National Library of Energy BETA

Sample records for morphology physical properties

  1. PHYSICAL AND MORPHOLOGICAL PROPERTIES OF [O II] EMITTING GALAXIES IN THE HETDEX PILOT SURVEY

    SciTech Connect (OSTI)

    Bridge, Joanna S.; Gronwall, Caryl; Ciardullo, Robin; Hagen, Alex; Zeimann, Greg; Malz, A. I.; Schneider, Donald P. E-mail: caryl@astro.psu.edu E-mail: hagen@psu.edu E-mail: aimalz@psu.edu; and others

    2015-02-01

    The Hobby-Eberly Dark Energy Experiment pilot survey identified 284 [O II] ?3727 emitting galaxies in a 169arcmin{sup 2} field of sky in the redshift range 0 < z < 0.57. This line flux limited sample provides a bridge between studies in the local universe and higher-redshift [O II] surveys. We present an analysis of the star formation rates (SFRs) of these galaxies as a function of stellar mass as determined via spectral energy distribution fitting. The [O II] emitters fall on the ''main sequence'' of star-forming galaxies with SFR decreasing at lower masses and redshifts. However, the slope of our relation is flatter than that found for most other samples, a result of the metallicity dependence of the [O II] star formation rate indicator. The mass-specific SFR is higher for lower mass objects, supporting the idea that massive galaxies formed more quickly and efficiently than their lower mass counterparts. This is confirmed by the fact that the equivalent widths of the [O II] emission lines trend smaller with larger stellar mass. Examination of the morphologies of the [O II] emitters reveals that their star formation is not a result of mergers, and the galaxies' half-light radii do not indicate evolution of physical sizes.

  2. Morphology of Gas Release in Physical Simulants

    SciTech Connect (OSTI)

    Daniel, Richard C.; Burns, Carolyn A.; Crawford, Amanda D.; Hylden, Laura R.; Bryan, Samuel A.; MacFarlan, Paul J.; Gauglitz, Phillip A.

    2014-07-03

    This report documents testing activities conducted as part of the Deep Sludge Gas Release Event Project (DSGREP). The testing described in this report focused on evaluating the potential retention and release mechanisms of hydrogen bubbles in underground radioactive waste storage tanks at Hanford. The goal of the testing was to evaluate the rate, extent, and morphology of gas release events in simulant materials. Previous, undocumented scoping tests have evidenced dramatically different gas release behavior from simulants with similar physical properties. Specifically, previous gas release tests have evaluated the extent of release of 30 Pa kaolin and 30 Pa bentonite clay slurries. While both materials are clays and both have equivalent material shear strength using a shear vane, it was found that upon stirring, gas was released immediately and completely from bentonite clay slurry while little if any gas was released from the kaolin slurry. The motivation for the current work is to replicate these tests in a controlled quality test environment and to evaluate the release behavior for another simulant used in DSGREP testing. Three simulant materials were evaluated: 1) a 30 Pa kaolin clay slurry, 2) a 30 Pa bentonite clay slurry, and 3) Rayleigh-Taylor (RT) Simulant (a simulant designed to support DSGREP RT instability testing. Entrained gas was generated in these simulant materials using two methods: 1) application of vacuum over about a 1-minute period to nucleate dissolved gas within the simulant and 2) addition of hydrogen peroxide to generate gas by peroxide decomposition in the simulants over about a 16-hour period. Bubble release was effected by vibrating the test material using an external vibrating table. When testing with hydrogen peroxide, gas release was also accomplished by stirring of the simulant.

  3. Growth morphology and properties of metals on graphene (Journal...

    Office of Scientific and Technical Information (OSTI)

    Growth morphology and properties of metals on graphene Citation Details In-Document Search This content will become publicly available on December 1, 2016 Title: Growth morphology ...

  4. PHYSICAL PROPERTIES OF SPECTROSCOPICALLY CONFIRMED GALAXIES AT z {>=} 6. II. MORPHOLOGY OF THE REST-FRAME UV CONTINUUM AND Ly{alpha} EMISSION

    SciTech Connect (OSTI)

    Jiang Linhua; Windhorst, Rogier A.; Cohen, Seth H.; Mechtley, Matthew; Egami, Eiichi; Fan Xiaohui; Dave, Romeel; Finlator, Kristian; Kashikawa, Nobunari; Ouchi, Masami; Shimasaku, Kazuhiro

    2013-08-20

    We present a detailed structural and morphological study of a large sample of spectroscopically confirmed galaxies at z {>=} 6 using deep Hubble Space Telescope (HST) near-IR broad-band images and Subaru Telescope optical narrow-band images. The galaxy sample consists of 51 Ly{alpha} emitters (LAEs) at z {approx_equal} 5.7, 6.5, and 7.0, and 16 Lyman break galaxies (LBGs) at 5.9 {<=} z {<=} 6.5. These galaxies exhibit a wide range of rest-frame UV continuum morphology in the HST images, from compact features to multiple component systems. The fraction of merging/interacting galaxies reaches 40%-50% at the brightest end of M{sub 1500} {<=} -20.5 mag. The intrinsic half-light radii r{sub hl,in}, after correcting for point-spread function (PSF) broadening, are roughly between r{sub hl,in} {approx_equal} 0.''05 (0.3 kpc) and 0.''3 (1.7 kpc) at M{sub 1500} {<=} -19.5 mag. The median r{sub hl,in} value is 0.''16 ({approx}0.9 kpc). This is consistent with the sizes of bright LAEs and LBGs at z {>=} 6 found in previous studies. In addition, more luminous galaxies tend to be larger and exhibit a weak size-luminosity relation, r{sub hl,in}{proportional_to}L {sup 0.14} at M{sub 1500} {<=} -19.5 mag. The slope of 0.14 is significantly flatter than those in fainter LBG samples. We discuss the morphology of z {>=} 6 galaxies with nonparametric methods, including the concentration, asymmetry, and smoothness system and the Gini and M{sub 20} parameters, and demonstrate their validity through simulations. We search for extended Ly{alpha} emission halos around LAEs at z {approx_equal} 5.7 and 6.5 by stacking a number of narrow-band images. We do not find evidence of extended Ly{alpha} halos predicted by cosmological simulations. Such halos, if they exist, could be weaker than predicted. Finally, we investigate positional misalignment between the UV continuum and Ly{alpha} emissions in LAEs. While the two positions are generally consistent, several merging galaxies show significant

  5. Physical Properties of Gas Hydrates: A Review

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gabitto, Jorge F.; Tsouris, Costas

    2010-01-01

    Memore » thane gas hydrates in sediments have been studied by several investigators as a possible future energy resource. Recent hydrate reserves have been estimated at approximately 10 16   m 3 of methane gas worldwide at standard temperature and pressure conditions. In situ dissociation of natural gas hydrate is necessary in order to commercially exploit the resource from the natural-gas-hydrate-bearing sediment. The presence of gas hydrates in sediments dramatically alters some of the normal physical properties of the sediment. These changes can be detected by field measurements and by down-hole logs. An understanding of the physical properties of hydrate-bearing sediments is necessary for interpretation of geophysical data collected in field settings, borehole, and slope stability analyses; reservoir simulation; and production models. This work reviews information available in literature related to the physical properties of sediments containing gas hydrates. A brief review of the physical properties of bulk gas hydrates is included. Detection methods, morphology, and relevant physical properties of gas-hydrate-bearing sediments are also discussed.« less

  6. Physical properties of residential insulations

    SciTech Connect (OSTI)

    Yarbrough, D.W.

    1980-01-01

    Research to evaluate properties, test methods and operating environments for thermal insulations used in residences is an important part of the Building Thermal Envelope Systems and Insulating Materials (BTESIM) program sponsored by the US DOE. Three projects were carried out under the Insulating Materials part of BTESIM. The areas discussed are: (1) the thermal performance of mineral fiber insulating batts, (2) the design density for loose-fill insulations, and (3) the operatio of recesses light fixtures covered by loose-fill cellulosic insulation.

  7. Acoustical, morphological and optical properties of oral rehydration salts (ORS)

    SciTech Connect (OSTI)

    George, Preetha Mary E-mail: jayakumars030@gmail.com; Divya, P.; Jayakumar, S. E-mail: jayakumars030@gmail.com; Subhashree, N. S.; Ahmed, M. Anees

    2015-06-24

    Ultrasonic velocity, density and viscosity were measured in different concentrations of oral rehydration salts (ORS) at room temperature 303 k. From the experimental data other related thermodynamic parameters, viz adiabatic compressibility, intermolecular free length, acoustic impedence, relaxation time are calculated. The experimental data were discussed in the light of molecular interaction existing in the liquid mixtures. The results have been discussed in terms of solute-solvent interaction between the components. Structural characterization is important for development of new material. The morphology, structure and grain size of the samples are investigated by SEM. The optical properties of the sample have been studied using UV Visible spectroscopy.

  8. Physical Properties of Gas Hydrates: A Review (Journal Article...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Physical Properties of Gas Hydrates: A Review Citation Details In-Document Search Title: Physical Properties of Gas Hydrates: A Review Methane gas hydrates in ...

  9. Physical Properties of Gas Hydrates: A Review (Journal Article...

    Office of Scientific and Technical Information (OSTI)

    Physical Properties of Gas Hydrates: A Review Citation Details In-Document Search Title: Physical Properties of Gas Hydrates: A Review Methane gas hydrates in sediments have been ...

  10. Growth morphology and properties of metals on graphene

    SciTech Connect (OSTI)

    Liu, Xiaojie; Han, Yong; Evans, James W.; Engstfeld, Albert K.; Behm, R. Juergen; Tringides, Michael C.; Hupalo, Myron; Lin, Hai -Qing; Huang, Li; Ho, Kai -Ming; Appy, David; Thiel, Patricia A.; Wang, Cai -Zhuang

    2015-12-01

    Graphene, a single atomic layer of graphite, has been the focus of recent intensive studies due to its novel electronic and structural properties. With this study, metals grown on graphene also have been of interest because of their potential use as metal contacts in graphene devices, for spintronics applications, and for catalysis. All of these applications require good understanding and control of the metal growth morphology, which in part reflects the strength of the metal–graphene bond. The interaction between graphene and metal is sufficiently strong to modify the electronic structure of graphene is also of great importance. We will discuss recent experimental and computational studies related to deposition of metals on graphene supported on various substrates (SiC, SiO2, and hexagonal close-packed metal surfaces). Of specific interest are the metal–graphene interactions (adsorption energies and diffusion barriers of metal adatoms), and the crystal structures and thermal stability of the metal nanoclusters.

  11. Physical Properties of Hanford Transuranic Waste

    SciTech Connect (OSTI)

    Berg, John C.

    2010-03-25

    The research described herein was undertaken to provide needed physical property descriptions of the Hanford transuranic tank sludges under conditions that might exist during retrieval, treatment, packaging and transportation for disposal. The work addressed the development of a fundamental understanding of the types of systems represented by these sludge suspensions through correlation of the macroscopic rheological properties with particle interactions occurring at the colloidal scale in the various liquid media. The results of the work have advanced existing understanding of the sedimentation and aggregation properties of complex colloidal suspensions. Bench scale models were investigated with respect to their structural, colloidal and rheological properties that should be useful for the development and optimization of techniques to process the wastes at various DOE sites.

  12. Growth morphology and properties of metals on graphene

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Liu, Xiaojie; Han, Yong; Evans, James W.; Engstfeld, Albert K.; Behm, R. Juergen; Tringides, Michael C.; Hupalo, Myron; Lin, Hai -Qing; Huang, Li; Ho, Kai -Ming; et al

    2015-12-01

    Graphene, a single atomic layer of graphite, has been the focus of recent intensive studies due to its novel electronic and structural properties. With this study, metals grown on graphene also have been of interest because of their potential use as metal contacts in graphene devices, for spintronics applications, and for catalysis. All of these applications require good understanding and control of the metal growth morphology, which in part reflects the strength of the metal–graphene bond. The interaction between graphene and metal is sufficiently strong to modify the electronic structure of graphene is also of great importance. We will discussmore » recent experimental and computational studies related to deposition of metals on graphene supported on various substrates (SiC, SiO2, and hexagonal close-packed metal surfaces). Of specific interest are the metal–graphene interactions (adsorption energies and diffusion barriers of metal adatoms), and the crystal structures and thermal stability of the metal nanoclusters.« less

  13. The physical properties of microcellular composite foams

    SciTech Connect (OSTI)

    Nyitray, A.M.; Williams, J.M.; Onn, D.; Witek, A. (Los Alamos National Lab., NM (USA); Delaware Univ., Newark, DE (USA). Applied Thermal Physics Lab.)

    1989-01-01

    Recently we reported on a method of preparing microcellular composite foams. In this procedure an open-celled polystyrene foam is prepared by the polymerization of a high-internal-phase water-in-oil emulsion containing styrene, divinylbenzene, surfactant, free-radial initiator and water. After drying, the cells of the polystyrene foam are then filled with other materials such as aerogel or resoles. The physical properties of these materials, e.g., surface area, density, thermal conductivity, and compressive strength will be presented. 10 refs., 1 fig., 3 tabs.

  14. Effect of suspension property on granule morphology and compaction behavior

    SciTech Connect (OSTI)

    Hae-Weon Lee, Guesup Song, In-Sik Suk

    1995-12-31

    Granule morphology is an important factor during dry pressing, since it has great influences on die flowability, compaction ratio, and resulting green microstructure. Granule morphology and packing structure of ultrafine Si{sub 3}N{sub 4} particles in the granule were optimized during spray drying by adjusting the suspension structure. The particle packing structure of spray-dried granule was investigated with suspension structure. The effects of granule morphology and its particle packing structure on compaction and resultant sintering behavior were evaluated.

  15. HYDRAULIC AND PHYSICAL PROPERTIES OF MCU SALTSTONE

    SciTech Connect (OSTI)

    Dixon, K; Mark Phifer, M

    2008-03-19

    The Saltstone Disposal Facility (SDF), located in the Z-Area of the Savannah River Site (SRS), is used for the disposal of low-level radioactive salt solution. The SDF currently contains two vaults: Vault 1 (6 cells) and Vault 4 (12 cells). Additional disposal cells are currently in the design phase. The individual cells of the saltstone facility are filled with saltstone., Saltstone is produced by mixing the low-level radioactive salt solution, with blast furnace slag, fly ash, and cement or lime to form a dense, micro-porous, monolithic, low-level radioactive waste form. The saltstone is pumped into the disposal cells where it subsequently solidifies. Significant effort has been undertaken to accurately model the movement of water and contaminants through the facility. Key to this effort is an accurate understanding of the hydraulic and physical properties of the solidified saltstone. To date, limited testing has been conducted to characterize the saltstone. The primary focus of this task was to estimate the hydraulic and physical properties of MCU (Modular Caustic Side Solvent Extraction Unit) saltstone relative to two permeating fluids. These fluids included simulated groundwater equilibrated with vault concrete and simulated saltstone pore fluid. Samples of the MCU saltstone were prepared by the Savannah River National Laboratory (SRNL) and allowed to cure for twenty eight days prior to testing. These samples included two three-inch diameter by six inch long mold samples and three one-inch diameter by twelve inch long mold samples.

  16. Oxygen Control of Atomic Structure and Physical Properties of...

    Office of Scientific and Technical Information (OSTI)

    Properties of SrRuO3 Surfaces Citation Details In-Document Search Title: Oxygen Control of Atomic Structure and Physical Properties of SrRuO3 Surfaces Authors: Tselev, ...

  17. Physical Properties of Hanford Transuranic Waste Sludge

    SciTech Connect (OSTI)

    Berg, John C.

    2005-06-01

    Equipment that was purchased in the abbreviated year 1 of this project has been used during year 2 to study the fundamental behavior of materials that simulate the behavior of the Hanford transuranic waste sludge. Two significant results have been found, and each has been submitted for publication. Both studies found non-DLVO behavior in simulant systems. These separate but related studies were performed concurrently. It was previously shown in Rassat et al.'s report Physical and Liquid Chemical Simulant Formulations for Transuranic Wastes in Hanford Single-Shell Tanks that colloidal clays behave similarly to transuranic waste sludge (PNNL-14333, National Technical Information Service, U.S. Dept. of Commerce). Rassat et al. also discussed the pH and salt content of actual waste materials. It was shown that these materials exist at high pHs, generally above 10, and at high salt content, approximately 1.5 M from a mixture of different salts. A type of clay commonly studied, due to its uniformity, is a synthetic hectorite, Laponite. Therefore the work performed over the course of the last year was done mainly using suspensions of Laponite at high pH and involving high salt concentrations. One study was titled ''Relating Clay Rheology to Colloidal Parameters''. It has been submitted to the Journal of Colloid and INterface Science and is currently in the review process. The idea was to gain the ability to use measurable quantities to predict the flow behavior of clay systems, which should be similar to transuranic waste sludge. Leong et al. had previously shown that the yield stress of colloidal slurries of titania and alumina could be predicted, given the measurement of the accessible parameter zeta potential (Leong YK et al. J Chem Soc Faraday Trans, 19 (1993) 2473). Colloidal clays have a fundamentally different morphology and surface charge distribution than the spheroidal, uniformly charged colloids previously studied. This study was therefore performed in order to

  18. Measuring Physical Properties of Polymer Electrolyte Membranes | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy Measuring Physical Properties of Polymer Electrolyte Membranes Measuring Physical Properties of Polymer Electrolyte Membranes Presented by Cortney Mittelsteadt of Giner Electrochemical Systems, LLC, at the DOE High Temperature Membrane Working Group held September 14, 2006. htmwg_mittelsteadt.pdf (450.28 KB) More Documents & Publications Membrane Performance and Durability Overview for Automotive Fuel Cell Applications 2006 DOE Hydrogen Program Dimensionally Stable High

  19. COLLOQUIUM: Exploring the Physical Properties of Matter in Extreme

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Conditions | Princeton Plasma Physics Lab May 7, 2014, 4:00pm to 5:30pm Colloquia MBG Auditorium COLLOQUIUM: Exploring the Physical Properties of Matter in Extreme Conditions Siegfried Glenzer SLAC National Accelerator Laboratory One of the great challenges of this century is to determine if nuclear fusion of hydrogen isotopes can be demonstrated in the laboratory and developed into an unlimited carbon-free energy source. Recently, experiments on laser-driven targets have begun on the

  20. Effects of hypergravity on adipose-derived stem cell morphology, mechanical property and proliferation

    SciTech Connect (OSTI)

    Tavakolinejad, Alireza; Rabbani, Mohsen; Janmaleki, Mohsen

    2015-08-21

    Alteration in specific inertial conditions can lead to changes in morphology, proliferation, mechanical properties and cytoskeleton of cells. In this report, the effects of hypergravity on morphology of Adipose-Derived Stem Cells (ADSCs) are indicated. ADSCs were repeatedly exposed to discontinuous hypergravity conditions of 10 g, 20 g, 40 g and 60 g by utilizing centrifuge (three times of 20 min exposure, with an interval of 40 min at 1 g). Cell morphology in terms of length, width and cell elongation index and cytoskeleton of actin filaments and microtubules were analyzed by image processing. Consistent changes observed in cell elongation index as morphological change. Moreover, cell proliferation was assessed and mechanical properties of cells in case of elastic modulus of cells were evaluated by Atomic Force Microscopy. Increase in proliferation and decrease in elastic modulus of cells are further results of this study. Staining ADSC was done to show changes in cytoskeleton of the cells associated to hypergravity condition specifically in microfilament and microtubule components. After exposing to hypergravity, significant changes were observed in microfilaments and microtubule density as components of cytoskeleton. It was concluded that there could be a relationship between changes in morphology and MFs as the main component of the cells. - Highlights: • Hypergravity (10 g, 20 g, 40 g and 60 g) affects on adipose derived stem cells (ADSCs). • ADSCs after exposure to the hypergravity are more slender. • The height of ADSCs increases in all test groups comparing their control group. • Hypergravity decreases ADSCs modulus of elasticity and cell actin fiber content. • Hypergravity enhances proliferation rate of ADSCs.

  1. Physical property characterization of 183-H Basin sludge

    SciTech Connect (OSTI)

    Biyani, R.K.; Delegard, C.H.

    1995-09-20

    This document describes the characterization of 183-H Basin sludge physical properties, e.g. bulk density of sludge and absorbent, and determination of free liquids. Calcination of crucible-size samples of sludge was also done and the resulting `loss-on-ignition` was compared to the theoretical weight loss based on sludge analysis obtained from Weston Labs.

  2. Morphology Of Diesel Soot Residuals From Supercooled Water Droplets And Ice Crystals: Implications For Optical Properties

    SciTech Connect (OSTI)

    China, Swarup; Kulkarni, Gourihar; Scarnatio, Barbara; Sharma, Noopur; Pekour, Mikhail S.; Shilling, John E.; Wilson, Jacqueline M.; Zelenyuk, Alla; Chand, Duli; Liu, Shang; Aiken, Allison; Dubey, Manvendra K.; Laskin, Alexander; Zaveri, Rahul A.; Mazzoleni, Claudio

    2015-11-04

    Freshly emitted soot particles are fractal-like aggregates, but atmospheric processing often transforms their morphology. Morphology of soot particles plays an important role in determining their optical properties, life cycle and hence their effect on Earth’s radiative balance. However, little is known about the morphology of soot particles that participated in cold cloud processes. Here we report results from laboratory experiments that simulate cold cloud processing of diesel soot particles by allowing them to form supercooled droplets and ice crystals at -20 and -40°C, respectively. Electron microscopy revealed that soot residuals from ice crystals were more compact (roundness~0.55) than those from supercooled droplets (roundness ~0.45), while nascent soot particles were the least compact (roundness~0.41). Optical simulations using the discrete dipole approximation showed that the more compact structure enhances soot single scattering albedo by a factor up to 1.4, thereby reducing the top-of-the-atmosphere direct radiative forcing by ~63%. These results underscore that climate models should consider the morphological evolution of soot particles due to cold cloud processing to improve the estimate of direct radiative forcing of soot.

  3. Processing-structure-property relationships in electron beam physical vapor deposited yttria stabilized zirconia coatings

    SciTech Connect (OSTI)

    Rao, D. Srinivasa; Valleti, Krishna; Joshi, S. V.; Janardhan, G. Ranga

    2011-05-15

    The physical and mechanical properties of yttria stabilized zirconia (YSZ) coatings deposited by the electron beam physical vapor deposition technique have been investigated by varying the key process variables such as vapor incidence angle and sample rotation speed. The tetragonal zirconia coatings formed under varying process conditions employed were found to have widely different surface and cross-sectional morphologies. The porosity, phase composition, planar orientation, hardness, adhesion, and surface residual stresses in the coated specimens were comprehensively evaluated to develop a correlation with the process variables. Under transverse scratch test conditions, the YSZ coatings exhibited two different crack formation modes, depending on the magnitude of residual stress. The influence of processing conditions on the coating deposition rate, column orientation angle, and adhesion strength has been established. Key relationships between porosity, hardness, and adhesion are also presented.

  4. The correlation of epitaxial graphene properties and morphology of SiC (0001)

    SciTech Connect (OSTI)

    Guo, Y.; Guo, L. W., E-mail: lwguo@iphy.ac.cn, E-mail: xlchen@iphy.ac.cn; Huang, J.; Jia, Y. P.; Lin, J. J.; Lu, W.; Li, Z. L. [Research and Development Center for Functional Crystals, Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (China); Yang, R. [Nanoscale Physics and Devices Laboratory, Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (China); Chen, X. L., E-mail: lwguo@iphy.ac.cn, E-mail: xlchen@iphy.ac.cn [Research and Development Center for Functional Crystals, Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (China); Collaborative Innovation Center of Quantum Matter, Beijing 100190 (China)

    2014-01-28

    The electronic properties of epitaxial graphene (EG) on SiC (0001) depend sensitively on the surface morphology of SiC substrate. Here, 23 layers of graphene were grown on on-axis 6H-SiC with different step densities realized through controlling growth temperature and ambient pressure. We show that epitaxial graphene on SiC (0001) with low step density and straight step edge possesses fewer point defects laying mostly on step edges and higher carrier mobility. A relationship between step density and EG mobility is established. The linear scan of Raman spectra combined with the atomic force microscopy morphology images revealed that the Raman fingerprint peaks are nearly the same on terraces, but shift significantly while cross step edges, suggesting the graphene is not homogeneous in strain and carrier concentration over terraces and step edges of substrates. Thus, control morphology of epitaxial graphene on SiC (0001) is a simple and effective method to pursue optimal route for high quality graphene and will be helpful to prepare wafer sized graphene for device applications.

  5. Composition, morphology and mechanical properties of sputtered TiAlN coating

    SciTech Connect (OSTI)

    Budi, Esmar; Razali, M. Mohd.; Nizam, A. R. Md.

    2014-03-24

    TiAlN coating was deposited on the tungsten carbide cutting tool by using DC magnetron sputtering system to study the influence of substrate bias and nitrogen flow rate on the composition, morphology and mechanical properties. The negatively substrate bias and nitrogen flow rate was varied from about ?79 to ?221 V and 30 sccm to 72 sccm, respectively. The coating composition and roughness were characterized by using SEM/EDX and Atomic Force Microscopy (AFM), respectively. The dynamic ultra micro hardness tester was used to measure the mechanical properties. The coating hardness increases to about 10-12 GPa with an increase of the negatively substrate bias up to ? 200 V and it tend to decrease with an increase in nitrogen flow rate up to 70 sccm. The increase of hardness follows the increase of Ti and N content and rms coating roughness.

  6. Physical-chemical property based sequence motifs and methods regarding same

    DOE Patents [OSTI]

    Braun, Werner; Mathura, Venkatarajan S.; Schein, Catherine H.

    2008-09-09

    A data analysis system, program, and/or method, e.g., a data mining/data exploration method, using physical-chemical property motifs. For example, a sequence database may be searched for identifying segments thereof having physical-chemical properties similar to the physical-chemical property motifs.

  7. PHYSICAL PROPERTY MEASUREMENTS OF LABORATORY PREPARED SALTSTONE GROUT

    SciTech Connect (OSTI)

    Hansen, E.; Cozzi, A.; Edwards, T.

    2014-05-05

    The Saltstone Production Facility (SPF) built two new Saltstone Disposal Units (SDU), SDU 3 and SDU 5, in 2013. The variable frequency drive (VFD) for the grout transfer hose pump tripped due to high current demand by the motor during the initial radioactive saltstone transfer to SDU 5B on 12/5/2013. This was not observed during clean cap processing on July 5, 2013 to SDU 3A, which is a slightly longer distance from the SPF than is SDU 5B. Saltstone Design Authority (SDA) is evaluating the grout pump performance and capabilities to transfer the grout processed in SPF to SDU 3/5. To assist in this evaluation, grout physical properties are required. At this time, there are no rheological data from the actual SPF so the properties of laboratory prepared samples using simulated salt solution or Tank 50 salt solution will be measured. The physical properties of grout prepared in the laboratory with de-ionized water (DI) and salt solutions were obtained at 0.60 and 0.59 water to premix (W/P) ratios, respectively. The yield stress of the DI grout was greater than any salt grout. The plastic viscosity of the DI grout was lower than all of the salt grouts (including salt grout with admixture). When these physical data were used to determine the pressure drop and fluid horsepower for steady state conditions, the salt grouts without admixture addition required a higher pressure drop and higher fluid horsepower to transport. When 0.00076 g Daratard 17/g premix was added, both the pressure drop and fluid horsepower were below that of the DI grout. Higher concentrations of Daratard 17 further reduced the pressure drop and fluid horsepower. The uncertainty in the single point Bingham Plastic parameters is + 4% of the reported values and is the bounding uncertainty. Two different mechanical agitator mixing protocols were followed for the simulant salt grout, one having a total mixing time of three minutes and the other having a time of 10 minutes. The Bingham Plastic parameters

  8. Composition dependence of electronic, magnetic, transport and morphological properties of mixed valence manganite thin films

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Singh, Surendra; Freeland, J. W.; Fitzsimmons, Michael R.; Jeen, H.; Biswas, A.

    2016-07-27

    Mixed-valence manganese oxides present striking properties like the colossal magnetoresistance, metal-insulator transition (MIT) that may result from coexistence of ferromagnetic, metallic and insulating phases. Percolation of such phase coexistence in the vicinity of MIT leads to first-order transition in these manganites. However the length scales over which the electronic and magnetic phases are separated across MIT which appears compelling for bulk systems has been elusive in (La1-yPry)1-xCaxMnO3 films. Here we show the in-plane length scale over which charge and magnetism are correlated in (La0.4Pr0.6)1-xCaxMnO3 films with x = 0.33 and 0.375, across the MIT temperature. We combine electrical transport (resistance)more » measurements, x-ray absorption spectroscopy (XAS), x-ray magnetic circular dichroism (XMCD), and specular/off-specular x-ray resonant magnetic scattering (XRMS) measurements as a function of temperature to elucidate relationships between electronic, magnetic and morphological structure of the thin films. Using off-specular XRMS we obtained the charge-charge and charge-magnetic correlation length of these LPCMO films across the MIT. We observed different charge-magnetic correlation length for two films which increases below the MIT. The different correlation length shown by two films may be responsible for different macroscopic (transport and magnetic) properties.« less

  9. Computational Studies of Physical Properties of Boron Carbide

    SciTech Connect (OSTI)

    Lizhi Ouyang

    2011-09-30

    The overall goal is to provide valuable insight in to the mechanisms and processes that could lead to better engineering the widely used boron carbide which could play an important role in current plight towards greener energy. Carbon distribution in boron carbide, which has been difficult to retrieve from experimental methods, is critical to our understanding of its structure-properties relation. For modeling disorders in boron carbide, we implemented a first principles method based on supercell approach within our G(P,T) package. The supercell approach was applied to boron carbide to determine its carbon distribution. Our results reveal that carbon prefers to occupy the end sites of the 3-atom chain in boron carbide and further carbon atoms will distribute mainly on the equatorial sites with a small percentage on the 3-atom chains and the apex sites. Supercell approach was also applied to study mechanical properties of boron carbide under uniaxial load. We found that uniaxial load can lead to amorphization. Other physical properties of boron carbide were calculated using the G(P,T) package.

  10. Physical and mechanical properties of bituminous mixtures containing oil shales

    SciTech Connect (OSTI)

    Katamine, N.M.

    2000-04-01

    Rutting of bituminous surfaces on the Jordanian highways is a recurring problem. Highway authorities are exploring the use of extracted shale oil and oil shale fillers, which are abundant in Jordan. The main objectives of this research are to investigate the rheological properties of shale oil binders (conventional binder with various percentages of shale oil), in comparison with a conventional binder, and to investigate the ability of mixes to resist deformation. The latter is done by considering three wearing course mixes containing three different samples of oil shale fillers--which contained three different oil percentages--together with a standard mixture containing limestone filler. The Marshall design method and the immersion wheel tracking machine were adopted. It was concluded that the shale oil binders displayed inconsistent physical properties and therefore should be treated before being used. The oil shale fillers have provided mixes with higher ability to resist deformation than the standard mix, as measured by the Marshall quotients and the wheel tracking machine. The higher the percentages of oil in the oil shale fillers, the lower the ability of the mixes to resist deformation.

