National Library of Energy BETA

Sample records for monoxide particulate matter

  1. Investigation of Direct Injection Vehicle Particulate Matter...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Direct Injection Vehicle Particulate Matter Emissions Investigation of Direct Injection Vehicle Particulate Matter Emissions This study focuses primarily on particulate matter mass ...

  2. Rigid particulate matter sensor

    DOE Patents [OSTI]

    Hall, Matthew (Austin, TX)

    2011-02-22

    A sensor to detect particulate matter. The sensor includes a first rigid tube, a second rigid tube, a detection surface electrode, and a bias surface electrode. The second rigid tube is mounted substantially parallel to the first rigid tube. The detection surface electrode is disposed on an outer surface of the first rigid tube. The detection surface electrode is disposed to face the second rigid tube. The bias surface electrode is disposed on an outer surface of the second rigid tube. The bias surface electrode is disposed to face the detection surface electrode on the first rigid tube. An air gap exists between the detection surface electrode and the bias surface electrode to allow particulate matter within an exhaust stream to flow between the detection and bias surface electrodes.

  3. Apparatus for particulate matter analysis

    DOE Patents [OSTI]

    Gundel, Lara A.; Apte, Michael G.; Hansen, Anthony D.; Black, Douglas R.

    2007-01-30

    The apparatus described herein is a miniaturized system for particle exposure assessment (MSPEA) for the quantitative measurement and qualitative identification of particulate content in gases. The present invention utilizes a quartz crystal microbalance (QCM) or other mass-sensitive temperature compensated acoustic wave resonator for mass measurement. Detectors and probes and light sources are used in combination for the qualitative determination of particulate matter.

  4. Advanced particulate matter control apparatus and methods

    DOE Patents [OSTI]

    Miller, Stanley J. (Grand Forks, ND); Zhuang, Ye (Grand Forks, ND); Almlie, Jay C. (East Grand Forks, MN)

    2012-01-10

    Apparatus and methods for collection and removal of particulate matter, including fine particulate matter, from a gas stream, comprising a unique combination of high collection efficiency and ultralow pressure drop across the filter. The apparatus and method utilize simultaneous electrostatic precipitation and membrane filtration of a particular pore size, wherein electrostatic collection and filtration occur on the same surface.

  5. Reduction of Transient Particulate Matter Spikes with Decision...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Transient Particulate Matter Spikes with Decision Tree Based Control Reduction of Transient Particulate Matter Spikes with Decision Tree Based Control Using a non-parametric ...

  6. Particulate matter pollution in Mexico City

    SciTech Connect (OSTI)

    Vega R, E.; Mora P, V.; Mugica A, V.

    1998-12-31

    The levels of particulate matter are of concern since they may induce severe effects on public health and is the second atmospheric pollution problem in Mexico City. Another noticeable effect in large cities attributable to particulate matter, is the deterioration of visibility. In this paper the analysis of the data of TSP and PM10 during 1988 to 1996 is presented. The seasonal variation of particulate matter, the typical ratios of PM10/TSP and relationships of the two variables were determined. It was found that PM10 concentrations show an important tendency to decrease during this period, due to some control strategies, although this is not the case for TSP. The monthly trend exhibits a clear relationship with the dry (October through April) and wet (May through September) seasons. The particulate matter concentrations are lower during the wet season. The hourly behavior shows that the highest concentrations are correlated with the traffic rush hours. The most TSP polluted area was the northeast, meanwhile the southeast is the most PM10 polluted area. There is a clear evidence of the particulate matter transportation from these areas to other sites of the City.

  7. Effects of Advanced Combustion Technologies on Particulate Matter Emissions

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Characteristics | Department of Energy Advanced Combustion Technologies on Particulate Matter Emissions Characteristics Effects of Advanced Combustion Technologies on Particulate Matter Emissions Characteristics Findings of important implications for aftertreatment devices such as EGR coolers and diesel particulate filters, of physico-chemical changes observed in particulate matter during advanced combustion. PDF icon deer08_storey.pdf More Documents & Publications Measurement and

  8. Particulate matter sensor with a heater

    DOE Patents [OSTI]

    Hall, Matthew (Austin, TX)

    2011-08-16

    An apparatus to detect particulate matter. The apparatus includes a sensor electrode, a shroud, and a heater. The electrode measures a chemical composition within an exhaust stream. The shroud surrounds at least a portion of the sensor electrode, exclusive of a distal end of the sensor electrode exposed to the exhaust stream. The shroud defines an air gap between the sensor electrode and the shroud and an opening toward the distal end of the sensor electrode. The heater is mounted relative to the sensor electrode. The heater burns off particulate matter in the air gap between the sensor electrode and the shroud.

  9. Investigation of Direct Injection Vehicle Particulate Matter Emissions |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Direct Injection Vehicle Particulate Matter Emissions Investigation of Direct Injection Vehicle Particulate Matter Emissions This study focuses primarily on particulate matter mass analysis of a gasoline direct injection engine in a test cell with a chassis dynamometer. PDF icon p-10_gibbs.pdf More Documents & Publications On-Road PM Mass Emission Measured with OBS-TRPM Performance of the Low-Efficiency Diesel Particulate Filter for Diesel PM Reduction Reducing the

  10. Fuel-Neutral Studies of Particulate Matter Transport Emissions...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon ace056stewart2011o.pdf More Documents & Publications Fuel-Neutral Studies of Particulate Matter ...

  11. Method for removing particulate matter from a gas stream

    DOE Patents [OSTI]

    Postma, Arlin K. (Benton City, WA)

    1984-01-01

    Particulate matter is removed from a stream of pressurized gas by directing the stream of gas upwardly through a bed of porous material, the porous bed being held in an open ended container and at least partially submerged in liquid. The passage of the gas through the porous bed sets up a circulation in the liquid which cleans the particulate matter from the bed.

  12. On-Board Engine Exhaust Particulate Matter Sensor for HCCI and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Engine Exhaust Particulate Matter Sensor for HCCI and Conventional Diesel Engines On-Board Engine Exhaust Particulate Matter Sensor for HCCI and Conventional Diesel Engines 2009...

  13. Accelerated Extraction of Diesel Particulate Matter SOF | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Extraction of Diesel Particulate Matter SOF Accelerated Extraction of Diesel Particulate Matter SOF Poster presentation at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August, 2007, Detroit, Michigan. Sponsored by the U.S. Department of Energy's (DOE) Office of FreedomCAR and Vehicle Technologies (OFCVT). PDF icon deer07_lewis.pdf More Documents & Publications Chemical Analysis of Soot Using Thermal Desorption/Pyrolysis Gas

  14. Reduction of Transient Particulate Matter Spikes with Decision Tree Based

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Control | Department of Energy Transient Particulate Matter Spikes with Decision Tree Based Control Reduction of Transient Particulate Matter Spikes with Decision Tree Based Control Using a non-parametric decision tree to measure transient PM could correctly identify 94% of high opacity spikes and used to take targeted action to reduce PM without affecting NOx. PDF icon deer12_brahma.pdf More Documents & Publications New Demands on Heavy Duty Engine Management Systems An Enabling Study

  15. Concentrations and Size Distributions of Particulate Matter Emissions from

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Catalyzed Trap-Equipped Heavy-duty Diesel Vehicles Operating on Ultra-low Sulfur EC-D Fuel | Department of Energy Concentrations and Size Distributions of Particulate Matter Emissions from Catalyzed Trap-Equipped Heavy-duty Diesel Vehicles Operating on Ultra-low Sulfur EC-D Fuel Concentrations and Size Distributions of Particulate Matter Emissions from Catalyzed Trap-Equipped Heavy-duty Diesel Vehicles Operating on Ultra-low Sulfur EC-D Fuel 2002 DEER Conference Presentation: West Virginia

  16. Particulate Matter Characteristics for Highly Dilute Stoichiometric GDI

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Engine Operations | Department of Energy Matter Characteristics for Highly Dilute Stoichiometric GDI Engine Operations Particulate Matter Characteristics for Highly Dilute Stoichiometric GDI Engine Operations The overall goal of this study is to help identify which conditions and potential mechanisms impede soot formation in GDI operations. PDF icon p-24_storey.pdf More Documents & Publications Ethanol Effects on Lean-Burn and Stoichiometric GDI Emissions Effects of Advanced Combustion

  17. Electrically heated particulate matter filter with recessed inlet end plugs

    DOE Patents [OSTI]

    Gonze, Eugene V. (Pinckney, MI); Ament, Frank (Troy, MI)

    2012-02-21

    A particulate matter (PM) filter includes filter walls having inlet ends and outlet ends. First adjacent pairs of the filter walls define inlet channels. Second adjacent pairs of the filter walls define outlet channels. Outlet end plugs are arranged in the inlet channels adjacent to the output ends. Inlet end plugs arranged in the outlet channels spaced from the inlet ends.

  18. Inductively heated particulate matter filter regeneration control system

    DOE Patents [OSTI]

    Gonze, Eugene V; Paratore Jr., Michael J; Kirby, Kevin W; Phelps, Amanda; Gregoire, Daniel J

    2012-10-23

    A system includes a particulate matter (PM) filter with an upstream end for receiving exhaust gas, a downstream end and zones. The system also includes a heating element. A control module selectively activates the heating element to inductively heat one of the zones.

  19. Fuel-Neutral Studies of Particulate Matter Transport Emissions | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy 1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon ace056_stewart_2011_o.pdf More Documents & Publications Fuel-Neutral Studies of Particulate Matter Transport Emissions

  20. Biodiesel Fuel Property Effects on Particulate Matter Reactivity

    SciTech Connect (OSTI)

    Williams, A.; Black, S.; McCormick, R. L.

    2010-06-01

    Controlling diesel particulate emissions to meet the 2007 U.S. standard requires the use of a diesel particulate filter (DPF). The reactivity of soot, or the carbon fraction of particulate matter, in the DPF and the kinetics of soot oxidation are important in achieving better control of aftertreatment devices. Studies showed that biodiesel in the fuel can increase soot reactivity. This study therefore investigated which biodiesel fuel properties impact reactivity. Three fuel properties of interest included fuel oxygen content and functionality, fuel aromatic content, and the presence of alkali metals. To determine fuel effects on soot reactivity, the performance of a catalyzed DPF was measured with different test fuels through engine testing and thermo-gravimetric analysis. Results showed no dependence on the aromatic content or the presence of alkali metals in the fuel. The presence and form of fuel oxygen was the dominant contributor to faster DPF regeneration times and soot reactivity.

  1. Apparatus for removal of particulate matter from gas streams

    DOE Patents [OSTI]

    Smith, Peyton L. (Baton Rouge, LA); Morse, John C. (Baton Rouge, LA)

    2000-01-01

    An apparatus for the removal of particulate matter from the gaseous product stream of an entrained flow coal gasifier which apparatus includes an initial screen, an intermediate screen which is aligned with the direction of flow of the gaseous product stream and a final screen transversely disposed to the flow of gaseous product and which apparatus is capable of withstanding at least a pressure differential of about 10 psi (68.95 kPa) or greater at the temperatures of the gaseous product stream.

  2. Ash reduction system using electrically heated particulate matter filter

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI; Paratore, Jr., Michael J; He, Yongsheng [Sterling Heights, MI

    2011-08-16

    A control system for reducing ash comprises a temperature estimator module that estimates a temperature of an electrically heated particulate matter (PM) filter. A temperature and position estimator module estimates a position and temperature of an oxidation wave within the electrically heated PM filter. An ash reduction control module adjusts at least one of exhaust flow, fuel and oxygen levels in the electrically heated PM filter to adjust a position of the oxidation wave within the electrically heated PM filter based on the oxidation wave temperature and position.

  3. Low exhaust temperature electrically heated particulate matter filter system

    DOE Patents [OSTI]

    Gonze, Eugene V. (Pinckney, MI); Paratore, Jr., Michael J. (Howell, MI); Bhatia, Garima (Bangalore, IN)

    2012-02-14

    A system includes a particulate matter (PM) filter, a sensor, a heating element, and a control module. The PM filter includes with an upstream end that receives exhaust gas, a downstream end and multiple zones. The sensor detects a temperature of the exhaust gas. The control module controls current to the heating element to convection heat one of the zones and initiate a regeneration process. The control module selectively increases current to the heating element relative to a reference regeneration current level when the temperature is less than a predetermined temperature.

  4. Elevated exhaust temperature, zoned, electrically-heated particulate matter filter

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI; Bhatia, Garima [Bangalore, IN

    2012-04-17

    A system includes an electrical heater and a particulate matter (PM) filter that is arranged one of adjacent to and in contact with the electrical heater. A control module selectively increases an exhaust gas temperature of an engine to a first temperature and that initiates regeneration of the PM filter using the electrical heater while the exhaust gas temperature is above the first temperature. The first temperature is greater than a maximum exhaust gas temperature at the PM filter during non-regeneration operation and is less than an oxidation temperature of the PM.

  5. Wireless zoned particulate matter filter regeneration control system

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI; Kirby, Kevin W [Calabasas Hills, CA; Phelps, Amanda [Malibu, CA

    2011-10-04

    An assembly includes a particulate matter (PM) filter that comprises an upstream end for receiving exhaust gas, a downstream end and multiple zones. An absorbing layer absorbs microwave energy in one of N frequency ranges and is arranged with the upstream end. N is an integer. A frequency selective filter has M frequency selective segments and receives microwave energy in the N frequency ranges. M is an integer. One of the M frequency selective segments permits passage of the microwave energy in one of the N frequency ranges and does not permit passage of microwave energy in the other of the N frequency ranges.

  6. On-Board Engine Exhaust Particulate Matter Sensor for HCCI and Conventional

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Diesel Engines | Department of Energy Engine Exhaust Particulate Matter Sensor for HCCI and Conventional Diesel Engines On-Board Engine Exhaust Particulate Matter Sensor for HCCI and Conventional Diesel Engines 2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. PDF icon ace_44_hall.pdf More Documents & Publications Development and Demonstration of an Electronic Particulate Matter Sensor for Both

  7. Active DPF for Off-Road Particulate Matter (PM) Control | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy DPF for Off-Road Particulate Matter (PM) Control Active DPF for Off-Road Particulate Matter (PM) Control This presentation details how a possibly catalyzed active diesel particulate filter can be used to control off-road particulate matter. PDF icon deer08_servati.pdf More Documents & Publications DPF for a Tractor Auxiliary Power Unit A Low-Cost Continuous Emissions Monitoring System for Mobile and Stationary Engine SCR/DPF Applications/Data-Logger for Vehicle Data Acquisition

  8. High exhaust temperature, zoned, electrically-heated particulate matter filter

    DOE Patents [OSTI]

    Gonze, Eugene V.; Paratore, Jr., Michael J.; Bhatia, Garima

    2015-09-22

    A system includes a particulate matter (PM) filter, an electric heater, and a control circuit. The electric heater includes multiple zones, which each correspond to longitudinal zones along a length of the PM filter. A first zone includes multiple discontinuous sub-zones. The control circuit determines whether regeneration is needed based on an estimated level of loading of the PM filter and an exhaust flow rate. In response to a determination that regeneration is needed, the control circuit: controls an operating parameter of an engine to increase an exhaust temperature to a first temperature during a first period; after the first period, activates the first zone; deactivates the first zone in response to a minimum filter face temperature being reached; subsequent to deactivating the first zone, activates a second zone; and deactivates the second zone in response to the minimum filter face temperature being reached.

  9. Development and Demonstration of an Electronic Particulate Matter...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Aftertreatment and Low Pressure Loop EGR Applied to an Off-Highway Engine Advanced Radio Frequency-Based Sensors for Monitoring Diesel Particulate Filter Loading and...

  10. On-Board Engine Exhaust Particulate Matter Sensor for HCCI and Conventional Diesel Engines

    SciTech Connect (OSTI)

    Hall, Matt; Matthews, Ron

    2011-09-30

    The goal of the research was to refine and complete development of an on-board particulate matter (PM) sensor for diesel, DISI, and HCCI engines, bringing it to a point where it could be commercialized and marketed.

  11. Removal of residual particulate matter from filter media

    DOE Patents [OSTI]

    Almlie, Jay C; Miller, Stanley J

    2014-11-11

    A method for removing residual filter cakes that remain adhered to a filter after typical particulate removal methodologies have been employed, such as pulse-jet filter element cleaning, for all cleanable filters used for air pollution control, dust control, or powder control.

  12. Fuel-Neutral Studies of Particulate Matter Transport Emissions | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy 2 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon ace056_stewart_2012_o.pdf More Documents & Publications Characterization of Pre-Commercial Gasoline Engine Particulates Through Advanced Aerosol Methods

  13. Effects of solar radiation on organic matter cycling: Formation of carbon monoxide and carbonyl sulfide (Chapter 11). Book chapter

    SciTech Connect (OSTI)

    Zepp, R.G.

    1994-01-01

    The effects of photoinduced processes on carbon cycling and the biospheric emission of two important trace carbon gases--carbon monoxide and carbonyl sulfide--are examined. Both of these gases are likely to play an important role in the biospheric feedbacks that may reinforce or attenuate future changes in climate. Evidence is presented to support the hypothesis that a significant fraction of the global sources of both of these gases derives from the photochemical fragmentation of decayed plant materials and other biogenic organic matter in terrestrial and marine environments.

  14. Development of a Low-Cost Particulate Matter Monitor

    SciTech Connect (OSTI)

    White, Richard M.; Apte, Michael G.; Gundel, Lara A.; Black, Justin

    2008-08-01

    We describe a small, inexpensive portable monitor for airborne particulates, composed of the following elements: a. A simple size-selective inlet (vertical elutriator) that permits only particles below a pre-set diameter to pass and enter the measurement section; b. A measurement section in which passing particles are deposited thermophoretically on a micro-fabricated resonant piezoelectric mass sensor; c. An optical characterization module co-located with the mass sensor module that directs infrared and ultraviolet beams through the deposit. The emergent optical beams are detected by a photodiode. The optical absorption of the deposit can be measured in order to characterize the deposit, and determine how much is due to diesel exhaust and/or environmental tobacco smoke; and d. A small pump that moves air through the device, which may also be operated in a passive mode. The component modules were designed by the project team, and fabricated at UCB andLBNL. Testing and validation were performed in a room-sized environmental chamber at LBNL in to which was added either environmental tobacco smoke (ETS, produced by a cigarette smoking machine) or diesel exhaust (from a conventional diesel engine). Two pilot field tests in a dwelling compared the monitor with existing aerosol instruments during exposure to infiltrated ambient air to which cigarette smoke, diesel exhaust, wood smoke and cooking fumes were added. The limit of detection (LOD) derived from statistical analysis of field data is 18 mu g m-3, at the 99percent confidence level. The monitor weighs less than 120 g and has a volume of roughly 250 cm3. Power consumption is approximately 100 milliwatts. During this study, the optical component of the device was not fully implemented and has been left for future efforts. Suggested improvements in the current prototype include use of integrated thermal correction, reconfiguration of the resonator for increased particle collection area, increased thermophoretic collection efficiency using an increased temperature gradient, and shielding the resonator electronics from deposition of ultrafine particles.

  15. Measurements of particulate matter concentrations at a landfill site (Crete, Greece)

    SciTech Connect (OSTI)

    Chalvatzaki, E.; Kopanakis, I.; Kontaksakis, M.; Glytsos, T.; Kalogerakis, N.; Lazaridis, M.

    2010-11-15

    Large amounts of solid waste are disposed in landfills and the potential of particulate matter (PM) emissions into the atmosphere is significant. Particulate matter emissions in landfills are the result of resuspension from the disposed waste and other activities such as mechanical recycling and composting, waste unloading and sorting, the process of coating residues and waste transport by trucks. Measurements of ambient levels of inhalable particulate matter (PM{sub 10}) were performed in a landfill site located at Chania (Crete, Greece). Elevated PM{sub 10} concentrations were measured in the landfill site during several landfill operations. It was observed that the meteorological conditions (mainly wind velocity and temperature) influence considerably the PM{sub 10} concentrations. Comparison between the PM{sub 10} concentrations at the landfill and at a PM{sub 10} background site indicates the influence of the landfill activities on local concentrations at the landfill. No correlation was observed between the measurements at the landfill and the background sites. Finally, specific preventing measures are proposed to control the PM concentrations in landfills.

  16. Assessment of Contribution of Contemporary Carbon Sources to Size-Fractionated Particulate Matter and Time-Resolved Bulk Particulate Matter Using the Measurement of Radiocarbon

    SciTech Connect (OSTI)

    Hwang, H M; Young, T M; Buchholz, B A

    2009-04-16

    This study was motivated by a desire to improve understanding of the sources contributing to the carbon that is an important component of airborne particulate matter (PM). The ultimate goal of this project was to lay a ground work for future tools that might be easily implemented with archived or routinely collected samples. A key feature of this study was application of radiocarbon measurement that can be interpreted to indicate the relative contributions from fossil and non-fossil carbon sources of atmospheric PM. Size-resolved PM and time-resolved PM{sub 10} collected from a site in Sacramento, CA in November 2007 (Phase I) and March 2008 (Phase II) were analyzed for radiocarbon and source markers such as levoglucosan, cholesterol, and elemental carbon. Radiocarbon data indicates that the contributions of non-fossil carbon sources were much greater than that from fossil carbon sources in all samples. Radiocarbon and source marker measurements confirm that a greater contribution of non-fossil carbon sources in Phase I samples was highly likely due to residential wood combustion. The present study proves that measurement of radiocarbon and source markers can be readily applied to archived or routinely collected samples for better characterization of PM sources. More accurate source apportionment will support ARB in developing more efficient control strategies.

  17. Implications of Low Particulate Matter Emissions on System Fuel Efficiency for High Efficiency Clean Combustion

    SciTech Connect (OSTI)

    Parks, II, James E; Prikhodko, Vitaly Y

    2009-01-01

    Advanced diesel combustion regimes such as High Efficiency Clean Combustion (HECC) offer the benefits of reduced engine out NOX and particulate matter (PM) emissions. Lower PM emissions during advanced combustion reduce the demand on diesel particulate filters (DPFs) and can, thereby, reduce the fuel penalty associated with DPF regeneration. In this study, a SiC DPF was loaded and regenerated on a 1.7-liter 4-cylinder diesel engine operated in conventional and advanced combustion modes at different speed and load conditions. A diesel oxidation catalyst (DOC) and a lean NOX trap (LNT) were also installed in the exhaust stream. Five steady-state speed and load conditions were weighted to estimate Federal Test Procedure (FTP) fuel efficiency. The DPF was loaded using lean-rich cycling with frequencies that resulted in similar levels of NOX emissions downstream of the LNT. The pressure drop across the DPF was measured at a standard point (1500 rpm, 5.0 bar) before and after loading, and a P rise rate was determined for comparison between conventional and advanced combustion modes. Higher PM emissions in conventional combustion resulted in a higher rate of backpressure rise across the DPF at all of the load points leading to more frequent DPF regenerations and higher fuel penalty. The fuel penalty during conventional combustion was 4.2% compared with 3.1% for a mixture of conventional and advanced modes.

  18. SIZE DISTRIBUTION AND RATE OF PRODUCTION OF AIRBORNE PARTICULATE MATTER GENERATED DURING METAL CUTTING

    SciTech Connect (OSTI)

    M.A. Ebadian, Ph.D.; S.K. Dua, Ph.D., C.H.P.; Hillol Guha, Ph.D.

    2001-01-01

    During deactivation and decommissioning activities, thermal cutting tools, such as plasma torch, laser, and gasoline torch, are used to cut metals. These activities generate fumes, smoke and particulates. These airborne species of matter, called aerosols, may be inhaled if suitable respiratory protection is not used. Inhalation of the airborne metallic aerosols has been reported to cause ill health effects, such as acute respiratory syndrome and chromosome damage in lymphocytes. In the nuclear industry, metals may be contaminated with radioactive materials. Cutting these metals, as in size reduction of gloveboxes and tanks, produces high concentrations of airborne transuranic particles. Particles of the respirable size range (size < 10 {micro}m) deposit in various compartments of the respiratory tract, the fraction and the site in the respiratory tract depending on the size of the particles. The dose delivered to the respiratory tract depends on the size distribution of the airborne particulates (aerosols) and their concentration and radioactivity/toxicity. The concentration of airborne particulate matter in an environment is dependent upon the rate of their production and the ventilation rate. Thus, measuring aerosol size distribution and generation rate is important for (1) the assessment of inhalation exposures of workers, (2) the selection of respiratory protection equipment, and (3) the design of appropriate filtration systems. Size distribution of the aerosols generated during cutting of different metals by plasma torch was measured. Cutting rates of different metals, rate of generation of respirable mass, as well as the fraction of the released kerf that become respirable were determined. This report presents results of these studies. Measurements of the particles generated during cutting of metal plates with a plasma arc torch revealed the presence of particles with mass median aerodynamic diameters of particles close to 0.2 {micro}m, arising from condensation of vaporized material and subsequent rapid formation of aggregates. Particles of larger size, resulting from ejection of melted material or fragments from the cutting zone, were also observed. This study presents data regarding the metal cutting rate, particle size distribution, and their generation rate, while using different cutting tools and metals. The study shows that respirable particles constitute only a small fraction of the released kerf.

  19. Sub-micrometre Particulate Matter is Primarily in Liquid Form over Amazon Rainforests

    SciTech Connect (OSTI)

    Bateman, Adam P.; Gong, Z. H.; Liu, Pengfei; Sato, Bruno; Cirino, Glauber; Zhang, Yue; Artaxo, Paulo; Bertram, Allan K.; Manzi, A.; Rizzo, L. V.; Souza, Rodrigo A.; Zaveri, Rahul A.; Martin, Scot T.

    2016-01-01

    Particulate matter (PM) occurs in the Earth’s atmosphere both in liquid and non-liquid forms. The physical state affects the available physical and chemical mechanisms of growth and reactivity, ultimately affecting the number, size, and composition of the atmospheric particle population. Herein, the physical state, including the response to relative humidity (RH), was investigated on-line and in real time for PM (< 1 μm) over the tropical rain forest of central Amazonia during both the wet and dry seasons of 2013. The results show that the PM was liquid for RH > 80% across 296 to 300 K. These results, in conjunction with the distributions of RH and temperature in Amazonia, imply that near-surface submicron PM in Amazonia is liquid most of the time. The observations are consistent with laboratory experiments showing that PM produced by isoprene photo-oxidation is liquid across these meteorological conditions. The findings have implications for the mechanisms of new particle production in Amazonia, the growth of submicron particles and hence dynamics of the cloud life cycle, and the sensitivity of these processes to anthropogenic activities. An approach for inclusion of particle physical state in chemical transport models is presented.

  20. Cytotoxicity of settling particulate matter and sediments of the Neckar River (Germany) during a winter flood

    SciTech Connect (OSTI)

    Hollert, H.; Duerr, M.; Erdinger, L.; Braunbeck, T.

    2000-03-01

    To investigate the cytotoxic and genotoxic potentials of settling particulate matter (SPM) carried by the Neckar River, a well-studied model for a lock-regulated river in central Europe, during a flood, acute cytotoxicity was investigated using the fibroblast-like fish cell line RTG-2 with the neutral red retention, the succinic acid dehydrogenase (MTT), and the lactatedehydrogenase (LDH) release assays as well as microscopic inspection as endpoints. Genotoxicity of water, pore water, sediments, and SPM were assessed using the Ames test. Different extraction methods (Soxhlet extraction with solvents of variable polarity as well as a fluid/fluid extraction according to pH) in addition to a supplementation of biotests with 59 fractions from the liver of {beta}-naphthoflavone/phenobarbital-induced rats allowed a further characterization of the biological damage. Both sediments and SPM extracts caused cytotoxic effects in RTG-2 cells. Cytotoxicity was found to increase significantly with polarity of extracting solvents. Following extraction according to pH, cytotoxicity could be attributed mainly to neutral substances, whereas the slightly acid and basic fractions already showed little or no cytotoxicity. Samples taken during the period of flood rise showed the highest cytotoxic activities. Cytotoxicity was significantly enhanced by the addition of S9 preparations. In contrast, no genotoxic activity was found in native surface waters, pore waters, and SPM.

  1. Characterization of Fine Particulate Matter (PM) and Secondary PM Precursor Gases in the Mexico City Metropolitan Area

    SciTech Connect (OSTI)

    Molina, Luisa T.; Molina, Mario J.; Volkamer, Rainer; de Foy, Benjamin; Lei, Wenfang; Zavaka, Miguel; Velasco, Erik

    2008-10-31

    This project was one of three collaborating grants funded by DOE/ASP to characterize the fine particulate matter (PM) and secondary PM precursors in the Mexico City Metropolitan Area (MCMA) during the MILAGRO Campaign. The overall effort of MCMA-2006, one of the four components, focused on i) examination of the primary emissions of fine particles and precursor gases leading to photochemical production of atmospheric oxidants and secondary aerosol particles; ii) measurement and analysis of secondary oxidants and secondary fine PM production, with particular emphasis on secondary organic aerosol (SOA), and iii) evaluation of the photochemical and meteorological processes characteristic of the Mexico City Basin. The collaborative teams pursued the goals through three main tasks: i) analyses of fine PM and secondary PM precursor gaseous species data taken during the MCMA-2002/2003 campaigns and preparation of publications; ii) planning of the MILAGRO Campaign and deployment of the instrument around the MCMA; and iii) analysis of MCMA-2006 data and publication preparation. The measurement phase of the MILAGRO Campaign was successfully completed in March 2006 with excellent participation from the international scientific community and outstanding cooperation from the Mexican government agencies and institutions. The project reported here was led by the Massachusetts Institute of Technology/Molina Center for Energy and the Environment (MIT/MCE2) team and coordinated with DOE/ASP-funded collaborators at Aerodyne Research Inc., University of Colorado at Boulder and Montana State University. Currently 24 papers documenting the findings from this project have been published. The results from the project have improved significantly our understanding of the meteorological and photochemical processes contributing to the formation of ozone, secondary aerosols and other pollutants. Key findings from the MCMA-2003 include a vastly improved speciated emissions inventory from on-road vehicles: the MCMA motor vehicles produce abundant amounts of primary PM, elemental carbon, particle-bound polycyclic aromatic hydrocarbons, carbon monoxide and a wide range of air toxics; the feasibility of using eddy covariance techniques to measure fluxes of volatile organic compounds in an urban core and a valuable tool for validating local emissions inventory; a much better understanding of the sources and atmospheric loadings of volatile organic compounds; the first spectroscopic detection of glyoxal in the atmosphere; a unique analysis of the high fraction of ambient formaldehyde from primary emission sources; characterization of ozone formation and its sensitivity to VOCs and NOx; a much more extensive knowledge of the composition, size distribution and atmospheric mass loadings of both primary and secondary fine PM, including the fact that the rate of MCMA SOA production greatly exceeded that predicted by current atmospheric models; evaluations of significant errors that can arise from standard air quality monitors for O3 and NO2; and the implementation of an innovative Markov Chain Monte Carlo method for inorganic aerosol modeling as a powerful tool to analyze aerosol data and predict gas phase concentrations where these are unavailable. During the MILAGRO Campaign the collaborative team utilized a combination of central fixed sites and a mobile laboratory deployed throughout the MCMA to representative urban and boundary sites to measure trace gases and fine particles. Analysis of the extensive 2006 data sets has confirmed the key findings from MCMA-2002/2003; additionally MCMA-2006 provided more detailed gas and aerosol chemistry and wider regional scale coverage. Key results include an updated 2006 emissions inventory; extension of the flux system to measure fluxes of fine particles; better understanding of the sources and apportionment of aerosols, including contribution from biomass burning and industrial sources; a comprehensive evaluation of metal containing particles in a com

  2. SOURCE SIGNATURES OF FINE PARTICULATE MATTER FROM PETROLEUM REFINING AND FUEL USE

    SciTech Connect (OSTI)

    Gerald P. Huffman; Frank E. Huggins; Naresh Shah; Artur Braun; Yuanzhi Chen; J. David Robertson; Joseph Kyger; Adel F. Sarofim; Ronald J. Pugmire; Henk L.C. Meuzelaar; JoAnn Lighty

    2003-07-31

    The molecular structure and microstructure of a suite of fine particulate matter (PM) samples produced by the combustion of residual fuel oil and diesel fuel were investigated by an array of analytical techniques. Some of the more important results are summarized below. Diesel PM (DPM): A small diesel engine test facility was used to generate a suite of diesel PM samples from different fuels under engine load and idle conditions. C XANES, {sup 13}C NMR, XRD, and TGA were in accord that the samples produced under engine load conditions contained more graphitic material than those produced under idle conditions, which contained a larger amount of unburned diesel fuel and lubricating oil. The difference was enhanced by the addition of 5% of oxygenated compounds to the reference fuel. Scanning transmission x-ray micro-spectroscopy (STXM) was able to distinguish particulate regions rich in C=C bonds from regions rich in C-H bonds with a resolution of {approx}50 nm. The former are representative of more graphitic regions and the latter of regions rich in unburned fuel and oil. The dominant microstructure observed by SEM and TEM consisted of complex chain-like structures of PM globules {approx}20-100 nm in mean diameter, with a high fractal dimension. High resolution TEM revealed that the graphitic part of the diesel soot consisted of onion-like structures made up of graphene layers. Typically 3-10 graphene layers make up the ''onion rings'', with the layer spacing decreasing as the number of layers increases. ROFA PM: Residual oil fly ash (ROFA) PM has been analyzed by a new approach that combines XAFS spectroscopy with selective leaching procedures. ROFA PM{sub 2.5} and PM{sub 2.5+} produced in combustion facilities at the U.S. EPA National Risk Management Research Laboratory (NRML) were analyzed by XAFS before and after leaching with water, acid (1N HCl), and pentane. Both water and acid leaching removed most of the metal sulfates, which were the dominant phase present for most metals (V, Ni, Zn, etc.). This allowed conclusive identification in the leaching residue of important secondary sulfide and oxide phases, including Ni sulfide, a toxic and carcinogenic phase observed in the leached PM{sub 2.5+} samples. Other significant secondary phases identified included V{sub 2}O{sub 4}, V sulfide, and NiFe{sub 2}O{sub 4}.

  3. Cashew nut roasting: Chemical characterization of particulate matter and genotocixity analysis

    SciTech Connect (OSTI)

    Oliveira Galvo, Marcos Felipe de; Melo Cabral, Thiago de; Andr, Paulo Afonso de; Ftima Andrade, Maria de; Miranda, Regina Maura de; Saldiva, Paulo Hilrio Nascimento; Castro Vasconcellos, Prola de; Batistuzzo de Medeiros, Silvia Regina

    2014-05-01

    Background: Particulate matter (PM) is potentially harmful to health and related to genotoxic events, an increase in the number of hospitalizations and mortality from respiratory and cardiovascular diseases. The present study conducted the first characterization of elemental composition and polycyclic aromatic hydrocarbon (PAH) analysis of PM, as well as the biomonitoring of genotoxic activity associated to artisanal cashew nut roasting, an important economic and social activity worldwide. Methods: The levels of PM{sub 2.5} and black carbon were also measured by gravimetric analysis and light reflectance. The elemental composition was determined using X-ray fluorescence spectrometry and PAH analysis was carried out by gas chromatographymass spectrometry. Genotoxic activity was measured by the Tradescantia pallida micronucleus bioassay (Trad-MCN). Other biomarkers of DNA damage, such as nucleoplasmic bridges and nuclear fragments, were also quantified. Results: The mean amount of PM{sub 2.5} accumulated in the filters (January 2124.2 g/m{sup 3}; May 1022.2 g/m{sup 3}; September 1291.9 g/m{sup 3}), black carbon (January 363.6 g/m{sup 3}; May 70 g/m{sup 3}; September 69.4 g/m{sup 3}) and concentrations of Al, Si, P, S, Cl, K, Ca, Ti, Cr, Mn, Fe, Ni, Cu, Zn, Se, Br and Pb were significantly higher than the non-exposed area. Biomass burning tracers K, Cl, and S were the major inorganic compounds found. Benzo[k]fluoranthene, indene[1,2,3-c,d]pyrene, benzo[ghi]perylene, phenanthrene and benzo[b]fluoranthene were the most abundant PAHs. Mean benzo[a]pyrene-equivalent carcinogenic power values showed a significant cancer risk. The Trad-MCN bioassay revealed an increase in micronucleus frequency, 27 times higher than the negative control and significantly higher in all the months analyzed, possibly related to the mutagenic PAHs found. Conclusions: This study demonstrated that artisanal cashew nut roasting is a serious occupational problem, with harmful effects on workers' health. Those involved in this activity are exposed to higher PM{sub 2.5} concentrations and to 12 PAHs considered potentially mutagenic and/or carcinogenic. The Trad-MCN with T. pallida was sensitive and efficient in evaluating the genotoxicity of the components and other nuclear alterations may be used as effective biomarkers of DNA damage. - Highlights: The cashew nut roasting generated high concentrations of particulate matter fine. The biomass burning tracers K, Cl, S were the major inorganic compounds found. It was identified 12 PAHs considered to be potentially mutagenic and/or carcinogenic. The genotoxic potential of this activity was confirmed by the Trad MCN assay. This activity is a serious occupational problem with harmful effects to health workers.

  4. The innate and adaptive immune response induced by alveolar macrophages exposed to ambient particulate matter

    SciTech Connect (OSTI)

    Miyata, Ryohei; Eeden, Stephan F. van

    2011-12-15

    Emerging epidemiological evidence suggests that exposure to particulate matter (PM) air pollution increases the risk of cardiovascular events but the exact mechanism by which PM has adverse effects is still unclear. Alveolar macrophages (AM) play a major role in clearing and processing inhaled PM. This comprehensive review of research findings on immunological interactions between AM and PM provides potential pathophysiological pathways that interconnect PM exposure with adverse cardiovascular effects. Coarse particles (10 {mu}m or less, PM{sub 10}) induce innate immune responses via endotoxin-toll-like receptor (TLR) 4 pathway while fine (2.5 {mu}m or less, PM{sub 2.5}) and ultrafine particles (0.1 {mu}m or less, UFP) induce via reactive oxygen species generation by transition metals and/or polyaromatic hydrocarbons. The innate immune responses are characterized by activation of transcription factors [nuclear factor (NF)-{kappa}B and activator protein-1] and the downstream proinflammatory cytokine [interleukin (IL)-1{beta}, IL-6, and tumor necrosis factor-{alpha}] production. In addition to the conventional opsonin-dependent phagocytosis by AM, PM can also be endocytosed by an opsonin-independent pathway via scavenger receptors. Activation of scavenger receptors negatively regulates the TLR4-NF-{kappa}B pathway. Internalized particles are subsequently subjected to adaptive immunity involving major histocompatibility complex class II (MHC II) expression, recruitment of costimulatory molecules, and the modulation of the T helper (Th) responses. AM show atypical antigen presenting cell maturation in which phagocytic activity decreases while both MHC II and costimulatory molecules remain unaltered. PM drives AM towards a Th1 profile but secondary responses in a Th1- or Th-2 up-regulated milieu drive the response in favor of a Th2 profile.

  5. Source apportionment of particulate matter in the US and associations with lung inflammatory markers

    SciTech Connect (OSTI)

    Duvall, R.M.; Norris, G.A.; Dailey, L.A.; Burke, J.M.; McGee, J.K.; Gilmour, M.I.; Gordon, T.; Devlin, R.B.

    2008-07-01

    Size-fractionated particulate matter (PM) samples were collected from six U.S. cities and chemically analyzed as part of the Multiple Air Pollutant Study. Particles were administered to cultured lung cells and the production of three different proinflammatory markers was measured to explore the association between the health effect markers and PM. Ultrafine, fine, and coarse PM samples were collected between December 2003 and May 2004 over a 4-wk period in each city. Filters were pooled for each city and the PM samples were extracted then analyzed for trace metals, ions, and elemental carbon. Particle extracts were applied to cultured human primary airway epithelial cells, and the secreted levels of interleukin-8 (IL-8), heme oxygenase-1, and cyclooxygenase-2 were measured 1 and 24 h following exposure. Fine PM sources were quantified by the chemical mass balance (CMB) model. The relationship between toxicological measures, PM sources, and individual species were evaluated using linear regression. Ultrafine and fine PM mass were associated with increases in IL-8 (r{sup 2} = .80 for ultrafine and r{sup 2} = .52 for fine). Sources of fine PM and their relative contributions varied across the sampling sites and a strong linear association was observed between IL-8 and secondary sulfate from coal combustion (r{sup 2} = .79). Ultrafine vanadium, lead, copper, and sulfate were also associated with increases in IL-8. Increases in inflammatory markers were not observed for coarse PM mass and source markers. These findings suggest that certain PM size fractions and sources are associated with markers of lung injury or inflammation.

