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Note: This page contains sample records for the topic "na-sg sodium silica" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

Suitability of Silica Gel to Process INEEL Sodium Bearing Waste - Letter Report  

SciTech Connect

The suitability of using the silica gel process for Idaho National Engineering and Environmental Laboratory (INEEL) sodium bearing waste was investigated during fiscal year 2000. The study was co-funded by the Tanks Focus Area as part of TTP No. ID-77WT-31 and the High Level Waste Program. The task also included the investigation of possible other absorbents. Scoping tests and examination of past work showed that the silica gel absorption/adsorption and drying method was the most promising; thus only silica gel was studied and not other absorbents. The documentation on the Russian silica gel process provided much of the needed information but did not provide some of the processing detail so these facts had to be inferred or gleaned from the literature.

Kirkham, Robert John; Herbst, Alan Keith

2000-09-01T23:59:59.000Z

2

Sodium  

SciTech Connect

Some of the properties of sodium are reviewed, particularly its properties which make it useful as a FBR coolant. The FFTF and other sodium research facilities at HEDL are described. (DLC)

1979-09-27T23:59:59.000Z

3

PROGRAM TOPIC: GASIFICATION TECHNOLOGIES PREVENTING AGGLOMERATION PROBLEMS DURING GASIFICATION OF HIGH-SODIUM LIGNITE  

E-Print Network (OSTI)

Previous gasification studies have shown that sodium vapor released from high-sodium lignites can react with silica to form sticky sodium silicates. 1,2,3

Robert S. Dahlin; Johnny R. Dorminey; Southern Company Services; Wanwang Peng; Southern Company Services; Pannalal Vimalch; Southern Company Services

2008-01-01T23:59:59.000Z

4

Kinetics of silica polymerization  

DOE Green Energy (OSTI)

The polymerization of silicic acid in geothermal brine-like aqueous solutions to produce amorphous silica in colloidal form has been studied experimentally and theoretically. A large amount of high quality experimental data has been generated over the temperature rang 23 to 100{sup 0}C. Wide ranges of dissolved silica concentration, pH, and sodium chloride concentration were covered. The catalytic effects of fluoride and the reaction inhibiting effects of aluminum and boron were studied also. Two basic processes have been separately studied: the formation of new colloidal particles by the homogeneous nucleation process and the deposition of dissolved silica on pre-existing colloidal particles. A rigorous theory of the formation of colloidal particles of amorphous silica by homogeneous nucleation was developed. This theory employs the Lothe-Pound formalism, and is embodied in the computer code SILNUC which quantitatively models the homogeneous nucleation and growth of colloidal silica particles in more than enough detail for practical application. The theory and code were extensively used in planning the experimental work and analyzing the data produced. The code is now complete and running in its final form. It is capable of reproducing most of the experimental results to within experimental error. It is also capable of extrapolation to experimentally inaccessible conditions, i.e., high temperatures, rapidly varying temperature and pH, etc.

Weres, O.; Yee, A.; Tsao, L.

1980-05-01T23:59:59.000Z

5

Silica Sand  

NLE Websites -- All DOE Office Websites (Extended Search)

the molds and cores in foundries that make steel castings, and for casting gray iron, brass, aluminum and magnesium metals. Since silica sand has a very high melting point, it is...

6

Visibly photoluminescent silica aerogels  

NLE Websites -- All DOE Office Websites (Extended Search)

Visibly photoluminescent silica aerogels Title Visibly photoluminescent silica aerogels Publication Type Journal Article Year of Publication 1997 Authors Ayers, Michael R., and...

7

Silica Scaling Removal Process  

NLE Websites -- All DOE Office Websites (Extended Search)

Silica Scaling Removal Process Silica Scaling Removal Process Silica Scaling Removal Process Scientists at Los Alamos National Laboratory have developed a novel technology to remove both dissolved and colloidal silica using small gel particles. Available for thumbnail of Feynman Center (505) 665-9090 Email Silica Scaling Removal Process Applications: Cooling tower systems Water treatment systems Water evaporation systems Potential mining applications (produced water) Industry applications for which silica scaling must be prevented Benefits: Reduces scaling in cooling towers by up to 50% Increases the number of cycles of concentration substantially Reduces the amount of antiscaling chemical additives needed Decreases the amount of makeup water and subsequent discharged water (blowdown) Enables considerable cost savings derived from reductions in

8

Silica Scaling Removal Process  

NLE Websites -- All DOE Office Websites (Extended Search)

systems Water treatment systems Water evaporation systems Potential mining applications (produced water) Industry applications for which silica scaling must be prevented Benefits:...

9

Silica Scaling Removal Process  

NLE Websites -- All DOE Office Websites (Extended Search)

applications for which silica scaling must be prevented Benefits: Reduces scaling in cooling towers by up to 50% Increases the number of cycles of concentration substantially...

10

Hydrogen separation using silica membranes  

Science Conference Proceedings (OSTI)

Silica membranes were synthesized on tubular supports of alumina by dipping in silica colloidal solutions. The quality and the performance of the silica membranes were tested by experiments on single gas permeation and gas separation of mixed N2, ... Keywords: Knudsen diffusion, colloidal solution, gas permeation, hydrogen separation, silica membranes

Salvador Alfaroa; Miguel A. Valenzuelaa; Pedro Bosch

2008-11-01T23:59:59.000Z

11

Silica Embedded Metal Hydrides  

DOE Green Energy (OSTI)

A method to produce silica embedded metal hydride was developed. The product is a composite in which metal hydride particles are embedded in a matrix of silica. The silica matrix is highly porous. Hydrogen gas can easily reach the embedded metal hydride particles. The pores are small so that the metal hydride particles cannot leave the matrix. The porous matrix also protects the metal hydride particles from larger and reactive molecules such as oxygen, since the larger gas molecules cannot pass through the small pores easily. Tests show that granules of this composite can absorb hydrogen readily and withstand many cycles without making fines.

Heung, L.K. [Westinghouse Savannah River Company, AIKEN, SC (United States); Wicks, G.G.

1998-08-01T23:59:59.000Z

12

Silica Geothermometers | Open Energy Information  

Open Energy Info (EERE)

Silica Geothermometers Silica Geothermometers Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Technique: Silica Geothermometers Details Activities (0) Areas (0) Regions (0) NEPA(0) Exploration Technique Information Exploration Group: Geochemical Techniques Exploration Sub Group: Geochemical Data Analysis Parent Exploration Technique: Liquid Geothermometry Information Provided by Technique Lithology: Stratigraphic/Structural: Hydrological: Thermal: Used to estimate reservoir temperatures. Dictionary.png Silica Geothermometers: No definition has been provided for this term. Add a Definition Introduction Some experts have stated that the factor that changes the risk assessment of a geothermal prospect the fastest is obtaining attractive chemical confirmation (geothermometry, gas analyses) that a thermal resource exists

13

Idaho Nuclear Technology and Engineering Center Sodium-Bearing Waste Treatment Research and Development FY-2002 Status Report  

SciTech Connect

The Idaho National Engineering and Environmental Laboratory (INEEL) is considering several optional processes for disposal of liquid sodium-bearing waste. During fiscal year 2002, immobilization-related research included of grout formulation development for sodium-bearing waste, absorption of the waste on silica gel, and off-gas system mercury collection and breakthrough using activated carbon. Experimental results indicate that sodium-bearing waste can be immobilized in grout at 70 weight percent and onto silica gel at 74 weight percent. Furthermore, a loading of 11 weight percent mercury in sulfur-impregnated activated carbon was achieved with 99.8% off-gas mercury removal efficiency.

Herbst, Alan Keith; Deldebbio, John Anthony; Mc Cray, John Alan; Kirkham, Robert John; Olson, Lonnie Gene; Scholes, Bradley Adams

2002-09-01T23:59:59.000Z

14

Coagulation chemistries for silica removal from cooling tower water.  

SciTech Connect

The formation of silica scale is a problem for thermoelectric power generating facilities, and this study investigated the potential for removal of silica by means of chemical coagulation from source water before it is subjected to mineral concentration in cooling towers. In Phase I, a screening of many typical as well as novel coagulants was carried out using concentrated cooling tower water, with and without flocculation aids, at concentrations typical for water purification with limited results. In Phase II, it was decided that treatment of source or make up water was more appropriate, and that higher dosing with coagulants delivered promising results. In fact, the less exotic coagulants proved to be more efficacious for reasons not yet fully determined. Some analysis was made of the molecular nature of the precipitated floc, which may aid in process improvements. In Phase III, more detailed study of process conditions for aluminum chloride coagulation was undertaken. Lime-soda water softening and the precipitation of magnesium hydroxide were shown to be too limited in terms of effectiveness, speed, and energy consumption to be considered further for the present application. In Phase IV, sodium aluminate emerged as an effective coagulant for silica, and the most attractive of those tested to date because of its availability, ease of use, and low requirement for additional chemicals. Some process optimization was performed for coagulant concentration and operational pH. It is concluded that silica coagulation with simple aluminum-based agents is effective, simple, and compatible with other industrial processes.

Nyman, May Devan; Altman, Susan Jeanne; Stewart, Tom

2010-02-01T23:59:59.000Z

15

Method for dissolution and stabilization of silica-rich fibers  

DOE Patents (OSTI)

This invention is comprised of a method for dissolving silica-rich fibers such as borosilicate fibers, fiberglass and asbestos to stabilize them for disposal. The method comprises (1) immersing the fibers in hot, five-weight-percent sodium hydroxide solution until the concentration of dissolved silica reaches equilibrium and a only a residue is left (about 48 hours), then immersing the residue in hot, five-weight-percent nitric acid until the residue dissolves (about 96 hours). After adjusting the pH of the dissolved fibers to be caustic, the solution can then be added to a waste vitrification stream for safe disposal. The method is useful in disposing contaminated HEME and HEPA filters.

Jantzen, C.M.

1992-12-31T23:59:59.000Z

16

Method for dissolution and stabilization of silica-rich fibers  

DOE Patents (OSTI)

A method is described for dissolving silica-rich fibers such as borosilicate fibers, fiberglass and asbestos to stabilize them for disposal. The method comprises (1) immersing the fibers in hot, five-weight-percent sodium hydroxide solution until the concentration of dissolved silica reaches equilibrium and a only a residue is left (about 48 hours), then immersing the residue in hot, five-weight-percent nitric acid until the residue dissolves (about 96 hours). After adjusting the pH of the dissolved fibers to be caustic, the solution can then be added to a waste vitrification stream for safe disposal. The method is useful in disposing contaminated HEME and HEPA filters. 1 fig.

Jantzen, C.M.

1997-11-11T23:59:59.000Z

17

Silica aerogel: synthesis and applications  

Science Conference Proceedings (OSTI)

Silica aerogels have drawn a lot of interest both in science and technology because of their low bulk density (up to 95% of their volume is air), hydrophobicity, low thermal conductivity, high surface area, and optical transparency. Aerogels are synthesized ...

Jyoti L. Gurav; In-Keun Jung; Hyung-Ho Park; Eul Son Kang; Digambar Y. Nadargi

2010-01-01T23:59:59.000Z

18

Sample Desorption/Ionization From Mesoporous Silica  

NLE Websites -- All DOE Office Websites (Extended Search)

Sample Desorption/Ionization From Mesoporous Silica Sample Desorption/Ionization From Mesoporous Silica Sample Desorption/Ionization From Mesoporous Silica Mesoporous silica is shown to be a sample holder for laser desorption/ionization of mass spectrometry. Available for thumbnail of Feynman Center (505) 665-9090 Email Sample Desorption/Ionization From Mesoporous Silica Mesoporous silica is shown to be a sample holder for laser desorption/ionization of mass spectrometry. Supported mesoporous silica was prepared by coating an ethanolic silicate solution having a removable surfactant onto a substrate to produce a self-assembled, ordered, nanocomposite silica thin film. The surfactant was chosen to provide a desired pore size between about 1 nanometer diameter and 50 nanometers diameter. Removal of the surfactant resulted in a mesoporous silica thin

19

METHOD FOR REMOVING SODIUM OXIDE FROM LIQUID SODIUM  

DOE Patents (OSTI)

A method is described for removing sodium oxide from a fluent stream of liquid sodium by coldtrapping the sodium oxide. Apparatus utilizing this method is disclosed in United States Patent No. 2,745,552. Sodium will remain in a molten state at temperatures below that at which sodium oxide will crystallize out and form solid deposits, therefore, the contaminated stream of sodium is cooled to a temperature at which the solubility of sodium oxide in sodium is substantially decreased. Thereafter the stream of sodium is passed through a bed of stainless steel wool maintained at a temperature below that of the stream. The stream is kept in contact with the wool until the sodium oxide is removed by crystal growth on the wool, then the stream is reheated and returned to the system. This method is useful in purifying reactor coolants where the sodium oxide would otherwise deposit out on the walls and eventually plug the coolant tubes.

Bruggeman, W.H.; Voorhees, B.G.

1957-12-01T23:59:59.000Z

20

Removal of dissolved and colloidal silica  

DOE Patents (OSTI)

Small amorphous silica particles are used to provide a relatively large surface area upon which silica will preferentially adsorb, thereby preventing or substantially reducing scaling caused by deposition of silica on evaporative cooling tower components, especially heat exchange surfaces. The silica spheres are contacted by the cooling tower water in a sidestream reactor, then separated using gravity separation, microfiltration, vacuum filtration, or other suitable separation technology. Cooling tower modifications for implementing the invention process have been designed.

Midkiff, William S. (Ruidoso, NM)

2002-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "na-sg sodium silica" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Stabilized fuel with silica support structure  

DOE Patents (OSTI)

This report describes a stabilized fuel which is supported by a silica support structure. The silica support structure provides a low density, high porosity vehicle for safely carrying hydrocarbon fuels. The silica support structure for hydrocarbon fuel does not produce toxic material residues on combustion which would pose environmentally sensitive disposal problems. The silica stabilized fuel composition is useful as a low temperature, continuous burning fire starter for wood or charcoal.

Poco, J.F.; Hrubesh, L.W.

1991-12-31T23:59:59.000Z

22

Human Sodium Risks  

NLE Websites -- All DOE Office Websites (Extended Search)

comes from restaurants and it can be hard for a person to tell how much sodium is in restaurant foods. Brands of foods matter: Different brands of the same foods may have...

23

Solidification of Acidic, High Nitrate Nuclear Wastes by Grouting or Absorption on Silica Gel  

Science Conference Proceedings (OSTI)

The use of grout and silica gel were explored for the solidification of four types of acidic, high nitrate radioactive wastes. Two methods of grouting were tested: direct grouting and pre-neutralization. Two methods of absorption on silica gel were also tested: direct absorption and rotary spray drying. The waste simulant acidity varied between 1 N and 12 N. The waste simulant was neutralized by pre-blending calcium hydroxide with Portland cement and blast furnace slag powders prior to mixing with the simulant for grout solidification. Liquid sodium hydroxide was used to partially neutralize the simulant to a pH above 2 and then it was absorbed for silica gel solidification. Formulations for each of these methods are presented along with waste form characteristics and properties. Compositional variation maps for grout formulations are presented which help determine the optimum "recipe" for a particular waste stream. These maps provide a method to determine the proportions of waste, calcium hydroxide, Portland cement, and blast furnace slag that provide a waste form that meets the disposal acceptance criteria. The maps guide researchers in selecting areas to study and provide an operational envelop that produces acceptable waste forms. The grouts both solidify and stabilize the wastes, while absorption on silica gel produces a solid waste that will not pass standard leaching procedures (TCLP) if required. Silica gel wastes can be made to pass most leach tests if heated to 600ºC.

A. K. Herbst; S. V. Raman; R. J. Kirkham

2004-01-01T23:59:59.000Z

24

Sodium sulfur battery seal  

DOE Patents (OSTI)

This disclosure is directed to an improvement in a sodium sulfur battery construction in which a seal between various battery compartments is made by a structure in which a soft metal seal member is held in a sealing position by holding structure. A pressure applying structure is used to apply pressure on the soft metal seal member when it is being held in sealing relationship to a surface of a container member of the sodium sulfur battery by the holding structure. The improvement comprises including a thin, well-adhered, soft metal layer on the surface of the container member of the sodium sulfur battery to which the soft metal seal member is to be bonded.

Mikkor, Mati (Ann Arbor, MI)

1981-01-01T23:59:59.000Z

25

Categorical Exclusion (CX) Determinations By Date | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

3, 2009 3, 2009 CX-000207: Categorical Exclusion Determination NaSi (Sodium Silicide) and Na-SG (Sodium Silica Gell) Powder Hydrogen Fuel Cells CX(s) Applied: B3.6 Date: 11/23/2009 Location(s): New York Office(s): Energy Efficiency and Renewable Energy, Golden Field Office November 23, 2009 CX-000445: Categorical Exclusion Determination Sulfur Dioxide resistant Immobilized Amine Sorbents for Carbon Dioxide Capture CX(s) Applied: A9, A11, B3.1 Date: 11/23/2009 Location(s): Akron, Ohio Office(s): Fossil Energy, National Energy Technology Laboratory November 23, 2009 CX-000206: Categorical Exclusion Determination Michigan Biogas Center of Excellence CX(s) Applied: A9, B3.6 Date: 11/23/2009 Location(s): Flint, Michigan Office(s): Energy Efficiency and Renewable Energy, Golden Field Office

26

Page not found | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

11 - 4820 of 29,416 results. 11 - 4820 of 29,416 results. Download CX-000207: Categorical Exclusion Determination NaSi (Sodium Silicide) and Na-SG (Sodium Silica Gell) Powder Hydrogen Fuel Cells CX(s) Applied: B3.6 Date: 11/23/2009 Location(s): New York Office(s): Energy Efficiency and Renewable Energy, Golden Field Office http://energy.gov/nepa/downloads/cx-000207-categorical-exclusion-determination Download CX-001522: Categorical Exclusion Determination Activity 8 CX(s) Applied: B5.1 Date: 04/01/2010 Location(s): Sacramento County, California Office(s): Energy Efficiency and Renewable Energy, Golden Field Office http://energy.gov/nepa/downloads/cx-001522-categorical-exclusion-determination Download CX-010683: Categorical Exclusion Determination Glen Canyon Substation Stage 09- 50MVA 230/69KV Transformer addition

27

Categorical Exclusion Determinations: New York | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

November 23, 2009 November 23, 2009 CX-000091: Categorical Exclusion Determination Cheektowaga's Installation of Photovoltaic Solar Panels CX(s) Applied: B5.1 Date: 11/23/2009 Location(s): Cheektowaga, New York Office(s): Energy Efficiency and Renewable Energy November 23, 2009 CX-000207: Categorical Exclusion Determination NaSi (Sodium Silicide) and Na-SG (Sodium Silica Gell) Powder Hydrogen Fuel Cells CX(s) Applied: B3.6 Date: 11/23/2009 Location(s): New York Office(s): Energy Efficiency and Renewable Energy, Golden Field Office November 23, 2009 CX-000097: Categorical Exclusion Determination Mount Vernon's Energy Efficiency Retrofits and Programs CX(s) Applied: B5.1, B1.32, A1, A9, A11 Date: 11/23/2009 Location(s): Mount Vernon, New York Office(s): Energy Efficiency and Renewable Energy

28

Categorical Exclusion Determinations: Office of Energy Efficiency and  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

23, 2009 23, 2009 CX-000208: Categorical Exclusion Determination Recovery Act - PEM (Polymer Electrolyte Membrane) Fuel Cell Systems Providing Emergency Reserve and Backup Power CX(s) Applied: B5.1 Date: 11/23/2009 Location(s): Washington Office(s): Energy Efficiency and Renewable Energy, Golden Field Office November 23, 2009 CX-000207: Categorical Exclusion Determination NaSi (Sodium Silicide) and Na-SG (Sodium Silica Gell) Powder Hydrogen Fuel Cells CX(s) Applied: B3.6 Date: 11/23/2009 Location(s): New York Office(s): Energy Efficiency and Renewable Energy, Golden Field Office November 23, 2009 CX-000206: Categorical Exclusion Determination Michigan Biogas Center of Excellence CX(s) Applied: A9, B3.6 Date: 11/23/2009 Location(s): Flint, Michigan Office(s): Energy Efficiency and Renewable Energy, Golden Field Office

29

Categorical Exclusion Determinations: B3.6 | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

24, 2009 24, 2009 CX-000549: Categorical Exclusion Determination Solubility Testing of Boron and Gadolinium in Nitric Acid CX(s) Applied: B3.6 Date: 11/24/2009 Location(s): Aiken, South Carolina Office(s): Environmental Management, Savannah River Operations Office November 23, 2009 CX-000207: Categorical Exclusion Determination NaSi (Sodium Silicide) and Na-SG (Sodium Silica Gell) Powder Hydrogen Fuel Cells CX(s) Applied: B3.6 Date: 11/23/2009 Location(s): New York Office(s): Energy Efficiency and Renewable Energy, Golden Field Office November 23, 2009 CX-000206: Categorical Exclusion Determination Michigan Biogas Center of Excellence CX(s) Applied: A9, B3.6 Date: 11/23/2009 Location(s): Flint, Michigan Office(s): Energy Efficiency and Renewable Energy, Golden Field Office

30

New York | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

November 23, 2009 November 23, 2009 CX-000091: Categorical Exclusion Determination Cheektowaga's Installation of Photovoltaic Solar Panels CX(s) Applied: B5.1 Date: 11/23/2009 Location(s): Cheektowaga, New York Office(s): Energy Efficiency and Renewable Energy November 23, 2009 CX-000207: Categorical Exclusion Determination NaSi (Sodium Silicide) and Na-SG (Sodium Silica Gell) Powder Hydrogen Fuel Cells CX(s) Applied: B3.6 Date: 11/23/2009 Location(s): New York Office(s): Energy Efficiency and Renewable Energy, Golden Field Office November 23, 2009 CX-000097: Categorical Exclusion Determination Mount Vernon's Energy Efficiency Retrofits and Programs CX(s) Applied: B5.1, B1.32, A1, A9, A11 Date: 11/23/2009 Location(s): Mount Vernon, New York Office(s): Energy Efficiency and Renewable Energy

31

Elevated Silica Project at Palisades -- Final Report  

Science Conference Proceedings (OSTI)

Silica concentrations as high as 2-5 ppm in the primary water during startup at some pressurized water reactor (PWR) plants exceed the prevailing industry diagnostic limit of 1 ppm and raise concerns about the possible formation of tenacious silicate deposits on the fuel. To minimize the costs of removing excess silica at fuel outages, EPRI initiated an investigation on the effect of silica on fuel performance. This report documents the final stage of this research, a fuel surveillance project at Palisad...

2000-10-27T23:59:59.000Z

32

PWR RCS Elevated Silica - Fuel Surveillance  

Science Conference Proceedings (OSTI)

Many PWR plants have recently experienced silica concentration as high as 2-5 ppm in the primary water at startup. That level exceeds the prevailing industry diagnostic limit of 1 ppm for safeguarding fuel from potential deposition of tenacious silicates. The high silica experience is primarily limited to plants using silica-containing Boroflex storage racks, which tend to decay in the intense radiation environment in the storage pool. Some plants using recycled boric acid have also experienced high star...

1999-07-28T23:59:59.000Z

33

Preventing ash agglomeration during gasification of high-sodium lignite  

Science Conference Proceedings (OSTI)

Various additives were evaluated to assess their ability to prevent ash agglomeration during the gasification of high-sodium lignite. Additives that showed promise in simple muffle furnace tests included meta-kaolin, vermiculite, two types of silica fume, and one type of bauxite. Additives that were tested and rejected included dolomite, calcite, sand flour, kaolinite, fine kaolin, and calcined bauxite. Based on the muffle furnace test results, the meta-kaolin was selected for a follow-on demonstration in a pilot-scale coal gasifier. Pilot-scale testing showed that the addition of coarse (minus 14-mesh, 920-{mu}m mean size) meta-kaolin at a feed rate roughly equivalent to the ash content of the lignite (10 wt %) successfully prevented agglomeration and deposition problems during gasification of high-sodium lignite at a maximum operating temperature of 927{sup o}C (1700{sup o}F). 13 refs., 24 figs., 1 tab.

Robert S. Dahlin; Johnny R. Dorminey; WanWang Peng; Roxann F. Leonard; Pannalal Vimalchand [Southern Research Institute and Southern Company Services, Wilsonville, AL (USA). Power Systems Development Facility

2009-01-15T23:59:59.000Z

34

Sodium sulfur battery seal  

SciTech Connect

This invention is directed to a seal for a sodium sulfur battery in which a flexible diaphragm sealing elements respectively engage opposite sides of a ceramic component of the battery which separates an anode compartment from a cathode compartment of the battery.

Topouzian, Armenag (Birmingham, MI)

1980-01-01T23:59:59.000Z

35

Cellular membrane trafficking of mesoporous silica nanoparticles  

Science Conference Proceedings (OSTI)

This dissertation mainly focuses on the investigation of the cellular membrane trafficking of mesoporous silica nanoparticles. We are interested in the study of endocytosis and exocytosis behaviors of mesoporous silica nanoparticles with desired surface functionality. The relationship between mesoporous silica nanoparticles and membrane trafficking of cells, either cancerous cells or normal cells was examined. Since mesoporous silica nanoparticles were applied in many drug delivery cases, the endocytotic efficiency of mesoporous silica nanoparticles needs to be investigated in more details in order to design the cellular drug delivery system in the controlled way. It is well known that cells can engulf some molecules outside of the cells through a receptor-ligand associated endocytosis. We are interested to determine if those biomolecules binding to cell surface receptors can be utilized on mesoporous silica nanoparticle materials to improve the uptake efficiency or govern the mechanism of endocytosis of mesoporous silica nanoparticles. Arginine-glycine-aspartate (RGD) is a small peptide recognized by cell integrin receptors and it was reported that avidin internalization was highly promoted by tumor lectin. Both RGD and avidin were linked to the surface of mesoporous silica nanoparticle materials to investigate the effect of receptor-associated biomolecule on cellular endocytosis efficiency. The effect of ligand types, ligand conformation and ligand density were discussed in Chapter 2 and 3. Furthermore, the exocytosis of mesoporous silica nanoparticles is very attractive for biological applications. The cellular protein sequestration study of mesoporous silica nanoparticles was examined for further information of the intracellular pathway of endocytosed mesoporous silica nanoparticle materials. The surface functionality of mesoporous silica nanoparticle materials demonstrated selectivity among the materials and cancer and normal cell lines. We aimed to determine the specific organelle that mesoporous silica nanoparticles could approach via the identification of harvested proteins from exocytosis process. Based on the study of endo- and exocytosis behavior of mesoporous silica nanoparticle materials, we can design smarter drug delivery vehicles for cancer therapy that can be effectively controlled. The destination, uptake efficiency and the cellular distribution of mesoporous silica nanoparticle materials can be programmable. As a result, release mechanism and release rate of drug delivery systems can be a well-controlled process. The deep investigation of an endo- and exocytosis study of mesoporous silica nanoparticle materials promotes the development of drug delivery applications.

Fang, I-Ju

2012-06-21T23:59:59.000Z

36

SURVEY OF SODIUM PUMP TECHNOLOGY  

SciTech Connect

A review is presented of the current status of sodium pump development as related to nuclear power applications. A description is given of the design features and performance characteristics of the more important types of sodium and sodium-- potassium alloy (NaK) pumps. Some requirements for sodium pumps for future large liquid metal reactor systems are presented with some preliminary consideration of the potential of various pump types to meet these requirements. (auth)

Nixon, D.R.

1963-06-01T23:59:59.000Z

37

Text of The Solubility of Silica in Calcium Ferrite Slags  

Science Conference Proceedings (OSTI)

To successfully use lime flux, the dissolution of silica in calcium-ferrite slags must ... samples were chemically analyzed by standard methods for calcium, silica, ...

38

Synthesis and properties of chitosan-silica hybrid aerogels  

NLE Websites -- All DOE Office Websites (Extended Search)

Synthesis and properties of chitosan-silica hybrid aerogels Title Synthesis and properties of chitosan-silica hybrid aerogels Publication Type Journal Article Year of Publication...

39

Synthesis and properties of Chitosan-silica hybrid aerogels  

E-Print Network (OSTI)

chitosan-silica composite aerogels can be easily synthesizedphysical properties of these aerogels. These materials may1. Top: Chitosan-silica aerogel (sample 4), Bottom: Same

Ayers, Michael R.; Hunt, Arlon J.

2001-01-01T23:59:59.000Z

40

Investigations of silica alcogel aging using coherent light  

NLE Websites -- All DOE Office Websites (Extended Search)

Investigations of silica alcogel aging using coherent light Title Investigations of silica alcogel aging using coherent light Publication Type Journal Article Year of Publication...

Note: This page contains sample records for the topic "na-sg sodium silica" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Study of cesium volatility from sodium carbonate based melts  

SciTech Connect

Purpose of this study was to obtain thermodynamic data on cesium volatility from sodium carbonate-based molten salts for application to the Rockwell-ETEC molten salt oxidation process. At 1073 to 1373 K, volatility tests were conducted on a horizontal and a vertical transpiration apparatus using a carrier gas composed of CO{sub 2}(g) and H{sub 2}O(g) which was passed over or bubbled through a sodium carbonate bath containing cesium carbonate and various additives. The major vapor species was identified to be CsOH(g) except when greater than 3% chloride is present in the melt, then the major vapor species is CsCl(g). The decrease in volatility of cesium as a function of cesium concentration in Cs{sub 2}CO{sub 3{minus}}Na{sub 2}CO{sub 3} mixtures follows Raoult`s law very closely. Thus, this system exhibits close to ideal solution behavior. Addition of 22.5 wt % sodium sulfate decreases the cesium volatility by just under a factor of 2, and the addition of 10.0 wt % sodium chloride increases the cesium volatility about an order of magnitude. The addition of 2.0 wt % ash, molecular sieve, or silica show little or no effect. However, the data indicate that higher concentrations of ash will decrease the cesium volatility. For the addition of 22.5 wt % sodium sulfate the activity coefficient, {gamma}(Cs{sub 2}CO{sub 3}){sup {1/2}}, is calculated to be 0.720 {plus_minus} 0.068, and for the addition of 10.0 wt % sodium chloride, the activity coefficient, {gamma}(CsCl), is calculated to be 8.118 {plus_minus} 2.317. Assuming that Henry`s law applies, these activity coefficients are used to extrapolate the effect on cesium retention in the molten salt oxidizer of sulfate and chloride at lower cesium concentrations.

Ebbinghaus, B.B.; Krikorian, O.H.; Adamson, M.G.; Fleming, D.L.

1993-12-01T23:59:59.000Z

42

Pressure Drops Due to Silica Scaling  

DOE Green Energy (OSTI)

Experience with reinjection returns in many geothermal fields has prompted a move towards injecting waste fluids at some distance from the production field. This means that often, reinjection pipelines cover very long distances. If the waste water in the pipelines is supersaturated with respect to amorphous silica, then the deposition of silica in these pipelines is almost certain. Although the deposit may be of negligible thickness, the inner surface characteristics of the pipe will be different to those of clean mild steel. During a silica scaling experiment. geothermal brine was passed through a series of pipes of different sizes and over a period of three weeks, silica scale formed on the inner surface. The pressure drop along a distance of approximately 5m was measured by a water manometer in all test pipe sections. Significant pressure drop was observed during this time and can be correlated with the increase in the friction factor of the pipe walls due to silica scaling.

Brown, K.L.; Freeston, D.H.; Dimas, Z.O.; Slatter, A.

1995-01-01T23:59:59.000Z

43

It's Elemental - The Element Sodium  

NLE Websites -- All DOE Office Websites (Extended Search)

Neon Neon Previous Element (Neon) The Periodic Table of Elements Next Element (Magnesium) Magnesium The Element Sodium [Click for Isotope Data] 11 Na Sodium 22.98976928 Atomic Number: 11 Atomic Weight: 22.98976928 Melting Point: 370.95 K (97.80°C or 208.04°F) Boiling Point: 1156 K (883°C or 1621°F) Density: 0.97 grams per cubic centimeter Phase at Room Temperature: Solid Element Classification: Metal Period Number: 3 Group Number: 1 Group Name: Alkali Metal What's in a name? From the English word soda and from the Medieval Latin word sodanum, which means "headache remedy." Sodium's chemical symbol comes from the Latin word for sodium carbonate, natrium. Say what? Sodium is pronounced as SO-dee-em. History and Uses: Although sodium is the sixth most abundant element on earth and comprises

44

Coal desulfurization with sodium hypochlorite.  

E-Print Network (OSTI)

??Wet desulfurization of Pittsburgh No. 8 coal and Illinois No. 6 coal were conducted with sodium hypochlorite in the laboratory. Pittsburgh No. 8 coal was… (more)

Li, Wei, M.S.

2004-01-01T23:59:59.000Z

45

LIGHT SCATTERING STUDIES OF SILICA AEROGELS  

E-Print Network (OSTI)

S.S. , "Coherent Expanded Aerogels," J. of Phys. Chern.Production of Silica Aerogel," Physica Scripta 23, Nicolaon,S.J. , "Preparation des aerogels de silice a partir

Hunt, A.J.

2010-01-01T23:59:59.000Z

46

Silica-coated liposomes for insulin delivery  

Science Conference Proceedings (OSTI)

Liposomes coated with silica were explored as protein delivery vehicles for their enhanced stability and improved encapsulation efficiency. Insulin was encapsulated within the fluidic phosphatidylcholine lipid vesicles by thin film hydration at pH 2.5, ...

Neelam Dwivedi; M. A. Arunagirinathan; Somesh Sharma; Jayesh Bellare

2010-01-01T23:59:59.000Z

47

Thermophysical Properties of Sodium Nitrate and Sodium Chloride  

Office of Scientific and Technical Information (OSTI)

Thermophysical Properties of Sodium Nitrate and Sodium Chloride Thermophysical Properties of Sodium Nitrate and Sodium Chloride Solutions and Their Effects on Fluid Flow in Unsaturated Media Tianfu Xu and Karsten Pruess Earth Sciences Division, Lawrence Berkeley National Laboratory, University of California, Berkeley, CA 94720 ABSTRACT. Understanding movement of saline sodium nitrate (NaNO 3 ) waste solutions is important for assessing the contaminant migration near leaking waste storage tanks in the unsaturated zone at the Hanford site (Washington, USA). The purpose of this study is to contribute a basic understanding of effects of the thermophysical behavior of NaNO 3 solutions on fluid flow in unsaturated media. We first present mathematical expressions for the dependence of density, viscosity, solubility and vapor pressure of

48

Chemistry of silica in Cerro Prieto brines  

DOE Green Energy (OSTI)

The precipitation of amorphous silica from synthetic geothermal brines which resemble the flashed brine at Cerro Prieto has been studied. It was found that part of the dissolved silica quickly polymerizes to form suspended colloidal silica. The colloidal silica flocculates and settles slowly at unmodified brine pH values near 7.35. Raising the pH of the brine to about 7.8 by adding base and stirring for a few minutes causes rapid and complete flocculation and settling. These results have been confirmed in the field using actual Cerro Prieto brine. Both in the laboratory and in the field quaternary amines were found to be effective with some brine compositions but not with others. Polyacrylamides do not work at all. These results suggest the following simple preinjection brine treatment process: age the brine for 10 to 20 minutes in a covered holding tank, add 20 to 30 ppM lime (CaO), stir for 5 minutes, and separate the flocculated silica from the brine using a conventional clarifier. The brine coming out of such a process will be almost completely free of suspended solids. The pilot plant tests needed to reduce this conceptual process to practice are discussed. The rate of deposition of silica scale from synthetic brines was separately studied. It was found that a modest decrease in pH could significantly reduce the scaling rate at a reasonable cost. The equilibrium chemistry of Cerro Prieto brine was studied theoretically. These calculations indicate that increasing the brine pH to remove silica might cause some precipitation of carbonate minerals, but also that this problem could easily be eliminated at a reasonable cost if it did arise.

Weres, O.; Tsao, L.; Iglesias, E.

1980-04-01T23:59:59.000Z

49

Chemistry of Silica in Cerro Prieto Brines  

DOE Green Energy (OSTI)

The precipitation of amorphous silica from synthetic geothermal, brines which resemble the flashed brine at Cerro Prieto has been studied. It was found that part of the dissolved silica quickly polymerizes to form suspended colloidal silica. The colloidal silica flocculates and settles slowly at unmodified brine pH values near 7.35. Raising the pH of the brine to about 7.8 by adding base and stirring for a few minutes causes rapid and complete flocculation and settling. these results have been confirmed in the field using actual Cerro Prieto brine. Both in the laboratory and in the field quaternary amines were found to be effective with some brine compositions but not with others. Polyacrylamides do not work at all. These results suggest the following simple preinjection brine treatment process: age the brine for 10-20 minutes in a covered holding tank, add 20-30 ppm lime (CaO), stir for 5 minutes, and separate the flocculated silica from the brine using a conventional clarifier. The brine coming out of such a process will be almost completely free of suspended solids. The pilot plant tests needed to reduce this conceptual process to practice are discussed. The rate of deposition of silica scale from synthetic brines was separately studied. It was found that a modest decrease in pH could significantly reduce the scaling rate at a reasonable cost. The equilibrium chemistry of Cerro Prieto brine was studied theoretically. These calculations indicate that increasing the brine pH to remove silica might cause some precipitation of carbonate minerals, but also that this problem could easily be eliminated at a reasonable cost if it did arise.

Weres, Oleh; Iglesias, Eduardo; Tsao, Leon

1980-04-01T23:59:59.000Z

50

Simulation of sodium boiling experiments with THERMIT sodium version  

E-Print Network (OSTI)

Natural and forced convection experiments(SBTF and French) are simulated with the sodium version of the thermal-hydraulic computer code THERMIT. Simulation is done for the test secti- -on with the pressure-velocity boundary ...

Huh, Kang Yul

1982-01-01T23:59:59.000Z

51

Water simulation of sodium reactors  

Science Conference Proceedings (OSTI)

The thermal hydraulic simulation of a large sodium reactor by a scaled water model is examined. The Richardson Number, friction coefficient and the Peclet Number can be closely matched with the water system at full power and the similarity is retained for buoyancy driven flows. The simulation of thermal-hydraulic conditions in a reactor vessel provided by a scaled water experiment is better than that by a scaled sodium test. Results from a correctly scaled water test can be tentatively extrapolated to a full size sodium system.

Grewal, S.S.; Gluekler, E.L.

1981-06-28T23:59:59.000Z

52

Low-Pressure Sodium Lighting  

Energy.gov (U.S. Department of Energy (DOE))

Low-pressure sodium lighting provides more energy-efficient outdoor lighting than high-intensity discharge lighting, but it has very poor color rendition. Typical applications include highway and...

53

High resolution patterning of silica aerogels  

SciTech Connect

Three-dimensional metallic structures are fabricated with high spatial resolution in silica aerogels. In our method, silica hydrogels are prepared with a standard base-catalyzed route, and exchanged with an aqueous solution typically containing Ag{sup +} ions (1 M) and 2-propanol (0.2 M). The metal ions are reduced photolytically with a table-top ultraviolet lamp, or radiolytically, with a focused X-ray beam. We fabricated dots and lines as small as 30 x 70 {micro}m, protruding for several mm into the bulk of the materials. The hydrogels are eventually supercritically dried to yield aerogels, without any measurable change in the shape and spatial resolution of the lithographed structures. Transmission electron microscopy shows that illuminated regions are composed by Ag clusters with a size of several {micro}m, separated by thin layers of silica.

Bertino, M.F.; Hund, J.F.; Sosa, J.; Zhang, G.; Sotiriou-Leventis, C.; Leventis, N.; Tokuhiro, A.T.; Terry, J. (UMR-MUST); (IIT)

2008-10-30T23:59:59.000Z

54

Measurement of muonium emission from silica aerogel  

E-Print Network (OSTI)

Emission of muonium ($\\mu^{+}e^{-}$) atoms from silica aerogel into vacuum was observed. Characteristics of muonium emission were established from silica aerogel samples with densities in the range from 29 mg cm$^{-3}$ to 178 mg cm$^{-3}$. Spectra of muonium decay times correlated with distances from the aerogel surfaces, which are sensitive to the speed distributions, follow general features expected from a diffusion process, while small deviations from a simple room-temperature thermal diffusion model are identified. The parameters of the diffusion process are deduced from the observed yields.

Bakule, P; Contreras, D; Esashi, M; Fujiwara, Y; Fukao, Y; Hirota, S; Iinuma, H; Ishida, K; Iwasaki, M; Kakurai, T; Kanda, S; Kawai, H; Kawamura, N; Marshall, G M; Masuda, H; Matsuda, Y; Mibe, T; Miyake, Y; Okada, S; Olchanski, K; Olin, A; Onishi, H; Saito, N; Shimomura, K; Strasser, P; Tabata, M; Tomono, D; Ueno, K; Yokoyama, K; Yoshida, S

2013-01-01T23:59:59.000Z

55

Measurement of muonium emission from silica aerogel  

E-Print Network (OSTI)

Emission of muonium ($\\mu^{+}e^{-}$) atoms from silica aerogel into vacuum was observed. Characteristics of muonium emission were established from silica aerogel samples with densities in the range from 29 mg cm$^{-3}$ to 178 mg cm$^{-3}$. Spectra of muonium decay times correlated with distances from the aerogel surfaces, which are sensitive to the speed distributions, follow general features expected from a diffusion process, while small deviations from a simple room-temperature thermal diffusion model are identified. The parameters of the diffusion process are deduced from the observed yields.

P. Bakule; G. A. Beer; D. Contreras; M. Esashi; Y. Fujiwara; Y. Fukao; S. Hirota; H. Iinuma; K. Ishida; M. Iwasaki; T. Kakurai; S. Kanda; H. Kawai; N. Kawamura; G. M. Marshall; H. Masuda; Y. Matsuda; T. Mibe; Y. Miyake; S. Okada; K. Olchanski; A. Olin; H. Onishi; N. Saito; K. Shimomura; P. Strasser; M. Tabata; D. Tomono; K. Ueno; K. Yokoyama; S. Yoshida

2013-06-17T23:59:59.000Z

56

Safety Bulletin 2007-08 Silica Dust Exposure  

NLE Websites -- All DOE Office Websites (Extended Search)

minerals. Potential work exposure to airborne crystalline silica includes abrasive blasting, sandblasting, rock cutting, chipping, drilling, grinding, jack hammering, concrete...

57

A threshold Cherenkov detector for K separation using silica aerogel  

E-Print Network (OSTI)

A threshold Cherenkov detector for Kþ =pþ separation using silica aerogel R. Siudak a,b , A August 2008 Keywords: Threshold Cherenkov detector Silica aerogel Reaction pp ! Kþ ðLp� Kþ =pþ separation in the focal plane of a magnetic spectrograph. Silica aerogel with refractive index of n ¼ 1:05 is applied

Magiera, Andrzej

58

Characterization of vanadium/silica and copper/silica aerogel catalysts  

DOE Green Energy (OSTI)

Vanadium/silica and copper/silica aerogels have been prepared using the sol-gel method followed by CO{sub 2} exchange and supercritical extraction. Structural properties of samples supercritically dried, oxidized and used in reactions studies conducted with a feed representing the average composition of automobile exhaust from a lean burn engine were investigated using laser Raman spectroscopy and temperature-programmed reduction. No evidence of crystalline V{sub 2}O{sub 5} was found for the vanadium/silica aerogel, freshly extracted, oxidized or following exposure to reaction conditions using these techniques. However, results obtained for the copper/silica sample indicate that changes in the structure of the copper species had occurred as the sample was oxidized and exposed to reaction conditions.

Owens, L.; Tillotson, T.M.; Hair, L.M. [Lawrence Livermore National Lab., CA (United States). Chemistry and Materials Science Dept.

1995-09-01T23:59:59.000Z

59

Molecular sieving silica membrane fabrication process  

DOE Patents (OSTI)

A process is described for producing a molecular sieve silica membrane comprising depositing a hybrid organic-inorganic polymer comprising at least one organic constituent and at least one inorganic constituent on a porous substrate material and removing at least a portion of the at least one organic constituent of the hybrid organic-inorganic polymer, forming a porous film. 11 figs.

Raman, N.K.; Brinker, C.J.

1999-08-10T23:59:59.000Z

60

Moisture transport in silica gel particle beds  

DOE Green Energy (OSTI)

A theoretical and experimental study of the performance of silica gel packed particle beds is described. A bench-scale test rig was used to obtain data for parameter values pertinent to solar air-conditioning applications. Both adsorption and desorption experiments were performed for Regular Density (RD) silica gel for a wide range of particle size. Adsorption data were also obtained for Intermediate Density (ID) gel. A model of heat and mass transfer in the bed was developed with special attention paid to the modeling of solid side resistance. For this latter purpose an extensive review of the available literature on moisture adsorption and moisture transport in silica gel was made. Both Knudsen and surface diffusion are found to be important mechanisms of moisture transport in Intermediate Density gels while surface diffusion is dominant in Regular Density gels. A general equation for moisture transport in a spherical silica gel particle was developed and was incorporated into the model equations governing heat and mass transfer between the gel particles and air flowing through a packed particle bed. A computer code DESICCANT was written to solve the coupled set of partial differential equations using a finite difference numerical method. The agreement between theory and experiment for adsorption on RD gel is satisfactory, and is somewhat better for the outlet water vapor concentration than for the outlet air temperature. The agreement for desorption from RD gel and adsorption to ID gel is satisfactory, but not as good as for adsorption on RD gel.

Pesaran, A.A.

1983-02-01T23:59:59.000Z

Note: This page contains sample records for the topic "na-sg sodium silica" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Significant Silica Solubility in Geothermal Steam  

DOE Green Energy (OSTI)

Although it is widely believed that silica solubility in low pressure (5 to 10 bar) geothermal steam is negligible, when one takes into account steam flows exceeding 10 million tonnes a year--at Wairakei, for instance--it is found that the amount transmitted in the vapor has the potential to give significant deposits on turbine nozzles and blades. A 150 MWe power station, when based on flows from a hot water reservoir at (a) 250 C or (b) 315 C, and with separator pressures of 6 bar, is found to carry about 100 and 200 kg/year respectively in the steam phase. In the case of a similar sized station exploiting a dry steam reservoir such as The Geysers, equivalent silica flows are obtained, dissolved in steam and carried as dust--the latter as solid particles precipitating from the vapor en route from source to turbine, and not preexisting in the formations as is commonly considered. Choking or coating of subterranean rock near such dry steam wells due to exsolving silica, may be the principal cause of declining steam discharge under production. Silica from completely dry or superheated steam can also seal the cap and sides of steam reservoirs when expanding below the criticus temperature (236 C) in a way previously thought possible only by hot water or wet steam.

James, Russell

1986-01-21T23:59:59.000Z

62

Molecular sieving silica membrane fabrication process  

DOE Patents (OSTI)

A process for producing a molecular sieve silica membrane comprising depositing a hybrid organic-inorganic polymer comprising at least one organic constituent and at least one inorganic constituent on a porous substrate material and removing at least a portion of the at least one organic constituent of the hybrid organic-inorganic polymer, forming a porous film.

Raman, Narayan K. (400 Maple St. SE., Apartment 112, Albuquerque, NM 87106); Brinker, Charles Jeffrey (14 Eagle Nest Dr., NE., Albuquerque, NM 87122)

1998-01-01T23:59:59.000Z

63

Molecular sieving silica membrane fabrication process  

DOE Patents (OSTI)

A process for producing a molecular sieve silica membrane comprising depositing a hybrid organic-inorganic polymer comprising at least one organic constituent and at least one inorganic constituent on a porous substrate material and removing at least a portion of the at least one organic constituent of the hybrid organic-inorganic polymer, forming a porous film.

Raman, Narayan K. (Monroeville, PA); Brinker, Charles Jeffrey (Albuquerque, NM)

1999-01-01T23:59:59.000Z

64

Conversion of geothermal waste to commercial products including silica  

DOE Patents (OSTI)

A process for the treatment of geothermal residue includes contacting the pigmented amorphous silica-containing component with a depigmenting reagent one or more times to depigment the silica and produce a mixture containing depigmented amorphous silica and depigmenting reagent containing pigment material; separating the depigmented amorphous silica and from the depigmenting reagent to yield depigmented amorphous silica. Before or after the depigmenting contacting, the geothermal residue or depigmented silica can be treated with a metal solubilizing agent to produce another mixture containing pigmented or unpigmented amorphous silica-containing component and a solubilized metal-containing component; separating these components from each other to produce an amorphous silica product substantially devoid of metals and at least partially devoid of pigment. The amorphous silica product can be neutralized and thereafter dried at a temperature from about 25.degree. C. to 300.degree. C. The morphology of the silica product can be varied through the process conditions including sequence contacting steps, pH of depigmenting reagent, neutralization and drying conditions to tailor the amorphous silica for commercial use in products including filler for paint, paper, rubber and polymers, and chromatographic material.

Premuzic, Eugene T. (East Moriches, NY); Lin, Mow S. (Rocky Point, NY)

2003-01-01T23:59:59.000Z

65

Vacuum pyrolysis of sodium stearate  

DOE Green Energy (OSTI)

Vacuum pyrolysis of sodium stearate was studied to provide useful information for Green River oil shale pyrolysis. Sodium stearate is a typical compound of carboxylic acid salts amounting to 3.6% of total organic materials in the oil shale by methanol extraction. Sodium stearate contained in a stainless steel miniature reactor was heated at 450/sup 0/C in a fluidized sand bath. Pyrolysis times ranged from 15 to 120 minutes. The amounts of gas and liquid products were measured and composition determined by gas chromatography. Ethane, methane, propylene plus propane, hydrogen, carbon dioxide, and carbon monoxide are the major gaseous products, in order of decreasing concentration. The predominant liquid product is a C/sub 17/ alkene with C/sub 12/-C/sub 21/ alkene/alkane pairs present. The first order decomposition rate constant for sodium stearate at 450/sup 0/C was calculated to be 6.4 x 10/sup -3/ min./sup -1/. 18 refs., 7 figs.

Chong, S.L.

1985-09-01T23:59:59.000Z

66

Seal for sodium sulfur battery  

SciTech Connect

This invention is directed to a seal for a sodium sulfur battery in which the sealing is accomplished by a radial compression seal made on a ceramic component of the battery which separates an anode compartment from a cathode compartment of the battery.

Topouzian, Armenag (Birmingham, MI); Minck, Robert W. (Lathrup Village, MI); Williams, William J. (Northville, MI)

1980-01-01T23:59:59.000Z

67

Volume efficient sodium sulfur battery  

SciTech Connect

In accordance with the teachings of this specification, a sodium sulfur battery is formed as follows. A plurality of box shaped sulfur electrodes are provided, the outer surfaces of which are defined by an electrolyte material. Each of the electrodes have length and width dimensions substantially greater than the thicknesses thereof as well as upwardly facing surface and a downwardly facing surface. An electrode structure is contained in each of the sulfur electrodes. A holding structure is provided for holding the plurality of sulfur electrodes in a stacked condition with the upwardly facing surface of one sulfur electrode in facing relationship to the downwardly facing surface of another sulfur electrode thereabove. A small thickness dimension separates each of the stacked electrodes thereby defining between each pair of sulfur electrodes a volume which receives the sodium reactant. A reservoir is provided for containing sodium. A manifold structure interconnects the volumes between the sulfur electrodes and the reservoir. A metering structure controls the flow of sodium between the reservoir and the manifold structure.

Mikkor, Mati (Ann Arbor, MI)

1980-01-01T23:59:59.000Z

68

Carbon nanomaterials in silica aerogel matrices  

SciTech Connect

Silica aerogels are ultra low-density, high surface area materials that are extremely good thermal insulators and have numerous technical applications. However, their mechanical properties are not ideal, as they are brittle and prone to shattering. Conversely, single-walled carbon nanotubes (SWCNTs) and graphene-based materials, such as graphene oxide, have extremely high tensile strength and possess novel electronic properties. By introducing SWCNTs or graphene-based materials into aerogel matrices, it is possible to produce composites with the desirable properties of both constituents. We have successfully dispersed SWCNTs and graphene-based materials into silica gels. Subsequent supercritical drying results in monolithic low-density composites having improved mechanical properties. These nanocomposite aerogels have great potential for use in a wide range of applications.

Hamilton, Christopher E [Los Alamos National Laboratory; Chavez, Manuel E [Los Alamos National Laboratory; Duque, Juan G [Los Alamos National Laboratory; Gupta, Gautam [Los Alamos National Laboratory; Doorn, Stephen K [Los Alamos National Laboratory; Dattelbaum, Andrew M [Los Alamos National Laboratory; Obrey, Kimberly A D [Los Alamos National Laboratory

2010-01-01T23:59:59.000Z

69

(129)Xe NMR of Mesoporous Silicas  

DOE Green Energy (OSTI)

The porosities of three mesoporous silica materials were characterized with {sup 129}Xe NMR spectroscopy. The materials were synthesized by a sol-gel process with r = 0, 25, and 70% methanol by weight in an aqueous cetyltrimethylammonium bromide solution. Temperature dependent chemical shifts and spin lattice relaxation times reveal that xenon does not penetrate the pores of the largely disordered (r= 70%) silica. For both r = 0 and 25%, temperature dependent resonances corresponding to physisorbed xenon were observed. An additional resonance for the r = 25% sample was attributed to xenon between the disordered cylindrical pores. 2D NMR exchange experiments corroborate the spin lattice relaxation data which show that xenon is in rapid exchange between the adsorbed and the gas phase.

