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Sample records for n2 h2s hg

  1. Review of H2S Abatement in Geothermal Plants and Laboratory Scale Design of

    E-Print Network [OSTI]

    Karlsson, Brynjar

    Review of H2S Abatement in Geothermal Plants and Laboratory Scale Design of Tray Plate Distillation Engineering ­ ISE December 2013 #12;ii Review of H2S Abatement Methods in Geothermal Plants and Laboratory having significantly lower emissions in comparison to traditional fossil fuel plants, geothermal power

  2. H2S removal with ZnO during fuel processing for PEM fuel cell applications

    SciTech Connect (OSTI)

    Li, Liyu; King, David L.

    2006-09-15

    The possibility of using ZnO as a H2S absorbent to protect catalysts in the gasoline and diesel fuel processor for PEM fuel cell applications was studied. It is possible to use commercial ZnO absorbent as a guard bed to protect the PROX catalyst and PEM fuel cell. However, it is not feasible to use ZnO to protect high and low temperature WGS catalysts, most likely due to COS formation via reactions CO + H2S = COS + H2 and CO2 + H2S = COS + H2O.

  3. Modeling Studies on the Transport of Benzene and H2S in CO2-Water Systems

    E-Print Network [OSTI]

    Zheng, L.

    2011-01-01

    Studies on the Transport of Benzene and H 2 S in CO 2 -WaterSolubility measurements of benzene and the alkylbenzenes inDeguchi, 1987. Solubility benzene-hydrocarbon binary mixture

  4. Retrofitting existing chemical scrubbers to biotrickling filters for H2S emission control

    E-Print Network [OSTI]

    Retrofitting existing chemical scrubbers to biotrickling filters for H2S emission control David owned treatment works in the United States (1, 2) and probably 50,000 worldwide, and emission

  5. Qualitative determination of H2S crossover rates in nation membranes using ion-probe techniques

    SciTech Connect (OSTI)

    Brosha, Eric L; Rockward, Tommy; Uribe, Francisco A; Garzon, Fernando H

    2008-01-01

    Polymer electrolyte membrane fuel cells are sensitive to impurities that may be present in either the oxidizer or fuel. H2S, even at the ppb level, will have a dramatic and adverse affect on fuel cell performance. The H2S permeability through dry and humidified Nafion PEMFC membranes was studied using ion probe techniques. A sulfide anti-oxidant buffer solution was used to trap and concentrate trace quantities of H2S that permeated through 50 cm2samples of Nafion 117 and 212 membranes using a partial pressure difference up to I030ppm at room temperature. Experiments were conducted for up to 24 hours in order to achieve sulfide ion concentrations high enough to be precisely determined by subsequent titration with Pb(N03)2. The rate of H2S crossover for dry 117 and 212 were identical at 1.2e-7 g/min. Humidification increased the crossover rate to 5.ge-7 glmin and 1.8e-6 glmin for 117 and 212 respectively. Although the data collected in this work show that the rate of H2S crossover increases with water content and reduced membrane thickness, an accurate determination of permeation constants from this work was not possible because the H2S partial pressure was not constant throughout the experiment.

  6. Rate of H2S and CO2 attack on pozzolan-amended Class H well cement...

    Office of Scientific and Technical Information (OSTI)

    Rate of H2S and CO2 attack on pozzolan-amended Class H well cement under geologic sequestration conditions Citation Details In-Document Search Title: Rate of H2S and CO2 attack on...

  7. The effect of continuous H2S exposure on the performance of thick palladium-copper alloy membranes (book chapter)

    SciTech Connect (OSTI)

    Howard, B.H.; Cugini, A.V.; Killmeyer, R.P.; Morreale, B.D.; Enick, R.M.

    2007-03-01

    Membranes fabricated from Pd-Cu alloys containing 80, 60, and 53wt%Pd, as well as pure Pd, were exposed to flowing 1000 ppm H2S in H2 over the temperature range of 350 to 900°C using three approaches to verify NETL's previously reported transient H2S exposure results. 100 um thick braze-mounted foils failed prior to 600°C due to apparent sulfur attack at the braze. 1000 um thick welded membranes demonstrated similar trends as found using the transient method in that hydrogen flux through the Pd-Cu alloys with fcc structure was not significantly degraded by H2S exposure. However, both of these experimental methods suffered from possible disadvantages. The transient method had limited H2S availability and limited exposure duration, and in the 1000 um steady-state test, bulk diffusion limitations could mask effects resulting from H2S exposure. Preliminary results obtained using an alternative membrane mounting method and test protocol for steady-state testing of 100 um thick Pd and 80wt%Pd-Cu foils at 350°C showed that significant flux losses occurred on exposure to flowing 1000 ppm H2S in H2, contrary to the earlier studies. Characterization showed that relatively thick sulfide layers had developed on the membrane surfaces during the 120 hours of exposure.

  8. Oxidation of H2S by coadsorbed oxygen on the ?-Cr2O3(0001) surface

    SciTech Connect (OSTI)

    Henderson, Michael A.; Rosso, Kevin M.

    2011-03-01

    The interactions of H2S and oxygen have been explored on the a-Cr2O3(0001) surface using temperature programmed desorption (TPD), Auger electron spectroscopy (AES) and sticking coefficient measurements. H2S adsorbs with near unity sticking on the clean a-Cr2O3(0001) surface at 125 K up to a coverage of ~1.6 ML (where 1 ML is defined as the surface areal density of Cr3+ sites). Reversible adsorption is evidenced in TPD by three desorption states evolving between 150 and 315 K. Although no S-containing decomposition products were observed in TPD, AES detected S on the surface after TPD indicating that some degree of irreversible decomposition occurred. The level of H2S decomposition on the clean surface was estimated to be between 0.2-0.5 ML using water TPD as an indicator of S site blocking. In contrast, preadsorbed O2 at three temperatures (125, 400 and 800 K) exerted drastic changes on the surface chemistry of H2S seen on the clean surface. At 400 and 800 K, O2 adsorption on clean ?-Cr2O3(0001) is dissociative, populating the surface with chromyl groups (Cr=O) in the former case (corresponding to roughly 1 O per Cr3+ surface site) and resulting in a nearly complete O-termination sheet (~3 O per Cr3+) in the latter case. Little or no H2S chemistry is observed on the O-terminated surface based on TPD and AES. However, availability of Cr-coordination sites on the chromyl-terminated surface facilitated H2S adsorption and oxidation during TPD to SO2 (445-470 K) and H2O (320 K). Isotopic-labeling studies suggest that the oxygen atom in the water product originates from dosed oxygen whereas that in the SO2 product comes from the lattice. Similar results were obtained from H2S dosed on the surface pretreated with O2 at 125 K, where O2 adsorption is predominately molecular, except that S2 was also detected in TPD at 525 K and the amount of SO2 produced at 445 K decreased. These results suggest that atomically adsorbed oxygen effectively oxidizes H2S, but that molecularly adsorbed O2 is key to the partial oxidation of H2S to elemental sulfur.

  9. Influence of pp ions on pion absorption in H2 S. Jonsell,1

    E-Print Network [OSTI]

    reaction p 0 n 2 from the bound states of the pionic atoms p 4 . If the initial velocity of the pionic difference is important in stud- ies of the rare pion decay through the reaction 0 e 1 and allows tests

  10. Chemical Engineering Journal 87 (2002) 101110 Co-treatment of H2S and toluene in a biotrickling filter

    E-Print Network [OSTI]

    2002-01-01

    Chemical Engineering Journal 87 (2002) 101­110 Co-treatment of H2S and toluene in a biotrickling filter Huub H.J. Cox, Marc A. Deshusses Department of Chemical and Environmental Engineering, University/hypochlorite or caustic/peroxide scrubbers. However, chemical scrubbers are expensive to operate and relatively

  11. New sulfur adsorbents derived from layered double hydroxides: II. DRIFTS study of COS and H2S adsorption

    SciTech Connect (OSTI)

    Toops, Todd J [ORNL; Crocker, Mark [University of Kentucky

    2008-01-01

    H2S and COS adsorption were studied on two calcined layered double hydroxides (LDHs), Mg0.75Al0.25(OH)2(CO3)0.125 and Mg0.65Al0.35(OH)2(CO3)0.175, using Diffuse Reflectance Infrared Fourier Transform Spectroscopy (DRIFTS) and a chemisorption apparatus. Both demonstrated the ability to irreversibly adsorb H2S, corresponding to uptakes of 1.54 and 1.76 mol/m2 respectively, but Mg0.75Al0.25 had a significantly larger capacity for COS, 1.62 mol/m2 compared to 0.80 mol/m2 for Mg0.65Al0.35. Analysis of the DRIFT spectra suggests the adsorption of H2S proceeds via the substitution of lattice oxygen with sulfur, resulting in the formation of H2O on the surface. COS adsorption is more complicated, although it appears that a similar substitution of lattice oxygen with sulfur occurs. This results in the formation of CO2 and subsequently bicarbonates and carbonates. The formation of hydrogen thiocarbonate is also involved, although this form is generally only observed in the later stages of adsorption and appears to form at the expense of bicarbonate. The Mg0.75Al0.25 LDH retained its ability to adsorb COS in the presence of propene.

  12. AOI [3] High-Temperature Nano-Derived Micro-H2 and - H2S Sensors

    SciTech Connect (OSTI)

    Perepezko, John; Lu-Steffes, Otto

    2014-08-31

    The emissions from coal-fired power plants remain a significant concern for air quality. This environmental challenge must be overcome by controlling the emission of sulfur dioxide (SO2) and hydrogen sulfide (H2S) throughout the entire coal combustion process. One of the processes which could specifically benefit from robust, low cost, and high temperature compatible gas sensors is the coal gasification process which converts coal and/or biomass into syngas. Hydrogen (H2), carbon monoxide (CO) and sulfur compounds make up 33%, 43% and 2% of syngas, respectively. Therefore, development of a high temperature (>500°C) chemical sensor for in-situ monitoring of H2, H2S and SO2 levels during coal gasification is strongly desired. The selective detection of SO2/H2S in the presence of H2, is a formidable task for a sensor designer. In order to ensure effective operation of these chemical sensors, the sensor system must inexpensively function within harsh temperature and chemical environment. Currently available sensing approaches, which are based on gas chromatography, electrochemistry, and IR-spectroscopy, do not satisfy the required cost and performance targets. This work focused on the development microsensors that can be applied to this application. In order to develop the high- temperature compatible microsensor, this work addressed various issues related to sensor stability, selectivity, and miniaturization. In the research project entitled “High-Temperature Nano-Derived Micro-H2 and -H2S Sensors”, the team worked to develop micro-scale, chemical sensors and sensor arrays composed of nano-derived, metal-oxide composite materials to detect gases like H2, SO2, and H2S within high-temperature environments (>500?C). The research was completed in collaboration with NexTech Materials, Ltd. (Lewis Center, Ohio). NexTech assisted in the testing of the sensors in syngas with contaminate levels of H2S. The idea of including nanomaterials as the sensing material within resistive-type chemical sensor platforms was to increase the sensitivity (as shown for room temperature applications). Unfortunately, nanomaterials are not stable at high temperatures due to sintering and coarsening processes that are driven by their high surface to volume ratio. Therefore, new hydrogen and sulfur selective nanomaterial systems with high selectivity and stability properties in the proposed harsh environment were investigated. Different nano-morphologies of zirconate, molybdate, and tungstate compounds were investigated. The fabrication of the microsensors consisted of the deposition of the selective nanomaterial systems over metal based interconnects on an inert substrate. This work utilized the chemi-resistive (resistive- type) microsensor architecture where the chemically and structurally stable, high temperature compatible electrodes were sputtered onto a ceramic substrate. The nanomaterial sensing systems were deposited over the electrodes using a lost mold method patterned by conventional optical lithography. The microsensor configuration with optimized nanomaterial system was tested and compared to a millimeter-size sensor e outcomes of this research will contribute to the economical application of sensor arrays for simultaneous sensing of H2, H2S, and SO2.

  13. Characterization of BCl3/N-2 plasmas

    E-Print Network [OSTI]

    Sia, S. F.

    2003-08-15

    Optical emission spectroscopy, quadrupole mass spectrometry, and electron density measurements were used to study the effect of the percentage of N-2 on the characteristics of BCl3/N-2 plasmas and their resulting etch processes. The etch rate of Ga...

  14. Hg System Assembly and Testing Status

    E-Print Network [OSTI]

    McDonald, Kirk

    ;4VRVS Meeting 8 Nov 2006 OAK RIDGE NATIONAL LABORATORY U. S. DEPARTMENT OF ENERGY Hydraulic Hose Issue #12;2VRVS Meeting 8 Nov 2006 OAK RIDGE NATIONAL LABORATORY U. S. DEPARTMENT OF ENERGY Hg Drain & Spill Meeting 8 Nov 2006 OAK RIDGE NATIONAL LABORATORY U. S. DEPARTMENT OF ENERGY Local Hg Vapor Filters · Hg

  15. Mathematical Model Analysis for Hg Flow

    E-Print Network [OSTI]

    McDonald, Kirk

    Mathematical Model Analysis for Hg Flow Yan Zhan SUNYSB April 20th, 2010 #12;Outline · Introduction ­ Mechanism of Jet Breakup & Atomization ­ Dynamic Problems in Hg Target Flow · Mathematical Model for Hg Flow ­ Parameters ­ Incompressible Flow (No MHD) ­ Incompressible Flow (MHD) ­ Proton Beam Energy Conversion

  16. N=2 supersymmetric Pais-Uhlenbeck oscillator

    E-Print Network [OSTI]

    Ivan Masterov

    2015-05-29

    We construct an N=2 supersymmetric extension of the Pais-Uhlenbeck oscillator for distinct frequencies of oscillation. A link to a set of decoupled N=2 supersymmetric harmonic oscillators with alternating sign in the Hamiltonian is introduced. Symmetries of the model are discussed in detail. The investigation of a quantum counterpart of the constructed model shows that the corresponding Fock space contains negative norm states and the energy spectrum of the system is unbounded from below.

  17. Aero III/IV Sheet 2 Solutions 1 A. G. Walton 5 ' % n +c + 52 n 25 ' E% n +2 n 2E% n + ' %2 +2 n 2% n E2+ n 2%+

    E-Print Network [OSTI]

    Walton, Andrew G

    Aero III/IV Sheet 2 Solutions 1 A. G. Walton 1(i) 5 ' % n +c + 52 n 25 ' E% n +2 n 2E% n + ' %2 +2 #12;Aero III/IV Sheet 2 Solutions 2 A. G. Walton and let @ ' Z*2 (inside Then, U ' 2ZsE@ ' 2Ze 3Z*2

  18. IDS120j WITHOUT RESISTIVE MAGNETS MODIFYING Hg MODULE ( NEW SH#1 REGION + Hg POOL LENGTH)

    E-Print Network [OSTI]

    McDonald, Kirk

    IDS120j WITHOUT RESISTIVE MAGNETS MODIFYING Hg MODULE ( NEW SH#1 REGION + Hg POOL LENGTH) Nicholas CRYO#1 WAS DECIDED DURING THE LAST MEETING AND AN EXTENSION OF THE Hg POOL UPSTREAM UP TO ~ - 100 cm FROM SIMULATIONS WITH MODIFIED Hg POOL AND SH#1 REGION

  19. An Extremal N=2 Superconformal Field Theory

    E-Print Network [OSTI]

    Nathan Benjamin; Ethan Dyer; A. Liam Fitzpatrick; Shamit Kachru

    2015-06-30

    We provide an example of an extremal chiral ${\\cal N}=2$ superconformal field theory at $c=24$. The construction is based on a ${\\mathbb Z}_2$ orbifold of the theory associated to the $A_{1}^{24}$ Niemeier lattice. The statespace is governed by representations of the sporadic group $M_{23}$.

  20. New Seiberg Dualities from N=2 Dualities

    E-Print Network [OSTI]

    Kazunobu Maruyoshi; Masato Taki; Seiji Terashima; Futoshi Yagi

    2009-09-01

    We propose a number of new Seiberg dualities of N=1 quiver gauge theories. The new Seiberg dualities originate in new S-dualities of N=2 superconformal field theories recently proposed by Gaiotto. N=2 S-dual theories deformed by suitable mass terms flow to our N=1 Seiberg dual theories. We show that the number of exactly marginal operators is universal for these Seiberg dual theories and the 't Hooft anomaly matching holds for these theories. These provide strong evidence for the new Seiberg dualities. Furthermore, we study in detail the Klebanov-Witten type theory and its dual as a concrete example. We show that chiral operators and their non-linear relations match between these theories. These arguments also give non-trivial consistency checks for our proposal.

  1. Thermodynamics of the N=2* flow

    E-Print Network [OSTI]

    Buchel, A S; Buchel, Alex; Liu, James T.

    2003-01-01

    We discuss the thermodynamics of the N=2*, SU(N) gauge theory at large 't Hooft coupling. The tool we use is the non-extremal deformation of the supergravity solution of Pilch and Warner (PW) [hep-th/0004063], dual to N=4, SU(N) gauge theory softly broken to N=2. We construct the exact non-extremal solution in five-dimensional gauged supergravity and further uplift it to ten dimensions. Turning to the thermodynamics, we analytically compute the leading correction in m/T to the free energy of the non-extremal D3 branes due to the PW mass deformation, and find that it is positive. We also demonstrate that the mass deformation of the non-extremal D3 brane geometry induces a temperature dependent gaugino condensate. We find that the standard procedure of extracting the N=2* gauge theory thermodynamic quantities from the dual supergravity leads to a violation of the first law of thermodynamics. We speculate on a possible resolution of this paradox.

  2. High Power Hg Target Conceptual Design Review

    E-Print Network [OSTI]

    McDonald, Kirk

    OF ENERGY Conceptual Design Review 7-8 Feb 05 Pump Issues · Pump adds heat to Hg - Pump delivers nominal 51 to pump heating only · Max available pump output pressure is 750 psi (50 bar) - Estimated piping system Review 7-8 Feb 05 Pump Energy Balance Pump Heat Direct to Tunnel Heat Input to Hg Flow Losses Energy

  3. RSE Table N2.1 and N2.2. Relative Standard Errors for Tables N2.1 and N2.2

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: AlternativeMonthly","10/2015"Monthly","10/2015" ,"Release7Cubicthroughthe PriceThousanda Oxygenated55,453.9151 and N1.2.N2.1

  4. N=2 String as a Topological Conformal Algebra

    E-Print Network [OSTI]

    J. Gomis; H. Suzuki

    1991-11-28

    We prove that critical and subcritical N=2 string theory gives a realization of an N=2 superfield extension of the topological conformal algebra. The essential observation is the vanishing of the background charge.

  5. The role of plants in the Hg biogeochemical cycle

    E-Print Network [OSTI]

    Nowak, Robert S.

    Biogeochemical Cycle Hg0RGM Hgp Sources Natural: · Soils G th l A ti Z Anthropogenic: · Coal fired power plants W Cycle Hg0RGM Hgp Factors that control Hg release from soils ­ Light TemperatureTemperature Precipitation ­ Anthropogenic emission sources and secondary formation by id ti f H 0oxidation of Hg0 · Particulate mercury (Hgp

  6. Photooxidation of Hg(0) in Artificial and Natural Waters

    E-Print Network [OSTI]

    Morel, François M. M.

    artificial and natural waters irradiated with a UV-B lamp. No change in Hg speciation was observed in dark waters could represent a net balance between Hg(II) photoreduction and Hg(0) photooxidation oxidized in the dark (7, 8). But it is not known iftheseresultsobtainedwithliquiddropsofHg(0)arerelevant

  7. Magnetic fields of HgMn stars

    E-Print Network [OSTI]

    Hubrig, S; Ilyin, I; Korhonen, H; Schoeller, M; Savanov, I; Arlt, R; Castelli, F; Curto, G Lo; Briquet, M; Dall, T H

    2012-01-01

    The frequent presence of weak magnetic fields on the surface of spotted late-B stars with HgMn peculiarity in binary systems has been controversial during the two last decades. We re-analyse available spectropolarimetric material by applying the moment technique on spectral lines of inhomogeneously distributed elements separately. Furthermore, we present new determinations of the mean longitudinal magnetic field for the HgMn star HD65949 and the hotter analog of HgMn stars, the PGa star HD19400, using FORS2 installed at the VLT. We also give new measurements of the eclipsing system AR Aur with a primary star of HgMn peculiarity which were obtained with the SOFIN spectropolarimeter installed at the Nordic Optical Telescope. We downloaded from the ESO archive the publically available HARPS spectra for eight HgMn stars and one normal and one superficially normal B-type star obtained in 2010. The application of the moment technique to the HARPS and SOFIN spectra allowed us to study the presence of the longitudina...

  8. Superfield Realizations of $N=2$ Super-$W_3$

    E-Print Network [OSTI]

    E. Ivanov; S. Krivonos

    1992-04-10

    We present a manifestly $N=2$ supersymmetric formulation of $N=2$ super-$W_3$ algebra (its classical version) in terms of the spin 1 and spin 2 supercurrents. Two closely related types of the Feigin-Fuchs representation for these supercurrents are found: via two chiral spin $\\frac{1}{2}$ superfields generating $N=2$ extended $U(1)$ Kac-Moody algebras and via two free chiral spin 0 superfields. We also construct a one-parameter family of $N=2$ super Boussinesq equations for which $N=2$ super-$W_3$ provides the second hamiltonian structure.

  9. Renormalizable N=2 supersymmetric and gauge invariant interactions from the N=2 harmonic superspace with central charges

    SciTech Connect (OSTI)

    Saidi, E.H. (Laboratoire de Physique Theorique, Faculte de Sciences, Battouta, Rabat (MA))

    1987-01-01

    The N=2 harmonic superspace in the presence of central charges is developed. Renormalizable interactions unusual in N=2 supersymmetric theories are derived in a consistent way. Symmetries generated by the central charges are discussed. A certain equivalence between N=2 harmonic superspace with and without central charges is established. An Abelian generalization of the model is given.

  10. Hg System Status V.B. Graves

    E-Print Network [OSTI]

    McDonald, Kirk

    LABORATORY U. S. DEPARTMENT OF ENERGY HPU Setup · Hydraulic fluid fill and drain process developed using Friday Meeting4 Aug 2006 OAK RIDGE NATIONAL LABORATORY U. S. DEPARTMENT OF ENERGY Syringe Pump at ORNL · Hydraulic power unit (HPU) and syringe cylinders delivered to ORNL July 21 - Hg cylinder discharge piping

  11. Hg System Assembly and Testing Status

    E-Print Network [OSTI]

    McDonald, Kirk

    U. S. DEPARTMENT OF ENERGY Hydraulic Hose Issue Corrected · Replaced flex hoses with rigid tubing #12;2VRVS Meeting 22 Nov 2006 OAK RIDGE NATIONAL LABORATORY U. S. DEPARTMENT OF ENERGY Hg System baseplate #12;3VRVS Meeting 22 Nov 2006 OAK RIDGE NATIONAL LABORATORY U. S. DEPARTMENT OF ENERGY Basic

  12. Safety Issues for Hg irradiation Experiment siting -

    E-Print Network [OSTI]

    McDonald, Kirk

    1 SC/RP Safety Issues for Hg irradiation Experiment siting - Activation of air and components water retention Activation of air by 40 pulses of 2E13 p corresponds to approx. 1 yr of operation in EHN1. Lack of beam dump leads to unnecessary activation of components and aggravates air activation #12

  13. (n, 2)-SETS HAVE FULL HAUSDORFF DIMENSION THEMIS MITSIS

    E-Print Network [OSTI]

    Jyväskylä, University of

    : dist(x, Le(a)) } is the infinite tube with axis Le(a) and cross-section radius . 2000 Mathematics measure n,2 which is invariant under the action of the orthogonal group. The elements of Gn that n,2({P Gn : d(P, P0) }) 2(n-2) for all P0 Gn, 1. So if A Gn and B is a maximal -separated

  14. N=2 Superfields and the M-Fivebrane

    E-Print Network [OSTI]

    N. D. Lambert; P. C. West

    1998-02-23

    In this paper we provide a manifestly N=2 supersymmetric formulation of the M-fivebrane in the presence of threebrane solitons. The superspace form of four-dimensional effective equations for the threebranes are readily obtained and yield the complete Seiberg-Witten equations of motion for N=2 super-Yang-Mills. A particularly simple derivation is given by introducing an N=2 superfield generalisation of the Seiberg-Witten differential.

  15. High-Permeance Room-Temperature Ionic-Liquid-Based Membranes for CO2/N-2 Separation

    SciTech Connect (OSTI)

    Zhou, JS; Mok, MM; Cowan, MG; McDanel, WM; Carlisle, TK; Gin, DL; Noble, RD

    2014-12-24

    We have developed and fabricated thin-film composite (TFC) membranes with an active layer consisting of a room-temperature ionic liquid/polymerized (room-temperature ionic liquid) [i.e., (RTIL)/poly(RTIL)] composite material. The resulting membrane has a CO2 permeance of 6100 +/- 400 GPU (where 1 GPU = 10(-6) cm(3)/(cm(2) s cmHg)) and an ideal CO2/N-2 selectivity of 22 +/- 2. This represents a new membrane with state-of-the-art CO2 permeance and good CO2/N-2 selectivity. To our knowledge, this is the first example of a TFC gas separation membrane composed of an RTIL-containing active layer.

  16. CO and N$_2$ desorption energies from water ice

    E-Print Network [OSTI]

    Fayolle, Edith C; Loomis, Ryan; Bergner, Jennifer; Graninger, Dawn M; Rajappan, Mahesh; Öberg, Karin I

    2015-01-01

    The relative desorption energies of CO and N$_2$ are key to interpretations of observed interstellar CO and N$_2$ abundance patterns, including the well-documented CO and N$_2$H$^+$ anti-correlations in disks, protostars and molecular cloud cores. Based on laboratory experiments on pure CO and N$_2$ ice desorption, the difference between CO and N$_2$ desorption energies is small; the N$_2$-to-CO desorption energy ratio is 0.93$\\pm$0.03. Interstellar ices are not pure, however, and in this study we explore the effect of water ice on the desorption energy ratio of the two molecules. We present temperature programmed desorption experiments of different coverages of $^{13}$CO and $^{15}$N$_2$ on porous and compact amorphous water ices and, for reference, of pure ices. In all experiments, $^{15}$N$_2$ desorption begins a few degrees before the onset of $^{13}$CO desorption. The $^{15}$N$_2$ and $^{13}$CO energy barriers are 770 and 866 K for the pure ices, 1034-1143 K and 1155-1298 K for different sub-monolayer co...

  17. Hg Anomalies In Soils- A Geochemical Exploration Method For Geothermal...

    Open Energy Info (EERE)

    Hg Anomalies In Soils- A Geochemical Exploration Method For Geothermal Areas Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: Hg Anomalies In...

  18. IDS120j WITHOUT RESISTIVE MAGNETS MODIFYING Hg MODULE ( UPDATED )

    E-Print Network [OSTI]

    McDonald, Kirk

    Hg POOL. *********************************************************** >SIMULATIONS CODE: mars1512 OVERVIEW (LEFT), POOL REGION DETAILS (RIGHT). [20 cm GAPS] SH#1 SH#1 SH#1A SH#2 SH#1A Hg POOL SH#4 SH#3 Hg POOL SH#1 2 cm THICK STST OUTER TUBE CRYO#1 CRYO#4CRYO#3 CRYO#2 2 cm THICK STST BEAM PIPE BEAM PIPE

  19. Lorentz Symmetry Breaking in $\\mathcal{N} =2$ Superspace

    E-Print Network [OSTI]

    Faizal, Mir

    2015-01-01

    In this paper, we will study the deformation of a three dimensional theory with $\\mathcal{N} =2$ supersymmetry. This theory will be deformed by the presence of a constant vector field. This deformation will break the Lorentz symmetry. So, we will analyse this theory using $\\mathcal{N} =2$ aether superspace. The $\\mathcal{N} =2$ aether superspace will be obtained from a deformation of the usual $\\mathcal{N} =2$ superspace. This will be done by deforming the generators of the three dimensional $\\mathcal{N} =2$ supersymmetry. After analysing this deformed superalgebra, we will derive an explicit expression for the superspace propagators in this deformed superspace. Finally, we will use these propagators for performing perturbative calculations.

  20. Lorentz Symmetry Breaking in $\\mathcal{N} =2$ Superspace

    E-Print Network [OSTI]

    Mir Faizal; Prince A. Ganai

    2015-09-09

    In this paper, we will study the deformation of a three dimensional theory with $\\mathcal{N} =2$ supersymmetry. This theory will be deformed by the presence of a constant vector field. This deformation will break the Lorentz symmetry. So, we will analyse this theory using $\\mathcal{N} =2$ aether superspace. The $\\mathcal{N} =2$ aether superspace will be obtained from a deformation of the usual $\\mathcal{N} =2$ superspace. This will be done by deforming the generators of the three dimensional $\\mathcal{N} =2$ supersymmetry. After analysing this deformed superalgebra, we will derive an explicit expression for the superspace propagators in this deformed superspace. Finally, we will use these propagators for performing perturbative calculations.

  1. ELECTROSTATIC (LANGMUIR) PROBE MEASUREMENTS IN RF DRIVEN He, N2, BCl3, AND BCl3/N2 PLASMAS

    E-Print Network [OSTI]

    Pathak, Bogdan Amaru

    2008-08-01

    of GaAs with nitrogen addition. The system was validated in both helium and nitrogen plasmas. Probe measurements showed that as the nitrogen concentration in BCl3/N2 plasmas increased, the average electron energy actually decreased (5.52 eV @ 0% N2, 4...

  2. On the Provenance of Pluto's Nitrogen (N2)

    E-Print Network [OSTI]

    Singer, Kelsi N

    2015-01-01

    N2 is abundant in Pluto's atmosphere and on its surface, but the supply is depleted by prodigious atmospheric escape. We demonstrate that cometary impacts could not have delivered enough N2 mass to resupply Pluto's atmospheric escape over time; thus Pluto's N2 is likely endogenous, and therefore was either acquired early in its history or created by chemistry inside/on Pluto. We find that cratering could excavate a considerable amount of N2 to resupply the atmosphere against escape if the near-surface N2 reservoir is deep. However, we find that this process likely falls short of that necessary to resupply the atmosphere against escape by at least an order of magnitude. We conclude that either the escape of N2 from Pluto's atmosphere was on average much lower than the predictions for the current epoch, or that internal activity could be necessary to bring N2 to the surface and resupply escape losses. Observations made by the New Horizons spacecraft in mid-2015 will yield further constraints on the provenance a...

  3. Scattering and Thermodynamics of Integrable N=2 Theories

    E-Print Network [OSTI]

    P. Fendley; K. Intriligator

    1992-02-04

    We study $N$=2 supersymmetric integrable theories with spontaneously-broken \\Zn\\ symmetry. They have exact soliton masses given by the affine $SU(n)$ Toda masses and fractional fermion numbers given by multiples of $1/n$. The basic such $N$=2 integrable theory is the $A_n$-type $N$=2 minimal model perturbed by the most relevant operator. The soliton content and exact S-matrices are obtained using the Landau-Ginzburg description. We study the thermodynamics of these theories and calculate the ground-state energies exactly, verifying that they have the correct conformal limits. We conjecture that the soliton content and S-matrices in other integrable \\Zn\\ $N$=2 theories are given by the tensor product of the above basic $N$=2 \\Zn\\ scattering theory with various $N$=0 theories. In particular, we consider integrable perturbations of $N$=2 Kazama-Suzuki models described by generalized Chebyshev potentials, $CP^{n-1}$ sigma models, and $N$=2 sine-Gordon and its affine Toda generalizations.

  4. Atmospheric mercury (Hg) in the Adirondacks: Concentrations and sources

    SciTech Connect (OSTI)

    Hyun-Deok Choi; Thomas M. Holsen; Philip K. Hopke

    2008-08-15

    Hourly averaged gaseous elemental Hg (GEM) concentrations and hourly integrated reactive gaseous Hg (RGM), and particulate Hg (HgP) concentrations in the ambient air were measured at Huntington Forest in the Adirondacks, New York from June 2006 to May 2007. The average concentrations of GEM, RGM, and HgP were 1.4 {+-} 0.4 ng m{sup -3}, 1.8 {+-} 2.2 pg m{sup -3}, and 3.2 {+-} 3.7 pg m{sup -3}, respectively. RGM represents <3.5% of total atmospheric Hg or total gaseous Hg (TGM: GEM + RGM) and HgP represents <3.0% of the total atmospheric Hg. The highest mean concentrations of GEM, RGM, and HgP were measured during winter and summer whereas the lowest mean concentrations were measured during spring and fall. Significant diurnal patterns were apparent in warm seasons for all species whereas diurnal patterns were weak in cold seasons. RGM was better correlated with ozone concentration and temperature in both warm than the other species. Potential source contribution function (PSCF) analysis was applied to identify possible Hg sources. This method identified areas in Pennsylvania, West Virginia, Ohio, Kentucky, Texas, Indiana, and Missouri, which coincided well with sources reported in a 2002 U.S. mercury emissions inventory. 51 refs., 7 figs., 1 tab.

  5. Stress-tensor OPE in N=2 Superconformal Theories

    E-Print Network [OSTI]

    Pedro Liendo; Israel Ramirez; Jihye Seo

    2015-08-31

    We carry out a detailed superspace analysis of the OPE of two N=2 stress-tensor multiplets. Knowledge of the multiplets appearing in the expansion, together with the two-dimensional chiral algebra description of N=2 SCFTs, imply an analytic bound on the central charge c. This bound is valid for any N=2 SCFT regardless of its matter content and flavor symmetries, and is saturated by the simplest Argyres-Douglas fixed point. We also present a partial conformal block analysis for the scalar superconformal primary of the multiplet.

  6. Chiral and real N=2 supersymmetric ?-conformal Galilei algebras

    SciTech Connect (OSTI)

    Aizawa, N. [Department of Mathematics and Information Sciences, Graduate School of Science, Osaka Prefecture University, Nakamozu Campus, Sakai, Osaka 599-8351 (Japan)] [Department of Mathematics and Information Sciences, Graduate School of Science, Osaka Prefecture University, Nakamozu Campus, Sakai, Osaka 599-8351 (Japan); Kuznetsova, Z. [UFABC, Rua Santa Adélia 166, Bangu, cep 09210-170, Santo André, SP (Brazil)] [UFABC, Rua Santa Adélia 166, Bangu, cep 09210-170, Santo André, SP (Brazil); Toppan, F. [CBPF, Rua Dr. Xavier Sigaud 150, Urca, cep 22290-180, Rio de Janeiro, RJ (Brazil)] [CBPF, Rua Dr. Xavier Sigaud 150, Urca, cep 22290-180, Rio de Janeiro, RJ (Brazil)

    2013-09-15

    Inequivalent N=2 supersymmetrizations of the ?-conformal Galilei algebra in d-spatial dimensions are constructed from the chiral (2, 2) and the real (1, 2, 1) basic supermultiplets of the N=2 supersymmetry. For non-negative integer and half-integer ?, both superalgebras admit a consistent truncation with a (different) finite number of generators. The real N=2 case coincides with the superalgebra introduced by Masterov, while the chiral N=2 case is a new superalgebra. We present D-module representations of both superalgebras. Then we investigate the new superalgebra derived from the chiral supermultiplet. It is shown that it admits two types of central extensions, one is found for any d and half-integer ?, and the other only for d= 2 and integer ?. For each central extension, the centrally extended ?-superconformal Galilei algebra is realized in terms of its super-Heisenberg subalgebra generators.

  7. Process of [sup 196]Hg enrichment

    DOE Patents [OSTI]

    Grossman, M.W.; Mellor, C.E.

    1993-04-27

    A simple rate equation model shows that by increasing the length of the photochemical reactor and/or by increasing the photon intensity in said reactor, the feedstock utilization of [sup 196]Hg will be increased. Two preferred embodiments of the present invention are described, namely (1) long reactors using long photochemical lamps and vapor filters; and (2) quartz reactors with external UV reflecting films. These embodiments have each been constructed and operated, demonstrating the enhanced utilization process dictated by the mathematical model (also provided).

  8. Process of .sup.196 Hg enrichment

    DOE Patents [OSTI]

    Grossman, Mark W. (Belmont, MA); Mellor, Charles E. (Salem, MA)

    1993-01-01

    A simple rate equation model shows that by increasing the length of the photochemical reactor and/or by increasing the photon intensity in said reactor, the feedstock utilization of .sup.196 Hg will be increased. Two preferred embodiments of the present invention are described, namely (1) long reactors using long photochemical lamps and vapor filters; and (2) quartz reactors with external UV reflecting films. These embodiments have each been constructed and operated, demonstrating the enhanced utilization process dictated by the mathematical model (also provided).

  9. IDS120j WITHOUT RESISTIVE MAGNETS MODIFYING Hg MODULE

    E-Print Network [OSTI]

    McDonald, Kirk

    OVERVIEW (LEFT), POOL REGION DETAILS (RIGHT). [20 cm GAPS] SH#1 SH#1 SH#1A SH#2 SH#1A Hg POOL SH#4 SH#3 Hg POOL SH#1 2 cm THICK STST OUTER TUBE CRYO#1 CRYO#4CRYO#3 CRYO#2 2 cm THICK STST BEAM PIPE BEAM PIPE EXTENDS HALF WAY UPSTREAM TO THE POOL SH#1 10 cm THICK STST RIGHT FLANGE Hg POOL STARTS ~ 85 cm

  10. U01HG004279 (D.M.M.), U01HG004261 (E.L.), U01HG004274 (S.H.), and U41HG004269 (L.S.). Awards

    E-Print Network [OSTI]

    .T.N.), the Indiana Genomics Initiative (T.C.K.), H. Smith and the NIDDK genomics core laboratory (B.O.), NIH R01HG

  11. A Specific N = 2 Supersymmetric Quantum Mechanical Model: Supervariable Approach

    E-Print Network [OSTI]

    Shukla, Aradhya

    2015-01-01

    By exploiting the supersymmetric invariant restrictions on the chiral and anti-chiral supervariables, we derive the off-shell nilpotent symmetry transformations for a specific (0 + 1)-dimensional N = 2 supersymmetric quantum mechanical model which is considered on a (1, 2)-dimensional supermanifold (parametrized by a bosonic variable t and a pair of Grassmannian variables (\\theta, \\bar\\theta). We also provide the geometrical meaning to the symmetry transformations. Finally, we show that this specific N = 2 SUSY quantum mechanical model is a model for Hodge theory.

  12. CERN Hg Jet System V.B. Graves

    E-Print Network [OSTI]

    McDonald, Kirk

    Delivery System Pump Motor Centrifugal Pump Hg Jet Containment Sump Tank Secondary Containment Target Pump Issues · Pump adds heat to Hg - Pump delivers nominal 51 bhp at 23% efficiency (60 bhp max (30kw) · With an assumed Vol=12liter, T=2.4°F/sec (1.3°C/sec) due to pump heating only · Heat

  13. Growth of superconducting Hg-1212 very-thin films

    E-Print Network [OSTI]

    Wu, Judy; Xie, Y. Y.; Kang, B. W.; Gapud, A. A.; Aytug, T.; Fang, L.

    1999-06-01

    High quality epitaxial HgBa2CaCu2O6+delta (Hg- High 1212) films with thickness less than 100 nm have been successfully synthesized using cation-exchange process. The films show the superconducting transition up to similar to 118 K which is close...

  14. MERIT Hg System Review V.B. Graves

    E-Print Network [OSTI]

    McDonald, Kirk

    in rough vacuum · Full-beam interaction length is 30-cm · Beam line is 120cm above the tunnel floor · Up between the Hg and the tunnel environment · Hydraulic pump will be in adjacent tunnel, personnel in remote/vapor containment - Ports for instruments, Hg fill/drain, hydraulics · Optical diagnostic components - Passive

  15. Elucidate the mechanism(s) of Hg uptake in methylating bacteria and effects on Hg methylation in nature.

    E-Print Network [OSTI]

    Post, Wilfred M.

    Objective · Elucidate the mechanism(s) of Hg uptake in methylating bacteria and effects on Hg, suggesting a possible detoxification mechanism for the formation and export of methylmercury. 1 BER Overview A New Mechanism of Mercury Uptake and Methylation in Anaerobic Bacteria Contact: Jeffra Schaefer

  16. N2O Emissions From 2010 SCR Systems | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    N2O Emissions From 2010 SCR Systems N2O Emissions From 2010 SCR Systems Reviews potential contribution to N2O formation of typical diesel exhaust aftertreatment system based on...

  17. Nonlocality from N>2 independent single-photon emitters

    SciTech Connect (OSTI)

    Thiel, C.; Wiegner, R.; Zanthier, J. von [Institut fuer Optik, Information und Photonik, Universitaet Erlangen-Nuernberg, D-91058 Erlangen (Germany); Agarwal, G. S. [Department of Physics, Oklahoma State University, Stillwater, Oklahoma 74078-3072 (United States)

    2010-09-15

    We demonstrate that intensity correlations of second order in the fluorescence light of N>2 single-photon emitters may violate locality while the visibility of the signal remains below 1/{radical}(2){approx_equal}71%. For this, we derive a homogeneous Bell-Wigner-type inequality, which can be applied to a broad class of experimental setups. We trace the violation of this inequality back to path entanglement created by the process of detection.