  11. GLYCOLIC ACID PHYSICAL PROPERTIES, IMPURITIES, AND RADIATION EFFECTS ASSESSMENT

    SciTech Connect (OSTI)

    Pickenheim, B.; Bibler, N.

    2010-06-08

    The DWPF is pursuing alternative reductants/flowsheets to increase attainment to meet closure commitment dates. In fiscal year 2009, SRNL evaluated several options and recommended the further assessment of the nitric/formic/glycolic acid flowsheet. SRNL is currently performing testing with this flowsheet to support the DWPF down-select of alternate reductants. As part of the evaluation, SRNL was requested to determine the physical properties of formic and glycolic acid blends. Blends of formic acid in glycolic acid were prepared and their physical properties tested. Increasing amounts of glycolic acid led to increases in blend density, viscosity and surface tension as compared to the 90 wt% formic acid that is currently used at DWPF. These increases are small, however, and are not expected to present any difficulties in terms of processing. The effect of sulfur impurities in technical grade glycolic acid was studied for its impact on DWPF glass quality. While the glycolic acid specification allows for more sulfate than the current formic acid specification, the ultimate impact is expected to be on the order of 0.03 wt% sulfur in glass. Note that lower sulfur content glycolic acid could likely be procured at some increased cost if deemed necessary. A paper study on the effects of radiation on glycolic acid was performed. The analysis indicates that substitution of glycolic acid for formic acid would not increase the radiolytic production rate of H{sub 2} and cause an adverse effect in the SRAT or SME process. It has been cited that glycolic acid solutions that are depleted of O{sub 2} when subjected to large radiation doses produced considerable quantities of a non-diffusive polymeric material. Considering a constant air purge is maintained in the SRAT and the solution is continuously mixed, oxygen depletion seems unlikely, however, if this polymer is formed in the SRAT solution, the rheology of the solution may be affected and pumping of the solution may be

  12. GLYCOLIC ACID PHYSICAL PROPERTIES, IMPURITIES, AND RADIATION EFFECTS ASSESSMENT

    SciTech Connect (OSTI)

    Lambert, D.; Pickenheim, B.; Hay, M.

    2011-06-20

    The Defense Waste Processing Facility (DWPF) is pursuing alternative reductants/flowsheets to increase attainment to meet closure commitment dates. In fiscal year 2009, SRNL evaluated several options and recommended the further assessment of the nitric/formic/glycolic acid flowsheet. SRNL is currently performing testing with this flowsheet to support the DWPF down-select of alternate reductants. As part of the evaluation, SRNL was requested to determine the physical properties of formic and glycolic acid blends. Blends of formic acid in glycolic acid were prepared and their physical properties tested. Increasing amounts of glycolic acid led to increases in blend density, viscosity and surface tension as compared to the 90 wt% formic acid that is currently used at DWPF. These increases are small, however, and are not expected to present any difficulties in terms of processing. The effect of sulfur impurities in technical grade glycolic acid was studied for its impact on DWPF glass quality. While the glycolic acid specification allows for more sulfate than the current formic acid specification, the ultimate impact is expected to be on the order of 0.03 wt% sulfur in glass. Note that lower sulfur content glycolic acid could likely be procured at some increased cost if deemed necessary. A paper study on the effects of radiation on glycolic acid was performed. The analysis indicates that substitution of glycolic acid for formic acid would not increase the radiolytic production rate of H{sub 2} and cause an adverse effect in the SRAT or SME process. It has been cited that glycolic acid solutions that are depleted of O{sub 2} when subjected to large radiation doses produced considerable quantities of a non-diffusive polymeric material. Considering a constant air purge is maintained in the SRAT and the solution is continuously mixed, oxygen depletion seems unlikely, however, if this polymer is formed in the SRAT solution, the rheology of the solution may be affected and

  13. Physical properties of zircon and scheelite lutetium orthovanadate...

    Office of Scientific and Technical Information (OSTI)

    ... DENSITY; DISPERSIONS; EFFECTIVE CHARGE; LUTETIUM; PHASE TRANSFORMATIONS; PHONONS; SOLIDS; THERMODYNAMIC PROPERTIES; THERMODYNAMICS; ZIRCON Word Cloud More Like This ...

  14. Instability and Anharmonicity in Plutonium Thermo-physical Properties...

    Office of Scientific and Technical Information (OSTI)

    Resource Relation: Conference: XII INTERNATIONAL WORKSHOP: FUNDAMENTAL PLUTONIUM PROPERTIES ; 2012-07-21 - 2012-07-22 ; Cambridge, United Kingdom Research Org: Los Alamos National ...

  15. Instability and Anharmonicity in Plutonium Thermo-physical Properties...

    Office of Scientific and Technical Information (OSTI)

    INTERNATIONAL WORKSHOP: FUNDAMENTAL PLUTONIUM PROPERTIES ; 2012-07-21 - 2012-07-22 ; Cambridge, United Kingdom Research Org: Los Alamos National Laboratory (LANL) Sponsoring Org:...

  16. Physical properties, crystal and magnetic structure of layered...

    Office of Scientific and Technical Information (OSTI)

    Fesubscript 1.11Tesubscript 1;8722;xSesubscript x superconductors Citation ... Fesubscript 1.11Tesubscript 1;8722;xSesubscript x superconductors The physical ...

  17. Morphology, electrical, and optical properties of heavily doped ZnTe:Cu thin films

    SciTech Connect (OSTI)

    El Akkad, Fikry; Abdulraheem, Yaser

    2013-11-14

    We report on a study of the physical properties of ZnTe:Cu films with Cu content up to ∼12 at. % prepared using rf magnetron sputtering. The composition and lateral homogeneities are studied using X-ray photoelectron spectroscopy (XPS). Atomic force microscopy measurements on films deposited at different substrate temperatures (up to 325 °C) yielded activation energy of 12 kJ/mole for the grains growth. The results of XPS and electrical and optical measurements provide evidence for the formation of the ternary zinc copper telluride alloy in films containing Cu concentration above ∼4 at. %. The XPS results suggest that copper is incorporated in the alloy with oxidation state Cu{sup 1+} so that the alloy formula can be written Zn{sub 1−y}Cu{sub y} Te with y = 2−x, where x is a parameter measuring the stoichiometry in the Cu site. The formation of this alloy causes appreciable shift in the binding energies of the XPS peaks besides an IR shift in the energy band gap. Detailed analysis of the optical absorption data revealed the presence of two additional transitions, besides the band gap one, originating from the Γ{sub 8} and Γ{sub 7} (spin-orbit) valence bands to a donor level at ∼0.34 eV below the Γ{sub 6} conduction band. This interpretation yields a value for the valence band splitting energy Δ≅ 0.87 eV independent of copper concentration. On the other hand, the mechanism of formation of the alloy is tentatively explained in terms of a point defect reaction in which substitutional Cu defect Cu{sub Zn} is also created. Assuming that substitutional Cu is the dominant acceptor in the Zn rich alloy as in ZnTe, its formation energy was determined to be 1.7 eV close to the theoretical value (1.41 eV) in ZnTe.

  18. CRC handbook of physical properties of rocks. Volume III

    SciTech Connect (OSTI)

    Carmichael, R.S.

    1984-01-01

    This book presents topics on: Density of rocks and minerals, includes histograms of density ranges; elastic constants of minerals, elastic moduli, thermal properties; inelastic properties, strength and rheology for rocks and minerals, rock mechanics and friction, and stress-strain relations; radioactivity, decay constants and heat production of isotope systems in geology; seismic attenuation, in rocks, minerals, and the earth, with application to oil exploration and terrestrial studies; and index.

  19. Effective Interaction Potentials and Physical Properties of Complex Plasmas

    SciTech Connect (OSTI)

    Ramazanov, T. S.; Dzhumagulova, K. N.; Gabdullin, M. T.; Omarbakiyeva, Y. A.

    2009-11-10

    Microscopic, thermodynamic and transport properties of complex plasmas are investigated on the basis of effective potentials of interparticle interaction. These potentials take into account correlation effects and quantum-mechanical diffraction. Plasma composition, thermodynamic functions of hydrogen and helium plasmas are obtained for a wide region of coupling parameter. Collision processes in partially ionized plasma are considered; some kinetic characteristics such as phase shift, scattering cross section, bremsstrahlung cross section and absorption coefficient are investigated. Dynamic and transport properties of dusty plasma are studied by computer simulation method of the Langevin dynamics.

  20. Morphology, microstructure, stress and damage properties of thin film coatings for the LCLS x-ray mirrors

    SciTech Connect (OSTI)

    Soufli, R; Baker, S L; Robinson, J C; Gullikson, E M; McCarville, T J; Pivovaroff, M J; Stefan, P; Hau-Riege, S P; Bionta, R

    2009-04-23

    The development and properties of reflective coatings for the x-ray offset mirror systems of the Linac Coherent Light Source (LCLS) free-electron laser (FEL) are discussed in this manuscript. The uniquely high instantaneous dose of the LCLS FEL beam translates to strict limits in terms of materials choice, thus leading to an x-ray mirror design consisting of a reflective coating deposited on a silicon substrate. Coherent wavefront preservation requirements for these mirrors result in stringent surface figure and finish specifications. DC-magnetron sputtered B{sub 4}C and SiC thin film coatings with optimized stress, roughness and figure properties for the LCLS x-ray mirrors are presented. The evolution of microstructure, morphology, and stress of these thin films versus deposition conditions is discussed. Experimental results on the performance of these coatings with respect to FEL damage are also presented.

  1. Physical-Property Measurements on Core Samples from Drill-Holes...

    Open Energy Info (EERE)

    Physical-Property Measurements on Core Samples from Drill-Holes DB-1 and DB-2, Blue Mountain Geothermal Prospect, North-Central Nevada Jump to: navigation, search OpenEI Reference...

  2. Investigation of the physical properties of the tetragonal CeMAl4Si2...

    Office of Scientific and Technical Information (OSTI)

    You are accessing a document from the Department of Energy's (DOE) SciTech Connect. This ... The synthesis, crystal structure and physical properties studied by means of x-ray ...

  3. Investigation of the physical properties of the tetragonal CeMAl4Si2...

    Office of Scientific and Technical Information (OSTI)

    the tetragonal CeMAl4Si2 (M Rh, Ir, Pt) compounds Prev Next Title: Investigation of the physical properties of the tetragonal CeMAl4Si2 (M Rh, Ir, Pt) compounds The ...

  4. Physical properties of kraft black liquor. Final report. Phase I

    SciTech Connect (OSTI)

    Fricke, A.L.

    1983-12-01

    Methods were selected, equipment installed, and procedures developed for determining rheological properties; for determining thermal properties (stability, density, thermal expansion, and heat capacity); for purification and characterization of lignin (glass transition, stability, weight average molecular weight, and number average molecular weight); and for performing chemical analyses (negative inorganic ions, positive inorganic ions, acid organic salts, lignin, and total solids). A strategy for pulping to supply test liquors was developed, and a statistically designed pulping experiment was specified for a Southern softwood species. Arrangements were made for performing initial pulping work in an industrial pilot plant, and a preliminary set of pulping experiments were conducted. Liquors from the preliminary pulping experiments were used to test procedures and to determine reproducibility of the experiment. Literature was also surveyed and preliminary selection of designs for a pilot digester, and for equipment to determine surface tension were made.

  5. Active doublet method for measuring small changes in physical properties

    DOE Patents [OSTI]

    Roberts, Peter M.; Fehler, Michael C.; Johnson, Paul A.; Phillips, W. Scott

    1994-01-01

    Small changes in material properties of a work piece are detected by measuring small changes in elastic wave velocity and attenuation within a work piece. Active, repeatable source generate coda wave responses from a work piece, where the coda wave responses are temporally displaced. By analyzing progressive relative phase and amplitude changes between the coda wave responses as a function of elapsed time, accurate determinations of velocity and attenuation changes are made. Thus, a small change in velocity occurring within a sample region during the time periods between excitation origin times (herein called "doublets") will produce a relative delay that changes with elapsed time over some portion of the scattered waves. This trend of changing delay is easier to detect than an isolated delay based on a single arrival and provides a direct measure of elastic wave velocity changes arising from changed material properties of the work piece.

  6. Iron hydroxyl phosphate microspheres: Microwave-solvothermal ionic liquid synthesis, morphology control, and photoluminescent properties

    SciTech Connect (OSTI)

    Cao Shaowen; Zhu Yingjie; Cui Jingbiao

    2010-07-15

    A variety of iron hydroxyl phosphate (NH{sub 4}Fe{sub 2}(PO{sub 4}){sub 2}OH.2H{sub 2}O) nanostructures such as solid microspheres, microspheres with the core in the hollow shell, and double-shelled hollow microspheres were synthesized by a simple one-step microwave-solvothermal ionic liquid method. The effects of the experimental parameters on the morphology and crystal phase of the resultant materials were investigated. Structural dependent photoluminescence was observed from the double-shelled hollow microspheres and the underlying mechanisms were discussed. - Graphical abstract: A variety of iron hydroxyl phosphate (NH{sub 4}Fe{sub 2}(PO{sub 4}){sub 2}OH.2H{sub 2}O) nanostructures were synthesized by a simple one-step microwave-solvothermal ionic liquid method. Structural dependent photoluminescence was observed from the double-shelled hollow microspheres.

  7. Synthesis, morphology and optical properties of GaN and AlGaN semiconductor nanostructures

    SciTech Connect (OSTI)

    Kuppulingam, B. Singh, Shubra Baskar, K.

    2014-04-24

    Hexagonal Gallium Nitride (GaN) and Aluminum Gallium Nitride (AlGaN) nanoparticles were synthesized by sol-gel method using Ethylene Diamine Tetra Acetic acid (EDTA) complex route. Powder X-ray diffraction (PXRD) analysis confirms the hexagonal wurtzite structure of GaN and Al{sub 0.25}Ga{sub 0.75}N nanoparticles. Surface morphology and elemental analysis were carried out by Scanning Electron Microscope (SEM) and Energy Dispersive X-ray spectroscopy (EDX). The room temperature Photoluminescence (PL) study shows the near band edge emission for GaN at 3.35 eV and at 3.59 eV for AlGaN nanoparticles. The Aluminum (Al) composition of 20% has been obtained from PL emission around 345 nm.

  8. Photovoltaic properties and morphology of organic solar cells based on liquid-crystal semiconducting polymer with additive

    SciTech Connect (OSTI)

    Suzuki, Atsushi; Zushi, Masahito; Suzuki, Hisato; Ogahara, Shinichi; Akiyama, Tsuyoshi; Oku, Takeo

    2014-02-20

    Bulk heterojunction organic solar cell based on liquid crystal semiconducting polymers of poly[9,9-dioctylfluorene-co-bithiophene] (F8T2) as p-type semiconductors and fullerenes (C{sub 60}) and [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) as electron donor and acceptor has been fabricated and characterized for improving photovoltaic and optical properties. The photovoltaic performance including current voltage curves in the dark and illumination of the F8T2/C{sub 60} conventional and inverted bulk heterojunction solar cells were investigated. Relationship between the photovoltaic properties and morphological behavior was focused on tuning for optimization of photo-voltaic performance under annealing condition near glass transition temperature. Additive-effect of diiodooctane (DIO) and poly(3-hexylthiophene-2,5-diyl) (P3HT) on the photovoltaic performance and optical properties was investigated. Mechanism of the photovoltaic properties of the conventional and inverted solar cells will be discussed by the experimental results.

  9. Development of an ASPEN PLUS physical property database for biofuels components

    SciTech Connect (OSTI)

    Wooley, R.J.; Putsche, V.

    1996-04-01

    Physical property data for many of the key components used in the simulation for the ethanol from lignocellulose process are not available in the standard ASPEN PLUS property databases. Indeed, many of the properties necessary to successfully simulate this process are not available anywhere. In addition, inputting the available properties into each simulation is awkward and tedious, and mistakes can be easily introduced when a long list of physical property equation parameters is entered. Therefore, one must evaluate the literature, estimate properties where necessary, and determine a set of consistent physical properties for all components of interest. The components must then be entered into an in-house NREL ASPEN PLUS database so they can be called on without being retyped into each specific simulation. The first phase of this work is complete. A complete set of properties for the currently identifiable important compounds in the ethanol process is attached. With this as the starting base the authors can continue to search for and evaluate new properties or have properties measured in the laboratory and update the central database.

  10. Thermo-physical Properties of DU-10 wt.% Mo Alloys

    SciTech Connect (OSTI)

    Douglas E. Burkes; Cynthia A. Papesch; Andrew P. Maddison; Thomas Hartmann; Francine J. Rice

    2010-08-01

    Low-enriched uranium alloyed with 10 wt% molybdenum is under consideration by the Global Threat Reduction Initiative reactor convert program as a very high density fuel to enable the conversion of high-performance research reactors away from highly-enriched uranium fuels. As with any fuel development program, the thermophysical properties of the fuel as a function of temperature are extremely important and must be well characterized in order to effectively model and predict fuel behavior under normal and off-normal irradiation conditions. For the alloy system under investigation, there is a lack of thermophysical property data, and in most cases, the data is relatively inconsistent and lacks sufficient explanation. Available literature on this alloy system comes mainly from studies done during the 1960s and 1970s, and often does not include sufficient information on fabrication history or conditions to draw conclusions for the current application. The current paper has investigated specific heat capacity, coefficient of linear thermal expansion, density, and thermal diffusivity that were then used to calculate alloy thermal conductivity as a function of temperature. The data obtained from this investigation was compared to available literature on similar U-Mo alloys, and in most cases are in good agreement.

  11. Physical properties of bifunctional BST/LSMO nanocomposites

    SciTech Connect (OSTI)

    Beltran-Huarac, Juan Morell, Gerardo; Martinez, Ricardo

    2014-02-28

    We report the fabrication of bifunctional nanocomposites consisting of ferroelectric Ba{sub 0.7}Sr{sub 0.3}TiO{sub 3} (BST) and ferromagnetic La{sub 0.67}Sr{sub 0.33}MnO{sub 3} (LSMO) at different concentrations via a high-temperature solid state route. The structural, dielectric, electrical, magnetodielectric (MD), magnetoelectric (ME) and magnetic properties of BST/LSMO nanocomposites were systematically investigated over a wide range of temperatures and frequencies. The X-Ray Diffraction analyses reveal the nanocrystalline nature of the heterostructures, wherein both perovskite phases co-exist. No parasitic phases were observed. The study of the dielectric properties shows that the nanocomposites exhibit relaxor ferroelectric character, with ferroelectric-paraelectric phase transition temperatures around 287–292 K that do not follow the Curie-Weiss law. The electrical measurements indicate that ac conductivities of the nanocomposites follow the Jonscher's universal power law, with activation energies of 0.42–0.63 eV based on Arrhenius-type behavior at high temperatures. The nanocomposites exhibit well-defined ferromagnetic hysteresis loops at room temperature (RT). The MD and ME measurements at RT indicate that BST/LSMO exhibits a nonlinear ME effect at low frequencies, with a threshold near 0.5 T. The magnetocapacitance (MC{sub p}) measurements evidence a quadratic dependence on magnetic field, further confirming the multiferroic nature of BST/LSMO. The order of MC{sub p} was found to be ∼7% per Tesla. The analysis of the MC{sub p} measurements indicates that one of the BST/LSMO compositions studied can be considered as a new multiferroic compound.

  12. Physical properties of bio-diesel & Implications for use of bio-diesel in diesel engines

    SciTech Connect (OSTI)

    Chakravarthy, Veerathu K; McFarlane, Joanna; Daw, C Stuart; Ra, Youngchul; Griffin, Jelani K

    2008-01-01

    In this study we identify components of a typical biodiesel fuel and estimate both their individual and mixed thermo-physical and transport properties. We then use the estimated mixture properties in computational simulations to gauge the extent to which combustion is modified when biodiesel is substituted for conventional diesel fuel. Our simulation studies included both regular diesel combustion (DI) and premixed charge compression ignition (PCCI). Preliminary results indicate that biodiesel ignition is significantly delayed due to slower liquid evaporation, with the effects being more pronounced for DI than PCCI. The lower vapor pressure and higher liquid heat capacity of biodiesel are two key contributors to this slower rate of evaporation. Other physical properties are more similar between the two fuels, and their impacts are not clearly evident in the present study. Future studies of diesel combustion sensitivity to both physical and chemical properties of biodiesel are suggested.

  13. Physics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Group (PDG) Organizations American Institute of Physics (AIP) American Physical Society (APS) Institute of Physics (IOP) SPIE - International society for optics and photonics Top...

  14. Effect of Pore Morphology on the Electrochemical Properties of Electric Double Layer Carbon Cryogel Supercapacitors

    SciTech Connect (OSTI)

    Garcia, B.B.; Feaver, A.M.; Zhang, Q.; Champion, R.D.; Cao, G.; Fister, T.T.; Nagle, K.P.; Seidler, G.T.

    2008-07-28

    In this study, a group of carbon cryogels have been synthesized using resorcinol formaldehyde as precursors, and altered via catalysis and activation, to obtain varied nanostructures and pore size distributions. To understand the relation between structure and electrochemical properties, an alternate approach to de Levi's cylindrical pore, transmission line method was utilized. Using electrochemical impedance spectroscopy, the capacitor can be studied as a dielectric system composed of a porous electrode and the electrolyte (tetraethylammonium tetrafluoroborate in propylene carbonate). The complex capacitance and power are used to study the behavior of the system below the relaxation frequency f{sub 0} ({var_phi} = -45{sup o}). Therefore, the relaxation of the capacitor system at the low frequency range, f

  15. A comprehensive program to develop correlations for physical properties of kraft black liquor. Final report

    SciTech Connect (OSTI)

    Fricke, A.L.; Zaman, A.A.

    1998-05-01

    The overall objective of the program was to develop correlations to predict physical properties within requirements of engineering precision from a knowledge of pulping conditions and of kraft black liquor composition, if possible. These correlations were to include those relating thermodynamic properties to pulping conditions and liquor composition. The basic premise upon which the research was based is the premise that black liquor behaves as a polymer solution. This premise has proven to be true, and has been used successfully in developing data reduction methods and in interpreting results. A three phase effort involving pulping, analysis of liquor composition, and measurement of liquor properties was conducted.

  16. Capabilities for measuring physical and chemical properties of rocks at high pressure

    SciTech Connect (OSTI)

    Durham, W.B.

    1990-01-01

    The Experimental Geophysics Group of the Earth Sciences Department at Lawrence Livermore National Laboratory (LLNL) has experimental equipment that measures a variety of physical properties and phase equilibria and kinetics on rocks and minerals at extreme pressures (to 500 GPa) and temperatures (from 10 to 2800 K). These experimental capabilities are described in this report in terms of published results, photographs, and schematic diagrams.

  17. Physical property changes in hydrate-bearingsediment due to depressurization and subsequent repressurization

    SciTech Connect (OSTI)

    Kneafsey, Timothy; Waite, W.F.; Kneafsey, T.J.; Winters, W.J.; Mason, D.H.

    2008-06-01

    Physical property measurements of sediment cores containing natural gas hydrate are typically performed on material exposed at least briefly to non-in situ conditions during recovery. To examine effects of a brief excursion from the gas-hydrate stability field, as can occur when pressure cores are transferred to pressurized storage vessels, we measured physical properties on laboratory-formed sand packs containing methane hydrate and methane pore gas. After depressurizing samples to atmospheric pressure, we repressurized them into the methane-hydrate stability field and remeasured their physical properties. Thermal conductivity, shear strength, acoustic compressional and shear wave amplitudes and speeds are compared between the original and depressurized/repressurized samples. X-ray computed tomography (CT) images track how the gas-hydrate distribution changes in the hydrate-cemented sands due to the depressurization/repressurization process. Because depressurization-induced property changes can be substantial and are not easily predicted, particularly in water-saturated, hydrate-bearing sediment, maintaining pressure and temperature conditions throughout the core recovery and measurement process is critical for using laboratory measurements to estimate in situ properties.

  18. Physics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Physics Physics Print Because a large proportion of ALS experiments are "physics" experiments, it's useful to separate them into two categories - one focused on Materials/Condensed Matter, and this one, with a dual focus on AMO (atomic, molecular, and optical) physics and accelerator physics. Light sources such as the ALS have opened up research frontiers that may hold the answers to fundamental questions about structure and dynamics in AMO physics. The advanced spectroscopies that

  19. Morphology-dependent optical absorption and conduction properties of photoelectrochemical photocatalysts for H{sub 2} production: A case study

    SciTech Connect (OSTI)

    Huda, Muhammad N.; Turner, John A.

    2010-06-15

    Efficient photoelectrochemical H{sub 2} production by solar irradiation depends not only on the photocatalyst's band gap and its band-edge positions but also on the detailed electronic nature of the bands, such as the localization or delocalization of the band edges and their orbital characteristics. These determine the carrier transport properties, reactivity, light absorption strength, etc. and significantly impact the material's efficiency as a photoconverter. The localization or delocalization of the band edges may arise either due to the orbital nature of the bands or the structural morphology of the material. A recent experimental report on a photocatalyst based on s/p orbitals showed very poor performance for H{sub 2} production despite the delocalized nature of the s/p bands as compared to the d-bands of transition metal oxides. It is then important to examine whether this poor performance is inherent to these materials or rather arises from some experimental limitations. A theoretical analysis by first-principle methods is well suited to shed light on this question.

  20. Glancing angle deposition of SiO{sub 2} thin film microstructures: Investigations of optical and morphological properties

    SciTech Connect (OSTI)

    Tokas, R. B. E-mail: tokasstar@gmail.com; Jena, S. E-mail: tokasstar@gmail.com; Sarkar, P. E-mail: tokasstar@gmail.com; Thakur, S. E-mail: tokasstar@gmail.com; Sahoo, N. K. E-mail: tokasstar@gmail.com

    2014-04-24

    In present work, the optical and the morphological properties of micro-structured SiO{sub 2} thin films fabricated by using glancing angle deposition (GLAD) technique has been carried out. The results are compared with the normally deposited SiO{sub 2} films for the gained advantages. The influence of the glancing angle on the refractive index of porous SiO{sub 2} film was investigated by the spectral transmission measurement in 400–950 nm wavelength regimes. The refractive index has been found to be 1.14@532 nm for the porous SiO{sub 2} film deposited at a glancing angle of 85°. The density and surface qualities of these samples were primarily investigated by using grazing angle X-ray reflectivity (GIXR) and atomic force microscope (AFM) measurements. Results indicate a substantial decrease in film density and refractive index and increase in surface roughness and grain size for GLAD SiO{sub 2} compared to normally deposited SiO{sub 2} films.

  1. Prototype Data Models and Data Dictionaries for Hanford Sediment Physical and Hydraulic Properties

    SciTech Connect (OSTI)

    Rockhold, Mark L.; Last, George V.; Middleton, Lisa A.

    2010-09-30

    The Remediation Decision Support (RDS) project, managed by the Pacific Northwest National Laboratory (PNNL) for the U.S. Department of Energy (DOE) and the CH2M HILL Plateau Remediation Company (CHPRC), has been compiling physical and hydraulic property data and parameters to support risk analyses and waste management decisions at Hanford. In FY09 the RDS project developed a strategic plan for a physical and hydraulic property database. This report documents prototype data models and dictionaries for these properties and associated parameters. Physical properties and hydraulic parameters and their distributions are required for any type of quantitative assessment of risk and uncertainty associated with predictions of contaminant transport and fate in the subsurface. The central plateau of the Hanford Site in southeastern Washington State contains most of the contamination at the Site and has up to {approx}100 m of unsaturated and unconsolidated or semi-consolidated sediments overlying the unconfined aquifer. These sediments contain a wide variety of contaminants ranging from organic compounds, such as carbon tetrachloride, to numerous radionuclides including technetium, plutonium, and uranium. Knowledge of the physical and hydraulic properties of the sediments and their distributions is critical for quantitative assessment of the transport of these contaminants in the subsurface, for evaluation of long-term risks and uncertainty associated with model predictions of contaminant transport and fate, and for evaluating, designing, and operating remediation alternatives. One of the goals of PNNL's RDS project is to work with the Hanford Environmental Data Manager (currently with CHPRC) to develop a protocol and schedule for incorporation of physical property and hydraulic parameter datasets currently maintained by PNNL into HEIS. This requires that the data first be reviewed to ensure quality and consistency. New data models must then be developed for HEIS that are

  2. Physics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Physics Print Because a large proportion of ALS experiments are "physics" experiments, it's useful to separate them into two categories - one focused on Materials/Condensed Matter, and this one, with a dual focus on AMO (atomic, molecular, and optical) physics and accelerator physics. Light sources such as the ALS have opened up research frontiers that may hold the answers to fundamental questions about structure and dynamics in AMO physics. The advanced spectroscopies that have been

  3. Physics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Physics Physics Our science answers questions about the nature of the universe and delivers solutions for national security concerns. Contact Us Division Leader David Meyerhofer Deputy Division Leader Scott Wilburn Division Office (505) 667-4117 For more than 70 years-from the Manhattan Project to today-Physics Division researchers have been performing groundbreaking fundamental and applied research. For more than 70 years-from the Manhattan Project to today-Physics Division researchers have

  4. Thermal and Physical Properties of Plutonium Dioxide Produced from the Oxidation of Metal: a Data Summary

    SciTech Connect (OSTI)

    Wayne, David M.

    2014-01-13

    The ARIES Program at the Los Alamos National Laboratory removes plutonium metal from decommissioned nuclear weapons, and converts it to plutonium dioxide in a specially-designed Direct Metal Oxidation furnace. The plutonium dioxide is analyzed for specific surface area, particle size distribution, and moisture content. The purpose of these analyses is to certify that the plutonium dioxide powder meets or exceeds the specifications of the end-user, and the specifications for the packaging and transport of nuclear materials. Analytical results from plutonium dioxide from ARIES development activities, from ARIES production activities, from muffle furnace oxidation of metal, and from metal that was oxidized over a lengthy time interval in air at room temperature, are presented. The processes studied produce plutonium dioxide powder with distinct differences in measured properties, indicating the significant influence of oxidation conditions on physical properties.

