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Note: This page contains sample records for the topic "n2 h2s hg" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

Accurate Thermodynamic Model for the Calculation of H2S Solubility in Pure Water and Brines  

E-Print Network [OSTI]

Accurate Thermodynamic Model for the Calculation of H2S Solubility in Pure Water and Brines Zhenhao, 2007 A thermodynamic model calculating the solubility of hydrogen sulfide (H2S) in pure water phase. With this specific interaction approach, this model is able to predict H2S solubility in other

Zhu, Chen

2

Sulfur Impregnation on Activated Carbon Fibers through H2S Oxidation for Vapor Phase  

E-Print Network [OSTI]

Sulfur Impregnation on Activated Carbon Fibers through H2S Oxidation for Vapor Phase Mercury: Sulfur was impregnated onto activated carbon fibers ACFs through H2S oxidation catalyzed by the sorbent CE Database subject headings: Activated carbon; Sulfur; Mercury; Hydrogen sulfides; Oxidation

Borguet, Eric

3

Review of H2S Abatement in Geothermal Plants and Laboratory Scale Design of  

E-Print Network [OSTI]

Review of H2S Abatement in Geothermal Plants and Laboratory Scale Design of Tray Plate Distillation Engineering ­ ISE December 2013 #12;ii Review of H2S Abatement Methods in Geothermal Plants and Laboratory for decreasing these emissions through abatement systems or even potentially using these gases to generate value

Karlsson, Brynjar

4

Corrosion mechanisms in aqueous solutions containing dissolved H2S. Part 2: Mode! ofthe cathodic reactions.  

E-Print Network [OSTI]

Corrosion mechanisms in aqueous solutions containing dissolved H2S. Part 2: Mode! ofthe cathodicFP Energies nouvelles, Rond-point de 1'échangeur de Solaize BP3, 69360 Solaize, France. J. Corrosion

Paris-Sud XI, Université de

5

Modeling Studies on the Transport of Benzene and H2S in CO2-Water Systems  

E-Print Network [OSTI]

interest in subcritical (hot/liquid) water from 298 K to 473subcritical region. Modeling Studies on the Transport of Benzene and H 2 S in CO 2 -Water

Zheng, L.

2011-01-01T23:59:59.000Z

6

Qualitative determination of H2S crossover rates in nation membranes using ion-probe techniques  

SciTech Connect (OSTI)

Polymer electrolyte membrane fuel cells are sensitive to impurities that may be present in either the oxidizer or fuel. H2S, even at the ppb level, will have a dramatic and adverse affect on fuel cell performance. The H2S permeability through dry and humidified Nafion PEMFC membranes was studied using ion probe techniques. A sulfide anti-oxidant buffer solution was used to trap and concentrate trace quantities of H2S that permeated through 50 cm2samples of Nafion 117 and 212 membranes using a partial pressure difference up to I030ppm at room temperature. Experiments were conducted for up to 24 hours in order to achieve sulfide ion concentrations high enough to be precisely determined by subsequent titration with Pb(N03)2. The rate of H2S crossover for dry 117 and 212 were identical at 1.2e-7 g/min. Humidification increased the crossover rate to 5.ge-7 glmin and 1.8e-6 glmin for 117 and 212 respectively. Although the data collected in this work show that the rate of H2S crossover increases with water content and reduced membrane thickness, an accurate determination of permeation constants from this work was not possible because the H2S partial pressure was not constant throughout the experiment.

Brosha, Eric L [Los Alamos National Laboratory; Rockward, Tommy [Los Alamos National Laboratory; Uribe, Francisco A [Los Alamos National Laboratory; Garzon, Fernando H [Los Alamos National Laboratory

2008-01-01T23:59:59.000Z

7

Influence of pp ions on pion absorption in H2 S. Jonsell,1  

E-Print Network [OSTI]

of experiments measuring the mass difference m m 0 from pion absorption in pionic atoms. These mechanismsInfluence of pp ions on pion absorption in H2 S. Jonsell,1 J. Wallenius,2 and P. Froelich1 1 Institute for Theoretical Atomic and Molecular Physics, Harvard-Smithsonian Center for Astrophysics, 60

8

Effects of Alloying on the Chemistry of CO and H2S on Fe Surfaces D. E. Jiang  

E-Print Network [OSTI]

dusting is preceded by carbide formation, those carbides are not stable and decompose to fine metal and the relatively weak H-S bond, the barriers for H2S dissociation on transition-metal surfaces are usually very. Sulfur can also cause the embrittlement of transition metals such as Ni and Fe.7 Moreover, since H2S

Carter, Emily A.

9

AOI [3] High-Temperature Nano-Derived Micro-H2 and - H2S Sensors  

SciTech Connect (OSTI)

The emissions from coal-fired power plants remain a significant concern for air quality. This environmental challenge must be overcome by controlling the emission of sulfur dioxide (SO2) and hydrogen sulfide (H2S) throughout the entire coal combustion process. One of the processes which could specifically benefit from robust, low cost, and high temperature compatible gas sensors is the coal gasification process which converts coal and/or biomass into syngas. Hydrogen (H2), carbon monoxide (CO) and sulfur compounds make up 33%, 43% and 2% of syngas, respectively. Therefore, development of a high temperature (>500C) chemical sensor for in-situ monitoring of H2, H2S and SO2 levels during coal gasification is strongly desired. The selective detection of SO2/H2S in the presence of H2, is a formidable task for a sensor designer. In order to ensure effective operation of these chemical sensors, the sensor system must inexpensively function within harsh temperature and chemical environment. Currently available sensing approaches, which are based on gas chromatography, electrochemistry, and IR-spectroscopy, do not satisfy the required cost and performance targets. This work focused on the development microsensors that can be applied to this application. In order to develop the high- temperature compatible microsensor, this work addressed various issues related to sensor stability, selectivity, and miniaturization. In the research project entitled High-Temperature Nano-Derived Micro-H2 and -H2S Sensors, the team worked to develop micro-scale, chemical sensors and sensor arrays composed of nano-derived, metal-oxide composite materials to detect gases like H2, SO2, and H2S within high-temperature environments (>500?C). The research was completed in collaboration with NexTech Materials, Ltd. (Lewis Center, Ohio). NexTech assisted in the testing of the sensors in syngas with contaminate levels of H2S. The idea of including nanomaterials as the sensing material within resistive-type chemical sensor platforms was to increase the sensitivity (as shown for room temperature applications). Unfortunately, nanomaterials are not stable at high temperatures due to sintering and coarsening processes that are driven by their high surface to volume ratio. Therefore, new hydrogen and sulfur selective nanomaterial systems with high selectivity and stability properties in the proposed harsh environment were investigated. Different nano-morphologies of zirconate, molybdate, and tungstate compounds were investigated. The fabrication of the microsensors consisted of the deposition of the selective nanomaterial systems over metal based interconnects on an inert substrate. This work utilized the chemi-resistive (resistive- type) microsensor architecture where the chemically and structurally stable, high temperature compatible electrodes were sputtered onto a ceramic substrate. The nanomaterial sensing systems were deposited over the electrodes using a lost mold method patterned by conventional optical lithography. The microsensor configuration with optimized nanomaterial system was tested and compared to a millimeter-size sensor e outcomes of this research will contribute to the economical application of sensor arrays for simultaneous sensing of H2, H2S, and SO2.

Perepezko, John; Lu-Steffes, Otto

2014-08-31T23:59:59.000Z

10

Alkaline Biofiltration of H2S Odors A R M A N D O G O N Z A L E Z -S A N C H E Z , ,  

E-Print Network [OSTI]

, such as elemental sulfur and sulfate (eqs 2, 3) depending on the availability of dissolved oxygen. The pH in H2S relevant to H2S gas treatment, since the amount of H2S that can be absorbed in a scrubbing liquid increases). Therefore, the saturation solubility of H2S in aqueous solution at pH

11

Angular dependence of dissociative electron attachment topolyatomic molecules: application to the 2B1 metastable state of the H2Oand H2S anions  

SciTech Connect (OSTI)

The angular dependence of dissociative electron attachment (DEA) to polyatomic targets is formulated in the local complex potential model, under the assumption that the axial recoil approximation describes the dissociation dynamics. An additional approximation, which is found to be valid in the case of H2O but not in the case of H2S, makes it possible to describe the angular dependence of DEA solely from an analysis of the fixed-nuclei entrance amplitude, without carrying out nuclear dynamics calculations. For H2S, the final-vibrational-state-specific angular dependence of DEA is obtained by incorporating the variation of the angular dependence of the entrance amplitude with nuclear geometry into the nuclear dynamics. Scattering calculations using the complex Kohn method and, for H2S, full quantum calculations of the nuclear dynamics using the Multi-Configuration Time-Dependent Hartree method, are performed.

Haxton, Daniel J.; McCurdy, C. William; Rescigno, Thomas N.

2006-01-12T23:59:59.000Z

12

N=2 superconformal nets  

E-Print Network [OSTI]

We provide an Operator Algebraic approach to N=2 chiral Conformal Field Theory and set up the Noncommutative Geometric framework. Compared to the N=1 case, the structure here is much richer. There are naturally associated nets of spectral triples and the JLO cocycles separate the Ramond sectors. We construct the N=2 superconformal nets of von Neumann algebras in general, classify them in the discrete series cnets with cnet representations.

Sebastiano Carpi; Robin Hillier; Yasuyuki Kawahigashi; Roberto Longo; Feng Xu

2014-11-21T23:59:59.000Z

13

M351 H2 (S. Zhang) 2.7,2.8,3.1 0. 2.7: 13-14, 21-25, 31, 33  

E-Print Network [OSTI]

M351 H2 (S. Zhang) 2.7,2.8,3.1 0. 2.7: 13-14, 21-25, 31, 33 1. (2.7:13) A thermometer is removed degrees. After one-half minute the thermometer reads 50 degrees. What is the reading of the thermometer

Zhang, Shangyou

14

Hg System Assembly and Testing Status  

E-Print Network [OSTI]

#12;2VRVS Meeting 8 Nov 2006 OAK RIDGE NATIONAL LABORATORY U. S. DEPARTMENT OF ENERGY Hg Drain & Spill Ports Completed Hg drain from cylinder Hg leak sump with float switch Hg spill extraction port #12;3VRVS Meeting 8 Nov 2006 OAK RIDGE NATIONAL LABORATORY U. S. DEPARTMENT OF ENERGY Local Hg Vapor Filters · Hg

McDonald, Kirk

15

Hg supply piping simulation Stony Brook University  

E-Print Network [OSTI]

Hg supply piping simulation (No MHD) Stony Brook University Yan Zhan Prof. Foluso Ladeinde July 2nd, 2010 #12;Outline · Hg supply piping in Muon Collider · Turbulence models for bend pipe flow · Problems need studying · Arrangements in the near future #12;Outline · Hg supply piping in Muon Collider ­ Hg

McDonald, Kirk

16

Hg Delivery System Vacuum 25 Oct 2005  

E-Print Network [OSTI]

. S. DEPARTMENT OF ENERGY V. Graves 25 Oct 2005 MERIT Mtg at MIT Oct 17-19 · During Hg delivery system to both design and operations #12;3 OAK RIDGE NATIONAL LABORATORY U. S. DEPARTMENT OF ENERGY V. Graves 25 & return lines - Sump tank & all connecting ports - Hg cylinder & bellows Hg inlet Hg cylinder & Bellows

McDonald, Kirk

17

Characterization of BCl3/N-2 plasmas  

E-Print Network [OSTI]

Optical emission spectroscopy, quadrupole mass spectrometry, and electron density measurements were used to study the effect of the percentage of N-2 on the characteristics of BCl3/N-2 plasmas and their resulting etch ...

Sia, S. F.

2003-08-15T23:59:59.000Z

18

MERIT Hg System Design Update  

E-Print Network [OSTI]

tank · Multiple Hg cylinder ports #12;4 OAK RIDGE NATIONAL LABORATORY U. S. DEPARTMENT OF ENERGY MERIT Princeton University Nov 17-18, 2005 #12;2 OAK RIDGE NATIONAL LABORATORY U. S. DEPARTMENT OF ENERGY MERIT distortion #12;3 OAK RIDGE NATIONAL LABORATORY U. S. DEPARTMENT OF ENERGY MERIT Collab. Mtg Nov 17-18, 2005

McDonald, Kirk

19

Supersymmetry and {sup 198}Hg  

SciTech Connect (OSTI)

The energy spectrum and electromagnetic transition properties of the supermultiplet members with two proton fermions can be constructed using the dynamical U{sub v}(6/12) x U{sub {pi}}(6/4) extended supersymmetry. In order to investigate predictions of the two proton fermion--four neutron boson supermultiplet member {sup 198}Hg, an experiment with the HORUS cube {gamma}-ray spectrometer at the Cologne TANDEM accelerator was performed using the {sup 196}Pt({alpha},2n){sup 198}Hg reaction. By analyzing {gamma}{gamma} coincidence spectra and {gamma}{gamma} angular correlations, the required experimental data--level and decay energies, level spins and multipole mixing ratios--could be obtained. For the low-energy states, the experimental data show good agreement with theory.

Bernards, Christian; Heinze, Stefan; Jolie, Jan; Fransen, Christoph; Linnemann, Andreas; Radeck, Desiree [Institut fuer Kernphysik, Universitaet zu Koeln, Zuelpicher Strasse 77, 50937 Koeln (Germany)

2009-01-28T23:59:59.000Z

20

MERIT Hg System Final Design Review  

E-Print Network [OSTI]

MERIT Hg System Final Design Review Hg Target System Operations V.B. Graves P.T. Spampinato T Facility Constraints · No overhead lifting capability within tunnel · Modularity required - Component 2 (In- beam) · Baseplate & magnet will go in beam line prior to Hg system · Blocks under magnet end

McDonald, Kirk

Note: This page contains sample records for the topic "n2 h2s hg" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

N=2 supersymmetric Pais-Uhlenbeck oscillator  

E-Print Network [OSTI]

We construct an N=2 supersymmetric extension of the Pais-Uhlenbeck oscillator for distinct frequencies of oscillation. A link to a set of decoupled N=2 supersymmetric harmonic oscillators with alternating sign in the Hamiltonian is introduced. Symmetries of the model are discussed in detail. The investigation of a quantum counterpart of the constructed model shows that the corresponding Fock space contains negative norm states and the energy spectrum of the system is unbounded from below.

Ivan Masterov

2015-03-12T23:59:59.000Z

22

Target System Operations and Hg Handling  

E-Print Network [OSTI]

CERN June 19-20, 2006 #12;2 OAK RIDGE NATIONAL LABORATORY U. S. DEPARTMENT OF ENERGY Hg System Safety RIDGE NATIONAL LABORATORY U. S. DEPARTMENT OF ENERGY Hg System Safety Review 19-20 June 2006 Containment/vent ports will be soap- bubble checked Primary Enclosure Secondary Enclosure #12;4 OAK RIDGE NATIONAL

McDonald, Kirk

23

The ${\\mathcal N}=2$ superconformal bootstrap  

E-Print Network [OSTI]

In this work we initiate the conformal bootstrap program for ${\\mathcal N}=2$ superconformal field theories in four dimensions. We promote an abstract operator-algebraic viewpoint in order to unify the description of Lagrangian and non-Lagrangian theories, and formulate various conjectures concerning the landscape of theories. We analyze in detail the four-point functions of flavor symmetry current multiplets and of ${\\mathcal N}=2$ chiral operators. For both correlation functions we review the solution of the superconformal Ward identities and describe their superconformal block decompositions. This provides the foundation for an extensive numerical analysis discussed in the second half of the paper. We find a large number of constraints for operator dimensions, OPE coefficients, and central charges that must hold for any ${\\mathcal N}=2$ superconformal field theory.

Christopher Beem; Madalena Lemos; Pedro Liendo; Leonardo Rastelli; Balt C. van Rees

2014-12-23T23:59:59.000Z

24

Critical phenomena in N=2* plasma  

E-Print Network [OSTI]

We use gauge theory/string theory correspondence to study finite temperature critical behaviour of mass deformed N=4 SU(N) supersymmetric Yang-Mills theory at strong coupling, also known as N=2* gauge theory. For certain range of the mass parameters, N=2* plasma undergoes a second-order phase transition. We compute all the static critical exponents of the model and demonstrate that the transition is of the mean-field theory type. We show that the dynamical critical exponent of the model is z=0, with multiple hydrodynamic relaxation rates at criticality. We point out that the dynamical critical phenomena in N=2* plasma is outside the dynamical universality classes established by Hohenberg and Halperin.

A. Buchel; C. Pagnutti

2010-10-16T23:59:59.000Z

25

CERN Hg Jet System V.B. Graves  

E-Print Network [OSTI]

Collaboration Mtg 16 Feb 05 Alternative Hg Delivery System Hydraulic Fluid Cylinder (3000 psi) Hg Cylinder (1000 energy performed on piston = press*area*dist/time 11 Hyd Pump pump inefficiency 8 11 340 340 6 8 Piston Sized for 20sec jet Drain Hg Supply Hg Return Position Sensor Hydraulic Lines Hg Cylinder Vent Line #12

McDonald, Kirk

26

Fusion rules for N=2 superconformal modules  

E-Print Network [OSTI]

In this note we calculate the fusion coefficients for minimal series representations of the N=2 superconformal algebra by using a modified Verlinde's formula, and obtain associative and commutative fusion algebras with non-negative integral fusion coefficients at each level. Some references are added.

Minoru Wakimoto

1998-07-22T23:59:59.000Z

27

High Power Hg Target Conceptual Design Review  

E-Print Network [OSTI]

to Hg Hg Temp Rise Input Energy (hp) Losses Lost Energy (hp) Output Energy (hp) BTU/min BTU/min BTU/min BTU/ min KW HP BTU/min F/sec Elect Motor 60 60 hp * 5% inefficiency 3 57 127 127 2 3 Mag Coupling 5 Energy (hp) BTU/min BTU/min BTU/min BTU/ min KW HP BTU/min F/sec Elect Motor 60 60 hp * 5% inef

McDonald, Kirk

28

Bulk viscosity of N=2* plasma  

E-Print Network [OSTI]

We use gauge theory/string theory correspondence to study the bulk viscosity of strongly coupled, mass deformed SU(N_c) N=4 supersymmetric Yang-Mills plasma, also known as N=2^* gauge theory. For a wide range of masses we confirm the bulk viscosity bound proposed in arXiv:0708.3459. For a certain choice of masses, the theory undergoes a phase transition with divergent specific heat c_V ~ |1-T_c/T|^(-1/2). We show that, although bulk viscosity rapidly grows as T -> T_c, it remains finite in the vicinity of the critical point.

Alex Buchel; Chris Pagnutti

2009-03-02T23:59:59.000Z

29

HgTe-low-field Strained HgTe: a textbook 3D topological insulator  

E-Print Network [OSTI]

HgTe-low-field Strained HgTe: a textbook 3D topological insulator Clement Bouvier, Tristan Meunier martyrs 38054 Grenoble Cedex 9, France (Dated: December 9, 2011) Topological insulators can be seen-conductors and topological- insulators, other contributions make transport data more difficult to unravel. This letter

Paris-Sud XI, Universit de

30

2, 779827, 2005 Inventories of N2O  

E-Print Network [OSTI]

BGD 2, 779­827, 2005 Inventories of N2O and NO emissions from European forest soils M. Kesik et al Biogeosciences Discussions is the access reviewed discussion forum of Biogeosciences Inventories of N2O Inventories of N2O and NO emissions from European forest soils M. Kesik et al. Title Page Abstract

Paris-Sud XI, Université de

31

Mechanism of terahertz photoconductivity in semimetallic HgTe/CdHgTe quantum wells  

SciTech Connect (OSTI)

Terahertz photoconductivity in magnetic fields in semimetallic HgTe/CdHgTe quantum wells has been studied. The main contribution to photoconductivity comes from a signal that appears as a result of electron-gas heating. It is shown that, with the cyclotron resonance conditions satisfied, the photoconductivity signal is composed of cyclotron-resonance and bolometric components. However, in this case too, the bolometric contribution predominates.

Vasilyev, Yu. B., E-mail: yu.vasilyev@mail.ioffe.ru [Russian Academy of Sciences, Ioffe Physical-Technical Institute (Russian Federation); Mikhailov, N. N. [Russian Academy of Sciences, Rzhanov Institute of Semiconductor Physics, Siberian Branch (Russian Federation); Gouider, F. [Institut fuer Angewandte Physik (Germany); Vasilyeva, G. Yu. [St. Petersburg State Polytechnic University (Russian Federation); Nachtwei, G. [Institut fuer Angewandte Physik (Germany)

2012-05-15T23:59:59.000Z

32

13286 J. Phys. Chem. 1994,98, 13286-13293 Kinetics of Ti(a3F,a5F)and V(a4F,a6D)Depletion by NH3 and H2S  

E-Print Network [OSTI]

) and V(a6D) upon interactions with NH3 and HzS are studied in a fast-flow reactor at a He pressure of 0) x Introduction Information about the gas-phase kinetics for the reactions of simple molecules studied the activation of NH3 and H2S by neutral titanium and vanadium atoms. In addition to the gas

Clemmer, David E.

33

Dipole Bands in {sup 196}Hg  

SciTech Connect (OSTI)

High spin states in {sup 196}Hg have been populated in the {sup 198}Pt({alpha},6n) reaction at 65 MeV and the level scheme has been extended. A new dipole band has been observed and a previously observed dipole has been confirmed. Excitation energies, spins and parities of these bands were determined from DCO ratio and linear polarization measurements. Possible quasiparticle excitations responsible for these structures are discussed.

Lawrie, J. J.; Lawrie, E. A.; Newman, R. T.; Sharpey-Schafer, J. F.; Smit, F. D. [iThemba LABS, PO Box 722, Somerset West 7129 (South Africa); Msezane, B. [iThemba LABS, PO Box 722, Somerset West 7129 (South Africa); Physics Department, University of Zululand, Private Bag X1001, Kwadlangezwa 3886 (South Africa); Benatar, M.; Mabala, G. K.; Mutshena, K. P. [iThemba LABS, PO Box 722, Somerset West 7129 (South Africa); Physics Department, University of Cape Town, Rondebosch 7700 (South Africa); Federke, M.; Mullins, S. M. [Physics Department, University of Cape Town, Rondebosch 7700 (South Africa); Ncapayi, N. J.; Vymers, P. [iThemba LABS, PO Box 722, Somerset West 7129 (South Africa); Physics Department, University of the Western Cape, Private Bag X17, Belleville 7535 (South Africa)

2011-10-28T23:59:59.000Z

34

Lean NOx Trap Regeneration Selectivity Towards N2O -- Similarities...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

exhaust temperatures, N2O is emitted in two peaks. This presentation uses a global model for the primary and secondary peaks to explain the chemical reactions....

35

Process of [sup 196]Hg enrichment  

DOE Patents [OSTI]

A simple rate equation model shows that by increasing the length of the photochemical reactor and/or by increasing the photon intensity in said reactor, the feedstock utilization of [sup 196]Hg will be increased. Two preferred embodiments of the present invention are described, namely (1) long reactors using long photochemical lamps and vapor filters; and (2) quartz reactors with external UV reflecting films. These embodiments have each been constructed and operated, demonstrating the enhanced utilization process dictated by the mathematical model (also provided).

Grossman, M.W.; Mellor, C.E.

1993-04-27T23:59:59.000Z

36

Unexpected Nondissociative Binding of N2O on Oxygen Vacancies...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Nondissociative Binding of N2O on Oxygen Vacancies on a Rutile TiO2(110)-11 . Unexpected Nondissociative Binding of N2O on Oxygen Vacancies on a Rutile TiO2(110)-11 ....

37

U01HG004279 (D.M.M.), U01HG004261 (E.L.), U01HG004274 (S.H.), and U41HG004269 (L.S.). Awards  

E-Print Network [OSTI]

.T.N.), the Indiana Genomics Initiative (T.C.K.), H. Smith and the NIDDK genomics core laboratory (B.O.), NIH R01HG

38

Hg L3 XANES Study of Mercury Methylation in Shredded  

E-Print Network [OSTI]

,indicatingbioaccumulationofmercury.Plantsamples collected at this site were also grown in nutrient solution with 1 ppm HgCl2 under (1) aerobic conditions

39

N=2 superconformal symmetry in super coset models  

SciTech Connect (OSTI)

We extend the Kazama-Suzuki construction of models with N=(2,2) world-sheet supersymmetry to cosets S/K of supergroups. Among the admissible target spaces that allow for an extension to N=2 superconformal algebras are some simple Lie supergroups, including PSL(N|N). Our general analysis is illustrated at the example of the N=1 Wess-Zumino-Novikov-Witten model on GL(1|1). After constructing its N=2 superconformal algebra we determine the (anti-)chiral ring of the theory. It exhibits an interesting interplay between world-sheet and target space supersymmetry.

Creutzig, Thomas; Roenne, Peter B.; Schomerus, Volker [DESY Theory Group, DESY Hamburg, Notkestrasse 85, D-22603 Hamburg (Germany)

2009-09-15T23:59:59.000Z

40

Growth of superconducting Hg-1212 very-thin films  

E-Print Network [OSTI]

High quality epitaxial HgBa2CaCu2O6+delta (Hg- High 1212) films with thickness less than 100 nm have been successfully synthesized using cation-exchange process. The films show the superconducting transition up to similar to 118 K which is close...

Wu, Judy; Xie, Y. Y.; Kang, B. W.; Gapud, A. A.; Aytug, T.; Fang, L.

1999-06-01T23:59:59.000Z

Note: This page contains sample records for the topic "n2 h2s hg" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

The helium abundances in HgMn and normal stars  

E-Print Network [OSTI]

The parameter-free model of diffusion in the atmospheres of HgMn stars (Michaud 1986; Michaud et al 1979) predicts that helium should sink below the He II ionization zone in order that diffusion of other elements may take place, and that all HgMn stars should have deficits of helium in their photospheres, with a minimum deficit of 0.3 dex. In this study, the Smith & Dworetsky (1993) sample of HgMn stars and normal comparison stars is examined, and the helium abundances determined by spectrum synthesis using echelle spectra taken at Lick Observatory and the AAT. The prediction is confirmed; all HgMn stars are deficient in He by as much as 1.5 dex. Also, two HgMn stars, HR7361 and HR7664, show clear evidence of helium stratification.

M. M. Dworetsky

2004-07-26T23:59:59.000Z

42

Paleomagnetic Secular Variation (PSV), 137Cs, and Hg dating techniques  

E-Print Network [OSTI]

Portland State University Department of Geology #12;Hg-Mercury contamination dating http fission of Uranium-235 · Due to nuclear weapons testing · Highly water soluble (spreads quickly) · Half

Fountain, Andrew G.

43

Unique Thylakoid Membrane Architecture of aUnicellular N2-Fixing...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Unique Thylakoid Membrane Architecture of aUnicellular N2-Fixing Cyanobacterium Revealedby Electron Tomography. Unique Thylakoid Membrane Architecture of aUnicellular N2-Fixing...

44

Nonlocality from N>2 independent single-photon emitters  

SciTech Connect (OSTI)

We demonstrate that intensity correlations of second order in the fluorescence light of N>2 single-photon emitters may violate locality while the visibility of the signal remains below 1/{radical}(2){approx_equal}71%. For this, we derive a homogeneous Bell-Wigner-type inequality, which can be applied to a broad class of experimental setups. We trace the violation of this inequality back to path entanglement created by the process of detection.

Thiel, C.; Wiegner, R.; Zanthier, J. von [Institut fuer Optik, Information und Photonik, Universitaet Erlangen-Nuernberg, D-91058 Erlangen (Germany); Agarwal, G. S. [Department of Physics, Oklahoma State University, Stillwater, Oklahoma 74078-3072 (United States)

2010-09-15T23:59:59.000Z

45

Photodesorption of ices I: CO, N2 and CO2  

E-Print Network [OSTI]

A longstanding problem in astrochemistry is how molecules can be maintained in the gas phase in dense inter- and circumstellar regions. Photodesorption is a non-thermal desorption mechanism, which may explain the small amounts of observed cold gas in cloud cores and disk mid-planes. This paper aims to determine the UV photodesorption yields and to constrain the photodesorption mechanisms of three astrochemically relevant ices: CO, N2 and CO2. In addition, the possibility of co-desorption in mixed and layered CO:N2 ices is explored. The ice photodesorption is studied experimentally under ultra high vacuum conditions and at 15-60 K using a hydrogen discharge lamp (7-10.5 eV). The ice desorption during irradiation is monitored by reflection absorption infrared spectroscopy of the ice and simultaneous mass spectrometry of the desorbed molecules. Both the UV photodesorption yields per incident photon and the photodesorption mechanisms are molecule specific. CO photodesorbs without dissociation from the surface layer of the ice. N2, which lacks an electronic transition in this wavelength range, has a photodesorption yield that is more than an order of magnitude lower. This yield increases significantly due to co-desorption when N2 is mixed in with or layered on top of CO ice. CO2 photodesorbs through dissociation and subsequent recombination from the top 10 layers of the ice. At low temperatures (15-18 K) the derived photodesorption yields are 2.7x10^-3 and CO2 photodesorption yield is 1.2x10^-3x(1-e^(-X/2.9)) + 1.1x10^-3x(1-e^(-X/4.6)) molecules photon-1, where X is the ice thickness in monolayers and the two parts of the expression represent a CO2 and CO photodesorption pathway.

Karin I. Oberg; Ewine F. van Dishoeck; Harold Linnartz

2009-01-23T23:59:59.000Z

46

Mercury nonstoichiometry of the Hg1-xBa2CuO4+ superconductor and the P(Hg)-P(O2)-T phase diagram of the Hg-Ba-Cu-O system.  

E-Print Network [OSTI]

1 Mercury nonstoichiometry of the Hg1-xBa2CuO4+ superconductor and the P(Hg)-P(O2)-T phase diagram-nonstoichiometry and exists in a certain P(Hg), P(O2) and T range. Mercury nonstoichiometry of Hg-1201 was investigated in the 923 T 1095 K; 2.0 P(Hg) 8.4 atm; 0.09 P(O2) 0.86 atm ranges. It was found that the mercury

Rudnyi, Evgenii B.

47

Active transport, substrate specificity, and methylation of Hg(II) in anaerobic bacteria  

SciTech Connect (OSTI)

The formation of methylmercury (MeHg), which is biomagnified in aquatic food chains and poses a risk to human health, is effected by some iron- and sulfate-reducing bacteria (FeRB and SRB) in anaerobic environments. However, very little is known regarding the mechanism of uptake of inorganic Hg by these organisms, in part because of the inherent difficulty in measuring the intracellular Hg concentration. By using the FeRB Geobacter sulfurreducens and the SRB Desulfovibrio desulfuricans ND132 as model organisms, we demonstrate that Hg(II) uptake occurs by active transport. We also establish that Hg(II) uptake by G. sulfurreducens is highly dependent on the characteristics of the thiols that bind Hg(II) in the external medium, with some thiols promoting uptake and methylation and others inhibiting both. The Hg(II) uptake system of D. desulfuricans has a higher affinity than that of G. sulfurreducens and promotes Hg methylation in the presence of stronger complexing thiols. We observed a tight coupling between Hg methylation and MeHg export from the cell, suggesting that these two processes may serve to avoid the build up and toxicity of cellular Hg. Our results bring up the question of whether cellular Hg uptake is specific for Hg(II) or accidental, occurring via some essential metal importer. Our data also point at Hg(II) complexation by thiols as an important factor controlling Hg methylation in anaerobic environments.

Schasfer, Jeffra [Princeton University; Rocks, Sara [Princeton University; Zheng, Wang [ORNL; Liang, Liyuan [ORNL; Gu, Baohua [ORNL; Morel, Francois M [ORNL

2011-01-01T23:59:59.000Z

48

Energy loss rate of a charged particle in HgTe/(HgTe, CdTe) quantum wells  

SciTech Connect (OSTI)

The energy loss rate (ELR) of a charged particle in a HgTe/(HgTe, CdTe) quantum well is investigated. We consider scattering of a charged particle by the bulk insulating states in this type of topological insulator. It is found that the ELR characteristics due to the intraband excitation have a linear energy dependence while those due to interband excitation depend on the energy exponentially. An interesting quantitative result is that for a large range of the incident energy, the mean inelastic scattering rate is around a few terahertz.

Chen, Qinjun; Sin Ang, Yee [School of Physics, University of Wollongong, New South Wales 2522 (Australia)] [School of Physics, University of Wollongong, New South Wales 2522 (Australia); Wang, Xiaolin [Institute for Superconducting and Electronic Materials, University of Wollongong, New South Wales 2522 (Australia)] [Institute for Superconducting and Electronic Materials, University of Wollongong, New South Wales 2522 (Australia); Lewis, R. A.; Zhang, Chao [School of Physics, University of Wollongong, New South Wales 2522 (Australia) [School of Physics, University of Wollongong, New South Wales 2522 (Australia); Institute for Superconducting and Electronic Materials, University of Wollongong, New South Wales 2522 (Australia)

2013-11-04T23:59:59.000Z

49

MERIT Hg System Design V.B. Graves  

E-Print Network [OSTI]

testing · The pump equipment operates in a range of 6000 Gauss to 300 Gauss (1 Tesla = 104 Gauss) Target system must deliver a stable, unconstrained jet of Hg into a 15 Tesla field #12;4 OAK RIDGE NATIONAL · Hydraulic pump (outside secondary containment) - Pump, motor, reservoir - Proportional, directional control

McDonald, Kirk

50

Mother-embryo isotope (15 C) fractionation and mercury (Hg)  

E-Print Network [OSTI]

used to investigate the trophic ecology, foraging habitats and heavy metal contamination). Consequently, Hg concentrations are important to monitor because of the toxicity of this metal. In order of this element in muscle and liver. Key words: sharks; stable isotopes; trace metal; maternal influence. hal

Paris-Sud XI, Université de

51

The new Hg-rich barium indium mercurides BaIn{sub x}Hg{sub 7?x} (x=3.1) and BaIn{sub x}Hg{sub 11?x} (x=02.8)  

SciTech Connect (OSTI)

The title compounds BaIn{sub x}Hg{sub 7?x} (x=3.1(1)) and BaIn{sub x}Hg{sub 11?x} (x=02.8) were synthesized from stoichiometric ratios of the elements in Ta crucibles. Their crystal structures have been determined using single crystal X-ray data. BaIn{sub x}Hg{sub 7?x} (x=3.1(1)) crystallizes in a new structure type (orthorhombic, oC16, space group Cmmm: a=512.02(1), b=1227.68(3), c=668.61(2) pm, Z=2, R1=0.0311). In the structure, the atoms of the three crystallographically different mixed In/Hg positions form planar nets of four-, six- and eight-membered rings. These nets are shifted against each other such that the four-membered rings form empty distorted cubes. The cubes are connected via common edges, corners and folded ladders, which are also found in BaIn{sub 2}/BaHg{sub 2} (KHg{sub 2} structure type) and BaIn (?-NaHg type). The Ba atoms are centered in the eight-membered rings and exhibit an overall coordination number of 20. The [BaM{sub 20}] polyhedra and twice as many distorted [M{sub 8}] cubes tesselate the space. BaIn{sub 2.8}Hg{sub 8.2} (cubic, cP36, space group Pm3{sup }m, a=961.83(1) pm, Z=3, R1=0.0243) is the border compound of the phase width BaIn{sub x}Hg{sub 11?x} of the rare BaHg{sub 11} structure type. In the structure, ideal [M{sub 8}] cubes (at the corners of the unit cell) and BaM{sub 20} polyhedra (at the edges of the unit cell) represent the building blocks comparable to the other new In mercuride. In accordance with the increased In/Hg content, additional M-pure regions appear: the center of the unit cell contains a huge [Hg(1)M(2){sub 12}M(3,4){sub 32}] polyhedron, a Hg-centered cuboctahedron of In/Hg atoms surrounded by a capped cantellated cube of 32 additional M atoms. For both structure types, the bonding situation and the coloring, i.e. the In/Hg distribution of the polyanionic network, are discussed considering the different sizes of the atoms and the charge distribution (Bader AIM charges), which have been calculated within the framework of FP-LAPW density functional theory. - Graphical abstract: BaIn{sub 2.6}Hg{sub 4.4}: distorted cubes [(In/Hg){sub 8}] (green, like in BaHg{sub 11}), folded ladders (violet, like in BaIn, BaHg{sub 2} and BaIn{sub 2}) and Ba coordination polyhedra [Ba(In/Hg){sub 20}] (blue, like in BaHg{sub 11}). - Highlights: The Hg-rich In-mercuride BaIn{sub 3.1}Hg{sub 3.9} crystallizes with a singular structure type. The phase width of the BaHg{sub 11} structure in BaIn{sub x}Hg{sub 11-x} ends at x=2.8. The relations of both compounds with other alkaline-earth mercurides are outlined. The Hg/In coloring of the polyanion is discussed considering the structure features. Bonding aspects are explored using band structure calculations.

Wendorff, Marco; Schwarz, Michael; Rhr, Caroline, E-mail: caroline@ruby.chemie.uni-freiburg.de

2013-07-15T23:59:59.000Z

52

Understanding mercury demethylation is the key to decrease the high environmental levels of the neurotoxin methyl-Hg in lakes.  

E-Print Network [OSTI]

dynamics of MeHg is the net result of three major processes: 1) formation by Hg methylation 2) degradation (demethylation) and Hg2+ reduction to Hg0 and evasion to the atmosphere. The major process of MeHg degradation is driven by UV light in surface waters. Although biotic demethylation processes are less well understood

Uppsala Universitet

53

Neutrino parameters and the $N_2$-dominated scenario of leptogenesis  

E-Print Network [OSTI]

We briefly review the main aspects of leptogenesis, describing both the unflavoured and the flavoured versions of the $N_2$-dominated scenario. A study of the success rates of both classes of models has been carried out. We comment on these results and discuss corrective effects to this simplest scenario. Focusing on the flavoured case, we consider the conditions required by strong thermal leptogenesis, where the final asymmetry is fully independent of the initial conditions. Barring strong cancellations in the seesaw formula and in the flavoured decay parameters, we show that strong thermal leptogenesis favours a lightest neutrino mass $m_1\\gtrsim10\\,\\mbox{meV}$ for normal ordering (NO) and $m_1\\gtrsim 3\\,\\mbox{meV}$ for inverted ordering (IO). Finally, we briefly comment on the power of absolute neutrino mass scale experiments to either support or severely corner strong thermal leptogenesis.

Michele Re Fiorentin; Sophie E. King

2014-05-09T23:59:59.000Z

54

Coadsorption of sulfate/bisulfate anions with Hg cations during Hg underpotential deposition on Au(111): An in situ x-ray diffraction study  

SciTech Connect (OSTI)

The first stage of mercury underpotential deposition on Au(111) electrodes in 0.10 M H{sub 2}SO{sub 4} containing 1.0 mM Hg{sup 2+} has been studied by synchrotron X-ray scattering techniques including grazing incidence X-ray diffraction and specular crystal truncation rod measurements. An ordered coadsorbed structure of sulfate/bisulfate anions and Hg cations was found at potentials between the first and second Hg UPD peaks (+0.80 V > E > +0.88 V vs Ag/AgCl(3 M KCl)). The coadsorption structure was found to consist of a compressed Hg honeycomb lattice with the honeycomb centers occupied by sulfate or bisulfate anions. The compression of the lattice is likely due to the formation of mercurous (Hg{sub 2}{sup 2+}) ions which have a much shorter Hg-Hg distance than that in frozen bulk Hg crystals. The net charge transferred under the first Hg UPD peak suggests that the chemical state of the species in the coadsorbed structure is likely Hg{sub 2}SO{sub 4}. Our results indicate that both the chemical state of the mercury cations and the nature of the anions are important in the resulting electrodeposited structures. 38 refs., 8 figs., 1 tab.

Li, J.; Abruna, H.D. [Cornell Univ., Ithaca, NY (United States)] [Cornell Univ., Ithaca, NY (United States)

1997-01-09T23:59:59.000Z

55

Photoinduced Oxidation of Hg0 in the Waters from the St.  

E-Print Network [OSTI]

-A induced reactions. Doubling UV irradiation did not increase the reaction rate of Hg0 photooxidation food chain. Understanding the parameters that govern Hg0 oxidation is therefore crucial to assess

Morel, François M. M.

56

On-line method of determining utilization factor in Hg-196 photochemical separation process  

DOE Patents [OSTI]

The present invention is directed to a method for determining the utilization factor [U] in a photochemical mercury enrichment process (.sup.196 Hg) by measuring relative .sup.196 Hg densities using absorption spectroscopy.

Grossman, Mark W. (Belmont, MA); Moskowitz, Philip E. (Peabody, MA)

1992-01-01T23:59:59.000Z

57

A Hydrogen-Evolving Ni(P2N2)2 Electrocatalyst Covalently Attached...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

A Hydrogen-Evolving Ni(P2N2)2 Electrocatalyst Covalently Attached to a Glassy Carbon Electrode: Preparation, Characterization, A Hydrogen-Evolving Ni(P2N2)2 Electrocatalyst...

58

Anthropogenic and Natural Emissions of Mercury (Hg) in the northeastern United Jeffrey MacAdam Sigler  

E-Print Network [OSTI]

Abstract Anthropogenic and Natural Emissions of Mercury (Hg) in the northeastern United States impact may depend on the emission rate. Anthropogenic Hg emissions in the United States are poorly characterized. Natural Hg emissions are poorly understood worldwide, due to lack of data or measurement systems

Lee, Xuhui

59

Offsetting the radiative benefit of ocean iron fertilization by enhancing N2O emissions  

E-Print Network [OSTI]

from the atmospheric CO2 reduction significantly, because N2O is a much more powerful greenhouse gas

Gruber, Nicolas

60

Global distribution of N2O emissions from aquatic systems: natural emissions and anthropogenic eects  

E-Print Network [OSTI]

Global distribution of N2O emissions from aquatic systems: natural emissions and anthropogenic, are increasing due to human activities. Our analysis suggests that a third of global anthropogenic N2O emission the remainder. Over 80% of aquatic anthropogenic N2O emissions are from the Northern Hemisphere mid

Seitzinger, Sybil

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61

N=2 cascade revisited and the enhancon bearings  

SciTech Connect (OSTI)

Supergravity backgrounds with varying fluxes generated by fractional branes at nonisolated Calabi-Yau singularities had escaped a precise dual field theory interpretation so far. In the present work, considering the prototypical example of such models, the CxC{sup 2}/Z{sub 2} orbifold, we propose a solution for this problem, and show that the known cascading solution corresponds to a vacuum on the Coulomb branch of the corresponding quiver gauge theory involving a sequence of strong coupling transitions reminiscent of the baryonic root of N=2 supersymmetric quantum chromodynamics . We also find a slight modification of this cascading vacuum which upon mass deformation is expected to flow to the Klebanov-Strassler cascade. Finally, we discuss an infinite class of vacua on the Coulomb branch whose renormalization group flows include infinitely coupled conformal regimes, and explain their gravitational manifestation in terms of new geometric structures that we dub enhancon bearings. Repulson-free backgrounds dual to all the vacua we analyze are explicitly provided.

Benini, Francesco [Department of Physics, Princeton University, Princeton, New Jersey 08544 (United States); SISSA and INFN-Sezione di Trieste Via Beirut 2, I 34014 Trieste (Italy); Bertolini, Matteo [SISSA and INFN-Sezione di Trieste Via Beirut 2, I 34014 Trieste (Italy); Closset, Cyril [Physique Theorique et Mathematique and International Solvay Institutes, Universite Libre de Bruxelles, C.P. 231, 1050 Bruxelles (Belgium); Cremonesi, Stefano [SISSA and INFN-Sezione di Trieste Via Beirut 2, I 34014 Trieste (Italy); Raymond and Beverly Sackler Faculty of Exact Sciences, School of Physics and Astronomy, Tel-Aviv University, Ramat-Aviv 69978 (Israel)

2009-03-15T23:59:59.000Z

62

Crystal Growth And Characterization of the Model High-Temperature Superconductor HgBa{sub 2}CuO{sub 4+{delta}}  

SciTech Connect (OSTI)

Since the discovery of high-transition-temperature (T{sub c}) superconductivity in La{sub 2-x}Ba{sub x}CuO{sub 4} in 1986, the study of the lamellar copper oxides has remained at the forefront of condensed matter physics. Apart from their unusually high values of T{sub c}, these materials also exhibit a variety of complex phenomena and phases. This rich behavior is a consequence of the lamellar crystal structures, formed of copper-oxygen sheets separated by charge reservoir layers, and of the strong electron-electron correlations in the copper-oxygen sheets. After two decades of intensive research, which has stimulated many valuable new insights into correlated electron systems in general, there remains a lack of consensus regarding the correct theory for high-T{sub c} superconductivity. The ultimate technological goal of room-temperature superconductivity might only be attained after the development of a deeper understanding of the mercury-based compounds HgBa{sub 2}Ca{sub n-1}Cu{sub n}OI{sub 2n+2+{delta}}, which currently exhibit the highest T{sub c}values. One very important issue in this regard is the role of electronic versus chemical and structural inhomogeneities in these materials, and the associated need to separate material-specific properties from those that are essential to superconductivity. Unfortunately, there has been remarkably little scientific work on the mercury-based compounds because sizable crystals have not been available; quantitative measurements of any kind would be invaluable benchmarks for testing the theories of high-T{sub c} superconductivity. The compounds HgBa{sub 2}Ca{sub n-1}Cu{sub n}OI{sub 2n+2+{delta}} can be viewed as model systems not only because of their record high-T{sub c} values, but also because of their high-symmetry crystal structures. Of particular interest is the simplest member of this materials family, HgBa{sub 2}CuO{sub 4+{delta}} (Hg1201), which possesses only one copper-oxygen sheet per unit cell (n = 1), as shown schematically in Figure 1a. The largest crystals obtained by previous growth methods do not exceed 1 mm{sup 3}, and hence are insufficient in size for detailed studies by many experimental techniques. Here we report a novel recipe for the growth of Hg1201 crystals as well as detailed sample characterization results, including initial inelastic magnetic neutron scattering data. We note that samples grown by the method described here have already enabled recent optical conductivity, inelastic X-ray scattering, and angle-resolved photoemission studies.

Zhao, Xudong; Yu, Guichuan; Cho, Yong-Chan; Chabot-Couture, Guillaume; Barisic, Neven; Bourges, Philippe; Kaneko, Nobuhisa; Li, Yuan; Lu, Li; Motoyama, Eugene M.; Vajk,; Greven, Martin; /Stanford U., Appl. Phys. Dept. /SLAC, SSRL /Jilin U. /Stanford U., Phys. Dept. /Saclay /NIST, Wash., D.C.