  18. Photodesorption of ices I: CO, N2 and CO2

    E-Print Network [OSTI]

    Karin I. Oberg; Ewine F. van Dishoeck; Harold Linnartz

    2009-01-23

    A longstanding problem in astrochemistry is how molecules can be maintained in the gas phase in dense inter- and circumstellar regions. Photodesorption is a non-thermal desorption mechanism, which may explain the small amounts of observed cold gas in cloud cores and disk mid-planes. This paper aims to determine the UV photodesorption yields and to constrain the photodesorption mechanisms of three astrochemically relevant ices: CO, N2 and CO2. In addition, the possibility of co-desorption in mixed and layered CO:N2 ices is explored. The ice photodesorption is studied experimentally under ultra high vacuum conditions and at 15-60 K using a hydrogen discharge lamp (7-10.5 eV). The ice desorption during irradiation is monitored by reflection absorption infrared spectroscopy of the ice and simultaneous mass spectrometry of the desorbed molecules. Both the UV photodesorption yields per incident photon and the photodesorption mechanisms are molecule specific. CO photodesorbs without dissociation from the surface layer of the ice. N2, which lacks an electronic transition in this wavelength range, has a photodesorption yield that is more than an order of magnitude lower. This yield increases significantly due to co-desorption when N2 is mixed in with or layered on top of CO ice. CO2 photodesorbs through dissociation and subsequent recombination from the top 10 layers of the ice. At low temperatures (15-18 K) the derived photodesorption yields are 2.7x10^-3 and CO2 photodesorption yield is 1.2x10^-3x(1-e^(-X/2.9)) + 1.1x10^-3x(1-e^(-X/4.6)) molecules photon-1, where X is the ice thickness in monolayers and the two parts of the expression represent a CO2 and CO photodesorption pathway.

  19. N=2 supersymmetric gauge theories and quantum integrable systems

    E-Print Network [OSTI]

    Yuan Luo; Meng-Chwan Tan; Junya Yagi

    2014-04-01

    We study N=2 supersymmetric gauge theories on the product of a two-sphere and a cylinder. We show that the low-energy dynamics of a BPS sector of such a theory is described by a quantum integrable system, with the Planck constant set by the inverse of the radius of the sphere. If the sphere is replaced with a hemisphere, then our system reduces to an integrable system of the type studied by Nekrasov and Shatashvili. In this case we establish a correspondence between the effective prepotential of the gauge theory and the Yang-Yang function of the integrable system.

  20. Exact results on N=2 supersymmetric gauge theories

    E-Print Network [OSTI]

    Jörg Teschner

    2015-03-10

    This is the introduction to the collection of review articles "Exact results on N=2 supersymmetric gauge theories". The first three sections are intended to give a general overview over the physical motivations behind this direction of research, and some of the developments that initiated this project. These sections are written for a broad audience of readers with interest in quantum field theory, assuming only very basic knowledge of supersymmetric gauge theories and string theory. This will be followed by a brief overview over the different chapters collected in this volume, while the last section indicates some related developments that we were unfortunately not able to cover.

  1. Purification of HgI.sub.2 for nuclear detector fabrication

    DOE Patents [OSTI]

    Schieber, Michael M. (Goleta, CA)

    1978-01-01

    A process for purification of mercuric iodide (HgI.sub.2) to be used as a source material for the growth of detector quality crystals. The high purity HgI.sub.2 raw material is produced by a combination of three stages: synthesis of HgI.sub.2 from Hg and I.sub.2, repeated sublimation, and zone refining.

  2. Pure N=2 Super Yang-Mills and Exact WKB

    E-Print Network [OSTI]

    Amir-Kian Kashani-Poor; Jan Troost

    2015-04-30

    We apply exact WKB methods to the study of the partition function of pure N=2 epsilon_i-deformed gauge theory in four dimensions in the context of the 2d/4d correspondence. We study the partition function at leading order in epsilon_2/epsilon_1 (i.e. at large central charge) and in an expansion in epsilon_1. We find corrections of the form ~ exp[- SW periods / epsilon_1] to this expansion. We attribute these to the exchange of the order of summation over gauge instanton number and over powers of epsilon_1 when passing from the Nekrasov form of the partition function to the topological string theory inspired form. We conjecture that such corrections should be computable from a worldsheet perspective on the partition function. Our results follow upon the determination of the Stokes graphs associated to the Mathieu equation with complex parameters and the application of exact WKB techniques to compute the Mathieu characteristic exponent.

  3. Pure N=2 Super Yang-Mills and Exact WKB

    E-Print Network [OSTI]

    Kashani-Poor, Amir-Kian

    2015-01-01

    We apply exact WKB methods to the study of the partition function of pure N=2 epsilon_i-deformed gauge theory in four dimensions in the context of the 2d/4d correspondence. We study the partition function at leading order in epsilon_2/epsilon_1 (i.e. at large central charge) and in an expansion in epsilon_1. We find corrections of the form ~ exp[- SW periods / epsilon_1] to this expansion. We attribute these to the exchange of the order of summation over gauge instanton number and over powers of epsilon_1 when passing from the Nekrasov form of the partition function to the topological string theory inspired form. We conjecture that such corrections should be computable from a worldsheet perspective on the partition function. Our results follow upon the determination of the Stokes graphs associated to the Mathieu equation with complex parameters and the application of exact WKB techniques to compute the Mathieu characteristic exponent.

  4. Spectroscopic variability and magnetic fields of HgMn stars

    E-Print Network [OSTI]

    Hubrig, S; Ilyin, I; Korhonen, H; Savanov, I S; Dall, T; Schoeller, M; Cowley, C R; Briquet, M; Arlt, R

    2011-01-01

    The discovery of exotic abundances, chemical inhomogeneities, and weak magnetic fields on the surface of late B-type primaries in spectroscopic binaries has important implications not only for our understanding of the formation mechanisms of stars with Hg and Mn peculiarities themselves, but also for the general understanding of B-type star formation in binary systems. The origin of the abundance anomalies observed in late B-type stars with HgMn peculiarity is still poorly understood. The connection between HgMn peculiarity and membership in binary and multiple systems is supported by our observations during the last decade. The important result achieved in our studies of a large sample of HgMn stars is the finding that most HgMn stars exhibit spectral variability of various chemical elements, proving that the presence of an inhomogeneous distribution on the surface of these stars is a rather common characteristic and not a rare phenomenon. Further, in the studied systems, we found that all components are che...

  5. Active transport, substrate specificity, and methylation of Hg(II) in anaerobic bacteria

    SciTech Connect (OSTI)

    Schasfer, Jeffra [Princeton University; Rocks, Sara [Princeton University; Zheng, Wang [ORNL; Liang, Liyuan [ORNL; Gu, Baohua [ORNL; Morel, Francois M [ORNL

    2011-01-01

    The formation of methylmercury (MeHg), which is biomagnified in aquatic food chains and poses a risk to human health, is effected by some iron- and sulfate-reducing bacteria (FeRB and SRB) in anaerobic environments. However, very little is known regarding the mechanism of uptake of inorganic Hg by these organisms, in part because of the inherent difficulty in measuring the intracellular Hg concentration. By using the FeRB Geobacter sulfurreducens and the SRB Desulfovibrio desulfuricans ND132 as model organisms, we demonstrate that Hg(II) uptake occurs by active transport. We also establish that Hg(II) uptake by G. sulfurreducens is highly dependent on the characteristics of the thiols that bind Hg(II) in the external medium, with some thiols promoting uptake and methylation and others inhibiting both. The Hg(II) uptake system of D. desulfuricans has a higher affinity than that of G. sulfurreducens and promotes Hg methylation in the presence of stronger complexing thiols. We observed a tight coupling between Hg methylation and MeHg export from the cell, suggesting that these two processes may serve to avoid the build up and toxicity of cellular Hg. Our results bring up the question of whether cellular Hg uptake is specific for Hg(II) or accidental, occurring via some essential metal importer. Our data also point at Hg(II) complexation by thiols as an important factor controlling Hg methylation in anaerobic environments.

  6. HgMn Stars as apparent X-ray emitters

    E-Print Network [OSTI]

    Hubrig, S; Mathys, G

    1998-01-01

    In the ROSAT all-sky survey 11 HgMn stars were detected as soft X-ray emitters (Berghoefer, Schmitt & Cassinelli 1996). Prior to ROSAT, X-ray observations with the Einstein Observatory had suggested that stars in the spectral range B5-A7 are devoid of X-ray emission. Since there is no X-ray emitting mechanism available for these stars (also not for HgMn stars), the usual argument in the case of an X-ray detected star of this spectral type is the existence of an unseen low-mass companion which is responsible for the X-ray emission. The purpose of the present work is to use all available data for our sample of X-ray detected HgMn stars and conclude on the nature of possible companions.

  7. Can N 2 O stable isotopes and isotopomers be useful tools to characterize sources and microbial pathways of N 2 O production and consumption in tropical soils?

    E-Print Network [OSTI]

    2011-01-01

    in Microbial Production and Consumption of Green- housesoil denitrification: Production and consumption of nitrouspathways of N 2 O production and consumption in tropical

  8. Selective Catalytic Oxidation (SCO) of NH3 to N2 for Hot Exhaust...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Oxidation (SCO) of NH3 to N2 for Hot Exhaust Treatment Selective Catalytic Oxidation (SCO) of NH3 to N2 for Hot Exhaust Treatment Investigation of a series of transition metal...

  9. O_3-N_2O correlations from the Atmospheric Chemistry Experiment

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    O_3-N_2O correlations from the Atmospheric Chemistry Experiment: revisiting a diagnostic. (2007) O_3-N_2O correlations from the Atmospheric Chemistry Experiment: revisiting a diagnostic outputs online #12;O3-N2O correlations from the Atmospheric Chemistry Experiment: Revisiting a diagnostic

  10. Global distribution of N2O emissions from aquatic systems: natural emissions and anthropogenic eects

    E-Print Network [OSTI]

    Seitzinger, Sybil

    Global distribution of N2O emissions from aquatic systems: natural emissions and anthropogenic, are increasing due to human activities. Our analysis suggests that a third of global anthropogenic N2O emission the remainder. Over 80% of aquatic anthropogenic N2O emissions are from the Northern Hemisphere mid

  11. Structure and critical function of Fe and acid sites in Fe-ZSM-5 in propane oxidative dehydrogenation with N2O and N2O decomposition

    E-Print Network [OSTI]

    Sklenak, Stepan

    Structure and critical function of Fe and acid sites in Fe-ZSM-5 in propane oxidative species Steamed Fe-zeolites Mössbauer spectroscopy UV­Vis FTIR H2-TPR N2O decomposition Propane oxidative of propane to propene with N2O. The evacuated non-steamed FeH-ZSM-5 contained high concentration of Brønsted

  12. Experimental study of 199Hg spin anti-relaxation coatings

    E-Print Network [OSTI]

    Z. Chowdhuri; M. Fertl; M. Horras; K. Kirch; J. Krempel; B. Lauss; A. Mtchedlishvili; D. Rebreyend; S. Roccia; P. Schmidt-Wellenburg; G. Zsigmond

    2013-09-04

    We report on a comparison of spin relaxation rates in a $^{199}$Hg magnetometer using different wall coatings. A compact mercury magnetometer was built for this purpose. Glass cells coated with fluorinated materials show longer spin coherence times than if coated with their hydrogenated homologues. The longest spin relaxation time of the mercury vapor was measured with a fluorinated paraffin wall coating.

  13. The new Hg-rich barium indium mercurides BaIn{sub x}Hg{sub 7?x} (x=3.1) and BaIn{sub x}Hg{sub 11?x} (x=0–2.8)

    SciTech Connect (OSTI)

    Wendorff, Marco; Schwarz, Michael; Röhr, Caroline

    2013-07-15

    The title compounds BaIn{sub x}Hg{sub 7?x} (x=3.1(1)) and BaIn{sub x}Hg{sub 11?x} (x=0–2.8) were synthesized from stoichiometric ratios of the elements in Ta crucibles. Their crystal structures have been determined using single crystal X-ray data. BaIn{sub x}Hg{sub 7?x} (x=3.1(1)) crystallizes in a new structure type (orthorhombic, oC16, space group Cmmm: a=512.02(1), b=1227.68(3), c=668.61(2) pm, Z=2, R1=0.0311). In the structure, the atoms of the three crystallographically different mixed In/Hg positions form planar nets of four-, six- and eight-membered rings. These nets are shifted against each other such that the four-membered rings form empty distorted cubes. The cubes are connected via common edges, corners and folded ladders, which are also found in BaIn{sub 2}/BaHg{sub 2} (KHg{sub 2} structure type) and BaIn (?-NaHg type). The Ba atoms are centered in the eight-membered rings and exhibit an overall coordination number of 20. The [BaM{sub 20}] polyhedra and twice as many distorted [M{sub 8}] cubes tesselate the space. BaIn{sub 2.8}Hg{sub 8.2} (cubic, cP36, space group Pm3{sup ¯}m, a=961.83(1) pm, Z=3, R1=0.0243) is the border compound of the phase width BaIn{sub x}Hg{sub 11?x} of the rare BaHg{sub 11} structure type. In the structure, ideal [M{sub 8}] cubes (at the corners of the unit cell) and BaM{sub 20} polyhedra (at the edges of the unit cell) represent the building blocks comparable to the other new In mercuride. In accordance with the increased In/Hg content, additional M-pure regions appear: the center of the unit cell contains a huge [Hg(1)M(2){sub 12}M(3,4){sub 32}] polyhedron, a Hg-centered cuboctahedron of In/Hg atoms surrounded by a capped cantellated cube of 32 additional M atoms. For both structure types, the bonding situation and the ‘coloring’, i.e. the In/Hg distribution of the polyanionic network, are discussed considering the different sizes of the atoms and the charge distribution (Bader AIM charges), which have been calculated within the framework of FP-LAPW density functional theory. - Graphical abstract: BaIn{sub 2.6}Hg{sub 4.4}: distorted cubes [(In/Hg){sub 8}] (green, like in BaHg{sub 11}), folded ladders (violet, like in BaIn, BaHg{sub 2} and BaIn{sub 2}) and Ba coordination polyhedra [Ba(In/Hg){sub 20}] (blue, like in BaHg{sub 11}). - Highlights: • The Hg-rich In-mercuride BaIn{sub 3.1}Hg{sub 3.9} crystallizes with a singular structure type. • The phase width of the BaHg{sub 11} structure in BaIn{sub x}Hg{sub 11-x} ends at x=2.8. • The relations of both compounds with other alkaline-earth mercurides are outlined. • The Hg/In coloring of the polyanion is discussed considering the structure features. • Bonding aspects are explored using band structure calculations.

  14. IDS120hm GEOMETRY WITH MODIFIED Hg POOL VESSEL SIMULATIONS FOR 60% W + 40% He SHIELDING WITHOUT/WITH

    E-Print Network [OSTI]

    McDonald, Kirk

    IDS120hm GEOMETRY WITH MODIFIED Hg POOL VESSEL SIMULATIONS FOR 60% W + 40% He SHIELDING WITHOUT: (m IS FOR) modified Hg pool vessel IN IDS120h. # WITHOUT AND WITH Hg IN THE POOL SIMULATIONS Hg POOL VESSEL AND SHIFTED Be WIDOW FROM 600 cm (0.6 cm THICK) TO 300 cm (1 cm THICK). MODIFIED Hg

  15. nTOF11 Hg System Design Tony Gabriel, Phil Spampinato

    E-Print Network [OSTI]

    McDonald, Kirk

    delivery system size reduction - Target cart design optimization - Magnet base support #12;6 OAK RIDGE of Hg system using jackbolts · Hg system fixed to top plate, final position locked using nut/bolt #12

  16. IDS120j WITHOUT RESISTIVE MAGNETS INTRODUCING A DOUBLE WALL Hg POOL VESSSELAND Be WINDOW.

    E-Print Network [OSTI]

    McDonald, Kirk

    IDS120j WITHOUT RESISTIVE MAGNETS INTRODUCING A DOUBLE WALL Hg POOL VESSSELAND Be WINDOW. SC#4 STUDIES FOR 20 cm GAPS SIZE FOR STST IN THE PLACE OF RESISTIVE MAGNETS AND REST OF VOLUME IN Hg POOL SHIELDING IN THE PLACE OF RESISTIVE MAGNETS AND IN THE REST OF VOLUME IN THE Hg POOL VESSEL

  17. Anthropogenic and Natural Emissions of Mercury (Hg) in the northeastern United Jeffrey MacAdam Sigler

    E-Print Network [OSTI]

    Lee, Xuhui

    Abstract Anthropogenic and Natural Emissions of Mercury (Hg) in the northeastern United States impact may depend on the emission rate. Anthropogenic Hg emissions in the United States are poorly characterized. Natural Hg emissions are poorly understood worldwide, due to lack of data or measurement systems

  18. A Free Jet Hg Target Operating in a High Magnetic Field Intersecting

    E-Print Network [OSTI]

    McDonald, Kirk

    , 2005) Sect. A-A Hg Supply Tube Nozzle Solenoid Bore A A Fiber Optic Bundle Hydraulic Fluid Lines Vacuum · Hydraulically-actuated piston pump delivers Hg to the nozzle · Hg cylinder 25-cm (10-inch) bore, 38-cm (15-inch

  19. The development of N2S2 metal complexes as bidentate ligands for organometallic chemistry 

    E-Print Network [OSTI]

    Rampersad, Marilyn Vena

    2007-04-25

    from CO addition to (NiN2S2)W(CO)4, which is in equilibrium with the resulting (NiN2S2)W(CO)5 species (Keq = 2.8 M-1, G = -1.4 kJ/mole at 50C). Complete NiN2S2 ligand displacement by CO-cleavage of the remaining W-S bond to form W(CO)6 was not observed...

  20. Synthesis and growth of HgI{sub 2} nanocrystals in a glass matrix: Heat treatment

    SciTech Connect (OSTI)

    Condeles, J. F. E-mail: ricssilva@yahoo.com.br; Silva, R. S. E-mail: ricssilva@yahoo.com.br; Silva, A. C. A.; Dantas, N. O.

    2014-08-14

    Mercury iodide (HgI{sub 2}) nanocrystals (NCs) were successfully grown in a barium phosphate glass matrix synthesized by fusion. Growth control of HgI{sub 2} NCs was investigated by Atomic Force Microscopy (AFM), Optical Absorption (OA), Fluorescence (FL), and X-ray diffraction (XRD). AFM images reveal the formation of HgI{sub 2} nanocrystals in host glass matrix. HgI{sub 2} NCs growth was evidenced by an OA and FL band red-shift with increasing annealing time. XRD measurements revealed the ? crystalline phase of the HgI{sub 2} nanocrystals.

  1. SSC v s . Hg at 0 -150,000 c fs SSC vs. Hg at 150,000 -370,000 cfs

    E-Print Network [OSTI]

    SSC v s . Hg at 0 - 150,000 c fs SSC vs. Hg at 150,000 - 370,000 cfs 0 20 40 60 80 0 20 40 60 80 0 (cfs) (Figure 1 ). The Bypass serves as flood protection for the City of Sacramento and conveys

  2. N2 DISSOCIATION IN THE MESOSPHERE DUE TO SECONDARY ELECTRONS DURING A SOLAR

    E-Print Network [OSTI]

    Ulich, Thomas

    N2 DISSOCIATION IN THE MESOSPHERE DUE TO SECONDARY ELECTRONS DURING A SOLAR PROTON EVENT, ionization processes produce secondary electrons that, if possessing 9.76 eV or more energy, dissociate N2 to secondary electrons dur- ing a solar proton event. Further, we have studied the effect on atomic nitrogen

  3. Extended BRS and anti-BRS symmetries in N=2 harmonic superspace

    SciTech Connect (OSTI)

    Lhallabi, T.; Saidi, E.H. (L.P.T., av. Ibn Battouta, Rabat (MA))

    1988-01-01

    The full set of extended BRS and anti-BRS symmetries are derived for components of superconnection and gauge superfield using the N = 2 harmonic superspace. The quantization of N = 2 supersymmetric theory is developed and the proof of its gauge invariance is presented.

  4. Apparatus for growing HgI.sub.2 crystals

    DOE Patents [OSTI]

    Schieber, Michael M. (Jerusalem, IL); Beinglass, Israel (Jerusalem, IL); Dishon, Giora (Jerusalem, IL)

    1978-01-01

    A method and horizontal furnace for vapor phase growth of HgI.sub.2 crystals which utilizes controlled axial and radial airflow to maintain the desired temperature gradients. The ampoule containing the source material is rotated while axial and radial air tubes are moved in opposite directions during crystal growth to maintain a desired distance and associated temperature gradient with respect to the growing crystal, whereby the crystal interface can advance in all directions, i.e., radial and axial according to the crystallographic structure of the crystal. Crystals grown by this method are particularly applicable for use as room-temperature nuclear radiation detectors.

  5. Multiparameter statistical models from $N^2\\times N^2$ braid matrices: Explicit eigenvalues of transfer matrices ${\\bf T}^{(r)}$, spin chains, factorizable scatterings for all $N$

    E-Print Network [OSTI]

    B. Abdesselam; A. Chakrabarti

    2008-07-02

    For a class of multiparameter statistical models based on $N^2\\times N^2$ braid matrices the eigenvalues of the transfer matrix ${\\bf T}^{(r)}$ are obtained explicitly for all $(r,N)$. Our formalism yields them as solutions of sets of linear equations with simple constant coefficients. The role of zero-sum multiplets constituted in terms of roots of unity is pointed out and their origin is traced to circular permutations of the indices in the tensor products of basis states induced by our class of ${\\bf T}^{(r)}$ matrices. The role of free parameters, increasing as $N^2$ with $N$, is emphasized throughout. Spin chain Hamiltonians are constructed and studied for all $N$. Inverse Cayley transforms of Yang-Baxter matrices corresponding to our braid matrices are obtained for all $N$. They provide potentials for factorizable $S$-matrices. Main results are summarized and perspectives are indicated in the concluding remarks.

  6. Analytical Formulas of Molecular Ion Abundances and N2H+ Ring in Protoplanetary Disks

    E-Print Network [OSTI]

    Aikawa, Yuri; Nomura, Hideko; Qi, Chunhua

    2015-01-01

    We investigate the chemistry of ion molecules in protoplanetary disks, motivated by the detection of N$_2$H$^+$ ring around TW Hya. While the ring inner radius coincides with the CO snow line, it is not apparent why N$_2$H$^+$ is abundant outside the CO snow line in spite of the similar sublimation temperatures of CO and N$_2$. Using the full gas-grain network model, we reproduced the N$_2$H$^+$ ring in a disk model with millimeter grains. The chemical conversion of CO and N$_2$ to less volatile species (sink effect hereinafter) is found to affect the N$_2$H$^+$ distribution. Since the efficiency of the sink depends on various parameters such as activation barriers of grain surface reactions, which are not well constrained, we also constructed the no-sink model; the total (gas and ice) CO and N$_2$ abundances are set constant, and their gaseous abundances are given by the balance between adsorption and desorption. Abundances of molecular ions in the no-sink model are calculated by analytical formulas, which a...

  7. The inverse conductivity problem with power densities in dimension n2

    E-Print Network [OSTI]

    François Monard, Guillaume Bal

    2012-06-19

    Jun 19, 2012 ... The model: X ? Rn bounded domain, n ? 2. ? · (??u) ? ? .... A first-order quasi-linear system is then derived for the frame S. ?Si = HkqHjp( ...

  8. Topics in 3D N=2 AdS supergravity in superspace

    E-Print Network [OSTI]

    Gabriele Tartaglino-Mazzucchelli

    2012-02-01

    We review some recent results on the construction in superspace of 3D N=2 AdS supergravities and on the formulation of rigid supersymmetric theories in (1,1) and (2,0) AdS superspaces.

  9. Elastic stability and electronic structure of pyrite type PtN2: Ahard semiconductor

    SciTech Connect (OSTI)

    Yu, Rong; Zhan, Qian; Zhang, Xiao-Feng

    2006-08-29

    The elastic properties and electronic structure of PtN2 withthe pyrite structure (PtN2(C2)) were studied with first-principlescalculations. The crystal structure is demonstrated to be elasticallystable with a lower energy than the metastable fluorite structureproposed before. The calculated shear modulus of 214 GPa suggests thatPtN2(C2) is harder than some well known hard materials such as TiN andSiC. The high elastic moduli are attributed to a stacking ofcorner-shared PtN6 octahedra bonded by strong N-N covalent bonding. Incontrast to the metallic fluorite-type phase, PtN2(C2) is semiconductingwith an indirect band gap.

  10. Classical M-Fivebrane Dynamics and Quantum N=2 Yang-Mills

    E-Print Network [OSTI]

    P. S. Howe; N. D. Lambert; P. C. West

    1997-11-05

    We obtain the complete quantum Seiberg-Witten effective action for N=2 supersymmetric SU(N) Yang-Mills theory from the classical M-fivebrane equations of motion with N threebranes moving in its worldvolume.

  11. D-module Representations of N=2,4,8 Superconformal Algebras and Their Superconformal Mechanics

    E-Print Network [OSTI]

    Zhanna Kuznetsova; Francesco Toppan

    2011-12-05

    The linear (homogeneous and inhomogeneous) (k, N, N-k) supermultiplets of the N-extended one-dimensional Supersymmetry Algebra induce D-module representations for the N=2,4,8 superconformal algebras. For N=2, the D-module representations of the A(1,0) superalgebra are obtained. For N=4 and scaling dimension \\lambda=0, the D-module representations of the A(1,1) superalgebra are obtained. For $\\lambda\

  12. D-module Representations of N=2,4,8 Superconformal Algebras and Their Superconformal Mechanics

    E-Print Network [OSTI]

    Kuznetsova, Zhanna

    2011-01-01

    The linear (homogeneous and inhomogeneous) (k, N, N-k) supermultiplets of the N-extended one-dimensional Supersymmetry Algebra induce D-module representations for the N=2,4,8 superconformal algebras. For N=2, the D-module representations of the A(1,0) superalgebra are obtained. For N=4 and scaling dimension \\lambda=0, the D-module representations of the A(1,1) superalgebra are obtained. For $\\lambda\

  13. Hybrid r-Vacua in N=2 Supersymmetric QCD: Universal Condensate Formula

    E-Print Network [OSTI]

    M. Shifman; A. Yung

    2013-03-06

    We derive an exact unified formula for all condensates (quark and monopole) in the hybrid r vacua in N=2 supersymmetric QCD slightly deformed by a \\mu A^2 term. The gauge group is assumed to be U(N) and the number of the quark flavors N_f subject to the condition Nhybrid r vacua in \\mu-deformed N=2 SQCD (the small-\\mu limit).

  14. Author's personal copy Wading bird guano contributes to Hg accumulation in tree island soils

    E-Print Network [OSTI]

    Ma, Lena

    . The mean Hg concentration in surface soils of ghost tree islands was low and similar to marsh soil. For live tree islands, Hg concentrations in the surface head region were considerably greater than those Everglades typically consists of head, middle and tail re- gions (Mason and Valk, 2002). The head is the most

  15. Nested reactor chamber and operation for Hg-196 isotope separation process

    DOE Patents [OSTI]

    Grossman, M.W.

    1991-10-08

    The present invention is directed to an apparatus for use in [sup 196]Hg separation and its method of operation. Specifically, the present invention is directed to a nested reactor chamber useful for [sup 196]Hg isotope separation reactions avoiding the photon starved condition commonly encountered in coaxial reactor systems. 6 figures.

  16. IDS120j WITHOUT RESISTIVE MAGNETS MODIFYING Hg MODULE ( NEW SH#1 REGION )

    E-Print Network [OSTI]

    McDonald, Kirk

    CRYO#1 WAS DECIDED DURING 11 / 15 / 2012 TARGET MEETING AND AN EXTENSION OF THE Hg POOL UPSTREAM UP cm. # RESULTS FROM SIMULATIONS WITH MODIFIED Hg POOL AND SH#1 REGION ( SC#1+2, SC#4 SEGMENTATION;IDS120j: GENERAL OVERVIEW (LEFT), POOL REGION DETAILS (RIGHT). [20 cm GAPS] SH#1 SH#1 SH#1A SH#2 SH#1A

  17. Disentangling the nuclear shape coexistence in even-even Hg isotopes using the interacting boson model

    E-Print Network [OSTI]

    J. E. García-Ramos; K. Heyde

    2014-10-10

    We intend to provide a consistent description of the even-even Hg isotopes, 172-200Hg, using the interacting boson model including configuration mixing. We pay special attention to the description of the shape of the nuclei and to its connection with the shape coexistence phenomenon.

  18. INELASTIC NEUTRON SCATTERING SELECTION RULES OF 03B1 HgI2 M. SIESKIND

    E-Print Network [OSTI]

    Boyer, Edmond

    899 INELASTIC NEUTRON SCATTERING SELECTION RULES OF 03B1 HgI2 M. SIESKIND Laboratoire de The inelastic neutron scattering selection rules of 03B1 HgI2 in the directions 0394, 03A3 and 039B are derived Abstracts 63.20D Introduction. - Inelastic neutron scattering is a powerful technique for the determination

  19. N2 and CO2 vibrational modes in solid nitrogen under pressure M. D. McCluskeya)

    E-Print Network [OSTI]

    McCluskey, Matthew

    . For CO2 concentrations of 0.1%, phase separation is present at low pressures, but is suppressed for pressures greater than 1 GPa. In summary, these studies have contributed to the knowledge of the N2 phase on N2 under hydrostatic pressure. These studies contribute to the knowledge of the N2 phase diagram

  20. Gauge/Gravity Duality, Green Functions of N=2 SYM and Radial/Energy-Scale Relation

    E-Print Network [OSTI]

    Xiao-Jun Wang; Seng Hu

    2002-07-19

    We consider supergravity configuration of D5 branes wrapped on supersymmetric 2-cycles and use it to calculate one-point and two-point Green functions of some special operators in N=2 super Yang-Mills theory. We show that Green functions obtained from supergravity include two very different parts. One of them corresponds to perturbative results of quantum field theory, and another is a non-perturbative effect which corresponds to contribution from instantons with fractional charge. Comparing Green functions obtained from supergravity and gauge theory, we obtain radial/energy-scale relation for this gauge/gravity correspondence with N=2 supersymmetry. This relation leads right beta-function of N=2 SYM from supergravity configuration.

  1. Supersymmetric extension of the nine-dimensional continuation of the Euler density with N=2

    E-Print Network [OSTI]

    Mokhtar Hassaine; Rodrigo Olea; Ricardo Troncoso

    2004-08-26

    A local supersymmetric extension with N=2 of the dimensional continuation of the Euler-Gauss-Bonnet density from eight to nine dimensions is constructed. The gravitational sector is invariant under local Poincare translations, and the full field content is given by the vielbein, the spin connection, a complex gravitino, and an Abelian one-form. The local symmetry group is shown to be super Poincare with N=2 and a U(1) central extension, and the full supersymmetric Lagrangian can be written as a Chern-Simons form.

  2. Photochemistry of HgBr2 in methanol investigated using time-resolved X-ray liquidography

    E-Print Network [OSTI]

    Ihee, Hyotcherl

    , the photodissociation of HgX2 in the gas phase has been the subject of many spectroscopic and theoretical studies-body dissociation of HgI2 - HgI + I along reaction coordinates consisting of two vibrational modes.16,17 Moreover with the potential applications in blue-green laser system.22,23 Photodissociation of HgX2 induces the formation

  3. IDS120j: NO RESISTIVE MAGNETS / NEW Hg MODULE AZIMUTHAL DEPOSITED POWER STUDIES FOR SC#10-SC#12

    E-Print Network [OSTI]

    McDonald, Kirk

    SECTIONS WITH DETAILS OF Hg POOL MODULE FROM VAN GRAVE'S PRESENTATION ( 8 / 9 / 2012 ). THE DESIGN REQUIRES A 2.5 cm ! GAP BETWEEN SH#1 INNER VESSEL AND Hg POOL MODULE OUTER VESSEL. AN EVEN LARGER SPACE APPEARS TO BE BETWEEN INNER AND OUTER VESSEL OF THE Hg POOL MODULE FOR THE FLOW OF He GAS FOR COOLING THE POOL

  4. IDS120j WITHOUT RESISTIVE MAGNETS: NEW Hg MODULE mars1510: OFF VS. ON LAQGSM MODE SIMULATIONS

    E-Print Network [OSTI]

    McDonald, Kirk

    5E4 EVENTS ] #12;3 IDS120j: yz CROSS SECTIONS WITH DETAILS OF Hg POOL MODULE FROM VAN GRAVE'S PRESENTATION ( 8 / 9 / 2012 ). THE DESIGN REQUIRES A 2.5 cm ! GAP BETWEEN SH#1 INNER VESSEL AND Hg POOL MODULE OUTER VESSEL. AN EVEN LARGER SPACE APPEARS TO BE BETWEEN INNER AND OUTER VESSEL OF THE Hg POOL MODULE

  5. IDS120h GEOMETRY WITH MODIFIED Hg POOL VESSEL SIMULATIONS FOR 60% W + 40% He SHIELDING (P12 'POINT') WITH

    E-Print Network [OSTI]

    McDonald, Kirk

    IDS120h GEOMETRY WITH MODIFIED Hg POOL VESSEL SIMULATIONS FOR 60% W + 40% He SHIELDING (P12 'POINT POWER DISTRIBUTION. Nicholas Souchlas, PBL (1/24/2012) 1 #12;IDS120hm: (m IS FOR) modified Hg pool 'POINT'). >GAUSSIAN PROFILE: x = y = 0.12 cm. 2 #12;3 IDS120hm GEOMETRY = IDS120h WITH MODIFIED Hg POOL

  6. Growth of HgTe Quantum Wells for IR to THz Detectors S. DVORETSKY,1,3

    E-Print Network [OSTI]

    Ganichev, Sergey

    on this research, high-quality (013)-grown HgTe QW structures can be used for all-electric detection of radiation. Detection was demon- strated for various low-power continuous-wave (CW) lasers and high-power THz pulsed laser systems. Key words: Growth, HgTe, HgCdTe, quantum wells (QWs), ellipsometric parameters, MBE, far

  7. H-2(p,n)2p Spin Transfer from 305 to 788 Mev 

    E-Print Network [OSTI]

    McNaughton, M. W.; Koch, K.; Supek, I.; Tanaka, N.; Ambrose, DA; Coffey, P.; Johnston, K.; McNaughton, K. H.; Riley, P. J.; Glass, G.; Hiebert, John C.; Northcliffe, L. C.; Simon, A. J.; Mercer, D. J.; Adams, D. L.; Spinka, H.; Jeppersen, R. H.; Tripard, G. E.; Woolverton, H.

    1992-01-01

    Measurements of the spin-transfer parameter K(LL) for H-2(p, n)2p at 0-degrees to calibrate the neutron-beam polarization clarify a normalization discrepancy affecting np data at LAMPF. The new data are in good agreement with theoretical predictions....

  8. Enhancement of CO2/N2 selectivity in a metal-organic framework by cavity modification

    E-Print Network [OSTI]

    are a strong motivation to reduce CO2 emissions from industrial processes. Burning of fossil fuel to generate electricity is a major source of CO2 in the atmosphere, but the capture and sequestration of CO2 from flue gasEnhancement of CO2/N2 selectivity in a metal-organic framework by cavity modification Youn-Sang Bae

  9. THE RADIO NUMBERS OF ALL GRAPHS OF ORDER n AND DIAMETER n -2

    E-Print Network [OSTI]

    Tomova, Maggy

    THE RADIO NUMBERS OF ALL GRAPHS OF ORDER n AND DIAMETER n - 2 KATHERINE BENSON, MATTHEW PORTER, AND MAGGY TOMOVA Abstract. A radio labeling of a connected graph G is a function c : V (G) Z+ such that for every two distinct vertices u and v of G distance(u, v) + |c(u) - c(v)| 1 + diameter(G). The radio

  10. Shock-Tube Study of Methane Ignition with NO2 and N2

    E-Print Network [OSTI]

    Pemelton, John

    2012-10-19

    . The experimental pressure range was 1 - 44 atm and the temperature range tested was 1177 – 2095 K. The additives NO2 and N2O were added in concentrations from 831 ppm to 3539 ppm. The results of the mixtures with NO2 have a reduction in ignition delay time across...

  11. Sminaire du Groupe N2IS Manipulation of chemicals in droplet-based microfluidics

    E-Print Network [OSTI]

    Ingrand, François

    Séminaire du Groupe N2IS Manipulation of chemicals in droplet-based microfluidics Le 06 Septembre TOULOUSE Cedex 4 Résumé Droplet-based microfluidics has a tremendous potential for the miniaturization of chemicals in microfluidic systems is therefore a key to reliably downscale the assays from microtiter plates

  12. Shape coexistence in {sup 180}Hg studied through the {beta} decay of {sup 180}Tl

    SciTech Connect (OSTI)

    Elseviers, J.; Bree, N.; Diriken, J.; Huyse, M.; Ivanov, O.; Van den Bergh, P.; Van Duppen, P.; Andreyev, A. N.; Antalic, S.; Barzakh, A.; Fedorov, D.; Cocolios, T. E.; Seliverstov, M.; Comas, V. F.; Heredia, J. A.; Fedosseyev, V. N.; Marsh, B. A.; Franchoo, S.; Page, R. D.

    2011-09-15

    The {beta}{sup +}/EC decay of {sup 180}Tl and excited states in the daughter nucleus {sup 180}Hg have been investigated at the CERN On-Line Isotope Mass Separator (ISOLDE) facility. Many new low-lying energy levels were observed in {sup 180}Hg, of which the most significant are the 0{sub 2}{sup +} at 419.6 keV and the 2{sub 2}{sup +} at 601.3 keV. The former is the bandhead of an excited band in {sup 180}Hg assumed originally to be of prolate nature. From the {beta} feeding to the different states in {sup 180}Hg, the ground-state spin of {sup 180}Tl was deduced to be (4{sup -},5{sup -}).

  13. Results of Hg speciation testing on tanks 30, 32, and 37 surface samples

    SciTech Connect (OSTI)

    Bannochie, C. J.

    2015-11-11

    The Savannah River National Laboratory (SRNL) was tasked with preparing and shipping samples for Hg speciation by Eurofins Frontier Global Sciences, Inc. in Seattle, WA on behalf of the Savannah River Remediation (SRR) Mercury Task Team.

  14. 2.2.29. Demostrar que nx((n) -(n))2 Solucion: Para el resto de la prueba, p y q representan siempre un

    E-Print Network [OSTI]

    Cilleruelo, Javier

    2.2.29. Demostrar que nx((n) - (n))2 = O(x). Soluci´on: Para el resto de la prueba, p y q (n) = p|n 1, por tanto lo que queremos estimar es: nx ((n) - (n))2 = nx ( p|n 2 1)2 . Donde es un cantidad elevada al cuadrado, podemos poner eso como nx ((n) - (n))2 = nx ( p|n 2 1)( q|n 2 1). Reordenando

  15. Dielectric response of N2-Ar solid solutions in the audio frequency range S. Pilla,* J. A. Hamida, K. A. Muttalib, and N. S. Sullivan

    E-Print Network [OSTI]

    Muttalib, Khandker

    -long-range quadrupolar ordered phase phase IB .5,6 At intermediate N2 concentrations, 57 x(N2) 78 mol%, the lattice

  16. New classes of D = 4, N = 2 supersymmetric nonlinear /sigma/ models

    SciTech Connect (OSTI)

    Saidi, E.H.

    1989-01-01

    The authors show that there exists three independent N = 2, harmonic superspaces denoted as (2,2-bar)/sub +-/; (2,2-bar)/sub ++/ and (2,2)/sub +-/. These superspaces are in one-to-one correspondence with the three complex structures of the quaternionic body. The underlying supersymmetric nonlinear /sigma/ models preserving the SU(2) symmetry are developed. Two of them are described by a neutral hyperkahler potential. New results are obtained.

  17. AN IMPROVED BOUND FOR THE HAUSDORFF DIMENSION OF (n, 2)-SETS

    E-Print Network [OSTI]

    Jyväskylä, University of

    )-sets. In higher dimensions it is an open question whether an (n, 2)-set must have positive measure. We = {x Rn : dist(x, Le(a)) } is the infinite tube with axis Le(a) and cross-section radius . 2000, 1 Pl, 2 T e (a), where = C/d(P1, P2). Therefore |Pl, 1 Pl, 2 | |Pl, 1 T e (a)| n-1 d(P1, P2

  18. Vafa-Witten Theory on N=2 and N=4 Twisted Superspace in Four Dimensions

    E-Print Network [OSTI]

    Kato, Junji

    2009-01-01

    We construct a new off-shell twisted hypermultiplet with a scalar and an anti-self-dual tensor superfields. Using the N=2 twisted superspace formalism, we construct a Donaldson-Witten theory coupled to the hypermultiplet. We show that this action possesses the Vafa-Witten type N=4 twisted supersymmetry at the on-shell level. We also reconstruct the action using a N=4 twisted superconnection formalism.

  19. Vafa-Witten Theory on N=2 and N=4 Twisted Superspace in Four Dimensions

    E-Print Network [OSTI]

    Junji Kato; Akiko Miyake

    2008-08-25

    We construct a new off-shell twisted hypermultiplet with a scalar and an anti-self-dual tensor superfields. Using the N=2 twisted superspace formalism, we construct a Donaldson-Witten theory coupled to the hypermultiplet. We show that this action possesses the Vafa-Witten type N=4 twisted supersymmetry at the on-shell level. We also reconstruct the action using a N=4 twisted superconnection formalism.

  20. Steric, Quantum, and Electrostatic Effects on S{sub N}2 Reaction Barriers in Gas Phase

    SciTech Connect (OSTI)

    Liu, Shubin; Hu, Hao; Pedersen, Lee G.

