Sample records for na ti ona

  1. A=20Na (1998TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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  2. A=16Na (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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  3. A=18Na (1995TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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  4. A=17Na (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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  5. A=19Na (1995TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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  6. Thermochemical generation of hydrogen and oxygen from water. [NaMnO/sub 2/ and TiO/sub 2/

    DOE Patents [OSTI]

    Robinson, P.R.; Bamberger, C.E.

    1980-02-08T23:59:59.000Z

    A thermochemical cyclic process for the production of hydrogen exploits the reaction between sodium manganate (NaMnO/sub 2/) and titanium dioxide (TiO/sub 2/) to form sodium titanate (Na/sub 2/TiO/sub 3/), manganese (II) titanate (MnTiO/sub 3/) and oxygen. The titanate mixture is treated with sodium hydroxide, in the presence of steam, to form sodium titanate, sodium manganate (III), water and hydrogen. The sodium titanate-manganate (III) mixture is treated with water to form sodium manganate (III), titanium dioxide and sodium hydroxide. Sodium manganate (III) and titanium dioxide are recycled following dissolution of sodium hydroxide in water.

  7. NA-42 TI Shared Software Component Library FY2011 Final Report

    SciTech Connect (OSTI)

    Knudson, Christa K.; Rutz, Frederick C.; Dorow, Kevin E.

    2011-07-21T23:59:59.000Z

    The NA-42 TI program initiated an effort in FY2010 to standardize its software development efforts with the long term goal of migrating toward a software management approach that will allow for the sharing and reuse of code developed within the TI program, improve integration, ensure a level of software documentation, and reduce development costs. The Pacific Northwest National Laboratory (PNNL) has been tasked with two activities that support this mission. PNNL has been tasked with the identification, selection, and implementation of a Shared Software Component Library. The intent of the library is to provide a common repository that is accessible by all authorized NA-42 software development teams. The repository facilitates software reuse through a searchable and easy to use web based interface. As software is submitted to the repository, the component registration process captures meta-data and provides version control for compiled libraries, documentation, and source code. This meta-data is then available for retrieval and review as part of library search results. In FY2010, PNNL and staff from the Remote Sensing Laboratory (RSL) teamed up to develop a software application with the goal of replacing the aging Aerial Measuring System (AMS). The application under development includes an Advanced Visualization and Integration of Data (AVID) framework and associated AMS modules. Throughout development, PNNL and RSL have utilized a common AMS code repository for collaborative code development. The AMS repository is hosted by PNNL, is restricted to the project development team, is accessed via two different geographic locations and continues to be used. The knowledge gained from the collaboration and hosting of this repository in conjunction with PNNL software development and systems engineering capabilities were used in the selection of a package to be used in the implementation of the software component library on behalf of NA-42 TI. The second task managed by PNNL is the development and continued maintenance of the NA-42 TI Software Development Questionnaire. This questionnaire is intended to help software development teams working under NA-42 TI in documenting their development activities. When sufficiently completed, the questionnaire illustrates that the software development activities recorded incorporate significant aspects of the software engineering lifecycle. The questionnaire template is updated as comments are received from NA-42 and/or its development teams and revised versions distributed to those using the questionnaire. PNNL also maintains a list of questionnaire recipients. The blank questionnaire template, the AVID and AMS software being developed, and the completed AVID AMS specific questionnaire are being used as the initial content to be established in the TI Component Library. This report summarizes the approach taken to identify requirements, search for and evaluate technologies, and the approach taken for installation of the software needed to host the component library. Additionally, it defines the process by which users request access for the contribution and retrieval of library content.

  8. Early-type stars observed in the ESO UVES Paranal Observatory Project: I -- Interstellar Na I UV, Ti II and Ca II K observations

    E-Print Network [OSTI]

    I. Hunter; J. V. Smoker; F. P. Keenan; C. Ledoux; E. Jehin; R. Cabanac; C. Melo; S. Bagnulo

    2006-01-17T23:59:59.000Z

    We present an analysis of interstellar Na I (lambda=3302.37\\AA, 3302.98\\AA), Ti II (lambda=3383.76\\AA) and Ca II K (lambda=3933.66\\AA) absorption features for 74 sightlines towards O- and B-type stars in the Galactic disc. The data were obtained from the UVES Paranal Observatory Project, at a spectral resolution of 3.75km/s and with mean signal to noise ratios per pixel of 260, 300 and 430 for the Na I, Ti II and Ca II observations, respectively. Interstellar features were detected in all but one of the Ti II sightlines and all of the Ca II sightlines. The dependence of the column density of these three species with distance, height relative to the Galactic plane, H I column density, reddening and depletion relative to the solar abundance has been investigated. We also examine the accuracy of using the Na I column density as an indicator of that for H I. In general we find similar strong correlations for both Ti and Ca, and weaker correlations for Na. Our results confirm the general belief that Ti and Ca occur in the same regions of the interstellar medium and also that the Ti II/Ca II ratio is constant over all parameters. We hence conclude that the absorption properties of Ti and Ca are essentially constant under the general interstellar medium conditions of the Galactic disc.

  9. Catalytic Effect of Ti for Hydrogen Cycling in NaAlH4

    Broader source: Energy.gov (indexed) [DOE]

    + 2AlH 3 3 NaAlH 4 M. Mamula et al., Coll. Czechoslov. Chem. Commun. 32, 884 (1967). Atomic Hydrogen Interacting with Al Surfaces "H adsorption and the formation of alane...

  10. Aging in the relaxor and ferroelectric state of Fe-doped (1-x)(Bi{sub 1/2}Na{sub 1/2})TiO{sub 3}-xBaTiO{sub 3} piezoelectric ceramics

    SciTech Connect (OSTI)

    Sapper, Eva; Dittmer, Robert; Rdel, Jrgen [Materials Science Department, Technische Universitt Darmstadt, 64287 Darmstadt (Germany); Damjanovic, Dragan [Ceramics Laboratory, cole Polytechnique Fdrale de Lausanne, Lausanne 1015 (Switzerland); Erdem, Emre [Institute of Physical Chemistry I, Universitt Freiburg, 79104 Freiburg (Germany); Keeble, David J. [Division of Electronic Engineering and Physics, University of Dundee, Dundee DD1 4HN (United Kingdom); Jo, Wook [School of Materials Science and Engineering, Ulsan National Institute of Science and Technology, Ulsan 689-798 (Korea, Republic of); Granzow, Torsten [Centre de Recherche PublicGabriel Lippmann, L-4422 Belvaux (Luxembourg)

    2014-09-14T23:59:59.000Z

    Aging of piezoelectric properties was investigated in lead-free (1???x)(Bi{sub 1/2}Na{sub 1/2})TiO{sub 3}-xBaTiO{sub 3} doped with 1at.?% Fe. The relaxor character of the un-poled material prevents macroscopic aging effects, while in the field-induced ferroelectric phase aging phenomena are similar to those found in lead zirconate titanate or barium titanate. Most prominent aging effects are the development of an internal bias field and the decrease of switchable polarization. These effects are temperature activated, and can be explained in the framework of defect complex reorientation. This picture is further supported by electron paramagnetic resonance spectra indicating the existence of (Fe{sub Ti}{sup ?}?V{sub O}{sup }){sup } defect complexes in the Fe-doped material.

  11. Structural investigation in the TiB{sub 2}-(Na{sub 2}O.B{sub 2}O{sub 3}.Al{sub 2}O{sub 3}) system

    SciTech Connect (OSTI)

    Buixaderas, Elena, E-mail: buixader@fzu.c [Institute of Physics, Academy of Science of the Czech Republic, Dielectrics Department, Na Slovance 2, 18221 Prague 8 (Czech Republic); Maria Anghel, Elena, E-mail: manghel@icf.r [Institute of Physical Chemistry 'Ilie Murgulescu'of Romanian Academy, Molten Salts Department, Spl. Independentei 202, 060021 Bucharest (Romania); Petrescu, Simona [Institute of Physical Chemistry 'Ilie Murgulescu'of Romanian Academy, Molten Salts Department, Spl. Independentei 202, 060021 Bucharest (Romania); Osiceanu, Petre, E-mail: posic@icf.r [Institute of Physical Chemistry 'Ilie Murgulescu' of Romanian Academy, Laboratory of Catalysis and Surface Chemistry, Spl. Independentei 202, 060021 Bucharest (Romania)

    2010-09-15T23:59:59.000Z

    Composites in the TiB{sub 2}-Na{sub 2}O.B{sub 2}O{sub 3}.Al{sub 2}O{sub 3} systems, TiB{sub 2}-MBA (MB stands for sodium metaborate and A is Al{sub 2}O{sub 3}), were prepared by self-propagating high-temperature synthesis (SHS), in simultaneous mode. Selection of these compositions was ruled by the interesting properties of both TiB{sub 2} and double borates of alkali metal and aluminum. The structure of the obtained materials was evaluated by micro-Raman spectroscopy, from room temperature up to 600 {sup o}C, and X-ray photoelectron spectroscopy (XPS). Formation of the TiB{sub 2} and TiO{sub 2-x}B{sub x} phases along with TiO{sub 2} as rutile were identified as titanium speciation in the grain phase embedded in a sodium aluminum borate matrix. Integration of the Raman spectra of the grain phases revealed a TiB{sub 2} content of 16.99% and 23.32% for the two composite investigated 2TiB{sub 2}.2MBA and 3TiB{sub 2}.5MBA. A constrained-width model for the spectral deconvolution of the high-frequency Raman band was forwarded to calculate the proportion of tetrahedral boron atoms (7.424%) in the blank borate matrix Na{sub 2}B{sub 2}O{sub 4}.Al{sub 2}O{sub 3} in solid phase. - Graphical abstract: Deconvolution of the reduced Raman spectrum of the grain phase in TiB{sub 2}-(Na{sub 2}O.B{sub 2}O{sub 3}.Al{sub 2}O{sub 3}) composite along with its Raman micrographs collected at room temperature.

  12. Unification of the negative electrocaloric effect in Bi{sub 1/2}Na{sub 1/2}TiO{sub 3}-BaTiO{sub 3} solid solutions by Ba{sub 1/2}Sr{sub 1/2}TiO{sub 3} doping

    SciTech Connect (OSTI)

    Uddin, Sarir [Department of Mechanical Engineering, The Hong Kong Polytechnic University, Hung Hom, Kowloon (Hong Kong); Materials Research Laboratory, Institute of Physics and Electronics, University of Peshawar, Peshawar 25120 (Pakistan); Zheng, Guang-Ping, E-mail: mmzheng@polyu.edu.hk [Department of Mechanical Engineering, The Hong Kong Polytechnic University, Hung Hom, Kowloon (Hong Kong); School of Materials Science and Engineering, The University of Shanghai for Science and Technology, Shanghai (China); Iqbal, Yaseen [Materials Research Laboratory, Institute of Physics and Electronics, University of Peshawar, Peshawar 25120 (Pakistan); Ubic, Rick [Department of Materials Science and Engineering, Boise State University, Boise, Idaho 83725-2090 (United States); Yang, Junhe [School of Materials Science and Engineering, The University of Shanghai for Science and Technology, Shanghai (China)

    2013-12-07T23:59:59.000Z

    The microscopic mechanisms of the negative electrocaloric effect (ECE) of the single-phase (1?x)(0.94Bi{sub 1/2}Na{sub 1/2}TiO{sub 3}-0.06BaTiO{sub 3})-xBa{sub 1/2}Sr{sub 1/2}TiO{sub 3} (BNT-BT-BST) perovskite solid solutions fabricated via the sol-gel technique are explored in this study. Dielectric and mechanical relaxation analyses are employed to investigate the ferroelectric and structural transitions of the samples. The electrocaloric properties of the samples were measured by thermodynamics Maxwell relations. The difference between the depolarization temperature (T{sub d}) and the maximum dielectric constant temperature (T{sub m}) was found to decrease with increasing BST content. Doping with BST stabilized the ferroelectric phase along with unifying the EC temperature changes (?T) to only negative values. The origin of the uniform negative ECE of BNT-BT-BST is discussed.

  13. Optimizing Synthesis of Na2Ti2SiO7 - 2H2O (Na-CST) and Ion Exchange Pathways for Cs0.4H1.6Ti2SiO7 - H2O (Cs-CST) Determined from in situ Synchrotron X-ray Powder Diffraction

    SciTech Connect (OSTI)

    Celestian,A.; Medvedev, D.; Tripathi, A.; Parise, J.; Clearfield, A.

    2005-01-01T23:59:59.000Z

    Observation of wide angle diffraction data collected in situ during previous synthesis of Na-CST (Na{sub 2}Ti{sub 2}SiO{sub 7}-2H{sub 2}O) showed initial crystallization of a precursor phase (SNT) at 30 C followed by conversion to CST after 1 h at 220 C. In situ studies of Cs{sup +} ion exchange into the H{sup +} form of CST showed a site-by-site ion exchange pathway accompanied by a simultaneous structural transition from P4{sub 2}/mbc (cell parameters a = 11.0690(6) Angstroms, c = 11.8842(6) Angstroms) to P4{sub 2}/mcm (cell parameters a = 7.847(2) Angstroms, c = 11.9100(6) Angstroms). After approximately 18% Cs{sup +} exchange into site designated Cs2 in space group P4{sub 2}/mcm, a site designated Cs1 in space group P4{sub 2}/mcm began to fill at the center of the 8MR windows until a maximum of approximately 22% exchange was achieved for Cs1. Bond valence sums of site Cs1 to framework O{sup 2-} are 1.00 v.u., while bond valence sums of site Cs2 to framework O{sup 2-} are 0.712 v.u. suggesting Cs1 to have a more stable bonding environment.

  14. Determination of crystallographic orientation of lead-free piezoelectric (K,Na)NbO{sub 3} epitaxial thin films grown on SrTiO{sub 3} (100) surfaces

    SciTech Connect (OSTI)

    Yu, Qi; Zhu, Fang-Yuan; Cheng, Li-Qian; Wang, Ke; Li, Jing-Feng, E-mail: jingfeng@mail.tsinghua.edu.cn [State Key Laboratory of New Ceramics and Fine Processing, School of Materials Science and Engineering, Tsinghua University, 100084 Beijing (China)] [State Key Laboratory of New Ceramics and Fine Processing, School of Materials Science and Engineering, Tsinghua University, 100084 Beijing (China)

    2014-03-10T23:59:59.000Z

    Crystallographic structure of sol-gel-processed lead-free (K,Na)NbO{sub 3} (KNN) epitaxial films on [100]-cut SrTiO{sub 3} single-crystalline substrates was investigated for a deeper understanding of its piezoelectric response. Lattice parameter measurement by high-resolution X-ray diffraction and transmission electron microscopy revealed that the orthorhombic KNN films on SrTiO{sub 3} (100) surfaces are [010] oriented (b-axis-oriented) rather than commonly identified c-axis orientation. Based on the crystallographic orientation and corresponding ferroelectric domain structure investigated by piezoresponse force microscopy, the superior piezoelectric property along b-axis of epitaxial KNN films than other orientations can be explained.

  15. On the crystal energy and structure of A{sub 2}Ti{sub n}O{sub 2n+1} (A=Li, Na, K) titanates by DFT calculations and neutron diffraction

    SciTech Connect (OSTI)

    Catti, Michele, E-mail: catti@mater.unimib.it [Dipartimento di Scienza dei Materiali, Universit di Milano Bicocca, Via Cozzi 53, 20125 Milano (Italy); Pinus, Ilya [Dipartimento di Scienza dei Materiali, Universit di Milano Bicocca, Via Cozzi 53, 20125 Milano (Italy); Scherillo, Antonella [ISIS Facility, CCLRC Rutherford Appleton Laboratory, Chilton, Didcot, Oxon, OX11 0QX (United Kingdom)

    2013-09-15T23:59:59.000Z

    First-principles quantum-mechanical calculations (CRYSTAL09 code, B3LYP functional) were performed on alkali titanates A{sub 2}Ti{sub n}O{sub 2n+1} with layered structure (n=3,4,6). Monoclinic structural types with unshifted (P2{sub 1}/m) and with shifted (C2/m) layers were considered. Crystal energies and full structural details were obtained for all Li, Na, and K phases. Neutron diffraction data were collected on powder samples of P2{sub 1}/m-Li{sub 2}Ti{sub 3}O{sub 7} (a=9.3146(3), b=3.7522(1), c=7.5447(3) , ?=97.611(4)) and C2/m-K{sub 2}Ti{sub 4}O{sub 9} (a=18.2578(8), b=3.79160(9), c=12.0242(4) , ?=106.459(4)) and their structures were Rietveld-refined. Computed energies show the P2{sub 1}/m arrangement as favoured over the C2/m one for n=3, and the opposite holds for n=6. In the n=4 case the P2{sub 1}/m configuration is predicted to be more stable for Li and Na, and the C2/m one for K titanates. Analysis of LiO and KO crystal-chemical environments from experiment and theory shows that the alkali atom bonding is stabilized/destabilized in the different phases consistently with the energy trend. - Graphical abstract: Display Omitted - Highlights: The P2{sub 1}/m structure-type is found to be more stable for A{sub 2}Ti{sub 3}O{sub 7} layer titanates. The C2/m structure-type is found to be more stable for A{sub 2}Ti{sub 6}O{sub 13} layer titanates. Tetratitanates are predicted to prefer the P2{sub 1}/m (Li and Na) or C2/m (K) structure. LiO and KO bond distances follow a trend consistent with computed phase energies.

  16. Structural stability and depolarization of manganese-doped (Bi{sub 0.5}Na{sub 0.5}){sub 1?x}Ba{sub x}TiO{sub 3} relaxor ferroelectrics

    SciTech Connect (OSTI)

    Wang, Sheng-Fen [Department of Physics, Fu Jen Catholic University, New Taipei City 24205, Taiwan (China); Tu, Chi-Shun, E-mail: 039611@mail.fju.edu.tw [Department of Physics, Fu Jen Catholic University, New Taipei City 24205, Taiwan (China); Graduate Institute of Applied Science and Engineering, Fu Jen Catholic University, New Taipei City 24205, Taiwan (China); Chang, Ting-Lun; Chen, Pin-Yi [Department of Mechanical Engineering, Ming-Chi University of Technology, New Taipei City 24301, Taiwan (China); Chen, Cheng-Sao [Department of Mechanical Engineering, Hwa-Hsia University of Technology, New Taipei City 23567, Taiwan (China); Hugo Schmidt, V. [Department of Physics, Montana State University, Bozeman, Montana 59717 (United States); Anthoniappen, J. [Graduate Institute of Applied Science and Engineering, Fu Jen Catholic University, New Taipei City 24205, Taiwan (China)

    2014-10-21T23:59:59.000Z

    This work reveals that 0.5?mol. % manganese (Mn) doping in (Bi{sub 0.5}Na{sub 0.5}){sub 1?x}Ba{sub x}TiO{sub 3} (x?=?0 and 0.075) solid solutions can increase structural thermal stability, depolarization temperature (T{sub d}), piezoelectric coefficient (d{sub 33}), and electromechanical coupling factor (k{sub t}). High-resolution X-ray diffraction and transmission electron microscopy reveal coexistence of rhombohedral (R) R3c and tetragonal (T) P4bm phases in (Bi{sub 0.5}Na{sub 0.5}){sub 0.925}Ba{sub 0.075}TiO{sub 3} (BN7.5BT) and 0.5?mol. % Mn-doped BN7.5BT (BN7.5BT-0.5Mn). (Bi{sub 0.5}Na{sub 0.5})TiO{sub 3} (BNT) and BN7.5BT show an R???R?+?T phase transition, which does not occur in 0.5?mol. % Mn-doped BNT (BNT-0.5Mn) and BN7.5BT-0.5Mn. Dielectric permittivity (??) follows the Curie-Weiss equation, ???=?C/(T???T{sub o}), above the Burns temperature (T{sub B}), below which polar nanoregions begin to develop. The direct piezoelectric coefficient (d{sub 33}) and electromechanical coupling factor (k{sub t}) of BN7.5BT-0.5Mn reach 190 pC/N and 47%.

  17. Numerical model to determine the composition of H2ONaClCaCl2 fluid inclusions based on

    E-Print Network [OSTI]

    Bodnar, Robert J.

    Numerical model to determine the composition of H2O­NaCl­CaCl2 fluid inclusions based 2010 Abstract Natural fluids approximated by the H2O­NaCl­CaCl2 system are common in a wide range the compositions of fluid inclusions in the H2O­NaCl­CaCl2 sys- tem based on microthermometric and microanalytical

  18. The electronic properties and lattice dynamics of (Na{sub 0.5}Bi{sub 0.5})TiO{sub 3}: From cubic to tetragonal and rhombohedral phases

    SciTech Connect (OSTI)

    L, Hongfeng [Department of Applied Physics, College of Science, China Agricultural University, Beijing 100083 (China); Wang, Shanying [Department of Physics, Tsinghua University, Beijing 100084 (China); Wang, Xiaosu, E-mail: xiaosuwang@cau.edu.cn [Department of Applied Physics, College of Science, China Agricultural University, Beijing 100083 (China); Department of Physics, Tsinghua University, Beijing 100084 (China)

    2014-03-28T23:59:59.000Z

    The structural, electronic and dynamical properties of the cubic, tetragonal and rhombohedral phases of a lead-free ferroelectrics, (Na{sub 0.5}Bi{sub 0.5})TiO{sub 3} (NBT), have been studied with a density functional formalism. The direct band gap is determined to be 2?3?eV for three phases, suggesting them to be good optical material. The equilibrium structures were given, and the importance of Bi atom in the low-symmetry ferroelectric phases were investigated with the electron localization functions analysis. The vibration modes at the ? point were calculated to provide a basis for analyzing the Raman and IR spectra. Soft modes were found in both the cubic and the tetragonal phases, providing a clue in understanding the ferroelectric phase transition in NBT.

  19. Synthesis and characterization of alkali-metal titanium alkoxide compounds MTi(O-i-Pr) sub 5 (M = Li, Na, K): Single-crystal x-ray diffraction structure of (LiTi(O-i-Pr) sub 5 ) sub 2

    SciTech Connect (OSTI)

    Hampden-Smith, M.J.; Williams, D.S. (Univ. of New Mexico, Albuquerque (USA)); Rheingold, A.L. (Univ. of Delaware, Newark (USA))

    1990-10-03T23:59:59.000Z

    The series (MTi(O-iPr){sub 5}), M = Li, Na, or K, has been prepared by the reaction of MO-i-Pr with Ti(O-i-Pr){sub 4}. A single-crystal x-ray diffraction study revealed that (LiTi(O-i-Pr){sub 5}) crystallizes from toluene at {minus}30{degree}C in the monoclinic space group P2{sub 1}/n, with unit cell dimensions a = 11.440 (8) {angstrom}, b = 16.396 (13) {angstrom}, c = 11.838 (8) {angstrom}, {beta} = 92.59 (5){degree}, and Z = 4, as a dimer containing two approximately trigonal-bipyramidal titanium centers linked by lithium bridges. In benzene solution, all three compounds are dimeric, as revealed by cryoscopic molecular weight determination, and all three undergo an alkoxide ligand exchange process that is rapid on the {sup 1}H NMR time scale at room temperature. The positions of {nu}(M-O) are assigned based on the low-energy shifts observed upon deuteriation of the isopropoxide ligands. 23 refs., 3 figs., 3 tabs.

  20. Polar nanoregions and dielectric properties in high-strain lead-free 0.93(Bi{sub 1/2}Na{sub 1/2})TiO{sub 3}-0.07BaTiO{sub 3} piezoelectric single crystals

    SciTech Connect (OSTI)

    Chen, Cheng-Sao, E-mail: rickchen@cc.hwh.edu.tw [Department of Mechanical Engineering, Hwa-Hsia Institute of Technology, New Taipei City 23567, Taiwan (China); Chen, Pin-Yi [Department of Mechanical Engineering, Ming-Chi University of Technology, New Taipei City 24301, Taiwan (China); Tu, Chi-Shun [Graduate Institute of Applied Science and Engineering, Fu Jen Catholic University, New Taipei City 24205, Taiwan (China)

    2014-01-07T23:59:59.000Z

    A structural coexistence of rhombohedral (R) and tetragonal (T) phases has been revealed in the (001){sub c}-cut lead-free 0.93(Bi{sub 1/2}Na{sub 1/2})TiO{sub 3}0.07BaTiO{sub 3} (BNB7T) piezoelectric crystals, which grown by the self-flux method, in the lower temperatures by high-resolution synchrotron X-ray diffraction, reciprocal space mapping, and transmission electron microscopy. The dielectric permittivity exhibits a thermal hysteresis in the region of 120260?C, implying a first-order-like phase transition from R+T to T. The real part (??) of dielectric permittivity begins to deviates from the Curie-Weiss equation, ???=?C/(T ? T{sub o}), from the Burns temperature T{sub B}?=?460?C, below which the polar nanoregions (or nanoclusters) develop and attenuate dielectric responses. The polar nanoregions of 510?nm were revealed by high-resolution transmission electron microscope. The normal piezoelectric coefficient d{sub 33} exhibits a rapid increase at E?=?1520?kV/cm and reaches a maximum of d{sub 33} ?450 pC/N. The high piezoelectric response and E-field induced strain in BNB7T single crystals can be attributed to structural phase transitions under an E-field application.

  1. EPR study of Ti3+ ions formed under beta irradiation in silicate

    E-Print Network [OSTI]

    Boyer, Edmond

    1 EPR study of Ti3+ ions formed under beta irradiation in silicate glasses P. Lombard1* , N. Ollier in various silicate glasses have been studied by EPR spectroscopy at 20 K. Different parameters like the [Na of the Ti3+ ion EPR spectra in different Ti-doped silicate glasses has shown three different Ti3

  2. Electrochemical corrosion behavior of biomedical Ti22Nb and Ti22Nb6Zr alloys in saline medium

    E-Print Network [OSTI]

    Zheng, Yufeng

    Electrochemical corrosion behavior of biomedical Ti­22Nb and Ti­22Nb­6Zr alloys in saline medium B addition and potentiodynamic polarization on the microstructure and corrosion resistance of Ti­22Nb and Ti­22Nb­6Zr alloy samples.The corrosion tests were carried out in 0.9% NaCl at 37 8C and neutral p

  3. Size-Dependent Detachment-Limited Decay Kinetics of Two-Dimensional TiN Islands on TiN(111)

    E-Print Network [OSTI]

    Gall, Daniel

    Size-Dependent Detachment-Limited Decay Kinetics of Two-Dimensional TiN Islands on TiN(111) S kinetics of two-dimensional TiN adatom and vacancy islands on atomically smooth TiN(111) terraces. We numbers: 68.35.Md, 68.35.Fx, 68.37.Ef, 82.45.Mp B1-NaCl structure TiN is widely used as a hard wear

  4. A Comparison of Auger Electron Spectra from Stoichiometric Epitaxial TiN,,001...

    E-Print Network [OSTI]

    Gall, Daniel

    A Comparison of Auger Electron Spectra from Stoichiometric Epitaxial TiN,,001... After ,,1... UHV spectra from epitaxial B1-NaCl-structure TiN 001 layers grown on MgO 001 1 1 by ultrahigh vacuum magnetron backscattering spectroscopy RBS . AES spectra were obtained from clean TiN 100 surfaces by cleaving 5- m

  5. Self-Organized Amorphous TiO2 Nanotube Arrays on Porous Ti Foam for Rechargeable Lithium and Sodium Ion Batteries

    SciTech Connect (OSTI)

    Bi, Zhonghe [ORNL; Paranthaman, Mariappan Parans [ORNL; Menchhofer, Paul A [ORNL; Dehoff, Ryan R [ORNL; Bridges, Craig A [ORNL; Chi, Miaofang [ORNL; Guo, Bingkun [ORNL; Sun, Xiao-Guang [ORNL; Dai, Sheng [ORNL

    2013-01-01T23:59:59.000Z

    Self-organized amorphous TiO2 nanotube arrays (NTAs) were successfully fabricated on both Ti foil and porous Ti foam through electrochemical anodization techniques. The starting Ti foams were fabricated using ARCAM s Electron Beam Melting (EBM) technology. The TiO2 NTAs on Ti foam were used as anodes in lithium ion batteries; they exhibited high capacities of 103 Ahcm-2 at 10 Acm-2 and 83 Ahcm-2 at 500 Acm-2, which are two to three times higher than those achieved on the standard Ti foil, which is around 40 Ahcm-2 at 10 Acm-2 and 24 Ahcm-2 at 500 Acm-2, respectively. This improvement is mainly attributed to higher surface area of the Ti foam and higher porosity of the nanotube arrays layer grown on the Ti foam. In addition, a Na-ion half-cell composed of these NTAs anodes and Na metal showed a self-improving specific capacity upon cycling at 10 Acm-2. These results indicate that TiO2 NTAs grown on Ti porous foam are promising electrodes for Li-ion or Na-ion rechargeable batteries.

  6. Temperature dependent near infrared ultraviolet range dielectric functions of nanocrystalline (Na{sub 0.5}Bi{sub 0.5}){sub 1?x}Ce{sub x}(Ti{sub 0.99}Fe{sub 0.01})O{sub 3} films

    SciTech Connect (OSTI)

    Zhang, S.; Zhang, J. Z.; Han, M. J.; Li, Y. W.; Hu, Z.G., E-mail: zghu@ee.ecnu.edu.cn; Chu, J. H. [Key Laboratory of Polar Materials and Devices, Ministry of Education, Department of Electronic Engineering, East China Normal University, Shanghai 200241 (China)

    2014-01-27T23:59:59.000Z

    Optical properties and phase transition of Ce-modified (Na{sub 0.5}Bi{sub 0.5})(Ti{sub 0.99}Fe{sub 0.01})O{sub 3} nanocrystalline films have been investigated by spectroscopic ellipsometry from ?70 to 500?C. Temperature dependent dielectric functions in the photon energy range of 0.66.4?eV can be derived by the Tauc-Lorentz model. It was found that the features in dielectric function (?) showed an abrupt variation near 200 and 340?C, respectively. The phenomena can be explained by the appearance and/or reversal of polarization. It indicates that ferroelectric (rhombohedral) to paraelectric (tetragonal) phase transition is related to electronic band variation, which is observed by this technique.

  7. Um novo paradigma na medicina DESENVOLVEU UMA METODOLOGIA DISRUPTIVA BASEADA NA INTEGRAO DE AVANADAS TECNOLOGIAS

    E-Print Network [OSTI]

    Instituto de Sistemas e Robotica

    Um novo paradigma na medicina do coração DESENVOLVEU UMA METODOLOGIA DISRUPTIVA BASEADA NA M?DICOS A MELHORAR DIAGN?STICOS NA MEDICINA DO CORA??O. #12;Depois do aperfeiçoamento das tecnologias pa medicina. A utilização dos resultados da genéti- ca como meio auxiliar de diagnóstico clínico é já uma

  8. Corrigendum to Zircon solubility and zirconium complexation in H2O+Na2O+SiO2Al2O3 fluids at high pressure and temperature [Earth Planet. Sci. Lett. 349-350 (2012) 15-25

    E-Print Network [OSTI]

    2013-01-01T23:59:59.000Z

    A confocal set-up for micro-XRF and XAFS experiments usingsynchrotron radiation micro-XRF. Earth Planet. Sci. Lett.diamond-anvil cell and SR-XRF: solubility of AgCl in water.

  9. Corrigendum to Zircon solubility and zirconium complexation in H2O+Na2O+SiO2Al2O3 fluids at high pressure and temperature [Earth Planet. Sci. Lett. 349-350 (2012) 15-25

    E-Print Network [OSTI]

    2013-01-01T23:59:59.000Z

    to the model compounds due to the higher energy bandwidth ofmodel compounds, these spectra were acquired at lower energyenergy (17,998 eV) means that absorption of X-rays by the diamond is low. Structural models

  10. Photocatalytic activity of undoped and Ag-doped TiO{sub 2}-supported zeolite for humic acid degradation and mineralization

    SciTech Connect (OSTI)

    Lazau, C. [National Institute for Research and Development in Electrochemistry and Condensed Matter, Timisoara, Condensed Matter Department, P. Andronescu no.1, 300254 Timisoara (Romania)] [National Institute for Research and Development in Electrochemistry and Condensed Matter, Timisoara, Condensed Matter Department, P. Andronescu no.1, 300254 Timisoara (Romania); Ratiu, C. [National Institute for Research and Development in Electrochemistry and Condensed Matter, Timisoara, Condensed Matter Department, P. Andronescu no.1, 300254 Timisoara (Romania) [National Institute for Research and Development in Electrochemistry and Condensed Matter, Timisoara, Condensed Matter Department, P. Andronescu no.1, 300254 Timisoara (Romania); National Institute for Research and Development in Microtechnologies, Erou Iancu Nicolae Street, 077190 Bucharest (Romania); Orha, C. [National Institute for Research and Development in Electrochemistry and Condensed Matter, Timisoara, Condensed Matter Department, P. Andronescu no.1, 300254 Timisoara (Romania)] [National Institute for Research and Development in Electrochemistry and Condensed Matter, Timisoara, Condensed Matter Department, P. Andronescu no.1, 300254 Timisoara (Romania); Pode, R. ['Politehnica' University of Timisoara, P-ta Victoriei no.2, 300006 Timisoara (Romania)] ['Politehnica' University of Timisoara, P-ta Victoriei no.2, 300006 Timisoara (Romania); Manea, F., E-mail: florica.manea@chim.upt.ro ['Politehnica' University of Timisoara, P-ta Victoriei no.2, 300006 Timisoara (Romania)

    2011-11-15T23:59:59.000Z

    Highlights: {yields} Hybrid materials based on natural zeolite and TiO{sub 2} obtained by solid-state reaction. {yields} XRD proved the presence of anatase form of undoped and Ag-doped TiO{sub 2} onto zeolite. {yields} FT-IR spectra evidenced the presence on TiO{sub 2} bounded at the zeolite network. {yields} Ag-doped TiO{sub 2} onto zeolitic matrix exhibited an enhanced photocatalytic activity. -- Abstract: The hybrid materials based on natural zeolite and undoped and Ag-doped TiO{sub 2}, i.e., Z-Na-TiO{sub 2} and Z-Na-TiO{sub 2}-Ag, were successfully synthesized by solid-state reaction in microwave-assisted hydrothermal conditions. Undoped TiO{sub 2} and Ag-doped TiO{sub 2} nanocrystals were previously synthesized by sol-gel method. The surface characterization of undoped TiO{sub 2}/Ag-doped TiO{sub 2} and natural zeolite hybrid materials has been investigated by X-ray diffraction, DRUV-VIS spectroscopy, FT-IR spectroscopy, BET analysis, SEM microscopy and EDX analysis. The results indicated that anatase TiO{sub 2} is the dominant crystalline type as spherical form onto zeolitic matrix. The presence of Ag into Z-Na-TiO{sub 2}-Ag was confirmed by EDX analysis. The DRUV-VIS spectra showed that Z-Na-TiO{sub 2}-Ag exhibited absorption within the range of 400-500 nm in comparison with Z-Na-TiO{sub 2} catalyst. The enhanced photocatalytic activity of Z-Na-TiO{sub 2}-Ag catalyst is proved through the degradation and mineralization of humic acid under ultraviolet and visible irradiation.

  11. An analysis of lead-free (Bi{sub 0.5}Na{sub 0.5}){sub 0.915}-(Bi{sub 0.5}K{sub 0.5}){sub 0.05}Ba{sub 0.02}Sr{sub 0.015}TiO{sub 3} ceramic for efficient refrigeration and thermal energy harvesting

    SciTech Connect (OSTI)

    Vats, Gaurav; Vaish, Rahul, E-mail: rahul@iitmandi.ac.in [School of Engineering, Indian Institute of Technology Mandi, Himachal Pradesh 175 001 (India); Bowen, Chris R. [Department of Mechanical Engineering, Materials Research Centre, University of Bath, Bath BA2 7AY (United Kingdom)

    2014-01-07T23:59:59.000Z

    This article demonstrates the colossal energy harvesting capability of a lead-free (Bi{sub 0.5}Na{sub 0.5}){sub 0.915}-(Bi{sub 0.5}K{sub 0.5}){sub 0.05}Ba{sub 0.02}Sr{sub 0.015}TiO{sub 3} ceramic using the Olsen cycle. The maximum harvestable energy density estimated for this system is found to be 1523?J/L (1523?kJ/m{sup 3}) where the results are presented for extreme ambient conditions of 20160?C and electric fields of 0.14 MV/m. This estimated energy density is 1.7 times higher than the maximum reported to date for the lanthanum-doped lead zirconate titanate (thin film) system. Moreover, this study introduces a generalized and effective solid state refrigeration cycle in contrast to the ferroelectric Ericson refrigeration cycle. The cycle is based on a temperature induced polarization change on application of an unipolar electric field to ferroelectric ceramics.

  12. In situ NiTi/Nb(Ti) composite

    SciTech Connect (OSTI)

    Jiang, Daqiang, E-mail: dq80jiang@126.com; Cui, Lishan; Jiang, Jiang; Zheng, Yanjun

    2013-12-15T23:59:59.000Z

    Graphical abstract: - Highlights: In situ NiTi/Nb(Ti) composites were fabricated. The transformation temperature was affected by the mixing Ti:Ni atomic ratios. The NiTi component became micron-scale lamella after forging and rolling. The composite exhibited high strength and high damping capacity. - Abstract: This paper reports on the creation of a series of in situ NiTi/Nb(Ti) composites with controllable transformation temperatures based on the pseudo-binary hypereutectic transformation of NiTiNb system. The composite constituent morphology was controlled by forging and rolling. It is found that the thickness of the NiTi lamella in the composite reached micron level after the hot-forging and cold-rolling. The NiTi/Nb(Ti) composite exhibited high damping capacity as well as high yield strength.

  13. High-rate and low-temperature synthesis of TiO2, TiN, and TiO2/TiN/TiO2 thin films and study of their optical and interfacial characteristics

    E-Print Network [OSTI]

    Boo, Jin-Hyo

    High-rate and low-temperature synthesis of TiO2, TiN, and TiO2/TiN/TiO2 thin films and study with unbalanced magnetrons, we deposited advanced inorganic functional thin films such as TiO2, TiN, and TiO2/Ti sputtering. The TiO2 101 and TiN 100 thin films were stoichiometric and polycrystalline but highly oriented

  14. Structure and hydrogen dynamics of pure and Ti-doped sodium alanate Jorge iguez,1,2

    E-Print Network [OSTI]

    Yildirim, Taner

    Structure and hydrogen dynamics of pure and Ti-doped sodium alanate Jorge iguez,1,2 T. Yildirim,1, Honolulu, Hawaii 96822, USA (Received 2 June 2004; published 3 August 2004) We have studied the structure, energetics, and dynamics of pure and Ti-doped sodium alanate NaAlH4 , focusing on the possibility

  15. A new Bi{sub 0.5}Na{sub 0.5}TiO{sub 3} based lead-free piezoelectric system with calculated end-member Bi(Zn{sub 0.5}Hf{sub 0.5})O{sub 3}

    SciTech Connect (OSTI)

    Liu, Feng [The Key Laboratory of Inorganic Functional Materials and Devices, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050 (China); University of Chinese Academy of Sciences, Beijing 100049 (China); Wahyudi, Olivia; Li, Yongxiang, E-mail: yxli@mail.sic.ac.cn [The Key Laboratory of Inorganic Functional Materials and Devices, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050 (China)

    2014-03-21T23:59:59.000Z

    The phase structure, dielectric and piezoelectric properties of a new lead-free piezoelectric system (1???x)Bi{sub 0.5}Na{sub 0.5}TiO{sub 3}xBi(Zn{sub 0.5}Hf{sub 0.5})O{sub 3} [(1???x)BNTxBZH, x?=?0, 0.01, 0.02, 0.03, and 0.04] were investigated. The structure of Bi(Zn{sub 0.5}Hf{sub 0.5})O{sub 3} was calculated using first-principles method and (1???x)BNTxBZH ceramics were fabricated by conventional solid-state process. At room temperature, a morphotropic phase boundary (MPB) from rhombohedral to pseudocubic is identified near x?=?0.02 by the analysis of X-ray diffraction patterns. The ceramics with MPB near room temperature exhibit excellent electrical properties: the Curie temperature, maximum polarization, remnant polarization, and coercive field are 340?C, 56.3??C/cm{sup 2}, 43.5??C/cm{sup 2}, and 5.4?kV/mm, respectively, while the maximum positive bipolar strain and piezoelectric coefficient are 0.09% and 92 pC/N, respectively. In addition, a linear relationship between the MPB phase boundary composition and the calculated tetragonality of non-BNT end-member was demonstrated. Thus, this study not only shows a new BNT-based lead-free piezoelectric system but also suggest a new way to predict the composition at MPB a priori when designing new lead-free piezoelectric system.

  16. Ti (II) Mediated Reactions in Organic Chemistry

    E-Print Network [OSTI]

    Johnson, Jeff S.

    ' #12;Generation of Ti(II) from Ti(IV) · Bercaw accessed and characterized the first Ti'X -X Generation of Ti(II) via Reductive Alkylation · Ti(IV) converted to Ti(II) via reductive/Acetylene Functionalizations · Reductive Couplings #12;Advantages of Titanium · Titanium (IV) reagents are cheap and readily

  17. Giant resonances in Ti-46,Ti-48

    E-Print Network [OSTI]

    Tokimoto, Y.; Lui, Y. -W; Clark, H. L.; John, B.; Chen, X.; Youngblood, David H.