  6. Exposure assessment approaches to evaluate respiratory health effects of particulate matter and nitrogen dioxide

    SciTech Connect (OSTI)

    Quackenboss, J.J.; Krzyzanowski, M.; Lebowitz, M.D. )

    1991-01-01

    Several approaches can be taken to estimate or classify total personal exposures to air pollutants. While personal exposure monitoring (PEM) provides the most direct measurements, it is usually not practical for extended time periods or large populations. This paper describes the use of indirect approaches to estimate total personal exposure for NO2 and particulate matter (PM), summarizes the distributions of these estimates, and compares the effectiveness of these estimates with microenvironmental concentrations for evaluating effects on respiratory function and symptoms. Pollutant concentrations were measured at several indoor and outdoor locations for over 400 households participating in an epidemiological study in Tucson, Arizona. Central site monitoring data were significantly correlated with samples collected directly outside homes, but the former usually had higher pollutant concentrations. Integrated indices of daily total personal exposure were calculated using micro-environmental (ME) measurements or estimates and time-budget diary information. Peak expiratory flow rates (PEFR) were measured for up to four times a day during two-week study periods. In thirty children (ages 6-15 years) with current diagnosed asthma, a significant reduction in PEFR was associated with NO2 levels measured outside of their homes. Additional decrements of morning PEFR were found in those children sleeping in bedrooms with higher measured NO2 levels. Morning and noon PEFR decrements were also linked to higher morning NO2 levels that were measured at central monitoring stations. Effects of PM were also found, but were limited to morning PEFR. No effects were found in non-asthmatic children. The relationship of PEFR to the calculated indices of daily average total exposure were weaker than to the microenvironment concentrations.

  7. Cell-specific oxidative stress and cytotoxicity after wildfire coarse particulate matter instillation into mouse lung

    SciTech Connect (OSTI)

    Williams, Keisha M.; Franzi, Lisa M.; Last, Jerold A.

    2013-01-01

    Our previous work has shown that coarse particulate matter (PM{sub 10-2.5}) from wildfire smoke is more toxic to lung macrophages on an equal dose (by mass) basis than coarse PM isolated from normal ambient air, as evidenced by decreased numbers of macrophages in lung lavage fluid 6 and 24 hours after PM instillation into mouse lungs in vivo and by cytotoxicity to a macrophage cell line observed directly in vitro. We hypothesized that pulmonary macrophages from mice instilled with wildfire coarse PM would undergo more cytotoxicity than macrophages from controls, and that there would be an increase in oxidative stress in their lungs. Cytotoxicity was quantified as decreased viable macrophages and increased percentages of dead macrophages in the bronchoalveolar lavage fluid (BALF) of mice instilled with wildfire coarse PM. At 1 hour after PM instillation, we observed both decreased numbers of viable macrophages and increased dead macrophage percentages as compared to controls. An increase in free isoprostanes, an indicator of oxidative stress, from control values of 28.1 3.2 pg/mL to 83.9 12.2 pg/mL was observed a half-hour after PM instillation. By 1 hour after PM instillation, isoprostane values had returned to 30.4 7.6 pg/mL, not significantly different from control concentrations. Lung sections from mice instilled with wildfire coarse PM showed rapid Clara cell responses, with decreased intracellular staining for the Clara cell secretory protein CCSP 1 hour after wildfire PM instillation. In conclusion, very rapid cytotoxicity occurs in pulmonary macrophages and oxidative stress responses are seen 0.51 hour after wildfire coarse PM instillation. These results define early cellular and biochemical events occurring in vivo and support the hypothesis that oxidative stress-mediated macrophage toxicity plays a key role in the initial response of the mouse lung to wildfire PM exposure. -- Highlights: ? We studied very early events (0.51 hour) after giving wildfire PM{sub 10-2.5} to mice. ? Wildfire PM{sub 10-2.5} rapidly kills lung macrophages in mice. ? Wildfire PM{sub 10-2.5} rapidly elicits oxidative stress in mice. ? Wildfire PM{sub 10-2.5} rapidly elicits Clara cell CCSP secretion in mice. ? Wildfire PM{sub 10-2.5} rapidly elicits TNF-? secretion into BALF in mice.

  8. Ethanol Blend Effects On Direct Injection Spark-Ignition Gasoline Vehicle Particulate Matter Emissions

    SciTech Connect (OSTI)

    Storey, John Morse; Lewis Sr, Samuel Arthur; Barone, Teresa L

    2010-01-01

    Direct injection spark-ignition (DISI) gasoline engines can offer better fuel economy and higher performance over their port fuel-injected counterparts, and are now appearing increasingly in more U.S. vehicles. Small displacement, turbocharged DISI engines are likely to be used in lieu of large displacement engines, particularly in light-duty trucks and sport utility vehicles, to meet fuel economy standards for 2016. In addition to changes in gasoline engine technology, fuel composition may increase in ethanol content beyond the 10% allowed by current law due to the Renewable Fuels Standard passed as part of the 2007 Energy Independence and Security Act (EISA). In this study, we present the results of an emissions analysis of a U.S.-legal stoichiometric, turbocharged DISI vehicle, operating on ethanol blends, with an emphasis on detailed particulate matter (PM) characterization. Gaseous species, particle mass, and particle number concentration emissions were measured for the Federal Test Procedure urban driving cycle (FTP 75) and the more aggressive US06 cycle. Particle number-size distributions and organic to elemental carbon ratios (OC/EC) were measured for 30 MPH and 80 MPH steady-state operation. In addition, particle number concentration was measured during wide open throttle accelerations (WOTs) and gradual accelerations representative of the FTP 75. For the gaseous species and particle mass measurements, dilution was carried out using a full flow constant volume sampling system (CVS). For the particle number concentration and size distribution measurements, a micro-tunnel dilution system was employed. The vehicles were fueled by a standard test gasoline and 10% (E10) and 20% (E20) ethanol blends from the same supplier. The particle mass emissions were approximately 3 and 7 mg/mile for the FTP75 and US06, respectively, with lower emissions for the ethanol blends. During steady-state operation, the geometric mean diameter of the particle-number size distribution remained approximately the same (50 nm) but the particle number concentration decreased with increasing ethanol content in the fuel. In addition, increasing ethanol content significantly reduced the number concentration of 50 and 100 nm particles during gradual and WOT accelerations.

  9. Hydrocarbon-enhanced particulate filter regeneration via microwave ignition

    DOE Patents [OSTI]

    Gonze, Eugene V. (Pinckney, MI); Brown, David B. (Brighton, MI)

    2010-02-02

    A regeneration method for a particulate filter includes estimating a quantity of particulate matter trapped within the particulate filter, comparing the quantity of particulate matter to a predetermined quantity, heating at least a portion of the particulate filter to a combustion temperature of the particulate matter, and introducing hydrocarbon fuel to the particulate filter. The hydrocarbon fuel facilitates combustion of the particulate matter to regenerate the particulate filter.

  10. Method for contamination control and barrier apparatus with filter for containing waste materials that include dangerous particulate matter

    DOE Patents [OSTI]

    Pinson, Paul A. (Idaho Falls, ID)

    1998-01-01

    A container for hazardous waste materials that includes air or other gas carrying dangerous particulate matter has incorporated in barrier material, preferably in the form of a flexible sheet, one or more filters for the dangerous particulate matter sealably attached to such barrier material. The filter is preferably a HEPA type filter and is preferably chemically bonded to the barrier materials. The filter or filters are preferably flexibly bonded to the barrier material marginally and peripherally of the filter or marginally and peripherally of air or other gas outlet openings in the barrier material, which may be a plastic bag. The filter may be provided with a backing panel of barrier material having an opening or openings for the passage of air or other gas into the filter or filters. Such backing panel is bonded marginally and peripherally thereof to the barrier material or to both it and the filter or filters. A coupling or couplings for deflating and inflating the container may be incorporated. Confining a hazardous waste material in such a container, rapidly deflating the container and disposing of the container, constitutes one aspect of the method of the invention. The chemical bonding procedure for producing the container constitutes another aspect of the method of the invention.

  11. Method for contamination control and barrier apparatus with filter for containing waste materials that include dangerous particulate matter

    DOE Patents [OSTI]

    Pinson, P.A.

    1998-02-24

    A container for hazardous waste materials that includes air or other gas carrying dangerous particulate matter has incorporated barrier material, preferably in the form of a flexible sheet, and one or more filters for the dangerous particulate matter sealably attached to such barrier material. The filter is preferably a HEPA type filter and is preferably chemically bonded to the barrier materials. The filter or filters are preferably flexibly bonded to the barrier material marginally and peripherally of the filter or marginally and peripherally of air or other gas outlet openings in the barrier material, which may be a plastic bag. The filter may be provided with a backing panel of barrier material having an opening or openings for the passage of air or other gas into the filter or filters. Such backing panel is bonded marginally and peripherally thereof to the barrier material or to both it and the filter or filters. A coupling or couplings for deflating and inflating the container may be incorporated. Confining a hazardous waste material in such a container, rapidly deflating the container and disposing of the container, constitutes one aspect of the method of the invention. The chemical bonding procedure for producing the container constitutes another aspect of the method of the invention. 3 figs.

  12. Cardiopulmonary Toxicity Induced by Ambient Particulate Matter (BI City Concentrated Ambient Particle Study)

    SciTech Connect (OSTI)

    Annette Rohr; James Wagner Masako Morishita; Gerald Keeler; Jack Harkema

    2010-06-30

    Alterations in heart rate variability (HRV) have been reported in rodents exposed to concentrated ambient particles (CAPs) from different regions of the United States. The goal of this study was to compare alterations in cardiac function induced by CAPs in two distinct regional atmospheres. AirCARE 1, a mobile laboratory with an EPA/Harvard fine particle (particulate matter <2.5 {micro}m; PM{sub 2.5}) concentrator was located in urban Detroit, MI, where the PM mixture is heavily influenced by motor vehicles, and in Steubenville, OH, where PM is derived primarily from long-range transport and transformation of power plant emissions, as well as from local industrial operations. Each city was studied during both winter and summer months, for a total of four sampling periods. Spontaneously hypertensive rats instrumented for electrocardiogram (ECG) telemetry were exposed to CAPs 8 h/day for 13 consecutive days during each sampling period. Heart rate (HR), and indices of HRV (standard deviation of the average normal-to-normal intervals [SDNN]; square root of the mean squared difference of successive normal-to-normal intervals [rMSSD]), were calculated for 30-minute intervals during exposures. A large suite of PM components, including nitrate, sulfate, elemental and organic carbon, and trace elements, were monitored in CAPs and ambient air. In addition, a unique sampler, the Semi-Continuous Elements in Air Sampler (SEAS) was employed to obtain every-30-minute measurements of trace elements. Positive matrix factorization (PMF) methods were applied to estimate source contributions to PM{sub 2.5}. Mixed modeling techniques were employed to determine associations between pollutants/CAPs components and HR and HRV metrics. Mean CAPs concentrations in Detroit were 518 and 357 {micro}g/m{sup 3} (summer and winter, respectively) and 487 and 252 {micro}g/m{sup 3} in Steubenville. In Detroit, significant reductions in SDNN were observed in the summer in association with cement/lime, iron/steel, and gasoline/diesel factors, while associations with the sludge incineration factor and components were less consistent. In winter, increases in HR were associated with a refinery factor and its components. CAPs-associated HR decreases in winter were linked to sludge incineration, cement/lime, and coal/secondary factors and the majority of their associated components. Specific relationships for increased rMSSD in winter were difficult to determine due to lack of consistency between factors and associated constituents. In Steubenville, we observed significant changes in HR (both increases and decreases), SDNN, and rMSSD in the summer, but not in the winter. We examined associations between individual source factors/PM components and HRV metrics segregated by predominant wind direction (NE or SW). Changes in HR (both increases and decreases) were linked with metal processing, waste incineration, and iron/steel factors along with most of their associated elemental constituents. Reductions in SDNN were associated with metal processing, waste incineration, and mobile source factors and the majority of elements loading onto these factors. There were no consistent associations between changes in rMSSD and source factors/components. Despite the large number of coal-fired power plants in the region, and therefore the large contribution of secondary sulfate to overall PM mass, we did not observe any associations with the coal/secondary factor or with the majority of its associated components. There were several inconsistencies in our results which make definitive conclusions difficult. For example, we observed opposing signs of effect estimates with some components depending on season, and with others depending on wind direction. In addition, our extensive dataset clearly would be subject to issues of multiple comparisons, and the 'true' significant results are unknown. Overall, however, our results suggest that acute changes in cardiac function were most strongly associated with local industrial sources. Results for coal-fired power plant-derived PM were

  13. Mechanisms of particulate matter formation in spark-ignition engines. 2: Effect of fuel, oil, and catalyst parameters

    SciTech Connect (OSTI)

    Kayes, D.; Hochgreb, S.

    1999-11-15

    A combined experimental and modeling effort was performed in order to understand how particulate matter (PM) is formed in spark-ignition (SI) internal combustion engines. Fuel type and fuel/air ratio strongly affect particle concentrations. PM emissions vary by up to 6 orders of magnitude between fuels at the same fuel/air ratio. Minimum PM concentrations are emitted at a global fuel/air ratio within 10% of stoichiometric, with the exact value depending on the particular fuel. Concentrations can increase by more than 3 orders of magnitude when the fuel/air ratio is either increased or decreased 30% from stoichiometric. Particles derived from oil consumption were found to be between 0 and 40% of the PM concentration for the oils used in the present experiments. Differences in PM emissions with and without the catalytic converter are not statistically significant. Particulate number and mass concentrations plus particle sizes are addressed in this paper, as is the correlation between PM and hydrocarbon (HC) emissions.

  14. Total Particulate Matter Air Sampling Data (TEOM) from Los Alamos National Laboratory

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    LANL measures the total particulate mass concentration in the air on a routine basis as well as during incidents that may affect ambient air. The collected data is added to the Air Quality Index (AQI). AQI is an index for reporting daily air quality. It tells you how clean or polluted your air is, and what associated health effects might be a concern for you. The AQI focuses on health effects you may experience within a few hours or days after breathing polluted air. EPA calculates the AQI for five major air pollutants regulated by the Clean Air Act.

  15. Kinetic Model Development for the Combustion of Particulate Matter from Conventional and Soy Methyl Ester Diesel Fuels

    SciTech Connect (OSTI)

    Strzelec, Andrea

    2009-12-01

    The primary objective of this research has been to investigate how the oxidation characteristics of diesel particulate matter (PM) are affected by blending soy-based biodiesel fuel with conventional ultra low sulfur diesel (ULSD) fuel. PM produced in a light duty engine from different biodiesel-conventional fuel blends was subjected to a range of physical and chemical measurements in order to better understand the mechanisms by which fuel-related changes to oxidation reactivity are brought about. These observations were then incorporated into a kinetic model to predict PM oxidation. Nanostructure of the fixed carbon was investigated by HR-TEM and showed that particulates from biodiesel had a more open structure than particulates generated from conventional diesel fuel, which was confirmed by BET surface area measurements. Surface area evolution with extent of oxidation reaction was measured for PM from ULSD and biodiesel. Biodiesel particulate has a significantly larger surface area for the first 40% of conversion, at which point the samples become quite similar. Oxidation characteristics of nascent PM and the fixed carbon portion were measured by temperature programmed oxidation (TPO) and it was noted that increased biodiesel blending lowered the light-off temperature as well as the temperature where the peak rate of oxidation occurred. A shift in the oxidation profiles of all fuels was seen when the mobile carbon fraction was removed, leaving only the fixed carbon, however the trend in temperature advantage of the biofuel blending remained. The mobile carbon fraction was measured by temperature programmed desorption found to generally increase with increasing biodiesel blend level. The relative change in the light-off temperatures for the nascent and fixed carbon samples was found to be related to the fraction of mobile carbon. Effective Arrhenius parameters for fixed carbon oxidation were directly measured with isothermal, differential oxidation experiments. Normalizing the reaction rate to the total carbon surface area available for reaction allowed for the definition of a single reaction rate with constant activation energy (112.5 {+-} 5.8 kJ/mol) for the oxidation of PM, independent of its fuel source. A kinetic model incorporating the surface area dependence of fixed carbon oxidation rate and the impact of the mobile carbon fraction was constructed and validated against experimental data.

  16. Evaluation of a Partial Flow Dilution System for Transient Particulate...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    a Partial Flow Dilution System for Transient Particulate Matter Emissions Evaluation of a Partial Flow Dilution System for Transient Particulate Matter Emissions A commercially...

  17. Particulate Matter Sampling and Volatile Organic Compound Removal for Characterization of Spark Ignited Direct Injection Engine Emissions

    SciTech Connect (OSTI)

    Matthias, Nicholas; Farron, Carrie; Foster, David E.; Andrie, Michael; Krieger, Roger; Najt, Paul M.; Narayanaswamy, Kushal; Solomon, Arun S.; Zelenyuk, Alla

    2012-01-01

    More stringent emissions regulations are continually being proposed to mitigate adverse human health and environmental impacts of internal combustion engines. With that in mind, it has been proposed that vehicular particulate matter (PM) emissions should be regulated based on particle number in addition to particle mass. One aspect of this project is to study different sample handling methods for number based aerosol measurements, specifically, two different methods for removing volatile organic compounds (VOCs). One method is a thermodenuder (TD) and the other is an evaporative chamber/diluter (EvCh). These sample handling methods have been implemented in an engine test cell with a spark ignited direct injection (SIDI) engine. The engine was designed for stoichiometric, homogeneous combustion. SIDI is of particular interest for improved fuel efficiency compared to other SI engines, however, the efficiency benefit comes with greater PM emissions and may therefore be subject to the proposed number based PM regulation. Another aspect of this project is to characterize PM from this engine in terms of particle number and composition.

  18. Particulate Matter Sampling and Volatile Organic Compound Removal for Characterization of Spark Ignited Direct Injection Engine Emissions

    SciTech Connect (OSTI)

    Matthias, Nicholas; Farron, Carrie; Foster, David E.; Andrie, Michael; Krieger, Roger; Najt, Paul; Narayanaswamy, Kushal; Solomon, Arun S.; Zelenyuk, Alla

    2012-01-01

    More stringent emissions regulations are continually being proposed to mitigate adverse human health and environmental impacts of internal combustion engines. With that in mind, it has been proposed that vehicular particulate matter (PM) emissions should be regulated based on particle number in addition to particle mass. One aspect of this project is to study different sample handling methods for number based aerosol measurements, specifically, two different methods for removing volatile organic compounds (VOCs). One method is a thermodenuder (TD) and the other is an evaporative chamber/diluter (EvCh). These sample handling methods have been implemented in an engine test cell with a spark ignited direct injection (SIDI) engine. The engine was designed for stoichiometric, homogeneous combustion. SIDI is of particular interest for improved fuel efficiency compared to other SI engines, however, the efficiency benefit comes with greater PM emissions and may therefore be subject to the proposed number based PM regulation. Another aspect of this project is to characterize PM from this engine in terms of particle number and composition

  19. Characterization of Fine Particulate Matter (PM) and Secondary PM Precursor Gases in the Mexico City Metropolitan Area

    DOE R&D Accomplishments [OSTI]

    Molina, Luisa T.; Volkamer, Rainer; de Foy, Benjamin; Lei, Wenfang; Zavala, Miguel; Velasco, Erik; Molina; Mario J.

    2008-10-31

    This project was one of three collaborating grants funded by DOE/ASP to characterize the fine particulate matter (PM) and secondary PM precursors in the Mexico City Metropolitan Area (MCMA) during the MILAGRO Campaign. The overall effort of MCMA-2006, one of the four components, focused on i) examination of the primary emissions of fine particles and precursor gases leading to photochemical production of atmospheric oxidants and secondary aerosol particles; ii) measurement and analysis of secondary oxidants and secondary fine PM production, with particular emphasis on secondary organic aerosol (SOA), and iii) evaluation of the photochemical and meteorological processes characteristic of the Mexico City Basin. The collaborative teams pursued the goals through three main tasks: i) analyses of fine PM and secondary PM precursor gaseous species data taken during the MCMA-2002/2003 campaigns and preparation of publications; ii) planning of the MILAGRO Campaign and deployment of the instrument around the MCMA; and iii) analysis of MCMA-2006 data and publication preparation.

  20. Advances in exposure and toxicity assessment of particulate matter: An overview of presentations at the 2009 Toxicology and Risk Assessment Conference

    SciTech Connect (OSTI)

    Gunasekar, Palur G.; Stanek, Lindsay W.

    2011-07-15

    The 2009 Toxicology and Risk Assessment Conference (TRAC) session on 'Advances in Exposure and Toxicity Assessment of Particulate Matter' was held in April 2009 in West Chester, OH. The goal of this session was to bring together toxicology, geology and risk assessment experts from the Department of Defense and academia to examine issues in exposure assessment and report on recent epidemiological findings of health effects associated with particulate matter (PM) exposure. Important aspects of PM exposure research are to detect and monitor low levels of PM with various chemical compositions and to assess the health risks associated with these exposures. As part of the overall theme, some presenters discussed collection methods for sand and dust from Iraqi and Afghanistan regions, health issues among deployed personnel, and future directions for risk assessment research among these populations. The remaining speakers focused on the toxicity of ultrafine PM and the characterization of aerosols generated during ballistic impacts of tungsten heavy alloys.

  1. Diesel Emission Control -- Sulfur Effects (DECSE) Program; Phase I Interim Date Report No. 3: Diesel Fuel Sulfur Effects on Particulate Matter Emissions

    SciTech Connect (OSTI)

    DOE; ORNL; NREL; EMA; MECA

    1999-11-15

    The Diesel Emission Control-Sulfur Effects (DECSE) is a joint government/industry program to determine the impact of diesel fuel sulfur levels on emission control systems whose use could lower emissions of nitrogen oxides (NO{sub x}) and particulate matter (PM) from on-highway trucks in the 2002--2004 model years. Phase 1 of the program was developed with the following objectives in mind: (1) evaluate the effects of varying the level of sulfur content in the fuel on the emission reduction performance of four emission control technologies; and (2) measure and compare the effects of up to 250 hours of aging on selected devices for multiple levels of fuel sulfur content. This interim report covers the effects of diesel fuel sulfur level on particulate matter emissions for four technologies.

  2. The use of CETANER{trademark} for the reduction of particulate matter emissions in a turbocharged direct injection (TDI) diesel engine

    SciTech Connect (OSTI)

    Hess, H.S.; Chiodo, J.A.; Boehman, A.L.; Tijim, P.J.A.; Waller, F.J.

    1999-07-01

    In this experimental study, the effects of the addition of CETANER{trademark} to a premium diesel fuel at various blend levels (5%, 10% and 15% by weight) were evaluated using a 1.9 liter turbocharged direct injection diesel engine. CETANER{trademark}, a product developed by Air Products and Chemicals, Inc., can be manufactured from coal-derived syngas through a two-stage process: (i) Liquid Phase DiMethyl Ether synthesis (LPDME); and (ii) oxidative coupling of DiMethyl Ether (DME) to form long chain linear ethers. When compared to other oxygenated components currently being researched, CETANER has several key advantages: (1) it is derived from a non-petroleum feedstock; (2) it has a cetane number greater than 100; and (3) it will have a cost comparable to diesel fuel. Particulate matter emissions and exhaust gas composition (NOx and CO), were determined at six steady-state engine operating conditions. In addition, fuel properties (viscosity, cloud point, pour point, density, flash point and calorific value) of the various blends were also determined. Engine test results indicate that CETANER is effective in reducing particulate matter emissions at all blend levels tested, without any modifications to engine operating parameters. At the highest blend level (15% CETANER by weight), particulate matter emissions were reduced by greater than 20% when compared to premium diesel fuel.

  3. Persistent activation of DNA damage signaling in response to complex mixtures of PAHs in air particulate matter

    SciTech Connect (OSTI)

    Jarvis, Ian W.H.; Bergvall, Christoffer; Bottai, Matteo; Westerholm, Roger; Stenius, Ulla; Dreij, Kristian

    2013-02-01

    Complex mixtures of polycyclic aromatic hydrocarbons (PAHs) are present in air particulate matter (PM) and have been associated with many adverse human health effects including cancer and respiratory disease. However, due to their complexity, the risk of exposure to mixtures is difficult to estimate. In the present study the effects of binary mixtures of benzo[a]pyrene (BP) and dibenzo[a,l]pyrene (DBP) and complex mixtures of PAHs in urban air PM extracts on DNA damage signaling was investigated. Applying a statistical model to the data we observed a more than additive response for binary mixtures of BP and DBP on activation of DNA damage signaling. Persistent activation of checkpoint kinase 1 (Chk1) was observed at significantly lower BP equivalent concentrations in air PM extracts than BP alone. Activation of DNA damage signaling was also more persistent in air PM fractions containing PAHs with more than four aromatic rings suggesting larger PAHs contribute a greater risk to human health. Altogether our data suggests that human health risk assessment based on additivity such as toxicity equivalency factor scales may significantly underestimate the risk of exposure to complex mixtures of PAHs. The data confirms our previous findings with PAH-contaminated soil (Niziolek-Kierecka et al., 2012) and suggests a possible role for Chk1 Ser317 phosphorylation as a biological marker for future analyses of complex mixtures of PAHs. -- Highlights: ? Benzo[a]pyrene (BP), dibenzo[a,l]pyrene (DBP) and air PM PAH extracts were compared. ? Binary mixture of BP and DBP induced a more than additive DNA damage response. ? Air PM PAH extracts were more potent than toxicity equivalency factor estimates. ? Larger PAHs (> 4 rings) contribute more to the genotoxicity of PAHs in air PM. ? Chk1 is a sensitive marker for persistent activation of DNA damage signaling from PAH mixtures.

  4. Impacts of Mid-level Biofuel Content in Gasoline on SIDI Engine-Out and Tailpipe Particulate Matter Emissions: Preprint

    SciTech Connect (OSTI)

    He, X.; Ireland, J. C.; Zigler, B. T.; Ratcliff, M. A.; Knoll, K. E.; Alleman, T. L.; Tester, J. T.

    2011-02-01

    The influences of ethanol and iso-butanol blended with gasoline on engine-out and post Three-Way Catalyst (TWC) particle size distribution and number concentration were studied using a GM 2.0L turbocharged Spark Ignition Direct Injection (SIDI) engine. The engine was operated using the production ECU with a dynamometer controlling the engine speed and the accelerator pedal position controlling the engine load. A TSI Fast Mobility Particle Sizer (FMPS) spectrometer was used to measure the particle size distribution in the range from 5.6 to 560 nm with a sampling rate of 1 Hz. US federal certification gasoline (E0), two ethanol-blended fuels (E10 and E20), and 11.7% iso-butanol blended fuel (BU12) were tested. Measurements were conducted at ten selected steady-state engine operation conditions. Bi-modal particle size distributions were observed for all operating conditions with peak values at particle sizes of 10 nm and 70 nm. Idle and low speed / low load conditions emitted higher total particle numbers than other operating conditions. At idle, the engine-out Particulate Matter (PM) emissions were dominated by nucleation mode particles, and the production TWC reduced these nucleation mode particles by more than 50%, while leaving the accumulation mode particle distribution unchanged. At engine load higher than 6 bar NMEP, accumulation mode particles dominated the engine-out particle emissions and the TWC had little effect. Compared to the baseline gasoline (E0), E10 does not significantly change PM emissions, while E20 and BU12 both reduce PM emissions under the conditions studied. Iso-butanol was observed to impact PM emissions more than ethanol, with up to 50% reductions at some conditions. In this paper, the issues related to PM measurement using FMPS are also discussed. While some uncertainties are due to engine variation, the FMPS must be operated under careful maintenance procedures in order to achieve repeatable measurement results.

  5. Particulate Matter Aerosols

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The study of atmospheric aerosols is important because of its adverse effects on health, air quality, visibility, cultural heritage, and Earth's radiation balance. Techniques that...

  6. Particulate Matter Sampling and Volatile Organic Compound Removal for Characterization of Spark Ignited Direct Injection Engine Emissions

    SciTech Connect (OSTI)

    Matthias, Nick; Farron, Carrie; Foster, David E.; Andrie, Mike; Krieger, Roger; Najt, Paul; Narayanaswamy, Kushal; Solomon, Arun; Zelenyuk, Alla

    2012-01-01

    More stringent emissions regulations are continually being proposed to mitigate adverse human health and environmental impacts of internal combustion. With that in mind, it has been proposed that vehicular particulate matter (PM) emissions should be regulated based on particle number in addition to particle mass. One aspect of this project is to study different sample handling methods for number based aerosol measurements, specifically, two different methods for removing volatile organic compounds (VOCs) from an aerosol sample. One method is a Dekati Thermodenuder (TD) and the other is an evaporative chamber/diluter (EvCh). These sample handling methods have been implemented for this project in an engine test cell built around a direct injection spark ignited (DISI) engine. The engine was designed for stoichiometric, homogeneous combustion. Direct injection is of particular interest for improved fuel efficiency but this comes with the production of a significant amount of (PM) and may therefore be subject to the proposed number based regulation. Another aspect of this project is to characterize PM from this engine in terms of particle number and composition. The first interesting observation is that PM number distributions, acquired using a TSI SMPS, have a large accumulation mode (30-294 nm) but a very small nuclei mode (8-30 nm). This is understood to represent a lack of condensation particles meaning that neither the exhaust conditions nor the sample handling conditions are conducive to condensation. This lack of nuclei mode does not, however, represent a lack of VOCs in the sample. It has been observed, using mass spectral analysis (limited to PM>50 nm), that PM from the DISI engine has approximately 40% organic content through varying operating conditions. This begs the question of how effective different sample handling methods are at removing these VOCs. For one specific operating condition, called Cold Start, the un-treated PM was 40% organic. The TD reduced this by 7% while the EvCh reduced it by 13%. For other operating conditions, PM treated for volatile removal actually exhibited an increase in organic fraction on the order of 5%. This addition appears to be sensitive to the gaseous hydrocarbon concentrations in the exhaust although a precise correlation has not yet been derived. It has been concluded that VOCs are tightly bound to the PM carbon core and thus are not effectively removed by either treatment method.

  7. Advanced Diesel Combustion with Low Hydrocarbon and Carbon Monoxide

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Emissions | Department of Energy Combustion with Low Hydrocarbon and Carbon Monoxide Emissions Advanced Diesel Combustion with Low Hydrocarbon and Carbon Monoxide Emissions Poster presented at the 16th Directions in Engine-Efficiency and Emissions Research (DEER) Conference in Detroit, MI, September 27-30, 2010. PDF icon p-19_lilik.pdf More Documents & Publications Effects of Ignition Quality and Fuel Composition on Critical Equivalence Ratio Particulate Produced from Advanced Combustion

  8. Electrically heated particulate filter restart strategy

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI; Ament, Frank [Troy, MI

    2011-07-12

    A control system that controls regeneration of a particulate filter is provided. The system generally includes a propagation module that estimates a propagation status of combustion of particulate matter in the particulate filter. A regeneration module controls current to the particulate filter to re-initiate regeneration based on the propagation status.

  9. Electrically heated particulate filter propagation support methods and systems

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI; Ament, Frank [Troy, MI

    2011-06-07

    A control system that controls regeneration of a particulate filter is provided. The system generally includes a regeneration module that controls current to the particulate filter to initiate combustion of particulate matter in the particulate filter. A propagation module estimates a propagation status of the combustion of the particulate matter based on a combustion temperature. A temperature adjustment module controls the combustion temperature by selectively increasing a temperature of exhaust that passes through the particulate filter.

  10. EVALUATION OF THE EMISSION, TRANSPORT, AND DEPOSITION OF MERCURY, FINE PARTICULATE MATTER, AND ARSENIC FROM COAL-BASED POWER PLANTS IN THE OHIO RIVER VALLEY REGION

    SciTech Connect (OSTI)

    Kevin Crist

    2004-10-02

    Ohio University, in collaboration with CONSOL Energy, Advanced Technology Systems, Inc (ATS) and Atmospheric and Environmental Research, Inc. (AER) as subcontractors, is evaluating the impact of emissions from coal-fired power plants in the Ohio River Valley region as they relate to the transport and deposition of mercury, arsenic, and associated fine particulate matter. This evaluation will involve two interrelated areas of effort: ambient air monitoring and regional-scale modeling analysis. The scope of work for the ambient air monitoring will include the deployment of a surface air monitoring (SAM) station in southeastern Ohio. The SAM station will contain sampling equipment to collect and measure mercury (including speciated forms of mercury and wet and dry deposited mercury), arsenic, particulate matter (PM) mass, PM composition, and gaseous criteria pollutants (CO, NOx, SO{sub 2}, O{sub 3}, etc.). Laboratory analysis of time-integrated samples will be used to obtain chemical speciation of ambient PM composition and mercury in precipitation. Near-real-time measurements will be used to measure the ambient concentrations of PM mass and all gaseous species including Hg{sup 0} and RGM. Approximately of 18 months of field data will be collected at the SAM site to validate the proposed regional model simulations for episodic and seasonal model runs. The ambient air quality data will also provide mercury, arsenic, and fine particulate matter data that can be used by Ohio Valley industries to assess performance on multi-pollutant control systems. The scope of work for the modeling analysis will include (1) development of updated inventories of mercury and arsenic emissions from coal plants and other important sources in the modeled domain; (2) adapting an existing 3-D atmospheric chemical transport model to incorporate recent advancements in the understanding of mercury transformations in the atmosphere; (3) analyses of the flux of Hg{sup 0}, RGM, arsenic, and fine particulate matter in the different sectors of the study region to identify key transport mechanisms; (4) comparison of cross correlations between species from the model results to observations in order to evaluate characteristics of specific air masses associated with long-range transport from a specified source region; and (5) evaluation of the sensitivity of these correlations to emissions from regions along the transport path. This will be accomplished by multiple model runs with emissions simulations switched on and off from the various source regions. To the greatest extent possible, model results will also be compared to field data collected at other air monitoring sites in the Ohio Valley region, operated independently of this project. These sites may include (1) the DOE National Energy Technologies Laboratory's monitoring site at its suburban Pittsburgh, PA facility; (2) sites in Pittsburgh (Lawrenceville) PA and Holbrook, PA operated by ATS; (3) sites in Steubenville, OH and Pittsburgh, PA operated by U.S. EPA and/or its contractors; and (4) sites operated by State or local air regulatory agencies. Field verification of model results and predictions will provide critical information for the development of cost effective air pollution control strategies by the coal-fired power plants in the Ohio River Valley region.

  11. Evaluation of the Emission, Transport, and Deposition of Mercury and Fine Particulate Matter from Coal-Based Power Plants in the Ohio River Valley Region

    SciTech Connect (OSTI)

    Kevin Crist

    2008-12-31

    As stated in the proposal: Ohio University, in collaboration with CONSOL Energy, Advanced Technology Systems, Inc (ATS) and Atmospheric and Environmental Research, Inc. (AER) as subcontractors, evaluated the impact of emissions from coal-fired power plants in the Ohio River Valley region as they relate to the transport and deposition of mercury and associated fine particulate matter. This evaluation involved two interrelated areas of effort: ambient air monitoring and regional-scale modeling analysis. The scope of work for the ambient air monitoring included the deployment of a surface air monitoring (SAM) station in southeastern Ohio. The SAM station contains sampling equipment to collect and measure mercury (including speciated forms of mercury and wet and dry deposited mercury), particulate matter (PM) mass, PM composition, and gaseous criteria pollutants (CO, NOx, SO2, O3, etc.). Laboratory analyses of time-integrated samples were used to obtain chemical speciation of ambient PM composition and mercury in precipitation. Nearreal- time measurements were used to measure the ambient concentrations of PM mass and all gaseous species including Hg0 and RGM. Approximately 30 months of field data were collected at the SAM site to validate the proposed regional model simulations for episodic and seasonal model runs. The ambient air quality data provides mercury, and fine particulate matter data that can be used by Ohio Valley industries to assess performance on multi-pollutant control systems. The scope of work for the modeling analysis includes (1) development of updated inventories of mercury emissions from coal plants and other important sources in the modeled domain; (2) adapting an existing 3-D atmospheric chemical transport model to incorporate recent advancements in the understanding of mercury transformations in the atmosphere; (3) analyses of the flux of Hg0, RGM, and fine particulate matter in the different sectors of the study region to identify key transport mechanisms; (4) comparison of cross correlations between species from the model results to observations in order to evaluate characteristics of specific air masses associated with long-range transport from a specified source region; and (5) evaluation of the sensitivity of these correlations to emissions from regions along the transport path. This is accomplished by multiple model runs with emissions simulations switched on and off from the various source regions. To the greatest extent possible, model results were compared to field data collected at other air monitoring sites in the Ohio Valley region, operated independently of this project. These sites may include (1) the DOE National Energy Technologies Laboratorys monitoring site at its suburban Pittsburgh, PA facility; (2) sites in Pittsburgh (Lawrenceville) PA and Holbrook, PA operated by ATS; (3) sites in Steubenville, OH and Pittsburgh, PA operated by the USEPA and/or its contractors; and (4) sites operated by State or local air regulatory agencies. Field verification of model results and predictions provides critical information for the development of cost effective air pollution control strategies by the coal-fired power plants in the Ohio River Valley region.

  12. Response of fine particulate matter to emission changes of oxides of nitrogen and anthropogenic volatile organic compounds in the eastern United States

    SciTech Connect (OSTI)

    Alexandra P. Tsimpidi; Vlassis A. Karydis; Spyros N. Pandis

    2008-11-15

    A three-dimensional chemical transport model (Particulate Matter Comprehensive Air Quality Model with Extensions) is used to investigate changes in fine particle (PM2.5) concentrations in response to 50% emissions changes of oxides of nitrogen (NOx) and anthropogenic volatile organic compounds (VOCs) during July 2001 and January 2002 in the eastern United States. The reduction of NOx emissions by 50% during the summer results in lower average oxidant levels and lowers PM2.5 (8% on average), mainly because of reductions of sulfate (9-11%), nitrate (45-58%), and ammonium (7-11%). The organic particulate matter (PM) slightly decreases in rural areas, whereas it increases in cities by a few percent when NOx is reduced. Reduction of NOx during winter causes an increase of the oxidant levels and a rather complicated response of the PM components, leading to small net changes. Sulfate increases (8-17%), nitrate decreases (18-42%), organic PM slightly increases, and ammonium either increases or decreases a little. The reduction of VOC emissions during the summer causes on average a small increase of the oxidant levels and a marginal increase in PM2.5. This small net change is due to increases in the inorganic components and decreases of the organic ones. Reduction of VOC emissions during winter results in a decrease of the oxidant levels and a 5-10% reduction of PM2.5 because of reductions in nitrate (4-19%), ammonium (4-10%), organic PM (12-14%), and small reductions in sulfate. Although sulfur dioxide (SO{sub 2}) reduction is the single most effective approach for sulfate control, the coupled decrease of SO{sub 2} and NOx emissions in both seasons is more effective in reducing total PM2.5 mass than the SO{sub 2} reduction alone. 34 refs., 7 figs., 1 tab.

  13. Real-time measurements of particulate matter and polycyclic aromatic hydrocarbon emissions from stationary combustion sources used in oil and gas production

    SciTech Connect (OSTI)

    D. w. Hahn; K. r. Hencken; H. A. Johnsen; J. R. Ross; P. M. Walsh

    1998-12-10

    Particulate matter emissions and some components of the particles were measured in the exhaust from combustion equipment used in oil and gas production operations near Bakersfield, California. The combustion sources included a 22.5 MW (electric) turbine generator, a 342-Bhp rich-burn spark ignition engine, and a 50 million Btu/h steam generator, all fired using natural gas. The particle components and measurement techniques were as follows: (1) Calcium, magnesium, sodium, silicon, and iron were measured using laser-induced breakdown spectroscopy (LIBS), (2) particle-bound polycyclic aromatic hydrocarbons (PAH) were detected using the charge produced by photoionization, (3) particles having sizes between 0.1 and 7.5 {micro}m were counted using an instrument based on light scattering, and (4) total particulate matter was measured according to US EPA Method 5. Not all of the methods were applied to all of the sources. Measurements were also made in the ambient air near the combustion air inlets to the units, for comparison with the concentrations in the exhaust, but the inlet and outlet measurements were not done simultaneously. Calcium, sodium, and silicon were found in the exhaust from the steam generator at concentrations similar to those in the ambient air near the inlet to the burner. Sodium and silicon were observed in the engine exhaust at levels a factor of four higher than their concentrations in the air. The principal metal observed in the engine exhaust was calcium, a component of the lubricating oil, at a concentration of 11.6 {micro}g/m{sup 3}. The air entering the gas turbine is filtered, so the average concentrations of metals in the turbine exhaust under steady operating conditions were even lower than in the air. During start-up following a shut-down to wash the turbine, silicon and iron were the major species in the stack, at concentrations of 6.4 and 16.2 {micro}g/m{sup 3}, respectively. A possible source of silicon is the water injected into the turbine for NO{sub x} control. Iron-containing particles are expected to be scale from ferrous metals. A commercial photoelectric aerosol sensor was used to measure PAH adsorbed on particles in the exhaust from the steam generator and the rich-burn engine. The conversion of the instrument readings to PAH concentrations is dependent upon the specific distribution of PAH species present. Using the typical calibration factor recommended by the instrument manufacturer, the estimated average concentration of particle-bound PAH was below the instrument detection limit (3--10 ng/m{sup 3}) in the stack gas from the steam generator, and was estimated to be 0.045--0.15 {micro}g/m{sup 3} in the exhaust from the rich-burn engine. Particle mass concentrations estimated from number concentrations determined using the particle counting and sizing instrument were only small fractions of the concentrations measured using Method 5. This is thought to be due primarily to the limited range over which size was quantified (0.1 to 7.5 {micro}m) and the poor efficiency with which the sampling system transferred large particles.