    2010-05-13

    Biomolecular nucleophilic substitution reactions, S{sub N}2, are fundamental and commonplace in chemistry. It is the well-documented experimental finding in the literature that vicinal substitution with bulkier groups near the reaction center significantly slows the reaction due to steric hindrance, but theoretical understanding in the quantitative manner about factors dictating the S{sub N}2 reaction barrier height is still controversial. In this work, employing the new quantification approach that we recently proposed for the steric effect from the density functional theory framework, we investigate the relative contribution of three independent effects—steric, electrostatic, and quantum—to the S{sub N}2 barrier heights in gas phase for substituted methyl halide systems, R{sub 1}R{sub 2}R{sub 3}CX, reacting with the fluorine anion, where R{sub 1}, R{sub 2}, and R{sub 3} denote substituting groups and X = F or Cl. We found that in accordance with the experimental finding, for these systems, the steric effect dominates the transition state barrier, contributing positively to barrier heights, but this contribution is largely compensated by the negative, stabilizing contribution from the quantum effect due to the exchange-correlation interactions. Moreover, we find that it is the component from the electrostatic effect that is linearly correlated with the S{sub N}2 barrier height for the systems investigated in the present study. In addition, we compared our approach with the conventional method of energy decomposition in density functional theory as well as examined the steric effect from the wave function theory for these systems via natural bond orbital analysis.

  1. Non Abelian Sugawara Construction and the q-deformed N=2 Superconformal Algebra

    E-Print Network [OSTI]

    E. Batista; J. F. Gomes; I. J. Lautenschleguer

    1996-03-06

    The construction of a q-deformed N=2 superconformal algebra is proposed in terms of level 1 currents of ${\\cal{U}}_{q} ({\\widehat{su}}(2))$ quantum affine Lie algebra and a single real Fermi field. In particular, it suggests the expression for the q-deformed Energy-Momentum tensor in the Sugawara form. Its constituents generate two isomorphic quadratic algebraic structures. The generalization to ${\\cal{U}}_{q} ({\\widehat{su}}(N+1))$ is also proposed.

  2. Observations on BI from $\\mathcal{N}=2$ Supergravity and the General Ward Identity

    E-Print Network [OSTI]

    Andrianopoli, Laura; D'Auria, Riccardo; Rodriguez, Evelyn; Trigiante, Mario

    2015-01-01

    The multi-vector generalization of a rigid, partially-broken $\\mathcal{N}=2$ supersymmetric theory is presented as a rigid limit of a suitable gauged $\\mathcal{N}=2$ supergravity with electric, magnetic charges and antisymmetric tensor fields. This on the one hand generalizes a known result by Ferrara, Girardello and Porrati while on the other hand allows to recover the multi-vector BI models from $\\mathcal{N}=2$ supergravity as the end-point of a hierarchical limit in which the Planck mass first and then the supersymmetry breaking scale are sent to infinity. We define, in the parent supergravity model, a new symplectic frame in which, in the rigid limit, manifest symplectic invariance is preserved and the electric and magnetic Fayet-Iliopoulos terms are fully originated from the dyonic components of the embedding tensor. The supergravity origin of several features of the resulting rigid supersymmetric theory will be elucidated, such as the presence of a traceless ${\\rm SU}(2)$- Lie algebra term in the Ward i...

  3. Geometric Engineering, Mirror Symmetry and 6d (1,0) -> 4d, N=2

    E-Print Network [OSTI]

    Michele Del Zotto; Cumrun Vafa; Dan Xie

    2015-05-31

    We study compactification of 6 dimensional (1,0) theories on T^2. We use geometric engineering of these theories via F-theory and employ mirror symmetry technology to solve for the effective 4d N=2 geometry for a large number of the (1,0) theories including those associated with conformal matter. Using this we show that for a given 6d theory we can obtain many inequivalent 4d N=2 SCFTs. Some of these respect the global symmetries of the 6d theory while others exhibit SL(2,Z) duality symmetry inherited from global diffeomorphisms of the T^2. This construction also explains the 6d origin of moduli space of 4d affine ADE quiver theories as flat ADE connections on T^2. Among the resulting 4d N=2 CFTs we find theories whose vacuum geometry is captured by an LG theory (as opposed to a curve or a local CY geometry). We obtain arbitrary genus curves of class S with punctures from toroidal compactification of (1,0) SCFTs where the curve of the class S theory emerges through mirror symmetry. We also show that toroidal compactification of the little string version of these theories can lead to class S theories with no punctures on arbitrary genus Riemann surface.

  4. Angular Momentum of the N2H+ Cores in the Orion A Cloud

    E-Print Network [OSTI]

    Tatematsu, Ken'ichi; Sanhueza, Patricio; Luong, Quang Nguyen; Umemoto, Tomofumi; Mizuno, Norikazu

    2016-01-01

    We have analyzed the angular momentum of the molecular cloud cores in the Orion A giant molecular cloud observed in the N2H+ J = 1-0 line with the Nobeyama 45 m radio telescope. We have measured the velocity gradient using position velocity diagrams passing through core centers, and made sinusoidal fitting against the position angle. 27 out of 34 N2H+ cores allowed us to measure the velocity gradient without serious confusion. The derived velocity gradient ranges from 0.5 to 7.8 km/s/pc. We marginally found that the specific angular momentum J/M (against the core radius R) of the Orion N2H+ cores tends to be systematically larger than that of molecular cloud cores in cold dark clouds obtained by Goodman et al., in the J/M-R relation. The ratio beta of rotational to gravitational energy is derived to be beta = 10^{-2.3+/-0.7}, and is similar to that obtained for cold dark cloud cores in a consistent definition. The large-scale rotation of the integral-shaped filament of the Orion A giant molecular cloud does n...

  5. The new barium zinc mercurides Ba{sub 3}ZnHg{sub 10} and BaZn{sub 0.6}Hg{sub 3.4} - Synthesis, crystal and electronic structure

    SciTech Connect (OSTI)

    Schwarz, Michael; Wendorff, Marco; Roehr, Caroline

    2012-12-15

    The title compounds Ba{sub 3}ZnHg{sub 10} and BaZn{sub 0.6}Hg{sub 3.4} were synthesized from stoichiometric ratios of the elements in Ta crucibles. Their crystal structures, which both represent new structure types, have been determined using single crystal X-ray data. The structure of Ba{sub 3}ZnHg{sub 10} (orthorhombic, oP28, space group Pmmn, a=701.2(3), b=1706.9(8), c=627.3(3)pm, Z=2, R1=0.0657) contains folded 4{sup 4} Hg nets, where the meshes form the bases of flat rectangular pyramids resembling the structure of BaAl{sub 4}. The flat pyramids are connected via Hg-Zn/Hg bonds, leaving large channels at the folds, in which Ba(1) and Hg(2) atoms alternate. Whereas the remaining Hg/Zn atoms form a covalent 3D network of three- to five-bonded atoms with short M-M distances (273-301 pm; CN 9-11), the Hg(2) atoms in the channels adopt a comparatively large coordination number of 12 and increased distances (317-348 pm) to their Zn/Hg neighbours. In the structure of BaZn{sub 0.6}Hg{sub 3.4} (cubic, cI320, space group I4{sup Macron }3d, a=2025.50(7) pm, Z=64, R1=0.0440), with a chemical composition not much different from that of Ba{sub 3}ZnHg{sub 10}, the Zn/Hg atoms of the mixed positions M(1/2) are arranged in an slightly distorted primitive cubic lattice with a 4 Multiplication-Sign 4 Multiplication-Sign 4 subcell relation to the unit cell. The 24 of the originating 64 cubes contain planar cis tetramers Hg(5,6){sub 4} with Hg in a nearly trigonal planar or tetrahedral coordination. In another 24 of the small cubes, two opposing faces are decorated by Hg(3,4){sub 2} dumbbells, two by Ba(2) atoms respectively. The third type of small cubes are centered by Ba(1) atoms only. The complex 3D polyanionic Hg/Zn network thus formed is compared with the Hg partial structure in Rb{sub 3}Hg{sub 20} applying a group-subgroup relation. Despite their different overall structures, the connectivity of the negatively charged Hg atoms, the rather metallic Zn bonding characteristic (as obtained from FP-LAPW band structure calculations) and the coordination number of 16 for all Ba cations relate the two title compounds. - Graphical abstract: Six of the 64 small sub-cubes of three types (A, B, C) forming the unit cell of the Hg-rich mercuride BaZn{sub 0.6}Hg{sub 3.4}. Highlights: Black-Right-Pointing-Pointer Two new Hg-rich Ba mercurides, both synthesized from the elements in pure phase. Black-Right-Pointing-Pointer BaZn{sub 0.6}HgG{sub 3.4} and Ba{sub 3}ZnHg{sub 10} with new complex structure types. Black-Right-Pointing-Pointer Structure relation to other complex cubic intermetallics. Black-Right-Pointing-Pointer Discussion of covalent and metallic bonding aspects, as found by the structure features and band structure calculations.

  6. PHYSIOLOGICAL ECOLOGY -ORIGINAL PAPER N2 fixation estimates in real-time by cavity ring-down laser

    E-Print Network [OSTI]

    Jackson, Robert B.

    by flame ionization detector gas chromatography. First, the detection of acetylene reduction to ethylene on a modestly priced, commercially available instrument. We illustrate its use for measuring N2 fixation using of atmospheric N2 to ammonium, is the dominant natural pathway for new nitrogen that enters most ecosystems

  7. Dynamics of NO reduction by H2 on Rh(111): Velocity and angular distributions of the N2 product

    E-Print Network [OSTI]

    Sibener, Steven

    Dynamics of NO reduction by H2 on Rh(111): Velocity and angular distributions of the N2 product J; accepted 17 January 1996 The velocity and angular distributions of N2 produced from the reduction temperature. Both the angular and velocity distributions are well fit by bimodal forms. The high energy

  8. Unified Approach to Pore Size Characterization of Microporous Carbonaceous Materials from N2, Ar, and CO2

    E-Print Network [OSTI]

    Muzzio, Fernando J.

    , and CO2 Adsorption Isotherms Peter I. Ravikovitch, Aleksey Vishnyakov, Ron Russo, and Alexander V adsorption at standard temperatures, 77 K for N2 and Ar and 273 K for CO2. Reference isotherms of N2, Ar, and CO2 in a series of model slit-shaped carbon pores in the range from 0.3 to 36 nm have been calculated

  9. In-beam conversion-electron spectroscopy of {sup 180}Hg

    SciTech Connect (OSTI)

    Page, R. D.; Wiseman, D. R.; Butler, P. A.; Herzberg, R.-D.; Jones, G. D.; Joss, D. T.; Keenan, A.; Rainovski, G. I.; Andreyev, A. N.; Grahn, T.; Greenlees, P. T.; Jones, P. M.; Julin, R.; Juutinen, S.; Kankaanpaeae, H.; Kettunen, H.; Kuusiniemi, P.; Leino, M.; Muikku, M.; Nieminen, P.

    2011-09-15

    Excited states in {sup 180}Hg were populated using the {sup 147}Sm({sup 36}Ar,3n){sup 180}Hg reaction and studied by in-beam conversion-electron spectroscopy. Conversion electrons emitted at the target position were measured using the Silicon Array for Conversion Electron Detection (SACRED) spectrometer and tagged through the characteristic {alpha} decays of {sup 180}Hg detected in a position-sensitive silicon strip detector located at the focal plane of the gas-filled recoil separator Recoil Ion Transport Unit (RITU). Electron conversion of transitions previously assigned to {sup 180}Hg through in-beam {gamma}-ray spectroscopy studies was identified up to the 10{sup +}{yields}8{sup +} transition and the intensities of the conversion-electron transitions were found to be consistent with the previous multipolarity assignments. Evidence was also found for two highly converted transitions in {sup 180}Hg: a 167 keV transition is interpreted as the transition from the newly identified 2{sub 2}{sup +} state at 601 keV to the 2{sub 1}{sup +} state at 434 keV, while a 420 keV transition is assigned as the E0 decay from the 0{sup +} bandhead of the prolate-deformed configuration to the weakly deformed ground state.

  10. IDS120j WITHOUT RESISTIVE MAGNETS: NEW Hg MODULE MARS1510 ( DESKTOP ) vs. MARS1512 ( PRINCETON CLUSTER )

    E-Print Network [OSTI]

    McDonald, Kirk

    500,000 / 5,000,000 2 #12;3 IDS120j: yz CROSS SECTIONS WITH DETAILS OF Hg POOL MODULE FROM VAN GRAVE'S PRESENTATION ( 8 / 9 / 2012 ). THE DESIGN REQUIRES A 2.5 cm ! GAP BETWEEN SH#1 INNER VESSEL AND Hg POOL MODULE OUTER VESSEL. AN EVEN LARGER SPACE APPEARS TO BE BETWEEN INNER AND OUTER VESSEL OF THE Hg POOL MODULE

  11. IDS120j WITHOUT RESISTIVE MAGNETS: NEW Hg MODULE mars1510 ( DESKTOP ) vs. mars1512 ( PRINCETON CLUSTER )

    E-Print Network [OSTI]

    McDonald, Kirk

    500,000 / 5,000,000 20,000,000 2 #12;3 IDS120j: yz CROSS SECTIONS WITH DETAILS OF Hg POOL MODULE FROM VESSEL AND Hg POOL MODULE OUTER VESSEL. AN EVEN LARGER SPACE APPEARS TO BE BETWEEN INNER AND OUTER VESSEL OF THE Hg POOL MODULE FOR THE FLOW OF He GAS FOR COOLING THE POOL. THE RADIUS OF THE UPPER HALF SEMICIRCULAR

  12. IDS120h GEOMETRY WITH MODIFIED Hg POOL VESSEL SIMULATIONS FOR 60% W + 40% He SHIELDING (P12 'POINT')

    E-Print Network [OSTI]

    McDonald, Kirk

    IDS120h GEOMETRY WITH MODIFIED Hg POOL VESSEL SIMULATIONS FOR 60% W + 40% He SHIELDING (P12 'POINT (12/27/2011) 1 #12;IDS120hm: (m IS FOR) modified Hg pool vessel IN IDS120h. # 5E5 SIMULATIONS AND SHIFTED Be WIDOW FROM 600 cm (0.6 cm THICK) TO 300 cm (1 cm THICK). MODIFIED Hg POOL EXTENTS FROM 86 cm

  13. Angular Momentum and Gravimagnetization of the ${\\cal N}=2$ SYM vacuum

    E-Print Network [OSTI]

    A. Gorsky

    2011-02-09

    In this note we discuss the gravimagnetization of the ${\\cal N}=2$ SYM vacuum in the $\\Omega$-background. It is argued that the Seiberg-Witten prepotential is related to the vacuum density of the angular momentum in the Euclidean $R^4$ space. The possible role of the dyonic instantons as the microscopic angular momentum carriers which could yield the spontaneous vacuum gravimagnetization is conjectured. We interpret the dyonic instanton as a kind of the Euclidean bounce in $R^4$ similar to one responsible for the Schwinger pair creation. The induced angular momentum in $R^4$ is also briefly considered in the dual Liouville formulation of $SU(2)$ theory via AGT relation.

  14. A $\\mathcal{N}=2$ Supersymmetric $AdS_4$ Solution in M-theory

    E-Print Network [OSTI]

    Lozano, Yolanda; Montero, Jesús

    2015-01-01

    We find a new $\\mathcal{N}=2$ $AdS_4$ solution in M-theory supported by purely magnetic flux via a sequence of abelian and non-abelian T-dualities. This provides the second known example in this class besides the uplift of the Pernici and Sezgin solution to 7d gauged supergravity constructed in the eighties. We compute the free energy of the solution, and show that it scales as $N^{3/2}$. It is intriguing that even though the natural holographic interpretation is in terms of M5-branes wrapped on a special Lagrangian 3-cycle, this solution does not exhibit the expected $N^3$ behavior.

  15. Lagrangians with electric and magnetic charges of N=2 supersymmetric gauge theories

    E-Print Network [OSTI]

    Mathijs de Vroome; Bernard de Wit

    2007-07-18

    General Lagrangians are constructed for N=2 supersymmetric gauge theories in four space-time dimensions involving gauge groups with (non-abelian) electric and magnetic charges. The charges induce a scalar potential, which, when the charges are regarded as spurionic quantities, is invariant under electric/magnetic duality. The resulting theories are especially relevant for supergravity, but details of the extension to local supersymmetry will be discussed elsewhere. The results include the coupling to hypermultiplets. Without the latter, it is demonstrated how an off-shell representation can be constructed based on vector and tensor supermultiplets.

  16. The free energy of N=2 supersymmetric AdS_4 solutions of M-theory

    E-Print Network [OSTI]

    Maxime Gabella; Dario Martelli; Achilleas Passias; James Sparks

    2011-07-29

    We show that general N=2 supersymmetric AdS_4 solutions of M-theory with non-zero M2-brane charge admit a canonical contact structure. The free energy of the dual superconformal field theory on S^3 and the scaling dimensions of operators dual to supersymmetric wrapped M5-branes are expressed via AdS/CFT in terms of contact volumes. In particular, this leads to topological and localization formulae for the coefficient of N^{3/2} in the free energy of such solutions.

  17. Higher Rank Wilson Loops in N = 2* Super-Yang-Mills Theory

    E-Print Network [OSTI]

    Xinyi Chen-Lin; Konstantin Zarembo

    2015-02-13

    The N=2* Super-Yang-Mills theory (SYM*) undergoes an infinite sequence of large-N quantum phase transitions. We compute expectation values of Wilson loops in k-symmetric and antisymmetric representations of the SU(N) gauge group in this theory and show that the same phenomenon that causes the phase transitions at finite coupling leads to a non-analytic dependence of Wilson loops on k/N when the coupling is strictly infinite, thus making the higher-representation Wilson loops ideal holographic probes of the non-trivial phase structure of SYM*.

  18. N = 2 Supersymmetric Harmonic Oscillator: Basic Brackets Without Canonical Conjugate Momenta

    E-Print Network [OSTI]

    N. Srinivas; A. Shukla; R. P. Malik

    2015-08-16

    We exploit the ideas of spin-statistics theorem, normal-ordering and the key concepts behind the symmetry principles to derive the canonical (anti)commutators for the case of a one (0 + 1)-dimensional (1D) N = 2 supersymmetric (SUSY) harmonic oscillator (HO) without taking the help of the mathematical definition of canonical conjugate momenta with respect to the bosonic and fermionic variables of this toy model for the Hodge theory (where the continuous and discrete symmetries of the theory provide the physical realizations of the de Rham cohomological operators of differential geometry). In our present endeavor, it is the full set of continuous symmetries and their corresponding generators that lead to the derivation of basic (anti)commutators amongst the creation and annihilation operators that appear in the normal mode expansions of the dynamical fermionic and bosonic variables of our present N = 2 SUSY theory of a HO. These basic brackets are in complete agreement with such kind of brackets that are derived from the standard canonical method of quantization scheme.

  19. Two-dimensional N=(2,2) super Yang-Mills theory on computer

    E-Print Network [OSTI]

    Hiroshi Suzuki

    2007-09-05

    We carry out preliminary numerical study of Sugino's lattice formulation \\cite{Sugino:2004qd,Sugino:2004qdf} of the two-dimensional $\\mathcal{N}=(2,2)$ super Yang-Mills theory (2d $\\mathcal{N}=(2,2)$ SYM) with the gauge group $\\SU(2)$. The effect of dynamical fermions is included by re-weighting a quenched ensemble by the pfaffian factor. It appears that the complex phase of the pfaffian due to lattice artifacts and flat directions of the classical potential are not problematic in Monte Carlo simulation. Various one-point supersymmetric Ward-Takahashi (WT) identities are examined for lattice spacings up to $a=0.5/g$ with the fixed physical lattice size $L=4.0/g$, where $g$ denotes the gauge coupling constant in two dimensions. WT identities implied by an exact fermionic symmetry of the formulation are confirmed in fair accuracy and, for most of these identities, the quantum effect of dynamical fermions is clearly observed. For WT identities expected only in the continuum limit, the results seem to be consistent with the behavior expected from supersymmetry, although we do not see clear distintion from the quenched simulation. We measure also the expectation values of renormalized gauge-invariant bi-linear operators of scalar fields.

  20. PET exam A 424304 20-032013 Short answers 111. Ex = Ex (O2) + Ex(N2) + Ex (unmix)

    E-Print Network [OSTI]

    Zevenhoven, Ron

    (303/293)+8,314*293*ln(5) = 2288,6 W Similar Ex (N2) = 3709,8 W, and Ex (unmix) = 3478,1 W Total = 9475PET exam ÅA 424304 20-032013 Short answers 111. Ex = Ex (O2) + Ex(N2) + Ex (unmix) Ex (O2) = (O2 --- Similar for N2. Ex (unmix) = · -R·T·(0.21ln0.21 + 079ln0.79) Ex (O2) = (2100/3600)*(29,4*10-293*29,4*ln

  1. ATOC 3500/CHEM 3151 Spring 201, Problem 14 Evaluating the importance of Heterogeneous Chemistry of N2O5

    E-Print Network [OSTI]

    Toohey, Darin W.

    for NOx, because when sunlight returns it will photolyzes to reform NOx (NO + NO2). However, N2O5 can also been destroyed by catalytic reactions with the original NOx. The reactions described above are written

  2. SmartHG: Energy Demand Aware Open Services for Smart Grid Intelligent Automation

    E-Print Network [OSTI]

    Tronci, Enrico

    : to minimise energy usage and cost for each home, and to support the Distribution Network Operator (DNO) in optimising operation of the Electric Distribution Network (EDN). SmartHG goals are achieved solar panels)], for each time slot (say each hour) the DNO price policy defines an interval of energy

  3. IDS120h POWER DEPOSITION AND Hg POOL STUDIES Nicholas Souchlas (7/26/2011)

    E-Print Network [OSTI]

    McDonald, Kirk

    IDS120h POWER DEPOSITION AND Hg POOL STUDIES Nicholas Souchlas (7/26/2011) 1 #12;Power deposition;ENERGY DEPOSITED IN SC SOLENOIDS (SC#), SHIELDING (SH#). P12 OPTIMIZED POINT, POOL WALL CASES x=+/-6W DECREASE IN DP (BLUE AREA) SH#4~ SMALL INCREASE IN DP (YELLOW AREA) RS, BP~ SAME DP #12;HIGHLIGHTS : Power

  4. Application of tree rings [dendrochemistry] for detecting historical trends in air Hg concentrations across multiple

    E-Print Network [OSTI]

    Weisberg, Peter J.

    ). Additional sources include cement production, oil and ore processing, mining (lead, zinc, pig iron, steel to millennia) at time steps of B5 years. Keywords Pinus Á National Park Á Proxy for air pollution Á Mining, artisanal mining and coal combus- tion are considered the two major sources of Hg emissions (UNEP 2013

  5. Spectral Sequences and Vacua in N = 2 Gauged Linear Quantum Mechanics with Potentials

    E-Print Network [OSTI]

    Kenny Wong

    2015-11-24

    We study the behaviour of supersymmetric ground states in a class of one-dimensional N = 2 abelian gauged linear sigma models, including theories for which the target space is a complete intersection in projective space, and more generally, models with an interaction term introduced by Herbst, Hori and Page in which the vacua correspond to elements of hypercohomology groups of complexes of sheaves. Combining physical insights from recent work by Hori, Kim and Yi with the use of spectral sequences, we propose a way to reconcile the non-linear sigma model description, valid deep within a geometric phase, with the effective Coulomb branch description, valid near a phase boundary. This leads to a physical interpretation of the hypercohomology groups from the perspective of the Coulomb branch, as well as an interpretation for the spectral sequences used to compute them.

  6. Gate-Defined Wires in HgTe Quantum Wells: From Majorana Fermions to Spintronics Johannes Reuther and Jason Alicea

    E-Print Network [OSTI]

    Yacoby, Amir

    Gate-Defined Wires in HgTe Quantum Wells: From Majorana Fermions to Spintronics Johannes Reuther and various spintronics applications based on gate-defined wires in HgTe quantum wells. Because of the Dirac­15] architectures, while not usually viewed from a spintronics lens, similarly rely crucially on spin manipulation

  7. Strong-field control of the dissociative ionization of N2O with near-single-cycle pulses

    E-Print Network [OSTI]

    Kling, Matthias

    Strong-field control of the dissociative ionization of N2O with near-single-cycle pulses M Kübel1.1088/1367-2630/16/6/065017 Abstract The dissociative ionization of N2O by near-single-cycle laser pulses is studied using phase, journal citation and DOI. #12;results demonstrate how few-femtosecond dynamics can drive and steer mole

  8. KINETICS OF DIRECT OXIDATION OF H2S IN COAL GAS TO ELEMENTAL SULFUR

    SciTech Connect (OSTI)

    K.C. Kwon

    2005-01-01

    The direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and the hot-gas desulfurization using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process. The objective of this research is to support the near- and long-term process development efforts to commercialize this direct oxidation technology. The objectives of this research are to measure kinetics of direct oxidation of H{sub 2}S to elemental sulfur in the presence of a simulated coal gas mixture containing SO{sub 2}, H{sub 2}, and moisture, using 160-{micro}m C-500-04 alumina catalyst particles and a micro bubble reactor, and to develop kinetic rate equations and model the direct oxidation process to assist in the design of large-scale plants. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam. To achieve the above-mentioned objectives, experiments on conversion of hydrogen sulfide into liquid elemental sulfur were carried out for the space time range of 0.059-0.87 seconds at 125-155 C to evaluate effects of reaction temperature, H{sub 2}S concentration, reaction pressure, and catalyst loading on conversion of hydrogen sulfide into liquid elemental sulfur. Simulated coal gas mixtures consist of 62-78 v% hydrogen, 3,000-7,000-ppmv hydrogen sulfide, 1,500-3,500 ppmv sulfur dioxide, and 10 vol % moisture, and nitrogen as remainder. Volumetric feed rates of a simulated coal gas mixture to a micro bubble reactor are 50 cm{sup 3}/min at room temperature and atmospheric pressure. The temperature of the reactor is controlled in an oven at 125-155 C. The pressure of the reactor is maintained at 40-170 psia. The molar ratio of H{sub 2}S to SO{sub 2} in the bubble reactor is maintained at 2 for all the reaction experiment runs.

  9. KINETICS OF DIRECT OXIDATION OF H2S IN COAL GAS TO ELEMENTAL SULFUR

    SciTech Connect (OSTI)

    K.C. Kwon

    2004-01-01

    The direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and the hot-gas desulfurization using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process. The objective of this research is to support the near- and long-term process development efforts to commercialize this direct oxidation technology. The objectives of this research are to measure kinetics of direct oxidation of H{sub 2}S to elemental sulfur in the presence of a simulated coal gas mixture containing SO{sub 2}, H{sub 2}, and moisture, using 160-{micro}m C-500-04 alumina catalyst particles and a micro bubble reactor, and to develop kinetic rate equations and model the direct oxidation process to assist in the design of large-scale plants. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam. To achieve the above-mentioned objectives, experiments on conversion of hydrogen sulfide into liquid elemental sulfur were carried out for the space time range of 1-6 milliseconds at 125-155 C to evaluate effects of reaction temperature, moisture concentration, reaction pressure on conversion of hydrogen sulfide into liquid elemental sulfur. Simulated coal gas mixtures consist of 70 v% hydrogen, 2,500-7,500-ppmv hydrogen sulfide, 1,250-3,750 ppmv sulfur dioxide, and 0-15 vol% moisture, and nitrogen as remainder. Volumetric feed rates of a simulated coal gas mixture to a micro bubble reactor are 100 cm{sup 3}/min at room temperature and atmospheric pressure. The temperature of the reactor is controlled in an oven at 125-155 C. The pressure of the reactor is maintained at 40-170 psia.

  10. KINETICS OF DIRECT OXIDATION OF H2S IN COAL GAS TO ELEMENTAL SULFUR

    SciTech Connect (OSTI)

    K.C. Kwon

    2003-01-01

    The direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and HGD/DSRP. The objective of this research is to support the near- and long-term DOE efforts to commercialize this direct oxidation technology. The objectives of this research are to measure kinetics of direct oxidation of H{sub 2}S to elemental sulfur in the presence of a simulated coal gas mixture containing SO{sub 2}, H{sub 2}, and moisture, using 60-{micro}m C-500-04 alumina catalyst particles and a PFA differential fixed-bed micro reactor, and to develop kinetic rate equations and model the direct oxidation process to assist in the design of large-scale plants. To achieve the above-mentioned objectives, experiments on conversion of hydrogen sulfide into elemental sulfur were carried out for the space time range of 0.01-0.047 seconds at 125-155 C to evaluate effects of reaction temperatures, moisture concentrations, reaction pressures on conversion of hydrogen sulfide into elemental sulfur. Simulated coal gas mixtures consist of 61-89 v% hydrogen, 2,300-9,200-ppmv hydrogen sulfide, 1,600-4,900 ppmv sulfur dioxide, and 2.6-13.7 vol % moisture, and nitrogen as remainder. Volumetric feed rates of a simulated coal gas mixture to the reactor are 100-110 cm{sup 3}/min at room temperature and atmospheric pressure (SCCM). The temperature of the reactor is controlled in an oven at 125-155 C. The pressure of the reactor is maintained at 28-127 psia. The following results were obtained based on experimental data generated from the differential reactor system, and their interpretations, (1) Concentration of moisture and concentrations of both H{sub 2}S and SO{sub 2} appear to affect slightly reaction rates of H{sub 2}S with SO{sub 2} over the moisture range of 2.5-13.6 v% moisture at 140 C and 120-123 psia. (2) Concentrations of both H{sub 2}S and SO{sub 2} appear to affect slightly reaction rates of H{sub 2}S with SO{sub 2} over the temperature range of 135-145 C at 5-v% moisture and 112-123 psia. However, reaction rates of H{sub 2}S with SO{sub 2} appear to decrease slightly with increased reaction temperatures over the temperature range of 135-145 C at 5-v% moisture and 112-123 psia. (3) Concentrations of both H{sub 2}S and SO{sub 2} appear to affect slightly reaction rates of H{sub 2}S with SO{sub 2} over the pressure range of 28-123 psia at 5-v% moisture and 140 C. However, reaction rates of H{sub 2}S with SO{sub 2} increase significantly with increased reaction pressures over the pressure range of 28-123 psia at 5-v% moisture and 140 C.

  11. Sensitive Detection of H2S Using Gold Nanoparticle Decorated Single-Walled Carbon

    E-Print Network [OSTI]

    , and increasing the bias voltage reduced the sensor recovery time, probably by local Joule heating. The sensing in large amounts in coal and natural gas processing, petroleum industries, biogas production, and sewage

  12. Modeling Studies on the Transport of Benzene and H2S in CO2-Water Systems

    E-Print Network [OSTI]

    Zheng, L.

    2011-01-01

    brines co-produced with crude oil (Zarrella et al. , 1967)brines co-produced with crude oil (Zarrella et al. , 1967)of Production Condensate Crude oil Crude oil Crude oil Crude

  13. Modeling Studies on the Transport of Benzene and H2S in CO2-Water Systems

    E-Print Network [OSTI]

    Zheng, L.

    2011-01-01

    1980). Mole fraction of organics in CO2 60 C o benzene+CO2,1980). Mole fraction of organics in CO2 100 C phenol+CO2,o VP CO2 Vapor pressure (bar) VP C6H6 0 Mole fraction of CO

  14. Modeling Studies on the Transport of Benzene and H2S in CO2-Water Systems

    SciTech Connect (OSTI)

    Zheng, L.; Spycher, N.; Xu, T.; Apps, J.; Kharaka, Y.; Birkholzer, J.T.

    2010-11-05

    In this study, reactive transport simulations were used to assess the mobilization and transport of organics with supercritical CO{sub 2} (SCC), and the co-injection and transport of H{sub 2}S with SCC. These processes were evaluated at conditions of typical storage reservoirs, and for cases of hypothetical leakage from a reservoir to an overlying shallower fresh water aquifer. Modeling capabilities were developed to allow the simulation of multiphase flow and transport of H{sub 2}O, CO{sub 2}, H{sub 2}S, as well as specific organic compounds (benzene), coupled with multicomponent geochemical reaction and transport. This included the development of a new simulator, TMVOC-REACT, starting from existing modules of the TOUGH2 family of codes. This work also included an extensive literature review, calculation, and testing of phase-partitioning properties for mixtures of the phases considered. The reactive transport simulations presented in this report are primarily intended to illustrate the capabilities of the new simulator. They are also intended to help evaluate and understand various processes at play, in a more qualitative than quantitative manner, and only for hypothetical scenarios. Therefore, model results are not intended as realistic assessments of groundwater quality changes for specific locations, and they certainly do not provide an exhaustive evaluation of all possible site conditions, especially given the large variability and uncertainty in hydrogeologic and geochemical parameter input into simulations. The first step in evaluating the potential mobilization and transport of organics was the identification of compounds likely to be present in deep storage formations, and likely to negatively impact freshwater aquifers if mobilized by SCC. On the basis of a literature review related to the occurrence of these organic compounds, their solubility in water and SCC, and their toxicity (as reflected by their maximum contaminant levels MCL), benzene was selected as a key compound for inclusion into numerical simulations. Note that considering additional organic compounds and/or mixtures of such compounds in the simulations was beyond the scope of this study, because of the effort required to research, calculate, and validate the phase-partitioning data necessary for simulations. The injection of CO{sub 2} into a deep saline aquifer was simulated, followed by modeling the leaching of benzene by SCC and transport of benzene to an overlying aquifer along a hypothetical leakage pathway. One- and two-dimensional models were set up for this purpose. The target storage formation was assumed to initially contain about 10{sup -4} ppm benzene. Model results indicate that: (1) SCC efficiently extracts benzene from the storage formation. (2) Assuming equilibrium, the content of benzene in SCC is roportional to the concentration of benzene in the aqueous and solid phases. (3) Benzene may co-migrate with CO{sub 2} into overlying aquifers if a leakage pathway is present. Because the aqueous solubility of benzene in contact with CO{sub 2} is lower than the aqueous solubility of CO{sub 2}, benzene is actually enriched in the CO{sub 2} phase as the plume advances. (4) For the case studied here, the resulting aqueous benzene concentration in the overlying aquifer is on the same order of magnitude as the initial concentration in the storage formation. This generic modeling study illustrates, in a semi-quantitative manner, the possible mobilization of benzene by SCC. The extent to which the mobilization of this organic compound evolves temporally and spatially depends on a large number of controlling parameters and is largely site specific. Therefore, for more 'truly' predictive work, further sensitivity studies should be conducted, and further modeling should be integrated with site-specific laboratory and/or field experimental data. The co-injection of H{sub 2}S with CO{sub 2} into a deep saline aquifer was also simulated. In addition, the model considered leakage of the supercritical CO{sub 2}+H{sub 2}S mixture along a preferential p

  15. Modeling Studies on the Transport of Benzene and H2S in CO2-Water Systems

    E-Print Network [OSTI]

    Zheng, L.

    2011-01-01

    synthetic aluminous goethite before and after transformationAdsorption of lead(ll) on the goethite surface: voltammetric5.35.   Profile of the goethite volume fraction change (

  16. Kinetics of Direct Oxidation of H2S in Coal Gas to Elemental Sulfur

    SciTech Connect (OSTI)

    K.C. Kwon

    2005-11-01

    Removal of hydrogen sulfide (H{sub 2}S) from coal gasifier gas and sulfur recovery are key steps in the development of Department of Energy's (DOE's) advanced Vision 21 plants that produce electric power and clean transportation fuels with coal and natural gas. These Vision 21 plants will require highly clean coal gas with H{sub 2}S below 1 ppm and negligible amounts of trace contaminants such as hydrogen chloride, ammonia, alkali, heavy metals, and particulate. The conventional method of sulfur removal and recovery employing amine, Claus, and tail-gas treatment is very expensive. A second generation approach developed under DOE's sponsorship employs hot-gas desulfurization (HGD) using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process (DSRP). However, this process sequence does not remove trace contaminants and is targeted primarily towards the development of advanced integrated gasification combined cycle (IGCC) plants that produce electricity (not both electricity and transportation fuels). There is an immediate as well as long-term need for the development of cleanup processes that produce highly clean coal gas for next generation Vision 21 plants. To this end, a novel process is now under development at several research organizations in which the H{sub 2}S in coal gas is directly oxidized to elemental sulfur over a selective catalyst. Such a process is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. The direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and HGD/DSRP. The objectives of this research are to measure kinetics of direct oxidation of H{sub 2}S to elemental sulfur in the presence of a simulated coal gas mixture containing SO{sub 2}, H{sub 2}, and moisture, using 160-{micro}m C-500-04 alumina catalyst particles and 400 square cells/inch{sup 2}, {gamma}-Al{sub 2}O{sub 3}-wash-coated monolithic catalyst, and various reactors such as a micro packed-bed reactor, a micro bubble reactor, and a monolithic catalyst reactor, and to develop kinetic rate equations and model the direct oxidation process to assist in the design of large-scale plants. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam.

  17. Materials Data on Si2H2S3 (SG:114) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  18. Chemical Engineering Journal 113 (2005) 119126 Understanding the limits of H2S degrading biotrickling filters

    E-Print Network [OSTI]

    2005-01-01

    ) and optimum operating conditions (nutrients, pH, CO2). The unconventional conditions of the biotrickling, in this case a single 4-cm open-pore polyurethane foam cube. External mass transfer was limiting below air

  19. Modeling Studies on the Transport of Benzene and H2S in CO2-Water Systems

    E-Print Network [OSTI]

    Zheng, L.

    2011-01-01

    pressure gradient and a geothermal gradient of 30 o C/1000and a typical geothermal gradient. It should be noted thatpressure gradient and a geothermal gradient of 30°C/1,000 m,

  20. ORIGINAL RESEARCH PAPER Gas phase H2S product recovery in a packed bed bioreactor

    E-Print Network [OSTI]

    Daugulis, Andrew J.

    of sulfate-laden wastewaters and bioremediation of acid mine drainage (Colleran et al. 1995; Hulshoff et al to the conversion of CH4 to H2 by steam reforming. In the treatment of acid mine drainage, dissolved heavy metals

  1. Development of analytical techniques to study H2s poisoning of PEMFCs and components

    SciTech Connect (OSTI)

    Brosha, Eric L; Rockward, Tommy; Uribe, Francisco A; Garzon, Fernando H

    2008-01-01

    Polymer electrolyte membrane fuel cells are sensitive to impurities that may be present in either the oxidizer or fuel. H{sub 2}S, even at the ppb level, will have a dramatic and adverse affect on fuel cell performance. Not only is it important to know a particular material's affinity to adsorb H{sub 2}S, when considering materials for PEMFC applications, issues such as permeation and crossover rates also become extremely important Several experimental methods have been developed to quantify H{sub 2}S adsorption onto surfaces and to quantify H{sub 2}S permeation through Nafion(reg.) membranes using readily available and inexpensive Ag/AgS ion probes. In addition to calculating the H{sub 2}S uptake on commonly used XC-72 carbon supports and PtlXC-72 catalysts, the H{sub 2}S permeability through dry and humidified Nafion(reg.) PEMFC membranes was also studied using these specialized techniques. In each ion probe experiment performed, a sulfide anti-oxidant buffer solution was used to trap and concentrate trace quantities of H{sub 2}S during the course of the measurement. Crossover experiments were conducted for up to 24 hours in order to achieve sulfide ion concentrations high enough to be precisely determined by subsequent titration with Pb(NO{sub 3}){sub 2}. By using these techniques, we have confirmed H{sub 2}S crossover in Nafion(reg.) membranes and have calculated preliminary rates of H{sub 2}S crossover.

  2. 15 Years of Successful H2S Abatement | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmental Jump to:EAand Dalton Jump to:Wylie, Texas:V.S.A. Chapter 5 CommonOpen5414Cal.

  3. Effect of exposure environment on the interactions between acid gas (H2S

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfate Reducing(Journal Article) | SciTech ConnectExperimentsGAMMA-RAYNp, Pu, and Am):

  4. Three-dimensional N=2 (AdS) supergravity and associated supercurrents

    E-Print Network [OSTI]

    Sergei M. Kuzenko; Gabriele Tartaglino-Mazzucchelli

    2012-09-28

    Long ago, Achucarro and Townsend discovered that in three dimensions (3D) N-extended anti-de Sitter (AdS) supergravity exists in several incarnations, which were called the (p,q) AdS supergravity theories with non-negative integers p>=q such that N=p+q. Using the superspace approach to 3D N-extended supergravity developed in arXiv:1101.4013, we present three superfield formulations for N=2 supergravity that allow for well defined cosmological terms and supersymmetric AdS solutions. The conformal compensators corresponding to these theories are respectively: (i) a chiral scalar multiplet: (ii) a vector multiplet; and (iii) an improved complex linear multiplet. The theories corresponding to (i) and (iii) are shown to provide two dually equivalent realizations of the (1,1) AdS supergravity, while (ii) describes the (2,0) AdS supergravity. We associate with each supergravity formulation, with and without a cosmological term, a consistent supercurrent multiplet. The supercurrents in the (1,1) and (2,0) AdS backgrounds are derived for the first time. We elaborate on rigid supersymmetric theories in (1,1) and (2,0) AdS superspaces.

  5. N=2 Supersymmetry, Painleve III and Exact Scaling Functions in 2D Polymers

    E-Print Network [OSTI]

    P. Fendley; H. Saleur

    1992-04-29

    We discuss in this paper various aspects of the off-critical $O(n)$ model in two dimensions. We find the ground-state energy conjectured by Zamolodchikov for the unitary minimal models, and extend the result to some non-unitary minimal cases. We apply our results to the discussion of scaling functions for polymers on a cylinder. We show, using the underlying N=2 supersymmetry, that the scaling function for one non-contractible polymer loop around the cylinder is simply related to the solution of the Painleve III differential equation. We also find the ground-state energy for a single polymer on the cylinder. We check these results by numerically simulating the polymer system. We also analyze numerically the flow to the dense polymer phase. We find there surprising results, with a $c_{\\hbox{eff}}$ function that is not monotonous and seems to have a roaming behavior, getting very close to the values 81/70 and 7/10 between its UV and IR values of 1.