  5. Status of Initial Assessment of Physical and Mechanical Properties of Graphite Grades for NGNP Appkications

    SciTech Connect (OSTI)

    Strizak, Joe P; Burchell, Timothy D; Windes, Will

    2011-12-01

    Current candidate graphite grades for the core structures of NGNP include grades NBG-17, NBG-18, PCEA and IG-430. Both NBG-17 and NBG-18 are manufactured using pitch coke, and are vibrationally molded. These medium grain products are produced by SGL Carbon SAS (France). Tayo Tanso (Japan) produces IG-430 which is a petroleum coke, isostatically molded, nuclear grade graphite. And PCEA is a medium grain, extruded graphite produced by UCAR Carbon Co. (USA) from petroleum coke. An experimental program has been initiated to develop physical and mechanical properties data for these current candidate graphites. The results will be judged against the requirements for nuclear grade graphites set forth in ASTM standard D 7219-05 "Standard Specification for Isotropic and Near-isotropic Nuclear Graphites". Physical properties data including thermal conductivity and coefficient of thermal expansion, and mechanical properties data including tensile, compressive and flexural strengths will be obtained using the established test methods covered in D-7219 and ASTM C 781-02 "Standard Practice for Testing Graphite and Boronated Graphite Components for High-Temperature Gas-Cooled Nuclear Reactors". Various factors known to effect the properties of graphites will be investigated. These include specimen size, spatial location within a graphite billet, specimen orientation (ag and wg) within a billet, and billet-to-billet variations. The current status of the materials characterization program is reported herein. To date billets of the four graphite grades have been procured, and detailed cut up plans for obtaining the various specimens have been prepared. Particular attention has been given to the traceability of each specimen to its spatial location and orientation within a billet.

  6. Effects of biogenic silica on acoustic and physical properties of clay-rich marine sediments

    SciTech Connect (OSTI)

    Tribble, J.S.; Mackenzie, F.T.; Urmos, J.; O'Brien, D.K.; Manghnani, M.H. )

    1992-06-01

    The physical properties of marine sediments are influenced by compaction and diagenesis during burial. Changes in mineralogy, chemistry, density, porosity, and microfabric all affect a sediment's acoustic and electrical properties. Sediments from the Japan Trench illustrate the dependence of physical properties on biogenic silica content. Increased opal-A content is correlated with increased porosity and decreased grain density and compressional velocity. Variations with depth in opal-A concentration are therefore reflected in highly variable and, at times, inverse velocity-depth gradients. The diagenetic conversion of opal-A to opal-CT and finally to quartz was investigated at a site in the San Miguel Gap, California. Distinct changes in microfabric, particularly in the porosity distribution, accompany the diagenetic reactions and contribute to a sharp velocity discontinuity at the depth of the opal-A to opal-CT conversion. Evaluation of this reaction at several sites indicates a systematic dependence on temperature and age in clay-rich and moderately siliceous sediments. In ocean margin regions, sediments are buried rapidly, and opal-A may be converted to opal-CT in less than 10 m.y. Temperatures of conversion range from 30{degree} to 50{degree}C. Much longer times (>40 m.y.) are required to complete the conversion in open ocean deposits which are exposed to temperatures less than 15{degree}C. In the absence of silica diagenesis, velocity-depth gradients of most clay-rich and moderately siliceous sediments fall in the narrow range of 0.15 to 0.25 km/s/km which brackets the gradient (0.18 km/s/km) determined for a type pelagic clay section. Relationships such as these can be useful in unraveling the history of a sediment sequence, including the evolution with time of reservoir properties and seismic signatures.

  7. PHYSICAL PROPERTIES OF THE CIRCUMNUCLEAR STARBURST RING IN THE BARRED GALAXY NGC 1097

    SciTech Connect (OSTI)

    Hsieh, Pei-Ying; Matsushita, Satoki; Ho, Paul T. P.; Wu, Ya-Lin; Liu, Guilin; Oi, Nagisa

    2011-08-01

    We report high-resolution {sup 12}CO(J = 2-1), {sup 13}CO(J = 2-1), and {sup 12}CO(J = 3-2) imaging of the Seyfert 1/starburst ring galaxy NGC 1097 with the Submillimeter Array for the purpose of studying the physical and kinematic properties of the 1 kpc circumnuclear starburst ring. Individual star clusters as detected in the Hubble Space Telescope map of Pa{alpha} line emission have been used to determine the star formation rate (SFR), and are compared with the properties of the molecular gas. The molecular ring has been resolved into individual clumps at the giant molecular cloud association (GMA) scale of 200-300 pc in all three CO lines. The intersection between the dust lanes and the starburst ring, which is associated with the orbit-crowding region, is resolved into two physically/kinematically distinct features in the 1.''5 x 1.''0 (105 x 70 pc) {sup 12}CO(J = 2-1) map. The clumps associated with the dust lanes have broader line widths, higher surface gas densities, and lower SFRs, while the narrow line clumps associated with the starburst ring have opposite characteristics. A Toomre-Q value lower than unity at the radius of the ring suggests that the molecular ring is gravitationally unstable to fragmentation at GMA scale. The line widths and surface density of the gas mass of the clumps show an azimuthal variation related to the large-scale dynamics. The SFR, on the other hand, is not significantly affected by the dynamics, but has a correlation with the intensity ratio of {sup 12}CO (J = 3-2) and {sup 12}CO(J = 2-1), which traces the denser gas associated with star formation. Our resolved CO map, especially in the orbit-crowding region, observationally demonstrates for the first time that the physical/kinematic properties of GMAs are affected by the large-scale bar-potential dynamics in NGC 1097.

  8. A comparison of the morphological properties between local and z ∼ 1 infrared luminous galaxies: Are local and high-z (U)LIRGs different?

    SciTech Connect (OSTI)

    Hung, Chao-Ling; Sanders, D. B.; Larson, Kirsten L.; Lee, Nicholas; Li, Yanxia; Lockhart, Kelly; Shih, Hsin-Yi; Barnes, Joshua E.; Casey, Caitlin M.; Koss, Michael; Kartaltepe, Jeyhan S.; Smith, Howard A.

    2014-08-10

    Ultraluminous and luminous infrared galaxies (ULIRGs and LIRGs) are the most extreme star-forming galaxies in the universe and dominate the total star formation rate density at z > 1. In the local universe (z < 0.3), the majority of ULIRGs and a significant portion of LIRGs are triggered by interactions between gas-rich spiral galaxies, yet it is unclear if this is still the case at high z. To investigate the relative importance of galaxy interactions in infrared luminous galaxies, we carry out a comparison of optical morphological properties between local (U)LIRGs and (U)LIRGs at z = 0.5-1.5 based on the same sample selection, morphology classification scheme, and optical morphology at similar rest-frame wavelengths. In addition, we quantify the systematics in comparing local and high-z data sets by constructing a redshifted data set from local (U)LIRGs, in which its data quality mimics the high-z data set. Based on the Gini-M{sub 20} classification scheme, we find that the fraction of interacting systems decreases by ∼8% from local to z ≲ 1, and it is consistent with the reduction between local and redshifted data sets (6{sub −6}{sup +14}%). Based on visual classifications, the merger fraction of local ULIRGs is found to be ∼20% lower compared to published results, and the reduction due to redshifting is 15{sub −8}{sup +10}%. Consequently, the differences of merger fractions between local and z ≲ 1 (U)LIRGs is only ∼17%. These results demonstrate that there is no strong evolution in the fraction of (U)LIRGs classified as mergers at least out to z ∼ 1. At z > 1, the morphology types of ∼30% of (U)LIRGs cannot be determined due to their faintness in the F814W band; thus, the merger fraction measured at z > 1 suffers from large uncertainties.

  9. On-Line Physical Property Process Measurements for Nuclear Fuel Recycling

    SciTech Connect (OSTI)

    Pappas, Richard A.; Bond, Leonard J.; Greenwood, Margaret S.; Hostick, Cody J.

    2007-07-01

    The Global Nuclear Energy Partnership (GNEP) is looking to close the nuclear fuel cycle and demonstrate key fuel recycling technologies, while at the same time reducing proliferation risks. A key element of GNEP is the demonstration of the uranium extraction (UREX) +1a process, and potentially other fuel reprocessing schemes. Advanced recycling of nuclear fuel will require improved on-line monitoring and process control. Advanced ultrasonic sensor technology can be a critical component of a process quality control strategy that is designed to determine the sources of variability and minimize their impact on the quality of the end product. PNNL ultrasonic devices and methodologies, many of which were initially developed and deployed to address the needs of the DOE Hanford site, provide on-line physical property measurement useful in optimizing plant capacity, assuring cost-effective analyses, and satisfying direct sampling requirements.. A select collection of PNNL ultrasonic technology is discussed in this context. (authors)

  10. Geochemical and physical properties of wetland soils at the Savannah River site

    SciTech Connect (OSTI)

    Dixon, K.L; Rogers, V.A.; Conner, S.P.; Cummings, C.L.; Gladden, J.B.; Weber, J.M.

    1996-05-01

    The Savannah River Site (SRS), located in Aiken, Allendale, and Barnwell Counties, South Carolina, is a nuclear production facility operated for the U.S. Department of Energy (DOE) by Westinghouse Savannah River Company (WSRC). To facilitate future human health and ecological risk assessments, treatability studies, remedial investigations, and feasibility studies for its wetland areas, SRS needs a database of background geochemical and physical properties of wetland soils. These data are needed for comparison to data collected from wetland soils that may have been affected by SRS operations. SRS contains 36,000 acres of wetlands and an additional 5,000 acres of bottom land soils subject to flooding. Recent studies of wetland soils near various waste units at SRS show that some wetlands have been impacted by releases of contaminants resulting from SRS operations (WSRC, 1992). Waste waters originating from the operations facilities typically have been discharged into seepage basins located in upland soils, direct discharge of waste water to wetland areas has been minimal. This suggests that impacted wetland areas have been affected indirectly as a result of transport mechanisms such as surface runoff, groundwater seeps, fluvial or sediment transport, and leaching. Looney et al. (1990) conducted a study to characterize the geochemical and physical properties of upland soils and shallow sediments on the SRS. A primary objective of the upland study was to collect the data needed to assess the qualitative and quantitative impacts of SRS operations on the environment. By comparing the upland soils data to data collected from waste units located in similar soils, SRS impacts could be assessed. The data were also intended to aid in selection of remediation alternatives. Because waste units at SRS have historically been located in upland areas, wetland soils were not sampled. (Abstract Truncated)

  11. Methods and apparatus for moving and separating materials exhibiting different physical properties

    DOE Patents [OSTI]

    Peterson, Stephen C.; Brimhall, Owen D.; McLaughlin, Thomas J.; Baker, Charles D.; Sparks, Sam L.

    1988-01-01

    Methods and apparatus for controlling the movement of materials having different physical properties when one of the materials is a fluid. The invention does not rely on flocculation, sedimentation, centrifugation, the buoyancy of the materials, or any other gravity dependent characteristic, in order to achieve its desired results. The methods of the present invention provide that a first acoustic wave is progpagated through a vessel containing the materials. A second acoustic wave, at a frequency different than the first acoustic wave, is also propagated through the vessel so that the two acoustic waves are superimposed upon each other. The superimposition of the two waves creates a beat frequency wave. The beat frequency wave comprises pressure gradients dividing regions of maximum and minimum pressure. The pressure gradients and the regions of maximum and minimum pressure move through space and time at a group velocity. The moving pressure gradients and regions of maximum and minimum pressure act upon the marterials so as to move one of the materials towards a predetermined location in the vessel. The present invention provides that the materials may be controllably moved toward a location, aggreated at a particular location, or physically separated from each other.

  12. Methods and apparatus for moving and separating materials exhibiting different physical properties

    DOE Patents [OSTI]

    Peterson, Stephen C.; Brimhall, Owen D.; McLaughlin, Thomas J.; Baker, Charles D.; Sparks, Sam L.

    1991-01-01

    Methods and apparatus for controlling the movement of materials having different physical properties when one of the materials is a fluid. The invention does not rely on flocculation, sedimentation, centrifugation, the buoyancy of the materials, or any other gravity dependent characteristic, in order to achieve its desired results. The methods of the present invention provide that a first acoustic wave is propagated through a vessel containing the materials. A second acoustic wave, at a frequency different than the first acoustic wave, is also propagated through the vessel so that the two acoustic waves are superimposed upon each other. The superimposition of the two waves creates a beat frequency wave. The beat frequency wave comprises pressure gradients dividing regions of maximum and minimum pressure. The pressure gradients and the regions of maximum and minimum pressure move through space and time at a group velocity. The moving pressure gradients and regions of maximum and minimum pressure act upon the materials so as to move one of the materials towards a predetermined location in the vessel. The present invention provides that the materials may be controllably moved toward a location, aggregated at a particular location, or physically separated from each other.

  13. PHYSICAL PROPERTIES OF LARGE AND SMALL GRANULES IN SOLAR QUIET REGIONS

    SciTech Connect (OSTI)

    Yu Daren; Xie Zongxia; Hu Qinghua; Yang Shuhong; Zhang Jun; Wang Jingxiu E-mail: zjun@ourstar.bao.ac.cn

    2011-12-10

    The normal mode observations of seven quiet regions obtained by the Hinode spacecraft are analyzed to study the physical properties of granules. An artificial intelligence technique is introduced to automatically find the spatial distribution of granules in feature spaces. In this work, we investigate the dependence of granular continuum intensity, mean Doppler velocity, and magnetic fields on granular diameter. We recognized 71,538 granules by an automatic segmentation technique and then extracted five properties: diameter, continuum intensity, Doppler velocity, and longitudinal and transverse magnetic flux density to describe the granules. To automatically explore the intrinsic structures of the granules in the five-dimensional parameter space, the X-means clustering algorithm and one-rule classifier are introduced to define the rules for classifying the granules. It is found that diameter is a dominating parameter in classifying the granules and two families of granules are derived: small granules with diameters smaller than 1.''44, and large granules with diameters larger than 1.''44. Based on statistical analysis of the detected granules, the following results are derived: (1) the averages of diameter, continuum intensity, and Doppler velocity in the upward direction of large granules are larger than those of small granules; (2) the averages of absolute longitudinal, transverse, and unsigned flux density of large granules are smaller than those of small granules; (3) for small granules, the average of continuum intensity increases with their diameters, while the averages of Doppler velocity, transverse, absolute longitudinal, and unsigned magnetic flux density decrease with their diameters. However, the mean properties of large granules are stable; (4) the intensity distributions of all granules and small granules do not satisfy Gaussian distribution, while that of large granules almost agrees with normal distribution with a peak at 1.04 I{sub 0}.

  14. Influence of solvent on the morphology and photocatalytic properties of ZnS decorated CeO{sub 2} nanoparticles

    SciTech Connect (OSTI)

    Raubach, Cristiane W. Polastro, Lisnias; Ferrer, Mateus M.; Perrin, Andre; Perrin, Christiane; Albuquerque, Anderson R.; Buzolin, Prescila G. C.; Sambrano, Julio R.; Santana, Yuri B. V. de; Varela, Jos A.; Longo, Elson

    2014-06-07

    Herein, we report a theoretical and experimental study on the photocatalytic activity of CeO{sub 2} ZnS, and ZnS decorated CeO{sub 2} nanoparticles prepared by a microwave-assisted solvothermal method. Theoretical models were established to analyze electron transitions primarily at the interface between CeO{sub 2} and ZnS. As observed, the particle morphology strongly influenced the photocatalytic degradation of organic dye Rhodamine B. A model was proposed to rationalize the photocatalytic behavior of the prepared decorated systems taking into account different extrinsic and intrinsic defect distributions, including order-disorder effects at interfacial and intra-facial regions, and vacancy concentration.

  15. A Long-Term Strategic Plan for Hanford Sediment Physical Property and Vadose Zone Hydraulic Parameter Databases

    SciTech Connect (OSTI)

    Rockhold, Mark L.; Last, George V.; Middleton, Lisa A.

    2009-09-30

    Physical property data and unsaturated hydraulic parameters are critical input for analytic and numerical models used to predict transport and fate of contaminants in variably saturated porous media and to assess and execute remediation alternatives. The Remediation Decision Support (RDS) project, managed by the Pacific Northwest National Laboratory (PNNL) for the U.S. Department of Energy (DOE) and the CH2M Hill Plateau Remediation Company (CHPRC), has been compiling physical and hydraulic property data and parameters to support risk analyses and waste management decisions at Hanford. Efforts have been initiated to transfer sediment physical property data and vadose zone hydraulic parameters to CHPRC for inclusion in HEIS-Geo, a new instance of the Hanford Environmental Information System database that is being developed for borehole geologic data. This report describes these efforts and a strategic plan for continued updating and improvement of these datasets.

  16. Effects of the solvent on the structure, morphology and photocatalytic properties of Bi{sub 2}MoO{sub 6} in the solvothermal process

    SciTech Connect (OSTI)

    Bi, Jinhong; Che, Jiangang; Wu, Ling; Liu, Minghua

    2013-06-01

    Graphical abstract: Various nanostructure Bi{sub 2}MoO{sub 6} photocatalysts have been prepared by a solvothermal process via simply altering the used solvent. It is revealed that the type of solvents has a strong influence on the morphology of Bi{sub 2}MoO{sub 6}. This could be understood in terms of the reaction media effect on the crystal growth. The photocatalytic experiments for the decomposition of RhB demonstrate that the samples prepared by different solvents show different photocatalytic activity. The highest photocatalytic activity is obtained by the sample with glycol as solvent. Highlights: ? The used solvent in the synthesis can affect the morphology and size of Bi{sub 2}MoO{sub 6}. ? Different solvent in the reaction leads to different surface area and pore size. ? The highest photocatalytic activity is obtained by the sample prepared in glycol. ? The high activity is mainly due to the large surface area and small particle size. - Abstract: Visible-light-driven photocatalyst Bi{sub 2}MoO{sub 6} was prepared by a solvothermal process with different kinds of solvent including water, isopropanol and ethylene glycol. The obtained samples were characterized by X-ray diffraction technique, N{sub 2}-sorption, UVvis diffuse reflectance spectra, transmission electron microscopy and Fourier transform infrared spectroscopy. The results revealed that the type of solvent has a strong influence on the morphologies and physico-chemical properties of Bi{sub 2}MoO{sub 6}. Meanwhile, the formation mechanism of Bi{sub 2}MoO{sub 6} with various morphologies was discussed. The photocatalytic activities of Bi{sub 2}MoO{sub 6} photocatalysts were evaluated by the decomposition of rhodamine B (RhB) under visible light irradiation (? > 420 nm). It was found that the sample prepared with glycol as solvent showed the best performance in the photodegradation of RhB under visible light irradiation. This could be ascribed to the large surface area, unique morphology and small

  17. INITIAL COMPARISON OF BASELINE PHYSICAL AND MECHANICAL PROPERTIES FOR THE VHTR CANDIDATE GRAPHITE GRADES

    SciTech Connect (OSTI)

    Carroll, Mark C

    2014-09-01

    High-purity graphite is the core structural material of choice in the Very High Temperature Reactor (VHTR) design, a graphite-moderated, helium-cooled configuration that is capable of producing thermal energy for power generation as well as process heat for industrial applications that require temperatures higher than the outlet temperatures of present nuclear reactors. The Baseline Graphite Characterization Program is endeavoring to minimize the conservative estimates of as-manufactured mechanical and physical properties in nuclear-grade graphites by providing comprehensive data that captures the level of variation in measured values. In addition to providing a thorough comparison between these values in different graphite grades, the program is also carefully tracking individual specimen source, position, and orientation information in order to provide comparisons both in specific properties and in the associated variability between different lots, different billets, and different positions from within a single billet. This report is a preliminary comparison between each of the grades of graphite that are considered candidate grades from four major international graphite producers. These particular grades (NBG-18, NBG-17, PCEA, IG-110, and 2114) are the major focus of the evaluations presently underway on irradiated graphite properties through the series of Advanced Graphite Creep (AGC) experiments. NBG-18, a medium-grain pitch coke graphite from SGL from which billets are formed via vibration molding, was the favored structural material in the pebble-bed configuration. NBG-17 graphite from SGL is essentially NBG-18 with the grain size reduced by a factor of two. PCEA, petroleum coke graphite from GrafTech with a similar grain size to NBG-17, is formed via an extrusion process and was initially considered the favored grade for the prismatic layout. IG-110 and 2114, from Toyo Tanso and Mersen (formerly Carbone Lorraine), respectively, are fine-grain grades

  18. Variation of the shape and morphological properties of silica and metal oxide powders by electro homogeneous precipitation

    DOE Patents [OSTI]

    Harris, Michael T.; Basaran, Osman A.; Sisson, Warren G.; Brunson, Ronald R.

    1997-01-01

    The present invention provides a method for preparing irreversible linear aggregates (fibrils) of metal oxide powders by utilizing static or pulsed DC electrical fields across a relatively non-conducting liquid solvent in which organometal compounds or silicon alkoxides have been dissolved. The electric field is applied to the relatively non-conducting solution throughout the particle formation and growth process promoting the formation of either linear aggregates (fibrils) or spherical shaped particles as desired. Thus the present invention provides a physical method for altering the size, shape and porosity of precursor hydrous metal oxide or hydrous silicon oxide powders for the development of advanced ceramics with improved strength and insulating capacity.

  19. Effect of ZnO seed layer on the morphology and optical properties of ZnO nanorods grown on GaN buffer layers

    SciTech Connect (OSTI)

    Nandi, R. Mohan, S. Major, S. S.; Srinivasa, R. S.

    2014-04-24

    ZnO nanorods were grown by chemical bath deposition on sputtered, polycrystalline GaN buffer layers with and without ZnO seed layer. Scanning electron microscopy and X-ray diffraction show that the ZnO nanorods on GaN buffer layers are not vertically well aligned. Photoluminescence spectrum of ZnO nanorods grown on GaN buffer layer, however exhibits a much stronger near-band-edge emission and negligible defect emission, compared to the nanorods grown on ZnO buffer layer. These features are attributed to gallium incorporation at the ZnO-GaN interface. The introduction of a thin (25 nm) ZnO seed layer on GaN buffer layer significantly improves the morphology and vertical alignment of ZnO-NRs without sacrificing the high optical quality of ZnO nanorods on GaN buffer layer. The presence of a thick (200 nm) ZnO seed layer completely masks the effect of the underlying GaN buffer layer on the morphology and optical properties of nanorods.

  20. Geochemical and physical properties of soils and shallow sediments at the Savannah River Site

    SciTech Connect (OSTI)

    Looney, B.B.; Eddy, C.A.; Ramdeen, M.; Pickett, J. ); Rogers, V. . Savannah River Site Savannah River Lab., Aiken, SC ); Scott, M.T.; Shirley, P.A. )

    1990-08-31

    A program to characterize the geochemical and physical properties of the unimpacted soils and shallow sediments at the Savannah River Site (SRS) has been completed. The maximum, minimum, median, standard deviation, and mean values for metals, radionuclides, inorganic anions, organic compounds, and agricultural indicator parameters are summarized for six soil series that were identified as representative of the 29 soil series at SRS. The soils from unimpacted areas of SRS are typical of soils found in moderately aggressive weathering environments, including the southeastern United States. Appendix 8 organic compounds were detected in all samples. Since these constituents are not generally present in soil, this portion of the investigation was intended to assess possible laboratory artifacts. An additional objective of the SRS Soil Study was to determine if the composition of the split spoon sampler biased chemical analysis of the soils. Twenty-five duplicate samples were analyzed for a number of metals, radiological and agricultural parameters, and organics by two laboratories currently contracted with to analyze samples during waste site characterization. In all cases, the absolute values of the average differences are relatively small compared to the overall variability in the population. 31 refs., 14 figs., 48 tabs.

  1. Lidar Measurements of the Vertical Distribution of Aerosol Optical and Physical Properties over Central Asia

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chen, Boris B.; Sverdlik, Leonid G.; Imashev, Sanjar A.; Solomon, Paul A.; Lantz, Jeffrey; Schauer, James J.; Shafer, Martin M.; Artamonova, Maria S.; Carmichael, Gregory R.

    2013-01-01

    The vertical structure of aerosol optical and physical properties was measured by Lidar in Eastern Kyrgyzstan, Central Asia, from June 2008 to May 2009. Lidar measurements were supplemented with surface-based measurements of PM 2.5 and PM 10 mass and chemical composition in both size fractions. Dust transported into the region is common, being detected 33% of the time. The maximum frequency occurred in the spring of 2009. Dust transported to Central Asia comes from regional sources, for example, Taklimakan desert and Aral Sea basin, and from long-range transport, for example, deserts of Arabia, Northeast Africa, Iran, and Pakistan. Regionalmore » sources are characterized by pollution transport with maximum values of coarse particles within the planetary boundary layer, aerosol optical thickness, extinction coefficient, integral coefficient of aerosol backscatter, and minimum values of the Ångström exponent. Pollution associated with air masses transported over long distances has different characteristics during autumn, winter, and spring. During winter, dust emissions were low resulting in high values of the Ångström exponent (about 0.51) and the fine particle mass fraction (64%). Dust storms were more frequent during spring with an increase in coarse dust particles in comparison to winter. The aerosol vertical profiles can be used to lower uncertainty in estimating radiative forcing.« less

  2. Effect of biomass feedstock chemical and physical properties on energy conversion processes: Volume 2, Appendices

    SciTech Connect (OSTI)

    Butner, R.S.; Elliott, D.C.; Sealock, L.J., Jr.; Pyne, J.W.

    1988-12-01

    This report presents an exploration of the relationships between biomass feedstocks and the conversion processes that utilize them. Specifically, it discusses the effect of the physical and chemical structure of biomass on conversion yields, rates, and efficiencies in a wide variety of available or experimental conversion processes. A greater understanding of the complex relationships between these conversion systems and the production of biomass for energy uses is required to help optimize the complex network of biomass production, collection, transportation, and conversion to useful energy products. The review of the literature confirmed the scarcity of research aimed specifically at identifying the effect of feedstock properties on conversion. In most cases, any mention of feedstock-related effects was limited to a few brief remarks (usually in qualitative terms) in the conclusions, or as a topic for further research. Attempts to determine the importance of feedstock parameters from published data were further hampered by the lack of consistent feedstock characterization and the difficulty of comparing results between different experimental systems. Further research will be required to establish quantitative relationships between feedstocks and performance criteria in conversion. 127 refs., 4 figs., 7 tabs.

  3. Chlorinated degreasing solvents: Physical-chemical properties affecting aquifer contamination and remediation

    SciTech Connect (OSTI)

    Jackson, R.E.; Dwarakanath, V.

    1999-09-30

    Chlorinated degreasing solvents are multicomponent liquids containing not only the chlorinated hydrocarbons with which their name is associated (e.g., trichloroethylene or [TCE], perchloroethylene or [PCE], 1,1,1-trichloroethane [TCA]) but also a number of organic additives included as corrosion inhibitors and antioxidants. The additives, such as 1,4-dioxane, are likely to be of significant public-health importance as ground water contaminants due to their toxicity, solubility, and mobility. Following their use in vapor degreasing systems by industry, chlorinated degreasing solvents will also contain about 25% solubilized oil and grease. A number of physical-chemical properties become especially important in the light of the multicomponent nature of these solvents. First, the higher aqueous solubility and lower sorption of the additives makes it reasonable to expect that faster moving plumes of these solvent additives will precede plumes of the chlorinated hydrocarbons. Second, due to high losses of chlorinated hydrocarbons by volatilization from vapor degreasers during years in the middle of the century, it is probable that background concentrations of these hydrocarbons are present in ground water flow systems due to their downwind washout. Finally, the solubilized oil and grease may cause profound changes to the wettability of aquifer materials contacted by the solvents during their subsurface migration. It is argued, therefore, that the wettability of aquifer materials contaminated by chlorinated degreasing solvents needs to be experimentally determined before remediation of DNAPL at each site, rather than being simply assumed as water wet.

  4. Electrode Materials with the Na0.44MnO2 Structure: Effect ofTitanium Substitution on Physical and Electrochemical Properties

    SciTech Connect (OSTI)

    Doeff, Marca M; Saint, Juliette A.; Doeff, Marca M; Wilcox, James D.

    2008-03-10

    The physical and electrochemical properties of LixMnO2 and LixTi0.11Mn0.89O2 synthesized from precursors made by glycine-nitrate combustion (GNC) and solid-state synthesis methods (SS) are examined in this paper. The highest specific capacities in lithium cells are obtained for SS-LixMnO2 electrodes at low current densities, but GNC-LixTi0.11Mn0.89O2 electrodes show the best high rate performance. These results can be explained by changes in the voltage characteristics and differences in the particle morphologies induced by the Ti-substitution and synthesis method. Ti-substitution also results in a decrease in the electronic conductivity, but greatly improves the thermal properties and imparts dissolution resistance to the electrode. For these reasons, it is preferable to use LixTi0.11MnO0.89O2 in lithium battery configurations rather than LixMnO2. Suggestions for improving the electrochemical performance of the Ti-substituted variant are given based on the results described herein.

  5. Variation of the shape and morphological properties of silica and metal oxide powders by electro homogeneous precipitation

    DOE Patents [OSTI]

    Harris, M.T.; Basaran, O.A.; Sisson, W.G.; Brunson, R.R.

    1997-02-18

    The present invention provides a method for preparing irreversible linear aggregates (fibrils) of metal oxide powders by utilizing static or pulsed DC electrical fields across a relatively non-conducting liquid solvent in which organometal compounds or silicon alkoxides have been dissolved. The electric field is applied to the relatively non-conducting solution throughout the particle formation and growth process promoting the formation of either linear aggregates (fibrils) or spherical shaped particles as desired. Thus the present invention provides a physical method for altering the size, shape and porosity of precursor hydrous metal oxide or hydrous silicon oxide powders for the development of advanced ceramics with improved strength and insulating capacity. 3 figs.

  6. Multiwalled carbon nanotubes and dispersed nanodiamond novel hybrids: Microscopic structure evolution, physical properties, and radiation resilience

    SciTech Connect (OSTI)

    Gupta, S.; Farmer, J.

    2011-01-01

    We report the structure and physical properties of novel hybrids of multiwalled carbon nanotubes (MWCNTs) and ultradispersed diamond (UDD) forming nanocomposite ensemble that were subjected to 50, 100, and 10{sup 3} kGy gamma ray doses and characterized using various analytical tools to investigate hierarchical defects evolution. This work is prompted by recent work on single-walled CNTs and UDD ensemble [Gupta et al., J. Appl. Phys. 107, 104308 (2010)] where radiation-induced microscopic defects seem to be stabilized by UDD. The present experiments show similar effects where these hybrids display only a minimal structural modification under the maximum dose. Quantitative analyses of multiwavelength Raman spectra revealed lattice defects induced by irradiation assessed through the variation in prominent D, G, and 2D bands. A minimal change in the position of D, G, and 2D bands and a marginal increase in intensity of the defect-induced double resonant Raman scattered D and 2D bands are some of the implications suggesting the radiation coupling. The in-plane correlation length (L{sub a}) was also determined following Tunistra-Koenig relation from the ratio of D to G band (I{sub D}/I{sub G}) besides microscopic stress. However, we also suggest the following taking into account of intrinsic defects of the constituents: (a) charge transfer arising at the interface due to the difference in electronegativity of MWCNT C sp{sup 2} and UDD core (C sp{sup 3}) leading to phonon and electron energy renormalization; (b) misorientation of C sp{sup 2} at the interface of MWCNT and UDD shell (C sp{sup 2}) resulting in structural disorder; (c) softening or violation of the q{approx}0 selection rule leading to D band broadening and a minimal change in G band intensity; and (d) normalized intensity of D and G bands with 2D band help to distinguish defect-induced double resonance phenomena. The MWCNT when combined with nanodiamond showed a slight decrease in their conductance further

  7. Electrical properties and surface morphology of electron beam evaporated p-type silicon thin films on polyethylene terephthalate for solar cells applications

    SciTech Connect (OSTI)

    Ang, P. C.; Ibrahim, K.; Pakhuruddin, M. Z.