2007-03-16T23:59:59.000Z

63

Structure and critical function of Fe and acid sites in Fe-ZSM-5 in propane oxidative dehydrogenation with N2O and N2O decomposition  

E-Print Network [OSTI]

Structure and critical function of Fe and acid sites in Fe-ZSM-5 in propane oxidative species Steamed Fe-zeolites Mössbauer spectroscopy UV­Vis FTIR H2-TPR N2O decomposition Propane oxidative of propane to propene with N2O. The evacuated non-steamed FeH-ZSM-5 contained high concentration of Brønsted

Sklenak, Stepan

64

The development of N2S2 metal complexes as bidentate ligands for organometallic chemistry  

E-Print Network [OSTI]

from CO addition to (NiN2S2)W(CO)4, which is in equilibrium with the resulting (NiN2S2)W(CO)5 species (Keq = 2.8 M-1, G = -1.4 kJ/mole at 50C). Complete NiN2S2 ligand displacement by CO-cleavage of the remaining W-S bond to form W(CO)6 was not observed...

Rampersad, Marilyn Vena

2007-04-25T23:59:59.000Z

65

Optical characteristics of a HgBr excilamp  

SciTech Connect (OSTI)

Optical characteristics of a coaxial HgBr excilamp on multicomponent mercury dibromide vapour mixtures with helium, nitrogen and sulfur hexafluoride are investigated under pumping by a pulse-periodic barrier discharge. Stable excilamp operation was demonstrated at a pump pulse repetition rate of 3 9 kHz. The component composition of the working system was determined, which provides a maximal average and pulsed specific radiation power of 48.8 mW cm{sup -3} and 40.6 W cm{sup -3}, respectively, at the efficiency of 7.3 % in the blue-green spectral range with the maximal radiation intensity at the wavelength of 502 nm. The reduction in the radiation power after 2.5 10{sup 6} shots is 5 %. Interpretation is given for the results of optimisation of excilamp characteristics. (optical radiation sources)

Malinina, A A; Malinin, A N; Shuaibov, A K [Uzhgorod National University, Uzhgorod (Ukraine)

2013-08-31T23:59:59.000Z

66

Raman excitation profiles for the (n1, n2) assignment in carbon nanotubes  

E-Print Network [OSTI]

Raman excitation profiles for the (n1, n2) assignment in carbon nanotubes H. Telg , J. Maultzsch indices n1 and n2 in semiconducting and metallic nanotubes was performed comparing resonance Raman nanotube families. Ever since the discovery of how to keep isolated nanotubes from rebundeling in solu

Nabben, Reinhard

67

Uncertainties Associated with Theoretically Calculated N2-Broadened Half-Widths of H2O Lines  

E-Print Network [OSTI]

to be calculated theoretically. The accuracy of these calculated values depends on many factors such as the line-shape1 Uncertainties Associated with Theoretically Calculated N2- Broadened Half-Widths of H2O Lines Q-offs used in the theoretical calculations, we have carried out extensive numerical calculations of the N2

Gamache, Robert R.

68

15N2 formation and fast oxygen isotope exchange during pulsed...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

N2 formation and fast oxygen isotope exchange during pulsed 15N18O exposure of MnOxCeO2. 15N2 formation and fast oxygen isotope exchange during pulsed 15N18O exposure of MnOx...

69

Siemens AG, CT IC 4, H.-G. Zimmermann1 CORPORATETECHNOLOGY  

E-Print Network [OSTI]

Siemens AG, CT IC 4, H.-G. Zimmermann1 CORPORATETECHNOLOGY System Identification & Forecasting with Advanced Neural Networks Principles, Techniques, Applications Hans Georg Zimmermann Siemens AG Email : Hans_Georg.Zimmermann@siemens.com Siemens AG, CT IC 4, H.-G. Zimmermann2 CORPORATETECHNOLOGY . . . . ! " i ii wxw 0 w1 wn xn x1 Distinct

Schmidhuber, Juergen

70

Frequency Ratio of ${}^{199}$Hg and ${}^{87}$Sr Optical Lattice Clocks beyond the SI Limit  

E-Print Network [OSTI]

We report on a frequency ratio measurement of a ${}^{199}$Hg-based optical lattice clock referencing a ${}^{87}$Sr-based clock. Evaluations of lattice light shift, including atomic-motion-dependent shift, enable us to achieve a total systematic uncertainty of $7.2 \\times 10^{-17}$ for the Hg clock. The frequency ratio is measured to be $\

Yamanaka, Kazuhiro; Ushijima, Ichiro; Takamoto, Masao; Katori, Hidetoshi

2015-01-01T23:59:59.000Z

71

SmartHG: Energy Demand Aware Open Services for Smart Grid Intelligent Automation  

E-Print Network [OSTI]

solar panels)], for each time slot (say each hour) the DNO price policy defines an interval of energySmartHG: Energy Demand Aware Open Services for Smart Grid Intelligent Automation Enrico Tronci.prodanovic,jorn.gruber, barry.hayes}@imdea.org I. INTRODUCTION The SmartHG project [1], [2] has the goal of developing

Tronci, Enrico

72

INELASTIC NEUTRON SCATTERING SELECTION RULES OF 03B1 HgI2 M. SIESKIND  

E-Print Network [OSTI]

899 INELASTIC NEUTRON SCATTERING SELECTION RULES OF 03B1 HgI2 M. SIESKIND Laboratoire de The inelastic neutron scattering selection rules of 03B1 HgI2 in the directions 0394, 03A3 and 039B are derived Abstracts 63.20D Introduction. - Inelastic neutron scattering is a powerful technique for the determination

Boyer, Edmond

73

Pb(II) and Hg(II) binding to $de$ $novo$ designed proteins studied by $^{204m}$Pb- and $^{199m}$Hg-Perturbed Angular Correlation of $\\gamma$-rays (PAC) spectroscopy Clues to heavy metal toxicity  

E-Print Network [OSTI]

Pb(II) and Hg(II) binding to $de$ $novo$ designed proteins studied by $^{204m}$Pb- and $^{199m}$Hg-Perturbed Angular Correlation of $\\gamma$-rays (PAC) spectroscopy

CERN. Geneva. ISOLDE and Neutron Time-of-Flight Experiments Committee; Correia, J G

2006-01-01T23:59:59.000Z

74

Angle-resolved photoemission spectroscopy study of HgBa[subscript 2]CuO[subscript 4+?  

E-Print Network [OSTI]

HgBa[subscript 2]CuO[subscript 4+?]. (Hg1201) has been shown to be a model cuprate for scattering, optical, and transport experiments, but angle-resolved photoemission spectroscopy (ARPES) data are still lacking owing to ...

Chan, M. K.

75

Atmospheric O2//N2 changes, 19932002: Implications for the partitioning of fossil fuel CO2 sequestration  

E-Print Network [OSTI]

Atmospheric O2//N2 changes, 1993­­2002: Implications for the partitioning of fossil fuel CO2. Cassar (2005), Atmospheric O2/N2 changes, 1993­2002: Implications for the partitioning of fossil fuel CO2. The O2/N2 ratio of air is falling because combustion of fossil fuel and biomass both con- sume O2

Ho, David

76

Relative importance of organic coatings for the heterogeneous hydrolysis of N2O5 during summer in Europe  

E-Print Network [OSTI]

coatings, formed via gas-to- particle conversion on aqueous aerosols, to N2O5 hydrolysis on localRelative importance of organic coatings for the heterogeneous hydrolysis of N2O5 during summer suppress heterogeneous N2O5 hydrolysis. In this study we investigated the relative importance of organic

Riemer, Nicole

77

Gauge/Gravity Duality, Green Functions of N=2 SYM and Radial/Energy-Scale Relation  

E-Print Network [OSTI]

We consider supergravity configuration of D5 branes wrapped on supersymmetric 2-cycles and use it to calculate one-point and two-point Green functions of some special operators in N=2 super Yang-Mills theory. We show that Green functions obtained from supergravity include two very different parts. One of them corresponds to perturbative results of quantum field theory, and another is a non-perturbative effect which corresponds to contribution from instantons with fractional charge. Comparing Green functions obtained from supergravity and gauge theory, we obtain radial/energy-scale relation for this gauge/gravity correspondence with N=2 supersymmetry. This relation leads right beta-function of N=2 SYM from supergravity configuration.

Xiao-Jun Wang; Seng Hu

2002-07-19T23:59:59.000Z

78

The new barium zinc mercurides Ba{sub 3}ZnHg{sub 10} and BaZn{sub 0.6}Hg{sub 3.4} - Synthesis, crystal and electronic structure  

SciTech Connect (OSTI)

The title compounds Ba{sub 3}ZnHg{sub 10} and BaZn{sub 0.6}Hg{sub 3.4} were synthesized from stoichiometric ratios of the elements in Ta crucibles. Their crystal structures, which both represent new structure types, have been determined using single crystal X-ray data. The structure of Ba{sub 3}ZnHg{sub 10} (orthorhombic, oP28, space group Pmmn, a=701.2(3), b=1706.9(8), c=627.3(3)pm, Z=2, R1=0.0657) contains folded 4{sup 4} Hg nets, where the meshes form the bases of flat rectangular pyramids resembling the structure of BaAl{sub 4}. The flat pyramids are connected via Hg-Zn/Hg bonds, leaving large channels at the folds, in which Ba(1) and Hg(2) atoms alternate. Whereas the remaining Hg/Zn atoms form a covalent 3D network of three- to five-bonded atoms with short M-M distances (273-301 pm; CN 9-11), the Hg(2) atoms in the channels adopt a comparatively large coordination number of 12 and increased distances (317-348 pm) to their Zn/Hg neighbours. In the structure of BaZn{sub 0.6}Hg{sub 3.4} (cubic, cI320, space group I4{sup Macron }3d, a=2025.50(7) pm, Z=64, R1=0.0440), with a chemical composition not much different from that of Ba{sub 3}ZnHg{sub 10}, the Zn/Hg atoms of the mixed positions M(1/2) are arranged in an slightly distorted primitive cubic lattice with a 4 Multiplication-Sign 4 Multiplication-Sign 4 subcell relation to the unit cell. The 24 of the originating 64 cubes contain planar cis tetramers Hg(5,6){sub 4} with Hg in a nearly trigonal planar or tetrahedral coordination. In another 24 of the small cubes, two opposing faces are decorated by Hg(3,4){sub 2} dumbbells, two by Ba(2) atoms respectively. The third type of small cubes are centered by Ba(1) atoms only. The complex 3D polyanionic Hg/Zn network thus formed is compared with the Hg partial structure in Rb{sub 3}Hg{sub 20} applying a group-subgroup relation. Despite their different overall structures, the connectivity of the negatively charged Hg atoms, the rather metallic Zn bonding characteristic (as obtained from FP-LAPW band structure calculations) and the coordination number of 16 for all Ba cations relate the two title compounds. - Graphical abstract: Six of the 64 small sub-cubes of three types (A, B, C) forming the unit cell of the Hg-rich mercuride BaZn{sub 0.6}Hg{sub 3.4}. Highlights: Black-Right-Pointing-Pointer Two new Hg-rich Ba mercurides, both synthesized from the elements in pure phase. Black-Right-Pointing-Pointer BaZn{sub 0.6}HgG{sub 3.4} and Ba{sub 3}ZnHg{sub 10} with new complex structure types. Black-Right-Pointing-Pointer Structure relation to other complex cubic intermetallics. Black-Right-Pointing-Pointer Discussion of covalent and metallic bonding aspects, as found by the structure features and band structure calculations.

Schwarz, Michael; Wendorff, Marco [Institut fuer Anorganische und Analytische Chemie, University of Freiburg, Albertstr. 21, D-79104 Freiburg (Germany)] [Institut fuer Anorganische und Analytische Chemie, University of Freiburg, Albertstr. 21, D-79104 Freiburg (Germany); Roehr, Caroline, E-mail: caroline@ruby.chemie.uni-freiburg.de [Institut fuer Anorganische und Analytische Chemie, University of Freiburg, Albertstr. 21, D-79104 Freiburg (Germany)] [Institut fuer Anorganische und Analytische Chemie, University of Freiburg, Albertstr. 21, D-79104 Freiburg (Germany)

2012-12-15T23:59:59.000Z

79

N2 DISSOCIATION IN THE MESOSPHERE DUE TO SECONDARY ELECTRONS DURING A SOLAR  

E-Print Network [OSTI]

) Sodankylä Geophysical Observatory, Sodankylä, Finland. (pekka.verronen@fmi.fi/+358-9-19294603) Solar protonN2 DISSOCIATION IN THE MESOSPHERE DUE TO SECONDARY ELECTRONS DURING A SOLAR PROTON EVENT, Helsinki, Finland. (2) Institute of Astronomy of the Russian Academy of Sciences, Moscow, Russia. (3

Ulich, Thomas

80

Dipartimento di Fisica -Ufficio Assegni Edificio Marconi -Piazz.le Aldo Moro n. 2, 00185 Roma  

E-Print Network [OSTI]

Dipartimento di Fisica - Ufficio Assegni Edificio Marconi - Piazz.le Aldo Moro n. 2, 00185 Roma T (+39) 06 49914379 F (+39) 06 49914230 http://www.phys.uniroma1.it/fisica/ daria.varone@uniroma1.it RAPPORTO DI LAVORO A TEMPO DETERMINATO TIPOLOGIA A Il Direttore del Dipartimento di Fisica Visto il D

Roma "La Sapienza", Università di

Note: This page contains sample records for the topic "n2 h2s hg" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

CAHIER DU CAMPUS LOGISTIQUE N2 Des carrefours intelligents pour une meilleure gestion du  

E-Print Network [OSTI]

CAHIER DU CAMPUS LOGISTIQUE N2 Des carrefours intelligents pour une meilleure gestion du gestion du trafic en milieu urbain ncessite le dploiement de solutions techniques innovantes pour Journal Europen des Systmes Automatiss. MOTS-CLS : gestion du trafic, rseau de Petri hybride, systme

Boyer, Edmond

82

Exact beta-functions in softly-broken N=2 Chern-Simons matter theories  

E-Print Network [OSTI]

We present exact results for the beta-functions for the soft-breaking parameters in softly-broken N=2 Chern-Simons matter theories in terms of the anomalous dimension in the unbroken theory. We check our results explicitly up to the two loop level.

I. Jack; C. Luckhurst

2011-01-21T23:59:59.000Z

83

Shock-Tube Study of Methane Ignition with NO2 and N2O  

E-Print Network [OSTI]

. The experimental pressure range was 1 - 44 atm and the temperature range tested was 1177 2095 K. The additives NO2 and N2O were added in concentrations from 831 ppm to 3539 ppm. The results of the mixtures with NO2 have a reduction in ignition delay time across...

Pemelton, John

2012-10-19T23:59:59.000Z

84

Vibrational spectra of N2: An advanced undergraduate laboratory in atomic and molecular spectroscopy  

E-Print Network [OSTI]

an advanced laboratory course focused on spectroscopy of atoms and molecules, for a diverse and solid#12;Vibrational spectra of N2: An advanced undergraduate laboratory in atomic and molecular to demonstrate molecular spectroscopy by measuring the vibrational energy spacing of nitrogen molecules

Bayram, S. Burçin

85

Sminaire du Groupe N2IS Manipulation of chemicals in droplet-based microfluidics  

E-Print Network [OSTI]

Séminaire du Groupe N2IS Manipulation of chemicals in droplet-based microfluidics Le 06 Septembre TOULOUSE Cedex 4 Résumé Droplet-based microfluidics has a tremendous potential for the miniaturization of chemicals in microfluidic systems is therefore a key to reliably downscale the assays from microtiter plates

Ingrand, François

86

MIS 381N.2 Research in Information Systems: Organizational and Behavioral Perspectives  

E-Print Network [OSTI]

, corporate strategy and IT, business value of IT, knowledge management and organizational learning1 MIS 381N.2 Research in Information Systems: Organizational and Behavioral Perspectives Spring creation, to new organizational, network, and community structures, to a new cadre of business models

Ghosh, Joydeep

87

What can topology changes in the oddball N2 reveal about underlying processes?  

E-Print Network [OSTI]

of Victoria, Victoria, British Columbia, Canada Correspondence to Christopher M. Warren, MSc, Department of Psychology, University of Victoria, Courier: Room A234, Cornett Building, PO BOX 3050, STN CSC, Victoria, BC 18 July 2011 accepted 7 August 2011 The N2 is a negative deflection in the human event- related brain

Nieuwenhuis, Sander

88

New estimates of global emissions of N2O from rivers and estuaries  

E-Print Network [OSTI]

from rivers and estuaries. We present total global emissions, as well as regional shares. 2New estimates of global emissions of N2O from rivers and estuaries CAROLIEN KROEZE1 , EGON DUMONT1 rivers and estuaries, using the NEWS-DIN model. NEWS-DIN is a model of the global transport of dissolved

Seitzinger, Sybil

89

CH4 and N2O emissions from Spartina alterniflora and Phragmites australis in experimental mesocosms  

E-Print Network [OSTI]

Author's personal copy CH4 and N2O emissions from Spartina alterniflora and Phragmites australis emissions from S. alterniflora with those from a native C3 plant, Phragmites australis, by establishing Elsevier Ltd. All rights reserved. Keywords: Common reed (Phragmites australis); Brackish marsh mesocosms

Chen, Jiquan

90

Manifold and method of batch measurement of Hg-196 concentration using a mass spectrometer  

DOE Patents [OSTI]

A sample manifold and method of its use has been developed so that milligram quantities of mercury can be analyzed mass spectroscopically to determine the .sup.196 Hg concentration to less than 0.02 atomic percent. Using natural mercury as a standard, accuracy of .+-.0.002 atomic percent can be obtained. The mass spectrometer preferably used is a commercially available GC/MS manufactured by Hewlett Packard. A novel sample manifold is contained within an oven allowing flow rate control of Hg into the MS. Another part of the manifold connects to an auxiliary pumping system which facilitates rapid clean up of residual Hg in the manifold. Sample cycle time is about 1 hour.

Grossman, Mark W. (Belmont, MA); Evans, Roger (N. Hampton, NH)

1991-01-01T23:59:59.000Z

91

Manifold and method of batch measurement of Hg-196 concentration using a mass spectrometer  

DOE Patents [OSTI]

A sample manifold and method of its use has been developed so that milligram quantities of mercury can be analyzed mass spectroscopically to determine the [sup 196]Hg concentration to less than 0.02 atomic percent. Using natural mercury as a standard, accuracy of [+-]0.002 atomic percent can be obtained. The mass spectrometer preferably used is a commercially available GC/MS manufactured by Hewlett Packard. A novel sample manifold is contained within an oven allowing flow rate control of Hg into the MS. Another part of the manifold connects to an auxiliary pumping system which facilitates rapid clean up of residual Hg in the manifold. Sample cycle time is about 1 hour. 8 figures.

Grossman, M.W.; Evans, R.

1991-11-26T23:59:59.000Z

92

The Chemical Separation of Eka-Hg from CERN W Targets in view of Recent Relativistic Calculations  

E-Print Network [OSTI]

In 1971 evidence for the production of element 112 via secondary reactions in CERN W targets was obtained. The evidence was mainly based on the observation of fission fragments in Hg sources separated from the W targets, on the measured masses of the fissioning nuclei and on the assumption that element 112 (Eka-Hg) actually behaves like Hg in the chemical separation process. This assumption is analyzed in view of recent relativistic calculations of the electronic structure of element 112. It is shown that in the superheavy element region only the chemistry of element 112 is similar to that of Hg.

D. Kolb; A. Marinov; G. W. A. Newton; R. Brandt

2004-12-07T23:59:59.000Z

93

Observation de super-rseaux CdTe-HgTe par microscopie lectronique en transmission  

E-Print Network [OSTI]

-conducteurs II-VI a été beaucoup plus tardive [2]. Dans cette dernière famille, le système CdTe- HgTe présente l'avantage d'un accord de maille quasi parfait entre les deux composés (a = 0,648 nm pour CdTe contre a = 0 JET MOL?CULAIRE. - Les super- réseaux CdTe-HgTe ont été épitaxiés sur un substrat CdTe d

Paris-Sud XI, Université de

94

Dipartimento di Fisica -Edificio Marconi -Piazz.le Aldo Moro n. 2, 00185 Roma  

E-Print Network [OSTI]

Dipartimento di Fisica - Edificio Marconi - Piazz.le Aldo Moro n. 2, 00185 Roma T (+39) 06 49914379 Direttore del Dipartimento di Fisica Visto il D.L. luogotenenziale 31 agosto 1945, n. 660; Visti i DD.MM. 4 del Dipartimento di Fisica del 23/01/2013 D e c r e t a Art. 1 ­ Oggetto del bando. E' indetta una

Roma "La Sapienza", Università di

95

Integrable N = 2 Landau-Ginzburg Theories from Quotients of Fusion Rings  

E-Print Network [OSTI]

The discovery of integrable $N=2$ supersymmetric Landau-Ginzburg theories whose chiral rings are fusion rings suggests a close connection between fusion rings, the related Landau-Ginzburg superpotentials, and $N=2$ quantum integrability. We examine this connection by finding the natural $SO(N)_K$ analogue of the construction that produced the superpotentials with $Sp(N)_K$ and $SU(N)_K$ fusion rings as chiral rings. The chiral rings of the new superpotentials are not directly the fusion rings of any conformal field theory, although they are natural quotients of the tensor subring of the $SO(N)_K$ fusion ring. The new superpotentials yield solvable (twisted $N=2$) topological field theories. We obtain the integer-valued correlation functions as sums of $SO(N)_K$ Verlinde dimensions by expressing the correlators as fusion residues. The $SO(2n+1)_{2k+1}$ and $SO(2k+1)_{2n+1}$ related topological Landau-Ginzburg theories are isomorphic, despite being defined via quite different superpotentials.

Eli J. Mlawer; Harold A. Riggs; Howard J. Schnitzer

1993-10-14T23:59:59.000Z

96

Indirect ultraviolet photodesorption from CO:N2 binary ices - an efficient grain-gas process  

E-Print Network [OSTI]

UV ice photodesorption is an important non-thermal desorption pathway in many interstellar environments that has been invoked to explain observations of cold molecules in disks, clouds and cloud cores. Systematic laboratory studies of the photodesorption rates, between 7 and 14 eV, from CO:N2 binary ices, have been performed at the DESIRS vacuum UV beamline of the synchrotron facility SOLEIL. The photodesorption spectral analysis demonstrates that the photodesorption process is indirect, i.e. the desorption is induced by a photon absorption in sub-surface molecular layers, while only surface molecules are actually desorbing. The photodesorption spectra of CO and N2 in binary ices therefore depend on the absorption spectra of the dominant species in the subsurface ice layer, which implies that the photodesorption efficiency and energy dependence are dramatically different for mixed and layered ices compared to pure ices. In particular, a thin (1-2 ML) N2 ice layer on top of CO will effectively quench CO photod...

Bertin, Mathieu; Romanzin, Claire; Poderoso, Hugo A M; Michaut, Xavier; Philippe, Laurent; Jeseck, Pascal; berg, Karin I; Linnartz, Harold; Fillion, Jean-Hugues

2013-01-01T23:59:59.000Z

97

Modeling Studies on the Transport of Benzene and H2S in CO2-Water Systems  

E-Print Network [OSTI]

reservoir to shallower formations, for example through fault or fracture zones, or poorly plugged abandoned

Zheng, L.

2011-01-01T23:59:59.000Z

98

Modeling Studies on the Transport of Benzene and H2S in CO2-Water Systems  

E-Print Network [OSTI]

Gu and Evans, 2007) (Bradbury and Baeyens, 2005) Sme s _OPb + Sme w _OPb + Sme s _OPb + + H + = Sme s _OH + Pb +2 Sme w _OPb + +

Zheng, L.

2011-01-01T23:59:59.000Z

99

Synthesis and Characterization of CO- and H2S-Tolerant Electrocatalysts for PEM Fuel Cell  

SciTech Connect (OSTI)

The present state-of-art Proton Exchange Membrane Fuel Cell (PEMFC) technology is based on platinum (Pt) as a catalyst for both the fuel (anode) and air (cathode) electrodes. This catalyst is highly active but susceptible to poisoning by CO, which may be present in the H{sub 2}-fuel used or may be introduced during the fuel processing. Presence of trace amount of CO and H{sub 2}S in the H{sub 2}-fuel poisons the anode irreversibly and decreases the performance of the PEMFCs. In an effort to reduce the Pt-loading and improve the PEMFC performance, we propose to synthesize a number of Pt-based binary, ternary, and quaternary electrocatalysts using Ru, Mo, Ir, Ni, and Co as a substitute for Pt. By fine-tuning the metal loadings and compositions of candidate electrocatalysts, we plan to minimize the cost and optimize the catalyst activity and performance in PEMFC. The feasibility of the novel electrocatalysts will be demonstrated in the proposed effort with gas phase CO and H{sub 2}S concentrations typical of those found in reformed fuel gas with coal/natural gas/methanol feedstocks. During this reporting period we used four Pt-based electrocatalysts (Pt/Ru/Mo/Se, Pt/Ru/Mo/Ir, Pt/Ru/Mo/W, Ptr/Ru/Mo/Co) in MEAs and these were evaluated for CO-tolerance with 20 and 100 ppm CO concentration in H{sub 2}-fuel. From current-voltage performance study, the catalytic activity was found in the increasing order of Pt/Ru/Mo/Ir > Pt/Ru/Mo/W > Pt/Ru/Mo/Co > Pt/Ru/MO/Se. From preliminary cost analysis it appears that could of the catalyst metal loading can reduced by 40% to 60% depending on the selection of metal combinations without compromising the fuel cell performance.

Shamsuddin Ilias

2006-05-18T23:59:59.000Z

100

Synthesis and Characterization of CO- and H2S-Tolerant Electrocatalysts for PEM Fuel Cell  

SciTech Connect (OSTI)

The present state-of-art Proton Exchange Membrane Fuel Cell (PEMFC) technology is based on platinum (Pt) as a catalyst for both the fuel (anode) and air (cathode) electrodes. This catalyst is highly active but susceptible to poisoning by CO, which may be present in the H{sub 2}-fuel used or may be introduced during the fuel processing. Presence of trace amount of CO and H{sub 2}S in the H{sub 2}-fuel poisons the anode irreversibly and decreases the performance of the PEMFCs. In an effort to reduce the Pt-loading and improve the PEMFC performance, we propose to synthesize a number of Pt-based binary, ternary, and quaternary electrocatalysts using Ru, Mo, Ir, Ni, and Co as a substitute for Pt. By fine-tuning the metal loadings and compositions of candidate electrocatalysts, we plan to minimize the cost and optimize the catalyst activity and performance in PEMFC. The feasibility of the novel electrocatalysts will be demonstrated in the proposed effort with gas phase CO and H{sub 2}S concentrations typical of those found in reformed fuel gas with coal/natural gas/methanol feedstocks. In this work binary, ternary, and quaternary platinum-based electrocatalysts were synthesized for the purpose of lowering the cost and increasing the CO tolerance of the membrane electrode assembly (MEA) in the fuel cell. The metals Ru, Mo, W, Ir, Co and Se were alloyed with platinum on a carbon support using a modified reduction method. These catalysts were fabricated into MEAs and evaluated for electrical performance and CO tolerance with polarization experiments. The quaternary system Pt/Ru/Mo/Ir system is the most CO tolerant in the PEMFC and has a low total metal loading of 0.4 mg/cm{sup 2} in the electrode of the cell.

Shamsuddin Ilias

2006-09-30T23:59:59.000Z

Note: This page contains sample records for the topic "n2 h2s hg" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Synthesis and Characterization of CO- and H2S-Tolerant Electrocatalysts for PEM Fuel Cell  

SciTech Connect (OSTI)

The present state-of-art Proton Exchange Membrane Fuel Cell (PEMFC) technology is based on platinum (Pt) as a catalyst for both the fuel (anode) and air (cathode) electrodes. This catalyst is highly active but susceptible to poisoning by CO, which may be present in the H{sub 2}-fuel used or may be introduced during the fuel processing. Presence of trace amount of CO and H{sub 2}S in the H{sub 2}-fuel poisons the anode irreversibly and decreases the performance of the PEMFCs. In an effort to reduce the Pt-loading and improve the PEMFC performance, we propose to synthesize a number of Pt-based binary, ternary, and quaternary electrocatalysts using Ru, Mo, Ir, Ni, and Co as a substitute for Pt. By fine-tuning the metal loadings and compositions of candidate electrocatalysts, we plan to minimize the cost and optimize the catalyst activity and performance in PEMFC. The feasibility of the novel electrocatalysts will be demonstrated in the proposed effort with gas phase CO and H{sub 2}S concentrations typical of those found in reformed fuel gas with coal/natural gas/methanol feedstocks. During this reporting period we synthesized several tri-metallic electrocatalysts catalysts (Pt/Ru/Mo, Pt/Ru/Ir, Pt/Ru/W, Ptr/Ru/Co, and Pt/Ru/Se on Vulcan XG72 Carbon) by ultrasonication method. These catalysts were tested in MEAs for CO tolerance at 20 and 100 ppm CO concentrations. From Galvonstatic study the catalytic activity was found in the order of: Pt/Ru/Mo/C > Pt/Ru/Ir/C > Pt/Ru/W/C > Ptr/Ru/Co/C > and Pt/Ru/Se. The catalysts performed very well at 20 ppm CO but at 100 ppm CO performance dropped significantly.

Shamsuddin Ilias

2005-07-20T23:59:59.000Z

102

Development of analytical techniques to study H2s poisoning of PEMFCs and components  

SciTech Connect (OSTI)

Polymer electrolyte membrane fuel cells are sensitive to impurities that may be present in either the oxidizer or fuel. H{sub 2}S, even at the ppb level, will have a dramatic and adverse affect on fuel cell performance. Not only is it important to know a particular material's affinity to adsorb H{sub 2}S, when considering materials for PEMFC applications, issues such as permeation and crossover rates also become extremely important Several experimental methods have been developed to quantify H{sub 2}S adsorption onto surfaces and to quantify H{sub 2}S permeation through Nafion(reg.) membranes using readily available and inexpensive Ag/AgS ion probes. In addition to calculating the H{sub 2}S uptake on commonly used XC-72 carbon supports and PtlXC-72 catalysts, the H{sub 2}S permeability through dry and humidified Nafion(reg.) PEMFC membranes was also studied using these specialized techniques. In each ion probe experiment performed, a sulfide anti-oxidant buffer solution was used to trap and concentrate trace quantities of H{sub 2}S during the course of the measurement. Crossover experiments were conducted for up to 24 hours in order to achieve sulfide ion concentrations high enough to be precisely determined by subsequent titration with Pb(NO{sub 3}){sub 2}. By using these techniques, we have confirmed H{sub 2}S crossover in Nafion(reg.) membranes and have calculated preliminary rates of H{sub 2}S crossover.

Brosha, Eric L [Los Alamos National Laboratory; Rockward, Tommy [Los Alamos National Laboratory; Uribe, Francisco A [Los Alamos National Laboratory; Garzon, Fernando H [Los Alamos National Laboratory

2008-01-01T23:59:59.000Z

103

Kinetics of Direct Oxidation of H2S in Coal Gas to Elemental Sulfur  

SciTech Connect (OSTI)

Removal of hydrogen sulfide (H{sub 2}S) from coal gasifier gas and sulfur recovery are key steps in the development of Department of Energy's (DOE's) advanced Vision 21 plants that produce electric power and clean transportation fuels with coal and natural gas. These Vision 21 plants will require highly clean coal gas with H{sub 2}S below 1 ppm and negligible amounts of trace contaminants such as hydrogen chloride, ammonia, alkali, heavy metals, and particulate. The conventional method of sulfur removal and recovery employing amine, Claus, and tail-gas treatment is very expensive. A second generation approach developed under DOE's sponsorship employs hot-gas desulfurization (HGD) using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process (DSRP). However, this process sequence does not remove trace contaminants and is targeted primarily towards the development of advanced integrated gasification combined cycle (IGCC) plants that produce electricity (not both electricity and transportation fuels). There is an immediate as well as long-term need for the development of cleanup processes that produce highly clean coal gas for next generation Vision 21 plants. To this end, a novel process is now under development at several research organizations in which the H{sub 2}S in coal gas is directly oxidized to elemental sulfur over a selective catalyst. Such a process is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. The direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and HGD/DSRP. The objectives of this research are to measure kinetics of direct oxidation of H{sub 2}S to elemental sulfur in the presence of a simulated coal gas mixture containing SO{sub 2}, H{sub 2}, and moisture, using 160-{micro}m C-500-04 alumina catalyst particles and 400 square cells/inch{sup 2}, {gamma}-Al{sub 2}O{sub 3}-wash-coated monolithic catalyst, and various reactors such as a micro packed-bed reactor, a micro bubble reactor, and a monolithic catalyst reactor, and to develop kinetic rate equations and model the direct oxidation process to assist in the design of large-scale plants. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam.

K.C. Kwon

2005-11-01T23:59:59.000Z

104

Modeling Studies on the Transport of Benzene and H2S in CO2-Water Systems  

SciTech Connect (OSTI)

In this study, reactive transport simulations were used to assess the mobilization and transport of organics with supercritical CO{sub 2} (SCC), and the co-injection and transport of H{sub 2}S with SCC. These processes were evaluated at conditions of typical storage reservoirs, and for cases of hypothetical leakage from a reservoir to an overlying shallower fresh water aquifer. Modeling capabilities were developed to allow the simulation of multiphase flow and transport of H{sub 2}O, CO{sub 2}, H{sub 2}S, as well as specific organic compounds (benzene), coupled with multicomponent geochemical reaction and transport. This included the development of a new simulator, TMVOC-REACT, starting from existing modules of the TOUGH2 family of codes. This work also included an extensive literature review, calculation, and testing of phase-partitioning properties for mixtures of the phases considered. The reactive transport simulations presented in this report are primarily intended to illustrate the capabilities of the new simulator. They are also intended to help evaluate and understand various processes at play, in a more qualitative than quantitative manner, and only for hypothetical scenarios. Therefore, model results are not intended as realistic assessments of groundwater quality changes for specific locations, and they certainly do not provide an exhaustive evaluation of all possible site conditions, especially given the large variability and uncertainty in hydrogeologic and geochemical parameter input into simulations. The first step in evaluating the potential mobilization and transport of organics was the identification of compounds likely to be present in deep storage formations, and likely to negatively impact freshwater aquifers if mobilized by SCC. On the basis of a literature review related to the occurrence of these organic compounds, their solubility in water and SCC, and their toxicity (as reflected by their maximum contaminant levels MCL), benzene was selected as a key compound for inclusion into numerical simulations. Note that considering additional organic compounds and/or mixtures of such compounds in the simulations was beyond the scope of this study, because of the effort required to research, calculate, and validate the phase-partitioning data necessary for simulations. The injection of CO{sub 2} into a deep saline aquifer was simulated, followed by modeling the leaching of benzene by SCC and transport of benzene to an overlying aquifer along a hypothetical leakage pathway. One- and two-dimensional models were set up for this purpose. The target storage formation was assumed to initially contain about 10{sup -4} ppm benzene. Model results indicate that: (1) SCC efficiently extracts benzene from the storage formation. (2) Assuming equilibrium, the content of benzene in SCC is roportional to the concentration of benzene in the aqueous and solid phases. (3) Benzene may co-migrate with CO{sub 2} into overlying aquifers if a leakage pathway is present. Because the aqueous solubility of benzene in contact with CO{sub 2} is lower than the aqueous solubility of CO{sub 2}, benzene is actually enriched in the CO{sub 2} phase as the plume advances. (4) For the case studied here, the resulting aqueous benzene concentration in the overlying aquifer is on the same order of magnitude as the initial concentration in the storage formation. This generic modeling study illustrates, in a semi-quantitative manner, the possible mobilization of benzene by SCC. The extent to which the mobilization of this organic compound evolves temporally and spatially depends on a large number of controlling parameters and is largely site specific. Therefore, for more 'truly' predictive work, further sensitivity studies should be conducted, and further modeling should be integrated with site-specific laboratory and/or field experimental data. The co-injection of H{sub 2}S with CO{sub 2} into a deep saline aquifer was also simulated. In addition, the model considered leakage of the supercritical CO{sub 2}+H{sub 2}S mixture along a preferential p

Zheng, L.; Spycher, N.; Xu, T.; Apps, J.; Kharaka, Y.; Birkholzer, J.T.

2010-11-05T23:59:59.000Z

105

Mineralization of Basalts in the CO2-H2O-H2S System. | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: VegetationEquipment SurfacesResource Program PreliminaryA3,0 Alabama - NaturalHanford TankMineralization

106

15 Years of Successful H2S Abatement | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 NoPublic Utilities Address: 160 East 300 South Place:ReferenceEditWisconsin:YBR14 CCR § 13315Legal Abstract1415of

107

Optical Diagnostics Hg_jet_meeting, 01-18-05 Thomas Tsang  

E-Print Network [OSTI]

Optical Diagnostics Hg_jet_meeting, 01-18-05 Thomas Tsang · tight environment · high radiation area · non-serviceable area · passive components · optics only, no active electronics · back illuminated with a single fiber laser - pulsed laser X · transmit image through flexible fiber bundle #12;Optical

McDonald, Kirk

108

H-G Diagram Based Rotor Parameters Identification for Induction Motors Thermal Monitoring  

E-Print Network [OSTI]

H-G Diagram Based Rotor Parameters Identification for Induction Motors Thermal Monitoring Mohamed: In this paper, an effective on-line method for induction motor parameter identification, especially rotor for each operating point. Computer simulations and experimental tests, carried out for a 4-kW four

Brest, Université de

109

6035 Hg(Ar) Lamp in 6058 Fiber Optic Accessory. Pencil Style Calibration Lamps  

E-Print Network [OSTI]

to that of the Hg(Ar) Lamp, which is the characteristic mercury line spectrum. Forced air-cooling (i.e. from of the handle for connection to the power supply. Table 1 Usable Wavelengths of Spectral Calibration Lamps (in.2 1079.8 1084.5 1114.3 Power Supplies; AC versus DC We offer different power supplies for different needs

Woodall, Jerry M.

110

Appendix: Mercury Emissions used in CAM-Chem/Hg model. 1. Anthropogenic emissions  

E-Print Network [OSTI]

Appendix: Mercury Emissions used in CAM-Chem/Hg model. 1. Anthropogenic emissions The anthropogenic emission of mercury is directly adopted from global mercury emission inventory [Pacyna et al., 2005]. The anthropogenic emissions are shown in annual averaged total mercury emissions. (Unit: µg/m2 /day) 2. Land

Meskhidze, Nicholas

111

creasing Hg2 concentration. After correcting for the initial shift caused by the new environment,  

E-Print Network [OSTI]

- tical density 9 4). The HgCl2 was still detected through these highly absorptive media (Fig. 3D-SWNTs and inserted into whole blood and muscle tissue. The complex was added directly to a black dye solution (op). The near-IR fluorescence of DNA-SWNTs in the dye solution exhibited the same response as SWNTs in pure

Garzione, Carmala N.

112

Nitrous Oxide Nitrous oxide (chemical formula N2O), is a trace gas in Earth's atmosphere, with a  

E-Print Network [OSTI]

fuel, biomass and biofuel, and industrial processes. Nitrous oxide emissions related to biofuel, the Global Warming Potential (GWP) is a more useful quantity. The GWP of N2O is the time- integrated radiative forcing following a 1 kg pulse emission of N2O, relative to the same quantity following a 1 kg

113

Single-QCL-based absorption sensor for simultaneous trace-gas detection of CH4 and N2O  

E-Print Network [OSTI]

compact multipass gas cell (MGC). This sensor uses a thermoelectrically cooled, continuous wave­8]. A compact mid-infrared absorption spectrometer for N2O and CH4 was developed using thermoelectrically cooled.04 cm-1 ) and N2O (1274.61 cm-1 ) lines at a 1 Hz repetition rate. Wavelength modulation spec- troscopy

114

ORIGINAL PAPER Short-term effect of tillage intensity on N2O and CO2 emissions  

E-Print Network [OSTI]

ORIGINAL PAPER Short-term effect of tillage intensity on N2O and CO2 emissions Pascal Boeckx negative to positive. We studied the short-term effect of tillage intensity on N2O and CO2 emissions. We site, an intermediately aerated Luvisol in Belgium, were similar. Nitrous oxide and CO2 emissions were

Paris-Sud XI, Université de

115

Pinning lattice: Effect of rhenium doping on the microstructural evolution from Tl-2212 to Hg-1212 films during cation exchange  

E-Print Network [OSTI]

In a cation exchange process developed recently by some of us, epitaxial HgBa2CaCu2O6 films can be obtained by diffusing volatile Tl cations out of, and simultaneously diffusing Hg cations into, the crystalline lattice of ...

Wu, Judy; Zhao, H.

2004-08-15T23:59:59.000Z

116

OPTIMIZATION OF GRADED BAND GAP CdHgTe SOLAR CELLS A. BOUAZZI (*), Y. MARFAING and J. MIMILA-ARROYO  

E-Print Network [OSTI]

145 OPTIMIZATION OF GRADED BAND GAP CdHgTe SOLAR CELLS A. BOUAZZI (*), Y. MARFAING and J. MIMILA and an n-type CdHgTe alloy of uniform band gap as the base region. The optimization of solar energy conversion is conducted with respect to two constitutive para- meters : the gradient of the band gap

Boyer, Edmond

117

Absorption of Narrow-Gap HgCdTe Near the Band Edge Including Nonparabolicity and the Urbach Tail  

E-Print Network [OSTI]

Absorption of Narrow-Gap HgCdTe Near the Band Edge Including Nonparabolicity and the Urbach Tail, USA. 6.--e-mail: yonchang@uic.edu An analytical model describing the absorption behavior of Hg1-x. This model smoothly fits experimental absorption coefficients over energies ranging from the Urbach tail

Flatte, Michael E.

118

High resolution measurements of the {sup 241}Am(n,2n) reaction cross section  

SciTech Connect (OSTI)

Measurements of the {sup 241}Am(n,2n) reaction cross section have been performed at the Joint Research Centre (JRC) Geel in the frame of a collaboration between the European Commission (EC) JRC and French laboratories from CNRS and the Commissariat a L'Energie Atomique (CEA) Cadarache. Raw material coming from the Atalante facility of CEA Marcoule has been transformed by JRC Karlsruhe into suitable {sup 241}AmO{sub 2} samples embedded in Al{sub 2}O{sub 3} matrices specifically designed for these measurements. The irradiations were carried out at the 7-MV Van de Graaff accelerator. The {sup 241}Am(n,2n) reaction cross section was determined relative to the {sup 27}Al(n,alpha){sup 24}Na standard cross section. The measurements were performed in four sessions, using quasi-mono-energetic neutrons with energies ranging from 8 to 21 MeV produced via the {sup 2}H(d,n){sup 3}He and the {sup 3}H(d,n){sup 4}He reactions. The induced activity was measured by standard gamma-ray spectrometry using a high-purity germanium detector. Below 15 MeV, the present results are in agreement with data obtained earlier. Above 15 MeV, these measurements allowed the experimental investigation of the {sup 241}Am(n,2n) reaction cross section for the first time. The present data are in good agreement with predictions obtained with the talys code that uses an optical and fission model developed at CEA.

Sage, C. [Commissariat a L'Energie Atomique Saclay, DSM/IRFU/SPhN, F-91191 Gif-sur-Yvette (France); European Commission, Joint Research Centre, Institute for Reference Materials and Measurements, Retieseweg 111, B-2440 Geel (Belgium); Commissariat a L'Energie Atomique Cadarache, DEN/CAD/DER/SPRC/LEPh, F-13108 St Paul-lez-Durance (France); Institut Pluridisciplinaire Hubert Curien, F-67037 Strasbourg (France); Semkova, V. [European Commission, Joint Research Centre, Institute for Reference Materials and Measurements, Retieseweg 111, B-2440 Geel (Belgium); Institute for Nuclear Research and Nuclear Energy, Bulgarian Academy of Sciences, BG-1784 Sofia (Bulgaria); Bouland, O. [Commissariat a L'Energie Atomique Cadarache, DEN/CAD/DER/SPRC/LEPh, F-13108 St Paul-lez-Durance (France); Los Alamos National Laboratory, Theoretical Division, Los Alamos, New Mexico 87545 (United States); Dessagne, P.; Rudolf, G. [Institut Pluridisciplinaire Hubert Curien, F-67037 Strasbourg (France); Fernandez, A.; Naestren, C.; Ottmar, H.; Somers, J.; Wastin, F. [European Commission, Joint Research Centre, Institute for Transuranium Elements, Postfach 2340, D-76125 Karlsruhe (Germany); Gunsing, F. [Commissariat a L'Energie Atomique Saclay, DSM/IRFU/SPhN, F-91191 Gif-sur-Yvette (France); Noguere, G. [Commissariat a L'Energie Atomique Cadarache, DEN/CAD/DER/SPRC/LEPh, F-13108 St Paul-lez-Durance (France); Plompen, A. J. M. [European Commission, Joint Research Centre, Institute for Reference Materials and Measurements, Retieseweg 111, B-2440 Geel (Belgium); Romain, P. [Commissariat a L'Energie Atomique, DAM, DIF, F-91297 Arpajon (France)

2010-06-15T23:59:59.000Z

119

The free energy of N=2 supersymmetric AdS_4 solutions of M-theory  

E-Print Network [OSTI]

We show that general N=2 supersymmetric AdS_4 solutions of M-theory with non-zero M2-brane charge admit a canonical contact structure. The free energy of the dual superconformal field theory on S^3 and the scaling dimensions of operators dual to supersymmetric wrapped M5-branes are expressed via AdS/CFT in terms of contact volumes. In particular, this leads to topological and localization formulae for the coefficient of N^{3/2} in the free energy of such solutions.

Maxime Gabella; Dario Martelli; Achilleas Passias; James Sparks

2011-07-29T23:59:59.000Z

120

H-2(p,n)2p Spin Transfer from 305 to 788 Mev  

E-Print Network [OSTI]

PHYSICAL REVIEW C VOLUME 45, NUMBER 6 JUNE 1992 ARTICLES 2H(y, n)2p spin transfer from $05 to 7'88 Mev M. W. McNaughton, K. Koch, ' I. Supek, and N. Tanakat Los Alamos National Laboratory, Ios Alarnos, ?wMexico 876/6 D. A. Ambrose, P. Coff... the primary polarized-proton beam onto a liquid-deuterium (LD2) target and collimating the neutrons at a laboratory scat- tering angle of 0 (180' c.m. ). The neutron beam is po- larized via the L-to-L spin-transfer observable A'L, l. for the ~H(p, n...

McNaughton, M. W.; Koch, K.; Supek, I.; Tanaka, N.; Ambrose, DA; Coffey, P.; Johnston, K.; McNaughton, K. H.; Riley, P. J.; Glass, G.; Hiebert, John C.; Northcliffe, L. C.; Simon, A. J.; Mercer, D. J.; Adams, D. L.; Spinka, H.; Jeppersen, R. H.; Tripard, G. E.; Woolverton, H.

