significant guidance to the biofuel and fuel industries. ... to evaluate the impacts on emissions and engine systems, and on the performance, ...

  16. Collaborative Lubricating Oil Study on Emissions (CLOSE) Project...

    Broader source: Energy.gov (indexed) [DOE]

    Extensive chemical and physical characterization performed on emissions from normal and high emitting light-, medium-, and heavy-duty vehicles to evaluate relative contributions of ...

  17. Reducing Lubricant Ash Impact on Exhaust Aftertreatment with a Oil

    Energy Savers [EERE]

    Reducing Energy Loss Reducing Energy Loss Below is information about the student activity/lesson plan from your search. Grades 5-8 Subject Energy Efficiency and Conservation Summary Students will learn about the Law of Conservation of Energy. They will also compare and contrast Energy Guide Labels to study energy efficiency and conservation as well. Curriculum Economics, Language Arts, Mathematics, Science Plan Time 90 minutes, plus 90 minute lab Materials Handouts and other materials needed

  18. FY 2012 Progress Report for Fuel & Lubricant Technologies

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... 5. Cylinder pressure and heat release traces for RCCI ... The ambient temperature and pressure variation will ... direction) and fnal melting temperature (FMT - measured in the ...

  19. LubricantInfused Nanoparticulate Coatings Assembled by LayerbyLayer...

    Office of Scientific and Technical Information (OSTI)

    ... cost, based on aqueous solutions and thus environmentally ... Stainless steel and polymer substrates were purchased ...m 3 at 0 C; kinematic viscosity 0.12 cm 2 s, evaporation ...

  20. Large-Scale Manufacturing of Nanoparticle-Based Lubrication Additives

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    In response to this need, this project is developing ... Very rapid market penetration of nanolubrication technology ... schedule, the project team is carefully monitoring and ...

  1. Force Field Parameter Estimation of Functional Perfluoropolyether Lubricants

    SciTech Connect (OSTI)

    Smith, R.; Chung, P.S.; Steckel, J; Jhon, M.S.; Biegler, L.T.

    2011-01-01

    The head disk interface in a hard disk drive can be considered to be one of the hierarchical multiscale systems, which require the hybridization of multiscale modeling methods with coarse-graining procedure. However, the fundamental force field parameters are required to enable the coarse-graining procedure from atomistic/molecular scale to mesoscale models. In this paper, we investigate beyond molecular level and perform ab initio calculations to obtain the force field parameters. Intramolecular force field parameters for Zdol and Ztetraol were evaluated with truncated PFPE molecules to allow for feasible quantum calculations while still maintaining the characteristic chemical structure of the end groups. Using the harmonic approximation to the bond and angle potentials, the parameters were derived from the Hessian matrix, and the dihedral force constants are fit to the torsional energy profiles generated by a series of constrained molecular geometry optimization.

  2. Force Field Parameter Estimation of Functional Perfluoropolyether Lubricants

    SciTech Connect (OSTI)

    Smith, R.; Chung, P.S.; Steckel, J; Jhon, M.S.; Biegler, L.T.

    2011-01-01

    The head disk interface in hard disk drive can be considered one of the hierarchical multiscale systems, which require the hybridization of multiscale modeling methods with coarse-graining procedure. However, the fundamental force field parameters are required to enable the coarse-graining procedure from atomistic/molecular scale to mesoscale models .In this paper, we investigate beyond molecular level and perform ab-initio calculations to obtain the force field parameters. Intramolecular force field parameters for the Zdol and Ztetraol were evaluated with truncated PFPE molecules to allow for feasible quantum calculations while still maintaining the characteristic chemical structure of the end groups. Using the harmonic approximation to the bond and angle potentials, the parameters were derived from the Hessian matrix, and the dihedral force constants are fit to the torsional energy profiles generated by a series of constrained molecular geometry optimization.

  3. An evaluation and optimization of lubricants for turbocharged gasoline engines

    SciTech Connect (OSTI)

    Kagaya, M.; Ishikawa

    1984-01-01

    In Japan, turbocharged passenger cars have recently been introduced with increased improvements in fuel economy and engine performance. However, a turbocharger is driven by hot exhaust gas, so that an engine oil with superior thermal stability is required. After studying a turbocharged engine's thermal effects, two laboratory screening tests that correlate with dynamometer engine tests were established. These tests, termed the panel coking test and the high temperature panel corrosion test, enable one to evaluate base oils, additive components and viscosity index improvers for a given engine oil. Finally, a 10W-30 engine oil formulated by using these tests, showed superior deposit control and anticorrosion performance in the dynamometer engine test and actual driving conditions.

  4. An evaluation and optimization of lubricants for turbocharged gasoline engines

    SciTech Connect (OSTI)

    Kagaya, M.; Ishikawa, S.

    1984-02-01

    In Japan, turbocharged passenger cars have recently been introduced with increased improvements in fuel economy and engine performance. However, a turbocharger is driven by hot exhaust gas, so that an engine oil with superior thermal stability is required. After studying a turbocharged engine's thermal effects, two laboratory screening tests that correlate with dynamometer engine tests were established. These tests, termed the panel coking test and the high temperature panel corrosion test, enable one to evaluate base oils, additive components and viscosity index improvers for a given engine oil. Finally, a 10W-30 engine oil formulated by using these tests, showed superior deposit control and anticorrosion performance in the dynamometer engine test and actual driving conditions.

  5. The Role of Lubricant Additives in Fuel Efficiency and Emission...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    EERE Announces the Energy Materials Network EERE Announces the Energy Materials Network In support of President Obama's Materials Genome Initiative, the Energy Department launched ...

  6. Transparency and damage tolerance of patternable omniphobic lubricated...

    Office of Scientific and Technical Information (OSTI)

    ... Language: English Subject: 36 MATERIALS SCIENCE physical sciences; materials science; nanotechnology Word Cloud More Like This Free Publicly Accessible Full Text Accepted ...

  7. Fuels and Lubricants to Support Advanced Diesel Engine Technology...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    New Diesel Feedstocks and Future Fuels Future Engine Fluids Technologies: Durable, Fuel-Efficient, and Emissions-Friendly New Feedstocks and Replacement Fuel Diesel Engine ...

  8. Overview of DOE Fuel & Lubricant Technologies R&D

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Vehicle Technologies Program Mission To develop more energy efficient and environmentally friendly highway transportation technologies that enable America to use less petroleum. ...

  9. Characteristics and Effects of Lubricant Additive Chemistry and Exhaust

    Broader source: Energy.gov (indexed) [DOE]

    Department of Energy Andy Oare Andy Oare Former New Media Strategist, Office of Public Affairs What does this mean for me? Clean energy manufacturing is expanding across the Midwest. This was spurred in large part by the Advanced Energy Manufacturing Tax Credit, also known as 48C, which was part of the Recovery Act. The $2.3 billion in tax credits received by 183 projects is being matched by nearly $5.4 billion in private capital. One of the big reasons we became a global economic leader is

  10. Examining Effects of Lubricant Composition in Engine Component Systems in

    Broader source: Energy.gov (indexed) [DOE]

    document provides an overview and definition of EM&V. PDF icon What is EMV? More Documents & Publications Benefits of Evaluation, Measurement, and Verification Developing an Evaluation Measurement and Verification Plan for Your Energy Efficiency Project/Program Developing an Evaluation Measurement, and Verification Plan: Residential Retrofits

    Past Workshops and Conference Sessions 2014 2013 2012 2011 Past Partner Events 2013 2012 2011 2010 Past Workshops and Conference Sessions The

  11. Friction of Steel Sliding Under Boundary Lubrication Regime in Commercial

    Broader source: Energy.gov (indexed) [DOE]

    Gear Oils at Elevated Temperatures | Department of Energy This study was conducted to understand how to increase engine efficiency by reducing parasitic boundary regime friction losses and enable operation with lower viscosity oils while maintaining engine durability. PDF icon deer08_erck.pdf More Documents & Publications Impact of Low-Friction Surface Treatments on Engine Friction Low-Friction Engineered Surfaces Overview of Friction and Wear Reduction for Heavy Vehicles

  12. Fuels and Lubricants to Support Advanced Diesel Engine Technology |

    Broader source: Energy.gov (indexed) [DOE]

    Department of Energy 5 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters PDF icon 2005_deer_baranescu.pdf More Documents & Publications New Diesel Feedstocks and Future Fuels Future Engine Fluids Technologies: Durable, Fuel-Efficient, and Emissions-Friendly New Feedstocks and Replacement Fuel Diesel Engine Challenges

  13. Table Definitions, Sources, and Explanatory Notes

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    ... fuel oil, and heavy gas oil) and other petroleum (e.g., cat cracked naphtha, coker naphtha, gas oil, etc.) in the presence of catalysts and substantial quantities of hydrogen. ...

  14. RPT_PERIOD","R_S_NAME","LINE_NUM","PROD_CODE","PROD_NAME","PORT...

    U.S. Energy Information Administration (EIA) Indexed Site

    AMER",5,822,"NAPHTHA ( < 401 DEGREES F ENDPOINT)",5301,"HOUSTON, TX","TEXAS",3,830,"SPAIN",24,0,0,,,,, 35826,"EXXON CHEM AMER",6,822,"NAPHTHA ( < 401 DEGREES F...

  15. Fuel-Cycle Energy and Emissions Analysis with the GREET Model

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... Petroleum: Conventional Oil Sands Gasoline Diesel LPG Naphtha Residual oil Natural Gas: NA Non-NA CNG LNG LPG Methanol Dimethyl Ether FT Diesel and Naphtha Hydrogen Nuclear Energy ...

  16. Atmospheric Crude Oil Distillation Operable Capacity

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Charge Capacity (BSD) Catalytic Hydrotreating NaphthaReformer Feed Charge Cap (BSD) Catalytic Hydrotreating Gasoline Charge Capacity (BSD) Catalytic Hydrotreating...