    2006-01-01T23:59:59.000Z

    PHYSICAL REVIEW C 74, 044308 (2006) Giant resonances in 46,48Ti Y. Tokimoto, Y.-W. Lui, H. L. Clark, B. John,* X. Chen, and D. H. Youngblood Cyclotron Institute, Texas A&M University, College Station, Texas 77843, USA (Received 30 June 2006... parameter sets using electro- magnetic B(E2) values [14] and collective model transition potentials successfully reproduced the angular distributions of 0556-2813/2006/74(4)/044308(9) 044308-1 ?2006 The American Physical Society TOKIMOTO, LUI, CLARK, JOHN...

  18. Solubility of grossular, Ca3Al2Si3O12, in H2ONaCl solutions at 800 C and 10 kbar, and the stability of garnet in

    E-Print Network [OSTI]

    Manning, Craig

    Solubility of grossular, Ca3Al2Si3O12, in H2O­NaCl solutions at 800 °C and 10 kbar, and the stability of garnet in the system CaSiO3­Al2O3­H2O­NaCl Robert C. Newton, Craig E. Manning * Department of Earth and Space Sciences, University of California Los Angeles, Los Angeles, CA 90095-1567, USA Received

  19. Adsorption of L-aspartate to rutile (a-TiO2): Experimental and theoretical surface complexation studies

    E-Print Network [OSTI]

    Sverjensky, Dimitri A.

    Adsorption of L-aspartate to rutile (a-TiO2): Experimental and theoretical surface complexation the adsorption of L-aspartate on the surface of rutile (a-TiO2, pHPPZC = 5.4) in NaCl(aq) over a wide range of pH, ligand-to-solid ratio and ionic strength, using potentiometric titrations and batch adsorption

  20. 3d X 3d X SrTiO3Ti 2p 3d

    E-Print Network [OSTI]

    Katsumoto, Shingo

    XX 3d X 3d X X XX X XX SrTiO3Ti 2p 3d SrTiO3Ti 2p 3d 2p 2p SrTiO3 ts) 2p3/2 (t2g) 2p3/2 (e ) 2p1/2 (eg)2p SrTiO3 3d unit (t2g) (eg) (eg)2p1/2 (t2g)3d (Ti Fe Cu) arb. ( 2g) (Ti, Fe, Cu) y(ansitynten 3d In 3d 468464460456 · Photon Energy (e

  1. Above Code: What does that mean?

    E-Print Network [OSTI]

    Muns, S.

    be the most expensive t f t ht t t type of wa er hea er to opera e. Role of Governments #0;? Federal DOE i ti l d l (ICC d #0;? DOE recognizes na ona mo e s (ICC an ASHRAE), and provides technical assistance St t#0;? a es #0;? Adoption can be regulatory...;?Healthy U bl d ld til#0;?Uses renewable and recyc ed ma er a s #0;?Environmentally friendly Alt t th d f t ti#0;? erna e metho s o cons ruction #0;?Innovative, cutting edge technology Impact of Buildings #0;? 1.3 million single-family housing starts...

  2. Surface characterization and mechanical property of TiN/Ti-coated NiTi alloy by PIIID

    E-Print Network [OSTI]

    Zheng, Yufeng

    significantly reduces the friction coefficient and improves wear resistance of the NiTi alloy. © 2006 Elsevier B prosthesis, heart valve replacement and biosensors [6,7]. TiN surface coating has also been found

  3. Dual Phase Li4 Ti5O12TiO2 Nanowire Arrays As Integrated...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Phase Li4 Ti5O12TiO2 Nanowire Arrays As Integrated Anodes For High-rate Lithium-ion Batteries. Dual Phase Li4 Ti5O12TiO2 Nanowire Arrays As Integrated Anodes For...

  4. Characterization of TiN, TiC and TiCN coatings on Ti50.6 at.% Ni alloy deposited by PIII and deposition technique

    E-Print Network [OSTI]

    Zheng, Yufeng

    high content of nickel [1]. In addition, its wear resistance is expected to be improved by transition-metal as nitride, carbide and carbonitride, respectively. Based on the electrochemical measurement and ion carbides and nitrides coatings at a rather broad composition range, such as TiN, TiC and TiC1-xNx (0b?b1

  5. Report from NA49

    E-Print Network [OSTI]

    Katarzyna Grebieszkow; for the NA49 Collaboration

    2011-12-04T23:59:59.000Z

    The signatures of the onset of deconfinement, found by the NA49 experiment at low SPS energies, are confronted with new results from the Beam Energy Scan (BES) program at BNL RHIC and CERN LHC results. Additionally, new NA49 results on chemical (particle ratio) fluctuations, azimuthal angle fluctuations, intermittency of di-pions, etc. are presented.

  6. ---COrn!CTT ON---A Science service Feature

    E-Print Network [OSTI]

    doors and this undeniably had a favorable advertising effect, Pmsersby were greeted vith a blast? was over and they returned to the street the outeide air was like the breath o f e. blast

  7. NATlONA L LABORATORY Building 510A

    E-Print Network [OSTI]

    Homes, Christopher C.

    of Energy MemoJune 20, 2011 Record M. Zarcone (physics Department ESH Coordinator~ hi( M. Schueller (Medical and laboratories in Building 901 is defined as follows: The Physics Department's Manager of ESH&T Programs, or his to attend. The Physics Department will notify and invite the Facility Project Manager and the ES&H

  8. Electrochemistry properties of multilayer TiN/Ti coatings on NiTi alloy for cardiac occluder application

    E-Print Network [OSTI]

    Zheng, Yufeng

    -elasticity, thermal shape memory, high corrosion and fatigue resistance, make NiTi alloy especially suitableTi alloy is a subject of numerous recent studies to improve the material's corrosion resistance as well,b , D.Y. Zhang e a Center for Biomedical Materials and Tissue Engineering, Academy for Advanced

  9. Highly uniform bipolar resistive switching characteristics in TiO{sub 2}/BaTiO{sub 3}/TiO{sub 2} multilayer

    SciTech Connect (OSTI)

    Ma, W. J.; Zhang, X. Y.; Wang, Ying; Zheng, Yue, E-mail: zhengy35@mail.sysu.edu.cn, E-mail: wangbiao@mail.sysu.edu.cn [State Key Laboratory of Optoelectronic Materials and Technologies, School of Physics and Engineering, Sun Yat-Sen University, 510275 Guangzhou (China) [State Key Laboratory of Optoelectronic Materials and Technologies, School of Physics and Engineering, Sun Yat-Sen University, 510275 Guangzhou (China); Micro and Nano Physics and Mechanics Research Laboratory, School of Physics and Engineering, Sun Yat-Sen University, 510275 Guangzhou (China); Lin, S. P. [Micro and Nano Physics and Mechanics Research Laboratory, School of Physics and Engineering, Sun Yat-Sen University, 510275 Guangzhou (China) [Micro and Nano Physics and Mechanics Research Laboratory, School of Physics and Engineering, Sun Yat-Sen University, 510275 Guangzhou (China); Sino-French Institute of Nuclear Engineering and Technology, Zhuhai Campus, Sun Yat-Sen University, Zhuhai 519082 (China); Luo, J. M.; Wang, B., E-mail: zhengy35@mail.sysu.edu.cn, E-mail: wangbiao@mail.sysu.edu.cn [State Key Laboratory of Optoelectronic Materials and Technologies, School of Physics and Engineering, Sun Yat-Sen University, 510275 Guangzhou (China); Li, Z. X. [Micro and Nano Physics and Mechanics Research Laboratory, School of Physics and Engineering, Sun Yat-Sen University, 510275 Guangzhou (China)] [Micro and Nano Physics and Mechanics Research Laboratory, School of Physics and Engineering, Sun Yat-Sen University, 510275 Guangzhou (China)

    2013-12-23T23:59:59.000Z

    Nanoscale multilayer structure TiO{sub 2}/BaTiO{sub 3}/TiO{sub 2} has been fabricated on Pt/Ti/SiO{sub 2}/Si substrate by chemical solution deposition method. Highly uniform bipolar resistive switching (BRS) characteristics have been observed in Pt/TiO{sub 2}/BaTiO{sub 3}/TiO{sub 2}/Pt cells. Analysis of the current-voltage relationship demonstrates that the space-charge-limited current conduction controlled by the localized oxygen vacancies should be important to the resistive switching behavior. X-ray photoelectron spectroscopy results indicated that oxygen vacancies in TiO{sub 2} play a crucial role in the resistive switching phenomenon and the introduced TiO{sub 2}/BaTiO{sub 3} interfaces result in the high uniformity of bipolar resistive switching characteristics.

  10. Budu ti vypravet Michal Hruza

    E-Print Network [OSTI]

    Cerveny, Vlastislav

    ym zamava. Co ted', Tvuj usmev znam uz nazpamet, vstupenka na nebesky let o tom, ze spolu budem d, the C major lift The D baffled king H composing Halle Emi lujah Ref. Halle C lujah, Halle Emi lujah

  11. A=16Mg (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See Energy0AJ04) (See93TI07) (Not1982AJ01)Li (1993TI07)93TI07)

  12. A=20O (1998TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07) (See the Isobar98TI06)7AJ02)98TI06) (See Energy

  13. A=20n (1998TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07) (See the Isobar98TI06)7AJ02)98TI06)

  14. A=3H (1987TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07) (See the Isobar98TI06)7AJ02)98TI06)3

  15. A=8Li (2004TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07) (See4AJ01)59AJ76) (See the2004TI06)4AJ01)2004TI06)

  16. Corrosion resistance and friction of sintered NdFeB coated with Ti/TiN multilayers

    E-Print Network [OSTI]

    Volinsky, Alex A.

    Corrosion resistance and friction of sintered NdFeB coated with Ti/TiN multilayers Yuanyuan Cheng Polarization Fretting corrosion Ti/TiN multilayers were deposited on sintered NdFeB by radio frequency magnetron sputtering. The film grain size decreased with the number of multilayers in the stack. Corrosion

  17. Calculator Tips for TI-30XA

    E-Print Network [OSTI]

    Owen Davis

    2013-01-04T23:59:59.000Z

    TI-30XA Calculator Tips. Calculator Memory. - To use the memory function, hit the STO key to store a number in either memory 1, 2, or 3. o To store the product of...

  18. Combustion synthesis/quasi-isostatic pressing of TiCNiTi cermets: processing and mechanical response

    E-Print Network [OSTI]

    Meyers, Marc A.

    were produced by a technique combining self-propagating high-temperature synthesis (SHS) of elemental- transmitting medium. Self-propagating high-temperature synthesis (SHS) uses the energy of the exothermicCombustion synthesis/quasi-isostatic pressing of TiC­NiTi cermets: processing and mechanical

  19. Structure, Magnetism and Conductivity in Epitaxial Ti-doped ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Magnetism and Conductivity in Epitaxial Ti-doped -Fe2O3 Hematite: Experiment and density functional theory Structure, Magnetism and Conductivity in Epitaxial Ti-doped -Fe2O3...

  20. Oxygen Vacancies and Ferromagnetism in CoxTixy...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Vacancies and Ferromagnetism in CoxTixy. Oxygen Vacancies and Ferromagnetism in CoxTixy. Abstract: Abstract: Cobalt-doped titanium dioxide, or CTO, has...

  1. Morphology, deformation, and defect structures of TiCr{sub 2} in Ti-Cr alloys

    SciTech Connect (OSTI)

    Chen, K.C.; Allen, S.M.; Livingston, J.D.

    1992-12-31T23:59:59.000Z

    The morphologies and defect structures of TiCr{sub 2} in several Ti-Cr alloys have been examined by optical metallography, x-ray diffraction, and transmission electron microscopy (TEM), in order to explore the room-temperature deformability of the Laves phase TiCr{sub 2}. The morphology of the Laves phase was found to be dependent upon alloy composition and annealing temperature. Samples deformed by compression have also been studied using TEM. Comparisons of microstructures before and after deformation suggest an increase in twin, stacking fault, and dislocation density within the Laves phase, indicating some but not extensive room-temperature deformability.

  2. A=16C (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See Energy0AJ04) (See93TI07) (Not illustrated)93TI07) (See

  3. A=16F (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See Energy0AJ04) (See93TI07) (Not1982AJ01) (See Energy93TI07)

  4. A=16Li (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See Energy0AJ04) (See93TI07) (Not1982AJ01)Li (1993TI07) (Not

  5. A=16N (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See Energy0AJ04) (See93TI07) (Not1982AJ01)Li1982AJ01)93TI07)

  6. A=17Be (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See Energy0AJ04) (See93TI07)7AJ02)6AJ04) (Not7AJ02)93TI07)

  7. A=17C (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See Energy0AJ04) (See93TI07)7AJ02)6AJ04)2AJ01) (See the93TI07)

  8. A=18Mg, etc. (1995TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See Energy0AJ04)86AJ04) (Not6AJ04)95TI07) (Not95TI07) (Not

  9. A=18N (1995TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See Energy0AJ04)86AJ04) (Not6AJ04)95TI07)95TI07) (See Energy

  10. A=19B (1995TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See Energy0AJ04)86AJ04)1978AJ03) (See95TI07) (See3AJ01)95TI07)

  11. A=19Be (1995TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See Energy0AJ04)86AJ04)1978AJ03) (See95TI07)95TI07) (Not

  12. A=19Li (1995TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See Energy0AJ04)86AJ04)1978AJ03)72AJ02)95TI07) (Not95TI07)

  13. A=19Ne (1995TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07) (See the Isobar Diagram for 19N)83AJ01) (See95TI07)

  14. A=19O (1995TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07) (See the Isobar Diagram for83AJ01) (See95TI07) (See

  15. A=20Al, etc. (1998TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07) (See the Isobar Diagram for83AJ01)2072AJ02)98TI06)

  16. A=20C (1998TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07) (See the Isobar Diagram3AJ01)7AJ02) (Not98TI06)

  17. A=20F (1998TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07) (See the Isobar98TI06) (See Energy Level Diagrams

  18. A=20He (1998TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07) (See the Isobar98TI06) (See Energy LevelHe

  19. A=20Li (1998TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07) (See the Isobar98TI06) (See Energy LevelHeLi

  20. A=20Mg (1998TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07) (See the Isobar98TI06) (See Energy7AJ02) (See

  1. A=20N (1998TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07) (See the Isobar98TI06) (See7AJ02) (Not

  2. A=20Ne (1998TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07) (See the Isobar98TI06)7AJ02) (See Energy

  3. A=5Be (2002TI10)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07) (See the2010PU04) GENERAL: GroundPDF2002TI10) (See

  4. A=5H (2002TI10)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07) (See the2010PU04) GENERAL:4AJ01) (Not2002TI10) (Not

  5. A=5He (2002TI10)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07) (See the2010PU04) GENERAL:4AJ01)74AJ01)2002TI10)

  6. A=5n (2002TI10)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07) (See the2010PU04)66LA04) (See74AJ01)2002TI10) (Not

  7. A=6B (2002TI10)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07) (See the2010PU04)66LA04)2002TI10) (Not illustrated)

  8. A=6Be (2002TI10)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07) (See the2010PU04)66LA04)2002TI10)

  9. A=6C (2002TI10)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07) (See4AJ01) (Not illustrated) Not observed:2002TI10)

  10. A=6He (2002TI10)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07) (See4AJ01) (Not illustrated)2002TI10) (See Energy

  11. A=6n (2002TI10)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07) (See4AJ01) (Not59AJ76) (See the2002TI10) (Not

  12. A=7Be (2002TI10)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07) (See4AJ01) (Not59AJ76) (See74AJ01) (See2002TI10)

  13. A=7H (2002TI10)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07) (See4AJ01) (Not59AJ76)2002TI10) (Not illustrated)

  14. A=7He (2002TI10)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07) (See4AJ01) (Not59AJ76)2002TI10)

  15. A=8C (2004TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07) (See4AJ01)59AJ76) (See the2004TI06) (See the Isobar

  16. A=8He (2004TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07) (See4AJ01)59AJ76) (See the2004TI06) (See8AJ01)

  17. A=9Be (2004TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07) (See4AJ01)59AJ76) (See 8Li8AJ01)2004TI06) (See

  18. A=9C (2004TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07) (See4AJ01)59AJ76) (See79AJ01) (See the2004TI06)

  19. A=9He (2004TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07) (See4AJ01)59AJ76) (See79AJ01)2004TI06) (See the

  20. A=9Li (2004TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07) (See4AJ01)59AJ76) (See79AJ01)2004TI06)8AJ01)

  1. A=9N (2004TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07) (See4AJ01)59AJ76)74AJ01) (See Energy2004TI06) (Not

  2. Band Offsets at the Epitaxial Anatase TiO2/n-SrTiO3(001) Interface...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to measure valence band offsets at the epitaxial anatase TiO2(002)n-SrTiO3(001) heterojunction prepared by molecular beam epitaxy, Within experimental error, the valance band...

  3. Carrier-Controlled Ferromagnetism in SrTiO3

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Moetakef, Pouya; Williams, James R.; Ouellette, Daniel G.; Kajdos, Adam P.; Goldhaber-Gordon, David; Allen, S. James; Stemmer, Susanne

    2012-06-01T23:59:59.000Z

    Magnetotransport and superconducting properties are investigated for uniformly La-doped SrTiO3 films and GdTiO3/SrTiO3 heterostructures, respectively. GdTiO3/SrTiO3 interfaces exhibit a high-density 2D electron gas on the SrTiO3 side of the interface, while, for the SrTiO3 films, carriers are provided by the dopant atoms. Both types of samples exhibit ferromagnetism at low temperatures, as evidenced by a hysteresis in the magnetoresistance. For the uniformly doped SrTiO3 films, the Curie temperature is found to increase with doping and to coexist with superconductivity for carrier concentrations on the high-density side of the superconducting dome. The Curie temperature of the GdTiO3/SrTiO3 heterostructures scales with the thickness of the SrTiO3 quantum well. The results are used to construct a stability diagram for the ferromagnetic and superconducting phases of SrTiO3.

  4. Catalytic Effect of Ti for Hydrogen Cycling in NaAlH4 | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-Up fromDepartmentTie Ltd:June 20154:04-21-2014InnovativeCatalyst-Assisted2010 DOE

  5. Oriented Hierarchical Porous TiO2 Nanowires on Ti Substrate: Evolution of Nanostructures for Dye-Sensitized Solar Cells

    E-Print Network [OSTI]

    Park, Byungwoo

    of highly-oriented anatase TiO2 nanocrystals, are adopted as photoelectrodes in dye-sensitized solar cells. [1­4]. In particular, lightweight and flexible dye-sensitized solar cells (DSSCs) have received muchOriented Hierarchical Porous TiO2 Nanowires on Ti Substrate: Evolution of Nanostructures for Dye-Sensitized

  6. Gas-phase transport of WF6 through annular nanopipes in TiN during chemical vapor deposition of W on TiN/Ti/SiO2 structures for integrated

    E-Print Network [OSTI]

    Allen, Leslie H.

    Gas-phase transport of WF6 through annular nanopipes in TiN during chemical vapor deposition of W through the 106-nm-thick TiN film. W piles up at the TiN/Ti interface, while F rapidly saturates the TiN-sectional and scanning transmission electron microscopy analyses demonstrate that WF6 penetrates into the TiN layer

  7. Challenges for Na-ion Negative Electrodes

    E-Print Network [OSTI]

    Chevrier, V. L.

    Na-ion batteries have been proposed as candidates for replacing Li-ion batteries. In this paper we examine the viability of Na-ion negative electrode materials based on Na alloys or hard carbons in terms of volumetric ...

  8. TiNi shape memory alloy thin films for microactuator application

    E-Print Network [OSTI]

    Fu, Yongqing

    TiNi films were prepared by co-sputtering TiNi target and a separate Ti target. Crystalline structure and phase transformation behaviors of TiNi films were investigated. Results showed that TiNi films had fine grain size ...

  9. Aithisg Bhliadhnail Coilltearachd na h-Alba

    E-Print Network [OSTI]

    ' toirt thugaibh Lirmheas Bliadhnail ghdarras Coilltearachd na h-Alba 2007-08. B' e seo a' chiad bliadhna. Tha mise a' meas an Lirmheas seo mar `iris dhealbhach' an cois na h-Aithisg Bhliadhnail agus ghdarras na Coilltearachd a bhith danamh cinnteach gu lean an fhs seo agus gum bi e na bhuannachd do

  10. A=3He (1987TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07) (See the

  11. Effects of TiCl4 Purity on the Sinterability of Armstrong-Processed Ti Powder

    SciTech Connect (OSTI)

    Weil, K. Scott; Hovanski, Yuri; Lavender, Curt A.

    2009-04-03T23:59:59.000Z

    A series of high purity and low purity powders were synthesized from TiCl4 by the Armstrong process. While both powders displayed swelling when consolidated and sintered, the lower purity powder exhibited this phenomenon in significantly lower degree. The improvement is attributed to the increase in the onset of sintering temperature, which mitigates the entrapment of volatile impurities that would otherwise lead to pore formation and growth. The net effect is that the use of a lower purity TiCl4 may beneficial in two ways: (1) it is a potentially lower cost precursor to Ti powder production and (2) the trace impurities allow higher density components to be fabricated via a typical low-cost press and sinter approach.

  12. A Review Corrosion of TI Grade 7 and Other TI Alloys in Nuclear Waste Repository Environments

    SciTech Connect (OSTI)

    F. Hua; K. Mon; P. Pasupathi; G. Gordon

    2004-05-11T23:59:59.000Z

    Titanium alloy degradation modes are reviewed in relation to their performance in repository environments. General corrosion, localized corrosion, stress corrosion cracking, hydrogen induced cracking, microbially influenced corrosion, and radiation-assisted corrosion of Ti alloys are considered. With respect to the Ti Grade 7 drip shields selected for emplacement in the repository at Yucca Mountain, general corrosion, hydrogen induced cracking, and radiation-assisted corrosion will not lead to failure within the 10,000 year regulatory period; stress corrosion cracking (in the absence of disruptive events) is of no consequence to barrier performance; and localized corrosion and microbially influenced corrosion are not expected to occur. To facilitate the discussion, Ti Grades 2, 5, 7, 9, 11, 12, 16, 17, 18, and 24 are included in this review.

  13. Effect of Chemical Lithium Intercalation into Rutile TiO2 Nanorods...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemical Lithium Intercalation into Rutile TiO2 Nanorods. Effect of Chemical Lithium Intercalation into Rutile TiO2 Nanorods. Abstract: Rutile TiO2 nanorods were synthesized by...

  14. Nonthermal Water Splitting on Rutile TiO2: Electron-Stimulated...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nonthermal Water Splitting on Rutile TiO2: Electron-Stimulated Production of H-2 and O-2 in Amorphous Solid Water Films on TiO2 Nonthermal Water Splitting on Rutile TiO2:...

  15. Molecular Hydrogen Formation from Proximal Glycol Pairs on TiO2...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrogen Formation from Proximal Glycol Pairs on TiO2(110). Molecular Hydrogen Formation from Proximal Glycol Pairs on TiO2(110). Abstract: Understanding hydrogen formation on TiO2...

  16. Microstructural Characterization and Shape Memory Response of Ni-Rich NiTiHf and NiTiZr High Temperature Shape Memory Alloys

    E-Print Network [OSTI]

    Evirgen, Alper

    2014-08-14T23:59:59.000Z

    NiTiHf and NiTiZr high temperature shape memory alloys (HTSMAs) have drawn a great deal of attention as cheaper alternatives to Pt, Pd and Au alloyed NiTi-based HTSMAs while NiTiZr alloys also providing at least 20% weight reduction then its Ni...

  17. The Influence of Ni-Coated TiC on Laser-Deposited IN625 Metal Matrix Composites

    E-Print Network [OSTI]

    2010-01-01T23:59:59.000Z

    matrix and the TiC particles, the interaction between the laser beam and TiC ceramicmatrix and the TiC particles, the interaction between the laser beam and the TiC ceramic

  18. A=20Na (72AJ02)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07) (See the Isobar98TI06) (See7AJ02)98TI06)

  19. NA61/SHINE ion program

    E-Print Network [OSTI]

    Maja Mackowiak for the NA61 Collaboration

    2010-09-06T23:59:59.000Z

    The Super Proton Synchrotron (SPS) at CERN covers one of the most interesting regions of the phase diagram (T - \\mu_{B}) of strongly interacting matter. The study of central Pb+Pb collisions by NA49 indicate that the threshold for deconfinement is reached already at the low SPS energies. Theoretical considerations predict a critical point of strongly interacting matter at energies accessible at the SPS. The NA61/SHINE experiment, a successor of the NA49 project, will study hadron production in p+p, p+A, h+A, and A+A reactions at various energies. The broad physics program includes the investigation of the properties of strongly interacting matter, as well as precision measurements of hadron spectra for the T2K neutrino experiment and for the Pierre Auger Observatory and KASCADE cosmic-ray projects. The main physics goals of the NA61/SHINE ion program are to study the properties of the onset of deconfinement at low SPS energies and to find signatures of the critical point of strongly interacting matter. To achieve these goals a broad range in the (T - \\mu_{B}) phase diagram will be covered by performing an energy (10A-158A GeV/c) and system size (p+p, B+C, Ar+Ca, Xe+La) scan. The first data for this 2-D scan were taken in 2009, i.e. p+p interactions at 20, 30, 40, 80, 158 GeV/c beam energy. This contribution will summarize physics arguments for the NA61/SHINE ion program, show the detector performance and present the current status of the experiment and plans for the next years.

  20. Film Coating Process Research and Characterization of TiN Coated Racetrack-type Ceramic Pipe

    E-Print Network [OSTI]

    Wang, Jie; Zhang, Bo; Wei, Wei; Fan, Le; Pei, Xiangtao; Hong, Yuanzhi; Wang, Yong

    2015-01-01T23:59:59.000Z

    TiN film was coated on the internal face of racetrack-type ceramic pipe by three different methods: radio-frequency sputtering, DC sputtering and DC magnetron sputtering. The deposition rates of TiN film under different coating methods were compared. According to the AFM, SEM, XPS test results,these properties were analyzed, such as TiN film roughness and surface morphology. At the same time, the deposition rates were studied under two types' cathode, Ti wires and Ti plate. According to the SEM test results, Ti plate cathode can improve the TiN/Ti film deposition rate obviously.

  1. Tetraoxygen on Reduced Ti02(110): Oxygen Adsorption and Reactions...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Tetraoxygen on Reduced Ti02(110): Oxygen Adsorption and Reactions with Oxygen Vacancies. Tetraoxygen on Reduced Ti02(110): Oxygen Adsorption and Reactions with Oxygen Vacancies....

  2. TiSol | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 No revisionEnvReviewNonInvasiveExplorationUT-gTaguspark JumpDetective JumpInc., 2010) |TheseeSpringsOpenfieldTiSol

  3. Sandia National Laboratories: TiO2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas ConchasPassiveSubmitted for USMaterials ProgramProtected: Tech ReferenceEnhancementTiO2

  4. A=10He (2004TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See Energy Level Diagrams for 10Be)79AJ01)8AJ01) (Not2004TI06)

  5. A=10Ne (2004TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See Energy Level Diagrams for74AJ01) (Not79AJ01)2004TI06) (Not

  6. A=16B (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See Energy0AJ04) (See the59AJ76)6AJ01)6AJ01)93TI07) (Not

  7. A=16Be (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See Energy0AJ04) (See93TI07) (Not illustrated) This nucleus

  8. A=16He (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See Energy0AJ04) (See93TI07) (Not1982AJ01)

  9. A=16Ne (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See Energy0AJ04) (See93TI07)7AJ02) (See Energy6AJ04) (See

  10. A=16O (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See Energy0AJ04) (See93TI07)7AJ02) (See1982AJ01) (See

  11. A=16Si (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See Energy0AJ04) (See93TI07)7AJ02) (See1982AJ01)86AJ04)

  12. A=17Al (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See Energy0AJ04) (See93TI07)7AJ02) (See1982AJ01)86AJ04)Al

  13. A=17B (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See Energy0AJ04) (See93TI07)7AJ02)6AJ04) (Not illustrated)

  14. A=17F (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See Energy0AJ04) (See93TI07)7AJ02)6AJ04)2AJ01)6AJ04)

  15. A=17Mg (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See Energy0AJ04)86AJ04) (Not illustrated) NotMg (1993TI07)

  16. A=18Be (1995TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See Energy0AJ04)86AJ04) (Not6AJ04) (See8 -7AJ02) (Not95TI07)

  17. A=18C (1995TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See Energy0AJ04)86AJ04) (Not6AJ04) (See8 -7AJ02)83AJ01)95TI07)

  18. A=18F (1995TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See Energy0AJ04)86AJ04) (Not6AJ04) (See81959AJ76)95TI07) (See

  19. A=18He (1995TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See Energy0AJ04)86AJ04) (Not6AJ04)95TI07) (Not illustrated)

  20. A=18Li (1995TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See Energy0AJ04)86AJ04) (Not6AJ04)95TI07) (Not illustrated)Li

  1. A=18O (1995TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See Energy0AJ04)86AJ04)1978AJ03) (See95TI07) (See Energy Level

  2. A=19He (1995TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See Energy0AJ04)86AJ04)1978AJ03)72AJ02)95TI07) (Not observed)

  3. A=19Mg (1995TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See Energy0AJ04)86AJ04)1978AJ03)72AJ02)95TI07)83AJ01) (NotMg

  4. A=19N (1995TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07) (See the Isobar Diagram for 19N) 19N has been

  5. A=20B (1998TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07) (See the Isobar Diagram3AJ01) (Not

  6. A=20Be (1998TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07) (See the Isobar Diagram3AJ01) (Not87AJ02)

  7. A=3Li (1987TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07) (See the2010PU04) GENERAL: Ground State: Jπ =

  8. A=3n (1987TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07) (See the2010PU04) GENERAL: Ground State:

  9. A=4H (1992TI02)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07) (See the2010PU04) GENERAL: GroundPDF format TheH

  10. A=4HE (1992TI02)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07) (See the2010PU04) GENERAL: GroundPDF format TheHHe

  11. A=4Li (1992TI02)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07) (See the2010PU04) GENERAL: GroundPDF format

  12. A=4n (1992TI02)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07) (See the2010PU04) GENERAL: GroundPDF format4n

  13. A=5Li (2002TI10)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07) (See the2010PU04)66LA04) (See Energy8AJ01)

  14. A=6H (2002TI10)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07) (See4AJ01) (Not illustrated) Not4AJ01)

  15. A=6Li (2002TI10)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07) (See4AJ01) (Not

  16. A=7B (2002TI10)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07) (See4AJ01) (Not59AJ76) (See

  17. A=7Li (2002TI10)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07) (See4AJ01)

  18. A=8B (2004TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07) (See4AJ01)59AJ76) (See the Energy

  19. A=8Be (2004TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07) (See4AJ01)59AJ76) (See the Energy8B8AJ01)

  20. A=8n (2004TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07) (See4AJ01)59AJ76) (See 8Li (66LA04)8AJ01)

  1. A=9B (2004TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07) (See4AJ01)59AJ76) (See 8Li8AJ01) (See Energy

  2. Understanding the effect of halide poisoning in CO oxidation over Au/TiO[subscript 2

    SciTech Connect (OSTI)

    Oxford, S.M.; Henao, J.D.; Yang, J.H.; Kung, M.C.; Kung, H.H. (NWU)

    2008-07-08T23:59:59.000Z

    The effect of halide poisoning of Au/TiO{sub 2} catalysts in low temperature CO oxidation was investigated using bromide as the poison and a combination of X-ray absorption spectroscopy (XANES and EXAFS), quantitative CO adsorption, and catalytic measurements. It was found that halide prevented full reduction of cationic Au by displacing oxyhydroxy ligands and remaining bound to Au during low temperature reduction, causing a reduction in catalytic activity. On reduced Au samples, bromide (likely as NaBr molecule) was preferentially adsorbed on Au and not on TiO{sub 2}, and suppressed both the adsorption of CO and the catalytic activity. At low Br contents, each adsorbed Br suppressed adsorption of three CO, suggesting that Br was adsorbed on three-fold sites but the effect decreased with increasing Br content possibly due to crowding of adsorbed Br. When 5--10% of the Au was bound to Br, the catalytic activity was completely blocked, although {approx}35% of the original CO adsorption capacity remained. The data suggest that not all CO adsorption sites are catalytic active sites, and are consistent with the perimeter Au atoms at/near the particle-support interface (perimeter) being active sites.

  3. Fe(III) doped and grafted PbTiO{sub 3} film photocathode with enhanced photoactivity for hydrogen production

    SciTech Connect (OSTI)

    Hu, Yuxiang; Dong, Wen; Zheng, Fengang; Fang, Liang; Shen, Mingrong, E-mail: mrshen@suda.edu.cn [College of Physics, Optoelectronics and Energy and Collaborative Innovation Center of Suzhou Nano Science and Technology and Jiangsu Key Laboratory of Thin Films, Soochow University, 1 Shizi Street, Suzhou 215006 (China)

    2014-08-25T23:59:59.000Z

    The photoelectrochemical activity of the PbTiO{sub 3} film photocathode deposited on indium tin oxide-coated quartz substrate was significantly improved through modifying the film surface by both the Fe(III) doping and grafting. Doping the PbTiO{sub 3} with Fe(III) ions narrows its band gap thus increases the visible light utilization, while the surface-grafted Fe(III) ions on the doped PbTiO{sub 3} surface are helpful to improve the charge transfer on the photocathode/electrolyte interface. Consequently, the photocurrent was increased from 38??A/cm{sup 2} to 220??A/cm{sup 2} under the irradiation of 100 mW/cm{sup 2} Xe lamp by using 0.1M Na{sub 2}SO{sub 4} as an electrolyte and zero-potential versus saturated calomel as a reference electrode. The corresponding increase in open circuit voltage was 0.951.11?V.

  4. Facile synthesis of mesoporous core-shell TiO{sub 2} nanostructures from TiCl{sub 3}

    SciTech Connect (OSTI)

    Xue, Bin, E-mail: bxue@shou.edu.cn [Department of Chemistry, College of Food Science and Technology, Shanghai Ocean University, Shanghai 201306 (China)] [Department of Chemistry, College of Food Science and Technology, Shanghai Ocean University, Shanghai 201306 (China); Sun, Tao; Mao, Fang; Sun, Li-Chun; Yang, Wei [Department of Chemistry, College of Food Science and Technology, Shanghai Ocean University, Shanghai 201306 (China)] [Department of Chemistry, College of Food Science and Technology, Shanghai Ocean University, Shanghai 201306 (China); Xu, Zhu-De [Department of Chemistry, Zhejiang University, Hangzhou 310027 (China)] [Department of Chemistry, Zhejiang University, Hangzhou 310027 (China); Zhang, Xin [Chemical Engineering College, Inner Mongolia University of Technology, Hohhot 010051 (China)] [Chemical Engineering College, Inner Mongolia University of Technology, Hohhot 010051 (China)

    2011-09-15T23:59:59.000Z

    Highlights: {yields} Stable TiCl{sub 3} solution is adopted as Ti sources. {yields} Low-cost glucose assisted facile solvothermal reactions. {yields} Exquisite core-shell morphology and mesoporous structure of TiO{sub 2} nanostructures. {yields} Superior photocatalytic activity of TiO{sub 2} nanostructures in UV light irradiation. -- Abstract: The present study reports the synthesis and formation process of mesoporous core-shell TiO{sub 2} nanostructures by employing a glucose-assisted solvothermal process using water-ethanol mixture as solvent and subsequent calcination process at 550 {sup o}C for 4 h. X-ray diffraction, field emission scanning electron microscopy, transmission electron microscopy and nitrogen adsorption-desorption analysis were used to investigate the structural properties of these nanostructures. By optimizing the preparation conditions, especially the contents of water and ethanol in the mixture solvent, mesoporous core-shell TiO{sub 2} nanostructures were obtained. These mesoporous nanostructures have anatase phase and exhibit the superior photocatalytic activity. This synthesis route is facile due to the usage of stable and low-cost Ti precursor such as TiCl{sub 3} and is thus applicable for large-scale production.

  5. Development of Ti/Ti{sub 3}Sn functionally gradient material produced by eutectic bonding method

    SciTech Connect (OSTI)

    Kirihara, S.; Takeda, M.; Tsujimoto, T. [Ibaraki Univ., Hitachi (Japan). Faculty of Engineering] [Ibaraki Univ., Hitachi (Japan). Faculty of Engineering

    1996-07-15T23:59:59.000Z

    Although many materials which have a single function have been developed, future needs are anticipated to include materials which have various functions. A functionally gradient material (FGM) which has characteristics of two different materials is a promising candidate for multi-functional material. The present methods for production of FGM, however, are very complicated and costly. In this study the authors answer the serious problem of high production cost by fabricating the FGM by a eutectic bonding method. This fabrication method includes structural control of FGM by changing the cooling process. They describe Ti/Ti{sub 3}Sn FGM obtained by the eutectic bonding method, and tell how the structure of its composition gradient part is changed by controlling the cooling process.

  6. Low-Energy Electron Microscopy Studies of Interlayer Mass Transport Kinetics on TiN(111)

    E-Print Network [OSTI]

    Israeli, Navot

    Low-Energy Electron Microscopy Studies of Interlayer Mass Transport Kinetics on TiN(111) S annealing of three-dimensional (3D) TiN(111) mounds, consisting of stacked 2D islands, at temperatures-limited decay of 2D TiN islands on atomically-flat TiN(111) terraces [Phys. Rev. Lett. 89 (2002) 176102

  7. TiN for MEMS hotplate heaters J.F. Creemer1

    E-Print Network [OSTI]

    Technische Universiteit Delft

    TiN for MEMS hotplate heaters J.F. Creemer1 , P.M. Sarro2 , M. Laros2 , H. Schellevis2 , L, DIMES, ECTM, Mekelweg 4, 2628 CD Delft, Netherlands. Summary: Low-stress TiN has been investigated is required to protect the TiN against oxidation. Keywords: TiN thin films, micro heater, hot plate 1

  8. Measurement of neutron capture on 50Ti at thermonuclear energies

    E-Print Network [OSTI]

    P. V. Sedyshev; P. Mohr; H. Beer; H. Oberhummer; Yu. P. Popov; W. Rochow

    1999-07-28T23:59:59.000Z

    At the Karlsruhe and Tuebingen 3.75 MV Van de Graaff accelerators the thermonuclear 50Ti(n,gamma)51Ti(5.8 min) cross section was measured by the fast cyclic activation technique via the 320.852 and 928.65 keV gamma-ray lines of the 51Ti-decay. Metallic Ti samples of natural isotopic composition and samples of TiO2 enriched in 50Ti by 67.53 % were irradiated between two gold foils which served as capture standards. The capture cross-section was measured at the neutron energies 25, 30, 52, and 145 keV, respectively. The direct capture cross section was determined to be 0.387 +/- 0.011 mbarn at 30 keV. We found evidence for a bound state s-wave resonance with an estimated radiative width of 0.34 eV which destructively interfers with direct capture. The strength of a suggested s-wave resonance at 146.8 keV was determined. The present data served to calculate, in addition to the directly measured Maxwellian averaged capture cross sections at 25 and 52 keV, an improved stellar 50Ti(n,gamma)51Ti rate in the thermonuclear energy region from 1 to 250 keV. The new stellar rate leads at low temperatures to much higher values than the previously recommended rate, e.g., at kT=8 keV the increase amounts to about 50 %. The new reaction rate therefore reduces the abundance of 50Ti due to s-processing in AGB stars.

  9. Modeling and experimental studies of oxide covered metal surfaces: TiO{sub 2}/Ti a model system. Progress report

    SciTech Connect (OSTI)

    Smyrl, W.H.

    1991-12-31T23:59:59.000Z

    Prior work in our laboratories at the Corrosion Research Center has shown that thin, anodic TiO{sub 2} films formed by the Slow Growth Mode (SGM) on polycrystalline titanium and microcrystalline with a texture that varies from one metal grain to another. Furthermore, the underlying metal grains are mapped by the photoelectrochemical response of the oxide. The same characteristics have also been demonstrated in our laboratory for ZnO grown on Zn. The TiO{sub 2}/Ti system has been chosen for study both because of its importance in energy systems, and because it can serve as a model system for other metal-metal oxide couples. The investigations of anodic TiO{sub 2} films on Ti have shown that the properties of thin films are consistent with the rutile form of the oxide. Both experimental data and theoretical calculations show the close resemblance to results on single crystal TiO{sub 2}. Furthermore, the modeling studies reveal that the optical transitions near the bandedge arise from the bulk band structure. The photoelectrochemical properties of anodic TiO{sub 2} films have now been shown to obey the simple Gaertner-Butler model for the semiconductor-electrolyte interface, with a few modifications. The most important deviation has now been shown to be a result of multiple internal reflections in the oxide film.

  10. Modeling and experimental studies of oxide covered metal surfaces: TiO sub 2 /Ti a model system

    SciTech Connect (OSTI)

    Smyrl, W.H.