  14. Characterization of Pre-Commercial Gasoline Engine Particulates Through

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Advanced Aerosol Methods | Department of Energy Pre-Commercial Gasoline Engine Particulates Through Advanced Aerosol Methods Characterization of Pre-Commercial Gasoline Engine Particulates Through Advanced Aerosol Methods Advanced aerosol analysis methods were used to examine particulates from single cylinder test engines running on gasoline and ethanol blends. PDF icon deer12_zelenyuk.pdf More Documents & Publications Fuel-Neutral Studies of Particulate Matter Transport Emissions

  15. Evaluation of a Partial Flow Dilution System for Transient Particulate

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Matter Emissions | Department of Energy a Partial Flow Dilution System for Transient Particulate Matter Emissions Evaluation of a Partial Flow Dilution System for Transient Particulate Matter Emissions A commercially available partial flow dilution system was evaluated against a constant volume sampling system over a suite of transient engine dynamometer tests. PDF icon deer08_shade.pdf More Documents & Publications Evaluation of the European PMP Methodologies Using Chassis Dynamometer

  16. Chemopreventive activity of compounds extracted from Casearia sylvestris (Salicaceae) Sw against DNA damage induced by particulate matter emitted by sugarcane burning near Araraquara, Brazil

    SciTech Connect (OSTI)

    Prieto, A.M.; Santos, A.G.; Csipak, A.R.; Caliri, C.M.; Silva, I.C.; Arbex, M.A.; Silva, F.S.; Marchi, M.R.R.

    2012-12-15

    Ethanolic extract of Casearia sylvestris is thought to be antimutagenic. In this study, we attempted to determine whether this extract and casearin X (a clerodane diterpene from C. sylvestris) are protective against the harmful effects of airborne pollutants from sugarcane burning. To that end, we used the Tradescantia micronucleus test in meiotic pollen cells of Tradescantia pallida, the micronucleus test in mouse bone marrow cells, and the comet assay in mouse blood cells. The mutagenic compound was total suspended particulate (TSP) from air. For the Tradescantia micronucleus test, T. pallida cuttings were treated with the extract at 0.13, 0.25, or 0.50 mg/ml. Subsequently, TSP was added at 0.3 mg/ml, and tetrads from the inflorescences were examined for micronuclei. For the micronucleus test in mouse bone marrow cells and the comet assay in mouse blood cells, Balb/c mice were treated for 15 days with the extract3.9, 7.5, or 15.0 mg/kg body weight (BW)or with casearin X0.3, 0.25, or 1.2 mg/kg BWafter which they received TSP (3.75 mg/kg BW). In T. pallida and mouse bone marrow cells, the extract was antimutagenic at all concentrations tested. In mouse blood cells, the extract was antigenotoxic at all concentrations, whereas casearin X was not antimutagenic but was antigenotoxic at all concentrations. We conclude that C. sylvestris ethanolic extract and casearin X protect DNA from damage induced by airborne pollutants from sugarcane burning. -- Highlights: ? We assessed DNA protection of C. sylvestris ethanolic extract. ? We assessed DNA protection of casearin X. ? We used Tradescantia pallida micronucleus test as screening. ? We used comet assay and micronucleus test in mice. ? The compounds protected DNA against sugar cane burning pollutants.

  17. Shielded regeneration heating element for a particulate filter

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI; Ament, Frank [Troy, MI

    2011-01-04

    An exhaust system includes a particulate filter (PF) that is disposed downstream from an engine. The PF filters particulates within an exhaust from the engine. A heating element heats particulate matter in the PF. A catalyst substrate or a flow converter is disposed upstream from said heating element. The catalyst substrate oxidizes the exhaust prior to reception by the heating element. The flow converter converts turbulent exhaust flow to laminar exhaust flow prior to reception by the heating element.

  18. The State of the Science in Diesel Particulate Control | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy The State of the Science in Diesel Particulate Control The State of the Science in Diesel Particulate Control 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters PDF icon 2005_deer_muntean.pdf More Documents & Publications Method Development: Identification of the Soluble Organic Fraction of Particulate Matter on DPF Soot Aftertreatment Research Prioritization: A CLEERS Industrial Survey Development of a Sub-Grid Model of a Diesel Particulate Filter:

  19. Particulate hot gas stream cleanup technical issues

    SciTech Connect (OSTI)

    Pontius, D.H.; Snyder, T.R.

    1999-09-30

    The analyses of hot gas stream cleanup particulate samples and descriptions of filter performance studied under this contract were designed to address problems with filter operation that have been linked to characteristics of the collected particulate matter. One objective of this work was to generate an interactive, computerized data bank of the key physical and chemical characteristics of ash and char collected from operating advanced particle filters and to relate these characteristics to the operation and performance of these filters. The interactive data bank summarizes analyses of over 160 ash and char samples from fifteen pressurized fluidized-bed combustion and gasification facilities utilizing high-temperature, high pressure barrier filters.

  20. Particulate Matter Characteristics for Highly Dilute Stoichiometric...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    PDF icon p-24storey.pdf More Documents & Publications Ethanol Effects on Lean-Burn and Stoichiometric GDI Emissions Effects of Advanced Combustion Technologies on...

  1. Carbon Monoxide Sensor - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Carbon Monoxide Sensor Los Alamos National Laboratory Contact LANL About This Technology Technology Marketing SummaryScientists at Los Alamos National Laboratory (LANL) have developed an electrochemical carbon monoxide (CO) sensor that is more reliable and reproducible than any other CO sensor on the market today. The patented method for producing the sensor ensures reproducibility and reduces the need for calibration of every sensor coming off the production line.DescriptionInaccurate CO

  2. Device for staged carbon monoxide oxidation

    DOE Patents [OSTI]

    Vanderborgh, Nicholas E.; Nguyen, Trung V.; Guante, Jr., Joseph

    1993-01-01

    A method and apparatus for selectively oxidizing carbon monoxide in a hydrogen rich feed stream. The method comprises mixing a feed stream consisting essentially of hydrogen, carbon dioxide, water and carbon monoxide with a first predetermined quantity of oxygen (air). The temperature of the mixed feed/oxygen stream is adjusted in a first the heat exchanger assembly (20) to a first temperature. The mixed feed/oxygen stream is sent to reaction chambers (30,32) having an oxidation catalyst contained therein. The carbon monoxide of the feed stream preferentially absorbs on the catalyst at the first temperature to react with the oxygen in the chambers (30,32) with minimal simultaneous reaction of the hydrogen to form an intermediate hydrogen rich process stream having a lower carbon monoxide content than the feed stream. The elevated outlet temperature of the process stream is carefully controlled in a second heat exchanger assembly (42) to a second temperature above the first temperature. The process stream is then mixed with a second predetermined quantity of oxygen (air). The carbon monoxide of the process stream preferentially reacts with the second quantity of oxygen in a second stage reaction chamber (56) with minimal simultaneous reaction of the hydrogen in the process stream. The reaction produces a hydrogen rich product stream having a lower carbon monoxide content than the process stream. The product stream is then cooled in a third heat exchanger assembly (72) to a third predetermined temperature. Three or more stages may be desirable, each with metered oxygen injection.

  3. Method for immobilizing particulate materials in a packed bed

    DOE Patents [OSTI]

    Even, W.R. Jr.; Guthrie, S.E.; Raber, T.N.; Wally, K.; Whinnery, L.L.; Zifer, T.

    1999-02-02

    The present invention pertains generally to immobilizing particulate matter contained in a packed bed reactor so as to prevent powder migration, compaction, coalescence, or the like. More specifically, this invention relates to a technique for immobilizing particulate materials using a microporous foam-like polymer such that (a) the particulate retains its essential chemical nature, (b) the local movement of the particulate particles is not unduly restricted, (c) bulk powder migration and is prevented, (d) physical and chemical access to the particulate is unchanged over time, and (e) very high particulate densities are achieved. The immobilized bed of the present invention comprises a vessel for holding particulate matter, inlet and an outlet ports or fittings, a loosely packed bed of particulate material contained within the vessel, and a three dimensional porous matrix for surrounding and confining the particles thereby fixing the movement of an individual particle to a limited local position. The established matrix is composed of a series of cells or chambers comprising walls surrounding void space, each wall forming the wall of an adjacent cell; each wall containing many holes penetrating through the wall yielding an overall porous structure and allowing useful levels of gas transport. 4 figs.

  4. Method for immobilizing particulate materials in a packed bed

    DOE Patents [OSTI]

    Even, Jr., William R.; Guthrie, Stephen E.; Raber, Thomas N.; Wally, Karl; Whinnery, LeRoy L.; Zifer, Thomas

    1999-01-01

    The present invention pertains generally to immobilizing particulate matter contained in a "packed" bed reactor so as to prevent powder migration, compaction, coalescence, or the like. More specifically, this invention relates to a technique for immobilizing particulate materials using a microporous foam-like polymer such that a) the particulate retains its essential chemical nature, b) the local movement of the particulate particles is not unduly restricted, c) bulk powder migration and is prevented, d) physical and chemical access to the particulate is unchanged over time, and e) very high particulate densities are achieved. The immobilized bed of the present invention comprises a vessel for holding particulate matter, inlet and an outlet ports or fittings, a loosely packed bed of particulate material contained within the vessel, and a three dimensional porous matrix for surrounding and confining the particles thereby fixing the movement of individual particle to a limited local position. The established matrix is composed of a series of cells or chambers comprising walls surrounding void space, each wall forming the wall of an adjacent cell; each wall containing many holes penetrating through the wall yielding an overall porous structure and allowing useful levels of gas transport.

  5. Pitch based foam with particulate

    DOE Patents [OSTI]

    Klett, James W. (Knoxville, TN)

    2001-01-01

    A thermally conductive, pitch based foam composite having a particulate content. The particulate alters the mechanical characteristics of the foam without severely degrading the foam thermal conductivity. The composite is formed by mixing the particulate with pitch prior to foaming.

  6. Airborne particulate discriminator

    DOE Patents [OSTI]

    Creek, Kathryn Louise; Castro, Alonso; Gray, Perry Clayton

    2009-08-11

    A method and apparatus for rapid and accurate detection and discrimination of biological, radiological, and chemical particles in air. A suspect aerosol of the target particulates is treated with a taggant aerosol of ultrafine particulates. Coagulation of the taggant and target particles causes a change in fluorescent properties of the cloud, providing an indication of the presence of the target.

  7. Advanced Hybrid Particulate Collector Project Management Plan

    SciTech Connect (OSTI)

    Miller, S.J.

    1995-11-01

    As the consumption of energy increases, its impact on ambient air quality has become a significant concern. Recent studies indicate that fine particles from coal combustion cause health problems as well as atmospheric visibility impairment. These problems are further compounded by the concentration of hazardous trace elements such as mercury, cadmium, selenium, and arsenic in fine particles. Therefore, a current need exists to develop superior, but economical, methods to control emissions of fine particles. Since most of the toxic metals present in coal will be in particulate form, a high level of fine- particle collection appears to be the best method of overall air toxics control. However, over 50% of mercury and a portion of selenium emissions are in vapor form and cannot be collected in particulate control devices. Therefore, this project will focus on developing technology not only to provide ultrahigh collection efficiency of particulate air toxic emissions, but also to capture vapor- phase trace metals such as mercury and selenium. Currently, the primary state-of-the-art technologies for particulate control are fabric filters (baghouses) and electrostatic precipitators (ESPs). However, they both have limitations that prevent them from achieving ultrahigh collection of fine particulate matter and vapor-phase trace metals. The objective of this project is to develop a highly reliable advanced hybrid particulate collector (AHPC) that can provide > 99.99 % particulate collection efficiency for all particle sizes between 0.01 and 50 14m, is applicable for use with all U.S. coals, and is cost-0443competitive with existing technologies. Phase I of the project is organized into three tasks: Task I - Project Management, Reporting, and Subcontract Consulting Task 2 - Modeling, Design, and Construction of 200-acfm AHPC Model Task 3 - Experimental Testing and Subcontract Consulting

  8. Face crack reduction strategy for particulate filters

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI

    2012-01-31

    A system comprises a particulate matter (PM) filter that comprises an upstream end for receiving exhaust gas, a downstream end and at least one portion. A control module initiates combustion of PM in the PM filter using a heater and selectively adjusts oxygen levels of the exhaust gas to adjust a temperature of combustion adjacent to the at least one portion of the PM filter. A method comprises providing a particulate matter (PM) filter that comprises an upstream end for receiving exhaust gas, a downstream end and at least one portion; initiating combustion of PM in the PM filter using a heater; selectively adjusting oxygen levels of the exhaust gas to adjust a temperature of combustion adjacent to the at least one portion of the PM filter.

  9. Carbon monoxide sensor and method of use

    DOE Patents [OSTI]

    Dutta, Prabir K.; Swartz, Scott L.; Holt, Christopher T.; Revur, Ramachandra Rao

    2006-01-10

    A sensor and method of use for detection of low levels of carbon monoxide in gas mixtures. The approach is based on the change in an electrical property (for example: resistance) that occurs when carbon monoxide is selectively absorbed by a film of copper chloride (or other metal halides). The electrical property change occurs rapidly with both increasing and decreasing CO contents, varies with the amount of CO from the gas stream, and is insensitive to the presence of hydrogen. To make a sensor using this approach, the metal halide film will deposited onto an alumina substrate with electrodes. The sensor may be maintained at the optimum temperature with a thick film platinum heater deposited onto the opposite face of the substrate. When the sensor is operating at an appropriate (and constant) temperature, the magnitude of the electrical property measured between the interdigital electrodes will provide a measure of the carbon monoxide content of the gas.

  10. Method of feeding particulate material to a fluidized bed

    DOE Patents [OSTI]

    Borio, Richard W. (Somers, CT); Goodstine, Stephen L. (Windsor, CT)

    1984-01-01

    A centrifugal spreader type feeder that supplies a mixture of particulate limestone and coal to the top of a fluidized bed reactor having a flow of air upward therethrough. Large particles of particulate matter are distributed over the upper surface of the bed to utilize the natural mixing within the bed, while fine particles are adapted to utilize an independent feeder that separates them from the large particles and injects them into the bed.

  11. Radiant zone heated particulate filter

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI

    2011-12-27

    A system includes a particulate matter (PM) filter including an upstream end for receiving exhaust gas and a downstream end. A radiant zoned heater includes N zones, where N is an integer greater than one, wherein each of the N zones includes M sub-zones, where M is an integer greater than or equal to one. A control module selectively activates at least a selected one of the N zones to initiate regeneration in downstream portions of the PM filter from the one of the N zones, restricts exhaust gas flow in a portion of the PM filter that corresponds to the selected one of the N zones, and deactivates non-selected ones of the N zones.

  12. Particulate contamination removal from wafers using plasmas and mechanical agitation

    DOE Patents [OSTI]

    Selwyn, G.S.

    1998-12-15

    Particulate contamination removal from wafers is disclosed using plasmas and mechanical agitation. The present invention includes the use of plasmas with mechanical agitation for removing particulate matter from the surface of a wafer. The apparatus hereof comprises a mechanical activator, at least one conducting contact pin for transferring the vibration from the activator to the wafer, clamp fingers that maintain the wafer`s position, and means for generating a plasma in the vicinity of the surface of the wafer, all parts of the cleaning apparatus except the mechanical activator and part of the contact pin being contained inside the processing chamber. By exposing a wafer to a plasma and providing motion thereto in a direction perpendicular to its surface, the bonding between the particulate matter and the surface may be overcome. Once free of the wafer surface, the particulates become charged by electrons from the plasma and are drawn into the plasma by attractive forces which keep them from redepositing. The introduction of a flowing gas through the plasma sweeps the particulates away from the wafer and out of the plasma. The entire surface is cleaned during one cleaning step. The use of an rf plasma to accomplish the particulate removal was found to remove more than 90% of the particulates. 4 figs.

  13. Particulate contamination removal from wafers using plasmas and mechanical agitation

    DOE Patents [OSTI]

    Selwyn, Gary S. (Los Alamos, NM)

    1998-01-01

    Particulate contamination removal from wafers using plasmas and mechanical agitation. The present invention includes the use of plasmas with mechanical agitation for removing particulate matter from the surface of a wafer. The apparatus hereof comprises a mechanical activator, at least one conducting contact pin for transferring the vibration from the activator to the wafer, clamp fingers that maintain the wafer's position, and means for generating a plasma in the vicinity of the surface of the wafer, all parts of the cleaning apparatus except the mechanical activator and part of the contact pin being contained inside the processing chamber. By exposing a wafer to a plasma and providing motion thereto in a direction perpendicular to its surface, the bonding between the particulate matter and the surface may be overcome. Once free of the wafer surface, the particulates become charged by electrons from the plasma and are drawn into the plasma by attractive forces which keep them from redepositing. The introduction of a flowing gas through the plasma sweeps the particulates away from the wafer and out of the plasma. The entire surface is cleaned during one cleaning step. The use of an rf plasma to accomplish the particulate removal was found to remove more than 90% of the particulates.

  14. Advanced Fine Particulate Characterization Methods

    SciTech Connect (OSTI)

    Steven Benson; Lingbu Kong; Alexander Azenkeng; Jason Laumb; Robert Jensen; Edwin Olson; Jill MacKenzie; A.M. Rokanuzzaman

    2007-01-31

    The characterization and control of emissions from combustion sources are of significant importance in improving local and regional air quality. Such emissions include fine particulate matter, organic carbon compounds, and NO{sub x} and SO{sub 2} gases, along with mercury and other toxic metals. This project involved four activities including Further Development of Analytical Techniques for PM{sub 10} and PM{sub 2.5} Characterization and Source Apportionment and Management, Organic Carbonaceous Particulate and Metal Speciation for Source Apportionment Studies, Quantum Modeling, and High-Potassium Carbon Production with Biomass-Coal Blending. The key accomplishments included the development of improved automated methods to characterize the inorganic and organic components particulate matter. The methods involved the use of scanning electron microscopy and x-ray microanalysis for the inorganic fraction and a combination of extractive methods combined with near-edge x-ray absorption fine structure to characterize the organic fraction. These methods have direction application for source apportionment studies of PM because they provide detailed inorganic analysis along with total organic and elemental carbon (OC/EC) quantification. Quantum modeling using density functional theory (DFT) calculations was used to further elucidate a recently developed mechanistic model for mercury speciation in coal combustion systems and interactions on activated carbon. Reaction energies, enthalpies, free energies and binding energies of Hg species to the prototype molecules were derived from the data obtained in these calculations. Bimolecular rate constants for the various elementary steps in the mechanism have been estimated using the hard-sphere collision theory approximation, and the results seem to indicate that extremely fast kinetics could be involved in these surface reactions. Activated carbon was produced from a blend of lignite coal from the Center Mine in North Dakota and sunflower hulls for the biomass material to be carbonized. The ability to remove mercury from a bituminous coal's derived flue gas was low. Removals of only 15% were attained while injecting 6 lb/Macf of activated carbon upstream of an electrostatic precipitator. Poisoning of sites on the activated carbon by SO{sub 2} and SO{sub 3} contributed to the poor mercury capture performance.

  15. Method and apparatus for selective removal of carbon monoxide

    DOE Patents [OSTI]

    Borup, Rodney L. (East Rochester, NY); Skala, Glenn W. (Churchville, NY); Brundage, Mark A. (Pittsford, NY); LaBarge, William J. (Bay City, MI)

    2000-01-01

    There is provided a method and apparatus for treatment of a hydrogen-rich gas to reduce the carbon monoxide content thereof by reacting the carbon monoxide in the gas with an amount of oxygen sufficient to oxidize at least a portion of the carbon monoxide in the presence of a catalyst in a desired temperature range without substantial reaction of hydrogen. The catalyst is an iridium-based catalyst dispersed on, and supported on, a carrier. In the presence of the catalyst, carbon monoxide in a hydrogen-rich feed gas is selectively oxidized such that a product stream is produced with a very low carbon monoxide content.

  16. Performance of the Low-Efficiency Diesel Particulate Filter for Diesel PM

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Reduction | Department of Energy the Low-Efficiency Diesel Particulate Filter for Diesel PM Reduction Performance of the Low-Efficiency Diesel Particulate Filter for Diesel PM Reduction Poster presented at the 16th Directions in Engine-Efficiency and Emissions Research (DEER) Conference in Detroit, MI, September 27-30, 2010. PDF icon p-15_wei.pdf More Documents & Publications On-Road PM Mass Emission Measured with OBS-TRPM Investigation of Direct Injection Vehicle Particulate Matter

  17. Monitoring and Control of Alkali Volatilization and Batch Carryover for Minimization of Particulates and Crown Corrosion

    SciTech Connect (OSTI)

    2001-01-01

    New Technology will Allow Glass Manufacturers to Optimize Furnace Conditions. Laser-induced breakdown spectroscopy is a continuous monitoring technique that glass manufacturers can use to reduce particulate matter emissions and extend furnace life.

  18. Fluidizing device for solid particulates

    DOE Patents [OSTI]

    Diebold, James P. (Lakewood, CO); Scahill, John W. (Golden, CO)

    1986-01-01

    A flexible whip or a system of whips with novel attachments is suspended in a hopper and is caused to impact against fibrous and irregularly shaped particulates in the hopper to fluidize the particulates and facilitate the flow of the particulates through the hopper. The invention provides for the flow of particulates at a substantially constant mass flow rate and uses a minimum of energy.

  19. Fluidizing device for solid particulates

    DOE Patents [OSTI]

    Diebold, J.P.; Scahill, J.W.

    1984-06-27

    A flexible whip or a system of whips with novel attachments is suspended in a hopper and is caused to impact against fibrous and irregularly shaped particulates in the hopper to fluidize the particulates and facilitate the flow of the particulates through the hopper. The invention provides for the flow of particulates at a substantially constant mass flow rate and uses a minimum of energy.

  20. Electrically-Assisted Diesel Particulate Filter Regeneration...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Substrate Studies of an Electrically-Assisted Diesel Particulate Filter Electrically-Assisted Diesel Particulate Filter Regeneration...

  1. Advanced Particulate Filter Technologies for Direct Injection...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Particulate Filter Technologies for Direct Injection Gasoline Engine Applications Advanced Particulate Filter Technologies for Direct Injection Gasoline Engine Applications Specific ...

  2. Electrically heated particulate filter with reduced stress

    DOE Patents [OSTI]

    Gonze, Eugene V.

    2013-03-05

    A system comprises a particulate matter (PM) filter comprising an inlet for receiving exhaust gas. A zoned heater is arranged in the inlet and comprises a resistive heater comprising N zones, where N is an integer greater than one. Each of the N zones comprises M sub-zones, where M is an integer greater than one. A control module selectively activates one of the N zones to initiate regeneration in downstream portions of the PM filter from the one of the N zones and deactivates others of the N zones.

  3. Void/particulate detector

    DOE Patents [OSTI]

    Claytor, T.N.; Karplus, H.B.

    1983-09-26

    Apparatus for detecting voids and particulates in a flowing stream of fluid contained in a pipe may comprise: (a) a transducer for transmitting an ultrasonic signal into the stream, coupled to the pipe at a first location; (b) a second transducer for detecting the through-transmission of said signal, coupled to the pipe at a second location; (c) a third transducer for detecting the back-scattering of said signal, coupled to the pipe at a third location, said third location being upstream from said first location; (d) circuit means for normalizing the back-scattered signal from said third transducer to the through-transmitted signal from said second transducer; which normalized signal provides a measure of the voids and particulates flowing past said first location.

  4. Regenerable particulate filter

    DOE Patents [OSTI]

    Stuecker, John N. (Albuquerque, NM); Cesarano, III, Joseph (Albuquerque, NM); Miller, James E. (Albuquerque, NM)

    2009-05-05

    A method of making a three-dimensional lattice structure, such as a filter used to remove particulates from a gas stream, where the physical lattice structure is designed utilizing software simulation from pre-defined mass transfer and flow characteristics and the designed lattice structure is fabricated using a free-form fabrication manufacturing technique, where the periodic lattice structure is comprised of individual geometric elements.

  5. CO (Carbon Monoxide Mixing Ratio System) Handbook

    SciTech Connect (OSTI)

    Biraud, S

    2011-02-23

    The main function of the CO instrument is to provide continuous accurate measurements of carbon monoxide mixing ratio at the ARM SGP Central Facility (CF) 60-meter tower (36.607 °N, 97.489 °W, 314 meters above sea level). The essential feature of the control and data acquisition system is to record signals from a Thermo Electron 48C and periodically calibrate out zero and span drifts in the instrument using the combination of a CO scrubber and two concentrations of span gas (100 and 300 ppb CO in air). The system was deployed on May 25, 2005.

  6. Sandia Energy - Heavy Duty Low-Temperature & Diesel Combustion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    toxic air pollutants including particulate matter (PM), smog-forming nitrogen oxides (NOx) and unburned hydrocarbons, and carbon monoxide (CO). To address these challenges,...

  7. Reduction of Carbon Monoxide. Past Research Summary

    DOE R&D Accomplishments [OSTI]

    Schrock, R. R.

    1982-01-01

    Research programs for the year on the preparation, characterization, and reactions of binuclear tantalum complexes are described. All evidence to date suggest the following of these dimeric molecules: (1) the dimer does not break into monomers under mild conditions; (2) intermolecular hydride exchange is not negligible, but it is slow; (3) intermolecular non-ionic halide exchange is fast; (4) the ends of the dimers can rotate partially with respect to one another. The binuclear tantalum hydride complexes were found to react with carbon monoxide to give a molecule which is the only example of reduction of CO by a transition metal hydride to give a complex containing a CHO ligand. Isonitrides also reacted in a similar manner with dimeric tantalum hydride. (ATT)

  8. Carbon monoxide sensor and method of use thereof

    DOE Patents [OSTI]

    McDaniel; Anthony H. (Livermore, CA), Medlin; J. Will (Boulder, CO), Bastasz; Robert J. (Livermore, CA)

    2007-09-04

    Carbon monoxide sensors suitable for use in hydrogen feed streams and methods of use thereof are disclosed. The sensors are palladium metal/insulator/semiconductor (Pd-MIS) sensors which may possess a gate metal layer having uniform, Type 1, or non-uniform, Type 2, film morphology. Type 1 sensors display an increased sensor response in the presence of carbon monoxide while Type 2 sensors display a decreased response to carbon monoxide. The methods and sensors disclosed herein are particularly suitable for use in proton exchange membrane fuel cells (PEMFCs).

  9. Microwave mode shifting antenna system for regenerating particulate filters

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI; Kirby, Kevin W [Calabasas Hills, CA; Phelps, Amanda [Malibu, CA; Gregoire, Daniel J [Thousand Oaks, CA

    2011-04-26

    A regeneration system comprises a particulate matter (PM) filter including a microwave energy absorbing surface, and an antenna system comprising N antennas and an antenna driver module that sequentially drives the antenna system in a plurality of transverse modes of the antenna system to heat selected portions of the microwave absorbing surface to regenerate the PM filter, where N is an integer greater than one. The transverse modes may include transverse electric (TE) and/or transverse magnetic (TM) modes.

  10. ADVANCED HYBRID PARTICULATE COLLECTOR

    SciTech Connect (OSTI)

    Ye Zhuang; Stanley J. Miller; Michelle R. Olderbak; Rich Gebert

    2001-12-01

    A new concept in particulate control, called an advanced hybrid particulate collector (AHPC), is being developed under funding from the U.S. Department of Energy. The AHPC combines the best features of electrostatic precipitators (ESPs) and baghouses in an entirely novel manner. The AHPC concept combines fabric filtration and electrostatic precipitation in the same housing, providing major synergism between the two methods, both in the particulate collection step and in transfer of dust to the hopper. The AHPC provides ultrahigh collection efficiency, overcoming the problem of excessive fine-particle emissions with conventional ESPs, and solves the problem of reentrainment and re-collection of dust in conventional baghouses. Phase I of the development effort consisted of design, construction, and testing of a 5.7-m{sup 3}/min (200-acfm) working AHPC model. Results from both 8-hr parametric tests and 100-hr proof-of-concept tests with two different coals demonstrated excellent operability and greater than 99.99% fine-particle collection efficiency. Since all of the developmental goals of Phase I were met, the approach was scaled up in Phase II to a size of 255 m{sup 3}/min (9000 acfm) (equivalent in size to 2.5 MW) and was installed on a slipstream at the Big Stone Power Plant. For Phase II, the AHPC at Big Stone Power Plant was operated continuously from late July 1999 until mid-December 1999. The Phase II results were highly successful in that ultrahigh particle collection efficiency was achieved, pressure drop was well controlled, and system operability was excellent. For Phase III, the AHPC was modified into a more compact configuration, and components were installed that were closer to what would be used in a full-scale commercial design. The modified AHPC was operated from April to July 2000. While operational results were acceptable during this time, inspection of bags in the summer of 2000 revealed some membrane damage to the fabric that appeared to be caused by electrical effects. Subsequently, extensive theoretical, bench-scale, and pilot-scale investigations were completed to find an approach to prevent bag damage without compromising AHPC performance. Results showed that the best bag protection and AHPC performance were achieved by using a perforated plate installed between the discharge electrodes and bags. This perforated-plate design was then installed in the 2.5-MW AHPC at Big Stone Power Plant in Big Stone City, South Dakota, and the AHPC was operated from March to June 2001. Results showed that the perforated-plate design solved the bag damage problem and offered even better AHPC performance than the previous design. All of the AHPC performance goals were met, including ultrahigh collection efficiency, high air-to-cloth ratio, reasonable pressure drop, and long bag-cleaning interval.

  11. Overlap zoned electrically heated particulate filter

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI; Chapman, Mark R [Brighton, MI

    2011-07-19

    A system includes a particulate matter (PM) filter that includes an upstream end for receiving exhaust gas and a downstream end. A zoned heater is arranged spaced from the upstream end and comprises N zones, where N is an integer greater than one, wherein each of the N zones comprises M sub-zones, where M is an integer greater than or equal to one, and wherein the N zones and the M sub-zones are arranged in P layers, where P is an integer greater than one. A control module selectively activates at least a selected one of the N zones to initiate regeneration in downstream portions of the PM filter from the one of the N zones and deactivates non-selected ones of the N zones.

  12. Process for the conversion of carbonaceous feedstocks to particulate carbon and methanol

    DOE Patents [OSTI]

    Steinberg, M.; Grohse, E.W.

    1995-06-27

    A process is described for the production of a pollutant-free particulate carbon (i.e., a substantially ash-, sulfur- and nitrogen-free carbon) from carbonaceous feedstocks. The basic process involves de-oxygenating one of the gas streams formed in a cyclic hydropyrolysis-methane pyrolysis process in order to improve conversion of the initial carbonaceous feedstock. De-oxygenation is effected by catalytically converting carbon monoxide, carbon dioxide, and hydrogen contained in one of the pyrolysis gas streams, preferably the latter, to a methanol co-product. There are thus produced two products whose use is known per se, viz., a substantially pollutant-free particulate carbon black and methanol. These products may be admixed in the form of a liquid slurry of carbon black in methanol. 3 figs.

  13. Process for the conversion of carbonaceous feedstocks to particulate carbon and methanol

    DOE Patents [OSTI]

    Steinberg, Meyer (Melville, NY); Grohse, Edward W. (Port Jefferson, NY)

    1995-01-01

    A process for the production of a pollutant-free particulate carbon (i.e., a substantially ash-, sulfur- and nitrogen-free carbon) from carbonaceous feedstocks. The basic process involves de-oxygenating one of the gas streams formed in a cyclic hydropyrolysis-methane pyrolysis process in order to improve conversion of the initial carbonaceous feedstock. De-oxygenation is effected by catalytically converting carbon monoxide, carbon dioxide, and hydrogen contained in one of the pyrolysis gas streams, preferably the latter, to a methanol co-product. There are thus produced two products whose use is known per se, viz., a substantially pollutant-free particulate carbon black and methanol. These products may be admixed in the form of a liquid slurry of carbon black in methanol.

  14. Investigations of release phenomenon of volatile organic compounds and particulates from residual storage chip piles

    SciTech Connect (OSTI)

    Mohan, S.; Nagarkatti, M.

    1996-12-31

    This paper outlines the method for estimating Particulate Matter and Volatile Organic Compounds (VOCs) emissions from wood handling and storage operations at a pulp mill. Fugitive particulate matter emissions from wood handling and storage operations are due to material load/dropout operations, wind erosion from storage piles and vehicular traffic on paved roads. The particulate matter emissions are a function of a number of variables like windspeed, surface moisture content, material silt content, and number of days of precipitation. Literature review attributes VOC emissions to biological, microbiological, chemical, and physical processes occurring in wood material storage pile. The VOC emissions are from the surface of these piles and the VOC released during retrieval of chips from the pile. VOC emissions are based on the chip throughput, number of turnovers, moisture content and surface area of the pile. The emission factors with the requisite calculation methodology to be utilized for quantifying VOC emissions from chip piles has been discussed in this paper.

  15. Electrical diesel particulate filter (DPF) regeneration

    DOE Patents [OSTI]

    Gonze, Eugene V; Ament, Frank

    2013-12-31

    An exhaust system that processes exhaust generated by an engine includes a diesel particulate filter (DPF) that is disposed downstream of the engine and that filters particulates from the exhaust. An electrical heater is disposed upstream of the DPF and selectively heats the exhaust to initiate combustion of the particulates within the exhaust as it passes therethrough. Heat generated by combustion of the particulates induces combustion of particulates within the DPF.

  16. Advanced Diesel Combustion with Low Hydrocarbon and Carbon Monoxide...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Effects of Ignition Quality and Fuel Composition on Critical Equivalence Ratio Particulate Produced from Advanced Combustion Operation in a ...

  17. Terpolymerization of ethylene, sulfur dioxide and carbon monoxide

    DOE Patents [OSTI]

    Johnson, Richard (Shirley, NY); Steinberg, Meyer (Huntington Station, NY)

    1981-01-01

    This invention relates to a high molecular weight terpolymer of ethylene, sulfur dioxide and carbon monoxide stable to 280.degree. C. and containing as little as 36 mol % ethylene and about 41-51 mol % sulfur dioxide; and to the method of producing said terpolymer by irradiation of a liquid and gaseous mixture of ethylene, sulfur dioxide and carbon monoxide by means of Co-60 gamma rays or an electron beam, at a temperature of about 10.degree.-50.degree. C., and at a pressure of about 140 to 680 atmospheres, to initiate polymerization.

  18. Fuel-Neutral Studies of Particulate Matter Transport Emissions

    Broader source: Energy.gov [DOE]

    2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  19. Concentrations and Size Distributions of Particulate Matter Emissions...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Investigation of the Effects of Fuels and Aftertreatment Devices on the Emission Profiles of Trucks and Buses ARB's Study of Emissions from Diesel and CNG Heavy-duty Transit Buses ...

  20. Effects of Advanced Combustion Technologies on Particulate Matter...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Emissions from Advanced Technologies Efficient Emissions Control for Multi-Mode Lean DI Engines Measurement and Characterization of Lean NOx Adsorber Regeneration and...

  1. Observations and Modeling of GoAmazon Particulate Matter and...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... The scientific literature agrees that this air pollution is a significant threat to the health of the world population, especially in developing countries (WHO 2006, Bruce et al. ...

  2. Optical Backscatter Probe for Sensing Particulate Matter - Energy...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    This Technology Technology Marketing SummaryTo provide emissions information for automotive engines, ORNL researchers developed a technology that enables very rapid measurement...

  3. Fuel-Neutral Studies of Particulate Matter Transport Emissions...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon ace056stewart2012o.pdf More Documents & Publications Characterization of Pre-Commercial Gasoline ...

  4. Catalytic fabric filtration for simultaneous NO{sub x} and particulate control. Final report

    SciTech Connect (OSTI)

    Weber, G.F.; Dunham, G.E.; Laudal, D.L.; Ness, S.R.; Schelkoph, G.L.

    1994-08-01

    The overall objective of the project proposed was to evaluate the catalyst-coated fabric filter concept for effective control of NO{sub 2} and particulate emissions simultaneously. General goals included demonstrating high removal efficiency of NO{sub x} and particulate matter, acceptable bag and catalyst life, and that process economics show a significant cost savings in comparison to a commercial SCR process and conventional particulate control. Specific goals included the following: reduce NO{sub x} emissions to 60 ppM or less; demonstrate particulate removal efficiency of >99.5%; demonstrate a bag/catalyst life of >1 year; Control ammonia slip to <25 ppM; show that catalytic fabric filtration can achieve a 50% cost savings over conventional fabric filtration and SCR control technology; determine compatibility with S0{sub 2} removal systems; and show that the concept results in a nonhazardous waste product.

  5. Ceramic Particulate Filters | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ceramic Particulate Filters Ceramic Particulate Filters Poster presentation at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August, 2007, Detroit, Michigan. Sponsored by the U.S. Department of Energy's (DOE) Office of FreedomCAR and Vehicle Technologies (OFCVT). PDF icon deer07_yonushonis.pdf More Documents & Publications Durability of Diesel Engine Particulate Filters Durability of Diesel Engine Particulate Filters Durability of Diesel Engine

  6. Real-Time Particulate Mass Measurements Pre and Post Diesel Particulate

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Filters for LIght-Duty Diesel Vehicles | Department of Energy Particulate Mass Measurements Pre and Post Diesel Particulate Filters for LIght-Duty Diesel Vehicles Real-Time Particulate Mass Measurements Pre and Post Diesel Particulate Filters for LIght-Duty Diesel Vehicles PDF icon 2005_deer_anderson.pdf More Documents & Publications Advanced Radio Frequency-Based Sensors for Monitoring Diesel Particulate Filter Loading and Regeneration Real-Time Measurement of Diesel Trap Efficiency

  7. Electrically heated particulate filter with zoned exhaust flow control

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI

    2012-06-26

    A system includes a particulate matter (PM) filter that includes X zones. An electrical heater includes Y heater segments that are associated with respective ones of the X zones. The electrical heater is arranged upstream from and proximate with the PM filter. A valve assembly includes Z sections that are associated with respective ones of the X zones. A control module adjusts flow through each of the Z sections during regeneration of the PM filter via control of the valve assembly. X, Y and Z are integers.

  8. Zoned electrical heater arranged in spaced relationship from particulate filter

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI

    2011-11-15

    A system comprises a particulate matter (PM) filter that comprises an upstream end for receiving exhaust gas and a downstream end. A zoned heater is arranged spaced from the upstream end and comprises N zones, where N is an integer greater than one, wherein each of the N zones comprises M sub-zones, where M is an integer greater than one. A control module selectively activates at least a selected one of the N zones to initiate regeneration in downstream portions of the PM filter from the one of the N zones and deactivates non-selected ones of the N zones.

  9. Particulate Generation in Tritium Systems

    Office of Environmental Management (EM)

    Particulate Generation in a Tritium System Paul Cloessner, PhD Laboratory Fellow Tritium Focus Group February 22, 2014 Outline * Description of Events * Analysis of Material * Sources of material contamination * System Restoration/Modifications * Contaminant Minimization and Control * Lessons Learned 2 An Unpleasant Surprise * Let down filter on compressor became plugged after 10 years of operation. * Tritium processing interrupted when other filters (flow orifices) became plugged approximately

  10. Catalyst for the methanation of carbon monoxide in sour gas

    DOE Patents [OSTI]

    Kustes, William A. (Louisville, KY); Hausberger, Arthur L. (Louisville, KY)

    1985-01-01

    The invention involves the synergistic effect of the specific catalytic constituents on a specific series of carriers for the methanation of carbon monoxide in the presence of sulfur at relatively high temperatures and at low steam to gas ratios in the range of 0.2:1 or less. This effect was obtained with catalysts comprising the mixed sulfides and oxides of nickel and chromium supported on carriers comprising magnesium aluminate and magnesium silicate. Conversion of carbon monoxide to methane was in the range of from 40 to 80%. Tests of this combination of metal oxides and sulfides on other carriers and tests of other metal oxides and sulfides on the same carrier produced a much lower level of conversion.

  11. Composite catalyst for carbon monoxide and hydrocarbon oxidation

    DOE Patents [OSTI]

    Liu, Wei (Cambridge, MA); Flytzani-Stephanopoulos, Maria (Winchester, MA)

    1996-01-01

    A method and composition for the complete oxidation of carbon monoxide and/or hydrocarbon compounds. The method involves reacting the carbon monoxide and/or hydrocarbons with an oxidizing agent in the presence of a metal oxide composite catalyst. The catalyst is prepared by combining fluorite-type oxygen ion conductors with active transition metals. The fluorite oxide, selected from the group consisting of cerium oxide, zirconium oxide, thorium oxide, hafnium oxide, and uranium oxide, and may be doped by alkaline earth and rare earth oxides. The transition metals, selected from the group consisting of molybdnum, copper, cobalt, maganese, nickel, and silver, are used as additives. The atomic ratio of transition metal to fluorite oxide is less than one.

  12. Composite catalyst for carbon monoxide and hydrocarbon oxidation

    DOE Patents [OSTI]

    Liu, W.; Flytzani-Stephanopoulos, M.

    1996-03-19

    A method and composition are disclosed for the complete oxidation of carbon monoxide and/or hydrocarbon compounds. The method involves reacting the carbon monoxide and/or hydrocarbons with an oxidizing agent in the presence of a metal oxide composite catalyst. The catalyst is prepared by combining fluorite-type oxygen ion conductors with active transition metals. The fluorite oxide, selected from the group consisting of cerium oxide, zirconium oxide, thorium oxide, hafnium oxide, and uranium oxide, and may be doped by alkaline earth and rare earth oxides. The transition metals, selected from the group consisting of molybdenum, copper, cobalt, manganese, nickel, and silver, are used as additives. The atomic ratio of transition metal to fluorite oxide is less than one.