  17. Separation of Fischer-Tropsch Wax from Catalyst by Supercritical Extraction

    SciTech Connect (OSTI)

    Mark C. Thies; Patrick C. Joyce

    1998-04-30

    Further progress in achieving the objectives of the project was made in the period of January I to March 31, 1998. The direct numerical simulation of particle removal process in turbulent gas flows was completed. Variations of particle trajectories are studied. It is shown that the near wall vortices profoundly affect the particle removal process in turbulent boundary layer flows. Experimental data for transport and deposition of fibrous particles in the aerosol wind tunnel was obtained. The measured deposition velocity for irregular fibrous particles is compared with the empirical correlation and the available data for glass fibers and discussed. Additional progress on the sublayer model for evaluating the particle deposition and resuspension in turbulent flows was made.

  18. Remarkable waxing, waning, and wandering of populations of Mimulus guttatus: An unexpected example of global warming

    SciTech Connect (OSTI)

    Vickery, R.K. Jr.

    1999-04-01

    The purpose of this study was to observe the dynamics of a meta-population of Mimulus guttatus. Changes in size and location of 16 original populations and the new populations established in their vicinities in Big Cottonwood Canyon, Salt Lake county, Utah, were observed for 25 yr. Twenty-three new populations appeared. Seven original populations and 13 new populations had become extinct by the end of the observation period in 1996. Many populations died out and were reestablished, often repeatedly, during the observation period. Altogether there were 54 population disappearances and 34 reappearances. Many populations changed size as much as 100-fold or more from year to year. There were spectacular examples of populations expanding to fill newly available, large habitats. Frequent extinctions were due overwhelmingly to the canyon drying trend, which led to the drying up of most Mill D North drainage springs, creeks, and ponds. Precipitation and minimum temperatures increased moderately during the observation period. The growing season lengthened almost 50%, a typical consequence of global warming. The drying trend, lengthened growing season, and disappearance of Mimulus populations in Big Cottonwood Canyon appear to be a clear, local example of global warming.

  19. Vacuum pyrolysis of used tires

    SciTech Connect (OSTI)

    Roy, C.; Darmstadt, H.; Benallal, B.; Chaala, A.; Schwerdtfeger, A.E.

    1995-11-01

    The vacuum pyrolysis of used tires enables the recovery of useful products, such as pyrolytic oil and pyrolytic carbon black (CB{sub P}). The light part of the pyrolytic oil contains dl-limonene which has a high price on the market. The naphtha fraction can be used as a high octane number component for gasoline. The middle distillate demonstrated mechanical and lubricating properties similar to those of the commercial aromatic oil Dutrex R 729. The heavy oil was tested as a feedstock for the production of needle coke. It was found that the surface morphology of CB{sub P} produced by vacuum pyrolysis resembles that of commercial carbon black. The CB{sub P} contains a higher concentration of inorganic compounds (especially ZnO and S) than commercial carbon black. The pyrolysis process feasibility looks promising. One old tire can generate upon vacuum pyrolysis, incomes of at least $2.25 US with a potential of up to $4.83 US/tire upon further product improvement. The process has been licensed to McDermott Marketing Servicing Inc. (Houston) for its exploitation in the US.

  20. Total Crude Oil and Petroleum Products Imports by Processing...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Product: Total Crude Oil and Petroleum Products Crude Oil Total Products Other Liquids Unfinished Oils Naphthas and Lighter Kerosene and Light Gas Oils Heavy Gas Oils Residuum ...

  1. U.S. Energy Information Administration | State Energy Data 2013...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    This section describes the data identification codes in the State Energy Data System (SEDS). ... special naphtha SO photovoltaic and solar thermal energy TE total energy TN ...

  2. CSV File Documentation: Consumption

    Gasoline and Diesel Fuel Update (EIA)

    Consumption Estimates The State Energy Data System (SEDS) comma-separated value (CSV) files ... SG still gas SN special naphthas SO solar thermal and photovoltaic energy TE total ...

  3. This Week In Petroleum Summary Printer-Friendly Version

    Gasoline and Diesel Fuel Update (EIA)

    Jet fuel exports have primarily increased to Western Europe, Central America (including Mexico), and South America, and to a lesser extent Africa. Propane and naphtha exports are...

  4. X:\\Data_Publication\\Pma\\current\\ventura\\pma00.vp

    U.S. Energy Information Administration (EIA) Indexed Site

    by PAD District and State (Thousand Gallons per Day) - Continued Geographic Area Month Aviation Gasoline Naphtha- Type Jet Fuel Kerosene- Type Jet Fuel Propane (Consumer Grade)...

  5. X:\\L6046\\Data_Publication\\Pma\\current\\ventura\\pma.vp

    U.S. Energy Information Administration (EIA) Indexed Site

    by PAD District and State (Thousand Gallons per Day) - Continued Geographic Area Month Aviation Gasoline Naphtha- Type Jet Fuel Kerosene- Type Jet Fuel Propane (Consumer Grade)...

  6. Appendix A: Reference case

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    road oil, still gas, special naphthas, petroleum coke, crude oil product supplied, methanol, and miscellaneous petroleum products. 14 Includes energy for combined heat and...

  7. Ionic Liquids as Multi-Functional Lubricant Additives to Enhance Engine Efficiency

    Broader source: Energy.gov [DOE]

    2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  8. Lubricants Market to Record 44,165.11 Kilo Tons Volume by 2020...

    Open Energy Info (EERE)

    over 50% of the global market share. Automotive oils sector is further segmented into hydraulic oil, engine oil, and gear oil. Improving GDP in developing nations such as India and...

  9. Auto/Steel Partnership: Hydroforming Materials and Lubricant Lightweight Rear Chassis Structures Future Generation Passenger Compartment

    Broader source: Energy.gov [DOE]

    2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C.

  10. Vehicle Technologies Office Merit Review 2015: Fuel and Lubricant Effects on Emissions Control Technologies

    Broader source: Energy.gov [DOE]

    Presentation given by Oak Ridge National Laboratory at 2015 DOE Hydrogen and Fuel Cells Program and vehicle technologies office annual merit review and peer evaluation meeting about fuel and...

  11. Minimizing Lubricant-Ash Requirement and Impact on Emission Aftertreatment Systems via an Oil Conditioning Filter

    Broader source: Energy.gov [DOE]

    Presentation given at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August, 2007, Detroit, Michigan. Sponsored by the U.S. Department of Energy's (DOE) Office of FreedomCAR and Vehicle Technologies (OFCVT).

  12. Vehicle Technologies Office Merit Review 2015: Polyalkylene Glycol (PAG) Based Lubricant for Light & Medium Duty Axles

    Broader source: Energy.gov [DOE]

    Presentation given by Ford Motor Company at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about polyalkylene glycol (PAG)...

  13. Self-lubrication for long runout landslides: Examination by computer simulation

    SciTech Connect (OSTI)

    Cleary, P.W.; Campbell, C.S. |

    1993-12-01

    This paper describes the use of a discrete particle computer simulation to test whether the apparent low friction exhibited by long runout landslides could be explained in terms of simple granular mechanics. The flow structure consists of an active basal shear zone supporting the majority of the landslide, which travels as a relatively solid plug. The observed runout appears to depend on the total energy dissipation which is a trade-off between (1) the inelasticity of the particles, which governs the energy dissipated in each event, and, (2), the size of the dissipating shear zone, which governs the number of particles that are actively dissipating energy. Very inelastic particles quickly dissipate the work performed at boundaries and result in thin dissipative zones. As a result, these two factors balance and the runout is nearly independent of particle inelasticity. Along the same lines, increasing the boundary roughness was found to increase the size of the dissipative shear zone and markedly decrease the runout. Also, a distribution of particle sizes destroyed ordered structures within the body which, once again, increases the dissipation and decreases the runout. Unfortunately, the simulations also indicate that the runout should be independent of the depth of the flow and thus cannot account for the observed volumetric effect on runout.

  14. Impact of Biodiesel on Ash Emissions and Lubricant Properties Affecting Fuel Economy and Engine Wear

    Broader source: Energy.gov [DOE]

    Presentation given at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August, 2007, Detroit, Michigan. Sponsored by the U.S. Department of Energy's (DOE) Office of FreedomCAR and Vehicle Technologies (OFCVT).

  15. Multi-component Nanoparticle Based Lubricant Additive to Improve Efficiency and Durability in Engines

    Broader source: Energy.gov [DOE]

    Development of active nanoparticle additive for lubricatns that will minimize sulfur and phosporous content in engine oil, and lower ash forming elements

  16. The Impact of Lubricant Formulation on the Performance of NOx Adsorber

    Broader source: Energy.gov (indexed) [DOE]

    Acting Under Secretary Cathy Zoi talks about the new Home Energy Score pilot program. Dr. Kathleen Hogan Dr. Kathleen Hogan Deputy Assistant Secretary for Energy Efficiency You may know the miles per gallon your car gets, but have you ever wanted to know the miles per gallon your home gets? Today, Vice President Biden and Secretary Chu launched the Home Energy Score program to help consumers save money by saving energy. The program is kicking off in ten pilot locations across the nation. The

  17. The Role of Lubricant Additives in Fuel Efficiency and Emission Reductions:

    Broader source: Energy.gov (indexed) [DOE]

    Department of Energy Combustion plays an important role in enabling high thermal efficiencies. Technologies that deliver short combustion duration and low soot emissions are needed. PDF icon deer08_gehrke.pdf More Documents & Publications Development of Enabling Technologies for High Efficiency, Low Emissions Homogeneous Charge Compression Ignition (HCCI) Engines Heavy-Duty Low Temperature Combustion Development Activities at Caterpillar Development of Enabling Technologies for High

  18. Investigations of non-linear polymers as high performance lubricant additives

    SciTech Connect (OSTI)

    Robinson, Joshua W.; Bhattacharya, Priyanka; Qu, Jun; Bays, J. Timothy; Cosimbescu, Lelia