    1991-01-01T23:59:59.000Z

    Prior work in our laboratories at the Corrosion Research Center has shown that thin, anodic TiO{sub 2} films formed by the Slow Growth Mode (SGM) on polycrystalline titanium and microcrystalline with a texture that varies from one metal grain to another. Furthermore, the underlying metal grains are mapped by the photoelectrochemical response of the oxide. The same characteristics have also been demonstrated in our laboratory for ZnO grown on Zn. The TiO{sub 2}/Ti system has been chosen for study both because of its importance in energy systems, and because it can serve as a model system for other metal-metal oxide couples. The investigations of anodic TiO{sub 2} films on Ti have shown that the properties of thin films are consistent with the rutile form of the oxide. Both experimental data and theoretical calculations show the close resemblance to results on single crystal TiO{sub 2}. Furthermore, the modeling studies reveal that the optical transitions near the bandedge arise from the bulk band structure. The photoelectrochemical properties of anodic TiO{sub 2} films have now been shown to obey the simple Gaertner-Butler model for the semiconductor-electrolyte interface, with a few modifications. The most important deviation has now been shown to be a result of multiple internal reflections in the oxide film.

  11. TI--CR--AL--O thin film resistors

    DOE Patents [OSTI]

    Jankowski, Alan F. (Livermore, CA); Schmid, Anthony P. (Solana Beach, CA)

    2000-01-01T23:59:59.000Z

    Thin films of Ti--Cr--Al--O are used as a resistor material. The films are rf sputter deposited from ceramic targets using a reactive working gas mixture of Ar and O.sub.2. Resistivity values from 10.sup.4 to 10.sup.10 Ohm-cm have been measured for Ti--Cr--Al--O film <1 .mu.m thick. The film resistivity can be discretely selected through control of the target composition and the deposition parameters. The application of Ti--Cr--Al--O as a thin film resistor has been found to be thermodynamically stable, unlike other metal-oxide films. The Ti--Cr--Al--O film can be used as a vertical or lateral resistor, for example, as a layer beneath a field emission cathode in a flat panel display; or used to control surface emissivity, for example, as a coating on an insulating material such as vertical wall supports in flat panel displays.

  12. A=18Na (1978AJ03)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See Energy0AJ04)86AJ04) (Not6AJ04)95TI07)95TI07) (See78AJ03)

  13. A=18Na (1983AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See Energy0AJ04)86AJ04) (Not6AJ04)95TI07)95TI07)

  14. A=18Na (1987AJ02)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See Energy0AJ04)86AJ04) (Not6AJ04)95TI07)95TI07)7AJ02) (Not

  15. A=18Na (72AJ02)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See Energy0AJ04)86AJ04) (Not6AJ04)95TI07)95TI07)7AJ02)72AJ02)

  16. A=20Na (1978AJ03)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07) (See the Isobar98TI06) (See7AJ02) (Not72AJ02)

  17. A=20Na (1983AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07) (See the Isobar98TI06) (See7AJ02) (Not72AJ02)3AJ01)

  18. A=20Na (1987AJ02)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07) (See the Isobar98TI06) (See7AJ02)

  19. Seoul National UniversitySeoul National University http://bp.snu.ac.kr1 The Effect of TiCl4-Treated TiO2

    E-Print Network [OSTI]

    Park, Byungwoo

    TiO2 Compact Layer on the Performance of Dye-Sensitized Solar Cell #12;Seoul National UniversitySeoul National University http://bp.snu.ac.kr Dye-Sensitized Solar Cell 2 Schematic Diagram of the Electron Flow by the TiO2 compact layer. Electrolyte Hydrolysis of TiCl4 Solution Dye-Coated TiO2 Back Electron Transfere

  20. Low thermal expansion behavior and thermal durability of ZrTiO4Al2TiO5Fe2O3 ceramics between 750 and 1400

    E-Print Network [OSTI]

    Cao, Guozhong

    2002 Abstract The thermal-shock-resistant materials in the system Al2TiO5­ZrTiO4 (ZAT) were synthesized Aluminum titanate (Al2TiO5) is well-known as an excellent thermal shock-resistant material, resulting from. All rights reserved. Keywords: Al2TiO5; Thermal expansion; Thermal shock resistance 1. Introduction

  1. SECOND HARMONIC GENERATION OF Bi4Ti3O12 FILMS IN-SITU PROBING OF DOMAIN POLING IN Bi4Ti3O12 THIN

    E-Print Network [OSTI]

    Gopalan, Venkatraman

    SECOND HARMONIC GENERATION OF Bi4Ti3O12 FILMS IN-SITU PROBING OF DOMAIN POLING IN Bi4Ti3O12 THIN FILMS BY OPTICAL SECOND HARMONIC GENERATION YANIV BARAD, VENKATRAMAN GOPALAN Materials Research, of a ferroelectric Bi4Ti3O12 thin film using optical second harmonic generation as a probe. The ferroelectric

  2. Shape memory behavior of ultrafine grained NiTi and TiNiPd shape memory alloys

    E-Print Network [OSTI]

    Kockar, Benat

    2009-05-15T23:59:59.000Z

    The cyclic instability in shape memory characteristics of NiTi-based shape memory alloys (SMAs), such as transformation temperatures, transformation and irrecoverable strains and transformation hysteresis upon thermal and mechanical cycling limits...

  3. Hexaferrite M (Co, Ti) magnetic properties optimization

    SciTech Connect (OSTI)

    Autissier, D.; Rousselle, D.; Podembski, A. [CEA-DAM, Bruyeres-le-Chatel (France)

    1995-09-01T23:59:59.000Z

    Barium hexaferrites are anisotropic iron oxides which can present high values of permeability. We have studied Ba (Co, Ti){sub x}Fe{sub 12-2x}O{sub 19} compositions. Powders are synthesized using the ceramic method: stoichiometric amounts of basic components are ground and fired at high temperature (1170{degrees}C) to obtain the desired phase. The powders are then ground for 6 hours in order to reduce the particle size. The slurry is cast in a plaster matrix. This matrix is rotated between the poles of a stationary electromagnet. Fields of approximately 500 Oe are used for the orientation procedure. Samples are then sintered for different temperatures between 1200 and 1300{degrees}C. We present results (magnetization, permeability, permittivity, orientation rate) obtained for diverse compositions (1.1

  4. Magneto-transport in LaTi{sub 1?x}Mn{sub x}O{sub 3}/SrTiO{sub 3} oxide heterostructures

    SciTech Connect (OSTI)

    Kumar, Pramod, E-mail: pramodnpl2011@gmail.com; Dogra, Anjana, E-mail: pramodnpl2011@gmail.com; Budhani, R. C., E-mail: pramodnpl2011@gmail.com [Quantum Phenomena and Applications Division, National Physical Laboratory (CSIR), Dr. K.S. Krishnan Marg, New Delhi-110012 (India)

    2014-04-24T23:59:59.000Z

    We report the growth of ultrathin film of Mn doped LaTiO{sub 3} on TiO{sub 2} terminated SrTiO{sub 3} (001) substrate by pulsed laser deposition (PLD) and their electrical transport characteristics including magnetoresistance (MR). Though the replacement of Mn in LaTiO{sub 3} at the Ti site in dilute limit does not affect the metallic behaviour of films but variation in resistance is observed. Normalised resistance behaviour is explained on the basis of variation in charge carriers and increased interaction between Mn atoms in the system under investigation.

  5. PrOfeSSiOnaL certificate in SuStainaBiLityfOr

    E-Print Network [OSTI]

    Examines environmental sustainability at a global and national level. Studies the Green Building movement and the development of the building rating systems. Provides core/foundational knowledge in Sustainability an increasingly significant core concept for the building industry. Green initiatives and practices continue

  6. Nucleation kinetics during homoepitaxial growth of TiN(001) by reactive magnetron sputtering Marcel A. Wall, David G. Cahill, I. Petrov, D. Gall, and J. E. Greene

    E-Print Network [OSTI]

    Gall, Daniel

    Nucleation kinetics during homoepitaxial growth of TiN(001) by reactive magnetron sputtering Marcel to study the nucleation of homoepitaxial TiN layers grown on TiN(001) by ultrahigh vacuum reactive kinet- ics of TiN, a two-component refractory ceramic, on TiN 001 . TiN, typically deposited by reactive

  7. Study of Martensitic Phase transformation in a NiTiCu Thin Film...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Phase transformation in a NiTiCu Thin Film Shape Memory Alloy Using Photoelectron Emission Microscopy. Study of Martensitic Phase transformation in a NiTiCu Thin Film Shape...

  8. Hydrogen Reactivity on Highly-hydroxylated TiO2(110) Surfaces...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    TiO2(110) Surfaces Prepared via Carboxylic Acid Adsorption and Photolysis. Hydrogen Reactivity on Highly-hydroxylated TiO2(110) Surfaces Prepared via Carboxylic Acid...

  9. Thermal stability and oxidation resistance of TiCrAlYO coatings...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    stability and oxidation resistance of TiCrAlYO coatings on SS430 for solid oxide fuel cell interconnect applications. Thermal stability and oxidation resistance of TiCrAlYO...

  10. Irradiation behavior of SrTiO3 at temperatures close to the critical...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for amorphization. Abstract: Damage accumulation on both the Sr and Ti sublattices in strontium titanate (SrTiO3) has been investigated under 1.0 MeV Au+ irradiation at 360 and 400...

  11. Structure, magnetic properties and magnetoelastic anisotropy in epitaxial Sr(Ti???Co?)O? films

    E-Print Network [OSTI]

    Bi, Lei

    We report the structure, magnetic properties and magnetoelastic anisotropy of epitaxial Sr(Ti???Co?)O? films grown on LaAlO? (001) and SrTiO? (001) substrates by pulsed laser deposition. Room temperature ferromagnetism was ...

  12. BaTiO? based materials for piezoelectric and electro-optic applications

    E-Print Network [OSTI]

    Avrahami, Ytshak, 1969-

    2003-01-01T23:59:59.000Z

    Ferroelectric materials are key to many modem technologies, in particular piezoelectric actuators and electro-optic modulators. BaTiO? is one of the most extensively studied ferroelectric materials. The use of BaTiO? for ...

  13. WELDABILITY OF GRAIN-REFINED Fe-12Ni-0.25Ti STEEL FOR CRYOGENIC APPLICATIONS

    E-Print Network [OSTI]

    Morris Jr., J.W.

    2013-01-01T23:59:59.000Z

    of the Cryogenic Nickel Steels, WRC Bull, 205, May, 1975.REFINED Fe-12Ni-0.25Ti STEEL FOR CRYOGENIC APPLICATIONS D.E.REFINED Fe-12Ni-0.25Ti STEEL FOR CRYOGENIC APPLICATIONS D.

  14. Inorganic-modified semiconductor TiO2 nanotube arrays for photocatalysis

    E-Print Network [OSTI]

    Lin, Zhiqun

    titanium dioxide (TiO2) has become a promising route to degrade organic pollutants.5­8 TiO2 is one and efficient technologies to control and reduce pollution growth. Traditional techniques, such as adsorption

  15. Scanning tunneling microscopy investigation of the TiO2 anatase ,,101... surface Wilhelm Hebenstreit,1

    E-Print Network [OSTI]

    Diebold, Ulrike

    of tunneling sites in STM. Titanium dioxide (TiO2) is a versatile material that finds uses as a promoter. Fourfold-coordinated Ti atoms at step edges are preferred adsorption sites and allow the identification

  16. 2-Propanol Dehydration on TiO2(110): The Effect of Bridge-Bonded...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2-Propanol Dehydration on TiO2(110): The Effect of Bridge-Bonded Oxygen Vacancy Blocking. 2-Propanol Dehydration on TiO2(110): The Effect of Bridge-Bonded Oxygen Vacancy Blocking....

  17. Growth of Cr-doped TiO Films in the Rutile and Anatase Structures...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of Cr-doped TiO Films in the Rutile and Anatase Structures by Oxygen Plasma Assisted Molecular Beam Epitaxy . Growth of Cr-doped TiO Films in the Rutile and Anatase Structures by...

  18. Chemical Reactivity of Reduced TiO2(110): The dominant role of...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Reactivity of Reduced TiO2(110): The dominant role of surface defects in oxygen chemisorption. Chemical Reactivity of Reduced TiO2(110): The dominant role of surface defects in...

  19. Methylene Bromide Chemistry and Photochemistry on Rutile TiO2...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Methylene Bromide Chemistry and Photochemistry on Rutile TiO2(110). Methylene Bromide Chemistry and Photochemistry on Rutile TiO2(110). Abstract: The chemistry and photochemistry...

  20. Alcohol Chemistry on Rutile TiO2(110): The Influence of Alkyl...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Alcohol Chemistry on Rutile TiO2(110): The Influence of Alkyl Substituents on Reactivity and Selectivity. Alcohol Chemistry on Rutile TiO2(110): The Influence of Alkyl Substituents...

  1. Surface Chemistry of 2-Propanol on TiO2(110): Low and High Temperature...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry of 2-Propanol on TiO2(110): Low and High Temperature Dehydration, Isotope Effects, and Influence of Local Surface Chemistry of 2-Propanol on TiO2(110): Low and High...

  2. Self-assembled TiO2-Graphene Hybrid Nanostructures for Enhanced...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    TiO2-Graphene Hybrid Nanostructures for Enhanced Li-ion Insertion . Self-assembled TiO2-Graphene Hybrid Nanostructures for Enhanced Li-ion Insertion . Abstract: We used anionic...

  3. Role of polaron hopping in leakage current behavior of a SrTiO3 ...

    E-Print Network [OSTI]

    2014-03-14T23:59:59.000Z

    Dec 10, 2013 ... zirconate titanite (PZT), strontium titanite (SrTiO3), and bar- ium titanite (BaTiO3), have been widely utilized in various electronic devices such...

  4. Compton Profile Study of Intermetallic Ti{sub 3}Al

    SciTech Connect (OSTI)

    Vyas, V.; Sharma, G. [Department of Physics, Banasthali University, Banasthali-304022 (India); Mishra, M. C.; Sharma, B. K. [Department of Physics, University of Rajasthan, Jaipur-302004 (India); Joshi, K. B. [Department of Physics, University College of Science, M.L.Sukhadia University, Udaipur-313 002 (India)

    2011-10-20T23:59:59.000Z

    The Compton scattering measurement on intermetallic alloy Ti{sub 3}Al is reported in this work. The measurement is made using 59.54 keV gamma-rays from Am{sup 241} source. Theoretical calculation of Compton profile is also performed employing CRYSTAL code within the framework of density functional theory to compare with the measurement. The theoretical profile of the alloy is also synthesized following the superposition model taking the published Compton profiles of elemental solids from the APW method. The experimental study of charge transfer in the alloys has also been done by performing the experimental Compton profile measurements on Ti and Al following the superposition model and charge transfer from Al to Ti is clearly seen on the alloy formation.

  5. Corrosion behavior of newly developed TiAgFe dental alloys in neutral saline solution

    E-Print Network [OSTI]

    Zheng, Yufeng

    Corrosion behavior of newly developed Ti­Ag­Fe dental alloys in neutral saline solution B. B. Zhang, B. L. Wang, L. Li and Y. F. Zheng* The corrosion behavior of Ti­5Ag­xFe alloys (x ¼ 1, 2.5, 5 wt) Ti,Ti­ 5Ag­xFe alloys exhibited higher corrosion potentials, lower current densities, and larger

  6. TiN-Coating Effects on Stainless Steel Tribological Behavior Under Dry and Lubricated Conditions

    E-Print Network [OSTI]

    Volinsky, Alex A.

    microscopy and energy dispersive spectroscopy. TiN coatings and 316L stainless steel had better tribological (316L, 1.6 and 2.4 lm TiN coatings), 2.4 lm TiN coating exhibits the best wear resistance. The difference in wear damage of the three materials is essentially due to the wear mechanisms. For the TiN

  7. Microstructure, residual stress, and fracture of sputtered TiN films Liqiang Zhang a

    E-Print Network [OSTI]

    Volinsky, Alex A.

    Microstructure, residual stress, and fracture of sputtered TiN films Liqiang Zhang a , Huisheng Keywords: TiN films Residual stress Hardness Fracture toughness Morphology, structure, residual stress, hardness, and fracture toughness of magnetron sputtered titanium nitride (TiN) thin films, deposited at 300

  8. Site-Dependent Activity of Atomic Ti Catalysts in Al-Based Hydrogen Storage Materials

    E-Print Network [OSTI]

    Ciobanu, Cristian

    Site-Dependent Activity of Atomic Ti Catalysts in Al-Based Hydrogen Storage Materials Abdullah Al storage processes. Here we analyze the role of atomic Ti catalysts in the hydrogenation of Al-based hydrogen storage materials. We show that Ti atoms near the Al surface activate gas-phase H2, a key step

  9. Hybrid Carbon Nanotubes-TiO2 Photoanodes for High Efficiency Dye-Sensitized Solar Cells

    E-Print Network [OSTI]

    Hybrid Carbon Nanotubes-TiO2 Photoanodes for High Efficiency Dye-Sensitized Solar Cells Kadiatou photoanodes for dye- sensitized solar cells (DSCs), based on nanocrystalline TiO2 with limited addition applied (i.e., soaking in TiCl4 to boost open circuit photovoltage). INTRODUCTION Dye-sensitized solar

  10. Investigation into Photoconductivity in Single CNF/TiO2-Dye CoreShell Nanowire Devices

    E-Print Network [OSTI]

    Li, Zhuangzhi; Rochford, Caitlin; Baca, F. Javier

    2010-06-15T23:59:59.000Z

    A vertically aligned carbon nanofiber array coated with anatase TiO2 (CNF/TiO2) is an attractive possible replacement for the sintered TiO2 nanoparticle network in the original dye-sensitized solar cell (DSSC) design due to the potential...

  11. Sputtered TiN films for superconducting coplanar waveguide resonators S. Ohya,1, a)

    E-Print Network [OSTI]

    Martinis, John M.

    Sputtered TiN films for superconducting coplanar waveguide resonators S. Ohya,1, a) B. Chiaro,2 A of the properties of TiN films by varying the deposition conditions in an ultra-high-vacuum reactive magnetron changes to weak tensile in-plane strain. The TiN films absorb a high concentration of contaminants

  12. First-principles calculations of step formation energies and step interactions on TiN(001)

    E-Print Network [OSTI]

    Ciobanu, Cristian

    First-principles calculations of step formation energies and step interactions on TiN(001) Cristian the formation energies and repulsive interactions of monatomic steps on the TiN(001) surface, using den- sity studies on different aspects related to thin film growth on TiN surfaces, few atomistic studies have been

  13. TiN surface dynamics: role of surface and bulk mass transport processes

    E-Print Network [OSTI]

    Khare, Sanjay V.

    TiN surface dynamics: role of surface and bulk mass transport processes J. Bareoa , S. Kodambakab, USA Abstract. Transition-metal nitrides, such as TiN, have a wide variety of applications as hard/decay kinetics of two- and three-dimensional TiN(111) islands and the effect of surface-terminated dislocations

  14. Atomic layer deposition of TiN films Growth and electrical behavior down to

    E-Print Network [OSTI]

    Atomic layer deposition of TiN films Growth and electrical behavior down to sub-nanometer scale Hao Van Bui #12;ATOMIC LAYER DEPOSITION OF TiN FILMS GROWTH AND ELECTRICAL BEHAVIOR DOWN TO SUBD. Thesis - University of Twente, Enschede, the Netherlands Title: Atomic layer deposition of TiN films

  15. Mechanical properties of nanocrystalline and epitaxial TiN films on (100) silicon

    E-Print Network [OSTI]

    Wei, Qiuming

    Mechanical properties of nanocrystalline and epitaxial TiN films on (100) silicon H. Wang, A 2001) We investigated mechanical properties of TiN as a function of microstructure varying from nanocrystalline to single crystal TiN films deposited on (100) silicon substrates. By varying the substrate

  16. IMPROVE XRF Analysis TI 301A: LN2 Fill/Calibration

    E-Print Network [OSTI]

    Fischer, Emily V.

    IMPROVE XRF Analysis TI 301A: LN2 Fill/Calibration Page 1 of 5 TI 301A: LN2 Fills and Detector ................................................................................ 4 #12;IMPROVE XRF Analysis TI 301A: LN2 Fill/Calibration Page 2 of 5 that has been fully trained in the safety hazards of working with liquid nitrogen. #12;IMPROVE XRF

  17. Multiscale Modeling of TiO2 Nanoparticle Production in Flame Reactors: Effect of Chemical Mechanism

    E-Print Network [OSTI]

    Raman, Venkat

    Multiscale Modeling of TiO2 Nanoparticle Production in Flame Reactors: Effect of Chemical Mechanism and Engineering Mechanics, The UniVersity of Texas, Austin, Texas 78712 For titanium dioxide (TiO2) nanoparticles, catalysis, energy, and semiconductors. Titanium dioxide (TiO2) nanoparticles are traditionally used

  18. UNCORRECTEDPROOF 2 Compression behavior of porous NiTi shape memory alloy

    E-Print Network [OSTI]

    Taya, Minoru

    Ti by self-propagating 41high temperature synthesis (SHS), and again the porous 42NiTi fabricated. The compression behavior of the 11 porous NiTi was examined with the aim of using it possibly as a high energy for possible application 30 in medical implant devices and as high energy absorp- 31 tion structural material

  19. A UV light enhanced TiO2/graphene device for oxygen sensing at room temperature

    E-Print Network [OSTI]

    Cao, Wenwu

    A UV light enhanced TiO2/graphene device for oxygen sensing at room temperature Jia Zhang,ab Chao temperature oxygen sensor based on TiO2/graphene device was developed with an enhanced sensing performance­hole pairs in the TiO2 film and the photogenerated electrons were scavenged by graphene and percolated

  20. analiticheskij kompleks na: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Na monocarboxylate transport (SMCT) protein expression correlates with survival in colon cancer, 2006) We report an extensive characterization of the Na monocarboxy- late...

  1. aktinidnykh matrits na: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Na monocarboxylate transport (SMCT) protein expression correlates with survival in colon cancer, 2006) We report an extensive characterization of the Na monocarboxy- late...

  2. aprendizagem organizacional na: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Na monocarboxylate transport (SMCT) protein expression correlates with survival in colon cancer, 2006) We report an extensive characterization of the Na monocarboxy- late...

  3. aplicacao na prevencao: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Na monocarboxylate transport (SMCT) protein expression correlates with survival in colon cancer, 2006) We report an extensive characterization of the Na monocarboxy- late...

  4. acumulam na doenca: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Na monocarboxylate transport (SMCT) protein expression correlates with survival in colon cancer, 2006) We report an extensive characterization of the Na monocarboxy- late...

  5. acometido na vertigem: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Na monocarboxylate transport (SMCT) protein expression correlates with survival in colon cancer, 2006) We report an extensive characterization of the Na monocarboxy- late...

  6. apendicite aguda na: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Na monocarboxylate transport (SMCT) protein expression correlates with survival in colon cancer, 2006) We report an extensive characterization of the Na monocarboxy- late...

  7. aplicacao na producao: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Na monocarboxylate transport (SMCT) protein expression correlates with survival in colon cancer, 2006) We report an extensive characterization of the Na monocarboxy- late...

  8. argila na morfologia: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Na monocarboxylate transport (SMCT) protein expression correlates with survival in colon cancer, 2006) We report an extensive characterization of the Na monocarboxy- late...

  9. atividade pesqueira na: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Na monocarboxylate transport (SMCT) protein expression correlates with survival in colon cancer, 2006) We report an extensive characterization of the Na monocarboxy- late...

  10. adjuvante na papilomatose: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Na monocarboxylate transport (SMCT) protein expression correlates with survival in colon cancer, 2006) We report an extensive characterization of the Na monocarboxy- late...

  11. alcalino neoproterozoico na: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Na monocarboxylate transport (SMCT) protein expression correlates with survival in colon cancer, 2006) We report an extensive characterization of the Na monocarboxy- late...

  12. artificiais na bacia: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Na monocarboxylate transport (SMCT) protein expression correlates with survival in colon cancer, 2006) We report an extensive characterization of the Na monocarboxy- late...

  13. acidente na usina: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Na monocarboxylate transport (SMCT) protein expression correlates with survival in colon cancer, 2006) We report an extensive characterization of the Na monocarboxy- late...

  14. ambulatoriais na cidade: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Na monocarboxylate transport (SMCT) protein expression correlates with survival in colon cancer, 2006) We report an extensive characterization of the Na monocarboxy- late...

  15. adquirida na comunidade: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Na monocarboxylate transport (SMCT) protein expression correlates with survival in colon cancer, 2006) We report an extensive characterization of the Na monocarboxy- late...

  16. aplicacao na calibracao: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Na monocarboxylate transport (SMCT) protein expression correlates with survival in colon cancer, 2006) We report an extensive characterization of the Na monocarboxy- late...

  17. adsorbirovannogo na tverdykh: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Na monocarboxylate transport (SMCT) protein expression correlates with survival in colon cancer, 2006) We report an extensive characterization of the Na monocarboxy- late...

  18. animais silvestres na: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Na monocarboxylate transport (SMCT) protein expression correlates with survival in colon cancer, 2006) We report an extensive characterization of the Na monocarboxy- late...

  19. acidentes na industria: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Na monocarboxylate transport (SMCT) protein expression correlates with survival in colon cancer, 2006) We report an extensive characterization of the Na monocarboxy- late...

  20. aliado na busca: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Na monocarboxylate transport (SMCT) protein expression correlates with survival in colon cancer, 2006) We report an extensive characterization of the Na monocarboxy- late...

  1. alteracoes na secrecao: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Na monocarboxylate transport (SMCT) protein expression correlates with survival in colon cancer, 2006) We report an extensive characterization of the Na monocarboxy- late...

  2. auxilio na atividade: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Na monocarboxylate transport (SMCT) protein expression correlates with survival in colon cancer, 2006) We report an extensive characterization of the Na monocarboxy- late...

  3. aplicacao na dosimetria: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Na monocarboxylate transport (SMCT) protein expression correlates with survival in colon cancer, 2006) We report an extensive characterization of the Na monocarboxy- late...

  4. aplicado na automacao: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Na monocarboxylate transport (SMCT) protein expression correlates with survival in colon cancer, 2006) We report an extensive characterization of the Na monocarboxy- late...

  5. aktivnosti na fiziologicheskie: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Na monocarboxylate transport (SMCT) protein expression correlates with survival in colon cancer, 2006) We report an extensive characterization of the Na monocarboxy- late...

  6. avaliadas na semeadura: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Na monocarboxylate transport (SMCT) protein expression correlates with survival in colon cancer, 2006) We report an extensive characterization of the Na monocarboxy- late...

  7. Preparation, characterization and applications of novel carbon and nitrogen codoped TiO{sub 2} nanoparticles from annealing TiN under CO atmosphere

    SciTech Connect (OSTI)

    Sun, Mingxuan; Song, Peng; Li, Jing; Cui, Xiaoli, E-mail: xiaolicui@fudan.edu.cn

    2013-10-15T23:59:59.000Z

    Graphical abstract: Carbon and nitrogen codoped TiO{sub 2} nanoparticles were firstly fabricated by calcining TiN powder under CO atmosphere at different temperatures between 400 and 600 C, both the improved photocatalytic activity for degradation of methylene blue and enhanced photovoltaic performance for dye sensitized solar cells were demonstrated. - Highlights: CN-codoped TiO{sub 2} nanoparticles were prepared by calcining TiN under CO atmosphere. More visible light response was confirmed by UVvis DRS and photocatalytic results. Enhanced conversion efficiency was observed for the DSSCs from CN-TiO{sub 2} photoanode. CN-codoping played an important role to improve the photocatalytic performance. - Abstract: Carbon and nitrogen codoped titania (CN-TiO{sub 2}) nanoparticles were fabricated by calcining titanium nitride (TiN) nanoparticles under carbon monoxide (CO) atmosphere at four different temperatures in a range of 400600 C. The as-prepared samples were characterized with X-ray diffraction (XRD), field-emission scanning electron microscopy (FE-SEM) and X-ray photoelectron spectroscopy (XPS). Enhanced light absorption in both the UV and visible light region was observed for the resulted CN-TiO{sub 2} nanoparticles in ultraviolet-visible diffuse reflectance spectroscopy (UVvis DRS). Improved photocatalytic activity toward the degradation of methylene blue by the CN-TiO{sub 2} nanoparticles was demonstrated under UV and visible light, respectively. The highest degradation rate was achieved for CN-TiO{sub 2} nanoparticles (13%) compared to N-TiO{sub 2} (10%) and the commercial P25 (5%) under visible light illumination for 40 min. Furthermore, the improved photocatalytic activity of CN-TiO{sub 2} was also confirmed by the degradation of colorless resorcinol under UVvis light irradiation. Dye-sensitized solar cells (DSSCs) were fabricated using P25, N-TiO{sub 2} and CN-TiO{sub 2} photoanodes, respectively. The highest conversion efficiency of 3.31% was achieved by the DSSCs based on the CN-TiO{sub 2} photoanodes in comparison with the commercial P25 (1.61%) and N-TiO{sub 2} (2.44%) photoanodes. This work demonstrates that thermal treatment of TiN nanoparticles under CO atmosphere has shown to be a rapid, direct and clean approach to synthesize photocatalysts with enhanced photocatalytic and photovoltaic performance.

  8. Hysteretic electrical transport in BaTiO{sub 3}/Ba{sub 1?x}Sr{sub x}TiO{sub 3}/Ge heterostructures

    SciTech Connect (OSTI)

    Ngai, J. H.; Kumah, D. P.; Walker, F. J. [Department of Applied Physics and Center for Research on Interface Structures and Phenomena, Yale University, 15 Prospect Street, New Haven, Connecticut 06520-8284 (United States); Ahn, C. H. [Department of Applied Physics and Center for Research on Interface Structures and Phenomena, Yale University, 15 Prospect Street, New Haven, Connecticut 06520-8284 (United States); Department of Mechanical Engineering and Materials Science, Yale University, 10 Hillhouse Avenue, New Haven, Connecticut 06520-8267 (United States)

    2014-02-10T23:59:59.000Z

    We present electrical transport measurements of heterostructures comprised of BaTiO{sub 3} and Ba{sub 1?x}Sr{sub x}TiO{sub 3} epitaxially grown on Ge. Sr alloying imparts compressive strain to the BaTiO{sub 3}, which enables the thermal expansion mismatch between BaTiO{sub 3} and Ge to be overcome to achieve c-axis oriented growth. The conduction bands of BaTiO{sub 3} and Ba{sub 1?x}Sr{sub x}TiO{sub 3} are nearly aligned with the conduction band of Ge, which facilitates electron transport. Electrical transport measurements through the dielectric stack exhibit rectifying behavior and hysteresis, where the latter is consistent with ferroelectric switching.

  9. In situ corrosion analysis of Al-Zn-In-Mg-Ti-Ce sacrificial anode alloy

    SciTech Connect (OSTI)

    Ma Jingling, E-mail: majingling.student@sina.com; Wen Jiuba; Zhai Wenxia; Li Quanan

    2012-03-15T23:59:59.000Z

    The corrosion behaviour of Al-5Zn-0.02In-1Mg-0.05Ti-0.5Ce (wt.%) alloy has been investigated by immersion test, scanning electron microscopy, energy dispersive X-ray detector, electrochemical impedance spectroscopy and electrochemical noise. The results show that there exist different corrosion types of the alloy in 3.5% NaCl solution with the immersion time. At the initial stage of immersion, pitting due to the precipitates predominates the corrosion with a typical inductive loop at low frequencies in electrochemical impedance spectroscopy. The major precipitates of the alloy are MgZn{sub 2} and Al{sub 2}CeZn{sub 2} particles. The corrosion potentials of the bulk MgZn{sub 2} and Al{sub 2}CeZn{sub 2} alloys are negative with respect to that of {alpha}-Al, so the MgZn{sub 2} and Al{sub 2}CeZn{sub 2} precipitates can act as activation centre and cause the pitting. In the late corrosion, a relative uniform corrosion predominates the corrosion process controlled by the dissolution/precipitation of the In ions and characterized by a capacitive loop at medium-high frequencies in electrochemical impedance spectroscopy. The potential noise of the pitting shows larger amplitude fluctuation and lower frequency, but the potential noise of the uniform corrosion occurs with smaller amplitude fluctuation and higher frequency.

  10. Ni-Pt Silicide Formation Through Ti Mediating Layers

    SciTech Connect (OSTI)

    Besser,P.; Lavoie, C.; Ozcan, A.; Murray, C.; Strane, J.; Wong, K.; Gribelyuk, M.; Wang, Y.; Parks, C.; Jordan-Sweet, J.

    2007-01-01T23:59:59.000Z

    With Ni1-xPtxSi, the variation in queue time between the final surface cleaning and Ni-Pt deposition represents a significant manufacturability issue. A short queue time is often difficult to maintain, leading to the formation of an oxide layer on the Si substrate prior to Ni-Pt deposition that can affect the formation of Ni1-xPtxSi and its texture. In this manuscript, it will be shown that an extended queue time prior to Ni-Pt deposition leads to morphological changes in the Ni1-xPtxSi formation sequence. A layer of Ti deposited between Ni-Pt and Si reduces the native oxide and may facilitate Ni1-xPtxSi formation. With increasing Ti thickness, the presence of metal-rich phases is gradually reduced and the formation temperature of Ni1-xPtxSi increases, suggesting a direct formation of Ni1-xPtxSi from Ni-Pt. In the presence of an interfacial oxide, an increase in formation temperature is also observed with increasing Ti interlayer thickness. When the Ti layer is sufficiently thick, the phase formation sequence becomes relatively insensitive to the presence of an interfacial oxide or extended queue time.

  11. q www.Governo.it Ti trovi in: Rassegna stampa

    E-Print Network [OSTI]

    De Cindio, Fiorella

    #12;#12;#12;q www.Governo.it Ti trovi in: Rassegna stampa : STAMINALI, IN ARRIBO 12 MILIONI Da "IL. .......... .......................................... C2 www.unimi.it [.] Governo Italiano - Rassegna stampa http://rassegna.governo.it/testo.asp?d=3388912715/12/2008 13.50.59 www.Governo.it Home #12;BUR.it - Bollettino Universit & Ricerca Rubriche Bandi

  12. TI 2013-055/III Tinbergen Institute Discussion Paper

    E-Print Network [OSTI]

    Chen, Yiling

    TI 2013-055/III Tinbergen Institute Discussion Paper Parallel Sequential Monte Carlo for Efficient Density Combination: The Deco Matlab Toolbox Roberto Casarin1 Stefano Grassi2 Francesco Ravazzolo3 Herman Mahlerplein 117 1082 MS Amsterdam The Netherlands Tel.: +31(0)20 525 8579 #12;PARALLEL SEQUENTIAL MONTE CARLO

  13. cONNEcTiONS SPriNG 2015

    E-Print Network [OSTI]

    Velev, Orlin D.

    curricular cONNEcTiONS GuiDE SPriNG 2015 Aquila Theatre Wuthering Heights Photo Credit: Richard Termine (top) Susan Brandeis Design Class at the Gregg Museum Photo Credit: Matthew Gay (bottom) #12G) is a great way to integrate the arts into academic work, to foster a well-rounded education where art

  14. A Study of Oxygen Vacancy Formation and Annihilation in Submonolayer Coverages of TiO2 Dispersed on MCM-48

    E-Print Network [OSTI]

    Bell, Alexis

    A Study of Oxygen Vacancy Formation and Annihilation in Submonolayer Coverages of TiO2 Dispersed.932), suggesting the formation of oxygen vacancies. The fraction of Ti that could be reduced increased with TiO2 the TiO2 overlayer as the size of the titania patches increases. The amount of oxygen removed during

  15. Intrinsic metastability of orthorhombic HfTiO{sub 4} in thin film hafnia-titania

    SciTech Connect (OSTI)

    Cisneros-Morales, Massiel Cristina; Aita, Carolyn Rubin [Department of Chemistry and Biochemistry, University of Wisconsin-Milwaukee, P.O. Box 413, Milwaukee, Wisconsin 53201 (United States)

    2011-01-31T23:59:59.000Z

    Orthorhombic (o) HfTiO{sub 4} is crystallized when sputter deposited hafnia-titania nanolaminates with ultrathin layers and bilayer (HfO{sub 2}){sub 0.5}(TiO{sub 2}){sub 0.5} composition are annealed between 573 and 1173 K. However, o-HfTiO{sub 4} demixes after annealing at 1273 K, a result not predicted from bulk thermodynamics. X-ray diffraction and Raman microscopy are used here to study structural changes as o-HfTiO{sub 4} demixes upon long-term annealing at 1273 K into Ti-doped monoclinic HfO{sub 2} and Hf-doped rutile TiO{sub 2}. We conclude that o-HfTiO{sub 4} crystallized at low temperature is intrinsically metastable. A space group symmetry analysis shows that demixing can be accomplished by a continuous phase transition chain.

  16. Interaction of TiO{sub 2}{sup ?} with water: Photoelectron spectroscopy and density functional calculations

    SciTech Connect (OSTI)

    Li, Ren-Zhong [College of Electronics and Information, Xi'an Polytechnic University, Xi'an 710048 (China) [College of Electronics and Information, Xi'an Polytechnic University, Xi'an 710048 (China); Beijing National Laboratory for Molecular Sciences, State Key Laboratory of Molecular Reaction Dynamics, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190 (China); Xu, Hong-Guang; Cao, Guo-Jin; Xu, Xi-Ling; Zheng, Wei-Jun, E-mail: zhengwj@iccas.ac.cn [Beijing National Laboratory for Molecular Sciences, State Key Laboratory of Molecular Reaction Dynamics, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190 (China)] [Beijing National Laboratory for Molecular Sciences, State Key Laboratory of Molecular Reaction Dynamics, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190 (China)

    2013-11-14T23:59:59.000Z

    The interactions of titania with water molecules were studied via photoelectron spectroscopy and density functional calculations of TiO(OH){sub 2}{sup ?} and Ti(OH){sub 4}(H{sub 2}O){sub n}{sup ?} (n = 05) clusters which are corresponding to the TiO{sub 2}(H{sub 2}O){sup ?} and TiO{sub 2}(H{sub 2}O){sub n+2}{sup ?} (n = 05) systems, respectively. Experimental observation and theoretical calculations confirmed that TiO(OH){sub 2}{sup ?} was produced when TiO{sub 2}{sup ?} interacts with one water molecule, and Ti(OH){sub 4}(H{sub 2}O){sub n}{sup ?} (n = 05) were produced successively when TiO{sub 2}{sup ?} interacts with two or more water molecules. The structures of Ti(OH){sub 4}(H{sub 2}O){sub n}{sup ?} with n = 4, 5 are slightly different from those of n = 13. The structures of Ti(OH){sub 4}(H{sub 2}O){sub 1-3}{sup ?} can be viewed as the water molecules interacting with the Ti(OH){sub 4}{sup ?} core through hydrogen bonds; however, in Ti(OH){sub 4}(H{sub 2}O){sub 4,5}{sup ?}, one of the water molecules interacts directly with the Ti atom via its oxygen atom instead of a hydrogen bond and distorted the Ti(OH){sub 4}{sup ?} core.

  17. Au/PO43-/TiO2 and PO43-/Au/TiO2 catalysts for CO oxidation: effect of synthesis details on catalytic performance

    SciTech Connect (OSTI)

    Ma, Zhen [ORNL; Overbury, Steven {Steve} H [ORNL; Dai, Sheng [ORNL

    2007-01-01T23:59:59.000Z

    Supported gold catalysts are active for CO oxidation, but the high-temperature deactivation is a shortcoming that may constrain their applications. Herein, we attempted to address this problem by using phosphate-doped Au/TiO{sub 2} synthesized via two routes. In route I, Au/PO{sub 4}{sup 3-}/TiO{sub 2} catalysts were prepared by treating TiO{sub 2} (Degussa P25) with diluted H{sub 3}PO{sub 4}, followed by loading gold via deposition-precipitation. In route II, PO{sub 4}{sup 3-}/Au/TiO{sub 2} catalysts were prepared by treating H{sub 2}-reduced Au/TiO{sub 2} with diluted H{sub 3}PO{sub 4}. These catalysts were systematically pretreated at 200 or 500 C before reaction testing. The overall CO conversion on 200 C-pretreated Au/PO43-/TiO2 or PO43-/Au/TiO2 was always lower than that on 200 C-pretreated Au/TiO2. However, the advantage of the phosphate addition became apparent after thermal treatment at a higher temperature. Both Au/PO43-/TiO2 and PO43-/Au/TiO2 pretreated at 500 C retained significant activities at room temperature, whereas 500 C-pretreated Au/TiO2 lost its activity. Control experiments and catalyst characterization were performed to investigate the impact of synthesis details on catalytic performance.

