Powered by Deep Web Technologies
Note: This page contains sample records for the topic "ms uo uo" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

UoS Motor Accident Report Form COMPANY DETAILS  

E-Print Network [OSTI]

UNIV01FL02 UoS Motor Accident Report Form COMPANY DETAILS INSURED: University of Sussex ADDRESS: LOCATION: DESCRIPTION OF HOW ACCIDENT HAPPENED: PLEASE DRAW A SKETCH OF THE ACCIDENT: #12;DRIVER DETAILS: PREVIOUS ACCIDENTS: ADDRESS: VEHICLE DETAILS DATE VEHICLE PURCHASED: MAKE/MODEL: REGISTRATION: MILEAGE

Sussex, University of

2

UO Policy Library Resource for  

E-Print Network [OSTI]

UO Policy Library Resource for Policy Owners To ensure University- wide consistency in the formulation, review, approval, and implementation of policies, the Policy Library has provided a resource section for policy owners. It helps answer questions such as: Is this a policy or procedure? What

Oregon, University of

3

Cameco UO3 Materials Analysis  

SciTech Connect (OSTI)

Uranium trioxide (UO{sub 3}) was characterized using a variety of techniques to better understand its physical properties. Scanning electron microscope (SEM) images were collected to examine particle morphology, which consisted of semi-spherical particles that tended to agglomerate before sonication. Particle size analysis revealed a singular mode distribution with a mean particle size of 43.0 {micro}m. After sonication a bimodal distribution was produced with peak particle sizes at 0.226 {micro}m and 9.43 {micro}m. The O/U ratio was measured to be 3.09 by Cameco in 2009, by gravimetric analysis. X-ray diffraction (XRD) showed that the sample was mostly {gamma}-UO{sub 3} (87.1%) with a small amount of UO{sub 3} {center_dot} 0.80 H{sub 2}O (12.9%). Bulk and tap densities were determined to be 3.678 {+-} 0.2 and 4.81 {+-} 0.2 g/cm{sup 3}, respectively (crystalline density is 7.3 g/cm{sup 3}). The stoichiometry was measured to be 2.99 in 2012.

Hill, Mary Ann [Los Alamos National Laboratory; Nolen, Blake Penfield [Los Alamos National Laboratory; Wermer, Joseph R. [Los Alamos National Laboratory; Wilkerson, Marianne P. [Los Alamos National Laboratory; Fredenburg, David A. [Los Alamos National Laboratory; Wagner, Gregory L. [Los Alamos National Laboratory; Papin, Pallas A. [Los Alamos National Laboratory; Scott, Brian L. [Los Alamos National Laboratory; Guidry, Dennis Ray [Los Alamos National Laboratory

2012-07-12T23:59:59.000Z

4

UO  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear SecurityTensile Strain Switched Ferromagnetism in Layeredof EnergyLeaseEnergyUNCLASSIFIED 2 1IsotopeFigure 1.

5

OXYGEN DIFFUSION IN UO2-x  

E-Print Network [OSTI]

~ K.C. K:i.m, "Oxygen Diffusion in Hypostoichiometricsystem for enriching uo 2 in oxygen-18 or for stoichiometry+nal of Nuclear Materials OXYGEN DIFFUSION IN U0 2 _:x K.C.

Kim, K.C.

2013-01-01T23:59:59.000Z

6

Crystal fields in UO2 - revisited  

SciTech Connect (OSTI)

We performed inelastic neutron scattering (INS) in order to re-investigate the crystal-field ground state and the level splitting in UO{sub 2}. Previous INS studies on UO{sub 2} by Amorelli et al. [Physical Review B 15, 1989, 1856] uncovered four excitations at low temperatures in the 150-180 meV range. Considering the dipole-allowed transitions, only three of these transitions could be explained by the published crystal-field model. Our INS results on a different UO{sub 2} sample revealed that the unaccounted peak at about 180 meV is a spurious one, and thus not intrinsic to UO{sub 2}. In good agreement with Amoretti's results, we corroborated that the ground-state of UO{sub 2} is the {Lambda}{sub 5} triplet, and we computed that the fourth- and six-order crystal field parameters are V{sub 4} = -116 meV and V{sub 6} = 26 meV, respectively. We also studied the INS response of the non-magnetic U{sub 0.4}Th{sub 0.6}O{sub 2}. The splitting for this thorium-doped compound is similar to the one of UO{sub 2}, which orders antiferromagnetically at low temperatures. Therefore, we can conclude that magnetic interactions only weakly perturb the energy level splitting, which is dominated by strong crystal fields.

Nakotte, Heinz [Los Alamos National Laboratory; Rajatram, R [NMSU/UNIV OF N.C.; Kern, S [COLORADO STATE UNIV; Mcqueeney, R J [AMES LAB; Lander, G H [EUROPEAN COMMISIONS, JRC; Robinson, R A [BRAGG INSTITUTE

2009-01-01T23:59:59.000Z

7

advanced doped uo2: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

N. Creton1,a Physics Websites Summary: layer during the anionic oxidation of UO2 pellets induced very important mechanical stresses due to the crystallographic lattice...

8

Vendor Control UoW 1730 (Rev. 10/07)  

E-Print Network [OSTI]

Vendor Control Use Only UoW 1730 (Rev. 10/07) ACCOUNTING DETAIL U.S. Taxpayer ID Number 1. Vendor. VENDOR'S CERTIFICATE: I hereby certify that the items and totals listed herein are proper charges

Borenstein, Elhanan

9

advanced uo2 fuel: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Last Page Topic Index 1 Determination of Gd concentration profile in UO2-Gd2O3 fuel pellets CERN Preprints Summary: A transversal mapping of the Gd concentration was measured in...

10

PUREX/UO{sub 3} deactivation project management plan  

SciTech Connect (OSTI)

From 1955 through 1990, the Plutonium-Uranium Extraction Plant (PUREX) provided the United States Department of Energy Hanford Site with nuclear fuel reprocessing capability. It operated in sequence with the Uranium Trioxide (UO{sub 3}) Plant, which converted the PUREX liquid uranium nitrate product to solid UO{sub 3} powder. Final UO{sub 3} Plant operation ended in 1993. In December 1992, planning was initiated for the deactivation of PUREX and UO{sub 3} Plant. The objective of deactivation planning was to identify the activities needed to establish a passively safe, environmentally secure configuration at both plants, and ensure that the configuration could be retained during the post-deactivation period. The PUREX/UO{sub 3} Deactivation Project management plan represents completion of the planning efforts. It presents the deactivation approach to be used for the two plants, and the supporting technical, cost, and schedule baselines. Deactivation activities concentrate on removal, reduction, and stabilization of the radioactive and chemical materials remaining at the plants, and the shutdown of the utilities and effluents. When deactivation is completed, the two plants will be left unoccupied and locked, pending eventual decontamination and decommissioning. Deactivation is expected to cost $233.8 million, require 5 years to complete, and yield $36 million in annual surveillance and maintenance cost savings.

Washenfelder, D.J.

1993-12-01T23:59:59.000Z

11

Spark Plasma Sintering of W-UO2 Cermets  

SciTech Connect (OSTI)

About 50 vol.% 3 um depleted uranium dioxide (UO2) powder was encapsulated within a tungsten super alloy matrix produced from sub-micron tungsten powders using the Spark Plasma Sintering (SPS) process. An additive of 25 atom-percent (at.%) rhenium was included within the tungsten matrix to improve the ductility and fracture toughness of the ceramic–metallic (cermet) matrix. Cermet fabrication to 97.9% of the theoretical cermet density was achieved by sintering at 1500 degrees C with 40 MPa of applied pressure for 20 min. The results presented are from the first known trials of W–UO2 and nuclear cermet production via SPS.

R. C. O'Brien; N. D. Jerred

2013-02-01T23:59:59.000Z

12

Thermal Reactions of Uranium Metal, UO2, U3O8, UF4, and UO2F2 with NF3 to Produce UF6  

SciTech Connect (OSTI)

he objective of this paper is to demonstrate that NF3 fluorinates uranium metal, UO2, UF4, UO3, U3O8, and UO2F2•2H2O to produce the volatile UF6 at temperatures between 100 and 500?C. Thermogravimetric reaction profiles are described that reflect changes in the uranium oxidation state and discrete chemical speciation. Differences in the onset temperatures for each system indicate that NF3-substrate interactions are important for the temperature at which NF3 reacts: U metal > UO3 > UO2 > UO2F2 > UF4 and in fact may indicate different fluorination mechanisms for these various substrates. These studies demonstrate that NF3 is a potential replacement fluorinating agent in the existing nuclear fuel cycle and in oft-proposed actinide volatility reprocessing.

McNamara, Bruce K.; Scheele, Randall D.; Kozelisky, Anne E.; Edwards, Matthew K.

2009-11-01T23:59:59.000Z

13

UO{sub 3} plant turnover - facility description document  

SciTech Connect (OSTI)

This document was developed to provide a facility description for those portions of the UO{sub 3} Facility being transferred to Bechtel Hanford Company, Inc. (BHI) following completion of facility deactivation. The facility and deactivated state condition description is intended only to serve as an overview of the plant as it is being transferred to BHI.

Clapp, D.A.

1995-01-01T23:59:59.000Z

14

Density Functional Theory Calculations of Mass Transport in UO2  

SciTech Connect (OSTI)

In this talk we present results of density functional theory (DFT) calculations of U, O and fission gas diffusion in UO{sub 2}. These processes all impact nuclear fuel performance. For example, the formation and retention of fission gas bubbles induce fuel swelling, which leads to mechanical interaction with the clad thereby increasing the probability for clad breach. Alternatively, fission gas can be released from the fuel to the plenum, which increases the pressure on the clad walls and decreases the gap thermal conductivity. The evolution of fuel microstructure features is strongly coupled to diffusion of U vacancies. Since both U and fission gas transport rates vary strongly with the O stoichiometry, it is also important to understand O diffusion. In order to better understand bulk Xe behavior in UO{sub 2{+-}x} we first calculate the relevant activation energies using DFT techniques. By analyzing a combination of Xe solution thermodynamics, migration barriers and the interaction of dissolved Xe atoms with U, we demonstrate that Xe diffusion predominantly occurs via a vacancy-mediated mechanism. Since Xe transport is closely related to diffusion of U vacancies, we have also studied the activation energy for this process. In order to explain the low value of 2.4 eV found for U migration from independent damage experiments (not thermal equilibrium) the presence of vacancy clusters must be included in the analysis. Next we investigate species transport on the (111) UO{sub 2} surface, which is motivated by the formation of small voids partially filled with fission gas atoms (bubbles) in UO{sub 2} under irradiation. Surface diffusion could be the rate-limiting step for diffusion of such bubbles, which is an alternative mechanism for mass transport in these materials. As expected, the activation energy for surface diffusion is significantly lower than for bulk transport. These results are further discussed in terms of engineering-scale fission gas release models. Finally, oxidation of UO{sub 2} and the importance of cluster formation for understanding thermodynamic and kinetic properties of UO{sub 2+x} are investigated.

Andersson, Anders D. [Los Alamos National Laboratory; Dorado, Boris [CEA; Uberuaga, Blas P. [Los Alamos National Laboratory; Stanek, Christopher R. [Los Alamos National Laboratory

2012-06-26T23:59:59.000Z

15

Etching of UO{sub 2} in NF{sub 3} RF Plasma Glow Discharge  

SciTech Connect (OSTI)

A series of room temperature, low pressure (10.8 to 40 Pa), low power (25 to 210 W) RF plasma glow discharge experiments with UO{sub 2} were conducted to demonstrate that plasma treatment is a viable method for decontaminating UO{sub 2} from stainless steel substrates. Experiments were conducted using NF{sub 3} gas to decontaminate depleted uranium dioxide from stainless-steel substrates. Depleted UO{sub 2} samples each containing 129.4 Bq were prepared from 100 microliter solutions of uranyl nitrate hexahydrate solution. The amorphous UO{sub 2} in the samples had a relatively low density of 4.8 gm/cm{sub 3}. Counting of the depleted UO{sub 2} on the substrate following plasma immersion was performed using liquid scintillation counting with alpha/beta discrimination due to the presence of confounding beta emitting daughter products, {sup 234}Th and {sup 234}Pa. The alpha emission peak from each sample was integrated using a gaussian and first order polynomial fit to improve quantification. The uncertainties in the experimental measurement of the etched material were estimated at about {+-} 2%. Results demonstrated that UO{sub 2} can be completely removed from stainless-steel substrates after several minutes processing at under 200 W. At 180 W and 32.7 Pa gas pressure, over 99% of all UO{sub 2} in the samples was removed in just 17 minutes. The initial etch rate in the experiments ranged from 0.2 to 7.4 {micro}m/min. Etching increased with the plasma absorbed power and feed gas pressure in the range of 10.8 to 40 Pa. A different pressure effect on UO{sub 2} etching was also noted below 50 W in which etching increased up to a maximum pressure, {approximately}23 Pa, then decreased with further increases in pressure.

John M. Veilleux

1999-08-01T23:59:59.000Z

16

Benchmarking of Graphite Reflected Critical Assemblies of UO2  

SciTech Connect (OSTI)

A series of experiments were carried out in 1963 at the Oak Ridge National Laboratory Critical Experiments Facility (ORCEF) for use in space reactor research programs. A core containing 93.2% enriched UO2 fuel rods was used in these experiments. The first part of the experimental series consisted of 253 tightly-packed fuel rods (1.27 cm triangular pitch) with graphite reflectors [1], the second part used 253 graphite-reflected fuel rods organized in a 1.506 cm triangular pitch [2], and the final part of the experimental series consisted of 253 beryllium-reflected fuel rods with a 1.506 cm triangular pitch. [3] Fission rate distribution and cadmium ratio measurements were taken for all three parts of the experimental series. Reactivity coefficient measurements were taken for various materials placed in the beryllium reflected core. The first part of this experimental series has been evaluated for inclusion in the International Reactor Physics Experiment Evaluation Project (IRPhEP) [4] and the International Criticality Safety Benchmark Evaluation Project (ICSBEP) Handbooks, [5] and is discussed below. These experiments are of interest as benchmarks because they support the validation of compact reactor designs with similar characteristics to the design parameters for a space nuclear fission surface power systems. [6

Margaret A. Marshall; John D. Bess

2011-11-01T23:59:59.000Z

17

PUREX/UO3 Facilities deactivation lessons learned history  

SciTech Connect (OSTI)

Disconnecting the criticality alarm permanently in June 1996 signified that the hazards in the PUREX (plutonium-uranium extraction) plant had been so removed and reduced that criticality was no longer a credible event. Turning off the PUREX criticality alarm also marked a salient point in a historic deactivation project, 1 year before its anticipated conclusion. The PUREX/UO3 Deactivation Project began in October 1993 as a 5-year, $222.5- million project. As a result of innovations implemented during 1994 and 1995, the project schedule was shortened by over a year, with concomitant savings. In 1994, the innovations included arranging to send contaminated nitric acid from the PUREX Plant to British Nuclear Fuels, Limited (BNFL) for reuse and sending metal solutions containing plutonium and uranium from PUREX to the Hanford Site tank farms. These two steps saved the project $36.9- million. In 1995, reductions in overhead rate, work scope, and budget, along with curtailed capital equipment expenditures, reduced the cost another $25.6 million. These savings were achieved by using activity-based cost estimating and applying technical schedule enhancements. In 1996, a series of changes brought about under the general concept of ``reengineering`` reduced the cost approximately another $15 million, and moved the completion date to May 1997. With the total savings projected at about $75 million, or 33.7 percent of the originally projected cost, understanding how the changes came about, what decisions were made, and why they were made becomes important. At the same time sweeping changes in the cultural of the Hanford Site were taking place. These changes included shifting employee relations and work structures, introducing new philosophies and methods in maintaining safety and complying with regulations, using electronic technology to manage information, and, adopting new methods and bases for evaluating progress. Because these changes helped generate cost savings and were accompanied by and were an integral part of sweeping ``culture changes,`` the story of the lessons learned during the PUREX Deactivation Project are worth recounting. Foremost among the lessons is recognizing the benefits of ``right to left`` project planning. A deactivation project must start by identifying its end points, then make every task, budget, and organizational decision based on reaching those end points. Along with this key lesson is the knowledge that project planning and scheduling should be tied directly to costing, and the project status should be checked often (more often than needed to meet mandated reporting requirements) to reflect real-time work. People working on a successful project should never be guessing about its schedule or living with a paper schedule that does not represent the actual state of work. Other salient lessons were learned in the PUREX/UO3 Deactivation Project that support these guiding principles. They include recognizing the value of independent review, teamwork, and reengineering concepts; the need and value of cooperation between the DOE, its contractors, regulators, and stakeholders; and the essential nature of early and ongoing communication. Managing a successful project also requires being willing to take a fresh look at safety requirements and to apply them in a streamlined and sensible manner to deactivating facilities; draw on the enormous value of resident knowledge acquired by people over years and sometimes decades of working in old plants; and recognize the value of bringing in outside expertise for certain specialized tasks.This approach makes possible discovering the savings that can come when many creative options are pursued persistently and the wisdom of leaving some decisions to the future. The essential job of a deactivation project is to place a facility in a safe, stable, low-maintenance mode, for an interim period. Specific end points are identified to recognize and document this state. Keeping the limited objectives of the project in mind can guide decisions that reduce risks with minimal manipul

Gerber, M.S.

1996-09-19T23:59:59.000Z

18

DISSOLUTION OF ZIRCALOY 2 CLAD UO2 COMMERCIAL REACTOR FUEL  

SciTech Connect (OSTI)

The primary goal of this investigation was to evaluate the effectiveness of the chop-leach process, with nitric acid solvent, to produce a nominally 300 g/L [U] and 1 M [H{sup +}] product solution. The results of this study show that this processing technique is appropriate for applications in which a low free acid and moderately high U content are desired. The 7.75 L of product solution, which was over 450 g/L in U, was successfully diluted to produce about 13 L of solvent extraction feed that was 302 g/L in U with a [H{sup +}] in the range 0.8-1.2 M. A secondary goal was to test the effectiveness of this treatment for the removal of actinides from Zircaloy cladding to produce a low-level radioactive waste (LLW) cladding product. Analysis of the cladding shows that actinides are present in the cladding at a concentration of about 5000 {eta}Ci/g, which is about 50 times greater than the acceptable transuranium element limit in low level radioactive waste. It appears that the concentration of nitric acid used for this dissolution study (initial concentration 4 M, with 10 M added as the dissolution proceeded) was inadequate to completely digest the UO{sub 2} present in the spent fuel. The mass of insoluble material collected from the initial treatments with nitric acid, 340 g, was much higher than expected, and analysis of this insoluble residue showed that it contained at least 200 g U.

Kessinger, G.; Thompson, M.

2009-08-07T23:59:59.000Z

19

Determination of Gd concentration profile in UO2-Gd2O3 fuel pellets  

E-Print Network [OSTI]

A transversal mapping of the Gd concentration was measured in UO2-Gd2O3 nuclear fuel pellets by electron paramagnetic resonance spectroscopy (EPR). The quantification was made from the comparison with a Gd2O3 reference sample. The nominal concentration in the pellets is UO2: 7.5 % Gd2O3. A concentration gradient was found, which indicates that the Gd2O3 amount diminishes towards the edges of the pellets. The concentration varies from (9.3 +/- 0.5)% in the center to (5.8 +/- 0.3)% in one of the edges. The method was found to be particularly suitable for the precise mapping of the distribution of Gd3+ ions in the UO2 matrix.

D. Tobia; E. L. Winkler; J. Milano; A. Butera; R. Kempf; L. Bianchi; F. Kaufmann

2014-02-28T23:59:59.000Z

20

Determination of Gd concentration profile in UO2-Gd2O3 fuel pellets  

E-Print Network [OSTI]

A transversal mapping of the Gd concentration was measured in UO2-Gd2O3 nuclear fuel pellets by electron paramagnetic resonance spectroscopy (EPR). The quantification was made from the comparison with a Gd2O3 reference sample. The nominal concentration in the pellets is UO2: 7.5 % Gd2O3. A concentration gradient was found, which indicates that the Gd2O3 amount diminishes towards the edges of the pellets. The concentration varies from (9.3 +/- 0.5)% in the center to (5.8 +/- 0.3)% in one of the edges. The method was found to be particularly suitable for the precise mapping of the distribution of Gd3+ ions in the UO2 matrix.

Tobia, D; Milano, J; Butera, A; Kempf, R; Bianchi, L; Kaufmann, F

2014-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "ms uo uo" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

UNIVERSITY OF OREGON SOLAR MONITORING LABORATORY The University of Oregon (UO) Solar Moni-  

E-Print Network [OSTI]

i UNIVERSITY OF OREGON SOLAR MONITORING LABORATORY The University of Oregon (UO) Solar Moni- toring Laboratory has been measuring incident solar radiation since 1975. Current support for this work comes from the Regional Solar Radiation Monitoring Project (RSRMP), a utility consortium project including the Bon

Oregon, University of

22

f Fk66iCOP-] NBSIR 86-3422 uoL_ i 1  

E-Print Network [OSTI]

f Fk66iCOP-] NBSIR 86-3422 uoL_ i 1 The Performance of A Conventional Residential Sized Heat Pump RESIDENTIAL SIZED HEAT PUMP OPERATING WITH A NONAZEOTROPIC BINARY REFRIGERANT MIXTURE William Mulroy David unmodified residential heat pump designed for R22 when charged with a nonazeotropic refrigerant mixture (NARM

Oak Ridge National Laboratory

23

Radiation-Induced Decomposition of U(VI) Phase to Nanocrystals of UO2  

SciTech Connect (OSTI)

U{sup 6+}-phases are common alteration products, under oxidizing conditions, of uraninite and the UO{sub 2} in spent nuclear fuel. These U{sup 6+}-phases are subjected to a radiation field caused by the {alpha}-decay of U, or in the case of spent nuclear fuel, incorporated actinides, such as {sup 239}Pu and {sup 237}Np. In order to evaluate the effects of {alpha}-decay events on the stability of the U{sup 6+}-phases, we report, for the first time, the results of ion beam irradiations (1.0 MeV Kr{sup 2+}) of U{sup 6+}-phases. The heavy-particle irradiations are used to simulate the ballistic interactions of the recoil-nucleus of an {alpha}-decay event with the surrounding structure. The Kr{sup 2+}-irradiation decomposed the U{sup 6+}-phases to UO{sub 2} nanocrystals at doses as low as 0.006 displacements per atom (dpa). U{sup 6+}-phases accumulate substantial radiation doses ({approx}1.0 displacement per atom) within 100,000 years if the concentration of incorporated {sup 239}Pu is as high as 1 wt%. Similar nanocrystals of UO{sub 2} were observed in samples from the natural fission reactors at Oklo, Gabon. Multiple cycles of radiation-induced decomposition to UO{sub 2} followed by alteration to U{sup 6+}-phases provide a mechanism for the remobilization of incorporated radionuclides.

S. Utsunomiya; R.C. Ewing; L. Wang

2005-06-13T23:59:59.000Z

24

additives doped-uo2 pellets: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

additives doped-uo2 pellets First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Journal of Nuclear...

25

UO Organizational Development and Training HUMAN RESOURCES, ORGANIZATIONAL DEVELOPMENT AND TRAINING  

E-Print Network [OSTI]

UO Organizational Development and Training HUMAN RESOURCES, ORGANIZATIONAL DEVELOPMENT AND TRAINING Organizational Development and Training HUMAN RESOURCES, ORGANIZATIONAL DEVELOPMENT AND TRAINING 5210 University with your field of choice. Explore what they have to offer members and consider learning from, and creating

Oregon, University of

26

Theoretical investigation of the impact of grain boundaries and fission gases on UO2 thermal conductivity  

SciTech Connect (OSTI)

Thermal conductivity is one of the most important metrics of nuclear fuel performance. Therefore, it is crucial to understand the impact of microstructure features on thermal conductivity, especially since the microstructure evolves with burn-up or time in the reactor. For example, UO{sub 2} fuels are polycrystalline and for high-burnup fuels the outer parts of the pellet experience grain sub-division leading to a very fine grain structure. This is known to impact important physical properties such as thermal conductivity as fission gas release. In a previous study, we calculated the effect of different types of {Sigma}5 grain boundaries on UO{sub 2} thermal conductivity and predicted the corresponding Kapitza resistances, i.e. the resistance of the grain boundary in relation to the bulk thermal resistance. There have been reports of pseudoanisotropic effects for the thermal conductivity in cubic polycrystalline materials, as obtained from molecular dynamics simulations, which means that the conductivity appears to be a function of the crystallographic direction of the temperature gradient. However, materials with cubic symmetry should have isotropic thermal conductivity. For this reason it is necessary to determine the cause of this apparent anisotropy and in this report we investigate this effect in context of our earlier simulations of UO{sub 2} Kapitza resistances. Another source of thermal resistance comes from fission products and fission gases. Xe is the main fission gas and when generated in sufficient quantity it dissolves from the lattice and forms gas bubbles inside the crystalline structure. We have performed studies of how Xe atoms dissolved in the UO{sub 2} matrix or precipitated as bubbles impact thermal conductivity, both in bulk UO{sub 2} and in the presence of grain boundaries.

Du, Shiyu [Los Alamos National Laboratory; Andersson, Anders D. [Los Alamos National Laboratory; Germann, Timothy C. [Los Alamos National Laboratory; Stanek, Christopher R. [Los Alamos National Laboratory

2012-05-02T23:59:59.000Z

27

Criticality experiments with low enriched UO/sub 2/ fuel rods in water containing dissolved gadolinium  

SciTech Connect (OSTI)

The results obtained in a criticality experiments program performed for British Nuclear Fuels, Ltd. (BNFL) under contract with the United States Department of Energy (USDOE) are presented in this report along with a complete description of the experiments. The experiments involved low enriched UO/sub 2/ and PuO/sub 2/-UO/sub 2/ fuel rods in water containing dissolved gadolinium, and are in direct support of BNFL plans to use soluble compounds of the neutron poison gadolinium as a primary criticality safeguard in the reprocessing of low enriched nuclear fuels. The experiments were designed primarily to provide data for validating a calculation method being developed for BNFL design and safety assessments, and to obtain data for the use of gadolinium as a neutron poison in nuclear chemical plant operations - particularly fuel dissolution. The experiments program covers a wide range of neutron moderation (near optimum to very under-moderated) and a wide range of gadolinium concentration (zero to about 2.5 g Gd/l). The measurements provide critical and subcritical k/sub eff/ data (1 greater than or equal to k/sub eff/ greater than or equal to 0.87) on fuel-water assemblies of UO/sub 2/ rods at two enrichments (2.35 wt % and 4.31 wt % /sup 235/U) and on mixed fuel-water assemblies of UO/sub 2/ and PuO/sub 2/-UO/sub 2/ rods containing 4.31 wt % /sup 235/U and 2 wt % PuO/sub 2/ in natural UO/sub 2/ respectively. Critical size of the lattices was determined with water containing no gadolinium and with water containing dissolved gadolinium nitrate. Pulsed neutron source measurements were performed to determine subcritical k/sub eff/ values as additional amounts of gadolinium were successively dissolved in the water of each critical assembly. Fission rate measurements in /sup 235/U using solid state track recorders were made in each of the three unpoisoned critical assemblies, and in the near-optimum moderated and the close-packed poisoned assemblies of this fuel.

Bierman, S.R.; Murphy, E.S.; Clayton, E.D.; Keay, R.T.

1984-02-01T23:59:59.000Z

28

UO{sub 2} corrosion in high surface-area-to-volume batch experiments.  

SciTech Connect (OSTI)

Unsaturated drip tests have been used to investigate the alteration of unirradiated UO{sub 2} and spent UO{sub 2} fuel in an unsaturated environment such as may be expected in the proposed repository at Yucca Mountain. In these tests, simulated groundwater is periodically injected onto a sample at 90 C in a steel vessel. The solids react with the dripping groundwater and water condensed on surfaces to form a suite of U(VI) alteration phases. Solution chemistry is determined from leachate at the bottom of each vessel after the leachate stops interacting with the solids. A more detailed knowledge of the compositional evolution of the leachate is desirable. By providing just enough water to maintain a thin film of water on a small quantity of fuel in batch experiments, we can more closely monitor the compositional changes to the water as it reacts to form alteration phases.

Bates, J. K.; Finch, R. J.; Hanchar, J. M.; Wolf, S. F.

1997-12-08T23:59:59.000Z

29

UO2 CORROSION IN HIGH SURFACE-AREA-TO-VOLUME BATCH EXPERIMENTS  

SciTech Connect (OSTI)

Unsaturated drip tests have been used to investigate the alteration of unirradiated UO{sub 2} and spent UO{sub 2} fuel in an unsaturated environment, such as may be expected in the proposed repository at Yucca Mountain. In these tests, simulated groundwater is periodically injected onto a sample at 90 C in a steel vessel. The solids react with the dripping groundwater and water condensed on surfaces to form a suite of U(VI) alteration phases. Solution chemistry is determined from leachate at the bottom of each vessel after the leachate stops interacting with the solids. A more detailed knowledge of the compositional evolution of the leachate is desirable. By providing just enough water to maintain a thin film of water on a small quantity of fuel in batch experiments, we can more closely monitor the compositional changes to the water as it reacts to form alteration phases.

Finch, Robert J.; Wolf, Stephen F.; Hanchar, John M.; Bates, John K.

1998-05-11T23:59:59.000Z

30

Bubble formation and Kr distribution in Kr-irradiated UO2  

SciTech Connect (OSTI)

In situ and ex situ transmission electron microscopy observation of small Kr bubbles in both single-crystal and polycrystalline UO2 were conducted to understand the inert gas bubble behavior in oxide nuclear fuel. The bubble size and volume swelling are shown as a weak function of ion dose but strongly depend on the temperature. The Kr bubble formation at room temperature was observed for the first time. The depth profiles of implanted Kr determined by atom probe tomography are in good agreement with the calculated profiles by SRIM, but the measured concentration of Kr is about 1/3 of calculated one. This difference is mainly due to low solubility of Kr in UO2 matrix, which has been confirmed by both density-functional theory calculations and chemical equilibrium analysis.

L.F. He; B. Valderrama; A.-R. Hassan; J. Yu; M. Gupta; J. Pakarinen; H.B. Henderson; J. Gan; M.A. Kirk; A.T. Nelson; M.V. Manuel; A. El-Azab; T.R. Allen

2015-01-01T23:59:59.000Z

31

Recovery of UO[sub 2]/PuO[sub 2] in IFR electrorefining process  

DOE Patents [OSTI]

A process is described for converting PuO[sub 2] and UO[sub 2] present in an electrorefiner to the chlorides, by contacting the PuO[sub 2] and UO[sub 2] with Li metal in the presence of an alkali metal chloride salt substantially free of rare earth and actinide chlorides for a time and at a temperature sufficient to convert the UO[sub 2] and PuO[sub 2] to metals while converting Li metal to Li[sub 2]O. Li[sub 2]O is removed either by reducing with rare earth metals or by providing an oxygen electrode for transporting O[sub 2] out of the electrorefiner and a cathode, and thereafter applying an emf to the electrorefiner electrodes sufficient to cause the Li[sub 2]O to disassociate to O[sub 2] and Li metal but insufficient to decompose the alkali metal chloride salt. The U and Pu and excess lithium are then converted to chlorides by reaction with CdCl[sub 2].

Tomczuk, Z.; Miller, W.E.

1994-10-18T23:59:59.000Z

32

Oxidative Dissolution of UO2 in a Simulated Groundwater Containing Synthetic Nanocrystalline Mackinawite  

SciTech Connect (OSTI)

The long-term success of in situ reductive immobilization of uranium (U) depends on the stability of U(IV) precipitates (e.g., uraninite) under oxic conditions. Field and laboratory studies have implicated iron sulfide minerals as redox buffers or oxidant scavengers that may slow oxidation of reduced U(VI) solid phases by oxygen and Fe(III). Yet, the inhibition mechanism(s) and reaction rates of uraninite (UO2) oxidative dissolution by oxic species such as oxygen in FeS-bearing systems remain largely unresolved. To address this knowledge gap, abiotic batch experiments were conducted with synthetic UO2 in the presence and absence of synthetic mackinawite (FeS) under simulated groundwater conditions of pH = 7, PO2 = 0.02 atm, and PCO2 = 0.05 atm (equivalent to total dissolved carbonate of 0.01 M). The kinetic profiles of dissolved uranium indicate that FeS inhibited UO2 dissolution for 51 hr by effectively scavenging oxygen and keeping dissolved oxygen (DO) low. During this time period, oxidation of structural Fe(II) and S(-II) of FeS were found to control the DO levels, leading to the formation of iron oxyhydroxides and elemental sulfur, respectively, as verified by X-ray diffraction (XRD), Mössbauer and X-ray absorption spectroscopy (XAS). After FeS was depleted due to oxidation, DO levels increased and UO2 oxidative dissolution occurred at an initial rate of rm = 1.2 ± 0.4 ×10-8 mol•g-1•s-1, higher than rm = 5.4 ± 0.3 ×10-9 mol•g-1•s-1 in the control experiment where FeS was absent. Soluble U(VI) products were adsorbed by iron oxyhydroxides (i.e. nanogoethite and ferrihydrite) formed from FeS oxidation, which facilitated the detachment of U(VI) surface complexes and more rapid dissolution of UO2. XAS analysis confirmed the adsorption of U(VI) species, and also showed that U(VI) was not significantly incorporated into iron oxyhydroxide structure. This work reveals that both the oxygen scavenging by FeS and the adsorption of U(VI) to FeS oxidation products may be important in U reductive immobilization systems subject to redox cycling events.

Bi, Yuqiang; Hyun, Sung Pil; Kukkadapu, Ravi K.; Hayes, Kim F.

2013-02-01T23:59:59.000Z

33

Leaching patterns and secondary phase formation during unsaturated leaching of UO{sub 2} at 90{degrees}C  

SciTech Connect (OSTI)

Experiments are being conducted that examine the reaction of UO{sub 2} with dripping oxygenated ground water at 90{degrees}C. The experiments are designed to identify secondary phases formed during UO{sub 2} alteration, evaluate parameters controlling U release, and act as scoping tests for studies with spent fuel. This study is the first of its kind that examines the alteration of UO{sub 2} under unsaturated conditions expected to exist at the proposed Yucca Mountain repository site. Results suggest the UO{sub 2} matrix will readily react within a few months after being exposed to simulated Yucca Mountain conditions. A pulse of rapid U release, combined with the formation of dehydrated schoepite on the UO{sub 2} surface, characterizes the reaction between one to two years. Rapid dissolution of intergrain boundaries and spallation of UO{sub 2} granules appears to be responsible for much of the U released. Differential release of the UO{sub 2} granules may be responsible for much of the variation observed between duplicate experiments. Less than 5 wt % of the released U remains in solution or in a suspended form, while the remaining settles out of solution as fine particles or is reprecipitated as secondary phases. Subsequent to the pulse period, U release rates decline and a more stable assemblage of uranyl silicate phases are formed by incorporating cations from the ground water leachant. Uranophane, boltwoodite, and sklodowskite appear as the final solubility limiting phases that form in these tests. This observed paragenetic sequence (from uraninite to schoepite-type phases to uranyl silicates) is identical to those observed in weathered zones of natural uraninite occurrences. The combined results indicate that the release of radionuclides from spent fuel may not be limited by U solubility constraints, but that spallation of particulate matter may be an important, if not the dominant release mechanism affecting release.

Wronkiewicz, D.J.; Bates, J.K.; Gerding, T.J.; Veleckis, E.; Tani, B.S.

1991-11-01T23:59:59.000Z

34

Feasibility of Partial ZrO[subscript 2] Coatings on Outer Surface of Annular UO[subscript 2] Pellets to Control Gap Conductance  

E-Print Network [OSTI]

The viability of depositing a thin porous coating of zirconia on the outer surface of an annular UO[subscript 2] pellet

Feinroth, H.

35

Excited States and Luminescent Properties of UO2F2 and Its Solvated Complexes in Aqueous Solution  

SciTech Connect (OSTI)

The electronic absorption and emission spectra of free UO2F2 and its water solvated complexes below 32,000 cm?1 are investigated at the levels of ab initio CASPT2 and CCSD(T) with inclusion of scalar relativistic and spin-orbit coupling effects. The influence of the water coordination on the electronic spectra of UO2F2 is explored by investigating the excited states of solvated complexes (H2O)nUO2F2 (n = 1?3). In these uranyl-complexes, water coordination is found to have appreciable influence on the 3? (? = 1g) character of the luminescent state and on the electronic spectral shape. The simulated luminescence spectral curves based on the calculated spectral parameters of (H2O)nUO2F2 from CCSD(T) approach agree well with experimental spectra in aqueous solution at both near liquid helium temperature and room temperature. The possible luminescence spectra of free UO2F2 in gas phase are predicted based on CASPT2 and CCSD(T) results, respectively, by considering three symmetric vibration modes. The effect of competition between spin-orbital coupling and ligand field repulsion on the luminescent state properties is discussed.

Su, Jing; Wang, Zheming; Pan, Duoqiang; Li, Jun

2014-08-20T23:59:59.000Z

36

Identification of secondary phases formed during unsaturated reaction of UO{sub 2} with EJ-13 water  

SciTech Connect (OSTI)

A set of experiments, wherein UO{sub 2} has been contacted by dripping water, has been conducted over a period of 182.5 weeks. The experiments are being conducted to develop procedures to study spent fuel reaction under unsaturated conditions that are expected to exist over the lifetime of the proposed Yucca Mountain repository site. One half of the experiments have been terminated, while one half are ongoing. Analyses of solutions that have dripped from the reacted UO{sub 2} have been performed for all experiments, while the reacted UO{sub 2} surfaces have been examined for the terminated experiments. A pulse of uranium release from the UO{sub 2} solid, combined with the formation of schoepite on the surface of the UO{sub 2}, was observed between 39 and 96 weeks of reaction. Thereafter, the uranium release decreased and a second set of secondary phases was observed. The latter phases incorporated cations from the EJ-13 water and included boltwoodite, uranophane, sklodowskite, compreignacite, and schoepite. The experiments are continuing to monitor whether additional changes in solution chemistry or secondary phase formation occurs. 6 refs., 2 figs., 2 tabs.

Bates, J.K.; Tani, B.S.; Veleckis, E.

1989-11-01T23:59:59.000Z

37

Identification of secondary phases formed during unsaturated reaction of UO{sub 2} with EJ-13 water  

SciTech Connect (OSTI)

A set of experiments, wherein UO{sub 2} has been contacted by dripping water, has been conducted over a period of 182.5 weeks. The experiments are being conducted to develop procedures to study spent fuel reaction under unsaturated conditions that are expected to exist over the lifetime of the proposed Yucca Mountain repository site. One half of the experiments have been terminated, while one half are ongoing. Analyses of solutions that have dripped from the reacted UO{sub 2} have been performed for all experiments, while reacted UO{sub 2} surfaces have been examined for the terminated experiments. A pulse of uranium release from the UO{sub 2} solid, combined with the formation of schoepite on the surface of the UO{sub 2}, was observed between 39 and 96 weeks of reaction. Thereafter, the uranium release decreased and a second set of secondary phases was observed. The latter phases incorporated cations from the EJ-13 water and include boltwoodite, uranophane, sklodowskite, compreignacite, and schoepite. The experiments are continuing to monitor whether additional changes in solution chemistry or secondary phase formation occurs.

Bates, J.K.; Tani, B.S.; Veleckis, E.; Wronkiewicz, D.J. [Argonne National Lab., IL (USA)

1990-12-31T23:59:59.000Z

38

Vibrational Spectroscopy of Mass Selected [UO2(ligand)n]2+ Complexes in the Gas Phase  

SciTech Connect (OSTI)

The gas-phase infrared spectra of discrete uranyl ([UO2]2+) complexes ligated with acetone and/or acetonitrile were used to evaluate systematic trends of ligation on the position of the O=U=O stretch, and to enable rigorous comparison with the results of computational studies. Ionic uranyl complexes isolated in a Fourier transform ion cyclotron resonance mass spectrometer were fragmented via infrared multiphoton dissociation using a free electron laser scanned over the mid-IR wavelengths. The asymmetric O=U=O stretching frequency was measured at 1017 cm-1 for [UO2(CH3COCH3)2]2+, and was systematically red shifted to 1000 and 988 cm-1 by the addition of a third and fourth acetone ligands, respectively, which was consistent with more donation of electron density to the uranium center in complexes with higher coordination number. The experimental measurements were in good agreement with values generated computationally using LDA, B3LYP, and ZORA-PW91 approaches. In contrast to the uranyl frequency shifts, the carbonyl frequencies of the acetone ligands were progressively blue shifted as the number of ligands increased from 2 to 4, and approached that of free acetone. This observation was consistent with the formation of weaker noncovalent bonds between uranium and the carbonyl oxygen as the extent of ligation increases. Similar trends were observed for [UO2(CH3CN)n]2+ complexes although the magnitude of the red shift in the uranyl frequency upon addition more acetonitrile ligands was smaller than for acetone, consistent with the more modest nucleophilic nature of acetonitrile. This conclusion was amplified by the uranyl stretching frequencies measured for mixed acetone/acetonitrile complexes, which showed that substitution of one acetone for one acetonitrile produced a modest red shift of 3 to 6 cm-1.

Gary S. Groenewold; Anita Gianotto; Michael Vanstipdonk; Kevin C. Cossel; David T. Moore,; Nick Polfer; Jos Oomens

2006-03-01T23:59:59.000Z

39

Final Version: Orbital Specificity in the Unoccupied States of UO2 from Resonant Inverse Photoelectron Spectroscopy  

SciTech Connect (OSTI)

One of the crucial questions of all actinide electronic structure determinations is the issue of 5f versus 6d character and the distribution of these components across the density of states. Here, a break-though experiment is discussed, which has allowed the direct determination of the U5f and U6d contributions to the unoccupied density of states (UDOS) in Uranium Dioxide. A novel Resonant Inverse Photoelectron (RIPES) and X-ray Emission Spectroscopy (XES) investigation of UO{sub 2} is presented. It is shown that the U5f and U6d components are isolated and identified unambiguously.

Tobin, J G; Yu, S W

2012-03-12T23:59:59.000Z

40

Solar and Photovoltaic Data from the University of Oregon Solar Radiation Monitoring Laboratory (UO SRML)  

DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

The UO SRML is a regional solar radiation data center whose goal is to provide sound solar resource data for planning, design, deployment, and operation of solar electric facilities in the Pacific Northwest. The laboratory has been in operation since 1975. Solar data includes solar resource maps, cumulative summary data, daily totals, monthly averages, single element profile data, parsed TMY2 data, and select multifilter radiometer data. A data plotting program and other software tools are also provided. Shade analysis information and contour plots showing the effect of tilt and orientation on annual solar electric system perfomance make up a large part of the photovoltaics data.(Specialized Interface)

Note: This page contains sample records for the topic "ms uo uo" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

An Overview of Current and Past W-UO[2] CERMET Fuel Fabrication Technology  

SciTech Connect (OSTI)

Studies dating back to the late 1940s performed by a number of different organizations and laboratories have established the major advantages of Nuclear Thermal Propulsion (NTP) systems, particularly for manned missions. A number of NTP projects have been initiated since this time; none have had any sustained fuel development work that appreciably contributed to fuel fabrication or performance data from this era. As interest in these missions returns and previous space nuclear power researchers begin to retire, fuel fabrication technologies must be revisited, so that established technologies can be transferred to young researchers seamlessly and updated, more advanced processes can be employed to develop successful NTP fuels. CERMET fuels, specifically W-UO2, are of particular interest to the next generation NTP plans since these fuels have shown significant advantages over other fuel types, such as relatively high burnup, no significant failures under severe transient conditions, capability of accommodating a large fission product inventory during irradiation and compatibility with flowing hot hydrogen. Examples of previous fabrication routes involved with CERMET fuels include hot isostatic pressing (HIPing) and press and sinter, whereas newer technologies, such as spark plasma sintering, combustion synthesis and microsphere fabrication might be well suited to produce high quality, effective fuel elements. These advanced technologies may address common issues with CERMET fuels, such as grain growth, ductile to brittle transition temperature and UO2 stoichiometry, more effectively than the commonly accepted ‘traditional’ fabrication routes. Bonding of fuel elements, especially if the fabrication process demands production of smaller element segments, must be investigated. Advanced brazing techniques and compounds are now available that could produce a higher quality bond segment with increased ease in joining. This paper will briefly address the history of CERMET fuel fabrication technology as related to the GE 710 and ANL Nuclear Rocket Programs, in addition to discussing future plans, viable alternatives and preliminary investigations for W-UO2 CERMET fuel fabrication. The intention of the talk is to provide the brief history and tie in an overview of current programs and investigations as related to NTP based W-UO2 CERMET fuel fabrication, and hopefully peak interest in advanced fuel fabrication technologies.

Douglas E. Burkes; Daniel M. Wachs; James E. Werner; Steven D. Howe

2007-06-01T23:59:59.000Z

42

Grain boundary corrosion and alteration phase formation during the oxidative dissolution of UO{sub 2} pellets  

SciTech Connect (OSTI)

Alteration behavior of UO{sub 2} pellets following reaction under unsaturated drip-test conditions at 90 C for up to 10 years was examined by solid phase and leachate analyses. Sample reactions were characterized by preferential dissolution of grain boundaries between the original press-sintered UO{sub 2} granules comprising the samples, development of a polygonal network of open channels along the intergrain boundaries, and spallation of surface granules that had undergone severe grain boundary corrosion. The development of a dense mat of alteration phases after 2 years of reaction trapped loose granules, resulting in reduced rates of particulate U release. The paragenetic sequence of alteration phases that formed on the present samples was similar to that observed in surficial weathering zones of natural uraninite (UO{sub 2}) deposits, with alkali and alkaline earth uranyl silicates representing the long-term solubility-limiting phases for U in both systems.

Wronkiewicz, D.J.; Buck, E.C.; Bates, J.K.

1996-12-31T23:59:59.000Z

43

Evaluation of Heterogeneous Options: Effects of MgO versus UO2 Matrix Selection for Minor Actinide Targets in a Sodium Fast Reactor  

SciTech Connect (OSTI)

The primary focus of this work was to compare MgO with UO2 as target matrix material options for burning minor actinides in a transmutation target within a sodium fast reactor. This analysis compared the transmutation performance of target assemblies having UO2 matrix to those having specifically MgO inert matrix.

M. Pope; S. Bays; R. Ferrer

2008-03-01T23:59:59.000Z

44

Dissolution characteristics of mixed UO{sub 2} powders in J-13 water under saturated conditions  

SciTech Connect (OSTI)

The Yucca Mountain Project/Spent Fuel program at Argonne National Laboratory is designed to determine radionuclide release rates by exposing high-level waste to repository-relevant groundwater. To gain experience for the tests with spent fuel, a scoping experiment was conducted at room temperature to determine the uranium release rate from an unirradiated UO{sub 2} powder mixture (14.3 wt % enrichment in {sup 235}U) to J-13 water under saturated conditions. Another goal set for the experiment was to develop a method for utilizing isotope dilution techniques to determine whether the dissolution rate of UO{sub 2} matrix is in accordance with an existing kinetic model. Results of these analyses revealed unequal uranium dissolution rates from the enriched and depleted portions of the powder mixture because of undisclosed differences between them. Although the presence of this inhomogeneity has precluded the application of the kinetic model, it also provided an opportunity to elaborate on the utilization of isotope dilution data in recognizing and quantifying such conditions. Detailed listings of uranium release and solution chemistry data are presented. Other problems commonly associated with spent fuel, such as the effectiveness of filtering media, the existence of uranium concentration peaks during early stages of the leach tests, the need for concentration corrections due to water replenishments of sample volumes, and experience derived from isotope dilution data are discussed in the context of the present results. 10 refs., 5 figs., 7 tabs.

Veleckis, E.; Hoh, J.C.

1991-03-01T23:59:59.000Z

45

RELAP5/MOD3.2 analysis of a VVER-1000 reactor with UO[2] fuel and MOX fuel  

E-Print Network [OSTI]

.2 results showed a good agreement with calculations obtained with TECH-M computer program. The cladding temperatures of the MOX assembly have been compared with that of the hot UO? assembly. The peak cladding temperature of MOX assembly is about 55 K higher...

Fu, Chun

2012-06-07T23:59:59.000Z

46

Evaluation of sintering effects on SiC incorporated UO2 kernels under Ar and Ar-4%H2 environments  

SciTech Connect (OSTI)

Silicon carbide (SiC) is suggested as an oxygen getter in UO2 kernels used for TRISO particle fuels to lower oxygen potential and prevent kernel migration during irradiation. Scanning electron microscopy and X-ray diffractometry analyses performed on sintered kernels verified that internal gelation process can be used to incorporate SiC in urania fuel kernels. Sintering in either Ar or Ar-4%H2 at 1500 C lowered the SiC content in the UO2 kernels to some extent. Formation of UC was observed as the major chemical phase in the process, while other minor phases such as U3Si2C2, USi2, U3Si2, and UC2 were also identified. UC formation was presumed to be occurred by two reactions. The first was the SiC reaction with its protective SiO2 oxide layer on SiC grains to produce volatile SiO and free carbon that subsequently reacted with UO2 to form UC. The second process was direct UO2 reaction with SiC grains to form SiO, CO, and UC, especially in Ar-4%H2. A slightly higher density and UC content was observed in the sample sintered in Ar-4%H2, but the use of both atmospheres produced kernels with ~95% of theoretical density. It is suggested that incorporating CO in the sintering gas would prevent UC formation and preserve the initial SiC content.

Silva, Chinthaka M [ORNL] [ORNL; Lindemer, Terrence [Harbach Engineering and Solutions] [Harbach Engineering and Solutions; Hunt, Rodney Dale [ORNL] [ORNL; Collins, Jack Lee [ORNL] [ORNL; Terrani, Kurt A [ORNL] [ORNL; Snead, Lance Lewis [ORNL] [ORNL

2013-01-01T23:59:59.000Z

47

High Thermal Conductivity UO2-BeO Nulcear Fuel: Neutronic Performance Assessments and Overview of Fabrication  

E-Print Network [OSTI]

The objective of this work was to evaluate a new high conductivity nuclear fuel form. Uranium dioxide (UO2) is a very effective nuclear fuel, but it’s performance is limited by its low thermal conductivity. The fuel concept considered here is a...

Naramore, Michael J

2010-08-03T23:59:59.000Z

48

14UO TANK,OPENING REPORT NO.5. October 20th -November 26th (37 days total; 27 working days).  

E-Print Network [OSTI]

14UO TANK,OPENING REPORT NO.5. October 20th - November 26th (37 days total; 27 working days). Since the tank was last closed the accelerator ran for 97 days.until this opening which was scheduled to replace was done during the tank-open period. We believe that there would be value in gIvIng our assessments

Chen, Ying

49

NEAMS FPL M2 Milestone Report: Development of a UO? Grain Size Model using Multicale Modeling and Simulation  

SciTech Connect (OSTI)

This report summarizes development work funded by the Nuclear Energy Advanced Modeling Simulation program's Fuels Product Line (FPL) to develop a mechanistic model for the average grain size in UO? fuel. The model is developed using a multiscale modeling and simulation approach involving atomistic simulations, as well as mesoscale simulations using INL's MARMOT code.

Tonks, Michael R. [Idaho National Laboratory (INL), Idaho Falls, ID (United States); Zhang, Yongfeng [Idaho National Laboratory (INL), Idaho Falls, ID (United States); Bai, Xianming [Idaho National Laboratory (INL), Idaho Falls, ID (United States)

2014-06-01T23:59:59.000Z

50

Fire hazards analysis for the uranium oxide (UO{sub 3}) facility  

SciTech Connect (OSTI)

The Fire Hazards Analysis (FHA) documents the deactivation end-point status of the UO{sub 3} complex fire hazards, fire protection and life safety systems. This FHA has been prepared for the Uranium Oxide Facility by Westinghouse Hanford Company in accordance with the criteria established in DOE 5480.7A, Fire Protection and RLID 5480.7, Fire Protection. The purpose of the Fire Hazards Analysis is to comprehensively and quantitatively assess the risk from a fire within individual fire areas in a Department of Energy facility so as to ascertain whether the objectives stated in DOE Order 5480.7, paragraph 4 are met. Particular attention has been paid to RLID 5480.7, Section 8.3, which specifies the criteria for deactivating fire protection in decommission and demolition facilities.

Wyatt, D.M.

1994-12-06T23:59:59.000Z

51

D9 experiment: heat removal from stratified UO/sub 2/ debris  

SciTech Connect (OSTI)

The D9 experiment investigated the coolability of a shallow (77 mm), stratified urania bed in sodium. The bed was fission heated in the Annular Core Research Reactor (ACRR) at Sandia National Laboratories to simulate the effects of radioactive decay heating. It was the first stratified debris bed experiment to use an extended UO/sub 2/ particle size distribution (0.038 to 4.0 mm). Dryout occurred at powers ranging from 0.10 to 0.58 W/g, which was close to the incipient boiling power and before channels penetrated the subcooled zone in the bed, even with subcoolings as low as 80/sup 0/C. Channel penetration was observed after dryout began, but the bed became only moderately more coolable. All these observations agree with current models.