  13. Carbon Monoxide Tolerant Electrocatalyst with Low Platinum Loading and a

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Process for its Preparation - Energy Innovation Portal Startup America Startup America Hydrogen and Fuel Cell Hydrogen and Fuel Cell Find More Like This Return to Search Carbon Monoxide Tolerant Electrocatalyst with Low Platinum Loading and a Process for its Preparation Brookhaven National Laboratory Contact BNL About This Technology Publications: PDF Document Publication Pt Submonolayers on Ru Nanoparticles: A Novel Low Pt Loading, High CO Tolerance Fuel Cell Electrocatalyst (173 KB)

  14. MOL.19980331.0174 PARTICULATE MATTEX AMBIENT A I R QUALITY

    National Nuclear Security Administration (NNSA)

    MOL.19980331.0174 PARTICULATE MATTEX AMBIENT A I R QUALITY DATA REPORT FOR 1989 AND 1990 WBS No. 1.2.5.4.2 Contract No. DE-AC08-87NVl0576 March 1992 Prepared by: Radiological/Environmental Field Programs Department Science Applications International Corporation Technical & Management Support Services Las Vegas, Nevada 1.0 MECUTIVE SUMMARY Routine particulate matter ambient air quality monitoring has been performed at two stations in the Yucca Mountain air monitoring network since the spring

  15. NNA.921218.0092 PARTICULATE MATIER AMEIENT AIR QUALITY DATA REPORT FOR 1991

    National Nuclear Security Administration (NNSA)

    NNA.921218.0092 PARTICULATE MATIER AMEIENT AIR QUALITY DATA REPORT FOR 1991 WBS No. 1.2.13.4.2 Contract No. DE-ACO8-87NV10576 Oc tobe r 199 2 Prepared by: Radiological/Environmental Field Programs Department Science Applications International Corporation Technical & Management Support Services L a s Vegas, Nevada TABLE OF CONTENTS m Section 1. Executive Summary 2. 3. Results Particulate Matter Ambient Air Quality Monitoring Methods List of Tables 1-1 3-1 3-2 3-3 3-4 3-5 3-6 Page 1-1 2-1 3-1

  16. Diesel particulate filter with zoned resistive heater

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI

    2011-03-08

    A diesel particulate filter assembly comprises a diesel particulate filter (DPF) and a heater assembly. The DPF filters a particulate from exhaust produced by an engine. The heater assembly has a first metallic layer that is applied to the DPF, a resistive layer that is applied to the first metallic layer, and a second metallic layer that is applied to the resistive layer. The second metallic layer is etched to form a plurality of zones.

  17. Zone heated diesel particulate filter electrical connection

    DOE Patents [OSTI]

    Gonze, Eugene V. (Pinckney, MI); Paratore, Jr., Michael J. (Howell, MI)

    2010-03-30

    An electrical connection system for a particulate filter is provided. The system includes: a particulate filter (PF) disposed within an outer shell wherein the PF is segmented into a plurality of heating zones; an outer mat disposed between the particulate filter and the outer shell; an electrical connector coupled to the outer shell of the PF; and a plurality of printed circuit connections that extend along the outer surface of the PF from the electrical connector to the plurality of heating zones.

  18. Trends in Particulate Nanostructure | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Particulate Nanostructure Trends in Particulate Nanostructure This work attempts to explain the differences in the physical characteristics (nanostructure) of the soot across platforms, heavy-duty and light-duty, and biodiesel blend level. PDF icon p-10_strzelec.pdf More Documents & Publications Investigation of NO2 Oxidation Kinetics and Burning Mode for Medium Duty Diesel Particulate: Contrasting O2 and NO2 Oxidation Load Expansion with Diesel/Gasoline RCCI for Improved Engine Efficiency

  19. Diesel Particulate Filtration (DPF) Technology: Success stories...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Program Durability of Diesel Engine Particulate Filters High Temperature Thermoelectric Materials Characterization for Automotive Waste Heat Recovery: Success Stories from the...

  20. Electrically-Assisted Diesel Particulate Filter Regeneration...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    PDF icon pm041lance2011p.pdf More Documents & Publications Electrically-Assisted Diesel Particulate Filter Regeneration Substrate Studies of an Electrically-Assisted Diesel...

  1. Electrically heated particulate filter embedded heater design

    DOE Patents [OSTI]

    Gonze, Eugene V.; Chapman, Mark R.

    2014-07-01

    An exhaust system that processes exhaust generated by an engine is provided. The system generally includes a particulate filter (PF) that filters particulates from the exhaust wherein an upstream end of the PF receives exhaust from the engine and wherein an upstream surface of the particulate filter includes machined grooves. A grid of electrically resistive material is inserted into the machined grooves of the exterior upstream surface of the PF and selectively heats exhaust passing through the grid to initiate combustion of particulates within the PF.

  2. Electrically heated particulate filter using catalyst striping

    DOE Patents [OSTI]

    Gonze, Eugene V; Paratore, Jr., Michael J; Ament, Frank

    2013-07-16

    An exhaust system that processes exhaust generated by an engine is provided. The system generally includes a particulate filter (PF) that filters particulates from the exhaust wherein an upstream end of the PF receives exhaust from the engine. A grid of electrically resistive material is applied to an exterior upstream surface of the PF and selectively heats exhaust passing through the grid to initiate combustion of particulates within the PF. A catalyst coating is applied to the PF that increases a temperature of the combustion of the particulates within the PF.

  3. Particulate residue separators for harvesting devices

    DOE Patents [OSTI]

    Hoskinson, Reed L.; Kenney, Kevin L.; Wright, Christopher T.; Hess, John R.

    2010-06-29

    A particulate residue separator and a method for separating a particulate residue stream may include a plenum borne by a harvesting device, and have a first, intake end and a second, exhaust end; first and second particulate residue air streams which are formed by the harvesting device and which travel, at least in part, along the plenum and in a direction of the second, exhaust end; and a baffle assembly which is located in partially occluding relation relative to the plenum, and which substantially separates the first and second particulate residue air streams.

  4. Methods of separating particulate residue streams

    DOE Patents [OSTI]

    Hoskinson, Reed L. (Rigby, ID); Kenney, Kevin L. (Idaho Falls, ID); Wright, Christopher T. (Idaho Falls, ID); Hess, J. Richard (Idaho Falls, ID)

    2011-04-05

    A particulate residue separator and a method for separating a particulate residue stream may include an air plenum borne by a harvesting device, and have a first, intake end and a second, exhaust end; first and second particulate residue air streams that are formed by the harvesting device and that travel, at least in part, along the air plenum and in a direction of the second, exhaust end; and a baffle assembly that is located in partially occluding relation relative to the air plenum and that substantially separates the first and second particulate residue air streams.

  5. Preserving Diesel Exhaust Ultrafine (Nano-) Particulate Structure...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Exhaust Dispersion in a Phospholipid Lung Surfactant In Vitro Genotoxicity of Gasoline and Diesel Engine Vehicle Exhaust Particulate and Semi-Volatile Organic Compound Materials

  6. Combustor for fine particulate coal

    DOE Patents [OSTI]

    Carlson, L.W.

    1988-01-26

    A particulate coal combustor with two combustion chambers is provided. The first combustion chamber is toroidal; air and fuel are injected, mixed, circulated and partially combusted. The air to fuel ratio is controlled to avoid production of soot or nitrogen oxides. The mixture is then moved to a second combustion chamber by injection of additional air where combustion is completed and ash removed. Temperature in the second chamber is controlled by cooling and gas mixing. The clean stream of hot gas is then delivered to a prime mover. 4 figs.

  7. Combustor for fine particulate coal

    DOE Patents [OSTI]

    Carlson, Larry W. (Oswego, IL)

    1988-01-01

    A particulate coal combustor with two combustion chambers is provided. The first combustion chamber is toroidal; air and fuel are injected, mixed, circulated and partially combusted. The air to fuel ratio is controlled to avoid production of soot or nitrogen oxides. The mixture is then moved to a second combustion chamber by injection of additional air where combustion is completed and ash removed. Temperature in the second chamber is controlled by cooling and gas mixing. The clean stream of hot gas is then delivered to a prime mover.

  8. Combustor for fine particulate coal

    DOE Patents [OSTI]

    Carlson, L.W.

    1988-11-08

    A particulate coal combustor with two combustion chambers is provided. The first combustion chamber is toroidal; air and fuel are injected, mixed, circulated and partially combusted. The air to fuel ratio is controlled to avoid production of soot or nitrogen oxides. The mixture is then moved to a second combustion chamber by injection of additional air where combustion is completed and ash removed. Temperature in the second chamber is controlled by cooling and gas mixing. The clean stream of hot gas is then delivered to a prime mover. 4 figs.

  9. Pleated Ceramic Fiber Diesel Particulate Filter | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Pleated Ceramic Fiber Diesel Particulate Filter Pleated Ceramic Fiber Diesel Particulate Filter 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters PDF icon 2005_deer_nixdorf.pdf More Documents & Publications Versatile Diesel Particulate Filter Cartridge Any Size, Any Shape Ultra-Lite Diesel Particulate Filter Cartridge for Reduced Regeneration Time and Fuel Consumption Expanded Capacity Microwave-Cleaned Diesel Particulate Filter

  10. Dark Matters

    ScienceCinema (OSTI)

    Joseph Silk

    2010-01-08

    One of the greatest mysteries in the cosmos is that it is mostly dark.  Astronomers and particle physicists today are seeking to unravel the nature of this mysterious, but pervasive dark matter which has profoundly influenced the formation of structure in the universe.  I will describe the complex interplay between galaxy formation and dark matter detectability and review recent attempts to measure particle dark matter by direct and indirect means.

  11. Gold-catalyzed synthesis of carbonates and carbamates from carbon monoxide

    DOE Patents [OSTI]

    Friend, Cynthia M; Madix, Robert J; Xu, Bingjun

    2015-01-20

    The invention provides a method for producing organic carbonates via the reaction of alcohols and carbon monoxide with oxygen adsorbed on a metallic gold or gold alloy catalyst.

  12. Development of Advanced Diesel Particulate Filtration (DPF) Systems...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Particulate Filtration (DPF) Systems (ANLCorningCaterpillar CRADA) PDF icon ace22lee.pdf More Documents & Publications Development of Advanced Diesel Particulate Filtration...

  13. Mesoscale Simulations of Particulate Flows with Parallel Distributed...

    Office of Scientific and Technical Information (OSTI)

    Title: Mesoscale Simulations of Particulate Flows with Parallel Distributed Lagrange Multiplier Technique Fluid particulate flows are common phenomena in nature and industry. ...

  14. A New CFD Model for understanding and Managing Diesel Particulate...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CFD Model for understanding and Managing Diesel Particulate Filter Regeneration A New CFD Model for understanding and Managing Diesel Particulate Filter Regeneration PDF icon...

  15. New Cordierite Diesel Particulate Filters for Catalyzed and Non...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cordierite Diesel Particulate Filters for Catalyzed and Non-Catalyzed Applications New Cordierite Diesel Particulate Filters for Catalyzed and Non-Catalyzed Applications 2003 DEER...

  16. Durability of Diesel Particulate Filters - Bench Studies on Cordierite...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Particulate Filters - Bench Studies on Cordierite Filters Durability of Diesel Particulate Filters - Bench Studies on Cordierite Filters Presentation given at DEER 2006, August...

  17. Emissions and Durability of Underground Mining Diesel Particulate...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Testing an Active Diesel Particulate Filter on a 2-Cycle Marine Engine Ceramic Particulate Filters Development of an Accelerated Ash-Loading Protocol ...

  18. Requirements-Driven Diesel Catalyzed Particulate Trap Design...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Requirements-Driven Diesel Catalyzed Particulate Trap Design and Optimization Requirements-Driven Diesel Catalyzed Particulate Trap Design and Optimization 2005 Diesel Engine...

  19. Characterization of Particulate Emissions from GDI Engine Combustion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Particulate Emissions from GDI Engine Combustion with Alcohol-blended Fuels Characterization of Particulate Emissions from GDI Engine Combustion with Alcohol-blended Fuels Analysis ...

  20. 2007 Diesel Particulate Measurement Research (E-66 Project) ...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Diesel Particulate Measurement Research (E-66 Project) 2007 Diesel Particulate Measurement Research (E-66 Project) 2004 Diesel Engine Emissions Reduction (DEER) Conference:...

  1. Predicting Thermal Stress in Diesel Particulate Filters | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Thermal Stress in Diesel Particulate Filters Predicting Thermal Stress in Diesel Particulate Filters 2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation: Corning...

  2. Failure Stress and Apparent Elastic Modulus of Diesel Particulate...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Failure Stress and Apparent Elastic Modulus of Diesel Particulate Filter Ceramics Failure Stress and Apparent Elastic Modulus of Diesel Particulate Filter Ceramics Three...

  3. Characterization of Pre-Commercial Gasoline Engine Particulates...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Pre-Commercial Gasoline Engine Particulates Through Advanced Aerosol Methods Characterization of Pre-Commercial Gasoline Engine Particulates Through Advanced Aerosol Methods...

  4. Local Soot Loading Distribution in Cordierite Diesel Particulate...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Local Soot Loading Distribution in Cordierite Diesel Particulate Filters by Dynamic Neutron Radiography Local Soot Loading Distribution in Cordierite Diesel Particulate Filters by...

  5. Sizes, graphitic structures and fractal geometry of light-duty diesel engine particulates.

    SciTech Connect (OSTI)

    Lee, K. O.; Zhu, J.; Ciatti, S.; Choi, M. Y.; Energy Systems; Drexel Univ.

    2003-01-01

    The particulate matter of a light-duty diesel engine was characterized in its morphology, sizes, internal microstructures, and fractal geometry. A thermophoretic sampling system was employed to collect particulates directly from the exhaust manifold of a 1.7-liter turbocharged common-rail direct-injection diesel engine. The particulate samples collected at various engine-operating conditions were then analyzed by using a high-resolution transmission electron microscope (TEM) and an image processing/data acquisition system. Results showed that mean primary particle diameters (dp), and radii of gyration (Rg), ranged from 19.4 nm to 32.5 nm and 77.4 nm to 134.1 nm, respectively, through the entire engine-operating conditions of 675 rpm (idling) to 4000 rpm and 0% to 100% loads. It was also revealed that the other important parameters sensitive to the particulate formation, such as exhaust-gas recirculation (EGR) rate, equivalence ratio, and temperature, affected particle sizes significantly. Bigger primary particles were measured at higher EGR rates, higher equivalence ratios (fuel-rich), and lower exhaust temperatures. Fractal dimensions (D{sup f}) were measured at a range of 1.5 - 1.7, which are smaller than those measured for heavy-duty direct-injection diesel engine particulates in our previous study. This finding implies that the light-duty diesel engine used in this study produces more stretched chain-like shape particles, while the heavy-duty diesel engine emits more spherical particles. The microstructures of diesel particulates were observed at high TEM magnifications and further analyzed by a Raman spectroscope. Raman spectra revealed an atomic structure of the particulates produced at high engine loads, which is similar to that of typical graphite.

  6. Electrically heated particulate filter enhanced ignition strategy

    DOE Patents [OSTI]

    Gonze, Eugene V; Paratore, Jr., Michael J

    2012-10-23

    An exhaust system that processes exhaust generated by an engine is provided. The system generally includes a particulate filter (PF) that filters particulates from the exhaust wherein an upstream end of the PF receives exhaust from the engine. A grid of electrically resistive material is applied to an exterior upstream surface of the PF and selectively heats exhaust passing through the grid to initiate combustion of particulates within the PF. A catalyst coating applied to at least one of the PF and the grid. A control module estimates a temperature of the grid and controls the engine to produce a desired exhaust product to increase the temperature of the grid.

  7. The electric dipole moment of cobalt monoxide, CoO

    SciTech Connect (OSTI)

    Zhuang, Xiujuan; Steimle, Timothy C.

    2014-03-28

    A number of low-rotational lines of the E{sup 4}?{sub 7/2}???X{sup 4}?{sub 7/2} (1,0) band system of cobalt monoxide, CoO, were recorded field free and in the presence of a static electric field. The magnetic hyperfine parameter, h{sub 7/2}, and the electron quadrupole parameter, eQq{sub 0}, for the E{sup 4}?{sub 7/2}(? = 1) state were optimized from the analysis of the field-free spectrum. The permanent electric dipole moment, ?{sup -vector}{sub el}, for the X{sup 4}?{sub 7/2} (? = 0) and E{sup 4}?{sub 7/2} (? = 1) states were determined to be 4.18 0.05 D and 3.28 0.05 D, respectively, from the analysis of the observed Stark spectra of F? = 7???F? = 6 branch feature in the Q(7/2) line and the F? = 8???F? = 7 branch feature in the R(7/2) line. The measured dipole moments of CoO are compared to those from theoretical predictions and the trend across the 3d-metal monoxide series discussed.

  8. Particulate Produced from Advanced Combustion Operation in a...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Carbon Monoxide Emissions Hydrogen Assisted Diesel Combustion in a Common Rail Turbodiesel Engine Effects of Ignition Quality and Fuel Composition on Critical Equivalence Ratio

  9. Method of removing nitrogen monoxide from a nitrogen monoxide-containing gas using a water-soluble iron ion-dithiocarbamate, xanthate or thioxanthate

    DOE Patents [OSTI]

    Liu, D. Kwok-Keung; Chang, Shih-Ger

    1987-08-25

    The present invention relates to a method of removing of nitrogen monoxide from a nitrogen monoxide-containing gas which method comprises contacting a nitrogen oxide-containing gas with an aqueous solution of water soluble organic compound-iron ion chelate complex. The NO absorption efficiency of ferrous urea-dithiocarbamate and ferrous diethanolamine-xanthate as a function of time, oxygen content and solution ph is presented. 3 figs., 1 tab.

  10. The use of a receptor model for fine particulate in Mexico City

    SciTech Connect (OSTI)

    Vega, E.; Garcia, I.; Ruiz, M.E.

    1997-12-31

    Mexico City Metropolitan Area (MCMA) faces severe pollution problems typical of large urban areas all over the world. The city is in an elevated basin (2,240 m) at a subtropical latitude (19.5N), with a high mountain chain at the West and South. This basin setting inhibits dispersion of pollution and contributes to the frequent wintertime thermal inversions which further trap pollutants near the surface. The study of atmospheric pollution and its control have been carried out using physico-chemical dispersion models, and the type known as receptor models often finds favor. The main objective of this paper is to present the results of a chemical mass balance receptor model applied to two different data sets of particulate matter. The twelve-hour samples were collected during day and night periods in the winter of 1989, previous to the introduction of catalytic converters in automobiles, and the other after 1991, since the catalytic converters are compulsory in all the new model vehicles. Samples of particulate matter were collected using a denuder and a Hi-Vol systems for the fine fraction (aerosols with diameter less than 2.5 {micro}m) and total suspended particles respectively. The results show that the major source contributions to the inhalable particulate matter for the first period are: automobiles (44%); secondary aerosols (19%); dust (10%).

  11. Dark Matter

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Dark Matter Scientists are using the underground of the Waste Isolation Pilot Plant to try to solve the universe's major missing mass problem. He is enjoying his search They are searching for the presence of particles that may have mass but hardly interact with other matter. Based on observations of the relationships between mass and gravity and the speed of the stars and other cosmological systems, scientists believe that more than 90 percent of the universe's mass is "missing." A

  12. Neutron Imaging of Diesel Particulate Filters | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Diesel Particulate Filters Neutron Imaging of Diesel Particulate Filters Neutron computed tomography shows soot and ash loading in a cordierite diesel particulate filter PDF icon deer09_bilheux.pdf More Documents & Publications Neutron Imaging of Advanced Engine Technologies Neutron Imaging of Advanced Engine Technologies Development of an Accelerated Ash-Loading Protocol for Diesel Particulate Filters

  13. Integrated exhaust and electrically heated particulate filter regeneration systems

    DOE Patents [OSTI]

    Gonze, Eugene V.; Paratore, Jr., Michael J.

    2013-01-08

    A system includes a particulate matter (PM) filter that includes multiple zones. An electrical heater includes heater segments that are associated with respective ones of the zones. The electrical heater is arranged upstream from and proximate with the PM filter. A post-fuel injection system injects fuel into at least one of a cylinder of an engine and an exhaust system. A control module is configured to operate in a first mode that includes activating the electrical heater to heat exhaust of the engine. The control module is also configured to operate in a second mode that includes activating the post-injection system to heat the exhaust. The control module selectively operates in at least one of the first mode and the second mode.

  14. Dry scrubbing oxides and particulate contaminants from hot gases

    SciTech Connect (OSTI)

    Quee, J. A.; Haak, M. P.

    1985-03-12

    Sulfur dioxides are dry scrubbed from a flue gas by introducing minute droplets containing a liquid, such as water, and an alkali or alkaline reactant, such as lime, into the spray zone in the primary spray drying chamber of a spray dryer and concurrently contacting these droplets with the hot flue gas. The droplets are partially dried to a tacky condition before reaching a foraminous collecting member extending through the primary spray drying chamber and collect on the collecting member as a moist, porous mat. As the flue gas continues to flow through the mat, the mat serves as a filter for removing fly ash and other particulate matter and remaining sulfur oxides react with unreacted particles of the reactant and reactive ingredients of the fly ash particles in the mat.

  15. Requirements from Particulate Filter Technology for Commercial...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hot Gas Filtration of Fine and Ultra fine Particles with Liquid Phase Sintered SiC Ceramic DPF Evaluation of Passive and Active Soot Filters for Removal of Particulate Emissions ...

  16. Particle Number & Particulate Mass Emissions Measurements on...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    on a 'Euro VI' Heavy-duty Engine using the PMP Methodologies Particle Number & Particulate Mass Emissions Measurements on a 'Euro VI' Heavy-duty Engine using the PMP ...

  17. Requirements from Particulate Filter Technology for Commercial Vehicles:

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Sintered Metal Particulate Filter Opens a New Dimension of Performance | Department of Energy from Particulate Filter Technology for Commercial Vehicles: Sintered Metal Particulate Filter Opens a New Dimension of Performance Requirements from Particulate Filter Technology for Commercial Vehicles: Sintered Metal Particulate Filter Opens a New Dimension of Performance 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters PDF icon 2005_deer_biddinger.pdf More

  18. Expanded Capacity Microwave-Cleaned Diesel Particulate Filter | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy Expanded Capacity Microwave-Cleaned Diesel Particulate Filter Expanded Capacity Microwave-Cleaned Diesel Particulate Filter 2002 DEER Conference Presentation: Industrial Ceramic Solutions, LLC PDF icon 2002_deer_nixdorf.pdf More Documents & Publications Ultra-Lite Diesel Particulate Filter Cartridge for Reduced Regeneration Time and Fuel Consumption Pleated Ceramic Fiber Diesel Particulate Filter Versatile Diesel Particulate Filter Cartridge Any Size, Any Shape

  19. The effect of carbon monoxide on planetary haze formation

    SciTech Connect (OSTI)

    Hörst, S. M.; Tolbert, M. A

    2014-01-20

    Organic haze plays a key role in many planetary processes ranging from influencing the radiation budget of an atmosphere to serving as a source of prebiotic molecules on the surface. Numerous experiments have investigated the aerosols produced by exposing mixtures of N{sub 2}/CH{sub 4} to a variety of energy sources. However, many N{sub 2}/CH{sub 4} atmospheres in both our solar system and extrasolar planetary systems also contain carbon monoxide (CO). We have conducted a series of atmosphere simulation experiments to investigate the effect of CO on the formation and particle size of planetary haze analogues for a range of CO mixing ratios using two different energy sources, spark discharge and UV. We find that CO strongly affects both number density and particle size of the aerosols produced in our experiments and indicates that CO may play an important, previously unexplored, role in aerosol chemistry in planetary atmospheres.

  20. Methanation of gas streams containing carbon monoxide and hydrogen

    DOE Patents [OSTI]

    Frost, Albert C. (Congers, NY)

    1983-01-01

    Carbon monoxide-containing gas streams having a relatively high concentration of hydrogen are pretreated so as to remove the hydrogen in a recoverable form for use in the second step of a cyclic, essentially two-step process for the production of methane. The thus-treated streams are then passed over a catalyst to deposit a surface layer of active surface carbon thereon essentially without the formation of inactive coke. This active carbon is reacted with said hydrogen removed from the feed gas stream to form methane. The utilization of the CO in the feed gas stream is appreciably increased, enhancing the overall process for the production of relatively pure, low-cost methane from CO-containing waste gas streams.

  1. Method for dispersing catalyst onto particulate material

    DOE Patents [OSTI]

    Utz, Bruce R. (Pittsburgh, PA); Cugini, Anthony V. (Pittsburgh, PA)

    1992-01-01

    A method for dispersing finely divided catalyst precursors onto the surface of coal or other particulate material includes the steps of forming a wet paste mixture of the particulate material and a liquid solution containing a dissolved transition metal salt, for instance a solution of ferric nitrate. The wet paste mixture is in a state of incipient wetness with all of this solution adsorbed onto the surfaces of the particulate material without the presence of free moisture. On adding a precipitating agent such as ammonia, a catalyst precursor such as hydrated iron oxide is deposited on the surfaces of the coal. The catalyst is activated by converting it to the sulfide form for the hydrogenation or direct liquefaction of the coal.

  2. Method of removing nitrogen monoxide from a nitrogen monoxide-containing gas using a water-soluble iron ion-dithiocarbamate, xanthate or thioxanthate

    DOE Patents [OSTI]

    Liu, David K. (San Pablo, CA); Chang, Shih-Ger (El Cerrito, CA)

    1989-01-01

    A method of removing nitrogen monoxide from a nitrogen monoxide-containing gas, which method comprises: (a) contacting a nitrogen oxide-containing gas with an aqueous solution of water soluble organic compound-iron ion chelate of the formula: ##STR1## wherein the water-soluble organic compound is selected from compounds of the formula: ##STR2## wherein: R is selected from hydrogen or an organic moiety having at least one polar functional group; Z is selected from oxygen, sulfur, or --N--A wherein N is nitrogen and A is hydrogen or lower alkyl having from one to four carbon atoms; and M is selected from hydrogen, sodium or potassium; and n is 1 or 2, in a contacting zone for a time and at a temperature effective to reduce the nitrogen monoxide. These mixtures are useful to provide an unexpensive method of removing NO from gases, thus reducing atmospheric pollution from flue gases.

  3. Production of carbon monoxide-free hydrogen and helium from a high-purity source

    DOE Patents [OSTI]

    Golden, Timothy Christopher (Allentown, PA); Farris, Thomas Stephen (Bethlehem, PA)

    2008-11-18

    The invention provides vacuum swing adsorption processes that produce an essentially carbon monoxide-free hydrogen or helium gas stream from, respectively, a high-purity (e.g., pipeline grade) hydrogen or helium gas stream using one or two adsorber beds. By using physical adsorbents with high heats of nitrogen adsorption, intermediate heats of carbon monoxide adsorption, and low heats of hydrogen and helium adsorption, and by using vacuum purging and high feed stream pressures (e.g., pressures of as high as around 1,000 bar), pipeline grade hydrogen or helium can purified to produce essentially carbon monoxide -free hydrogen and helium, or carbon monoxide, nitrogen, and methane-free hydrogen and helium.

  4. Method of dispersing particulate aerosol tracer

    DOE Patents [OSTI]

    O'Holleran, Thomas P. (Belleville, MI)

    1988-01-01

    A particulate aerosol tracer which comprises a particulate carrier of sheet silicate composition having a particle size up to one micron, and a cationic dopant chemically absorbed in solid solution in the carrier. The carrier is preferably selected from the group consisting of natural mineral clays such as bentonite, and the dopant is selected from the group consisting of rare earth elements and transition elements. The tracers are dispersed by forming an aqueous salt solution with the dopant present as cations, dispersing the carriers in the solution, and then atomizing the solution under heat sufficient to superheat the solution droplets at a level sufficient to prevent reagglomeration of the carrier particles.

  5. Partial-Flow Diesel Particulate Filter of Sintered Metal Fiber...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Partial-Flow Diesel Particulate Filter of Sintered Metal Fiber Fleece Partial-Flow Diesel Particulate Filter of Sintered Metal Fiber Fleece Poster presented at the 16th Directions ...

  6. Monoxides of small terbium clusters: A density functional theory investigation

    SciTech Connect (OSTI)

    Zhang, G. L.; Yuan, H. K. Chen, H.; Kuang, A. L.; Li, Y.; Wang, J. Z.; Chen, J.

    2014-12-28

    To investigate the effect of oxygen atom on the geometrical structures, electronic, and magnetic properties of small terbium clusters, we carried out the first-principles calculations on Tb{sub n}O (n = 1-14) clusters. The capping of an oxygen atom on one trigonal-facet of Tb{sub n} structures is always favored energetically, which can significantly improve the structural stability. The far-infrared vibrational spectroscopies are found to be different from those of corresponding bare clusters, providing a distinct signal to detect the characteristic structures of Tb{sub n}O clusters. The primary effect of oxygen atom on magnetic properties is to change the magnetic orderings among Tb atoms and to reduce small of local magnetic moments of the O-coordinated Tb atoms, both of which serve as the key reasons for the experimental magnetic evolution of an oscillating behavior. These calculations are consistent with, and help to account for, the experimentally observed magnetic properties of monoxide Tb{sub n}O clusters [C. N. Van Dijk et al., J. Appl. Phys. 107, 09B526 (2010)].

  7. Expanded Capacity Microwave-Cleaned Diesel Particulate Filter...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    DEER Conference Presentation: Industrial Ceramic Solutions, LLC PDF icon ... Time and Fuel Consumption Pleated Ceramic Fiber Diesel Particulate Filter Versatile ...

  8. Advanced Particulate Filter Technologies for Direct Injection Gasoline

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Engine Applications | Department of Energy Particulate Filter Technologies for Direct Injection Gasoline Engine Applications Advanced Particulate Filter Technologies for Direct Injection Gasoline Engine Applications Specific designs and material properties have to be developed for gasoline particulate filters based on the different engine and exhaust gas characteristic of gasoline engines compared to diesel engines, e.g., generally lower levels of engine-out particulate emissions or higher

  9. Development of Advanced Particulate Filters | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Particulate Filters Development of Advanced Particulate Filters 2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon ace024_lee_2012_o.pdf More Documents & Publications Particulate Emissions Control by Advanced Filtration Systems or GDI Engines Diesel Particulate Filter: A Success for Faurecia Exhaust Systems Uncovering Fundamental Ash-Formation Mechanisms and Potential Means to Control the Impact on DPF

  10. Update on 2007 Diesel Particulate Measurement Research | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy 2007 Diesel Particulate Measurement Research Update on 2007 Diesel Particulate Measurement Research 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters PDF icon 2005_deer_shimpi.pdf More Documents & Publications Real-Time Measurement of Diesel Trap Efficiency Mass Correlation of Engine Emissions with Spectral Instruments Real-Time Particulate Mass Measurements Pre and Post Diesel Particulate Filters for LIght-Duty Diesel Vehicles

  11. Versatile Diesel Particulate Filter Cartridge Any Size, Any Shape |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Versatile Diesel Particulate Filter Cartridge Any Size, Any Shape Versatile Diesel Particulate Filter Cartridge Any Size, Any Shape Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and Fuel Partnership and 21st Century Truck Programs. PDF icon 2006_deer_nixdorf.pdf More Documents & Publications Pleated Ceramic Fiber Diesel Particulate Filter Ultra-Lite Diesel Particulate Filter Cartridge for Reduced

  12. Particulate Generation in a Tritium System | Department of Energy

    Office of Environmental Management (EM)

    Particulate Generation in a Tritium System Particulate Generation in a Tritium System Presentation from the 33rd Tritium Focus Group Meeting held in Aiken, South Carolina on April 22-24, 2014. PDF icon Particulate Generation in a Tritium System More Documents & Publications Fuel Injector Holes Fuel Injector Holes Fuel injector Holes (Fabrication of Micro-Orifices for Fuel Injectors)

  13. Electrically heated particulate filter preparation methods and systems

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI

    2012-01-31

    A control system that controls regeneration of a particulate filter is provided. The system generally includes a fuel control module that controls injection of fuel into exhaust that passes through the particulate filter. A regeneration module controls current to the particulate filter to initiate regeneration after the fuel has been injected into the exhaust.

  14. Development of Advanced Diesel Particulate Filtration (DPF) Systems

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    (ANL/Corning/Caterpillar CRADA) | Department of Energy (ANL/Corning/Caterpillar CRADA) Development of Advanced Diesel Particulate Filtration (DPF) Systems (ANL/Corning/Caterpillar CRADA) PDF icon ace_22_lee.pdf More Documents & Publications Development of Advanced Diesel Particulate Filtration (DPF) Systems Development of Advanced Diesel Particulate Filtration (DPF) Systems

  15. Development of Advanced Diesel Particulate Filtration (DPF) Systems |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy 1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon ace024_lee_2011_o.pdf More Documents & Publications Development of Advanced Particulate Filters Development of Advanced Diesel Particulate Filtration (DPF) Systems Development of Advanced Diesel Particulate Filtration (DPF) Systems (ANL/Corning/Caterpillar CRADA)

  16. Electrically-Assisted Diesel Particulate Filter Regeneration | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy 2 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon pm041_lance_2012_o.pdf More Documents & Publications Substrate Studies of an Electrically-Assisted Diesel Particulate Filter Electrically-Assisted Diesel Particulate Filter Regeneration Durability of Diesel Engine Particulate Filters (Agreement ID:10461)

  17. Carbon monoxide inhalation increases microparticles causing vascular and CNS dysfunction

    SciTech Connect (OSTI)

    Xu, Jiajun; Yang, Ming; Kosterin, Paul; Salzberg, Brian M.; Milovanova, Tatyana N.; Bhopale, Veena M.; Thom, Stephen R.

    2013-12-01

    We hypothesized that circulating microparticles (MPs) play a role in pro-inflammatory effects associated with carbon monoxide (CO) inhalation. Mice exposed for 1 h to 100 ppm CO or more exhibit increases in circulating MPs derived from a variety of vascular cells as well as neutrophil activation. Tissue injury was quantified as 2000 kDa dextran leakage from vessels and as neutrophil sequestration in the brain and skeletal muscle; and central nervous system nerve dysfunction was documented as broadening of the neurohypophysial action potential (AP). Indices of injury occurred following exposures to 1000 ppm for 1 h or to 1000 ppm for 40 min followed by 3000 ppm for 20 min. MPs were implicated in causing injuries because infusing the surfactant MP lytic agent, polyethylene glycol telomere B (PEGtB) abrogated elevations in MPs, vascular leak, neutrophil sequestration and AP prolongation. These manifestations of tissue injury also did not occur in mice lacking myeloperoxidase. Vascular leakage and AP prolongation were produced in nave mice infused with MPs that had been obtained from CO poisoned mice, but this did not occur with MPs obtained from control mice. We conclude that CO poisoning triggers elevations of MPs that activate neutrophils which subsequently cause tissue injuries. - Highlights: Circulating microparticles (MPs) increase in mice exposed to 100 ppm CO or more. MPs are lysed by infusing the surfactant polyethylene glycol telomere B. CO-induced MPs cause neutrophil activation, vascular leak and CNS dysfunction. Similar tissue injuries do not arise with MPs obtained from air-exposed, control mice.

  18. Acute changes in pulse pressure in relation to constituents of particulate air pollution in elderly persons

    SciTech Connect (OSTI)

    Jacobs, Lotte; Buczynska, Anna; Walgraeve, Christophe; Delcloo, Andy; Potgieter-Vermaak, Sanja; Molecular Science Institute, School of Chemistry, University of Witwatersrand, Johannesburg; Division of Chemistry and Environmental Science, Manchester Metropolitan University, Manchester ; Van Grieken, Rene; Demeestere, Kristof; Dewulf, Jo; Van Langenhove, Herman; De Backer, Hugo; Nemery, Benoit; Nawrot, Tim S.; Centre for Environmental Sciences, Hasselt University, Diepenbeek

    2012-08-15

    An increased pulse pressure (difference between systolic and diastolic blood pressure) suggests aortic stiffening. The objective of this study was to examine the acute effects of both particulate matter (PM) mass and composition on blood pressure, among elderly persons. We carried out a panel study in persons living in elderly homes in Antwerp, Belgium. We recruited 88 non-smoking persons, 70% women with a mean age of 83 years (standard deviation: 5.2). Blood pressure was measured and a blood sample was collected on two time points, which were chosen so that there was an exposure contrast in ambient PM exposure. The elemental content of the collected indoor and outdoor PM{sub 2.5} (particulate matter with an aerodynamic diameter <2.5 {mu}m) mass concentration was measured. Oxygenated polycyclic aromatic hydrocarbons (oxy-PAHs) on outdoor PM{sub 10} (particulate matter with an aerodynamic diameter <10 {mu}m) were measured. Each interquartile range increase of 20.8 {mu}g/m Superscript-Three in 24-h mean outdoor PM{sub 2.5} was associated with an increase in pulse pressure of 4.0 mmHg (95% confidence interval: 1.8-6.2), in persons taking antihypertensive medication (n=57), but not in persons not using antihypertensive medication (n=31) (p for interaction: 0.02). Vanadium, iron and nickel contents of PM{sub 2.5} were significantly associated with systolic blood pressure and pulse pressure, among persons on antihypertensive medication. Similar results were found for indoor concentrations. Of the oxy-PAHs, chrysene-5,6-dione and benzo[a]pyrene-3,6-dione were significantly associated with increases in systolic blood pressure and pulse pressure. In elderly, pulse pressure was positively associated with acute increases in outdoor and indoor air pollution, among persons taking antihypertensive medication. These results might form a mechanistic pathway linking air pollution as a trigger of cardiovascular events.

  19. Apparatus for measuring surface particulate contamination

    DOE Patents [OSTI]

    Woodmansee, Donald E. (Simpsonville, SC)

    2002-01-01

    An apparatus for measuring surface particulate contamination includes a tool for collecting a contamination sample from a target surface, a mask having an opening of known area formed therein for defining the target surface, and a flexible connector connecting the tool to the mask. The tool includes a body portion having a large diameter section defining a surface and a small diameter section extending from the large diameter section. A particulate collector is removably mounted on the surface of the large diameter section for collecting the contaminants. The tool further includes a spindle extending from the small diameter section and a spool slidingly mounted on the spindle. A spring is disposed between the small diameter section and the spool for biasing the spool away from the small diameter section. An indicator is provided on the spindle so as to be revealed when the spool is pressed downward to compress the spring.

  20. A population-based exposure assessment methodology for carbon monoxide: Development of a carbon monoxide passive sampler and occupational dosimeter

    SciTech Connect (OSTI)

    Apte, M.G.

    1997-09-01

    Two devices, an occupational carbon monoxide (CO) dosimeter (LOCD), and an indoor air quality (IAQ) passive sampler were developed for use in population-based CO exposure assessment studies. CO exposure is a serious public health problem in the U.S., causing both morbidity and mortality (lifetime mortality risk approximately 10{sup -4}). Sparse data from population-based CO exposure assessments indicate that approximately 10% of the U.S. population is exposed to CO above the national ambient air quality standard. No CO exposure measurement technology is presently available for affordable population-based CO exposure assessment studies. The LOCD and IAQ Passive Sampler were tested in the laboratory and field. The palladium-molybdenum based CO sensor was designed into a compact diffusion tube sampler that can be worn. Time-weighted-average (TWA) CO exposure of the device is quantified by a simple spectrophotometric measurement. The LOCD and IAQ Passive Sampler were tested over an exposure range of 40 to 700 ppm-hours and 200 to 4200 ppm-hours, respectively. Both devices were capable of measuring precisely (relative standard deviation <20%), with low bias (<10%). The LOCD was screened for interferences by temperature, humidity, and organic and inorganic gases. Temperature effects were small in the range of 10{degrees}C to 30{degrees}C. Humidity effects were low between 20% and 90% RH. Ethylene (200 ppm) caused a positive interference and nitric oxide (50 ppm) caused a negative response without the presence of CO but not with CO.

  1. Generator powered electrically heated diesel particulate filter

    DOE Patents [OSTI]

    Gonze, Eugene V; Paratore, Jr., Michael J

    2014-03-18

    A control circuit for a vehicle powertrain includes a switch that selectivity interrupts current flow between a first terminal and a second terminal. A first power source provides power to the first terminal and a second power source provides power to the second terminal and to a heater of a heated diesel particulate filter (DPF). The switch is opened during a DPF regeneration cycle to prevent the first power source from being loaded by the heater while the heater is energized.