  18. Dual Phase Li4 Ti5O12TiO2 Nanowire Arrays As Integrated Anodes For High-rate Lithium-ion Batteries

    SciTech Connect (OSTI)

    Liao, Jin; Chabot, Victor; Gu, Meng; Wang, Chong M.; Xiao, Xingcheng; Chen, Zhongwei

    2014-08-19T23:59:59.000Z

    Lithium titanate (Li4Ti5O12) is well known as a zero strain material inherently, which provides excellent long cycle stability as a negative electrode for lithium ion batteries. However, the low specific capacity (175 mA h g?1) limits it to power batteries although the low electrical conductivity is another intrinsic issue need to be solved. In this work, we developed a facile hydrothermal and ion-exchange route to synthesize the self-supported dual-phase Li4Ti5O12TiO2 nanowire arrays to further improve its capacity as well as rate capability. The ratio of Li4Ti5O12 to TiO2 in the dual phase Li4Ti5O12TiO2 nanowire is around 2:1. The introduction of TiO2 into Li4Ti5O12 increases the specific capacity. More importantly, by interface design, it creates a dual-phase nanostructure with high grain boundary density that facilitates both electron and Li ion transport. Compared with phase-pure nanowire Li4Ti5O12 and TiO2 nanaowire arrays, the dual-phase nanowire electrode yielded superior rate capability (135.5 at 5 C, 129.4 at 10 C, 120.2 at 20 C and 115.5 mA h g?1 at 30 C). In-situ transmission electron microscope clearly shows the near zero deformation of the dual phase structure, which explains its excellent cycle stability.

  19. A=16Na (1986AJ04)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See Energy0AJ04) (See93TI07)7AJ02) (See Energy Level

  20. A=17Na (71AJ02)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See Energy0AJ04)86AJ04) (Not illustrated)1AJ02)93TI07)

  1. A=17Na (77AJ02)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See Energy0AJ04)86AJ04) (Not illustrated)1AJ02)93TI07)7AJ02)

  2. A=19Na (1978AJ03)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07) (See the Isobar Diagram for 19N) 19N has78AJ03)

  3. A=19Na (1983AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07) (See the Isobar Diagram for 19N) 19N

  4. A=19Na (1987AJ02)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07) (See the Isobar Diagram for 19N) 19N7AJ02) (See the

  5. A=19Na (72AJ02)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07) (See the Isobar Diagram for 19N) 19N7AJ02)

  6. Na double-edge magneto-optic filter for Na lidar profiling of wind and temperature in the

    E-Print Network [OSTI]

    Chu, Xinzhao

    proposed by one of the authors (Williams), originating from the Na magneto-optic filter in solar-edge magneto-optic fil- ter (Na-DEMOF). It has advantages over the FPIs and iodine filters because of its magnetic field across the Na cell causes the Zeeman splitting of Na energy levels, which shifts

  7. Band gap structure modification of amorphous anodic Al oxide film by Ti-alloying

    SciTech Connect (OSTI)

    Canulescu, S., E-mail: stec@fotonik.dtu.dk; Schou, J. [Department of Photonics Engineering, Technical University of Denmark, 4000 Roskilde (Denmark); Rechendorff, K.; Pleth Nielsen, L. [Danish Technological Institute, Kongsvang Alle 29, 8000 Aarhus (Denmark); Borca, C. N. [Paul Scherrer Institute, 5232 Villigen (Switzerland); Jones, N. C.; Hoffmann, S. V. [ISA, Department of Physics and Astronomy, Aarhus University, 8000 Aarhus (Denmark); Bordo, K.; Ambat, R. [Department of Mechanical Engineering, Technical University of Denmark, 2800 Kongens Lyngby (Denmark)

    2014-03-24T23:59:59.000Z

    The band structure of pure and Ti-alloyed anodic aluminum oxide has been examined as a function of Ti concentration varying from 2 to 20 at.?%. The band gap energy of Ti-alloyed anodic Al oxide decreases with increasing Ti concentration. X-ray absorption spectroscopy reveals that Ti atoms are not located in a TiO{sub 2} unit in the oxide layer, but rather in a mixed Ti-Al oxide layer. The optical band gap energy of the anodic oxide layers was determined by vacuum ultraviolet spectroscopy in the energy range from 4.1 to 9.2?eV (300135?nm). The results indicate that amorphous anodic Al{sub 2}O{sub 3} has a direct band gap of 7.3?eV, which is about ?1.4?eV lower than its crystalline counterpart (single-crystal Al{sub 2}O{sub 3}). Upon Ti-alloying, extra bands appear within the band gap of amorphous Al{sub 2}O{sub 3}, mainly caused by Ti 3d orbitals localized at the Ti site.

  8. Structural and chemical characterization of BaTiO{sub 3} nanorods

    SciTech Connect (OSTI)

    Zagar, K.; Recnik, A.; Sturm, S. [Department for Nanostructured Materials, Jozef Stefan Institute, Jamova cesta 39, SI-1000 Ljubljana (Slovenia)] [Department for Nanostructured Materials, Jozef Stefan Institute, Jamova cesta 39, SI-1000 Ljubljana (Slovenia); Gajovic, A. [Molecular Physics Laboratory, Division of Materials Physics, Ruder Boskovic Institute, Bijenicka 54, HR-1002 Zagreb (Croatia)] [Molecular Physics Laboratory, Division of Materials Physics, Ruder Boskovic Institute, Bijenicka 54, HR-1002 Zagreb (Croatia); Ceh, M., E-mail: miran.ceh@ijs.si [Department for Nanostructured Materials, Jozef Stefan Institute, Jamova cesta 39, SI-1000 Ljubljana (Slovenia)

    2011-03-15T23:59:59.000Z

    Research highlights: {yields} Polycrystalline BaTiO{sub 3} nanorods were synthesized with EPD into AAO templates. {yields} Nanorods are composed of crystalline, nanosized grains with pseudo-cubic structure. {yields} Integrowth of hexagonal BaTiO{sub 3} polymorph within pseudo-cubic structure was observed. -- Abstract: An electron-microscopy investigation was performed on BaTiO{sub 3} nanorods that were processed by sol-gel electrophoretic deposition (EPD) into anodic aluminium oxide (AAO) membranes. The BaTiO{sub 3} nanorods grown within the template membranes had diameters ranging from 150 to 200 nm, with an average length of 10-50 {mu}m. By using various electron-microscopy techniques we showed that the processed BaTiO{sub 3} nanorods were homogeneous in their chemical composition. The BaTiO{sub 3} nanorods were always polycrystalline and were composed of well-crystallized, defect-free, pseudo-cubic BaTiO{sub 3} grains, ranging from 10 to 30 nm. No intergranular phases were observed between the BaTiO{sub 3} grains. A low-temperature hexagonal polymorph that is coherently intergrown with the BaTiO{sub 3} perovskite matrix was also observed as a minor phase. When annealing the AAO templates containing the BaTiO{sub 3} sol in an oxygen atmosphere the presence of the hexagonal polymorph was diminished.

  9. Application Of Ti-Based Self-Formation Barrier Layers To Cu Dual-Damascene Interconnects

    SciTech Connect (OSTI)

    Ito, Kazuhiro; Kohama, Kazuyuki [Department of Materials Science and Engineering, Kyoto University, Kyoto 606-8501 (Japan); Ohmori, Kazuyuki; Mori, Kenichi; Maekawa, Kazuyoshi; Asai, Koyu [Process Technology Div., Renesas Electronics Corporation, Hitachinaka, Ibaraki 312-8504 (Japan); Murakami, Masanori [The Ritsumeikan Trust, Nakagyo-ku, Kyoto 604-8520 (Japan)

    2010-11-24T23:59:59.000Z

    Cu interconnects have been used extensively in ULSI devices. However, large resistance-capacitance delay and poor device reliability have been critical issues as the device feature size has reduced to nanometer scale. In order to achieve low resistance and high reliability of Cu interconnects, we have applied a thin Ti-based self-formed barrier (SFB) using Cu(Ti) alloy seed to 45nm-node dual damascene interconnects and evaluated its performance. The line resistance and via resistance decreased significantly, compared with those of conventional Ta/TaN barriers. The stress migration performance was also drastically improved using the SFB process. A performance of time dependent dielectric breakdown revealed superior endurance. These results suggest that the Ti-based SFB process is one of the most promising candidates for advanced Cu interconnects. TEM and X-ray photoelectron spectroscopy observations for characterization of the Ti-based SFB structure were also performed. The Ti-based SFB consisted of mainly amorphous Ti oxides. Amorphous or crystalline Ti compounds such as TiC, TiN, and TiSi formed beneath Cu alloy films, and the formation varied with dielectric.

  10. Shape and strain-induced magnetization reorientation and magnetic anisotropy in thin film Ti/CoCrPt/Ti lines and rings

    E-Print Network [OSTI]

    Velazquez, D.

    The contributions to the magnetic anisotropy of thin-film rings and lines of width 50 nm and above made from Ti(5?nm)/Co[subscript 0.66]Cr[subscript 0.22]Pt[subscript 0.12] (10 and 20 nm)/Ti (3 nm) with a perpendicular ...

  11. low Si p+-n junctions fabricated by focused ion beam Ga+ implantation through thin Ti and TiSi2 layers

    E-Print Network [OSTI]

    Steckl, Andrew J.

    metals and silicide layers, in conjunction with rapid thermal annealing (RTA) to complete metal silicides and it forms uniform thin films on Si. Most of the current research involving salicide+ implantation through Ti metal (ITM) and TiSi, (ITS) layers, followed by rapid thermal annealing (RTA), has been

  12. The effect of TiCl4-treated TiO2 compact layer on the performance of dye-sensitized solar cell

    E-Print Network [OSTI]

    Park, Byungwoo

    The effect of TiCl4-treated TiO2 compact layer on the performance of dye-sensitized solar cell by a factor of five compared with the bare cell. ? 2011 Elsevier B.V. All rights reserved. 1. Introduction Dye-sensitized: Received 11 October 2011 Accepted 25 October 2011 Available online 4 November 2011 Keywords: Dye-sensitized

  13. Growth and Properties of (001)-oriented Pb(Zr?.??Ti?.??)O?/LaNiO? Films on Si(001) Substrates with TiN Buffer Layers

    E-Print Network [OSTI]

    Zhu, Tie-Jun

    Pulsed laser deposition has been used to grow Pb(Zr?.??Ti?.??)O? (PZT)/LaNiO? (LNO) heterostructures with restricted crystallographic orientations on bare Si(001) and SiO?-coated Si(001) substrates, using TiN buffer layers. ...

  14. Combustion synthesis/quasi-isostatic pressing of TiC0.7NiTi cermets: microstructure and transformation characteristics

    E-Print Network [OSTI]

    Meyers, Marc A.

    and objectives Combustion synthesis, also called self-propagating high- temperature synthesis (SHS), is a method, Borovinskaya, Gordopolov, and others [1­3] at the Institute for High-Temperature Synthesis. The subjectCombustion synthesis/quasi-isostatic pressing of TiC0.7­NiTi cermets: microstructure

  15. Wettability of Ti3SiC2 by Ag-Cu and Ag-Cu-Ti O. Dezellus,a*

    E-Print Network [OSTI]

    Boyer, Edmond

    ternary ceramics Mn+1AXn (where M corresponds to an early transition metal, A is an A-group element, and X of metals and ceramic properties [1]. Among these compounds, titanium silicon carbide (Ti3SiC2) has gained, the ternary carbide Ti3SiC2 has gained much attention due to its unique characteristics combining

  16. Current Status of Ti PM: Progress, Opportunities and Challenges

    SciTech Connect (OSTI)

    Peter, William H [ORNL; Chen, Wei [ORNL; Yamamoto, Yukinori [ORNL; Dehoff, Ryan R [ORNL; Muth, Thomas R [ORNL; Nunn, Stephen D [ORNL; Kiggans, Jim [ORNL; Clark, Michael B [ORNL; Sabau, Adrian S [ORNL; Gorti, Sarma B [ORNL; Blue, Craig A [ORNL; Williams, James C [Ohio State University

    2012-01-01T23:59:59.000Z

    Utilization of titanium components made by powder metallurgy methods has had limited acceptance largely due to the high cost of titanium (Ti) powder. There has been renewed interest in lower cost powder and several Ti reduction methods that produce a particulate product show promise. This talk summarizes work done at Oak Ridge National Laboratory to consolidate these lower cost powders into mill products. Press and sinter consolidation, hot isostatic pressing (HIP) and direct roll consolidation to make sheet have been explored. The characteristics of the consolidated products will be described as a function of the consolidation parameters. Research sponsored by the U.S. Department of Energy, Office of Energy Efficiency and Renewable Energy, Industrial Technologies Program, under contract DE-AC05-00OR22725 with UT-Battelle, LLC.

  17. The massive transformation in Ti-Al alloys: mechanistic observations

    SciTech Connect (OSTI)

    Zhang, X.D.; Godfrey, S.; Weaver, M.; Strangwood, M.; Kaufman, M.J.; Loretto, M.H. [Univ. of Birmingham, Edgbaston (United Kingdom). IRC in Materials for High Performance Applications] [Univ. of Birmingham, Edgbaston (United Kingdom). IRC in Materials for High Performance Applications; Threadgill, P. [Univ. of Birmingham, Edgbaston (United Kingdom). IRC in Materials for High Performance Applications] [Univ. of Birmingham, Edgbaston (United Kingdom). IRC in Materials for High Performance Applications; [TWI, Cambridge (United Kingdom)

    1996-09-01T23:59:59.000Z

    The massive {alpha}{yields}{gamma}{sub m} transformation, as observed using analytical transmission electron microscopy, in Ti-49Al, Ti-48Al-2Nb-2Mn, Ti-55Al-25Ta and Ti-50Al-20Ta alloys is described. Conventional solution heating and quenching experiments have been combined with the more rapid quenching possible using electron beam melting in order to provide further insight into the early stages of the transformation of these alloys. It is shown that the {gamma} develops first at grain boundaries as lamellae in one of the grains and that these lamellae intersect and spread into the adjacent grain in a massive manner. Consequently, there is no orientation relationship between the massive gamma ({gamma}{sub m}) and the grain being consumed whereas there is the expected relation between the {gamma}{sub m} and the first grain which is inherited from the lamellae. It is further shown that the {gamma}{sub m} grows as an f.c.c. phase after initially growing with the L1{sub 0} structure. Furthermore, it is shown that the massive f.c.c. phase then orders to the L1{sub 0} structure producing APDB-like defects which are actually thin 90{degree} domains separating adjacent domains that have the same orientation yet are out of phase. The advancing {gamma}{sub m} interface tends to facet parallel either to one of its four {l_brace}111{r_brace} planes or to the basal plane in the grain being consumed by impinging on existing {gamma} lamellae. Thin microtwins and {alpha}{sub 2} platelets then form in the {gamma}{sub m} presumably due, respectively, to transformation stresses and supersaturation of the {gamma}{sub m} with titanium for alloys containing {approximately}48% Al; indeed, there is a local depletion in aluminium across the {alpha}{sub 2} platelets as determined using fine probe microanalysis.

  18. master's degree NaNotechNology

    E-Print Network [OSTI]

    Twente, Universiteit

    master's degree NaNotechNology When choosing a Master's programme, it is wise to look one step topical, incorporating the latest developments in applied physics, nanotechnology, chemical engineering projects will be carried out at the MESA+ institute for nanotechnology, or the MIRA institute

  19. Significant electrical control of amorphous oxide thin film transistors by an ultrathin Ti surface polarity modifier

    SciTech Connect (OSTI)

    Cho, Byungsu [Division of Materials Science and Engineering, Hanyang University, Seoul 133-791 (Korea, Republic of); Samsung Display Co. Ltd., Tangjeong, Chungcheongnam-Do 336-741 (Korea, Republic of); Choi, Yonghyuk; Shin, Seokyoon [Division of Materials Science and Engineering, Hanyang University, Seoul 133-791 (Korea, Republic of); Jeon, Heeyoung [Department of Nano-scale Semiconductor Engineering, Hanyang University, Seoul 133-791 (Korea, Republic of); Seo, Hyungtak, E-mail: hseo@ajou.ac.kr [Department of Materials Science and Engineering and Energy Systems Research, Ajou University, Suwon 443-739 (Korea, Republic of); Jeon, Hyeongtag, E-mail: hjeon@hanyang.ac.kr [Division of Materials Science and Engineering, Hanyang University, Seoul 133-791 (Korea, Republic of); Department of Nano-scale Semiconductor Engineering, Hanyang University, Seoul 133-791 (Korea, Republic of)

    2014-01-27T23:59:59.000Z

    We demonstrate an enhanced electrical stability through a Ti oxide (TiO{sub x}) layer on the amorphous InGaZnO (a-IGZO) back-channel; this layer acts as a surface polarity modifier. Ultrathin Ti deposited on the a-IGZO existed as a TiO{sub x} thin film, resulting in oxygen cross-binding with a-IGZO surface. The electrical properties of a-IGZO thin film transistors (TFTs) with TiO{sub x} depend on the surface polarity change and electronic band structure evolution. This result indicates that TiO{sub x} on the back-channel serves as not only a passivation layer protecting the channel from ambient molecules or process variables but also a control layer of TFT device parameters.

  20. Tribological behavior of NiTi alloy against 52100 steel and WC at elevated temperatures

    SciTech Connect (OSTI)

    Abedini, M. [School of Metallurgy and Materials Engineering, University of Tehran, Tehran (Iran, Islamic Republic of); Ghasemi, H.M., E-mail: hghasemi@ut.ac.ir [School of Metallurgy and Materials Engineering, University of Tehran, Tehran (Iran, Islamic Republic of); Ahmadabadi, M. Nili [School of Metallurgy and Materials Engineering, University of Tehran, Tehran (Iran, Islamic Republic of)

    2010-07-15T23:59:59.000Z

    The dry tribological behavior of a Ti-50.3 at.% Ni alloy at temperatures of 25 deg. C, 50 deg. C and 200 deg. C was studied. The wear tests were performed on a high temperature pin-on-disk tribometer using 52100 steel and tungsten carbide pins. The worn surfaces of the NiTi alloy were examined by scanning electron microscope. The results showed that in the wear tests involving steel pins, the wear rate of the NiTi decreased as the wear testing temperature was increased. However, for the NiTi/WC contact, a reverse trend was observed. There was also a large decrease in the coefficient of friction for the NiTi/steel contact with increasing wear testing temperature. The formation of compact tribological layers could be the main reason for the reduction of the wear rate and coefficient of friction of the NiTi/steel contact at higher wear testing temperatures.

  1. Thermodynamic and mechanical properties of TiC from ab initio calculation

    SciTech Connect (OSTI)

    Dang, D. Y.; Fan, J. L.; Gong, H. R., E-mail: gonghr@csu.edu.cn [State Key Laboratory of Powder Metallurgy, Central South University, Changsha, Hunan 410083 (China)

    2014-07-21T23:59:59.000Z

    The temperature-dependent thermodynamic and mechanical properties of TiC are systematically investigated by means of a combination of density-functional theory, quasi-harmonic approximation, and thermal electronic excitation. It is found that the quasi-harmonic Debye model should be pertinent to reflect thermodynamic properties of TiC, and the elastic properties of TiC decease almost linearly with the increase of temperature. Calculations also reveal that TiC possesses a pronounced directional pseudogap across the Fermi level, mainly due to the strong hybridization of Ti 3d and C 2p states. Moreover, the strong covalent bonding of TiC would be enhanced (reduced) with the decrease (increase) of temperature, while the change of volume (temperature) should have negligible effect on density of states at the Fermi level. The calculated results agree well with experimental observations in the literature.

  2. Laser trapping of {sup 21}Na atoms

    SciTech Connect (OSTI)

    Lu, Zheng-Tian

    1994-09-01T23:59:59.000Z

    This thesis describes an experiment in which about four thousand radioactive {sup 21}Na (t{sub l/2} = 22 sec) atoms were trapped in a magneto-optical trap with laser beams. Trapped {sup 21}Na atoms can be used as a beta source in a precision measurement of the beta-asymmetry parameter of the decay of {sup 21}Na {yields} {sup 21}Ne + {Beta}{sup +} + v{sub e}, which is a promising way to search for an anomalous right-handed current coupling in charged weak interactions. Although the number o trapped atoms that we have achieved is still about two orders of magnitude lower than what is needed to conduct a measurement of the beta-asymmetry parameter at 1% of precision level, the result of this experiment proved the feasibility of trapping short-lived radioactive atoms. In this experiment, {sup 21}Na atoms were produced by bombarding {sup 24}Mg with protons of 25 MeV at the 88 in. Cyclotron of Lawrence Berkeley Laboratory. A few recently developed techniques of laser manipulation of neutral atoms were applied in this experiment. The {sup 21}Na atoms emerging from a heated oven were first transversely cooled. As a result, the on-axis atomic beam intensity was increased by a factor of 16. The atoms in the beam were then slowed down from thermal speed by applying Zeeman-tuned slowing technique, and subsequently loaded into a magneto-optical trap at the end of the slowing path. The last two chapters of this thesis present two studies on the magneto-optical trap of sodium atoms. In particular, the mechanisms of magneto-optical traps at various laser frequencies and the collisional loss mechanisms of these traps were examined.

  3. Heterojunction band offsets and dipole formation at BaTiO{sub 3}/SrTiO{sub 3} interfaces

    SciTech Connect (OSTI)

    Balaz, Snjezana [Department of Physics and Astronomy, Youngstown State University, One University Plaza, Youngstown, Ohio 44555 (United States)] [Department of Physics and Astronomy, Youngstown State University, One University Plaza, Youngstown, Ohio 44555 (United States); Zeng, Zhaoquan [Department of Electrical and Computer Engineering, The Ohio State University, 205 Dreese Lab, 2015 Neil Ave., Columbus, Ohio 43210 (United States)] [Department of Electrical and Computer Engineering, The Ohio State University, 205 Dreese Lab, 2015 Neil Ave., Columbus, Ohio 43210 (United States); Brillson, Leonard J. [Department of Electrical and Computer Engineering, The Ohio State University, 205 Dreese Lab, 2015 Neil Ave., Columbus, Ohio 43210 (United States) [Department of Electrical and Computer Engineering, The Ohio State University, 205 Dreese Lab, 2015 Neil Ave., Columbus, Ohio 43210 (United States); Department of Physics, The Ohio State University, 191 West Woodruff, Columbus, Ohio 43210 (United States)

    2013-11-14T23:59:59.000Z

    We used a complement of photoemission and cathodoluminescence techniques to measure formation of the BaTiO{sub 3} (BTO) on SrTiO{sub 3} (STO) heterojunction band offset grown monolayer by monolayer by molecular beam epitaxy. X-ray photoemission spectroscopy (XPS) provided core level and valence band edge energies to monitor the valence band offset in-situ as the first few crystalline BTO monolayers formed on the STO substrate. Ultraviolet photoemission spectroscopy (UPS) measured Fermi level positions within the band gap, work functions, and ionization potentials of the growing BTO film. Depth-resolved cathodoluminescence spectroscopy measured energies and densities of interface states at the buried heterojunction. Kraut-based XPS heterojunction band offsets provided evidence for STO/BTO heterojunction linearity, i.e., commutativity and transitivity. In contrast, UPS and XPS revealed a large dipole associated either with local charge transfer or strain-induced polarization within the BTO epilayer.

  4. MEMS Hotplates with TiN as a Heater Material J.F. Creemer1

    E-Print Network [OSTI]

    Technische Universiteit Delft

    MEMS Hotplates with TiN as a Heater Material J.F. Creemer1 , W. van der Vlist2 , C.R. de Boer2 , H investigated as a heater material for hotplates and microreactors. TiN is CMOS compatible, and has a higher melting point (2950 C) than conventional heaters of Pt and poly-Si. For the first time, TiN is tested

  5. Spin and orbital Ti magnetism at LaMnO3/SrTiO3 interfaces

    SciTech Connect (OSTI)

    Garcial-Barriocanal, J [Universidad Complutense, Spain; Cezar, J. C. [European Synchrotron Radiation Facility (ESRF); Bruno, F. Y. [Universidad Complutense, Spain; Thakur, P. [European Synchrotron Radiation Facility (ESRF); Brookes, N. B. [European Synchrotron Radiation Facility (ESRF); Utfeld, C. [University of Bristol, UK; Riviera-Calzada, A. [Universidad Complutense, Spain; Giblin, S. R. [ISIS Facility, Rutherford Appleton Laboratory; Taylor, J. W. [ISIS Facility, Rutherford Appleton Laboratory; Duffy, J. A. [University of Warwick, UK; Dugdale, S. B. [University of Bristol, UK; Nakamura, T. [Japan Synchrotron Radiation Research Institute, SPring-8; Kodama, K. [Japan Synchrotron Radiation Research Institute, SPring-8; Leon, C. [Universidad Complutense, Spain; Okamoto, Satoshi [ORNL; Santamaria, J. [Universidad Complutense, Spain

    2010-01-01T23:59:59.000Z

    In systems with strong electron-lattice coupling, such as manganites, orbital degeneracy is lifted, what causes a null expectation value of the orbital moment. Magnetic structure is thus determined by spin-spin superexchange. In titanates, however, with much smaller Jahn-Teller distortions, orbital degeneracy might allow non-zero values of the orbital magnetic moment. Accordingly, novel forms of ferromagnetic superexchange interaction unique to t2g electrons systems have been theoretically predicted, although their experimental observation has remained elusive. Here we report a new kind of Ti3+ ferromagnetism at LaMnO3/SrTiO3 epitaxial interfaces. It results from charge transfer to the empty conduction band of the titanate and has spin and orbital contributions evidencing the role played by orbital degeneracy. The possibility of tuning magnetic alignment (ferromagnetic or antiferromagnetic) of Ti and Mn moments by structural parameters is demonstrated. This result will provide important clues for the understanding of the effects of orbital degeneracy in superexchange coupling.

  6. Grain boundary migration induced segregation in V-Cr-Ti alloys

    SciTech Connect (OSTI)

    Gelles, D.S. [Pacific Northwest National Lab., Richland, WA (United States); Ohnuki, S.; Takahashi, H. [Univ. of Hokkaido (Japan)

    1996-10-01T23:59:59.000Z

    Analytical electron microscopy results are reported for a series of vanadium alloys irradiated in the HFIR JP23 experiment at 500{degrees}C. Alloys were V-5Cr-5Ti and pure vanadium which are expected to have transmuted to V-15Cr-5Ti and V-10Cr following irradiation. Analytical microscopy confirmed the expected transmutation occurred and showed redistribution of Cr and Ti resulting from grain boundary migration in V-5Cr-5Ti, but in pure V, segregation was reduced and no clear trends as a function of position near a boundary were identified.

  7. Adsorption States and Mobility of TMAA Molecules on Reduced TiO2...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    spectroscopy (XPS) and density functional theory (DFT) studies have probed the bonding configurations and mobility of trimethylacetic acid (TMAA) molecules on TiO2(100)...

  8. Ferroelectric and ferromagnetic properties in BaTiO{sub 3} thin films on Si (100)

    SciTech Connect (OSTI)

    Singamaneni, Srinivasa Rao, E-mail: ssingam@ncsu.edu; Prater, John T. [Materials Science Division, Army Research Office, Research Triangle Park, North Carolina 27709 (United States); Department of Materials Science and Engineering, North Carolina State University, Raleigh, North Carolina 27695 (United States); Punugupati, Sandhyarani; Hunte, Frank; Narayan, Jagdish [Department of Materials Science and Engineering, North Carolina State University, Raleigh, North Carolina 27695 (United States)

    2014-09-07T23:59:59.000Z

    In this paper, we report on the epitaxial integration of room temperature lead-free ferroelectric BaTiO{sub 3} thin (?1050?nm) films on Si (100) substrates by pulsed laser deposition technique through a domain matching epitaxy paradigm. We employed MgO and TiN as buffer layers to create BaTiO{sub 3}/SrRuO{sub 3}/MgO/TiN/Si (100) heterostructures. C-axis oriented and cube-on-cube epitaxial BaTiO{sub 3} is formed on Si (100) as evidenced by the in-plane and out-of-plane x-ray diffraction, and transmission electron microscopy. X-ray photoemission spectroscopic measurements show that Ti is in 4(+) state. Polarization hysteresis measurements together with Raman spectroscopy and temperature-dependent x-ray diffraction confirm the room temperature ferroelectric nature of BaTiO{sub 3}. Furthermore, laser irradiation of BaTiO{sub 3} thin film is found to induce ferromagnetic-like behavior but affects adversely the ferroelectric characteristics. Laser irradiation induced ferromagnetic properties seem to originate from the creation of oxygen vacancies, whereas the pristine BaTiO{sub 3} shows diamagnetic behavior, as expected. This work has opened up the route for the integration of room temperature lead-free ferroelectric functional oxides on a silicon platform.

  9. Ann bay lodyans 14 / Se Bryant Freeman ("Tonton Liben") ki pare ti liv sa a

    E-Print Network [OSTI]

    Freeman, Bryant C.

    2000-01-01T23:59:59.000Z

    chante. A! chwal pati, men krapo pi vif pase I. Li bondi al tache nan gwo ke chwal la. F6 nou te we chwal kouri tout boulin. Li voltije ni rigol ni lantiray. Le li bouke, li fe yon ti rete. 10 Men, tou dousman, krapo fe yon ti "ef-6f." Chwal sezi... chwal, fe yon ti "ef-df" anko. Chwal rele: "Sa pa posib!" Epi li komanse galope vites boulin pou I ka rive pi vit. Nan yon ti moman, li paret nan bouk la. Men kay Melani. Chwal rele: "Cheri! cheri!" Yo tande vwa li. Tout moun vini pou yo ka resevwa...

  10. Structure of epitaxial (Fe,N) codoped rutile TiO2 thin films...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    No evidence of structural disorder associated with a high concentration of oxygen vacancies is observed. Substitution of Fe for Ti could not be confirmed, although secondary...

  11. A novel 3D structure composed of strings of hierarchical TiO{sub 2} spheres formed on TiO{sub 2} nanobelts with high photocatalytic properties

    SciTech Connect (OSTI)

    Jiang, Yongjian [State Key Laboratory of Alternate Electrical Power System with Renewable Energy Sources, School of Renewable Energy, North China Electric Power University, Beijing 102206 (China); Li, Meicheng, E-mail: mcli@ncepu.edu.cn [State Key Laboratory of Alternate Electrical Power System with Renewable Energy Sources, School of Renewable Energy, North China Electric Power University, Beijing 102206 (China); Suzhou Institute, North China Electric Power University, Suzhou 215123 (China); Song, Dandan; Li, Xiaodan; Yu, Yue [State Key Laboratory of Alternate Electrical Power System with Renewable Energy Sources, School of Renewable Energy, North China Electric Power University, Beijing 102206 (China)

    2014-03-15T23:59:59.000Z

    A novel hierarchical titanium dioxide (TiO{sub 2}) composite nanostructure with strings of anatase TiO{sub 2} hierarchical micro-spheres and rutile nanobelts framework (TiO{sub 2} HSN) is successfully synthesized via a one-step hydrothermal method. Particularly, the strings of hierarchical spheres are assembled by very thin TiO{sub 2} nanosheets, which are composed of highly crystallized anatase nanocrystals. Meanwhile, the HSN has a large surface area of 191 m{sup 2}/g, which is about 3 times larger than Degussa P25. More importantly, the photocatalytic activity of HSN and P25 were evaluated by the photocatalytic oxidation decomposition of methyl orange (MO) under UV light illumination, and the TiO{sub 2} HSN shows enhanced photocatalytic activity compared with Degussa P25, as result of its continuous hierarchical structures, special conductive channel and large specific surface area. With these features, the hierarchical TiO{sub 2} may have more potential applications in the fields of dye-sensitized solar cells and lithium ion batteries. -- Graphical abstract: Novel TiO{sub 2} with anatase micro-spheres and rutile nanobelts is synthesized. Enhanced photocatalysis is attributed to hierarchical structures (3D spheres), conductive channel (1D nanobelts) and large specific surface area (2D nanosheet). Highlights: The novel TiO{sub 2} nanostructure (HSN) is fabricated for the first time. HSN is composed of strings of anatase hierarchical spheres and rutile nanobelt. HSN presents a larger S{sub BET} of 191 m{sup 2}/g, 3 times larger than the Degussa P25 (59 m{sup 2}/g). HSN owns three kinds of dimensional TiO{sub 2} (1D, 2D and 3D) simultaneously. HSN exhibits better photocatalytic performance compared with Degussa P25.

  12. 2011 Annual Planning Summary for Defense Nuclear Nonproliferation (NA-20)

    Broader source: Energy.gov [DOE]

    The ongoing and projected Environmental Assessments and Environmental Impact Statements for 2011 and 2012 within Defense Nuclear Nonproliferation (NA-20).

  13. Gua para a Sustentabilidade Ambiental na UDC

    E-Print Network [OSTI]

    Fraguela, Basilio B.

    #12;#12;#12;Guía para a Sustentabilidade Ambiental na UDC #12;Redacción Dolores Árias Vázquez Juan Introdución 23 Indicadores de sustentabilidade 27 O contorno natural e humanizado 35 Caracterización dos Ambientalización curricular 101 Outros servizos da udC relacionados coa sustentabilidade 105 O medio ambiente

  14. Measurement of the 44Ti(alpha,p)47V reaction cross section, of relevance to gamma-ray observation of core collapse supernovae, using reclaimed 44Ti from radioactive waste

    E-Print Network [OSTI]

    Murphy, A; Davinson, T; Dressler, R; Fallis, J; Kankainen, A; Laird, A; Murphy, C; Seiffert, C; Schumann, D; Stowasser, T; Stora, T; Wang, C; Woods, P

    2014-01-01T23:59:59.000Z

    Measurement of the 44Ti(alpha,p)47V reaction cross section, of relevance to gamma-ray observation of core collapse supernovae, using reclaimed 44Ti from radioactive waste

  15. Comparative studies of etching mechanisms of CR-39 in NaOH/H2O and NaOH/ethanol

    E-Print Network [OSTI]

    Yu, K.N.

    Comparative studies of etching mechanisms of CR-39 in NaOH/H2O and NaOH/ethanol K.C.C. Tse, D Avenue, Kowloon Tong, Hong Kong Available online 13 May 2007 Abstract The bulk etch rate for CR-39 in NaOH/ethanol accumulates on the surface of CR-39 detector during etching in NaOH/ethanol, which is absent during etching

  16. Deformation in ramp regions of thrust faults: experiments with rock models

    E-Print Network [OSTI]

    Morse, James Donald

    1978-01-01T23:59:59.000Z

    &a&es of? the L'ona- sauga G& oup (I&liddl e and Upper Camj&rfan) and Lhe Chattanooga Shale (Devonian ar d tfississippian), and transverse tr& bed?ini; in ti e more "cr&mpetrr t" sir ata. 1 he final conf igiuration, accordirg to Rich, is sho:in scheim...

  17. Stable atomic structure of NiTi austenite

    SciTech Connect (OSTI)

    Zarkevich, Nikolai A [Ames Laboratory; Johnson, Duane D [Ames Laboratory

    2014-08-01T23:59:59.000Z

    Nitinol (NiTi), the most widely used shape-memory alloy, exhibits an austenite phase that has yet to be identified. The usually assumed austenitic structure is cubic B2, which has imaginary phonon modes, hence it is unstable. We suggest a stable austenitic structure that on average has B2 symmetry (observed by x-ray and neutron diffraction), but it exhibits finite atomic displacements from the ideal B2 sites. The proposed structure has a phonon spectrum that agrees with that from neutron scattering, has diffraction spectra in agreement with x-ray diffraction, and has an energy relative to the ground state that agrees with calorimetry data.

  18. Nature of Transactions (TI) Code | National Nuclear Security Administration

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarlyEnergyDepartmentNationalRestart of the Review ofElectronic InputNuclearNature of Transactions (TI)

  19. HNF-SD-WM-TI-740, Rev. OC

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFun with Big Sky9, 2010 The meeting was called1999Harvest84047 HNF-SD-WM-TI-740,

  20. Carbon monoxide annealed TiO2 nanotube array electrodes for efficient biosensor applications

    E-Print Network [OSTI]

    Cao, Guozhong

    Carbon monoxide annealed TiO2 nanotube array electrodes for efficient biosensor applications by anodic oxidation of titanium foil followed with O2 and CO annealing were employed as matrices consisted of Ti3+ defects with carbon-doping and exhibited well defined quasi-reversible cyclic voltammetric

  1. Nanoindentation of Nanoscale Ti/Au Multilayer Benjamin Revard and David Bahr

    E-Print Network [OSTI]

    Collins, Gary S.

    the mechanical properties of the substrates. Results Figure 1 contains representative load-depth curves for all unloading segment of the load-depth curve) for the three Ti/Au samples, as well as the hardness values in Figure 1, the load-depth curves for the three Ti/Au samples tested all appear quite similar to each other

  2. High-pressure phases of FeTiO3 from first principles N. C. Wilson

    E-Print Network [OSTI]

    2005; published 19 July 2005 The structural, elastic, and electronic properties of the high-pressure Fe and their interaction with the structural degrees of freedom. Ilmenite, the mineral form of FeTiO3, is commonly found of diamond deposits.2 In addition to ilmenite, two other polymorphs of FeTiO3 are known,3 namely, the lithium

  3. Composition dependent intrinsic defect structures in SrTiO3

    SciTech Connect (OSTI)

    Liu, Bin [ORNL] [ORNL; Cooper, Valentino R [ORNL] [ORNL; Xu, Haixuan [University of Tennessee, Knoxville (UTK)] [University of Tennessee, Knoxville (UTK); Xiao, Haiyan [University of Tennessee, Knoxville (UTK)] [University of Tennessee, Knoxville (UTK); Zhang, Yanwen [ORNL] [ORNL; Weber, William J [ORNL] [ORNL

    2014-01-01T23:59:59.000Z

    Intrinsic point defect complexes in SrTiO3 under different chemical conditions are studied using density functional theory. The Schottky defect complex consisting of nominally charged Sr, Ti and O vacancies is predicted to be the most stable defect structure in stoichiometric SrTiO3, with a relatively low formation energy of 1.64 eV/defect. In addition, the mechanisms of defect complex formation in nonstoichiometric SrTiO3 are investigated. Excess SrO leads to the formation of the oxygen vacancies and a strontium-titanium antisite defect, while a strontium vacancy together with an oxygen vacancy and the titanium-strontium antisite defect are produced in an excess TiO2 environment. Since point defects, such as oxygen vacancies and cation antisite defects, are intimately related to the functionality of SrTiO3, these results provide guidelines for controlling the formation of intrinsic point defects and optimizing the functionality of SrTiO3 by controlling nonstoichiometric chemical compositions of SrO and TiO2 in experiments.

  4. Surface studies of nitrogen implanted TiO2 Matthias Batzill a,*, Erie H. Morales b

    E-Print Network [OSTI]

    Diebold, Ulrike

    .V. All rights reserved. Keywords: Titanium dioxide; Doping; Nitrogen; Surface science 1. IntroductionSurface studies of nitrogen implanted TiO2 Matthias Batzill a,*, Erie H. Morales b , Ulrike Diebold Available online 3 August 2007 Abstract Rutile TiO2(110) single crystals have been doped by nitrogen

  5. Enhanced Energy Conversion Efficiency of the Sr2+-Modified Nanoporous TiO2 Electrode Sensitized

    E-Print Network [OSTI]

    Huang, Yanyi

    efficiency achieved with dye-sensitized solar cells may be attributed to the nanoporous TiO2 electrode.3 photon to current efficiency of a solar cell based on the dye Ru[LL(NCS)2] (L ) 2,2-bipyridine-4 cell based on dye-sensitized nanoporous TiO2 thin film electrode, and power conversion efficiency

  6. Solar Energy Materials & Solar Cells 71 (2002) 261271 Photoelectric behavior of nanocrystalline TiO2

    E-Print Network [OSTI]

    Huang, Yanyi

    . A sandwich-type solar cell fabricated by this dye-sensitized nanocrystalline TiO2 film generated 6:1 mA cm?2; Nanocrystalline TiO2; Dye sensitized solar cell; Terpyridyl ruthenium dyes; Photoelectrochemical solar cells unmatched performance in dye staff studied as solar cell sensitizer before 1997. Only recently, a black dye

  7. Laser processing of nanocrystalline TiO2 films for dye-sensitized solar cells

    E-Print Network [OSTI]

    Arnold, Craig B.

    Laser processing of nanocrystalline TiO2 films for dye-sensitized solar cells H. Kim,a) G. P­20 m thick) layers incorporated in dye-sensitized solar cells. Laser direct-write is a laser techniques to produce porous nc- TiO2 films required for dye-sensitized solar cells. The dye solar cells

  8. Microstructure development in Nb3Sn(Ti) internal tin superconducting wire

    E-Print Network [OSTI]

    Elliott, James

    Microstructure development in Nb3Sn(Ti) internal tin superconducting wire I. Pong S. C. Hopkins have studied the phase formation sequences in a Nb3Sn `internal tin' process superconductor. Heat treatments were performed to convert the starting materials of tin, TiSn, copper and niobium, to bronze

  9. A Low Noise NbTiN-based 850 GHz SIS Receiver for the

    E-Print Network [OSTI]

    the 350 micron atmospheric window. This frequency band lies entirely above the energy gap of niobium (700 that consists of two Nb/AlN/NbTiN tunnel junctions, NbTiN thin-film microstrip tuning elements, and a Nb window was deployed at the CSO. It used a novel 1 µm thick Silicon Nitride membrane which support an all

  10. Analysis of the e-beam evaporation of titanium and Ti-6Al-4V

    SciTech Connect (OSTI)

    Westerberg, K.W.; Merier, T.C.; McClelland, M.A.; Braun, D.G.; Berzins, L.V.; Anklam, T.M.; Storer, J.