Ottinger, C A; Mitchell, G W; Lipinski, R J; Kelly, J E

1985-04-01T23:59:59.000Z

52

RADIATION-INDUCED DECOMPOSITION OF U(VI) ALTERATION PHASES OF UO2  

SciTech Connect (OSTI)

U{sup 6+}-phases are common alteration products of spent nuclear fuel under oxidizing conditions, and they may potentially incorporate actinides, such as long-lived {sup 239}Pu and {sup 237}Np, delaying their transport to the biosphere. In order to evaluate the ballistic effects of {alpha}-decay events on the stability of the U{sup 6+}-phases, we report, for the first time, the results of ion beam irradiations (1.0 MeV Kr{sup 2+}) for six different structures of U{sup 6+}-phases: uranophane, kasolite, boltwoodite, saleeite, carnotite, and liebigite. The target uranyl-minerals were characterized by powder X-ray diffraction and identification confirmed by SAED (selected area electron diffraction) in TEM (transmission electron microscopy). The TEM observation revealed no initial contamination of uraninite in these U{sup 6+} phases. All of the samples were irradiated with in situ TEM observation using 1.0 MeV Kr{sup 2+} in the IVEM (intermediate-voltage electron microscope) at the IVEM-Tandem Facility of Argonne National Laboratory. The ion flux was 6.3 x 10{sup 11} ions/cm{sup 2}/sec. The specimen temperatures during irradiation were 298 and 673 K, respectively. The Kr{sup 2+}-irradiation decomposed the U{sup 6+}-phases to nanocrystals of UO{sub 2} at doses as low as 0.006 dpa. The cumulative doses for the pure U{sup 6+}-phases, e.g., uranophane, at 0.1 and 1 million years (m.y.) are calculated to be 0.009 and 0.09 dpa using SRIM2003. However, with the incorporation of 1 wt.% {sup 239}Pu, the calculated doses reach 0.27 and {approx}1.00 dpa in ten thousand and one hundred thousand years, respectively. Under oxidizing conditions, multiple cycles of radiation-induced decomposition to UO{sub 2} followed by alteration to U{sup 6+}-phases should be further investigated to determine the fate of trace elements that may have been incorporated in the U{sup 6+}-phases.

S. Utsunomiya; R.C. Ewing

2005-09-08T23:59:59.000Z

53

A Validation Study of Pin Heat Transfer for UO2 Fuel Based on the IFA-432 Experiments  

SciTech Connect (OSTI)

The IFA-432 (Integrated Fuel Assessment) experiments from the International Fuel Performance Experiments (IFPE) database were designed to study the effects of gap size, fuel density, and fuel densification on fuel centerline temperature in light-water-reactor fuel. An evaluation of nuclear fuel pin heat transfer in the FRAPCON-3.4 and Exnihilo codes for uranium dioxide (UO$_2$) fuel systems was performed, with a focus on the densification stage (2.2 \\unitfrac{GWd}{MT(UO$_{2}$)}). In addition, sensitivity studies were performed to evaluate the effect of the radial power shape and approximations to the geometry to account for the thermocouple hole. The analysis demonstrated excellent agreement for rods 1, 2, 3, and 5 (varying gap thicknesses and density with traditional fuel), demonstrating the accuracy of the codes and their underlying material models for traditional fuel. For rod 6, which contained unstable fuel that densified an order of magnitude more than traditional, stable fuel, the magnitude of densification was over-predicted and the temperatures were outside of the experimental uncertainty. The radial power shape within the fuel was shown to significantly impact the predicted centerline temperatures, whereas modeling the fuel at the thermocouple location as either annular or solid was relatively negligible. This has provided an initial benchmarking of the pin heat transfer capability of Exnihilo for UO$_2$ fuel with respect to a well-validated nuclear fuel performance code.

Phillippe, Aaron M [ORNL; Clarno, Kevin T [ORNL; Banfield, James E [ORNL; Ott, Larry J [ORNL; Philip, Bobby [ORNL; Berrill, Mark A [ORNL; Sampath, Rahul S [ORNL; Allu, Srikanth [ORNL; Hamilton, Steven P [ORNL

2014-01-01T23:59:59.000Z

54

Development of an Innovative High-Thermal Conductivity UO2 Ceramic Composites Fuel Pellets with Carbon Nano-Tubes Using Spark Plasma Sintering  

SciTech Connect (OSTI)

Uranium dioxide (UO2) is the most common fuel material in commercial nuclear power reactors. Despite its numerous advantages such as high melting point, good high-temperature stability, good chemical compatibility with cladding and coolant, and resistance to radiation, it suffers from low thermal conductivity that can result in large temperature gradients within the UO2 fuel pellet, causing it to crack and release fission gases. Thermal swelling of the pellets also limits the lifetime of UO2 fuel in the reactor. To mitigate these problems, we propose to develop novel UO2 fuel with uniformly distributed carbon nanotubes (CNTs) that can provide high-conductivity thermal pathways and can eliminate fuel cracking and fission gas release due to high temperatures. CNTs have been investigated extensively for the past decade to explore their unique physical properties and many potential applications. CNTs have high thermal conductivity (6600 W/mK for an individual single- walled CNT and >3000 W/mK for an individual multi-walled CNT) and high temperature stability up to 2800°C in vacuum and about 750°C in air. These properties make them attractive candidates in preparing nano-composites with new functional properties. The objective of the proposed research is to develop high thermal conductivity of UO2–CNT composites without affecting the neutronic property of UO2 significantly. The concept of this goal is to utilize a rapid sintering method (5–15 min) called spark plasma sintering (SPS) in which a mixture of CNTs and UO2 powder are used to make composites with different volume fractions of CNTs. Incorporation of these nanoscale materials plays a fundamentally critical role in controlling the performance and stability of UO2 fuel. We will use a novel in situ growth process to grow CNTs on UO2 particles for rapid sintering and develop UO2-CNT composites. This method is expected to provide a uniform distribution of CNTs at various volume fractions so that a high thermally conductive UO2-CNT composite is obtained with a minimal volume fraction of CNTs. The mixtures are sintered in the SPS facility at a range of temperatures, pressures, and time durations so as to identify the optimal processing conditions to obtain the desired microstructure of sintered UO2-CNT pellets. The second objective of the proposed work is to identify the optimal volume fraction of CNTs in the microstructure of the composites that provides the desired high thermal conductivity yet retaining the mechanical strength required for efficient function as a reactor fuel. We will systematically study the resulting microstructure (grain size, porosity, distribution of CNTs, etc.) obtained at various SPS processing conditions using optical microscopy, scanning electron microscopy (SEM), and transmission electron microscope (TEM). We will conduct indentation hardness measurements and uniaxial strength measurements as a function of volume fraction of CNTs to determine the mechanical strength and compare them to the properties of UO2. The fracture surfaces will be studied to determine the fracture characteristics that may relate to the observed cracking during service. Finally, we will perform thermal conductivity measurements on all the composites up to 1000° C. This study will relate the microstructure, mechanical properties, and thermal properties at various volume fractions of CNTs. The overall intent is to identify optimal processing conditions that will provide a well-consolidated compact with optimal microstructure and thermo-mechanical properties. The deliverables include: (1) fully characterized UO2-CNT composite with optimal CNT volume fraction and high thermal conductivity and (2) processing conditions for production of UO2-CNT composite pellets using SPS method.

Subhash, Ghatu; Wu, Kuang-Hsi; Tulenko, James

2014-03-10T23:59:59.000Z

55

Intergranular fracture in UO{sub 2}: derivation of traction-separation law from atomistic simulations  

SciTech Connect (OSTI)

In this study, the intergranular fracture behavior of UO{sub 2} was studied by molecular dynamics simulations using the Basak potential. In addition, the constitutive traction-separation law was derived from atomistic data using the cohesive-zone model. In the simulations a bicrystal model with the (100) symmetric tilt ?5 grain boundaries was utilized. Uniaxial tension along the grain boundary normal was applied to simulate Mode-I fracture. The fracture was observed to propagate along the grain boundary by micro-pore nucleation and coalescence, giving an overall intergranular fracture behavior. Phase transformations from the Fluorite to the Rutile and Scrutinyite phases were identified at the propagating crack tips. These new phases are metastable and they transformed back to the Fluorite phase at the wake of crack tips as the local stress concentration was relieved by complete cracking. Such transient behavior observed at atomistic scale was found to substantially increase the energy release rate for fracture. Insertion of Xe gas into the initial notch showed minor effect on the overall fracture behavior. (authors)

Zhang, Yongfeng; Millett, P.C.; Tonks, M.R.; Bai, Xian-Ming; Biner, S.B. [Fuels Modeling and Simulation Department, Idaho National Laboratory - INL, Idaho Falls, ID 83415 (United States)

2013-07-01T23:59:59.000Z

56

Intergranular fracture in UO2: derivation of traction-separation law from atomistic simulations  

SciTech Connect (OSTI)

In this study, the intergranular fracture behavior of UO2 was studied by molecular dynamics simulations using the Basak potential. In addition, the constitutive traction-separation law was derived from atomistic data using the cohesive-zone model. In the simulations a bicrystal model with the (100) symmetric tilt E5 grain boundaries was utilized. Uniaxial tension along the grain boundary normal was applied to simulate Mode-I fracture. The fracture was observed to propagate along the grain boundary by micro-pore nucleation and coalescence, giving an overall intergranular fracture behavior. Phase transformations from the Fluorite to the Rutile and Scrutinyite phases were identified at the propagating crack tips. These new phases are metastable and they transformed back to the Fluorite phase at the wake of crack tips as the local stress concentration was relieved by complete cracking. Such transient behavior observed at atomistic scale was found to substantially increase the energy release rate for fracture. Insertion of Xe gas into the initial notch showed minor effect on the overall fracture behavior.

Yongfeng Zhang; Paul C Millett; Michael R Tonks; Xian-Ming Bai; S Bulent Biner

2013-10-01T23:59:59.000Z

57

Interface control document between PUREX/UO{sub 3} Plant Transition and Solid Waste Disposal Division  

SciTech Connect (OSTI)

This interface control document (ICD) between PUREX/UO{sub 3} Plant Transition (PPT) and Solid Waste Disposal Division (SWD) establishes at a top level the functional responsibilities of each division where interfaces exist between the two divisions. Since the PUREX Transition and Solid Waste Disposal divisions operate autonomously, it is important that each division has a clear understanding of the other division`s expectations regarding these interfaces. This ICD primarily deals with solid wastes generated by the PPT. In addition to delineating functional responsibilities, the ICD includes a baseline description of those wastes that will require management as part of the interface between the divisions. The baseline description of wastes includes waste volumes and timing for use in planning the proper waste management capabilities: the primary purpose of this ICD is to ensure defensibility of expected waste stream volumes and Characteristics for future waste management facilities. Waste descriptions must be as complete as-possible to ensure adequate treatment, storage, and disposal capability will exist. The ICD also facilitates integration of existing or planned waste management capabilities of the PUREX. Transition and Solid Waste Disposal divisions. The ICD does not impact or affect the existing processes or procedures for shipping, packaging, or approval for shipping wastes by generators to the Solid Waste Division.

Duncan, D.R.

1994-06-30T23:59:59.000Z

58

Report of clean out and flushing of UO{sub 3} Plant processing equipment: Revision 1  

SciTech Connect (OSTI)

The UO{sub 3} Plant went through a clean out leading to the deactivation of the facility. This clean out consisted of three phases. Phase 1 consisted of the removal of residual process material and the deactivation of most process equipment and instrumentation. Phase 2 consisted of the fixing or removal of contamination so storm water processing would be no longer required. Phase 3 consisted of the remaining activities that had to be completed before the facility was turned over to the Surplus Facility Program. Since the activities of Phase 2 and 3 were closely related, these two phases were worked simultaneously. The first part of this document summarizes the Phase 1 clean out procedures and their results. Phase 1 was completed on February 28, 1994. The second part summarizes the Phase 2/3 clean out procedures and their results. Phase 2/3 was completed before December 31, 1994. Because tanks and equipment were flushed simultaneously or in a specific sequence, the clean out processes are discussed per workplan.

Gonsalves, E.

1994-12-02T23:59:59.000Z

59

Graphite and Beryllium Reflector Critical Assemblies of UO2 (Benchmark Experiments 2 and 3)  

SciTech Connect (OSTI)

INTRODUCTION A series of experiments was carried out in 1962-65 at the Oak Ridge National Laboratory Critical Experiments Facility (ORCEF) for use in space reactor research programs. A core containing 93.2 wt% enriched UO2 fuel rods was used in these experiments. The first part of the experimental series consisted of 252 tightly-packed fuel rods (1.27-cm triangular pitch) with graphite reflectors [1], the second part used 252 graphite-reflected fuel rods organized in a 1.506-cm triangular-pitch array [2], and the final part of the experimental series consisted of 253 beryllium-reflected fuel rods in a 1.506-cm-triangular-pitch configuration and in a 7-tube-cluster configuration [3]. Fission rate distribution and cadmium ratio measurements were taken for all three parts of the experimental series. Reactivity coefficient measurements were taken for various materials placed in the beryllium reflected core. All three experiments in the series have been evaluated for inclusion in the International Reactor Physics Experiment Evaluation Project (IRPhEP) [4] and the International Criticality Safety Benchmark Evaluation Project (ICSBEP) Handbooks, [5]. The evaluation of the first experiment in the series was discussed at the 2011 ANS Winter meeting [6]. The evaluations of the second and third experiments are discussed below. These experiments are of interest as benchmarks because they support the validation of compact reactor designs with similar characteristics to the design parameters for a space nuclear fission surface power systems [7].

Margaret A. Marshall; John D. Bess

2012-11-01T23:59:59.000Z

60

Leaching action of EJ-13 water on unirradiated UO{sub 2} surfaces under unsaturated conditions at 90{degree}C: Interim report  

SciTech Connect (OSTI)

A set of experiments, based on the application of the Unsaturated Test method to the reaction of UO{sub 2} with EJ-13 water, has been conducted over a period of 182.5 weeks. One half of the experiments have been terminated, while one half are still ongoing. Solutions that have dripped from UO{sub 2} specimens have been analyzed for all experiments, while the reacted UO{sub 2} surfaces have been examined for only the terminated experiments. A pulse of uranium release from the UO{sub 2} solid, in conjunction with the formation of dehydrated schoepite on the surface of the UO{sub 2}, was observed during the 39- to 96-week period. Thereafter, the uranium release decreased and a second set of secondary phases was observed. The latter phases incorporate cations from the EJ-13 water and include boltwoodite, uranophane, sklodowskite, compreignacite, and schoepite. The experiments are being continued to monitor for additional changes in solution composition and secondary phase formation, and have now reached the 319-week period. 9 refs., 17 figs., 25 tabs.

Wronkiewicz, D.J.; Bates, J.K.; Gerding, T.J.; Veleckis, E.; Tani, B.S.

1991-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "ms uo uo" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Vibrational Spectroscopy of Mass-Selected [UO2(ligand)n]2+ Complexes in the Gas Phase: Comparison with Theory  

SciTech Connect (OSTI)

The gas-phase infrared spectra of discrete uranyl ([UO2]2+) complexes ligated with acetone and/or acetonitrile were used to evaluate systematic trends of ligation on the position of the OdUdO stretch and to enable rigorous comparison with the results of computational studies. Ionic uranyl complexes isolated in a Fourier transform ion cyclotron resonance mass spectrometer were fragmented via infrared multiphoton dissociation using a free electron laser scanned over the mid-IR wavelengths. The asymmetric OdUdO stretching frequency was measured at 1017 cm-1 for [UO2(CH3COCH3)2]2+ and was systematically red shifted to 1000 and 988 cm-1 by the addition of a third and fourth acetone ligand, respectively, which was consistent with increased donation of electron density to the uranium center in complexes with higher coordination number. The values generated computationally using LDA, B3LYP, and ZORA-PW91 were in good agreement with experimental measurements. In contrast to the uranyl frequency shifts, the carbonyl frequencies of the acetone ligands were progressively blue shifted as the number of ligands increased from two to four and approached that of free acetone. This observation was consistent with the formation of weaker noncovalent bonds between uranium and the carbonyl oxygen as the extent of ligation increases. Similar trends were observed for [UO2(CH3CN)n]2+ complexes, although the uranyl asymmetric stretching frequencies were greater than those measured for acetone complexes having equivalent coordination, which is consistent with the fact that acetonitrile is a weaker nucleophile than is acetone. This conclusion was confirmed by the uranyl stretching frequencies measured for mixed acetone/acetonitrile complexes, which showed that substitution of one acetone for one acetonitrile produced a modest red shift of 3-6 cm-1.

Gary S. Groenewold; Anita K. Gianotto

2006-03-01T23:59:59.000Z

62

Vibrational Spectroscopy of Mass-Selected [UO?(ligand)n]˛? Complexes in the Gas Phase: Comparison with Theory  

SciTech Connect (OSTI)

The gas-phase infrared spectra of discrete uranyl ([UO?]˛?) complexes ligated with acetone and/or acetonitrile were used to evaluate systematic trends of ligation on the position of the O=U=O stretch, and to enable rigorous comparison with the results of computational studies. Ionic uranyl complexes isolated in a Fourier transform ion cyclotron resonance mass spectrometer were fragmented via infrared multiphoton dissociation using a free electron laser scanned over the mid-IR wavelengths. The asymmetric O=U=O stretching frequency was measured at 1017 cm?ą for [UO?(CH?COCH?)?]˛? and was systematically red shifted to 1000 and 988 cm?ą by the addition of a third and fourth acetone ligand, respectively, which was consistent with increased donation of electron density to the uranium center in complexes with higher coordination number. The values generated computationally using LDA, B3LYP, and ZORA-PW91 were in good agreement with experimental measurements. In contrast to the uranyl frequency shifts, the carbonyl frequencies of the acetone ligands were progressively blue shifted as the number of ligands increased from 2 to 4, and approached that of free acetone. This observation was consistent with the formation of weaker noncovalent bonds between uranium and the carbonyl oxygen as the extent of ligation increases. Similar trends were observed for [UO?(CH?CN)n]˛? complexes, although the magnitude of the red shift in the uranyl frequency upon addition of more acetonitrile ligands was smaller than for acetone, consistent with the more modest nucleophilic nature of acetonitrile. This conclusion was confirmed by the uranyl stretching frequencies measured for mixed acetone/acetonitrile complexes, which showed that substitution of one acetone for one acetonitrile produced a modest red shift of 3 to 6 cm?ą.

Groenewold, G. S.; Gianotto, Anita K.; Cossel, Kevin C.; Van Stipdonk, Michael J.; Moore, David T.; Polfer, Nick; Oomens, Jos; De Jong, Wibe A.; Visscher, Lucas

2006-03-18T23:59:59.000Z

63

Atomistic Calculations of the Effect of Minor Actinides on Thermodynamic and Kinetic Properties of UO{sub 2{+-}x}  

SciTech Connect (OSTI)

The team will examine how the incorporation of actinide species important for mixed oxide (MOX) and other advanced fuel designs impacts thermodynamic quantities of the host UO{sub 2} nuclear fuel and how Pu, Np, Cm and Am influence oxygen mobility. In many cases, the experimental data is either insufficient or missing. For example, in the case of pure NpO2, there is essentially no experimental data on the hyperstoichiometric form it is not even known if hyperstoichiometry NpO{sub 2{+-}x} is stable. The team will employ atomistic modeling tools to calculate these quantities

Deo, Chaitanya; Adnersson, Davis; Battaile, Corbett; uberuaga, Blas

2012-10-30T23:59:59.000Z

64

Production of Depleted UO2Kernels for the Advanced Gas-Cooled Reactor Program for Use in TRISO Coating Development  

SciTech Connect (OSTI)

The main objective of the Depleted UO{sub 2} Kernels Production Task at Oak Ridge National Laboratory (ORNL) was to conduct two small-scale production campaigns to produce 2 kg of UO{sub 2} kernels with diameters of 500 {+-} 20 {micro}m and 3.5 kg of UO{sub 2} kernels with diameters of 350 {+-} 10 {micro}m for the U.S. Department of Energy Advanced Fuel Cycle Initiative Program. The final acceptance requirements for the UO{sub 2} kernels are provided in the first section of this report. The kernels were prepared for use by the ORNL Metals and Ceramics Division in a development study to perfect the triisotropic (TRISO) coating process. It was important that the kernels be strong and near theoretical density, with excellent sphericity, minimal surface roughness, and no cracking. This report gives a detailed description of the production efforts and results as well as an in-depth description of the internal gelation process and its chemistry. It describes the laboratory-scale gel-forming apparatus, optimum broth formulation and operating conditions, preparation of the acid-deficient uranyl nitrate stock solution, the system used to provide uniform broth droplet formation and control, and the process of calcining and sintering UO{sub 3} {center_dot} 2H{sub 2}O microspheres to form dense UO{sub 2} kernels. The report also describes improvements and best past practices for uranium kernel formation via the internal gelation process, which utilizes hexamethylenetetramine and urea. Improvements were made in broth formulation and broth droplet formation and control that made it possible in many of the runs in the campaign to produce the desired 350 {+-} 10-{micro}m-diameter kernels, and to obtain very high yields.

Collins, J.L.

2004-12-02T23:59:59.000Z

65

Final Report: Manganese Redox Mediation of UO2 Stability and Uranium Fate in the Subsurface: Molecular and Meter Scale Dynamics  

SciTech Connect (OSTI)

One strategy to remediate U contamination in the subsurface is the immobilization of U via injection of an electron donor, e.g., acetate, which leads to stimulation of the bioreduction of U(VI), the more mobile form of U, to U(IV), the less mobile form. This process is inevitably accompanied by the sequential reductive dissolution of Mn and Fe oxides and often continuing into sulfate-reducing conditions. When these reducing zones, which accumulate U(IV), experience oxidizing conditions, reduced Fe and Mn can be reoxidized forming Fe and Mn oxides that, along with O2, can impact the stability of U(IV). The focus of our project has been to investigate (i) the effects of Mn(II) on the dissolution of UO2 under both reducing and oxidizing conditions, (ii) the oxidative dissolution of UO2 by soluble Mn(III), (iii) the fate of U once it is oxidized by MnO2 in both laboratory and field settings, and (iv) the effects of groundwater constituents on the coupled Mn(II)/U(IV) oxidation process. Additionally, studies of the interaction of Se, found at the DOE site at Rifle, CO, and Mn cycling were initiated to understand if observed seasonal fluctuations of Se and Mn are directly linked and whether any such linkages can affect the stability of U(IV).

Tebo, Bradley M. [OSHU; Tebo, Bradley M.

2014-09-02T23:59:59.000Z

66

Monte Carlo analysis of burnup-dependent plutonium concentration profiles in UO{sub 2} and MOX fuel pins  

SciTech Connect (OSTI)

The ability to accurately predict fuel performance is an essential requirement for fuel design studies. Prediction of plutonium concentration profiles in an irradiated fuel pin is important for fuel performance analysis and spent-fuel storage. The MCNP coupling with ORIGEN2 (MCWO) burnup calculation code as demonstrated in this paper can analyze the rim effect in UO{sub 2} and mixed-oxide (MOX) fuel pins. Acceptance of a code such as MCWO depends very strongly on its validation. Validation involves the benchmark of the code predictions to the in-pile experimental data and results of post-irradiation examinations (PIEs). In this paper, a validation was made by comparing the MCWO calculated results with the VIM-BURN code, which has been validated against PIE data. The validated MCWO can provide the best-estimate neutronic characteristics of fuel burnup performance analysis. In this paper, Pu concentration (wt%) and fission power profiles versus burnup of UO{sub 2} and reactor-grade (RG)-MOX fuel pins were calculated with MCWO, and results are discussed.

Chang, G.S. [Lockheed Martin Idaho Technologies, Idaho Falls, ID (United States). Idaho National Engineering and Environmental Lab.

1998-09-01T23:59:59.000Z

67

D10 experiment: coolability of UO/sub 2/ debris in sodium with downward heat removal. [LMFBR  

SciTech Connect (OSTI)

The LMFBR Debris Coolability Program at Sandia National Laboratories investigates the coolability of particle beds which may form following a severe accident involving core disassembly in a nuclear reactor. The D series experiments utilize fission heating of fully enriched UO/sub 2/ particles submerged in sodium to realistically simulate decay heating. The D10 experiment is the first in the series to study the effects of bottom cooling of the debris that could be provided in an actual accident condition by structural materials onto which the debris might settle. Additionally, the D10 experiment was designed to achieve maximum temperatures in the debris approaching the melting point of UO/sub 2/. The experiment was successfully operated for over 50 hours and investigated downward heat removal in a packed bed at specific powers of 0.16 to 0.58 W/g. Dryout in the debris was achieved at powers from 0.42 to 0.58 W/g. Channels were induced in the bed and channeled bed dryout was achieved at powers of 1.06 to 1.77 W/g. Maximum temperatures in excess of 2500/sup 0/C were attained.

Mitchell, G.W.; Ottinger, C.A.; Meister, H.

1984-12-01T23:59:59.000Z

68

Microstructure changes and thermal conductivity reduction in UO2 following 3.9 MeV He2+ ion irradiation  

SciTech Connect (OSTI)

The microstructural changes and associated effects on thermal conductivity were examined in UO2 after irradiation using 3.9 MeV He2+ ions. Lattice expansion of UO2 was observed in x-ray diffraction after ion irradiation up to 5×1016 He2+/cm2 at low-temperature (< 200 °C). Transmission electron microscopy (TEM) showed homogenous irradiation damage across an 8 µm thick plateau region, which consisted of small dislocation loops accompanied by dislocation segments. Dome-shaped blisters were observed at the peak damage region (depth around 8.5 µm) in the sample subjected to 5×1016 He2+/cm2, the highest fluence reached, while similar features were not detected at 9×1015 He2+/cm2. Laser-based thermo-reflectance measurements showed that the thermal conductivity for the irradiated layer decreased about 55 % for the high fluence sample and 35% for the low fluence sample as compared to an un-irradiated reference sample. Detailed analysis for the thermal conductivity indicated that the conductivity reduction was caused by the irradiation induced point defects.

Janne Pakrinen; Marat Khafizov; Lingfeng He; Chris Wetland; Jian Gan; Andrew T. Nelson; David H Hurley; Anter El-Azab; Todd R Allen

2014-11-01T23:59:59.000Z

69

Coolability of stratified UO/sub 2/ debris in sodium with downward heat removal: The D13 experiment  

SciTech Connect (OSTI)

The LMFBR Debris Coolability Program at Sandia National Laboratories investigates the coolability of particle beds that may form following a severe accident involving core disassembly in a nuclear reactor. The D series experiments utilize fission heating of fully enriched UO/sub 2/ particles submerged in sodium to realistically simulate decay heating. The D13 experiment is the first in the series to study the effects of bottom cooling of stratified debris, which could be provided in an actual accident condition by structural materials onto which the debris might settle. Additionally, the D13 experiment was designed to achieve maximum temperatures in the debris approaching the melting point of UO/sub 2/. The experiment was operated for over 40 hours and investigated downward heat removal at specific powers of 0.22 to 2.58 W/g. Channeled dryout in the debris was achieved at powers from 0.94 to 2.58 W/g. Maximum temperatures approaching 2700/sup 0/C were attained. Bottom heat removal was up to 750 kW/m/sup 2/ as compared to 450 kW/m/sup 2/ in the D10 experiment.

Ottinger, C.A.; Mitchell, G.W.; Reed, A.W.; Meister, H.

1987-03-01T23:59:59.000Z

70

Synthesis and structure of Cs[UO{sub 2}(SeO{sub 4})(OH)] . nH{sub 2}O (n = 1.5 or 1)  

SciTech Connect (OSTI)

The synthesis and single-crystal X-ray diffraction study of Cs[UO{sub 2}(SeO{sub 4})(OH)] . 1.5H{sub 2}O (I) and Cs[UO{sub 2}(SeO{sub 4})(OH)] . H{sub 2}O (II) are performed. Compound I crystallizes in the monoclinic crystal system, a = 7.2142(2) A, b = 14.4942(4) A, c = 8.9270(3) A, {beta} = 112.706(1){sup o}, space group P2{sub 1}/m, Z = 4, and R = 0.0222. Compound II is monoclinic, a = 8.4549(2) A, b = 11.5358(3) A, c = 9.5565(2) A, {beta} = 113.273(1){sup o}, space group P2{sub 1}/c, Z = 4, and R = 0.0219. The main structural units of crystals I and II are [UO{sub 2}(SeO{sub 4})(OH)]{sup -} layers which belong to the AT{sup 3}M{sup 2} crystal chemical group of uranyl complexes (A = UO{sub 2}{sup 2+}, T{sup 3} = SeO{sub 4}{sup 2-}, and M{sup 2} = OH{sup -}). In structure I, johannite-like layers are found. Structure II is a topological isomer of I. The two structures differ in the number of U(VI) atoms bound to the central atom by all bridging ligands.

Serezhkina, L. B., E-mail: lserezh@ssu.samara.ru [Samara State University (Russian Federation); Peresypkina, E. V.; Virovets, A. V. [Russian Academy of Sciences, Institute of Inorganic Chemistry, Siberian Branch (Russian Federation); Pushkin, D. V.; Verevkin, A. G. [Samara State University (Russian Federation)

2010-05-15T23:59:59.000Z

71

Possible Bose-condensated Behavior in a Quantum Phase Originating in a Collective Excitation in the Chemically and Optically Doped Mott-Hubbard System UO2+x  

SciTech Connect (OSTI)

The pinned charge defects in U4O9, and U3O7 that are the single phase fluoritestructured derivatives of UO2 have been characterized by U L3 EXAFS at 30, 100, and 200 K, xray and neutron pair distribution function analysis, O K edge XAS and non-resonant inelastic xray scattering, and Raman spectroscopy, while mobile charge defects were investigated by femtosecond time-resolved pump-probe laser spectroscopy on single crystal UO2 between 7 and 300 K. The results from all of these measurements show highly complex and anomalous behaviors, which we attribute to a charge-lattice instability in UO2 that most likely originates in the intersection of the ground U(IV) and a proximate uranyl-like excited state in a conic section, causing a breakdown of the Born-Oppenheimer approximation. Furthermore, the photoinduced quasiparticles undergo a gap-opening condensation between 50 and 60 K. Doped UO2 may therefore exhibit novel correlated electron physics that extends beyond that of the cuprate-manganite-pnictide family of compounds.

Conradson, Steven D.; Durakiewicz, Tomasz; Espinosa-Faller, Francisco J.; An, Yong Q.; Andersson , David; Bishop, Alan R.; Boland, Kevin S.; Bradley, Joseph A.; Byler, Darrin D.; Clark, David L.; Conradson, Dylan R.; Conradson, Leilani L.; Costello, Alison E.; Hess, Nancy J.; Lander, Gerard H.; Llobet, Anna; Martucci, Mary B.; de Leon, Jose M.; Nordlund, Dennis; Lezama-Pacheco, Juan S.; Proffen, Thomas E.; Rodriguez, George; Schwarz, Daniel E.; Seidler, Gerald T.; Taylor, Antoinette; Trugman, Stuart A.; Tyson, Trevor A.; Valdez, James A.

2013-09-23T23:59:59.000Z

72

UO Purchasing & Contracting Services rev: August 13, 2012 Text Requirements for Level 1 and Level 2 Signature Authority Purchase Orders and Invoices.  

E-Print Network [OSTI]

UO Purchasing & Contracting Services rev: August 13, 2012 Text Requirements for Level 1 and Level 2 the payment is due and payable (may be same person exercising L1SA)] · Either: 1. List contract # or purchase number); of 2. If you do not have a written contract or purchase order, generally describe what goods and

73

UO Purchasing & Contracting Services rev: August 19, 2014 Text Requirements for Level 1 and Level 2 Contracting Authority Purchase Orders and Invoices.  

E-Print Network [OSTI]

UO Purchasing & Contracting Services rev: August 19, 2014 Text Requirements for Level 1 and Level 2 Contracting Authority Purchase Orders and Invoices. Purchase Orders - Level 1 Contracting Authority: · L1CA [Insert on First Line of Document Text] · [name of individual exercising Level 1 Contracting Authority

74

UO Department of Chemistry -Faculty Research Interests Berglund, Andy -The primary goals of the Berglund lab are to understand the molecular basis of the human disease myotonic  

E-Print Network [OSTI]

applications in solar energy harvesting and electrochemical energy storage. Chartoff, Richard - The UO Polymer and thermodynamics of quantum states of molecules embedded in a quantum environment. Lonergan, Mark C. - Research interesting electrical and electrochemical phenomena in solid-state systems. Marcus, Andrew - The Marcus group

Cina, Jeff

75

UoE Employees How to gain access to internal vacancies As a current University employee, you will be eligible to access (via the jobs site) vacancies  

E-Print Network [OSTI]

UoE Employees ­ How to gain access to internal vacancies As a current University employee, you will be eligible to access (via the jobs site) vacancies advertised internally, in addition to those advertised gain access to all vacancies (including those advertised to internal applicants only) whenever you log

Edinburgh, University of

76

Possible effects of UO/sub 2/ oxidation on light water reactor spent fuel performance in long-term geologic disposal  

SciTech Connect (OSTI)

Disposal of spent nuclear fuel in a conventionally mined geologic formation is the nearest-term option for permanently isolating radionuclides from the biosphere. Because irradiated uranium dioxide (UO/sub 2/) fuel pellets retain 95 to 99% of the radionuclides generated during normal light water reactor operation, they may represent a significant barrier to radionuclide release. This document presents a technical assessment of published literature representing the current level of understanding of spent fuel characteristics and conditions that may degrade pellet integrity during a geologic disposal sequence. A significant deterioration mechanism is spent UO/sub 2/ oxidation with possible consequences identified as fission gas release, rod diameter increases, cladding breach extension, and release of solid fuel particles containing radionuclides. Areas requiring further study to support development of a comprehensive spent fuel performance prediction model are highlighted. A program and preliminary schedule to obtain the information needed to develop model correlations are also presented.

Almassy, M.Y.; Woodley, R.E.

1982-08-01T23:59:59.000Z

77

Oxidative corrosion of spent UO{sub 2} fuel in vapor and dripping groundwater at 90{degree}C.  

SciTech Connect (OSTI)

Corrosion of spent UO{sub 2} fuel has been studied in experiments conducted for nearly six years. Oxidative dissolution in vapor and dripping groundwater at 90 C occurs via general corrosion at fuel-fragment surfaces. Dissolution along fuel-grain boundaries is also evident in samples contacted by the largest volumes of groundwater, and corroded grain boundaries extend at least 20 or 30 grains deep (> 200 {micro}m), possibly throughout millimeter-sized fragments. Apparent dissolution of fuel along defects that intersect grain boundaries has created dissolution pits that are 50 to 200 nm in diameter. Dissolution pits penetrate 1-2 {micro}m into each grain, producing a ''worm-like'' texture along fuel-grain-boundaries. Sub-micrometer-sized fuel shards are common between fuel grains and may contribute to the reactive surface area of fuel exposed to groundwater. Outer surfaces of reacted fuel fragments develop a fine-grained layer of corrosion products adjacent to the fuel (5-15 {micro}m thick). A more coarsely crystalline layer of corrosion products commonly covers the fine-grained layer, the thickness of which varies considerably among samples (from less than 5 {micro}m to greater than 40 {micro}m). The thickest and most porous corrosion layers develop on fuel fragments exposed to the largest volumes of groundwater. Corrosion-layer compositions depend strongly on water flux, with uranyl oxy-hydroxides predominating in vapor experiments, and alkali and alkaline earth uranyl silicates predominating in high drip-rate experiments. Low drip-rate experiments exhibit a complex assemblage of corrosion products, including phases identified in vapor and high drip-rate experiments.

Finch, R. J.

1999-04-29T23:59:59.000Z

78

Measurements of the modified conversion ratio by gamma-ray spectrometry of fuel rods for water-moderated UO[sub 2] cores  

SciTech Connect (OSTI)

The modified conversion ratio is defined as the ratio of [sup 238]U captures to total fission. Gamma-ray spectrometry of irradiated fuel rods has been introduced to measure this quantity in two types of water-moderated low-enriched UO[sub 2] cores: the standard core, called the 1.42S core, and a tight-lattice core, called the 0.56S core. The water moderator-to-fuel volume ratios V[sub m]/V[sub [line integral

Nakajima, Ken; Akai, Masanori; Suzaki, Takenori (Japan Atomic Energy Research Inst., Ibaraki (Japan). Dept. of Fuel Cycle Safety Research)

1994-02-01T23:59:59.000Z

79

Dispersion of UO{sub 2}F{sub 2} aerosol and HF vapor in the operating floor during winter ventilation at the Paducah Gaseous Diffusion Plant  

SciTech Connect (OSTI)

The gaseous diffusion process is currently employed at two plants in the US: the Paducah Gaseous Diffusion Plant and the Portsmouth Gaseous Diffusion Plant. As part of a facility-wide safety evaluation, a postulated design basis accident involving large line-rupture induced releases of uranium hexafluoride (UF{sub 6}) into the process building of a gaseous diffusion plant (GDP) is evaluated. When UF{sub 6} is released into the atmosphere, it undergoes an exothermic chemical reaction with moisture (H{sub 2}O) in the air to form vaporized hydrogen fluoride (HF) and aerosolized uranyl fluoride (UO{sub 2}F{sub 2}). These reactants disperse in the process building and transport through the building ventilation system. The ventilation system draws outside air into the process building, distributes it evenly throughout the building, and discharges it to the atmosphere at an elevated temperature. Since air is recirculated from the cell floor area to the operating floor, issues concerning in-building worker safety and evacuation need to be addressed. Therefore, the objective of this study is to evaluate the transport of HF vapor and UO{sub 2}F{sub 2} aerosols throughout the operating floor area following B-line break accident in the cell floor area.

Kim, S.H.; Chen, N.C.J.; Taleyarkhan, R.P.; Keith, K.D.; Schmidt, R.W. [Oak Ridge National Lab., TN (United States); Carter, J.C. [J.C. Carter Associates, Inc., Knoxville, TN (United States)

1996-12-30T23:59:59.000Z

80

Criticality Safety Study of UF6and UO2F2in 8-in. Inner Diameter Piping  

SciTech Connect (OSTI)

The purpose of this report is to provide an evaluation of the criticality safety aspects of using up to 8-in.-inner-diameter (ID) piping as part of a system to monitor the {sup 235}U enrichment in uranium hexafluoride (UF{sub 6}) gas both before and after an enrichment down-blending operation. The evaluated operation does not include the blending stage but includes only the monitors and the piping directly associated with the monitors, which are in a separate room from the blending operation. There are active controls in place to limit the enrichment of the blended UF{sub 6} to a maximum of 5 weight percent (wt%) {sup 235}U. Under normal operating conditions of temperature and pressure, the UF{sub 6} will stay in the gas phase and criticality will not be credible. The two accidents of concern are solidification of the UF{sub 6} along with some hydrofluoric acid (HF) and water or moisture ingress, which would cause the UF{sub 6} gas to react and form a hydrated uranyl fluoride (UO{sub 2}F{sub 2}) solid or solution. Of these two types of accidents, the addition of water and formation of UO{sub 2}F{sub 2} is the most reactive scenario and thus limits related to UO{sub 2}F{sub 2} will bound the limits related to UF{sub 6}. Two types of systems are included in the monitoring process. The first measures the enrichment of the approximately 90 wt% enriched UF{sub 6} before it is blended. This system uses a maximum 4-in.-(10.16-cm-) ID pipe, which is smaller than the 13.7-cm-cylinder-diameter subcritical limit for UO{sub 2}F{sub 2} solution of any enrichment as given in Table 1 of American National Standard ANSI/ANS-8.1.1 Therefore, this system poses no criticality concerns for either accident scenario. The second type of system includes two enrichment monitors for lower-enriched UF{sub 6}. One monitors the approximately 1.5 wt% enriched UF{sub 6} entering the blending process, and the second monitors the approximately 5 wt% enriched UF{sub 6} coming out of the blending process. Both use a maximum 8-in.-(20.32-cm-) ID piping, where the length of the larger ID piping is approximately 9.5 m. This diameter of piping is below the 26.6-cm-cylinder-diameter subcritical limit for 5 wt% enriched UO{sub 2}F{sub 2} solutions as given in Table 6 of ANSI/ANS-8.1. Therefore, for up to 5 wt% enriched UF{sub 6}, this piping does not present a criticality concern for either accident scenario. Calculations were performed to determine the enrichment level at which criticality could become a concern in these 8-in.-ID piping sections. Both unreflected and fully water-reflected conditions were considered.

Elam, K.R.

2003-10-07T23:59:59.000Z

Note: This page contains sample records for the topic "ms uo uo" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

2. HIGH-LOv~ JUNCTION FORY_,\\'UO AN EXPERIMENTAL STUDY OF AL-ALLOYED:'p+ JUNCT;[ONS FOR SSF SOLAR CELT.S As temperature rises en..!."  

E-Print Network [OSTI]

. Luque formed. The deposited Al diss Instituto de Energia Solar {E.T,S,I.T,} phase composition given2. HIGH-LOv~ JUNCTION FORY_,\\'UO AN EXPERIMENTAL STUDY OF AL-ALLOYED:§'p+ JUNCT;[ONS FOR SSF SOLAR+pp+ bifacial SSF solar cells are used to experimentally analyse the interphase in a similar way a 5i layer

del Alamo, JesĂşs A.

82

High temperature redox reactions with uranium: Synthesis and characterization of Cs(UO{sub 2})Cl(SeO{sub 3}), Rb{sub 2}(UO{sub 2}){sub 3}O{sub 2}(SeO{sub 3}){sub 2}, and RbNa{sub 5}U{sub 2}(SO{sub 4}){sub 7}  

SciTech Connect (OSTI)

Cs(UO{sub 2})Cl(SeO{sub 3}) (1), Rb{sub 2}(UO{sub 2}){sub 3}O{sub 2}(SeO{sub 3}){sub 3} (2), and RbNa{sub 5}U{sub 2}(SO{sub 4}){sub 7} (3) single crystals were synthesized using CsCl, RbCl, and a CuCl/NaCl eutectic mixture as fluxes, respectively. Their lattice parameters and space groups are as follows: P2{sub 1}/n (a=6.548(1) Ĺ, b=11.052(2) Ĺ, c=10.666(2) Ĺ and ?=93.897(3)°), P1{sup Ż} (a=7.051(2) Ĺ, b=7.198(2) Ĺ, c=8.314(2) Ĺ, ?=107.897(3)°, ?=102.687(3)° and ?=100.564(3)°) and C2/c (a=17.862(4) Ĺ, b=6.931(1) Ĺ, c=20.133(4) Ĺ and ?=109.737(6)°. The small anionic building units found in these compounds are SeO{sub 3}{sup 2?} and SO{sub 4}{sup 2?} tetrahedra, oxide, and chloride. The crystal structure of the first compound is composed of [(UO{sub 2}){sub 2}Cl{sub 2}(SeO{sub 3}){sub 2}]{sup 2?} chains separated by Cs{sup +} cations. The structure of (2) is constructed from [(UO{sub 2}){sub 3}O{sub 11}]{sup 16?} chains further connected through selenite units into layers stacked perpendicularly to the [0 1 0] direction, with Rb{sup +} cations intercalating between them. The structure of compound (3) is made of uranyl sulfate layers formed by edge and vertex connections between dimeric [U{sub 2}O{sub 16}] and [SO{sub 4}] polyhedra. These layers contain unusual sulfate–metal connectivity as well as large voids. - Graphical abstract: A new family of uranyl selenites and sulfates has been prepared by high-temperature redox reactions. This compounds display new bonding motifs. Display Omitted - Highlights: • Low-dimensional Uranyl Oxoanion compounds. • Conversion of U(IV) to U(VI) at high temperatures. • Dimensional reduction by both halides and stereochemically active lone-pairs.

Babo, Jean-Marie [Department of Chemistry and Biochemistry, Florida State University, 95 Chieftan Way, Tallahassee, FL 32306-4390 (United States); Department of Civil and Environmental Engineering and Earth Sciences and Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, IN 46556 (United States); Albrecht-Schmitt, Thomas E., E-mail: talbrechtschmitt@gmail.com [Department of Chemistry and Biochemistry, Florida State University, 95 Chieftan Way, Tallahassee, FL 32306-4390 (United States)

2013-10-15T23:59:59.000Z

83

LWR fuel assembly designs for the transmutation of LWR Spent Fuel TRU with FCM and UO{sub 2}-ThO{sub 2} Fuels  

SciTech Connect (OSTI)

In this paper, transmutation of transuranic (TRU) nuclides from LWR spent fuels is studied by using LWR fuel assemblies which consist of UO{sub 2}-ThO{sub 2} fuel pins and FCM (Fully Ceramic Microencapsulated) fuel pins. TRU from LWR spent fuel is loaded in the kernels of the TRISO particle fuels of FCM fuel pins. In the FCM fuel pins, the TRISO particle fuels are distributed in SiC matrix having high thermal conductivity. The loading patterns of fuel pins and the fuel compositions are searched to have high transmutation rate and feasible neutronic parameters including pin power peaking, temperature reactivity coefficients, and cycle length. All studies are done only in fuel assembly calculation level. The results show that our fuel assembly designs have good transmutation performances without multi-recycling and without degradation of the safety-related neutronic parameters. (authors)

Bae, G.; Hong, S. G. [Department of Nuclear Engineering, KyungHee University, 1732 Deokyoungdaero, Giheung-gu, Yongin, Gyeonggi-do, 446-701 (Korea, Republic of)

2013-07-01T23:59:59.000Z

84

Safety Criticality Standards Using the French CRISTAL Code Package: Application to the AREVA NP UO{sub 2} Fuel Fabrication Plant  

SciTech Connect (OSTI)

Criticality safety evaluations implement requirements to proof of sufficient sub critical margins outside of the reactor environment for example in fuel fabrication plants. Basic criticality data (i.e., criticality standards) are used in the determination of sub critical margins for all processes involving plutonium or enriched uranium. There are several criticality international standards, e.g., ARH-600, which is one the US nuclear industry relies on. The French Nuclear Safety Authority (DGSNR and its advising body IRSN) has requested AREVA NP to review the criticality standards used for the evaluation of its Low Enriched Uranium fuel fabrication plants with CRISTAL V0, the recently updated French criticality evaluation package. Criticality safety is a concern for every phase of the fabrication process including UF{sub 6} cylinder storage, UF{sub 6}-UO{sub 2} conversion, powder storage, pelletizing, rod loading, assembly fabrication, and assembly transportation. Until 2003, the accepted criticality standards were based on the French CEA work performed in the late seventies with the APOLLO1 cell/assembly computer code. APOLLO1 is a spectral code, used for evaluating the basic characteristics of fuel assemblies for reactor physics applications, which has been enhanced to perform criticality safety calculations. Throughout the years, CRISTAL, starting with APOLLO1 and MORET 3 (a 3D Monte Carlo code), has been improved to account for the growth of its qualification database and for increasing user requirements. Today, CRISTAL V0 is an up-to-date computational tool incorporating a modern basic microscopic cross section set based on JEF2.2 and the comprehensive APOLLO2 and MORET 4 codes. APOLLO2 is well suited for criticality standards calculations as it includes a sophisticated self shielding approach, a P{sub ij} flux determination, and a 1D transport (S{sub n}) process. CRISTAL V0 is the result of more than five years of development work focusing on theoretical approaches and the implementation of user-friendly graphical interfaces. Due to its comprehensive physical simulation and thanks to its broad qualification database with more than a thousand benchmark/calculation comparisons, CRISTAL V0 provides outstanding and reliable accuracy for criticality evaluations for configurations covering the entire fuel cycle (i.e. from enrichment, pellet/assembly fabrication, transportation, to fuel reprocessing). After a brief description of the calculation scheme and the physics algorithms used in this code package, results for the various fissile media encountered in a UO{sub 2} fuel fabrication plant will be detailed and discussed. (authors)

Doucet, M.; Durant Terrasson, L.; Mouton, J. [AREVA-NP (France)

2006-07-01T23:59:59.000Z

85

Mesoscale Benchmark Demonstration Problem 1: Mesoscale Simulations of Intra-granular Fission Gas Bubbles in UO2 under Post-irradiation Thermal Annealing  

SciTech Connect (OSTI)

A study was conducted to evaluate the capabilities of different numerical methods used to represent microstructure behavior at the mesoscale for irradiated material using an idealized benchmark problem. The purpose of the mesoscale benchmark problem was to provide a common basis to assess several mesoscale methods with the objective of identifying the strengths and areas of improvement in the predictive modeling of microstructure evolution. In this work, mesoscale models (phase-field, Potts, and kinetic Monte Carlo) developed by PNNL, INL, SNL, and ORNL were used to calculate the evolution kinetics of intra-granular fission gas bubbles in UO2 fuel under post-irradiation thermal annealing conditions. The benchmark problem was constructed to include important microstructural evolution mechanisms on the kinetics of intra-granular fission gas bubble behavior such as the atomic diffusion of Xe atoms, U vacancies, and O vacancies, the effect of vacancy capture and emission from defects, and the elastic interaction of non-equilibrium gas bubbles. An idealized set of assumptions was imposed on the benchmark problem to simplify the mechanisms considered. The capability and numerical efficiency of different models are compared against selected experimental and simulation results. These comparisons find that the phase-field methods, by the nature of the free energy formulation, are able to represent a larger subset of the mechanisms influencing the intra-granular bubble growth and coarsening mechanisms in the idealized benchmark problem as compared to the Potts and kinetic Monte Carlo methods. It is recognized that the mesoscale benchmark problem as formulated does not specifically highlight the strengths of the discrete particle modeling used in the Potts and kinetic Monte Carlo methods. Future efforts are recommended to construct increasingly more complex mesoscale benchmark problems to further verify and validate the predictive capabilities of the mesoscale modeling methods used in this study.

Li, Yulan; Hu, Shenyang Y.; Montgomery, Robert; Gao, Fei; Sun, Xin; Tonks, Michael; Biner, Bullent; Millet, Paul; Tikare, Veena; Radhakrishnan, Balasubramaniam; Andersson , David

2012-04-11T23:59:59.000Z

86

Structural evolution of the double perovskites Sr{sub 2}B'UO{sub 6} (B' = Mn, Fe, Co, Ni, Zn) upon reduction: Magnetic behavior of the uranium cations  

SciTech Connect (OSTI)

Highlights: {yields} Evolution of the double perovskites Sr{sub 2}B'UO{sub 6} upon reduction were studied by XRPD. {yields} Orthorhombic (Pnma) disordered perovskites SrB'{sub 0.5-x}U{sub 0.5+x}O{sub 3} were obtained at 900 {sup o}C. {yields} U{sup 5+/4+} and Zn{sup 2+} cations are distributed at random over the octahedral positions. {yields} AFM ordering for the perovskite with B' = Zn appears below 30 K. -- Abstract: We describe the preparation of five perovskite oxides obtained upon reduction of Sr{sub 2}B'UO{sub 6} (B' = Mn, Fe, Co, Ni, Zn) with H{sub 2}/N{sub 2} (5%/95%) at 900 {sup o}C during 8 h, and their structural characterization by X-ray powder diffraction (XRPD). During the reduction process there is a partial segregation of the elemental metal when B' = Co, Ni, Fe, and the corresponding B'O oxide when B' = Mn, Zn. Whereas the parent, oxygen stoichiometric double perovskites Sr{sub 2}B'UO{sub 6} are long-range ordered concerning B' and U cations. The crystal structures of the reduced phases, SrB'{sub 0.5-x}U{sub 0.5+x}O{sub 3} with 0.37 < x < 0.27, correspond to simple, disordered perovskites; they are orthorhombic, space group Pnma (No. 62), with a full cationic disorder at the B site. Magnetic measurements performed on the phase with B' = Zn, indicate uncompensated antiferromagnetic ordering of the U{sup 5+}/U{sup 4+} sublattice below 30 K.