    2015-03-22

    Off-the-shelf available engine oils contain an assortment of additives that increase the performance of base oils and maximize the overall efficiency of the machine. With ever increasing requirements for fuel efficiency, the demand for novel materials that outperform older generations is also on the rise. One approach towards increasing overall efficiency is to reduce internal friction and wear in an engine. From an additive approach, this is typically achieved by altering the bulk oil’s viscosity at high temperatures via polymers. In general, the hydrodynamic volume of polymers increase (expand) at elevated temperatures and decrease (contract/deflate) with declining temperatures and this effect is enhanced be carefully designing specific structures and architectures. The natural thinning tendency of base oil with increasing temperatures is in part mitigated by the expansion of the macromolecules added, and the overall effect is decreasing the viscosity losses at high temperatures. Traditional polymer architectures vary from linear to dendritic, where linear polymers of the same chemical composition and molecular weight to its dendritic counterpart will undergo a more significant free volume change in solution with regards to temperature changes. This advantage has been exploited in the literature towards the production of viscosity modifiers. However, one major disadvantage of linear polymers is degradation due to mechanical shear forces and high temperatures causing a shorter additive lifetime. Dendrimers on the other hand are known to demonstrate superior robustness to shear degradation when compared to their respective linear counterparts. An additional advantage of the dendritic architecture is the ability to tailor the peripheral end-groups towards influencing polymer-solvent and/or polymer-surface interactions. Comb-burst hyperbranched polymers are a hybrid of the aforementioned architectures and provide several compromises between the traditional structures including the tailoring of peripheral functional groups, conformational flexibility via lipophilic long chain linkers, and a readily available synthesis amenable to scale-up. In the following communication, the synthesis of an aryl comb-burst hyperbranched polymer will be described. Some of the challenges we had to overcome are being highlighted, such as efforts towards increasing lipophilicity of the molecule via changes in saturated carbon content, controlling polymerization conditions to control average molecular weight and degree of branching. In addition, trends in viscosity modification of the bulk oil and wear/friction studies will be discussed.

  19. The Influence of Molecular Structure of Distillate Fuels on HFRR Lubricity

    Broader source: Energy.gov [DOE]

    Presentation given at 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August, 2007, Detroit, Michigan. Sponsored by the U.S. Department of Energy's (DOE) Office of FreedomCAR and Vehicle Technologies (OFCVT).

  20. AWEA O&M Recommended Practices Series Part VII: Wind Turbine Gear Lubricant Flushing Procedures

    Broader source: Energy.gov [DOE]

    The AWEA Operations and Maintenance Recommended Practice 101 was developed to provide guidance to the wind industry regarding proper methods of wind turbine gearbox flushing and oil conversion...

  1. Vehicle Technologies Office Merit Review 2014: Fuel and Lubricant Effects on Emissions Control Technologies

    Broader source: Energy.gov [DOE]

    Presentation given by Oak Ridge National Laboratory at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about fuel and...

  2. Lubricant-Friendly, Superhard and Low-Friction Coatings by Design

    Broader source: Energy.gov [DOE]

    Superhard and low-friction coatings and surface treatments can help improve fuel economy and durability in engines.

  3. The Sensitivity of DPF Performance to the Spatial Distribution of Ash Generated from Six Lubricant Formulations

    Broader source: Energy.gov [DOE]

    Discusses potential of DPF pressure drop reduction by optimizing the spatial distribution of ash inside DPF inlet channel

  4. A perspective on syngas from coal

    SciTech Connect (OSTI)

    Rath, L.K.; Longanbach, J.R. )

    1991-01-01

    Syngas, a mixture of hydrogen and carbon monoxide, has been produced from coal for more than 100 years. But today most syngas is produced from noncoal feedstocks, by catalytic steam reforming of natural gas and naphtha or partial oxidation of heavy hydrocarbons such as petroleum resid. Three types of syngas, characterized by their H{sub 2}/CO ratio, are needed. Low ratio, H{sub 2}/CO = 0.4-0.8, syngas can be used in recently developed processes such as the Liquid Phase Methanol synthesis and the Shell Fischer-Tropsch wax synthesis; moderate ratio, H{sub 2}/CO = 0.8-1.5, syngas is used in the Tennessee Eastman coal based synthesis of methanol and acetic anhydride; high ratio, H{sub 2}/CO = 1.8-2.5, syngas is used in traditional methanol synthesis and the Fischer-Tropsch synthesis at Sasol. Different types of gasifiers are available for the production of syngas. These include Lurgi fixed-bed dry bottom and slagging gasifiers, agglomerating fluidized-bed gasifiers, single and two-stage entrained slurry feed gasifiers, and single-stage entrained dry feed gasifiers. The cost of syngas from subbituminous coal is shown to be relatively insensitive to the H{sub 2}/CO ratio produced and may soon be competitive with natural gas-based syngas in some parts of the country due to the increasing demand for and cost of natural gas. Recent in this paper, DOE sponsored research on three topics on the production of syngas from coal, coal gasifiers for the direct production of high hydrogen content syngas, advanced methods to separate hydrogen from syngas at elevated temperatures and biological conversion of coal to syngas, are also discussed.

  5. Validation of a Small Engine Based Procedure for Studying Performance of Engine Lube Oils, Ionic Liquids as Lubricants and/or Lubricant Additives, Opportunities for Engine Friction Reduction and Durable Design

    Broader source: Energy.gov [DOE]

    Poster presented at the 16th Directions in Engine-Efficiency and Emissions Research (DEER) Conference in Detroit, MI, September 27-30, 2010.

  6. Vehicle Technologies Office Merit Review 2015: Overview of the VTO Fuel and Lubricant Technologies R&D

    Broader source: Energy.gov [DOE]

    Presentation given by U.S. Department of Energy at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about overview of the VTO...

  7. Vehicle Technologies Office Merit Review 2015: Overview of the VTO Fuel and Lubricant Technologies R&D

    Broader source: Energy.gov [DOE]

    Presentation given by U.S. Department of Energy  at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation meeting about overview of the...

  8. Vehicle Technologies Office Merit Review 2014: Overview of the DOE Fuel and Lubricant Technologies R&D

    Broader source: Energy.gov [DOE]

    Presentation given by U.S. Department of Energy at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting providing an overview of...

  9. The FreedomCAR & Vehicle Technologies Health Impacts Program- The Collaborative Lubricating Oil Study on Emissions (CLOSE) Project

    Broader source: Energy.gov [DOE]

    Poster presentation at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August, 2007, Detroit, Michigan. Sponsored by the U.S. Department of Energy's (DOE) Office of FreedomCAR and Vehicle Technologies (OFCVT).

  10. Process for recovering uranium from waste hydrocarbon oils containing the same. [Uranium contaminated lubricating oils from gaseous diffusion compressors

    DOE Patents [OSTI]

    Conrad, M.C.; Getz, P.A.; Hickman, J.E.; Payne, L.D.

    1982-06-29

    The invention is a process for the recovery of uranium from uranium-bearing hydrocarbon oils containing carboxylic acid as a degradation product. In one aspect, the invention comprises providing an emulsion of water and the oil, heating the same to a temperature effecting conversion of the emulsion to an organic phase and to an acidic aqueous phase containing uranium carboxylate, and recovering the uranium from the aqueous phase. The process is effective, simple and comparatively inexpensive. It avoids the use of toxic reagents and the formation of undesirable intermediates.

  11. Vehicle Technologies Office Merit Review 2014: Lubricant Formulations to Enhance Engine Efficiency (LFEEE) in Modern Internal Combustion Engines

    Broader source: Energy.gov [DOE]

    Presentation given by Massachusetts Institute of Technology at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about...

  12. Vehicle Technologies Office Merit Review 2014: Can hard coatings and lubricant anti-wear additives work together?

    Broader source: Energy.gov [DOE]

    Presentation given by Oak Ridge National Laboratory at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about hard coatings...

  13. Influence of lubricant oil on heat transfer performance of refrigerant flow boiling inside small diameter tubes. Part I: Experimental study

    SciTech Connect (OSTI)

    Wei, Wenjian; Ding, Guoliang; Hu, Haitao; Wang, Kaijian

    2007-10-15

    Two-phase flow pattern and heat transfer characteristics of refrigerant-oil mixture flow boiling inside small tubes with inside diameters of 6.34 mm and 2.50 mm are investigated experimentally. The test condition of nominal oil concentration is from 0% to 5%, mass flux from 200 to 400 kg m{sup -2} s{sup -1}, heat flux from 3.2 to 14 kW m{sup -2}, evaporation temperature of 5 C, inlet quality from 0.1 to 0.8, and quality change from 0.1 to 0.2. Wavy, wavy-annular, annular and mist-annular flow pattern in 6.34 mm tube are observed, while only slug-annular and annular flow pattern are observed in 2.50 mm tube. Oil presence can make annular flow to form early and to retard to diminish in quality direction at nominal oil concentration {>=}3%. Augmentation effect of oil on heat transfer coefficient becomes weakened or even diminishes for small diameter tube while detrimental effect of oil on small tube performance becomes more significant than large tube. For both test tubes, variation of heat transfer coefficient and enhanced factor with oil concentration is irregular. Two-phase heat transfer multiplier with refrigerant-oil mixture properties increases consistently and monotonically with local oil concentration at different vapor quality. (author)

  14. Functionalizing Nanotubes for Biomedical Applications - Donghui...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    PBLG How are the polypeptides ordered on the nanotube? Small (or wide) Angle X-ray Scattering (SAXS, WAXS) Same physics, different info WAXS gives spatial correlations of...

  15. M

    U.S. Energy Information Administration (EIA) Indexed Site

    resources 1. Includes c oal, n atural g as, p etroleum, h ydrothermal, Source: E IA ... U S Propane, U S Naphtha, A RA Natural G as, U S Price MMBTU Historical Forecast 5 ...