    2015-04-24

    One way to realize low-cost thin film silicon (Si) solar cells fabrication is by depositing the films with high-deposition rate and manufacturing-compatible electron beam (e-beam) evaporation onto inexpensive foreign substrates such as glass or plastic. Most of the ongoing research is reported on e-beam evaporation of Si films on glass substrates to make polycrystalline solar cells but works combining both e-beam evaporation and plastic substrates are still scarce in the literature. This paper studies electrical properties and surface morphology of 1 µm electron beam evaporated Al-doped p-type silicon thin films on textured polyethylene terephthalate (PET) substrate for application as an absorber layer in solar cells. In this work, Si thin films with different doping concentrations (including an undoped reference) are prepared by e-beam evaporation. Energy dispersion X-ray (EDX) showed that the Si films are uniformly doped by Al dopant atoms. With increased Al/Si ratio, doping concentration increased while both resistivity and carrier mobility of the films showed opposite relationships. Root mean square (RMS) surface roughness increased. Overall, the Al-doped Si film with Al/Si ratio of 2% (doping concentration = 1.57×10{sup 16} atoms/cm{sup 3}) has been found to provide the optimum properties of a p-type absorber layer for fabrication of thin film Si solar cells on PET substrate.

  8. Effect of reductant and PVP on morphology and magnetic property of ultrafine Ni powders prepared via hydrothermal route

    SciTech Connect (OSTI)

    Zhang, Jun Wang, Xiucai; Li, Lili; Li, Chengxuan; Peng, Shuge

    2013-10-15

    Graphical abstract: The ultrafine Ni powders with the shapes including sphere, pearl-string, leaf, fish-bone, hexagonal sheet and silknet were prepared through one-step hydrothermal reduction using different reductants. Their saturation magnetization, remanent magnetization and coercivity sequentially increase, and the coercivity of hexagonal sheet-like Ni powders increases by 25% compared with the Ni bulk counterpart. - Highlights: • The ultrafine Ni powders with various shapes of sphere, fish-bone, hexagonal sheet, etc. • Facile and one-step hydrothermal reduction using three reductants and PVP additive was developed. • Magnetic properties of the ultrafine Ni powders with different shapes were measured. • Compared with bulk Ni material, coercivity of hexagonal sheet Ni increases by 25%. • The formation mechanism of the shapes was suggested. - Abstract: The ultrafine nickel particles with different shapes including sphere, pearl-string, leaf, fish-bone, hexagonal sheet and silknet were prepared through one-step hydrothermal reduction using hydrazine hydrate, sodium hypophosphite and ethylene glycol as reductants, polyvinylpyrrolidone as structure-directing agent. It has been verified with the characterization of X-ray powder diffraction and transmission/scanning electronic microscopy that as-prepared products belong to face-centered cubic structure of nickel microcrystals with high purity and fine dispersity. The magnetic hysteresis loops measured at room temperature reveal that the values of saturation magnetization, remanent magnetization and coercivity rise sequentially from silknet, sphere to hexagonal sheet. In comparison with nickel bulk counterpart, the coercivity of the hexagonal sheet nickel powders increases by 25%.

  9. Influence of combustion conditions and coal properties on physical properties of fly ash generated from pulverized coal combustion

    SciTech Connect (OSTI)

    Hiromi Shirai; Hirofumi Tsuji; Michitaka Ikeda; Toshinobu Kotsuji

    2009-07-15

    To develop combustion technology for upgrading the quality of fly ash, the influences of the coal properties, such as the size of pulverized coal particles and the two-stage combustion ratio during the combustion, on the fly ash properties were investigated using our test furnace. The particle size, density, specific surface area (obtained by the Blaine method), and shape of fly ash particles of seven types of coal were measured. It was confirmed that the size of pulverized coal particles affects the size of the ash particles. Regarding the coal properties, the fuel ratio affected the ash particle size distribution. The density and shape of the ash particles strongly depended on their ash size. Our results indicated that the shape of the ash particles and the concentration of unburned carbon affected the specific surface area. The influence of the two-stage combustion ratio was limited. 8 refs., 13 figs., 3 tabs.

  10. Status Report for Remediation Decision Support Project, Task 1, Activity 1.B Physical and Hydraulic Properties Database and Interpretation

    SciTech Connect (OSTI)

    Rockhold, Mark L.

    2008-09-26

    The objective of Activity 1.B of the Remediation Decision Support (RDS) Project is to compile all available physical and hydraulic property data for sediments from the Hanford Site, to port these data into the Hanford Environmental Information System (HEIS), and to make the data web-accessible to anyone on the Hanford Local Area Network via the so-called Virtual Library. In past years efforts were made by RDS project staff to compile all available physical and hydraulic property data for Hanford sediments and to transfer these data into SoilVision{reg_sign}, a commercial geotechnical software package designed for storing, analyzing, and manipulating soils data. Although SoilVision{reg_sign} has proven to be useful, its access and use restrictions have been recognized as a limitation to the effective use of the physical and hydraulic property databases by the broader group of potential users involved in Hanford waste site issues. In order to make these data more widely available and useable, a decision was made to port them to HEIS and to make them web-accessible via a Virtual Library module. In FY08 the objectives of Activity 1.B of the RDS Project were to: (1) ensure traceability and defensibility of all physical and hydraulic property data currently residing in the SoilVision{reg_sign} database maintained by PNNL, (2) transfer the physical and hydraulic property data from the Microsoft Access database files used by SoilVision{reg_sign} into HEIS, which has most recently been maintained by Fluor-Hanford, Inc., (3) develop a Virtual Library module for accessing these data from HEIS, and (4) write a User's Manual for the Virtual Library module. The development of the Virtual Library module was to be performed by a third party under subcontract to Fluor. The intent of these activities is to make the available physical and hydraulic property data more readily accessible and useable by technical staff and operable unit managers involved in waste site assessments and

  11. Additional development of remote sensing techniques for observing morphology, microphysics, and radiative properties of clouds and tests using a new, robust CO{sub 2} lidar. Annual progress report, August 15, 1994--August 30, 1995

    SciTech Connect (OSTI)

    Eberhard, W.L.; Intrieri, J.M.; Brewer, W.A.

    1996-04-01

    The bulk morphology and microphysical characteristics of a cloud are both important in determining the cloud`s effect on radiative transfer. A better understanding of all these properties, and the links among them, are needed for developing adequate parameterizations of these components in climate models. The objective of this project is to develop remote sensing techniques for observing key cloud properties, including the linkages. The research has technique development and instrument development prongs.

  12. Physical, Hydraulic, and Transport Properties of Sediments and Engineered Materials Associated with Hanford Immobilized Low-Activity Waste

    SciTech Connect (OSTI)

    Rockhold, Mark L.; Zhang, Z. F.; Meyer, Philip D.; Thomle, Jonathan N.

    2015-02-28

    Current plans for treatment and disposal of immobilized low-activity waste (ILAW) from Hanford’s underground waste storage tanks include vitrification and storage of the glass waste form in a nearsurface disposal facility. This Integrated Disposal Facility (IDF) is located in the 200 East Area of the Hanford Central Plateau. Performance assessment (PA) of the IDF requires numerical modeling of subsurface flow and reactive transport processes over very long periods (thousands of years). The models used to predict facility performance require parameters describing various physical, hydraulic, and transport properties. This report provides updated estimates of physical, hydraulic, and transport properties and parameters for both near- and far-field materials, intended for use in future IDF PA modeling efforts. Previous work on physical and hydraulic property characterization for earlier IDF PA analyses is reviewed and summarized. For near-field materials, portions of this document and parameter estimates are taken from an earlier data package. For far-field materials, a critical review is provided of methodologies used in previous data packages. Alternative methods are described and associated parameters are provided.

  13. Molecular modeling of the morphology and transport properties of two direct methanol fuel cell membranes: phenylated sulfonated poly(ether ether ketone ketone) versus Nafion

    SciTech Connect (OSTI)

    Devanathan, Ramaswami; Idupulapati, Nagesh B.; Dupuis, Michel

    2012-08-14

    We have used molecular dynamics simulations to examine membrane morphology and the transport of water, methanol and hydronium in phenylated sulfonated poly ether ether ketone ketone (Ph-SPEEKK) and Nafion membranes at 360 K for a range of hydration levels. At comparable hydration levels, the pore diameter is smaller, the sulfonate groups are more closely packed, the hydronium ions are more strongly bound to sulfonate groups, and the diffusion of water and hydronium is slower in Ph-SPEEKK relative to the corresponding properties in Nafion. The aromatic carbon backbone of Ph-SPEEKK is less hydrophobic than the fluorocarbon backbone of Nafion. Water network percolation occurs at a hydration level ({lambda}) of {approx}8 H{sub 2}O/SO{sub 3}{sup -}. At {lambda} = 20, water, methanol and hydronium diffusion coefficients were 1.4 x 10{sup -5}, 0.6 x 10{sup -5} and 0.2 x 10{sup -5} cm{sup 2}/s, respectively. The pore network in Ph-SPEEKK evolves dynamically and develops wide pores for {lambda} > 20, which leads to a jump in methanol crossover and ion transport. This study demonstrates the potential of aromatic membranes as low-cost challengers to Nafion for direct methanol fuel cell applications and the need to develop innovative strategies to combat methanol crossover at high hydration levels.

  14. Using Plasmon Peaks in Electron Energy-Loss Spectroscopy to Determine the Physical and Mechanical Properties of Nanoscale Materials

    SciTech Connect (OSTI)

    Howe, James M.

    2013-05-09

    In this program, we developed new theoretical and experimental insights into understanding the relationships among fundamental universality and scaling phenomena, the solid-state physical and mechanical properties of materials, and the volume plasmon energy as measured by electron energy-loss spectroscopy (EELS). Particular achievements in these areas are summarized as follows: (i) Using a previously proposed physical model based on the universal binding-energy relation (UBER), we established close phenomenological connections regarding the influence of the valence electrons in materials on the longitudinal plasma oscillations (plasmons) and various solid-state properties such as the optical constants (including absorption and dispersion), elastic constants, cohesive energy, etc. (ii) We found that carbon materials, e.g., diamond, graphite, diamond-like carbons, hydrogenated and amorphous carbon films, exhibit strong correlations in density vs. Ep (or maximum of the volume plasmon peak) and density vs. hardness, both from available experimental data and ab initio DFT calculations. This allowed us to derive a three-dimensional relationship between hardness and the plasmon energy, that can be used to determine experimentally both hardness and density of carbon materials based on measurements of the plasmon peak position. (iii) As major experimental accomplishments, we demonstrated the possibility of in-situ monitoring of changes in the physical properties of materials with conditions, e.g., temperature, and we also applied a new plasmon ratio-imaging technique to map multiple physical properties of materials, such as the elastic moduli, cohesive energy and bonding electron density, with a sub-nanometer lateral resolution. This presents new capability for understanding material behavior. (iv) Lastly, we demonstrated a new physical phenomenon - electron-beam trapping, or ?¢????electron tweezers?¢??? - of a solid metal nanoparticle inside a liquid metal

  15. Comparison of physical properties of quiet and active regions through the analysis of magnetohydrodynamic simulations of the solar photosphere

    SciTech Connect (OSTI)

    Criscuoli, S.

    2013-11-20

    Recent observations have shown that the photometric and dynamic properties of granulation and small-scale magnetic features depend on the amount of magnetic flux of the region they are embedded in. We analyze results from numerical hydrodynamic and magnetohydrodynamic simulations characterized by different amounts of average magnetic flux and find qualitatively the same differences as those reported from observations. We show that these different physical properties result from the inhibition of convection induced by the presence of the magnetic field, which changes the temperature stratification of both quiet and magnetic regions. Our results are relevant for solar irradiance variations studies, as such differences are still not properly taken into account in irradiance reconstruction models.

  16. Tailoring the physical properties of Ni-based single-phase equiatomic alloys by modifying the chemical complexity

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jin, Ke; Sales, Brian C.; Stocks, George Malcolm; Samolyuk, German D.; Daene, Markus; Weber, William J.; Zhang, Yanwen; Bei, Hongbin

    2016-02-01

    We discovered that equiatomic alloys (e.g. high entropy alloys) have recently attracted considerable interest due to their exceptional properties, which might be closely related to their extreme disorder induced by the chemical complexity. To understand the effects of chemical complexity on their fundamental physical properties, a family of (eight) Ni-based, face-center-cubic (FCC), equiatomic alloys, extending from elemental Ni to quinary high entropy alloys, has been synthesized, and their electrical, thermal, and magnetic properties are systematically investigated in the range of 4–300 K by combining experiments with ab initio Korring-Kohn-Rostoker coherent-potential-approximation (KKR-CPA) calculations. The scattering of electrons is significantly increased duemore » to the chemical (especially magnetic) disorder. It has weak correlation with the number of elements but strongly depends on the type of elements. Thermal conductivities of the alloys are largely lower than pure metals, primarily because the high electrical resistivity suppresses the electronic thermal conductivity. Moreover, the temperature dependence of the electrical and thermal transport properties is further discussed, and the magnetization of five alloys containing three or more elements is measured in magnetic fields up to 4 T.« less

  17. Influence of growth time on crystalline structure, morphologic and optical properties of In{sub 2}O{sub 3} thin films

    SciTech Connect (OSTI)

    Attaf, A. Bouhdjar, A.; Saidi, H.; Benkhetta, Y.; Bendjedidi, H.; Nouadji, M.; Lehraki, N.

    2015-03-30

    Indium oxide (In{sub 2}O{sub 3}) thin films are successfully deposited on glass substrate at different deposition timings by ultrasonic spray technique using Indium chloride (InCl{sub 3}) material source witch is prepared with dissolvent Ethanol (C{sub 2}H{sub 5}-OH), the physical properties of these films are characterized by XRD, MEB,UV-visible. XRD analysis revealed that the films are polycrystalline in nature having centered cubic crystal structure and symmetry space group I2{sub 1}3 with a preferred grain orientation along to (222) plane when the deposition time changes from 4 to 10 min but after t = 10 min, especially when t = 13 min we found that the majority of grains preferred the plane (400). The maximum value of grain size D = 61,51 nm is attained for In{sub 2}O{sub 3} films grown at t =10 min. the average transmittance is about 72%, The optical gap energy is found to decrease from 3.8 to 3.66 eV with growth time Increased from 4 to 10 min but after t = 10 min the value of E{sub g} will increase to 3.72 eV. A systematic study on the influence of growth time on the properties of In{sub 2}O{sub 3} thin films deposited by ultrasonic spray at 400 °C has been reported.

  18. Dynamical properties of fractal networks: Scaling, numerical simulations, and physical realizations

    SciTech Connect (OSTI)

    Nakayama, T.; Yakubo, K. ); Orbach, R.L. )

    1994-04-01

    This article describes the advances that have been made over the past ten years on the problem of fracton excitations in fractal structures. The relevant systems to this subject are so numerous that focus is limited to a specific structure, the percolating network. Recent progress has followed three directions: scaling, numerical simulations, and experiment. In a happy coincidence, large-scale computations, especially those involving array processors, have become possible in recent years. Experimental techniques such as light- and neutron-scattering experiments have also been developed. Together, they form the basis for a review article useful as a guide to understanding these developments and for charting future research directions. In addition, new numerical simulation results for the dynamical properties of diluted antiferromagnets are presented and interpreted in terms of scaling arguments. The authors hope this article will bring the major advances and future issues facing this field into clearer focus, and will stimulate further research on the dynamical properties of random systems.

  19. Influence of Radiation-Induced Voids and Bubbles on Physical Properties of Austenitic Structural Alloys

    SciTech Connect (OSTI)

    Shcherbakov, E. N.; Kozlov, A. V.; Portnykh, I. A.; Balachov, Iouri I.; Garner, Francis A.

    2004-08-01

    Void swelling in austenitic stainless steels induces significant changes in their electrical resistivity and elastic moduli, as demonstrated in this study using a Russian stainless steel irradiated as fuel pin cladding in BN-600. Precipitation induced by irradiation also causes second-order changes in these properties. When cavities are full of helium as expected under some fusion irradiation conditions, additional second-order changes are expected but they will be small enough to exclude from the analysis.

  20. On the Chemistry and Physical Properties of Flux and Floating Zone Grown SmB6 Single Crystals

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Phelan, W. A.; Koohpayeh, S. M.; Cottingham, P.; Tutmaher, J. A.; Leiner, J. C.; Lumsden, M. D.; Lavelle, C. M.; Wang, X. P.; Hoffmann, C.; Siegler, M. A.; et al

    2016-02-19

    Recent theoretical and experimental findings suggest the long-known but not well understood low temperature resistance plateau of SmB6 may originate from protected surface states arising from a topologically non-trivial bulk band structure having strong Kondo hybridization. Yet others have ascribed this feature to impurities, vacancies, and surface reconstructions. Given the typical methods used to prepare SmB6 single crystals, flux and floating-zone procedures, such ascriptions should not be taken lightly. We demonstrate how compositional variations and/or observable amounts of impurities in SmB6 crystals grown using both procedures affect the physical properties. From X-ray diffraction, neutron diffraction, and X-ray computed tomography experimentsmore » we observe that natural isotope containing (SmB6) and doubly isotope enriched (154Sm11B6) crystals prepared using aluminum flux contain co-crystallized, epitaxial aluminum. Further, a large, nearly stoichiometric crystal of SmB6 was successfully grown using the float-zone technique; upon continuing the zone melting, samarium vacancies were introduced. These samarium vacancies drastically alter the resistance and plateauing magnitude of the low temperature resistance compared to stoichiometric SmB6. Finally, these results highlight that impurities and compositional variations, even at low concentrations, must be considered when collecting/analyzing physical property data of SmB6. Finally, a more accurate samarium-154 coherent neutron scattering length, 8.9(1) fm, is reported.« less

  1. Grinding energy and physical properties of chopped and hammer-milled barley, wheat, oat, and canola straws

    SciTech Connect (OSTI)

    J.S. Tumuluru; L.G. Tabil; Y. Song; K.L. Iroba; V. Meda

    2014-01-01

    In the present study, specific energy for grinding and physical properties of wheat, canola, oat and barley straw grinds were investigated. The initial moisture content of the straw was about 0.130.15 (fraction total mass basis). Particle size reduction experiments were conducted in two stages: (1) a chopper without a screen, and (2) a hammer mill using three screen sizes (19.05, 25.4, and 31.75 mm). The lowest grinding energy (1.96 and 2.91 kWh t-1) was recorded for canola straw using a chopper and hammer mill with 19.05-mm screen size, whereas the highest (3.15 and 8.05 kWh t-1) was recorded for barley and oat straws. The physical properties (geometric mean particle diameter, bulk, tapped and particle density, and porosity) of the chopped and hammer-milled wheat, barley, canola, and oat straw grinds measured were in the range of 0.984.22 mm, 3680 kg m-3, 49119 kg m-3, 6001220 kg m-3, and 0.90.96, respectively. The average mean particle diameter was highest for the chopped wheat straw (4.22-mm) and lowest for the canola grind (0.98-mm). The canola grinds produced using the hammer mill (19.05-mm screen size) had the highest bulk and tapped density of about 80 and 119 kg m-3; whereas, the wheat and oat grinds had the lowest of about 58 and 8890 kg m-3. The results indicate that the bulk and tapped densities are inversely proportional to the particle size of the grinds. The flow properties of the grinds calculated are better for chopped straws compared to hammer milled using smaller screen size (19.05 mm).

  2. CONSTRAINING PHYSICAL PROPERTIES OF TYPE IIn SUPERNOVAE THROUGH RISE TIMES AND PEAK LUMINOSITIES

    SciTech Connect (OSTI)

    Moriya, Takashi J.; Maeda, Keiichi

    2014-08-01

    We investigate the diversity in the wind density, supernova ejecta energy, and ejecta mass in Type IIn supernovae based on their rise times and peak luminosities. We show that the wind density and supernova ejecta properties can be estimated independently if both the rise time and peak luminosity are observed. The peak luminosity is mostly determined by the supernova properties and the rise time can be used to estimate the wind density. We find that the ejecta energies of Type IIn supernovae need to vary by factors of 0.2-5 from the average if their ejecta masses are similar. The diversity in the observed rise times indicates that their wind densities vary by factors of 0.2-2 from the average. We show that Type IIn superluminous supernovae should have not only large wind density but also large ejecta energy and/or small ejecta mass to explain their large luminosities and the rise times at the same time. We also note that shock breakout does not necessarily occur in the wind even if it is optically thick, except for the case of superluminous supernovae, and we analyze the observational data both with and without assuming that the shock breakout occurs in the dense wind of Type IIn supernovae.

  3. A study of the physical properties of single crystalline Fe5B2P

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lamichhane, Tej N.; Taufour, Valentin; Thimmaiah, Srinivasa; Parker, David S.; Bud'ko, Sergey L.; Canfield, Paul C.

    2015-10-24

    Single crystals of Fe5B2PP were grown by self-flux growth technique. Structural and magnetic properties are studied. The Curie temperature of Fe5B2P is determined to be 655 ± 2 K. The saturation magnetization is determined to be 1.72 μB/Fe at 2 K. The temperature variation of the anisotropy constant K1 is determined for the first time, reaching 0:50 MJ/m3 at 2 K, and it is comparable to that of hard ferrites. The saturation magnetization is found to be larger than the hard ferrites. The first principle calculations of saturation magnetization and anisotropy constant are found to be consistent with the experimentalmore » results.« less

  4. Method of varying a physical property of a material through its depth

    SciTech Connect (OSTI)

    Daniel, Claus

    2015-04-21

    A method is disclosed for varying a mechanical property of a material at two depths. The method involves the application of at least two laser pulses of different durations. The method involves a determination of the density of the material from the surface to each depth, a determination of the heat capacity of the material from the surface to each depth, and a determination of the thermal conductivity of the material from the surface to each depth. Each laser pulse may affect the density, heat capacity, and thermal conductivity of the material, so it may be necessary to re-evaluate those parameters after each laser pulse and prior to the next pulse. The method may be applied to implantation materials to improve osteoblast and osteoclast activity.

  5. Physical properties and analytical models of band-to-band tunneling in low-bandgap semiconductors

    SciTech Connect (OSTI)

    Shih, Chun-Hsing Dang Chien, Nguyen

    2014-01-28

    Low-bandgap semiconductors, such as InAs and InSb, are widely considered to be ideal for use in tunnel field-effect transistors to ensure sufficient on-current boosting at low voltages. This work elucidates the physical and mathematical considerations of applying conventional band-to-band tunneling models in low-bandgap semiconductors, and presents a new analytical alternative for practical use. The high-bandgap tunneling generates most at maximum field region with shortest tunnel path, whereas the low-bandgap generations occur dispersedly because of narrow tunnel barrier. The local electrical field associated with tunneling-electron numbers dominates in low-bandgap materials. This work proposes decoupled electric-field terms in the pre-exponential factor and exponential function of generation-rate expressions. Without fitting, the analytical results and approximated forms exhibit great agreements with the sophisticated forms both in high- and low-bandgap semiconductors. Neither nonlocal nor local field is appropriate to be used in numerical simulations for predicting the tunneling generations in a variety of low- and high-bandgap semiconductors.

  6. Superconductivity and Physical Properties of CaPd2Ge2 Single Crystals

    SciTech Connect (OSTI)

    Anand, V K; Kim, Hyunsoo; Tanatar, Makariy A; Prozorov, Ruslan; Johnston, David C

    2014-10-08

    We present the superconducting and normal state properties of CaPd2Ge2 single crystals investigated by magnetic susceptibility ?, isothermal magnetization M, heat capacity Cp, in-plane electrical resistivity ? and London penetration depth ? versus temperature T and magnetic field H measurements. Bulk superconductivity is inferred from the ?(T) and Cp(T) data. The ?(T) data exhibit metallic behavior and a superconducting transition with Tc onset = 1.98 K and zero resistivity at Tc 0 = 1.67 K. The ?(T) reveals the onset of superconductivity at 2.0 K. For T > 2.0 K, the ?(T) and M(H) are weakly anisotropic paramagnetic with ?ab > ?c. The Cp(T) data confirm the bulk superconductivity below Tc = 1.69(3) K. The superconducting state electronic heat capacity is analyzed within the framework of a single-band ?-model of BCS superconductivity and various normal and superconducting state parameters are estimated. Within the ?-model, the Cp(T) data and the ab plane ?(T) data consistently indicate a moderately anisotropic s-wave gap with ?(0)/kBTc ? 1.6, somewhat smaller than the BCS value of 1.764. The relationship of the heat capacity jump at Tc and the penetration depth measurement to the anisotropy in the s-wave gap is discussed.

  7. Ultem®/ZIF-8 mixed matrix membranes for gas separation: Transport and physical properties

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Eiras, Daniel; Labreche, Ying; Pessan, Luiz Antonio

    2016-02-19

    Mixed matrix membranes are promising options for improving gas separation processes. Zeolitic imidazolate frameworks (ZIFs) have a porous structure similar to conventional zeolites, being capable in principle of separating gases based on their differences in kinetic diameter while offering the advantage of having a partial organic character. This partial organic nature improves the compatibility between the sieve and the polymer, and a combination of the mentioned characteristics makes these hybrid materials interesting for the preparation of mixed matrix gas separation membranes. In this context the present work reports the preparation of Ultem®/ZIF-8 mixed matrix membranes and their permeabilities to puremore » CO2, N2 and CH4 gases. A significant increase in permeability with increase in CO2/N2 selectivity was observed for the mixed matrix systems as compared to the properties of the neat Ultem®. Sorption results allowed to speculate that the ZIF-8 framework is not completely stable dimensionally, what influences the separation process by allowing gases with higher kinetic diameter than its nominal aperture to be sorbed and to diffuse through the crystal. Lastly, sorption and diffusion selectivities indicate that the higher separation performance of the mixed matrix membranes is governed by the diffusion process associated with the influence of gas molecule´s geometry.« less

  8. Modeling of Some Physical Properties of Zirconium Alloys for Nuclear Applications in Support of UFD Campaign

    SciTech Connect (OSTI)

    Michael V. Glazoff

    2013-08-01

    Zirconium-based alloys Zircaloy-2 and Zircaloy-4 are widely used in the nuclear industry as cladding materials for light water reactor (LWR) fuels. These materials display a very good combination of properties such as low neutron absorption, creep behavior, stress-corrosion cracking resistance, reduced hydrogen uptake, corrosion and/or oxidation, especially in the case of Zircaloy-4. However, over the last couple of years, in the post-Fukushima Daiichi world, energetic efforts have been undertaken to improve fuel clad oxidation resistance during off-normal temperature excursions. Efforts have also been made to improve upon the already achieved levels of mechanical behavior and reduce hydrogen uptake. In order to facilitate the development of such novel materials, it is very important to achieve not only engineering control, but also a scientific understanding of the underlying material degradation mechanisms, both in working conditions and in storage of used nuclear fuel. This report strives to contribute to these efforts by constructing the thermodynamic models of both alloys; constructing of the respective phase diagrams, and oxidation mechanisms. A special emphasis was placed upon the role of zirconium suboxides in hydrogen uptake reduction and the atomic mechanisms of oxidation. To that end, computational thermodynamics calculations were conducted concurrently with first-principles atomistic modeling.

  9. Improved crystal orientation and physical properties from single-shot XFEL stills

    SciTech Connect (OSTI)

    Sauter, Nicholas K., E-mail: nksauter@lbl.gov; Hattne, Johan; Brewster, Aaron S.; Echols, Nathaniel; Zwart, Petrus H.; Adams, Paul D. [Lawrence Berkeley National Laboratory, Berkeley, CA 94720 (United States)

    2014-12-01

    X-ray free-electron laser crystallography relies on the collection of still-shot diffraction patterns. New methods are developed for optimal modeling of the crystals orientations and mosaic block properties. X-ray diffraction patterns from still crystals are inherently difficult to process because the crystal orientation is not uniquely determined by measuring the Bragg spot positions. Only one of the three rotational degrees of freedom is directly coupled to spot positions; the other two rotations move Bragg spots in and out of the reflecting condition but do not change the direction of the diffracted rays. This hinders the ability to recover accurate structure factors from experiments that are dependent on single-shot exposures, such as femtosecond diffract-and-destroy protocols at X-ray free-electron lasers (XFELs). Here, additional methods are introduced to optimally model the diffraction. The best orientation is obtained by requiring, for the brightest observed spots, that each reciprocal-lattice point be placed into the exact reflecting condition implied by Braggs law with a minimal rotation. This approach reduces the experimental uncertainties in noisy XFEL data, improving the crystallographic R factors and sharpening anomalous differences that are near the level of the noise.

  10. Spreading of crude petroleum in brash ice; Effects of oil`s physical properties and water current

    SciTech Connect (OSTI)

    Sayed, M.; Kotlyar, L.S.; Sparks, B.D.

    1994-12-31

    Experiments were conducted in a refrigerated, circulating current flume to examine crude oil spreading in brash ice. Amauligak, Hibernia and Norman Wells crudes were tested. Measurements of the physical properties of the oils were also conducted, including: surface and interfacial tensions as well as viscosities. Spreading coefficients were calculated from measured surface and interfacial tensions. Results were obtained for original and weathered oils. For the spreading tests, spill volumes up to 3 liters and water currents up to 0.55 m/s were used. Tests were done using both fresh water ice and saline ice. Slick dimensions were measured, and modes of oil spreading were observed. Slick dimensions depended on oil type, but were not influenced by water current. Oils of high spreading coefficient and low viscosity spread over larger areas than those with low spreading coefficient and high viscosity.

  11. DOE THREE-DIMENSIONAL STRUCTURE AND PHYSICAL PROPERTIES OF A METHANE HYDRATE DEPOSIT AND GAS RESERVOIR, BLAKE RIDGE

    SciTech Connect (OSTI)

    W. Steven Holbrook

    2004-11-11

    This report contains a summary of work conducted and results produced under the auspices of award DE-FC26-00NT40921, ''DOE Three-Dimensional Structure and Physical Properties of a Methane Hydrate Deposit and Gas Reservoir, Blake Ridge.'' This award supported acquisition, processing, and interpretation of two- and three-dimensional seismic reflection data over a large methane hydrate reservoir on the Blake Ridge, offshore South Carolina. The work supported by this project has led to important new conclusions regarding (1) the use of seismic reflection data to directly detect methane hydrate, (2) the migration and possible escape of free gas through the hydrate stability zone, and (3) the mechanical controls on the maximum thickness of the free gas zone and gas escape.