Pinacca, R.M., E-mail: rmp@unsl.edu.ar [Area de Quimica General e Inorganica 'Dr. Gabino F. Puelles', Departamento de Quimica, Facultad de Quimica, Bioquimica y Farmacia, Universidad Nacional de San Luis, Chacabuco y Pedernera, 5700 San Luis (Argentina); Viola, M.C.; Pedregosa, J.C. [Area de Quimica General e Inorganica 'Dr. Gabino F. Puelles', Departamento de Quimica, Facultad de Quimica, Bioquimica y Farmacia, Universidad Nacional de San Luis, Chacabuco y Pedernera, 5700 San Luis (Argentina)] [Area de Quimica General e Inorganica 'Dr. Gabino F. Puelles', Departamento de Quimica, Facultad de Quimica, Bioquimica y Farmacia, Universidad Nacional de San Luis, Chacabuco y Pedernera, 5700 San Luis (Argentina); Carbonio, R.E. [INFIQC (CONICET), Departamento de Fisicoquimica, Facultad de Ciencias Quimicas, Universidad Nacional de Cordoba, Ciudad Universitaria, X5000HUA Cordoba (Argentina)] [INFIQC (CONICET), Departamento de Fisicoquimica, Facultad de Ciencias Quimicas, Universidad Nacional de Cordoba, Ciudad Universitaria, X5000HUA Cordoba (Argentina); Lope, M.J. Martinez; Alonso, J.A. [Instituto de Ciencia de Materiales de Madrid, C.S.I.C., Cantoblanco, 28049 Madrid (Spain)] [Instituto de Ciencia de Materiales de Madrid, C.S.I.C., Cantoblanco, 28049 Madrid (Spain)

2011-11-15T23:59:59.000Z

87

Synthesis and X-ray structural investigation of K{sub 8}[(UO{sub 2}){sub 2}(C{sub 2}O{sub 4}){sub 2}(SeO{sub 4}){sub 4}] . 2H{sub 2}O  

SciTech Connect (OSTI)

Single crystals of the compound K{sub 8}[(UO{sub 2}){sub 2}(C{sub 2}O{sub 4}){sub 2}(SeO{sub 4})4] . 2H{sub 2}O (I) are synthesized, and their structure is investigated using X-ray diffraction. Compound I crystallizes in the monoclinic system with the unit cell parameters a = 14.9290(4) A, b = 7.2800(2) A, c = 15.3165(4) A, {beta} = 109.188(1){sup o}, V = 1572.17(7) A{sup 3}, space group P2{sub 1}/n, Z = 2, and R = 0.0297. The uranium-containing structural units of crystals I are dimers of the composition [(UO {sub 2}){sub 2}(C{sub 2}O{sub 4}){sub 2}(SeO{sub 4}){sub 4}]{sup 8-}, which belong to the crystal-chemical group AB{sup 01}B{sup 2}M{sup 1} (A = UO{sub 2}{sup 2+}, B{sup 01} = C{sub 2}O{sub 4}{sup 2-}, B{sup 2} = SeO{sub 4}{sup 2-}, M{sup 1} = SeO{sub 4}{sup 2-}) of the uranyl complexes. The [(UO{sub 2}){sub 2}(C{sub 2}O{sub 4}){sub 2}(SeO{sub 4}){sub 4}]{sup 8-} dimers are joined into a three-dimensional framework through electrostatic interactions with the outer-sphere potassium cations.

Serezhkina, L. B., E-mail: lserezh@ssu.samara.ru [Samara State University (Russian Federation); Peresypkina, E. V.; Virovets, A. V. [Russian Academy of Sciences, Nikolaev Institute of Inorganic Chemistry, Siberian Branch (Russian Federation); Verevkin, A. G.; Pushkin, D. V. [Samara State University (Russian Federation)

2009-01-15T23:59:59.000Z

88

Pipe diffusion at dislocations in UO2  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the1 - September 2006Photovoltaic Theory and ModelingPink Skies Coming ToFUEL.P8.01 Pipe

89

UO Annual Report 2011 Page 1 2011 Annual Report  

E-Print Network [OSTI]

. CONDITIONS NOT MET Student Performance Criteria SPC 9: Non-Western Traditions progress to ensure that we are meeting 2009 SPC A. 9. Historical Traditions and Global Culture. SPC 13: Human Diversity The visiting team report states

90

Oxidative Dissolution of UO2 in a Simulated Groundwater Containing...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Groundwater Containing Synthetic Nanocrystalline Mackinawite. Abstract: The long-term success of in situ reductive immobilization of uranium (U) depends on the stability of...

91

Modeling of UO{sub 2} oxidation in steam atmosphere  

SciTech Connect (OSTI)

Nuclear fuel oxidation is an important phenomenon affecting fission product behavior. As indicated by a number of studies, uranium dioxide shows a very wide range of nonstoichiometric states. In steam, fuel oxidation produces a hyperstoichiometric composition, changing the transport properties. Variation of stoichiometry changes diffusion coefficients for oxygen, noble gases, and fission products substantially, affecting the release of fission products.

Dobrov, B.V.; Likhanskii, V.V. [Triniti Research Center, Triniti, Moscow (Russian Federation); Ozrin, V.D. [Nuclear Safety Institute IBREA, Moscow (Russian Federation)] [and others

1997-12-01T23:59:59.000Z

92

Oxidative Dissolution of UO2 in a Simulated Groundwater Containing  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the1 - September 2006 The 2002Optics GroupPlanning Workshop OverviewOxidationSynthetic

93

IWW's strategic plan at maturity was to be considered a technical resource by state and federal agencies. IWW was strategically positioned to  

E-Print Network [OSTI]

micro-hydro research through OSU Foundation to fund first joint UO JD/ OSU MS water student. #12;Metric

Escher, Christine

94

, 227 240 . Half-life Radioactive decay Reaction with 2200 m/s neutrons  

E-Print Network [OSTI]

. 700-800 U2N3 UN2 . 1.2.5. 1.5 . , . UF4 UF6 UO2 HF . UO3 + 4HF Boils at 1 atm UF6 Black ~1427 8.95 UF4 Green 1036 1457 6.70 U4F17 Black 430 Disp. 6.94 U2F9 390 Disp. 7.06 UF5 White 348 Disp. 6.45 UF6 Colorless 64.05 56.54 5.06 UCl3 Olive green 837 1657 5.51 UCl4 Dark

Hong, Deog Ki

95

Recovery of UO{sub 2}/PuO{sub 2} in IFR electrorefining process  

DOE Patents [OSTI]

This invention is comprised of a process for converting PuO{sub 2} and U0{sub 2} present in an electrorefiner to the chlorides, by contacting the PuO{sub 2} and U0{sub 2} with Li metal in the presence of an alkali metal chloride salt substantially free of rare earth and actinide chlorides for a time and at a temperature sufficient to convert the U0{sub 2} and PuO{sub 2} to metals while converting Li metal to Li{sub 2}O. Li{sub 2}O is removed either by reducing with rare earth metals or by providing an oxygen electrode for transporting 0{sub 2} out of the electrorefiner and a cathode, and thereafter applying an emf to the electrorefiner electrodes sufficient to cause the Li{sub 2}O to disassociate to 0{sub 2} and Li metal but insufficient to decompose the alkali metal chloride salt. The U and Pu and excess lithium are then converted to chlorides by reaction with CdCl{sub 2}.

Tomczuk, Z.; Miller, W.E.

1992-01-01T23:59:59.000Z

96

Lattice anisotropy, electronic and chemical structures of uranyl carbonate, UO2CO3, from  

E-Print Network [OSTI]

-sur-Yvette (Seine-et- Oise). (2) Quelques tentatives pour obtenir le spectre de l'ura- nium par décharge dans UF 6 n

Boyer, Edmond

97

Lattice thermal conductivity of UO{sub 2} using ab-initio and classical molecular dynamics  

SciTech Connect (OSTI)

We applied the non-equilibrium ab-initio molecular dynamics and predict the lattice thermal conductivity of the pristine uranium dioxide for up to 2000?K. We also use the equilibrium classical molecular dynamics and heat-current autocorrelation decay theory to decompose the lattice thermal conductivity into acoustic and optical components. The predicted optical phonon transport is temperature independent and small, while the acoustic component follows the Slack relation and is in good agreement with the limited single-crystal experimental results. Considering the phonon grain-boundary and pore scatterings, the effective lattice thermal conductivity is reduced, and we show it is in general agreement with the sintered-powder experimental results. The charge and photon thermal conductivities are also addressed, and we find small roles for electron, surface polaron, and photon in the defect-free structures and for temperatures below 1500?K.

Kim, Hyoungchul [Department of Mechanical Engineering, University of Michigan, Ann Arbor, Michigan 48109 (United States); High-Temperature Energy Materials Research Center, Korea Institute of Science and Technology, Seoul 136–791 (Korea, Republic of); Kim, Moo Hwan [Division of Advanced Nuclear Engineering, Pohang University of Science and Technology, Pohang 790-784 (Korea, Republic of); Kaviany, Massoud, E-mail: kaviany@umich.edu [Department of Mechanical Engineering, University of Michigan, Ann Arbor, Michigan 48109 (United States); Division of Advanced Nuclear Engineering, Pohang University of Science and Technology, Pohang 790-784 (Korea, Republic of)

2014-03-28T23:59:59.000Z

98

A brief history of the PUREX and UO{sub 3} facilities  

SciTech Connect (OSTI)

The Plutonium-Uranium Extraction (PUREX) Plant, conceived during the early Cold War years, was a vehicle to increase significantly US nuclear weapons production capacity. The original PUREX Plant was a concrete rectangle 1,005 feet long and 61.5 feet wide. The shielding capacity of the concrete was designed so that personnel in non-regulated service areas would not receive radiation in excess of 0.1 millirem per hour. This report discusses the design of the PUREX Plant, the production chronology, projects and equipment changes, equipment decontamination and reuse, waste management, and contamination events that have occurred during the operation of the plant. Additionally, the development and history of the Uranium Trioxide Plant are also covered.

Gerber, M.S.

1993-11-01T23:59:59.000Z

99

Dissolution of Irradiated Commercial UO2 Fuels in Ammonium Carbonate and Hydrogen Peroxide  

SciTech Connect (OSTI)

We propose and test a disposition path for irradiated nuclear fuel using ammonium carbonate and hydrogen peroxide media. We demonstrate on a 13 g scale that >98% of the irradiated fuel dissolves. Subsequent expulsion of carbonate from the dissolver solution precipitates >95% of the plutonium, americium, curium, and substantial amounts of fission products, effectively partitioning the fuel at the dissolution step. Uranium can be easily recovered from solution by any of several means, such as ion exchange, solvent extraction, or direct precipitation. Ammonium carbonate can be evaporated from solution and recovered for re-use, leaving an extremely compact volume of fission products, transactinides, and uranium. Stack emissions are predicted to be less toxic, less radioactive, chemically simpler, and simpler to treat than those from the conventional PUREX process.

Soderquist, Chuck Z.; Johnsen, Amanda M.; McNamara, Bruce K.; Hanson, Brady D.; Chenault, Jeffrey W.; Carson, Katharine J.; Peper, Shane M.

2011-01-18T23:59:59.000Z

100

(04) UO05 MFA (Creative Writing)/11 Master of Fine Arts (Creative Writing)  

E-Print Network [OSTI]

the currently proposed degree, the practical experience of conceiving, sustaining and completing a significant) will be expected to have completed papers at each level or, in the case of external or overseas applicants of the origins and management of creative processes, awareness of generic literary forms and traditions

Hickman, Mark

Note: This page contains sample records for the topic "ms uo uo" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Cation-Cation Interactions in [(UO2)2(OH)n](4-n) Complexes. | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation Proposed New Substation Sites ProposedOccupational Healthcatalysts . |withzeolite:

102

Ligand field effects on the multiplet structure of the U4f XPS of UO2. |  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: VegetationEquipment Surfaces and Interfaces Sample6, 2011 LawrenceEfeedstocks and the climateLife

103

Ab initio DFT+U Study of He Atom Incorporation into UO2 Crystals. | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc Documentation RUCProductstwrmrAre the Effects of GlobalASCR UserProgramICarbide.Ar-CF. Ab

104

First-principles study of defects and phase transition in UO2. | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsing ZirconiaPolicyFeasibilityField OfficeFirmFirsthexagonal 2H-MoS2. |

105

Excited States and Luminescent Properties of UO2F2 and Its Solvated  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsing ZirconiaPolicy and Assistance100 tonusingdeposition. |

106

A QM/MM Study on the Aqueous Solvation of theTetrahydroxouranylate [UO(OH)]  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinanInformation Desert SouthwestTechnologies |November 2011A First LookMicroscopyComplex Ion. | EMSL QM/MM

107

A DualDisk File System: ext4 Mihai Budiu  

E-Print Network [OSTI]

uranium oxide, UO2 [8,4] and hexavalent uranium based fluorides, UF6 [5], oxides, CaUO4 [9] and CdUO4 [10

Budiu, Mihai

108

MS Detectors  

SciTech Connect (OSTI)

Good eyesight is often taken for granted, a situation that everyone appreciates once vision begins to fade with age. New eyeglasses or contact lenses are traditional ways to improve vision, but recent new technology, i.e. LASIK laser eye surgery, provides a new and exciting means for marked vision restoration and improvement. In mass spectrometry, detectors are the 'eyes' of the MS instrument. These 'eyes' have also been taken for granted. New detectors and new technologies are likewise needed to correct, improve, and extend ion detection and hence, our 'chemical vision'. The purpose of this report is to review and assess current MS detector technology and to provide a glimpse towards future detector technologies. It is hoped that the report will also serve to motivate interest, prompt ideas, and inspire new visions for ion detection research.

Koppenaal, David W.; Barinaga, Charles J.; Denton, M Bonner B.; Sperline, Roger P.; Hieftje, Gary M.; Schilling, G. D.; Andrade, Francisco J.; Barnes IV., James H.

2005-11-01T23:59:59.000Z

109

A Study of UO2 Grain Boundary Structure and Thermal Resistance Change under Irradiation using Molecular Dynamics Simulations  

E-Print Network [OSTI]

annealed at different temperatures to study the mechanism and kinetic of intermetallic phase formation [19]. One important fission product that impacts FCCI is lanthanide, which influences the interdiffusion process. Researchers have found that FCCI... is determined by the particular fuel/cladding combination and temperature before lanthanide accumulated at the interface; but dominated by the presence of lanthanides after there is enough of them. And the accumulation of lanthanide at the interphase...

Chen, Tianyi

2013-08-02T23:59:59.000Z

110

E&nr Ph. S. W.. Wahhgt~n. D.C. 200242174, TIkpbnc (202) 48a60uo  

Office of Legacy Management (LM)

Institute Rockefeller Institute'for Medical Research University of Rochester Case School of Applied Science, Ohio State University University of Cincinnati University of...

111

Forest transitions and ecosystem services in Zimbabwe Supervisors: Dr Casey Ryan (UoE), Dr Isla Grundy (University of Zimbabwe)  

E-Print Network [OSTI]

, in combination with rising demand for wood fuel and charcoal in the face of increasing energy costs

112

THE ELECTRON AFFINITY OF UO E.B. Rudnyi, E.A. Kaibicheva, L.N. Sidorov  

E-Print Network [OSTI]

;equilibria. A platinum effusion chamber (12 mm x 12 mm) was used with (0.5 to 1.2 mm) effusion orifice. The temperature was measured with a Pt-Pt/Rh (10 %) thermocouple, the accuracy being +4 K. Ionic currents were

Rudnyi, Evgenii B.

113

E&nr Ph. S. W.. Wahhgt~n. D.C. 200242174, TIkpbnc (202) 48a60uo  

Office of Legacy Management (LM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarlyEnergyDepartment ofDepartment ofof EnergyYou areDowntownRockyDeparttient,ofREQUEST FOR75' 00.955

114

Y H-S I-H HATIOHAL LEAth~~Y~~OF' OtUO ' Industrial Hygiene No.  

Office of Legacy Management (LM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarlyEnergyDepartment ofDepartment ofof EnergyYou$0.C. 20545 OCTTO:March 20,Since 5% "y$ --

115

Issues in the use of Weapons-Grade MOX Fuel in VVER-1000 Nuclear Reactors: Comparison of UO2 and MOX Fuels  

SciTech Connect (OSTI)

The purpose of this report is to quantify the differences between mixed oxide (MOX) and low-enriched uranium (LEU) fuels and to assess in reasonable detail the potential impacts of MOX fuel use in VVER-1000 nuclear power plants in Russia. This report is a generic tool to assist in the identification of plant modifications that may be required to accommodate receiving, storing, handling, irradiating, and disposing of MOX fuel in VVER-1000 reactors. The report is based on information from work performed by Russian and U.S. institutions. The report quantifies each issue, and the differences between LEU and MOX fuels are described as accurately as possible, given the current sources of data.

Carbajo, J.J.

2005-05-27T23:59:59.000Z

116

UO Department of Chemistry & Biochemistry -Faculty Research Interests Berglund, Andy -The primary goals of the Berglund lab are to understand the molecular basis of the human disease myotonic  

E-Print Network [OSTI]

that have applications in solar energy harvesting and electrochemical energy storage Cina, Jeffrey A research and materials science. Lonergan, Mark C. - Research in the Lonergan group blends synthesis and electrochemical phenomena in solid-state systems Marcus, Andrew - The Marcus group studies the structure

Cina, Jeff

117

Raman Investigation of The Uranium Compounds U3O8, UF4, UH3 and UO3 under Pressure at Room Temperature  

SciTech Connect (OSTI)

Our current state-of-the-art X-ray diffraction experiments are primarily sensitive to the position of the uranium atom. While the uranium - low-Z element bond (such as U-H or U-F) changes under pressure and temperature the X-ray diffraction investigations do not reveal information about the bonding or the stoichiometry. Questions that can be answered by Raman spectroscopy are (i) whether the bonding strength changes under pressure, as observed by either blue- or red-shifted peaks of the Raman active bands in the spectrum and (ii) whether the low-Z element will eventually be liberated and leave the host lattice, i.e. do the fluorine, oxygen, or hydrogen atoms form dimers after breaking the bond to the uranium atom. Therefore Raman spectra were also collected in the range where those decomposition products would appear. Raman is particularly well suited to these types of investigations due to its sensitivity to trace amounts of materials. One challenge for Raman investigations of the uranium compounds is that they are opaque to visible light. They absorb the incoming radiation and quickly heat up to the point of decomposition. This has been dealt with in the past by keeping the incoming laser power to very low levels on the tens of milliWatt range consequently affecting signal to noise. Recent modern investigations also used very small laser spot sizes (micrometer range) but ran again into the problem of heating and chemical sensitivity to the environment. In the studies presented here (in contrast to all other studies that were performed at ambient conditions only) we employ micro-Raman spectroscopy of samples situated in a diamond anvil cell. This increases the trustworthiness of the obtained data in several key-aspects: (a) We surrounded the samples in the DAC with neon as a pressure transmitting medium, a noble gas that is absolutely chemically inert. (b) Through the medium the sample is thermally heat sunk to the diamond anvils, diamond of course possessing the very best heat conductivity of any material. Therefore local heating and decomposition are avoided, a big challenge with other approaches casting doubts on their results. (c) This in turn benefits the signal/noise ratio tremendously since the Raman features of uranium-compounds are very small. The placement of the samples in DACs allows for higher laser powers to impinge on the sample spot while keeping the spot-size larger than in previous studies and keep the samples from heating up. Raman spectroscopy is a very sensitive non-invasive technique and we will show that it is even possible to distinguish the materials by their origin / manufacturer as we have studied samples from Cameco (Canada) and IBI-Labs (US-Florida) and can compare with ambient literature data for samples from Strem (US-MA) and Areva (Pierrelatte, France).

Lipp, M J; Jenei, Z; Park-Klepeis, J; Evans, W J

2011-12-15T23:59:59.000Z

118

Hello "Rhythms and Rhymes" FIG student! My name is Brandon Parry and I will be your FIG Assistant this fall at the UO. When fall  

E-Print Network [OSTI]

Hello "Rhythms and Rhymes" FIG student! My name is Brandon Parry and I will be your FIG Assistant, and I wanted to give Professor Kendall the chance to tell you a little more about himself: Hello. I

Oregon, University of

119

Biosciences Undergraduate Research at Nottingham School of Biosciences, UoN, 2009. 1 Assessing the link between forest composition and soil nutrient  

E-Print Network [OSTI]

threat of global climate change, concern is growing about the consequence of large scale biodiversity exudates or changes in growth, increasing litter input or nutrient uptake. Nutrient cycling and the plant and therefore more efficient nutrient cycling. The Kamchatka peninsula in Far East Russia makes up the northern

Nottingham, University of

120

LA-23336-MS  

Office of Scientific and Technical Information (OSTI)

3336-MS UC-700 and UC-704 Issued: November 1997 Potential Containment Materials for Liquid-Lead and Lead-Bismuth Eutectic Spallation Neutron Source John J. Park Darryl P. Butt Carl...

Note: This page contains sample records for the topic "ms uo uo" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Ms. Maria Galanti  

Broader source: Energy.gov (indexed) [DOE]

Office 2195 Front Street Logan, Ohio 43138 Dear Ms. Galanti: PPPO-03-1158259-11 CONSTRUCTION COMPLETION REPORT FOR REMOVAL OF THE X-533 SWITCHYARD COMPLEX AT THE PORTSMOUTH...

122

(front end fuel cycle) 2.1 (CANDU  

E-Print Network [OSTI]

, , Phosphorus . 2.2. (U3O8) . U235 . UO2 ( ) UF6 ( ) . 2235 U235 UF6 . 2.2.2. UF6 UO2 UF6 UO2 UF4 UF4 UF6 . (1) : (4) : UF4 UF6 . UF4 1600 500 . UF4 UF4 UO2 . UF6 , , 150

Hong, Deog Ki

123

Prof Dr Mr Mrs Ms Prof Dr Mr Mrs Ms  

E-Print Network [OSTI]

Prof Dr Mr Mrs Ms Prof Dr Mr Mrs Ms Standard Room Request Payment Card No Expiry Date Contact or a 1-night applicable room charge will be levied as cancellation charge. * Daily rate will be subject

Xu, Jianliang

124

LA-11224-MS  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFunInfraredJeffersonJonathanMultimaterial2 J.N. Shadid,a SANDIAL> -i1224-MS

125

LA-23336-MS  

Office of Scientific and Technical Information (OSTI)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinan antagonist Journal Article: Crystal structureComposite--FORRemarksHEATINGI _ _++,J ' "2713336-MS

126

Ms. Maria Galanti  

Broader source: Energy.gov (indexed) [DOE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarly Careerlumens_placard-green.eps MoreWSRC-STI-2007-00250 Rev.Tech Brief answers: Why9, 20145, 2013 Ms.HAR

127

M.S. Physics Program M.S. in Physics  

E-Print Network [OSTI]

M.S. Physics Program M.S. in Physics Department(s) Physics and Astronomy College Sciences 1 for later reference. 1. understanding of a variety of fields of physics at the graduate level 2. performance of a physics research project suitable for a masters thesis 3. ability to communicate scientific research

Hemmers, Oliver

128

M.S. Astronomy Program M.S. in Astronomy  

E-Print Network [OSTI]

M.S. Astronomy Program M.S. in Astronomy Department(s) Physics and Astronomy College Sciences 1 for later reference. 1. understanding of a variety of fields of physics and astronomy at the graduate level 2*. performance of an astronomy research project suitable for a masters thesis 3*. ability

Hemmers, Oliver

129

METLIN: MS/MS metabolite data from the MAGGIE Project  

DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

METLIN is a metabolite database for metabolomics containing over 50,000 structures, it also represents a data management system designed to assist in a broad array of metabolite research and metabolite identification by providing public access to its repository of current and comprehensive MS/MS metabolite data. An annotated list of known metabolites and their mass, chemical formula, and structure are available on the METLIN website. Each metabolite is conveniently linked to outside resources such as the the Kyoto Encyclopedia of Genes and Genomes (KEGG) for further reference and inquiry. MS/MS data is also available on many of the metabolites. The list is expanding continuously as more metabolite information is being deposited and discovered. [from http://metlin.scripps.edu/] Metlin is a component of the MAGGIE Project. MAGGIE is funded by the DOE Genomics: GTL and is an acronym for "Molecular Assemblies, Genes, and Genomics Integrated Efficiently."

130

An economic study of the peanut industry  

E-Print Network [OSTI]

?CBCDPECYCOOW PEC rcPO UDC DCsyfrMkCn mS PEC PDUnC UO DCUnS lyD nMOayOUYe NECS UDC DClCDDCn Py UO ilUDHCDOu OPysp aCUrcPOie NEC fCrCDUY aDUsPMsC MO Py OUsp PEC aCUrcPO Mr yrC EcrnDCn aycrn mUfO Urn EUcY PECH Py HUDpCP yD Py U hUDCEycOCe NEC EUS MO mUYCn UO... MP MO PEDCOECn Urn CMPECD OPyDCn yr PEC lUDH yD HUDpCPCne vP EUO U EMfE lCCn BUYcC lyD YMBCOPysp UO lynnCD yD fDycrn UO Ur MrfDCnMCrP lyD HMJCn lCCnO Urn PEC syHHCDsMUY aCYYCP PSaC yl lCCne bUmyD NEC YUmyD DC,cMDCHCrPO Mr PEC yaCDUPMyr Mrs...

Wilkins, Charlie Smith

2013-10-04T23:59:59.000Z

131

ICP-MS (Quadrupole) | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-SeriesFlickr FlickrGuidedCH2MLLCBasics HydropowerI/OICP-MS (Quadrupole) ICP-MS

132

Sodium meta-autunite colloids: Synthesis, characterization, stability  

E-Print Network [OSTI]

J.T.Baker) and crystalline uranyl nitrate, UO 2 (NO 3 ) 2 .by: mixing 0.5 mM uranyl nitrate, UO 2 (NO 3 ) 2 .6H 2 O,

Zheng, Zuoping; Wan, Jiamin; Tokunaga, Tetsu K.

2004-01-01T23:59:59.000Z

133

The Influence of the Linker Geometry in Bis(3-hydroxy-N-methyl-pyridin-2-one) Ligands on Solution-Phase Uranyl Affinity  

E-Print Network [OSTI]

M. S. Murali, K. L. Nash, Solv. Extr. Ion Exch. 2001, 19,dimers of the form [UO 2 L 2 (solv. )] 2 as opposed to thesterically-induced [UO 2 (L)(solv. )] 2 dimer formation, [

Szigethy, Géza

2011-01-01T23:59:59.000Z

134

Clustering of protein families into functional subtypes using Relative Complexity Measure with reduced  

E-Print Network [OSTI]

@su.sabanciuniv.edu HHO: hotu@bidmc.harvard.edu UOS: ugur@sabanciuniv.edu #12;- 2 - Abstract Background Phylogenetic

Yanikoglu, Berrin

135

MODELING THE PERFORMANCE OF HIGH BURNUP THORIA AND URANIA PWR FUEL  

E-Print Network [OSTI]

Fuel performance models have been developed to assess the performance of ThO[subscript 2]-UO[subscript 2]

Long, Y.

136

Winter 2012 Prof. Carol Silverman Office: 321 Condon Off. hrs. M 4-5, W 12-1:00 PM  

E-Print Network [OSTI]

in the UO Bookstore are: Sacco, Joe. Safe Area Gorazde: The War in Eastern Bosnia 1992-95. Fantagraphics

137

SUPPLEMENTARY MATERIALS MS-EPS APPLICANT INFORMATION  

E-Print Network [OSTI]

SUPPLEMENTARY MATERIALS MS-EPS APPLICANT INFORMATION PERSONAL INFORMATION (please type or print application requirements, applicants to the Master of Science in Environmental Policy Studies (MS-EPS) program applicants must submit a Personal Statement that outlines how the MS-EPS program will meet a candidate

Bieber, Michael

138

The Influence of Linker Geometry on Uranyl Complexation by Rigidly-Linked Bis(3-hydroxy-N-methyl-pyridin-2-one)  

E-Print Network [OSTI]

to the formation of UO 2 L(solv. ) complexes (where L is theUO 2 (bis-Me-3,2-HOPO)(solv. ) (right), tabulated in Tablethe uranyl cation. The U–O solv distances also show little

Szigethy, Geza

2011-01-01T23:59:59.000Z

139

LA-5097-MS INFORMAL REPORT  

Office of Legacy Management (LM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarlyEnergyDepartment ofDepartment ofof EnergyYou$ EGcG ENERGYELIkNATIONHEALXH: l ._I5097-MS INFORMAL

140

Paper Preview Paper Number 15730-MS  

E-Print Network [OSTI]

Permeability Authors Ali, H.S., Al-Marhoun, M.A., Abu-Khamsin, S.A., Celik, M.S., U. of Petroleum and Minerals

Abu-Khamsin, Sidqi

Note: This page contains sample records for the topic "ms uo uo" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

2d-LC-MS/MS Method-ORNL Developed for Bacteriophage  

E-Print Network [OSTI]

mass spectrometry (2d-LC-MS/MS) method was optimized for bacteriophage by Kristen Corrier undergraduate should be. 4. The mass spectrometer is run in data dependent mode, specific settings should be optimized

Sullivan, Matthew B.

142

Analysis of Thiodiglycol: Validation of Semi-Volatile Analysis by HPLC-MS/MS by EPA Method MS777  

SciTech Connect (OSTI)

The Environmental Protection Agency's (EPA) Region 5 Chicago Regional Laboratory (CRL) developed a method for the analysis of thiodiglycol, the breakdown product of the sulfur mustard HD, in water by high performance liquid chromatography tandem mass spectrometry (HPLC-MS/MS), titled Method EPA MS777 (hereafter referred to as EPA CRL SOP MS777). This draft standard operating procedure (SOP) was distributed to multiple EPA laboratories and to Lawrence Livermore National Laboratory, which was tasked to serve as a reference laboratory for EPA's Environmental Reference Laboratory Network (ERLN) and to develop and validate analytical procedures. The primary objective of this study was to verify the analytical procedures described in MS777 for analysis of thiodiglycol in aqueous samples. The gathered data from this study will be used to: (1) demonstrate analytical method performance; (2) generate quality control acceptance criteria; and (3) revise the SOP to provide a validated method that would be available for use during a homeland security event. The data contained in this report will be compiled, by EPA CRL, with data generated by other EPA Regional laboratories so that performance metrics of Method EPA MS777 can be determined.

Owens, J; Koester, C

2008-07-24T23:59:59.000Z

143

SPEAKER BIOGRAPHIES Jim Bowker BS, MS  

E-Print Network [OSTI]

, and Bioligics. Jim earned BS and MS degrees from Eastern Michigan University. He is President- elect liaison, she manages a large cooperative agreement and represents Veterinary Services (VS) Illinois

144

MS.BIOLOGY.THESIS ACADEMIC LEARNING PLAN  

E-Print Network [OSTI]

effectively to constructive feedback. Job Prospects for Biology Graduates MS in Biology Bioremediation Biotechnology Medical Research Industry Government Education Microbiology Health Professions Research Health Food Production Pollution Control Environmental Diagnostics Forestry Agriculture #12;APPENDIX B

O'Laughlin, Jay

145

Analysis of Ethanolamines: Validation of Semi-Volatile Analysis by HPLC-MS/MS by EPA Method MS888  

SciTech Connect (OSTI)

The Environmental Protection Agency's (EPA) Region 5 Chicago Regional Laboratory (CRL) developed a method titled 'Analysis of Diethanolamine, Triethanolamine, n-Methyldiethanolamine, and n-Ethyldiethanolamine in Water by Single Reaction Monitoring Liquid Chromatography/Tandem Mass Spectrometry (LC/MS/MS): EPA Method MS888'. This draft standard operating procedure (SOP) was distributed to multiple EPA laboratories and to Lawrence Livermore National Laboratory, which was tasked to serve as a reference laboratory for EPA's Environmental Reference Laboratory Network (ERLN) and to develop and validate analytical procedures. The primary objective of this study was to validate and verify the analytical procedures described in 'EPA Method MS888' for analysis of the listed ethanolamines in aqueous samples. The gathered data from this validation study will be used to: (1) demonstrate analytical method performance; (2) generate quality control acceptance criteria; and (3) revise the SOP to provide a validated method that would be available for use during a homeland security event. The data contained in this report will be compiled, by EPA CRL, with data generated by other EPA Regional laboratories so that performance metrics of 'EPA Method MS888' can be determined.

Owens, J; Vu, A; Koester, C

2008-10-08T23:59:59.000Z

146

Analysis of Carbamate Pesticides: Validation of Semi-Volatile Analysis by HPLC-MS/MS by EPA Method MS666  

SciTech Connect (OSTI)

The Environmental Protection Agency's (EPA) Region 5 Chicago Regional Laboratory (CRL) developed a method for analysis of aldicarb, bromadiolone, carbofuran, oxamyl, and methomyl in water by high performance liquid chromatography tandem mass spectrometry (HPLC-MS/MS), titled Method EPA MS666. This draft standard operating procedure (SOP) was distributed to multiple EPA laboratories and to Lawrence Livermore National Laboratory, which was tasked to serve as a reference laboratory for EPA's Environmental Reference Laboratory Network (ERLN) and to develop and validate analytical procedures. The primary objective of this study was to validate and verify the analytical procedures described in MS666 for analysis of carbamate pesticides in aqueous samples. The gathered data from this validation study will be used to: (1) demonstrate analytical method performance; (2) generate quality control acceptance criteria; and (3) revise the SOP to provide a validated method that would be available for use during a homeland security event. The data contained in this report will be compiled, by EPA CRL, with data generated by other EPA Regional laboratories so that performance metrics of Method EPA MS666 can be determined.

Owens, J; Koester, C

2008-05-14T23:59:59.000Z

147

Sources of Technical Variability in Quantitative LC-MS Proteomics...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Sources of Technical Variability in Quantitative LC-MS Proteomics: Human Brain Tissue Sample Analysis. Sources of Technical Variability in Quantitative LC-MS Proteomics: Human...

148

Investigation of Uranium Polymorphs  

SciTech Connect (OSTI)

The UO3-water system is complex and has not been fully characterized, even though these species are common throughout the nuclear fuel cycle. As an example, most production schemes for UO3 result in a mixture of up to six or more different polymorphic phases, and small differences in these conditions will affect phase genesis that ultimately result in measureable changes to the end product. As a result, this feature of the UO3-water system may be useful as a means for determining process history. This research effort attempts to better characterize the UO3-water system with a variety of optical techniques for the purpose of developing some predictive capability for estimating process history in polymorphic phases of unknown origin. Three commercially relevant preparation methods for the production of UO3 were explored. Previously unreported low temperature routes to ?- and ?-UO3 were discovered. Raman and fluorescence spectroscopic libraries were established for pure and mixed polymorphic forms of UO3 in addition to the common hydrolysis products of UO3. An advantage of the sensitivity of optical fluorescence microscopy over XRD has been demonstrated. Preliminary aging studies of the ? and ? forms of UO3 have been conducted. In addition, development of a 3-D phase field model used to predict phase genesis of the system was initiated. Thermodynamic and structural constants that will feed the model have been gathered from the literature for most of the UO3 polymorphic phases.

Sweet, Lucas E.; Henager, Charles H.; Hu, Shenyang Y.; Johnson, Timothy J.; Meier, David E.; Peper, Shane M.; Schwantes, Jon M.

2011-08-01T23:59:59.000Z

149

LA-12968-MS The Unsaturated Hydraulic  

E-Print Network [OSTI]

LA-12968-MS The Unsaturated Hydraulic Characteristics of the BandelierTuff LosN A T I O N A L L A B technical correctness. #12;The Unsaturated Hydraulic Characteristics of the Bandelier Tuff David B. Rogers........................................................................................................4 Hydraulic Data Presentation

150

LA-13194-MS Fracture Characterization of the  

E-Print Network [OSTI]

LA-13194-MS Fracture Characterization of the Bandelier Tuff in OU-1098 (TA-2 and TA-41) LosN A T I technical correctness. #12;Fracture Characterization of the Bandelier Tuff in OU-1098 (TA-2 and TA-41 Los Alamos, New Mexico 87545 #12;1 Fracture Characterization of the Bandelier Tuff in OU-1098 (TA-2

151

Analysis of Phosphonic Acids: Validation of Semi-Volatile Analysis by HPLC-MS/MS by EPA Method MS999  

SciTech Connect (OSTI)

The Environmental Protection Agency's (EPA) Region 5 Chicago Regional Laboratory (CRL) developed a method titled Analysis of Diisopropyl Methylphosphonate, Ethyl Hydrogen Dimethylamidophosphate, Isopropyl Methylphosphonic Acid, Methylphosphonic Acid, and Pinacolyl Methylphosphonic Acid in Water by Multiple Reaction Monitoring Liquid Chromatography/Tandem Mass Spectrometry: EPA Version MS999. This draft standard operating procedure (SOP) was distributed to multiple EPA laboratories and to Lawrence Livermore National Laboratory, which was tasked to serve as a reference laboratory for EPA's Environmental Reference Laboratory Network (ERLN) and to develop and validate analytical procedures. The primary objective of this study was to validate and verify the analytical procedures described in EPA Method MS999 for analysis of the listed phosphonic acids and surrogates in aqueous samples. The gathered data from this validation study will be used to: (1) demonstrate analytical method performance; (2) generate quality control acceptance criteria; and (3) revise the SOP to provide a validated method that would be available for use during a homeland security event. The data contained in this report will be compiled, by EPA CRL, with data generated by other EPA Regional laboratories so that performance metrics of EPA Method MS999 can be determined.

Owens, J; Vu, A; Koester, C

2008-10-31T23:59:59.000Z

152

MS 211 -CALCULO NUMERICO -1o http://www.ime.unicamp.br/ ms211/  

E-Print Network [OSTI]

MS 211 - C´ALCULO NUM´ERICO - 1o SEM/2010 http://www.ime.unicamp.br/ ms211/ Turma Per triangulares. Elimina¸c~ao de Gauss. Pivoteamento Parcial. Decomposi¸c~ao LU. M´etodos iterativos de Jacobi e¸c~ao num´erica. 4. Equa¸c~oes n~ao-lineares: M´etodo da bissec¸c~ao . M´etodo de Newton. M´etodo da Secante

Sussner, Peter

153

Molten uranium dioxide structure and dynamics  

DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

Uranium dioxide (UO2) is the major nuclear fuel component of fission power reactors. A key concern during severe accidents is the melting and leakage of radioactive UO2 as it corrodes through its zirconium cladding and steel containment. Yet, the very high temperatures (>3140 kelvin) and chemical reactivity of molten UO2 have prevented structural studies. In this work, we combine laser heating, sample levitation, and synchrotron x-rays to obtain pair distribution function measurements of hot solid and molten UO2. The hot solid shows a substantial increase in oxygen disorder around the lambda transition (2670 K) but negligible U-O coordination change. On melting, the average U-O coordination drops from 8 to 6.7 ± 0.5. Molecular dynamics models refined to this structure predict higher U-U mobility than 8-coordinated melts.

Skinner, L. B. [Argonne National Laboratory (ANL), Argonne, IL (United States); Stony Brook Univ., Stony Brook, NY (United States); Materials Development Inc., Arlington Heights, IL (United States); Parise, J. B. [Stony Brook Univ., Stony Brook, NY (United States); Benmore, C. J. [Argonne National Laboratory (ANL), Argonne, IL (United States); Weber, J. K.R. [Materials Development Inc., Arlington Heights, IL (United States); Williamson, M. A. [Argonne National Laboratory (ANL), Argonne, IL (United States); Tamalonis, A. [Materials Development Inc., Arlington Heights, IL (United States); Hebden, A. [Argonne National Laboratory (ANL), Argonne, IL (United States); Wiencek, T. [Argonne National Laboratory (ANL), Argonne, IL (United States); Alderman, O. L.G. [Materials Development Inc., Arlington Heights, IL (United States); Guthrie, M. [Carnegie Inst., Washington, DC (United States); Leibowitz, L. [Argonne National Laboratory (ANL), Argonne, IL (United States)

2014-11-20T23:59:59.000Z

154

MS.BIOLOGY.NON-THESIS ACADEMIC LEARNING PLAN  

E-Print Network [OSTI]

to constructive feedback Job Prospects for Biology Graduates MS/non-thesis in Biology Bioremediation Biotechnology Medical Research Industry Government Education Microbiology Health Professions Research Laboratories Find Food Production Pollution Control Environmental Diagnostics Forestry Agriculture #12;MS

O'Laughlin, Jay

155

Ms. Victoria A. White Chief Operating Officer Fermilab  

Broader source: Energy.gov (indexed) [DOE]

Ms. Victoria A. White Chief Operating Officer Fermilab P.O. Box 500 Batavia, I L 60510 Dear Ms. White: SUBJECT : NATIONA L ENVIRON MENTAL POLICY ACT DETERMI NATION AT FERMI...

156

DEBRA ANNE ROACH, M.S. Assistant Dean  

E-Print Network [OSTI]

#12;DEBRA ANNE ROACH, M.S. Assistant Dean Director Graduate Enrollment SEAN-MICHAEL GREEN, J.D., LL & Adult Enrollment 845-575-3512 sean-michael.green@marist.edu DEBRA ANNE ROACH, M.S. Assistant Dean

Navara, Kristen

157

Genizah MS T-S AS 154.342  

E-Print Network [OSTI]

Possibly payment order or accounting, mentioning M?s? (?), Egypt and 'only three', with Persian-Arabic numerals....

Unknown

2011-02-24T23:59:59.000Z

158

Department of Mathematical Sciences Accelerated M.S. Program  

E-Print Network [OSTI]

Department of Mathematical Sciences Accelerated M.S. Program The Department of Mathematical education and an M.S. in Statistics. The Accelerated M.S. Program (AMSP) is designed to assist MSU at Montana State University may accelerate their program through any combination of Advanced Placement Credit

Lawrence, Rick L.

159

Carbon Management working with the  

E-Print Network [OSTI]

: UoR42 Energy centre 82 Appendix C29: UoR43 Fume cupboard control 83 Appendix C30: UoR44 Solar PV achievement towards target 29 5. Carbon Management Plan Financing 32 5.1 Assumptions 32 5.2 Benefits / savings ­ quantified and un-quantified 33 5.3 Additional resources 33 5.4 Financial costs and sources of funding 34 6

Reading, University of

160

High Field Magnetization measurements of uranium dioxide single crystals (P08358- E003-PF)  

SciTech Connect (OSTI)

Conclusions: Our preliminary high field magnetic measurements of UO2 are consistent with a complex nature of the magnetic ordering in this material, compatible with the previously proposed non-collinear 3-k magnetic structure. Further extensive magnetic studies on well-oriented (<100 > and <111>) UO2 crystals are planned to address the puzzling behavior of UO2 in both antiferromagnetic and paramagnetic states at high fields.

K. Gofryk; N. Harrison; M. Jaime

2014-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "ms uo uo" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Category:Jackson, MS | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of InspectorConcentrating SolarElectricEnergyCTBarreis aCallahanWind FarmAdd a newISGAN Definitions JumpMS"

162

MS makes the clinical grade | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: VegetationEquipment Surfaces and InterfacesAdministration -Lowell L.FallU . S . D e p a rMS makes the

163

c-Type Cytochrome-Dependent Formation of U(IV) Nanoparticles...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

extracellularly to high densities in association with an exopolymeric substance (EPS). In wild type cells, this UO2-EPS matrix exhibited glycocalyx-like properties,...

164

Electron donor-dependent radionuclide reduction and nanoparticle...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

size were observed, the association of UO2 nanoparticles with an exopolymeric substance (EPS) was observed and found to be independent of electron donor source. Electron...

165

Crystallographic controls on uranyl binding at the quartz/water...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

controls on uranyl binding at the quartzwater interface. Abstract: Molecular dynamics methods were used to simulate UO2(OH)20 binding to pairs of oxo sites on three...

166

E-Print Network 3.0 - autoimmune skin blistering Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Engineering, McMaster University Collection: Materials Science 6 For additional Environmental Health and Safety needs please visit our website at: http:www.uos.harvard.edu...

167

E-Print Network 3.0 - action description memorandum Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

REPAIR GOODS MEMORANDUM Summary: UNIVERSITY OF WASHINGTON RETURNREPAIR GOODS MEMORANDUM PURCHASING, Box No. 351110 UoW 1458 (Rev.8... label) Vendor Authorization Name P.O. Item...

168

Searching for the Decay of 229m Th  

E-Print Network [OSTI]

3 , UO 2 (NO 3 ) 2 (uranyl nitrate), and metallic uranium.varied from 12% for uranyl nitrate to 31% for uranium metal.

Swanberg, Erik

2012-01-01T23:59:59.000Z

169

U Plant Ancillary Facility Demolition A Department of Energy...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

35,346 square foot multi- storied concrete structure used for the concentration of liquid uranium solutions and UO3 powder conversion equipment. 224-UA Calcination and Loadout...

170

Complexation of U(VI) with 1-Hydroxyethane-1,1-diphosphonicAcid (HEDPA) in Acidic to Basic Solutions  

SciTech Connect (OSTI)

Complexation of U(VI) with 1-hydroxyethane-1,1-diphosphonic acid (HEDPA) in acidic to basic solutions has been studied with multiple techniques. A number of 1:1 (UO{sub 2}H{sub 3}L), 1:2 (UO{sub 2}H{sub j}L{sub 2} where j = 4, 3, 2, 1, 0 and -1) and 2:2 ((UO{sub 2}){sub 2}H{sub j}L{sub 2} where j = 1, 0 and -1) complexes form, but the 1:2 complexes are the major species in a wide pH range. Thermodynamic parameters (formation constants, enthalpy and entropy of complexation) were determined by potentiometry and calorimetry. Data indicate that the complexation of U(VI) with HEDPA is exothermic, favored by the enthalpy of complexation. This is in contrast to the complexation of U(VI) with dicarboxylic acids in which the enthalpy term usually is unfavorable. Results from electrospray ionization mass spectrometry (ESI-MS) and {sup 31}P NMR have confirmed the presence of 1:1, 1:2 and 2:2 U(VI)-HEDPA complexes.

Reed, W A; Rao, L; Zanonato, P; Garnov, A; Powell, B A; Nash, K L

2007-01-24T23:59:59.000Z

171

Source term evaluation for UF{sub 6} release event in feed facility at gaseous diffusion plants  

SciTech Connect (OSTI)

An assessment of UF{sub 6} release accidents was conducted for the feed facility of a gaseous diffusion plant (GDP). Release rates from pig-tail connections were estimated from CYLIND code predictions, whereas, MELCOR was utilized for simulating reactions of UF{sub 6} with moisture and consequent transport of UO{sub 2}F{sub 2} aerosols and HF vapor through the building and to the environment. Two wind speeds were utilized. At the high end (Case 1) a wind speed of {approximately} 1 m/s (200 fpm) was assumed to flow parallel to the building length. At the low end (Case 2) to represent stagnant conditions a corresponding wind speed of 1 cm/s (2 fpm) was utilized. A further conservative assumption was made to specify no closure of crane and train doors at either end of the building. Relaxation of this assumption should provide for additional margins. Results indicated that, for the high (200 fpm) wind speed, close to 66% of the UO{sub 2}F{sub 2} aerosols and 100% of the HF gas get released to the environment over a 10-minute period. However, for the low (2 fpm) wind speed, negligible amount ({approximately} 1% UO{sub 2}F{sub 2}) of aerosols get released even over a 2 hour period.

Kim, S.H.; Taleyarkhan, R.P.

1997-01-30T23:59:59.000Z

172

Alignment of LC-MS Data Using Peptide Features  

E-Print Network [OSTI]

Spectrometry MALDI Matrix Assisted Laser Desorption Ionization MS Mass Spectrometry MS/MS Tandem Mass Spectrometry M/Z Mass-To-Charge Ratio PNNL Paci c Northwest National Laboratory RT Retention Time SELDI Surface Enhanced Laser Desorption Ionization... alignment. In this paper, two Shewanella datasets are obtained from Paci c Northwest Na- tional Laboratory (PNNL) and they were analyzed by SEQUEST on di erent days. SEQUEST correlates uninterpreted tandem mass spectra of peptides with amino acid...

Tang, Xincheng

2012-02-14T23:59:59.000Z

173

Ms. Victoria A. White Chief Operating Officer Fermilab  

Broader source: Energy.gov (indexed) [DOE]

1L 60510 Dear Ms. White: SUBJECT: NATIUNAL ENVIRONMENTA L POLICY ACT (NEPA) DETERMINATIO N AT FERMI NATIONAL ACCELERATOR LABORATORY (FERMlLAB) - NEPESE MARSH UPGRADES Reference:...

174

PhD Chemical Engineering MS Chemical Engineering  

E-Print Network [OSTI]

1 PhD Chemical Engineering MS Chemical Engineering Bylaws Gene and Linda Voiland School of Chemical Engineering and Bioengineering College of Engineering and Architecture Approved by Voiland School facultyD Chemical Engineering, MS Chemical Engineering B. Discipline: Edgar, et al.1 provide a succinct description

Collins, Gary S.

175

GRADUATE STUDENT HANDBOOK Vol. I. Master Programs (MS and ME)  

E-Print Network [OSTI]

.2 Degree Requirements 3.2.1 MS and ME Degree Requirements in Civil Engineering and Environmental.1 Welcome Welcome to the graduate program of the Department of Civil and Environmental Engineering and Environmental Engineering: Master of Engineering (M.E.) in Civil Engineering Master of Science (M.S.) in Civil

176

Ms. Maushumi, Head Mistress Babul Sarkar, Vice President  

E-Print Network [OSTI]

Ms. Maushumi, Head Mistress Babul Sarkar, Vice President Char Domdoama Primary School Vill: Char Razzaq-Shamsun Best Teacher Award and Abdul Awal Sarkar Best Student Awards in Char Domdoma Primary School Dear Ms. Maushumi and Mr. Sarkar, My proposal for the introduction of one teaching and three

Nahar, Sultana Nurun

177

Characterization of the Human Pancreatic Islet Proteome by Two-Dimensional LC/MS/MS  

SciTech Connect (OSTI)

Research to elucidate the pathogenesis of type 1 diabetes mellitus has traditionally focused on the genetic and immunological factors associated with the disease, and, until recently, has not considered the target cell. While there have been reports detailing proteomic analyses of established islet cell lines or isolated rodent islets, the information gained is not always easily extrapolated to humans. Therefore, extensive characterization of the human islet proteome could result in better understanding of islet biology and lead to more effective treatment strategies. We have applied a two-dimensional LC-MS/MS-based analysis to the characterization of the human islet proteome, resulting in the detection of 29,021 unique peptides corresponding to 4,925 proteins. As expected, major islet hormones (insulin, glucagon, somatostatin), beta-cell enriched secretory products (IAPP), ion channels (K-ATP channel), and transcription factors (PDX-1, Nkx 6.1, HNF-1 beta) were detected. In addition, significant proteome coverage of metabolic enzymes and cellular pathways was obtained, including the insulin signaling cascade and the MAP kinase, NF-??, and JAK/STAT pathways. This work represents the most extensive characterization of the human islet proteome to date and provides a peptide reference library that may be utilized in future studies of islet biology and type 1 diabetes.

Metz, Thomas O.; Jacobs, Jon M.; Gritsenko, Marina A.; Fontes, Ghislaine; Qian, Weijun; Camp, David G.; Poitout, Vincent J.; Smith, Richard D.

2006-12-01T23:59:59.000Z

178

On the possibility of using uranium-beryllium oxide fuel in a VVER reactor  

SciTech Connect (OSTI)

The possibility of using UO{sub 2}-BeO fuel in a VVER reactor is considered with allowance for the thermophysical properties of this fuel. Neutron characteristics of VVER fuel assemblies with UO{sub 2}-BeO fuel pellets are estimated.

Kovalishin, A. A.; Prosyolkov, V. N.; Sidorenko, V. D. [National Research Center Kurchatov Institute (Russian Federation); Stogov, Yu. V., E-mail: YVStogov@mephi.ru [National Research Nuclear University MEPhI (Russian Federation)

2014-12-15T23:59:59.000Z

179

NANCY YEN-WEN CHENG Department of Architecture, School of Architecture and Allied Arts nywc@uoregon.edu  

E-Print Network [OSTI]

of Oregon (UO) Architecture Department 2012-present Director, UO - Shanghai Xian Dai Sustainable Design1 NANCY YEN-WEN CHENG Department of Architecture, School of Architecture and Allied Arts nywc mobile: +1-541-556-4590 http://architecture.uoregon.edu/faculty/cheng AUS mobile +61 (04) 1824 3873 E D U

180

JOURNAL OF GEOPHYSICAL RESEARCH, VOL. 97, NO. A9, PAGES 13,911-13,914, SEPTEMBER 1, 1992 Comment on "Dayside Pickup Oxygen Ion Precipitation at Venus and Mars'  

E-Print Network [OSTI]

on "Dayside Pickup Oxygen Ion Precipitation at Venus and Mars' Spatial Distributions, Energy Deposition; McGrath and Johnson, 1987]and by locally generated"pickup ions" [e.g., Kozyra et al., 1982; Ishimoto a hemisphericallyaveragedyield for ejection of oxygen atoms (O) from an oxygen exosphere, Y0= [rr(T> Uo)+ (6/·2)(otSn)/Uo]/o'd (1

Johnson, Robert E.

Note: This page contains sample records for the topic "ms uo uo" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Magnetization measurements of uranium dioxide single crystals (P08358-E002-PF)  

SciTech Connect (OSTI)

Conclusions Our preliminary magnetic susceptibility measurements of UO2 point to complex nature of the magnetic ordering in this material, consistent with the proposed non-collinear 3-k magnetic structure. Further extensive magnetic studies are planned to address the puzzling behavior of UO2 in both antiferromagnetic and paramagnetic states.

K. Gofryk; V. Zapf; M. Jaime

2014-12-01T23:59:59.000Z

182

Origin of Low Thermal Conductivity in Nuclear Fuels Quan Yin and Sergey Y. Savrasov  

E-Print Network [OSTI]

, the thermal conductivity of UO2 is very low, and the search for alternative materials continuesOrigin of Low Thermal Conductivity in Nuclear Fuels Quan Yin and Sergey Y. Savrasov Department in a very low thermal conductivity of modern nuclear fuels. Consider semiconducting UO2 which is a main

Savrasov, Sergej Y.

