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Note: This page contains sample records for the topic "mtbe ethyl tertiary" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
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1

State Restrictions on Methyl Tertiary Butyl Ether (released in AEO2006)  

Reports and Publications (EIA)

By the end of 2005, 25 states had barred, or passed laws banning, any more than trace levels of methyl tertiary butyl ether (MTBE) in their gasoline supplies, and legislation to ban MTBE was pending in 4 others. Some state laws address only MTBE; others also address ethers such as ethyl tertiary butyl ether (ETBE) and tertiary amyl methyl ether (TAME). Annual Energy Outlook 2006 assumes that all state MTBE bans prohibit the use of all ethers for gasoline blending.

2006-01-01T23:59:59.000Z

2

Induction of Methyl Tertiary Butyl Ether (MTBE)-Oxidizing Activity in Mycobacterium vaccae JOB5 by MTBE  

Science Journals Connector (OSTI)

...directly from the culture vessels. In experiments that followed...time course of organic acid consumption as well as MTBE oxidation...determine the extent of MTBE consumption and the accumulation of TBA...detectable growth or MTBE consumption occurred when cells were incubated...

Erika L. Johnson; Christy A. Smith; Kirk T. O'Reilly; Michael R. Hyman

2004-02-01T23:59:59.000Z

3

MTBE Production Economics  

Gasoline and Diesel Fuel Update (EIA)

MTBE Production MTBE Production Economics Tancred C. M. Lidderdale Contents 1. Summary 2. MTBE Production Costs 3. Relationship between price of MTBE and Reformulated Gasoline 4. Influence of Natural Gas Prices on the Gasoline Market 5. Regression Results 6. Data Sources 7. End Notes 1. Summary Last year the price of MTBE (methyl tertiary butyl ether) increased dramatically on two occasions (Figure 1) (see Data Sources at end of article.): 1. Between April and June 2000, the price (U.S. Gulf Coast waterborne market) of MTBE rose from $1.00 per gallon to over $1.60 per gallon. This represented an increase in the price premium for MTBE over the wholesale price of conventional gasoline from its normal (1995 though 2000 average) $0.26 per gallon to $0.60 per gallon. The MTBE

4

MTBE Production Economics (Released in the STEO April 2001)  

Reports and Publications (EIA)

The purpose of this analysis is to evaluate the causes of methyl tertiary butyl ether (MTBE) price increases in 2000.

2001-01-01T23:59:59.000Z

5

MTBE, Oxygenates, and Motor Gasoline  

Gasoline and Diesel Fuel Update (EIA)

MTBE, Oxygenates, and MTBE, Oxygenates, and Motor Gasoline Contents * Introduction * Federal gasoline product quality regulations * What are oxygenates? * Who gets gasoline with oxygenates? * Which areas get MTBE? * How much has been invested in MTBE production capacity? * What does new Ethanol capacity cost? * What would an MTBE ban cost? * On-line information resources * Endnotes * Summary of revisions to this analysis Introduction The blending of methyl tertiary butyl ether (MTBE) into motor gasoline has increased dramatically since it was first produced 20 years ago. MTBE usage grew in the early 1980's in response to octane demand resulting initially from the phaseout of lead from gasoline and later from rising demand for premium gasoline. The oxygenated gasoline program stimulated an

6

Drinking Water Problems: MTBE  

E-Print Network (OSTI)

Methyl tertiary-butyl ether, a gasoline additive commonly known as MTBE, can contaminate ground water and cause health problems for those exposed to it for a long time. However, filtering devices can remove this and other additives from well water...

Dozier, Monty; Lesikar, Bruce J.

2008-08-28T23:59:59.000Z

7

Role of Volatilization in Changing TBA and MTBE Concentrations at  

E-Print Network (OSTI)

a low affinity for gasoline (low Kfw, Table 1). Therefore, minute amounts of TBA in the MTBE blended tertiary butyl ether (MTBE) added to gasoline. Frequent observations of high TBA, and especially rising TBA/MTBE concentration ratios, in groundwater at gasoline spill sites are generally attributed to microbial conversion

8

Status and Impact of State MTBE Bans  

Gasoline and Diesel Fuel Update (EIA)

Status and Impact of State MTBE Bans Status and Impact of State MTBE Bans Background As a result of the Clean Air Act Amendments of 1990 (CAAA90), the year-round use of reformulated gasoline (RFG) has been required in cities with the worst smog problems since 1995 (Figure 1). One of the requirements of RFG specified by CAAA90 is a 2- percent oxygen requirement, which is met by blending "oxygenates," 1 including methyl tertiary butyl ether (MTBE) and ethanol, into the gasoline. MTBE is the oxygenate used in almost all RFG outside of the Midwest. Ethanol is currently used in the Midwest as an oxygenate in RFG and as an octane booster and volume extender in conventional gasoline. Several years ago, MTBE was detected in water supplies scattered throughout the country, but predominantly in areas using RFG. MTBE from RFG was apparently

9

Motor Gasoline Outlook and State MTBE Bans  

Gasoline and Diesel Fuel Update (EIA)

Motor Gasoline Outlook Motor Gasoline Outlook and State MTBE Bans Tancred Lidderdale Contents 1. Summary 2. MTBE Supply and Demand 3. Ethanol Supply 4. Gasoline Supply 5. Gasoline Prices A. Long-Term Equilibrium Price Analysis B. Short-Term Price Volatility 6. Conclusion 7. Appendix A. Estimating MTBE Consumption by State 8. Appendix B. MTBE Imports and Exports 9. Appendix C. Glossary of Terms 10. End Notes 11. References 1. Summary The U.S. is beginning the summer 2003 driving season with lower gasoline inventories and higher prices than last year. Recovery from this tight gasoline market could be made more difficult by impending State bans on the blending of methyl tertiary butyl ether (MTBE) into gasoline that are scheduled to begin later this year. Three impending State bans on MTBE blending could significantly affect gasoline

10

Eliminating MTBE in Gasoline in 2006  

Gasoline and Diesel Fuel Update (EIA)

02/22/2006 02/22/2006 Eliminating MTBE in Gasoline in 2006 Summary In 2005, a number of petroleum companies announced their intent to remove methyl tertiary-butyl ether (MTBE) from their gasoline in 2006. Companies' decisions to eliminate MTBE have been driven by State bans due to water contamination concerns, continuing liability exposure from adding MTBE to gasoline, and perceived potential for increased liability exposure due to the elimination of the oxygen content requirement for reformulated gasoline (RFG) included in the Energy Policy Act of 2005. EIA's informal discussions with a number of suppliers indicate that most of the industry is trying to move away from MTBE before the 2006 summer driving season. Currently, the largest use of MTBE is in RFG consumed on the East Coast outside of

11

UMass builds bugs to eat MTBE ByAuriaCimino  

E-Print Network (OSTI)

a toxic gasoline component might be just what the doctor ordered for Maine's con- taminated groundwater with methyl tertiary butyl ether (MTBE), which is found in gasoline. Once the first field trial is complete out of the reformulated gasoline pro- gram (RFG) .The gasoline, which con- tains 11 percent MTBE

Lovley, Derek

12

Motor Gasoline Outlook and State MTBE Bans  

Reports and Publications (EIA)

The U.S. is beginning the summer 2003 driving season with lower gasoline inventories and higher prices than last year. Recovery from this tight gasoline market could be made more difficult by impending state bans on the blending of methyl tertiary butyl ether (MTBE) into gasoline that are scheduled to begin later this year.

2003-01-01T23:59:59.000Z

13

MTBE, Oxygenates, and Motor Gasoline (Released in the STEO October 1999)  

Reports and Publications (EIA)

The blending of methyl tertiary butyl ether (MTBE) into motor gasoline has increased dramatically since it was first produced 20 years ago. MTBE usage grew in the early 1980's in response to octane demand resulting initially from the phaseout of lead from gasoline and later from rising demand for premium gasoline. The oxygenated gasoline program stimulated an increase in MTBE production between 1990 and 1994. MTBE demand increased from 83,000 in 1990 to 161,000 barrels per day in 1994. The reformulated gasoline (RFG) program provided a further boost to oxygenate blending. The MTBE contained in motor gasoline increased to 269,000 barrels per day by 1997.

1999-01-01T23:59:59.000Z

14

Microsoft Word - LBNL 53866_SPME-MTBE_Final_112103.doc  

Office of Scientific and Technical Information (OSTI)

There are numerous sources of MTBE contamination including leaking underground storage tanks, surface runoff, and precipitation (1-4). In California, MTBE contamination of...

15

MTBE Prices Responded to Natural Gas Prices  

Gasoline and Diesel Fuel Update (EIA)

6 6 Notes: On top of the usual factors impacting gasoline prices, natural gas has had some influence recently. MTBE is an oxygenate used in most of the RFG consumed in the U.S. Generally, it follows gasoline prices and its own supply/demand balance factors. But this winter, we saw it respond strongly to natural gas prices. MTBE is made from methanol and isobutylene, which in turn come from methane and butane. Both methane and butane come from natural gas streams. Until this year, the price of natural gas has been so low that it had little effect. But the surge that occurred in December and January pulled MTBE up . Keep in mind that about 11% MTBE is used in a gallon of RFG, so a 30 cent increase in MTBE is only about a 3 cent increase in the price of RFG. While we look ahead at this summer, natural gas prices should be

16

Remedial Costs for MTBE in Soil and Ground Water  

Science Journals Connector (OSTI)

The contamination of MTBE in ground water has introduced concerns about the increased cost of remediating MTBE/BTEX releases compared to remediating sites with BTEX only contamination. In an attempt to evaluat...

Barbara H. Wilson; John T. Wilson Ph.D.

2003-01-01T23:59:59.000Z

17

E-Print Network 3.0 - aerobic mtbe biodegradation Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

27 ACCEPTED BY WATER ENVIRONMENT RESEARCH ODOR AND VOC REMOVAL FROM WASTEWATER TREATMENT PLANT Summary: capable of MTBE biodegradation. 12;Effective treatment of a mixture...

18

Environmental Microbiology (2001) 3(6), 407416 Methyl tert-butyl ether (MTBE) degradation by a  

E-Print Network (OSTI)

Tank (LUFT) remediation programme. A recent USGS study has estimated that as many as 9000 community, remediation actions are implemented at costs usually 10± 30% higher than those at sites without MTBE contamina- tion. The evaluation of innovative and cost-effective treatment such as bioremediation for MTBE spills

19

Spitsbergen Tertiary Coal Fossils  

Science Journals Connector (OSTI)

... grains and spores to be observed in coal deposits of Tertiary age in west Spitsbergen (Norsk Polarinstitutt, Med. 79, pp. 1-9; 1954; English summary).

1955-08-06T23:59:59.000Z

20

Remediation of Releases Containing MTBE at Gasoline Station Sites—ENSR International’s Experience  

Science Journals Connector (OSTI)

This chapter summarizes ENSR’s national and international experience remediating MTBE and other gasoline constituents in soil and ground water at retail gasoline station sites. ENSR has extensive experience in...

Robert M. Cataldo P.G.

2003-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "mtbe ethyl tertiary" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Preparations for Meeting New York and Connecticut MTBE Bans  

Gasoline and Diesel Fuel Update (EIA)

2 2 Preparations for Meeting New York and Connecticut MTBE Bans October 2003 Office of Oil and Gas Energy Information Administration U.S. Department of Energy Washington, DC 20585 This report was prepared by the Energy Information Administration, the independent statistical and analytical agency within the Department of Energy. The information contained herein should not be construed as advocating or reflecting any policy position of the Department of Energy or of any other organization. Contacts and Acknowledgments This report was prepared by the Office of Oil and Gas of the Energy Information Administration (EIA) under the direction of John Cook, Director, Petroleum Division. Questions concerning the report may be directed to Joanne Shore (202/586-4677),

22

Automobile proximity and indoor residential concentrations of BTEX and MTBE  

SciTech Connect

Attached garages have been identified as important sources of indoor residential air pollution. However, the literature lacks information on how the proximity of cars to the living area affects indoor concentrations of gasoline-related compounds, and the origin of these pollutants. We analyzed data from the Relationships of Indoor, Outdoor, and Personal Air (RIOPA) study and evaluated 114 residences with cars in an attached garage, detached garage or carport, or without cars. Results indicate that homes with cars in attached garages were affected the most. Concentrations in homes with cars in detached garages and residences without cars were similar. The contribution from gasoline-related sources to indoor benzene and MTBE concentrations appeared to be dominated by car exhaust, or a combination of tailpipe and gasoline vapor emissions. Residing in a home with an attached garage could lead to benzene exposures ten times higher than exposures from commuting in heavy traffic.

Corsi, Dr. Richard [University of Texas, Austin; Morandi, Dr. Maria [University of Texas Health Science Center, Houston; Siegel, Dr. Jeffrey [University of Texas, Austin; Hun, Diana E [ORNL

2011-01-01T23:59:59.000Z

23

IDENTIFYING THE USAGE PATTERNS OF METHYL TERT-BUTYL ETHER (MTBE) AND OTHER OXYGENATES IN GASOLINE USING GASOLINE  

E-Print Network (OSTI)

IDENTIFYING THE USAGE PATTERNS OF METHYL TERT-BUTYL ETHER (MTBE) AND OTHER OXYGENATES IN GASOLINE USING GASOLINE SURVEYS By Michael J. Moran, Rick M. Clawges, and John S. Zogorski U.S. Geological Survey 1608 Mt. View Rapid City, SD 57702 Methyl tert-butyl ether (MTBE) is commonly added to gasoline

24

energy savings by the use of mtbe to replace alkylate in automotive gasolines  

SciTech Connect

This paper presents data on the differences in energy consumption in the production of leaded and unleaded AI-93 gasolines with various blend components. The authors investigate as high-octane components certain products that are more effective in use and less energy-consuming in production in comparison with alkylate. In particular, methyl tert-butyl ether (MTBE) is discussed; it is not poisonous, it has a high heat of combustion, and it does not attack materials of construction. The addition of 11% MTBE to gasoline lowers the cold start temperature of engines by 10-12 degrees. Moreover, no adjustment of the carburetor is required for the changeover to gasoline with 11% MTBE.

Englin, B.A.; Emel'yanov, V.E.; Terent'ev, G.A.; Vinogradov, A.M.

1986-07-01T23:59:59.000Z

25

Kinetics of ethanol dehydrogenation into ethyl acetate  

Science Journals Connector (OSTI)

The kinetics of gas-phase dehydrogenation of ethanol into ethyl acetate over a copper-zinc- ... means to design a reactor for dehydrogenation of ethanol into ethyl acetate in different regimes.

V. A. Men’shchikov; L. Kh. Gol’dshtein; I. P. Semenov

2014-01-01T23:59:59.000Z

26

Impacts of Ethanol on Anaerobic Production of Tert-Butyl Alcohol (TBA) from Methyl Tert-Butyl Ether (MTBE) in Groundwater  

E-Print Network (OSTI)

Project title: Impacts of Ethanol on Anaerobic Production oftert-butanol (TBA). As ethanol is being promoted as ainvestigate the effect of ethanol release on existing MTBE

Scow, K M; MacKay, Douglas

2008-01-01T23:59:59.000Z

27

VOL. 32, No.4 UNL WATER CENTER AUGUST 2000 New Method For Detecting Trace Amounts of MTBE  

E-Print Network (OSTI)

water their use to help curb growing prob- at spill sites. lems with air pollution. MTBE is the most emis-by Steve Ress sions, are considered small. Gasoline additives that help keep our air clean can- "Most of the information available on oxygenates 10 mine the extent of their environmental impacts

Nebraska-Lincoln, University of

28

Process for the preparation of ethyl benzene  

DOE Patents (OSTI)

Ethyl benzene is produced in a catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 50.degree. C. to 300.degree. C., using as the catalyst a mole sieve characterized as acidic by feeding ethylene to the catalyst bed while benzene is conveniently added through the reflux to result in a molar excess present in the reactor to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene and diethyl benzene in the bottoms. The bottoms are fractionated, the ethyl benzene recovered and the bottoms are contacted with benzene in the liquid phase in a fixed bed straight pass reactor under conditions to transalkylate the benzene thereby converting most of the diethyl benzene to ethyl benzene which is again separated and recovered.

Smith, Jr., Lawrence A. (Houston, TX); Arganbright, Robert P. (Houston, TX); Hearn, Dennis (Houston, TX)

1995-01-01T23:59:59.000Z

29

Process for the preparation of ethyl benzene  

DOE Patents (OSTI)

Ethyl benzene is produced in a catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 50 C to 300 C, using as the catalyst a mole sieve characterized as acidic by feeding ethylene to the catalyst bed while benzene is conveniently added through the reflux to result in a molar excess present in the reactor to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene and diethyl benzene in the bottoms. The bottoms are fractionated, the ethyl benzene recovered and the bottoms are contacted with benzene in the liquid phase in a fixed bed straight pass reactor under conditions to transalkylate the benzene thereby converting most of the diethyl benzene to ethyl benzene which is again separated and recovered. 2 figs.

Smith, L.A. Jr.; Arganbright, R.P.; Hearn, D.

1995-12-19T23:59:59.000Z

30

Isobaric vapor–liquid equilibria of binary system ethyl acetate + ethyl benzene + lithium bromide  

Science Journals Connector (OSTI)

Lithium bromide salt (99.9 wt% purity) ... . The salt studied was dissolved in ethyl acetate as a solvent to the saturated level...

Zaid Ahmed Al-Anber; Munther Issa Kandah…

2013-05-01T23:59:59.000Z

31

Use of superconductor type catalysts in the preparation of tertiary butyl alcohol from tertiary butyl hydroperoxide  

SciTech Connect

In a method wherein a solution of a tertiary butyl hydroperoxide charge stock in tertiary butyl alcohol is brought into contact with a catalytically effective amount of a hydroperoxide decomposition catalyst in a hydroperoxide decomposition reaction zone in liquid phase with agitation to convert said tertiary butyl hydroperoxide to decomposition products, principally tertiary butyl alcohol, the improvement is described which comprises: (a) using a superconductor as said hydroperoxide decomposition catalyst, and (b) recovering tertiary butyl alcohol from the products of said hydroperoxide decomposition reaction.

Sanderson, J.R.; Stockton, M.E.

1993-08-17T23:59:59.000Z

32

Concentrating aqueous acetate solutions with tertiary amines  

E-Print Network (OSTI)

Water may be extracted from aqueous calcium acetate or sodium acetate solutions using low miscibility, low molecular weight tertiary amines, e.g. triethylamine (TEA) and N,N- dietliylmethylaniine (DEMA). This novel extraction technology...

Lee, Champion

2012-06-07T23:59:59.000Z

33

Control Study of Ethyl tert-Butyl Ether Reactive Distillation Muhammad A. Al-Arfaj  

E-Print Network (OSTI)

-butyl ether (ETBE) for gasoline blending as a replacement for methyl tert-butyl ether (MTBE) because and be blended with ETBE in the gasoline pool. Even for neat operation, if the conversion is low, the unconverted

Al-Arfaj, Muhammad A.

34

Methyl tert-butyl ether (MTBE) is a volatile organic com-pound (VOC) derived from natural gas that is added to gas-  

E-Print Network (OSTI)

Methyl tert-butyl ether (MTBE) is a volatile organic com- pound (VOC) derived from natural gas Water in Urban and Agricultural Areas made from methanol, which is derived primarily from natural gas that is added to gas- oline either seasonally or year round in many parts of the United States to increase

35

Quarterly Technical Progress Report - West Hackberry Tertiary Project  

SciTech Connect

The West Hackberry Tertiary Project is a field test of the concept that air injection can generate tertiary oil recovery through the Double Displacement Process is the gas displacement of a water invaded oil column for the purpose of recovering tertiary oil through gravity discharge. The novel aspect of this project is the use of air as the injection fluid.

Demetrois Yannimaras; Travis Gillham

1998-04-15T23:59:59.000Z

36

Quarterly Technical Progress Report - West Hackberry Tertiary Project  

SciTech Connect

The West Hackberry Tertiary Project is a field test of the concept that air injection can generate tertiary oil recovery through the Double Displacement Process is the gas displacement of a water invaded oil column for the purpose of recovering tertiary oil through gravity discharge. The novel aspect of this project is the use of air as the injection fluid.

Bruce Cerveny; Tor Kragas; Travis Gillham

1998-01-13T23:59:59.000Z

37

A SUMMARY OF COAL IN THE COALMONT FORMATION (TERTIARY),  

E-Print Network (OSTI)

Chapter SN A SUMMARY OF COAL IN THE COALMONT FORMATION (TERTIARY), NORTH PARK BASIN, COLORADO By S assessment of selected Tertiary coal beds and zones in the Northern RockyMountains and Great Plains region, U Resource assessment of selected Tertiary coal beds and zones in the Northern Rocky Mountains and Great

38

Effects of Gasoline Formulation on Methyl tert-Butyl Ether (MTBE) Contamination in Private Wells near Gasoline Stations  

Science Journals Connector (OSTI)

New York State Department of Health, Bureau of Environmental Exposure Investigation, 547 River Street, Room 300, Troy, New York 12180, and New York State Department of Health, Wadsworth Center for Laboratories and Research, P.O. ... Wells with contamination of ?20 ?g/L were scheduled for periodic or follow-up sampling by local county health departments or scheduled for remedial action, as appropriate. ... (13)?Delzer, G. C.; Zogorski, J. S.; Lopes, T. J.; Bosshart, R. L. Occurrence of the gasoline Oxygenate MTBE and BTEX compounds in urban stormwater in the United States, 1991?1995; U.S. Geologic Survey Water-Resources Investigations Report, WRIR 96-4145, Rapid City, SD, 1996. ...

Daniel P. Lince; Lloyd R. Wilson; Gordon A. Carlson; Anthony Bucciferro

2001-02-10T23:59:59.000Z

39

Catalytic distillation for the synthesis of tertiary butyl alcohol.  

E-Print Network (OSTI)

??Catalytic Distillation for the synthesis of tertiary butyl alcohol (TBA) is investigated in this thesis. The solvent, ethylene glycol, is proposed as a means of… (more)

Safinski, Tomasz

2005-01-01T23:59:59.000Z

40

Aqueous flooding methods for tertiary oil recovery  

DOE Patents (OSTI)

A method of aqueous flooding of subterranean oil bearing formation for tertiary oil recovery involves injecting through a well into the formation a low alkaline pH aqueous sodium bicarbonate flooding solution. The flooding solution's pH ranges from about 8.25 to 9.25 and comprises from 0.25 to 5 weight percent and preferably about 0.75 to 3.0 weight percent of sodium bicarbonate and includes a petroleum recovery surfactant of 0.05 to 1.0 weight percent and between 1 and 20 weight percent of sodium chloride. After flooding, an oil and water mixture is withdrawn from the well and the oil is separated from the oil and water mixture.

Peru, Deborah A. (Bartlesville, OK)

1989-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "mtbe ethyl tertiary" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Blended language learning in tertiary education  

Science Journals Connector (OSTI)

This paper examines the supporting and enhancing role of technology in language learning and teaching in a higher education institution in Slovenia. Despite the fact that the vast majority of foreign language teaching is still carried out in face-to-face environments, a growing extent of foreign language teaching in a number of tertiary education institutions has moved, at least partly, online. In this paper, the development of e-learning practices in Slovenia is described first, together with the evolution of computer technologies – from multimedia to the internet – and their potential for language learning and teaching purposes. Against this background, the practical application of the Blended Language Learning (BLL) experience at the Faculty of Management Koper is discussed. The paper also addresses the changing role of teachers in blended language teaching/learning environments and analyses the opinions of students who participated in a combination of Face-to-Face (F2F) and Computer-Assisted Language Learning (CALL) courses and expressed their opinions on the BLL experience in a questionnaire.

Igor Riznar

2009-01-01T23:59:59.000Z

42

A SUMMARY OF COAL IN THE FORT UNION FORMATION (TERTIARY), BIGHORN BASIN,  

E-Print Network (OSTI)

Chapter SB A SUMMARY OF COAL IN THE FORT UNION FORMATION (TERTIARY), BIGHORN BASIN, WYOMING assessment of selected Tertiary coal beds and zones in the Northern RockyMountains and Great Plains region, U...........................................................................................................................SB-1 Coal Production History

43

E-Print Network 3.0 - australian tertiary referral Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

Darwin Institution Programme Summary: ANUTECH (Australian National University) Foundation Studies Program Australian National University... for Tertiary Studies) Batchelor...

44

EXECUTIVE SUMMARY TERTIARY COAL RESOURCES IN THE NORTHERN  

E-Print Network (OSTI)

EXECUTIVE SUMMARY TERTIARY COAL RESOURCES IN THE NORTHERN ROCKY MOUNTAINS AND GREAT PLAINS REGION RockyMountains and Great Plains region, U.S. Geological Survey Professional Paper 1625-A Click here in the Northern Rocky Mountains and Great Plains region, U.S. Geological Survey Professional Paper 1625-A #12;ES

45

Aptamer-Based Microcantilever Sensor for O-ethyl S-[2(diisopropylamino)ethyl] methylphosphonothiolate, Sarin Detection and Kinetic Analysis  

Science Journals Connector (OSTI)

Abstract A novel method for O-ethyl S-[2(diisopropylamino)ethyl] methylphosphonothiolate (VX), sarin detection and kinetic analysis based on piezoresistive microcantilever aptasensor was proposed, where VX and sarin aptamers were immobilized on the microcantilever surface by biotin-avidin binding system. A linear relationship between the response voltage and the concentration of VX in the range of 2?60 ?g L?1 was obtained, the linear regression equation was ?Ue = 0.886C ? 1.039 (n = 5, R = 0.984, p < 0.001) and the detection limit was 2 ?g L?1 (S/N ?A linear relationship between the response voltage and the concentration of sarin in the range of 10?60 ?g L?1 was obtained, the linear regression equation was ?Ue = 0.716C ? 2.304 (n = 5, R = 0.996, p < 0.001) and the detection limit was 10 ?g L?1 (S/N ?The sensor showed no response for O-butyl methylphosphonochloridate, a structural analog of VX and sarin, indicating a high specificity and good selectivity. On this basis, a reaction kinetic model based on receptor-ligand binding and the relationship with response voltage was established. Response voltage (?Ue) and response time (t0) obtained from the fitting equation on different concentrations of VX and sarin fitted well with the measured values.

Zhi-Wei LIU; Zhao-Yang TONG; Lan-Qun HAO; Bing LIU; Xi-Hui MU; Jin-Ping ZHANG; Chuan GAO

2014-01-01T23:59:59.000Z

46

Reactions of Ethyl Groups on a Model Chromia Surface: Ethyl Chloride on Stoichiometric Alpha-Cr2O3(1012)  

SciTech Connect

The reaction of CH3CH2Cl over the nearly-stoichiometric ?-Cr2O3 (1 0 View the MathML source 2) surface yields gas phase CH2double bond; length as m-dashCH2, CH3CH3, H2 and surface chlorine adatoms. The decomposition reaction is initiated via C-Cl bond cleavage to give a surface ethyl (CH3CH2-) intermediate. A rate-limiting ?-hydride elimination from the surface ethyl species produces gas phase CH2double bond; length as m-dashCH2 and surface hydrogen atoms. Two parallel competing reactions form CH3CH3, via ?-hydride addition to remaining surface ethyl species (reductive elimination), and H2, via the combination of two surface hydrogen atoms. The chlorine freed from the dissociation of CH3CH2Cl binds at the five-coordinate surface Cr3+ sites on the stoichiometric surface and inhibits the surface chemistry via simple site blocking. No surface carbon deposition is observed from the thermal reaction of ethyl chloride, suggesting that ethyl intermediates are not primary coke forming intermediates in the dehydrogenation of ethane over (1 0 View the MathML source 2) facets of ?-Cr2O3.

Brooks, J.; Ma, Q; Cox, D

2009-01-01T23:59:59.000Z

47

E-Print Network 3.0 - academic tertiary care Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

of Rochester, Rochester, New York 14627 (Received 1 April 1996) Tertiary protons with birth... targets, such as those planned for the National Ignition Facility. Measurement of...

48

An investigation into diglossia, literacy, and tertiary-level EFL classes in the Arabian Gulf States.  

E-Print Network (OSTI)

??This study investigates whether the remedial tertiary-level EFL classes in the Arabian Gulf States optimize the process of acquiring English for the majority of the… (more)

Rivard, Jane Nathalie.

2006-01-01T23:59:59.000Z

49

E-Print Network 3.0 - alcohols aromatic tertiary Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

Summary: in their synthesis include the use of a nucleophilic aromatic substitution reaction to construct the chiral tertiary... of 13-membered macrolactams that possess a...

50

E-Print Network 3.0 - aromatic tertiary alcohols Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

Summary: in their synthesis include the use of a nucleophilic aromatic substitution reaction to construct the chiral tertiary... of 13-membered macrolactams that possess a...

51

Table Definitions, Sources, and Explanatory Notes  

Gasoline and Diesel Fuel Update (EIA)

Ethanol Plant Production Ethanol Plant Production Definitions Key Terms Definition Barrel A unit of volume equal to 42 U.S. gallons. Fuel Ethanol An anhydrous alcohol (ethanol with less than 1% water) intended for gasoline blending as described in the Oxygenates definition. Oxygenates Substances which, when added to gasoline, increase the amount of oxygen in that gasoline blend. Ethanol, Methyl Tertiary Butyl Ether (MTBE), Ethyl Tertiary Butyl Ether (ETBE), and methanol are common oxygenates. Fuel Ethanol: Blends of up to 10 percent by volume anhydrous ethanol (200 proof) (commonly referred to as the "gasohol waiver"). Methanol: Blends of methanol and gasoline-grade tertiary butyl alcohol (GTBA) such that the total oxygen content does not exceed 3.5 percent by weight and the ratio of methanol to GTBA is less than or equal to 1. It is also specified that this blended fuel must meet ASTM volatility specifications (commonly referred to as the "ARCO" waiver).

52

Water Research 37 (2003) 37563766 Seasonal and daily variations in concentrations of methyl-  

E-Print Network (OSTI)

by volume to gasoline from November to February, and blending 11% MTBE by volume during the rest of the year; accepted 24 March 2003 Abstract Methyl-tertiary-butyl ether (MTBE), an additive used to oxygenate gasoline of gasoline-powered watercraft. This paper documents and explains both seasonal and daily variations in MTBE

Toran, Laura

53

The identification of recurrent tertiary motifs by interactions of protein secondary structure units  

E-Print Network (OSTI)

. Through an informatics analysis of recurrent tertiary contacts, we have derived a database of recurrent tertiary motifs. A group of 691 high-resolution, non-redundant protein structures was obtained. For each protein in this source data, we found all...

Hodges, Hamilton Courtney

2013-02-22T23:59:59.000Z

54

1,4,7-Trimethyloxatriquinane: SN2 Reaction at Tertiary Carbon Mark Mascal,* Nema Hafezi, and Michael D. Toney  

E-Print Network (OSTI)

1,4,7-Trimethyloxatriquinane: SN2 Reaction at Tertiary Carbon Mark Mascal,* Nema Hafezi for the reaction between 1 and N3 - is SN2, despite the fact that substitution is occurring at a tertiary carbon chemistry textbooks, is that bimolecular nucleophilic substitution (SN2) reactions do not occur at tertiary

Toney, Michael

55

Small angle neutron scattering study of deuterated sodium dodecylsulfate micellization in dilute poly((2edimethylamino)ethyl methacrylate) solutions  

E-Print Network (OSTI)

Small angle neutron scattering study of deuterated sodium dodecylsulfate micellization in dilute 2010 Keywords: Poly((2edimethylamino)ethyl methacrylate) Micelle Small angle neutron scattering a b angle neutron scattering. We found three transitions of the poly ((2edimethylamino)ethyl methacrylate

Kofinas, Peter

56

Origin of gaseous hydrocarbons from Upper Cretaceous and Tertiary strata in the Piceance basin, western Colorado  

E-Print Network (OSTI)

Natural gas samples were collected for geochemical analyses from Upper Cretaceous and Tertiary strata of the Piceance basin in western Colorado to: 1) determine the origin of gases (i.e., microbial versus thermogenic), 2) determine the thermogenic...

Katz, David Jonathan

2012-06-07T23:59:59.000Z

57

Petrogenesis of voluminous mid-Tertiary ignimbrites of the Sierra Madre Occidental, Chihuahua, Mexico  

Science Journals Connector (OSTI)

The mid-Tertiary ignimbrites of the Sierra Madre Occidental of western Mexico constitute the largest continuous rhyolitic province in the world. The rhyolites appear to represent part of a continental magmatic...

Maryellen Cameron; William C. Bagby…

1980-10-01T23:59:59.000Z

58

Radiation dose levels during interventional cardiology procedures in a tertiary care hospital  

Science Journals Connector (OSTI)

......cardiology procedures in a tertiary care hospital O. Dragusin 1 W. Desmet 2 H. Heidbuchel...Department of Radiology, University Hospital Gasthuisberg, Herestraat 49, B-3000...Department of Cardiology, University Hospital Gasthuisberg, Herestraat 49, B-3000......

O. Dragusin; W. Desmet; H. Heidbuchel; R. Padovani; H. Bosmans

2005-12-01T23:59:59.000Z

59

A SUMMARY OF TERTIARY COAL RESOURCES OF THE RATON BASIN, COLORADO AND NEW MEXICO  

E-Print Network (OSTI)

............................................................................................................SR-13 Coal-bed Methane and potential coal-bed methane production in Raton Basin. Adapted from Hemborg (1996). 1999 RChapter SR A SUMMARY OF TERTIARY COAL RESOURCES OF THE RATON BASIN, COLORADO AND NEW MEXICO By R

60

Stochastic Programming Approach to Hydraulic Fracture Design for the Lower Tertiary Gulf of Mexico  

E-Print Network (OSTI)

In this work, we present methodologies for optimization of hydraulic fracturing design under uncertainty specifically with reference to the thick and anisotropic reservoirs in the Lower Tertiary Gulf of Mexico. In this analysis we apply a stochastic...

Podhoretz, Seth

2013-07-27T23:59:59.000Z

Note: This page contains sample records for the topic "mtbe ethyl tertiary" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Detection of Benzene, Toluene, Ethyl Benzene, and Xylenes (BTEX) Using Toluene Dioxygenase-Peroxidase Coupling Reactions  

E-Print Network (OSTI)

bioassay may be suitable for field monitoring of BTEX to identify and track contaminated water and follow in contaminated water because of their accuracy and sensitivity. Although very sensitive, the cost associatedDetection of Benzene, Toluene, Ethyl Benzene, and Xylenes (BTEX) Using Toluene Dioxygenase

Chen, Wilfred

62

Ultrasonic absorption associated with tertiary butanol complex formation in normal-hexane solutions  

E-Print Network (OSTI)

ULTRASONIC ABSORPTION ASSOCIATED WITH TERTIARY BUTANOL COMPLEX FORMATION IN NORMAL-HEXANE SOLUTIONS A Thesis by SALIM MICHEL BUCARAM Submitted to the Graduate School of the Agricultural and Mechanical College of Texas in partial fulfillment... of the requirements for the degree of MASTER OF SCIENCE May 196l Major Subject; Physics ULTRASONIC ABSORPTION ASSOCIATED WITH TERTIARY BUTANOL COMPLEX FORMATION IN NORMAL-HEXANE SOLUTIONS A Thesis by SALIM MICHEL BUCARAM Approved as to style and content by...

Bucaram, Salim Michel

2012-06-07T23:59:59.000Z

63

A review of Tertiary climate changes in southern South America and the Antarctic Peninsula. Part 1: Oceanic conditions .  

E-Print Network (OSTI)

??Oceanic conditions around southern South America and the Antarctic Peninsula have a major influence on climate patterns in these subcontinents. During the Tertiary, changes in… (more)

Le Roux, J. P.

2012-01-01T23:59:59.000Z

64

Storage effects on desorption efficiencies of methyl ethyl ketone and styrene collected on activated charcoal  

E-Print Network (OSTI)

efficier&cy nf methyl etiiy', Ketone and styrene monomer adsorbed on activated charcoal samples, and stored under isotherm&al condit'ions, were investigated as a function of storage time. The dependence of the storage time effects on the storage temp...- erature and compound concentration were also studied. Results showed no siqnif', cant storag&e time effects on adsorbed styrene after sixty days of storage. A very significant decrease in the desorption ef iciency of methyl ethyl ketone was observed...

Dommer, Richard Alvin

2012-06-07T23:59:59.000Z

65

Dynamic Simulation of Startup in Ethyl tert-Butyl Ether Reactive Distillation with Input Multiplicity  

Science Journals Connector (OSTI)

Dynamic Simulation of Startup in Ethyl tert-Butyl Ether Reactive Distillation with Input Multiplicity ... However, smaller internal rates inside the column that result from lower reboiler and condenser duty could increase the potential risk of flooding in the column and reduce the availability of reactants in the reactive section. ... Column simulations performed using both Pro/II and SpeedUp showed excellent agreement with previously published exptl. ...

Budi H. Bisowarno; Moses O. Tadé

2000-05-09T23:59:59.000Z

66

Association Behavior of Biotinylated and Non-Biotinylated PolyEthylene Oxide-b-Poly(2-(Diethylamino)Ethyl Methacrylate)  

E-Print Network (OSTI)

Biotinylated and non-biotinylated copolymers of ethylene oxide (EO) and 2-(diethylamino)ethyl methacrylate (DEAEMA) were synthesized by the atom transfer radical polymerization technique (ATRP). The chemical compositions ...

Tan, J. F.

67

Short report Doctors leaving 12 tertiary hospitals in Iraq, 20042007q  

E-Print Network (OSTI)

Short report Doctors leaving 12 tertiary hospitals in Iraq, 2004­2007q Gilbert M. Burnham a 21205, USA b Al Mustansiriya, Baghdad, Iraq a r t i c l e i n f o Article history: Available online 6 June 2009 Keywords: Iraq Doctors Violence Doctor migration Hospitals Medical workforce a b s t r a c

Scharfstein, Daniel

68

New surfactant classes for enhanced oil recovery and their tertiary oil recovery potential  

E-Print Network (OSTI)

commercial scale projects were also executed. Nowadays, because of the high oil price, this technology hasNew surfactant classes for enhanced oil recovery and their tertiary oil recovery potential Stefan States a b s t r a c ta r t i c l e i n f o Article history: Received 23 February 2009 Accepted 14

Goddard III, William A.

69

Interplay between Secondary and Tertiary Structure Formation in Protein Folding Cooperativity  

E-Print Network (OSTI)

Interplay between Secondary and Tertiary Structure Formation in Protein Folding Cooperativity¨lich, 52425 Ju¨lich, Germany Received June 14, 2010; E-mail: deserno@andrew.cmu.edu Abstract: Protein folding be difficult to measure. Therefore, protein folding cooperativity is often probed using the calorimetric

Bachmann, Michael

70

Occurrence and Implication of dissolved organic phosphorus (DOP) in tertiary wastewater Effluents Page 1 of 6  

E-Print Network (OSTI)

GU, APRIL Occurrence and Implication of dissolved organic phosphorus (DOP) in tertiary wastewater wastewater effluents L. Liu1 , D. S. Smith2 , M. Bracken3 , J.B. Neethling4 , H.D. Stensel5 and S. Murthy6 levels (e.g. TPwastewater treatment plants. A few previous studies (Benisch et al., 2007

Brody, James P.

71

An Efficient Genetic Algorithm for Predicting Protein Tertiary Structures in the 2D HP Model  

E-Print Network (OSTI)

, predicting its tertiary structure is known as the protein folding problem. This problem has been widely genetic algo- rithm for the protein folding problem under the HP model in the two-dimensional square Genetic Algorithm, Protein Folding Problem, 2D HP Model 1. INTRODUCTION Amino acids are the building

Istrail, Sorin

72

Biosynthesis and urinary excretion of methyl sulfonium derivatives of the sulfur mustard analog, 2-chloroethyl ethyl sulfide, and other thioethers  

SciTech Connect

Thioether methyltransferase was previously shown to catalyze the S-adenosylmethionine-dependent methylation of diemthyl selenide, dimethyl telluride, and various thioethers to produce the corresponding methyl onium ions. In this paper we show that the following thioethers are also substrates for this enzyme in vitro: 2-hydroxyethyl ethyl sulfide, 2-chloroethyl ethyl sulfide, thiodiglycol, t-butyl sulfide, and isopropyl sulfide. To demonstrate thioether methylation in vivo, mice were injected with (methyl-{sup 3}H)methionine plus different thioethers, and extracts of lungs, livers, kidneys, and urine were analyzed by high-performance liquid chromatography for the presence of ({sup 3}H)methyl sulfonium ions. The following thioethers were tested, and all were found to be methylated in vivo: dimethyl sulfide, diethyl sulfide, methyl n-propyl sulfide, tetrahydrothiophene, 2-(methylthio)ethylamine, 2-hydroxyethyl ethyl sulfide, and 2-chloroethyl ethyl sulfide. This supports our hypothesis that the physiological role of thioether methyltransferase is to methylate seleno-, telluro-, and thioethers to more water-soluble onium ions suitable for urinary excretion. Conversion of the mustard gas analog, 2-chloroethyl ethyl sulfide, to the methyl sulfonium derivative represents a newly discovered mechanism for biochemical detoxification of sulfur mustards, as this conversion blocks formation of the reactive episulfonium ion that is the ultimate alkylating agent for this class of compounds.

Mozier, N.M.; Hoffman, J.L. (Univ. of Louisville, KY (USA))

1990-12-01T23:59:59.000Z

73

Catalytic oxidation of ethyl acetate over La-Co and La-Cu oxides  

Science Journals Connector (OSTI)

Abstract Lanthanum-containing mixed oxides (La-Co and La-Cu) were synthesized by several methods: exotemplating, evaporation, glycine-nitrate and glycine-nitrate-exotemplating. Samples were characterized by thermogravimetry and differential scanning calorimetry, N2 adsorption, temperature programmed reduction, scanning electron microscopy and X-ray diffraction. The materials obtained were tested as catalysts for ethyl acetate oxidation, as a model volatile organic compound. La-Cu samples showed poor catalytic performance, but La-Co materials were much more active than the individual components. Catalytic activity seems to be mainly determined by the easiness of reduction of the catalysts, which is related to the availability of oxygen from the lattice. Catalysts containing Co or Cu in excess of La (on a molar base) were more active than the corresponding mixed oxides consisting of equal amounts of La and the transition metal. Samples prepared by the evaporation method were more active than those prepared by exotemplating, for the same molar ratio. Samples prepared by evaporation and glycine-nitrate methods calcined at 600 °C had a better performance than the corresponding oxides calcined at 300 °C. The most active sample found in this study was the La-Co mixed oxide prepared by the glycine nitrate method and calcined at 600 °C, 100% conversion of ethyl acetate to H2O and CO2 being achieved at 230 °C.

X. Chen; S.A.C. Carabineiro; P.B. Tavares; J.J.M. Órfão; M.F.R. Pereira; J.L. Figueiredo

2014-01-01T23:59:59.000Z

74

Play analysis and stratigraphic position of Uinta Basin tertiary - age oil and gas fields  

SciTech Connect

Tertiary-age sediments in the Uinta basin produce hydrocarbons from five types of plays. These play types were determined by hydrocarbon type, formation, depositional environment, rock type, porosity, permeability, source, and per-well recovery. Each well was reviewed to determine the stratigraphic position and producing characteristics of each producing interval. The five types of plays are as follows: (1) naturally fractured oil reservoirs, (2) low-permeability oil reservoirs, (3) high-permeability of oil reservoirs, (4) low-permeability gas reservoirs, and (5) tight gas sands. Several fields produce from multiple plays, which made it necessary to segregate the hydrocarbon production into several plays. The stratigraphic position of the main producing intervals is shown on a basin-wide cross section, which is color-coded by play type. This 61-well cross section has several wells from each significant Tertiary oil and gas field in the Uinta basin.

Williams, R.A. (Pennzoil Exploration and Production Co., Houston, TX (United States))

1993-08-01T23:59:59.000Z

75

Concentrating aqueous volatile fatty acid salt solutions using a tertiary amine mixture  

E-Print Network (OSTI)

, and that reaction is difficult to reverse (Streitwieser and Heathcock, 1976; King and Poole, 1994). Tertiary amines (R, N) do not form amides but generally give lower K, values than secondary amines. For the extraction of undissociated carboxylic acids, aliphatic... by acidifying with carbon dioxide under pressure in the presence of a suitable solvent (Busche, 1988). Gregor has used electrodialysis to recover acetic acid from dilute (1-5 wt%) acetate solutions. With newer membranes, acid concentrations up to 30% were...