  2. DEMONSTRATION OF POTENTIAL FOR SELECTIVE CATALYTIC REDUCTION AND DIESEL PARTICULATE FILTERS

    SciTech Connect (OSTI)

    McGILL,R; KHAIR, M; SHARP, C

    2003-08-24

    This project addresses the potential for Selective Catalytic Reduction (SCR) devices (using urea as reductant) together with Diesel Particulate Filters (DPF) and low-pressure loop exhaust gas recirculation (EGR) to achieve future stringent emissions standards for heavy-duty engines powering Class 8 vehicles. Two emission control systems consisting of the three technologies (EGR, SCR, and DPF) were calibrated on a Caterpillar C-12 heavy-duty diesel engine. Results of these calibrations showed good promise in meeting the 2010 heavy-duty emission standards as set forth by the Environmental Protection Agency (EPA). These two emission control systems were developed to evaluate a series of fuels that have similar formulations except for their sulfur content. Additionally, one fuel, code-named BP15, was also evaluated. This fuel was prepared by processing straight-run distillate stocks through a commercial, single stage hydrotreater employing high activity catalyst at maximum severity. An additional goal of this program is to provide data for an on-going EPA technology review that evaluates progress toward meeting 2007/2010 emission standards. These emissions levels were to be achieved not only on the transient test cycles but in other modes of operation such as the steady-state Euro-III style emission test known as the OICA (Organisation Internationale des Compagnies d'Automobiles) or the ESC (European Stationary Cycle). Additionally, hydrocarbon and carbon monoxide emissions standards are to be met.

  3. Substantially isotactic, linear, alternating copolymers of carbon monoxide and an olefin

    DOE Patents [OSTI]

    Sen, A.; Jiang, Z.

    1996-05-28

    The compound, [Pd(Me-DUPHOS)(MeCN){sub 2}](BF{sub 4}){sub 2}, [Me-DUPHOS: 1,2-bis(2,5-dimethylphospholano)benzene] is an effective catalyst for the highly enantioselective, alternating copolymerization of olefins, such as aliphatic {alpha}-olefins, with carbon monoxide to form optically active, isotactic polymers which can serve as excellent starting materials for the synthesis of other classes of chiral polymers. For example, the complete reduction of a propylene-carbon monoxide copolymer resulted in the formation of a novel, optically active poly(1,4-alcohol). Also, the previously described catalyst is a catalyst for the novel alternating isomerization cooligomerization of 2-butene with carbon monoxide to form optically active, isotactic poly(1,5-ketone).

  4. Substantially isotactic, linear, alternating copolymers of carbon monoxide and an olefin

    DOE Patents [OSTI]

    Sen, Ayusman; Jiang, Zhaozhong

    1996-01-01

    The compound, [Pd(Me-DUPHOS)(MeCN).sub.2 ](BF.sub.4).sub.2, [Me-DUPHOS: 1,2-bis(2,5-dimethylphospholano)benzene] is an effective catalyst for the highly enantioselective, alternating copolymerization of olefins, such as aliphatic .alpha.-olefins, with carbon monoxide to form optically active, isotactic polymers which can serve as excellent starting materials for the synthesis of other classes of chiral polymers. For example, the complete reduction of a propylene-carbon monoxide copolymer resulted in the formation of a novel, optically active poly(1,4-alcohol). Also, the previously described catalyst is a catalyst for the novel alternating isomerization cooligomerization of 2-butene with carbon monoxide to form optically active, isotactic poly(1,5-ketone)

  5. Cyclic process for producing methane from carbon monoxide with heat removal

    DOE Patents [OSTI]

    Frost, Albert C. (Congers, NY); Yang, Chang-lee (Spring Valley, NY)

    1982-01-01

    Carbon monoxide-containing gas streams are converted to methane by a cyclic, essentially two-step process in which said carbon monoxide is disproportionated to form carbon dioxide and active surface carbon deposited on the surface of a catalyst, and said carbon is reacted with steam to form product methane and by-product carbon dioxide. The exothermic heat of reaction generated in each step is effectively removed during each complete cycle so as to avoid a build up of heat from cycle-to-cycle, with particularly advantageous techniques being employed for fixed bed, tubular and fluidized bed reactor operations.

  6. Estimates of Particulate Mass in Multi Canister Overpacks (MCO)

    SciTech Connect (OSTI)

    SLOUGHTER, J.P.

    2000-02-16

    High, best estimate, and low values are developed for particulate inventories within MCO baskets that have been loaded with freshly cleaned fuel assemblies and scrap. These per-basket estimates are then applied to all anticipated MCO payload configurations to identify which configurations are bounding for each type of particulate. Finally the resulting bounding and nominal values for residual particulates are combined with corresponding values [from other documents] for particulates that may be generated by corrosion of exposed uranium after the fuel has been cleaned. The resulting rounded nominal estimate for a typical MCO after 40 years of storage is 8 kg. The estimate for a bounding total particulate case MCO is that it may contain up to 64 kg of particulate after 40 years of storage.

  7. Estimates of particulate mass in multi-canister overpacks

    SciTech Connect (OSTI)

    SLOUGHTER, J.P.

    1999-02-25

    High, best estimate, and low values are developed for particulate inventories within MCO baskets that have been loaded with freshly cleaned fuel assemblies and scrap. These per-basket estimates are then applied to all anticipated MCO payload configurations to identify which configurations are bounding for each type of particulate. Finally the resulting bounding and nominal values for residual particulates are combined with corresponding values [from other documents] for particulate that may be generated by corrosion of exposed uranium after the fuel has been cleaned. The resulting rounded nominal estimate for a typical MCO after 40 years of storage is 8 kg. The estimate for a bounding total particulate case MCO is that it may contain up to 64 kg of particulate after 40 years of storage.

  8. Mesoscale Simulations of Particulate Flows with Parallel Distributed

    Office of Scientific and Technical Information (OSTI)

    Lagrange Multiplier Technique (Conference) | SciTech Connect Mesoscale Simulations of Particulate Flows with Parallel Distributed Lagrange Multiplier Technique Citation Details In-Document Search Title: Mesoscale Simulations of Particulate Flows with Parallel Distributed Lagrange Multiplier Technique Fluid particulate flows are common phenomena in nature and industry. Modeling of such flows at micro and macro levels as well establishing relationships between these approaches are needed to

  9. Local Soot Loading Distribution in Cordierite Diesel Particulate Filters by

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Dynamic Neutron Radiography | Department of Energy Local Soot Loading Distribution in Cordierite Diesel Particulate Filters by Dynamic Neutron Radiography Local Soot Loading Distribution in Cordierite Diesel Particulate Filters by Dynamic Neutron Radiography Quantitative analysis of the soot loading and soot distribution for Cordierite type DPFs are studied under controlled conditions. PDF icon deer10_harvel.pdf More Documents & Publications Neutron Imaging of Diesel Particulate Filters

  10. Final Report: Particulate Emissions Testing, Unit 1, Potomac River

    Energy Savers [EERE]

    Generating Station, Alexandria, Virginia | Department of Energy Final Report: Particulate Emissions Testing, Unit 1, Potomac River Generating Station, Alexandria, Virginia Final Report: Particulate Emissions Testing, Unit 1, Potomac River Generating Station, Alexandria, Virginia Docket No. EO-05-01: TRC Environmental Corporation (TRC) of Lowell, Massachusetts was retained by Mirant Potomac River, LLC (Mirant) to provide sampling and analytical support in completing a Particulate Emission

  11. High Efficiency Particulate Air (HEPA) Filter Test Facility (FTF) |

    Energy Savers [EERE]

    Department of Energy High Efficiency Particulate Air (HEPA) Filter Test Facility (FTF) High Efficiency Particulate Air (HEPA) Filter Test Facility (FTF) DOE-STD-3020-2015 Specification for HEPA Filters Used by DOE Contractors The purpose of this standard is to establish specifications and quality assurance (QA) requirements for the procurement, packaging, shipping and storage of high efficiency particulate air (HEPA) filters. DOE-STD-3025-2007 Quality Assurance Inspection and Testing of HEPA

  12. Non-Destructive Neutron Imaging to Analyze Particulate Filters | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy Neutron Imaging to Analyze Particulate Filters Non-Destructive Neutron Imaging to Analyze Particulate Filters Non-destructive, non-invasive imaging is being employed in the laboratory to understand how soot, ash, and catalytic washcoat are deposited within a diesel particulate filter. PDF icon p-27_toops.pdf More Documents & Publications Neutron Imaging of Advanced Engine Technologies Neutron Imaging of Advanced Engine Technologies Vehicle Technologies Office Merit Review 2014:

  13. Reliability and Design Strength Limit Calculations on Diesel Particulate

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Filters | Department of Energy and Design Strength Limit Calculations on Diesel Particulate Filters Reliability and Design Strength Limit Calculations on Diesel Particulate Filters 2004 Diesel Engine Emissions Reduction (DEER) Confererence Presentation: Corning PDF icon 2004_deer_webb.pdf More Documents & Publications Predicting Thermal Stress in Diesel Particulate Filters Environmental Effects on Power Electronic Devices Effect of Machining Procedures on the Strength of Ceramics for

  14. Requirements-Driven Diesel Catalyzed Particulate Trap Design and

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Optimization | Department of Energy Requirements-Driven Diesel Catalyzed Particulate Trap Design and Optimization Requirements-Driven Diesel Catalyzed Particulate Trap Design and Optimization 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters PDF icon 2005_deer_harris.pdf More Documents & Publications Diesel Emission Control Technology Review Investigation of Aging Mechanisms in Lean NOx Traps Diesel Particulate Filters: Market Introducution

  15. Characterization of Particulate Emissions from GDI Engine Combustion with

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Alcohol-blended Fuels | Department of Energy Particulate Emissions from GDI Engine Combustion with Alcohol-blended Fuels Characterization of Particulate Emissions from GDI Engine Combustion with Alcohol-blended Fuels Analysis showed that gasoline direct injection engine particulates from alcohol-blended fuels are significantly different in morphology and nanostructures PDF icon p-19_seong.pdf More Documents & Publications Vehicle Technologies Office Merit Review 2014: Fuel and Lubricant

  16. Detailed Assessment of Particulate Characteristics from Low-Temperature

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Combustion Engines | Department of Energy Assessment of Particulate Characteristics from Low-Temperature Combustion Engines Detailed Assessment of Particulate Characteristics from Low-Temperature Combustion Engines 2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon ace083_lee_2012_p.pdf More Documents & Publications Characterization of Pre-Commercial Gasoline Engine Particulates Through Advanced Aerosol

  17. Development and Applications of Catalyzed Diesel Particulate Filter |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Applications of Catalyzed Diesel Particulate Filter Development and Applications of Catalyzed Diesel Particulate Filter 2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation: Sud Chemie Prototech Inc. PDF icon 2004_deer_huang.pdf More Documents & Publications CARB Verification of Catalyzed Diesel Particulate Filters for Emergency Generator Sets A Revealing Look Inside Passive and Active DPF Regeneration: In-Situ Optical Analysis of Ash Formation and

  18. Development of Acicular Mullite Materials for Diesel Particulate Filters

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Application | Department of Energy Acicular Mullite Materials for Diesel Particulate Filters Application Development of Acicular Mullite Materials for Diesel Particulate Filters Application 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters PDF icon 2005_deer_pyzik.pdf More Documents & Publications Tailored Acicular Mullite Substrates for Multifunctional Diesel Particulate Filters Future Trends for DPFƒSCR On-Filter (SCRF) fundamental Modeling and

  19. Development of Advanced Diesel Particulate Filtration (DPF) Systems |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy 0 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C. PDF icon ace024_lee_2010_o.pdf More Documents & Publications Development of Advanced Diesel Particulate Filtration (DPF) Systems Development of Advanced Diesel Particulate Filtration (DPF) Systems (ANL/Corning/Caterpillar CRADA) Development of Advanced Particulate Filters

  20. Development of an Active Regeneration Diesel Particulate Filter System |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy an Active Regeneration Diesel Particulate Filter System Development of an Active Regeneration Diesel Particulate Filter System PDF icon 2004_deer_anderson.pdf More Documents & Publications A New Active DPF System for "Stop and Go" Duty-Cycle Vehicles Donaldson Active Regeneration PM System A New CFD Model for understanding and Managing Diesel Particulate Filter Regeneration

  1. Diesel Particulate Filter: A Success for Faurecia Exhaust Systems |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Filter: A Success for Faurecia Exhaust Systems Diesel Particulate Filter: A Success for Faurecia Exhaust Systems 2003 DEER Conference Presentation: Faurecia Exhaust Systems PDF icon 2003_deer_parmann.pdf More Documents & Publications Combination of Diesel fuel system architectures and Ceria-based fuel-borne catalysts for improvement and simplification of the Diesel Particulate Filter System in serial applications Improvement and Simplification of Diesel Particulate

  2. Durability of Diesel Particulate Filters - Bench Studies on Cordierite

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Filters | Department of Energy Particulate Filters - Bench Studies on Cordierite Filters Durability of Diesel Particulate Filters - Bench Studies on Cordierite Filters Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and Fuel Partnership and 21st Century Truck Programs. PDF icon 2006_deer_dacosta.pdf More Documents & Publications Requirements-Driven Diesel Catalyzed Particulate Trap Design and Optimization Development of

  3. Emissions and Durability of Underground Mining Diesel Particulate Filter

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Applications | Department of Energy Durability of Underground Mining Diesel Particulate Filter Applications Emissions and Durability of Underground Mining Diesel Particulate Filter Applications Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and Fuel Partnership and 21st Century Truck Programs. PDF icon 2006_deer_rubeli.pdf More Documents & Publications Testing an Active Diesel Particulate Filter on a 2-Cycle Marine

  4. Mesoscale Simulations of Particulate Flows with Parallel Distributed

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Lagrange Multiplier Technique (Conference) | SciTech Connect Mesoscale Simulations of Particulate Flows with Parallel Distributed Lagrange Multiplier Technique Citation Details In-Document Search Title: Mesoscale Simulations of Particulate Flows with Parallel Distributed Lagrange Multiplier Technique Fluid particulate flows are common phenomena in nature and industry. Modeling of such flows at micro and macro levels as well establishing relationships between these approaches are needed to

  5. Blowers for Air Assisted Diesel Particulate Filter Regeneration |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Blowers for Air Assisted Diesel Particulate Filter Regeneration Blowers for Air Assisted Diesel Particulate Filter Regeneration Prototypes of a new series of high-pressure, brushless DC motor-drive blowers have completed field testing, and DFM and manufacturing cost studies are well advanced. PDF icon p-14_milburn.pdf More Documents & Publications Development of a Non Air-assisted Thermal Regenerator Development of an Active Regeneration Diesel Particulate Filter

  6. CARB Verification of Catalyzed Diesel Particulate Filters for Emergency

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Generator Sets | Department of Energy CARB Verification of Catalyzed Diesel Particulate Filters for Emergency Generator Sets CARB Verification of Catalyzed Diesel Particulate Filters for Emergency Generator Sets 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters PDF icon 2005_deer_huang.pdf More Documents & Publications Development and Applications of Catalyzed Diesel Particulate Filter California ARB Verification Testing of the CBSTM Soot Filter for

  7. Substrate Studies of an Electrically-Assisted Diesel Particulate Filter |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Substrate Studies of an Electrically-Assisted Diesel Particulate Filter Substrate Studies of an Electrically-Assisted Diesel Particulate Filter Transient distributed DPF wall and gas temperature were simultaneously measured using the optical and thermocouple systems, on both electrically assisted and conventional fuel-only DPF regeneration cycles PDF icon deer12_parks.pdf More Documents & Publications Electrically-Assisted Diesel Particulate Filter Regeneration

  8. Diesel particulate filter regeneration via resistive surface heating

    DOE Patents [OSTI]

    Gonze, Eugene V; Ament, Frank

    2013-10-08

    An exhaust system that processes exhaust generated by an engine is provided. The system includes: a particulate filter (PF) that filters particulates from the exhaust wherein an upstream end of the PF receives exhaust from the engine; and a grid of electrically resistive material that is applied to an exterior upstream surface of the PF and that selectively heats exhaust passing through the grid to initiate combustion of particulates within the PF.

  9. Development of Advanced Diesel Particulate Filtration (DPF) Systems...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon ace024lee2011o.pdf More Documents & Publications Development of Advanced Particulate Filters...

  10. Development of an Active Regeneration Diesel Particulate Filter...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    DPF System for "Stop and Go" Duty-Cycle Vehicles Donaldson Active Regeneration PM System A New CFD Model for understanding and Managing Diesel Particulate Filter Regeneration...

  11. Effect of Biodiesel Blends on Diesel Particulate Filter Performance

    SciTech Connect (OSTI)

    Williams, A.; McCormick, R. L.; Hayes, R. R.; Ireland, J.; Fang, H. L.

    2006-11-01

    Presents results of tests of ultra-low sulfur diesel blended with soy-biodiesel at 5 percent using a Cummins ISB engine with a diesel particulate filter.

  12. Ultra-Lite Diesel Particulate Filter Cartridge for Reduced Regeneratio...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Self-cleaning ceramic filter cartridges offer the advantage of better fuel economy, faster ... More Documents & Publications Pleated Ceramic Fiber Diesel Particulate Filter Expanded ...

  13. Final Report: Particulate Emissions Testing, Unit 1, Potomac...

    Broader source: Energy.gov (indexed) [DOE]

    analytical support in completing a Particulate Emission Test of Unit 1 of the Potomac River generating facility. The Test Program at the Potomac facility involved the completion ...

  14. Non-Destructive Neutron Imaging to Analyze Particulate Filters...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    non-invasive imaging is being employed in the laboratory to understand how soot, ash, and catalytic washcoat are deposited within a diesel particulate filter. PDF icon...

  15. Detailed Assessment of Particulate Characteristics from Low-Temperatur...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Detailed Assessment of Particulate Characteristics from Low-Temperature Combustion Engines ... Program Annual Merit Review and Peer Evaluation Meeting PDF icon ...

  16. Development of Acicular Mullite Materials for Diesel Particulate...

    Broader source: Energy.gov (indexed) [DOE]

    Tailored Acicular Mullite Substrates for Multifunctional Diesel Particulate Filters Future Trends for DPFSCR On-Filter (SCRF) fundamental Modeling and Experimental Studies of ...

  17. Substrate Studies of an Electrically-Assisted Diesel Particulate...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of an Electrically-Assisted Diesel Particulate Filter Transient distributed DPF wall and gas temperature were simultaneously measured using the optical and thermocouple systems, on...

  18. Value Analysis of Alternative Diesel Particulate Filter (DPF...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Value Analysis of Alternative Diesel Particulate Filter (DPF) Substrates for Future Diesel ... Provide higher soot mass limits and durability than other materials at the same porosity. ...

  19. Diesel Particulate Oxidation Model: Combined Effects of Fixed...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Oxidation Model: Combined Effects of Fixed & Volatile Carbon Diesel Particulate Oxidation Model: Combined Effects of Fixed & Volatile Carbon Poster presented at the 16th Directions ...

  20. Mesoscale simulations of particulate flows with parallel distributed...

    Office of Scientific and Technical Information (OSTI)

    distributed Lagrange multiplier technique Citation Details In-Document Search Title: Mesoscale simulations of particulate flows with parallel distributed Lagrange multiplier ...

  1. Electrically heated particulate filter regeneration using hydrocarbon adsorbents

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI

    2011-02-01

    An exhaust system that processes exhaust generated by an engine is provided. The system generally includes a particulate filter (PF) that filters particulates from the exhaust wherein an upstream end of the PF receives exhaust from the engine. A grid of electrically resistive material selectively heats exhaust passing through the upstream end to initiate combustion of particulates within the PF. A hydrocarbon adsorbent coating applied to the PF releases hydrocarbons into the exhaust to increase a temperature of the combustion of the particulates within the PF.

  2. Neutron Imaging of Diesel Particulate Filters

    SciTech Connect (OSTI)

    Strzelec, Andrea; Bilheux, Hassina Z; FINNEY, Charles E A; Daw, C Stuart; Foster, Prof. Dave; Rutland, Prof. Christopher J.; Schillinger, Burkhard; Schulz, Michael

    2009-01-01

    This article presents nondestructive neutron computed tomography (nCT) measurements of Diesel Particulate Filters (DPFs) as a method to measure ash and soot loading in the filters. Uncatalyzed and unwashcoated 200cpsi cordierite DPFs exposed to 100% biodiesel (B100) exhaust and conventional ultra low sulfur 2007 certification diesel (ULSD) exhaust at one speed-load point (1500rpm, 2.6bar BMEP) are compared to a brand new (never exposed) filter. Precise structural information about the substrate as well as an attempt to quantify soot and ash loading in the channel of the DPF illustrates the potential strength of the neutron imaging technique.

  3. Method of forming particulate materials for thin-film solar cells

    DOE Patents [OSTI]

    Eberspacher, Chris; Pauls, Karen Lea

    2004-11-23

    A method for preparing particulate materials useful in fabricating thin-film solar cells is disclosed. Particulate materials is prepared by the method include for example materials comprising copper and indium and/or gallium in the form of single-phase, mixed-metal oxide particulates; multi-phase, mixed-metal particulates comprising a metal oxide; and multinary metal particulates.

  4. Process for producing methane from gas streams containing carbon monoxide and hydrogen

    DOE Patents [OSTI]

    Frost, Albert C. (Congers, NY)

    1980-01-01

    Carbon monoxide-containing gas streams are passed over a catalyst capable of catalyzing the disproportionation of carbon monoxide so as to deposit a surface layer of active surface carbon on the catalyst essentially without formation of inactive coke thereon. The surface layer is contacted with steam and is thus converted to methane and CO.sub.2, from which a relatively pure methane product may be obtained. While carbon monoxide-containing gas streams having hydrogen or water present therein can be used only the carbon monoxide available after reaction with said hydrogen or water is decomposed to form said active surface carbon. Although hydrogen or water will be converted, partially or completely, to methane that can be utilized in a combustion zone to generate heat for steam production or other energy recovery purposes, said hydrogen is selectively removed from a CO--H.sub.2 -containing feed stream by partial oxidation thereof prior to disproportionation of the CO content of said stream.

  5. New clean fuel from coal -- Direct dimethyl ether synthesis from hydrogen and carbon monoxide

    SciTech Connect (OSTI)

    Ogawa, T.; Ono, M.; Mizuguchi, M.; Tomura, K.; Shikada, T.; Ohono, Y.; Fujimoto, K.

    1997-12-31

    Dimethyl ether (DME), which has similar physical properties to propane and is easily liquefied at low pressure, has a significant possibility as a clean and non-toxic fuel from coal or coal bed methane. Equilibrium calculation also shows a big advantage of high carbon monoxide conversion of DME synthesis compared to methanol synthesis. By using a 50 kg/day DME bench scale test plant, direct synthesis of DME from hydrogen and carbon monoxide has been studied with newly developed catalysts which are very fine particles. This test plant features a high pressure three-phase slurry reactor and low temperature DME separator. DME is synthesized at temperatures around 533--553 K and at pressures around 3--5 MPa. According to the reaction stoichiometry, the same amount of hydrogen and carbon monoxide react to DME and carbon dioxide. Carbon conversion to DME is one third and the rest of carbon is converted to carbon dioxide. As a result of the experiments, make-up CO conversion is 35--50% on an once-through basis, which is extremely high compared to that of methanol synthesis from hydrogen and carbon monoxide. DME selectivity is around 60 c-mol %. Most of the by-product is CO{sub 2} with a small amount of methanol and water. No heavy by-products have been recognized. Effluent from the reactor is finally cooled to 233--253 K in a DME separator and liquid DME is recovered as a product.

  6. Process for off-gas particulate removal and apparatus therefor

    DOE Patents [OSTI]

    Carl, D.E.

    1997-10-21

    In the event of a breach in the off-gas line of a melter operation requiring closure of the line, a secondary vessel vent line is provided with a particulate collector utilizing atomization for removal of large particulates from the off-gas. The collector receives the gas containing particulates and directs a portion of the gas through outer and inner annular channels. The collector further receives a fluid, such as water, which is directed through the outer channel together with a second portion of the particulate-laden gas. The outer and inner channels have respective ring-like termination apertures concentrically disposed adjacent one another on the outer edge of the downstream side of the particulate collector. Each of the outer and inner channels curves outwardly away from the collector`s centerline in proceeding toward the downstream side of the collector. Gas flow in the outer channel maintains the fluid on the channel`s wall in the form of a ``wavy film,`` while the gas stream from the inner channel shears the fluid film as it exits the outer channel in reducing the fluid to small droplets. Droplets formed by the collector capture particulates in the gas stream by one of three mechanisms: impaction, interception or Brownian diffusion in removing the particulates. The particulate-laden droplets are removed from the fluid stream by a vessel vent condenser or mist eliminator. 4 figs.

  7. Electrically-Assisted Diesel Particulate Filter Regeneration | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy 1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon pm041_lance_2011_p.pdf More Documents & Publications Electrically-Assisted Diesel Particulate Filter Regeneration Substrate Studies of an Electrically-Assisted Diesel Particulate Filter Biofuels Impact on DPF Durability

  8. Process for off-gas particulate removal and apparatus therefor

    DOE Patents [OSTI]

    Carl, Daniel E. (Orchard Park, NY)

    1997-01-01

    In the event of a breach in the off-gas line of a melter operation requiring closure of the line, a secondary vessel vent line is provided with a particulate collector utilizing atomization for removal of large particulates from the off-gas. The collector receives the gas containing particulates and directs a portion of the gas through outer and inner annular channels. The collector further receives a fluid, such as water, which is directed through the outer channel together with a second portion of the particulate-laden gas. The outer and inner channels have respective ring-like termination apertures concentrically disposed adjacent one another on the outer edge of the downstream side of the particulate collector. Each of the outer and inner channels curves outwardly away from the collector's centerline in proceeding toward the downstream side of the collector. Gasflow in the outer channel maintains the fluid on the channel's wall in the form of a "wavy film," while the gas stream from the inner channel shears the fluid film as it exits the outer channel in reducing the fluid to small droplets. Droplets formed by the collector capture particulates in the gas stream by one of three mechanisms: impaction, interception or Brownian diffusion in removing the particulates. The particulate-laden droplets are removed from the fluid stream by a vessel vent condenser or mist eliminator.

  9. Process for producing dispersed particulate composite materials

    DOE Patents [OSTI]

    Henager, Jr., Charles H. (Richland, WA); Hirth, John P. (Viola, ID)

    1995-01-01

    This invention is directed to a process for forming noninterwoven dispersed particulate composite products. In one case a composite multi-layer film product comprises a substantially noninterwoven multi-layer film having a plurality of discrete layers. This noninterwoven film comprises at least one discrete layer of a first material and at least one discrete layer of a second material. In another case the first and second materials are blended together with each other. In either case, the first material comprises a metalloid and the second material a metal compound. At least one component of a first material in one discrete layer undergoes a solid state displacement reaction with at least one component of a second material thereby producing the requisite noninterwoven composite film product. Preferably, the first material comprises silicon, the second material comprises Mo.sub.2 C, the third material comprises SiC and the fourth material comprises MoSi.sub.2.

  10. Real-Time Particulate Mass Measurements Pre and Post Diesel Particulat...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Real-Time Particulate Mass Measurements Pre and Post Diesel Particulate Filters for ... Filter Loading and Regeneration Real-Time Measurement of Diesel Trap Efficiency ...

  11. Regenerative process and system for the simultaneous removal of particulates and the oxides of sulfur and nitrogen from a gas stream

    DOE Patents [OSTI]

    Cohen, M.R.; Gal, E.

    1993-04-13

    A process and system are described for simultaneously removing from a gaseous mixture, sulfur oxides by means of a solid sulfur oxide acceptor on a porous carrier, nitrogen oxides by means of ammonia gas and particulate matter by means of filtration and for the regeneration of loaded solid sulfur oxide acceptor. Finely-divided solid sulfur oxide acceptor is entrained in a gaseous mixture to deplete sulfur oxides from the gaseous mixture, the finely-divided solid sulfur oxide acceptor being dispersed on a porous carrier material having a particle size up to about 200 microns. In the process, the gaseous mixture is optionally pre-filtered to remove particulate matter and thereafter finely-divided solid sulfur oxide acceptor is injected into the gaseous mixture.

  12. Regenerative process and system for the simultaneous removal of particulates and the oxides of sulfur and nitrogen from a gas stream

    DOE Patents [OSTI]

    Cohen, Mitchell R. (Troy, NY); Gal, Eli (Lititz, PA)

    1993-01-01

    A process and system for simultaneously removing from a gaseous mixture, sulfur oxides by means of a solid sulfur oxide acceptor on a porous carrier, nitrogen oxides by means of ammonia gas and particulate matter by means of filtration and for the regeneration of loaded solid sulfur oxide acceptor. Finely-divided solid sulfur oxide acceptor is entrained in a gaseous mixture to deplete sulfur oxides from the gaseous mixture, the finely-divided solid sulfur oxide acceptor being dispersed on a porous carrier material having a particle size up to about 200 microns. In the process, the gaseous mixture is optionally pre-filtered to remove particulate matter and thereafter finely-divided solid sulfur oxide acceptor is injected into the gaseous The government of the United States of America has rights in this invention pursuant to Contract No. DE-AC21-88MC 23174 awarded by the U.S. Department of Energy.

  13. Asymmetric dark matter

    SciTech Connect (OSTI)

    Kumar, Jason

    2014-06-24

    We review the theoretical framework underlying models of asymmetric dark matter, describe astrophysical constraints which arise from observations of neutron stars, and discuss the prospects for detecting asymmetric dark matter.

  14. Effects on carbon monoxide levels in mobile homes using unvented kerosene heaters for residential heating

    SciTech Connect (OSTI)

    Williams, R.; Walsh, D.; White, J.; Jackson, M.; Mumford, J.

    1992-01-01

    Carbon monoxide (CO) emission levels were continuously monitored in 8 mobile trailer homes less than 10 years old. These homes were monitored in an US EPA study on indoor air quality as affected by unvented portable kerosene heaters. Respondents were asked to operate their heaters in a normal fashion. CO, air exchange and temperature values were measured during the study in each home. Results indicate that consumers using unvented kerosene heaters may be unknowingly exposed to high CO levels without taking proper precautions.

  15. High Performance Silicon Monoxide (SiO) Electrode for Next Generation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Lithium Ion Batteries - Energy Innovation Portal High Performance Silicon Monoxide (SiO) Electrode for Next Generation Lithium Ion Batteries Lawrence Berkeley National Laboratory Contact LBL About This Technology Publications: PDF Document Publication Park, S.-J., Zhao, H., Ai, G., Wang, C., Song, X., Yuca, N., Battaglia, V. S., Yang, W., Liu, G. "Side Chain Conducting and Phase Separated Polymeric Binders for High Performance Silicon Anodes in Lithium Ion Batteries," Journal of

  16. Loading and Regeneration Analysis of a Diesel Particulate Filter with a Radio Frequency-Based Sensor

    SciTech Connect (OSTI)

    Sappok, Alex; Prikhodko, Vitaly Y; Parks, II, James E

    2010-01-01

    Accurate knowledge of diesel particulate filter (DPF) loading is critical for robust and efficient operation of the combined engine-exhaust aftertreatment system. Furthermore, upcoming on-board diagnostics regulations require on-board technologies to evaluate the status of the DPF. This work describes the application of radio frequency (RF) based sensing techniques to accurately measure DPF soot levels and the spatial distribution of the accumulated material. A 1.9L GM turbo diesel engine and a DPF with an RF-sensor were studied. Direct comparisons between the RF measurement and conventional pressure-based methods were made. Further analysis of the particulate matter loading rates was obtained with a mass-based soot emission measurement instrument (TEOM). Comparison with pressure drop measurements show the RF technique is unaffected by exhaust flow variations and exhibits a high degree of sensitivity to DPF soot loading and good dynamic response. Additional computational and experimental work further illustrates the spatial resolution of the RF measurements. Based on the experimental results, the RF technique shows significant promise for improving DPF control enabling optimization of the combined engine-aftertreatment system for improved fuel economy and extended DPF service life.

  17. Method and apparatus for acoustically monitoring the flow of suspended solid particulate matter

    DOE Patents [OSTI]

    Roach, Paul D. (Darien, IL); Raptis, Apostolos C. (Downers Grove, IL)

    1982-01-01

    A method and apparatus for monitoring char flow in a coal gasifier system cludes flow monitor circuits which measure acoustic attenuation caused by the presence of char in a char line and provide a char flow/no flow indication and an indication of relative char density. The flow monitor circuits compute the ratio of signals in two frequency bands, a first frequency band representative of background noise, and a second higher frequency band in which background noise is attenuated by the presence of char. Since the second frequency band contains higher frequencies, the ratio can be used to provide a flow/no flow indication. The second band can also be selected so that attenuation is monotonically related to particle concentration, providing a quantitative measure of char concentration.

  18. Vehicle Technologies Office Merit Review 2014: Fuel-Neutral Studies of Particulate Matter Transport Emissions

    Broader source: Energy.gov [DOE]

    Presentation given by Pacific Northwest National Laboratory at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about fuel...

  19. Big Questions: Dark Matter

    ScienceCinema (OSTI)

    Lincoln, Don

    2014-08-07

    Carl Sagan's oft-quoted statement that there are "billions and billions" of stars in the cosmos gives an idea of just how much "stuff" is in the universe. However scientists now think that in addition to the type of matter with which we are familiar, there is another kind of matter out there. This new kind of matter is called "dark matter" and there seems to be five times as much as ordinary matter. Dark matter interacts only with gravity, thus light simply zips right by it. Scientists are searching through their data, trying to prove that the dark matter idea is real. Fermilab's Dr. Don Lincoln tells us why we think this seemingly-crazy idea might not be so crazy after all.

  20. Big Questions: Dark Matter

    SciTech Connect (OSTI)

    Lincoln, Don

    2013-12-05

    Carl Sagan's oft-quoted statement that there are "billions and billions" of stars in the cosmos gives an idea of just how much "stuff" is in the universe. However scientists now think that in addition to the type of matter with which we are familiar, there is another kind of matter out there. This new kind of matter is called "dark matter" and there seems to be five times as much as ordinary matter. Dark matter interacts only with gravity, thus light simply zips right by it. Scientists are searching through their data, trying to prove that the dark matter idea is real. Fermilab's Dr. Don Lincoln tells us why we think this seemingly-crazy idea might not be so crazy after all.

  1. Particulate and gaseous organic receptor modeling for the southern California Air Quality Study. Final report

    SciTech Connect (OSTI)

    Watson, J.G.; Chow, J.G.; Lu, Z.; Gertler, A.W.

    1993-11-01

    The Chemical Mass Balance (CMB) receptor model was applied to the chemically-speciated diurnal particulate matter samples and volatile organic compound (VOC) acquired during the summer and fall campaigns of the Southern California Air Quality Study (SCAQS). Source profiles applicable to the Los Angeles area were used to apportion PM[sub (2.5)] and PM[sub (10)] to primary paved road dust, primary construction dust, primary motor vehicle exhaust, primary marine aerosol, secondary ammonium nitrate, and secondary ammonium sulfate. Nonmethane hydrocarbon was apportioned to motor vehicle exhaust, liquid fuel, gasoline vapor, gas leaks, architectural and industrial coatings, and biogenic emissions. Suspended dust was the major contributor to PM(10) during the summer, while secondary ammonium nitrate and primary motor vehicle exhaust contributions were high in the fall. Motor vehicle exhaust was the major contributor to nonmethane hydrocarbons, ranging from 30% to 70% of the total.

  2. Variable power distribution for zoned regeneration of an electrically heated particulate filter

    DOE Patents [OSTI]

    Bhatia, Garima [Bangalore, IN; Gonze, Eugene V [Pinckney, MI

    2012-04-03

    A system includes a particulate matter (PM) filter with multiple zones, an electric heater and a control module. The electrical heater includes heater segments, which each correspond with a respective one of the zones. The electrical heater is arranged upstream from and is proximate with the PM filter. The control module selectively applies a first energy level to a first one of the zones via a first one of the heater segments to initiate regeneration in the first zone. The control module also selectively applies a second energy level that is less than the first energy level to a second one of the zones via a second one of the heater segments to initiate regeneration in the second zone.

  3. Development of Advanced Diesel Particulate Filtration (DPF) Systems...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C. PDF icon ace024lee2010o.pdf More Documents & Publications Development of Advanced Diesel Particulate...

  4. Diesel Particulate Filter Technology for Low-Temperature and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Filter Technology for Low-Temperature and Low-NOxPM Applications Diesel Particulate Filter Technology for Low-Temperature and Low-NOxPM Applications 2004 DEER Conference...

  5. Blowers for Air Assisted Diesel Particulate Filter Regeneration...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Blowers for Air Assisted Diesel Particulate Filter Regeneration Prototypes of a new series of high-pressure, brushless DC motor-drive blowers have completed field testing, and DFM ...

  6. Mechanical Properties of Particulate Reinforced Aluminium Alloy Matrix Composite

    SciTech Connect (OSTI)

    Sayuti, M. [Faculty of Engineering, Malikussaleh University of Lhokseumawe, 24300 Aceh (Indonesia); Department of Mechanical and Manufacturing Engineering, Faculty of Engineering, Universiti Putra Malaysia, 43400 Serdang, Selangor (Malaysia); Sulaiman, S.; Baharudin, B. T. H. T.; Arifin, M. K. A. [Department of Mechanical and Manufacturing Engineering, Faculty of Engineering, Universiti Putra Malaysia, 43400 Serdang, Selangor (Malaysia); Suraya, S.; Vijayaram, T. R.

    2011-01-17

    This paper discusses the mechanical properties of Titanium Carbide (TiC) particulate reinforced aluminium-silicon alloy matrix composite. TiC particulate reinforced LM6 alloy matrix composites were fabricated by carbon dioxide sand molding process with different particulate weight fraction. Tensile strength, hardness and microstructure studies were conducted to determine the maximum load, tensile strength, modulus of elasticity and fracture surface analysis have been performed to characterize the morphological aspects of the test samples after tensile testing. Hardness values are measured for the TiC reinforced LM6 alloy composites and it has been found that it gradually increases with increased addition of the reinforcement phase. The tensile strength of the composites increased with the increase percentage of TiC particulate.

  7. ARM - Field Campaign - Semi-Continuous OCEC Particulate Measurement

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Send Campaign : Semi-Continuous OCEC Particulate Measurement 2013.06.01 - 2013.11.27 Lead Scientist : Robert Cary For data sets, see below. Abstract The Sunset Laboratory...

  8. ARM - Field Campaign - 1999 Northeast Corridor Ozone & Particulate...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    would love to hear from you Send us a note below or call us at 1-888-ARM-DATA. Send Campaign : 1999 Northeast Corridor Ozone & Particulate Study 1999.07.23 - 1999.08.11 Lead...

  9. Zone heated inlet ignited diesel particulate filter regeneration

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI; Ament, Frank [Troy, MI

    2012-06-26

    An exhaust system that processes exhaust generated by an engine is provided. The system includes: a particulate filter (PF) that is disposed downstream of the engine and that filters particulates from the exhaust; and a grid that includes electrically resistive material that is segmented by non-conductive material into a plurality of zones and wherein the grid is applied to an exterior upstream surface of the PF.