183

Admission Guidelines 2015 MS-Ph.D Integrated Degree Program  

E-Print Network [OSTI]

Admission Guidelines 2015 MS-Ph.D Integrated Degree Program (For KAIST Master's Degree Enrolled. of Chemical & Biomolecular Engineering Dept. of Materials Science & Engineering Dept. of Nuclear Transportation Dept. of Electrical Engineering Dept. of Computer Science Dept. of Industrial

Kim, Min H.

184

Admission Guidelines 2014 MS-Ph.D Integrated Degree Program  

E-Print Network [OSTI]

Admission Guidelines 2014 MS-Ph.D Integrated Degree Program (For KAIST Master's Degree Enrolled. of Chemical & Biomolecular Engineering Dept. of Materials Science & Engineering Dept. of Nuclear Transportation Dept. of Electrical Engineering Dept. of Computer Science Dept. of Industrial

Kim, Min H.

185

Ms. Victoria A, White Chief Operating Officer Fermilab  

Broader source: Energy.gov (indexed) [DOE]

A, White Chief Operating Officer Fermilab P.O. Box 50Q Batavia, I L 60510 Dear Ms. White: SUBJECT: NATIONAL ENVIRONMEN TAL POLICY ACT DTRMINATI QN AT ERMs NATIONAL ACCELERATO R...

186

MS211 -CALCULO NUMERICO -1o semestre de 2012  

E-Print Network [OSTI]

¸c~ao, Editora Pearson, 1997. · "M´etodos Num´ericos", Maria Cristina Cunha, 2a edi¸c~ao, Editora da UnicampMS211 - C´ALCULO NUM´ERICO - 1o semestre de 2012 http://www.ime.unicamp.br/ms211 Ementa 1. Aritm¸c~oes reais. M´etodos: bissec¸c~ao, Newton e secante. 3. Resolu¸c~ao de sistemas lineares: M´etodos diretos

Sussner, Peter

187

MS211 -CALCULO NUMERICO -2o semestre de 2012  

E-Print Network [OSTI]

¸c~ao, Editora Pearson, 1997. · "M´etodos Num´ericos", Maria Cristina Cunha, 2a edi¸c~ao, Editora da UnicampMS211 - C´ALCULO NUM´ERICO - 2o semestre de 2012 http://www.ime.unicamp.br/ms211 Ementa 1. Aritm¸c~oes reais. M´etodos: bissec¸c~ao, Newton e secante. 3. Resolu¸c~ao de sistemas lineares: M´etodos diretos

Sussner, Peter

188

MS211 -CALCULO NUMERICO -2o semestre de 2007  

E-Print Network [OSTI]

Pearson, 1997. · "M´etodos Num´ericos", Maria Cristina Cunha, 2a edi¸c~ao, Editora da Unicamp, 2000MS211 - C´ALCULO NUM´ERICO - 2o semestre de 2007 (http://www.ime.unicamp.br/ms211) Turma Professor fun¸c~oes reais. M´etodos: bissec¸c~ao, Newton e secante. 4. Resolu¸c~ao de sistemas lineares. M´etodos

Sussner, Peter

189

MS211 -CALCULO NUMERICO -1o semestre de 2008  

E-Print Network [OSTI]

¸c~ao, Editora Pearson, 1997. · "M´etodos Num´ericos", Maria Cristina Cunha, 2a edi¸c~ao, Editora da UnicampMS211 - C´ALCULO NUM´ERICO - 1o semestre de 2008 (http://www.ime.unicamp.br/ms211) turma professor flutuante. 2. Zeros reais de fun¸c~oes reais. M´etodos: bissec¸c~ao, Newton e secante. 3. Resolu¸c~ao de

Sussner, Peter

190

MS211 -CALCULO NUMERICO -1o semestre de 2008  

E-Print Network [OSTI]

MS211 - C´ALCULO NUM´ERICO - 1o semestre de 2008 (http://www.ime.unicamp.br/ms211) turma professor¸c~ao: o suporte computacional b´asico da disciplina ser´a o MatLab. BIBLIOGRAFIA · "C´alculo Num´erico¸c~ao, Editora Pearson, 1997. · "M´etodos Num´ericos", Maria Cristina Cunha, 2a edi¸c~ao, Editora da Unicamp

Gomes Ruggiero, Márcia A.

191

Some effects of data base variations on numerical simulations of uranium migration  

SciTech Connect (OSTI)

Numerical simulations of migration of chemicals in the geosphere depend on knowledge of identities of chemical species and on values of chemical equilibrium constants supplied to the simulators. In this work, some effects of variability in assumed speciation and in equilibrium constants were examined, using migration of uranium as an example. Various simulations were done of uranium migration in systems with varying oxidation potential, pH, and mator component content. A simulation including formation of aqueous species UO/sub 2//sup 2 +/, UO/sub 2/CO/sub 3//sup 0/, UO/sub 2/(CO/sub 3/)/sub 2//sup 2 -/, UO/sub 2/(CO/sub 3/)/sub 3//sup 4 -/, (UO/sub 2/)/sub 2/CO/sub 3/(OH)/sub 3//sup -/, UO/sub 2//sup +/, U(OH)/sub 4//sup 0/, and U(OH)/sub 5//sup -/ is compared to simulation excluding formation of UO/sub 2//sup +/ and U(OH)/sub 5//sup -/. These simulations relied on older data bases, and they are compared to a further simulation using recently published data on formation of U(OH)/sub 4//sup 0/, (UO/sub 2/)/sub 2/CO/sub 3/(OH)/sub 3//sup -/, UO/sub 2/(CO/sub 3/)/sub 5//sup 5 -/, and U(CO/sub 3/)/sub 5//sup 6 -/. Significant differences in dissolved uranium concentrations are noted among the simulations. Differences are noted also in precipitation of two solids, USiO/sub 4/(c) (coffinite) and CaUO/sub 4/(c) (calcium uranate), although the solubility products of the solids were not varied in the simulations. 18 refs., 9 figs., 2 tabs.

Carnahan, C.L.

1987-12-01T23:59:59.000Z

192

Fast and accurate database searches with MS-GF+Percolator  

SciTech Connect (OSTI)

To identify peptides and proteins from the large number of fragmentation spectra in mass spectrometrybased proteomics, researches commonly employ so called database search engines. Additionally, postprocessors like Percolator have been used on the results from such search engines, to assess confidence, infer peptides and generally increase the number of identifications. A recent search engine, MS-GF+, has previously been showed to out-perform these classical search engines in terms of the number of identified spectra. However, MS-GF+ generates only limited statistical estimates of the results, hence hampering the biological interpretation. Here, we enabled Percolator-processing for MS-GF+ output, and observed an increased number of identified peptides for a wide variety of datasets. In addition, Percolator directly reports false discovery rate estimates, such as q values and posterior error probabilities, as well as p values, for peptide-spectrum matches, peptides and proteins, functions useful for the whole proteomics community.

Granholm, Viktor; Kim, Sangtae; Navarro, Jose' C.; Sjolund, Erik; Smith, Richard D.; Kall, Lukas

2014-02-28T23:59:59.000Z

193

MS6983: Sediment transport processes in coastal environments Instructor: Courtney K. Harris  

E-Print Network [OSTI]

MS698­3: Sediment transport processes in coastal environments Instructor: Courtney K. Harris Spring

Harris, Courtney K.

194

Montana State University 1 M.S. in Mathematics -  

E-Print Network [OSTI]

Montana State University 1 M.S. in Mathematics - Mathematics Education Option (MSMME) The MSMME program emphasizes the teaching and learning of high school mathematics. The program offers a blend of courses addressing key topics in mathematics content and pedagogy. The MSMME curriculum

Lawrence, Rick L.

195

Deborah K. Smith Department of Geology and Geophysics, MS 22  

E-Print Network [OSTI]

Deborah K. Smith Department of Geology and Geophysics, MS 22 Woods Hole Oceanographic Institution: Jordan, T. H., H. W. Menard, and D.K. Smith, Density and size distribution of seamounts in the eastern. Smith, H. W. Menard, J. A. Orcutt and T. H. Jordan, Seismic reflection site survey: correlation

Smith, Deborah K.

196

SPE-163690-MS Synthetic, Geomechanical Logs for Marcellus Shale  

E-Print Network [OSTI]

SPE-163690-MS Synthetic, Geomechanical Logs for Marcellus Shale M. O. Eshkalak, SPE, S. D of hydrocarbons from the reservoirs, notably shale, is attributed to realizing the key fundamentals of reservoir and mineralogy is crucial in order to identify the "right" pay-zone intervals for shale gas production. Also

Mohaghegh, Shahab

197

MS211 -CALCULO NUMERICO -2o semestre de 2014  

E-Print Network [OSTI]

.L.Burden, J.D. Faires. An´alise Num´erica. Pioneira Thompson Learning, 2003. 3. M.C.Cunha. M´etodos Num´ericosMS211 - C´ALCULO NUM´ERICO - 2o semestre de 2014 Turma Professor Sala­IMECC e-mail A M. Aparecida´umeros reais. Aritm´etica de ponto flutuante. Teorema de Taylor. 2. Zeros reais de fun¸c~oes reais. M´etodos

Sussner, Peter

198

MS211 -CALCULO NUMERICO -2o semestre de 2011  

E-Print Network [OSTI]

. An´alise Num´erica. Pioneira Thompson Learning, 2003. 2. M.C.Cunha. M´etodos Num´ericos. 2a ediMS211 - C´ALCULO NUM´ERICO - 2o semestre de 2011 turma professor sala e-mail A ´Alvaro R. De Pierro flutuante. Teorema de Taylor. 2. Zeros reais de fun¸c~oes reais. M´etodos: bissec¸c~ao, Newton e secante. 3

Sussner, Peter

199

Method for factor analysis of GC/MS data  

DOE Patents [OSTI]

The method of the present invention provides a fast, robust, and automated multivariate statistical analysis of gas chromatography/mass spectroscopy (GC/MS) data sets. The method can involve systematic elimination of undesired, saturated peak masses to yield data that follow a linear, additive model. The cleaned data can then be subjected to a combination of PCA and orthogonal factor rotation followed by refinement with MCR-ALS to yield highly interpretable results.

Van Benthem, Mark H; Kotula, Paul G; Keenan, Michael R

2012-09-11T23:59:59.000Z

200

Label-Free Quantitative LC?MS Proteomics of Alzheimer&rsquo...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Label-Free Quantitative LC?MS Proteomics of Alzheimer’s Disease and Normally Aged Human Brains. Label-Free Quantitative LC?MS Proteomics of Alzheimer’s...

Note: This page contains sample records for the topic "ms uo uo" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Applying a Targeted Label-free Approach using LC-MS AMT Tags...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Applying a Targeted Label-free Approach using LC-MS AMT Tags to Evaluate Changes in Protein Phosphorylation Following Applying a Targeted Label-free Approach using LC-MS AMT Tags...

202

Electrolytic process for preparing uranium metal  

DOE Patents [OSTI]

An electrolytic process for making uranium from uranium oxide using Cl.sub.2 anode product from an electrolytic cell to react with UO.sub.2 to form uranium chlorides. The chlorides are used in low concentrations in a melt comprising fluorides and chlorides of potassium, sodium and barium in the electrolytic cell. The electrolysis produces Cl.sub.2 at the anode that reacts with UO.sub.2 in the feed reactor to form soluble UCl.sub.4, available for a continuous process in the electrolytic cell, rather than having insoluble UO.sub.2 fouling the cell.

Haas, Paul A. (Knoxville, TN)

1990-01-01T23:59:59.000Z

203

Extreme Performance Scalable Operating Systems Final Progress Report (July 1, 2008 Ă?Â?Ă?¢Ă?Â?Ă?Â?Ă?Â?Ă?Â? October 31, 2011)  

SciTech Connect (OSTI)

This is the final progress report for the FastOS (Phase 2) (FastOS-2) project with Argonne National Laboratory and the University of Oregon (UO). The project started at UO on July 1, 2008 and ran until April 30, 2010, at which time a six-month no-cost extension began. The FastOS-2 work at UO delivered excellent results in all research work areas: * scalable parallel monitoring * kernel-level performance measurement * parallel I/0 system measurement * large-scale and hybrid application performance measurement * onlne scalable performance data reduction and analysis * binary instrumentation

Allen D. Malony; Sameer Shende

2011-10-31T23:59:59.000Z

204

Effects of the anesthesia agents benozocaine and tricaine methanesulfonate (MS-222) on  

E-Print Network [OSTI]

1 Effects of the anesthesia agents benozocaine and tricaine methanesulfonate (MS-222) on immune anesthesia ­ 10 min MS-222 ­ 14 min benzocaine #12;3 Materials and Methods Control Rinse MS-222 Benzocaine Control Anesthesia Recovery ASW ASW Aquaria 7 days Materials and Methods: Experiment 1 · Blood collection

Kane, Andrew S.

205

ARM - Campaign Instrument - pyran-eko-ms-801  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinanInformationbudapest Comments? We would love to hear from you! Send us a note below or calleko-ms-801

206

Ms. Julie Smith Office of Electricity Delivery and Energy Reliability  

Broader source: Energy.gov (indexed) [DOE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarly Careerlumens_placard-green.eps MoreWSRC-STI-2007-00250 Rev.Tech Brief answers: Why9, 20145, 2013 Ms.

207

Materials Science and Engineering BS/MS Program The Department of Materials Science and Engineering offers a combined BS/MS degree  

E-Print Network [OSTI]

Materials Science and Engineering BS/MS Program The Department of Materials Science and Engineering currently enrolled in Major Status in the Materials Science and Engineering program can be admitted to expand the research of the student's Senior Design Project to a M.S. thesis. The Senior Design

Tipple, Brett

208

Rapid, potentially automatable, method extract biomarkers for HPLC/ESI/MS/MS to detect and identify BW agents  

SciTech Connect (OSTI)

The program proposes to concentrate on the rapid recovery of signature biomarkers based on automated high-pressure, high-temperature solvent extraction (ASE) and/or supercritical fluid extraction (SFE) to produce lipids, nucleic acids and proteins sequentially concentrated and purified in minutes with yields especially from microeukaryotes, Gram-positive bacteria and spores. Lipids are extracted in higher proportions greater than classical one-phase, room temperature solvent extraction without major changes in lipid composition. High performance liquid chromatography (HPLC) with or without derivatization, electrospray ionization (ESI) and highly specific detection by mass spectrometry (MS) particularly with (MS){sup n} provides the detection, identification and because the signature lipid biomarkers are both phenotypic as well as genotypic biomarkers, insights into potential infectivity of BW agents. Feasibility has been demonstrated with detection, identification, and determination of infectious potential of Cryptosporidium parvum at the sensitivity of a single oocyst (which is unculturable in vitro) and accurate identification and prediction, pathogenicity, and drug-resistance of Mycobacteria spp.

White, D.C. [Univ. of Tennessee, Knoxville, TN (United States). Center for Environmental Biotechnology]|[Oak Ridge National Lab., TN (United States). Environmental Science Div.; Burkhalter, R.S.; Smith, C. [Univ. of Tennessee, Knoxville, TN (United States). Center for Environmental Biotechnology; Whitaker, K.W. [Microbial Insights, Inc., Rockford, TN (United States)

1997-12-31T23:59:59.000Z

209

Evaluation of alternative fuel cycle strategies for nuclear power generation in the 21st century  

E-Print Network [OSTI]

The deployment of fuel recycling through either CONFU (COmbined Non-Fertile and UO2 fuel) thermal watercooled reactors (LWRs) or fast ABR (Actinide Burner Reactor) reactors is compared to the Once-Through LWR reactor system ...

Boscher, Thomas

2005-01-01T23:59:59.000Z

210

MARMOT Enhanced  

Broader source: Energy.gov [DOE]

To develop mechanistic models for fuel thermal conductivity, the Fuel team used supercells up to 55 nm long to determine the thermal conductivity of UO2 with Xe incorporated.

211

Changes in U(VI) speciation upon sorption onto montmorillonite from aqueous and organic solutions  

SciTech Connect (OSTI)

The speciation of UO{sub 2}{sup 2+} and UO{sub 2}{sup 2+} Tributylphosphate (TBP) mixtures has been investigated in solution and intercalated with the reference smectite clay SAz-1 using x-ray absorption, Raman, and luminescence spectroscopies. Neither aquated UO{sub 2}{sup 2+} nor its TBP complex undergoes any detectable changes in uranium oxidation state on intercalation. Further, at the pH values employed in this work, there is no evidence for hydrolysis of the uranium species to generate dimeric or higher order uranium oligomers. However, we do find indications that the structures of the solution complexes are altered on intercalation, particularly for the UO{sub 2}{sup 2+}/TBP system. In addition, several lines of evidence suggest that, at the loading levels used in this study, the uranyl species may be interacting with two or more spectroscopically distinguishable sites on SAz-1. 29 refs., 3 figs., 2 tabs.

Chisholm-Brause, C.; Morris, D.E.; Eller, P.G.; Buscher, T.; Conradson, S.D.

1991-01-01T23:59:59.000Z

212

Analysis of conventional and plutonium recycle unit-assemblies for the Yankee (Rowe) PWR  

E-Print Network [OSTI]

An analysis and comparison of Unit Conventional UO2 Fuel-Assemblies and proposed Plutonium Recycle Fuel Assemblies for the Yankee (Rowe) Reactor has been made. The influence of spectral effects, at the watergaps -and ...

Mertens, Paul Gustaaf

1971-01-01T23:59:59.000Z

213

MFR PAPER 1031 Traw ls and traps capture  

E-Print Network [OSTI]

a carapace II idlh of 7 inches and a \\\\eighl of more than 2.5 pounds (WillieI'. 1966), A cammer· ci al prl,\\uo, of ,\\ ,hart ,upph prl)UULCr "I red .:rab

214

2/21/11 11:08 AMOregon Quarterly Features Page 1 of 4http://www.oregonquarterly.com/winter2010/feature4.php  

E-Print Network [OSTI]

/feature4.php UO Home | Dept index Winter 2010 | Volume 90, Number 2 Donate to OQ | Past Issues:08 AMOregon Quarterly Features Page 2 of 4http://www.oregonquarterly.com/winter2010/feature4.php monochrome

Richmond, Geraldine L.

215

Small Satellite Applications of Commercial off the Shelf Radio Frequency Integrated Circuits  

E-Print Network [OSTI]

small satellite, Orbiting Satellite Carrying Amateur Radio (OSCAR) UO-14, was launched in 1990 [15]. While these amateur radio speeds may be sufficient for requirements of the aforementioned missions, they do very little towards expanding future...

Graves, John

2012-02-14T23:59:59.000Z

216

Subsurface Uranium Fate and Transport: Integrated Experiments and Modeling of Coupled Biogeochemical Mechanisms of Nanocrystalline Uraninite Oxidation by Fe(III)-(hydr)oxides - Project Final Report  

SciTech Connect (OSTI)

Subsurface bacteria including sulfate reducing bacteria (SRB) reduce soluble U(VI) to insoluble U(IV) with subsequent precipitation of UO2. We have shown that SRB reduce U(VI) to nanometer-sized UO2 particles (1-5 nm) which are both intra- and extracellular, with UO2 inside the cell likely physically shielded from subsequent oxidation processes. We evaluated the UO2 nanoparticles produced by Desulfovibrio desulfuricans G20 under growth and non-growth conditions in the presence of lactate or pyruvate and sulfate, thiosulfate, or fumarate, using ultrafiltration and HR-TEM. Results showed that a significant mass fraction of bioreduced U (35-60%) existed as a mobile phase when the initial concentration of U(VI) was 160 µM. Further experiments with different initial U(VI) concentrations (25 - 900 ?M) in MTM with PIPES or bicarbonate buffers indicated that aggregation of uraninite depended on the initial concentrations of U(VI) and type of buffer. It is known that under some conditions SRB-mediated UO2 nanocrystals can be reoxidized (and thus remobilized) by Fe(III)-(hydr)oxides, common constituents of soils and sediments. To elucidate the mechanism of UO2 reoxidation by Fe(III) (hydr)oxides, we studied the impact of Fe and U chelating compounds (citrate, NTA, and EDTA) on reoxidation rates. Experiments were conducted in anaerobic batch systems in PIPES buffer. Results showed EDTA significantly accelerated UO2 reoxidation with an initial rate of 9.5?M day-1 for ferrihydrite. In all cases, bicarbonate increased the rate and extent of UO2 reoxidation with ferrihydrite. The highest rate of UO2 reoxidation occurred when the chelator promoted UO2 and Fe(III) (hydr)oxide dissolution as demonstrated with EDTA. When UO2 dissolution did not occur, UO2 reoxidation likely proceeded through an aqueous Fe(III) intermediate as observed for both NTA and citrate. To complement to these laboratory studies, we collected U-bearing samples from a surface seep at the Rifle field site and have measured elevated U concentrations in oxic iron-rich sediments. To translate experimental results into numerical analysis of U fate and transport, a reaction network was developed based on Sani et al. (2004) to simulate U(VI) bioreduction with concomitant UO2 reoxidation in the presence of hematite or ferrihydrite. The reduction phase considers SRB reduction (using lactate) with the reductive dissolution of Fe(III) solids, which is set to be microbially mediated as well as abiotically driven by sulfide. Model results show the oxidation of HS– by Fe(III) directly competes with UO2 reoxidation as Fe(III) oxidizes HS– preferentially over UO2. The majority of Fe reduction is predicted to be abiotic, with ferrihydrite becoming fully consumed by reaction with sulfide. Predicted total dissolved carbonate concentrations from the degradation of lactate are elevated (log(pCO2) ~ –1) and, in the hematite system, yield close to two orders-of-magnitude higher U(VI) concentrations than under initial carbonate concentrations of 3 mM. Modeling of U(VI) bioreduction with concomitant reoxidation of UO2 in the presence of ferrihydrite was also extended to a two-dimensional field-scale groundwater flow and biogeochemically reactive transport model for the South Oyster site in eastern Virginia. This model was developed to simulate the field-scale immobilization and subsequent reoxidation of U by a biologically mediated reaction network.

Peyton, Brent M. [Montana State University; Timothy, Ginn R. [University of California Davis; Sani, Rajesh K. [South Dakota School of Mines and Technology

2013-08-14T23:59:59.000Z

217

Characterizing solution and solid-phase amorphous uranyl silicates q  

E-Print Network [OSTI]

2007 Elsevier Ltd. All rights reserved. 1. INTRODUCTION Dissolved uranium, as the uranyl ion UO2 2Ăľ , is consid- ered a contaminant introduced into the environment near mining, processing and production

Illinois at Chicago, University of

218

anti-ganglioside gd2 antibodies: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Dillon; Barry; M. Gray 3 Determination of Gd concentration profile in UO2-Gd2O3 fuel pellets CERN Preprints Summary: A transversal mapping of the Gd concentration was measured in...

219

Contact Detection and Constraints Enforcement for the Simulation of Pellet/Clad Thermo-Mechanical Contact in Nuclear Fuel Rods  

E-Print Network [OSTI]

As fission process heats up the fuel rods, UO2 pellets stacked on top of each other swell both radially and axially, while the surrounding Zircaloy cladding creeps down, so that the pellets eventually come into contact with the clad...

Lebrun-Grandié, Damien Thomas

2014-03-05T23:59:59.000Z

220

Diffusion and Adsorption of Uranyl Carbonate Species in Nanosized...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

whereas adsorption of CO32- and Ca2UO2(CO3)3, which attach to the surface via hydrogen bonding from a surface hydroxyl group to a carbonate oxygen, was calculated to be either...

Note: This page contains sample records for the topic "ms uo uo" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Annual Report 2008 -- Office of the Chief Financial Officer (OCFO)  

E-Print Network [OSTI]

C R A D A - Small Business CRADA • Othei Total CooperativeInformation ($K) uo.ooo DOEM&O CRADA WFO Program (WN| BT FY2006 FY2007 T DOEM&O CRADA WFO Program (WN| Universities

Fernandez, Jeffrey

2009-01-01T23:59:59.000Z

222

Department of architecturein portlanD  

E-Print Network [OSTI]

recognized for educating architects who understand and practice sustainable design. The UO architecture program is rated in the top three for sustainable design education based on surveys of U.S. architectural . . . . . . . . . . . . . 24 For further information . . . . . . . . 26 Arch architecture

223

Physical Separation and Multiphase  

E-Print Network [OSTI]

- research into CVD and HVOF coatings for subsea choke valve applications. s US Navy - understanding the processes of charge generation in gear contacts as a predictive maintenance tool. s DRA/UoS - corrosion

Sóbester, András

224

E-Print Network 3.0 - attached chinese hamster Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

uranium; V79, Chinese hamster lung cells; DU-UO2NO3 depleted uranium... - tial for DU as uranyl nitrate to induce mutations and cell trans- formation in Chinese hamster lung... in...

225

TO  

Office of Legacy Management (LM)

Chemical 42-17, Grade A. It is not presently known whether the code number refers to the uranyl nitrate which was originally ordered or tc the UO3 which was actually reoeived....

226

A density functional study of actinyl containing complexes.  

E-Print Network [OSTI]

??Density functional (DFT) methods are first used to study 22 of the most stable solution-phase UN4O12 isomers containing uranyl nitrate, UO2(NO3)2. Based on relative free… (more)

Berard, Joel J.

2008-01-01T23:59:59.000Z

227

Whole-genome transcriptional analysis of heavy metal stresses in Caulobacter crescentus  

E-Print Network [OSTI]

A concentration of 200 ?M uranyl nitrate was used forthe exception of the uranyl nitrate stock solution which wasK 2 Cr 2 O 7 ) and uranyl nitrate (UO 2 (NO 3 ) 2 ·6H 2 O).

Hu, Ping; Brodie, Eoin L.; Suzuki, Yohey; McAdams, Harley H.; Andersen, Gary L.

2005-01-01T23:59:59.000Z

228

DOE - Office of Legacy Management -- University of California...  

Office of Legacy Management (LM)

Subject: List of California Sites; May 17, 1989 CA.05-3 - AEC Memorandum; Ball to Smith; Subject: 500 Pounds UO3 - SR-1952; July 10, 1951 CA.05-4 - AEC Memorandum; Blatzs to...

229

Identification and Characterization of UndA-HRCR-6, an Outer...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

MR-1 mutant’s ability to reduce solid phase ferrihydrite at 40% of that for MR-1 wild type, (ii) increased extracellular formation of UO2 associated with the outer membrane...

230

Electronic structure and ionicity of actinide oxides from first principles L. Petit,1,2,* A. Svane,1 Z. Szotek,2 W. M. Temmerman,2 and G. M. Stocks3  

E-Print Network [OSTI]

. A mixture of UO2 and PuO2, where Pu is blended with either natural or depleted uranium, constitutes. INTRODUCTION Actinide oxides play a dominant role in the nuclear fuel cycle.1 For many years, uranium dioxide

Svane, Axel Torstein

231

Pacific Northwest Solar Radiation Data  

E-Print Network [OSTI]

Pacific Northwest Solar Radiation Data UO SOLAR MONITORING LAB Physics Department -- Solar Energy Center 1274 University of Oregon Eugene, Oregon 97403-1274 April 1, 1999 #12;Hourly solar radiation data

Oregon, University of

232

STEPS: A Grid Search Methodology for Optimized Peptide Identification Filtering of MS/MS Database Search Results  

SciTech Connect (OSTI)

For bottom-up proteomics there are a wide variety of database searching algorithms in use for matching peptide sequences to tandem MS spectra. Likewise, there are numerous strategies being employed to produce a confident list of peptide identifications from the different search algorithm outputs. Here we introduce a grid search approach for determining optimal database filtering criteria in shotgun proteomics data analyses that is easily adaptable to any search. Systematic Trial and Error Parameter Selection - referred to as STEPS - utilizes user-defined parameter ranges to test a wide array of parameter combinations to arrive at an optimal "parameter set" for data filtering, thus maximizing confident identifications. The benefits of this approach in terms of numbers of true positive identifications are demonstrated using datasets derived from immunoaffinity-depleted blood serum and a bacterial cell lysate, two common proteomics sample types.

Piehowski, Paul D.; Petyuk, Vladislav A.; Sandoval, John D.; Burnum, Kristin E.; Kiebel, Gary R.; Monroe, Matthew E.; Anderson, Gordon A.; Camp, David G.; Smith, Richard D.

2013-03-01T23:59:59.000Z

233

Discovery of novel glucose-regulated proteins in isolated human pancreatic islets using LC-MS/MS-based proteomics  

SciTech Connect (OSTI)

The prevalence of diabetes mellitus is increasing dramatically throughout the world, and the disease has become a major public health issue. The most common form of the disease, type 2 diabetes, is due in part to insufficient insulin production from the pancreatic beta-cell. Since glucose is the most potent and physiologically important regulators of beta-cell function under physiological conditions, understanding the insulin secretory defect underlying type 2 diabetes requires a better understanding of glucose regulation of beta-cell function. To this aim, a bottom-up LC-MS/MS-based proteomics approach was used to profile pooled islets from multiple donors under basal (5 mM) or high (15 mM) glucose conditions. Our analysis discovered 256 differentially abundant proteins ({approx}p < 0.05) after 24 h of high glucose exposure from more than 4500 identified in total. Several novel glucose-regulated proteins were elevated under high glucose conditions, including regulators of mRNA splicing (Pleiotropic regulator 1), processing (Retinoblastoma binding protein 6), and function (Nuclear RNA export factor 1), in addition to Neuron navigator 1 and Plasminogen activator inhibitor 1. Proteins whose abundances markedly decreased during incubation at 15 mM glucose included Bax inhibitor 1 and Synaptotagmin-17. Many proteins found to be differentially abundant after high glucose stimulation were uncharacterized or hypothetical. These findings expand our knowledge of glucose regulation of the human islet proteome and suggest many hitherto unknown responses to glucose that require additional studies to explore novel functional roles.

Rutledge, Alexandra C.; Fontes, Ghislaine; Gritsenko, Marina A.; Norbeck, Angela D.; Anderson, David J.; Waters, Katrina M.; Adkins, Joshua N.; Smith, Richard D.; Poitout, Vincent; Metz, Thomas O.

2012-07-06T23:59:59.000Z

234

Variables and units in Ocean 420 u zonal velocity (east-west) m/s  

E-Print Network [OSTI]

speed m/s Cg group velocity m/s k wave number 1/m frequency 1/s wavelength m T period s kinematic mixed-layer and water below C E Energy density in surface gravity wave J/m 2 #12;Some constants k Von surface height m g gravitational constant m/s 2 a amplitude of wave in sea surface height m f Coriolis

Thompson, LuAnne

235

Application of Printed Circuit Board Technology to FT-ICR MS...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

to FT-ICR MS Analyzer Cell Construction and Prototyping. Abstract: Although Fourier transform ion cyclotron resonance mass spectrometry (FT-ICRMS) remains themass spectrometry...

236

Improved Quality Control Processing of Peptide-centric LC-MS...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

measures), LC-MS analyses with poor quality pep-tide abundance data can bias downstream statistical analyses and hence the biological interpretation for an otherwise high...

237

E-Print Network 3.0 - allison ms fache Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

and Medicine 80 GOVERNMENT FUNDING FOR ADVANCED TECHNOLOGY, A GUIDE TO APPLYING FOR GOVERNMENT GRANTS Summary: improved recovery projects in the petroleum industry. Ms....

238

E-Print Network 3.0 - assisted maldi-tof-ms estudo Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

desorption... spectrometry (MALDI-TOF MS). Pure peptides were finally subjected to Edman degradation. All HPLC purifications... 600S, and a UV detector model 486. MALDI-TOF ......

239

Ms. Elizabeth Withers, EIS Document Manager U.S. Department of...  

National Nuclear Security Administration (NNSA)

August 14, 2002 Ms. Elizabeth Withers, EIS Document Manager U.S. Department of Energy (DOE), National Nuclear Security Administration (NNSA) Office of Los Alamos Site Operations...

240

Apply for the OIA Undergraduate Scholarship 1. Your name Mr. Miss, Ms., Mrs.  

E-Print Network [OSTI]

Apply for the OIA Undergraduate Scholarship 1. Your name Mr. Miss, Ms., Mrs. Family Name (as of birth (country): ____________________________________________ Page 1 of 3 You are eligible

Rock, Chris

Note: This page contains sample records for the topic "ms uo uo" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

E-Print Network 3.0 - aggressive ms successfully Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Explorit Topic List Advanced Search Sample search results for: aggressive ms successfully Page: << < 1 2 3 4 5 > >> 1 Brad J. Bushman University of Michigan & VU University...

242

Computational evaluation of two reactor benchmark problems  

E-Print Network [OSTI]

benchmark problem . . . Fig. 2. Layouts of assembly types B and C Fig. 3. Core diagram/layout for the NEA WPPR benchmark problem . . . Fig. 4. Layouts of UOz and MOX assemblies Fig. 5. Core A effective multiplication factor. Fig. 6. Core B effective... by rod peaking factors for the MOX assembly. . . . . . . . . . . . . Fig. 12 Rod by rod peaking factors for the middle UO. assembly . . . Fig. 13. Rod by rod peaking factors for the corner UO assembly. . . . . . 30 . . . . . 3 1 . . . . . 32 Fig. 14...

Cowan, James Anthony

2012-06-07T23:59:59.000Z

243

Thermodynamics of Uranyl Minerals: Enthalpies of Formation of Uranyl Oxide Hydrates  

SciTech Connect (OSTI)

The enthalpies of formation of seven uranyl oxide hydrate phases and one uranate have been determined using high-temperature oxide melt solution calorimetry: [(UO{sub 2}){sub 4}O(OH){sub 6}](H{sub 2}O){sub 5}, metaschoepite; {beta}-UO{sub 2}(OH){sub 2}; CaUO{sub 4}; Ca(UO{sub 2}){sub 6}O{sub 4}(OH){sub 6}(H{sub 2}O){sub 8}, becquerelite; Ca(UO{sub 2}){sub 4}O{sub 3}(OH){sub 4}(H{sub 2}O){sub 2}; Na(UO{sub 2})O(OH), clarkeite; Na{sub 2}(UO{sub 2}){sub 6}O{sub 4}(OH){sub 6}(H{sub 2}O){sub 7}, the sodium analogue of compreignacite and Pb{sub 3}(UO{sub 2}){sub 8}O{sub 8}(OH){sub 6}(H{sub 2}O){sub 2}, curite. The enthalpy of formation from the binary oxides, {Delta}H{sub f-ox}, at 298 K was calculated for each compound from the respective drop solution enthalpy, {Delta}H{sub ds}. The standard enthalpies of formation from the elements, {Delta}H{sub f}{sup o}, at 298 K are -1791.0 {+-} 3.2, -1536.2 {+-} 2.8, -2002.0 {+-} 3.2, -11389.2 {+-} 13.5, -6653.1 {+-} 13.8, -1724.7 {+-} 5.1, -10936.4 {+-} 14.5 and -13163.2 {+-} 34.4 kJ mol{sup -1}, respectively. These values are useful in exploring the stability of uranyl oxide hydrates in auxiliary chemical systems, such as those expected in U-contaminated environments.

K. Kubatko; K. Helean; A. Navrotsky; P.C. Burns

2005-05-11T23:59:59.000Z

244

Fundamental study on recovery uranium oxide from HEPA filters  

SciTech Connect (OSTI)

Large numbers of spent HEPA filters are produced at uranium fuel fabrication facilities. Uranium oxide particles have been collected on these filters. Then, a spent HEPA filter treatment system was developed from the viewpoint of recovering the UO{sub 2} and minimizing the volume. The system consists of a mechanical separation process and a chemical dissolution process. This paper describes the results of fundamental experiments on recovering UO{sub 2} from HEPA filters.

Izumida, T. [Hitachi Ltd., Ibaraki (Japan). Hitachi Works; Matsumoto, H.; Tsuchiya, H.; Iba, H. [Hitachi Nuclear Engineering Co., Ltd., Ibaraki (Japan); Noguchi, Y. [Radioactive Waste Management Center, Tokyo (Japan)

1993-12-31T23:59:59.000Z

245

Infrared Spectroscopy of Discrete Uranyl Anion Complexes  

SciTech Connect (OSTI)

The Free-Electron Laser for Infrared Experiments, FELIX, was used to study the wavelength-resolved multiphoton dissociation of discrete, gas phase uranyl (UO22+) complexes containing a single anionic ligand (A), with or without ligated solvent molecules (S). The apparent uranyl antisymmetric and symmetric stretching frequencies were measured for complexes with general formula [UO2A(S)n]+, where A was either hydroxide, methoxide or acetate, S was water, ammonia, acetone or acetonitrile, and n = 0-2. The values for the antisymmetric stretching frequency for uranyl ligated with only an anion ([UO2A]+) were as low or lower than measurements for [UO2]2+ ligated with as many as five strong neutral donor ligands, and are comparable to solution phase values. This result was surprising because initial DFT calculations using B3LYP predicted values that were 30 – 40 cm-1 higher, consistent with intuition but not with the data. Modification of the basis set and use of alternative functionals improved computational accuracy for the methoxide and acetate complexes, but calculated values for the hydroxide were greater than the measurement regardless of the computational method used. Attachment of a neutral donor ligand S to [UO2A]+ produced [UO2AS]+, which resulted only very modest changes to the uranyl frequency, and did not universally shift values lower. DFT calculations for [UO2AS]+ were in accord with trends in the data, and showed that attachment of the solvent was accommodated by weakening of the U-anion bond as well as the uranyl. When uranyl frequencies were compared for [UO2AS]+ species having different solvent neutrals, values decreased with increasing neutral nucleophilicity.

Gary S. Groenewold; Anita K. Gianotto; Michael E. McIlwain; Michael J. Van Stipdonk; Michael Kullman; Travis J. Cooper; David T. Moore; Nick Polfer; Jos Oomens; Ivan Infante; Lucas Visscher; Bertrand Siboulet; Wibe A. de Jong

2007-12-01T23:59:59.000Z

246

Infared Spectroscopy of Discrete Uranyl Anion Complexes  

SciTech Connect (OSTI)

The Free-Electron Laser for Infrared Experiments (FELIX) w 1 as used to study the wavelength-resolved multiple photon photodissociation of discrete, gas phase uranyl (UO2 2 2+) complexes containing a single anionic ligand (A), with or without ligated solvent molecules (S). The uranyl antisymmetric and symmetric stretching frequencies were measured for complexes with general formula [UO2A(S)n]+, where A was either hydroxide, methoxide, or acetate; S was water, ammonia, acetone, or acetonitrile; and n = 0-3. The values for the antisymmetric stretching frequency for uranyl ligated with only an anion ([UO2A]+) were as low or lower than measurements for [UO2]2+ ligated with as many as five strong neutral donor ligands, and are comparable to solution phase values. This result was surprising because initial DFT calculations predicted values that were 30–40 cm-1 higher, consistent with intuition but not with the data. Modification of the basis sets and use of alternative functionals improved computational accuracy for the methoxide and acetate complexes, but calculated values for the hydroxide were greater than the measurement regardless of the computational method used. Attachment of a neutral donor ligand S to [UO2A]+ produced [UO2AS]+, which produced only very modest changes to the uranyl antisymmetric stretch frequency, and did not universally shift the frequency to lower values. DFT calculations for [UO2AS]+ were in accord with trends in the data, and showed that attachment of the solvent was accommodated by weakening of the U-anion bond as well as the uranyl. When uranyl frequencies were compared for [UO2AS]+ species having different solvent neutrals, values decreased with increasing neutral nucleophilicity.

Groenewold, G. S.; Gianotto, Anita K.; McIIwain, Michael E.; Van Stipdonk, Michael J.; Kullman, Michael; Moore, David T.; Polfer, Nick; Oomens, Jos; Infante, Ivan A.; Visscher, Lucas; Siboulet, Bertrand; De Jong, Wibe A.

2008-01-24T23:59:59.000Z

247

P a g e | 1 Regional Ocean Modelling  

E-Print Network [OSTI]

(external data). #12;P a g e | 4 Slide 4: Flather Condition for Shallow-Water Barotropic Flow: h/t = -Hu/x u-running) characteristic for uo-c subcritical flows. Thus, either we set "u - (g/H)1/2 h + (g/H)1/2 h for uo+c >0 always for subcritical flows. This characteristic is determined as part

248

Advanced Proliferation Resistant, Lower Cost, Uranium-Thorium Dioxide Fuels for Light Water Reactors (Progress report for work through June 2002, 12th quarterly report)  

SciTech Connect (OSTI)

The overall objective of this NERI project is to evaluate the potential advantages and disadvantages of an optimized thorium-uranium dioxide (ThO2/UO2) fuel design for light water reactors (LWRs). The project is led by the Idaho National Engineering and Environmental Laboratory (INEEL), with the collaboration of three universities, the University of Florida, Massachusetts Institute of Technology (MIT), and Purdue University; Argonne National Laboratory; and all of the Pressurized Water Reactor (PWR) fuel vendors in the United States (Framatome, Siemens, and Westinghouse). In addition, a number of researchers at the Korean Atomic Energy Research Institute and Professor Kwangheon Park at Kyunghee University are active collaborators with Korean Ministry of Science and Technology funding. The project has been organized into five tasks: · Task 1 consists of fuel cycle neutronics and economics analysis to determine the economic viability of various ThO2/UO2 fuel designs in PWRs, · Task 2 will determine whether or not ThO2/UO2 fuel can be manufactured economically, · Task 3 will evaluate the behavior of ThO2/UO2 fuel during normal, off-normal, and accident conditions and compare the results with the results of previous UO2 fuel evaluations and U.S. Nuclear Regulatory Commission (NRC) licensing standards, · Task 4 will determine the long-term stability of ThO2/UO2 high-level waste, and · Task 5 consists of the Korean work on core design, fuel performance analysis, and xenon diffusivity measurements.

Mac Donald, Philip Elsworth

2002-09-01T23:59:59.000Z

249

Free energies and mechanisms of water exchange around Uranyl from first principles molecular dynamics  

SciTech Connect (OSTI)

From density functional theory (DFT) based ab initio (Car-Parrinello) metadynamics, we compute the activation energies and mechanisms of water exchange between the first and second hydration shells of aqueous Uranyl (UO{sub 2}{sup 2+}) using the primary hydration number of U as the reaction coordinate. The free energy and activation barrier of the water dissociation reaction [UO{sub 2}(OH{sub 2}){sub 5}]{sup 2+}(aq) {yields} [UO{sub 2}(OH{sub 2})4]{sup 2+}(aq) + H{sub 2}O are 0.7 kcal and 4.7 kcal/mol respectively. The free energy is in good agreement with previous theoretical (-2.7 to +1.2 kcal/mol) and experimental (0.5 to 2.2 kcal/mol) data. The associative reaction [UO{sub 2}(OH{sub 2}){sub 5}]{sup 2+}(aq) + H{sub 2}O {yields} [UO{sub 2}(OH{sub 2})6]{sup 2+}(aq) is short-lived with a free energy and activation barrier of +7.9 kcal/mol and +8.9 kca/mol respectively; it is therefore classified as associative-interchange. On the basis of the free energy differences and activation barriers, we predict that the dominant exchange mechanism between [UO{sub 2}(OH{sub 2}){sub 5}]{sup 2+}(aq) and bulk water is dissociative.

Atta-Fynn, Raymond; Bylaska, Eric J.; De Jong, Wibe A.

2012-02-01T23:59:59.000Z

250

Using Entrez Utilities Web Service with Visual Basic and MS Visual Studio 2008  

E-Print Network [OSTI]

Using Entrez Utilities Web Service with Visual Basic and MS Visual Studio 2008 Entrez Utilities Web to create a Visual Basic project to access the NCBI Entrez Utilities Web Service using MS Visual Studio 2005.wsdl or path to local file (for example, C: \\SOAP\\eUtils\\v2.0\\eutils.wsdl) if you downloaded eUtils WSDL

Levin, Judith G.

251

HPTLC/DESI-MS Imaging of Tryptic Protein Digests Separated in Two Dimensions  

SciTech Connect (OSTI)

Desorption electrospray ionization mass spectrometry (DESI-MS) was demonstrated as a method to detect and identify peptides from two-dimensional separations of cytochrome c and myoglobin tryptic digests on ProteoChrom HPTLC Cellulose sheets. Data-dependent tandem mass spectra were acquired during lane scans across the TLC plates. Peptides and the corresponding proteins were identified using a protein database search software. Two-dimensional distributions of identified peptides were mapped for each separated protein digest. Sequence coverages for cytochrome c and myoglobin were 81% and 74%, respectively. These compared well to those determined using the more standard HPLC/ESI-MS/MS approach (89% and 84%, respectively). Preliminary results show that use of more sensitive instrumentation has the potential for improved detection of peptides with low Rf values and improvement in sequence coverage. However, less multiple charging and more sodiation were seen in HPTLC/DESI-MS spectra relative to HPLC/ESI-MS spectra, which can affect peptide identification by MS/MS. Methods to increase multiple charging and reduce the extent of sodiation are currently under investigation.

Pasilis, Sofie P [ORNL; Kertesz, Vilmos [ORNL; Van Berkel, Gary J [ORNL; Schulz, Michael [Merck Research Laboratories; Schorcht, Susanne [Merck Research Laboratories

2008-01-01T23:59:59.000Z

252

Updated 7-12 Ms. Markowich is currently the Director of the Battlespace Simulation Department (AIR-5.4) at  

E-Print Network [OSTI]

and complete adequate testing to demonstrate suitable and effective operations in the joint battlespace. Ms and simulation in a Battlespace environment. Ms. Markowich is the Department of Navy Modeling and Simulation and unmanned partnerships across the Navy and Joint Services. Ms. Markowich previously served as the Deputy

253

FREEWAY PERFORMANCE MEASUREMENT SYSTEM (PeMS): AN OPERATIONAL ANALYSIS TOOL  

E-Print Network [OSTI]

and calibrate simulation models. The paper describes the use of PeMS in conducting operational analysis from case studies on conducting freeway operational analyses, bottleneck identification, Level and researchers in conducting freeway operational analyses, bottleneck identification, determining the Level

Varaiya, Pravin

254

Course: M.S. in Library and Information Science Test Code: PLA (Forenoon) Duration: 2 hours  

E-Print Network [OSTI]

Course: M.S. in Library and Information Science Test Code: PLA (Forenoon) Duration: 2 hours Science)-2013 Sub: Library & Information Science Test Code: PLA Duration: 2 hours 1) If p/q = 33 what

Bandyopadhyay, Antar

255

Daniel A. Goldstein 501 Campbell Hall #3411 1 Cyclotron Road MS 50B-4206  

E-Print Network [OSTI]

Daniel A. Goldstein 501 Campbell Hall #3411 1 Cyclotron Road MS 50B-4206 Department of Astronomy., Brown, P.J., Finley, D. A., Fischer, J., Goldstein, D., et al. DES13S2cmm: The First Superluminous

Backer, Don

256

5 year BS/MS Accelerated Physics Program Requirements and other important information.  

E-Print Network [OSTI]

5 year BS/MS Accelerated Physics Program Requirements and other important information. Overall GPA the Graduate School accelerated program application online application and include Statement of purpose Two

Crawford, T. Daniel

257

Revised 1/9/2009 MS&E Doctoral Candidacy Form  

E-Print Network [OSTI]

: ___________________________________________ SU ID_________________ Name of Tutorial/Paper Advisors (two required&E 221 or STAT 217 or approved substitution_________________ Grade/Waiver_____ MS&E 223 or 323 or STAT

Prinz, Friedrich B.

258

TEXTS OF EMPOWERMENT: A FUNCTIONAL RHETORICAL ANALYSIS OF MS. MAGAZINE IN THE FIRST FIVE YEARS  

E-Print Network [OSTI]

Ms. was the first mass mediated feminist magazine in the United States and has often been identified as an icon of the feminist movement. This study examines three rhetorical sites in the magazine during the first five ...

Partlow Lefevre, Sarah Taylor

2009-07-21T23:59:59.000Z

259

E-Print Network 3.0 - australian ms patients Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

by Explorit Topic List Advanced Search Sample search results for: australian ms patients Page: << < 1 2 3 4 5 > >> 1 Annals of Oncology 5: 199-204, 1994. O 1994 Kluwer Academic...

260

Automated Liquid Microjunction Surface Sampling-HPLC-MS/MS Analysis of Drugs and Metabolites in Whole-Body Thin Tissue Sections  

SciTech Connect (OSTI)

A fully automated liquid extraction-based surface sampling system utilizing a commercially available autosampler coupled to high performance liquid chromatography-tandem mass spectrometry (HPLC-MS/MS) detection is reported. Discrete spots selected for droplet-based sampling and automated sample queue generation for both the autosampler and MS were enabled by using in-house developed software. In addition, co-registration of spatially resolved sampling position and HPLC-MS information to generate heatmaps of compounds monitored for subsequent data analysis was also available in the software. The system was evaluated with whole-body thin tissue sections from propranolol dosed rat. The hands-free operation of the system was demonstrated by creating heatmaps of the parent drug and its hydroxypropranolol glucuronide metabolites with 1 mm resolution in the areas of interest. The sample throughput was approximately 5 min/sample defined by the time needed for chromatographic separation. The spatial distributions of both the drug and its metabolites were consistent with previous studies employing other liquid extraction-based surface sampling methodologies.

Kertesz, Vilmos [ORNL; Van Berkel, Gary J [ORNL

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "ms uo uo" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

SNRE MS and MLA Career Information From 2008-2009 the School of Natural Resources and Environment graduated 84 MS and MLA students.  

E-Print Network [OSTI]

Corps (Protected Areas Management Advisor) USDA Forest Service Sierra National Forest (Natural Resource (Research Assistant) Matthaei Botanical Gardens and Nichols Arboretum (Natural Areas Manager) Michigan StateSNRE MS and MLA Career Information From 2008-2009 the School of Natural Resources and Environment

Edwards, Paul N.

262

Potential incorporation of transuranics into uranium phases  

SciTech Connect (OSTI)

The UO{sub 2} in spent nuclear fuel is unstable under moist oxidizing conditions and will be altered to uranyl oxide hydrate phases. The transuranics released during the corrosion of spent fuel may also be incorporated into the structures of secondary U{sup 6+} phases. The incorporation of radionuclides into alteration products will affect their mobility. A series of precipitation tests were conducted at either 150 or 90 C for seven days to determine the potential incorporation of Ce{sup 4+} and Nd{sup 3+} (surrogates for Pu{sup 4+} and Am{sup 3+}, respectively) into uranium phases. Ianthinite ([U{sub 2}{sup 4+}(UO{sub 2}){sub 4}O{sub 6}(OH){sub 4}(H{sub 2}O){sub 4}](H{sub 2}O){sub 5}) was produced by dissolving uranium oxyacetate in a solution containing copper acetate monohydrate as a reductant. The leachant used in these tests were doped with either 2.1 ppm cerium or 399 ppm neodymium. Inductively coupled plasma-mass spectrometer (ICP-MS) analysis of the solid phase reaction products which were dissolved in a HNO{sub 3} solution indicates that about 306 ppm Ce (K{sub d} = 146) was incorporated into ianthinite, while neodymium contents were much higher, being approximately 24,800 ppm (K{sub d} = 62). Solid phase examinations using an analytical transmission electron microscope/electron energy-loss spectrometer (AEM/EELS) indicate a uniform distribution of Nd, while Ce contents were below detection. Becquerelite (Ca[(UO{sub 2}){sub 6}O{sub 4}(OH){sub 6}]{center_dot}8H{sub 2}O) was produced by dissolving uranium oxyacetate in a solution containing calcium acetate. The leachant in these tests was doped with either 2.1 ppm cerium or 277 ppm neodymium. ICP-MS results indicate that about 33 ppm Ce (K{sub d}=16) was incorporated into becquerelite, while neodymium contents were higher, being approximately 1,300 ppm (K{sub d}=5). Homogeneous distribution of Nd in the solid phase was noted during AEM/EELS examination, and Ce contents were also below detection.

Kim, C. W.; Wronkiewicz, D. J.; Buck, E. C.

1999-12-07T23:59:59.000Z

263

REACTIVITY INITIATED ACCIDENT TEST SERIES TEST RIA 1-4 EXPERIMENT PREDICTIONS  

SciTech Connect (OSTI)

The results of the pretest analyses for Test RIA 1-4 are presented. Test RIA 1-4 consists of a 3x3 array of previously irradiated MAP! fuel rods. The rods have 5.7% enriched UO{sub 2} fuel in zircaloy-4 cladding with an average burnup of 5300 MWd/t. The objective for Test RIA 1-4 is to provide information regarding loss-of-coolable fuel rod geometry following RIA event for a radial-average peak fuel enthalpy equivalent to the present licensing criteria of 1172 J/g (280 cal/g UO{sub 2}). Radial averaged peak fuel enthalpies of 1172 J/g (280 cal/g) 1077 J/g {257 cal/g), and 978 J/g (234 cal/g) for the corner, side, and center fuel rods, respectively, are planned to be achieved during a 2.7 ms reactor period power burst. The results of the FRAP-T5 analyses indicate that all nine rods will fail within 26 ms from the start of the power burst due to pellet-cladding mechanical interaction. All of the rods will undergo partial fuel melting. All rods will operate under extended film boiling (>30 sec) conditions and about 70% of the cladding length is expected to be molten. Approximately 15% of the cladding thickness will be oxided. Fuel swelling due to fission gas release and melting combined with fuel and cladding fragmentation, will probably produce a complete coolant flow blockage within the flow shroud.