Gaskin, David J

1997-01-01T23:59:59.000Z

76

Atmospheric chemistry of diethyl ether and ethyl tert-butyl ether  

SciTech Connect

The mechanisms for the Cl-initiated and OH-initiated atmospheric oxidation of diethyl ether and ethyl tert-butyl ether (ETBE) have been determined. For diethyl ether the products are ethyl formate and formaldehyde and its atmospheric oxidation can be represented by C{sub 2}H{sub 5}OC{sub 2}H{sub 5} + OH + 2NO {yields} C{sub 2}H{sub 5}OC(O)H + HCHO + 2NO{sub 2} + HO{sub 2}. The mechanism for the atmospheric oxidation of ETBE is more complex, with 80% of the reaction being accounted for in terms of tert-butyl formate and formaldehyde. The remaining 20% the authors ascribe to 2-ethoxy-2-methylpropanal. The atmospheric oxidation of ETBE can be represented by ETBE + OH + 1.8NO {yields} 0.8HCOOC(CH{sub 3}){sub 3} + 0.2C{sub 2}H{sub 5}OC(CH{sub 3}){sub 2}CHO + HO{sub 2} + 0.8HCHO + 1.8NO{sub 2}. THe subsequent atmospheric chemistry of 2-ethoxy-2-methylpropanal the authors estimate to be represented by C{sub 2}H{sub 5}OC(CH{sub 3}){sub 2}CHO + OH + 3NO {yields} CO{sub 2} + H{sub 2}CO + C{sub 2}H{sub 5}OC(O)CH{sub 3} + HO{sub 2} + 3NO{sub 2}. These results are discussed in terms of the reactivity of these compounds in urban atmospheres.

Wallington, T.J.; Japar, S.M. (Ford Motor Company, Dearborn, MI (USA))

1991-03-01T23:59:59.000Z

77

Has the National Health Insurance improved the inequality in the use of tertiary-care hospitals in Korea?  

Science Journals Connector (OSTI)

AbstractBackground To improve financial protection against catastrophic illness, the Korean government expanded the benefit coverage of the National Health Insurance (NHI) for cancer patients in 2005. This paper examined whether the policy has reduced income-inequality in the use of tertiary care hospitals. Methods We evaluated the effect of the policy on income-inequalities in outpatient visits and inpatient admissions to tertiary care hospitals, based on triple difference estimators. Using nationwide claims data of the NHI from 2002 to 2010, we compared cancer patients as a treatment group with liver disease and cardio-cerebrovascular disease as control groups and the lower-income with the highest-income group. Results Before the introduction of the policy, lower-income cancer patients utilized less inpatient and outpatient services in tertiary care hospitals than high-income patients did. After the benefit coverage was expanded, while the incidence and total number of inpatient admissions to tertiary care hospitals increased among cancer patients compared with liver diseases, lower-income cancer patients experienced a greater increase than those of higher-income did compared with both diseases. The use of outpatient services increased more in cancer patients than those of both diseases; however, the gap between the highest- and the lowest-income rarely decreased, except the incidence of visits when compared to liver disease. Conclusion Our findings indicated that the expanded NHI benefits coverage partially improved income-related inequalities in inpatient admissions to tertiary-care hospital, but not in outpatient visits.

Sujin Kim; Soonman Kwon

2014-01-01T23:59:59.000Z

78

APPENDXD.CHP:Corel VENTURA  

Gasoline and Diesel Fuel Update (EIA)

Report The Form EIA-819, "Monthly Oxygenate Report" provides production data for fuel ethanol and methyl tertiary butyl ether (MTBE). End-of-month stock data held at ethanol...

79

The feasibility of ethanol production in Texas  

E-Print Network (OSTI)

Agricultural interests across Texas are looking at the possibility of an ethanol industry in Texas. Continued conflict in the Middle East, the ban of methyl tertiary butyl ether (MTBE) in California, and low commodity prices have all lead...

Herbst, Brian Keith

2012-06-07T23:59:59.000Z

80

Physical insight into switchgrass dissolution in the ionic liquid 1-ethyl-3-methylimidazolium acetate  

SciTech Connect

Small-angle neutron scattering was used to characterize solutions of switchgrass and the constituent biopolymers cellulose, hemicellulose, and lignin, as well as a physical mixture of them mimicking the composition of switchgrass, dissolved in the ionic liquid (IL) 1-ethyl-3-methylimidazolium acetate. The results demonstrate that the IL dissolves the cellulose fibrils of switchgrass, although a supramolecular biopolymer network remains that is not present in solutions of the individual biopolymers and that does not self-assemble in a solution containing the physical mixture of the individual biopolymers. The persistence of a network-like structure indicates that dissolving switchgrass in the IL does not disrupt all of the physical entanglements and covalent linkages between the biopolymers created during plant growth. Reconstitution of the IL-dissolved switchgrass yields carbohydrate-rich material containing cellulose with a low degree of crystallinity, as determined by powder X-ray diffraction, which impacts potential down-stream uses of the biopolymers produced by the process. The data suggests that the use of chemical additives which would break bonds that exist between the lignin and hemicellulose might improve the purity of the resulting product, but may not be able to disrupt the highly physically-entangled biopolymer network sufficiently to facilitate their separation.

Wang, Hui [University of Alabama, Tuscaloosa] [University of Alabama, Tuscaloosa; Gurau, Gabriela [University of Alabama, Tuscaloosa] [University of Alabama, Tuscaloosa; Pingali, Sai Venkatesh [ORNL] [ORNL; O'Neil, Hugh [ORNL] [ORNL; Evans, Barbara R [ORNL] [ORNL; Urban, Volker S [ORNL] [ORNL; Heller, William T [ORNL] [ORNL; Rogers, Robin D [University of Alabama, Tuscaloosa] [University of Alabama, Tuscaloosa

2014-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "mtbe ethyl tertiary" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Effect of solvents on the radiation-induced polymerization of ethyl and isopropyl vinyl ethers  

SciTech Connect

The effect of solvents on the radiation-induced cationic polymerization of ethyl and isopropyl vinyl ethers (EVE and IPVE, respectively) was investigated. EVE and IPVE polymerizations were carried out in bulk and in solution under superdry conditions in which polar impurities, especially water, have been reduced to negligible levels. This was accomplished by means of a sodium mirror technique using joint free baked out glass equipment and high vacuum. Plots of the monomer conversions and irradiation times were obtained for EVE and IPVE polymerizations in bulk and in benzene solution at constant monomer concentrations. The monomer concentration dependence of the polymerization rate was studied for EVE polymerization in bulk and in benzene, diethlyl ether, diglyme and methylene chloride, and for IPVE polymerization in bulk and in benzene. Solvent effect on the estimated propagating rate constants was examined for EVE and IPVE polymerization in bulk and in solution. The effect of temperature on the polymerization rate was also investigated for EVE polymerization in bulk ad in benzene, diethyl and diisopropyl ethers, methylene chloride and nitromethane, and for IPVE ploymerization in bulk and in benzene.

Hsieh, W.C.

1981-01-01T23:59:59.000Z

82

The Behaviour of Electrolytes in Mixed Solvents. Part I. The Free Energies and Heat Contents of Hydrogen Chloride in Water-Ethyl Alcohol Solutions  

Science Journals Connector (OSTI)

1 November 1929 research-article The Behaviour of Electrolytes in Mixed Solvents. Part I. The Free Energies and Heat Contents of Hydrogen Chloride in Water-Ethyl Alcohol Solutions J. A. V. Butler C. M. Robertson The Royal Society...

1929-01-01T23:59:59.000Z

83

Beneficial Effect of Nanoclay in Atom Transfer Radical Polymerization of Ethyl Acrylate:? A One Pot Preparation of Tailor-Made Polymer Nanocomposite  

Science Journals Connector (OSTI)

Beneficial Effect of Nanoclay in Atom Transfer Radical Polymerization of Ethyl Acrylate:? A One Pot Preparation of Tailor-Made Polymer Nanocomposite ... Nanoclays [Cloisite 30B, Cloisite NA+, and Cloisite 20A] were supplied by Southern Clay products, Gonzales, TX. ...

Haimanti Datta; Nikhil K. Singha; Anil K. Bhowmick

2007-12-12T23:59:59.000Z

84

Plant observation report and evaluation, Pennwalt Corporation, secondary and tertiary aliphatic monoamines  

SciTech Connect

A site visit was made to the amine manufacturing facility of the Pennwalt Corporation, Wyandotte, Michigan, to evaluate the facility in regard to the Secondary and Tertiary Aliphatic Monoamines Criteria Document. A total of 21 people were directly in contact with the amine production process. Two to four of the maintenance personnel may also come in contact with the process. Maintenance workers ran the risk of exposure not only to primary, secondary and tertiary amine compounds, but also to several other chemicals being used in the process. The processes used to unload raw materials are described, along with reactor operations, decanter and recycling operations, distillation operations, product storage and shipping. Medical monitoring at the facility included chest x-ray, respiratory function tests, sight screening, urinalysis, and back x-rays. Restricted and potentially hazardous area signs were clearly posted. Employees wore hard hats and safety glasses on the job as well as gloves, rubber boots, face shields, goggles, and respirators as necessary. Emergency procedures are described, including fire protection. Sanitation and personal hygiene are discussed, along with monitoring of the workplace conditions.

Not Available

1980-08-27T23:59:59.000Z

85

Reaction of trans-dichloro-bis[N(1)-methyl-2-(arylazo)imidazole] ruthenium(II) with tertiary phosphines  

Science Journals Connector (OSTI)

Trans-dichloro-bis[N(1)-methyl-2-(arylazo)imidazol e] ruthenium(II) (tcc-Ru(MeL)2Cl2) reacts with tertiary phosphines giving rise to species of type [RuCl(P)-(MeL)2]+ and [Ru(P-P)(MeL)2]2+ in which Cl, P and P...

Tarun Kumar Misra; Chittaranjan Sinha

1999-04-01T23:59:59.000Z

86

Isotopic Data Bearing on the Origin of Mesozoic and Tertiary Granitic Rocks in the Western United States  

Science Journals Connector (OSTI)

...Granitic Rocks in the Western United States D. J...Utah, Arizona, and Colorado. The plutons, which...Utah, Arizona and Colorado. The plutons, which...California Cenozoic Colorado crust differentiation...Tertiary United States Utah Western U.S. 1983 03 23 The...

1984-01-01T23:59:59.000Z

87

Magnetostratigraphy of Tertiary sediments from the Hoh Xil Basin: implications for the Cenozoic tectonic history of the Tibetan Plateau  

Science Journals Connector (OSTI)

......consists mainly of the lake carbonate with some black oil shale (Liu Wang 1999). It disconformably overlies the Fenghuoshan...A, 326, 177-188. Liu Z. , Wang C., 1999. Oil shale in the Tertiary Hoh Xil basin, northern Qinghai-Tibet......

Zhifei Liu; Xixi Zhao; Chengshan Wang; Shun Liu; Haisheng Yi

2003-08-01T23:59:59.000Z

88

Alteration of the tertiary structure of the major bee venom allergen Api m 1 by multiple mutations is  

E-Print Network (OSTI)

Alteration of the tertiary structure of the major bee venom allergen Api m 1 by multiple mutations a recombinant form of the major bee venom allergen (Api m 1) with the final goal of reducing its IgE reactivity. This molecule (Api mut) contains 24 mutations and one deletion of 10 amino acids. The successive introduction

Gelb, Michael

89

Eliminating MTBE in Gasoline in 2006  

Annual Energy Outlook 2012 (EIA)

for and moving more ethanol to the East Coast and Texas, converting terminal tanks from petroleum to ethanol, adding blending equipment at many terminals, and finding...

90

Tectonostratigraphic reconstruction and lithofacies distribution of tertiary slope sedimentary rocks in the Western Mississippi Canyon area  

SciTech Connect

The distribution of upper Tertiary, sandstone-prone, deep-water sedimentary rocks from the vicinity of Cognac field, Mississippi Canyon (MC) 194, south of Mars field (MC763) is presented based on an integrated sequence stratigraphic analysis of seismic, well log, and biostratigraphic data. Paleo-salt distributions were reconstructed by plotting the changing positions of depocenters on five isopach maps generated from six key sequence boundaries. Depositional trends, projected under allochthonous salt sheets, indicated subsalt prospectivity. Sixteen sequences were interpreted and subdivided into three lowstand depositional units (basin-floor fan, slope fan, and prograding wedge). Thirty isochron/seismic facies maps were made to reveal the stratigraphic pattern through the late Tertiary. During the early Miocene, a salt-rimmed syncline centered north of Mars field in MC455 accumulated sediments. The salt rim collapsed, creating a middle Miocene turtle structure. Middle-late Miocene sand-rich turbidites bypassed this structure and were deposited to the south around Mars field and beyond. At the same time, another depotrough 30 mi east of Mars field channeled deep-water sands to the MC730 area. A late Miocene-early Pliocene counterregional fault striking parallel to the shelf edge formed as salt evacuated the area on the south side of the Cognac (MC194) and Lena (MC280) fields. This fault trapped the Pliocene reservoir sandstones that produce in these fields. Sedimentation during the late Pliocene-early Pleistocene was very slow (0.2m/1,000 yr) and characterized by thin, stacked, condensed sections of hemipelagic shale. Since the mid-Pleistocene, the Mississippi River has supplied sediments to the Mississippi Canyon area that have induced salt deformation that has in turn affected recent sedimentation.

Hannan, A.E.; Risch, D.L.; Chowdhury, A.N. [Geco-Prakla, Inc., Houston, TX (United States)

1994-12-31T23:59:59.000Z

91

Natural gas accumulations in low-permeability Tertiary, and Cretaceous (Campanian and Maastrichtian) rock, Uinta Basin, Utah  

SciTech Connect

This report characterizes Upper Cretaceous Campanian and Maastrichtian, and lower Tertiary gas-bearing rocks in the Uinta Basin with special emphasis on those units that contain gas in reservoirs that have been described as being tight. The report was prepared for the USDOE whose Western Tight Gas Sandstone Program cofunded much of this research in conjunction with the US Geological Survey's Evolution of Sedimentary Basins, and Onshore Oil and Gas Programs. (VC)

Fouch, T.D.; Wandrey, C.J.; Pitman, J.K.; Nuccio, V.F.; Schmoker, J.W.; Rice, D.D.; Johnson, R.C.; Dolton, G.L.

1992-02-01T23:59:59.000Z

92

Natural gas accumulations in low-permeability Tertiary, and Cretaceous (Campanian and Maastrichtian) rock, Uinta Basin, Utah. Final report  

SciTech Connect

This report characterizes Upper Cretaceous Campanian and Maastrichtian, and lower Tertiary gas-bearing rocks in the Uinta Basin with special emphasis on those units that contain gas in reservoirs that have been described as being tight. The report was prepared for the USDOE whose Western Tight Gas Sandstone Program cofunded much of this research in conjunction with the US Geological Survey`s Evolution of Sedimentary Basins, and Onshore Oil and Gas Programs. (VC)

Fouch, T.D.; Wandrey, C.J.; Pitman, J.K.; Nuccio, V.F.; Schmoker, J.W.; Rice, D.D.; Johnson, R.C.; Dolton, G.L.

1992-02-01T23:59:59.000Z

93

Anhydrous aluminum chloride as an alkylation catalyst: identification of mono- and dialkyl-benzenes from the condensation of tertiary butyl alcohol with benzene.  

E-Print Network (OSTI)

LIBRARY a a w c"I. I. SI - O~ TI:YAf ANHYDROUS ALUMINUM CHLORIDE AS AN ALKYLATION CATALYST: IDENTIFICATION OF MONO- AND DIALKYIZENZENES FROM THE CONDENSATION QF TERTIARY BUTYL ALCOHOL WITH BENKENE IACEY EUGENE SCOGGINS 4 A Thesis Submitted...: IDENTIFICATION OF MONO- AND DI~NZZNES FROM THE CONDENSATION OF TERTIARY BUTYL ALCOHOL WITH BENZENE A Thesis By LACEY EUGENE SCOGGINS Approved as to style and content hy: Chairman of Committee Head of Chemistry Department 1959 ACKNOWLEDGME1VTS The author...

Scoggins, Lacey E

1959-01-01T23:59:59.000Z

94

Average Conformations Determined from PRE Data Provide High-Resolution Maps of Transient Tertiary Interactions in Disordered Proteins  

Science Journals Connector (OSTI)

In the last decade it has become evident that disordered states of proteins play important physiological and pathological roles and that the transient tertiary interactions often present in these systems can play a role in their biological activity. The structural characterization of such states has so far largely relied on ensemble representations, which in principle account for both their local and global structural features. However, these approaches are inherently of low resolution due to the large number of degrees of freedom of conformational ensembles and to the sparse nature of the experimental data used to determine them. Here, we overcome these limitations by showing that tertiary interactions in disordered states can be mapped at high resolution by fitting paramagnetic relaxation enhancement data to a small number of conformations, which can be as low as one. This result opens up the possibility of determining the topology of cooperatively collapsed and hidden folded states when these are present in the vast conformational landscape accessible to disordered states of proteins. As a first application, we study the long-range tertiary interactions of acid-unfolded apomyoglobin from experimentally measured paramagnetic relaxation enhancement data.

Jordi Silvestre-Ryan; Carlos W. Bertoncini; Robert Bryn Fenwick; Santiago Esteban-Martin; Xavier Salvatella

2013-01-01T23:59:59.000Z

95

Seismic reflection evidence for two phase development of Tertiary basins from east-central Nevada  

SciTech Connect

Two east-west seismic reflection profiles crossing Antelope Valley, Smokey Valley, Railroad Valley and Big Sand Springs Valley demonstrate the evolution of Tertiary extension from broad sags to narrow, fault-bounded basins. Seismic reflection data was acquired for the Anschutz Corporation by the Digicon Corporation during the winter of 1988/1989. Reprocessing of a 480 channel, 60 fold, dynamite source experiment enabled good imaging of the basin stratigraphy. These data suggest two distinct phases of basin development occurred, separated by a regional unconformity. The early phase is characterized by development of a broad basin riddled with many small offset normal faults. The later phase shows a narrowing of the basin and subsidence along one dominant structure, an apparent planar normal fault. The unconformity separating the two phases of extension marks a transition from broad subsidence to local asymmetric tilting that took place over a short period of time relative to sedimentation rates. Antelope Valley and Railroad Valley clearly show strong evidence for two phase development, whereas Smokey Valley represents mostly the early phase and Big Sand Springs Valley represents only the later phase of extension. The absence of dating within the basins precludes the authors from determining if the abrupt tectonic transition within the basins resulted from differences in local strain rates or amounts, or was due to changes in regional stress fields.

Liberty, L.M.; Heller, P.L.; Smithson, S.B. (Univ. of Wyoming, Laramie, WY (United States). Dept. of Geology and Geophysics)

1993-04-01T23:59:59.000Z

96

Maturation of Tertiary sediments in the Asian Continental Margins: A basis for hydrocarbon generation studies  

SciTech Connect

In the marginal areas of the Asian continent, the Paleogene and Miocene coal-bearing formations are sporadically distributed. In some areas, particularly in the sea regions, their equivalents are possibly explored for oil and gas. The basins mainly formed as tectonic depressions, and are filled with fluvial to marine clastic rocks. The formations show marked lateral variation in thickness, lithology, and sediment characteristics, which are related to the geotectonic settings of the basins at active plate margins. Remarkable accumulation of overburden and high paleogeothermal conditions, which are marked in northern Kyushu, Japan, and Thailand, influenced diagenesis. Organic and inorganic maturation studies in northern Kyushu reveal a progress of diagenesis from the inland of Kyushu toward the sea region essentially controlled by additional heat supply from the sea region during and after sedimentation. The sediments on the land surface are chiefly overmatured, and/or contain minor amounts of organic carbon. High paleogeothermal influence on Tertiary maturation is clear also in northern Thailand. The high paleotemperature conditions in these areas may be related to tectonic interaction between the oceanic and continental plates.

Miki, Takashi (Kyushu Univ., Fukuoka (Japan))

1994-07-01T23:59:59.000Z

97

Factors controlling reservoir quality in tertiary sandstones and their significance to geopressured geothermal production  

SciTech Connect

Variable intensity of diagenesis is the factor primarily responsible for contrasting regional reservoir quality of Tertiary sandstones from the upper and lower Texas coast. Detailed comparison of Frio sandstone from the Chocolate Bayou/Danbury Dome area, Brazoria County, and Vicksburg sandstones from the McAllen Ranch Field area, Hidalgo County, reveals that extent of diagenetic modification is most strongly influenced by (1) detrital mineralogy and (2) regional geothermal gradients. The regional reservoir quality of Frio sandstones from Brazoria County is far better than that characterizing Vicksburg sandstones from Hidalgo County, especially at depths suitable for geopressured geothermal energy production. However, in predicting reservoir quality on a site-specific basis, locally variable factors such as relative proportions for porosity types, pore geometry as related to permeability, and local depositional environment must also be considered. Even in an area of regionally favorable reservoir quality, such local factors can significantly affect reservoir quality and, hence, the geothermal production potential of a specific sandstone unit.

Loucks, R.G.; Richmann, D.L.; Milliken, K.L.

1981-01-01T23:59:59.000Z

98

Interplay between Secondary and Tertiary Structure Formation in Protein Folding Cooperativity  

E-Print Network (OSTI)

Protein folding cooperativity is defined by the nature of the finite-size thermodynamic transition exhibited upon folding: two-state transitions show a free energy barrier between the folded and unfolded ensembles, while downhill folding is barrierless. A microcanonical analysis, where the energy is the natural variable, has shown better suited to unambiguously characterize the nature of the transition compared to its canonical counterpart. Replica exchange molecular dynamics simulations of a high resolution coarse-grained model allow for the accurate evaluation of the density of states, in order to extract precise thermodynamic information, and measure its impact on structural features. The method is applied to three helical peptides: a short helix shows sharp features of a two-state folder, while a longer helix and a three-helix bundle exhibit downhill and two-state transitions, respectively. Extending the results of lattice simulations and theoretical models, we find that it is the interplay between secondary structure and the loss of non-native tertiary contacts which determines the nature of the transition.

Tristan Bereau; Michael Bachmann; Markus Deserno

2011-07-01T23:59:59.000Z

99

THE TRENDS HIGH-CONTRAST IMAGING SURVEY. II. DIRECT DETECTION OF THE HD 8375 TERTIARY  

SciTech Connect

We present the direct imaging detection of a faint tertiary companion to the single-lined spectroscopic binary HD 8375 AB. Initially noticed as an 53 m s{sup -1} yr{sup -1} Doppler acceleration by Bowler et al., we have obtained high-contrast adaptive optics observations at Keck using NIRC2 that spatially resolve HD 8375 C from its host(s). Astrometric measurements demonstrate that the companion shares a common proper-motion. We detect orbital motion in a clockwise direction. Multiband relative photometry measurements are consistent with an early M-dwarf spectral type ({approx}M1V). Our combined Doppler and imaging observations place a lower-limit of m {>=} 0.297 M{sub Sun} on its dynamical mass. We also provide a refined orbit for the inner pair using recent radial velocity measurements obtained with the High Resolution Echelle Spectrometer. HD 8375 is one of many triple-star systems that are apparently missing in the solar neighborhood.

Crepp, Justin R. [Department of Physics, University of Notre Dame, 225 Nieuwland Science Hall, Notre Dame, IN 46556 (United States); Johnson, John Asher; Yantek, Scott M. [Department of Astronomy, California Institute of Technology, 1200 E. California Blvd., Pasadena, CA 91125 (United States); Howard, Andrew W. [Institute for Astronomy, University of Hawaii, 2680 Woodlawn Drive, Honolulu, HI 96822 (United States); Marcy, Geoff W.; Isaacson, Howard [Department of Astronomy, University of California, Berkeley, CA 94720 (United States); Fischer, Debra A. [Department of Physics, Yale University, New Haven, CT 06511 (United States); Wright, Jason T.; Feng Ying, E-mail: jcrepp@nd.edu [Department of Astronomy and Astrophysics, The Pennsylvania State University, University Park, PA 16802 (United States)

2013-07-01T23:59:59.000Z

100

Complete oxidation of CO, ethanol, and ethyl acetate over copper oxide supported on titania and ceria modified titania  

SciTech Connect

Titania and titania modified with 3 and 12 {mu}mol Ce/m{sup 2} surface area of the titania were prepared and were used as supports for copper oxide. Preparations with 3 and 12 {mu}mol CuO{sub x}/m{sup 2} surface area of the support were tested for the combustion of CO, ethyl acetate, and ethanol. The results show that the Ce-doped titania surface is good as support for CuO{sub x} and that the cerium not only enhances the activity of the copper species, but also stabilizes the surface area of the TiO{sub 2} support in the presence of copper oxide. Additions of Al, K, and La are also found to stabilize the TiO{sub 2} support but, compared with Ce, these elements do not to the same extent enhance the activity of the copper species. Acetaldehyde is observed to ban an intermediate in the combustion of both ethanol and ethyl acetate over Cu-Ce-Ti-O catalysts. Since acetaldehyde is more harmful than any of the reactants and also is photochemically active, it is in applications important to assure that the combustion is complete. Cu-Ce-Ti-O catalysts show good performance not only for feeds without water vapor, but also for humid feeds. Although the concentrations of intermediates are affected by the addition of water, there is little effect on the temperature required for obtaining complete conversion to carbon dioxide and water. Characterization with XRD, FT-Raman, TPR, and XPS indicates that the dispersed copper species are in the form of patches or a bidimensional layer which interacts with the surface of the support. When the content of cerium and copper is low, other types of dispersed copper species are present, which possibly are monomers or dimers. The copper species are predominantly Cu{sup 2+} species.

Larsson, P.O. [Perstorp AB (Sweden)] [Perstorp AB (Sweden); Andersson, A. [Univ. of Lund (Sweden). Dept. of Chemical Engineering II] [Univ. of Lund (Sweden). Dept. of Chemical Engineering II

1998-10-01T23:59:59.000Z

Note: This page contains sample records for the topic "mtbe ethyl tertiary" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
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101

Effect of varying polyacrylamide molecular weight on tertiary oil recovery from porous media of varying permeability  

SciTech Connect

Three different molecular weight emulsion polyacrylamides (PAA) have been tested for their ability to recover oil from a multi-permeability Berea core system. Injection of a 6.5 x 10/sup 6/, 17 x 10/sup 6/, and 36 x 10/sup 6/ molecular weight PAA resulted in oil recovery from the multiple permeability core systems of 53.4, 63.7, and 57.2 percent of the waterflood residual oil, respectively. In tests with 15 g/kg Na/sub 2/CO/sub 3/, injection of the polymer systems resulted in recoveries of 65.6, 75.3, and 68.0 percent of the waterflood residual oil, respectively. In the presence of alkali, the injection of high molecular weight PAA resulted in the reduction of fluid flow into the medium and low permeability cores with 70 to 75 percent of the tertiary oil being recovered from the high permeability core. Decreasing the PAA molecular weight to 17 x 10/sup 6/ and subsequently to 6.5 x 10/sup 6/ resulted in an increasing amount of fluid flowing through the low and medium permeability cores. While decreasing the molecular weight of the PAA resulted in increased fluid diversion, the 6.5 x 10/sup 6/ molecular weight PAA recovery efficiency was less than either of the other two polymers in the high permeability core. The data indicates selection of too large a polymer can result in less than maximum oil recovery from a heterogeneous permeability reservoir as a result of lower sweep efficiency. Selection of too small a polymer can result in less than maximum oil recovery from a heterogeneous permeability reservoir as a result of decreased oil recovery from the high permeability zones. Proper selection of polyacrylamide for a heterogeneous permeability reservoir either in the presence or in the absence of alkali will maximize oil recovery.

Ball, J.T.; Pitts, M.J.

1984-04-01T23:59:59.000Z

102

Use of Treated Municipal Wastewater as Power Plant Cooling System Makeup Water: Tertiary Treatment versus Expanded Chemical Regimen for Recirculating Water Quality Management  

SciTech Connect

Treated municipal wastewater is a common, widely available alternative source of cooling water for thermoelectric power plants across the U.S. However, the biodegradable organic matter, ammonia-nitrogen, carbonate and phosphates in the treated wastewater pose challenges with respect to enhanced biofouling, corrosion, and scaling, respectively. The overall objective of this study was to evaluate the benefits and life cycle costs of implementing tertiary treatment of secondary treated municipal wastewater prior to use in recirculating cooling systems. The study comprised bench- and pilot-scale experimental studies with three different tertiary treated municipal wastewaters, and life cycle costing and environmental analyses of various tertiary treatment schemes. Sustainability factors and metrics for reuse of treated wastewater in power plant cooling systems were also evaluated. The three tertiary treated wastewaters studied were: secondary treated municipal wastewater subjected to acid addition for pH control (MWW_pH); secondary treated municipal wastewater subjected to nitrification and sand filtration (MWW_NF); and secondary treated municipal wastewater subjected nitrification, sand filtration, and GAC adsorption (MWW_NFG). Tertiary treatment was determined to be essential to achieve appropriate corrosion, scaling, and biofouling control for use of secondary treated municipal wastewater in power plant cooling systems. The ability to control scaling, in particular, was found to be significantly enhanced with tertiary treated wastewater compared to secondary treated wastewater. MWW_pH treated water (adjustment to pH 7.8) was effective in reducing scale formation, but increased corrosion and the amount of biocide required to achieve appropriate biofouling control. Corrosion could be adequately controlled with tolytriazole addition (4-5 ppm TTA), however, which was the case for all of the tertiary treated waters. For MWW_NF treated water, the removal of ammonia by nitrification helped to reduce the corrosivity and biocide demand. Also, the lower pH and alkalinity resulting from nitrification reduced the scaling to an acceptable level, without the addition of anti-scalant chemicals. Additional GAC adsorption treatment, MWW_NFG, yielded no net benefit. Removal of organic matter resulted in pitting corrosion in copper and cupronickel alloys. Negligible improvement was observed in scaling control and biofouling control. For all of the tertiary treatments, biofouling control was achievable, and most effectively with pre-formed monochloramine (2-3 ppm) in comparison with NaOCl and ClO2. Life cycle cost (LCC) analyses were performed for the tertiary treatment systems studied experimentally and for several other treatment options. A public domain conceptual costing tool (LC3 model) was developed for this purpose. MWW_SF (lime softening and sand filtration) and MWW_NF were the most cost-effective treatment options among the tertiary treatment alternatives considered because of the higher effluent quality with moderate infrastructure costs and the relatively low doses of conditioning chemicals required. Life cycle inventory (LCI) analysis along with integration of external costs of emissions with direct costs was performed to evaluate relative emissions to the environment and external costs associated with construction and operation of tertiary treatment alternatives. Integrated LCI and LCC analysis indicated that three-tiered treatment alternatives such as MWW_NSF and MWW_NFG, with regular chemical addition for treatment and conditioning and/or regeneration, tend to increase the impact costs and in turn the overall costs of tertiary treatment. River water supply and MWW_F alternatives with a single step of tertiary treatment were associated with lower impact costs, but the contribution of impact costs to overall annual costs was higher than all other treatment alternatives. MWW_NF and MWW_SF alternatives exhibited moderate external impact costs with moderate infrastructure and chemical conditioner dosing, which makes them (especially

David Dzombak; Radisav Vidic; Amy Landis

2012-06-30T23:59:59.000Z

103

Effect of use of low oxygenate gasoline blends upon emissions from California vehicles. Final report  

SciTech Connect

The objective of this project was to investigate the emissions effects of low-oxygenate gasoline blends on exhaust and evaporative emissions from a test fleet of California certified light-duty autos. Thirteen vehicles were procured and tested using four gasoline-oxygenate blends over three test cycles. The four gasoline blends were: Methyl Tertiary Butyl Ether (MTBE), Ethyl Tertiary Butyl Ether (ETBE), and 'match' and 'splash' blends of ethanol (in the 'match' blend the fuel Reid Vapor Pressure (RVP) is held constant, while in the 'splash' blend the fuel RVP is allowed to increase). Hydrocarbon and carbon monoxide exhaust emissions were generally reduced for the oxygenated blends, the exception being the 'splash-blended' ethanol gasoline which showed mixed results. Older technology vehicles (e.g., non-catalyst and oxidation catalyst) showed the greatest emissions reductions regardless of gasoline blend, while later technology vehicles showed the smallest reductions. Evaporative emissions and toxics were generally reduced for ETBE, while results for the other blends were mixed.

Born, G.L.; Lucas, S.V.; Scott, R.D.; DeFries, T.H.; Kishan, S.

1994-02-01T23:59:59.000Z

104

Investigating Sequestration Potential of Carbonate Rocks during Tertiary Recovery from a Billion Barrel Oil Field, Weyburn, Saskatchewan: the Geoscience Framework (IEA Weyburn CO2 Monitoring Project)  

NLE Websites -- All DOE Office Websites (Extended Search)

Sequestration Potential of Carbonate Rocks during Tertiary Sequestration Potential of Carbonate Rocks during Tertiary Recovery from a Billion Barrel Oil Field, Weyburn, Saskatchewan: the Geoscience Framework (IEA Weyburn CO 2 Monitoring and Storage Project) G. Burrowes (Geoffrey_Burrowes@pancanadian.ca; 403-290-2796) PanCanadian Resources 150 - 9 th Avenue S.W., P.O. Box 2850 Calgary, Alberta, Canada T2P 2S5 C. Gilboy (cgilboy@sem.gov.sk.ca; 306-787-2573) Petroleum Geology Branch, Saskatchewan Energy and Mines 201 Dewdney Avenue East Regina, Saskatchewan, Canada S4N 4G3 Introduction In Western Canada the application of CO 2 injection for enhanced, 'tertiary' oil recovery is a relatively recent addition to the arsenal available to reservoir engineers. The first successful application of CO 2 as a miscible fluid in Western Canada began in 1984 at Joffre Field, a

105

Evaluation of the 3M Organic Vapor Monitor #3500 as a sampling device for ethyl acrylate and the effect of discontinued exposure on vapor retention  

E-Print Network (OSTI)

Sampling Theories of Adsorption Forces of Adsorption Activation Procedures Surface Structure Statement of Hypotheses METHODOLOGV Test Atmosphere Generation Exposure Chamber MIRAN Calibration and Use Monitor Exposure to EA Analytical Procedures...EVALUATION OF THE 3M ORGANIC VAPOR MONITOR 53500 AS A SAMPLING DEVICE FOR ETHYL ACRYLATE AND THE EFFECT OF DISCONTINUED EXPOSURE ON VAPOP, RETENTION A Thesis by ROBERT WAYNE BARR Submitted to the Graduate College of Texas Al!M University...

Barr, Robert Wayne

2012-06-07T23:59:59.000Z

106

Intramolecular cationic [5 + 2] cycloaddition reactions promoted by trimethylsilyl triflate in 3.0 M lithium perchlorate-ethyl acetate: Application to a formal total synthesis of (±)-isocomene  

Science Journals Connector (OSTI)

Trimethylsilyl triflate is an effective reagent in 3.0 M lithium perchlorate-ethyl acetate for promoting intramolecular cationic [5 + 2] cycloaddition reactions. A formal total synthesis of the angular triquinane isocomene (10) is detailed. Cationic [5 + 2] cycloaddition of quinone monoketal 40 gives rise to tricyclic diketone 35 which is subsequently converted into the known tricyclic ketone 33. Addition of methyl lithium followed by acid-catalyzed rearrangement employing the Pirrung protocol affords (±)-isocomene (10).

Paul A. Grieco; John K. Walker

1997-01-01T23:59:59.000Z

107

Detection of chlorpyrifos-ethyl (Dursban) and its metabolites in urine samples using immunoassays with confirmation by gas chromatography/mass spectrometry  

E-Print Network (OSTI)

by The Dow Chemical Company. ' In 1986, when regulatory measures restricted chlordane usage, Dursban (a 5% formulation of chlorpytifos-ethyl) became popular for termite control. Since chlotpyrifoswthyl is effective against a wide range of insects... (O, O-diethyl phosphate) and DETP (O, O-diethyl phosphorothioate). " A study involving termite control workers concluded that urinary alkyl phosphate levels would be a useful index in biological monitoring of chlorpyrifos exposuie: maximum DETP...

Clewis, Suenda Beth

1995-01-01T23:59:59.000Z

108

High energy beam impact tests on a LHC tertiary collimator at the CERN high-radiation to materials facility  

Science Journals Connector (OSTI)

The correct functioning of a collimation system is crucial to safely operate highly energetic particle accelerators, such as the Large Hadron Collider (LHC). The requirements to handle high intensity beams can be demanding. In this respect, investigating the consequences of LHC particle beams hitting tertiary collimators (TCTs) in the experimental regions is a fundamental issue for machine protection. An experimental test was designed to investigate the robustness and effects of beam accidents on a fully assembled collimator, based on accident scenarios in the LHC. This experiment, carried out at the CERN High-Radiation to Materials (HiRadMat) facility, involved 440 GeV proton beam impacts of different intensities on the jaws of a horizontal TCT. This paper presents the experimental setup and the preliminary results obtained, together with some first outcomes from visual inspection and a comparison of such results with numerical simulations.

Marija Cauchi; O. Aberle; R.?W. Assmann; A. Bertarelli; F. Carra; K. Cornelis; A. Dallocchio; D. Deboy; L. Lari; S. Redaelli; A. Rossi; B. Salvachua; P. Mollicone; N. Sammut

2014-02-24T23:59:59.000Z

109

Review and reconnaissance of the hydrogeology of Tertiary sedimentary rocks in the vicinity of Frenchman Flat, Nevada Test Site  

SciTech Connect

Work is currently underway within the Underground Test Area (UGTA) subproject of the US Department of Energy/Nevada Operations Office Environmental Restoration Program to develop corrective action plans in support of the overall corrective action strategy for the Nevada Test Site (NTS) as established in the Federal Facility Agreement and Consent Order (FFACO, 1996). A closure plan is currently being developed for Frenchman Flat, which has been identified in the FFACO as a Corrective Action Unit (CAU). Part of this effort requires that hydrogeologic data be compiled for inclusion in a CAU-specific hydrologic flow and transport model that will be used to predict contaminant boundaries. Hydrogeologic maps and cross sections are currently being prepared for use in the model to define the nature and extent of aquifers and confining units that might influence the flow of contaminated groundwater from underground nuclear tests conducted in Frenchman Flat. During this effort, it has been found that older Tertiary-age sediments might be hydrogeologically important in the Frenchman Flat model area. Although the character and extent of these units are poorly known, there is reason to believe that in some parts of Frenchman Flat they may lie between the regional Lower Carbonate Aquifer (LCA) and the younger Tertiary saturated alluvium and volcanic units in which several underground nuclear tests were conducted. It was not possible to quickly determine their extent, or ascertain whether or not these units might act as confining units or aquifers. The work described in this report was done to gain a better understanding of the hydrogeology of these rocks.

Prothro, L.B.; Drellack, S.L. Jr.

1997-09-01T23:59:59.000Z

110

Contrasting styles of Pre-Cenozoic and mid-Tertiary crustal evolution in northern Mexico: Evidence from deep crustal xenoliths from La Olivina  

SciTech Connect

The principal deep crustal rock types found at the La Olivina xenolith locality in southeastern Chihuahua, Mexico, are mafic granulites, paragneisses, and intermediate- to silicic-composition orthogneisses. These granulite facies xenoliths are interpreted in terms of two age groups, pre-Cenozoic and mid-Tertiary, based on previous ion probe dating of zircons from the xenoliths and on isotopic comparisons of the xenoliths to rocks of known age. The mafic granulites have Pb, Nd, and Sr isotopic compositions identical to those of Oligocene volcanic rocks from the La Olivina region. Compositionally, they are olivine-normative gabbroic cumulates, and they precipitated from two or more mid-Tertiary basalt to dacite or rhyolite assimilation/fractional crystallization series. Mineral assemblages in the xenoliths record pressures of {le} 7.2 kbar or depths of < 25 km. If these are the maximum pressures the rocks experienced and if the crust was > 35 km thick in Oligocene time as inferred from regional tectonic considerations, then the mafic granulites cannot be samples of basaltic magmas underplated near the crust-mantle boundary. The cumulate protoliths for the mafic granulites probably formed in magma chambers well above the Moho. The mafic granulites are plausibly ignimbrite fields of Mexico. Pre-Cenozoic and mid-Tertiary crustal evolution followed very different paths in northern Mexico. For example, Nd isotopic evidence for crustal recycling is much more evident in rocks associated with the Paleozoic convergence than in rocks produced during mid-Tertiary magmatism. Furthermore, mafic rocks are very rare in the pre-Cenozoic xenolith suite, but they dominate the mid-Tertiary one. The rarity of pre-Cenozoic mafic xenoliths suggests that Proterozoic and Paleozoic lower crust may have delaminated in response to crustal overthickening associated with the Ouachita collision event. 97 refs., 14 figs., 5 tabs.

Cameron, K.L.; Robinson, J.V.; Kuentz, D.C.; Collerson, K.D. [Univ. of California, Santa Cruz, CA (United States); Niemeyer, S. [Lawrence Livermore National Lab., CA (United States); Harmon, R.S. [NERC Isotope Geosciences Lab., Keyworth (United Kingdom); Bohlen, S.R. [Geological Survey, Menlo Park, CA (United States)

1992-11-10T23:59:59.000Z

111

Ethyl Alcohol Production.  

E-Print Network (OSTI)

-1/2 bushel batch. 2. The ground grain is added to and mixed with 150 gallons of water (12 gallons per bushel) at 120 degrees F. This begins the cooking process, during which the grain mixture or mash is constantly agitated. A liquefying enzyme (Taka...-1/2 bushel batch. 2. The ground grain is added to and mixed with 150 gallons of water (12 gallons per bushel) at 120 degrees F. This begins the cooking process, during which the grain mixture or mash is constantly agitated. A liquefying enzyme (Taka...

O'Neal, Henry

1981-01-01T23:59:59.000Z

112

An evaluation of the 3M Organic Vapor Monitor #3500 as a short term exposure limit sampling device for acetone, methyl ethyl ketone, and methyl iso butyl ketone  

E-Print Network (OSTI)

. An exploded view of the monitor is illustrated in Figure 1. The theory of diffusive sampling considers a concentration gra- dient between the ambient air and the adsorbent to be the driving force for sampling. For the adsorption to be controlled by diffu...AN EVALUATION OF THE 3M ORGANIC VAPOR MONITOR 43500 AS A SHOR'I TERM EXPOSURE LIMIT SAMPLING DEVICE FOR ACETONE, METHYL ETHYL KETONE, AND METHYL ISO BUTYL KETONE A Thesis by LLOYD B. ANDREW III Submitted to the Graduate College of Texas ASM...

Andrew, Lloyd B.

2012-06-07T23:59:59.000Z

113

Study of degumming process and evaluation of oxidative stability of methyl and ethyl biodiesel of Jatropha curcas L. oil from three different Brazilian states  

Science Journals Connector (OSTI)

Abstract This work describes the production of biodiesel from Jatropha curcas oil. The kernel samples provided by Embrapa-PI, were first crushed in a blender and then subjected to extraction with hexane. The oil yield was between 54.71 ± 0.47 and 64.16 ± 2.88%. The J. curcas oil was then submitted to two different kinds of degumming, first with water and second with H3PO4 to evaluate the influence of these processes in the yield of the transesterification reaction. Methyl and ethyl biodiesel prepared from the degummed oil with H3PO4 had higher conversions than those prepared with the degummed with water. Therefore, among the processes of degumming studied, H3PO4 was more suitable for the treatment of J. curcas oil. The study shows the results about oxidation stability were good, because the biodiesels methyl and ethyl biodiesel have induction period at 13.51 h and 13.03 h without antioxidant addition when submitted a Rancimat text. Such biodiesels had their physicochemical parameters defined under the specifications of ANP Resolutions n° 14/2012 (ANP- National Agency of Petroleum, Natural Gas and Biofuels from Brazil). The results showed that J. curcas cultivation in Brazil is an adequate source for biodiesel production, considering the technical standards available.