1992-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "n2 h2s hg" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Temperature Dependence of Scott Thermomagnetic Torque in N2, Ch4, and Hd  

E-Print Network [OSTI]

10 '&D&2x10 ', B. Gosse (private communica- tion). PHYSIC AL REVIEW A VO LUME 6, NUMBER 1 JULY 1972 Temperature Dependence of the Scott Thermomagnetic Torque in N, , CH4, and HD T. W. Adair, III Department of Physics, Texas A@M University..., College Station, Texas 77843 (Received 20 December 1971) The temperature dependence of the Scott thermomagnetic torque has been measured in N2, CH4, and HD. Measurements were made from a temperature of 75 up to 300'K, from a pres- sure of 0.003 up to 1...

Adair, Thomas W.

1972-01-01T23:59:59.000Z

122

The N2K Consortium. IV. New temperatures and metallicities for 100,000+ FGK dwarfs  

E-Print Network [OSTI]

We have created a framework to facilitate the construction of specialized target lists for radial velocity surveys that are biased toward stars that (1) possess planets and (2) are easiest to observe with current detection techniques. We use a procedure that uniformly estimates fundamental stellar properties of Tycho 2 stars, with errors, using spline functions of broadband photometry and proper motion found in Hipparcos/Tycho 2 and 2MASS. We provide estimates of temperature and distance for 2.4 million Tycho 2 stars that lack trigonometric distances. For stars that appear to be FGK dwarfs according to estimated temperature and absolute magnitude, we also derive [Fe/H] and identify unresolved binary systems with mass ratios between 1.25 and 3. Our spline function models are trained on the unique Valenti & Fischer (2005) set, composed of 1000 dwarfs with precise stellar parameters estimated from HIRES spectroscopy. For FGK dwarfs with V photometric error less than 0.05 magnitudes, or V 0.2). Our metallicity estimates have been used to identify targets for N2K (Fischer et al. 2005), a large-scale radial velocity search for Hot Jupiters, which has published the detection of 4 Hot Jupiters with one transit. The broadband filtering outlined here is the first screening tier for N2K; the second tier is a low-resolution spectroscopy program headed by S.E. Robinson (astro-ph/0510150).

S. Mark Ammons; Sarah E. Robinson; Jay Strader; Gregory Laughlin; Debra Fischer; Aaron Wolf

2005-10-07T23:59:59.000Z

123

Physisorption of N2, O2, and CO on Fully Oxidized TiO2(110)  

SciTech Connect (OSTI)

Physisorption of N2, O2 and CO was studied on fully oxidized TiO2(110) using beam reflection and temperature programmed desorption (TPD) techniques. Sticking coefficients for all three molecules are nearly equal (0.75 0.05) and approximately independent of coverage suggesting that adsorption occurs via a precursor mediated mechanism. Excluding multilayer coverages, the TPD spectra for all three adsorbates exhibit three distinct coverage regimes that can be interpreted in accord with previous theoretical studies of N2 adsorption. At low coverages (0 to 0.5 N2/Ti4+), N2 molecules bind head-on to five-coordinated Ti4+ ions. The adsorption occurs preferentially on the Ti4+ sites that do not have neighboring adsorbates. This arrangement minimizes the repulsive interactions between the adsorbed molecules along the Ti4+ rows resulting in a relatively small shift of the TPD peak (105 ? 90 K) with increasing coverage. At higher N2 coverages (0 to 1.0 N2/Ti4+) the nearest-neighbor Ti4+ sites become occupied. The close proximity of the adsorbates results in strong repulsion thus giving rise to a significant shift of the TPD leading edges (90 ? 45 K) with increasing coverage. For N2/Ti4+ > 1, an additional low temperature peak (~ 43 K) is present and is ascribed to N2 adsorption on bridge-bonded oxygen rows. The results for O2 and CO are qualitatively similar. The repulsive adsorbate-adsorbate interactions largest for CO, most likely due to aligned CO dipole moments. The coverage dependent binding energies of O2, N2, and CO are determined by inverting TPD profiles.

Dohnalek, Zdenek; Kim, Jooho; Bondarchuk, Oleksander A.; White, J. M.; Kay, Bruce D.

2006-03-30T23:59:59.000Z

124

Axi-symmetrical flow reactor for [sup 196]Hg photochemical enrichment  

DOE Patents [OSTI]

The present invention is directed to an improved photochemical reactor useful for the isotopic enrichment of a predetermined isotope of mercury, especially, [sup 196]Hg. Specifically, two axi-symmetrical flow reactors were constructed according to the teachings of the present invention. These reactors improve the mixing of the reactants during the photochemical enrichment process, affording higher yields of the desired [sup 196]Hg product. Measurements of the variation of yield (Y) and enrichment factor (E) along the flow axis of these reactors indicates very substantial improvement in process uniformity compared to previously used photochemical reactor systems. In one preferred embodiment of the present invention, the photoreactor system was built such that the reactor chamber was removable from the system without disturbing the location of either the photochemical lamp or the filter employed therewith. 10 figures.

Grossman, M.W.

1991-04-30T23:59:59.000Z

125

Comparison of Self-Consistent Skyrme and Gogny Calculations for Light Hg Isotopes  

E-Print Network [OSTI]

The ground-state properties of neutron-deficient Hg isotopes have been investigated by the constrained self-consistent Hartree-Fock-Bogoliubov approach with the Skyrme and Gogny effective forces. In the case of the Skyrme interaction we h ave also applied the Hartree-Fock+BCS model with the state-dependent $\\delta$-pairing interaction. Potential energy surfaces and pairing properties have been compared for the both types of forces.

M. Warda; A. Staszczak; L. Prchniak

2011-07-05T23:59:59.000Z

126

Automated product recovery in a Hg-196 photochemical isotope separation process  

DOE Patents [OSTI]

A method of removing deposited product from a photochemical reactor used in the enrichment of [sup 196]Hg has been developed and shown to be effective for rapid re-cycling of the reactor system. Unlike previous methods relatively low temperatures are used in a gas and vapor phase process of removal. Importantly, the recovery process is understood in a quantitative manner so that scaling design to larger capacity systems can be easily carried out. 2 figs.

Grossman, M.W.; Speer, R.

1992-07-21T23:59:59.000Z

127

Spin polarized current injection through HgBr{sub 2} intercalated Bi2212 intrinsic Josephson junctions.  

SciTech Connect (OSTI)

To investigate the effect of polarized current on tunneling characteristics of intrinsic Josephson junctions (IJJs), spin-polarized and spin-degenerate current have been injected through the c-axis of HgBr{sub 2} intercalated Bi{sub 2.1}Sr{sub 1.5}Ca{sub 1.4}Cu{sub 2}O{sub 8+delta} (Bi2212) single crystals on which 10 times 10 mum{sup 2} mesas have been fabricated. These two spin conditions are achieved by depositing either Au (15 nm)/Co (80 nm)/Au (156 nm) multilayers or single Au film on HgBr{sub 2} intercalated Bi2212 with T{sub c} = 74 K followed by photolithography and Ar ion beam etching. The I-V characteristics have been measured with and without a magnetic field parallel to c-axis at 4.2 K. A fine, soft Au wire is used to make a gentle mechanical contact on the top of a particular mesa in the array. Tunneling conductance characteristics were obtained and the magnetic field dependence of sumgap voltage peaks was investigated. These peaks do not change in position with increasing magnetic field for both contact configurations. In addition, the temperature dependence of tunneling characteristics of the IJJs are obtained and existence of pseudogap feature is observed above T{sub c} for HgBr{sub 2} intercalated Bi2212.

Ozyuzer, L.; Kurter, C.; Ozdemir, M.; Zasadzinski, J. F.; Gray, K. E.; Hinks, D. G. (Materials Science Division); (Izmir Inst. of Tech.); (Illinois Inst. of Tech.)

2007-06-01T23:59:59.000Z

128

Homogeneous and Heterogeneous Reaction and Transformation of Hg and Trace Metals in Combustion Systems  

SciTech Connect (OSTI)

The overall goal of this project was to produce a working dynamic model to predict the transformation and partitioning of trace metals resulting from combustion of a broad range of fuels. The information provided from this model will be instrumental in efforts to identify fuels and conditions that can be varied to reduce metal emissions. Through the course of this project, it was determined that mercury (Hg) and arsenic (As) would be the focus of the experimental investigation. Experiments were therefore conducted to examine homogeneous and heterogeneous mercury oxidation pathways, and to assess potential interactions between arsenic and calcium. As described in this report, results indicated that the role of SO{sub 2} on Hg oxidation was complex and depended upon overall gas phase chemistry, that iron oxide (hematite) particles contributed directly to heterogeneous Hg oxidation, and that As-Ca interactions occurred through both gas-solid and within-char reaction pathways. Modeling based on this study indicated that, depending upon coal type and fly ash particle size, vaporization-condensation, vaporization-surface reaction, and As-CaO in-char reaction all play a role in arsenic transformations under combustion conditions.

J. Helble; Clara Smith; David Miller

2009-08-31T23:59:59.000Z

129

A U T U M N 2 0 1 4www.ucd.ie/ucdtoday 5.Alooktothe  

E-Print Network [OSTI]

A U T U M N 2 0 1 4www.ucd.ie/ucdtoday 5.Alooktothe biggerpicture ofresearch 7.Thenatural worldin Quinn, Bernadette Rafter, Eugene Roche, Mark Simpson, Craig Slattery, Barry Smyth, Conor Sweeney, Cathy

Pollastri, Gianluca

130

Large rank Wilson loops in N=2 superconformal QCD at strong coupling  

E-Print Network [OSTI]

We compute the expectation values of circular Wilson loops in large representations at strong coupling, in the large-N limit of the N=2 superconformal theory with SU(N) gauge group and 2N hypermultiplets. Employing Pestun's matrix integral, we focus attention on symmetric and antisymmetric representations with ranks of order N. We find that large rank antisymmetric loops are independent of the coupling at strong 't Hooft coupling while symmetric Wilson loops grow exponentially with it. Symmetric loops display a non-analyticity as a function of the rank, characterized by the splitting of a single matrix model eigenvalue from the continuum, bearing close resemblance to Bose-Einstein condensation in an ideal gas. We discuss implications of these for a putative large-N string dual. The method of calculation we adopt makes explicit the connection to Fermi and Bose gas descriptions and also suggests a tantalizing connection of the above system to a multichannel Kondo model.

Benedict Fraser; S. Prem Kumar

2012-02-28T23:59:59.000Z

131

Enhanced CO2/N2 Selectivity in Amidoxime-Modified Porous Carbon  

SciTech Connect (OSTI)

In this work, we examine the use of the amidoxime functional group grafted onto a hierarchical porous carbon framework for the selective capture and removal of carbon dioxide from combustion streams. Measured CO2/N2 ideal selectivity values for the amidoxime-grafted carbon were significantly higher than the pristine porous carbon with improvements of 65%. Though the overall CO2 capacity decreased slightly for the activated carbon from 4.97 mmol g-1 to 4.24 mmol g-1 after surface modification due to a reduction in the total surface area, the isosteric heats of adsorption increased after amidoxime incorporation indicating an increased interaction of CO2 with the sorbent. Total capacity was reproducible and stable after multiple adsorption/desorption cycles with no loss of capacity suggesting that modification with the amidoxime group is a potential method to enhance carbon capture.

Mahurin, Shannon Mark [ORNL] [ORNL; Gorka, Joanna [ORNL] [ORNL; Nelson, Kimberly M [ORNL] [ORNL; Mayes, Richard T [ORNL] [ORNL; Dai, Sheng [ORNL] [ORNL

2014-01-01T23:59:59.000Z

132

High-pressure dissociation of silver mercury iodide, Ag{sub 2}HgI{sub 4}  

SciTech Connect (OSTI)

High-pressure X-ray diffraction has been used to probe the behavior of the superionic conductor silver mercury iodide (Ag{sub 2}HgI{sub 4}) at pressures up to 5GPa and at temperatures from 295 to 370K. Significant changes in the diffraction spectra, indicative of structural transitions, are observed around 0.7 and 1.3GPa across the range of temperatures studied. The change at 0.7GPa is shown to correspond to the dissociation of silver mercury iodide into silver iodide and mercury iodide, i.e., Ag{sub 2}HgI{sub 4}->2AgI+HgI{sub 2}. The second transition, at 1.3GPa, is due to a structural phase transition within HgI{sub 2}. Rietveld analysis of the diffraction data is used to confirm and refine all the known crystal structures.

Parfitt, D.C. [Department of Physics, Oxford University, Parks Road, Oxford OX1 3PU (United Kingdom); Hull, S. [ISIS Facility, Rutherford Appleton Laboratory, Chilton, Didcot, OX11 0QX (United Kingdom)]. E-mail: s.hull@rl.ac.uk; Keen, D.A. [Department of Physics, Oxford University, Parks Road, Oxford OX1 3PU (United Kingdom); ISIS Facility, Rutherford Appleton Laboratory, Chilton, Didcot, OX11 0QX (United Kingdom); Crichton, W. [ESRF, 6 Rue Jules Horowitz, BP 220, 38043 Grenoble CEDEX 9 (France)

2004-10-01T23:59:59.000Z

133

Phases of underpotentially deposited Hg on Au(111): An in situ surface X-ray diffraction study  

SciTech Connect (OSTI)

We report on an in situ surface X-ray diffraction study of the underpotential deposition (UPD) of mercury on Au(111). We have observed three UPD phases present at potentials prior to bulk mercury deposition. These phases consist of two well-ordered intermediate states and what appears to be either a fully discharged two-dimensional liquid Hg layer or a monolayer of an amorphous Hg-Au alloy. Both ordered intermediate phases have hexagonal structures with lattice vectors that are rotated 30{degree} from those of the Au(111) substrate. The first phase (phase I), present at a potential of +0.68 V, was only observed on fresh flame-annealed Au(111) electrodes and appears to be an open incommensurate structure with a lattice constant of 3.86 {+-} 0.03 A. This phase appears to be metastable since it changes to a second ordered phase (phase II) after a certain time. The second phase has a more compact lattice with a = 3.34 {+-} 0.01 A and appears to be a commensurate 2x2 structure with 2/3 of the Hg atoms at threefold hollow sites and 1/3 on atop sites. Similar to the first one, this phase is also metastable and can be transformed to a final, fully discharged, state of a two-dimensional liquid Hg layer or an amorphous Hg-Au alloy. The entire Hg UPD process, from Hg{sup 2+} to the fully discharged metallic Hg layer, agrees well with a multistep mechanism based on previous electrochemical kinetic studies on polycrystalline Au electrodes. 31 refs., 10 figs., 2 tabs.

Li, J.; Abruna, H.D. [Cornell Univ., Ithaca, NY (United States)] [Cornell Univ., Ithaca, NY (United States)

1997-04-10T23:59:59.000Z

134

CdTe AND CdTe : Hg ALLOYS CRYSTAL GROWTH USING STOICHIOMETRIC AND OFF-STOICHIOMETRIC  

E-Print Network [OSTI]

123 CdTe AND CdTe : Hg ALLOYS CRYSTAL GROWTH USING STOICHIOMETRIC AND OFF-STOICHIOMETRIC ZONE.-Briand, 92190 Meudon/Bellevue, France Résumé. 2014 En vue de la croissance de cristaux de CdTe de haute cristaux semi-isolants Cd0, 9Hg0, 1Te. Abstract. 2014 Some aspects of the thermodynamic state of CdTe

Paris-Sud XI, Université de

135

Ultrasensitive detection of Hg{sup 2+} using oligonucleotide-functionalized AlGaN/GaN high electron mobility transistor  

SciTech Connect (OSTI)

An oligonucleotide-functionalized ion sensitive AlGaN/GaN high electron mobility transistor (HEMT) was fabricated to detect trace amounts of Hg{sup 2+}. The advantages of ion sensitive AlGaN/GaN HEMT and highly specific binding interaction between Hg{sup 2+} and thymines were combined. The current response of this Hg{sup 2+} ultrasensitive transistor was characterized. The current increased due to the accumulation of Hg{sup 2+} ions on the surface by the highly specific thymine-Hg{sup 2+}-thymine recognition. The dynamic linear range for Hg{sup 2+} detection has been determined in the concentrations from 10{sup ?14} to 10{sup ?8} M and a detection limit below 10{sup ?14} M level was estimated, which is the best result of AlGaN/GaN HEMT biosensors for Hg{sup 2+} detection till now.

Cheng, Junjie [Key Laboratory of Ion Beam Bioengineering, Hefei Institutes of Physical Science, Chinese Academy of Sciences, Hefei 230031 (China); Division of Nanobiomedicine, Key Laboratory for Nano-Bio Interface Research, Suzhou Institute of Nano-Tech and Nano-Bionics, Chinese Academy of Sciences, Suzhou 215123 (China); Li, Jiadong; Miao, Bin; Wu, Dongmin, E-mail: dmwu2008@sinano.ac.cn [i-Lab, Suzhou Institute of Nano-Tech and Nano-Bionics, Chinese Academy of Sciences, Suzhou 215125 (China); Key Laboratory of Nanodevices and Applications, Suzhou Institute of Nano-Tech and Nano-Bionics, Chinese Academy of Sciences, Suzhou 215123 (China); Wang, Jine; Pei, Renjun, E-mail: rjpei2011@sinano.ac.cn [Division of Nanobiomedicine, Key Laboratory for Nano-Bio Interface Research, Suzhou Institute of Nano-Tech and Nano-Bionics, Chinese Academy of Sciences, Suzhou 215123 (China); Wu, Zhengyan, E-mail: zywu@ipp.ac.cn [Key Laboratory of Ion Beam Bioengineering, Hefei Institutes of Physical Science, Chinese Academy of Sciences, Hefei 230031 (China)

2014-08-25T23:59:59.000Z

136

Data-based estimates of suboxia, denitrification, and N2O production in the ocean and their sensitivities to dissolved O2  

E-Print Network [OSTI]

pathways, N2O is a powerful greenhouse gas that affects the Earth's energy balance and climate. The ocean

137

High resolution n = 3 to n = 2 spectra of neon-like silver  

SciTech Connect (OSTI)

Spectra of the n = 3 to n = 2 transitions in neon-like silver emitted from the Princeton Large Torus have been recorded with a high-resolution Bragg-crystal spectrometer. The measurements cover the wavelength region 3.3 to 4.1 A and include the forbidden 3p ..-->.. 2p electric quadrupole lines. Transitions in the adjacent sodium-like, and aluminum-like charge states of silver have also been observed and identified. The Ly-..cap alpha.. spectra of hydrogen-like argon and iron, the K..cap alpha.. spectra of helium-like argon, potassium, manganese, and iron, and the K..beta.. spectrum of helium-like argon fall in the same wavelength region in first or second order and have been measured concurrently. These spectra provide a coherent set of wavelength reference data obtained with the same spectrometer and from the same tokamak. This set is used as a basis to compare wavelength predictions for one- and two-electron systems to each other and to determine the transition energies of the silver lines with great accuracy.

Beiersdorfer, P.; Bitter, M.; von Goeler, S.; Cohen, S.; Hill, K.W.; Timberlake, J.; Walling, R.S.; Chen, M.H.; Hagelstein, P.L.; Scofield, J.H.

1986-04-01T23:59:59.000Z

138

Intrinsic Spin Hall Effect Induced by Quantum Phase Transition in HgCdTe Quantum Wells  

SciTech Connect (OSTI)

Spin Hall effect can be induced both by the extrinsic impurity scattering and by the intrinsic spin-orbit coupling in the electronic structure. The HgTe/CdTe quantum well has a quantum phase transition where the electronic structure changes from normal to inverted. We show that the intrinsic spin Hall effect of the conduction band vanishes on the normal side, while it is finite on the inverted side. This difference gives a direct mechanism to experimentally distinguish the intrinsic spin Hall effect from the extrinsic one.

Yang, Wen; Chang, Kai; /Beijing, Inst. Semiconductors; Zhang, Shou-Cheng; /Stanford U., Phys. Dept.

2010-03-19T23:59:59.000Z

139

Vibrational Spectroscopy of Mass Selected [UO2(ligand)n]2+ Complexes in the Gas Phase  

SciTech Connect (OSTI)

The gas-phase infrared spectra of discrete uranyl ([UO2]2+) complexes ligated with acetone and/or acetonitrile were used to evaluate systematic trends of ligation on the position of the O=U=O stretch, and to enable rigorous comparison with the results of computational studies. Ionic uranyl complexes isolated in a Fourier transform ion cyclotron resonance mass spectrometer were fragmented via infrared multiphoton dissociation using a free electron laser scanned over the mid-IR wavelengths. The asymmetric O=U=O stretching frequency was measured at 1017 cm-1 for [UO2(CH3COCH3)2]2+, and was systematically red shifted to 1000 and 988 cm-1 by the addition of a third and fourth acetone ligands, respectively, which was consistent with more donation of electron density to the uranium center in complexes with higher coordination number. The experimental measurements were in good agreement with values generated computationally using LDA, B3LYP, and ZORA-PW91 approaches. In contrast to the uranyl frequency shifts, the carbonyl frequencies of the acetone ligands were progressively blue shifted as the number of ligands increased from 2 to 4, and approached that of free acetone. This observation was consistent with the formation of weaker noncovalent bonds between uranium and the carbonyl oxygen as the extent of ligation increases. Similar trends were observed for [UO2(CH3CN)n]2+ complexes although the magnitude of the red shift in the uranyl frequency upon addition more acetonitrile ligands was smaller than for acetone, consistent with the more modest nucleophilic nature of acetonitrile. This conclusion was amplified by the uranyl stretching frequencies measured for mixed acetone/acetonitrile complexes, which showed that substitution of one acetone for one acetonitrile produced a modest red shift of 3 to 6 cm-1.

Gary S. Groenewold; Anita Gianotto; Michael Vanstipdonk; Kevin C. Cossel; David T. Moore,; Nick Polfer; Jos Oomens

2006-03-01T23:59:59.000Z

140

Report on International Collaboration Involving the FE Heater and HG-A Tests at Mont Terri  

SciTech Connect (OSTI)

Nuclear waste programs outside of the US have focused on different host rock types for geological disposal of high-level radioactive waste. Several countries, including France, Switzerland, Belgium, and Japan are exploring the possibility of waste disposal in shale and other clay-rich rock that fall within the general classification of argillaceous rock. This rock type is also of interest for the US program because the US has extensive sedimentary basins containing large deposits of argillaceous rock. LBNL, as part of the DOE-NE Used Fuel Disposition Campaign, is collaborating on some of the underground research laboratory (URL) activities at the Mont Terri URL near Saint-Ursanne, Switzerland. The Mont Terri project, which began in 1995, has developed a URL at a depth of about 300 m in a stiff clay formation called the Opalinus Clay. Our current collaboration efforts include two test modeling activities for the FE heater test and the HG-A leak-off test. This report documents results concerning our current modeling of these field tests. The overall objectives of these activities include an improved understanding of and advanced relevant modeling capabilities for EDZ evolution in clay repositories and the associated coupled processes, and to develop a technical basis for the maximum allowable temperature for a clay repository. The R&D activities documented in this report are part of the work package of natural system evaluation and tool development that directly supports the following Used Fuel Disposition Campaign (UFDC) objectives: ? Develop a fundamental understanding of disposal-system performance in a range of environments for potential wastes that could arise from future nuclear-fuel-cycle alternatives through theory, simulation, testing, and experimentation. ? Develop a computational modeling capability for the performance of storage and disposal options for a range of fuel-cycle alternatives, evolving from generic models to more robust models of performance assessment. For the purpose of validating modeling capabilities for thermal-hydro-mechanical (THM) processes, we developed a suite of simulation models for the planned full-scale FE Experiment to be conducted in the Mont Terri URL, including a full three-dimensional model that will be used for direct comparison to experimental data once available. We performed for the first time a THM analysis involving the Barcelona Basic Model (BBM) in a full three-dimensional field setting for modeling the geomechanical behavior of the buffer material and its interaction with the argillaceous host rock. We have simulated a well defined benchmark that will be used for codeto- code verification against modeling results from other international modeling teams. The analysis highlights the complex coupled geomechanical behavior in the buffer and its interaction with the surrounding rock and the importance of a well characterized buffer material in terms of THM properties. A new geomechanical fracture-damage model, TOUGH-RBSN, was applied to investigate damage behavior in the ongoing HG-A test at Mont Terri URL. Two model modifications have been implemented so that the Rigid-Body-Spring-Network (RBSN) model can be used for analysis of fracturing around the HG-A microtunnel. These modifications are (1) a methodology to compute fracture generation under compressive stress conditions and (2) a method to represent anisotropic elastic and strength properties. The method for computing fracture generation under compressive load produces results that roughly follow trends expected for homogeneous and layered systems. Anisotropic properties for the bulk rock were represented in the RBSN model using layered heterogeneity and gave bulk material responses in line with expectations. These model improvements were implemented for an initial model of fracture damage at the HG-A test. While the HG-A test model results show some similarities with the test observations, differences between the model results and observations remain.

Houseworth, Jim; Rutqvist, Jonny; Asahina, Daisuke; Chen, Fei; Vilarrasa, Victor; Liu, Hui-Hai; Birkholzer, Jens

2013-11-06T23:59:59.000Z

Note: This page contains sample records for the topic "n2 h2s hg" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Jeffrey R. Row Environment and Resource Studies, University of Waterloo, Waterloo, Ontario, Canada, N2L 3G1  

E-Print Network [OSTI]

, N2L 3G1 Website: http://jeffrow.ca · Email: jeff.row@me.com · Phone: 1-416-399-3066 1 Education 2006 and population structure of foxsnakes across spatial and temporal scales. 2003-2005 M.Sc. Biology, University (Lampropeltis triangulum). 1997-2001 B.Sc. Environmental Biology, Queen's University, Kingston, Ontario. 2

Row, Jeffrey R.

142

Impacts of Fertilization on Rates of Autotrophic N2 Fixation in Salt Marshes and Cranberry Bogs of Massachusetts  

E-Print Network [OSTI]

Impacts of Fertilization on Rates of Autotrophic N2 Fixation in Salt Marshes and Cranberry Bogs fixation in salt marshes and cranberry bogs of MA. I measured pools of NH4, NO3, and PO4, in addition to total C and N content of the soils of salt marshes and cranberry bogs, each under two different

Vallino, Joseph J.

143

Qualitative analysis of Zircaloy-4 cladding air degradation in O2-N2 mixtures at high temperature  

E-Print Network [OSTI]

. Thermogravimetry, optical microscopy, scanning electron microscopy and energy dispersive X-ray spectrometry1 Qualitative analysis of Zircaloy-4 cladding air degradation in O2-N2 mixtures at high temperature Email: M. Lasserre (marina.lasserre@irsn.fr) Keywords: Zircaloy-4; thermogravimetry; high temperature

Boyer, Edmond

144

Probing the Vibrational Relaxation of N2 and O2 by Use of CARS Spectroscopy to Model NTE-Turbulence  

E-Print Network [OSTI]

-thermochemical equilibrium (NTE) exists downstream of strong shock fronts and encountered in the shear layers from hypersonic flight, and coupled with turbulence, it has significant effects on flow dynamics. NTE, characterized by high vibrational temperatures of N2 and O2...

Dean, Jacob

2009-06-09T23:59:59.000Z

145

Memorandum, CH2M HG Idaho, LLC, Request for Variance to Title 10 Code of Federal Regulations part 851, "Worker Safety and Health"  

Broader source: Energy.gov [DOE]

CH2M HG Idaho, LLC, Request for Variance to Title 10 Code of Federal Regulations part 851, "Worker Safety and Health"

146

Abundance analysis of SB2 binary stars with HgMn primaries  

E-Print Network [OSTI]

We present a short review of the abundances in the atmospheres of SB2 systems with Mercury-Manganese (HgMn) primaries. Up to now a careful study has been made for both components of 8 out of 17 known SB2 binaries with orbital periods shorter than 100 days and mass ratio ranging from 1.08 to 2.2. For all eight systems we observe a lower Mn abundance in the secondary's atmospheres than in the primary's. Significant difference in the abundances is also found for some peculiar elements such as Ga, Xe, Pt. All secondary stars with effective temperatures less than 10000 K show abundance characteristics typical of the metallic-line stars.

T. Ryabchikova

1998-05-06T23:59:59.000Z

147

Determination of the cross sections of (n,2n), (n,gamma) nuclear reactions on germanium isotopes at the energy of neutrons 13.96 MeV  

E-Print Network [OSTI]

The cross sections of 70Ge(n,2n)69Ge, 72Ge(n,2n)71Ge, 76Ge(n,gamma)77(g+0.21m)Ge, 76Ge(n,2n)75Ge nuclear reactions were measured at the energy of neutrons 13.96(6) MeV by activation method with gamma-ray and X-ray spectra studies.

S. V. Begun; O. G. Druzheruchenko; O. O. Pupirina; V. K. Tarakanov

2007-01-23T23:59:59.000Z

148

Le gisement Ag Hg de Zgounder (Jebel Siroua, Anti-Atlas, Maroc) : un pithermal noprotrozoque de type  

E-Print Network [OSTI]

Le gisement Ag Hg de Zgounder (Jebel Siroua, Anti- Atlas, Maroc) : un épithermal néoprotérozoïque Compagnie minière de Touissit (CMT), 279, bd Zerktouni, Casablanca, Maroc Abstract The Zgounder ore deposit and more as a silver metallogenic province Résumé Le gisement argentifère de Zgounder (Anti-Atlas, Maroc

Paris-Sud XI, Université de

149

Exploiting the Higher Specificity of Silver Amalgamation: Selective Detection of Mercury(II) by Forming Ag/Hg Amalgam  

E-Print Network [OSTI]

, 32611-7200, United States *S Supporting Information ABSTRACT: Heavy metal ion pollution poses severe and biological samples. Contamination of the environment with heavy metal ions has been an important concern selective for Hg2+ and does not respond to other metal ions with up to millimolar concentration levels

Tan, Weihong

150

Demonstrating the Model Nature of the High-Temperature Superconductor HgBa2CuO4+d  

SciTech Connect (OSTI)

The compound HgBa{sub 2}CuO{sub 4+{delta}} (Hg1201) exhibits a simple tetragonal crystal structure and the highest superconducting transition temperature (T{sub c}) among all single Cu-O layer cuprates, with T{sub c} = 97 K (onset) at optimal doping. Due to a lack of sizable single crystals, experimental work on this very attractive system has been significantly limited. Thanks to a recent breakthrough in crystal growth, such crystals have now become available. Here, we demonstrate that it is possible to identify suitable heat treatment conditions to systematically and uniformly tune the hole concentration of Hg1201 crystals over a wide range, from very underdoped (T{sub c} = 47 K, hole concentration p {approx} 0.08) to overdoped (T{sub c} = 64 K, p {approx} 0.22). We then present quantitative magnetic susceptibility and DC charge transport results that reveal the very high-quality nature of the studied crystals. Using XPS on cleaved samples, we furthermore demonstrate that it is possible to obtain large surfaces of good quality. These characterization measurements demonstrate that Hg1201 should be viewed as a model high-temperature superconductor, and they provide the foundation for extensive future experimental work.

Barisic, Neven; Li, Yuan; Zhao, Xudong; Cho, Yong-Chan; Chabot-Couture, Guillaume; Yu, Guichuan; Greven, Martin; /SLAC, SSRL /Boskovic Inst., Zagreb /Stanford U., Phys. Dept. /Jilin U. /Stanford U., Appl. Phys. Dept.

2008-09-30T23:59:59.000Z

151

Diagnosing ions and neutrals via n=2 excited hydrogen atoms in plasmas with high electron density and low electron temperature  

SciTech Connect (OSTI)

Ion and neutral parameters are determined in the high electron density, magnetized, hydrogen plasma beam of an ITER divertor relevant plasma via measurements of the n=2 excited neutrals. Ion rotation velocity (up to 7 km/s) and temperature (2-3 eV{approx}T{sub e}) are obtained from analysis of H{alpha} spectra measured close to the plasma source. The methodology for neutral density determination is explained whereby measurements in the linear plasma beam of Pilot-PSI are compared to modeling. Ground-state atomic densities are obtained via the production rate of n=2 and the optical thickness of the Lyman-{alpha} transition (escape factor {approx}0.6) and yield an ionization degree >85% and dissociation degree in the residual gas of {approx}4%. A 30% proportion of molecules with a rovibrational excitation of more than 2 eV is deduced from the production rate of n=2 atoms. This proportion increases by more than a factor of 4 for a doubling of the electron density in the transition to ITER divertor relevant electron densities, probably because of a large increase in the production and confinement of ground-state neutrals. Measurements are made using laser-induced fluorescence (LIF) and absorption, the suitability of which are evaluated as diagnostics for this plasma regime. Absorption is found to have a much better sensitivity than LIF, mainly owing to competition with background emission.

Shumack, A. E.; Schram, D. C.; Biesheuvel, J.; Goedheer, W. J.; Rooij, G. J. van [FOM-Institute for Plasma Physics Rijnhuizen, Association EURATOM-FOM, Trilateral Euregio Cluster, Nieuwegein (Netherlands)

2011-03-15T23:59:59.000Z

152

Removal of elemental mercury (Hg(0)) by nanosized V{sub 2}O{sub 5}/TiO{sub 2} catalysts  

SciTech Connect (OSTI)

Novel reactive nanosized V{sub 2}O{sub 5}/TiO{sub 2} catalysts (aerogel, xerogel, and impregnated catalysts) for the removal of Hg{sup 0} and their synthesis methods have been introduced in this research. Aerogel catalyst has the highest surface area among the catalysts synthesized in this research and contained reactive monovanadates on its surfaces resulting in higher reactivity for the Hg{sup 0} removal than impregnated and selective catalytic reduction catalysts. XPS analyses on the surfaces of nanosized catalysts after the removal of Hg{sup 0} suggest that adsorbed Hg{sup 0} oxidatively transformed to Hg{sup O} by surface vanadates (mono- and poly vanadates), consistent with the Mars-Maessen mechanism. Early column breakthrough has been observed at temperatures above 300{sup o}C due mainly to the desorption of Hg{sup 0} from the catalyst surfaces. The decrease in Hg{sup 0} concentration and increase in catalyst content in a column reactor have increased the removal of Hg{sup 0}, indicating that the removal is a heterogeneous surface-limited reaction. At 400{sup o}C, the catalysts under air flow have shown a higher Hg{sup 0} removal because gas-phase oxygen from the flow could provide an oxygen-rich environment for producing more oxidized vanadate species on their surfaces. No significant difference in the Hg{sup 0} removal between different gas types (nitrogen and air) has been observed at 100{sup o}C. 27 refs., 5 figs.

Lee, W.; Bae, G.N. [Korea Advanced Institute of Science and Technology, Daejeon (Republic of Korea)

2009-03-01T23:59:59.000Z

153

SYNTHESIS OF THE FULLY PROTECTED PHOSPHORAMIDITE OF THE BENZENE-DNA ADDUCT, N2- (4-HYDROXYPHENYL)-2'-DEOXYGUANOSINE AND INCORPORATION OF THE LATER INTO DNA OLIGOMERS  

SciTech Connect (OSTI)

N2-(4-Hydroxyphenyl)-2'-deoxyguanosine-5'-O-DMT-3'-phosphoramidite has been synthesized and used to incorporate the N2-(4-hydroxyphenyl)-2'-dG (N2-4-HOPh-dG) into DNA, using solid-state synthesis technology. The key step to obtaining the xenonucleoside is a palladium (Xantphos-chelated) catalyzed N2-arylation (Buchwald-Hartwig reaction) of a fully protected 2'-deoxyguanosine derivative by 4-isobutyryloxybromobenzene. The reaction proceeded in good yield and the adduct was converted to the required 5'-O-DMT-3'-O-phosphoramidite by standard methods. The latter was used to synthesize oligodeoxynucleotides in which the N2-4-HOPh-dG adduct was incorporated site-specifically. The oligomers were purified by reverse-phase HPLC. Enzymatic hydrolysis and HPLC analysis confirmed the presence of this adduct in the oligomers.

Chenna, Ahmed; Gupta, Ramesh C.; Bonala, Radha R.; Johnson, Francis; Huang, Bo

2008-06-09T23:59:59.000Z

154

Modeling of fate and transport of co-injection of H2S with CO2 in deep saline formations  

E-Print Network [OSTI]

operation in a depleted sandstone oil reservoir on theformations, and depleted oil or gas reservoirs, for allinclude depleted or depleting oil and gas reservoirs, un-

Zhang, W.

2011-01-01T23:59:59.000Z

155

Combined Theoretical and Experimental Investigation and Design of H2S Tolerant Anode for Solid Oxide Fuel Cells  

SciTech Connect (OSTI)

A solid oxide fuel cell (SOFC) is a high temperature fuel cell and it normally operates in the range of 850 to 1000 C. Coal syngas has been considered for use in SOFC systems to produce electric power, due to its high temperature and high hydrogen and carbon monoxide content. However, coal syngas also has contaminants like carbon dioxide (CO{sub 2}) and hydrogen sulfide (H{sub 2}S). Among these contaminants, H{sub 2}S is detrimental to electrode material in SOFC. Commonly used anode material in SOFC system is nickel-yttria stabilized zirconia (Ni-YSZ). The presence of H{sub 2}S in the hydrogen stream will damage the Ni anode and hinder the performance of SOFC. In the present study, an attempt was made to understand the mechanism of anode (Ni-YSZ) deterioration by H{sub 2}S. The study used computation methods such as quantum chemistry calculations and molecular dynamics to predict the model for anode destruction by H{sub 2}S. This was done using binding energies to predict the thermodynamics and Raman spectroscopy to predict molecular vibrations and surface interactions. On the experimental side, a test stand has been built with the ability to analyze button cells at high temperature under syngas conditions.

Gerardine G. Botte; Damilola Daramola; Madhivanan Muthuvel

2009-01-07T23:59:59.000Z

156

Modeling of fate and transport of co-injection of H2S with CO2 in deep saline formations  

SciTech Connect (OSTI)

The geological storage of CO{sub 2} in deep saline formations is increasing seen as a viable strategy to reduce the release of greenhouse gases into the atmosphere. However, costs of capture and compression of CO{sub 2} from industrial waste streams containing small quantities of sulfur and nitrogen compounds such as SO{sub 2}, H{sub 2}S and N{sub 2} are very expensive. Therefore, studies on the co-injection of CO{sub 2} containing other acid gases from industrial emissions are very important. In this paper, numerical simulations were performed to study the co-injection of H{sub 2}S with CO{sub 2} in sandstone and carbonate formations. Results indicate that the preferential dissolution of H{sub 2}S gas (compared with CO{sub 2} gas) into formation water results in the delayed breakthrough of H{sub 2}S gas. Co-injection of H{sub 2}S results in the precipitation of pyrite through interactions between the dissolved H{sub 2}S and Fe{sup 2+} from the dissolution of Fe-bearing minerals. Additional injection of H{sub 2}S reduces the capabilities for solubility and mineral trappings of CO{sub 2} compared to the CO{sub 2} only case. In comparison to the sandstone (siliciclastic) formation, the carbonate formation is less favorable to the mineral sequestration of CO{sub 2}. Different from CO{sub 2} mineral trapping, the presence of Fe-bearing siliciclastic and/or carbonate is more favorable to the H{sub 2}S mineral trapping.

Zhang, W.; Xu, T.; Li, Y.

2010-12-15T23:59:59.000Z

157

A dsorption of H2 S or SO2 on an activated carbon cloth modified by ammonia treatment  

E-Print Network [OSTI]

Recent studies have reported that activated carbon fibers, such as PAN-ACF [1] or Nomex-ACF [2], have for the recovery of sulfuric acid compared to granular activated carbon because the diffusion of sulfuric acid rarely been investigated to improve the performance of activated carbon fibers for the removal of SO2

Paris-Sud XI, Université de

158

Synthesis and Characterization of CO-and H2S-Tolerant Electrocatalysts for PEM Fuel Cell  

SciTech Connect (OSTI)

The present state-of-art Proton Exchange Membrane Fuel Cell (PEMFC) technology is based on platinum (Pt) as a catalyst for both the fuel (anode) and air (cathode) electrodes. This catalyst is highly active but susceptible to poisoning by CO, which may be present in the H{sub 2}-fuel used or may be introduced during the fuel processing. Presence of trace amount of CO and H{sub 2}S in the H{sub 2}-fuel poisons the anode irreversibly and decreases the performance of the PEMFCs. In an effort to reduce the Pt-loading and improve the PEMFC performance, we propose to synthesize a number of Pt-based binary, ternary, and quaternary electrocatalysts using Ru, Mo, Ir, Ni, and Co as a substitute for Pt. By fine-tuning the metal loadings and compositions of candidate electrocatalysts, we plan to minimize the cost and optimize the catalyst activity and performance in PEMFC. The feasibility of the novel electrocatalysts will be demonstrated in the proposed effort with gas phase CO and H{sub 2}S concentrations typical of those found in reformed fuel gas with coal/natural gas/methanol feedstocks. During this reporting period we synthesized four Pt-based electrocatalysts catalysts (Pt/Ru/Mo/Se, Pt/Ru/Mo/Ir, Pt/Ru/Mo/W, Ptr/Ru/Mo/Co) on Vulcan XG72 Carbon support by both conventional and ultra-sonication method. From current-voltage performance study, the catalytic activity was found in the increasing order of Pt/Ru/Mo/Ir > Pt/Ru/Mo/W > Pt/Ru/Mo/Co > Pt/Ru/MO/Se. Sonication method appears to provide better dispersion of catalysts on carbon support.

Shamsuddin Ilias

2005-12-22T23:59:59.000Z

159

SYNTHESIS AND CHARACTERIZATION OF CO-AND H2S-TOLERANT ELECTROCATALYSTS FOR PEM FUEL CELL  

SciTech Connect (OSTI)

The present state-of-art Proton Exchange Membrane Fuel Cell (PEMFC) technology is based on platinum (Pt) as a catalyst for both the fuel (anode) and air (cathode) electrodes. This catalyst is highly active but susceptible to poisoning by CO, which may be present in the H{sub 2}-fuel used or may be introduced during the fuel processing. Presence of trace amount of CO and H{sub 2}S in the H{sub 2}-fuel poisons the anode irreversibly and decreases the performance of the PEMFCs. In an effort to reduce the Pt-loading and improve the PEMFC performance, we propose to synthesize a number of Pt-based binary, ternary, and quaternary electrocatalysts using Ru, Mo, Ir, Ni, and Co as a substitute for Pt. By fine-tuning the metal loadings and compositions of candidate electrocatalysts, we plan to minimize the cost and optimize the catalyst activity and performance in PEMFC. The feasibility of the novel electrocatalysts will be demonstrated in the proposed effort with gas phase CO and H{sub 2}S concentrations typical of those found in reformed fuel gas with coal/natural gas/methanol feedstocks. During this reporting period several bi-metallic electrocatalysts were synthesized and tested in MEAs. From Galvonstatic study the catalytic activity was found in the order of: Pt/Ru/C > Pt/Mo/C > Pt/Ir/C > Pt/Ni/C > Pt/Cr/C. Work in progress to further study these catalysts for CO-tolerance in PEMFC and identify potential candidate metals for synthesis of trimetallic electrocatalysts.

Shamsuddin Ilias

2004-03-31T23:59:59.000Z

160

SYNTHESIS AND CHARACTERIZATION OF CO-AND H2S-TOLERANT ELECTROCATALYSTS FOR PEM FUEL CELL  

SciTech Connect (OSTI)

The present state-of-art Proton Exchange Membrane Fuel Cell (PEMFC) technology is based on platinum (Pt) as a catalyst for both the fuel (anode) and air (cathode) electrodes. This catalyst is highly active but susceptible to poisoning by CO, which may be present in the H{sub 2}-fuel used or may be introduced during the fuel processing. Presence of trace amount of CO and H{sub 2}S in the H{sub 2}-fuel poisons the anode irreversibly and decreases the performance of the PEMFCs. In an effort to reduce the Pt-loading and improve the PEMFC performance, we propose to synthesize a number of Pt-based binary, ternary, and quaternary electrocatalysts using Ru, Mo, Ir, Ni, and Co as a substitute for Pt. By fine-tuning the metal loadings and compositions of candidate electrocatalysts, we plan to minimize the cost and optimize the catalyst activity and performance in PEMFC. The feasibility of the novel electrocatalysts will be demonstrated in the proposed effort with gas phase CO and H{sub 2}S concentrations typical of those found in reformed fuel gas with coal/natural gas/methanol feedstocks. During this reporting period several bi-metallic electrocatalysts were synthesized using ultra-sonication. These catalysts (Pt/Ru, Pt/Mo and Pt/Ir) were tested in MEAs. From Galvonstatic study the catalytic activity was found in the order of: Pt/Ru/C > Pt/Mo/C > Pt/Ir/C. It appears that electrocatalysts prepared by ultra-sonication process are more active compared to the conventional technique. Work is in progress to further study these catalysts for CO-tolerance in PEMFC and identify potential candidate metals for synthesis of tri-metallic electrocatalysts.

Shamsuddin Ilias

2005-03-29T23:59:59.000Z

Note: This page contains sample records for the topic "n2 h2s hg" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Highly Attrition Resistant Zinc Oxide-Based Sorbents for H2S Removal by Spray Drying Technique  

SciTech Connect (OSTI)

Primary issues for the fluidized-bed/transport reactor process are high attrition resistant sorbent, its high sorption capacity and regenerability, durability, and cost. The overall objective of this project is the development of a superior attrition resistant zinc oxide-based sorbent for hot gas cleanup in integrated coal gasification combined cycle (IGCC). Sorbents applicable to a fluidized-bed hot gas desulfurization process must have a high attrition resistance to withstand the fast solid circulation between a desulfurizer and a regenerator, fast kinetic reactions, and high sulfur sorption capacity. The oxidative regeneration of zinc-based sorbent usually initiated at greater than 600 C with highly exothermic nature causing deactivation of sorbent as well as complication of sulfidation process by side reaction. Focusing on solving the sorbent attrition and regenerability of zinc oxide-based sorbent, we have adapted multi-binder matrices and direct incorporation of regeneration promoter. The sorbent forming was done with a spray drying technique that is easily scalable to commercial quantity.

Ryu, C.K.; Lee, J.B.; Ahn, D.H.; Kim, J.J.; Yi, C.K.