Fukuda, S. K.; Martinson, Z. R.

1980-02-01T23:59:59.000Z

264

ANALYSIS OF SULFONATES IN AQUEOUS SAMPLES BY ION-PAIR LC/ESI-MS/MS WITH IN-SOURCE CID FOR ADDUCT PEAK ELIMINATION  

SciTech Connect (OSTI)

Determination of low-molecular-weight organic sulfonates (e.g. taurine and cysteic acid) in aqueous solutions is important in many applications of biological, environmental and pharmaceutical sciences. These compounds are difficult to be determined by commonly used reversed-phase liquid chromatographic separation combined with UV-Visible detection because of their high solubility and the lack chromophoric moieties. Here the authors report a method combining ion-pair liquid chromatography and electrospray ionization tandem mass spectrometry (IPLC/ESI-MS/MS)for determining sulfonates. The ability of low-molecular-weight sulfonates to form ion-pairs with quaternary ammonium cations in aqueous solutions allowed LC separation with a C{sub 18} column. Detection of the sulfonates was accomplished with ESI-MS that lends a universal mode of mass detection for polar, water soluble compounds. An in-source collision induced dissociation (CID) was applied to eliminate the adduct peaks in mass spectra. Characteristic marker ions showed in the second stage mass spectra lent a method for identifying sulfonates.

OUYANG,S.; VAIRAVAMURTHY,M.A.

1999-06-13T23:59:59.000Z

265

Exploring the in vitro formation of trimethylarsine sulfide from dimethylthioarsinic acid in anaerobic microflora of mouse cecum using HPLC-ICP-MS and HPLC-ESI-MS  

SciTech Connect (OSTI)

Although metabolism of arsenicals to form methylated oxoarsenical species has been extensively studied, less is known about the formation of thiolated arsenical species that have recently been detected as urinary metabolites. Indeed, their presence suggests that the metabolism of ingested arsenic is more complex than previously thought. Recent reports have shown that thiolated arsenicals can be produced by the anaerobic microflora of the mouse cecum, suggesting that metabolism prior to systemic absorption may be a significant determinant of the pattern and extent of exposure to various arsenic-containing species. Here, we examined the metabolism of {sup 34}S labeled dimethylthioarsinic acid ({sup 34}S-DMTA{sup V}) by the anaerobic microflora of the mouse cecum using HPLC-ICP-MS and HPLC-ESI-MS/MS to monitor for the presence of various oxo- and thioarsenicals. The use of isotopically enriched {sup 34}S-DMTA{sup V} made it possible to differentiate among potential metabolic pathways for production of the trimethylarsine sulfide (TMAS{sup V}). Upon in vitro incubation in an assay containing anaerobic microflora of mouse cecum, {sup 34}S-DMTA{sup V} underwent several transformations. Labile {sup 34}S was exchanged with more abundant {sup 32}S to produce {sup 32}S-DMTA{sup V}, a thiol group was added to yield DMDTA{sup V}, and a methyl group was added to yield {sup 34}S-TMAS{sup V}. Because incubation of {sup 34}S-DMTA{sup V} resulted in the formation of {sup 34}S-TMAS{sup V}, the pathway for its formation must preserve the arsenic-sulfur bond. The alternative metabolic pathway postulated for formation of TMAS{sup V} from dimethylarsinic acid (DMA{sup V}) would proceed via a dimethylarsinous acid (DMA{sup III}) intermediate and would necessitate the loss of {sup 34}S label. Structural confirmation of the metabolic product was achieved using HPLC-ESI-MS/MS. The data presented support the direct methylation of DMTA{sup V} to TMAS{sup V}. Additionally, the detection of isotopically pure {sup 34}S-TMAS{sup V} raises questions about the sulfur exchange properties of TMAS{sup V} in the cecum material. Therefore, {sup 34}S-TMAS{sup V} was incubated and the exchange was monitored with respect to time. The data suggest that the As-S bond associated with TMAS{sup V} is less labile than the As-S bond associated with DMTA{sup V}.

Kubachka, Kevin M. [US EPA, ORD, NERL, Microbiological and Chemical Exposure, Assessment Research Division, Cincinnati, OH 45268 (United States); Kohan, Michael C. [US EPA, ORD, NHEERL, Environmental Carcinogenesis Division, Research Triangle Park, NC 27711 (United States); Herbin-Davis, Karen [US EPA, ORD, NHEERL, Experimental Toxicology Division, Research Triangle Park, NC 27711 (United States); Creed, John T. [US EPA, ORD, NERL, Microbiological and Chemical Exposure, Assessment Research Division, Cincinnati, OH 45268 (United States)], E-mail: creed.jack@epa.gov; Thomas, David J. [US EPA, ORD, NHEERL, Experimental Toxicology Division, Research Triangle Park, NC 27711 (United States)

2009-09-01T23:59:59.000Z

266

{sup 99}Tc bioassay by inductively coupled plasma mass spectrometry (ICP-MS)  

SciTech Connect (OSTI)

A means of analyzing {sup 99}Tc in urine by inductively coupled plasma mass spectrometry (ICP-MS) has been developed. Historically, {sup 99}Tc analysis was based on the radiometric detection of the 293 keV E{sub Max} beta decay product by liquid scintillation or gas flow proportional counting. In a urine matrix, the analysis of{sup 99}Tc is plagued with many difficulties using conventional radiometric methods. Difficulties originate during chemical separation due to the volatile nature of Tc{sub 2}O{sub 7} or during radiation detection due to color or chemical quenching. A separation scheme for {sup 99}Tc detection by ICP-MS is given and is proven to be a sensitive and robust analytical alternative. A comparison of methods using radiometric and mass quantitation of {sup 99}Tc has been conducted in water, artificial urine, and real urine matrices at activity levels between 700 and 2,200 dpm/L. Liquid scintillation results based on an external standard quench correction and a quench curve correction method are compared to results obtained by ICP-MS. Each method produced accurate results, however the precision of the ICP-MS results is superior to that of liquid scintillation results. Limits of detection (LOD) for ICP-MS and liquid scintillation detection are 14.67 and 203.4 dpm/L, respectively, in a real urine matrix. In order to determine the basis for the increased precision of the ICP-MS results, the detection sensitivity for each method is derived and measured. The detection sensitivity for the {sup 99}Tc isotope by ICP-MS is 2.175 x 10{sup {minus}7} {+-} 8.990 x 10{sup {minus}9} and by liquid scintillation is 7.434 x 10{sup {minus}14} {+-} 7.461 x 10{sup {minus}15}. A difference by seven orders of magnitude between the two detection systems allows ICP-MS samples to be analyzed for a period of 15 s compared to 3,600 s by liquid scintillation counting with a lower LOD.

Lewis, L.A.

1998-05-01T23:59:59.000Z

267

The burnup dependence of light water reactor spent fuel oxidation  

SciTech Connect (OSTI)

Over the temperature range of interest for dry storage or for placement of spent fuel in a permanent repository under the conditions now being considered, UO{sub 2} is thermodynamically unstable with respect to oxidation to higher oxides. The multiple valence states of uranium allow for the accommodation of interstitial oxygen atoms in the fuel matrix. A variety of stoichiometric and nonstoichiometric phases is therefore possible as the fuel oxidizers from UO{sub 2} to higher oxides. The oxidation of UO{sub 2} has been studied extensively for over 40 years. It has been shown that spent fuel and unirradiated UO{sub 2} oxidize via different mechanisms and at different rates. The oxidation of LWR spent fuel from UO{sub 2} to UO{sub 2.4} was studied previously and is reasonably well understood. The study presented here was initiated to determine the mechanism and rate of oxidation from UO{sub 2.4} to higher oxides. During the early stages of this work, a large variability in the oxidation behavior of samples oxidized under nearly identical conditions was found. Based on previous work on the effect of dopants on UO{sub 2} oxidation and this initial variability, it was hypothesized that the substitution of fission product and actinide impurities for uranium atoms in the spent fuel matrix was the cause of the variable oxidation behavior. Since the impurity concentration is roughly proportional to the burnup of a specimen, the oxidation behavior of spent fuel was expected to be a function of both temperature and burnup. This report (1) summarizes the previous oxidation work for both unirradiated UO{sub 2} and spent fuel (Section 2.2) and presents the theoretical basis for the burnup (i.e., impurity concentration) dependence of the rate of oxidation (Sections 2.3, 2.4, and 2.5), (2) describes the experimental approach (Section 3) and results (Section 4) for the current oxidation tests on spent fuel, and (3) establishes a simple model to determine the activation energies associated with spent fuel oxidation (Section 5).

Hanson, B.D.

1998-07-01T23:59:59.000Z

268

Measurement of lithium isotope ratios by quadrupole-ICP-MS: application to seawater and natural carbonates  

E-Print Network [OSTI]

Measurement of lithium isotope ratios by quadrupole-ICP-MS: application to seawater and natural method for lithium isotope ratio (7 Li/6 Li) determinations with low total lithium consumption ( lithium from all matrix elements using small volume resin (2 ml/3.4 meq AG 50W-X8) and low volume elution

Weston, Ken

269

EB2012-MS-43 ADVANCES IN THE MODELLING OF CARBON/CARBON  

E-Print Network [OSTI]

, the Carbon-Carbon composites (C/C) are materials frequently used in industrial applications such as planeEB2012-MS-43 ADVANCES IN THE MODELLING OF CARBON/CARBON COMPOSITE UNDER TRIBOLOGICAL CONSTRAINTS 1, homogenization, carbon ABSTRACT Thermo mechanical properties of Carbon-Carbon composite (C/C) allow them

Paris-Sud XI, Université de

270

Aerospace Engineering Aircraft and Spacecraft Design BS, MS Space Transportation and Exploration  

E-Print Network [OSTI]

and Systems Engineering Management Engineering Healthcare Industrial Engineering BS, MS, MSE Human Factors-924-3190 www.engr.sjsu.edu/avtech Department office located in Industrial Studies 111 Biomedical Engineering.sjsu.edu Industrial and Systems Engineering 408-924-3301 www.ise.sjsu.edu Industrial Technology 408-924-3190 www

Su, Xiao

271

KooPeratIonsProGraMMe CooPeratIon ProGraMs03  

E-Print Network [OSTI]

und Innovation haben die Max-Planck-Gesellschaft und die Fraunhofer-Gesellschaft ihre Kooperationen for Research and Innovation, the Max Planck Society and Fraunhofer-Gesellschaft intend to continue50 KooPeratIonsProGraMMe CooPeratIon ProGraMs03 Kooperationen mit der Fraunhofer

272

Computer Science MS degree Plan C Certification of Project, Report, and Oral Presentation Requirements  

E-Print Network [OSTI]

Computer Science MS degree Plan C Certification of Project, Report, and Oral Presentation of Project or Activity Course Instructor Initial here ___ Project: ____ Half - (50-99 hours expected effort *************************************************************************************************************** Term/Yr Course Number Course Name Instructor Grade Brief Description of Project or Activity Course

Minnesota, University of

273

AutoDEVS: A Methodology for Automating M&S Software Development and Testing  

E-Print Network [OSTI]

and objectives are met. Many organizations make use of the System Development Life Cycle (SDLC) [Sdl08], Joint process by validating the system early on the development cycle as possible, before the actual hardware modeling and simulation (M&S) methodology which becomes essential as the scale of systems under development

274

--------Original Message --------Subject: [robo-ms] Fwd: [robotics-worldwide] Tenure Track Robotics Position at Rutgers  

E-Print Network [OSTI]

-------- Original Message -------- Subject: [robo-ms] Fwd: [robotics-worldwide] Tenure Track Robotics Position at Rutgers University, Dept of CS Date: Sat, 22 Oct 2011 15:25:43 -0400 From: Kostas@cs.rutgers.edu> Date: Fri, Oct 21, 2011 at 10:48 AM Subject: [robotics-worldwide] Tenure Track Robotics Position

Plotkin, Joshua B.

275

Environmental Hydrology and Hydraulic Engineering Degree Requirements for 1year MS  

E-Print Network [OSTI]

Environmental Hydrology and Hydraulic Engineering Degree Requirements for 1year MS To obtain (choose 4 hours) Core Courses [Requireda ] CEE 450: Surface Hydrology CEE 451: Env. Fluid Mech. CEE 457: Groundwater Hydrology CEE 434: Environmental Systems I CEE 595W: Seminar CEE 595W: Seminar Choose at least

Minsker, Barbara S.

276

MS in Energy Studies Division of University Interdisciplinary Programs (DUIP) Apply Now  

E-Print Network [OSTI]

Economics ENST 320 Energy Law and Case Studies ECON 337 Economic Development ECON 338 Economics of Natural faculties. MS in Energy Studies The Master of Energy Studies program is planned to consolidate and build of the region in areas such as energy science and technology, economics, public policy, and energy management

Shihadeh, Alan

277

Parentage: MS702-80 x NY88 Developers: Michigan State University and  

E-Print Network [OSTI]

Boulder (MSF373-8) Parentage: MS702-80 x NY88 Developers: Michigan State University Douches at Michigan State University (517-355- 0271 x 194, douchesd@msu.edu). Morphological and the Michigan Agricultural Experiment Station Plant Variety Protection: In application Strengths: Boulder

Douches, David S.

278

Predicting the Permeability of Pervious Concretes from Planar Images M.S. Sumanasooriya1  

E-Print Network [OSTI]

-dimensional material structures. Introduction Pervious concrete (also called Enhanced Porosity Concrete, or porous1 Predicting the Permeability of Pervious Concretes from Planar Images M.S. Sumanasooriya1 , D-dimensional material structures of pervious concretes using two-dimensional digital images obtained from actual

Bentz, Dale P.

279

*Correspondence address. Fermilab, MS 122 E 871, Batavia, IL 60510, USA. Fax: 16308403867.  

E-Print Network [OSTI]

*Correspondence address. Fermilab, MS 122 E 871, Batavia, IL 60510, USA. Fax: 1­630­840­3867. E, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA #Fermilab, Batavia, IL 60510, USA; accepted 29 April 2000 Abstract The data acquisition system of the HyperCP experiment at Fermilab recorded

Fermilab Experiment E871

280

The Department of Mechanical Engineering and the MS & E Program present: Sandeep Kumar, Ph.D.  

E-Print Network [OSTI]

JC ME MSE The Department of Mechanical Engineering and the MS & E Program present: Sandeep Kumar, Ph.D. Assistant Professor, Mechanical Engineering Department University of California Riverside-electronics, data storage, sensors and actuators, energy conversion and micro-electro-mechanical systems, where

Note: This page contains sample records for the topic "ms uo uo" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Computer Engineering Integrated BS/MS Handbook Dated: February 06, 2014  

E-Print Network [OSTI]

Computer Engineering Integrated BS/MS Handbook Dated: February 06, 2014 INTEGRATED BACHELOR AND MASTER OF SCIENCE IN COMPUTER ENGINEERING Computer Engineering Program College of Engineering & Computer@fullerton.edu Telephone: 657-278-5987 Fax: 657-278-5804 http://www.fullerton.edu/ecs/cpe #12;Computer Engineering

de Lijser, Peter

282

Physiological Stress Responses to Prolonged Exposure to MS-222 and Surgical Implantation in Juvenile Chinook Salmon  

SciTech Connect (OSTI)

While many studies have investigated the effects of transmitters on fish condition, behavior, and survival, to our knowledge, no studies have taken into account anesthetic exposure time in addition to tag and surgery effects. We investigated stress responses to prolonged MS-222 exposure after stage 4 induction in surgically implanted juvenile Chinook salmon (Oncorhynchus tshawytscha). Survival, tag loss, plasma cortisol concentration, and blood [Na+], [K+], [Ca2+], and pH were measured immediately following anesthetic exposure and surgical implantation and 1, 7, and 14 days post-treatment. Despite the prolonged anesthetic exposure, 3-15 minutes post Stage 4 induction, there were no mortalities or tag loss in any treatment. MS-222 was effective at delaying immediate cortisol release during surgical implantation; however, osmotic disturbances resulted, which were more pronounced in longer anesthetic time exposures. From day 1 to day 14, [Na+], [Ca2+], and pH significantly decreased, while cortisol significantly increased. The cortisol increase was exacerbated by surgical implantation. There was a significant interaction between MS-222 time exposure and observation day for [Na+], [Ca2+], [K+], and pH; variations were seen in the longer time exposures, although not consistently. In conclusion, stress response patterns suggest stress associated with surgical implantation is amplified with increased exposure to MS-222.

Wagner, Katie A.; Woodley, Christa M.; Seaburg, Adam; Skalski, John R.; Eppard, Matthew B.

2014-08-07T23:59:59.000Z

283

Roger E Husser, Jr., M.S., P.E. Planning, Design & Construction  

E-Print Network [OSTI]

Roger E Husser, Jr., M.S., P.E. Director Planning, Design & Construction Herschel Hoffpauir Associate Director Campus Design & Construction Cliff Gillio Manager Mechanical Engineering Neal Pendleton Project Manager Architect Danielle Welborn Civil Engineer Planning, Design & Construction 1/13/2014 Hari

Harms, Kyle E.

284

Revised 10/3/2008 MS&E Doctoral Candidacy Form  

E-Print Network [OSTI]

: ___________________________________________ SU ID_________________ Name of Tutorial/Paper Advisors (two required&E 220 or approved substitution_______________________ Grade/Waiver_____ MS&E 221 or STAT 217 or approved_______________________ Grade/Waiver_____ STAT 200 or 201 or 202 or Econ 271 or approved substitution___________ Grade

Prinz, Friedrich B.

285

School of Architecture College of Architecture Georgia Institute of Technology M.S. IN URBAN DESIGN  

E-Print Network [OSTI]

1 School of Architecture College of Architecture Georgia Institute of Technology M.S. IN URBAN and richly interdisciplinary experience, with required courses in urban design, architecture and city planning, with additional opportunities in civil and environmental engineering, real estate development

286

Calibration and Optimization of PTR-MS for Measurement of Methyl Hydroperoxide (CH3OOH)  

E-Print Network [OSTI]

is to optimize and calibrate a Proton Transfer Reaction Mass Spectrometer (PTR-MS) for the analysis of MHP with the sensitivity to measure this species in air. A promising technique is proton transfer reaction mass by a NSF Research Experience for Undergraduates (REU) grant ATM- 0754990. I would like to thank all

Collins, Gary S.

287

8-1-12 1 MS Online App UNIVERSITY OF ROCHESTER  

E-Print Network [OSTI]

of Student Affairs, 601 Elmwood Avenue Box SON, Rochester NY 14642 Questions may be directed to the School, programs and activities. Questions on compliance should be directed to the particular school or department8-1-12 1 MS Online App UNIVERSITY OF ROCHESTER SCHOOL OF NURSING Nurse Practitioner Masters Program

Goldman, Steven A.

288

Profiling of Human Serum Glycans Associated with Liver Cancer and Cirrhosis by IMS-MS  

E-Print Network [OSTI]

in their mobilities through the gas.5 IMS-MS is similar in many ways to electrophoretic migration in the condensed mobility spectrometry/mass spectrometry analysis of N-linked glycans from human serum. Distributions about glycan conformational and isomeric composition. Statistical analysis of data from 22 apparently

Clemmer, David E.

289

Courses for Breadth Requirement of Aerospace Engineering M.S. Degree Aerodynamics,  

E-Print Network [OSTI]

Courses for Breadth Requirement of Aerospace Engineering M.S. Degree Program Aerodynamics, Fluid Mechanics, Combustion and Propulsion (AFMCP) AE 410/CSE 461: Computational Aerodynamics AE 412/ME 411: Viscous Flow & Heat Transfer AE 416: Applied Aerodynamics AE 419: Aircraft Flight Mechanics AE 433

Gilbert, Matthew

290

Improving Alpha Spectrometry Energy Resolution by Ion Implantation with ICP-MS  

SciTech Connect (OSTI)

We report results of a novel technique using an Inductively Coupled Plasma Mass Spectrometer (ICP-MS) as a method of source preparation for alpha spectrometry. This method produced thin, contaminant free 241Am samples which yielded extraordinary energy resolution which appear to be at the lower limit of the detection technology used in this research.

Dion, Michael P.; Liezers, Martin; Farmer, Orville T.; Miller, Brian W.; Morley, Shannon M.; Barinaga, Charles J.; Eiden, Gregory C.

2015-01-01T23:59:59.000Z

291

Tourism in the Maldives: experiencing the difference from the Maldives Ms. Bndicte AUVRAY  

E-Print Network [OSTI]

Tourism in the Maldives: experiencing the difference from the Maldives Ms. Bénédicte AUVRAY Ph Tourism Promotion Board, the country looks like a white and blue world for honeymooners, divers ­ Enclave ­ Exoticism halshs-00536400,version1-16Nov2010 Author manuscript, published in "Tourism

Paris-Sud XI, Université de

292

M.S. Physics and Astronomy, University of Pittsburgh, 2005 Submitted to the Graduate Faculty of  

E-Print Network [OSTI]

M.S. Physics and Astronomy, University of Pittsburgh, 2005 Submitted to the Graduate Faculty of the Department of Physics and Astronomy in partial fulfillment of the requirements for the degree of Doctor of Philosophy University of Pittsburgh 2009 Andrew J. Mason B.S. Physics, State University of New York

Minnesota, University of

293

Aggregate production: Fines generation during rock crushing M.S. Guimaraes a  

E-Print Network [OSTI]

Aggregate production: Fines generation during rock crushing M.S. Guimaraes a , J.R. Valdes b , A.M.: +1 814 865 9427; fax: +1 814 863 7304. E-mail address: amp26@psu.edu (A.M. Palomino). 0301

Palomino, Angelica M.

294

BME BIOMEDICAL IMAGING CONCENTRATION F12 MS: 30 total credit hours minimum  

E-Print Network [OSTI]

BME BIOMEDICAL IMAGING CONCENTRATION ­ F12 MS: 30 total credit hours minimum Advisor: Luis Hernandez-Garcia, Ph.D. (hernan@umich.edu) Biomedical Imaging: BIOMEDE 5161 Medical Imaging Systems (3) (I)2 General: BIOMEDE 500 Biomedical Engineering Seminar (1) (I,II) BIOMEDE 550 Ethics and Enterprise (1) (I

Kamat, Vineet R.

295

BME BIOMEDICAL IMAGING CONCENTRATION F11 MS: 30 total credit hours minimum  

E-Print Network [OSTI]

BME BIOMEDICAL IMAGING CONCENTRATION ­ F11 MS: 30 total credit hours minimum Advisor: Luis Hernandez-Garcia, Ph.D. (hernan@umich.edu) Biomedical Imaging: BIOMEDE 5161 Medical Imaging Systems (3) (I)2 General: BIOMEDE 500 Biomedical Engineering Seminar (1) (I,II) BIOMEDE 550 Ethics and Enterprise (1) (I

Eustice, Ryan

296

UC Davis Forensic Science Graduate Program Proposed curriculum changes to the MS Degree in Forensic Science  

E-Print Network [OSTI]

1 UC Davis Forensic Science Graduate Program Proposed curriculum changes to the MS Degree in Forensic Science (Graduate Council approved June 21, 2007) Background The Graduate Forensic Science M reflection of that research effort would be 18-36 research units. Initial Forensic Science Curriculum 2001

Ullrich, Paul

297

Surface Decontamination of System Components in Uranium Conversion Plant at KAERI  

SciTech Connect (OSTI)

A chemical decontamination process using nitric acid solution was selected as in-situ technology for recycle or release with authorization of a large amount of metallic waste including process system components such as tanks, piping, etc., which is generated by dismantling a retired uranium conversion plant at Korea Atomic Energy Research Institute (KAERI). The applicability of nitric acid solution for surface decontamination of metallic wastes contaminated with uranium compounds was evaluated through the basic research on the dissolution of UO2 and ammonium uranyl carbonate (AUC) powder. Decontamination performance was verified by using the specimens contaminated with such uranium compounds as UO2 and AUC taken from the uranium conversion plant. Dissolution rate of UO2 powder is notably enhanced by the addition of H2O2 as an oxidant even in the condition of a low concentration of nitric acid and low temperature compared with those in a nitric acid solution without H2O2. AUC powders dissolve easily in nitric acid solutions until the solution pH attains about 2.5 {approx} 3. Above that solution pH, however, the uranium concentration in the solution is lowered drastically by precipitation as a form of U3(NH3)4O9 . 5H2O. Decontamination performance tests for the specimens contaminated with UO2 and AUC were quite successful with the application of decontamination conditions obtained through the basic studies on the dissolution of UO2 and AUC powders.

Choi, W. K.; Kim, K. N.; Won, H. J.; Jung, C. H.; Oh, W. Z.

2003-02-25T23:59:59.000Z

298

EFRC CMSNF Major Accomplishments  

SciTech Connect (OSTI)

The mission of the Center for Material Science of Nuclear Fuels (CMSNF) has been to develop a first-principles-based understanding of thermal transport in the most widely used nuclear fuel, UO2, in the presence of defect microstructure associated with radiation environments. The overarching goal within this mission was to develop an experimentally validated multiscale modeling capability directed toward a predictive understanding of the impact of radiation and fission-product induced defects and microstructure on thermal transport in nuclear fuel. Implementation of the mission was accomplished by integrating the physics of thermal transport in crystalline solids with microstructure science under irradiation through multi institutional experimental and computational materials theory teams from Idaho National Laboratory, Oak Ridge National Laboratory, Purdue University, the University of Florida, the University of Wisconsin, and the Colorado School of Mines. The Center’s research focused on five major areas: (i) The fundamental aspects of anharmonicity in UO2 crystals and its impact on thermal transport; (ii) The effects of radiation microstructure on thermal transport in UO2; (iii) The mechanisms of defect clustering in UO2 under irradiation; (iv) The effect of temperature and oxygen environment on the stoichiometry of UO2; and (v) The mechanisms of growth of dislocation loops and voids under irradiation. The Center has made important progress in each of these areas, as summarized below.

D. Hurley; Todd R. Allen

2014-09-01T23:59:59.000Z

299

UGA IACUC Guidelines for the Use of Tricaine Methanesulfonate (MS-222) in Fishes and Other Aquatic Animals  

E-Print Network [OSTI]

UGA IACUC Guidelines for the Use of Tricaine Methanesulfonate (MS-222) in Fishes and Other Aquatic Animals MS-222 is used for anesthesia and euthanasia of fishes and other aquatic species. See widely between species and is affected by water temperature, hardness, and size of the individual fish

Hall, Daniel

300

Master's Degree in Agriculture Plant Health Management Option Option Title: Master of Science (MS) in Agriculture: Plant Health  

E-Print Network [OSTI]

Master's Degree in Agriculture ­ Plant Health Management Option Option Title: Master of Science (MS) in Agriculture: Plant Health Management Department(s) or Program(s): Supported of Agricultural, Human, and Natural Resource Sciences (CAHNRS) Contact Name: Dr. Kim Kidwell, Director MS

Collins, Gary S.

Note: This page contains sample records for the topic "ms uo uo" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

11/04/02 G. W. Rubloff AVS 2002 MS MoA5 1 Spatially Programmable Reactor Design  

E-Print Network [OSTI]

optimization is constrained by fixed reactor design manufacturing #12;11/04/02 G. W. Rubloff ­ AVS 2002 ­ MS Mo spatial conditions in programmable reactor Uniformity unacceptable Produce high uniformity with optimal11/04/02 G. W. Rubloff ­ AVS 2002 ­ MS MoA5 1 Spatially Programmable Reactor Design: Toward a New

Rubloff, Gary W.

302

Using Entrez Utilities Web Service with C# and MS Visual Studio Entrez Utilities Web Service has been tested with  

E-Print Network [OSTI]

Using Entrez Utilities Web Service with C# and MS Visual Studio 2008 Entrez Utilities Web Service Version 9.0.30729.1 SP Creating a Web Service Client Project The following walkthrough describes how to create a new C# project to access the NCBI Entrez Utilities Web Service using MS Visual Studio 2008

Levin, Judith G.

303

Russell Brown: Department of Mathematics, University of Kentucky, Lexington, Kentucky 40506--0027, brown@ms.uky.edu  

E-Print Network [OSTI]

Russell Brown: Department of Mathematics, University of Kentucky, Lexington, Kentucky 40506--0027, brown@ms.uky.edu Zhongwei Shen: Department of Mathematics, University of Kentucky, Lexington, Kentucky 40506--0027, shenz@ms.uky.edu Peter Perry: Department of Mathematics, University of Kentucky, Lexington

Kentucky, University of

304

Elemental fractionation during LA-ICP-MS analysis of silicate glasses: implications for matrix-independent standardization  

E-Print Network [OSTI]

Elemental fractionation during LA-ICP-MS analysis of silicate glasses: implications for matrix-element solution and from the laser ablation of a range of silicate reference materials (SRM 61X series, MPI-independent standardization of LA- ICP-MS analysis of non-transparent silicates and ceramics, then, is an accurate and viable

Weston, Ken

305

Overseas Affairs and Planning Institute for Integrated Cell-Material Sciences (iCeMS), Kyoto University  

E-Print Network [OSTI]

Contact: Overseas Affairs and Planning Institute for Integrated Cell-Material Sciences (i Cell-Material Sciences, iCeMS for short, I welcome you to the Seventh iCeMS International Symposium to develop them through evolution. They are also very important to design and create various novel "smart

Takada, Shoji

306

Improved DESI-MS Performance using Edge Sampling and aRotational Sample Stage  

SciTech Connect (OSTI)

The position of the surface to be analyzed relative to the sampling orifice or capillary into the mass spectrometer has been known to dramatically affect the observed signal levels in desorption electrospray ionization mass spectrometry (DESIMS). In analyses of sample spots on planar surfaces, DESI-MS signal intensities as much as five times greater were routinely observed when the bottom of the sampling capillary was appropriately positioned beneath the surface plane ( edge sampling") compared to when the capillary just touched the surface. To take advantage of the optimum "edge sampling" geometry and to maximize the number of samples that could be analyzed in this configuration, a rotational sample stage was integrated into a typical DESI-MS setup. The rapid quantitative determination of caffeine in two diet sport drinks (Diet Turbo Tea, Speed Stack Grape) spiked with an isotopically labeled internal standard demonstrated the utility of this approach.

Kertesz, Vilmos [ORNL; Van Berkel, Gary J [ORNL

2008-01-01T23:59:59.000Z

307

Calculo Numerico (MS211) PROVA 1 (25/09/2012) Nome: RA: Turma  

E-Print Network [OSTI]

C´alculo Num´erico (MS211) PROVA 1 (25/09/2012) Nome: RA: Turma: Trabalhe com radianos e 4 d boa aproxima¸c~ao de uma solu¸c~ao pode ser encontrada atrav´es o m´etodo de Newton(-Raphson). Se for poss´ivel, execute duas itera¸c~oes do m´etodo de Newton(-Raphson) gr´aficamente para cada um dos

Sussner, Peter

308

Calculo Numerico (MS211) PROVA 1 (19/04/2010) Nome: RA: Turma  

E-Print Network [OSTI]

C´alculo Num´erico (MS211) PROVA 1 (19/04/2010) Nome: RA: Turma: Trabalhe com 4 d´igitos decimais desta equa¸c~ao utilizando o M´etodo de Newton- Raphson com x0 = 2.5 e precis~oes 1 = 2 = 10. [0.5 pts] (c) Se tomarmos x0 = 1.01 como ser´a o comportamento da sequ^encia gerada pelo M´etodo de

Sussner, Peter

309

Calculo Numerico (MS211) PROVA 1 (01/10/2013) Nome: RA: Turma: Y  

E-Print Network [OSTI]

] (c) Em qual dos m´etodos n´umericos que voc^e conhece geralmente se usa a fatora¸c~ao LU (com ou semC´alculo Num´erico (MS211) PROVA 1 (01/10/2013) Nome: RA: Turma: Y Trabalhe com radianos e 4 d = b fazendo todas as contas na maquina. Explicite as opera¸c~oes bin´arias que produzem erros num´ericos

Sussner, Peter

310

A 2.14 ms candidate optical pulsar in SN1987A: Ten years after  

SciTech Connect (OSTI)

We have monitored Supernova 1987A in optical/near-infrared bands from a few weeks following its birth until the present time in order to search for a pulsar remnant. We have found an apparent pattern of emission near the frequency of 467.5 Hz - a 2.14 ms pulsar candidate, first detected in data taken on the remnant at the Las Campanas Observatory (LCO) 2.5-m Dupont telescope during 14-16 Feb. 1992 UT. We detected further signals near the 2.14 ms period on numerous occasions over the next four years in data taken with a variety of telescopes, data systems and detectors, at a number of ground- and space-based observatories. The sequence of detections of this signal from Feb. `92 through August `93, prior to its apparent subsequent fading, is highly improbable (< 10{sup -10} for any noise source). We also find evidence for modulation of the 2.14 ms period with a {approx}1,000 s period which, when taken with the high spindown of the source (2-3 x 10{sup -10} Hz/s), is consistent with precession and spindown via gravitational radiation of a neutron star with a non- axisymmetric oblateness of {approx}10{sup -6}, and an implied gravitational luminosity exceeding that of the Crab Nebula pulsar by an order of magnitude.

Middleditch, J. [Los Alamos National Lab., NM (United States); Kristian, J.A.; Kunkel, W.E. [Hale Observatories, Pasadena, CA (United States); Hill, K.M. [Tasmania Univ., Hobart, TAS (Australia). Dept. of Mathematics; Watson, R.D. [Tasmania Univ., Hobart, TAS (Australia). Dept. of Physics

1997-09-01T23:59:59.000Z

311

Performance characteristics of cryofocusing GC/MS system at BWXT Pantex Plant.  

SciTech Connect (OSTI)

Ensuring the reliability of all components within a weapon system becomes increasingly important as the stockpile ages. One of the most noteworthy surveillance techniques designed to circumvent (or take place alongside) traditional D&I operations is to collect a sample of gas from within the internal atmosphere of a particular region in a weapon. While a wealth of information about the weapon may be encoded within the composition of its gas sample, our access to that information is only as good as the method used to analyze the sample. It has been shown that cryofocusing-GC/MS offers advantages in terms of sensitivity, ease of sample collection, and robustness of the equipment/hardware used. Attention is therefore focused on qualifying a cryo-GC/MS system for routine stockpile surveillance operations at Pantex. A series of tests were performed on this instrument to characterize the linearity and repeatability of its response using two different standard gas mixes (ozone precursor and TO-14) at various concentrations. This paper outlines the methods used and the results of these tests in order to establish a baseline by which to compare future cryo-GC/MS analyses. A summary of the results is shown.

Brown, Jason R.; Banet, Judith F.; Ithaca, Jerry (BWXT Pantex Plant, Amarillo, TX); Thornberg, Steven Michael; Woods, Lorelei (BWXT Pantex Plant, Amarillo, TX)

2006-07-01T23:59:59.000Z

312

Evaluation of ultra-low background materials for uranium and thorium using ICP-MS  

SciTech Connect (OSTI)

An increasing number of physics experiments require low background materials for their construction. The presence of Uranium and Thorium and their progeny in these materials present a variety of unwanted background sources for these experiments. The sensitivity of the experiments continues to drive the necessary levels of detection ever lower as well. This requirement for greater sensitivity has rendered direct radioassay impractical in many cases requiring large quantities of material, frequently many kilograms, and prolonged counting times, often months. Other assay techniques have been employed such as Neutron Activation Analysis but this requires access to expensive facilities and instrumentation and can be further complicated and delayed by the formation of unwanted radionuclides. Inductively Coupled Plasma Mass Spectrometry (ICP-MS) is a useful tool and recent advancements have increased the sensitivity particularly in the elemental high mass range of U and Th. Unlike direct radioassay, ICP-MS is a destructive technique since it requires the sample to be in liquid form which is aspirated into a high temperature plasma. But it benefits in that it usually requires a very small sample, typically about a gram. This paper discusses how a variety of low background materials such as copper, polymers, and fused silica are made amenable to ICP-MS assay and how the arduous task of maintaining low backgrounds of U and Th is achieved.

Hoppe, E. W.; Overman, N. R.; LaFerriere, B. D. [Pacific Northwest National Laboratory, Richland, WA 99354 (United States)] [Pacific Northwest National Laboratory, Richland, WA 99354 (United States)

2013-08-08T23:59:59.000Z

313

Evaluation of Ultra-Low Background Materials for Uranium and Thorium Using ICP-MS  

SciTech Connect (OSTI)

An increasing number of physics experiments require low background materials for their construction. The presence of Uranium and Thorium and their progeny in these materials present a variety of unwanted background sources for these experiments. The sensitivity of the experiments continues to drive the necessary levels of detection ever lower as well. This requirement for greater sensitivity has rendered direct radioassay impractical in many cases requiring large quantities of material, frequently many kilograms, and prolonged counting times, often months. Other assay techniques have been employed such as Neutron Activation Analysis but this requires access to expensive facilities and instrumentation and can be further complicated and delayed by the formation of unwanted radionuclides. Inductively Coupled Plasma Mass Spectrometry (ICP-MS) is a useful tool and recent advancements have increased the sensitivity particularly in the elemental high mass range of U and Th. Unlike direct radioassay, ICP-MS is a destructive technique since it requires the sample to be in liquid form which is aspirated into a high temperature plasma. But it benefits in that it usually requires a very small sample, typically about a gram. Here we will discuss how a variety of low background materials such as copper, polymers, and fused silica are made amenable to ICP-MS assay and how the arduous task of maintaining low backgrounds of U and Th is achieved.

Hoppe, Eric W.; Overman, Nicole R.; LaFerriere, Brian D.

2013-08-08T23:59:59.000Z

314

The effect of geometry on symbology recognition  

E-Print Network [OSTI]

displays' Of the twenty geometric forms tested it was reported that the best combinations of five symbols each were 1 ) rectangle, circle, zig-zag Z, cross, and semicircle or 2) cross, semicircle, ellipse, triangle, and square. These studies led...AaTA fiue 1e Tte1ap 1sa[[errrs aq1 uJaosrp o1 1o[rd aq1 aJTnbaJ uot1eurJogut go sadfi1 q1oH srUa1sfis fieydstp pue s1uaurnJ1sut 1geJoJre aq1 rrroJQ pa~taoaJ st uo rlerUJogut 1oaJTpuZ '1geJoJ&e aq1 go 1uarUuoJznua TeuJa1xa aq1 rUoJg pawTaoaJ st uoT, 1errr...

Boyless, James Andrus

2012-06-07T23:59:59.000Z

315

Effects of air oxidation on the dissolution rate of LWR spent fuel  

SciTech Connect (OSTI)

Dissolution rates for air-oxidized spent fuel were measured in flowthrough tests. Results from two types of specimens, separated grains and multigrain particles, both in oxidized (U[sub 4]O[sub 9+x]) and unoxidized (UO[sub 2]) conditions indicated only minor effects of oxidation on the surface-area-normalized rates. Similar results were obtained for unirradiated specimens in three different oxidation states (UO[sub 2], U[sub 3]O[sub 7], and U[sub 3]O[sub 8]). These observations have important practical implications for disposal of spent fuel in a geologic repository as well as implications regarding the oxidative dissolution mechanism of UO[sub 2] fuel.

Gray, W.J.; Thomas, L.E.; Einziger, R.E.

1992-11-01T23:59:59.000Z

316

Production of small uranium dioxide microspheres for cermet nuclear fuel using the internal gelation process  

SciTech Connect (OSTI)

The U.S. National Aeronautics and Space Administration (NASA) is developing a uranium dioxide (UO2)/tungsten cermet fuel for potential use as the nuclear cryogenic propulsion stage (NCPS). The first generation NCPS is expected to be made from dense UO2 microspheres with diameters between 75 and 150 m. Previously, the internal gelation process and a hood-scale apparatus with a vibrating nozzle were used to form gel spheres, which became UO2 kernels with diameters between 350 and 850 m. For the NASA spheres, the vibrating nozzle was replaced with a custom designed, two-fluid nozzle to produce gel spheres in the desired smaller size range. This paper describes the operational methodology used to make 3 kg of uranium oxide microspheres.

Collins, Robert T [ORNL] [ORNL; Collins, Jack Lee [ORNL] [ORNL; Hunt, Rodney Dale [ORNL] [ORNL; Ladd-Lively, Jennifer L [ORNL] [ORNL; Patton, Kaara K [ORNL] [ORNL; Hickman, Robert [NASA Marshall Space Flight Center, Huntsville, AL] [NASA Marshall Space Flight Center, Huntsville, AL

2014-01-01T23:59:59.000Z

317

c-Type Cytochrome-Dependent Formation of U(IV) Nanoparticles by Shewanella oneidensis  

SciTech Connect (OSTI)

Modern approaches for bioremediation of radionuclide contaminated environments are based on the ability of microorganisms to effectively catalyze changes in the oxidation states of metals that in turn influence their solubility. Although microbial metal reduction has been identified as an effective means for immobilizing highly-soluble uranium(VI) complexes in situ, the biomolecular mechanisms of U(VI) reduction are not well understood. Here, we show that c-type cytochromes of a dissimilatory metal reducing bacterium, Shewanella oneidensis MR-1 are essential for the reduction of U(VI) and formation of extracelluar UO2 nanoparticles. In particular, the outer membrane (OM) decaheme cytochrome MtrC, previously implicated in Mn(IV) and Fe(III) reduction, directly transferred electrons to U(VI). Additionally, deletions of mtrC and/or omcA significantly affected the in vivo U(VI) reduction rate relative to wild type MR-1. Similar to the wild type, the mutants accumulated UO2 nanoparticles extracellularly to high densities in association with an exopolymeric substance (EPS). In wild type cells, this UO2-EPS matrix exhibited glycocalyx-like properties, contained multiple elements of the OM, polysaccharide, and heme containing proteins. Using a novel combination of methods including synchrotron-based X-ray fluorescence microscopy and high resolution immune-electron microscopy, we demonstrate a close association of the extracellular UO2 nanoparticles with MtrC and OmcA. This is the first study to directly localize the OM-associated cytochromes with EPS, which contains biogenic UO2 nanoparticles. In the environment, such association of UO2 nanoparticles with biopolymers may exert a strong influence on subsequent behavior including susceptibility to oxidation by O2 or transport in soils and sediments.

Marshall, Matthew J.; Beliaev, Alex S.; Dohnalkova, Alice; Kennedy, David W.; Shi, Liang; Wang, Zheming; Boyanov, Maxim I.; Lai, Barry; Kemner, Kenneth M.; Mclean, Jeffrey S.; Reed, Samantha B.; Culley, David E.; Bailey, Vanessa L.; Simonson, Cody J.; Saffarini, Daad; Romine, Margaret F.; Zachara, John M.; Fredrickson, Jim K.

2006-08-08T23:59:59.000Z

318

Source term evaluation for postulated UF{sub 6} release accidents in gaseous diffusion plants -- Summer ventilation mode (non-seismic cases)  

SciTech Connect (OSTI)

Computer models have been developed to simulate the transient behavior of aerosols and vapors as a result of a postulated accident involving the release of uranium hexafluoride (UF{sub 6}) into the process building of a gaseous diffusion plant. For the current study, gaseous UF{sub 6} is assumed to get released in the cell housing atmosphere through B-line break at 58.97 kg/s for 10 min and 30 min duration at the Paducah and Portsmouth Gaseous Diffusion Plants. The released UF{sub 6} undergoes an exothermic chemical reaction with moisture (H{sub 2}O) in the air to form hydrogen fluoride (HF) and radioactive uranyl fluoride (UO{sub 2}F{sub 2}) while it disperses throughout the process building. As part of a facility-wide safety evaluation, this study evaluated source terms consisting of UO{sub 2}F{sub 2} as well as HF during a postulated UF{sub 6} release accident in a process building. UO{sub 2}F{sub 2} mainly remains as airborne-solid particles (aerosols), and HF is in a vapor form. Some UO{sub 2}F{sub 2} aerosols are removed from the air flow due to gravitational settling. The HF and the remaining UO{sub 2}F{sub 2} are mixed with air and exhausted through the building ventilation system. The MELCOR computer code was selected for simulating aerosols and vapor transport in the process building. To characterize leakage flow through the cell housing wall, 3-D CFD tool (CFDS-FLOW3D) was used. About 57% of UO{sub 2}F{sub 2} was predicted to be released into the environment. Since HF was treated as vapor, close to 100% was estimated to get released into the environment.

Kim, S.H.; Chen, N.C.J.; Taleyarkhan, R.P.; Wendel, M.W.; Keith, K.D.; Schmidt, R.W. [Oak Ridge National Lab., TN (United States); Carter, J.C. [J.C. Carter Associates, Inc., Knoxville, TN (United States); Dyer, R.H. [Dyer Enterprises, Harriman, TN (United States)

1996-12-30T23:59:59.000Z

319

M.S. Economic Geology, Oregon State University College of Earth, Ocean, and Atmospheric Sciences, Corvallis, OR Expected Spring, 2015  

E-Print Network [OSTI]

EDUCATION M.S. Economic Geology, Oregon State University College of Earth, Ocean. Dilles Relevant Courses Interpretation of Geologic Maps Igneous Petrology Tectonic Geomorphology B.S. Geology, University of Idaho College of Science, Moscow, ID; GPA: 3

Kurapov, Alexander

320

SUMMARY OF PROPOSED AMENDMENT TO REGULATION FSU-2.024, TUITION AND FEES; MS-NURSE ANESTHESIA PROGRAM; MD TUITION  

E-Print Network [OSTI]

SUMMARY OF PROPOSED AMENDMENT TO REGULATION FSU-2.024, TUITION AND FEES; MS-NURSE ANESTHESIA for a new Master of Science in Nurse Anesthesia program at the Panama City Florida Campus. The new program

Weston, Ken

Note: This page contains sample records for the topic "ms uo uo" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Combined thermogravimetric and mass spectroscopic analysis (TG/MS). Quarterly report, April 1, 1995--June 30, 1995  

SciTech Connect (OSTI)

Progress is reported on the analysis of coals using thermogravimetric (TG) and mass spectrographic (MS) analysis and adding information to the database. Samples were analyzed using oxidative pyrolysis. Various types (coal rank) of coal were utilized.

Kopp, O.C.

1995-09-01T23:59:59.000Z

322

Proteome Profiling for Assessing Diversity: Analysis of Individual Heads of Drosophila melanogaster Using LC-Ion Mobility-MS  

E-Print Network [OSTI]

Proteome Profiling for Assessing Diversity: Analysis of Individual Heads of Drosophila melanogaster dimensions of condensed-phase separations with mass spec- trometry (MS).4 In this approach, mass-to-charge (m-speed, gas-phase sep

Clemmer, David E.

323

Images of the lines under the MS transformations and the Concept of Velocity in the DSR theories  

E-Print Network [OSTI]

The effect of the Maguejo-Smolin (MS) transformations on a straight line in the energy- momentum space will be studied. We will interpret the slope of this line as velocity $dE/dp$, which can leads to addition rule for the velocities in the MS doubly special relativity (DSR) case. Relation between two expressions $dE/dp$ and $p/E$ for velocity in the momentum space will be investigated more and the energy dependency of the velocities in the DSR theories is related to the geometrical properties of the lines under DSR transformations. The images of two parallel lines under the MS transformations will be studied and we will compute crossing point of these lines under the MS transformations in the energy-momentum space. The linear-fractional transformations don't keep parallelism. The crossing point is on a line in the energy-momentum space with a constant momentum $E_p/c$.

Jafari, Nosrtollah

2015-01-01T23:59:59.000Z

324

Images of the lines under the MS transformations and the Concept of Velocity in the DSR theories  

E-Print Network [OSTI]

The effect of the Maguejo-Smolin (MS) transformations on a straight line in the energy- momentum space will be studied. We will interpret the slope of this line as velocity $dE/dp$, which can leads to addition rule for the velocities in the MS doubly special relativity (DSR) case. Relation between two expressions $dE/dp$ and $p/E$ for velocity in the momentum space will be investigated more and the energy dependency of the velocities in the DSR theories is related to the geometrical properties of the lines under DSR transformations. The images of two parallel lines under the MS transformations will be studied and we will compute crossing point of these lines under the MS transformations in the energy-momentum space. The linear-fractional transformations don't keep parallelism. The crossing point is on a line in the energy-momentum space with a constant momentum $E_p/c$.

Nosrtollah Jafari

2015-01-30T23:59:59.000Z

325

Market Research Survey of Commercial Off-The-Shelf (COTS) Portable MS Systems for IAEA Safeguards Applications  

SciTech Connect (OSTI)

This report summarizes the results for the market research survey of mass spectrometers that are deemed pertinent to International Atomic Energy Agency (IAEA) needs and strategic objectives. The focus of the report is on MS instruments that represent currently available (or soon to be) commercial off-the shelf (COTS) technology and weigh less than 400 pounds. A compilation of all available MS instruments (36 COTS and 2 R&D) is presented, along with pertinent information regarding each instrument.

Hart, Garret L.; Hager, George J.; Barinaga, Charles J.; Duckworth, Douglas C.

2013-02-01T23:59:59.000Z

326

A Novel Self-Calibration Scheme for 12-bit 50MS/s In-Seok Jung  

E-Print Network [OSTI]

A Novel Self-Calibration Scheme for 12-bit 50MS/s SAR ADC In-Seok Jung Department of Electrical@ece.neu.edu Abstract-- This paper presents a low-power 12-bit 50MS/s suc- cessive approximation register (SAR) analog-to-digital converter (ADC) using single input condition for Built-In Self Test (BIST) that uses a novel self-calibration

Ayers, Joseph

327

File:USDA-CE-Production-GIFmaps-MS.pdf | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 NoPublicIDAPowerPlantSitingConstruction.pdfNotify98.pdf Jump to: navigation,storage planIL.pdf JumpMN.pdf JumpMS.pdf

328

Ms. Judy Clayton, Chair Paducah Citizens Advisory Board EHI Consultants, Inc.  

Office of Environmental Management (EM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "of Energy Power.pdf11-161-LNG |September 15, 2010 Printing and Mail ManagersforRobertUnited States 0 Ms.

329

Ms Linda Cerrone | U.S. DOE Office of Science (SC)  

Office of Science (SC) Website

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear SecurityTensile Strain Switched5 IndustrialIsadore Perlman,Bios HighRadiobiology: Low DoseofMiscellaneous AdvancedMs.

330

Congrs "Matriaux 2006", Colloque "Matrise des microstructures des matriaux", 13-17 nov. 2006, Dijon. Actes dits sur DVD, ISBN 978-2-9528-1400-3.  

E-Print Network [OSTI]

France par une conversion en voie sèche d'UF6 gazeux. Le procédé comporte deux étapes : hydrolyse en UO2F combustible nucléaire peut être produite par le procédé de conversion en voie sèche d'UF6 gazeux. Ce procédé réalise successivement une hydrolyse de l'UF6 gazeux en poudre de difluorure d'uranyle UO2F2, puis une

Paris-Sud XI, Université de

331

Preparation of thorium-uranium gel spheres  

SciTech Connect (OSTI)

Ceramic oxide spheres with diameters of 15 to 1500 ..mu..m are being evaluated for fabrication of power reactor fuel rods. (Th,U)O/sub 2/ spheres can be prepared by internal or external chemical gelation of nitrate solutions or oxide sols. Two established external gelation techniques were tested but proved to be unsatisfactory for the intended application. Established internal gelation techniques for UO/sub 2/ spheres were applied with minor modifications to make 75% ThO/sub 2/-25% UO/sub 2/ spheres that sinter to diameters of 200 to 1400 ..mu..m (99% T.D.).

Spence, R.D.; Haas, P.A.

1980-01-01T23:59:59.000Z

332

Effects of Time, Heat, and Oxygen on K Basin Sludge Agglomeration, Strength, and Solids Volume  

SciTech Connect (OSTI)

Sludge disposition will be managed in two phases under the K Basin Sludge Treatment Project. The first phase is to retrieve the sludge that currently resides in engineered containers in the K West (KW) Basin pool at ~10 to 18°C. The second phase is to retrieve the sludge from interim storage in the sludge transport and storage containers (STSCs) and treat and package it in preparation for eventual shipment to the Waste Isolation Pilot Plant. The work described in this report was conducted to gain insight into how sludge may change during long-term containerized storage in the STSCs. To accelerate potential physical and chemical changes, the tests were performed at temperatures and oxygen partial pressures significantly greater than those expected in the T Plant canyon cells where the STSCs will be stored. Tests were conducted to determine the effects of 50°C oxygenated water exposure on settled quiescent uraninite (UO2) slurry and a full simulant of KW containerized sludge to determine the effects of oxygen and heat on the composition and mechanical properties of sludge. Shear-strength measurements by vane rheometry also were conducted for UO2 slurry, mixtures of UO2 and metaschoepite (UO3•2H2O), and for simulated KW containerized sludge. The results from these tests and related previous tests are compared to determine whether the settled solids in the K Basin sludge materials change in volume because of oxidation of UO2 by dissolved atmospheric oxygen to form metaschoepite. The test results also are compared to determine if heating or other factors alter sludge volumes and to determine the effects of sludge composition and settling times on sludge shear strength. It has been estimated that the sludge volume will increase with time because of a uranium metal ? uraninite ? metaschoepite oxidation sequence. This increase could increase the number of containers required for storage and increase overall costs of sludge management activities. However, the volume might decrease because of decreases in the water-volume fraction caused by sludge solid reactions, compaction, or intergrowth and recrystallization of metaschoepite. In that case, fewer STSCs may be needed, but the shear strength would increase, and this could challenge recovery by water jet erosion and require more aggressive retrieval methods. Overall, the tests described herein indicate that the settled solids volume remains the same or decreases with time. The only case for which the sludge solids volumes increase with time is for the expansion factor attendant upon the anoxic corrosion of uranium metal to produce UO2 and subsequent reaction with oxygen to form equimolar UO2.25 and UO3•2H2O.