Anderson, M.T.; Asink, R.A.; Kneller, J.M.; Pietrass, T.

1999-04-23T23:59:59.000Z

70

Interaction of silica nano-particles with a flat silica surface through neutron reflectometry  

SciTech Connect

Neutron reflectometry (NR) was employed to study the interaction of nanosized silica particles with a flat silica surface in aqueous solutions. Unlike other experimental tools that are used to study surface interactions, NR can provide information on the particle density profile in the solution near the interface. Two types of silica particles (25 and 100 nm) were suspended in aqueous solutions of varying ionic strength. Theoretical calculations of the surface interaction potential between a particle and a flat silica surface using the Derjaguin-Landau-Verwey-Overbeek (DLVO) theory were compared to the experimental data. The theory predicts that the potential energy is highly dependent on the ionic strength. In high ionic strength solutions, NR reveals a high concentration of particles near the flat silica surface. Under the same conditions, theoretical calculations show an attractive force between a particle and a flat surface. For low ionic strength solutions, the particle concentration near the surface obtained from NR is the same as the bulk concentration, while depletion of particles near the surface is expected because of the repulsion predicted by the DLVO theory.

Chung, Eunhyea [Georgia Institute of Technology; Yiacoumi, Sotira [Georgia Institute of Technology; Halbert, Candice E [ORNL; Ankner, John Francis [ORNL; Wang, Wei [ORNL; Tsouris, Costas [ORNL

2012-01-01T23:59:59.000Z

71

Recent progress in silica aerogel Cherenkov radiator  

E-Print Network (OSTI)

In this paper, we present recent progress in the development of hydrophobic silica aerogel as a Cherenkov radiator. In addition to the conventional method, the recently developed pin-drying method for producing high-refractive-index aerogels with high transparency was studied in detail. Optical qualities and large tile handling for crack-free aerogels were investigated. Sufficient photons were detected from high-performance aerogels in a beam test.

Tabata, Makoto; Kawai, Hideyuki; Kubo, Masato; Sato, Takeshi

2012-01-01T23:59:59.000Z

72

Energy Basics: Low-Pressure Sodium Lighting  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Low-Pressure Sodium Lighting Low-pressure sodium lighting provides more energy-efficient outdoor lighting than high-intensity discharge lighting, but it has very poor color...

73

Protective tubes for sodium heated water tubes  

DOE Patents (OSTI)

A heat exchanger in which water tubes are heated by liquid sodium which minimizes the results of accidental contact between the water and the sodium caused by failure of one or more of the water tubes. A cylindrical protective tube envelopes each water tube and the sodium flows axially in the annular spaces between the protective tubes and the water tubes.

Essebaggers, Jan (39 Honeyman Dr., Succasunna, NJ 07876)

1979-01-01T23:59:59.000Z

74

Chloride substitution in sodium borohydride  

Science Conference Proceedings (OSTI)

The dissolution of sodium chloride and sodium borohydride into each other resulting in formation of solid solutions of composition Na(BH{sub 4}){sub 1-x}Cl{sub x} is studied. The dissolution reaction is facilitated by two methods: ball milling or combination of ball milling and annealing at 300 deg. C for three days of NaBH{sub 4}-NaCl samples in molar ratios of 0.5:0.5 and 0.75:0.25. The degree of dissolution is studied by Rietveld refinement of synchrotron radiation powder X-ray diffraction (SR-PXD) data. The results show that dissolution of 10 mol% NaCl into NaBH{sub 4}, forming Na(BH{sub 4}){sub 0.9}Cl{sub 0.1}, takes place during ball milling. A higher degree of dissolution of NaCl in NaBH{sub 4} is obtained by annealing resulting in solid solutions containing up to 57 mol% NaCl, i.e. Na(BH{sub 4}){sub 0.43}Cl{sub 0.57}. In addition, annealing results in dissolution of 10-20 mol% NaBH{sub 4} into NaCl. The mechanism of the dissolution during annealing and the decomposition pathway of the solid solutions are studied by in situ SR-PXD. Furthermore, the stability upon hydrogen release and uptake were studied by Sieverts measurements. - Graphical Abstract: Dissolution of sodium chloride and sodium borohydride into each other resulting in formation of solid solutions of composition Na(BH{sub 4}){sub 1-x}Cl{sub x} is studied. Dissolution is facilitated by two methods: ball milling or annealing at 300 deg. C for three days of NaBH{sub 4}-NaCl samples. Sample compositions and dissolution mechanism are studied by Rietveld refinement of synchrotron radiation powder X-ray diffraction data. Highlights: > Studies of dissolution of sodium chloride and sodium borohydride into each other. > Solid state diffusion facilitated by mechanical and thermal treatments. > Dissolution is more efficiently induced by heating than by mechanical treatment. > Mechanism for dissolution studied by Rietveld refinement of in situ SR-PXD data.

Ravnsbaek, Dorthe B.; Rude, Line H. [Center for Materials Crystallography (CMC), Interdisciplinary Nanoscience Center (iNANO), Department of Chemistry, Aarhus University, Langelandsgade 140, DK-8000 Arhus C (Denmark); Jensen, Torben R., E-mail: trj@chem.au.dk [Center for Materials Crystallography (CMC), Interdisciplinary Nanoscience Center (iNANO), Department of Chemistry, Aarhus University, Langelandsgade 140, DK-8000 Arhus C (Denmark)

2011-07-15T23:59:59.000Z

75

Thermal Conductivity of Cubic and Hexagonal Mesoporous Silica Thin Films  

E-Print Network (OSTI)

K.L. Fang, “Anisotropic thermal conductivity of nanoporousmesoporous silica as a thermal isolation layer”, Ceramicsand V. Wittwer, “Some thermal and optical properties of a

Coquil, Thomas; Richman, Eric K.; Hutchinson, Neal J.; Tolbert, S H; Pilon, Laurent

2009-01-01T23:59:59.000Z

76

Dynamic performance characterization of bound, porous silica gel desiccant  

DOE Green Energy (OSTI)

Drying of air with silica gel is a well established procedure. However, for the specific use of silica gel in a novel desiccant air conditioning system, which continually cools the silica gel and utilizes solar energy for silica gel regeneration, conventional packed bed devices are not suitable. For this system to operate effectively the silica gel must not rise in its temperature or its capacity will be greatly diminished. Dynamic dehumidificatuion performance was investigted for a silica gel desiccant fabricated in bound, porous paper-like sheets. Sheets of various thickness (0.7 to 3 mm) were fabricated and tested under several dynamic flow conditions in a flat rectangular channel apparatus. During each experiment conditions of inlet moisture, air flowrate, and sheet temperature were maintained constant. Comparisons were also made with conventional silica gel pellets and with other forms of bound silica gel. The sheets show superior utilization of silica gel in short times (30 minutes or less). Tests were also made to examine the sheet structure in order to explore the effect of temperature on the porous structure, and to obtain pore size distributions.

Onischak, M.; Gidaspow, D.; Perkari, S.; Sasaki, T.

1979-10-01T23:59:59.000Z

77

Mesoporous Silica-Supported Rhodium Nanocatalysts for Selective...  

NLE Websites -- All DOE Office Websites (Extended Search)

Mesoporous Silica-Supported Rhodium Nanocatalysts for Selective Production of Ethanol From Syngas and Conversion of Ethanol to Hydrogen Description Coal will likely play a major...

78

Heat Transfer through Materials: Application to Silica Aerogels...  

NLE Websites -- All DOE Office Websites (Extended Search)

Heat Transfer through Materials: Application to Silica Aerogels and Building Envelopes Speaker(s): Brangre Lartigue Date: December 19, 2005 - 12:00pm Location: Bldg. 90 After...

79

Feasibility of using silica aerogel as insulation for buildings.  

E-Print Network (OSTI)

?? For recent years, silica aerogel has attracted great attention and been extensively used in different technical fields owning to its remarkable properties in optics,… (more)

Huang, Lang

2012-01-01T23:59:59.000Z

80

Fire suppressing apparatus. [sodium fires  

DOE Patents (OSTI)

Apparatus for smothering a liquid sodium fire comprises a pan, a perforated cover on the pan, and tubed depending from the cover and providing communication between the interior of the pan and the ambient atmosphere through the perforations in the cover. Liquid caught in the pan rises above the lower ends of the tubes and thus serves as a barrier which limits the amount of air entering the pan.

Buttrey, K.E.

1980-12-19T23:59:59.000Z

Note: This page contains sample records for the topic "na-sg sodium silica" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Dual-Layer Asymmetric Microporous Silica Membranes  

DOE Green Energy (OSTI)

We report a novel sol-gel dip-coating process to form dual-layer microporous silica membranes with improved membrane performance and reproducibility. First, we deposit a surfactant-templated silica (STS) intermediate layer on top of a commercial {gamma}-alumina support both to improve its ''surface finish'' and to prevent a subsequently deposited microporous overlayer from penetrating into the support. Second, membranes are processed under clean room conditions to avoid dust contamination and, third, membranes are vacuum-calcined to promote further pore shrinkage and impart surface hydrophobicity. The resulting asymmetric membrane exhibits a gradual change in pore diameter from 50{angstrom} ({gamma}-alumina support layer) to 10-12{angstrom} (STS intermediate layer), and then to 3-4{angstrom} (30nm thick, ultramicroporous silica top-layer). Compared to a single-layer process using only the microporous overlayer, the dual-layer process improves both flux and selectivity. For the industrially important problem of natural gas purification, the combined CO{sub 2} flux [(3{approx} 0.5) x 10{sup {minus}4} cm{sup 3}(STP)/(s{center_dot}cm{sup 2}{center_dot}cm-Hg)] and CO{sub 2}/CH{sub 4} separation factors [200{approx}600] are superior to all previously reported values for separation of a 50/50 (v/v) CO{sub 2}/CH{sub 4} gas mixture. In addition, the membrane selectively separated hydrogen from a simulated reformate from partial oxidation of methanol as evidenced by a high concentration of hydrogen recovery.

TSAI,CHUNG-YI; TAM,SIU-YUE; LU,YUNFENG; BRINKER,C. JEFFREY

1999-11-19T23:59:59.000Z

82

Hydrophobic silica aerogel production at KEK  

E-Print Network (OSTI)

We present herein a characterization of a standard method used at the High Energy Accelerator Research Organization (KEK) to produce hydrophobic silica aerogels and expand this method to obtain a wide range of refractive index (n = 1.006-1.14). We describe in detail the entire production process and explain the methods used to measure the characteristic parameters of aerogels, namely the refractive index, transmittance, and density. We use a small-angle X-ray scattering (SAXS) technique to relate the transparency to the fine structure of aerogels.

Tabata, Makoto; Kawai, Hideyuki; Sumiyoshi, Takayuki; Yokogawa, Hiroshi

2011-01-01T23:59:59.000Z

83

Hydrophobic silica aerogel production at KEK  

E-Print Network (OSTI)

We present herein a characterization of a standard method used at the High Energy Accelerator Research Organization (KEK) to produce hydrophobic silica aerogels and expand this method to obtain a wide range of refractive index (n = 1.006-1.14). We describe in detail the entire production process and explain the methods used to measure the characteristic parameters of aerogels, namely the refractive index, transmittance, and density. We use a small-angle X-ray scattering (SAXS) technique to relate the transparency to the fine structure of aerogels.

Makoto Tabata; Ichiro Adachi; Hideyuki Kawai; Takayuki Sumiyoshi; Hiroshi Yokogawa

2011-12-14T23:59:59.000Z

84

Silica scaling in simulated geothermal brines  

DOE Green Energy (OSTI)

A 6.3 1/sec (100 GPM) titanium corrosion test loop was modified to provide a dynamic facility for studying the formation of silica deposits, their properties and fates, as a function of brine composition, temperature, and flow conditions. Scale formation was studied in a segmented heat exchanger operating under realistic conditions; the segmented design permitted examination of scale formations in five temperature regimes. The program was terminated after minimal exploratory operation because of reduced sponsor perceptions of the need for concern with scaling problems. The runs which were completed dealt cursorily with brine concentration and pH effects. Results are presented.

Bohlmann, E.G.; Shor, A.J.; Berlinski, P.; Mesmer, R.E.

1981-04-01T23:59:59.000Z

85

Fibrous composites comprising carbon nanotubes and silica  

DOE Patents (OSTI)

Fibrous composite comprising a plurality of carbon nanotubes; and a silica-containing moiety having one of the structures: (SiO).sub.3Si--(CH.sub.2).sub.n--NR.sub.1R.sub.2) or (SiO).sub.3Si--(CH.sub.2).sub.n--NCO; where n is from 1 to 6, and R.sub.1 and R.sub.2 are each independently H, CH.sub.3, or C.sub.2H.sub.5.

Peng, Huisheng (Shanghai, CN); Zhu, Yuntian Theodore (Cary, NC); Peterson, Dean E. (Los Alamos, NM); Jia, Quanxi (Los Alamos, NM)

2011-10-11T23:59:59.000Z

86

Silica-Coated Titania and Zirconia Colloids for Subsurface Transport  

E-Print Network (OSTI)

, Environmental Engineering Program, Yale University, New Haven, Connecticut 06520-8286, and Department of Civil transport experiments. Electrophoretic mobility measurements showed that coating with silica imparted electrophoretic mobility and size (by dynamic light scattering) over a 90-day period showed that the silica

Elimelech, Menachem

87

Functionalization of silica nanoparticles for polypropylene nanocomposite applications  

Science Conference Proceedings (OSTI)

Synthetic silica nanospheres of 20 and 100nm diameter were produced via the sol-gel method to be used as filler in polypropylene (PP) composites. Modification of the silica surface was further performed by reaction with organic chlorosilanes in order ...

Diego Bracho, Vivianne N. Dougnac, Humberto Palza, Raúl Quijada

2012-01-01T23:59:59.000Z

88

Community Geothermal Technology Program: Silica bronze project. Final report  

DOE Green Energy (OSTI)

Objective was to incorporate waste silica from the HGP-A geothermal well in Pohoiki with other refractory materials for investment casting of bronze sculpture. The best composition for casting is about 50% silica, 25% red cinders, and 25% brick dust; remaining ingredient is a binder, such as plaster and water.

Bianchini, H.

1989-10-01T23:59:59.000Z

89

Simulations Reveal That Earth's Silica Is Predominantly Superficial - NERSC  

NLE Websites -- All DOE Office Websites (Extended Search)

Reveal Reveal Earth's Silica Is Predominantly Superficial Simulations Reveal Earth's Silica Is Predominantly Superficial May 24, 2010 Silica is one of the most common minerals on Earth. Not only does it make up two-thirds of our planet's crust, it is also used to create a variety of materials from glass to ceramics, computer chips and fiber optic cables. Yet new quantum mechanics results generated by a team of physicists from Ohio State University (OSU) show that this mineral only populates our planet superficially-in other words, silica is relatively uncommon deep within the Earth. Cross-section of the Earth Using several of the largest supercomputers in the nation, including the National Energy Research Scientific Computing Center's (NERSC) Cray XT4 "Franklin" system, the team simulated the behavior of silica in

90

Sodium technology, 1972--1973  

SciTech Connect

References to 897 publications on sodium and NaK technology cited in Nuclear Science Abstracts Volume 26 (1972) through Volume 27 (1973 through June) are contained in this bibliography. Keyword indexing is displayed under each citation to provide information on the contents of the document. References are arranged in order by the original NSA abstract number which approximately places them in chronological order. Sequence numbers appear beside each reference, and the personal author index refers to these sequence numbers. The subject index refers to the original abstract numbers. (auth)

1974-02-01T23:59:59.000Z

91

Batteries with Orthorhombic Sodium Manganese Oxide Cathodes  

Berkeley National Laboratory researchers have discovered a low-cost, low-toxicity manganese oxide for rechargeable lithium and sodium batteries.

92

Electrolytic process to produce sodium hypochlorite using sodium ion conductive ceramic membranes  

SciTech Connect

An electrochemical process for the production of sodium hypochlorite is disclosed. The process may potentially be used to produce sodium hypochlorite from seawater or low purity un-softened or NaCl-based salt solutions. The process utilizes a sodium ion conductive ceramic membrane, such as membranes based on NASICON-type materials, in an electrolytic cell. In the process, water is reduced at a cathode to form hydroxyl ions and hydrogen gas. Chloride ions from a sodium chloride solution are oxidized in the anolyte compartment to produce chlorine gas which reacts with water to produce hypochlorous and hydrochloric acid. Sodium ions are transported from the anolyte compartment to the catholyte compartment across the sodium ion conductive ceramic membrane. Sodium hydroxide is transported from the catholyte compartment to the anolyte compartment to produce sodium hypochlorite within the anolyte compartment.

Balagopal, Shekar; Malhotra, Vinod; Pendleton, Justin; Reid, Kathy Jo

2012-09-18T23:59:59.000Z

93

Laser Damage Precursors in Fused Silica  

Science Conference Proceedings (OSTI)

There is a longstanding, and largely unexplained, correlation between the laser damage susceptibility of optical components and both the surface quality of the optics, and the presence of near surface fractures in an optic. In the present work, a combination of acid leaching, acid etching, and confocal time resolved photoluminescence (CTP) microscopy has been used to study laser damage initiation at indentation sites. The combination of localized polishing and variations in indentation loads allows one to isolate and characterize the laser damage susceptibility of densified, plastically flowed and fractured fused silica. The present results suggest that: (1) laser damage initiation and growth are strongly correlated with fracture surfaces, while densified and plastically flowed material is relatively benign, and (2) fracture events result in the formation of an electronically defective rich surface layer which promotes energy transfer from the optical beam to the glass matrix.

Miller, P; Suratwala, T; Bude, J; Laurence, T A; Shen, N; Steele, W A; Feit, M; Menapace, J; Wong, L

2009-11-11T23:59:59.000Z

94

Water dynamics in controlled pore silica glasses  

DOE Green Energy (OSTI)

Water in porous silica glass is a suitable system for investigating the effect of confinement on translational diffusion. These systems are important because of their relevance in catalytic and separation processes. Two factors are to be considered in the case of confined water: (1) the effects of hydrophilic and hydrophobic surfaces on interfacial water and (2) how the dynamics of the hydrogen bond network changes due to the volume of confinement. Here quasi-elastic neutron scattering experiments at room temperature on water filled controlled pore glasses with radius of 15, 24 and 32 {angstrom}, are presented and analyzed using the random-jump diffusion model. Both the average residence time and the mean jump distance increase with decreasing pore radius.

Bordallo, H. N.; Herwig, K. W.; Dozier, W. D.; Drake, F.

1999-12-09T23:59:59.000Z

95

Ambient-pressure silica aerogel films  

SciTech Connect

Very highly porous (aerogel) silica films with refractive index in the range 1.006--1.05 (equivalent porosity 98.5--88%) were prepared by an ambient-pressure process. It was shown earlier using in situ ellipsometric imaging that the high porosity of these films was mainly attributable to the dilation or `springback` of the film during the final stage of drying. This finding was irrefutably reconfirmed by visually observing a `springback` of >500% using environmental scanning electron microscopy (ESEM). Ellipsometry and ESEM also established the near cent per cent reversibility of aerogel film deformation during solvent intake and drying. Film thickness profile measurements (near the drying line) for the aerogel, xerogel and pure solvent cases are presented from imaging ellipsometry. The thickness of these films (crack-free) were controlled in the range 0.1-3.5 {mu}m independent of refractive index.

Prakash, S.S. [New Mexico Univ., Albuquerque, NM (United States); Brinker, C.J. [New Mexico Univ., Albuquerque, NM (United States)]|[Sandia National Labs., Albuquerque, NM (United States); Hurd, A.J. [Sandia National Labs., Albuquerque, NM (United States)

1994-12-31T23:59:59.000Z

96

In-Situ Method for Treating Residual Sodium  

DOE Patents (OSTI)

A unique process for deactivating residual sodium in Liquid Metal Fast Breeder Reactor (LMFBR) systems which uses humidified (but not saturated) carbon dioxide at ambient temperature and pressure to convert residual sodium into solid sodium bicarbonate.

Sherman, Steven R.; Henslee, S. Paul

2005-07-19T23:59:59.000Z

97

Synthesis of Monolithic Iron Incorporated Silica Aerogels by Ambient ...  

Science Conference Proceedings (OSTI)

With the Fe to Si molar ratio not exceeding 0.10, the bulk density of iron incorporated silica aerogels increased to 0.55g/cm3, while the porosity reduced to 76% ...

98

Mesoporous-silica films, fibers, and powders by evaporation  

SciTech Connect

This invention pertains to surfactant-templated nanometer-scale porosity of a silica precursor solution and forming a mesoporous material by first forming the silica precursor solution into a preform having a high surface area to volume ratio, then rapid drying or evaporating a solvent from the silica precursor solution. The mesoporous material may be in any geometric form, but is preferably in the form of a film, fiber, powder or combinations thereof. The rapid drying or evaporation of solvent from the solution is accomplished by layer thinning, for example spin casting, liquid drawing, and liquid spraying respectively. Production of a film is by layer thinning, wherein a layer of the silica precursor solution is formed on a surface followed by removal of an amount of the silica precursor solution and leaving a geometrically thinner layer of the silica precursor solution from which the solvent quickly escapes via evaporation. Layer thinning may be by any method including but not limited to squeegeeing and/or spin casting. In powder formation by spray drying, the same conditions of fast drying exists as in spin-casting (as well as in fiber spinning) because of the high surface-area to volume ratio of the product. When a powder is produced by liquid spraying, the particles or micro-bubbles within the powder are hollow spheres with walls composed of mesoporous silica. Mesoporous fiber formation starts with a similar silica precursor solution but with an added pre-polymer making a pituitous mixture that is drawn into a thin strand from which solvent is evaporated leaving the mesoporous fiber(s).

Bruinsma, Paul J. (Kennewick, WA); Baskaran, Suresh (Kennewick, WA); Bontha, Jagannadha R. (Richland, WA); Liu, Jun (West Richland, WA)

1999-01-01T23:59:59.000Z

99

SO/sub 2/ scrubbing: more work for sodium  

SciTech Connect

The effects that dry scrubbing of flue gases with sodium sorbents could have on supplies of naturally-occurring sodium compounds such as nahcolite and trona are discussed.

Not Available

1984-07-18T23:59:59.000Z

100

Silica Extraction at the Mammoth Lakes Geothermal Site  

DOE Green Energy (OSTI)

The purpose of this project is to develop a cost-effective method to extract marketable silica (SiO{sub 2}) from fluids at the Mammoth Lakes, California geothermal power plant. Marketable silica provides an additional revenue source for the geothermal power industry and therefore lowers the costs of geothermal power production. The use of this type of ''solution mining'' to extract resources from geothermal fluids eliminates the need for acquiring these resources through energy intensive and environmentally damaging mining technologies. We have demonstrated that both precipitated and colloidal silica can be produced from the geothermal fluids at Mammoth Lakes by first concentrating the silica to over 600 ppm using reverse osmosis (RO). The RO permeate can be used in evaporative cooling at the plant; the RO concentrate is used for silica and potentially other (Li, Cs, Rb) resource extraction. Preliminary results suggest that silica recovery at Mammoth Lakes could reduce the cost of geothermal electricity production by 1.0 cents/kWh.

Bourcier, W; Ralph, W; Johnson, M; Bruton, C; Gutierrez, P

2006-06-07T23:59:59.000Z

Note: This page contains sample records for the topic "na-sg sodium silica" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Controlled drug release from bifunctionalized mesoporous silica  

Science Conference Proceedings (OSTI)

Serial of trimethylsilyl-carboxyl bifunctionalized SBA-15 (TMS/COOH/SBA-15) have been studied as carriers for controlled release of drug famotidine (Famo). To load Famo with large capacity, SBA-15 with high content of carboxyl groups was successfully synthesized by one-pot synthesis under the assistance of KCl. The mesostructure of carboxyl functionalized SBA-15 (COOH/SBA-15) could still be kept even though the content of carboxyl groups was up to 57.2%. Increasing carboxyl content could effectively enhance the loading capacity of Famo. Compared with pure SBA-15, into which Famo could be hardly adsorbed, the largest drug loading capacity of COOH/SBA-15 could achieve 396.9 mg/g. The release of Famo from mesoporous silica was studied in simulated intestine fluid (SIF, pH=7.4). For COOH/SBA-15, the release rate of Famo decreased with narrowing pore size. After grafting TMS groups on the surface of COOH/SBA-15 with hexamethyldisilazane, the release of Famo was greatly delayed with the increasing content of TMS groups. - Graphical abstract: Trimethylsilyl-carboxyl bifunctionalized SBA-15 has been studied as carrier for controlled release of drug famotidine. To load drug with large capacity, SBA-15 with high content of carboxyl groups was successfully synthesized. After grafting trimethylsilyl groups on the surface of carboxyl functionalized SBA-15, the release of Famo was greatly delayed with the increasing content of TMS groups.

Xu Wujun; Gao Qiang [State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001 (China); Graduate University of the Chinese Academy of Sciences, Beijing 100049 (China); Xu Yao [State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001 (China)], E-mail: xuyao@sxicc.ac.cn; Wu Dong; Sun Yuhan [State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001 (China); Shen Wanling [State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics, Wuhan Institute of Physics and Mathematics, Chinese Academy of Sciences, Wuhan 430071 (China); Graduate University of the Chinese Academy of Sciences, Beijing 100049 (China); Deng Feng [State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics, Wuhan Institute of Physics and Mathematics, Chinese Academy of Sciences, Wuhan 430071 (China)

2008-10-15T23:59:59.000Z

102

Silica gel sorption properties under adiabatic conditions  

DOE Green Energy (OSTI)

The SERI Sorption Test Facility was modified from isothermal operation to adiabatic operating conditions so that we could measure the adsorption/desorption characteristics of silica-gel-coated, parallel-channel geometry as a function of operating conditions and aspect ratio under adiabatic conditions. We performed single-blow experiments on two single-passage test cells with different aspect ratios, air flow rates, and inlet conditions. Both adsorption and desorption runs were performed. As the air flow rate and aspect ratio increase when other parameters are kept constant, the desiccant matrix loses its sorption capacity faster. The test cell operated near isothermal conditions rather than adiabatically because the cell walls had a large thermal mass compared with the amount of desiccant used. Since constructing single-passage test cells with small thermal masses that can be operated adiabatically at the Sorption Test Facility is difficult, further testing at this facility will be primarily for isothermal operation. The adiabatic experiments can best be done with multipassage test cells having small thermal masses relative to desiccant mass. A single-blow test facility for performing experiments with multipassage test cells was fabricated in FY 1984, and experiments were performed in an FY 1985 desiccant project.

Pesaran, A.A.; Choudhury, K.

1986-02-01T23:59:59.000Z

103

Radial power flattening in sodium fast reactors  

E-Print Network (OSTI)

In order to improve a new design for a uranium startup sodium cooled fast reactor which was proposed at MIT, this thesis evaluated radial power flattening by varying the fuel volume fraction at a fixed U-235 enrichment of ...

Krentz-Wee, Rebecca (Rebecca Elizabeth)

2012-01-01T23:59:59.000Z

104

Low-temperature Sodium-Beta Battery  

Rechargeable metallic sodium batteries have application in large-scale energy storage applications such as electric power generation and distribution, in motive applications such as electric vehicles, hybrids, and plug-in hybrids, and for aerospace ...

105

Method of preparing silicon from sodium fluosilicate  

DOE Patents (OSTI)

A process for preparing high purity silicon metal from Na.sub.2 SiF.sub.6 (sodium fluosilicate). The sodium fluosilicate is heated to decomposition temperature to form NaF, which retains most of the impurities, and gaseous SiF.sub.4. The SiF.sub.4 is then reduced by the bomb reduction method using a reductant having a low packing density.

Schmidt, Frederick A. (Ames, IA); Rehbein, David (Ames, IA); Chiotti, Premo (Ames, IA)

1984-01-01T23:59:59.000Z

106

Silica recovery and control in Hawaiian geothermal fluids  

DOE Green Energy (OSTI)

A series of experiments was performed to investigate methods of controlling silica in waste geothermal brines produced at the HGP-A Generator Facility. Laboratory testing has shown that the rate of polymerization of silica in the geothermal fluids is highly pH dependent. At brine pH values in excess of 8.5 the suspension of silica polymers flocculated and rapidly precipitated a gelatinous silica mass. Optimum flocculation and precipitation rates were achieved at pH values in the range of 10.5 to 11.5. The addition of transition metal salts to the geothermal fluids similarly increased the rate of polymerization as well as the degree of precipitation of the silica polymer from suspension. A series of experiments performed on the recovered silica solids demonstrated that methanol extraction of the water in the gels followed by critical point drying yielded surface areas in excess of 300 M{sup 2}/g and that treatment of the dried solids with 2 N HCl removed most of the adsorbed impurities in the recovered product. A series of experiments tested the response of the waste brines to mixing with steam condensate and non-condensable gases.The results demonstrated that the addition of condensate and NCG greatly increased the stability of the silica in the geothermal brines. They also indicated that the process could reduce the potential for plugging of reinjection wells receiving waste geothermal fluids from commercial geothermal facilities in Hawaii. Conceptual designs were proposed to apply the gas re-combination approach to the disposal of geothermal waste fluids having a range of chemical compositions. Finally, these designs were applied to the geothermal fluid compositions found at Cerro Prieto, Ahuachapan, and Salton Sea.

Thomas, D.M.

1992-06-01T23:59:59.000Z

107

Silica recovery and control in Hawaiian geothermal fluids. Final report  

DOE Green Energy (OSTI)

A series of experiments was performed to investigate methods of controlling silica in waste geothermal brines produced at the HGP-A Generator Facility. Laboratory testing has shown that the rate of polymerization of silica in the geothermal fluids is highly pH dependent. At brine pH values in excess of 8.5 the suspension of silica polymers flocculated and rapidly precipitated a gelatinous silica mass. Optimum flocculation and precipitation rates were achieved at pH values in the range of 10.5 to 11.5. The addition of transition metal salts to the geothermal fluids similarly increased the rate of polymerization as well as the degree of precipitation of the silica polymer from suspension. A series of experiments performed on the recovered silica solids demonstrated that methanol extraction of the water in the gels followed by critical point drying yielded surface areas in excess of 300 M{sup 2}/g and that treatment of the dried solids with 2 N HCl removed most of the adsorbed impurities in the recovered product. A series of experiments tested the response of the waste brines to mixing with steam condensate and non-condensable gases.The results demonstrated that the addition of condensate and NCG greatly increased the stability of the silica in the geothermal brines. They also indicated that the process could reduce the potential for plugging of reinjection wells receiving waste geothermal fluids from commercial geothermal facilities in Hawaii. Conceptual designs were proposed to apply the gas re-combination approach to the disposal of geothermal waste fluids having a range of chemical compositions. Finally, these designs were applied to the geothermal fluid compositions found at Cerro Prieto, Ahuachapan, and Salton Sea.

Thomas, D.M.

1992-06-01T23:59:59.000Z

108

Silica-polystyrene nanocomposite particles synthesized by nitroxide-mediated polymerization and their encapsulation through miniemulsion polymerization  

Science Conference Proceedings (OSTI)

Polystyrene (PS) chains with molecular weights comprised between 8000 and 64000 g?mol-1and narrow polydispersities were grown from the surface of silica nanoparticles (Aerosil A200 fumed silica and Stöber silica, resp.) through nitroxide-mediated ...

Bérangère Bailly; Anne-Carole Donnenwirth; Christèle Bartholome; Emmanuel Beyou; Elodie Bourgeat-Lami

2006-01-01T23:59:59.000Z

109

Molecular oxygen sensors based on photoluminescent silica aerogels  

NLE Websites -- All DOE Office Websites (Extended Search)

Molecular oxygen sensors based on photoluminescent silica aerogels Molecular oxygen sensors based on photoluminescent silica aerogels Title Molecular oxygen sensors based on photoluminescent silica aerogels Publication Type Journal Article Year of Publication 1998 Authors Ayers, Michael R., and Arlon J. Hunt Journal Journal of Non-Crystalline Solids Volume 225 Pagination 343-347 Keywords aerogel, air pressure, oxygen concentration, oxygen molecules, photoluminescence Abstract Photoluminescent silica aerogel acts as the active element of an optical sensor for molecular oxygen. The luminescent aerogel is prepared by the action of energized reducing gases on a standard silica aerogel. Intensity of aerogel photoluminescence decreases as the collision frequency between oxygen molecules and the luminescent carriers in the aerogel matrix increases. This behavior is a characteristic of many photoluminescent materials and arises from a transfer of energy from the aerogel to surrounding oxygen molecules. A sensor for oxygen concentration or air pressure can therefore be simply constructed utilizing an ultraviolet source for excitation and a suitable detector for the emitted visible signal. Stern-Volmer quenching constants for the aerogel sensing element are 1.55×10-2 Torr-1 for hydrophilic aerogel and 2.4×10-3 Torr-1 for hydrophobic aerogel.

110

Methods to quantify contamination effects on silica gel samples  

DOE Green Energy (OSTI)

This report describes a study to establish methods for measuring sorption degradation of contaminated solid desiccants and determining the identity and nature of the contaminants. A literature search was conducted to determine how contaminants affect the sorption properties of silica gel and advanced solid desiccant materials; the search yielded 73 papers. Silica gel was chosen for the contamination study; nine samples from various batches and suppliers were tested. Methods were established (1) to measure the degradation of desiccant adsorption capacity caused by regeneration processes and/or exposure to contaminants and (2) to determine the nature of these contaminants. Sorption measurements on a limited number of fresh silica gel samples showed that the water adsorption capacity varied about +-10%. The silica gel sample regenerated with electric heaters exhibited a maximum capacity degradation of 7%. Silica gel samples processed in other ways lost between 20% and 47% capacity, depending on the age and cycle of regeneration. The contaminants found were silicon, oxygen, carbon, and nitrogen using x-ray photoelectron spectroscopy. Contamination can degrade the water sorption capacity of desiccants.

Pesaran, A.A.; Thomas, T.M.; Penney, T.R.; Czanderna, A.W.

1986-09-01T23:59:59.000Z

111

Kinetics of silica deposition from simulated geothermal brines  

DOE Green Energy (OSTI)

Supersaturated brines were passed through columns packed with several forms of silica (crystalline ..cap alpha.. quartz, polycrystalline ..cap alpha.. quartz, and porous Vycor). Also, silica deposition on ThO/sub 2/ microspheres and titanium powder was studied under controlled conditions of supersaturation, pH, temperature, and salinity. The residence time was varied by adjustments of flow rate and column length. The silica contents of the input and effluent solutions were determined colorimetrically by a molybdate method which does not include polymers without special pretreatment. Essentially identical deposition behavior was observed once the substrate was thoroughly coated with amorphous silica and the BET surface area of the coated particles was taken into account. The reaction rate is not diffusion limited in the columns. The silica deposition is a function of the monomeric Si(OH)/sub 4/ concentration in the brine. The deposition on all surfaces examined was spontaneously nucleated. The dependence on the supersaturation concentration, hydroxide ion concentration, surface area, temperature and salinity were examined. Fluoride was shown to have no effect at pH 5.94 and low salinity. The empirical rate law which describes the data in 1 m NaCl in the pH range 5-7 and temperatures from 60 to 120/sup 0/C is given.

Bohlmann, E.G.; Mesmer, R.E.; Berlinski, P.

1980-03-01T23:59:59.000Z

112

FIRST LABORATORY OBSERVATION OF SILICA GRAINS FROM CORE COLLAPSE SUPERNOVAE  

SciTech Connect

We report the discovery of two supernova silica (SiO{sub 2}) grains in the primitive carbonaceous chondrites LaPaZ 031117 and Grove Mountains 021710. Only five presolar silica grains have been previously reported from laboratory measurements but they all exhibit enrichments in {sup 17}O relative to solar, indicating origins in the envelopes of asymptotic giant branch stars. The two SiO{sub 2} grains identified in this study are characterized by moderate enrichments in {sup 18}O relative to solar, indicating that they originated in Type II supernova ejecta. If compared to theoretical models, the oxygen isotopic compositions of these grains can be reproduced by mixing of different supernova zones. While both theoretical models of grain condensation and recent NASA Spitzer Space Telescope observations have suggested the presence of silica in supernova ejecta, no such grains had been identified, until now, in meteorites. The discovery of these two silica grains provides definitive evidence of the condensation of silica dust in supernova ejecta.

Haenecour, Pierre; Floss, Christine; Zinner, Ernst [Laboratory for Space Sciences, McDonnell Center for the Space Sciences and Physics Department, Washington University, One Brookings Drive, St. Louis, MO 63130-4899 (United States); Zhao Xuchao; Lin Yangting, E-mail: haenecour@wustl.edu [Key Laboratory of the Earth's Deep Interior, Institute of Geology and Geophysics, Chinese Academy of Sciences, Beijing 100029 (China)

2013-05-01T23:59:59.000Z

113

Dewetting of silica surfaces upon reactions with supercritical CO2 and brine: Pore-scale studies in micromodels  

E-Print Network (OSTI)

Influence of Compressed Carbon Dioxide on the Capillarity ofof supercritical carbon dioxide on silica. Langmuir 2001,Silica Surfaces and the Carbon Dioxide Molecule. J Phys Chem

Kim, Y.

2013-01-01T23:59:59.000Z

114

Silica membranes for hydrogen separation from coal gas. Final report  

DOE Green Energy (OSTI)

This project is a continuation of a previous DOE-UCR project (DE-FG22- 89PC89765) dealing with the preparation of silica membranes highly permselective to hydrogen at elevated temperatures, suitable for hydrogen separation from coal gas. The membranes prepared in the previous project had very high selectivity but relatively low permeance. Therefore, the general objectives of this project were to improve the permeance of these membranes and to obtain fundamental information about membrane structure and properties. The specific objectives were: (1) to explore new silylation reagents and reaction conditions with the purpose of reducing the thickness and increasing the permeance of silica membranes prepared by chemical vapor deposition (CVD), (2) to characterize the membrane structure, (3) to delineate mechanism and kinetics of deposition, (4) to measure the permeability of silica layers at different extents of deposition, and (5) to mathematically model the relationship between structure and deposition kinetics.

Gavalas, G.R.

1996-01-01T23:59:59.000Z

115

The dissociation of liquid silica at high pressure and temperature  

Science Conference Proceedings (OSTI)

Liquid silica at high pressure and temperature is shown to undergo significant structural modifications and profound changes in its electronic properties. Temperature measurements on shock waves in silica at 70-1000 GPa indicate that the specific heat of liquid SiO{sub 2} rises well above the Dulong-Petit limit, exhibiting a broad peak with temperature that is attributable to the growing structural disorder caused by bond-breaking in the melt. The simultaneous sharp rise in optical reflectivity of liquid SiO{sub 2} indicates that dissociation causes the electrical and therefore thermal conductivities of silica to attain metallic-like values of 1-5 x 10{sup 5} S/m and 24-600 W/m.K respectively.

Hicks, D; Boehly, T; Eggert, J; Miller, J; Celliers, P; Collins, G

2005-11-17T23:59:59.000Z

116

PATCHY SILICA-COATED SILVER NANOWIRES AS SERS SUBSTRATES  

SciTech Connect

We report a class of core-shell nanomaterials that can be used as efficient surface-enhancement Raman scattering (SERS) substrates. The core consists of silver nanowires, prepared through a chemical reduction process, that are used to capture 4- mercaptobenzoic acid (4-MBA), a model analyte. The shell was prepared through a modified Stöber method and consists of patchy or full silica coats. The formation of silica coats was monitored via transmission electron microscopy, UV-visible spectroscopy and phase-analysis light scattering for measuring effective surface charge. Surprisingly, the patchy silica coated silver nanowires are better SERS substrate than silver nanowires; nanomolar concentration of 4-MBA can be detected. In addition, “nano-matryoshka” configurations were used to quantitate/explore the effect of the electromagnetic field at the tips of the nanowire (“hot spots”) in the Raman scattering experiment.

Murph, S.; Murphy, C.

2013-03-29T23:59:59.000Z

117

Electrospinning of silica nanofibers: characterization and application to biosensing  

E-Print Network (OSTI)

Electrospinning is a technique to achieve nanometer scale fibers. Similar to the conventional spin methods of making fabric, the viscous polymer solution is ejected from a spinneret; stretched and solidified in the air, the solution forms the fibers. The different part of electrospinning among others is that the fibers are driven by the electrostatic force, which induces the repulsion inside the liquid and further reduces the diameter. The resultant product is a non-woven membrane, which is porous; and the pore size is around several nanometers to a micrometer wide. In this work, the relationship between the diameter of electrospun silica fibers, experimental parameters such as concentration and voltage, and between pore size of the fiber membrane and experimental time were studied. Materials used in the process are Polyvinylpyrrolidone (PVP), butanol and spin-on-glass coating solution, which act as polymer carrier, solvent, and silica-precursor, respectively. Polymer/silica precursor composite fibers were ejected from the needle of a plastic syringe when an electrical field, as high as several kV/cm, was applied. Then silica fibers were achieved by baking the composite ones at 773 oK for 12 h. Electrospun silica nanofibers were characterized as a function of polymer solution parameters. The calcined fibers were examined by using a field emission scanning electron microscope. The results showed that the fiber diameters decrease with decreasing proportion of polymer and silica precursor, and increase with a higher electric field. Pore sizes, defined as the grid areas enclosed by fibers on nearby layers, were also examined and showed no time-dependent tendency when the electrospin time was between 1-5 min. Fiber membranes were then used as the platform for protein detection. The results were compared with the control, which used glass slides as the platform. The results make it possible to make a more sensitive biosensing device.

Tsou, Pei-Hsiang

2006-08-01T23:59:59.000Z

118

Potential Health Effects of Crystalline Silica Exposures from Coal Fly Ash: A Literature Review  

Science Conference Proceedings (OSTI)

The amount of crystalline silica in coal fly ash (CFA) depends on a variety of factors, including the amount of silica in the pre-combustion coal, the combustion process, and emission control technologies among others. Occupational exposures to crystalline silica in CFA are related to these factors as well as activities associated with exposures and durations of exposure. This review summarizes the occupational and environmental health literature relevant to the presence of crystalline silica in CFA from...

2006-03-27T23:59:59.000Z

119

Analysis of the elastic behaviour of silica aerogels taken as a percolating system  

E-Print Network (OSTI)

289 Analysis of the elastic behaviour of silica aerogels taken as a percolating system T. Woignier of silica aerogels are performed using the three points flexural technique. The elastic behaviour is studied measurement - for silica aerogels. These highly porous materials are obtained from a sol-gel process. Solvent

Paris-Sud XI, Université de

120

Method of making a sodium sulfur battery  

SciTech Connect

A method of making a portion of a sodium sulfur battery is disclosed. The battery portion made is a portion of the container which defines the volume for the cathodic reactant materials which are sulfur and sodium polysulfide materials. The container portion is defined by an outer metal casing with a graphite liner contained therein, the graphite liner having a coating on its internal diameter for sealing off the porosity thereof. The steel outer container and graphite pipe are united by a method which insures that at the operating temperature of the battery, relatively low electrical resistance exists between the two materials because they are in intimate contact with one another.

Elkins, Perry E. (Santa Ana, CA)

1981-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "na-sg sodium silica" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Capacity degradation of field-tested silica gel samples  

DOE Green Energy (OSTI)

Researchers at the Solar Energy Research Institute (SERI) have begun preliminary studies to quantify the effect of contamination of silica gel used in dehumidification processes of desiccant cooling systems. Sorption capacity degradation of field tested samples was measured, and the source of degradation was quantified using surface analysis experimental methods.

Penney, T.R.; Pesaran, A.A.; Thomas, T.M.

1985-06-01T23:59:59.000Z

122

Fractal Studies on Titanium-Silica Aerogels using SMARTer  

SciTech Connect

Power-law scattering approximation has been employed to reveal the fractal structures of solid-state titanium-silica aerogel samples. All small-angle neutron scattering (SANS) measurements were performed using 36 meters SANS BATAN spectrometer (SMARTer) at the neutron scattering laboratory (NSL) in Serpong, Indonesia. The mass fractal dimension of titanium-silica aerogels at low scattering vector q range increases from -1.4 to -1.92 with the decrease of acid concentrations during sol-gel process. These results are attributed to the titanium-silica aerogels that are growing to more polymeric and branched structures. At high scattering vector q range the Porod slope of -3.9 significantly down to -2.24 as the roughness of particle surfaces becomes higher. The cross over between these two regimes decreases from 0.4 to 0.16 nm{sup -1} with the increase of acid concentrations indicating also that the titanium-silica aerogels are growing.

Putra, E. Giri Rachman; Ikram, A.; Bharoto; Santoso, E. [Neutron Scattering Laboratory, BATAN, Kawasan Puspiptek Serpong, Tangerang 15314 (Indonesia); Fang, T. Chiar; Ibrahim, N. [Department of Physics, Faculty of Science Universiti Teknologi Malaysia (UTM), 81310 Skudai, Johor (Malaysia); Mohamed, A. Aziz [Materials Technology Group, Industrial Technology Division Agensi Nuklear Malaysia, 43000 Kajang (Malaysia)

2008-03-17T23:59:59.000Z

123

High temperature thermographic measurements of laser heated silica  

SciTech Connect

In situ spatial and temporal surface temperature profiles of CO{sub 2} laser-heated silica were obtained using a long wave infrared (LWIR) HgCdTe camera. Solutions to the linear diffusion equation with volumetric and surface heating are shown to describe the temperature evolution for a range of beam powers, over which the peak surface temperature scales linearly with power. These solutions were used with on-axis steady state and transient experimental temperatures to extract thermal diffusivity and conductivity for a variety of materials, including silica, spinel, sapphire, and lithium fluoride. Experimentally-derived thermal properties agreed well with reported values and, for silica, thermal conductivity and diffusivity are shown to be approximately independent of temperature between 300 and 2800K. While for silica our analysis based on a temperature independent thermal conductivity is shown to be accurate, for other materials studied this treatment yields effective thermal properties that represent reasonable approximations for laser heating. Implementation of a single-wavelength radiation measurement in the semi-transparent regime is generally discussed, and estimates of the apparent temperature deviation from the actual outer surface temperature are also presented. The experimental approach and the simple analysis presented yield surface temperature measurements that can be used to validate more complex physical models, help discriminate dominant heat transport mechanisms, and to predict temperature distribution and evolution during laser-based material processing.

Elhadj, S; Yang, S T; Matthews, M J; Cooke, D J; Bude, J D; Johnson, M; Feit, M; Draggoo, V; Bisson, S E

2009-11-02T23:59:59.000Z

124

Fabrication of magnetite/silica/titania core-shell nanoparticles  

Science Conference Proceedings (OSTI)

Fe3O4/SiO2/TiO2 core-shell nanoparticles were synthesized via a sol-gel method with the aid of sonication. Fe3O4 nanoparticles were being encapsulated within discrete silica nanospheres, ...

Suh Cem Pang; Sze Yun Kho; Suk Fun Chin

2012-01-01T23:59:59.000Z

125

Flue gas injection control of silica in cooling towers.  

Science Conference Proceedings (OSTI)

Injection of CO{sub 2}-laden flue gas can decrease the potential for silica and calcite scale formation in cooling tower blowdown by lowering solution pH to decrease equilibrium calcite solubility and kinetic rates of silica polymerization. Flue gas injection might best inhibit scale formation in power plant cooling towers that use impaired makeup waters - for example, groundwaters that contain relatively high levels of calcium, alkalinity, and silica. Groundwaters brought to the surface for cooling will degas CO{sub 2} and increase their pH by 1-2 units, possibly precipitating calcite in the process. Recarbonation with flue gas can lower the pHs of these fluids back to roughly their initial pH. Flue gas carbonation probably cannot lower pHs to much below pH 6 because the pHs of impaired waters, once outgassed at the surface, are likely to be relatively alkaline. Silica polymerization to form scale occurs most rapidly at pH {approx} 8.3 at 25 C; polymerization is slower at higher and lower pH. pH 7 fluids containing {approx}220 ppm SiO{sub 2} require > 180 hours equilibration to begin forming scale whereas at pH 8.3 scale formation is complete within 36 hours. Flue gas injection that lowers pHs to {approx} 7 should allow substantially higher concentration factors. Periodic cycling to lower recoveries - hence lower silica concentrations - might be required though. Higher concentration factors enabled by flue gas injection should decrease concentrate volumes and disposal costs by roughly half.

Brady, Patrick Vane; Anderson, Howard L., Jr.; Altman, Susan Jeanne

2011-06-01T23:59:59.000Z

126

INHIBITION OF WASHED SLUDGE WITH SODIUM NITRITE  

SciTech Connect

This report describes the results of electrochemical tests used to determine the relationship between the concentration of the aggressive anions in washed sludge and the minimum effective inhibitor concentration. Sodium nitrate was added as the inhibitor because of its compatibility with the DWPF process. A minimum of 0.05M nitrite is required to inhibit the washed sludge simulant solution used in this study. When the worst case compositions and safety margins are considered, it is expected that a minimum operating limit of nearly 0.1M nitrite will be specified. The validity of this limit is dependent on the accuracy of the concentrations and solubility splits previously reported. Sodium nitrite additions to obtain 0.1M nitrite concentrations in washed sludge will necessitate the additional washing of washed precipitate in order to decrease its sodium nitrite inhibitor requirements sufficiently to remain below the sodium limits in the feed to the DWPF. Nitrite will be the controlling anion in "fresh" washed sludge unless the soluble chloride concentration is about ten times higher than predicted by the solubility splits. Inhibition of "aged" washed sludge will not be a problem unless significant chloride dissolution occurs during storage. It will be very important tomonitor the composition of washed sludge during processing and storage.

Congdon, J.; Lozier, J.

2012-09-25T23:59:59.000Z

127

Devitrification of Fused Silica into Cristobalite in Sintered Powder ...  

Science Conference Proceedings (OSTI)

A History of the Theories of Glass Structure: Can We Really Believe What is ... Field Assisted Viscous Flow and Crystallization in a Sodium Aluminosilicate Glass ... Mechanisms of the Conversion Reaction in FeF2 Cathodes Exposed to Li in ...

128

The electrical conductivity of sodium polysulfide melts  

DOE Green Energy (OSTI)

The sodium polysulfide melt has been described by a macroscopic model. This model considers the melt to be composed of sodium cations, monosulfide anions, and neutral sulfur solvent. The transport equations of concentrated-solution theory are used to derived the governing equations for this binaryelectrolyte melt model. These equations relate measurable transport properties to fundamental transport parameters. The focus of this research is to measure the electrical conductivity of sodium polysulfide melts and calculate one of fundamental transport parameters from the experimental data. The conductance cells used in the conductivity measurements are axisymmetric cylindrical cells with a microelectrode. The electrode effects, including double-layer capacity, charge transfer resistance, and concentration overpotential, were minimized by the use of the alternating current at an adequately high frequency. The high cell constants of the conductance cells not only enhanced the experimental accuracy but also made the electrode effects negligible. The electrical conductivities of sodium polysulfide Na{sub 2}S{sub 4} and Na{sub 2}S{sub 5} were measured as a function of temperature (range: 300 to 360{degree}C). Variations between experiments were only up to 2%. The values of the Arrhenius activation energy derived from the experimental data are about 33 kJ/mol. The fundamental transport parameter which quantifies the interaction within sodium cations and monosulfide anions are of interest and expected to be positive. Values of it were calculated from the experimental conductivity data and most of them are positive. Some negative values were obtained probably due to the experimental errors of transference number, diffusion coefficient, density or conductivity data.

Meihui Wang

1992-06-01T23:59:59.000Z

129

Viscosity and density tables of sodium chloride solutions  

DOE Green Energy (OSTI)

A file is presented containing tabulated data extracted from the scientific literature on the density and viscosity of aqueous sodium chloride solutions. Also included is a bibliography of the properties of aqueous sodium chloride solutions. (MHR)

Fair, J.A.; Ozbek, H. (comps.) [comps.

1977-04-01T23:59:59.000Z

130

Structure and Properties of Piezoelectric Sodium Bismuth Titanate ...  

Science Conference Proceedings (OSTI)

Presentation Title, Structure and Properties of Piezoelectric Sodium Bismuth Titanate ... Nanostructures and Their Potential for Mechanical Energy Scavenging.

131

Sodium and sulfur release and recapture during black liquor burning  

DOE Green Energy (OSTI)

The objective of this study was to provide data on sulfur and sodium volatilization during black liquor burning, and on SO2 capture by solid sodium carbonate and sodium chloride. This data was interpreted and modeled into rate equations suitable for use in computational models for recovery boilers.

Frederick, W.J.; Iisa, K.; Wag, K.; Reis, V.V.; Boonsongsup, L.; Forssen, M.; Hupa, M.

1995-08-01T23:59:59.000Z

132

Corrosion performance of advanced structural materials in sodium.  