  6. Tillage and seasonal emissions of CO2, N2O and NO across a seed bed and at the field scale in a Mediterranean climate

    E-Print Network [OSTI]

    van Kessel, Chris

    Tillage and seasonal emissions of CO2, N2O and NO across a seed bed and at the field scale tillage may increase N2O emissions under certain circumstances, thereby offsetting C sequestration manage- ment accounted for almost 94% of total US N2O emissions from 1990 to 2004 (USEPA, 2006). In 2004

  7. Axi-symmetrical flow reactor for [sup 196]Hg photochemical enrichment

    DOE Patents [OSTI]

    Grossman, M.W.

    1991-04-30

    The present invention is directed to an improved photochemical reactor useful for the isotopic enrichment of a predetermined isotope of mercury, especially, [sup 196]Hg. Specifically, two axi-symmetrical flow reactors were constructed according to the teachings of the present invention. These reactors improve the mixing of the reactants during the photochemical enrichment process, affording higher yields of the desired [sup 196]Hg product. Measurements of the variation of yield (Y) and enrichment factor (E) along the flow axis of these reactors indicates very substantial improvement in process uniformity compared to previously used photochemical reactor systems. In one preferred embodiment of the present invention, the photoreactor system was built such that the reactor chamber was removable from the system without disturbing the location of either the photochemical lamp or the filter employed therewith. 10 figures.

  8. Three very young HgMn stars in the Orion OB1 Association

    E-Print Network [OSTI]

    Vincent M. Woolf; David L. Lambert

    1999-05-18

    We report the detection of three mercury-manganese stars in the Orion OB1 association. HD 37886 and BD-0 984 are in the approximately 1.7 million year old Orion OB1b. HD 37492 is in the approximately 4.6 million year old Orion OB1c. Orion OB1b is now the youngest cluster with known HgMn star members. This places an observational upper limit on the time scale needed to produce the chemical peculiarities seen in mercury-manganese stars, which should help in the search for the cause or causes of the peculiar abundances in HgMn and other chemically peculiar upper main sequence stars.

  9. Automated product recovery in a HG-196 photochemical isotope separation process

    DOE Patents [OSTI]

    Grossman, Mark W. (Belmont, MA); Speer, Richard (Reading, MA)

    1992-01-01

    A method of removing deposited product from a photochemical reactor used in the enrichment of .sup.196 Hg has been developed and shown to be effective for rapid re-cycling of the reactor system. Unlike previous methods relatively low temperatures are used in a gas and vapor phase process of removal. Importantly, the recovery process is understood in a quantitative manner so that scaling design to larger capacity systems can be easily carried out.

  10. Automated product recovery in a Hg-196 photochemical isotope separation process

    DOE Patents [OSTI]

    Grossman, M.W.; Speer, R.

    1992-07-21

    A method of removing deposited product from a photochemical reactor used in the enrichment of [sup 196]Hg has been developed and shown to be effective for rapid re-cycling of the reactor system. Unlike previous methods relatively low temperatures are used in a gas and vapor phase process of removal. Importantly, the recovery process is understood in a quantitative manner so that scaling design to larger capacity systems can be easily carried out. 2 figs.

  11. Homogeneous and Heterogeneous Reaction and Transformation of Hg and Trace Metals in Combustion Systems

    SciTech Connect (OSTI)

    J. Helble; Clara Smith; David Miller

    2009-08-31

    The overall goal of this project was to produce a working dynamic model to predict the transformation and partitioning of trace metals resulting from combustion of a broad range of fuels. The information provided from this model will be instrumental in efforts to identify fuels and conditions that can be varied to reduce metal emissions. Through the course of this project, it was determined that mercury (Hg) and arsenic (As) would be the focus of the experimental investigation. Experiments were therefore conducted to examine homogeneous and heterogeneous mercury oxidation pathways, and to assess potential interactions between arsenic and calcium. As described in this report, results indicated that the role of SO{sub 2} on Hg oxidation was complex and depended upon overall gas phase chemistry, that iron oxide (hematite) particles contributed directly to heterogeneous Hg oxidation, and that As-Ca interactions occurred through both gas-solid and within-char reaction pathways. Modeling based on this study indicated that, depending upon coal type and fly ash particle size, vaporization-condensation, vaporization-surface reaction, and As-CaO in-char reaction all play a role in arsenic transformations under combustion conditions.

  12. Evaluation of HgI[sub 2] detectors for lead detection in paint

    SciTech Connect (OSTI)

    Wang, Y.J.; Iwanczyk, J.S.; Graham, W.R. )

    1993-08-01

    The authors conducted a laboratory study of HgI[sub 2] spectrometers used for in-situ determination of lead on painted surfaces. [sup 109]Cd and [sup 57]Co isotopes have been used to excite lead characteristic x-rays from samples. The energy resolution of HgI[sub 2] detectors in the energy region corresponding to lead K x-rays has been measured. An energy resolution of 880 eV (FWHM) for the 60 keV line from an [sup 241]Am source has been obtained. Measurements using thin film standards ranging from 0.5 mg Pb/cm[sup 2] to 2 mg Pb/cm[sup 2] have been conducted. Detection limits, accuracy and precision of the measurements have been estimated. Based upon a comparison of the results that the authors have obtained with the performance of existing detector technology, the HgI[sub 2] detectors seem to be the best solution for handheld XRF lead analyzers.

  13. Electron-Transfer Collisions of Low-Energy Multicharged Nitrogen-Ions with H-2 and N-2 

    E-Print Network [OSTI]

    Wang, H. Y.; Church, David A.

    1987-01-01

    VOLUME 36, NUMBER 9 NOVEMBER 1, 1987 Electron-transfer collisions of low-energy multicharged nitrogen ions with H2 and N2 Hua-Ying Wang and D. A. Church Department of Physics, Texas A&M University, College Station, Texas 77843-4242 (Received 27 April... 1987) A stored-ion collision technique has been used to study the charge-changing collisions of mul- ticharged nitrogen ions with H2 and N2 target gases. The ions were produced inside a Penning trap with use of electron-impact ionization. The time...

  14. Computation of the Central Charge for the Leading Order of the N=2 Super-Yang-Mills Effective Action

    E-Print Network [OSTI]

    Sylvain Wolf

    1999-05-26

    The central charge in the N=2 Super-Yang-Mills theory plays an essential role in the work of Seiberg and Witten as it gives the mass spectrum of the BPS states of the quantum theory. Our aim in this note is to present a direct computation of this central charge for the leading order (in a momentum expansion) of the effective action. We will consider the N=2 Super-Yang-Mills theory with gauge group SU(2). The leading order of the effective action is given by the same holomorphic function F appearing in the low energy U(1) effective action.

  15. Measurements of Dynamic Characteristics of Hg Jet Stream 11/16/2005 by HeeJin Park, SUNY Stony Brook

    E-Print Network [OSTI]

    McDonald, Kirk

    Measurements of Dynamic Characteristics of Hg Jet Stream 11/16/2005 by HeeJin Park, SUNY Stony Brook Purpose : To measure velocity and distortion of jet stream and verify the hydro-dynamic phenomenon

  16. High-pressure dissociation of silver mercury iodide, Ag{sub 2}HgI{sub 4}

    SciTech Connect (OSTI)

    Parfitt, D.C. [Department of Physics, Oxford University, Parks Road, Oxford OX1 3PU (United Kingdom); Hull, S. [ISIS Facility, Rutherford Appleton Laboratory, Chilton, Didcot, OX11 0QX (United Kingdom)]. E-mail: s.hull@rl.ac.uk; Keen, D.A. [Department of Physics, Oxford University, Parks Road, Oxford OX1 3PU (United Kingdom); ISIS Facility, Rutherford Appleton Laboratory, Chilton, Didcot, OX11 0QX (United Kingdom); Crichton, W. [ESRF, 6 Rue Jules Horowitz, BP 220, 38043 Grenoble CEDEX 9 (France)

    2004-10-01

    High-pressure X-ray diffraction has been used to probe the behavior of the superionic conductor silver mercury iodide (Ag{sub 2}HgI{sub 4}) at pressures up to 5GPa and at temperatures from 295 to 370K. Significant changes in the diffraction spectra, indicative of structural transitions, are observed around 0.7 and 1.3GPa across the range of temperatures studied. The change at 0.7GPa is shown to correspond to the dissociation of silver mercury iodide into silver iodide and mercury iodide, i.e., Ag{sub 2}HgI{sub 4}->2AgI+HgI{sub 2}. The second transition, at 1.3GPa, is due to a structural phase transition within HgI{sub 2}. Rietveld analysis of the diffraction data is used to confirm and refine all the known crystal structures.

  17. Total and organic Hg concentrations in cephalopods from the North Eastern Atlantic waters: influence of geographical origin and feeding

    E-Print Network [OSTI]

    Boyer, Edmond

    %). With the exception of oceanic squids, the digestive gland globally displayed higher T-Hg concentrations than its toxicity as a result of its enhanced penetration through lipid membranes (Boudou et al. 1983

  18. Biokinetics of Hg and Pb accumulation in the encapsulated egg of the1 common cuttlefish Sepia officinalis: radiotracer experiments2

    E-Print Network [OSTI]

    Boyer, Edmond

    with the32 eggshell indicating that the latter acted as an efficient shield against metal penetration. From the Ocean (Cossa et al., 2002). Hg and Pb are also discharged in coastal waters due to the50 contaminated

  19. Ultrasensitive detection of Hg{sup 2+} using oligonucleotide-functionalized AlGaN/GaN high electron mobility transistor

    SciTech Connect (OSTI)

    Cheng, Junjie; Li, Jiadong; Miao, Bin; Wu, Dongmin; Wang, Jine; Pei, Renjun; Wu, Zhengyan

    2014-08-25

    An oligonucleotide-functionalized ion sensitive AlGaN/GaN high electron mobility transistor (HEMT) was fabricated to detect trace amounts of Hg{sup 2+}. The advantages of ion sensitive AlGaN/GaN HEMT and highly specific binding interaction between Hg{sup 2+} and thymines were combined. The current response of this Hg{sup 2+} ultrasensitive transistor was characterized. The current increased due to the accumulation of Hg{sup 2+} ions on the surface by the highly specific thymine-Hg{sup 2+}-thymine recognition. The dynamic linear range for Hg{sup 2+} detection has been determined in the concentrations from 10{sup ?14} to 10{sup ?8} M and a detection limit below 10{sup ?14} M level was estimated, which is the best result of AlGaN/GaN HEMT biosensors for Hg{sup 2+} detection till now.

  20. HNO3, N2O5, and ClONO2 enhancements after the OctoberNovember 2003 solar proton

    E-Print Network [OSTI]

    Jackman, Charles H.

    HNO3, N2O5, and ClONO2 enhancements after the October­November 2003 solar proton events M. Lo-energy protons which reached the Earth and penetrated into the middle atmosphere in the polar regions solar proton events. Two distinct HNO3 enhancements were observed. An instantaneous increase of 1­2 ppbv

  1. Nitrous Oxide Nitrous oxide (chemical formula N2O), is a trace gas in Earth's atmosphere, with a

    E-Print Network [OSTI]

    Stevenson, David

    is from the use of nitrogenous fertilizer in the agricultural sector; others include combustion of fossil radiative forcing following a 1 kg pulse emission of N2O, relative to the same quantity following a 1 kg pulse emission of CO2. The GWP time horizon must also be specified ­ typically it is 100 yr, but IPCC

  2. Accurate Modeling of the Siemens S7 SCADA ... JDFSL V9N2 ACCURATE MODELING OF THE SIEMENS S7

    E-Print Network [OSTI]

    Wool, Avishai

    Accurate Modeling of the Siemens S7 SCADA ... JDFSL V9N2 ACCURATE MODELING OF THE SIEMENS S7 SCADA is commonly used in SCADA systems for communications between a Human Machine Interface (HMI.82% of the traffic was identified as normal. Keywords: network, intrusion-detection, SCADA, S7 1. INTRODUCTION

  3. 19Agrociencia (2008) Vol XII N 2 pg. 19 -30 Botryosphaeriaceae from Eucalyptus and Native Myrtaceae in

    E-Print Network [OSTI]

    2008-01-01

    19Agrociencia (2008) Vol XII N° 2 pág. 19 - 30 Botryosphaeriaceae from Eucalyptus and Native on plantation grown Eucalyptus globulus. These fungi also exist as endophytes in healthy Eucalyptus leaves that species of the Botryosphaeriaceae, other than those previously reported, could cause cankers on Eucalyptus

  4. MRC Technique for RNS to Decimal Conversion Using the Moduli Set {2n + 2, 2n + 1, 2n}

    E-Print Network [OSTI]

    Cotofana, Sorin

    MRC Technique for RNS to Decimal Conversion Using the Moduli Set {2n + 2, 2n + 1, 2n} Kazeem Alagbe, Navrongo, Ghana. Abstract--This paper investigates the conversion of Residue Number System (RNS) operands to decimal, which is an important issue concerning the utilization of RNS numbers in digital signal

  5. An Improved RNS Reverse Converter for the {22n+1 -1,2n,2n -1} Moduli Set

    E-Print Network [OSTI]

    Cotofana, Sorin

    An Improved RNS Reverse Converter for the {22n+1 -1,2n,2n -1} Moduli Set K.A. Gbolagade1,2, R Residue Number Systems (RNS) have significant ad- vantages over conventional binary number systems tolerance. RNS have been widely applied in Digital Signal Pro- cessing (DSP) applications [5]. However

  6. An Efficient RNS to Binary Converter Using the Moduli Set {2n + 1, 2n, 2n -1}

    E-Print Network [OSTI]

    Cotofana, Sorin

    An Efficient RNS to Binary Converter Using the Moduli Set {2n + 1, 2n, 2n - 1} Kazeem Alagbe System (RNS) to decimal conversion which is an important issue concerning the utilization of RNS numbers System (RNS) is an unweighted number system with inherent parallel characteristics, which supports carry

  7. Dynamics of NO reduction by H2 on Rh(111): Velocity and angular distributions of the N2 product

    E-Print Network [OSTI]

    Sibener, Steven

    examine the dynamics of the NO H2 reaction on the Rh 111 surface by measuring the velocity distribution. Product velocity distributions have been measured for a number of surface reactions, and show a wideDynamics of NO reduction by H2 on Rh(111): Velocity and angular distributions of the N2 product J

  8. Chemical spots and their dynamical evolution on HgMn stars

    E-Print Network [OSTI]

    Korhonen, Heidi; Briquet, Maryline; Gonzalez, Federico; Savanov, Igor

    2010-01-01

    Our recent studies of late B-type stars with HgMn peculiarity revealed for the first time the presence of fast dynamical evolution of chemical spots on their surfaces. These observations suggest a hitherto unknown physical process operating in the stars with radiative outer envelopes. Furthermore, we have also discovered existence of magnetic fields on these stars that have up to now been thought to be non-magnetic. Here we will discuss the dynamical spot evolution on HD 11753 and our new results on magnetic fields on AR Aur.

  9. Quantum Anomalous Hall Effect in Hg_1-yMn_yTe Quantum Wells

    SciTech Connect (OSTI)

    Liu, Chao-Xing; /Tsinghua U., Beijing /Stanford U., Phys. Dept.; Qi, Xiao-Liang; /Stanford U., Phys. Dept.; Dai, Xi; Fang, Zhong; /Beijing, Inst. Phys.; Zhang, Shou-Cheng; /Stanford U., Phys. Dept.

    2010-03-19

    The quantum Hall effect is usually observed when the two-dimensional electron gas is subjected to an external magnetic field, so that their quantum states form Landau levels. In this work we predict that a new phenomenon, the quantum anomalous Hall effect, can be realized in Hg{sub 1-y}Mn{sub y}Te quantum wells, without the external magnetic field and the associated Landau levels. This effect arises purely from the spin polarization of the Mn atoms, and the quantized Hall conductance is predicted for a range of quantum well thickness and the concentration of the Mn atoms. This effect enables dissipationless charge current in spintronics devices.

  10. Quantum Hall effect in HgTe quantum wells at nitrogen temperatures

    SciTech Connect (OSTI)

    Kozlov, D. A. Kvon, Z. D.; Mikhailov, N. N.; Dvoretskii, S. A.; Weishäupl, S.; Krupko, Y.; Portal, J.-C.

    2014-09-29

    We report on the observation of quantized Hall plateaus in a system of two-dimensional Dirac fermions, implemented in a 6.6?nm HgTe quantum well at magnetic fields up to 34?T at nitrogen temperatures. The activation energies determined from the temperature dependence of the longitudinal resistivity are found to be almost equal for the filling factors ? of 1 and 2. This indicates that the large values of the g-factor (about 30–40) remain unchanged at very strong magnetic fields.

  11. Quantum Hall Effect in n-p-n and n-2D Topological Insulator-n Junctions G. M. Gusev,1

    E-Print Network [OSTI]

    Gusev, Guennady

    Quantum Hall Effect in n-p-n and n-2D Topological Insulator-n Junctions G. M. Gusev,1 A. D. Levin,1 TI) with locally controlled density allowing n-p-n and n-2D TI-n junctions. The resistance reveals quantization in the graphene p-n [1] or n-p-n [2,3] junctions, which has been attributed to chiral edge states

  12. Determination of the cross sections of (n,2n), (n,gamma) nuclear reactions on germanium isotopes at the energy of neutrons 13.96 MeV

    E-Print Network [OSTI]

    S. V. Begun; O. G. Druzheruchenko; O. O. Pupirina; V. K. Tarakanov

    2007-01-23

    The cross sections of 70Ge(n,2n)69Ge, 72Ge(n,2n)71Ge, 76Ge(n,gamma)77(g+0.21m)Ge, 76Ge(n,2n)75Ge nuclear reactions were measured at the energy of neutrons 13.96(6) MeV by activation method with gamma-ray and X-ray spectra studies.

  13. Exact results for ${\\cal N}=2$ supersymmetric gauge theories on compact toric manifolds and equivariant Donaldson invariants

    E-Print Network [OSTI]

    Bershtein, Mikhail; Ronzani, Massimiliano; Tanzini, Alessandro

    2015-01-01

    We provide a contour integral formula for the exact partition function of ${\\cal N}=2$ super-symmetric $U(N)$ gauge theories on compact toric four-manifolds by means of supersymmetric localisation. We perform the explicit evaluation of the contour integral for $U(2)$ ${\\cal N}=2$ theory on $\\mathbb{P}^2$ for all instanton numbers. In the zero mass case, corresponding to the ${\\cal N}=4$ supersymmetric gauge theory, we obtain the generating function of the Euler characteristics of instanton moduli spaces in terms of quasi-modular forms. In the decoupling limit of infinite mass we find that the generating function of local and surface observables computes equivariant Donaldson invariants, thus proving in this case a long-standing conjecture by N. Nekrasov. In the case of vanishing first Chern class the resulting equivariant Donaldson polynomials are new.

  14. Impact of air-exposure on the chemical and electronic structure ofZnO:Zn3N2 thin films

    SciTech Connect (OSTI)

    Bar, M.; Ahn, K.-S.; Shet, S.; Yan, Y.; Weinhardt, L.; Fuchs, O.; Blum, M.; Pookpanratana, S.; George, K.; Yang, W.; Denlinger, J.D.; Al-Jassim, M.; Heske, C.

    2008-09-08

    The chemical and electronic surface structure of ZnO:Zn3N2 ("ZnO:N") thin films with different N contents was investigated by soft x-ray emission spectroscopy. Upon exposure to ambient air (in contrast to storage in vacuum), the chemical and electronic surface structure of the ZnO:N films changes substantially. In particular, we find that the Zn3N2/(Zn3N2+ZnO) ratio decreases with exposure time and that this change depends on the initial N content. We suggest a degradation mechanism based on the reaction of the Zn3N2 content with atmospheric humidity.

  15. N = 2 superconformal algebra in NSR string and Gepner approach to space-time supersymmetry in ten dimensions

    E-Print Network [OSTI]

    Belavin, Alexander

    2015-01-01

    The fermionic NSR string possesses a hidden N = 2 superconformal algebra on the world-sheet. In this work, we show how to use an isomorphism of this algebra, the so-called spectral flow, for construction of a subspace of physical states of the string, on which space-time supersymmetry acts. This construction is an alternative to the GSO-projection in string theory.

  16. Report on International Collaboration Involving the FE Heater and HG-A Tests at Mont Terri

    SciTech Connect (OSTI)

    Houseworth, Jim; Rutqvist, Jonny; Asahina, Daisuke; Chen, Fei; Vilarrasa, Victor; Liu, Hui-Hai; Birkholzer, Jens

    2013-11-06

    Nuclear waste programs outside of the US have focused on different host rock types for geological disposal of high-level radioactive waste. Several countries, including France, Switzerland, Belgium, and Japan are exploring the possibility of waste disposal in shale and other clay-rich rock that fall within the general classification of argillaceous rock. This rock type is also of interest for the US program because the US has extensive sedimentary basins containing large deposits of argillaceous rock. LBNL, as part of the DOE-NE Used Fuel Disposition Campaign, is collaborating on some of the underground research laboratory (URL) activities at the Mont Terri URL near Saint-Ursanne, Switzerland. The Mont Terri project, which began in 1995, has developed a URL at a depth of about 300 m in a stiff clay formation called the Opalinus Clay. Our current collaboration efforts include two test modeling activities for the FE heater test and the HG-A leak-off test. This report documents results concerning our current modeling of these field tests. The overall objectives of these activities include an improved understanding of and advanced relevant modeling capabilities for EDZ evolution in clay repositories and the associated coupled processes, and to develop a technical basis for the maximum allowable temperature for a clay repository. The R&D activities documented in this report are part of the work package of natural system evaluation and tool development that directly supports the following Used Fuel Disposition Campaign (UFDC) objectives: ? Develop a fundamental understanding of disposal-system performance in a range of environments for potential wastes that could arise from future nuclear-fuel-cycle alternatives through theory, simulation, testing, and experimentation. ? Develop a computational modeling capability for the performance of storage and disposal options for a range of fuel-cycle alternatives, evolving from generic models to more robust models of performance assessment. For the purpose of validating modeling capabilities for thermal-hydro-mechanical (THM) processes, we developed a suite of simulation models for the planned full-scale FE Experiment to be conducted in the Mont Terri URL, including a full three-dimensional model that will be used for direct comparison to experimental data once available. We performed for the first time a THM analysis involving the Barcelona Basic Model (BBM) in a full three-dimensional field setting for modeling the geomechanical behavior of the buffer material and its interaction with the argillaceous host rock. We have simulated a well defined benchmark that will be used for codeto- code verification against modeling results from other international modeling teams. The analysis highlights the complex coupled geomechanical behavior in the buffer and its interaction with the surrounding rock and the importance of a well characterized buffer material in terms of THM properties. A new geomechanical fracture-damage model, TOUGH-RBSN, was applied to investigate damage behavior in the ongoing HG-A test at Mont Terri URL. Two model modifications have been implemented so that the Rigid-Body-Spring-Network (RBSN) model can be used for analysis of fracturing around the HG-A microtunnel. These modifications are (1) a methodology to compute fracture generation under compressive stress conditions and (2) a method to represent anisotropic elastic and strength properties. The method for computing fracture generation under compressive load produces results that roughly follow trends expected for homogeneous and layered systems. Anisotropic properties for the bulk rock were represented in the RBSN model using layered heterogeneity and gave bulk material responses in line with expectations. These model improvements were implemented for an initial model of fracture damage at the HG-A test. While the HG-A test model results show some similarities with the test observations, differences between the model results and observations remain.

  17. IDS120h GEOMETRY WITH MODIFIED Hg POOL VESSEL SIMULATIONS FOR 60% W + 40% He SHIELDING (P11/P12 'POINTS') (CONT.)

    E-Print Network [OSTI]

    McDonald, Kirk

    IDS120h GEOMETRY WITH MODIFIED Hg POOL VESSEL SIMULATIONS FOR 60% W + 40% He SHIELDING (P11/P12hm: (m IS FOR) modified Hg pool vessel IN IDS120h. # 1E5 AND 5E5 SIMULATIONS COMPARISON = y = 0.12 cm. 2 #12;3 IDS120hm GEOMETRY = IDS120h WITH MODIFIED Hg POOL VESSEL AND SHIFTED Be WIDOW

  18. Optical emission spectroscopy of metal-halide lamps: Radially resolved atomic state distribution functions of Dy and Hg

    SciTech Connect (OSTI)

    Nimalasuriya, T.; Flikweert, A.J.; Stoffels, W.W.; Haverlag, M.; Mullen, J.J.A.M. van der; Pupat, N.B.M. [Department of Applied Physics, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven (Netherlands); Ecole Nationale Superieure de Chimie de Paris, 11 Rue Pierre et Marie Curie, 75005 Paris (France)

    2006-03-01

    Absolute line intensity measurements are performed on a metal-halide lamp. Several transitions of atomic and ionic Dy and atomic Hg are measured at different radial positions from which we obtain absolute atomic and ionic Dy intensity profiles. From these profiles we construct the radially resolved atomic state distribution function (ASDF) of the atomic and ionic Dy and the atomic Hg. From these ASDFs several quantities are determined as functions of radial position, such as the (excitation) temperature, the ion ratio Hg{sup +}/Dy{sup +}, the electron density, the ground state, and the total density of Dy atoms and ions. Moreover, these ASDFs give us insight about the departure from equilibrium. The measurements show a hollow density profile for the atoms and the ionization of atoms in the center. In the outer parts of the lamp molecules dominate.

  19. H.G. Okuno and M. Ali (Eds.): IEA/AIE 2007, LNAI 4570, pp. 444453, 2007. Springer-Verlag Berlin Heidelberg 2007

    E-Print Network [OSTI]

    Cho, Sung-Bae

    H.G. Okuno and M. Ali (Eds.): IEA/AIE 2007, LNAI 4570, pp. 444­453, 2007. © Springer-Verlag Berlin

  20. H.G. Okuno and M. Ali (Eds.): IEA/AIE 2007, LNAI 4570, pp. 621632, 2007. Springer-Verlag Berlin Heidelberg 2007

    E-Print Network [OSTI]

    Bosse, Tibor

    H.G. Okuno and M. Ali (Eds.): IEA/AIE 2007, LNAI 4570, pp. 621­632, 2007. © Springer-Verlag Berlin

  1. H.G. Okuno and M. Ali (Eds.): IEA/AIE 2007, LNAI 4570, pp. 796805, 2007. Springer-Verlag Berlin Heidelberg 2007

    E-Print Network [OSTI]

    Cho, Sung-Bae

    H.G. Okuno and M. Ali (Eds.): IEA/AIE 2007, LNAI 4570, pp. 796­805, 2007. © Springer-Verlag Berlin

  2. SYNTHESIS OF THE FULLY PROTECTED PHOSPHORAMIDITE OF THE BENZENE-DNA ADDUCT, N2- (4-HYDROXYPHENYL)-2'-DEOXYGUANOSINE AND INCORPORATION OF THE LATER INTO DNA OLIGOMERS

    SciTech Connect (OSTI)

    Chenna, Ahmed; Gupta, Ramesh C.; Bonala, Radha R.; Johnson, Francis; Huang, Bo

    2008-06-09

    N2-(4-Hydroxyphenyl)-2'-deoxyguanosine-5'-O-DMT-3'-phosphoramidite has been synthesized and used to incorporate the N2-(4-hydroxyphenyl)-2'-dG (N2-4-HOPh-dG) into DNA, using solid-state synthesis technology. The key step to obtaining the xenonucleoside is a palladium (Xantphos-chelated) catalyzed N2-arylation (Buchwald-Hartwig reaction) of a fully protected 2'-deoxyguanosine derivative by 4-isobutyryloxybromobenzene. The reaction proceeded in good yield and the adduct was converted to the required 5'-O-DMT-3'-O-phosphoramidite by standard methods. The latter was used to synthesize oligodeoxynucleotides in which the N2-4-HOPh-dG adduct was incorporated site-specifically. The oligomers were purified by reverse-phase HPLC. Enzymatic hydrolysis and HPLC analysis confirmed the presence of this adduct in the oligomers.

  3. Abundance analysis of SB2 binary stars with HgMn primaries

    E-Print Network [OSTI]

    T. Ryabchikova

    1998-05-06

    We present a short review of the abundances in the atmospheres of SB2 systems with Mercury-Manganese (HgMn) primaries. Up to now a careful study has been made for both components of 8 out of 17 known SB2 binaries with orbital periods shorter than 100 days and mass ratio ranging from 1.08 to 2.2. For all eight systems we observe a lower Mn abundance in the secondary's atmospheres than in the primary's. Significant difference in the abundances is also found for some peculiar elements such as Ga, Xe, Pt. All secondary stars with effective temperatures less than 10000 K show abundance characteristics typical of the metallic-line stars.

  4. BPS black holes in a non-homogeneous deformation of the stu model of $N=2$, $D=4$ gauged supergravity

    E-Print Network [OSTI]

    Dietmar Klemm; Alessio Marrani; Nicolò Petri; Camilla Santoli

    2015-07-20

    We consider a deformation of the well-known stu model of $N=2$, $D=4$ supergravity, characterized by a non-homogeneous special K\\"{a}hler manifold, and by the smallest electric-magnetic duality Lie algebra consistent with its upliftability to five dimensions. We explicitly solve the BPS attractor equations and construct static supersymmetric black holes with radial symmetry, in the context of $\\text{U}(1)$ dyonic Fayet-Iliopoulos gauging, focussing on axion-free solutions. Due to non-homogeneity of the scalar manifold, the model evades the analysis recently given in the literature. The relevant physical properties of the resulting black hole solution are discussed.

  5. BPS black holes in a non-homogeneous deformation of the stu model of $N=2$, $D=4$ gauged supergravity

    E-Print Network [OSTI]

    Klemm, Dietmar; Petri, Nicolò; Santoli, Camilla

    2015-01-01

    We consider a deformation of the well-known stu model of $N=2$, $D=4$ supergravity, characterized by a non-homogeneous special K\\"{a}hler manifold, and by the smallest electric-magnetic duality Lie algebra consistent with its upliftability to five dimensions. We explicitly solve the BPS attractor equations and construct static supersymmetric black holes with radial symmetry, in the context of $\\text{U}(1)$ dyonic Fayet-Iliopoulos gauging, focussing on axion-free solutions. Due to non-homogeneity of the scalar manifold, the model evades the analysis recently given in the literature. The relevant physical properties of the resulting black hole solution are discussed.

  6. A $\\mathcal{N}=2$ Supersymmetric $AdS_4$ Solution in M-theory with Purely Magnetic Flux

    E-Print Network [OSTI]

    Yolanda Lozano; Niall T. Macpherson; Jesús Montero

    2015-07-10

    We find a new $\\mathcal{N}=2$ $AdS_4$ solution in M-theory supported by purely magnetic flux via a sequence of abelian and non-abelian T-dualities. This provides the second known example in this class besides the uplift of the Pernici and Sezgin solution to 7d gauged supergravity constructed in the eighties. We compute the free energy of the solution, and show that it scales as $N^{3/2}$. It is intriguing that even though the natural holographic interpretation is in terms of M5-branes wrapped on a special Lagrangian 3-cycle, this solution does not exhibit the expected $N^3$ behavior.

  7. Irradiation damage studies of high power accelerator materials N. Simos a,1,*, H.G. Kirk a

    E-Print Network [OSTI]

    McDonald, Kirk

    and composites. These new high-perfor- mance materials, which appear to possess the right combination to proton beams to assess the survivability potential of these new alloys and composite materials. WhileIrradiation damage studies of high power accelerator materials N. Simos a,1,*, H.G. Kirk a , P

  8. Pinning lattice: Effect of rhenium doping on the microstructural evolution from Tl-2212 to Hg-1212 films during cation exchange

    E-Print Network [OSTI]

    Wu, Judy; Zhao, H.

    2004-08-15

    them. HgBa2CaCu2O6 films obtained from these Re-doped Tl-2212 precursor films have much improved microstructures with the pore dimension reduced by an order of magnitude. (C) 2004 American Institute of Physics....

  9. Accretions of Dark Matter and Dark Energy onto ($n+2$)-dimensional Schwarzschild Black Hole and Morris-Thorne Wormhole

    E-Print Network [OSTI]

    Ujjal Debnath

    2015-03-06

    We have studied accretion of the dark matter and dark energy onto of $(n+2)$-dimensional Schwarzschild black hole and Morris-Thorne wormhole. The mass and the rate of change of mass for $(n+2)$-dimensional Schwarzschild black hole and Morris-Thorne wormhole have been found. We have assumed some candidates of dark energy like holographic dark energy, new agegraphic dark energy, quintessence, tachyon, DBI-essence, etc. The black hole mass and the wormhole mass have been calculated in term of redshift when dark matter and above types of dark energies accrete onto them separately. We have shown that the black hole mass increases and wormhole mass decreases for holographic dark energy, new agegraphic dark energy, quintessence, tachyon accretion and the slope of increasing/decreasing of mass sensitively depends on the dimension. But for DBI-essence accretion, the black hole mass first increases and then decreases and the wormhole mass first decreases and then increases and the slope of increasing/decreasing of mass not sensitively depends on the dimension.

  10. Coupling of alcohols to ethers: The dominance of the surface S{sub N}2 reaction pathway

    SciTech Connect (OSTI)

    Klier, K.; Feeley, O.C.; Johansson, M.; Herman, R.G.

    1996-12-31

    Coupling of alcohols to ethers, important high value oxygenates, proceeds on acid catalysts via general pathways that uniquely control product composition, oxygen retention, chirality inversion, and kinetics. The dominant pathway is the S{sub N}2 reaction with competition of the alcohols for the surface acid sites. This is exemplified by formation of methyl(ethyl) isobutylether (M(E)IBE) from methanol(ethanol)/isobutanol mixtures, retention of oxygen ({sup 18}O) of the heavier alcohol, and optimum rate as a function of concentration of either reactant alcohol. The S{sub N}2 pathway in the confinement of zeolite pores exhibits additional features of a near-100% selectivity to dimethylether (DME) in H-mordenite and a near-100% selectivity to chiral inversion in 2-pentanol/ethanol coupling to 2-ethoxypentane in HZSM-5. A minor reaction pathway entails olefin or carbenium intermediates, as exemplified by the formation of methyl tertiarybutyl ether (MTBE) from methanol/isobutanol mixtures with oxygen retention of the lighter alcohol. Calculations of transition state and molecular modeling of the oxonium-involving pathways dramatically demonstrate how the reaction path selects the products.

  11. Effects of EGR, water/N2/CO2 injection and oxygen enrichment on the availability destroyed due to combustion for a range of conditions and fuels 

    E-Print Network [OSTI]

    Sivadas, Hari Shanker

    2009-06-02

    This study was directed at examining the effects of exhaust gas recirculation (EGR), water/N2/CO2 injections and oxygen enrichment on availability destroyed because of combustion in simple systems like those of constant ...

  12. Lean NOx Trap Regeneration Selectivity Towards N2O-- Similarities and Differences Between H2, CO and C3H6 Reductants

    Broader source: Energy.gov [DOE]

    At lower-intermediate exhaust temperatures, N2O is emitted in two peaks. This presentation uses a global model for the primary and secondary peaks to explain the chemical reactions.

  13. Temperature- and frequency-dependent dielectric properties of organic–inorganic hybrid compound: (C{sub 6}H{sub 9}N{sub 2}){sub 2}(Hg{sub 0.75}Cd{sub 0.25})Cl{sub 4}

    SciTech Connect (OSTI)

    Elwej, R. Hamdi, M.; Hannachi, N.; Hlel, F.

    2015-02-15

    Highlights: • We have synthesized a new hybrid compound of composition (C6H9N2)2(Hg0.75Cd0.25)Cl4. • The Ac conductivity of the title material was studied as a function of frequency and temperature. • The dielectric data have been analyzed in modulus formalism using KWW. - Abstract: The bis-2-amino-4-picolinium tetrachloromercurate-cadmate compound (C{sub 6}H{sub 9}N{sub 2}){sub 2}(Hg{sub 0.75}Cd{sub 0.25})Cl{sub 4} was prepared by hydrothermal method and characterized by X-ray diffraction (XRD) technique. The electrical properties of the compound were studied using impedance spectroscopy in the frequency and temperature range of 200 Hz–5 MHz and 308–403 K, respectively. The equivalent circuit is modeled by a combination of a parallel Rp//CPE circuit to explain the impedance results. The dielectric data were analyzed using complex electrical modulus M* at various temperatures. The activation energy responsible for the relaxation calculated from the modulus spectra is found to be almost the same as the value obtained from the temperature variation of dc conductivity. The electrical modulus and its scaling behavior are also investigated.

  14. Microstructural evolutions in converting epitaxial Tl2Ba2CaCu2Ox thin films to epitaxial HgBa2CaCu2O6+delta thin films

    E-Print Network [OSTI]

    Wu, Judy; Siegal, M. P.; Xie, Y. Y.; Aytug, T.; Fang, L.

    2003-02-01

    Superconducting HgBa2CaCu2O6+delta (Hg-1212) thin films were obtained from Tl2Ba2CaCu2Ox (Tl-2212) precursor films using a cation-exchange process. In this process, Tl cations on the precursor lattice were thermally excited and then replaced with Hg...

  15. Trap Activation Energy and Transport Parameters of HgI$_2$ Crystals for Bubble-Plasma Diagnostics

    E-Print Network [OSTI]

    M. B. Miller; V. F. Kushniruk; A. V. Sermyagin

    2003-01-13

    In recent data on neutron induced acoustic cavitation in deuterium--containing liquids obtained by neutron measurements it was shown that very high temperatures could arise in some special cases. To study temperature of so--called bubble plasma it is desirable to have micro--detectors of X-rays, which can be prepared on the basis of room--temperature semiconductor detectors, in particular on mercuric iodide ($\\alpha$--HgI$_2$) crystals. Having in view this aim, the properties of gel--grown ($\\alpha$--HgI$_2$) crystals was studied by means of isothermal currents, and trap parameters was estimated. Results are promising for special aim of preparing X-ray detectors with moderate energy resolution needed in bubble--plasma diagnostic, though improving of crystal growing technology is necessary. {\\it PACS:} 29.40.Wk; 52.70.La {\\it Keywords:} X-ray and gamma--ray measurements; semiconductor detectors; mercuric iodide; plasma diagnostics; cavitation

  16. Dynamical evolution of titanium, strontium, and yttrium spots on the surface of the HgMn star HD 11753

    E-Print Network [OSTI]

    Briquet, M; Gonzalez, J F; Hubrig, S; Hackman, T

    2010-01-01

    Aims. We gathered about 100 high-resolution spectra of three typical HgMn (mercury-manganese) stars, HD 11753, HD 53244, and HD 221507, to search for slowly pulsating B-like pulsations and surface inhomogeneous distribution of various chemical elements. Methods. Classical frequency analysis methods were used to detect line profile variability and to determine the variation period. Doppler imaging reconstruction was performed to obtain abundance maps of chemical elements on the stellar surface. Results. For HD 11753, which is the star with the most pronounced variability, distinct spectral line profile changes were detected for Ti, Sr, Y, Zr, and Hg, whereas for HD 53244 and HD 221507 the most variable line profiles belong to the elements Hg and Y, respectively. We derived rotation periods for all three stars from the variations of radial velocities and equivalent widths of spectral lines belonging to inhomogeneously distributed elements: P_rot (HD 11753)=9.54 d, P_rot (HD 53244)=6.16 d, and P_rot (HD 221507)=...

  17. Modeling of electron energy spectra and mobilities in semi-metallic Hg1-xCdxTe quantum wells

    E-Print Network [OSTI]

    Melezhik, E O; Sizov, F F

    2015-01-01

    Electron mobility, energy spectra and intrinsic carrier concentrations in the n-type Hg0.32Cd0.68Te / Hg1-xCdxTe / Hg0.32Cd0.68Te quantum well (QW) in semi-metallic state are numerically modeled. Energy spectra and wave functions were calculated in the framework of the 8-band k-p Hamiltonian. In our model, electron scattering on longitudinal optical phonons, charged impurities, and holes has been taken into account, and the mobility has been calculated by an iterative solution of the Boltzmann transport equation. Our results show that the increase of the electron concentration in the well enhances the screening of the 2D electron gas, decreases the hole concentration, and can ultimately lead to a high electron mobility at liquid nitrogen temperatures. The increase of the electron concentration in the QW could be achieved in situ by delta-doping of barriers or by applying the top-gate potential. Our modeling has shown that for low molar composition x the concentration of holes in the well is high in a wide ran...

  18. Uptake of carbonyl sulfide by silver nitrate impregnated filters: Implications for the measurement of low level atmospheric H 2 S

    E-Print Network [OSTI]

    Cooper, David J; Saltzman, Eric S

    1987-01-01

    Geophys. J.P. Franey, Carbonyl Sulfide: Potential Agent ofJ.E. , The lifetime of carbonyl sulfide in the troposphere,and mass balances of carbonyl sulfide correct•on •s clearly

  19. Uptake of carbonyl sulfide by silver nitrate impregnated filters: implications for the analysis of low level atmospheric H 2 S

    E-Print Network [OSTI]

    Saltzman, ES; Cooper, DJ

    1987-01-01

    Geophys. J.P. Franey, Carbonyl Sulfide: Potential Agent ofJ.E. , The lifetime of carbonyl sulfide in the troposphere,interference from carbonyl sulfide, despite the fact that

  20. Conversion of Full-Scale Wet Scrubbers to Biotrickling Filters for H2S Control at Publicly Owned Treatment Works

    E-Print Network [OSTI]

    ; Conversion; Biological treatment; Air pollution. Introduction Many of the 16,700 publicly owned treatment contact time than chemical scrubbing, hence bioreactors for air treatment required a larger footprint-scale chemical scrubbers treating odorous air at the Sanitation District of Orange County, Calif., were converted

  1. A dsorption of H2 S or SO2 on an activated carbon cloth modified by ammonia treatment

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    by treatment with ammonia/air at 300 8 C or with ammonia/steam at 800 8 C. The pore structure of the samples so prepared was examined by adsorption measurements. Changes in the surface chemistry were assessed by X granular activated carbons with similar pore size distribution [3]. However, the cost of ACFs makes

  2. Modeling of fate and transport of co-injection of H2S with CO2 in deep saline formations

    SciTech Connect (OSTI)

    Zhang, W.; Xu, T.; Li, Y.