  16. RPT_PERIOD","R_S_NAME","LINE_NUM","PROD_CODE","PROD_NAME","PORT...

    U.S. Energy Information Administration (EIA) Indexed Site

    RP",31,820,"UNFINISHED OILS, NAPHTHAS & LIGHTER",5312,"CORPUS CHRIS, TX","TEXAS",3,830,"SPAIN",219,0,0,"CITGO REFG & CHEM INC","CORPUS CHRISTI","TX","TEXAS",3 34000,"CITGO PETRO...

  17. Rocky Mountain (PADD 4) Total Crude Oil and Products Imports

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fuel Ethanol (Renewable) Biomass-Based Diesel (Renewable) Distillate Fuel Oil Distillate ... Jet Fuel Special Naphthas Residual Fuel Oil Residual F.O., Less than 0.31% Sulfur ...

  18. Effect of Exhaust Gas Recirculation (EGR) on Diesel Engine Oil...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Effects of Fuel Dilution with Biodiesel on Lubricant Acidity, Oxidation and Corrosion Impact of Biodiesel on Ash Emissions and Lubricant Properties ...

  19. Ionic Liquids Used as Wear Reduction, Wins R&D 100 Award | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    that can be used as friction and wear reduction additives for lubricating oils. ... that can be used as friction and wear reduction additives for lubricating oils. ...

  20. The Influence of Molecular Structure of Distillate Fuels on HFRR...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The Influence of Molecular Structure of Distillate Fuels on HFRR Lubricity The Influence of Molecular Structure of Distillate Fuels on HFRR Lubricity Presentation given at 2007 ...

  1. DOE Vehicle Technologies Program 2009 Merit Review Report - Fuels...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuels and Lubricants DOE Vehicle Technologies Program 2009 Merit Review Report - Fuels and Lubricants Merit review of DOE Vehicle Technologies Program research efforts...

  2. 2010 DOE EERE Vehicle Technologies Program Merit Review - Fuels...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications 2011 Annual Merit Review Results Report - Fuels & Lubricants 2011 Annual Merit Review Results Report - Fuels & Lubricants DOE Vehicle...

  3. Low-friction Materials and Coatings | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Materials for Tribological Applications Chapter 8 ISBN 9789814463904 Other Numbers CAT N11165 Abstract Comprehensive overview of new solid lubricants and self-lubricating...

  4. Vehicle Technologies Office Merit Review 2014: Development of Modified PAG (polyalkylene glycol) High VI High Fuel Efficient Lubricant for LDV Applications

    Broader source: Energy.gov [DOE]

    Presentation given by Ford Motor Company at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about development of modified...

  5. Outboard motor provided with a four-stroke engine

    SciTech Connect (OSTI)

    Sumigawa, Y.

    1986-09-16

    This patent describes a lubricating system for an internal combustion engine having a lubricant reservoir adapted to contain a lubricant for the engine. The system includes an inlet line depending into the lubricant reservoir for supplying lubricant for an engine lubricating system, a strainer disposed at the inlet end of the inlet line for removing foreign particles from the lubricant entering the inlet line, a drain opening in the lubricant reservoir for draining lubricant therefrom, and a drain plug for closing the drain opening, the improvement is described comprising the drain opening and the strainer being sized and related for servicing of the strainer through the drain opening, and relief valve means for bypassing the strainer in providing unfiltered lubricant to the inlet line in the event the strainer becomes plugged.

  6. West Coast (PADD 5) Total Crude Oil and Products Imports

    U.S. Energy Information Administration (EIA) Indexed Site

    Distillate Fuel Oil Distillate F.O., 15 ppm and under Distillate F.O., 15 to 500 ppm Distillate F.O., Greater than 500 ppm Distillate F.O., 501 to 2000 ppm Distillate F.O., Greater than 2000 ppm Kerosene Finished Aviation Gasoline Aviation Gasoline Blending Components Kerosene-Type Jet Fuel Special Naphthas Residual Fuel Oil Residual F.O., Less than 0.31% Sulfur Residual F.O., 0.31 to 1% Sulfur Residual F.O., Greater than 1% Sulfur Naphtha for Petrochem. Feed. Use Other Oils for Petrochem. Feed.

  7. Rocky Mountain (PADD 4) Total Crude Oil and Products Imports

    U.S. Energy Information Administration (EIA) Indexed Site

    Conventional Gasoline Blend. Comp. Fuel Ethanol (Renewable) Biomass-Based Diesel (Renewable) Distillate Fuel Oil Distillate F.O., 15 ppm and under Distillate F.O., 15 to 500 ppm Distillate F.O., Greater than 500 ppm Distillate F.O., 501 to 2000 ppm Distillate F.O., Greater than 2000 ppm Kerosene Finished Aviation Gasoline Kerosene-Type Jet Fuel Special Naphthas Residual Fuel Oil Residual F.O., Less than 0.31% Sulfur Residual F.O., 0.31 to 1% Sulfur Residual F.O., Greater than 1% Sulfur Naphtha

  8. Rocky Mountain Research Station and LANL build

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Conventional Gasoline Blend. Comp. Fuel Ethanol (Renewable) Biomass-Based Diesel (Renewable) Distillate Fuel Oil Distillate F.O., 15 ppm and under Distillate F.O., 15 to 500 ppm Distillate F.O., Greater than 500 ppm Distillate F.O., 501 to 2000 ppm Distillate F.O., Greater than 2000 ppm Kerosene Finished Aviation Gasoline Kerosene-Type Jet Fuel Special Naphthas Residual Fuel Oil Residual F.O., Less than 0.31% Sulfur Residual F.O., 0.31 to 1% Sulfur Residual F.O., Greater than 1% Sulfur Naphtha

  9. U.S. Refinery Net Production

    U.S. Energy Information Administration (EIA) Indexed Site

    ... Petrochemical Feedstocks 119,344 112,263 110,319 123,577 114,001 106,153 2005-2015 Naphtha For Petrochemical Feedstock Use 76,367 75,347 75,054 87,357 74,553 69,214 2005-2015 Other ...

  10. Fuel and fuel blending components from biomass derived pyrolysis oil

    DOE Patents [OSTI]

    McCall, Michael J.; Brandvold, Timothy A.; Elliott, Douglas C.

    2012-12-11

    A process for the conversion of biomass derived pyrolysis oil to liquid fuel components is presented. The process includes the production of diesel, aviation, and naphtha boiling point range fuels or fuel blending components by two-stage deoxygenation of the pyrolysis oil and separation of the products.

  11. Vehicle Technologies Office Merit Review 2015: Overview of the...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    the VTO Fuel and Lubricant Technologies R&D Vehicle Technologies Office Merit Review 2015: Overview of the VTO Fuel and Lubricant Technologies R&D Presentation given by U.S....

  12. The Advanced Petroleum-Based Fuels Program DECSE and APBF Overview

    SciTech Connect (OSTI)

    2000-04-11

    The following topics are summarized: Role of fuel blends in controlling engine-out emissions; Effect of fuels and lubricants on emission control devices; and Effect of fuels and lubricants on vehicle emissions and operations.

  13. AWEA O&M Recommended Practices Series Part VII: Wind Turbine...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AWEA O&M Recommended Practices Series Part VII: Wind Turbine Gear Lubricant Flushing Procedures AWEA O&M Recommended Practices Series Part VII: Wind Turbine Gear Lubricant Flushing...

  14. METHOD OF INHIBITING IRRADIATION-INDUCED VISCOSITY INCREASE OF ORGANIC FLUIDS

    DOE Patents [OSTI]

    Denison, G.H.; Bolt, R.O.; Kent, J.W.; Christiansen, F.A.; Carroll, J.G.

    1963-12-24

    Methods of reducing radiation-induced thickening of lubricating oils are presented. A system subjected to nuclear radiation is lubricated with an oil containing iodonaphthalene, preferably in the amount of 0.5 to 16 per cent by volume. (AEC)

  15. Sustainable Endeavors | Open Energy Information

    Open Energy Info (EERE)

    Sector: Biomass, Renewable Energy Product: Focused on commercialisation of renewable fuels, primarily biodiesel, lubricants, speciality chemicals and other biobased products...

  16. COMMODITIES USED BY WIPP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Flags, Poles, Banners & Accessories ? Fuel, Oil, Grease & Lubricants ? Gases ? Germicides ... Printing & Related Services ? Publications & Audiovisual Material ? Pumping Equipment & ...

  17. COMPARATIVE STUDY ON EXHAUST EMISSIONS FROM DIESEL- AND CNG-POWERED...

    Office of Scientific and Technical Information (OSTI)

    ... Research Org: French Agency of Environment and Energy Management, Air & Transport Division ... SPAN; LUBRICANTS; MODIFICATIONS; NOISE POLLUTION; POLLUTANTS; RELIABILITY; TRANSPORT; ...

  18. Uncovering Fundamental Ash-Formation Mechanisms and Potential Means to Control the Impact on DPF Performance and Engine Efficiency

    Broader source: Energy.gov [DOE]

    Results illustrate ash particle growth and formation pathways, and influence of lubricant chemistry and exhaust conditions on fundamental ash properties

  19. Fuel Tables.indd

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    F6: Lubricants consumption, price, and expenditure estimates, 2014 State Consumption Prices a Expenditures Industrial Transportation Total Industrial Transportation Total ...

  20. NREL: Awards and Honors - Electroexploded Metal Nanopowders

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Metal Nanopowders include catalysis, batteries, microelectronic contacts, lubrication, sinteringwelding, coating substrates for wear or corrosion resistance, and more...

  1. Improved Die Casting Process to Preserve the Life of the Die Casting Dies

    SciTech Connect (OSTI)

    None

    2004-11-01

    Study the combined effects of die design, proper internal cooling and efficient die lubricants on die life.