Delegard, Calvin H.; Sinkov, Sergey I.; Schmidt, Andrew J.; Daniel, Richard C.; Burns, Carolyn A.

2011-01-04T23:59:59.000Z

333

Trapped-ion cell with improved DC potential harmonicity for FT-ICR MS  

SciTech Connect (OSTI)

The trapped-ion cell is a key component critical for optimal performance in Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometry (MS). We have upgraded our 12 Tesla FT-ICR instrument with a new open cylindrical cell that includes four additional cylindrical segments that serve as compensation electrodes. The DC potential on the additional segments can be set to specific pre-calculated values to suppress DC trapping field anharmonicity, in an effort to improve coherence of the ion cyclotron motion and minimize deviations from the calibration function of the ideal cell. Alternatively, the compensation potentials can be set equal to potentials of adjacent cell electrodes, which creates a DC potential distribution equivalent to that of a regular open cylindrical cell. The initial experimental characterization of both the compensated and open cell configurations was performed using ESI direct infusion of a peptide mixture. Operating the compensated cell at increased post-excitation radii resulted in improved mass measurement accuracy together with increased signal intensity, while the regular configuration exhibited peak splitting and reduced signal life time under these operating conditions. The observed improvement of the compensated cell performance was consistent with the expected behavior due to the improved DC potential harmonicity. These results confirm that the trapping DC potential harmonicity is significant for optimizing FT-ICR MS performance.

Tolmachev, Aleksey V.; Robinson, Errol W.; Wu, Si; Kang, Hyuk; Lourette, Natacha M.; Pasa-Tolic, Ljiljana; Smith, Richard D.

2008-04-01T23:59:59.000Z

334

Characterization of CMPO and its radiolysis products by Direct Infusion ESI-MS  

SciTech Connect (OSTI)

Direct infusion electrospray ionization-mass spectrometry (ESI-MS) approaches were developed for rapid identification of octyl,phenyl,(N,N-(diisobutyl)carbamoylmethyl) phosphine oxide (CMPO) and impurity compounds formed during alpha and gamma irradiation experiments. CMPO is an aggressive Lewis base, and produces extremely abundant metal complex ions in the ESI-MS analysis that make identification of low abundance compounds that are less nucleophilic challenging. Radiolysis products were identified using several approaches including restricting ion trapping so as to exclude the abundant natiated CMPO ions, extraction of acidic products using aqueous NaOH, and extraction of basic products using HNO3. These approaches generated protonated, natiated and deprotonated species derived from CMPO degradation products formed via radiolytic cleavages of several different bonds. Cleavages of the amide and methylene-phosphoryl bonds appear to be favored by both forms of irradiation, while alpha irradiation also appears to induce cleavage of the methylene-carbonyl bond. The degradation products observed are formed from recombination of the initially formed radicals with hydrogen, methyl, isopropyl and hydroxyl radicals that are derived either from CMPO, or the dodecane solvent.

G. S. Groenewold; G. Elias; B. J. Mincher; S. P. Mezyk

2012-09-01T23:59:59.000Z

335

Studies on the content of heavy metals in Aries River using ICP-MS  

SciTech Connect (OSTI)

Among the industrial branches, the mining industry has always been an important source of environmental pollution, both aesthetically and chemically. Through this paper results of ICP-MS characterization of Aries River Basin are reported. Mining activities from this area has resulted in contamination of environment and its surrounding biota. This is clearly evidenced in analyzed water samples, especially from Baia de Aries site where increased amount of trace elements as Cr, Zn, As, Se, Cd, Pb and U were founded. Also in this site greater amount of rare earth elements was evidenced also. Through monitoring of Aries River from other non-mining area it was observed that the quantitative content of heavy metals was below the maximum permissible levels which made us to conclude that the water table wasn't seriously affected (which possibly might be attributed to the cessation of mining activities in this area from a few years ago)

Voica, Cezara, E-mail: Cezara.Voica@itim-cj.ro; Kovacs, Melinda, E-mail: Cezara.Voica@itim-cj.ro; Feher, Ioana, E-mail: Cezara.Voica@itim-cj.ro [National Institute for Research and Development of Isotopic and Molecular Technologies, 65-103 Donath Str., 400293 Cluj-Napoca (Romania)] [National Institute for Research and Development of Isotopic and Molecular Technologies, 65-103 Donath Str., 400293 Cluj-Napoca (Romania)

2013-11-13T23:59:59.000Z

336

Top-Down Mass Spectrometry Imaging of Intact Proteins by LAESI FT-ICR MS  

E-Print Network [OSTI]

Laser Ablation Electrospray Ionization is a recent development in mass spectrometry imaging. It has been shown that lipids and small metabolites can be imaged in various samples such as plant material, tissue sections or bacterial colonies without anysample pre-treatment. Further, laser ablation electrospray ionization has been shown to produce multiply charged protein ions from liquids or solid surfaces. This presents a means to address one of the biggest challenges in mass spectrometry imaging; the identification of proteins directly from biological tissue surfaces. Such identification is hindered by the lack of multiply charged proteins in common MALDI ion sources and the difficulty of performing tandem MS on such large, singly charged ions. We present here top-down identification of intact proteins from tissue with a LAESI ion source combined with a hybrid ion-trap FT-ICR mass spectrometer. The performance of the system was first tested with a standard protein with ECD and IRMPD fragmentation to prove the...

Kiss, András; Reschke, Brent R; Powell, Matthew J; Heeren, Ron M A

2013-01-01T23:59:59.000Z

337

Mass Spectrometry Data from the Biological MS Data and Software Distribution Center  

DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

The mass spectrometry capabilities at Pacific Northwest National Laboratory (PNNL) are primarily applied to biological research, with an emphasis on proteomics and metabolomics. Many of these cutting-edge mass spectrometry capabilities and bioinformatics methods are housed in the Department of Energy's Environmental Molecular Sciences Laboratory (EMSL), a national scientific user facility operated by PNNL. These capabilities have been developed and acquired through cooperation between the EMSL national scientific user program and PNNL programmatic research. At the website of the Biological MS Data and Software Distribution Center, the following resources are made available: PNNL-developed software tools and source code, PNNL-generated raw data and processed results, links to publications that used the data and results available on this site, and tutorials and user manuals. [taken from http://omics.pnl.gov/

Anderson, Gordon

338

Separation of Yeast Cells from MS2 Viruses Using Acoustic Radiation Force  

SciTech Connect (OSTI)

We report a rapid and robust separation of Saccharomyces cerevisiae and MS2 bacteriophage using acoustic focusing in a microfluidic device. A piezoelectric transducer (PZT) generates acoustic standing waves in the microchannel. These standing waves induce acoustic radiation force fields that direct microparticles towards the nodes (i.e., pressure minima) or the anti-nodes (i.e., pressure maxima) of the standing waves depending on the relative compressidensity between the particle and the suspending liquid.[1] For particles larger than 2 {micro}m, the transverse velocities generated by these force fields enable continuous, high throughput separation. Extensive work in the last decade [2-4] has demonstrated acoustic focusing for manipulating microparticles or biological samples in microfluidic devices. This prior work has primarily focused on experimental realization of acoustic focusing without modeling or with limited one-dimensional modeling estimates. We recently developed a finite element modeling tool to predict the two-dimensional acoustic radiation force field perpendicular to the flow direction in microfluidic devices.[1] Here we compare results from this model with experimental parametric studies including variations of the PZT driving frequencies and voltages as well as various particle sizes and compressidensities. These experimental parametric studies also provide insight into the development of an adjustable 'virtual' pore-size filter as well as optimal operating conditions for various microparticle sizes. Figure 1 shows a typical experimental acoustic focusing result for microparticles (diameter = 2.0 {micro}m) in a 500 {micro}m wide by 200 {micro}m deep microchannel. In this case, the PZT driving frequency and voltage are, respectively, 1.459 MHz and 6.6 V. The microparticles tightly focus (full width half maximum (FWHM) {approx}30 {micro}m) less than 30 s after the initiation of the acoustic field. We simulated the same geometry and operating conditions for comparison. The surface plot in Figure 2 illustrates the two-dimensional pressure field orthogonal to the flow direction (x-direction) from the simulation. The superimposed vector plot shows the acoustic radiation force in this plane. The dark regions and the light regions respectively represent the nodes and anti-nodes of the acoustic pressure field. The corresponding force field predicts acoustic focusing at the center of the microchannel, which is confirmed by the experimental results shown in Figure 1. We demonstrated the separation of Saccharomyces cerevisiae (typical cell size of 4-6 {micro}m depending on the cell growth stage, measured using a Coulter counter) and MS2 bacteriophage (typical diameter {approx}30 nm [5]) using acoustic focusing (Figure 3). A mixture of S. cerevisiae and MS2 labeled with Ribogreen was prepared and injected into one inlet of the microchip (i.e., half of the microchannel was filled with the sample). We varied driving voltages from 1.96 to 4.76 V, while fixing the driving frequency at 1.459 MHz and flow rate at 20 {micro}l/min. The acoustic radiation force did not affect the MS2 viruses, and their concentration profile remained unchanged. Increased driving voltages enhanced the acoustic focusing of the yeast cells thereby achieving good separation. We are able to achieve yields of > 80% and sample purities of > 90% in this continuous-flow sample preparation device.

Jung, B; Fisher, K; Ness, K; Rose, K A; Mariella, Jr., R P

2008-03-27T23:59:59.000Z

339

Ultrashort-period MS eclipsing systems. New observations and light curve solutions of six NSVS binaries  

E-Print Network [OSTI]

We carried out photometric and low-resolution spectral observations of six eclipsing ultrashort-period binaries with MS components. The light curve solutions of the Rozhen observations show that all targets are overcontact systems. We found well-defined empirical relation "period -- semi-major axis" for the short-period binaries and used it for estimation of the global parameters of the targets. Our results revealed that NSVS 925605 is quite interesting target: (a) it is one of a few contact binaries with M components; (b) it exhibits high activity (emission in H$\\alpha$ line, X-ray emission, large cool spots, non-Planck energy distribution); (c) its components differ in temperature by 700 K. All appearances of high magnetic activity and huge fillout factor (0.7) of NSVS 925605 might be assumed as a precursor of the predicted merging of close magnetic binaries. Another unusual binary is NSVS 2700153 which reveals considerable long-term variability.

Dimitrov, Dinko

2015-01-01T23:59:59.000Z

340

A New Weak Lensing Analysis of MS1224.7+2007  

E-Print Network [OSTI]

Galaxy cluster mass distributions are useful probes of Omega_0 and the nature of the dark matter. Large clusters will distort the observed shapes of background galaxies through gravitational lensing allowing the measurement of the cluster mass distributions. For most cases, the agreement between weak lensing and radial velocity mass measurements of clusters is reasonably good. There is, however, one significant exception, the z=0.32 cluster MS1224.7+2007, which has a lensing mass substantially larger than the virial mass and also a very high mass-to-light ratio. Since this controversial object might be an unusually dark mass a follow-up study is definitely warranted. In this paper we study the mass and light distributions of MS1224+2007 out to a projected radius of 800/h kpc by measuring the gravitationally-induced distortions of background galaxies. We detect a shear signal in the background galaxies in the radial range 27.5 arcsec < r < 275 arcsec at the 5.5 sigma level. The resultant mass map exhibits a peak centered on the dominant cluster galaxy and strong evidence for substructure which is even more strongly seen in the galaxy distribution. Assuming all the detected shear is due to mass at z=0.32 we find cluster mass-to-light ratio of M/L_R = 640 +/- 150. The mass profile is quite flat compared to other clusters, disagreeing with a pseudo-singular isothermal sphere at the 95% confidence level. Our mass and M/L estimates are consistent with the previous weak lensing result. The discrepancy between the lensing and virial mass remains although it might be partially explained by subclustering and infall perpendicular to the line-of-site. This cluster remains a candidate dark object deficient in baryons and as such severely tests cosmological models.

Philippe Fischer

1999-01-29T23:59:59.000Z

Note: This page contains sample records for the topic "ms uo uo" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

MS Degree in Mechanical Engineering, King Fahd University of Petroleum and Minerals, Dhahran, Saudi Arabia, April 2006. Grade Point Average 3.34/4.00. MS Thesis on "The Effect  

E-Print Network [OSTI]

EDUCATION · MS Degree in Mechanical Engineering, King Fahd University of Petroleum and Minerals/Lab Engineer, The Petroleum Institute, Abu Dhabi, United Arab Emirates · May 2006 June 2012: Core Analysis Engineer, Research Institute, Center for Petroleum and Minerals, KFUPM, Dhahran, Saudi Arabia · February

Williams, John M.

342

Report on R&D Projects Access, describing procedures for identifying, defining and launching of collaborative R&D projects: Milestone MS16  

E-Print Network [OSTI]

Report on R&D Projects Access, describing procedures for identifying, defining and launching of collaborative R&D projects: Milestone MS16

Garvey, T.; Launé, B.; Lilje, L.; Napoly, O.; Obradors, D.; Omet, C.; Pierini, P.; Skoczen, B.; Bocian, D.; Schulte, D.; Smith, S.; Ziemann, V.

2012-01-01T23:59:59.000Z

343

SUMUKH V., engineering educator; b. Maharashlra. India; S. BabWekar. MS in Mech. Engring. The V. Toledo, Ohio. 2002.  

E-Print Network [OSTI]

and Zhenyu Bai; m, Yan Wang, Feb. 25,1958; I child, Xoe, MS. Beijing Inst. Tech,. 1987; BS. Tsinghua Br. V .· Beijing. 1983; PhD. Aa. Atlantic V .· Boca Raton, 2000. Sr. software engr. Lam Rsch. Corp.. Fremont. Calif

Baica, Malvina

344

A self-consistent nonlinear force-free solution for a solar active region magnetic M.S. Wheatland  

E-Print Network [OSTI]

fields 1. Introduction Solar coronal magnetic fields provide the source of energy for solar flaresA self-consistent nonlinear force-free solution for a solar active region magnetic field M.S. Wheatland Sydney Institute for Astronomy, School of Physics, University of Sydney, NSW 2006, Australia m

Régnier, Stéphane

345

SURFACE OXIDATION OF DIESEL PARTICULATE MATTER IN PRESENCE OF O3 +NOX: NEW TD/GC/MS ANALYSIS METHOD  

E-Print Network [OSTI]

in the atmosphere. TD-GC-MS ANALYSIS METHODOLOGY A thermal desorption (TD) injection device (M. Ezrin, 1991. Valve Spindle 10. Carrier Gas Inlet 11. Inlet Assembly 12. Injection Port Insert PAH standard Solution, 1ppm, 1µL injection Alkanes Standard Solution, 0.1ppm, 1µL injection FUTURE EXPERIMENTS Verify PM

Holmén, Britt A.

346

FOREST CONSERVATION/CLIMATE CHANGE ADAPTATION Prestigious van Eck Scholarships are available to graduate students (M.S. or  

E-Print Network [OSTI]

to graduate students (M.S. or Ph.D.) seeking training in Forest Conservation and Climate Change Adaptation to manage forest tree species for long-term growth and survival in changing climates. The research options in both academia and private industry. Research will take place at The Hardwood Tree Improvement

347

Self-Assembly of Viral Capsids via a Hamiltonian Paths Approach: The Case of Bacteriophage MS2  

E-Print Network [OSTI]

Self-Assembly of Viral Capsids via a Hamiltonian Paths Approach: The Case of Bacteriophage MS2 of viruses the assembly of the viral capsids that encapsulate and hence provide protection for the viral genome can be modeled as tile assembly, where tiles represent are schematic representations of suitable

Severini, Simone

348

11/04/02 G. W. Rubloff AVS 2002 MS MoA5 1 Spatially Programmable Reactor Design  

E-Print Network [OSTI]

) reactor design · Process change impacts (often degrades) uniformity · Process optimization is constrained11/04/02 G. W. Rubloff ­ AVS 2002 ­ MS MoA5 1 Spatially Programmable Reactor Design: Toward a New recipe logic and timingProcess optimization requiresProcess optimization requires tradeoffs between

Rubloff, Gary W.

349

Bogazici University, Istanbul, Turkey Chemical Engineering B.S., 2006 Bogazici University, Istanbul, Turkey Chemical Engineering M.S., 2008  

E-Print Network [OSTI]

Education Bogazici University, Istanbul, Turkey Chemical Engineering B.S., 2006 Bogazici University, Istanbul, Turkey Chemical Engineering M.S., 2008 The Ohio State University, Columbus, Ohio Chemical study awarded from The Scientific and Technological Research Council of Turkey Ibrahim Ilgaz Soykal

Pennycook, Steve

350

Application for theAnn and Bill Fisher Graduate Scholarship 1. Your name Mr. Miss, Ms., Mrs.  

E-Print Network [OSTI]

Application for theAnn and Bill Fisher Graduate Scholarship 1. Your name Mr. Miss, Ms., Mrs): _____________________________________________ _____________________________________________ 6. Date of birth: (month, day, year): Page 1 of 3 Eligibility: You are eligible for this scholarship; and You are proficient in at least two languages; and You are able to demonstrate 1) outstanding academic

Rock, Chris

351

Application for theAnn and Bill Fisher Graduate Scholarship 1. Your name Mr. Miss, Ms., Mrs.  

E-Print Network [OSTI]

Application for theAnn and Bill Fisher Graduate Scholarship 1. Your name Mr. Miss, Ms., Mrs): _____________________________________________ _____________________________________________ 5. Date of birth: (month, day, year): Page 1 of 3 Eligibility: You are eligible for this scholarship, and You are proficient in at least two languages, and You are able to demonstrate 1)outstanding academic

Rock, Chris

352

MS#040418-01 1 Abstract--The fine scale swimming behavior of fish can now be  

E-Print Network [OSTI]

MS#040418-01 1 Abstract--The fine scale swimming behavior of fish can now be studied because evaluation of the performance of these tracking algorithms for the analysis of fine scale behavior of fish was performed using a data set of 100 fish track tracks recorded simultaneously with a multibeam sonar

Linder, Stephen

353

Brazilian think tanks and their search for identity and recognition1 Author: Ms. Tatiana Teixeira da Silva2  

E-Print Network [OSTI]

1 Brazilian think tanks and their search for identity and recognition1 Author: Ms. Tatiana Teixeira version of the chapter "Think tanks brasileiros: entre o passado e o futuro", that will be published;2 ABSTRACT In Brazil, the study of think tanks is still at its beginning, even if this is far from being

Paris-Sud XI, Université de

354

Modular Multi-ported SRAM-based Memories Ameer M.S. Abdelhadi and Guy G.F. Lemieux  

E-Print Network [OSTI]

Modular Multi-ported SRAM-based Memories Ameer M.S. Abdelhadi and Guy G.F. Lemieux Department,lemieux}@ece.ubc.ca ABSTRACT Multi-ported RAMs are essential for high-performance parallel computation systems. VLIW and vector processors, CGRAs, DSPs, CMPs and other processing systems often rely upon multi-ported memories for parallel

Lemieux, Guy

355

Discovery of Optical Bursts from MS1603.6+2600 = UW CrB  

E-Print Network [OSTI]

We report the discovery of several optical burst-like events from the low-mass X-ray binary MS1603.6+2600 (UW CrB). The events last for a few tens of seconds, exhibit a very fast rise and slow decay, and involve optical brightening of a factor of 2-3. The flares appear distinct from the lower level flickering and instead strongly resemble reprocessed type-I X-ray bursts as seen in a number of other neutron star low-mass X-ray binaries. In conjunction with the previously reported candidate X-ray burst, these confirm that the compact object in UW CrB is a neutron star. We examine the optical burst brightness and recurrence times and discuss how the nature of the system can be constrained. We conclude that the source is most likely an accretion disk corona source at an intermediate distance, rather than a nearby quiescent system or very distant dipper.

R. I. Hynes; E. L. Robinson; E. Jeffery

2004-05-11T23:59:59.000Z

356

0 ms 7 ms 12 ms 18 ms 24 ms 30 ms 36 ms 41 ms 47 ms 53 ms 59 ms 65 ms 71 ms The Reference Simulation (ktendon-ankle = 75,000 N/m)  

E-Print Network [OSTI]

.5 The Reference Simulation (ktendon-ankle = 75,000 N/m) Download a copy of this poster and read more about ourD MODEL2,3 : -SKELETON: 5 bones, 4 joints -MUSCULATURE: Hip, knee & ankle extensor groups THEORY') MODEL MUSCLE - TENDON (MT) UNITKnee extensors `KE' Hip extensors `HE' Ankle extensors `AE' Hip (COM) TMT

Richards, Chris

357

Shutdown mechanisms for a hypothetical criticality accident involving HEU powder: Preliminary results  

SciTech Connect (OSTI)

This work examines the physical processes that would cause an accidental criticality involving higly enriched uranium(HEU) powder to shut down naturally. The study analyses an excursion resulting from the continous poring of slightly damp HEU powder (either UO{sub 3} or UF{sub 4} containing 1.5% water) onto a concrete floor.

Bentley, C.; Basoglu, B.; Dunn, M.; Plaster, M.; Ruggles, A.; Wilkinson, A.; Yamamoto, T.; Dodds, H. [Univ. of Tennessee, Knoxville, TN (United States)

1994-12-31T23:59:59.000Z

358

VII. SOLAR RADIATION DATA COMPARISONS In this section some of the solar radiation data  

E-Print Network [OSTI]

18 VII. SOLAR RADIATION DATA COMPARISONS In this section some of the solar radiation data gathered by the UO Solar Monitoring Network is presented in tabular and pictorial form and related to similar information from other Western U.S. sites. A comparison of the amount of incident solar radiation is made us

Oregon, University of

359

APOLLO 16 VOICE TRANSCRIPT PERTAINING TO THE GEOLOGY OF THE LANDING SITE  

E-Print Network [OSTI]

* * *: {( APOLLO 16 VOICE TRANSCRIPT PERTAINING TO THE GEOLOGY OF THE LANDING SITE #12;- APOLLO 16 VOICE TRANSCRIPT Pertaining to the geology of the landIng site by N.G. Bai loey and G.E. Ulrich U.s. Geol:ogical Survey Branch of Astrogeology F]agstaff~ Arizona 1915 #12;FORM NTlS·315 UO-70

Rathbun, Julie A.

360

Continued on back UNIVERSITY OF OREGON  

E-Print Network [OSTI]

Continued on back UNIVERSITY OF OREGON MOBILE TECHNOLOGY ACCESS AND PAYMENT OPTION REQUEST Please complete this form to apply for access to mobile technology (e.g., cell phones, smart phones, etc device use. Information on the UO policies regarding access to mobile technology and payment options can

Oregon, University of

Note: This page contains sample records for the topic "ms uo uo" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Project-Role Pair user_tokens  

E-Print Network [OSTI]

OSAC Users (U) Domains (D) Roles (R) User Assignment (UA) Permission Assignment (PA) Project Ownership (PO) Project-Role Pair (PRP) Projects (P) Tokens (T) User Ownership (UO) Services (S) user_tokens token_project Groups (G) Group Ownership (GO) User Group (UG) Group Assignment (GA) token_roles PERMS

Sandhu, Ravi

362

Design and Optimization of Neuro-Fuzzy-Based Recognition of Musical Rhythm Patterns  

E-Print Network [OSTI]

Design and Optimization of Neuro-Fuzzy-Based Recognition of Musical Rhythm Patterns Tillman Weyde framework to support computer models and applications has not yet been established. Musical Pattern@uos.de Abstract The task of recognizing patterns and assigning rhythmic structure to unquan- tized musical input

Weyde, Tillman

363

Development of a RELAP5-3D three-dimensional model of a VVER-1000 Nuclear Power Plant for analysis of a large-break loss-of-coolant accident  

E-Print Network [OSTI]

large-break loss-of-coolant accident (LB LOCA). A validated, one-dimensional control of the nuclear power plant, for the study of the effects of mixed oxide (MOX) fuel, was modified to include a standard fuel loading of UO?. The development...

Clarno, Kevin Taylor

2012-06-07T23:59:59.000Z

364

Evaluation of weapons-grade mixed oxide fuel performance in U.S. Light Water Reactors using COMETHE 4D release 23 computer code  

E-Print Network [OSTI]

The COMETHE 4D Release 23 computer code was used to evaluate the thermal, chemical and mechanical performance of weapons-grade MOX fuel irradiated under U.S. light water reactor typical conditions. Comparisons were made to and UO? fuels exhibited...

Bellanger, Philippe

2012-06-07T23:59:59.000Z

365

Modulation cancellation method for laser spectroscopy V. Spagnolo*a,b  

E-Print Network [OSTI]

Fisica, University and Politecnico of Bari, CNR--IFN UOS BARI, Via Amendola 173, 70126 Bari, Italy of the proposed approach are: *spagnolo@fisica.uniba.it; phone 39 080 544-2373; fax 39 080 544-2219; www.fisica

366

Curriculum vitae of Viviana Mascardi (updated to September Personal data  

E-Print Network [OSTI]

rock carvings. #12;Role: Principal investigator, UO coordinator Funding source and programme: MIUR FIRB: Mobilit`a Intelligente Ecosostenibile (MIE) Role: Participant Funding source and programme: MIUR, progetto for Reliable Large-Scale Software Systems (BETTY) Role: Participant Funding source and programme: ICT COST

Mascardi, Viviana

367

n a recent TEDx talk she gave before a Portland audience, microbiologist  

E-Print Network [OSTI]

), Brown is an expert in sustainable buildings. His involvement ensures that the discoveries made test sites like the UO's sustainably built Lundquist College of Business and a Portland hospital other, with humans, and with their environment. "Buildings are complex ecosystems that are an important

Oregon, University of

368

Thermodynamics of fission products in dispersion fuel designs - first principles modeling of defect behavior in bulk and at interfaces  

SciTech Connect (OSTI)

Density functional theory (DFT) calculations of fission product (Xe, Sr, and Cs) incorporation and segregation in alkaline earth metal oxides, HfO{sub 2} and UO{sub 2} oxides, and the MgO/(U, Hf, Ce)O{sub 2} interfaces have been carried out. In the case of UO{sub 2}, the calculations were performed using spin polarization and with a Hubbard U term characterizing the on-sit Coulomb repulsion between the localized 5f electrons. The fission product solution energies in bulk UO{sub 2{+-}x} have been calculated as a function of non-stoichiometry x, and were compared to that in MgO. These calculations demonstrate that the fission product incorporation energies in MgO are higher than in HfO{sub 2}. However, this trend is reversed or reduced for alkaline earth oxides with larger cation sizes. The solution energies of fission products in MgO are substantially higher than in UO{sub 2{+-}x}, except for the case of Sr in the hypostoichiometric case. Due to size effects, the thermodynamic driving force of segregation for Xe and Cs from bulk MgO to the MgO/fluorite interface is strong. However, this driving force is relatively weak for Sr.

Liu, Xiang-yand [Los Alamos National Laboratory; Uberuaga, Blas P [Los Alamos National Laboratory; Nerikar, Pankaj [Los Alamos National Laboratory; Sickafus, Kurt E [Los Alamos National Laboratory; Stanek, Chris R [Los Alamos National Laboratory

2009-01-01T23:59:59.000Z

369

Preparation and Characterization of Uranium Oxides in Support of the K Basin Sludge Treatment Project  

SciTech Connect (OSTI)

Uraninite (UO2) and metaschoepite (UO3·2H2O) are the uranium phases most frequently observed in K Basin sludge. Uraninite arises from the oxidation of uranium metal by anoxic water and metaschoepite arises from oxidation of uraninite by atmospheric or radiolytic oxygen. Studies of the oxidation of uraninite by oxygen to form metaschoepite were performed at 21°C and 50°C. A uranium oxide oxidation state characterization method based on spectrophotometry of the solution formed by dissolving aqueous slurries in phosphoric acid was developed to follow the extent of reaction. This method may be applied to determine uranium oxide oxidation state distribution in K Basin sludge. The uraninite produced by anoxic corrosion of uranium metal has exceedingly fine particle size (6 nm diameter), forms agglomerates, and has the formula UO2.004±0.007; i.e., is practically stoichiometric UO2. The metaschoepite particles are flatter and wider when prepared at 21°C than the particles prepared at 50°C. These particles are much smaller than the metaschoepite observed in prolonged exposure of actual K Basin sludge to warm moist oxidizing conditions. The uraninite produced by anoxic uranium metal corrosion and the metaschoepite produced by reaction of uraninite aqueous slurries with oxygen may be used in engineering and process development testing. A rapid alternative method to determine uranium metal concentrations in sludge also was identified.

Sinkov, Sergey I.; Delegard, Calvin H.; Schmidt, Andrew J.

2008-07-08T23:59:59.000Z

370

Developing a High Thermal Conductivity Fuel with Silicon Carbide Additives  

SciTech Connect (OSTI)

The objective of this research is to increase the thermal conductivity of uranium oxide (UO{sub 2}) without significantly impacting its neutronic properties. The concept is to incorporate another high thermal conductivity material, silicon carbide (SiC), in the form of whiskers or from nanoparticles of SiC and a SiC polymeric precursor into UO{sub 2}. This is expected to form a percolation pathway lattice for conductive heat transfer out of the fuel pellet. The thermal conductivity of SiC would control the overall fuel pellet thermal conductivity. The challenge is to show the effectiveness of a low temperature sintering process, because of a UO{sub 2}-SiC reaction at 1,377°C, a temperature far below the normal sintering temperature. Researchers will study three strategies to overcome the processing difficulties associated with pore clogging and the chemical reaction of SiC and UO{sub 2} at temperatures above 1,300°C:

Ronald baney; James Tulenko

2012-11-20T23:59:59.000Z

371

Bioremediation of Uranium Plumes with Nano-scale  

E-Print Network [OSTI]

(IV) (UO2[s], uraninite) Anthropogenic · Release of mill tailings during uranium mining - MobilizationBioremediation of Uranium Plumes with Nano-scale Zero-valent Iron Angela Athey Advisers: Dr. Reyes Undergraduate Student Fellowship Program April 15, 2011 #12;Main Sources of Uranium Natural · Leaching from

Fay, Noah

372

The Development of Models to Optimize Selection of Nuclear Fuels through Atomic-Level Simulation  

SciTech Connect (OSTI)

Demonstrated that FRAPCON can be modified to accept data generated from first principles studies, and that the result obtained from the modified FRAPCON make sense in terms of the inputs. Determined the temperature dependence of the thermal conductivity of single crystal UO2 from atomistic simulation.

Prof. Simon Phillpot; Prof. Susan B. Sinnott; Prof. Hans Seifert; Prog. James Tulenko

2009-01-26T23:59:59.000Z

373

Refinement in the ultrasonic velocity data and estimation of the critical parameters for molten uranium dioxide  

E-Print Network [OSTI]

accurate exper- imental measurements on the density, and heat capacity of liquid UO2 up to $8000 K density and isobaric heat capacity, much more easily than other conventional methods [3,4]. Many of state for liquid urania has also been developed which predicts a critical temperature (Tc) % 10500 K

Azad, Abdul-Majeed

374

Synthesis of triglyceride by the intestinal mucosa  

E-Print Network [OSTI]

l i b r a r y A & M COLLEGE OF TEXAS A&MCOLAEA GF CTEXS&1LTE9L 5& COL EMCLACEM8S VI1GA8 8 9.PPrecuc.so 5f XLGTXL 1OTEACGlOLT 5ILSS Ayid.ccr- cs c3r Xeu-yucr A23ssp sa c3r 8te.2ypcyeup uo- Vr23uo.2up 1spprtr sa CrnuP .o Duec.up aypa....ppdroc sa c3r erNy.erdrocP ase c3r -rterr sa 9G1CGT GF lOESGAGlO& Vuf 1958 Vu'se Ayi'r2cH 5.s23rd.Pcef uo- Myce.c.so ^A & r A&MCOLAEA GF CTEXS&1LTE9L 5& COL EMCLACEM8S VI1GA8 8 9.PPrecuc.so 5f XLGTXL 1OTEACGlOLT 5ILSS 8DDesbr- uP cs Pcfpr uo- 2...

Buell, George Christopher

2013-10-04T23:59:59.000Z

375

A Multi-Modular Neutronically Coupled Power Generation System  

E-Print Network [OSTI]

The High Temperature Integrated Multi-Modular Thermal Reactor is a small modular reactor that uses an enhanced conductivity BeO-UO2 fuel with supercritical CO2 coolant to drive turbo-machinery in a direct Brayton cycle. The core consists of several...

Patel, Vishal

2012-07-16T23:59:59.000Z

376

Spin-lattice coupling in uranium dioxide probed by magnetostriction measurements at high magnetic fields (P08358-E001-PF)  

SciTech Connect (OSTI)

Conclusions Our preliminary magnetostriction measurements have already shown a strong interplay of lattice dynamic and magnetism in both antiferromagnetic and paramagnetic states, and give unambiguous evidence of strong spin- phonon coupling in uranium dioxide. Further studies are planned to address the puzzling behavior of UO2 in magnetic and paramagnetic states and details of the spin-phonon coupling.

K. Gofryk; M. Jaime

2014-12-01T23:59:59.000Z

377

Quantifying submarine groundwater discharge in the coastal zone via multiple methods  

E-Print Network [OSTI]

South Florida Water Management District, USA i University of Western Australia, Australia j Department, Tallahassee, FL 32306, USA b Isotope Hydrology Section, International Atomic Energy Agency, Austria c, Turkey n Marine Environment Laboratory, International Atomic Energy Agency, Monaco o U.O. 4.17 of the G

378

HMSC Sustainability Committee Meeting Minutes: January 13, 2009  

E-Print Network [OSTI]

for Sustainability Committee Oregon Climate Dialog/ National Teach-in Recycle Mania Earth Tub Industrial audit about tax and energy rebates and home energy conservation. Actions: Devin will get a blurb from. Devin concluded that UO and OSU both had excellent websites, and that the University of Pennsylvania

379

Water-Moderated and -Reflected Slabs of Uranium Oxyfluoride  

SciTech Connect (OSTI)

A series of ten experiments were conducted at the Oak Ridge National Laboratory Critical Experiment Facility in December 1955, and January 1956, in an attempt to determine critical conditions for a slab of aqueous uranium oxyfluoride (UO2F2). These experiments were recorded in an Oak Ridge Critical Experiments Logbook and results were published in a journal of the American Nuclear Society, Nuclear Science and Engineering, by J. K. Fox, L. W. Gilley, and J. H. Marable (Reference 1). The purpose of these experiments was to obtain the minimum critical thickness of an effectively infinite slab of UO2F2 solution by extrapolation of experimental data. To do this the slab thickness was varied and critical solution and water-reflector heights were measured using two different fuel solutions. Of the ten conducted experiments eight of the experiments reached critical conditions but the results of only six of the experiments were published in Reference 1. All ten experiments were evaluated from which five critical configurations were judged as acceptable criticality safety benchmarks. The total uncertainty in the acceptable benchmarks is between 0.25 and 0.33 % ?k/keff. UO2F2 fuel is also evaluated in HEU-SOL-THERM-043, HEU-SOL-THERM-011, and HEU-SOL-THERM-012, but these those evaluation reports are for large reflected and unreflected spheres. Aluminum cylinders of UO2F2 are evaluated in HEU-SOL-THERM-050.

Margaret A. Marshall; John D. Bess; J. Blair Briggs; Clinton Gross

2010-09-01T23:59:59.000Z

380

APPLIED AND ENVIRONMENTAL MICROBIOLOGY, Nov. 2005, p. 74537460 Vol. 71, No. 11 0099-2240/05/$08.00 0 doi:10.1128/AEM.71.11.74537460.2005  

E-Print Network [OSTI]

with nitrate and incubated with no electron acceptor, was used for the two time points considered and for both- ganese(IV), nitrate, nitrite, thiosulfate, sulfite, trimethylamine N-oxide (TMAO), dimethyl sulfoxide and soluble hexavalent uranyl (UO2 2 ) and chro- mate (CrO4 2 ) to less soluble and less toxic forms [U

Tebo, Brad

Note: This page contains sample records for the topic "ms uo uo" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Hydrothermal synthesis, structure and thermal stability of diamine templated layered uranyl-vanadates  

E-Print Network [OSTI]

crystal structure and thermal behavior are reported herein. Experimental Synthesis Uranyl nitrate (UO2(NO31 Hydrothermal synthesis, structure and thermal stability of diamine templated layered uranyl. Murielle.rivenet@ensc-lille.fr Running Title : Diamine templated layered uranyl-vanadates. Figure for table

Paris-Sud XI, Université de

382

Nagoya University Description  

E-Print Network [OSTI]

is a friendly, bustling industrial port city, and is the site of Toyota HQ (whose plant you can visit to watch their amazing robot workforce). Don't miss the festivals at Atsuta-jing, one of the most important Shinto for a JASSO Scholarship. Apply Once you have completed the UoB online application and been allocated a space

Bristol, University of

383

Hydrofluoric Acid Corrosion Testing on Unplated and Electroless Gold-Plated Samples  

SciTech Connect (OSTI)

The Molten Salt Reactor Experiment (MSRE) remediation requires that almost 40 kg of uranium hexafluoride (UF6) be converted to uranium oxide (UO). In the process of this conversion, six moles of hydrofluoric acid (HP) are produced for each mole of UF6 converted.

Osborne, P.E.; Icenhour, A.S.; Del Cul, G.D.

2000-08-01T23:59:59.000Z

384

Structural similarities between biogenic uraninites produced by phylogenetically and metabolically diverse bacteria.  

SciTech Connect (OSTI)

While the product of microbial uranium reduction is often reported to be“UO2”, a comprehensive characterization including stoichiometry and unit cell determination is available for only one Shewanella species. Here, we compare the products of batch uranyl reduction by a collection of dissimilatory metal- and sulfate-reducing bacteria of the genera Shewanella, Geobacter, Anaeromyxobacter, and Desulfovibrio under similar laboratory conditions. Our results demonstrate that U(VI) bioreduction by this assortment of commonly studied, environmentally relevant bacteria leads to the precipitation of uraninite with a composition between UO2.00 and UO2.075, regardless of phylogenetic or metabolic diversity. Coupled analyses, including electron microscopy, X-ray absorption spectroscopy, and powder diffraction, confirm that structurally and chemically analogous uraninite solids are produced. These biogenic uraninites have particle diameters of about 2-3 nm and lattice constants consistent with UO2.0 and exhibit a high degree of intermediate-range order. Results indicate that phylogenetic and metabolic variability within delta- and gamma-proteobacteria has little effect on nascent biouraninite structure or crystal size under the investigated conditions.

Sharp, Jonathan; Schofield, Eleanor J.; Veeramani, Harish; Suvorova, Elena; Kennedy, David W.; Marshall, Matthew J.; Mehta, Apurva; Bargar, John R.; Bernier-Latmani, Rizlan

2009-11-01T23:59:59.000Z

385

SURVEY OF THE COLUMBIA RIVER AND ITS TRIBUTARIES -Part VII  

E-Print Network [OSTI]

SURVEY OF THE COLUMBIA RIVER AND ITS TRIBUTARIES - Part VII I ^^^^'fie^BkJioJS SPECIAL SCIENTIFIC, Director Special Scientific Report - Fisheries No. UO SURVEY OF THE COLUMBIA RIVER AND ITS TRIBUTARIES PART these have been divided for con- venience into four sub-areas. On the Idaho side of the Snake River

386

CX-011566: Categorical Exclusion Determination  

Broader source: Energy.gov [DOE]

Mechanical Behavior of Uranium Oxide (UO2) at Sub-grain Length Scales: Quantification of Elastic, Plastic and Creep Properties via Microscale Testing CX(s) Applied: B3.6 Date: 11/18/2013 Location(s): Arizona Offices(s): Idaho Operations Office

387

IAEA-TECDOC-1450 Thorium fuel cycle --Potential  

E-Print Network [OSTI]

in liquid metal cooled fast breeder reactor (LMFBR) and for neutron flux flattening of the initial core neutron reactor has been recognized. Several experimental and prototype power reactors were successfully operated during the mid 1950s to the mid 1970s using (Th, U)O2 and (Th, U)C2 fuels in high temperature gas

Laughlin, Robert B.

388

Rational Ligand Design for U(VI) and Pu(IV)  

E-Print Network [OSTI]

Murali, M. S. ; Nash, K. L. Solv. Extr. Ion Exch. 2001, 19,D. C. ; Raymond, K. N. Solv. Extr. Ion Exch. 2004, 22, (22)DMF) and UO 2 (bis-Me-3,2-HOPO)(solv) tabulated in Table 2-

Szigethy, Geza

2010-01-01T23:59:59.000Z

389

Radiative heat transfer in porous uranium dioxide  

SciTech Connect (OSTI)

Due to low thermal conductivity and high emissivity of UO{sub 2}, it has been suggested that radiative heat transfer may play a significant role in heat transfer through pores of UO{sub 2} fuel. This possibility was computationally investigated and contribution of radiative heat transfer within pores to overall heat transport in porous UO{sub 2} quantified. A repeating unit cell was developed to model approximately a porous UO{sub 2} fuel system, and the heat transfer through unit cells representing a wide variety of fuel conditions was calculated using a finite element computer program. Conduction through solid fuel matrix as wekk as pore gas, and radiative exchange at pore surface was incorporated. A variety of pore compositions were investigated: porosity, pore size, shape and orientation, temperature, and temperature gradient. Calculations were made in which pore surface radiation was both modeled and neglected. The difference between yielding the integral contribution of radiative heat transfer mechanism to overall heat transport. Results indicate that radiative component of heat transfer within pores is small for conditions representative of light water reactor fuel, typically less than 1% of total heat transport. It is much larger, however, for conditions present in liquid metal fast breeder reactor fuel; during restructuring of this fuel type early in life, the radiative heat transfer mode was shown to contribute as much as 10-20% of total heat transport in hottest regions of fuel.

Hayes, S.L. [Texas A and M Univ., College Station, TX (United States)] [Texas A and M Univ., College Station, TX (United States)

1992-12-01T23:59:59.000Z

390

Reactivity initiated accident test series Test RIA 1-4 fuel behavior report. [PWR; BWR  

SciTech Connect (OSTI)

This report presents and discusses results from the final test in the Reactivity Initiated Accident (RIA) Test Series, Test RIA 1-4, conducted in the Power Burst Facility (PBF) at the Idaho National Engineering Laboratory. Nine preirradiated fuel rods in a 3 x 3 bundle configuration were subjected to a power burst while at boiling water reactor hot-startup system conditions. The test resulted in estimated axial peak, radial average fuel enthalpies of 234 cal/g UO/sub 2/ on the center rod, 255 cal/g UO/sub 2/ on the side rods, and 277 cal/g UO/sub 2/ on the corner rods. Test RIA 1-4 was conducted to investigate fuel coolability and channel blockage within a bundle of preirradiated rods near the present enthalpy limit of 280 cal/g UO/sub 2/ established by the US Nuclear Regulatory Commission. The test design and conduct are described, and the bundle and individual rod thermal and mechanical responses are evaluated. Conclusions from this final test and the entire PBF RIA Test Series are presented.

Cook, B.A.; Martinson, Z.R.

1984-09-01T23:59:59.000Z

391

GEOBULLETIN SEpTEmBEr 19Th  

E-Print Network [OSTI]

are requested! If you have a news item, a request, an announcement etc. email it to geodept@geology on the oxidation state of uranium, therefore understanding the mechanisms of UO2 oxidative corrosion is essential-classical diffusion is driven by electron transfer from multiple uranium atoms to each interstitial #12;GEOBULLETIN

Carlson, Anders

392

E-Print Network 3.0 - alkaline phosphate wastes Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

aqueous UO2(PO4)n 2-3n (n > 1) and mixed hydroxide-phosphate... Effects of Phosphate on Uranium(VI) Adsorption to Goethite-Coated Sand T A O C H E N G , M A R K O... -0206...

393

Radiochim. Acta 93, 265272 (2005) by Oldenbourg Wissenschaftsverlag, Mnchen  

E-Print Network [OSTI]

characterization of uranium(VI) silicate solids and associated neptunium(V) By Matthew Douglas1 , Sue B. Clark1 in revised form October 16, 2004) Uranyl / Solid solution / Spent nuclear fuel / Uranium minerals / Uranophane Summary. The uranium(VI) silicate phases urano- phane, Ca[(UO2)(SiO3OH)]2 ·5H2O, and sodium

Utsunomiya, Satoshi

394

Nanocrystalline Metals Andy Howe, Corus RD&T  

E-Print Network [OSTI]

for single phase polygonal structures · Concentrate on refinement of dual phase structures ­ Dual Phase & with the emphasis on steel! Andy Howe, Corus RD&T Super Bainite Workshop, 6/05/2010 #12;Outline · Ultra-fine Ferrite iron to whatever strength you want! FIB-cut and imaged sub-micron IF steel Corus ­ UoManchester +FEI

Cambridge, University of

395

Incorporation of radionuclides in the alteration phases of spent nuclear fuel.  

SciTech Connect (OSTI)

Alteration may be expected for spent nuclear fuel exposed to groundwater under oxidizing conditions such as that which exist at the proposed nuclear waste repository at Yucca Mountain, Nevada. The actinide elements released during the corrosion of spent fuel may be incorporated into the structures of secondary U{sup 6+} phases. The incorporation of transuranics into the crystal structures of the alteration products may significantly decrease their mobility. A series of precipitation tests were conducted at 90 C to determine the potential incorporation of Ce{sup 4+} and Nd{sup 3+} (surrogates for Pu{sup 4+} and Am{sup 3+}, respectively) into uranyl phase. Dehydrated schoepite (UO{sub 3}{center_dot}0.8-1.0HP{sub 2}O) was produced by hydrolysis of a uranium oxyacetate solution containing either cerium or neodymium. ICP-MS analysis of the leachant, leachate, and solid phase reaction products which were dissolved in a HNO{sub 3} solution indicates that 26 ppm of Ce was incorporated into dehydrated schoepite. ICP-MS results from the Nd-doped tests indicate significant neodymium incorporation as well, however, the heterogeneous distribution of Nd in the solid phase noted during the AEM/EELS examination implies that neodymium may not incorporate into the structure of dehydrated schoepite.

Buck, E. C.; Kim, C.-W.; Wronkiewicz, D. J.

1999-08-25T23:59:59.000Z

396

2.5 5.0 7.5 10.0 12.5 15.0 RIC all gcms#2.ms  

E-Print Network [OSTI]

200 300 400 500 kCounts 0 100 200 300 kCounts RIC all gcms#2.ms RIC all gcms#1.ms Flash pyrolysis GCMS from biomass. Biomass is easily transformed into char; however, the process leads to loss introduces a significant enrichment of 13 C in plant material. Pyrolysis of carbohydrates: Lignin Lignin

397

Handbook of M.S. Programs -Industrial & Systems Engineering Department, Wayne State University Revised: May 8, 2013 Pg. 1 of 10  

E-Print Network [OSTI]

Handbook of M.S. Programs - Industrial & Systems Engineering Department, Wayne State University Revised: May 8, 2013 Pg. 1 of 10 M.S. Programs Handbook Industrial & Systems Engineering Department Wayne Engineering at Wayne State University: Master of Science in Industrial Engineering Master of Science

Berdichevsky, Victor

398

Web Site: http://www.coop-program.engr.uga.edu/ms.html UGA Cooperative Engineering Program Development Key Points and Notes.docx  

E-Print Network [OSTI]

Web Site: http://www.coop-program.engr.uga.edu/ms.html UGA Cooperative Engineering Program;Web Site: http://www.coop-program.engr.uga.edu/ms.html UGA Cooperative Engineering Program Development Development Key Points and Notes.docx Latest Update: October 3, 2012 Mission Statement: The UGA Engineering

Arnold, Jonathan

399

Surface Cleaning Techniques: Ultra-Trace ICP-MS Sample Preparation and Assay of HDPE  

SciTech Connect (OSTI)

The world’s most sensitive radiation detection and assay systems depend upon ultra-low background (ULB) materials to reduce unwanted radiological backgrounds. Herein, we evaluate methods to clean HDPE, a material of interest to ULB systems and the means to provide rapid assay of surface and bulk contamination. ULB level material and ultra-trace level detection of actinide elements is difficult to attain, due to the introduction of contamination from sample preparation equipment such as pipette tips, sample vials, forceps, etc. and airborne particulate. To date, literature available on the cleaning of such polymeric materials and equipment for ULB applications and ultra-trace analyses is limited. For these reasons, a study has been performed to identify an effective way to remove surface contamination from polymers in an effort to provide improved instrumental detection limits. Inductively Coupled Plasma Mass Spectroscopy (ICP-MS) was utilized to assess the effectiveness of a variety of leachate solutions for removal of inorganic uranium and thorium surface contamination from polymers, specifically high density polyethylene (HDPE). HDPE leaching procedures were tested to optimize contaminant removal of thorium and uranium. Calibration curves for thorium and uranium ranged from 15 ppq (fg/mL) to 1 ppt (pg/mL). Detection limits were calculated at 6 ppq for uranium and 7 ppq for thorium. Results showed the most effective leaching reagent to be clean 6 M nitric acid for 72 hour exposures. Contamination levels for uranium and thorium found in the leachate solutions were significant for ultralow level radiation detection applications.

Overman, Nicole R.; Hoppe, Eric W.; Addleman, Raymond S.

2013-06-01T23:59:59.000Z

400

Project Final Report: Ubiquitous Computing and Monitoring System (UCoMS) for Discovery and Management of Energy Resources  

SciTech Connect (OSTI)

The UCoMS research cluster has spearheaded three research areas since August 2004, including wireless and sensor networks, Grid computing, and petroleum applications. The primary goals of UCoMS research are three-fold: (1) creating new knowledge to push forward the technology forefronts on pertinent research on the computing and monitoring aspects of energy resource management, (2) developing and disseminating software codes and toolkits for the research community and the public, and (3) establishing system prototypes and testbeds for evaluating innovative techniques and methods. Substantial progress and diverse accomplishment have been made by research investigators in their respective areas of expertise cooperatively on such topics as sensors and sensor networks, wireless communication and systems, computational Grids, particularly relevant to petroleum applications.

Tzeng, Nian-Feng; White, Christopher D.; Moreman, Douglas

2012-07-14T23:59:59.000Z

Note: This page contains sample records for the topic "ms uo uo" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Validation of Electrochemically Modulated Separations Performed On-Line with MC-ICP-MS for Uranium and Plutonium Isotopic Analyses  

SciTech Connect (OSTI)

The most time consuming process in uranium or plutonium isotopic analyses is performing the requisite chromatographic separation of the actinides. Filament preparation for thermal ionization (TIMS) adds further delays, but is generally accepted due to the unmatched performance in trace isotopic analyses. Advances in Multi-Collector Inductively Coupled Plasma Mass Spectrometry (MC-ICP-MS) are beginning to rival the performance of TIMS. Methods, such as Electrochemically Modulated Separations (EMS) can efficiently pre-concentrate U or Pu quite selectively from small solution volumes in a matrix of 0.5 M nitric acid. When performed in-line with ICP-MS, the rapid analyte release from the electrode is fast, and large transient analyte signal enhancements of >100 fold can be achieved as compared to more conventional continuous nebulization of the original starting solution. This makes the approach ideal for very low level isotope ratio measurements. In this paper, some aspects of EMS performance are described. These include low level Pu isotope ratio behavior versus concentration by MC-ICP-MS and uranium rejection characteristics that are also important for reliable low level Pu isotope ratio determinations.

Liezers, Martin; Olsen, Khris B.; Mitroshkov, Alexandre V.; Duckworth, Douglas C.