  12. Modulation of physical and photocatalytic properties of (Cr, N) codoped TiO{sub 2} nanorods using soft solution processing

    SciTech Connect (OSTI)

    Lu, Wen-Chung; Nguyen, Hoang-Diem; Wu, Chun-Yi; Chang, Kao-Shuo Yoshimura, Masahiro

    2014-04-14

    Facile polymerized complex reactions together with a hydrothermal reaction were implemented to make single crystalline TiO{sub 2} nanorods for the first time. Chromium (Cr) and nitrogen (N{sub 2}) co-doping was performed to tailor the physical properties. Transmission electron microscopy and x-ray diffraction study illustrated that highly reactive facets of (101), (111), and (001) dominated rutile TiO{sub 2} nanorods. A growth model, based on formation of complex species, was proposed to elucidate effectiveness of the soft solution processing in making TiO{sub 2} nanorods. X-ray photoelectron spectroscopy analysis and consideration of fundamentals of charge neutrality showed N{sub 2} doping could inhibit formation of Cr{sup 6+} and oxygen vacancies (V{sub O}{sup 2+}). An investigation of the photocatalytic properties exhibited high efficiency of photodegradation of methylene blue in 15 min under pH = 10, using a nanocomposite of (7% Cr, 0.0021% N) codoped and 3% Cr doped TiO{sub 2} nanorods.

  13. PHYSICAL PROPERTIES OF MAIN-BELT COMET 176P/LINEAR

    SciTech Connect (OSTI)

    Hsieh, Henry H.; Ishiguro, Masateru; Lacerda, Pedro; Jewitt, David E-mail: p.lacerda@qub.ac.uk E-mail: jewitt@ucla.edu

    2011-07-15

    We present a physical characterization of comet 176P/LINEAR, the third discovered member of the new class of main-belt comets, which exhibit cometary activity but are dynamically indistinguishable from main-belt asteroids. Observations show the object exhibiting a fan-shaped tail for at least one month in late 2005, but then becoming inactive in early 2006. During this active period, we measure broadband colors of B - V = 0.63 {+-} 0.02, V - R = 0.35 {+-} 0.02, and R - I = 0.31 {+-} 0.04. Using data from when the object was observed to be inactive, we derive best-fit IAU phase function parameters of H = 15.10 {+-} 0.05 mag and G = 0.15 {+-} 0.10, and best-fit linear phase function parameters of m(1, 1, 0) = 15.35 {+-} 0.05 mag and {beta} = 0.038 {+-} 0.005 mag deg{sup -1}. From this baseline phase function, we find that 176P exhibits a mean photometric excess of {approx}30% during its active period, implying an approximate total coma dust mass of M{sub d} {approx} (7.2 {+-} 3.6) x 10{sup 4} kg. From inactive data obtained in early 2007, we find a rotation period of P{sub rot} = 22.23 {+-} 0.01 hr and a peak-to-trough photometric range of {Delta}m {approx} 0.7 mag. Phasing our photometric data from 176P's 2005 active period to this rotation period, we find that the nucleus exhibits a significantly smaller photometric range than in 2007 that cannot be accounted for by coma damping effects, and as such, are attributed by us to viewing geometry effects. A detailed analysis of these geometric effects showed that 176P is likely to be a highly elongated object with an axis ratio of 1.8 < b/a < 2.1, an orbital obliquity of {epsilon} {approx} 60{sup 0}, and a solstice position at a true anomaly of {nu}{sub o} = 20{sup 0} {+-} 20{sup 0}. Numerical modeling of 176P's dust emission found that its activity can only be reproduced by asymmetric dust emission, such as a cometary jet. We find plausible fits to our observations using models assuming {approx}10 {mu}m dust particles

  14. Transfer of Physical and Hydraulic Properties Databases to the Hanford Environmental Information System - PNNL Remediation Decision Support Project, Task 1, Activity 6

    SciTech Connect (OSTI)

    Rockhold, Mark L.; Middleton, Lisa A.

    2009-03-31

    This report documents the requirements for transferring physical and hydraulic property data compiled by PNNL into the Hanford Environmental Information System (HEIS). The Remediation Decision Support (RDS) Project is managed by Pacific Northwest National Laboratory (PNNL) to support Hanford Site waste management and remedial action decisions by the U.S. Department of Energy and one of their current site contractors - CH2M-Hill Plateau Remediation Company (CHPRC). The objective of Task 1, Activity 6 of the RDS project is to compile all available physical and hydraulic property data for sediments from the Hanford Site, to port these data into the Hanford Environmental Information System (HEIS), and to make the data web-accessible to anyone on the Hanford Local Area Network via the so-called Virtual Library.1 These physical and hydraulic property data are used to estimate parameters for analytical and numerical flow and transport models that are used for site risk assessments and evaluation of remedial action alternatives. In past years efforts were made by RDS project staff to compile all available physical and hydraulic property data for Hanford sediments and to transfer these data into SoilVision{reg_sign}, a commercial geotechnical software package designed for storing, analyzing, and manipulating soils data. Although SoilVision{reg_sign} has proven to be useful, its access and use restrictions have been recognized as a limitation to the effective use of the physical and hydraulic property databases by the broader group of potential users involved in Hanford waste site issues. In order to make these data more widely available and useable, a decision was made to port them to HEIS and to make them web-accessible via a Virtual Library module. In FY08 the original objectives of this activity on the RDS project were to: (1) ensure traceability and defensibility of all physical and hydraulic property data currently residing in the SoilVision{reg_sign} database

  15. Investigation of the physical properties of the tetragonal CeMAl4Si2 (M = Rh, Ir, Pt) compounds

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ghimire, N. J.; Ronning, F.; Williams, D. J.; Scott, B. L.; Luo, Yongkang; Thompson, J. D.; Bauer, E. D.

    2014-12-15

    The synthesis, crystal structure and physical properties studied by means of x-ray diffraction, magnetic, thermal and transport measurements of CeMAl4Si2 (M = Rh, Ir, Pt) are reported, along with the electronic structure calculations for LaMAl4Si2 (M = Rh, Ir, Pt). These materials adopt a tetragonal crystal structure (space group P4/mmm) comprised of BaAl4 blocks, separated by MAl2 units, stacked along the c-axis. Both CeRhAl4Si2 and CeIrAl4Si2 order antiferromagnetically below TN1 = 14 and 16 K, respectively, and undergo a second antiferromagnetic transitition at lower temperature (TN2 = 9 and 14 K, respectively). CePtAl4Si2 orders ferromagnetically below TC = 3 Kmore » with an ordered moment of μsat = 0.8 μB for a magnetic field applied perpendicular to the c-axis. Electronic structure calculations reveal quasi-2D character of the Fermi surface.« less

  16. CONSTRAINTS ON THE PHYSICAL PROPERTIES OF MAIN BELT COMET P/2013 R3 FROM ITS BREAKUP EVENT

    SciTech Connect (OSTI)

    Hirabayashi, Masatoshi; Snchez, Diego Paul; Gabriel, Travis; Scheeres, Daniel J.

    2014-07-01

    Jewitt etal. recently reported that main belt comet P/2013 R3 experienced a breakup, probably due to rotational disruption, with its components separating on mutually hyperbolic orbits. We propose a technique for constraining physical properties of the proto-body, especially the initial spin period and cohesive strength, as a function of the body's estimated size and density. The breakup conditions are developed by combining mutual orbit dynamics of the smaller components and the failure condition of the proto-body. Given a proto-body with a bulk density ranging from 1000kgm{sup 3} to 1500kgm{sup 3} (a typical range of the bulk density of C-type asteroids), we obtain possible values of the cohesive strength (40-210Pa) and the initial spin state (0.48-1.9hr). From this result, we conclude that although the proto-body could have been a rubble pile, it was likely spinning beyond its gravitational binding limit and would have needed cohesive strength to hold itself together. Additional observations of P/2013 R3 will enable stronger constraints on this event, and the present technique will be able to give more precise estimates of its internal structure.

  17. Combined effects of post-growth thermal treatment and chemical substitution on physical properties of CaFe2As2

    SciTech Connect (OSTI)

    Ran, Sheng

    2014-12-01

    This thesis summarizes experimental work using process of postgrowth thermal treatment and chemical substitution as tuning parameters in the study of physical properties of CaFe2As2. Details of sample preparation and characterization are given as well as various phase diagrams.

  18. Plasma Physics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    plasma physics Plasma Physics Almost all of the observable matter in the universe is in the plasma state. Formed at high temperatures, plasmas consist of freely moving ions and free electrons. They are often called the "fourth state of matter" because their unique physical properties distinguish them from solids, liquids and gases. Plasma densities and temperatures vary widely, from the cold gases of interstellar space to the extraordinarily hot, dense cores of stars and inside a

  19. Effect of AlN buffer layer properties on the morphology and polarity of GaN nanowires grown by molecular beam epitaxy

    SciTech Connect (OSTI)

    Brubaker, Matt D.; Rourke, Devin M.; Sanford, Norman A.; Bertness, Kris A.; Bright, Victor M.

    2011-09-01

    Low-temperature AlN buffer layers grown via plasma-assisted molecular beam epitaxy on Si (111) were found to significantly affect the subsequent growth morphology of GaN nanowires. The AlN buffer layers exhibited nanowire-like columnar protrusions, with their size, shape, and tilt determined by the AlN V/III flux ratio. GaN nanowires were frequently observed to adopt the structural characteristics of the underlying AlN columns, including the size and the degree of tilt. Piezoresponse force microscopy and polarity-sensitive etching indicate that the AlN films and the protruding columns have a mixed crystallographic polarity. Convergent beam electron diffraction indicates that GaN nanowires are Ga-polar, suggesting that Al-polar columns are nanowire nucleation sites for Ga-polar nanowires. GaN nanowires of low density could be grown on AlN buffers that were predominantly N-polar with isolated Al-polar columns, indicating a high growth rate for Ga-polar nanowires and suppressed growth of N-polar nanowires under typical growth conditions. AlN buffer layers grown under slightly N-rich conditions (V/III flux ratio = 1.0 to 1.3) were found to provide a favorable growth surface for low-density, coalescence-free nanowires.

  20. The role of galaxy interaction in the SFR-M {sub *} relation: characterizing morphological properties of Herschel-selected galaxies at 0.2 < z < 1.5

    SciTech Connect (OSTI)

    Hung, Chao-Ling; Sanders, D. B.; Casey, C. M.; Lee, N.; Barnes, J. E.; Koss, M.; Larson, K. L.; Lockhart, K.; Man, A. W. S.; Mann, A. W.; Capak, P.; Kartaltepe, J. S.; Le Floc'h, E.; Riguccini, L.; Scoville, N.; Symeonidis, M.

    2013-12-01

    Galaxy interactions/mergers have been shown to dominate the population of IR-luminous galaxies (L {sub IR} ≳ 10{sup 11.6} L {sub ☉}) in the local universe (z ≲ 0.25). Recent studies based on the relation between galaxies' star formation rates and stellar mass (the SFR-M {sub *} relation or the {sup g}alaxy main sequence{sup )} have suggested that galaxy interaction/mergers may only become significant when galaxies fall well above the galaxy main sequence. Since the typical SFR at a given M {sub *} increases with redshift, the existence of the galaxy main sequence implies that massive, IR-luminous galaxies at high z may not necessarily be driven by galaxy interactions. We examine the role of galaxy interactions in the SFR-M {sub *} relation by carrying out a morphological analysis of 2084 Herschel-selected galaxies at 0.2 < z < 1.5 in the COSMOS field. Using a detailed visual classification scheme, we show that the fraction of 'disk galaxies' decreases and the fraction of 'irregular' galaxies increases systematically with increasing L {sub IR} out to z ≲ 1.5 and z ≲ 1.0, respectively. At L {sub IR} >10{sup 11.5} L {sub ☉}, ≳ 50% of the objects show evident features of strongly interacting/merger systems, where this percentage is similar to the studies of local IR-luminous galaxies. The fraction of interacting/merger systems also systematically increases with the deviation from the SFR-M {sub *} relation, supporting the view that galaxies falling above the main sequence are more dominated by mergers than the main-sequence galaxies. Meanwhile, we find that ≳ 18% of massive IR-luminous 'main-sequence galaxies' are classified as interacting systems, where this population may not evolve through the evolutionary track predicted by a simple gas exhaustion model.

  1. PHYSICAL PROPERTIES, STAR FORMATION, AND ACTIVE GALACTIC NUCLEUS ACTIVITY IN BALMER BREAK GALAXIES AT 0 < z < 1

    SciTech Connect (OSTI)

    Diaz Tello, J.; Donzelli, C.; Padilla, N.; Fujishiro, N.; Yoshikawa, T.; Hanami, H.; Hatsukade, B.

    2013-07-01

    We present a spectroscopic study with the derivation of the physical properties of 37 Balmer break galaxies, which have the necessary lines to locate them in star-forming-active galactic nuclei (AGNs) diagnostic diagrams. These galaxies span a redshift range from 0.045 to 0.93 and are somewhat less massive than similar samples of previous works. The studied sample has multiwavelength photometric data coverage from the ultraviolet to mid-infrared (MIR) Spitzer bands. We investigate the connection between star formation and AGN activity via optical, mass-excitation (MEx), and MIR diagnostic diagrams. Through optical diagrams, 31 (84%) star-forming galaxies, two (5%) composite galaxies, and three (8%) AGNs were classified, whereas from the MEx diagram only one galaxy was classified as AGN. A total of 19 galaxies have photometry available in all the IRAC/Spitzer bands. Of these, three AGN candidates were not classified as AGN in the optical diagrams, suggesting they are dusty/obscured AGNs, or that nuclear star formation has diluted their contributions. By fitting the spectral energy distribution of the galaxies, we derived the stellar masses, dust reddening E(B - V), ages, and UV star formation rates (SFRs). Furthermore, the relationship between SFR surface density ({Sigma}{sub SFR}) and stellar mass surface density per time unit ({Sigma}{sub M{sub */{tau}}}) as a function of redshift was investigated using the [O II] {lambda}3727, 3729, H{alpha} {lambda}6563 luminosities, which revealed that both quantities are larger for higher redshift galaxies. We also studied the SFR and specific SFR (SSFR) versus stellar mass and color relations, with the more massive galaxies having higher SFR values but lower SSFR values than less massive galaxies. These results are consistent with previous ones showing that, at a given mass, high-redshift galaxies have on average larger SFR and SSFR values than low-redshift galaxies. Finally, bluer galaxies have larger SSFR values than redder

  2. Thermo-Physical Properties and Equilibrium Vapor-Composition of Lithium Fluoride-Beryllium Fluoride (2LiF/BeF{sub 2}) Molten Salt

    SciTech Connect (OSTI)

    Zaghloul, Mofreh R.; Sze, D.K.; Raffray, A. Rene

    2003-09-15

    An assessment of Flibe thermo-physical properties relevant to the prompt x-rays ablation of the liquid wall is presented with emphasis given to the equilibrium vapor composition and vapor pressure. The available data sets for Flibe thermo-physical properties, which cover a very narrow range of temperature have been extended and adjusted to cover the whole range of the liquid phase and to assure consistency with the estimated critical constants. Investigation of the equilibrium vapor composition showed a contradiction with previously published results regarding the stability of the mixed dimmer LiBeF{sub 3}. New results for the vapor composition and total vapor pressure of Flibe also have been presented, compared to previous results, and used to calculate the temperature-dependent latent heat of vaporization.

  3. A short note on physical properties to irradiated nuclear fuel by means of X-ray diffraction and neutron scattering techniques

    SciTech Connect (OSTI)

    Abdullah, Yusof Husain, Hishamuddin; Hak, Cik Rohaida Che; Alias, Nor Hayati; Yusof, Mohd Reusmaazran; Kasim, Norasiah Ab; Zali, Nurazila Mat; Mohamed, Abdul Aziz

    2015-04-29

    For nuclear reactor applications, understanding the evolution of the fuel materials microstructure during irradiation are of great importance. This paper reviews the physical properties of irradiated nuclear fuel analysis which are considered to be of most importance in determining the performance behavior of fuel. X-rays diffraction was recognize as important tool to investigate the phase identification while neutron scattering analyses the interaction between uranium and other materials and also investigation of the defect structure.

  4. Status Report on Transfer of Physical and Hydraulic Properties Databases to the Hanford Environmental Information System - PNNL Remediation Decision Support Project, Task 1, Activity 6

    SciTech Connect (OSTI)

    Rockhold, Mark L.; Middleton, Lisa A.; Cantrell, Kirk J.

    2009-06-30

    This document provides a status report on efforts to transfer physical and hydraulic property data from PNNL to CHPRC for incorporation into HEIS. The Remediation Decision Support (RDS) Project is managed by Pacific Northwest National Laboratory (PNNL) to support Hanford Site waste management and remedial action decisions by the U.S. Department of Energy and their contractors. The objective of Task 1, Activity 6 of the RDS project is to compile all available physical and hydraulic property data for sediments from the Hanford Site, to port these data into the Hanford Environmental Information System (HEIS), and to make the data web-accessible to anyone on the Hanford Local Area Network via the so-called Virtual Library. These physical and hydraulic property data are used to estimate parameters for analytical and numerical flow and transport models that are used for site risk assessments and evaluation of remedial action alternatives. In past years efforts were made by RDS project staff to compile all available physical and hydraulic property data for Hanford sediments and to transfer these data into SoilVision{reg_sign}, a commercial geotechnical software package designed for storing, analyzing, and manipulating soils data. Although SoilVision{reg_sign} has proven to be useful, its access and use restrictions have been recognized as a limitation to the effective use of the physical and hydraulic property databases by the broader group of potential users involved in Hanford waste site issues. In order to make these data more widely available and useable, a decision was made to port them to HEIS and to make them web-accessible via a Virtual Library module. In FY08 the original objectives of this activity on the RDS project were to: (1) ensure traceability and defensibility of all physical and hydraulic property data currently residing in the SoilVision{reg_sign} database maintained by PNNL, (2) transfer the physical and hydraulic property data from the Microsoft

  5. Polymer/organosilica nanocomposites based on polyimide with benzimidazole linkages and reactive organoclay containing isoleucine amino acid: Synthesis, characterization and morphology properties

    SciTech Connect (OSTI)

    Mallakpour, Shadpour; Nanotechnology and Advanced Materials Institute, Isfahan University of Technology, Isfahan 84156-83111, Islamic Republic of Iran ; Dinari, Mohammad

    2012-09-15

    Highlights: ► A reactive organoclay was formed using L-isoleucine amino acid as a swelling agent. ► Polyimide was synthesized from benzimidazole diamine and pyromellitic dianhydride. ► Imide and benzimidazole groups assured the thermal stability of the nanocomposites. ► Nanocomposite films were prepared by an in situ polymerization reaction. ► The TEM micrographs of nanocomposites revealed well-exfoliated structures. -- Abstract: Polyimide–silica nanocomposites are attractive hybrid architectures that possess excellent mechanical, thermal and chemical properties. But, the dispersion of inorganic domains in the polymer matrix and the compatibility between the organic and inorganic phases are critical factors in these hybrid systems. In this investigation, a reactive organoclay was prepared via ion exchange reaction between protonated form of difunctional L-isoleucine amino acid as a swelling agent and Cloisite Na{sup +} montmorillonite. Amine functional groups of this swelling agent formed an ionic bond with the negatively charged silicates, whereas the remaining acid functional groups were available for further interaction with polymer chains. Then organo-soluble polyimide (PI) have been successfully synthesized from the reaction of 2-(3,5-diaminophenyl)-benzimidazole and pyromellitic dianhydride in N,N-dimethylacetamide. Finally, PI/organoclay nanocomposite films enclosing 1%, 3%, 5%, 7% and 10% of synthesized organoclay were successfully prepared by an in situ polymerization reaction through thermal imidization. The synthesized hybrid materials were subsequently characterized by Fourier transform infrared spectroscopy, X-ray diffraction, electron microscopy, and thermogravimetric analysis techniques. The PI/organoclay nanocomposite films have good optical transparencies and the mechanical properties were substantially improved by the incorporation of the reactive organoclay.

  6. Physical and chemical properties of dust produced in a N{sub 2}-CH{sub 4} RF plasma discharge

    SciTech Connect (OSTI)

    Ouni, F.; Alcouffe, G.; Szopa, C.; Carrasco, N.; Cernogora, G.; Adande, G.; Thissen, R.; Quirico, E.; Brissaud, O.; Schmitz-Afonso, I.; Laprevote, O.

    2008-09-07

    Titan's atmospheric chemistry is simulated using a Capacitively Coupled Plasma discharge produced in a N{sub 2}-CH{sub 4} mixture. The produced solid particles are analysed ex-situ. Chemical properties are deduced from: elemental composition, FTIR and LTQ-Orbitrap mass spectrometer. Optical properties are deduced from reflectivity in visible and IR range.

  7. Property

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ER-B-98-07 AUDIT REPORT PERSONAL PROPERTY AT THE OAK RIDGE OPERATIONS OFFICE AND THE OFFICE OF SCIENTIFIC AND TECHNICAL INFORMATION U.S. DEPARTMENT OF ENERGY OFFICE OF INSPECTOR GENERAL OFFICE OF AUDIT SERVICES APRIL 1998 Page 10 DEPARTMENT OF ENERGY Washington, DC 20585 April 6, 1998 MEMORANDUM FOR THE MANAGER, OAK RIDGE OPERATIONS OFFICE AND THE DIRECTOR, OFFICE OF SCIENTIFIC AND TECHNICAL INFORMATION FROM: Terry L. Brendlinger Eastern Regional Audit Office Office of Inspector General SUBJECT:

  8. Effect of carbonization temperature on the physical and electrochemical properties of supercapacitor electrode from fibers of oil palm empty fruit bunches

    SciTech Connect (OSTI)

    Ishak, M. M.; Deraman, M. Talib, I. A.; Basri, N. H.; Omar, R.; Nor, N. S. M.; Dolah, B. N. M.; Awitdrus,; Farma, R.; Taer, E.

    2015-04-16

    Self-adhesive carbon grains (SACG) was prepared from fibers of oil palm empty fruit bunches. The SACG green monoliths were carbonized in N{sub 2} environment at 400, 500, 600 and 700°C to produce carbon monoliths labeled as CM1, CM2, CM3 and CM4 respectively. The CMs were activated in CO{sub 2} surrounding at 800°C for 1 hour to produce activated carbon monolith electrodes (ACM1, ACM2, ACM3 and ACM4). The physical properties of the CMs and ACMs were investigated using X-ray diffraction, field emission scanning electron microscopy (FESEM) and N{sub 2} adsorption-desorption isotherm techniques. ACMs were used as electrode to fabricate symmetry supercapacitor cells and the cells’ performances were investigated using electrochemical impedance spectroscopy (EIS), cyclic voltammetry (CV) and galvanostatic charge-discharge (GCD) standard techniques. In this paper we report the physical and electrochemical properties of the ACM electrodes by analyzing the influence of the carbonization temperature on these properties.

  9. Gogny, D; Schunck, N 73 NUCLEAR PHYSICS AND RADIATION PHYSICS...

    Office of Scientific and Technical Information (OSTI)

    of low energy fission: fragment properties Younes, W; Gogny, D; Schunck, N 73 NUCLEAR PHYSICS AND RADIATION PHYSICS Abstract not provided Lawrence Livermore National Laboratory...

  10. Physical properties of Al{sub x}In{sub 1–x}N thin film alloys sputtered at low temperature

    SciTech Connect (OSTI)

    Besleaga, C.; Galca, A. C. Miclea, C. F.; Mercioniu, I.; Enculescu, M.; Stan, G. E.; Mateescu, A. O.; Dumitru, V.; Costea, S.

    2014-10-21

    In this paper, we report on the structural, optical, and electrical properties of a wide compositional range of Al{sub x}In{sub 1–x}N thin layers deposited on glass and polyethylene terephthalate substrates. Al{sub x}In{sub 1–x}N layers of controlled composition were obtained by a simple reactive magnetron co-sputtering protocol, using a single aluminium target with indium insets, by varying the Al/In target surface area ratio, and the composition of the deposition atmosphere. The relevant physical properties were investigated and discussed. It is shown that the texture of the thin films is dependent on the cation ratio, while the bowing parameters of lattice constants and band gap values are larger than those of epitaxial layers.

  11. Physical Protection

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2009-07-23

    This Manual establishes requirements for the physical protection of interests under the U.S. Department of Energys (DOEs) purview ranging from facilities, buildings, Government property, and employees to national security interests such as classified information, special nuclear material (SNM), and nuclear weapons. Cancels Section A of DOE M 470.4-2 Chg 1. Canceled by DOE O 473.3.

  12. Derivation of physical and optical properties of mid-latitude cirrus ice crystals for a size-resolved cloud microphysics model

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Fridlind, Ann M.; Atlas, Rachel; van Diedenhoven, Bastiaan; Um, Junshik; McFarquhar, Greg M.; Ackerman, Andrew S.; Moyer, Elisabeth J.; Lawson, R. Paul

    2016-06-10

    Single-crystal images collected in mid-latitude cirrus are analyzed to provide internally consistent ice physical and optical properties for a size-resolved cloud microphysics model, including single-particle mass, projected area, fall speed, capacitance, single-scattering albedo, and asymmetry parameter. Using measurements gathered during two flights through a widespread synoptic cirrus shield, bullet rosettes are found to be the dominant identifiable habit among ice crystals with maximum dimension (Dmax) greater than 100 µm. Properties are therefore first derived for bullet rosettes based on measurements of arm lengths and widths, then for aggregates of bullet rosettes and for unclassified (irregular) crystals. Derived bullet rosette massesmore » are substantially greater than reported in existing literature, whereas measured projected areas are similar or lesser, resulting in factors of 1.5–2 greater fall speeds, and, in the limit of large Dmax, near-infrared single-scattering albedo and asymmetry parameter (g) greater by  ∼  0.2 and 0.05, respectively. A model that includes commonly imaged side plane growth on bullet rosettes exhibits relatively little difference in microphysical and optical properties aside from  ∼ 0.05 increase in mid-visible g primarily attributable to plate aspect ratio. In parcel simulations, ice size distribution, and g are sensitive to assumed ice properties.« less

  13. Derivation of physical and optical properties of mid-latitude cirrus ice crystals for a size-resolved cloud microphysics model

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Fridlind, Ann M.; Atlas, Rachel; van Diedenhoven, Bastiaan; Um, Junshik; McFarquhar, Greg M.; Ackerman, Andrew S.; Moyer, Elisabeth J.; Lawson, R. Paul

    2016-06-10

    Single-crystal images collected in mid-latitude cirrus are analyzed to provide internally consistent ice physical and optical properties for a size-resolved cloud microphysics model, including single-particle mass, projected area, fall speed, capacitance, single-scattering albedo, and asymmetry parameter. Using measurements gathered during two flights through a widespread synoptic cirrus shield, bullet rosettes are found to be the dominant identifiable habit among ice crystals with maximum dimension (Dmax) greater than 100 µm. Properties are therefore first derived for bullet rosettes based on measurements of arm lengths and widths, then for aggregates of bullet rosettes and for unclassified (irregular) crystals. Derived bullet rosette massesmore » are substantially greater than reported in existing literature, whereas measured projected areas are similar or lesser, resulting in factors of 1.5–2 greater fall speeds, and, in the limit of large Dmax, near-infrared single-scattering albedo and asymmetry parameter (g) greater by ~0.2 and 0.05, respectively. Furthermore, a model that includes commonly imaged side plane growth on bullet rosettes exhibits relatively little difference in microphysical and optical properties aside from ~0.05 increase in mid-visible g primarily attributable to plate aspect ratio. In parcel simulations, ice size distribution, and g are sensitive to assumed ice properties.« less

  14. High Dose Neutron Irradiation of Hi-Nicalon Type S Silicon Carbide Composites, Part 2. Mechanical and Physical Properties

    SciTech Connect (OSTI)

    Katoh, Yutai; Nozawa, Takashi; Shih, Chunghao Phillip; Ozawa, Kazumi; Koyanagi, Takaaki; Porter, Wallace D; Snead, Lance Lewis

    2015-01-07

    Nuclear-grade silicon carbide (SiC) composite material was examined for mechanical and thermophysical properties following high-dose neutron irradiation in the High Flux Isotope Reactor at a temperature range of 573–1073 K. Likewise, the material was chemical vapor-infiltrated SiC-matrix composite with a two-dimensional satin weave Hi-Nicalon Type S SiC fiber reinforcement and a multilayered pyrocarbon/SiC interphase. Moderate (1073 K) to very severe (573 K) degradation in mechanical properties was found after irradiation to >70 dpa, whereas no evidence was found for progressive evolution in swelling and thermal conductivity. The swelling was found to recover upon annealing beyond the irradiation temperature, indicating the irradiation temperature, but only to a limited extent. Moreover, the observed strength degradation is attributed primarily to fiber damage for all irradiation temperatures, particularly a combination of severe fiber degradation and likely interphase damage at relatively low irradiation temperatures.

  15. Effect of low and high storage temperatures on head space gas concentrations and physical properties of wood pellets

    SciTech Connect (OSTI)

    Jaya Shankar Tumuluru; Shahab Sokhansanj; C. Jim Lim; Tony Bi; Xingya Kuang; Staffan Melin

    2013-11-01

    Headspace gas concentrations and wood pellet properties were studied in sealed glass canisters at 5–40 degrees C storage temperatures. CO2 and CO concentrations at 5, 10, 20 and 40 degrees C at the end of 23–28 days of storage were 1600 and 200, 4700 and 1200, and 31 200 and 15 800 parts per million by volume (ppmv) respectively. Corresponding O2 concentration was about 19•49, 19•20, 18•0 and 2•07% respectively. Non-linear regression equations adequately described the gas concentrations in the storage container as a function of time. Safe level estimation functions developed were linear for O2 and logarithmic for CO and CO2 concentrations. Measured pellet properties moisture, length, diameter, unit, bulk and tapped density, durability, calorific value, ash content and per cent fines were in the range of 4•6–5•02%, 14–15 mm, 6•4–6•5 mm, 1125–1175 kg m-3, 750–770 kg m-3, 825–840 kg m-3, 73–74%, 18•32–18•78 MJ kg-1, 0•65–0•74% and 0•13–0•15%. Durability values of pellets decreased by 13% at 40 degrees C storage temperature and other properties changed marginally.