    1998-02-11T23:59:59.000Z

    An experimental and finite element analysis was performed for the electron-beam evaporation of Ti and Ti-6Al-4V from a bottom-feed system. The bulk evaporation rate was measured by feed consumption, and the pool elevation was held constant by adjusting the feed rate in a closed-loop control system. The instantaneous titanium and aluminum evaporation rates were determined by laser absorption in the vapor plume. Water temperature rises in cooling water circuits provided heat flows, and post-run cross sections revealed the location of the solidification zone. The MELT finite element code was applied to model the steady-state two-dimensional fluid flow and energy transport in the rod. There was good agreement between model and measured values of the heat flows and solidification boundaries for Ti. Measured bulk evaporation rates were similar for Ti and Ti-6-4 with greater variation observed for the Ti values. The model evaporation rates were higher than the measured values, but a similar linear dependence on e-beam power was observed in all cases. In a Ti-6-4 evaporation experiment with steady process conditions, laser absorption measurements showed much larger fluctuations in the evaporation rate for Al than Ti.

  11. Morphological Dependence of Lithium Insertion in Nanocrystalline TiO2(B) Nanoparticles and Nanosheets

    E-Print Network [OSTI]

    Henkelman, Graeme

    Morphological Dependence of Lithium Insertion in Nanocrystalline TiO2(B) Nanoparticles ABSTRACT: The lithium insertion behavior of nanoparticle (3-D) and nanosheet (2- D) architectures of TiO2(B-axis that reduces Li+ -Li+ interactions between C and A2 sites. The calculated lithiation potentials and degree

  12. Photocatalytic Degradation of VOC's by TOTO's Hydrotect (TiO2 Impregnated) Surfaces

    E-Print Network [OSTI]

    Bergin, Mike

    1 Photocatalytic Degradation of VOC's by TOTO's Hydrotect (TiO2 Impregnated) Surfaces Eva Land. This report describes the photocatalytic degradation of formaldehyde and methanol, two common VOC's, by TiO2 to produce measurable gas phase concentrations. The extended UV illumination of the tiles resulted in a 50

  13. Passivation and anodic oxidation of duplex TiN coating on stainless steel

    SciTech Connect (OSTI)

    Rudenja, S.; Pan, J.; Wallinder, I.O.; Leygraf, C.; Kulu, P.

    1999-11-01T23:59:59.000Z

    The passivation and anodic oxidation of duplex TiN coatings deposited by arc ion plating onto prenitrided AISI 304 stainless steel have been studied by potentiodynamic polarization, electrochemical impedance spectroscopy, and Mott-Schottky measurements in 0.1 M H{sub 2}SO{sub 4} + 0.05 M HCl. The chemical composition of the oxidized surface film atop TiN was analyzed by X-ray photoelectron spectroscopy. Up to 1.2 V/SHE the TiN coating exhibits passive behavior, which is attributed to the formation of a TiO{sub 2}-like film of nanometer thickness which grows linearly with anodic potential at a rate of 2.4 nm/V. Above 1.2 V/SHE enhanced anodic oxidation of TiN is observed at a rate of 17.7 nm/V, and the overall corrosion performance is governed both by the oxidized TiN coating and by a metallic Ti interlayer atop the nitrided stainless steel substrate. At all potentials the TiO{sub 2} film is characterized by relatively high donor densities and is, furthermore, terminated by a hydroxylated surface.

  14. Preparation of BaTiO3 nanoparticles by combustion spray pyrolysis Sangjin Leea

    E-Print Network [OSTI]

    Messing, Gary L.

    ], hydrothermal [6], and spray pyrolysis [7­9] have been developed to prepare stoichiometric, ultra- fine BaTiO3 process. Hydrothermal BaTiO3 powders [6] are usually a paraelectric cubic phase, which needs additional freedom from hydrocarbon-based chem- icals, and thus avoiding carbon-contamination problems. As a result

  15. NICKEL-FREE Fe-12Mn-0.2Ti ALLOY STEEL FOR CRYOGENIC APPLICATIONS

    E-Print Network [OSTI]

    Hwang, S.

    2010-01-01T23:59:59.000Z

    Parr, J. Gordon, J. Iron and Steel Inst. B, vol. 283,137 (Properties of Fe-12Mn-0.2Ti Steel at -196C Yield Stress (FREE Fe-12Mn-O. 2Ti ALLOY STEEL FOR CRYOGENIC APPLICATIONS

  16. Surface Structure of TiO2011-2 1 T. J. Beck,1

    E-Print Network [OSTI]

    Diebold, Ulrike

    .43.Bc, 68.47.Gh Titanium dioxide is a promising photocatalyst for the remediation of pollutants of metal oxides [9,10]. In bulk TiO2 the titanium atoms are surrounded by octahedra of six oxygen atoms of the model in Fig. 1.) Such undercoordinated Ti(5) atoms are preferred adsorption sites for a variety

  17. Steps on anatase TiO2(101) XUE-QING GONG1

    E-Print Network [OSTI]

    Diebold, Ulrike

    of anatase titanium dioxide (TiO2). This surface is of great interest in its own right. TiO2 is one with the theoretical predictions. Step-edge formation energies as well as the adsorption energies of water scale to be related to defects3,4 . Steps are special adsorption sites for molecules5­7 , and most metals

  18. Europium-Doped TiO2 Hollow Nanoshells: Two-Photon Imaging of Cell Binding

    E-Print Network [OSTI]

    Kummel, Andrew C.

    Europium-Doped TiO2 Hollow Nanoshells: Two-Photon Imaging of Cell Binding Sergio Sandoval,,,§ Jian Laboratory, § Moores Cancer Center, Department of Chemistry & Biochemistry, Department of Nano method to fabricate luminescent monodisperse 200 nm europium-doped hollow TiO2 nanoshell (NS) particles

  19. Biomaterials 24 (2003) 39313939 Corrosion and wear-corrosion behavior of NiTi modified

    E-Print Network [OSTI]

    Crone, Wendy C.

    Biomaterials 24 (2003) 3931­3939 Corrosion and wear-corrosion behavior of NiTi modified by plasma Received 10 November 2002; accepted 8 April 2003 Abstract The understanding of corrosion behavior in NiTi such as corrosion resistance, plasma source ion implantation (PSII) technique was employed with oxygen as incident

  20. Optical excitations of metallic nanoclusters buried in TiO2 for solar photochemistry

    E-Print Network [OSTI]

    to the solar spectrum.3 A natural dielectric to consider is to encapsulate these metal clusters supported on TiOptical excitations of metallic nanoclusters buried in TiO2 for solar photochemistry Fei WangV range, a much better match to the solar spectrum than the 3.8 eV Ag plasmon. AFM measurements indicate

  1. Thermomechanical Characterization of a TiPdNi High Temperature SMA under Tension

    E-Print Network [OSTI]

    Thermomechanical Characterization of a TiPdNi High Temperature SMA under Tension Parikshith K issues, a nominal composition of Ti50Pd40Ni10 HTSMA was used. The alloy was fabricated using a vacuum arc Electrode Discharge Machining (EDM). A high temperature experimental setup was developed on a load frame

  2. Candidato Situao/Financ. Regime Thiago Marques Toledo Aceito com bolsa de fomento TI

    E-Print Network [OSTI]

    Rodriguez, Noemi

    /Rec. Prop. TI Diogo Guimarães Rocha Aceito/Rec. Prop. TP Taissa Abdala Filgueiras de Sousa Aceito TI Michele Marcelo de Medeiros Soares Aceito/Rec. Prop. TP Sergio Luiz Rodrigues da Cunha Aceito/Rec. Prop. TP Antônio Francisco da Silva Junior Aceito/Rec. Prop. TP Carlos Lima Dias Aceito/Rec. Prop. TP Fabio da

  3. Modulation of over 10{sup 14}?cm{sup ?2} electrons in SrTiO{sub 3}/GdTiO{sub 3} heterostructures

    SciTech Connect (OSTI)

    Boucherit, M.; Shoron, O.; Polchinski, C. [Department of Electrical and Computer Engineering, The Ohio State University, Columbus, Ohio 43210 (United States); Jackson, C. A.; Cain, T. A.; Buffon, M. L. C.; Stemmer, S. [Materials Department, University of California, Santa Barbara, California 93106-5050 (United States); Rajan, S. [Department of Electrical and Computer Engineering, The Ohio State University, Columbus, Ohio 43210 (United States); Department of Materials Science and Engineering, The Ohio State University, Columbus, Ohio 43210 (United States)

    2014-05-05T23:59:59.000Z

    We demonstrate charge modulation of over 10{sup 14}?cm{sup ?2} electrons in a two-dimensional electron gas formed in SrTiO{sub 3}/GdTiO{sub 3} inverted heterostructure field-effect transistors. Increased charge modulation was achieved by reducing the effect of interfacial region capacitances through thick SrTiO{sub 3} cap layers. Transport and device characteristics of the heterostructure field-effect transistors were found to match a long channel field effect transistor model. SrTiO{sub 3} impurity doped metalsemiconductor field effect transistors were also demonstrated with excellent pinch-off and current density exceeding prior reports. The work reported here provides a path towards oxide-based electronics with extreme charge modulation exceeding 10{sup 14}?cm{sup ?2}.

  4. 2+/TiO2-Codoped Zeolites: Synthesis, Characterization, and the Role of TiO2 in Electron Transfer Photocatalysis

    E-Print Network [OSTI]

    Turro, Claudia

    consist of zeolite Y-encapsulated Ru(bpy)3 2+ (bpy ) 2,2- bipyridine) sensitizers in close proximity to Ti are necessary to improve cost efficiency, to utilize solar energy, and to avoid the formation of highly toxic

  5. Thermodynamics of spinel LixTiO2 from first principles M. Wagemaker a,*, A. Van Der Ven b

    E-Print Network [OSTI]

    Ceder, Gerbrand

    phases differ in the sites occupied by Li: in Li1/2TiO2 and LiTiO2 Li occupies the crystallographic 8a to composi- tion LiTiO2 [2]. Other titanium oxide compounds stud- ied in relation to Li intercalation include sites in LiTiO2 [6]. The latter structure 0301-0104/$ - see front matter ? 2005 Elsevier B.V. All rights

  6. Site preferences of indium impurity atoms in intermetallics having Al3Ti and Al3Zr crystal structures

    E-Print Network [OSTI]

    Collins, Gary S.

    Site preferences of indium impurity atoms in intermetallics having Al3Ti and Al3Zr crystal-04843 (Metals Program) and Praveen Sinha Fund for Physics Research. L12 DO22 DO23 Cu3Au Al3Ti Al3Zr #12;Outline · Indium was doped in samples of Al3V and Al3Ti (Al3Ti structure) and Al3Zr (Al3Zr structure) by arc

  7. MICMIC--GPU:GPU: Hi hHi h P f C tiP f C tiHighHigh--Performance ComputingPerformance Computing

    E-Print Network [OSTI]

    Mueller, Klaus

    MICMIC--GPU:GPU: Hi hHi h P f C tiP f C tiHighHigh--Performance ComputingPerformance Computing 2011 but wait, there is more to this..... #12;Amdahl's LawAmdahl's Law Governs theoretical speedupp p P Medical Imaging 2011 MIC-GPU 5 Amdahl's LawAmdahl's Law Governs theoretical speedupp p P P P P S )1( 1

  8. TiN/VN composites with core/shell structure for supercapacitors

    SciTech Connect (OSTI)

    Dong, Shanmu; Chen, Xiao [Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, No. 189 Songling Road, Qingdao 266101 (China)] [Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, No. 189 Songling Road, Qingdao 266101 (China); Gu, Lin [WPI Advanced Institute for Materials Research, Tohoku University, Sendai 9808577 (Japan)] [WPI Advanced Institute for Materials Research, Tohoku University, Sendai 9808577 (Japan); Zhou, Xinhong [Qingdao University of Science and Technology, Qingdao 266101 (China)] [Qingdao University of Science and Technology, Qingdao 266101 (China); Wang, Haibo; Liu, Zhihong; Han, Pengxian; Yao, Jianhua; Wang, Li [Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, No. 189 Songling Road, Qingdao 266101 (China)] [Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, No. 189 Songling Road, Qingdao 266101 (China); Cui, Guanglei, E-mail: cuigl@qibebt.ac.cn [Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, No. 189 Songling Road, Qingdao 266101 (China)] [Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, No. 189 Songling Road, Qingdao 266101 (China); Chen, Liquan [Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, No. 189 Songling Road, Qingdao 266101 (China) [Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, No. 189 Songling Road, Qingdao 266101 (China); Institute of Physics, Chinese Academy of Sciences, Beijing 100080 (China)

    2011-06-15T23:59:59.000Z

    Research highlights: {yields} Vanadium and titanium nitride nanocomposite with core-shell structure was prepared. {yields} TiN/VN composites with different V:Ti molar ratios were obtained. {yields} TiN/VN composites can provide promising electronic conductivity and favorable capacity storage. -- Abstract: TiN/VN core-shell composites are prepared by a two-step strategy involving coating of commercial TiN nanoparticles with V{sub 2}O{sub 5}.nH{sub 2}O sols followed by ammonia reduction. The highest specific capacitance of 170 F g{sup -1} is obtained when scanned at 2 mV s{sup -1} and a promising rate capacity performance is maintained at higher voltage sweep rates. These results indicate that these composites with good electronic conductivity can deliver a favorable capacity performance.

  9. The 40Ca(alpha,gamma)44Ti reaction in the energy regime of supernova nucleosynthesis

    E-Print Network [OSTI]

    H. Nassar; M. Paul; I. Ahmad; Y. Ben-Dov; J. Caggiano; S. Ghelberg; S. Goriely; J. P. Greene; M. Hass; A. Heger; A. Heinz; D. J. Henderson; R. V. F. Janssens; C. L. Jiang; Y. Kashiv; B. S. Nara Singh; A. Ofan; R. C. Pardo; T. Pennington; K. E. Rehm; G. Savard; R. Scott; R. Vondrasek

    2006-01-11T23:59:59.000Z

    The 44Ti(t1/2 = 59 y) nuclide, an important signature of supernova nucleosynthesis, has recently been observed as live radioactivity by gamma-ray astronomy from the Cas A remnant. We investigate in the laboratory the major 44Ti production reaction, 40Ca(alpha,gamma)44Ti (E_cm = 0.6-1.2 MeV/u), by direct off- line counting of 44Ti nuclei. The yield, significantly higher than inferred from previous experiments, is analyzed in terms of a statistical model using microscopic nuclear inputs. The associated stellar rate has important astrophysical consequences, increasing the calculated supernova 44Ti yield by a factor ~2 over previous estimates and bringing it closer to Cas A observations.

  10. Abstract--Titanium nitride (TiN) has been investigated as a material for MEMS hotplate heaters operating at high

    E-Print Network [OSTI]

    Technische Universiteit Delft

    TiN Bond pad TiN Figure 1. Schematic cross section of the hotplate. Titanium Nitride for MEMSAbstract--Titanium nitride (TiN) has been investigated as a material for MEMS hotplate heaters boundaries start to diffuse above one- third of the melting point. As a result, residual stresses relax [3

  11. Characterization for strontium titinateFe3O4 and TiNFe3O4 interfaces A. Lussiera)

    E-Print Network [OSTI]

    Idzerda, Yves

    Characterization for strontium titinate?Fe3O4 and TiN?Fe3O4 interfaces A. Lussiera) and Y. U The interface formation between different thicknesses of strontium titanate (SrTiO3) or titanium nitride Ti

  12. Short-range order of low-coverage Ti/Al,,111...: Implications for hydrogen storage in complex metal hydrides

    E-Print Network [OSTI]

    Ciobanu, Cristian

    Short-range order of low-coverage Ti/Al,,111...: Implications for hydrogen storage in complex metal-coverage Ti atoms on Al 111 as a model surface system for transition metal doped alanate hydrogen storage the dissociative chemisorption of hydrogen in Ti-doped alanate storage materials. © 2007 American Institute

  13. Increasing the Conversion Efficiency of Dye-Sensitized TiO2 Photoelectrochemical Cells by Coupling to Photonic Crystals

    E-Print Network [OSTI]

    The mechanism of enhancing the light harvesting efficiency of dye-sensitized TiO2 solar cells by coupling TiO2Increasing the Conversion Efficiency of Dye-Sensitized TiO2 Photoelectrochemical Cells by Coupling to conventional single-crystal solar cells. In this cell, an optically excited dye injects electrons

  14. DOI: 10.1002/asia.201200349 Dye-Sensitized TiO2 Nanotube Solar Cells: Rational Structural and Surface

    E-Print Network [OSTI]

    Lin, Zhiqun

    DOI: 10.1002/asia.201200349 Dye-Sensitized TiO2 Nanotube Solar Cells: Rational Structural employed to substitute TiO2 nanoparticles for use in dye-sensitized solar cells. To fur- ther improve the performance of dye-sensitized TiO2 nanotube solar cells, efforts have been directed toward the optimization

  15. Absolute orientation-dependent TiN(001) step energies from two-dimensional equilibrium island shape and

    E-Print Network [OSTI]

    Khare, Sanjay V.

    Absolute orientation-dependent TiN(001) step energies from two-dimensional equilibrium island shape and coarsening measurements on epitaxial TiN(001) layers S. Kodambaka *, S.V. Khare, V. Petrova, A. Vailionis 1 microscopy was used to determine the equilibrium shapes of two-dimensional TiN vacancy islands on atomically

  16. Orientation-dependent mobilities from analyses of two-dimensional TiN(111) island decay J. Bareo,1*

    E-Print Network [OSTI]

    Khare, Sanjay V.

    Orientation-dependent mobilities from analyses of two-dimensional TiN(111) island decay kinetics J (T = 1550-1700 K) low-energy electron microscopy measurements of two-dimensional TiN island coarsening/decay kinetics on TiN(111) terraces for which ( ) values are known [Phys. Rev. B 67 (2003) 35409

  17. Epitaxial TiN,,001... Grown and Analyzed In situ by XPS and UPS. II. Analysis of Ar

    E-Print Network [OSTI]

    Gall, Daniel

    Epitaxial TiN,,001... Grown and Analyzed In situ by XPS and UPS. II. Analysis of Ar Sputter Etched and UPS were used to study epitaxial TiN 001 layers grown in situ which were Ar sputter etched. The films Host Material: epitaxial TiN(001) thin film sputter etched Instrument: Physical Electronics, Inc. 5400

  18. Epitaxial TiN,,001... Grown and Analyzed In situ by XPS and UPS. I. Analysis of

    E-Print Network [OSTI]

    Gall, Daniel

    Epitaxial TiN,,001... Grown and Analyzed In situ by XPS and UPS. I. Analysis of As-deposited Layers used to characterize as- deposited epitaxial TiN 001 layers grown in situ. The films were deposited, while the UPS data was generated by He I and He II UV radiation. The spectra show that the TiN 001

  19. Pathways of atomistic processes on TiN,,001... and ,,111... surfaces during film growth: an ab initio study

    E-Print Network [OSTI]

    Gall, Daniel

    Pathways of atomistic processes on TiN,,001... and ,,111... surfaces during film growth: an ab used to calculate binding and diffusion energies of adatoms, molecules, and small clusters on TiN 001 and TiN 111 surfaces in order to isolate the key atomistic processes which determine texture evolution

  20. Absolute orientation-dependent anisotropic TiN,,111... island step energies and stiffnesses from shape fluctuation analyses

    E-Print Network [OSTI]

    Khare, Sanjay V.

    Absolute orientation-dependent anisotropic TiN,,111... island step energies and stiffnesses from fluctuations about the anisotropic equilibrium shape of two-dimensional TiN 111 adatom and vacancy islands on atomically smooth TiN 111 terraces. The equilibrium island shape was found to be a truncated hexagon bounded

  1. Effect of Welding Speed and Defocusing Distance on the Quality of Laser Welded Ti-6Al-4V

    E-Print Network [OSTI]

    Medraj, Mamoun

    Effect of Welding Speed and Defocusing Distance on the Quality of Laser Welded Ti-6Al-4V A:YAG laser, Laser welding, Ti-6Al-4V alloy Abstract In this study, the weldability of 5.1-mm thick Ti-6Al-4V at various welding speeds and defocusing distances. The joint quality was characterized in terms of weld

  2. Hydrothermal Synthesis of Dy-Doped BaTiO3 Powders ERSIN E. OREN and A. CUNEYT TAS

    E-Print Network [OSTI]

    Tas, A. Cuneyt

    . Hydrothermal processing sis method used and temperature, may exhibit four different of BaTiO3 powders has) are "ferroelectric." hydrothermal processing required a pH 12 in the aqueous BaTiO3 is of the tetragonal symmetryHydrothermal Synthesis of Dy-Doped BaTiO3 Powders ERSIN E. OREN and A. CUNEYT TAS Submicron

  3. Synthesis and structure of Al clusters supported on TiO2,,110...: A scanning tunneling microscopy study

    E-Print Network [OSTI]

    Goodman, Wayne

    Synthesis and structure of Al clusters supported on TiO2,,110...: A scanning tunneling microscopy, Texas 77843-3255 Received 14 October 1997; accepted 6 April 1998 Al clusters supported on TiO2(110) have been investigated using scanning tunneling microscopy. Al interacts strongly with the TiO2(110) surface

  4. Corrosion behaviour and biocompatibility evaluation of low modulus Ti16Nb shape memory alloy as potential biomaterial

    E-Print Network [OSTI]

    Zheng, Yufeng

    Corrosion behaviour and biocompatibility evaluation of low modulus Ti­16Nb shape memory alloy and alloys Corrosion and oxidation Cytotoxicity With CP Ti sample as control, the electrochemical measurements were used to investigate the corrosion resistance of low modulus Ti16Nb shape memory alloy in Hank

  5. Revealing the atomic and electronic structure of a SrTiO{sub 3}/LaNiO{sub 3}/SrTiO{sub 3} heterostructure interface

    SciTech Connect (OSTI)

    Zhang, Zaoli, E-mail: zaoli.zhang@oeaw.ac.at [Erich Schmid Institute of Materials Science, Austrian Academy of Sciences, Leoben (Austria); Electron Microscopy Group for Materials Science, University of Ulm, Ulm (Germany); Soltan, S. [Max-Planck Institute for Solid State Research, D-70561 Stuttgart (Germany); Faculty of Science, Helwan University, 11795 Cairo (Egypt); Schmid, H. [INMLeibniz-Institut fr Neue Materialien, 66123 Saarbrcken (Germany); Habermeier, H.-U.; Keimer, B. [Max-Planck Institute for Solid State Research, D-70561 Stuttgart (Germany); Kaiser, U. [Electron Microscopy Group for Materials Science, University of Ulm, Ulm (Germany)

    2014-03-14T23:59:59.000Z

    The atomic structures of SrTiO{sub 3} (STO)/LaNiO{sub 3} (LNO)/STO heterostructure interfaces were investigated by spherical aberration-corrected (C{sub S}) (scanning) transmission electron microscopy. Atomic displacement and lattice distortion measurements and electron energy loss spectroscopy (EELS) were used to quantitatively analyze the distortion of the interfacial octahedra and the bond length at the interfaces. Combined with high-resolution transmission electron microscopy (HRTEM) and scanning transmission electron microscopy analyses, two distinct interfacial atomic terminating layers are unambiguously determined. Ensuing quantitative HRTEM measurements revealed that the Ni-O bond length in the interfacial octahedral is elongated at the bottom interface (NiO{sub 2}-SrO). Atomic displacement shows structural relaxation effects when crossing the interfaces and lattice distortions across the interface is more pronounced in LNO than in STO. The Ti/O atomic ratio, La and Ti relative atomic ratio as derived by EELS quantification indicate non-stoichiometric composition at the interfaces. Distinct fine structures of Ti-L{sub 2,3} edge and O-K edge at the bottom and top interfaces are observed. By comparison, we are able to estimate Ti valency at both interfaces. Combining the structural distortions and Ti valency, the polar discontinuity and charge transfer at the interfaces are discussed.

  6. Active wear and failure mechanisms of TiN-coated high speed steel and TiN-coated cemented carbide tools when machining powder metallurgically made stainless steels

    SciTech Connect (OSTI)

    Jiang, L.; Haenninen, H.; Paro, J.; Kauppinen, V. [Helsinki Univ. of Technology, Espoo (Finland)

    1996-09-01T23:59:59.000Z

    In this study, active wear and failure mechanisms of both TiN-coated high speed steel and TiN-coated cemented carbide tools when machining stainless steels made by powder metallurgy in low and high cutting speed ranges, respectively, have been investigated. Abrasive wear mechanisms, fatigue-induced failure, and adhesive and diffusion wear mechanisms mainly affected the tool life of TiN-coated high speed steel tools at cutting speeds below 35 m/min, between 35 and 45 m/min, and over 45 m/min, respectively. Additionally, fatigue-induced failure was active at cutting speeds over 45 m/min in the low cutting speed range when machining powder metallurgically made duplex stainless steel 2205 and austenitic stainless steel 316L. In the high cutting speed range, from 100 to 250 m/min, fatigue-induced failure together with diffusion wear mechanism, affected the tool life of TiN-coated cemented carbide tools when machining both 316L and 2205 stainless steels. It was noticed that the tool life of TiN-coated high speed steel tools used in the low cutting speed range when machining 2205 steel was longer than that when machining 316L steel, whereas the tool life of TiN-coated cemented carbide tools used in the high cutting speed range when machining 316L steel was longer than that when machining 2205 steel.

  7. Thermodynamics of TiO{sub x} in blast furnace-type slags

    SciTech Connect (OSTI)

    Morizane, Y.; Ozturk, B.; Fruehan, R.J. [Carnegie Mellon Univ., Pittsburgh, PA (United States). Dept. of Materials Science and Engineering

    1999-02-01T23:59:59.000Z

    Equilibrium studies between CaO-SiO{sub 2}-10 pct MgO-Al{sub 2}O{sub 3}-TiO{sub 1.5}-TiO{sub 2} slags, carbon-saturated iron, and a carbon monoxide atmosphere were performed at 1773 K to determine the activities of TiO{sub 1.5} and TiO{sub 2} in the slag. These thermodynamic parameters are required to predict the formation of titanium carbonitride in the blast furnace. In order to calculate the activity of titanium oxide, the activity coefficient of titanium in carbon-saturated iron-carbon-titanium alloys was determined by measuring the solubility of titanium in carbon-saturated iron in equilibrium with titanium carbide. The solubility and the activity coefficient of titanium obtained were 1.3 pct and 0.023 relative to 1 wt pct titanium in liquid iron or 0.0013 relative to pure solid titanium at 1773 K, respectively. Over the concentration range studied, the effect of the TiO{sub x} content on its activity coefficient is small. In the slag system studied containing 35 to 50 pct CaO, 25 to 45 pct SiO{sub 2}, 7 to 22 pct Al{sub 2}O{sub 3}, and 10 pct MgO, the activity coefficients of TiO{sub 1.5} and TiO{sub 2} relative to pure solid standard states range from 2.3 to 8.8 and from 0.1 to 0.3, respectively. Using thermodynamic data obtained, the prediction of the formation of titanium carbonitride was made. Assuming hypothetical TiO{sub 2}, i.e., total titanium in the slag expressed as TiO{sub 2}, and using the values of the activity coefficients of TiO{sub 1.5} and TiO{sub 2} determined, the equilibrium distribution of titanium between blast furnace-type slags and carbon-saturated iron was computed. The value of [pct Ti]/(pct TiO{sub 2}) ranges from 0.1 to 0.2.

  8. Consolidation Process in Near Net Shape Manufacturing of Armstrong CP-Ti/Ti-6Al-4V Powders

    SciTech Connect (OSTI)

    Yamamoto, Yukinori [ORNL; Kiggans, Jim [ORNL; Clark, Michael B [ORNL; Nunn, Stephen D [ORNL; Sabau, Adrian S [ORNL; Peter, William H [ORNL

    2010-01-01T23:59:59.000Z

    This paper summarizes our recent efforts to develop the manufacturing technologies of consolidated net-shape components by using new low-cost commercially pure titanium (CP-Ti) and Ti-6Al-4V alloy powders made by the Armstrong process. Fabrication processes of net shape/ near net shape components, such as uniaxial die-pressing, cold isostatic pressing (CIP), sintering, roll compaction and stamping, have been evaluated. The press-and-sinter processing of the powders were systematically investigated in terms of theoretical density and microstructure as a function of time, pressure, and temperature. Up to 96.4% theoretical density has been achieved with the press-and-sinter technology. Tensile properties of the consolidated samples exhibit good ductility as well as equivalent yield/ultimate tensile strengths to those of fully consolidate materials, even with the presence of a certain amount of porosity. A consolidation model is also under development to interpret the powder deformation during processing. Net shape components made of the Armstrong powder can successfully be fabricated with clearer surface details by using press-and-sinter processing.

  9. Brazing ZrO{sub 2} ceramic to Ti6Al4V alloy using NiCrSiB amorphous filler foil: Interfacial microstructure and joint properties

    SciTech Connect (OSTI)

    Cao, J., E-mail: cao_jian@hit.edu.cn [Shandong Provincial Key Laboratory of Special Welding Technology, Harbin Institute of Technology at Weihai, Weihai 264209 (China); State Key Laboratory of Advanced Welding and Joining, Harbin Institute of Technology, Harbin 150001 (China); Song, X.G., E-mail: song_xiaoguohit@yahoo.com.cn [Shandong Provincial Key Laboratory of Special Welding Technology, Harbin Institute of Technology at Weihai, Weihai 264209 (China); State Key Laboratory of Advanced Welding and Joining, Harbin Institute of Technology, Harbin 150001 (China); Li, C., E-mail: li_chun1989@yahoo.cn [State Key Laboratory of Advanced Welding and Joining, Harbin Institute of Technology, Harbin 150001 (China); Zhao, L.Y., E-mail: Zhao_ly@163.com [State Key Laboratory of Advanced Welding and Joining, Harbin Institute of Technology, Harbin 150001 (China); Feng, J.C., E-mail: feng_jicai@163.com [Shandong Provincial Key Laboratory of Special Welding Technology, Harbin Institute of Technology at Weihai, Weihai 264209 (China); State Key Laboratory of Advanced Welding and Joining, Harbin Institute of Technology, Harbin 150001 (China)

    2013-07-15T23:59:59.000Z

    Reliable brazing of ZrO{sub 2} ceramic and Ti6Al4V alloy was achieved using NiCrSiB amorphous filler foil. The interfacial microstructure of ZrO{sub 2}/Ti6Al4V joints was characterized by scanning electron microscope, energy dispersive spectrometer and micro-focused X-ray diffractometer. The effects of brazing temperature on the interfacial microstructure and joining properties of brazed joints were investigated in detail. Active Ti of Ti6Al4V alloy dissolved into molten filler metal and reacted with ZrO{sub 2} ceramic to form a continuous TiO reaction layer, which played an important role in brazing. Various reaction phases including Ti{sub 2}Ni, Ti{sub 5}Si{sub 3} and ?-Ti were formed in brazed joints. With an increasing of brazing temperature, the TiO layer thickened gradually while the Ti{sub 2}Ni amount reduced. Shear test indicated that brazed joints tend to fracture at the interface between ZrO{sub 2} ceramic and brazing seam or Ti{sub 2}Ni intermetallic layer. The maximum average shear strength reached 284.6 MPa when brazed at 1025 C for 10 min. - Graphical Abstract: Interfacial microstructure of ZrO{sub 2}/TC4 joint brazed using NiCrSiB amorphous filler foil was: ZrO{sub 2}/TiO/Ti{sub 2}Ni + ?-Ti + Ti{sub 5}Si{sub 3}/?-Ti/Widmansttten structure/TC4. - Highlights: Brazing of ZrO{sub 2} ceramic and Ti-6Al-4V alloy was achieved. Interfacial microstructure was TiO/Ti{sub 2}Ni + ? + Ti{sub 5}Si{sub 3}/?/Widmansttten structure. The formation of TiO produced the darkening effect of ZrO{sub 2} ceramic. The highest joining strength of 284.6MPa was obtained.

  10. Developing TiAIN Coatings for Intermediate Temperature-Solid Oxide Fuel Cell Interconnect Applications

    SciTech Connect (OSTI)

    Liu, X. (West Virginia University); Johnson, C.D.; Li, C. (West Virginia University); Xu, J. (West Virginia University); Cross, C.

    2007-02-01T23:59:59.000Z

    TiN-type coatings have potential to be used as SOFC interconnect coatings SOFC because of their low resistance and high temperature stability. In this research, various (Ti,Al)N coatings were deposited on stainless steels by filtered-arc method. ASR and XRD tests were conducted on these coatings, and SEM/EDAX analysis were conducted after ASR and XRD tests. SEM/EDAX analyses show that (Ti,Al)N remains stable at temperature up to 700C. It is also indicated that Al has beneficial effect on the stability of TiN type coatings. At 900C, (Ti-30Al)N is fully oxidized and some of (Ti-50Al)N coating still remains as nitride. The analyses on cross-sectional samples show that these coatings are effective barrier to the Cr migration. In summary, (Ti.Al)N coatings are good candidates for the SOFC interconnect applications at 700C. The future directions of this research are to improve the stability of these coatings by alloy-doping and to develop multi-layer coatings.

  11. Transition metal atoms pathways on rutile TiO{sub 2} (110) surface: Distribution of Ti{sup 3+} states and evidence of enhanced peripheral charge accumulation

    SciTech Connect (OSTI)

    Cai Yongqing; Bai Zhaoqiang; Chintalapati, Sandhya; Feng Yuanping [Department of Physics, National University of Singapore, 2 Science Drive 3, Singapore 117542 (Singapore); Zeng Qingfeng [School of Materials Science and Engineering, Northwestern Polytechnical University, Xi'an 710072 (China)

    2013-04-21T23:59:59.000Z

    Charge transfer between metal nanoparticles and the supported TiO{sub 2} surface is primarily important for catalytic applications as it greatly affects the catalytic activity and the thermal stability of the deposited nanoparticles on the surface. Herein, systematic spin-polarized density functional and HSE06 calculations are performed to evaluate the adsorption, diffusion, and charge state of several transition metal monomers on both stoichiometric and reduced rutile TiO{sub 2} (110) surface. Although the presence of oxygen vacancy (O{sub v}) increases the binding of Au, Pt and Pd on the surface, it weakens the interaction thus enhancing the diffusion for Fe, Co, Ni, Ag, and Cu adatoms on the surface. For pristine reduced surface, only a small portion (around 5%) of the excess electrons occupy the topmost surface, which are mainly delocalized at the second nearest and third nearest fivefold coordinated Ti (Ti{sub 5c}) atoms. Excess electrons populating at the Ti{sub 5c} atoms on the basal plane can be transferred to strongly electronegative adsorbates like Au and Pt thus enabling a moderate adsorption at this site, whereas no stable adsorption is found for other less electronegative transition metal adatoms (Ag, Cu, Fe, Co, Ni, and Pd) on the reduced surface and for all the adatoms on stoichiometric surface. This result clarifies the origin of the experimental observation of the adsorption of O{sub 2} and CO molecules at Ti{sub 5c} sites in connection with charge transfer. In addition, the spatial redistribution of the excess electrons around the O{sub v} upon the adsorption of the monomers is thoroughly examined. Our finding of an accumulation of excess electrons at the Ti{sub 5c} sites around the monomers explains the critical role of the perimeter interface of the deposited nanoparticles in promoting the adsorption and activation of reactants observed in experiments.

  12. Combustion synthesis of metal-matrix composites. Part 1: The Ti-TiC-Al{sub 2}O{sub 3} system

    SciTech Connect (OSTI)

    Kunrath, A.O.; Strohaecker, T.R. [UFRGS, Porto Alegre, Rio Grande do Sul (Brazil). Dept. de Metalurgia] [UFRGS, Porto Alegre, Rio Grande do Sul (Brazil). Dept. de Metalurgia; Moore, J.J. [Colorado School of Mines, Golden, CO (United States). Dept. of Metallurgical and Materials Engineering] [Colorado School of Mines, Golden, CO (United States). Dept. of Metallurgical and Materials Engineering

    1996-01-15T23:59:59.000Z

    Combustion synthesis or Self-propagating High-temperature Synthesis (SHS) is a process that involves a reaction which is sufficiently exothermic to sustain itself, and, as such, provides considerable potential for the development of an affordable (low cost), energetically efficient means of producing advanced materials. In the combustion synthesis process, a mix of the reactant powders, pressed into a pellet, is heated to the ignition temperature, Tig, when the exothermic reaction takes place, transforming reactants into products. The heat generated by the reaction raises the temperature of the products to a maximum recorded combustion temperature, Tc, which, under adiabatic conditions, would be the adiabatic temperature, Tad. However, in most combustion reactions, Tc is less than Tad, since heat losses occur from the reaction front. Materials synthesized with each of these combustion modes are typically associated with high levels of porosity, e.g., 50%, which is manifested as both macroporosity and microporosity. Previous work demonstrated that it was possible to decrease the porosity of a TiC-Al{sub 2}O{sub 3}-Ti composite by incorporating an excess liquid metal into the combustion synthesis reaction system. This reaction utilizes aluminothermic reduction of TiO{sub 2} to generate the exothermic condition, and at the same time, uses the required TiO{sub 2}/Al stoichiometry to provide the excess Ti to generate an excess Ti in a matrix of TiC and Al{sub 2}O{sub 3}, each of which are synthesized, in-situ within the overall reaction system.

  13. Novel Au-TiC Catalysts for CO Oxidation and Desulfurization Processes

    SciTech Connect (OSTI)

    J Rodriguez; P Liu; Y Takahashi; F Vines; L Feria; E Florez; K Nakamura

    2011-12-31T23:59:59.000Z

    Recent articles dealing with the physical and chemical properties of novel Au-TiC catalysts are reviewed. High-resolution photoemission, scanning tunneling microscopy and first-principles periodic density-functional calculations were used to study the deposition of gold on a TiC(0 0 1) surface. Gold grows forming two-dimensional (very low coverage) and three-dimensional (medium and large coverage) islands on the carbide substrate. A positive shift in the binding energy of the C 1s core level is observed after the deposition of Au on TiC(0 0 1). The results of the density-functional calculations corroborate the formation of Au-C bonds. In general, the bond between Au and the TiC(0 0 1) surface exhibits very little ionic character, but there is a substantial polarization of electrons around Au that facilitates bonding of the adatoms with electron-acceptor molecules (CO, O{sub 2}, C{sub 2}H{sub 4}, SO{sub 2}, thiophene, etc.). Experimental measurements indicate that Au/TiC(0 0 1) is a very good catalysts for the oxidation of CO, the destruction of SO{sub 2} and the hydrodesulfurization of thiophene. At temperatures below 200 K, Au/TiC(0 0 1) is able to perform the 2CO + O{sub 2} {yields} 2CO{sub 2} reaction and the full decomposition of SO{sub 2}. Furthermore, in spite of the very poor hydrodesulfurization performance of TiC(0 0 1) or Au(1 1 1), a Au/TiC(0 0 1) surface displays a hydrodesulfurization activity higher than that of conventional Ni/MoS{sub x} catalysts. Metal carbides are excellent supports for enhancing the chemical reactivity of gold. The Au/TiC system is more chemically active than systems generated by depositing Au nanoparticles on oxide surfaces.

  14. Efficient photocatalytic degradation of gaseous formaldehyde by the TiO{sub 2}/tourmaline composites

    SciTech Connect (OSTI)

    Zhang, Gaoke, E-mail: gkzhang@whut.edu.cn; Qin, Xi

    2013-10-15T23:59:59.000Z

    Graphical abstract: - Highlights: The TiO{sub 2}/tourmaline composites were prepared by a solgel method. The composites exhibited excellent photocatalytic activity and good stability. The physicochemical property of tourmaline may be favor for the degradation of HCHO. The mixed-phase of anatase and rutile TiO{sub 2} may be favor for the degradation of HCHO. - Abstract: The TiO{sub 2} supported tourmaline composites were prepared by a solgel method and used as a photocatalyst for the degradation of formaldehyde (HCHO). The composites were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM), N{sub 2} adsorptiondesorption, Fourier transform infrared (FT-IR) spectroscopy and UVvis diffuse reflectance spectroscopy (UVvis DRS). The results indicate that the mixed-phase of anatase and rutile exists in the TiO{sub 2}/tourmaline composites. The specific surface area of the TiO{sub 2}/tourmaline composites is much higher than that of the pure TiO{sub 2}. The TiO{sub 2}/tourmaline composites exhibited excellent photocatalytic activity for the degradation of HCHO, which was 6 times higher than that of the pure TiO{sub 2}. Moreover, the excellent photocatalytic activity of the composites was fully maintained after five photocatalytic cycles, which may be attributed to the physicochemical property of tourmaline and the mixed-phase of anatase and rutile in the TiO{sub 2}/tourmaline composites.

  15. Crnica: "A horta na cidade" (Primavera Ambiental 2013)

    E-Print Network [OSTI]

    Fraguela, Basilio B.