2002-09-19T23:59:59.000Z

162

ICARUS91, 220--233(1991) Possible Microwave Absorption by H2S Gas in Uranus' and  

E-Print Network [OSTI]

, University of Michigan, Ann Arbor, Michigan 48109 ReceivedMay25, 1990;revisedFebruary12, 1991 We present new the solar sulfur elemental ratio, and that the S/Nratio must exceed 5 x the solar ratio. Our calculations by a factor of -50 compared to the solar N value throughout the region of the atmosphere probed at centimeter

Atreya, Sushil

163

Injection of CO2 with H2S and SO2 and Subsequent Mineral Trapping in Sandstone-Shale Formation  

SciTech Connect (OSTI)

Carbon dioxide (CO{sub 2}) injection into deep geologic formations can potentially reduce atmospheric emissions of greenhouse gases. Sequestering less-pure CO{sub 2} waste streams (containing H{sub 2}S and/or SO{sub 2}) would be less expensive or would require less energy than separating CO{sub 2} from flue gas or a coal gasification process. The long-term interaction of these injected acid gases with shale-confining layers of a sandstone injection zone has not been well investigated. We therefore have developed a conceptual model of injection of CO{sub 2} with H{sub 2}S and/or SO{sub 2} into a sandstone-shale sequence, using hydrogeologic properties and mineral compositions commonly encountered in Gulf Coast sediments of the United States. We have performed numerical simulations of a 1-D radial well region considering sandstone alone and a 2-D model using a sandstone-shale sequence under acid-gas injection conditions. Results indicate that shale plays a limited role in mineral alteration and sequestration of gases within a sandstone horizon for short time periods (10,000 years in present simulations). The co-injection of SO{sub 2} results in different pH distribution, mineral alteration patterns, and CO{sub 2} mineral sequestration than the co-injection of H{sub 2}S or injection of CO{sub 2} alone. Simulations generate a zonal distribution of mineral alteration and formation of carbon and sulfur trapping minerals that depends on the pH distribution. The co-injection of SO{sub 2} results in a larger and stronger acidified zone close to the well. Precipitation of carbon trapping minerals occurs within the higher pH regions beyond the acidified zones. In contrast, sulfur trapping minerals are stable at low pH ranges (below 5) within the front of the acidified zone. Corrosion and well abandonment due to the co-injection of SO{sub 2} could be important issues. Significant CO{sub 2} is sequestered in ankerite and dawsonite, and some in siderite. The CO{sub 2} mineral-trapping capability can reach 80 kg per cubic meter of medium. Most sulfur is trapped through alunite precipitation, although some is trapped by anhydrite precipitation and minor amount of pyrite. The addition of the acid gases and induced mineral alteration result in changes in porosity. The limited information currently available on the mineralogy of natural high-pressure acid-gas reservoirs is generally consistent with our simulations.

Xu, Tianfu; Apps, John A.; Pruess, Karsten; Yamamoto, Hajime

2004-09-07T23:59:59.000Z

164

Dimensionality-induced insulator-metal crossover in layered nickelates La{sub n+1}Ni{sub n}O{sub 2n+2} (n = 2, 3, and ?)  

SciTech Connect (OSTI)

Low-valence layered nickelates are a structural analog to the superconducting cuprates and possess interesting properties. In this work, we have systematically studied the electronic structure of La{sub n+1}Ni{sub n}O{sub 2n+2} using first-principles calculations. Our results reveal that the Ni-3d 3z{sup 2} ? r{sup 2} orbital state is active and evolves from discrete molecular levels to a continuous solid band and its filling varies as the dimensionality (or n) increases. The two-dimensional (2D) La{sub 3}Ni{sub 2}O{sub 6} and La{sub 4}Ni{sub 3}O{sub 8} are thus found to have a molecular insulating state. In contrast, the 3D LaNiO{sub 2} is metallic and its 3z{sup 2} ? r{sup 2} band surprisingly becomes 3D due to the Ni-La hybridization, and the La-5d xy orbital also forms a 2D metallic band. Therefore, La{sub n+1}Ni{sub n}O{sub 2n+2} is a dimensionality-controlled insulator-metal crossover system.

Liu, Ting; Jia, Ting; Zhang, Xiaoli [Key Laboratory of Materials Physics, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031 (China)] [Key Laboratory of Materials Physics, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031 (China); Wu, Hua, E-mail: wuh@fudan.edu.cn [Laboratory for Computational Physical Sciences (MOE), State Key Laboratory of Surface Physics, and Department of physics, Fudan University, Shanghai 200433 (China)] [Laboratory for Computational Physical Sciences (MOE), State Key Laboratory of Surface Physics, and Department of physics, Fudan University, Shanghai 200433 (China); Zeng, Zhi, E-mail: zzeng@theory.issp.ac.cn [Key Laboratory of Materials Physics, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031 (China) [Key Laboratory of Materials Physics, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031 (China); Hefei National Laboratory for Physical Sciences at Microscale, Department of Physics, University of Science and Technology of China, Hefei 230026 (China); Lin, H. Q. [Beijing Computational Science Research Center, Beijing 100084 (China)] [Beijing Computational Science Research Center, Beijing 100084 (China); Li, X. G. [Hefei National Laboratory for Physical Sciences at Microscale, Department of Physics, University of Science and Technology of China, Hefei 230026 (China)] [Hefei National Laboratory for Physical Sciences at Microscale, Department of Physics, University of Science and Technology of China, Hefei 230026 (China)

2014-04-15T23:59:59.000Z

165

On N = 2 compactifications of M-theory to AdS{sub 3} using geometric algebra techniques  

SciTech Connect (OSTI)

We investigate the most general warped compactification of eleven-dimensional supergravity on eight-dimensional manifolds to AdS{sub 3} spaces (in the presence of non-vanishing four-form flux) which preserves N = 2 supersymmetry in three dimensions. Without imposing any restrictions on the chirality of the internal part of the supersymmetry generators, we use geometric algebra techniques to study some implications of the supersymmetry constraints. In particular, we discuss the Lie bracket of certain vector fields constructed as pinor bilinears on the compactification manifold.

Babalic, E. M.; Coman, I. A.; Condeescu, C.; Micu, A. [IFIN-HH, Department of Theoretical Physics, 077125 Magurele (Romania); Lazaroiu, C. I. [IFIN-HH, Department of Theoretical Physics, 077125 Magurele, Romania and IBS, Center for Geometry and Physics, and POSTECH, Department of Mathematics, Pohang, Gyeongbuk 790-784 (Korea, Republic of)

2013-11-13T23:59:59.000Z

166

Trap Activation Energy and Transport Parameters of HgI$_2$ Crystals for Bubble-Plasma Diagnostics  

E-Print Network [OSTI]

In recent data on neutron induced acoustic cavitation in deuterium--containing liquids obtained by neutron measurements it was shown that very high temperatures could arise in some special cases. To study temperature of so--called bubble plasma it is desirable to have micro--detectors of X-rays, which can be prepared on the basis of room--temperature semiconductor detectors, in particular on mercuric iodide ($\\alpha$--HgI$_2$) crystals. Having in view this aim, the properties of gel--grown ($\\alpha$--HgI$_2$) crystals was studied by means of isothermal currents, and trap parameters was estimated. Results are promising for special aim of preparing X-ray detectors with moderate energy resolution needed in bubble--plasma diagnostic, though improving of crystal growing technology is necessary. {\\it PACS:} 29.40.Wk; 52.70.La {\\it Keywords:} X-ray and gamma--ray measurements; semiconductor detectors; mercuric iodide; plasma diagnostics; cavitation

M. B. Miller; V. F. Kushniruk; A. V. Sermyagin

2003-01-13T23:59:59.000Z

167

Microstructural evolutions in converting epitaxial Tl2Ba2CaCu2Ox thin films to epitaxial HgBa2CaCu2O6+delta thin films  

E-Print Network [OSTI]

Superconducting HgBa2CaCu2O6+delta (Hg-1212) thin films were obtained from Tl2Ba2CaCu2Ox (Tl-2212) precursor films using a cation-exchange process. In this process, Tl cations on the precursor lattice were thermally excited and then replaced with Hg...

Wu, Judy; Siegal, M. P.; Xie, Y. Y.; Aytug, T.; Fang, L.

2003-02-01T23:59:59.000Z

168

Accretions of Dark Matter and Dark Energy onto ($n+2$)-dimensional Schwarzschild Black Hole and Morris-Thorne Wormhole  

E-Print Network [OSTI]

We have studied accretion of the dark matter and dark energy onto of $(n+2)$-dimensional Schwarzschild black hole and Morris-Thorne wormhole. The mass and the rate of change of mass for $(n+2)$-dimensional Schwarzschild black hole and Morris-Thorne wormhole have been found. We have assumed some candidates of dark energy like holographic dark energy, new agegraphic dark energy, quintessence, tachyon, DBI-essence, etc. The black hole mass and the wormhole mass have been calculated in term of redshift when dark matter and above types of dark energies accrete onto them separately. We have shown that the black hole mass increases and wormhole mass decreases for holographic dark energy, new agegraphic dark energy, quintessence, tachyon accretion and the slope of increasing/decreasing of mass sensitively depends on the dimension. But for DBI-essence accretion, the black hole mass first increases and then decreases and the wormhole mass first decreases and then increases and the slope of increasing/decreasing of mass...

Debnath, Ujjal

2015-01-01T23:59:59.000Z

169

Accretions of Dark Matter and Dark Energy onto ($n+2$)-dimensional Schwarzschild Black Hole and Morris-Thorne Wormhole  

E-Print Network [OSTI]

We have studied accretion of the dark matter and dark energy onto of $(n+2)$-dimensional Schwarzschild black hole and Morris-Thorne wormhole. The mass and the rate of change of mass for $(n+2)$-dimensional Schwarzschild black hole and Morris-Thorne wormhole have been found. We have assumed some candidates of dark energy like holographic dark energy, new agegraphic dark energy, quintessence, tachyon, DBI-essence, etc. The black hole mass and the wormhole mass have been calculated in term of redshift when dark matter and above types of dark energies accrete onto them separately. We have shown that the black hole mass increases and wormhole mass decreases for holographic dark energy, new agegraphic dark energy, quintessence, tachyon accretion and the slope of increasing/decreasing of mass sensitively depends on the dimension. But for DBI-essence accretion, the black hole mass first increases and then decreases and the wormhole mass first decreases and then increases and the slope of increasing/decreasing of mass not sensitively depends on the dimension.

Ujjal Debnath

2015-02-08T23:59:59.000Z

170

Accretions of Dark Matter and Dark Energy onto ($n+2$)-dimensional Schwarzschild Black Hole and Morris-Thorne Wormhole  

E-Print Network [OSTI]

We have studied accretion of the dark matter and dark energy onto of $(n+2)$-dimensional Schwarzschild black hole and Morris-Thorne wormhole. The mass and the rate of change of mass for $(n+2)$-dimensional Schwarzschild black hole and Morris-Thorne wormhole have been found. We have assumed some candidates of dark energy like holographic dark energy, new agegraphic dark energy, quintessence, tachyon, DBI-essence, etc. The black hole mass and the wormhole mass have been calculated in term of redshift when dark matter and above types of dark energies accrete onto them separately. We have shown that the black hole mass increases and wormhole mass decreases for holographic dark energy, new agegraphic dark energy, quintessence, tachyon accretion and the slope of increasing/decreasing of mass sensitively depends on the dimension. But for DBI-essence accretion, the black hole mass first increases and then decreases and the wormhole mass first decreases and then increases and the slope of increasing/decreasing of mass not sensitively depends on the dimension.

Ujjal Debnath

2015-03-06T23:59:59.000Z

171

Structural and optical properties of coreshell Ag{sub 2}S/HgS nanostructures  

SciTech Connect (OSTI)

Graphical abstract: - Highlights: Coreshell Ag{sub 2}S/HgS nanostructures are successfully synthesized. The particle size and the structure were confirmed through TEM images. The absorbance analysis reveals red shift with increasing shell concentration. A transition from TYPE 1 to TYPE 2 coreshell nanostructure is observed. - Abstract: Here we report on a two-step synthesis route for fabrication of coreshell Ag{sub 2}S/HgS nanostructures. Nanoscale Ag{sub 2}S semiconductors are prepared by a standard redox reaction using AgNO{sub 3} and CS{sub 2} as the reactants in PVP. HgS layers are developed on Ag{sub 2}S cores through S-S bonding at the interface separating the two systems. The properties of these coreshell nanostructures are studied via various spectroscopic and microscopic tools like UVVis absorption spectra, photoluminescence spectra, X-ray diffraction pattern and transmission electron microscopic images. Change in optical properties is observed while varying the shell thickness in the sample. A detailed study on the luminescence properties reveal transition from TYPE 1 to TYPE 2 coreshell nanostructures is observed with increasing shell thickness.

Basyach, Priyanka; Choudhury, Amarjyoti, E-mail: ajc@tezu.ernet.in

2013-07-15T23:59:59.000Z

172

Electrical characteristics of the CdTe-n-CdHgTe structure fabricated in a single molecular-beam epitaxy process  

SciTech Connect (OSTI)

An extraordinary shape of the capacitance-voltage characteristics of CdTe-CdHgTe structures has been detected; these characteristics include a specific 'hump' in the inversion region, the height of which increased severalfold under illumination. Additional measurements using an optical probe, measurements of current-voltage characteristics, and an analysis of the energy-band diagram of the structure showed the following. CdTe, in contrast to CdHgTe, is a p-type semiconductor with an acceptor concentration of 1 x 10{sup 16} cm{sup -3}; there is a hole inversion layer in CdHgTe at the boundary with CdTe, which causes the 'hump'; and the barrier height for holes at the CdTe-Cd{sub 0.43}Hg{sub 0.57}Te interface was determined as 0.13 eV.

Mashukov, Yu. P., E-mail: dr_mashukov@mail.ru; Mikhailov, N. N.; Vasilyev, V. V. [Russian Academy of Sciences, Rzhanov Institute of Semiconductor Physics, Siberian Branch (Russian Federation)

2010-09-15T23:59:59.000Z

173

In-situ spectroscopic ellipsometry for real time composition control of Hg{sub 1{minus}x}Cd{sub x}Te grown by molecular beam epitaxy  

SciTech Connect (OSTI)

Spectral ellipsometry (SE) was applied to in situ composition control of Hg{sub 1{minus}x}Cd{sub x}Te grown by molecular beam epitaxy (MBE), and the impact of surface topography of the Hg{sub 1{minus}x}Cd{sub x}Te layers on the accuracy of SE was investigated. Of particular importance is the presence of surface defects, such as voids in MBE-Hg{sub 1{minus}x}Cd{sub x}Te layers. While dislocations do not have any significant impact on the dielectric functions, the experimental data in this work show that MBE-Hg{sub 1{minus}x}Cd{sub x}Te samples having the same composition, but different void densities, have different effective dielectric functions.

Dat, R.; Aqariden, F.; Chandra, D.; Shih, H.D. [Raytheon TI Systems, Sensors and Infrared Lab., Dallas, TX (United States); Duncan, W.M. [Texas Instruments Inc., Dallas, TX (United States). Components and Materials Research Center

1998-12-31T23:59:59.000Z

174

H.G. Okuno and M. Ali (Eds.): IEA/AIE 2007, LNAI 4570, pp. 444453, 2007. Springer-Verlag Berlin Heidelberg 2007  

E-Print Network [OSTI]

H.G. Okuno and M. Ali (Eds.): IEA/AIE 2007, LNAI 4570, pp. 444­453, 2007. © Springer-Verlag Berlin estimated the individuality of fingerprints [1]. Hong, et al. reviewed performance evaluation for #12

Cho, Sung-Bae

175

NANOSENSOR DETECTS MERCURY IN WATER J.-S. Lee, M. S. Han, C. A. Mirkin, "Colorimetric Detection of Mercuric Ion (Hg2+  

E-Print Network [OSTI]

NANOSENSOR DETECTS MERCURY IN WATER J.-S. Lee, M. S. Han, C. A. Mirkin, "Colorimetric Detection ­ 0647560 Mercuric ion (Hg2+ ) is one of the most stable inorganic forms of mercury. It is also a caustic

Shull, Kenneth R.

176

Vapor-liquid equilibria of coal-derived liquids; 3: Binary systems with tetralin at 200 mmHg  

SciTech Connect (OSTI)

Isobaric vapor-liquid equilibrium data are reported for binary systems of tetralin with p-xylene, [gamma]-picoline, piperidine, and pyridine; all systems were measured at 26.66 kPa (200 mmHg) with a recirculation still. Liquid-phase activity coefficients were correlated using the Van Laar, Wilson, NRTL, and UNIQUAC equations. Vapor-phase nonidealities were found negligible under the experimental conditions of this work, and deviations of the liquid phase from the ideal behavior, as described by Raoult's law, were found to be slightly positive for all the systems.

Blanco, B.; Beltran, S.; Cabezas, J.L. (University Coll., Burgos (Spain). Dept. of Chemical Engineering); Coca, J. (Univ. of Oviedo (Spain). Dept. of Chemical Engineering)

1994-01-01T23:59:59.000Z

177

European Journal of Soil Science, December 2010, 61, 903913 doi: 10.1111/j.1365-2389.2009.01217.x Towards an agronomic assessment of N2O emissions  

E-Print Network [OSTI]

Towards an agronomic assessment of N2O emissions: a case study for arable crops J . W . V a n G r o e n i. Commonly, N2O emissions are expressed as a function of N application rate. This suggests that smaller fertilizer applications always lead to smaller N2O emissions. Here we argue that, because of global demand

van Kessel, Chris

178

Rigid Holography and Six-Dimensional N=(2,0) Theories on AdS_5 times S^1  

E-Print Network [OSTI]

Field theories on anti-de Sitter (AdS) space can be studied by realizing them as low-energy limits of AdS vacua of string/M theory. In an appropriate limit, the field theories decouple from the rest of string/M theory. Since these vacua are dual to conformal field theories (CFTs), this relates some of the observables of these field theories on AdS to a subsector of the dual CFTs. We exemplify this `rigid holography' by studying in detail the 6d N=(2,0) A_{K-1} superconformal field theory (SCFT) on AdS_5xS^1, with equal radii for AdS_5 and for S^1. We choose specific boundary conditions preserving sixteen supercharges that arise when this theory is embedded into Type IIB string theory on AdS_5xS^5/Z_K. On R^{4,1}xS^1, this 6d theory has a 5(K-1)-dimensional moduli space, with unbroken 5d SU(K) gauge symmetry at (and only at) the origin. On AdS_5xS^1, the theory has a 2(K-1)-dimensional `moduli space' of supersymmetric configurations. We argue that in this case the SU(K) gauge symmetry is unbroken everywhere in...

Aharony, Ofer; Rey, Soo-Jong

2015-01-01T23:59:59.000Z

179

Hall, Seebeck, and Nernst Coefficients of Underdoped HgBa2CuO4+?: Fermi-Surface Reconstruction in an Archetypal Cuprate Superconductor  

DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

Charge-density-wave order has been observed in cuprate superconductors whose crystal structure breaks the square symmetry of the CuO2 planes, such as orthorhombic YBa2Cu3Oy (YBCO), but not so far in cuprates that preserve that symmetry, such as tetragonal HgBa2CuO4+? (Hg1201). We have measured the Hall (RH), Seebeck (S), and Nernst (?) coefficients of underdoped Hg1201 in magnetic fields large enough to suppress superconductivity. The high-field RH(T) and S(T) are found to drop with decreasing temperature and become negative, as also observed in YBCO at comparable doping. In YBCO, the negative RH and S are signatures of a small electron pocket caused by Fermi-surface reconstruction, attributed to charge-density-wave modulations observed in the same range of doping and temperature. We deduce that a similar Fermi-surface reconstruction takes place in Hg1201, evidence that density-wave order exists in this material. A striking similarity is also found in the normal-state Nernst coefficient ?(T), further supporting this interpretation. Given the model nature of Hg1201, Fermi-surface reconstruction appears to be common to all hole-doped cuprates, suggesting that density-wave order is a fundamental property of these materials.

Doiron-Leyraud, Nicolas; Lepault, S.; Cyr-Choinire, O.; Vignolle, B.; Grissonnanche, G.; Lalibert, F.; Chang, J.; Barii?, N.; Chan, M. K.; Ji, L.; Zhao, X.; Li, Y.; Greven, M.; Proust, C.; Taillefer, Louis

2013-06-01T23:59:59.000Z

180

Vibrational Spectroscopy of Mass-Selected [UO2(ligand)n]2+ Complexes in the Gas Phase: Comparison with Theory  

SciTech Connect (OSTI)

The gas-phase infrared spectra of discrete uranyl ([UO2]2+) complexes ligated with acetone and/or acetonitrile were used to evaluate systematic trends of ligation on the position of the OdUdO stretch and to enable rigorous comparison with the results of computational studies. Ionic uranyl complexes isolated in a Fourier transform ion cyclotron resonance mass spectrometer were fragmented via infrared multiphoton dissociation using a free electron laser scanned over the mid-IR wavelengths. The asymmetric OdUdO stretching frequency was measured at 1017 cm-1 for [UO2(CH3COCH3)2]2+ and was systematically red shifted to 1000 and 988 cm-1 by the addition of a third and fourth acetone ligand, respectively, which was consistent with increased donation of electron density to the uranium center in complexes with higher coordination number. The values generated computationally using LDA, B3LYP, and ZORA-PW91 were in good agreement with experimental measurements. In contrast to the uranyl frequency shifts, the carbonyl frequencies of the acetone ligands were progressively blue shifted as the number of ligands increased from two to four and approached that of free acetone. This observation was consistent with the formation of weaker noncovalent bonds between uranium and the carbonyl oxygen as the extent of ligation increases. Similar trends were observed for [UO2(CH3CN)n]2+ complexes, although the uranyl asymmetric stretching frequencies were greater than those measured for acetone complexes having equivalent coordination, which is consistent with the fact that acetonitrile is a weaker nucleophile than is acetone. This conclusion was confirmed by the uranyl stretching frequencies measured for mixed acetone/acetonitrile complexes, which showed that substitution of one acetone for one acetonitrile produced a modest red shift of 3-6 cm-1.

Gary S. Groenewold; Anita K. Gianotto

2006-03-01T23:59:59.000Z

Note: This page contains sample records for the topic "n2 h2s hg" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Novel signal inversion of laser beam induced current for femtosecond-laser-drilling-induced junction on vacancy-doped p-type HgCdTe  

SciTech Connect (OSTI)

In this paper, experimental results of temperature-dependent signal inversion of laser beam induced current (LBIC) for femtosecond-laser-drilling-induced junction on vacancy-doped p-type HgCdTe are reported. LBIC characterization shows that the traps induced by femtosecond laser drilling are sensitive to temperature. Theoretical models for trap-related p-n junction transformation are proposed and demonstrated using numerical simulations. The simulations are in good agreement with the experimental results. The effects of traps and mixed conduction are possibly the main reasons that result in the novel signal inversion of LBIC microscope at room temperature. The research results provide a theoretical guide for practical applications of large-scale array HgCdTe infrared photovoltaic detectors formed by femtosecond laser drilling, which may act as a potential new method for fabricating HgCdTe photodiodes.

Qiu, W. C.; Wang, R.; Xu, Z. J.; Jiang, T. [College of Photoelectric Science and Engineering, National University of Defense Technology, Changsha, Hunan 410073 (China); Cheng, X. A., E-mail: xiang-ai-cheng@126.com [College of Photoelectric Science and Engineering, National University of Defense Technology, Changsha, Hunan 410073 (China); State Key Laboratory of High Performance Computing, National University of Defense Technology, Changsha, Hunan 410073 (China); Science and Technology on Electro-Optical Information Security Control Laboratory, Hebei 065201 (China)

2014-05-28T23:59:59.000Z

182

Improved performance of HgCdTe infrared detector focal plane arrays by modulating light field based on photonic crystal structure  

SciTech Connect (OSTI)

An HgCdTe long-wavelength infrared focal plane array photodetector is proposed by modulating light distributions based on the photonic crystal. It is shown that a promising prospect of improving performance is better light harvest and dark current limitation. To optimize the photon field distributions of the HgCdTe-based photonic crystal structure, a numerical method is built by combining the finite-element modeling and the finite-difference time-domain simulation. The optical and electrical characteristics of designed HgCdTe mid-wavelength and long-wavelength photon-trapping infrared detector focal plane arrays are obtained numerically. The results indicate that the photon crystal structure, which is entirely compatible with the large infrared focal plane arrays, can significantly reduce the dark current without degrading the quantum efficiency compared to the regular mesa or planar structure.

Liang, Jian; Hu, Weida, E-mail: wdhu@mail.sitp.ac.cn; Ye, Zhenhua; Li, Zhifeng; Chen, Xiaoshuang, E-mail: xschen@mail.sitp.ac.cn; Lu, Wei [National Laboratory for Infrared Physics, Shanghai Institute of Technical Physics, Chinese Academy of Sciences, 500 Yu Tian Road, Shanghai 200083 (China); Liao, Lei [Department of Physics and Key Laboratory of Artificial Micro- and Nano-structures of Ministry of Education, Wuhan University, Wuhan 430072 (China)

2014-05-14T23:59:59.000Z

183

A Tungsten(VI) Nitride Having a W2(-N)2 Core Zachary J. Tonzetich, Richard R. Schrock,* Keith M. Wampler, Brad C. Bailey,  

E-Print Network [OSTI]

A Tungsten(VI) Nitride Having a W2(-N)2 Core Zachary J. Tonzetich, Richard R. Schrock,* Keith M-331, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 Received September 27, 2007 The tungsten that the tungsten alkylidyne species W(C-t-Bu)(CH2-t-Bu)(OAr)2 (Ar ) 2,6-diisopropylphenyl) can be prepared readily

Mller, Peter

184

---Home Yahoo! Help My Yahoo! http://asia.news.yahoo.com/041201/kyodo/d86n2bdg0.html  

E-Print Network [OSTI]

- - -Home Yahoo! Help My Yahoo! http://asia.news.yahoo.com/041201/kyodo/d86n2bdg0.html Thursday Reserved. - - -Privacy Policy Terms of Service Community Help 12/1/04 8:49 PMFrance confident of U.S., S

185

Rate constants for the reactions of O+ with N2 and O2 as a function of temperature (3001800 K)  

E-Print Network [OSTI]

We have studied the rate constants for the reaction of O+ with N2 over the temperature range 3001600 K and the reaction of O+ with O2 over the range 300 to 1800 K. The results are in good agreement with previous measurements ...

Hierl, Peter M.; Dotan, I.; Seeley, John V.; Doren, Jane M. Van; Morris, Robert A.; Viggiano, A. A.

1997-01-01T23:59:59.000Z

186

Supersaturated N2O in a perennially ice-covered Antarctic lake: Molecular and stable isotopic evidence for a biogeochemical relict  

E-Print Network [OSTI]

Supersaturated N2O in a perennially ice-covered Antarctic lake: Molecular and stable isotopic Abstract The east lobe of Lake Bonney, a permanently ice-covered lake in the McMurdo Dry Valleys2O was produced via incomplete nitrification and has undergone virtually no subsequent consumption

Priscu, John C.

187

Optical Nonlinearity in Ar and N2 near the Ionization Threshold J. K. Wahlstrand, Y.-H. Cheng, Y.-H. Chen, and H. M. Milchberg  

E-Print Network [OSTI]

Optical Nonlinearity in Ar and N2 near the Ionization Threshold J. K. Wahlstrand, Y.-H. Cheng, Y measure the nonlinear optical response in argon and nitrogen in a thin gas target to laser intensities.103901 PACS numbers: 42.65.An, 42.65.Jx, 42.65.Re The optical Kerr effect, the intensity-dependent refrac

Milchberg, Howard

188

King Air flight RICO 2004/12/13 page 1 King Air N2UW flight report for December 13, 2004  

E-Print Network [OSTI]

repair of the air conditioner on the aircraft, a test flight was needed and was to be transformedKing Air flight RICO 2004/12/13 page 1 King Air N2UW flight report for December 13, 2004 Crew: Drew, Vali, Oolman, Glover After

Vali, Gabor

189

Scientific uncertainties in atmospheric mercury models III: Boundary and initial conditions, model grid resolution, and Hg(II) reduction mechanism  

SciTech Connect (OSTI)

In this study, the model response in terms of simulated mercury concentration and deposition to boundary condition (BC), initial condition (IC), model grid resolution (12 km versus 36 km), and two alternative Hg(II) reduction mechanisms, was investigated. The model response to the change of gaseous elemental mercury (GEM) concentration from 0 to 2 ngm3 in IC/BC is found to be very linear (r240.99) based on the results of sensitivity simulations in July 2001. An increase of 1 ngm3 of GEM in BC resulted in an increase of 0.81 ngm3 in the monthly average of total mercury concentration, and 1270 ngm2 in the monthly total deposition. IC has similar but weaker effects compared to those of BC. An increase of 1 ngm3 of GEM in IC resulted in an increase of 0.14 ngm3 in the monthly average of total mercury concentration, and 250 ngm2 in the monthly total deposition. Varying reactive gaseous mercury (RGM) or particulate mercury (PHg) in BC/IC has much less significant impact. Simulation results at different grid resolutions show good agreement (slope 0.950 1.026, r 0.816 0.973) in mercury concentration, dry deposition, and total deposition. The agreement in wet deposition is somewhat weaker (slope 0.770 0.794, r 0.685 0.892) due to the difference in emission dilution and simulated precipitation that subsequently change reaction rates in the aqueous phase. Replacing the aqueous Hg(II)-HO2 reduction by either RGM reduction by CO (51018cm3 molecule1 s1) or photoreduction of RGM (1105 s1) gives significantly better model agreement with the wet deposition measured by Mercury Deposition Network (MDN). Possible ranges of the reduction rates are estimated based on model sensitivity results. The kinetic estimate requires further verification by laboratory studies.

Lin, Che-Jen [ORNL; Pongprueksa, Pruek [Lamar University; Lindberg, Steven Eric [ORNL; Jang, Carey [U.S. Environmental Protection Agency, Raleigh, North Carolina; Braverman, Thomas [U.S. Environmental Protection Agency, Raleigh, North Carolina; Bullock, Russell O [NOAA; Ho, Thomas [ORNL; Chu, Hsing-Wei [Lamar University

2008-03-01T23:59:59.000Z

190

Sulfurization of a carbon surface for vapor phase mercury removal II: Sulfur forms and mercury uptake  

E-Print Network [OSTI]

promote the formation of organic sulfur and the presence of H2S during the cooling process increased in the presence of H2S was very effective towards Hg uptake in nitrogen. Corre- lation of mercury uptake capacitySulfurization of a carbon surface for vapor phase mercury removal ­ II: Sulfur forms and mercury

Borguet, Eric

191

SNS Target Test Facility: Prototype Hg Operations and Remote Handling Tests P. T. Spampinato, T. W. Burgess, J. B. Chesser, V. B. Graves, and S.L. Schrock  

E-Print Network [OSTI]

SNS Target Test Facility: Prototype Hg Operations and Remote Handling Tests P. T. Spampinato, T. W remote handling techniques and tools for replacing target system components. During the past year and analytical data. These included a welded-tube heat exchanger, an electromagnetic flow meter, a hydraulically

McDonald, Kirk

192

207Pb(n,2n{gamma})206Pb Cross-Section Measurements by In-Beam Gamma-Ray Spectroscopy  

SciTech Connect (OSTI)

207Pb(n,2n{gamma})206Pb cross section were measured for incident neutron energies between 6 and 20 MeV with the white neutron beam produced at GELINA. The {gamma}-ray production cross section for the main transition (803 keV, 2+{yields} 0+) in 206Pb is compared to results obtained at Los Alamos and to the TALYS and EMPIRE-II code predictions.

Baumann, P.; Kerveno, M.; Rudolf, G. [IReS, IN2P3, Strasbourg (France); Borcea, C. [EC, JRC, IRMM, Geel (Belgium); NIPNE, Bucarest (Romania); Jericha, E. [Technische Universitaet Wien, Wien (Austria); Jokic, S. [INN Vinca, Belgrade (Serbia and Montenegro); Lukic, S. [IReS, IN2P3, Strasbourg (France); INN Vinca, Belgrade (Serbia and Montenegro); Mihailescu, L. C.; Plompen, A. J. M. [EC, JRC, IRMM, Geel (Belgium); Pavlik, A. [Universitaet Wien, Vienna (Austria)

2006-03-13T23:59:59.000Z

193

Powerplant Technology Problem 3-2: Fuel oils generally are a mix of components such as CnH2n+2 (see Table 4-4  

E-Print Network [OSTI]

Table 4-4 on page 147); to convert from a mass-analysis to moles-per-pound-of-fuel, we need to introduce.499N2 (a.) The total of 0.666 lbmole of gas produced by this combustion of one lbm of fuel, includes condensation if the temperature dropped to or below 135.6o F. (b.) The amount of sulfurous acid produced from

194

Yrast structure of the two-proton- and three-neutron-hole nucleus {sup 203}Hg from the decay of a 53/2{sup +} isomer  

SciTech Connect (OSTI)

The decay of a new, 53/2{sup +}, isomer at 8281 keV in {sup 203}Hg has been studied by {gamma} coincidence spectroscopy. A half-life of 146(30) ns was measured. In addition, another isomeric, 39/2{sup +}, level with a half-life of 7.8(1.5) ns was observed. Some elements of the Rydstroem shell-model interaction have been adjusted to reproduce level energies in nuclei with two to four holes in the {sup 208}Pb core. With this interaction, the new states in the five-hole nucleus {sup 203}Hg are reproduced with an rms error of 105 keV.

Szpak, B.; Maier, K. H.; Fornal, B.; Broda, R.; Cieplicka, N.; Krolas, W.; Pawlat, T.; Wrzesinski, J. [Niewodniczanski Institute of Nuclear Physics PAN, Krakow (Poland); Smolkowska, A. S. [Niewodniczanski Institute of Nuclear Physics PAN, Krakow (Poland); Gdansk University of Technology, Gdansk (Poland); Carpenter, M. P.; Janssens, R. V. F.; Zhu, S. [Argonne National Laboratory, Argonne, Illinois 60439 (United States)

2011-06-15T23:59:59.000Z

195

Recent progress in commensurate-incommensurate phase transformations. [Hg/sub 3/-delta AsF/sub 6/; 2H polytype of TaSe/sub 2/  

SciTech Connect (OSTI)

Three topics are discussed. (1) the nature of long wavelength excitations in Hg/sub 3/-delta AsF/sub 6/, where gapless excitations in addition to the conventional acoustic modes are observed. (2) Thiourea, in which new commensurate phases can be induced by an external electric field. (3) Discommensurations in 2HTaSe/sub 2/, where recent electron diffraction and high resolution x-ray data combine with neutron results to establish a quite complex and subtle behavior. 9 figures.

Axe, J.D.

1982-08-01T23:59:59.000Z

196

Investigation of the liquid/vapor composition of compressed liquid CO2 with N2 and O2 in integrated pollutant removal systems for coal combustion  

SciTech Connect (OSTI)

Accurate prediction of the processes in Integrated Pollutant Removal (IPR) using compression and condensation of coal combustion products requires an understanding of the liquid/vapor ternary CO2/O2/N2 system. At conditions close to the critical point of CO2 the existing equations of state deviate from the sparse measured results available in the literature. Building on existing data and procedures, the USDOE/Albany Research Center has designed an apparatus for examining compositions in this region. The design of the apparatus and planned initial experiments are presented.

Oryshchyn, Danylo B.; Ochs, Thomas L.; Summers, Cathy A.; Penner, Larry R.; Gerdemann, Stephen J.

2005-01-01T23:59:59.000Z

197

UBC Centre for Blood Research: Fermentation Suite Brom A5 (F4) PDF.xls: FermentationProfile Air O2 rpm N2 Base Acid  

E-Print Network [OSTI]

UBC Centre for Blood Research: Fermentation Suite Brom A5 (F4) PDF.xls: FermentationProfile Air O2 rpm N2 Base Acid NH4OH Acetic Acid 8.6 16.0 Configuration 1 SP 4 - - - SP - 2 SP 3 0.000 Temp (oC) dO2 Fermentation (Hrs) pH rpm Temp Do OD CK (mg/50-L) MeOH (ml) dO2 (%)Temp (C) 40 20 60 80 0 100 6 8 4 2 0 10 28

Strynadka, Natalie

198

Caractrisation en bruit des photodiodes P.I.N. Hg1-x Cdx Te 03BB = B. Orsal (*), R. Alabedra (*), C. Maille (*), C. Boisrobert (**), D. Morvan (**), J. Meslage (***) et  

E-Print Network [OSTI]

63 Caractérisation en bruit des photodiodes P.I.N. Hg1-x Cdx Te à 03BB = 1,3 03BCm B. Orsal (*), R montrent que la qualité des contacts des photodiodes de 2e génération est meilleure que celle obtenue sur.I.N. Hg1-xCdxTe photodiodes at 03BB = 1.3 03BCm by measurements of 1/f noise. The devices are manufactured

Paris-Sud XI, Université de

199

Multi-Pollutant Emissions Control: Pilot Plant Study of Technologies for Reducing Hg, SO3, NOx and CO2 Emissions  

SciTech Connect (OSTI)

A slipstream pilot plant was built and operated to investigate technology to adsorb mercury (Hg) onto the existing particulate (i.e., fly ash) by cooling flue gas to 200-240 F with a Ljungstrom-type air heater or with water spray. The mercury on the fly ash was then captured in an electrostatic precipitator (ESP). An alkaline material, magnesium hydroxide (Mg(OH){sub 2}), is injected into flue gas upstream of the air heater to control sulfur trioxide (SO{sub 3}), which prevents acid condensation and corrosion of the air heater and ductwork. The slipstream was taken from a bituminous coal-fired power plant. During this contract, Plant Design and Construction (Task 1), Start Up and Maintenance (Task 2), Baseline Testing (Task 3), Sorbent Testing (Task 4), Parametric Testing (Task 5), Humidification Tests (Task 6), Long-Term Testing (Task 7), and a Corrosion Study (Task 8) were completed. The Mercury Stability Study (Task 9), ESP Report (Task 11), Air Heater Report (Task 12) and Final Report (Task 14) were completed. These aspects of the project, as well as progress on Public Outreach (Task 15), are discussed in detail in this final report. Over 90% mercury removal was demonstrated by cooling the flue gas to 200-210 F at the ESP inlet; baseline conditions with 290 F flue gas gave about 26% removal. Mercury removal is sensitive to flue gas temperature and carbon content of fly ash. At 200-210 F, both elemental and oxidized mercury were effectively captured at the ESP. Mg(OH){sub 2} injection proved effective for removal of SO{sub 3} and eliminated rapid fouling of the air heater. The pilot ESP performed satisfactorily at low temperature conditions. Mercury volatility and leaching tests did not show any stability problems. No significant corrosion was detected at the air heater or on corrosion coupons at the ESP. The results justify larger-scale testing/demonstration of the technology. These conclusions are presented and discussed in two presentations given in July and September of 2005 and are included in Appendices E and F.

Michael L. Fenger; Richard A. Winschel

2005-08-31T23:59:59.000Z

200

Air Pollution Grant Ideas Possible air pollutants to study: SO2, H2S, NO2, NH3, CO, CO2, O3.  

E-Print Network [OSTI]

. Nitrogen Dioxide: Nitrogen dioxide (NO2) is one of a group of highly reactive gasses known as "oxides://www.gradko.co.uk/ram/ Gradko tubes - http://www.gradko.co.uk/pdf/Nitrogen_Dioxide.pdf Grants and Funding Allegheny County of nitrogen," or "nitrogen oxides (NOx)." Other nitrogen oxides include nitrous acid and nitric acid. While

Short, Daniel

Note: This page contains sample records for the topic "n2 h2s hg" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Elevated-Temperature Corrosion of CoCrCuFeNiAl0.5Bx High-Entropy Alloys in Simulated Syngas Containing H2S  

SciTech Connect (OSTI)

High-entropy alloys are formed by synthesizing five or more principal elements in equimolar or near equimolar concentrations. Microstructure of the CoCrCuFeNiAl{sub 0.5}B{sub x} (x = 0, 0.2, 0.6, 1) high-entropy alloys under investigation is composed of a mixture of disordered bcc and fcc phases and borides. These alloys were tested gravimetrically for their corrosion resistance in simulated syngas containing 0, 0.01, 0.1, and 1 % H{sub 2}S at 500 C. The exposed coupons were characterized using XRD and SEM. No significant corrosion was detected at 500 C in syngas containing 0 and 0.01 % H{sub 2}S while significant corrosion was observed in syngas containing 0.1 and 1 % H{sub 2}S. Cu{sub 1.96}S was the primary sulfide in the external corrosion scale on the low-boron high-entropy alloys, whereas FeCo{sub 4}Ni{sub 4}S{sub 8} on the high-boron high-entropy alloys. Multi-phase Cu-rich regions in the low-B high-entropy alloys were vulnerable to corrosive attack.

Dogan, Omer N.; Nielsen, Benjamin C.; Hawk, Jeffrey A.

2013-08-01T23:59:59.000Z

202

Numerical modeling of injection and mineral trapping of CO2 withH2S and SO2 in a Sandstone Formation  

SciTech Connect (OSTI)

Carbon dioxide (CO{sub 2}) injection into deep geologic formations could decrease the atmospheric accumulation of this gas from anthropogenic sources. Furthermore, by co-injecting H{sub 2}S or SO{sub 2}, the products respectively of coal gasification or combustion, with captured CO{sub 2}, problems associated with surface disposal would be mitigated. We developed models that simulate the co-injection of H{sub 2}S or SO{sub 2} with CO{sub 2} into an arkose formation at a depth of about 2 km and 75 C. The hydrogeology and mineralogy of the injected formation are typical of those encountered in Gulf Coast aquifers of the United States. Six numerical simulations of a simplified 1-D radial region surrounding the injection well were performed. The injection of CO{sub 2} alone or co-injection with SO{sub 2} or H{sub 2}S results in a concentrically zoned distribution of secondary minerals surrounding a leached and acidified region adjacent to the injection well. Co-injection of SO{sub 2} with CO{sub 2} results in a larger and more strongly acidified zone, and alteration differs substantially from that caused by the co-injection of H{sub 2}S or injection of CO{sub 2} alone. Precipitation of carbonates occurs within a higher pH (pH > 5) peripheral zone. Significant quantities of CO{sub 2} are sequestered by ankerite, dawsonite, and lesser siderite. The CO{sub 2} mineral-trapping capacity of the formation can attain 40-50 kg/m{sup 3} medium for the selected arkose. In contrast, secondary sulfates precipitate at lower pH (pH < 5) within the acidified zone. Most of the injected SO{sub 2} is transformed and immobilized through alunite precipitation with lesser amounts of anhydrite and minor quantities of pyrite. The dissolved CO{sub 2} increases with time (enhanced solubility trapping). The mineral alteration induced by injection of CO{sub 2} with either SO{sub 2} or H{sub 2}S leads to corresponding changes in porosity. Significant increases in porosity occur in the acidified zones where mineral dissolution dominates. With co-injection of SO{sub 2}, the porosity increases from an initial 0.3 to 0.43 after 100 years. However, within the CO{sub 2} mineral-trapping zone, the porosity decreases to about 0.28 for both cases, because of the addition of CO{sub 2} mass as secondary carbonates to the rock matrix. Precipitation of sulfates at the acidification front causes porosity to decrease to 0.23. The limited information currently available on the mineralogy of naturally occurring high-pressure CO{sub 2} reservoirs is generally consistent with our simulations.

Xu, Tianfu; Apps, John A.; Pruess, Karsten; Yamamoto, Hajime

2004-09-07T23:59:59.000Z

203

components of the droplet stream in the first regime before,during, and after the impact. The energy audit shows thatthe change in trandiameter dropllo theleiee smpo ohat modes (i.e. n [ 2) decay quickly, leaving the dominant  

E-Print Network [OSTI]

. The energy audit shows thatthe change in trandiameter dropllo theleiee smpo ohat #12;#12;modes (i.e. n [ 2) at the University of Rochester also contributed financially. A. Tucker-Schwartz of UCLA suggested use of the HDFT

Jones, Thomas B.

204

Heat capacity of Cu 2 (C 5 H 12 N 2 ) 2 Cl 4 in a magnetic eld Masayuki Hagiwara a;1 , Hiroko Aruga Katori a , Uli Schollwock b , Hans-Jurgen Mikeska c  

E-Print Network [OSTI]

structure in a gapless spin liquid system. Keywords: heat capacity; spin-ladder; Cu 2 (C5H12N2 ) 2 Cl4Heat capacity of Cu 2 (C 5 H 12 N 2 ) 2 Cl 4 in a magnetic #12;eld Masayuki Hagiwara a;1 , Hiroko, D- 30167 Hannover, Germany Abstract Heat capacity measurements down to 0.5 K in a magnetic #12;eld

Kersting, Roland

205

Faddeev-Senjanovic Quantization of SU(n) N=2 Supersymmetric Gauge Field System with Non-Abelian Chern-Simons Topological Term and Its Fractional Spin  

E-Print Network [OSTI]

Using Faddeev-Senjanovic path integral quantization for constrained Hamilton system, we quantize SU(n) N=2 supersymmetric gauge field system with non-abelian Chern-Simons topological term in 2+1 dimensions, and use consistency of a gauge condition naturally to deduce another gauge condition. Further, we get the generating functional of Green function in phase space, deduce the angular momentum based on the global canonical Noether theorem at quantum level, obtain the fractional spin of this supersymmetric system, and show that the total angular momentum has the orbital angular momentum and spin angular momentum of the non-abelian gauge field. Finally, we find out the anomalous fractional spin and discover that the fractional spin has the contributions of both the group superscript components and the A_0^s (x) charge.

Yong-Chang Huang; Qiu-Hong Huo

2009-01-13T23:59:59.000Z

206

Hg and Se capture and fly ash carbons from combustion of complex pulverized feed blends mainly of anthracitic coal rank in Spanish power plants  

SciTech Connect (OSTI)

In this work, the petrology and chemistry of fly ashes produced in a Spanish power plant from the combustion of complex pulverized feed blends made up of anthracitic/meta-anthracitic coals, petroleum, and natural coke are investigated. It was found that the behavior of fly ash carbons derived from anthracitic coals follows relatively similar patterns to those established for the carbons from the combustion of bituminous coals. Fly ashes were sampled in eight hoppers from two electrostatic precipitator (ESP) rows. The characterization of the raw ashes and their five sieved fractions (from {gt}150 to {lt}25 {mu}m) showed that glassy material, quartz, oxides, and spinels in different proportions are the main inorganic components. As for the organic fraction, the dominant fly ash carbons are anisotropic carbons, mainly unburned carbons derived from anthracitic vitrinite. The concentration of Se and Hg increased in ashes of the second ESP row, this increase being related to the higher proportion of anisotropic unburned carbons, particularly those largely derived from anthracitic vitrinite in the cooler ashes of the ESP (second row) and also related to the decrease in the flue gas temperature. This suggests that the flue gas temperature plays a major role in the concentration of mercury for similar ratios of unburned carbons. It was also found that Hg is highly concentrated in the medium-coarser fractions of the fly ashes ({gt} 45 {mu}m), there being a positive relationship between the amount of these carbons, which are apparently little modified during the combustion process, in the medium-coarse fractions of the ashes and the Hg retention. According to the results obtained, further research on this type of fly ash could be highly productive. 28 refs., 10 figs., 8 tabs.