  10. A Standard Soot Generator for Diesel Particulate Filter Testing |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy A Standard Soot Generator for Diesel Particulate Filter Testing A Standard Soot Generator for Diesel Particulate Filter Testing Poster presentation at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August, 2007, Detroit, Michigan. Sponsored by the U.S. Department of Energy's (DOE) Office of FreedomCAR and Vehicle Technologies (OFCVT). PDF icon deer07_nickolaus.pdf More Documents & Publications XP-SiC: An Innovative Substrate

  11. Mesoscale simulations of particulate flows with parallel distributed

    Office of Scientific and Technical Information (OSTI)

    Lagrange multiplier technique (Journal Article) | SciTech Connect Journal Article: Mesoscale simulations of particulate flows with parallel distributed Lagrange multiplier technique Citation Details In-Document Search Title: Mesoscale simulations of particulate flows with parallel distributed Lagrange multiplier technique Authors: Kanarska, Y ; Lomov, I ; Antoun, T Publication Date: 2010-09-10 OSTI Identifier: 1120915 Report Number(s): LLNL-JRNL-455392 DOE Contract Number: W-7405-ENG-48

  12. Improvement and Simplification of Diesel Particulate Filter System using a

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ceria-Based Fuel-Borne Catalyst in Serial Applications | Department of Energy Improvement and Simplification of Diesel Particulate Filter System using a Ceria-Based Fuel-Borne Catalyst in Serial Applications Improvement and Simplification of Diesel Particulate Filter System using a Ceria-Based Fuel-Borne Catalyst in Serial Applications 2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation: Rhodia Electronics and Catalysis PDF icon 2004_deer_macaudiere.pdf More Documents &

  13. Mesoscale Simulations of Particulate Flows with Parallel Distributed

    Office of Scientific and Technical Information (OSTI)

    Lagrange Multiplier Technique (Conference) | SciTech Connect Mesoscale Simulations of Particulate Flows with Parallel Distributed Lagrange Multiplier Technique Citation Details In-Document Search Title: Mesoscale Simulations of Particulate Flows with Parallel Distributed Lagrange Multiplier Technique × You are accessing a document from the Department of Energy's (DOE) SciTech Connect. This site is a product of DOE's Office of Scientific and Technical Information (OSTI) and is provided as a

  14. Mesoscale simulations of particulate flows with parallel distributed

    Office of Scientific and Technical Information (OSTI)

    Lagrange multiplier technique (Journal Article) | SciTech Connect Journal Article: Mesoscale simulations of particulate flows with parallel distributed Lagrange multiplier technique Citation Details In-Document Search Title: Mesoscale simulations of particulate flows with parallel distributed Lagrange multiplier technique × You are accessing a document from the Department of Energy's (DOE) SciTech Connect. This site is a product of DOE's Office of Scientific and Technical Information (OSTI)

  15. Advanced Radio Frequency-Based Sensors for Monitoring Diesel Particulate

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Filter Loading and Regeneration | Department of Energy Radio Frequency-Based Sensors for Monitoring Diesel Particulate Filter Loading and Regeneration Advanced Radio Frequency-Based Sensors for Monitoring Diesel Particulate Filter Loading and Regeneration Presentation given at the 16th Directions in Engine-Efficiency and Emissions Research (DEER) Conference in Detroit, MI, September 27-30, 2010. PDF icon deer10_sappok.pdf More Documents & Publications Vehicle Technologies Office Merit

  16. Reducing the Particulate Emission Numbers in DI Gasoline Engines |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy the Particulate Emission Numbers in DI Gasoline Engines Reducing the Particulate Emission Numbers in DI Gasoline Engines Formation of droplets was minimized through optimization of fuel vaporization and distribution avoiding air/fuel zones richer than stoichiometric and temperatures that promote particle formation PDF icon deer10_klindt.pdf More Documents & Publications Bosch Powertrain Technologies Vehicle Emissions Review - 2012 Ethanol Effects on Lean-Burn and

  17. Experimental Diesel Particulate Filter Capabilities at PNNL | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Diesel Particulate Filter Capabilities at PNNL Experimental Diesel Particulate Filter Capabilities at PNNL Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and Fuel Partnership and 21st Century Truck Programs. PDF icon 2006_deer_gallant.pdf More Documents & Publications Diesel Soot Filter Characterization and Modeling for Advanced Substrates fundamental Modeling and Experimental Studies of Acicular Mullite Diesel

  18. Failure Stress and Apparent Elastic Modulus of Diesel Particulate Filter

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ceramics | Department of Energy Failure Stress and Apparent Elastic Modulus of Diesel Particulate Filter Ceramics Failure Stress and Apparent Elastic Modulus of Diesel Particulate Filter Ceramics Three established mechanical test specimen geometries and test methods for brittle materials are adapted to DPF architecture to evaluate failure initiation stress and apparent elastic modulus of the ceramics. PDF icon p-15_wereszczak.pdf More Documents & Publications Durability of Diesel Engine

  19. Ultra-Lite Diesel Particulate Filter Cartridge for Reduced Regeneration

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Time and Fuel Consumption | Department of Energy Lite Diesel Particulate Filter Cartridge for Reduced Regeneration Time and Fuel Consumption Ultra-Lite Diesel Particulate Filter Cartridge for Reduced Regeneration Time and Fuel Consumption Self-cleaning ceramic filter cartridges offer the advantage of better fuel economy, faster regeneration time, improved heat transfer, and reduction in manufacturing steps PDF icon deer09_nixdorf.pdf More Documents & Publications Pleated Ceramic Fiber

  20. Value Analysis of Alternative Diesel Particulate Filter (DPF) Substrates

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    for Future Diesel Aftertreatment Systems | Department of Energy Value Analysis of Alternative Diesel Particulate Filter (DPF) Substrates for Future Diesel Aftertreatment Systems Value Analysis of Alternative Diesel Particulate Filter (DPF) Substrates for Future Diesel Aftertreatment Systems DPF products like Acicular Mullite meet multiple needs Provide higher soot mass limits and durability than other materials at the same porosity. PDF icon deer09_majkowski.pdf More Documents &

  1. Diesel Particulate Filters: Market Introducution in Europe | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Filters: Market Introducution in Europe Diesel Particulate Filters: Market Introducution in Europe 2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation: Aaqius and Aaqius PDF icon 2004_deer_seguelong2.pdf More Documents & Publications A New Active DPF System for "Stop and Go" Duty-Cycle Vehicles French perspective on diesel engines & emissions Diesel Particulate Filter: A Success for Faurecia Exhaust Systems

  2. Tailored Acicular Mullite Substrates for Multifunctional Diesel Particulate

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Filters | Department of Energy Acicular Mullite Substrates for Multifunctional Diesel Particulate Filters Tailored Acicular Mullite Substrates for Multifunctional Diesel Particulate Filters SEM analysis showed that ACM DPF can be coated with relatively high catalyst washcoat without significantly affecting the porosity or pore size Therefore, it maintains a low back pressure performance at very high catalyst PDF icon deer09_malanga.pdf More Documents & Publications Future Trends for

  3. Radio Frequency Diesel Particulate Filter Sensor Reduces Fuel Consumption,

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Wins R&D 100 Award | Department of Energy Radio Frequency Diesel Particulate Filter Sensor Reduces Fuel Consumption, Wins R&D 100 Award Radio Frequency Diesel Particulate Filter Sensor Reduces Fuel Consumption, Wins R&D 100 Award October 15, 2014 - 4:51pm Addthis Developed jointly by Corning, the FEV Group, Maguffin Microwave, Detroit Diesel, and Oak Ridge National Laboratory (ORNL) in cooperation with the New York City Department of Sanitation, the Radio Frequency Diesel

  4. Progression of soot cake layer properties during the systematic regeneration of diesel particulate filters measured with neutron tomography

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Toops, Todd J.; Pihl, Josh A.; Finney, Charles E. A.; Gregor, Jens; Bilheux, Hassina

    2015-01-16

    Although particulate filters (PFs) have been a key component of the emission control system for modern diesel engines, there remain significant questions about the basic regeneration behavior of the filters and how it changes with accumulation of increasing soot layers. This effort describes a systematic deposition and regeneration of particulate matter in 25-mm diameter 76-mm long wall-flow PFs composed of silicon carbide (SiC) material. The initial soot distributions were analyzed for soot cake thickness using a nondestructive neutron imaging technique. With the PFs intact, it was then possible to sequentially regenerate the samples and reanalyze them, which was performedmoreafter nominal 20, 50, and 70 % regenerations. The loaded samples show a relatively uniform distribution of particulate with an increasing soot cake thickness and nearly identical initial density of 70 mg/cm3. Throughout regeneration, the soot cake thickness initially decreases significantly while the density increases to 8090 mg/cm3. After ~50 % regeneration, the soot cake thickness stays relatively constant, but instead, the density decreases as pores open up in the layer (~35 mg/cm3 at 70 % regeneration). Complete regeneration initially occurs at the rear of the PF channels. With this information, a conceptual model of the regeneration is proposed.less

  5. Diesel particulate filter (DPF) regeneration by electrical heating of resistive coatings

    DOE Patents [OSTI]

    Williamson, Weldon S. (Malibu, CA); Gonze, Eugene V. (Pinckney, MI)

    2008-12-30

    An exhaust system that processes exhaust generated by an engine includes a diesel particulate filter (DPF) that is disposed downstream of the engine and that filters particulates from the exhaust. An electrical heater is integrally formed in an upstream end of the DPF and selectively heats the exhaust to initiate combustion of the particulates within the exhaust as it passes therethrough. Heat generated by combustion of the particulates induces combustion of particulates within the DPF.

  6. Materials/Condensed Matter

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Materials/Condensed Matter Materials/Condensed Matter Print Materials research provides the foundation on which the economic well being of our high-tech society rests. The impact of advanced materials ranges dramatically over every aspect of our modern world from the minutiae of daily life to the grand scale of our national economy. Invariably, however, breakthroughs to new technologies trace their origin both to fundamental research in the basic properties of condensed matter and to applied

  7. Cosmology with Mimetic Matter

    SciTech Connect (OSTI)

    Chamseddine, Ali H.; Mukhanov, Viatcheslav; Vikman, Alexander E-mail: viatcheslav.Mukhanov@lmu.de

    2014-06-01

    We consider minimal extensions of the recently proposed Mimetic Dark Matter and show that by introducing a potential for the mimetic non-dynamical scalar field we can mimic nearly any gravitational properties of the normal matter. In particular, the mimetic matter can provide us with inflaton, quintessence and even can lead to a bouncing nonsingular universe. We also investigate the behaviour of cosmological perturbations due to a mimetic matter. We demonstrate that simple mimetic inflation can produce red-tilted scalar perturbations which are largely enhanced over gravity waves.

  8. Science on Tap - Matter

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Science on Tap - Matter Science on Tap - Matter WHEN: Feb 18, 2016 5:30 PM - 7:00 PM WHERE: UnQuarked Wine Room 145 Central Park Square, Los Alamos, New Mexico 87544 USA SPEAKER: Jack Shlachter CONTACT: Linda Anderman (505) 665-9196 CATEGORY: Bradbury INTERNAL: Calendar Login Event Description Mark your calendars for this event held every third Thursday from 5:30 to 7 p.m. A short presentation is followed by a lively discussion on a different subject each month. What's the Matter with Matter?

  9. Energy Matters Mailbag

    Broader source: Energy.gov [DOE]

    This edition of the mailbag tackles follow-up questions from our Energy Matters discussion on breaking our reliance on foreign oil.

  10. Dark Matter Theory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    matter? What is its large scale structure and evolution of the Universe? results from satelite satellite image Read caption + Figure: Recent results from the Planck satellite...

  11. Dark Matter Theory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Dark Matter Theory Dark Matter Theory Understanding discoveries at the Energy, Intensity, and Cosmic Frontiers Get Expertise Rajan Gupta (505) 667-7664 Email Bruce Carlsten (505) 667-5657 Email Dark Matter Theory The existence of dark matter can be traced back to the pioneering discoveries of Fritz Zwicky and Jan Oort that the motion of galaxies in the Coma cluster, and of nearby stars in our own Galaxy, do not follow the expected motion based on Newton's law of gravity and the observed visible

  12. Center for Nanophase Materials Sciences (CNMS) - Soft matter synthesis

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Soft matter synthesis

  13. Ti{sub 5}O{sub 5} superstructures of cubic titanium monoxide

    SciTech Connect (OSTI)

    Gusev, A. I.

    2013-08-15

    A cubic model is proposed for the Ti{sub 5}O{sub 5} (Ti{sub 5} Black-Small-Square O{sub 5}{open_square} {identical_to} Ti{sub 90} Black-Small-Square {sub 18}O{sub 90}{open_square}{sub 18}) superstructure of nonstoichiometric titanium monoxide Ti{sub x}O{sub z} with double imperfection. The unit cell of the cubic Ti{sub 5}O{sub 5} superstructure has the threefold lattice parameter of the unit cell of the basis disordered B1 structure of Ti{sub x}O{sub z} monoxide and belongs to space group Pm 3-bar m . The channel of the disorder-order transition, i.e., Ti{sub x}O{sub z} (space group Fm 3-bar m)-Ti{sub 5}O{sub 5} (space group Pm 3-bar m), includes 75 superstructure vectors of seven stars (k{sub 10}), (k{sub 7}), (k{sub 6(1)}), (k{sub 6(2)}), (k{sub 4(1)}), (k{sub 4(2)}), and (k{sub 1}). The distribution functions of Ti and O atoms over the sites of the cubic Ti{sub 5}O{sub 5} superstructure are calculated. A comparison of the X-ray and electron diffraction data obtained for ordered TiO{sub 1.087} monoxide with the theoretical simulation results supports the existence of the cubic Ti{sub 5}O{sub 5} superstructure. The cubic (space group Pm 3-bar m) Ti{sub 5}O{sub 5} superstructure is shown to be a high-temperature structure relative to the well-known monoclinic (space group C2/m) superstructure of the same type.

  14. Carbon monoxide tolerant electrocatalyst with low platinum loading and a process for its preparation

    DOE Patents [OSTI]

    Adzic, Radoslav; Brankovic, Stanko; Wang, Jia

    2003-12-30

    An electrocatalyst is provided for use in a fuel cell that has low platinum loading and a high tolerance to carbon monoxide poisoning. The fuel cell anode includes an electrocatalyst that has a conductive support material, ruthenium nanoparticles reduced in H.sub.2 and a Group VIII noble metal in an amount of between about 0.1 and 25 wt % of the ruthenium nanoparticles, preferably between about 0.5 and 15 wt %. The preferred Group VIII noble metal is platinum. In one embodiment, the anode can also have a perfluorinated polymer membrane on its surface.

  15. Method for dispersing catalyst onto particulate material and product thereof

    DOE Patents [OSTI]

    Utz, Bruce R. (Pittsburgh, PA); Cugini, Anthony V. (Pittsburgh, PA)

    1992-01-01

    A method for dispersing finely divided catalyst precursors onto the surface of coal or other particulate material includes the steps of forming a wet paste mixture of the particulate material and a liquid solution containing a dissolved transition metal salt, for instance a solution of ferric nitrate. The wet paste mixture is in a state of incipient wetness with all of this solution adsorbed onto the surfaces of the particulate material without the presence of free moisture. On adding a precipitating agent such as ammonia, a catalyst precursor such as hydrated iron oxide is deposited on the surfaces of the coal. The catalyst is activated by converting it to the sulfide form for the hydrogenation or direct liquefaction of the coal.

  16. Method and apparatus for injecting particulate media into the ground

    DOE Patents [OSTI]

    Dwyer, Brian P.; Dwyer, Stephen F.; Vigil, Francine S.; Stewart, Willis E.

    2004-12-28

    An improved method and apparatus for injecting particulate media into the ground for constructing underground permeable reactive barriers, which are used for environmental remediation of subsurface contaminated soil and water. A media injector sub-assembly attached to a triple wall drill string pipe sprays a mixture of active particulate media suspended in a carrier fluid radially outwards from the sub-assembly, at the same time that a mixing fluid is sprayed radially outwards. The media spray intersects the mixing spray at a relatively close distance from the point of injection, which entrains the particulate media into the mixing spray and ensures a uniform and deep dispersion of the active media in the surrounding soil. The media injector sub-assembly can optionally include channels for supplying compressed air to an attached down-the-hole hammer drive assembly for use during drilling.

  17. On the photoelectron velocity-map imaging of lutetium monoxide anion LuO{sup ?}

    SciTech Connect (OSTI)

    Liu, Zhiling; Xie, Hua; Qin, Zhengbo; Cong, Ran; Wu, Xia; Tang, Zichao, E-mail: zctang@dicp.ac.cn; Fan, Hongjun, E-mail: fanhj@dicp.ac.cn [State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 (China)] [State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 (China); Li, Quanjiang [School of Physics and Optoelectronic Technology, and College of Advanced Science and Technology, Dalian University of Technology, Dalian 116024 (China)] [School of Physics and Optoelectronic Technology, and College of Advanced Science and Technology, Dalian University of Technology, Dalian 116024 (China)

    2014-01-21

    We report a combined photoelectron velocity-map imaging spectroscopy and density functional theory investigation on lutetium monoxide anion. Transition between the X {sup 1}?{sup +} anion electronic ground state and the neutral X {sup 2}?{sup +} electronic ground state is observed. Vibrationally resolved spectra were obtained at four different photon energies, providing a wealth of spectroscopic information for the electronic ground states of the anionic lutetium monoxide and corresponding neutral species. Franck-Condon simulations of the ground-state transition are performed to assign vibrational structure in the spectra and to assist in identifying the observed spectral bands. The electronic ground state of LuO{sup ?} is found to have a vibrational frequency of 743 10 cm{sup ?1} and an equilibrium bond length of 1.841 . The electron affinity of LuO is measured to be 1.624 0.002 eV. The fundamental frequency of ground-state LuO is estimated to be 839 10 cm{sup ?1}.

  18. Thermal device and method for production of carbon monoxide and hydrogen by thermal dissociation of hydrocarbon gases

    DOE Patents [OSTI]

    Detering, Brent A. (Idaho Falls, ID); Kong, Peter C. (Idaho Falls, ID)

    2001-01-01

    Carbon monoxide is produced in a fast quench reactor. The production of carbon monoxide includes injecting carbon dioxide and some air into a reactor chamber having a high temperature at its inlet and a rapidly expanding a reactant stream, such as a restrictive convergent-divergent nozzle at its outlet end. Carbon dioxide and other reactants such as methane and other low molecular weight hydrocarbons are injected into the reactor chamber. Other gas may be added at different stages in the process to form a desired end product and prevent back reactions. The resulting heated gaseous stream is then rapidly cooled by expansion of the gaseous stream.

  19. EERE Success Story-Radio Frequency Diesel Particulate Filter Sensor

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Reduces Fuel Consumption, Wins R&D 100 Award | Department of Energy Radio Frequency Diesel Particulate Filter Sensor Reduces Fuel Consumption, Wins R&D 100 Award EERE Success Story-Radio Frequency Diesel Particulate Filter Sensor Reduces Fuel Consumption, Wins R&D 100 Award October 15, 2014 - 4:51pm Addthis Developed jointly by Corning, the FEV Group, Maguffin Microwave, Detroit Diesel, and Oak Ridge National Laboratory (ORNL) in cooperation with the New York City Department of

  20. Imaging of Diesel Particulate Filters using a High-Flux Neutron...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Imaging of Diesel Particulate Filters using a High-Flux Neutron Source Imaging of Diesel Particulate Filters using a High-Flux Neutron Source Detailed images of deposits identified...

  1. Testing an Active Diesel Particulate Filter on a 2-Cycle Marine...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    an Active Diesel Particulate Filter on a 2-Cycle Marine Engine Testing an Active Diesel Particulate Filter on a 2-Cycle Marine Engine Presentation given at DEER 2006, August 20-24, ...

  2. UTILIZING WATER EMULSIFICATION TO REDUCE NOX AND PARTICULATE EMISSIONS ASSOCIATED WITH BIODIESEL

    SciTech Connect (OSTI)

    Kass, Michael D; Lewis Sr, Samuel Arthur; Lee, Doh-Won; Huff, Shean P; Storey, John Morse; Swartz, Matthew M; Wagner, Robert M

    2009-01-01

    A key barrier limiting extended utilization of biodiesel is higher NOx emissions compared to petrodiesel fuels. The reason for this effect is unclear, but various researchers have attributed this phenomena to the higher liquid bulk modulus associated with biodiesel and the additional heat released during the breaking of C-C double bonds in the methyl ester groups. In this study water was incorporated into neat biodiesel (B100) as an emulsion in an attempt to lower NOx and particulate matter (PM) emissions. A biodiesel emulsion containing 10wt% water was formulated and evaluated against an ultra-low sulfur petroleum diesel (ULSD) and neat biodiesel (B100) in a light-duty diesel engine operated at 1500RPM and at loads of 68Nm (50ft-lbs) and 102Nm (75ft-lbs). The influence of exhaust gas recirculation (EGR) was also examined. The incorporation of water was found to significantly lower the NOx emissions of B100, while maintaining fuel efficiency when operating at 0 and 27% EGR. The soot fraction of the particulates (as determined using an opacity meter) was much lower for the B100 and B100-water emulsion compared ULSD. In contrast, total PM mass (for the three fuel types) was unchanged for the 0% EGR condition but was significantly lower for the B100 and B100-emulsion during the 27% EGR condition compared to the ULSD fuel. Analysis of the emissions and heat release data indicate that water enhances air-fuel premixing to maintain fuel economy and lower soot formation. The exhaust chemistry of the biodiesel base fuels (B100 and water-emulsified B100) was found to be unique in that they contained measurable levels of methyl alkenoates, which were not found for the ULSD. These compounds were formed by the partial cracking of the methyl ester groups during combustion.

  3. Materials/Condensed Matter

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Materials/Condensed Matter Print Materials research provides the foundation on which the economic well being of our high-tech society rests. The impact of advanced materials ranges dramatically over every aspect of our modern world from the minutiae of daily life to the grand scale of our national economy. Invariably, however, breakthroughs to new technologies trace their origin both to fundamental research in the basic properties of condensed matter and to applied research aimed at manipulating

  4. A New CFD Model for understanding and Managing Diesel Particulate Filter

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Regeneration | Department of Energy CFD Model for understanding and Managing Diesel Particulate Filter Regeneration A New CFD Model for understanding and Managing Diesel Particulate Filter Regeneration PDF icon 2004_deer_hou.pdf More Documents & Publications Substrate Studies of an Electrically-Assisted Diesel Particulate Filter Diesel Particulate Filter: A Success for Faurecia Exhaust Systems Vehicle Evaluation of Downsized Dow ACM DPF

  5. Electrically heated particulate filter diagnostic systems and methods

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI

    2009-09-29

    A system that diagnoses regeneration of an electrically heated particulate filter is provided. The system generally includes a grid module that diagnoses a fault of the grid based on at least one of a current signal and a voltage signal. A diagnostic module at least one of sets a fault status and generates a warning signal based on the fault of the grid.

  6. Comparison of Particulate Collection in Probes and on Filters

    SciTech Connect (OSTI)

    Eaton, J.M.; Humphreys, M.P.

    2001-06-14

    Major radionuclide emissions from the Department of Energy's Y-12 National Security Complex are nuclides of uranium which are emitted as a particulate. The radionuclide NESHAP regulation requires stack sampling to be conducted in accordance with ANST Standard N13.1, 1969. Appendix B of this standard requires in every case where sampling delivery lines are used that an evaluation should be made of deposition in these lines. A number of Y-12 Complex stacks are fitted with continuous samplers which draw particulate laden air through a probe and across a sample filter. One approach to evaluate line loss as required by the ANSI standard is to establish a representative factor that is used for all subsequent sampling efforts. Another approach is to conduct a routine probe wash procedure on an ongoing basis to account for line losses. In 1991, Y-12 National Security Complex personnel began routine probe washes as part of their sample collection procedure. Since then, 50-80 stacks have been sampled on a near continuous basis and probe washes have been conducted quarterly. Particulate collection in probes versus particulate collection on filters is recorded as a probe factor and probe factor trends for a 10-year period are available.

  7. Process for producing hydrogen and carbonyl sulfide from hydrogen sulfide and carbon monoxide using a heteropolyanionic metal complex catalyst

    SciTech Connect (OSTI)

    Kuch, Ph. L.

    1984-12-18

    Hydrogen and carbonyl sulfide are produced by a process comprising contracting gaseous hydrogen sulfide with gaseous carbon monoxide in the presence of a heteropolymolybdate or tungstate complex. Use of these catalysts reduce the amount of by-product carbon dioxide and methane formation and thus enhance the make of hydrogen and carbonyl sulfide.

  8. Electrically heated particulate filter regeneration methods and systems for hybrid vehicles

    DOE Patents [OSTI]

    Gonze, Eugene V. (Pinckney, MI); Paratore, Jr., Michael J. (Howell, MI)

    2010-10-12

    A control system for controlling regeneration of a particulate filter for a hybrid vehicle is provided. The system generally includes a regeneration module that controls current to the particulate filter to initiate regeneration. An engine control module controls operation of an engine of the hybrid vehicle based on the control of the current to the particulate filter.

  9. Asymmetric twin Dark Matter

    SciTech Connect (OSTI)

    Farina, Marco

    2015-11-09

    We study a natural implementation of Asymmetric Dark Matter in Twin Higgs models. The mirroring of the Standard Model strong sector suggests that a twin baryon with mass around 5 GeV is a natural Dark Matter candidate once a twin baryon number asymmetry comparable to the SM asymmetry is generated. We explore twin baryon Dark Matter in two different scenarios, one with minimal content in the twin sector and one with a complete copy of the SM, including a light twin photon. The essential requirements for successful thermal history are presented, and in doing so we address some of the cosmological issues common to many Twin Higgs models. The required interactions we introduce predict signatures at direct detection experiments and at the LHC.

  10. Origin of particulate organic carbon in the marine atmosphere as indicated by it stable carbon isotopic composition

    SciTech Connect (OSTI)

    Chesselet, R.; Fontugne, M.; Buat-Menard, P.; Ezat, U.; Lambert, C.E.

    1981-04-01

    Organic carbon concentration and isotopic composition were determined in samples of atmospheric particulate matter collected in 1979 at remote marine locations (Enewetak atoll, Sargasso Sea) during the SEAREX (Sea-Air Exchange) program field experiments. Atmospheric Particulate Organic Carbon (POC) concentrations were found to be in the range of 0.3 to 1.2 mg. m/sup -3/, in agreement with previous literature data. The major mass of POC was found on the smallest particles (r<0.5 mm). The /sup 13/C//sup 12/C of the small particles is close to the one expected (d/sup 13/C = 26 +- 2/sup 0///sub infinity/) for atmospheric POC of continental origin. For all the samples analysed so far, it appears that more than 80% of atmospheric POC over remote marine areas is of continental origin. This can be explained either by long-range transport of small sized continental organic aserosols or by the production of POC in the marine atmosphere from a vapor phase organic carbon pool of continental origin. The POC in the large size fraction of marine aerosols (<20% of the total concentration) is likely to have a direct marine origin since its carbon isotopic composition is close to the expected value (d/sup 13/C = -21 +- 2/sup 0///sub 00/) for POC associated with sea-salt droplets transported to the marine atmosphere.

  11. Fluidizable particulate materials and methods of making same

    DOE Patents [OSTI]

    Gupta, Raghubir P. (Durham, NC)

    1999-01-01

    The invention provides fluidizable, substantially spherical particulate material of improved attrition resistance having an average particle size from about 100 to about 400 microns useful as sorbents, catalysts, catalytic supports, specialty ceramics or the like. The particles are prepared by spray drying a slurry comprising inorganic starting materials and an organic binder. Exemplary inorganic starting materials include mixtures of zinc oxide with titanium dioxide, or with iron oxide, alumina or the like. Exemplary organic binders include polyvinyl alcohol, hydroxypropylemethyl cellulose, polyvinyl acetate and the like. The spray dried particles are heat treated at a first temperature wherein organic binder material is removed to thereby provide a porous structure to the particles, and thereafter the particles are calcined at a higher temperature to cause reaction of the inorganic starting materials and to thereby form the final inorganic particulate material.

  12. Design characteristics for facilities which process hazardous particulate

    SciTech Connect (OSTI)

    Abeln, S.P.; Creek, K.; Salisbury, S.

    1998-12-01

    Los Alamos National Laboratory is establishing a research and processing capability for beryllium. The unique properties of beryllium, including light weight, rigidity, thermal conductivity, heat capacity, and nuclear properties make it critical to a number of US defense and aerospace programs. Concomitant with the unique engineering properties are the health hazards associated with processing beryllium in a particulate form and the potential for worker inhalation of aerosolized beryllium. Beryllium has the lowest airborne standard for worker protection compared to all other nonradioactive metals by more than an order of magnitude. This paper describes the design characteristics of the new beryllium facility at Los Alamos as they relate to protection of the workforce. Design characteristics to be reviewed include; facility layout, support systems to minimize aerosol exposure and spread, and detailed review of the ventilation system design for general room air cleanliness and extraction of particulate at the source.

  13. Fluidizable particulate materials and methods of making same

    SciTech Connect (OSTI)

    Gupta, R.P.

    1999-10-26

    The invention provides fluidizable, substantially spherical particulate material of improved attrition resistance having an average particle size from about 100 to about 400 microns useful as sorbents, catalysts, catalytic supports, specialty ceramics or the like. The particles are prepared by spray drying a slurry comprising inorganic starting materials and an organic binder. Exemplary inorganic starting materials include mixtures of zinc oxide with titanium dioxide, or with iron oxide, alumina or the like. Exemplary organic binders include polyvinyl alcohol, hydroxypropylemethyl cellulose, polyvinyl acetate and the like. The spray dried particles are heat treated at a first temperature wherein organic binder material is removed to thereby provide a porous structure to the particles, and thereafter the particles are calcined at a higher temperature to cause reaction of the inorganic starting materials and to thereby form the final inorganic particulate material.

  14. Stabilization void-fill encapsulation high-efficiency particulate filters

    SciTech Connect (OSTI)

    Alexander, R.G.; Stewart, W.E.; Phillips, S.J.; Serkowski, M.M.; England, J.L.; Boynton, H.C.

    1994-05-01

    This report discusses high-efficiency particulate air (HEPA) filter systems that which are contaminated with radionuclides are part of the nuclear fuel processing systems conducted by the US Department of Energy (DOE) and require replacement and safe and efficient disposal for plant safety. Two K-3 HEPA filters were removed from service, placed burial boxes, buried, and safely and efficiently stabilized remotely which reduced radiation exposure to personnel and the environment.

  15. Advanced hybrid particulate collector and method of operation

    DOE Patents [OSTI]

    Miller, Stanley J. (Grand Forks, ND)

    2003-04-08

    A device and method for controlling particulate air pollutants of the present invention combines filtration and electrostatic collection devices. The invention includes a chamber housing a plurality of rows of filter elements. Between the rows of filter elements are rows of high voltage discharge electrodes. Between the rows of discharge electrodes and the rows of filter elements are grounded perforated plates for creating electrostatic precipitation zones.

  16. Diesel Particulate Oxidation Model: Combined Effects of Fixed & Volatile

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Carbon | Department of Energy Oxidation Model: Combined Effects of Fixed & Volatile Carbon Diesel Particulate Oxidation Model: Combined Effects of Fixed & Volatile Carbon Poster presented at the 16th Directions in Engine-Efficiency and Emissions Research (DEER) Conference in Detroit, MI, September 27-30, 2010. PDF icon p-14_strzelec.pdf More Documents & Publications Non-Petroleum-Based Fuels: Effects on Emissions Control Technologies Vehicle Technologies Office: 2010 Fuel

  17. Inflatable Dark Matter

    SciTech Connect (OSTI)

    Davoudiasl, Hooman; Hooper, Dan; McDermott, Samuel D.

    2015-07-30

    We describe a general scenario, dubbed Inflatable Dark Matter, in which the density of dark matter particles can be reduced through a short period of late-time inflation in the early universe. The overproduction of dark matter that is predicted within many otherwise well-motivated models of new physics can be elegantly remedied within this context, without the need to tune underlying parameters or to appeal to anthropic considerations. Thermal relics that would otherwise be disfavored can easily be accommodated within this class of scenarios, including dark matter candidates that are very heavy or very light. Furthermore, the non-thermal abundance of GUT or Planck scale axions can be brought to acceptable levels, without invoking anthropic tuning of initial conditions. Additionally, a period of late-time inflation could have occurred over a wide range of scales from ~ MeV to the weak scale or above, and could have been triggered by physics within a hidden sector, with small but not necessarily negligible couplings to the Standard Model.

  18. Energy Matters - Fall 2002

    SciTech Connect (OSTI)

    2002-09-01

    Quarterly newsletter from DOE's Industrial Technologies Program to promote the use of energy-efficient industrial systems. This issue focus of this edition of the Energy Matters Newsletter is on energy and environmental issues. Read more about compressed air's role in productivity, making good motor decisions, and more.

  19. Energy Matters - Spring 2002

    SciTech Connect (OSTI)

    2002-03-01

    Quarterly newsletter from DOE's Industrial Technologies Program to promote the use of energy-efficient industrial systems. The focus of the Spring 2002 Issue of Energy Matters focuses on premium energy efficiency systems, with articles on new gas technologies, steam efficiency, the Augusta Newsprint Showcase, and more.

  20. Mutagenic activity and chemical analysis of airborne particulates collected in Pisa (Italy)

    SciTech Connect (OSTI)

    Vellosi, R.; Fiorio, R.; Rosellini, D.; Bronzetti, G. ); Vannucchi, C.; Ciacchini, G.; Giaconi, V. ); Bianchi, F. )

    1994-03-01

    In the last few years there has been much concern about the problem connected to the exposure to mutagens present in the environment of industrialized countries. Particularly, the mutagenic activity of airborne particulate matter has been studied by many investigators and correlated with elevated lung cancer mortality rates. In most cases the Salmonella typhimurium/microsome test has been used for these studies. This short-term test, which is the most validated among the short-term genotoxicity tests, provides an important indication on the carcinogenic potential of environmental pollutants. That are complex mixtures containing a wide variety of compounds potentially capable of causing additive, antagonistic or synergistic genotoxic response in living organisms. Several studies have suggested that diverse factors, such as traffic and meteorological conditions, could affect the levels of pollutants in the air. In our work, we have investigated three different areas in Pisa, where the intensity and the kind of the road traffic were different. Airborne particles have been collected during a year and the genotoxic activity has been studied using TA98 and TA100 strains of Salmonella typhimurium. 20 refs., 1 fig., 3 tabs.

  1. Detailed Characterization of Particulates Emitted by Pre-Commercial Single-Cylinder Gasoline Compression Ignition Engine

    SciTech Connect (OSTI)

    Zelenyuk, Alla; Reitz, Paul; Stewart, Mark L.; Imre, D.; Loeper, Paul; Adams, Cory; Andrie, Michael; Rothamer, David; Foster, David E.; Narayanaswamy, Kushal; Najt, Paul M.; Solomon, Arun S.

    2014-08-01

    Gasoline Compression Ignition (GCI) engines have the potential to achieve high fuel efficiency and to significantly reduce both NOx and particulate matter (PM) emissions by operating under dilute partially-premixed conditions. This low temperature combustion strategy is dependent upon direct-injection of gasoline during the compression stroke and potentially near top dead center (TDC). The timing and duration of the in-cylinder injections can be tailored based on speed and load to create optimized conditions that result in a stable combustion. We present the results of advanced aerosol analysis methods that have been used for detailed real-time characterization of PM emitted from a single-cylinder GCI engine operated at different speed, load, timing, and number and duration of near-TDC fuel injections. PM characterization included 28 measurements of size and composition of individual particles sampled directly from the exhaust and after mass and/or mobility classification. We use these data to calculate particle effective density, fractal dimension, dynamic shape factors in free-molecular and transition flow regimes, average diameter of primary spherules, number of spherules, and void fraction of soot agglomerates.

  2. Molten metal reactor and method of forming hydrogen, carbon monoxide and carbon dioxide using the molten alkaline metal reactor

    DOE Patents [OSTI]

    Bingham, Dennis N.; Klingler, Kerry M.; Turner, Terry D.; Wilding, Bruce M.

    2012-11-13

    A molten metal reactor for converting a carbon material and steam into a gas comprising hydrogen, carbon monoxide, and carbon dioxide is disclosed. The reactor includes an interior crucible having a portion contained within an exterior crucible. The interior crucible includes an inlet and an outlet; the outlet leads to the exterior crucible and may comprise a diffuser. The exterior crucible may contain a molten alkaline metal compound. Contained between the exterior crucible and the interior crucible is at least one baffle.

  3. The Search for Dark Matter

    ScienceCinema (OSTI)

    Orrell, John

    2014-07-24

    More than 25 years ago, PNNL scientists began the first underground measurements searching for dark matter using specialized radiation detector technology. Dark matter is yet to be discovered says Physicist John L. Orrell.

  4. The Search for Dark Matter

    SciTech Connect (OSTI)

    Orrell, John

    2013-11-20

    More than 25 years ago, PNNL scientists began the first underground measurements searching for dark matter using specialized radiation detector technology. Dark matter is yet to be discovered says Physicist John L. Orrell.

  5. Direct search for dark matter

    SciTech Connect (OSTI)

    Yoo, Jonghee; /Fermilab

    2009-12-01

    Dark matter is hypothetical matter which does not interact with electromagnetic radiation. The existence of dark matter is only inferred from gravitational effects of astrophysical observations to explain the missing mass component of the Universe. Weakly Interacting Massive Particles are currently the most popular candidate to explain the missing mass component. I review the current status of experimental searches of dark matter through direct detection using terrestrial detectors.

  6. Relationship of respiratory symptoms and pulmonary function to tar, nicotine, and carbon monoxide yield of cigarettes

    SciTech Connect (OSTI)

    Krzyzanowski, M.; Sherrill, D.L.; Paoletti, P.; Lebowitz, M.D. )

    1991-02-01

    The data from consecutive surveys of the Tucson Epidemiologic Study (1981-1988) were used to evaluate the relationship in cigarette smokers of respiratory symptoms and pulmonary function to tar, nicotine, and carbon monoxide (CO) yields of the cigarette. There were 690 subjects who reported smoking regularly in at least one survey, over age 15. After adjustment for intensity and duration of smoking and for depth of inhalation, the risk of chronic phlegm, cough, and dyspnea were not related to the tar and nicotine yields. In 414 subjects with pulmonary function tested in at least one of the three surveys the spirometric indices used were significantly related to the daily dose of tar, nicotine, and CO (product of the cigarette yield and daily number of cigarettes smoked). The effects were more pronounced for past than for current doses. However, the differentiation of pulmonary function due to various yields of cigarettes was small in comparison to the difference in pulmonary function between smokers and nonsmokers.

  7. Cosmology with matter diffusion

    SciTech Connect (OSTI)

    Calogero, Simone; Velten, Hermano E-mail: velten@cce.ufes.br

    2013-11-01

    We construct a viable cosmological model based on velocity diffusion of matter particles. In order to ensure the conservation of the total energy-momentum tensor in the presence of diffusion, we include a cosmological scalar field ? which we identify with the dark energy component of the universe. The model is characterized by only one new degree of freedom, the diffusion parameter ?. The standard ?CDM model can be recovered by setting ? = 0. If diffusion takes place (? > 0) the dynamics of the matter and of the dark energy fields are coupled. We argue that the existence of a diffusion mechanism in the universe may serve as a theoretical motivation for interacting models. We constrain the background dynamics of the diffusion model with Supernovae, H(z) and BAO data. We also perform a perturbative analysis of this model in order to understand structure formation in the universe. We calculate the impact of diffusion both on the CMB spectrum, with particular attention to the integrated Sachs-Wolfe signal, and on the matter power spectrum P(k). The latter analysis places strong constraints on the magnitude of the diffusion mechanism but does not rule out the model.

  8. Partial-Flow Diesel Particulate Filter of Sintered Metal Fiber Fleece |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Partial-Flow Diesel Particulate Filter of Sintered Metal Fiber Fleece Partial-Flow Diesel Particulate Filter of Sintered Metal Fiber Fleece Poster presented at the 16th Directions in Engine-Efficiency and Emissions Research (DEER) Conference in Detroit, MI, September 27-30, 2010. PDF icon p-05_lu.pdf More Documents & Publications Advanced Metal Fiber Wall-Flow DPF For Diesel Emission Control Requirements from Particulate Filter Technology for Commercial Vehicles:

  9. New Cordierite Diesel Particulate Filters for Catalyzed and Non-Catalyzed

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Applications | Department of Energy Cordierite Diesel Particulate Filters for Catalyzed and Non-Catalyzed Applications New Cordierite Diesel Particulate Filters for Catalyzed and Non-Catalyzed Applications 2003 DEER Conference Presentation: Corning Incorporated PDF icon 2003_deer_merkel.pdf More Documents & Publications 12TH DIESEL ENGINE-EFFICIENCY AND EMISSIONS RESEARCH CONFERENCE (DEER 2006) PRESENTATIONS Vehicle Technologies Office Merit Review 2015: Particulate Emissions Control by

  10. Development of a Sub-Grid Model of a Diesel Particulate Filter: application

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of the lattice-Boltzmann technique | Department of Energy a Sub-Grid Model of a Diesel Particulate Filter: application of the lattice-Boltzmann technique Development of a Sub-Grid Model of a Diesel Particulate Filter: application of the lattice-Boltzmann technique 2002 DEER Conference Presentation: Pacific Northwest National Laboratory PDF icon 2002_deer_muntean.pdf More Documents & Publications The State of the Science in Diesel Particulate Control fundamental Modeling and Experimental

  11. Vehicle Technologies Office Merit Review 2015: Particulate Emissions Control by Advanced Filtration Systems for GDI Engines

    Broader source: Energy.gov [DOE]

    Presentation given by Argonne National Laboratory at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about particulate...

  12. Development of a Sub-Grid Model of a Diesel Particulate Filter...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of the lattice-Boltzmann technique Development of a Sub-Grid Model of a Diesel Particulate Filter: application of the lattice-Boltzmann technique 2002 DEER Conference ...

  13. Vehicle Technologies Office Merit Review 2014: Particulate Emissions Control by Advanced Filtration Systems for GDI Engines

    Broader source: Energy.gov [DOE]

    Presentation given by Argonne National Laboratory at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about particulate...

  14. Measuring PM Distribution in a Catalyzed Particulate Filter using a Terahertz Wave Scanner

    Broader source: Energy.gov [DOE]

    Terahertz scanning system produced 3-dimensional image of local PM density in catatalyzed particulate filters tested under loading and oxidizing conditions

  15. Advanced hybrid particulate collector and method of operation

    DOE Patents [OSTI]

    Miller, S.J.

    1999-08-17

    A device and method for controlling particulate air pollutants of the present invention combines filtration and electrostatic collection devices. The invention includes a chamber housing a plurality of rows of filter elements. Between each row of filter elements is a grounded plate. Between the grounded plates and the filter elements are electrode grids for creating electrostatic precipitation zones between each row of filter elements. In this way, when the filter elements are cleaned by pulsing air in a reverse direction, the dust removed from the bags will collect in the electrostatic precipitation zones rather than on adjacent filter elements. 12 figs.

  16. Controlled laser production of elongated articles from particulates

    DOE Patents [OSTI]

    Dixon, Raymond D. (Los Alamos, NM); Lewis, Gary K. (Los Alamos, NM); Milewski, John O. (Santa Fe, NM)

    2002-01-01

    It has been discovered that wires and small diameter rods can be produced using laser deposition technology in a novel way. An elongated article such as a wire or rod is constructed by melting and depositing particulate material into a deposition zone which has been designed to yield the desired article shape and dimensions. The article is withdrawn from the deposition zone as it is formed, thus enabling formation of the article in a continuous process. Alternatively, the deposition zone is moved along any of numerous deposition paths away from the article being formed.