    2010-12-15

    The geological storage of CO{sub 2} in deep saline formations is increasing seen as a viable strategy to reduce the release of greenhouse gases into the atmosphere. However, costs of capture and compression of CO{sub 2} from industrial waste streams containing small quantities of sulfur and nitrogen compounds such as SO{sub 2}, H{sub 2}S and N{sub 2} are very expensive. Therefore, studies on the co-injection of CO{sub 2} containing other acid gases from industrial emissions are very important. In this paper, numerical simulations were performed to study the co-injection of H{sub 2}S with CO{sub 2} in sandstone and carbonate formations. Results indicate that the preferential dissolution of H{sub 2}S gas (compared with CO{sub 2} gas) into formation water results in the delayed breakthrough of H{sub 2}S gas. Co-injection of H{sub 2}S results in the precipitation of pyrite through interactions between the dissolved H{sub 2}S and Fe{sup 2+} from the dissolution of Fe-bearing minerals. Additional injection of H{sub 2}S reduces the capabilities for solubility and mineral trappings of CO{sub 2} compared to the CO{sub 2} only case. In comparison to the sandstone (siliciclastic) formation, the carbonate formation is less favorable to the mineral sequestration of CO{sub 2}. Different from CO{sub 2} mineral trapping, the presence of Fe-bearing siliciclastic and/or carbonate is more favorable to the H{sub 2}S mineral trapping.

  3. SYNTHESIS AND CHARACTERIZATION OF CO-AND H2S-TOLERANT ELECTROCATALYSTS FOR PEM FUEL CELL

    SciTech Connect (OSTI)

    Shamsuddin Ilias

    2005-03-29

    The present state-of-art Proton Exchange Membrane Fuel Cell (PEMFC) technology is based on platinum (Pt) as a catalyst for both the fuel (anode) and air (cathode) electrodes. This catalyst is highly active but susceptible to poisoning by CO, which may be present in the H{sub 2}-fuel used or may be introduced during the fuel processing. Presence of trace amount of CO and H{sub 2}S in the H{sub 2}-fuel poisons the anode irreversibly and decreases the performance of the PEMFCs. In an effort to reduce the Pt-loading and improve the PEMFC performance, we propose to synthesize a number of Pt-based binary, ternary, and quaternary electrocatalysts using Ru, Mo, Ir, Ni, and Co as a substitute for Pt. By fine-tuning the metal loadings and compositions of candidate electrocatalysts, we plan to minimize the cost and optimize the catalyst activity and performance in PEMFC. The feasibility of the novel electrocatalysts will be demonstrated in the proposed effort with gas phase CO and H{sub 2}S concentrations typical of those found in reformed fuel gas with coal/natural gas/methanol feedstocks. During this reporting period several bi-metallic electrocatalysts were synthesized using ultra-sonication. These catalysts (Pt/Ru, Pt/Mo and Pt/Ir) were tested in MEAs. From Galvonstatic study the catalytic activity was found in the order of: Pt/Ru/C > Pt/Mo/C > Pt/Ir/C. It appears that electrocatalysts prepared by ultra-sonication process are more active compared to the conventional technique. Work is in progress to further study these catalysts for CO-tolerance in PEMFC and identify potential candidate metals for synthesis of tri-metallic electrocatalysts.

  4. Injection of CO2 with H2S and SO2 and Subsequent Mineral Trapping in Sandstone-Shale Formation

    SciTech Connect (OSTI)

    Xu, Tianfu; Apps, John A.; Pruess, Karsten; Yamamoto, Hajime

    2004-09-07

    Carbon dioxide (CO{sub 2}) injection into deep geologic formations can potentially reduce atmospheric emissions of greenhouse gases. Sequestering less-pure CO{sub 2} waste streams (containing H{sub 2}S and/or SO{sub 2}) would be less expensive or would require less energy than separating CO{sub 2} from flue gas or a coal gasification process. The long-term interaction of these injected acid gases with shale-confining layers of a sandstone injection zone has not been well investigated. We therefore have developed a conceptual model of injection of CO{sub 2} with H{sub 2}S and/or SO{sub 2} into a sandstone-shale sequence, using hydrogeologic properties and mineral compositions commonly encountered in Gulf Coast sediments of the United States. We have performed numerical simulations of a 1-D radial well region considering sandstone alone and a 2-D model using a sandstone-shale sequence under acid-gas injection conditions. Results indicate that shale plays a limited role in mineral alteration and sequestration of gases within a sandstone horizon for short time periods (10,000 years in present simulations). The co-injection of SO{sub 2} results in different pH distribution, mineral alteration patterns, and CO{sub 2} mineral sequestration than the co-injection of H{sub 2}S or injection of CO{sub 2} alone. Simulations generate a zonal distribution of mineral alteration and formation of carbon and sulfur trapping minerals that depends on the pH distribution. The co-injection of SO{sub 2} results in a larger and stronger acidified zone close to the well. Precipitation of carbon trapping minerals occurs within the higher pH regions beyond the acidified zones. In contrast, sulfur trapping minerals are stable at low pH ranges (below 5) within the front of the acidified zone. Corrosion and well abandonment due to the co-injection of SO{sub 2} could be important issues. Significant CO{sub 2} is sequestered in ankerite and dawsonite, and some in siderite. The CO{sub 2} mineral-trapping capability can reach 80 kg per cubic meter of medium. Most sulfur is trapped through alunite precipitation, although some is trapped by anhydrite precipitation and minor amount of pyrite. The addition of the acid gases and induced mineral alteration result in changes in porosity. The limited information currently available on the mineralogy of natural high-pressure acid-gas reservoirs is generally consistent with our simulations.

  5. Modeling of fate and transport of co-injection of H2S with CO2 in deep saline formations

    E-Print Network [OSTI]

    Zhang, W.

    2011-01-01

    capture and compression of CO 2 from industrial waste streams containing small quantities of sulfur and

  6. Combined Theoretical and Experimental Investigation and Design of H2S Tolerant Anode for Solid Oxide Fuel Cells

    SciTech Connect (OSTI)

    Gerardine G. Botte; Damilola Daramola; Madhivanan Muthuvel

    2009-01-07

    A solid oxide fuel cell (SOFC) is a high temperature fuel cell and it normally operates in the range of 850 to 1000 C. Coal syngas has been considered for use in SOFC systems to produce electric power, due to its high temperature and high hydrogen and carbon monoxide content. However, coal syngas also has contaminants like carbon dioxide (CO{sub 2}) and hydrogen sulfide (H{sub 2}S). Among these contaminants, H{sub 2}S is detrimental to electrode material in SOFC. Commonly used anode material in SOFC system is nickel-yttria stabilized zirconia (Ni-YSZ). The presence of H{sub 2}S in the hydrogen stream will damage the Ni anode and hinder the performance of SOFC. In the present study, an attempt was made to understand the mechanism of anode (Ni-YSZ) deterioration by H{sub 2}S. The study used computation methods such as quantum chemistry calculations and molecular dynamics to predict the model for anode destruction by H{sub 2}S. This was done using binding energies to predict the thermodynamics and Raman spectroscopy to predict molecular vibrations and surface interactions. On the experimental side, a test stand has been built with the ability to analyze button cells at high temperature under syngas conditions.

  7. Rate of H2S and CO2 attack on pozzolan-amended Class H well cement under

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTech ConnectSpeedingConnect PulseSummary (Programbatteries as(Journal Article)geologic

  8. Results of Hg speciation testing on tanks 30, 32, and 37 depth samples

    SciTech Connect (OSTI)

    Bannochie, C. J.

    2015-11-30

    The Savannah River National Laboratory (SRNL) was tasked with preparing and shipping samples for Hg speciation by Eurofins Frontier Global Sciences, Inc. in Seattle, WA on behalf of the Savannah River Remediation (SRR) Mercury Task Team. The twelfth shipment of samples was designated to include 3H evaporator system Tank 30, 32, and 37 depth samples. The Tank 30 depth sample (HTF-30-15-70) was taken at 190 inches from the tank bottom and the Tank 32 depth sample (HTF-32-15-68) was taken at 89 inches from the tank bottom and both were shipped to SRNL on June 29, 2015 in an 80 mL stainless steel dip bottles. The Tank 37 surface sample (HTF-37-15-94) was taken around 253.4 inches from the tank bottom and shipped to SRNL on July 21, 2015 in an 80 mL stainless steel dip bottle. All samples were placed in the SRNL Shielded Cells and left unopened until intermediate dilutions were made on July 24, 2015 using 1.00 mL of sample diluted to 100.00 mL with deionized H2O. A 30 mL Teflon® bottle was rinsed twice with the diluted tank sample and then filled leaving as little headspace as possible. It was immediately removed from the Shielded Cells and transferred to refrigerated storage where it remained at 4 °C until final dilutions were made on October 20. A second portion of the cells diluted tank sample was poured into a shielded polyethylene bottle and transferred to Analytical Development for radiochemical analysis data needed for Hazardous Material Transportation calculations.

  9. Chemical evolution of the HC3N and N2H+ molecules in dense cores of the Vela C giant molecular cloud complex

    E-Print Network [OSTI]

    Ohashi, Satoshi; Fujii, Kosuke; Sanhueza, Patricio; Luong, Quang Nguyen; Choi, Minho; Hirota, Tomoya; Mizuno, Norikazu

    2015-01-01

    We have observed the HC3N (J=10-9) and N2H+ (J=1-0) lines toward the Vela C molecular clouds with the Mopra 22 m telescope to study chemical characteristics of dense cores. The intensity distributions of these molecules are similar to each other at an angular resolution of 53", corresponding to 0.19 pc suggesting that these molecules trace the same dense cores. We identified 25 local peaks in the velocity-integrated intensity maps of the HC3N and/or N2H+ emission. Assuming LTE conditions, we calculated the column densities of these molecules and found a tendency that N2H+/HC3N abundance ratio seems to be low in starless regions while it seems to be high in star-forming regions, similar to the tendencies in the NH3/CCS, NH3/HC3N, and N2H+/CCS abundance ratios found in previous studies of dark clouds and the Orion A GMC. We suggest that carbon chain molecules, including HC3N, may trace chemically young molecular gas and N-bearing molecules, such as N2H+, may trace later stages of chemical evolution in the Vela ...

  10. Jacobi Forms of Higher Index and Paramodular Groups in N=2, D=4 Compactifications of String Theory

    E-Print Network [OSTI]

    Caner Nazaroglu

    2013-09-25

    We associate a Jacobi form over a rank s lattice to N=2, D=4 heterotic string compactifications which have s Wilson lines at a generic point in the vector multiplet moduli space. Jacobi forms of index m=1 and m=2 have appeared earlier in the context of threshold corrections to heterotic string couplings. We emphasize that higher index Jacobi forms as well as Jacobi forms of several variables over more generic even lattices also appear and construct models in which they arise. In particular, we construct an orbifold model which can be connected to models that give index m=3, 4 or 5 Jacobi forms through the Higgsing process. Constraints from being a Jacobi form are then employed to get threshold corrections using only partial information on the spectrum. We apply this procedure for index m=3, 4 or 5 Jacobi form examples and also for Jacobi forms over A_2 and A_3 root lattices. Examples with a single Wilson line are examined in detail and we display the relation of Siegel forms over a paramodular group \\Gamma_m to these models, where \\Gamma_m is associated with the T-duality group of the models we study. Finally, results on the heterotic string side are used to clarify the linear mapping of vector multiplet moduli to Type IIA duals without using the one-loop cubic part of the prepotential on the Type II side, and also to give predictions for the geometry of the dual Calabi-Yau manifolds.

  11. Twisted compactification of N=2 5D SCFTs to three and two dimensions from F(4) gauged supergravity

    E-Print Network [OSTI]

    Karndumri, Parinya

    2015-01-01

    We study supersymmetric $AdS_4\\times \\Sigma_2$ and $AdS_3\\times \\Sigma_3$ solutions in half-maximal gauged supergravity in six dimensions with $SU(2)_R\\times SU(2)$ gauge group. The gauged supergravity is obtained by coupling three vector multiplets to the pure $F(4)$ gauged supergravity. The $SU(2)_R$ R-symmetry together with the $SO(3)\\sim SU(2)$ symmetry of the vector multiplets are gauged. The resulting gauged supergravity admits supersymmetric $AdS_6$ critical points with $SO(4)\\sim SU(2)\\times SU(2)$ and $SO(3)\\sim SU(2)_{\\textrm{diag}}$ symmetries. The former corresponds to five-dimensional $N=2$ superconformal field theories (SCFTs) with $E_1\\sim SU(2)$ symmetry. We find new classes of supersymmetric $AdS_4\\times \\Sigma_2$ and $AdS_3\\times \\Sigma_3$ solutions with $\\Sigma_{2,3}$ being $S^{2,3}$ and $H^{2,3}$. These solutions describe SCFTs in three and two dimensions obtained from twisted compactifications of the aforementioned five-dimensional SCFTs with different numbers of unbroken supersymmetry an...

  12. Mechanism of Cation Exchange Process for Epitaxy of Superconducting HgBa2CaCu2O6 Films and Passive Microwave Devices

    E-Print Network [OSTI]

    Zhao, Hua

    2007-12-17

    and the rf JIP3 derived from the IP3 against reduced temperature suggests that the magnetic vortex depinning in HTS materials dominates the microwave nonlinearity at elevated temperatures. These encouraging results have marked Hg-1212 out as a promising...

  13. 1 Managed by UT-Battelle for the U.S. Department of Energy NF/IDS Hg Vessel Layout 30 Jun 09

    E-Print Network [OSTI]

    McDonald, Kirk

    1 Managed by UT-Battelle for the U.S. Department of Energy NF/IDS Hg Vessel Layout 30 Jun 09;3 Managed by UT-Battelle for the U.S. Department of Energy NF/IDS Hg Vessel Layout 30 Jun 09 Cross Section to flow out the front of the cryostat #12;4 Managed by UT-Battelle for the U.S. Department of Energy NF

  14. Defect study in molecular beam epitaxy-grown HgCdTe films with activated and unactivated arsenic

    SciTech Connect (OSTI)

    Izhnin, I. I.; Dvoretsky, S. A.; Mikhailov, N. N.; Varavin, V. S.; Mynbaev, K. D.; Fitsych, O. I.; Pociask-Bialy, M.; Sheregii, E.; Voitsekhovskii, A. V.

    2014-04-28

    A defect study was performed on molecular beam epitaxy-grown HgCdTe films in situ doped with arsenic. Doping was performed from either effusion cell or cracker cell, and studied were both as-grown samples and samples subjected to arsenic activation annealing. Electrical properties of the films were investigated with the use of ion milling as a means of “stirring” defects in the material. As a result of the study, it was confirmed that the most efficient incorporation of electrically active arsenic occurs at the cracking zone temperature of 700?°C. Interaction between arsenic and tellurium during the growth was observed and is discussed in the paper.

  15. Nuclear structure ''southeast'' of {sup 208}Pb: Isomeric states in {sup 208}Hg and {sup 209}Tl

    SciTech Connect (OSTI)

    Al-Dahan, N. [Department of Physics, University of Surrey, Guildford GU2 7XH (United Kingdom); Department of Physics, University of Kerbala, Kerbala (Iraq); Podolyak, Zs.; Regan, P. H.; Alkhomashi, N.; Deo, A. Y.; Farrelly, G.; Steer, S. J.; Cullen, I. J.; Gelletly, W.; Swan, T.; Thomas, J. S.; Walker, P. M. [Department of Physics, University of Surrey, Guildford GU2 7XH (United Kingdom); Gorska, M.; Grawe, H.; Gerl, J.; Pietri, S. B.; Wollersheim, H. J.; Boutachkov, P.; Domingo-Pardo, C.; Farinon, F. [GSI, D-64291 Darmstadt (Germany)] (and others)

    2009-12-15

    The nuclear structure of neutron-rich N>126 nuclei has been investigated following their production via relativistic projectile fragmentation of a E/A=1 GeV {sup 238}U beam. Metastable states in the N=128 isotones {sup 208}Hg and {sup 209}Tl have been identified. Delayed {gamma}-ray transitions are interpreted as arising from the decay of I{sup {pi}}=(8{sup +}) and (17/2{sup +}) isomers, respectively. The data allow for the so far most comprehensive verification of the shell-model approach in the region determined by magic numbers Z<82 and N>126.

  16. 47Agrociencia. (2006) Vol. X N 2 pg. 47 -61 CAMBIOS EN EL USO DE LA TIERRA EN ARGENTINA Y URUGUAY

    E-Print Network [OSTI]

    Nacional de San Luis, Universidad

    2006-01-01

    47Agrociencia. (2006) Vol. X N° 2 pág. 47 - 61 CAMBIOS EN EL USO DE LA TIERRA EN ARGENTINA Y. Buenos Aires, Argentina. 2 Ecología Terrestre, Facultad de Ciencias ­ Universidad de la República. Montevideo. Uruguay. 3 Grupo de Estudios Ambientales ­ Universidad Nacional de San Luis. San Luis. Argentina

  17. UNIVERSITY OF ILLINOIS AT URBANA-CHAMPAIGN S T R AT E G I C P L A N 2 0 1 3 -1 6

    E-Print Network [OSTI]

    Liberzon, Daniel

    , Professsor Department of Physics Robert Hauser, Dean College of ACES Stig Lanesskog, Associate Provost OfficeUNIVERSITY OF ILLINOIS AT URBANA-CHAMPAIGN S T R AT E G I C P L A N 2 0 1 3 - 1 6 #12;Strategic Vice Provost - Office of the Provost Kenneth Ballom, Dean Office of the Dean of Students Jeffrey Brown

  18. Ultrasimple calculation of very-low-energy momentum-transfer and rotational-excitation cross sections: e-N2 scattering

    E-Print Network [OSTI]

    Morrison, Michael A.

    Ultrasimple calculation of very-low-energy momentum-transfer and rotational-excitation cross energies. We apply this method to the calculation of e-N2 momentum-transfer and rotational excitation cross. INTRODUCTION Integral elastic, momentum transfer, and rotational exci- tation cross sections at energies below

  19. Off-shell Invariant D=N=2 Twisted Super Yang-Mills Theory with a Gauged Central Charge without Constraints

    E-Print Network [OSTI]

    Asaka, Keisuke; Kawamoto, Noboru; Miyake, Akiko

    2013-01-01

    We formulate N=2 twisted super Yang-Mills theory with a gauged central charge by superconnection formalism in two dimensions. We obtain off-shell invariant supermultiplets and actions with and without constraints, which is in contrast with the off-shell invariant D=N=4 super Yang-Mills formulation with unavoidable constraints.

  20. Off-shell Invariant D=N=2 Twisted Super Yang-Mills Theory with a Gauged Central Charge without Constraints

    E-Print Network [OSTI]

    Keisuke Asaka; Junji Kato; Noboru Kawamoto; Akiko Miyake

    2013-09-18

    We formulate N=2 twisted super Yang-Mills theory with a gauged central charge by superconnection formalism in two dimensions. We obtain off-shell invariant supermultiplets and actions with and without constraints, which is in contrast with the off-shell invariant D=N=4 super Yang-Mills formulation with unavoidable constraints.

  1. IL NUOVO CIMENTO Vol. 110 B, N. 2 Febbraio 1995 A novel method to detect quantum states of the radiation field

    E-Print Network [OSTI]

    Paris, Matteo G. A.

    . --- We propose a new method for detecting the density matrix of the radiation field via optical homodyneIL NUOVO CIMENTO Vol. 110 B, N. 2 Febbraio 1995 A novel method to detect quantum states of the radiation field G. M. D'Ariano ( 1 )( 2 ), Chiara Macchiavello( 1 ), Matteo G. A. Paris( 1 ) ( 1

  2. Nighttime NO3y chemistry: In situ Observation of the Various Removal Pathways of NO3 and N2O5 around the UK

    E-Print Network [OSTI]

    Jackson, Sophie

    and synoptic wind suggest air mass originated from the European continent; High aerosol organics in this aged on the left shows a typical scenario when urban emitted NO2 was transported to > 3 km, forming N2O5 which and to falling ice were frequently observed (even though days with forecast precipitation were deliberately

  3. Q1 Consider the n = 1 and n = 2 states of an electron in a hydrogen atom. The energy eigenfunctions nlm(r, , ) are

    E-Print Network [OSTI]

    Lee, Tonghun

    Q1 Consider the n = 1 and n = 2 states of an electron in a hydrogen atom. The energy eigenfunctions for the spherical harmonics Y m l (, ) may be found in the formulæ pages at the beginning of the exam. The hydrogen energy due to H is zero. You may do this by either explicit calculation, or by applying selection rules

  4. Modeling impacts of farming management alternatives on CO2, CH4, and N2O emissions: A case study for water management of rice

    E-Print Network [OSTI]

    emissions about 40%, or 5 Tg CH4 yrÀ1 , roughly 5­10% of total global methane emissions from rice paddies contribution to the net climate impact due to the low radiative potential of CO2. The change in water. Introduction [2] Food production contributes approximately 70% of global atmospheric input of nitrous oxide (N2

  5. Optical Nonlinearity in Ar and N2 near the Ionization Threshold J. K. Wahlstrand, Y.-H. Cheng, Y.-H. Chen, and H. M. Milchberg

    E-Print Network [OSTI]

    Milchberg, Howard

    Optical Nonlinearity in Ar and N2 near the Ionization Threshold J. K. Wahlstrand, Y.-H. Cheng, Y measure the nonlinear optical response in argon and nitrogen in a thin gas target to laser intensities.103901 PACS numbers: 42.65.An, 42.65.Jx, 42.65.Re The optical Kerr effect, the intensity-dependent refrac

  6. Evidence for inelastic processes for N3 and N4 from ion energy distributions in He/N2 radio frequency glow discharges

    E-Print Network [OSTI]

    Kushner, Mark

    Evidence for inelastic processes for N3 and N4 from ion energy distributions in He/N2 radio May 1995; accepted for publication 19 September 1995 The ion energy distributions IEDs striking. The importance of the distributions of ion energies and angles striking the wafer in obtaining straight walled

  7. European Journal of Soil Science, December 2010, 61, 903913 doi: 10.1111/j.1365-2389.2009.01217.x Towards an agronomic assessment of N2O emissions

    E-Print Network [OSTI]

    van Kessel, Chris

    that of CO2, and an atmospheric lifetime of about 120 years (IPCC, 2007). It also contributes source of N2O. It has been estimated that total anthropogenic emissions are 6.7 Tg N2O-N year-1, 42 Towards an agronomic assessment of N2O emissions: a case study for arable crops J . W . V a n G r o e n i

  8. The effect of irradiation with electrons on the electrical parameters of Hg{sub 3}In{sub 2}Te{sub 6}

    SciTech Connect (OSTI)

    Grushka, O. G., E-mail: semicon-dpt@chnu.edu.ua [Fedkovich Chernovtsy National University (Ukraine); Maslyuk, V. T. [Ukrainian Academy of Sciences, Institute of Electron Physics (Ukraine); Chupyra, S. M.; Mysliuk, O. M.; Bilichuk, S. V.; Zabolotskiy, I. I. [Fedkovich Chernovtsy National University (Ukraine)

    2012-03-15

    The results of studying the electrical properties of Hg{sub 3}In{sub 2}Te{sub 6} crystals irradiated with electrons with the energy E{sub e} = 18 MeV and the dose D = 4 Multiplication-Sign 10{sup 16} cm{sup -2} are reported. It is shown that, irrespective of the charge-carrier concentration in the initial material, the Hg{sub 3}In{sub 2}Te{sub 6} samples acquire the charge-carrier concentration (1.6-1.8) Multiplication-Sign 10{sup 13} cm{sup -3} after irradiation. The phenomenon of Fermi level pinning in an irradiated material is discussed. The initial charge-carrier concentration, which remains virtually unchanged after irradiation and which ensures the high radiation resistance of Hg{sub 3}In{sub 2}Te{sub 6} crystals, corresponds to a compensated material, similar to an intrinsic semiconductor at T > 260 K.

  9. Multielectron effects in high harmonic generation in N_2 and benzene: simulation using a non-adiabatic quantum molecular dynamics approach for laser-molecule interactions

    E-Print Network [OSTI]

    Dundas, Daniel

    2012-01-01

    A mixed quantum-classical approach is introduced which allows the dynamically response of molecules driven far from equilibrium to be modeled. This method is applied here to the interaction of molecules with intense, short-duration laser pulses. The electronic response of the molecule is described using time-dependent density functional theory (TDDFT) and the resulting Kohn-Sham equations are solved numerically using finite difference techniques in conjunction with local and global adaptations of an underlying grid in curvilinear coordinates. Using this approach, simulations can be carried out for a wide range of molecules and both all-electron and pseudopotential calculations can be performed. The approach is applied to the study of high harmonic generation in N_2 and benzene using linearly-polarized laser pulses and to the best of our knowledge, the results for benzene represent the first TDDFT calculations of high harmonic generation in benzene using linearly polarized laser pulses. For N_2 an enhancement ...

  10. 15N2 formation and fast oxygen isotope exchange during pulsed 15N18O exposure of MnOx/CeO2

    SciTech Connect (OSTI)

    Kwak, Ja Hun; Szanyi, Janos

    2014-12-23

    Pulsing 15N18O onto an annealed 1% Mn16Ox/Ce16O2 catalyst resulted in very fast oxygen isotope exchange and 15N2 formation at 295 K. In the 1st 15N18O pulse, due to the presence of large number of surface oxygen defects, extensive 15N218O and 15N2 formations were observed. In subsequent pulses oxygen isotope exchange dominated as a result of highly labile oxygen in the oxide. We gratefully acknowledge the US Department of Energy (DOE), Office of Energy Efficiency and Renewable Energy/Vehicle Technologies Program for the support of this work. The research described in this paper was performed at the Environmental Molecular Sciences Laboratory (EMSL), a national scientific user facility sponsored by the DOE’s Office of Biological and Environmental Research and located at Pacific Northwest National Laboratory (PNNL). PNNL is operated for the US DOE by Battelle.

  11. Identification and decay of the 0.48 ms 13/2{sup +} isomer in {sup 181}Hg

    SciTech Connect (OSTI)

    Andreyev, A. N.; Antalic, S.; Saro, S.; Ackermann, D.; Comas, V. F.; Heinz, S.; Heredia, J. A.; Hessberger, F. P.; Khuyagbaatar, J.; Kojouharov, I.; Kindler, B.; Lommel, B.; Mann, R.; Cocolios, T. E.; Elseviers, J.; Huyse, M.; Duppen, P. Van; Venhart, M.; Franchoo, S.; Hofmann, S.

    2009-10-15

    A new isomer with a half-life of 0.48(2) ms was identified in the nuclide {sup 181}Hg, which was produced in the complete fusion reaction {sup 40}Ca+{sup 144}Sm{yields}{sup 184}Pb* at the velocity filter SHIP (GSI, Darmstadt). The isomeric state was tentatively assigned a spin-parity of 13/2{sup +}. We propose that this isomer de-excites by a yet unobserved low-energy, strongly converted {gamma}-ray transition, followed by a newly identified cascade composed of a 90.3 keV M1 and a 71.4 keV E2 {gamma}-ray transition.

  12. Measurement of a false electric dipole moment signal from $^{199}$Hg atoms exposed to an inhomogeneous magnetic field

    E-Print Network [OSTI]

    S. Afach; C. A. Baker; G. Ban; G. Bison; K. Bodek; Z. Chowdhuri; M. Daum; M. Fertl; B. Franke; P. Geltenbort; K. Green; M. G. D. van der Grinten; Z. Grujic; P. G. Harris; W. Heil; V. Hélaine; R. Henneck; M. Horras; P. Iaydjiev; S. N. Ivanov; M. Kasprzak; Y. Kermaïdic; K. Kirch; P. Knowles; H. -C. Koch; S. Komposch; A. Kozela; J. Krempel; B. Lauss; T. Lefort; Y. Lemière; A. Mtchedlishvili; O. Naviliat-Cuncic; J. M. Pendlebury; F. M. Piegsa; G. Pignol; P. N. Prashant; G. Quéméner; D. Rebreyend; D. Ries; S. Roccia; P. Schmidt-Wellenburg; N. Severijns; A. Weis; E. Wursten; G. Wyszynski; J. Zejma; J. Zenner; G. Zsigmond

    2015-08-03

    We report on the measurement of a Larmor frequency shift proportional to the electric-field strength for $^{199}{\\rm Hg}$ atoms contained in a volume permeated with aligned magnetic and electric fields. This shift arises from the interplay between the inevitable magnetic field gradients and the motional magnetic field. The proportionality to electric-field strength makes it apparently similar to an electric dipole moment (EDM) signal, although unlike an EDM this effect is P- and T-conserving. We have used a neutron magnetic resonance EDM spectrometer, featuring a mercury co-magnetometer and an array of external cesium magnetometers, to measure the shift as a function of the applied magnetic field gradient. Our results are in good agreement with theoretical expectations.

  13. SNS Target Test Facility: Prototype Hg Operations and Remote Handling Tests P. T. Spampinato, T. W. Burgess, J. B. Chesser, V. B. Graves, and S.L. Schrock

    E-Print Network [OSTI]

    McDonald, Kirk

    SNS Target Test Facility: Prototype Hg Operations and Remote Handling Tests P. T. Spampinato, T. W Neutron Source, Target Test Facility is a full-scale replica of the mercury-target flow loop prototypic target, and numerous pressure sensors. Outside of the loop enclosure, tests were done on a new

  14. Results of Hg speciation testing on 3Q15 tank 50, salt solution feed tank (SSFT), and solvent hold tank (SHT) materials

    SciTech Connect (OSTI)

    Bannochie, C.

    2015-08-13

    The Savannah River National Laboratory (SRNL) was tasked with preparing and shipping samples for Hg speciation by Eurofins Frontier Global Sciences, Inc. in Seattle, WA on behalf of the Savannah River Remediation (SRR) Mercury Task Team. The results are documented in this report.

  15. WRF-Chem model predictions of the regional impacts of N2O5 heterogeneous processes on night-time chemistry over north-western Europe

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lowe, Douglas; Archer-Nicholls, Scott; Morgan, Will; Allan, James D.; Utembe, Steve; Ouyang, Bin; Aruffo, Eleonora; Le Breton, Michael; Zaveri, Rahul A.; di Carlo, Piero; et al

    2015-02-09

    Chemical modelling studies have been conducted over north-western Europe in summer conditions, showing that night-time dinitrogen pentoxide (N2O5) heterogeneous reactive uptake is important regionally in modulating particulate nitrate and has a~modest influence on oxidative chemistry. Results from Weather Research and Forecasting model with Chemistry (WRF-Chem) model simulations, run with a detailed volatile organic compound (VOC) gas-phase chemistry scheme and the Model for Simulating Aerosol Interactions and Chemistry (MOSAIC) sectional aerosol scheme, were compared with a series of airborne gas and particulate measurements made over the UK in July 2010. Modelled mixing ratios of key gas-phase species were reasonably accurate (correlationsmore »with measurements of 0.7–0.9 for NO2 and O3). However modelled loadings of particulate species were less accurate (correlation with measurements for particulate sulfate and ammonium were between 0.0 and 0.6). Sulfate mass loadings were particularly low (modelled means of 0.5–0.7 ?g kg?1air, compared with measurements of 1.0–1.5 ?g kg?1air). Two flights from the campaign were used as test cases – one with low relative humidity (RH) (60–70%), the other with high RH (80–90%). N2O5 heterogeneous chemistry was found to not be important in the low-RH test case; but in the high-RH test case it had a strong effect and significantly improved the agreement between modelled and measured NO3 and N2O5. When the model failed to capture atmospheric RH correctly, the modelled NO3 and N2O5 mixing ratios for these flights differed significantly from the measurements. This demonstrates that, for regional modelling which involves heterogeneous processes, it is essential to capture the ambient temperature and water vapour profiles. The night-time NO3 oxidation of VOCs across the whole region was found to be 100–300 times slower than the daytime OH oxidation of these compounds. The difference in contribution was less for alkenes (× 80) and comparable for dimethylsulfide (DMS). However the suppression of NO3 mixing ratios across the domain by N2O5 heterogeneous chemistry has only a very slight, negative, influence on this oxidative capacity. The influence on regional particulate nitrate mass loadings is stronger. Night-time N2O5 heterogeneous chemistry maintains the production of particulate nitrate within polluted regions: when this process is taken into consideration, the daytime peak (for the 95th percentile) of PM10 nitrate mass loadings remains around 5.6 ?g kg?1air, but the night-time minimum increases from 3.5 to 4.6 ?g kg?1air. The sustaining of higher particulate mass loadings through the night by this process improves model skill at matching measured aerosol nitrate diurnal cycles and will negatively impact on regional air quality, requiring this process to be included in regional models.« less

  16. Multispectrum analysis of the v9 band of 12C2H6: Positions, intensities, self- and N2-broadened half-width coefficients

    SciTech Connect (OSTI)

    Devi, V. Malathy; Rinsland, Curtis P.; Benner, D. C.; Sams, Robert L.; Blake, Thomas A.

    2010-06-01

    Line positions, intensities, Lorentz self- and N2-broadened half-width coefficients have been measured for PQ3, PQ2, PQ1, RQ0,RQ1, RQ2, and RQ3 sub-band transitions in the 9 fundamental band of 12C2H6. A multispectrum nonlinear least-squares fitting technique was used to fit up to 17 high-resolution (~0.00156 cm-1), room temperature absorption spectra of pure (99.99% chemical purity) natural sample of ethane and lean mixtures of the high-purity ethane diluted with N2. A Bruker IFS 120HR Fourier transform spectrometer located at the Pacific Northwest National Laboratory (PNNL), in Richland, Washington was used to record the data. A standard Voigt line shape was assumed to fit all the data since no line mixing or other non Voigt line shapes were required to fit any of the spectra used in the analysis. Short spectral intervals (~2 to 2.5 cm-1) of all 17 spectra covering a specific PQ or RQ sub band were fit simultaneously. For the first time in an ethane band, pressure-broadened half-width coefficients were determined for each of the torsional-split components. Constraints were used such that the half-width coefficients of both torsional-split components were identical for a specific broadening gas. No pressure-induced shift coefficients were necessary to fit the spectra to their noise level. The present study revealed for the first time the dependence of self- and N2-broadened half-width coefficients upon the J, K quantum numbers of the transitions in ethane. A number of transitions belonging to the 9+ 4- 4 and the 9+2 4-2 4 hot bands were also observed in the fitted regions and measurements were made when possible.

  17. R-matrix calculation of integral and differential cross sections for low-energy electron impact excitations of N2 molecule

    E-Print Network [OSTI]

    Motomichi Tashiro; Keiji Morokuma

    2006-12-21

    Low-energy electron impact excitations of N$_2$ molecules are studied using the fixed-bond R-matrix method based on state-averaged complete active space SCF orbitals. Thirteen target electronic states of N$_2$ are included in the model within a valence configuration interaction representations of the target states. Integrated as well as differential cross sections of the $A^{3} \\Sigma_{u}^{+}$, $B^{3} \\Pi_{g}$, $W^{3} \\Delta_{u}$, ${B'}^{3} \\Sigma_{u}^{-}$, ${a'}^{1} \\Sigma_{u}^{-}$, $a^{1} \\Pi_{g}$, $w^{1} \\Delta_{u}$ and $C^{3} \\Pi_{u}$ states are calculated and compared with the previous experimental measurements. These excitations, especially of the higher four states, have not been studied enough theoretically in the previous literature. In general, good agreements are observed both in the integrated and differential cross sections. However, some discrepancies are seen in the integrated cross sections of the $A^{3} \\Sigma_{u}^{+}$ and $C^{3} \\Pi_{u}$ states, especially around a peak structure.

  18. A New Equation of State for CCS Pipeline Transport: Calibration of Mixing Rules for Binary Mixtures of CO2 with N2, O2 and H2

    E-Print Network [OSTI]

    Demetriades, Thomas A

    2015-01-01

    One of the aspects currently holding back commercial scale deployment of carbon capture and storage (CCS) is an accurate understanding of the thermodynamic behaviour of carbon dioxide and relevant impurities during the pipeline transport stage. In this article we develop a general framework for deriving pressure-explicit EoS for impure CO2. This flexible framework facilitates ongoing development of custom EoS in response to new data and computational applications. We use our method to generalise a recent EoS for pure CO2 [Demetriades et al. Proc IMechE Part E, 227 (2013) pp. 117] to binary mixtures with N2, O2 and H2, obtaining model parameters by fitting to experiments made under conditions relevant to CCS-pipeline transport. Our model pertains to pressures up to 16MPa and temperatures between 273K and the critical temperature of pure CO2. In this region, we achieve close agreement with experimental data. When compared to the GERG EoS, our EoS has a comparable level of agreement with CO2 -N2 VLE experiments ...

  19. Population of low-seniority isomeric states of {sup 206}Hg by two-proton knockout reactions at relativistic energies

    SciTech Connect (OSTI)

    Simpson, E. C.; Tostevin, J. A.; Podolyak, Zs.; Regan, P. H.; Steer, S. J. [Department of Physics, Faculty of Engineering and Physical Sciences, University of Surrey, Guildford, Surrey GU2 7XH (United Kingdom)

    2009-12-15

    We consider calculations of direct two-proton removal reactions from a relativistic-energy {sup 208}Pb beam incident on a {sup 9}Be target, leading to the population of two-proton-hole isomeric configurations in {sup 206}Hg. The calculated 5{sup -} and 10{sup +} isomeric state population ratios of 18.8% and 4.7%, respectively, are in fair agreement with the values deduced experimentally (21.9{sub -2.9}{sup +1.2}% and 3.1{sub -1.2}{sup +1.0}%); however, the high density of final states in this case complicates the prediction of isomeric ratios for those states fed by unobserved prompt {gamma}-ray cascades. We also consider and quantify the effects of selection of events, according to the longitudinal momenta of the reaction residues, on the measured isomeric ratios for high-spin final states and, hence, of the potential to exploit such sensitivity to gain further insight into the reaction mechanism.

  20. Results of Hg speciation testing on MCU strip effluent hold tank (SEHT) and decontaminated salt solution hold tank (DSSHT) materials

    SciTech Connect (OSTI)

    Bannochie, C. J.

    2015-09-17

    The Savannah River National Laboratory (SRNL) was tasked with preparing and shipping samples for Hg speciation by Eurofins Frontier Global Sciences, Inc. in Seattle, WA on behalf of the Savannah River Remediation (SRR) Mercury Task Team.i,ii The tenth shipment of samples was designated to include Modular Caustic Side Solvent Extraction Unit (MCU) Strip Effluent Hold Tank (SEHT) and MCU Decontaminated Salt Solution Hold Tank (DSSHT) materials from processing Salt Batch 7b. The MCU SEHT (MCU-15-722) and DSSHT (MCU-15-709) samples were pulled on June 15, 2015. All MCU samples were received at SRNL on June 16, 2015. The DSSHT sample was moved the same day to refrigeration, while the SEHT sample was placed in the Shielded Cells. On July 9, 2015 it was opened and an aliquot diluted 1:100 with Eurofins deionized water and a portion of the diluted sample transferred to a Teflon® bottle prior to moving it to refrigeration that same day. All samples were kept in the dark and refrigerated until final dilutions were prepared for shipment to Eurofins.

  1. Relationship between textural properties, fly ash carbons, and Hg capture in fly ashes derived from the combustion of anthracitic pulverized feed blends

    SciTech Connect (OSTI)

    Isabel Surez-Ruiz; Jose B. Parra

    2007-08-15

    In this work, the textural properties of a series of whole anthracitic-derived fly ashes sampled in eight hoppers from the electrostatic precipitators and their sized fractions (from {gt}150 to {lt}25 {mu}m) are investigated. Data from N{sub 2} adsorption isotherms at 77 K, helium density, and mercury porosimetry have contributed to establish a relationship between the Brunauer-Emmett-Teller (BET) surface areas, VTOT, porosity, carbon content (the type of fly ash carbons), and Hg retention in these fly ashes. The unburned carbons in these ashes are macroporous materials, and they are different from the carbons in fly ashes from classes C and F (the latter derived from the combustion of bituminous coals) and show different textural properties. These ashes represent the end member of the fly ash classes C and F with respect to certain textural properties. Although the BET surface area and VTOT values for the studied samples are the lowest reported, they increase with the increase in carbon content, anisotropic carbon content, and particle size of the ashes. Thus, a positive relationship between all these parameters and Hg capture by the coarser ash fractions was found. The finest fraction of carbons ({lt}25 {mu}m) represented an exception. Although it makes a significant contribution to the total carbon of the whole fly ashes and shows relatively higher surface areas and VTOT values, its Hg concentration was found to be the lowest. This suggests that the type of unburned carbons in the finest fraction and/or other adsorption mechanisms may play a role in Hg concentration. Because the textural properties of anisotropic carbons depend on their subtype and on their origin, the need for its differentiation has been evidenced. 54 refs., 8 figs., 3 tabs.

  2. Weak antilocalization effect in LPE-grown p-Hg0.8Cd0.2Te thin film and the evidence of Te-precipitation

    E-Print Network [OSTI]

    R. Yang; L. M. Wei; G. L. Yu

    2010-06-07

    The weak antilocalization effect is observed in a p-type Hg0.8Cd0.2Te thin film with thickness ~10 micrometers. Based on the analysis of composition, carrier species and excellent fitting of data with a model concerning weak antilocalization effect in Te crystal, the most plausible explanation is that the observed weak antilocalization effect is caused by Te-precipitation.