I. Surez-Ruiz; J.C. Hower; G.A. Thomas [Instituto Nacional del Carbon (INCAR-CSIC), Oviedo (Spain)

2007-01-15T23:59:59.000Z

207

Acceptor and donor production in Hg b1 s[subscript -x]Cd[subscript x]Te by neutron transmutation doping  

E-Print Network [OSTI]

remains constant during the irradiation, 4. The dopant or oduced i'rom the decay of the pr oduct isot. ope is stable, 5. The effect of bur nup of the product isotopes and the dopants is negligible. With these assumptions and approximations one has... amounts such as Te and Te, and with products arri tting gamma rays with approximately the same ener gy, theoretical methods wer e developed for deter mining acceptor and donor production levels in Hg& xCdxTe based on the simultaneous irradiation of a...

Seager, Kevin Douglas

1985-01-01T23:59:59.000Z

208

Method of controlling the mercury vapor pressure in a photo-chemical lamp or vapor filter used for Hg.sup.196 enrichment  

DOE Patents [OSTI]

The present invention is directed to a method of eliminating the cold spot zones presently used on Hg.sup.196 isotope separation lamps and filters by the use of a mercury amalgams, preferably mercury - indium amalgams. The use of an amalgam affords optimization of the mercury density in the lamp and filter of a mercury enrichment reactor, particularly multilamp enrichment reactors. Moreover, the use of an amalgam in such lamps and/or filters affords the ability to control the spectral line width of radiation emitted from lamps, a requirement for mercury enrichment.

Grossman, Mark W. (Belmont, MA)

1993-01-01T23:59:59.000Z

209

Method of controlling the mercury vapor pressure in a photo-chemical lamp or vapor filter used for Hg[sup 196] enrichment  

DOE Patents [OSTI]

The present invention is directed to a method of eliminating the cold spot zones presently used on Hg[sup 196] isotope separation lamps and filters by the use of a mercury amalgams, preferably mercury - indium amalgams. The use of an amalgam affords optimization of the mercury density in the lamp and filter of a mercury enrichment reactor, particularly multilamp enrichment reactors. Moreover, the use of an amalgam in such lamps and/or filters affords the ability to control the spectral line width of radiation emitted from lamps, a requirement for mercury enrichment.

Grossman, M.W.

1993-02-16T23:59:59.000Z

210

Near-Zero Emissions Oxy-Combustion Flue Gas Purification Task 2: SOx/Nox/Hg Removal for High Sulfur Coal  

SciTech Connect (OSTI)

The goal of this project is to develop a near-zero emissions flue gas purification technology for existing PC (pulverized coal) power plants that are retrofitted with oxy-combustion technology. The objective of Task 2 of this project was to evaluate an alternative method of SOx, NOx and Hg removal from flue gas produced by burning high sulfur coal in oxy-combustion power plants. The goal of the program was not only to investigate a new method of flue gas purification but also to produce useful acid byproduct streams as an alternative to using a traditional FGD and SCR for flue gas processing. During the project two main constraints were identified that limit the ability of the process to achieve project goals. 1) Due to boiler island corrosion issues >60% of the sulfur must be removed in the boiler island with the use of an FGD. 2) A suitable method could not be found to remove NOx from the concentrated sulfuric acid product, which limits sale-ability of the acid, as well as the NOx removal efficiency of the process. Given the complexity and safety issues inherent in the cycle it is concluded that the acid product would not be directly saleable and, in this case, other flue gas purification schemes are better suited for SOx/NOx/Hg control when burning high sulfur coal, e.g. this project's Task 3 process or a traditional FGD and SCR.

Nick Degenstein; Minish Shah; Doughlas Louie

2012-05-01T23:59:59.000Z

211

The influence of the magnetic field on the effect of drag of electrons by phonons in n-Cd{sub x}Hg{sub 1-x}Te  

SciTech Connect (OSTI)

Thermopower in n-Cd{sub 0.2}Hg{sub 0.8}Te (6-100 K) is studied. A large effect of drag of the charge carriers by phonons {alpha}{sub ph} is found. The influence of the magnetic field H on the drag thermopower is considered. It is established that the magnetic field exerts the effect mainly on the electron component of {alpha}{sub ph}. The data are interpreted in the context of the theory taking into account the effect of H on thermopower {alpha}{sub ph}, in which parameter A({epsilon}) proportional to the static force of the drag effect is introduced. By the experimental data {alpha}{sub ph}(T, H), T, and H dependences A({epsilon}) are determined. It is shown that, as H increases, A({epsilon}) sharply decreases. This explains a decrease in {alpha}{sub ph} in the magnetic field, power index k in dependence {alpha}{sub ph} {proportional_to} T{sup -}{kappa}, and narrowing the region of manifestation of the drag effect. It is established that at classically high fields, the drag effect in n-Cd{sub 0.2}Hg{sub 0.8}Te does not vanish.

Aliyev, S. A.; Zulfigarov, E. I.; Selim-Zade, R. I.; Agayev, Z. F., E-mail: agayevz@rambler.ru [National Academy of Sciences of Azerbaijan, Institute of Physics (Azerbaijan)

2009-09-15T23:59:59.000Z

212

E-Print Network 3.0 - aluminum phosphide pc Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

HCP CCP PO phosphorus monoxide molecular oxygen Aluminum oxide H2 H2 O H2 S CSi carbon... isocyanide HCl NaCl NaCN N2 O KCl AlCl aluminum monochloride NH2 amidyl radical*...

213

Temporal Nodal Regression and Regional Control After Primary Radiation Therapy for N2-N3 Head-and-Neck Cancer Stratified by HPV Status  

SciTech Connect (OSTI)

Purpose: To compare the temporal lymph node (LN) regression and regional control (RC) after primary chemoradiation therapy/radiation therapy in human papillomavirus-related [HPV(+)] versus human papillomavirus-unrelated [HPV(?)] head-and-neck cancer (HNC). Methods and Materials: All cases of N2-N3 HNC treated with radiation therapy/chemoradiation therapy between 2003 and 2009 were reviewed. Human papillomavirus status was ascertained by p16 staining on all available oropharyngeal cancers. Larynx/hypopharynx cancers were considered HPV(?). Initial radiologic complete nodal response (CR) (?1.0 cm 8-12 weeks after treatment), ultimate LN resolution, and RC were compared between HPV(+) and HPV(?) HNC. Multivariate analysis identified outcome predictors. Results: A total of 257 HPV(+) and 236 HPV(?) HNCs were identified. The initial LN size was larger (mean, 2.9 cm vs 2.5 cm; P<.01) with a higher proportion of cystic LNs (38% vs 6%, P<.01) in HPV(+) versus HPV(?) HNC. CR was achieved is 125 HPV(+) HNCs (49%) and 129 HPV(?) HNCs (55%) (P=.18). The mean post treatment largest LN was 36% of the original size in the HPV(+) group and 41% in the HPV(?) group (P<.01). The actuarial LN resolution was similar in the HPV(+) and HPV(?) groups at 12 weeks (42% and 43%, respectively), but it was higher in the HPV(+) group than in the HPV(?) group at 36 weeks (90% vs 77%, P<.01). The median follow-up period was 3.6 years. The 3-year RC rate was higher in the HPV(?) CR cases versus non-CR cases (92% vs 63%, P<.01) but was not different in the HPV(+) CR cases versus non-CR cases (98% vs 92%, P=.14). On multivariate analysis, HPV(+) status predicted ultimate LN resolution (odds ratio, 1.4 [95% confidence interval, 1.1-1.7]; P<.01) and RC (hazard ratio, 0.3 [95% confidence interval 0.2-0.6]; P<.01). Conclusions: HPV(+) LNs involute more quickly than HPV(?) LNs but undergo a more prolonged process to eventual CR beyond the time of initial assessment at 8 to 12 weeks after treatment. Post radiation neck dissection is advisable for all non-CR HPV(?)/non-CR N3 HPV(+) cases, but it may be avoided for selected non-CR N2 HPV(+) cases with a significant LN involution if they can undergo continued imaging surveillance. The role of positron emission tomography for response assessment should be investigated.

Huang, Shao Hui; O'Sullivan, Brian [Department of Radiation Oncology, Princess Margaret Cancer Centre/University of Toronto, Toronto, Ontario (Canada); Xu, Wei; Zhao, Helen [Department of Biostatistics, Princess Margaret Cancer Centre/University of Toronto, Toronto, Ontario (Canada); Chen, Duo-duo [Radiation Medicine Program, Princess Margaret Cancer Centre, Toronto, Ontario (Canada); Ringash, Jolie; Hope, Andrew [Department of Radiation Oncology, Princess Margaret Cancer Centre/University of Toronto, Toronto, Ontario (Canada); Razak, Albiruni [Division of Medical Oncology, Princess Margaret Cancer Centre, Toronto, Ontario (Canada); Gilbert, Ralph; Irish, Jonathan [Department of Otolaryngology-Head and Neck Surgery/Surgical Oncology, Princess Margaret Cancer Centre/University of Toronto, Toronto, Ontario (Canada); Kim, John; Dawson, Laura A.; Bayley, Andrew; Cho, B.C. John [Department of Radiation Oncology, Princess Margaret Cancer Centre/University of Toronto, Toronto, Ontario (Canada); Goldstein, David; Gullane, Patrick [Department of Otolaryngology-Head and Neck Surgery/Surgical Oncology, Princess Margaret Cancer Centre/University of Toronto, Toronto, Ontario (Canada); Yu, Eugene [Department of Radiology, Princess Margaret Cancer Centre, Toronto, Ontario (Canada); Perez-Ordonez, Bayardo; Weinreb, Ilan [Department of Pathology, Princess Margaret Cancer Centre, Toronto, Ontario (Canada); Waldron, John, E-mail: John.Waldron@rmp.uhn.on.ca [Department of Radiation Oncology, Princess Margaret Cancer Centre/University of Toronto, Toronto, Ontario (Canada)

2013-12-01T23:59:59.000Z

214

Relativistic distorted-wave collision strengths for the 49 ?n=0 optically allowed transitions with n=2 in the 67 B-like ions with 26?Z?92  

SciTech Connect (OSTI)

Relativistic distorted-wave collision strengths have been calculated for the 49 ?n=0 optically allowed transitions with n=2 in the 67 B-like ions with nuclear charge number Z in the range 26?Z?92. The calculations were made for the four final, or scattered, electron energies E{sup ?}=0.20, 0.42, 0.80, and 1.40, where E{sup ?} is in units of Z{sub eff}{sup 2} Ry with Z{sub eff}=Z?3.33. In the present calculations, an improved top-up method, which employs relativistic plane waves, was used to obtain the high partial-wave contribution for each transition, in contrast to the partial-relativistic CoulombBethe approximation used in previous work by Zhang and Sampson [H.L. Zhang and D.H. Sampson, At. Data Nucl. Data Tables 56 (1994) 41]. In that earlier work, collision strengths were also provided for B-like ions, but for a more comprehensive data set consisting of all 105 ?n=0 transitions, six scattered energies and the 85 ions with Z in the range 8?Z?92. The collision strengths covered in the present work should be more accurate than the corresponding data given by Zhang and Sampson [H.L. Zhang and D.H. Sampson, At. Data Nucl. Data Tables 56 (1994) 41] and are presented here to replace those earlier results.

Fontes, Christopher J., E-mail: cjf@lanl.gov; Zhang, Hong Lin

2014-05-15T23:59:59.000Z

215

Quantum mechanical study of solvent effects in a prototype S{sub N}2 reaction in solution: Cl{sup ?} attack on CH{sub 3}Cl  

SciTech Connect (OSTI)

The nucleophilic attack of a chloride ion on methyl chloride is an important prototype S{sub N}2 reaction in organic chemistry that is known to be sensitive to the effects of the surrounding solvent. Herein, we develop a highly accurate Specific Reaction Parameter (SRP) model based on the Austin Model 1 Hamiltonian for chlorine to study the effects of solvation into an aqueous environment on the reaction mechanism. To accomplish this task, we apply high-level quantum mechanical calculations to study the reaction in the gas phase and combined quantum mechanical/molecular mechanical simulations with TIP3P and TIP4P-ew water models and the resulting free energy profiles are compared with those determined from simulations using other fast semi-empirical quantum models. Both gas phase and solution results with the SRP model agree very well with experiment and provide insight into the specific role of solvent on the reaction coordinate. Overall, the newly parameterized SRP Hamiltonian is able to reproduce both the gas phase and solution phase barriers, suggesting it is an accurate and robust model for simulations in the aqueous phase at greatly reduced computational cost relative to comparably accurate ab initio and density functional models.

Kuechler, Erich R. [BioMaPS Institute and Department of Chemistry and Chemical Biology, Rutgers University, Piscataway, New Jersey 08854-8087 (United States) [BioMaPS Institute and Department of Chemistry and Chemical Biology, Rutgers University, Piscataway, New Jersey 08854-8087 (United States); Department of Chemistry, University of Minnesota, Minneapolis, Minnesota 55455-0431 (United States); York, Darrin M., E-mail: york@biomaps.rutgers.edu [BioMaPS Institute and Department of Chemistry and Chemical Biology, Rutgers University, Piscataway, New Jersey 08854-8087 (United States)

2014-02-07T23:59:59.000Z

216

F O R E S T R E S E A R C H C O R P O R A T E P L A N 2 0 0 2 2 0 0 5  

E-Print Network [OSTI]

F O R E S T R E S E A R C H #12;C O R P O R A T E P L A N 2 0 0 2 2 0 0 5 F O R E S T R E S E A R C H Forest Research C O R P O R A T E P L A N 2 0 0 2 2 0 0 5 1 #12;C O R P O R A T E P L A N 2 0 0 2 2 0 0 5 F O R E S T R E S E A R C H Acting Chief Executive Peter Freer-Smith Forest Research

217

Structural and electronic properties of Au{sub n?x}Pt{sub x} (n = 214; x ? n) clusters: The density functional theory investigation  

SciTech Connect (OSTI)

The structural evolutions and electronic properties of bimetallic Au{sub nx}Pt{sub x} (n = 214; x ? n) clusters are investigated by using the density functional theory (DFT) with the generalized gradient approximation (GGA). The monatomic doping Au{sub n1}Pt clusters are emphasized and compared with the corresponding pristine Au{sub n} clusters. The results reveal that the planar configurations are favored for both Au{sub n1}Pt and Au{sub n} clusters with size up to n = 13, and the former often employ the substitution patterns based on the structures of the latter. The most stable clusters are Au{sub 6} and Au{sub 6}Pt, which adopt regular planar triangle (D{sub 3h}) and hexagon-ring (D{sub 6h}) structures and can be regarded as the preferential building units in designing large clusters. For Pt-rich bimetallic clusters, their structures can be obtained from the substitution of Pt atoms by Au atoms from the Pt{sub n} structures, where Pt atoms assemble together and occupy the center yet Au atoms prefer the apex positions showing a segregation effect. With respect to pristine Au clusters, Au{sub n}Pt clusters exhibit somewhat weaker and less pronounced odd-even oscillations in the highest occupied and lowest unoccupied molecular-orbital gaps (HOMO-LUMO gap), electron affinity (EA), and ionization potential (IP) due to the partially released electron pairing effect. The analyses of electronic structure indicate that Pt atoms in AuPt clusters would delocalize their one 6s and one 5d electrons to contribute the electronic shell closure. The sp-d hybridizations as well as the d-d interactions between the host Au and dopant Pt atoms result in the enhanced stabilities of AuPt clusters.

Yuan, H. K.; Kuang, A. L.; Tian, C. L.; Chen, H., E-mail: chenh@swu.edu.cn [School of Physical Science and Technology, Southwest University, Chongqing, 400715 (China)

2014-03-15T23:59:59.000Z

218

Stress corrosion cracking: New experiments, new insights M I T E N E R G Y I N I T I AT I V E A U T U M N 2 0 1 2  

E-Print Network [OSTI]

% post-consumer recycled content, with the balance coming from responsibly managed sources. Energy. Economic pressures both in the United States and in other key economies around the world threaten T U M N 2 0 1 2 I N T H I S I S S U E Energy Futures Discovering solutions: Undergrads take the lead

Yildiz, Bilge

219

The concrete theory of numbers : New Mersenne conjectures. Simplicity and other wonderful properties of numbers $L(n) = 2^{2n}\\pm2^n\\pm1$  

E-Print Network [OSTI]

New Mersenne conjectures. The problems of simplicity, common prime divisors and free from squares of numbers $L(n) = 2^{2n}\\pm2^n\\pm1$ are investigated. Wonderful formulas $gcd $ for numbers $L (n) $ and numbers repunit are proved.

Boris V. Tarasov

2008-04-24T23:59:59.000Z

220

Prof. Dr. Uwe Holtz Universitt Bonn Am Hofgarten 15D -53113 Bonn UHoltz@aol.com www.uni-bonn.de/~uholtz1 OECD (Hg.): DAC Peer Review Germany, Paris 2006.4  

E-Print Network [OSTI]

.uni-bonn.de/~uholtz1 6.4.072 3 OECD (Hg.): DAC Peer Review Germany, Paris 2006.4 (www.oecd.org/dataoecd/54 of poorer countries but need for greater strategic selectivity8 9 Germany has never stated a preference in favor of specific groups of countries. Germany admits10 that poorest countries need donors' full support

Franz, Sven Oliver

Note: This page contains sample records for the topic "n2 h2s hg" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Electrochemical Oxidation of H2 Catalyzed by Ruthenium Hydride Complexes Bearing P2N2 Ligands With Pendant Amines as Proton Relays  

SciTech Connect (OSTI)

Two Ru hydride complexes (Cp*Ru(PPh2NBn2)H, 1-H and (Cp*Ru(PtBu2NBn2)H, 2-H) supported by cyclic PR2NR'2 ligands (Cp* = ?5-C5Me5; 1,5-diaza-3,7-diphosphacyclooctane, where R = Ph or tBu and R' = Bn) have been synthesized and fully characterized. Both complexes are demonstrated to be electrocatalysts for oxidation of H2 (1 atm, 22 C) in the presence of external base, DBU (1,8-diazabicyclo[5.4.0]undec-7-ene). The turnover frequency of 2-H is 1.2 s-1, with an overpotential at Ecat/2 of 0.45 V, while catalysis by 1-H has a turnover frequency of 0.6 s-1 and an overpotential of 0.6 V at Ecat/2. Addition of H2O facilitates oxidation of H2 by 2-H and increases its turnover frequency to 1.9 s-1 while , H2O slows down the catalysis by 1-H. The different effects of H2O for 1-H and 2-H are ascribed to different binding affinities of H2O to the Ru center of the corresponding unsaturated species, [Cp*Ru(PPh2NBn2)]+ and [Cp*Ru(PPh2NBn2)]+. In addition, studies of Cp*Ru(dmpm)H (where dmpm = bis(dimethylphosphino)methane), a control complex lacking pendent amines in its diphosphine ligand, confirms the critical roles of the pendent amines of P2N2 ligands for oxidation of H2. We thank the U.S. Department of Energy, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences and Biosciences, for supporting initial parts of the work. Current work is supported by the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences. Pacific Northwest National Laboratory is operated by Battelle for the U.S. Department of Energy.

Liu, Tianbiao L.; Rakowski DuBois, Mary; DuBois, Daniel L.; Bullock, R. Morris

2014-11-03T23:59:59.000Z

222

Microsoft Word - Hg.doc  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: VegetationEquipment Surfaces andMappingENVIRONMENTALHYDROPOWER MEETINGR&DHighImproved4/2012

223

Time-dependent density-functional theory for molecular processes in strong fields: Study of multiphoton processes and dynamical response of individual valence electrons of N2 in intense laser fields  

E-Print Network [OSTI]

in the exchange ~x!- only limit. In the latter approach @1#, theTime-dependent density-functional theor Study of multiphoton processes and dynam of N2 in inten Xi Chu and Department of Chemistry, University of Kansas, and Kansas Ce ~Received 30 July 2001; pu We...-I CHU PHYSICAL REVIEW A 64 0634041sg 21su 22sg 22su 21pu 43sg 2 . According to the valence bond theory, this molecule has a triple bond formed with 3sg and 1pu electrons. The 3sg orbital is parallel to the internuclear axis and the two degen- erate 1pu...

Chu, Xi; Chu, Shih-I

2001-11-14T23:59:59.000Z

224

Near-Zero Emissions Oxy-Combustion Flue Gas Purification Task 3: SOx/NOx/Hg Removal for Low Sulfur Coal  

SciTech Connect (OSTI)

The goal of this project was to develop a near-zero emissions flue gas purification technology for existing PC (pulverized coal) power plants that are retrofitted with oxycombustion technology. The objective of Task 3 of this project was to evaluate an alternative method of SOx, NOx and Hg removal from flue gas produced by burning low sulfur coal in oxy-combustion power plants. The goal of the program was to conduct an experimental investigation and to develop a novel process for simultaneously removal of SOx and NOx from power plants that would operate on low sulfur coal without the need for wet-FGD & SCRs. A novel purification process operating at high pressures and ambient temperatures was developed. Activated carbon??s catalytic and adsorbent capabilities are used to oxidize the sulfur and nitrous oxides to SO{sub 3} and NO{sub 2} species, which are adsorbed on the activated carbon and removed from the gas phase. Activated carbon is regenerated by water wash followed by drying. The development effort commenced with the screening of commercially available activated carbon materials for their capability to remove SO{sub 2}. A bench-unit operating in batch mode was constructed to conduct an experimental investigation of simultaneous SOx and NOx removal from a simulated oxyfuel flue gas mixture. Optimal operating conditions and the capacity of the activated carbon to remove the contaminants were identified. The process was able to achieve simultaneous SOx and NOx removal in a single step. The removal efficiencies were >99.9% for SOx and >98% for NOx. In the longevity tests performed on a batch unit, the retention capacity could be maintained at high level over 20 cycles. This process was able to effectively remove up to 4000 ppm SOx from the simulated feeds corresponding to oxyfuel flue gas from high sulfur coal plants. A dual bed continuous unit with five times the capacity of the batch unit was constructed to test continuous operation and longevity. Full-automation was implemented to enable continuous operation (24/7) with minimum operator supervision. Continuous run was carried out for 40 days. Very high SOx (>99.9%) and NOx (98%) removal efficiencies were also achieved in a continuous unit. However, the retention capacity of carbon beds for SOx and NOx was decreased from ~20 hours to ~10 hours over a 40 day period of operation, which was in contrast to the results obtained in a batch unit. These contradictory results indicate the need for optimization of adsorption-regeneration cycle to maintain long term activity of activated carbon material at a higher level and thus minimize the capital cost of the system. In summary, the activated carbon process exceeded performance targets for SOx and NOx removal efficiencies and it was found to be suitable for power plants burning both low and high sulfur coals. More efforts are needed to optimize the system performance.

Monica Zanfir; Rahul Solunke; Minish Shah

2012-06-01T23:59:59.000Z

225

RSE Table N2.1 and N2.2. Relative Standard Errors for Tables N2.1 and N2.2  

U.S. Energy Information Administration (EIA) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia,(Million Barrels) Crude Oil Reserves in NonproducingAdditions to Capacity on theThousand7.End1 Relative3E8.1 and

226

Sciences Po Grenoble working paper n.2  

E-Print Network [OSTI]

will first analyse the forms of resistance to hard law based on the widespread secondary literature available. This will then be compared to areas in which soft law reigns, with a view to demonstrate that soft law triggers as much resistance as hard law. Based on this empirical data and using a policy instruments approach, the paper

Boyer, Edmond

227

N2Solar | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of InspectorConcentrating Solar Powerstories onFocus Area EnergyMohawkaccrediation ofInformationCoop,

228

Dicarboxylate assisted synthesis of the monoclinic heterometallic tetrathiocyanato bridged copper(II) and mercury(II) coordination polymer {l_brace}Cu[Hg(SCN){sub 4}]{r_brace}{sub n}: Synthesis, structural, vibration, luminescence, EPR studies and DFT calculations  

SciTech Connect (OSTI)

The synthesis of the monoclinic polymorph of {l_brace}Cu[Hg(SCN){sub 4}]{r_brace}{sub n} is reported. The compound, as determined by X-ray diffraction of a twinned crystal, consists of mercury and copper atoms linked by {mu}{sub 1,3}-SCN bridges. The crystal packing shows a highly porous infinite 3D structure. Diagnostic resonances for the SCN{sup -} ligand and metal-ligand bonds in the IR, far-IR and Raman spectra are assigned and discussed. The electronic band structure along with density of states (DOS) calculated by the DFT method indicates that the compound is an indirect band gap semiconductor. The DFT calculations show that the observed luminescence of the compound arises mainly from an excited LLCT state with small MLCT contributions (from the copper to unoccupied {pi}{sup *} orbital of the thiocyanate groups). The X-band EPR spectrum of the powdered sample at room temperature reveals an axial signal with anisotropic g factors consistent with the unpaired electron of Cu(II) ion in the d{sub x}{sup 2}{sub -y}{sup 2} orbital. -- Graphical abstract: Synthesis and X-ray structure determination of the monoclinic {l_brace}Cu[Hg(SCN){sub 4}]{r_brace}{sub n} is reported. The IR, far-IR, Raman, photoluminescence as well as EPR spectra of the compound is discussed. Also, the emission and semiconducting behavior of the compound is illustrated through the density functional theory calculation of electronic band structure along with density of states. Display Omitted Research highlights: > The monoclinic {l_brace}Cu[Hg(SCN){sub 4}]{r_brace}{sub n} has been prepared. > The structure of the compound is determined by XRD of a twinned crystal. > The IR, far-IR, Raman, EPR and emission spectra of the compound is investigated. > As shown by DFT calculations, the emission bands of the compound are mainly LLCT. > Small MLCT from the copper to the thiocyanate groups contributes to these bands.

Khandar, Ali Akbar, E-mail: akhandar@yahoo.co [Department of Inorganic Chemistry, Faculty of Chemistry, University of Tabriz, 5166614766 Tabriz (Iran, Islamic Republic of); Klein, Axel [Institut fuer Anorganische Chemie, Universitaet zu Koeln, Greinstrasse 6, 50939 Koeln (Germany); Bakhtiari, Akbar [Department of Inorganic Chemistry, Faculty of Chemistry, University of Tabriz, 5166614766 Tabriz (Iran, Islamic Republic of); Institut fuer Anorganische Chemie, Universitaet zu Koeln, Greinstrasse 6, 50939 Koeln (Germany); Mahjoub, Ali Reza [Department of Chemistry, School of Science, Tarbiat Modares University, P.O. Box 14155-4838 Tehran (Iran, Islamic Republic of); Pohl, Roland W.H. [Institut fuer Anorganische Chemie, Universitaet zu Koeln, Greinstrasse 6, 50939 Koeln (Germany)

2011-02-15T23:59:59.000Z

229

On modeling the potential impacts of CO2 sequestration on shallow groundwater: Transport of organics and co-injected H2S by supercritical CO2 to shallow aquifers  

E-Print Network [OSTI]

reservoir to shallower formations, for example through fault or fracture zones, or poorly plugged abandoned

Zheng, L.

2014-01-01T23:59:59.000Z

230

Optimal geometries and harmonic vibrational frequencies of the global minima of water clusters (H2O)n, n=2-6, and several hexamer local minima at the CCSD(T) level of theory  

SciTech Connect (OSTI)

We report the first optimum geometries and harmonic vibrational frequencies for the ring pentamer and several water hexamer (prism, cage, cyclic and two book) at the CCSD(T)/aug-cc-pVDZ level of theory. All five hexamer isomer minima previously reported by MP2 are also minima on the CCSD(T) potential energy surface (PES). In addition, all CCSD(T) minimum energy structures for the n=2-6 cluster isomers are quite close to the ones previously obtained by MP2 on the respective PESs, as confirmed by a modified Procrustes analysis that quantifies the difference between any two cluster geometries. The CCSD(T) results confirm the cooperative effect of the homodromic ring networks (systematic contraction of the nearest-neighbor (nn) intermolecular separations with cluster size) previously reported by MP2, albeit with O-O distances shorter by ~0.02 , indicating that MP2 overcorrects this effect. The harmonic frequencies at the minimum geometries were obtained by the double differentiation of the CCSD(T) energy using an efficient scheme based on internal coordinates that reduces the number of required single point energy evaluations by ~15% when compared to the corresponding double differentiation using Cartesian coordinates. Negligible differences between MP2 and CCSD(T) are found for the librational modes, while uniform increases of ~15 and ~25 cm-1 are observed for the bending and free OH harmonic frequencies. The largest differences between MP2 and CCSD(T) are observed for the harmonic hydrogen bonded frequencies. The CCSD(T) red shifts from the monomer frequencies (??) are smaller than the MP2 ones, due to the fact that the former produces shorter elongations (?R) of the respective hydrogen bonded OH lengths from the monomer value with respect to the latter. Both the MP2 and CCSD(T) results for the hydrogen bonded frequencies were found to closely follow the relation - ?? = s ? ?R, with a rate of s = 20.3 cm-1 / 0.001 . The CCSD(T) harmonic frequencies, when corrected using the MP2 anharmonicities obtained from second order vibrational perturbation theory (VPT2), produce anharmonicCCSD(T) estimates that are within < 60 cm-1 from the measured infrared (IR) active bands of the n=2-6 clusters and furthermore trace the observed red shifts with respect to the monomer (??) quite accurately. The energetic order between the various hexamer isomers on the PES (prism has the lowest energy) previously reported at MP2 was found to be preserved at the CCSD(T) level, whereas the inclusion of anharmonic corrections further stabilizes the cage among the hexamer isomers.

Miliordos, Evangelos; Apra, Edoardo; Xantheas, Sotiris S.

2013-09-21T23:59:59.000Z

231

Simulation of relaxation times and energy spectra of the CdTe/Hg{sub 1-x}Cd{sub x}Te/CdTe quantum well for variable valence band offset, well width, and composition x  

SciTech Connect (OSTI)

The dependences of relaxation times and energy spectrum of the CdTe/Hg{sub 1-x}Cd{sub x}Te/CdTe quantum well (QW) on its parameters were simulated in the cadmium molar fraction range 0 < x < 0.16. It was found that the x increase from 0 to 0.16 changes electron wave function localization in the QW. A criterion for determining the number of interface levels of localized electrons depending on QW parameters was obtained. The effect of a sharp (by two orders of magnitude) increase in the relaxation time of localized electrons was detected at small QW widths and x close to 0.16.

Melezhik, E. O., E-mail: emelezhik@gmail.com; Gumenjuk-Sichevska, J. V.; Sizov, F. F. [National Academy of Sciences, Lashkariev Institute of Semiconductor Physics (Ukraine)

2010-10-15T23:59:59.000Z

232

Effect of annealing on the kinetic properties and band parameters of Hg{sub 1?x?y}Cd{sub x}Eu{sub y}Se semiconductor crystals  

SciTech Connect (OSTI)

The results of studies of the kinetic properties of Hg{sub 1?x?y}Cd{sub x}Eu{sub y}Se semiconductor crystals in the ranges of temperatures T = 77300 K and magnetic fields H = 0.55 kOe before and after heat treatment of the samples in Se vapors are reported. It is established that annealing of the samples in Se vapors induces a decrease in the electron concentration. From the concentration dependence of the electron effective mass at the Fermi level, the band gap, the matrix element of interband interaction, and the electron effective mass at the bottom of the conduction band are determined.

Kovalyuk, T. T., E-mail: tarik-1006@mail.ru; Maistruk, E. V.; Maryanchuk, P. D. [Chernivtsy National University (Ukraine)

2014-12-15T23:59:59.000Z

233

DENSE PHASE REBURN COMBUSTION SYSTEM (DPRCS) DEMONSTRATION ON A 154 MWE TANGENTIAL FURNACE: ADDITIONAL AREA OF INTEREST-TO DEVELOP AND DEMONSTRATE AN IN-FURNACE MULTI-POLLUTANT REDUCTION TECHNOLOGY TO REDUCE NOx, SO2 & Hg  

SciTech Connect (OSTI)

Semi-dense phase pneumatic delivery and injection of calcium and sodium sorbents, and microfine powdered coal, at various sidewall elevations of an online operating coal-fired power plant, was investigated for the express purpose of developing an in-furnace, economic multi-pollutant reduction methodology for NO{sub x}, SO{sub 2} & Hg. The 154 MWe tangentially-fired furnace that was selected for a full-scale demonstration, was recently retrofitted for NO{sub x} reduction with a high velocity rotating-opposed over-fire air system. The ROFA system, a Mobotec USA technology, has a proven track record of breaking up laminar flow along furnace walls, thereby enhancing the mix of all constituents of combustion. The knowledge gained from injecting sorbents and micronized coal into well mixed combustion gases with significant improvement in particulate retention time, should serve well the goals of an in-furnace multi-pollutant reduction technology; that of reducing back-end cleanup costs on a wide variety of pollutants, on a cost per ton basis, by first accomplishing significant in-furnace reductions of all pollutants.

Allen C. Wiley; Steven Castagnero; Geoff Green; Kevin Davis; David White

2004-03-01T23:59:59.000Z

234

Specific features of the temperature dependence of the conduction electron concentration in the narrow-gap and zero-gap states of Cd{sub x}Hg{sub 1-x}Te  

SciTech Connect (OSTI)

Results of studies of the conductivity {sigma} and the Hall coefficient R in the Cd{sub x}Hg{sub 1-x}Te crystals with x = 0.1, 0.12, 0.14, and 0.15 are analyzed in the temperature range T = 4.2-300 K and the magnetic field range B = 0.005-2.22 T. Using data on the R(B) in low and high magnetic fields and the data on {sigma}(T), electron and hole concentrations and mobilities are determined. It is shown that the electron concentration n in the studied samples is almost independent of T in the range 4.2-15 K, while as T increases, it increases according to the law n {proportional_to} T {sup r} (r > 3/2), where r = f(n, T, x). It is found that r varies from 1.7 at x = 0.1 to 3.1 at compositions with x = 0.14 and 0.15. The results for n(T) are compared with theory, taking into account nonparabolicity of the variance law for {epsilon}(T), and with the theory of impurity states in narrow-gap and zero-gap semiconductors. It is shown that the constancy of n(T) up to {approx}15 K and the strong dependence n(T) (r > 3/2) at higher temperatures are caused by the intense ionization of electrons localized at acceptor states.

Aliev, S. A.; Zulfigarov, E. I.; Selim-zade, R. I. [Academy of Sciences of Azerbaijan, Institute of Physics (Azerbaijan)

2012-03-15T23:59:59.000Z

235

Life on Earth. II The Hadean Earth  

E-Print Network [OSTI]

to space Source of atmosphere, oceans: outgassing and impacts Early atmosphere: CO2, H2O, N2, H2S, SO2, H2? #12;Rocks The fossil evidence is preserved in rocks. Igneous rock: solidified lava Sedimentary rock: sediment laid down and compressed into rock. Metamorphic rock: sedimentary rock that has been modified

Walter, Frederick M.

236

Mathematical Model Analysis for Hg Flow  

E-Print Network [OSTI]

Properties (25 C ) Density 13.546 kg/L Sound Speed 1451 m/s Viscosity 1.526E-3 kg/sm Dynamic Viscosity 1Mechanism of Jet Breakup & Atomization R.D. Reitz and F.V. Bracco, Mechanism of atomization of a liquid jet,Phys. Fluids, Vol.25, No.10,Oct.1982 Environment Liquid Properties Viscosity Density Jet Breakup & Atomization

McDonald, Kirk

237

High Power Hg Target Conceptual Design Review  

E-Print Network [OSTI]

for systems tests · 15 Tesla field · 1-sec steady state jet during the magnet peak field (unresolved) #12=-2.5, R=0.4 (pump motor) is 0.03

McDonald, Kirk

238

Hg System Assembly and Testing Status  

E-Print Network [OSTI]

OF ENERGY Current Status / Next Steps · Populate secondary box ports · Complete plumbing inside secondary #12;2VRVS Meeting 1 Nov 2006 OAK RIDGE NATIONAL LABORATORY U. S. DEPARTMENT OF ENERGY Welding OAK RIDGE NATIONAL LABORATORY U. S. DEPARTMENT OF ENERGY Cart Modifications · Secondary box center

McDonald, Kirk

239

Sources and distribution of Campylobacter fetus subsp. jejuni in turkeys  

E-Print Network [OSTI]

. Characteristics Cam lobacter s ecies C. ~e uni C. coli C. fetus subsp. fetus C. fetus subsp. venerealis Oxidase Ferment sugars N03 reduction N02 reduction H2S (SIN) H2S (strip)a Hippurate hydrolysis Growth with: 1% glycine 3. 5X NaCl Growth at: 25 C 30.... These plates were incubated at 42 C for 48 h in an atmosphere of 5% 02, 1+ 002, and 85K N2. Suspect colonies (smooth, convex, translucent, colorless to cream-colored, pin-point to 1-1. 2 mm in diameter or often spreading colonies) of C. fetus subsp. jejuni...

Acuff, Gary Royce

1982-01-01T23:59:59.000Z

240

Molecular Electronics Electron Transfer in a Hg-SAM//SAM-Hg  

E-Print Network [OSTI]

, Prof. Wolfgang Schmickler, Mandar Deshmukh, Mark Gudiksen, Amy Prieto, Babak Parviz, Logan Mc redox centers at their surface.[21] Standard electrochemical techniques demonstrate that this junction shows a schematic illustration of the junc- tion[22­30] and the associated electrochemical system

Prentiss, Mara

Note: This page contains sample records for the topic "n2 h2s hg" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Reduction of Hg(II) to Hg(0) by Magnetite. | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the1 -the Mid-Infrared at 278, 298,NIST 800-53 National RenewableSolid-ElectrolyteRolesof

242

Surface characterization of Pd/Al2O3 sorbents for mercury capture from fuel gas  

SciTech Connect (OSTI)

The surface composition of a series of Pd/alumina sorbents has been characterized to better understand the factors influencing their ability to adsorb mercury from fuel gas. Both a temperature effect and a dispersion effect were found. Maximum adsorption of Hg occurred at the -lowest temperature tested, 204C, and decreased with increasing temperatures. Maximum adsorption of Hg on a per-atom basis of Pd is observed at low loadings of Pd ( < 8.5% Pd) due to better dispersion of Pd at those loadings; a change in its partitioning occurs at higher loadings. The presence of H2S 'in the fuel gas acts to promote the adsorption of Hg through its association with Hg in the Pd lattice.

Baltrus, J.P.; Granite, E.J.; Stanko, D.C.; Pennline, H.W.

2008-01-01T23:59:59.000Z

243

Surface characterization of Pd/Al2O3 sorbents for mercury capture from fuel gas  

SciTech Connect (OSTI)

The surface composition of a series of Pd/alumina sorbents has been characterized to better understand the factors influencing their ability to adsorb mercury from fuel gas. Both a temperature effect and a dispersion effect were found. Maximum adsorption of Hg occurred at the lowest temperature tested, 2048C, and decreased with increasing temperatures. Maximum adsorption of Hg on a per-atom basis of Pd is observed at low loadings of Pd (58.5% Pd) due to better dispersion of Pd at those loadings; a change in its partitioning occurs at higher loadings. The presence of H2S in the fuel gas acts to promote the adsorption of Hg through its association with Hg in the Pd lattice.

Baltrus, J.P.; Granite, E.J.; Stanko, D.C.; Pennline, H.W.

2008-09-01T23:59:59.000Z

244

U N I V E R S I T Y O F R O C H E S T E R , O N E U N I V E R S I T Y --O N E P L A N 2 0 0 8 C A M P U S M A S T E R P L A N  

E-Print Network [OSTI]

U N I V E R S I T Y O F R O C H E S T E R , O N E U N I V E R S I T Y -- O N E P L A N 2 0 0 8 C A M P U S M A S T E R P L A N E x e c u t i v e S u m m a r y #12;U N I V E R S I T Y O F R O C H E S T E R , O N E U N I V E R S I T Y -- O N E P L A N Copyright 2008 AYERS | SAINT | GROSS All Rights

Portman, Douglas

245

TECHNICAL REPORTS Continuous measurement of soil N2  

E-Print Network [OSTI]

at night. Although increased battery storage capacity would decrease down time, supplemental power from

Minnesota, University of

246

R5 TechComm N2 Keynotes 2011  

E-Print Network [OSTI]

Immunogold Electron Microscopy TC5-LM3 TC5-LM4 Fluorescent checking TC5-LM1 TC5-LM2 Confocal microscopy TC5-LM3 TC5-LM4 Fluorescence microscopy Auto- fluorescence Fluorescent staining Other samples TC5-LM5 Monoclonal antibody * TC4-E10 ELISA system TC4-E11 Epitope prediction TC5 TC5-EM1 SEM or TEM TC5-LM2

Wu, Yih-Min

247

SSQ V3 N2_Final_13aug13.indd  

National Nuclear Security Administration (NNSA)

testing (UGT) stockpile stewardship and management program. The use of high performance computing coupled with detailed verification and validation has transformed our business,...

248

1 function fe2d_n 2 %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%  

E-Print Network [OSTI]

_ki = triangle_area*s1/(h3*h1); 98 K_ik = K_ki; 99 K_kj = triangle_area*s2/(h3*h2); 100 K_jk = K_kj; 101 K

Garvie, Marcus R

249

1 function fe2dx_n 2 %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%  

E-Print Network [OSTI]

_ki = triangle_area*s1/(h3*h1); 98 K_ik = K_ki; 99 K_kj = triangle_area*s2/(h3*h2); 100 K_jk = K_kj; 101 K

Garvie, Marcus R

250

SSQ V1 N2_6june11_FINAL  

National Nuclear Security Administration (NNSA)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarlyEnergyDepartmentNationalRestart of the Review of theOFFICE OF CIVIL to Mod 0099 datedMod0/%2A enFY12

251

SSQ V3 N2_Final_13aug13.indd  

National Nuclear Security Administration (NNSA)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarlyEnergyDepartmentNationalRestart of the Review of theOFFICE OF CIVIL to Mod 0099 datedMod0/%2A2 *

252

Observation of a stripping threshold for the reaction N2 ^++CH4?N2H^++CH3  

E-Print Network [OSTI]

reactions of positive ions have been found to proceed with no activa tion energT; (2) the most probable value of the product translational energy is about 0.1 eV lower than the value predicted by the spectator stripping model, 3 exactly the opposite... that the methyl fragment be produced with in ternal excitation. B. Reaction cross section a R The reaction cross section is calculated from the equation where Ie is the total reactively scattered product ion intensity, IA is the transmitted primary ion...

Wyatt, J. R.; Strattan, L. W.; Snyder, S. C.; Hierl, Peter M.

1976-01-01T23:59:59.000Z

253

ELECTROSTATIC (LANGMUIR) PROBE MEASUREMENTS IN RF DRIVEN He, N2, BCl3, AND BCl3/N2 PLASMAS  

E-Print Network [OSTI]

with similar kT e and N e values or using similar etching chemistries. 5 1.3. Plasma Chemistry?Reactive, Inert, and Inhibiting Species Previous work in the University of Kansas Plasma Research Laboratory (KU PRL or KU Plasma Research Lab) has focused...

Pathak, Bogdan Amaru

2008-08-01T23:59:59.000Z

254

Molecular Simulation Studies of Separation of CO2/N2, CO2/CH4, and CH4/N2  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinanInformation Desert Southwest Regionat Cornell Batteries & Fuel CellsModels fromMolecular Scienceby

255

Manure to Energy: Understanding Processes, Principles and Jargon  

E-Print Network [OSTI]

of air (especially oxygen) to produce biogas. Biogas, which is produced from degradation of organic matter in manure by the bacteria, contains primarily methane (CH 4 ) and carbon dioxide (CO 2 ). Other gases, such as nitrogen (N 2 ), hydrogen... sulfide (H 2 S) and trace organic components are also present in relatively small quantities. Typically, 60-65 percent #24; of the biogas is CH 4 . Methane and CO 2 represent more than 90 percent of the biogas. Virtually all N, phosphorus (P...

Mukhtar, Saqib

2006-11-30T23:59:59.000Z

256

MERIT Hg System Status V.B. Graves  

E-Print Network [OSTI]

modules inserted into magnet utilizes Ti or Ti alloys - Alleviates issues with welding dissimilar metals Mar 2006 Beam Windows · Windows fabricated from Ti6Al4V alloy · Welded attachments provide more usable

McDonald, Kirk

257

Packed bed reactor for photochemical .sup.196 Hg isotope separation  

DOE Patents [OSTI]

Straight tubes and randomly oriented pieces of tubing having been employed in a photochemical mercury enrichment reactor and have been found to improve the enrichment factor (E) and utilization (U) compared to a non-packed reactor. One preferred embodiment of this system uses a moving bed (via gravity) for random packing.

Grossman, Mark W. (Belmont, MA); Speer, Richard (Reading, MA)

1992-01-01T23:59:59.000Z

258

Hg Anomalies In Soils- A Geochemical Exploration Method For Geothermal...  

Open Energy Info (EERE)

Areas. Geothermics. () . Related Geothermal Exploration Activities Activities (5) Mercury Vapor At Breitenbush Hot Springs Area (Varekamp & Buseck, 1983) Mercury Vapor At...