SciTech Connect

This report gives a description of the activities in design, fabrication, construction, and assembling of a pumped sodium loop for the sodium compatibility studies on advanced structural materials. The work is the Argonne National Laboratory (ANL) portion of the effort on the work project entitled, 'Sodium Compatibility of Advanced Fast Reactor Materials,' and is a part of Advanced Materials Development within the Reactor Campaign. The objective of this project is to develop information on sodium corrosion compatibility of advanced materials being considered for sodium reactor applications. This report gives the status of the sodium pumped loop at Argonne National Laboratory, the specimen details, and the technical approach to evaluate the sodium compatibility of advanced structural alloys. This report is a deliverable from ANL in FY2010 (M2GAN10SF050302) under the work package G-AN10SF0503 'Sodium Compatibility of Advanced Fast Reactor Materials.' Two reports were issued in 2009 (Natesan and Meimei Li 2009, Natesan et al. 2009) which examined the thermodynamic and kinetic factors involved in the purity of liquid sodium coolant for sodium reactor applications as well as the design specifications for the ANL pumped loop for testing advanced structural materials. Available information was presented on solubility of several metallic and nonmetallic elements along with a discussion of the possible mechanisms for the accumulation of impurities in sodium. That report concluded that the solubility of many metals in sodium is low (<1 part per million) in the temperature range of interest in sodium reactors and such trace amounts would not impact the mechanical integrity of structural materials and components. The earlier report also analyzed the solubility and transport mechanisms of nonmetallic elements such as oxygen, nitrogen, carbon, and hydrogen in laboratory sodium loops and in reactor systems such as Experimental Breeder Reactor-II, Fast Flux Test Facility, and Clinch River Breeder Reactor. Among the nonmetallic elements discussed, oxygen is deemed controllable and its concentration in sodium can be maintained in sodium for long reactor life by using cold-trap method. It was concluded that among the cold-trap and getter-trap methods, the use of cold trap is sufficient to achieve oxygen concentration of the order of 1 part per million. Under these oxygen conditions in sodium, the corrosion performance of structural materials such as austenitic stainless steels and ferritic steels will be acceptable at a maximum core outlet sodium temperature of {approx}550 C. In the current sodium compatibility studies, the oxygen concentration in sodium will be controlled and maintained at {approx}1 ppm by controlling the cold trap temperature. The oxygen concentration in sodium in the forced convection sodium loop will be controlled and monitored by maintaining the cold trap temperature in the range of 120-150 C, which would result in oxygen concentration in the range of 1-2 ppm. Uniaxial tensile specimens are being exposed to flowing sodium and will be retrieved and analyzed for corrosion and post-exposure tensile properties. Advanced materials for sodium exposure include austenitic alloy HT-UPS and ferritic-martensitic steels modified 9Cr-1Mo and NF616. Among the nonmetallic elements in sodium, carbon was assessed to have the most influence on structural materials since carbon, as an impurity, is not amenable to control and maintenance by any of the simple purification methods. The dynamic equilibrium value for carbon in sodium systems is dependent on several factors, details of which were discussed in the earlier report. The current sodium compatibility studies will examine the role of carbon concentration in sodium on the carburization-decarburization of advanced structural materials at temperatures up to 650 C. Carbon will be added to the sodium by exposure of carbon-filled iron tubes, which over time will enable carbon to diffuse through iron and dissolve into sodium. The method enables addition of dissolved carbon (without carb

Natesan, K.; Momozaki, Y.; Li, M.; Rink, D.L. (Nuclear Engineering Division)

2012-05-16T23:59:59.000Z

133

CAST STONE FORMULATION AT HIGHER SODIUM CONCENTRATIONS  

SciTech Connect

A low temperature waste form known as Cast Stone is being considered to provide supplemental Low Activity Waste (LAW) immobilization capacity for the Hanford site. Formulation of Cast Stone at high sodium concentrations is of interest since a significant reduction in the necessary volume of Cast Stone and subsequent disposal costs could be achieved if an acceptable waste form can be produced with a high sodium molarity salt solution combined with a high water to premix (or dry blend) ratio. The objectives of this study were to evaluate the factors involved with increasing the sodium concentration in Cast Stone, including production and performance properties and the retention and release of specific components of interest. Three factors were identified for the experimental matrix: the concentration of sodium in the simulated salt solution, the water to premix ratio, and the blast furnace slag portion of the premix. The salt solution simulants used in this study were formulated to represent the overall average waste composition. The cement, blast furnace slag, and fly ash were sourced from a supplier in the Hanford area in order to be representative. The test mixes were prepared in the laboratory and fresh properties were measured. Fresh density increased with increasing sodium molarity and with decreasing water to premix ratio, as expected given the individual densities of these components. Rheology measurements showed that all of the test mixes produced very fluid slurries. The fresh density and rheology data are of potential value in designing a future Cast Stone production facility. Standing water and density gradient testing showed that settling is not of particular concern for the high sodium compositions studied. Heat of hydration measurements may provide some insight into the reactions that occur within the test mixes, which may in turn be related to the properties and performance of the waste form. These measurements showed that increased sodium concentration in the salt solution reduced the time to peak heat flow, and reducing the amount of slag in the premix increased the time to peak heat flow. These observations may help to describe some of the cured properties of the samples, in particular the differences in compressive strength observed after 28 and 90 days of curing. Samples were cured for at least 28 days at ambient temperature in the laboratory prior to cured properties analyses. The low activity waste form for disposal at the Hanford Site is required to have a compressive strength of at least 500 psi. After 28 days of curing, several of the test mixes had mean compressive strengths that were below the 500 psi requirement. Higher sodium concentrations and higher water to premix ratios led to reduced compressive strength. Higher fly ash concentrations decreased the compressive strength after 28 days of curing. This may be explained in that the cementitious phases matured more quickly in the mixes with higher concentrations of slag, as evidenced by the data for the time to peak heat generation. All of the test mixes exhibited higher mean compressive strengths after 90 days of curing, with only one composition having a mean compressive strength of less than 500 psi. Leach indices were determined for the test mixes for contaminants of interest. The leaching performance of the mixes evaluated in this study was not particularly sensitive to the factors used in the experimental design. This may be beneficial in demonstrating that the performance of the waste form is robust with respect to changes in the mix composition. The results of this study demonstrate the potential to achieve significantly higher waste loadings in Cast Stone and other low temperature, cementitious waste forms. Additional work is needed to elucidate the hydration mechanisms occurring in Cast Stone formulated with highly concentrated salt solutions since these reactions are responsible for determining the performance of the cured waste form. The thermal analyses completed in this study provide some preliminary insight, although the limited

Fox, K.; Edwards, T.; Roberts, K.

2013-10-02T23:59:59.000Z

134

CAST STONE FORMULATION AT HIGHER SODIUM CONCENTRATIONS  

SciTech Connect

A low temperature waste form known as Cast Stone is being considered to provide supplemental Low Activity Waste (LAW) immobilization capacity for the Hanford site. Formulation of Cast Stone at high sodium concentrations is of interest since a significant reduction in the necessary volume of Cast Stone and subsequent disposal costs could be achieved if an acceptable waste form can be produced with a high sodium molarity salt solution combined with a high water to premix (or dry blend) ratio. The objectives of this study were to evaluate the factors involved with increasing the sodium concentration in Cast Stone, including production and performance properties and the retention and release of specific components of interest. Three factors were identified for the experimental matrix: the concentration of sodium in the simulated salt solution, the water to premix ratio, and the blast furnace slag portion of the premix. The salt solution simulants used in this study were formulated to represent the overall average waste composition. The cement, blast furnace slag, and fly ash were sourced from a supplier in the Hanford area in order to be representative. The test mixes were prepared in the laboratory and fresh properties were measured. Fresh density increased with increasing sodium molarity and with decreasing water to premix ratio, as expected given the individual densities of these components. Rheology measurements showed that all of the test mixes produced very fluid slurries. The fresh density and rheology data are of potential value in designing a future Cast Stone production facility. Standing water and density gradient testing showed that settling is not of particular concern for the high sodium compositions studied. Heat of hydration measurements may provide some insight into the reactions that occur within the test mixes, which may in turn be related to the properties and performance of the waste form. These measurements showed that increased sodium concentration in the salt solution reduced the time to peak heat flow, and reducing the amount of slag in the premix increased the time to peak heat flow. These observations may help to describe some of the cured properties of the samples, in particular the differences in compressive strength observed after 28 and 90 days of curing. Samples were cured for at least 28 days at ambient temperature in the laboratory prior to cured properties analyses. The low activity waste form for disposal at the Hanford Site is required to have a compressive strength of at least 500 psi. After 28 days of curing, several of the test mixes had mean compressive strengths that were below the 500 psi requirement. Higher sodium concentrations and higher water to premix ratios led to reduced compressive strength. Higher fly ash concentrations decreased the compressive strength after 28 days of curing. This may be explained in that the cementitious phases matured more quickly in the mixes with higher concentrations of slag, as evidenced by the data for the time to peak heat generation. All of the test mixes exhibited higher mean compressive strengths after 90 days of curing, with only one composition having a mean compressive strength of less than 500 psi. Leach indices were determined for the test mixes for contaminants of interest. The leaching performance of the mixes evaluated in this study was not particularly sensitive to the factors used in the experimental design. This may be beneficial in demonstrating that the performance of the waste form is robust with respect to changes in the mix composition. The results of this study demonstrate the potential to achieve significantly higher waste loadings in Cast Stone and other low temperature, cementitious waste forms. Additional work is needed to elucidate the hydration mechanisms occurring in Cast Stone formulated with highly concentrated salt solutions since these reactions are responsible for determining the performance of the cured waste form. The thermal analyses completed in this study provide some preliminary insight, although the limited

Fox, K.; Roberts, K.; Edwards, T.

2013-09-17T23:59:59.000Z

135

Large-scale sodium spray fire code validation (SOFICOV) test  

Science Conference Proceedings (OSTI)

A large-scale, sodium, spray fire code validation test was performed in the HEDL 850-m/sup 3/ Containment System Test Facility (CSTF) as part of the Sodium Spray Fire Code Validation (SOFICOV) program. Six hundred fifty eight kilograms of sodium spray was sprayed in an air atmosphere for a period of 2400 s. The sodium spray droplet sizes and spray pattern distribution were estimated. The containment atmosphere temperature and pressure response, containment wall temperature response and sodium reaction rate with oxygen were measured. These results are compared to post-test predictions using SPRAY and NACOM computer codes.

Jeppson, D.W.; Muhlestein, L.D.

1985-01-01T23:59:59.000Z

136

Plutonium complexation by phosphonate-functionalized mesoporous silica  

Science Conference Proceedings (OSTI)

MCM-41-type mesoporous silica functionalized with the CMPO-based 'Ac-Phos' silane has been reported in the literature (1) to show good capacity as an acftinide sorbent material, with potential applications in environmental sequestration, aqueous waste separation and/or vitrification, and chemical sensing of actinides in solution. The study explores the complexation of Pu(IV and VI) and other selected actinides and lanthanides by SBA-15 type mesoporous silica functionalized with Ac-Phos. The Pu binding kinetics and binding capacity were determined for both the Ac-Phos functionalized and unmodified SBA-15. They analyzed the binding geometry and redox behavior of Pu(VI) by X-ray absorption spectroscopy (XAS). They discuss the synthesis and characterization of the functionalized mesoporous material, batch sorption experiments, and the detailed analyses of the actinide complexes that are formed. Structural measurements are paired with high-level quantum mechanical modeling to elucidate the binding mechanisms.

Parsons-Moss, T; Schwaiger, L K; Hubaud, A; Hu, Y J; Tuysuz, H; Yang, P; Balasubramanian, K; Nitsche, H

2010-10-27T23:59:59.000Z

137

Laser supported solid state absorption fronts in silica  

SciTech Connect

We develop a model based on simulation and experiment that explains the behavior of solid-state laser-supported absorption fronts generated in fused silica during high intensity (up to 5GW/cm{sup 2}) laser exposure. We find that the absorption front velocity is constant in time and is nearly linear in laser intensity. Further, this model can explain the dependence of laser damage site size on these parameters. This behavior is driven principally by the temperature-activated deep sub band-gap optical absorptivity, free electron transport and thermal diffusion in defect-free silica for temperatures up to 15,000K and pressures < 15GPa. The regime of parameter space critical to this problem spans and extends that measured by other means. It serves as a platform for understanding general laser-matter interactions in dielectrics under a variety of conditions.

Carr, C W; Bude, J D

2010-02-09T23:59:59.000Z

138

Molecular engineering of porous silica using aryl templates  

DOE Patents (OSTI)

A process is described for manipulating the porosity of silica using a series of organic template groups covalently incorporated into the silicate matrix. The templates in the bridged polysilsesquioxanes are selectively removed from the material by oxidation with oxygen plasma or other means, leaving engineered voids or pores. The size of these pores is dependent upon the length or size of the template or spacer. The size of the templates is measured in terms of Si-Si distances which range from about 0.67 nm to 1.08 nm. Changes introduced by the loss of the templates result in a narrow range of micropores (i.e. <2 nm). Both aryl and alkyl template groups are used as spacers. Novel microporous silica materials useful as molecular sieves, desiccants, and catalyst supports are produced. 3 figs.

Loy, D.A.; Shea, K.J.

1994-06-14T23:59:59.000Z

139

Molecular engineering of porous silica using aryl templates  

SciTech Connect

A process for manipulating the porosity of silica using a series of organic template groups covalently incorporated into the silicate matrix. The templates in the bridged polysilsesquioxanes are selectively removed from the material by oxidation with oxygen plasma or other means, leaving engineered voids or pores. The size of these pores is dependent upon the length or size of the template or spacer. The size of the templates is measured in terms of Si-Si distances which range from about 0.67 nm to 1.08 nm. Changes introduced by the loss of the templates result in a narrow range of micropores (i.e. <2 nm). Both aryl and alkyl template groups are used as spacers. Novel microporous silica materials useful as molecular seives, dessicants, and catalyst supports are produced.

Loy, Douglas A. (Albuquerque, NM); Shea, Kenneth J. (Irvine, CA)

1994-01-01T23:59:59.000Z

140

Fluorescent Functionalized Mesoporous Silica for Radioactive Material Extraction  

Science Conference Proceedings (OSTI)

Mesoporous silica with covalently bound salicylic acid molecules incorporated in the structure was synthesized with a one-pot, co-condensation reaction at room temperature. The as-synthesized material has a large surface area, uniform particle size, and an ordered pore structure as determined by characterization with transmission electron microscopy, thermal gravimetric analysis, and infrared spectra, etc. Using the strong fluorescence and metal coordination capability of salicylic acid, functionalized mesoporous silica (FMS) was developed to track and extract radionuclide contaminants, such as uranyl [U(VI)] ions encountered in subsurface environments. Adsorption measurements showed a strong affinity of the FMS toward U(VI) with a Kd value of 105 mL/g, which is four orders of magnitude higher than the adsorption of U(VI) onto most of the sediments in natural environments. The new materials have a potential for synergistic environmental monitoring and remediation of the radionuclide U(VI) from contaminated subsurface environments.

Li, Juan; Zhu, Kake; Shang, Jianying; Wang, Donghai; Nie, Zimin; Guo, Ruisong; Liu, Chongxuan; Wang, Zheming; Li, Xiaolin; Liu, Jun

2012-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "na-sg sodium silica" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Sodium Plugging Test Loop - Nuclear Engineering Division (Argonne)  

NLE Websites -- All DOE Office Websites (Extended Search)

Sodium Plugging Test Loop Sodium Plugging Test Loop Sodium Plugging Test Loop Overview Other Facilities Work with Argonne Contact us For Employees Site Map Help Join us on Facebook Follow us on Twitter NE on Flickr Sodium Plugging Test Loop This experimental setup is part of the Global Nuclear Energy Partnership (GNEP) Advanced Fuel Cycle R&D work carried out at Argonne on advanced sodium component technology. Bookmark and Share For long range sodium technology research and development, employing supercritical CO2 Brayton cycle power conversion technology as an advanced balance of plant technology is being considered. The component that provides the interface between the sodium and supercritical CO2 is a compact heat exchanger known as a printed circuit heat exchanger (PCHE). This heat exchanger has very small coolant flow passages that may foul or

142

Idaho Site Obtains Patent for Nuclear Reactor Sodium Cleanup Treatment |  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Obtains Patent for Nuclear Reactor Sodium Cleanup Obtains Patent for Nuclear Reactor Sodium Cleanup Treatment Idaho Site Obtains Patent for Nuclear Reactor Sodium Cleanup Treatment March 28, 2013 - 12:00pm Addthis CWI engineers Jeff Jones, David Tolman, right, and Kirk Dooley (seated) developed a treatment to safely dissolve a bicarbonate crust and treat and remove the sodium in the Experimental Breeder Reactor-II at the Idaho site. CWI engineers Jeff Jones, David Tolman, right, and Kirk Dooley (seated) developed a treatment to safely dissolve a bicarbonate crust and treat and remove the sodium in the Experimental Breeder Reactor-II at the Idaho site. Piping in the east boiler basement of the sodium processing building was color coded for easy identification. Orange indicates sodium and green identifies cooling water.

143

Low-Pressure Sodium Lighting Basics | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Low-Pressure Sodium Lighting Basics Low-Pressure Sodium Lighting Basics Low-Pressure Sodium Lighting Basics August 16, 2013 - 10:17am Addthis Low-pressure sodium lighting provides more energy-efficient outdoor lighting than high-intensity discharge lighting, but it has very poor color rendition. Typical applications include highway and security lighting, where color is not important. Low-pressure sodium lamps work somewhat like fluorescent lamps. Like high-intensity discharge lighting, low-pressure sodium lamps require up to 10 minutes to start and have to cool before they can restart. Therefore, they are most suitable for applications in which they stay on for hours at a time. They are not suitable for use with motion detectors. The chart below compares low-pressure sodium lamps and high-intensity

144

Idaho Site Obtains Patent for Nuclear Reactor Sodium Cleanup Treatment |  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Idaho Site Obtains Patent for Nuclear Reactor Sodium Cleanup Idaho Site Obtains Patent for Nuclear Reactor Sodium Cleanup Treatment Idaho Site Obtains Patent for Nuclear Reactor Sodium Cleanup Treatment March 28, 2013 - 12:00pm Addthis CWI engineers Jeff Jones, David Tolman, right, and Kirk Dooley (seated) developed a treatment to safely dissolve a bicarbonate crust and treat and remove the sodium in the Experimental Breeder Reactor-II at the Idaho site. CWI engineers Jeff Jones, David Tolman, right, and Kirk Dooley (seated) developed a treatment to safely dissolve a bicarbonate crust and treat and remove the sodium in the Experimental Breeder Reactor-II at the Idaho site. Piping in the east boiler basement of the sodium processing building was color coded for easy identification. Orange indicates sodium and green identifies cooling water.

145

Functionalized bimodal mesoporous silicas as carriers for controlled aspirin delivery  

Science Conference Proceedings (OSTI)

The bimodal mesoporous silica modified with 3-aminopropyltriethoxysilane was performed as the aspirin carrier. The samples' structure, drug loading and release profiles were characterized with X-ray diffraction, scanning electron microscopy, N{sub 2} adsorption and desorption, Fourier transform infrared spectroscopy, TG analysis, elemental analysis and UV-spectrophotometer. For further exploring the effects of the bimodal mesopores on the drug delivery behavior, the unimodal mesoporous material MCM-41 was also modified as the aspirin carrier. Meantime, Korsmeyer-Peppas equation f{sub t}=kt{sup n} was employed to analyze the dissolution data in details. It is indicated that the bimodal mesopores are beneficial for unrestricted drug molecules diffusing and therefore lead to a higher loading and faster releasing than that of MCM-41. The results show that the aspirin delivery properties are influenced considerably by the mesoporous matrix, whereas the large pore of bimodal mesoporous silica is the key point for the improved controlled-release properties. - Graphical abstract: Loading (A) and release profiles (B) of aspirin in N-BMMs and N-MCM-41 indicated that BMMs have more drug loading capacity and faster release rate than that MCM-41. Highlights: > Bimodal mesoporous silicas (BMMs) and MCM-41 modified with amino group via post-treatment procedure. > Loading and release profiles of aspirin in modified BMMs and MCM-41. > Modified BMMs have more drug loading capacity and faster release rate than that modified MCM-41.

Gao Lin [Department of Chemistry and Chemical Engineering, College of Environmental and Energy Engineering, Beijing University of Technology, Beijing 100124 (China); Sun Jihong, E-mail: jhsun@bjut.edu.cn [Department of Chemistry and Chemical Engineering, College of Environmental and Energy Engineering, Beijing University of Technology, Beijing 100124 (China); Li Yuzhen [Department of Chemistry and Chemical Engineering, College of Environmental and Energy Engineering, Beijing University of Technology, Beijing 100124 (China)

2011-08-15T23:59:59.000Z

146

Silica aerogel: An intrinsically low dielectric constant material  

Science Conference Proceedings (OSTI)

Silica aerogels are highly porous solids having unique morphologies in wavelength of visible which both the pores and particles have sizes less than the wavelength of visible light. This fine nanostructure modifies the normal transport mechanisms within aerogels and endows them with a variety of exceptional physical properties. For example, aerogels have the lowest measured thermal conductivity and dielectric constant for any solid material. The intrinsically low dielectric properties of silica aerogels are the direct result of the extremely high achievable porosities, which are controllable over a range from 75% to more than 99.8 %, and which result in measured dielectric constants from 2.0 to less than 1.01. This paper discusses the synthesis of silica aerogels, processing them as thin films, and characterizing their dielectric properties. Existing data and other physical characteristics of bulk aerogels (e.g., thermal stablity, thermal expansion, moisture adsorption, modulus, dielectric strength, etc.), which are useful for evaluating them as potential dielectrics for microelectronics, are also given.

Hrubesh, L.W.

1995-04-01T23:59:59.000Z

147

Multimodality Imaging with Silica-Based Targeted Nanoparticle Platforms  

SciTech Connect

Objectives: To synthesize and characterize a C-Dot silica-based nanoparticle containing 'clickable' groups for the subsequent attachment of targeting moieties (e.g., peptides) and multiple contrast agents (e.g., radionuclides with high specific activity) [1,2]. These new constructs will be tested in suitable tumor models in vitro and in vivo to ensure maintenance of target-specificity and high specific activity. Methods: Cy5 dye molecules are cross-linked to a silica precursor which is reacted to form a dye-rich core particle. This core is then encapsulated in a layer of pure silica to create the core-shell C-Dot (Figure 1) [2]. A 'click' chemistry approach has been used to functionalize the silica shell with radionuclides conferring high contrast and specific activity (e.g. 64Cu and 89Zr) and peptides for tumor targeting (e.g. cRGD and octreotate) [3]. Based on the selective Diels-Alder reaction between tetrazine and norbornene, the reaction is bioorthogonal, highyielding, rapid, and water-compatible. This radiolabeling approach has already been employed successfully with both short peptides (e.g. octreotate) and antibodies (e.g. trastuzumab) as model systems for the ultimate labeling of the nanoparticles [1]. Results: PEGylated C-Dots with a Cy5 core and labeled with tetrazine have been synthesized (d = 55 nm, zeta potential = -3 mV) reliably and reproducibly and have been shown to be stable under physiological conditions for up to 1 month. Characterization of the nanoparticles revealed that the immobilized Cy5 dye within the C-Dots exhibited fluorescence intensities over twice that of the fluorophore alone. The nanoparticles were successfully radiolabeled with Cu-64. Efforts toward the conjugation of targeting peptides (e.g. cRGD) are underway. In vitro stability, specificity, and uptake studies as well as in vivo imaging and biodistribution investigations will be presented. Conclusions: C-Dot silica-based nanoparticles offer a robust, versatile, and multi-functional platform to enhance in vivo detection sensitivity and non-invasively assay receptor expression/status of tumor cellular targets, including those of low abundance, using nuclear-NIR fluorescence imaging approaches [2]. Improvements in molecular diagnostics, refined by the availability of nanotechnology platforms, will be a key determinant in driving early-stage disease detection and prevention, ultimately leading to decreases in mortality.

Jason S. Lewis

2012-04-09T23:59:59.000Z

148

Preparation of silica stabilized biological templates for the production of metal and layered nanoparticles  

Science Conference Proceedings (OSTI)

The present invention relates to a system and method providing for increased silica growth on a bio-template, wherein the bio-template is pretreated with aniline to produce a uniform silica attractive surface and yielding a significant silica layers of at least 10 nm, and more preferably at least 20 nm in thickness, thereby providing for a high degree of stability to the bio-template.

Culver, James N; Royston, Elizabeth; Brown, Adam; Harris, Michael

2013-02-26T23:59:59.000Z

149

Report on sodium compatibility of advanced structural materials.  

SciTech Connect

This report provides an update on the evaluation of sodium compatibility of advanced structural materials. The report is a deliverable (level 3) in FY11 (M3A11AN04030403), under the Work Package A-11AN040304, 'Sodium Compatibility of Advanced Structural Materials' performed by Argonne National Laboratory (ANL), as part of Advanced Structural Materials Program for the Advanced Reactor Concepts. This work package supports the advanced structural materials development by providing corrosion and tensile data from the standpoint of sodium compatibility of advanced structural alloys. The scope of work involves exposure of advanced structural alloys such as G92, mod.9Cr-1Mo (G91) ferritic-martensitic steels and HT-UPS austenitic stainless steels to a flowing sodium environment with controlled impurity concentrations. The exposed specimens are analyzed for their corrosion performance, microstructural changes, and tensile behavior. Previous reports examined the thermodynamic and kinetic factors involved in the purity of liquid sodium coolant for sodium reactor applications as well as the design, fabrication, and construction of a forced convection sodium loop for sodium compatibility studies of advanced materials. This report presents the results on corrosion performance, microstructure, and tensile properties of advanced ferritic-martensitic and austenitic alloys exposed to liquid sodium at 550 C for up to 2700 h and at 650 C for up to 5064 h in the forced convection sodium loop. The oxygen content of sodium was controlled by the cold-trapping method to achieve {approx}1 wppm oxygen level. Four alloys were examined, G92 in the normalized and tempered condition (H1 G92), G92 in the cold-rolled condition (H2 G92), G91 in the normalized and tempered condition, and hot-rolled HT-UPS. G91 was included as a reference to compare with advanced alloy, G92. It was found that all four alloys showed weight loss after sodium exposures at 550 and 650 C. The weight loss of the four alloys was comparable after sodium exposures at 550 C; the weight loss of ferritic-martensitic steels, G92 and G91 is more significant than that of austenitic stainless steel, HT-UPS after sodium exposures at 650 C. Sodium exposures up to 2700 h at 550 C had no significant influence on tensile properties, while sodium exposures up to 5064 h at 650 C dramatically lowered the tensile strengths of the four alloys. The ultimate tensile strength of H1 G92, H2 G92, and G91 ferritic-martensitic steels was reduced to as much as nearly half of its initial value after sodium exposures at 650 C. Though the uniform elongation was recovered to some extent, these three ferritic-martensitic steels showed considerable strain softening after sodium exposures. The yield stress of HT-UPS austenitic stainless steel increased, the ultimate tensile strength decreased, and the total elongation was reduced after sodium exposures at 650 C. The dynamic strain aging effect observed in the as-received HT-UPS specimens became less pronounced after sodium exposures at 650 C. Microstructural characterization of sodium-exposed specimens showed no appreciable surface deterioration or grain structure changes under an optical microscope, except for the H2 G92 steel, in which the martensite structure transformed to large grain ferrite after sodium exposures at 650 C. TEM observations of the sodium-exposed H2 G92 steel showed significant recrystallization after sodium exposure for 2700 h at 550 C, and transformation of martensite to ferrite and high density of precipitates in nearly dislocation-free matrix after sodium exposures at 650 C. Further microstructural analysis and evaluation of decarburization/carburization behavior is needed to understand the dramatic changes in the tensile strengths of advanced ferritic-martensitic and austenitic steels after sodium exposures at 650 C.

Li, M.; Natesan, K.; Momozaki, Y.; Rink, D.L.; Soppet, W.K.; Listwan, J.T. (Nuclear Engineering Division)

2012-07-09T23:59:59.000Z

150

Super-radiance in the sodium resonance lines from sodium iodide arc lamps  

Science Conference Proceedings (OSTI)

Super-radiance observed within the centers of the sodium resonance D lines emitted by arc lamps containing sodium iodide as additive in a high-pressure mercury plasma environment was studied by high-resolution emission spectroscopy. The spectral radiance of these self-reversed lines including super-radiance was simulated by considering a local enhancement of the source function due to the presence of an additional source of radiation near the arc wall. Causes of this hitherto unrecognized source of radiation are given.

Karabourniotis, D. [Department of Physics, Institute of Plasma Physics, University of Crete, 71003 Heraklion (Greece); Drakakis, E. [Department of Electrical Engineering, Technological Educational Institute, Heraklion (Greece)

2010-08-09T23:59:59.000Z

151

Factors contributing to the breakdown of sodium beta-alumina  

DOE Green Energy (OSTI)

Clarification of the breakdown process occurring during charge transfer in sodium beta alumina solid electrolytes was derived from: (1) studying the effects of molten sodium contact at 350/sup 0/C on single crystal sodium beta alumina and polycrystalline sodium beta alumina; (2) determination of critical current density by monitoring acoustic emissions accompanying crack growth in sodium/sodium beta alumina/sodium cells subjected to linear current ramping at 1 mA cm/sup -2/ sec/sup -1/; (3) failure analysis conducted on cycled electrolytes, some from commercial sodium/sulfur cells, which had been subjected to up to 703 Ahr cm/sup -2/ of charge transfer. Gray coloration developing in beta aluminas in contact with molten sodium was found to be a consequence of formation, through reduction by sodium, of oxygen vacancies charge compensated by electrons. Electronic conductivity of the electrolyte increases as a result. No second phase formation was detected. Colored electrolytes from sodium/sulfur cells show evidence of a newly recognized degradation mechanism in which fracture occurs when sodium is reduced and deposited internally under pressure as metal in regions where an electronic conductivity gradient exists. Heating colored beta aluminas in air produces reoxidation and bleaching. Kinetics and other properties of the coloration and bleaching processes were determined. Critical current density was found to bear an inverse relation to average electrolyte grain size. Evidence was found in the cycled electrolytes for a slow crack growth mechanism and a progressive mode of degradation advancing from the sulfur electrode interface. Implications of the findings for the construction and operation of sodium/sulfur battery systems are discussed.

Buechele, A.C.

1982-05-01T23:59:59.000Z

152

XAS of uranium(VI) sorbed onto silica, alumina, and montmorillonite  

Science Conference Proceedings (OSTI)

The purpose of this work is to determine the speciation (oxidation state and molecular structure) of uranium sorbed onto surfaces of silica

E. R. Sylwester; P. G. Allen; E. A. Hudson

2000-01-01T23:59:59.000Z

153

Synthesis and new structure shaping mechanism of silica particles formed at high pH  

SciTech Connect

For the sol-gel synthesis of silica particles under high pH catalytic conditions (pH>12) in water/ethanol solvent, we have deduced that the competing dynamics of chemical etching and sol-gel process can explain the types of silica particles formed and their morphologies. We have demonstrated that emulsion droplets that are generated by adding tetraethyl orthosilicate (TEOS) to a water-ethanol solution serve as soft templates for hollow spherical silica (1-2 {mu}m). And if the emulsion is converted by the sol-gel process, one finds that suspended solid silica spheres of diameter of {approx}900 nm are formed. Moreover, several other factors are found to play fundamental roles in determining the final morphologies of silica particles, such as by variation of the pH (in our case, using OH{sup -}) to a level where condensation dominates; by changing the volume ratios of water/ethanol; and using an emulsifier (specifically, CTAB) - Graphical abstract: 'Local chemical etching' and sol-gel process have been proposed to interpret the control of morphologies of silica particles through varying initial pHs in syntheses. Highlights: Black-Right-Pointing-Pointer Different initial pHs in our syntheses provides morphological control of silica particles. Black-Right-Pointing-Pointer 'Local chemical etching' and sol-gel process describes the formation of silica spheres. Black-Right-Pointing-Pointer The formation of emulsions generates hollow silica particles.

Zhang, Henan; Zhao, Yu [Department of Chemistry, The City College of The University of New York, 160 Convent Avenue, New York, NY 10031 (United States)] [Department of Chemistry, The City College of The University of New York, 160 Convent Avenue, New York, NY 10031 (United States); Akins, Daniel L., E-mail: akins@sci.ccny.cuny.edu [Department of Chemistry, The City College of The University of New York, 160 Convent Avenue, New York, NY 10031 (United States)

2012-10-15T23:59:59.000Z

154

Silica Exposure Assessment of Oil And Gas Drilling Workers During Hydraulic Fracking Process.  

E-Print Network (OSTI)

??The problem investigated in this study was that of identifying the silica exposure to the employees of an oil gas company during the fracking process… (more)

Li, Jigang

2011-01-01T23:59:59.000Z

155

Luminescent organosilicon polymers and sol-gel synthesis of nano-structured silica  

E-Print Network (OSTI)

sol-­?gel  synthesis  of  nano-­?structured  silica     by  a   Malvern  Zetasizer  Nano  series  instrument.  Zeta  of   aggregates   of   nano-­?C60.   Aquatic   Toxicol.  

Martinez, H. Paul

2011-01-01T23:59:59.000Z

156

Synthesis of Mesocellular Silica Foams with Tunable Window and Cell Dimensions  

E-Print Network (OSTI)

Polystyrene microspheres coated with cationic surfactants are easily prepared by micro- emulsion templates. These silica foams resemble dense aerogels. Introduction Because of their greatly enhanced pore

Yang, Peidong

157

Silicon Surface Texturing by Electro-Deoxidation of a Thin Silica ...  

Science Conference Proceedings (OSTI)

Presentation Title, Silicon Surface Texturing by Electro-Deoxidation of a Thin Silica Layer in Molten Salt. Author(s), Eimutis Juzeliunas, Antony Cox, Derek Fray

158

Cellular Effect of High Doses of Silica-Coated Quantum Dot ...  

Cellular Effect of High Doses of Silica-Coated Quantum Dot Profiled with High Throughput Gene Expression Analysis and High Content Cellomics ...

159

Fact Sheet: Sodium-Beta Batteries (October 2012)  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Sodium-Beta Batteries Sodium-Beta Batteries Improving the performance and reducing the cost of sodium-beta batteries for large-scale energy storage Sodium-beta batteries (Na-beta batteries or NBBs) use a solid beta-alumina (ß˝-Al 2 O 3 ) electrolyte membrane that selectively allows sodium ion transport between a positive electrode (e.g., a metal halide) and a negative sodium electrode. NBBs typically operate at temperatures near 350˚C. They are increasingly used in renewable storage and utility applications due to their high round-trip efficiency, high energy densities, and energy storage capacities ranging from a few kilowatt-hours to multiple megawatt-hours. In fact, U.S. utilities

160

Sodium/Phosphorus-Sulfur Cells II. Phase Equilibria  

NLE Websites -- All DOE Office Websites (Extended Search)

II. Phase Equilibria II. Phase Equilibria Title Sodium/Phosphorus-Sulfur Cells II. Phase Equilibria Publication Type Journal Article Year of Publication 1996 Authors Ridgway, Paul L., Frank R. McLarnon, and John S. Newman Journal Journal of the Electrochemistry Society Volume 143 Issue 2 Pagination 412-417 Keywords 25 ENERGY STORAGE, 36 MATERIALS SCIENCE, ALUMINIUM OXIDES, equilibrium, performance, PHASE DIAGRAMS, PHOSPHIDES, PHOSPHORUS ADDITIONS, SODIUM COMPOUNDS, SODIUM SULFIDES, SODIUM-SULFUR BATTERIES Abstract Equilibrium open-circuit cell voltage data from a sodium/{beta}{double_prime}-alumina/phosphorus-sulfur cell utilizing P/S ratios of 0, 0.143, and 0.332 and a sodium atom fraction ranging from 0 to 0.4 were interpreted to construct ternary phase diagrams of the Na-P-S ternary system at 350 and 400 C.

Note: This page contains sample records for the topic "na-sg sodium silica" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Review of Chemical Processes for the Synthesis of Sodium Borohydride  

NLE Websites -- All DOE Office Websites (Extended Search)

Review of Chemical Processes for the Synthesis of Sodium Borohydride Review of Chemical Processes for the Synthesis of Sodium Borohydride Millennium Cell Inc. Prepared by Ying Wu Michael T. Kelly Jeffrey V. Ortega Under DOE Cooperative Agreement DE-FC36-04GO14008 August 2004 Table of Contents Introduction..................................................................................................................................... 1 Section 1: Commercially Practiced Sodium Borohydride Synthesis Process ............................... 2 The Brown-Schlesinger Process ................................................................................................. 2 The Bayer Process.......................................................................................................................

162

METHOD FOR REDUCING THE IMPURITY RESISTIVITY OF SODIUM  

DOE Patents (OSTI)

The inherent resistivity of sodium, at cryogenic temperatures, can be reduced by clustering the impurity atoms within the crystal latiice structure of the sodium, thereby reducing the effective electron collision cross section and thus reducing the number of collisions between the electrons and such lattice imperfections. The clustering is effected by heating the sodium to a temperature approaching its melting point, and maintaining the temperature for a period of time ranging generally from two to six days. (AEC)

Post, R.F.; Taylor, C.E.

1963-08-13T23:59:59.000Z

163

Thermal annealing of laser damage precursors on fused silica surfaces  

Science Conference Proceedings (OSTI)

Previous studies have identified two significant precursors of laser damage on fused silica surfaces at fluenes below {approx} 35 J/cm{sup 2}, photoactive impurities in the polishing layer and surface fractures. In the present work, isothermal heating is studied as a means of remediating the highly absorptive, defect structure associated with surface fractures. A series of Vickers indentations were applied to silica surfaces at loads between 0.5N and 10N creating fracture networks between {approx} 10{micro}m and {approx} 50{micro}m in diameter. The indentations were characterized prior to and following thermal annealing under various times and temperature conditions using confocal time-resolved photo-luminescence (CTP) imaging, and R/1 optical damage testing with 3ns, 355nm laser pulses. Significant improvements in the damage thresholds, together with corresponding reductions in CTP intensity, were observed at temperatures well below the glass transition temperature (T{sub g}). For example, the damage threshold on 05.N indentations which typically initiates at fluences 35 J/cm{sup 2} through the use of a {approx} 750 C thermal treatment. Larger fracture networks required longer or higher temperature treatment to achieve similar results. At an annealing temperature > 1100 C, optical microscopy indicates morphological changes in some of the fracture structure of indentations, although remnants of the original fracture and significant deformation was still observed after thermal annealing. This study demonstrates the potential of using isothermal annealing as a means of improving the laser damage resistance of fused silica optical components. Similarly, it provides a means of further understanding the physics associated with optical damage and related mitigation processes.

Shen, N; Miller, P E; Bude, J D; Laurence, T A; Suratwala, T I; Steele, W A; Feit, M D; Wang, L L

2012-03-19T23:59:59.000Z

164

Thermal annealing of laser damage precursors on fused silica surfaces  

SciTech Connect

Previous studies have identified two significant precursors of laser damage on fused silica surfaces at fluenes below {approx} 35 J/cm{sup 2}, photoactive impurities in the polishing layer and surface fractures. In the present work, isothermal heating is studied as a means of remediating the highly absorptive, defect structure associated with surface fractures. A series of Vickers indentations were applied to silica surfaces at loads between 0.5N and 10N creating fracture networks between {approx} 10{micro}m and {approx} 50{micro}m in diameter. The indentations were characterized prior to and following thermal annealing under various times and temperature conditions using confocal time-resolved photo-luminescence (CTP) imaging, and R/1 optical damage testing with 3ns, 355nm laser pulses. Significant improvements in the damage thresholds, together with corresponding reductions in CTP intensity, were observed at temperatures well below the glass transition temperature (T{sub g}). For example, the damage threshold on 05.N indentations which typically initiates at fluences <8 J/cm{sup 2} could be improved >35 J/cm{sup 2} through the use of a {approx} 750 C thermal treatment. Larger fracture networks required longer or higher temperature treatment to achieve similar results. At an annealing temperature > 1100 C, optical microscopy indicates morphological changes in some of the fracture structure of indentations, although remnants of the original fracture and significant deformation was still observed after thermal annealing. This study demonstrates the potential of using isothermal annealing as a means of improving the laser damage resistance of fused silica optical components. Similarly, it provides a means of further understanding the physics associated with optical damage and related mitigation processes.

Shen, N; Miller, P E; Bude, J D; Laurence, T A; Suratwala, T I; Steele, W A; Feit, M D; Wang, L L

2012-03-19T23:59:59.000Z

165

PROCESSING OF SODIUM--POTASSIUM NIOBATE CERAMICS.  

SciTech Connect

Sintering studies of undoped (Na{sub 0.5}K{sub 0.5})NbO{sub 3} and the same material doped with 1/2, 1, 2, and 4 mole percent BaO and 2 mole % B{sub 2}O{sub 3} were made. The persistence of a second phase after calcining to form the compound led to a study of reactions occurring during calcination. The calcining of sodium-potassium niobates involves the formation of an intermediate compound (the second phase) and its subsequent reaction with sodium oxide and potassium oxide to form (Na{sub 0.5}K{sub 0.5})NbO{sub 3}. Sintering data show that up to 1/2 mole % BaO added to the system increases the initial densification. However, the sintered bodies then exhibit densification and form sharp cubic grains and large voids. Indications are that a liquid phase is the major contributor to densification of this system through the mechanism of particle rearrangement, and that the contribution of any sintering mechanism to densification is negligible.

Powell, B.R. Jr.

1971-01-01T23:59:59.000Z

166

Sodium tetraphenylborate solubility and dissolution rates  

DOE Green Energy (OSTI)

The rate of solid sodium tetraphenylborate (NaTPB) dissolution in In-Tank Precipitation salt solutions has been experimentally determined. The data indicates that the dissolution rate of solid NaTPB is a minor contributor the lag time experienced in the 1983 Salt Decontamination Demonstration Test and should not be considered as the rate determining step. Current analytical models for predicting the time to reach the composite lower flammability limit assume that the lag time is not more than 6 hours, and the data supports this assumption (i.e., dissolution by itself requires much less than 6 hours). The data suggests that another step--such as mass transport, the reaction of a benzene precursor or the mixing behavior--is the rate determining factor for benzene release to the vapor space in Tank 48H. In addition, preliminary results from this program show that the degree of agitation employed is not a significant parameter in determining the rate of NaTPB dissolution. As a result of this study, an improved equation for predicting equilibrium tetraphenylborate solubility with respect to temperature and sodium ion concentration has been determined.

Barnes, M.J.; Peterson, R.A.; Swingle, R.F.; Reeves, C.T.

1995-12-31T23:59:59.000Z

167

Sodium Reactor Experiment decommissioning. Final report  

Science Conference Proceedings (OSTI)

The Sodium Reactor Experiment (SRE) located at the Rockwell International Field Laboratories northwest of Los Angeles was developed to demonstrate a sodium-cooled, graphite-moderated reactor for civilian use. The reactor reached full power in May 1958 and provided 37 GWh to the Southern California Edison Company grid before it was shut down in 1967. Decommissioning of the SRE began in 1974 with the objective of removing all significant radioactivity from the site and releasing the facility for unrestricted use. Planning documentation was prepared to describe in detail the equipment and techniques development and the decommissioning work scope. A plasma-arc manipulator was developed for remotely dissecting the highly radioactive reactor vessels. Other important developments included techniques for using explosives to cut reactor vessel internal piping, clamps, and brackets; decontaminating porous concrete surfaces; and disposing of massive equipment and structures. The documentation defined the decommissioning in an SRE dismantling plan, in activity requirements for elements of the decommissioning work scope, and in detailed procedures for each major task.

Carroll, J.W.; Conners, C.C.; Harris, J.M.; Marzec, J.M.; Ureda, B.F.

1983-08-15T23:59:59.000Z

168

Optical and radiographical characterization of silica aerogel for Cherenkov radiator  

E-Print Network (OSTI)

We present optical and X-ray radiographical characterization of silica aerogels with refractive index from 1.05 to 1.07 for a Cherenkov radiator. A novel pin-drying method enables us to produce highly transparent hydrophobic aerogels with high refractive index by shrinking wet-gels. In order to investigate the uniformity in the density (i.e., refractive index) of an individual aerogel monolith, we use the laser Fraunhofer method, an X-ray absorption technique, and Cherenkov imaging by a ring imaging Cherenkov detector in a beam test. We observed an increase in density at the edge of the aerogel tiles, produced by pin-drying.

Tabata, Makoto; Hatakeyama, Yoshikiyo; Kawai, Hideyuki; Morita, Takeshi; Nishikawa, Keiko

2012-01-01T23:59:59.000Z

169

Measurement of Radiation Damage on Silica Aerogel \\v Cerenkov Radiator  

E-Print Network (OSTI)

We measured the radiation damage on silica aerogel \\v Cerenkov radiators originally developed for the $B$-factory experiment at KEK. Refractive index of the aerogel samples ranged from 1.012 to 1.028. The samples were irradiated up to 9.8~MRad of equivalent dose. Measurements of transmittance and refractive index were carried out and these samples were found to be radiation hard. Deteriorations in transparency and changes of refractive index were observed to be less than 1.3\\% and 0.001 at 90\\% confidence level, respectively. Prospects of using aerogels under high-radiation environment are discussed.

S. K. Sahu et al

1996-04-11T23:59:59.000Z

170

Sodium Bearing Waste Treatment Project ? Countdown to Startup  

NLE Websites -- All DOE Office Websites (Extended Search)

Date: March 19, 2012 Media Contact: Natalie Packer, 208-533-0253 Sodium Bearing Waste Treatment Project Countdown to Startup Marking completion of another major...

171

Energy absorber for sodium-heated heat exchanger  

DOE Patents (OSTI)

A heat exchanger is described in which water-carrying tubes are heated by liquid sodium and in which the results of accidental contact between the water and the sodium caused by failure of one or more of the water tubes is minimized. An energy absorbing chamber contains a compressible gas and is connected to the body of flowing sodium by a channel so that, in the event of a sodium-water reaction, products of the reaction will partially fill the energy absorbing chamber to attenuate the rise in pressure within the heat exchanger.

Essebaggers, J.

1975-12-01T23:59:59.000Z

172

Battery Electrode Materials Based on Layered Sodium Titanates  

Berkeley Lab researcher Marca Doeff and colleagues have developed a new electrode material based on a layered sodium titanate compound that can be ...

173

Interaction of sodium vapor and graphite studied by ...  

Science Conference Proceedings (OSTI)

The kinetics of the reaction between graphite and sodium vapor is analyzed with support ... High temperature compression test to determine the anode paste ...

174

Low Temperature Sodium-Sulfur Grid Storage and EV Battery  

Berkeley Lab researcher Gao Liu has developed an innovative design for a battery, made primarily of sodium and sulfur, that holds promise for both ...

175

Low Temperature Sodium-Sulfur Grid Storage and EV Battery ...  

Berkeley Lab researcher Gao Liu has developed an innovative design for a battery, made primarily of sodium and sulfur, that holds promise for both large-scale grid ...

176

NASICON-Type Electrolytes for Low Temperature Sodium Battery ...  

Science Conference Proceedings (OSTI)

Presentation Title, NASICON-Type Electrolytes for Low Temperature Sodium Battery Applications. Author(s), Hui Zhang, Xingbo Liu. On-Site Speaker ( Planned) ...

177

ESS 2012 Peer Review - Sodium Intercalation Battery for Stationary...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

LLC 35 Hartwell Avenue Lexington, MA 02421-3102 www.TIAXLLC.com Sodium Intercalation Battery for Stationary Storage Energy Storage Systems Program (ESS) Peer Review and Update...

178

Sodium cobalt bronze batteries and a method for making same  

SciTech Connect

A solid state secondary battery utilizing a low cost, environmentally sound, sodium cobalt bronze electrode. A method is provided for producing same.

Doeff, Marca M. (Hayward, CA); Ma, Yanping (Berkeley, CA); Visco, Steven J. (Berkeley, CA); DeJonghe, Lutgard (Lafayette, CA)

1999-01-01T23:59:59.000Z

179

Reductive Sulfur-fixation Smelting of Stibnite Concentrate in Sodium ...  

Science Conference Proceedings (OSTI)

Abstract Scope, A new process to extracted antimony directly from stibnite concentrate by reductive sulfur-fixation smelting in sodium molten salt has been ...

180

Influence of Petroleum Coke Sulphur Content on the Sodium ... - TMS  

Science Conference Proceedings (OSTI)

Feb 1, 1993 ... Influence of Petroleum Coke Sulphur Content on the Sodium Sensitivity of Carbon Anodes by S.M. Hume ... TMS Student Member price: 0.00.

Note: This page contains sample records for the topic "na-sg sodium silica" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Sodium cobalt bronze batteries and a method for making same  

DOE Patents (OSTI)

A solid state secondary battery utilizing a low cost, environmentally sound, sodium cobalt bronze electrode is described. A method is provided for producing same. 11 figs.

Doeff, M.M.; Ma, Y.; Visco, S.J.; DeJonghe, L.

1999-06-29T23:59:59.000Z

182

Planar Sodium Metal Halide Battery for Renewable Integration and ...  

Science Conference Proceedings (OSTI)

In this work we will present a sodium ߔ-alumina cell designed for widespread renewable energy integration and electrical grid applications. The new generation ...

183

Sodium fast reactor safety and licensing research plan. Volume II.  

SciTech Connect

Expert panels comprised of subject matter experts identified at the U.S. National Laboratories (SNL, ANL, INL, ORNL, LBL, and BNL), universities (University of Wisconsin and Ohio State University), international agencies (IRSN, CEA, JAEA, KAERI, and JRC-IE) and private consultation companies (Radiation Effects Consulting) were assembled to perform a gap analysis for sodium fast reactor licensing. Expert-opinion elicitation was performed to qualitatively assess the current state of sodium fast reactor technologies. Five independent gap analyses were performed resulting in the following topical reports: (1) Accident Initiators and Sequences (i.e., Initiators/Sequences Technology Gap Analysis), (2) Sodium Technology Phenomena (i.e., Advanced Burner Reactor Sodium Technology Gap Analysis), (3) Fuels and Materials (i.e., Sodium Fast Reactor Fuels and Materials: Research Needs), (4) Source Term Characterization (i.e., Advanced Sodium Fast Reactor Accident Source Terms: Research Needs), and (5) Computer Codes and Models (i.e., Sodium Fast Reactor Gaps Analysis of Computer Codes and Models for Accident Analysis and Reactor Safety). Volume II of the Sodium Research Plan consolidates the five gap analysis reports produced by each expert panel, wherein the importance of the identified phenomena and necessities of further experimental research and code development were addressed. The findings from these five reports comprised the basis for the analysis in Sodium Fast Reactor Research Plan Volume I.

Ludewig, H. (Brokhaven National Laboratory, Upton, NY); Powers, D. A.; Hewson, John C.; LaChance, Jeffrey L.; Wright, A. (Argonne National Laboratory, Argonne, IL); Phillips, J.; Zeyen, R. (Institute for Energy Petten, Saint-Paul-lez-Durance, France); Clement, B. (IRSN/DPAM.SEMIC Bt 702, Saint-Paul-lez-Durance, France); Garner, Frank (Radiation Effects Consulting, Richland, WA); Walters, Leon (Advanced Reactor Concepts, Los Alamos, NM); Wright, Steve; Ott, Larry J. (Oak Ridge National Laboratory, Oak Ridge, TN); Suo-Anttila, Ahti Jorma; Denning, Richard (Ohio State University, Columbus, OH); Ohshima, Hiroyuki (Japan Atomic Energy Agency, Ibaraki, Japan); Ohno, S. (Japan Atomic Energy Agency, Ibaraki, Japan); Miyhara, S. (Japan Atomic Energy Agency, Ibaraki, Japan); Yacout, Abdellatif (Argonne National Laboratory, Argonne, IL); Farmer, M. (Argonne National Laboratory, Argonne, IL); Wade, D. (Argonne National Laboratory, Argonne, IL); Grandy, C. (Argonne National Laboratory, Argonne, IL); Schmidt, R.; Cahalen, J. (Argonne National Laboratory, Argonne, IL); Olivier, Tara Jean; Budnitz, R. (Lawrence Berkeley National Laboratory, Berkeley, CA); Tobita, Yoshiharu (Japan Atomic Energy Agency, Ibaraki, Japan); Serre, Frederic (Centre d'%C3%94etudes nucl%C3%94eaires de Cadarache, Cea, France); Natesan, Ken (Argonne National Laboratory, Argonne, IL); Carbajo, Juan J. (Oak Ridge National Laboratory, Oak Ridge, TN); Jeong, Hae-Yong (Korea Atomic Energy Research Institute, Daejeon, Korea); Wigeland, Roald (Idaho National Laboratory, Idaho Falls, ID); Corradini, Michael (University of Wisconsin-Madison, Madison, WI); Thomas, Justin (Argonne National Laboratory, Argonne, IL); Wei, Tom (Argonne National Laboratory, Argonne, IL); Sofu, Tanju (Argonne National Laboratory, Argonne, IL); Flanagan, George F. (Oak Ridge National Laboratory, Oak Ridge, TN); Bari, R. (Brokhaven National Laboratory, Upton, NY); Porter D. (Idaho National Laboratory, Idaho Falls, ID); Lambert, J. (Argonne National Laboratory, Argonne, IL); Hayes, S. (Idaho National Laboratory, Idaho Falls, ID); Sackett, J. (Idaho National Laboratory, Idaho Falls, ID); Denman, Matthew R.