Francisca Diana da Silva Araújo; Iranildo C. Araújo; Isabella Cristhina G. Costa; Carla Verônica Rodarte de Moura; Mariana H. Chaves; Eugênio Celso E. Araújo

2014-01-01T23:59:59.000Z

114

Distribution of hazardous air pollutant trace elements, total sulfur, and ash in coals from five Tertiary basins in the Rocky Mountain Region  

SciTech Connect

Arithmetic mean values of the contents of hazardous air pollutant (HAP) trace elements named in the 1990 Clean Air Act Amendments (antimony, arsenic, beryllium, cadmium, chromium, cobalt, lead, manganese, mercury, nickel, selenium, and uranium), ash, and total sulfur were statistically compared on a whole-coal basis for Paleocene coals from five Tertiary basins in the Rocky Mountain Region. The study of proximate and elemental analyses indicate a relationship between trace element contents and paleogeography.

Ellis, M.S.; Stricker, G.D.; Flores, R.M. [Geological Survey, Denver, CO (United States)

1994-12-31T23:59:59.000Z

115

Biostratigraphic, chronostratigraphic, and stratigraphic sequence analysis of Lower Tertiary marine sediments of Alabama for indicators of sea-level change  

SciTech Connect

Early Eocene to late Oligocene marine sedimentary units in southwestern Alabama were sampled at closely spaced intervals to derive a precise time-stratigraphic framework and to determine the paleoecological and mineralogical responses to fluctuations in sea level. Paleontologic control consisted of planktonic, smaller and larger benthonic foraminifera, calcareous nannofossils, dinoflagellates, and megafossils. Paleomagnetic reversals were delineated in two boreholes which, when supplemented by strontium isotope dates and the biostratigraphic control, provided a robust in situ chronostratigraphy for the Gulf Coast lower Tertiary. Paleoecologic trends in regression and transgression can be clearly correlated across major regional facies changes. Using the chronostratigraphy developed here, the second-, third-, and fourth-orders of Vail's global sea-level cycles can be recognized and demonstrate the influence of sea-level change on sedimentation. Stratigraphic systems tracts (SSTs) and bounding surfaces in outcrop were determined by lithologic variations and paleoecologic trends, and additionally by gamma logs in the cores. The lower sequence boundary occurs at a contact where an older, relatively fine-grained, deep-water, fossiliferous unit was abruptly succeeded by a coarse-grained, shallow-water, poorly fossiliferous unit. The transgressive surface occurs at the base of a fining- and deepening-upwards unit that was commonly glauconitic and very fossiliferous. Transgression culminated with a pulse of planktonic microfossils in a bed having reduced clastic sedimentation; on the log the surface of maximum starvation was marked by a gamma spike.

Thompson, P.R. (ARCO Oil and Gas Co., Plano, TX (United States)); Baum, G.R. (ARCO Alaska, Inc., Anchorage (United States))

1991-03-01T23:59:59.000Z

116

TABLE33.CHP:Corel VENTURA  

Annual Energy Outlook 2012 (EIA)

products are reported by the PAD District of entry. b Includes crude oil imported for storage in the Strategic Petroleum Reserve. c Includes ethyl tertiary butyl ether (ETBE),...

117

TABLE34.CHP:Corel VENTURA  

Gasoline and Diesel Fuel Update (EIA)

products are reported by the PAD District of entry. b Includes crude oil imported for storage in the Strategic Petroleum Reserve. c Includes ethyl tertiary butyl ether (ETBE),...

118

Biofouling of reverse-osmosis membranes under different shear rates during tertiary wastewater desalination: Microbial community composition  

Science Journals Connector (OSTI)

Abstract We investigated the influence of feed-water shear rate during reverse-osmosis (RO) desalination on biofouling with respect to microbial community composition developed on the membrane surface. The RO membrane biofilm's microbial community profile was elucidated during desalination of tertiary wastewater effluent in a flat-sheet lab-scale system operated under high (555.6 s?1), medium (370.4 s?1), or low (185.2 s?1) shear rates, corresponding to average velocities of 27.8, 18.5, and 9.3 cm s?1, respectively. Bacterial diversity was highest when medium shear was applied (Shannon–Weaver diversity index H' = 4.30 ± 0.04) compared to RO-membrane biofilm developed under lower and higher shear rates (H? = 3.80 ± 0.26 and H? = 3.42 ± 0.38, respectively). At the medium shear rate, RO-membrane biofilms were dominated by Betaproteobacteria, whereas under lower and higher shear rates, the biofilms were dominated by Alpha- and Gamma- Proteobacteria, and the latter biofilms also contained Deltaproteobacteria. Bacterial abundance on the RO membrane was higher at low and medium shear rates compared to the high shear rate: 8.97 × 108 ± 1.03 × 103, 4.70 × 108 ± 1.70 × 103 and 5.72 × 106 ± 2.09 × 103 copy number per cm2, respectively. Interestingly, at the high shear rate, the RO-membrane biofilm's bacterial community consisted mainly of populations known to excrete high amounts of extracellular polymeric substances. Our results suggest that the RO-membrane biofilm's community composition, structure and abundance differ in accordance with applied shear rate. These results shed new light on the biofouling phenomenon and are important for further development of antibiofouling strategies for RO membranes.

Ashraf Al Ashhab; Osnat Gillor; Moshe Herzberg

2014-01-01T23:59:59.000Z

119

Experimental Autoignition of C4-C6 Saturated and Unsaturated Methyl and Ethyl Esters H. Bennadji*, J. Biet, L. Coniglio-Jaubert, F. Billaud, P.A. Glaude, F. Battin-Leclerc  

E-Print Network (OSTI)

. Keywords: Biodiesel, Methyl esters, Ethyl esters, Shock tube, Reaction mechanism. 1. Introduction Biodiesel is an alternative fuel which can be used directly to a diesel engine without modifying the engine system. Basically separate infrastructure. The use of biodiesel in conventional diesel engines results in substantial

Boyer, Edmond

120

In Situ MTBE Biodegradation Supported by Diffusive Oxygen Release  

Science Journals Connector (OSTI)

Noted on the figure are the locations of some of the monitoring conducted as part of our project, notably transects A?C. ... Selected VOC samples were sent to Turtle Bayou Laboratories (Liberty, TX) for TBA analyses via GC/MS (estimated detection limit 1 ?g/L). ...

Ryan D. Wilson; Douglas M. Mackay; Kate M. Scow

2001-12-13T23:59:59.000Z

Note: This page contains sample records for the topic "mtbe ethyl tertiary" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

The Social Costs of an MTBE Ban in California  

E-Print Network (OSTI)

additive factors of the net loss in volume due to removal ofadditive factors of the net loss in volume due to removal of

Rausser, Gordon C.; Adams, Gregory D.; Montgomery, W. David; Smith, Anne E.

2005-01-01T23:59:59.000Z

122

The Social Costs of an MTBE Ban in California  

E-Print Network (OSTI)

and W.D. Montgomery. Oil Prices, Energy Security, and Importnew equilibrium world oil price and level of U.S. imports.to estimate the changes in oil prices that would result from

Rausser, Gordon C.; Adams, Gregory D.; Montgomery, W. David; Smith, Anne E.

2005-01-01T23:59:59.000Z

123

The Social Costs of an MTBE Ban in California  

E-Print Network (OSTI)

for crude oil. Ethanol also has lower energy density thangallon. 41 Ethanol also contains less energy per physicalbe replaced by ethanol. California Energy Commission, Staff

Rausser, Gordon C.; Adams, Gregory D.; Montgomery, W. David; Smith, Anne E.

2005-01-01T23:59:59.000Z

124

Hospital-acquired infection rate in a tertiary care teaching hospital in China: a cross-sectional survey involving 2434 inpatients  

Science Journals Connector (OSTI)

Summary A single-day hospital-acquired infections (HAIs) point prevalence study was conducted in a tertiary care hospital in China. The overall prevalence rate of \\{HAIs\\} was 3.53% (95% confidence interval 2.80–4.26%) among 2434 inpatients surveyed. Respiratory system infection was the most common type of HAI (49.43%), followed by surgical site infection (22.99%). The pathogen detection results for 50 patients showed Pseudomonas aeruginosa to account for 24.00% of isolates, followed by Klebsiella pneumoniae (14.00%) and Escherichia coli (14.00%).

Xiu-Bin Tao; Li-Hua Qian; Yan Li; Qun Wu; Jing-Jing Ruan; Dong-Zhen Cai; Hui Peng

2014-01-01T23:59:59.000Z

125

Simultaneous Efficiency, NOx, and Smoke Improvements through Diesel/Gasoline Dual-Fuel Operation in a Diesel Engine  

E-Print Network (OSTI)

or liquefied petroleum gas, natural gas, biogas, hydrogen, and alcohols such as methanol, ethanol, iso-propanol, and n-butanol), and fuel additives (MTBE or methyl tertiary-butyl ether, H2O2 or hydrogen peroxide, 2-EHN or ethylhexyl nitrate and DTBP or di...

Sun, Jiafeng

2014-08-05T23:59:59.000Z

126

Sub-crop geologic map of pre-Tertiary rocks in the Yucca Flat and northern Frenchman Flat areas, Nevada Test Site, southern Nevada  

SciTech Connect

This map displays interpreted structural and stratigraphic relations among the Paleozoic and older rocks of the Nevada Test Site region beneath the Miocene volcanic rocks and younger alluvium in the Yucca Flat and northern Frenchman Flat basins. These interpretations are based on a comprehensive examination and review of data for more than 77 drillholes that penetrated part of the pre-Tertiary basement beneath these post-middle Miocene structural basins. Biostratigraphic data from conodont fossils were newly obtained for 31 of these holes, and a thorough review of all prior microfossil paleontologic data is incorporated in the analysis. Subsurface relationships are interpreted in light of a revised regional geologic framework synthesized from detailed geologic mapping in the ranges surrounding Yucca Flat, from comprehensive stratigraphic studies in the region, and from additional detailed field studies on and around the Nevada Test Site. All available data indicate the subsurface geology of Yucca Flat is considerably more complicated than previous interpretations have suggested. The western part of the basin, in particular, is underlain by relics of the eastward-vergent Belted Range thrust system that are folded back toward the west and thrust by local, west-vergent contractional structures of the CP thrust system. Field evidence from the ranges surrounding the north end of Yucca Flat indicate that two significant strike-slip faults track southward beneath the post-middle Miocene basin fill, but their subsurface traces cannot be closely defined from the available evidence. In contrast, the eastern part of the Yucca Flat basin is interpreted to be underlain by a fairly simple north-trending, broad syncline in the pre-Tertiary units. Far fewer data are available for the northern Frenchman Flat basin, but regional analysis indicates the pre-Tertiary structure there should also be relatively simple and not affected by thrusting. This new interpretation has implications for ground water flow through pre-Tertiary rocks beneath the Yucca Flat and northern Frenchman Flat areas, and has consequences for ground water modeling and model validation. Our data indicate that the Mississippian Chainman Shale is not laterally extensive confining unit in the western part of the basin because it is folded back onto itself by the convergent structures of the Belted Range and CP thrust systems. Early and Middle Paleozoic limestone and dolomite are present beneath most of both basins and, regardless of structural complications, are interpreted to form a laterally continuous and extensive carbonate aquifer. Structural culmination that marks the French Peak accommodation zone along the topographic divide between the two basins provides a lateral pathway through highly fractured rock between the volcanic aquifers of Yucca Flat and the regional carbonate aquifer. This pathway may accelerate the migration of ground-water contaminants introduced by underground nuclear testing toward discharge areas beyond the Nevada Test Site boundaries. Predictive three-dimensional models of hydrostratigraphic units and ground-water flow in the pre-Tertiary rocks of subsurface Yucca Flat are likely to be unrealistic due to the extreme structural complexities. The interpretation of hydrologic and geochemical data obtained from monitoring wells will be difficult to extrapolate through the flow system until more is known about the continuity of hydrostratigraphic units. 1 plate

Cole, J.C.; Harris, A.G.; Wahl, R.R.

1997-10-02T23:59:59.000Z

127

Variations in Mg/Ca as a control on distribution of strontium concentrations and delta/sup 18/O in upper Tertiary dolomites from Bahamas  

SciTech Connect

Strontium concentrations and delta/sup 18/O are commonly used to infer the gross composition of dolomitizing waters, yet the bases for such inferences are not firmly established. A new approach to calibrating these 2 parameters is suggested from analyses of a section of upper Tertiary dolomites from the Bahamas. In an interval of dolomite, 120 m (394 ft) from a core taken on San Salvador Island, mole % MgCO/sub 3/ is correlated positively with delta/sup 18/O, and negatively with strontium. Strontium substitutes mainly for calcium, thus the negative correlation with mole % MgCO/sub 3/. Dolomites are enriched between 3 to 7% in delta/sup 18/O as compared with coprecipitated calcite, and thus the positive correlation. These two covariations indicate the need to consider the stoichiometric coefficient of dolomites, and to normalize strontium concentrations and delta/sup 18/O with their respective stoichiometric coefficients before inferring their relationship with fluid composition.

Swart, P.K.; Dawans, J.M.

1984-04-01T23:59:59.000Z

128

Nonassociated gas resources in low-permeability sandstone reservoirs, lower tertiary Wasatch Formation, and upper Cretaceous Mesaverde Group, Uinta Basin, Utah  

SciTech Connect

The US Geological Survey recognizes six major plays for nonassociated gas in Tertiary and Upper Cretaceous low-permeability strata of the Uinta Basin, Utah. For purposes of this study, plays without gas/water contacts are separated from those with such contacts. Continuous-saturation accumulations are essentially single fields, so large in areal extent and so heterogeneous that their development cannot be properly modeled as field growth. Fields developed in gas-saturated plays are not restricted to structural or stratigraphic traps and they are developed in any structural position where permeability conduits occur such as that provided by natural open fractures. Other fields in the basin have gas/water contacts and the rocks are water-bearing away from structural culmination`s. The plays can be assigned to two groups. Group 1 plays are those in which gas/water contacts are rare to absent and the strata are gas saturated. Group 2 plays contain reservoirs in which both gas-saturated strata and rocks with gas/water contacts seem to coexist. Most units in the basin that have received a Federal Energy Regulatory Commission (FERC) designation as tight are in the main producing areas and are within Group 1 plays. Some rocks in Group 2 plays may not meet FERC requirements as tight reservoirs. However, we suggest that in the Uinta Basin that the extent of low-permeability rocks, and therefore resources, extends well beyond the limits of current FERC designated boundaries for tight reservoirs. Potential additions to gas reserves from gas-saturated tight reservoirs in the Tertiary Wasatch Formation and Cretaceous Mesaverde Group in the Uinta Basin, Utah is 10 TCF. If the potential additions to reserves in strata in which both gas-saturated and free water-bearing rocks exist are added to those of Group 1 plays, the volume is 13 TCF.

Fouch, T.D.; Schmoker, J.W.; Boone, L.E.; Wandrey, C.J.; Crovelli, R.A.; Butler, W.C.

1994-08-01T23:59:59.000Z

129

Oxygenate Supply/Demand Balances in the Short-Term Integrated Forecasting Model (Released in the STEO March 1998)  

Reports and Publications (EIA)

The blending of oxygenates, such as fuel ethanol and methyl tertiary butyl ether (MTBE), into motor gasoline has increased dramatically in the last few years because of the oxygenated and reformulated gasoline programs. Because of the significant role oxygenates now have in petroleum product markets, the Short-Term Integrated Forecasting System (STIFS) was revised to include supply and demand balances for fuel ethanol and MTBE. The STIFS model is used for producing forecasts in the Short-Term Energy Outlook. A review of the historical data sources and forecasting methodology for oxygenate production, imports, inventories, and demand is presented in this report.

1998-01-01T23:59:59.000Z

130

Atmospheric Chemistry of Ethyl Propionate  

Science Journals Connector (OSTI)

Atomic chlorine was produced by photolysis of Cl gas (reaction 9) with UV-A light, and OH was generated by photolysis of ozone with UV-C light followed by reaction with water vapor (reactions 10 and 11). ... (9)(10)(11)O3 was generated from O2 with an ozone generator from O3 Technology (model AC-20), and condensed on silica gel that was cooled with ethanol and dry ice to approximately ?70 °C. ... However, we show here a new surface-mediated coupling of nitrogen oxide and halogen activation cycles in which uptake of gaseous NO(2) or N(2)O(5) on solid substrates generates adsorbed intermediates that react with HCl to generate gaseous nitrosyl chloride (ClNO) and nitryl chloride (ClNO(2)), respectively. ...

Vibeke F. Andersen; Kristian B. Ørnsø; Solvejg Jørgensen; Ole John Nielsen; Matthew S. Johnson

2012-04-23T23:59:59.000Z

131

Factors controlling reservoir quality in tertiary sandstones and their significance to geopressured geothermal production. Annual report, May 1, 1979-May 31, 1980  

SciTech Connect

Differing extents of diagenetic modification is the factor primarily responsible for contrasting regional reservoir quality of Tertiary sandstones from the Upper and Lower Texas Gulf Coast. Detailed comparison of Frio sandstones from the Chocolate Bayou/Danbury Dome area, Brazoria County, and Vicksburg sandstones from the McAllen Ranch Field area, Hidalgo County, reveals that extent of diagenetic modification is most strongly influenced by (1) detrital mineralogy and (2) regional geothermal gradients. Vicksburg sandstones from the McAllen Ranch Field area are less stable, chemically and mechanically, than Frio sandstones from the Chocolate Bayou/Danbury dome area. Vicksburg sandstones are mineralogically immature and contain greater proportions of feldspars and rock fragments than do Frio sandstones. Thr reactive detrital assemblage of Vicksubrg sandstones is highly susceptible to diagenetic modification. Susceptibility is enhanced by higher than normal geothermal gradients in the McAllen Ranch Field area. Thus, consolidation of Vicksburg sandstones began at shallower depth of burial and precipitation of authigenic phases (especially calcite) was more pervasive than in Frio sandstones. Moreover, the late-stage episode of ferroan calcite precipitation that occluded most secondary porosity in Vicksburg sandstones did not occur significantly in Frio sandstones. Therefore, regional reservoir quality of Frio sandstones from Brazoria County is far better than that characterizing Vicksburg sandstones from Hidalgo County, especially at depths suitable for geopressured geothermal energy production.

Loucks, R.G.; Richmann, D.L.; Milliken, K.L.

1980-07-01T23:59:59.000Z

132

Compound “J” in Late Cretaceous/Tertiary terrigenous oils revisited: Structure elucidation of a rearranged oleanane coeluting on GC with 18?(H)-oleanane  

Science Journals Connector (OSTI)

Abstract A C30 pentacyclic triterpane eluting slightly after 18?(H)-oleanane in the m/z 191 mass chromatograms of Late Cretaceous/Tertiary terrigenous oils (peak “J” in the early literature) has been isolated from a Niger Delta oil and identified using NMR spectroscopy as 3?-methyl-24-nor-18?(H)-oleanane. The previous assignment as 18?(H)-oleanane is therefore partly erroneous. 3?-Methyl-24-nor-18?(H)-oleanane affords a larger m/z 412 ? 356 response than the oleananes and the relative contribution of 3?-methyl-24-nor-18?(H)-oleanane to the 412 ? 191 “oleanane peak” can be roughly estimated from comparison of the 412 ? 356/412 ? 191 ratio from the oleanane peak with that of the pure compounds. 3?-Methyl-24-nor-18?(H)-oleanane can be as abundant as 18?(H)-oleanane in oils having a high concentration of early eluting rearranged oleananes. 3?-Methyl-24-nor-19?(H)-taraxastane was also tentatively assigned in the oils on the basis of its mass spectrum as well as its gas chromatography and high performance liquid chromatography retention times. 3?-Methyl-24-nor-gammacerane was tentatively assigned in a similar way in an oil containing gammacerane. All 3?-methyl-24-nor-triterpanes could be formed via dehydration, rearrangement and hydrogenation of triterpenoids having an OH group at C-3.

Hans Peter Nytoft; Geir Kildahl-Andersen; Tatjana Šolevi? Knudsen; Ksenija Stojanovi?; Frode Rise

2014-01-01T23:59:59.000Z

133

Reaction of Cp*3Co3(.mu.3-CCH3)(.mu.3-H) with (Trimethylsilyl)diazomethane and Ethyl Diazoacetate: Facile Hydrogen Transfer Forms the Diazenide Clusters Cp*3Co3(.mu.3-CCH3)(.mu.3-.eta.1-NNCH2SiMe3) and Cp*3Co3(.mu.3-CCH3)(.mu.3-.eta.1-NNCH2CO2Et)  

Science Journals Connector (OSTI)

Reaction of Cp*3Co3(.mu.3-CCH3)(.mu.3-H) with (Trimethylsilyl)diazomethane and Ethyl Diazoacetate: Facile Hydrogen Transfer Forms the Diazenide Clusters Cp*3Co3(.mu.3-CCH3)(.mu.3-.eta.1-NNCH2SiMe3) and Cp*3Co3(.mu.3-CCH3)(.mu.3-.eta.1-NNCH2CO2Et) ...

Charles P. Casey; Ross A. Widenhoefer; Randy K. Hayashi

1995-04-01T23:59:59.000Z

134

Asymmetric synthesis of both enantiomers of esters and ?-lactones from optically active 1-chlorovinyl p-tolyl sulfoxides and lithium ester enolates with the formation of a tertiary or a quaternary carbon stereogenic center at the ?-position  

Science Journals Connector (OSTI)

Treatment of optically active 1-chlorovinyl p-tolyl sulfoxides having two different substituents at the 2-position, which were synthesized from aldehydes or unsymmetrical ketones and (R)-(?)-chloromethyl p-tolyl sulfoxide in two or three steps, with the lithium enolate of tert-butyl acetate gave optically active adducts in 99% chiral induction from the sulfur stereogenic center. The adducts were converted to optically active esters, carboxylic acids, and ?-lactones, which have a tertiary or a quaternary carbon stereogenic center at the ?-position. A synthesis of optically active spiro-lactones was realized starting from 2-cyclohexenone by this method.

Shimpei Sugiyama; Tsuyoshi Satoh

2005-01-01T23:59:59.000Z

135

Acute, sub-acute and general pharmacological evaluation of 5-(3,4-methylenedioxyphenyl)-4-ethyl-2E,4E-pentadienoic acid piperidide (SK-20): A novel drug bioavailability enhancer  

Science Journals Connector (OSTI)

An efflux pump inhibitor, SK-20 (5-(3,4-methylenedioxyphenyle)-4 ethyl-2E,4E-pentadienoic acid piperidide), was assessed for its toxicity at three different pharmacological profiles: acute, sub-acute and general pharmacology with pharmacokinetics. In acute study, the SK-20 was found safe up to a dose of 2000 mg/kg (b.wt.); and at sub-acute, dosages of 50 and 100 mg/kg (b.wt.) were found to be safe. However, dosages of 200 mg or above per kg (b.wt.) showed some morphological alterations in cellular architecture of both liver and kidneys in both sexes, viz., mild vascular congestion along with sporadic hemorrhages and infiltration into renal and hepatic parenchyma by mononucleate cell. General pharmacological studies did not result into any alterations in analgesic, convulsions, rectal temperatures and in the rhythm or the rate of the intestinal motility or the secretion of the bile. While the respiratory and the cardiac rate remained normal, the only parameter to show was the blood pressure, which at all the doses tested, showed a tendency toward reduction. Characteristically, the SK-20 at all doses influenced pentobarbital-induced hypnosis positively and negatively to spontaneous motor activity in a dose dependent manner. Pharmacokinetics of SK-20 revealed it to have retention time at 10.2 min and half life 2.47 h.

Sheikh Rayees; Rohit Sharma; Gurdarshan Singh; Ishtiyaq Ahmad Najar; Amarinder Singh; Dastagir Basheer Ahamad; Subash Chander Sharma; Manoj Kumar Tikoo; Vijay Kumar Gupta; Payare Lal Sangwan; Surjeet Singh; Surinder Koul; Rakesh Kamal Johri

2013-01-01T23:59:59.000Z

136

Combustion Characteristics of Tricomponent Fuel Blends of Ethyl Acetate, Ethyl Propionate, and Ethyl Butyrate in Homogeneous Charge Compression Ignition (HCCI)  

Science Journals Connector (OSTI)

Their proportions in the mixture vary according to fermentation conditions and biomass feedstocks. ...

Francesco Contino; Fabrice Foucher; Christine Mounaïm-Rousselle; Hervé Jeanmart

2011-03-09T23:59:59.000Z

137

Viscosity of gaseous ethyl fluoride (HFC-161)  

Science Journals Connector (OSTI)

Abstract The paper describes an improved Maxwell type oscillating-disk viscometer. The experimental system was calibrated by argon, carbon dioxide, nitrogen, hydrogen and verified by nitrogen. The viscosities of gaseous HFC-161 were measured from 293 K to 369 K at pressures from 0.1 MPa up to the saturated vapor pressure. An empirical viscosity equation is proposed to interpolate the present experimental data as a function of density and temperature. The uncertainty of the reported viscosity was estimated to be within 1%.

Shaohua Lv; Xiaoming Zhao; Chuanqi Yao; Wei Wang; Zhikai Guo

2014-01-01T23:59:59.000Z

138

Sandia National Laboratories: fatty acid ethyl esters  

NLE Websites -- All DOE Office Websites (Extended Search)

Doppler Velocimeter EC Top Publications A Comparison of Platform Options for Deep-water Floating Offshore Vertical Axis Wind Turbines: An Initial Study Nonlinear Time-Domain...

139

Assessment of Summer RBOB Supply for NY & CT  

Gasoline and Diesel Fuel Update (EIA)

Update of Summer Reformulated Gasoline Supply Update of Summer Reformulated Gasoline Supply Assessment for New York and Connecticut May 5, 2004 In October 2003, EIA published a review of the status of the methyl tertiary butyl ether (MTBE) ban transition in New York (NY) and Connecticut (CT) 1 that noted significant uncertainties in gasoline supply for those States for the summer of 2004. To obtain updated information, EIA spoke to major suppliers to the two States over the past several months as the petroleum industry began the switch from winter- to summer-grade gasoline. As discussed on our earlier report, the NY and CT bans on MTBE mainly affect reformulated gasoline (RFG), which in recent years has been provided by domestic refineries on the East Coast (PADD 1) and imports. Our recent findings indicate that

140

Pool octanes via oxygenates  

SciTech Connect

Increasingly stringent antipollution regulations placed on automobile exhaust gases with consequent reduction or complete lead ban from motor gasoline result in octane shortage at many manufacturing sites. Attractive solutions to this problem, especially in conjunction with abundant methanol supplies, are the hydration and etherification of olefins contained in light product streams from cracking unit or produced by field gas dehydrogenation. A comparison is made between oxygenates octane-volume pool contributions and established refinery technologies. Process reviews for bulk manufacture of fuel-grade isopropanol (IPA), secondary butanol (SBA), tertiary butanol (TBA), methyl tertiary butyl ether (MTBE) and tertiary amyl methyl ether (TAME) are presented together with the characteristic investment and operating data. The implantation of these processes into a typical FCCU refinery complex with the resulting octane-pool improvement possibilities is descried.

Prezelj, M.

1987-09-01T23:59:59.000Z

Note: This page contains sample records for the topic "mtbe ethyl tertiary" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Later Tertiary Leporidae of North America  

E-Print Network (OSTI)

Saskatchewan. Generic characters. Compared with Megalagus brachyodon, cheek-teeth less hypsodont, molarization of premolars less advanced, molars less reduced, and maxilla and mandibular ramus narrower in premolar region; P3-P4 each having shallow hypostria... the Myton Pocket in Utah and M. wyomingensis from Badwater Creek, Wyoming, specimens from the Wagonhound member of the Uinta Eocene, the Duchesne River (Rand- lett horizon), and the Swift Current Creek beds of Saskatchewan have been referred to this genus...

Dawson, M. R.

1958-05-01T23:59:59.000Z

142

Tertiary paleomagnetic results from east Kalimantan  

E-Print Network (OSTI)

0 Fig. l. Major transcurrent faults in Southeast Asia. Ic = Indochina; M = Malaysia; SCS = South China Sea; B = Kalimantan; J = Java Sea; S = Sulawesi. eastern Kalimantsn ranging from Eocene to Plio ? Pleistocene age. The result of this study... al. , 1983), the Philippines (McCabe et al. , 1987), Sulawesi (Haile, 1978; Sasajima et al. , 1980; Otofuji et al. , 1981) and Indochina (Giang, 1982; McCabe et sl. , 1988). The pole from this study is indistin- guisha. ble at the 95% confidence...

Lumadyo, Leonard E. D

2012-06-07T23:59:59.000Z

143

Ion exchange as a tertiary treatment  

E-Print Network (OSTI)

that these treatment methods are capable of removing an appreciable amount of objection? able dissolved organic and inorganic materi aJ s from the final effluent. Color and turbidity were greatly reduced and an appreciable amount of the suspended solids were... Demand Re Resin A General Anion mg. /1. MLVSS psi gpm Milligrams per I. iter Mixed Liquor Volatile Suspended Solids Pounds per Square Inch Gallons per Minute. mm Mi llimeters kgr meq ml Kilogram Milliequilavent Millimeter S. S. BV...

Westervelt, Ronald David

1968-01-01T23:59:59.000Z

144

Energy Balance for Ethyl Alcohol Production from Crops  

Science Journals Connector (OSTI)

...used in agricultural and industrial processing, except the solar energy that the plants use for growth. Moreira and Goldemberg...which they live to-gether in the Serengeti National Park of Tanzania. During the wet season, which extends from November through...

JOSÉ GOMES DA SILVA; GIL EDUARDO SERRA; JOSÉ ROBERTO MOREIRA; JOSÉ CARLOS CONÇALVES; JOSÉ GOLDEMBERG

1978-09-08T23:59:59.000Z

145

LIGNIN BIODEGRADATION AND THE PRODUCTION OF ETHYL ALCOHOL FROM CELLULOSE  

E-Print Network (OSTI)

and Moore, W. E. , Removing lignin from wood with white-rotof carbohydrates on lignin degradation by the white-rotP. and Eriksson, K. -E. , Lignin degradation and utilization

Rosenberg, S.L.

2013-01-01T23:59:59.000Z

146

Methylene II. Gas Phase Reactions with Ethyl Chloride  

Science Journals Connector (OSTI)

27 August 1968 research-article Methylene II. Gas Phase Reactions...free-radical mechanism in which CH abstracts a chlorine or a hydrogen atom from C...in electronic structure rather than energy content. The Royal Society is collaborating...

1968-01-01T23:59:59.000Z

148

Ozone-forming potential of a series of oxygenated organic compounds  

SciTech Connect

An incremental reactivity approach has been used to assess the relative ozone-forming potentials of various important oxygenated fuels/fuel additives, i.e., tert-butyl alcohol (TBA), dimethyl ether (DME), diethyl ether (DEE), methyl tert-butyl ether (MTBE), and ethyl tert-butyl ether (ETBE), in a variety of environments. Calculations were performed using a single-cell trajectory model, combined with the Lurmann-Carter-Coyner chemical mechanism, with (NMOC)/(NO{sub x}) ratios ranging from 4 to 20. This work provides the first quantitative assessment of the air quality impact of release of these important oxygenated compounds. ETBE and DEE are the two most reactive compounds on a per carbon equivalent basis, while TBA is the least reactive species. At a (NMOC)/(NO{sub x}) ratio of 8, which is generally typical of polluted urban areas in the United States, TBA, DME, MTBE, and ETBE all have incremental reactivities less than or equal to that of the urban NMHC mix. Thus, use of these additives in fuels may have a beneficial impact on urban ozone levels.

Japar, S.M.; Wallington, T.J.; Rudy, S.J.; Chang, Tai Y. (Ford Motor Company, Dearborn, MI (USA))

1991-03-01T23:59:59.000Z

149

Assessing and Managing the Risks of Fuel Compounds: Ethanol Case Study  

SciTech Connect

We have implemented a suite of chemical transport and fate models that provide diagnostic information about the behavior of ethanol (denoted EtOH) and other fuel-related chemicals released to the environment. Our principal focus is on the impacts to water resources, as this has been one of the key issues facing the introduction of new fuels and additives. We present analyses comparing the transport and fate of EtOH, methyl tertiary butyl ether (MTBE), and 2,2,4 trimethyl pentane (TMP) for the following cases (1) discharges to stratified lakes, subsurface release in a surficial soil, (3) cross-media transfer from air to ground water, and (4) fate in a regional landscape. These compounds have significantly different properties that directly influence their behavior in the environment. EtOH, for example, has a low Henry's law constant, which means that it preferentially partitions to the water phase instead of air. An advantageous characteristic of EtOH is its rapid biodegradation rate in water; unlike MTBE or TMP, which degrade slowly. As a consequence, EtOH does not pose a significant risk to water resources. Preliminary health-protective limits for EtOH in drinking water suggest that routine releases to the environment will not result in levels that threaten human health.

Layton, D.W.; Rice, D.W.

2002-02-04T23:59:59.000Z

150

High octane ethers from synthesis gas-derived alcohols. Final technical report, September 25, 1990--December 24, 1993  

SciTech Connect

The objective of the research was to develop the methodology for the catalytic synthesis of ethers, primarily methyl isobutyl ether (MIBE) and methyl tertiary butyl ether (MTBE), directly from alcohol mixtures that are rich in methanol and 2-methyl-1-propanol (isobutanol). The overall scheme involves gasification of coal, purification and shifting of the synthesis gas, higher alcohol synthesis, and direct synthesis of ethers. The last stage of the synthesis involves direct coupling of synthesis gas-derived methanol and isobutanol that has been previously demonstrated by us to occur over superacid catalysts to yield MIBE and smaller amounts of MTBE at moderate pressures and a mixture of methanol and isobutene at low pressures. A wide range of organic resin catalysts and inorganic oxide and zeolite catalysts have been investigated for activity and selectivity in directly coupling alcohols, principally methanol and isobutanol, to form ethers and in the dehydration of isobutanol to isobutene in the presence of methanol. All of these catalysts are strong acids, and it was found that the organic and inorganic catalysts operate in different, but overlapping, temperature ranges, i.e. mainly 60--120{degrees}C for the organic resins and 90--175{degrees}C for the inorganic catalysts. For both types of catalysts, the presence of strong acid centers is required for catalytic activity, as was demonstrated by lack of activity of fully K{sup +} ion exchanged Nafion resin and zirconia prior to being sulfated by treatment with sulfuric acid.

Klier, K.; Herman, R.G.

1994-05-01T23:59:59.000Z

151

Appendix A - Acronyms  

NLE Websites -- All DOE Office Websites (Extended Search)

A - ACRONYMS A - ACRONYMS AASHTO American Association of State Highway and Transportation Officials CNG Compressed Natural Gases CVO Commercial Vehicle Operation DOE Department of Energy DOT Department of Transportation E85 85% Ethanol, 15% Gasoline EPA Environmental Protection Agency ExFIRS Excise Files Information Retrieval System ExSTARS Excise Summary Terminal Activity Reporting System FHWA Federal Highway Administration FTA Federation of Tax Administrators GAO General Accounting Office HTF Highway Trust Fund IFTA International Fuel Tax Agreement IM Interstate Maintenance IRS Internal Revenue Service LNG Liquid Natural Gases LPG Liquefied Petroleum Gases M85 85% Methanol, 15% Gasoline MTBE Methyl Tertiary Butyl Ether NHS National Highway System ORNL Oak Ridge National Laboratory STP Surface Transportation Program

152

Total Blender Net Input of Petroleum Products  

U.S. Energy Information Administration (EIA) Indexed Site

Input Input Product: Total Input Natural Gas Plant Liquids and Liquefied Refinery Gases Pentanes Plus Liquid Petroleum Gases Normal Butane Isobutane Other Liquids Oxygenates/Renewables Methyl Tertiary Butyl Ether (MTBE) Renewable Fuels (incl. Fuel Ethanol) Fuel Ethanol Renewable Diesel Fuel Other Renewable Fuels Unfinished Oils (net) Unfinished Oils, Naphthas and Lighter Unfinished Oils, Kerosene and Light Gas Oils Unfinished Oils, Heavy Gas Oils Residuum Motor Gasoline Blending Components (MGBC) (net) MGBC - Reformulated MGBC - Reformulated - RBOB MGBC - Reformulated, RBOB for Blending w/ Alcohol MGBC - Reformulated, RBOB for Blending w/ Ether MGBC - Reformulated, GTAB MGBC - Conventional MGBC - Conventional, CBOB MGBC - Conventional, GTAB MGBC - Other Conventional Period-Unit: Monthly-Thousand Barrels Monthly-Thousand Barrels per Day Annual-Thousand Barrels Annual-Thousand Barrels per Day

153

Total Refinery Net Input of Crude Oil and Petroleum Products  

U.S. Energy Information Administration (EIA) Indexed Site

Input Input Product: Total Crude Oil & Petroleum Products Crude Oil Natural Gas Plant Liquids Pentanes Plus Liquefied Petroleum Gases Normal Butane Isobutane Other Liquids Hydrogen/Oxygenates/Renewables/Other Hydrocarbons Hydrogen Oxygenates (excl. Fuel Ethanol) Methyl Tertiary Butyl Ether (MTBE) All Other Oxygenates Renewable Fuels (incl. Fuel Ethanol) Fuel Ethanol Renewable Diesel Fuel Other Renewable Fuels Other Hydrocarbons Unfinished Oils (net) Unfinished Oils, Naphthas and Lighter Unfinished Oils, Kerosene and Light Gas Oils Unfinished Oils, Heavy Gas Oils Residuum Motor Gasoline Blending Components (MGBC) (net) MGBC - Reformulated MGBC - Reformulated - RBOB MGBC - Reformulated, RBOB for Blending w/ Alcohol MGBC - Reformulated, RBOB for Blending w/ Ether MGBC - Conventional MGBC - CBOB MGBC - Conventional, GTAB MGBC - Other Conventional Aviation Gasoline Blending Components (net) Alaskan Crude Oil Receipts Period-Unit: Monthly-Thousand Barrels Monthly-Thousand Barrels per Day Annual-Thousand Barrels Annual-Thousand Barrels per Day

154

Refinery & Blenders Net Input of Crude Oil  

U.S. Energy Information Administration (EIA) Indexed Site

Input Input Product: Total Crude Oil & Petroleum Products Crude Oil Natural Gas Plant Liquids and Liquefied Refinery Gases Pentanes Plus Liquefied Petroleum Gases Ethane Normal Butane Isobutane Other Liquids Hydrogen/Oxygenates/Renewables/Other Hydrocarbons Hydrogen Oxygenates (excl. Fuel Ethanol) Methyl Tertiary Butyl Ether (MTBE) All Other Oxygenates Renewable Fuels (incl. Fuel Ethanol) Fuel Ethanol Renewable Diesel Fuel Other Renewable Fuels Other Hydrocarbons Unfinished Oils (net) Unfinished Oils, Naphthas and Lighter Unfinished Oils, Kerosene and Light Gas Oils Unfinished Oils, Heavy Gas Oils Residuum Motor Gasoline Blending Components (MGBC) (net) MGBC - Reformulated MGBC - Reformulated - RBOB MGBC - Reformulated, RBOB for Blending w/ Alcohol MGBC - Reformulated, RBOB for Blending w/ Ether MGBC - Reformulated, GTAB MGBC - Conventional MGBC - CBOB MGBC - Conventional, GTAB MGBC - Other Conventional Aviation Gasoline Blending Components (net) Period-Unit: Monthly-Thousand Barrels Monthly-Thousand Barrels per Day Annual-Thousand Barrels Annual-Thousand Barrels per Day

155

Process for tertiary oil recovery using tall oil pitch  

DOE Patents (OSTI)

A process and compositions for enhancing the recovery of acid crudes are disclosed. The process involves injecting caustic solutions into the reservoir to maintain a pH of 11 to 13. The fluid contains an effective amount of multivalent cation for inhibiting alkaline silica dissolution with the reservoir. A tall oil pitch soap is added as a polymeric mobility control agent. (DMC)

Radke, C.J.

1983-07-25T23:59:59.000Z

156

The Existence of Man in the Tertiary Epoch  

Science Journals Connector (OSTI)

... IN the Bibliothèque Universelle et Revue Suisse for the 15 th February, M. Favre, in an article ...

1870-04-07T23:59:59.000Z

157

Cosolvent-induced transformation of a death domain tertiary structure  

Science Journals Connector (OSTI)

...Density modification using SOLOMON (17) increased the figure of merit from 0.70 to 0.82 at 2.7-a resolution. A...S. W. ( 1993 ) Proteins 17,75 -86. 8234246 We thank Nick Pace for a critical reading of the manuscript, A. Loew, D...

Tsan Xiao; Kevin H. Gardner; Stephen R. Sprang

2002-01-01T23:59:59.000Z

158

THE EARLY TERTIARY VOLCAINOES OF THE ABSAROKA RANGE  

Science Journals Connector (OSTI)

...interbedded breecias pass into sheets, and later again assume the...varied modifications of eruptive energy, a bold stock, Clouds Home...examples of a massive interbedded sheet extends for a mile or more along...Beyond this point eruptive energy gradually dies out, and is...

Arnold Hague

1899-03-24T23:59:59.000Z

159

Freezing-induced perturbation of tertiary structure of monoclonal antibody  

E-Print Network (OSTI)

-30 -20 -10 0 10 20 Temperature (C) E m i ssi o n p eak p o s i t i o n ( n m) IgG+KCl Pre-frozen 20C Frozen -30C Post-thawed 20C Peak shift due to freez- ing pH8 338.4 ? 0.1 nm 338.7 ? 0.0 nm 338.0 ? 0.1 nm 0.3 nm pH3 340.7 ? 0.5 nm...

Liu, Lu; Kueltzo, L. A.; Jones, L. S.; Carpenter, J. F.

2006-10-25T23:59:59.000Z

160

Low Barrier Hydrogen Bonds in Acyclic Tertiary Diamines  

E-Print Network (OSTI)

B: synthesis of diamide with phosphorous pentoxide, and C:synthesis uses phosphorous pentoxide and dimethylformamide (B: synthesis of diamide with phosphorous pentoxide, and C:

Khodagholian, Sevana

2010-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "mtbe ethyl tertiary" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

RELATIONS BETWEEN THE DETECTION OF METHYL TERT-BUTYL ETHER (MTBE) IN SURFACE AND GROUND WATER AND ITS CONTENT IN GASOLINE  

E-Print Network (OSTI)

AND ITS CONTENT IN GASOLINE By Michael J. Moran, Mike J. Halde, Rick M. Clawges and John S. Zogorski U in the United States as an octane enhancer and oxygenate in gasoline. Octane enhancement began in the late 1970's with the phase-out of tetraethyl lead from gasoline. The use of oxygenates was expanded

162

Vehicle Technologies Office: Fact #264: April 21, 2003 Production of  

NLE Websites -- All DOE Office Websites (Extended Search)

4: April 21, 4: April 21, 2003 Production of Ethanol and MTBE to someone by E-mail Share Vehicle Technologies Office: Fact #264: April 21, 2003 Production of Ethanol and MTBE on Facebook Tweet about Vehicle Technologies Office: Fact #264: April 21, 2003 Production of Ethanol and MTBE on Twitter Bookmark Vehicle Technologies Office: Fact #264: April 21, 2003 Production of Ethanol and MTBE on Google Bookmark Vehicle Technologies Office: Fact #264: April 21, 2003 Production of Ethanol and MTBE on Delicious Rank Vehicle Technologies Office: Fact #264: April 21, 2003 Production of Ethanol and MTBE on Digg Find More places to share Vehicle Technologies Office: Fact #264: April 21, 2003 Production of Ethanol and MTBE on AddThis.com... Fact #264: April 21, 2003 Production of Ethanol and MTBE

163

Cometabolic bioremediation  

E-Print Network (OSTI)

contaminants, e.g. PCE, TCE, MTBE, TNT, dioxane, atrazine,Geobacter, Clavibacter) BTEX, PCE, PAHs, Pyrene, Atrazine,VC, 1,1-DCE, 1,1,1- TCA, MTBE PCE, TCE, DCE, VC, Hexachloro-

Hazen, Terry C.