  17. Advanced hybrid particulate collector and method of operation

    DOE Patents [OSTI]

    Miller, Stanley J. (Grand Forks, ND)

    1999-01-01

    A device and method for controlling particulate air pollutants of the present invention combines filtration and electrostatic collection devices. The invention includes a chamber housing a plurality of rows of filter elements. Between each row of filter elements is a grounded plate. Between the grounded plates and the filter elements are electrode grids for creating electrostatic precipitation zones between each row of filter elements. In this way, when the filter elements are cleaned by pulsing air in a reverse direction, the dust removed from the bags will collect in the electrostatic precipitation zones rather than on adjacent filter elements.

  18. Prospecting by sampling and analysis of airborne particulates and gases

    DOE Patents [OSTI]

    Sehmel, G.A.

    1984-05-01

    A method is claimed for prospecting by sampling airborne particulates or gases at a ground position and recording wind direction values at the time of sampling. The samples are subsequently analyzed to determine the concentrations of a desired material or the ratios of the desired material to other identifiable materials in the collected samples. By comparing the measured concentrations or ratios to expected background data in the vicinity sampled, one can select recorded wind directions indicative of the upwind position of the land-based source of the desired material.

  19. Discrete dark matter

    SciTech Connect (OSTI)

    Hirsch, M.; Morisi, S.; Peinado, E.; Valle, J. W. F. [AHEP Group, Institut de Fisica Corpuscular--C.S.I.C./Universitat de Valencia, Edificio Institutos de Paterna, Apartado 22085, E-46071 Valencia (Spain)

    2010-12-01

    We propose a new motivation for the stability of dark matter (DM). We suggest that the same non-Abelian discrete flavor symmetry which accounts for the observed pattern of neutrino oscillations, spontaneously breaks to a Z{sub 2} subgroup which renders DM stable. The simplest scheme leads to a scalar doublet DM potentially detectable in nuclear recoil experiments, inverse neutrino mass hierarchy, hence a neutrinoless double beta decay rate accessible to upcoming searches, while {theta}{sub 13}=0 gives no CP violation in neutrino oscillations.

  20. Heterologous production of an energy-conserving carbon monoxide dehydrogenase complex in the hyperthermophile Pyrococcus furiosus

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Schut, Gerrit J.; Lipscomb, Gina L.; Nguyen, Diep M. N.; Kelly, Robert M.; Adams, Michael W. W.

    2016-01-29

    In this study, carbon monoxide (CO) is an important intermediate in anaerobic carbon fixation pathways in acetogenesis and methanogenesis. In addition, some anaerobes can utilize CO as an energy source. In the hyperthermophilic archaeon Thermococcus onnurineus, which grows optimally at 80°C, CO oxidation and energy conservation is accomplished by a respiratory complex encoded by a 16-gene cluster containing a CO dehydrogenase, a membrane-bound [NiFe]-hydrogenase and a Na+/H+ antiporter module. This complex oxidizes CO, evolves CO2 and H2, and generates a Na+ motive force that is used to conserve energy by a Na+-dependent ATP synthase. Herein we used a bacterial artificialmore » chromosome to insert the 13.2 kb gene cluster encoding the CO-oxidizing respiratory complex of T. onnurineus into the genome of the heterotrophic archaeon, Pyrococcus furiosus, which grows optimally at 100° C. P. furiosus is normally unable to utilize CO, however, the recombinant strain readily oxidized CO and generated H2 at 80° C. Moreover, CO also served as an energy source and allowed the P. furiosus strain to grow with a limiting concentration of sugar or with peptides as the carbon source. Moreover, CO oxidation by P. furiosus was also coupled to the re-utilization, presumably for biosynthesis, of acetate generated by fermentation. The functional transfer of CO utilization between Thermococcus and Pyrococcus species demonstrated herein is representative of the horizontal gene transfer of an environmentally relevant metabolic capability. The transfer of CO utilizing, hydrogen-producing genetic modules also has applications for biohydrogen production and a CO-based industrial platform for various thermophilic organisms.« less

  1. Reaction of uranium oxides with chlorine and carbon or carbon monoxide to prepare uranium chlorides

    SciTech Connect (OSTI)

    Haas, P.A.; Lee, D.D.; Mailen, J.C.

    1991-11-01

    The preferred preparation concept of uranium metal for feed to an AVLIS uranium enrichment process requires preparation of uranium tetrachloride (UCI{sub 4}) by reacting uranium oxides (UO{sub 2}/UO{sub 3}) and chlorine (Cl{sub 2}) in a molten chloride salt medium. UO{sub 2} is a very stable metal oxide; thus, the chemical conversion requires both a chlorinating agent and a reducing agent that gives an oxide product which is much more stable than the corresponding chloride. Experimental studies in a quartz reactor of 4-cm ID have demonstrated the practically of some chemical flow sheets. Experimentation has illustrated a sequence of results concerning the chemical flow sheets. Tests with a graphite block at 850{degrees}C demonstrated rapid reactions of Cl{sub 2} and evolution of carbon dioxide (CO{sub 2}) as a product. Use of carbon monoxide (CO) as the reducing agent also gave rapid reactions of Cl{sub 2} and formation of CO{sub 2} at lower temperatures, but the reduction reactions were slower than the chlorinations. Carbon powder in the molten salt melt gave higher rates of reduction and better steady state utilization of Cl{sub 2}. Addition of UO{sub 2} feed while chlorination was in progress greatly improved the operation by avoiding the plugging effects from high UO{sub 2} concentrations and the poor Cl{sub 2} utilizations from low UO{sub 2} concentrations. An UO{sub 3} feed gave undesirable effects while a feed of UO{sub 2}-C spheres was excellent. The UO{sub 2}-C spheres also gave good rates of reaction as a fixed bed without any molten chloride salt. Results with a larger reactor and a bottom condenser for volatilized uranium show collection of condensed uranium chlorides as a loose powder and chlorine utilizations of 95--98% at high feed rates. 14 refs., 7 figs., 14 tabs.

  2. Cooler and particulate separator for an off-gas stack

    DOE Patents [OSTI]

    Wright, George T. (15 Cherry Hills Dr., Aiken, SC 29803)

    1992-01-01

    An off-gas stack for a melter comprising an air conduit leading to two sets of holes, one set injecting air into the off-gas stack near the melter plenum and the second set injecting air downstream of the first set. The first set injects air at a compound angle, having both downward and tangential components, to create a reverse vortex flow, counter to the direction of flow of gas through the stack and also along the periphery of the stack interior surface. Air from the first set of holes pervents recirculation zones from forming and the attendant accumulation of particulate deposits on the wall of the stack and will also return to the plenum any particulate swept up in the gas entering the stack. The second set of holes injects air in the same direction as the gas in the stack to compensate for the pressure drop and to prevent the concentration of condensate in the stack. A set of sprayers, receiving water from a second conduit, is located downstream of the second set of holes and sprays water into the gas to further cool it.

  3. Cooler and particulate separator for an off-gas stack

    DOE Patents [OSTI]

    Wright, G.T.

    1991-04-08

    This report describes an off-gas stack for a melter, furnace or reaction vessel comprising an air conduit leading to two sets of holes, one set injecting air into the off-gas stack near the melter plenum and the second set injecting air downstream of the first set. The first set injects air at a compound angle, having both downward and tangential components, to create a reverse vortex flow, counter to the direction of flow of gas through the stack and also along the periphery of the stack interior surface. Air from the first set of holes prevents recirculation zones from forming and the attendant accumulation of particulate deposits on the wall of the stack and will also return to the plenum any particulate swept up in the gas entering the stack. The second set of holes injects air in the same direction as the gas in the stack to compensate for the pressure drop and to prevent the concentration of condensate in the stack. A set of sprayers, receiving water from a second conduit, is located downstream of the second set of holes and sprays water into the gas to further cool it.

  4. Decoding dark matter in genes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Decoding dark matter in genes Decoding dark matter in genes Possible future applications, for example, include making new cancer therapies based on how ribosomes differentiate in healthy versus cancerous tissue. February 19, 2016 Decoding dark matter in genes In 1994, researchers from Harvard and Stanford published a paper in which they described three mice: one was yellow and fat, one mottled and fat, and the last one was brown and lean. An ordinary image, except for one thing: despite being so

  5. Resistive heater geometry and regeneration method for a diesel particulate filter

    DOE Patents [OSTI]

    Phelps, Amanda; Kirby, Kevin W.; Gregoir, Daniel J.

    2011-10-25

    One embodiment of the invention includes a diesel particulate filter comprising a first face and a second face; a bottom electrode layer formed over the first face of the diesel particulate filter; a middle resistive layer formed over a portion of the bottom electrode layer; and a top electrode layer formed over a portion of the middle resistive layer.

  6. Solving the Dark Matter Problem

    ScienceCinema (OSTI)

    Baltz, Ted

    2009-09-01

    Cosmological observations have firmly established that the majority of matter in the universe is of an unknown type, called 'dark matter'. A compelling hypothesis is that the dark matter consists of weakly interacting massive particles (WIMPs) in the mass range around 100 GeV. If the WIMP hypothesis is correct, such particles could be created and studied at accelerators. Furthermore they could be directly detected as the primary component of our galaxy. Solving the dark matter problem requires that the connection be made between the two. We describe some theoretical and experimental avenues that might lead to this connection.

  7. Geometry Matters | The Ames Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Geometry Matters Researchers have discovered how the geometry of gold nanoparticles affects their images. Gold nanoparticles can be imaged optically and their movements can be seen...

  8. Alternatives to conventional diesel fuel-some potential implications of California's TAC decision on diesel particulate.

    SciTech Connect (OSTI)

    Eberhardt, J. J.; Rote, D. M.; Saricks, C. L.; Stodolsky, F.

    1999-08-10

    Limitations on the use of petroleum-based diesel fuel in California could occur pursuant to the 1998 declaration by California's Air Resources Board (CARB) that the particulate matter component of diesel exhaust is a carcinogen, therefore a toxic air contaminant (TAC) subject to provisions of the state's Proposition 65. It is the declared intention of CARB not to ban or restrict diesel fuel, per se, at this time. Assuming no total ban, Argonne National Laboratory (ANL) explored two feasible ''mid-course'' strategies. (1) Increased penetration of natural gas and greater gasoline use in the transportation fuels market, to the extent that some compression-ignition (CI) applications revert to spark-ignition (SI) engines. (2) New specifications requiring diesel fuel reformulation based on exhaust products of individual diesel fuel constituents. Each of these alternatives results in some degree of (conventional) diesel displacement. In the first case, diesel fuel is assumed admissible for ignition assistance as a pilot fuel in natural gas (NG)-powered heavy-duty vehicles, and gasoline demand in California increases by 32.2 million liters per day overall, about 21 percent above projected 2010 baseline demand. Natural gas demand increases by 13.6 million diesel liter equivalents per day, about 7 percent above projected (total) consumption level. In the second case, compression-ignition engines utilize substitutes for petroleum-based diesel having similar ignition and performance properties. For each case we estimated localized air emission plus generalized greenhouse gas and energy changes. Economic implications of vehicle and engine replacement were not evaluated.

  9. Composition and chemistry of particulates from the Tidd Clean Coal Demonstration Plant pressurized fluidized bed combustor, cyclone, and filter vessel

    SciTech Connect (OSTI)

    Smith, D.H.; Grimm, U.; Haddad, G.

    1995-12-31

    In a Pressurized Fluidized Bed Combustion (PFBC)/cyclone/filter system ground coal and sorbent are injected as pastes into the PFBC bed; the hot gases and entrained fine particles of ash and calcined or reacted sorbent are passed through a cyclone (which removes the larger entrained particles); and the very-fine particles that remain are then filtered out, so that the cleaned hot gas can be sent through a non-ruggedized hot-gas turbine. The 70 MWe Tidd PFBC Demonstration Plant in Brilliant, Ohio was completed in late 1990. The initial design utilized seven strings of primary and secondary cyclones to remove 98% of the particulate matter. However, the Plant also included a pressurized filter vessel, placed between the primary and secondary cyclones of one of the seven strings. Coal and dolomitic limestone (i.e, SO{sub 2} sorbent) of various nominal sizes ranging from 12 to 18 mesh were injected into the combustor operating at about 10 atm pressure and 925{degree}C. The cyclone removed elutriated particles larger than about 0.025 mm, and particles larger than ca. 0.0005 mm were filtered at about 750{degree}C by ceramic candle filters. Thus, the chemical reaction times and temperatures, masses of material, particle-size distributions, and chemical compositions were substantially different for particulates removed from the bed drain, the cyclone drain, and the filter unit. Accordingly, we have measured the particle-size distributions and concentrations of calcium, magnesium, sulfur, silicon, and aluminum for material taken from the three units, and also determined the chemical formulas and predominant crystalline forms of the calcium and magnesium sulfate compounds formed. The latter information is particularly novel for the filter-cake material, from which we isolated the ``new`` compound Mg{sub 2}Ca(SO{sub 4}){sub 3}.

  10. Final report for "Characterization of Fine Particulate Matter (PM) and secondary PM Precursor Gases in the Mexico City Metropolitan Area"

    SciTech Connect (OSTI)

    Prof. Jose-Luis Jimenez

    2009-05-18

    The objectives of this funded project were (a) to further analyze the data collected by our group and collaborators in Mexico City during the MCMA-2003 field campaign, with the goal of further our understanding of aerosol sources and processes; and (b) to deploy several advanced instruments, including the newly developed high-resolution time-of-flight aerosol mass spectrometer (HR-ToF-AMS) and thermal-denuder (TD), during the MILAGRO/MAX-Mex/MCMA-2006 field campaign, and to analyze those data (together with the 2003 data) to provide additional insights on the formation and transformation of aerosols in the Mexico City area. These goals were addressed in collaboration with our project partners, MIT/Molina Center, and Aerodyne Research. Overall this project was very successful, resulting on 22+ journal papers including six highly cited papers and three papers that are the most cited in their respective journals (out of several thousand papers) since the year in which they were published. Multiple discoveries, such as the the underestimation of SOA in urban areas even for short photochemical ages, the demonstration that urban POA is of similar or higher volatility than urban SOA, and the first analysis of organic aerosol elemental composition in real-time have been recently published. Several dozen presentations at major US and international conferences and seminars also acknowledged this grant.

  11. Effects of fine particulate matter and its constituents on low birth weight among full-term infants in California

    SciTech Connect (OSTI)

    Basu, Rupa; Harris, Maria; Sie, Lillian; Malig, Brian; Broadwin, Rachel; Green, Rochelle

    2014-01-15

    Relationships between prenatal exposure to fine particles (PM{sub 2.5}) and birth weight have been observed previously. Few studies have investigated specific constituents of PM{sub 2.5}, which may identify sources and major contributors of risk. We examined the effects of trimester and full gestational prenatal exposures to PM{sub 2.5} mass and 23 PM{sub 2.5} constituents on birth weight among 646,296 term births in California between 2000 and 2006. We used linear and logistic regression models to assess associations between exposures and birth weight and risk of low birth weight (LBW; <2500 g), respectively. Models were adjusted for individual demographic characteristics, apparent temperature, month and year of birth, region, and socioeconomic indicators. Higher full gestational exposures to PM{sub 2.5} mass and several PM{sub 2.5} constituents were significantly associated with reductions in term birth weight. The largest reductions in birth weight were associated with exposure to vanadium, sulfur, sulfate, iron, elemental carbon, titanium, manganese, bromine, ammonium, zinc, and copper. Several of these PM{sub 2.5} constituents were associated with increased risk of term LBW. Reductions in birth weight were generally larger among younger mothers and varied by race/ethnicity. Exposure to specific constituents of PM{sub 2.5}, especially traffic-related particles, sulfur constituents, and metals, were associated with decreased birth weight in California. -- Highlights: Examine full gestational and trimester fine particle and its constituents on term birth weight. Fine particles and several of its constituents associated with birth weight reductions. Largest reductions for traffic-related particles, sulfur constituents, and metals. Greater birth weight reductions for younger mothers, and varied by race/ethnicity.

  12. Development and Demonstration of an Electronic Particulate Matter Sensor for Both Engine-Out and Post-DPF Exhaust Monitoring

    Broader source: Energy.gov [DOE]

    Demanding emission legislation has created a need for low-cost, sensitive, accurate, and robust PM sensors for OBD

  13. Superconducting magnetic control system for manipulation of particulate matter and magnetic probes in medical and industrial applications

    DOE Patents [OSTI]

    Cha, Yung Sheng; Hull, John R.; Askew, Thomas R.

    2006-07-11

    A system and method of controlling movement of magnetic material with at least first and second high temperature superconductors at spaced locations. A plurality of solenoids are associated with the superconductors to induce a persistent currents in preselected high temperature superconductors establishing a plurality of magnetic fields in response to pulsed currents introduced to one or more of the solenoids. Control mechanism in communication with said solenoids and/or said high temperature superconductors are used to demagnetize selected ones of the high temperature superconductors to reduce the magnetic fields substantially to zero. Magnetic material is moved between magnetic fields by establishing the presence thereof and thereafter reducing magnetic fields substantially to zero and establishing magnetic fields in other superconductors arranged in a predetermined configuration.

  14. DEVELOPMENT OF FINE PARTICULATE EMISSION FACTORS AND SPECIATION PROFILES FOR OIL AND GAS-FIRED COMBUSTION SYSTEMS

    SciTech Connect (OSTI)

    Glenn C. England

    2004-10-20

    In 1997, the United States Environmental Protection Agency (EPA) promulgated new National Ambient Air Quality Standards (NAAQS) for particulate matter, including for the first time particles with aerodynamic diameter smaller than 2.5 micrometers ({micro}m) referred to as PM2.5. PM2.5 in the atmosphere also contributes to reduced atmospheric visibility, which is the subject of existing rules for siting emission sources near Class 1 areas and new Regional Haze rules. There are few existing data regarding emissions and characteristics of fine aerosols from oil, gas and power generation industry combustion sources, and the information that is available is generally outdated and incomplete. Traditional stationary source air emission sampling methods tend to underestimate or overestimate the contribution of the source to ambient aerosols because they do not properly account for primary aerosol formation, which occurs after the gases leave the stack. Primary aerosol includes both filterable particles that are solid or liquid aerosols at stack temperature plus those that form as the stack gases cool through mixing and dilution processes in the plume downwind of the source. These deficiencies in the current methods can have significant impacts on regulatory decision-making. PM2.5 measurement issues were extensively reviewed by the American Petroleum Institute (API) (England et al., 1998), and it was concluded that dilution sampling techniques are more appropriate for obtaining a representative particulate matter sample from combustion systems for determining PM2.5 emission rate and chemical speciation. Dilution sampling is intended to collect aerosols including those that condense and/or react to form solid or liquid aerosols as the exhaust plume mixes and cools to near-ambient temperature immediately after the stack discharge. These techniques have been widely used in recent research studies. For example, Hildemann et al. (1994) and McDonald et al. (1998) used filtered ambient air to dilute the stack gas sample followed by 80-90 seconds residence time to allow aerosol formation and growth to stabilize prior to sample collection and analysis. More accurate and complete emissions data generated using the methods developed in this program will enable more accurate source-receptor and source apportionment analysis for PM2.5 National Ambient Air Quality Standards (NAAQS) implementation and streamline the environmental assessment of oil, gas and power production facilities. The overall goals of this program were to: (1) Develop improved dilution sampling technology and test methods for PM2.5 mass emissions and speciation measurements, and compare results obtained with dilution and traditional stationary source sampling methods. (2) Develop emission factors and speciation profiles for emissions of fine particulate matter, especially organic aerosols, for use in source-receptor and source apportionment analyses. (3) Identify and characterize PM2.5 precursor compound emissions that can be used in source-receptor and source apportionment analyses.

  15. Internal energy and parameters of the order-disorder phase transition in titanium monoxide TiO{sub y}

    SciTech Connect (OSTI)

    Kostenko, M. G.; Rempel, A. A.; Lukoyanov, A. V.

    2013-06-15

    Quantum-mechanical ab initio calculations are used to simulate the free energy functions for titanium monoxide TiO{sub y}. The effect of the long-range order of the Ti{sub 5}O{sub 5} type superstructure on the internal energy of the compound is studied by the supercell method. The dependences of the configuration entropy and free energy on the long-range order parameter are determined. It is found that the order-disorder phase transition in titanium monoxide must occur in accordance with the mechanism of the first-order phase transition with a critical value of the long-range order parameter of 0.971. The calculated parameters of the phase transition are compared with the experimental data and the results obtained using the model of point charges and by calculating the Madelung energy. It is concluded that the short-range order and the phonon entropy must be taken into account in calculating the equilibrium phase diagrams for strongly nonstoichiometric compounds.

  16. Nuclear-matter--quark-matter phase diagram with strangeness

    SciTech Connect (OSTI)

    Barz, H. W.; Friman, B. L.; Knoll, J.; Schulz, H.

    1989-07-01

    A phenomenological equation of state of strongly interacting matter, including strange degrees of freedom, is presented. It is shown that the hyperon and kaon interactions must be included, in order to obtain a reasonable description of the deconfinement transition at high baryon densities. The consequences of kaon condensation on the nuclear-matter--quark-matter phase diagram are explored. The relative particle abundances obtained in an isentropic expansion of a blob of quark-gluon plasma are presented for different initial conditions. Implications for ultrarelativistic heavy-ion collisions are briefly discussed.

  17. Probing gravitational dark matter

    SciTech Connect (OSTI)

    Ren, Jing; He, Hong-Jian

    2015-03-27

    So far all evidences of dark matter (DM) come from astrophysical and cosmological observations, due to the gravitational interactions of DM. It is possible that the true DM particle in the universe joins gravitational interactions only, but nothing else. Such a Gravitational DM (GDM) may act as a weakly interacting massive particle (WIMP), which is conceptually simple and attractive. In this work, we explore this direction by constructing the simplest scalar GDM particle χ{sub s}. It is a ℤ{sub 2} odd singlet under the standard model (SM) gauge group, and naturally joins the unique dimension-4 interaction with Ricci curvature, ξ{sub s}χ{sub s}{sup 2}R, where ξ{sub s} is the dimensionless nonminimal coupling. We demonstrate that this gravitational interaction ξ{sub s}χ{sub s}{sup 2}R, together with Higgs-curvature nonminimal coupling term ξ{sub h}H{sup †}HR, induces effective couplings between χ{sub s}{sup 2} and SM fields, and can account for the observed DM thermal relic abundance. We analyze the annihilation cross sections of GDM particles and derive the viable parameter space for realizing the DM thermal relic density. We further study the direct/indirect detections and the collider signatures of such a scalar GDM. These turn out to be highly predictive and testable.

  18. Engine-External HC-Dosing for Regeneration of Diesel Particulate Filters

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    for Heavy Duty and NRMM According to Annex XXVII StVZO | Department of Energy Engine-External HC-Dosing for Regeneration of Diesel Particulate Filters for Heavy Duty and NRMM According to Annex XXVII StVZO Engine-External HC-Dosing for Regeneration of Diesel Particulate Filters for Heavy Duty and NRMM According to Annex XXVII StVZO This presentation discusses how a diesel particulate filter can be integrated in the exhaust piping of a heavy-duty engine. PDF icon deer08_rembor.pdf More

  19. MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; SOLID STATE...

    Office of Scientific and Technical Information (OSTI)

    Open problems in condensed matter physics, 1987 Falicov, L.M. 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; SOLID STATE PHYSICS; RESEARCH PROGRAMS;...

  20. Energy Matters LLC | Open Energy Information

    Open Energy Info (EERE)

    Name: Energy Matters LLC Place: Santa Rosa, California Zip: 95402 Sector: Renewable Energy Product: Energy Matters specialises in software tools for the renewable energy...

  1. Physics of Condensed Matter and Complex Systems

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    4 Physics of Condensed Matter and Complex Systems A tradition of international leadership ... Basic and applied research in condensed matter, statistical and quantum physics The ...

  2. Particulate, colloidal, and solution phase associations of plutonium, americium, and uranium in surface and groundwater at the Rocky Flats Plant, Colorado

    SciTech Connect (OSTI)

    Harnish, R.A.; McKnight, D.M.; Ranville, J.F.; Stephens, V.C.; Honeyman, B.D.

    1993-12-31

    With the cessation of plutonium processing at the D.O.E.-administered Rocky Flats Plant near Denver, CO, the focus of activities at the facility has switched to contaminant assessment and potential remediation strategies. In this context the authors began a study in 1991 to determine the potential for colloid-facilitated transport of the actinides Pu, Am, and in surface- and groundwater at this site. Using the technique of tangential flow ultrafiltration, the authors isolated particles from four size fractions at one groundwater well and two surface water seeps to determine the distribution of Pu, Am, and U among particulate, colloidal, and dissolved aqueous phases. Analysis of particle isolates and filtrate fractions showed significant associations of Am and Pu with colloidal and particulate size particles; uranium isotopes were associated mainly with low molecular weight organic species. The results indicate a potential for colloidal-facilitated transport of the actinides Pu and Am and a significant contribution by low molecular weight natural organic matter to uranium transport.

  3. Process for the production of hydrogen and carbonyl sulfide from hydrogen sulfide and carbon monoxide using a metal boride, nitride, carbide and/or silicide catalyst

    SciTech Connect (OSTI)

    McGuiggan, M.F.; Kuch, P.L.

    1984-05-08

    Hydrogen and carbonyl sulfide are produced by a process comprising contacting gaseous hydrogen sulfide with gaseous carbon monoxide in the presence of a metal boride, carbide, nitride and/or silicide catalyst, such as titanium carbide, vanadium boride, manganese nitride or molybdenum silicide.

  4. Physical Protection of Classified Matter

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    1988-02-03

    The order establishes policy and objectives for physical protection of classified matter. This directive does not cancel another directive. Chg 1, 7-30-93. Canceled by 5632.1C.

  5. Integrated coherent matter wave circuits

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ryu, C.; Boshier, M. G.

    2015-09-21

    An integrated coherent matter wave circuit is a single device, analogous to an integrated optical circuit, in which coherent de Broglie waves are created and then launched into waveguides where they can be switched, divided, recombined, and detected as they propagate. Applications of such circuits include guided atom interferometers, atomtronic circuits, and precisely controlled delivery of atoms. We report experiments demonstrating integrated circuits for guided coherent matter waves. The circuit elements are created with the painted potential technique, a form of time-averaged optical dipole potential in which a rapidly moving, tightly focused laser beam exerts forces on atoms through theirmoreelectric polarizability. Moreover, the source of coherent matter waves is a BoseEinstein condensate (BEC). Finally, we launch BECs into painted waveguides that guide them around bends and form switches, phase coherent beamsplitters, and closed circuits. These are the basic elements that are needed to engineer arbitrarily complex matter wave circuitry.less

  6. Energy Matters: Our Energy Independence

    Broader source: Energy.gov [DOE]

    In this installment of the livechat series "Energy Matters," Dr. Arun Majumdar takes questions from the public about the investments we're making today that will move us off of foreign oil and...

  7. Strongly interacting parton matter equilibration

    SciTech Connect (OSTI)

    Ozvenchuk, V.; Linnyk, O.; Bratkovskaya, E.; Gorenstein, M.; Cassing, W.

    2012-07-15

    We study the kinetic and chemical equilibration in 'infinite' parton matter within the Parton-Hadron-String Dynamics transport approach. The 'infinite' matter is simulated within a cubic box with periodic boundary conditions initialized at different energy densities. Particle abundances, kinetic energy distributions, and the detailed balance of the off-shell quarks and gluons in the strongly-interacting quarkgluon plasma are addressed and discussed.

  8. Relativistic Laser-Matter Interactions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Relativistic Laser-Matter Interactions Relativistic Laser-Matter Interactions Enabling the next generation of intense particle accelerators Contact Juan Fernandez (505) 667-6575 Email Short-pulse ion acceleration The Trident facility is a world-class performer in the area of ion acceleration from laser-solid target interactions. Trident has demonstrated over 100 MeV protons at intensities of 8x1020 W/cm2 with efficiencies approaching 5%. These intense relativistic interactions can be diagnosed

  9. Condensed Matter and Magnet Science

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CMMS Condensed Matter and Magnet Science The group has a distinguished history of applying cutting-edge condensed matter physics research and high magnetic field science to mission-relevant materials challenges as well as fundamental investigations of emergent physical phenomena. Contact Us Group Leader (acting) Chuck Mielke Email Deputy Group Leader (acting) Leonardo Civale Email Deputy Group Leader (acting) Ross McDonald Email NHMFL-PFF Director Chuck Mielke Email Deputy NHMFL-PFF Director

  10. Energy Matters | Department of Energy

    Office of Environmental Management (EM)

    Matters Energy Matters July 25, 2011 - 1:04pm Addthis On Wednesday, January 26th, Secretary Chu held an online town hall to discuss President Obama's clean energy and innovation agenda. Read a recap and watch video from the full event here. Addthis Related Articles WEDNESDAY: Secretary Chu to Host Live Chat on Clean Energy and Innovation Vice President Biden Kicks Off Five Days of Earth Day Activities with Announcement of Major New Energy Efficiency Effort Energy Secretary Steven Chu to Travel

  11. Engine-External HC-Dosing for Regeneration of Diesel Particulate...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Filters for Heavy Duty and NRMM According to Annex XXVII StVZO Engine-External HC-Dosing for Regeneration of Diesel Particulate Filters for Heavy Duty and NRMM According to ...

  12. Optical backscatter probe for sensing particulate in a combustion gas stream

    DOE Patents [OSTI]

    Parks, James E; Partridge, William P

    2013-05-28

    A system for sensing particulate in a combustion gas stream is disclosed. The system transmits light into a combustion gas stream, and thereafter detects a portion of the transmitted light as scattered light in an amount corresponding to the amount of particulates in the emissions. Purge gas may be supplied adjacent the light supply and the detector to reduce particles in the emissions from coating or otherwise compromising the transmission of light into the emissions and recovery of scattered light from the emissions.

  13. Imaging of Diesel Particulate Filters using a High-Flux Neutron Source |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Imaging of Diesel Particulate Filters using a High-Flux Neutron Source Imaging of Diesel Particulate Filters using a High-Flux Neutron Source Detailed images of deposits identified inside automotive DPFs using neutrons show how the deposits of soot, ash, and washcoat occurs within the filter. PDF icon p-14_toops.pdf More Documents & Publications Neutron Imaging of Advanced Engine Technologies Neutron Imaging of Advanced Engine Technologies Non-Destructive Neutron

  14. Evaluation of Passive and Active Soot Filters for Removal of Particulate

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Emissions from Diesel Engines | Department of Energy Passive and Active Soot Filters for Removal of Particulate Emissions from Diesel Engines Evaluation of Passive and Active Soot Filters for Removal of Particulate Emissions from Diesel Engines 2002 DEER Conference Presentation: Cummins, Inc. PDF icon 2002_deer_bunting.pdf More Documents & Publications Exhaust Aftertreatment and Low Pressure Loop EGR Applied to an Off-Highway Engine Active Soot Filter Regeneration Development and Field

  15. Development of SCR on Diesel Particulate Filter System for Heavy Duty

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Applications | Department of Energy SCR on Diesel Particulate Filter System for Heavy Duty Applications Development of SCR on Diesel Particulate Filter System for Heavy Duty Applications Evaluation of a system consisting of SCRDPF in comparison to a commercial 2010 CDPF system on an engine under high and low engine-out NOx conditions PDF icon deer12_naseri.pdf More Documents & Publications Investigation on continuous soot oxidation and NOx reduction by SCR coated DPF SCR-DPF Integrations

  16. Development of an Accelerated Ash-Loading Protocol for Diesel Particulate

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Filters | Department of Energy an Accelerated Ash-Loading Protocol for Diesel Particulate Filters Development of an Accelerated Ash-Loading Protocol for Diesel Particulate Filters Poster presentation at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August, 2007, Detroit, Michigan. Sponsored by the U.S. Department of Energy's (DOE) Office of FreedomCAR and Vehicle Technologies (OFCVT). PDF icon deer07_bunting_2.pdf More Documents & Publications

  17. Burning Modes and Oxidation Rates of Soot: Relevance to Diesel Particulate

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Traps | Department of Energy Burning Modes and Oxidation Rates of Soot: Relevance to Diesel Particulate Traps Burning Modes and Oxidation Rates of Soot: Relevance to Diesel Particulate Traps Presentation given at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August, 2007, Detroit, Michigan. Sponsored by the U.S. Department of Energy's (DOE) Office of FreedomCAR and Vehicle Technologies (OFCVT). PDF icon deer07_vanderwal.pdf More Documents &

  18. Dark matter in 3D

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Alves, Daniele S. M.; El Hedri, Sonia; Wacker, Jay G.

    2016-03-21

    We discuss the relevance of directional detection experiments in the post-discovery era and propose a method to extract the local dark matter phase space distribution from directional data. The first feature of this method is a parameterization of the dark matter distribution function in terms of integrals of motion, which can be analytically extended to infer properties of the global distribution if certain equilibrium conditions hold. The second feature of our method is a decomposition of the distribution function in moments of a model independent basis, with minimal reliance on the ansatz for its functional form. We illustrate our methodmore » using the Via Lactea II N-body simulation as well as an analytical model for the dark matter halo. Furthermore, we conclude that O(1000) events are necessary to measure deviations from the Standard Halo Model and constrain or measure the presence of anisotropies.« less

  19. Collection efficiency of the Soot-Particle Aerosol Mass Spectrometer (SP-AMS) for internally mixed particulate black carbon

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Willis, M. D.; Lee, A. K. Y.; Onasch, T. B.; Fortner, E. C.; Williams, L. R.; Lambe, A. T.; Worsnop, D. R.; Abbatt, J. P. D.

    2014-05-26

    The soot-particle aerosol mass spectrometer (SP-AMS) uses an intra-cavity infrared laser to vaporize refractory black carbon (rBC) containing particles, making the particle beam–laser beam overlap critical in determining the collection efficiency (CE) for rBC and associated non-refractory particulate matter (NR-PM). This work evaluates the ability of the SP-AMS to quantify rBC and NR-PM mass in internally mixed particles with different thicknesses of organic coating. Using apparent relative ionization efficiencies for uncoated and thickly coated rBC particles, we report measurements of SP-AMS sensitivity to NR-PM and rBC, for Regal Black, the recommended particulate calibration material. Beam width probe (BWP) measurements aremore » used to illustrate an increase in sensitivity for highly coated particles due to narrowing of the particle beam, which enhances the CE of the SP-AMS by increasing the laser beam–particle beam overlap. Assuming complete overlap for thick coatings, we estimate CE for bare Regal Black particles of 0.6 ± 0.1, which suggests that previously measured SP-AMS sensitivities to Regal Black were underestimated by up to a factor of two. The efficacy of the BWP measurements is highlighted by studies at a busy road in downtown Toronto and at a non-roadside location, which show particle beam widths similar to, but greater than that of bare Regal Black and coated Regal Black, respectively. Further BWP measurements at field locations will help to constrain the range of CE for fresh and aged rBC-containing particles. The ability of the SP-AMS to quantitatively assess the composition of internally mixed particles is validated through measurements of laboratory-generated organic coated particles, which demonstrate that the SP-AMS can quantify rBC and NR-PM over a wide range of particle compositions and rBC core sizes.« less

  20. Collection efficiency of the soot-particle aerosol mass spectrometer (SP-AMS) for internally mixed particulate black carbon

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Willis, M. D.; Lee, A. K. Y.; Onasch, T. B.; Fortner, E. C.; Williams, L. R.; Lambe, A. T.; Worsnop, D. R.; Abbatt, J. P. D.

    2014-12-18

    The soot-particle aerosol mass spectrometer (SP-AMS) uses an intra-cavity infrared laser to vaporize refractory black carbon (rBC) containing particles, making the particle beam–laser beam overlap critical in determining the collection efficiency (CE) for rBC and associated non-refractory particulate matter (NR-PM). This work evaluates the ability of the SP-AMS to quantify rBC and NR-PM mass in internally mixed particles with different thicknesses of organic coating. Using apparent relative ionization efficiencies for uncoated and thickly coated rBC particles, we report measurements of SP-AMS sensitivity to NR-PM and rBC, for Regal Black, the recommended particulate calibration material. Beam width probe (BWP) measurements aremore » used to illustrate an increase in sensitivity for highly coated particles due to narrowing of the particle beam, which enhances the CE of the SP-AMS by increasing the laser beam–particle beam overlap. Assuming complete overlap for thick coatings, we estimate CE for bare Regal Black particles of 0.6 ± 0.1, which suggests that previously measured SP-AMS sensitivities to Regal Black were underestimated by up to a factor of 2. The efficacy of the BWP measurements is highlighted by studies at a busy road in downtown Toronto and at a non-roadside location, which show particle beam widths similar to, but greater than that of bare Regal Black and coated Regal Black, respectively. Further BWP measurements at field locations will help to constrain the range of CE for fresh and aged rBC-containing particles. The ability of the SP-AMS to quantitatively assess the composition of internally mixed particles is validated through measurements of laboratory-generated organic coated particles, which demonstrate that the SP-AMS can quantify rBC and NR-PM over a wide range of particle compositions and rBC core sizes.« less

  1. Transpiring purging access probe for particulate laden or hazardous environments

    DOE Patents [OSTI]

    VanOsdol, John G

    2013-12-03

    An access probe for remote-sensing access through a viewing port, viewing volume, and access port into a vessel. The physical boundary around the viewing volume is partially formed by a porous sleeve lying between the viewing volume and a fluid conduit. In a first mode of operation, a fluid supplied to the fluid conduit encounters the porous sleeve and flows through the porous material to maintain the viewing volume free of ash or other matter. When additional fluid force is needed to clear the viewing volume, the pressure of the fluid flow is increased sufficiently to slidably translate the porous sleeve, greatly increasing the flow into the viewing volume. The porous sleeve is returned to position by an actuating spring. The access probe thereby provides for alternate modes of operation based on the pressure of an actuating fluid.

  2. Advances in controlling particulate emissions from fossil-fired power plants

    SciTech Connect (OSTI)

    Chang, R.

    1995-12-31

    Present and possible future Federal, state, and local air pollutant emission regulations coupled with an increasingly competitive business environment and the aging of existing particulate control equipment are motivating utilities to improve particulate control system effectiveness and reduce control cost. To these ends, several cost-effective means of improving particulate control are being developed and tested. Three fossil plant retrofit technologies of note include two flue gas conditioning systems--one ``agentless`` arrangement that uses the SO{sub 2} in the flue gas as the raw material for an SO{sub 3} conditioning system, and a promising new additive that has performed well in laboratory and pilot-scale tests. A second retrofit technology supplements all or most of the existing electrostatic precipitator with a pulse-jet baghouse. A third approach described in this paper is one example of a new class of advanced filtration systems, some of which can remove NO{sub x} and particulate in the same vessel. Technologies like these will enable utilities to boost particulate removal effectiveness after switching to lower-sulfur coal for Clean Air Act compliance, minimize compliance costs, and optimally position themselves for possible further emission regulations.

  3. Plasma regenerated particulate trap and NO.sub.x reduction system

    DOE Patents [OSTI]

    Penetrante, Bernardino M. (San Ramon, CA); Vogtlin, George E. (Fremont, CA); Merritt, Bernard T. (Livermore, CA); Brusasco, Raymond M. (Livermore, CA)

    2000-01-01

    A non-catalytic two-stage process for removal of NO.sub.x and particulates from engine exhaust comprises a first stage that plasma converts NO to NO.sub.2 in the presence of O.sub.2 and hydrocarbons, and a second stage, which preferably occurs simultaneously with the first stage, that converts NO.sub.2 and carbon soot particles to respective environmentally benign gases that include N.sub.2 and CO.sub.2. By preconverting NO to NO.sub.2 in the first stage, the efficiency of the second stage for NO.sub.x reduction is enhanced while carbon soot from trapped particulates is simultaneously converted to CO.sub.2 when reacting with the NO.sub.2 (that converts to N.sub.2). For example, an internal combustion engine exhaust is connected by a pipe to a chamber where carbon-containing particulates are electrostatically trapped or filtered and a non-thermal plasma converts NO to NO.sub.2 in the presence of O.sub.2 and hydrocarbons. Volatile hydrocarbons (C.sub.x H.sub.y) from the trapped particulates are oxidized in the plasma and the remaining soot from the particulates reacts with the NO.sub.2 to convert NO.sub.2 to N.sub.2, and the soot to CO.sub.2. The nitrogen exhaust components remain in the gas phase throughout the process, with no accompanying adsorption.

  4. Wino dark matter under siege

    SciTech Connect (OSTI)

    Cohen, Timothy; Lisanti, Mariangela; Pierce, Aaron; Slatyer, Tracy R. E-mail: mlisanti@princeton.edu E-mail: tslatyer@mit.edu

    2013-10-01

    A fermion triplet of SU(2){sub L} a wino is a well-motivated dark matter candidate. This work shows that present-day wino annihilations are constrained by indirect detection experiments, with the strongest limits coming from H.E.S.S. and Fermi. The bounds on wino dark matter are presented as a function of mass for two scenarios: thermal (winos constitute a subdominant component of the dark matter for masses less than 3.1 TeV) and non-thermal (winos comprise all the dark matter). Assuming the NFW halo model, the H.E.S.S. search for gamma-ray lines excludes the 3.1 TeV thermal wino; the combined H.E.S.S. and Fermi results completely exclude the non-thermal scenario. Uncertainties in the exclusions are explored. Indirect detection may provide the only probe for models of anomaly plus gravity mediation where the wino is the lightest superpartner and scalars reside at the 100 TeV scale.