  2. EVENT: 2016 AMERICAN ENERGY & MANUFACTURING COMPETITIVENESS NORTHEAST

    Broader source: Energy.gov (indexed) [DOE]

    Demonstrate Improved Fuel Economy | Department of Energy Story - Novel Engine Lubrication Anti-Wear Additives Demonstrate Improved Fuel Economy EERE Success Story - Novel Engine Lubrication Anti-Wear Additives Demonstrate Improved Fuel Economy EERE Success Story - Novel Engine Lubrication Anti-Wear Additives Demonstrate Improved Fuel Economy EERE Success Story - Novel Engine Lubrication Anti-Wear Additives Demonstrate Improved Fuel Economy Oak Ridge National Laboratory (ORNL) has been

  3. Microsoft Word - 2012 ASER R2

    Energy Savers [EERE]

    ... fluoride, kerosene, lubricating oils, methanol, mineral oils, nitric acid, nitrogen, ... (22 acres) - 2002 & 2003 Injection of hydrogen release compounds - 2004 ...

  4. January

    Energy Savers [EERE]

    ... peroxide, kerosene, lubricating oil, methanol, nitric acid, nitrogen, PCBs, ... (22 acres) - 2002 & 2003 Injection of hydrogen release compounds - 2004 ...

  5. Microsoft Word - 2013 ASER.docx

    Office of Environmental Management (EM)

    ... oxide, limestone, lubricating oils, methanol, mineral oils, nitric acid, nitrogen, ... (22 acres) - 2002 & 2003 Injection of hydrogen release compounds - 2004 ...

  6. Annual Site Environmental Report

    Office of Environmental Management (EM)

    ... oxide, limestone, lubricating oils, methanol, mineral oils, nitric acid, nitrogen, ... (22 acres) - 2002 & 2003 Injection of hydrogen release compounds - 2004 ...

  7. Department of Energy Awards More Than $175 Million for Advanced...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... supports research in electric drive vehicle systems, advanced combustion engines, materials technologies, fuels and lubricants, energy storage, and automotive electronics. ...

  8. Rotating plug bearing and seal

    DOE Patents [OSTI]

    Wade, Elman E.

    1977-01-01

    A bearing and seal structure for nuclear reactors utilizing rotating plugs above the nuclear reactor vessel. The structure permits lubrication of bearings and seals of the rotating plugs without risk of the lubricant draining into the reactor vessel below. The structure permits lubrication by utilizing a rotating outer race bearing.

  9. Molecular Foundry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Flatter and Faster: Transition Metal Dichalcogendies at the Molecular Foundry (Part II) Brain Imaging and Optical Manipulation Active Nanointerfaces for Electrochemistry SAXS-WAXS...

  10. Climax Global Energy | Open Energy Information

    Open Energy Info (EERE)

    Place: Summit, New Jersey Zip: 7901 Product: The company converts landfill-bound plastics into high value feedstock for clean biodiesel, syn-lube and wax markets. Coordinates:...

  11. Search results | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Careers http:energy.goveereeducationexplore-bioenergy-technology-careers Page History of Wind Energy Through history, the use of wind power has waxed and waned,from the...

  12. Search results | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    in energy. http:energy.goveereeducationdownloadsenergy-literacy-videos Page History of Wind Energy Through history, the use of wind power has waxed and waned,from the...

  13. Enabling Small-Scale Biomass Gasification for Liquid Fuel Production

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ...activity wax-free Chevron cobalt-zeolite hybrid catalyst - Initial testing carried ... Synthesis Performance of a Chevron Co- Zeolite Hybrid Liquid Selective Catalyst Time on ...

  14. Table Definitions, Sources, and Explanatory Notes

    Gasoline and Diesel Fuel Update (EIA)

    ... reformulated or conventional based on emissions performance and the intended end use in ... products, other hydrocarbons and oxygenates, pentanes plus, petroleum coke, and waxes. ...

  15. Table Definitions, Sources, and Explanatory Notes

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    reformulated or conventional based on emissions performance and the intended end use in ... waxes, petroleum coke, asphalt, road oil, still gas, and miscellaneous products. ...

  16. Host cells and methods for producing isoprenyl alkanoates (Patent...

    Office of Scientific and Technical Information (OSTI)

    the esterification of an isoprenol and a straight-chain fatty acid, such as an alcohol acetyltransferase (AAT), wax ester synthasediacylglycerol acyltransferase (WSDGAT) ...

  17. Evaluation of a Heat Flux Sensor for Spray Cooling for the Die Casting Processes

    SciTech Connect (OSTI)

    Sabau, Adrian S; Wu, Zhuoxi

    2007-02-01

    During the die casting process, lubricants are sprayed in order to cool the dies and facilitate the ejection of the casting. In this paper, a new technique for measuring the heat flux during lubricant application is evaluated. Data from experiments conducted using water spray are first presented. Water spray experiments were conducted for different initial plate temperatures. Measurements were conducted for the application of two different lubricants, of dilution ratios of 1/15 and 1/50 of lubricant in water. The measurement uncertainties were documented. The results show that the surface temperature decreases initially very fast. Numerical simulation results confirmed that the abrupt temperature drop is not an artifact but illustrates the thermal shock experienced by the dies during the initial stages of lubricant application. The lubricant experiments show that the sensor can be successfully used for testing die lubricants with typical dilution ratios encountered in the die casting process.

  18. Synthetic crude oils carcinogenicity screening tests. Progress report, September 15, 1979-March 15, 1980

    SciTech Connect (OSTI)

    Calkins, W.H.; Deye, J.F.; King, C.F.; Hartgrove, R.W.; Krahn, D.F.

    1980-01-01

    Four crude oils (H Coal-Fuel Oil Mode, Occidental in situ Shale Oil, Exxon Donor Solvent Liquid, and SRC II) which were distilled into four fractions (naphtha, mid-distillate, gas oil and residue) for analysis and biological screening testing during the last report period were tested for mutagenicity by the Ames test and for tumor initiating activity by an initiation/promotion (skin painting) test. Substantial agreement exists between Ames and skin painting results. Low boiling naphtha fractions of the 4 crude oils showed little or no mutagenicity or tumor initiating activity by the two tests used. The higher boiling fractions (gas oils and residues) and the crude oils themselves were mutagenic and exhibited tumor initiation activity. The coal derived fractions were more active by both tests than the shale oil fractions.

  19. Donor solvent coal liquefaction with bottoms recycle at elevated pressure

    DOE Patents [OSTI]

    Bauman, Richard F.; Taunton, John W.; Anderson, George H.; Trachte, Ken L.; Hsia, Steve J.

    1982-01-01

    An improved process for liquefying solid carbonaceous materials wherein increased naphtha yields are achieved by effecting the liquefaction at a pressure within the range from about 1750 to about 2800 psig in the presence of recycled bottoms and a hydrogen-donor solvent containing at least 0.8 wt % donatable hydrogen. The liquefaction is accomplished at a temperature within the range from about 700.degree. to about 950.degree. F. The coal:bottoms ratio in the feed to liquefaction will be within the range from about 1:1 to about 5:1 and the solvent or diluent to total solids ratio will be at least 1.5:1 and preferably within the range from about 1.6:1 to about 3:1. The yield of naphtha boiling range materials increases as the pressure increases but generally reaches a maximum at a pressure within the range from about 2000 to about 2500 psig.

  20. Total Crude Oil and Petroleum Products Exports

    U.S. Energy Information Administration (EIA) Indexed Site

    Exports Product: Total Crude Oil and Petroleum Products Crude Oil Natural Gas Plant Liquids and Liquefied Refinery Gases Pentanes Plus Liquefied Petroleum Gases Ethane/Ethylene Propane/Propylene Normal Butane/Butylene Isobutane/Isobutylene Other Liquids Hydrogen/Oxygenates/Renewables/Other Hydrocarbons Oxygenates (excl. Fuel Ethanol) Methyl Tertiary Butyl Ether (MTBE) Other Oxygenates Renewable Fuels (incl. Fuel Ethanol) Fuel Ethanol Biomass-Based Diesel Unfinished Oils Naphthas and Lighter

  1. Integrated coal liquefaction process

    DOE Patents [OSTI]

    Effron, Edward

    1978-01-01

    In a process for the liquefaction of coal in which coal liquids containing phenols and other oxygenated compounds are produced during the liquefaction step and later hydrogenated, oxygenated compounds are removed from at least part of the coal liquids in the naphtha and gas oil boiling range prior to the hydrogenation step and employed as a feed stream for the manufacture of a synthesis gas or for other purposes.

  2. Total number of slots consumed in long_excl.q (exclusive nodes) will be

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Product: Total Crude Oil and Petroleum Products Crude Oil Natural Gas Plant Liquids and Liquefied Refinery Gases Pentanes Plus Liquefied Petroleum Gases Ethane/Ethylene Propane/Propylene Normal Butane/Butylene Isobutane/Isobutylene Other Liquids Hydrogen/Oxygenates/Renewables/Other Hydrocarbons Oxygenates (excl. Fuel Ethanol) Methyl Tertiary Butyl Ether (MTBE) Other Oxygenates Renewable Fuels (incl. Fuel Ethanol) Fuel Ethanol Biomass-Based Diesel Unfinished Oils Naphthas and Lighter Kerosene and

  3. West Virginia Native Selected to Present at the Council for Chemical Research Me

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Reformulated Gasoline Blend. Comp. Conventional Gasoline Blend. Comp. MTBE (Oxygenate) Other Oxygenates Fuel Ethanol (Renewable) Biomass-Based Diesel (Renewable) Other Renewable Diesel Distillate Fuel Oil Distillate F.O., 15 ppm and under Distillate F.O., 15 to 500 ppm Distillate F.O., Greater than 500 ppm Distillate F.O., 501 to 2000 ppm Distillate F.O., Greater than 2000 ppm Kerosene Finished Aviation Gasoline Aviation Gasoline Blending Components Kerosene-Type Jet Fuel Special Naphthas

  4. North Dakota Refining Capacity Study

    SciTech Connect (OSTI)

    Dennis Hill; Kurt Swenson; Carl Tuura; Jim Simon; Robert Vermette; Gilberto Marcha; Steve Kelly; David Wells; Ed Palmer; Kuo Yu; Tram Nguyen; Juliam Migliavacca

    2011-01-05

    According to a 2008 report issued by the United States Geological Survey, North Dakota and Montana have an estimated 3.0 to 4.3 billion barrels of undiscovered, technically recoverable oil in an area known as the Bakken Formation. With the size and remoteness of the discovery, the question became 'can a business case be made for increasing refining capacity in North Dakota?' And, if so what is the impact to existing players in the region. To answer the question, a study committee comprised of leaders in the region's petroleum industry were brought together to define the scope of the study, hire a consulting firm and oversee the study. The study committee met frequently to provide input on the findings and modify the course of the study, as needed. The study concluded that the Petroleum Area Defense District II (PADD II) has an oversupply of gasoline. With that in mind, a niche market, naphtha, was identified. Naphtha is used as a diluent used for pipelining the bitumen (heavy crude) from Canada to crude markets. The study predicted there will continue to be an increase in the demand for naphtha through 2030. The study estimated the optimal configuration for the refinery at 34,000 barrels per day (BPD) producing 15,000 BPD of naphtha and a 52 percent refinery charge for jet and diesel yield. The financial modeling assumed the sponsor of a refinery would invest its own capital to pay for construction costs. With this assumption, the internal rate of return is 9.2 percent which is not sufficient to attract traditional investment given the risk factor of the project. With that in mind, those interested in pursuing this niche market will need to identify incentives to improve the rate of return.