2010-01-01T23:59:59.000Z

164

Economics of Lifecycle analysis and greenhouse gas regulations  

E-Print Network (OSTI)

namely, the hike in crude oil prices, replacement of MTBE bygrowth in demand. Crude oil import price is expected to

Rajagopal, Deepak

2009-01-01T23:59:59.000Z

165

CRC fuel rating program: road octane performance of oxygenates in 1982 model cars  

SciTech Connect

Because of the widespread interest in the use of alcohols and ethers as gasoline blending components, this program was conducted to evaluate the effects of several oxygenates on gasoline octane performance and to evaluate the effects of car design features such as engine and transmission type. Five oxygenates were evaluated at two nominal concentrations, 5 and 10 volume%, at both regular- and premium-grade octane levels: methanol (MeOH), ethanol (ETOH), isopropanol (IPA), tertiary butanol (TBA), and methyl tertiary butyl ether (MTBE). A blend of 5% MeOH and 5 percent TBA was also tested at both octane levels. Twenty-eight unleaded fuels, including four hydrocarbon fuels, two hydrocarbon fuels plus toluene, and twenty-two oxygenated fuels, were rated in duplicate in thirty-eight cars using the Modified Uniontown Technique (CRC Designation F-28-75 described in Appendix C), plus some additional instructions. All testing was done on chassis dynamometers. Ratings were obtained at full throttle with all thirty-eight cars, and at the most critical part-throttle condition (occurring with manifold vacuum of 4 in. Hg (13.5 kPa) or greater above the full-throttle vacuum) with nine cars.

Not Available

1985-07-01T23:59:59.000Z

166

Direct Determination of Ethyl Glucuronide and Ethyl Sulfate in Postmortem Urine Specimens Using Hydrophilic Interaction Liquid Chromatography-Electrospray Ionization-Tandem Mass Spectrometry  

Science Journals Connector (OSTI)

......presence of ETG and ETS in wine at concentrations of 0.153...ratio in order to ensure the quality of IPs, and the ratio should...other CNS active drugs can increase the risk of intoxication and...causing death where ethanol may increase toxicity as an addi- tive......

Ahmed I. Al-Asmari; Robert A. Anderson; Patrik Appelblad

2010-06-01T23:59:59.000Z

167

Synthesis of ethyl N-carbobenzoxy-L-valyl-L-valyl-4-amino-3-hydroxyoctanoate  

E-Print Network (OSTI)

~~I~H2~mH~~~H~I?H CH2~0H Figure 1. Structure of isovaleryl-L-valyl-L-valyl-(3S, 4S)-statyl-L-alanyl-(3S, 4S)-statine (pepstatin). Table I. Biological Activity of Pepstatin and Analogs 1 compounds I050 (ug/ml ) pepsin cathepsin D renin AHMHA IVA...-Val-Val Ac-Ala-AHMHA Ac-Leu-AHMHA Ac-Val-AHMHA IVA-Val-AHMHA-Val-AHMHA IVA-Val-Val-AHMHA-Ala-AHMHA &250 &250 26 9. 3 2. 4 0. 01 0. 01 &250 &250 280 8. 5 4. 4 0. 05 0. 005 &250 &250 &250 &250 &250 &250 4. 5 a ID50...

Chesky, Elizabeth Gourley

1982-01-01T23:59:59.000Z

168

E-Print Network 3.0 - alcohol ethyl alcohol Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

By The University of Texas at Arlington Police Department... 817-272-3381 Tips for Young Adults: The Truth about Alcohol If you are the victim of a crime on the U... . One...

169

Direct Catalytic Asymmetric Aldol-Type Reaction of Aldehydes with Ethyl  

E-Print Network (OSTI)

high stereocontrol in these processes, considering the requirement of atom efficiency, it would be more of China wangjb@pku.edu.cn Received February 24, 2003 ABSTRACT The direct aldol-type condensation. Because the aldol reaction is generally considered as one of the most powerful and efficient C-C bond

Wang, Jianbo

170

A theoretical analysis of the reaction between ethyl and molecular oxygen  

SciTech Connect

Using a combination of electronic-structure theory, variational transition-state theory, and solutions to the time-dependent master equation, the authors have studied the kinetics of the title reaction theoretically over wide ranges of temperature and pressure. The agreement between theory and experiment is quite good. By comparing the theoretical and experimental results describing the kinetic behavior, they have been able to deduce a value for the C{sub 2}H{sub 5}-O{sub 2} bond energy of {approximately}34 kcal/mole and a value for the exit-channel transition-state energy of {minus}4.3 kcal/mole (measured from reactants). These numbers compare favorably with the electronic-structure theory predictions of 33.9 kcal/mole and {minus}3.0 kcal/mole, respectively. The master-equation solutions show three distinct temperature regimes for the reaction, discussed extensively in the paper. Above T {approx} 700 K, the reaction can be written as an elementary step, C{sub 2}H{sub 5} + O{sub 2} {leftrightarrow} C{sub 2}H{sub 4} + HO{sub 2}, with the rate coefficient, k(T) = 3.19 x 10{sup {minus}17} T{sup 1.02} exp(2035/RT) cm{sup 3}/molec.-sec., independent of pressure even though the intermediate collision complex may suffer a large number of collisions.

James A. Miller; Stephen J. Klippenstein; Stuart H. Robertson

2000-12-13T23:59:59.000Z

171

Hydrogenated soy ethyl ester (HySEE) from ethanol and waste vegetable oil  

SciTech Connect

Biodiesel is gaining recognition in the United States as a renewable fuel which may be used as an alternative to diesel fuel without any modifications to the engine. Currently the cost of this fuel is the factor that limits its use. One way to reduce the cost of biodiesel is to use a less expensive form of vegetable oil such as waste oil from a processing plant. These operations use mainly hydrogenated soybean oil, some tallow and some Canola as their frying oils. It is estimated that there are several million pounds of waste vegetable oil from these operations. Additional waste frying oil is available from smaller processors, off-grade oil seeds and restaurants. This paper reports on developing a process to produce the first 945 liters (250 gallons) of HySEE using recipes developed at the University of Idaho; fuel characterization tests on the HySEE according to the ASAE proposed Engineering Practice for Testing of Fuels from Biological Materials, X552; short term injector coking tests and performance tests in a turbocharged, DI, CI engine; and a 300 hour screening test in a single cylinder, IDI, CI engine.

Peterson, C.; Reece, D.; Thompson, J. [Univ. of Idaho, Moscow, ID (United States)] [and others

1995-11-01T23:59:59.000Z

172

Enrichment, isolation and characterization of fungi tolerant to 1-ethyl-3-methylimidazolium acetate  

E-Print Network (OSTI)

Davis, 95616; Biomass Science and Conversion Technologybiomass is a potential renewable feedstock that is available for conversion

Singer, S.W.

2012-01-01T23:59:59.000Z

173

Inhibitory Effects of Plant-Derived Flavonoids and Phenolic Acids on Malonaldehyde Formation from Ethyl Arachidonate  

Science Journals Connector (OSTI)

The antioxidant activities of the flavones and flavonols decreased in the following order:? luteolin > rhamnetin > fisetin > kaempferol > morin > quercetin. ... It was also reported that caffeic acid is more effective than ferulic acid against lipid peroxyl radicals generated in the lipophilic phase of low-density lipoproteins (LDL) and in protecting LDL cholesterol from oxidation (36). ...

Kwang-Geun Lee; Takayuki Shibamoto; Gary R. Takeoka; Sung-Eun Lee; Jeong-Han Kim; Byeoung-Soo Park

2003-10-22T23:59:59.000Z

174

Low Temperature Autoignition of C8H16O2 Ethyl and Methyl Esters...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

500 600 700 800 900 1000 300 320 340 360 380 400 420 Apparent Heat Release Rate (kJDeg) Bulk Cylinder Gas Temperature (K) CA (Deg) -0.01 0.01 0.03 0.05 0.07 0.09 0.11 50 250 450...

175

SEC data for polymer 1, 2 (R= 2-ethyl-hexyl) and 3  

E-Print Network (OSTI)

performance shown: Solar cells based on copolymers of benzothiadiazole and thiophene Eva Bundgaard a,b and Frederik C. Krebs a a Polymer Solar Cell Initiative, The Danish Polymer Centre, Risø National Laboratory Universitycenter, Universitetsvej 1, PO Box 260, DK-4000 Roskilde, Denmark. IV-curves for the polymer 1 (a) and 3

176

Copper-Catalyzed Addition of Ethyl Diazoacetate to Furans:? An Alternative to Dirhodium(II) Tetraacetate  

Science Journals Connector (OSTI)

A.C. thanks the MCYT and M.M.D.R. thanks the Ramón y Cajal Program for a research fellowship. ... (d) Wenker, E.; Khatuya, H.; Klein, P. S. Tetrahedron Lett. ...

Ana Caballero; M. Mar Díaz-Requejo; Swiatoslaw Trofimenko; Tomás R. Belderrain; Pedro J. Pérez

2005-06-29T23:59:59.000Z

177

Rate of isomerization of triethyl phosphite to diethyl ethylphosphonate in the presence of ethyl iodide  

E-Print Network (OSTI)

Wbnsov. Eswevaz; vms. Attic hIInetie' gate ce'ether'gamest svidenss has been yvesented, to saypaA this view ' 'Xhzss, yspcnrs in selatiwelp ebsscwre gecLcnals~ @~ with tbs Rinetio's, of tbs msaetien, have spys~. Ths finest was bg S~shi mk ' aod M... (gggseeqj g~) esStJe@j. eely, at $~ ~9M gsSttge ecssse54~%hloge, Xzk Cge p&5seaS Qeeey lj&I55 sgSSleetfo@ pe&We" +. oz'@QP se cia~ bg' Qg lgit4sl 4iLe4~isp~w liI? Vis 8?p8pisssatel ~s ezgh ae a. 'yo@ew4@t Z. sstgm ~P L@ %he'fatggel 4o~t eee " es' ~54:. v...

Zerwekh, Ralph Edwin

2012-06-07T23:59:59.000Z

178

E-Print Network 3.0 - arrhizus ethyl esters Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

Rhizopus arrhizus fungal biomass. Biosorption was not considered globally... groups; Sorption capacity; Rhizopus arrhizus fungal biomass 1. Introduction The influential role of...

179

Combustion chemical kinetics of biodiesel and related compounds (methyl and ethyl esters): Experiments and  

E-Print Network (OSTI)

energy resource that has been consumed by the world's population, exceeding natural gas, coal, nuclear a shift toward alternative sources of energy that are renewable, sustainable, efficient, cost Industries Chimiques de Nancy, Laboratoire Réactions et Génie des Procédés, UMR CNRS 7274, 1 rue Grandville

Paris-Sud XI, Université de

180

?9-Tetrahydrocannabinol and Ethyl Alcohol: Evidence for Cross-Tolerance in the Rat  

Science Journals Connector (OSTI)

...332 (1968). 3. R. K. Kubena and H. Barry ill, J. Pharmacol. Exp. Ther. 173, 94 (1970); B. C. Bose, A. W. Saifi, A. W. Bhagwat, Arch. Int. Pharmacodyn. Ther. 141, 520 (1963). 4. H. I. Bicher and R. Mechoulam, Arch. Int...

L. Michael Newman; Michael P. Lutz; Michael H. Gould; Edward F. Domino

1972-03-03T23:59:59.000Z

Note: This page contains sample records for the topic "mtbe ethyl tertiary" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Electronic Structure and Spectroscopic Analysis of 1-Ethyl-3-methylimidazolium Bis(trifluoromethylsulfonyl)imide Ion Pair  

Science Journals Connector (OSTI)

High purity [EMIM+][NTf2–] was obtained as a generous gift by Boulder Ionics. ... Li, G.; Parimal, K.; Vyas, S.; Hadad, C. M.; Flood, A. H.; Glusac, K. D.Pinpointing the Extent of Electronic Delocalization in the Re(I)-to-tetrazine Charge-separated Excited State using Time-resolved Infrared Spectroscopy J. Am. ...

Shubham Vyas; Christopher Dreyer; Jason Slingsby; David Bicknase; Jason M. Porter; C. Mark Maupin

2014-08-01T23:59:59.000Z

182

Two Types of Intramolecular Lewis-Base Adducts with the [2-(Dimethylamino)ethyl]cyclopentadienyl Ligand  

E-Print Network (OSTI)

/or carbide-forming metals are involved.3 We were therefore led to investigate some organonickel com- plexes applied. A dead-time delay of 10 µs and a pulse repetition time of 200 Organo Group 13 Transition Metal ring.1 Jutzi et al. have been studying a number of metal complexes bearing this Lewis base

Bluemel, Janet

183

Directed evolution of phosphotriesterase: towards the efficient detoxification of sarin and soman  

E-Print Network (OSTI)

resulting in an inversion of configuration at the phosphorus center (Lewis et al., 1988). P O O O NO2 H2O -O NO2 O OH O + Scheme 1. The hydrolysis of paraoxon results in p-nitrophenol and diethylphosphate. In terms of tertiary folding, each monomer... in previous studies in which both the substituent size and the binding pocket size were varied (Chen-Goodspeed et al., 2001a,b). The effects of substrates containing either methyl, ethyl, isopropyl, and or phenyl substituents at the phosphorus center were...

Lum, Karin Tien

2004-09-30T23:59:59.000Z

184

The National Energy Modeling System: An Overview 2000 - International  

Gasoline and Diesel Fuel Update (EIA)

international energy module (IEM) consists of four submodules (Figure 4) that perform the following functions: international energy module (IEM) consists of four submodules (Figure 4) that perform the following functions: world oil market submodule—calculates the average annual world oil price (imported refiner acquisition cost) that is consistent with worldwide petroleum demand and supply availability crude oil supply submodule—provides im- ported crude oil supply curves for five crude oil quality classes petroleum products supply submodule—pro- vides imported refined product supply curves for eleven types of refined products oxygenates supply submodule—provides imported oxygenates supply curves for methyl tertiary butyl ether (MTBE) and methanol. Figure 4. International Energy Module Structure The world oil price that is generated by the world oil market submodule is used by all the modules of NEMS as well as the other submodules of IEM. The import supply curves for crude oils, refined products, and oxygenates are used by the petroleum market module.

185

Refinery Stocks of Crude Oil and Petroleum Products  

Gasoline and Diesel Fuel Update (EIA)

Product: Crude Oil and Petroleum Products Crude Oil Petroleum Products Pentanes Plus Liquefied Petroleum Gases Ethane/Ethylene Propane/Propylene Normal Butane/Butylene Isobutane/Isobutylene Oxygenates/Renewables/Other Hydrocarbons Oxygenates (excl. Fuel Ethanol) Methyl Tertiary Butyl Ether (MTBE) All Other Oxygenates Renewable Fuels (incl. Fuel Ethanol) Fuel Ethanol Renewable Diesel Fuel Other Renewable Fuels Other Hydrocarbons Unfinished Oils Naphthas and Lighter Kerosene and Light Gas Oils Heavy Gas Oils Residuum Motor Gasoline Blending Components MGBC - Reformulated MGBC - Reformulated - RBOB MGBC - RBOB for Blending with Alcohol* MGBC - RBOB for Blending with Ether* MGBC - Conventional MGBC - Conventional CBOB MGBC - Conventional GTAB MGBC - Conventional Other Aviation Gasoline Blending Components Finished Motor Gasoline Reformulated Reformulated Blended with Fuel Ethanol Reformulated, Other Conventional Gasoline Conventional Gasoline Blended with Fuel Ethanol Conventional Gasoline Blended with Fuel Ethanol, Ed55 and Lower Conventional Other Gasoline Finished Aviation Gasoline Kerosene-Type Jet Fuel Kerosene Distillate Fuel Oil Distillate Fuel Oil, 15 ppm and Under Distillate Fuel Oil, Greater than 15 ppm to 500 ppm Distillate Fuel Oil, Greater than 500 ppm Residual Fuel Oil Less than 0.31 Percent Sulfur 0.31 to 1.00 Percent Sulfur Greater than 1.00 Percent Sulfur Petrochemical Feedstocks Naphtha for Petrochemical Feedstock Use Other Oils for Petrochemical Feedstock Use Special Naphthas Lubricants Waxes Petroleum Coke Marketable Coke Asphalt and Road Oil Miscellaneous Products Period-Units: Monthly-Thousand Barrels Annual-Thousand Barrels

186

U.S. Blender Net Input  

U.S. Energy Information Administration (EIA) Indexed Site

2007 2008 2009 2010 2011 2012 View 2007 2008 2009 2010 2011 2012 View History Total Input 1,184,435 1,522,193 1,850,204 2,166,784 2,331,109 2,399,318 2005-2012 Natural Gas Plant Liquids and Liquefied Refinery Gases 3,445 5,686 6,538 7,810 10,663 2008-2012 Pentanes Plus 2,012 474 1,808 1,989 2,326 4,164 2005-2012 Liquid Petroleum Gases 2,971 3,878 4,549 5,484 6,499 2008-2012 Normal Butane 2,943 2,971 3,878 4,549 5,484 6,499 2005-2012 Isobutane 2005-2006 Other Liquids 1,518,748 1,844,518 2,160,246 2,323,299 2,388,655 2008-2012 Oxygenates/Renewables 234,047 274,974 286,837 295,004 2009-2012 Methyl Tertiary Butyl Ether (MTBE) 2005-2006 Renewable Fuels (incl. Fuel Ethanol) 234,047 274,974 286,837 295,004 2009-2012 Fuel Ethanol 131,810 182,772 232,677 273,107 281,507 287,433 2005-2012

187

U.S. Blender Net Input  

U.S. Energy Information Administration (EIA) Indexed Site

Apr-13 May-13 Jun-13 Jul-13 Aug-13 Sep-13 View Apr-13 May-13 Jun-13 Jul-13 Aug-13 Sep-13 View History Total Input 206,541 217,867 212,114 216,075 219,783 208,203 2005-2013 Natural Gas Plant Liquids and Liquefied Refinery Gases 891 352 376 196 383 1,397 2008-2013 Pentanes Plus 261 301 313 67 287 393 2005-2013 Liquid Petroleum Gases 630 51 63 129 96 1,004 2008-2013 Normal Butane 630 51 63 129 96 1,004 2005-2013 Isobutane 2005-2006 Other Liquids 205,650 217,515 211,738 215,879 219,400 206,806 2008-2013 Oxygenates/Renewables 25,156 26,576 26,253 26,905 27,788 25,795 2009-2013 Methyl Tertiary Butyl Ether (MTBE) 2005-2006 Renewable Fuels (incl. Fuel Ethanol) 25,156 26,576 26,253 26,905 27,788 25,795 2009-2013 Fuel Ethanol 24,163 25,526 24,804 25,491 25,970 24,116 2005-2013

188

The conversion of natural gas to liquid fuels using the Sasol Slurry Phase Distillate Process  

SciTech Connect

The natural gas and energy industries have long sought an economically attractive means of converting remote gas reserves into transportable products, such as fuels or petrochemicals. Applicable gas sources include: undeveloped gas fields in locations so remote that pipeline construction is prohibitively expensive and associated gas from oil wells that is either flared, which is becoming environmentally unacceptable in many parts of the world, or reinjected, which is costly. Projects which have been developed to exploit such feeds typically have converted the gas into one of the following: (1) liquefied natural gas (LNG)--the process plants for LNG production are expensive, need to be very large to be economically viable, have costly dedicated shipping requirements, and suffer from a limited market concentrated in few countries; (2) methanol--the market for petrochemical feedstock methanol is limited, for use as a fuel, further downstream processing is needed, for example in a methyl tertiary butyl ether (MTBE) or methanol to gasoline (MTG) unit. Clearly, there is a need for an alternative that produces high quality fuels or value added products that can be transported to far-off markets, while yielding an attractive return on the developers` investment. The Sasol Slurry Phase Distillate Process will fulfill this need.

Silverman, R.W. [Raytheon Engineers and Constructors, Cambridge, MA (United States); Hill, C.R. [Sastech, Johannesburg (South Africa)

1997-12-31T23:59:59.000Z

189

Total Crude Oil and Petroleum Products Exports  

U.S. Energy Information Administration (EIA) Indexed Site

Exports Exports Product: Total Crude Oil and Petroleum Products Crude Oil Natural Gas Plant Liquids and Liquefied Refinery Gases Pentanes Plus Liquefied Petroleum Gases Ethane/Ethylene Propane/Propylene Normal Butane/Butylene Isobutane/Isobutylene Other Liquids Hydrogen/Oxygenates/Renewables/Other Hydrocarbons Oxygenates (excl. Fuel Ethanol) Methyl Tertiary Butyl Ether (MTBE) Other Oxygenates Renewable Fuels (incl. Fuel Ethanol) Fuel Ethanol Biomass-Based Diesel Motor Gasoline Blend. Comp. (MGBC) MGBC - Reformulated MGBC - Conventional Aviation Gasoline Blend. Comp. Finished Petroleum Products Finished Motor Gasoline Reformulated Gasoline Conventional Gasoline Finished Aviation Gasoline Kerosene-Type Jet Fuel Kerosene Distillate Fuel Oil Distillate F.O., 15 ppm and under Distillate F.O., Greater than 15 to 500 ppm Distillate F.O., Greater than 500 ppm Residual Fuel Oil Naphtha for Petro. Feed. Use Other Oils Petro. Feed. Use Special Naphthas Lubricants Waxes Petroleum Coke Asphalt and Road Oil Miscellaneous Products Period-Unit: Monthly-Thousand Barrels Monthly-Thousand Barrels per Day Annual-Thousand Barrels Annual-Thousand Barrels per Day

190

NAME/TEAM: ______________________________________ FTIR postlab -1  

E-Print Network (OSTI)

in gasoline v/v % ethanol in vodka v/v % ethanol in mouthwash 2) Based on your results, what is the proof your value % RE 100 lit. value - = � 4) Convert your v/v % MTBE in gasoline to units of mass % (w/w %) of oxygen in gasoline. Density of MTBE = 0.74 g/mL, Density of gasoline = 0.66 g/mL, Molar Mass of MTBE = 88

Nizkorodov, Sergey

191

TERTIARY AND QUATERNARY GEOLOGY OF THE LOWER RIO PUERCO AREA, NEW MEXICO  

Science Journals Connector (OSTI)

...hogbacks east of Lucero Mesa, where resistant...fig. 2). The Chupadera formation may be...backs east of Lucero Mesa, and most of the...Andres member of the Chupadera formation consists...Santa Fe time the Chupadera was exposed in the...the lava-capped mesas and the alluvium...

192

Early Tertiary Age of Pitchstone in the Northern Black Hills, South Dakota  

Science Journals Connector (OSTI)

...the glass is isotropic but has tiny anisotropic particles. Some of these particles are...offossil-iferous Upper Cretaceous Carlile shale. The Carlile is about 1100 m stratigraphi-cally...xiii). Drake supposed that the Carlile shale fragments had been acquired from steep...

JACK A. REDDEN; JOHN D. OBRADOVICH; CHARLES W. NAESER; ROBERT E. ZARTMAN; JAMES J. NORTON

1983-06-10T23:59:59.000Z

193

Micropaleontology and mineralogy of a tertiary sediment core from the Sigsbee knolls, Gulf of Mexico  

E-Print Network (OSTI)

PLATES ~ ~ o ~ a ~ o ~ e e ~ o o a a ~ ~ o ~ 91 LIST OF FIQEES Figure Page 1 Physiographic provinces of the Western Gulf of Mexico showing location of the Sigsbee knolls. . . . . 16 2 Bathymetry of the Sigsbee knolls ~ e o a a e a o ~ o ~ 18 3 X..., size analyses, and water content . 14 2 Distribution of calcareous nannoplankton in core 64& 9 SE e ~ o o e o o o o o ~ o e a a o ~ e o o e ~ ~ 35 3 Interpretation of X-ray diffractogoams ~ . . ~. . . . 50 LIST OF PLATES Plate 1 Ihotognaph of core...

Pyle, Thomas Edward

2012-06-07T23:59:59.000Z

194

Palaeomagnetism and radiometric dating of the British Tertiary Igneous Province: Muck and Eigg  

Science Journals Connector (OSTI)

......Vaternish dyke swarm on North Skye, Scotland, Geophys...sediments on the shore of Camas Mor in Muck and Cretaceous...M O R G A B B R O The Camas Mdr Gabbro was sampled...1 for locations). North Cliffs Cleadale- Laig...lava succession, at the north of Eigg, has an age spectrum......

P. Dagley; A. E. Mussett

1986-04-01T23:59:59.000Z

195

Monitoring Electricity Consumption in the Tertiary Sector- A Project within the Intelligent Energy Europe Program  

E-Print Network (OSTI)

Services and Energydesign, Technical University of Braunschweig, Germany Univ.-Prof. Dr.-Ing. M. Norbert Fisch Head of Institute IGS ? Institute of Building Services and Energydesign, Technical University of Braunschweig, Germany Edelgard Gruber... Competence Centre Energy Policy and Energy Systems, Fraunhofer Institute for Systems and Innovation Research, Karlsruhe, Germany Barbara Schlomann Competence Centre Energy Policy and Energy Systems, Fraunhofer Institute for Systems and Innovation...

Plesser, S.; Fisch, M. N.; Gruber, E.; Schlomann, B.

196

Mineralogy and diagenesis of Gulf Coast Tertiary shales Ann-Mag Field, Brooks County, Texas  

E-Print Network (OSTI)

basins containing sediments of the same age (Bruce, 19S4). Shale dehydration and subsequent fluid movement has also been proposed as a mechanism to redistribute ions and form cements ( Towe, 1962; Boles and pranks, 1979) and authi genic minerals... composition with increasing depth of burial provides evidence of systematic diagenetic conversions (Boles and Franks, 1979; Hower et al. , 1976; Perry and Hower, 1972; Weaver and Beck, 1971; Dunoyer De Segonzac, 1970; Burst, 1969; Powers, 1967). When...

Bott, Winston Frederick

1985-01-01T23:59:59.000Z

197

40Ar/39Ar Age of Cretaceous-Tertiary Boundary Tektites from Haiti  

Science Journals Connector (OSTI)

...90G15K obtained with laser system and for...ultrason-ically in dilute HF (-5%) for removal...size for total-fusion and incremental-heating...We determined laser total fusion 'Ar/ 39Ar ages...mean of the four laser-fusion plateau ages at...

G. A. IZETT; G. B. DALRYMPLE; L. W. SNEE

1991-06-14T23:59:59.000Z

198

The effect of solids retention time on tertiary ozonation and carbon adsorption of petrochemical wastewaters  

E-Print Network (OSTI)

and biochemical oxygen demands were measured before and after ozaontion as well as the amount of ozone consumed. Non-adsorbable COD was measured and a comparison of ozonized and unozonized wastewater made. BOD concentration rose after ozonation, but decreased... of solids retention time on nonadsorbable COD, with and without ozonation. 39 LIST OF TABLES Table Page Biochemical and chemical oxygen demand data. COD removal and ozone consumption data 21 26 iVon-adsorbable COD data for bio-oxidized effluent. . 3O...

Buys, Ronald Earl

2012-06-07T23:59:59.000Z

199

Yoon et al. 1 Research Article: Tertiary Endosymbiosis Driven Genome Evolution in  

E-Print Network (OSTI)

apoprotein; PsbD, photosystem II D2 reaction center protein; PsbO, oxygen-evolving enhancer protein 1 MBE, 2 and Debashish Bhattacharya 1 * 1 Department of Biological Sciences and Roy J. Carver Center, NOAA National Ocean Service, Center for Coastal Environmental Health and Biomolecular Research

Bhattacharya, Debashish

200

Calcareous nannofossils from the uppermost Cretaceous and the lowermost Tertiary of central Texas  

E-Print Network (OSTI)

noflagellates, successively dominate the nanno- fossil assemblage immed1ately above the boundary. The opportunistic of small placolith species, such as Cruci lacolithus sp. cf. C. primus, C ocl la 11th p I, else t p. f. I!. ~di h d T wef s p tat, hl h t lty... yl ld t p dly I I s m I Pal o nannoflora. This boundary succession is nearly ident1cal to the boundary succession documented in detail 1n Spain and 1s most reasonably inter- preted as representing a continuous sect1on because there is no ev1dence...

Jiang, Ming-Jung

2012-06-07T23:59:59.000Z

Note: This page contains sample records for the topic "mtbe ethyl tertiary" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

An investigation into student academic help seeking behaviours in a tertiary institution's learning support centre.  

E-Print Network (OSTI)

??The majority of academic help seeking studies worldwide have predominantly used the quantitative paradigm and have been undertaken in the secondary and primary sector. This… (more)

Protheroe, Mervyn

2009-01-01T23:59:59.000Z

202

Late Tertiary/Quaternary volcanics of southern Costa Rica and northern Panama  

SciTech Connect

The recent tectonic evolution of the Isthmus of Panama is marked by a complexity imparted by a subduction zone - magmatic arc, a transform plate boundary, and the attempted subduction of an aseismic ridge. In northern Panama andesites form the morphologically young Chiriqui stratovolcano, while in southern Costa Rica they are found interbedded with thick lahars. Two groups of andesites occur in the region. One is low in Si and K (Group I); the other high in Si and K (Group II). The Panamanian andesites belong to both the groups, while Costa Rican andesites are restricted to Group II. Group I andesites are glassy, plagioclase-phyric (An45 rims), and contain abundant augite (Wo46En46Fs8) and magnetite. Rare, resorbed olivine (Fo82) and amphibole are occasionally observed. The Group II andesites have similar mineralogy but also contain abundant pargasitic hornblende and minor orthopyroxene or pigeonite. Xenoliths are common in the Group II andesites of Chiriqui Volcano. Two types of xenoliths are recognized. Cumulate-textured, hornblende gabbro xenoliths vary from nearly pure plagioclase to nearly pure amphibole. These gabbroic xenoliths contain plagioclase (An90 cores to An53 rims), augite, and pargasitic hornblende often displaying the same reaction products as found in the andesites. These xenoliths are interpreted as cognate. These andesites are all characterized by high alkalis and alkali earths; Group II have over 1500 ppm Ba and 1000 ppm Sr. They are apparently produced by partial melting of a highly metasomatised mantle followed by high-pressure fractionation dominated by hornblende.

Roy, A.; Byerly, G.R.

1985-01-01T23:59:59.000Z

203

1208 Organometallics1988,7,1208-1213 Copper(I) Alkyls. Synthesis and Characterization of Tertiary  

E-Print Network (OSTI)

-Champaign, Urbana, Illinois 61801 Received December 28. 1986 Alkylation of copper(I1)acetate reflections and 62 variables. Introduction Lithium dialkylcuprates, LiCuR2,are used extensively in organic

Girolami, Gregory S.

204

Application of a moving bed biofilm reactor for tertiary ammonia treatment in high temperature industrial wastewater  

E-Print Network (OSTI)

industrial wastewater Jennifer L. Shore a,b , William S. M'Coy b , Claudia K. Gunsch a , Marc A. Deshusses a 2012 Available online 17 February 2012 Keywords: Moving bed biofilm reactor Industrial wastewater and industrial wastewater. No biotreatment was observed at 45 °C, although effective nitrification was rapidly

205

Palaeobotanical evidence for a June 'impact winter' at the Cretaceous/Tertiary boundary  

Science Journals Connector (OSTI)

... , well preserved palynomorphs, 91% of which are one type of fern spore. Near Teapot Dome, 100 km west of the Dogie Creek site, the fern spike also occurs ... has physical evidence of early fallout from bolide impact. But detailed palaeobotanical analysis of the Teapot Dome section (Fig. 2), which is the only western interior section that preserves ...

Jack A. Wolfe

1991-08-01T23:59:59.000Z

206

Petrophysical and sedimentological evaluation of the Tertiary sandstones of Barua-Motatan, Eastern Zulia  

SciTech Connect

The combined application of conventional well logs such as resistivity, gamma ray, neutron density and sonic, and specialized logs such as acoustic image and analysis of fluid and rotary coring tool samples are excellent means of evaluating reservoir rock quality, fluid saturations, and hole conditions. This paper describes the application of such a technique and presents the results thereof of reservoir characterization as applied to an exploration well PAA-1X in the eastern coast of the Maracaibo Lake, Venezuela. The PAA-1X well was drilled on the flank of a monocline west of Mene Grande fault near the border of Mene Grande field to explore the Misca Formation of Eocene age. Intermediate and Basal Pauji sandstones were not present in PAA-1X well, contrary to our expectations. The similarity of well logs and geological columns with an earlier exploration well, Tom-3X, confirmed this finding. The sandstones are medium to fine grained, with porosities of 5-21% and permeabilities of 0.02-0.8 md. The acoustic image log shows an ovalness of the hole, a characteristic typical of silty and shaly formations. The interpretation with the aforementioned tools indicates that the exploratory well has very few thin productive intervals and is therefore likely to be deemed uneconomic. This is corroborated by the DST of the upper part of the Misoa Formation that produced only water. The study does indicate that this set of tools can be used very effectively in an integrated manner to accurately assess and evaluate prospects.

Carmona, R.; Mederos, S. [Maraven S.A., Caracas (Venezuela)

1996-08-01T23:59:59.000Z

207

E-Print Network 3.0 - african tertiary institution Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

and Medicine 3 GRADUATE STUDY IN AFRICAN AND AFRICAN-AMERICAN STUDIES "...We are where Africa, Summary: GRADUATE STUDY IN AFRICAN AND AFRICAN-AMERICAN STUDIES "...We are where...

208

E-Print Network 3.0 - african tertiary teaching Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

and Medicine 2 GRADUATE STUDY IN AFRICAN AND AFRICAN-AMERICAN STUDIES "...We are where Africa, Summary: :www.ku.eduafs. MeganMcAteeKUUniversityRelations Professor Elizabeth...

209

Late Tertiary paleomagnetic data from Leyte, Philippines: implications for Philippine fault zone motion  

E-Print Network (OSTI)

= 20. 1' (oss ? 6. 6', le ? 29. 9) and a paleomagnetic pole A ? 89. 0" N, P ? 10. 4'E (Ass ? 4. 8', K ? 55. 3). Eight early Neogene sites (3 normal polarity and 5 reversed polarity) give a mean direction D = 23. 2', I = 13. 9' (oss ? 9. 3', k = 36.... 2) and a paleomagnetic pole A = 66. 5'N, 6 = 220. 5'E (Ass ? 7. 1', It = 62. 0). The late Veogene pole is indistinguishable at the 95% confidence level from published Plio-Pleistocene poles from the entire Philippines and the late Miocene pole...

Cole, Jay Timothy

1988-01-01T23:59:59.000Z

210

Hydrogeologic characterization of the cretaceous-tertiary Coastal Plain sequence at the Savannah River Site  

SciTech Connect

Several hydrostratigraphic classification schemes have been devised to describe the hydrogeology at the Savannah River Site SRS. Central to these schemes is the one-to-one fixed relationship between the hydrostratigraphic units and the lithostratigraphic units currently favored for the Site. This fixed relationship has proven difficult to apply in studies of widely separated locations at the Site due to the various facies observed in the updip Coastal Plain sequence. A detailed analysis and synthesis of the geophysical, core, and hydrologic data available from more than 164 deep wells from 23 cluster locations both on the Site and in the surrounding region was conducted to provide the basis for a hydrostratigraphic classification scheme which could be applied to the entire SRS region. As a result, an interim hydrostratigraphic classification was developed that defines the regional hydrogeologic characteristics of the aquifers underlying the Site (Aadland et al., 1990). The hydrostratigraphic code accounts for and accommodates the rapid lateral variation in lithofacies observed in the region, and eliminates all formal'' connection between the hydrostratigraphic nomenclature and the lithostratigraphic nomenclature. The code is robust and can be made as detailed as is needed to characterize the aquifer units and aquifer zones described in Site-specific studies. 15 refs., 2 figs.

Aadland, R.K.

1990-01-01T23:59:59.000Z

211

E-Print Network 3.0 - antiknock ratings Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

etryandgaschromatography-thermal conductivity techniques. A rate law is developed for the removal of MTBE from an aqueous solution in the DMP... reactor. Rate constants are also...

212

Total  

U.S. Energy Information Administration (EIA) Indexed Site

Normal ButaneButylene Other Liquids Oxygenates Fuel Ethanol MTBE Other Oxygenates Biomass-based Diesel Other Renewable Diesel Fuel Other Renewable Fuels Gasoline Blending...

213

Total  

U.S. Energy Information Administration (EIA) Indexed Site

Normal ButaneButylene Other Liquids Oxygenates Fuel Ethanol MTBE Other Oxygenates Biomass-based Diesel Fuel Other Renewable Diesel Fuel Other Renewable Fuels Gasoline Blending...

214

Numerical and experimental studies of ethanol flames and autoignition theory for higher alkanes  

E-Print Network (OSTI)

initiated ignition in methane-propane mixtures”, Combustiontemperature ignition of propane with MTBE as an additive:detonation in ethylene and propane mixtures”, Combustion and

Saxena, Priyank

2007-01-01T23:59:59.000Z

215

Molecular Analysis of Ethyl Methanesulfonate-induced Mutations at the hprt Gene in the Ethyl Methanesulfonate-sensitive Chinese Hamster Cell Line EM-C11 and Its Parental Line CHO9  

Science Journals Connector (OSTI)

...cleophilic centers in the DNA via a SN1 reaction, in which the rate limiting step...selectivity in their alkylation reaction. Since the number of oxygen atoms...67) and follows a mixed SN1/SN2 type reaction. Therefore, EMS also reacts with...

Christel W. Op het Veld; Matgorzata Z. Zdzienicka; Harry Vrieling; Paul H. M. Lohman; and Albert A. van Zeeland

1994-06-01T23:59:59.000Z

216

Experimental and Computational Study of the Kinetics of OH + Pyridine and Its Methyl-and Ethyl-Substituted Derivatives  

E-Print Network (OSTI)

remains somewhat uncertain; however, these compounds have been observed as products of coal combustion5-Substituted Derivatives Laurence Y. Yeung and Matthew J. Elrod* Department of Chemistry, Oberlin College, Oberlin, Ohio in some respects, the authors noted that the lack of knowledge concerning the ion-molecule chemistry

Elrod, Matthew J.

217

Low Temperature Autoignition of C8H16O2 Ethyl and Methyl Esters in a Motored Engine  

Energy.gov (U.S. Department of Energy (DOE))

The alkyl chain of fatty acid esters experience the typical paraffin-like low temperature oxidation sequence; the alkyl chain length of fatty acid esters has a crucial impact on the ignition behavior of fatty acid esters

218

Supporting Information for Stoltz et al. SI 1 Development of (Trimethylsilyl)Ethyl Ester Protected Enolates and  

E-Print Network (OSTI)

cm) obtained from Daicel Chemical Industries, Ltd. Analytical SFC was performed with a Mettler SFC-H, or OB-H) columns (4.6 mm x 25 cm) obtained from Daicel Chemical Industries, Ltd. Analytical chiral GC). TLC was performed using E. Merck silica gel 60 F254 precoated glass plates (0.25 mm) and visualized

Stoltz, Brian M.

219

Interaction of Ethyl Chloride with Amorphous Solid Water Thin Film on Ru(001) and O/Ru(001) Surfaces  

E-Print Network (OSTI)

demonstrated for several molecules beside N2 such as CCl4,7 CD3Cl,8 and CO2.9 EC was chosen for this study coverage, respectively. Compression of preadsorbed 0.3 ML EC molecules into small islands on the surface developed above 20 ASW BL. A reversed TPD peak shift of the trapped EC molecules occurs from its compressed

Asscher, Micha

220

Synthesis and crystal structure studies of ethyl 5-methyl-1, 3-diphenyl-1H-pyrazole-4-carboxylate  

SciTech Connect

The title compound, C{sub 19}H{sub 18}N{sub 2}O{sub 2}, was investigated by single crystal X-ray diffraction method. It crystallizes in monoclinic class under the space group P2{sub 1}/c with cell parameters a= 8.4593(4) Å, b=15.6284(6) Å, c=12.4579(5) Å, ?=90°, ?=98.241(3)°, ?=90° and Z=2. The ethoxycarbonyl group is slightly twisted from the pyrazole ring, and adopts syn-periplanar conformation. The crystal structure is stabilized by intermolecular C-H….O hydrogen bonds, which help in stabilizing the crystal structure.

Chandra,; Babu, E. A. Jithesh; Mahendra, M., E-mail: mahendra@physics.uni-mysore.ac.in [Department of Studies in Physics, Manasagangotri, University of Mysore, Mysore-570006 (India); Srikantamurthy, N.; Umesha, K. B. [Department of Chemistry, Yuvaraja's College, University of Mysore, Mysore-570005 (India)

2014-04-24T23:59:59.000Z

Note: This page contains sample records for the topic "mtbe ethyl tertiary" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

A determination of the heats of combustion of the five-carbon fatty acids and their methyl and ethyl esters  

E-Print Network (OSTI)

'srr Ins~ Ce?c ~c Dl? 30? Tbe bstwLs sodAL 1Need wss ohtwixlsd frccc ths Q?S? Wool? Bar? of ghsnclalPds? Tbs hest ef ~tdocc wss giwRl se g6?QQ shs? kja/g? cocos (weighed in wceccs) er QLg eaL/g? essa (in @sees)? 3 oslorie? 0?wg$840 sbs, +? 'ei ~ r...LLd bs ~aied fer tbs fi~carhc?L aCCLds?ad the baste of vaoorisat4os of tbs ether Lsaee4e ac@de ae4hsated a4 their ~g, xdn4s The bs?te of vsyorhwQ. oe o' ths sands a4 2~ C? wars estiaated ly a?S~ 4R? k", ~? ~4lcsi55, ccsd '~ ~ . -? AIL' %7? Q? ~ +sad...

Gilby, Ralph F

2012-06-07T23:59:59.000Z

222

Critical Reviews in Environmental Science and Technology, 00(0):000000 (2001) 1064-3389/01/$.50  

E-Print Network (OSTI)

-3389/01/$.50 © 2001 by CRC Press LLC The Transport and Fate of Ethanol and BTEX in Groundwater Contaminated by Gasohol water contamination by methyl tert-butyl ether (MTBE) have made policymakers more cognizant of the need). It has been discovered that MTBE is a ubiquitous contaminant in surface and ground waters throughout

Alvarez, Pedro J.

223

AirUCI Summer Training Workshop in Environmental  

E-Print Network (OSTI)

schedule Syllabus Wet Lab: MTBE in gasoline and ethanol in vodka / mouthwash measured by FTIR FTIR Wet Lab: Determination of ethanol and benzene in gasoline by GCMS GCMS Wet Lab: Determination of PAH in cigarette smoke and benzene in gasoline by GC/MS - MTBE in gasoline and ethanol in vodka / mouthwash measured by FTIR

Nizkorodov, Sergey

224

Microsoft Word - BingQuestionOne1004.doc  

Gasoline and Diesel Fuel Update (EIA)

Supply Impacts of an MTBE Ban Supply Impacts of an MTBE Ban September 2002 ii Energy Information Administration/Supply Impacts of An MTBE Ban Contacts This report was prepared by the Office of Oil and Gas of the Energy Information Administration. General questions concerning the report may be directed to Mary J. Hutzler (202/586-2222, mhutzler@eia.doe.gov), Director, Office of Integrated Analysis and Forecasting, or Joanne Shore (202/586-4677, joanne.shore@eia.doe.gov), Team Leader, Petroleum Division. 1 Energy Information Administration/Supply Impacts of An MTBE Ban Supply Impacts of an MTBE Ban On June 17, 2002, Senator Jeff Bingaman, Chairman of the Senate Committee on Energy and Natural Resources, requested (Appendix A) that the Energy Information Administration (EIA) provide analysis of eight factors related to the Senate-passed fuels

225

A Novel Method for Separation and Identification of Sulphur Compounds in Naphtha (30–200°C) and Middle Distillate (200–350°C) Fractions of Lloydminster Heavy Oil by GC/MS  

Science Journals Connector (OSTI)

......5-diethylthiophene thiophene diethyl sulphide tetrahydrothiophene ethyl phenyl sulphide naphthalene...benzothiophene dibenzothiophene methyl tetrahydrothiophene methyl tetrahydrothiopyran dimethyl tetrahydrothiophene ethyl butyl sulphide amyl ethyl......