  16. Magnetic order and heavy fermion behavior in CePd{sub 1+x}Al{sub 6-x}: Synthesis, structure, and physical properties

    SciTech Connect (OSTI)

    Tobash, Paul H., E-mail: ptobash@lanl.go [Materials Physics and Application Division, MPA-10, Los Alamos National Laboratory, Los Alamos, NM 87545 (United States); Department of Chemistry and Biochemistry, University of Delaware, Newark, DE 19716 (United States); Ronning, Filip; Thompson, J.D. [Materials Physics and Application Division, MPA-10, Los Alamos National Laboratory, Los Alamos, NM 87545 (United States); Bobev, Svilen [Department of Chemistry and Biochemistry, University of Delaware, Newark, DE 19716 (United States); Bauer, Eric D. [Materials Physics and Application Division, MPA-10, Los Alamos National Laboratory, Los Alamos, NM 87545 (United States)

    2010-03-15

    The physical properties including magnetic susceptibility, specific heat, and electrical resistivity of single crystals are reported for the compound CePd{sub 1+x}Al{sub 6-x} (x=0.5) which crystallizes in the tetragonal SrAu{sub 2}Ga{sub 5}-type structure (space group P4/mmm). The compound was grown from an excess of molten Al flux from the respective elements and the crystal structure was established from single-crystal X-ray diffraction. Anomalies in the low temperature specific heat C{sub p}(T) and electrical resistivity rho(T) show that the compound undergoes ferromagnetic order at T{sub C}=2.8 K. In the ordered state, CePd{sub 1.5}Al{sub 5.5} displays heavy fermion behavior with a Sommerfeld coefficient of ca. 500 mJ/mol-K{sup 2}. - Graphical abstract: The compound CePd{sub 1+x}Al{sub 6-x} (x=0.5) has been synthesized and structurally characterized by single-crystal X-ray diffraction. The measured physical properties of temperature and field dependent magnetic susceptibility, specific heat, and electrical resistivity suggests that the compound undergoes ferromagnetic order at ca. 2.8 K and further exhibits relatively heavy fermion behavior with a Sommerfeld coefficient of 500 mJ/mol-K2.

  17. Microstructural and optical properties of nanocrystalline ZnO deposited onto vertically aligned carbon nanotubes by physical vapor deposition

    SciTech Connect (OSTI)

    Borkar, Tushar; Chang, Won Seok; Hwang, Jun Yeon; Shepherd, Nigel D.; Banerjee, Rajarshi

    2012-10-15

    Nanocrystalline ZnO films with thicknesses of 5 nm, 10 nm, 20 nm, and 50 nm were deposited via magnetron sputtering onto the surface of vertically aligned multi-walled carbon nanotubes (MWCNTs). The ZnO/CNTs heterostructures were characterized by scanning electron microscopy, high resolution transmission electron microscopy, and X-ray diffraction studies. No structural degradation of the CNTs was observed and photoluminescence (PL) measurements of the nanostructured ZnO layers show that the optical properties of these films are typical of ZnO deposited at low temperatures. The results indicate that magnetron sputtering is a viable technique for growing heterostructures and depositing functional layers onto CNTs.

  18. High Dose Neutron Irradiation of Hi-Nicalon Type S Silicon Carbide Composites, Part 2. Mechanical and Physical Properties

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Katoh, Yutai; Nozawa, Takashi; Shih, Chunghao Phillip; Ozawa, Kazumi; Koyanagi, Takaaki; Porter, Wallace D; Snead, Lance Lewis

    2015-01-07

    Nuclear-grade silicon carbide (SiC) composite material was examined for mechanical and thermophysical properties following high-dose neutron irradiation in the High Flux Isotope Reactor at a temperature range of 573–1073 K. Likewise, the material was chemical vapor-infiltrated SiC-matrix composite with a two-dimensional satin weave Hi-Nicalon Type S SiC fiber reinforcement and a multilayered pyrocarbon/SiC interphase. Moderate (1073 K) to very severe (573 K) degradation in mechanical properties was found after irradiation to >70 dpa, whereas no evidence was found for progressive evolution in swelling and thermal conductivity. The swelling was found to recover upon annealing beyond the irradiation temperature, indicating themore » irradiation temperature, but only to a limited extent. Moreover, the observed strength degradation is attributed primarily to fiber damage for all irradiation temperatures, particularly a combination of severe fiber degradation and likely interphase damage at relatively low irradiation temperatures.« less

  19. GALAXIES IN X-RAY GROUPS. III. SATELLITE COLOR AND MORPHOLOGY TRANSFORMATIONS

    SciTech Connect (OSTI)

    George, Matthew R.; Ma, Chung-Pei; Bundy, Kevin; Leauthaud, Alexie; Vulcani, Benedetta; Tinker, Jeremy; Wechsler, Risa H.; Finoguenov, Alexis

    2013-06-20

    While the star formation rates and morphologies of galaxies have long been known to correlate with their local environment, the process by which these correlations are generated is not well understood. Galaxy groups are thought to play an important role in shaping the physical properties of galaxies before entering massive clusters at low redshift, and transformations of satellite galaxies likely dominate the buildup of local environmental correlations. To illuminate the physical processes that shape galaxy evolution in dense environments, we study a sample of 116 X-ray selected galaxy groups at z = 0.2-1 with halo masses of 10{sup 13}-10{sup 14} M{sub Sun} and centroids determined with weak lensing. We analyze morphologies based on Hubble Space Telescope imaging and colors determined from 31 photometric bands for a stellar mass-limited population of 923 satellite galaxies and a comparison sample of 16,644 field galaxies. Controlling for variations in stellar mass across environments, we find significant trends in the colors and morphologies of satellite galaxies with group-centric distance and across cosmic time. Specifically at low stellar mass (log (M{sub *}/M{sub Sun }) = 9.8-10.3), the fraction of disk-dominated star-forming galaxies declines from >50% among field galaxies to <20% among satellites near the centers of groups. This decline is accompanied by a rise in quenched galaxies with intermediate bulge+disk morphologies, and only a weak increase in red bulge-dominated systems. These results show that both color and morphology are influenced by a galaxy's location within a group halo. We suggest that strangulation and disk fading alone are insufficient to explain the observed morphological dependence on environment, and that galaxy mergers or close tidal encounters must play a role in building up the population of quenched galaxies with bulges seen in dense environments at low redshift.

  20. Matrix-filler interfaces and physical properties of metal matrix composites with negative thermal expansion manganese nitride

    SciTech Connect (OSTI)

    Takenaka, Koshi; Kuzuoka, Kota; Sugimoto, Norihiro

    2015-08-28

    Copper matrix composites containing antiperovskite manganese nitrides with negative thermal expansion (NTE) were formed using pulsed electric current sintering. Energy dispersive X-ray spectroscopy revealed that the chemically reacted region extends over 10 μm around the matrix–filler interfaces. The small-size filler was chemically deteriorated during formation of composites and it lost the NTE property. Therefore, we produced the composites using only the nitride particles having diameter larger than 50 μm. The large-size filler effectively suppressed the thermal expansion of copper and improved the conductivity of the composites to the level of pure aluminum. The present composites, having high thermal conductivity and low thermal expansion, are suitable for practical applications such as a heat radiation substrate for semiconductor devices.

  1. Optical and Physical Properties from Primary On-Road Vehicle ParticleEmissions And Their Implications for Climate Change

    SciTech Connect (OSTI)

    Strawa, A.W.; Kirchstetter, T.W.; Hallar, A.G.; Ban-Weiss, G.A.; McLaughlin, J.P.; Harley, R.A.; Lunden, M.M.

    2009-01-23

    During the summers of 2004 and 2006, extinction and scattering coefficients of particle emissions inside a San Francisco Bay Area roadway tunnel were measured using a combined cavity ring-down and nephelometer instrument. Particle size distributions and humidification were also measured, as well as several gas phase species. Vehicles in the tunnel traveled up a 4% grade at a speed of approximately 60 km h{sup -1}. The traffic situation in the tunnel allows the apportionment of emission factors between light duty gasoline vehicles and diesel trucks. Cross-section emission factors for optical properties were determined for the apportioned vehicles to be consistent with gas phase and particulate matter emission factors. The absorption emission factor (the absorption cross-section per mass of fuel burned) for diesel trucks (4.4 {+-} 0.79 m{sup 2} kg{sup -1}) was 22 times larger than for light-duty gasoline vehicles (0.20 {+-} 0.05 m{sup 2} kg{sup -1}). The single scattering albedo of particles - which represents the fraction of incident light that is scattered as opposed to absorbed - was 0.2 for diesel trucks and 0.3 for light duty gasoline vehicles. These facts indicate that particulate matter from motor vehicles exerts a positive (i.e., warming) radiative climate forcing. Average particulate mass absorption efficiencies for diesel trucks and light duty gasoline vehicles were 3.14 {+-} 0.88 m{sup 2} g{sub PM}{sup -1} and 2.9 {+-} 1.07 m{sup 2} g{sub PM}{sup -1}, respectively. Particle size distributions and optical properties were insensitive to increases in relative humidity to values in excess of 90%, reinforcing previous findings that freshly emitted motor vehicle particulate matter is hydrophobic.

  2. Effect of UV curing time on physical and electrical properties and reliability of low dielectric constant materials

    SciTech Connect (OSTI)

    Kao, Kai-Chieh; Cheng, Yi-Lung; Chang, Wei-Yuan; Chang, Yu-Min; Leu, Jihperng

    2014-11-01

    This study comprehensively investigates the effect of ultraviolet (UV) curing time on the physical, electrical, and reliability characteristics of porous low-k materials. Following UV irradiation for various periods, the depth profiles of the chemical composition in the low-k dielectrics were homogeneous. Initially, the UV curing process preferentially removed porogen-related CH{sub x} groups and then modified Si-CH{sub 3} and cage Si-O bonds to form network Si-O bonds. The lowest dielectric constant (k value) was thus obtained at a UV curing time of 300?s. Additionally, UV irradiation made porogen-based low-k materials hydrophobic and to an extent that increased with UV curing time. With a short curing time (<300?s), porogen was not completely removed and the residues degraded reliability performance. A long curing time (>300?s) was associated with improved mechanical strength, electrical performance, and reliability of the low-k materials, but none of these increased linearly with UV curing time. Therefore, UV curing is necessary, but the process time must be optimized for porous low-k materials on back-end of line integration in 45?nm or below technology nodes.

  3. High moisture corn stover pelleting in a flat die pellet mill fitted with a 6 mm die: physical properties and specific energy consumption

    SciTech Connect (OSTI)

    Tumuluru, Jaya Shankar

    2015-06-15

    The quality and specific energy consumption (SEC) of the biomass pellets produced depend upon pelleting process conditions. The present study includes understanding the effect of feedstock moisture in the range of 28–38% (wet basis [w.b.]) and preheating in the range of 30–110°C at two die speeds of 40 and 60 Hz on the physical properties and SEC. A flat die pellet mill fitted with a 6 mm die was used in the present study. The physical properties of pellets such as moisture content, unit, bulk and tapped density, durability, and expansion ratio and SEC of the pelleting process are measured. The results indicate that the pellets produced have durability values in the range of 87–98%, and unit bulk and tapped density in the range of 670–1100, 375–575, and 420–620 kg/m³. Increasing the feedstock moisture content from 33% to 38% (w.b) decreased the unit, bulk and tapped density by about 30–40%. Increasing feedstock moisture content increased the expansion ratio and decreased the density values. A higher feedstock moisture content of 38% (w.b.) and higher preheating temperature of 110°C resulted in lower density and a higher expansion ratio, which can be attributed to flash off of moisture as the material extrudes out of the die. The SEC was in the range of 75–275 kWh/ton. Higher feedstock moisture content of 38% (w.b.) and a lower die speed of 40 Hz increased the SEC, whereas lower to medium preheating temperature (30–70°C), medium feedstock moisture content of 33% (w.b.), and a higher die speed of 60 Hz minimized the SEC to <100 kWh/ton.

  4. High moisture corn stover pelleting in a flat die pellet mill fitted with a 6 mm die: physical properties and specific energy consumption

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Tumuluru, Jaya Shankar

    2015-06-15

    The quality and specific energy consumption (SEC) of the biomass pellets produced depend upon pelleting process conditions. The present study includes understanding the effect of feedstock moisture in the range of 28–38% (wet basis [w.b.]) and preheating in the range of 30–110°C at two die speeds of 40 and 60 Hz on the physical properties and SEC. A flat die pellet mill fitted with a 6 mm die was used in the present study. The physical properties of pellets such as moisture content, unit, bulk and tapped density, durability, and expansion ratio and SEC of the pelleting process are measured.more » The results indicate that the pellets produced have durability values in the range of 87–98%, and unit bulk and tapped density in the range of 670–1100, 375–575, and 420–620 kg/m³. Increasing the feedstock moisture content from 33% to 38% (w.b) decreased the unit, bulk and tapped density by about 30–40%. Increasing feedstock moisture content increased the expansion ratio and decreased the density values. A higher feedstock moisture content of 38% (w.b.) and higher preheating temperature of 110°C resulted in lower density and a higher expansion ratio, which can be attributed to flash off of moisture as the material extrudes out of the die. The SEC was in the range of 75–275 kWh/ton. Higher feedstock moisture content of 38% (w.b.) and a lower die speed of 40 Hz increased the SEC, whereas lower to medium preheating temperature (30–70°C), medium feedstock moisture content of 33% (w.b.), and a higher die speed of 60 Hz minimized the SEC to <100 kWh/ton.« less

  5. Gold-rich R3Au7Sn3: Establishing the interdependence between electronic features and physical properties

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Provino, Alessia; Steinberg, Simon; Smetana, Volodymyr; Kulkarni, Ruta; Dhar, Sudesh K.; Manfrinetti, Pietro; Mudring, Anja -Verena

    2015-05-18

    Two new polar intermetallic compounds Y3Au7Sn3 (I) and Gd3Au7Sn3 (II) have been synthesized and their structures have been determined by single crystal X-ray diffraction (P63/m; Z = 2, a = 8.148(1)/8.185(3), and c = 9.394(2)/9.415(3) for I/II, respectively). They can formally be assigned to the Cu10Sn3 type and consist of parallel slabs of Sn centered, edge-sharing trigonal Au6 antiprisms connected through R3 (R = Y, Gd) triangles. Additional Au atoms reside in the centres of trigonal Au6 prisms forming Au@Au6 clusters with Au–Au distances of 2.906–2.960 Å, while the R–R contacts in the R3 groups are considerably larger than themore » sums of their metallic radii. These exclusive structural arrangements provide alluring systems to study the synergism between strongly correlated systems, particularly, those in the structure of (II), and extensive polar intermetallic contacts, which has been inspected by measurements of the magnetic properties, heat capacities and electrical conductivities of both compounds. Gd3Au7Sn3 shows an antiferromagnetic ordering at 13 K, while Y3Au7Sn3 is a Pauli paramagnet and a downward curvature in its electrical resistivity at about 1.9 K points to a superconducting transition. DFT-based band structure calculations on R3Au7Sn3 (R = Y, Gd) account for the results of the conductivity measurements and different spin ordering models of (II) provide conclusive hints about its magnetic structure. As a result, chemical bonding analyses of both compounds indicate that the vast majority of bonding originates from the heteroatomic Au–Gd and Au–Sn interactions, while homoatomic Au–Au bonding is evident within the Au@Au6 clusters.« less

  6. Gold-rich R3Au7Sn3: Establishing the interdependence between electronic features and physical properties

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Provino, Alessia; Steinberg, Simon; Smetana, Volodymyr; Kulkarni, Ruta; Dhar, Sudesh K.; Manfrinetti, Pietro; Mudring, Anja -Verena

    2015-05-18

    Two new polar intermetallic compounds Y3Au7Sn3 (I) and Gd3Au7Sn3 (II) have been synthesized and their structures have been determined by single crystal X-ray diffraction (P63/m; Z = 2, a = 8.148(1)/8.185(3), and c = 9.394(2)/9.415(3) for I/II, respectively). They can formally be assigned to the Cu10Sn3 type and consist of parallel slabs of Sn centered, edge-sharing trigonal Au6 antiprisms connected through R3 (R = Y, Gd) triangles. Additional Au atoms reside in the centres of trigonal Au6 prisms forming Au@Au6 clusters with Au–Au distances of 2.906–2.960 Å, while the R–R contacts in the R3 groups are considerably larger than themore »sums of their metallic radii. These exclusive structural arrangements provide alluring systems to study the synergism between strongly correlated systems, particularly, those in the structure of (II), and extensive polar intermetallic contacts, which has been inspected by measurements of the magnetic properties, heat capacities and electrical conductivities of both compounds. Gd3Au7Sn3 shows an antiferromagnetic ordering at 13 K, while Y3Au7Sn3 is a Pauli paramagnet and a downward curvature in its electrical resistivity at about 1.9 K points to a superconducting transition. DFT-based band structure calculations on R3Au7Sn3 (R = Y, Gd) account for the results of the conductivity measurements and different spin ordering models of (II) provide conclusive hints about its magnetic structure. As a result, chemical bonding analyses of both compounds indicate that the vast majority of bonding originates from the heteroatomic Au–Gd and Au–Sn interactions, while homoatomic Au–Au bonding is evident within the Au@Au6 clusters.« less

  7. THE AVERAGE PHYSICAL PROPERTIES AND STAR FORMATION HISTORIES OF THE UV-BRIGHTEST STAR-FORMING GALAXIES AT z {approx} 3.7

    SciTech Connect (OSTI)

    Lee, Kyoung-Soo; Glikman, Eilat; Dey, Arjun; Reddy, Naveen; Jannuzi, Buell T.; Brown, Michael J. I.; Gonzalez, Anthony H.; Cooper, Michael C.; Fan Xiaohui; Bian Fuyan; Stern, Daniel; Brodwin, Mark; Cooray, Asantha

    2011-06-01

    We investigate the average physical properties and star formation histories (SFHs) of the most UV-luminous star-forming galaxies at z {approx} 3.7. Our results are based on the average spectral energy distributions (SEDs), constructed from stacked optical-to-infrared photometry, of a sample of the 1913 most UV-luminous star-forming galaxies found in 5.3 deg{sup 2} of the NOAO Deep Wide-Field Survey. We find that the shape of the average SED in the rest optical and infrared is fairly constant with UV luminosity, i.e., more UV-luminous galaxies are, on average, also more luminous at longer wavelengths. In the rest UV, however, the spectral slope {beta} ({identical_to} dlogF{sub {lambda}}/dlog{lambda}; measured at 0.13 {mu}m < {lambda}{sub rest} < 0.28 {mu}m) rises steeply with the median UV luminosity from -1.8 at L {approx} L* to -1.2 (L {approx} 4-5L*). We use population synthesis analyses to derive their average physical properties and find that (1) L{sub UV} and thus star formation rates (SFRs) scale closely with stellar mass such that more UV-luminous galaxies are also more massive, (2) the median ages indicate that the stellar populations are relatively young (200-400 Myr) and show little correlation with UV luminosity, and (3) more UV-luminous galaxies are dustier than their less-luminous counterparts, such that L {approx} 4-5L* galaxies are extincted up to A(1600) = 2 mag while L {approx} L* galaxies have A(1600) = 0.7-1.5 mag. We argue that the average SFHs of UV-luminous galaxies are better described by models in which SFR increases with time in order to simultaneously reproduce the tight correlation between the UV-derived SFR and stellar mass and their universally young ages. We demonstrate the potential of measurements of the SFR-M{sub *} relation at multiple redshifts to discriminate between simple models of SFHs. Finally, we discuss the fate of these UV-brightest galaxies in the next 1-2 Gyr and their possible connection to the most massive galaxies at

  8. Mesoscale morphologies in polymer thin films.

    SciTech Connect (OSTI)

    Ramanathan, M.; Darling, S. B. (Center for Nanoscale Materials)

    2011-06-01

    In the midst of an exciting era of polymer nanoscience, where the development of materials and understanding of properties at the nanoscale remain a major R&D endeavor, there are several exciting phenomena that have been reported at the mesoscale (approximately an order of magnitude larger than the nanoscale). In this review article, we focus on mesoscale morphologies in polymer thin films from the viewpoint of origination of structure formation, structure development and the interaction forces that govern these morphologies. Mesoscale morphologies, including dendrites, holes, spherulites, fractals and honeycomb structures have been observed in thin films of homopolymer, copolymer, blends and composites. Following a largely phenomenological level of description, we review the kinetic and thermodynamic aspects of mesostructure formation outlining some of the key mechanisms at play. We also discuss various strategies to direct, limit, or inhibit the appearance of mesostructures in polymer thin films as well as an outlook toward potential areas of growth in this field of research.

  9. Effect of the substrate temperature on the physical properties of molybdenum tri-oxide thin films obtained through the spray pyrolysis technique

    SciTech Connect (OSTI)

    Martinez, H.M.; Torres, J.; Lopez Carreno, L.D.; Rodriguez-Garcia, M.E.

    2013-01-15

    Polycrystalline molybdenum tri-oxide thin films were prepared using the spray pyrolysis technique; a 0.1 M solution of ammonium molybdate tetra-hydrated was used as a precursor. The samples were prepared on Corning glass substrates maintained at temperatures ranging between 423 and 673 K. The samples were characterized through micro Raman, X-ray diffraction, optical transmittance and DC electrical conductivity. The species MoO{sub 3} (H{sub 2}O){sub 2} was found in the sample prepared at a substrate temperature of 423 K. As the substrate temperature rises, the water disappears and the samples crystallize into {alpha}-MoO{sub 3}. The optical gap diminishes as the substrate temperature rises. Two electrical transport mechanisms were found: hopping under 200 K and intrinsic conduction over 200 K. The MoO{sub 3} films' sensitivity was analyzed for CO and H{sub 2}O in the temperature range 160 to 360 K; the results indicate that CO and H{sub 2}O have a reduction character. In all cases, it was found that the sensitivity to CO is lower than that to H{sub 2}O. - Highlights: Black-Right-Pointing-Pointer A low cost technique is used which produces good material. Black-Right-Pointing-Pointer Thin films are prepared using ammonium molybdate tetra hydrated. Black-Right-Pointing-Pointer The control of the physical properties of the samples could be done. Black-Right-Pointing-Pointer A calculation method is proposed to determine the material optical properties. Black-Right-Pointing-Pointer The MoO{sub 3} thin films prepared by spray pyrolysis could be used as gas sensor.

  10. The three-dimensional morphology of growing dendrites

    SciTech Connect (OSTI)

    Gibbs, J. W.; Mohan, K. A.; Gulsoy, E. B.; Shahani, A. J.; Xiao, X.; Bouman, C. A.; De Graef, M.; Voorhees, P. W.

    2015-07-03

    The processes controlling the morphology of dendrites have been of great interest to a wide range of communities, since they are examples of an out-of-equilibrium pattern forming system, there is a clear connection with battery failure processes, and their morphology sets the properties of many metallic alloys. We determine the three-dimensional morphology of free growing metallic dendrites using a novel X-ray tomographic technique that improves the temporal resolution by more than an order of magnitude compared to conventional techniques. These measurements show that the growth morphology of metallic dendrites is surprisingly different from that seen in model systems, the morphology is not self-similar with distance back from the tip, and that this morphology can have an unexpectedly strong influence on solute segregation in castings. These experiments also provide benchmark data that can be used to validate simulations of free dendritic growth.

  11. Resolution of the discrepancy between the variation of the physical properties of Ce1-xYbxCoIn5 single crystals and thin films with Yb composition

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jang, S.; White, B. D.; Lum, I. K.; Kim, H.; Tanatar, M. A.; Straszheim, W. E.; Prozorov, R.; Keiber, T.; Bridges, F.; Shu, L.; et al

    2014-11-18

    The extraordinary electronic phenomena including an Yb valence transition, a change in Fermi surface topology, and suppression of the heavy fermion quantum critical field at a nominal concentration x≈0.2 have been found in the Ce1-xYbxCoIn5 system. These phenomena have no discernable effect on the unconventional superconductivity and normal-state non-Fermi liquid behaviour that occur over a broad range of x up to ~0.8. However, the variation of the coherence temperature T* and the superconducting critical temperature Tc with nominal Yb concentration x for bulk single crystals is much weaker than that of thin films. To determine whether differences in the actualmore » Yb concentration of bulk single crystals and thin film samples might be responsible for these discrepancies, we employed Vegard’s law and the spectroscopically determined values of the valences of Ce and Yb as a function of x to determine the actual composition xact of bulk single crystals. This analysis is supported by energy-dispersive X-ray spectroscopy, wavelength-dispersive X-ray spectroscopy, and transmission X-ray absorption edge spectroscopy measurements. The actual composition xact is found to be about one-third of the nominal concentration x up to x~0.5, and resolves the discrepancy between the variation of the physical properties of Ce1-xYbxCoIn5 single crystals and thin films with Yb concentration.« less

  12. PHYSICAL SCIENCES, Physics Phase

    Office of Scientific and Technical Information (OSTI)

    SCIENCES, Physics Phase competition in trisected superconducting dome I. M. Vishik, 1, 2 M Hashimoto, 3 R.-H. He, 4 W. S. Lee, 1, 2 F. Schmitt, 1, 2 D. H. Lu, 3 R. G. Moore, 1...

  13. Preparation and physical properties of antiperovskite-type compounds CdNCo{sub 3-z}Ni{sub z} (0{<=}z{<=}3)

    SciTech Connect (OSTI)

    He Bing; Dong Cheng; Yang Lihong; Ge Linhui; Chen Hong

    2011-08-15

    A series of CdNCo{sub 3-z}Ni{sub z} (0{<=}z{<=}3) samples were prepared from CdO and metal powders under NH{sub 3} atmosphere at 743 K. The structural and physical properties were investigated by means of X-ray powder diffraction, temperature dependent resistivity and magnetic measurements. X-ray powder diffraction results show that CdNCo{sub 3} is a new ternary nitride with antiperovskite structure, and it can form a complete solid solution series with CdNNi{sub 3}. Both CdNCo{sub 3} and CdNNi{sub 3} samples show metallic temperature dependent resistivity and exhibit a Fermi liquid behavior below 50 K. All samples are ferromagnetic, and their coercivity and remanence decrease as the Ni content increases. The temperature dependence of the magnetization of the CdNCo{sub 3-z}Ni{sub z} samples can be well fitted to the combination of a Bloch term and a Curie-Weiss term. The CdNCo{sub 3} sample is ferromagnet with coercivity of 240 Oe at room-temperature. In contrast to the paramagnetism previously reported, our CdNNi{sub 3} sample exhibits very soft and weak ferromagnetism. - Graphical Abstract: CdNCo{sub 3} is a new ternary nitride with antiperovskite structure, and it can form a complete solid solution series with CdNNi{sub 3}. Highlights: > CdNCo{sub 3-z}Ni{sub z} (0{<=}z{<=}3) samples were synthesized by solid-gas reactions. > CdNCo{sub 3} is a new ternary antiperovskite nitride, and it can form a complete solid solution series with CdNNi{sub 3}. > Both CdNCo{sub 3} and CdNNi{sub 3} samples show metallic behavior and exhibit a Fermi liquid behavior below 50 K. > Magnetic measurements show that CdNCo{sub 3} and CdNNi{sub 3} exhibit ferromagnetic and weak ferromagnetic behavior, respectively.

  14. Top physics at CDF

    SciTech Connect (OSTI)

    Julia Thom

    2004-06-24

    Precision studies of top quark properties are a primary goal of the Run II physics program at the Fermilab Tevatron. Marking the first stages of this program, the CDF collaboration presents recent results on top pair production cross section, single top physics and top mass, using between 109 and 200 pb{sup -1} of Run II data.

  15. Materials Physics and Applications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    MPA Materials Physics and Applications We develop new technologies that solve pressing national energy and security challenges by exploring and exploiting materials and their properties; developing practical applications of materials, and providing world-class user facilities. Contact Us Division Leader Tanja Pietrass Email Deputy Division Leader Rick Martineau Email Chief of Staff Jeff Willis Email Division Office (505) 665-1131 Materials Physics Applications Division Materials Physics and

  16. The three-dimensional morphology of growing dendrites

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gibbs, J. W.; Mohan, K. A.; Gulsoy, E. B.; Shahani, A. J.; Xiao, X.; Bouman, C. A.; De Graef, M.; Voorhees, P. W.

    2015-07-03

    The processes controlling the morphology of dendrites have been of great interest to a wide range of communities, since they are examples of an out-of-equilibrium pattern forming system, there is a clear connection with battery failure processes, and their morphology sets the properties of many metallic alloys. We determine the three-dimensional morphology of free growing metallic dendrites using a novel X-ray tomographic technique that improves the temporal resolution by more than an order of magnitude compared to conventional techniques. These measurements show that the growth morphology of metallic dendrites is surprisingly different from that seen in model systems, the morphologymore » is not self-similar with distance back from the tip, and that this morphology can have an unexpectedly strong influence on solute segregation in castings. These experiments also provide benchmark data that can be used to validate simulations of free dendritic growth.« less

  17. Degradative and Morphological Characterization of POSS Modified...

    Office of Scientific and Technical Information (OSTI)

    Degradative and Morphological Characterization of POSS Modified Nanohybrid Polyurethane Elastomers Citation Details In-Document Search Title: Degradative and Morphological ...

  18. MATPRO-Version 11: a handbook of materials properties for use...

    Office of Scientific and Technical Information (OSTI)

    Nonboiling Water Cooled; 360104 -- Metals & Alloys-- Physical Properties; 360204 -- Ceramics, Cermets, & Refractories-- Physical Properties This handbook describes the materials...

  19. Physics Fellow

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    as Institute of Physics Fellow January 18, 2011 LOS ALAMOS, New Mexico, January 18, ... simulation, and computation, has been selected as a Fellow of the Institute of Physics. ...

  20. Nuclear Physics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nuclear Physics Nuclear Physics Enabling remarkable discoveries and tools that transform our understanding of energy and matter and advance national, economic, and energy security. ...

  1. Theoretical Physics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    HEP Theoretical Physics Understanding discoveries at the Energy, Intensity, and Cosmic Frontiers Get ... HEP Theory at Los Alamos The Theoretical High Energy Physics group at ...

  2. Neutrino Physics | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Neutrino Physics Neutrino Physics Experimental neutrino physics is focused on the measurements of mass and other properties of neutrinos that may have profound consequences for understanding the evolution of the universe. Over the last few decades, particle physicists have accumulated experimental evidence on the properties of major constituents of matter, including neutrinos, to explain how neutrinos interact with matter and how these ghostly particles propagate over long distances. We have

  3. Palm Physics Page

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Palm Physics Page ** We no longer support this website. This is a preliminary group of Palm applications/databases that are intended to serve the interests of atomic, nuclear and particle physics. Applications Periodic Table: Shareware version of the periodic table with basic chemical properties of the elements.(Download) Particle Data Book: From the Particle Data Group at LBL. (Download) Heavy Ion Fusion Calculator: Compute available energy, Coulomb energy, maximum angular momentum for compound

  4. Top Physics at CDF

    SciTech Connect (OSTI)

    Moon, Chang-Seong

    2011-06-01

    We present the recent results of top-quark physics using up to 6 fb{sup -1} of p{bar p} collisions at a center of mass energy of {radical}s = 1.96 TeV analyzed by the CDF collaboration. Thanks to this large data sample, precision top quark measurements are now a reality at the Tevatron. Further, several new physics signals could appear in this large dataset. We will present the latest measurements of top quark intrinsic properties as well as direct searches for new physics in the top sector.