  3. Influenza A H3N2 subtype virus NS1 protein targets into the nucleus and binds primarily via its C-terminal NLS2/NoLS to nucleolin and fibrillarin

    E-Print Network [OSTI]

    Melén, Krister; Tynell, Janne; Fagerlund, Riku; Roussel, Pascal; Hernandez-Verdun, Danièle; Julkunen, Ilkka

    2012-01-01

    Influenza A H3N2 subtype virus NS1 protein targets into theBinding of the influenza A virus NS1 protein to PKR mediatespathogenic H5N1 influenza virus. Nature 2008, 456:985–988.

  4. Neutron scattering evidence for isolated spin-1/2 ladders in (C5D12N)2CuBr4

    SciTech Connect (OSTI)

    Savici, Andrei T [ORNL; Granroth, Garrett E [ORNL; Broholm, Collin L [ORNL; Pajerowski, Daniel M. [University of Florida, Gainesville; Brown, Craig [National Institute of Standards and Technology (NIST); Talham, Daniel R. [University of Florida, Gainesville; Meisel, Mark W. [University of Florida, Gainesville; Schmidt, K. P. [Technische Universit Dortmund, Germany; Uhrig, G. S. [Technische Universit Dortmund, Germany; Nagler, Stephen E [ORNL

    2009-01-01

    Inelastic neutron scattering was used to determine the spin Hamiltonian for the singlet ground state system (C5D12N)2CuBr4 (BPCB). A 2-leg spin 1/2 ladder model, with J? = 1:084 0:005 meV and Jk = 0:321 0:008 meV, accurately describes the data. The experimental limit on the inter-ladder exchange constant is jJ0j 0.005 meV, and the limit on diagonal, intra-ladder exchange is jJF j 0.1 meV. The experimental ratios of intra-ladder bond energies are consistent with the predictions of continuous unitary transformations calculations.

  5. Stellar (n,{gamma}) cross sections of p-process isotopes. II. {sup 168}Yb, {sup 180}W, {sup 184}Os, {sup 190}Pt, and {sup 196}Hg

    SciTech Connect (OSTI)

    Marganiec, J.; Dillmann, I.; Pardo, C. Domingo; Kaeppeler, F.; Walter, S.

    2010-09-15

    The neutron-capture cross sections of {sup 168}Yb, {sup 180}W, {sup 184}Os, {sup 190}Pt, and {sup 196}Hg have been measured by means of the activation technique. The samples were irradiated in a quasistellar neutron spectrum of kT=25 keV, which was produced at the Karlsruhe 3.7-MV Van de Graaff accelerator via the {sup 7}Li(p,n){sup 7}Be reaction. Systematic uncertainties were investigated in repeated activations with different samples and by variation of the experimental parameters, that is, irradiation times, neutron fluxes, and {gamma}-ray counting conditions. The measured data were converted into Maxwellian-averaged cross sections at kT=30 keV, yielding 1214{+-}61, 624{+-}54, 590{+-}43, 511{+-}46, and 201{+-}11 mb for {sup 168}Yb, {sup 180}W, {sup 184}Os, {sup 190}Pt, and {sup 196}Hg, respectively. The present results either represent first experimental data ({sup 168}Yb, {sup 184}Os, and {sup 196}Hg) or could be determined with significantly reduced uncertainties ({sup 180}W and {sup 190}Pt). These measurements are part of a systematic study of stellar (n,{gamma}) cross sections of the stable p isotopes.

  6. Multi-Pollutant Emissions Control: Pilot Plant Study of Technologies for Reducing Hg, SO3, NOx and CO2 Emissions

    SciTech Connect (OSTI)

    Michael L. Fenger; Richard A. Winschel

    2005-08-31

    A slipstream pilot plant was built and operated to investigate technology to adsorb mercury (Hg) onto the existing particulate (i.e., fly ash) by cooling flue gas to 200-240 F with a Ljungstrom-type air heater or with water spray. The mercury on the fly ash was then captured in an electrostatic precipitator (ESP). An alkaline material, magnesium hydroxide (Mg(OH){sub 2}), is injected into flue gas upstream of the air heater to control sulfur trioxide (SO{sub 3}), which prevents acid condensation and corrosion of the air heater and ductwork. The slipstream was taken from a bituminous coal-fired power plant. During this contract, Plant Design and Construction (Task 1), Start Up and Maintenance (Task 2), Baseline Testing (Task 3), Sorbent Testing (Task 4), Parametric Testing (Task 5), Humidification Tests (Task 6), Long-Term Testing (Task 7), and a Corrosion Study (Task 8) were completed. The Mercury Stability Study (Task 9), ESP Report (Task 11), Air Heater Report (Task 12) and Final Report (Task 14) were completed. These aspects of the project, as well as progress on Public Outreach (Task 15), are discussed in detail in this final report. Over 90% mercury removal was demonstrated by cooling the flue gas to 200-210 F at the ESP inlet; baseline conditions with 290 F flue gas gave about 26% removal. Mercury removal is sensitive to flue gas temperature and carbon content of fly ash. At 200-210 F, both elemental and oxidized mercury were effectively captured at the ESP. Mg(OH){sub 2} injection proved effective for removal of SO{sub 3} and eliminated rapid fouling of the air heater. The pilot ESP performed satisfactorily at low temperature conditions. Mercury volatility and leaching tests did not show any stability problems. No significant corrosion was detected at the air heater or on corrosion coupons at the ESP. The results justify larger-scale testing/demonstration of the technology. These conclusions are presented and discussed in two presentations given in July and September of 2005 and are included in Appendices E and F.

  7. Temporal Nodal Regression and Regional Control After Primary Radiation Therapy for N2-N3 Head-and-Neck Cancer Stratified by HPV Status

    SciTech Connect (OSTI)

    Huang, Shao Hui; O'Sullivan, Brian; Ringash, Jolie; Hope, Andrew; Gilbert, Ralph; Irish, Jonathan; Perez-Ordonez, Bayardo; Weinreb, Ilan; Waldron, John

    2013-12-01

    Purpose: To compare the temporal lymph node (LN) regression and regional control (RC) after primary chemoradiation therapy/radiation therapy in human papillomavirus-related [HPV(+)] versus human papillomavirus-unrelated [HPV(?)] head-and-neck cancer (HNC). Methods and Materials: All cases of N2-N3 HNC treated with radiation therapy/chemoradiation therapy between 2003 and 2009 were reviewed. Human papillomavirus status was ascertained by p16 staining on all available oropharyngeal cancers. Larynx/hypopharynx cancers were considered HPV(?). Initial radiologic complete nodal response (CR) (?1.0 cm 8-12 weeks after treatment), ultimate LN resolution, and RC were compared between HPV(+) and HPV(?) HNC. Multivariate analysis identified outcome predictors. Results: A total of 257 HPV(+) and 236 HPV(?) HNCs were identified. The initial LN size was larger (mean, 2.9 cm vs 2.5 cm; P<.01) with a higher proportion of cystic LNs (38% vs 6%, P<.01) in HPV(+) versus HPV(?) HNC. CR was achieved is 125 HPV(+) HNCs (49%) and 129 HPV(?) HNCs (55%) (P=.18). The mean post treatment largest LN was 36% of the original size in the HPV(+) group and 41% in the HPV(?) group (P<.01). The actuarial LN resolution was similar in the HPV(+) and HPV(?) groups at 12 weeks (42% and 43%, respectively), but it was higher in the HPV(+) group than in the HPV(?) group at 36 weeks (90% vs 77%, P<.01). The median follow-up period was 3.6 years. The 3-year RC rate was higher in the HPV(?) CR cases versus non-CR cases (92% vs 63%, P<.01) but was not different in the HPV(+) CR cases versus non-CR cases (98% vs 92%, P=.14). On multivariate analysis, HPV(+) status predicted ultimate LN resolution (odds ratio, 1.4 [95% confidence interval, 1.1-1.7]; P<.01) and RC (hazard ratio, 0.3 [95% confidence interval 0.2-0.6]; P<.01). Conclusions: HPV(+) LNs involute more quickly than HPV(?) LNs but undergo a more prolonged process to eventual CR beyond the time of initial assessment at 8 to 12 weeks after treatment. Post radiation neck dissection is advisable for all non-CR HPV(?)/non-CR N3 HPV(+) cases, but it may be avoided for selected non-CR N2 HPV(+) cases with a significant LN involution if they can undergo continued imaging surveillance. The role of positron emission tomography for response assessment should be investigated.

  8. Physically Gelled Room-Temperature Ionic Liquid-Based Composite Membranes for CO2/N-2 Separation: Effect of Composition and Thickness on Membrane Properties and Performance

    SciTech Connect (OSTI)

    Nguyen, PT; Voss, BA; Wiesenauer, EF; Gin, DL; Nobe, RD

    2013-07-03

    An aspartame-based, low molecular-weight organic gelator (LMOG) was used to form melt-infused and composite membranes with two different imidazolium-based room-temperature ionic liquids (RTILs) for CO2 separation from N-2. Previous work demonstrated that LMOGs can gel RTILs at low, loading levels, and this aspartame-based LMOG was selected because it has been reported to gel a large number of RTILs. The imidazolium-based RTILs were used because of their inherent good properties for CO2/light gas separations. Analysis of the resulting bulk RTIL/LMOG physical gels showed that these materials have high sol-gel transition temperatures (ca. 135 degrees C) suitable for flue gas applications. Gas permeabilities and burst pressure measurements of thick, melt infused membranes revealed a trade-off between high CO2 permeabilities and good mechanical stability as a function of the LMOG loading. Defect-free, composite membranes of the gelled RTILs were successfully fabricated by choosing an appropriate porous membrane support (hydrophobic PTFE) using a suitable coating technique (roller coating). The thicknesses of the applied composite gel layers ranged from 10.3 to 20.7 mu m, which represents an order of magnitude decrease in active layer thickness, compared to the original melt-infused gel RTIL membranes.

  9. Auxiliary Ligand-Dependent Assembly of Several Ni/Ni-Cd Compounds with N2O2 Donor Tetradentate Symmetrical Schiff Base Ligand

    SciTech Connect (OSTI)

    Ge, Ying Ying; Li, Guo-Bi; Fang, Hua-Cai; Zhan, Xu Lin; Gu, Zhi-Gang; Chen, Jin Hao; Sun, Feng; Cai, Yue-Peng; Thallapally, Praveen K.

    2010-09-18

    Several low-dimensional Ni/Ni-Cd complexes containing N2O2 donor tetradentate symmetrical Schiff base ligand bis(acetylacetone)ethylene-diamine (sy-H2L2), namely, [Ni(sy-L2)]2?HLa?ClO4 (2), (HLa)2?(ClO4)?(NO3) (3), [Ni(sy-L2)X]2](4,4’-bipy) (where La = 5,7-dimethyl-3,6-dihydro-2H-1,4-diazepine, X = ClO4 (4), X=NO3 (5), [Ni(sy-L2)Cd(SCN)2]n (6) and [Ni(sy-L2)?Cd(N3)2]n (7) have been synthesized from [Ni(sy-L2)]2?H2O (1). Complex 2, is three component discrete assembly generated from (HLa)+ moiety bridged with [Ni(sy-L2)] unit and ClO4- anion. A solution containing complex 2 and Cd(NO3)2 results in a mixture of 1 and 3. Further re-crystallization of 1 and 3 with various auxiliary ligands, provides coordination complexes 4 – 7 stabilized by weak hydrogen bonds in which 6 and 7 represent the first 1D heteronuclear complexes based on symmetric acacen-base Schiff base ligand.

  10. Method of controlling the mercury vapor pressure in a photo-chemical lamp or vapor filter used for Hg[sup 196] enrichment

    DOE Patents [OSTI]

    Grossman, M.W.

    1993-02-16

    The present invention is directed to a method of eliminating the cold spot zones presently used on Hg[sup 196] isotope separation lamps and filters by the use of a mercury amalgams, preferably mercury - indium amalgams. The use of an amalgam affords optimization of the mercury density in the lamp and filter of a mercury enrichment reactor, particularly multilamp enrichment reactors. Moreover, the use of an amalgam in such lamps and/or filters affords the ability to control the spectral line width of radiation emitted from lamps, a requirement for mercury enrichment.

  11. Method of controlling the mercury vapor pressure in a photo-chemical lamp or vapor filter used for Hg.sup.196 enrichment

    DOE Patents [OSTI]

    Grossman, Mark W. (Belmont, MA)

    1993-01-01

    The present invention is directed to a method of eliminating the cold spot zones presently used on Hg.sup.196 isotope separation lamps and filters by the use of a mercury amalgams, preferably mercury - indium amalgams. The use of an amalgam affords optimization of the mercury density in the lamp and filter of a mercury enrichment reactor, particularly multilamp enrichment reactors. Moreover, the use of an amalgam in such lamps and/or filters affords the ability to control the spectral line width of radiation emitted from lamps, a requirement for mercury enrichment.

  12. Air Pollution Grant Ideas Possible air pollutants to study: SO2, H2S, NO2, NH3, CO, CO2, O3.

    E-Print Network [OSTI]

    Short, Daniel

    emissions from cars, trucks and buses, power plants, and off-road equipment. In addition to contributing of an approximately $10,000 electrical chemiluminescent analyzer which is usually located at one fixed site. NO2

  13. Numerical modeling of injection and mineral trapping of CO2 with H2S and SO2 in a Sandstone Formation

    E-Print Network [OSTI]

    Xu, Tianfu; Apps, John A.; Pruess, Karsten; Yamamoto, Hajime

    2008-01-01

    capture, rather than retrofit existing conventional plants. The fate of minor quantities of sulfur and

  14. Numerical modeling of injection and mineral trapping of CO2 with H2S and SO2 in a Sandstone Formation

    E-Print Network [OSTI]

    Xu, Tianfu; Apps, John A.; Pruess, Karsten; Yamamoto, Hajime

    2008-01-01

    quality of the Aldebaran Sandstone, Denison Trough, east-accumulation in a lithic sandstone reservoir. Energy, 29(9-of carbon dioxide in a sandstone-shale system. Chem. Geol.

  15. Near-Zero Emissions Oxy-Combustion Flue Gas Purification Task 2: SOx/Nox/Hg Removal for High Sulfur Coal

    SciTech Connect (OSTI)

    Nick Degenstein; Minish Shah; Doughlas Louie

    2012-05-01

    The goal of this project is to develop a near-zero emissions flue gas purification technology for existing PC (pulverized coal) power plants that are retrofitted with oxy-combustion technology. The objective of Task 2 of this project was to evaluate an alternative method of SOx, NOx and Hg removal from flue gas produced by burning high sulfur coal in oxy-combustion power plants. The goal of the program was not only to investigate a new method of flue gas purification but also to produce useful acid byproduct streams as an alternative to using a traditional FGD and SCR for flue gas processing. During the project two main constraints were identified that limit the ability of the process to achieve project goals. 1) Due to boiler island corrosion issues >60% of the sulfur must be removed in the boiler island with the use of an FGD. 2) A suitable method could not be found to remove NOx from the concentrated sulfuric acid product, which limits sale-ability of the acid, as well as the NOx removal efficiency of the process. Given the complexity and safety issues inherent in the cycle it is concluded that the acid product would not be directly saleable and, in this case, other flue gas purification schemes are better suited for SOx/NOx/Hg control when burning high sulfur coal, e.g. this project's Task 3 process or a traditional FGD and SCR.

  16. components of the droplet stream in the first regime before,during, and after the impact. The energy audit shows thatthe change in trandiameter dropllo theleiee smpo ohat modes (i.e. n [ 2) decay quickly, leaving the dominant

    E-Print Network [OSTI]

    Jones, Thomas B.

    . The energy audit shows thatthe change in trandiameter dropllo theleiee smpo ohat #12;#12;modes (i.e. n [ 2 (Rayleigh 1945). Often, rotation is observed in rebounding droplets. The downstream velocity and reflection in #12;interference between the incoming and outgoing streams after they rebound; something that might

  17. L I B R A R Y B U S I N E S S P L A N 2 0 1 4 The Library supports the University's goals of excellence in research, excellence in education and contribution

    E-Print Network [OSTI]

    All pcs in library public spaces replaced 2 Respond more effectively to student needs through1 | L I B R A R Y B U S I N E S S P L A N 2 0 1 4 Context The Library supports the University. The University library provides a collection, library services, digital literacy and research skills, the ANU

  18. TiO2 Nanotube Arrays Annealed in N2 for Efficient Lithium-Ion Intercalation Dawei Liu, Peng Xiao,, Yunhuai Zhang,, Betzaida B. Garcia, Qifeng Zhang, Qing Guo,|

    E-Print Network [OSTI]

    Cao, Guozhong

    TiO2 Nanotube Arrays Annealed in N2 for Efficient Lithium-Ion Intercalation Dawei Liu, Peng Xiao capacity and improved cyclic stability. TiO2 nanotube arrays annealed at 300 °C exhibited the best lithium capacity decreased, but the cyclic stability improved; 400 °C annealed TiO2 nanotube arrays possessed

  19. Correlation Between Bands Structure and Magneto-Transport Properties in n-type HgTe/CdTe Superlattice with Relatively Thin CdTe Barrier

    SciTech Connect (OSTI)

    Braigue, M.; Nafidi, A.; Chaib, H.; Tirbiyine, A.; Hemine, J.; Idbaha, A.; Boulkassim, A.; El Gouti, T.; Massaq, M. [Laboratory of Condensed Matter Physics and Nanomaterials for Renewable Energy, Department of Physics, Faculty of Sciences, BP 8106 Hay Dakhla (Morocco); University Ibn Zohr, 80000 Agadir (Morocco); Talwar, Devki N. [Physics Department, Indiana University of Pennsylvania, 975 Oakland Avenue, Indiana, PA 15705 (United States); SrinivasaVinod, M. [Mechanical Engineering Department, RV College of Engineering, Bangalore - 560 059 (India)

    2011-12-26

    Theoretical calculations of the electronic properties of n-type HgTe/CdTe superlattices (SLs) in the envelope function formalism have provided a reasonable agreement with the experimental data on the magneto-transport behavior. Numerical results of the band energies E(d{sub 2}), E(k{sub z}) and E(k{sub p}) in the direction of growth and in plane of the SLs predict that the system retains semiconductor characteristics for d{sub 1}/d{sub 2} = 2.69 and d{sub 2}<10 nm. For d{sub 2} = 3.2 nm the calculated effective band gap (E{sub g}({Gamma},4.2 K) = 48 meV) suggests that the material sample is a two-dimensional modulated nanostructure and a potential candidate to be used for the far infrared detection applications.

  20. Prof. Dr. Uwe Holtz Universitt Bonn Am Hofgarten 15D -53113 Bonn UHoltz@aol.com www.uni-bonn.de/~uholtz1 OECD (Hg.): DAC Peer Review Germany, Paris 2006.4

    E-Print Network [OSTI]

    Franz, Sven Oliver

    , India,39 Indonesia, Egypt and Turkey. Germany does not intend to focus only on the poorest countries40.uni-bonn.de/~uholtz1 6.4.072 3 OECD (Hg.): DAC Peer Review Germany, Paris 2006.4 (www.oecd.org/dataoecd/54 of poorer countries but need for greater strategic selectivity8 9 Germany has never stated a preference

  1. Chemical surface inhomogeneities in late B-type stars with Hg and Mn peculiarity I Spot evolution in HD 11753 on short and long time scales

    E-Print Network [OSTI]

    Korhonen, H; Briquet, M; Soriano, M Flores; Hubrig, S; Savanov, I; Hackman, T; Ilyin, I V; Eulaers, E; Pessemier, W

    2013-01-01

    Aims: Time series of high-resolution spectra of the late B-type star HD 11753 exhibiting HgMn chemical peculiarity are used to study the surface distribution of different chemical elements and their temporal evolution. Methods: High-resolution and high signal-to-noise ratio spectra were obtained using the CORALIE spectrograph at La Silla in 2000, 2009, and 2010. Surface maps of YII, SrII, TiII, and CrII were calculated using the Doppler imaging technique. The results were also compared to equivalent width measurements. The evolution of chemical spots both on short and long time scales were investigated. Results: We determine the binary orbit of HD 11753 and fine-tune the rotation period of the primary. The earlier discovered fast evolution of the chemical spots is confirmed by an analysis using both the chemical spot maps and equivalent width measurements. In addition, a long-term decrease in the overall YII and SrII abundances is discovered. A detailed analysis of the chemical spot configurations reveals som...

  2. Electrical and optical properties of Mn-doped Hg{sub 3}In{sub 2}Te{sub 6} crystals

    SciTech Connect (OSTI)

    Grushka, O. G. Chupyra, S. M.; Mysliuk, O. M.; Bilichuk, S. V.; Koziarskyi, D. P.

    2013-09-15

    The effect of Mn impurities on the properties of Hg{sub 3}In{sub 2}Te{sub 6} crystals is studied by electrical and optical measurements. It is shown that, despite the high dopant concentration (1 Multiplication-Sign 10{sup 19} cm{sup -3}), the electron concentration remains the same as that in an undoped crystal ({approx}10{sup 13} cm{sup -3} at 300 K). At the same time, narrowing of the band gap from 0.74 to 0.7 eV is observed. From an analysis of the absorption spectra, it is found that the absorption edge is formed by optical transitions involving density-of-states (DoS) tails and that two acceptor- and donor-type impurity bands are formed in the band gap. The two bands are described by a Gaussian distribution of the DoS, with an energy gap between the peaks of E{sub 0} = E{sub d}{sup 0} - E{sub a}{sup 0} = 0.4 eV. The total donor and acceptor concentration N{sub d} + N{sub a} and the degree of compensation K = N{sub a}/N{sub d} {yields} 1 are determined. Such compensation is responsible for pinning of the Fermi level near the middle of the band gap and for quasi-intrinsic conductivity at temperatures T {>=} 300 K.

  3. MERIT Hg System Fabrication Status

    E-Print Network [OSTI]

    McDonald, Kirk

    LABORATORY U. S. DEPARTMENT OF ENERGY MC Friday Meeting 13 Jan 2006 Syringe Pump · Consists of 3 hydraulic Friday Meeting January 13, 2006 #12;2 OAK RIDGE NATIONAL LABORATORY U. S. DEPARTMENT OF ENERGY MC Friday cylinders, hydraulic pump, and manual controls · Awarded to Airline Hydraulics Corporation (AHC

  4. Microsoft Word - Hg.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMass map shines light on77 PAGE OF PAGESpersonal CERTIFIED MAIL43 PART III:Figure 1. Dr.

  5. Multispectrum measurements of spectral line parameters including temperature dependences of N2- and self-broadened half-width coefficients in the region of the v9 band of 12C2H6

    SciTech Connect (OSTI)

    Malathy Devi, V.; Benner, D. C.; Rinsland, C.P.; Smith, M.A.H.; Sams, Robert L.; Blake, Thomas A.; Flaud, Jean Marie; Sung, Keeyoon; Brown, L.R.; Mantz, A. W.

    2010-11-01

    Ethane is a prominent contributor to the spectrum of Titan, particularly in the region of the v9 band at 12?m. A multispectrum nonlinear least squares fitting program was applied to laboratory spectra of ethane to measure accurate positions, absolute intensities, N2- and selfbroadened half- width coefficients and their temperature dependences for a large number transitions. These measurements include several pQ and rQ sub-bands (and other sub-bands such as pP, rR) in the v9 fundamental band of 12C2H6 centered near 822 cm-1. Positions were measured for 2958 transitions and intensities for 3771 transitions. N2- and self-broadened half-width coefficients were determined for over 1700 transitions while temperature dependence exponents were retrieved for over 1350 of those transitions. Of these, many measurements (mostly line positions and intensities) belong to the v9+v4-v4 hot band, v9+2v4-2v4 hot band, 13C12CH6 v9 band and unidentified transitions. Forty-three high resolution (0.0016-0.005 cm-1) infrared laboratory absorption spectra recorded at temperatures between 148 and 298 K were fitted simultaneously to retrieve these parameters. Forty-one of these spectra were obtained in the temperature range of 211-298 K using the Bruker IFS 120HR interferometer located at the Pacific Northwest National Laboratory (PNNL) in Richland, Washington. Two additional spectra at 148 K were recorded using a new temperature stabilized cryogenic cell designed to work inside the sample compartment of the high resolution Bruker IFS 125HR interferometer of the Jet Propulsion Laboratory (JPL) in Pasadena California. The specialized cooling cell developed at Connecticut College and capable of achieving gas sample temperatures down to 70 K with a temperature stability and uniformity of better than ±0.05 K was employed to record the 148 K spectra. Constraints to intensity ratios, doublet separations, half-width coefficients and their temperature dependence exponents were required to determine these parameters for each of the two torsional split components. Similar to N2- and self-broadened half-width coefficients, their temperature dependence exponents were also found to follow distinctively different patterns. The variations of the observed half-width coefficients and their temperature dependences with respect to J, K quantum numbers are discussed. Because of the high density of torsionally split spectral lines, hot-band ransitions as well as blends, it was not possible to retrieve any information on the small pressure-induced shift coefficients. Present results are compared to other available measurements.

  6. A Hydrogen-Evolving Ni(P2N2)2 Electrocatalyst Covalently Attached to a Glassy Carbon Electrode: Preparation, Characterization, and Catalysis. Comparisons With the Homogeneous Analog

    SciTech Connect (OSTI)

    Das, Atanu K.; Engelhard, Mark H.; Bullock, R. Morris; Roberts, John A.

    2014-07-07

    A hydrogen-evolving homogeneous Ni(P2N2)2 electrocatalyst with peripheral ester groups has been covalently attached to a 1,2,3-triazolyllithium-terminated glassy carbon electrode. The surface-confined complex is an electroctalyst for hydrogen evolution, showing onset of catalytic current at the same potential as the soluble parent complex. X-ray photoemission spectra show excellent agreement between the coupled and homogeneous species. Coverage approaches a dense monolayer. This research was supported as part of the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the US Department of Energy, Office of Science, Office of Basic Energy Sciences. Pacific Northwest National Laboratory is operated by Battelle for the US Department of Energy. The XPS measurements were performed at EMSL, a national scientific user facility sponsored by the Department of Energy's Office of Biological and Environmental Research and located at Pacific Northwest National Laboratory.

  7. Frelsning 12 O(n2)-algoritmer

    E-Print Network [OSTI]

    passar bra i olika sammanhang. Ingen enskild algoritm är bäst i alla möjliga situtioner. PFK (Föreläsning

  8. N2Solar | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoop Inc Jump to: navigation,Mereg GmbHMontebalitoMtMxEnergy

  9. Analysis of HgI{sub 2} and PbI{sub 2} crystals and detectors by particle-induced x-ray emission (PIXE) and ion backscattering spectroscopy (IBS)

    SciTech Connect (OSTI)

    Bench, G.S.; Heikkinen, D.W. [Lawrence Livermore National Lab., CA (United States); Antolak, A.J.; Morse, D.H.; Pontau, A.E.; James, R.B.; David, D.C. [Sandia National Labs., Livermore, CA (United States); Burger, A. [Fisk Univ., Nashville, TN (United States); Van Den Berg, L. [EG and G Energy Measurements, Inc., Goleta, CA (United States)

    1993-03-01

    The Ion Micro-Analysis Group (IMAG) in Livermore conducts quantitative trace elemental analysis with PIXE and depth profiling with IBS using an MeV ion microbeam. The system has the capability to produce two-dimensional trace element and IBS images. PIXE analyses have been conducted on HgI{sub 2} and PbI{sub 2} crystals and detector materials in order to identify and quantify near surface trace contaminants. IBS measurements have been conducted to investigate elemental depth distributions in various materials. The results of measurements on several different samples are reported and a discussion of factors affecting quantitative in vacuo microanalysis of these materials is presented.

  10. Near-Zero Emissions Oxy-Combustion Flue Gas Purification Task 3: SOx/NOx/Hg Removal for Low Sulfur Coal

    SciTech Connect (OSTI)

    Monica Zanfir; Rahul Solunke; Minish Shah

    2012-06-01

    The goal of this project was to develop a near-zero emissions flue gas purification technology for existing PC (pulverized coal) power plants that are retrofitted with oxycombustion technology. The objective of Task 3 of this project was to evaluate an alternative method of SOx, NOx and Hg removal from flue gas produced by burning low sulfur coal in oxy-combustion power plants. The goal of the program was to conduct an experimental investigation and to develop a novel process for simultaneously removal of SOx and NOx from power plants that would operate on low sulfur coal without the need for wet-FGD & SCRs. A novel purification process operating at high pressures and ambient temperatures was developed. Activated carbonâ??s catalytic and adsorbent capabilities are used to oxidize the sulfur and nitrous oxides to SO{sub 3} and NO{sub 2} species, which are adsorbed on the activated carbon and removed from the gas phase. Activated carbon is regenerated by water wash followed by drying. The development effort commenced with the screening of commercially available activated carbon materials for their capability to remove SO{sub 2}. A bench-unit operating in batch mode was constructed to conduct an experimental investigation of simultaneous SOx and NOx removal from a simulated oxyfuel flue gas mixture. Optimal operating conditions and the capacity of the activated carbon to remove the contaminants were identified. The process was able to achieve simultaneous SOx and NOx removal in a single step. The removal efficiencies were >99.9% for SOx and >98% for NOx. In the longevity tests performed on a batch unit, the retention capacity could be maintained at high level over 20 cycles. This process was able to effectively remove up to 4000 ppm SOx from the simulated feeds corresponding to oxyfuel flue gas from high sulfur coal plants. A dual bed continuous unit with five times the capacity of the batch unit was constructed to test continuous operation and longevity. Full-automation was implemented to enable continuous operation (24/7) with minimum operator supervision. Continuous run was carried out for 40 days. Very high SOx (>99.9%) and NOx (98%) removal efficiencies were also achieved in a continuous unit. However, the retention capacity of carbon beds for SOx and NOx was decreased from ~20 hours to ~10 hours over a 40 day period of operation, which was in contrast to the results obtained in a batch unit. These contradictory results indicate the need for optimization of adsorption-regeneration cycle to maintain long term activity of activated carbon material at a higher level and thus minimize the capital cost of the system. In summary, the activated carbon process exceeded performance targets for SOx and NOx removal efficiencies and it was found to be suitable for power plants burning both low and high sulfur coals. More efforts are needed to optimize the system performance.

  11. Herschel-HIFI observations of H2O, NH3 and N2H+ toward high-mass starless and proto-stellar clumps identified by the Hi-GAL survey

    E-Print Network [OSTI]

    Olmi, Luca; Codella, Claudio

    2015-01-01

    Our present understanding of high-mass star formation still remains very schematic. In particular, it is not yet clear how much of the difference between low-mass and high-mass star formation occurs during the earliest star formation phases. The chemical characteristics of massive cold clumps, and the comparison with those of their low-mass counterparts, could provide crucial clues about the exact role that chemistry plays in differentiating the early phases of low-mass and high-mass star formation. Water, in particular, is a unique probe of physical and chemical conditions in star-forming regions. Using the HIFI instrument of Herschel we have observed the ortho-NH3 (1_0-0_0) (572GHz), ortho-H2O (1_10-1_01) (557GHz) and N2H+ (6-5) (559GHz) lines toward a sample of high-mass starless and proto-stellar clumps selected from the "Herschel} Infrared Galactic Plane Survey" (Hi-GAL). We compare our results to previous studies of low-mass and high-mass proto-stellar objects. At least one of the three molecular lines ...

  12. TCO (n=2, k=0), 80 nm TCO (n=2, k=0), 80 nm

    E-Print Network [OSTI]

    between non-radiative recombination and light trapping in crystalline silicon p-n junctions. We adopt the scientific and PV industrial communities with the common aim of developing thin and cheap devices, while

  13. Effect of annealing on the kinetic properties and band parameters of Hg{sub 1?x?y}Cd{sub x}Eu{sub y}Se semiconductor crystals

    SciTech Connect (OSTI)

    Kovalyuk, T. T. Maistruk, E. V.; Maryanchuk, P. D.

    2014-12-15

    The results of studies of the kinetic properties of Hg{sub 1?x?y}Cd{sub x}Eu{sub y}Se semiconductor crystals in the ranges of temperatures T = 77–300 K and magnetic fields H = 0.5–5 kOe before and after heat treatment of the samples in Se vapors are reported. It is established that annealing of the samples in Se vapors induces a decrease in the electron concentration. From the concentration dependence of the electron effective mass at the Fermi level, the band gap, the matrix element of interband interaction, and the electron effective mass at the bottom of the conduction band are determined.

  14. Alkaline Biofiltration of H2S Odors A R M A N D O G O N Z A L E Z -S A N C H E Z , ,

    E-Print Network [OSTI]

    Tecnolog´ia, Universidad Aut´onoma Metropolitana-Cuajimalpa, c/o IPH, UAM-Iztapalapa, Apdo. Postal 55

  15. On modeling the potential impacts of CO2 sequestration on shallow groundwater: Transport of organics and co-injected H2S by supercritical CO2 to shallow aquifers

    E-Print Network [OSTI]

    Zheng, L.

    2014-01-01

    F.C. Knopf, 1991. Supercritical CO2 extraction of organicaqueous sulfide and supercritical CO2. Chemical Geology 271(reactivity with supercritical CO2 and aqueous sulfide.

  16. A Combined Crossed Molecular Beam and ab Initio Study of the Reactions C2(X1g + C2H4 f n-C4H3(X2A) + H(2S1/2)

    E-Print Network [OSTI]

    Kaiser, Ralf I.

    have been identified in a variety of terrestrial and astrophysical environments from the high, are useful for modeling combustion chemistry and astrophysical processes. The kinetics of some reactions

  17. S P R I N G C O N V O C AT I O N 2 0 1 4 S F U ' S V I S I O N | T H E E N G A G E D U N I V E R S I T Y

    E-Print Network [OSTI]

    S P R I N G C O N V O C AT I O N 2 0 1 4 #12;S F U ' S V I S I O N | T H E E N G A G E D U N I V E ..............................................................................................................2 P R E S I D E N T ' S W E L C O M E .................................................................................................................................................3 P A R T I C I P A N

  18. DENSE PHASE REBURN COMBUSTION SYSTEM (DPRCS) DEMONSTRATION ON A 154 MWE TANGENTIAL FURNACE: ADDITIONAL AREA OF INTEREST-TO DEVELOP AND DEMONSTRATE AN IN-FURNACE MULTI-POLLUTANT REDUCTION TECHNOLOGY TO REDUCE NOx, SO2 & Hg

    SciTech Connect (OSTI)

    Allen C. Wiley; Steven Castagnero; Geoff Green; Kevin Davis; David White

    2004-03-01

    Semi-dense phase pneumatic delivery and injection of calcium and sodium sorbents, and microfine powdered coal, at various sidewall elevations of an online operating coal-fired power plant, was investigated for the express purpose of developing an in-furnace, economic multi-pollutant reduction methodology for NO{sub x}, SO{sub 2} & Hg. The 154 MWe tangentially-fired furnace that was selected for a full-scale demonstration, was recently retrofitted for NO{sub x} reduction with a high velocity rotating-opposed over-fire air system. The ROFA system, a Mobotec USA technology, has a proven track record of breaking up laminar flow along furnace walls, thereby enhancing the mix of all constituents of combustion. The knowledge gained from injecting sorbents and micronized coal into well mixed combustion gases with significant improvement in particulate retention time, should serve well the goals of an in-furnace multi-pollutant reduction technology; that of reducing back-end cleanup costs on a wide variety of pollutants, on a cost per ton basis, by first accomplishing significant in-furnace reductions of all pollutants.

  19. Hg System Assembly and Testing Status

    E-Print Network [OSTI]

    McDonald, Kirk

    NATIONAL LABORATORY U. S. DEPARTMENT OF ENERGY Wiring Started · Sensor wiring inside the hydraulic control #12;2VRVS Meeting 1 Nov 2006 OAK RIDGE NATIONAL LABORATORY U. S. DEPARTMENT OF ENERGY Welding OAK RIDGE NATIONAL LABORATORY U. S. DEPARTMENT OF ENERGY Cart Modifications · Secondary box center

  20. Hg System Status V.B. Graves

    E-Print Network [OSTI]

    McDonald, Kirk

    2006 OAK RIDGE NATIONAL LABORATORY U. S. DEPARTMENT OF ENERGY Syringe Pump at ORNL · Hydraulic power OF ENERGY HPU Setup · Hydraulic fluid fill and drain process developed using peristaltic pump - Pump works OAK RIDGE NATIONAL LABORATORY U. S. DEPARTMENT OF ENERGY Manual Control Operational · Fluid added

  1. High Power Hg Target Conceptual Design Review

    E-Print Network [OSTI]

    McDonald, Kirk

    · With minimal dismantling in situ, move equipment out of beam line · Leave in tunnel area as long as CERN

  2. Target System Operations and Hg Handling

    E-Print Network [OSTI]

    McDonald, Kirk

    in the sump tank or drain line using the pump #12;9 OAK RIDGE NATIONAL LABORATORY U. S. DEPARTMENT OF ENERGY fill and drain operations ... gloves, gauze, drip shields, etc. will be double-bagged, taped and placed

  3. Hg System Assembly and Testing Status

    E-Print Network [OSTI]

    McDonald, Kirk

    · Secondary beam windows received and installed · Problem with bolt pattern on downstream window was corrected tech support #12;5VRVS Meeting 20 Dec 2006 OAK RIDGE NATIONAL LABORATORY U. S. DEPARTMENT OF ENERGY

  4. High Power Hg Target Conceptual Design Review

    E-Print Network [OSTI]

    McDonald, Kirk

    Monitor $12000Total $5500 LabView control system (software & hardware) $500 Control box (power supplies in Solidworks $4800AL Base Support Secondary Containment Primary Containment Sump Subsystem $13000Total $5700SS U. S. DEPARTMENT OF ENERGY Conceptual Design Review 7-8 Feb 05 Outline · Procured systems - Syringe

  5. High Power Hg Target Conceptual Design Review

    E-Print Network [OSTI]

    McDonald, Kirk

    for systems tests · 15 Tesla field · 1-sec steady state jet during the magnet peak field (unresolved) #12=-2.5, R=0.4 (pump motor) is 0.03

  6. Materials Data on N2 (SG:194) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  7. Revue Europenne des Migrations Internationales Volume 8 n2,

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    enfants migrants se traitent d'« arabe » dans une classe primaire Pierre ACHARD, Gabrielle VARRO, François

  8. N=2 Supersymmetric Kinks and real algebraic curves

    E-Print Network [OSTI]

    A. Alonso Izquierdo; M. A. Gonzalez Leon; J. Mateos Guilarte

    2000-02-17

    The kinks of the (1+1)-dimensional Wess-Zumino model with polynomic superpotential are investigated and shown to be related to real algebraic curves.

  9. Theory of the n=2 levels in muonic deuterium

    E-Print Network [OSTI]

    Julian J. Krauth; Marc Diepold; Beatrice Franke; Aldo Antognini; Franz Kottmann; Randolf Pohl

    2015-06-08

    The present knowledge of Lamb shift, fine- and hyperfine structure of the $\\mathrm{2S}$ and $\\mathrm{2P}$ states in muonic deuterium is reviewed in anticipation of the results of a first measurement of several $\\mathrm{2S-2P}$ transition frequencies in muonic deuterium ($\\mu\\mathrm{d}$). A term-by-term comparison of all available sources reveals reliable values and uncertainties of the QED and nuclear structure-dependent contributions to the Lamb shift, which are essential for a determination of the deuteron rms charge radius from $\\mu\\mathrm{d}$. Apparent discrepancies between different sources are resolved, in particular for the difficult two-photon exchange contributions. Problematic single-sourced terms are identified which require independent recalculation.

  10. SSQ V3 N2_Final_13aug13.indd

    National Nuclear Security Administration (NNSA)

    off momentumvelocity transfer. Nonnuclear methods include gravity attractors and solar energy absorption. In Figure 1, scientists are calculating a nuclear explosion on the...

  11. Lean NOx Trap Regeneration Selectivity Towards N2O -- Similarities...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    This presentation uses a global model for the primary and secondary peaks to explain the chemical reactions. deer12bartova.pdf More Documents & Publications Spatiotemporal...

  12. Aspects of Four Dimensional N = 2 Field Theory 

    E-Print Network [OSTI]

    Xie, Dan

    2011-07-11

    hypermulti- plets. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 134 22 Left: (p, q)-web realizing the TN theory, with aligned 7-branes. Right: Quiver diagram of the mirror of TN , with gauge groups U(r). The group at the center... gauge groups are U(r). . . 137 xiii FIGURE Page 25 Top: We take two copies of TN and gauge together two SU(N) Higgs symmetries. Bottom: Its mirror. We gauge together two SU(N) Coulomb symmetries. This ends up eliminating the two T[SU(N)] tails. Here...

  13. Self-Dual Supergravity from N = 2 Strings

    E-Print Network [OSTI]

    de Boer, J.

    2010-01-01

    the difference between the RNS formulation of the (1,2)to the conventional N = 1 RNS string through a non-localto formulate our model in RNS variables. One immediate

  14. Efficient algorithm for online N - 2 power grid contingency selection

    E-Print Network [OSTI]

    Kaplunovich, Petr A. (Petr Alexandrovich)

    2014-01-01

    Multiple element outages (N - k contingencies) have caused some of the most massive blackouts and disturbances in the power grid. Such outages affect millions of people and cost the world economy billions of dollars annually. ...