M.A. Poirier; G.T. Smiley

1984-07-01T23:59:59.000Z

226

Molecular organization in the native state of woody tissue: Studies of tertiary structure using the Raman microprobe solid state 13C NMR and biomimetic tertiary aggregates. Progress report, July 1, 1989--June 30, 1993  

SciTech Connect

We have previously shown that all relatively pure plant and bacterial celluloses are, in their native states, composites of two lattice forms, I{sub {alpha}} and I{sub {beta}}, and that the two forms possess molecular chains in the same conformations but with different hydrogen bonding patterns. In the current period we have demonstrated that in higher plant cell wall matrices, the hemicelluloses are likely to have a regulatory function during the aggregation of cellulose. Different hemicelluloses appear to influence the aggregation in different ways. We have also developed preliminary evidence indicating the hemicelluloses may have a protective function against the action of some cellulolytic enzymes. The specific accomplishments during the current period are detailed. Demonstration that hemicelluloses present during biogenesis can transform bacterial cellulose into a cellulose typical of higher plant celluloses, and that each hemicellulose has a different effect on the pattern of aggregation. Evidence is presented that the hemicelluloses may limit the action of certain cellulolytic enzymes, suggesting that their function may go beyond regulation to include passive resistance to cellulolytic pathogens. Enhancing the potential of the Raman microprobe technique for mapping variability of lignin in the cell wall by identifying the contribution of the different substructures of lignin to the intensity of the key band in the Raman spectrum of lignin. Mapping of the variability of lignin across two cell wall sections. The mappings have convoluted within them both composition and concentration, but they demonstrate the potential of the method and point to the improvements we are now making so as to distinguish between variability of concentration and variability of composition.

Atalla, R.H.

1993-12-31T23:59:59.000Z

227

Dehydration of isobutanol to isobutene in a slurry reactor  

SciTech Connect

The April 1990 Alternative Fuels Proposal to the Department of Energy involved the development of new technology, based on the liquid phase process, for conversion of coal-derived synthesis gas to oxygenated hydrocarbon fuels, fuel additives, and fuel intermediates. The objective of this work was to develop a slurry reactor based process for the dehydration of isobutanol to isobutene. The isobutene can serve as a feedstock for the high octane oxygenated fuel additive methyl tertiary-butyl either (MTBE). Alumina catalysts were investigated because of their wide use as a dehydration catalyst. Four commercially available alumina catalysts (Catapal B, Versal B, Versal GH, and Al-3996R) were evaluated for both activity and selectivity to the branched olefin. All four catalysts demonstrated conversions greater than 80% at 290 C, while conversions of near 100% could be obtained at 330 C. The reaction favors low pressures and moderate to low space velocities. A yield of 0.90 mole isobutene per mole reacted isobutanol or better was obtained at conversions of 60--70% and higher. From 75 to 98% conversion, the four catalysts all provide isobutene yields ranging from 0.92 to 0.94 with the maximum occurring around 90% conversion. At low conversions, the concentration of diisobutyl ether becomes significant while the concentration of linear butenes is essentially a linear function of isobutanol conversion. Doping the catalyst with up to 0.8 wt % potassium showed a modest increase in isobutene selectivity; however, this increase was more than offset by a reduction in activity. Investigations using a mixed alcohols feed (consistent with isobutanol synthesis from syngas) demonstrated a small increase in the C4 iso-olefin selectivity over that observed for a pure isobutanol feed. 55 refs.

Latshaw, B.E.

1994-02-01T23:59:59.000Z

228

GEOLOGY, TAPHONOMY, AND PALEOECOLOGY OF A UNIQUE UPPER CRETACEOUS BONEBED NEAR THE CRETACEOUS-TERTIARY BOUNDARY IN SOUTH DAKOTA  

E-Print Network (OSTI)

remains……………………………..100 Figure 3.36 Fused hadrosaur caudal vertebrae with embedded theropod tooth………………..104 Figure 3.37 Pristine bone compared to one with “sun cracks”…………………………………105 Figure 3.38 Graph comparing number of specimens collected...

DePalma, Robert Anthony

2010-04-27T23:59:59.000Z

229

Tertiary development of heavy oil sands through thermal stimulation in the Wilmington Oil Field, California: A geological perspective  

SciTech Connect

In 1995, a DOE cost share project was initiated to extend thermal recovery in the Tar Zone, Fault Block 11 of the West Wilmington Oil Field, California. The project involved the collection of old oil well data and the construction of a modern digital data base in order to develop a deterministic geological model. The plan was to rigorously define the geology such that horizontal wells could be accurately placed within the sands containing heavy oil to facilitate gravity drainage. A detailed deterministic geological model was constructed using a state of the art 3D mapping and modeling package. Beginning in July, 1995, five observation wells were drilled. Data inconsistencies were revealed when core hole OB2-003 was drilled. It was discovered that the data used to make the maps was corrupted; as a result, the predicted coring point was missed by more than 20'. Significant modifications to the data base were required due to inaccurate subsidence corrections in the original data set. Horizontal wells were then laid out based on the revised data and the geological model was completely reconstructed. Detailed cross sections extracted from the model were use for geosteering. These cross sections proved to be highly accurate and five more wells are now planned for the target sands. This detailed deterministic model will be further refined and combined with our geostatistical mode for geological control in an advanced reservoir simulator. If successful, the thermal stimulation project will be expanded to other fault blocks.

Clarke, D.D. (Department of Oil Properties, Long Beach, CA (United States)); Henry, M.J.; Strehle, R.W. (Dept. of Oil Properties, Long Beach, CA (United States))

1996-01-01T23:59:59.000Z

230

Tertiary development of heavy oil sands through thermal stimulation in the Wilmington Oil Field, California: A geological perspective  

SciTech Connect

In 1995, a DOE cost share project was initiated to extend thermal recovery in the Tar Zone, Fault Block 11 of the West Wilmington Oil Field, California. The project involved the collection of old oil well data and the construction of a modern digital data base in order to develop a deterministic geological model. The plan was to rigorously define the geology such that horizontal wells could be accurately placed within the sands containing heavy oil to facilitate gravity drainage. A detailed deterministic geological model was constructed using a state of the art 3D mapping and modeling package. Beginning in July, 1995, five observation wells were drilled. Data inconsistencies were revealed when core hole OB2-003 was drilled. It was discovered that the data used to make the maps was corrupted; as a result, the predicted coring point was missed by more than 20`. Significant modifications to the data base were required due to inaccurate subsidence corrections in the original data set. Horizontal wells were then laid out based on the revised data and the geological model was completely reconstructed. Detailed cross sections extracted from the model were use for geosteering. These cross sections proved to be highly accurate and five more wells are now planned for the target sands. This detailed deterministic model will be further refined and combined with our geostatistical mode for geological control in an advanced reservoir simulator. If successful, the thermal stimulation project will be expanded to other fault blocks.

Clarke, D.D. [Department of Oil Properties, Long Beach, CA (United States); Henry, M.J.; Strehle, R.W. [Dept. of Oil Properties, Long Beach, CA (United States)

1996-12-31T23:59:59.000Z

231

Outbreak of Pichia anomala Infection in the Pediatric Service of a Tertiary-Care Center in Northern India  

Science Journals Connector (OSTI)

...intensified hospital-wide health education campaign with poster displays, formal lectures...be controlled after a health education campaign to improve hand-washing...Postgraduate Institute of Medical Education and Research, Chandigarh 160012...

A. Chakrabarti; K. Singh; A. Narang; S. Singhi; R. Batra; K. L. N. Rao; P. Ray; S. Gopalan; S. Das; V. Gupta; A. K. Gupta; S. M. Bose; M. M. McNeil

2001-05-01T23:59:59.000Z

232

Healthcare associated bloodstream infections – secular trends of 8 years hospital-wide surveillance in a tertiary care university hospital  

Science Journals Connector (OSTI)

Introduced 1995 in acute care, prospective and systematic BSI surveillance at the University of Geneva hospitals was extended to a hospital-wide survey in 2003. Positive blood culture...

M-N Chraiti; W Zingg; V Sauvan; D Pittet

2011-06-01T23:59:59.000Z

233

P261: Study of hospital associated infections (HAI) at tertiary hospital in India; economic implication for developing countries  

Science Journals Connector (OSTI)

Over 1.4 million people worldwide suffer from HAI at any given time. Hospital wide prevalence of HAI varies from 5....1...]. This study focuses on the economic consequences and social burden of HAI cases in a ter...

S Satpathy; A Chaudhry; SK Gupta; A Kapil

2013-06-01T23:59:59.000Z

234

Volume and accessibility of entrained (solution) methane in deep geopressured reservoirs - tertiary formations of the Texas Gulf Coast. Final report  

SciTech Connect

The objective of this project was to appraise the total volume of in-place methane dissolved in formation waters of deep sandstone reservoirs of the onshore Texas Gulf Coast within the stratigraphic section extending from the base of significant hydrocarbon production (8000 ft)* to the deepest significant sandstone occurrence. The area of investigation is about 50,000 mi/sup 2/. Factors that determine the total methane resource are reservoir bulk volume, porosity, and methane solubility; the latter is controlled by the temperature, pressure, and salinity of formation waters. Regional assessment of the volume and the distribution of potential sandstone reservoirs was made from a data base of 880 electrical well logs, from which a grid of 24 dip cross sections and 4 strike cross sections was constructed. Solution methane content in each of nine formations or divisions of formations was determined for each subdivision. The distribution of solution methane in the Gulf Coast was described on the basis of five reservoir models. Each model was characterized by depositional environment, reservoir continuity, porosity, permeability, and methane solubility.

Gregory, A.R.; Dodge, M.M.; Posey, J.S.; Morton, R.A.

1980-10-01T23:59:59.000Z

235

Tunable Energy Transfer Rates via Control of Primary, Secondary, and Tertiary Structure of a Coiled Coil Peptide Scaffold  

Science Journals Connector (OSTI)

Dale J. Wilger †, Stephanie E. Bettis †, Christopher K. Materese †, Maria Minakova †, Garegin A. Papoian *‡, John M. Papanikolas *†, and Marcey L. Waters *† ... M. Kyle Brennaman, Cavan N. Fleming, Cheryl A. Slate, Scafford A. Serron, Stephanie E. Bettis, Bruce W. Erickson, John M. Papanikolas, and Thomas J. Meyer ... M. Kyle Brennaman, Cavan N. Fleming, Cheryl A. Slate, Scafford A. Serron, Stephanie E. Bettis, Bruce W. Erickson, John M. Papanikolas, and Thomas J. Meyer ...

Dale J. Wilger; Stephanie E. Bettis; Christopher K. Materese; Maria Minakova; Garegin A. Papoian; John M. Papanikolas; Marcey L. Waters

2012-06-08T23:59:59.000Z

236

Proportions of coarse and fine clay across the Cretaceous-Tertiary boundary in Milam, Falls, and Travis Counties, Texas  

E-Print Network (OSTI)

and are of little value. It is concluded that the method proposed in this thesis is capable of detecting small differences between clay sampi es at a = ingle locai ity, but prob. bly cannot be used to correlate samples f'rom one locality to another. i&1tlloagh... making dispersion and I'rac- tionation difficult. The efficiency of the X-ray diffraction t, echniques is also improved when these constituents are removed. As a simplified means of comp:rison, the various procedures performed on each sample...

Smith, John Charles

1966-01-01T23:59:59.000Z

237

A Major Meteorite Impact on the Earth 65 Million Years Ago: Evidence from the Cretaceous-Tertiary Boundary Clay  

Science Journals Connector (OSTI)

...and are normally depleted on the terrestrial...ISOTOPIC COMPOSITION OF URANIUM IN CHONDRITIC METEORITES...GRAZING ANIMALS, HEALTH PHYSICS 30 : 345...and are normally depleted on the terrestrial...since Pd is not depleted to the same extent...elements such as uranium in certain meteorites...

R. GANAPATHY

1980-08-22T23:59:59.000Z

238

Fistulotomy in the Tertiary Setting can Achieve High Rates of Fistula Cure with an Acceptable Risk of Deterioration in Continence  

Science Journals Connector (OSTI)

Surgery is the mainstay of treatment of anal fistulas. Low fistulas are often laid open, but higher fistulas present a more difficult problem. Patient choice centres on a compromise between risk of recurrence ...

P. Tozer; S. Sala; V. Cianci; K. Kalmar; G. K. Atkin…

2013-11-01T23:59:59.000Z

239

Stratigraphic and structural analysis of Shannon Sandstone, Teapot Dome field: implications for secondary and tertiary oil recovery  

SciTech Connect

The Department of Energy and Lawrence-Allison Associates have initiated three enhanced oil recovery (EOR) pilot projects in the last 4 years in the Shannon Sandstone at the Teapot Dome field. Performance of these pilot projects has generally been poor. As a result, a reevaluation of the geology for the entire field and for the pilot areas was conducted in an attempt to explain the pilots' performances. Based on core descriptions, conceptual reservoir flow patterns, and post-fireflood coring, only the bar-margin facies was found amenable to fluid displacement processes for oil recovery. This results in 25 million bbl of oil originally in place vs 180 million bbl of oil originally in place as a target for EOR. Stratigraphy alone does not explain the observed production patterns and simulation of the reservoir. Faulting and fracturing are extensive. Based on faults mapped in the in-situ pilot area, 12 to 16 northeast-trending normal faults per mile can be projected. Fracture orientations were obtained by mapping calcareous streaks in the upper and lower Shannon. These orientations confirm directions of premature fluid breakthroughs observed in the pilot projects and in the old East Teapot waterflood. Water resistivities and total dissolved solids measurements, water-cut maps, and daily oil production maps suggest that some faults are partial to total barriers to fluid flow across the field.

Chappelle, H.; Emsurak, G.; Obernyer, S.

1986-08-01T23:59:59.000Z

240

Reconstruction of Tertiary Metasequoia forests. II. Structure, biomass, and productivity of Eocene floodplain forests in the Canadian Arctic  

Science Journals Connector (OSTI)

...estimates of fossil biomass and productivity...Metasequoia had higher wood density than...branchwood and foliar biomass we relied on...closed-canopy plantations. This is a standard...Metasequoia had higher wood density than...branchwood and foliar biomass we relied on...closed-cano-py plantations. This is a standard...

Christopher J. Williams; Arthur H. Johnson; Ben A. LePage; David R. Vann; Tatsuo Sweda

Note: This page contains sample records for the topic "mtbe ethyl tertiary" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Reconstruction of Tertiary Metasequoia forests. I. Test of a method for biomass determination based on stem dimensions  

Science Journals Connector (OSTI)

...crown in the Tanashi plantation. We developed branch...for foliage and branch wood of canopy branches cut from a variety of plantation-grown Metasequoia...the standard for forest biomass calculations (Sprugel...to analysis. Branch wood and foliage dry weights...

Christopher J. Williams; Arthur H. Johnson; Ben A. LePage; David R. Vann; Karen D. Taylor

242

Measurement of Trihalomethanes and Methyl Tertiary-Butyl Ether in Tap Water Using Solid-Phase Microextraction GC-MS  

Science Journals Connector (OSTI)

......ductive age living in Corpus Christi, Texas and Cobb...micro extraction with gas chromatography-mass...determinations using gas chromatog- raphy...of fulvic acids in natural waters. Env. Sci...trihalomethane by headspace-gas chromatog- raphy......

Frederick L. Cardinali; David L. Ashley; John C. Morrow; Deborah M. Moll; Benjamin C. Blount

2004-04-01T23:59:59.000Z

243

Annual Energy Outlook 2005-Acronyms  

Gasoline and Diesel Fuel Update (EIA)

AD AD Associated-dissolved (natural gas) AEO2004 Annual Energy Outlook 2004 AEO2005 Annual Energy Outlook 2005 Altos Altos Partners AMT Alternative Minimum Tax ANWR Arctic National Wildlife Refuge Btu British thermal unit CAFE Corporate average fuel economy CAMR Clean Air Mercury Rule CARB California Air Resources Board CBECS Commercial Buildings Energy Consumption Survey (EIA) CBO Congressional Budget Office CCCC Climate Change Credit Corporation CH 4 Methane CHP Combined heat and power CO 2 Carbon dioxide CTL Coal-to-liquids DB Deutsche Bank, A.G. E85 Fuel containing a blend of 70 to 85 percent ethanol and 30 to 15 percent gasoline by volume EEA Energy and Environmental Analysis, Inc. EIA Energy Information Administration EPA U.S. Environmental Protection Agency EPACT Energy Policy Act of 1992 ETBE Ethyl tertiary butyl ether EVA Energy Ventures Analysis, Incorporated FERC

244

Annual Energy Outlook 2000 - Acronyms  

Gasoline and Diesel Fuel Update (EIA)

Homepage Homepage ACEEE American Council for an Energy-Efficient Economy AD Associated-dissolved (natural gas) AEO Annual Energy Outlook AGA American Gas Association ANWR Arctic National Wildlife Refuge API American Petroleum Institute BRP Blue Ribbon Panel Btu British thermal unit CAAA90 Clean Air Act Amendments of 1990 CARB California Air Resources Board CCAP Climate Change Action Plan CDM Clean Development Mechanism CECA Comprehensive Electricity Competition Act CIDI Compression ignition direct injection CO Carbon monoxide DBAB Deutsche Banc Alex. Brown DOE U.S. Department of Energy DRI Standard & PoorÂ’s DRI EIA Energy Information Administration EOR Enhanced oil recovery EPA U.S. Environmental Protection Agency EPACT Energy Policy Act of 1992 ETBE Ethyl tertiary butyl ether

245

Annual Energy Outlook 1999 - Acronyms  

Gasoline and Diesel Fuel Update (EIA)

acronyms.gif (3491 bytes) acronyms.gif (3491 bytes) AD - Associated/dissolved natural gas AEO98 - Annual Energy Outlook 1998 AEO99 - Annual Energy Outlook 1999 AFVs - Alternative-fuel vehicles AGA - American Gas Association API - American Petroleum Institute BTAB - BT Alex Brown CAAA90 - Clean Air Act Amendments of 1990 CCAP - Climate Change Action Plan CDM - Clean Development Mechanism CFCs - Chlorofluorocarbons CNG - Compressed natural gas CO - Carbon monoxide CO2 - Carbon dioxide DOE - U.S. Department of Energy DRI - DRI/McGraw-Hill EIA - Energy Information Administration EOR - Enhanced oil recovery EPA - U.S. Environmental Protection Agency EPACT - Energy Policy Act of 1992 ETBE - Ethyl tertiary butyl ether EU - European Union FERC - Federal Energy Regulatory Commission GDP - Gross domestic product

246

Risindialogue Risindialogue  

E-Print Network (OSTI)

- based substances such as MTBE. There is a large global market for new technologies which may result systems which are suitable for the production of bioenergy and biomaterials, and which can at the same

247

Life-Cycle Water Impacts of U.S. Transportation Fuels  

E-Print Network (OSTI)

Generation Requirements. DOE/NETL-400/2008/1339; NationalGeneration Requirements. DOE/NETL-400/2008/1339; NationalMTBE MWD MWDOC NAICS NERC NETL NOAA NPCC NREL PADD PDI ppm

Scown, Corinne Donahue

2010-01-01T23:59:59.000Z

248

Saving Energy and Reducing Emissions from the Regeneration Air System of a Butane Dehydrogenation Plant  

E-Print Network (OSTI)

Texas Petrochemicals operates a butane dehydrogenation unit producing MTBE for reformulated gasoline that was originally constructed when energy was cheap and prior to environmental regulation. The process exhausts 900,000 pounds per hour of air...

John, T. P.

249

E-Print Network 3.0 - alcohol tba biodegradation Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

biodegradation. Inoculum size 0.3 g50 mL 0 20 40 60 80 100... in liquid phase, capture 14CO2. 12;Biodegradation of MTBE in Soil Columns Setup: Height: 47 cm ID: 4 Source:...

250

Cumene by catalytic distillation  

SciTech Connect

Catalytic distillation, a combination of catalytic reaction and distillation in a single column, has several advantages when used in a process to make cumene from benzene and propylene. An extremely high purity cumene is obtained in high yield. The catalytic distillation principle was used in an earlier process to make MTBE. A unit, started up up in Houston refinery in 1981, operated successfully for four years. Since then, three other MTBE units of this design have gone into service.

Shoemaker, J.D.; Jones, E.M. Jr.

1987-06-01T23:59:59.000Z

251

Pilot-Scale Production of Fatty Acid Ethyl Esters by an Engineered Escherichia coli Strain Harboring the p(Microdiesel) Plasmid  

Science Journals Connector (OSTI)

...Bey, Alexandria, Egypt. Alexander Steinbuchel...produce FAEEs by its natural metabolism, and it...because of its low price; glycerol of sufficient...analyzed by TLC, gas chromatography (GC...cells, as analyzed by gas chromatography (data...shown). Analyses by gas chromatography (GC...

Yasser Elbahloul; Alexander Steinbüchel

2010-05-07T23:59:59.000Z

252

Pilot-Scale Production of Fatty Acid Ethyl Esters by an Engineered Escherichia coli Strain Harboring the p(Microdiesel) Plasmid  

Science Journals Connector (OSTI)

...and is even available from renewable sources as a byproduct of microbial...and could contribute to the energy market as a substitute for...engineered E. coli strain on renewable substrates such as hemicelluloses...56-81-5 Glycerol | Bioelectric Energy Sources Biomass Biotechnology...

Yasser Elbahloul; Alexander Steinbüchel

2010-05-07T23:59:59.000Z

253

Simultaneous Speciation of Butyl-, Phenyl-, and Cyclohexyltin Compounds in Aqueous Matrices Using Ethylation Followed by Solid-Phase Trace Enrichment, SFE, and GC Determination  

Science Journals Connector (OSTI)

......TCyT), and their degradation products (1,2...the extraction cell had an internal volume...respectively. Flows of fuel gases were 120 mL...into the extraction cell, which contained...butyltin and its degradation products from seawater......

Yong Cai; Josep M. Bayona

1995-03-01T23:59:59.000Z

254

(+)-2-(1-Hydroxyl-4-Oxocyclohexyl) Ethyl Caffeate Suppresses Solar UV-Induced Skin Carcinogenesis by Targeting PI3K, ERK1/2, and p38  

Science Journals Connector (OSTI)

...University of Science Technology, Shanghai...activated by solar ultraviolet...of JB6 Cl41 cells without toxicity...mouse epidermal cells. The inhibition...vivo model of solar UV-induced...purchased from Cell Signaling Technology. The antibody...

Do Young Lim; Mee-Hyun Lee; Seung Ho Shin; Hanyoung Chen; Joohyun Ryu; Lei Shan; Honglin Li; Ann M. Bode; Wei-Dong Zhang; and Zigang Dong

2014-08-01T23:59:59.000Z

255

Investigation of Pulsed Electric Field (PEF) as an Intensification Pretreatment for Solvent Lipid Extraction from Microalgae, utilizing Ethyl Acetate as a Greener Substitute to Chloroform-based Extraction  

E-Print Network (OSTI)

. Moreover, the novel utilization of Pulsed Electric Field (PEF) as a membrane permeating technique for intensification of the lipid extraction is analyzed. When compared to inherently toxic chloroform-based solvent (Bligh & Dyer method), this work...

Antezana Zbinden, Mauricio Daniel R.

2011-02-16T23:59:59.000Z

256

Determination of Total Biodiesel Fatty Acid Methyl, Ethyl Esters, and Hydrocarbon Types in Diesel Fuels by Supercritical Fluid Chromatography-Flame Ionization Detection  

Science Journals Connector (OSTI)

......Research and Engineering, Paulsboro...determining total biodiesel methyl and...in diesel fuels by supercritical...mixture. Introduction The proposed use of biodiesel esters derived...as diesel fuel blending...of Total Biodiesel Fatty Acid...in Diesel Fuels by Supercritical...Research and Engineering, Paulsboro......

John W. Diehl; Frank P. DiSanzo

257

Metabolic Engineering of the Regulators in Nitrogen Catabolite Repression To Reduce the Production of Ethyl Carbamate in a Model Rice Wine System  

Science Journals Connector (OSTI)

...03602531003611915 . 7. Cadranel, JF , C Legendre, B Desaint, N Delamarre, C Florent and VG Levy. 1993. Liver disease from surreptitious administration of urethane. J. Clin. Gastroenterol. 17 :52-56. doi: 10.1097/00004836-199307000-00015...

Xinrui Zhao; Huijun Zou; Jianwei Fu; Jingwen Zhou; Guocheng Du; Jian Chen

2013-11-01T23:59:59.000Z

258

Experimental investigations of the performance, emission and combustion characteristics of a biodiesel (ethyl ester of fish oil) fuelled direct-injection diesel engine  

Science Journals Connector (OSTI)

The thirst for fuel is steadily increasing as technology continues to open new areas of exploration. At the same time, the indiscriminate extraction of fossil fuels may also result in pollutant emissions which cause major impacts on ecological systems. In order to overcome the above problems, a suitable biodiesel should be used to replace the diesel fuel. Hence, in this work, feasibility of using biodiesel prepared from fish oil was investigated. Experimental tests were carried out to evaluate the performance, emission and combustion characteristics of a single cylinder, constant speed engine using several blends under variable load conditions. It was found that NOx, HC and CO emission was reduced for blends along with a marginal increase of brake thermal efficiency and smoke. The ignition delay and maximum heat release rate were reduced compared to diesel. Ultimately, fish oil can indeed become the appropriate source for biodiesel with environmental benefits.

G. Sakthivel; G. Nagarajan; M. Ilangkumaran

2013-01-01T23:59:59.000Z

259

Influence of Neighboring Base Sequence on the Distribution and Repair of N-Ethyl-N-nitrosourea-induced Lesions in Escherichia coli  

Science Journals Connector (OSTI)

...total mutation. REFERENCES 1. Burns. P. A.. Gordon, A. J...194: 385-390, 1987. 2. Burns, P. A.. Allen, F. F...Smith, A. J. H., and Roe, B. A. Cloning in single-stranded...10. Gordon, A. J. E., Burns. P. A.. Fix, D. F...

Philip A. Burns; Alasdair J. E. Gordon; Kathy Kunsmann; and Barry W. Glickman

1988-08-15T23:59:59.000Z

260

Determination of Total Biodiesel Fatty Acid Methyl, Ethyl Esters, and Hydrocarbon Types in Diesel Fuels by Supercritical Fluid Chromatography-Flame Ionization Detection  

Science Journals Connector (OSTI)

......Determination of Total Biodiesel Fatty Acid Methyl...vortex mixer. This process produced solutions ranging...D5186 indicated that the biodiesel esters were not eluted...0%. For further evaluation, the quantitative analysis...determination of the biodiesel ester components by......

John W. Diehl; Frank P. DiSanzo

Note: This page contains sample records for the topic "mtbe ethyl tertiary" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

IMPACT OF OXYGENATED FUEL ON DIESEL ENGINE PERFORMANCE AND EMISSIONS  

SciTech Connect

As evidenced by recent lawsuits brought against operators of large diesel truck fleets [1] and by the Consent Decree brought against the heavy-duty diesel manufacturers [2], the environmental and health effects of diesel engine emissions continue to be a significant concern. Reduction of diesel engine emissions has traditionally been achieved through a combination of fuel system, combustion chamber, and engine control modifications [3]. Catalytic aftertreatment has become common on modern diesel vehicles, with the predominant device being the diesel oxidation catalytic converter [3]. To enable advanced after-treatment devices and to directly reduce emissions, significant recent interest has focused on reformulation of diesel fuel, particularly the reduction of sulfur content. The EPA has man-dated that diesel fuel will have only 15 ppm sulfur content by 2007, with current diesel specifications requiring around 300 ppm [4]. Reduction of sulfur will permit sulfur-sensitive aftertreatment devices, continuously regenerating particulate traps, NOx control catalysts, and plasma assisted catalysts to be implemented on diesel vehicles [4]. Another method of reformulating diesel fuel to reduce emissions is to incorporate oxygen in the fuel, as was done in the reformulation of gasoline. The use of methyl tertiary butyl ether (MTBE) in reformulated gasoline has resulted in contamination of water resources across the country [5]. Nonetheless, by relying on the lessons learned from MTBE, oxygenation of diesel fuel may be accomplished without compromising water quality. Oxygenation of diesel fuel offers the possibility of reducing particulate matter emissions significantly, even for the current fleet of diesel vehicles. The mechanism by which oxygen content leads to particulate matter reductions is still under debate, but recent evidence shows clearly that ''smokeless'' engine operation is possible when the oxygen content of diesel fuel reaches roughly 38% by weight [6]. The potential improvements in energy efficiency within the transportation section, particularly in sport utility vehicles and light-duty trucks, that can be provided by deployment of diesel engines in passenger cars and trucks is a strong incentive to develop cleaner burning diesel engines and cleaner burning fuels for diesel engines. Thus, serious consideration of oxygenated diesel fuels is of significant practical interest and value to society. In the present work, a diesel fuel reformulating agent, CETANERTM, has been examined in a popular light-medium duty turbodiesel engine over a range of blending ratios. This additive is a mixture of glycol ethers and can be produced from dimethyl ether, which itself can be manufactured from synthesis gas using Air Products' Liquid Phase Dimethyl Ether (LPDME TM) technology. CETANERTM is a liquid, has an oxygen content of 36 wt.%, has a cetane number over 100 and is highly miscible in diesel fuel. This combination of physical and chemical properties makes CETANERTM an attractive agent for oxygenating diesel fuel. The present study considered CETANERTM ratios from 0 to 40 wt.% in a California Air Resources Board (CARB) specification diesel fuel. Particulate matter emissions, gaseous emissions and in-cylinder pressure traces were monitored over the AVL 8-Mode engine test protocol [7]. This paper presents the results from these measurements and discusses the implications of using high cetane number oxygenates in diesel fuel reformulation.

Boehman, Andre L.

2000-08-20T23:59:59.000Z

262

DEPARTMENTS:  

Science Journals Connector (OSTI)

......Ethane Ethyl Acetylene Ethyl Chloride Ethyl Fluoride Ethylene Ethylene Oxide Fluorine Halocarbon- 11, 12, 13, 13B1, 14...compounds, the molecular weight, the catalog number and price. Listed for most items are the struc- tural formula......

New Products

1969-09-01T23:59:59.000Z

263

Total Crude Oil and Petroleum Products Imports by Area of Entry  

U.S. Energy Information Administration (EIA) Indexed Site

by Area of Entry by Area of Entry Product: Total Crude Oil and Petroleum Products Crude Oil Natural Gas Plant Liquids and Liquefied Refinery Gases Pentanes Plus Liquefied Petroleum Gases Ethane Ethylene Propane Propylene Normal Butane Butylene Isobutane Isobutylene Other Liquids Hydrogen/Oxygenates/Renewables/Other Hydrocarbons Oxygenates (excl. Fuel Ethanol) Methyl Tertiary Butyl Ether (MTBE) Other Oxygenates Renewable Fuels (incl. Fuel Ethanol) Fuel Ethanol Biomass-Based Diesel Fuel Other Renewable Diesel Fuel Other Renewable Fuels Other Hydrocarbons Unfinished Oils Naphthas and Lighter Kerosene and Light Gas Oils Heavy Gas Oils Residuum Motor Gasoline Blending Components (MGBC) MGBC - Reformulated, RBOB MGBC - Conventional MGBC - Conventional, CBOB MGBC - Conventional, GTAB MGBC - Other Conventional Aviation Gasoline Blending Components Finished Petroleum Products Finished Motor Gasoline Reformulated Gasoline Reformulated Blended w/ Fuel Ethanol Conventional Gasoline Conventional Blended w/ Fuel Ethanol Conventional Blended w/ Fuel Ethanol, Ed55 and Lower Conventional Other Finished Aviation Gasoline Kerosene-Type Jet Fuel Kerosene-Type Bonded Aircraft Fuel Other Bonded Aircraft Fuel Kerosene Distillate Fuel Oil Distillate F.O., 15 ppm and under Distillate F.O., Bonded, 15 ppm and under Distillate F.O., Other, 15 ppm and under Distillate F.O., Greater than 15 to 500 ppm Distillate F.O., Bonded, Greater than 15 to 500 ppm Distillate F.O., Other, Greater than 15 to 500 ppm Distillate F.O., Greater than 500 ppm Distillate F.O., Greater than 500 to 2000 ppm Distillate F.O., Bonded, Greater than 500 to 2000 ppm Distillate F.O., Other, Greater than 500 ppm to 2000 ppm Distillate F.O., Greater than 2000 ppm Distillate F.O., Bonded, Greater than 2000 ppm Distillate F.O., Other, Greater than 2000 ppm Residual Fuel Oil Residual F.O., Bonded Ship Bunkers, Less than 0.31% Sulfur Residual F.O., Bonded Ship Bunkers, 0.31 to 1.00% Sulfur Residual F.O., Bonded Ship Bunkers, Greater than 1.00% Sulfur Petrochemical Feedstocks Naphtha for Petrochem. Feed. Use Other Oils for Petrochem Feed. Use Special Naphthas Lubricants Waxes Petroleum Coke Asphalt and Road Oil Miscellaneous Products Period-Unit: Monthly-Thousand Barrels Monthly-Thousand Barrels per Day Annual-Thousand Barrels Annual-Thousand Barrels per Day

264

Tertiary Volcanic Rocks, Mogollon-Datil Province, New Mexico, and Surrounding Region: K-Ar Dates, Patterns of Eruption, and Periods of Mineralization  

Science Journals Connector (OSTI)

...poor run. Intrudes Spears and Hells Mesa Formations (nos. 2, 3, 4, 5...Correlation uncertain Caps Hells Mesa and younger rocks in type section...Los Pi os Mountains, and North Chupadera Mesa, Valencia, Torrance, and Socorro...

265

The Effect of the Di-Tertiary Butyl Peroxide (DTBP) additive on HCCI Combustion of Fuel Blends of Ethanol and Diethyl Ether  

E-Print Network (OSTI)

Ignition Using Isooctane, Ethanol and Natural Gas - AModel for High Temperature Ethanol Oxidation," Internationalof Bio-Derived Carbon from Ethanol-in-Diesel Blends in the

Mack, John Hunter; Buchholz, Bruce A; Flowers, Daniel L; Dibble, Robert W

2005-01-01T23:59:59.000Z

266

Southern Cordilleran Basaltic Andesite suite, southern Chihuahua, Mexico: A link between Tertiary continental arc and flood basalt magmatism in the North America  

SciTech Connect

Mid-Cenozoic orogenic andesites and ignimbrites of western Mexico, southwestern New Mexico, and Arizona are commonly capped by basaltic andesites, most from 29--20 Ma. We refer to these mafic lavas as the Southern Cordilleran Basaltic Andesite (SCORBA) suite, and they may constitute the most extensive Cenozoic basaltic suite in North America. The SCORBA suite has trace element and isotopic characteristics of orogenic (arc) rocks (i.g., Ba/Nb/gt/40), and silica content (53--56% SiO/sub 2/) like the Grande Ronde Basalt, which represents about 80% of the volume of the Columbia River Group. Geochemical and isotopic data are presented on SCORBA lavas and rare mafic lavas (PRE-SCORBA) interlayered with older ignimbrites from a 700-km-long NE-SW transect of southern Chihuahua, Mexico. SCORBA and PRE-SCORBA lavas with relatively low K/P (/lt/7) and differing Ba/Nd (50 versus 18) have similar isotopic compositions, arguing against their isotopic signatures being controlled by crustal assimilation. Along the entire length of the transect, the basaltic rocks have /var epsilon//sub Nd/ and /sup 87/Sr//sup 86/Sr near bulk Earth and /sup 206/Pb//sup 204/Pb and /sup 207/Pb//sup 204/Pb ratios that lie along a 1.7 Ga pseudoisochron. The Pb isotopic variation is geographically controlled, becoming more radiogenic from east to west, reflecting mixing in mantle source regions. The eastern mantle source has low/sup 206/Pb//sup 204/Pb and is a mixture of an enriched, enriched-mantle-like (EMI) component with one or more depleted components, which could include an intraplate component with relatively high Nb/Y (/gt/0.8).

Cameron, K. L.; Nimz, G. J.; Kuentz, D.; Niemeyer, S.; Gunn, S.

1989-06-10T23:59:59.000Z

267

Comparison of maternal and neonatal outcome before and after the availability of a rapid assay for fetal fibronectin at a tertiary level maternity hospital  

E-Print Network (OSTI)

in decisions to admit to hospital for preterm labor. Clinlabour at Middlemore Hospital, New Zealand. Pathology, 37, (negative predictive value for hospital admission after fetal

Poeltler, Debra Ann Milbert

2010-01-01T23:59:59.000Z

268

Investigating Returns to Investments in Education: An Empirical Study Estimating Returns to Primary, Secondary and Tertiary Education for Countries at Different Levels of Economic Development  

E-Print Network (OSTI)

refer to where in education governments should invest in order to obtain the highest returns, based on the specific characteristics of their countries (i.e. level of economic development). The purpose of this dissertation is to estimate and determine...

Lozano, Ricardo Viviano

2012-07-16T23:59:59.000Z

269

Advances in mass storage technology are producing devices capable of holding terabytes of data. These new devices, often called tertiary storage devices, have dramatically different performance  

E-Print Network (OSTI)

-overwrite technique for managing storage. This technique allows the user to see the entire history of the database of the database at any moment in history. This capability is referred to as time travel. Since only the start time characteristics than magnetic disks. Conventional database systems include explicit dependen- cies on magnetic

California at Irvine, University of

270

Study of the kinetics of the gas-phase, iodine catalyzed elimination of HBr from isobutylbromide: the tertiary C-H bond dissociation energy in isobutylbromide.  

E-Print Network (OSTI)

, (with the possible exception of the very electronegative F atom) unless the substituent can delocalize the odd electron such as with the vinyI substituent, i. e. the allyl radical. The stabi'Iization energy is defined as the difference between... of formation of the radical. f s indicated in section (II); the stabilization energy of bromine bridged radical by the delocalization of tne odd electron can be obtained by comparisior, with a localized free radical. Thus, the stabi11zat1on energy...

Jirustithipong, Pongsiri

2012-06-07T23:59:59.000Z

271

Occurrence of Tertiary Lymphoid Tissue Is Associated with T-Cell Infiltration and Predicts Better Prognosis in Early-Stage Colorectal Cancers  

Science Journals Connector (OSTI)

...obtained from the Institutional Intranet; please refer to Supplementary...data from the institutional intranet (Supplementary Table S1...and CD3+ TILs, baseline characteristics and tumor features of patient...the patient histopathologic characteristics are described in Supplementary...

Giuseppe Di Caro; Francesca Bergomas; Fabio Grizzi; Andrea Doni; Paolo Bianchi; Alberto Malesci; Luigi Laghi; Paola Allavena; Alberto Mantovani; and Federica Marchesi

2014-04-15T23:59:59.000Z

272

Occurrence of female genital tuberculosis among infertile women: a study from a tertiary maternal health care research centre in South India  

Science Journals Connector (OSTI)

The purpose of this investigation was to estimate the proportion of female genital tuberculosis (FGTB) among infertile women, along with the mean cost of diagnosis by different methods. The study was carried o...

V. Bhanothu; J. P. Theophilus; P. K. Reddy…

2014-11-01T23:59:59.000Z

273

Use of ethers as high-octane components of gasolines  

SciTech Connect

This article reports on a study of the possible utilization of methyl tert-amyl ether (MTAE) as an automotive gasoline component, both by itself and in combination with methyl tert-butyl ether (MTBE). The naphtha used in these studies consisted of 80% reformer naphtha produced under severe conditions and 20% straight-run IBP-62/sup 0/C cut. The physicochemical properties of the MTAE, the MTBE, and the naphtha base stock are given. It is determined that MTAE, which has a slightly poorer knock resistance than MTBE, is fully equal to MTBE in all other respects and can be used as an automotive gasoline component; that a gasoline blend prepared from 89% naphtha base stock, 5.5% MTAE, and 5.5% MTBE meets all of the requirements of the standard GOST 2084-77 for Grade AI-93 gasoline; and that the use of MTAE offers a means for expanding the resources of high-octane components, lowering the toxicity of the gasolines and the exhaust gas (in comparison with organometallic antiknock agents), and bringing non-petroleum raw materials into the fuel production picture.

Gureev, A.A.; Baranova, G.N.; Korotkov, I.V.; Levinson, G.I.

1984-01-01T23:59:59.000Z

274

High octane ethers from synthesis gas-derived alcohols. Quarterly technical progress report, April--June 1993  

SciTech Connect

The results shown in Figures 10 and 11 demonstrate that the formation of butenes was very sensitive to the alcohol partial pressure. A small elevation of the alcohol pressure suppressed the formation of butenes rather drastically at both 90 and 117{degree}C. The synthesis rates of DME, MIBE, and MTBE ethers were not significantly affected at 90{degree}C, although there was a trend to increase the space time yield of DME as the alcohol pressure was increased. At the reaction temperature of 117{degree}C, all of the ethers showed increasing productivities as the pressure of the reactants was increased (Figure 11). An isotope labelling experiment was carried out to provide mechanistic insight into the manner in which methanol and isobutanol react together to form DME, MIBE, and MTBE ethers and to determine if MTBE were derived from MIBE.

Klier, K.; Herman, R.G.; Menszak, J.; Johansson, M.A.; Feeley, O.C.; Kim, D.

1993-07-01T23:59:59.000Z

275

Production of methyl tert-alkyl ethers  

SciTech Connect

The transition to the use of unleaded gasolines has required the replacement of tetraethyl lead by oxygen-containing compounds such as methanol, ethanol, and ethers, which are termed {open_quotes}oxygenates{close_quotes} in the technical literature. These may be used in commercial gasolines in amounts of 10-15% by volume, equivalent to 2% oxygen by weight. When methyl tert-butyl ether (MTBE) is used, the oxygen content may amount to 2.7% by weight. This oxygenate gives a significant improvement of knock resistance of naphtha fractions, the greatest effects being observed for straight-run naphthas and reformer naphthas produced under normal conditions; the MTBE also improves the engine power and economy characteristics and lowers the carbon monoxide content in the exhaust by 15-30% and the hydrocarbon content by 7-8%. This paper describes methods for the production of MTBE and also methyl tert-alkyl ethers.

Trofimov, V.A.

1995-01-01T23:59:59.000Z

276

INVESTIGATION OF PHASE AND EMULSION BEHAVIOR, SURFACTANT RETENTION, AND CONDENSATE RECOVERY FOR CONDENSATE/WATER/ETHANOL MIXTURES  

SciTech Connect

This final technical report describes work performed at Morehouse College under DOE Grant No. DE-FG26-02NT15447 during the period October 01, 2002 to September 30, 2005, which covers the total performance period of the project. During this period, work was conducted to characterize phase and emulsion behavior for ethylbenzene/water/ethanol system. Ethylbenzene that has the equivalent carbon number was used as the model condensate. Salinity scans were performed for 0, 5, 10, 20, 50, 100, 250, 500, and 1000 mM salt concentrations at room temperature to identify the optimal salinity and salinity intervals in which all phases coexisted. It was found that only two phases formed, and salinity has no significant effect in the volumes of the phases formed. Experiments were repeated at 30 C and observed salinity has no effect at higher temperatures as well. Following the salinity experiments, measurements were made with 10mM NaCl water for surfactant concentrations from 2 to 70 volume percent at room temperature. It was found that only two phases were formed upto 60 vol% concentration of the surfactant. Above 60 vol% surfactant, the mixture produced only a single phase. Experiments were repeated from 2 to 70 C and observed that temperature has no significant effect on the number of phases formed. At the temperatures and surfactant concentration tested, volume fraction of the aqueous bottom phase was found to be larger than that of the top phase. Electrical conductivity measurements were then conducted for bottom/top, and top/bottom conjugate pair phases of the ethylbenzene/water/ethanol system formed by mixing ethanol at various volume percentages including 2,10,33,and 56% while keeping the volumes of ethylbenzene and water the same in the mixture. Electrical conductivity of the bottom phase decreased as ethanol volume fraction in the mixture increased. Conductivity of the top phase was found small and remained almost the same for variations in ethanol volume fraction in the mixture. Also inversion phenomena was observed. Prediction of the conductivity data obtained was then conducted employing a theoretical model developed in this project based on Maxwell relations. Results of the comparisons for 2, 10, 33, and 56% ethanol volume in the mixture are presented here. A good agreement was obtained between the predicted emulsion conductivities and the measured values. Work was also conducted at Surtek, Golden, CO, our industrial partner in this project, to measure the effectiveness for condensate recovery employing coreflooding techniques. In Run 1 of the radial coreflooding experiments conducted, 10 mM NaCl without ethanol injection recovered 31.5% of the initial ethyl benzene saturation. Injection of ethanol following 10 mM NaCl produced a tertiary ethyl benzene bank with maximum ethyl benzene cuts of 32%. In Run 2, 50 vol% of pure (100%) ethanol was injected and flowed through the Berea sandstone after Ethyl Benzene Saturation. 69% of the initial ethyl benzene was recovered. While 50 vol% of ethanol injection does not make economic sense when injecting a large fraction of a pore volume, injection of sufficient volume to remove water and condensate from around the near well bore area of a gas well could be economic.