2010-08-11T23:59:59.000Z

402

Yucca Mountain Project - Argonne National Laboratory annual progress report, FY 1994  

SciTech Connect (OSTI)

This document reports on the work done by the Nuclear Waste Management Section of the Chemical Technology Division (CMT), Argonne National Laboratory, in the period October 1993-September 1994. Studies have been performed to evaluate the performance of nuclear waste glass and spent fuel samples under unsaturated conditions (low volume water contact) that are likely to exist in the Yucca Mountain environment being considered as a potential site for a high-level waste repository. Tests with simulated waste glasses have been in progress for over eight years and demonstrate that actinides from initially fresh glass surfaces will be released as a result of the spallation of reacted glass layers from the surface, as the small volume of water passes over the waste form. Studies are also underway to evaluate the performance of spent fuel samples and unirradiated UO{sub 2} in projected repository conditions. Tests with UO{sub 2} have been ongoing for nine years and show that the oxidation of UO{sub 2} occurs rapidly, and the resulting paragenetic sequence of secondary phases that form on the sample surface is similar to that observed in natural analogues. The reaction of spent fuel samples under conditions similar to those used with UO{sub 2} have been in progress for nearly two years, and the results suggest that spent fuel follows the same reaction progress as UO{sub 2}. The release of individual fission products and transuranic elements was not congruent, with the release being controlled by the formation of small particles or colloids that are suspended in solution and transported away from the waste form. The reaction progress depends on the composition of the spent fuel samples used and, likely, on the composition of the groundwater that contacts the waste form.

Bates, J.K.; Fortner, J.A.; Finn, P.A.; Wronkiewicz, D.J.; Hoh, J.C.; Emery, J.W.; Buck, E.C.; Wolf, S.F.

1995-02-01T23:59:59.000Z

403

New insights into uranium (VI) sol-gel processing  

SciTech Connect (OSTI)

Nuclear Magnetic Resonance (NMR) investigations on the Oak Ridge National Laboratory process for sol-gel synthesis of microspherical nuclear fuel (UO{sub 2}), has been extremely useful in sorting out the chemical mechanism in the sol-gel steps. {sup 13}C, {sup 15}N, and {sup 1}H NMR studies on the HMTA gelation agent (Hexamethylene tetramine, C{sub 6}H{sub 12}N{sub 4}) has revealed near quantitative stability of this adamantane-like compound in the sol-gel process, contrary to its historical role as an ammonia source for gelation from the worldwide technical literature. {sup 17}O NMR of uranyl (UO{sub 2}{sup ++}) hydrolysis fragments produced in colloidal sols has revealed the selective formation of a uranyl trimer, ((UO{sub 2}){sub 3}({mu}{sub 3}-O)({mu}{sub 2}-OH){sub 3}){sup +}, induced by basic hydrolysis with the HMTA gelation agent. Spectroscopic results will be presented to illustrate that trimer condensation occurs during sol-gel processing leading to layered polyanionic hydrous uranium oxides in which HMTAH{sup +} is occluded as an intercalation'' cation. Subsequent sol-gel processing of microspheres by ammonia washing results in in-situ exchange and formation of a layered hydrous ammonium uranate with a proposed structural formula of (NH{sub 4}){sub 2} ((UO{sub 2}){sub 8} O{sub 4} (OH){sub 10}) {center dot} 8H{sub 2}O. This compound is the precursor to sintered UO{sub 2} ceramic fuel. 23 refs., 10 figs.

King, C.M.; Thompson, M.C.; Buchanan, B.R. (Westinghouse Savannah River Co., Aiken, SC (USA)); King, R.B. (Georgia Univ., Athens, GA (USA). Dept. of Chemistry); Garber, A.R. (South Carolina Univ., Columbia, SC (USA). Dept. of Chemistry)

1990-01-01T23:59:59.000Z

404

X-ray Absorption Spectroscopy Identifies Calcium-Uranyl-Carbonate Complexes at Environmental Concentrations  

SciTech Connect (OSTI)

Current research on bioremediation of uranium-contaminated groundwater focuses on supplying indigenous metal-reducing bacteria with the appropriate metabolic requirements to induce microbiological reduction of soluble uranium(VI) to poorly soluble uranium(IV). Recent studies of uranium(VI) bioreduction in the presence of environmentally relevant levels of calcium revealed limited and slowed uranium(VI) reduction and the formation of a Ca-UO2-CO3 complex. However, the stoichiometry of the complex is poorly defined and may be complicated by the presence of a Na-UO2-CO3 complex. Such a complex might exist even at high calcium concentrations, as some UO2-CO3 complexes will still be present. The number of calcium and/or sodium atoms coordinated to a uranyl carbonate complex will determine the net charge of the complex. Such a change in aqueous speciation of uranium(VI) in calcareous groundwater may affect the fate and transport properties of uranium. In this paper, we present the results from X-ray absorption fine structure (XAFS) measurements of a series of solutions containing 50 lM uranium(VI) and 30 mM sodium bicarbonate, with various calcium concentrations of 0-5 mM. Use of the data series reduces the uncertainty in the number of calcium atoms bound to the UO2-CO3 complex to approximately 0.6 and enables spectroscopic identification of the Na-UO2-CO3 complex. At nearly neutral pH values, the numbers of sodium and calcium atoms bound to the uranyl triscarbonate species are found to depend on the calcium concentration, as predicted by speciation calculations.

Kelly, Shelly D [Argonne National Laboratory (ANL); Kemner, Kenneth M [Argonne National Laboratory (ANL); Brooks, Scott C [ORNL

2007-01-01T23:59:59.000Z

405

Capsule HRB-15B postirradiation examination report  

SciTech Connect (OSTI)

Capsule HRB-15B design tested 184 thin graphite trays containing unbonded fuel particles to peak exposures of 6.6 x 10/sup 25/ n/m/sup 2/ (E > 29 fJ)/sub HTGR/ fast fluence, approx. 27% fissions per initial metal atom (FIMA) fissile burnup, and 6% FIMA fertile burnup at nominal time-averaged temperatures of 815 to 915/sup 0/C. The capsule tested a variety of low-enriched uranium (approx. 19.5% U-235) fissile particle types, including UC/sub 2/, UC/sub x/O/sub y/, UO/sub 2/, zirconium-buffered UO/sub 2/ (referred to in this report as UO/sub 2//sup *), and 1:1(Th,U)O/sub 2/ with both TRISO and silicon-BISO coatings. All fertile particles were ThO/sub 2/ with BISO, silicon-BISO, or TRISO coatings. The findings indicated that all TRISO particles retained virtually all of their fission product inventories, except small quantities of silver, at these irradiation temperatures, while some of the silicon-BISO particles released significant amounts of both silver and cesium. No kernel migration, pressure vessel, or outer pyrolytic carbon (OPyC) failures were observed in the fuel particles, which had total diameters of < 900 ..mu..m; however, the incidence of failed OPyC coatings was found to increase with particle size in the TRISO inert particles, which had diameters of 1000 to 1200 ..mu..m. UO/sub 2//sup */ particles exhibited no detrimental irradiation effects, but they contained pure carbon precipitates in the kernels after irradiation which were not observed in the undoped UO/sub 2/ particles. Postirradiation examination revealed no differences in the irradiation performance of three UC/sub x/O/sub y/ kernel types with varying oxygen/uranium ratios.

Ketterer, J.W.; Bullock, R.E.

1981-06-01T23:59:59.000Z

406

Modeling and analyses of postulated UF{sub 6} release accidents in gaseous diffusion plant  

SciTech Connect (OSTI)

Computer models have been developed to simulate the transient behavior of aerosols and vapors as a result of a postulated accident involving the release of uranium hexafluoride (UF{sub 6}) into the process building of a gaseous diffusion plant. UF{sub 6} undergoes an exothermic chemical reaction with moisture (H{sub 2}O) in the air to form hydrogen fluoride (HF) and radioactive uranyl fluoride (UO{sub 2}F{sub 2}). As part of a facility-wide safety evaluation, this study evaluated source terms consisting of UO{sub 2}F{sub 2} as well as HF during a postulated UF{sub 6} release accident in a process building. In the postulated accident scenario, {approximately}7900 kg (17,500 lb) of hot UF{sub 6} vapor is released over a 5 min period from the process piping into the atmosphere of a large process building. UO{sub 2}F{sub 2} mainly remains as airborne-solid particles (aerosols), and HF is in a vapor form. Some UO{sub 2}F{sub 2} aerosols are removed from the air flow due to gravitational settling. The HF and the remaining UO{sub 2}F{sub 2} are mixed with air and exhausted through the building ventilation system. The MELCOR computer code was selected for simulating aerosols and vapor transport in the process building. MELCOR model was first used to develop a single volume representation of a process building and its results were compared with those from past lumped parameter models specifically developed for studying UF{sub 6} release accidents. Preliminary results indicate that MELCOR predicted results (using a lumped formulation) are comparable with those from previously developed models.

Kim, S.H.; Taleyarkhan, R.P.; Keith, K.D.; Schmidt, R.W. [Oak Ridge National Lab., TN (United States); Carter, J.C. [J.C. Carter Associates, Inc., Oak Ridge, TN (United States); Dyer, R.H. [Dyer Enterprises, Oak Ridge, TN (United States)

1995-10-01T23:59:59.000Z

407

Calculation of Stochasticity from Topological Noise in the DIII-D Shot 115467 3000 ms  

SciTech Connect (OSTI)

An area-preserving map in magnetic coordinates is derived from Hamiltonian equations of motion for magnetic field lines using an infinitesimal canonical transformation of second type. The map generating function for the field lines in the DIII-D is calculated from the experimental data for the shot 115467 at 3000 ms. The poloidal magnetic flux, {chi}, is the Hamiltonian for field lines. The equilibrium Hamiltonian function for the DIII-D, {chi}0, is calculated from the shot data as a piece-wise defined function of toroidal flux, {psi}. For 0{<=}{psi}{<=}{psi}1, safety factor q increases monotonically to the value 5. For {psi}1{<=}{psi}{<=}{psi}sep, the safety factor increases logarithmically without limit. {psi}sep is the toroidal flux inside separatrix in the DII-D. The logarithmic singularity is symmetric about the separatrix. The singular region contains 5% of toroidal flux, and 0.87% of poloidal flux inside the separatrix in the DIII-D shot. In the open field line region outside the separatrix, q is defined by the distance a field line requires to go from its first to its second close approach to the X-point. In this region, the safety factor first decreases to the value 3.8, and then increases. Stochasticity caused by topological noise in the DIII-D shot is calculated using this map. Topological noise consists of modes (m,n) = {l_brace}(3,1), (4,1), (6,2), (7,2), (8,2), (9,3), (10,3), (11,3), (12,3){r_brace} with each amplitude equals to 0.8x10-5. Topological noise creates two very narrow layers of stochasticity. One is inside the separatrix and another is outside the separatrix. From the equilibrium data, a transformation from magnetic coordinates to the DIII-D (R,Z,{phi}) coordinates is calculated. This transformation is used to calculate stochasticity in physical space. Preliminary results of this investigation are presented. This work is supported by DE-FG02-01ER54624 and DE-FG02-04ER54793.

Punjabi, Alkesh; Ali, Halima [Hampton University, Hampton, Virginia 23668 (United States); Evans, Todd [General Atomics, San Diego, California 92186 (United States); Boozer, Allen [Columbia University, New York, New York 10027 (United States)

2006-11-30T23:59:59.000Z

408

Aufgabe 3-7: Luft tritt mit 1 = 2,21 kg/m und v1 = 40 m/s kontinuierlich in eine Dse ein und verlsst diese mit 2 = 0,762 kg/m und v2 = 180 m/s. Die Einlassflche der Dse betrgt 90  

E-Print Network [OSTI]

Aufgabe 3-7: Luft tritt mit 1 = 2,21 kg/m³ und v1 = 40 m/s kontinuierlich in eine Düse ein und, 800 kPa) tritt mit 10 m/s in eine Düse ein (siehe Abbildung 1). In der Düse verliert der Dampf Wärme

Peters, Norbert

409

TECHBOOKS Journal: AGAG MS Code: 529 PIPS No: 5271116 DISK 1-4-2004 18:38 Pages: 43 Annals of Global Analysis and Geometry xxx: 143, 2004.  

E-Print Network [OSTI]

UNCO RRECTED PRO O F TECHBOOKS Journal: AGAG MS Code: 529 PIPS No: 5271116 DISK 1-4-2004 18 et Phys. Parc de Grandmont, 37200 Tours, France. e-mail: belaud@univ-tours.fr 5 6 (Received: 25

Belaud, Yves

410

{sup 99}Tc bioassay: A direct comparison of liquid scintillation radiation detection and ICP-MS mass detection of the {sup 99}Tc isotope  

SciTech Connect (OSTI)

A means of analyzing {sup 99}Tc in urine by inductively coupled plasma mass spectrometry (ICP-MS) has been developed. Historically, {sup 99}Tc analysis was based on the radiometric detection of the 293 keV E{sub Max.} beta decay product by liquid scintillation or gas flow proportional counting. A separation scheme for {sup 99}Tc detection by ICP-MS is given and is proven to be a sensitive and robust analytical alternative. A comparison of methods using radiometric and mass quantitation of {sup 99}Tc has been conducted in water, artificial urine, and real urine matrices at activity levels between 700 and 2,200 dpm/L. Liquid scintillation results based on an external standard manual quench correction and an automatic quench curve correction method are compared with results obtained by ICP-MS. Each method produced accurate results; however, the precision of the ICP-MS results is superior to that of liquid scintillation results.

Lewis, L.A. [Lockheed Martin Energy Systems, Inc., Oak Ridge, TN (United States). Analytical Services Organization; Schweitzer, G.K. [Univ. of Tennessee, Knoxville, TN (United States). Dept. of Chemistry

1998-12-31T23:59:59.000Z

411

A 12b 50MS/s 2.1mW SAR ADC with redundancy and digital background calibration  

E-Print Network [OSTI]

A 12-bit 50MS/s SAR ADC implemented in 65nm CMOS technology is presented. The design employs redundancy to relax the DAC settling requirement and to provide sufficient room for errors such that the static nonlinearity ...

Chang, Albert H.

412

Measurement of elemental speciation by liquid chromatography -- inductively coupled plasma mass spectrometry (LC-ICP-MS) with the direct injection nebulizer (DIN)  

SciTech Connect (OSTI)

This thesis is divided into 4 parts: elemental speciation, speciation of mercury and lead compounds by microbore column LC-ICP-MS with direct injection nebulization, spatially resolved measurements of size and velocity distributions of aerosol droplets from a direct injection nebulizer, and elemental speciation by anion exchange and size exclusion chromatography with detection by ICP-MS with direct injection nebulization. Tabs, figs, refs.

Shum, S.

1993-05-01T23:59:59.000Z

413

Precise ruthenium fission product isotopic analysis using dynamic reaction cell inductively coupled plasma mass spectrometry (DRC-ICP-MS)  

SciTech Connect (OSTI)

99Tc is a subsurface contaminant of interest at numerous federal, industrial, and international facilities. However, as a mono-isotopic fission product, 99Tc lacks the ability to be used as a signature to differentiate between the different waste disposal pathways that could have contributed to subsurface contamination at these facilities. Ruthenium fission-product isotopes are attractive analogues for the characterization of 99Tc sources because of their direct similarity to technetium with regard to subsurface mobility, and their large fission yields and low natural background concentrations. We developed an inductively coupled plasma mass spectrometry (ICP-MS) method capable of measuring ruthenium isotopes in groundwater samples and extracts of vadose zone sediments. Samples were analyzed directly on a Perkin Elmer ELAN DRC II ICP-MS after a single pass through a 1-ml bed volume of Dowex AG 50W-X8 100-200 mesh cation exchange resin. Precise ruthenium isotopic ratio measurements were achieved using a low-flow Meinhard-type nebulizer and long sample acquisition times (150,000 ms). Relative standard deviations of triplicate replicates were maintained at less than 0.5% when the total ruthenium solution concentration was 0.1 ng/ml or higher. Further work was performed to minimize the impact caused by mass interferences using the dynamic reaction cell (DRC) with O2 as the reaction gas. The aqueous concentrations of 96Mo and 96Zr were reduced by more than 99.7% in the reaction cell prior to injection of the sample into the mass analyzer quadrupole. The DRC was used in combination with stable-mass correction to quantitatively analyze samples containing up to 2-orders of magnitude more zirconium and molybdenum than ruthenium. The analytical approach documented herein provides an efficient and cost-effective way to precisely measure ruthenium isotopes and quantitate total ruthenium (natural vs. fission-product) in aqueous matrixes.

Brown, Christopher F.; Dresel, P. Evan; Geiszler, Keith N.; Farmer, Orville T.

2006-05-09T23:59:59.000Z

414

GC/MS characterization of condensable tars in the output stream of a stirred fixed-bed gasifier  

SciTech Connect (OSTI)

The output stream of the stirred fixed-bed gasifier at the Morgantown Energy Technology Center was sampled for total entrained material. A major portion of the entrained material, in addition to particles, is condensable tar that is subsequently removed from the process gas by wet scrubbing. Characterization of the entrained materials, specifically the tar, is important to establish contaminant levels and to evaluate performance of downstream cleanup units. Samples of tars were collected from the process unit in a combined ice, dry ice, and liquid nitrogen sampler and stored in a refrigerator. The tar samples were then separated into asphaltene, neutral oil, tar acid, and base fractions by solvent extraction using toluene, pentane, sulfuric acid, and potassium hydroxide extraction. Characterization of the fractions obtained from these tars include IR, UV, GC, and GC/MS analysis. The mass spectrometer analysis of the various isolates shows that many individual peaks in the gas chromatograph are in fact mixtures that can be readily identified by the mass spectrometer. It was found that many of the species identified in these fractions were members of aromatic homologous series consisting of parent, mono, di, and tri substituted compounds. Compound identification was made by comparison of the data system library and standard reference spectra. This paper will discuss the instrumental approach and limitation of the GC/MS and the results of the characterization studies of entrained hydrocarbons collected from the gasifier stream.

Lamey, S.C.; McCaskill, K.B.; Smith, R.R.

1981-12-01T23:59:59.000Z

415

Standard test method for determination of impurities in nuclear grade uranium compounds by inductively coupled plasma mass spectrometry  

E-Print Network [OSTI]

1.1 This test method covers the determination of 67 elements in uranium dioxide samples and nuclear grade uranium compounds and solutions without matrix separation by inductively coupled plasma mass spectrometry (ICP-MS). The elements are listed in Table 1. These elements can also be determined in uranyl nitrate hexahydrate (UNH), uranium hexafluoride (UF6), triuranium octoxide (U3O8) and uranium trioxide (UO3) if these compounds are treated and converted to the same uranium concentration solution. 1.2 The elements boron, sodium, silicon, phosphorus, potassium, calcium and iron can be determined using different techniques. The analyst's instrumentation will determine which procedure is chosen for the analysis. 1.3 The test method for technetium-99 is given in Annex A1. 1.4 The values stated in SI units are to be regarded as standard. 1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish ...

American Society for Testing and Materials. Philadelphia

2010-01-01T23:59:59.000Z

416

Uranyl fluoride luminescence in acidic aqueous solutions  

SciTech Connect (OSTI)

Luminescence emission spectra and decay rates are reported for uranyl species in acidic aqueous solutions containing HF or added NaF. The longest luminescence lifetime, 0.269 {+-} 0.006 ms, was observed from uranyl in 1 M HF + 1 M HClO{sub 4} at 296 K and decreased with increasing temperature. Based on a luminescence dynamics model that assumes equilibrium among electronically excited uranyl fluoride species and free fluoride ion, this long lived uranyl luminescence in aqueous solution is attributed primarily to UO{sub 2}F{sub 2}. Studies on the effect of added LiNO{sub 3} or Na{sub 2}WO{sub 4}{center_dot}2H{sub 2}O showed relatively weak quenching of uranyl fluoride luminescence which suggests that high sensitivity determination of the UF{sub 6} content of WF{sub 6} gas should be feasible via uranyl luminescence analysis of hydrolyzed gas samples of impure WF{sub 6}.

Beitz, J.V.; Williams, C.W. [Argonne National Lab., IL (United States). Chemistry Div.

1996-08-01T23:59:59.000Z

417

The Plant Cell, Vol. 7, 759-771, June 1995 O 1995 American Society of Plant Physiologists cycMs3, a Nove1 B-Type Alfalfa Cyclin Gene, 1s lnduced  

E-Print Network [OSTI]

, a Nove1 B-Type Alfalfa Cyclin Gene, 1s lnduced the Go-to-G1 Transition of the Cell Cycle in lrute in all eukaryotes. We have previously isolated two B-type cyclin genes, cycMs7 and cycMs2, from alfalfa report the isolation of a nove1alfalfa cyclin gene, termed cycMs3 (for Xclin Medicago sativa

Hirt, Heribert

418

Health Outreach Program to Educate (HOPE) Palo Alto Shane Morrison, MS1, Krishnan Subrahmanian, MPhil1, Shah Ali, BA1, and Lars Osterberg, MD, MPH2  

E-Print Network [OSTI]

Health Outreach Program to Educate (HOPE) Palo Alto Shane Morrison, MS1, Krishnan Subrahmanian, Stanford University medical students started Health Outreach Program to Educate (HOPE) Palo Alto to this population of patients.4,5 Current strategies to increase health literacy amongst low-income patients through

Kay, Mark A.

419

INI Policies & Procedures MS20 02/05/09 The Policies and Procedures detailed on this page apply only to students entering the MSIN,  

E-Print Network [OSTI]

INI Policies & Procedures ­ MS20 ­ 02/05/09 The Policies and Procedures detailed on this page apply. These policies are subject to change and/or modifications and do not constitute a contract. I. INI DEGREE. TUITION VII. OTHER UNIVERSITY POLICIES VIII. INI NON-ACADEMIC POLICIES IX. OTHER POLICIES X. MISCELLANEOUS

Tague, Patrick

420

INI Policies & Procedures MS18 8/09/06 The information provided in this policy guide is intended to summarize the rules of the INI MSIN,  

E-Print Network [OSTI]

INI Policies & Procedures ­ MS18 ­ 8/09/06 The information provided in this policy guide is intended to summarize the rules of the INI MSIN, Athens MSIN, MSISTM, and Carnegie Mellon CyLab Japan MSIT a contract. I. INI DEGREE REQUIREMENTS II. COURSE ENROLLMENT III. REGISTRATION PROCEDURES IV. GRADES V

Tague, Patrick

Note: This page contains sample records for the topic "ms uo uo" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

INI Policies & Procedures MS17 8/31/05 Note: There has been a correction to the policy. INI students may take graduate courses in  

E-Print Network [OSTI]

INI Policies & Procedures ­ MS17 ­ 8/31/05 Note: There has been a correction to the policy. INI. The information provided in this policy guide is intended to summarize the rules of the INI MSIN, Athens MSIN and/or modifications and do not constitute a contract. I. INI DEGREE REQUIREMENTS II. COURSE

Tague, Patrick

422

A Statistical Selection Strategy for Normalization Procedures in LC-MS Proteomics Experiments through Dataset Dependent Ranking of Normalization Scaling Factors  

SciTech Connect (OSTI)

Quantification of LC-MS peak intensities assigned during peptide identification in a typical comparative proteomics experiment will deviate from run-to-run of the instrument due to both technical and biological variation. Thus, normalization of peak intensities across a LC-MS proteomics dataset is a fundamental step in pre-processing. However, the downstream analysis of LC-MS proteomics data can be dramatically affected by the normalization method selected . Current normalization procedures for LC-MS proteomics data are presented in the context of normalization values derived from subsets of the full collection of identified peptides. The distribution of these normalization values is unknown a priori. If they are not independent from the biological factors associated with the experiment the normalization process can introduce bias into the data, which will affect downstream statistical biomarker discovery. We present a novel approach to evaluate normalization strategies, where a normalization strategy includes the peptide selection component associated with the derivation of normalization values. Our approach evaluates the effect of normalization on the between-group variance structure in order to identify candidate normalization strategies that improve the structure of the data without introducing bias into the normalized peak intensities.

Webb-Robertson, Bobbie-Jo M.; Matzke, Melissa M.; Jacobs, Jon M.; Pounds, Joel G.; Waters, Katrina M.

2011-12-01T23:59:59.000Z

423

July 2013 M.S. in Genetics -University of A Corua, A Corua, Spain June 2012 B.S. in Biology -University of A Corua, A Corua, Spain  

E-Print Network [OSTI]

EDUCATION July 2013 M.S. in Genetics - University of A Coruña, A Coruña, Spain June 2012 B.S. in Biology - University of A Coruña, A Coruña, Spain RESEARCH INTERESTS Marine Biology, Genotoxicology, Chromosomal Proteins, Molecular Evolution, Genomics, Molecular Techniques. 2011 University of A Coruña, Spain

Eirin Lopez, Jose Maria

424

The Institute for Integrated Cell-Material Sciences (iCeMS) was founded in 2007 as part of a government program called the World Premier International  

E-Print Network [OSTI]

, Sports, Science and Technology (MEXT) of Japan. The fund provides a total of 6 million dollars per year science. iCeMS is one of nine WPI centers throughout Japan and boasts eighteen world-renowned principal investigators, who are leading experts in cell biology, chemistry, and physics. Notably, Kyoto University Center

Takada, Shoji

425

Hausaufgabe 9: Aufgabe 4-6: Wasserdampf tritt im Zustand 1 (600C, 7 MPa, 80 m/s) in eine Turbine ein  

E-Print Network [OSTI]

Hausaufgabe 9: Aufgabe 4-6: Wasserdampf tritt im Zustand 1 (600°C, 7 MPa, 80 m/s) in eine Turbine) Den isentropen Wirkungsgrad des Turbine Aufgabe 4-7: Luft im Zustand 1 (17°C, 100 kPa, 2,4 m³/s) tritt

Peters, Norbert

426

December 19, 2006 19:23 WSPC -Proceedings Trim Size: 9in x 6in ms RECONSTRUCTION OF NONLINEAR FORCE-FREE  

E-Print Network [OSTI]

fields around sunspots provide the energy for large scale solar activity, in particular solar flares FORCE-FREE FIELDS AND SOLAR FLARE PREDICTION M.S. WHEATLAND School of Physics, The University of Sydney, NSW 2006, Australia A brief review is presented of methods for calculating nonlinear force-free fields

Wheatland, Michael S.

427

New features in the NIST MS Search Program (version 2.0g) for the 2011 Version of the NIST/EPA/NIH Mass Spectral Library (NIST 11)  

E-Print Network [OSTI]

New features in the NIST MS Search Program (version 2.0g) for the 2011 Version of the NIST/EPA/NIH Mass Spectral Library (NIST 11) 1. Search for exact precursor mass in the NIST/EPA/NIH Mass Spectral

428

The MS-Q Force Field for Clay Minerals: Application to Oil Production Sungu Hwang, Mario Blanco, Ersan Demiralp, Tahir Cagin, and William A. Goddard, III*  

E-Print Network [OSTI]

in studying oil production chemicals, including corrosion inhibitors,11 scale inhibitors,12 and dissolvers.13 and corrosion inhibition). Among the minerals present in the walls of oil reservoirs, clay minerals are believedThe MS-Q Force Field for Clay Minerals: Application to Oil Production Sungu Hwang, Mario Blanco

Ă?agin, Tahir

429

Quantitative 3-D Elemental Mapping by LA-ICP-MS of a Basaltic Clast from the Hanford 300 Area, Washington, USA  

E-Print Network [OSTI]

Quantitative 3-D Elemental Mapping by LA-ICP-MS of a Basaltic Clast from the Hanford 300 Area collected from the Hanford 300 Area in south-central Washington State, United States. A calibration method and riparian quality in many locations, most notably at the Hanford, Savannah River, Oak Ridge, and Nevada Test

Hu, Qinhong "Max"

430

Lactonization and protonation of gluconic acid: a thermodynamicand kinetic study by potentiometry, nmr and esi-ms  

SciTech Connect (OSTI)

In acidic aqueous solutions, gluconate protonation is coupled with lactonization of gluconic acid. With the decrease of pC{sub H}, two lactones ({delta}/{gamma}) are sequentially formed. The {delta}-lactone forms more readily than the {gamma}-lactone. In 0.1 M gluconate solutions, if pC{sub H} is above 2.5, only the {delta}-lactone is generated. When pC{sub H} is decreased below 2.0, the formation of the {gamma}-lactone is observable although the {delta}-lactone predominates. At I = 0.1 M NaClO{sub 4} and room temperature, the deprotonation constant of the carboxylic group, using the NMR technique, was determined to be log K{sub a} = 3.30 {+-} 0.02; the {delta}-lactonization constant, by the batch potentiometric titrations, was obtained to be log K{sub L} = - (0.54 {+-} 0.04). Using ESI-MS, the rate constants of the {delta}-lactonization and the hydrolysis at pC{sub H} {approx} 5.0 were estimated to be k{sub 1} = 3.2 x 10{sup -5} s{sup -1} and k{sup -1} = 1.1 x 10{sup -4} s{sup -1}, respectively.

Zhang, Z.; Gibson, P.; Clark, S.B.; Tian, G.; Zanonato, P.; Rao, L.

2007-01-10T23:59:59.000Z

431

Validation predictions of a 13 m/s cross-wind fire for Fuego and the University of Waterloo dataset.  

SciTech Connect (OSTI)

Detailed herein are the results of a validation comparison. The experiment involved a 2 meter diameter liquid pool of Jet-A fuel in a 13 m/s crosswind. The scenario included a large cylindrical blocking object just down-stream of the fire. It also included seven smaller calorimeters and extensive instrumentation. The experiments were simulated with Fuego. The model included several conduction regions to model the response of the calorimeters, the floor, and the large cylindrical blocking object. A blind comparison was used to compare the simulation predictions with the experimental data. The more upstream data compared very well with the simulation predictions. The more downstream data did not compare very well with the simulation predictions. Further investigation suggests that features omitted from the original model contributed to the discrepancies. Observations are made with respect to the scenario that are aimed at helping an analyst approach a comparable problem in a way that may help improve the potential for quantitative accuracy.

Brown, Alexander L.; Evans, Gregory Herbert (Sandia National Laboratories, Livermore, CA); Gill, Walter; Jarboe, Daniel T. (Sandia National Laboratories, Livermore, CA)

2008-03-01T23:59:59.000Z

432

Ms. Sharon M. Fiorillo  

Broader source: Energy.gov (indexed) [DOE]

Morgantown, WV 26507 Kathy J. Clinton President Perfor.mance Results Corporation 2605 Cranberry Square Morgantown, WV 26508 Michelle Rodriguez de Varela Whistleblower Program...

433

Beth Aubuchon MS Candidate  

E-Print Network [OSTI]

its exact modes of dispersal · Distance travels byy wind · Potting substances Continuing monitoring.M., Slaughter, G.W., Koike, S.T. 2002. Phytophthora ramorum as the cause of extensive mortality of Quercus spp

Gray, Matthew

434

Is LA-12152-MS  

Office of Scientific and Technical Information (OSTI)

5 PRINCIPLE OF INDEPENDENT ACTION (PIA) AND MULTIAXIAL STRESS FIELDS....? Anistropic Materials 8 Finite Element Implementation 10 A FURTHER DISCUSSION OF THE MEAN UNIT VOLUME...

435

Ms. Mary Hopkins  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas Conchas recovery challenge fundProject8MistakesAdministration AboutMovingNOV 0 1

436

LA-5052-MS  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFunInfraredJeffersonJonathanMultimaterial2 J.N. Shadid,a SANDIAL>

437

LA-10256-MS  

Office of Legacy Management (LM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarlyEnergyDepartment ofDepartment ofof EnergyYou$0.C. 20545*. . : '*I_ - I _ _ _ _

438

LA-983%MS  

Office of Legacy Management (LM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarlyEnergyDepartment ofDepartment ofof EnergyYou$0.C. 20545*. . : '*I_ - I _ _ _ _/p/j ,()i --'

439

MS, II-J  

Office of Legacy Management (LM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarlyEnergyDepartment ofDepartment ofof EnergyYou$ EGcG ENERGYELIkNATIONHEALXH:LTS-S,:?' _.JMOUNDI' ;

440

Is LA-12152-MS  

Office of Scientific and Technical Information (OSTI)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarlyEnergyDepartmentNationalRestart ofMeasuringInformation 9 DefaultDecoding DNAOffice ofTechnicalIs

Note: This page contains sample records for the topic "ms uo uo" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Ms. Maggie Owen, Chair  

Office of Environmental Management (EM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "of EnergyEnergyENERGY TAXBalanced Scorecard Federal2 to: AMilestoneFebruaryMonthlyEnergy9,Ron5, 2013

442

Ms. Maggie Owen, Chair  

Office of Environmental Management (EM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "of EnergyEnergyENERGY TAXBalanced Scorecard Federal2 to: AMilestoneFebruaryMonthlyEnergy9,Ron5, 2013March 7,

443

Ms. Margaret Owen, Chair  

Office of Environmental Management (EM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "of EnergyEnergyENERGY TAXBalanced Scorecard Federal2 to: AMilestoneFebruaryMonthlyEnergy9,Ron5,

444

Ms. Margaret Owen, Chair  

Office of Environmental Management (EM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "of EnergyEnergyENERGY TAXBalanced Scorecard Federal2 to: AMilestoneFebruaryMonthlyEnergy9,Ron5,recommending

445

Ms. Margaret Owen, Chair  

Office of Environmental Management (EM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "of EnergyEnergyENERGY TAXBalanced Scorecard Federal2 to:

446

Ms. Maria Galanti  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

... .... ... ... ..... ..... ...... ... 18 4.5 TRANSFORMER STORAGE PAD ... ... ...... .... .. ...... ...... .....

447

Hagen Maraun MS Candidate  

E-Print Network [OSTI]

for optimization of yield in both cellulose and lignin Introduction ... into cellulose, hemicellulose and lignin Concept of the biorefinery... · Utilize the full potential of lignocellulosic biomass · Making ethanol is only one of many revenues

Gray, Matthew

448

LA-11224-MS  

Office of Scientific and Technical Information (OSTI)

Government or any agency thereof. Los Alarnos National Laboratory os Alarnos,New Mexico 87545 DISCLAIMER This report was prepared as an account of work sponsored by an agency...

449

Naturalistic interpersonal reactions to assertive and unassertive styles  

E-Print Network [OSTI]

sinai awaJ)xa jo asneoaq pa&oaias Ai[ensn os(e aJa~ suogen(ena aug 6uiqew sgoa jqns auj. uogJasse jo s(ana[ &ua~ajjrp Ran 6ugeJgsuowap s(apow qgie sauaos pake(d a[oJ gJous paztlgn peq qojeasaJ sno[naJd aqi aa&Jasse aug uo uo[gjasse jo )oedwl aui... weeks ago, then failed to return them at the next class, thus forcing you to take notes on scrap paper. Now he/she is asking to borrow your notes again. Suppose that the person who borrowed your notes were someone you had only met in class and did...

Paquette, Raymond Joseph

1988-01-01T23:59:59.000Z

450

Depleted uranium hexafluoride: Waste or resource?  

SciTech Connect (OSTI)

the US Department of Energy is evaluating technologies for the storage, disposal, or re-use of depleted uranium hexafluoride (UF{sub 6}). This paper discusses the following options, and provides a technology assessment for each one: (1) conversion to UO{sub 2} for use as mixed oxide duel, (2) conversion to UO{sub 2} to make DUCRETE for a multi-purpose storage container, (3) conversion to depleted uranium metal for use as shielding, (4) conversion to uranium carbide for use as high-temperature gas-cooled reactor (HTGR) fuel. In addition, conversion to U{sub 3}O{sub 8} as an option for long-term storage is discussed.

Schwertz, N.; Zoller, J.; Rosen, R.; Patton, S. [Lawrence Livermore National Lab., CA (United States); Bradley, C. [USDOE Office of Nuclear Energy, Science, Technology, Washington, DC (United States); Murray, A. [SAIC (United States)

1995-07-01T23:59:59.000Z

451

Extraction of Uranium from Aqueous Solutions Using Ionic Liquid and Supercritical Carbon Dioxide in Conjunction  

SciTech Connect (OSTI)

Uranyl ions (UO2)2+ in aqueous nitric acid solutions can be extracted into supercritical CO2 (sc-CO2) via an imidazolium-based ionic liquid using tri-n-butylphosphate (TBP) as a complexing agent. The transfer of uranium from the ionic liquid to the supercritical fluid phase was monitored by UV/Vis spectroscopy using a high-pressure fiberoptic cell. The form of the uranyl complex extracted into the supercritical CO2 phase was found to be UO2(NO3)2(TBP)2. The extraction results were confirmed by UV/Vis spectroscopy and by neutron activation analysis. This technique could potentially be used to extract other actinides for applications in the field of nuclear waste management.

Wang, Joanna S.; Sheaff, Chrystal N.; Yoon, Byunghoon; Addleman, Raymond S.; Wai, Chien M.

2009-01-01T23:59:59.000Z

452

Fast Breeder Blanket Facility FBBF. Annual report, January 1, 1981-December 31, 1981  

SciTech Connect (OSTI)

This annual report contains a summmary of fission rate, spectra, and gamma-ray heating rate measurements made in the first blanket of the Purdue Fast Breeder Blanket Facility. The first blanket consisted of aluminum clad, natural UO/sub 2/ fuel rods with a secondary cladding of stainless steel or aluminum. The blanket was arranged in two concentric regions around the neutron source and converter regions. A neutron diffusion code, 2DB, and a Monte Carlo code, VIM, both using homogeneous cross section groups have been used to calculate the reaction rates. Calculated to experimental values for a number of important reactions are presented. A modified method of applying Bondarenko self-shielding factors to correct for the self shielding of resonance energy neutrons in aluminum, stainless steel and UO/sub 2/ has improved the agreement between the calculations and experiment, but does not account for all of the differences.

Clikeman, F M [ed.] [ed.

1982-07-01T23:59:59.000Z

453

Simulation of the thermodynamic properties of organic extraction solutions  

SciTech Connect (OSTI)

A method is proposed for the simulation of the activity coefficients of the components, the excess volume, the heat of mixing, and other excess thermodynamic functions of organic extraction solutions. The method is based on a search in an assigned region for parameters of the NRTL equations of local composition for which the state of the solution satisfies the requirements of chemical thermodynamics, as well as the assigned recovery criteria. The following binary systems of the solvent-extractant, and solvent-solvate types have been simulated according to the program developed on an ES-1033 computer: C6H/sub 14/-TBP, CHC1/sub 3/-TBP, CC1/sub 4/-TBP, UO/sub 2/(NO/sub 3/)/sub 2/ X 2TBP-TBP, and CC1/sub 4/-UO/sub 2/(NO/sub 3/)/sub 2/ X 2TBP.

Kolker, A.R.

1986-05-01T23:59:59.000Z

454

Method for fluorination of uranium oxide  

DOE Patents [OSTI]

Highly pure uranium hexafluoride is made from uranium oxide and fluorine. The uranium oxide, which includes UO.sub.3, UO.sub.2, U.sub.3 O.sub.8 and mixtures thereof, is introduced together with a small amount of a fluorine-reactive substance, selected from alkali chlorides, silicon dioxide, silicic acid, ferric oxide, and bromine, into a constant volume reaction zone. Sufficient fluorine is charged into the zone at a temperature below approximately 0.degree. C. to provide an initial pressure of at least approximately 600 lbs/sq. in. at the ambient atmospheric temperature. The temperature is then allowed to rise in the reaction zone until reaction occurs.

Petit, George S. (Oak Ridge, TN)

1987-01-01T23:59:59.000Z

455

Sampling, characterization, and remote sensing of aerosols formed in the atmospheric hydrolysis of uranium hexafluoride  

SciTech Connect (OSTI)

When gaseous uranium hexafluoride (UF/sub 6/) is released into the atmosphere, it rapidly reacts with ambient moisture to form an aerosol of uranyl fluoride (UO/sub 2/F/sub 2/) and hydrogen fluoride (HF). As part of our Safety Analysis program, we have performed several experimental releases of HF/sub 6/ in contained volumes in order to investigate techniques for sampling and characterizing the aerosol materials. The aggregate particle morphology and size distribution have been found to be dependent upon several conditions, including the temperature of the UF/sub 6/ at the time of its release, the relative humidity of the air into which it is released, and the elapsed time after the release. Aerosol composition and settling rate have been investigated using stationary samplers for the separate collection of UO/sub 2/F/sub 2/ and HF and via laser spectroscopic remote sensing (Mie scatter and infrared spectroscopy). 25 refs., 16 figs., 5 tabs.

Bostick, W.D.; McCulla, W.H.; Pickrell, P.W.

1984-05-01T23:59:59.000Z

456

Female characters in Thomas Wolfe's four major novels: Look Homeward, Angel; Of Time and the River; The Web and the Rock; and You Can't Go Home Again.  

E-Print Network [OSTI]

~ aqszeq aauy us 'BuTSSsu 'yes 'saTyp ~ Zq. Tsze~Tug eqq oq. m~ e~q. pygmy quqq. uTszq agq uo xgO au85~ mund egg Wyaas azs ueyea zeqsTs s~ pus zeqgom ttt!Tt; go tlT Sl!St: OZtt Ztt;g tttt OZBgattt'I. tlt etitttlA Za . Be l'tt' tttl1 exjujf'txoa ggf...ZgggueyT ylxs 89900'GB EzszegTT zan $$9Tlb 8rq QQTCey 8$9Aou za f sin zxioj 8 t 9+Qajtj uo'f &~ss QusSzp '8TGAalx zo f. sB zTLQ+ Gl[$ lx'f szegaszsqa 8 DiG~Gg eqg ~ 9 0". l ssx:0 o zeezsp eq. Tg GqtTt l GIMP/ $0 Aoyu j(X 9'lpga Zyeuueg g yzsqarjj 'p96j...

Sheffield, Jewell Frieda

2012-06-07T23:59:59.000Z

457

AGR-2 Irradiation Test Final As-Run Report, Rev 2  

SciTech Connect (OSTI)

This document presents the as-run analysis of the AGR-2 irradiation experiment. AGR-2 is the second of the planned irradiations for the Advanced Gas Reactor (AGR) Fuel Development and Qualification Program. Funding for this program is provided by the U.S. Department of Energy as part of the Very High Temperature Reactor (VHTR) Technical Development Office (TDO) program. The objectives of the AGR-2 experiment are to: (a) Irradiate UCO (uranium oxycarbide) and UO2 (uranium dioxide) fuel produced in a large coater. Fuel attributes are based on results obtained from the AGR-1 test and other project activities. (b) Provide irradiated fuel samples for post-irradiation experiment (PIE) and safety testing. (c) Support the development of an understanding of the relationship between fuel fabrication processes, fuel product properties, and irradiation performance. The primary objective of the test was to irradiate both UCO and UO2 TRISO (tri-structural isotropic) fuel produced from prototypic scale equipment to obtain normal operation and accident condition fuel performance data. The UCO compacts were subjected to a range of burnups and temperatures typical of anticipated prismatic reactor service conditions in three capsules. The test train also includes compacts containing UO2 particles produced independently by the United States, South Africa, and France in three separate capsules. The range of burnups and temperatures in these capsules were typical of anticipated pebble bed reactor service conditions. The results discussed in this report pertain only to U.S. produced fuel. In order to achieve the test objectives, the AGR-2 experiment was irradiated in the B-12 position of the Advanced Test Reactor (ATR) at Idaho National Laboratory (INL) for a total irradiation duration of 559.2 effective full power days (EFPD). Irradiation began on June 22, 2010, and ended on October 16, 2013, spanning 12 ATR power cycles and approximately three and a half calendar years. The test contained six independently controlled and monitored capsules. Each U.S. capsule contained 12 compacts of either UCO or UO2 AGR coated fuel. No fuel particles failed during the AGR-2 irradiation. Final burnup values on a per compact basis ranged from 7.26 to 13.15% FIMA (fissions per initial heavy-metal atom) for UCO fuel, and 9.01 to 10.69% FIMA for UO2 fuel, while fast fluence values ranged from 1.94 to 3.47´1025 n/m2 (E >0.18 MeV) for UCO fuel, and from 3.05 to 3.53´1025 n/m2 (E >0.18 MeV) for UO2 fuel. Time-average volume-average (TAVA) temperatures on a capsule basis at the end of irradiation ranged from 987°C in Capsule 6 to 1296°C in Capsule 2 for UCO, and from 996 to 1062°C in UO2-fueled Capsule 3. By the end of the irradiation, all of the installed thermocouples (TCs) had failed. Fission product release-to-birth (R/B) ratios were quite low. In the UCO capsules, R/B values during the first three cycles were below 10-6 with the exception of the hotter Capsule 2, in which the R/Bs reached 2´10-6. In the UO2 capsule (Capsule 3), the R/B values during the first three cycles were below 10-7. R/B values for all following cycles are not reliable due to gas flow and cross talk issues.

Blaise Collin

2014-08-01T23:59:59.000Z

458

Semiempirical range and stopping power values for heavy ions  

E-Print Network [OSTI]

0 CO CCI CO O O O rn UJ O r mU. m ~ ~ ~ OOOOO cl N O I N 4 O' ICI N w ~ Q ~ N ~ U 0 Q If Cl CO 0' M 0' In ICI ~ ~ 0 000 ~ ~ ~ Ln or o o Lnr o UO N Z O' pCI rn N w ~ ~ ~ ~ Q 4 ~ 0 N CCI OI 0 0 r UI Cr rll m ~ ~ N 0 m... O ~ ~ N U'. r co I ~ ~ N 0 O UO CO CO Q N N ~ ~ nd NI 0 0 ILI C3 CO 0 0 t CO r UJ O' rh ~ ~ cn 0 N 'Z \\ ~ CO m rn m ~ ~ U, 0 N CO cn N N ~ ~ 0 0 U I I 4 I ? 4 4 G V 4 a a LU N IU UJ CO O Lf 0 UJ...

Schilling, Ralph Franklin, III

2012-06-07T23:59:59.000Z

459

AGR-2 irradiation test final as-run report, Rev. 1  

SciTech Connect (OSTI)

This document presents the as-run analysis of the AGR-2 irradiation experiment. AGR-2 is the second of the planned irradiations for the Advanced Gas Reactor (AGR) Fuel Development and Qualification Program. Funding for this program is provided by the U.S. Department of Energy as part of the Very High Temperature Reactor (VHTR) Technical Development Office (TDO) program. The objectives of the AGR-2 experiment are to: (a) Irradiate UCO (uranium oxycarbide) and UO2 (uranium dioxide) fuel produced in a large coater. Fuel attributes are based on results obtained from the AGR-1 test and other project activities; (b) Provide irradiated fuel samples for post-irradiation experiment (PIE) and safety testing; and, (c) Support the development of an understanding of the relationship between fuel fabrication processes, fuel product properties, and irradiation performance. The primary objective of the test was to irradiate both UCO and UO2 TRISO (tri-structural isotropic) fuel produced from prototypic scale equipment to obtain normal operation and accident condition fuel performance data. The UCO compacts were subjected to a range of burnups and temperatures typical of anticipated prismatic reactor service conditions in three capsules. The test train also includes compacts containing UO2 particles produced independently by the United States, South Africa, and France in three separate capsules. The range of burnups and temperatures in these capsules were typical of anticipated pebble bed reactor service conditions. The results discussed in this report pertain only to U.S. produced fuel. In order to achieve the test objectives, the AGR-2 experiment was irradiated in the B-12 position of the Advanced Test Reactor (ATR) at Idaho National Laboratory (INL) for a total irradiation duration of 559.2 effective full power days (EFPD). Irradiation began on June 22, 2010, and ended on October 16, 2013, spanning 12 ATR power cycles and approximately three and a half calendar years. The test contained six independently controlled and monitored capsules. Each U.S. capsule contained 12 compacts of either UCO or UO2 AGR coated fuel. No fuel particles failed during the AGR-2 irradiation. Final burnup values on a per compact basis ranged from 7.26 to 13.15% FIMA (fissions per initial heavy-metal atom) for UCO fuel, and 9.01 to 10.69% FIMA for UO2 fuel, while fast fluence values ranged from 1.94 to 3.47´1025 n/m2 (E >0.18 MeV) for UCO fuel, and from 3.05 to 3.53´1025 n/m2 (E >0.18 MeV) for UO2 fuel. Time-average volume-average (TAVA) temperatures on a capsule basis at the end of irradiation ranged from 987°C in Capsule 6 to 1296°C in Capsule 2 for UCO, and from 996 to 1062°C in UO2-fueled Capsule 3. By the end of the irradiation, all of the installed thermocouples (TCs) had failed. Fission product release-to-birth (R/B) ratios were quite low. In the UCO capsules, R/B values during the first three cycles were below 10-6 with the exception of the hotter Capsule 2, in which the R/Bs reached 2´10-6. In the UO2 capsule (Capsule 3), the R/B values during the first three cycles were below 10-7. R/B values for all following cycles are not reliable due to gas flow and cross talk issues.

Collin, Blaise P.

2014-08-01T23:59:59.000Z

460

AGR-2 IRRADIATION TEST FINAL AS-RUN REPORT  

SciTech Connect (OSTI)

This document presents the as-run analysis of the AGR-2 irradiation experiment. AGR-2 is the second of the planned irradiations for the Advanced Gas Reactor (AGR) Fuel Development and Qualification Program. Funding for this program is provided by the U.S. Department of Energy as part of the Very High Temperature Reactor (VHTR) Technical Development Office (TDO) program. The objectives of the AGR-2 experiment are to: (a) Irradiate UCO (uranium oxycarbide) and UO2 (uranium dioxide) fuel produced in a large coater. Fuel attributes are based on results obtained from the AGR-1 test and other project activities. (b) Provide irradiated fuel samples for post-irradiation experiment (PIE) and safety testing. (c) Support the development of an understanding of the relationship between fuel fabrication processes, fuel product properties, and irradiation performance. The primary objective of the test was to irradiate both UCO and UO2 TRISO (tri-structural isotropic) fuel produced from prototypic scale equipment to obtain normal operation and accident condition fuel performance data. The UCO compacts were subjected to a range of burnups and temperatures typical of anticipated prismatic reactor service conditions in three capsules. The test train also includes compacts containing UO2 particles produced independently by the United States, South Africa, and France in three separate capsules. The range of burnups and temperatures in these capsules were typical of anticipated pebble bed reactor service conditions. The results discussed in this report pertain only to U.S. produced fuel. In order to achieve the test objectives, the AGR-2 experiment was irradiated in the B-12 position of the Advanced Test Reactor (ATR) at Idaho National Laboratory (INL) for a total irradiation duration of 559.2 effective full power days (EFPD). Irradiation began on June 22, 2010, and ended on October 16, 2013, spanning 12 ATR power cycles and approximately three and a half calendar years. The test contained six independently controlled and monitored capsules. Each U.S. capsule contained 12 compacts of either UCO or UO2 AGR coated fuel. No fuel particles failed during the AGR-2 irradiation. Final burnup values on a per compact basis ranged from 7.26 to 13.15% FIMA (fissions per initial heavy-metal atom) for UCO fuel, and 9.01 to 10.69% FIMA for UO2 fuel, while fast fluence values ranged from 1.94 to 3.47´1025 n/m2 (E >0.18 MeV) for UCO fuel, and from 3.05 to 3.53´1025 n/m2 (E >0.18 MeV) for UO2 fuel. Time-average volume-average (TAVA) temperatures on a capsule basis at the end of irradiation ranged from 987°C in Capsule 6 to 1296°C in Capsule 2 for UCO, and from 996 to 1062°C in UO2-fueled Capsule 3. By the end of the irradiation, all of the installed thermocouples (TCs) had failed. Fission product release-to-birth (R/B) ratios were quite low. In the UCO capsules, R/B values during the first three cycles were below 10-6 with the exception of the hotter Capsule 2, in which the R/Bs reached 2´10-6. In the UO2 capsule (Capsule 3), the R/B values during the first three cycles were below 10-7. R/B values for all following cycles are not reliable due to gas flow and cross talk issues.

Blaise, Collin

2014-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "ms uo uo" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Standard specification for uranium oxides with a 235U content of less than 5 % for dissolution prior to conversion to nuclear-grade uranium dioxide  

E-Print Network [OSTI]

1.1 This specification covers uranium oxides, including processed byproducts or scrap material (powder, pellets, or pieces), that are intended for dissolution into uranyl nitrate solution meeting the requirements of Specification C788 prior to conversion into nuclear grade UO2 powder with a 235U content of less than 5 %. This specification defines the impurity and uranium isotope limits for such urania powders that are to be dissolved prior to processing to nuclear grade UO2 as defined in Specification C753. 1.2 This specification provides the nuclear industry with a general standard for such uranium oxide powders. It recognizes the diversity of conversion processes and the processes to which such powders are subsequently to be subjected (for instance, by solvent extraction). It is therefore anticipated that it may be necessary to include supplementary specification limits by agreement between the buyer and seller. 1.3 The scope of this specification does not comprehensively cover all provisions for prevent...

American Society for Testing and Materials. Philadelphia

2005-01-01T23:59:59.000Z

462

TREKiSM Issue 40  

E-Print Network [OSTI]

~~JnJas leuo~+8N ay+ WOJj auo 4+~M 5uole 'uosqoH +Jaql~ Aq pau61s 'PJEJ ~IJ aYl Jay 5M04s a4 (OT lpJ8n6 IEuosJad AW S.8J84M (a lUO 6u~o6 s.+EYM(P lpJEaq JnOA sldJa4M (J lS14l 51 WJOj1 un jO pU1~ lP4M (q lAZPJJ auo6 AX8TE6 ay o4M a4l SPH (8 :aJe suo1lsanb BA...