  5. Crude Oil and Petroleum Products Total Stocks Stocks by Type

    U.S. Energy Information Administration (EIA) Indexed Site

    Stocks by Type Product: Crude Oil and Petroleum Products Crude Oil All Oils (Excluding Crude Oil) Pentanes Plus Liquefied Petroleum Gases Ethane/Ethylene Propane/Propylene Normal Butane/Butylene Isobutane/Butylene Other Hydrocarbons Oxygenates (excluding Fuel Ethanol) MTBE Other Oxygenates Renewables (including Fuel Ethanol) Fuel Ethanol Renewable Diesel Fuel Other Renewable Fuels Unfinished Oils Unfinished Oils, Naphthas & Lighter Unfinished Oils, Kerosene & Light Gas Unfinished Oils,

  6. West Coast (PADD 5) Total Crude Oil and Products Imports

    U.S. Energy Information Administration (EIA) Indexed Site

    Reformulated Gasoline Blend. Comp. Conventional Gasoline Blend. Comp. MTBE (Oxygenate) Other Oxygenates Fuel Ethanol (Renewable) Biomass-Based Diesel (Renewable) Other Renewable Diesel Distillate Fuel Oil Distillate F.O., 15 ppm and under Distillate F.O., 15 to 500 ppm Distillate F.O., Greater than 500 ppm Distillate F.O., 501 to 2000 ppm Distillate F.O., Greater than 2000 ppm Kerosene Finished Aviation Gasoline Aviation Gasoline Blending Components Kerosene-Type Jet Fuel Special Naphthas

  7. Process Design and Economics for the Conversion of Lignocellulosic Biomass to Hydrocarbons: Dilute-Acid and Enzymatic Deconstruction of Biomass to Sugars and Catalytic Conversion of Sugars to Hydrocarbons

    SciTech Connect (OSTI)

    Davis, R.; Tao, L.; Scarlata, C.; Tan, E. C. D.; Ross, J.; Lukas, J.; Sexton, D.

    2015-03-01

    This report describes one potential conversion process to hydrocarbon products by way of catalytic conversion of lignocellulosic-derived hydrolysate. This model leverages expertise established over time in biomass deconstruction and process integration research at NREL, while adding in new technology areas for sugar purification and catalysis. The overarching process design converts biomass to die die diesel- and naphtha-range fuels using dilute-acid pretreatment, enzymatic saccharification, purifications, and catalytic conversion focused on deoxygenating and oligomerizing biomass hydrolysates.

  8. EIS-0002: Allocation of Petroleum Feedstock, Baltimore Gas & Electric Co., Sollers Point SNG Plant, Sollers Point, Baltimore County, MD

    Broader source: Energy.gov [DOE]

    The Economic Regulatory Administration (ERA) developed this EIS to evaluate the social, economic and environmental impacts which may occur within the Baltimore Gas and Electric Company (BG&E) service area as a result of the ERA' s proposed decision to allocate up to 2,186,000 barrels per year of naphtha feedstock to BG&E to operate BG&E's existing synthetic natural gas facility located on Sollers Point in Baltimore County, Maryland.

  9. KINETIC MODELING OF A FISCHER-TROPSCH REACTION OVER A COBALT CATALYST IN A SLURRY BUBBLE COLUMN REACTOR FOR INCORPORATION INTO A COMPUTATIONAL MULTIPHASE FLUID DYNAMICS MODEL

    SciTech Connect (OSTI)

    Anastasia Gribik; Doona Guillen, PhD; Daniel Ginosar, PhD

    2008-09-01

    Currently multi-tubular fixed bed reactors, fluidized bed reactors, and slurry bubble column reactors (SBCRs) are used in commercial Fischer Tropsch (FT) synthesis. There are a number of advantages of the SBCR compared to fixed and fluidized bed reactors. The main advantage of the SBCR is that temperature control and heat recovery are more easily achieved. The SBCR is a multiphase chemical reactor where a synthesis gas, comprised mainly of H2 and CO, is bubbled through a liquid hydrocarbon wax containing solid catalyst particles to produce specialty chemicals, lubricants, or fuels. The FT synthesis reaction is the polymerization of methylene groups [-(CH2)-] forming mainly linear alkanes and alkenes, ranging from methane to high molecular weight waxes. The Idaho National Laboratory is developing a computational multiphase fluid dynamics (CMFD) model of the FT process in a SBCR. This paper discusses the incorporation of absorption and reaction kinetics into the current hydrodynamic model. A phased approach for incorporation of the reaction kinetics into a CMFD model is presented here. Initially, a simple kinetic model is coupled to the hydrodynamic model, with increasing levels of complexity added in stages. The first phase of the model includes incorporation of the absorption of gas species from both large and small bubbles into the bulk liquid phase. The driving force for the gas across the gas liquid interface into the bulk liquid is dependent upon the interfacial gas concentration in both small and large bubbles. However, because it is difficult to measure the concentration at the gas-liquid interface, coefficients for convective mass transfer have been developed for the overall driving force between the bulk concentrations in the gas and liquid phases. It is assumed that there are no temperature effects from mass transfer of the gas phases to the bulk liquid phase, since there are only small amounts of dissolved gas in the liquid phase. The product from the incorporation of absorption is the steady state concentration profile of the absorbed gas species in the bulk liquid phase. The second phase of the model incorporates a simplified macrokinetic model to the mass balance equation in the CMFD code. Initially, the model assumes that the catalyst particles are sufficiently small such that external and internal mass and heat transfer are not rate limiting. The model is developed utilizing the macrokinetic rate expression developed by Yates and Satterfield (1991). Initially, the model assumes that the only species formed other than water in the FT reaction is C27H56. Change in moles of the reacting species and the resulting temperature of the catalyst and fluid phases is solved simultaneously. The macrokinetic model is solved in conjunction with the species transport equations in a separate module which is incorporated into the CMFD code.

  10. Method for hydrocracking a heavy polynuclear hydrocarbonaceous feedstock in the presence of a molten metal halide catalyst

    DOE Patents [OSTI]

    Gorin, Everett (San Rafael, CA)

    1981-01-01

    A method for hydrocracking a heavy polynuclear hydrocarbonaceous feedstock to produce lighter hydrocarbon fuels by contacting the feedstock with hydrogen in the presence of a molten metal halide catalyst, the method comprising: mixing the feedstock with a heavy naphtha fraction which has an initial boiling point from about 100.degree. to about 160.degree. C. with a boiling point difference between the initial boiling point and the final boiling point of no more than about 50.degree. C. to produce a mixture; thereafter contacting the mixture with partially spent molten metal halide and hydrogen under temperature and pressure conditions so that the temperature is near the critical temperature of the heavy naphtha fraction; separating at least a portion of the heavy naphtha fraction and lighter hydrocarbon fuels from the partially spent molten metal halide, unreacted feedstock and reaction products; thereafter contacting the partially spent molten metal halide, unreacted feedstock and reaction products with hydrogen and fresh molten metal halide in a hydrocracking zone to produce additional lighter hydrocarbon fuels and separating at least a major portion of the lighter hydrocarbon fuels from the spent molten metal halide.

  11. System and process for upgrading hydrocarbons

    SciTech Connect (OSTI)

    Bingham, Dennis N.; Klingler, Kerry M.; Smith, Joseph D.; Turner, Terry D.; Wilding, Bruce M.

    2015-08-25

    In one embodiment, a system for upgrading a hydrocarbon material may include a black wax upgrade subsystem and a molten salt gasification (MSG) subsystem. The black wax upgrade subsystem and the MSG subsystem may be located within a common pressure boundary, such as within a pressure vessel. Gaseous materials produced by the MSG subsystem may be used in the process carried out within the black wax upgrade subsystem. For example, hydrogen may pass through a gaseous transfer interface to interact with black wax feed material to hydrogenate such material during a cracking process. In one embodiment, the gaseous transfer interface may include one or more openings in a tube or conduit which is carrying the black wax material. A pressure differential may control the flow of hydrogen within the tube or conduit. Related methods are also disclosed.

  12. Rotary seal with improved film distribution

    DOE Patents [OSTI]

    Dietle, Lannie Laroy; Schroeder, John Erick

    2015-09-01

    The present invention is a generally circular rotary seal that establishes sealing between relatively rotatable machine components for lubricant retention and environmental exclusion, and incorporates seal geometry that interacts with the lubricant during relative rotation to distribute a lubricant film within the dynamic sealing interface. The features of a variable inlet size, a variable dynamic lip flank slope, and a reduction in the magnitude and circumferentially oriented portion of the lubricant side interfacial contact pressure zone at the narrowest part of the lip, individually or in combination thereof, serve to maximize interfacial lubrication in severe operating conditions, and also serve to minimize lubricant shear area, seal torque, seal volume, and wear, while ensuring retrofitability into the seal grooves of existing equipment.