Ramanathan Sampath

2005-12-01T23:59:59.000Z

277

Metal-organic frameworks with high capacity and selectivity for harmful gases  

E-Print Network (OSTI)

, chlorine, tetrahydrothiophene, benzene, dichloromethane, ethyl- ene oxide, and carbon monoxide. Kinetic

Yaghi, Omar M.

278

Societies and Academies  

Science Journals Connector (OSTI)

... glucoside (fustin); he described the preparation and the ethyl- and acetyl-derivatives of fisetin.

1886-08-26T23:59:59.000Z

279

BulletinofMathematicalBiologyVol.47,No.3,pp.367 407,1985. PrintedinGreatBritain  

E-Print Network (OSTI)

the tertiary structure. Five proteins, parvalbumin, hemerythrin, human hemoglobin, lamprey hemoglobin

Cariani, Peter

280

The Development and Application of Gold(I)-Catalyzed Cyclization Cascades  

E-Print Network (OSTI)

lithium trimethylsilylacetylide to give tertiary alcohol 4.43. Deprotection and esterification then provided acetate

Sethofer, Steven Gregory

2011-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "mtbe ethyl tertiary" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

The process of developing a strategy of sustainable development in the Pamir  

E-Print Network (OSTI)

activities such as mineral exploitation and hydroelectricity genera- tion. Tertiary sector activities

Richner, Heinz

282

Synthesis of N-formyl-3,4-di-t-butoxycarbonyloxy-6(trimethylstannyl)-L-phenylalanine ethyl ester and its regioselective radiofluorodestannylation to 6-[{sup 18}F]fluoro-1-dopa  

DOE Patents (OSTI)

A process is revealed for forming a 6-fluoro derivative of compounds in the L-Dopa family comprising the steps of protecting the groups attached to the benzene ring in the compound followed by serially reacting the protected compound with (a) iodine and silver trifluoroacetic acid; (b) Bb{sub 3}; (c) dit-butyldicarbonate; (d) hexamethyltin; (e) a fluoro compound; (f) hydrobromic acid; and (g) raising the pH to {<=}7. 1 fig.

Satyamurthy, N.; Barrio, J.R.; Bishop, A.J.; Namavari, M.; Bida, G.T.

1996-04-23T23:59:59.000Z

283

Synthesis of N-formyl-3,4-di-t-butoxycarbonyloxy-6(trimethylstannyl)-L-phenylalanine ethyl ester and its regioselective radiofluorodestannylation to 6-[{sup 18}F]fluoro-L-dopa  

DOE Patents (OSTI)

A protected 6-trimethylstannyl dopa derivative has been synthesized for the as a precursor for the preparation of 6-[{sup 18}F]fluoro-L-dopa. The tin derivative readily reacts with electrophilic radiofluorinating agents such as [{sup 18}F]F{sub 2}, [{sup 18}F]OF{sub 2} and [{sup 18}F]AcOF. The [{sup 18}F]fluoro intermediate was easily hydrolyzed with HBr and the product 6-[{sup 18}F]fluoro-L-dopa was isolated after HPLC purification in a maximum radiochemical yield of 23%, ready for human use. 1 fig.

Satyamurthy, N.; Barrio, J.R.; Bishop, A.J.; Namavari, M.

1995-02-28T23:59:59.000Z

284

C(sp2)?C(sp3) Rotational Barriers in Simple Amides:? H2N?C(O)R (R = Methyl, Ethyl, i-Propyl, tert-Butyl)  

Science Journals Connector (OSTI)

(a) Cuillerdier, C.; Musikas, C.; Hoel, P.; Nigond, L.; Vitart, X. Sep. ... (f) Cuillerdier, C.; Musikas, C.; Nigond, L. Sep. ... (i) Nigond, L.; Musikas, C.; Cuillerdier, C. Solv. ...

Giovanni Sandrone; David A. Dixon; Benjamin P. Hay

1999-02-03T23:59:59.000Z

285

Phase I and Pharmacological Study of the Novel Topoisomerase I Inhibitor 7-Ethyl-10-[4-(1-piperidino)-1-piperidino]carbonyloxycamptothecin (CPT-11) Administered as a Ninety-Minute Infusion Every 3 Weeks  

Science Journals Connector (OSTI)

...P. O. Box 1029, Princeton, NJ 08540. 3 Postdoctoral...Ayerst Laboratories, Princeton, NJ 08540. 4 Recipient...specific receptors on the plasma membrane. Cells are...specificreceptors on the plasma membrane.Cells are...P. O. Box 1029, Princeton, NJ 08540. 5Postdoctoral...

Eric K. Rowinsky; Louise B. Grochow; David S. Ettinger; Susan E. Sartorius; Barbara G. Lubejko; Tian-Ling Chen; Michael K. Rock; and Ross C. Donehower

1994-01-15T23:59:59.000Z

286

Impact of Ethanol on Benzene Plume Lengths: Microbial and Modeling Studies  

E-Print Network (OSTI)

Impact of Ethanol on Benzene Plume Lengths: Microbial and Modeling Studies Rula A. Deeb1 ; Jonathan with Federal Clean Air Act requirements for carbon monoxide and ozone attainment, ethanol is being considered as a replacement for MTBE. The objective of this study is to evaluate the potential impact of ethanol on benzene

Alvarez, Pedro J.

287

Energy Efficient Refinery Process Developed with U.S. D.O.E. Support  

E-Print Network (OSTI)

in one column, the exothermic heat of reaction is utilized to supplement distil lation energy requirements. Spent Recycle C4's MeOH MeOH C4's MTBE MeOH Reaction Water recovery column wash column INEL 3 0110 Figure 2. Process Flow Diagram...

Mings, W. J.

1983-01-01T23:59:59.000Z

288

Tomato Fruit Antioxidants in Relation to Salinity and Greenhouse Climate  

Science Journals Connector (OSTI)

Tomato Fruit Antioxidants in Relation to Salinity and Greenhouse Climate ... Blocks were positioned to account for experimental error due to minor light gradients in the greenhouse. ... Tomato extracts (15 ?L injection) were eluted with a methanol/MTBE gradient over an 80 min run. ...

David L. Ehret; Kevin Usher; Tom Helmer; Glenn Block; Dan Steinke; Brenda Frey; Tallie Kuang; Moussa Diarra

2013-01-14T23:59:59.000Z

289

Treatment of Methyl tert-Butyl Ether Vapors in Biotrickling Filters. 1.  

E-Print Network (OSTI)

because of its low cost and blending characteristics. Depending on the season, reformulated gasoline of reactor per hour, a value comparable to other gasoline constituents. Such high performance could enhancer in gasoline. The use of MTBE increased rapidly after the 1990 Clean Air Act Amendments required

290

MT3DMS, A Modular Three-Dimensional Multispecies Transport Model User Guide to the  

E-Print Network (OSTI)

.M. Cozzarelli, M.H. Lahvis, and B.A. Bekins. 1998. Ground water contamination by crude oil near Bemidji (LNAPL) contaminant through the unsaturated zone and the formation of an oil lens on the water table ................................................................................................................. 18 #12;1 1. INTRODUCTION Leaks of fuels that release contaminants such as BTEX, MTBE and other fuel

Zheng, Chunmiao

291

Remediation of water contamination using catalytic technologies  

Science Journals Connector (OSTI)

Remediation of contaminated ground and underground water is becoming a critical issue in Europe and worldwide. We discuss here the role of catalysis in water remediation, with reference to two specific examples of catalytic water remediation technologies: (i) the elimination of nitrate and pesticides from water contaminated as a result of agricultural practices and (ii) the conversion of methyl tert-butyl ether (MTBE) in contaminated underground water. Of particular interest is a technology based on catalytic membranes for remediation of water contaminated by nitrate, which offers various advantages with respect to conventional technologies. Using a Pd-Cu-based catalytic membrane, a reaction temperature below 15 °C, a mixed 4:1 CO2:H2 feed and controlling bulk solution pH by \\{HCl\\} addition, it is possible to obtain a nitrate conversion higher than 80% even with ammonium ion formation below 0.5 ppm, i.e. the maximum concentration allowed to meet the requirements for drinking water quality. In MTBE conversion in contaminated underground water, acid zeolites with suitable pore structures (channel structure and pore openings) such as H-ZSM-5 and H-BEA can be used as catalytic permeable reactive barriers for in situ remediation. These zeolites not only act as adsorbents for both MTBE and its reaction products, but also effectively catalyze the hydrolysis of MTBE to t-butyl alcohol (TBA) and methanol (MeOH) which then can be rapidly biodegraded by indigenous microorganisms.

Gabriele Centi; Siglinda Perathoner

2003-01-01T23:59:59.000Z

292

DME-to-oxygenates process studies  

SciTech Connect

The feasibility of the production of hydrocarbons from dimethyl ether (DNM) has been illustrated in a fixed bed micro-reactor as well as a bench scale fluidized bed reactor by the University of Akron/EPRI DME-to-Hydrocarbon (DTG) Process. The DTG process has distinct advantages over its methanol based counterpart. Specifically, the DTG process excels in the area of higher productivity, higher per-pass conversion, and lower heat duties than the MTG process. Also of special importance is the production of oxygenates -- including MTBE, ETBE, and TAME. DME may be reacted with isobutylene to produce a mixture of MTBE and ETBE. The properties of ETBE excel over MTBE in the areas of lower RVP and higher RON. According to industrial reports, MTBE is the fastest growing chemical (1992 US capacity 135,350 BPD, with expected growth of 34%/year to 1997). Also, recent renewed interest as an octane-enhancer and as a source of oxygen has spurred a growing interest in nonrefinery synthesis routes to ETBE. TAME, with its lower RVP and higher RON has proven useful as a gasoline blending agent and octane enhancer and may also be produced directly from DME. DME, therefore, serves as a valuable feedstock in the conversion of may oxygenates with wide-scale industrial importance. It should be also noted that the interest in the utilization of DME as process feedstock is based on the favorable process economics of EPRI/UA`s liquid phase DME process.

Tartamella, T.L.; Sardesai, A.; Lee, S. [Univ. of Akron, OH (United States); Kulik, C.J. [Electric Power Research Inst., Palo Alto, CA (United States)

1994-12-31T23:59:59.000Z

293

Achieving Acceptable Air Quality: Some Reflections on Controlling Vehicle Emissions  

Science Journals Connector (OSTI)

...combus-tion. Over time, electric vehicles will not...shift as fossil fuel power plants that provide...trans-portation power that is free of...urban areas where electric vehicles are used...some-times increased. In refineries, MTBE is generally...mechanisms. Volatility curves for methanol-gasoline...

J. G. Calvert; J. B. Heywood; R. F. Sawyer; J. H. Seinfeld

1993-07-02T23:59:59.000Z

294

he increasing frequency of detection of the widely used gasoline additive methyl tert-  

E-Print Network (OSTI)

T he increasing frequency of detection of the widely used gasoline additive methyl tert- butyl, the September 15, 1999, Report of the Blue Ribbon Panel on Oxygenates in Gasoline (1) states that between 5 with large releases (e.g., LUFTs). Unprecedented growth in use Use of MTBE as a gasoline additive began

295

UMass scientists tackle gas spills Underground microbesseenas  

E-Print Network (OSTI)

on earth could be the newest , weapon against gasoline spills. Researchers at the University spills of the gasoline additive MTBE. First added to gasoline to enhance octane, and later in much larger on sulfur, the UMass team has been. able to remove benzene, a carcino- genic component of gasoline and other

Lovley, Derek

296

Water Research Institute Annual Technical Report  

E-Print Network (OSTI)

Air Act mandated oxygenated gasoline containing methyl tert-butyl ether (MtBE) in certain areas percent. The State of Maine elected to use reformulated gasoline (RFG) that contained at least 11 percent and by 1995, oxygenated gasoline use was common in the northeast. Soon after the widespread use of gasoline

297

Numerical study of the effect of oxygenated blending compounds on soot formation in shock tubes  

SciTech Connect

This numerical study deals with the influence of blends on the amount of soot formed in shock tubes, which were simulated by assuming a homogeneous plug flow reactor model. For this purpose, first, the reaction model used here was validated against experimental results previously obtained in the literature. Then, the soot volume fractions of various mixtures of methyl tert-butyl ether (MTBE)-benzene, isobutene-benzene, methanol-benzene, and ethanol-benzene diluted in argon were simulated and compared to the results of benzene-argon pyrolysis at 1721 K and 5.4 MPa. For MTBE, isobutene, methanol, and ethanol, small amounts of additives to benzene-argon mixtures promoted soot formation, for the shock tube model assumed, while higher concentrations of these additives led to smaller soot volume fractions in comparison to pure benzene-argon pyrolysis. The most significant soot promotion effect was found for the additives MTBE and isobutene. The channel for MTBE decomposition producing isobutene and methanol is very effective at temperatures beyond 1200 K. Thus, both MTBE-benzene and isobutene-benzene mixtures diluted in argon showed rather similar behavior in regard to soot formation. Special emphasis was directed toward the causes for the concentration-dependent influence of the blends on the amount of soot formed. Aromatic hydrocarbons and acetylene were identified as key gas-phase species that determine the trends in the formation of soot of various mixtures. From reaction flux analysis for phenanthrene, it was deduced that the combinative routes including phenyl species play a major role in forming PAHs, especially at early reaction times. It is found that the additives play an important role in providing material to grow side chains, such as by reaction channels including phenylacetylene or benzyl, which are confirmed to form aromatic hydrocarbons and thus to influence the amount of soot formed, particularly when the concentrations of the blends are increased. (author)

Boehm, H. [Physikalische Chemie I, Universitaet Bielefeld (Germany); Braun-Unkhoff, M. [Deutsches Zentrum fuer Luft- und Raumfahrt e.V., Stuttgart (Germany)

2008-04-15T23:59:59.000Z

298

DEPARTMENTS:  

Science Journals Connector (OSTI)

......Acetylene Ethyl Chloride Ethyl Fluoride Ethylene Ethylene Oxide Fluorine Halocarbon- 11...chromato - graphy. No guess: the price is low.Alurninum OxideW 200 acid...neutra) For informati Al on and price liet Write to: upharm Chemicals0......

New Literature Available

1969-11-01T23:59:59.000Z

299

Improved Synthesis of the ABCDE Fragment of Brevetoxin A  

E-Print Network (OSTI)

. An unprecedented Claisen condensation of the N-acyloxazolidinone with the lithium enolate of ethyl acetate provided

300

Energy Efficiency in the Process of Ethanol Production from Molasses  

Science Journals Connector (OSTI)

Production of ethanol (ethyl alcohol) by fermentation is one... 1. Continuous fermentation technology in order to achieve higher ethanol

Ali Beba

1983-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "mtbe ethyl tertiary" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Electrolyte-Concentration and Ion-Size Dependence of Excited-State Intramolecular Charge-Transfer Reaction in (Alkylamino)benzonitriles: Steady-State Spectroscopic Studies  

E-Print Network (OSTI)

)benzonitrile (P6C), in ethyl acetate and acetonitrile in presence of lithium perchlorate (LiClO4) at room relative to that in pure ethyl acetate whereas it is a factor of 4 for both P5C and P6C. However as the electrolyte (LiClO4) concentration is increased, electrolyte effects being more pronounced in ethyl acetate

Biswas, Ranjit

302

Early opening history of the North Atlantic — I. Structure and origin of the Faeroe—Shetland Escarpment  

Science Journals Connector (OSTI)

......Faeroe-Shetland Trough and More Basin. References Am K...NW-European Tertiary basin, Newsl. Strat., 8...Australia: Great Australian Bight and western sections...NW-European Tertiary basin, Newsl. Strat., 8...Australia: Great Australian Bight and western sections......

D. K. Smythe; J. A. Chalmers; A. G. Skuce; A. Dobinson; A. S. Mould

1983-02-01T23:59:59.000Z

303

Early opening history of the North Atlantic — I. Structure and origin of the Faeroe—Shetland Escarpment  

Science Journals Connector (OSTI)

......Trough and More Basin. References Am...NW-European Tertiary basin, Newsl. Strat...of Australia: Great Australian Bight and western sections...NW-European Tertiary basin, Newsl. Strat...of Australia: Great Australian Bight and western sections......

D. K. Smythe; J. A. Chalmers; A. G. Skuce; A. Dobinson; A. S. Mould

1983-02-01T23:59:59.000Z

304

BIOINFORMATICS Vol. 20 no. 10 2004, pages 16031611  

E-Print Network (OSTI)

that the majority of most proteins fold via a cooperative process where secondary and tertiary structure form

305

U.S. Department of the Interior U.S. Geological Survey  

E-Print Network (OSTI)

Basin are unconsolidated deposits of the Tertiary Santa Fe Group. Post-Santa Fe Group deposits (piedmont

306

2 CHANCELLOR'S INTRODUCTION SECTION 01. OVERVIEW  

E-Print Network (OSTI)

with the Government's tertiary reforms, in the hope that these reforms would assist the University in meeting its of the Education (Tertiary Reform) Amendment Bill. Those provisions, if enacted, would have given the government. Other aspects of this engagement were less encouraging. It seems clear that the current tertiary reforms

Goodman, James R.

307

Oxygenate Supply/Demand Balances  

Gasoline and Diesel Fuel Update (EIA)

Oxygenate Supply/Demand Oxygenate Supply/Demand Balances in the Short-Term Integrated Forecasting Model By Tancred C.M. Lidderdale This article first appeared in the Short-Term Energy Outlook Annual Supplement 1995, Energy Information Administration, DOE/EIA-0202(95) (Washington, DC, July 1995), pp. 33-42, 83-85. The regression results and historical data for production, inventories, and imports have been updated in this presentation. Contents * Introduction o Table 1. Oxygenate production capacity and demand * Oxygenate demand o Table 2. Estimated RFG demand share - mandated RFG areas, January 1998 * Fuel ethanol supply and demand balance o Table 3. Fuel ethanol annual statistics * MTBE supply and demand balance o Table 4. EIA MTBE annual statistics * Refinery balances

308

ETBE Synthesis via Reactive Distillation. 1. Steady-State Simulation and Design Aspects  

Science Journals Connector (OSTI)

To validate the simulation results without experimental data, Smith's MTBE column was simulated for the case described in his patent application (Smith, 1980) using both Pro/II and SpeedUp. ... The maximum conversion in a 10-stage ETBE reactive distillation column (Figure 5) and a 30-stage ETBE reactive distillation column based on a commercial MTBE column (Simulation Sciences, 1995) (where the co-objective is to essentially eliminate butylenes from the ether product) was determined for varying isobutylene concentrations in the hydrocarbon feed to the primary reactor, by simulations using Pro/II. ... 11.?Determine?column?diameter?from?simulation?data?for?vapor?and?liquid?loadings?and?column?height?from?stage?efficiency? estimates,?including?appropriate?allowances?for?uncertainties?in?flooding?factor?and?stage?efficiency. ...

Martin G. Sneesby; Moses O. Tadé; Ravindra Datta; Terence N. Smith

1997-05-05T23:59:59.000Z

309

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center (EERE)

hydrogen Go hydrogen Go Hydrogen-stations Hydrogen Fueling Station Locations by State Hydrogen-stations View Map Graph Hydrogen_li_by_state Hydrogen Incentives and Laws, by State Hydrogen_li_by_state View Map Graph Generated_thumb20130810-31804-1c5lrlb Commuter Responses to the 2008 Oil Price Spike Generated_thumb20130810-31804-1c5lrlb Ways that workers changed their commutes in response to high gasoline prices Last update May 2012 View Graph Graph Download Data Generated_thumb20130810-31804-f64ffe U.S. Consumption of Ethanol and MTBE Oxygenates Generated_thumb20130810-31804-f64ffe Trend of ethanol and MTBE consumption as oxygenates and gasohol blends from 1992-2009 Last update February 2012 View Graph Graph Download Data Generated_thumb20130810-31804-14nv4j5 AFV Acquisitions by Regulated Fleets (by Fuel Type)

310

Molybdenum recovery  

SciTech Connect

This patent describes a process for the preparation of propylene oxide and tertiary butyl alcohol. It comprises: propylene and tertiary butyl hydroperoxide are reacted in an epoxidation reaction zone in solution in tertiary butyl alcohol in the presence of a soluble molybdenum catalyst to provide an epoxidation reaction product comprising unreacted propylene, unreacted tertiary butyl hydroperoxide, propylene oxide, tertiary butyl alcohol, dissolved molybdenum catalyst and impurities, including lower aliphatic C{sub 1}-C{sub 4} carboxylic acids, and wherein the epoxidation reaction product is resolved into product fractions in a distillation zone including a distillate propylene fraction.

Meyer, R.A.; Marquis, E.T.

1992-03-31T23:59:59.000Z

311

Study downplays health concerns  

SciTech Connect

A government-funded study has concluded that reformulated gasoline containing methyl tert-butyl ether (MTBE) does not increase short-term health risks when compared with gasoline that does not contain the additive. The study, performed by the Health Effects Institute (Cambridge, MA), compared data from dozens of animal, human, and epidemiological studies of health effects linked to oxygenates, including MTBE and ethanol, but did not find enough evidence to warrant an immediate reduction in oxygenate use. However, the study did recommend that additional research be conducted on possible health consequences associated with the gasoline additives, including neurotoxic effects, if oxygenates continue to be used long term. Oxygenates have been used in gasoline since 1992, when EPA mandated that several municipalities use MTBE or other oxygenates in reformulated gasoline to reduce carbon monoxide emissions and meet Clean Air Act requirements. Shortly after the program began, residents in areas where the oxygenates were used complained of nausea, headaches, and dizziness. The institute says the study--funded by EPA and the Centers for Disease Control--will be used for a broader review of gasoline oxygenates by the White House Office of Science and Technology Policy.

Stringer, J.

1996-03-13T23:59:59.000Z

312

Synthesis and Preclinical Evaluation of 2-(2-Furanyl)-7-[2-[4-[4-(2-[11C]methoxyethoxy)phenyl]-1-piperazinyl]ethyl]7H-pyrazolo[4,3-e][1,2,4]triazolo[1,5-c]pyrimidine-5-amine ([11C]Preladenant) as a PET Tracer for the Imaging of Cerebral Adenosine A2A Receptors  

Science Journals Connector (OSTI)

Regional brain uptake of [11C]-3 was consistent with known A2ARs distribution, with highest uptake in striatum. ... The results indicate that [11C]-3 has favorable brain kinetics and exhibits suitable characteristics as an A2AR PET tracer. ...

Xiaoyun Zhou; Shivashankar Khanapur; Anja P. Huizing; Rolf Zijlma; Marianne Schepers; Rudi A. J. O. Dierckx; Aren van Waarde; Erik F. J. de Vries; Philip H. Elsinga

2014-10-03T23:59:59.000Z

313

Synthesis and structures of new niobium cluster compounds with pyridinium cations: (PyrH){sub 2}[Nb{sub 6}Cl{sub 18}].EtOH (Pyr: pyridine, Et: ethyl) and the cubic modification of (PyrH){sub 2}[Nb{sub 6}Cl{sub 18}  

SciTech Connect

Slow crystallization of (PyrH){sub 2}[Nb{sub 6}Cl{sub 18}] from hot ethanol solution affords triclinic (PyrH){sub 2}[Nb{sub 6}Cl{sub 18}].EtOH. Treatment of [Nb{sub 6}Cl{sub 14}(H{sub 2}O){sub 4}].4H{sub 2}O with pyridine in a methanol solution gives the second title compound, the cubic modification of (PyrH){sub 2}[Nb{sub 6}Cl{sub 18}]. Both structures were determined by single crystal X-ray diffraction, (PyrH){sub 2}[Nb{sub 6}Cl{sub 18}].EtOH: P1-bar , a=9.3475(3), b=9.3957(3), c=10.8600(3) A, {alpha}=82.582(1){sup o}, {beta}=78.608(1){sup o}, and {gamma}=78.085(1){sup o}, Z=1, R{sub 1}(F)/wR{sub 2}(F{sup 2})=0.0254/0.0573, cub.-(PyrH){sub 2}[Nb{sub 6}Cl{sub 18}]: Fd3-bar m, a=19.935(2) A, Z=8, R{sub 1}(F)/wR{sub 2}(F{sup 2})=0.0557/0.1796. The cluster compounds contain isolated, molecular [Nb{sub 6}Cl{sup i}{sub 12}Cl{sup a}{sub 6}]{sup 2-} cluster anions with an octahedron of metal atoms edge bridged by chlorido ligands with additional ones on all the six exo positions. These cluster anions are separated by the pyridinium cations and ethanol solvent molecules, respectively. For the cubic modification of (PyrH){sub 2}[Nb{sub 6}Cl{sub 18}], a structural comparison is given to the known rhombohedral modification using the group-subgroup relations as expressed by a Baernighausen tree. - Graphical abstract: The synthesis and structure of a second cubic modification of (PyrH){sub 2}[Nb{sub 6}Cl{sub 18}] and of the new (PyrH){sub 2}[Nb{sub 6}Cl{sub 18}].EtOH are reported, both of which contain isolated niobium halide cluster anions with an octahedral core of metal atoms.

Flemming, Anke; Hoppe, Alessandra [Institut fuer Chemie, Abteilung Anorganische Chemie/Festkoerperchemie, Universitaet Rostock, Albert-Einstein-Str. 3a, Rostock D-18059 (Germany); Koeckerling, Martin [Institut fuer Chemie, Abteilung Anorganische Chemie/Festkoerperchemie, Universitaet Rostock, Albert-Einstein-Str. 3a, Rostock D-18059 (Germany)], E-mail: Martin.Koeckerling@uni-rostock.de

2008-10-15T23:59:59.000Z

314

Design and synthesis of mesoionic carbenes /  

E-Print Network (OSTI)

diisopropylphenyl. tht: tetrahydrothiophene. Et: Ethyl. Ts:0.171 mmol, 1 eq) and tetrahydrothiophene gold chloride (540.48 mmol, 1 eq) and tetrahydrothiophene gold chloride (154

Ung, Gaël

2013-01-01T23:59:59.000Z

315

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center (EERE)

Blend Definition An ethanol blend is defined as a blended motor fuel containing ethyl alcohol that is at least 99% pure, derived from agricultural products, and blended exclusively...

316

Advancing Cellulosic Ethanol for Large Scale Sustainable Transportation  

E-Print Network (OSTI)

Advancing Cellulosic Ethanol for Large Scale SustainableHydrogen Batteries Nuclear By Lee Lynd, Dartmouth Ethanol •Ethanol, ethyl alcohol, fermentation ethanol, or just “

Wyman, C

2007-01-01T23:59:59.000Z

317

Short Time Dynamics of Ionic Liquids in AIMD-Based Power Spectra  

Science Journals Connector (OSTI)

Short Time Dynamics of Ionic Liquids in AIMD-Based Power Spectra ... A Car-Parrinello study of 1-ethyl-3-methyl-imidazolium chloride water mixture ...

Katharina Wendler; Martin Brehm; Friedrich Malberg; Barbara Kirchner; Luigi Delle Site

2012-04-04T23:59:59.000Z

318

E-Print Network 3.0 - asymmetric dimethylarginine adma Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

with ethene. The substrates used in this study include AEE (Allyl Ethyl Ether), ADMA (Acrolein... which mechanism is operative in this case. 3.4. Functional monomer - allyl...

319

STUDIES CONCERNING NUCLEOPHILIC PHOSPHINE CATALYSIS AND DESIGNS OF NEW CHIRAL AMINOPHOSPHINES TOWARD ASYMMETRIC PHOSPHINE-CATALYZED REACTIONS  

E-Print Network (OSTI)

A. E. ?Structure of Phosphorous Acid and its Derivatives,?onto the phosphonium phosphorous was essentially significantmethyl or ethyl zinc and phosphorous trichloride. 4 1.3

Khong, San Ngoc

2013-01-01T23:59:59.000Z

320

Membrane Stresses Induced by Overproduction of Free Fatty Acids...  

NLE Websites -- All DOE Office Websites (Extended Search)

coli. Abstract: Microbially produced fatty acids are potential precursors to high energy density biofuels, including alkanes and alkyl ethyl esters by either catalytic...

Note: This page contains sample records for the topic "mtbe ethyl tertiary" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

The enantioselective total synthesis of (+)-Symbioimine  

E-Print Network (OSTI)

producing ethyl sulfide 45, followed by CSA-catalyzed silyl-ether methanolysis and acetal formation, and PPTS-catalyzed condensation/elimination of methanol

Born, Stephen Christopher

2009-01-01T23:59:59.000Z

322

What substitutes for oil?  

Science Journals Connector (OSTI)

... bagasse, ethyl alcohol, vegetable oils, methane and hydrogen; as well as hydro and nuclear power generation, conservation methods, and solar, wind and tidal energy.

David Spurgeon

1978-06-29T23:59:59.000Z

323

Guidance Document Carcinogenic Substances  

E-Print Network (OSTI)

Mustard gas (bis(2-chloroethyl)sulfide) Formaldehyde (gas) Vinyl chloride Acetaldehyde Carbon tetrachloride 1,4-Dioxane Chloroform Ethyl carbamate (uret 3-Chloro-2-methylpropene Hexamethylphosphor 1

324

[Research and workshop on alternative fuels for aviation. Final report  

SciTech Connect

The Renewable Aviation Fuels Development Center (RAFDC) at Baylor University was granted U. S. Department of Energy (US DOE) and Federal Aviation Administration (FAA) funds for research and development to improve the efficiency in ethanol powered aircraft, measure performance and compare emissions of ethanol, Ethyl Tertiary Butyl Ether (ETBE) and 100 LL aviation gasoline. The premise of the initial proposal was to use a test stand owned by Engine Components Inc. (ECI) based in San Antonio, Texas. After the grant was awarded, ECI decided to close down its test stand facility. Since there were no other test stands available at that time, RAFDC was forced to find additional support to build its own test stand. Baylor University provided initial funds for the test stand building. Other obstacles had to be overcome in order to initiate the program. The price of the emission testing equipment had increased substantially beyond the initial quote. Rosemount Analytical Inc. gave RAFDC an estimate of $120,000.00 for a basic emission testing package. RAFDC had to find additional funding to purchase this equipment. The electronic ignition unit also presented a series of time consuming problems. Since at that time there were no off-the-shelf units of this type available, one had to be specially ordered and developed. FAA funds were used to purchase a Super Flow dynamometer. Due to the many unforeseen obstacles, much more time and effort than originally anticipated had to be dedicated to the project, with much of the work done on a volunteer basis. Many people contributed their time to the program. One person, mainly responsible for the initial design of the test stand, was a retired engineer from Allison with extensive aircraft engine test stand experience. Also, many Baylor students volunteered to assemble the. test stand and continue to be involved in the current test program. Although the program presented many challenges, which resulted in delays, the RAFDC's test stand is an asset which provides an ongoing research capability dedicated to the testing of alternative fuels for aircraft engines. The test stand is now entirely functional with the exception of the electronic ignition unit which still needs adjustments.

NONE

1999-09-01T23:59:59.000Z

325

--No Title--  

National Nuclear Security Administration (NNSA)

early Permian in age and consist of 22,000 feet of limestone, dolomite, quartzite, shale, and conglomerate beds. The predominantly volcanic Oak Springs formation of Tertiary...

326

Title  

National Nuclear Security Administration (NNSA)

early Permian in age and consist of 22,000 feet of limestone, dolomite, quartz- ite, shale, and conglomerate beds. The predominantly volcanic Oak Springs formation of Tertiary...

327

This Week In Petroleum Printer-Friendly Version  

Annual Energy Outlook 2012 (EIA)

or tertiary stock levels. For example, if gasoline stations are drawing down their tanks more than normal in order to postpone purchases (a reasonable strategy when prices are...

328

E-Print Network 3.0 - aliphatic amines extraction Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

; Environmental Sciences and Ecology 37 Exploratory Studies on Fast Pyrolysis Oil Upgrading Summary: using Aliphatic Tertiary Amines... -1 Acetic Acid Recovery from Fast...

329

u42501.PDF  

Office of Legacy Management (LM)

Younger sedimentary rocks overlying the Wasatch Formation are the Tertiary sandstone, oil shale, and marlstone beds of the Green River Formation which crop out almost continuously...

330

Mineralogy and organic petrology of oil shales in the Sangkarewang formation, Ombilin Basin, West Sumatra, Indonesia.  

E-Print Network (OSTI)

??The Ombilin Basin, which lies in Sumatra Island, is one of the Tertiary basins in Indonesia. This basin contains a wide variety of rock units,… (more)

Fatimah, Fatimah

2009-01-01T23:59:59.000Z

331

Fractures of the Dammam Dome Carbonate Outcrops: Their Characterization, Development, and Implications for Subsurface Reservoirs.  

E-Print Network (OSTI)

??The exposed Tertiary carbonates of the Dammam Dome present an opportunity to study fractures in outcrops within the oil-producing region of Eastern Saudi Arabia. The… (more)

Al-Fahmi, Mohammed M

2012-01-01T23:59:59.000Z

332

Relative influence of natural watershed properties and human disturbance on stream solute concentrations in the southwestern  

E-Print Network (OSTI)

balance calculations suggest that supplemental cattle salts could comprise a significant fraction, tertiary sediments or sandstone for a given soil exchangeable cation content in both seasons. Simple mass

Biggs, Trent

333

MULTI-SCALE SIMULATIONS OF INTRINSICALLY DISORDERED PROTEINS AND DEVELOPMENT OF ENHANCED SAMPLING TECHNIQUES.  

E-Print Network (OSTI)

??Intrinsically disordered proteins (IDPs) are functional proteins that lack stable tertiary structures under physiological conditions. IDPs are key components of regulatory networks that dictate various… (more)

Zhang, Weihong

2014-01-01T23:59:59.000Z

334

Mechanisms of binding diversity in protein disorder : molecular recognition features mediating protein interaction networks.  

E-Print Network (OSTI)

??Indiana University-Purdue University Indianapolis (IUPUI) Intrinsically disordered proteins are proteins characterized by lack of stable tertiary structures under physiological conditions. Evidence shows that disordered proteins… (more)

Hsu, Wei-Lun

2014-01-01T23:59:59.000Z

335

Geothermal Literature Review At Lightning Dock Geothermal Area...  

Open Energy Info (EERE)

Evidence for Large-Scale Laramide Tectonic Inversion and a Mid-Tertiary Caldera Ring Fracture Zone at the Lightning Dock Geothermal System, New Mexico Additional References...

336

Retreat of the state and the market: liberalisation and education expansion in Sudan under the NCP.  

E-Print Network (OSTI)

??This thesis is an analysis of two concurrent processes - the liberalisation of the economy and the expansion of the tertiary education system - by… (more)

Mann, Laura Elizabeth

2012-01-01T23:59:59.000Z

337

E-Print Network 3.0 - antigen proteins promotes Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

characteristics is focused on antigenic proteins. Epitopes play... another through protein folding. Thus, the importance of the tertiary conformation of the antigen... that are...

338

E-Print Network 3.0 - antigenic protein fractions Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

characteristics is focused on antigenic proteins. Epitopes play... another through protein folding. Thus, the importance of the tertiary conformation of the antigen... that are...

339

E-Print Network 3.0 - aryl bisdiazeniumdiolates potent Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

of Hindered Alkyl-Aryl Ethers Thomas F. Woiwode... synthesis.2 Our retrosynthetic analysis of phomopsin A targeted the chiral tertiary alkyl-aryl ether... substitution (SNAr)...

340

Shallow seismic investigations in the Valles Caldera  

E-Print Network (OSTI)

type · Complex shallow structure Davidson, M. Thesis, Perdue Univ. 1999 unconsolidated sediments fill Davidson, M. Thesis, Perdue Univ. 1999 unconsolidated sediments Permian/tertiary sediments

West, Michael

Note: This page contains sample records for the topic "mtbe ethyl tertiary" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

E-Print Network 3.0 - acute cardiac care Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

Summary: patients are enrolled in cardiac rehabilitation programmes, both from the health care staV and other... being discharged from a tertiary care centre in western...

342

An Aerosol Condensation Model for Sulfur Trioxide  

SciTech Connect

This document describes a model for condensation of sulfuric acid aerosol given an initial concentration and/or source of gaseous sulfur trioxide (e.g. fuming from oleum). The model includes the thermochemical effects on aerosol condensation and air parcel buoyancy. Condensation is assumed to occur heterogeneously onto a preexisting background aerosol distribution. The model development is both a revisiting of research initially presented at the Fall 2001 American Geophysical Union Meeting [1] and a further extension to provide new capabilities for current atmospheric dispersion modeling efforts [2]. Sulfuric acid is one of the most widely used of all industrial chemicals. In 1992, world consumption of sulfuric acid was 145 million metric tons, with 42.4 Mt (mega-tons) consumed in the United States [10]. In 2001, of 37.5 Mt consumed in the U.S., 74% went into producing phosphate fertilizers [11]. Another significant use is in mining industries. Lawuyi and Fingas [7] estimate that, in 1996, 68% of use was for fertilizers and 5.8% was for mining. They note that H{sub 2}SO{sub 4} use has been and should continue to be very stable. In the United States, the elimination of MTBE (methyl tertiary-butyl ether) and the use of ethanol for gasoline production are further increasing the demand for petroleum alkylate. Alkylate producers have a choice of either a hydrofluoric acid or sulfuric acid process. Both processes are widely used today. Concerns, however, over the safety or potential regulation of hydrofluoric acid are likely to result in most of the growth being for the sulfuric acid process, further increasing demand [11]. The implication of sulfuric acid being a pervasive industrial chemical is that transport is also pervasive. Often, this is in the form of oleum tankers, having around 30% free sulfur trioxide. Although sulfuric acid itself is not a volatile substance, fuming sulfuric acid (referred to as oleum) is [7], the volatile product being sulfur trioxide. Sulfate aerosols and mist may form in the atmosphere on tank rupture. From chemical spill data from 1990-1996, Lawuyi02 and Fingas [7] prioritize sulfuric acid as sixth most serious. During this period, they note 155 spills totaling 13 Mt, out of a supply volume of 3700 Mt. Lawuyi and Fingas [7] summarize information on three major sulfuric acid spills. On 12 February 1984, 93 tons of sulfuric acid were spilled when 14 railroad cars derailed near MacTier, Parry Sound, Ontario. On 13 December 1978, 51 railroad cars derailed near Springhill, Nova Scotia. One car, containing 93% sulfuric acid, ruptured, spilling nearly its entire contents. In July 1993, 20 to 50 tons of fuming sulfuric acid spilled at the General Chemical Corp. plant in Richmond, California, a major industrial center near San Francisco. The release occurred when oleum was being loaded into a nonfuming acid railroad tank car that contained only a rupture disk as a safety device. The tank car was overheated and this rupture disk blew. The resulting cloud of sulfuric acid drifted northeast with prevailing winds over a number of populated areas. More than 3,000 people subsequently sought medical attention for burning eyes, coughing, headaches, and nausea. Almost all were treated and released on the day of the spill. By the day after the release, another 5,000 people had sought medical attention. The spill forced the closure of five freeways in the region as well as some Bay Area Rapid Transit System stations. Apart from corrosive toxicity, there is the additional hazard that the reactions of sulfur trioxide and sulfuric acid vapors with water are extremely exothermic [10, 11]. While the vapors are intrinsically denser than air, there is thus the likelihood of strong, warming-induced buoyancy from reactions with ambient water vapor, water-containing aerosol droplets, and wet environmental surface. Nordin [12] relates just such an occurrence following the Richmond, CA spill, with the plume observed to rise to 300 m. For all practical purposes, sulfur trioxide was the constituent released from the heated tank

Grant, K E

2008-02-07T23:59:59.000Z

343

Efficient Energy Usage in Butane Splitters  

E-Print Network (OSTI)

PEN*ANE + I n-BUTANE ISOMERISATION i/n-BUTANE FLOW DIAGRAM 2 ALKYLATE PROCESS PROPANE n?BUTANE i/n?BUTANE I * Incorporates C4 Splitter With environmental pressure to remove lead from gas oline expected to continue, the use of MTBE, TBA... ALKYLATION I I I . n?BUTANE FRACTIONATION ISOMERISATION 1sPEL AJKYLATI ACID CONVENTIONAL FRACTIONATOR Fllctionetor Reboil_ n?C4 Prod... 783 ESL-IE-82-04-142 Proceedings from the Fourth Industrial Energy Technology Conference, Houston, TX, April...

Barnwell, J.; Morris, C. P.

1982-01-01T23:59:59.000Z

344

Cumene by Catalytic Distillation  

SciTech Connect

The novel concept of Catalytic Distillation has been commercialized in the CRandL MTBE process, in which combined reaction and distillation provide energy savings over conventional processes. This concept has now been extended to production of cumene from benzene and propylene. In this case the advantages of the technique are not only energy savings but significant reductions in by-product losses and capital requirements. In this paper the development of the process is discussed and the economics of commercial operation are presented.

Jones, E.M.; Mawer, J.

1986-01-01T23:59:59.000Z

345

Modification of Y Zeolite with Alkaline Treatment: Textural Properties and Catalytic Activity for Diethyl Carbonate Synthesis  

Science Journals Connector (OSTI)

(1) Compared to dimethyl carbonate (DMC) and ethanol, DEC has been proposed as a potential fuel oxygenate additive to replace methyl tert-butyl ether (MTBE) because of its high oxygen content (40.6 wt %) and favorable fuel/water partition coefficient. ... For CuY using untreated zeolite as a support, there were only two H2-comsumption peaks at 473 and 681 K, ascribed to the Cu+ located on sites III? and II. ... Dunn, B. C.; Guenneau, C.; Hilton, S. A.; Pahnke, J.; Eyring, E. M.Production of diethyl carbonate from ethanol and carbon monoxide over a heterogeneous catalyst Energy Fuels 2002, 16, 177– 181 ...

Shouying Huang; Pengzhen Chen; Bing Yan; Shengping Wang; Yongli Shen; Xinbin Ma

2013-04-20T23:59:59.000Z

346

Quantitation by Gas Chromatography-Chemical Ionization Mass Spectrometry of Cyclophosphamide, Phosphoramide Mustard, and Nornitrogen Mustard in the Plasma and Urine of Patients Receiving Cyclophosphamide Therapy  

Science Journals Connector (OSTI)

...Mutagenicity of Urethan (Ethyl Carbamate) Gas in Drosophila melanogaster 1 1 The work...spermatozoa to urethan (ethyl carbamate) gas induced a high frequency of X-linked recessive...observed. Mutagenic activity of urethan gas on mature spermatozoa following 1.5...

I. Jardine; C. Fenselau; M. Appler; M-N. Kan; R. B. Brundrett; M. Colvin

1978-02-01T23:59:59.000Z

347

Evaluation of a Modeling System for S-Phase Estimation in Breast Cancer by Flow Cytometry  

Science Journals Connector (OSTI)

...Protocol B. injection of ethyl carbamate midway through BrdUrd infusion; Protocol C...population treated with ethyl car bamate midway between the 2 cycles (Protocol B) estimates...the beginning of the first cycle (Ai; midway between the first and second cycles...