  15. SSQ V1 N2_6june11_FINAL

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal GasAdministration Medal01 Sandia4) August 20123/%2A en NNSAReference to Mod/%2A19FY

  16. SSQ V3 N2_Final_13aug13.indd

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal GasAdministration Medal01 Sandia4) August 20123/%2A en NNSAReference to Mod/%2A19FY4 *1

  17. Molecular Simulation Studies of Separation of CO2/N2, CO2/CH4, and CH4/N2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTechtail.Theory ofDid you notHeatMaRIEdioxide capture |GEUtilizing sevenNationalNEWSSeeby ZIFs

  18. MERIT Hg System Testing V.B. Graves

    E-Print Network [OSTI]

    McDonald, Kirk

    OF ENERGY Syringe Statistics · 30hp / 4000psi / 12.9gpm hydraulic pump · 40 gal vegetable-oil based. DEPARTMENT OF ENERGY Outline · Requirements review · System description · Testing to date · Preparations OF ENERGY Requirements and Operating Conditions · 1-cm diameter jet at 20 m/s delivered every 30 minutes - Q

  19. Packed bed reactor for photochemical .sup.196 Hg isotope separation

    DOE Patents [OSTI]

    Grossman, Mark W. (Belmont, MA); Speer, Richard (Reading, MA)

    1992-01-01

    Straight tubes and randomly oriented pieces of tubing having been employed in a photochemical mercury enrichment reactor and have been found to improve the enrichment factor (E) and utilization (U) compared to a non-packed reactor. One preferred embodiment of this system uses a moving bed (via gravity) for random packing.

  20. Page 1 of 3 Summary of Hg Jet Target Meeting

    E-Print Network [OSTI]

    McDonald, Kirk

    ' memoranda) and for dismantling/disposal of the test equipment. 2) The magnet has a great deal of operating

  1. Microsoft Word - Hg SEIS NNMCAB Member Comments Letter Rev 1

    Office of Environmental Management (EM)

    "hazardous impurities" require that an accounting or categorization of stored mercury vessels will be needed, and mercury vessels stored accordingly. Mercury is an element that...

  2. Target Design Meeting Nozzle & Hg Collection Tests, Design

    E-Print Network [OSTI]

    McDonald, Kirk

    and proton beam control system · Emergency shut off coupled to PB line emergency shutoff, as well as manual Shut down pump - 41.0-45.0 De-energize to zero - - 45.0-1

  3. MERIT Hg System Design V.B. Graves

    E-Print Network [OSTI]

    McDonald, Kirk

    , also considering running in rough vacuum · Full-beam interaction length is 30-cm · Beam line is 120-cm to Airline Hydraulics (HQ Bensalem, PA) · Complete system design based on specified requirements · Piston with integrated position sensors - Tie beam - Hydraulic hoses inside secondary for operating Drive Cylinders

  4. Hg System Operation Review V.B. Graves

    E-Print Network [OSTI]

    McDonald, Kirk

    runs with field (10- 15-20 m/s jets, 5-10-15 Tesla fields) · Syringe pump performed as expected spill risk & vapor generation · Drain into intermediate container reduces chance of overfilling flask

  5. Packed bed reactor for photochemical sup 196 Hg isotope separation

    SciTech Connect (OSTI)

    Grossman, M.W.; Speer, R.

    1992-03-03

    This patent describes a photochemical reactor useful for the isotopic enrichment of a predetermined isotope of mercury comprising a reactor cell and a monoisotopic light source It comprises: a plurality of transparent, straight reactor cell tubes disposed axially within the internal volume of the reactor cell to increase the surface area thereof for production deposition.

  6. Paleomagnetic Secular Variation (PSV), 137Cs, and Hg dating techniques

    E-Print Network [OSTI]

    Fountain, Andrew G.

    fission of Uranium-235 · Due to nuclear weapons testing · Highly water soluble (spreads quickly) · Half ­ Depositional or post-depositional remanent magnetization (magnetic field direction) · Sediment water interface not preserve » Higher rates of deposition = higher accuracy #12;Paleomagnetic Secular Variation (PSV) · (Lund

  7. Controlling Across Complex Networks , H.G. Tanner

    E-Print Network [OSTI]

    and Astronomy University of New Mexico, Albuquerque NM 87131. Sandia National Laboratories, Albuquerque, NM into our designs, e.g., we now consider the impact of link capacity, latency and packet loss on control as diverse as biology, computer science, physics, and social science have recently begun using more abstract

  8. Technology could deliver 90% Hg reduction from coal

    SciTech Connect (OSTI)

    Maize, K.

    2009-07-15

    Reducing mercury emissions at coal-fired power plants by 90% has been considered the holy grail of mercury control. A new technology promises to get used there, but at a price. This is a mixture of chemical approaches, including activated carbon injection into the gases coming off the combustor along with injection of trona or calcium carbonate to reduce sulfur trioxide in the exhaust gases. The trick according to Babcock and Wilcox's manager Sam Kumar, to 'capture the mercury as a particulate on the carbon and then capture the particulate' in an electrostatic precipitator or a fabric filter baghouse. 2 figs.

  9. NNMCAB Correspondence 2013-01 (Hg SEIS) | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i nAand DOEDepartment of Energy009At This2015-04The NNMCAB submitted

  10. Hg Anomalies In Soils- A Geochemical Exploration Method For Geothermal

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIXsource History View NewGuam: Energyarea, CaliforniaHess Retail NaturalAreas | Open Energy

  11. 3UREOHP 6WDWHPHQW3UREOHP 6WDWHPHQW 0HWKRGRORJ\\ (PSOR\\HG0HWKRGRORJ\\ (PSOR\\HG

    E-Print Network [OSTI]

    Mohaghegh, Shahab

    price of oil & gas is high requiresa time when price of oil & gas is high requires a reliable reservoir Production rate data.Production rate data.Production rate data.Production rate data. Recently a new based onfor characterization of mature fields based on monthly production rate data. Thismonthly

  12. Revisiting HgCl2: A Solution- and Solid-State 199Hg NMR and ZORA-DFT Computational Study

    E-Print Network [OSTI]

    Taylor, Robert E; Carver, Colin T; Larsen, Ross E; Dmitrenko, Olga; Bai, Shi; Dybowski, Cecil

    2009-01-01

    7 (1997), 333-336. [26] R. E. Taylor, Concepts Magn. Reson.DFT Computational Study R. E. Taylor 1 *, Colin T. Carver2522 USA *Corresponding author: R. E. Taylor Email address:

  13. Studies of the Excited State Dynamics of N2O2 by Dissociative Photodetachment of N2O2 Runjun Li and Robert E. Continetti*

    E-Print Network [OSTI]

    Continetti, Robert E.

    to their potential importance as intermediates in catalytic reduction processes1,2 and as potential energetic materials.3 The weakly bound ground- state dimer of nitric oxide, (NO)2, has been extensively investigated The oxides of nitrogen play an important role in atmospheric chemistry and have received attention owing

  14. Can N 2 O stable isotopes and isotopomers be useful tools to characterize sources and microbial pathways of N 2 O production and consumption in tropical soils?

    E-Print Network [OSTI]

    2011-01-01

    from tropical forest soils, Global Biogeochem. Cycles, 14,2 O source partitioning in soils: recent progress, remaininga temperate grassland soil after fertiliser application,

  15. Can N 2 O stable isotopes and isotopomers be useful tools to characterize sources and microbial pathways of N 2 O production and consumption in tropical soils?

    E-Print Network [OSTI]

    2011-01-01

    20632, Caracas 1020?A, Venezuela. S. Park, Department ofTierra Nueva,” Guárico State, Venezuela). The statisticallyLaboratory, IVIC, Caracas, Venezuela. Department of Earth

  16. Two-phase compressibility factors for retrograde gases 

    E-Print Network [OSTI]

    Rayes, Daniel George

    1989-01-01

    . K. , M Cain, W. D. , Jr. and Jennings, J. W. : "An Improved Method for the Determination of the Reservoir Specific Gravity for Retrograde Gases, " JPT (July 1989) 747-752. 7. Craft, B. C. and Hawkins, M. F. : A li P 1 m R rv ir En ine rin...). Variable Mean Standard Deviation Minimum Maximum H2S CO2 N2 CI C2 C3 IC4 NC4 IC5 NC5 C6 C7+ M. W. C7+ S. G. C7+ 1, 01840 0. 00997 0. 02545 0. 01840 0. 73233 0. 07584 0. 03948 0. 00859 0. 01482 0. 00611 0. 00637 0. 00857 0. 05404...

  17. CH4 and N2O emissions embodied in international trade of meat

    E-Print Network [OSTI]

    Caro, D; Lopresti, A; Davis, SJ; Bastianoni, S; Caldeira, K

    2014-01-01

    emissions due to production and consumption for the largestemissions from production and consumption of beef, pork anddisconnect of production and consumption represents a

  18. International Journal of General Systems, Vol. 32 n.2. March 2003 BOOK REVIEW

    E-Print Network [OSTI]

    Gerla, Giangiacomo

    Academic Publishers (Trends in Logic, Studia Logica Library, Vol. 11), Dordrecht, 2001, 288 pages, ISBN 0-7923-6941-6. The present book is another book from the Kluwer's series Trends in Logic which is devoted to fuzzy logic

  19. Multistep N2 Breathing in the Metal-Organic Framework Co(1,4-benzenedipyrazolate)

    E-Print Network [OSTI]

    to external stimuli can render them excellent candidates as sensors for the evalu- ation of adsorbent. Variable-temperature magnetic susceptibility measurements and in situ infrared and UV-vis-NIR spectroscopic

  20. Materials Data on Sr(BeN)2 (SG:140) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  1. Appearance Potentials and Kinetic Energies of Ions from N2, CO, and NO

    E-Print Network [OSTI]

    Hierl, Peter M.; Franklin, J. L.

    1967-01-01

    A recently developed method has permitted the measurement of excess translational energy of ions formed in a time?of?flight mass spectrometer. The method, in conjunction with the RPD technique for determining appearance ...

  2. Symbiotic nitrogen fixation in legumes Define: the process by which molecular nitrogen (N2) is

    E-Print Network [OSTI]

    Constabel, Peter

    -Rhizobium communication - roots release flavonoid signals (flavone), stimulate Rhizobium nod genes - nod genes are 'common' and 'host-specific' - nodD is the activator - nod factors: lipo-oligosaccharide signals - chitin

  3. N=2 gauge theories on toric singularities, blow-up formulae and W-algebrae

    E-Print Network [OSTI]

    Giulio Bonelli; Kazunobu Maruyoshi; Alessandro Tanzini; Futoshi Yagi

    2013-02-05

    We compute the Nekrasov partition function of gauge theories on the (resolved) toric singularities C^2/\\Gamma in terms of blow-up formulae. We discuss the expansion of the partition function in the \\epsilon_1,\\epsilon_2 \\to 0 limit along with its modular properties and how to derive them from the M-theory perspective. On the two-dimensional conformal field theory side, our results can be interpreted in terms of representations of the direct sum of Heisenberg plus W_N-algebrae with suitable central charges, which can be computed from the fan of the resolved toric variety.We provide a check of this correspondence by computing the central charge of the two-dimensional theory from the anomaly polynomial of M5-brane theory. Upon using the AGT correspondence our results provide a candidate for the conformal blocks and three-point functions of a class of the two-dimensional CFTs which includes parafermionic theories.

  4. The bioinorganic chemistry of N2S2 metal complexes: reactivity and ligating ability 

    E-Print Network [OSTI]

    Golden, Melissa Lynn

    2005-08-29

    determined for Pb2+, Ni2+, Zn2+, Cu+, and Ag+. A quantitative estimate places copper some 15 orders of magnitude above nickel or zinc in binding affinity. Sulfur dioxide uptake by Ni-1?? is characterized by significant color change, improved adduct...

  5. $\\mathcal{N}=2$ Supersymmetric Janus Solutions and Flows: From Gauged Supergravity to M Theory

    E-Print Network [OSTI]

    Pilch, Krzysztof; Warner, Nicholas P

    2015-01-01

    We investigate a family of SU(3)$\\times$U(1)$\\times$U(1)-invariant holographic flows and Janus solutions obtained from gauged $\\mathcal{N}=8$ supergravity in four dimensions. We give complete details of how to use the uplift formulae to obtain the corresponding solutions in M theory. While the flow solutions appear to be singular from the four-dimensional perspective, we find that the eleven-dimensional solutions are much better behaved and give rise to interesting new classes of compactification geometries that are smooth, up to orbifolds, in the infra-red limit. Our solutions involve new phases in which M2 branes polarize partially or even completely into M5 branes. We derive the eleven-dimensional supersymmetries and show that the eleven-dimensional equations of motion and BPS equations are indeed satisfied as a consequence of their four-dimensional counterparts. Apart from elucidating a whole new class of eleven-dimensional Janus and flow solutions, our work provides extensive and highly non-trivial tests...

  6. $\\mathcal{N}=2$ Supersymmetric Janus Solutions and Flows: From Gauged Supergravity to M Theory

    E-Print Network [OSTI]

    Krzysztof Pilch; Alexander Tyukov; Nicholas P. Warner

    2015-10-27

    We investigate a family of SU(3)$\\times$U(1)$\\times$U(1)-invariant holographic flows and Janus solutions obtained from gauged $\\mathcal{N}=8$ supergravity in four dimensions. We give complete details of how to use the uplift formulae to obtain the corresponding solutions in M theory. While the flow solutions appear to be singular from the four-dimensional perspective, we find that the eleven-dimensional solutions are much better behaved and give rise to interesting new classes of compactification geometries that are smooth, up to orbifolds, in the infra-red limit. Our solutions involve new phases in which M2 branes polarize partially or even completely into M5 branes. We derive the eleven-dimensional supersymmetries and show that the eleven-dimensional equations of motion and BPS equations are indeed satisfied as a consequence of their four-dimensional counterparts. Apart from elucidating a whole new class of eleven-dimensional Janus and flow solutions, our work provides extensive and highly non-trivial tests of the recently-derived uplift formulae.

  7. Understanding denitrification with stable isotope measurements of N2: proof of concept study 

    E-Print Network [OSTI]

    Downer, Roswell Curtis

    2004-01-01

    The biologically mediated removal of nitrogen from estuarine and shallow coastal waters was investigated using a new method for the determination of N? isotope ratios. This method employs the use of a chromatographic separation technique to purify...

  8. in FocusA U T U M N 2 0 0 3 Canada Post

    E-Print Network [OSTI]

    Shoubridge, Eric

    ways in which your support is critical to our mission. With collegial regards and best wishes, PhD'65, and Michel Tremblay celebrate the McGill Cancer Centre's 25th Anniversary. Photo by Owen Egan. Photo:NadineSaumure Dean of the Faculty of Medicine, Abraham Fuks #12;M E D I C I N E 3 W hen most

  9. Innovative Concepts Phase I: Inorganic Membranes for CO2/N2 Separation

    SciTech Connect (OSTI)

    William Desisto

    2003-09-23

    Silica membranes were prepared using a novel technique of catalyzed-atomic layer deposition of silica within a mesoporous matrix. Pyridine was used to catalyze the silicon chloride attachment to the hydroxylated silica surface at room temperature. This half-reaction was followed by the hydration of the surface with water regenerating surface hydroxyls and completing one reaction cycle. The technique resulted in the self-limited pore size reduction of the mesoporous matrix to pore sizes near 1 nm. The self-limited reaction was presumed to be the exclusion of the large catalyst molecule from the pore entrance. In addition to pore size reduction, viscous flow defects were repaired without significantly reducing overall porosity of the membrane. In addition, we investigated the ability of amine-functionalization to enhance the CO{sub 2} transport in silica membranes. Specifically, we examined three synthesis techniques for functionalizing silica membranes with amino groups that resulted in different surface chemistries of the silica membranes. These differences were correlated with changes in the CO{sub 2} facilitation characteristics. It was found that high loadings of amino groups where interaction with the silica surface was minimized promoted the highest CO{sub 2} transport.

  10. Solvothermal synthesis and electrochemical charge storage assessment of Mn3N2

    E-Print Network [OSTI]

    in lithium and sodium batteries, where the metal nitride is reduced to metal and lithium nitride. In lithium manganese oxides are common positive electrode materials in primary and Li-ion batteries, taking advantage on cycling. In lithium cells a reversible first cycle capacity of 600 mA h g-1 was obtained, and this decayed

  11. Materials Data on BH7N2 (SG:60) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  12. Materials Data on B5H11N2 (SG:15) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  13. Materials Data on H4N2O3 (SG:59) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  14. Materials Data on H8S5N2 (SG:14) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  15. Materials Data on Be(H2N)2 (SG:142) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  16. PRODUCT ENERGY AND ANGULAR DISTIBUTIONS FROM THE REACTION OP N2+ WITH ISOTOPIC HYDROGEN MOLECULES

    E-Print Network [OSTI]

    Gentry, W.R.; Gislason, E.A.; Lee, Yuan-tseh; Mahan, B.H.; Tsao, Chi-wing.

    2008-01-01

    No. w-y405-eng-4.8 PRODUCT ENERGY AND ANGULAR DISTRJBUTIONSauspices of the U. S. Atomic Energy Commission. Eepartmentthis text. Short Title: Energy and Angular Distri'outions.

  17. Structures, Energetics and Spectroscopic Fingerprints of Water Clusters n = 2-24

    SciTech Connect (OSTI)

    Yoo, Soohaeng; Xantheas, Sotiris S.

    2012-01-01

    Water's function as a universal solvent and its role in mediating several biological functions that are responsible for sustaining life has created tremendous interest in the understanding of its structure at the molecular level.1 Due to the size of the simulation cells and the sampling time needed to compute many macroscopic properties, most of the initial simulations are performed using a classical force field whereas several processes that involve chemistry are subsequently probed with electronic structure based methods. A significant effort has therefore been devoted towards the development of classical force fields for water.2 Clusters of water molecules are useful in probing the intermolecular interactions at the microscopic level as well as providing information about the subtle energy differences that are associated with different bonding arrangements within a hydrogen bonded network. They moreover render a quantitative picture of the nature and magnitude of the various components of the intermolecular interactions such as exchange, dispersion, induction etc. They can finally serve as a vehicle for the study of the convergence of properties with increasing size.

  18. Materials Data on Sm4S3N2 (SG:12) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  19. Selective Catalytic Oxidation (SCO) of NH3 to N2 for Hot Exhaust Treatment

    Broader source: Energy.gov [DOE]

    Investigation of a series of transition metal oxides and precious metal based catalysts for ammonia selective oxidation at low temperatures

  20. Materials Data on Zr4N2O5 (SG:1) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  1. ~~"jr..TT-."';\\"fli" ~n~/ 2/3/67

    E-Print Network [OSTI]

    Rathbun, Julie A.

    information when monitoring UF6 gas in pipes. 1/18/2011 11-008 C11043 getMirFiles.sh, Version 0.x Code

  2. Materials Data on Th2BiN2 (SG:139) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  3. Materials Data on U2BiN2 (SG:139) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  4. Materials Data on Ca3N2 (SG:194) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  5. Materials Data on Ca3N2 (SG:164) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  6. Astrocytes increase the activity of synaptic GluN2B NMDA receptors

    E-Print Network [OSTI]

    Hahn, J; Wang, X; Margeta, M

    2015-01-01

    subunit or acts through an ancillary protein that is part ofarrow) or, more likely, an ancillary protein (X) associated

  7. Noncompact gauging of N=2 7D supergravity and AdS/CFT holography

    E-Print Network [OSTI]

    Parinya Karndumri

    2015-02-02

    Half-maximal gauged supergravity in seven dimensions coupled to $n$ vector multiplets contains $n+3$ vectors and $3n+1$ scalars parametrized by $\\mathbb{R}^+\\times SO(3,n)/SO(3)\\times SO(n)$ coset manifold. The two-form field in the gravity multiplet can be dualized to a three-form field which admits a topological mass term. Possible non-compact gauge groups take the form of $G_0\\times H\\subset SO(3,n)$ with a compact group $H$. $G_0$ is one of the five possibilities; $SO(3,1)$, $SL(3,\\mathbb{R})$, $SO(2,2)$, $SO(2,1)$ and $SO(2,2)\\times SO(2,1)$. We investigate all of these possible non-compact gauge groups and classify their vacua. Unlike the gauged supergravity without a topological mass term, there are new supersymmetric $AdS_7$ vacua in the $SO(3,1)$ and $SL(3,\\mathbb{R})$ gaugings. These correspond to new $N=(1,0)$ superconformal field theories (SCFT) in six dimensions. Additionally, we find a class of $AdS_5\\times S^2$ and $AdS_5\\times H^2$ backgrounds with $SO(2)$ and $SO(2)\\times SO(2)$ symmetries. These should correspond to $N=1$ SCFTs in four dimensions obtained from twisted compactifications of six-dimensional field theories on $S^2$ or $H^2$. We also study RG flows from six-dimensional $N=(1,0)$ SCFT to $N=1$ SCFT in four dimensions and RG flows from a four-dimensional $N=1$ SCFT to a six-dimensional SYM in the IR. The former are driven by a vacuum expectation value of a dimension-four operator dual to the supergravity dilaton while the latter are driven by vacuum expectation values of marginal operators.

  8. N2O and CH4 variations during the last glacial epoch: Insight into global processes

    E-Print Network [OSTI]

    Chappellaz, Jérôme

    provide important insight into the former composition of the atmosphere, its natural variations; accepted 12 December 2003; published 30 January 2004. [1] Greenhouse gas measurements along polar ice cores reconstructed for Greenland. INDEX TERMS: 0325 Atmospheric Composition and Structure: Evolution

  9. Raman Spectroscopic Investigation of CH4 and N2 Adsorption in Metal-Organic Frameworks

    E-Print Network [OSTI]

    Yaghi, Omar M.

    by IRMOFs make them attractive for adsorption processes. The application of IRMOFs as media for gas storage been reported.2,6 Given the emerging applications of IRMOFs as gas storage materials, it is important

  10. DIELECTRONIC RECOMBINATION OF Fe xxi AND Fe xxii VIA N = 2!N0 = 2 CORE EXCITATIONS

    E-Print Network [OSTI]

    Savin, Daniel Wolf

    coefficients for the iron L-shell ions (Fe xviii­Fe xxiv). These ions are predicted to play an important role in deter- mining the thermal structure and line emission from X-ray photoionized plasmas (Hess, Kahn

  11. D) + N2O Reaction: NO Vibrational and Rotational Distributions J. Chen, C. K. Ulrich,

    E-Print Network [OSTI]

    Houston, Paul L.

    relative velocity collisions. The former might correspond to an insertion/complex-formation reaction, while the latter might correspond to a stripping reaction. Velocity relaxation of the O(1 D) is argued to compete in low relative velocity reactions because the O(1 D) is not relaxed from its initial velocity before

  12. A comparison of three learning methods to predict N2O fluxes and N leaching

    E-Print Network [OSTI]

    Villa-vialaneix, Nathalie

    Commission, Joint Research Center - Climate Change Unit Via Enrico Fermi, 2749, 21027 Ispra - Italy Abstract of the data The Homogeneous Spatial Mapping Unit (HSMU) is the minimal geographical unit used for our simulations [15]. The main environmental informations are European soil [13] and daily meteorological data [20

  13. REVISTA DO DETUA, VOL. 4, N 2, JANEIRO 2004 235 Architectures for Open Access Hotspots

    E-Print Network [OSTI]

    Paiva, António R. C.

    problema da sustentabilidade econ´omica deste servic¸o ´e tamb´em analisado. Finalmente, ap- resentamos

  14. Isotopic variability of N 2 O emissions from tropical forest soils

    E-Print Network [OSTI]

    Perez, T.; Trumbore, S. E; Tyler, S. C; Davidson, E. A; Keller, M.; de Camargo, P. B

    2000-01-01

    de Camargo, Centro de Energia Nuclear na Agricultura, AvlSN relative to 4Centro de Energia Nuclear na Agricultura,

  15. Materials Data on Li2ThN2 (SG:0) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  16. Reversible CO Binding Enables Tunable CO/H2 and CO/N2 Separations in

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTechtail.Theory ofDid youOxygen Generation |Publications|Retiree Benefits RetireeRevCom

  17. Comparative Study of the Valence Electronic Excitations of N-2 by Inelastic

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfate Reducing BacteriaConnect Collider Tests of the LittleJournaltransverse

  18. Average and effective Q-values for fission product average (n,2n) and

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfate Reducing Bacteria (Technical Report) | SciTech ConnectPatent:

  19. Average and effective Q-values for fission product average (n,2n) and

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfate Reducing Bacteria (Technical Report) | SciTech ConnectPatent:(n,3n) reaction cross sections

  20. Phonon-mediated superconducting transitions in layered cuprate superconductors Xiao-Jia Chen, Viktor V. Struzhkin, Zhigang Wu, Russell J. Hemley, and Ho-kwang Mao

    E-Print Network [OSTI]

    Wu, Zhigang

    Phonon-mediated superconducting transitions in layered cuprate superconductors Xiao-Jia Chen series of layered cuprate super- conductors. We show that the dependence of both the superconducting, and cation disorder in the model superconducting series HgBa2Can-1CunO2n+2+ can be well reproduced within one

  1. Project 2012: Increasing Female Representation in Government

    E-Print Network [OSTI]

    McLean, Lindsey

    2011-01-01

    Slovenia Ukraine Hungary Croatia Bosnia and Herzegovina Rep.HG) Chile (HS/HG) Croatia (HG) Finland (HS) Germany (HG)

  2. SUCHTT a g d e r M e d i z i n 2 0 0 7 SUCHTT a g d e r M e d i z i n 2 0 0 7 0 Tag der Medizin 2007

    E-Print Network [OSTI]

    Gollisch, Tim

    . (2007): Trias Verlag, Stuttgart Magersüchtige Frau Magersucht Magersucht (Anorexia nervosa) entsteht

  3. Ambient Measurements of the NOx Reservoir Species N2O5 using Cavity Ring-down Spectroscopy 

    E-Print Network [OSTI]

    Geidosch, Justine Nicole

    2012-10-19

    to the occurrence of asthma. Ozone is formed through reactions of oxidized volatile organic compounds with nitrogen oxides, and the accurate modeling of the process is necessary for smart and effective regulations. Ambient measurements are important to understanding...

  4. A comparison of eight metamodeling techniques for the simulation of N2O fluxes and N leaching from corn crops

    E-Print Network [OSTI]

    Villa-vialaneix, Nathalie

    , 1991) and the Water Framework Directive (European Council,23 2000). Initially, however, compliance the environmental im-21 pact of the agriculture sector, particularly the Nitrates Directive (Euro-22 pean Council to these directives was poor (Oenema24 e

  5. Design of a Metal-Organic Framework with Enhanced Back Bonding for Separation of N2 and CH4

    E-Print Network [OSTI]

    with a considerably higher enthalpy of adsorption for dinitrogen than for methane, based on strong selective back methane-rich gases. This is an extraordinarily difficult separation based on physical properties alone,*,, and Laura Gagliardi*,, Department of Chemical and Biomolecular Engineering, University of California

  6. Formation and Genotoxicity of Novel Oxidatively Generated Tandem DNA Lesions and N2-(1-carboxyethyl)-2'-deoxyguanosine

    E-Print Network [OSTI]

    Jiang, Yong

    2009-01-01

    quantified by UV absorbance measurements, and aliquots ofwere determined by UV absorbance measurements using molarquantified by UV absorbance measurements, and to the mixture

  7. Single-QCL-based absorption sensor for simultaneous trace-gas detection of CH4 and N2O

    E-Print Network [OSTI]

    in soil and water or human activities such as agriculture, fossil fuel combustion, wastewater management (TEC), pulsed quantum cascade lasers (QCLs) and a multipass gas cell (MGC) with 56 m path length and 0 system based on a pulsed distributed feed- back (DFB) QCL near 7.7 lm and a 215 m path length MGC

  8. Catalytic oxidative coupling of methane over Li/MgO using N2O as an oxidant 

    E-Print Network [OSTI]

    Yamamoto, Hiroshi

    1992-01-01

    be attributed to the C-H bond cleavage. A low selectivity for COv (A e. high ethane and ethylene selectivity), was observed when the CH~/NvO ratio was large. The condition where a small amount of CO~ was observed corresponds to the region in which oxygen... formation over Li/MgO while CH was kepi. at about, 30 kpa. . . 36. The influence of N 0 on the rate of CO~ formation over Li/MgO whde CH was kept at about 10 kPa. . . 37. The influence of CH on the rate of CO~ formation over Li/MgO while NvO was kept...

  9. Benzene-derived N2-(4-hydroxyphenyl)-deoxyguanosine adduct: UvrABC incision and its conformation in DNA

    E-Print Network [OSTI]

    Hang, Bo

    2010-01-01

    in a historical UK cohort of benzene exposed workers. OccupEnvironmental exposure to benzene: an update. Environ Health2004. Genotoxicity of benzene and its metabolites. Mutat Res

  10. BANDO n. 2/2012 PER IL RECLUTAMENTO DI UN RICERCATORE CON RAPPORTO DI LAVORO A TEMPO DETERMINATO TIPOLOGIA A

    E-Print Network [OSTI]

    Di Pillo, Gianni

    processi enzimatici, alla caratterizzazione termodinamica di complessi di inclusione di tipo host-guest. Un

  11. JOURNAL DE PHYSIQUE Colloque C2, supplment au n2, Tome 46, fvrier 1985 page C2-665

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    . This problem is avoided by film burners which evaporate the film and allow it to condense in a region of high refrigeration "-"power. This system is currently under test. WAVEGUIDE STILL 3 K SHIELD STABILIZATION SOLENOID F will be pulsed with a period of 2.5 s, and a duty cycle of 10%. The cryostat, refrigerator and storage cell

  12. Experimental and quantum mechanics investigations of early reactions of monomethylhydrazine with mixtures of NO2 and N2O4

    E-Print Network [OSTI]

    Goddard III, William A.

    States b Department of Mechanical and Nuclear Engineering, The Pennsylvania State University, University Hypergolic bipropellants are fuel-oxidizer combinations that ignite spontaneously upon mixing at ambient it important to develop computa- tional fluid dynamics (CFD) models to gain insight into the influ- ence

  13. Materials Data on TbAg3H6C6(N2O)3 (SG:193) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  14. Temporal development of the plasma composition of Zr and Cr metal plasma streams in a N2 environment

    E-Print Network [OSTI]

    Rosen, Johanna; Anders, Andre; Hultman, Lars; Schneider, Jochen M.

    2003-01-01

    properties [4]. The vacuum arc plasma composition and theIn a cathodic arc discharge, the plasma production at theassociated with plasma production in cathodic arc spots may

  15. Modulo di Matematica, Prova scritta parziale n. 2, 27 Novembre 2003 Corso di laurea in Tecnica Vivaistica

    E-Print Network [OSTI]

    Bianchi, Gabriele

    compresa tra l'asse delle x e il grafico della funzione y = x3 + x2 - 6x (vedi figura)(attenti al segno rotazione ottenuto ruotando intorno all'asse x l'insieme delimitato dall'asse x e dal grafico della funzione

  16. Materials Data on H8PtN2(ClO)2 (SG:14) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  17. Bando n. 03_2012 AVVISO PUBBLICO DI SELEZIONE PER IL CONFERIMENTO DI N. 2 INCARICHI DI

    E-Print Network [OSTI]

    Di Pillo, Gianni

    DIPARTIMENTO DI FISIOLOGIA E FARMACOLOGIA "VITTORIO ERSPAMER" VISTO - Visto il Regolamento per l'affidamento di rappresentate dal Dipartimento di Fisiologia e Farmacologia "Vittorio Erspamer"; - Ravvisata conseguentemente la all'art. 1 del presente avviso a favore del Dipartimento di Fisiologia e Farmacologia "Vittorio

  18. Current biofuel feedstock crops such as corn lead to large environmental losses of N through nitrate leaching and N2

    E-Print Network [OSTI]

    David, Mark B.

    219 Current biofuel feedstock crops such as corn lead to large environmental losses of N through biofuel crops established on a rich Mollisol soil. Reduced Nitrogen Losses after Conversion of Row Crop Agriculture to Perennial Biofuel Crops Candice M. Smith, Mark B. david,* Corey A. Mitchell, Michael d. Masters

  19. A Reverse Converter for the New 4-Moduli Set {2n + 3, 2n + 2, 2n + 1, 2n}

    E-Print Network [OSTI]

    Cotofana, Sorin

    complex adders and multipliers. Index Terms--Residue Number System, 4-Moduli Set with Common factor, RNS-Decimal Converter, Chinese Remainder Theorem. I. INTRODUCTION Residue Number Systems (RNS) offer great potential]. The major obstacle to the utilization of RNS is the overhead incurred in the conversions into and out of RNS

  20. I. Computer simulation of a trochoidal monochromator, energy dependance spectra of N2 and hot filament negativ ion mass

    E-Print Network [OSTI]

    Steiner, Daniel

    filament ­ negativ ion mass spectra of a series of halogenated compounds II. Excited-state proton transfer monochromator, electron energy loss, low energy collisions, hot filament - negative ion mass spectra, photoacid the contact of halogenated compounds with a hot filament, have been made. Photoacids, molecules showing

  1. Density-functional study of organicinorganic hybrid single crystal ZnSe,,C2H8N2...12

    E-Print Network [OSTI]

    Li, Jing

    , is revealed to be responsible for governing these properties. Suggestions for further engineering hybrid by structure disorders due to weak van der Waals interactions between organic molecules , and the resulting

  2. V2O5 xerogel electrodes with much enhanced lithium-ion intercalation properties with N2 annealing

    E-Print Network [OSTI]

    Cao, Guozhong

    intercalation properties.18 After annealing in CO, the surface layer of TiO2 nanotubes contained both carbide and the uniformity of the coating was another challenge.17 In our earlier work, it was found that annealing TiO2 nanotube arrays fabricated by means of anodization in reducing gas CO resulted in much improved lithium ion

  3. Direct observations of N2O5 reactivity on ambient aerosol particles Timothy H. Bertram,1,2

    E-Print Network [OSTI]

    aerosol flow reactor coupled to a custom-built chemical ionization mass spectrometer at two urban currently implemented large-scale model parameterizations would predict. Such discrepancies have likely and thus accurate description of the processes that remove NOx radicals is critical for predicting the down-wind

  4. JOURNAL DE PHYSIQUE Colloque C2, supplment au n2, Tome *6, fvrier 1985 page C2-713

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    OF POLARIZED PROTONS IN SppS AND OTHER HIGH ENERGY HADRON COLLIDERS* E.D. Courant Brookhaven National-350 0.8, 14-30 Tevatron (FNAL) pp 800-1000 10, 150 RHIC (BNL) p-ion 250-350 20-30 HERA (DESY) e-p 850 40. 3. Traversal of polarization resonances in booster synchrotrons (up to 15-70 GeV). 4. Elimination

  5. Probing the Vibrational Relaxation of N2 and O2 by Use of CARS Spectroscopy to Model NTE-Turbulence 

    E-Print Network [OSTI]

    Dean, Jacob

    2009-06-09

    NTE-preparation. The detection technique used in the experiment was coherent anti-Stokes Raman spectroscopy (CARS) and variations of this laser-based technique were optimized to maximize accuracy and signal-to-noise in the vibrational relaxation...

  6. Spatiotemporal Distribution of NOx Storage: a Factor Controlling NH3 and N2O Selectivities over a Commercial LNT Catalyst

    Broader source: Energy.gov [DOE]

    Evaluation of commercial Ba-based LNT (CLEERS benchmark catalyst; containing oxygen storage capacity) in a bench flow reactor under fast-cycling conditions, varying reductant type, temperature and sulfation level

  7. Benzene-derived N2-(4-hydroxyphenyl)-deoxyguanosine adduct: UvrABC incision and its conformation in DNA

    E-Print Network [OSTI]

    Hang, Bo

    2010-01-01

    p- benzoquinone DNA adducts derived from benzene are highlyphenol and hydroquinone derived mainly from diet andendonuclease toward the benzene-derived DNA adduct, pBQ-C.

  8. Selective Binding of O2 over N2 in a Redox-Active Metal-Organic Framework

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTechtail.Theory ofDidDevelopment Top Scientific Impact Since itsimpact / selectedwith Open

  9. Measurement and Modeling of the n=2-3 Emission of O VIII near 102 �A

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfate Reducing(JournalspectroscopyReport) | SciTech Connect Mathematicalmagnetics(Journal

  10. Measurement and Modeling of the n=2-3 Emission of O VIII near 102 �A

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfate Reducing(JournalspectroscopyReport) | SciTech Connect

  11. updated_supplemental_lists_1n-2n-3m_07-06-2012.xlsx | Department of Energy

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LIST OFAMERICA'S FUTURE.EnergyWooden RooftopsNRC

  12. sup 3 P Hg, Cd, and Zn photosensitized chemistry of vinyl halides in krypton matrix

    SciTech Connect (OSTI)

    Cartland, H.E.; Pimentel, G.C. )

    1990-01-25

    The reaction of group IIB metals in the {sup 3}P state with vinyl fluoride, chloride, and bromide is studied in krypton matrix. The primary process in all cases is hydrogen halide elimination to form a hydrogen halide/acetylene hydrogen-bonded complex. Insertion of metal atoms into C-Cl and C-Br bonds, but not into C-H and C-F bonds, is also observed. The insertion photochemistry can be explained by a mechanism which requires that the process occur on a triplet surface with the vinyl halide in the planar ground-state conformation.

  13. Materials Data on Li2HgGe (SG:225) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  14. Materials Data on Hg3(PO4)2 (SG:14) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  15. Materials Data on AgHg3SbO6 (SG:167) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  16. Materials Data on HgO (SG:62) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  17. Materials Data on BaSnHg (SG:194) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  18. Materials Data on CaHgPb (SG:194) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  19. An Optical Offgas Sensor Network Incorporating a HG Cavity Ringdown Spectrometer and IR Diode Lasers

    SciTech Connect (OSTI)

    George P. Miller

    2007-12-30

    A multi-element cavity ringdown system was evaluated with the objective of developing an intelligent sensor network to be incorporated into the control systems for advanced coal combustion facilities. Using a combination of a YAG-pumped dye laser and a tunable NIR/IR laser a dual cavity was constructed and a labview program was developed to provide multi-channel, real-time data to permit the real-time monitoring of typical exhaust emission gases, (for example: CO{sub 2}, SO{sub 2}, and mercury) of concern to the next generation of coal-powered facilities.

  20. Modelling Glass Parisons R.M.M. Mattheij, K. Wang & H.G. ter Morsche

    E-Print Network [OSTI]

    Eindhoven, Technische Universiteit

    , are being heated in a tank. This can be a device several tens of metres long and a few metres high and wide glass (for pane, wind shields etc.). In the latter case the major problems are to have a smooth flow

  1. Materials Data on HgHOF (SG:19) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  2. Report on International Collaboration Involving the FE Heater and HG-A Tests at Mont Terri

    E-Print Network [OSTI]

    Houseworth, Jim

    2014-01-01

    BBM Barcelona Basic Model CIEMAT Centro de Investigacionesdesign (Nater, 2012). 2) CIEMAT and UPC of Spain conductedmodel as applied by the CIEMAT and UPC (Garitte and Gens,

  3. Materials Data on HfCuHg2 (SG:216) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  4. Materials Data on Al2HgSe4 (SG:82) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  5. Materials Data on ZrCuHg2 (SG:216) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  6. Materials Data on InHg (SG:166) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  7. 2 Toxicity and Sources of Pb, Cd, Hg, Cr, As, and Radionuclides

    E-Print Network [OSTI]

    Volesky, Bohumil

    ........................................................................................... 35 2.3.1 Acid Mine Drainage ................................................................................................ 35 2.3.1.1 Chemistry of Acid Mine Water

  8. RATIO OF THE AL+ AND HG+ OPTICAL CLOCK FREQUENCIES TO 17 DECIMAL PLACES

    E-Print Network [OSTI]

    . ROSENBAND, D. B. HUME, P. O. SCHMIDT,t C. W. CHOU, A. BRUSCH,+ L. LORlNI,§ W. H. OSKAY,'lJ R. E. DRULLINGER of standards are based on single ions confined in Paul traps, but differ in the methods used to prepare

  9. Meson Production Comparison between HG and GA at 8 GeV

    E-Print Network [OSTI]

    McDonald, Kirk

    optimization (0.5cm/67mrad/33 mrad) 57340 (Pos) 60791 (Neg) 118131 (Sum) 46414 (Pos) 48830 (Neg) 95244 (Sum) Meson Production after optimization 61255 (Pos) 66996 (Neg) 128351 (Sum) (16.6% higher than GA case) 54129 (Pos) 55958 (Neg) 110087 (Sum) 53253 (Pos) 54091 (Neg) 107343 (Sum) #12;Meson Production

  10. Materials Data on Cs3HgCl5 (SG:62) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  11. Materials Data on TmHg (SG:221) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  12. Materials Data on NdHg2 (SG:191) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  13. A Solid-State 199Hg NMR Study of Mercury Halides

    E-Print Network [OSTI]

    Taylor, Robert E; Bai, Shi; Dybowski, Cecil

    2011-01-01

    550 (1998), 89-99. [25] R. E. Taylor, C. T. Carver, R. E.7 (1997), 333-336. [33] R. E. Taylor, Concepts Magn. Reson.Study of Mercury Halides R. E. Taylor 1 *, Shi Bai 2 , and

  14. NNMCAB Correspondence 2013-05 (Response Hg SEIS) | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i nAand DOEDepartment of Energy009At This2015-04The NNMCABWIPP facility

  15. H.G. Rickover, 1964 | U.S. DOE Office of Science (SC)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would likeUniverse (Journalvivo Low-Dose Lowï‚— WeUpdate JonGuided 8/12/15Guy MayneordHH.H.G.