  13. Rotary seal with improved film distribution

    DOE Patents [OSTI]

    Dietle, Lannie Laroy; Schroeder, John Erick

    2013-10-08

    The present invention is a generally circular rotary seal that establishes sealing between relatively rotatable machine components for lubricant retention and environmental exclusion, and incorporates seal geometry that interacts with the lubricant during relative rotation to distribute a lubricant film within the dynamic sealing interface. The features of a variable inlet size, a variable dynamic lip flank slope, and a reduction in the magnitude and circumferentially oriented portion of the lubricant side interfacial contact pressure zone at the narrowest part of the lip, individually or in combination thereof, serve to maximize interfacial lubrication in severe operating conditions, and also serve to minimize lubricant shear area, seal torque, seal volume, and wear, while ensuring retrofitability into the seal grooves of existing equipment.

  14. Vehicle Technologies Office Merit Review 2014: Ionic Liquids as Anti-Wear

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Additives for Next-Generation Low-Viscosity Fuel-Efficient Engine Lubricants | Department of Energy Ionic Liquids as Anti-Wear Additives for Next-Generation Low-Viscosity Fuel-Efficient Engine Lubricants Vehicle Technologies Office Merit Review 2014: Ionic Liquids as Anti-Wear Additives for Next-Generation Low-Viscosity Fuel-Efficient Engine Lubricants Presentation given by Oak Ridge National Laboratory at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit

  15. Skew and twist resistant hydrodynamic rotary shaft seal

    DOE Patents [OSTI]

    Dietle, L.; Kalsi, M.S.

    1999-02-23

    A hydrodynamically lubricated squeeze packing type rotary shaft seal suitable for lubricant retention and environmental exclusion which incorporates one or more resilient protuberances which cooperate with the gland walls to hold the seal straight in its installation groove in unpressurized and low pressure lubricant retention applications thereby preventing skew-induced wear caused by impingement of abrasive contaminants present in the environment, and which also serve as radial bearings to prevent tipping of the seal within its installation gland. 14 figs.

  16. Skew and twist resistant hydrodynamic rotary shaft seal

    DOE Patents [OSTI]

    Dietle, Lannie; Kalsi, Manmohan Singh

    1999-01-01

    A hydrodynamically lubricated squeeze packing type rotary shaft seal suitable for lubricant retention and environmental exclusion which incorporates one or more resilient protuberances which and cooperate with the gland walls to hold the seal straight in its installation groove in unpressurized and low pressure lubricant retention applications thereby preventing skew-induced wear caused by impingement of abrasive contaminants present in the environment, and which also serve as radial bearings to prevent tipping of the seal within its installation gland.

  17. Development of High Power Density Driveline for Vehicles | Department of

    Broader source: Energy.gov (indexed) [DOE]

    Energy FAME biodiesel will likely remain a part of the global diesel pool for the coming years and the use of biodiesel can lead to lubrication issues. PDF icon deer09_lauterwasser.pdf More Documents & Publications The Road to Improved Heavy Duty Fuel Economy Effects of Fuel Dilution with Biodiesel on Lubricant Acidity, Oxidation and Corrosion Biodiesel Impact on Engine Lubricant Oil Dilution Energy

    2 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual

  18. Diesel Engine Oil Technology Insights and Opportunities | Department of

    Broader source: Energy.gov (indexed) [DOE]

    Energy Perrformance of API CJ-4 diesel engine lubricating oil and emerging lubricant technologiy are examined with respect to protection and fuel economy benefits. PDF icon deer08_arcy.pdf More Documents & Publications Development of High Performance Heavy Duty Engine Oils Verification of Shell GTL Fuel as CARB Alternative Diesel Effects of Fuel Dilution with Biodiesel on Lubricant Acidity, Oxidation and Corrosion

  19. Fuel Additive Strategies for Enhancing the Performance of Engines and

    Broader source: Energy.gov (indexed) [DOE]

    Engine Oils | Department of Energy 3 DEER Conference Presentation: ChevronTexaco Technology PDF icon 2003_deer_kaufman.pdf More Documents & Publications Vehicle Technologies Office: 2012 Fuel and Lubricant Technologies R&D Annual Progress Report Vehicle Technologies Office: 2013 Fuel and Lubricant Technologies R&D Annual Progress Report Lubricants - Pathway to Improving Fuel Efficiency of Legacy Fleet Vehicles

  20. GRAPHITE EXTRUSIONS

    DOE Patents [OSTI]

    Benziger, T.M.

    1959-01-20

    A new lubricant for graphite extrusion is described. In the past, graphite extrusion mixtures have bcen composed of coke or carbon black, together with a carbonaceous binder such as coal tar pitch, and a lubricant such as petrolatum or a colloidal suspension of graphite in glycerin or oil. Sinee sueh a lubricant is not soluble in, or compatible with the biiider liquid, such mixtures were difficult to extrude, and thc formed pieees lacked strength. This patent teaches tbe use of fatty acids as graphite extrusion lubricants and definite improvemcnts are realized thereby since the fatty acids are soluble in the binder liquid.

  1. Performance of Biofuels and Biofuel Blends

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Performance of Biofuels and Biofuel Blends Robert McCormick Vehicle Technologies Program Merit Review - Fuels and Lubricants Technologies May 16, 2013 Project ID: FT003 This ...

  2. Development and Applications of Catalyzed Diesel Particulate...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    In-Situ Optical Analysis of Ash Formation and Transport Controlled Experiments on the Effects of LubricantAdditive (Low-Ash, Ashless) Characteristics on DPF Degradation

  3. Vehicle Technologies Office Merit Review 2014: Can hard coatings...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Driveline for Vehicles Vehicle Technologies Office Merit Review 2014: Ionic Liquids as Anti-Wear Additives for Next-Generation Low-Viscosity Fuel-Efficient Engine Lubricants

  4. Vehicle Technologies Office Merit Review 2014: Ionic Liquids...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Low-Viscosity Fuel-Efficient Engine Lubricants Vehicle Technologies Office Merit Review 2014: Ionic Liquids as Anti-Wear Additives for Next-Generation Low-Viscosity ...

  5. Hydrogen engine and combustion control process

    DOE Patents [OSTI]

    Swain, Michael R.; Swain, Matthew N.

    1997-01-01

    Hydrogen engine with controlled combustion comprises suction means connected to the crankcase reducing or precluding flow of lubricating oil or associated gases into the combustion chamber.

  6. Development and Demonstration of a Fuel-Efficient Class 8 Highway...

    Office of Environmental Management (EM)

    ... * Advanced Lighting Concepts - LightForm TM * Energy Efficient * Aerodynamic - LED lighting * Low-friction tires * Low viscosity oils & lubricants * Carrier lube level ...

  7. Development of High Performance Heavy Duty Engine Oils

    Broader source: Energy.gov [DOE]

    FAME biodiesel will likely remain a part of the global diesel pool for the coming years and the use of biodiesel can lead to lubrication issues.

  8. 2015 Annual Merit Review, Vehicle Technologies Office

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... Performance of Biofuels and Biofuel Blends (Fuel and Lubricant Technologies) 4-143 McNenly, Matthew; LLNL. Improved Solvers for Advanced Engine Combustion Simulation (Advanced ...

  9. Categorical Exclusion Determinations: Tennessee | Department...

    Energy Savers [EERE]

    February 26, 2016 CX-100506 Categorical Exclusion Determination Biofuel Micro-Refineries ... Low-Viscosity Oils for Automotive Engine and Rear Axle Lubrication for 4% Improved ...

  10. Center for Transportation Research | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Advanced Vehicle Technologies Friction, Wear, and Lubrication Technologies Fuel Spray Analysis Multi-Dimensional Modeling Vehicle-Grid Interoperability CTR research occurs in...

  11. Table Definitions, Sources, and Explanatory Notes

    Gasoline and Diesel Fuel Update (EIA)

    including heating oils; gasoline, diesel and jet fuels; lubricants; asphalt; ethane, propane, and butane; and many other products used for their energy or chemical content. ...

  12. Ionic Liquids as Multifunctional Ashless Additives for Engine...

    Broader source: Energy.gov (indexed) [DOE]

    A group of oil-miscible ionic liquids has been developed by an ORNL-GM team as candidate lubricant additives with promising physicalchemical properties and potential multiple ...

  13. The Impact of Oil Consumption Mechanisms on Diesel Exhaust Particle...

    Broader source: Energy.gov (indexed) [DOE]

    Mass Correlation of Engine Emissions with Spectral Instruments Lubricant Formulation and Consumption Effects on Diesel Exhaust Ash Emissions: Chemical and Physical Characteristics ...

  14. RPT_PERIOD","R_S_NAME","LINE_NUM","PROD_CODE","PROD_NAME","PORT...

    U.S. Energy Information Administration (EIA) Indexed Site

    " "applicationvnd.ms-excel","AFTON CHEMICAL CORP ",1,854,"Lubricants, ..."ANGOLA",496,0.54,23.6,"CITGO REFINING & CHEMICAL INC ",478,"CORPUS CHRISTI","TX","TEXAS",...

  15. index | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Technologies Office Batteries and Energy Storage Advanced Combustion Engines Hybrid and Vehicle Systems Advanced Power Electronics and Electrical Machines Fuels and Lubricants...

  16. Table Definitions, Sources, and Explanatory Notes

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    heating oils; gasoline, diesel and jet fuels; lubricants; ... Kerosene has a maximum distillation temperature of 400 ... aviation fuels and meets engine requirements at high ...

  17. Vehicle Technologies Program Government Performance and Results...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    stock were attributed to individual VTO technology areas, which included batteries and electric drives, advanced combustion engines, fuels and lubricants, materials (i.e.,...