    Crónica: "A horta na cidade" (Primavera Ambiental 2013) O pasado mércores 10 de abril tivo lugar na con ADEGA. A actividade que leva por título "A horta na cidade" consistiu nunha conferencia a cargo de, Isabel Barrio explicounos os pros e contras dos diferentes tipos de hortas urbanas, dende as máis básicas

  16. Fabrication of TiO{sub 2} nanocrystallized glass

    SciTech Connect (OSTI)

    Masai, Hirokazu; Fujiwara, Takumi; Mori, Hiroshi; Komatsu, Takayuki [Department of Applied Physics, Tohoku University, 6-6-05 Aoba, Sendai 980-8579 (Japan); Department of Materials Science and Technology, Nagaoka University of Technology, 1603-1 Kamitomioka, Nagaoka 940-2188 (Japan)

    2007-02-19T23:59:59.000Z

    Nanocrystallization of rutile and anatase was observed in a CaO-B{sub 2}O{sub 3}-Bi{sub 2}O{sub 3}-Al{sub 2}O{sub 3}-TiO{sub 2} crystallized glass. The color of the present crystallized glass was changed by the heat-treatment temperature, and x-ray diffraction (XRD) patterns of the crystallized glass show that the apparent color change is correlated with the formation of titania nanocrystallites. The particle size of crystallites observed in the transmission electron microscope image is comparable to that measured by XRD pattern. In addition, a large change of refractive index between the rutile particles and glass matrix, 0.8 or larger, was obtained. The present titania crystallized glass will be not only a photocatalytic material but also a promising candidate for random lasing devices.

  17. Initial reactions in Ti{endash}Si bilayers: New indications from in situ measurements

    SciTech Connect (OSTI)

    Cocchi, R.; Giubertoni, D.; Ottaviani, G.; Marangon, T.; Mastracchio, G.; Queirolo, G.; Sabbadini, A.

    2001-06-01T23:59:59.000Z

    The interactions occurring in a Ti{endash}Si bilayer have been investigated by in situ resistance measurements and the reaction products have been analyzed by complementary techniques, such as x-ray diffraction, Auger electron spectroscopy, and MeV {sup 4}He{sup +} Rutherford backscattering. The measurements were performed by heating the samples at a constant rate in the 5{endash}425{degree}C/min range. The samples are 60 nm of titanium sputter deposited on 250 nm of a silicon film deposited by chemical vapor technique; the bilayers were placed on 650 nm of SiO{sub 2}, thermally grown on p-type {l_angle}100{r_angle} silicon wafers. Samples were also prepared by reactively depositing 25 nm of TiN on the Ti film. The TiN cap, deposited without breaking the vacuum, protects the metal films from contaminants, namely oxygen, during handling and heat treatments. It has been shown that, at temperatures around 400{degree}C and before any massive Ti{endash}Si interaction, the resistance increases. This effect, attributed in the literature to the silicon diffusion in the metal film, is due to oxygen, generally contained in the annealing ambient, which diffuses in the Ti film. The Ti{endash}Si reaction produces a decrease in the value of resistance; the first decrease, generally attributed to the formation of a C49{endash}TiSi{sub 2} phase, is due to the growth of an amorphous compound having a graded in-depth composition between Ti{sub 5}Si{sub 3} and TiSi. The activation energy for such formation is 2.8{+-}0.1 eV. At higher temperatures C49{endash}TiSi{sub 2} starts to form, more likely between the silicon and the amorphous layer. The formation of silicide induces a segregation of oxygen in the unreacted Ti film, thus slowing down the growth of silicide. {copyright} 2001 American Institute of Physics.

  18. Formation of Ti-B surface alloys by excimer laser mixing

    SciTech Connect (OSTI)

    Jervis, T.R.; Nastasi, M.; Hirvonen, J.P.; Zocco, T.G.

    1990-01-01T23:59:59.000Z

    We have formed a surface Ti-B alloy by excimer laser mixing of a single B layer on a Ti-6Al-4V alloy substrate. Rutherford backscattering spectroscopy indicates a uniform B:Ti ratio of approximately 0.7 in the surface layer. A Boron layer 60 nm thick resulted in an alloy layer approximately 200 nm thick. There is little indication, by either Auger electron spectroscopy or nuclear reaction analysis, of substantial oxygen incorporation in the surface alloy despite the fact that the processing was done in air. Transmission electron microscopy of the surface alloy shows a completely amorphous surface layer underlain by a martensitic structure.

  19. Ann bay lodyans 7 / se Bryant Freeman ("Tonton Liben") ki pare ti liv sa a

    E-Print Network [OSTI]

    Freeman, Bryant C.

    2000-01-01T23:59:59.000Z

    ("Tonton Liben") ki pare ti liv sa a. AYITI SE PEP AYISYEN PM 7854 .H39 A56 Enstiti Etid Ayisyen - Inivesite Kannzas Bon Nouvel Fondasyon Alfa Lwes 1997 MALIS AP VANN, WA AP PRAN Yon jou yon neg t ap fe yon ti vizit lakay Malis. Pandan li t ap... I ak nan lespri I, ti lanp sa a ap pemet li we sot isit rive nan Ginen, menm anndan yon kay ki femen ak mi." Neg la mande: "Eske ou te seye sa deja?" Malis reponn: "O non, monche! Eske ou kwe m ta ka rete konsa jis pou m ka fe jouda, fouye lavi...

  20. Ann bay lodyans 8 / se Bryant Freeman ("Tonton Liben") ki pare ti liv sa a

    E-Print Network [OSTI]

    Freeman, Bryant C.

    2000-01-01T23:59:59.000Z

    dlo." Eklid Etyen, Teryewouj 1 2 TI GOUT TI GOUT, KONPE CHAT PEDI Yon jou diskisyon mete pye ant konpe Chen ak konpe Chat. Te gen yon moso vyann ate a. Konpe Chen di se li menm ki te we I anvan, men konpe Chat di se li menm ki te we I anvan... mak sonje. Konsa, Chat ale kay yon boko. Li di: "Papa, m vin lakay ou pou touye tout chen ki gen sou late. M ap peye ou mezi ou vie pou sa." Boko a reponn: "A monche, m ap ba ou sa sou de chez. Eske ou ka jwenn yon ti gout pipi chen?" Konpe Chat...

  1. Office of Nuclear Material Integration (ONMI), NA-73

    National Nuclear Security Administration (NNSA)

    U.S. as well as Imports and Exports Jointly funded by the NRC & NNSA - Managed by NA-73 Fuel Cycle Facilities Conversion Enrichment Fuel Fabrication Power Reactors,...

  2. alvo molecular na: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    relacionar as percepes de identidade profissional dos docentes de educao infantil com (more) Leito, Zuleica Maria Tavares de Brito 2013-01-01 122 for the NA48...

  3. Workforce Statistics - NA-30 | National Nuclear Security Administratio...

    National Nuclear Security Administration (NNSA)

    NA-30 | National Nuclear Security Administration Facebook Twitter Youtube Flickr RSS People Mission Managing the Stockpile Preventing Proliferation Powering the Nuclear Navy...

  4. Angular distributions of photoelectrons from free Na clusters

    SciTech Connect (OSTI)

    Wopperer, P.; Dinh, P. M. [Universite de Toulouse, UPS, Laboratoire de Physique Theorique, IRSAMC, F-31062 Toulouse Cedex, France and CNRS, UMR 5152, F-31062 Toulouse Cedex (France); Faber, B.; Reinhard, P.-G. [Institut fuer Theoretische Physik, Universitaet Erlangen, D-91058 Erlangen (Germany); Suraud, E. [Universite de Toulouse, UPS, Laboratoire de Physique Theorique, IRSAMC, F-31062 Toulouse Cedex, France and CNRS, UMR 5152, F-31062 Toulouse Cedex (France); Institut fuer Theoretische Physik, Universitaet Erlangen, D-91058 Erlangen (Germany)

    2010-12-15T23:59:59.000Z

    We explore, from a theoretical perspective, photoelectron angular distributions (PADs) of the Na clusters Na{sub 8}, Na{sub 10}, Na{sub 12}, Na{sub 18}, Na{sub 3}{sup +}, Na{sub 11}{sup +}, Na{sub 13}{sup +}, and Na{sub 19}{sup +}. The basis of the description is the time-dependent local-density approximation (TDLDA), augmented by a self-interaction correction (SIC) to describe ionization properties correctly. The scheme is solved on a numerical grid in coordinate space with absorbing bounds. We assume for each cluster system an isotropic ensemble of free clusters and develop for the case of one-photon emission analytical formulas for computing the orientation-averaged PAD on the basis of a few TDLDA-SIC calculations for properly chosen reference orientations. It turns out that all the information in the averaged PAD is contained in one anisotropy parameter. We find that this parameter varies very little with system size, but as a whole is crucially influenced by the detailed ionic structure. We also make comparisons with direct orientation averaging and consider one example reaching outside the perturbative regime.

  5. armazenamento na energia: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Rey Juan Carlos, Universidad 3 Portugal lidera consrcio envolvido na produo de "energia limpa, segura e abundante" Engineering Websites Summary: ) - A produo de...

  6. ambientais envolvidos na: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Elisa Flvia Luiz Cardoso 2014-01-01 4 Portugal lidera consrcio envolvido na produo de "energia limpa, segura e abundante" Engineering Websites Summary: ) - A produo de...

  7. alta energia na: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Leonardo Oliveira Ferreira 2006-01-01 2 Portugal lidera consrcio envolvido na produo de "energia limpa, segura e abundante" Engineering Websites Summary: ) - A produo de...

  8. Pion and kaon freezeout in NA44

    SciTech Connect (OSTI)

    NA44 Collaboration

    1994-12-01T23:59:59.000Z

    The NA44 spectrometer is optimized for the study of single and two-particle particle spectra near mid-rapidity for transverse momenta below {approx} 1 GeV/c. A large fraction of all pairs in the spectrometer`s acceptance are at low relative momenta, resulting in small statistical uncertainties on the extracted size parameters. In addition, the spectrometer`s clean particle identification allows the authors to measure correlation functions for pions, kaons, and protons. This contribution will concentrate on the source size parameters determined from pion and kaon correlation functions. These size parameters will be compared to calculations from the RQMD event generator and also interpreted in the context of a hydrodynamic model. Finally, the measured single particle spectra will be examined from the viewpoint of hydrodynamics.

  9. The investigation of die-pressing and sintering behavior of ITP CP-Ti and Ti-6Al-4V powders

    SciTech Connect (OSTI)

    Chen, Wei [ORNL; Yamamoto, Yukinori [ORNL; Peter, William H [ORNL; Clark, Michael B [ORNL; Nunn, Stephen D [ORNL; Kiggans, Jim [ORNL; Muth, Thomas R [ORNL; Blue, Craig A [ORNL; Williams, James C [Ohio State University; Fuller, Brian [International Titanium Powder; Akhtar, Kamal [International Titanium Powder

    2012-01-01T23:59:59.000Z

    This paper investigated the die-pressing and sintering behavior of the low-cost CP-Ti and Ti-6Al- 4V powders made by the Armstrong Process . The Armstrong powders have an irregular coral like, dendritic morphology, with a dendrite size of approximately 2-5 m. As-received as well as milled powders were uniaxially pressed at designated pressures up to 690 MPa to form disk samples with different aspect ratios. In the studied pressure range, an empirical powder compaction equation was applied to linearize the green density pressure relationship, and powder compaction parameters were obtained. The Armstrong Ti-64 powder exhibited a significantly higher sinterability than the CP-Ti powder. This was explained to be due to the higher diffusivity of V at the sintering temperature. The Ti-64 samples with a green density of 71.0% increased to 99.6% after sintering at 1300oC for 1 hour. An ex-situ technique was used to track the powder morphology change before and after sintering.

  10. Stoichiometry-driven metal-to-insulator transition in NdTiO{sub 3}/SrTiO{sub 3} heterostructures

    SciTech Connect (OSTI)

    Xu, Peng; Phelan, Daniel; Seok Jeong, Jong; Andre Mkhoyan, K.; Jalan, Bharat, E-mail: bjalan@umn.edu [Department of Chemical Engineering and Materials Science, University of Minnesota, Minneapolis, Minnesota 55455 (United States)

    2014-02-24T23:59:59.000Z

    By controlling stoichiometry via a hybrid molecular beam epitaxy approach, we report on the study of thin film growth and the electronic transport properties of phase-pure, epitaxial NdTiO{sub 3}/SrTiO{sub 3} heterostructures grown on (001) (La{sub 0.3}Sr{sub 0.7})(Al{sub 0.65}Ta{sub 0.35})O{sub 3} (LSAT) substrates as a function of cation stoichiometry in NdTiO{sub 3}. Despite the symmetry mismatch between bulk NdTiO{sub 3} and the substrate, NdTiO{sub 3} films grew in an atomic layer-by-layer fashion over a range of cation stoichiometry; however amorphous films resulted in cases of extreme cation non-stoichiometry. Temperature-dependent sheet resistance measurements were consistent with Fermi-liquid metallic behavior over a wide temperature range, but revealed a remarkable crossover from metal-to-insulator (M-I) type behavior at low temperatures for all compositions. A direct correlation between cation stoichiometry, transport behavior, and the temperature of M-I transition is established.

  11. Crnica I Encontro Solar na UDC O pasado mrcores 24 de abril tivo lugar na Praza da Fraga (Campus da

    E-Print Network [OSTI]

    Fraguela, Basilio B.

    /informativos/os-universitarios-da-coruna-comparten-unha-xornada-de- gastronomia-solar-573783 http://www.lavozdegalicia.es/noticia/coruna/2013/04/24/cocina-universitaria-energiaCrónica I Encontro Solar na UDC O pasado mércores 24 de abril tivo lugar na Praza da Fraga (Campus da Zapateira) a primeira edición do Encontro Solar na UDC. Esta era a terceira das actividades

  12. Supporting Information Electric Field Reversal of Na2SO4, (NH4)2SO4, and Na2CO3 relative to CaCl2

    E-Print Network [OSTI]

    water 1 M Na2 CO3 1 M Na2 SO4 1 M (NH4 )2 SO4 2 M CaCl2 2 M NaCl Re (2) (a.u.) Incident Infrared (cm -1.8 M CaCl2, 1.8 M NaCl, 1.1 M Na2CO3, 1.1 M Na2SO4, and 1.1 M (NH4)2SO4 salt solutions. ExperimentalS1 Supporting Information Electric Field Reversal of Na2SO4, (NH4)2SO4, and Na2CO3 relative to CaCl

  13. Low Spring Index NiTi Coil Actuators for Use in Active Compression Garments

    E-Print Network [OSTI]

    Holschuh, Bradley

    This paper describes the modeling, development, and testing of low spring index nickel titanium (NiTi) coil actuators designed for use in wearable compression garments, and presents a prototype tourniquet system using these ...

  14. Characterizations of a CERN NbTi Reference Wire at LBNL

    E-Print Network [OSTI]

    Godeke, A.; Dietderich, D.R.; Higley, H.C.; Liggins, N.L.

    2007-01-01T23:59:59.000Z

    et al. , report number LBNL-62392 Characterizations of aNbTi Reference Wire at LBNL ? A. Godeke D. R. Dietderich,tests and analysis between LBNL, BNL and Fermilab within

  15. Three-Dimensional Imaging of Individual Dopant Atoms inSrTiO3

    E-Print Network [OSTI]

    Hwang, Jinwoo; Zhang, Jack Y; DAlfonso, Adrian J; Allen, Leslie J; Stemmer, Susanne

    2013-01-01T23:59:59.000Z

    for a specific 3D dopant atom configuration. The methodto have more than 2 Gd atoms in a column is still less thanImaging of Individual Dopant Atoms in SrTiO 3 Jinwoo Hwang,

  16. Fabrication of NiTi shape memory alloy from elemental powders by hot isostatic pressing

    E-Print Network [OSTI]

    McNeese, Matthew Doyle

    1997-01-01T23:59:59.000Z

    The research involved in this thesis was conducted to develop a procedure for producing cylindrical specimens of NiTi shape memory alloy for mechanical testing from elemental powders by hot isostatic pressing. Powders were mixed to ratios of 50...

  17. Molecular Hydrogen Formation from Proximal Glycol Pairs on TiO2(110)

    SciTech Connect (OSTI)

    Chen, Long; Li, Zhenjun; Smith, R. Scott; Kay, Bruce D.; Dohnalek, Zdenek

    2014-04-16T23:59:59.000Z

    Understanding hydrogen formation on TiO2 surfaces is of great importance as it could provide fundamental insight into water splitting for hydrogen production using solar energy. In this work, hydrogen formation from glycols having different numbers of methyl end-groups have been studied using temperature pro-grammed desorption on reduced, hydroxylated, and oxidized TiO2(110) surfaces. The results from OD-labeled glycols demon-strate that gas-phase molecular hydrogen originates exclusively from glycol hydroxyl groups. The yield is controlled by a combi-nation of glycol coverage, steric hindrance, TiO2(110) order and the amount of subsurface charge. Combined, these results show that proximal pairs of hydroxyl aligned glycol molecules and subsurface charge are required to maximize the yield of this redox reaction. These findings highlight the importance of geometric and electronic effects in hydrogen formation from adsorbates on TiO2(110).

  18. Damage evolution in Au-implanted Ho2Ti2O7 titanate pyrochlore...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Zhang Y, J Jagielski, IT Bae, X Xiang, L Thome, G Balakrishnan, DM Paul, and WJ Weber.2010."Damage evolution in Au-implanted Ho2Ti2O7 titanate pyrochlore."Nuclear...

  19. Fabrication and characterization of porous NiTi Shape Memory Alloy by elevated pressure sintering

    E-Print Network [OSTI]

    Vandygriff, Eric Layton

    2012-06-07T23:59:59.000Z

    have not been adequately developed. Currently, three methods are commonly used for producing porous NiTi SMAs from elemental powders. These methods include conventional sintering, Self-propagating High-temperature Synthesis (SHS), and sintering...

  20. Thermomechanical Cyclic Response of TiNiPd High-Temperature Shape Memory Alloys

    E-Print Network [OSTI]

    Atli, Kadri

    2012-10-19T23:59:59.000Z

    TiNiPd high-temperature shape memory alloys (HTSMAs) have attracted considerable attention as potential solid-state actuators capable of operating at temperatures up to 500 C, exhibiting excellent corrosion resistance, adequate ductility levels...

  1. Effect of Aging Heat Treatments on Ni52Ti48 Shape Memory Alloy

    E-Print Network [OSTI]

    Akin, Erhan

    2011-10-21T23:59:59.000Z

    Ni-rich NiTi shape memory alloys (SMAs) are capable of attaining a wide range of transformation temperatures depending on the heat treatment conditions and superior thermo-mechanical cycling stability, which are desired for repeated solid...

  2. The development and synthetic applications of Ti- and Pd-catalyzed processes

    E-Print Network [OSTI]

    Hyde, Alan M. (Alan Michael)

    2009-01-01T23:59:59.000Z

    Chapter 1. Ti-Catalyzed Asymmetric Reduction of Aromatic Heterocycles A method for the highly selective asymmetric reduction of quinoxalines and quinazolines was developed. This complements technologies developed by others ...

  3. Process for producing Ti-Cr-Al-O thin film resistors

    DOE Patents [OSTI]

    Jankowski, Alan F. (Livermore, CA); Schmid, Anthony P. (Solana Beach, CA)

    2001-01-01T23:59:59.000Z

    Thin films of Ti-Cr-Al-O are used as a resistor material. The films are rf sputter deposited from ceramic targets using a reactive working gas mixture of Ar and O.sub.2. Resistivity values from 10.sup.4 to 10.sup.10 Ohm-cm have been measured for Ti-Cr-Al-O film <1 .mu.m thick. The film resistivity can be discretely selected through control of the target composition and the deposition parameters. The application of Ti-Cr-Al-O as a thin film resistor has been found to be thermodynamically stable, unlike other metal-oxide films. The Ti-Cr-Al-O film can be used as a vertical or lateral resistor, for example, as a layer beneath a field emission cathode in a flat panel display; or used to control surface emissivity, for example, as a coating on an insulating material such as vertical wall supports in flat panel displays.

  4. Flat panel display using Ti-Cr-Al-O thin film

    DOE Patents [OSTI]

    Jankowski, Alan F. (Livermore, CA); Schmid, Anthony P. (Solan Beach, CA)

    2002-01-01T23:59:59.000Z

    Thin films of Ti--Cr--Al--O are used as a resistor material. The films are rf sputter deposited from ceramic targets using a reactive working gas mixture of Ar and O.sub.2. Resistivity values from 10.sup.4 to 10.sup.10 Ohm-cm have been measured for Ti--Cr--Al--O film <1 .mu.m thick. The film resistivity can be discretely selected through control of the target composition and the deposition parameters. The application of Ti--Cr--Al--O as a thin film resistor has been found to be thermodynamically stable, unlike other metal-oxide films. The Ti--Cr--Al--O film can be used as a vertical or lateral resistor, for example, as a layer beneath a field emission cathode in a flat panel display; or used to control surface emissivity, for example, as a coating on an insulating material such as vertical wall supports in flat panel displays.

  5. Direct Application of TiBor Coatings Projects (4583), 3/12/2012

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Description: Submit by E-mail The scope of this Cooperative Research and Development (CRADA) is to demonstrate the performance of Ti8or coatings on steel tools, specifically...

  6. EPR Study of the Surface Characteristics of Nanostructured TiO2 under UV Irradiation

    E-Print Network [OSTI]

    EPR Study of the Surface Characteristics of Nanostructured TiO2 under UV Irradiation Juan M of EPR spectroscopy. The samples of the H series present the smallest crystallite size and after

  7. Vacancy Assisted Diffusion of Alkoxy Species on Rutile TiO2(110...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    vacancy sites. For reduced rutile TiO2(110)-11, the bridge-bonded oxygen (BBO) vacancies (BBOVs) are the most prevalent surface defects and, as has been shown, they...

  8. Lucas-Kanade Optical Flow Estimation on the TI C66x Digital Signal Processor

    E-Print Network [OSTI]

    Bakos, Jason D.

    technology for lightweight mobile platforms. The C66x DSP is based on TI's Keystone architecture and consists, scratchpad, or a mixture of both. Like other VLIW archi- tectures, the compiler must software pipeline each

  9. UPS STUDY OF THE ADSORPTION OF OXYGEN ON REDUCED SrTi03 SURFACES

    E-Print Network [OSTI]

    Ferrer, S.

    2013-01-01T23:59:59.000Z

    Figure Captions Figure 1. UPS spectra of a reduced SrTi0 3 (Journal of Applied Physics UPS STUDY OF THE ADSORPTION OFof California. LBL 11614 UPS STUDY OF THE ADSORPTION OF

  10. Transformation Induced Fatigue of Ni-Rich NiTi Shape Memory Alloy Actuators

    E-Print Network [OSTI]

    Schick, Justin Ryan

    2011-02-22T23:59:59.000Z

    In this work the transformation induced fatigue of Ni-rich NiTi shape memory alloys (SMAs) was investigated. The aerospace industry is currently considering implementing SMA actuators into new applications. However, before any new applications can...

  11. E-Print Network 3.0 - al si ti Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Gibbs 1976). 12;KROEKER ET AL.: OXYGEN-17 NMR OF GLASSY AND CRYSTALLINE TITANITE 575 CaTiSiO5 glass... ; Lee and Stebbins 2000; Zhao et ... Source: Nur, Amos -...

  12. Porous TiO2 microspheres with tunable properties for photocatalytic air purification Alberto Naldoni a,

    E-Print Network [OSTI]

    Suslick, Kenneth S.

    , continuous operation, facile scale-up process from small to large production, and thorough control overPorous TiO2 microspheres with tunable properties for photocatalytic air purification Alberto

  13. Waterless TiO{sub 2} atomic layer deposition using titanium tetrachloride and titanium tetraisopropoxide

    SciTech Connect (OSTI)

    Anderson, Virginia R.; Cavanagh, Andrew S.; Abdulagatov, Aziz I. [Department of Chemistry and Biochemistry, University of Colorado, Boulder, Colorado 80309-0215 (United States); Gibbs, Zachary M. [Department of Chemical and Biological Engineering, University of Colorado, Boulder, Colorado 80309-0424 (United States); George, Steven M., E-mail: Steven.George@Colorado.Edu [Department of Chemistry and Biochemistry, University of Colorado, Boulder, Colorado 80309-0215 and Department of Mechanical Engineering, University of Colorado, Boulder, Colorado 80309-0427. (United States)

    2014-01-15T23:59:59.000Z

    The surface chemistry for TiO{sub 2} atomic layer deposition (ALD) typically utilizes water or other oxidants that can oxidize underlying substrates such as magnetic disks or semiconductors. To avoid this oxidation, waterless or oxidant-free surface chemistry can be used that involves titanium halides and titanium alkoxides. In this study, waterless TiO{sub 2} ALD was accomplished using titanium tetrachloride (TiCl{sub 4}) and titanium tetraisopropoxide (TTIP). In situ transmission Fourier transform infrared (FTIR) studies were employed to study the surface species and the reactions during waterless TiO{sub 2} ALD. At low temperatures between 125 and 225??C, the FTIR absorbance spectra revealed that the isopropoxide species remained on the surface after TTIP exposures. The TiCl{sub 4} exposures then removed the isopropoxide species and deposited additional titanium species. At high temperatures between 250 and 300??C, the isopropoxide species were converted to hydroxyl species by ?-hydride elimination. The observation of propene gaseous reaction product by quadrupole mass spectrometry (QMS) confirmed the ?-hydride elimination reaction pathway. The TiCl{sub 4} exposures then easily reacted with the hydroxyl species. QMS studies also observed the 2-chloropropane and HCl gaseous reaction products and monitored the self-limiting nature of the TTIP reaction. Additional studies examined the waterless TiO{sub 2} ALD growth at low and high temperature. Quartz crystal microbalance measurements observed growth rates of ?3?ng/cm{sup 2} at a low temperature of 150??C. Much higher growth rates of ?15?ng/cm{sup 2} were measured at a higher temperature of 250??C under similar reaction conditions. X-ray reflectivity analysis measured a growth rate of 0.55 0.05?/cycle at 250??C. X-ray photoelectron depth-profile studies showed that the TiO{sub 2} films contained low Cl concentrations <1 at. %. This waterless TiO{sub 2} ALD process using TiCl{sub 4} and TTIP should be valuable to prevent substrate oxidation during TiO{sub 2} ALD on oxygen-sensitive substrates.

  14. Mixed cation phases in sputter deposited HfO{sub 2}-TiO{sub 2} nanolaminates

    SciTech Connect (OSTI)

    Cisneros-Morales, M. C.; Aita, C. R. [Advanced Coatings Experimental Laboratory, College of Engineering and Applied Science, University of Wisconsin-Milwaukee, P.O. Box 784, Milwaukee, Wisconsin 53201 (United States)

    2008-07-14T23:59:59.000Z

    Nanolaminate HfO{sub 2}-TiO{sub 2} films are grown by reactive sputter deposition on unheated fused SiO{sub 2}, sequentially annealed at 573 to 973 K, and studied by x-ray diffraction. A nanocrystalline structure of orthorhombic (o) HfTiO{sub 4} adjacent to an interface followed by monoclinic (m) Hf{sub 1-x}Ti{sub x}O{sub 2} is identified. m-Hf{sub 1-x}Ti{sub x}O{sub 2}, a metastable phase, is isomorphous with m-HfO{sub 2} and a high pressure phase, m-HfTiO{sub 4}. A Vegard's law analysis shows that the Ti atomic fraction in m-Hf{sub 1-x}Ti{sub x}O{sub 2} is much greater than Ti equilibrium solubility in m-HfO{sub 2}. A space group-subgroup argument proposes that m-Hf{sub 1-x}Ti{sub x}O{sub 2} arises from an o/m-HfTiO{sub 4} second order phase transition to accommodate the larger Hf atom.

  15. Hydrogenated TiO{sub 2} film for enhancing photovoltaic properties of solar cells and self-sensitized effect

    SciTech Connect (OSTI)

    He, Hongcai; Yang, Kui; Wang, Ning, E-mail: ning-wang@uestc.edu.cn; Luo, Feifei; Chen, Haijun [State Key Laboratory of Electronic Thin Films and Integrated Devices and School of Microelectronics and Solid-State Electronics, University of Electronic Science and Technology of China, Chengdu 610054 (China)

    2013-12-07T23:59:59.000Z

    Hydrogenated TiO{sub 2} film was obtained by annealing TiO{sub 2} film at 350?C for 2?h with hydrogen, and TiO{sub 2} films were prepared by screen printing on fluorine-doped tin oxide glass. Structural characterization by X-ray diffraction and electron microscopy did not show obvious difference between hydrogenated TiO{sub 2} film and pristine TiO{sub 2} film. Through optical and electrochemical characterization, the hydrogenated TiO{sub 2} film showed enhanced absorption and narrowed band gap, as well as reduced TiO{sub 2} surface impedance and dark current. As a result, an obviously enhanced photovoltaic effect was observed in the solar cell with hydrogenated TiO{sub 2} as photoanode without adding any dye due to the self-sensitized effect of hydrogenated TiO{sub 2} film, which excited electrons injecting internal conduction band of TiO{sub 2} to generate more photocurrent.

  16. Optical rotation in RbTiOAsO4 (point group mm2) W. Kaminsky*, I

    E-Print Network [OSTI]

    Kaminsky, Werner

    Optical rotation in RbTiOAsO4 (point group mm2) W. Kaminsky*, I , P. A. ThomasII and A. M. Glazer, UK Received March 5, 2001; accepted September 13, 2001 Abstract. Measurement of optical rotation in RbTiOAsO4 (RTA) with the tilter method resulted in an optical rotation of r12 ¼ þ17ð3? /mm

  17. [TiII] and [NiII] emission from the strontium filament of eta Carinae

    E-Print Network [OSTI]

    M. A. Bautista; H. Hartman; T. R. Gull; N. Smith; K. Lodders

    2006-06-12T23:59:59.000Z

    We study the nature of the [TiII] and [NiII] emission from the so-called strontium filament found in the ejecta of eta Carinae. To this purpose we employ multilevel models of the TiII and NiII systems which are used to investigate the physical condition of the filament and the excitation mechanisms of the observed lines. For the TiII ion, for which no atomic data was previously available, we carry out ab initio calculations of radiative transition rates and electron impact excitation rate coefficients. It is found that the observed spectrum is consistent with the lines being excited in a mostly neutral region with an electron density of the order of $10^7$ cm$^{-3}$ and a temperature around 6000 K. In analyzing three observations with different slit orientations recorded between March~2000 and November~2001 we find line ratios that change among various observations, in a way consistent with changes of up to an order of magnitude in the strength of the continuum radiation field. These changes result from different samplings of the extended filament, due to the different slit orientations used for each observation, and yield clues on the spatial extent and optical depth of the filament. The observed emission indicates a large Ti/Ni abundance ratio relative to solar abundances. It is suggested that the observed high Ti/Ni ratio in gas is caused by dust-gas fractionation processes and does not reflect the absolute Ti/Ni ratio in the ejecta of \\etacar. We study the condensation chemistry of Ti, Ni and Fe within the filament and suggest that the observed gas phase overabundance of Ti

  18. Ultrafast Photooxidation of Mn(II)-Terpyridine Complexes Covalently Attached to TiO2 Nanoparticles

    E-Print Network [OSTI]

    -energy conversion by dye-sensitized solar cells,1,2 photocatalysis,3-6 and molecular electronics.7,8 Most previous-cost, high-efficiency solar cell based on Ru-dye sensitization of colloidal TiO2 films.1 Presently, the most studies have been focused on TiO2 nanoparticles sensitized with Ru dyes,9,10 although IET in other

  19. Spectral slicing filters in titanium diffused lithium niobate (ti:linbo3)

    E-Print Network [OSTI]

    Rabelo, Renato Cunha

    2009-05-15T23:59:59.000Z

    SPECTRAL SLICING FILTERS IN TITANIUM DIFFUSED LITHIUM NIOBATE (Ti:LiNbO 3 ) A Dissertation by RENATO CUNHA RABELO Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements... for the degree of DOCTOR OF PHILOSOPHY December 2008 Major Subject: Electrical Engineering SPECTRAL SLICING FILTERS IN TITANIUM DIFFUSED LITHIUM NIOBATE (Ti:LiNbO 3 ) A Dissertation by RENATO CUNHA RABELO Submitted...

  20. Topical Review Voltage Dependence of the Na/K Pump

    E-Print Network [OSTI]

    Gadsby, David

    or ``ion well'' hy- pothesis. There are only two ways that net transport can be voltage dependent. Either of the external Na+ and K+ bind- ing sites within the membrane field. This access channel or ``ion well produced by applying a blocking Key words: Na,K-ATPase -- Membrane potential -- Access channel -- Ion well

  1. Dielectric property of NiTiO{sub 3} doped substituted ortho-chloropolyaniline composites

    SciTech Connect (OSTI)

    Lakshmi, Mohana; Faisal, Muhammad [Department of Physics, PES Institute of Technology, BSC, Bangalore- 560100 (India)] [Department of Physics, PES Institute of Technology, BSC, Bangalore- 560100 (India); Roy, Aashish S. [Department of Materials Science, Gulbarga University, Gulbarga-585106, Karnataka (India)] [Department of Materials Science, Gulbarga University, Gulbarga-585106, Karnataka (India); Khasim, Syed, E-mail: syed.pes@gmail.com [Department of Physics, PES Institute of Technology, BSC, Bangalore- 560100 (India) [Department of Physics, PES Institute of Technology, BSC, Bangalore- 560100 (India); Department of Physics, University of Tabuk-71491 (Saudi Arabia); Sajjan, K. C. [Department of Physics, Veerashaiva College, Bellary - 583 104, Karnataka (India)] [Department of Physics, Veerashaiva College, Bellary - 583 104, Karnataka (India); Revanasiddappa, M. [Department of Chemistry, PES Institute of Technology, BSC, Bangalore - 560100 (India)] [Department of Chemistry, PES Institute of Technology, BSC, Bangalore - 560100 (India)

    2013-11-15T23:59:59.000Z

    Ortho-chloropolyaniline (OCP)-NiTiO{sub 3} composites have been synthesized via in-situ polymerization of ortho-chloroaniline with various weight percentages of NiTiO{sub 3.} Fourier Transform Infrared spectroscopic studies of Ortho-chloropolyaniline and its composites indicated the formation of composites as a result of Vander Waal's interaction between OCP and NiTiO{sub 3} particles. Surface morphology of OCP and OCP-NiTiO{sub 3} composites were studied using Scanning Electron Microscope (SEM). The SEM micrographs indicated a modified morphology after the composite formation. Dielectric properties and electric modulus of OCP and OCP-NiTiO{sub 3} composites have been investigated in the frequency range of 50 Hz 5 MHz. It has been noticed that electrical resistance decreases with increase in weight percentage of NiTiO{sub 3} particles in polymer matrix as well as with applied frequency. The display of semicircular arcs in Cole-Cole plots indicates the formation of series resistor and capacitor in network causing a decrease in the relaxation time and as a result conductivity enhances in these composites. The facile and cost effective synthesis process and excellent dielectric and conductivity response of these materials makes them promising materials for practical applications.

  2. Effect of prior cold work on age hardening of Cu-3Ti-1Cr alloy

    SciTech Connect (OSTI)

    Markandeya, R. [Department of Metallurgical Engineering, College of Engineering, Jawaharlal Nehru Technological University, Kukatpally, Hyderabad-500 072 (India); Nagarjuna, S. [Defence Metallurgical Research Laboratory, Kanchanbagh, Hyderabad-500 058 (India)]. E-mail: snagarjuna1@rediffmail.com; Sarma, D.S. [Department of Metallurgical Engineering, Institute of Technology, Banaras Hindu University, Varanasi-221 005 (India)

    2006-12-15T23:59:59.000Z

    The influence of 50%, 75% and 90% cold work on the age hardening behavior of Cu-3Ti-1Cr alloy has been investigated by hardness and tensile tests, and light optical and transmission electron microscopy. Hardness increased from 118 Hv in the solution-treated condition to 373 Hv after 90% cold work and peak aging. Cold deformation reduced the peak aging time and temperature of the alloy. The yield strength and ultimate tensile strength reached a maximum of 1090 and 1110 MPa, respectively, following 90% deformation and peak aging. The microstructure of the deformed alloy exhibited elongated grains and deformation twins. The maximum strength on peak aging was obtained due to precipitation of the ordered, metastable and coherent {beta}'-Cu{sub 4}Ti phase, in addition to high dislocation density and deformation twins. Over-aging resulted in decreases in hardness and strength due to the formation of incoherent and equilibrium {beta}-Cu{sub 3}Ti phase in the form of a cellular structure. However, the morphology of the discontinuous precipitation changed to a globular form on high deformation. The mechanical properties of Cu-3Ti-1Cr alloy are superior to those of Cu-2.7Ti, Cu-3Ti-1Cd and the commercial Cu-0.5Be-2.5Co alloys in the cold-worked and peak-aged condition.

  3. Analytical Potential Energy Surface for the Na + HF NaF + H reaction: Application of Conventional Transition-State Theory

    E-Print Network [OSTI]

    Analytical Potential Energy Surface for the Na + HF NaF + H reaction: Application of Conventional Transition-State Theory Alessandra F. A. Vilela, Ricardo Gargano a Patricia R.P. Barreto b a Instituto de from calculation of the rate constant using con- ventional Transition State Theory (TST

  4. Otoczenie spoleczne i jego wplyw na wyniki ekonomiczne przedsibiorstwa na przykladzie instytucji nonprofit wiadczcej uslugi lecznicze i rehabilitacyjne.

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    _wyniki_ekonomiczne_przedsi_biorstwa_na_przyk_adzie_instytucji_nonpr ofit_wiadcz_cej_us_ugi_lecznicze_i_rehabilitacyjne_autorstwa_K_Szagdaja_A_Miks a/888478 Recenzja 2: N_wyniki_ekonomiczne_przedsi_biorstwa_na_przyk_adzie_instytucji_nonpr ofit_wiadcz_cej_us_ugi_lecznicze_i_rehabilitacyjne_autorstwa_K_Szagdaja_Recenzj a_2_N_Wenc_a/888477 hal

  5. Scintillation efficiency measurement of Na recoils in NaI(Tl) below the DAMA/LIBRA energy threshold

    E-Print Network [OSTI]

    Xu, Jingke; Calaprice, Frank; Westerdale, Shawn; Froborg, Francis; Suerfu, Burkhant; Alexander, Thomas; Aprahamian, Ani; Back, Henning O; Casarella, Clark; Fang, Xiao; Gupta, Yogesh K; Ianni, Aldo; Lamere, Edward; Lippincott, W Hugh; Liu, Qian; Lyons, Stephanie; Siegl, Kevin; Smith, Mallory; Tan, Wanpeng; Kolk, Bryant Vande

    2015-01-01T23:59:59.000Z

    The dark matter interpretation of the DAMA modulation signal depends on the NaI(Tl) scintillation efficiency of nuclear recoils. Previous measurements for Na recoils have large discrepancies, especially in the DAMA/LIBRA modulation energy region. We report a quenching effect measurement of Na recoils in NaI(Tl) from 3keV$_{\\text{nr}}$ to 52keV$_{\\text{nr}}$, covering the whole DAMA/LIBRA energy region for light WIMP interpretations. By using a low-energy, pulsed neutron beam, a double time-of-flight technique, and pulse-shape discrimination methods, we obtained the most accurate measurement of this kind for NaI(Tl) to date. The results differ significantly from the DAMA reported values at low energies, but fall between the other previous measurements. We present the implications of the new quenching results for the dark matter interpretation of the DAMA modulation signal.

  6. On the 21Na(p,gamma)22Mg thermonuclear rate for 22Na production in novae

    E-Print Network [OSTI]

    Nadya A. Smirnova; Alain Coc

    2000-08-16T23:59:59.000Z

    Classical novae are potential sources of gamma-rays, like the 1.275 MeV gamma emission following 22Na beta decay, that could be detected by appropriate instruments on board of future satellites like INTEGRAL. It has been shown that the production of 22Na by novae is affected by the uncertainty on the 21Na(p,gamma)22Mg rate and in particular by the unknown partial widths of the Ex = 5.714 MeV, J^pi = 2^+, 22Mg level. To reduce these uncertainties, we performed shell model calculations with the OXBASH code, compared the results with available spectroscopic data and calculated the missing partial widths. Finally, we discuss the influence of these results on the 21Na(p,gamma)22Mg reaction rate and 22Na synthesis.