2012-05-01T23:59:59.000Z

184

Preparation of silica aerogels with improved mechanical properties and extremely low thermal conductivities through modified sol-gel process  

E-Print Network (OSTI)

Reported silica aerogels have a thermal conductivity as low as 15 mW/mK. The fragility of silica aerogels, however, makes them impractical for structural applications. The purpose of the study is to improve the ductility ...

Zuo, Yanjia

2010-01-01T23:59:59.000Z

185

Synthesis of silica nanoparticles by sol-gel: size-dependent properties, surface modification, and applications in silica-polymer nanocomposites — a review  

Science Conference Proceedings (OSTI)

Application of silica nanoparticles as fillers in the preparation of nanocomposite of polymers has drawnmuch attention, due to the increased demand for new materials with improved thermal, mechanical, physical, and chemical properties. Recent developments ...

Ismail Ab Rahman; Vejayakumaran Padavettan

2012-01-01T23:59:59.000Z

186

Environmental, health, and safety issues of sodium-sulfur batteries for electric and hybrid vehicles. Volume 3, Transport of sodium-sulfur and sodium-metal-chloride batteries  

DOE Green Energy (OSTI)

This report examines the shipping regulations that govern the shipment of dangerous goods. Since the elemental sodium contained in both sodium-sulfur and sodium-metal-chloride batteries is classified as a dangerous good, and is listed on both the national and international hazardous materials listings, both national and international regulatory processes are considered in this report The interrelationships as well as the differences between the two processes are highlighted. It is important to note that the transport regulatory processes examined in this report are reviewed within the context of assessing the necessary steps needed to provide for the domestic and international transport of sodium-beta batteries. The need for such an assessment was determined by the Shipping Sub-Working Group (SSWG) of the EV Battery Readiness Working Group (Working Group), created in 1990. The Working Group was created to examine the regulatory issues pertaining to in-vehicle safety, shipping, and recycling of sodium-sulfur batteries, each of which is addressed by a sub-working group. The mission of the SSWG is to establish basic provisions that will ensure the safe and efficient transport of sodium-beta batteries. To support that end, a proposal to the UN Committee of Experts was prepared by the SSWG, with the goal of obtaining a proper shipping name and UN number for sodium-beta batteries and to establish the basic transport requirements for such batteries (see the appendix for the proposal as submitted). It is emphasized that because batteries are large articles containing elemental sodium and, in some cases, sulfur, there is no existing UN entry under which they can be classified and for which modal transport requirements, such as the use of packaging appropriate for such large articles, are provided for. It is for this reason that a specific UN entry for sodium-beta batteries is considered essential.

Hammel, C.J.

1992-09-01T23:59:59.000Z

187

Electrochromic nanocomposite of silica/polyaniline prepared from a water-in-oil microemulsion solution  

Science Conference Proceedings (OSTI)

A composite nanoparticle of silica/polyaniline was synthesized from a microemulsion and it was tested as an electrochromic film. The compositions for the stable microemulsion system was selected as 65.4 wt% cyclohexane, 30.4 wt% surfactant and 4.2 wt% ... Keywords: electrochromic, inorganic-organic hybrid, nanoparticle, operation life time, polyaniline, silica

Taejin Hwang; Heung Yeol Lee; Hohyeong Kim; Gyuntak Kim

2010-11-01T23:59:59.000Z

188

Young's modulus evaluation by SAWs for porous silica low-k film with cesium doping  

Science Conference Proceedings (OSTI)

Young's moduli of porous silica low-k films with cesium (Cs) doping are determined by surface acoustic waves (SAWs) in this study. Four low-k samples doped with 0-30ppmwt% Cs in the precursor solution are investigated to check the mechanical promotion ... Keywords: Cesium doping, Low-k film, Porous silica, Surface acoustic waves, Young's modulus

X. Xiao; X. M. Shan; Y. Kayaba; K. Kohmura; H. Tanaka; T. Kikkawa

2011-05-01T23:59:59.000Z

189

Mechanism of silica precipitation by lowering pH in chemi-thermomechanical pulping black liquors  

Science Conference Proceedings (OSTI)

Black liquor is a complex colloidal system obtained by chemical pulping process. It comprises of lignin, nearly 50% of the total organic and Silica approx. 2-3% (OD basis) of the total inorganic components. Black liquor is fed to chemical recovery plant ... Keywords: black liquors, desilication and concentrators, lignin, silica

Muhammad Ikram Aujla; Ishtiaq-Ur-Rehman Ishtiaq-Ur-Rehman; Asad Javaid

2007-12-01T23:59:59.000Z

190

Sodium waste technology: A summary report. [Melt-drain-evaporation-calcination (MEDEC)  

SciTech Connect

The Sodium Waste Technology (SWT) Program was established to resolve long-standing issues regarding disposal of sodium-bearing waste and equipment. Comprehensive SWT research programs investigated a variety of approaches for either removing sodium from sodium-bearing items, or disposal of items containing sodium residuals. The most successful of these programs was the design, test, and the production operation of the Sodium Process Demonstration Facility at ANL-W. The technology used was a series of melt-drain-evaporate operations to remove nonradioactive sodium from sodium-bearing items and then converting the sodium to storable compounds.

Abrams, C.S.; Witbeck, L.C.

1987-01-01T23:59:59.000Z

191

Terahertz Time-Domain Spectroscopy Study of Silica Aerogels and Adsorbed Molecular Jiangquan Zhang and D. Grischkowsky*  

E-Print Network (OSTI)

Terahertz Time-Domain Spectroscopy Study of Silica Aerogels and Adsorbed Molecular Vapors Jiangquan time-domain spectroscopy (THz-TDS) study of hydrophobic and hydrophilic silica aerogels, and the adsorption of several molecular vapors in the hydrophilic silica aerogel. The hydrophobic and hydrophilic

Oklahoma State University

192

It's Elemental - Isotopes of the Element Sodium  

NLE Websites -- All DOE Office Websites (Extended Search)

Neon Neon Previous Element (Neon) The Periodic Table of Elements Next Element (Magnesium) Magnesium Isotopes of the Element Sodium [Click for Main Data] Most of the isotope data on this site has been obtained from the National Nuclear Data Center. Please visit their site for more information. Naturally Occurring Isotopes Mass Number Natural Abundance Half-life 23 100% STABLE Known Isotopes Mass Number Half-life Decay Mode Branching Percentage 18 1.3×10-21 seconds Proton Emission 100.00% 19 < 40 nanoseconds Proton Emission No Data Available 20 447.9 milliseconds Electron Capture with delayed Alpha Decay 20.05% Electron Capture 100.00% 21 22.49 seconds Electron Capture 100.00% 22 2.6027 years Electron Capture 100.00% 23 STABLE - - 24 14.997 hours Beta-minus Decay 100.00%

193

Low temperature sodium-beta battery  

SciTech Connect

A battery that will operate at ambient temperature or lower includes an enclosure, a current collector within the enclosure, an anode that will operate at ambient temperature or lower within the enclosure, a cathode that will operate at ambient temperature or lower within the enclosure, and a separator and electrolyte within the enclosure between the anode and the cathode. The anode is a sodium eutectic anode that will operate at ambient temperature or lower and is made of a material that is in a liquid state at ambient temperature or lower. The cathode is a low melting ion liquid cathode that will operate at ambient temperature or lower and is made of a material that is in a liquid state at ambient temperature or lower.

Farmer, Joseph C

2013-11-19T23:59:59.000Z

194

Update; Sodium advanced fast reactor (SAFR) concept  

SciTech Connect

This paper reports on the sodium advanced fast reactor (SAFR) concept developed by the team of Rockwell International, Combustion Engineering, and Bechtel during the 3-year period extending from January 1985 to December 1987 as one element in the U.S. Department of Energy's Advanced Liquid Metal Reactor Program. In January 1988, the team was expanded to include Duke Engineering and Services, Inc., and the concept development was extended under DOE's Program for Improvement in Advanced Modular LMR Design. The SAFR plant concept employs a 450-MWe pool-type liquid metal cooled reactor as its basic module. The reactor assembly module is a standardized shop-fabricated unit that can be shipped to the plant site by barge for installation. Shop fabrication minimizes nuclear-grade field fabrication and reduces the plant construction schedule. Reactor modules can be used individually or in multiples at a given site to supply the needed generating capacity.

Oldenkamp, R.D.; Brunings, J.E. (Rockwell International Corp., Canoga Park, CA (USA)); Guenther, E. (Combustion Engineering, Windsor, CT (US)); Hren, R. (Bechtel National Inc., San Francisco, CA (US))

1988-01-01T23:59:59.000Z

195

FUEL PROGRAMMING FOR SODIUM GRAPHITE REACTORS  

SciTech Connect

The effect of fuel programming, i.e., the scheme used for changing fuel in a core, on the reactivity and specific power of a sodium graphite reactor is discussed Fuel programs considered Include replacing fuel a core-load at a time or a radial zone at a time, replacing fuel to manutain the same average exposure of fuel elements throughout the core, and replacing and transferring fuel elements to maintain more highly exposed fuel in the center or at the periphery of the core. Flux and criticality calculations show the degree of power flattening and the concurrent decrease in effective multiplication which results from maintaining more exposed fuel toward the core center. Corverse effects are shown for the case of maintaining more exposed fuel near the core periphery. The excess reactivity which must be controlled in the various programs is considered. Illustrative schedules for implementing each of these programs in an SGR are presented. (auth)

Connolly, T.J.

1959-10-15T23:59:59.000Z

196

Method of removing bulk sodium from metallic surfaces  

DOE Patents (OSTI)

A process of removing sodium from an article, particularly one made of stainless steel, by treating it with a mixture of water vapor and a gas which is inert to sodium is described. By selecting combinations of temperature and water vapor-to-gas ratio, the reaction temperature is controlled to prevent damage to the articles.

Maffei, H.P.; Borisch, R.R.

1975-11-11T23:59:59.000Z

197

Fluorescent single walled nanotube/silica composite materials  

DOE Patents (OSTI)

Fluorescent composites of surfactant-wrapped single-walled carbon nanotubes (SWNTs) were prepared by exposing suspensions of surfactant-wrapped carbon nanotubes to tetramethylorthosilicate (TMOS) vapor. Sodium deoxycholate (DOC) and sodium dodecylsulphate (SDS) were the surfactants. No loss in emission intensity was observed when the suspension of DOC-wrapped SWNTs were exposed to the TMOS vapors, but about a 50% decrease in the emission signal was observed from the SDS-wrapped SWNTs nanotubes. The decrease in emission was minimal by buffering the SDS/SWNT suspension prior to forming the composite. Fluorescent xerogels were prepared by adding glycerol to the SWNT suspensions prior to TMOS vapor exposure, followed by drying the gels. Fluorescent aerogels were prepared by replacing water in the gels with methanol and then exposing them to supercritical fluid drying conditions. The aerogels can be used for gas sensing.

Dattelbaum, Andrew M.; Gupta, Gautam; Duque, Juan G.; Doorn, Stephen K.; Hamilton, Christopher E.; DeFriend Obrey, Kimberly A.

2013-03-12T23:59:59.000Z

198

Independent Oversight Assessment, Idaho Cleanup Project Sodium Bearing  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Idaho Cleanup Project Sodium Idaho Cleanup Project Sodium Bearing Waste Treatment Project - November 2012 Independent Oversight Assessment, Idaho Cleanup Project Sodium Bearing Waste Treatment Project - November 2012 November 2012 Assessment of Nuclear Safety Culture at the Idaho Cleanup Project Sodium Bearing Waste Treatment Project The U.S. Department of Energy (DOE) Office of Enforcement and Oversight (Independent Oversight), within the Office of Health, Safety and Security (HSS), conducted an independent assessment of nuclear safety culture at the DOE Sodium Bearing Waste Treatment Project (SBWTP). The primary objective of the evaluation was to provide information regarding the status of the safety culture at SBWTP. The data collection phase of the assessment occurred in April and May 2012. SBWTP is one of DOE's largest nuclear

199

Independent Oversight Review, Sodium Bearing Waste Treatment Project -  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Sodium Bearing Waste Treatment Sodium Bearing Waste Treatment Project - Federal - June 2012 Independent Oversight Review, Sodium Bearing Waste Treatment Project - Federal - June 2012 June 2012 Review of the Sodium Bearing Waste Treatment Project - Integrated Waste Treatment Unit Federal Operational Readiness Review This report documents the U.S. Department of Energy (DOE) Office of Enforcement and Oversight (Independent Oversight), within the Office of Health, Safety and Security (HSS), independent review of the Sodium Bearing Waste Treatment Project-Integrated Waste Treatment Unit (SBWTP-IWTU) DOE (Federal) Operational Readiness Review (D-ORR). The review was performed by the HSS Office of Safety and Emergency Management Evaluations and was intended to assess the effectiveness of the CORR process as implemented for

200

EIS-0287: Notice of Preferred Sodium Bearing Waste Treatment Technology |  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Preferred Sodium Bearing Waste Treatment Preferred Sodium Bearing Waste Treatment Technology EIS-0287: Notice of Preferred Sodium Bearing Waste Treatment Technology Idaho High-Level Waste (HLW) and Facilities Disposition In October 2002, the U.S. Department of Energy (DOE or the Department) issued the Final Idaho High-Level Waste (HLW) and Facilities Disposition Environmental Impact Statement (DOE/EIS-0287 (Final EIS)). The Final EIS contains an evaluation of reasonable alternatives for the management of mixed transuranic waste/sodium bearing waste (SBW),1 mixed HLW calcine, and associated low-level waste (LLW), as well as disposition alternatives for HLW facilities when their missions are completed. DOE/EIS-0287, Notice of Preferred Sodium Bearing Waste Treatment Technology, Office of Environmental Management, Idaho, 70 FR 44598 (August

Note: This page contains sample records for the topic "na-sg sodium silica" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Independent Oversight Review, Sodium Bearing Waste Treatment Project -  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Sodium Bearing Waste Treatment Sodium Bearing Waste Treatment Project - Contractor - June 2012 Independent Oversight Review, Sodium Bearing Waste Treatment Project - Contractor - June 2012 June 2012 Review of the Sodium Bearing Waste Treatment Project - Integrated Waste Treatment Unit Contractor Operational Readiness Review This report documents the U.S. Department of Energy (DOE) Office of Enforcement and Oversight (Independent Oversight), within the Office of Health, Safety and Security (HSS), independent review of the Sodium Bearing Waste Treatment Project-Integrated Waste Treatment Unit (SBWTP-IWTU) contractor Operational Readiness Review (C-ORR). The review was conducted at the Idaho Site from February 27 to March 6, 2012. This report discusses the background, scope, results, and conclusions of the review, as well as

202

Solid-state sodium batteries using polymer electrolytes and sodium intercalation electrode materials  

DOE Green Energy (OSTI)

Solid-state sodium cells using polymer electrolytes (polyethylene oxide mixed with sodium trifluoromethanesulfonate: PEO{sub n}NaCF{sub 3}SO{sub 3}) and sodium cobalt oxide positive electrodes are characterized in terms of discharge and charge characteristics, rate capability, cycle life, and energy and power densities. The P2 phase Na{sub x}CoO{sub 2} can reversibly intercalate sodium in the range of x = 0.3 to 0.9, giving a theoretical specific energy of 440 Wh/kg and energy density of 1,600 Wh/l. Over one hundred cycles to 60% depth of discharge have been obtained at 0.5 mA/cm{sup 2}. Experiments show that the electrolyte/Na interface is stable and is not the limiting factor to cell cycle life. Na{sub 0.7}CoO{sub 2} composite electrodes containing various amounts of carbon black additive are investigated. The transport properties of polymer electrolytes are the critical factors for performance. These properties (the ionic conductivity, salt diffusion coefficient, and ion transference number) are measured for the PEO{sub n}NaCF{sub 3}SO{sub 3} system over a wide range of concentrations at 85 C. All the three transport properties are very salt-concentration dependent. The ionic conductivity exhibits a maximum at about n = 20. The transference number, diffusion coefficient, and thermodynamic factor all vary with salt concentration in a similar fashion, decreasing as the concentration increases, except for a local maximum. These results verify that polymer electrolytes cannot be treated as ideal solutions. The measured transport-property values are used to analyze and optimize the electrolytes by computer simulation and also cell testing. Salt precipitation is believed to be the rate limiting process for cells using highly concentrated solutions, as a result of lower values of these properties, while salt depletion is the limiting factor when a dilute solution is used.

Ma, Y. [Univ. of California, Berkeley, CA (United States). Dept. of Materials Science and Mineral Engineering]|[Lawrence Berkeley National Lab., CA (United States). Materials Sciences Div.

1996-08-01T23:59:59.000Z

203

Decommissioning of Experimental Breeder Reactor - II Complex, Post Sodium Draining  

Science Conference Proceedings (OSTI)

The Experimental Breeder Reactor - II (EBR-II) was shutdown in September 1994 as mandated by the United States Department of Energy. This sodium-cooled reactor had been in service since 1964. The bulk sodium was drained from the primary and secondary systems and processed. Residual sodium remaining in the systems after draining was converted into sodium bicarbonate using humid carbon dioxide. This technique was tested at Argonne National Laboratory in Illinois under controlled conditions, then demonstrated on a larger scale by treating residual sodium within the EBR-II secondary cooling system, followed by the primary tank. This process, terminated in 2002, was used to place a layer of sodium bicarbonate over all exposed surfaces of sodium. Treatment of the remaining EBR-II sodium is governed by the Resource Conservation and Recovery Act (RCRA). The Idaho Department of Environmental Quality issued a RCRA Operating Permit in 2002, mandating that all hazardous materials be removed from EBR-II within a 10 year period, with the ability to extend the permit and treatment period for another 10 years. A preliminary plan has been formulated to remove the remaining sodium and NaK from the primary and secondary systems using moist carbon dioxide, steam and nitrogen, and a water flush. The moist carbon dioxide treatment was resumed in May 2004. As of August 2005, approximately 60% of the residual sodium within the EBR-II primary tank had been treated. This process will continue through the end of 2005, when it is forecast that the process will become increasingly ineffective. At that time, subsequent treatment processes will be planned and initiated. It should be noted that the processes and anticipated costs associated with these processes are preliminary. Detailed engineering has not been performed, and approval for these methods has not been obtained from the regulator or the sponsors.

J. A. (Bart) Michelbacher; S. Paul Henslee; Collin J. Knight; Steven R. sherman

2005-09-01T23:59:59.000Z

204

Ion Recognition Approach to Volume Reduction of Alkaline Tank Waste by Separation and Recycle of Sodium Hydroxide and Sodium Nitrate  

SciTech Connect

This research was intended to provide the scientific foundation upon which the feasibility of liquid-liquid extraction chemistry for bulk reduction of the volume of high-activity tank waste can be evaluated. Primary focus has been on sodium hydroxide separation, with potential Hanford application. Value in sodium hydroxide separation can potentially be found in alternative flowsheets for treatment and disposal of low-activity salt waste. Additional value can be expected in recycle of sodium hydroxide for use in waste retrieval and sludge washing, whereupon additions of fresh sodium hydroxide to the waste can be avoided. Potential savings are large both because of the huge cost of vitrification of the low-activity waste stream and because volume reduction of high-activity wastes could obviate construction of costly new tanks. Toward these ends, the conceptual development begun in the original proposal was extended with the formulation of eight fundamental approaches that could be undertaken for extraction of sodium hydroxide.

Bruce A. Moyer; Alan P. Marchand; Peter V. Bonnesen; Jeffrey C. Bryan; Tamara J. Haverlock

2004-06-08T23:59:59.000Z

205

Encapsulated in silica: genome, proteome and physiology of the thermophilic bacterium Anoxybacillus flavithermus  

SciTech Connect

Gram-positive bacteria of the genus Anoxybacillus have been found in diverse thermophilic habitats, such as geothermal hot springs and manure, and in processed foods such as gelatin and milk powder. Anoxybacillus flavithermus is a facultatively anaerobic bacterium found in super-saturated silica solutions and in opaline silica sinter. The ability of A. flavithermus to grow in super-saturated silica solutions makes it an ideal subject to study the processes of sinter formation, which might be similar to the biomineralization processes that occurred at the dawn of life. We report here the complete genome sequence of A. flavithermus strain WK1, isolated from the waste water drain at the Wairakei geothermal power station in New Zealand. It consists of a single chromosome of 2,846,746 base pairs and is predicted to encode 2,863 proteins. In silico genome analysis identified several enzymes that could be involved in silica adaptation and biofilm formation, and their predicted functions were experimentally validated in vitro. Proteomic analysis confirmed the regulation of biofilm-related proteins and crucial enzymes for the synthesis of long-chain polyamines as constituents of silica nanospheres. Microbial fossils preserved in silica and silica sinters are excellent objects for studying ancient life, a new paleobiological frontier. An integrated analysis of the A. flavithermus genome and proteome provides the first glimpse of metabolic adaptation during silicification and sinter formation. Comparative genome analysis suggests an extensive gene loss in the Anoxybacillus/Geobacillus branch after its divergence from other bacilli.

Saw, Jimmy H [Los Alamos National Laboratory; Mountain, Bruce W [NEW ZEALAND; Feng, Lu [NANKAI UNIV; Omelchenko, Marina V [NCBI/NLM/NIH; Hou, Shaobin [UNIV OF HAWAII; Saito, Jennifer A [UNIV OF HAWAII; Stott, Matthew B [NEW ZEALAND; Li, Dan [NANKAI UNIV; Zhao, Guang [NANKAI UNIV; Wu, Junli [NANKAI UNIV; Galperin, Michael Y [NCBI/NLM/NIH; Koonin, Eugene V [NCBI/NLM/NIH; Makarova, Kira S [NCBI/NLM/NIH; Wolf, Yuri I [NCBI/NLM/NIH; Rigden, Daniel J [UNIV OF LIVERPOOL; Dunfield, Peter F [UNIV OF CALGARY; Wang, Lei [NANKAI UNIV; Alam, Maqsudul [UNIV OF HAWAII

2008-01-01T23:59:59.000Z

206

Problems of Silica Scaling at Cerro Prieto Geothrmal Power Station  

DOE Green Energy (OSTI)

In the Cerro Prieto Geothermal field, where the predominant fluid in the reservoir is water, they have had problems with silica and other deposits in the first exploration wells as well as in production wells. Scaling problems have also been encountered in silencers, cyclone separators, drains, water pipes, etc. Some scale problems have also been encountered in the turbine blades of the geothermal electric plant. Most of these problems have been solved by corrective procedures which, in some cases, have turned into routine. Scale deposition is a problem that certainly diminishes the useful capacity of geothermal fluids with water predominance, but it does not actually endanger the installations, since this problem is under control.

Mercado, S.; Guiza, J.

1976-01-01T23:59:59.000Z

207

Hydrogen and oxygen adsorption stoichiometries on silica supported ruthenium nanoparticles  

DOE Green Energy (OSTI)

Treatment under H{sub 2} at 300 C of Ru(COD)(COT) dispersed on silica yields 2 nm ruthenium nanoparticles, [Ru{sub p}/SiO{sub 2}], according to EXAFS, HRTEM and XPS. H{sub 2} adsorption measurements on [Ru{sub p}/SiO{sub 2}] in the absence of O{sub 2} show that Ru particles adsorb up to ca. 2 H per surface ruthenium atoms (2H/Ru{sub s}) on various samples; this technique can therefore be used to measure the dispersion of Ru particles. In contrast, O{sub 2} adsorption on [Ru{sub p}/SiO{sub 2}] leads to a partial oxidation of the bulk at 25 C, to RuO{sub 2} at 200 C and to sintering upon further reduction under H{sub 2}, showing that O{sub 2} adsorption cannot be used to measure the dispersion of Ru particles.

Berthoud, Romain; Delichere, Pierre; Gajan, David; Lukens, Wayne; Pelzer, Katrin; Basset, Jean-Marie; Candy, Jean-Pierre; Coperet, Christophe

2008-12-01T23:59:59.000Z

208

Performance predictions of silica-gel desiccant dehumidifiers  

DOE Green Energy (OSTI)

The analysis of a cross-cooled desiccant dehumidifier using silica gel in the form of sheets is described. This unit is the principal component of solar powered desiccant air conditioning system. The mathematical model has first been formulated describing the dynamics of the dehumidifier. The model leads to a system of nonlinear coupled heat and mass transfer equations for the sorption processes and linear heat transfer equations for the purging processes. The model accounts for the gas film resistance and for the moisture diffusion in the desiccant. The governing equations are solved by a finite difference scheme to obtain periodic steady state solutions. The accuracy of the theoretical predictions is ascertained by comparing them with the experimental results. The performance of the dehumidifier, for a chosen set of initial conditions and dehumidifier parameters, has also been given.

Mathiprakasam, B.; Lavan, Z.

1980-01-01T23:59:59.000Z

209

Preparation of silica or alumina pillared crystalline titanates  

Science Conference Proceedings (OSTI)

Layered crystalline titanates (CT) [Anthony and Dosch, US Patent 5 177 045 (1993)] are pillared with tetraethyl orthosilicate, 3-aminopropyltrimethoxysilane, and aluminum acetylacetonate to prepare porous and high surface area supports for sulfided NiMo catalyst. Tetra-ethyl orthosilicate or aluminum acetylacetonate intercalated CT are prepared by stepwise intercalation. First, the basal distance is increased by n-alkylammonium ions prior to intercalation with inorganic compounds. However, an aqueous solution of 3-aminopropyltrimethoxysilane could directly pillar CT without first swelling the titanate with n-alkylamine. The catalytic activities for hydrogenation of pyrene of sulfided NiMo supported silica or alumina pillared CT were higher than those of commercial catalysts (Shell324 and Amocat1C). The silicon and aluminum contents of the pillared CT, used as supports, have a considerable effect on the catalytic activities and physical properties of the supports.

Udomsak, S.; Nge, R.; Dufner, D.C.; Anthony, R.G. [Texas A and M Univ., College Station, TX (United States); Lott, S.E. [Sandia National Labs., Albuquerque, NM (United States)

1994-05-01T23:59:59.000Z

210

Experimental investigations on sodium plugging in narrow flow channels.  

SciTech Connect

A series of experiments was performed to investigate the potential for plugging of narrow flow channels of sodium by impurities (e.g., oxides). In the first phase of the experiments, clean sodium was circulated through the test sections simulating flow channels in a compact diffusion-bonded heat exchanger such as a printed circuit heat exchanger. The primary objective was to see if small channels whose cross sections are semicircles of 2, 4, and 6 mm in diameter are usable in liquid sodium applications where sodium purity is carefully controlled. It was concluded that the 2-mm channels, the smallest of the three, could be used in clean sodium systems at temperatures even as low as 100 to 110 C without plugging. In the second phase, sodium oxide was added to the loop, and the oxygen concentration in the liquid sodium was controlled by means of varying the cold-trap temperature. Intentional plugging was induced by creating a cold spot in the test sections, and the subsequent plugging behavior was observed. It was found that plugging in the 2-mm test section was initiated by lowering the cold spot temperature below the cold-trap temperature by 10 to 30 C. Unplugging of the plugged channels was accomplished by heating the affected test section.

Momozaki, Y.; Cho, D. H.; Sienicki, J. J.; Moisseytsev, A.; Nuclear Engineering Division

2010-08-01T23:59:59.000Z

211

Determination of silica deposition rates and thresholds applied towards protection of injection reservoirs  

SciTech Connect

This program was instituted to quantify certain aspects of silica scaling deposition processes at the Miravalles Geothermal Field, Costa Rica. The program objective was to identify the highest temperature at which silica scale will develop from partially evaporated and significantly cooled geothermal liquid under operating conditions. Integral to the study objective was the quantification of certain aspects of silica deposition processes at the Miravalles Geothermal Field, Costa Rica. There, the objective was to reduce the scaling risk associated with adding a bottoming-cycle to generate more electricity from the liquids already being produced.

Geothermal Development Associates; Don Michels Associates

1999-07-01T23:59:59.000Z

212

Molecular dynamics study of sodium using a model pseudopotential  

Science Conference Proceedings (OSTI)

The dynamics of sodium is investigated using the coulomb and Born-Mayer interaction augmented by a model pseudopotential to represent the electron interactions including screening, exchange, and correlation. The model parameters were previously determined and have been shown to accurately reproduce experimental equation-of-state, lattice vibration, and crystal phase properties of sodium in the harmonic limit. In this paper the equation-of-state and structural properties are examined in molecular dynamics calculations. The long range effects of the potential are included. Typically, each particle interacts with about 500 neighbors. The calculated equation of state of sodium in the hcp, bcc, and liquid structures is discussed.

Swanson, R.E.; Straub, G.K.; Holian, B.L.

1981-01-01T23:59:59.000Z

213

Sodium Bearing Waste Processing Alternatives Analysis  

SciTech Connect

A multidisciplinary team gathered to develop a BBWI recommendation to DOE-ID on the processing alternatives for the sodium bearing waste in the INTEC Tank Farm. Numerous alternatives were analyzed using a rigorous, systematic approach. The data gathered were evaluated through internal and external peer reviews for consistency and validity. Three alternatives were identified to be top performers: Risk-based Calcination, MACT to WIPP Calcination and Cesium Ion Exchange. A dual-path through early Conceptual design is recommended for MACT to WIPP Calcination and Cesium Ion Exchange since Risk-based Calcination does not require design. If calcination alternatives are not considered based on giving Type of Processing criteria significantly greater weight, the CsIX/TRUEX alternative follows CsIX in ranking. However, since CsIX/TRUEX shares common uncertainties with CsIX, reasonable backups, which follow in ranking, are the TRUEX and UNEX alternatives. Key uncertainties must be evaluated by the decision-makers to choose one final alternative. Those key uncertainties and a path forward for the technology roadmapping of these alternatives is provided.

Murphy, James Anthony; Palmer, Brent J; Perry, Keith Joseph

2003-12-01T23:59:59.000Z

214

Structure and Aqueous Solubility of Sodium Isosaccharinate  

SciTech Connect

It has been recently shown that isosaccharinic acid, C6H12O6 (ISA), and its derivative salts have a great potential for practical application in the area of nuclear waste treatment and disposal sites management. Several studies demonstrated the effect of ISA complexation on radionuclide solubility and sorptive properties, especially on actinides in (+4) oxidation state like Np(IV) and Th(IV). The presence of ISA and/or its derivatives strongly affects the migration of radionuclides by increasing their solubility in water by several orders of magnitude and Na-ISA has been proposed as a component of decontamination formulations for actinide-contaminated surfaces. Here we report the synthesis, crystal's structure and characterization (FTIR, TGA) of sodium isosaccharate, NaC6H11O6-H2O (Na-ISA). The structure has been solved by single crystal X-ray diffraction methods. The solubility of Na-ISA has been evaluated and compared to that of Ca-ISA based on the structural features of both compounds.

Bontchev, Ranko P.; Moore, Robert; Tucker, Mark; Holt, Kathleen

2004-03-29T23:59:59.000Z

215

NMR monitoring of intracellular sodium in dog and rabbit kidney tubules  

SciTech Connect

{sup 23}Na-nuclear magnetic resonance (NMR) was used to monitor intra- and extracellular sodium in suspensions of dog cortical tubules, rabbit cortical tubules, and dog thick ascending limbs. The NMR visibility of the intracellular sodium was determined by comparing the NMR and flame photometry results and by redistributing the sodium ions between the intra- and extracellular compartments using the ionophore nystatin (influx) or sodium substitution for choline in the extracellular fluid (efflux). The intracellular sodium visibility was {approximately}30% for the total sodium and 58% for the transportable sodium. Addition of sodium to sodium-depleted homogenates of dog renal cortex also showed a loss of visibility. The values of the relaxation times T{sub 1} and T{sub 2} were determined but could not be correlated with the visibility measurements. The intracellular sodium concentration in dog cortical tubules incubated in optimal biochemical conditions was estimated at 51 mM was dependent on the extracellular sodium concentration.

Boulanger, Y.; Vinay, P.; Boulanger, M. (Universite de Montreal, Quebec (Canada))

1987-11-01T23:59:59.000Z

216

Method for inhibiting silica precipitation and scaling in geothermal flow systems  

DOE Patents (OSTI)

A method for inhibiting silica scaling and precipitation in geothermal flow systems by on-line injection of low concentrations of cationic nitrogen-containing compounds, particularly polymeric imines, polymeric amines, and quaternary ammonium compounds.

Harrar, Jackson E. (Castro Valley, CA); Lorensen, Lyman E. (Orinda, CA); Locke, Frank E. (Lafayette, CA)

1982-01-01T23:59:59.000Z

217

Method for inhibiting silica precipitation and scaling in geothermal flow systems  

DOE Patents (OSTI)

A method for inhibiting silica scaling and precipitation in geothermal flow systems by on-line injection of low concentrations of cationic nitrogen-containing compounds, particularly polymeric imines, polymeric amines, and quaternary ammonium compounds is described.

Harrar, J.E.; Lorensen, L.E.; Locke, F.E.

1980-06-13T23:59:59.000Z

218

Luminescence properties of mesoporous silica nanoparticles encapsulating different europium complexes: application for biolabelling  

Science Conference Proceedings (OSTI)

In this work we have synthesized and characterized new hybrid nanoplatforms for luminescent biolabeling based on the concept of Eu3+ complexes encapsulation in mesoporous silica nanoparticles (?100 nm). Eu complexes have been selected ...

S. Lechevallier, J. Jorge, R. M. Silveira, N. Ratel-Ramond, D. Neumeyer, M. J. Menu, M. Gressier, A. L. Marçal, A. L. Rocha, M. A. U. Martines, E. Magdeleine, J. Dexpert-Ghys, M. Verelst

2013-01-01T23:59:59.000Z

219

Mesoporous silica SBA-16 functionalized with alkoxysilane groups: preparation, characterization, and release profile study  

Science Conference Proceedings (OSTI)

A mesoporous material sphere based on silica, SBA-16, was chemically modified with alkoxysilane using two different solvents: methanol and toluene. The influence of the chemical modification of the matrix on the release rate of a model drug was also ...

Gracielle Ferreira Andrade; Daniel Cristian Ferreira Soares; Ramon Kenned de Sousa Almeida; Edésia Martins Barros Sousa

2012-01-01T23:59:59.000Z

220

ADVANCED ONCE-THROUGH STEAM GENERATOR FOR SODIUM APPLICATION  

SciTech Connect

Preliminary design calculations were performed for a once-through type steam generator and reheater for advanced sodium power plants in the 300-Mwe range. Parameters and performance data are presented. (D.L.C.)

Terpe, G.R.

1960-09-19T23:59:59.000Z

Note: This page contains sample records for the topic "na-sg sodium silica" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Internal structure, hygroscopic and reactive properties of mixed sodium  

NLE Websites -- All DOE Office Websites (Extended Search)

Internal structure, hygroscopic and Internal structure, hygroscopic and reactive properties of mixed sodium methanesulfonate-sodium chloride particles Internal structure, hygroscopic and reactive properties of mixed sodium methanesulfonate-sodium chloride particles Print Friday, 13 May 2011 00:00 Scientists recently combined experimental approaches and molecular dynamics modeling to gain new insights into the internal structure of sea salt particles and relate it to their fundamental chemical reactivity in the atmosphere. This research shows that surface enhancement or depletion of chemical components in marine particles can occur because of the difference in the chemical nature of the species. Because the atmospheric chemistry of the salt particles takes place at the gas-particle interface, understanding their complex surfaces provides new insights about their effect on the environment and climate change. Article Link.

222

Probabilistic transient analysis of fuel choices for sodium fast reactors  

E-Print Network (OSTI)

This thesis presents the implications of using a risk-informed licensing framework to inform the design of Sodium Fast Reactors. NUREG-1860, more commonly known as the Technology Neutral Framework (TNF), is a risk-informed ...

Denman, Matthew R

2011-01-01T23:59:59.000Z

223

United States, France and Japan Increase Cooperation on Sodium...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

on Sodium-Cooled Fast Reactor Prototypes February 1, 2008 - 11:13am Addthis WASHINGTON, DC -The U.S Department of Energy (DOE), the French Atomic Energy Commission (CEA) and...

224

Probabilistic transient analysis of fuel choices for sodium fast reactors.  

E-Print Network (OSTI)

??This thesis presents the implications of using a risk-informed licensing framework to inform the design of Sodium Fast Reactors. NUREG-1860, more commonly known as the… (more)

Denman, Matthew R

2011-01-01T23:59:59.000Z

225

Reactor protection system design alternatives for sodium fast reactors  

E-Print Network (OSTI)

Historically, unprotected transients have been viewed as design basis events that can significantly challenge sodium-cooled fast reactors. The perceived potential consequences of a severe unprotected transient in a ...

DeWitte, Jacob D. (Jacob Dominic)

2011-01-01T23:59:59.000Z

226

Loop simulation capability for sodium-cooled systems  

E-Print Network (OSTI)

A one-dimensional loop simulation capability has been implemented in the thermal-hydraulic analysis code, THERMIT-4E. This code had been used to simulate and investigate flow in test sections of experimental sodium loops ...

Adekugbe, Oluwole A.

1984-01-01T23:59:59.000Z

227

ESS 2012 Peer Review - Sodium-based Battery Development - Dave...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Nuclear Security Administration under contract DE-AC04-94AL85000. Sodium-based Battery Development A Family of Batteries for Large Scale Energy Storage D. Ingersoll, C....

228

Wall pressure exerted by hydrogenation of sodium aluminum hydride.  

DOE Green Energy (OSTI)

Wall pressure exerted by the bulk expansion of a sodium aluminum hydride bed was measured as a function of hydrogen content. A custom apparatus was designed and loaded with sodium alanates at densities of 1.0, 1.1, and 1.16 g/cc. Four complete cycles were performed to identify variations in measured pressure. Results indicated poor correlation between exerted pressure and hydrogen capacity of the sodium alanate beds. Mechanical pressure due to the hydrogenation of sodium alanates does not influence full-scale system designs as it falls within common design factors of safety. Gas pressure gradients within the porous solid were identified and may limit reaction rates, especially for high aspect ratio beds.

Perras, Yon E.; Dedrick, Daniel E.; Zimmerman, Mark D.

2009-06-01T23:59:59.000Z

229

SODIUM-HEATED STEAM GENERATOR DEVELOPMENT. Interim Status Report  

SciTech Connect

Design and development of a once -through sodiumheated steam generator are discussed. Research proposals are discussed for evaluating: carbon transfer and mass transfer effects in the steam generator, effect on heat transfer and two- phase flow of coiling tubes, corrosion of Croloy 21/4 in products of sodium-water reactions, procedure for welding tube to back side of the tube sheet, radiographic inspection of back side tube welds, and chemical simulation of sodium environment for leak testing. (N.W.R.)

1964-01-22T23:59:59.000Z

230

High temperature sodium testing of the CRBR prototype primary pump  

Science Conference Proceedings (OSTI)

Qualification testing in sodium of the CRBR primary pump was conducted through 1982. This paper presents an overview of the test program, a description of the Sodium Pump Test Facility (largest of its kind in the world), a brief description of the test article and summary overview of results. Of special interest were the high temperature gas convection tests and the extensive flow/speed control (dynamic) tests. Special innovative test methods were employed to investigate these phenomena.

Tessier, M.J.; Grimaldi, J.L.

1983-01-01T23:59:59.000Z

231

Alignment and operability analysis of a vertical sodium pump  

SciTech Connect

With the objective of identifying important alignment features of pumps such as FFTF, HALLAM, EBR II, PNC, PHENIX, and CRBR, alignment of the vertical sodium pump for the Clinch River Breeder Reactor Plant (CRBRP) is investigated. The CRBRP pump includes a flexibly coupled pump shaft and motor shaft, two oil-film tilting-pad hydrodynamic radial bearings in the motor plus a vertical thrust bearing, and two sodium hydrostatic bearings straddling the double-suction centrifugal impeller in the pump.

Gupta, V.K.; Fair, C.E.

1981-01-01T23:59:59.000Z

232

Synthesis of SiC ceramics by the carbothermal reduction of mineralized wood with silica  

DOE Green Energy (OSTI)

This paper describes the synthesis of SiC by the carbothermal reduction of mineralized wood with silica in acidic condition. The biomorphic cellular SiC ceramics were prepared by controlling the amount of silica and the size of SiC nanoparticles. Up to 20wt% of SiO2 was mineralized into wood cellular structures and the hierarchical structures such as cells, lumen, and pits were mainly retained after the thermal treatment at 1400 C.

Shin, Yongsoon; Wang, Chong M.; Exarhos, Gregory J.

2005-01-06T23:59:59.000Z

233

Assessment of Methods to Consolidate Iodine-Loaded Silver-Functionalized Silica Aerogel  

SciTech Connect

The U.S. Department of Energy is currently investigating alternative sorbents for the removal and immobilization of radioiodine from the gas streams in a nuclear fuel reprocessing plant. One of these new sorbents, Ag0-functionalized silica aerogels, shows great promise as a potential replacement for Ag-bearing mordenites because of its high selectivity and sorption capacity for iodine. Moreover, a feasible consolidation of iodine-loaded Ag0-functionalized silica aerogels to a durable SiO2-based waste form makes this aerogel an attractive choice for sequestering radioiodine. This report provides a preliminary assessment of the methods that can be used to consolidate iodine-loaded Ag0-functionalized silica aerogels into a final waste form. In particular, it focuses on experimental investigation of densification of as prepared Ag0-functionalized silica aerogels powders, with or without organic moiety and with or without sintering additive (colloidal silica), with three commercially available techniques: 1) hot uniaxial pressing (HUP), 2) hot isostatic pressing (HIP), and 3) spark plasma sintering (SPS). The densified products were evaluated with helium gas pycnometer for apparent density, with the Archimedes method for apparent density and open porosity, and with high-resolution scanning electron microscopy and energy dispersive spectroscopy (SEM-EDS) for the extent of densification and distribution of individual elements. The preliminary investigation of HUP, HIP, and SPS showed that these sintering methods can effectively consolidate powders of Ag0-functionalized silica aerogel into products of near-theoretical density. Also, removal of organic moiety and adding 5.6 mass% of colloidal silica to Ag0-functionalized silica aerogel powders before processing provided denser products. Furthermore, the ram travel data for SPS indicated that rapid consolidation of powders can be performed at temperatures below 950°C.

Matyas, Josef; Engler, Robert K.

2013-09-01T23:59:59.000Z

234

Hydrogen storage in sodium aluminum hydride.  

DOE Green Energy (OSTI)

Sodium aluminum hydride, NaAlH{sub 4}, has been studied for use as a hydrogen storage material. The effect of Ti, as a few mol. % dopant in the system to increase kinetics of hydrogen sorption, is studied with respect to changes in lattice structure of the crystal. No Ti substitution is found in the crystal lattice. Electronic structure calculations indicate that the NaAlH{sub 4} and Na{sub 3}AlH{sub 6} structures are complex-ionic hydrides with Na{sup +} cations and AlH{sub 4}{sup -} and AlH{sub 6}{sup 3-} anions, respectively. Compound formation studies indicate the primary Ti-compound formed when doping the material at 33 at. % is TiAl{sub 3} , and likely Ti-Al compounds at lower doping rates. A general study of sorption kinetics of NaAlH{sub 4}, when doped with a variety of Ti-halide compounds, indicates a uniform response with the kinetics similar for all dopants. NMR multiple quantum studies of solution-doped samples indicate solvent interaction with the doped alanate. Raman spectroscopy was used to study the lattice dynamics of NaAlH{sub 4}, and illustrated the molecular ionic nature of the lattice as a separation of vibrational modes between the AlH{sub 4}{sup -} anion-modes and lattice-modes. In-situ Raman measurements indicate a stable AlH{sub 4}{sup -} anion that is stable at the melting temperature of NaAlH{sub 4}, indicating that Ti-dopants must affect the Al-H bond strength.

Ozolins, Vidvuds; Herberg, J.L. (Lawrence Livermore National Laboratories, Livermore, CA); McCarty, Kevin F.; Maxwell, Robert S. (Lawrence Livermore National Laboratories, Livermore, CA); Stumpf, Roland Rudolph; Majzoub, Eric H.

2005-11-01T23:59:59.000Z

235

Advanced sodium fast reactor accident source terms : research needs.  

Science Conference Proceedings (OSTI)

An expert opinion elicitation has been used to evaluate phenomena that could affect releases of radionuclides during accidents at sodium-cooled fast reactors. The intent was to identify research needed to develop a mechanistic model of radionuclide release for licensing and risk assessment purposes. Experts from the USA, France, the European Union, and Japan identified phenomena that could affect the release of radionuclides under hypothesized accident conditions. They qualitatively evaluated the importance of these phenomena and the need for additional experimental research. The experts identified seven phenomena that are of high importance and have a high need for additional experimental research: High temperature release of radionuclides from fuel during an energetic eventEnergetic interactions between molten reactor fuel and sodium coolant and associated transfer of radionuclides from the fuel to the coolantEntrainment of fuel and sodium bond material during the depressurization of a fuel rod with breached claddingRates of radionuclide leaching from fuel by liquid sodiumSurface enrichment of sodium pools by dissolved and suspended radionuclidesThermal decomposition of sodium iodide in the containment atmosphereReactions of iodine species in the containment to form volatile organic iodides. Other issues of high importance were identified that might merit further research as development of the mechanistic model of radionuclide release progressed.

Powers, Dana Auburn; Clement, Bernard [IRSN/DPAM.SEMIC Bt 702, Saint-Paul-lez-Durance, France] IRSN/DPAM.SEMIC Bt 702, Saint-Paul-lez-Durance, France; Denning, Richard [Ohio State University, Columbus, OH] Ohio State University, Columbus, OH; Ohno, Shuji [Japan Atomic Energy Agency, Ibaraki, Japan] Japan Atomic Energy Agency, Ibaraki, Japan; Zeyen, Roland [Institute for Energy Petten, Saint-Paul-lez-Durance, France] Institute for Energy Petten, Saint-Paul-lez-Durance, France

2010-09-01T23:59:59.000Z

236

Advanced sodium fast reactor accident source terms : research needs.  

SciTech Connect

An expert opinion elicitation has been used to evaluate phenomena that could affect releases of radionuclides during accidents at sodium-cooled fast reactors. The intent was to identify research needed to develop a mechanistic model of radionuclide release for licensing and risk assessment purposes. Experts from the USA, France, the European Union, and Japan identified phenomena that could affect the release of radionuclides under hypothesized accident conditions. They qualitatively evaluated the importance of these phenomena and the need for additional experimental research. The experts identified seven phenomena that are of high importance and have a high need for additional experimental research: High temperature release of radionuclides from fuel during an energetic eventEnergetic interactions between molten reactor fuel and sodium coolant and associated transfer of radionuclides from the fuel to the coolantEntrainment of fuel and sodium bond material during the depressurization of a fuel rod with breached claddingRates of radionuclide leaching from fuel by liquid sodiumSurface enrichment of sodium pools by dissolved and suspended radionuclidesThermal decomposition of sodium iodide in the containment atmosphereReactions of iodine species in the containment to form volatile organic iodides. Other issues of high importance were identified that might merit further research as development of the mechanistic model of radionuclide release progressed.

Powers, Dana Auburn; Clement, Bernard [IRSN/DPAM.SEMIC Bt 702, Saint-Paul-lez-Durance, France] IRSN/DPAM.SEMIC Bt 702, Saint-Paul-lez-Durance, France; Denning, Richard [Ohio State University, Columbus, OH] Ohio State University, Columbus, OH; Ohno, Shuji [Japan Atomic Energy Agency, Ibaraki, Japan] Japan Atomic Energy Agency, Ibaraki, Japan; Zeyen, Roland [Institute for Energy Petten, Saint-Paul-lez-Durance, France] Institute for Energy Petten, Saint-Paul-lez-Durance, France

2010-09-01T23:59:59.000Z

237

Independent Oversight Assessment, Idaho Cleanup Project Sodium Bearing Waste Treatment Project- November 2012  

Energy.gov (U.S. Department of Energy (DOE))

Assessment of Nuclear Safety Culture at the Idaho Cleanup Project Sodium Bearing Waste Treatment Project

238

Method of and apparatus for removing silicon from a high temperature sodium coolant  

DOE Patents (OSTI)

A method of and system for removing silicon from a high temperature liquid sodium coolant system for a nuclear reactor. The sodium is cooled to a temperature below the silicon saturation temperature and retained at such reduced temperature while inducing high turbulence into the sodium flow for promoting precipitation of silicon compounds and ultimate separation of silicon compound particles from the liquid sodium.

Yunker, Wayne H. (Richland, WA); Christiansen, David W. (Kennewick, WA)

1987-01-01T23:59:59.000Z

239

Fast Flux Test Facility, Sodium Storage Facility project-specific project management plan  

SciTech Connect

This Project-Specific Project Management Plan describes the project management methods and controls used by the WHC Projects Department to manage Project 03-F-031. The Sodium Storage Facility provides for storage of the 260,000 gallons of sodium presently in the FFTF Plant. The facility will accept the molten sodium transferred from the FFTF sodium systems, and store the sodium in a solid state under an inert cover gas until such time as a Sodium Reaction Facility is available for final disposal of the sodium.

Shank, D.R.

1994-12-29T23:59:59.000Z

240

Dispersion Morphology of Poly(methyl acrylate)/Silica Nanocomposites  

SciTech Connect

Nearly monodisperse poly(methyl acrylate) (PMA) and spherical SiO{sub 2} nanoparticles (NP, d = 14 {+-} 4 nm) were co-cast from 2-butanone, a mutually good solvent and a displacer of adsorbed PMA from silica. The effects of NP content and post-casting sample history on the dispersion morphology were found by small-angle X-ray scattering supplemented by transmission electron microscopy. Analysis of the X-ray results show that cast and thermally annealed samples exhibited a nearly random particle dispersion. That the same samples, prior to annealing, were not well-dispersed is indicative of thermodynamic miscibility during thermal annealing over the range of NP loadings studied. A simple mean-field thermodynamic model suggests that miscibility results primarily from favorable polymer segment/NP surface interactions. The model also indicates, and experiments confirm, that subsequent exposure of the composites to the likely displacer ethyl acetate results in entropic destabilization and demixing into NP-rich and NP-lean phases.

D Janes; J Moll; S Harton; C Durning

2011-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "na-sg sodium silica" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Assistant template and co-template agents in modeling mesoporous silicas and post-synthesizing organofunctionalizations  

SciTech Connect

Mesoporous SBA-16 silicas were synthesized through a direct methodology using the template (F127) combined with co-templates (ethanol and n-butanol), with tetraethylorthosilicate as the silica source. These ordered mesoporous silica were characterized by elemental analyses, infrared spectroscopy, solid-state nuclear magnetic resonance for {sup 13}C (CP/MAS) and {sup 29}Si (HP/DEC) nuclei, nitrogen sorption/desorption processes, small angle X-ray analyses (SAXS) and transmission electron microscopy (TEM). SAXS and TEM results confirmed the space group Im3m and cubic 3D symmetry, typical for highly ordered SBA-16. The sorption/desorption data for SBA-16 and when functionalized gave type IV isotherms, with hysteresis loop H2. Surface areas of 836; 657 and 618 m{sup 2} g{sup -1} and average pore diameters of 7.99; 8.10 and 9.85 nm, for SBA-16A, SBA-16B and SBA-16C were obtained, respectively. When functionalized the silicas presented a reduction in surface area, pore volume and pore diameter due to the pendant chains that interfere with nitrogen sorption in these measurements. The co-template ethanol favors the ordered mesopores with highest wall thicknesses. - Graphical Abstract: The mesoporous SBA-16 can be synthesized from binary (F127/TEOS) or ternary (F127/alcohol/TEOs) systems to give well-ordered mesoporous silicas. The co-templates ethanol or butanol gave the final material with highest wall thickness, mainly with ethanol. After these syntheses the pores were successfully organofunctionalized to give a good incorporation of the silylating agents. The final silicas presented of well-arranged solid characteristics as expressing by three distinct peaks, as indexed by the corresponding planes. Highlights: Black-Right-Pointing-Pointer Syntheses of mesoporous silicas by using ternary (F127/agent/TEOS) and binary (F127/TEOS) systems. Black-Right-Pointing-Pointer Use of co-templates to synthesize mesoporous silicas with larger wall thicknesses. Black-Right-Pointing-Pointer Immobilization of pendant chains inside the porous silicas. Black-Right-Pointing-Pointer Ordered mesoposous silicas as new materials for possible applications on sorption and delivering drug systems.