Lynn G. Dressler; Larry Seamer; Marilyn A. Owens; Gary M. Clark; William L. McGuire

1987-10-15T23:59:59.000Z

348

Vadose Zone Monitoring System Installation Report for McClellan AFB  

E-Print Network (OSTI)

Chloro- Toluene benzene Ethyl- PCE Xylene 1.3.5- 1.2,4- 1.3-Chloro- Toluene benzene Ethyl- PCE Xylene 1.3.5- 1.2,4- 1.3-Chlorobenzene • Toluene • PCE A— Xylene • 1.2,4-THB • 1.3-

Zawislanski, Peter

2010-01-01T23:59:59.000Z

349

NEW LITERATURE AVAILABLE:  

Science Journals Connector (OSTI)

......2-Ethoxyethanol H Ethyl Acetate H Ethylene Dichloride Ethyl Ether...spray reagents listing prices and uses, a description...of-the-art technology with low prices. Each column comes with...this flyer, as well as price information for available...measurement of H2, CO2, ethylene, ethane, acetylene......

New Literature Available

1979-04-01T23:59:59.000Z

350

Biological effects of simple changes in functionality on rhodium metalloinsertors  

Science Journals Connector (OSTI)

...pyridine-2-yl)amino)acetate (4) was prepared according...chromatography (SiO2, hexane/ethyl acetate=8:2) to give a yellow...ethanol (5a) To a slurry of lithium aluminium hydride (LAH; 1...chromatography (SiO2, hexane/ethyl acetate=1:1) to afford DPAE...

2013-01-01T23:59:59.000Z

351

Mechanistic and Reactivity Studies of Cationic Cyclizations Catalyzed by Supramolecular Encapsulation  

E-Print Network (OSTI)

lithium wire ( 45.2 mmol), 2.3 mL 2-bromo-2- butene (22.6 mmol), and 1.0 g ethyl acetate-lithium wire (27.7 mmol), 1.87 g (E)-2-bromo-2-butene (13.9 mmol), and 0.680 mL ethyl acetate (

Hastings, Courtney James

2010-01-01T23:59:59.000Z

352

Supporting Information A dipicolinic acid tag for rigid lanthanide tagging of proteins and paramagnetic  

E-Print Network (OSTI)

the resulting suspension was filtered. The filtrate was extracted with ethyl acetate (4 x 50 ml), the organic. The resulting dark solution was diluted with ethyl acetate (40 ml), washed with water (2 x 20 ml) and 3 M,6-Dimethoxycarbonyl-4-bromomethylpyridine (3). Lithium bromide (212 mg, 2.44 mmol) was added to a solution

Otting, Gottfried

353

GC and Mass Spectral Studies on Acylated Side Chain Regioisomers of 3-Methoxy-4-methyl-phenethylamine and 4-Methoxy-3-methyl-phenethylamine  

Science Journals Connector (OSTI)

......amine in 50 L of ethyl acetate followed by addition...with 200 L of ethyl acetate and 50 L of pyridine...working solutions. Synthesis The methods for the...upon reduction with lithium aluminum hydride (LAH...R.F.X. Klein. Synthesis and characteri- zation......

Tamer Awad; Jack DeRuiter; Tarek Belal; C. Randall Clark

2009-04-01T23:59:59.000Z

354

GC–MS and GC–IRD Studies on Dimethoxyphenethylamines (DMPEA): Regioisomers Related to 2,5-DMPEA  

Science Journals Connector (OSTI)

......amine in 50 microL of ethyl acetate, followed by the addition...reconstituted with 200 microL of ethyl acetate and 50 microL of pyridine...the corresponding amine using lithium aluminum hydride. The amines...salts using gaseous HCl. The synthesis of the analytical sample of......

Hadir M. Maher; Tamer Awad; Jack DeRuiter; C. Randall Clark

2012-01-01T23:59:59.000Z

355

GC—MS Analysis of Acylated Derivatives of a Series of Side Chain Regioisomers of 2-Methoxy-4-Methyl-Phenethylamines  

Science Journals Connector (OSTI)

......each amine in 50 L of ethyl acetate followed by addition of large...reconstituted with 200 L of ethyl acetate and 50 L of pyridine. General...which upon reduction with lithium aluminum hydride (LAH) yields...Hays. and R.F. X. Klein. Synthesis and characteriza- tion of......

Tamer Awad; Jack DeRuiter; C. Randall Clark

356

GC-MS Analysis of Acylated Derivatives of the Side-Chain Regioisomers of 4-Methoxy-3-Methyl-Phenethylamines Related to Methylenedioxymethamphetamine  

Science Journals Connector (OSTI)

......amine in 50 L of ethyl acetate followed by the addition...with 200 L of ethyl acetate and 50 L of pyridine. Results and Discussion Synthesis Condensation of the...upon reduction with lithium aluminum hydride (LAH...general procedure for the synthesis of these compounds begins......

Tamer Awad; C. Randall Clark; Jack DeRuiter

2007-09-01T23:59:59.000Z

357

Methods for the Differentiation of Methamphetamine from Regioisomeric Phenethylamines  

Science Journals Connector (OSTI)

......liquid chromatograph. Synthesis of N-ethyl- and N...pressure to Scheme 2. Synthesis of N-ethyl and N...to a suspen sion of lithium aluminum hydride (1...and the L C analysis. Synthesis of l-phenyl-2-aminobutane...m M o l ) , ammonium acetate (100 m M o l ) and......

F. Taylor Noggle; C. Randall Clark; Kamal H. Bouhadir; Jack DeRuiter

1991-01-01T23:59:59.000Z

358

GC—MS Analysis of Ring and Side Chain Regioisomers of Ethoxyphenethylamines  

Science Journals Connector (OSTI)

......amine in 50 L of ethyl acetate followed by addition...with 200 L of ethyl acetate and 50 L of pyridine...upon reduction with lithium aluminum hydride (LAH...general procedure for the synthesis of these compounds begins...R.F.X. Klein. Synthesis and characteriza- tion......

Tamer Awad; Jack DeRuiter; C. Randall Clark

2008-09-01T23:59:59.000Z

359

NOx Reduction from Biodiesel Fuels  

Science Journals Connector (OSTI)

NOx Reduction from Biodiesel Fuels ... NOx emissions appear to be different for biodiesels from different feedstocks. ... For the suite of biodiesels prepared from nearly pure fatty acids, all biodiesel fuels produced higher NOx than certification diesel with the following exceptions:? methyl palmitate, methyl laurate, ethyl stearate, and the ethyl ester of hydrogenated soybean oil. ...

Sandun Fernando; Chris Hall; Saroj Jha

2005-11-19T23:59:59.000Z

360

Evidence for high-temperature diffusional creep preserved by rapid cooling of lower crust (North Bohemian shear zone,  

E-Print Network (OSTI)

high-grade orthogneiss, migmatite and granulite (Zartner, 1929), largely covered by Tertiary volcanics´ , 1962). Gran- ulite has been drilled in bore holes and occurs in xenoliths of Tertiary basalts (Kopecky; Kotkova´ et al., 1996). A similar for- mation age has been derived from garnet peridotite from borehole T7

Dörr, Wolfgang

Note: This page contains sample records for the topic "mtbe ethyl tertiary" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

COAL RESOURCES, POWDER RIVER BASIN By M.S. Ellis,1  

E-Print Network (OSTI)

Chapter PN COAL RESOURCES, POWDER RIVER BASIN By M.S. Ellis,1 G.L. Gunther,2 A.M. Ochs,2 S, Delaware 1999 Resource assessment of selected Tertiary coal beds and zones in the Northern Rocky in the toolbar to return. 1999 Resource assessment of selected Tertiary coal beds and zones in the Northern Rocky

362

FORT UNION COAL IN THE GREATER GREEN RIVER BASIN, EAST FLANK OF THE ROCK SPRINGS UPLIFT,  

E-Print Network (OSTI)

Chapter GS FORT UNION COAL IN THE GREATER GREEN RIVER BASIN, EAST FLANK OF THE ROCK SPRINGS UPLIFT 1999 Resource assessment of selected Tertiary coal beds and zones in the Northern Rocky in the toolbar to return. 1999 Resource assessment of selected Tertiary coal beds and zones in the Northern Rocky

363

SHERIDAN COALFIELD, POWDER RIVER BASIN: GEOLOGY, COAL QUALITY, AND COAL RESOURCES  

E-Print Network (OSTI)

Chapter PH SHERIDAN COALFIELD, POWDER RIVER BASIN: GEOLOGY, COAL QUALITY, AND COAL RESOURCES By M assessment of selected Tertiary coal beds and zones in the Northern RockyMountains and Great Plains region, U Resource assessment of selected Tertiary coal beds and zones in the Northern Rocky Mountains and Great

364

Accommodation of a highly symmetric core within a symmetric protein superfold  

E-Print Network (OSTI)

threefold symmetry present in the tertiary structure of the protein fold (the -trefoil superfold factor; de novo design; superfold; protein evolution; -trefoil The protein-folding problem is one tertiary structures can be categorized into 1 of 10 fundamental protein folds (Orengo et al. 1994; Thornton

Blaber, Michael

365

Advanced quadrupole ion trap instrumentation for low level vehicle emissions measurements. CRADA final report for number ORNL93-0238  

SciTech Connect

Quadrupole ion trap mass spectrometry has been evaluated for its potential use in vehicle emissions measurements in vehicle test facilities as an analyzer for the top 15 compounds contributing to smog generation. A variety of ionization methods were explored including ion trap in situ chemical ionization, atmospheric sampling glow discharge ionization, and nitric oxide chemical ionization in a glow discharge ionization source coupled with anion trap mass spectrometer. Emphasis was placed on the determination of hydrocarbons and oxygenated hydrocarbons at parts per million to parts per billion levels. Ion trap in situ water chemical ionization and atmospheric sampling glow discharge ionization were both shown to be amenable to the analysis of arenes, alcohols, aldehydes and, to some degree, alkenes. Atmospheric sampling glow discharge also generated molecular ions of methyl-t-butyl ether (MTBE). Neither of these ionization methods, however, were found to generate diagnostic ions for the alkanes. Nitric oxide chemical ionization, on the other hand, was found to yield diagnostic ions for alkanes, alkenes, arenes, alcohols, aldehydes, and MTBE. The ability to measure a variety of hydrocarbons present at roughly 15 parts per billion at measurement rates of 3 Hz was demonstrated. These results have demonstrated that the ion trap has an excellent combination of sensitivity, specificity, speed, and flexibility with respect to the technical requirements of the top 15 analyzer.

McLuckey, S.A.; Buchanan, M.V.; Asano, K.G.; Hart, K.J.; Goeringer, D.E. [Oak Ridge National Lab., TN (United States); Dearth, M.A. [Ford Motor Co., Dearborn, MI (United States). Environmental Research Consortium

1997-09-01T23:59:59.000Z

366

Modeling Hydrolysis and Esterification Kinetics for Biofuel Processes  

Science Journals Connector (OSTI)

We determined the kinetics for ethyl oleate hydrolysis in high-temperature water and for the reverse reaction, oleic acid esterification, in near- and supercritical ethanol. Hydrolysis was clearly autocatalytic. The experimental data, from reactions at ...

Shujauddin Changi; Tanawan Pinnarat; Phillip E. Savage

2011-02-15T23:59:59.000Z

367

Alternative Fuels Data Center  

Alternative Fuels and Advanced Vehicles Data Center (EERE)

Ethanol Sales Tax Exemption The portion of ethanol (ethyl alcohol) sold and blended with motor fuel is exempt from sales tax. (Reference Oklahoma Statutes 68-500.10-1 and 68-1359...

368

Risk and benefit in environmental law  

Science Journals Connector (OSTI)

...67 : 729 ( 1979 ). RODGERS, W.H., HARD LOOK AT VERMONT YANKEE - ENVIRONMENTAL-LAW UNDER CLOSE SCRUTINY, GEORGETOWN...Cir., 1975) (low-level radiation from Maine Yankee plant acceptable). 16. Ethyl Corp. v. EPA, 541...

PF Ricci; LS Molton

1981-12-04T23:59:59.000Z

369

CO2-limitation-inducible Green Recovery of fatty acids from cyanobacterial biomass  

Science Journals Connector (OSTI)

...other microbial bioreactors such as algae, E. coli, and yeast...fatty acyl methyl, or ethyl esters (biodiesel), and alkanes...Green Recovery is introduced into algae. Fig. S1. One fluorescence microscopy...

Xinyao Liu; Sarah Fallon; Jie Sheng; Roy Curtiss III

2011-01-01T23:59:59.000Z

370

HPLC analysis of tonka bean extracts  

Science Journals Connector (OSTI)

Based on the results of GC-MS analysis, an HPLC procedure was developed for the determination of coumarin, dihydrocoumarin, melilotic acid (o...-dihyd-rocoumaric acid), methyl melilotate, ethyl melilotate, 5-hydroxymethylfurfural

Dorothea Ehlers; Michael Pfister…

1995-01-01T23:59:59.000Z

371

Cyanide Assay: Statistical Comparison of a New Gas Chromatographic Calibration Method versus the Classical Spectrophotometric Method  

Science Journals Connector (OSTI)

......spectrophotometric method (VIS) is linear from...Figure1. Chromatogramof hydrogen cyanide(HCN). o...HCY-a~5 Scheme1. Hydrogen cyanide production from ethyl thiocyano...coefficientfor both methods exceeded0.99, which......

Z.L. Cardeal; J.P. Gallet; A. Astier; D. Pradeau

1995-01-01T23:59:59.000Z

372

Synthesis and characterization of transparent silica-based aerogels using methyltrimethoxysilane precursor  

Science Journals Connector (OSTI)

Silica-based aerogels with high transparency and high bending strength were prepared using methyltrimethoxysilane and non-ionic surfactant under supercritical drying condition of CO2. Non-ionic surfactant, ethyle...

Masayuki Nogami; Shohei Hotta…

2010-11-01T23:59:59.000Z

373

Life-cycle Assessment of Semiconductors  

E-Print Network (OSTI)

of isopropyl alcohol (IPA), CO, NO X , ethyl lactate andHMDS: hexa-methyl disilizane IPA: isopropyl alcohol OMCTS:liquid H 2 SO 4 HCl NH 4 OH IPA oxide CMP slurry, chemicals

Boyd, Sarah B.

2009-01-01T23:59:59.000Z

374

Influence of organic salt concentration on the performance of bulk heterojunction organic solar cell  

Science Journals Connector (OSTI)

The effect of organic salt on the performance of bulk heterojunction organic solar cell was investigated by varying the concentration of...6). Organic solar cells based on TBAPF6-blended poly[2-methoxy-5-(2-ethyl...

Nasehah Syamin Sabri; Chi Chin Yap…

2013-07-01T23:59:59.000Z

375

The effect of die geometry on extruded paste flow for continuous production of pharmaceutical tablets  

E-Print Network (OSTI)

The design of an extruder-based continuous tablet forming process of a sample active pharmaceutical ingredient (API) and ethyl acetate requires a device to form and compress the tablets. The flow of the wet extrusion is ...

Nagaraj, Aditi

2011-01-01T23:59:59.000Z

376

Theoretical and experimental study on surface tension and dynamic surface tension of aqueous lithium bromide and water with additive  

Science Journals Connector (OSTI)

The surface tensions of water and aqueous lithium bromide (LiBr) with 2-ethyl-1- ... that surface tension varies linearly with the surface excess concentration is advanced, which could overcome the...

Wenlong Cheng; Zeshao Chen; Atsushi Akisawa…

2003-04-01T23:59:59.000Z

377

Pyrolysis—Gas Chromatography: A Bibliography (1960–1963)  

Science Journals Connector (OSTI)

......THE PYROLYSIS OF TOULENE, Price, S. J., Can. J. Chem...CHROMATOGRAPHIC ANALYSIS OF POLY(ETHYLENE ETHYLACRYLATE) AND POLY(ETHYLENE VINYL ACETATE) PYROLY- SATES...CHROMATOGRAPHIC ANALYSIS OF POLY(ETHYLENE ETHYL ACRYLATE) AND POLY......

R. W. McKinney

1964-12-01T23:59:59.000Z

378

AWARDS:  

Science Journals Connector (OSTI)

......include polymer of phthalic anhydride, ethylene glycol, heptanol, and 2-ethyl- hexanol...1-decanol; polymer of phthalic anhydride, ethylene glycol, heptanol, 1-decanol, and...Outstanding performance. Remarkably low price. The C-160 is much more than a basic......

Awards

1980-06-01T23:59:59.000Z

379

NEWS:  

Science Journals Connector (OSTI)

......include polymer of phthalic anhydride, ethylene glycol, heptanol, and 2-ethyl- hexanol...1-decanol; polymer of phthalic anhydride, ethylene glycol, heptanol, 1-decanol, and...Outstanding performance. Remarkably low price. The C-160 is much more than a basic......

News

1980-06-01T23:59:59.000Z

380

Plant Disease / July 2014 937 Sensitivity of Pythium irregulare, P. sylvaticum, and P. ultimum from Forest  

E-Print Network (OSTI)

and phosphorous acid consistently provided good protection against damping-off caused by P. dissotocum, P, phosphonates such as fosetyl-Al (aluminum tris-O-ethyl phosphonate) or phosphorous acid are used (J. Weiland

Grünwald, Niklaus J.

Note: This page contains sample records for the topic "mtbe ethyl tertiary" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Thermal instabilities of organic carbonates with discharged cathode materials in lithium-ion batteries  

Science Journals Connector (OSTI)

Thermal instability of lithiated cathode materials with organic...4, LiMn2O4, and LiCoO2...were mixed with diethyl carbonate, dimethyl carbonate, ethylene carbonate, ethyl methyl carbonate, and propylene carbonat...

Wei-Jie Ou; Chen-Shan Kao; Yih-Shing Duh…

2014-06-01T23:59:59.000Z

382

Carbon-Catalyzed Gasification of Organic Feedstocks in Supercritical Water  

Science Journals Connector (OSTI)

Feedstocks studied in this paper include glycerol, glucose, cellobiose, whole biomass feedstocks (depithed bagasse liquid extract and sewage sludge), and representative Department of Defense (DoD) wastes (methanol, methyl ethyl ketone, ethylene glycol, acetic acid, and phenol). ...

Xiaodong Xu; Yukihiko Matsumura; Jonny Stenberg; Michael Jerry Antal, Jr.

1996-08-08T23:59:59.000Z

383

Fruit flies learn to avoid odours associated with virulent infection  

Science Journals Connector (OSTI)

...induced by ingestion or injection of toxic compounds, such as lithium chloride, alkaloids or glycosides, or immune elicitors...odours and comparing their choice between these odours. Amyl acetate (AA) and ethyl hexanoate (EH) were used as odorants; these...

2014-01-01T23:59:59.000Z

384

Excited state intramolecular charge transfer reaction in nonaqueous electrolyte solutions: Temperature dependence  

E-Print Network (OSTI)

intramolecular charge transfer reaction of 4- 1-azetidinyl benzonitrile P4C in ethyl acetate EA , acetonitrile ACN , and ethanol at several concentrations of lithium perchlorate LiClO4 has been investigated

Biswas, Ranjit

385

J. Chem. Sci. Vol. 123, No. 3, May 2011, pp. 265277. c Indian Academy of Sciences. Excited state charge transfer reaction in (mixed solvent + electrolyte)  

E-Print Network (OSTI)

-propanol + ethyl acetate) and (propylene carbonate + acetonitrile), in the absence and presence of a strong electrolyte, lithium perchlorate. These two sets of mixed solvent systems represent binary solvent mixtures

Biswas, Ranjit

386

E-Print Network 3.0 - acid hydrazone dpktch Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

4865 solution of the acid 17 (250 mg, 0.79 mmol) in THF (15... (silica gel, ethyl acetate as eluant) to obtain the acid 24 (67 mg, 61%) as colorless crystals: mp 168... in the...

387

This Week In Petroleum Printer-Friendly Version  

Gasoline and Diesel Fuel Update (EIA)

ways in which the chemical reaction is implemented. For example, using ethanol instead of methanol as the alcohol would generate a fatty acid ethyl ester (FAEE), which is more...

388

Permanently charged tamoxifen derivatives: Chemical characterization, transcriptional activity, and biological effects  

Science Journals Connector (OSTI)

...methyl iodide, methyl bromide, ethyl bromide, isopropyl bromide, propyl bromide and butyl bromide) were obtained by SN2 reaction. Chemical structures were determined by NMR, electron microscopy and X-Ray diffraction. Biological effects: Binding...

Claudia Rivera Guevara; Rocio Garcia; Fernando Larrea; Martha S. Morales-Rios; Elizabeth Hermandez-Gallegos; David Barrera; Sandra Valencia; Victor Perez; and Javier Camacho

2007-11-01T23:59:59.000Z

389

Supplemental Material for Spessard and Stoltz 1 Supplemental Materials for  

E-Print Network (OSTI)

% yield) that was used without further purification. RF = 0.5 (30% ethyl acetate in hexanes eluent); FTIR, 29.18 mmol, 1.0 equiv) in dry THF (100 mL) was added methyl lithium (34 mL, 1.3 M in Et2O, 43.77 mmol was purified by silica gel chromatography (10% ethyl acetate in hexanes eluent) to afford enone 12 as a yellow

Stoltz, Brian M.

390

Before enzymes and templates: theory of surface metabolism.  

Science Journals Connector (OSTI)

...52, No. 4 MICROBIOLOGICAL REVIEWS, Dec. 1988, p. 452-484...480 LITERATURE CITED...This tertiary source of bioenergy is at first dependent on the...been of immeasurable value. LITERATURE CITED 1. Acevedo, 0. L...

G Wächtershäuser

1988-12-01T23:59:59.000Z

391

The VP4 Peptide of Hepatitis A Virus Ruptures Membranes through Formation of Discrete Pores  

Science Journals Connector (OSTI)

...predicted using Bhageerath-H (a homology ab initio hybrid web server for protein tertiary structure prediction) (22 - 26...D Sahu, and V Pandey. 2006. Bhageerath: an energy based web enabled computer software suite for limiting the search space...

Ashutosh Shukla; Aditya K. Padhi; James Gomes; Manidipa Banerjee

2014-08-13T23:59:59.000Z

392

Deformation, erosion and sedimentation in collisional orogens : case studies from eastern Tibet and southwestern China  

E-Print Network (OSTI)

This dissertation addresses aspects of the tectonics of regions adjacent to the eastern Himalayan syntaxis. The first chapter describes the Tertiary Gonjo basin, includes structural and sedimentologic observations, and ...

Studnicki-Gizbert, Christopher Terrance

2006-01-01T23:59:59.000Z

393

We offer a full range of surgical expertise. Bariatric Surgery  

E-Print Network (OSTI)

CARE MARS Medical Access and Referral System 800-WVA-MARS 800-982-6277 24-hour, 7-day per week are a major tertiary referral center for the region and state, offering the highest level of clinical

Mohaghegh, Shahab

394

Petroleum Supply Monthly  

Gasoline and Diesel Fuel Update (EIA)

or pipeline. Tertiary inventories are held by end users and include fuel in vehicle tanks, heating oil in residential tanks, fuel oil held by utilities, jet fuel stored in...

395

On the Fossil Algae of the Petroleum-Yielding Shales of the Green River Formation of Colorado and Utah  

Science Journals Connector (OSTI)

...georef/georef;1975057021 algae biostratigraphy Cenozoic Colorado Eocene Green River Formation microfossils occurrence oil shale organic residues paleobotany Paleogene Plantae sedimentary rocks Tertiary United States Utah GeoRef, Copyright 2004...

Charles A. Davis

1916-01-01T23:59:59.000Z

396

E-Print Network 3.0 - atlantic igneous province Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

modied from White and McKenzie 1. Also... 70 My prior to the Tertiary eruption of CFB of ... Source: Johnston, Stephen T. - School of Earth and Ocean Sciences, University of...

397

Pediatric Intestinal Failure Associated Liver Disease is Revered with Six Months of Intravenous Fish Oil  

E-Print Network (OSTI)

3. Secondary and tertiary outcomes for the fish oil (FO)and soybean oil (SO) group. Results are either as medianserror of the mean for the fish oil (FO) and soybean oil (SO)

Calkins, Kara

2013-01-01T23:59:59.000Z

398

Optimizing hysteretic power loss of magnetic ferrite nanoparticles  

E-Print Network (OSTI)

This thesis seeks to correlate hysteretic power loss of tertiary ferrite nanoparticles in alternating magnetic fields to trends predicted by physical models. By employing integration of hysteresis loops simulated from ...

Chen, Ritchie

2013-01-01T23:59:59.000Z

399

E-Print Network 3.0 - azeite transtensional shear Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

> >> Page: << < 1 2 3 4 5 > >> 41 Tertiary Evolution of the Three Pagodas Fault, Western Thailand Summary: ductile left-lateral shear zone in a transpressional environment as it...

400

E-Print Network 3.0 - aliphatic alkyl quaternaries Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

to almost... (e.g. Ar-Cl, tertiary amine, quaternary amine) NuH R'R"NH 11CCarbon Monoxide - In ring closure... is a nucleophilic subsitition of bisulfite by 11Ccyanide ion...

Note: This page contains sample records for the topic "mtbe ethyl tertiary" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Mechanisms Controlling Phosphorus Retention Capacity in Freshwater Wetlands  

Science Journals Connector (OSTI)

...Wetlands tested as wastewater filtration systems...HOOK, J.E., RECYCLING TREATED MU 148...WETLANDS AS A TERTIARY WASTEWATER-TREATMENT ALTERNATIVE...E. Sopper, in Recycling Treated Municipal Wastewater and Sludge Through...

CURTIS J. RICHARDSON

1985-06-21T23:59:59.000Z

402

Geranic Acid Formation, an Initial Reaction of Anaerobic Monoterpene Metabolism in DenitrifyingAlcaligenes defragrans  

Science Journals Connector (OSTI)

...transformation of a tertiary allylalchol: regioselective isomerisation of linalool to geraniol without nerol formation. . S. Fobeta...alkenoic monoterpenes (()-menthene, a-pinene, 2-carene and a-phellandrene) and nitrate. . G. Fuchs Novel reactions...

Udo Heyen; Jens Harder

2000-07-01T23:59:59.000Z

403

Eocene cooling linked to early flow across the Tasmanian Gateway  

Science Journals Connector (OSTI)

...gradients between oceanic basins lend additional support for increased...Malone MJ ( 2000 ) Great Australian Bight—Cenozoic cool-water...Tertiary of the Gippsland Basin, Victoria . APEA J...Malone MJ (2000) Great Australian Bight--Cenozoic...

Peter K. Bijl; James A. P. Bendle; Steven M. Bohaty; Jörg Pross; Stefan Schouten; Lisa Tauxe; Catherine E. Stickley; Robert M. McKay; Ursula Röhl; Matthew Olney; Appy Sluijs; Carlota Escutia; Henk Brinkhuis; Expedition 318 Scientists

2013-01-01T23:59:59.000Z

404

Membrane Bioreactors: Past, Present and Future?  

E-Print Network (OSTI)

Treatment, Elsevier King County Brightwater WastewaterJudd and Judd, 2006 ], King County, WA, USA (136,000 m3 /d in 2011) [King County] and tertiary treatment at

Hermanowicz, Slav W

2011-01-01T23:59:59.000Z

405

[superscript 15]N-[superscript 15]N Proton Assisted Recoupling in Magic Angle Spinning NMR  

E-Print Network (OSTI)

We describe a new magic angle spinning (MAS) NMR experiment for obtaining [superscript 15]N?[superscript 15]N correlation spectra. The approach yields direct information about the secondary and tertiary structure of proteins, ...

Lewandowski, Jozef R.

406

CX-007922: Categorical Exclusion Determination  

Energy.gov (U.S. Department of Energy (DOE))

Game Changing Technology of Polymeric-Surfactants for Tertiary Oil CX(s) Applied: A9, B3.6 Date: 02/23/2012 Location(s): California Offices(s): National Energy Technology Laboratory

407

CX-007928: Categorical Exclusion Determination  

Energy.gov (U.S. Department of Energy (DOE))

Game Changing Technology of Polymeric-Surfactants for Tertiary Oil CX(s) Applied: A9, B3.6 Date: 02/22/2012 Location(s): Indiana Offices(s): National Energy Technology Laboratory

408

Geological Development of Panama  

Science Journals Connector (OSTI)

The Panama that geologists see today is a young ... /early Tertiary time. The geological development of Panama is a consequence of the relative motions ... igneous rocks that comprise much of present-day Panama f...

Russell S.Harmon

2005-01-01T23:59:59.000Z

409

Salt deformation history and postsalt structural trends, offshore southern Gabon, West Africa  

SciTech Connect

Salt deformation in offshore southern Gabon is represented by mobilization of an Aptian salt layer in reaction to Tertiary clastic progradation. Seismic mapping of salt bodies and associated faulting has resulted in increased understanding of the types and distribution of these salt bodies, their associated faulting patterns, and some aspects of their origin. Away from the Tertiary depocenter, the growth history of salt swells or pillows can be determined by examining onlapping and draping seismic reflectors. Significant Tertiary clastic progradation into the area mobilized the salt and resulted in a series of linear, deep salt walls and asymmetric, basinward-dipping salt rollers, commonly associated with significant up-to-basin faulting dominates the southern Gabon subbasin. The expansion history of associated sediments suggests that these faults expanded episodically throughout the Tertiary, continuing to present-day bathymetric fault scarps. The bias toward up-to-basin faults, to the apparent exclusion of down-to-basin expansion faults, remains enigmatic.

Liro, L.M. [Texaco Exploration and Production Technology Dept., Houston, TX (United States); Coen, R. [British Gas, Houston, TX (United States)

1996-12-31T23:59:59.000Z

410

Gabon, Congo, Cabinda and Zaïre  

Science Journals Connector (OSTI)

The combined coastline of Gabon, Congo, Cabinda (a separate province of...1985...). It forms the oceanic boundary of two Mesozoic and Tertiary sedimentary basins, those of Gabon and the Congo, which are separated...

P. Giresse

2010-01-01T23:59:59.000Z

411

Palaeobotanical studies from tropical Africa: relevance to the evolution of forest, woodland and savannah biomes  

Science Journals Connector (OSTI)

...time interval coincides with the Eocene thermal maximum, a time of warm temperatures...Morley 2000; Sloan & Rea 1995). The thermal budget and dynamics of the hydrological...Tertiary nonmarine sediments of central Sudan. Palynology 13, 7990. Kedves, M...

2004-01-01T23:59:59.000Z

412

Evidence for Large-Scale Laramide Tectonic Inversion and a Mid...  

Open Energy Info (EERE)

Scale Laramide Tectonic Inversion and a Mid-Tertiary Caldera Ring Fracture Zone at the Lightning Dock Geothermal System, New Mexico Jump to: navigation, search OpenEI Reference...

413

Detection of Radon Emission at the Edges of Lunar Maria with the Apollo Alpha-Particle Spectrometer  

Science Journals Connector (OSTI)

...ecological balance away from...by advanced wastewater treatment. Both wastewater...tertiary sewage treatment or change...Physiol. Plant. 23, 828...Both advanced wastewater treatment and 1 FEBRUARY...bombardment or mass slumping...

Paul Gorenstein; Leon Golub; Paul Bjorkholm

1974-02-01T23:59:59.000Z

414

Protein folding and macromolecular dynamics : fundamental limits of length and time scales.  

E-Print Network (OSTI)

??In this thesis, physics-based models of protein folding at the secondary and tertiary level are developed to resolve long-standing issues of protein folding kinetics. As… (more)

Lin, Milo M.

2012-01-01T23:59:59.000Z

415

Adding a Medical Lexicon to an English Parser Peter Szolovits, PhD  

E-Print Network (OSTI)

in the Emergency Department of a large urban tertiary care pediatric hospital (ED), the Link Grammar Parser (LP) [3 summaries, radiology and pathology notes, etc., are nevertheless stored simply as text. 2 This assumes

Szolovits, Peter

416

Volcanology  

Science Journals Connector (OSTI)

...now appears, how-ever, that such heating is probably relatively unimportant...Richey, Scotland: The Tertiary Volcanic Districts (His Majesty's Stationery Office...made by Samuel Strauss, lately of the District of Co-lumbia public school system...

Gordon A. MacDonald

1961-03-10T23:59:59.000Z

417

Tectonic Evolution of the Contaya Arch Ucyali Basin, Peru  

E-Print Network (OSTI)

after deposition of the Pozo Formation sands and shales. To the east of this is the Contaya high. This structure originally formed during the Triassic-Jurassic and was later reactivated in the Tertiary. The easternmost structure, the Moa divisor...

Navarro Zelasco, Luis

2011-08-08T23:59:59.000Z

418

Large Hadron Collider commissioning and first operation  

Science Journals Connector (OSTI)

...systems [4], including the collimation system [5], are crucial in the...finalizing the protection. The collimation system [5] is part of the machine...machine. The hierarchy of the collimation system (primary, secondary and tertiary...

2012-01-01T23:59:59.000Z

419

"Simple paperwork made applying for a loan very easy."  

E-Print Network (OSTI)

Commission Public Programs Office (916) 654-4147 pubprog@energy.state.ca.us See Case Study on Back of Flyer at the adjacent wastewater treatment plant. Recently the city upgraded the plant to tertiary wastewater treatment

420

E-Print Network 3.0 - asymmetric horner-wadsworth-emmons reactions...  

NLE Websites -- All DOE Office Websites (Extended Search)

an Ireland-Claisen rearrangement to install the C7 tertiary alcohol stereocenter, an SN2 reaction... nucleo- phile.14 SN2 reactions of alkoxyalkyl Cu nucleophiles are not well...

Note: This page contains sample records for the topic "mtbe ethyl tertiary" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Equilibrium and hydrodynamic studies of water extraction from fermentation broth  

E-Print Network (OSTI)

Previous studies using tertiary amines to extract water from reagent-grade carboxylate salts (calcium acetate, propionate, and butyrate) have shown selectivity for water and not for the carboxylate salts. These results allow the design...

Adorno-Gomez, Wilberto

2012-06-07T23:59:59.000Z

422

GEOLOGY AND HYDROTHERMAL ALTERATION OF THE RAFT RIVER GEOTHERMAL...  

Open Energy Info (EERE)

the base of the Tertiary deposits in RRG-9. The results of thermal and quasi-static mechanical property measurements that were conducted on the core sample are presented. Authors...

423

Petrology of clinopyroxene-amphibole inclusions from the roque nublo volcanics, gran canaria, canary islands  

Science Journals Connector (OSTI)

Inclusions consisting of clinopyroxene, amphibole, Fe-Ti oxides and apatitc are abundant in the Roque Nublo volcanics, a unit of Late Tertiary age that is widespread on Gran Canaria Island. The unit includes alka...

T. Frisch; H. U. Schmincke

1969-01-01T23:59:59.000Z

424

Enhanced Oil Recovery Using the Alkaline-Surfactant-Polymer (ASP)  

E-Print Network (OSTI)

Alkaline Surfactant Polymer (ASP) process is a tertiary method of oil recovery that has promising results for future development. It has already been implemented in different areas of the United States such as Wyoming, west Texas, also in Canada...

Musharova, Darya

2010-07-14T23:59:59.000Z

425

Surfactant-Polymer Interaction for Improved Oil Recovery  

SciTech Connect

The goal of this research was to use the interaction between a surfactant and a polymer for efficient displacement of tertiary oil by improving slug integrity, oil solubility in the displacing fluid and mobility control. Surfactant-polymer flooding has been shown to be highly effective in laboratory-scale linear floods. The focus of this proposal is to design an inexpensive surfactant-polymer mixture that can efficiently recover tertiary oil by avoiding surfactant slug degradation and viscous/heterogeneity fingering.

Gabitto, Jorge; Mohanty, Kishore K.

2002-01-07T23:59:59.000Z

426

Range Con: a management evaluation system for assessing sucess of selected range improvement practices  

E-Print Network (OSTI)

interview, and 80 identified agency/academic and rancher tertiary experts interviewed with a questionnaire. Responses from the tertiary experts were used to assign weight to values of the object/attribute/value triplet. Face validation procedures... success he assigned to the evaluation due to his greater level of knowledge associated with the technology. Range management experts experience the same processes, which often leads them to recommend technology to ranchers that exceeds the ranchers...

Ekblad, Steven Linn

2012-06-07T23:59:59.000Z

427

Cenozoic evidence of displacements along the Meers Fault, southwestern Oklahoma  

E-Print Network (OSTI)

which had been deposited over this Tertiary surface. The remnant pediment surfaces in the Wichita Mountains may then be used as a relative datum horizon in interpreting Tertiary and younger displacements within the region. ACKNOWLEDGEMENTS I would...) Schematic diagram of the Pointer Site Excavations 34 36 10 A) The buried soil and caliche-clay deposits exhibiting plane of compaction between the upper- and lower-orange deposits. 8) Close-up of caliche-clay deposit. . . . . . 38 Photograph comparing...

Kientop, Gregory Allen

2012-06-07T23:59:59.000Z

428

Shallow meteoric alteration and burial diagenesis of massive dolomite in the Castle Reef Formation, northwest Montana  

E-Print Network (OSTI)

Precambrian (750 + 25 Ma; Mudge, et al. , 1968) and very Late Cretaceous to early Tertiary (Mudge, 1972). Any formation or recrystallization of dolomite by hydrothermal fluids must have occurred before the Jurassic since pre-Jurassic dolomite overgrowths... Precambrian (750 + 25 Ma; Mudge, et al. , 1968) and very Late Cretaceous to early Tertiary (Mudge, 1972). Any formation or recrystallization of dolomite by hydrothermal fluids must have occurred before the Jurassic since pre-Jurassic dolomite overgrowths...

Whitsitt, Philip Mark

2012-06-07T23:59:59.000Z

429

Ditertiary butyl peroxide recovery  

SciTech Connect

A process is described wherein a feed material comprising significant amounts of tertiary butyl hydroperoxide and tertiary butyl alcohol and minor amounts of ditertiary butyl peroxide and other impurities is charged to a reactor together with propylene and a soluble epoxidation catalyst. At least a portion of the tertiary butyl hydroperoxide is reacted in the reactor with the propylene to form a reaction product composed of unreacted feed components, propylene oxide, an additional quantity of tertiary butyl alcohol, and impurities, including a minor amount of ditertiary butyl peroxide. The improvement for recovering substantially pure ditertiary butyl peroxide from the reaction product after the reaction product is discharged from the reactor comprises the steps of: charging the reaction product to a first distillation zone and separating therein a first unreacted propylene distillate recycle fraction, charging the remaining heavier components of the reaction product from the first distillation zone to a second distillation zone and separating a second propylene oxide distillate product fraction therein charging the heavier components from the second distillation zone to a third distillation zone and separating a third distillate fraction comprising a major amount of tertiary butyl alcohol and a minor amount of ditertiary butyl peroxide, and recovering the second propylene oxide distillate fraction, the heavier tertiary butyl alcohol product fraction and the ditertiary butyl peroxide raffinate fraction.

Sanderson, J.R.; Meyer, R.A.; Smith, W.A.; Marquis, E.T.

1989-03-07T23:59:59.000Z

430

Slide 1  

U.S. Energy Information Administration (EIA) Indexed Site

Howard Gruenspecht Howard Gruenspecht Deputy Administrator Energy Information Administration 2008 Energy Conference 30 Years of Energy Information and Analysis Washington, DC April 7, 2008 EIA's Mission and Budget: Priority-Setting in the Short Run EIA is the Primary Activity Within DOE Concerned with Current Energy Markets and Issues * When energy issues are front and center, the Nation looks to the Department of Energy to interpret the current energy market situation * EIA is the main DOE entity involved in current energy markets and issues * In many settings, such as the situation following the 2005 hurricanes, the MTBE/ethanol transition in the spring of 2006, and the current oil price increases, both the Congress and the Administration directly rely on and benefit from EIA's role as a trusted source of energy information and

431

Annual Energy Outlook 2001 - Legislation and Regulations  

Gasoline and Diesel Fuel Update (EIA)

Legislation & Regulations Legislation & Regulations Nitrogen Oxide Emission Caps Heavy-Duty Vehicle Emissions and Diesel Fuel Quality Standards FERC Order 2000 Banning or Reducing the Use of MTBE in Gasoline Updates on State Renewable Portfolio Standards and Renewable Energy Mandates Proposed Changes to RFG Oxygen Standard FERC Order 637 Proposed Limits on Benzene in Gasoline Royalty Rules Low-Emission Vehicle Program Tier 2 Vehicle Emissions and Gasoline Sulfur Standards Appliance Efficiency Standards Petroleum Reserves Introduction Because analyses by the Energy Information Administration (EIA) are required to be policy-neutral, the projections in this Annual Energy Outlook 2001 (AEO2001) are based on Federal, State, and local laws and regulations in effect on July 1, 2000. The potential impacts of pending or

432

Environmental Regulations and Changes in Petroleum Refining Operations  

Gasoline and Diesel Fuel Update (EIA)

Environmental Regulations and Environmental Regulations and Changes in Petroleum Refining Operations By Tancred C.M. Lidderdale Contents * Introduction * Motor Gasoline Summer Volatility (RVP) Regulations o Table 1. Summer Volatility Regulations for Motor Gasoline o Table 2. Refinery Inputs and Production of Normal Butane o Figure 1. Refinery Inputs and Production of Normal Butane o Table 3. Price Relationship Between Normal Butane and Motor Gasoline o Table 4. Market Price Premium for Low Vapor Pressure (RVP) Gasoline * Oxygenate Content of Motor Gasoline o Figure 2. Oxygenate Content of Motor Gasoline o Table 5. Oxygenated and Conventional Motor Gasoline Price Relationship o Table 6. Reformulated and Conventional Motor Gasoline Price Relationship o Figure 3. Price Differences Between RFG or MTBE and Conventional Gasoline

433

Net Imports of Total Crude Oil and Products into the U.S. by Country  

U.S. Energy Information Administration (EIA) Indexed Site

Product: Total Crude Oil and Products Crude Oil Products Pentanes Plus Liquefied Petroleum Gases Unfinished Oils Finished Motor Gasoline Reformulated Conventional Motor Gasoline Blending Components Reformulated Gasoline Blend. Comp. Conventional Gasoline Blend. Comp. MTBE (Oxygenate) Other Oxygenates Fuel Ethanol (Renewable) Biomass-Based Diesel Other Renewable Diesel Other Renewable Fuels Distillate Fuel Oil Distillate F.O., 15 ppm and under Distillate F.O., 15 to 500 ppm Distillate F.O., 500 to 2000 ppm Distillate F.O., Greater than 2000 ppm Kerosene Finished Aviation Gasoline Kerosene-Type Jet Fuel Special Naphthas Residual Fuel Oil Naphtha for Petrochem. Feed. Use Other Oils for Petrochem. Feed. Use Waxes Petroleum Coke Asphalt and Road Oil Lubricants Miscellaneous Products Period-Unit: Monthly-Thousand Barrels per Day Annual-Thousand Barrels per Day

434

Microsoft Word - rfsreport.doc  

Gasoline and Diesel Fuel Update (EIA)

6 6 Impact of Renewable Fuels Standard/MTBE Provisions of S. 1766 March 2002 This Service Report was prepared by the Energy Information Administration, the independent statistical and analytical agency within the Department of Energy. The information contained herein should be attributed to the Energy Information Administration and should not be construed as advocating or reflecting any policy position of the Department of Energy or of any other organization. Service Reports are prepared by the Energy Information Administration upon special request and are based on assumptions specified by the requestor. ii Contacts This report was prepared by the staff of the Office of Integrated Analysis and Forecasting of the Energy Information Administration. General questions concerning the report may be directed to Mary J. Hutzler (202/586-2222, mhutzler@eia.doe.gov), Director,

435

Annual Energy Outlook 2001 - Issues in Focus  

Gasoline and Diesel Fuel Update (EIA)

Issues in Focus Issues in Focus Macroeconomic Forecasting with the Revised National Income and Product Accounts (NIPA) Phasing Out MTBE in Gasoline World Oil Demand and Prices Distributed Electricity Generation Resources Natural Gas Supply Availability Restructuring of State Retail Markets for Electricity Carbon Dioxide Emissions in AEO2001 Macroeconomic Forecasting with the Revised National Income and Product Accounts (NIPA) The NIPA Comprehensive Revision Economic activity is a key determinant of growth in U.S. energy supply and demand. The derivation of the forecast of economic activity is therefore a critical step in developing the energy forecast presented in the Annual Energy Outlook 2001 (AEO2001). In turn, the forecast of economic activity is rooted fundamentally in the historical data series maintained by a

436

No Slide Title  

Gasoline and Diesel Fuel Update (EIA)

and Summer Fuels Outlook Guy Caruso Administrator, Energy Information Administration 2006 Summer Transportation Fuels Outlook Conference April 11, 2006 Washington, DC Several Key Factors Drive the Short-Term Fuels Forecast 1) Rising world oil consumption; 2) Low global surplus production capacity and tight crude oil supply relative to demand; 3) Supply concerns in international oil markets (such as in Nigeria, Iraq, and Iran); 4) The challenges of:  Stricter sulfur standards under the Tier 2 Gasoline program;  MTBE phase-out;  A shift to ultra low sulfur diesel. All these factors contribute to higher prices for petroleum products, particularly in the coming months. World Oil Consumption Growth Slowed in 2005; Projected to Increase in 2006-2007 Source: EIA, Short-Term Energy Outlook, April 2006

437

Gulf Coast (PADD 3) Total Crude Oil and Products Imports  

U.S. Energy Information Administration (EIA) Indexed Site

MTBE (Oxygenate) Other Oxygenates Fuel Ethanol (Renewable) Biomass-Based Diesel (Renewable) Other Renewable Diesel Distillate Fuel Oil Distillate F.O., 15 ppm and under Distillate F.O., 15 to 500 ppm Distillate F.O., Greater than 500 ppm Distillate F.O., 501 to 2000 ppm Distillate F.O., Greater than 2000 ppm Kerosene Finished Aviation Gasoline Aviation Gasoline Blending Components Kerosene-Type Jet Fuel Special Naphthas Residual Fuel Oil Residual F.O., Less than 0.31% Sulfur Residual F.O., 0.31 to 1% Sulfur Residual F.O., Greater than 1% Sulfur Naphtha for Petrochem. Feed. Use Other Oils for Petrochem. Feed. Use Waxes Petroleum Coke Asphalt and Road Oil Lubricants Miscellaneous Products Period/Unit: Monthly-Thousand Barrels Monthly-Thousand Barrels per Day Annual-Thousand Barrels Annual-Thousand Barrels per Day

438

Environmental Energy Technologies Division News  

NLE Websites -- All DOE Office Websites (Extended Search)

2000: 2000: Vol. 2, No. 1 Electrochromic Window Tests in U.S. Office Show Promise CLASP Helps Developing Nations Implement Energy Standards EETD Scientists Aid Research Efforts Leading to MTBE Ban Power Outage Study Team Examines Electricity Reliability Research Highlights Sources and Credits PDF of EETD News Electrochromic Window Tests in U.S. Office Show Promise Electrochromic glazings promise to be the next major advance in energy-efficient window technology, helping to achieve the goal of transforming windows and skylights from an energy liability in buildings to an energy source for the nation's building stock. The glazing can be reversibly switched from clear to a transparent, colored state by applying a low voltage, resulting in dynamically controllable thermal and optical

439

Why sequence ethene and vinyl chloride-oxidizing Mycobacterium strains?  