1985-01-01T23:59:59.000Z

463

A view of treatment process of melted nuclear fuel on a severe accident plant using a molten salt system  

SciTech Connect (OSTI)

At severe accident such as Fukushima Daiichi Nuclear Power Plant Accident, the nuclear fuels in the reactor would melt and form debris which contains stable UO2-ZrO2 mixture corium and parts of vessel such as zircaloy and iron component. The requirements for solution of issues are below; -) the reasonable treatment process of the debris should be simple and in-situ in Fukushima Daiichi power plant, -) the desirable treatment process is to take out UO{sub 2} and PuO{sub 2} or metallic U and TRU metal, and dispose other fission products as high level radioactive waste; and -) the candidate of treatment process should generate the smallest secondary waste. Pyro-process has advantages to treat the debris because of the high solubility of the debris and its total process feasibility. Toshiba proposes a new pyro-process in molten salts using electrolysing Zr before debris fuel being treated.

Fujita, R.; Takahashi, Y.; Nakamura, H.; Mizuguchi, K. [Power and Industrial Research and Development Center, Toshiba Corporation Power Systems Company, 4-1 Ukishima-cho, Kawasaki-ku, Kawasaki 210-0862 (Japan); Oomori, T. [Chemical System Design and Engineering Department, Toshiba Corporation Power Systems Company, 8 Shinsugita-cho, Isogo-ku, Yokohama 235-8523 (Japan)

2013-07-01T23:59:59.000Z

464

THE X-RAY STAR FORMATION STORY AS TOLD BY LYMAN BREAK GALAXIES IN THE 4 Ms CDF-S  

SciTech Connect (OSTI)

We present results from deep X-ray stacking of >4000 high-redshift galaxies from z Almost-Equal-To 1 to 8 using the 4 Ms Chandra Deep Field-South data, the deepest X-ray survey of the extragalactic sky to date. The galaxy samples were selected using the Lyman break technique based primarily on recent Hubble Space Telescope ACS and WFC3 observations. Based on such high specific star formation rates (sSFRs): log SFR/M {sub *} > -8.7, we expect that the observed properties of these Lyman break galaxies (LBGs) are dominated by young stellar populations. The X-ray emission in LBGs, eliminating individually detected X-ray sources (potential active galactic nucleus), is expected to be powered by X-ray binaries and hot gas. We find, for the first time, evidence of evolution in the X-ray/SFR relation. Based on X-ray stacking analyses for z < 4 LBGs (covering {approx}90% of the universe's history), we find that the 2-10 keV X-ray luminosity evolves weakly with redshift (z) and SFR as log L {sub X} = 0.93log (1 + z) + 0.65log SFR + 39.80. By comparing our observations with sophisticated X-ray binary population synthesis models, we interpret that the redshift evolution of L {sub X}/SFR is driven by metallicity evolution in high mass X-ray binaries, likely the dominant population in these high sSFR galaxies. We also compare these models with our observations of X-ray luminosity density (total 2-10 keV luminosity per Mpc{sup 3}) and find excellent agreement. While there are no significant stacked detections at z {approx}> 5, we use our upper limits from 5 {approx}< z {approx}< 8 LBGs to constrain the supermassive black hole accretion history of the universe around the epoch of reionization.

Basu-Zych, Antara R.; Lehmer, Bret D.; Hornschemeier, Ann E.; Tzanavaris, Panayiotis [NASA Goddard Space Flight Center, Code 662, Greenbelt, MD 20771 (United States)] [NASA Goddard Space Flight Center, Code 662, Greenbelt, MD 20771 (United States); Bouwens, Rychard J. [Leiden Observatory, Leiden University, NL-2300 RA Leiden (Netherlands)] [Leiden Observatory, Leiden University, NL-2300 RA Leiden (Netherlands); Fragos, Tassos; Zezas, Andreas [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States)] [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States); Oesch, Pascal A. [UCO/Lick Observatory, University of California, Santa Cruz, CA 95064 (United States)] [UCO/Lick Observatory, University of California, Santa Cruz, CA 95064 (United States); Belczynski, Krzysztof [Astronomical Observatory, University of Warsaw, Al. Ujazdowskie 4, 00-478 Warsaw (Poland)] [Astronomical Observatory, University of Warsaw, Al. Ujazdowskie 4, 00-478 Warsaw (Poland); Brandt, W. N.; Luo, Bin; Xue, Yongquan [Department of Astronomy and Astrophysics, Pennsylvania State University, University Park, PA 16802 (United States)] [Department of Astronomy and Astrophysics, Pennsylvania State University, University Park, PA 16802 (United States); Kalogera, Vassiliki [Department of Physics and Astronomy, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208 (United States)] [Department of Physics and Astronomy, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208 (United States); Miller, Neal [Department of Astronomy, University of Maryland, College Park, MD 20742 (United States)] [Department of Astronomy, University of Maryland, College Park, MD 20742 (United States); Mullaney, James R., E-mail: antara.r.basu-zych@nasa.gov [Department of Physics, Durham University, South Road, Durham DH1 3LE (United Kingdom)

2013-01-01T23:59:59.000Z

465

Simulation of Low-Enriched Uranium (LEU) Burnup in Russian VVER Reactors with the HELIOS Code Package  

SciTech Connect (OSTI)

The HELIOS reactor-physics computer program system was used to simulate the burnup of UO{sub 2} fuel in three VVER reactors. The manner in which HELIOS was used in these simulations is described. Predictions of concentrations for actinides up to {sup 244}Cm and for isotopes of neodymium were compared with laboratory-measured values. Reasonable agreement between calculated and measured values was seen for experimental samples from a fuel rod in the interior of an assembly.

Murphy, B.D.; Kravchenko, J.; Lazarenko, A.; Pavlovitchev, A.; Sidorenko, V.; Chetverikov, A.

2000-03-01T23:59:59.000Z

466

Draft report on melt point as a function of composition for urania-based systems  

SciTech Connect (OSTI)

This report documents the testing of a urania (UO{sub 2.00}) sample as a baseline and the attempt to determine the melt point associated with 4 compositions of urania-ceria and urania-neodymia pseudo binaries provided by ORNL, with compositions of 95/5, and 80/20 and of (U/Ce)O{sub 2.00} and (U/Nd)O{sub 2.00} in the newly developed ceramic melt point determination system. A redesign of the system using parts fabricated from tungsten was undertaken in order to help prevent contamination and tungsten carbide formation in the crucibles. The previously developed system employed mostly graphite parts that were shown to react with the sample containment black-body crucible leading to unstable temperature readings and crucible failure, thus the redesign. Measured melt point values of UO{sub 2.00} and U{sub 0.95}Ce{sub 0.05}O{sub 2.00}, U{sub 0.80}Ce{sub 0.20}O{sub 2.00}, U{sub 0.95}Nd{sub 0.05}O{sub 2.00} and U{sub 0.80}Nd{sub 0.20}O{sub 2.00} were measured using a 2-color pyrometer. The value measured for UO{sub 2.00} was consistent with the published accepted value 2845 C {+-} 25 C, although a wide range of values has been published by researchers and will be discussed later in the text. For comparison, values obtained from a published binary phase diagram of UO{sub 2}-Nd{sub 2}O{sub 3} were used for comparison with our measure values. No literature melt point values for comparison with the measurements performed in this study were found for (U/Ce)O{sub 2.00} in our stoichiometry range.

Valdez, James A [Los Alamos National Laboratory; Byler, Darrin D [Los Alamos National Laboratory

2012-06-08T23:59:59.000Z

467

2nd Annual Workshop Proceedings EC FP FIRST-Nuclides 5th  

E-Print Network [OSTI]

phases, (2) quantification of H2O2 and H2 produced by water radiolysis and (3) determination of the UO2 surface by H2O2 produced by water radiolysis. We have verified that studtite is not formed to the inhibition effect of H2 produced by water radiolysis. In these conditions, G(H2O2) and G(H2) are respectively

Paris-Sud XI, Université de

468

Universal fuel basket for use with an improved oxide reduction vessel and electrorefiner vessel  

DOE Patents [OSTI]

A basket, for use in the reduction of UO.sub.2 to uranium metal and in the electrorefining of uranium metal, having a continuous annulus between inner and outer perforated cylindrical walls, with a screen adjacent to each wall. A substantially solid bottom and top plate enclose the continuous annulus defining a fuel bed. A plurality of scrapers are mounted adjacent to the outer wall extending longitudinally thereof, and there is a mechanism enabling the basket to be transported remotely.

Herrmann, Steven D. (Idaho Falls, ID); Mariani, Robert D. (Idaho Falls, ID)

2002-01-01T23:59:59.000Z

469

Head-end process for the reprocessing of HTGR spent fuel  

SciTech Connect (OSTI)

The reprocessing of HTGR spent fuels is in favor of the sustainable development of nuclear energy to realize the maximal use of nuclear resource and the minimum disposal of nuclear waste. The head-end of HTGR spent fuels reprocessing is different from that of the LWR spent fuels reprocessing because of the difference of spent fuel structure. The dismantling of the graphite spent fuel element and the highly effective dissolution of fuel kernel is the most difficult process in the head end of the reprocessing. Recently, some work on the head-end has been done in China. First, the electrochemical method with nitrate salt as electrolyte was studied to disintegrate the graphite matrix from HTGR fuel elements and release the coated fuel particles, to provide an option for the head-end technology of reprocessing. The results show that the graphite matrix can be effectively separated from the coated particle without any damage to the SiC layer. Secondly, the microwave-assisted heating was applied to dissolve the UO{sub 2} kernel from the crashed coated fuel particles. The ceramic UO{sub 2} as the solute has a good ability to absorb the microwave energy. The results of UO{sub 2} kernel dissolution from crushed coated particles by microwave heating show that the total dissolution percentage of UO{sub 2} is more than 99.99% after 3 times cross-flow dissolution with the following parameters: 8 mol/L HNO{sub 3}, temperature 100 Celsius degrees, initial ratio of solid to liquid 1.2 g/ml. (authors)

Chen, J.; Wen, M. [Institute of Nuclear and New Energy Technology, Tsinghua University, Bejing 10084 (China)

2013-07-01T23:59:59.000Z

470

Magnetic resonance as a structural probe of a uranium (VI) sol-gel process  

SciTech Connect (OSTI)

NMR investigations on the ORNL process for sol-gel synthesis of microspherical nuclear fuel (UO{sub 2}), has been useful in sorting out the chemical mechanism in the sol-gel steps. {sup 13}C, {sup 15}N, and {sup 1}H NMR studies on the HMTA gelation agent (Hexamethylene tetramine, C{sub 6}H{sub l2}N{sub 4}) has revealed near quantitative stability of this adamantane-like compound in the sol-Gel process, contrary to its historical role as an ammonia source for gelation from the worldwide technical literature. {sub 17}0 NMR of uranyl (UO{sub 2}{sup ++}) hydrolysis fragments produced in colloidal sols has revealed the selective formation of a uranyl trimer, ((UO{sub 2}){sub 3}({mu}{sub 3}-O)({mu}{sub 2}-OH){sub 3}){sup +}, induced by basic hydrolysis with the HMTA gelation agent. Spectroscopic results show that trimer condensation occurs during sol-gel processing leading to layered polyanionic hydrous uranium oxides in which HMTAH{sup +} is occluded as an intercalation'' cation. Subsequent sol-gel processing of microspheres by ammonia washing results in in-situ ion exchange and formation of a layered hydrous ammonium uranate with a proposed structural formula of (NH{sub 4}){sub 2}((UO{sub 2}){sub 8}O{sub 4}(OH){sub 10}) {center dot} 8H{sub 2}0. This compound is the precursor to sintered U0{sub 2} ceramic fuel.

King, C.M.; Thompson, M.C.; Buchanan, B.R. (Westinghouse Savannah River Co., Aiken, SC (United States)); King, R.B. (Georgia Univ., Athens, GA (United States). Dept. of Chemistry); Garber, A.R. (South Carolina Univ., Columbia, SC (United States). Dept. of Chemistry)

1989-01-01T23:59:59.000Z

471

Magnetic resonance as a structural probe of a uranium (VI) sol-gel process  

SciTech Connect (OSTI)

NMR investigations on the ORNL process for sol-gel synthesis of microspherical nuclear fuel (UO{sub 2}), has been useful in sorting out the chemical mechanism in the sol-gel steps. {sup 13}C, {sup 15}N, and {sup 1}H NMR studies on the HMTA gelation agent (Hexamethylene tetramine, C{sub 6}H{sub l2}N{sub 4}) has revealed near quantitative stability of this adamantane-like compound in the sol-Gel process, contrary to its historical role as an ammonia source for gelation from the worldwide technical literature. {sub 17}0 NMR of uranyl (UO{sub 2}{sup ++}) hydrolysis fragments produced in colloidal sols has revealed the selective formation of a uranyl trimer, [(UO{sub 2}){sub 3}({mu}{sub 3}-O)({mu}{sub 2}-OH){sub 3}]{sup +}, induced by basic hydrolysis with the HMTA gelation agent. Spectroscopic results show that trimer condensation occurs during sol-gel processing leading to layered polyanionic hydrous uranium oxides in which HMTAH{sup +} is occluded as an ``intercalation`` cation. Subsequent sol-gel processing of microspheres by ammonia washing results in in-situ ion exchange and formation of a layered hydrous ammonium uranate with a proposed structural formula of (NH{sub 4}){sub 2}[(UO{sub 2}){sub 8}O{sub 4}(OH){sub 10}] {center_dot} 8H{sub 2}0. This compound is the precursor to sintered U0{sub 2} ceramic fuel.

King, C.M.; Thompson, M.C.; Buchanan, B.R. [Westinghouse Savannah River Co., Aiken, SC (United States); King, R.B. [Georgia Univ., Athens, GA (United States). Dept. of Chemistry; Garber, A.R. [South Carolina Univ., Columbia, SC (United States). Dept. of Chemistry

1989-12-31T23:59:59.000Z

472

Report of Progress with Citrus Fruits at the Beeville Sub-Station, Bee County.  

E-Print Network [OSTI]

65-109-5m TEXAS AGRICULTURAL EXPERIMENT STATIONS. -T- I . ! '? . ........ ?' ? r ; 'V ? J 'V ? ? ? BULLETIN NO. 118. February, 1 9 0 9 . REPORT Of PROGRESS WITH CITRUS FRUITS AT THE BEEVILLE SUB-STATION, BEE COUNTY S. A. WASCHKA................. ................................Stenographer. A. S. F IB5 mmmmmmmmmmmmmmmmmmmmmmmmmmmmm mmmmmmmmmmmmmmm STATE SUBSTATIONS. H. H. R IBBC8 -1X8 mmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmDirector. W. S. R X1uoMCPP0 Superintendent...

Waschka, S. A.

1909-01-01T23:59:59.000Z

473

The relative basicity and reactivity of D-mannosamine  

E-Print Network [OSTI]

$$A IIIGQB UQJOJQlu 9T)0 '. JB Uof'. reu" I Jiroro QQTIOT080 QIP, $G 90UQ qV foui'. 'PQI&STI! Tr 'TP eq ggr'I O'0 noun ~ Qcyo9pgq . [ rl oqq Uo QGUQUQTU T . TOT UT. I Iq'c'00 "" g /nlrb. 0nq eu~=9oaul!UT r IG 980q;QJT e~g u L quoeosd oq gTjrl UGI08Teq0...

Carlo, Michael John

1962-01-01T23:59:59.000Z

474

Thorium oxide slurries as blankets in fissile producing fusion- fission hybrids  

E-Print Network [OSTI]

of the blanket as related to the energy of the incident fusion neutrons. CALCULATIONAL MODEL The MARS computer code package from the Radiation Shielding Information Center (RSIC) at Oak Ridge National Laboratory (ORNL) 11 was used to determine... the aqueous homogeneous power reactor program at ORNL was begun. Significant progress was made in studies of uranium oxide (UO ) and its slurries, and in the development of equipment for circulating slurries at concentrations of several hundred grams per...

Geer, Thomas Charles

1982-01-01T23:59:59.000Z

475

High-harmonic XUV source for time- and angle-resolved photoemission spectroscopy  

SciTech Connect (OSTI)

We present a laser-based apparatus for visible pump/XUV probe time- and angle-resolved photoemission spectroscopy (TRARPES) utilizing high-harmonic generation from a noble gas. Femtosecond temporal resolution for each selected harmonic is achieved by using a time-delay-compensated monochromator (TCM). The source has been used to obtain photoemission spectra from insulators (UO{sub 2}) and ultrafast pump/probe processes in semiconductors (GaAs).

Dakovski, Georgi L [Los Alamos National Laboratory; Li, Yinwan [Los Alamos National Laboratory; Durakiewicz, Tomasz [Los Alamos National Laboratory; Rodriguez, George [Los Alamos National Laboratory

2009-01-01T23:59:59.000Z

476

P a g e | 1 Regional Ocean Modelling  

E-Print Network [OSTI]

). #12;P a g e | 4 Slide 4: Flather Condition for Shallow-Water Barotropic Flow: h/t = -Hu/x u/t = -gh be shown that for shallow-water eqn: u - (g/H)1/2 h is the incoming (i.e. left-running) characteristic for uo-c subcritical flows. Thus, either we set "u - (g/H)1/2 h" to be zero

477

Development of Chiral LC-MS Methods for small Molecules and Their Applications in the Analysis of Enantiomeric Composition and Pharmacokinetic Studies  

SciTech Connect (OSTI)

The purpose of this research was to develop sensitive LC-MS methods for enantiomeric separation and detection, and then apply these methods for determination of enantiomeric composition and for the study of pharmacokinetic and pharmacodynamic properties of a chiral nutraceutical. Our first study, evaluated the use of reverse phase and polar organic mode for chiral LC-API/MS method development. Reverse phase methods containing high water were found to decrease ionization efficiency in electrospray, while polar organic methods offered good compatibility and low limits of detection with ESI. The use of lower flow rates dramatically increased the sensitivity by an order of magnitude. Additionally, for rapid chiral screening, the coupled Chirobiotic column afforded great applicability for LC-MS method development. Our second study, continued with chiral LC-MS method development in this case for the normal phase mode. Ethoxynonafluorobutane, a fluorocarbon with low flammability and no flashpoint, was used as a substitute solvent for hexane/heptane mobile phases for LC-APCI/MS. Comparable chromatographic resolutions and selectivities were found using ENFB substituted mobile phase systems, although, peak efficiencies were significantly diminished. Limits of detection were either comparable or better for ENFB-MS over heptane-PDA detection. The miscibility of ENFB with a variety of commonly used organic modifiers provided for flexibility in method development. For APCI, lower flow rates did not increase sensitivity as significantly as was previously found for ESI-MS detection. The chiral analysis of native amino acids was evaluated using both APCI and ESI sources. For free amino acids and small peptides, APCI was found to have better sensitivities over ESI at high flow rates. For larger peptides, however, sensitivity was greatly improved with the use of electrospray. Additionally, sensitivity was enhanced with the use of non-volatile additives, This optimized method was then used to simultaneously separate all 19 native amino acids enantiomerically in less than 20 minutes, making it suitable for complex biological analysis. The previously developed amino acid method was then used to enantiomerically separate theanine, a free amino acid found in tea leaves. Native theanine was found to have lower limits of detection and better sensitivity over derivatized theanine samples. The native theanine method was then used to determine the enantiomeric composition of six commercially available L-theanine products. Five out of the six samples were found to be a racemic mixture of both D- and L-theanine. Concern over the efficacy of these theanine products led to our final study evaluating the pharmacokinetics and pharmacodynamics of theanine in rats using LC-ESI/MS. Rats were administered D-, L, and QL-theanine both orally and intra-peritoneally. Oral administration data demonstrated that intestinal absorption of L-theanine was greater than that of D-theanine, while i.p. data showed equal plasma uptake of both isomers. This suggested a possible competitive binding effect with respect to gut absorption. Additionally, it was found that regardless of administration method, the presence of the other enantiomer always decreased overall theanine plasma concentration. This indicated that D- and L- theanine exhibit competitive binding with respect to urinary reabsorption as well. The large quantities of D-theanine detected in the urine suggested that D-themine was eliminated with minimal metabolism, while L-theanine was preferentially reabsorbed and metabolized to ethylamine. Clearly, the metabolic fate of racemic theanine and its individual enantiomers was quite different, placing into doubt the utility of the commercial theanine products.

Meera Jay Desai

2004-12-19T23:59:59.000Z

478

Single voxel MR spectroscopy with echo times below 2 ms at 16.4 T in the rat brain: first in vivo results D. Z. Balla1  

E-Print Network [OSTI]

results D. Z. Balla1 , S-T. Hong1 , G. Shajan1 , R. Pohmann1 , and K. Ugurbil1,2 1 High-Field MR Center for Magnetic Resonance Research, Minneapolis, Minnesota, United States Introduction In vivo 1H MR spectroscopySingle voxel MR spectroscopy with echo times below 2 ms at 16.4 T in the rat brain: first in vivo

479

Continuous Flow Liquid Microjunction Surface Sampling Probe Connected On-line with HPLC/MS for Spatially Resolved Analysis of Small Molecules and Proteins  

SciTech Connect (OSTI)

RATIONALE: A continuous flow liquid microjunction surface sampling probe extracts soluble material from surfaces for direct ionization and detection by MS. Demonstrated here is the on-line coupling of such a probe with HPLC/MS enabling extraction, separation and detection of small molecules and proteins from surfaces in a spatially resolved (~0.5 mm diameter spots) manner. Methods: A continuous flow liquid microjunction surface sampling probe was connected to a 6-port, 2-position valve for extract collection and injection to an HPLC column. A QTRAP 5500 hybrid triple quadrupole linear ion trap equipped with a Turbo V ion source operated in positive ESI mode was used for all experiments. System operation was tested with extraction, separation and detection of propranolol and associated metabolites from drug dosed tissues and proteins from dried sheep blood spots on paper. Results: Confirmed in the tissue were the parent drug and two different hydroxypropranolol glucuronides. The mass spectrometric response for these compounds from different locations in the liver showed an increase with increasing extraction time (5, 20 and 40 s extractions). For on-line separation and detection/identification of extracted proteins from dried sheep blood spots, two major protein peaks dominated the chromatogram and could be correlated with the expected masses for the hemoglobin and chains. Conclusions: Spatially resolved sampling, separation, and detection of small molecules and proteins from surfaces can be accomplished using a continuous flow liquid microjunction surface sampling probe coupled on-line with HPLC/MS detection.

Van Berkel, Gary J [ORNL; Kertesz, Vilmos [ORNL

2013-01-01T23:59:59.000Z

480

Multiple Irradiation Capsule Experiment (MICE)-3B Irradiation Test of Space Fuel Specimens in the Advanced Test Reactor (ATR) - Close Out Documentation for Naval Reactors (NR) Information  

SciTech Connect (OSTI)

Few data exist for UO{sub 2} or UN within the notional design space for the Prometheus-1 reactor (low fission rate, high temperature, long duration). As such, basic testing is required to validate predictions (and in some cases determine) performance aspects of these fuels. Therefore, the MICE-3B test of UO{sub 2} pellets was designed to provide data on gas release, unrestrained swelling, and restrained swelling at the upper range of fission rates expected for a space reactor. These data would be compared with model predictions and used to determine adequacy of a space reactor design basis relative to fission gas release and swelling of UO{sub 2} fuel and to assess potential pellet-clad interactions. A primary goal of an irradiation test for UN fuel was to assess performance issues currently associated with this fuel type such as gas release, swelling and transient performance. Information learned from this effort may have enabled use of UN fuel for future applications.

M. Chen; CM Regan; D. Noe

2006-01-09T23:59:59.000Z

Note: This page contains sample records for the topic "ms uo uo" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Development of a high-temperature oven for the 28 GHz electron cyclotron resonance ion source  

SciTech Connect (OSTI)

We have been developing the 28 GHz ECR ion source in order to accelerate high-intensity uranium beams at the RIKEN RI-beam Factory. Although we have generated U{sup 35+} beams by the sputtering method thus far, we began developing a high-temperature oven with the aim of increasing and stabilizing the beams. Because the oven method uses UO{sub 2}, a crucible must be heated to a temperature higher than 2000?°C to supply an appropriate amount of UO{sub 2} vapor to the ECR plasma. Our high-temperature oven uses a tungsten crucible joule-heated with DC current of approximately 450 A. Its inside dimensions are ?11 mm × 13.5 mm. Since the crucible is placed in a magnetic field of approximately 3 T, it is subject to a magnetic force of approximately 40 N. Therefore, we used ANSYS to carefully design the crucible, which was manufactured by machining a tungsten rod. We could raise the oven up to 1900?°C in the first off-line test. Subsequently, UO{sub 2} was loaded into the crucible, and the oven was installed in the 28 GHz ECR ion source and was tested. As a result, a U{sup 35+} beam current of 150 ?A was extracted successfully at a RF power of approximately 3 kW.

Ohnishi, J., E-mail: ohnishi@riken.jp; Higurashi, Y.; Kidera, M.; Ozeki, K.; Nakagawa, T. [RIKEN Nishina Center, Wako, Saitama 351-0198 (Japan)] [RIKEN Nishina Center, Wako, Saitama 351-0198 (Japan)

2014-02-15T23:59:59.000Z

482

Electrochemistry of LiCl-Li2O-H2O Molten Salt Systems  

SciTech Connect (OSTI)

Uranium can be recovered from uranium oxide (UO2) spent fuel through the combination of the oxide reduction and electrorefining processes. During oxide reduction, the spent fuel is introduced to molten LiCl-Li2O salt at 650 degrees C and the UO2 is reduced to uranium metal via two routes: (1) electrochemically, and (2) chemically by lithium metal (Li0) that is produced electrochemically. However, the hygroscopic nature of both LiCl and Li2O leads to the formation of LiOH, contributing hydroxyl anions (OH-), the reduction of which interferes with the Li0 generation required for the chemical reduction of UO2. In order for the oxide reduction process to be an effective method for the treatment of uranium oxide fuel, the role of moisture in the LiCl-Li2O system must be understood. The behavior of moisture in the LiCl-Li2O molten salt system was studied using cyclic voltammetry, chronopotentiometry and chronoamperometry, while reduction to hydrogen was confirmed with gas chromatography.

Natalie J. Gese; Batric Pesic

2013-03-01T23:59:59.000Z

483

Uranyl coordination environment in hydrophobic ionic liquids : an in situ investigation.  

SciTech Connect (OSTI)

Different inner-sphere coordination environments are observed for the uranyl nitrate complexes formed with octyl-phenyl-N,N-diisobutylcarbamoylmethylphosphine oxide and tributyl phosphate in dodecane and in the hydrophobic ionic liquids (ILs) [C{sub 4}mim][PF{sub 6}] and [C{sub 8}mim][N(SO{sub 2}CF{sub 3}){sub 2}]. Qualitative differences in the coordination environment of the extracted uranyl species are implied by changes in peak intensity patterns and locations for uranyl UV-visible spectral bands when the solvent is changed. EXAFS data for uranyl complexes in dodecane solutions is consistent with hexagonal bipyramidal coordination and the existence of UO{sub 2}(NO{sub 3}){sub 2}(CMPO){sub 2}. In contrast, the complexes formed when uranyl is transferred from aqueous nitric acid solutions into the ILs exhibit an average equatorial coordination number of approximately 4.5. Liquid/liquid extraction results for uranyl in both ILs indicate a net stoichiometry of UO{sub 2}(NO{sub 3})(CMPO){sup +}. The concentration of the IL cation in the aqueous phase increases in proportion to the amount of UO{sub 2}(NO{sub 3})(CMPO){sup +} in the IL phase, supporting a predominantly cation exchange mechanism for partitioning in the IL systems.

Visser, A. E.; Jensen, M. P.; Laszak, I.; Nash, K. L.; Choppin, G. R.; Roers, R. D.; Chemistry; Univ. of Alabama; Flordia State Univ.

2003-01-01T23:59:59.000Z

484

Multiscale Simulation of Thermo-mechancial Processes in Irradiated Fission-reactor Materials.  

SciTech Connect (OSTI)

The work funded from this project has been published in six papers, with two more in draft form, with submission planned for the near future. The papers are: (1) Kinetically-Evolving Irradiation-Induced Point-Defect Clusters in UO{sub 2} by Molecular-Dynamics Simulation; (2) Kinetically driven point-defect clustering in irradiated MgO by molecular-dynamics simulation; (3) Grain-Boundary Source/Sink Behavior for Point Defect: An Atomistic Simulation Study; (4) Energetics of intrinsic point defects in uranium dioxide from electronic structure calculations; (5) Thermodynamics of fission products in UO{sub 2{+-}x}; and (6) Atomistic study of grain boundary sink strength under prolonged electron irradiation. The other two pieces of work that are currently being written-up for publication are: (1) Effect of Pores and He Bubbles on the Thermal Transport Properties of UO2 by Molecular Dynamics Simulation; and (2) Segregation of Ruthenium to Edge Dislocations in Uranium Dioxide.

Simon R. Phillpot

2012-06-08T23:59:59.000Z

485

Irradiation of SiC Clad Fuel Rods in the HFIR  

SciTech Connect (OSTI)

During 2009 and- 2010, new test capability for the High Flux Isotope Reactor (HFIR) at Oak Ridge National Laboratory (ORNL) was developed that allows testing of advanced nuclear fuels and cladding under prototypic light-water-reactor (LWR) operating conditions (i.e., cladding and fuel temperatures, fuel average linear heat generation rates, and cladding fluence). For the initial experiments for this test program, ORNL teamed with commercial fuel/cladding vendors who have developed an advanced composite-wound SiC cladding material for possible use in LWRs. The first experiment, containing SiC-clad UN fuel, was inserted in HFIR in June 2010, and the second experiment, containing SiC-clad UO2 fuel, was inserted in October 2010. Two capsules (one containing UN fuel and the other UO2) were withdrawn from their respective assemblies in November 2011 at an estimated fuel burnup of approximately 10 GWd/MTHM; and two capsules (one containing UN fuel and the other UO2) were withdrawn from their respective assemblies in February 2013 at an estimated fuel burnup of approximately 20 GWd/MTHM. These capsules are currently awaiting PIE. This paper will describe the experiment, as-run operating conditions for these capsules, and current PIE plans and status.

Ott, Larry J [ORNL] [ORNL; Bell, Gary L [ORNL] [ORNL; Ellis, Ronald James [ORNL] [ORNL; McDuffee, Joel Lee [ORNL] [ORNL; Morris, Robert Noel [ORNL] [ORNL

2013-01-01T23:59:59.000Z

486

Molecular Dynamics Simulation of Thermodynamic Properties in Uranium Dioxide  

SciTech Connect (OSTI)

In the present study, we investigated the thermodynamic properties of uranium dioxide (UO2) by molecular dynamics (MD) simulations. As for solid UO2, the lattice parameter, density, and enthalpy obtained by MD simulations were in good agreement with existing experimental data and previous theoretical predictions. The calculated thermal conductivities matched the experiment results at the midtemperature range but were underestimated at very low and very high temperatures. The calculation results of mean square displacement represented the stability of uranium at all temperatures and the high mobility of oxygen toward 3000 K. By fitting the diffusivity constant of oxygen with the Vogel-Fulcher-Tamman law, we noticed a secondary phase transition near 2006.4 K, which can be identified as a ‘‘strong’’ to ‘‘fragile’’ supercooled liquid or glass phase transition in UO2. By fitting the oxygen diffusion constant with the Arrhenius equation, activation energies of 2.0 and 2.7 eV that we obtained were fairly close to the recommended values of 2.3 to 2.6 eV. Xiangyu Wang, Bin Wu, Fei Gao, Xin Li, Xin Sun, Mohammed A. Khaleel, Ademola V. Akinlalu and Li Liu

Wang, Xiangyu; Wu, Bin; Gao, Fei; Li, Xin; Sun, Xin; Khaleel, Mohammad A.; Akinlalu, Ademola V.; Liu, L.

2014-03-01T23:59:59.000Z

487

Theory of Deep Impurity Levels in Cucl  

E-Print Network [OSTI]

, respectively, + 0.59 ~ e ~ and ?0.59 ~ e ~ . E(s,c) E(s,a) E(p, c) E(p, a) E(d,c) E'{d,c) V(x?yz,) 2.80 ?15.15 9.00 ?3.75 ?1.25 ?1.90 V(s,s) ?2.877 V(x?s,) 4.841 V(s?x,) 2.866 V(x,x) 0 V(x,y) 0 V,d ?1.980 ?5.085 1.220 quirements... than C13p Cu 3d character at top of valence band C13p character at top of valence band 75%%uo 25rob 75%%uo 25%%uo Band gap (eV) 3.25' 3.25 Photoemission peaks (eV) B C D 0.8 ?1.4 1.9?2.6b 4.9?5.2 6.0?6.3 0.6 1.9 4.8 6.4 Width...

REN, SY; Allen, Roland E.; DOW, JD; LEFKOWITZ, I.

1982-01-01T23:59:59.000Z

488

Standard specification for sintered gadolinium oxide-uranium dioxide pellets  

E-Print Network [OSTI]

1.1 This specification is for finished sintered gadolinium oxide-uranium dioxide pellets for use in light-water reactors. It applies to gadolinium oxide-uranium dioxide pellets containing uranium of any 235U concentration and any concentration of gadolinium oxide. 1.2 This specification recognizes the presence of reprocessed uranium in the fuel cycle and consequently defines isotopic limits for gadolinium oxide-uranium dioxide pellets made from commercial grade UO2. Such commercial grade UO2 is defined so that, regarding fuel design and manufacture, the product is essentially equivalent to that made from unirradiated uranium. UO2 falling outside these limits cannot necessarily be regarded as equivalent and may thus need special provisions at the fuel fabrication plant or in the fuel design. 1.3 This specification does not include (1) provisions for preventing criticality accidents or (2) requirements for health and safety. Observance of this specification does not relieve the user of the obligation to be aw...

American Society for Testing and Materials. Philadelphia

2008-01-01T23:59:59.000Z

489

Effect of Grain Boundaries on Krypton Segregation Behavior in Irradiated Uranium Dioxide  

SciTech Connect (OSTI)

Fission products, such as krypton (Kr), are known to be insoluble within UO2, segregating towards grain boundaries, eventually leading to a lowering of the thermal conductivity and fuel swelling. Recent computational studies have identified that differences in grain boundary structure have a significant effect on the segregation behavior of fission products. However, experimental work supporting these simulations is lacking. Atom probe tomography was used to measure the Kr distribution across grain boundaries in UO2. Polycrystalline depleted-UO2 samples was irradiated with 0.7 and 1.8 MeV Kr-ions and annealed to 1000, 1300, and 1600°C for 1 hour to produce a Kr-bubble dominated microstructure. The results of this work indicate a strong dependence of Kr concentration as a function of grain boundary structure. Temperature also influences grain boundary chemistry with greater Kr concentration evident at higher temperatures, resulting in a reduced Kr concentration in the bulk. While Kr migration is active at elevated temperatures, no changes in grain size or texture were observed in the irradiated samples.

Billy Valderrama; Lingfeng He; Hunter B. Henderson; Janne Pakarinen; Brian Jaques; Jian Gan; Darryl P. Butt; Todd R. Allen; Michele V. Manuel

2015-01-01T23:59:59.000Z

490

Conceptual Design of a CERMET NTR Fission Core Using Multiphysics Modeling Techniques  

SciTech Connect (OSTI)

An initial pre-conceptual CERMET Nuclear Thermal Propulsion reactor system is investigated within this paper. Reactor configurations are investigated where the fuel consists of 60 vol.% UO2 and 40 vol.% W where the UO2 consists of Gd2O3 concentrations of 5 and 10 mol.%.Gd2O3. The fuel configuration consisting of 5 mol.% UO2 was found to have a total mass of 2761 kg and a thrust to weight ratio of 4.10 and required a coolant channel surface area to fueled volume ratio of approximately 15.0 in order to keep the centerline temperature below 3000 K. The configuration consisting of 10 mol.% Gd2O3 required a surface area to volume ratio of approximately 12.2 to cool the reactor to a peak temperature of 3000 K and had a total mass of 3200 kg and a thrust to weight ratio of 3.54. It is not known yet what concentration of Gd2O3 is required to maintain fuel stability at 3000 K; however, both reactors offer the potential for operations at 25,000 lb, and at a specific impulse which may range from 900 to 950 seconds.

Jonathan A. Webb; Brian J. Gross; William T. Taitano

2011-08-01T23:59:59.000Z

491

Criticality Safety Code Validation with LWBR’s SB Cores  

SciTech Connect (OSTI)

The first set of critical experiments from the Shippingport Light Water Breeder Reactor Program included eight, simple geometry critical cores built with 233UO2-ZrO2, 235UO2-ZrO2, ThO2, and ThO2-233UO2 nuclear materials. These cores are evaluated, described, and modeled to provide benchmarks and validation information for INEEL criticality safety calculation methodology. In addition to consistency with INEEL methodology, benchmark development and nuclear data are consistent with International Criticality Safety Benchmark Evaluation Project methodology.Section 1 of this report introduces the experiments and the reason they are useful for validating some INEEL criticality safety calculations. Section 2 provides detailed experiment descriptions based on currently available experiment reports. Section 3 identifies criticality safety validation requirement sources and summarizes requirements that most affect this report. Section 4 identifies relevant hand calculation and computer code calculation methodologies used in the experiment evaluation, benchmark development, and validation calculations. Section 5 provides a detailed experiment evaluation. This section identifies resolutions for currently unavailable and discrepant information. Section 5 also reports calculated experiment uncertainty effects. Section 6 describes the developed benchmarks. Section 6 includes calculated sensitivities to various benchmark features and parameters. Section 7 summarizes validation results. Appendices describe various assumptions and their bases, list experimenter calculations results for items that were independently calculated for this validation work, report other information gathered and developed by SCIENTEC personnel while evaluating these same experiments, and list benchmark sample input and miscellaneous supplementary data.

Putman, Valerie Lee

2003-01-01T23:59:59.000Z

492

In situ treatment of VOCs by recirculation technologies  

SciTech Connect (OSTI)

The project described herein was conducted by Oak Ridge National Laboratory (ORNL) to identify processes and technologies developed in Germany that appeared to have near-term potential for enhancing the cleanup of volatile organic compound (VOC) contaminated soil and groundwater at DOE sites. Members of the ORNL research team identified and evaluated selected German technologies developed at or in association with the University of Karlsruhe (UoK) for in situ treatment of VOC contaminated soils and groundwater. Project activities included contacts with researchers within three departments of the UoK (i.e., Applied Geology, Hydromechanics, and Soil and Foundation Engineering) during fall 1991 and subsequent visits to UoK and private industry collaborators during February 1992. Subsequent analyses consisted of engineering computations, groundwater flow modeling, and treatment process modeling. As a result of these project efforts, two processes were identified as having near-term potential for DOE: (1) the vacuum vaporizer well/groundwater recirculation well and (2) the porous pipe/horizontal well. This document was prepared to summarize the methods and results of the assessment activities completed during the initial year of the project. The project is still ongoing, so not all facets of the effort are completely described in this document. Recommendations for laboratory and field experiments are provided.

Siegrist, R.L.; Webb, O.F.; Ally, M.R.; Sanford, W.E. [Oak Ridge National Lab., TN (US); Kearl, P.M.; Zutman, J.L. [Oak Ridge National Lab., Grand Junction, CO (US)

1993-06-01T23:59:59.000Z

493

Experimental Results for SimFuels  

SciTech Connect (OSTI)

Assessing the performance of Spent (or Used) Nuclear Fuel (UNF) in geological repository requires quantification of time-dependent phenomena that may influence its behavior on a time-scale up to millions of years. A high-level waste repository environment will be a dynamic redox system because of the time-dependent generation of radiolytic oxidants and reductants and the corrosion of Fe-bearing canister materials. One major difference between used fuel and natural analogues, including unirradiated UO2, is the intense radiolytic field. The radiation emitted by used fuel can produce radiolysis products in the presence of water vapor or a thin-film of water that may increase the waste form degradation rate and change radionuclide behavior. To study UNF, we have been working on producing synthetic UO2 ceramics, or SimFuels that can be used in testing and which will contain specific radionuclides or non-radioactive analogs so that we can test the impact of radiolysis on fuel corrosion without using actual spent fuel. Although, testing actual UNF would be ideal for understanding the long term behavior of UNF, it requires the use of hot cells and is extremely expensive. In this report, we discuss, factors influencing the preparation of SimFuels and the requirements for dopants to mimic the behavior of UNF. We have developed a reliable procedure for producing large grain UO2 at moderate temperatures. This process will be applied to a series of different formulations.

Buck, Edgar C.; Casella, Andrew M.; Skomurski, Frances N.; MacFarlan, Paul J.; Soderquist, Chuck Z.; Wittman, Richard S.; Mcnamara, Bruce K.

2012-08-22T23:59:59.000Z

494

A Spectroscopic Study of the effect of Ligand Complexation on the Reduction of Uranium(VI) by Anthraquinone-2,6-disulfonate (AH2DS)  

SciTech Connect (OSTI)

In this project, the reduction rate of uranyl complexes with hydroxide, carbonate, EDTA, and Desferriferrioxamine B (DFB) by anthraquinone-2,6-disulfonate (AH2DS), a potential electron shuttle for microbial reduction of metal ions (Newman and Kolter 2000), is studied by stopped-flow kinetics techniques under anoxic atmosphere. The apparent reaction rates varied with ligand type, solution pH, and U(VI) concentration. For each ligand, a single largest kobs within the studied pH range was observed, suggesting the influence of pH-dependent speciation on the U(VI) reduction rate. The maximum reaction rate found in each case followed the order of OH- > CO32- > EDTA > DFB, consistent with the same trend of the thermodynamic stability of the uranyl complexes and ionic sizes of the ligands. Increasing the stability of uranyl complexes and ligand size decreased the maximum reduction rate. The pH-dependent rates were modeled using a second-order rate expression that was assumed to be dependent on a single U(VI) complex and AH2DS species. By quantitatively comparing the calculated and measured apparent rate constants as a function of pH, species AHDS3- was suggested as the primary reductant in all cases examined. Species UO2CO3(aq) , UO2HEDTA-, and (UO2)2(OH)22+ were suggested as the principal electron acceptors among the U(VI) species mixture in carbonate, EDTA, and hydroxyl systems, respectively.

Wang, Zheming; Wagnon, Ken B.; Ainsworth, Calvin C.; Liu, Chongxuan; Rosso, Kevin M.; Fredrickson, Jim K.

2008-11-03T23:59:59.000Z

495

Please cite this article in press as: M.S. Glover, et al., Int. J. Mass Spectrom. (2013), http://dx.doi.org/10.1016/j.ijms.2013.06.014 ARTICLE IN PRESS  

E-Print Network [OSTI]

Please cite this article in press as: M.S. Glover, et al., Int. J. Mass Spectrom. (2013), http Matthew S. Glover, Jonathan M. Dilger, Feifei Zhu, David E. Clemmer Department of Chemistry, Indiana

Clemmer, David E.

496

The Plant Cell, Vol. 7, 1847-1857, November 1995 O 1995 American Society of Plant Physiologists The D-Type Alfalfa Cyclin Gene cycMs4 Complements G1  

E-Print Network [OSTI]

The D-Type Alfalfa Cyclin Gene cycMs4 Complements G1 Cyclin-Deficient Yeast and 1s lnduced in the G1 eukaryotes. In alfalfa, we have previously isolated three 6-type cyclins. The closely related cycMsl and cyc.y complementation of G1 cyclin-deficient yeast cells, a nove1 alfalfa cyclin, designated cycMs4, was isolated

Hirt, Heribert

497

Kinematics and thermodynamics across a propagating non-stoichiometric oxidation phase front in spent fuel grains  

SciTech Connect (OSTI)

Spent fuel contains mixtures, alloy and compound, but are dominated by U and O except for some UO{sub 2} fuels with burnable poisons (gadolinia in BWR rods), the other elements evolve during reactor operation from neutron reaction and fission + fission decay events. Due to decay, chemical composition and activity of spent fuel will continue to evolve after removal from reactors. During the time interval with significant radioactivity levels relevant for a geological repository, it is important to develop models for potential chemical responses in spent fuel and potential degradation of repository. One such potential impact is the oxidation of spent fuel, which results in initial phase change of UO{sub 2} lattice to U{sub 4}O{sub 9} and the next phase change is probably to U{sub 3}O{sub 8} although it has not been observed yet below 200C. The U{sub 4}O{sub 9} lattice is nonstoichiometric with a O/U weight ratio at 2.4. Preliminary indications are that the UO{sub 2} has a O/U of 2. 4 at the time just before it transforms into the U{sub 4}O{sub 9} phase. In the oxygen weight gain versus time response, a plateau appears as the O/U approaches 2.4. Part of this plateau is due to geometrical effects of a U{sub 4}O{sub 9} phase change front propagating into UO{sub 2} grain volumes; however, this may indicate a metastable phase change delay kinetics or a diffusional related delay time until the oxygen density can satisfy stoichiometry and energy conditions for phase changes. Experimental data show a front of U{sub 4}O{sub 9} lattice structure propagating into grains of the UO{sub 2} lattice. To describe this spatially inhomogenous oxidation phase transition, as well as the expected U{sub 3}O{sub 8} phase transition from the U{sub 4}O{sub 9} lattice, lattice models are developed and spatially discontinuous kinematic and energetic expressions are derived. 9 refs.

Stout, R.B.; Kansa, E.J.; Wijesinghe, A.M.

1993-09-01T23:59:59.000Z

498

The nature and fate of natural resins in the geosphere - VIII - NMR and Py-GC-MS characterization of soluble labdanoid polymers isolated from holocene class I resins.  

SciTech Connect (OSTI)

Soluble polylabdanoids isolated by sequential solvent extraction have been characterized by liquid-state {sup 13}C- and {sup 1}H NMR and {sup 13}C-{sup 1}H HMQC (heteronuclear correlation) NMR spectroscopy in addition to solid-state NMR and Py-GC-MS techniques. Two Holocene resins originating from Santander, Colombia and Mombasa, Kenya were analyzed. Soluble polymers were isolated by extraction with a 1:1 (v/v) methylene chloride-methanol mixture following sequential extractions with methylene chloride and methanol. The molecular weight of polymer extracts was shown by GPC analyses to exceed that of non-polymeric occluded terpenoids. Py-GC-MS, solid-state {sup 13}C CP/MAS and {sup 13}C cross-polarization/depolarization NMR spectroscopy results indicated that chemical compositions of soluble polymers isolated from immature resins are highly representative of the structure of corresponding insoluble polymers, i.e. polylabdatrienes. These data provide evidence for cross-linking or cyclization of side-chain olefinic carbons during or shortly after polymerization. Generally, the characterization of soluble resin polymers by liquid-state NMR spectroscopy has proven to be an excellent means for investigating the maturation mechanism of polylabdanoid resinites, and has potential for furthering the application of Class I resinites as geothermal indicators.

Clifford, D. J.; Hatcher, P. G.; Botto, R. E.; Muntean, J. V.; Michaels, B.; Anderson, K. B.; Chemistry; Pennsylvania State Univ.; Amoco Oil Co.

1997-01-01T23:59:59.000Z

499

In-Situ Measurements of Low Enrichment Uranium Holdup Process Gas Piping at K-25 - Paper for Waste Management Symposia 2010 East Tennessee Technology Park Oak Ridge, Tennessee  

SciTech Connect (OSTI)

This document is the final version of a paper submitted to the Waste Management Symposia, Phoenix, 2010, abstract BJC/OR-3280. The primary document from which this paper was condensed is In-Situ Measurement of Low Enrichment Uranium Holdup in Process Gas Piping at K-25 Using NaI/HMS4 Gamma Detection Systems, BJC/OR-3355. This work explores the sufficiency and limitations of the Holdup Measurement System 4 (HJVIS4) software algorithms applied to measurements of low enriched uranium holdup in gaseous diffusion process gas piping. HMS4 has been used extensively during the decommissioning and demolition project of the K-25 building for U-235 holdup quantification. The HMS4 software is an integral part of one of the primary nondestructive assay (NDA) systems which was successfully tested and qualified for holdup deposit quantification in the process gas piping of the K-25 building. The initial qualification focused on the measurement of highly enriched UO{sub 2}F{sub 2} deposits. The purpose of this work was to determine if that qualification could be extended to include the quantification of holdup in UO{sub 2}F{sub 2} deposits of lower enrichment. Sample field data are presented to provide evidence in support of the theoretical foundation. The HMS4 algorithms were investigated in detail and found to sufficiently compensate for UO{sub 2}F{sub 2} source self-attenuation effects, over the range of expected enrichment (4-40%), in the North and East Wings of the K-25 building. The limitations of the HMS4 algorithms were explored for a described set of conditions with respect to area source measurements of low enriched UO{sub 2}F{sub 2} deposits when used in conjunction with a 1 inch by 1/2 inch sodium iodide (NaI) scintillation detector. The theoretical limitations of HMS4, based on the expected conditions in the process gas system of the K-25 building, are related back to the required data quality objectives (DQO) for the NBA measurement system established for the K-25 demolition project. The combined review of the HMS software algorithms and supporting field measurements lead to the conclusion that the majority of process gas pipe measurements are adequately corrected for source self-attenuation using HMS4. While there will be instances where the UO{sub 2}F{sub 2} holdup mass presents an infinitely thick deposit to the NaI-HMS4 system these situations are expected to be infrequent. This work confirms that the HMS4 system can quantify UO{sub 2}F{sub 2} holdup, in its current configuration (deposition, enrichment, and geometry), below the DQO levels for the K-25 building decommissioning and demolition project. For an area measurement of process gas pipe in the K-25 building, if an infinitely thick UO{sub 2}F{sub 2} deposit is identified in the range of enrichment of {approx}4-40%, the holdup quantity exceeds the corresponding DQO established for the K-25 building demolition project.

Rasmussen B.

2010-01-01T23:59:59.000Z

500

Pillared and open-framework uranyl diphosphonates  

SciTech Connect (OSTI)

The hydrothermal reactions of uranium trioxide, uranyl acetate, or uranyl nitrate with 1,4-benzenebisphosphonic acid in the presence of very small amount of HF at 200 deg. C results in the formation of three different uranyl diphosphonate compounds, [H{sub 3}O]{sub 2}{l_brace}(UO{sub 2}){sub 6}[C{sub 6}H{sub 4}(PO{sub 3})(PO{sub 2}OH)]{sub 2}[C{sub 6}H{sub 4}(PO{sub 2}OH){sub 2}]{sub 2}[C{sub 6}H{sub 4}(PO{sub 3}){sub 2}]{r_brace}(H{sub 2}O){sub 2} (Ubbp-1), [H{sub 3}O]{sub 4}{l_brace}(UO{sub 2}){sub 4}[C{sub 6}H{sub 4}(PO{sub 3}){sub 2}]{sub 2}F{sub 4}{r_brace}.H{sub 2}O (Ubbp-2), and {l_brace}(UO{sub 2})[C{sub 6}H{sub 2}F{sub 2}(PO{sub 2}OH){sub 2}(H{sub 2}O){r_brace}{sub 2}.H{sub 2}O (Ubbp-3). The crystal structures of these compounds were determined by single crystal X-ray diffraction experiments. Ubbp-1 consists of UO{sub 7} pentagonal bipyramids that are bridged by the phosphonate moieties to form a three-dimensional pillared structure. Ubbp-2 is composed of UO{sub 5}F{sub 2} pentagonal bipyramids that are bridged through the phosphonate oxygen atoms into one-dimensional chains that are cross-linked by the phenyl spacers into a pillared structure. The structure of Ubbp-3 is a three-dimensional open-framework with large channels containing water molecules with internal dimensions of approximately 10.9x10.9 A. Ubbp-1 and Ubbp-2 fluoresce at room temperature. - Graphical Abstract: Illustration of the three-dimensional open-framework structure of {l_brace}(UO{sub 2})[C{sub 6}H{sub 2}F{sub 2}(PO{sub 2}OH){sub 2}(H{sub 2}O){r_brace}{sub 2}.H{sub 2}O viewed along the c-axis. The structure is constructed from UO{sub 7} units, pentagonal bipyramids=green, oxygen=red, phosphorus=magenta, carbon=black, hydrogen=white. Highlights: > The influence of the uranyl salt anions and pH were critically examined in relation to structural variation. > The acetate and nitrate counter ions of uranyl may be acting as structure directing agents. > The use of rigid phenyl spacer yield a three-dimensional network of pillared structures of uranyl diphosphonates that fluoresce. > The fluorination of the phenyl ring under hydrothermal condition. > The large voids in this structure are suggestive of potential applications in sorption, separation of gases and in catalytic processes.

Adelani, Pius O. [Department of Civil Engineering and Geological Sciences, 156 Fitzpatrick Hall, University of Notre Dame, Notre Dame, IN 46556 (United States); Department of Chemistry and Biochemistry, 156 Fitzpatrick Hall, University of Notre Dame, Notre Dame, IN 46556 (United States); Albrecht-Schmitt, Thomas E., E-mail: talbrec1@nd.edu [Department of Civil Engineering and Geological Sciences, 156 Fitzpatrick Hall, University of Notre Dame, Notre Dame, IN 46556 (United States); Department of Chemistry and Biochemistry, 156 Fitzpatrick Hall, University of Notre Dame, Notre Dame, IN 46556 (United States)

2011-09-15T23:59:59.000Z