Oliveira, Vaeudo V. [Institute of Chemistry, University of Campinas, UNICAMP, PO Box 6154, 13084-971 Campinas, SP (Brazil)] [Institute of Chemistry, University of Campinas, UNICAMP, PO Box 6154, 13084-971 Campinas, SP (Brazil); Airoldi, Claudio, E-mail: airoldi@iqm.unicamp.br [Institute of Chemistry, University of Campinas, UNICAMP, PO Box 6154, 13084-971 Campinas, SP (Brazil)] [Institute of Chemistry, University of Campinas, UNICAMP, PO Box 6154, 13084-971 Campinas, SP (Brazil)

2012-12-15T23:59:59.000Z

242

Silica precipitation and scaling in a dynamic loop system. [Design and testing of titanium corrosion test loop  

DOE Green Energy (OSTI)

A titanium corrosion test loop was modified to provide a dynamic facility for studying the formation of silica precipitates and scale from simulated geothermal brines as a function of composition, temperature, and flow conditions. A schematic of the modified loop system is presented. The principal components and connecting piping are all constructed of commercially pure titanium. These components include a centrifugal pump, silica saturator column, segmented heat exchanger, reheat heat exchanger, and a high pressure feed pump (stainless steel). The system is designed to circulate simulated geothermal brines saturated with silica to approximately 300/sup 0/C for study of silica scaling. Data obtained from a test run are included. (JGB)

Bohlmann, E.G.; Shor, A.J.; Berlinski, P.

1977-01-01T23:59:59.000Z

243

Thin film nanoporous silica and graphene based biofuel cells (iBFCs) for low-power implantable medical device applications.  

E-Print Network (OSTI)

??This thesis describes the fabrication and characterization of an inorganic catalyst based glucose Biofuel cell using nanoporous (mesoporous) silica thin-film as a functional membrane. The… (more)

Sharma, Tushar

2011-01-01T23:59:59.000Z

244

Generation IV International Forum Signs Agreement to Collaborate on Sodium  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Forum Signs Agreement to Collaborate on Forum Signs Agreement to Collaborate on Sodium Cooled Fast Reactors Generation IV International Forum Signs Agreement to Collaborate on Sodium Cooled Fast Reactors February 17, 2006 - 11:58am Addthis FUKUI , JAPAN - The Department of Energy today announced that the United States signed a sodium-cooled fast reactor systems arrangement with France and Japan, providing the framework for collaboration among these countries on the research and development of these advanced nuclear reactors. The signing of the agreement took place on February 16, 2006. This arrangement will support the development of technologies associated with the U.S.-led Global Nuclear Energy Partnership (GNEP), announced earlier this month by Secretary of Energy Samuel W. Bodman. GNEP is a

245

Independent Oversight Review, Sodium Bearing Waste Treatment Project -  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Federal - June 2012 Federal - June 2012 Independent Oversight Review, Sodium Bearing Waste Treatment Project - Federal - June 2012 June 2012 Review of the Sodium Bearing Waste Treatment Project - Integrated Waste Treatment Unit Federal Operational Readiness Review This report documents the U.S. Department of Energy (DOE) Office of Enforcement and Oversight (Independent Oversight), within the Office of Health, Safety and Security (HSS), independent review of the Sodium Bearing Waste Treatment Project-Integrated Waste Treatment Unit (SBWTP-IWTU) DOE (Federal) Operational Readiness Review (D-ORR). The review was performed by the HSS Office of Safety and Emergency Management Evaluations and was intended to assess the effectiveness of the CORR process as implemented for the SBWTP-IWTU. This review also provides additional data regarding

246

Independent Oversight Review, Sodium Bearing Waste Treatment Project -  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Contractor - June 2012 Contractor - June 2012 Independent Oversight Review, Sodium Bearing Waste Treatment Project - Contractor - June 2012 June 2012 Review of the Sodium Bearing Waste Treatment Project - Integrated Waste Treatment Unit Contractor Operational Readiness Review This report documents the U.S. Department of Energy (DOE) Office of Enforcement and Oversight (Independent Oversight), within the Office of Health, Safety and Security (HSS), independent review of the Sodium Bearing Waste Treatment Project-Integrated Waste Treatment Unit (SBWTP-IWTU) contractor Operational Readiness Review (C-ORR). The review was conducted at the Idaho Site from February 27 to March 6, 2012. This report discusses the background, scope, results, and conclusions of the review, as well as opportunities for improvement (OFIs) and items identified for further

247

Method of forming and starting a sodium sulfur battery  

SciTech Connect

A method of forming a sodium sulfur battery and of starting the reactive capability of that battery when heated to a temperature suitable for battery operation is disclosed. An anodic reaction zone is constructed in a manner that sodium is hermetically sealed therein, part of the hermetic seal including fusible material which closes up openings through the container of the anodic reaction zone. The hermetically sealed anodic reaction zone is assembled under normal atmospheric conditions with a suitable cathodic reaction zone and a cation-permeable barrier. When the entire battery is heated to an operational temperature, the fusible material of the hermetically sealed anodic reaction zone is fused, thereby allowing molten sodium to flow from the anodic reaction zone into reactive engagement with the cation-permeable barrier.

Paquette, David G. (Costa Mesa, CA)

1981-01-01T23:59:59.000Z

248

ESS 2012 Peer Review - Sodium-based Battery Development - Dave Ingersoll, SNL  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Sodium-based Battery Development Sodium-based Battery Development A Family of Batteries for Large Scale Energy Storage D. Ingersoll, C. Apblett, E. Spoerke, K. Zavadil, R. Cygan, J. Ihlefeld, F. Delnick, & T. Anderson Sandia National Laboratories, Albuquerque, NM Prof. E. Wachsman University of Maryland, College Park, MD Profs. R. Kee & J. Porter, Dr. H. Zhu Colorado School of Mines, Golden, CO S. Bhavaraju & M. Robins Ceramatec, Inc, Salt Lake City, UT D. Beeaff CoorsTek, Inc, Golden, CO J. Martin Boulder Ionics, Golden CO US DOE Energy Storage Systems Research Program Peer Review, Washington, DC, Sept. 26-28, 2012 Sodium-based batteries  Purpose  Demonstrate a family of sodium-based battery chemistries  sodium-iodine, sodium-bromine, sodium-air, sodium insertion, sodium-metal, etc

249

Solubility of Gases in Glass. II. He, Ne, and H2 in Fused Silica  

Science Conference Proceedings (OSTI)

The statistical thermodynamics of the gas?in?glass system provides a basic model of both physical and chemical solubility. The physical solubility result is essentially equivalent to that for monatomic solubility. The chemical solubility result is dependent upon the specific system involved. The model was compared with experiment for a variety of systems. Helium and neon in fused silica were examples of the physical solubility of monatomic gases. Variations of the thermal history of the fused silica did not appear to have a measurable effect on physical solubility as evidenced in the helium data. Hydrogen in fused silica was an example of the physical solubility of polyatomic gases. Physical solubility was measured by a modified Seiverts technique and was characterized by a linear dependence on pressure. Binding energies for the physically dissolved species were of the order expected for van der Waals bonding. Vibrational frequencies were on the order of 1013 sec?1 with the heavier species having the lower frequencies. Hydrogen in fused silica was also an example of the chemical solubility of polyatomic gases. The literature gave data for the chemical solution of hydrogen in fused silica

James F. Shackelford; Perry L. Studt; Richard M. Fulrath

1972-01-01T23:59:59.000Z

250

Synthesis of palladium-doped silica nanofibers by sol-gel reaction and electrospinning process  

Science Conference Proceedings (OSTI)

Nanofiber is drawing great attention nowadays with their high surface area per volume and flexibility in surface functionalities that make them favorable as a proton exchange membrane in fuel cell application. In this study, incorporation of palladium nanoparticles in silica nanofibers was prepared by combination of a tetraorthosilane (TEOS) sol-gel reaction with electrospinning process. This method can prevent the nanoparticles from aggregation by direct mixing of palladium nanoparticles in silica sol. The as-produced electrospun fibers were thermally treated to remove poly(vinyl pyrrolidone) (PVP) and condensation of silanol in silica framework. PVP is chosen as fiber shaping agent because of its insulting and capping properties for various metal nanoparticles. Scanning electron microscopy (SEM), energy dispersive spectrometer (EDS) and Fourier transform infrared spectroscopy (FTIR) were used to characterize the silica fibers and Pd nanoparticles on the fibers. Spun fibers with average diameter ranged from 100nm to 400nm were obtained at optimum operating condition and distribution of Pd nanoparticles on silica fibers was investigated.

San, Thiam Hui; Daud, Wan Ramli Wan; Kadhum, Abdul Amir Hassan; Mohamad, Abu Bakar; Kamarudin, Siti Kartom; Shyuan, Loh Kee; Majlan, Edy Herianto [Fuel Cell Institute, Universiti Kebangsaan Malaysia, 43600 UKM Bangi, Selangor (Malaysia); Fuel Cell Institute, Universiti Kebangsaan Malaysia, 43600 UKM Bangi, Selangor, Malaysia and Department of Chemical and Process Engineering, Universiti Kebangsaan Malaysia, 43600 UKM Bangi, Selangor (Malaysia); Fuel Cell Institute, Universiti Kebangsaan Malaysia, 43600 UKM Bangi, Selangor (Malaysia)

2012-06-29T23:59:59.000Z

251

Direct encapsulation of water-soluble drug into silica microcapsules for sustained release applications  

SciTech Connect

Direct encapsulation of water-soluble drug into silica microcapsules was facilely achieved by a sol-gel process of tetraethoxysilane (TEOS) in W/O emulsion with hydrochloric acid (HCl) aqueous solution containing Tween 80 and drug as well as cyclohexane solution containing Span 80. Two water-soluble drugs of gentamicin sulphate (GS) and salbutamol sulphate (SS) were chosen as model drugs. The characterization of drug encapsulated silica microcapsules by scanning electronic microscopy (SEM), FTIR, thermogravimetry (TG) and N{sub 2} adsorption-desorption analyses indicated that drug was successfully entrapped into silica microcapsules. The as-prepared silica microcapsules were uniform spherical particles with hollow structure, good dispersion and a size of 5-10 {mu}m, and had a specific surface area of about 306 m{sup 2}/g. UV-vis and thermogravimetry (TG) analyses were performed to determine the amount of drug encapsulated in the microcapsules. The BJH pore size distribution (PSD) of silica microcapsules before and after removing drug was examined. In vitro release behavior of drug in simulated body fluid (SBF) revealed that such system exhibited excellent sustained release properties.

Wang Jiexin; Wang Zhihui [Key Lab for Nanomaterials, Ministry of Education, Beijing University of Chemical Technology, Beijing 100029 (China); Chen Jianfeng [Key Lab for Nanomaterials, Ministry of Education, Beijing University of Chemical Technology, Beijing 100029 (China); Research Center of the Ministry of Education for High Gravity Engineering and Technology, Beijing University of Chemical Technology, Beijing 100029 (China)], E-mail: chenjf@mail.buct.edu.cn; Yun, Jimmy [Nanomaterials Technology Pte. Ltd., 28 Ayer Rajah Crescent 03-03, Singapore 139959 (Singapore)

2008-12-01T23:59:59.000Z

252

Sodium and lithium corrosion in molybdenum heat pipes  

SciTech Connect

Sodium and lithium corrosin in molybdenum heat pipes has been shown to be impurity dependent rather than solubility dependent. Impurities represent the major contributors to corrosion in the heat pipes tested. Our experiments have shown no evidence of direct solution of molybdenum by either sodium or lithium. Analysis has suggested that a critical concentration of impurities is required to initiate corrosion. Thus it appears that corrosion in Mo/Na and Mo/Li heat pipes can be controlled if impurity concentration can be limited by removal of impurities from the working fluid and heat pipe components prior to operation or by internal gettering during operation.

Lundberg, L.B.; Merrigan, M.A.

1984-01-01T23:59:59.000Z

253

Solid-state laser system for laser cooling of Sodium  

E-Print Network (OSTI)

We demonstrate a frequency-stabilized, all-solid laser source at 589 nm with up to 800 mW output power. The laser relies on sum-frequency generation from two laser sources at 1064 nm and 1319 nm through a PPKTP crystal in a doubly-resonant cavity. We obtain conversion efficiency as high as 2 W/W^2 after optimization of the cavity parameters. The output wavelength is tunable over 60 GHz, which is sufficient to lock on the Sodium D2 line. The robustness, beam quality, spectral narrowness and tunability of our source make it an alternative to dye lasers for atomic physics experiments with Sodium atoms.

Emmanuel Mimoun; Luigi de Sarlo; Jean-Jacques Zondy; Jean Dalibard; Fabrice Gerbier

2009-08-03T23:59:59.000Z

254

Solid-state laser system for laser cooling of Sodium  

E-Print Network (OSTI)

We demonstrate a frequency-stabilized, all-solid laser source at 589 nm with up to 800 mW output power. The laser relies on sum-frequency generation from two laser sources at 1064 nm and 1319 nm through a PPKTP crystal in a doubly-resonant cavity. We obtain conversion efficiency as high as 2 W/W^2 after optimization of the cavity parameters. The output wavelength is tunable over 60 GHz, which is sufficient to lock on the Sodium D2 line. The robustness, beam quality, spectral narrowness and tunability of our source make it an alternative to dye lasers for atomic physics experiments with Sodium atoms.

Mimoun, Emmanuel; Zondy, Jean-Jacques; Dalibard, Jean; Gerbier, Fabrice

2009-01-01T23:59:59.000Z

255

Characterization of Dry-Air Aged Granules of Silver-Functionalized Silica Aerogel  

Science Conference Proceedings (OSTI)

This is a letter report to complete level 3 milestone "Assess aging characteristics of silica aerogels" for DOE FCRD program. Recently, samples of Ag0-functionalized silica aerogel were aged in flowing dry air for up to 6 months and then loaded with iodine. This dry-air aging simulated the impact of long-term exposure to process gases during process idling. The 6-month aged sample exhibited an iodine sorption capacity of 32 mass%, which was 9 mass % lower than that for an un-aged Ag0-functionalized silica aerogel. In an attempt to understand this decrease in sorption capacity, we characterized physical properties of the aged samples with Brunauer-Emmett-Teller (BET) nitrogen adsorption, X-ray diffraction (XRD), and high resolution scanning electron microscopy (SEM). The results showed no impact of aging on the aerogel microstructure or the silver nanoparticles in the aerogel, including their spatial distribution and morphology.

Matyas, Josef; Fryxell, Glen E.; Robinson, Matthew J.

2012-09-01T23:59:59.000Z

256

Sodium-Doped Molybdenum Targets for Controllable Sodium Incorporation in CIGS Solar Cells: Preprint  

DOE Green Energy (OSTI)

The efficiency of Cu(In,Ga)Se2 (CIGS) solar cells is enhanced when Na is incorporated in the CIGS absorber layer. This work examines Na incorporation in CIGS utilizing Na-doped Mo sputtered from targets made with sodium molybdate-doped (MONA) powder. Mo:Na films with varying thicknesses were sputtered onto Mo-coated borosilicate glass (BSG) or stainless steel substrates for CIGS solar cells. By use of this technique, the Na content of CIGS can be varied from near-zero to higher than that obtained from a soda-lime glass (SLG) substrate. Targets and deposition conditions are described. The doped Mo films are analyzed, and the resulting devices are compared to devices fabricated on Mo-coated SLG as well as Mo-coated BSG with NaF. Completed devices utilizing MONA exceeded 15.7% efficiency without anti-reflective coating, which was consistently higher than devices prepared with the NaF precursor. Strategies for minimizing adhesion difficulties are presented.

Mansfield, L. M.; Repins, I. L.; Glynn, S.; Carducci, M. D.; Honecker, D. M.; Pankow, J.; Young, M.; DeHart, C.; Sundaramoorthy, R.; Beall, C. L.; To, B.

2011-07-01T23:59:59.000Z

257

Very large-scale structures in sintered silica aerogels as evidenced by atomic force microscopy and ultra-small angle  

E-Print Network (OSTI)

Very large-scale structures in sintered silica aerogels as evidenced by atomic force microscopy of silica aerogels has been extensively studied mainly by scattering techniques (neutrons, X-rays, light) and atomic force microscopy (AFM) experiments have been carried out on aerogels at dierent steps of densi

Demouchy, Sylvie

258

Mercury Binding Sites in Thiol-Functionalized Mesostructured Silica  

SciTech Connect

Thiol-functionalized mesostructured silica with anhydrous compositions of (SiO{sub 2}){sub 1-x}(LSiO{sub 1.5}){sub x}, where L is a mercaptopropyl group and x is the fraction of functionalized framework silicon centers, are effective trapping agents for the removal of mercuric(II) ions from water. In the present work, we investigate the mercury-binding mechanism for representative thiol-functionalized mesostructures by atomic pair distribution function (PDF) analysis of synchrotron X-ray powder diffraction data and by Raman spectroscopy. The mesostructures with wormhole framework structures and compositions corresponding to x = 0.30 and 0.50 were prepared by direct assembly methods in the presence of a structure-directing amine porogen. PDF analyses of five mercury-loaded compositions with Hg/S ratios of 0.50-1.30 provided evidence for the bridging of thiolate sulfur atoms to two metal ion centers and the formation of chain structures on the pore surfaces. We find no evidence for Hg-O bonds and can rule out oxygen coordination of the mercury at greater than the 10% level. The relative intensities of the PDF peaks corresponding to Hg-S and Hg-Hg atomic pairs indicate that the mercury centers cluster on the functionalized surfaces by virtue of thiolate bridging, regardless of the overall mercury loading. However, the Raman results indicate that the complexation of mercury centers by thiolate depends on the mercury loading. At low mercury loadings (Hg/S {le} 0.5), the dominant species is an electrically neutral complex in which mercury most likely is tetrahedrally coordinated to bridging thiolate ligands, as in Hg(SBu{sup t}){sub 2}. At higher loadings (Hg/S 1.0-1.3), mercury complex cations predominate, as evidenced by the presence of charge-balancing anions (nitrate) on the surface. This cationic form of bound mercury is assigned a linear coordination to two bridging thiolate ligands.

Billinge, Simon J.L.; McKimmey, Emily J.; Shatnawi, Mouath; Kim, HyunJeong; Petkov, Valeri; Wermeille, Didier; Pinnavaia, Thomas J. (MSU); (CMU); (Iowa State)

2010-07-13T23:59:59.000Z

259

Permeability reduction of unconsolidated media due to stress-induced silica dissolution  

SciTech Connect

Permeability measurements were made on both glass beads and Ottowa sand under uniform confining stress conditions. Extreme permeability reduction (95%) of the glass beads was observed at temperatures exceeding 150/sup 0/C and confining pressures of 13.8 MPa with distilled water as the flowing fluid. Permeability reduction in the Ottowa sand (40%) was also observed at high temperature and confining pressure. Effluent analysis revealed high concentrations of silica. Subsequent 300 hour experiments with Ottowa sand exhibited a steady decrease in permeability with time. SEM photographs of post experiment cores, indicate that the permeability reduction is mainly due to stress induced silica dissolution at grain contacts.

Udell, K.S.; Lofy, J.D.

1985-03-01T23:59:59.000Z

260

Theoretical study of the light scattering from two alternating concentric double silica-gold nanoshell  

SciTech Connect

The cross section of two alternating concentric double silica-gold nanoshell (DSGNS) is obtained as a function of wavelength. Numerical calculations show that two alternating concentric DSGNSs display two separated scattering peaks that the intensity and position of the scattering peaks depend on two gold shells thicknesses and silica layer thickness between them. By varying thicknesses of the layers of the gold shells, two alternating concentric DSGNS can be designed with the scattering peak from the visible to infrared regions of the spectrum.

Khosravi, H. [Department of Physics, Kermanshah Azad University, Kermanshah, 67189-97551 (Iran, Islamic Republic of); Daneshfar, N. [Department of Physics, Razi University, Kermanshah, 67149-67346 (Iran, Islamic Republic of); Bahari, A. [Department of Physics, Lorestan University, Lorestan, 68137-17133 (Iran, Islamic Republic of)

2010-05-15T23:59:59.000Z

Note: This page contains sample records for the topic "na-sg sodium silica" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Nickel container of highly-enriched uranium bodies and sodium  

SciTech Connect

A fuel element comprises highly a enriched uranium bodies coated with a nonfissionable, corrosion resistant material. A plurality of these bodies are disposed in layers, with sodium filling the interstices therebetween. The entire assembly is enclosed in a fluid-tight container of nickel.

Zinn, Walter H. (Hinsdale, IL)

1976-01-01T23:59:59.000Z

262

Compatibility Assessment of Advanced Stainless Steels in Sodium  

Science Conference Proceedings (OSTI)

Type 316L stainless steel capsules containing commercially pure sodium and miniature tensile specimens of HT-UPS (austenitic, 14Cr-16Ni), NF-616 (ferritic/martensitic, 9Cr-2W-0.5Mo), or 316L (austenitic, 17Cr-10Ni-2Mo) stainless steel were exposed at 600 or 700 C for 100 and 400 h as a screening test for compatibility. Using weight change, tensile testing, and metallographic analysis, HT-UPS and 316L were found to be largely immune to changes resulting from sodium exposure, but NF-616 was found susceptible to substantial decarburization at 700 C. Subsequently, two thermal convection loops (TCLs) constructed of 316L and loaded with commercially pure sodium and miniature tensile specimens of HT-UPS and 316L were operated for 2000 h each one between 500 and 650 C, the other between 565 and 725 C at a flow rate of about 1.5 cm/s. Changes in specimen appearance, weight, and tensile properties were observed to be very minor in all cases, and there was no metallographic evidence of microstructure changes, composition gradients, or mass transfer resulting from prolonged exposure in a TCL. Thus, it appears that HT-UPS and 316L stainless steels are similarly compatible with commercially pure sodium under these exposure conditions.

Pawel, Steven J [ORNL

2012-01-01T23:59:59.000Z

263

Volatility of Aqueous Acetic Acid, Formic Acid, and Sodium Acetate  

Science Conference Proceedings (OSTI)

The quality of water and steam is central to ensuring power plant component availability and reliability. A key part of developing operating cycle chemistry guidelines is an understanding of the impurity distribution between water and steam. This report examines the volatility of some of the principal cycle organic corrodents: acetic acid, formic acid, and sodium acetate.

2000-07-28T23:59:59.000Z

264

Method of generating hydrogen gas from sodium borohydride  

DOE Patents (OSTI)

A compact solid source of hydrogen gas, where the gas is generated by contacting water with micro-disperse particles of sodium borohydride in the presence of a catalyst, such as cobalt or ruthenium. The micro-disperse particles can have a substantially uniform diameter of 1-10 microns, and preferably about 3-5 microns. Ruthenium or cobalt catalytic nanoparticles can be incorporated in the micro-disperse particles of sodium borohydride, which allows a rapid and complete reaction to occur without the problems associated with caking and scaling of the surface by the reactant product sodium metaborate. A closed loop water management system can be used to recycle wastewater from a PEM fuel cell to supply water for reacting with the micro-disperse particles of sodium borohydride in a compact hydrogen gas generator. Capillary forces can wick water from a water reservoir into a packed bed of micro-disperse fuel particles, eliminating the need for using an active pump.

Kravitz, Stanley H. (Placitas, NM); Hecht, Andrew M. (Sandia Park, NM); Sylwester, Alan P. (Albuquerque, NM); Bell, Nelson S. (Albuquerque, NM)

2007-12-11T23:59:59.000Z

265

Method of Manufacturing Micro-Disperse Particles of Sodium Borohydride  

DOE Patents (OSTI)

A compact solid source of hydrogen gas, where the gas is generated by contacting water with micro-disperse particles of sodium borohydride in the presence of a catalyst, such as cobalt or ruthenium. The micro-disperse particles can have a substantially uniform diameter of 1-10 microns, and preferably about 3-5 microns. Ruthenium or cobalt catalytic nanoparticles can be incorporated in the micro-disperse particles of sodium borohydride, which allows a rapid and complete reaction to occur without the problems associated with caking and scaling of the surface by the reactant product sodium metaborate. A closed loop water management system can be used to recycle wastewater from a PEM fuel cell to supply water for reacting with the micro-disperse particles of sodium borohydride in a compact hydrogen gas generator. Capillary forces can wick water from a water reservoir into a packed bed of micro-disperse fuel particles, eliminating the need for using an active pump.

Kravitz, Stanley H. (Placitas, NM); Hecht, Andrew M. (Sandia Park, NM); Sylwester. Alan P. (Albuquerque, NM); Bell, Nelson S. (Albuquerque, NM)

2008-09-23T23:59:59.000Z

266

Sodium sulfur container with chromium/chromium oxide coating  

SciTech Connect

A coating of chromium/chromium oxide is disclosed for coating the surfaces of electrically conducting components of a sodium sulfur battery. This chromium/chromium oxide coating is placed on the surfaces of the electrically conducting components of the battery which are in contact with molten polysulfide and sulfur reactants during battery operation.

Ludwig, Frank A. (Irvine, CA); Higley, Lin R. (Santa Ana, CA)

1981-01-01T23:59:59.000Z

267

An Electrical Cathode Model of a High Pressure Sodium Lamp  

Science Conference Proceedings (OSTI)

An electrical cathode model (ECM) of a high pressure sodium lamp (HPS) based on physical laws has been developed. The proposed ECM calculates the instantaneous voltage drop in a cathode sheath and the temperature distribution inside the cathode using ... Keywords: cathode model, HPS lamp ballast designs

Jose Luis Tapia; Joel O. Pacheco Sotelo; Eduardo Diaz Rodriguez; Yulia Nikolaevna Ledeneva; Rene Arnulfo Garcia Hernandez

2010-09-01T23:59:59.000Z

268

Chemical kinetic studies on dry sorbents. Final report. [Sodium bicarbonate  

Science Conference Proceedings (OSTI)

The scope of this research investigation has included a review of potential additives suitable for dry flue-gas desulfurization (FGD) and a bench scale laboratory study to determine the chemical kinetics for the reaction of five different sorbents with sulfur dioxide. The sorbents chosen included sodium bicarbonate (NaHCO/sub 3/), soda ash (Na/sub 2/CO/sub 3/), trona, lime (CaO) and hydrated lime (Ca(OH)/sub 2/). This study has shown that: (1) The reaction rate increases with temperature for soda ash and calcium oxide. The reaction temperature has an inverse effect on sodium bicarbonate and trona due, primarily, to the simultaneous thermal activation reaction. The calcium hydroxide-SO/sub 2/ reaction increased up to 550/sup 0/F, and then decreased, due to uneven gas flow distribution. (2) The reaction rates for soda ash, calcium oxide and calcium hydroxide were increased by decreasing their particle size. This effect was not confirmed for sodium bicarbonate and trona where reaction temperature was the most important reaction parameter. (3) Reaction with soda ash was found to be limited by the presence of an impervious ash layer which prevented interparticle gaseous diffusion. Calcium oxide and calcium hydroxide were found to be limited by a slow chemical reaction rate. Results on the rate-limiting steps for sodium bicarbonate and trona were inconclusive because of the simultaneous thermal activation reaction. (4) The effect of thermal activation was to increase the reaction rate for sodium bicarbonate and trona at lower temperatures. This effect was less pronounced at higher temperatures. (5) Results obtained for nitric oxide show limited adsorption for the five sorbents tested as compared to the finding for sulfur dioxide.

Davis, W.T.; Keener, T.C.

1982-02-15T23:59:59.000Z

269

Method of and apparatus for removing silicon from a high temperature sodium coolant  

DOE Patents (OSTI)

This patent discloses a method of and system for removing silicon from a high temperature liquid sodium coolant system for a nuclear reactor. The sodium is cooled to a temperature below the silicon saturation temperature and retained at such reduced temperature while inducing high turbulence into the sodium flow for promoting precipitation of silicon compounds and ultimate separation of silicon compound particles from the liquid sodium.

Yunker, W.H.; Christiansen, D.W.

1983-11-25T23:59:59.000Z

270

Go No-Go Recommendation for Sodium Borohydride for On-Board Vehicular Hydrogen Storage  

Fuel Cell Technologies Publication and Product Library (EERE)

Independent review panel recommendation for go/no go decision on use of hydrolysis of sodium borohydride for hydrogen storage.

271

A new approach in signal processing for sodium boiling noise detection by probability density function estimates  

Science Conference Proceedings (OSTI)

The probability density function (pdf) method of noise signal processing has been investigated for its capability and quality in detecting sodium boiling noise. In an attempt to identify proper features of the pdf for sodium boiling noise detection, the segmented areas under the pdf curves have been found sensitive to sodium boiling noise. New approaches have been followed in selecting the feature threshold and achieving the targeted probabilities for false and missed sodium boiling noise detection.

Reddy, C.P.; Singh, O.P.; Vyjayanthi, R.K.; Prabhakar, R.

1988-03-01T23:59:59.000Z

272

Lithium/V6O13 cells using silica nanoparticle-based composite electrolyte  

E-Print Network (OSTI)

Lithium/V6O13 cells using silica nanoparticle-based composite electrolyte Yangxing Li, Peter S) both in liquid electrolyte consisting of oligomeric poly(ethyleneglycol)dimethylether'/lithium bis of suppressing lithium dendrite growth due to the rigidity and immobility of the electrolyte structure

Khan, Saad A.

273

Inhibition of Lithium Dendrites by Fumed Silica-Based Composite Electrolytes  

E-Print Network (OSTI)

Inhibition of Lithium Dendrites by Fumed Silica-Based Composite Electrolytes Xiang-Wu Zhang State University, Raleigh, North Carolina 27695-7905, USA Lithium dendrite formation is investigated via in situ microscopy in a liquid electrolyte containing polyethylene glycol dimethyl ether lithium bis

Khan, Saad A.

274

Silica-alumina trihydrate filled epoxy castings resistant to arced SF.sub.6  

SciTech Connect

A cured, insulating, casting composition, having a coefficient of linear thermal expansion of below about 38 .times. 10.sup.-6 in./in./.degree. C and being resistant to arced sulfur hexafluoride gas, in contact with a metal surface in a sulfur hexafluoride gas environment, is made from hydantoin epoxy resin, anhydride curing agent and a filler combination of fused silica and alumina trihydrate.

Chenoweth, Terrence E. (Monroeville, PA); Yeoman, Frederick A. (Murrysville, PA)

1978-01-01T23:59:59.000Z

275

TESLA-FEL 2004-01 Silica Aerogel Radiators for Bunch Length  

E-Print Network (OSTI)

TESLA-FEL 2004-01 Silica Aerogel Radiators for Bunch Length Measurements J. B¨ahr a , V. Djordjadze aerogel are used to measure the electron bunch length at the photo injector test facility at DESY Zeuthen by the usage of aerogel is calculated analytically and Monte Carlo simulations are performed. It is shown

276

Silica control and materials tests at the Salton Sea geothermal field  

DOE Green Energy (OSTI)

The Lawrence Livermore Laboratory maintains and operates a test facility near Niland, California, in the Imperial Valley for field studies on SSGF brine chemistry, scale and solids control, materials, and injection. Recent work in silica control and materials testing is reviewed.

Quong, R.; Harrar, J.E.; McCright, R.D.; Locke, R.D.; Lorensen, L.E.; Tardiff, G.E.

1979-06-07T23:59:59.000Z

277

Coupling of Advanced Oxidation and Adsorption Processes onto Silica-Titania Composites for Low Level  

E-Print Network (OSTI)

was mercury adsorption onto calcium sulfate (CaSO4), a byproduct of the flue gas desulfurization (FGD) wet., Powers K.W., and Pitoniak E.R. (2004) Method for Purifying Flue Gases from Combustion Sources. PatentCoupling of Advanced Oxidation and Adsorption Processes onto Silica-Titania Composites for Low

Choate, Paul M.

278

Facile and sensitive epifluorescent silica nanoparticles for the rapid screening of EHEC  

Science Conference Proceedings (OSTI)

This study was to develop antibodies conjugated fluorescent dye-doped silica nanoparticles (FDS-NPs) aiming to increase signals for the rapid detection of Escherichia coli O157:H7 with glass slide method. The FDS-NPs were produced with microemulsion/solgel ...

Pravate Tuitemwong, Nut Songvorawit, Kooranee Tuitemwong

2013-01-01T23:59:59.000Z

279

Refractive index and density in F- and Cl-doped silica glasses  

Science Conference Proceedings (OSTI)

The refractive index and density of fluorine- and chlorine-doped silica glasses were measured as functions of fictive temperature. The halogen concentrations were observed to have a refractive index or density that is independent of the fictive temperature were found. This implies that these properties are not affected by any heat-treatment conditions.

Kakiuchida, Hiroshi; Shimodaira, Noriaki; Sekiya, Edson H.; Saito, Kazuya; Ikushima, Akira J. [Research Center for Advanced Photon Technology, Toyota Technological Institute, 2-12-1 Hisakata, Tempaku, Nagoya, Aichi 468-8511 (Japan); Research Center for Advanced Photon Technology, Toyota Technological Institute, 2-12-1 Hisakata, Tempaku, Nagoya, Aichi 468-8511, Japan and Research Center, Asahi Glass Co., Ltd., 1150 Hazawa-cho, Kanagawa, Yokohama, Kanagawa 221-8755 (Japan); Research Center for Advanced Photon Technology, Toyota Technological Institute, 2-12-1 Hisakata, Tempaku, Nagoya, Aichi 468-8511 (Japan)

2005-04-18T23:59:59.000Z

280

Effects of Surface Modification Conditions on Hydrophobicity of Silica-based Coating Additives  

SciTech Connect

Superhydrophobic silica (SHS) powders are being evaluated as a potential additive to the polyurethane topcoats used in Chemical Agent Resistant Coating (CARC) systems, with the goal of improving water repellency and corrosion protection characteristics. The current generation of CARC topcoats is already highly loaded with solids, and thus there is a premium on minimization of the total SHS powder required to achieve the desired properties. Therefore, efficient surface modification of the silica and proper dispersion in the coating will be required. The effect of a dispersant on the surface modification of silica particles by chlorosilanes was addressed in this study. The properties of various SHS powders were characterized by thermogravimetric analysis and mass spectroscopy. Correlations between powder modification conditions and the ultimate effects of the modified particles on hydrophobicity of CARC topcoats were assessed. The use of contact and rolling angle measurements along with scanning electron microscopy are discussed as they pertain to the ability to quantify the effects of modified silicas on corrosion prevention coatings. Furthermore, a systematic approach to modifying and testing both powders and top coats of corrosion prevention systems is presented.

Armstrong, Beth L [ORNL; Pawel, Steven J [ORNL; Hunter, Scott Robert [ORNL; Haynes, James A [ORNL; Hillesheim, Daniel A [ORNL

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "na-sg sodium silica" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Determination of silica scale deposition rates and thresholds applied toward protection of injection reservoirs. Quarterly progress report, April 1--June 30, 1998  

DOE Green Energy (OSTI)

The program objective aims to identify the highest temperature at which silica scale will develop from partially evaporated and significantly cooled geothermal liquid. The approach involves tracking deposition of silica scale by monitoring the apparent electrical conductivity of the geothermal liquid in an isolation chamber. A decrease in apparent conductivity occurs because silica deposited on electrode surfaces is less conductive than the geothermal liquid. The major technical hurdle is building a conductivity monitoring system that is sensitive enough to distinguish between no silica deposition and almost no silica deposition, while accounting for other factors which also affect conductivity, such as temperature and varying fluid composition.

NONE

1998-07-01T23:59:59.000Z

282

Determination of silica scale deposition rates and thresholds applied toward protection of injection reservoirs. Quarterly progress report, January 1, 1988--March 31, 1998  

DOE Green Energy (OSTI)

The program objective aims to identify the highest temperature at which silica scale will develop from partially evaporated and significantly cooled geothermal liquid. The approach involves tracking deposition of silica scale by monitoring the apparent electrical conductivity of the geothermal liquid in an isolation chamber. A decrease in apparent conductivity occurs because the deposited silica is less conductive than the geothermal liquid. The major technical hurdle is building a conductivity monitoring system that is sensitive enough to distinguish between no silica deposition and almost no silica deposition, while accounting for other factors which also affect conductivity, such as temperature and varying fluid composition.

NONE

1998-05-01T23:59:59.000Z

283

Determination of silica scale deposition rates and thresholds applied toward protection of injection reservoirs. Quarterly progress report, July 1--September 30, 1998  

DOE Green Energy (OSTI)

The program objective aims to identify the highest temperature at which silica scale will develop from partially evaporated and significantly cooled geothermal liquid. The approach involves tracking deposition of silica scale by monitoring the apparent electrical conductivity of the geothermal liquid in an isolation chamber. A decrease in apparent conductivity occurs because silica deposited on electrode surfaces is less conductive than the geothermal liquid. The major technical hurdle is building a conductivity monitoring system that is sensitive enough to distinguish between no silica deposition and almost no silica deposition, while accounting for other factors which also affect conductivity, such as temperature and varying fluid composition.

NONE

1998-11-01T23:59:59.000Z

284

Microsoft Word - EC Sodium coolant removal.doc  

NLE Websites -- All DOE Office Websites (Extended Search)

1 1 SECTION A. Project Title: MFC - EBR-II Sodium Removal/RCRA Closure Activities SECTION B . Project Description The proposed action will remove the sodium from the Experimental Breeder Reactor (EBR)-II piping system and tanks to achieve clean-closure for eventual decommissioning, deactivation and demolition (DD&D). The clean-closure will be completed in compliance with the EBR-II Hazardous Waste Management Act/Resource Conservation and Recovery Act (HWMA/RCRA) Storage and Treatment Permit PER-120, which includes the closure plan. EBR-II is located at the Materials and Fuels Complex at the Idaho National Laboratory. The EBR-II DD&D actions will be addressed under the Comprehensive Environmental Response Compensation, and Liability Act, specifically, the Engineering Evaluation/Cost

285

First-Principles Study on Electron Conduction in Sodium Nanowire  

E-Print Network (OSTI)

Abstract. We present detailed first-principles calculations of the electron-conduction properties of a three-sodium-atom nanowire suspended between semi-infinite crystalline Na(001) electrodes during its elongation. Our investigations reveal that the conductance is ? 1 G0 before the nanowire breaks and only one channel with the characteristic of the 3s orbital of the center atom in the nanowire contributes to the electron conduction. Moreover, the channel fully opens around the Fermi level, and the behavior of the channel-current density is insensitive to the structural deformation of the nanowire. These results verify that the conductance trace as a function of the electrode spacing exhibits a flat plateau at ? 1 G0 during elongation. First-Principles Study on Electron Conduction in Sodium Nanowire 2 1.

Yoshiyuki Egami; Takashi Sasaki; Tomoya Ono

2004-01-01T23:59:59.000Z

286

Sodium-Beta Alumina Batteries: Status and Challenges  

DOE Green Energy (OSTI)

Sodium-beta alumina batteries, have been extensively developed for a few decades and encouraging progress has been achieved so far. The anode is typically molten sodium while the cathode can be molten sulfur (Na-S battery) or solid transition metal halides plus a liquid phase secondary electrolyte (e.g., ZEBRA battery). The electrolyte typically used is a ?"-Al2O3 solid membrane. The issues prohibiting broad commercialization of this type of technology are dependent on the materials used, but can be broadly described as relatively high cost, safety (particularly for the Na-S couple), and low power. This paper offers a review on materials and designs for the batteries and discusses the challenges ahead for further technology improvement.

Lu, Xiaochuan; Lemmon, John P.; Sprenkle, Vincent L.; Yang, Zhenguo

2010-09-05T23:59:59.000Z

287

TEN-YEAR SODIUM-REACTOR DEVELOPMENT PROGRAM  

SciTech Connect

>A 10-year program of development and construction of large-scale, sodium-cooled reactors is summarized. The current state of development of the SGR and its associated components is sufficiently advanced to permit construction of economic plants within the 10-year period. Two advanced Sodium Reactor concepts are presented. A construction program involving two reactor experiments and two full-scale plants with a capacity of 550 Mwe, together with associated development, is estimated to cost 6 million. Of this amount approximately 06 million would be borne by the AEC and the remainder by power utility companies. Escalation and construction loan interest charges are included in these figures. The cost of power from the larger power plant would be approximately 6 mills/kw-hr, based on 1959 dollars. (auth)

1959-04-11T23:59:59.000Z

288

CORE PARAMETER STUDY FOR A 300-MW SODIUM GRAPHITE REACTOR  

SciTech Connect

A core parameter study of the operating costs was performed for a 300- Mwe sodium graphite reactor, a scale-up of the Hallam Power Reactor. The results of the study indicate that the core design is nsar optimum and that core modifications would reduce the power costs by less than 5%. The lattice spacing, fuel rod diameter, and sodium flow can be varied within a rather broad range without significant changes in power generation costs. The effect of the fuel cladning thickness is more significant; fuel cycle costs can be reduced if stainless steel canning is replaced with zirconium canning. Use of UC in place of uraniummolybdenum fuel would also permit cost reductions. (D.L.C.)

Corcoran, W.P.

1959-10-22T23:59:59.000Z

289

Selective Adsorption of Sodium Aluminum Fluoride Salts from Molten Aluminum  

SciTech Connect

Aluminum is produced in electrolytic reduction cells where alumina feedstock is dissolved in molten cryolite (sodium aluminum fluoride) along with aluminum and calcium fluorides. The dissolved alumina is then reduced by electrolysis and the molten aluminum separates to the bottom of the cell. The reduction cell is periodically tapped to remove the molten aluminum. During the tapping process, some of the molten electrolyte (commonly referred as “bath” in the aluminum industry) is carried over with the molten aluminum and into the transfer crucible. The carryover of molten bath into the holding furnace can create significant operational problems in aluminum cast houses. Bath carryover can result in several problems. The most troublesome problem is sodium and calcium pickup in magnesium-bearing alloys. Magnesium alloying additions can result in Mg-Na and Mg-Ca exchange reactions with the molten bath, which results in the undesirable pickup of elemental sodium and calcium. This final report presents the findings of a project to evaluate removal of molten bath using a new and novel micro-porous filter media. The theory of selective adsorption or removal is based on interfacial surface energy differences of molten aluminum and bath on the micro-porous filter structure. This report describes the theory of the selective adsorption-filtration process, the development of suitable micro-porous filter media, and the operational results obtained with a micro-porous bed filtration system. The micro-porous filter media was found to very effectively remove molten sodium aluminum fluoride bath by the selective adsorption-filtration mechanism.

Leonard S. Aubrey; Christine A. Boyle; Eddie M. Williams; David H. DeYoung; Dawid D. Smith; Feng Chi

2007-08-16T23:59:59.000Z

290

Sodium boiling in LMFBR fuel assemblies. Progress report  

Science Conference Proceedings (OSTI)

Objective is to improve current understanding of sodium voiding behavior under postulated LMFBR accident conditions. Multi-dimensional computer models are being developed under low flow and low power conditions. The following computer codes are being developed and assessed: NATOF-2D, THERMIT-S-6E, and THERMIT-S-4E. The effect of virtual mass on the characteristics and numerical stability in two-phase flows was studied. (DLC)

Not Available

1981-04-30T23:59:59.000Z

291

Chaotic Dynamos Generated by a Turbulent Flow of Liquid Sodium  

SciTech Connect

We report the observation of several dynamical regimes of the magnetic field generated by a turbulent flow of liquid sodium (VKS experiment). Stationary dynamos, transitions to relaxation cycles or to intermittent bursts, and random field reversals occur in a fairly small range of parameters. Large scale dynamics of the magnetic field result from the interactions of a few modes. The low dimensional nature of these dynamics is not smeared out by the very strong turbulent fluctuations of the flow.

Ravelet, F.; Monchaux, R.; Aumaitre, S.; Chiffaudel, A.; Daviaud, F.; Dubrulle, B. [Service de Physique de lEtat Condense, Direction des Sciences de la Matiere, CEA-Saclay, CNRS URA 2464, 91191 Gif-sur-Yvette cedex (France); Berhanu, M.; Fauve, S.; Mordant, N.; Petrelis, F. [Laboratoire de Physique Statistique de lEcole Normale Superieure, CNRS UMR 8550, 24 Rue Lhomond, 75231 Paris Cedex 05 (France); Bourgoin, M.; Odier, Ph.; Plihon, N.; Pinton, J.-F.; Volk, R. [Laboratoire de Physique de lEcole Normale Superieure de Lyon, CNRS UMR 5672, 46 allee dItalie, 69364 Lyon Cedex 07 (France)

2008-08-15T23:59:59.000Z

292

Sodium-Bearing Waste Treatment, Applied Technology Plan  

SciTech Connect

Settlement Agreement between the Department of Energy and the State of Idaho mandates treatment of sodium-bearing waste at the Idaho Nuclear Technology and Engineering Center within the Idaho National Engineering and Environmental Laboratory. One of the requirements of the Settlement Agreement is to complete treatment of sodium-bearing waste by December 31, 2012. Applied technology activities are required to provide the data necessary to complete conceptual design of four identified alternative processes and to select the preferred alternative. To provide a technically defensible path forward for the selection of a treatment process and for the collection of needed data, an applied technology plan is required. This document presents that plan, identifying key elements of the decision process and the steps necessary to obtain the required data in support of both the decision and the conceptual design. The Sodium-Bearing Waste Treatment Applied Technology Plan has been prepared to provide a description/roadmap of the treatment alternative selection process. The plan details the results of risk analyzes and the resulting prioritized uncertainties. It presents a high-level flow diagram governing the technology decision process, as well as detailed roadmaps for each technology. The roadmaps describe the technical steps necessary in obtaining data to quantify and reduce the technical uncertainties associated with each alternative treatment process. This plan also describes the final products that will be delivered to the Department of Energy Idaho Operations Office in support of the office's selection of the final treatment technology.

Lance Lauerhass; Vince C. Maio; S. Kenneth Merrill; Arlin L. Olson; Keith J. Perry

2003-06-01T23:59:59.000Z

293

Development of the sodium/sulfur technology for energy storage  

DOE Green Energy (OSTI)

The US Department of Energy (DOE) has supported the development of the sodium-sulfur technology since 1973. The programs have focused on progressing core aspects of the technology and completing initial battery engineering for both mobile and stationary applications. An overview of the Office of Energy Management (OEM) activities is contained in this paper. Two major development programs have been active: the first with Ford Aerospace and Communications Corporation (1975 to 1985), and the second with Chloride Silent Power Limited (1985 to 1990). With the completion this year of the qualification of a cell suitable for initial Solar Energy Systems (SES) applications, the emphasis of future DOE/OEM sodium/sulfur programs will shift to SES-battery engineering and development. The initial effort will resolve a number of issues related to the feasibility of utilizing the sodium/sulfur technology in these large-scale applications. This multi-year activity will represent the initial phase of an integrated long-term DOE-supported program to produce a commercially viable battery system.

Landgrebe, A. (USDOE Assistant Secretary for Conservation and Renewable Energy, Washington, DC (USA). Office of Energy Management); Magnani, N.J. (Sandia National Labs., Albuquerque, NM (USA))

1990-01-01T23:59:59.000Z

294

Compact intermediate heat transport system for sodium cooled reactor  

SciTech Connect

This patent describes a combination with a sodium cooled reactor having an intermediate heat exchanger for extracting heat in a nonradioactive secondary sodium loop from the sodium rector. It comprises: first and second upstanding closed cylindrical vessels, one of the cylindrical vessels being exterior of the other of the cylindrical vessels; the other of the cylindrical vessels being interior, smaller, and concentric of the larger cylindrical vessel so as to define between the inside of the larger vessel and the outside of the smaller vessel an interstitial annular volume; at least one feedwater inlet plenums at the bottom of the larger vessel communicated to the interstitial annular volume; at least one feedwater outlet plenums at the top of the larger and outer vessel communicated to the interstitial annular volume; tubes communicated to the feedwater inlet plenum at the bottom of the vessels and to the steam outlet plenum at the top of the vessel; a first conduit; a large submersible electromagnetic pump; and a jet pump having an inlet, a venturi, and a diffusing outlet.

Boardman, C.E.; Maurer, J.P.

1990-03-06T23:59:59.000Z

295

Sodium Dichromate Barrel Landfill expedited response action proposal  

SciTech Connect

The US Environmental Protection Agency (EPA) and Washington State Department of Ecology (Ecology) recommended that the US Department of Energy (DOE) prepare an expedited response action (ERA) for the Sodium Dichromate Barrel Landfill. The Sodium Dichromate Barrel Disposal Site was used in 1945 for disposal of crushed barrels. The site location is the sole waste site within the 100-IU-4 Operable Unit. The Waste Information Data System (WIDS 1992) assumes that the crushed barrels contained 1% residual sodium dichromate at burial time and that only buried crushed barrels are at the site. Burial depth is shallow since visual inspection finds numerous barrel debris on the surface. A non-time-critical ERA proposal includes preparation of an engineering evaluation and cost analysis (EE/CA) section. The EE/CA is a rapid, focused evaluation of available technologies using specific screening factors to assess feasibility, appropriateness, and cost. The ERA goal is to reduce the potential for any contaminant migration from the landfill to the soil column, groundwater, and Columbia River. Since the landfill is the only waste site within the operable unit, the ERA will present a final remediation of the 100-IU-4 operable unit.

Not Available

1993-09-01T23:59:59.000Z

296

Sodium meta-autunite colloids: Synthesis, characterization,stability  

Science Conference Proceedings (OSTI)

Waste forms of U such as those in the United States Department of Energy's Hanford Site often contain high concentrations of Na and P. Low solubility sodium uranyl phosphates such as sodium meta-autunite have the potential to form mobile colloids that can facilitate transport of this radionuclide. In order to understand the geochemical behavior of uranyl phosphate colloids, we synthesized sodiummeta-autunite colloids, and characterized their morphology, chemical composition, structure, dehydration, and surface charge. The stability of these synthetic plate-shaped colloids was tested with respect to time and pH. The highest aggregation rate was observed at pH 3, and the rate decreases as pH increases, indicating that higher stability of colloid dispersion under neutral and alkaline pH conditions. The synthetic colloids are all negatively charged and no isoelectric points were found over a pH range of 3 to 9. The zeta-potentials of the colloids in the phosphate solution show a strong pH-dependence in the more acidic range over time, but are relatively constant in the neutral and alkaline pH range. The geochemical behavior of the synthetic colloids can be interpreted using DLVO theory. The results suggest that formation of mobile sodium meta-autunite colloids can enhance the transport of U in some contaminated sediments.

zzuoping@lbl.gov

2004-04-10T23:59:59.000Z

297

EIS-0306: Treatment and Management of Sodium-Bonded Spent Nuclear Fuel |  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

306: Treatment and Management of Sodium-Bonded Spent Nuclear 306: Treatment and Management of Sodium-Bonded Spent Nuclear Fuel EIS-0306: Treatment and Management of Sodium-Bonded Spent Nuclear Fuel Summary This EIS evaluates the potential environmental impacts of the proposed electrometallurgical treatment of DOE-owned sodium bonded spent nuclear fuel in the Fuel Conditioning Facility at Argonne National Laboratory-West (ANL-W). Public Comment Opportunities None available at this time. Documents Available for Download September 19, 2000 EIS-0306: Record of Decision Treatment and Management of Sodium-Bonded Spent Nuclear Fuel July 1, 2000 EIS-0306: Final Environmental Impact Statement Treatment and Management of Sodium-Bonded Spent Nuclear Fuel July 1, 1999 EIS-0306: Draft Environmental Impact Statement Treatment of Sodium-Bonded Spent Nuclear Fuel

298

Interstitial BiO molecule as a center of broadband IR luminescence in bismuth-doped silica glass  

E-Print Network (OSTI)

IR luminescence and absorption in bismuth-doped silica glass-core fibers observed recently (see [arXiv:1106.2969v1 [physics.optics]) are argued to be caused by transitions in interstitial BiO molecules

Sokolov, V O; Dianov, E M

2011-01-01T23:59:59.000Z

299

Extreme Chromatography: Faster, Hotter, SmallerChapter 5 High-efficiency Liquid Chromatography Separations Achieved by Monolithic Silica Columns  

Science Conference Proceedings (OSTI)

Extreme Chromatography: Faster, Hotter, Smaller Chapter 5 High-efficiency Liquid Chromatography Separations Achieved by Monolithic Silica Columns Methods and Analyses eChapters Methods - Analyses Books AOCS Press Downloada

300

Study of a Threshold Cherenkov Counter Based on Silica Aerogels with Low Refractive Indices ?  

E-Print Network (OSTI)

To identify ? ± and K ± in the region of 1.0 ? 2.5 GeV/c, a threshold Cherenkov counter equipped with silica aerogels has been investigated. Silica aerogels with a low refractive index of 1.013 have been successfully produced using a new technique. By making use of these aerogels as radiators, we have constructed a Cherenkov counter and have checked its properties in a test beam. The obtained results have demonstrated that our aerogel was transparent enough to make up for loss of the Cherenkov photon yield due to a low refractive index. Various configurations for the photon collection system and some types of photomultipliers, such as the fine-mesh type, for a read out were also tested. From these studies, our design of a Cherenkov counter dedicated to ?/K separation up to a few GeV/c with an efficiency greater than 90 % was considered. 1

I. Adachi; T. Sumiyoshi; K. Hayashi; N. Iida; R. Enomoto; K. Tsukada; R. Suda; S. Matsumoto; K. Natori; M. Yokoyama; H. Yokogawa

1994-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "na-sg sodium silica" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Mesoporous silica film from a solution containing a surfactant and methods of making same  

DOE Patents (OSTI)

The present invention is a mesoporous silica film having a low dielectric constant and method of making having the steps of combining a surfactant in a silica precursor solution, spin-coating a film from this solution mixture, forming a partially hydroxylated mesoporous film, and dehydroxylating the hydroxylated film to obtain the mesoporous film. It is advantageous that the small polyoxyethylene ether surfactants used in spin-coated films as described in the present invention will result in fine pores smaller on average than about 20 nm. The resulting mesoporous film has a dielectric constant less than 3, which is stable in moist air with a specific humidity. The present invention provides a method for superior control of film thickness and thickness uniformity over a coated wafer, and films with low dielectric constant.