  18. High-Temperature Components for Rankine-Cycle-Based Waste Heat...

    Broader source: Energy.gov (indexed) [DOE]

    Biodiesel Impact on Engine Lubricant Oil Dilution Statistical Analysis of Transient Cycle Test Results in a 40 CFR Part 1065 Engine Dynamometer Test Cell Small-Particle Solar ...

  19. A Novel Approach in Determining Oil Dilution Level on a DPF Equipped...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications The Advanced Collaborative Emissions Study (ACES):Phase 3 Biodiesel Impact on Engine Lubricant Oil Dilution Light Duty Diesels in the United States - ...

  20. Recent Research to Address Technical Barriers to Increased Use...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The Advanced Collaborative Emissions Study (ACES):Phase 3 Diesel Reformers for On-board Hydrogen Applications Minimizing Lubricant-Ash Requirement and Impact on Emission ...

  1. Fungal Genomics Presentation for BETO 2015 Project Peer Review

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... Terpenes Fatty Acidss (lipids) Alkanealkene fuels, lubricants Cycloalkanes ... in Aspergillus oryzae by enhancing expressions of fatty acid synthesis-related genes. ...

  2. Friction and Wear Enhancement of Titanium Alloy Engine Components...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Friction and Wear Enhancement of Titanium Alloy Engine Components Vehicle Technologies Office Merit Review 2014: Can hard coatings and lubricant anti-wear additives work together? ...

  3. EIS_Summary_TextandFigures

    Office of Environmental Management (EM)

    ... of magnetic fields on a daily basis from sources like ... Inadvertent spills of fuel, 28 lubricants, antifreeze, or ... and herbicides, scheduling of construction ...

  4. Feasibility of observing small differences in friction mean effective...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Feasibility of observing small differences in friction mean effective pressure between different lubricating oil formations using small, single-cylinder motored ...

  5. DOE Vehicle Technologies Program 2009 Merit Review Report - Propulsion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    - Lightweight Materials DOE Vehicle Technologies Program 2009 Merit Review Report - Fuels and Lubricants DOE Vehicle Technologies Program 2009 Merit Review Report - Advanced...

  6. Vehicle Technologies Office: 2010 Fuel Technologies R&D Annual...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Vehicle Technologies Office: 2010 Fuel Technologies R&D Annual Progress Report The Fuels Technologies subprogram supports fuels and lubricants research and development (R&D)...

  7. Shell Morocco | Open Energy Information

    Open Energy Info (EERE)

    of Lubricants for motorists and industries; Storage and Distribution of Oils and LPG; Marine and Aviation; Off-Shore Exploration Year Founded: 1922 Phone Number: +212 (0)...

  8. REFRACTORY METAL TUBE DRAWING

    DOE Patents [OSTI]

    Bean, C.H.; Karasek, F.J.

    1963-01-29

    A lubricant for drawing Zr and other refractory metals is described. Metallic Cu powder is added to a solution of acrylic resin in chlorinated hydrocarbon solvent. (AEC)

  9. Shell India Pvt Ltd | Open Energy Information

    Open Energy Info (EERE)

    Services, Solar Product: Delhi-based subsidiary of Royal Dutch Shell having interests in natural gas (LNG), liquefied petroleum gas (LPG), lubricants and bitumen. The firm also...

  10. The Sensitivity of DPF Performance to the Spatial Distribution...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The Sensitivity of DPF Performance to the Spatial Distribution of Ash Generated from Six Lubricant Formulations Discusses potential of DPF pressure drop reduction by optimizing the ...

  11. Vehicle Technologies Office Merit Review 2014: Friction Reduction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Vehicle Technologies Office Merit Review 2014: Can hard coatings and lubricant anti-wear additives work together? An integrated surface technology for...

  12. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... The lubrication of silicon surfaces with alcohol vapors has recently been demonstrated. ... The parent alcohol molecule pentanol, has molecular weight of 88amu, suggesting that ...

  13. Table Definitions, Sources, and Explanatory Notes

    Gasoline and Diesel Fuel Update (EIA)

    lubricants; asphalt; ethane, propane, and butane; and many other products used for their energy or chemical content. Futures Price The price quoted for delivering a specified...

  14. Self regulating formulations for safe hydrogen gettering

    DOE Patents [OSTI]

    Shepodd, Timothy Jon (Livermore, CA)

    2002-01-01

    A method and composition are disclosed for preventing uncontrolled exothermic reaction in the presence of a catalyst. A catalyst deployed as a finely divided powder which is attached to the surface of a low melting point wax or wax-like material which is utilized as a carrier for the catalyst. During operation should the catalyst overheat due to uncontrolled conditions brought about by a run-away reaction the heat of reaction melts the low melting point wax which would itself wet the surface of the catalyst and prevent further catalysis.

  15. Self regulating formulations for safe hydrogen gettering

    DOE Patents [OSTI]

    Shepodd, Timothy Jon

    2004-03-16

    A method and composition are disclosed for preventing uncontrolled exothermic reaction in the presence of a catalyst. A catalyst deployed as a finely divided powder which is attached to the surface of a low melting point wax or wax-like material which is utilized as a carrier for the catalyst. During operation should the catalyst overheat due to uncontrolled conditions brought about by a run-away reaction the heat of reaction melts the low melting point wax which would itself wet the surface of the catalyst and prevent further catalysis.

  16. METHOD OF OPPOSING IRRADIATION-INDUCED VISCOSITY INCREASE IN EMPLOYMENT OF ORGANIC FLUIDS

    DOE Patents [OSTI]

    Balt, R.O.

    1961-10-24

    A method is described for conducting mechanical operations necessitating the use of a lubricant in a medium operaject to reactor irradiation of 0.5 x 10/ sup 12/ to 1 x 10/sup 12/ neut rons/ cm/sup 2//sec. A thiopolyether lubricant such as 16, 19-dioxa-13, 22-dithiatetratriacontane is used. (AEC)

  17. Future Engine Fluids Technologies: Durable, Fuel-Efficient, and

    Broader source: Energy.gov (indexed) [DOE]

    Emissions-Friendly | Department of Energy bardasz.pdf More Documents & Publications Controlled Experiments on the Effects of Lubricant/Additive (Low-Ash, Ashless) Characteristics on DPF Degradation Diesel Particulate Filters: Market Introducution in Europe Characteristics and Effects of Lubricant Additive Chemistry and Exhaust Conditions on Diesel Particulate Filter Service Life and Vehicle Fuel Economy

  18. Breckinridge Project, initial effort

    SciTech Connect (OSTI)

    1982-01-01

    Report IV, Volume 3, provides descriptions, data, and drawings pertaining to H-COAL Recycle Slurry Preparation (Plant 5), H-COAL Recycle Hydrogen Compression (Plant 6), and H-COAL Distillate Separation (Plant 17). H-COAL Recycle Slurry Preparation (Plant 5) receives a slurry stream from H-COAL Primary Separation (Plant 4), and then pumps the slurry through hydrocyclones, producing two slurry streams. One, dilute in solids is recycled back to the reactor. The other, concentrated in solids, is further processed to recover liquid products and is then transferred to Gasification and Purification (Plant 12). H-COAL Recycle Hydrogen Compression (Plant 6) compresses and recycles back to the reactor system hydrogen-rich vapor from H-COAL Primary Separation (Plant 4). This recycling maintains a hydrogen partial pressure and gas flow through the reactor vessel. H-COAL Distillate Separation (Plant 17) processes products from H-COAL Primary Separation (Plant 4) and H-COAL Recycle Slurry Preparation to produce light naphtha for the Gas Plant (Plant 7), middle and heavy distillates for tank farms, and heavy naphtha for Naphtha Hydrotreating and Reforming (Plant 18). The following information is included for each of the three plants: a description of the plant's process design, including the utility balance, heat and material balance (if applicable), and a process flow diagram; an equipment list, including item numbers and descriptions; data sheets and sketches for major plant components; and pertinent engineering drawings. An appendix contains: an overall site plan showing the locations of all plants; and the symbols and legend for the piping and instrument diagrams included in this volume.

  19. Low torque hydrodynamic lip geometry for bi-directional rotation seals

    DOE Patents [OSTI]

    Dietle, Lannie L.; Schroeder, John E.

    2009-07-21

    A hydrodynamically lubricating geometry for the generally circular dynamic sealing lip of rotary seals that are employed to partition a lubricant from an environment. The dynamic sealing lip is provided for establishing compressed sealing engagement with a relatively rotatable surface, and for wedging a film of lubricating fluid into the interface between the dynamic sealing lip and the relatively rotatable surface in response to relative rotation that may occur in the clockwise or the counter-clockwise direction. A wave form incorporating an elongated dimple provides the gradual convergence, efficient impingement angle, and gradual interfacial contact pressure rise that are conducive to efficient hydrodynamic wedging. Skewed elevated contact pressure zones produced by compression edge effects provide for controlled lubricant movement within the dynamic sealing interface between the seal and the relatively rotatable surface, producing enhanced lubrication and low running torque.

  20. Low torque hydrodynamic lip geometry for rotary seals

    SciTech Connect (OSTI)

    Dietle, Lannie L.; Schroeder, John E.

    2015-07-21

    A hydrodynamically lubricating geometry for the generally circular dynamic sealing lip of rotary seals that are employed to partition a lubricant from an environment. The dynamic sealing lip is provided for establishing compressed sealing engagement with a relatively rotatable surface, and for wedging a film of lubricating fluid into the interface between the dynamic sealing lip and the relatively rotatable surface in response to relative rotation that may occur in the clockwise or the counter-clockwise direction. A wave form incorporating an elongated dimple provides the gradual convergence, efficient impingement angle, and gradual interfacial contact pressure rise that are conducive to efficient hydrodynamic wedging. Skewed elevated contact pressure zones produced by compression edge effects provide for controlled lubricant movement within the dynamic sealing interface between the seal and the relatively rotatable surface, producing enhanced lubrication and low running torque.