  7. Cr, N-Codoped TiO2 Mesoporous Microspheres for Li-ion Rechargeable Batteries with Enhanced Electrochemical Performance

    SciTech Connect (OSTI)

    Bi, Zhonghe [ORNL] [ORNL; Paranthaman, Mariappan Parans [ORNL] [ORNL; Guo, Bingkun [ORNL] [ORNL; Unocic, Raymond R [ORNL] [ORNL; Meyer III, Harry M [ORNL] [ORNL; Bridges, Craig A [ORNL] [ORNL; Sun, Xiao-Guang [ORNL] [ORNL; Dai, Sheng [ORNL] [ORNL

    2014-01-01T23:59:59.000Z

    Cr,N-codoped TiO2 mesoporous microspheres synthesized using hydrothermal and subsequent nitridation treatment, exhibited higher solubility of nitrogen, and improved electrical conductivity than N-doped TiO2, as anode for Lithium-ion rechargeable batteries, which led to improving charge-discharge capacity at 0.1 C and twice higher rate capability compared to that of nitrogen-doped TiO2 mesoporous microsphere at 10 C

  8. Metallic glass alloys of Zr, Ti, Cu and Ni

    DOE Patents [OSTI]

    Lin, Xianghong (Pasadena, CA); Peker, Atakan (Pasadena, CA); Johnson, William L. (Pasadena, CA)

    1997-01-01T23:59:59.000Z

    At least quaternary alloys form metallic glass upon cooling below the glass transition temperature at a rate less than 10.sup.3 K/s. Such alloys comprise titanium from 19 to 41 atomic percent, an early transition metal (ETM) from 4 to 21 atomic percent and copper plus a late transition metal (LTM) from 49 to 64 atomic percent. The ETM comprises zirconium and/or hafnium. The LTM comprises cobalt and/or nickel. The composition is further constrained such that the product of the copper plus LTM times the atomic proportion of LTM relative to the copper is from 2 to 14. The atomic percentage of ETM is less than 10 when the atomic percentage of titanium is as high as 41, and may be as large as 21 when the atomic percentage of titanium is as low as 24. Furthermore, when the total of copper and LTM are low, the amount of LTM present must be further limited. Another group of glass forming alloys has the formula (ETM.sub.1-x Ti.sub.x).sub.a Cu.sub.b (Ni.sub.1-y Co.sub.y).sub.c wherein x is from 0.1 to 0.3, y.cndot.c is from 0 to 18, a is from 47 to 67, b is from 8 to 42, and c is from 4 to 37. This definition of the alloys has additional constraints on the range of copper content, b.

  9. Advancements in Ti Alloy Powder Production by Close-Coupled Gas Atomization

    SciTech Connect (OSTI)

    Heidloff, Andy; Rieken, Joel; Anderson, Iver; Byrd, David

    2011-04-01T23:59:59.000Z

    As the technology for titanium metal injection molding (Ti-MIM) becomes more readily available, efficient Ti alloy fine powder production methods are required. An update on a novel close-coupled gas atomization system has been given. Unique features of the melting apparatus are shown to have measurable effects on the efficiency and ability to fully melt within the induction skull melting system (ISM). The means to initiate the melt flow were also found to be dependent on melt apparatus. Starting oxygen contents of atomization feedstock are suggested based on oxygen pick up during the atomization and MIM processes and compared to a new ASTM specification. Forming of titanium by metal injection molding (Ti-MIM) has been extensively studied with regards to binders, particle shape, and size distribution and suitable de-binding methods have been discovered. As a result, the visibility of Ti-MIM has steadily increased as reviews of technology, acceptability, and availability have been released. In addition, new ASTM specification ASTM F2885-11 for Ti-MIM for biomedical implants was released in early 2011. As the general acceptance of Ti-MIM as a viable fabrication route increases, demand for economical production of high quality Ti alloy powder for the preparation of Ti-MIM feedstock correspondingly increases. The production of spherical powders from the liquid state has required extensive pre-processing into different shapes thereby increasing costs. This has prompted examination of Ti-MIM with non-spherical particle shape. These particles are produced by the hydride/de-hydride process and are equi-axed but fragmented and angular which is less than ideal. Current prices for MIM quality titanium powder range from $40-$220/kg. While it is ideal for the MIM process to utilize spherical powders within the size range of 0.5-20 {mu}m, titanium's high affinity for oxygen to date has prohibited the use of this powder size range. In order to meet oxygen requirements the top size cut has traditionally been 45 {mu}m, and in some instances a bottom cut at +5 {mu}m is made to remove ultra-fine particles and reduce oxygen content. Predictably, use of irregular shaped or larger particle feedstock powder can reduce part quality as sintering shrinkage and part detail suffer. Thus, widespread production and technological use of Ti-MIM is limited due in large part to Ti alloy feedstock cost and availability, not MIM processing capability. Lower cost feedstock of fine, spherical Ti alloy powder with sufficient purity must be available in order to fully utilize the advantages of the Ti-MIM processing route allowing expansion of the market to small complex Ti parts in many high volume applications.

  10. Influence of a TiO{sub 2} buffer layer on the magnetic properties of anatase Co:TiO{sub 2} thin films

    SciTech Connect (OSTI)

    Gabor, M. S.; Petrisor, T. Jr.; Tiusan, C. [Technical University of Cluj-Napoca, Materials Science Laboratory, Cluj-Napoca (Romania); Institut Jean Lamour, P2M, CNRS - Nancy University, Nancy (France); Hehn, M. [Institut Jean Lamour, P2M, CNRS - Nancy University, Nancy (France); Vasile, B. S. [Faculty of Applied Chemistry and Material Science, Department of Science and Engineering of Oxide Materials and Nanomaterials, University POLITEHNICA Bucharest, Bucharest (Romania); Petrisor, T. [Technical University of Cluj-Napoca, Materials Science Laboratory, Cluj-Napoca (Romania)

    2012-04-15T23:59:59.000Z

    Our study addresses the influence of a TiO{sub 2} buffer layer on the morphological, structural, and magnetic properties of Co:TiO{sub 2} films grown on (001) SrTiO{sub 3} substrates by RF sputtering. We demonstrate that a direct correlation exist between the morphology, the Co heterogeneity, and the magnetic properties measured in the films. Correlated analysis by cross section transmission electron microscopy, energy dispersive x-ray, and x-ray photoemission spectroscopy reveals that the Co is not uniformly distributed in the film but concentrated in the surface clusters. Atomic force microscopy analysis illustrates that the unbuffered films present a large density of surface clusters. These clusters are not metallic Co but Co rich TiO{sub 2} anatase phase and they are accompanied by structural defects in the film: dislocations, small angle grain boundaries. Magnetometry analysis shows that the unbuffered films have a net ferromagnetic behavior, while in the buffered ones the ferromagnetism is quenched. Therefore, we conclude that the magnetism in unbuffered samples is related to the surface clusters and seems to have an extrinsic nature.

  11. 2nd RESPOND project Workshop "Id tifi ti d l f k t b d ti"Identification and analyses of market-based response options

    E-Print Network [OSTI]

    pricing A t ti l d t l Nickel-Hydride, Lithium-Ion, Polymer, Metal-air (Zn, Al, Mg) Compressed air energy-based response options aimed at increasing the contribution of variable energy resources such as Wind, technology) ­ Storage of electricity or heat 4 ­ Storage of electricity or heat ­ New demand technologies

  12. An application of Ti-K X-ray absorption edges and fine structures to the study of substoichiometric titanium carbide TiC1-x

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    remarkable physical proper- ties, cubic rocksalt transition metal carbides present a large domain of substoichiometric titanium carbide TiC1-x V. Moisy-Maurice and C. H. de Novion C.E.A./IRDI/DMECN/DTech, Laboratoire concentration on the bulk physical properties of the carbides has been extensively studied [2] ; but a detailed

  13. Micro- and nano-scale hollow TiO{sub 2} fibers by coaxial electrospinning: Preparation and gas sensing

    SciTech Connect (OSTI)

    Zhang Jin; Choi, Sun-Woo [School of Materials Science and Engineering, Inha University, Incheon 402-751 (Korea, Republic of); Kim, Sang Sub, E-mail: sangsub@inha.ac.kr [School of Materials Science and Engineering, Inha University, Incheon 402-751 (Korea, Republic of)

    2011-11-15T23:59:59.000Z

    We report the preparation of micro- and nano-scale hollow TiO{sub 2} fibers using a coaxial electrospinning technique and their gas sensing properties in terms of CO. The diameter of hollow TiO{sub 2} fibers can be controlled from 200 nm to several micrometers by changing the viscosity of electrospinning solutions. Lower viscosities produce slim hollow nanofibers. In contrast, fat hollow microfibers are obtained in the case of higher viscosities. A simple mathematical expression is presented to predict the change in diameter of hollow TiO{sub 2} fibers as a function of viscosity. The successful control over the diameter of hollow TiO{sub 2} fibers is expected to bring extensive applications. To test a potential use of hollow TiO{sub 2} fibers in chemical gas sensors, their sensing properties to CO are investigated at room temperature. - Graphical abstract: Microstructures of as-prepared and calcined hollow TiO{sub 2} fibers prepared by the electrospinning technique with a coaxial needle. Dynamic response at various CO concentrations for the sensor fabricated with the hollow TiO{sub 2} fibers. Highlights: > Hollow TiO{sub 2} fibers were synthesized using a coaxial electrospinning technique. > Their diameter can be controlled by changing the viscosity of electrospinning solutions. > Lower viscosities produce slim hollow nanofibers. > In contrast, fat hollow microfibers are obtained in the case of higher viscosities. > Successful control over the diameter of hollow TiO{sub 2} fibers will bring extensive applications.

  14. Sulfur Poisoning and Regeneration of NOx Storage-Reduction Cu/K2Ti2O5 Qiang Wang,*,

    E-Print Network [OSTI]

    Guo, John Zhanhu

    , Lamar UniVersity, Beaumont, Texas 77710 A new Cu/K2Ti2O5 catalyst has been developed recently to remove

  15. Atelier " i l ti ri e e l i e e ilie lli i el " e re er t ire e ri

    E-Print Network [OSTI]

    Passot, Thierry

    Atelier " i l ti ri e e l i e e ilie lli i el " e re er t ire e ri A r e i ti e A r e l i e ti l i e et le r l e e l er et re l i " le i ti e" i i t er e i i e r le l r e elle ti te relle t et r r el t li #12; Atelier " i l ti ri e e l i e e ilie lli i el " e re er t ire e ri

  16. E-Print Network 3.0 - azotada na produtividade Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    das melhores prticas da... destacar o crescimento significativo da certificao ISO 9001 ABNT, 1994 na indstria de software e... reside na gerao de estimativas...

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    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    das melhores prticas da... destacar o crescimento significativo da certificao ISO 9001 ABNT, 1994 na indstria de software e... reside na gerao de estimativas...

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    Fax: +41 22 730 80258013 Summary: efeito estufa e aerossis da atmosfera, na radiao solar e nas propriedades da superfcie terrestre... na alterao do equilbrio da...

  19. auto-anticorpos na artrite: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Na monocarboxylate transport (SMCT) protein expression correlates with survival in colon cancer, 2006) We report an extensive characterization of the Na monocarboxy- late...

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    Na monocarboxylate transport (SMCT) protein expression correlates with survival in colon cancer, 2006) We report an extensive characterization of the Na monocarboxy- late...

  1. autonomia na auto-reconquista: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Na monocarboxylate transport (SMCT) protein expression correlates with survival in colon cancer, 2006) We report an extensive characterization of the Na monocarboxy- late...

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    de maior intensidade e freqncia esto na periferia das placas tectnicas. O Brasil se situa numa... posio privilegiada, ou seja, na poro central da Placa...

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    Na ltima dcada, o Projeto Peixes de Bonito junto com vrias... universidades do Brasil e do exterior revelaram numerosos achados. Os mais recentes aconteceram na Expedio...

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    Atualmente, segundo o censo que realizamos em 200910 na comunidade... trabalho na horta que eles chamam de agricultura. Aqui procurei preservar a classificao deles,...

  5. Coherent growth of superconducting TiN thin films by plasma enhanced molecular beam epitaxy

    SciTech Connect (OSTI)

    Krockenberger, Yoshiharu; Karimoto, Shin-ichi; Yamamoto, Hideki; Semba, Kouich [NTT Basic Research Laboratories, NTT Corporation, 3-1 Morinosato-Wakamiya, Atsugi, Kanagawa 243-0198 (Japan)

    2012-10-15T23:59:59.000Z

    We have investigated the formation of titanium nitride (TiN) thin films on (001) MgO substrates by molecular beam epitaxy and radio frequency acitvated nitrogen plasma. Although cubic TiN is stabile over a wide temperature range, superconducting TiN films are exclusively obtained when the substrate temperature exceeds 710 Degree-Sign C. TiN films grown at 720 Degree-Sign C show a high residual resistivity ratio of approximately 11 and the superconducting transition temperature (T{sub c}) is well above 5 K. Superconductivity has been confirmed also by magnetiztion measurements. In addition, we determined the upper critical magnetic field ({mu}{sub 0}H{sub c2}) as well as the corresponding coherence length ({xi}{sub GL}) by transport measurements under high magnetic fields. High-resolution transmission electron microscopy data revealed full in plane coherency to the substrate as well as a low defect density in the film, in agreement with a mean-free path length Script-Small-L Almost-Equal-To 106 nm, which is estimated from the residual resistivity value. The observations of reflection high energy electron diffraction intensity oscillations during the growth, distinct Laue fringes around the main Bragg peaks, and higher order diffraction spots in the reciprocal space map suggest the full controlability of the thickness of high quality superconducting TiN thin films.

  6. First-principles study on negative thermal expansion of PbTiO{sub 3}

    SciTech Connect (OSTI)

    Wang, Fangfang; Chen, Jun; Xing, Xianran, E-mail: xing@ustb.edu.cn [Department of Physical Chemistry, University of Science and Technology Beijing, Beijing 100083 (China)] [Department of Physical Chemistry, University of Science and Technology Beijing, Beijing 100083 (China); Xie, Ying; Fu, Honggang [Key Laboratory of Functional Inorganic Material Chemistry, Ministry of Education of the People's Republic of China, Heilongjiang University, Harbin 150080 (China)] [Key Laboratory of Functional Inorganic Material Chemistry, Ministry of Education of the People's Republic of China, Heilongjiang University, Harbin 150080 (China)

    2013-11-25T23:59:59.000Z

    It is well known that perovskite-type PbTiO{sub 3} behaves negative thermal expansion in a wide temperature range from room temperature to Curie temperature (763?K). The present study reports the first-principles study of the anisotropic thermal expansion of PbTiO{sub 3}, in the framework of the density-functional theory and the density-functional perturbation theory. The curve of temperature dependence of the unit cell volume is presented from 20 to 520?K through the calculation of the minimum of total free energy at each temperature point. The negative thermal expansion of PbTiO{sub 3} is calculated without empirical parameters. Furthermore, the distinctive thermodynamic act of PbTiO{sub 3} from expanding to contracting at tetragonal phase is reproduced. The ab-initio calculations reveal that this unique appearance depends on the phonon vibration. The dynamical contributions of various atoms are also calculated to account for the disparate role of Pb-O and Ti-O bond.

  7. Significant increase of Curie temperature in nano-scale BaTiO{sub 3}

    SciTech Connect (OSTI)

    Li, Yueliang; Liao, Zhenyu; Fang, Fang; Zhu, Jing, E-mail: jzhu@mail.tsinghua.edu.cn [National Center for Electron Microscopy in Beijing, School of Materials Science and Engineering, State Key Laboratory of New Ceramics and Fine Processing, Laboratory of Advanced Materials (MOE), Tsinghua University, Beijing 100084 (China); Wang, Xiaohui; Li, Longtu [State Key Laboratory of New Ceramics and Fine Processing, School of Materials Science and Engineering, Tsinghua University, Beijing 100084 (China)

    2014-11-03T23:59:59.000Z

    The low Curie temperature (T{sub c}?=?130?C) of bulk BaTiO{sub 3} greatly limits its applications. In this work, the phase structures of BaTiO{sub 3} nanoparticles with sizes ranging from 2.5?nm to 10?nm were studied at various temperatures by using aberration-corrected transmission electron microscopy (TEM) equipped with an in-situ heating holder. The results implied that each BaTiO{sub 3} nanoparticle was composed of different phases, and the ferroelectric ones were observed in the shells due to the complicated surface structure. The ferroelectric phases in BaTiO{sub 3} nanoparticles remained at 600?C, suggesting a significant increase of T{sub c}. Based on the in-situ TEM results and the data reported by others, temperature-size phase diagrams for BaTiO{sub 3} particles and ceramics were proposed, showing that the phase transition became diffused and the T{sub c} obviously increased with decreasing size. The present work sheds light on the design and fabrication of advanced devices for high temperature applications.

  8. Deformation and fracture behavior of composite structured Ti-Nb-Al-Co(-Ni) alloys

    SciTech Connect (OSTI)

    Okulov, I. V., E-mail: i.okulov@ifw-dresden.de; Marr, T.; Schultz, L.; Eckert, J. [IFW Dresden, Helmholtzstr. 20, D-01069 Dresden (Germany); Institut fr Werkstoffwissenschaft, Technische Universitt Dresden, D-01062 Dresden (Germany); Khn, U. [IFW Dresden, Helmholtzstr. 20, D-01069 Dresden (Germany); Freudenberger, J. [IFW Dresden, Helmholtzstr. 20, D-01069 Dresden (Germany); Institut fr Werkstoffwissenschaft, Technische Universitt Bergakademie Freiberg, Gustav-Zeuner-Str. 5, D-09599 Freiberg (Germany); Oertel, C.-G.; Skrotzki, W. [Institut fr Strukturphysik, Technische Universitt Dresden, D-01062 Dresden (Germany)

    2014-02-17T23:59:59.000Z

    Tensile ductility of the Ti-based composites, which consist of a ?-Ti phase surrounded by ultrafine structured intermetallics, is tunable through the control of intermetallics. The two Ti-based alloys studied exhibit similar compressive yield strength (about 1000?MPa) and strain (about 35%40%) but show a distinct difference in their tensile plasticity. The alloy Ti{sub 71.8}Nb{sub 14.1}Ni{sub 7.4}Al{sub 6.7} fractures at the yield stress while the alloy Ti{sub 71.8}Nb{sub 14.1}Co{sub 7.4}Al{sub 6.7} exhibits about 4.5% of tensile plastic deformation. To clarify the effect of microstructure on the deformation behavior of these alloys, tensile tests were carried out in the scanning electron microscope. It is shown that the distribution as well as the type of intermetallics affects the tensile ductility of the alloys.

  9. Femtosecond laser-induced periodic surface structure on the Ti-based nanolayered thin films

    SciTech Connect (OSTI)

    Petrovi?, Suzana M.; Gakovi?, B.; Peruko, D. [Institute of Nuclear ScienceVin?a, University of Belgrade, POB 522, 11001 Belgrade (Serbia)] [Institute of Nuclear ScienceVin?a, University of Belgrade, POB 522, 11001 Belgrade (Serbia); Stratakis, E. [Institute of Electronic Structure and Laser, Foundation for Research and TechnologyHellas, P.O. Box 1527, Gr-711 10 Heraklion (Greece) [Institute of Electronic Structure and Laser, Foundation for Research and TechnologyHellas, P.O. Box 1527, Gr-711 10 Heraklion (Greece); Department of Materials Science and Technology, University of Crete, 710 03 Heraklion, Crete (Greece); Bogdanovi?-Radovi?, I. [Ru?er Bokovi? Institute, P.O. Box 180, 10002 Zagreb (Croatia)] [Ru?er Bokovi? Institute, P.O. Box 180, 10002 Zagreb (Croatia); ?ekada, M. [Joef Stefan Institute, Jamova 39, 1000 Ljubljana (Slovenia)] [Joef Stefan Institute, Jamova 39, 1000 Ljubljana (Slovenia); Fotakis, C. [Institute of Electronic Structure and Laser, Foundation for Research and TechnologyHellas, P.O. Box 1527, Gr-711 10 Heraklion (Greece) [Institute of Electronic Structure and Laser, Foundation for Research and TechnologyHellas, P.O. Box 1527, Gr-711 10 Heraklion (Greece); Department of Physics, University of Crete, 714 09 Heraklion, Crete (Greece); Jelenkovi?, B. [Institute of Physics, University of Belgrade, Pregrevica 118, 11080 Belgrade (Serbia)] [Institute of Physics, University of Belgrade, Pregrevica 118, 11080 Belgrade (Serbia)

    2013-12-21T23:59:59.000Z

    Laser-induced periodic surface structures (LIPSSs) and chemical composition changes of Ti-based nanolayered thin films (Al/Ti, Ni/Ti) after femtosecond (fs) laser pulses action were studied. Irradiation is performed using linearly polarized Ti:Sapphire fs laser pulses of 40 fs pulse duration and 800 nm wavelength. The low spatial frequency LIPSS (LSFL), oriented perpendicular to the laser polarization with periods slightly lower than the irradiation wavelength, was typically formed at elevated laser fluences. On the contrary, high spatial frequency LIPSS (HSFL) with uniform period of 155 nm, parallel to the laser light polarization, appeared at low laser fluences, as well as in the wings of the Gaussian laser beam distribution for higher used fluence. LSFL formation was associated with the material ablation process and accompanied by the intense formation of nanoparticles, especially in the Ni/Ti system. The composition changes at the surface of both multilayer systems in the LSFL area indicated the intermixing between layers and the substrate. Concentration and distribution of all constitutive elements in the irradiated area with formed HSFLs were almost unchanged.

  10. Enhanced photoelectrochemical properties of TiO{sub 2} by codoping with tungsten and silver

    SciTech Connect (OSTI)

    Khan, Matiullah, E-mail: matiullahustb@gmail.com [Department of Inorganic Nonmetallic Materials, School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083 (China); Department of Physics, Kohat University of Science and Technology (KUST), Kohat 26000 (Pakistan); Jiang, Peng; Cao, Wenbin, E-mail: wbcao@ustb.edu.cn [Department of Inorganic Nonmetallic Materials, School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083 (China); Li, Jing [State Key Laboratory of Advanced Metallurgy, University of Science and Technology Beijing, Beijing 100083 (China)

    2014-04-21T23:59:59.000Z

    The Tungsten (W) and Silver (Ag) codoped TiO{sub 2} samples were successfully synthesized by hydrothermal method without any post calcination. To understand the correlation between electronic structure and photocatalytic properties, the synthesized samples were characterized using X-ray diffraction, BrunauerEmmettTeller specific surface area, transmission electron microscopy, ultra-violetvisible absorption spectra, and X-ray photoelectron spectroscopy (XPS), and the photocatalytic properties were evaluated under visible light irradiations. Codoping could not induce any changes in the phase and all the synthesized samples displayed pure anatase phase with spherical morphology. Visible light absorptions of the codoped samples were dramatically improved compared to the corresponding mono-doped samples. XPS analysis indicated that the dopant atoms successfully entered the TiO{sub 2} network. Results from the visible light photodegradation experiments showed that tungsten-silver codoped TiO{sub 2} possessed strong ability in photo-degrading methylene blue compared to tungsten doped TiO{sub 2} and silver doped TiO{sub 2}, which was attributed to the smaller particle size, higher specific surface area, enhanced visible light absorption, and improved separation of photogenerated carriers.

  11. Surface-polishing process for NaI crystals

    SciTech Connect (OSTI)

    Francis, J.

    1982-09-01T23:59:59.000Z

    Darkening of large arrays of NaI used in high energy physics experiments at SLAC has prompted an investigation of methods for annealing radiation damage. As part of this research, it has been necessary to repolish the flat faces of the NaI crystals. The final polishing parameters are given in this document as well as an indication of some techniques which did not work.

  12. Synthesis, characterization, and ion exchange properties of a sodium nonatitanate, Na4Ti9O20.xH2O

    E-Print Network [OSTI]

    Graziano, Gina Marie

    1998-01-01T23:59:59.000Z

    During the Cold War, the Hanford Weapons Site in Richland, Washington, produced weapons grade plutonium which first needed to be separated from the other products using the PUREX process (plutonium and uranium extraction). As a by product...

  13. Active Oxygen on Au/TiO2 Catalysts DOI: 10.1002/anie.201102062 Active oxygen on a Au/TiO2 catalyst Formation, stability and CO

    E-Print Network [OSTI]

    Pfeifer, Holger

    1 Active Oxygen on Au/TiO2 Catalysts DOI: 10.1002/anie.201102062 Active oxygen on a Au/TiO2 are the activation of molecular oxygen, the active site for this reaction step, and the nature of the catalytically active oxygen species present under working conditions.[3;9-15] Stiehl et al. had shown that molecularly

  14. High-Resolution Soft X-Ray Spectral Analysis in the CK Region of Titanium Carbide (TiC) using the DV-X alpha Molecular Orbital Method

    E-Print Network [OSTI]

    Shimomura, Kenta

    2010-01-01T23:59:59.000Z

    in the CK Region of Titanium Carbide (TiC) using the DV-X?USA Keyword titanium carbide, soft X-ray spectroscopy,C K region of titanium carbide (TiC). The spectral profiles

  15. H+ diffusion and electrochemical stability of Li1+x+yAlxTi2-xSiyP3-yO12 glass in aqueous Li/air battery electrolytes

    SciTech Connect (OSTI)

    Ding, Fei; Xu, Wu; Shao, Yuyan; Chen, Xilin; Wang, Zhiguo; Gao, Fei; Liu, Xingjiang; Zhang, Jiguang

    2012-09-15T23:59:59.000Z

    It is well known that LATP (Li1+x+y AlxTi2?x SiyP3?yO12) glass is a good lithium ion conductor. However, the interaction between LATP glass and H+ ions (including its diffusion and surface adsorption) needs to be well understood before the long-term application of LATP glass in an aqueous electrolyte based Li-air batteries where H+ always present. In this work, we investigate the H+ ion diffusion properties in LATP glass and their surface interactions using both experimental and modeling approaches. Our analysis indicates that the apparent H+ related current observed in the initial cyclic voltammetry scan should be attributed to the adsorption of H+ ions on the LATP glass rather than the bulk diffusion of H+ ions in the glass. Furthermore, the density functional theory calculations indicate that the H+ ion diffusion energy barrier (3.21 eV) is much higher than that of Li+ ion (0.79 eV) and Na+ ion (0.79 eV) in NASICON type LiTi2(PO4)3 material. As a result, the H+ ion conductivity in LATP glass is negligible at room temperature. However, significant surface corrosion was found after the LATP glass was soaked in strong alkaline electrolyte for extended time. Therefore, appropriate electrolytes have to be developed to prevent the corrosion of LATP glass before its practical application for Li-air batteries using aqueous electrolyte.

  16. Field-effect BaTiO{sub 3}-Si solar cells

    SciTech Connect (OSTI)

    Wang, Wentao; Liu, Fude, E-mail: fordliu@hku.hk; Man Lau, Chor; Wang, Lei; Yang, Guandong; Zheng, Dawei [Department of Mechanical Engineering, The University of Hong Kong, Pokfulam Road, Hong Kong (China); Li, Zhigang [Department of Mechanical and Aerospace Engineering, The Hong Kong University of Science and Technology, Hong Kong (China)

    2014-03-24T23:59:59.000Z

    Conventional solar cells make use of the spatial variation in electronic environment due to junctions for charge separation. We investigated field-effect BaTiO{sub 3}-Si solar cells that utilize the bound surface charges of BaTiO{sub 3} to separate charge carriers in silicon. Rectifying behavior and photovoltaic effect were observed on cells with forward polarization. Theoretical simulation indicated that the induced electric field due to BaTiO{sub 3} polarization could extend into the silicon layer, which is consistent with experimental observations. In addition, adjusting relevant parameters may optimize the electric field distribution. The cells are promising in terms of material selection, device design, and fabrication.

  17. Nanoscale structural heterogeneity in Ni-rich half-Heusler TiNiSn

    SciTech Connect (OSTI)

    Douglas, Jason E., E-mail: jedouglas@mrl.ucsb.edu; Pollock, Tresa M. [Materials Department, University of California, Santa Barbara, California 93106 (United States); Materials Research Laboratory, University of California, Santa Barbara, California 93106 (United States); Chater, Philip A. [Diamond Light Source, Chilton, Oxfordshire OX11 0DE (United Kingdom); Brown, Craig M. [Center for Neutron Research, National Institute of Standards and Technology, Gaithersburg, Maryland 20899 (United States); Department of Chemical Engineering, University of Delaware, Newark, Delaware 19716 (United States); Seshadri, Ram [Materials Department, University of California, Santa Barbara, California 93106 (United States); Materials Research Laboratory, University of California, Santa Barbara, California 93106 (United States); Department of Chemistry and Biochemistry, University of California, Santa Barbara, California 93106 (United States)

    2014-10-28T23:59:59.000Z

    The structural implications of excess Ni in the TiNiSn half-Heusler compound are examined through a combination of synchrotron x-ray and neutron scattering studies, in conjunction with first principles density functional theory calculations on supercells. Despite the phase diagram suggesting that TiNiSn is a line compound with no solid solution, for small x in TiNi{sub 1+x}Sn there is indeed an appearancefrom careful analysis of the scatteringof some solubility, with the excess Ni occupying the interstitial tetrahedral site in the half-Heusler structure. The analysis performed here would point to the excess Ni not being statistically distributed, but rather occurring as coherent nanoclusters. First principles calculations of energetics, carried out using supercells, support a scenario of Ni interstitials clustering, rather than a statistical distribution.

  18. Eutectic bonding of a Ti sputter coated, carbon aerogel wafer to a Ni foil

    SciTech Connect (OSTI)

    Jankowski, A.F.; Hayes, J.P.; Kanna, R.L.

    1994-06-01T23:59:59.000Z

    The formation of high energy density, storage devices is achievable using composite material systems. Alternate layering of carbon aerogel wafers and Ni foils with rnicroporous separators is a prospective composite for capacitor applications. An inherent problem exists to form a physical bond between Ni and the porous carbon wafer. The bonding process must be limited to temperatures less than 1000{degrees}C, at which point the aerogel begins to degrade. The advantage of a low temperature eutectic in the Ni-Ti alloy system solves this problem. Ti, a carbide former, is readily adherent as a sputter deposited thin film onto the carbon wafer. A vacuum bonding process is then used to join the Ni foil and Ti coating through eutectic phase formation. The parameters required for successfld bonding are described along with a structural characterization of the Ni foil-carbon aerogel wafer interface.

  19. Effect of Reactive Sputtering Parameters on TiAlN Nanocoating Structure and Morphology

    SciTech Connect (OSTI)

    Budi, Esmar [Jurusan Fisika FMIPA Universitas Negeri Jakarta Jl. Pemuda No. 10 Rawamangun Jakarta 13220 (Indonesia); Razali, M. Mohd.; Nizam, A. R. Md. [Faculty of Manufacturing Engineering Universiti Teknikal Malaysia Melaka (UTeM) Karung Berkunci No 1752 Pejabat Pos Durian Tunggal 76109 Melaka (Malaysia)

    2010-10-24T23:59:59.000Z

    The effect of substrate bias and nitrogen flow rate on the TiAlN nanocoating structure and morphology has been investigated by using reactive unbalance DC magnetron sputtering. TiAlN nanocoating was deposited on the tungsten carbide insert tool and the structure and morphology were characterized by using XRD and AFM, respectively. The substrate bias was varied between 0 to -221 V and the nitrogen flow rate was varied between 30 to 72 sccm. The results showed that the structure of TiAlN nanocoating consisted of mainly (111) and (200) plane. The structure was significatly influenced by substrate bias in promoting finer crystal size and increased crystal plane spacing while the rms roughness of nanocoating was influenced by substrate bias and nitrogen flow rate.

  20. NbTiN Based SIS Multilayer Structures for SRF Applications

    SciTech Connect (OSTI)

    Valente, Anne-marie; Eremeev, Grigory; Phillips, H.; Reece, Charles; Spradlin, Joshua; Yang, Qiguang; Lukaszew, Rosa

    2013-09-01T23:59:59.000Z

    For the past three decades, bulk niobium has been the material of choice for SRF cavities applications. RF cavity performance is now approaching the theoretical limit for bulk niobium. For further improvement of RF cavity performance for future accelerator projects, Superconductor ? Insulator - Superconductor (SIS) multilayer structures (as recently proposed by Alex Gurevich) present the theoretical prospect to reach RF performance beyond bulk Nb, using thinly layered higher-Tc superconductors with enhanced Hc1. Jefferson Lab (JLab) is pursuing this approach with the development of NbTiN and AlN based multilayer SIS structures. This paper presents the results on the characteristics of NbTiN films and the first RF measurements on NbTiN-based multilayer structure on thick Nb films.

  1. PS-wave moveout inversion for tilted TI media: A physical-modeling study Pawan Dewangan1

    E-Print Network [OSTI]

    PS-wave moveout inversion for tilted TI media: A physical-modeling study Pawan Dewangan1 , Ilya Tsvankin2 , Mike Batzle3 , Kasper van Wijk4 , and Matthew Haney5 ABSTRACT Mode-converted PS-waves can- and PS- waves can be inverted for the parameters of a horizontal TI layer with a tilted symmetry axis

  2. The electrochemical behavior of a Ti50Ni47Fe3 shape memory alloy C. Li, Y.F. Zheng

    E-Print Network [OSTI]

    Zheng, Yufeng

    University, Beijing 100871, PR China Received 31 July 2005; accepted 28 November 2005 Available online 20 film consisting mainly of a layer of TiO2 which is deemed to be important for all biomaterials. 2005 the effect of copper on the localized corrosion resistance of NiTi shape memory alloy [6]. Wen et al. have

  3. Correlation between corrosion performance and surface wettability in ZrTiCuNiBe bulk metallic glasses

    E-Print Network [OSTI]

    Zheng, Yufeng

    Correlation between corrosion performance and surface wettability in ZrTiCuNiBe bulk metallic June 2010 The corrosion properties of two Zr-based bulk metallic glass, Zr41Ti14Cu12Ni10Be23 LM1 and Zr potential, LM1b showed superior corrosion resistance to LM1. Under identical sample preparation and testing

  4. Improved Lithium Ion Behavior Properties of TiO2@Graphitic-like Carbon Core@Shell Nanostructure

    E-Print Network [OSTI]

    Cao, Guozhong

    Improved Lithium Ion Behavior Properties of TiO2@Graphitic-like Carbon Core@Shell Nanostructure Min Intercalation Electrochemistry Capacitance Lithium Ion batteries A B S T R A C T We demonstrate TiO2@graphitic on the electrode surface and enhanced lithium ion intercalation, leading to lower charge transfer resistance

  5. Simply AlF3-treated Li4Ti5O12 composite anode materials for stable...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Simply AlF3-treated Li4Ti5O12 composite anode materials for stable and ultrahigh power lithium-ion batteries. Simply AlF3-treated Li4Ti5O12 composite anode materials for stable and...

  6. Thermodynamics of the Magnetite-Ulvspinel (Fe3O4-Fe2TiO4) Solid...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the Magnetite-Ulvspinel (Fe3O4-Fe2TiO4) Solid Solution. Thermodynamics of the Magnetite-Ulvspinel (Fe3O4-Fe2TiO4) Solid Solution. Abstract: The thermodynamics of mixing and its...

  7. First-principles study of hydrogen storage on Ti-decorated B{sub 2}C sheet

    SciTech Connect (OSTI)

    Guo, Y.H.; Xu, B.; Xia, Y.D.; Yin, J. [Department of Materials Science and Engineering and National Laboratory of Solid State Microstructures, Nanjing University, Nanjing 210093 (China); Liu, Z.G., E-mail: liuzg@nju.edu.cn [Department of Materials Science and Engineering and National Laboratory of Solid State Microstructures, Nanjing University, Nanjing 210093 (China)

    2012-06-15T23:59:59.000Z

    The hydrogen storage capacity of Ti decorated B{sub 2}C sheet has been investigated by first-principles plane-wave calculation. It is revealed that a single Ti atom adsorbed on the B{sub 2}C sheet can strongly bind up to four hydrogen molecules. The adsorption energy is in the range of -0.36--0.82 eV/H{sub 2}, which is suitable for ambient temperature hydrogen storage. Considering the fact that Ti can be loaded on both sides of B{sub 2}C sheet, corresponding gravimetric storage capacity of Ti/B{sub 2}C system was also calculated and it can reach to about 7.0 wt%, exceeding the minimum requirement of 6.0 wt% for applications. - Graphical abstract: We investigated the hydrogen storage capacity of Ti decorated B{sub 2}C sheet. The most favorable adsorption geometries for every number of hydrogen molecules on Ti/B{sub 2}C complex are given in the figure. Highlights: Black-Right-Pointing-Pointer Ti decorated B{sub 2}C sheet serve as hydrogen storage medium. Black-Right-Pointing-Pointer A single Ti atom adsorbed on the B{sub 2}C sheet can strongly bind up to four hydrogen molecules. Black-Right-Pointing-Pointer The adsorption energy is in moderate range of -0.36--0.82 eV/H{sub 2}.

  8. IEEE TRANSACTIONS ON NANOTECHNOLOGY, VOL. 10, NO. 3, MAY 2011 499 TiSi2 Nanocrystal Metal Oxide Semiconductor Field

    E-Print Network [OSTI]

    Yang, Zheng

    IEEE TRANSACTIONS ON NANOTECHNOLOGY, VOL. 10, NO. 3, MAY 2011 499 TiSi2 Nanocrystal Metal Oxide memory window, faster writing and erasing, and longer retention lifetime as a result of the metallic property of the silicide NCs. Due to thermally stable, CMOS compatible properties, TiSi2 NCs are highly

  9. Dye Surface Coating Enables Visible Light Activation of TiO2 Nanoparticles Leading to Degradation of

    E-Print Network [OSTI]

    Brown, Eric

    Dye Surface Coating Enables Visible Light Activation of TiO2 Nanoparticles Leading to Degradation that an alizarin red S ~ARS! dye coating on TiO2 nanoparticles enables visible light activation of reactive oxygen species. Successful coating of nanoparti- cles with dye is demonstrated through

  10. Tunable synthesis of TiO{sub 2}/SrO core/shell nanowire arrays with enhanced photocatalytic activity

    SciTech Connect (OSTI)

    Wang, Wenqi [Faculty of Earth Sciences, China University of Geosciences, Wuhan 430074 (China)] [Faculty of Earth Sciences, China University of Geosciences, Wuhan 430074 (China); Yang, Jie, E-mail: flyyangj@163.com [Faculty of Mechanical and Electronic Information, China University of Geosciences, Wuhan 430074 (China)] [Faculty of Mechanical and Electronic Information, China University of Geosciences, Wuhan 430074 (China); Gong, Yingpeng, E-mail: ypgong@jhust.edu.cn [School of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074 (China)] [School of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074 (China); Hong, Hanlie [Faculty of Earth Sciences, China University of Geosciences, Wuhan 430074 (China)] [Faculty of Earth Sciences, China University of Geosciences, Wuhan 430074 (China)

    2013-01-15T23:59:59.000Z

    Graphical abstract: TiO{sub 2} nanowires with tunable SrO shell layer are easily fabricated. The core/shell structure can enhance the photocatalytic activity of TiO{sub 2} nanowires and restrict the recombination of the electrons/holes. Display Omitted Highlights: ? A facile method to fabricate TiO{sub 2}/SrO core-shell nanowire array is reported. ? The thickness of SrO shell layer can be tunable by adjusting the dipping time. ? TiO{sub 2}/SrO core/shell nanowires shows enhanced photocatalytic activity. -- Abstract: We report a simple method to fabricate well-aligned TiO{sub 2}/SrO core/shell nanowire arrays. The core/shell structure is confirmed to have crystalline TiO{sub 2} nanowires core and amorphous SrO shell layer. The shell is composed of SrO with tunable thickness. Photocatalytic activity measurement shows that TiO{sub 2}/SrO core/shell nanowire arrays outperform uncovered TiO{sub 2} nanowires. Such core/shell nanowire arrays have potential applications for photovoltaic devices and as high performance photocatalyst.

  11. Preparation and characterization of VOx/TiO2 catalytic coatings on stainless steel plates for structured catalytic reactors.

    E-Print Network [OSTI]

    Boyer, Edmond

    for structured catalytic reactors. Thierry Giornelli, Axel Löfberg* and Elisabeth Bordes-Richard Unité de.Lofberg@univ-lille1.fr Abstract The parameters to be controlled to coat metallic walls by VOx/TiO2 catalysts which) was chosen because of its large application in industrial catalytic reactors. TiO2 films on stainless steel

  12. Stoichiometric, nonstoichiometric, and locally nonstoichiometric SrTiO{sub 3} films grown by molecular beam epitaxy

    SciTech Connect (OSTI)

    Fisher, P.; Du, H.; Skowronski, M.; Salvador, P. A. [Department of Materials Science and Engineering, Carnegie Mellon University, Pittsburgh, Pennsylvania 15213 (United States); Maksimov, O. [Electro-Optics Center, Pennsylvania State University, Freeport, Pennsylvania 16229 (United States); Weng, X. [Materials Research Institute, Pennsylvania State University, University Park, Pennsylvania 16802 (United States)

    2008-01-01T23:59:59.000Z

    SrTiO{sub 3} films were grown by reactive molecular beam epitaxy to have varying degrees of both global and local cationic nonstoichiometries (with stoichiometry defined as a 1:1 ratio of Sr:Ti). Slight global excesses of Sr and Ti resulted in two-fold reconstructions in the reflection high-energy electron diffraction patterns along the [110] and [100] azimuths, respectively. Larger global nonstoichiometries (2:1 and 1:2 ratios) were also accommodated into the film's crystalline structure and affected the long-range crystalline order as observed in the x-ray diffraction patterns, both of which were related to the parent perovskite pattern. Local nonstoichiometries were introduced by depositing multiple monolayers (MLs) (from 2 to 33) of SrO and TiO{sub 2} in an alternating fashion, while maintaining the global SrTiO{sub 3} stoichiometry. These layered structures of SrO and TiO{sub 2} blocks inter-reacted during growth to form highly crystalline epitaxial SrTiO{sub 3}. Films grown in this manner with blocks thicker than 8 MLs were fully relaxed and, when the block thicknesses ranged between 8 and 10 MLs, the full widths at half maxima of 2{theta} peaks were narrower than the standard SrTiO{sub 3} films having blocks 1 ML thick.