Liu, Jun (West Richland, WA); Domansky, Karel (Cambridge, MA); Li, Xiaohong (Richland, WA); Fryxell, Glen E. (Kennewick, WA); Baskaran, Suresh (Kennewick, WA); Kohler, Nathan J. (Richland, WA); Thevuthasan, Suntharampillai (Kennewick, WA); Coyle, Christopher A. (Richland, WA); Birnbaum, Jerome C. (Richland, WA)

2001-01-01T23:59:59.000Z

302

Flow cytometric analysis of respiratory tract cells exposed to oil shale and silica particulates. [Hamsters  

SciTech Connect

Flow cytometric techniques were used to measure the cytological and biochemical damage to respiratory tract cells in animals exposed to particulates. Hamsters were exposed to raw and spent oil shale particulates and silica by intratracheal instillation. Exfoliated lung cells were obtained by sacrificing the animals and lavaging the respiratory tract posterior to the trachea with saline. Cell samples were fixed in ethanol and stained with mithramycin for fluorescence analysis of DNA content. DNA content distributions from hamsters exposed to spent oil shale and silica particulates showed atypical changes 28 to 35 days later. Cell counts and total numbers of macrophages, leukocytes, and epithelial cells in the lavage fluid also showed marked changes related to time after exposure.

Steinkamp, J.A.; Wilson, J.S.

1979-01-01T23:59:59.000Z

303

Petrography study on altered flint aggregate by alkali-silica reaction  

SciTech Connect

The aim of our study is to improve our understanding of an alkali-silica reaction (ASR) via petrography. We used a chemical concrete subsystem: flint aggregate, portlandite and KOH. The altered flint aggregate is followed by optical microscopy and scanning electron microscopy (SEM) before and after acid treatment at different intervals. After acid treatment, the observations showed an increase in aggregate porosity and revealed internal degradation of the aggregate. This degradation created amorphous zones. Before acid treatment, the analyses on polished sections by scanning electron microscopy coupled with energy dispersive spectroscopy (EDS) enabled visualization of K{sup +} and Ca{sup 2+} penetration into the aggregate. The appearance of amorphous zones and penetration of positive ions into the aggregate are correlated with the increase in the molar fraction of silanol sites. This degradation is specific to the alkali-silica reaction.

Bulteel, D. [Departement Genie Civil de l'Ecole Nationale Superieure des Techniques Industrielles et des Mines de Douai, 941 rue Charles Bourseul, B.P. 838, F-59508, DOUAI Cedex (France)]. E-mail: bulteel@ensm-douai.fr; Rafai, N. [Laboratoire d'Etude et de Recherches des Materiaux a Arles, F-13631 ARLES (France); Degrugilliers, P. [Departement Genie Civil de l'Ecole Nationale Superieure des Techniques Industrielles et des Mines de Douai, 941 rue Charles Bourseul, B.P. 838, F-59508, DOUAI Cedex (France); Garcia-Diaz, E. [Departement Genie Civil de l'Ecole Nationale Superieure des Techniques Industrielles et des Mines de Douai, 941 rue Charles Bourseul, B.P. 838, F-59508, DOUAI Cedex (France)

2004-11-15T23:59:59.000Z

304

The Role of High Calcium Fly Ashes in Controlling Alkali-Silica Reactions in Concrete  

Science Conference Proceedings (OSTI)

The alkali-silica reaction (ASR) is a deleterious chemical reaction that can result in the deterioration of concrete structures. This report builds upon the results of a research and development study, funded by a broadly-based multi-national industry consortium, that is developing an engineering database on the long-term effectiveness of Class F fly ash and other supplementary cementing materials (SCMs) in counteracting ASR in concrete.

2002-11-20T23:59:59.000Z

305

A New Concept for the Fabrication of Hydrogen Selective Silica Membranes  

DOE Green Energy (OSTI)

We are attempting to fabricate H{sub 2}-selective silica-based films by ''layer-by-layer'' deposition as a new approach for thin films. A sonication-assisted deposition method was mainly used for ''layer-by-layer'' deposition. In addition, other approaches such as a dip-coating and the use of a polymer matrix with a layered silicate were contrived as well. This report shows the progress done during the 2nd Year of this award.

Michael Tsapatsis

2006-07-31T23:59:59.000Z

306

Modified Murnaghan equation of state applied to shock compression of silica, basalt, and dolomite  

DOE Green Energy (OSTI)

An equation of state previously used by the author is developed further and applied to geologic media. The equation is of the same form as the Murnaghan equation of state, but with the elastic constant terms replaced by the cohesive energy density (internal pressure), and the exponential term given as a sum of the Gruneisen parameter and the gaseous adiabatic exponent. Data for shock compression of silica, basalt, and dolomite are analyzed according to the equation.

Rogers, L.A.

1965-12-20T23:59:59.000Z

307

Sulfate Fining Chemistry in Oxidized and Reduced Soda-Lime-Silica Glasses  

SciTech Connect

Various reducing agents were used and their additions were varied to (1) increase glass quality through eliminating defects from silica scum, (2) decrease SOx emissions through changing the kind and quantity of reducing agents, and (3) improve production efficiency through increased flexibility of glass redox control during continuous processing. The work included measuring silica sand dissolution and sulfate decomposition in melts from glass batches. Glass batches were heated at a temperature-increase rate deemed similar to that experienced in the melting furnace. The sulfate decomposition kinetics was investigated with thermogravimetric analysis-differential thermal analysis and evolved gas analysis. Sulfur concentrations in glasses quenched at different temperatures were determined using X-ray fluorescence spectroscopy. The distribution of residual sand (that which was not dissolved during the initial batch reactions) in the glass was obtained as a function of temperature with optical microscopy in thin-sections of melts. The fraction of undissolved sand was measured with X-ray diffraction. The results of the present study helped Visteon Inc. reduce the energy consumption and establish the batch containing 0.118 mass% of graphite as the best candidate for Visteon glass production. The improved glass batch has a lower potential for silica scum formation and for brown fault occurrence in the final glass product. It was established that bubbles trapped in the melt even at 1450 C have a high probability to be refined when reaching the hot zone in the glass furnace. Furthermore, silica sand does not accumulate at the glass surface and dissolves faster in the batch with graphite than in the batch with carbocite.

Matyas, Josef; Hrma, Pavel R.

2005-05-13T23:59:59.000Z

308

In-depth survey report of silica flour dust during packing, transfer, and shipping at the Central Silica Company, Glass Rock Plant, Glass Rock, Ohio  

Science Conference Proceedings (OSTI)

A visit was made to the Central Silica Company, Glass Rock, Ohio to evaluate methods used to control employee exposure to silica dust. The control methods at this company included careful handling and transfer of damp materials, exhaust ventilation, good housekeeping procedures, and the use of respiratory protection. Evaluations were made of the packing area, transfer point, inside loading trucks, and ambient air at sections of the flour building. Control systems included a good exhaust-ventilation system and four ventilation hoods. Evaluations were made of samples collected by an MSA gravimeter dust sampler, the Del High volume electrostatic precipitation, and bulk and rafter samples. Dust control methods appeared to be effective due to the existence of good engineering controls, good work practices, and an effective respiratory protection program. Additional control measures included the handling of the ore as a damp material, thus reducing the generation of dust particles. Outside dust sources were being reduced. Most of the product was shipped in bulk. Plastic wrapping was used around pallet loads to reduce bag breakage and dust dispersion. A filtered air system controlled low dust levels in the Pebble Mill control room. Enclosed screens operated under negative pressure separated fine from coarse product at the process building.

Caplan, P.E.; Reed, L.D.; Amendola, A.A.; Cooper, T.C.

1981-12-01T23:59:59.000Z

309

HIGH SODIUM SIMULANT TESTING TO SUPPORT SB8 SLUDGE PREPARATION  

Science Conference Proceedings (OSTI)

Scoping studies were completed for high sodium simulant SRAT/SME cycles to determine any impact to CPC processing. Two SRAT/SME cycles were performed with simulant having sodium supernate concentration of 1.9M at 130% and 100% of the Koopman Minimum Acid requirement. Both of these failed to meet DWPF processing objectives related to nitrite destruction and hydrogen generation. Another set of SRAT/SME cycles were performed with simulant having a sodium supernate concentration of 1.6M at 130%, 125%, 110%, and 100% of the Koopman Minimum Acid requirement. Only the run at 110% met DWPF processing objectives. Neither simulant had a stoichiometric factor window of 30% between nitrite destruction and excessive hydrogen generation. Based on the 2M-110 results it was anticipated that the 2.5M stoichiometric window for processing would likely be smaller than from 110-130%, since it appeared that it would be necessary to increase the KMA factor by at least 10% above the minimum calculated requirement to achieve nitrite destruction due to the high oxalate content. The 2.5M-130 run exceeded the DWPF hydrogen limits in both the SRAT and SME cycle. Therefore, testing of this wash endpoint was halted. This wash endpoint with this minimum acid requirement and mercury-noble metal concentration profile appears to be something DWPF should not process due to an overly narrow window of stoichiometry. The 2M case was potentially processable in DWPF, but modifications would likely be needed in DWPF such as occasionally accepting SRAT batches with undestroyed nitrite for further acid addition and reprocessing, running near the bottom of the as yet ill-defined window of allowable stoichiometric factors, potentially extending the SRAT cycle to burn off unreacted formic acid before transferring to the SME cycle, and eliminating formic acid additions in the frit slurry.

Newell, J.

2012-09-19T23:59:59.000Z

310

Self-welding evaluation of reactor materials in flowing sodium  

SciTech Connect

An experimental study was made of the self-welding of various combinations of FBR materials (304 ss, Inconel 718, A286, Stellite 156, and Stellite 6) in sodium at 800 to 1100$sup 0$F for time periods up to 6 months and contact stresses of 2 to 148 ksi. Stresses required to separate the surfaces were determined. Self-welding was observed only at temperatures of 1050$sup 0$F and above, with the breakaway force being less than 5 ksi. (DLC)

Chang, J.Y.; Flagella, P.N.; Schrock, S.L.

1975-01-01T23:59:59.000Z

311

Electrolytic Treatment of ICPP Sodium-Bearing Waste Simulant  

SciTech Connect

Two proof-of-principle tests were conducted to determine if nitrate can be destroyed electrochemically in a simulated Idaho Chemical Processing Plant (ICPP) Sodium-Bearing waste. Both tests demonstrated the destruction of nitrate as well as the removal of other metals in the simulant. Metals removal is believed to be due to precipitation as a result of a change in the pH of the waste solution from strongly acidic to highly alkaline and reduction to a metal or metal oxide. Although gas evolution at the cathode was visible during each test, there were no visible signs of NO{sub x} formation in either test.

Hobbs, D.T.

1995-02-02T23:59:59.000Z

312

Feed Composition for Sodium-Bearing Waste Treatment Process  

SciTech Connect

Treatment of sodium-bearing waste (SBW) at the Idaho Nuclear Technology and Engineering Center (INTEC) within the Idaho National Engineering and Environmental Laboratory is mandated by a Settlement Agreement between the Department of Energy and the State of Idaho. One of the requirements of the Settlement Agreement is to complete treatment of SBW by December 31, 2012. To support both design and development studies for the SBW treatment process, detailed feed compositions are needed. This report contains the expected compositions of these feed streams and the sources and methods used in obtaining these compositions.

Barnes, C.M.

2000-10-30T23:59:59.000Z

313

STATIC SODIUM TEST OF WESTINGHOUSE FLOW CONTROLLER BEARING  

SciTech Connect

Tests were carried out to determine the action of a static sodium environment on a special high-temperature ball bearing while operating at the specified speed and loading. The test bearing was operated at 85 rpm and 870 pounds axial load for 385 hr at 1000 deg F. Visual inspection of the test bearing showed a very marked increase in roughness of both the balls and the ball races. Details of the measurements and a photograph of the bearing parts after test are given. On the basis of this test it did not appear that this bearing will be satisfactory for the service intended. (M.C.G.)

Cygan, R.

1960-12-01T23:59:59.000Z

314

United States, France and Japan Increase Cooperation on Sodium-Cooled Fast  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

United States, France and Japan Increase Cooperation on United States, France and Japan Increase Cooperation on Sodium-Cooled Fast Reactor Prototypes United States, France and Japan Increase Cooperation on Sodium-Cooled Fast Reactor Prototypes February 1, 2008 - 11:13am Addthis WASHINGTON, DC -The U.S Department of Energy (DOE), the French Atomic Energy Commission (CEA) and Japan Atomic Energy Agency (JAEA) today expanded cooperation to coordinate Sodium-Cooled Fast Reactor Prototype development through a Memorandum of Understanding (MOU) signed by DOE Assistant Secretary for Nuclear Energy Dennis R. Spurgeon, CEA Chairman Alain Bugat and JAEA President Toshio Okazaki. The MOU establishes a collaborative framework with the ultimate goal of deploying sodium-cooled fast reactor prototypes. A sodium-cooled fast reactor uses liquid sodium

315

Ion Recognition Approach to Volume Reduction of Alkaline Tank Waste by Separation of Sodium Salts  

SciTech Connect

The purpose of this research involving collaboration between Oak Ridge National Laboratory (ORNL) and Pacific Northwest National Laboratory (PNNL) is to explore new approaches to the separation of sodium hydroxide, sodium nitrate, and other sodium salts from high-level alkaline tank waste. The principal potential benefit is a major reduction in disposed waste volume, obviating the building of expensive new waste tanks and reducing the costs of low-activity waste immobilization. Principles of ion recognition are being researched toward discovery of liquid extraction systems that selectively separate sodium hydroxide and sodium nitrate from other waste components. The successful concept of pseudohydroxide extraction using fluorinated alcohols and phenols is being developed at ORNL and PNNL toward a greater understanding of the controlling equilibria, role of solvation, and of synergistic effects involving crown ethers. Studies at PNNL are directed toward new solvent formulation for the practical sodium pseudohydroxide extraction systems.

Levitskaia, Tatiana G.; Lumetta, Gregg J.; Moyer, Bruce A.; Bonnesen, Peter V.

2006-06-01T23:59:59.000Z

316

OPERATING EXPERIENCE WITH THE SODIUM REACTOR EXPERIMENT AND ITS APPLICATION TO THE HALLAM NUCLEAR POWER FACILITY  

SciTech Connect

The Sodium Reactor Experiment (SRE) was constructed to demonstrate the feasibility of sodium-oooled graphitemoderated reactors for central station power. The operating experience of SRE has provided valuable data for the design of the Hallam Nuclear Power Facillty (HNPF) now under construction. Some of the difficulties found in the SRE, which HNPF will be designed to avoid, are the sodium-sodium intermediate heat exchanger (horizontal position in SRE gave trouble; a vertical position will be used in HNPF), sodium pumps, handling of broken fuel elements, and excessive thermal stresses due to inadequate coolant flow. Other features of HNPF include the addition of an activity monitoring system for the core cover gas, elimination of tetralin for auxiliary cooling of plant equipment, instrumentation of fuel elements, and addition of carbon traps in the primary sodium system. SRE operation has demonstrated unusual reactor stability and capability for rapid power changes. (D.L.C.)

Beeley, R.J.; Mahlmeister, J.E.

1960-01-01T23:59:59.000Z

317

Multiscale Filler Structure in Simplified Industrial Nanocomposite Silica/SBR Systems Studied by SAXS and TEM  

E-Print Network (OSTI)

Simplified silica (Zeosil 1165 MP) and SBR (140k carrying silanol end-groups) nanocomposites have been formulated by mixing of a reduced number of ingredients with respect to industrial applications. The thermo-mechanical history of the samples during the mixing process was monitored and adjusted to identical final temperatures. The filler structure on large scales up to micrometers was studied by transmission electron microscopy (TEM) and very small-angle X-ray scattering (SAXS). A complete quantitative model extending from the primary silica nanoparticle (of radius \\approx 10 nm), to nanoparticles aggregates, up to micrometer-sized branches with typical lateral dimension of 150 nm is proposed. Image analysis of the TEM-pictures yields the fraction of zones of pure polymer, which extend between the branches of a large-scale filler network. This network is compatible with a fractal of average dimension 2.4 as measured by scattering. On smaller length scales, inside the branches, small silica aggregates are present. Their average radius has been deduced from a Kratky analysis, and it ranges between 35 and 40 nm for all silica fractions investigated here (\\phi_si = 8-21% vol.). A central piece of our analysis is the description of the interaggregate interaction by a simulated structure factor for polydisperse spheres representing aggregates. A polydispersity of 30% in aggregate size is assumed, and interactions between these aggregates are described with a hard core repulsive potential. The same distribution in size is used to evaluate the polydisperse form factor. Comparison with the experimental intensity leads to the determination of the average aggregate compacity (assumed identical for all aggregates in the distribution, between 31% and 38% depending on \\phi_si), and thus aggregation number (ca. 45, with a large spread). Because of the effect of aggregate compacity and of pure polymer zones, the volume fraction of aggregates is higher in the branches than \\phi_si. The repulsion between aggregates has a strong effect on the apparent isothermal compressibility: it leads to a characteristic low-q depression, which cannot be interpreted as aggregate mass decrease in our data. In addition, the reinforcement effect of these silica structures in the SBR-matrix is characterized with oscillatory shear and described with a model based on the same aggregate compacity. Finally, our results show that it is possible to analyze the complex structure of interacting aggregates in nanocomposites of industrial origin in a self-consistent and quantitative manner.

Guilhem Baeza; ANNE-CAROLINE GENIX; Christophe Degrandcourt; Laurent Petitjean; Jérémie Gummel; Marc Couty; Julian OBERDISSE

2012-12-20T23:59:59.000Z

318

AN ADVANCED SODIUM-GRAPHITE REACTOR NUCLEAR POWER PLANT  

SciTech Connect

An advanced sodium-cooled, graphite-moderated nuclear power plant is described which utilizes high-pressure, high-temperature steam to generate electricity at a high thermal efficiency. Steam is generated at 2400 psig, superheated to 1050 deg F and, after partial expansion in the turbine, reheated to 1000 deg F. Net thermal efficiency of the plant is 42.3%. In a plant sized to produce a net electrical output of 256 Mw, the estimated cost is 8232/kw. Estimated cost of power generation is 6.7 mills/kwh. In a similar plant with a net electrical output of 530 Mw, the estimated power generating cost is 5.4 mills/ kwh. Most of the components of the plant are within the capability of current technology. The major exception is the fuel material, uranium carbide. Preliminary results of the development work now in progress indicate that uranium carbide would be an excellent fuel for high-temperature reactors, but temperature and burnup limitation have yet to be firmly established. Additional development work is also required on the steam generators. These are the single-barrier type similar to those which will be used in the Enrico Fernri Fast Breeder Reactor plant but produce steam at higher pressure and temperature. Questions also remain regarding the use of nitrogen as a cover gas over sodium at 1200 deg F and compatibility of the materials used in the primary neutron shield. All of these questions are currently under investigation. (auth)

Churchill, J.R.; Renard, J.

1960-03-15T23:59:59.000Z

319

Synaptosomal calcium influx is activated by sodium fluoride  

Science Conference Proceedings (OSTI)

Neuronal calcium channels can be modulated by changes in membrane potential or by activation of channel-associated receptors. The latter may be modulated by guanine nucleotide binding proteins. NaF, which activates guanine nucleotide binding proteins, caused a large stimulation of /sup 45/Ca/sup 2 +/ uptake by synaptosomes prepared from rat brain. Stimulation of /sup 45/Ca/sup 2 +/ influx by NaF (i) was apparent in media containing either 5 mM-K+ or 50 mM-K+, (ii) was slower than the fast-phase of voltage-dependent /sup 45/Ca/sup 2 +/ influx but continued for a longer period of time than did depolarization-induced /sup 45/Ca/sup 2 +/ influx, and (iii) was not mimicked or modified by a number of drugs, including ouabain, dinitrophenol, sodium azide or sodium vanadate. These results are consistent with the hypothesis that NaF activates a guanine nucleotide binding protein associated with receptor-coupled calcium channels, resulting in stimulation of calcium influx.

Jope, R.S.; Lally, K.M.

1988-03-15T23:59:59.000Z

320

TRUEX partitioning studies applied to ICPP sodium-bearing waste  

SciTech Connect

The Idaho Chemical Processing Plant (ICPP), located in southeast Idaho at the USDOE Idaho National Engineering Laboratory, formerly reprocessed highly enriched spent nuclear fuel to recover fissionable uranium. The HLW raffinates from the combined PUREX/REDOX type uranium recovery process were converted to solid oxides (calcine) in a high temperature fluidized bed. Liquid effluents from the calcination process were combined with liquid sodium bearing waste (SBW) generated primarily in conjunction with decontamination activities. Due to the high sodium content in the SBW, this secondary waste stream is not directly amenable to solidification via calcination. Currently, approximately 1.5 millon gallons of liquid SBW are stored at the ICPP in large tanks. Several treatment options for the SBW are currently being considered, including the TRansUranic EXtraction (TRUEX) process developed by Horwitz and co-workers at Argonne National Laboratory (ANL), in preparation for the final disposition of SBW. Herein described are experimental results of radionuclide tracer studies with simulated SBW using the TRUEX process solvent.

Herbst, R.S.; Brewer, K.N.; Law, J.D.; Tranter, T.J.; Todd, T.A.

1994-05-01T23:59:59.000Z

Note: This page contains sample records for the topic "na-sg sodium silica" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

REACTIONS OF SODIUM PEROXIDE WITH COMPONENTS OF LEGACY PLUTONIUM MATERIALS  

Science Conference Proceedings (OSTI)

Plutonium oxide (PuO{sub 2}) calcined at >900 C resists dissolution in nitric acid (HNO{sub 3})-potassium fluoride (KF) solutions, a common method for their dissolution. The Savannah River National Laboratory (SRNL) has developed an alternate method for large samples of PuO{sub 2}-bearing materials using sodium peroxide (Na{sub 2}O{sub 2}) fusion as a pretreatment. The products of the reaction between Na{sub 2}O{sub 2} and PuO{sub 2} have been reported in the literature. As part of the SRNL development effort, additional data about the reaction between Na{sub 2}O{sub 2} and PuO{sub 2} were required. Also needed were data concerning the reaction of Na{sub 2}O{sub 2} with other components that may be present in the feed materials. Sodium peroxide was reacted with aluminum metal (Al), beryllium metal (Be), graphite, potassium chloride (KCl), magnesium chloride (MgCl{sub 2}), and calcium chloride (CaCl{sub 2}). The paper reports and discusses the reaction products of these and related compounds with Na{sub 2}O{sub 2}.

Pierce, R.; Missimer, D.; Crowder, M.

2011-10-04T23:59:59.000Z

322

Sodium fast reactor safety and licensing research plan. Volume I.  

SciTech Connect

This report proposes potential research priorities for the Department of Energy (DOE) with the intent of improving the licensability of the Sodium Fast Reactor (SFR). In support of this project, five panels were tasked with identifying potential safety-related gaps in available information, data, and models needed to support the licensing of a SFR. The areas examined were sodium technology, accident sequences and initiators, source term characterization, codes and methods, and fuels and materials. It is the intent of this report to utilize a structured and transparent process that incorporates feedback from all interested stakeholders to suggest future funding priorities for the SFR research and development. While numerous gaps were identified, two cross-cutting gaps related to knowledge preservation were agreed upon by all panels and should be addressed in the near future. The first gap is a need to re-evaluate the current procedures for removing the Applied Technology designation from old documents. The second cross-cutting gap is the need for a robust Knowledge Management and Preservation system in all SFR research areas. Closure of these and the other identified gaps will require both a reprioritization of funding within DOE as well as a re-evaluation of existing bureaucratic procedures within the DOE associated with Applied Technology and Knowledge Management.

Sofu, Tanju (Argonne National Laboratory, Argonne, IL); LaChance, Jeffrey L.; Bari, R. (Brokhaven National Laboratory Upton, NY); Wigeland, Roald (Idaho National Laboratory, Idaho Falls, ID); Denman, Matthew R.; Flanagan, George F. (Oak Ridge National Laboratory, Oak Ridge, TN)

2012-05-01T23:59:59.000Z

323

Preliminary engineering design of sodium-cooled CANDLE core  

Science Conference Proceedings (OSTI)

The CANDLE burning process is characterized by the autonomous shifting of burning region with constant reactivity and constant spacial power distribution. Evaluations of such critical burning process by using widely used neutron diffusion and burning codes under some realistic engineering constraints are valuable to confirm the technical feasibility of the CANDLE concept and to put the idea into concrete core design. In the first part of this paper, it is discussed that whether the sustainable and stable CANDLE burning process can be reproduced even by using conventional core analysis tools such as SLAROM and CITATION-FBR. As a result, it is certainly possible to demonstrate it if the proper core configuration and initial fuel composition required as CANDLE core are applied to the analysis. In the latter part, an example of a concrete image of sodium cooled, metal fuel, 2000MWt rating CANDLE core has been presented by assuming an emerging inevitable technology of recladding. The core satisfies engineering design criteria including cladding temperature, pressure drop, linear heat rate, and cumulative damage fraction (CDF) of cladding, fast neutron fluence and sodium void reactivity which are defined in the Japanese FBR design project. It can be concluded that it is feasible to design CANDLE core by using conventional codes while satisfying some realistic engineering design constraints assuming that recladding at certain time interval is technically feasible.

Takaki, Naoyuki; Namekawa, Azuma; Yoda, Tomoyuki; Mizutani, Akihiko; Sekimoto, Hiroshi [Department of Nuclear Engineering, Tokai University, Kitakaname, Hiratsuka, Kanagawa 259-1292 (Japan); AISA, Fuchu, Ishioka, Ibaraki 315-0013 (Japan); Research Laboratory for Nuclear Reactors, Tokyo Institute of Technology, Ookayama, Meguro-ku, Tokyo, 152-8550 (Japan)

2012-06-06T23:59:59.000Z

324

Safety evaluation for packaging for 1720-DR sodium-filled tank  

SciTech Connect

Preparations are under way to sell the sodium stored in the 1720-DR tank in the 1720-DR building. This will require that the tank, as well as the 1720-DR facility, be moved to the 300 Area, so that the sodium may be melted and transferred into a railroad tanker car. Because the sodium is a hazardous material and is being shipped in a nonspecification packaging, a safety evaluation for packaging (SEP) is required. This SEP approves the sodium-filled tank for a single shipment from the 105-DR area to the 300 Area.

Mercado, M.S.

1996-03-09T23:59:59.000Z

325

Sodium compatibility studies of low friction carbide coatings for reactor application  

SciTech Connect

Design requirements for low friction materials in FFTF have led to an experimental sodium compatibility program, the objective of which is to select and qualify a low friction coating for the fuel assembly duct load pad. Results are given for chromium carbide and titanium carbide-based coatings on stainless steel exposed to 1160 deg F sodium for several thousand hours. A chromium carbide coating (with a nichrome binder) having an average corrosion rate of approximately 0.25 mpy exhibits optimum sodium compatibility behavior of the materials examined. Both plasma-sprayed chromium carbide and titanium carbide based coatings were found to be unstable when exposed to sodium. (auth)

Whitlow, G.A.; Miller, R.L.; Schrock, S.L.; Wu, P.C.S.

1973-09-01T23:59:59.000Z

326

Sodium-Lithium Ratio In Water Applied To Geothermometry Of Geothermal...  

Open Energy Info (EERE)

Sign Up Search Page Edit with form History Facebook icon Twitter icon Sodium-Lithium Ratio In Water Applied To Geothermometry Of Geothermal Reservoirs Jump to: navigation,...

327

Study of Trona (Sodium Sesquicarbonate) Reactivity with Sulfur Dioxide in a Simulated Flue Gas.  

E-Print Network (OSTI)

??Dry injection of sodium-based sorbents has gained a lot of attention in the last few years. With Dry injection, it is possible to achieve almost… (more)

Srinivasn, Rangesh

2004-01-01T23:59:59.000Z

328

Application of the technology neutral framework to sodium cooled fast reactors.  

E-Print Network (OSTI)

??Sodium cooled fast reactors (SFRs) are considered as a novel example to exercise the Technology Neutral Framework (TNF) proposed in NUREG- 1860. One reason for… (more)

Johnson, Brian C. (Brian Carl)

2010-01-01T23:59:59.000Z

329

Excess consumption of sugar-sweetened beverages and sodium in children and adolescents  

E-Print Network (OSTI)

with 100% juice or water intake Milk intake inverselyOnce water is included with dietary intake, the differenceswater based on heath risks of excessive sodium intake and

Banerjee, Victoria; Dankiewicz, Cheryl

2013-01-01T23:59:59.000Z

330

Sodium Sulfur (NaS) Battery Research in Korea: Part II ...  

Science Conference Proceedings (OSTI)

Abstract Scope, The activities of sodium sulfur (NaS) battery research in Korea ... The presentation was focused on the development of tubular NaS batteries ...

331

Remedial Action Certification Docket - Sodium Reactor Experiment (SRE)  

Office of Legacy Management (LM)

c~-?i-- c~-?i-- I ,3-l Remedial Action Certification Docket - Sodium Reactor Experiment (SRE) .Complex and the Hot Cave Facility (Bldg. 003), Santa Susana ,Fie!d Laboratory, Chatsworth, California ..:'..~::Yerlette Gatl in, MA-232 I am attaching for entry into the Public Document Room, one copy of the N -23 subject documentat ion. These documents are the backup data for the certification that the facilfties are radiologically acceptable for b- unrestricted use as noted in the certification statement published in the &aney Federal Register. Inasmuch as the certification for unrestricted use is 9/2(/85 being published in the Federal Register, it is prudent that the attached documentation also be available to the public. These documents should be retained In accordance with DOE Order 1324.2--disposal schedule 25.

332

Feasibility Study for Vitrification of Sodium-Bearing Waste  

Science Conference Proceedings (OSTI)

Treatment of sodium-bearing waste (SBW) at the Idaho Nuclear Technology and Engineering Center (INTEC) within the Idaho National Engineering and Environmental Laboratory is mandated under a Settlement Agreement between the Department of Energy and the State of Idaho. One of the requirements of the Settlement Agreement is the complete calcination (i.e., treatment) of all SBW by December 31, 2012. One of the proposed options for treatment of SBW is vitrification. This study will examine the viability of SBW vitrification. This study describes the process and facilities to treat the SBW, from beginning waste input from INTEC Tank Farm to the final waste forms. Schedules and cost estimates for construction and operation of a Vitrification Facility are included. The study includes a facility layout with drawings, process description and flow diagrams, and preliminary equipment requirements and layouts.

J. J. Quigley; B. D. Raivo; S. O. Bates; S. M. Berry; D. N. Nishioka; P. J. Bunnell

2000-09-01T23:59:59.000Z

333

THE SODIUM GRAPHITE REACTOR POWER PLANT FOR CPPD  

SciTech Connect

The plant arrangement, component design, and the functions of various systems are described and illustrated. Relative estimated costs of the systems and major components are indicated. The reactor core is designed around requiremouts for 254 thermal megawatts, 950 deg F maximum sodium temperature, stainless steel clad graphite moderator blocks, and low enrichment (0.015 to 0.04 U/sup 235/) uranium fuel elements. The fuel cycle is described for the possible fuel elements. The fuel cost factors are discussed. Burn-up limitations encountered for metallic fuel in the SGR temperature range indicate UO/sub 2/ the more desirable choice. The estimated cost of electrical energy associated with the UO/sub 2/ fuel is given. (auth)

Olson, R.L.; Gerber, R.C.; Gordon, R.B.; Ross-Clunis, H.A.; Stolz, J.F.

1958-10-31T23:59:59.000Z

334

Sodium-Bearing Waste Treatment Alternatives Implementation Study  

SciTech Connect

The purpose of this document is to discuss issues related to the implementation of each of the five down-selected INEEL/INTEC radioactive liquid waste (sodium-bearing waste - SBW) treatment alternatives and summarize information in three main areas of concern: process/technical, environmental permitting, and schedule. Major implementation options for each treatment alternative are also identified and briefly discussed. This report may touch upon, but purposely does not address in detail, issues that are programmatic in nature. Examples of these include how the SBW will be classified with respect to the Nuclear Waste Policy Act (NWPA), status of Waste Isolation Pilot Plant (WIPP) permits and waste storage availability, available funding for implementation, stakeholder issues, and State of Idaho Settlement Agreement milestones. It is assumed in this report that the SBW would be classified as a transuranic (TRU) waste suitable for disposal at WIPP, located in New Mexico, after appropriate treatment to meet transportation requirements and waste acceptance criteria (WAC).

Charles M. Barnes; James B. Bosley; Clifford W. Olsen

2004-07-01T23:59:59.000Z

335

Sodium fast reactor fuels and materials : research needs.  

SciTech Connect

An expert panel was assembled to identify gaps in fuels and materials research prior to licensing sodium cooled fast reactor (SFR) design. The expert panel considered both metal and oxide fuels, various cladding and duct materials, structural materials, fuel performance codes, fabrication capability and records, and transient behavior of fuel types. A methodology was developed to rate the relative importance of phenomena and properties both as to importance to a regulatory body and the maturity of the technology base. The technology base for fuels and cladding was divided into three regimes: information of high maturity under conservative operating conditions, information of low maturity under more aggressive operating conditions, and future design expectations where meager data exist.

Denman, Matthew R.; Porter, Douglas (Idaho National Laboratory, Idaho Falls, ID); Wright, Art (Argonne National Laboratory Argonne, IL); Lambert, John (Argonne National Laboratory Argonne, IL); Hayes, Steven (Idaho National Laboratory, Idaho Falls, ID); Natesan, Ken (Argonne National Laboratory Argonne, IL); Ott, Larry J. (Oak Ridge National Laboratory, Oak Ridge, TN); Garner, Frank (Radiation Effects Consulting. Richland, WA); Walters, Leon (Advanced Reactor Concepts, Idaho Falls, ID); Yacout, Abdellatif (Argonne National Laboratory Argonne, IL)

2011-09-01T23:59:59.000Z

336

Sodium sulfur battery design for the ETX-II  

Science Conference Proceedings (OSTI)

Chloride Silent Power Limited (CSPL) has developed a number of laboratory and field test batteries in support of its sodium sulfur development program. The most demanding of these test batteries is being developed for the Ford ETX-II electric vehicle, under a three year contract from the US Department of Energy. A major milestone of this program is to build and test an Intermediate Deliverable (ID) battery which is a fully representative section of the final battery. This will allow the performance predictions to be evaluated using an operational battery before the final battery is built and delivered. The performance predictions for the battery have been made and are described in this paper. The Intermediate Deliverable Battery, representing one third of the full battery both electrically and thermally, has now been built and preliminary test results are available.

Mangan, M.F.; Leadbetter, A.

1989-01-01T23:59:59.000Z

337

THE SODIUM GRAPHITE REACTOR: TOMMORROW'S POWER PLANT  

SciTech Connect

A description is given of the Advanced Sodium Graphite Reactor Power Plant, including the reactor, heat transfer systems, generatirg plant, control systems, and the economics of producing 256 Mw(e). The safety of this design is due to its unusually low operating pressure, absence of chemically incompatible materials in the core, and excellent stability under atatic and dynamic conditions. The reactor is being constructed at Hallam, Nebraska, at a probable cost of 0 to 0/kw, exclusive of the first core costs. The 151 fuel elements of uranium carbide are enriched to 2.75 at.% U/sup 235/ and clad in stainless steel. The average thermal neutron flux in the fuel is 8 x 10/sup 13/ n/cm/sup 2/sec. (B.O.G.)

Beeley, R.J.; Lowell, E.G.; Polak, H.; Renard, J.

1960-04-25T23:59:59.000Z

338

Diffusion bonding resistant valve development for sodium service  

SciTech Connect

Unanticipated functional failures occurred in valves undergoing containment integrity testing for liquid sodium service. The failures resulted from diffusion bonding of the Stellite 6B valve plug to the Type 316 stainless steel (SS) seat. As a result of these failures, a valve development program was undertaken. A modified valve incorporating a Tribaloy 800 plug showed significant improvement in resistance to diffusion bonding but still failed after long term exposure in a closed position. A second modified valve using Tribaloy 800 in both the valve plug and seat successfully resisted diffusion bonding failure. This paper reports the details of the testing and posttest valve examinations. The results of scanning electron microscopy, dispersive x-ray spectrometry, and metallography provide the characteristics of the valve failures. Limitations of the various valve designs are also discussed.

Crandall, D.L.; Low, J.O.; Chung, D.T.; Loop, R.B.

1984-04-16T23:59:59.000Z

339

Design Considerations for Economically Competitive Sodium Cooled Fast Reactors  

SciTech Connect

The technological viability of sodium cooled fast reactors (SFR) has been established by various experimental and prototype (demonstration) reactors such as EBR-II, FFTF, Phénix, JOYO, BN-600 etc. However, the economic competitiveness of SFR has not been proven yet. The perceived high cost premium of SFRs over LWRs has been the primary impediment to the commercial expansion of SFR technologies. In this paper, cost reduction options are discussed for advanced SFR designs. These include a hybrid loop-pool design to optimize the primary system, multiple reheat and intercooling helium Brayton cycle for the power conversion system and the potential for suppression of intermediate heat transport system. The design options for the fully passive decay heat removal systems are also thoroughly examined. These include direct reactor auxiliary cooling system (DRACS), reactor vessel auxiliary cooling system (RVACS) and the newly proposed pool reactor auxiliary cooling system (PRACS) in the context of the hybrid loop-pool design.

Hongbin Zhang; Haihua Zhao

2009-05-01T23:59:59.000Z

340

Quantitative measurement of atomic sodium in the plume of a single burning coal particle  

Science Conference Proceedings (OSTI)

The release of volatile sodium during coal combustion is a significant factor in the fouling and corrosion of heat transfer surfaces within industrial coal-fired boilers. A method for measuring the temporal release of atomic sodium from a single coal particle is described. Laser absorption was used to calibrate laser-induced fluorescence measurements of atomic sodium utilising the sodium D1 line (589.59 nm) in a purpose-designed flat flame environment. The calibration was then applied to planar laser-induced fluorescence measurements of sodium atoms in the plume from a single Victorian brown coal particle (53 mg) suspended within the flat flame. The peak concentration of atomic sodium was approximately 64.1 ppb after 1080.5 s, which appears to correspond to the end of char combustion. To our knowledge this is the first in situ quantitative measurement of the concentration field of atomic sodium in the plume above a burning particle. A simple kinetic model has been used to estimate the rate of sodium decay in the post-flame gases. Comparison of the estimated and measured decay rates showed reasonable agreement. (author)

van Eyk, P.J.; Ashman, P.J.; Alwahabi, Z.T. [Cooperative Research Centre for Clean Power from Lignite, School of Chemical Engineering, The University of Adelaide, South Australia 5005 (Australia); Nathan, G.J. [School of Mechanical Engineering, The University of Adelaide, South Australia 5005 (Australia)

2008-11-15T23:59:59.000Z

Note: This page contains sample records for the topic "na-sg sodium silica" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Sodium Chloride Hideout In a Simulated Steam Generator Tube and Tube Support Place Crevice  

Science Conference Proceedings (OSTI)

Localized corrosion of steam generator (SG) tubing in PWRs has been a serious problem that limits the life of this component. Preliminary measurements of sodium chloride hideout in simulated PWR SG crevices have shown that hideout rate increases with heat flux and concentration of sodium chloride in the bulk water.

1998-06-30T23:59:59.000Z

342

Sodium Heat Engine Development Program. Phase 1, Final report  

DOE Green Energy (OSTI)

The Sodium Heat Engine (SHE) is an efficient thermoelectric conversion device which directly generates electricity from a thermally regenerative electrochemical cell that relies on the unique conduction properties of {beta}{double_prime}-alumina solid electrolyte (BASE). Laboratory models of a variety of SHE devices have demonstrated the feasibility and efficiency of the system, engineering development of large prototype devices has been slowed by a series of materials and fabrication problems. Failure of the electrolyte tubes has been a recurring problem and a number of possible causes have been postulated. To address these issues, a two-phase engineering development program was undertaken. This report summarizes the final results of the first phase of the program, which included extensive materials characterization activities, a study of applicable nondestructive evaluation methods, an investigation of possible stress states that would contribute to fracture, and certain operational issues associated with the electromagnetic pumps used in the SHE prototype. Mechanical and microstructural evaluation of commercially obtained BASE tubes revealed that they should be adequate for SHE applications and that sodium exposure produced no appreciable deleterious strength effects. Processing activities to produce a more uniform and smaller grain size for the BASE tubes were completed using isostatic pressing, extrusion, and slip casting. Green tubes were sintered by conventional and microwave plasma methods. Of particular interest is the residual stress state in the BASE tubes, and both analysis and nondestructive evaluation methods were employed to evaluate these stresses. X-ray and neutron diffraction experiments were performed to determine the bulk residual stresses in commercially fabricated BASE tubes; however, tube-to-tube variations and variations among the various methods employed did not allow formulation of a definitive definition of the as-fabricated stress state.

Singh, J.P.; Kupperman, D.S.; Majumdar, S.; Dorris, S.; Gopalsami, N.; Dieckman, S.L.; Jaross, R.A.; Johnson, D.L.; Gregar, J.S.; Poeppel, R.B.; Raptis, A.C.; Valentin, R.A.

1992-01-01T23:59:59.000Z

343

105-DR Large Sodium Fire Facility closure plan. Revision 1  

SciTech Connect

The Hanford Site, located northwest of the city of Richland, Washington, houses reactors, chemical-separation systems, and related facilities used for the production of special nuclear materials, and activities associated with nuclear energy development. The 105-DR Large Sodium Fire Facility (LSFF), which was in operation from about 1972 to 1986, was a research laboratory that occupied the former ventilation supply room on the southwest side of the 105-DR Reactor facility. The LSFF was established to provide a means of investigating fire and safety aspects associated with large sodium or other metal alkali fires in the liquid metal fast breeder reactor (LMFBR) facilities. The 105-DR Reactor facility was designed and built in the 1950`s and is located in the 100-D Area of the Hanford Site. The building housed the 105-DR defense reactor, which was shut down in 1964. The LSFF was initially used only for engineering-scale alkali metal reaction studies. In addition, the Fusion Safety Support Studies program sponsored intermediate-size safety reaction tests in the LSFF with lithium and lithium lead compounds. The facility has also been used to store and treat alkali metal waste, therefore the LSFF is subject to the regulatory requirements for the storage and treatment of dangerous waste. Closure will be conducted pursuant to the requirements of the Washington Administrative Code (WAC) 173-303-610. This closure plan presents a description of the facility, the history of waste managed, and the procedures that will be followed to close the LSFF as an Alkali Metal Treatment Facility. No future use of the LSFF is expected.

Not Available

1993-05-01T23:59:59.000Z

344

Quartz dissolution and silica deposition in hot-dry-rock geothermal systems  

DOE Green Energy (OSTI)

The kinetics of quartz dissolution control the produced fluid dissolved silica concentration in geothermal systems in which the downhole residence time is finite. The produced fluid of the Phase I, Run Segment 5 experimental Hot Dry Rock (HDR) geothermal system at Fenton Hill, NM, was undersaturated with respect to quartz in one pass through the reservoir, suggesting that the rate of granite dissolution governed the outlet dissolved silica concentration in this system. The literature data for the rate of quartz dissolution in water from 65 to 625/sup 0/C is correlated using an empirical rate law which is first order in quartz surface area and degree of undersaturation of the fluid. The Arrhenius plot (ln k vs T/sup -1/) is linear over eight orders of magnitude of the rate constant, verifying the validity of the proposed rate expression. Carefully performed quartz dissolution experiments in the present study duplicated the literature data and completed the data base in the temperature range from 150 to 250/sup 0/C. Identical experiments using crushed granite indicate that the rate of quartz dissolution in the presence of granite could be as much as 1 to 2 orders of magnitude faster than the rates observed in the pure quartz experiments. A temperature dependent HDR reservoir model incorporates the quartz dissolution rate law to simulate the dissolved silica behavior during the Fenton Hill Run Segment 5 experiment. For this low-permeability, fracture-dominated reservoir, the assumptions of one-dimensional plug flow through a vertically-inclined rectangular fracture and one-dimensional rock heat conduction perpendicular to the direction of flow are employed. These simplifications lead to an analytical solution for the temperature field in the reservoir.

Robinson, B.A.

1982-07-01T23:59:59.000Z

345

Self-Assembled Mercaptan on Mesoporous Silica (SAMMS) technology of mercury removal and stabilization  

SciTech Connect

This paper explains the technology developed to produce Self-Assembled Mercaptan on Mesoporous Silica (SAMMS) for mercury removal from aqueous wastewater and from organic wastes. The characteristics of SAMMS materials, including physical characteristics and mercury loading, and its application for mercury removal and stabilization are discussed. Binding kinetics and binding speciations are reported. Preliminary cost estimates are provided for producing SAMMS materials and for mercury removal from wastewater. The characteristics of SAMMS in mercury separation were studied at PNNL using simulated aqueous tank wastes and actual tritiated pump oil wastes from Savannah River Site; preliminary results are outlined. 47 refs., 16 figs., 16 tabs.

Feng, Xiangdong; Liu, Jun; Fryxell, G.E. [and others

1997-09-01T23:59:59.000Z

346

Atomic structure of Au-nanoparticles on silica support by X-ray PDF study  

SciTech Connect

We investigated the atomic structure of gold nanoparticles with an average size of 5 nm in diameter, supported by silica. We used high-energy X-ray diffraction and the atomic pair distribution function (PDF) to probe the local atomic structure. Measurements were performed from 25 to 950 C. The structure is approximately fcc in average but exhibits small distortions. The structural distortion increases with the temperature and could be related to the catalytic activity of gold nanoparticles. Above 425 C, rapid particle growth and coalescence were observed.

Dmowski, W. [University of Tennessee, Knoxville (UTK); Yin, Hongfeng [ORNL; Dai, Sheng [ORNL; Overbury, Steven {Steve} H [ORNL; Egami, T. [University of Tennessee, Knoxville (UTK)

2010-01-01T23:59:59.000Z

347

Atomic Structure of Au Nanoparticles on a Silica Support by an X-ray PDF Study  

SciTech Connect

We investigated the atomic structure of gold nanoparticles with an average size of {approx}5 nm in diameter, supported by silica. We used high-energy X-ray diffraction and the atomic pair distribution function (PDF) to probe the local atomic structure. Measurements were performed from 25 to 950 C. The structure is approximately fcc in average but exhibits small distortions. The structural distortion increases with the temperature and could be related to the catalytic activity of gold nanoparticles. Above 425 C, rapid particle growth and coalescence were observed.

Dmowski, Wojtek; Yin, Hongfeng; Dai, Sheng; Overbury, Steven H.; Egami, Takeshi (Tennessee-K); (ORNL)

2010-05-04T23:59:59.000Z

348

Characterization of the polymer-filler interface in (gamma)-irradiated silica-reinforced polysiloxane composites  

DOE Green Energy (OSTI)

The changes in hydrogen bonding at the interface of silica-reinforced polysiloxane composites due to aging in gamma radiation environments were examined in this study. Solvent swelling was utilized to determine the individual contributions of the matrix polymer and polymer-filler interactions to the overall crosslink density. The results show how the polymer-filler hydrogen bonding dominates the overall crosslink density of the material. Air irradiated samples displayed decreased hydrogen bonding at the polymer-filler interface, while vacuum irradiation revealed the opposite effect.

Chien, A T; Balazs, B; LeMay, J

2000-04-03T23:59:59.000Z

349

Mesoporous Silica Nanomaterials for Applications in Catalysis, Sensing, Drug Delivery and Gene Transfection  

SciTech Connect

The central theme of this dissertation is represented by the versatility of mesoporous silica nanomaterials in various applications such as catalysis and bio-applications, with main focus on biological applications of Mesoporous Silica Nanospheres (MSN). The metamorphosis that we impose to these materials from catalysis to sensing and to drug and gene delivery is detailed in this dissertation. First, we developed a synthetic method that can fine tune the amount of chemically accessible organic functional groups on the pores surface of MSN by exploiting electrostatic and size matching between the cationic alkylammonium head group of the cetyltrimethylammonium bromide (CTAB) surfactant and various anionic organoalkoxysilane precursors at the micelle-water interface in a base-catalyzed condensation reaction of silicate. Aiming nature imitation, we demonstrated the catalytic abilities of the MSNs, We utilized an ethylenediamine functional group for chelating Cu{sup 2+} as a catalytic functional group anchored inside the mesopores. Thus, a polyalkynylene-based conducting polymer (molecular wire) was synthesized within the Cu-functionalized MSNs silica catalyst. For sensing applications, we have synthesized a poly(lactic acid) coated mesoporous silica nanosphere (PLA-MSN) material that serves as a fluorescence sensor system for detection of amino-containing neurotransmitters in neutral aqueous buffer. We exploited the mesoporosity of MSNs for encapsulating pharmaceutical drugs. We examined bio-friendly capping molecules such as polyamidoamine dendrimers of generations G2 to G4, to prevent the drug leaching. Next, the drug delivery system employed MSNs loaded with Doxorubicin, an anticancer drug. The results demonstrated that these nano-Trojan horses have ability to deliver Doxorubicin to cancer cells and induce their death. Finally, to demonstrate the potential of MSN as an universal cellular transmembrane nanovehicle, we anchored positively charged dendrimers on the surface of MSN and utilize them to complex cationic DNA. The p-EGFP-CI gene-coated MSN nanocomposite was able to transfect cancer cell lines, such as human HeLa and CHO cancer cell lines. The gene carrier ability of MSNs was further proved by transfecting primary cells and cotransfecting of two different genes in cancer cell lines. In sum, MSN are versatile partners in several types of applications.

Daniela Rodica Radu

2005-12-19T23:59:59.000Z

350

Femtosecond laser pulse filamentation under anomalous dispersion in fused silica. Part 1. Numerical investigation  

SciTech Connect

We report the results of investigation of femtosecond laser pulse filamentation in fused silica by varying the wavelength in the range from 800 to 2300 nm. It is shown that in the case of the anomalous group-velocity dispersion, a sequence of 'light bullets' with a high spatial and temporal localisation of the light field is formed along the filament. The relation of the formation and propagation of light bullets with the formation of an isolated anti-Stokes wing of the supercontinuum spectrum is established. (nonlinear optical phenomena)

Smetanina, E O; Kompanets, V O; Chekalin, Sergei V; Kandidov, V P

2012-10-31T23:59:59.000Z

351

Silica Deposition in Field and Laboratory Thermal Tests of Yucca Mountain Tuff  

SciTech Connect

A field thermal test was conducted by the Yucca Mountain Site Characterization Project to observe changes in the Topopah Spring Tuff middle nonlithophysal zone geohydrologic system due to thermal loading. A laboratory-scale crushed-tuff hydrothermal column test was used to investigate the tuff as a potential construction material within a nuclear-waste repository. Results of similar column tests have been cited as indications that silica deposition would plug the rock fractures above a repository and create unfavorable drainage conditions. Data from field and laboratory tests are used here to predict the magnitude of fracture sealing. For the crushed-tuff column test, a one-meter-high column was packed with crushed tuff to a porosity of about 50%. Water filling the lowermost 10 cm of the column was boiled and the vapor condensed at the top of the column, percolating down to the boiling zone. After 100 days, intergranular pore space in the saturated portion of the column was almost filled with amorphous silica. The Drift Scale Test at Yucca Mountain is a heating test in the unsaturated zone. It consists of a four-year heating phase, now complete, followed by a four-year cooling phase. Heaters in a 60-m-long drift and in the adjacent rock have heated the drift walls to 200 C. As the rock was heated, fluids naturally present in the rock migrated away from the heat sources. A boiling zone now separates an inner dry-out zone from an outer condensation zone. A heat-pipe region exists in the outer margin of the boiling zone above the heated drift. Amorphous silica coatings up to a few micrometers thick were deposited in this region. Deposits were observed in less than 10% of the fractures in the heat pipe region. Drift-scale test results yield a silica deposition rate of about 250 {micro}m/1000 years in 10% of the fractures in the heat-pipe region. We did not calculate deposition rates from our column test, but a rate of 9.1 mm/1000 years in all fractures of the heat-pipe region is predicted by Sun and Rimstidt (2002) from the results of a similar test. We believe the rate based on field-test observations is a better prediction because the field test more closely resembles the expected environment in a repository. Rates based on column-test results may be reasonable for local zones of preferred fluid flow.