259

Hg Anomalies In Soils- A Geochemical Exploration Method For Geothermal  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 No revision hasInformation Earth's Heat Jump to:Photon Place:NetHealth DivisionHelioMotionisHesperia,Areas | Open

260

3UREOHP 6WDWHPHQW3UREOHP 6WDWHPHQW 0HWKRGRORJ\\ (PSOR\\HG0HWKRGRORJ\\ (PSOR\\HG  

E-Print Network [OSTI]

price of oil & gas is high requiresa time when price of oil & gas is high requires a reliable reservoir

Mohaghegh, Shahab

Note: This page contains sample records for the topic "n2 h2s hg" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

The solubility of gold in water-hydrogen sulphide vapours: An experimental study  

E-Print Network [OSTI]

O-H2S gas mixtures. The solubility of gold was measured in pure H2S gas and H2O-H2S gas mixtures. The following reactions are interpreted to control the solubility of gold in H2O-H2S gas mixtures: )()()()()1 by the reaction H2+S=H2S, the solubility of gold in reduced sulphur-bearing vapour is relatively high (up to 1 ppb

Barnes, Sarah-Jane

262

Observing nanoscience and technology worldwide Newsletter n2, February 2009 Stephan Roche www.nanotrendchart.com  

E-Print Network [OSTI]

Observing nanoscience and technology worldwide Newsletter n°2 of the 35 largest districts worldwide. Studying nano-districts gives a new view on nanoscience Data from 200 represented. Interestingly, al- though activity in nanoscience is concentrated in a limited number of areas

Paris-Sud XI, Université de

263

A comparison of three learning methods to predict N2O fluxes and N leaching  

E-Print Network [OSTI]

leaching; the first indicator is a powerful greenhouse gas and the second one is an important source

Boyer, Edmond

264

STATISTICA INFERENZIALE SHEDA N. 2 INTERVALLI DI CONFIDENZA PER IL VALORE ATTESO E LA FREQUENZA  

E-Print Network [OSTI]

dati campionari. In questa scheda costruiremo un intervallo nel quale ci aspettiamo stia il parametro

Rogantin, Maria Piera

265

The Tiffany Unit N2 - ECBM Pilot: A Reservoir Modeling Study  

SciTech Connect (OSTI)

In October, 2000, the U.S. Department of Energy, through contractor Advanced Resources International, launched a multi-year government-industry R&D collaboration called the Coal-Seq project. The Coal-Seq project is investigating the feasibility of CO{sub 2} sequestration in deep, unmineable coalseams, by performing detailed reservoir studies of two enhanced coalbed methane recovery (ECBM) field projects in the San Juan basin. The two sites are the Allison Unit, operated by Burlington Resources, and into which CO{sub 2} is being injected, and the Tiffany Unit, operating by BP America, into which N{sub 2} is being injected (the interest in understanding the N{sub 2}-ECBM process has important implications for CO{sub 2} sequestration via flue-gas injection). The purposes of the field studies are to understand the reservoir mechanisms of CO{sub 2} and N{sub 2} injection into coalseams, demonstrate the practical effectiveness of the ECBM and sequestration processes, demonstrate an engineering capability to model them, and to evaluate sequestration economics. In support of these efforts, laboratory and theoretical studies are also being performed to understand and model multi-component isotherm behavior, and coal permeability changes due to swelling with CO{sub 2} injection. This report describes the results of an important component of the overall project, the Tiffany Unit reservoir modeling study. The Tiffany Unit is located in the northern portion of the prolific San Juan basin (in Southern Colorado). The study area consists of 34 methane production wells and 12 nitrogen injection wells. The field originally began production in 1983, and N{sub 2} injection operations for ECBM purposes commenced in 1998. Nitrogen injection was suspended in 2002, to evaluate the results of the pilot. In this study, a detailed reservoir characterization of the field was developed, the field history was matched using the COMET3 reservoir simulator, and future field performance was forecast under various operating conditions. Based on the results of the study, the following major conclusions have been drawn: (1) The injection of N{sub 2} at the Tiffany Unit has resulted in incremental methane recovery over estimated primary recovery, in approximate proportion of one volume of methane for every 0.4 volumes of injected nitrogen on a net basis. In the swept areas, an incremental methane recovery of approximately 20% of original-gas-in-place resulted from N{sub 2}-ECBM operations. (2) At the prevailing gas prices at the time the project was implemented ({approx}2.20/Mcf), and not considering any tax credit benefits, the pilot itself was uneconomic. However, with today's gas prices of {approx}$4.00/Mcf, N{sub 2}-ECBM appears economically attractive. (3) Performance predictions of future injection suggests CO{sub 2} sequestration can be accomplished at a slight profit. Economic performance is enhanced by adding some N{sub 2} to the injectant.

Scott Reeves; Anne Oudinot

2004-03-31T23:59:59.000Z

266

AVVISO DI CONFERIMENTO DI N.2 INCARICHI DI COLLABORAZIONE Prot. 872/2013  

E-Print Network [OSTI]

/08/2008 si rende noto che il Dipartimento di Fisica intende conferire un incarico per la seguente attività COMPETENZE RICHIESTE: · Studenti del dottorato di ricerca in Fisica e Astrofisica · Dottori di ricerca in Fisica ed Astrofisica · Assegnisti di ricerca presso il Dipartimento di Fisica o altri enti

Guidoni, Leonardo

267

A Calcium Coordination Framework Having Permanent Porosity and High CO2/N2 Selectivity  

SciTech Connect (OSTI)

A thermally stable, microporous calcium coordination network shows a reversible 5.75 wt % CO{sub 2} uptake at 273 K and 1 atm pressure, with an enthalpy of interaction of {approx}31 kJ/mol and a CO{sub 2}/N{sub 2} selectivity over 45 under ideal flue gas conditions. The absence of open metal sites in the activated material suggests a different mechanism for selectivity and high interaction energy compared to those for frameworks with open metal sites.

Banerjee D.; Parise J.; Zhang, Z.; Plonka, A.M.; Li, J.

2012-03-15T23:59:59.000Z

268

asanka chisso n2o: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

with low advective stream input and strong-0636828. Logistic support was provided by Raytheon Polar Services and Petroleum Helicopters Inc Priscu, John C. 104 Short-term effects...

269

Unlocking the Standard Model. IV. N=2 generations of quarks : spectrum and mixing  

E-Print Network [OSTI]

The Glashow-Salam-Weinberg model for 2 generations of quarks is extended to 8 composite Higgs multiplets, with no adjunction of extra fermions. It is the minimal number of Higgs doublets required to suitably account, simultaneously, for the spectrum of pseudoscalar mesons that can be built with 4 quarks and for the mass of the W gauge bosons. These masses being used as input, together with elementary low energy considerations for the pions, we calculate all other parameters, masses and couplings. We focus in this work on the spectrum of the 8 Higgs bosons (which all potentially contribute to the W and quark masses), and on the mixing (Cabibbo) angle, leaving the study of couplings to a subsequent work. The Higgs bosons fall into one triplet, two doublets and one singlet. In the triplet stand three states with masses \\sqrt{2} x that of heaviest pseudoscalar meson D_s, which, for 2 generations, pushes them up to 2.80 GeV. The 2 components of the first doublet have masses close to 1.25 GeV. The singlet has a mas...

Machet, Bruno

2013-01-01T23:59:59.000Z

270

40 | Environmental Engineer & Scientist Spring 2014 | V 50, N 2 WATERDISINFECTIONUSINGNANOTECHNOLOGYFORSAFER  

E-Print Network [OSTI]

is highly contaminated with human and ani- mal wastes. A prototype fluidized bed photoreactor -- amended mechanical, electronic, photonic, and magnetic properties (Qu et al. 2012). In addition to individual is frequently contaminated by waste discharge from upstream, runoff from large- scale agricultural sites

Alvarez, Pedro J.

271

Enhancement of CO2/N2 selectivity in a metal-organic framework by cavity modification  

E-Print Network [OSTI]

electricity is a major source of CO2 in the atmosphere, but the capture and sequestration of CO2 from flue gas two-thirds), CO2, water vapor, oxygen, and minor components such as carbon monoxide, nitrogen oxides

272

The bioinorganic chemistry of N2S2 metal complexes: reactivity and ligating ability  

E-Print Network [OSTI]

[N,N??-bis-(mercaptoethyl)-1,5-diazacyclooctanato]NiII, Ni-1, is known to undergo metallation reactions with numerous metals. [N,N??-bis-(mercaptoethyl)-1,5-diazacycloheptanato]NiII, (bme-dach)Ni or Ni-1??, differs from Ni-1 by one less carbon...

Golden, Melissa Lynn

2005-08-29T23:59:59.000Z

273

Holographic Dark Energy with Time Varying n^2 Parameter in Non-Flat Universe  

E-Print Network [OSTI]

We consider a holographic dark energy model, with a varying parameter, n, which evolves slowly with time. We obtain the differential equation describing evolution of the dark energy density parameter, $\\Omega_d$, for the flat and non-flat FRW universes. The equation of state parameter in this generalized version of holographic dark energy depends on n.

Bushra Majeed; Mubasher Jamil; Azad A. Siddiqui

2014-11-01T23:59:59.000Z

274

Transported PDF Modeling of Nonpremixed Turbulent CO/H-2/N-2 Jet Flames  

SciTech Connect (OSTI)

Turbulent CO/H{sub 2}/N{sub 2} (syngas) flames are simulated using a transported composition probability density function (PDF) method. A consistent hybrid Lagrangian particle/Eulerian mesh algorithm is used to solve the modeled PDF transport equation. The model includes standard k? turbulence, gradient transport for scalars, and Euclidean minimum spanning tree (EMST) mixing. Sensitivities of model results to variations in the turbulence model, the treatment of radiation heat transfer, the choice of chemical mechanism, and the PDF mixing model are explored. A baseline model reproduces the measured mean and rms temperature, major species, and minor species profiles reasonably well, and captures the scaling that is observed in the experiments. Both our results and the literature suggest that further improvements can be realized with adjustments in the turbulence model, the radiation heat transfer model, and the chemical mechanism. Although radiation effects are relatively small in these flames, consideration of radiation is important for accurate NO prediction. Chemical mechanisms that have been developed specifically for fuels with high concentrations of CO and H{sub 2} perform better than a methane mechanism that was not designed for this purpose. It is important to account explicitly for turbulencechemistry interactions, although the details of the mixing model do not make a large difference in the results, within reasonable limits.

Zhao, xinyu; Haworth, D. C.; Huckaby, E. David

2012-01-01T23:59:59.000Z

275

JOURNAL DE PHYSIQUE Colloque Cl, supplment au n2. Tome 47, fvrier 1986 page ci-919  

E-Print Network [OSTI]

OF THE DIFFUSION OF OXYGEN ON THE AGING OF ZINC OXIDE-BASED VARISTORS D. BINESTI, J.-P. BONNET, M. ONILLON and R of zinc oxide-based varistors has been studied at 650°C in CO-CO, mixtures in order to correlate ageing. I - INTRODUCTION The zinc oxide-based varistors exhibit a marked non-linearity in their current vs

Boyer, Edmond

276

Innovative Concepts Phase I: Inorganic Membranes for CO2/N2 Separation  

SciTech Connect (OSTI)

Silica membranes were prepared using a novel technique of catalyzed-atomic layer deposition of silica within a mesoporous matrix. Pyridine was used to catalyze the silicon chloride attachment to the hydroxylated silica surface at room temperature. This half-reaction was followed by the hydration of the surface with water regenerating surface hydroxyls and completing one reaction cycle. The technique resulted in the self-limited pore size reduction of the mesoporous matrix to pore sizes near 1 nm. The self-limited reaction was presumed to be the exclusion of the large catalyst molecule from the pore entrance. In addition to pore size reduction, viscous flow defects were repaired without significantly reducing overall porosity of the membrane. In addition, we investigated the ability of amine-functionalization to enhance the CO{sub 2} transport in silica membranes. Specifically, we examined three synthesis techniques for functionalizing silica membranes with amino groups that resulted in different surface chemistries of the silica membranes. These differences were correlated with changes in the CO{sub 2} facilitation characteristics. It was found that high loadings of amino groups where interaction with the silica surface was minimized promoted the highest CO{sub 2} transport.

William Desisto

2003-09-23T23:59:59.000Z

277

Synthesis and Characterization of Th2N2(NH) Isomorphous to Th2N3  

SciTech Connect (OSTI)

Using a new, low-temperature, fluoride-based process, thorium nitride imide of the chemical formula Th{sub 2}N{sub 2}(NH) was synthesized from thorium dioxide via an ammonium thorium fluoride intermediate. The resulting product phase was characterized by powder X-ray diffraction (XRD) analysis and was found to be crystallographically similar to Th{sub 2}N{sub 3}. Its unit cell was hexagonal with a space group of P3m{bar 1} and lattice parameters of a = b = 3.886(1) and c = 6.185(2) {angstrom}. The presence of -NH in the nitride phase was verified by Fourier transform infrared spectroscopy (FTIR). Total energy calculations performed using all-electron scalar relativistic density functional theory (DFT) showed that the hydrogen atom in the Th{sub 2}N{sub 2}(NH) prefers to bond with nitrogen atoms occupying 1a Wyckoff positions of the unit cell. Lattice fringe disruptions observed in nanoparticle areas of the nitride species by high-resolution transmission electron microscopic (HRTEM) images also displayed some evidence for the presence of -NH group. As ThO{sub 2} was identified as an impurity, possible reaction mechanisms involving its formation are discussed.

Silva, G W Chinthaka M [ORNL; Yeamans, Charles B. [University of California, Berkeley; Hunn, John D [ORNL; Sattelberger, Alfred P [Argonne National Laboratory (ANL); Czerwinski, Ken R. [University of Nevada, Las Vegas; Weck, Dr. Phil F [University of Nevada, Las Vegas

2012-01-01T23:59:59.000Z

278

COLLOQUE DE PHYSIQUE Colloque C2, supplment au n*2. Tome 51, Fvrier 1990 ,,_ ,, 7  

E-Print Network [OSTI]

TURBINES GAZ P. WETTA METRAVIB R . D . S . , Dpartement Acoustique, 64 Chemin d e s M o u i l l e s , BP coordonnes cylindriques, ont t appliques la surveillance acoustique de turbines gaz et ont montr avec turbines gaz. Dans ce domaine en effet la demande de systmes de surveillance fiables et performants est

Paris-Sud XI, Universit de

279

Structures, Energetics and Spectroscopic Fingerprints of Water Clusters n = 2-24  

SciTech Connect (OSTI)

Water's function as a universal solvent and its role in mediating several biological functions that are responsible for sustaining life has created tremendous interest in the understanding of its structure at the molecular level.1 Due to the size of the simulation cells and the sampling time needed to compute many macroscopic properties, most of the initial simulations are performed using a classical force field whereas several processes that involve chemistry are subsequently probed with electronic structure based methods. A significant effort has therefore been devoted towards the development of classical force fields for water.2 Clusters of water molecules are useful in probing the intermolecular interactions at the microscopic level as well as providing information about the subtle energy differences that are associated with different bonding arrangements within a hydrogen bonded network. They moreover render a quantitative picture of the nature and magnitude of the various components of the intermolecular interactions such as exchange, dispersion, induction etc. They can finally serve as a vehicle for the study of the convergence of properties with increasing size.

Yoo, Soohaeng; Xantheas, Sotiris S.

2012-01-01T23:59:59.000Z

280

JOURNAL DE PHYSIQUE Colloque CI, supplement au n2. Tome 47, fevrier 1986 page cl-861  

E-Print Network [OSTI]

are particularly important in the case of cobalt-doped zinc oxide, which is the major phase in varistor materials energy levels in the forbidden band. I - INTRODUCTION Zinc oxide is a n-type semiconductor with a large energy gap ( «^ 3.2 eV) . This is generally attributed to the presence of an excess of metal

Boyer, Edmond

Note: This page contains sample records for the topic "n2 h2s hg" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Unexpected Nondissociative Binding of N2O on Oxygen Vacancies on a Rutile  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear SecurityTensile Strain Switched Ferromagnetism in Layeredof2014National Nuclear23,Diversity of Signal Peptides

282

Unique Thylakoid Membrane Architecture of aUnicellular N2-Fixing  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear SecurityTensile Strain Switched Ferromagnetism in Layeredof2014National Nuclear23,Diversity part 2

283

Reversible CO Binding Enables Tunable CO/H2 and CO/N2 Separations in  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinanInformation Desert Southwest RegionatSearch Welcome toResearch AreasResearchRetiree BenefitsRevCom

284

Accurate dipole polarizabilities for water clusters n=2-12 at the  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc Documentation RUCProductstwrmrAre the Effects ofAboutTestAccounting -

285

Lean NOx Trap Regeneration Selectivity Towards N2O -- Similarities and  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-UpHeatMulti-Dimensionalthe10 DOEWashington,LM-04-XXXXLocated and

286

Selective Catalytic Oxidation (SCO) of NH3 to N2 for Hot Exhaust Treatment  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion |Energy Usage » SearchEnergyDepartment of Energy Moniz: WhatM-1at the High Temperature|

287

A common intermediate for N2 formation in enzymes and zeolites: side-on  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinanInformation Desert SouthwestTechnologies |November 2011A FirstEMSL ShellACalmodulin inU T

288

N2O Emissions From 2010 SCR Systems | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion | Department ofT ib l L d F S i DOEToward a PeacefulDriving Demand What's WorkingMyronN.

289

15N2 formation and fast oxygen isotope exchange during pulsed 15N18O  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinanInformation Desert SouthwestTechnologies | BlandinePrincetonOPT OpticsFrequently Asked12

290

E-Print Network 3.0 - avian influenza h9n2 Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Sciences and Ecology 6 DIVA SOLUTIONS Pty Ltd Investment Profile Summary: is the first line of defence against Avian Influenza pandemics in humans. This involves measures......

291

Understanding denitrification with stable isotope measurements of N2: proof of concept study  

E-Print Network [OSTI]

show that the use of [DELTA]?N-N? isotope ratios can be used in conjunction with N? concentrations and environmental conditions to elucidate the mechanisms of denitrification in both estuarine and coastal waters. Additionally, MRP results imply...

Downer, Roswell Curtis

2004-01-01T23:59:59.000Z

292

Glutathione Complex Formation With Mercury(Ii) in Aqueous Solution at Physiological Ph  

SciTech Connect (OSTI)

The mercury(II) complexes formed in neutral aqueous solution with glutathione (GSH, here denoted AH{sub 3} in its triprotonated form) were studied using Hg L{sub III}-edge extended X-ray absorption fine structure (EXAFS) and {sup 199}Hg NMR spectroscopy, complemented with electrospray ionization mass spectrometric (ESI-MS) analyses. The [Hg(AH){sub 2}]{sup 2-} complex, with the Hg-S bond distances at 2.325 {+-} 0.01 {angstrom} in linear S-Hg-S coordination, and the {sup 199}Hg NMR chemical shift at -984 ppm, dominates except at high excess of glutathione. In a series of solutions with C{sub Hg(II)} {approx} 17 mM and GSH/Hg(II) mole ratios rising from 2.4 to 11.8, the gradually increasing mean Hg-S bond distance corresponds to an increasing amount of the [Hg(AH){sub 3}]{sup 4-} complex. ESI-MS peaks appear at -m/z values of 1208 and 1230 corresponding to the [Na{sub 4}Hg(AH){sub 2}(A)]{sup -} and [Na{sub 5}Hg(AH)(A){sub 2}]{sup -} species, respectively. In another series of solutions at pH 7.0 with CHg(II) 50 mM and GSH/Hg(II) ratios from 2.0 to 10.0, the Hg L{sub III}-edge EXAFS and {sup 199}Hg NMR spectra show that at high excess of glutathione (0.35 M) about 70% of the total mercury(II) concentration is present as the [Hg(AH){sub 3}]4- complex, with the average Hg-S bond distance 2.42 {+-} 0.02 {angstrom} in trigonal HgS{sub 3} coordination. The proportions of HgSn species, n = 2, 3, and 4, quantified by fitting linear combinations of model EXAFS oscillations to the experimental EXAFS data in our present and previous studies were used to obtain stability constants for the [Hg(AH){sub 3}]{sup 4-} complex and also for the [Hg(A){sub 4}]{sup 10-} complex that is present at high pH. For Hg(II) in low concentration at physiological conditions (pH 7.4, C{sub GSH} = 2.2 mM), the relative amounts of the HgS{sub 2} species [Hg(AH){sub 2}]{sup 2-}, [Hg(AH)(A)]{sup 3-}, and the HgS{sub 3} complex [Hg(AH){sub 3}]{sup 4-} were calculated to be 95:2:3. Our results are not consistent with the formation of dimeric Hg(II)-GSH complexes proposed in a recent EXAFS study.

Mah, V.; Jalilehvand, F.; /SLAC

2012-08-23T23:59:59.000Z

293

Kinetic study of hydrogen sulfide absorption in aqueous chlorine solution  

E-Print Network [OSTI]

). This technique involves H2S mass transfer in an aqueous phase using a gas-liquid contactor. Since H2S is poorly. This scrubbing liquid is just drained when the salt accumulation due to H2S oxidation into sulfate anions becomes Hydrogen sulfide (H2S) is currently removed from gaseous effluents by chemical scrubbing using water

Paris-Sud XI, Université de

294

SSC v s . Hg at 0 -150,000 c fs SSC vs. Hg at 150,000 -370,000 cfs  

E-Print Network [OSTI]

a weir from the Sacramento River into the Yolo Bypass when flows are above 70,000 cubic feet per second through the Yolo Bypass, had not been described yet. To assess pollutant loads from the Delta more accurately, loads from the Sacramento watershed, including the contribu- tion of flow from the Yolo Bypass

295

Project 2012: Increasing Female Representation in Government  

E-Print Network [OSTI]

Slovenia Ukraine Hungary Croatia Bosnia and Herzegovina Rep.HG) Chile (HS/HG) Croatia (HG) Finland (HS) Germany (HG)

McLean, Lindsey

2011-01-01T23:59:59.000Z

296

Quantum Spin Hall Effect and Topological Phase Transition in HgTe Quantum Wells  

SciTech Connect (OSTI)

We show that the quantum spin Hall (QSH) effect, a state of matter with topological properties distinct from those of conventional insulators, can be realized in mercury telluride-cadmium telluride semiconductor quantum wells. When the thickness of the quantum well is varied, the electronic state changes from a normal to an 'inverted' type at a critical thickness d{sub c}. We show that this transition is a topological quantum phase transition between a conventional insulating phase and a phase exhibiting the QSH effect with a single pair of helical edge states. We also discuss methods for experimental detection of the QSH effect.

Bernevig, A.

2010-03-02T23:59:59.000Z

297

Investigation of HgTe-CdTe superlattices grown by molecular beam epitaxy.  

E-Print Network [OSTI]

??[Truncated abstract] Infrared detection finds application in a wide range of fields, including remote sensing, astronomy, medicine and defence. Many of these applications, which require (more)

Hatch, Stuart D.

2010-01-01T23:59:59.000Z

298

2 Toxicity and Sources of Pb, Cd, Hg, Cr, As, and Radionuclides  

E-Print Network [OSTI]

........................................................................................... 33 2.3 Heavy Metal Pollution Sources ..................................................................................................................... 14 2.1.1 Selected Heavy Metals ...................................................................................................... 27 2.2.1 Heavy Metals in Aquifers

Volesky, Bohumil

299

Characterization of a Large Format HgCdTe on Si Focal Plane Array  

E-Print Network [OSTI]

. Keasler2 Rochester Institute of Technology 1 , Raytheon Vision Systems 2 ABSTRACT The Center for Detectors (CfD) at the Rochester Institute of Technology (RIT) and Raytheon Vision Systems (RVS) are advancing. The Center for Detectors (CfD) at the Rochester Institute of Technology (RIT) and Raytheon Vision Systems

Figer, Donald F.

300

H.G. Kirk May 31, 2007 MERIT Pulsed Solenoid Status  

E-Print Network [OSTI]

with cryo experts at BNL led us to consider an alternative sealant material know as Gore-Tex Joint Sealant precisely the environment of the electrical leads penetrations at both room temperature and 800 K A testing-bar gaseous He at both cryogenic and room temperatures. This exceeds the expected operating conditions

McDonald, Kirk

Note: This page contains sample records for the topic "n2 h2s hg" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

A Free Jet Hg Target Operating in a High Magnetic Field Intersecting  

E-Print Network [OSTI]

2005 Venice, Italy August 29 ­ Sept 1, 2005 #12;2 OAK RIDGE NATIONAL LABORATORY U. S. DEPARTMENT OF ENERGY AccApp05 Background · Proof-of-principle experiment to investigate the interaction of a proton. DEPARTMENT OF ENERGY AccApp05 Participants · BNL, Princeton ­ project oversight, nozzle development, beam

McDonald, Kirk

302

Elsevier Science 1 A Free Jet Hg Target Operating In a High Magnetic Field  

E-Print Network [OSTI]

University, Massachusetts Institute Of Technology, European Organization for Nuclear Research system and the mercury to CERN, decommissioning the experiment, and returning the mildly activated

McDonald, Kirk

303

Microbial pathways for the mobilization of mercury as Hg(O) in anoxic subsurface environments  

SciTech Connect (OSTI)

The goal of our project which was initiated in June 2005 is focused on the presence of merA in microbial communities of anoxic environments and the effect of anaerobic respiratory pathways on MR expression and activities. The following progress has been made to date: PCR primers were designed to span the known phylogenetic range of merA genes of Gram-negative bacteria. In control experiments, these primers successfully amplified a 288 bp region at the 3? end of previously characterized merA genes from Shewanella putrefaciens pMERPH, Acidithiobacillus ferrooxidans, Pseudomonas stutzeri pPB, Tn5041, Pseudomonas sp. K-62, and Serratia marcescens pDU1358.

Barkay, Tamar

2005-06-01T23:59:59.000Z

304

H.G. Rickover, 1964 | U.S. DOE Office of Science (SC)  

Office of Science (SC) Website

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear SecurityTensile Strain Switched5 Industrial CarbonArticlesHumanJuneDocumentingFermiGeorge A.Rise | U.S.H.G. Rickover,

305

The Secondary Star of the HgMn Binary Phi Her  

E-Print Network [OSTI]

The binary nature of the bright (V = 4.2 mag) Mercury-Manganese star Phi Her has been known since 1976 and it was considered a low-amplitude single-lined SB. In a recent study we found evidence for lines of the secondary star. Other recent results from interferometry provide a good measure of the light ratio. It is very plausible that the secondary is a late main-sequence A star. We find the rotational velocity of the secondary to be ~42 +/- 5 km/s.

M. M. Dworetsky; Rosemary Willatt

2006-12-15T23:59:59.000Z

306

CORRLATION ANGULAIRE DES NEUTRONS MIS DANS LES RACTIONS 9Be(n, 2n)8Be ET 209Bi(n, 2n)208Bi A 14 MeV  

E-Print Network [OSTI]

.), AECL, 1961, n° 32. RETHMEIER (J.), Thèse, Amsterdam, 1961. RETHMEIER (J.), JONKER (C. C.), RODENBURG (M

Paris-Sud XI, Université de

307

Novel -Distonic Radical Cations [CnH2n+2S]+ (n ) 2, 3) Formed upon Decarbonylation of Ionized S-Alkyl Thioformates: A Mass Spectrometric and ab Initio Study  

E-Print Network [OSTI]

ions. Strong evidence for the distonic nature of the fragment ions derived from 2-7·+ has been obtained to intense peaks corresponding to H2S·+ and ionized olefins. Portions of the potential energy surface related explored in the gas phase by a variety of mass spectral methods.2,3 In particular, the -distonic isomer

Nguyen, Minh Tho

308

Beam foil spectroscopy of N = 3 to N = 2 transitions in highly stripped heavy ions. Revision 1  

SciTech Connect (OSTI)

The spectroscopy of very highly ionized atoms provides an important testing ground for multi-electron atomic theory. We report preliminary experimental results on the n = 3 ..-->.. 2 spectra of Bi/sup +73/ and A/sup +69/ obtained at the GSI UNILAC accelerator. 19 refs., 4 figs.

Dietrich, D.D.; Chandler, G.A.; Egan, P.O.; Ziock, K.P.; Mokler, P.H.; Reusch, S.; Hoffmann, D.H.H.

1986-09-01T23:59:59.000Z

309

266 CHIL. J. AGRIC. RES. -VOL. 70 -N 2 -2010 VARIABILITY OF SOIL TYPES IN WETLAND MEADOWS IN THE SOUTH  

E-Print Network [OSTI]

IN THE SOUTH OF THE CHILEAN PATAGONIA Ladislava Filipová1* , Radim Hédl2 , and Nilo Covacevich C.3 ABSTRACT Patagonia are productive and intensively exploited ecosystems. However, there is scarce data about and canyons of Patagonia, produced by the fusion of Pleistocene glaciers, there are wetland meadows locally

Hédl, Radim

310

Embedding into the rectilinear plane in optimal O(n2 Nicolas Catusse, Victor Chepoi, and Yann Vax`es  

E-Print Network [OSTI]

, and Yann Vax`es Laboratoire d'Informatique Fondamentale, Universit´e d'Aix-Marseille, Facult´e des Sciences de Luminy, F-13288 Marseille Cedex 9, France {catusse,chepoi,vaxes}@lif.univ-mrs.fr Abstract

Chepoi, Victor

311

Formation and Genotoxicity of Novel Oxidatively Generated Tandem DNA Lesions and N2-(1-carboxyethyl)-2'-deoxyguanosine  

E-Print Network [OSTI]

Nucleic Acids Res. 33, 1593-1603. von Sonntag, C. (1987) TheNucleic Acids Res. 33, 1593-1603. Liu, Z. J. , Gao, Y. , andNucleic Acids Res. 33, 1593-1603. Wang, Y. (2008) Bulky DNA

Jiang, Yong

2009-01-01T23:59:59.000Z

312

109Agrociencia. (2006) Vol. X N 2 pg. 109 -124 FORESTACIN EN PASTIZALES: HACIA UNA VISIN INTEGRAL DE  

E-Print Network [OSTI]

posiblemente por el inminente comercio de bonos de carbono. Evaluamos como esta transformacin afecta la preexisting and original information on their influence on biomass production, water dynamics, and nutrient

Jackson, Robert B.

2006-01-01T23:59:59.000Z

313

PET exam A 424304 20-032013 Short answers 111. Ex = Ex (O2) + Ex(N2) + Ex (unmix)  

E-Print Network [OSTI]

,7 = 3018,0 kJ/mol L Ex mix gases = 6*R*T*ln (½) = -10,1 kJ/mol L losses = 998,0 + 2678,9 ­ 3018,0 + 10. outsideoutside outside outside glass window outside outside outside window inside A R FA R A R Eb R J R J R Eb 11) · (h - T·s) = (O2) ·(cp· T - T·cp·ln(T/T) + R·T·cp·ln(p/p) ) ---------- T effect ----- ---- p effect

Zevenhoven, Ron

314

CCCG 2013, Waterloo, Ontario, August 810, 2013 Maximum-Weight Planar Boxes in O(n2  

E-Print Network [OSTI]

and Coordination in Networks ICM/FIC P10- 024F, Mideplan, Chile. §Escuela de Ingenier´ia Civil en Inform

Chan, Timothy M.

315

Catalytic oxidative coupling of methane over Li/MgO using N2O as an oxidant  

E-Print Network [OSTI]

for methanol synthesis at 240 to 260 C and 5 to 10 MPa pressure. In the second step, HZSM ? 5 zeolite is used as a catalyst, to synthesize gasoline from methanol at. about 360 to 415 C and 2. 0 MPa pressure. The latter part, of this technology was developed... is converted to synthesis gas by steam reforming and the methanol synthesis uses conventional technology. The advent of this technology (MTG process), which synthesizes high octane gasoline from methanol, may be contrasted with the Fischer ? Tropsch process...

Yamamoto, Hiroshi

1992-01-01T23:59:59.000Z

316

Boltzmann Equation Analysis and Monte Carlo Simulation of Electron Transport in N2-O2 streamer discharge  

E-Print Network [OSTI]

energy, drift velocity, diffusion coefficients and rate coefficients are reported. 1. Introduction of electrons and ions in regions of high electric field; (2) drift and diffusion in the local electric field trees [6]. In particular, fluid models and/or fluid parts of hybrid models of streamers often require

Ebert, Ute

317

Spectroscopic and Electronic Structure Studies of the 4-Sulfide Bridged Tetranuclear CuZ Cluster in N2O  

E-Print Network [OSTI]

Tecnologia, UniVersidade NoVa de Lisboa, 2825-114 Caparica, Portugal Received April 8, 2002 Abstract

Chen, Peng

318

Electronic Structure Description of the 4-Sulfide Bridged Tetranuclear CuZ Center in N2O Reductase  

E-Print Network [OSTI]

Versity, Stanford, California 94305, Departamento de Quimica, CQFB, Faculdade de Cie^ncias e Tecnologia, Uni

Chen, Peng

319

Test plan for N2 HEPA filters assembly shop stock used on PFP E4 exhaust system  

SciTech Connect (OSTI)

At Plutonium Finishing Plant (PFP) and Plutonium Reclamation Facility (PRF) Self-contained HEPA filters, encased in wooden frames and boxes, are installed in the E4 Exhaust Ventilation System to provide confinement of radioactive releases to the environment and confinement of radioactive contamination within designated zones inside the facility. Recently during the routine testing in-leakage was discovered downstream of the Self-contained HEPA filters boxes. This Test Plan describes the approach to conduct investigation of the root causes for the in-leakage of HEPA filters.

DICK, J.D.

1999-09-01T23:59:59.000Z

320

Formation and Genotoxicity of Novel Oxidatively Generated Tandem DNA Lesions and N2-(1-carboxyethyl)-2'-deoxyguanosine  

E-Print Network [OSTI]

and E. coli strains; Prof. Myron F. Goodman for offering theprovided by Prof. Myron F. Goodman (29). Human polymerase ?

Jiang, Yong

2009-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "n2 h2s hg" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

JOURNAL DE PHYSIQUE Colloque C2, supplement au n2, Tome 46, fevrier 1985 page C2-*75  

E-Print Network [OSTI]

to a quark description of t' . We recall the Lennar-Jones fbrce between point atoms effectively replacing

Paris-Sud XI, Université de

322

Current biofuel feedstock crops such as corn lead to large environmental losses of N through nitrate leaching and N2  

E-Print Network [OSTI]

219 Current biofuel feedstock crops such as corn lead to large environmental losses of N through biofuel crops established on a rich Mollisol soil. Reduced Nitrogen Losses after Conversion of Row Crop Agriculture to Perennial Biofuel Crops Candice M. Smith, Mark B. david,* Corey A. Mitchell, Michael d. Masters

DeLucia, Evan H.

323

Revista Electrnica de Enseanza de las Ciencias Vol. 2 N 2 (2003) Metalibros: La construccin colectiva de un recurso  

E-Print Network [OSTI]

Revista Electrónica de Enseñanza de las Ciencias Vol. 2 Nº 2 (2003) Metalibros: La construcción Internet Juan Miguel Campanario Grupo de Investigación sobre Aprendizaje de las Ciencias. Departamento de enseñanza de las ciencias. Palabras clave: Libros de texto, nuevas tecnologías, renovación educativa

Campanario, Juan Miguel

324

JOURNAL DE PHYSIQUE Colloque C2, supplement au n2, Tome 46, fevrier 1985 page C2-463  

E-Print Network [OSTI]

quasi-free incident protons and neutrons a r e consistent with in- dependence on A0 only a t Aerec > 0 , whereas a t Aerec

Paris-Sud XI, Université de

325

HNO3, N2O5, and ClONO2 enhancements after the OctoberNovember 2003 solar proton  

E-Print Network [OSTI]

Investigaciones Cienti´ficas, Granada, Spain T. von Clarmann, G. P. Stiller, M. Ho¨pfner, S. Kellmann, G. Mengistu pronounced. Citation: Lo´pez-Puertas, M., B. Funke, S. Gil-Lo´pez, T. von Clarmann, G. P. Stiller, M. Ho

Jackman, Charles H.

326

The structure and electrochemical behavior of nitrogen-containing nanocrystalline diamond films deposited from CH4/N2/Ar mixtures.  

SciTech Connect (OSTI)

Electrically conductive nanocrystalline diamond films (approximately 750 to 1000 nm thick) were deposited on conducting Si and W substrates from CH{sub 4}/N{sub 2}/Ar gas mixtures using plasma-enhanced chemical vapor deposition. Such films are continuous over the surface and nanometer smooth. The grain size is 3 to 10 nm, and the grain boundaries are 0.2 to 0.5 nm wide (two carbon atoms). Nitrogen appears to substitutionally insert into the grain boundaries and the film concentration ({approx}10{sup 20} atom/cm{sup 3}) scales with the N{sub 2} added to the source gas mixture up to about the 5% level. The nitrogen-incorporated films are void of pinholes and cracks, and electrically conducting due in part to the high concentration of nitrogen impurities and or the nitrogen-related defects (sp{sup 2} bonding). The films possess semimetallic electronic properties over a potential range from at least -1.5 to 1.0 V vs. SCE. The electrodes, like boron-doped microcrystalline diamond, exhibit a wide working potential window, a low background current, and high degree of electrochemical activity for redox systems such as Fe(CN)6{sup -3/-4}, Ru(NH{sub 3}6{sup +3/+2}), IrCl6{sup -2/-3}, and methyl viologen (MV{sup +2/+}). More sluggish electrode kinetics are observed for 4-methylcatechol, presumably due to weak adsorption on the surface. Apparent heterogeneous electron transfer rate constants of 10{sup -2} to 10{sup -1} cm/s are observed for Fe(CN)6{sup -3/-4}, Ru(NH{sub 3})6{sup +3/+2}, IrCl6{sup -2/-3}, and MV {sup +2/+} at films without any pretreatment.

Chen, Q.; Gruen, D. M.; Krauss, A. R.; Corrigan, T. D.; Swain, G. M.; Utah State Univ.; Northwestern Univ.

2001-01-01T23:59:59.000Z

327

International Journal of Structural Changes in Solids (IJSCS), 2, N2, (2010), Materials with a desired refraction coefficient can  

E-Print Network [OSTI]

and discussed. The desired refraction coefficient can be complex-valued. This means that the enrgy absorption

328

COLLOQUE DE PHYSIQUE Colloque C2, supplment au n2, Tome 51, Fvrier 1990 C2-587  

E-Print Network [OSTI]

are related to the periodicity of the ceramic bars into the matrix. To avoid the influence of the lateral Franais d'Acoustique 1990 BROAD-BAND CERAMIC-POLYMER PIEZOELECTRIC COMPOSITES M. SOL SANCHEZ, F.R. MONTERO to enlarge the frequency of (1-3) ceramic polymer piezoelectric composites. In this paper a new concept of (1

Paris-Sud XI, Universit de

329

JOURNAL DE PHYSIQUE Colloque C2, supplement au n2, Tome 46, fevrier 1985 page C2-289  

E-Print Network [OSTI]

amplitudes has been used C2,43. There a r e two s e t s of nucleon transversity amplitudes Ugi- r e c o i l

Paris-Sud XI, Université de

330

COLLOQUE DE PHYSIQUE Colloque C2, supplment au n"2. Tome 51, Fvrier 1990 C2-221  

E-Print Network [OSTI]

://dx.doi.org/10.1051/jphyscol:1990253 #12;COLLOQUE DE PHYSIQUE avec + 1 v(bords)= $+cl1a[J(a, 1) + w2 (a,- da+ 1 I

Boyer, Edmond

331

Brady et al. Geological Materials Research v.1, n.2, p.1 Copyright 1998 by the Mineralogical Society of America  

E-Print Network [OSTI]

) and several major talc mines were in operation in the 1990's. Olson (1976) and Berg (1979) described , Chris Green2 , Mathieu Duvall3 , Ari Kogut4 Lewis Kaufman5 , Dana Kovaric1 Departments of Geology: 1 of America Introduction Talc has been mined in southwest Montana for over fifty years (Olson, 1976

Brady, John B.

332

USE OF NITROGEN BUDGETS AND N2 FLUX MEASUREMENTS TO ESTIMATE THE ROLE OF DENITRIFICATION IN BROWNFIELD STORMWATER WETLANDS  

E-Print Network [OSTI]

IN BROWNFIELD STORMWATER WETLANDS Monica M. Palta 1, Peter Groffman2, Stuart Findlay2 1 School of Life Sciences in inorganic nitrogen cycling and removal in urban brownfield wetlands INTRODUCTION · Urban areas are net BROWNFIELD SITES SUPPORTING SEMI-PERMANENTLY FLOODED WETLANDS. White outlines delineate low-lying semi

Hall, Sharon J.

333

King Air flight RICO 20050116 page 1 King Air N2UW flight report for January 16, 2005.  

E-Print Network [OSTI]

of the inversion winds turned westerly; this is clearly visible in the inclination of the turrets in photographs the easterly low level winds. At flight level, winds outside the clouds were from the south, but in clouds the in situ measured updraft was up to 10 m s1 and the LWC approached 2 g m3. The pronounced wind shear near

Vali, Gabor

334

JOURNAL DE PHYSIQUE Colloque C2, supplment au n2, Tome 45, fvrier 1984 page C2-705  

E-Print Network [OSTI]

) a STEM analysis of centrifugally-atomised powders of high-phosphorous steels, and (b) a study the need for detailed microstructural analysis. Also, with the reduction in size of characteristic and an electron energy loss spectrometer. The electron source is a cold tungsten field emitter. There is a two

Paris-Sud XI, Université de

335

Selective Binding of O2 over N2 in a Redox-Active Metal-Organic Framework  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinanInformation Desert Southwest RegionatSearchScheduled System OutagesNewsMaterials Center atwith Open

336

Photoelectron Imaging of Doubly Charged Anions, -O2C(CH2)nCO2- (n=2-8):  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the1 - September 2006 TheStevenAdministration Album OfHCO3-. |

337

Physisorption of N2, O2, and CO on Fully Oxidized TiO2(110). | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the1 - September 2006Photovoltaic Theory and Modeling LosPhysics LinksPhysisorption of

338

QEPAS based ppb-level detection of CO and N2O using a high power CW DFB-QCL  

E-Print Network [OSTI]

), distributed feedback quantum cascade laser (DFB-QCL) operating at 10°C as the excitation source. For the R(6­1995 (1997). 5. L. Tao, K. Sun, D. J. Miller, M. A. Khan, and M. A. Zondlo, "Optimization for simultaneous, and H. Fischer, "Real-time measurements of atmospheric CO using a continuous-wave room temperature

339

updated_supplemental_lists_1n-2n-3m_07-06-2012.xlsx | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarlyEnergyDepartment ofDepartment of EnergyofDepartmentDEPARTMENT wasm-2m-3l-04-05-2012.xlsx

340

A Hydrogen-Evolving Ni(P2N2)2 Electrocatalyst Covalently Attached to a  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinanInformation Desert SouthwestTechnologies |November 2011A First Look at Yeast FattyA GreenerGlassy Carbon

Note: This page contains sample records for the topic "n2 h2s hg" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

On the Action of Acyl Reagents on the Substituted Ureas  

E-Print Network [OSTI]

)gCO RCoCl RNHCONR * HG1 COR The acyl urea dissociates,forming an anilide compound, and an isocyanate and HC1. RNHCONR * HC1 RNHCOR RNCO HC1. I CCR 2.- RNHCOR RNCO HC1 RNHX , CR.HC1 C02 RN ' The anilide and the Isocyanate react... the following analysis * .1126 gram platinum salt gave .0239 grams platinum. .1103 grams platinum salt gave .0237 grams platinum. Calculated for (CI7Hg0N2)gPi|Cl6 Found Platinum 21.3~ 21.22 21.49 DI-METATotYL UREA and IKOWLERYL CHLORIDE. 10 grams di...

Roberts, R. Chester

1914-05-15T23:59:59.000Z

342

www.sciencemag.org SCIENCE VOL 325 28 AUGUST 2009 1079 PERSPECTIVES  

E-Print Network [OSTI]

), euxinia (anoxic water infused with H2 S) (5), or something else. There is even less agree- ment on what

Connolly Jr, Harold C.

343

The authors are solely responsible for the content of this technical presentation. The technical presentation does not necessarily reflect the official position of the American Society of Agricultural Engineers (ASAE), and its printing and distribution do  

E-Print Network [OSTI]

(NH3), hydrogen sulfide (H2S), carbon dioxide (CO2), and sulfur dioxide (SO2) from swine manure in 138). Ammonia (NH3), hydrogen sulfide (H2S), carbon dioxide (CO2) and sulfur dioxide (SO2) are among the major release and influenced H2S release. A new model of "bubble release" is proposed to explain release

Ni, Jiqin "Jee-Chin"

344

Heterometallic Ln/Hg Compounds with Fluorinated Thiolate Ligands Santanu Banerjee, Thomas J. Emge, and John G. Brennan*  

E-Print Network [OSTI]

-15699. (b) Rodriguez-Cortinas, R.; Avecilla, F.; Platas-Iglesias, C.; Imbert, D.; Buenzli, J.; de Blas, A.; Rodriguez-Blas, T. Inorg. Chem. 2002, 41, 5336-5349. (c) Buenzli, J. G.; Piguet, C. Chem. ReV. 2002, 102.; Qian, Y.-T.; Huang, J.-S. Polyhedron 2001, 20, 1795-1802. (2) (a) James, C.; Willand, P. S. J. Am. Chem

Lawson, Catherine L.

345

A 15T PULSED SOLENOID FOR A HIGHPOWER TARGET H.G Kirk # , BNL, Upton, NY 11973, USA  

E-Print Network [OSTI]

[MJ] R [mW­40] DT [K] Seconds 15.1 T, 70 K Pulse Coil Employing 315 Exide XL6000 Batteries in Series

McDonald, Kirk

346

Fate of As, Se, and Hg in a Passive Integrated System for Treatment of Fossil Plant Wastewater  

SciTech Connect (OSTI)

TVA is collaborating with EPRI and DOE to demonstrate a passive treatment system for removing SCR-derived ammonia and trace elements from a coal-fired power plant wastewater stream. The components of the integrated system consist of trickling filters for ammonia oxidation, reaction cells containing zero-valent iron (ZVI) for trace contaminant removal, a settling basin for storage of iron hydroxide floc, and anaerobic vertical-flow wetlands for biological denitrification. The passive integrated treatment system will treat up to 0.25 million gallons per day (gpd) of flue gas desulfurization (FGD) pond effluent, with a configuration requiring only gravity flow to obviate the need for pumps. The design of the system will enable a comparative evaluation of two parallel treatment trains, with and without the ZVI extraction trench and settling/oxidation basin components. One of the main objectives is to gain a better understanding of the chemical transformations that species of trace elements such as arsenic, selenium, and mercury undergo as they are treated in passive treatment system components with differing environmental conditions. This progress report details the design criteria for the passive integrated system for treating fossil power plant wastewater as well as performance results from the first several months of operation. Engineering work on the project has been completed, and construction took place during the summer of 2005. Monitoring of the passive treatment system was initiated in October 2005 and continued until May 18 2006. The results to date indicate that the treatment system is effective in reducing levels of nitrogen compounds and trace metals. Concentrations of both ammonia and trace metals were lower than expected in the influent FGD water, and additions to increase these concentrations will be done in the future to further test the removal efficiency of the treatment system. In May 2006, the wetland cells were drained of FGD water, refilled with less toxic ash pond water, and replanted due to low survival rates from the first planting the previous summer. The goals of the TVA-EPRI-DOE collaboration include building a better understanding of the chemical transformations that trace elements such as arsenic, selenium, and mercury undergo as they are treated in a passive treatment system, and to evaluate the performance of a large-scale replicated passive treatment system to provide additional design criteria and economic factors.