  13. Loading rate dependency of maximum nanoindentation depth in nano-grained NiTi shape memory alloy

    E-Print Network [OSTI]

    Sun, Qing-Ping

    of loading rate on nanoindentation depth for nano-grained polycrystalline superelastic (SE) NiTi SMA superelastic NiTi polycrystalline sheets were purchased from Memory Applications Inc. (USA). With X temperature (T=23 C). To avoid plastic deformation under the tip, two spherical diamond tips with radii of R

  14. "ATLAS.ti 101" November 30, 2011 Dr. Stuart Shuman Qualitative Data Analysis Program University of Massachusetts Amherst

    E-Print Network [OSTI]

    Massachusetts at Amherst, University of

    Page 1 "ATLAS.ti 101" November 30, 2011 Dr. Stuart Shuman ­ Qualitative Data Analysis Program University of Massachusetts Amherst "ATLAS.ti 101: A Primer" Dr. Stuart W. Shulman Director, QDAPUMass. According to ATLAS: "This file is the `gatekeeper' that controls access to the data source. Every user

  15. Adsorption of water and ammonia on TiO2-anatase cluster models Isik Onal a,*, Sezen Soyer a

    E-Print Network [OSTI]

    Senkan, Selim M.

    to the surface properties and the adsorption reactions of titanium dioxide-anatase surface. Lin and Bai [3 reserved. Keywords: TiO2; Anatase; Adsorption; Water; Ammonia; DFT 1. Introduction Titanium oxides are usedAdsorption of water and ammonia on TiO2-anatase cluster models Isik Onal a,*, Sezen Soyer a , Selim

  16. Figure 1: Functionalization of TiO2 by anhydrous chemical vapor deposition of trifunctional siloxane adsorbates.

    E-Print Network [OSTI]

    siloxanes form only 2 covalent bonds, in a `bridge' mode with adjacent Ti4+ ions on the TiO2 surface of binding enthalpies at the DFT B3LYP/(LACVP/6-31G**) level of theory indicating that the `bridge' binding optical, electrical, magnetic and mechanical properties of semiconductor materials. For example, dye

  17. Electrospun nanofibers of Er{sup 3+}-doped TiO{sub 2} with photocatalytic activity beyond the absorption edge

    SciTech Connect (OSTI)

    Zheng, Yali; Wang, Wenzhong, E-mail: wzwang@mail.sic.ac.cn

    2014-02-15T23:59:59.000Z

    Er{sup 3+}-doped TiO{sub 2} nanofibers with different Er{sup 3+} contents were prepared via electrospinning and characterized by X-ray diffraction, scanning electron microscopy, ultravioletvisible diffuse reflectance spectroscopy and photocurrent measurement. Photocatalytic activities of the as-prepared samples were evaluated by the decolorization of methyl orange aqueous solution under simulated solar light irradiation. The results indicated that the photocatalytic activity of Er{sup 3+}-doped TiO{sub 2} nanofibers was much higher than that of the undoped one, and the optimal dosage of Er{sup 3+} at 1 mol% achieved the highest degradation rate. Moreover, the photocatalytic activity of Er{sup 3+}-doped TiO{sub 2} nanofibers under the irradiation of light with the wavelength beyond the absorption edge of TiO{sub 2} was explored by the decolorization of a dye, rhodamine B and the photodegradation of a typical colorless pollutant, phenol. The results further revealed the mechanism of the enhanced photocatalytic activity through Er{sup 3+} doping in TiO{sub 2} nanofibers. - Graphical abstract: Display Omitted - Highlights: ?Er{sup 3+}:TiO{sub 2} nanofibers with different Er{sup 3+} contents were prepared via electrospinning. ?The photocatalytic activity of Er{sup 3+}:TiO{sub 2} was much higher than that of undoped one. ?Er{sup 3+}:TiO{sub 2} could be activated by the light with wavelength beyond the absorption edge.

  18. The corrosion behavior and hemocompatibility of TiNi alloys coated with DLC by plasma based ion implantation

    E-Print Network [OSTI]

    Zheng, Yufeng

    The corrosion behavior and hemocompatibility of TiNi alloys coated with DLC by plasma based ion characteristics and corrosion resistant property as well as hemocompatibility has been investigated. The results measurement and SEM observation, we found that the uncoated TiNi alloy shows severe pitting corrosion, which

  19. Predicting New TiO2 Phases with Low Band Gaps by a Multiobjective Global Optimization Approach

    E-Print Network [OSTI]

    Gong, Xingao

    stable. This is equivalent to a global optimization problem of a biobjective function, i.e., total energyPredicting New TiO2 Phases with Low Band Gaps by a Multiobjective Global Optimization Approach Hou as a novel global optimization algorithm to predict new polymorphs of bulk TiO2 with better optical

  20. Trapping in deep defects under substrate hot electron stress in TiN/Hf-silicate based gate stacks

    E-Print Network [OSTI]

    Misra, Durgamadhab "Durga"

    Trapping in deep defects under substrate hot electron stress in TiN/Hf-silicate based gate stacks N. Zaslavsky Abstract Substrate hot electron stress was applied on n+ -ringed n-channel MOS capacitors with TiN/Hf-silicate. Introduction Hafnium silicate based high-j gate dielectrics have been put forth as the leading candidates

  1. Epitaxial TiN(001) wetting layer for growth of thin single-crystal Cu(001) J. S. Chawla, X. Y. Zhang, and D. Galla)

    E-Print Network [OSTI]

    Gall, Daniel

    Epitaxial TiN(001) wetting layer for growth of thin single-crystal Cu(001) J. S. Chawla, X. Y.5-nm-thick TiN(001) buffer layer. X-ray diffraction and reflection indicate that the TiN(001) surface continuous Cu layer on MgO. The wet- ting of Cu on TiN is expected to be better, due to the surface energy

  2. Nondestructive characterization of a TiN metal gate: Chemical and structural properties by means of standing-wave hard x-ray

    E-Print Network [OSTI]

    Fadley, Charles

    Nondestructive characterization of a TiN metal gate: Chemical and structural properties by means (HXPS, HAXPES) is applied to a thick (100 A ) film of a metal gate TiN grown on top of a Si/MoSi2 of TiN, as well as the buried interface between TiN and the native oxide on top of the mirror

  3. Electronic polarizability and crystallization of K{sub 2}O-TiO{sub 2}-GeO{sub 2} glasses with high TiO{sub 2} contents

    SciTech Connect (OSTI)

    Fukushima, T. [Department of Materials Science and Technology, Nagaoka University of Technology, 1603-1 Kamitomioka-cho, Nagaoka 940-2188 (Japan); Benino, Y. [Department of Materials Science and Technology, Nagaoka University of Technology, 1603-1 Kamitomioka-cho, Nagaoka 940-2188 (Japan); Fujiwara, T. [Department of Applied Physics, Graduate School of Engineering, Tohoku University, 6-6-05 Aoba, Sendai 980-8579 (Japan); Dimitrov, V. [Department of Silicate Technology, University of Chemical Technology and Metallurgy, 8 Kl, Ohridki Blvd., Sofia 1756 (Bulgaria); Komatsu, T. [Department of Materials Science and Technology, Nagaoka University of Technology, 1603-1 Kamitomioka-cho, Nagaoka 940-2188 (Japan)]. E-mail: komatsu@chem.nagaokaut.ac.jp

    2006-12-15T23:59:59.000Z

    Some K{sub 2}O-TiO{sub 2}-GeO{sub 2} glasses with a large amount of TiO{sub 2} contents (15-25mol%) such as 25K{sub 2}O-25TiO{sub 2}-50GeO{sub 2} have been prepared, and their electronic polarizability, Raman scattering spectra, and crystallization behavior are examined to clarify thermal properties and structure of the glasses and to develop new nonlinear optical crystallized glasses. It is proposed that the glasses consist of the network of TiO{sub 6} and GeO{sub 4} polyhedra. The glasses show large optical basicities of {lambda}=0.88-0.92, indicating the high polarizabity of TiO{sub n} (n=4-6) polyhedra in the glasses. K{sub 2}TiGe{sub 3}O{sub 9} crystals are formed through crystallization in all glasses prepared in the present study. In particular, 20K{sub 2}O-20TiO{sub 2}-60GeO{sub 2} glass shows bulk crystallization and 18K{sub 2}O-18TiO{sub 2}-64GeO{sub 2} glass exhibits surface crystallization giving the c-axis orientation. The crystallized glasses show second harmonic generations (SHGs), and it is suggested that the distortion of TiO{sub 6} octahedra in K{sub 2}TiGe{sub 3}O{sub 9} crystals induces SHGs.

  4. Structural, textural and catalytic properties of Al-, Ti-pillared clays

    SciTech Connect (OSTI)

    Ramos-Galvan, C.E.; Dominguez, J.M.; Sandoval-Robles, G.; Castillo-Mares, A.; Nava E, N.

    1996-12-31T23:59:59.000Z

    Al-, Ti- and Zr-pillared clays were characterized and NiMo/Pilc`s were tested in HDS reactions. The combination of activity measurements with Moessbauer Spectroscopy and x-ray microanalysis at microscopical scale give insight in the metal phases migration during pillaring, reaction and regeneration steps. {Alpha}-Fe phase in free Fe{sub 2}O{sub 3} islands predominate together with structural Fe{sup 3+} phase, but during the catalytic reaction Fe{sup 2+} forms. Delamination of the Ti- and Zr-Clay supports, together with high Lewis acidity might enhance their catalytic properties.

  5. Superior Corrosion Resistance Properties of TiN-Based Coatings on Zircaloy Tubes in Supercritical Water

    SciTech Connect (OSTI)

    Fauzia Khatkhatay; Liang Jiao; Jie Jian; Zhijie Jiao; Hongbin Zhang; Jian Gan; Haiyan Wang; Wenrui Zhang; Xinghang Zhang

    2014-08-01T23:59:59.000Z

    Thin films of TiN and Ti0.35Al0.65N nanocomposite were deposited on polished Zircaloy-4 tubes. After exposure to supercritical water for 48 h, the coated tubes are remarkably intact, while the bare uncoated tube shows severe oxidation and breakaway corrosion. X-ray diffraction patterns, secondary electron images, backscattered electron images, and energy dispersive X-ray spectroscopy data from the tube surfaces and cross-sections show that a protective oxide, formed on the film surface, effectively prevents further oxidation and corrosion to the Zircaloy-4 tubes. This result demonstrates the effectiveness of thin film ceramics as protective coatings under extreme environments.

  6. Full $fp$-shell study of even-even $^{48-56}$Ti isotopes

    E-Print Network [OSTI]

    F. A. Majeed; A. A. Auda

    2006-02-02T23:59:59.000Z

    The level schemes and transition rates {\\em B}({\\em E}2;$\\uparrow$) of eve-even $^{48-56}$Ti isotopes were studied by performing large-scale shell model calculations with FPD6 and GXPF1 effective interactions. Excellent agreement were obtained by comparing the first 2$^{+}$ level for all isotopes with the recently available experimental data, but studying the transition strengths {\\em B}({\\em E}2; 0$^+_{g.s.} \\to2^+_1$) for all Ti isotopes using constant proton-neutron effective charges prove the limitations of the present large-scale calculations to reproduce the experiment in detail.

  7. Photocatalytic oxidation of NO{sub x} using TiO{sub 2}/activated carbon

    SciTech Connect (OSTI)

    Wang, S.; Chen, D.H.; Li, K.Y. [Lamar Univ., Beaumont, TX (United States)] [and others

    1995-12-31T23:59:59.000Z

    This paper summarizes experimental results for a method of nitrogen oxides (NO{sub x}) emission control. NO{sub x} was oxidized photocatalytically to nitric acid (HNO{sub 3}) using different titanium dioxide (TiO{sub 2}) catalysts. The addition of ferric oxide improved the performance of the TiO{sub 2}. Of four adsorbents tested, activated carbon performed best in suppressing NO{sub 2} concentration. Optimum catalyst compositions were determined. Initial results indicated that photocatalytic oxidation of NO{sub x} offers several advantages over other emission control methods.

  8. ZnO/porous-Si and TiO{sub 2}/porous-Si nanocomposite nanopillars

    SciTech Connect (OSTI)

    Wang, Dong, E-mail: dong.wang@tu-ilmenau.de; Yan, Yong; Schaaf, Peter [Chair Materials for Electronics, Institute of Materials Engineering and Institute of Micro- and Nanotechnologies MacroNano, TU Ilmenau, Gustav-Kirchhoff-Str. 5, 98693 Ilmenau (Germany); Sharp, Thomas [Oxford Instruments Plasma Technology Ltd., Yatton, Bristol BS49 4AP (United Kingdom); Schnherr, Sven; Ronning, Carsten [Institute for Solid State Physics, Friedrich Schiller University Jena, Max-Wien-Platz 1, 07743 Jena (Germany); Ji, Ran [SUSS MicroTec Lithography GmbH, Schleissheimer Str. 90, 85748 Garching (Germany)

    2015-01-01T23:59:59.000Z

    Porous Si nanopillar arrays are used as templates for atomic layer deposition of ZnO and TiO{sub 2}, and thus, ZnO/porous-Si and TiO{sub 2}/porous-Si nanocomposite nanopillars are fabricated. The diffusion of the precursor molecules into the inside of the porous structure occurs via Knudsen diffusion and is strongly limited by the small pore size. The luminescence of the ZnO/porous-Si nanocomposite nanopillars is also investigated, and the optical emission can be changed and even quenched after a strong plasma treatment. Such nanocomposite nanopillars are interesting for photocatalysis and sensors.

  9. Elastic and anelastic relaxations associated with phase transitions in EuTiO3

    E-Print Network [OSTI]

    Spalek, Leszek J.; Saxena, Siddharth S.; Panagopoulos, Christos; Katsufuji, Takuro; Schiemer, Jason A.; Carpenter, Michael A.

    2014-08-29T23:59:59.000Z

    resonance peaks are totally attenuated (superattenuation). The pinning process is still complete by ~400 K, however. 42 If the twin walls in EuTiO3 are subject to pinning by oxygen vacancies as in LaAlO3, it is likely that their freezing interval will also... resonance peaks are totally attenuated (superattenuation). The pinning process is still complete by ~400 K, however. 42 If the twin walls in EuTiO3 are subject to pinning by oxygen vacancies as in LaAlO3, it is likely that their freezing interval will also...

  10. Characterizations Of Precipitate Phases In a Ti-Ni-Pd Alloy

    SciTech Connect (OSTI)

    Yang, Fan; Kovarik, Libor; Phillips, Patrick J.; Noebe, Ronald D.; Mills, M. J.

    2012-06-01T23:59:59.000Z

    Precipitates in the Ti46Ni37.5Pd16.5 alloy were investigated by electron diffraction and high-resolution scanning transmission electron microscopy. The phase content and stability were determined at several different temperatures and times. Aging at 400 C for an hour results in a new phase, which is consumed by P-phase at longer aging time. At 450 C, the new phase appears first, and then coexists with P-phase. At 500 C, the entire alloy transformed into the new phase. At 550 C, Ti3(Ni,Pd)4 phase begins to form.

  11. Surface structure and electrochemical characteristics of Ti-V-Cr bcc-type solid solution alloys sintered with Ni

    SciTech Connect (OSTI)

    Tsuji, Yoichiro; Yamamoto, Osamu; Matsuda, Hiromu; Toyoguchi, Yoshinori

    2000-07-01T23:59:59.000Z

    Ti-V-Cr bcc-type solid solution alloys can absorb a large amount of hydrogen and be applied to active materials of the negative electrode in Ni-MH batteries. However, because of the insolubility of Ni into these alloys, the electrochemical characteristics like discharge capacity and cycle life were poor. In order to increase the discharge capacity of hydrogen absorbing alloy electrodes, Ti-V-Cr bcc-type alloy powders were sintered with Ni in order to form Ni contained surface layer on the alloy surface. As sintering temperature rose up, the surface composition changed from TiNi to Ti{sub 2}Ni. TiNi surface layer showed better electrochemical characteristics. For the Ni adding method, Ni electroless plating was preferred because of good adhesion. As a result of optimized conditions, a discharge capacity of 570 mAh/g and an improvement of cycle life were achieved.

  12. Interface control of ferroelectricity in LaNiO{sub 3}-BaTiO{sub 3} superlattices

    SciTech Connect (OSTI)

    Wu, Yin-Zhong, E-mail: yzwu@cslg.edu.cn [Jiangsu Laboratory of Advanced Functional Materials and Physics Department, Changshu Institute of Technology, Changshu 215500 (China); School of Mathematics and Physics, Suzhou University of Science and Technology, Suzhou 215009 (China); Lu, Hai-Shuang; Cai, Tian-Yi; Ju, Sheng, E-mail: jusheng@suda.edu.cn [Department of Physics and Jiangsu Key Laboratory of Thin Films, Soochow University, Suzhou 215006 (China)

    2014-08-15T23:59:59.000Z

    LaNiO{sub 3}-BaTiO{sub 3} superlattices with different types of interfaces are studied from first-principles density-functional theory. It is revealed that the ferroelectricity in the superlattice with (NiO{sub 2}){sup ?}/(BaO){sup 0} interfaces is enhanced from that of the superlattice with (LaO){sup +}/(TiO{sub 2}){sup 0} interfaces. The origin lies at the polar discontinuity at the interface, which makes the holes localized within the (NiO{sub 2}){sup ?}/(BaO){sup 0} interface, but drives a penetration of electrons into BaTiO{sub 3} component near (LaO){sup +}/(TiO{sub 2}){sup 0} interface. Our calculations demonstrate an effective avenue to the robust ferroelectricity in BaTiO{sub 3} ultrathin films.

  13. Micro artificial muscle fiber using NiTi spring for soft robotics Sangbae Kim, Elliot Hawkes, Kyujin Cho, Matthew Jolda, Joe Foley and Robert Wood

    E-Print Network [OSTI]

    Wood, Robert

    from shape memory alloy (NiTi) coiled springs. An enhanced spring NiTi model describes the combination of micro-coil spring, we present a novel mesh-worm prototype that utilizes bio-inspired antagonistic structure alteration, NiTi can be restructured into coil springs. Chang et al.[1], discuss the numerous

  14. The influence of TiSi2 and CoSi2 growth on Si native point defects: The role of the diffusing species

    E-Print Network [OSTI]

    Florida, University of

    from codeposited metal and Si. The as-deposited films had the compositions Ti, TiSi0.8 , TiSi2 undersaturation.3 Nevertheless, the mechanism by which silicide films effect a perturbance in the point defect, causing a va- cancy supersaturation. The formation of CoSi2 from CoSi proceeds via diffusion of metal

  15. Intrinsic anomalous surface roughening of TiN films deposited by reactive sputtering M. A. Auger,1,5 L. Vzquez,1,

    E-Print Network [OSTI]

    Cuerno, Rodolfo

    Intrinsic anomalous surface roughening of TiN films deposited by reactive sputtering M. A. Auger,1 manuscript received 1 December 2005; published 31 January 2006 We study surface kinetic roughening of TiN. The TiN films exhibit intrinsic anomalous scaling and multiscaling. The film kinetic roughening

  16. Selective etching of TiN over TaN and vice versa in chlorine-containing Hyungjoo Shin,a)

    E-Print Network [OSTI]

    Economou, Demetre J.

    Selective etching of TiN over TaN and vice versa in chlorine-containing plasmas Hyungjoo Shin 1 April 2013; published 18 April 2013) Selectivity of etching between physical vapor-deposited TiN selectivity of etching TiN over TaN by adding small amounts (

  17. Small Au and Pt Clusters at the Anatase TiO2(101) Surface: Behavior at Terraces, Steps, and Surface Oxygen Vacancies

    E-Print Network [OSTI]

    Diebold, Ulrike

    polymorph of titanium dioxide (TiO2). TiO2 is a versatile oxide material with important applications in many@ecust.edu.cn; diebold@tulane.edu Abstract: The adsorption properties of Au and Pt metal nanoclusters on TiO2 anatase edges. A preference for adsorption at type D-(112) steps is observed, which is probably a result

  18. Appl Nbr Full TiFirst Name Middle Name Last Name Sex Category PH Category 00036777 F ADITI GUPTA F GEN N

    E-Print Network [OSTI]

    Ribeiro, Vinay

    Appl Nbr Full TiFirst Name Middle Name Last Name Sex Category PH Category 00036777 F ADITI GUPTA F 00036674 F SRISHTI VIVEK SHARMA F GEN N Appl Nbr Full TiFirst Name Middle Name Last Name Sex Category PH) Appl Nbr Full TiFirst Name Middle Name Last Name Sex Category PH Category 00032299 F SANDEEP KUMAR

  19. TiSnSb a new efficient negative electrode for Li-ion batteries: mechanism investigations by operando-XRD and Mossbauer techniques

    E-Print Network [OSTI]

    Boyer, Edmond

    TiSnSb a new efficient negative electrode for Li-ion batteries: mechanism investigations We report the electrochemical study of TiSnSb towards Li, as a negative electrode for Li-ion batteries. TiSnSb can reversibly take up more than 5 lithiums per formula unit leading to reversible

  20. Aspects of the SrO-CuO-TiO2 Ternary System Related to the Deposition of SrTiO3 and Copper-Doped SrTiO3 Thin-Film Buffer Layers

    SciTech Connect (OSTI)

    A. Ayala

    2004-12-20T23:59:59.000Z

    YBa{sub 2}Cu{sub 3}O{sub 7-{delta}} (YBCO) coated conductors are promising materials for large-scale superconductivity applications. One version of a YBCO coated conductor is based on ion beam assisted deposition (IBAD) of magnesium oxide (MgO) onto polycrystalline metal substrates. SrTiO{sub 3} (STO) is often deposited by physical vapor deposition (PVD) methods as a buffer layer between the YBCO and IBAD MgO due to its chemical stability and lattice mismatch of only {approx}1.5% with YBCO. In this work, some aspects of the stability of STO with respect to copper (Cu) and chemical solution deposition of STO on IBAD MgO templates were examined. Solubility limits of Cu in STO were established by processing Cu-doped STO powders by conventional bulk preparation techniques. The maximum solubility of Cu in STO was {approx}1% as determined by transmission electron microscopy (TEM) and Rietveld refinements of x-ray diffraction (XRD) data. XRD analysis, performed in collaboration with NIST, on powder compositions on the STO/SrCuO{sub 2} tie line did not identify any ternary phases. SrCu{sub 0.10}Ti{sub 0.90}O{sub y} buffer layers were prepared by pulsed laser deposition (PLD) and CSD on IBAD MgO flexible metallic textured tapes. TEM analysis of a {approx}100 nm thick SrCu{sub 0.10}Ti{sub 0.90}O{sub y} buffer layer deposited by PLD showed a smooth Cu-doped STO/MgO interface. A {approx}600 nm thick YBCO film, deposited onto the SrCu{sub 0.10}Ti{sub 0.90}O{sub y} buffer by PLD, exhibited a T{sub c} of 87 K and critical current density (J{sub c}) of {approx}1 MA/cm{sup 2}. STO and Cu-doped STO thin films by CSD were {approx}30 nm thick. The in plane alignment (FWHM) after deposition of the STO improved by {approx}1{sup o} while it degraded by {approx}2{sup o} with the SrCu{sub 0.05}TiO{sub y} buffer. YBCO was deposited by PLD on the STO and SrCu{sub 0.05}TiO{sub y} buffers. The in plane alignment (FWHM) of the YBCO with the STO buffer layer slightly improved while that of the YBCO with the SrCu{sub 0.05}TiO{sub y} buffer layer remained constant. A goal of the CSD approach to fabrication of coated conductors is process simplicity. In this study, single layer textured films were obtained without a nucleating seed layer that has been deemed necessary by several investigators. These results indicate that Cu-doped STO buffer layers deposited by PLD or CSD are compatible with IBAD MgO and YBCO and that CSD is a viable approach to coated conductor fabrication.

  1. Synthesis and crystal structure of CuZrTiO{sub 5}-A new crystal structure type

    SciTech Connect (OSTI)

    Troitzsch, Ulrike [Research School of Earth Sciences, Australian National University, Canberra ACT 0200 (Australia); Christy, Andrew G., E-mail: Andrew.Christy@anu.edu.a [Research School of Earth Sciences, Australian National University, Canberra ACT 0200 (Australia); Willis, Anthony C. [Research School of Chemistry, Australian National University, Canberra ACT 0200 (Australia); Ellis, David J. [Research School of Earth Sciences, Australian National University, Canberra ACT 0200 (Australia)

    2010-03-15T23:59:59.000Z

    A new compound, CuZrTiO{sub 5}, was synthesized as strongly pleochroic green crystals from the oxides between 995 and 1010 deg. C, 1 atm. Its crystal structure was determined by single crystal XRD, resulting in R (F{sup 2}>2sigma(F{sup 2}))=0.032 and wR (all data)=0.079). CuZrTiO{sub 5} is orthorhombic, space group P2{sub 1}2{sub 1}2{sub 1}, a=3.5871(3) A, b=6.6968(4) A, c=14.6679(9) A, V=352.35(4) A{sup 3}, Z=4. The structure is topologically similar to In{sub 2}TiO{sub 5} but differs in space group and cation coordination. CuZrTiO{sub 5} has relatively regular TiO{sub 6} polyhedra, but coordination is 7+1 for Zr, and 4+2 for Cu due to the Jahn-Teller effect. Ordering of the long Cu-O bonds causes reduction in symmetry relative to In{sub 2}TiO{sub 5}. Layers of Cu alternate with Ti+Zr on (001), giving rise to a distinct cleavage. Bond valence sums on Ti and Zr are far from ideal, which appears due to the limited ability of this structural topology to avoid close next-nearest neighbour distances. - Graphical abstract: The new compound CuZrTiO{sub 5} is orthorhombic (P2{sub 1}2{sub 1}2{sub 1}), with a=3.5871(3) A, b=6.6968(4) A, c=14.6679(9) A. The structure, determined with single crystal XRD, represents a new crystal structure type that is a slight distortion of that of In{sub 2}TiO{sub 5} but differs in space group and cation coordination.

  2. Effects of Point Defects and Impurities on Kinetics in NaAlH4

    Broader source: Energy.gov (indexed) [DOE]

    Alanate * Viable hydrogen storage material (5.6 wt%) NaAlH 4 13 Na 3 AlH 6 + 23 Al + H 2 Na 3 AlH 6 3 NaH + Al + 32 H 2 * But: reactions slow - Only happen at too...

  3. In situ X-ray diffraction strain-controlled study of TiNbZr and TiNbTa shape memory alloys: crystal lattice and transformation features

    SciTech Connect (OSTI)

    Dubinskiy, S. [cole de technologie suprieure, 1100, Notre-Dame Street West, Montreal, Quebec H3C 1K3 (Canada); National University of Science and Technology MISIS, 4, Leninskiy prosp., Moscow 119049 (Russian Federation); Prokoshkin, S. [National University of Science and Technology MISIS, 4, Leninskiy prosp., Moscow 119049 (Russian Federation); Brailovski, V., E-mail: vladimir.brailovski@etsmtl.ca [cole de technologie suprieure, 1100, Notre-Dame Street West, Montreal, Quebec H3C 1K3 (Canada); Inaekyan, K. [cole de technologie suprieure, 1100, Notre-Dame Street West, Montreal, Quebec H3C 1K3 (Canada); Korotitskiy, A. [National University of Science and Technology MISIS, 4, Leninskiy prosp., Moscow 119049 (Russian Federation)

    2014-02-15T23:59:59.000Z

    Phase and structure transformations in biomedical Ti21.8Nb6.0Zr (TNZ) and Ti19.7Nb5.8Ta (TNT) shape memory alloys (at.%) under and without load in the ? 150 to 100 S temperature range are studied in situ using an original tensile module for a low-temperature chamber of an X-ray diffractometer. Alpha?- and beta-phase lattice parameters, the crystallographic resource of recovery strain, phase and structure transformation sequences, and microstress appearance and disappearance are examined, compared and discussed. For both alloys, the crystallographic resource of recovery strain decreases with temperature increase to become 4.5% for TNZ and 2.5% for TNT alloy (at RT). Loading at low temperatures leads to additional ??-phase formation and reorientation. Heating under load, as compared to strain-free heating, affects the reverse transformation sequence of both alloys in different ways. For TNZ alloy, strain-free heating results in simultaneous ??? and ???? transformations, whereas during heating under stress, they are sequential: ? + ???? precedes ????. For TNT alloy, strain-free heating results in reverse ???? transformation, whereas during heating under stress, ???? transformation is preceded by ??-phase reorientation. - Highlights: Comparative in situ XRD analysis of TiNbZr(Ta) shape memory alloys is realized. Lattice parameters of ?- and ??-phases are calculated in the ? 150 to + 100 C range. The higher the temperature, the lower the ???? transformation strain. Loading at low temperatures results in ??-phase formation and reorientation. Transformation sequences upon heating with and without loading are different.

  4. Formation of mixed oxide powders in flames: Part I. TiO sub 2 --SiO sub 2

    SciTech Connect (OSTI)

    Hung, C.; Katz, J.L. (Department of Chemical Engineering, The Johns Hopkins University, Baltimore, Maryland 21218 (United States))

    1992-07-01T23:59:59.000Z

    Mixed oxide powders, e.g., Al{sub 2}O{sub 3}--TiO{sub 2}, SiO{sub 2}--GeO{sub 2}, and TiO{sub 2}--SiO{sub 2}, are used in industry to produce ceramics, optical fibers, catalysts, and paint opacifiers. The properties of these products depend upon the morphology of the powders. Ceramics and optical fibers are produced using either a uniform mixture of multicomponent particles or a uniform solution. The desired morphology for catalysts is a high surface area and many active sites. TiO{sub 2} coated with a layer of SiO{sub 2} is the desired structure for use as a paint opacifier. In this paper, TiO{sub 2}--SiO{sub 2} mixed oxide powders were synthesized using a counterflow diffusion flame burner. TiCl{sub 4} and SiCl{sub 4} were used as source materials for the formation of oxide particles in hydrogen-oxygen flames. In-situ particle sizes were determined using dynamic light scattering. A thermophoretic sampling method also was used to collect particles directly onto carbon coated grids, and their size, morphology, and crystalline form examined using a transmission electron microscope. A photomultiplier at 90{degree} to the argon ion laser beam was used to measure the light-scattering intensity. The effect of temperature and of Si to Ti concentration ratio on particle morphology was investigated. Strong temperature dependence was observed. At high temperatures, TiO{sub 2} particles were covered with discrete SiO{sub 2} particles. At low temperatures, the structure changes to TiO{sub 2} particles encapsulated by SiO{sub 2}. TEM diffraction pattern measurements showed that the TiO{sub 2} is rutile and the SiO{sub 2} is amorphous silica. At high Si to Ti ratios, SiO{sub 2}-encapsulated TiO{sub 2} particles form. At low Si to Ti ratios, one obtains TiO{sub 2} particles covered with discrete SiO{sub 2} particles.

  5. Discussion! Measurements on these suites of L and LL chondrites show that internal variation in Ti

    E-Print Network [OSTI]

    Grossman, Lawrence

    with substitution of hydrogen, which bonds with oxygen in the lattice to form hydroxyl groups. ! The charge excess in olivine with increasing grade is consistent with diffusive loss of hydrogen during heating and entry of Ti. (2012) This meeting, Abst. #2601.! Effects of Metamorphism on the Valence and Coordination of! Titanium

  6. Processing and Mechanical Properties of Ti2AlC Reinforced with Alumina Fibers

    E-Print Network [OSTI]

    Jeon, Kwonguk

    2012-10-19T23:59:59.000Z

    , even at temperature as high as 1400 oC at which reaction between Ti2AlC and NextelTM 720 was observed. The double torsion (DT) tests were carried out at room temperature to measure the fracture toughness of the HIPed pure and 5vol% alumina fiber...

  7. The pure rotational spectrum of TiS (X3 Dr) at submillimeter wavelengths

    E-Print Network [OSTI]

    Ziurys, Lucy M.

    between layers of sulfide anions [1]. The lubricating properties arise from the weak van der Waals interaction between the layers. TiS2 is also a semiconductor mate- rial, and is widely used as the active cathode component in lithium batteries [2]. Titanium sulfide complexes have been shown to acti- vate H2 [3

  8. Band-engineered SrTiO{sub 3} nanowires for visible light photocatalysis

    SciTech Connect (OSTI)

    Fu, Q.; He, T.; Li, J. L.; Yang, G. W. [State Key Laboratory of Optoelectronic Materials and Technologies, Institute of Optoelectronic and Functional Composite Materials, Nanotechnology Research Center, School of Physics and Engineering, Sun Yat-sen University, Guangzhou 510275, Guangdong (China)

    2012-11-15T23:59:59.000Z

    We have theoretically investigated the structural, electronic, and optical properties of perovskite SrTiO{sub 3} nanowires for use in visible light photocatalytic applications using pseudopotential density-functional theory calculations. The electronic structure calculations show that the band gap is modified in the SrTiO{sub 3} nanowires compared with that of the bulk. For TiO{sub 2}-terminated nanowires, the mid-band states induced by the combination of oxygen and strontium atoms on the surface lead to a shift in the valence band toward the conduction band without interference from the edge of the conduction band, which reduces the band gap. On the contrary, the electronic states induced by the combination of oxygen and strontium atoms on the surface of SrO-terminated nanowires lead to a shift in the conduction band toward the valence band. The calculated optical results indicate that the absorption edge of the nanowires shift towards the red-light region. These theoretical results suggest that perovskite SrTiO{sub 3} nanowires are promising candidates for use in visible light photocatalytic processes such as solar-assisted water splitting reactions.

  9. Room temperature alcohol sensing by oxygen vacancy controlled TiO{sub 2} nanotube array

    SciTech Connect (OSTI)

    Hazra, A.; Dutta, K.; Bhowmik, B.; Bhattacharyya, P., E-mail: pb-etc-besu@yahoo.com [Nano-Thin Films and Solid State Gas Sensor Devices Laboratory, Department of Electronics and Telecommunication Engineering, Indian Institute of Engineering Science and Technology (IIEST), Shibpur, Howrah (India); Chattopadhyay, P. P. [Department of Metallurgy and Materials Engineering, Indian Institute of Engineering Science and Technology (IIEST), Shibpur, Howrah (India)

    2014-08-25T23:59:59.000Z

    Oxygen vacancy (OV) controlled TiO{sub 2} nanotubes, having diameters of 5070?nm and lengths of 200250?nm, were synthesized by electrochemical anodization in the mixed electrolyte comprising NH{sub 4}F and ethylene glycol with selective H{sub 2}O content. The structural evolution of TiO{sub 2} nanoforms has been studied by field emission scanning electron microscopy. Variation in the formation of OVs with the variation of the structure of TiO{sub 2} nanoforms has been evaluated by photoluminescence and X-ray photoelectron spectroscopy. The sensor characteristics were correlated to the variation of the amount of induced OVs in the nanotubes. The efficient room temperature sensing achieved by the control of OVs of TiO{sub 2} nanotube array has paved the way for developing fast responding alcohol sensor with corresponding response magnitude of 60.2%, 45.3%, and 36.5% towards methanol, ethanol, and 2-propanol, respectively.

  10. ORIGINAL ARTICLE Strength and microstructure of laser fusion-welded TiSS

    E-Print Network [OSTI]

    Yao, Y. Lawrence

    ORIGINAL ARTICLE Strength and microstructure of laser fusion-welded Ti­SS dissimilar material pair robust and reliable dissimilar metal joints has the potential to enable new func- tionalities and reduce the manufacturing costs of medical devices. The need for dissimilar material welds in the med- ical device industry

  11. Enhanced Photovoltaic Performance of Nanostructured Hybrid Solar Cell Using Highly Oriented TiO2 Nanotubes

    E-Print Network [OSTI]

    Cao, Guozhong

    -called third generation of solar cells including dye-sensitized solar cells, DSCs2,3 and organic phoEnhanced Photovoltaic Performance of Nanostructured Hybrid Solar Cell Using Highly Oriented TiO2 nanotubes can be effectively controlled for the suitable use for a hybrid solar cell by varying the diameter

  12. Hierarchical TiO2Si nanowire architecture with photoelectrochemical activity under visible light illumination

    E-Print Network [OSTI]

    Wang, Xudong

    systems are currently less competitive than common solar panels, which to a great extent limits decoration approach opens a new window to tailoring electrical properties of TiO2 for wider spectrum solar energy harvesting and conversion. Owing to the abundance, cleanness, potentially low-cost

  13. St h ti d i l i fStochastic dynamic analysis of offshore wind turbines

    E-Print Network [OSTI]

    Nørvåg, Kjetil

    1 St h ti d i l i fStochastic dynamic analysis of offshore wind turbines ­ with emphasis on fatigue analysis of offshore bottom-fixed wind turbines · Modelling and dynamic analysis of floating wind turbines ­ Stochastic dynamic analysis of offshore wind turbines; mooring system for wave energy converters · 2010 8

  14. www.ti.com SNOSC25B MAY 2004REVISED OCTOBER 2004 LM741 Operational Amplifier

    E-Print Network [OSTI]

    Lynch, Jerome P.

    LM741 www.ti.com SNOSC25B ­MAY 2004­REVISED OCTOBER 2004 LM741 Operational Amplifier Check for Samples: LM741 1FEATURES 2· Overload protection on the input and output · No latch-up when the common mode range is exceeded DESCRIPTION The LM741 series are general purpose operational amplifiers which feature

  15. Process Modeling of Ti-6Al-4V Linear Friction Welding (LFW)

    E-Print Network [OSTI]

    Grujicic, Mica

    Process Modeling of Ti-6Al-4V Linear Friction Welding (LFW) Mica Grujicic, G. Arakere, B finite-element analysis of the linear friction welding (LFW) process is combined with the basic physical in the open literature revealed that the weld region consists of a thermo- mechanically affected zone (TMAZ

  16. China For all ages a MulTi-generaTional exPloraTion

    E-Print Network [OSTI]

    Rowley, Clarence W.

    China For all ages a MulTi-generaTional exPloraTion The greaT Wall, TerraCoTTa Warriors & The MighCTuresque China Experience the Delights of a Well-Crafted Family Tour Dear Princetonian, Join Princeton Journeys, June 27 ­ July 9, 2013, for a comprehensive tour of China designed with families in mind. Explore

  17. Topology of charge density and elastic properties of Ti3SiC2 polymorphs

    SciTech Connect (OSTI)

    Yu, Rong; Zhang, Xiao Feng; He, Lian Long; Ye, Heng Qiang

    2004-06-24T23:59:59.000Z

    Using an all-electron, full potential first-principles method, we have investigated the topology of charge density and elastic properties of the two polymorphs, alpha and beta, of Ti3SiC2. The bonding effect was analyzed based on Bader's quantum theory of ''atoms in molecules'' (AIM). It was found that the Ti-Si bonding effect is significantly weaker in beta than in alpha, giving less stabilizing effect for beta. The Si-C bonds, which are absent in alpha, are formed in beta and provide additional stabilizing effect for beta. In contrast to conventional thinking, there is no direction interaction between Ti atoms in both alpha and beta. The calculated elastic properties are in good agreement with the experimental results, giving the bulk modulus of about 180 GPa and the Poisson's ratio of 0.2. The beta phase is generally softer than the alpha phase. As revealed by the direction dependent Young's modulus, there is only slight elastic anisotropy in Ti3SiC2. For alpha, Young's modulus is minimum in the c direction and maximum in the directions 42o from c. For beta, the maximum lies in the c direction, in part due to the formation of Si-C bonds in this direction.

  18. Wind-Forced ydrodynarnics and Their nteraction Fish and P ance: A Ti -Series An

    E-Print Network [OSTI]

    Taggart, Christopher

    Wind-Forced ydrodynarnics and Their nteraction Fish and P ance: A Ti -Series An Christopher T, Montreal, Que. H3A 151 Taggart, C. T., and W. C. beggett. 1989. Wind-forced hydrodynamics and physical properties essential for estimating short-term mortality of larval fish. We used the data to test

  19. Dopant location identification in Nd3+ -doped TiO2 nanoparticles

    E-Print Network [OSTI]

    Frenkel, Anatoly

    Dopant location identification in Nd3+ -doped TiO2 nanoparticles W. Li Department of Materials. The identification of dopant position and its local environ- ment are essential to explore the effect of doping. X and Technology, Gaithersburg, Maryland 20899, USA C. Ni Department of Materials Science and Engineering

  20. Predictions of the Pt8Ti Phase in Unexpected Systems Richard H. Taylor,,

    E-Print Network [OSTI]

    Curtarolo, Stefano

    Predictions of the Pt8Ti Phase in Unexpected Systems Richard H. Taylor,, Stefano CurtaroloVot 76100, Israel Received March 5, 2010; E-mail: gus.hart@gmail.com; stefano@duke.edu Abstract: The binary in the Rh-W system. A cluster-expansion-based Monte Carlo model reveals a relatively high order