S.S. Levy; S.J. Chipera; M.G. Snow

2002-08-30T23:59:59.000Z

352

Acidity and catalytic activity of zeolite catalysts bound with silica and alumina  

E-Print Network (OSTI)

Zeolites ZSM-5 (SiO2/Al2O3=30~280) and Y(SiO2/Al2O3=5.2~80) are bound with silica gel (Ludox HS-40 and Ludox AS-40) and alumina (?- Al2O3 and boehmite) by different binding methods, namely, gel-mixing, powder-mixing and powder-wet-mixing methods. The acidities of the bound catalysts and the zeolite powder are determined by NH3-TPD and FTIR. The textures of these catalysts are analyzed on a BET machine with nitrogen as a probe molecule. The micropore surface area and micropore volume are determined by t-plot method. Micropore volume distribution is determined by Horvath-Kawazoe approach with a cylindrical pore model. Mesopore volume distribution is determined by BJH method from the nitrogen desorption isotherm. Silica from the binder may react with extra-framework alumina in zeolites to form a new protonic acid. SiO2-bound catalysts have less strong acidity, Bronsted acidity and Lewis acidity than the zeolite powder. Also, the strength of strong acid sites of the zeolites is reduced when silica is embedded. Micropore surface area and micropore volume are reduced by about 19% and 18%, respectively, indicating some micropores of ZSM-5 are blocked on binding with silica. SiO2-bound ZSM-5 catalysts have less catalytic activity for butane transformation (cracking and disproportionation) and ethylene oligomerization than ZSM-5 powder. When alumina is used as a binder, both the total acid sites and Lewis acid sites are increased. Micropore surface area and micropore volume of ZSM-5 powder are reduced by 26% and 23%, respectively, indicating some micropores of ZSM-5 are blocked by the alumina binder. Alumina-bound catalysts showed a lower activity for butane transformation and ethylene oligomerization than ZSM-5 powder. Alkaline metals content in the binder is a crucial factor that influences the acidity of a bound catalyst. The metal cations neutralize more selectively Bronsted acid sites than Lewis acid sites. Alkaline metal cations in the binder and micropore blockage cause the bound catalysts to have a lower catalytic activity than the zeolite powder.

Wu, Xianchun

2003-12-01T23:59:59.000Z

353

Comparison of artificial neural network and fuzzy logic models for prediction of long-term compressive strength of silica fume concrete  

Science Conference Proceedings (OSTI)

In this study, an artificial neural network (ANN) and fuzzy logic (FL) study were developed to predict the compressive strength of silica fume concrete. A data set of a laboratory work, in which a total of 48 concretes were produced, was utilized in ... Keywords: Compressive strength, Concrete, Fuzzy logic, Neural networks, Silica fume

Fatih Özcan; Cengiz D. Ati?; Okan Karahan; Erdal Uncuo?lu; Harun Tanyildizi

2009-09-01T23:59:59.000Z

354

SILICA GEL BEHAVIOR UNDER DIFFERENT EGS CHEMICAL AND THERMAL CONDITIONS: AN EXPERIMENTAL STUDY  

Science Conference Proceedings (OSTI)

Fractures and fracture networks are the principal pathways for migration of water and contaminants in groundwater systems, fluids in enhanced geothermal systems (EGS), oil and gas in petroleum reservoirs, carbon dioxide leakage from geological carbon sequestration, and radioactive and toxic industrial wastes from underground storage repositories. When dealing with EGS fracture networks, there are several major issues to consider, e.g., the minimization of hydraulic short circuits and losses of injected geothermal fluid to the surrounding formation, which in turn maximize heat extraction and economic production. Gel deployments to direct and control fluid flow have been extensively and successfully used in the oil industry for enhanced oil recovery. However, to the best of our knowledge, gels have not been applied to EGS to enhance heat extraction. In-situ gelling systems can either be organic or inorganic. Organic polymer gels are generally not thermostable to the typical temperatures of EGS systems. Inorganic gels, such as colloidal silica gels, however, may be ideal blocking agents for EGS systems if suitable gelation times can be achieved. In the current study, we explore colloidal silica gelation times and rheology as a function of SiO{sub 2} concentration, pH, salt concentration, and temperature, with preliminary results in the two-phase field above 100 C. Results at 25 C show that it may be possible to choose formulations that will gel in a reasonable and predictable amount of time at the temperatures of EGS systems.

Hunt, J D; Ezzedine, S M; Bourcier, W; Roberts, S

2012-01-19T23:59:59.000Z

355

Highly ordered Zn-doped mesoporous silica: An efficient catalyst for transesterification reaction  

Science Conference Proceedings (OSTI)

Designing highly ordered material with nanoscale periodicity is of great significance in the field of solid state chemistry. Herein, we report the synthesis of highly ordered 2D-hexagonal mesoporous zinc-doped silica using a mixture of anionic and cationic surfactants under hydrothermal conditions. Powder XRD, N{sub 2} sorption, TEM analysis revealed highly ordered 2D-hexagonal arrangements of the pores with very good surface area (762 m{sup 2} g{sup -1}) in this Zn-rich mesoporous material. Chemical analysis shows very high loading of zinc (ca. 12.0 wt%) in the material together with retention of hexagonal pore structure. Interestingly, high temperature calcination resulted into zinc silicate phase, unlike any ZnO phase, which otherwise is expected under heat treatments. High surface area together with Zn loading in this mesoporous material has been found useful for the catalytic activity of the materials in the acid-catalyzed transesterification reactions of various esters under mild liquid phase conditions. - Graphical abstract: Zn-rich 2D-hexagonal mesoporous materials are synthesized hydrothermally, which show very good catalytic activity in the transesterification reaction under mild liquid phase reaction conditions. Highlights: > Zn-rich 2D-hexagonal mesoporous silica. > High surface area material. > Efficient catalyst in liquid phase transesterification reaction. > Biodiesel production.

Pal, Nabanita; Paul, Manidipa [Department of Materials Science, Indian Association for the Cultivation of Science, Jadavpur, Kolkata 700032 (India); Bhaumik, Asim, E-mail: msab@iacs.res.in [Department of Materials Science, Indian Association for the Cultivation of Science, Jadavpur, Kolkata 700032 (India)

2011-07-15T23:59:59.000Z

356

Study of a Threshold Cherenkov Counter Based on Silica Aerogels with Low Refractive Indices  

E-Print Network (OSTI)

To identify $\\pi^{\\pm}$ and $K^{\\pm}$ in the region of $1.0\\sim 2.5$ GeV/c, a threshold Cherenkov counter equipped with silica aerogels has been investigated. Silica aerogels with a low refractive index of 1.013 have been successfully produced using a new technique. By making use of these aerogels as radiators, we have constructed a Cherenkov counter and have checked its properties in a test beam. The obtained results have demonstrated that our aerogel was transparent enough to make up for loss of the Cherenkov photon yield due to a low refractive index. Various configurations for the photon collection system and some types of photomultipliers, such as the fine-mesh type, for a read out were also tested. From these studies, our design of a Cherenkov counter dedicated to $\\pi / K$ separation up to a few GeV/c %in the momentum range of $1.0 \\sim 2.5$ GeV/c with an efficiency greater than $90$ \\% was considered.

I. Adachi et al

1994-12-13T23:59:59.000Z

357

Power scaling analysis of fiber lasers and amplifiers based on non-silica materials  

SciTech Connect

A developed formalism for analyzing the power scaling of diffraction limited fiber lasers and amplifiers is applied to a wider range of materials. Limits considered include thermal rupture, thermal lensing, melting of the core, stimulated Raman scattering, stimulated Brillouin scattering, optical damage, bend induced limits on core diameter and limits to coupling of pump diode light into the fiber. For conventional fiber lasers based upon silica, the single aperture, diffraction limited power limit was found to be 36.6kW. This is a hard upper limit that results from an interaction of the stimulated Raman scattering with thermal lensing. This result is dependent only upon physical constants of the material and is independent of the core diameter or fiber length. Other materials will have different results both in terms of ultimate power out and which of the many limits is the determining factor in the results. Materials considered include silica doped with Tm and Er, YAG and YAG based ceramics and Yb doped phosphate glass. Pros and cons of the various materials and their current state of development will be assessed. In particular the impact of excess background loss on laser efficiency is discussed.

Dawson, J W; Messerly, M J; Heebner, J E; Pax, P H; Sridharan, A K; Bullington, A L; Beach, R J; Siders, C W; Barty, C P; Dubinskii, M

2010-03-30T23:59:59.000Z

358

High resolution transmission electron microscopy of melamine-formaldehyde aerogels and silica aerogels  

Science Conference Proceedings (OSTI)

The goal of the high resolution transmission electron microscopy (HRTEM) was to image the structure of two tetramethyl orthosilicate (TMOS) and two melamine-formaldehyde (MF) aerogels at the single polymer chain level{sup 1,2}. With this level of structural resolution we hoped to interrelate each aerogel's structure with its physical properties and its method of synthesis. Conventional single-step base catalysed TMOS aerogels show strings of spheroidal particles linked together with minimal necking. The spheroidal particles range from 86--132 {Angstrom} and average 113{plus minus}10 {Angstrom} in diameter{sup 2}. In contrast the TMOS aerogels reported on here were made by a two step method. After extended silica chains are grown in solution under acidic conditions with a substoichiometric amount of water, the reaction is stopped and the methanol hydrolysed from TMOS is removed. Then base catalysis and additional water are added to cause gel formation is a nonalcoholic solvent. The MF aerogels were prepared for HRTEM by fracturing them on a stereo microscope stage with razor knife so that fractured pieces with smooth flat surfaces could be selected for platinum-carbon replication. The two silica (TMOS) aerogels were both transparent and difficult to see. These aerogels were fractured on a stereo microscope stage with tweezers. 6 refs., 4 figs.

Ruben, G.C. (Dartmouth Coll., Hanover, NH (United States). Dept. of Biological Sciences)

1991-09-01T23:59:59.000Z

359

Highly ordered magnetic mesoporous silicas for effective elimination of carbon monoxide  

Science Conference Proceedings (OSTI)

Catalysts based on crystalline nanoparticles of Fe metal supported on mesoporous silica have been developed. The synthetic process involves hydrogen reduction processing for high abundant Fe metal nanoparticles within the mesopores, in which impregnated Fe salt in the inner nanopores of mesoporous silica is thermally treated under hydrogen at 500 Degree-Sign C. Detailed characterization was achieved by XRD, XPS, BET, and HR-TEM techniques. The catalytic efficiency was demonstrated as a function of the used amounts and reaction time. The results show that more than 90% of the carbon monoxide was eliminated at room temperature during a period 80 min with 0.5 g of catalyst. - Graphical abstract: Strategy for the preparation of highly abundant Fe nanoparticle embedded MS catalyst by hydrogen reduction process and HR-TEM images of cross-sectional and top view. Highlights: Black-Right-Pointing-Pointer MS based heterogeneous catalyst with Fe nanoparticles were demonstrated for CO elimination. Black-Right-Pointing-Pointer Highly Fe nanoparticle embedded MS catalyst prepared by hydrogen reduction process. Black-Right-Pointing-Pointer Systematic characterization was achieved by XRD, XPS, BET, and HR-TEM analyses. Black-Right-Pointing-Pointer More than 90% of the CO was eliminated at RT during 80 min with 0.5 g of catalyst.

Lee, Jiho [Korea Institute of Ceramic Engineering and Technology, Seoul 153-801 (Korea, Republic of); Department of Chemistry, Inha University, Incheon 402-751 (Korea, Republic of); Ho Chang, Jeong, E-mail: jhchang@kicet.re.kr [Korea Institute of Ceramic Engineering and Technology, Seoul 153-801 (Korea, Republic of)

2012-04-15T23:59:59.000Z

360

Research on Active Power Factor Correction of the Electronic Ballast for High-Pressure Sodium Lamps Based on L6563  

Science Conference Proceedings (OSTI)

In the recent years, there has been a growing interest in the design of high-pressure sodium lamp electronic ballast. Two measures are proposed to improve the power factor of high-pressure sodium lamp electronic ballasts from the definition of harmonic ... Keywords: high-pressure sodium lamps, electronic ballast, active power factor correction, L6563

Sun Jing

2010-06-01T23:59:59.000Z

Note: This page contains sample records for the topic "na-sg sodium silica" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

TRUEX partitioning from radioactive ICPP sodium bearing waste  

SciTech Connect

The Idaho Chemical Processing Plant (ICPP) located at the Idaho National Engineering Laboratory in Southeast Idaho is currently evaluating several treatment technologies applicable to waste streams generated over several decades of-nuclear fuel reprocessing. Liquid sodium bearing waste (SBW), generated primarily during decontamination activities, is one of the waste streams of interest. The TRansUranic EXtraction (TRUEX) process developed at Argonne National Laboratory is currently being evaluated to separate the actinides from SBW. On a mass basis, the amount of the radioactive species in SBW are low relative to inert matrix components. Thus, the advantage of separations is a dramatic decrease in resulting volumes of high activity waste (HAW) which must be dispositioned. Numerous studies conducted at the ICPP indicate the applicability of the TRUEX process has been demonstrated; however, these studies relied on a simulated SBW surrogate for the real waste. Consequently, a series of batch contacts were performed on samples of radioactive ICPP SBW taken from tank WM-185 to verify that actual waste would behave similarly to the simulated waste. The test results with SBW from tank WM-185 indicate the TRUEX solvent effectively extracts the actinides from the samples of actual waste. Gross alpha radioactivity, attributed predominantly to Pu and Am, was reduced from 3.14E+04 dps/mL to 1.46 dps/mL in three successive batch contacts with fresh TRUEX solvent. This reduction corresponds to a decontamination factor of DF = 20,000 or 99.995% removal of the gross a activity in the feed. The TRUEX solvent also extracted the matrix components Zr, Fe, and Hg to an appreciable extent (D{sub Zr} > 10, D{sub Fe} {approx} 2, D{sub Hg} {approx}6). Iron co-extracted with the actinides can be successfully scrubbed from the organic with 0.2 M HNO{sub 3}. Mercury can be selectively partitioned from the actinides with either sodium carbonate or nitric acid ({ge} 5 M HNO{sub 3}) solutions.

Herbst, R.S.; Brewer, K.N.; Tranter, T.J.; Todd, T.A.

1995-03-01T23:59:59.000Z

362

Environmental, health, and safety issues of sodium-sulfur batteries for electric and hybrid vehicles  

DOE Green Energy (OSTI)

This report examines the shipping regulations that govern the shipment of dangerous goods. Since the elemental sodium contained in both sodium-sulfur and sodium-metal-chloride batteries is classified as a dangerous good, and is listed on both the national and international hazardous materials listings, both national and international regulatory processes are considered in this report The interrelationships as well as the differences between the two processes are highlighted. It is important to note that the transport regulatory processes examined in this report are reviewed within the context of assessing the necessary steps needed to provide for the domestic and international transport of sodium-beta batteries. The need for such an assessment was determined by the Shipping Sub-Working Group (SSWG) of the EV Battery Readiness Working Group (Working Group), created in 1990. The Working Group was created to examine the regulatory issues pertaining to in-vehicle safety, shipping, and recycling of sodium-sulfur batteries, each of which is addressed by a sub-working group. The mission of the SSWG is to establish basic provisions that will ensure the safe and efficient transport of sodium-beta batteries. To support that end, a proposal to the UN Committee of Experts was prepared by the SSWG, with the goal of obtaining a proper shipping name and UN number for sodium-beta batteries and to establish the basic transport requirements for such batteries (see the appendix for the proposal as submitted). It is emphasized that because batteries are large articles containing elemental sodium and, in some cases, sulfur, there is no existing UN entry under which they can be classified and for which modal transport requirements, such as the use of packaging appropriate for such large articles, are provided for. It is for this reason that a specific UN entry for sodium-beta batteries is considered essential.

Hammel, C.J.

1992-09-01T23:59:59.000Z

363

Sodium-bearing Waste Treatment Technology Evaluation Report  

SciTech Connect

Sodium-bearing waste (SBW) disposition is one of the U.S. Department of Energy (DOE) Idaho Operation Office’s (NE-ID) and State of Idaho’s top priorities at the Idaho National Engineering and Environmental Laboratory (INEEL). The INEEL has been working over the past several years to identify a treatment technology that meets NE-ID and regulatory treatment requirements, including consideration of stakeholder input. Many studies, including the High-Level Waste and Facilities Disposition Environmental Impact Statement (EIS), have resulted in the identification of five treatment alternatives that form a short list of perhaps the most appropriate technologies for the DOE to select from. The alternatives are (a) calcination with maximum achievable control technology (MACT) upgrade, (b) steam reforming, (c) cesium ion exchange (CsIX) with immobilization, (d) direct evaporation, and (e) vitrification. Each alternative has undergone some degree of applied technical development and preliminary process design over the past four years. This report presents a summary of the applied technology and process design activities performed through February 2004. The SBW issue and the five alternatives are described in Sections 2 and 3, respectively. Details of preliminary process design activities for three of the alternatives (steam reforming, CsIX, and direct evaporation) are presented in three appendices. A recent feasibility study provides the details for calcination. There have been no recent activities performed with regard to vitrification; that section summarizes and references previous work.

Charles M. Barnes; Arlin L. Olson; Dean D. Taylor

2004-05-01T23:59:59.000Z

364

High-temperature sodium nickel chloride battery for electric vehicles  

DOE Green Energy (OSTI)

Although the sodium-nickel chloride cell couple has a high voltage (2.59 V) and a high specific energy (790 Wh/kg), the performance of present incarnations of this battery tend to be limited by their power. Because the nickel chloride electrode dominates the resistance and weight of the cell, research on this cell couple at Argonne National Laboratory (ANL) has been primarily directed toward improving both the specific power and energy of the NiCl{sub 2} electrodes. During the course of these investigations a major breakthrough was achieved in lowering the impedance and increasing the usable capacity through the use of chemical additives and a tailored electrode morphology. This improved Ni/NiCl{sub 2} electrode has excellent performance characteristics, wide-temperature operation and fast recharge capability. Modeling studies done on this electrode indicate that a fully developed Na/NiCl{sub 2} battery based on ANL-single tube and bipolar designs would surpass the mid-term and approach the long-term goals of the US Advanced Battery Consortium.

Prakash, J.; Redey, L.; Nelson, P.A.; Vissers, D.R. [Argonne National Lab., IL (United States). Electrotechnical Technology Program

1996-07-01T23:59:59.000Z

365

EXTENDING SODIUM FAST REACTOR DRIVER FUEL USE TO HIGHER TEMPERATURES  

Science Conference Proceedings (OSTI)

Calculations of potential sodium-cooled fast reactor fuel temperatures were performed to estimate the effects of increasing the outlet temperature of a given fast reactor design by increasing pin power, decreasing assembly flow, or increasing inlet temperature. Based upon experience in the U.S., both metal and mixed oxide (MOX) fuel types are discussed in terms of potential performance effects created by the increased operating temperatures. Assembly outlet temperatures of 600, 650 and 700 °C were used as goal temperatures. Fuel/cladding chemical interaction (FCCI) and fuel melting, as well as challenges to the mechanical integrity of the cladding material, were identified as the limiting phenomena. For example, starting with a recent 1000 MWth fast reactor design, raising the outlet temperature to 650 °C through pin power increase increased the MOX centerline temperature to more than 3300 °C and the metal fuel peak cladding temperature to more than 700 °C. These exceeded limitations to fuel performance; fuel melting was limiting for MOX and FCCI for metal fuel. Both could be alleviated by design ‘fixes’, such as using a barrier inside the cladding to minimize FCCI in the metal fuel, or using annular fuel in the case of MOX. Both would also require an advanced cladding material with improved stress rupture properties. While some of these are costly, the benefits of having a high-temperature reactor which can support hydrogen production, or other missions requiring high process heat may make the extra costs justified.

Douglas L. Porter

2011-02-01T23:59:59.000Z

366

SYNTHESIS OF OXYGENATED PRODUCTS FROM CARBON MONOXIDE AND HYDROGEN OVER SILICA- AND ALUMINA-SUPPORTED RUTHENIUM CATALYSTS  

E-Print Network (OSTI)

Formation Over a 1.01; Ru/A1 o Catalyst at 498K H/CO P (atm)a silica-supported Ru catalyst Fig. 2 Effect of feed flowan alumina-supported Ru catalyst Fig. 3 Effect of reaction

Kellner, C.Stephen

2013-01-01T23:59:59.000Z

367

Molecular Dynamics Studies on the Effects of Water Speciation on Interfacial Structure and Dynamics in Silica-Filled PDMS Composites  

DOE Green Energy (OSTI)

Significant changes in materials properties of siloxane based polymers can be obtained by the addition of inorganic fillers. In silica-filled polydimethylsiloxane (PDMS) based composites the mechanism of this reinforcing behavior is presumably hydrogen bonding between surface hydroxyls and backbone siloxane species. We have chosen to investigate in detail the effect of chemisorbed and physisorbed water on the interfacial structure and dynamics in silica-filled PDMS based composites. Toward this end, we have combined molecular dynamics simulations and experimental studies employing DMA and Nh4R analysis. Our results suggest that the polymer-silica contact distance and the mobility of interfacial polymer chains significantly decreased as the hydration level at the interface was reduced. The reduced mobility of the PDMS chains in the interfacial domain reduced the overall, bulk, motional properties of the polymer, thus causing an effective ''stiffening'' of the polymer matrix. The role of the long-ranged Coulombic interactions on the structural features and chain dynamics of the polymer were also examined. Both are found to be strongly influenced by the electrostatic interactions as identified by the bond orientation time correlation function and local density distribution functions. These results have important implications for the design of nanocomposite silica-siloxane materials.

Gee, R H; Maxwell, R S; Dinh, L N; Balazs, B

2001-11-21T23:59:59.000Z

368

Reducing Logistics Footprints and Replenishment Demands: Nano-engineered Silica Aerogels a Proven Method for Water Treatment  

SciTech Connect

Rapid deployment and the use of objective force aggressively reduce logistic footprints and replenishment demands. Maneuver Sustainment requires that Future Combat Systems be equipped with water systems that are lightweight, have small footprints, and are highly adaptable to a variety of environments. Technologies employed in these settings must be able to meet these demands. Lawrence Livermore National Laboratory has designed and previously field tested nano-engineered materials for the treatment of water. These materials have been either based on silica aerogel materials or consist of composites of these aerogels with granular activated carbon (GAC). Recent tests have proven successful for the removal of contaminants including uranium, hexavalent chromium, and arsenic. Silica aerogels were evaluated for their ability to purify water that had been spiked with the nerve agent VX (O-ethyl S-(2-diisopropylaminoethyl) methylphosphonothiolate). These results demonstrated that silica aerogels were able to remove the VX from the supply water and were nearly 30 times more adsorbent than GAC. This performance could result in REDUCING CHANGEOUT FREQUENCY BY A FACTOR OF 30 or DECREASING the VOLUME of adsorbent BY A FACTOR OF 30; thereby significantly reducing logistic footprints and replenishment demands. The use of the nano-engineered Silica Aerogel/GAC composites would provide a water purification technology that meets the needs of Future Combat Systems.

Daily, W; Coleman, S; Love, A; Reynolds, J; O'Brien, K; Gammon, S

2004-09-22T23:59:59.000Z

369

Durability of LDPE nanocomposites with clay, silica, and zinc oxide: part I: mechanical properties of the nanocomposite materials  

Science Conference Proceedings (OSTI)

Three types of LDPE-based nanocomposites with montmorillonite clay, silica, and zinc oxide were prepared by melt blending the nanofiller with the resin. As a prelude to studying their durability, the extent of reinforcement of the LDPE matrix by the ...

Halim Hamid Redhwi, Mohammad Nahid Siddiqui, Anthony L. Andrady, Syed Hussain

2013-01-01T23:59:59.000Z

370

Silver nanoparticles confined in SBA-15 mesoporous silica and the application as a sensor for detecting hydrogen peroxide  

Science Conference Proceedings (OSTI)

Silver nanoparticles within the pore channels of selectively grafted mesoporous silica SBA-15 were synthesized. Silanols on the external surface of as-SBA-15 were first capped by -Si(CH3)3 groups. After removal of the template of ...

Dong-Hai Lin; Yan-Xia Jiang; Ying Wang; Shi-Gang Sun

2008-01-01T23:59:59.000Z

371

Process Flow Chart for Immobilizing of Radioactive High Concentration Sodium Hydroxide Product from the Sodium Processing Facility at the BN-350 Nuclear power plant in Aktau, Kazakhstan  

Science Conference Proceedings (OSTI)

This paper describes the results of a joint research investigations carried out by the group of Kazakhstan, British and American specialists in development of a new material for immobilization of radioactive 35% sodium hydroxide solutions from the sodium coolant processing facility of the BN-350 nuclear power plant. The resulting solid matrix product, termed geo-cement stone, is capable of isolating long lived radionuclides from the environment. The physico-mechanical properties of geo-cement stone have been investigated and the flow chart for its production verified in a full scale experiments. (author)

Burkitbayev, M.; Omarova, K.; Tolebayev, T. [Ai-Farabi Kazakh National University, Chemical Faculty, Republic of Kazakhstan (Kazakhstan); Galkin, A. [KATEP Ltd., Republic of Kazakhstan (Kazakhstan); Bachilova, N. [NIISTROMPROEKT Ltd., Republic of Kazakhstan (Kazakhstan); Blynskiy, A. [Nuclear Technology Safety Centre, Republic of Kazakhstan (Kazakhstan); Maev, V. [MAEK-Kazatomprom Ltd., Republic of Kazakhstan (Kazakhstan); Wells, D. [NUKEM Limited- a member of the Freyssinet Group, Winfrith Technology Centre, Dorchester, Dorset (United Kingdom); Herrick, A. [NUKEM Limited- a member of the Freyssinet Group, Caithness (United Kingdom); Michelbacher, J. [Idaho National Laboratory, Idaho Falls (United States)

2008-07-01T23:59:59.000Z

372

Sodium/Phosphorus-Sulfur Cells I. Cell Performance Paul L. Ridgway,  

NLE Websites -- All DOE Office Websites (Extended Search)

Sodium/Phosphorus-Sulfur Cells Sodium/Phosphorus-Sulfur Cells I. Cell Performance Paul L. Ridgway, Frank R. McLarnon, and Elton J. Cairns* Energy and Environment Division, Lawrence Berkeley National Laboratory, and Department of Chemical Engineering, University of California, Berkeley, California 94720, USA ABSTRACT Sodium/°-alumina/phosphorus-sulfur cells utilizing P/S ratios of 0, 0.143, 0.332, and 1.17 at temperatures from 350 to 500°C were studied by measurement of the equilibrium cell voltages at open circuit, and the steady-state cell voltages at current densities up to 70 mA/cm2. States of charge, represented by sodium atom fraction in the P-S electrode, ranged from 0 to 0.4. Open-circuit voltages up to 2.65 V were measured. Theoretical specific energies up to 825 Wh/kg were cal-

373

Process for sodium sulfide/ferrous sulfate treatment of hexavalent chromium and other heavy metals  

SciTech Connect

433 of 9384 ) United States Patent 5,000,859 Suciu ,   et al. March 19, 1991 Process for sodium sulfide/ferrous sulfate treatment of hexavalent chromium and other heavy metals

Suciu, Dan F. (Idaho Falls, ID); Wikoff, Penny M. (Idaho Falls, ID); Beller, John M. (Idaho Falls, ID); Carpenter, Charles J. (Lynn Haven, FL)

1991-01-01T23:59:59.000Z

374

Applying risk informed methodologies to improve the economics of sodium-cooled fast reactors  

E-Print Network (OSTI)

In order to support the increasing demand for clean sustainable electricity production and for nuclear waste management, the Sodium-Cooled Fast Reactor (SFR) is being developed. The main drawback has been its high capital ...

Nitta, Christopher C

2010-01-01T23:59:59.000Z

375

Development of a model to predict flow oscillations in low-flow sodium boiling  

E-Print Network (OSTI)

An experimental and analytical program has been carried out in order to better understand the cause and effect of flow oscillations in boiling sodium systems. These oscillations have been noted in previous experiments with ...

Levin, Alan Edward

1980-01-01T23:59:59.000Z

376

Metal corrosion in a supercritical carbon dioxide - liquid sodium power cycle.  

Science Conference Proceedings (OSTI)

A liquid sodium cooled fast reactor coupled to a supercritical carbon dioxide Brayton power cycle is a promising combination for the next generation nuclear power production process. For optimum efficiency, a microchannel heat exchanger, constructed by diffusion bonding, can be used for heat transfer from the liquid sodium reactor coolant to the supercritical carbon dioxide. In this work, we have reviewed the literature on corrosion of metals in liquid sodium and carbon dioxide. The main conclusions are (1) pure, dry CO{sub 2} is virtually inert but can be highly corrosive in the presence of even ppm concentrations of water, (2) carburization and decarburization are very significant mechanism for corrosion in liquid sodium especially at high temperature and the mechanism is not well understood, and (3) very little information could be located on corrosion of diffusion bonded metals. Significantly more research is needed in all of these areas.

Moore, Robert Charles; Conboy, Thomas M.

2012-02-01T23:59:59.000Z

377

Ultracold molecules from ultracold atoms : interactions in sodium and lithium gas  

E-Print Network (OSTI)

The thesis presents results from experiments in which ultracold Sodium-6 and Lithium-23 atomic gases were studied near a Feshbach resonance at high magnetic fields. The enhanced interactions between atoms in the presence ...

Christensen, Caleb A

2011-01-01T23:59:59.000Z

378

An Evaluation of the Annular Fuel and Bottle-Shaped Fuel Concepts for Sodium Fast Reactors  

E-Print Network (OSTI)

Two innovative fuel concepts, the internally and externally cooled annular fuel and the bottle-shaped fuel, were investigated with the goal of increasing the power density and reduce the pressure drop in the sodium-cooled ...

Memmott, Matthew

379

Thermal-hydraulic analysis of innovative fuel configurations for the sodium fast reactor  

E-Print Network (OSTI)

The sodium fast reactor (SFR) is currently being reconsidered as an instrument for actinide management throughout the world, thanks in part to international programs such as the Generation-IV and especially the Global ...

Memmott, Matthew J

2009-01-01T23:59:59.000Z

380

Tools for supercritical carbon dioxide cycle analysis and the cycle's applicability to sodium fast reactors  

E-Print Network (OSTI)

The Sodium-Cooled Fast Reactor (SFR) and the Supercritical Carbon Dioxide (S-C0?) Recompression cycle are two technologies that have the potential to impact the power generation landscape of the future. In order for their ...

Ludington, Alexander R. (Alexander Rockwell)

2009-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "na-sg sodium silica" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Materials Issues in High Temperature Ultrasonic Transducers for Under-Sodium Viewing  

Science Conference Proceedings (OSTI)

Liquid sodium is used as the coolant in some fast spectrum nuclear reactors. This material is optically opaque. To facilitate operations and maintenance activities, an ultrasonic under-sodium viewing system has been developed. In the USA, the technology was successfully demonstrated in the 1970's, and, over the intervening 30+ years the capability was lost. This paper reports materials challenges encountered in developing both single-element and linear phased array 2 MHz transducers that must operate at temperatures up to 260C. The critical issues are fundamentally material selection: the ability of a transducer to be immersed into liquid sodium and function at 260C, to achieve wetting and transmission of ultrasound into the sodium, and to be able to be removed and re-used.

Bond, Leonard J.; Griffin, Jeffrey W.; Posakony, Gerald J.; Harris, Robert V.; Baldwin, David L.

2012-06-12T23:59:59.000Z

382

Sol-Gel Synthesis of Bio-Active Nanoporous Sodium Zirconate ...  

Science Conference Proceedings (OSTI)

Abstract Scope, Bio-active sodium substituted zirconium was coated by sol-gel method ... Templates Facilitates Neural Stem Cell Adhesion, Proliferation and Differentiation ... Improving the Resistance of Ceramic Surfaces to Biofilm Formation.

383

Solar test of an integrated sodium reflux heat pipe receiver/reactor for thermochemical energy transport  

DOE Green Energy (OSTI)

A chemical reactor for carbon dioxide reforming of methane was integrated into a sodium reflux heat pipe receiver and tested in the solar furnace of the Weizmann Institute of Science, Rehovot, Israel. The receiver/reactor was a heat pipe with seven tubes inside an evacuated metal box containing sodium. The catalyst, 0.5 wt% Rh on alumina, filled two of the tubes with the front surface of the box serving as the solar absorber. In operation, concentrated sunlight heated the front plate and vaporized sodium from a wire mesh wick attached to other side. Sodium vapor condensed on the reactor tubes, releasing latent heat and returning to the wick by gravity. The receiver system performed satisfactorily in many tests under varying flow conditions. The maximum power absorbed was 7.5 kW at temperatures above 800C. The feasibility of operating a heat pipe receiver/reactor under solar conditions was proven, and the advantages of reflux devices confirmed.

Diver, R.B.; Fish, J.D. (Sandia National Labs., Albuquerque, NM (United States)); Levitan, R.; Levy, M.; Meirovitch, E.; Rosin, H. (Weizmann Inst. of Science, Rehovot (Israel)); Paripatyadar, S.A.; Richardson, J.T. (Univ. of Houston, TX (United States))

1992-01-01T23:59:59.000Z

384

Application of the Technology Neutral Framework to Sodium-­Cooled Fast Reactors  

E-Print Network (OSTI)

Sodium cooled fast reactors (SFRs) are considered as a novel example to exercise the Technology Neutral Framework (TNF) proposed in NUREG-1860. One reason for considering SFRs is that they have historically had a licensing ...

Johnson, Brian C.

385

Application of the technology neutral framework to sodium cooled fast reactors  

E-Print Network (OSTI)

Sodium cooled fast reactors (SFRs) are considered as a novel example to exercise the Technology Neutral Framework (TNF) proposed in NUREG- 1860. One reason for considering SFRs is that they have historically had a licensing ...

Johnson, Brian C. (Brian Carl)

2010-01-01T23:59:59.000Z

386

Oxygen-hydrogen meter assembly for use in remote sodium sampling systems  

SciTech Connect

An assembly of an electrolytic oxygen meter and a diffusion type hydrogen meter was designed to fit into the Multipurpose Sampler hardware already installed and operating on the four FFTF sodium systems. One of the key elements in this assembly is a ceramic-metal sealed oxygen sensor which allows use of a metal tube to extend the 51 cm (20 in.) between the sampler top and the flowing sodium region.

Barton, G.B.; Bohringer, A.P.; Yount, J.A.

1980-02-01T23:59:59.000Z

387

REDUCTION OF PLUTONIUM TO Pu$sup +3$ BY SODIUM DITHIONITE IN POTASSIUM CARBONATE  

DOE Patents (OSTI)

Plutonium values are reduced in an alkaline aqueous medlum to the trlvalent state by means of sodium dlthionite. Plutonlum values are also separated from normally assoclated contaminants by metathesizing a lanthanum fluoride carrier precipitate containing plutonium with a hydroxide solution, performing the metathesis in the presence of about 0.2 M sodium dithionite at a temperature of between 40 and 90 icient laborato C.

Miller, D.R.; Hoekstra, H.R.

1958-12-16T23:59:59.000Z

388

Glass Formulation Development for INEEL Sodium-Bearing Waste  

SciTech Connect

For about four decades, radioactive wastes have been collected and calcined from nuclear fuels reprocessing at the Idaho Nuclear Technology and Engineering Center (INTEC), formerly Idaho Chemical Processing Plant (ICPP). Over this time span, secondary radioactive wastes have also been collected and stored as liquid from decontamination, laboratory activities, and fuel-storage activities. These liquid wastes are collectively called sodium-bearing wastes (SBW). About 5.7 million liters of these wastes are temporarily stored in stainless steel tanks at the Idaho National Engineering and Environmental Laboratory (INEEL). Vitrification is being considered as an immobilization step for SBW with a number of treatment and disposal options. A systematic study was undertaken to develop a glass composition to demonstrate direct vitrification of INEEL's SBW. The objectives of this study were to show the feasibility of SBW vitrification, not a development of an optimum formulation. The waste composition is relatively high in sodium, aluminum, and sulfur. A specific composition and glass property restrictions, discussed in Section 2, were used as a basis for the development. Calculations based on first-order expansions of selected glass properties in composition and some general tenets of glass chemistry led to an additive (fit) composition (68.69 mass % SiO{sub 2}, 14.26 mass% B{sub 2}O{sub 3}, 11.31 mass% Fe{sub 2}O{sub 3}, 3.08 mass% TiO{sub 2}, and 2.67 mass % Li{sub 2}O) that meets all property restrictions when melted with 35 mass % of SBW on an oxide basis, The glass was prepared using oxides, carbonates, and boric acid and tested to confirm the acceptability of its properties. Glass was then made using waste simulant at three facilities, and limited testing was performed to test and optimize processing-related properties and confirm results of glass property testing. The measured glass properties are given in Section 4. The viscosity at 1150 C, 5 Pa{center_dot}s, is nearly ideal for waste-glass processing in a standard liquid-fed joule-heated melter. The normalized elemental releases by 7-day PCT are all well below 1 g/m{sup 2}, which is a very conservative set point used in this study. The T{sub L}, ignoring sulfate formation, is less than the 1050 C limit. Based on these observations and the reasonable waste loading of 35 mass 0/0, the SBW glass was a prime candidate for further testing. Sulfate salt segregation was observed in all test melts formed from oxidized carbonate precursors. Melts fabricated using SBW simulants suggest that the sulfate-salt segregation seen in oxide and carbonate melts was much less of a problem. The cause for the difference is likely H{sub 2}SO{sub 4} fuming during the boil-down stage of wet-slurry processing. Additionally, some crucible tests with SBW simulant were conducted at higher temperatures (1250 C), which could increase the volatility of sulfate salts. The fate of sulfate during the melting process is still uncertain and should be the topic of future studies. The properties of the simulant glass confirmed those of the oxide and carbonate glass. Corrosion tests on Inconel 690 electrodes and K-3 refractory blocks conducted at INEEL suggest that the glass is not excessively corrosive. Based on the results of this study, the authors recommend that a glass made of 35% SBW simulant (on a mass oxide and halide basis) and 65% of the additive mix (either filled or raw chemical) be used in demonstrating the direct vitrification of INEEL SBW. It is further recommended that a study be conducted to determine the fate of sulfate during glass processing and the tolerance of the chosen melter technology to sulfate salt segregation and corrosivity of the melt.

J.D. Vienna; M.J. Schweiger; D.E. Smith; H.D. Smith; J.V. Crum; D.K. Peeler; I.A. Reamer; C.A. Musick; R.D. Tillotson

1999-08-03T23:59:59.000Z

389

Glass Formulation Development for INEEL Sodium-Bearing Waste  

SciTech Connect

For about four decades, radioactive wastes have been collected and calcined from nuclear fuels reprocessing at the Idaho Nuclear Technology and Engineering Center (INTEC), formerly Idaho Chemical Processing Plant (ICPP). Over this time span, secondary radioactive wastes have also been collected and stored as liquid from decontamination, laboratory activities, and fuel-storage activities. These liquid wastes are collectively called sodium-bearing wastes (SBW). About 5.7 million liters of these wastes are temporarily stored in stainless steel tanks at the Idaho National Engineering and Environmental Laboratory (INEEL). Vitrification is being considered as an immobilization step for SBW with a number of treatment and disposal options. A systematic study was undertaken to develop a glass composition to demonstrate direct vitrification of INEEL's SBW. The objectives of this study were to show the feasibility of SBW vitrification, not a development of an optimum formulation. The waste composition is relatively high in sodium, aluminum, and sulfur. A specific composition and glass property restrictions, discussed in Section 2, were used as a basis for the development. Calculations based on first-order expansions of selected glass properties in composition and some general tenets of glass chemistry led to an additive (fit) composition (68.69 mass % SiO{sub 2}, 14.26 mass% B{sub 2}O{sub 3}, 11.31 mass% Fe{sub 2}O{sub 3}, 3.08 mass% TiO{sub 2}, and 2.67 mass % Li{sub 2}O) that meets all property restrictions when melted with 35 mass % of SBW on an oxide basis, The glass was prepared using oxides, carbonates, and boric acid and tested to confirm the acceptability of its properties. Glass was then made using waste simulant at three facilities, and limited testing was performed to test and optimize processing-related properties and confirm results of glass property testing. The measured glass properties are given in Section 4. The viscosity at 1150 C, 5 Pa{center_dot}s, is nearly ideal for waste-glass processing in a standard liquid-fed joule-heated melter. The normalized elemental releases by 7-day PCT are all well below 1 g/m{sup 2}, which is a very conservative set point used in this study. The T{sub L}, ignoring sulfate formation, is less than the 1050 C limit. Based on these observations and the reasonable waste loading of 35 mass 0/0, the SBW glass was a prime candidate for further testing. Sulfate salt segregation was observed in all test melts formed from oxidized carbonate precursors. Melts fabricated using SBW simulants suggest that the sulfate-salt segregation seen in oxide and carbonate melts was much less of a problem. The cause for the difference is likely H{sub 2}SO{sub 4} fuming during the boil-down stage of wet-slurry processing. Additionally, some crucible tests with SBW simulant were conducted at higher temperatures (1250 C), which could increase the volatility of sulfate salts. The fate of sulfate during the melting process is still uncertain and should be the topic of future studies. The properties of the simulant glass confirmed those of the oxide and carbonate glass. Corrosion tests on Inconel 690 electrodes and K-3 refractory blocks conducted at INEEL suggest that the glass is not excessively corrosive. Based on the results of this study, the authors recommend that a glass made of 35% SBW simulant (on a mass oxide and halide basis) and 65% of the additive mix (either filled or raw chemical) be used in demonstrating the direct vitrification of INEEL SBW. It is further recommended that a study be conducted to determine the fate of sulfate during glass processing and the tolerance of the chosen melter technology to sulfate salt segregation and corrosivity of the melt.

J.D. Vienna; M.J. Schweiger; D.E. Smith; H.D. Smith; J.V. Crum; D.K. Peeler; I.A. Reamer; C.A. Musick; R.D. Tillotson

1999-08-03T23:59:59.000Z

390

A New Concept for the Fabrication of Hydrogen Selective Silica Membranes  

NLE Websites -- All DOE Office Websites (Extended Search)

New CoNCept for the fAbriCAtioN of New CoNCept for the fAbriCAtioN of hydrogeN SeleCtive SiliCA MeMbrANeS Background As stated in the National Research Council report on Novel Approaches to Carbon Management, a novel membrane is needed that can achieve the separation of carbon dioxide (CO 2 ) and hydrogen (H 2 ) at a high temperature and pressure. Extensive efforts over the last several decades have explored high temperature H 2 -selective membranes made of silicon dioxide (SiO 2 ) and other oxides, palladium (Pd) and other metals or alloys and, more recently, various zeolites and non-aluminosilicate molecular sieves. Although promising separation results have been reported for many of them, these technologies, they all suffer from high production costs for membrane fabrication and from long term stability problems. This project revisits

391

Post-Harvest Processing Methods for Reduction of Silica and Alkali Metals in Wheat Straw  

SciTech Connect

Silica and alkali metals in wheat straw limit its use for bioenergy and gasification. Slag deposits occur via the eutectic melting of SiO2 with K2O, trapping chlorides at surfaces and causing corrosion. A minimum melting point of 950°C is desirable, corresponding to SiO2:K2O of about 3:1. Mild chemical treatments were used to reduce Si, K, and Cl, while varying temperature, concentration, %-solids, and time. Dilute acid was more effective at removing K and Cl, while dilute alkali was more effective for Si. Reduction of minerals in this manner may prove economical for increasing utilization of the straw for combustion or gasification.

Thompson, David Neal; Lacey, Jeffrey Alan; Shaw, Peter Gordon

2002-04-01T23:59:59.000Z

392

Development of transparent silica aerogel over a wide range of densities  

E-Print Network (OSTI)

We have succeeded in developing hydrophobic silica aerogels over a wide range of densities (i.e. refractive indices). A pinhole drying method was invented to make possible producing highly transparent aerogels with entirely new region of refractive indices of 1.06-1.26. Obtained aerogels are more transparent than conventional ones, and the refractive index is well controlled in the pinhole drying process. A test beam experiment was carried out in order to evaluate the performance of the pinhole-dried aerogels as a Cherenkov radiator. A clear Cherenkov ring was successfully observed by a ring imaging Cherenkov counter. We also developed monolithic and hydrophobic aerogels with a density of 0.01 g/cm^3 (a low refractive index of 1.0026) as a cosmic dust capturer for the first time. Consequently, aerogels with any refractive indices between 1.0026 and 1.26 can be produced freely.

Makoto Tabata; Ichiro Adachi; Yoshikazu Ishii; Hideyuki Kawai; Takayuki Sumiyoshi; Hiroshi Yokogawa

2011-12-21T23:59:59.000Z

393

Tanpopo cosmic dust collector: Silica aerogel production and bacterial DNA contamination analysis  

E-Print Network (OSTI)

Hydrophobic silica aerogels with ultra-low densities have been designed and developed as cosmic dust capture media for the Tanpopo mission which is proposed to be carried out on the International Space Station. Glass particles as a simulated cosmic dust with 30 \\mu m in diameter and 2.4 g/cm^3 in density were successfully captured by the novel aerogel at a velocity of 6 km/s. Background levels of contaminated DNA in the ultra-low density aerogel were lower than the detection limit of a polymerase chain reaction assay. These results show that the manufactured aerogel has good performance as a cosmic dust collector and sufficient quality in respect of DNA contamination. The aerogel is feasible for the biological analyses of captured cosmic dust particles in the astrobiological studies.

Tabata, Makoto; Yokobori, Shin-ichi; Kawai, Hideyuki; Takahashi, Jun-ichi; Yano, Hajime; Yamagishi, Akihiko

2011-01-01T23:59:59.000Z

394

Development of transparent silica aerogel over a wide range of densities  

E-Print Network (OSTI)

We have succeeded in developing hydrophobic silica aerogels over a wide range of densities (i.e. refractive indices). A pinhole drying method was invented to make possible producing highly transparent aerogels with entirely new region of refractive indices of 1.06-1.26. Obtained aerogels are more transparent than conventional ones, and the refractive index is well controlled in the pinhole drying process. A test beam experiment was carried out in order to evaluate the performance of the pinhole-dried aerogels as a Cherenkov radiator. A clear Cherenkov ring was successfully observed by a ring imaging Cherenkov counter. We also developed monolithic and hydrophobic aerogels with a density of 0.01 g/cm^3 (a low refractive index of 1.0026) as a cosmic dust capturer for the first time. Consequently, aerogels with any refractive indices between 1.0026 and 1.26 can be produced freely.

Tabata, Makoto; Ishii, Yoshikazu; Kawai, Hideyuki; Sumiyoshi, Takayuki; Yokogawa, Hiroshi; 10.1016/j.nima.2010.02.241

2011-01-01T23:59:59.000Z

395

X-ray radiographic technique for measuring density uniformity of silica aerogel  

E-Print Network (OSTI)

This paper proposes a new X-ray radiographic technique for measuring density uniformity of silica aerogels used as radiator in proximity-focusing ring-imaging Cherenkov detectors. To obtain high performance in a large-area detector, a key characteristic of radiator is the density (i.e. refractive index) uniformity of an individual aerogel monolith. At a refractive index of n = 1.05, our requirement for the refractive index uniformity in the transverse plane direction of an aerogel tile is |\\delta (n - 1)/(n - 1)| aerogels from a trial production and that of Panasonic products (SP-50) as a reference, and to confirm they have sufficient density uniformity within \\pm 1% along the transverse plane direction. The measurement results show that the proposed technique can quantitatively estimate the density uniformity of aerogels.

Makoto Tabata; Yoshikiyo Hatakeyama; Ichiro Adachi; Takeshi Morita; Keiko Nishikawa

2012-12-14T23:59:59.000Z

396

Performance predictions of silica-gel desiccant dehumidifiers. Technical report No. 3  

SciTech Connect

The analysis of a cross-cooled desiccant dehumidifier using silica gel in the form of sheets is described. This unit is the principal component of solar powered desiccant air conditioning system. The mathematical model has first been formulated describing the dynamics of the dehumidifier. The model leads to a system of nonlinear coupled heat and mass transfer equations for the sorption processes and linear heat transfer equations for the purging processes. The model accounts for the gas film resistance and for the moisture diffusion in the desiccant. The governing equations are solved by a finite difference scheme to obtain periodic steady state solutions. The accuracy of the theoretical predictions is ascertained by comparing them with the experimental results. The performance of the dehumidifier, for a chosen set of initial conditions and dehumidifier parameters, has also been given.

Mathiprakasam, B.; Lavan, Z.

1980-01-01T23:59:59.000Z

397

A Novel Low-Cost Sodium-Zinc Chloride Battery  

Science Conference Proceedings (OSTI)

The sodium-metal halide (ZEBRA) battery has been considered as one of the most attractive energy storage systems for stationary and transportation applications. Even though Na-NiCl2 battery has been widely investigated, there is still a need to develop a more economical system to make this technology more attractive for commercialization. In the present work, a novel low-cost Na-ZnCl2 battery with a thin planar ??-Al2O3 solid electrolyte (BASE) was proposed, and its electrochemical reactions and battery performance were investigated. Compared to the Na-NiCl2 chemistry, the ZnCl2-based chemistry was more complicated, in which multiple electrochemical reactions including liquid-phase formation occurred at temperatures above 253°C. During the first stage of charge, NaCl reacted with Zn to form Na in the anode and Na2ZnCl4 in the cathode. Once all the residual NaCl was consumed, further charging led to the formation of a NaCl-ZnCl2 liquid phase. At the end of charge, the liquid phase reacted with Zn to produce solid ZnCl2. To identify the effects of liquid-phase formation on electrochemical performance, button cells were assembled and tested at 280°C and 240°C. At 280°C where the liquid phase formed during cycling, cells revealed quite stable cyclability. On the other hand, more rapid increase in polarization was observed at 240°C where only solid-state electrochemical reactions occurred. SEM analysis indicated that the stable performance at 280°C was due to the suppressed growth of Zn and NaCl particles, which were generated from the liquid phase during discharge of each cycle.

Lu, Xiaochuan; Li, Guosheng; Kim, Jin Yong; Lemmon, John P.; Sprenkle, Vincent L.; Yang, Zhenguo

2013-02-28T23:59:59.000Z

398

Ion Recognition Approach to Volume Reduction of Alkaline Tank Waste by Separation of Sodium Salts  

SciTech Connect

The purpose of this research involving collaboration between Oak Ridge National Laboratory (ORNL) and Pacific Northwest National Laboratory (PNNL) is to explore new approaches to the separation of sodium hydroxide, sodium nitrate, and other sodium salts from high-level alkaline tank waste. The principal potential benefit is a major reduction in disposed waste volume, obviating the building of expensive new waste tanks and reducing the costs of vitrification. Principles of ion recognition are being researched toward discovery of liquid-liquid extraction systems that selectively separate sodium hydroxide and sodium nitrate from other waste components. The successful concept of pseudo hydroxide extraction using fluorinated alcohols and phenols is being developed at ORNL and PNNL toward a greater understanding of the controlling equilibria, role of solvation, and of synergistic effects involving crown ethers. Synthesis efforts are being directed toward enhanced sodium binding by crown ethers, both neutral and proton-ionizable. Studies with real tank waste at PNNL will provide feedback toward solvent compositions that have promising properties.

Moyer, Bruce A.; Bonnesen, Peter V.; Custelcean, Radu; Delmau, Laetitia H.; Engle, Nancy L.; Kang, Hyun-Ah; Keever, Tamara J.; Marchand, Alan P.; Gadthula, Srinivas; Gore, Vinayak K.; Huang, Zilin; Sivappa, Rasapalli; Tirunahari, Pavan K.; Levitskaia, Tatiana G.; Lumetta, Gregg J.

2005-09-26T23:59:59.000Z

399

Ion Recognition Approach to Volume Reduction of Alkaline Tank Waste by Separation of Sodium Salts  

SciTech Connect

The purpose of this research involving collaboration between Oak Ridge National Laboratory (ORNL) and Pacific Northwest National Laboratory (PNNL) is to explore new approaches to the separation of sodium hydroxide, sodium nitrate, and other sodium salts from high-level alkaline tank waste. The principal potential benefit is a major reduction in disposed waste volume, obviating the building of expensive new waste tanks and reducing the costs of low-activity waste immobilization. Principles of ion recognition are being researched toward discovery of liquid-liquid extraction systems that selectively separate sodium hydroxide and sodium nitrate from other waste components. The successful concept of pseudohydroxide extraction using fluorinated alcohols and phenols is being developed at ORNL and PNNL toward a greater understanding of the controlling equilibria, role of solvation, and of synergistic effects involving crown ethers. Synthesis efforts are being directed toward enhanced sodium binding by crown ethers, both neutral and proton-ionizable. Studies with real tank waste at PNNL will provide feedback toward solvent compositions that have promising properties.

Levitskaia, Tatiana G.; Lumetta, Gregg J.; Moyer, Bruce A.; Bonnesen, Peter V.

2005-06-01T23:59:59.000Z

400

An evaluation of neutralization for processing sodium-bearing liquid waste  

SciTech Connect

This report addresses an alternative concept for potentially managing the sodium-bearing liquid waste generated at the Idaho Chemical Processing Plant from the current method of calcining a blend of sodium waste and high-level liquid waste. The concept is based on removing the radioactive components from sodium-bearing waste by neutralization and grouting the resulting low-level waste for on-site near-surface disposal. Solidifying the sodium waste as a remote-handled transuranic waste is not considered to be practical because of excessive costs and inability to dispose of the waste in a timely fashion. Although neutralization can remove most radioactive components to provide feed for a solidified low-level waste, and can reduce liquid inventories four to nine years more rapidly than the current practice of blending sodium-bearing liquid waste with first-cycle raffinite, the alternative will require major new facilities and will generate large volumes of low-level waste. Additional facility and operating costs are estimated to be at least $500 million above the current practice of blending and calcining. On-site, low-level waste disposal may be technically difficult and conflict which national and state policies. Therefore, it is recommended that the current practice of calcining a blend of sodium-bearing liquid waste and high-level liquid waste be continued to minimize overall cost and process complexities. 17 refs., 4 figs., 16 tabs.