Terry Yost; Paul Pier; Gregory Brodie

2007-12-31T23:59:59.000Z

347

Determination of certain trapping parameters in mercury sulphide (03B1-HgS) by Thermally Stimulated Conductivity  

E-Print Network [OSTI]

, 6, 7, 8] is 2.275 eV at liquid helium, 2.250 eV at liquid nitrogen and 2.100 eV at room temperature les résultats de nos mesures de courants stimulés thermiquement sur le sulfure de mercure. Celles profondeur du niveau (Et = 300 meV), la densité de pièges (Nt = 2,55 1012 cm- 3) et la section efficace de

Boyer, Edmond

348

9 0 A S T R O N O M Y N O W / J U N 2 0 0 2 he current debate over missile defence  

E-Print Network [OSTI]

Saddam Hussein, who set fire to the oil wells in Kuwait and caused an environmental disaster hazardous for peaceful as well as military purposes. Every bit of debris in orbit higher than about 800 km

California at Santa Cruz, University of

349

Global long-lived chemical modes excited in a 3-D chemistry transport model: Stratospheric N 2 O, NO y , O 3 and CH 4 chemistry  

E-Print Network [OSTI]

chemistry about a climatology of trace?gas composition [as well as the tabulated climatology and partial derivativesteady?state control?run climatology. (c) Mode?1 is scaled

Hsu, Juno; Prather, Michael J

2010-01-01T23:59:59.000Z

350

Effects of EGR, water/N2/CO2 injection and oxygen enrichment on the availability destroyed due to combustion for a range of conditions and fuels  

E-Print Network [OSTI]

combustion of iso octane.................................................................................................... 24 3 Percentage availability destroyed for different ?Cooled? EGR fractions as a function of reactant temperature for constant... volume combustion of iso octane, reactant pressure of 500 kPa......................................................... 24 4 Product temperature for different ?Cooled? EGR fractions as a function of reactant temperature for constant pressure combustion...

Sivadas, Hari Shanker

2009-06-02T23:59:59.000Z

351

Statistica inferenziale scheda n.2 1 Matematica e statistica: dai dati ai modelli alle scelte www.dima.unige/pls_statistica  

E-Print Network [OSTI]

parametro, usando dati campionari. In questa scheda costruiremo un intervallo nel quale ci aspettiamo stia

Rogantin, Maria Piera

352

Vector Analyzing Power at Theta-Lab=18-Degrees for the H-2(p-],N)2p Reaction at 21.3 Mev  

E-Print Network [OSTI]

agreement with the exact calculations of Bruinsma and Van Wagen- ingen" and the perturbative calculations of Stolk and Tjon' for n-d breakup at 22.7 MeV, which are also shown in Fig. 2. The suspected errors in the A~ values of Ref. 7 are attributed...

Nath, S.; Northcliffe, L. C.; Hiebert, John C.; Woolverton, H. L.; York, R. L.; Graves, R. G.; Craft, B. C.

1984-01-01T23:59:59.000Z

353

The infrared spectrum of the N2H He ion-neutral complex S. A. Nizkorodov, J. P. Maier, and E. J. Bieske  

E-Print Network [OSTI]

and mass spectrometry.5,6 The method most often used involves mass selecting the species before exciting scintillation detector, with the resulting current measured by a boxcar integrator. Tunable light in the 3 m

Nizkorodov, Sergey

354

Tillage and seasonal emissions of CO2, N2O and NO across a seed bed and at the field scale in a Mediterranean climate  

E-Print Network [OSTI]

County, California, under a Mediterranean climate. We focused on the spatiotemporal variation of GHG in a Mediterranean climate Juhwan Lee a, *, Jan W. Hopmans b , Chris van Kessel a , Amy P. King b , K. Jeannie Evatt of California, Davis, CA 95616, USA b Department of Land, Air, and Water Resources, University of California

van Kessel, Chris

355

Paru dans Adoption & Fostering, 2001, vol25, n2, 49-55. Relinquishment for adoption of babies with Down's Syndrome: announcement of the  

E-Print Network [OSTI]

with Down's Syndrome: announcement of the diagnosis to parents and institutional practices of maternity of why Down's Syndrome infants were given up for adoption, to evaluate the extent of the phenomenon noticed that a significant number of Down's Syndrome, infants were given up yearly for adoption

Paris-Sud XI, Université de

356

Activation of N2O Reduction by the Fully Reduced 4-Sulfide Bridged Tetranuclear CuZ Cluster in Nitrous Oxide Reductase  

E-Print Network [OSTI]

, California 94305, and REQUIMTE, Departmento de Quimica, CQFB, Faculdade de Cie^ncias e Tecnologia, Uni

Chen, Peng

357

Atomic-Scale Spin-Polarized Scanning Tunneling Microscopy Applied To Mn3N2(010) Haiqiang Yang and Arthur R. Smith  

E-Print Network [OSTI]

source effusion cell for Mn and a rf plasma source for N [5,6]. All STM imaging is performed at 300 K-centered tetragonal (fct) rock-salt type struc- ture. The bulk magnetic moments of the Mn atoms are FM within (001

358

PHYSICAL REVIEW A 87, 013434 (2013) Role of resonance-enhanced multiphoton excitation in high-harmonic generation of N2  

E-Print Network [OSTI]

molecular dynamics with subfemtosecond temporal resolution [3­8]. The sensitivity of HHG emissionPHYSICAL REVIEW A 87, 013434 (2013) Role of resonance-enhanced multiphoton excitation in high and Biochemistry and Center for Biomolecular Structure and Dynamics, The University of Montana, Missoula, Montana

Chu, Xi

359

Process sensing and metrology in gate oxide growth by rapid thermal chemical vapor deposition from SiH4 and N2O  

E-Print Network [OSTI]

SiO2 film. An optimal process window had been previously identified at a total pressure of 5 Torr, but also quantitative metrology for the film deposition process. © 1999 American Vacuum Society. S0734-211X the wafer. Radiative heating of the wafer was achieved through a quartz window by an array of halogen lamps

Rubloff, Gary W.

360

47Agrociencia. (2006) Vol. X N 2 pg. 47 -61 CAMBIOS EN EL USO DE LA TIERRA EN ARGENTINA Y URUGUAY  

E-Print Network [OSTI]

47Agrociencia. (2006) Vol. X N° 2 pág. 47 - 61 CAMBIOS EN EL USO DE LA TIERRA EN ARGENTINA Y. Buenos Aires, Argentina. 2 Ecología Terrestre, Facultad de Ciencias ­ Universidad de la República. Montevideo. Uruguay. 3 Grupo de Estudios Ambientales ­ Universidad Nacional de San Luis. San Luis. Argentina

Nacional de San Luis, Universidad

Note: This page contains sample records for the topic "n2 h2s hg" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

verso impressa ISSN 0101-7438 / verso online ISSN 1678-5142 Pesquisa Operacional, v.24, n.2, p.323-337, Maio a Agosto de 2004 323  

E-Print Network [OSTI]

eficientes de- vido a aspectos econômicos e avanços computacionais. Isto incentiva o crescimento de modelos

Oliveira, Aurélio R. L.

362

Appendix: A Chemistry Primer A pure substance is one with a definite chemical formula,. e.g., N2 or H2O. Atomic  

E-Print Network [OSTI]

is its heat capacity. In fact, there are two standard versions of heat capacity, depending on how liquid or gas, its state is determined by its temperature, T, its pressure, p, and its volume, V as holding for many gases around 273o K (0o F) and 1 atmosphere. But equations of state for liquids in wide

Yu, Gexin

363

T h e R e n s s e l a e R P l a n 2 0 2 4 initiatives  

E-Print Network [OSTI]

" and "infrastructural Resilience, Sustainability, and Stewardship." in Undergraduate education, we will target an under research umbrellas: "Beyond the internet: Digital Meets and "infrastructural Resilience, Sustainability, and global levels. in enabling Change, we will mount a comprehensive fund-raising campaign, building upon

Bystroff, Chris

364

N2s2 chelating agents as cys-x-cys biomimics for fe(no) and fe(no)2 complexes  

E-Print Network [OSTI]

model complexes I have examined the fundamental properties of a dithiolato-Fe(NO)2 complex, bismercaptoethandiazacyclooctane iron dinitrosyl or (H+bme-daco)Fe(NO)2 as a biomimic of dicysteinate coordination of [Fe(NO)2]. This complex was prepared...

Chiang, Chao-Yi

2006-08-16T23:59:59.000Z

365

JOURNAL DE PHYSIQUE Colloque Cl ,supplt?mentau n " 2, Tome 40, fgvrier 1979,page C1-157 SPECTROSCOPY IN THE GRAZING-INCIDENCE SPECTRAL REGION  

E-Print Network [OSTI]

-atom collisions at the 600-keV heavy-ion accelerator at Aarhus University. An ellipsoidal, gold-coated mirror ARRANGEMENT The experimental arrangement is shown schematically in Fig. 1 . A gold-coated, el- lipsoidal. This was accomplished by installing a shaft encoder (LOGIK, Denmark) on the drive shaft, connect- ing the gear box

Paris-Sud XI, Université de

366

Gographie physique et Quaternaire, 2000, vol. 54, n 2, p. 135-141, 8 fig., 3 tabl. LITTLE ICE AGE HISTORY OF  

E-Print Network [OSTI]

on the northeast flank of Tzeetsaytsul Peak and terminates in a moraine-dammed lake.A stream draining thelakehas, auparcprovincialdeTweedsmuir.Leglaciertire son origine d'un champ de glace situé sur le flanc nord-est du

Smith, Dan

367

Power calculations D.A. Freedman December 2007 What is the power of a randomized controlled experiment? We assume there are n1 + n2  

E-Print Network [OSTI]

Power calculations D.A. Freedman December 2007 What is the power of a randomized controlled of the null against the alternative µ1 = µ2, and we compute power at µ1 = µ2 + k where k > 0 is chosen so is asymptotically distributed as N(k, 1), where k = k/f Suppose k > 2. If Z is N(0, 1), asymptotic power is then P

Sekhon, Jasjeet S.

368

JOURNAL DE PHYSIQUE Colloque C2, supplment au n2, Tome k5, fvrier 198^ pageC2-465  

E-Print Network [OSTI]

in propane cooled by liquid nitrogen. Sections were cut in a cryostat (temperature of the chamber: -30 C. Cell zones of t h e growth p l a t e : M = mineralized, R= r e s t i n g , P= pro1 i f e r a t i n g

Paris-Sud XI, Université de

369

188 Rev. Tecnol. Fortaleza, v. 30, n. 2, p. 188-197, dez. 2009. Paulo Csar Lodi, Jorge Gabriel Zornberg e Benedito de Souza Bueno  

E-Print Network [OSTI]

materials like geomembranes, geotextiles, geosynthetics clay liners and/ or a combination from all those. Liner. Geosynthetics. 1 Introdução A produção de resíduos sólidos urbanos tem aumentado aplicados a aterros sanitários Resumo Os liners são barreiras impermeáveis utilizadas em aterros sanitários

Zornberg, Jorge G.

370

Ultrasimple calculation of very-low-energy momentum-transfer and rotational-excitation cross sections: e-N2 scattering  

E-Print Network [OSTI]

, threshold behavior, and many-body effects such as bound-free correlation, but also for technological ap planetary atmospheres and photoelectric heating in astrophysics. Be- cause rotational energy levels are veryUltrasimple calculation of very-low-energy momentum-transfer and rotational-excitation cross

Morrison, Michael A.

371

Acidic Ionic Liquid/Water Solution as Both Medium and Proton Source for Electrocatalytic H2 Evolution by [Ni(P2N2)2]2+ Complexes  

SciTech Connect (OSTI)

The electrocatalytic reduction of protons to H2 by [Ni(PPh2NC6H4-hex2)2](BF4)2 (where PPh2NC6H4-hex2 = 1,5-di(4-n-hexylphenyl)-3,7-diphenyl-1,5-diaza-3,7-diphosphacyclooctane) in the highly acidic ionic liquid dibutylformamidium bis(trifluoromethanesulfonyl)amide shows a strong dependence on added water. A turnover frequency of 43,000-53,000 s-1 has been measured for hydrogen production at 25 C when the mole fraction of water (?H2O) is 0.72. The same catalyst in acetonitrile with added dimethylformamidium trifluoromethanesulfonate and water has a turnover frequency of 720 s?1. Thus the use of an ionic liquid/aqueous solution enhances the observed catalytic rates by more than a factor of 50 compared to acids in traditional organic solvents such as acetonitrile. Complexes [Ni(PPh2NC6H4X2)2](BF4)2 (X = H, OMe, CH2P(O)(OEt)2, Br) are also catalysts in the ionic liquid/water mixture, and the observed catalytic rates correlate with the hydrophobicity of X. This research was supported as part of the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences. Pacific Northwest National Laboratory is operated by Battelle for the U.S. Department of Energy.

Pool, Douglas H.; Stewart, Michael P.; O'Hagan, Molly J.; Shaw, Wendy J.; Roberts, John A.; Bullock, R. Morris; DuBois, Daniel L.

2012-09-25T23:59:59.000Z

372

1 x N^2 wavelength-selective switch with two cross-scanning one-axis analog micromirror arrays in a 4-f optical system  

E-Print Network [OSTI]

optical microelectromechanical systems (MEMS), optical ?berinclude optical microelectromechanical systems (MEMS),

Tsai, J C; Huang, STY; Hah, D; Wu, Ming C

2006-01-01T23:59:59.000Z

373

Low-Temperature Desorption of N2O from NO on Rutile TiO2(110)-1x1. | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: VegetationEquipment Surfaces and InterfacesAdministration - RockyTemperature 65Atomically

374

"Quaderni di Ricerca in Didattica (Science)", n. 2, 2011 G.R.I.M. (Department of Mathematics, University of Palermo, Italy)  

E-Print Network [OSTI]

svolta nell'ambito dei corsi di laurea in inge- gneria Onofrio Rosario Battaglia UOP_PERG (University-mail: battaglia@difter.unipa.it Abstract. This paper describes the outcomes of an teaching experiment conducted, University of Palermo, Italy) Battaglia. La distribuzione di Maxwell-Boltzmann ... 37 In relazione a come si

Spagnolo, Filippo

375

ADVANCED SULFUR CONTROL CONCEPTS FOR HOT-GAS DESULFURIZATION TECHNOLOGY  

SciTech Connect (OSTI)

This research project examined the feasibility of a second generation high-temperature coal gas desulfurization process in which elemental sulfur is produced directly during the sorbent regeneration phase. Two concepts were evaluated experimentally. In the first, FeS was regenerated in a H2O-O2 mixture. Large fractions of the sulfur were liberated in elemental form when the H2O-O2 ratio was large. However, the mole percent of elemental sulfur in the product was always quite small (<<1%) and a process based on this concept was judged to be impractical because of the low temperature and high energy requirements associated with condensing the sulfur. The second concept involved desulfurization using CeO2 and regeneration of the sulfided sorbent, Ce2O2S, using SO2 to produce elemental sulfur directly. No significant side reactions were observed and the reaction was found to be quite rapid over the temperature range of 500C to 700C. Elemental sulfur concentrations (as S2) as large as 20 mol% were produced. Limitations associated with the cerium sorbent process are concentrated in the desulfurization phase. High temperature and highly reducing coal gas such as produced in the Shell gasification process are required if high sulfur removal efficiencies are to be achieved. For example, the equilibrium H2S concentration at 800C from a Shell gas in contact with CeO2 is about 300 ppmv, well above the allowable IGCC specification. In this case, a two-stage desulfurization process using CeO2 for bulk H2S removal following by a zinc sorbent polishing step would be required. Under appropriate conditions, however, CeO2 can be reduced to non-stoichiometric CeOn (n<2) which has significantly greater affinity for H2S. Pre-breakthrough H2S concentrations in the range of 1 ppmv to 5 ppmv were measured in sulfidation tests using CeOn at 700C in highly reducing gases, as measured by equilibrium O2 concentration, comparable to the Shell gas. Good sorbent durability was indicated in a twenty-five-cycle test. The sorbent was exposed for 58 consecutive days to temperatures between 600C and 800C and gas atmospheres from highly reducing to highly oxidizing without measurable loss of sulfur capacity or reactivity. In the process analysis phase of this study, a two-stage desulfurization process using cerium sorbent with SO2 regeneration followed by zinc sorbent with dilute O2 regeneration was compared to a single-stage process using zinc sorbent and O2 regeneration with SO2 in the regeneration product gas converted to elemental sulfur using the direct sulfur recovery process (DSRP). Material and energy balances were calculated using the process simulation package PRO/II. Major process equipment was sized and a preliminary economic analysis completed. Sorbent replacement rate, which is determined by the multicycle sorbent durability, was found to be the most significant factor in both processes. For large replacement rates corresponding to average sorbent lifetimes of 250 cycles or less, the single-stage zinc sorbent process with DSRP was estimated to be less costly. However, the cost of the two-stage cerium sorbent process was more sensitive to sorbent replacement rate, and, as the required replacement rate decreased, the economics of the two-stage process improved. For small sorbent replacement rates corresponding to average sorbent lifetimes of 1000 cycles or more, the two-stage cerium process was estimated to be less costly. In the relatively wide middle range of sorbent replacement rates, the relative economics of the two processes depends on other factors such as the unit cost of sorbents, oxygen, nitrogen, and the relative capital costs.

A. LOPEZ ORTIZ; D.P. HARRISON; F.R. GROVES; J.D. WHITE; S. ZHANG; W.-N. HUANG; Y. ZENG

1998-10-31T23:59:59.000Z

376

* Corresponding author: Tel: +33 2 23 23 81 57 / Fax: + 33 2 23 23 81 20 Email address : pierre-francois.biard@ensc-rennes.fr  

E-Print Network [OSTI]

):50 51 H2S + 4 NaOCl + 2 NaOH Na2SO4 + 4 NaCl + 2 H2O (1)52 53 H2S consumption in the liquid phase wire mesh packing structure where liquid and gas flow co-currently at high velocity (> 1220 m.s-1 ). H2 of the process. Correlations were developed to predict both the23 pressure drop and the H2S removal efficiency

Boyer, Edmond

377

Description of coordinatively unsaturated sites regeneration over MoS2-based HDS catalysts using 35  

E-Print Network [OSTI]

envisaged. Moreover, on the sulfur edge the H2S release activation energy is too high (~ 13.5 kcal.mol-1 likely to occur on the MoS2 metallic edge through the departure of an H2S molecule. In the present paper, we aimed at examining the H2S departure from MoS2 catalysts promoted with Co and Ni. The [35 S

Boyer, Edmond

378

Sulfur Degassing From Volcanoes: Source Conditions, Surveillance, Plume Chemistry and Earth System Impacts  

E-Print Network [OSTI]

of sulfur in magmas owes much to its multiple valence states (-II, 0, IV, VI), speciation (e.g., S2, H2S, SO on the redox chemistry of sulfur: by reducing sulfur, thiosulfate, sulfite and sulfate to H2S, or oxidizing sulfur and H2S to sulfate (e.g., Takano et al. 1997; Amend and Shock 2001; Shock et al. 2010

Boyer, Edmond

379

Controlling Emissions of SOx and NOx from power plants  

E-Print Network [OSTI]

#12;Sulfur Removal Sulfur is removed from crude oil by the catalytic reaction: R-S + H2 H2S + R Until the mid 1970's the H2S was mixed back into the fuel gas. The problem with this is that the H2S is burned + CO2 This is a two step process including the scrubber and the effluent hold tank. CaSO4 (gypsum

Toohey, Darin W.

380

aphis craccivora koch: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Commerce in der Versicherungswirtschaft In: VW In: Versicherungsbetriebe (29) 1999, H. 2, S. 42-45 Wagner, F. Koch, G.: Electronic Commerce in der Schler, Axel 13...

Note: This page contains sample records for the topic "n2 h2s hg" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

araucana molina koch: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Commerce in der Versicherungswirtschaft In: VW In: Versicherungsbetriebe (29) 1999, H. 2, S. 42-45 Wagner, F. Koch, G.: Electronic Commerce in der Schler, Axel 15...

382

E-Print Network 3.0 - air voc flow Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Geosciences 28 ACCEPTED BY WATER ENVIRONMENT RESEARCH ODOR AND VOC REMOVAL FROM WASTEWATER TREATMENT PLANT Summary: of biofilters for sequential removal of H2S and VOCs from...

383

E-Print Network 3.0 - automotive fuel ratings Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

(H2S, SO2, ... Source: DOE Office of Energy Efficiency and Renewable Energy, Hydrogen, Fuel Cells and Infrastructure Technologies Program Collection: Energy Storage, Conversion...

384

Selective trace determination of sulfur and aluminum using charged particle activation analysis  

E-Print Network [OSTI]

being sought (nuclear interference) or emit a gamma ray of the same or nearly the same energy as that of the isotope being sought ( gamma interference). In either case, the detector is recording events from more than one element rather than being...-VALUE (MeV) GAMMA ENERGY (MeV) B( p, 2n)9 C 120(p n)12N AN( p, 2n) 130 24zg(p, n)2~A1 28Si( n n) 28P 32S(p, n)32C1 ~ Ca(p, n) SC ~6Ti(p, n) V 198Hg(p P)199mHg 114'Cd(p n)ll?ln 208p~(p pn)207mp~ ~Re orted 127 8. 7 129 270 297 182 426 28...

Burton, Terrence Dale

1974-01-01T23:59:59.000Z

385

Integrated pollutant removal: modeling and experimentation  

SciTech Connect (OSTI)

Experimental and computational work at the Albany Research Center, USDOE is investigating an integrated pollutant removal (IPR) process which removes all pollutants from flue gas, including SOX, NOX, particulates, CO2, and Hg. In combination with flue gas recirculation, heat recovery, and oxy-fuel combustion, the process produces solid, gas, and liquid waste streams. The gas exhaust stream comprises O2 and N2. Liquid streams contain H2O, SOX, NOX, and CO2. Computer modeling and low to moderate pressure experimentation are defining system chemistry with respect to SOX and H2O as well as heat and mass transfer for the IPR process.

Ochs, Thomas L.; Oryshchyn, Danylo B.; Summers, Cathy A.

2005-01-01T23:59:59.000Z

386

Identification and Selection of Major Carbon Dioxide Stream Compositions  

SciTech Connect (OSTI)

A critical component in the assessment of long-term risk from geologic sequestration of CO2 is the ability to predict mineralogical and geochemical changes within storage reservoirs due to rock-brine-CO2 reactions. Impurities and/or other constituents selected for co-sequestration can affect both the chemical and physical (e.g. density, viscosity, interfacial tension) behavior of CO2 in the deep subsurface. These impurities and concentrations are a function of both the industrial source(s) of the CO2, as well as the carbon capture technology used to extract the CO2 and produce a concentrated stream for geologic sequestration. This report summarizes the relative concentrations of CO2 and other constituents in exhaust gases from major non-energy related industrial sources of CO2. Assuming that carbon-capture technology would remove most of the incondensable gases N2, O2, and Ar, leaving SO2 and NOx as the main impurities, we selected four test fluid compositions for use in geochemical experiments. These included: 1) a pure CO2 stream representative of food grade CO2 used in most enhanced oil recovery projects: 2) a test fluid composition containing low concentrations (0.5 mole %) SO2 and NOx (representative of that generated from cement production), 3) a test fluid composition with higher concentrations (2.5 mole %) of SO2, and 4) and test fluid composition containing 3 mole % H2S.

Last, George V.; Schmick, Mary T.

2011-06-30T23:59:59.000Z

387

A Biomass-based Model to Estimate the Plausibility of Exoplanet Biosignature Gases  

E-Print Network [OSTI]

Biosignature gas detection is one of the ultimate future goals for exoplanet atmosphere studies. We have created a framework for linking biosignature gas detectability to biomass estimates, including atmospheric photochemistry and biological thermodynamics. The new framework is intended to liberate predictive atmosphere models from requiring fixed, Earth-like biosignature gas source fluxes. New biosignature gases can be considered with a check that the biomass estimate is physically plausible. We have validated the models on terrestrial production of NO, H2S, CH4, CH3Cl, and DMS. We have applied the models to propose NH3 as a biosignature gas on a "cold Haber World," a planet with a N2-H2 atmosphere, and to demonstrate why gases such as CH3Cl must have too large of a biomass to be a plausible biosignature gas on planets with Earth or early-Earth-like atmospheres orbiting a Sun-like star. To construct the biomass models, we developed a functional classification of biosignature gases, and found that gases (such...

Seager, S; Hu, R

2013-01-01T23:59:59.000Z

388

Sound speed and thermal property measurements of inert materials: laser spectroscopy and the diamond-anvil cell  

SciTech Connect (OSTI)

An indispensable companion to dynamical physics experimentation, static high-pressure diamond-anvil cell research continues to evolve, with laser diagnostic, as an accurate and versatile experimental deep planetary properties have bootstrapped each other in a process that has produced even higher pressures; consistently improved calibrations of temperature and pressure under static and dynamic conditions; and unprecedented data and understanding of materials, their elasticity, equations of state (EOS), and transport properties under extreme conditions. A collection of recent pressure and/or temperature dependent acoustic and thermal measurements and deduced mechanical properties and EOS data are summarized for a wide range of materials including H2, H2O, H2S, D2S, CO2, CH4, N2O, CH3OH,, SiO2, synthetic lubricants, PMMA, single crystal silicates, and ceramic superconductors. Room P&T sound speed measurements are presented for the first time on single crystals of beta-HMX. New high-pressure and temperature diamond cell designed and pressure calibrant materials are reviewed.

Zaug, J.M.

1997-07-01T23:59:59.000Z

389

Corrosion behavior of an HVOF-sprayed Fe3Al coating in a high-temperature oxidizing/sulfidizing environment  

SciTech Connect (OSTI)

An iron aluminide (Fe3Al) intermetallic coating was deposited onto a F22 (2.25Cr-1Mo) steel substrate using a JP-5000 high velocity oxy-fuel (HVOF) thermal spray system. The as-sprayed coating was examined by electron microscopy and X-ray diffraction and was characterized in terms of oxidation and adhesion. Fe3Al-coated steel specimens were exposed to a mixed oxidizing/sulfidizing environment at 500, 600, 700, and 800DGC for approximately seven days. The gaseous environment consisted of N2-10%CO-5%CO2-2%H2O-0.12%H2S (by volume). All specimens gained mass after exposure to the environment and the mass gains were found to be inversely proportional to temperature increases. Representative specimens exposed at each temperature were cross-sectioned and subjected to examination under a scanning electron microscope (SEM) and X-ray mapping. Results are presented in terms of corrosion weight gain and corrosion product formation. The purpose of the research presented here was to evaluate the effectiveness of an HVOF-sprayed Fe3Al coating in protecting a steel substrate exposed to a fossil energy environment.

Covino, Bernard S., Jr.; Bullard, Sophie J.; Cramer, Stephen D.; Holcomb, Gordon R.; Ziomek-Moroz, Margaret; Shrestha, S. (TWI Ltd.); Harvey, D. (TWI Ltd.)

2005-01-01T23:59:59.000Z

390

atile-rich lo over 4.6 aeons. In fact, the Peale et al. theory suggests many such  

E-Print Network [OSTI]

abundant. Various sulfur compounds such as SO2 and H2S are Fommon constituents of terrestrial vol- 9anoes to oxidize FeS, in the presence of FeO, producing magnetite and H2S. However, once the entire plan- et had (2, 9). At the surface temperature of Io (100 K) sulfur will be in a crystalline state

Basu, Asish R.

391

JOURNAL DE PHYSIQUE Colloque C6, supplement au n 12, Tome 37, Decembre 1976, page C6-249 MOSSBAUER STUDIES OF THE ACTIVATED STATE  

E-Print Network [OSTI]

alumina. In this way the sulfur is removed as H2S. Extensive research on this catalyst system has been. The catalyst is then calcined in air at about 780 K and is activated for instance by exposure to a H2/H2S gas. The measurements indicate that the catalytic process is associated with a valence change of the Co ions. 1

Boyer, Edmond

392

Principal agent of energy and mass exchange between the ocean and the Earth's crust  

E-Print Network [OSTI]

to H2S (SO4 2- + Fe2+ H2S + Fe2O3) Si, Fe (Zn, Cu) and Mn are gained (i.e. leached out of the rock in chloro-complexes Phase separation Separation into two phases by boiling, condensation, vapor release

Siebel, Wolfgang

393

Operational aspects of the desulfurization process of energy gases mimics in biotrickling filters5  

E-Print Network [OSTI]

. Introduction Energy rich off-gases such as biogas are sometimes not used for electric power generation due impurities. H2S concentrations in biogas can range from 0.1 to 5 We dedicate this article to the memory/v (1000e20,000 ppmv), whereas the specifications for the maximum content of H2S in typical biogas

394

Generation of DNA-Damaging Reactive Oxygen Species via the Autoxidation of Hydrogen Sulfide under Physiologically Relevant  

E-Print Network [OSTI]

Generation of DNA-Damaging Reactive Oxygen Species via the Autoxidation of Hydrogen Sulfide under found that micromolar concentrations of H2S generated single-strand DNA cleavage. Mechanistic studies indicate that this process involved autoxidation of H2S to generate superoxide, hydrogen peroxide, and

Gates, Kent. S.

395

Persisting impact of historical mining activity to metal (Pb, Zn, Cd, Tl, Hg) and metalloid (As, Sb) enrichment in sediments of the Gardon River,  

E-Print Network [OSTI]

) enrichment in sediments of the Gardon River, Southern France Eléonore Resongles a, , Corinne Casiot a , Rémi in sediments was investigated in multi-source context. · Metal(loid) enrichment during the 19th century in sediment. · Cd, Zn and Pb may be mobilized under changing environmental conditions. a b s t r a c ta r t i

Demouchy, Sylvie

396

TUDE DES CASCADES 03B3201403B3 DANS LA CAPTURE DE NEUTRONS THERMIQUES CONDUISANT AU PREMIER TAT EXCIT DE 200Hg  

E-Print Network [OSTI]

on 03B3 2014 03B3 cascades which go down from the capturing state to the first excited state. LE JOURNAL montre que l'utilisation de la m6thode de Hoogenboom permettait l'emploi de cristaux d'iodure de sodium celles qui aboutissent aux premiers et second niveaux excites par exemple,. surtout si les intensites des

Paris-Sud XI, Université de

397

Enhancement of the Critical Temperature of HgBa2CuO4 by Applying Uniaxial and Hydrostatic Pressure: Implications for a Universal Trend in Cuprate Superconductors  

E-Print Network [OSTI]

an inverted parabolic shape as a function of hole (or electron) doping, reaching a maximum value, Tmax c.H. Geballe Laboratory for Advanced Materials, Stanford University, Stanford, California 94305, USA 6 I

Schilling, James

398

A soil microscale study to reveal the heterogeneity of Hg(II) impact on indigenous bacteria by quantication of adapted phenotypes and  

E-Print Network [OSTI]

toxicants. Heavy metals in soil are known to have a deleterious e¡ect on the num- bers of bacteria; RISA; Indirect enumeration 1. Introduction Bacterial response to heavy metal contamination in soil,2]). Several studies reported an impact of heavy metals at the community level using phenotypic or genetic

Thioulouse, Jean

399

Nyhetsbrev frn tsp-avdelningen v 5 2011 ven om sommaren kan knnas lngt borta r det hg tid att kasta ett ga p vad sommarens  

E-Print Network [OSTI]

Region Halland som står för programmet, och de har verkligen lyckats få ihop ett brett och intressant

400

Mechanism of Cation Exchange Process for Epitaxy of Superconducting HgBa2CaCu2O6 Films and Passive Microwave Devices  

E-Print Network [OSTI]

cations into, the lattice of epitaxial Tl2Ba2CaCu2O8 (Tl-2212) or TlBa2CaCu2O7 (Tl-1212) precursor films. Aiming at the remained issues in understanding the mechanism of the cation exchange (CE) process, this thesis work has studied the reversibility of CE...

Zhao, Hua

2007-12-17T23:59:59.000Z

Note: This page contains sample records for the topic "n2 h2s hg" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Modeling the Jovian subnebula: II - Composition of regular satellites ices  

E-Print Network [OSTI]

We use the evolutionary turbulent model of Jupiter's subnebula described by Alibert et al. (2005a) to constrain the composition of ices incorporated in its regular icy satellites. We consider CO2, CO, CH4, N2, NH3, H2S, Ar, Kr, and Xe as the major volatile species existing in the gas-phase of the solar nebula. All these volatile species, except CO2 which crystallized as a pure condensate, are assumed to be trapped by H2O to form hydrates or clathrate hydrates in the solar nebula. Once condensed, these ices were incorporated into the growing planetesimals produced in the feeding zone of proto-Jupiter. Some of these solids then flowed from the solar nebula to the subnebula, and may have been accreted by the forming Jovian regular satellites. We show that ices embedded in solids entering at early epochs into the Jovian subdisk were all vaporized. This leads us to consider two different scenarios of regular icy satellites formation in order to estimate the composition of the ices they contain. In the first scenario, icy satellites were accreted from planetesimals that have been produced in Jupiter's feeding zone without further vaporization, whereas, in the second scenario, icy satellites were accreted from planetesimals produced in the Jovian subnebula. In this latter case, we study the evolution of carbon and nitrogen gas-phase chemistries in the Jovian subnebula and we show that the conversions of N2 to NH3, of CO to CO2, and of CO to CH4 were all inhibited in the major part of the subdisk. Finally, we assess the mass abundances of the major volatile species with respect to H2O in the interiors of the Jovian regular icy satellites. Our results are then compatible with the detection of CO2 on the surfaces of Callisto and Ganymede and with the presence of NH3 envisaged in subsurface oceans within Ganymede and Callisto.

Olivier Mousis; Yann Alibert

2005-10-28T23:59:59.000Z

402

Mercury Methylation in Mine Wastes Collected from Abandoned Mercury Mines in the USA  

SciTech Connect (OSTI)

Mercury mines contain highly elevated Hg contents, but more problematic environmentally are elemental Hg and soluble Hg salts produced during ore retorting that remain in wastes at mine sites. Under certain conditions, these inorganic Hg compounds convert to bioavailable, highly toxic organic Hg forms. Speciation and transformation of Hg was studied in wastes collected from abandoned Hg mines at McDermitt, NV, and Terlingua, TX, which are moderate size on an international scale and produced about 10,000 and 5,000 t of elemental Hg, respectively. In waste samples, we measured total Hg and methyl-Hg contents, identified various Hg compounds using Hg-thermo-desorption pyrolysis, and determined rates of Hg methylation and methyl-Hg demethylation using isotopic-tracer methods. Pyrolysis analysis of mine wastes showed variable amounts of cinnabar, metacinnabar, Hg salts, elemental Hg, and elemental Hg sorbed onto particulates such as clay and Fe-oxides. Mine wastes with the highest methyl-Hg contents correspond to those with elemental Hg and particulate-sorbed elemental Hg, and also produced the highest laboratory-estimated potential Hg methylation rates, as much as 4.8%/day. Samples containing dominantly cinnabar showed little or no Hg methylation. Mine wastes with high methyl-Hg contents generally showed low methyl-Hg demethylation, suggesting that Hg methylation was dominant. Both mines are located in semiarid climates, and during this study, streambeds below the mines were dry. Total Hg contents in stream sediment collected below the mines show significant dilution, and methyl-Hg contents were typically below the limit of determination. Methylation of Hg downstream from Hg mines is probably lower in arid climates due to lack of mine-water runoff and lower microbial activity. The correspondence of mine wastes containing elemental Hg and high methyl-Hg contents suggests that Hg0 oxidizes to Hg2+, which is subsequently bioavailable for microbial Hg methylation.

Gray, John E. (U.S. Geological Survey); Hines, Mark E. (Massachusetts, Univ Of); Biester, Harald (Heidelberg College); Lasorsa, Brenda K. (BATTELLE (PACIFIC NW LAB))

2003-05-01T23:59:59.000Z

403

Development of an Integrated Multi-Contaminant Removal Process Applied to Warm Syngas Cleanup for Coal-Based Advanced Gasification Systems  

SciTech Connect (OSTI)

This project met the objective to further the development of an integrated multi-contaminant removal process in which H2S, NH3, HCl and heavy metals including Hg, As, Se and Cd present in the coal-derived syngas can be removed to specified levels in a single/integrated process step. The process supports the mission and goals of the Department of Energy??s Gasification Technologies Program, namely to enhance the performance of gasification systems, thus enabling U.S. industry to improve the competitiveness of gasification-based processes. The gasification program will reduce equipment costs, improve process environmental performance, and increase process reliability and flexibility. Two sulfur conversion concepts were tested in the laboratory under this project, i.e., the solventbased, high-pressure University of California Sulfur Recovery Process ?? High Pressure (UCSRP-HP) and the catalytic-based, direct oxidation (DO) section of the CrystaSulf-DO process. Each process required a polishing unit to meet the ultra-clean sulfur content goals of <50 ppbv (parts per billion by volume) as may be necessary for fuel cells or chemical production applications. UCSRP-HP was also tested for the removal of trace, non-sulfur contaminants, including ammonia, hydrogen chloride, and heavy metals. A bench-scale unit was commissioned and limited testing was performed with simulated syngas. Aspen-Plus®-based computer simulation models were prepared and the economics of the UCSRP-HP and CrystaSulf-DO processes were evaluated for a nominal 500 MWe, coal-based, IGCC power plant with carbon capture. This report covers the progress on the UCSRP-HP technology development and the CrystaSulf-DO technology.

Howard Meyer

2010-11-30T23:59:59.000Z

404

Nested-grid simulation of mercury over North America  

E-Print Network [OSTI]

coal combustion, waste incineration and gold mining (Streetsprofiles for waste incineration (22 % Hg(0), 78 % Hg(II)).

2012-01-01T23:59:59.000Z

405

Interfacial Reduction-Oxidation Mechanisms Governing Fate and Transport of Contaminants in the Vadose Zone  

SciTech Connect (OSTI)

Immobilization of toxic and radioactive metals in the vadose zone by In Situ Gaseous Reduction (ISGR) using hydrogen sulfide (H2S) is a promising technology for soil remediation. Earlier laboratory and field studies have shown that Cr(VI) can be effectively immobilized by treatment with dilute gaseous H2S. The objective of this project is to characterize the interactions among H2S, the metal contaminants, and soil components. Understanding these interactions is needed to assess the long-term effectiveness of the technology and to optimize the remediation system.

Baolin Deng; Edward Thornton; Kirk Cantrell; Khris Olsen; James Amonette

2004-01-11T23:59:59.000Z

406

(MIRU2005)!W2005 G/7 7n 2hA--Ns$rMxMQ$7$?0"F07?%l%s%8%;%s%5$+$iF@$i$l$k 3 !857Au=$I--  

E-Print Network [OSTI]

$l$F$$$k!%¡BJ*BN%b%G%j%s %0$N5;=Q$O!$3X=Q!$;:6H!$%(%s%?!¡%F%$%s%a%s%H$J$IB?$/$NJ, Ln$GI,MW$H$5$l!$$^$?GH5Z8z2L$,4--BT

Tokyo, University of

407

JOURNAL DE PHYSIQUE Colloque C 1, supplement au n 2-3, Tome 32, Fevrier-Mars 1971, page C 1 -386 THE EFFECT OF APPLIED STRESS ON THE POWER LOSS,  

E-Print Network [OSTI]

THE EFFECT OF APPLIED STRESS ON THE POWER LOSS, DYNAMIC MAGNETOSTRICTION AND DOMAIN BEHAVIOUR OF INDIVIDUAL supplementaires. Abstract. -- The power loss of individual grains of silicon-iron in a polycrystalline sample has-optic technique. The effect of applied stresses (0 7 x 106 N.m-2) on both the power loss and domain motion has

Paris-Sud XI, Universit de

408

Math 172 Spring 2011 Worksheet 1 1. If N = N(t), N = 3, and N(0) = 5, find N(1), N(2), N(3), N(4), N(5)  

E-Print Network [OSTI]

the 1980's, Costa Rica had a deforestation rate of 2.9% per year. Deforestation (meaning loss of forested

Vraciu, Adela

409

MeasureMents of the Differential Cross seCtion for the elastiC n3h anD n2h sCattering at 14.1 MeV LLE Review, Volume 128 151  

E-Print Network [OSTI]

is currently of great interest since it would provide valuable insights into low-energy nuclear reactions important to nuclear astrophysics. Radiative capture reactions, for example, occur in red giants at temperatures low enough that the reaction rates are too small to be directly measured in a laboratory. Extrapo

410

Studies of a Series of [Ni(PR2NPh2)2(CH3CN)]2+ Complexes as Electrocatalysts for H2 Production: Substituent Variation at the Phosphorus Atom of the P2N2 Ligand  

SciTech Connect (OSTI)

A series of [Ni(PR2NPh2)2(CH3CN)](BF4)2 complexes containing the cyclic diphosphine ligands (PR2NPh2 = 1,5-diaza-3,7-diphosphacyclooctane; R = benzyl (Bn), n-butyl (n-Bu), 2-phenylethyl (PE), 2,4,4-trimethylpentyl (TP), and cyclohexyl (Cy)) have been synthesized and characterized. X-ray diffraction studies reveal that the cations of [Ni(PBn2NPh2)2(CH3CN)](BF4)2 and [Ni(Pn-Bu2NPh2)2(CH3CN)](BF4)2 have distorted trigonal bipyramidal geometries. The Ni(0) complex [Ni(PBn2NPh2)2 (CH3CN)] was also synthesized and characterized by X-ray diffraction studies and shown to have a distorted tetrahedral structure. These complexes, with the exception of [Ni(PCy2NPh2)2(CH3CN)](BF4)2, all exhibit reversible electron transfer processes for both the Ni(II/I) and Ni(I/0) couples and are electrocatalysts for the production of H2 in acidic acetonitrile solutions. The heterolytic cleavage of H2 by [Ni(PR2NPh2)2(CH3CN)](BF4)2 complexes in the presence of p-anisidine or p-bromoaniline was used to determine the hydride donor abilities of the corresponding [HNi(PR2NPh2)2](BF4) complexes. However, the failure to observe a strong correlation between the turnover frequencies for H2 production and the hydride donor abilities, along with structural features of [Ni(PBn2NPh2)2(CH3CN)], suggest that steric interactions between the alkyl substituents on phosphorus and the nitrogen atom of the pendant amines play an important role in determining the overall catalytic rate. This material is based upon work supported as part of the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the US Department of Energy, Office of Science, Office of Basic Energy Sciences.

Kilgore, Uriah J.; Stewart, Michael P.; Helm, Monte L.; Dougherty, William G.; Kassel, W. S.; Rakowski DuBois, Mary; DuBois, Daniel L.; Bullock, R. Morris

2011-11-07T23:59:59.000Z

411

Bol. Mus. Para. Emlio Goeldi. Cincias Humanas, Belm, v. 3, n. 2, p. 195-211, maio-ago. 2008 A cidade, um foco de diversidade agrcola no Rio Negro (Amazonas, Brasil)?  

E-Print Network [OSTI]

A cidade, um foco de diversidade agrícola no Rio Negro (Amazonas, Brasil)? The urban area, a center pour le Développement. Unité de Recherche 200, Brasília, Brasil (laura.emperaire@uol.com.br). II;A cidade, um foco de diversidade agrícola no Rio Negro (Amazonas, Brasil)? 196 INTRODU??O O

Paris-Sud XI, Université de

412

(MIRU2004)!W2004 G/7 7n ;~6u4V5wN%2hA--$rMxMQ$7$?+8J0LCV?dDj$K$h$k  

E-Print Network [OSTI]

%-%c%s7k2L$N%^%C%A%s%0$r9T$C $F7WB,¡VN¿$N5sF0$r;;=P$9$kJK![8] $,$"$k!%Frueh $i$O$3$N ¡jK!$rMxMQ$7$F

Tokyo, University of

413

RAMATION V=W Ot TOTS= t sAy VnoffZW COMM1 AV 10i90 2M3 AM=W V A CLSI~LL331M A1N2UW  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the1 -the Mid-Infrared at 278, 298, and 323 K.Office of Science7a.RACETRACK AT ANLR :

414

Pochet P., Cusset J.-M. (1999), Cultural barriers to bicycle use in Western African cities: The case of Bamako and Ouagadougou, IATSS Research, Vol. 23, n2, pp. 43-50.  

E-Print Network [OSTI]

1 Pochet P., Cusset J.-M. (1999), Cultural barriers to bicycle use in Western African cities: The case of Bamako and Ouagadougou, IATSS Research, Vol. 23, n°2, pp. 43-50. Cultural barriers to bicycle-michel.cusset@let.ish-lyon.cnrs.fr Abstract This paper deals with the use and perception of bicycles in two Western African capital towns

Paris-Sud XI, Université de

415

Adsorption of Hydrogen Sulfide onto Activated Carbon Fibers: Effect of  

E-Print Network [OSTI]

. These processes include natural gas processing, petroleum refining, petrochemical plants, Kraft mills, coke ovens, and coal gasifiers. H2S concentrations in these processes vary from 0 to 60 vol % (6). The Claus process

Borguet, Eric

416

Accidental Gas Emission From Shallow Pressurized Aquifers At...  

Open Energy Info (EERE)

impervious cover. Gas consists mostly of CO2 with minor H2S and the diffuse CO2 soil flux is locally very high. Accidental gas blowouts, occurred during shallow well...

417

Helium Isotopes In Geothermal And Volcanic Gases Of The Western...  

Open Energy Info (EERE)

be qualitative criteria for the absence of a magmatic heat source. To first order, He(CO2 + H2S) ratios are inversely correlated with 3He4He and are consistent with a...

418

Background and Motivation Biomass derived syngas contains  

E-Print Network [OSTI]

Background and Motivation Biomass derived syngas contains: CO, H2, small hydrocarbons, H2S prepared by SEA contain smaller metal particle sizes and have higher dispersion The quantity of reducible

Das, Suman

419

Abrasion and Erosion testing of Materials used in Power Production...  

Office of Scientific and Technical Information (OSTI)

and exhaust gas can erode a boiler's heat exchange tubes 4-8 . In coal gasification power plants, the heat exchanger tubes can experience corrosion due to H 2 S and HCl in...

420

PRODUCTION OF HYDROGEN BY SUPERADIABATIC DECOMPOSITION OF HYDROGEN SULFIDE  

E-Print Network [OSTI]

in a cylindrical vessel packed with a porous ceramic medium with a high thermal capacity. The intensive heat experimental and numerical studies analyzed chemical and thermal structures of the H2S-containing gases

Note: This page contains sample records for the topic "n2 h2s hg" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

The millimeter/submillimeter spectrum of LiSH (~XX1 further investigations of the metalsulfur bond  

E-Print Network [OSTI]

. These species were created by the reaction of H2S or D2S and lithium vapor in a dc discharge. Extensive Ka. Although metaloxygen bonds are quite common in multiple areas such as combustion, corrosive processes

Ziurys, Lucy M.

422

Chemical kinetic modeling of oxy-fuel combustion of sour gas for enhanced oil recovery  

E-Print Network [OSTI]

Oxy-fuel combustion of sour gas, a mixture of natural gas (primarily methane (CH 4 )), carbon dioxide (CO 2 ), and hydrogen sulfide (H 2 S), could enable the utilization of large natural gas resources, especially when ...

Bongartz, Dominik

2014-01-01T23:59:59.000Z

423

NETL F 451.1/1-1, Categorical Exclusion Designation Form  

Broader source: Energy.gov (indexed) [DOE]

Gas Alarms Providing gas alarm monitoring sensing systems into Labs 407 and 410. The sensors provided will be for CO, NO2, H2S, combustibles and O2. The infrastructure, such as...