  5. Investigation of Morphology and Hydrogen Adsorption Capacity...

    Office of Scientific and Technical Information (OSTI)

    of Morphology and Hydrogen Adsorption Capacity of Disordered Carbons Citation Details In-Document Search Title: Investigation of Morphology and Hydrogen Adsorption Capacity of ...

  6. The effect of strontium non-stoichiometry on the physical properties of double perovskite Sr{sub 2}FeMoO{sub 6}

    SciTech Connect (OSTI)

    Harnagea, L. Berthet, P.

    2015-02-15

    We present a detailed study on the effect of strontium non-stoichiometry on the properties of double perovskite Sr{sub 2}FeMoO{sub 6} (SFMO). A citrate route has been used to prepare high quality polycrystalline samples with (2−x)Sr:Fe:Mo (x=0, 0.02, 0.04) and (2+x)Sr:Fe:Mo (x=0.02, 0.04, 0.10) cationic ratios. The strontium deficient samples exhibit a significant decrease in their values of saturation magnetization (Ms), Curie temperature (Tc) and magnetoresistance (MR) compared to the stoichiometric SFMO. On the other hand, the samples prepared with an excess of strontium, respectively those with x=0.02 and 0.04, show remarkably superior magneto–transport characteristics, despite of their increased level of Fe/Mo disorder and somewhat diminished magnetic properties compared to the stoichiometric SFMO. We also show that these samples exhibit superior MR values under low magnetic field and persisting up to temperatures as high as 400 K. - Graphical abstract: Evolution of the magnetization versus temperature under an applied magnetic field of 1000 Oe (left panel) and magnetoresistance versus applied magnetic field at 300 K (right panel) for strontium off-stoichiometric Sr{sub 2}FeMoO{sub 6} samples. - Highlights: • Strontium nonstoichiometric samples of Sr{sub 2}FeMoO{sub 6} are prepared by a citrate route. • The nonstoichiometric samples exhibit an increased Fe/Mo disorder in the structure. • We observed important changes in their magnetic and magnetoresistive properties. • Improved magnetoresistive properties for samples prepared with strontium excess.

  7. A convenient strategy to functionalize carbon nanotubes with ascorbic acid and its effect on the physical and thermomechanical properties of poly(amide–imide) composites

    SciTech Connect (OSTI)

    Mallakpour, Shadpour; Zadehnazari, Amin

    2014-03-15

    Multi-walled carbon nanotubes (MWCNTs) were functionalized by ascorbic acid by a fast strategy under microwave irradiation to improve interfacial interactions and dispersion of CNTs in a poly(amide–imide) (PAI) matrix. This technique provides a rapid and economically viable route to produce covalently functionalized CNTs. The as-prepared, new type of functionalized CNTs were analyzed by several techniques. The thermal stabilities and mechanical interfacial properties of CNT/PAI composites were investigated using several techniques. The dispersion state of CNTs in the PAI matrix was observed by field emission scanning electron microscopy (FE-SEM) and transmission electron microscopy (TEM). The mechanical interfacial property of the composites was significantly increased by the addition of ascorbic acid treated CNTs. The FE-SEM and TEM results showed that the separation and uniform dispersion of CNTs in the PAI matrix. The overview of these recent results is presented. -- Graphical abstract: Presentation of possible interactions of hydrogen bonding between the MWCNT-AS and the PAI chains. Highlights: • Surface functionalization of MWCNTs with ascorbic acid under microwave irradiation. • The MWCNT-AS/PAI composite films were fabricated by solution blending process. • Microstructure and MWCNT states in the composites were studied. • Thermal and mechanical properties of the composite films were evaluated. • Films of different contents of the MWCNTs-AS showed a superior tensile behavior.

  8. Thorium oxalate solubility and morphology

    SciTech Connect (OSTI)

    Monson, P.R. Jr.; Hall, R.

    1981-10-01

    Thorium was used as a stand-in for studying the solubility and precipitation of neptunium and plutonium oxalates. Thorium oxalate solubility was determined over a range of 0.001 to 10.0 in the concentration parameter (H/sub 2/C/sub 2/O/sub 4/)/(HNO/sub 3/)/sup 2/. Morphology of thorium oxide made from the oxalate precipitates was characterized by scanning electron microscopy. The different morphologies found for oxalate-lean and oxalate-rich precipitations were in agreement with predictions based on precipitation theory.

  9. Theoretical Physics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    HEP Theoretical Physics Understanding discoveries at the Energy, Intensity, and Cosmic Frontiers Get Expertise Rajan Gupta (505) 667-7664 Email Bruce Carlsten (505) 667-5657 Email HEP Theory at Los Alamos The Theoretical High Energy Physics group at Los Alamos National Laboratory is active in a number of diverse areas of research. Their primary areas of interest are in physics beyond the Standard Model, cosmology, dark matter, lattice quantum chromodynamics, neutrinos, the fundamentals of

  10. Nuclear Physics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nuclear Physics Nuclear Physics Enabling remarkable discoveries and tools that transform our understanding of energy and matter and advance national, economic, and energy security. Isotopes» A roadmap of matter that will help unlock the secrets of how the universe is put together The DOE Office of Science's Nuclear Physics (NP) program supports the experimental and theoretical research needed to create this roadmap. This quest requires a broad approach to different, but related, scientific

  11. Planetary Physics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    planetary physics Planetary Physics Some of the most intriguing NIF experiments test the physics believed to determine the structures of planets down to their cores, both in our solar system and beyond. In particular, scientists are using NIF to "explore" recently discovered exoplanets by duplicating the extreme conditions thought to exist in their interiors. Hundreds of extrasolar planets have been identified, some smaller than Earth and others a dozen times more massive than Jupiter.

  12. Physical properties and electronic structure of a new barium titanate suboxide Ba1+δTi13-δO₁₂ (δ = 0.11)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Rotundu, Costel R.; Jiang, Shan; Deng, Xiaoyu; Qian, Yiting; Khan, Saeed; Hawthorn, David G.; Kotliar, Gabriel; Ni, Ni

    2015-04-01

    The structure, transport, thermodynamic properties, x-ray absorption spectra (XAS), and electronic structure of a new barium titanate suboxide, Ba1+δTi13-δO₁₂ (δ = 0.11), are reported. It is a paramagnetic poor metal with hole carriers dominating the transport. Fermi liquid behavior appears at low temperature. The oxidization state of Ti obtained by the XAS is consistent with the metallic Ti²⁺ state. Local density approximation band structure calculations reveal the material is near the Van Hove singularity. The pseudogap behavior in the Ti-d band and the strong hybridization between the Ti-d and O-p orbitals reflect the characteristics of the building blocks of themore »Ti₁₃ semi-cluster and the TiO₄ quasi-squares, respectively.« less

  13. Physical properties and electronic structure of a new barium titanate suboxide Ba1+?Ti13-?O?? (? = 0.11)

    SciTech Connect (OSTI)

    Rotundu, Costel R.; Jiang, Shan; Deng, Xiaoyu; Qian, Yiting; Khan, Saeed; Hawthorn, David G.; Kotliar, Gabriel; Ni, Ni

    2015-04-01

    The structure, transport, thermodynamic properties, x-ray absorption spectra (XAS), and electronic structure of a new barium titanate suboxide, Ba1+?Ti13-?O?? (? = 0.11), are reported. It is a paramagnetic poor metal with hole carriers dominating the transport. Fermi liquid behavior appears at low temperature. The oxidization state of Ti obtained by the XAS is consistent with the metallic Ti? state. Local density approximation band structure calculations reveal the material is near the Van Hove singularity. The pseudogap behavior in the Ti-d band and the strong hybridization between the Ti-d and O-p orbitals reflect the characteristics of the building blocks of the Ti?? semi-cluster and the TiO? quasi-squares, respectively.

  14. Physical properties and electronic structure of a new barium titanate suboxide Ba{sub 1+?}Ti{sub 13??}O{sub 12} (? = 0.11)

    SciTech Connect (OSTI)

    Rotundu, Costel R.; Jiang, Shan; Ni, Ni; Deng, Xiaoyu; Kotliar, Gabriel; Qian, Yiting; Hawthorn, David G.; Khan, Saeed

    2015-04-01

    The structure, transport, thermodynamic properties, x-ray absorption spectra (XAS), and electronic structure of a new barium titanate suboxide, Ba{sub 1+?}Ti{sub 13??}O{sub 12} (? = 0.11), are reported. It is a paramagnetic poor metal with hole carriers dominating the transport. Fermi liquid behavior appears at low temperature. The oxidization state of Ti obtained by the XAS is consistent with the metallic Ti{sup 2+} state. Local density approximation band structure calculations reveal the material is near the Van Hove singularity. The pseudogap behavior in the Ti-d band and the strong hybridization between the Ti-d and O-p orbitals reflect the characteristics of the building blocks of the Ti{sub 13} semi-cluster and the TiO{sub 4} quasi-squares, respectively.

  15. Physical properties and electronic structure of a new barium titanate suboxide Ba1+δTi13-δO₁₂ (δ = 0.11)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Rotundu, Costel R.; Jiang, Shan; Deng, Xiaoyu; Qian, Yiting; Khan, Saeed; Hawthorn, David G.; Kotliar, Gabriel; Ni, Ni

    2015-04-01

    The structure, transport, thermodynamic properties, x-ray absorption spectra (XAS), and electronic structure of a new barium titanate suboxide, Ba1+δTi13-δO₁₂ (δ = 0.11), are reported. It is a paramagnetic poor metal with hole carriers dominating the transport. Fermi liquid behavior appears at low temperature. The oxidization state of Ti obtained by the XAS is consistent with the metallic Ti²⁺ state. Local density approximation band structure calculations reveal the material is near the Van Hove singularity. The pseudogap behavior in the Ti-d band and the strong hybridization between the Ti-d and O-p orbitals reflect the characteristics of the building blocks of themore » Ti₁₃ semi-cluster and the TiO₄ quasi-squares, respectively.« less

  16. physical security

    National Nuclear Security Administration (NNSA)

    5%2A en Physical Security Systems http:nnsa.energy.govaboutusourprogramsnuclearsecurityphysicalsecuritysystems

  17. Physical Sciences

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and the universe around us. Physics Division researchers are studying these interactions from the outermost reaches of the cosmos, to the innermost confines of subatomic particles....

  18. Influence of P{sub 2}O{sub 5} and Al{sub 2}O{sub 3} content on the structure of erbium-doped borosilicate glasses and on their physical, thermal, optical and luminescence properties

    SciTech Connect (OSTI)

    Bourhis, Kevin; Massera, Jonathan; Petit, Laeticia; Ihalainen, Heikki; Fargues, Alexandre; Cardinal, Thierry; Hupa, Leena; Hupa, Mikko; Dussauze, Marc; Rodriguez, Vincent; Boussard-Plédel, Catherine; Bureau, Bruno; Roiland, Claire; Ferraris, Monica

    2015-03-15

    Highlights: • Reorganization of the glass structure induced by the addition of P{sub 2}O{sub 5} or Al{sub 2}O{sub 3}. • Emission properties related to the presence of P or Al in the Er{sup 3+} coordination shell. • Declustering observed upon addition of P{sub 2}O{sub 5}. • No declustering upon addition of Al{sub 2}O{sub 3}. - Abstract: The effect of P{sub 2}O{sub 5} and/or Al{sub 2}O{sub 3} addition in Er-doped borosilicate glasses on the physical, thermal, optical, and luminescence properties is investigated. The changes in these glass properties are related to the glass structure modifications induced by the addition of P{sub 2}O{sub 5} and/or Al{sub 2}O{sub 3}, which were probed by FTIR, {sup 11}B MAS NMR and X-ray photoelectron spectroscopies. Variations of the polymerization degree of the silicate tetrahedra and modifications in the {sup [3]}B/{sup [4]}B ratio are explained by a charge compensation mechanism due to the formation of AlO{sub 4}, PO{sub 4} groups and the formation of Al-O-P linkages in the glass network. From the absorption and luminescence properties of the Er{sup 3+} ions at 980 nm and 1530 nm, declustering is suspected for the highest P{sub 2}O{sub 5} concentrations while for the highest Al{sub 2}O{sub 3} concentrations no declustering is observed.

  19. PHYSICAL PROPERTIES OF SPECTROSCOPICALLY CONFIRMED GALAXIES AT z {>=} 6. I. BASIC CHARACTERISTICS OF THE REST-FRAME UV CONTINUUM AND Ly{alpha} EMISSION

    SciTech Connect (OSTI)

    Jiang Linhua; Mechtley, Matthew; Cohen, Seth H.; Windhorst, Rogier A.; Egami, Eiichi; Fan Xiaohui; Dave, Romeel; Finlator, Kristian; Kashikawa, Nobunari; Ouchi, Masami; Shimasaku, Kazuhiro

    2013-08-01

    We present deep Hubble Space Telescope near-IR and Spitzer mid-IR observations of a large sample of spectroscopically confirmed galaxies at z {>=} 6. The sample consists of 51 Ly{alpha} emitters (LAEs) at z {approx_equal} 5.7, 6.5, and 7.0, and 16 Lyman break galaxies (LBGs) at 5.9 {<=} z {<=} 6.5. The near-IR images were mostly obtained with WFC3 in the F125W and F160W bands, and the mid-IR images were obtained with IRAC in the 3.6 {mu}m and 4.5 {mu}m bands. Our galaxies also have deep optical imaging data from Subaru Suprime-Cam. We utilize the multi-band data and secure redshifts to derive their rest-frame UV properties. These galaxies have steep UV-continuum slopes roughly between {beta} {approx_equal} -1.5 and -3.5, with an average value of {beta} {approx_equal} -2.3, slightly steeper than the slopes of LBGs in previous studies. The slope shows little dependence on UV-continuum luminosity except for a few of the brightest galaxies. We find a statistically significant excess of galaxies with slopes around {beta} {approx_equal} -3, suggesting the existence of very young stellar populations with extremely low metallicity and dust content. Our galaxies have moderately strong rest-frame Ly{alpha} equivalent width (EW) in a range of {approx}10 to {approx}200 A. The star formation rates are also moderate, from a few to a few tens of solar masses per year. The LAEs and LBGs in this sample share many common properties, implying that LAEs represent a subset of LBGs with strong Ly{alpha} emission. Finally, the comparison of the UV luminosity functions between LAEs and LBGs suggests that there exists a substantial population of faint galaxies with weak Ly{alpha} emission (EW < 20 A) that could be the dominant contribution to the total ionizing flux at z {>=} 6.

  20. Synthesis, characterization and physical properties of the skutterudites Yb{sub x}Fe{sub 2}Ni{sub 2}Sb{sub 12} (0{<=}x{<=}0.4)

    SciTech Connect (OSTI)

    Kaltzoglou, Andreas; Vaqueiro, Paz; Knight, Kevin S.; Powell, Anthony V.

    2012-09-15

    The skutterudites Yb{sub x}Fe{sub 2}Ni{sub 2}Sb{sub 12} (0{<=}x{<=}0.4) have been prepared by solid-state reaction and characterised by powder X-ray diffraction. The compounds crystallise in the cubic space group Im3{sup Macron} (a Almost-Equal-To 9.1 A) with Yb atoms partially filling the voids in the skutterudite framework. A neutron time-of-flight diffraction experiment for Fe{sub 2}Ni{sub 2}Sb{sub 12} confirms the disorder of Fe and Ni atoms on the transition-metal site. Electrical resistivity, Seebeck coefficient and thermal conductivity measurements indicate that the thermoelectric performance of the skutterudites shows a marked dependence on the Yb content. Magnetic measurements over the temperature range 2{<=}T/K{<=}300 show paramagnetic behaviour for all compounds. Decomposition studies under an oxidising atmosphere at elevated temperatures have also been carried out by thermogravimetric analysis. - Graphical abstract: The filled skutterudites Yb{sub x}Fe{sub 2}Ni{sub 2}Sb{sub 12} have been prepared by solid-state reaction and characterised by powder X-ray diffraction. The thermoelectric performance depends strongly on the Yb content. The physical properties and thermal stability of the compounds are further discussed in comparison with the current state-of-the art thermoelectric skutterudites. Highlights: Black-Right-Pointing-Pointer A new series of skutterudites has been prepared and characterised. Black-Right-Pointing-Pointer Physical properties are affected by the degree of Yb filling. Black-Right-Pointing-Pointer The highest thermoelectric performance is found for Yb{sub 0.15}Fe{sub 2}Ni{sub 2}Sb{sub 12}. Black-Right-Pointing-Pointer The skutterudites decompose in air above 550 K.

  1. Synthesis, crystal and electronic structure, and physical properties of the new lanthanum copper telluride La{sub 3}Cu{sub 5}Te{sub 7}

    SciTech Connect (OSTI)

    Zelinska, Mariya; Assoud, Abdeljalil [Department of Chemistry, University of Waterloo, Waterloo, ON, Canada N2L 3G1 (Canada); Kleinke, Holger, E-mail: kleinke@uwaterloo.c [Department of Chemistry, University of Waterloo, Waterloo, ON, Canada N2L 3G1 (Canada)

    2011-03-15

    The new lanthanum copper telluride La{sub 3}Cu{sub 5-x}Te{sub 7} has been obtained by annealing the elements at 1073 K. Single-crystal X-ray diffraction studies revealed that the title compound crystallizes in a new structure type, space group Pnma (no. 62) with lattice dimensions of a=8.2326(3) A, b=25.9466(9) A, c=7.3402(3) A, V=1567.9(1) A{sup 3}, Z=4 for La{sub 3}Cu{sub 4.86(4)}Te{sub 7}. The structure of La{sub 3}Cu{sub 5-x}Te{sub 7} is remarkably complex. The Cu and Te atoms build up a three-dimensional covalent network. The coordination polyhedra include trigonal LaTe{sub 6} prisms, capped trigonal LaTe{sub 7} prisms, CuTe{sub 4} tetrahedra, and CuTe{sub 3} pyramids. All Cu sites exhibit deficiencies of various extents. Electrical property measurements on a sintered pellet of La{sub 3}Cu{sub 4.86}Te{sub 7} indicate that it is a p-type semiconductor in accordance with the electronic structure calculations. -- Graphical abstract: Oligomeric unit comprising interconnected CuTe{sub 3} pyramids and CuTe{sub 4} tetrahedra. Display Omitted Research highlights: {yields} La{sub 3}Cu{sub 5-x}Te{sub 7} adopts a new structure type. {yields} All Cu sites exhibit deficiencies of various extents. {yields} The coordination polyhedra include trigonal LaTe{sub 6} prisms, capped trigonal LaTe{sub 7} prisms, CuTe{sub 4} tetrahedra and CuTe{sub 3} pyramids. {yields} La{sub 3}Cu{sub 5-x}Te{sub 7} is a p-type semiconductor.

  2. Gold-rich R3Au7Sn3: Establishing the interdependence between electronic features and physical properties

    SciTech Connect (OSTI)

    Provino, Alessia; Steinberg, Simon; Smetana, Volodymyr; Kulkarni, Ruta; Dhar, Sudesh K.; Manfrinetti, Pietro; Mudring, Anja -Verena

    2015-05-18

    Two new polar intermetallic compounds Y3Au7Sn3 (I) and Gd3Au7Sn3 (II) have been synthesized and their structures have been determined by single crystal X-ray diffraction (P63/m; Z = 2, a = 8.148(1)/8.185(3), and c = 9.394(2)/9.415(3) for I/II, respectively). They can formally be assigned to the Cu10Sn3 type and consist of parallel slabs of Sn centered, edge-sharing trigonal Au6 antiprisms connected through R3 (R = Y, Gd) triangles. Additional Au atoms reside in the centres of trigonal Au6 prisms forming Au@Au6 clusters with Au–Au distances of 2.906–2.960 Å, while the R–R contacts in the R3 groups are considerably larger than the sums of their metallic radii. These exclusive structural arrangements provide alluring systems to study the synergism between strongly correlated systems, particularly, those in the structure of (II), and extensive polar intermetallic contacts, which has been inspected by measurements of the magnetic properties, heat capacities and electrical conductivities of both compounds. Gd3Au7Sn3 shows an antiferromagnetic ordering at 13 K, while Y3Au7Sn3 is a Pauli paramagnet and a downward curvature in its electrical resistivity at about 1.9 K points to a superconducting transition. DFT-based band structure calculations on R3Au7Sn3 (R = Y, Gd) account for the results of the conductivity measurements and different spin ordering models of (II) provide conclusive hints about its magnetic structure. As a result, chemical bonding analyses of both compounds indicate that the vast majority of bonding originates from the heteroatomic Au–Gd and Au–Sn interactions, while homoatomic Au–Au bonding is evident within the Au@Au6 clusters.

  3. Gold-rich R3Au7Sn3: Establishing the interdependence between electronic features and physical properties

    SciTech Connect (OSTI)

    Provino, Alessia; Steinberg, Simon; Smetana, Volodymyr; Kulkarni, Ruta; Dhar, Sudesh K.; Manfrinetti, Pietro; Mudring, Anja -Verena

    2015-05-18

    Two new polar intermetallic compounds Y3Au7Sn3 (I) and Gd3Au7Sn3 (II) have been synthesized and their structures have been determined by single crystal X-ray diffraction (P63/m; Z = 2, a = 8.148(1)/8.185(3), and c = 9.394(2)/9.415(3) for I/II, respectively). They can formally be assigned to the Cu10Sn3 type and consist of parallel slabs of Sn centered, edge-sharing trigonal Au6 antiprisms connected through R3 (R = Y, Gd) triangles. Additional Au atoms reside in the centres of trigonal Au6 prisms forming Au@Au6 clusters with Au–Au distances of 2.906–2.960 Å, while the R–R contacts in the R3 groups are considerably larger than the sums of their metallic radii. These exclusive structural arrangements provide alluring systems to study the synergism between strongly correlated systems, particularly, those in the structure of (II), and extensive polar intermetallic contacts, which has been inspected by measurements of the magnetic properties, heat capacities and electrical conductivities of both compounds. Gd3Au7Sn3 shows an antiferromagnetic ordering at 13 K, while Y3Au7Sn3 is a Pauli paramagnet and a downward curvature in its electrical resistivity at about 1.9 K points to a superconducting transition. DFT-based band structure calculations on R3Au7Sn3 (R = Y, Gd) account for the results of the conductivity measurements and different spin ordering models of (II) provide conclusive hints about its magnetic structure. As a result, chemical bonding analyses of both compounds indicate that the vast majority of bonding originates from the heteroatomic Au–Gd and Au–Sn interactions, while homoatomic Au–Au bonding is evident within the Au@Au6 clusters.

  4. Physical Scientist

    Broader source: Energy.gov [DOE]

    The Office of Science is the single largest supporter of basic research in the physical sciences in the United States, providing more than 40 percent of total funding for this vital area of...

  5. REVEALING THE PHYSICAL PROPERTIES OF MOLECULAR GAS IN ORION WITH A LARGE-SCALE SURVEY IN J = 2-1 LINES OF {sup 12}CO, {sup 13}CO, AND C{sup 18}O

    SciTech Connect (OSTI)

    Nishimura, Atsushi; Tokuda, Kazuki; Kimura, Kimihiro; Muraoka, Kazuyuki; Maezawa, Hiroyuki; Ogawa, Hideo; Onishi, Toshikazu [Department of Physical Science, Graduate School of Science, Osaka Prefecture University, 1-1 Gakuen-cho, Naka-ku, Sakai, Osaka 599-8531 (Japan); Dobashi, Kazuhito; Shimoikura, Tomomi [Department of Astronomy and Earth Sciences, Tokyo Gakugei University, 4-1-1 Nukuikita-machi, Koganei, Tokyo 184-8501 (Japan); Mizuno, Akira [Solar-terrestrial Environment Laboratory, Nagoya University, Furo-cho, Chikusa-ku, Nagoya, Aichi 464-8601 (Japan); Fukui, Yasuo, E-mail: atsushi.nishimura@nao.ac.jp [Department of Physics and Astrophysics, Nagoya University, Furo-cho, Chikusa-ku, Nagoya, Aichi 464-8602 (Japan)

    2015-01-01

    We present fully sampled ?3' resolution images of {sup 12}CO(J=2-1), {sup 13}CO(J=2-1), and C{sup 18}O(J=2-1) emission taken with the newly developed 1.85 m millimeter-submillimeter telescope over the entire area of the Orion A and B giant molecular clouds. The data were compared with J=1-0 of the {sup 12}CO, {sup 13}CO, and C{sup 18}O data taken with the Nagoya 4 m telescope and the NANTEN telescope at the same angular resolution to derive the spatial distributions of the physical properties of the molecular gas. We explore the large velocity gradient formalism to determine the gas density and temperature using line combinations of {sup 12}CO(J=2-1), {sup 13}CO(J=2-1), and {sup 13}CO(J=1-0) assuming a uniform velocity gradient and abundance ratio of CO. The derived gas density is in the range of 500 to 5000 cm{sup 3}, and the derived gas temperature is mostly in the range of 20 to 50 K along the cloud ridge with a temperature gradient depending on the distance from the star forming region. We found that the high-temperature region at the cloud edge faces the H II region, indicating that the molecular gas is interacting with the stellar wind and radiation from the massive stars. In addition, we compared the derived gas properties with the young stellar objects distribution obtained with the Spitzer telescope to investigate the relationship between the gas properties and the star formation activity therein. We found that the gas density and star formation efficiency are positively well correlated, indicating that stars form effectively in the dense gas region.

  6. Advanced Technologies for Monitoring CO2 Saturation and Pore Pressure in Geologic Formations: Linking the Chemical and Physical Effects to Elastic and Transport Properties

    SciTech Connect (OSTI)

    Mavko, G.; Vanorio, T.; Vialle, S.; Saxena, N.

    2014-03-31

    advection: because of an efficient mass transfer of reactants and products, the fluid remains acidic, far from thermodynamical equilibrium and the dissolution of calcite is important. These conclusions are consistent with the lab observations. Sandstones from the Tuscaloosa formation in Mississippi were also subjected to injection under representative in situ stress and pore pressure conditions. Again, both P- and S-wave velocities decreased with injection. Time-lapse SEM images indicated permanent changes induced in the sandstone microstructure by chamosite dissolution upon injection of CO2-rich brine. After injection, the sandstone showed an overall cleaner microstructure. Two main changes are involved: (a) clay dissolution between grains and at the grain contact and (b) rearrangement of grains due to compaction under pressure Theoretical and empirical models were developed to quantify the elastic changes associated with injection. Permanent changes to the rock frame resulted in seismic velocity-porosity trends that mimic natural diagenetic changes. Hence, when laboratory measurments are not available for a candidate site, these trends can be estimated from depth trends in well logs. New theoretical equations were developed to predict the changes in elastic moduli upon substitution of pore-filling material. These equations reduce to Gassmann’s equations for the case of constant frame properties, low seismic frequencies, and fluid changes in the pore space. The new models also predict the change dissolution or precipitation of mineral, which cannot be described with the conventional Gassmann theory.

  7. Subatomic Physics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    5 Subatomic Physics We play a major role in large-scale scientific collaborations around the world, performing nuclear physics experiments that advance the understanding of the hidden subatomic reactions of the universe and how high explosives affect matter. Contact Us Group Leader Melynda Brooks Email Deputy Group Leader Frans Trouw Email Group Office (505) 667-6941 A detector that uses muons, tiny particles generated when cosmic rays interact with Earth's atmosphere to look inside the cores of

  8. Plasma Physics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    4 Plasma Physics By leveraging plasma under extreme conditions, we concentrate on solving critical scientific challenges such as detecting smuggled nuclear materials, advancing weapons physics and generating fusion energy. Contact Us Group Leader Ray Leeper Email Deputy Group Leader Julie Canepa Email Group Office (505) 665-9145 Laser-generated neutrons Researchers at Los Alamos have successfully demonstrated for the first time that laser-generated neutrons can be enlisted as a useful tool in

  9. Metal oxide nanostructures with hierarchical morphology

    DOE Patents [OSTI]

    Ren, Zhifeng; Lao, Jing Yu; Banerjee, Debasish

    2007-11-13

    The present invention relates generally to metal oxide materials with varied symmetrical nanostructure morphologies. In particular, the present invention provides metal oxide materials comprising one or more metallic oxides with three-dimensionally ordered nanostructural morphologies, including hierarchical morphologies. The present invention also provides methods for producing such metal oxide materials.

  10. FSU High Energy Physics

    SciTech Connect (OSTI)

    Prosper, Harrison B.; Adams, Todd; Askew, Andrew; Berg, Bernd; Blessing, Susan K.; Okui, Takemichi; Owens, Joseph F.; Reina, Laura; Wahl, Horst D.

    2014-12-01

    The High Energy Physics group at Florida State University (FSU), which was established in 1958, is engaged in the study of the fundamental constituents of matter and the laws by which they interact. The group comprises theoretical and experimental physicists, who sometimes collaborate on projects of mutual interest. The report highlights the main recent achievements of the group. Significant, recent, achievements of the group’s theoretical physicists include progress in making precise predictions in the theory of the Higgs boson and its associated processes, and in the theoretical understanding of mathematical quantities called parton distribution functions that are related to the structure of composite particles such as the proton. These functions are needed to compare data from particle collisions, such as the proton-proton collisions at the CERN Large Hadron Collider (LHC), with theoretical predictions. The report also describes the progress in providing analogous functions for heavy nuclei, which find application in neutrino physics. The report highlights progress in understanding quantum field theory on a lattice of points in space and time (an area of study called lattice field theory), the progress in constructing several theories of potential new physics that can be tested at the LHC, and interesting new ideas in the theory of the inflationary expansion of the very early universe. The focus of the experimental physicists is the Compact Muon Solenoid (CMS) experiment at CERN. The report, however, also includes results from the D0 experiment at Fermilab to which the group made numerous contributions over a period of many years. The experimental group is particularly interested in looking for new physics at the LHC that may provide the necessary insight to extend the standard model (SM) of particle physics. Indeed, the search for new physics is the primary task of contemporary particle physics, one motivated by the need to explain certain facts, such as the

  11. Physical Security

    SciTech Connect (OSTI)

    2008-01-01

    The future of physical security at government facilities and national laboratories is rapidly progressing beyond the cliché of gates, guns and guards, and is quickly being replaced by radars, sensors and cameras. Learn more about INL's security research at http://www.facebook.com/idahonationallaboratory.