Chipman, N.A.; Engelgau, G.O.; Berreth, J.R.

1989-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "na-sg sodium silica" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

An Innovative Hybrid Loop-Pool Design for Sodium Cooled Fast Reactor  

SciTech Connect

The existing sodium cooled fast reactors (SFR) have two types of designs – loop type and pool type. In the loop type design, such as JOYO (Japan) [1] and MONJU (Japan), the primary coolant is circulated through intermediate heat exchangers (IHX) external to the reactor tank. The major advantages of loop design include compactness and easy maintenance. The disadvantage is higher possibility of sodium leakage. In the pool type design such as EBR-II (USA), BN-600M(Russia), Superphénix (France) and European Fast Reactor [2], the reactor core, primary pumps, IHXs and direct reactor auxiliary cooling system (DRACS) heat exchangers (DHX) all are immersed in a pool of sodium coolant within the reactor vessel, making a loss of primary coolant extremely unlikely. However, the pool type design makes primary system large. In the latest ANL’s Advanced Burner Test Reactor (ABTR) design [3], the primary system is configured in a pool-type arrangement. The hot sodium at core outlet temperature in hot pool is separated from the cold sodium at core inlet temperature in cold pool by a single integrated structure called Redan. Redan provides the exchange of the hot sodium from hot pool to cold pool through IHXs. The IHXs were chosen as the traditional tube-shell design. This type of IHXs is large in size and hence large reactor vessel is needed.

Haihua Zhao; Hongbin Zhang

2007-11-01T23:59:59.000Z

402

Solar-thermal Water Splitting Using the Sodium Manganese Oxide Process & Preliminary H2A Analysis  

DOE Green Energy (OSTI)

There are three primary reactions in the sodium manganese oxide high temperature water splitting cycle. In the first reaction, Mn2O3 is decomposed to MnO at 1,500°C and 50 psig. This reaction occurs in a high temperature solar reactor and has a heat of reaction of 173,212 J/mol. Hydrogen is produced in the next step of this cycle. This step occurs at 700°C and 1 atm in the presence of sodium hydroxide. Finally, water is added in the hydrolysis step, which removes NaOH and regenerates the original reactant, Mn2O3. The high temperature solar�driven step for decomposing Mn2O3 to MnO can be carried out to high conversion without major complication in an inert environment. The second step to produce H2 in the presence of sodium hydroxide is also straightforward and can be completed. The third step, the low temperature step to recover the sodium hydroxide is the most difficult. The amount of energy required to essentially distill water to recover sodium hydroxide is prohibitive and too costly. Methods must be found for lower cost recovery. This report provides information on the use of ZnO as an additive to improve the recovery of sodium hydroxide.

Todd M. Francis, Paul R. Lichty, Christopher Perkins, Melinda Tucker, Peter B. Kreider, Hans H. Funke, Allan Lewandowski, and Alan W. Weimer

2012-10-24T23:59:59.000Z

403

Sustained Recycle in Light Water and Sodium-Cooled Reactors  

Science Conference Proceedings (OSTI)

From a physics standpoint, it is feasible to sustain recycle of used fuel in either thermal or fast reactors. This paper examines multi-recycle potential performance by considering three recycling approaches and calculating several fuel cycle parameters, including heat, gamma, and neutron emission of fresh fuel; radiotoxicity of waste; and uranium utilization. The first recycle approach is homogeneous mixed oxide (MOX) fuel assemblies in a light water reactor (LWR). The transuranic portion of the MOX was varied among Pu, NpPu, NpPuAm, or all-TRU. (All-TRU means all isotopes through Cf-252.) The Pu case was allowed to go to 10% Pu in fresh fuel, but when the minor actinides were included, the transuranic enrichment was kept below 8% to satisfy the expected void reactivity constraint. The uranium portion of the MOX was enriched uranium. That enrichment was increased (to as much as 6.5%) to keep the fuel critical for a typical LWR irradiation. The second approach uses heterogeneous inert matrix fuel (IMF) assemblies in an LWR - a mix of IMF and traditional UOX pins. The uranium-free IMF fuel pins were Pu, NpPu, NpPuAm, or all-TRU. The UOX pins were limited to 4.95% U-235 enrichment. The number of IMF pins was set so that the amount of TRU in discharged fuel from recycle N (from both IMF and UOX pins) was made into the new IMF pins for recycle N+1. Up to 60 of the 264 pins in a fuel assembly were IMF. The assembly-average TRU content was 1-6%. The third approach uses fast reactor oxide fuel in a sodium-cooled fast reactor with transuranic conversion ratio of 0.50 and 1.00. The transuranic conversion ratio is the production of transuranics divided by destruction of transuranics. The FR at CR=0.50 is similar to the CR for the MOX case. The fast reactor cases had a transuranic content of 33-38%, higher than IMF or MOX.

Steven J. Piet; Samuel E. Bays; Michael A. Pope; Gilles J. Youinou

2010-11-01T23:59:59.000Z

404

Robust conductive mesoporous carbon?silica composite films with highly ordered and oriented orthorhombic structures from triblock-copolymer template co-assembly  

Science Conference Proceedings (OSTI)

In this work, we describe a facile approach to improve the robustness of conductive mesoporous carbon-based thin films by the addition of silica to the matrix through the triconstituent organic-inorganic-organic co-assembly of resol (carbon precursor) and tetraethylorthosilicate (silica precursor) with triblock-copolymer Pluronic F127. The pyrolysis of the resol-silica-pluronic F127 film yields a porous composite thin film with well-defined mesostructure. X-Ray diffraction (XRD), grazing incidence small angle X-ray scattering (GISAXS), and electron microscopy measurements indicate that the obtained carbon-based thin films have a highly ordered orthorhombic mesostructure (Fmmm) with uniform large pore size ({approx}3 nm). The orthorhombic mesostructure is oriented and the (010) plane is parallel to the silicon wafer substrate. The addition of silica to the matrix impacts the pore size, surface area, porosity, modulus and conductivity. For composite films with approximately 40 wt% silica, the conductivity is decreased by approximately an order of magnitude in comparison to a pure carbon mesoporous film, but the conductivity is comparable to typical printed carbon inks used in electrochemical sensing, {approx}10 S cm{sup -1}. The mechanical properties of these mesoporous silica-carbon hybrid films are similar to the pure carbon analogs with a Young's modulus between 10 GPa and 15 GPa, but the material is significantly more porous. Moreover, the addition of silica to the matrix appears to improve the adhesion of the mesoporous film to a silicon wafer. These mesoporous silica-carbon composite films have appropriate characteristics for use in sensing applications.

Song, Lingyan; Feng, Dan; Campbell, Casey G.; Gu, Dong; Forster, Aaron M.; Yager, Kevin G.; Fredin, Nathaniel; Lee, Hae-Jeong; Jones, Ronald L.; Zhao, Dongyuan; Vogt, Bryan D. (AZU)

2012-07-11T23:59:59.000Z

405

An AC phase measuring interferometer for measuring dn/dT of fused silica and calcium fluoride at 193 nm  

Science Conference Proceedings (OSTI)

A novel method for the measurement of the change in index of refraction vs. temperature (dn/dT) of fused silica and calcium fluoride at the 193 nm wavelength has been developed in support of thermal modeling efforts for the development of 193 nm-based photolithographic exposure tools. The method, based upon grating lateral shear interferometry, uses a transmissive linear grating to divide a 193 nm laser beam into several beam paths by diffraction which propagate through separate identical material samples. One diffracted order passing through one sample overlaps the undiffracted beam from a second sample and forms interference fringes dependent upon the optical path difference between the two samples. Optical phase delay due to an index change from heating one of the samples causes the interference fringes to change sinusoidally with phase. The interferometer also makes use of AC phase measurement techniques through lateral translation of the grating. Results for several samples of fused silica and calcium fluoride are demonstrated.

Shagam, R.N.

1998-09-01T23:59:59.000Z

406

Effect of high silica content on scale deposition and pipe-wall loss in oilfield steam generators  

Science Conference Proceedings (OSTI)

Studies were conducted on site in the Coalinga, Belridge, and Midway Sunset fields in California to research the cause of metal losses detected in the radiant section return bends and immediate piping downstream form the stem generators. This paper reports on the surveillance of silica content in the influent and effluent streams of the selected steam generators and the results of X-ray inspection of bends, elbows, welds, and pipings which indicated that a correlation is likely to exist between the silica and bicarbonate concentration in the feedwater and the silicate scale buildup, and incident rate of wall loss and the cause of wall loss/pipe failures is a combination of corrosion and erosion mechanisms accelerated at higher steam qualities.

Khatib, Z.I.; Olson, E.E.; Place, M.C. Jr. (Shell Development Co., Houston, TX (United States))

1992-11-01T23:59:59.000Z

407

Electron-beam induced electric-hydraulic expansion in a silica-shelled gallium microball-nanotube structure  

Science Conference Proceedings (OSTI)

Heteroshape-heteroscale structure of silica-shelled Ga microball-nanotube was fabricated. Under in situ electron-beam irradiation, an abnormally large and fast expansion of Ga was observed. Failed by a sole routine heating effect of electron-beam, the expansion was explained by an electric-hydraulic expansion effect taking into account a huge inner pressure induced by the repelling Coulomb force of positively charged Ga ions on the Ga microball surface. The ions were accumulated due to knocking-out of Ga electrons under irradiation and shielding effect of a silica shell which prevents the charge balance restoration. A circuit model is proposed to calculate the accumulation of Ga ions.

Gao, Y. H.; Sun, M.; Su, J. [Wuhan National Laboratory for Optoelectronics (WNLO), School of Physics, College of Optoelectronic Science and Engineering, Huazhong University of Science and Technology (HUST), LuoyuRoad 1037, Wuhan 430074 (China); Zhi, C. Y.; Golberg, D.; Bando, Y. [International Center for Materials Nanoarchitectonics (MANA), National Institute for Materials Science (NIMS), Namiki 1-1, Tsukuba, Ibaraki 305-0044 (Japan); Duan, X. F. [Institute of Physics, Beijing National Laboratory of Condensed Matter Physics, Chinese Academy of Sciences, Beijing 100190 (China)

2011-08-22T23:59:59.000Z

408

SNAKE Sodium S-CO2 Interactions Experiment - Argonne National Laboratory  

NLE Websites -- All DOE Office Websites (Extended Search)

SNAKE Sodium S-CO2 Interactions Experiment SNAKE Sodium S-CO2 Interactions Experiment Capabilities Engineering Experimentation Reactor Safety Testing and Analysis Overview Nuclear Reactor Severe Accident Experiments MAX NSTF SNAKE Aerosol Experiments System Components Laser Applications Robots Applications Other Facilities Other Capabilities Work with Argonne Contact us For Employees Site Map Help Join us on Facebook Follow us on Twitter NE on Flickr SNAKE Sodium S-CO2 Interactions Experiment 1 2 The supercritical carbon dioxide (S-CO2) Brayton cycle, coupled with a Sodium-Cooled Fast Reactor (SFR), has been identified as a new and innovative energy conversion technology that could contribute to improving the economics of advanced nuclear energy. For these reactors, a new generation of compact, highly-efficient heat exchangers (HXs) will be employed that show great promise in improving the safety and cost of SFRs; however, small HX leaks could still occur. SNAKE is designed to study S-CO2 leakage into sodium.

409

Aerosol behavior during sodium spray fires and comparison with computer codes. [LMFBR  

SciTech Connect

The results of sodium spray fires in air in the 850-m/sup 3/ CSTF vessel are discussed. During these tests, sodium at 600/sup 0/C was sprayed downward through commercial nozzles located 16 m above the floor. Test AB3 released 48 kg of sodium spray in 140 seconds with 670-..mu..m MMD drop size and produced a maximum pressure increase of 0.041 MPa and 30 g/m/sup 3/ of airborne sodium compounds. Test NT-1 sprayed 82 kg of sodium at 320 ..mu..m MMD drop size over 4.7 hours. In both tests, large stable temperature gradients, not predicated by pre-test SPRAY computer code calculations, were observed. Also, post-test estimations of pressure and aerosol concentration made using SPRAY and HAA-3B codes exceeded actual values measured. Thus, the codes conservatively over-predicted the aerosol leakage potential. The experimental data and the SPRAY and HAA-3B code calculations are compared and discussed.

McCormack, J.D.; Hilliard, R.K.; Postma, A.K.; Owen, R.K.

1979-07-01T23:59:59.000Z

410

Development of the sodium/sulfur battery technology for utility applications  

SciTech Connect

The US Department of Energy is sponsoring the development of battery energy storage systems for electric utilities. An important part of this DOE program is the engineering of the battery subsystem. Because lower costs are possible and less space is required compared with conventional battery technologies, two advanced battery systems are being developed: sodium/sulfur and zinc/bromine. A brief description of the development approach being followed along with the current status of the sodium/sulfur technology is described in this paper. Of immediate relevance, a factory integrated modular sodium/sulfur system has been designed that incorporates many of the advantages of this technology. Each module (designated as NAS-P{sub AC}) combines a 600-kWh sodium/sulfur battery, a 300 kW power converter and a control system. In addition to the potential for low life-cycle cost, other specific benefits include excellent portability and an installed system-level footprint that is about 20% of an equivalent system using lead-acid batteries. The sodium/sulfur battery is designed to deliver its rated energy for 1500 cycles or 5 years of maintenance-free operation.

Braithwaite, J.W. [Sandia National Labs., Albuquerque, NM (United States); Koenig, A.A. [Silent Power, Inc., Wayne, PA (United States)

1993-08-01T23:59:59.000Z

411

The Effects of Temperature on the Electrochemical Performance of Sodium-Nickel Chloride Batteries  

Science Conference Proceedings (OSTI)

The sodium-nickel chloride (ZEBRA) battery is typically fabricated with a thick tubular ?"-alumina solid electrolyte (BASE) and operated at relatively high temperatures (? 300ºC) to achieve adequate electrochemical performance. In the present work, a planar-type sodium-nickel chloride battery possessing a thin BASE (~600 ?m thick) was tested in order to evaluate the feasibility of the battery operation at low temperatures (?200°C). Electrochemical test results revealed that the battery was able to be cycled at C/3 rate at as low as 175°C despite the higher cell polarization at the reduced temperature. Overall, low operating temperature resulted in a considerable improvement in the stability of cell performance. Cell degradation was negligible at 175°C, while 55% increase in end-of-charge polarization was observed at 280°C after 60 cycles. SEM analysis indicated that the performance degradation at higher temperatures was related to the particle growth of both nickel and sodium chloride in the cathode. The cells tested at lower temperatures (e.g., 175 and 200°C), however, exhibited a sharp drop in cell voltage at the end of discharge due to the diffusion limitation, possibly caused by the limited ionic conductivity of NaAlCl4 melt or the poor wettability of sodium on the BASE. Therefore, improvements in the ionic conductivity of a secondary electrolyte and sodium wetting are desirable to further enhance the battery performance at low temperatures.

Lu, Xiaochuan; Li, Guosheng; Kim, Jin Yong; Lemmon, John P.; Sprenkle, Vincent L.; Yang, Zhenguo

2012-10-01T23:59:59.000Z

412

Silane Modification of Glass and Silica Surfaces to Obtain Equally Oil-Wet Surfaces in Glass-Covered Silicon Micromodel Applications  

SciTech Connect

The wettability of silicon and glass surfaces can be modified by silanization. However, similar treatments of glass and silica surfaces using the same silane do not necessarily yield the same wettability as determined by the oil-water contact angle. In this technical note, surface cleaning pretreatments were investigated to determine conditions that would yield oil-wet surfaces on glass with similar wettability to silica surfaces treated with the same silane, and both air-water and oil-water contact angles were determined. Air-water contact angles were less sensitive to differences between silanized silica and glass surfaces, often yielding similar values while the oil-water contact angles were quite different. Borosilicate glass surfaces cleaned with standard cleaning solution 1 (SC1) yield intermediate-wet surfaces when silanized with hexamethyldisilazane, while the same cleaning and silanization yields oil-wet surfaces on silica. However, cleaning glass in boiling concentrated nitric acid creates a surface that can be silanized to obtain oil-wet surfaces using HDMS. Moreover, this method is effective on glass with prior thermal treatment at an elevated temperature of 400oC. In this way, silica and glass can be silanized to obtain equally oil-wet surfaces using HMDS. It is demonstrated that pretreatment and silanization is feasible in silicon-silica/glass micromodels previously assembled by anodic bonding, and that the change in wettability has a significant observable effect on immiscisble fluid displacements in the pore network.

Grate, Jay W.; Warner, Marvin G.; Pittman, Jonathan W.; Dehoff, Karl J.; Wietsma, Thomas W.; Zhang, Changyong; Oostrom, Martinus

2013-08-05T23:59:59.000Z

413

Eighth CANMET/ACI International Conference on Fly Ash, Silica Fume, Slag, and Natural Pozzolans in Concrete  

Science Conference Proceedings (OSTI)

The nine papers in this CD are collected by the U. S. Advisory Committee for presentation at the Eighth CANMET/ACI International Conference on Fly Ash, Silica Fume, Slag, and Natural Pozzolans in Concrete, May 23–29, 2004, Las Vegas, Nevada. They are being published by EPRI, Palo Alto, CA to make them available to all attendees, and other interested people, in a compact form for future reference and use.

2004-05-05T23:59:59.000Z

414

Experimental and Analytical Simulation of MFCI (Molten Fuel Coolant Interaction) during CDA (Core Disruptive Accident) in Sodium Cooled Fast Reactor.  

E-Print Network (OSTI)

??With increasing demand for understanding Severe Accident Scenario in Sodium Cooled Fast Reactors, there is an urgent need of enhancing numerical and experimental simulation techniques.… (more)

Natarajan, Venkataraman

2011-01-01T23:59:59.000Z

415

Quantitative in-situ measurements of sodium release during the combustion of single coal particles using planar laser induced fluorescence.  

E-Print Network (OSTI)

??The release of sodium from low rank coal during combustion is known to be an important factor in the phenomena of fouling and corrosion in… (more)

van Eyk, Philip Joseph

2011-01-01T23:59:59.000Z

416

Cr(VI) adsorption on functionalized amorphous and mesoporous silica from aqueous and non-aqueous media  

Science Conference Proceedings (OSTI)

A mesoporous silica (SBA-15) and amorphous silica (SG) have been chemically modified with 2-mercaptopyridine using the homogeneous route. This synthetic route involved the reaction of 2-mercaptopyridine with 3-chloropropyltriethoxysilane prior to immobilization on the support. The resulting material has been characterized by powder X-ray diffraction, nitrogen gas sorption, FT-IR and MAS NMR spectroscopy, thermogravimetry and elemental analysis. The solid was employed as a Cr(VI) adsorbent from aqueous and non-aqueous solutions at room temperature. The effect of several variables (stirring time, pH, metal concentration and solvent polarity) has been studied using the batch technique. The results indicate that under the optimum conditions, the maximum adsorption value for Cr(VI) was 1.83 {+-} 0.03 mmol/g for MP-SBA-15, whereas the adsorption capacity of the MP-SG was 0.86 {+-} 0.02 mmol/g. On the basis of these results, it can be concluded that it is possible to modify chemically SBA-15 and SG with 2-mercaptopyridine and to use the resulting modified silicas as effective adsorbents for Cr(VI)

Perez-Quintanilla, Damian [Departamento de Quimica Inorganica y Analitica, E.S.C.E.T, Universidad Rey Juan Carlos, C/Tulipan s/n, 28933 Mostoles, Madrid (Spain)]. E-mail: damian.perez@urjc.es; Hierro, Isabel del [Departamento de Quimica Inorganica y Analitica, E.S.C.E.T, Universidad Rey Juan Carlos, C/Tulipan s/n, 28933 Mostoles, Madrid (Spain); Fajardo, Mariano [Departamento de Quimica Inorganica y Analitica, E.S.C.E.T, Universidad Rey Juan Carlos, C/Tulipan s/n, 28933 Mostoles, Madrid (Spain); Sierra, Isabel [Departamento de Quimica Inorganica y Analitica, E.S.C.E.T, Universidad Rey Juan Carlos, C/Tulipan s/n, 28933 Mostoles, Madrid (Spain)]. E-mail: isabel.sierra@urjc.es

2007-08-07T23:59:59.000Z

417

ESS 2012 Peer Review - Sodium Intercalation Battery for Stationary Storage - David Ofer, Tiax  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Sodium Intercalation Battery for Sodium Intercalation Battery for Stationary Storage Energy Storage Systems Program (ESS) Peer Review and Update Meeting 2012 David Ofer Ofer.david@tiaxllc.com Washington DC, September 27, 2012 Sodium Intercalation Battery for Stationary Storage Background and Purpose 2 Large-scale stationary energy storage for integration with renewables and for off-peak energy capture is a new application requiring new rechargeable batteries. * New combination of requirements - Long cycle life under deep cycling use profile - High cycling efficiency - Moderate rate capability - Very low cost - No requirement for particularly high specific energy or energy density * TIAX is developing a novel Na-ion battery - Leverages teachings of Li-ion technology - Targets novel low-cost chemistry and cell design

418

Cost Transfers at the Department's Sodium Bearing Waste Treatment Facility Construction Project  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

U.S. Department of Energy U.S. Department of Energy Office of Inspector General Office of Audits and Inspections Audit Report Cost Transfers at the Department's Sodium Bearing Waste Treatment Facility Construction Project OAS-M-13-03 August 2013 Department of Energy Washington, DC 20585 August 8, 2013 MEMORANDUM FOR THE SENIOR ADVISOR FOR ENVIRONMENTAL MANAGEMENT FROM: Rickey R. Hass Deputy Inspector General for Audits and Inspections Office of Inspector General SUBJECT: INFORMATION: Audit Report on "Cost Transfers at the Department's Sodium Bearing Waste Treatment Facility Construction Project" BACKGROUND In 2005, the Department of Energy (Department) awarded the Idaho Cleanup Project contract to CH2M ♦ WG Idaho, LLC (CWI) to remediate the Idaho National Laboratory. The Sodium

419

Fact Sheet: Sodium-Beta Batteries (October 2012) | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Beta Batteries (October 2012) Beta Batteries (October 2012) Fact Sheet: Sodium-Beta Batteries (October 2012) DOE's Energy Storage Program is funding research to further develop a novel planar design for sodium-beta batteries (Na-beta batteries or NBBs) that will improve energy and power densities and simplify manufacturing. This project will demonstrate a planar prototype that operates at <300 degrees Celsius and will scale up the storage capacity to 5 kW, improving on the performance levels being pursued in related battery research projects. Fact Sheet: Sodium-Beta Batteries (October 2012) More Documents & Publications Energy Storage Systems 2012 Peer Review Presentations - Poster Session 1 (Day 1): ARPA-E Projects Energy Storage Systems 2012 Peer Review and Update Meeting Advanced Materials and Devices for Stationary Electrical Energy Storage

420

Sodium arsenite impairs insulin secretion and transcription in pancreatic {beta}-cells  

Science Conference Proceedings (OSTI)

Human studies have shown that chronic inorganic arsenic (iAs) exposure is associated with a high prevalence and incidence of type 2 diabetes. However, the mechanism(s) underlying this effect are not well understood, and practically, there is no information available on the effects of arsenic on pancreatic {beta}-cells functions. Thus, since insulin secreted by the pancreas plays a crucial role in maintaining glucose homeostasis, our aim was to determine if sodium arsenite impairs insulin secretion and mRNA expression in single adult rat pancreatic {beta}-cells. Cells were treated with 0.5, 1, 2, 5 and 10 {mu}M sodium arsenite and incubated for 72 and 144 h. The highest dose tested (10 {mu}M) decreased {beta}-cell viability, by 33% and 83%, respectively. Insulin secretion and mRNA expression were evaluated in the presence of 1 and 5 {mu}M sodium arsenite. Basal insulin secretion, in 5.6 mM glucose, was not significantly affected by 1 or 5 {mu}M treatment for 72 h, but basal secretion was reduced when cells were exposed to 5 {mu}M sodium arsenite for 144 h. On the other hand, insulin secretion in response to 15.6 mM glucose decreased with sodium arsenite in a dose-dependent manner in such a way that cells were no longer able to distinguish between different glucose concentrations. We also showed a significant decrease in insulin mRNA expression of cells exposed to 5 {mu}M sodium arsenite during 72 h. Our data suggest that arsenic may contribute to the development of diabetes mellitus by impairing pancreatic {beta}-cell functions, particularly insulin synthesis and secretion.

Diaz-Villasenor, Andrea [Department of Genomic Medicine and Environmental Toxicology, Instituto de Investigaciones Biomedicas, Universidad Nacional Autonoma de Mexico (Mexico); Sanchez-Soto, M. Carmen [Department of Biophysics, Instituto de Fisiologia Celular, Universidad Nacional Autonoma de Mexico, Ciudad Universitaria, A.P. 70-253 Coyoacan, Mexico D.F. 04510 (Mexico); Cebrian, Mariano E. [Section of Environmental Toxicology, CINVESTAV, IPN, Mexico City (Mexico); Ostrosky-Wegman, Patricia [Department of Genomic Medicine and Environmental Toxicology, Instituto de Investigaciones Biomedicas, Universidad Nacional Autonoma de Mexico (Mexico); Hiriart, Marcia [Department of Biophysics, Instituto de Fisiologia Celular, Universidad Nacional Autonoma de Mexico, Ciudad Universitaria, A.P. 70-253 Coyoacan, Mexico D.F. 04510 (Mexico)]. E-mail: mhiriart@ifc.unam.mx

2006-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "na-sg sodium silica" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

A New Concept for the Fabrication of Hydrogen Selective Silica Membranes  

DOE Green Energy (OSTI)

It is attempted to synthesize hydrogen selective silica-based membranes through a novel thin film deposition concept. This report describes the progress made during the 1st Year of this award. All project Tasks, for Year 1, were completed and the first thin films were prepared and characterized. The goal of this work is to use crystalline layered silicates to form hydrogen selective membranes for use in high temperature hydrogen/carbon dioxide separations. It was proposed to: (A) Synthesize layered silicate materials; (B) Prepare dispersions of as synthesized or delaminated layered silicates; (C) Prepare membranes by coating the layered silicates on macro-mesoporous supports; and (D) Test the membranes for H{sub 2}/CO{sub 2} selectivity at high temperature and pressures and for structural and functional stability at high temperature in the presence of water vapor. All Year 1 project Tasks are completed. Layered silicate particles were synthesized hydrothermally. Crystal shape and size was optimized for the formation of thin films. Calcination procedures that avoid particle agglomeration were developed and suspensions of the calcined silicate particles were prepared. The silicate particles and suspensions were characterized by X-Ray Diffraction, Electron Microscopy and Dynamic Light Scattering. The characterization data indicate that plate like morphology, large aspect ratio and good dispersion have been achieved. A deposition process that leads to uniform, high-coverage ({approx}100%) coating of the layered silicate particles on porous alpha-alumina supports was developed.

Michael Tsapatsis

2005-10-01T23:59:59.000Z

422

Enzymatic Conversion of CO2 to Bicarbonate in Functionalized Mesoporous Silica  

Science Conference Proceedings (OSTI)

We report here that carbonic anhydrase (CA), the fastest enzyme that can covert carbon dioxide to bicarbonate, can be spontaneously entrapped in functionalized mesoporous silica (FMS) with super-high loading density (up to 0.5 mg of protein/mg of FMS) due to the dominant electrostatic interaction. The binding of CA to HOOC-FMS can result in the protein’s conformational change comparing to the enzyme free in solution, but can be overcome with increased protein loading density. The higher the protein loading density, the less conformational change, hence the higher enzymatic activity and the higher enzyme immobilization efficiency. The electrostatically bound CA can be released by changing pH. The released enzyme still displayed the native conformational structure and the same high enzymatic activity as that prior to the enzyme entrapment. This work opens up a new approach converting carbon dioxide to biocarbonate in a biomimetic nanoconfiguration that can be integrated with the other part of biosynthesis process for the assimilation of carbon dioxide.

Yu, Yuehua; Chen, Baowei; Qi, Wen N.; Li, Xiaolin; Shin, Yongsoon; Lei, Chenghong; Liu, Jun

2012-05-01T23:59:59.000Z

423

Helium Adsorption in Silica Aerogel near the Liquid-Vapor Critical Point  

E-Print Network (OSTI)

We have investigated the adsorption and desorption of helium near its liquid-vapor critical point in silica aerogels with porosities between 95 % and 98%. We used a capacitive measurement technique which allowed us to probe the helium density inside the aerogel directly, even though the samples were surrounded by bulk helium. The aerogel’s very low thermal conductivity resulted in long equilibration times so we monitored the pressure and the helium density, both inside the aerogel and in the surrounding bulk, and waited at each point until all had stabilized. Our measurements were made at temperatures far from the critical point, where a well defined liquid-vapor interface exists, and at temperatures up to the bulk critical point. Hysteresis between adsorption and desorption isotherms persisted to temperatures close to the liquid-vapor critical point and there was no sign of an equilibrium liquid-vapor transition once the hysteresis disappeared. Many features of our isotherms can be described in terms of capillary condensation, although this picture becomes less applicable as the liquid-vapor critical point is approached and it is unclear how it can be applied to aerogels, whose tenuous structure includes a wide range of length scales. I.

Tobias Herman; James Day; John Beamish

2008-01-01T23:59:59.000Z

424

Compressed Silica Aerogels for the Study of Superfluid [superscript 3]He  

SciTech Connect

We have performed Small Angle X-ray Scattering (SAXS) on uniaxially strained aerogels and measured the strain-induced structural anisotropy. We use a model to connect our SAXS results to anisotropy of the {sup 3}He quasiparticle mean free path in aerogel. Measurements of the low temperature phase diagram of superfluid {sup 3}He in 98% aerogel indicate a stable B-phase and a metastable A-like phase. Vicente et al. proposed that the relative stability of these phases can be attributed to local anisotropic scattering of the 3He quasiparticles by the aerogel network. This network consists of silica strands with a diameter of {approx} 30 {angstrom} and average separation {zeta}{sub a} {approx} 300 {angstrom}. Vicente et al. also proposed using uniaxial strain of the aerogel to produce global anisotropy. We have performed SAXS on two uniaxially strained aerogels and found that strain introduces anisotropy on the {approx}100 {angstrom} length scale. We relate this to anisotropy of the quasiparticle mean free path, {lambda}.

Pollanen, J.; Choi, H.; Davis, J.P.; Blinstein, S.; Lippman, T.M.; Lurio, L.B.; Mulders, N.; Halperin, W.P. (NIU); (Delaware); (NWU)

2007-03-02T23:59:59.000Z

425

FUNCTIONALIZED SILICA AEROGELS: ADVANCED MATERIALS TO CAPTURE AND IMMOBILIZE RADIOACTIVE IODINE  

Science Conference Proceedings (OSTI)

To support the future expansion of nuclear energy, an effective method is needed to capture and safely store radiological iodine-129 released during reprocessing of spent nuclear fuel. Various materials have been investigated to capture and immobilize iodine. In most cases, however, the materials that are effective for capturing iodine cannot subsequently be sintered/densified to create a stable composite that could be a viable waste form. We have developed chemically modified, highly porous, silica aerogels that show sorption capacities higher than 440 mg of I2 per gram at 150 C. An iodine uptake test in dry air containing 4.2 ppm of iodine demonstrated no breakthrough after 3.5 h and indicated a decontamination factor in excess of 310. Preliminary densification tests showed that the I2-loaded aerogels retained more than 92 wt% of I2 after thermal sintering with pressure assistance at 1200 C for 30 min. These high capture and retention efficiencies for I2 can be further improved by optimizing the functionalization process and the chemistry as well as the sintering conditions.

Matyas, Josef; Fryxell, Glen E.; Busche, Brad J.; Wallace, Krys; Fifield, Leonard S.

2011-11-16T23:59:59.000Z

426

Helium adsorption in silica aerogel near the liquid-vapor critical point  

E-Print Network (OSTI)

We have investigated the adsorption and desorption of helium near its liquid-vapor critical point in silica aerogels with porosities between 95% and 98%. We used a capacitive measurement technique which allowed us to probe the helium density inside the aerogel directly, even though the samples were surrounded by bulk helium. The aerogel's very low thermal conductivity resulted in long equilibration times so we monitored the pressure and the helium density, both inside the aerogel and in the surrounding bulk, and waited at each point until all had stabilized. Our measurements were made at temperatures far from the critical point, where a well defined liquid-vapor interface exists, and at temperatures up to the bulk critical point. Hysteresis between adsorption and desorption isotherms persisted to temperatures close to the liquid-vapor critical point and there was no sign of an equilibrium liquid-vapor transition once the hysteresis disappeared. Many features of our isotherms can be described in terms of capillary condensation, although this picture becomes less applicable as the liquid-vapor critical point is approached and it is unclear how it can be applied to aerogels, whose tenuous structure includes a wide range of length scales.

Tobias Herman; James Day; John Beamish

2005-05-18T23:59:59.000Z

427

Tuning the properties of Ge-quantum dots superlattices in amorphous silica matrix through deposition conditions  

Science Conference Proceedings (OSTI)

In this work, we investigate the structural properties of Ge quantum dot lattices in amorphous silica matrix, prepared by low-temperature magnetron sputtering deposition of (Ge+SiO{sub 2})/SiO{sub 2} multilayers. The dependence of quantum dot shape, size, separation, and arrangement type on the Ge-rich (Ge + SiO{sub 2}) layer thickness is studied. We show that the quantum dots are elongated along the growth direction, perpendicular to the multilayer surface. The size of the quantum dots and their separation along the growth direction can be tuned by changing the Ge-rich layer thickness. The average value of the quantum dots size along the lateral (in-plane) direction along with their lateral separation is not affected by the thickness of the Ge-rich layer. However, the thickness of the Ge-rich layer significantly affects the quantum dot ordering. In addition, we investigate the dependence of the multilayer average atomic composition and also the quantum dot crystalline quality on the deposition parameters.

Pinto, S. R. C.; Ramos, M. M. D.; Gomes, M. J. M. [University of Minho, Centre of Physics and Physics Department, Braga 4710-057 (Portugal); Buljan, M. [Ruder Boskovic Institute, Bijenicka cesta 54, Zagreb 10000 (Croatia); Chahboun, A. [University of Minho, Centre of Physics and Physics Department, Braga 4710-057 (Portugal); Physics Department, FST Tanger, Tanger BP 416 (Morocco); Roldan, M. A.; Molina, S. I. [Departamento de Ciencia de los Materiales e Ing. Metalurgica y Q. I., Universidad de Cadiz, Cadiz (Spain); Bernstorff, S. [Sincrotrone Trieste, SS 14 km163, 5, Basovizza 34012 (Italy); Varela, M.; Pennycook, S. J. [Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 (United States); Barradas, N. P.; Alves, E. [Instituto Superior Tecnico e Instituto Tecnologico e Nuclear-, EN10, Sacavem 2686-953 (Portugal)

2012-04-01T23:59:59.000Z

428

Tuning the properties of Ge-quantum dots superlattices in amorphous silica matrix through deposition conditions  

Science Conference Proceedings (OSTI)

In this work, we investigate the structural properties of Ge quantum dot lattices in amorphous silica matrix, prepared by low-temperature magnetron sputtering deposition of (Ge+SiO{sub 2})/SiO{sub 2} multilayers. The dependence of quantum dot shape, size, separation, and arrangement type on the Ge-rich (Ge + SiO{sub 2}) layer thickness is studied. We show that the quantum dots are elongated along the growth direction, perpendicular to the multilayer surface. The size of the quantum dots and their separation along the growth direction can be tuned by changing the Ge-rich layer thickness. The average value of the quantum dots size along the lateral (in-plane) direction along with their lateral separation is not affected by the thickness of the Ge-rich layer. However, the thickness of the Ge-rich layer significantly affects the quantum dot ordering. In addition, we investigate the dependence of the multilayer average atomic composition and also the quantum dot crystalline quality on the deposition parameters.

Pinto, S. [University of Minho, Portugal; Roldan Gutierrez, Manuel A [ORNL; Ramos, M. M.D. [University of Minho, Portugal; Gomes, M.J.M. [University of Minho, Portugal; Molina, S. I. [Universidad de Cadiz, Spain; Pennycook, Stephen J [ORNL; Varela del Arco, Maria [ORNL; Buljan, M. [R. Boskovic Institute, Zagreb, Croatia; Barradas, N. [Instituto Tecnologico e Nuclear (ITN), Lisbon, Portugal; Alves, E. [Instituto Tecnologico e Nuclear (ITN), Lisbon, Portugal; Chahboun, A. [FST Tanger, Morocco; Bernstorff, S. [Sincrotrone Trieste, Basovizza, Italy

2012-01-01T23:59:59.000Z

429

Pyrolysis and hydropyrolysis of diphenylmethane and sulphur-containing compounds immobilised on silica  

DOE Green Energy (OSTI)

The use of high pressures and dispersed catalysts, such as sulphided molybdenum (Mo) in fixed-bed hydropyrolysis of coals give rise to increased tar yields. In order to improve our understanding of these phenomena, Particularly in relation to cleavage of C-C and C-S bonds, experiments have been conducted on samples of silica-immobilised benzene, diphenylmethane, thioanisole and dibenzothiophene (DBT). These model substrates have the inherent advantage that they do not soften and thus stay in the reactor. Moreover, for the surface-immobilized benzene, the SiO-C bond linking the substrate to the surface is reasonably stable and does not show significant cleavage until 550{degrees}C (peak maximum) with a high yield of benzene being achieved at 150 bar hydrogen pressure. For the diphenylmethane substrate, the use of 150 bar hydrogen pressure and the Mo catalyst both reduced the peak evolution temperatures for benzene and toluene clearly demonstrating their separate contributions to promoting C-C bond cleavage. Desulphurisation of the DBT substrate occurred only in hydrogen and the thermal decomposition of the thioanisole substrate was altered markedly by the Mo catalyst.

Mitchell, S.C.; Lafferty, C.J.; Garcia, R.; Ismail, K.; Snape, C.E. [Strathclyde Univ., Glasgow (United Kingdom). Dept. of Pure and Applied Chemistry; Buchanan, A.C. III; Britt, P.F. [Oak Ridge National Lab., TN (United States); Klavetter, E. [Sandia National Labs., Albuquerque, NM (United States); en

1992-08-01T23:59:59.000Z

430

Thermal and solar-optical properties of silica aerogel for use in insulated windows  

SciTech Connect

Silica aerogel is a porous insulating material that is transport to solar radiation. To understand its insulating performance in a window system, it is necessary to first study component heat transfer paths. Aerogel's absorption coefficient, a measure of the attenuation of radiation heat transfer, was determined over the spectral range 1-200 ..mu..m. Although radiation heat transfer is negligible over much of this region, there is a transmission window between 3-6 ..mu..m. At ambient temperatures, for aerogel thicknesses of 0.5-5.0 cm, radiation heat transfer through an unmodified aerogel window is less than 15% of the total heat flux. For evacuated or high-temperature furnace windows, this contribution can be over 50%. Thermal radiative transfer can be somewhat decreased by allowing the aerogel to absorb moisture, but solar transmission and optical clarity are sacrificed. Absorption of water vapor over time causes irreversible structural changes that increase scattering in the solar spectrum. Aerogel's thermal performance can be improved by replacing the pore gas with one of lower conductivity or by evacuating the aerogel to pressure below 0.1 atm. A hypothetical evacuated aerogel window has a calcuated U-Value of approx. =0.5 W/m/sup 2/-K for a gap spacing of 12.5 mm, which is four times better than currently available low-emissivity gas-filled units of similar size. 8 refs., 9 figs.

Hartmann, J.; Rubin, M.; Arasteh, D.

1987-06-01T23:59:59.000Z

431

Elastic properties of silica aerogels from a new rapid supercritical extraction process  

Science Conference Proceedings (OSTI)

Silica aerogels were produced by a new process from Tetramethoxysilane (TMOS) with ammonia as base catalyst. the process involves pouring the liquid sol in a stainless steel mold and immediately heating it to supercritical conditions. Gelation and aging occurs during heating and reaction rates are high die to high average temperatures. the gel fills the container completely, which enables relatively fast venting of the supercritical fluid by providing a constraint for swelling and failure of the gel monolith. The whole process can be completed in 6 h or less. Longitudinal and shear moduli were measured in the dried aerogels by ultrasonic velocity measurements both as a function of chemical composition of the original sol and of position in the aerogel. It was found that the sound velocity exhibits marked maxima on the surface of the cylindrical specimens and specifically close to the ends, where the fluid left during venting. Specimens with high catalyst concentration and high water:TMOS ratio exhibited higher average moduli.

Gross, J.; Coronado, P.R.; Hair, L.M.; Hrubesh, L.W.

1997-08-11T23:59:59.000Z

432

Corrugation of Phase-Separated Lipid Bilayers Supported by Nanoporous Silica Xerogel Surfaces  

Science Conference Proceedings (OSTI)

Lipid bilayers supported by substrates with nanometer-scale surface corrugations holds interest in understanding both nanoparticle-membrane interactions and the challenges of constructing models of cell membranes on surfaces with desirable properties, e.g. porosity. Here, we successfully form a two-phase (gel-fluid) lipid bilayer supported by nanoporous silica xerogel. Surface topology, diffusion, and lipid density in comparison to mica-supported lipid bilayers were characterized by AFM, FRAP, FCS, and quantitative fluorescence microscopy, respectively. We found that the two-phase lipid bilayer follows the xerogel surface contours. The corrugation imparted on the lipid bilayer results in a lipid density that is twice that on a flat mica surface. In direct agreement with the doubling of actual bilayer area in a projected area, we find that the lateral diffusion coefficient (D) of lipids on xerogel ({approx}1.7 {micro}m{sup 2}/s) is predictably lower than on mica ({approx}4.1 {micro}m{sup 2}/s) by both FRAP and FCS techniques. Furthermore, the gel-phase domains on xerogel compared to mica were larger and less numerous. Overall, our results suggest the presence of a relatively defect-free continuous two-phase bilayer that penetrates approximately midway into the first layer of {approx}50 nm xerogel beads.

Goksu, E I; Nellis, B A; Lin, W; Satcher Jr., J H; Groves, J T; Risbud, S H; Longo, M L

2008-10-30T23:59:59.000Z

433

The effect of particle-particle interaction forces on the flow properties of silica slurries  

SciTech Connect

Preliminary work has been completed to investigate the effect of particle-particle interaction forces on the flow properties of silica slurries. Classically hydro-transport studies have focused on the flow of coarse granular material in Newtonian fluids. However, with current economical and environmental pressures, the need to increase solid loadings in pipe flow has lead to studies that examine non-Newtonian fluid dynamics. The flow characteristics of non-Newtonian slurries can be greatly influenced through controlling the solution chemistry. Here we present data on an 'ideal' slurry where the particle size and shape is controlled together with the solution chemistry. We have investigated the effect of adsorbed cations on the stability of a suspension, the packing nature of a sediment and the frictional forces to be overcome during re-slurrying. A significant change in the criteria assessed was observed as the electrolyte concentration was increased from 0.1 mM to 1 M. In relation to industrial processes, such delicate control of the slurry chemistry can greatly influence the optimum operating conditions of non-Newtonian pipe flows. (authors)

Harbottle, David; Fairweather, Michael; Biggs, Simon [Institute of Particle Science and Engineering, School of Process, Environmental and Materials Engineering, University of Leeds, UK, LS2 9JT (United Kingdom); Rhodes, Dominic [Nexia Solutions, Sellafield, Cumbria (United Kingdom)

2007-07-01T23:59:59.000Z

434

Repassivation Potential of Alloy 22 in Sodium and Calcium Chloride Brines  

SciTech Connect

A comprehensive matrix of 60 tests was designed to explore the effect of calcium chloride vs. sodium chloride and the ratio R of nitrate concentration over chloride concentration on the repassivation potential of Alloy 22. Tests were conducted using the cyclic potentiodynamic polarization (CPP) technique at 75 C and at 90 C. Results show that at a ratio R of 0.18 and higher nitrate was able to inhibit the crevice corrosion in Alloy 22 induced by chloride. Current results fail to show in a consistent way a different effect on the repassivation potential of Alloy 22 for calcium chloride solutions than for sodium chloride solutions.

Rebak, R B; Ilevbare, G O; Carranza, R M

2007-08-11T23:59:59.000Z

435

Generation of a Magnetic Field by Dynamo Action in a Turbulent Flow of Liquid Sodium  

SciTech Connect

We report the observation of dynamo action in the von Karman sodium experiment, i.e., the generation of a magnetic field by a strongly turbulent swirling flow of liquid sodium. Both mean and fluctuating parts of the field are studied. The dynamo threshold corresponds to a magnetic Reynolds number R{sub m}{approx}30. A mean magnetic field of the order of 40 G is observed 30% above threshold at the flow lateral boundary. The rms fluctuations are larger than the corresponding mean value for two of the components. The scaling of the mean square magnetic field is compared to a prediction previously made for high Reynolds number flows.

Monchaux, R.; Chiffaudel, A.; Daviaud, F.; Dubrulle, B.; Gasquet, C.; Marie, L.; Ravelet, F. [Service de Physique de l'Etat Condense, Direction des Sciences de la Matiere, CEA-Saclay, CNRS URA 2464, 91191 Gif-sur-Yvette cedex (France); Berhanu, M.; Fauve, S.; Mordant, N.; Petrelis, F. [Laboratoire de Physique Statistique de l'Ecole Normale Superieure, CNRS UMR 8550, 24 Rue Lhomond, 75231 Paris Cedex 05 (France); Bourgoin, M.; Moulin, M.; Odier, Ph.; Pinton, J.-F.; Volk, R. [Laboratoire de Physique de l'Ecole Normale Superieure de Lyon, CNRS UMR 5672, 46 allee d'Italie, 69364 Lyon Cedex 07 (France)

2007-01-26T23:59:59.000Z

436

Method of making a current collector for a sodium/sulfur battery  

DOE Patents (OSTI)

This specification is directed to a method of making a current collector for a sodium/sulfur battery. The current collector so-made is electronically conductive and resistant to corrosive attack by sulfur/polysulfide melts. The method includes the step of forming the current collector for the sodium/sulfur battery from a composite material formed of aluminum filled with electronically conductive fibers selected from the group of fibers consisting essentially of graphite fibers having a diameter up to 10 microns and silicon carbide fibers having a diameter in a range of 500--1,000 angstroms. 2 figs.

Tischer, R.P.; Winterbottom, W.L.; Wroblowa, H.S.

1987-03-10T23:59:59.000Z

437

Method of making a current collector for a sodium/sulfur battery  

DOE Patents (OSTI)

This specification is directed to a method of making a current collector (14) for a sodium/sulfur battery (10). The current collector so-made is electronically conductive and resistant to corrosive attack by sulfur/polysulfide melts. The method includes the step of forming the current collector for the sodium/sulfur battery from a composite material (16) formed of aluminum filled with electronically conductive fibers selected from the group of fibers consisting essentially of graphite fibers having a diameter up to 10 microns and silicon carbide fibers having a diameter in a range of 500-1000 angstroms.

Tischer, Ragnar P. (Birmingham, MI); Winterbottom, Walter L. (Farmington Hills, MI); Wroblowa, Halina S. (West Bloomfield, MI)

1987-01-01T23:59:59.000Z

438

Preliminary analysis of patent trends for sodium/sulfur battery technology  

SciTech Connect

This document summarizes development trends in sodium/sulfur battery technology based on data from US patents. Purpose of the study was to use the activity, timing and ownership of 285 US patents to identify and describe broad patterns of change in sodium/sulfur battery technology. The analysis was conducted using newly developed statistical and computer graphic techniques for describing technology development trends from patent data. This analysis suggests that for some technologies trends in patent data provide useful information for public and private R and D planning.

Triplett, M.B.; Winter, C.; Ashton, W.B.

1985-07-01T23:59:59.000Z

439

100-MW NUCLEAR POWER PLANT UTILIZING A SODIUM COOLED, GRAPHITE MODERATED REACTOR  

SciTech Connect

The conceptual design of a 100 Mw(e) nuclear power plant is described. The plant utilized a sodium-cooled graphite-moderated reactor with stainless- steel clad. slightiy enriched UO/sub 2/ fuel. The reactor is provided with three main coolant circuits, and the steam cycle has three stages of regenerative heating. The plant control system allows automatic operation over the range of 20 to 100% load, or manual operation at all loads. The site, reactor, sodium systems, reactor auxiliaries, fuel handling, instrumentation, turbine-generator, buildings. and safety measures are described. Engineering drawings are included. (W.D.M.)

1958-02-28T23:59:59.000Z

440

Partitioning of gadolinium and its induced phase separation in sodium-aluminoborosilicate glasses  

SciTech Connect

Phase separation in sodium-aluminoborosilicate glasses was systematically studied as a function of Gd2O3 concentration with transmission electronic microscopy (TEM), energy dispersive X-ray spectroscopy (EDS) and electronic energy loss spectroscopy (EELS) methods. Dissolving Gd2O3 in sodium-aluminoborosilicate glasses causes phase separation when the Na2O/(Na2O + Al2O3) is between 0.4 and 0.6. Samples of these glasses were examined in the TEM with ELFS. The results are reported.

Qian, Maoxu; Li, Liyu; Li, Hong; Strachan, Denis M.

2003-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "na-sg sodium silica" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Current Status of Health and Safety Issues of Sodium/Metal Chloride (Zebra) Batteries  

DOE Green Energy (OSTI)

This report addresses environmental, health, and safety (EH&S) issues associated with sodium/ metal chloride batteries, in general, although most references to specific cell or battery types refer to units developed or being developed under the Zebra trademark. The report focuses on issues pertinent to sodium/metal chloride batteries and their constituent components; however, the fact that some ''issues'' arise from interaction between electric vehicle (EV) and battery design compels occasional discussion amid the context of EV vehicle design and operation. This approach has been chosen to provide a reasonably comprehensive account of the topic from a cell technology perspective and an applications perspective.

Trickett, D.

1998-12-15T23:59:59.000Z

442

EVALUATION OF CALANDRIA, THIMBLE, AND CANNED-MODERATOR CONCEPTS FOR SODIUM GRAPHITE REACTORS  

SciTech Connect

In efforts to improve the neutron economy and lower the capital costs of sodium graphite reactors, several methods of separating the sodium and graphite were investigated including the calandria, the thimble, and the canned moderator reactors. An analysis including nuclear, heat transfer, and economic comparisons was made of these SGR concepts. Based upon neutron economy and feasibility of core fabrication, the calandria concept appears to offer the greatest potential for improvement in 8GR design. The thimble concept provides some improvement in neutron economy but introduced numerous problems requiring developmental work. (auth)

Reed, G.L.

1960-06-10T23:59:59.000Z

443

F POWER MEASUREMENT FOR GENERATION IV SODIUM FAST R. COULON, S. NORMAND, M. MICHEL, L. BARBOT, T. DOMENECH,  

E-Print Network (OSTI)

.F-84500 Bollène, France. ABSTRACT The Phénix nuclear power plant has been a French Sodium Fast Reactor20 F POWER MEASUREMENT FOR GENERATION IV SODIUM FAST REACTORS R. COULON, S. NORMAND, M. MICHEL, L at the Phénix reactor shows that the use of 20 F as power tagging agent gives a fast and accurate power

444

HPS replacement project drives garage costs down. [High-pressure sodium luminaires  

SciTech Connect

The high cost of energy had forced a four-story New York airport parking garage to turn off almost half its low bay lights, leaving it gloomy and vandal-prone. By replacing the original lamps with high-pressure sodium (HPS) luminaires, the garage brightened its image with 2400 fewer fixtures and netted an annual energy savings of $60,000.

Not Available

1985-09-01T23:59:59.000Z

445

Formation and prevention of agglomerated deposits during the gasification of high-sodium lignite  

Science Conference Proceedings (OSTI)

A high-sodium lignite from the Freedom mine in North Dakota was tested in the transport gasifier at the Power Systems Development Facility (PSDF). During the first use of the high-sodium lignite in October 2003, agglomerated deposits formed at various locations in the transport gasifier system. An extensive laboratory testing program was carried out to characterize the deposits, understand the mechanism of the deposit formation, and test various methods of preventing or minimizing the agglomeration. The results of the deposit analysis and initial lab studies suggested that sodium released from the lignite was deposited on the surface of the sand bed material, resulting in the formation of sticky sodium silicates. Additional laboratory tests indicated that the agglomeration could be avoided or minimized by replacing the sand with a nonreactive bed material (e.g., coarse coal ash), operating at slightly reduced temperatures and using certain types of additives. By using these procedures, we completely eliminated the deposition problems in a subsequent gasification run in August 2004. 10 refs., 10 figs.

Robert S. Dahlin; WanWang Peng