424

E-Print Network 3.0 - acanthosis nigricans Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

zool. Beitr. Bd. 48 H. 2 S. 205-215 Bonn, Oktober 1998 Comparative osteology of Malagasy poison frogs Summary: a second, monophyletic group splits off. It is characterized by an...

425

E-Print Network 3.0 - allium cepa linn Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Nerato has been used... NS ratio in shoots of different cultivars of Allium cepa, A. fis- tulosum and A. porrum... the impact of short-term H2S exposure and sulfate supply on...

426

E-Print Network 3.0 - allium cepa Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Nerato has been used... NS ratio in shoots of different cultivars of Allium cepa, A. fis- tulosum and A. porrum... the impact of short-term H2S exposure and sulfate supply on...

427

E-Print Network 3.0 - allium cepa root Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Nerato has been used... NS ratio in shoots of different cultivars of Allium cepa, A. fis- tulosum and A. porrum... the impact of short-term H2S exposure and sulfate supply on...

428

E-Print Network 3.0 - allium cepa test Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Nerato has been used... NS ratio in shoots of different cultivars of Allium cepa, A. fis- tulosum and A. porrum... the impact of short-term H2S exposure and sulfate supply on...

429

E-Print Network 3.0 - allium cepa anaphase-telophase Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Nerato has been used... NS ratio in shoots of different cultivars of Allium cepa, A. fis- tulosum and A. porrum... the impact of short-term H2S exposure and sulfate supply on...

430

E-Print Network 3.0 - allium cepa liliaceae Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Nerato has been used... NS ratio in shoots of different cultivars of Allium cepa, A. fis- tulosum and A. porrum... the impact of short-term H2S exposure and sulfate supply on...

431

annual workshop proceedings: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

emits around 13000 tons of H2S into atmosphere. Under certain weather conditions the hydrogen sulfide from the power plant Stanford University 417 NCDEU 2011 Full-Day Workshop...

432

WAT ENVIRON RESEARCH (in press, final version may have small changes) ODOR AND VOC TREATMENT BY BIOTRICKLING FILTERS: PILOT SCALE  

E-Print Network [OSTI]

Treatment Plant (HTP) in Los Angeles have been testing pilot- scale biotrickling filters and biofilters odorous waste gases. The waste gas from the Headworks at HTP (100,000 cfm) contains 10-50 ppm H2S

433

E-Print Network 3.0 - ambient nitrogen dioxide Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Search Sample search results for: ambient nitrogen dioxide Page: << < 1 2 3 4 5 > >> 1 Air Pollution Grant Ideas Possible air pollutants to study: SO2, H2S, NO2, NH3, CO, CO2,...

434

The Geysers Geothermal Field Update1990/2010  

E-Print Network [OSTI]

B. ,2010. GeyserspowerplantH 2 Sabatement update. operationsatTheGeyserspowerplant,GeothermalResourcesTable1:GeothermalPowerPlantsOperatingatTheGeysers(

Brophy, P.

2012-01-01T23:59:59.000Z

435

Simulating Geologic Co-sequestration of Carbon Dioxide and Hydrogen Sulfide in a Basalt Formation  

SciTech Connect (OSTI)

Co-sequestered CO2 with H2S impurities could affect geologic storage, causing changes in pH and oxidation state that affect mineral dissolution and precipitation reactions and the mobility of metals present in the reservoir rocks. We have developed a variable component, non-isothermal simulator, STOMP-COMP (Water, Multiple Components, Salt and Energy), which simulates multiphase flow gas mixtures in deep saline reservoirs, and the resulting reactions with reservoir minerals. We use this simulator to model the co-injection of CO2 and H2S into brecciated basalt flow top. A 1000 metric ton injection of these supercritical fluids, with 99% CO2 and 1% H2S, is sequestered rapidly by solubility and mineral trapping. CO2 is trapped mainly as calcite within a few decades and H2S is trapped as pyrite within several years.

Bacon, Diana H.; Ramanathan, Ramya; Schaef, Herbert T.; McGrail, B. Peter

2014-01-15T23:59:59.000Z

436

JOURNALDE PHYSIQUE IV Colloque C3,supplement au Journal de Physique 11,Volume3,aoClt 1993  

E-Print Network [OSTI]

incorporation of sulfur was less effective : maximum 57 at.% S in Ge-S layers (GeH4/H2S = 1/96 and p = 0.1 mbar decomposing a mixture of two gaseous hydrides, GeH4 and H2S or H2Se, to yield layers of amorphous GexS1) i.e. less than the stoichiometriccomposition GeS2. Information concerning the structure of as

Boyer, Edmond

437

Neurotoxic mechanisms of methylmercury: cellular and behavior changes  

E-Print Network [OSTI]

The organic or methylated form of mercury (Hg), consisting of one methyl group bound to each atom of Hg, (methylmercury; MeHg), accounts for most of the Hg to which humans are exposed. MeHg, by virtue of its lipophilicity is highly neurotoxic...

Bellum, Sairam

2007-04-25T23:59:59.000Z

438

(Bh 1 2s) 1 / 58 http://ist.ksc.kwansei.ac.jp/tutimura/  

E-Print Network [OSTI]

/ 58 q K&R (1978 G/) 7?%A%'%C%/$J$7 q ANSI C (C89, 1989 G/) 4X?t%W%m%H%?%$%W, void 7?, enum 7? q C99%W%m%0%i%_%s%08@8lC ANSI 5,3J=`5r!JBh 2 HG!K!W B.W. Kernighan, D.M. Ritchie Cx, @PED @25W K]Lu, 6&N?, 2 CMJQ?t, %U%i%0JQ?t$J$I$H$b8F$P$l$k q TRUE $dFALSE $OC $G$OD>@\\$OMQ0U$5$l$F$$$J$$ 3 ANSI C89 $J

Murota, Kazuo

439

This article appeared in a journal published by Elsevier. The attached copy is furnished to the author for internal non-commercial research  

E-Print Network [OSTI]

five Gulf states have fish consumption advisories based on Hg. Per-capita fish consumption in the Gulf a potential for greater MeHg exposure due to higher levels of fish consumption. Atmospheric wet Hg deposition

Holmes, Christopher D.

440

Open Archive TOULOUSE Archive Ouverte (OATAO) OATAO is an open access repository that collects the work of Toulouse researchers and  

E-Print Network [OSTI]

. The predominant anthropogenic Hg sources were coal burning and smelter Hg emissions. a b s t r a c t Keywords and after the In- dustrial Revolution were coal burning and smelter Hg emissions. Mercury accumulation rates

Mailhes, Corinne

Note: This page contains sample records for the topic "n2 h2s hg" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

10.1177/0270467603259787ARTICLEBULLETIN OF SCIENCE, TECHNOLOGY & SOCIETY / October 2003Roe / FISHING FOR IDENTITY Fishing for Identity: Mercury Contamination  

E-Print Network [OSTI]

of mercury in the United States. During 1999, total mercury emis- sions from power plant emissions exceeded (HG0 ), inorganic mercury (HG2+ ), and methyl mercury (MeHg), methyl mercury poses the greatest threat

Delaware, University of

442

Beyer H.-G., Czeplak G., Terzenbach U., Wald L., 1997. Assessment of the method used to construct clearness index maps for the new european solar radiation atlas (ESRA). Solar Energy, 61, 6, 389-397.  

E-Print Network [OSTI]

clearness index maps for the new european solar radiation atlas (ESRA). Solar Energy, 61, 6, 389-397. Assessement of the method used to construct clearness index maps for the new European Solar Radiation Atlas of the methods used to construct maps for a new Solar Radiation Atlas for Europe. For this atlas station data

Paris-Sud XI, Université de

443

Marine Habitat Mapping Technology for Alaska, J.R. Reynolds and H.G. Greene (eds.) 185 Alaska Sea Grant College Program, University of Alaska Fairbanks. doi:10.4027/mhmta.2008.13  

E-Print Network [OSTI]

, and depth based on current standards used in California fisher- ies management. Both the GIS layer nautical miles from shore. CCSWMP is managed by the California Ocean Protection Council through. 2004, Harney et al. 2006). The California State Marine Life Protection Act (MLPA) calls for protecting

444

PROTON AND DEUTERIUM NMR EXPERIMENTS IN ZERO FIELD  

E-Print Network [OSTI]

4460(1967). and H.G. Zachmann, editors, (Springer, Berlin,Sci," H.H. Kausch and H.G. _J Zachmann, editors, (Springer,

Millar, J.M.

2010-01-01T23:59:59.000Z

445

Mitigation and Remediation of Mercury Contamination at the Y...  

Office of Environmental Management (EM)

and surface water Hg remediation strategy for adequacy in reducing Hg levels in the fish and to indentify opportunities to achieve cost and technical improvements andor to...

446

Summary - Mitigation and Remediation of Mercury Contamination...  

Office of Environmental Management (EM)

and surface water Hg remediation strategy for adequacy in reducing Hg levels in the fish and to indentify opportunities to achieve cost and technical improvements andor to...

447

Final Project Report: "??Exploratory Research: Mercury Stable Isotopes as Indicators of the Biogeochemical Cycling of Mercury"?  

SciTech Connect (OSTI)

This is the final project report for award DE-SC0005351, which supported the research project "??Exploratory Research: Mercury Stable Isotopes as Indicators of the Biogeochemical Cycling of Mercury."? This exploratory project investigated the use of mercury (Hg) stable isotope measurements as a new approach to study how Hg moves and changes its chemical form in environmental systems, with particular focus on the East Fork of Poplar Creek (EFPC) near the DOE Y-12 plant (a Hg contamination source). This study developed analytical methods and collected pilot data that have set the stage for more detailed studies and have begun to provide insights into Hg movement and chemical changes. The overall Hg stable isotope approach was effective. The Hg isotope analysis methods yielded high-precision measurements of the sediment, water, and fish samples analyzed; quality control measures demonstrated the precision. The pilot data show that the 202Hg/198Hg, 199Hg/198Hg, and 201Hg/198Hg isotope ratios vary in this system. 202Hg/198Hg ratios of the Hg released from the Y-12 plant are relatively high, and those of the regional Hg background in soils and river sediments are significantly lower. Unfortunately, 202Hg/198Hg differences that might have been useful to distinguish early Hg releases from later releases were not observed. However, 202Hg/198Hg ratios in sediments do provide insights into chemical transformations that may occur as Hg moves through the system. Furthermore, 199Hg/198Hg and 201Hg/198Hg ratio analyses of fish tissues indicate that the effects of sunlight-driven chemical reactions on the Hg that eventually ends up in EFPC fish are measureable, but small. These results provide a starting point for a more detailed study (already begun at Univ. of Michigan) that will continue Hg isotope ratio work aimed at improving understanding of how Hg moves, changes chemically, and does or does not take on more highly toxic forms in the Oak Ridge area. This work also benefits efforts to trace Hg contamination in the Clinch and Tennessee Rivers, into which EFPC flows, and to distinguish Hg from the Y-12 plant from that released from a nearby coal ash accident.

Johnson, Thomas M

2012-08-01T23:59:59.000Z

448

HbVar: A Relational Database of Human Hemoglobin Variants and Thalassemia Mutations  

E-Print Network [OSTI]

: Public Health Service; Contract grant numbers: HG02238; DK27635. #12;Inherited disorders of hemoglobin

Hardison, Ross C.

449

Mercury and Other Heavy Metals Influence Bacterial Community Structure in Contaminated Streams  

E-Print Network [OSTI]

Mercury and Other Heavy Metals Influence Bacterial Community Structure in Contaminated Streams Research The influences of uranium (U), mercury (Hg) and methylmercury (MeHg) on the microbial community. #12;High concentrations of uranium, inorganic mercury, Hg(II) and methymercury (MeHg) have been

450

doi:10.1016/j.gca.2005.06.029 Solubility of metallic mercury in octane, dodecane and toluene at temperatures between  

E-Print Network [OSTI]

Hg°, HgCl2, CH3Hg and (CH3)2Hg, and con- cluded that the solubility of these species decreases to predict the behavior of nonpolar solutes in polar solvents. This modification involves an adjustment of the Lennard Jones Potential and the hard-sphere diameters of solute and solvent to account for the effects

Long, Bernard

451

Atmos. Chem. Phys., 12, 50995112, 2012 www.atmos-chem-phys.net/12/5099/2012/  

E-Print Network [OSTI]

P ). Hg0 can be oxidized to RGM, part of which is further transformed to HgP on aerosol sur- faces. RGM and HgP eventually enter the biosphere via dry and wet deposition. Hg0 reportedly has a lifetime of 6­ 12 geographically due to different land surface types, chemical environments, and human influences. There have been

Meskhidze, Nicholas

452

Mercury Absorption in Aqueous Oxidants Catalyzed by Mercury(II) Lynn L. Zhao and Gary T. Rochelle*  

E-Print Network [OSTI]

Mercury Absorption in Aqueous Oxidants Catalyzed by Mercury(II) Lynn L. Zhao and Gary T. Rochelle-1062 The absorption of elemental Hg vapor into aqueous solution containing Hg(II) was measured in a stirred cell at 25 °C. For mercury absorption in Hg(II) obtained by HgCl2 injection, the presence of HNO3 greatly

Rochelle, Gary T.

453

XI Congrs de la Socit Franaise de Gnie des Procds. Des rponses industrielles pour une socit en mutation. Saint Etienne, 9 au 11 octobre 2007, N96, 2-910239-70-5  

E-Print Network [OSTI]

conclure à la réaction suivante : 9 CoSOH + 11/2 H2 = Co9S8 + 9 H2O + H2S. Du fait de la présence d'une phase minoritaire Co(OH)2 dans le solide initial, une deuxième réaction en parallèle, entre H2S produit des effluents liquides. (Loussot, 2006) a testé différents sulfures et a montré que CoSOH est le

Boyer, Edmond

454

JOURNAL DE PHYSIQUE ColloqueC4, supplment au no 10, Tome36, Octobre 1975, page C4-157 TUDE DE LA SGRGATION INTERGRANULAIRE  

E-Print Network [OSTI]

, marqué par l'isotope 35S,est apporté au-dessus de l'échantillon de cuivre par une atmosphère H2-H2S'hydrogène dans le tube A ; la composition du mélange H2-H2S qui en résulte est fixée par la température de 3sS.The results obtained permit the completion of recently acquired data on the solubility, volume

Boyer, Edmond

455

Icarus 157, 456463 (2002) doi:10.1006/icar.2002.6858  

E-Print Network [OSTI]

,sulfurdioxideSO2,hydrogensulfideH2S,andH2SO4 · nH2O.We measured the rate of sulfate anion production for cyclo energetic electrons. The measured rate is GMixture(SO2- 4 ) = fSulfur (r0/r) G1 molecules (100 eV)-1 , where) > N(H2S). The lifetime of a sulfur atom on Europa's surface for radiolysis to H2SO4 is (-S) = 120(r/r0

Johnson, Robert E.

456

Naval Petroleum Reserve No. 3 Site Environmental Report  

SciTech Connect (OSTI)

The CY1999 Site Environmental Report and Compliance Summary discusses environmental compliance activities for NPR-3 (Teapot Dome). All hazardous wastes that were stored in the hazardous waste accumulation at NPR-3 were removed in CY1999. NPR-3 maintains its status as a conditionally exempt small quantity generator. Hydrogen sulfide (H2S) flares have not operated at NPR-3 since 1996; monitoring of H2S indicates readings well below limits. All underground storage tanks were removed in 1998. Wastewater samples were in compliance with applicable standards.

None

2000-06-14T23:59:59.000Z

457

Investigation of Sulfur Removal by Direct Limestone Injection  

E-Print Network [OSTI]

combustion process. The CaC03 decomposes (calcines) according to Equation (1) below and the resulting CaO captures H2S by the reaction given in Equation (2). ~he. calcination reaction is endotherm~c w~th an enthalpy of reaction for calcination of 42... of CaO with H 2 S to simulate reducing conditions such as encountered in the first stage of a two-staged combustion process. Reactions of CaO with s02 will be considered at a future date. ANALYSIS General Considerations The analysis is conducted...

Colaluca, M. A.; Maloney, D. J.

458

Problem 8-3: Brayton Cycle in Figure 8-13 (page 324) operating at p1,4 = 14.696 psia  

E-Print Network [OSTI]

(no regenerator) using Standard Air Table I-1 (pages 809f) h1 = h(T1) = 124.27 BTU/lbm; pr1 = 1.2187 pr2 = 8 ? 1.2187 = 9.7496 ; T2s = 928 o R; h2s = 223.08 BTU/lbm h3 = h(T3) = 571.19 BTU/lbm; pr3 258 by extreme extrapolation pr4 = 258 ÷ 8 = 32.25 ; T4s = 1298 o R; h4s = 316.55 BTU/lbm w12s = h1 - h2s = -98

459

Defining the Molecular-Cellular-Field Continuum of Mercury Detoxification  

SciTech Connect (OSTI)

Hg is of special interest to DOE due to past use at the Oak Ridge Reservation (ORR). Its facile redox [Hg2+/0] chemistry, bonding to carbon [e.g. MeHg+] and unique physical properties [e.g., Hg0 volatility] underlie a complex global Hg cycle involving biotic and abiotic chemical and physical transport and transformations in soils, sediments, waterways and the atmosphere. Facultative and anaerobic bacteria make MeHg+, which is neurotoxic to wildlife and humans. Sustainable stewardship requires eliminating both MeHg+ and even more toxic Hg2+, which is also the substrate for methylation. The proteins encoded by the mer locus in aerobic and facultative mercury resistant (HgR) bacteria convert soil or waterborne Hg2+ or MeHg+ to less toxic, gaseous Hg0. HgR microbes live in highly Hg-contaminated sites and depress MeHg+ formation >500-fold in such zones. So, enhancing the capacity of natural HgR microbes to remove Hg2+/MeHg+ from wetlands and waterways is a logical component of contaminated site stewardship. To apply enhancement in the field requires knowing how the HgR pathway works including the metabolic demands it makes on the cell, i.e., the entire cell is the relevant catalytic unit. HgR loci occur in metabolically diverse bacteria and unique mer-host co-evolution has been found. In this project we extended our previous studies of mer enzymes in ?-proteobacteria, which are abundant in high Hg areas of the ORR to include studies of mer enzymes from HgR ?-proteobacteria and HgR actinobacteria, which also increase in the high Hg regions of the ORR. Specifically, we (1) examined interactions between structural compoenents of MerA and MerB enzymes from ?-proteobacteria, (2) investigated effects of mutations on kinetic efficiency of Hg2+ reduction by ?-proteobacterial MerA, (3) cloned and performed initital characterization of MerA and MerB enzymes from Streptomyces lividans, an actinobacterium, (4) cloned and performed initial characterization of a fused MerB-MerA protein from Ochrobactrum anthropi, an ?-proteobacterium, (5) investigate the extent of Hg isotope fractionation that occurs with purified ?-proteobacterial MerA.

Miller, Susan M. [UCSF

2014-09-04T23:59:59.000Z

460

T h e P e n n S T a T e S T r a T e g i c P l a n 2 0 0 9 1 0 t h r o u g h 2 0 1 3 1 4 e x e c u T i v e S u m m a r y Priorities for Excellence  

E-Print Network [OSTI]

Farmers' high School, has grown into a large and tremendously diverse university. It is today among many constitu- ents--while becoming more efficient and effective. Despite obvious challenges pursuit of excel- lence. Penn State is a very efficient institution that has accomplished great things

Lee, Dongwon

Note: This page contains sample records for the topic "n2 h2s hg" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Selenium inhibits the phytotoxicity of mercury in garlic (Allium sativum)  

SciTech Connect (OSTI)

To investigate the influence of selenium on mercury phytotoxicity, the levels of selenium and mercury were analyzed with inductively coupled plasma-mass spectrometry (ICP-MS) in garlic tissues upon exposure to different dosages of inorganic mercury (Hg{sup 2+}) and selenite (SeO{sub 3}{sup 2?}) or selenate (SeO{sub 4}{sup 2?}). The distributions of selenium and mercury were examined with micro-synchrotron radiation X-ray fluorescence (?-SRXRF), and the mercury speciation was investigated with micro-X-ray absorption near edge structure (?-XANES). The results show that Se at higher exposure levels (>1 mg/L of SeO{sub 3}{sup 2?} or SeO{sub 4}{sup 2?}) would significantly inhibit the absorption and transportation of Hg when Hg{sup 2+} levels are higher than 1 mg/L in culture media. SeO{sub 3}{sup 2?} and SeO{sub 4}{sup 2?} were found to be equally effective in reducing Hg accumulation in garlic. The inhibition of Hg uptake by Se correlates well with the influence of Se on Hg phytotoxicity as indicated by the growth inhibition factor. Elemental imaging using ?-SRXRF also shows that Se could inhibit the accumulation and translocation of Hg in garlic. ?-XANES analysis shows that Hg is mainly present in the forms of HgS bonding as Hg(GSH){sub 2} and Hg(Met){sub 2}. Se exposure elicited decrease of HgS bonding in the form of Hg(GSH){sub 2}, together with Se-mediated alteration of Hg absorption, transportation and accumulation, may account for attenuated Hg phytotoxicity by Se in garlic. -- Highlights: ? Hg phytotoxicity can be mitigated by Se supplement in garlic growth. ? Se can inhibit the accumulation and transportation of Hg in garlic tissues. ? Localization and speciation of Hg in garlic can be modified by Se.

Zhao, Jiating [CAS Key Laboratory of Nuclear Analytical Techniques, Key Lab for Biomedical Effects of Nanomaterial and Nanosafety, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049 (China)] [CAS Key Laboratory of Nuclear Analytical Techniques, Key Lab for Biomedical Effects of Nanomaterial and Nanosafety, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049 (China); Gao, Yuxi, E-mail: gaoyx@ihep.ac.cn [CAS Key Laboratory of Nuclear Analytical Techniques, Key Lab for Biomedical Effects of Nanomaterial and Nanosafety, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049 (China)] [CAS Key Laboratory of Nuclear Analytical Techniques, Key Lab for Biomedical Effects of Nanomaterial and Nanosafety, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049 (China); Li, Yu-Feng; Hu, Yi; Peng, Xiaomin [CAS Key Laboratory of Nuclear Analytical Techniques, Key Lab for Biomedical Effects of Nanomaterial and Nanosafety, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049 (China)] [CAS Key Laboratory of Nuclear Analytical Techniques, Key Lab for Biomedical Effects of Nanomaterial and Nanosafety, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049 (China); Dong, Yuanxing [Department of Physics, Xinzhou Teachers University, Xinzhou 034000 (China)] [Department of Physics, Xinzhou Teachers University, Xinzhou 034000 (China); Li, Bai; Chen, Chunying [CAS Key Laboratory of Nuclear Analytical Techniques, Key Lab for Biomedical Effects of Nanomaterial and Nanosafety, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049 (China)] [CAS Key Laboratory of Nuclear Analytical Techniques, Key Lab for Biomedical Effects of Nanomaterial and Nanosafety, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049 (China); Chai, Zhifang, E-mail: chaizf@ihep.ac.cn [CAS Key Laboratory of Nuclear Analytical Techniques, Key Lab for Biomedical Effects of Nanomaterial and Nanosafety, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049 (China)] [CAS Key Laboratory of Nuclear Analytical Techniques, Key Lab for Biomedical Effects of Nanomaterial and Nanosafety, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049 (China)

2013-08-15T23:59:59.000Z

462

PROCEEDINGS, Thirty-Sixth Workshop on Geothermal Reservoir Engineering Stanford University, Stanford, California, January 31 -February 2, 2011  

E-Print Network [OSTI]

problems associated with geothermal utilization. Hellisheiði Power Plant annually emits around 13000 tons The emission of hydrogen sulfide from geothermal power plants is one of the main environmental concerns is 101 µg/m3 . A review of the processes available for H2S abatement in geothermal power plant

Stanford University

463

Understanding Sulfur Poisoning and Regeneration of Nickel Biomass Conditioning Catalysts using X-Ray Absorption Spectroscopy  

SciTech Connect (OSTI)

The production of biofuels can proceed via a biomass gasification to produce syngas, which can then undergo catalytic conditioning and reforming reactions prior to being sent to a fuel synthesis reactor. Catalysts used for biomass conditioning are plagued by short lifetimes which are a result of, among other things, poisoning. Syngas produced from biomass gasification may contain between 30-300 ppm H2S, depending on the feedstock and gasification conditions, and H2S is a key catalyst poison. In order to overcome catalyst poisoning, either an H2S-tolerant catalyst or an efficient regeneration protocol should be employed. In this study, sulfur K-edge X-ray absorption near edge spectroscopy (XANES) was used to monitor sulfur species on spent catalyst samples and the transformation of these species from sulfides to sulfates during steam and air regeneration on a Ni/Mg/K/Al2O3 catalyst used to condition biomass-derived syngas. Additionally, nickel K-edge EXAFS and XANES are used to examine the state of nickel species on the catalysts. Post-reaction samples showed the presence of sulfides on the H2S-poisoned nickel catalyst and although some gaseous sulfur species were observed to leave the catalyst bed during regeneration, sulfur remained on the catalyst and a transformation from sulfides to sulfates was observed. The subsequent H2 reduction led to a partial reduction of sulfates back to sulfides. A proposed reaction sequence is presented and recommended regeneration strategies are discussed.

Yung, M. M.; Cheah, S.; Kuhn, J. N.

2013-01-01T23:59:59.000Z

464

The Astrophysical Journal, 773:184 (8pp), 2013 August 20 doi:10.1088/0004-637X/773/2/184 C 2013. The American Astronomical Society. All rights reserved. Printed in the U.S.A.  

E-Print Network [OSTI]

-containing precursors such as water (H2O), carbon dioxide (CO2), and/or methanol (CH3OH) upon interaction with ionizing are sulfur dioxide (SO2), sulfur monoxide (SO), hydrogen sulfide (H2S), carbon monosulfide (CS trioxide (SO3), and carbonyl sulfide (OCS). Formations of carbon dioxide (CO2), carbon monoxide (CO

Kaiser, Ralf I.

465

SSEENNSSOORR TTEECCHHNNOOLLOOGGYY AALLEERRTT Date Published: 24 Feb 2006  

E-Print Network [OSTI]

detection of Nitrogen Oxide (NOx) and H2S in coal power plants, Methane (CH4) and CO in coal mines (Sago their concentration reaches lethal levels is driven by events like the Sago coal mine disaster which took place on Jan valuable in situations where sensing of noxious gases such as carbon monoxide, methane, nitrogen oxides

Azad, Abdul-Majeed

466

Communications Counterion Effects in Liquid Crystal  

E-Print Network [OSTI]

Manuscript Received April 11, 1997 There have been several investigations on the syn- thesis of inorganics. In the methodology used here and in our previous work, H2S gas diffuses into the gellike mesophase leading composite was washed repeatedly with diethyl ether/ethanol (50/50) to remove byproducts and unbound

Braun, Paul

467

Diagenesis in seagrass vegetated sediments: biogeochemical processes on diurnal time scales  

E-Print Network [OSTI]

intervals (?x) of ?H2S and Fe2+. Characteristic scale lengths obtained for sediments from seagrass environments are not significantly different from those observed for unvegetated sediments and averaged 13.7?? 2.2 mm. Lateral variations in our scales...

Hebert, Andrew Brian

2005-11-01T23:59:59.000Z

468

Acknowledgments: NASA Glenn Research Center (Grant #NNC04GB44G) College of Engineering Prof. Martin Abraham NASA envisions employing fuel cells running on jet fuel reformate for its uninhabited aerial vehicles (UAVs), low emission alternative power (LE  

E-Print Network [OSTI]

· Prof. Martin Abraham NASA envisions employing fuel cells running on jet fuel reformate for its to the formation of H2S which is detrimental to the anode in the fuel cell stack in addition to emitting unpleasant's research and commercial flights using solid oxide fuel cells. ·· Designing nanoscale ceria-based sulfur

Azad, Abdul-Majeed

469

PublishedbyManeyPublishing(c)IOMCommunicationsLtd Influence of UV irradiation and ozone on  

E-Print Network [OSTI]

of purified humid air containing predetermined quantities of SO2, NO2, H2S, Cl2, HCI, NH3 and O3. This lackPublishedbyManeyPublishing(c)IOMCommunicationsLtd Influence of UV irradiation and ozone by ultraviolet (UV) light was investigated. A modified coulometric reduction technique was used, substituting

470

Worker Health on Modern Dairy and Poultry y y  

E-Print Network [OSTI]

/crushing 11 #12;Dairy Lagoons Odors/ VOC? Wind Anaerobic CO2 NH3 CH4 H2S Sludge bacteria Sludge 12 #12;Case study #2 MortalityCase study #2 Mortality · Jose Alatorre worked as a welder on a 1,700 cow dairy (200

Leistikow, Bruce N.

471

C. Plennevaux et al., Electrochemistry Communications 26 (2013) 1720 Contribution of CO2 on hydrogen evolution and hydrogen permeation in low  

E-Print Network [OSTI]

Introduction The risk of hydrogen embrittlement of steels is a primary concern for material selection in oil the risk of hydrogen embrittlement. Sulfide stress cracking (SSC) is one of the main risks of steel on hydrogen evolution and hydrogen permeation in low alloy steels exposed to H2S environment C. Plennevauxa

Paris-Sud XI, Université de

472

Biographical Summary Tianfu Xu is a Career Staff Scientist at the Lawrence Berkeley National Laboratory  

E-Print Network [OSTI]

diagenesis, evaluation of deep injection of H2S separated from natural gas reservoirs, and optimization in 1984 from Jilin University of China, an M.S. degree in 1993 from Delft University of Technology alterations due to CO2 intrusion, and the impact of CO2 leakage on groundwater quality. · Natural groundwater

Ajo-Franklin, Jonathan

473

MSU Extension Publication Archive Archive copy of publication, do not use for current recommendations. Up-to-date  

E-Print Network [OSTI]

. The high temperature trial ( 73° F.) in this study had three times the H2S gas production rates of the low temperature trial (60° F.). Several pro- ducers have confirmed these data in their hot nurseries with shallow The handling characteristics of swine manure depend upon the age of the pigs, the ration fed, and water usage

474

Sensing Requirements for Real-Time Monitoring and Control in Energy Production  

E-Print Network [OSTI]

effects from global warming, coupled with the rise of energy costs in developed countries has of US sources of coal contain high levels of sulfur. Physical and chemical sensor systems to monitor emission levels, H2S and COS which exist at significant levels must

Ghosh, Ruby N.

475

Effects of Hydrogen Sulfide on the Performance of a PEMFC R. Mohtadi,a,  

E-Print Network [OSTI]

October 7, 2003. In a ``hydrogen challenged'' economy, the fuel for proton ex- change membrane fuel cellsEffects of Hydrogen Sulfide on the Performance of a PEMFC R. Mohtadi,a, * W.-k. Lee,a, ** S. Cowan-products, such as carbon monoxide, ammonia, and hydrogen sulfide. While it is well known that H2S severely poisons Pt

Van Zee, John W.

476

Electrochemical Membrane Separation (EMS) of Hydrogen Sulfide from Coal Gasification Streams  

SciTech Connect (OSTI)

The goal of this work is to prepare an electrolytic cell for scale-up that is capable of removing H2S continuously. The major hurdles that remain are cathode selection and optimizing cell design and operating conditions. Studies have focused upon determining critical cell parameters for process scale-up as well as finding more stable and catalytically active cathode materials.

Burke, A.A.; Winnick, J.; Liu, M.; Li, S.

2002-09-20T23:59:59.000Z

477

Fresh clouds: A parameterized updraft method for calculating cloud densities in one-dimensional models  

E-Print Network [OSTI]

. Mihalka a a Department of Atmospheric, Oceanic, and Space Science, University of Michigan, Ann Arbor, MI 48109-2143, USA b Astronomy Department, University of California, Berkeley, CA 97420-3411, USA c NASA clouds com- posed of ammonia ice, ammonium hydrosulfide or other com- pounds formed by NH3 and H2S, water

Atreya, Sushil

478

The sulfur content of volcanic gases on Mars Fabrice Gaillard, a  

E-Print Network [OSTI]

principles, we model here the likely sulfur contents of (1) the martian and terrestrial mantles and (2 a denser atmosphere are shown to be dominated by CO ± CO2 and H2 ± H2O species, depending on fO2, sulfur by H2S, which should have favored the acidification of any persistent water layer. The calculated

Boyer, Edmond

479

6, 16191636, 2006 OCS variations by  

E-Print Network [OSTI]

significant sulfur trace gases such as carbon disulfide (CS2), hydrogen sulphide (H2S), dimethyl sulfide (DMS ­ (CH3)2S) and sulfur dioxide5 (SO2) (Brimblecombe, 1996). This lifetime, combined with an abundance, in the form of sulfur dioxide (SO2), directly to the stratosphere (Crutzen, 1976; Ko et al., 2003). However

Boyer, Edmond

480

subm. to Surf. Sci. Ab initio molecular dynamics study of H2 adsorption on sulfur-and chlorine-covered  

E-Print Network [OSTI]

subm. to Surf. Sci. Ab initio molecular dynamics study of H2 adsorption on sulfur- and chlorine/Germany The adsorption of molecular hydrogen on sulfur- and chlorine-covered Pd(100) in a (2?2) geometry is studied by ab initio molecular dynamics simulations. The potential energy surfaces of H2/S(2 ? 2)/Pd(100) and H2/Cl(2

Ulm, Universität

Note: This page contains sample records for the topic "n2 h2s hg" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Evidence for a Plasma Core during Multibubble Sonoluminescence in Sulfuric Acid  

E-Print Network [OSTI]

.g., SOx, trace amounts of H2S, and elemental sulfur)7 are either highly soluble or solids. Prior MBSL to be problematic. These volatile products can have limited solubility in the liquid and therefore accumulate for the generation of higher temperatures during cavitation. Sulfuric acid is one such liquid because it has a very

Suslick, Kenneth S.

482

Sulfur-induced greenhouse warming on early Mars Sarah Stewart Johnson,1  

E-Print Network [OSTI]

and 500 mbar CO2 with varying abundances of H2O and sulfur volatiles (H2S and SO2 mixing ratios of 10?3Sulfur-induced greenhouse warming on early Mars Sarah Stewart Johnson,1 Michael A. Mischna,2 melting model, we obtain a high sulfur solubility, approximately 1400 ppm, in Martian mantle melts. We

Zuber, Maria

483

EINDHOVEN UNIVERSITY OF TECHNOLOGY Department of Mathematics and Computer Science  

E-Print Network [OSTI]

unsaturated porous media, where the H2S air-water transfer and bacteria interplay together in the presence-14 May 2013 Large-time behavior of a two-scale semilinear reaction-diffusion system for concrete for concrete sulfatation Toyohiko Aiki and Adrian Muntean Department of Mathematics, Faculty of Science, Japan

Eindhoven, Technische Universiteit

484

Solar-Driven Photoelectrochemical Probing of Nanodot/Nanowire/ Cell Interface  

E-Print Network [OSTI]

the production and concentration of physiological H2S in real time. Nanowire-based photo- electrochemical (PEC and photocurrent, thus enabling the targeted electrochemical reactions without inducing other possible side reducing the background noise.19 Third, the light is absorbed along the nanowire's (NW's) micrometer

Gong, Xingao

485

Laboratoire de Conception de Systmes Mcaniques Gnie mcanique  

E-Print Network [OSTI]

recycled syngas CO2 + H2S storage Power O2 Air Gasification (Entrained flow gasifier) Gasifier Coal Dr MER François Maréchal Laurence Tock 1. Motivation 2. Objectives 5. Energy integration 3. IGCC model 6. Simulation results Industrial Energy Systems Laboratory LENI · The purpose of this project

Candea, George

486

Improved correlations for retrograde gases  

E-Print Network [OSTI]

. . . E-I GRACE Transformation of Ln(pressure), test correlation. . . . . E-2 GRACE Transformation of A'Z, test correlation. E-3 GRACE Transformation of CI, test correlation. F-4 GRACE Transformation of (CO2+H2S+C2+C5+C6], test correlation . . . F-5...

Crogh, Arne

1996-01-01T23:59:59.000Z

487

ACCEPTED BY WATER ENVIRONMENT RESEARCH ODOR AND VOC REMOVAL FROM WASTEWATER TREATMENT PLANT  

E-Print Network [OSTI]

ACCEPTED BY WATER ENVIRONMENT RESEARCH _______ ODOR AND VOC REMOVAL FROM WASTEWATER TREATMENT PLANT of biofilters for sequential removal of H2S and VOCs from wastewater treatment plant waste air. The biofilter volatile organic compounds (VOCs) and toxic air pollutants emitted from wastewater and solids handling

488

Effect of d-ferrite on impact properties of supermartensitic stainless steel  

E-Print Network [OSTI]

been intro- duced in the oil and gas industry to substitute more expensive duplex (ferritic is free from d-ferrite and offers good corrosion resistance in environments contain- ing CO2 and some H2S to a reduction in the corrosion resistance.6 The minimum titanium content required to prevent these effects

Cambridge, University of

489

Chemosynthesis vs. photosynthesis  

E-Print Network [OSTI]

1 Chemosynthesis vs. photosynthesis Solar energy is the energy source for most food webs http://www.bigelow.org/foodweb/chain4.html Chemicals produced by deep sea vents (H2S) are the primary energy source in a few cases Many in Peruvian poison frogs supports a Mllerian hypothesis. PRSLB 268:2415-2421 http://www.ucl.ac.uk

Mitchell, Randall J.

490

Literature Review of Air Pollution Control Biofilters and Biotrickling  

E-Print Network [OSTI]

Literature Review of Air Pollution Control Biofilters and Biotrickling Filters for Odor Emission Standards for Hazardous Air Pollutants and Title V permitting) as well as local and state for the treatment of complex odorous waste air containing hydrogen sulfide (H2S), organic reduced sulfur com- pounds

491

PRODUCTION OF HYDROGEN AND ELECTRICITY FROM COAL WITH CO2 CAPTURE  

E-Print Network [OSTI]

gasification, quench cooled and shifted to (pri- marily) H2 and CO2 via sulfur-tolerant water-gas shift (WGS with sulfur-bearing waste gases, H2S and SO2. I. INTRODUCTION Carbon-free energy carriers, H2 and electricity relative abundance, high carbon intensity, and low cost. Coal-to-H2 plants based on gasification have been

492

HELSINKI UNIVERSITY OF TECHNOLOGY ENE-47.153 SULPHUR #1SULPHUR #1  

E-Print Network [OSTI]

) ·· HH22S (gasification) highly poisonousS (gasification) highly poisonous oxidation to SOoxidation to SO. · natural gases / raw fuel gases á H2S · unrefined oil / heavy fuel oils á small amounts of sulphur · waste-derived fuels á e.g. vulcaniser, food-derived waste (garlic, onion), "black liquor" etc. organic á sulphides

Zevenhoven, Ron

493

Polyaniline nanowires-gold nanoparticles hybrid network based chemiresistive hydrogen sulfide sensor  

E-Print Network [OSTI]

Polyaniline nanowires-gold nanoparticles hybrid network based chemiresistive hydrogen sulfide for hydrogen sulfide detection and quantification using polyaniline nanowires-gold nanoparticles hybrid network.1063/1.3070237 Hydrogen sulfide H2S is a toxic, corrosive, and inflam- mable gas produced in sewage, coal mines, oil

494

Mitigation of Hydrogen Sulfide Emissions in the Geysers KGRA (Staff Draft)  

SciTech Connect (OSTI)

Violations of the ambient air quality standard (AAQS) for hydrogen sulfide (H2S) are currently being experienced in The Geysers KGRA and could significantly increase in the future. Attainment and maintenance of the H2S AAQS is a potential constraint to optimum development of this resource. The availability of reliable H2S controls and the development of a validated air dispersion model are critical to alleviating this constraint. The purpose of this report is to assess the performance capabilities for state-of-the-art controls, to identify potential cost-effective alternative controls, and to identify the California Energy Commission (CEC) staffs efforts to develop a validated air dispersion model. Currently available controls (Stretford, Hydrogen Peroxide, and EIC) are capable of abating H2S emissions from a proposed facility to five lbs/hr. Alternative controls, such as condensate stripping and condensate pH control, appear to promising, cost-effective control option. The CEC staff is currently developing a validated air dispersion model for The Geysers KGRA. The CEC staff recommends investigation of retrofit control options for existing units, investigation of alternative control technologies, and dispersion analysis for optimum plant location in order to maximize the development potential of The Geysers KGRA. Energy cost studies suggest that the EIC process would be the most cost-effective for retrofits at The Geysers. (DJE-2005)

Buell, Richard

1981-07-01T23:59:59.000Z

495

Performance of Sulfur Tolerant Reforming Catalysts for Production of Hydrogen from Jet Fuel Simulants  

E-Print Network [OSTI]

,2 operated by fuel cells. Unfortunately, the lack of infrastructure, such as a network of hydrogen refueling of hydrogen sulfide (H2S), which poisons the anode in the fuel cell stack, leading to low SOFC efficiencyPerformance of Sulfur Tolerant Reforming Catalysts for Production of Hydrogen from Jet Fuel

Azad, Abdul-Majeed

496

JOURNAL OF BACTERIOLOGY, 0021-9193/01/$04.00 0 DOI: 10.1128/JB.183.2.716724.2001  

E-Print Network [OSTI]

medium in the absence of peptides. Phenylacetate production rates (from phenylalanine fermentation) from elemental sulfur (S0 ) as a terminal electron acceptor leading to H2S production. The most studied of the S0 are dependent on ADP rather than ATP, and a novel tungsten-containing enzyme termed glycer- aldehyde-3-phosphate

Holden, James F.

497

Final Report - Development of New Pressure Swing Adsorption (PSA) Technology to Recover High Valued Products from Chemical Plant and Refinery Waste Systems  

SciTech Connect (OSTI)

Project Objective was to extend pressure swing adsorption (PSA) technology into previously under-exploited applications such as polyolefin production vent gas recovery and H2 recovery from refinery waste gases containing significant amounts of heavy hydrocarbons, aromatics, or H2S.

Keith Ludwig

2004-06-14T23:59:59.000Z

498

Mercury speciation driven by seasonal changes in a contaminated estuarine environment  

SciTech Connect (OSTI)

In this study, seasonal changes of mercury (Hg) species in the highly variable estuary of So?a/Isonzo River (northern Adriatic Sea) were investigated. Samplings were performed on a seasonal basis (September 2009, May, August and October 2010) and Hg species (total Hg, methylmercury (MeHg), dissolved gaseous Hg (DGM)) in waters, sediments and pore waters were determined. In addition, a range of ancillary parameters were measured (salinity, nutrients, organic carbon (OC), nitrogen species). Hg values were interpreted using these parameters and hydrological conditions (river flow, wave height) around the time of sampling. There were no significant changes in Hg load from river to the gulf, compared to previous studies. The load was temporarily higher in May 2010 due to higher river flow. Wave height, through changing hydrostatic pressure, was most likely to cause resuspension of already deposited Hg from the bottom (August 2010). The estuary is a net source of DGM to the atmosphere as suggested by DGM profiles, with salinity, redox potential and organic matter as the most probable controls over its production. MeHg is produced in situ in sediment or in water column, rather than transported by river, as indicated by its correlation with OC of the marine origin. Calculated fluxes for THg and MeHg showed sediment as a source for both the water column. In pore waters, OC in part affects partitioning of both THg and MeHg; however other factors (e.g. sulphide and/or oxyhydroxides precipitation and dissolution) are also probably important. -- Highlights: ? Water, sediment and pore water mercury species in front of So?a River estuary were measured. ? Seasonally variable hydrological conditions were shown to influence water column Hg speciation. ? Fluxes for total Hg and MeHg from sediment to water were calculated. ? Sediment is a source of total Hg and MeHg to the water column. ? Correlation of MeHg with organic carbon of marine origin suggests in situ formation.

Bratki?, Arne, E-mail: arne.bratkic@ijs.si [Department of Environmental Sciences, Joef Stefan Institute, Jamova 39, 1000 Ljubljana (Slovenia)] [Department of Environmental Sciences, Joef Stefan Institute, Jamova 39, 1000 Ljubljana (Slovenia); Ogrinc, Nives, E-mail: nives.orginc@ijs.si [Department of Environmental Sciences, Joef Stefan Institute, Jamova 39, 1000 Ljubljana (Slovenia)] [Department of Environmental Sciences, Joef Stefan Institute, Jamova 39, 1000 Ljubljana (Slovenia); Kotnik, Joe, E-mail: joze.kotnik@ijs.si [Department of Environmental Sciences, Joef Stefan Institute, Jamova 39, 1000 Ljubljana (Slovenia)] [Department of Environmental Sciences, Joef Stefan Institute, Jamova 39, 1000 Ljubljana (Slovenia); Faganeli, Jadran, E-mail: faganeli@mbss.org [Marine Biology Station, Forna?e 41, 6330 Piran (Slovenia)] [Marine Biology Station, Forna?e 41, 6330 Piran (Slovenia); agar, Duan, E-mail: dusan.zagar@fgg.uni-lj.si [Faculty of Civil and Geodetic Engineering, Jamova 2, 1000 Ljubljana (Slovenia)] [Faculty of Civil and Geodetic Engineering, Jamova 2, 1000 Ljubljana (Slovenia); Yano, Shinichiro [Faculty of Engineering, Kyushu University, Fukuoka 812-8581 (Japan)] [Faculty of Engineering, Kyushu University, Fukuoka 812-8581 (Japan); Tada, Akihide, E-mail: tada@civil.nagasaki-u.ac.jp [Faculty of Engineering, Nagasaki University, Bunkyo-machi 1-14, Nagasaki 852-8521 (Japan)] [Faculty of Engineering, Nagasaki University, Bunkyo-machi 1-14, Nagasaki 852-8521 (Japan); Horvat, Milena, E-mail: milena.horvat@ijs.si [Department of Environmental Sciences, Joef Stefan Institute, Jamova 39, 1000 Ljubljana (Slovenia)] [Department of Environmental Sciences, Joef Stefan Institute, Jamova 39, 1000 Ljubljana (Slovenia)

2013-08-15T23:59:59.000Z

499

Our Environment in Hot Water: Comparing Water Heaters, A Life Cycle Approach Comparing Tank and Tankless Water Heaters in California  

E-Print Network [OSTI]

unit*year) Heavy Metals to Water Heavy Metals to Water mg NiMatter Emissions (Water) Heavy Metals mg Hg/20 /unit*yearMatter Mg/year Emissions (Water) Heavy Metals Gg Hg/20 /year

Lu, Alison

2011-01-01T23:59:59.000Z

500

Enhanced Uptake and Modified Distribution of Mercury(II) by Fulvic  

E-Print Network [OSTI]

release Hg(0) or Hg(II) into the atmosphere, which is then returned to the surface by precipitation to mineral surfaces via electrostatic and hydrophobic interactions. Whereas organic matter coatings can alter

Illinois at Chicago, University of