  12. Rock physics at Los Alamos Scientific Laboratory

    SciTech Connect (OSTI)

    Not Available

    1980-01-01

    Rock physics refers to the study of static and dynamic chemical and physical properties of rocks and to phenomenological investigations of rocks reacting to man-made forces such as stress waves and fluid injection. A bibliography of rock physics references written by LASL staff members is given. Listing is by surname of first author. (RWR)

  13. Measuring Physical Properties of Polymer Electrolyte Membranes...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    at the DOE High Temperature Membrane Working Group held September 14, 2006. htmwgmittelsteadt.pdf (450.28 KB) More Documents & Publications Membrane Performance and Durability ...

  14. Crystal Structure, Physical Properties, and Electrochemistry...

    Office of Scientific and Technical Information (OSTI)

    Brookhaven National University; University of California, San Diego; University of Cambridge, UK; Lawrence Berkeley National Laboratory; Massachusetts Institute of Technology;...

  15. High Energy Physics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    High Energy Physics High Energy Physics Investigating the field of high energy physics ... Through the Office of High Energy Physics (HEP), Los Alamos conducts research in particle ...

  16. Physical Protection

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2005-08-26

    This Manual establishes requirements for the physical protection of safeguards and security interests. Copies of Section B, Safeguards and Security Alarm Management System, which contains Unclassified Controlled Nuclear Information, and Appendix 1, Security Badge Specifications, which contains Official Use Only information, are only available, by request, from the program manager, Protection Program Operations, 301-903-6209. Chg 1, dated 3/7/06. Cancels: DOE M 473.1-1 and DOE M 471.2-1B

  17. Physical Protection

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2005-08-26

    Establishes requirements for the physical protection of safeguards and security interests. Copies of Section B, Safeguards and Security Alarm Management System, which contains Unclassified Controlled Nuclear Information, and Appendix 1, Security Badge Specifications, which contains Official Use Only information, are only available, by request, from the program manager, Protection Program Operations, 301-903-6209. Cancels: DOE M 473.1-1 and DOE M 471.2-1B.

  18. SURFACE MORPHOLOGY OF CARBON FIBER POLYMER COMPOSITES AFTER LASER STRUCTURING

    SciTech Connect (OSTI)

    Sabau, Adrian S; Chen, Jian; Jones, Jonaaron F.; Alexandra, Hackett; Jellison Jr, Gerald Earle; Daniel, Claus; Warren, Charles David; Rehkopf, Jackie D.

    2015-01-01

    The increasing use of Carbon Fiber Polymer Composite (CFPC) as a lightweight material in automotive and aerospace industries requires the control of surface morphology. In this study, the composites surface was prepared by ablating the resin in the top fiber layer of the composite using an Nd:YAG laser. The CFPC specimens with T700S carbon fiber and Prepreg - T83 resin (epoxy) were supplied by Plasan Carbon Composites, Inc. as 4 ply thick, 0/90o plaques. The effect of laser fluence, scanning speed, and wavelength was investigated to remove resin without an excessive damage of the fibers. In addition, resin ablation due to the power variation created by a laser interference technique is presented. Optical property measurements, optical micrographs, 3D imaging, and high-resolution optical profiler images were used to study the effect of the laser processing on the surface morphology.

  19. Operational health physics training

    SciTech Connect (OSTI)

    1992-06-01

    The initial four sections treat basic information concerning atomic structure and other useful physical quantities, natural radioactivity, the properties of {alpha}, {beta}, {gamma}, x rays and neutrons, and the concepts and units of radiation dosimetry (including SI units). Section 5 deals with biological effects and the risks associated with radiation exposure. Background radiation and man-made sources are discussed next. The basic recommendations of the ICRP concerning dose limitations: justification, optimization (ALARA concepts and applications) and dose limits are covered in Section seven. Section eight is an expanded version of shielding, and the internal dosimetry discussion has been extensively revised to reflect the concepts contained in the MIRD methodology and ICRP 30. The remaining sections discuss the operational health physics approach to monitoring radiation. Individual sections include radiation detection principles, instrument operation and counting statistics, health physics instruments and personnel monitoring devices. The last five sections deal with the nature of, operation principles of, health physics aspects of, and monitoring approaches to air sampling, reactors, nuclear safety, gloveboxes and hot cells, accelerators and x ray sources. Decontamination, waste disposal and transportation of radionuclides are added topics. Several appendices containing constants, symbols, selected mathematical topics, and the Chart of the Nuclides, and an index have been included.

  20. Hadron physics

    SciTech Connect (OSTI)

    Bunce, G.

    1984-05-30

    Is all hadronic physics ultimately describable by QCD. Certainly, many disparate phenomena can be understood within the QCD framework. Also certainly, there are important questions which are open, both theoretically (little guidance, as yet) and experimentally, regarding confinement. Are there dibaryons, baryonium, glueballs. In addition, there are experimental results which at present do not have an explanation. This talk, after a short section on QCD successes and difficulties, will emphasize two experimental topics which have recent results - glueball spectroscopy and exclusive reactions at large momentum transfer. Both are experimentally accessible in the AGS/LAMPF II/AGS II/TRIUMF II/SIN II energy domain.

  1. Physical protection

    SciTech Connect (OSTI)

    Myre, W.C.; DeMontmollin, J.M. )

    1989-07-01

    Serious concern about physical protection of nuclear facilities began around 1972. R and D was initiated at Sandia National Laboratories which had developed techniques to protect weapons for many years. Special vehicles, convoy procedures, and a communications system previously developed for weapons shipments were improved and extended for shipments of other sensitive materials. Barriers, perimeter alarms, portal and internal control systems were developed, tested, and published in handbooks and presented at symposia. Training programs were initiated for U.S. and foreign personnel. Containment and surveillance techniques were developed for the IAEA. Presently emphasis is on computer security, active barriers, and techniques to prevent theft or sabotage by insiders .

  2. Top physics: CDF results

    SciTech Connect (OSTI)

    K. Bloom

    2004-06-23

    The top quark plays an important role in the grand scheme of particle physics, and is also interesting on its own merits. We present recent results from CDF on top-quark physics based on 100-200 pb{sup -1} of p{bar p} collision data. We have measured the t{bar t} cross section in different decay modes using several different techniques, and are beginning our studies of top-quark properties. New analyses for this conference include a measurement of {sigma}{sub t{bar t}} in the lepton-plus-jets channel using a neural net to distinguish signal and background events, and measurements of top-quark branching fractions.

  3. Crystallography and Physical Properties of BaCo2As2, Ba0.94K0.06Co2As2, and Ba0.78K0.22Co2As2

    SciTech Connect (OSTI)

    Anand, V K; Quirinale, Dante G; Lee, Yongbin; Harmon, Bruce N; Furukawa, Yuji; Ogloblichev, V V; Huq, A; Abernathy, D L; Stephens, P W; McQueeney, Robert J; Kreyssig, Aandreas; Goldman, Alan I; Johnston, David C

    2014-08-01

    The crystallographic and physical properties of polycrystalline and single crystal samples of BaCo2As2 and K-doped Ba{1-x}K{x}Co2As2 (x = 0.06, 0.22) are investigated by x-ray and neutron powder diffraction, magnetic susceptibility chi, magnetization, heat capacity Cp, {75}As NMR and electrical resistivity rho measurements versus temperature T. The crystals were grown using both Sn flux and CoAs self-flux, where the Sn-grown crystals contain 1.6-2.0 mol% Sn. All samples crystallize in the tetragonal ThCr2Si2-type structure (space group I4/mmm). For BaCo2As2, powder neutron diffraction data show that the c-axis lattice parameter exhibits anomalous negative thermal expansion from 10 to 300 K, whereas the a-axis lattice parameter and the unit cell volume show normal positive thermal expansion over this T range. No transitions in BaCo2As2 were found in this T range from any of the measurements. Below 40-50 K, we find rho ~ T^2 indicating a Fermi liquid ground state. A large density of states at the Fermi energy D(EF) ~ 18 states/(eV f.u.) for both spin directions is found from low-T Cp(T) measurements, whereas the band structure calculations give D(EF) = 8.23 states/(eV f.u.). The {75}As NMR shift data versus T have the same T dependence as the chi(T) data, demonstrating that the derived chi(T) data are intrinsic. The observed {75}As nuclear spin dynamics are consistent with the presence of ferromagnetic and/or stripe-type antiferromagnetic spin fluctuations. The crystals of Ba{0.78}K{0.22}Co2As2 were grown in Sn flux and show properties very similar to those of undoped BaCo2As2. On the other hand, the crystals from two batches of Ba{0.94}K{0.06}Co2As2 grown in CoAs self-flux show evidence of weak ferromagnetism at T < 10 K with small ordered moments at 1.8 K of 0.007 and 0.03 muB per formula unit, respectively.

  4. CDF Top Physics

    DOE R&D Accomplishments [OSTI]

    Tartarelli, G. F.; CDF Collaboration

    1996-05-01

    The authors present the latest results about top physics obtained by the CDF experiment at the Fermilab Tevatron collider. The data sample used for these analysis (about 110 pb{sup{minus}1}) represents almost the entire statistics collected by CDF during four years (1992--95) of data taking. This large data size has allowed detailed studies of top production and decay properties. The results discussed here include the determination of the top quark mass, the measurement of the production cross section, the study of the kinematics of the top events and a look at top decays.

  5. Resolution of the discrepancy between the variation of the physical properties of Ce1-xYbxCoIn5 single crystals and thin films with Yb composition

    SciTech Connect (OSTI)

    Jang, S.; White, B. D.; Lum, I. K.; Kim, H.; Tanatar, M. A.; Straszheim, W. E.; Prozorov, R.; Keiber, T.; Bridges, F.; Shu, L.; Baumbach, R. E.; Janoschek, M.; Maple, M. B.

    2014-11-18

    The extraordinary electronic phenomena including an Yb valence transition, a change in Fermi surface topology, and suppression of the heavy fermion quantum critical field at a nominal concentration x≈0.2 have been found in the Ce1-xYbxCoIn5 system. These phenomena have no discernable effect on the unconventional superconductivity and normal-state non-Fermi liquid behaviour that occur over a broad range of x up to ~0.8. However, the variation of the coherence temperature T* and the superconducting critical temperature Tc with nominal Yb concentration x for bulk single crystals is much weaker than that of thin films. To determine whether differences in the actual Yb concentration of bulk single crystals and thin film samples might be responsible for these discrepancies, we employed Vegard’s law and the spectroscopically determined values of the valences of Ce and Yb as a function of x to determine the actual composition xact of bulk single crystals. This analysis is supported by energy-dispersive X-ray spectroscopy, wavelength-dispersive X-ray spectroscopy, and transmission X-ray absorption edge spectroscopy measurements. The actual composition xact is found to be about one-third of the nominal concentration x up to x~0.5, and resolves the discrepancy between the variation of the physical properties of Ce1-xYbxCoIn5 single crystals and thin films with Yb concentration.

  6. Physics Division News

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    PADSTE » ADEPS » Physics » Physics Division News Physics Division News Discover more about the wide-ranging scope of Physics Division science and technology. Contact Us ADEPS Communications Email Physics Flash An electronic newsletter featuring interviews with Physics Division staff and news of awards and the latest research published in peer-reviewed journals. Physics Flash archive Focus on Physics Focus on Proton Radiography (pdf) High Energy Physics: LBNE, HAWC (pdf) Nuclear Physics:

  7. Top physics results at CDF

    SciTech Connect (OSTI)

    Vickey, Trevor; /Illinois U., Urbana

    2005-05-01

    The most recent results on top quark physics at CDF are reported. Measurements of cross-section and mass are presented, and the status of single top quark production searches are discussed. The results obtained from probing various top quark properties are also presented.

  8. Physics Topics - MST - UW Plasma Physics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Physics Topics UW Madison Madison Symmetric Torus Physics Topics MST HomeGraduate Student InformationLinksTourControl and Auxiliary SystemsPhysics TopicsDeviceResearch MissionMST People mst logo CPLA Home Directory Publications Links Internal University of Wisconsin Physics Department Research funding includes support from: Department of Energy National Science Foundation The MST physics challenges are large and many, but much of our work is captured in the following four major RFP physics goals

  9. DOE Fundamentals Handbook: Classical Physics

    SciTech Connect (OSTI)

    Not Available

    1992-06-01

    The Classical Physics Fundamentals Handbook was developed to assist nuclear facility operating contractors provide operators, maintenance personnel, and the technical staff with the necessary fundamentals training to ensure a basic understanding of physical forces and their properties. The handbook includes information on the units used to measure physical properties; vectors, and how they are used to show the net effect of various forces; Newton`s Laws of motion, and how to use these laws in force and motion applications; and the concepts of energy, work, and power, and how to measure and calculate the energy involved in various applications. This information will provide personnel with a foundation for understanding the basic operation of various types of DOE nuclear facility systems and equipment.

  10. DOE Fundamentals Handbook: Classical Physics

    SciTech Connect (OSTI)

    Not Available

    1992-06-01

    The Classical Physics Fundamentals Handbook was developed to assist nuclear facility operating contractors provide operators, maintenance personnel, and the technical staff with the necessary fundamentals training to ensure a basic understanding of physical forces and their properties. The handbook includes information on the units used to measure physical properties; vectors, and how they are used to show the net effect of various forces; Newton's Laws of motion, and how to use these laws in force and motion applications; and the concepts of energy, work, and power, and how to measure and calculate the energy involved in various applications. This information will provide personnel with a foundation for understanding the basic operation of various types of DOE nuclear facility systems and equipment.

  11. Properties and hydration of blended cements with steelmaking slag

    SciTech Connect (OSTI)

    Kourounis, S.; Tsivilis, S. . E-mail: stsiv@central.ntua.gr; Tsakiridis, P.E.; Papadimitriou, G.D.; Tsibouki, Z.

    2007-06-15

    The present research study investigates the properties and hydration of blended cements with steelmaking slag, a by-product of the conversion process of iron to steel. For this purpose, a reference sample and three cements containing up to 45% w/w steel slag were tested. The steel slag fraction used was the '0-5 mm', due to its high content in calcium silicate phases. Initial and final setting time, standard consistency, flow of normal mortar, autoclave expansion and compressive strength at 2, 7, 28 and 90 days were measured. The hydrated products were identified by X-ray diffraction while the non-evaporable water was determined by TGA. The microstructure of the hardened cement pastes and their morphological characteristics were examined by scanning electron microscopy. It is concluded that slag can be used in the production of composite cements of the strength classes 42.5 and 32.5 of EN 197-1. In addition, the slag cements present satisfactory physical properties. The steel slag slows down the hydration of the blended cements, due to the morphology of contained C{sub 2}S and its low content in calcium silicates.

  12. Headquarters Facilities Master Security Plan- Chapter 1, Physical Security

    Office of Energy Efficiency and Renewable Energy (EERE)

    2016 Headquarters Facilities Master Security Plan - Chapter 1, Physical Security Describes DOE Headquarters Physical Security procedures related to badges, inspections, access controls, visitor controls, and removal of government property.

  13. Quantum simulations of physics problems

    SciTech Connect (OSTI)

    Somma, R. D.; Ortiz, G.; Knill, E. H.; Gubernatis, J. E.

    2003-01-01

    If a large Quantum Computer (QC) existed today, what type of physical problems could we efficiently simulate on it that we could not efficiently simulate on a classical Turing machine? In this paper we argue that a QC could solve some relevant physical 'questions' more efficiently. The existence of one-to-one mappings between different algebras of observables or between different Hilbert spaces allow us to represent and imitate any physical system by any other one (e.g., a bosonic system by a spin-1/2 system). We explain how these mappings can be performed, and we show quantum networks useful for the efficient evaluation of some physical properties, such as correlation functions and energy spectra.

  14. Menu Driven Program Determining Properties of Aqueous Lithium Bromide Solutions

    Energy Science and Technology Software Center (OSTI)

    1992-12-09

    LIMENU is a menu driven program written to compute seven physical properties of a lithium bromide-water solution and three physical properties of water, and to display two plots.

  15. Saturday Morning Physics - Talks

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Further information online Contemporary Physics Education Project The Particle Adventure Particle Physics - Education and Outreach (Fermilab) CERN (Education Website) Wikipedia: ...

  16. Hydrocarbon and Deposit Morphology Effects on EGR Cooler Deposit...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Deposit Morphology Effects on EGR Cooler Deposit Stability and Removal Hydrocarbon and Deposit Morphology Effects on EGR Cooler Deposit Stability and Removal This paper reports ...

  17. Surface Morphology and Magnetic Anisotropy (Conference) | SciTech...

    Office of Scientific and Technical Information (OSTI)

    Conference: Surface Morphology and Magnetic Anisotropy Citation Details In-Document Search Title: Surface Morphology and Magnetic Anisotropy Authors: Lukaszew, R.A. ; Zhang, Z. ;...

  18. Addressable morphology control of silica structures by manipulating...

    Office of Scientific and Technical Information (OSTI)

    Addressable morphology control of silica structures by manipulating the reagent addition time Citation Details In-Document Search Title: Addressable morphology control of silica ...

  19. Exploration of multi-block polymer morphologies using high performance...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Exploration of multi-block polymer morphologies using high performance computing Modern material design increasingly relies on controlling small scale morphologies. Multi-block...

  20. Nanoscale Morphological and Chemical Changes of High Voltage...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nanoscale Morphological and Chemical Changes of High Voltage Lithium-Manganese Rich NMC ... must understand the evolution of chemical composition and morphology of battery ...

  1. PROPERTIES OF SEQUENTIAL CHROMOSPHERIC BRIGHTENINGS AND ASSOCIATED...

    Office of Scientific and Technical Information (OSTI)

    We report on the physical properties of solar sequential chromospheric brightenings ... (kernels) of solar flares and associated SCBs using high-resolution Halpha images. ...

  2. Testing Subgroup Workshop on Critical Property Needs

    Broader source: Energy.gov [DOE]

    Objectives: Develop an action plan that details the necessary tests to measure and compare the physical properties of metallic materials relevant to high pressure hydrogen service

  3. Statistical physics ""Beyond equilibrium

    SciTech Connect (OSTI)

    Ecke, Robert E

    2009-01-01

    The scientific challenges of the 21st century will increasingly involve competing interactions, geometric frustration, spatial and temporal intrinsic inhomogeneity, nanoscale structures, and interactions spanning many scales. We will focus on a broad class of emerging problems that will require new tools in non-equilibrium statistical physics and that will find application in new material functionality, in predicting complex spatial dynamics, and in understanding novel states of matter. Our work will encompass materials under extreme conditions involving elastic/plastic deformation, competing interactions, intrinsic inhomogeneity, frustration in condensed matter systems, scaling phenomena in disordered materials from glasses to granular matter, quantum chemistry applied to nano-scale materials, soft-matter materials, and spatio-temporal properties of both ordinary and complex fluids.

  4. Carl A. Gagliardi PHYSICS

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A. Gagliardi PHYSICS Fundamental interactions and nuclear astrophysics - Fellow, American Physical Society - Distinguished Achievement Award in Teaching, AFS, - Texas A&M John C. Hardy PHYSICS Fundamental interactions and exotic nuclei - Fellow, Royal Society of Canada - Fellow, American Physical Society Che Ming Ko PHYSICS Theoretical hadron physics and heavy-ion collisions - Humboldt Research Award - Fellow, American Physical Society Joseph B. Natowitz CHEMISTRY Heavy-ion reaction

  5. Cascade morphology transition in bcc metals

    SciTech Connect (OSTI)

    Setyawan, Wahyu; Selby, A.; Juslin, Niklas; Stoller, Roger E.; Wirth, Brian D.; Kurtz, Richard J.

    2015-06-10

    Energetic atom collisions in solids induce shockwaves with complex morphologies. In this paper, we establish the existence of a morphological transition in such cascades. The order parameter of the morphology is defined as the exponent, $b$, in the defect production curve as a function of cascade energy ($N_F$$ \\sim$$E_{MD}^b$). Response of different bcc metals can be compared in a consistent energy domain when the energy is normalized by the transition energy, $\\mu$, between the high- and the low-energy regime. Using Cr, Fe, Mo and W data, an empirical formula of $\\mu$ as a function of displacement threshold energy, $E_d$, is presented for bcc metals.

  6. Physics and Chemistry of Materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1 Physics and Chemistry of Materials Developing new science and technologies needed for the national security of the United States by understanding how basic forces operating at the atomic level manifest themselves in the properties of matter at the macroscopic level. Molecular docking simulations The influence of small organic molecules on the operation and mechanism of electron transfer in enzymatic anodes. Molecular docking simulations The influence of small organic molecules on the operation

  7. Physics Thrust Areas

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Thrust Areas Physics Thrust Areas Physics Division serves the nation through its broad portfolio of fundamental and applied research. Quality basic science research: critical component of maintaining our capabilities in national security research To further understand the physical world, generate new or improved technology in experimental physics, and establish a physics foundation for current and future Los Alamos programs, Physics Division leverages its expertise and experimental capabilities

  8. Descriptive Morphology Terms For MAMA software

    SciTech Connect (OSTI)

    Ruggiero, Christy E.; Porter, Reid B.

    2014-05-21

    The table on the following pages lists a set of morphology terms for describing materials. We have organized these terms by categories. Software uses are welcome to suggest other terms that are needed to accurately describe materials. This list is intended as a initial starting point to generating a consensus terminology list.

  9. Nuclear Physics: Recent Talks

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Free Electron Laser (FEL) Medical Imaging Physics Topics Campaigns Meetings Recent Talks Archived Talks Additional Information Computing at JLab Operations Logbook Physics Topics: ...

  10. Nuclear Physics: Meetings

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Physics Topics: Meetings Talks given at the Science & Technology Review 2004 Larry Cardman: Science Overview and the Experimental Program ppt | pdf Tony Thomas: Nuclear Physics ...

  11. Nuclear Physics: Campaigns

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Free-Electron Laser (FEL) Medical Imaging Physics Topics Campaigns The Structure of the Nuclear Building Blocks The Structure of Nuclei Symmetry Tests in Nuclear Physics Meetings ...

  12. UNIRIB: Physics Topics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Physics Topics Research Capitalizing on the strengths of nine collaborating research ... Ion Beam (UNIRIB) consortium is conducting research at the forefront of nuclear physics. ...

  13. Nuclear Physics: Experiment Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Physics Privacy and Security Notice Skip over navigation Search the JLab Site Nuclear Physics Program Please upgrade your browser. This site's design is only visible in a graphical ...

  14. Argonne Physics Division - ATLAS

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... equipped with the instruments required for precision nuclear and atomic physics research. ... Mass Analyzer (FMA), an atomic physics beam line, and two general purpose beam lines. ...

  15. Saturday Morning Physics - Talks

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Further information online Contemporary Physics Education Project Secret Worlds: The Universe within (Java animation) The Particle Adventure Particle Physics - Education and ...

  16. Computational Physics and Methods

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 Computational Physics and Methods Performing innovative simulations of physics phenomena on tomorrow's scientific computing platforms Growth and emissivity of young galaxy ...

  17. Office of Physical Protection

    Office of Energy Efficiency and Renewable Energy (EERE)

    The Office of Physical Protection is comprised of a team of security specialists engaged in providing Headquarters-wide physical protection.

  18. Argonne Physics Division - ATLAS

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Safety Tom Mullen, Physics Division Safety Engineer. Please Note: If you have any comments or concerns regarding safety at ATLAS, please contact the Physics Division Safety ...

  19. Experimental Physical Sciences

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in Physics, Chair ASM International, Board of Trustees Association for Iron & Steel Technology, Board of Directors National Science Foundation, Condensed Matter Physics, Program...

  20. ORISE: Health Physics Training

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Health Physics Training Student performs an analysis during an ORAU health physics training course Training and educating a highly skilled workforce that can meet operational ...

  1. On phase equilibria and crystal structures in the systems Ce-Pd-B and Yb-Pd-B. Physical properties of R{sub 2}Pd{sub 13.6}B{sub 5} (R=Yb, Lu)

    SciTech Connect (OSTI)

    Sologub, Oksana; Rogl, Peter; Salamakha, Leonid; Bauer, Ernst; Hilscher, Gerfried; Michor, Herwig; Giester, Gerald

    2010-05-15

    binary Yb{sub 5}Pd{sub 2-x} (Mn{sub 5}C{sub 2}-type) was confirmed from X-ray single crystal data and a slight defect on the Pd site (x=0.06) was established. The three structures tau{sub 1}-Ce{sub 6}Pd{sub 47-x}B{sub 6}, tau{sub 2}-CePd{sub 8}B{sub 2-x} and tau{sub 3}-Ce{sub 3}Pd{sub 25-x}B{sub 8-y} are related and can be considered as the packings of fragments observed in Nd{sub 2}Fe{sub 14}B structure with different stacking of common structural blocks. Physical properties for Yb{sub 2}Pd{sub 13.6}B{sub 5} (temperature dependent specific heat, electrical resistivity and magnetization) yielded a predominantly Yb-4f{sup 13} electronic configuration, presumably related with a magnetic instability below 2 K. Kondo interaction and crystalline electric field effects control the paramagnetic temperature domain. - Graphical Abstract: Crystal structure of CePd{sub 8}B{sub 2-x}.

  2. Degradative and Morphological Characterization of POSS Modified...

    Office of Scientific and Technical Information (OSTI)

    Laboratory (LLNL), Livermore, CA Sponsoring Org: USDOE Country of Publication: United States Language: English Subject: 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY

  3. Historic Properties

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of its historic properties. The National Park Service would provide interpretation, education, and technical preservation assistance for properties at LANL. Potential Los...

  4. “Using Statistical Comparisons between SPartICus Cirrus Microphysical Measurements, Detailed Cloud Models, and GCM Cloud Parameterizations to Understand Physical Processes Controlling Cirrus Properties and to Improve the Cloud Parameterizations”

    SciTech Connect (OSTI)

    Woods, Sarah

    2015-12-01

    The dual objectives of this project were improving our basic understanding of processes that control cirrus microphysical properties and improvement of the representation of these processes in the parameterizations. A major effort in the proposed research was to integrate, calibrate, and better understand the uncertainties in all of these measurements.

  5. Rock Physics of Geologic Carbon Sequestration/Storage (Technical Report) |

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect Rock Physics of Geologic Carbon Sequestration/Storage Citation Details In-Document Search Title: Rock Physics of Geologic Carbon Sequestration/Storage This report covers the results of developing the rock physics theory of the effects of CO{sub 2} injection and storage in a host reservoir on the rock's elastic properties and the resulting seismic signatures (reflections) observed during sequestration and storage. Specific topics addressed are: (a) how the elastic properties

  6. High Energy Physics and Nuclear Physics Network Requirements...

    Office of Scientific and Technical Information (OSTI)

    Technical Report: High Energy Physics and Nuclear Physics Network Requirements Citation Details In-Document Search Title: High Energy Physics and Nuclear Physics Network ...

  7. physics-based-html

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Physics-based High-Resolution Numerical Modeling of Bridge Foundation Scour

  8. GAUSSIAN RANDOM FIELD: PHYSICAL ORIGIN OF SERSIC PROFILES

    SciTech Connect (OSTI)

    Cen, Renyue

    2014-08-01

    While the Sersic profile family provides adequate fits for the surface brightness profiles of observed galaxies, its physical origin is unknown. We show that if the cosmological density field is seeded by random Gaussian fluctuations, as in the standard cold dark matter model, galaxies with steep central profiles have simultaneously extended envelopes of shallow profiles in the outskirts, whereas galaxies with shallow central profiles are accompanied by steep density profiles in the outskirts. These properties are in accord with those of the Sersic profile family. Moreover, galaxies with steep central profiles form their central regions in smaller denser subunits that possibly merge subsequently, which naturally leads to the formation of bulges. In contrast, galaxies with shallow central profiles form their central regions in a coherent fashion without significant substructure, a necessary condition for disk galaxy formation. Thus, the scenario is self-consistent with respect to the correlation between observed galaxy morphology and the Sersic index. We further predict that clusters of galaxies should display a similar trend, which should be verifiable observationally.

  9. Experimental Particle Physics

    SciTech Connect (OSTI)

    Rosenfeld, Carl; Mishra, Sanjib R.; Petti, Roberto; Purohit, Milind V.

    2014-08-31

    The high energy physics group at the University of South Carolina, under the leadership of Profs. S.R. Mishra, R. Petti, M.V. Purohit, J.R. Wilson (co-PI's), and C. Rosenfeld (PI), engaged in studies in "Experimental Particle Physics." The group collaborated with similar groups at other universities and at national laboratories to conduct experimental studies of elementary particle properties. We utilized the particle accelerators at the Fermi National Accelerator Laboratory (Fermilab) in Illinois, the Stanford Linear Accelerator Center (SLAC) in California, and the European Center for Nuclear Research (CERN) in Switzerland. Mishra, Rosenfeld, and Petti worked predominantly on neutrino experiments. Experiments conducted in the last fifteen years that used cosmic rays and the core of the sun as a source of neutrinos showed conclusively that, contrary to the former conventional wisdom, the "flavor" of a neutrino is not immutable. A neutrino of flavor "e," "mu," or "tau," as determined from its provenance, may swap its identity with one of the other flavors -- in our jargon, they "oscillate." The oscillation phenomenon is extraordinarily difficult to study because neutrino interactions with our instruments are exceedingly rare -- they travel through the earth mostly unimpeded -- and because they must travel great distances before a substantial proportion have made the identity swap. Three of the experiments that we worked on, MINOS, NOvA, and LBNE utilize a beam of neutrinos from an accelerator at Fermilab to determine the parameters governing the oscillation. Two other experiments that we worked on, NOMAD and MIPP, provide measurements supportive of the oscillation experiments. Good measurements of the neutrino oscillation parameters may constitute a "low energy window" on related phenomena that are otherwise unobservable because they would occur only at energies way above the reach of conceivable accelerators. Purohit and Wilson participated in the BaBar experiment

  10. Morphologically and size uniform monodisperse particles and their shape-directed self-assembly

    DOE Patents [OSTI]

    Collins, Joshua E.; Bell, Howard Y.; Ye, Xingchen; Murray, Christopher Bruce

    2015-11-17

    Monodisperse particles having: a single pure crystalline phase of a rare earth-containing lattice, a uniform three-dimensional size, and a uniform polyhedral morphology are disclosed. Due to their uniform size and shape, the monodisperse particles self assemble into superlattices. The particles may be luminescent particles such as down-converting phosphor particles and up-converting phosphors. The monodisperse particles of the invention have a rare earth-containing lattice which in one embodiment may be an yttrium-containing lattice or in another may be a lanthanide-containing lattice. The monodisperse particles may have different optical properties based on their composition, their size, and/or their morphology (or shape). Also disclosed is a combination of at least two types of monodisperse particles, where each type is a plurality of monodisperse particles having a single pure crystalline phase of a rare earth-containing lattice, a uniform three-dimensional size, and a uniform polyhedral morphology; and where the types of monodisperse particles differ from one another by composition, by size, or by morphology. In a preferred embodiment, the types of monodisperse particles have the same composition but different morphologies. Methods of making and methods of using the monodisperse particles are disclosed.