  16. Update on microkinetic modeling of lean NOx trap chemistry.

    SciTech Connect (OSTI)

    Larson, Richard S.; Daw, C. Stuart (Oak Ridge National Laboratory, Oak Ridge, TN); Pihl, Josh A. (Oak Ridge National Laboratory, Oak Ridge, TN); Choi, Jae-Soon (Oak Ridge National Laboratory, Oak Ridge, TN); Chakravarthy, V, Kalyana (Oak Ridge National Laboratory, Oak Ridge, TN)

    2010-04-01

    Our previously developed microkinetic model for lean NOx trap (LNT) storage and regeneration has been updated to address some longstanding issues, in particular the formation of N2O during the regeneration phase at low temperatures. To this finalized mechanism has been added a relatively simple (12-step) scheme that accounts semi-quantitatively for the main features observed during sulfation and desulfation experiments, namely (a) the essentially complete trapping of SO2 at normal LNT operating temperatures, (b) the plug-like sulfation of both barium oxide (NOx storage) and cerium oxide (oxygen storage) sites, (c) the degradation of NOx storage behavior arising from sulfation, (d) the evolution of H2S and SO2 during high temperature desulfation (temperature programmed reduction) under H2, and (e) the complete restoration of NOx storage capacity achievable through the chosen desulfation procedure.

  17. THE DEFINITION OF ENGINEERING DEVELOPMENT AND RESEARCH PROBLEMS RELATING TO THE USE OF GEOTHERMAL FLUIDS FOR ELECTRIC POWER GENERATION AND NONELECTRIC HEATING

    E-Print Network [OSTI]

    Apps, J.A.

    2011-01-01

    chemical reagents e. Catalytic oxidation in the condensate (for H2S) f. Catalytic oxidation of gas (especially for H2S)chemical reagents e. Catalytic oxidation in the condensate (

  18. HELSINKI UNIVERSITY OF TECHNOLOGY ENE-47.153 SULPHUR #1SULPHUR #1

    E-Print Network [OSTI]

    Zevenhoven, Ron

    ) Temp. 500...800 °C : catalytically (V, Ni, Fe)(heterogeneous) SO3 + H2O H2SO4 sulphuric acid Temp: 1100 °C : thermal (homogeneous reactions H2S + O2 SO2 CO2 + H2S COS + H2O CO + H2S H2 + COS COS + H2S CS2 + H2O CS2 C(s) + 2/x Sx (s) (4

  19. Sulfur emissions to the atmosphere from natural sourees

    E-Print Network [OSTI]

    Bates, TS; Lamb, BK; Guenther, A; Dignon, J; Stoiber, RE

    1992-01-01

    e.g. H2S, OCS, CS2, DMS, and DMDS) and varied sources (e.g.k a and k b for OCS, CS2, DMDS, DMS and H2S for five surface27%), and H2S (20%). CS 2 and DMDS each contribute about 3%

  20. Project 2012: Increasing Female Representation in Government

    E-Print Network [OSTI]

    McLean, Lindsey

    2011-01-01

    Sierra Leone Suriname Liberia French Guiana Ghana TogoHG) Iceland (HG) Ireland (HS) Liberia (HS/HG) Lithuania (HS)

  1. Summary of the MeHg Panels of the 2004 CalFed Science Conference 1 Summary of the MeHg Panels of the 2004 CalFed Science Conference

    E-Print Network [OSTI]

    the importance of methylmercury production relative to other potential problems in river and wetland restoration managers can optimize the benefits of restoration projects. Most of the mercury sources in the ecosystem. Newer sources, such as atmospheric deposition, urban run-off, and effluent from wastewater treatment

  2. Of Mice and Men: Evolution and the Socialist Utopia. William Morris, H.G. Wells, and George Bernard Shaw*

    E-Print Network [OSTI]

    Hale, Piers J.

    in the History of Science and Technology at the University of Minnesota, at the History Department colloquium Shaw* PIERS J. HALE Department of the History of Science University of Oklahoma 601 Elm Avenue, PHSC August Weismann to our understanding of heredity have earned him a significant place in the history

  3. Materials Data on HgH12C2(Br2N3)2 (SG:15) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  4. Materials Data on K2HgH2Cl4O (SG:55) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  5. Fate of As, Se, and Hg in a Passive Integrated System for Treatment of Fossil Plant Wastewater

    SciTech Connect (OSTI)

    Terry Yost; Paul Pier; Gregory Brodie

    2007-12-31

    TVA is collaborating with EPRI and DOE to demonstrate a passive treatment system for removing SCR-derived ammonia and trace elements from a coal-fired power plant wastewater stream. The components of the integrated system consist of trickling filters for ammonia oxidation, reaction cells containing zero-valent iron (ZVI) for trace contaminant removal, a settling basin for storage of iron hydroxide floc, and anaerobic vertical-flow wetlands for biological denitrification. The passive integrated treatment system will treat up to 0.25 million gallons per day (gpd) of flue gas desulfurization (FGD) pond effluent, with a configuration requiring only gravity flow to obviate the need for pumps. The design of the system will enable a comparative evaluation of two parallel treatment trains, with and without the ZVI extraction trench and settling/oxidation basin components. One of the main objectives is to gain a better understanding of the chemical transformations that species of trace elements such as arsenic, selenium, and mercury undergo as they are treated in passive treatment system components with differing environmental conditions. This progress report details the design criteria for the passive integrated system for treating fossil power plant wastewater as well as performance results from the first several months of operation. Engineering work on the project has been completed, and construction took place during the summer of 2005. Monitoring of the passive treatment system was initiated in October 2005 and continued until May 18 2006. The results to date indicate that the treatment system is effective in reducing levels of nitrogen compounds and trace metals. Concentrations of both ammonia and trace metals were lower than expected in the influent FGD water, and additions to increase these concentrations will be done in the future to further test the removal efficiency of the treatment system. In May 2006, the wetland cells were drained of FGD water, refilled with less toxic ash pond water, and replanted due to low survival rates from the first planting the previous summer. The goals of the TVA-EPRI-DOE collaboration include building a better understanding of the chemical transformations that trace elements such as arsenic, selenium, and mercury undergo as they are treated in a passive treatment system, and to evaluate the performance of a large-scale replicated passive treatment system to provide additional design criteria and economic factors.

  6. Helical Quantum States in HgTe Quantum Dots with Inverted Band Structures Kai Chang and Wen-Kai Lou

    E-Print Network [OSTI]

    - tensive attention in the past decades due to their application in electronic devices [1,2], e.g., single in TI nanostructures, e.g., QDs, remains rela- tively unexplored. In this Letter, we consider, these states are optical dark states that can be used in quan- tum information storage. A perpendicular

  7. BANDO PER IL RECLUTAMENTO DI n. 2 RICERCATORI CON RAPPORTO DI LAVORO A TEMPO DETERMINATO FINANZIATO DA FONDI DI DIPARTIMENTO (art.2, lett. d del Regolamento)

    E-Print Network [OSTI]

    Guidoni, Leonardo

    indirizzo di posta elettronica segreteria.radiologia@uniroma1.it Nella domanda di partecipazione i candidati

  8. JOURNAL DE PHYSIQUE Colloque C 1, supplment au n 2-3, Tome 32, Fvrier-Mars 1971, page C 1 -503 NEUTRON DIFFRACTION, MOSSBAUER

    E-Print Network [OSTI]

    Boyer, Edmond

    in neutron scattering amplitudes of Ti and V (b = - 0.38 and - 0.05 respectively) and Ta (b = 0.70 x 10- 1 2.17 (*) With temperature factor B = 0.4 A. The large contribution of oxygen to the neutron scattering permits us to refine NEUTRON DIFFRACTION, MOSSBAUER AND MAGNETIC INVESTIGATION OF RUTILE-TYPE TANTALATES MTa04 (M = Ti, V, Cr

  9. Power calculations D.A. Freedman December 2007 What is the power of a randomized controlled experiment? We assume there are n1 + n2

    E-Print Network [OSTI]

    Freedman, David A.

    Power calculations D.A. Freedman December 2007 What is the power of a randomized controlled of the null against the alternative µ1 = µ2, and we compute power at µ1 = µ2 + k where k > 0 is chosen so is asymptotically distributed as N(k, 1), where k = k/f Suppose k > 2. If Z is N(0, 1), asymptotic power is then P

  10. Synthesis ofN-(2-chloro-5-methylthiophenyl)-N'-(3-methyl-thiophenyl)-N'-[3H3]methylguanidine, l brace [3H3]CNS-5161 r brace

    SciTech Connect (OSTI)

    Gibbs, Andrew R.; Morimoto, Hiromi; VanBrocklin, Henry F.; Williams, Philip G.; Biegon, Anat

    2001-09-28

    The preparation of the title compound, [{sup 3}H{sub 3}]CNS-5161, was accomplished in three steps starting with the production of [{sup 3}H{sub 3}]iodomethane (CT{sub 3}I). The intermediate N-[{sup 3}H{sub 3}]methyl-3-(thiomethylphenyl)cyanamide was prepared in 77% yield by the addition of CT{sub 3}I to 3-(thiomethylphenyl)cyanamide, previously treated with sodium hydride. Reaction of this tritiated intermediate with 2-chloro-5-thiomethylaniline hydrochloride formed the guanidine compound [{sup 3}H{sub 3}]CNS-5161. Purification by HPLC gave the desired labeled product in an overall yield of 9% with greater than 96% radiochemical purity and a final specific activity of 66 Ci mmol{sup -1}.

  11. Global long-lived chemical modes excited in a 3-D chemistry transport model: Stratospheric N 2 O, NO y , O 3 and CH 4 chemistry

    E-Print Network [OSTI]

    Hsu, Juno; Prather, Michael J

    2010-01-01

    supported by NSF Atmospheric Chemistry (ATM?0550234) and theeigenstates in atmospheric chemistry, Geophys. Res. Lett. ,1998), Time scales in atmospheric chemistry: Coupled per-

  12. Berry's Phases for Arbitrary Spins Non-Linearly Coupled to External Fields. Application to the Entanglement of N > 2 Non-Correlated One-Half Spins

    E-Print Network [OSTI]

    Marie-Anne Bouchiat; Claude Bouchiat

    2010-11-05

    We derive the general formula giving the Berry phase for an arbitrary spin, having both magnetic-dipole and electric-quadrupole couplings with external time-dependent fields. We assume that the effective E and B fields remain orthogonal during the quantum cycles. This mild restriction has many advantages. It provides simple symmetries leading to selection rules and the Hamiltonian-parameter and density-matrix spaces coincide for S=1. This implies the identity of the Berry and Aharonov-Anandan phases, which is lost for S>1. We have found that new features of Berry phases emerge for integer spins>2. We provide explicit numerical results of Berry phases for S=2,3,4. We give a precise analysis of the non-adiabatic corrections. The accuracy for satisfying adiabaticity is greatly improved if one chooses for the time derivatives of the parameters a time-dependence having a Blackman pulse shape. This has the effect of taming the non-adiabatic oscillation corrections which could be generated by a linear ramping. For realistic experimental conditions, the non-adibatic corrections can be kept reversal of the angular velocity can be cancelled exactly if the quadrupole to dipole coupling ratio takes a "magic" value. The even ones are cancelled by subtraction of the phases relative to opposite velocities. As a possible application of the results of this paper we suggest a route to holonomic entanglement of N non-correlated 1/2-spins by performing adiabatic cycles governed by a Hamiltonian which is a non-linear function of the total spin operator S defined as the sum of the N spin operators. The case N=4 and Sz=1 is treated explicitly and maximum entanglement is achieved.

  13. Industry perspective chimica Oggi / cHEMISTRY TOdaY -vol 27 n 2 / March/April 2009 -Focus on Tides

    E-Print Network [OSTI]

    Rhode Island, University of

    , as a consequence, the metabolism in cells in diseased tissue becomes partially anaerobic, leading to the production of such metabolism in any tissue is the formation of H+, which must be removed from the cell to maintain the normal potential from the proton gradient across the dielectric membrane, the H+ ions accumulate near the surfaces

  14. Emissions of CH4 and N2O over the United States and Canada based on a receptor-oriented modeling framework and COBRA-NA

    E-Print Network [OSTI]

    Stephens, Britton B.

    , contributing nearly as much to radiative forcing (RF) as carbon dioxide (0.977 W mÀ2 compared to 1.626 W mÀ2 reliance on data from remote sites and coarse meteorological resolution (typically 1° Â 1° or larger

  15. 1 x N^2 wavelength-selective switch with two cross-scanning one-axis analog micromirror arrays in a 4-f optical system

    E-Print Network [OSTI]

    Tsai, J C; Huang, STY; Hah, D; Wu, Ming C

    2006-01-01

    optical microelectromechanical systems (MEMS), optical ?berinclude optical microelectromechanical systems (MEMS),

  16. N2s2 chelating agents as cys-x-cys biomimics for fe(no) and fe(no)2 complexes 

    E-Print Network [OSTI]

    Chiang, Chao-Yi

    2006-08-16

    model complexes I have examined the fundamental properties of a dithiolato-Fe(NO)2 complex, bismercaptoethandiazacyclooctane iron dinitrosyl or (H+bme-daco)Fe(NO)2 as a biomimic of dicysteinate coordination of [Fe(NO)2]. This complex was prepared...

  17. SYNTHESIS OF THE FULLY PROTECTED PHOSPHORAMIDITE OF THE BENZENE-DNA ADDUCT, N2- (4-HYDROXYPHENYL)-2'-DEOXYGUANOSINE AND INCORPORATION OF THE LATER INTO DNA OLIGOMERS

    E-Print Network [OSTI]

    Huang, Bo

    2008-01-01

    associated with low-level benzene exposure. EpidemiologyC. C. An overview of benzene metabolism. Environ. Healthstudies of human exposure to benzene in China and Europe An

  18. WRF-Chem model predictions of the regional impacts of N2O5 heterogeneous processes on night-time chemistry over north-western Europe

    E-Print Network [OSTI]

    Lowe, D.; Archer-Nicholls, S.; Morgan, W.; Allan, J.; Utembe, S.; Ouyang, B.; Aruffo, E.; Le Breton, M.; Zaveri, R. A.; Di Carlo, P.; Percival, C.; Coe, H.; Jones, R.; McFiggans, G.

    2015-02-09

    The hydroxyl radical (OH) dominates the oxidative control of the composition of the troposphere, primarily through its established role as a daytime oxidant. However, night-time chemistry, driven primarily by the nitrate radical (NO3), has been increasingly...

  19. BA 290N-2, ME290P-1, INFOSYS 290P-4 and DSID125 Managing the New Product Development Process: Design Theory and Methods

    E-Print Network [OSTI]

    Agogino, Alice M.

    Process: Design Theory and Methods Professors Alice M. Agogino, Sara Beckman and Leslie Speer Fall 2007-1058, (415) 464-0517, beckman@haas.berkeley.edu Leslie Speer, Industrial Design Program, San Jose State University, Art 231, (408) 924-4376, (510) 658- 3177, Leslie.Speer@sjsu.edu Teaching Assistants: Jonathan

  20. 1 x N^2 wavelength-selective switch with two cross-scanning one-axis analog micromirror arrays in a 4-f optical system

    E-Print Network [OSTI]

    Tsai, J C; Huang, STY; Hah, D; Wu, Ming C

    2006-01-01

    include optical microelectromechanical systems (MEMS),Index Terms—Microelectromechanical devices, optical compo-include optical microelectromechanical systems (MEMS),

  1. 1 x N^2 wavelength-selective switch with two cross-scanning one-axis analog micromirror arrays in a 4-f optical system

    E-Print Network [OSTI]

    Tsai, J C; Huang, STY; Hah, D; Wu, Ming C

    2006-01-01

    MEMS for biomedical appli- cations, microactuators, sensors,MEMS analog micromirror arrays with hidden vertical comb- drive actuators,” in Proc. Solid-State Sensor,Sensor and Actuator Center (BSAC). His research interests include optical microelectromechanical systems (MEMS),

  2. Equilibrium and transport properties of CO2+N2O and CO2+NO mixtures. A molecular simulation and equation of state modelling study.

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    viscosities were determined for CO2+NOx mixtures. Due to the strong similarities between carbon dioxide simulation; Equation of state. 1. Introduction In Carbon dioxide Capture and Storage (CCS) operations to a pure carbon dioxide. This may have impacts on the different stages of the CCS chain: capture

  3. Laser diagnostics of pulverized coal combustion in O_2/N_2 and O_2/CO_2 conditions: velocity and scalar field measurements

    E-Print Network [OSTI]

    Balusamy, Saravanan; Kamal, M. Mustafa; Lowe, Steven M.; Tian, Bo; Gao, Yi; Hochgreb, Simone

    2015-05-13

    .com emissions (Metz et al. 2005; IEA 2012). Increasing demand for power, especially in developing countries, will lead to a further increase in CO2 emissions and other harmful pollutants. To address the problem, several carbon capture and storage (CCS... Cerrejon coal Proximate analysis wt% Volatile matter 34.80 Fixed carbon 50.80 Moisture 5.80 Ash 8.60 Ultimate analysis wt% Carbon 69.20 Hydrogen 4.40 Oxygen 9.98 Nitrogen 1.42 Sulfur 0.58 Sieve pitch (?m) Cum. mass% Mass% 500 100 10 210 90 28 150 62 12 75...

  4. 2D-cadmium MOF and gismondine-like zinc coordination network based on the N-(2-tetrazolethyl)-4?-glycine linker

    E-Print Network [OSTI]

    Salinas-Castillo, Alfonso; Calahorro, Antonio J.; Briones, David; Fairen-Jiménez, David; Gándara, Felipe; Mendicute-Fierro, Claudio; Seco, José M.; Pérez-Mendoza, Manuel; Fernández, Belén; Rodríguez-Diéguez, Antonio

    2015-02-25

    and topological diversity as well as the properties that arise from their structural features.[1] In particular, the study of Cd- and Zn-based MOFs has evolved enormously[2] in areas such as luminescence,[3] gas adsorption,[4] sensing, and optical storage.[5... of 72.81(8)-114.19(7)º and 153.48(7)-158.66(8)º, respectively, highlighting the N8A-Cd-O12A angle with a large value of 114.19(7). Figure 1. View down the bc plane of layers in compound 1. Hydrogen atoms have been omitted for clarity...

  5. Global long-lived chemical modes excited in a 3-D chemistry transport model: Stratospheric N 2 O, NO y , O 3 and CH 4 chemistry

    E-Print Network [OSTI]

    Hsu, Juno; Prather, Michael J

    2010-01-01

    supported by NSF Atmospheric Chemistry (ATM?0550234) and theeigenstates in atmospheric chemistry, Geophys. Res. Lett. ,scales in atmospheric chemistry: Coupled per- turbations to

  6. Complexes of HNO3 and NO3 - with NO2 and N2O4, and their potential role in atmospheric HONO formation.

    E-Print Network [OSTI]

    Kamboures, Michael A; Raff, Jonathan D; Miller, Yifat; Phillips, Leon F; Finlayson-Pitts, Barbara J; Gerber, R Benny

    2008-01-01

    enthalpy of 24 kcal mol 1 calculated from the NIST-JANAF thermochemicalenthalpy DH of 14 kcal mol 1 calculated using the NIST-JANAF Thermochemical

  7. Vector Analyzing Power at Theta-Lab=18-Degrees for the H-2(p-],N)2p Reaction at 21.3 Mev 

    E-Print Network [OSTI]

    Nath, S.; Northcliffe, L. C.; Hiebert, John C.; Woolverton, H. L.; York, R. L.; Graves, R. G.; Craft, B. C.

    1984-01-01

    references to earlier works. 3J. A. Tjon, in Proceedings of the Ninth International Conference on the Few Body Problems, University of Oregon, 1980, edited by M. J. Moravcsik and F. S. Levin [Nucl. Phys. A353, 47c (1981)];A. C. Phillips, Rep. Frog. Phys.... Rev. C 8, 124 (1973)."J.Bruinsma, thesis, Vrije Universiteit, Amsterdam, 1976 (un- published); J. Bruinsma and R. Van Wageningen, Nucl. Phys. A282, 1 (1977). (a) C. Stolk and J. A. Tjon, Nucl. Phys. A319, 1 (1979); (b) C. Stolk and J. A. Tjon, Phys...

  8. Atmos. Chem. Phys., 3, 535548, 2003 www.atmos-chem-phys.org/acp/3/535/ Atmospheric

    E-Print Network [OSTI]

    Meskhidze, Nicholas

    (RGM) and particulate Hg (HgP). With interfacing to MM5 (meteorology processor) and SMOKE (emission- active gaseous divalent Hg) and HgP (particulate Hg). Al- though the existence of methylated Hg has been subject to ad- sorption onto the elemental carbon aerosols. HgP is referred to as particulate solid Hg

  9. A Hybrid Gas Cleaning Process for Production of Ultraclean Syngas

    SciTech Connect (OSTI)

    Merkel, T.C.; Turk, B.S.; Gupta, R.P.; Cicero, D.C.; Jain, S.C.

    2002-09-20

    The overall objective of this project is to develop technologies for cleaning/conditioning IGCC generated syngas to meet contaminant tolerance limits for fuel cell and chemical production applications. The specific goals are to develop processes for (1) removal of reduced sulfur species to sub-ppm levels using a hybrid process consisting of a polymer membrane and a regenerable ZnO-coated monolith or a mixed metal oxide sorbent; (2) removal of hydrogen chloride vapors to sub-ppm levels using an inexpensive, high-surface-area material; and (3) removal of NH3 with acidic adsorbents followed by conversion of this NH3 into nitrogen and water. Existing gasification technologies can effectively and efficiently convert a wide variety of carbonaceous feedstocks (coal, petcoke, resids, biomass, etc.) into syngas, which predominantly contains carbon monoxide and hydrogen. Unfortunately, the impurities present in these carbonaceous feedstocks are converted to gaseous contaminants such as H2S, COS, HCl, NH3, alkali macromolecules and heavy metal compounds (such as Hg) during the gasification process. Removal of these contaminants using conventional processes is thermally inefficient and capital intensive. This research and development effort is focused on investigation of modular processes for removal of sulfur, chlorine, nitrogen and mercury compounds from syngas at elevated temperature and pressures at significantly lower costs than conventional technologies.

  10. Effect of Environmental Factors on Sulfur Gas Emissions from Drywall

    E-Print Network [OSTI]

    Maddalena, Randy

    2012-01-01

    sulfide (H 2 S), carbonyl sulfide (OCS), sulfur dioxide (SOof hydrogen sulfide, carbonyl sulfide, methyl mercaptan,associated with the carbonyl sulfide that typically had very

  11. Terrestrial-Atmospheric Exchange of Reduced Sulfur Compounds in Natural Ecosystems

    E-Print Network [OSTI]

    Whelan, Mary Elizabeth

    2013-01-01

    simultaneous  production  and  consumption   fluxes  of  measured  annual  production  and  consumption  of  COS  1).    The  production  and  consumption  of  H 2 S  is  

  12. Microsoft Word - agreement_scanned.doc

    Office of Environmental Management (EM)

    * fuel processing (reformers, shift reactors, membrane separations) * gas clean-up (ammonia NH3, hydrogen sulfide H2S, alkali, hydrogen chloride HCI, trace elements) *...

  13. More Economical Sulfur Removal for Fuel Processing Plants

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    crude oil it is present in sulfur-containing organic compounds which are converted into hydrocarbons and H 2 S during the removal process (hydrodesulfurization). In both cases,...

  14. quality guidelines | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    levels are provided for limitations of carbon steel pipelines, enhanced oil recovery (EOR), saline reservoir sequestration, and cosequestration of CO2 and H2S in saline...

  15. Phase relationships in the BaO-Y?O?-Cu-O system 

    E-Print Network [OSTI]

    Hegg, Turi

    1989-01-01

    -Cu ? 0 Febr. 1988 Jan. 1988 Febr. 1987 80 liquid N2 80 40 20 Pb Hg La-Sr ? Cu ? 0 NbaGe Nb- Al- Ge NbN Nb0 NQSn Nb Jan. 1987 (under pressure) Dec. 1988 April 1986 ~ La-Ba-Cu-0 Jan. 1988 0 1910 1930 1950 1970 1990 Figure 7... time temperature transforma- tion (TTT) diagram in air, as shown in Figure 14, which shape suggests that / / ORTHORHOMBIC g / E IZ + 10' cc n. Z X 0 X = 6. 8 / TETRAGONAL 0 P ~ / / / / 10 2 6. 6/ 66 64 63 62 I 0 OM I 6. 1 500 600...

  16. Coating Microstructure-Property-Performance Issues

    SciTech Connect (OSTI)

    Terry C. Totemeier; Richard N. Wright

    2005-05-01

    Results of studies on the relationships between spray parameters and performance of thermally-sprayed intermetallic coatings for high-temperature oxidation and corrosion resistance are presented. Coating performance is being assessed by corrosion testing of free-standing coatings, thermal cycling of coating substrates, and coating ductility measurement. Coating corrosion resistance was measured in a simulated coal combustion gas environment (N2-CO-CO2-H2O-H2S) at temperatures from 500 to 800°C using thermo-gravimetric analysis (TGA). TGA testing was also performed on a typical ferritic-martensitic steel, austenitic stainless steel, and a wrought Fe3Al-based alloy for direct comparison to coating behavior. FeAl and Fe3Al coatings showed corrosion rates slightly greater than that of wrought Fe3Al, but markedly lower than the steels at all temperatures. The corrosion rates of the coatings were relatively independent of temperature. Thermal cycling was performed on coated 316SS and nickel alloy 600 substrates from room temperature to 800°C to assess the relative effects of coating microstructure, residual stress, and thermal expansion mismatch on coating cracking by thermal fatigue. Measurement of coating ductility was made by acoustic emission monitoring of coated 316SS tensile specimens during loading.

  17. An Assessment of Density Functional Methods for Potential Energy Curves of Nonbonded Interactions: The XYG3 and B97-D Approximations

    SciTech Connect (OSTI)

    Vazquez-Mayagoitia, Alvaro; Sherrill, David; Apra, Edoardo; Sumpter, Bobby G

    2010-01-01

    A recently proposed double-hybrid functional called XYG3 and a semilocal GGA functional (B97-D) with a semiempirical correction for van der Waals interactions have been applied to study the potential energy curves along the dissociation coordinates of weakly bound pairs of molecules governed by London dispersion and induced dipole forces. Molecules treated in this work were the parallel sandwich, T-shaped, and parallel-displaced benzene dimer, (C6H6)2; hydrogen sulfide and benzene, H2S C6H6; methane and benzene, CH4 C6H6; the methane dimer, (CH4)2; and the pyridine dimer, (C5H5N)2. We compared the potential energy curves of these functionals with previously published benchmarks at the coupled cluster singles, doubles, and perturbative triplets [CCSD(T)] complete-basis-set limit. Both functionals, XYG3 and B97-D, exhibited very good performance, reproducing accurate energies for equilibrium distances and a smooth behavior along the dissociation coordinate. Overall, we found an agreement within a few tenths of one kcal mol-1 with the CCSD(T) results across the potential energy curves.

  18. Identification and Selection of Major Carbon Dioxide Stream Compositions

    SciTech Connect (OSTI)

    Last, George V.; Schmick, Mary T.

    2011-06-30

    A critical component in the assessment of long-term risk from geologic sequestration of CO2 is the ability to predict mineralogical and geochemical changes within storage reservoirs due to rock-brine-CO2 reactions. Impurities and/or other constituents selected for co-sequestration can affect both the chemical and physical (e.g. density, viscosity, interfacial tension) behavior of CO2 in the deep subsurface. These impurities and concentrations are a function of both the industrial source(s) of the CO2, as well as the carbon capture technology used to extract the CO2 and produce a concentrated stream for geologic sequestration. This report summarizes the relative concentrations of CO2 and other constituents in exhaust gases from major non-energy related industrial sources of CO2. Assuming that carbon-capture technology would remove most of the incondensable gases N2, O2, and Ar, leaving SO2 and NOx as the main impurities, we selected four test fluid compositions for use in geochemical experiments. These included: 1) a pure CO2 stream representative of food grade CO2 used in most enhanced oil recovery projects: 2) a test fluid composition containing low concentrations (0.5 mole %) SO2 and NOx (representative of that generated from cement production), 3) a test fluid composition with higher concentrations (2.5 mole %) of SO2, and 4) and test fluid composition containing 3 mole % H2S.

  19. A Biomass-based Model to Estimate the Plausibility of Exoplanet Biosignature Gases

    E-Print Network [OSTI]

    Seager, S; Hu, R

    2013-01-01

    Biosignature gas detection is one of the ultimate future goals for exoplanet atmosphere studies. We have created a framework for linking biosignature gas detectability to biomass estimates, including atmospheric photochemistry and biological thermodynamics. The new framework is intended to liberate predictive atmosphere models from requiring fixed, Earth-like biosignature gas source fluxes. New biosignature gases can be considered with a check that the biomass estimate is physically plausible. We have validated the models on terrestrial production of NO, H2S, CH4, CH3Cl, and DMS. We have applied the models to propose NH3 as a biosignature gas on a "cold Haber World," a planet with a N2-H2 atmosphere, and to demonstrate why gases such as CH3Cl must have too large of a biomass to be a plausible biosignature gas on planets with Earth or early-Earth-like atmospheres orbiting a Sun-like star. To construct the biomass models, we developed a functional classification of biosignature gases, and found that gases (such...

  20. Atmos. Chem. Phys., 11, 76577668, 2011 www.atmos-chem-phys.net/11/7657/2011/

    E-Print Network [OSTI]

    Meskhidze, Nicholas

    OBr +...), and particulate mer- cury (HgP ). Deposition of atmospheric Hg, mainly the more soluble forms of RGM and HgP

  1. EUROPEAN ORGANIZATION FOR NUCLEAR RESEARCH CERN-SL-2001-061 AP

    E-Print Network [OSTI]

    Keil, Eberhard

    .5 ¢ £¥¤ ¡§¨ 2.6 ¢ £¥¤ ¡§¨ Target material lHg Hg lHg Collection system Horn Horn Solenoid Energy range/MeV 100

  2. Supplementary materials for Impact of the isoprene photochemical cascade on tropical

    E-Print Network [OSTI]

    Meskhidze, Nicholas

    Hg2+ +2Br- 196.0 G A12 HgSO3+H2O Hg+HSO4 - +H+ 0106.0 H A13 Hg(OH)2 h Hg+2 OH 73 -E s-1 I #12(OH)+ 109.3 E A EQ2 Hg(OH)+ +OH- Hg(OH)2 116.1 E A EQ3 Hg2+ +SO3 2- HgSO3 131.2 E B EQ4 HgSO3+ SO3 2- Hg(SO3)22- 100.1 E B EQ5 Hg(OH)+ +Cl- HgOHCl 77.2 E A EQ6 Hg(II)+Cl- HgCl+ 70.2 E C EQ7 HgCl+ +Cl- Hg

  3. Supplementary Information Supplementary Figure 1. Simulated vs. measured diurnal profiles of GEM and BrO.

    E-Print Network [OSTI]

    Meskhidze, Nicholas

    Hg2+ +2Br- 196.0 G A12 HgSO3+H2O Hg+HSO4 - +H+ 0106.0 H A13 Hg(OH)2 h Hg+2 OH 73 -E s-1 I #12(OH)+ 109.3 E A EQ2 Hg(OH)+ +OH- Hg(OH)2 116.1 E A EQ3 Hg2+ +SO3 2- HgSO3 131.2 E B EQ4 HgSO3+ SO3 2- Hg(SO3)22- 100.1 E B EQ5 Hg(OH)+ +Cl- HgOHCl 77.2 E A EQ6 Hg(II)+Cl- HgCl+ 70.2 E C EQ7 HgCl+ +Cl- Hg

  4. WAT ENVIRON RESEARCH (in press, final version may have small changes) ODOR AND VOC TREATMENT BY BIOTRICKLING FILTERS: PILOT SCALE

    E-Print Network [OSTI]

    in Los Angeles to study H2S/odor and VOC removal from the Headworks' waste air. The performance to the efficiency of removal of H2S as the major pollutant. VOCs were present at concentrations up to 150 ppb. Low Biotrickling filter, biological waste air treatment, hydrogen sulfide, odor, VOCs. #12;INTRODUCTION

  5. Generation of DNA-Damaging Reactive Oxygen Species via the Autoxidation of Hydrogen Sulfide under Physiologically Relevant

    E-Print Network [OSTI]

    Gates, Kent. S.

    Generation of DNA-Damaging Reactive Oxygen Species via the Autoxidation of Hydrogen Sulfide under found that micromolar concentrations of H2S generated single-strand DNA cleavage. Mechanistic studies indicate that this process involved autoxidation of H2S to generate superoxide, hydrogen peroxide, and

  6. Adsorption of Hydrogen Sulfide onto Activated Carbon Fibers: Effect of

    E-Print Network [OSTI]

    Borguet, Eric

    about 95-97% of the hydrogen sulfide, emissions from Claus units are now becoming a source of H2S with other gases such as COS, CS2, and CO2 at various concentrations. Now Claus plants are required to reduce H2S emissions from the tail gas (7). Adsorption/oxidation by carbonaceous surfaces

  7. Temporal influences of seasonal hypoxia on sediment biogeochemistry in coastal sediments 

    E-Print Network [OSTI]

    Sell, Karen S.

    2004-11-15

    +) and sulfide ([sigma]H2S) were the redox reactive species in these sediments. During hypoxic conditions an upward migration of dissolved Fe2+and [sigma]H2S through the sediment column and, at times, into the overlying water was observed as the dissolved oxygen...

  8. Published: December 06, 2011 r 2011 American Chemical Society 2411 dx.doi.org/10.1021/jp205573v |J. Phys. Chem. C 2012, 116, 24112424

    E-Print Network [OSTI]

    Yildiz, Bilge

    production and exploration fields since H2S and H2O are present in the drilling fluids, and H2S, in particular, is thought to be very aggressive to steels and Ni alloys.13,14 Drilling environ- ments contain up

  9. Dynamic viscosity estimation of hydrogen sulfide using a predictive scheme based on molecular dynamics.

    E-Print Network [OSTI]

    Boyer, Edmond

    natural gases containing hydrogen sulfide H2S and/or carbon dioxide CO2) are often encountered properties are very scarce because of the very high toxicity of H2S which leads to very complicated safety procedures for the experimentalists. This is especially true for the high pressures and temperatures

  10. Persisting impact of historical mining activity to metal (Pb, Zn, Cd, Tl, Hg) and metalloid (As, Sb) enrichment in sediments of the Gardon River,

    E-Print Network [OSTI]

    Cattin, Rodolphe

    in 1976 attributed to a tailings dam failure, and (iii) current levels in 2002 and 2011 similar to those

  11. Muon Collider / Neutrino Factory Targetry R&D 2009-2012 V.B. Graves, H.G. Kirk, K.T. McDonald

    E-Print Network [OSTI]

    McDonald, Kirk

    the solenoidal magnet system that captures/confines secondary pions. The baseline concept is that a pool of the pool/dump to mitigate the effects of disruption of the pool by the proton beam, and by the incoming

  12. Evidence for Half-Metallicity in n-type HgCr2Se4 Tong Guan, Chaojing Lin, Chongli Yang, Youguo Shi,*

    E-Print Network [OSTI]

    Wang, Wei Hua

    spintronic material due to its s-band half-metallicity when doped to n-type [4]. Ferromagnetic order in ACr2X polarization of itinerant carriers makes half-metals very attractive for spintronic applications

  13. Acceptor and donor production in Hg b1 s[subscript -x]Cd[subscript x]Te by neutron transmutation doping 

    E-Print Network [OSTI]

    Seager, Kevin Douglas

    1985-01-01

    ACCEPTOR AND DONOR PRODUCTION IN Hgi ?Cd?Te BY NEUTRON TRANSMUTATION DOPING A Thesis by KEVIN DOUGLAS SEAGFR Submitted to the Graduate College of Texas ASM University in partial fulfillment of the requirement for the degree of MASTER... OF SCIENCE December 1985 Majon Subject: Nuclear Fngineer ing ACCEPTOR AND DONOR PRODUCTION IN Hgl-xCdxTe BY NEUTRON TRANSMUTATION DOPING A Thesis by KEVIN DOUGLAS SEAGER Approved as to style and content by: Ron R. Hart (Chairman of Committee...

  14. Development of a coherent vacuum ultraviolet source at 104108 nm generated by four-wave sum frequency mixing in Hg vapor

    E-Print Network [OSTI]

    Kim, Myung Soo

    Development of a coherent vacuum ultraviolet source at 104­108 nm generated by four-wave sum-harmonic generation and four-wave mixing in a gas- eous nonlinear medium.8­11 Two tunable outputs from a pulsed dye ultraviolet VUV light source in the 104­108 nm range has been developed by utilizing four-wave sum frequency

  15. 1302 J. Phys. Chem. 1981, 85,1302-1305 PhotochemicalIsotope Separation of Hg-196 by Reaction with Hydrogen Halides

    E-Print Network [OSTI]

    chloride as substrate with added butadiene. The enrichment is definedhere asthe finalisotopicabundanceover amounts of the hydrogen halide (HC1,HBr, or HI) gas to be mixed with a fractional amount of l,&butadiene are of the highest purity commercially available (>99.9% for HC1). Before entry into the reaction cell, the butadiene

  16. Transient studies of an Integrated Gasification Combined Cycle (IGCC) plant with CO2 capture

    SciTech Connect (OSTI)

    Bhattacharyya, D.; Turton, R.; Zitney, S.

    2010-01-01

    Next-generation coal-fired power plants need to consider the option for CO2 capture as stringent governmental mandates are expected to be issued in near future. Integrated gasification combined cycle (IGCC) plants are more efficient than the conventional coal combustion processes when the option for CO2 capture is considered. However, no IGCC plant with CO2 capture currently exists in the world. Therefore, it is important to consider the operability and controllability issues of such a plant before it is commercially built. To facilitate this objective, a detailed plant-wide dynamic simulation of an IGCC plant with 90% CO2 capture has been developed in Aspen Plus Dynamics{reg_sign}. The plant considers a General Electric Energy (GEE)-type downflow radiant-only gasifier followed by a quench section. A two-stage water gas shift (WGS) reaction is considered for conversion of CO to CO2. A two-stage acid gas removal (AGR) process based on a physical solvent is simulated for selective capture of H2S and CO2. Compression of the captured CO2 for sequestration, an oxy-Claus process for removal of H2S and NH3, black water treatment, and the sour water treatment are also modeled. The tail gas from the Claus unit is recycled to the SELEXOL unit. The clean syngas from the AGR process is sent to a gas turbine followed by a heat recovery steam generator. This turbine is modeled as per published data in the literature. Diluent N2 is used from the elevated-pressure ASU for reducing the NOx formation. The heat recovery steam generator (HRSG) is modeled by considering generation of high-pressure, intermediate-pressure, and low-pressure steam. All of the vessels, reactors, heat exchangers, and the columns have been sized. The basic IGCC process control structure has been synthesized by standard guidelines and existing practices. The steady state results are validated with data from a commercial gasifier. In the future grid-connected system, the plant should satisfy the environmental targets and quality of the feed to other sections, wherever applicable, without violating the operating constraints, and without sacrificing the efficiency. However, it was found that the emission of acid gases may far exceed the environmental targets and the overshoot of some of the key variables may be unacceptable under transient operation while following the load. A number of operational strategies and control configurations is explored for achieving these stringent requirements. The transient response of the plant is also studied by perturbing a number of key inputs.

  17. Development of Silica/Vanadia/ Titania Catalysts for Removal of

    E-Print Network [OSTI]

    Li, Ying

    - bound Hg (Hgp) (4). Hgp can be collected in electrostatic precipitators (ESPs) and/or baghouses. Hg2

  18. Development of an Integrated Multi-Contaminant Removal Process Applied to Warm Syngas Cleanup for Coal-Based Advanced Gasification Systems

    SciTech Connect (OSTI)

    Howard Meyer

    2010-11-30

    This project met the objective to further the development of an integrated multi-contaminant removal process in which H2S, NH3, HCl and heavy metals including Hg, As, Se and Cd present in the coal-derived syngas can be removed to specified levels in a single/integrated process step. The process supports the mission and goals of the Department of Energyâ??s Gasification Technologies Program, namely to enhance the performance of gasification systems, thus enabling U.S. industry to improve the competitiveness of gasification-based processes. The gasification program will reduce equipment costs, improve process environmental performance, and increase process reliability and flexibility. Two sulfur conversion concepts were tested in the laboratory under this project, i.e., the solventbased, high-pressure University of California Sulfur Recovery Process â?? High Pressure (UCSRP-HP) and the catalytic-based, direct oxidation (DO) section of the CrystaSulf-DO process. Each process required a polishing unit to meet the ultra-clean sulfur content goals of <50 ppbv (parts per billion by volume) as may be necessary for fuel cells or chemical production applications. UCSRP-HP was also tested for the removal of trace, non-sulfur contaminants, including ammonia, hydrogen chloride, and heavy metals. A bench-scale unit was commissioned and limited testing was performed with simulated syngas. Aspen-Plus®-based computer simulation models were prepared and the economics of the UCSRP-HP and CrystaSulf-DO processes were evaluated for a nominal 500 MWe, coal-based, IGCC power plant with carbon capture. This report covers the progress on the UCSRP-HP technology development and the CrystaSulf-DO technology.

  19. Natural biogeochemical cycle of mercury in a global three-dimensional ocean tracer model

    E-Print Network [OSTI]

    Lyatt Jaeglé

    (HgP aq). Our Hg parameterization takes into account redox chemistry in ocean waters, air-sea exchange global mean concentrations of 0.16 pM for total Hg, partitioned as 80% HgII aq, 14% Hg0 aq, and 6% HgP aq

  20. Stress corrosion cracking: New experiments, new insights M I T E N E R G Y I N I T I AT I V E A U T U M N 2 0 1 2

    E-Print Network [OSTI]

    Yildiz, Bilge

    in 10.27 Renovation plans offer MIT opportunities to save energy, improve design Reducing wasted energy A R C H R E P O R T S 4 Harnessing solar energy: Novel approach yields both electricity and heat 7, energy-saving approach 16 Innovation prizes: Understanding how they work 20 Capturing energy from the sun