NLE Websites -- All DOE Office Websites (Extended Search)

sequence ethene and vinyl sequence ethene and vinyl chloride-oxidizing Mycobacterium strains? Mycobacteria are known for causing human and animal diseases but they are also important degraders of hard-to-break-down water contaminants such as polyaromatic hydrocarbons (PAHs) and methyl tert-butyl ether (MTBE). So far the handful of bacterial species representing the Mycobacterium genus that have been sequenced all break down PAHs. In this project, researchers focus on the genomes of mycobacterial species isolated from soil, freshwater and marine environments that use the alkene compounds ethene and vinyl chloride as carbon sources. Chlorinated ethene compounds are difficult to remove from contaminated groundwater but necessary because of their toxicity. Additionally these compounds reduce the ozone levels in the atmosphere.

440

Influence of the nature of FCC feed on the production of light olefins by catalytic cracking  

SciTech Connect

The 1990 Clean Air Act has act rules for gasoline reformulation, which requires major compositional changes, Including a higher contribution of oxygenated compounds to the gasoline pool. This explains why FCC units are expected to play a major role in the coming years as a producer of light olefins (propylene, butenes and amylenes) to be used as feedstock for oxygenate (MTBE/TAME) production. The impact of the nature of FCC feedstock on light olefins production (C3 to C5 olefins) has been studied using a MAT unit running at various operating conditions (C/O ratio, reactor temperature). Paraffinic feeds are potentially efficient to produce light olefins by catalytic cracking. Heavier paraffinic feeds like mixtures VGO + reside and pure reside have also been evaluated, and compared to naphthenic and aromatic feeds.

Chapus, Th.; Cauffriez, H.; Marcilly, Ch. [Institut Francais du Petrole, Rueil-Malmaison (France)

1996-10-01T23:59:59.000Z

Note: This page contains sample records for the topic "mtbe ethyl tertiary" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Catalytic distillation extends its reach  

SciTech Connect

Since the early 1980s, catalytic distillation processes have been selected by more than a hundred operators for various applications. Since such a unit performs both reaction and distillation simultaneously, a combined column can replace a separate, fixed-bed reactor and distillation column, thereby eliminating equipment and reducing capital costs. And, compared to the conventional approach, catalytic distillation may also improve other factors, such as reactant conversion, selectivity, mass transfer, operating pressure, oligomer formation and catalyst fouling. The constant washing of the catalyst by liquid flowing down the column and the distillation of high-boiling foulants results in extended catalyst life. Four selective hydrogenation applications of catalytic distillation are discussed: Butadiene selective hydrogenation combined within an MTBE unit; Pentadiene selective hydrogenation; C{sub 4} acetylene conversion; and Benzene saturation.

Rock, K.; McGuirk, T. [Catalytic Distillation Technologies, Houston, TX (United States); Gildert, G.R. [Catalytic Distillation Technologies, Pasadena, TX (United States)

1997-07-01T23:59:59.000Z

442

Effects of Some Oxygenated Substitutes on Gasoline Properties, Spark Ignition Engine Performance, and Emissions  

Science Journals Connector (OSTI)

It is worthwhile to mention that eucalyptol which can be steam-extracted from eucalyptus leaves has been tested as a co-solvent that prevents alcohol?gasoline blended fuels from phase separation. ... In this table, the compound along with the concentration in the respective base fuel, BRON, and its accuracy as well as relative effectiveness on a molar (RE-M) and a weight (RE-W) basis in comparison with MTBE are shown. ... All the compounds studied exhibited enhanced ignition quality, expressed with their capability to suppress engine knock, performance that can be confirmed from the BRON values of Table 3. From the data in the table, and given the accuracy of the BRON values, which is ±10/x, where x is the w/v % concentration of the compound in the fuel, a decrease of BRON values with the increase of the RON of the base fuel is observed. ...

S. Gouli; E. Lois; S. Stournas

1998-08-12T23:59:59.000Z

443

Regional refining models for alternative fuels using shale and coal synthetic crudes: identification and evaluation of optimized alternative fuels. Annual report, March 20, 1979-March 19, 1980  

SciTech Connect

The initial phase has been completed in the project to evaluate alternative fuels for highway transportation from synthetic crudes. Three refinery models were developed for Rocky Mountain, Mid-Continent and Great Lakes regions to make future product volumes and qualities forecast for 1995. Projected quantities of shale oil and coal oil syncrudes were introduced into the raw materials slate. Product slate was then varied from conventional products to evaluate maximum diesel fuel and broadcut fuel in all regions. Gasoline supplement options were evaluated in one region for 10% each of methanol, ethanol, MTBE or synthetic naphtha in the blends along with syncrude components. Compositions and qualities of the fuels were determined for the variation in constraints and conditions established for the study. Effects on raw materials, energy consumption and investment costs were reported. Results provide the basis to formulate fuels for laboratory and engine evaluation in future phases of the project.

Sefer, N.R.; Russell, J.A.

1980-11-01T23:59:59.000Z

444

Motiva Refinery | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Refinery Refinery Motiva Refinery May 18, 2006 - 10:45am Addthis Remarks Prepared for Energy Secretary Bodman Much of my time lately has been devoted to explaining why the price of gasoline has risen so sharply. President Bush understands the pinch this is creating for American consumers and has come forward with a variety of steps to address the problem. Rapid economic growth in emerging economies like China and India-and the growth here in the U.S.-have pushed up demand. Political unrest in some oil-producing regions has tightened supply. The transition from winter gasoline to summer blends, and the phase out of the additive MTBE in favor of ethanol, have increased the pressure on the market. Most significantly, we have very little spare refining capacity in this

445

East Coast (PADD 1) Total Crude Oil and Products Imports  

U.S. Energy Information Administration (EIA) Indexed Site

MTBE (Oxygenate) Other Oxygenates Fuel Ethanol (Renewable) Biomass-Based Diesel (Renewable) Other Renewable Diesel Other Renewable Fuels Distillate Fuel Oil Distillate F.O., 15 ppm and under Distillate F.O., 15 to 500 ppm Distillate F.O., Greater than 500 ppm Distillate F.O., 501 to 2000 ppm Distillate F.O., Greater than 2000 ppm Kerosene Finished Aviation Gasoline Aviation Gasoline Blending Components Kerosene-Type Jet Fuel Special Naphthas Residual Fuel Oil Residual F.O., Less than 0.31% Sulfur Residual F.O., 0.31 to 1% Sulfur Residual F.O., Greater than 1% Sulfur Naphtha for Petrochem. Feed. Use Other Oils for Petrochem. Feed. Use Waxes Petroleum Coke Asphalt and Road Oil Lubricants Miscellaneous Products Period/Unit: Monthly-Thousand Barrels Monthly-Thousand Barrels per Day Annual-Thousand Barrels Annual-Thousand Barrels per Day

446

Synthesis, adsorption and regeneration of nanoporous silica aerogel and silica aerogel-activated carbon composites  

Science Journals Connector (OSTI)

Abstract Usage of aerogels as an adsorbent has become more widespread because of its specifications such as high porosity and specific surface. Nanometer silica aerogel and silica aerogel-activated carbon composites were synthesized using a water glass precursor by ambient pressure drying method. Then, the adsorption capacity of synthesized adsorbents was studied in terms of benzene and ethyl benzene adsorption by chromatography method for continuous and batch testing. Results showed that silica aerogel and silica aerogel-activated carbon composites had high tendency for benzene and ethyl benzene adsorption. Silica aerogel showed maximum adsorption capacity of 2.3 g g?1 and 0.7 g g?1 in static adsorption of benzene and ethyl benzene respectively. Also, in dynamic adsorption of benzene and ethyl benzene, silica aerogel had maximum equilibrium adsorption capacity of 0.954 g g?1 and 0.219 g g?1 respectively. Minimum equilibrium adsorption capacity in benzene and ethyl benzene static adsorption was related to activated carbon with 0.7 g g?1 and silica aerogel–2 wt% activated carbon with 0.25 g g?1 respectively. After adsorption process, silica aerogel and silica aerogel–0.5 wt% activated carbon composite were regenerated by solvent extraction–thermal treatment method and, after at least 15 adsorption/desorption cycles, their adsorption capacity became fixed.

Akbar Mohammadi; Jafarsadegh Moghaddas

2014-01-01T23:59:59.000Z

447

Enzyme activity in dialkylphosphate ionic liquids  

NLE Websites -- All DOE Office Websites (Extended Search)

Enzyme activity in dialkylphosphate ionic liquids Enzyme activity in dialkylphosphate ionic liquids M. F. Thomas, L. Li, J. Handley-Pendleton, D. van der Lelie, J. J. Dunn and J. F. Wishart Bioresource Technology 102, in press. [Find paper at Science Direct] Abstract: The activity of four metagenomic enzymes and an enzyme cloned from the straw mushroom, Volvariella volvacea were studied in the following ionic liquids, 1,3-dimethylimidazolium dimethyl phosphate, [mmim][dmp], 1-ethyl-3-methylimidazolium dimethyl phosphate, [emim][dmp], 1-ethyl-3-methylimidazolium diethyl phosphate, [emim][dep] and 1-ethyl-3-methylimidazolium acetate, [emim][OAc]. Activity was determined by analyzing the hydrolysis of para-nitrobenzene carbohydrate derivatives. In general, the enzymes were most active in the dimethyl phosphate ionic

448

Preliminary screening of alternative technologies to incineration for treatment of chemical-agent-contaminated soil, Rocky Mountain Arsenal  

SciTech Connect

In support of the U.S. Army`s efforts to determine the best technologies for remediation of soils, water, and structures contaminated with pesticides and chemical agents, Argonne National Laboratory has reviewed technologies for treating soils contaminated with mustard, lewisite, sarin, o-ethyl s-(2- (diisopropylamino)ethyl)methyl-phosphonothioate (VX), and their breakdown products. This report focuses on assessing alternatives to incineration for dealing with these contaminants. For each technology, a brief description is provided, its suitability and constraints on its use are identified, and its overall applicability for treating the agents of concern is summarized. Technologies that merit further investigation are identified.

Shem, L.M.; Rosenblatt, D.H.; Smits, M.P.; Wilkey, P.L.; Ballou, S.W.

1995-12-01T23:59:59.000Z

449

Synthesis of N-carbobenzoxy-L-valyl-L-valyl-4-amino-3-hydroxy-5-methylhexanoic acid  

E-Print Network (OSTI)

, and dried over sodium sulfate. The sol- vent was removed by evaporation in vacuo and the products isolated by silica gel chromatography, eluting with 25% ethyl acetate/hexane, to give the following results: Ethyl (38, 4S)-N-t-butyloxycarbonyl-4-amino-3... columns prepacked with silica gel 60 (EM Reagents). Amino acids were coupled using mixed anhydride coupling methods. ACKNOWLEDGMENTS The author is grateful to Dr, G. I. Glover for all the guidance and support he has provided, A special thanks to Dr, E...

Hicks, Gary Dean

1980-01-01T23:59:59.000Z

450

Organic derivatives of zirconium phosphate  

E-Print Network (OSTI)

-propane or as it is commonly referred to, propylene oxide. The reaction conditions are the same as for those of the ethylene oxide reaction. The samples were analyzed using the same techniques as for the ethyl- ene oxide reaction. The interlayer spacing of the propylene...-propane or as it is commonly referred to, propylene oxide. The reaction conditions are the same as for those of the ethylene oxide reaction. The samples were analyzed using the same techniques as for the ethyl- ene oxide reaction. The interlayer spacing of the propylene...

Fine, Steven Beryl

2012-06-07T23:59:59.000Z

451

Conceptual Model At Raft River Geothermal Area (2011) | Open Energy  

Open Energy Info (EERE)

2011) 2011) Exploration Activity Details Location Raft River Geothermal Area Exploration Technique Conceptual Model Activity Date 2011 Usefulness not indicated DOE-funding Unknown Exploration Basis Explore for development of an EGS demonstration project Notes The reservoir is developed in fractured Proterozoic schist and quartzite, and Archean quartz monzonite cut by younger diabase intrusions. The basement complex was deformed during the mid Tertiary and covered by approximately 5000 ft of late Tertiary sedimentary and volcanic deposits. Listric normal faults of Cenozoic age disrupt the Tertiary deposits but do not offset the basement rocks. RRG-9, the target well, was drilled southwest of the main well field to a measured depth (MD) of 6089 ft. The well is deviated to the west and cased to a depth of 2316 ft MD. It

452

Bifunctional anion-exchange resins with improved selectivity and exchange kinetics  

DOE Patents (OSTI)

Disclosed herein are a class of anion exchange resins containing two different exchange sites with improved selectivity and sorptive capability for chemical species in solution, such as heptavalent technetium (as pertechnetate anion, TcO.sub.4.sup.-). The resins are prepared by first reacting haloalkylated crosslinked copolymer beads with a large tertiary amine in a solvent in which the resin beads can swell, followed by reaction with a second, smaller, tertiary amine to more fully complete the functionalization of the resin. The resins have enhanced selectivity, capacity, and exchange kinetics.

Alexandratos, Spiro D. (Knoxville, TN); Brown, Gilbert M. (Knoxville, TN); Bonnesen, Peter V. (Knoxville, TN); Moyer, Bruce A. (Oak Ridge, TN)

2000-01-01T23:59:59.000Z

453

Coal quality and estimated coal resources in the proposed Colville Mining District, central North Slope, Alaska  

SciTech Connect

The proposed Colville Mining District (CMD) encompasses 27,340 mi{sup 2} (70,800 km{sup 2}) in the central part of the North Slope. Known coal deposits within the proposed district range from Mississippian to Tertiary in age. Available information indicates that neither Mississippian and Tertiary coals in the CMD constitute a significant resource because they are excessively deep, thin, or high in ash content; however, considerable amount of low-sulfur Cretaceous coal is present. The paper briefly describes the geology and quality of these coal reserves. Difficult conditions will restrict mining of these coals in the near future.

Stricker, G.D. [Geological Survey, Denver, CO (United States); Clough, J.G. [Alaska Department of Natural Resources, Fairbanks, AK (United States). Division of Geological and Geophysical Surveys

1994-12-31T23:59:59.000Z

454

Energy Efficiency and Conservation Block Grant Program  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Description Description At the Wastewater Treatment Plant: install dissolved oxygen controls, reprogram wetwell level controls for the tertiary filter pumps, install electric actuators on tertiary filter effluent lines, install power monitors on motors, install standby generator; at the Biosolids Processing Facility and Landfill: install timers or programmable logic controllers (PLC); at the Wastewater Flow Equalization Basin and Pumping Station at Landfill: install timers or PLC, install variable frequency drives on wastewater pumps; at the Water Treatment Plant: install power monitors on motors; at several of the wastewater treatment facilities replace existing interior and exterior lighting fixtures with high efficiency units and provide engineering services.

455

An Examination of the Thermodynamics of Fusion, Vaporization, and Sublimation of Several Parabens by Correlation Gas  

E-Print Network (OSTI)

An Examination of the Thermodynamics of Fusion, Vaporization, and Sublimation of Several Parabens, Kasetsart University, Bangkane, Bangkok 10900, Thailand 2 Department of Chemistry and Biochemistry.com). DOI 10.1002/jps.22423 ABSTRACT: The vaporization, fusion, and sublimation enthalpies of methyl, ethyl

Chickos, James S.

456

Large scale total synthesis of apoptolidinone and progress towards the total synthesis of ammocidin  

E-Print Network (OSTI)

chapter: aldehyde 3.8 (C14-C19) was synthesized via Sharpless asymmetric epoxidation; ethyl ketone 3.9’ (C20-C28) was prepared via Kobayashi and Crimmins’s asymmetric aldol methodologies; aldehyde 3.14 (C7-C13) was generated by Brown crotylation and cross...

Liu, Qingsong

2009-05-15T23:59:59.000Z

457

Tamiflu Synthesis DOI: 10.1002/anie.200901345  

E-Print Network (OSTI)

Tamiflu Synthesis DOI: 10.1002/anie.200901345 Symmetry-Based Design for the Chemoenzymatic Synthesis of Oseltamivir (Tamiflu) from Ethyl Benzoate** Bradford Sullivan, Ignacio Carrera, Melissa Drouin at nanomolar levels.[2] Although oseltamivir is not a particularly complex molecule, its practical synthesis

Hudlicky, Tomas

458

An endogenous capsaicin-like substance with high potency at recombinant and native vanilloid VR1 receptors  

Science Journals Connector (OSTI)

...methanol/basified water (50:50)/water and eluted with...tandem MS system. Recovery was calculated...ethyl acetate/water/2,2,4-tri-methylpentane...lipid extract by atmospheric pressure chemical...biosynthesis is the condensation of dopamine with...

Susan M. Huang; Tiziana Bisogno; Marcello Trevisani; Abdulmonem Al-Hayani; Luciano De Petrocellis; Filomena Fezza; Michele Tognetto; Timothy J. Petros; Jocelyn F. Krey; Constance J. Chu; Jeffrey D. Miller; Stephen N. Davies; Pierangelo Geppetti; J. Michael Walker; Vincenzo Di Marzo

2002-01-01T23:59:59.000Z

459

RESUME February 2013 WILLIAM DAVID CONSTANT  

E-Print Network (OSTI)

- Chemical Engineer, Process Development, Ethyl Corp. Baton Rouge, LA. LSU/Academic: 1978 - 1984 - Graduate Experience - ChE 2171 Material and Energy Balances ChE 4104 Transport Sciences Lab PetE 3032 Phase Behavior Professionalism and Ethics Continuing Education - Hazardous Materials Manager Review Course Treatment Technologies

Cai, Steve C. S.

460

Bibliography and Index to the Literature on Gas Chromatography: January 1, 1963 to November 1, 1963  

Science Journals Connector (OSTI)

......THE STUDY OF RESINS IN BLACK COAL TARS, Ferrand, R., Chim...ALIPHATIC ESTERS. PART I. SLOW COMBUSTION OF ETHYL ACETATE, Fish...French) 421 USE OF CATALYTIC COMBUSTION FILA- MENTS FOR QUALITATIVE...1363-1368 (Sept. 1963) 433 THE CHEMISTRY OF SERUM LIPOPRO- TEINS......

Seaton T. Preston; Jr.; Geneva Hyder; Mignon Gill

1963-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "mtbe ethyl tertiary" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Alkyl nitrate (C 1 -C 3 ) depth profiles in the tropical Pacific Ocean  

E-Print Network (OSTI)

concentrations with a [ iPr]/[Et] ratio of 0.1±0.0. Noat all depths with an [iPr]/[Et] ratio of 0.2 ± 0.0. Thiswith ethyl nitrate with an [iPr]/[Et] ratio of 0.2 ± 0.0.

Dahl, E. E; Yvon-Lewis, S. A; Saltzman, E. S

2007-01-01T23:59:59.000Z

462

E-Print Network 3.0 - aminoethanesulfonic acid Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

methyl-2- aminoethane-sulfonic acid, 8 trehalose, 10 glucose, 26 NaHCO3, 1 NaH2PO4, 1.5 CaCl2, and 4 Mg... 0 100 150 0 10 20 Benzaldehyde 1-butanol Butyric acid Ethyl acetate...

463

Transfer RNA Methylases and Cancer  

Science Journals Connector (OSTI)

... base residues. One possible explanation is that ethionine is activated to form S-adenosylethionine (SAE), and that the methylase enzymes then use ... ), and that the methylase enzymes then use SAE in place of S-adenosylmethionine, so that tRNA is ethylated where it would normally ...

VALDA M. CRADDOCK

1970-12-26T23:59:59.000Z

464

A Robotic Sample Preparation Scheme for the High Performance Liquid Chromatographic Determination of Ivermectin in Animal Plasma  

Science Journals Connector (OSTI)

......dispensing device simplifies handling of the large solvent volumes...system for multiple sample handling. Equivalence to the manual...discarding eluate as necessary. Materials Ivermectin and 2 -22,23-dihydroavermectin...ethyl Figure 2. Schematic diagram of the solid phase extraction......

J.V. Pivnichny; A.A. Lawrence; J.D. Stong

1987-05-01T23:59:59.000Z

465

Alkyl nitrate (C1-C3) depth profiles in the tropical Pacific Ocean E. E. Dahl,1,2  

E-Print Network (OSTI)

and distribution of tropo- spheric ozone. Atmospheric alkyl nitrates are normally associated with polluted air free radical processes initiated by radioactive decay or cosmic rays, enzymatically mediated reactions expedition in the equatorial Pacific, an equatorial maximum in atmospheric ethyl and isopropyl nitrate

Saltzman, Eric

466

THE NEW ORLEANS MEETING OF SECTION C OF THE AMERICAN ASSOCIATION FOR THE ADVANCEMENT OF SCIENCE AND OF THE AMERICAN CHEMICAL SOCIETY  

Science Journals Connector (OSTI)

...attended by a decrease in the total carbo-hydrate. Failure to effect this chemical change...title.) 337 Ethyl Oxomalonate and its Behavior to-ward Ammonia: R. S. CURTISS...solution in equilibrium with both solid phases contains 355 grams MgSO4 and 0.50 gram...

CHAS. L. PARSONS; C. E. WATERS

1906-03-02T23:59:59.000Z

467

Organometallic Chemistry Supported by the PNP Pincer Framework for Both Early and Late Transition Metals  

E-Print Network (OSTI)

. The major decomposition product is believed to be a Hf alkylidene complex on the basis of in situ NMR spectroscopic observations (e.g., delta 248.2 ppm in the 13C{1H} NMR spectrum). The reaction of (PNP)TaF4 with an excess of ethyl Grignard led primarily...

Brammell, Christina 1987-

2012-08-20T23:59:59.000Z

468

SPME in Environmental Analysis: Biotransformation Pathways  

Science Journals Connector (OSTI)

......SPMEGCMS to study the degradation of ethyl benzene using...methyl-t-butyl ether and its degradation products, t-butyl...food by determining degradation products and other released...Bitumen is a fossil fuel rich in sulfur, which...Aliquots of the cell suspension (2 mL......

Annamaria Halasz; Jalal Hawari

2006-08-01T23:59:59.000Z

469

bined alleles also targets the rearranged anti-body genes for further mutation, and that this  

E-Print Network (OSTI)

of both of these shifts, rather than pollution or the alien invasion per se. The top trophic level of planktivorous fish. -- AMS Proc. Natl. Acad. Sci. U.S.A. 104, 10518 (2007). air to shrink the droplet to deter- mine the aqueous phase diagram of poly(ethyl- ene glycol) (PEG) and ammonium sulfate and to study

Fraden, Seth

470

Novel Fluoropolymer Blends for the Fabrication of Sprayable Multifunctional Superhydrophobic Nanostructured Composites  

Science Journals Connector (OSTI)

These nanoclays were surface-modified with fatty amino/amine functionality to render them hydrophobic. ... The wetting properties of PVDF–PMC–nanoclay composite coatings are compared with those of PVDF–poly(ethyl 2-cyanoacrylate)–nanoclay composites in order to demonstrate the effect of the PMC copolymer on liquid repellency. ...

Thomas M. Schutzius; Ilker S. Bayer; Manish K. Tiwari; Constantine M. Megaridis

2011-08-20T23:59:59.000Z

471

Mixed Columns Made to Order in Gas Chromatography I. Isothermal Analysis  

Science Journals Connector (OSTI)

......simplicity of the mixed phase, price, tem- perature stability...2-ethyl-hexyl sebacate, Ucon Oil LB 550X, Squalane, and...with a water pump while heating with a water-bath...under the vacuum of an oil rotary pump. Chromatograms...Di-2-ethylhexylsebacate (B) 10% Ucon oil LB 550X (R) 35% Squalane......

M. J. Molera; J. A. Garcia Dominguez; J. Fernandez Biarge

1969-05-01T23:59:59.000Z

472

Quantum critical point and spin fluctuations in lower-mantle ferropericlase  

Science Journals Connector (OSTI)

...emission spectroscopy with laser heating (36) in Fig. 6B. General agreement of the calculated...quasi-hydrostatic conditions with silicon oil (poly-ethyl-siloxane 5...506 – 508 . 49 Vocadlo L Price GD ( 1996 ) The melting...quasi-hydrostatic conditions with silicon oil (PES-5) as a pressure medium...

Igor S. Lyubutin; Viktor V. Struzhkin; A. A. Mironovich; Alexander G. Gavriliuk; Pavel G. Naumov; Jung-Fu Lin; Sergey G. Ovchinnikov; Stanislav Sinogeikin; Paul Chow; Yuming Xiao; Russell J. Hemley

2013-01-01T23:59:59.000Z

473

The Carcinogenicity of 3-Methoxy-4-aminoazobenzene and Its N-Methyl Derivatives for Extrahepatic Tissues of the Rat  

Science Journals Connector (OSTI)

...obtained. :Nineteen gm. (0.5 mole) of lithium aluminum hydride was suspended in 400...stirring was continued for 15 minutes. The excess hydride was destroyed by the dropwise addition of 50 ml. of ethyl acetate. The lithium aluminum-dye complex was decomposed...

James A. Miller and Elizabeth C. Miller

1961-09-01T23:59:59.000Z

474

Probing the Structure and Stability of the Tumor-localizing Derivative of Hematoporphyrin by Reductive Cleavage with LiAlH4  

Science Journals Connector (OSTI)

...involving the use of the reducing agent lithium aluminum hydride (I AllI4)has been...mixture was chilled to 4"( ' on ice, and excess hydride was destroyed by 4This distillation...explosively with THF at elevated temperatures. Excess hydride should be destroyed with ethyl...

David Kessel; Paul Thompson; Brian Musselman; and C. K. Chang

1987-09-01T23:59:59.000Z

475

Barrier to Rotation around the Csp2-Csp2 Bond of the Ketoaldehyde Enol Ether MeC(O)CHCH?OEt As Determined by 13C NMR and ab Initio Calculations  

Science Journals Connector (OSTI)

NMR measurements and ab initio calculations were applied to determine the barriers to rotation around formally single bonds of the title methyl-?-ethoxyvinyl ketone, i.e., the vinylogue of the ethyl ester of acetic acid. For comparison, ab initio ...

Hans-Christian Siebert; Emad Tajkhorshid; Janusz Dabrowski

2001-08-22T23:59:59.000Z

476

Synthesis of an A/B/C Triblock Copolymer for Battery Materials Applications  

E-Print Network (OSTI)

Section tert-Butylamine, cobalt chloride, and ethyl vinyl ether were purchased from Aldrich. Butyllithium incorporate metal salts. The organocobalt monomer was chosen due to the difficulty of polymerizing a lithium- containing monomer. The electrochemical reaction shown in reaction 1 is different from other lithium battery

Rubloff, Gary W.

477

Bibliography and Index of the Literature on Gas Chromatography—1964 November 1, 1963 to November 1, 1964  

Science Journals Connector (OSTI)

......Haus, Joseph B., Manolev, Lazar, and Price, Robert W. J. Assoc. Offic. Agr...Nov. 1963) 723 CHEMICAL CHANGE OF ETHYLENE GLYCOL INDUCED BY GAMMA RAPS, Hir- ota...INDUCED REACTION BE- TWEEN ACETALDEHYDE AND ETHYLENE- MAINLY ON THE PRODUCTION OF METHYL ETHYL......

Mignon Gill; Seaton T. Preston; Jr.

1964-12-01T23:59:59.000Z

478

Bibliography and Index to the Literature on Gas Chromatography: January 1, 1963 to November 1, 1963  

Science Journals Connector (OSTI)

......405 RETENTION DATA: ANALYSIS OF...CONCENTRATIONS OF HYDROCARBONS, Feldstein...PART I. SLOW COMBUSTION OF ETHYL ACETATE...NAPHTHALENES IN CRUDE HYDROCARBONS BY GAS-LIQUID...ESTERS FROM HEAT-BODIED LINSEED...German) 953 HYDROCARBONS IN THE LOS ANGELES...PEROXIDE BY COMBUSTION-GAS CHROMATOGRAPHY......

Seaton T. Preston; Jr.; Geneva Hyder; Mignon Gill

1963-12-01T23:59:59.000Z

479

Effects of temperature on the optical and electrical properties of ZnO nanoparticles synthesized by sol-gel method  

Science Journals Connector (OSTI)

ZnO nanoparticles for different thermal treatment temperatures were prepared by using sol-gel method under supercritical drying of ethyl alcohol. The structural properties showed that the ZnO nanoparticles exhibit hexagonal wurtzite structure. Thus, ... Keywords: Electrical conductivity, Nanoparticles, Optical materials, Sol-gel, Zinc oxide

K. Omri, I. Najeh, R. Dhahri, J. El Ghoul, L. El Mir

2014-10-01T23:59:59.000Z

480

Theoretical studies of hydrocarbon combustion chemistry. Annual progress report  

SciTech Connect

The author reports here the results of DZP CISD calculations for methylcarbene. Geometry, symmetry, and vibrational modes for the radical are reported for both the singlet and the triplet state. Future work will focus on the ethyl radical-oxygen interaction relevant to hydrocarbon combustion.

Schaefer, H.F. III

1994-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "mtbe ethyl tertiary" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Anisotropic membranes for gas separation  

DOE Patents (OSTI)

A gas separation membrane has a dense separating layer about 10,000 Angstroms or less thick and a porous support layer 10 to 400 microns thick that is an integral unit with gradually and continuously decreasing pore size from the base of the support layer to the surface of the thin separating layer and is made from a casting solution comprising ethyl cellulose and ethyl cellulose-based blends, typically greater than 47.5 ethoxyl content ethyl cellulose blended with compatible second polymers, such as nitrocellulose. The polymer content of the casting solution is from about 10% to about 35% by weight of the total solution with up to about 50% of this polymer weight a compatible second polymer to the ethyl cellulose in a volatile solvent such as isopropanol, methylacetate, methanol, ethanol, and acetone. Typical nonsolvents for the casting solutions include water and formamide. The casting solution is cast in air from about zero to 10 seconds to allow the volatile solvent to evaporate and then quenched in a coagulation bath, typically water, at a temperature of 7--25 C and then air dried at ambient temperature, typically 10--30 C. 2 figs.

Gollan, A.Z.

1987-07-21T23:59:59.000Z

482

Stereoselective Synthesis of (-) Acanthoic Acid Taotao Ling, Bryan A. Kramer, Michael A. Palladino, and Emmanuel A. Theodorakis*  

E-Print Network (OSTI)

(16.8 mg, 0.05 mmol) in N, N-dimethylformamide (2 ml) added lithium bromide (5.0 mg, 0.06 mmol (5 ml) and extracted with ethyl acetate (3 x 10 ml). The organic layer was collected, dried (MgSO4

Theodorakis, Emmanuel

483

Instructions for use Cross-Coupling Reaction of Organoboron Compounds via Base-Assisted  

E-Print Network (OSTI)

-3]. The interaction between 1-hexenylboronic acid and palladium(II) acetate was first demonstrated by Heck [4]. In situ preparation of (E)- or (Z)-1-alkenylpalladium(II) acetate via transmetalation was followed by its conjugate addition to ethyl acrylate (Scheme 1). Negishi found that boron-ate complexes such as lithium 1

Tachizawa, Kazuya

484

[Reprinted from the Journal of Orsanic Chemistrv. 10, 2516(1975i.1 Copyright 1975by the American Chemical Societyand reprinted b!' permissionrf the copyright owner.  

E-Print Network (OSTI)

and acetic anhy- dride,6'? and isolated as the lithium or silver salts.8All of these procedures contain precipitation or the filtration of the phosphate "slimes" generatedby neutralization with lithium acetateophosphoric acid in ethyl acetate at -10o, and the resulting mixture of mono- and polyacetyl phosphoric acids

Prentiss, Mara

485

5524 J. Am. Chem. SOC.1988, 110, 5524-5533 and 40.53 MHz, respectively. `H NMR spectra were recorded on a  

E-Print Network (OSTI)

oil. The red oil was multiply flash chromatographed on silica gel (5% ethyl acetate, hexane) to afford.13 (d, J N Lithium Diphenylamide (Ph2NLisolvcnt.frcc).The various isotopomers of solvent-free lithium diphenylamide were prepared as follows. A 500-mL round-bottom flask fitted to a glass

Collum, David B.

486

GLC Quantitation of 1-Piperidinocyclohexanecarbonitrile (PCC) in Illicit Phencyclidine (PCP)  

Science Journals Connector (OSTI)

......availability is the ease of synthesis of PCP--cheap, fast...the various routes of synthesis (7,8), those most...formaldehyde and lithium shot (BDH Chemicals...solvent systems, ethyl acetate- methanol-ammonium...amine derivatives. II. Synthesis and pharma- cologicalactivity......

James R. Ballinger; Joan A. Marshman

1979-01-01T23:59:59.000Z

487

Quantitative Selected Ion Monitoring (QSIM) of Drugs and/or Drug Metabolites in Biological Matrices  

Science Journals Connector (OSTI)

......continued. Substance Thiothixene Haloperidol Lithium Trazodone Hormones Testosterone 5n...Table I were chosen based on ease of synthesis. The one exception was amitriptyline-d6...deactivated by injecting aliquots of an ethyl acetate extract of a drug-free matrix. Aliquots......

W.A. Garland; M.L. Powell

1981-08-01T23:59:59.000Z

488

Analysis of MDMA and its Metabolites in Urine and Plasma Following a Neurotoxic Dose of MDMA  

Science Journals Connector (OSTI)

......Bloodsampleswere collected in lithium heparin tubes. The samples...by addition of 1 rnL sodium acetate buffer (pH 5.2). Fiftymicroliters...ammoniumhydroxide in ethyl acetate for urine samples and a methylene...Kingston, and C.A. Marsden.Synthesis,in vitro formation, and......

Sandra Valtier; Clyde F. Phelix; John T. Cody

2007-04-01T23:59:59.000Z

489

Synthesis and Characterization of Ferroferriborate (Fe3BO5) Nanorods  

E-Print Network (OSTI)

a number of interesting properties, including its catalytic oxidation of ethyl acetate and methanol[5] and Fe3BO5 and GdBO3 particles produced from interface diffusion between Fe­Gd particle cores and B2O3/H3) could be used as a weak reducing agent for producing Au and Pd nanoparticles in the presence of oleyl

Wang, Zhong L.

490

Crystallization of Congo Red  

Science Journals Connector (OSTI)

... It has been confirmed that the potassium salt of Congo Red will crystallize as needles from various ethyl alcohol-water mixtures, but only with ... observation during a trial of various salting-out procedures, however, the potassium salt of Congo Red has been found to be precipitated in crystalline form by salting out with potassium ...

PETER MITCHELL

1950-05-13T23:59:59.000Z

491

5 SPECIMEN COLLECTION AND PRESERVATION This section outlines the use of fixatives and preservatives used in necropsy procedures and  

E-Print Network (OSTI)

(10% neutral buffered seawater will do the regular buffer is unavailable) is a suitable fixative must be checked routinely during storage to avoid loss of fluid. 10% neutral buffered formalin can. Use extreme care with storage and handling (see Section 3.1). 5.1.3 Ethyl Alcohol EtOH (100%) Used

Marsh, Helene

492

Anisotropic membranes for gas separation  

DOE Patents (OSTI)

A gas separation membrane has a dense separating layer about 10,000 Angstroms or less thick and a porous support layer 10 to 400 microns thick that is an integral unit with gradually and continuously decreasing pore size from the base of the support layer to the surface of the thin separating layer and is made from a casting solution comprising ethyl cellulose and ethyl cellulose-based blends, typically greater than 47.5 ethoxyl content ethyl cellulose blended with compatible second polymers, such as nitrocellulose. The polymer content of the casting solution is from about 10% to about 35% by weight of the total solution with up to about 50% of this polymer weight a compatible second polymer to the ethyl cellulose in a volatile solvent such as isopropanol, methylacetate, methanol, ethanol, and acetone. Typical nonsolvents for the casting solutions include water and formamide. The casting solution is cast in air from about zero to 10 seconds to allow the volatile solvent to evaporate and then quenched in a coagulation bath, typically water, at a temperature of 7.degree.-25.degree. C. and then air dried at ambient temperature, typically 10.degree.-30.degree. C.

Gollan, Arye Z. (Newton, MA)

1987-01-01T23:59:59.000Z

493

Localization of Burkholderia cepacia Complex Bacteria in Cystic Fibrosis Lungs and Interactions with Pseudomonas aeruginosa in Hypoxic Mucus  

Science Journals Connector (OSTI)

...sections were counterstained with ethyl green, dehydrated in ethanol, and coverslipped...known to utilize arginine as the sole energy source for growth when neither oxygen...arginine was not utilized by Bcc bacteria for energy production and which is consistent with...

Ute Schwab; Lubna H. Abdullah; Olivia S. Perlmutt; Daniel Albert; C. William Davis; Roland R. Arnold; James R. Yankaskas; Peter Gilligan; Heiner Neubauer; Scott H. Randell; Richard C. Boucher

2014-08-25T23:59:59.000Z

494

Program of the Gordon Research Conferences  

Science Journals Connector (OSTI)

...effects at high pressure"; M. F. Crawford, "In-frared and Raman spectra of...chairmen: H. L. Welsh; B. L. Crawford, Jr.; B. Vodar; subjects to be announced...In September 1952, at age 65, he was retired as vice president of Ethyl Cor-poration...

W. George Parks

1956-03-02T23:59:59.000Z

495

Steric Effects in Ionic Pairing and Polyelectrolyte Interdiffusion within Multilayered Films: A Neutron Reflectometry Study  

SciTech Connect

Using a series of polycations synthesized by atom transfer radical polymerization (ATRP), we investigate the effects of the polymer charge density and hydrophobicity on salt-induced interdiffusion of polymer layers within polyelectrolyte multilayer (PEM) films. Polycations with two distinct hydrophobicities and various quaternization degrees (QPDMA and QPDEA) were derived from parent polymers of matched molecular weights poly(2-(dimethylamino)ethyl methacrylate) (PDMA) and poly(2-(diethylamino)ethyl methacrylate) (PDEA) by quaternization with either methyl or ethyl sulfate. Multilayers of these polycations with polystyrene sulfonate (PSS) were assembled in low-salt conditions, and annealed in NaCl solutions to induce layer intermixing. As revealed by neutron reflectometry (NR), polycations with lower charge density resulted in a faster decay of film structure with distance from the substrate. Interestingly, when comparing polymer mobility in QPDEA/PSS and QPDMA/PSS films, layer intermixing was faster in the case of more hydrophobic QPDEA as compared to QPDMA, because of the weaker ionic pairing (due to the presence of a bulky ethyl spacer) between QPDEA and PSS.

Xu, Li [Stevens Institute of Technology, Hoboken, New Jersey; Ankner, John Francis [ORNL; Sukhishvili, Prof. Svetlana A. [Stevens Institute of Technology, Hoboken, New Jersey

2011-01-01T23:59:59.000Z

496

Small-molecule inhibitor binding to an N-acyl-homoserine lactone synthase  

Science Journals Connector (OSTI)

...and 6C at the Pohang Accelerator Laboratory, Pohang, Korea. Structures...mg; 2.06 mmol). Nuclear magnetic resonance...concentrated under a vacuum. Ethyl 4...and 6C at the Pohang Accelerator Laboratory, Korea...then evaporated under vacuum. The remaining reaction...

Jiwoung Chung; Eunhye Goo; Sangheon Yu; Okhee Choi; Jeehyun Lee; Jinwoo Kim; Hongsup Kim; Jun Igarashi; Hiroaki Suga; Jae Sun Moon; Ingyu Hwang; Sangkee Rhee

2011-01-01T23:59:59.000Z

497

CO2-limitation-inducible Green Recovery of fatty acids from cyanobacterial biomass  

Science Journals Connector (OSTI)

...energy-intensive biomass processes such as concentration...or ethyl esters (biodiesel), and alkanes. However...needed for a productive process. We believe...biomass and metabolites: Process options and economics . Biotechnol...Rittmann BE ( 2011 ) Evaluation of methods to extract...

Xinyao Liu; Sarah Fallon; Jie Sheng; Roy Curtiss III

2011-01-01T23:59:59.000Z

498

NAME M/YEAR MASTERS THESES TITLES SCOPEL, ROBERT B Jun49 The Volcanic History of Jackson Hole, Wyoming  

E-Print Network (OSTI)

, Park County, Wyoming GOSSER, CHARLES F. Jun60 Petrography and Metamorphism of the Star Lake Area of the Keewatin Province, Ontario RUBEL, DANIEL N Apr59 Tertiary volcanic rocks of the Cooke city - pilot peak, Montana BRUEHL, DONALD H. Jun61 The Petrography and Structure of an area North of Cooke City, Montana #12

Baskaran, Mark

499

Downhole steam generator with improved preheating, combustion, and protection features  

DOE Patents (OSTI)

For tertiary oil recovery, a downhole steam generator is designed which provides for efficient counterflow cooling of the combustion chamber walls and preheating of the fuel and water. Pressure-responsive doors are provided for closing and opening the outlet in response to flameout, thereby preventing flooding of the combustion chamber. (DLC)

Fox, R.L.

1981-01-07T23:59:59.000Z

500

IEEE TRANSACTIONS ON POWER ELECTRONIC 1 Abstract--This paper presents a novel approach to conceive  

E-Print Network (OSTI)

. Keywords ­ Secondary control, Distributed Control, Networked Control Systems, Droop Control, Cooperative and voltage regulation, active and reactive power control between DG units and with the main grid to economic optimization, based on energy prices and electricity market [1]. Tertiary control exchanges

Vasquez, Juan Carlos