  5. Z-portal dark matter

    SciTech Connect (OSTI)

    Arcadi, Giorgio; Mambrini, Yann; Richard, Francois

    2015-03-11

    We propose to generalize the extensions of the Standard Model where the Z boson serves as a mediator between the Standard Model sector and the dark sector χ. We show that, like in the Higgs portal case, the combined constraints from the recent direct searches restrict severely the nature of the coupling of the dark matter to the Z boson and set a limit m{sub χ}≳200 GeV (except in a very narrow region around the Z-pole region). Using complementarity between spin dependent, spin independent and FERMI limits, we predict the nature of this coupling, more specifically the axial/vectorial ratio that respects a thermal dark matter coupled through a Z-portal while not being excluded by the current observations. We also show that the next generation of experiments of the type LZ or XENON1T will test Z-portal scenario for dark matter mass up to 2 TeV. The condition of a thermal dark matter naturally predicts the spin-dependent scattering cross section on the neutron to be σ{sub χn}{sup SD}≃10{sup −40} cm{sup 2}, which then becomes a clear prediction of the model and a signature testable in the near future experiments.

  6. On the formation of carbonyl sulfide in the reduction of sulfur dioxide by carbon monoxide on lanthanum oxysulfide catalyst: A study by XPS and TPR/MS

    SciTech Connect (OSTI)

    Lau, N.T.; Fang, M. [Hong Kong Univ. of Science and Technology, Clear Water Bay (Hong Kong). Applied Technology Center] [Hong Kong Univ. of Science and Technology, Clear Water Bay (Hong Kong). Applied Technology Center

    1998-10-25

    Both the X-ray photoelectron spectroscopy (XPS) and temperature-programmed reaction, coupled with mass spectrometry (TPR/MS), are used to study the formation of carbonyl sulfide in the reduction of sulfur dioxide on lanthanum oxysulfide catalyst. It was found that the lattice sulfur of the oxysulfide is released and reacts with carbon monoxide to form carbonyl sulfide when the oxysulfide is heated. The oxysulfide is postulated to form sulfur vacancies at a temperature lower than that for the formation of carbonyl sulfide and atomic sulfur is released in the process. The atomic sulfur can either enter the gas phase and leave the oxysulfide catalyst or react with carbon monoxide to form carbonyl sulfide.

  7. Impact of Biodiesel on the Oxidation Kinetics and Morphology of Diesel Particulate

    SciTech Connect (OSTI)

    Strzelec, Andrea; Toops, Todd J; Daw, C Stuart

    2011-01-01

    We compare the oxidation characteristics of four different diesel particulates generated with a modern light-duty engine. The four particulates represent engine fueling with conventional ultra-low sulfur diesel (ULSD), biodiesel, and two intermediate blends of these fuels. The comparisons discussed here are based on complementary measurements implemented in a laboratory micro-reactor, including temperature programmed desorption and oxidation, pulsed isothermal oxidation, and BET surface area. From these measurements we have derived models that are consistent with the observed oxidation reactivity differences. When accessible surface area effects are properly accounted for, the oxidation kinetics of the fixed carbon components were found to consistently exhibit an Arrhenius activation energy of 113 6 kJ/mol. Release of volatile carbon from the as-collected particulate appears to follow a temperaturedependent rate law.

  8. Apparatus for real-time airborne particulate radionuclide collection and analysis

    DOE Patents [OSTI]

    Smart, John E. (West Richland, WA); Perkins, Richard W. (Richland, WA)

    2001-01-01

    An improved apparatus for collecting and analyzing an airborne particulate radionuclide having a filter mounted in a housing, the housing having an air inlet upstream of the filter and an air outlet downstream of the filter, wherein an air stream flows therethrough. The air inlet receives the air stream, the filter collects the airborne particulate radionuclide and permits a filtered air stream to pass through the air outlet. The improvement which permits real time counting is a gamma detecting germanium diode mounted downstream of the filter in the filtered air stream. The gamma detecting germanium diode is spaced apart from a downstream side of the filter a minimum distance for a substantially maximum counting detection while permitting substantially free air flow through the filter and uniform particulate radionuclide deposition on the filter.

  9. Cold quark matter in compact stars

    SciTech Connect (OSTI)

    Franzon, B.; Fogaca, D. A.; Navarra, F. S.; Horvath, J. E.

    2013-03-25

    We used an equation of state for the cold quark matter to the study of properties of quark stars. We also discuss the absolute stability of quark matter and compute the mass-radius relation for self-bound stars.

  10. Policy Matters Ohio | Open Energy Information

    Open Energy Info (EERE)

    Matters Ohio Jump to: navigation, search Name: Policy Matters Ohio Address: 3631 Perkins Avenue - Suite 4C-East Place: Cleveland, Ohio Zip: 44114 Website: www.policymattersohio.org...

  11. Ultrafast Spectroscopy of Warm Dense Matter

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Spectroscopy of Warm Dense Matter Print Being neither solid, liquid, gas, nor plasma, warm dense matter (WDM) occupies a no man's land in the map of material phases. Its...

  12. Ultrafast Spectroscopy of Warm Dense Matter

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ultrafast Spectroscopy of Warm Dense Matter Print Being neither solid, liquid, gas, nor plasma, warm dense matter (WDM) occupies a no man's land in the map of material phases. Its...

  13. Science On Tap - Matter over. Antimatter

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Science On Tap - Matter over Antimatter Science On Tap - Matter over. Antimatter WHEN: Aug 20, 2015 5:30 PM - 7:00 PM WHERE: UnQuarked Wine Room 145 Central Park Square, Los...

  14. Method for the Removal of Ultrafine Particulates from an Aqueous Suspension

    SciTech Connect (OSTI)

    Chaiko, David J.; Kopasz, John P.; Ellison, Adam J.G.

    1999-03-05

    A method of separating ultra-fine particulate from an aqueous suspension such as a process stream or a waste stream. The method involves the addition of alkali silicate and an organic gelling agent to a volume of liquid, from the respective process or waste stream, to form a gel. The gel then undergoes syneresis to remove water and soluble salts from the gel-containing the particulate, thus, forming a silica monolith. The silica monolith is then sintered to form a hard, nonporous waste form.

  15. In Vitro Genotoxicity of Particulate and Semi-Volatile Organic Compound

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Exhaust Materails from a Set of Gasoline and a Set of Diesel Engine Vehicles Operated at 30°F | Department of Energy Particulate and Semi-Volatile Organic Compound Exhaust Materails from a Set of Gasoline and a Set of Diesel Engine Vehicles Operated at 30°F In Vitro Genotoxicity of Particulate and Semi-Volatile Organic Compound Exhaust Materails from a Set of Gasoline and a Set of Diesel Engine Vehicles Operated at 30°F 2003 DEER Conference Presentation: Centers for Disease Control and

  16. Method for the removal of ultrafine particulates from an aqueous suspension

    DOE Patents [OSTI]

    Chaiko, David J. (Naperville, IL); Kopasz, John P. (Bolingbrook, IL); Ellison, Adam J. G. (Corning, NY)

    2000-01-01

    A method of separating ultra-fine particulates from an aqueous suspension such as a process stream or a waste stream. The method involves the addition of alkali silicate and an organic gelling agent to a volume of liquid, from the respective process or waste stream, to form a gel. The gel then undergoes syneresis to remove water and soluble salts from the gel containing the particulates, thus, forming a silica monolith. The silica monolith is then sintered to form a hard, nonporous waste form.

  17. Testing an Active Diesel Particulate Filter on a 2-Cycle Marine Engine |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy an Active Diesel Particulate Filter on a 2-Cycle Marine Engine Testing an Active Diesel Particulate Filter on a 2-Cycle Marine Engine Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and Fuel Partnership and 21st Century Truck Programs. PDF icon 2006_deer_depetrillo.pdf More Documents & Publications Active Diesel Emission Control Technology for Sub-50 HP Engines with Low Exhaust Temperature Profiles

  18. The equation of state of nuclear matter

    SciTech Connect (OSTI)

    Gandolfi, Stefano; Carlson, Joseph Allen

    2015-06-30

    A brief status report of research on equation of state (EOS) of nuclear matter is provided, along with two graphs.

  19. Dark matter in a bouncing universe

    SciTech Connect (OSTI)

    Cheung, Yeuk-Kwan E.; Kang, Jin U; Li, Changhong E-mail: jin.u.kang2@gmail.com

    2014-11-01

    We investigate a new scenario of dark matter production in a bouncing universe, in which dark matter was produced completely out of equilibrium in the contracting as well as expanding phase. We explore possibilities of using dark matter as a probe of the bouncing universe, focusing on the relationship between a critical temperature of the bouncing universe and the present relic abundance of dark matter.

  20. Operations & Maintenance Best Practices Guide: Front Matter

    Broader source: Energy.gov [DOE]

    Guide describes the front matter of the Operations and Maintenance Best Practices: a Guide to Achieving Operational Efficiency.

  1. Controlling particulates, temperature, and tritium in an inert glovebox for a weapons program

    SciTech Connect (OSTI)

    Purson, J.D.; Powers, D.; Walthers, C.; Navarro, C.; Newman, E.; Romero, J.; Jenkins, R.

    1996-07-01

    A glovebox is described in which several environmental parameters are controlled and monitored. Included in these are particulate, tritium, water vapor, oxygen and temperature. The paper details the design rationale and process and describes the glovebox, presently in use for neutron generator production.

  2. Methods of hydrolyzing pretreated densified biomass particulates and systems related thereto

    DOE Patents [OSTI]

    Bals, Bryan; Teymouri, Farzaneh; Campbell, Tim; Dale, Bruce

    2015-02-03

    A method is provided in which pretreated and densified cellulosic biomass particulates can be hydrolyzed at a high solids loading rate as compared with the solids loading rate of loose hydrolysable cellulosic biomass fibers. The resulting high concentration sugar-containing stream can be easily converted to biofuels or an entire suite of other useful bioproducts.

  3. Diesel Particulate Filters and NO2 Emission Limits | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Filters and NO2 Emission Limits Diesel Particulate Filters and NO2 Emission Limits EPAs New air quality standards for NO2 will impact future DPF designs PDF icon deer09_ibrahim.pdf More Documents & Publications RYPOS - An Actively Regenerated DPF that Demonstrates Significant NO2 Reduction Emission Controls for Heavy-Duty Trucks RYPOS Trap Field Demonstrations Part 1

  4. Shape-selective catalysts for Fischer-Tropsch chemistry : iron-containing particulate catalysts. Activity report : January 1, 2001 - December 31, 2004.

    SciTech Connect (OSTI)

    Cronauer, D.; Chemical Engineering

    2006-05-12

    Argonne National Laboratory is carrying out a research program to create, prepare, and evaluate catalysts to promote Fischer-Tropsch (FT) chemistry--specifically, the reaction of hydrogen with carbon monoxide to form long-chain hydrocarbons. In addition to needing high activity, it is desirable that the catalysts have high selectivity and stability with respect to both mechanical strength and aging properties. It is desired that selectivity be directed toward producing diesel fraction components and avoiding excess yields of both light hydrocarbons and heavy waxes. The goal is to produce shape-selective catalysts that have the potential to limit the formation of longchain products and yet retain the active metal sites in a protected 'cage'. This cage also restricts their loss by attrition during use in slurry-bed reactors. The first stage of this program was to prepare and evaluate iron-containing particulate catalysts. This activity report centers upon this first stage of experimentation with particulate FT catalysts. (For reference, a second experimental stage is under way to prepare and evaluate active FT catalysts formed by atomic-layer deposition [ALD] of active components on supported membranes.) To date, experimentation has centered upon the evaluation of a sample of iron-based, spray-dried catalyst prepared by B.H. Davis of the Center of Applied Energy Research (CAER) and samples of his catalyst onto which inorganic 'shells' were deposited. The reference CAER catalyst contained a high level of dispersed fine particles, a portion of which was removed by differential settling. Reaction conditions have been established using a FT laboratory unit such that reasonable levels of CO conversion can be achieved, where therefore a valid catalyst comparison can be made. A wide range of catalytic activities was observed with SiO{sub 2}-coated FT catalysts. Two techniques were used for SiO{sub 2}coating. The first involved a caustic precipitation of SiO{sub 2} from an organo-silicate onto the CAER catalyst. The second was the acidic precipitation of an organo-silicate with aging to form fractal particles that were then deposited onto the CAER catalyst. Several resulting FT catalysts were as active as the coarse catalyst on which they were prepared. The most active ones were those with the least amount of coating, namely about 2.2 wt% SiO{sub 2}. In the case of the latter acid technique, the use of HCl and HNO{sub 3} was much more effective than that of H{sub 2}SO{sub 4}. Scanning electron microscopy (SEM) was used to observe and analyze as-received and treated FT catalysts. It was observed that (1) spherical particles of CAER FT catalyst were made up of agglomerates of particles that were, in turn, also agglomerates; (2) the spray drying process of CAER apparently concentrated the Si precursor at the surface during drying; (3) while SEM pointed out broad differences in the appearance of the prepared catalyst particles, there was little indication that the catalysts were being uniformly coated with a cage-like protective surface, with perhaps the exception of HNO{sub 3}-precipitated catalyst; and (4) there was only a limited penetration of carbon (i.e., CO) into the FT catalyst during the conditioning and FT reaction steps.

  5. Carbon monoxide alleviates ethanol-induced oxidative damage and inflammatory stress through activating p38 MAPK pathway

    SciTech Connect (OSTI)

    Li, Yanyan; Gao, Chao; Shi, Yanru; Tang, Yuhan; Liu, Liang; Xiong, Ting; Du, Min; Xing, Mingyou; Liu, Liegang; Yao, Ping

    2013-11-15

    Stress-inducible protein heme oxygenase-1(HO-1) is well-appreciative to counteract oxidative damage and inflammatory stress involving the pathogenesis of alcoholic liver diseases (ALD). The potential role and signaling pathways of HO-1 metabolite carbon monoxide (CO), however, still remained unclear. To explore the precise mechanisms, ethanol-dosed adult male Balb/c mice (5.0 g/kg.bw.) or ethanol-incubated primary rat hepatocytes (100 mmol/L) were pretreated by tricarbonyldichlororuthenium (II) dimmer (CORM-2, 8 mg/kg for mice or 20 ?mol/L for hepatocytes), as well as other pharmacological reagents. Our data showed that CO released from HO-1 induction by quercetin prevented ethanol-derived oxidative injury, which was abolished by CO scavenger hemoglobin. The protection was mimicked by CORM-2 with the attenuation of GSH depletion, SOD inactivation, MDA overproduction, and the leakage of AST, ALT or LDH in serum and culture medium induced by ethanol. Moreover, CORM-2 injection or incubation stimulated p38 phosphorylation and suppressed abnormal Tnfa and IL-6, accompanying the alleviation of redox imbalance induced by ethanol and aggravated by inflammatory factors. The protective role of CORM-2 was abolished by SB203580 (p38 inhibitor) but not by PD98059 (ERK inhibitor) or SP600125 (JNK inhibitor). Thus, HO-1 released CO prevented ethanol-elicited hepatic oxidative damage and inflammatory stress through activating p38 MAPK pathway, suggesting a potential therapeutic role of gaseous signal molecule on ALD induced by naturally occurring phytochemicals. - Highlights: CO alleviated ethanol-derived liver oxidative and inflammatory stress in mice. CO eased ethanol and inflammatory factor-induced oxidative damage in hepatocytes. The p38 MAPK is a key signaling mechanism for the protective function of CO in ALD.

  6. Dark Matter in the MSSM

    SciTech Connect (OSTI)

    Cotta, R.C.; Gainer, J.S.; Hewett, J.L.; Rizzo, T.G.; /SLAC

    2009-04-07

    We have recently examined a large number of points in the parameter space of the phenomenological MSSM, the 19-dimensional parameter space of the CP-conserving MSSM with Minimal Flavor Violation. We determined whether each of these points satisfied existing experimental and theoretical constraints. This analysis provides insight into general features of the MSSM without reference to a particular SUSY breaking scenario or any other assumptions at the GUT scale. This study opens up new possibilities for SUSY phenomenology both in colliders and in astrophysical experiments. Here we shall discuss the implications of this analysis relevant to the study of dark matter.

  7. Flavored dark matter beyond minimal flavor violation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Agrawal, Prateek; Blanke, Monika; Gemmler, Katrin

    2014-10-13

    We study the interplay of flavor and dark matter phenomenology for models of flavored dark matter interacting with quarks. We allow an arbitrary flavor structure in the coupling of dark matter with quarks. This coupling is assumed to be the only new source of violation of the Standard Model flavor symmetry extended by a U(3)x associated with the dark matter. We call this ansatz Dark Minimal Flavor Violation (DMFV) and highlight its various implications, including an unbroken discrete symmetry that can stabilize the dark matter. As an illustration we study a Dirac fermionic dark matter ? which transforms asmoretriplet under U(3)x , and is a singlet under the Standard Model. The dark matter couples to right-handed down-type quarks via a colored scalar mediator ? with a coupling ?. We identify a number of flavor-safe scenarios for the structure of ? which are beyond Minimal Flavor Violation. For dark matter and collider phenomenology we focus on the well-motivated case of b-flavored dark matter. The combined flavor and dark matter constraints on the parameter space of ? turn out to be interesting intersections of the individual ones. LHC constraints on simplified models of squarks and sbottoms can be adapted to our case, and monojet searches can be relevant if the spectrum is compressed.less

  8. Flavored dark matter beyond Minimal Flavor Violation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Agrawal, Prateek; Blanke, Monika; Gemmler, Katrin

    2014-10-13

    We study the interplay of flavor and dark matter phenomenology for models of flavored dark matter interacting with quarks. We allow an arbitrary flavor structure in the coupling of dark matter with quarks. This coupling is assumed to be the only new source of violation of the Standard Model flavor symmetry extended by a U(3) χ associated with the dark matter. We call this ansatz Dark Minimal Flavor Violation (DMFV) and highlight its various implications, including an unbroken discrete symmetry that can stabilize the dark matter. As an illustration we study a Dirac fermionic dark matter χ which transforms asmore » triplet under U(3) χ , and is a singlet under the Standard Model. The dark matter couples to right-handed down-type quarks via a colored scalar mediator Φ with a coupling λ. We identify a number of “flavor-safe” scenarios for the structure of λ which are beyond Minimal Flavor Violation. Also, for dark matter and collider phenomenology we focus on the well-motivated case of b-flavored dark matter. Furthermore, the combined flavor and dark matter constraints on the parameter space of λ turn out to be interesting intersections of the individual ones. LHC constraints on simplified models of squarks and sbottoms can be adapted to our case, and monojet searches can be relevant if the spectrum is compressed.« less

  9. Method of making polymer powders and whiskers as well as particulate products of the method and atomizing apparatus

    DOE Patents [OSTI]

    Otaigbe, Joshua U.; McAvoy, Jon M.; Anderson, Iver E.; Ting, Jason; Mi, Jia; Terpstra, Robert

    2001-01-09

    Method for making polymer particulates, such as spherical powder and whiskers, by melting a polymer material under conditions to avoid thermal degradation of the polymer material, atomizing the melt using gas jet means in a manner to form atomized droplets, and cooling the droplets to form polymer particulates, which are collected for further processing. Atomization parameters can be controlled to produce polymer particulates with controlled particle shape, particle size, and particle size distribution. For example, atomization parameters can be controlled to produce spherical polymer powders, polymer whiskers, and combinations of spherical powders and whiskers. Atomizing apparatus also is provided for atoomizing polymer and metallic materials.

  10. Process for the production of hydrogen and carbonyl sulfide from hydrogen sulfide and carbon monoxide using a multi-metal oxide/sulfide catalyst

    SciTech Connect (OSTI)

    Jevnikar, M. G.; Kuch, Ph. L.

    1985-02-19

    Hydrogen and carbonyl sulfide are produced by a process comprising contacting gaseous hydrogen sulfide with gaseous carbon monoxide in the presence of a catalytic composition containing an oxide and/or sulfide of at least one of molybdenum, tungsten, iron, chromium and vanadium in combination with at least one promoter metal, e.g. a catalyst of the formula Cs Cu /SUB 0.2/ Zn /SUB 0.5/ Mn /SUB 0.5/ Sn /SUB 2.4/ Mo O /SUB x/ S /SUB y/ .

  11. TASI 2008 Lectures on Dark Matter

    SciTech Connect (OSTI)

    Hooper, Dan; /Fermilab /Chicago U., Astron. Astrophys. Ctr.

    2009-01-01

    Based on lectures given at the 2008 Theoretical Advanced Study Institute (TASI), I review here some aspects of the phenomenology of particle dark matter, including the process of thermal freeze-out in the early universe, and the direct and indirect detection of WIMPs. I also describe some of the most popular particle candidates for dark matter and summarize the current status of the quest to discover dark matter's particle identity.

  12. Ultrafast Spectroscopy of Warm Dense Matter

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ultrafast Spectroscopy of Warm Dense Matter Ultrafast Spectroscopy of Warm Dense Matter Print Wednesday, 25 April 2012 00:00 Being neither solid, liquid, gas, nor plasma, warm dense matter (WDM) occupies a no man's land in the map of material phases. Its temperature can range between that of planetary cores (tens of thousands K) to that of stellar cores (hundreds of thousands K). Not only is it prevalent throughout the universe, it is relevant to inertial confinement fusion (ICF) and material

  13. COLLOQUIUM: Environmental Condensed Matter Physics | Princeton Plasma

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Physics Lab April 24, 2013, 4:15pm to 5:30pm Colloquia MBG Auditorium COLLOQUIUM: Environmental Condensed Matter Physics Professor Brad Marston Brown University The physics of condensed matter provides a unique perspective on materials and systems of environmental relevance. I discuss three ways in which concepts and methods of condensed matter physics bear upon the quest for a sustainable future. Electronic devices made from metal oxides may enable new approaches to renewable energy, such

  14. Pump Systems Matter Mission and Vision:

    Energy Savers [EERE]

    Pump Systems Matter Mission and Vision: Pump Systems Matter(tm) (PSM) places a primary focus on pump systems education and outreach and addresses energy savings and total cost of pump ownership. Vision: Pump Systems Matter initiative assists North American pump users gain a more competitive business advantage through strategic, broad-based energy management and pump system performance optimization. Mission: To provide the marketplace with tools and collaborative opportunities to integrate pump

  15. Dark matter annihilation or unresolved astrophysical sources...

    Office of Scientific and Technical Information (OSTI)

    origin of the cosmic gamma-ray background Citation Details In-Document Search Title: Dark matter annihilation or unresolved astrophysical sources? Anisotropy probe of the origin ...

  16. ALS Reveals New State of Matter

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    universe" of sorts. Some researchers believe that the conditions inside this new state of matter can be manipulated (for example, by bringing it into contact with a...

  17. Jelly Bean Universe (Dark Matter / Dark Energy)

    ScienceCinema (OSTI)

    Kurt Riesselmann

    2010-01-08

    Fermilab's Kurt Riesselmann explains how to make a jelly bean universe to help explain the mysteries of dark matter and dark energy.

  18. Ultrafast Spectroscopy of Warm Dense Matter

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the properties of all. In disciplines such as condensed matter or plasma physics, one force often dominates over the others, allowing smaller forces to be neglected in physical...

  19. Terra Matters PLLC | Open Energy Information

    Open Energy Info (EERE)

    to: navigation, search Name: Terra Matters, PLLC Place: Seattle, Washington Zip: 98122 Product: Boutique consultancy providing advice on sustainable design and business...

  20. Dipolar dark matter with massive bigravity

    SciTech Connect (OSTI)

    Blanchet, Luc; Heisenberg, Lavinia

    2015-12-14

    Massive gravity theories have been developed as viable IR modifications of gravity motivated by dark energy and the problem of the cosmological constant. On the other hand, modified gravity and modified dark matter theories were developed with the aim of solving the problems of standard cold dark matter at galactic scales. Here we propose to adapt the framework of ghost-free massive bigravity theories to reformulate the problem of dark matter at galactic scales. We investigate a promising alternative to dark matter called dipolar dark matter (DDM) in which two different species of dark matter are separately coupled to the two metrics of bigravity and are linked together by an internal vector field. We show that this model successfully reproduces the phenomenology of dark matter at galactic scales (i.e. MOND) as a result of a mechanism of gravitational polarisation. The model is safe in the gravitational sector, but because of the particular couplings of the matter fields and vector field to the metrics, a ghost in the decoupling limit is present in the dark matter sector. However, it might be possible to push the mass of the ghost beyond the strong coupling scale by an appropriate choice of the parameters of the model. Crucial questions to address in future work are the exact mass of the ghost, and the cosmological implications of the model.

  1. Three Ways to Bust Ghostly Dark Matter

    Broader source: Energy.gov [DOE]

    How the National Labs hunt for invisible “dark matter" on the Earth’s surface, underground and in space.

  2. Course Overview Pump Systems Matter Optimization | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Course Overview Pump Systems Matter Optimization Attendees of the "Pump Systems Optimization" one-day course will gain valuable new skills to help them improve...

  3. THE FAR-ULTRAVIOLET 'CONTINUUM' IN PROTOPLANETARY DISK SYSTEMS. II. CARBON MONOXIDE FOURTH POSITIVE EMISSION AND ABSORPTION

    SciTech Connect (OSTI)

    France, Kevin; Schindhelm, Eric; Burgh, Eric B.; Brown, Alexander; Green, James C.; Herczeg, Gregory J.; Brown, Joanna M.; Harper, Graham M.; Linsky, Jeffrey L.; Yang Hao; Abgrall, Herve; Ardila, David R.; Bergin, Edwin; Bethell, Thomas; Calvet, Nuria; Ingleby, Laura; Espaillat, Catherine; Gregory, Scott G.; Hillenbrand, Lynne A.; Hussain, Gaitee

    2011-06-10

    We exploit the high sensitivity and moderate spectral resolution of the Hubble Space Telescope Cosmic Origins Spectrograph to detect far-ultraviolet (UV) spectral features of carbon monoxide (CO) present in the inner regions of protoplanetary disks for the first time. We present spectra of the classical T Tauri stars HN Tau, RECX-11, and V4046 Sgr, representative of a range of CO radiative processes. HN Tau shows CO bands in absorption against the accretion continuum. The CO absorption most likely arises in warm inner disk gas. We measure a CO column density and rotational excitation temperature of N(CO) = (2 {+-} 1) x 10{sup 17} cm{sup -2} and T{sub rot}(CO) 500 {+-} 200 K for the absorbing gas. We also detect CO A-X band emission in RECX-11 and V4046 Sgr, excited by UV line photons, predominantly H I Ly{alpha}. All three objects show emission from CO bands at {lambda} > 1560 A, which may be excited by a combination of UV photons and collisions with non-thermal electrons. In previous observations these emission processes were not accounted for due to blending with emission from the accretion shock, collisionally excited H{sub 2}, and photo-excited H{sub 2}, all of which appeared as a 'continuum' whose components could not be separated. The CO emission spectrum is strongly dependent upon the shape of the incident stellar Ly{alpha} emission profile. We find CO parameters in the range: N(CO) {approx} 10{sup 18}-10{sup 19} cm{sup -2}, T{sub rot}(CO) {approx}> 300 K for the Ly{alpha}-pumped emission. We combine these results with recent work on photo-excited and collisionally excited H{sub 2} emission, concluding that the observations of UV-emitting CO and H{sub 2} are consistent with a common spatial origin. We suggest that the CO/H{sub 2} ratio ({identical_to} N(CO)/N(H{sub 2})) in the inner disk is {approx}1, a transition between the much lower interstellar value and the higher value observed in solar system comets today, a result that will require future observational and theoretical study to confirm.

  4. Vehicle Emission Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Emission Basics Vehicle Emission Basics November 22, 2013 - 2:07pm Addthis Vehicle emissions are the gases emitted by the tailpipes of internal combustion engine vehicles. These vehicles can run on gasoline, diesel, natural gas, or propane. Vehicle emissions are composed of varying amounts of: water vapor carbon dioxide (CO2) nitrogen oxygen pollutants such as: carbon monoxide (CO) nitrogen oxides (NOx) unburned hydrocarbons (UHCs) volatile organic compounds (VOCs) particulate matter (PM) A

  5. Fogging formulations for fixation of particulate contamination in ductwork and enclosures

    DOE Patents [OSTI]

    Maresca, Jr., Joseph W.; Kostelnik, Lori M.; Kriskivich, James R.; Demmer, Rick L.; Tripp, Julia L.

    2015-09-08

    A method and an apparatus using aqueous fixatives for fogging of ventilation ductwork, enclosures, or buildings containing dust, lint, and particulates that may be contaminated by radionuclides and other dangerous or unsafe particulate contaminants, which method and apparatus are capable of (1) obtaining full coverage within the ductwork and (2) penetrating and fixing the lint, dust and large particles present in the ductwork so that no airborne particles are released during or after the application of the fixative. New aqueous fogging solutions outperform conventional glycerin-based solutions. These aqueous solutions will fog using conventional methods of application and contain a surfactant to aid wetting and penetration of the lint and dust, a binder to stabilize loose or respirable particles, and an agent to aid in fogging and enhance adhesiveness. The solutions are safe and easy to use.

  6. Apparatus and method for removing particulate deposits from high temperature filters

    DOE Patents [OSTI]

    Nakaishi, Curtis V.; Holcombe, Norman T.; Micheli, Paul L.

    1992-01-01

    A combustion of a fuel-air mixture is used to provide a high-temperature and high-pressure pulse of gaseous combustion products for the back-flush cleaning of ceramic filter elements contained in a barrier filter system and utilized to separate particulates from particulate-laden process gases at high temperature and high pressure. The volume of gaseous combustion products provided by the combustion of the fuel-air mixture is preferably divided into a plurality of streams each passing through a sonic orifice and conveyed to the open end of each filter element as a high pressure pulse which passes through the filter elements and dislodges dust cake supported on a surface of the filter element.

  7. Method of producing particulate-reinforced composites and composites produced thereby

    DOE Patents [OSTI]

    Han, Qingyou; Liu, Zhiwei

    2013-12-24

    A process for producing particle-reinforced composite materials through utilization of an in situ reaction to produce a uniform dispersion of a fine particulate reinforcement phase. The process includes forming a melt of a first material, and then introducing particles of a second material into the melt and subjecting the melt to high-intensity acoustic vibration. A chemical reaction initiates between the first and second materials to produce reaction products in the melt. The reaction products comprise a solid particulate phase, and the high-intensity acoustic vibration fragments and/or separates the reaction products into solid particles that are dispersed in the melt and are smaller than the particles of the second material. Also encompassed are particle-reinforced composite materials produced by such a process.

  8. Method of producing particulate-reinforced composites and composties produced thereby

    DOE Patents [OSTI]

    Han, Qingyou; Liu, Zhiwei

    2013-12-24

    A process for producing particle-reinforced composite materials through utilization of an in situ reaction to produce a uniform dispersion of a fine particulate reinforcement phase. The process includes forming a melt of a first material, and then introducing particles of a second material into the melt and subjecting the melt to high-intenisty acoustic vibration. A chemical reaction initiates between the first and second materials to produce reaction products in the melt. The reaciton products comprise a solide particulate phase, and the high-intensity acoustic vibration fragments and/or separates the reaction products into solid particles that are dispersed in the melt and are smaller than the particles of the second material. Also encompassed are particles-reinforced composite materials produced by such a process.

  9. Method for removing solid particulate material from within liquid fuel injector assemblies

    DOE Patents [OSTI]

    Simandl, R.F.; Brown, J.D.; Andriulli, J.B.; Strain, P.D.

    1998-09-08

    A method is described for removing residual solid particulate material from the interior of liquid fuel injectors and other fluid flow control mechanisms having or being operatively associated with a flow-regulating fixed or variable orifice. The method comprises the sequential and alternate introduction of columns of a non-compressible liquid phase and columns of a compressed gas phase into the body of a fuel injector whereby the expansion of each column of the gas phase across the orifice accelerates the liquid phase in each trailing column of the liquid phase and thereby generates turbulence in each liquid phase for lifting and entraining the solid particulates for the subsequent removal thereof from the body of the fuel injector. 1 fig.

  10. Method for removing solid particulate material from within liquid fuel injector assemblies

    DOE Patents [OSTI]

    Simandl, Ronald F. (Knoxville, TN); Brown, John D. (Harriman, TN); Andriulli, John B. (Kingston, TN); Strain, Paul D. (Eads, TN)

    1998-01-01

    A method for removing residual solid particulate material from the interior of liquid fuel injectors and other fluid flow control mechanisms having or being operatively associated with a flow-regulating fixed or variable orifice. The method comprises the sequential and alternate introduction of columns of a non-compressible liquid phase and columns of a compressed gas phase into the body of a fuel injector whereby the expansion of each column of the gas phase across the orifice accelerates the liquid phase in each trailing column of the liquid phase and thereby generates turbulence in each liquid phase for lifting and entraining the solid particulates for the subsequent removal thereof from the body of the fuel injector.

  11. Method of producing particulate-reinforced composites and composites produced thereby

    DOE Patents [OSTI]

    Han, Qingyou; Liu, Zhiwei

    2015-12-29

    A process for producing particle-reinforced composite materials through utilization of an in situ reaction to produce a uniform dispersion of a fine particulate reinforcement phase. The process includes forming a melt of a first material, and then introducing particles of a second material into the melt and subjecting the melt to high-intensity acoustic vibration. A chemical reaction initiates between the first and second materials to produce reaction products in the melt. The reaction products comprise a solid particulate phase, and the high-intensity acoustic vibration fragments and/or separates the reaction products into solid particles that are dispersed in the melt and are smaller than the particles of the second material. Also encompassed are particle-reinforced composite materials produced by such a process.

  12. Operating Experience Level 3, Update to Requalification Test Failure of Certain High Efficiency Particulate Air (HEPA) Filters

    Broader source: Energy.gov [DOE]

    Operating Experience Level 3 (OE-3) document provides information regarding the previous requalification test failure and subsequent successful requalification, of certain high efficiency particulate air (HEPA) Filters models manufactured by Flanders Corporation.

  13. Engine gaseous, aerosol precursor and particulate at simulated flight altitude conditions. Technical memo

    SciTech Connect (OSTI)

    Wey, C.C.

    1998-10-01

    The overall objective of the NASA Atmospheric Effects of Aviation Project (AEAP) is to develop scientific bases for assessing atmospheric impacts of the exhaust emissions by both current and future fleets of subsonic and supersonic aircraft. Among the six primary elements of the AEAP is Emissions Characterization. The objective of the Emission Characterization effort is to determine the exhaust emission constituents and concentrations at the engine exit plane. The specific objective of this engine test is to obtain a database of gaseous and particulate emissions as a function of fuel sulfur and engine operating conditions. The database of the particulate emission properties is to be used as a comparative baseline with subsequent flight measurement. The engine used in this test was a Pratt and Whitney F100-200E turbofan engine. Aviation fuel (Jet A) with a range of fuel sulfur was used. Low and high sulfur values are limited by commercially available fuels and by fuel specification limits of 0.3% by weight. Test matrix was set by parametrically varying the combustor inlet temperature (T3) between idle and maximum power setting at simulated SLS and up to five other altitudes for each fuel. Four diagnostic systems, extractive and non-intrusive, were assembled for the gaseous and particulate emissions characterization measurements study. NASA extractive system includes smoke meter and analyzers for measurement of CO, CO{sub 2}, NO, NOx, O{sub 2}, total unburnt hydrocarbons (THC), and SO{sub 2}. Particulate emissions were characterized by University of Missouri-Rolla Mobile Aerosol Sampling System.

  14. Diesel Particulate Filter Technology for Low-Temperature and Low-NOx/PM

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Applications | Department of Energy Filter Technology for Low-Temperature and Low-NOx/PM Applications Diesel Particulate Filter Technology for Low-Temperature and Low-NOx/PM Applications 2004 DEER Conference Presentation: Johnson-Matthey Catalysts PDF icon 2004_deer_chatterjee.pdf More Documents & Publications Performance of Johnson Matthey EGRT’ Emission Control System for NOx and PM Emission Reduction in Retrofit Applications Part 1 Aftertreatment Modeling Status, Futur Potential, and

  15. Development of Optical Technologies for Monitoring Moisture and Particulate in Geothermal Steam

    SciTech Connect (OSTI)

    J. K. Partin

    2006-08-01

    The results of an investigation directed at evaluating the feasibility of using optical measurements for the real-time monitoring moisture and particulate in geothermal steam is described. The measurements exploit new technologies that have been developed for the telecommunications industry and includes new solid state laser devices, large-bandwidth, high-sensitivity detectors and low loss optical fiber compo-nents. In particular, the design, fabrication, and in-plant testing of an optical steam monitor for the detection of moisture is presented. The measurement principle is based upon the selective absorption of infrared energy in response to the presence of moisture. Typically, two wavelengths are used in the measurements: a wavelength that is strongly absorbed by water and a reference wavelength that is minimally influenced by water and steam which serves as a reference to correct for particulate or droplet scattering. The two wavelengths are chosen to be as close as possible in order to more effectively correct for scattering effects. The basic instrumentation platform developed for the in-situ monitoring of steam moisture can be modified and used to perform other measurements of interest to plant operators. An upgrade that will allow the instrument to be used for the sensitive detection of particulate in process streams has been investigated. The new monitor design involves the use of laser diodes that are much less sensitive to water and water vapor and more sensitive to scattering phenomena, as well as new processing techniques to recover these signals. The design reduces the averaging time and sampling volume, while increasing the laser probe power, enhancing particulate detection sensitivity. The design concept and initial laboratory experiments with this system are also reported.

  16. Light absorption from particulate impurities in snow and ice determined by spectrophotometric analysis of filters

    SciTech Connect (OSTI)

    Grenfell, Thomas C.; Doherty, Sarah J.; Clarke, Antony D.; Warren, Stephen G.

    2011-05-10

    Light absorption by particulate impurities in snow and ice can affect the surface albedo and is important for the climate. The absorption properties of these particles can be determined by collecting and melting snow samples and extracting the particulate material by filtration of the meltwater. This paper describes the optical design and testing of a new instrument to measure the absorption spectrum from 400 to 750 nm wavelength of the particles collected on filters using an ''integrating-sandwich'' configuration. The measured absorption is shown to be unaffected by scattering of light from the deposited particulates. A set of calibration standards is used to derive an upper limit for the concentration of black carbon (BC) in the snow. The wavelength dependence of the absorption spectra from 450 to 600 nm is used to calculate an absorption Angstrom exponent for the aerosol. This exponent is used to estimate the actual BC concentration in the snow samples as well as the relative contributions of BC and non-BC constituents to the absorption of solar radiation integrated over the wavelength band 300 to 750 nm.

  17. Investigation of vertical distribution and morphology of indigenous organic matter Sleeping Bear site, Michigan

    SciTech Connect (OSTI)

    West, C.C.; Lyon, W.G.; Ross, D.L.

    1994-11-01

    This study evaluates the nature and origin of particulate organic carbon and organic coatings on aquifer sands upgradient from a fuel spill site near the Sleeping Bear Dunes National Lakeshore in Michigan. The distribution of carbon was found to be highly complex due to the occurrence of high organic carbon horizons, bounded above and below by high carbonate sediments. The organic coatings on the sands were examined using white light and fluorescence microscopy and by scanning electron microscopy. Core samples were analyzed for organic and inorganic carbon, solution pH, humic/fulvic acid ratios, and insoluable organic matter content (that is, humin) as function of depth from the ground surface. The organic geochemistry of the soil profile at this site was found to be significantly influenced by the carbonates producing a sharp boundary of precipitated organic matter. This boundary was followed by coatings of predominantly fulvic acid salts on mineral grains deeper in the soil column. The coatings extended into the aquifer. The existence of native organic films on sand grains is well documented in the soils literature. The study reported here was greatly aided by this information and provides the framework for future studies concerning the influence of carbon distribution, chemical identity, and morphology on contaminant fate and transport processes. 56 refs., 9 figs., 2 tabs.

  18. Pump Systems Matter Mission and Vision | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Pump Systems Matter Mission and Vision Pump Systems Matter Mission and Vision Pump Systems Matter(tm) (PSM) places a primary focus on pump systems education and outreach and addresses energy savings and total cost of pump ownership. PDF icon C_Vision_&_Mission_of_Pump_Systems_Matter.pdf More Documents & Publications Overview of Pump Systems Matter Hydraulic Institute Member Benefits Course Overview Pump Systems Matter Optimization

  19. Overview of Pump Systems Matter | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Overview of Pump Systems Matter Overview of Pump Systems Matter Pump Systems Matter (PSM) is a non-profit (501(c) 3) educational foundation, established to educate the marketplace and promote pumping systems energy efficiency. PDF icon G_Overview_of_Pump_Systems_Matter.pdf More Documents & Publications Summary of 2011 Accomplishments HI & PSM Course Overview Pump Systems Matter Optimization Pump Systems Matter Mission and Vision

  20. ALS Reveals New State of Matter

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ALS Reveals New State of Matter ALS Reveals New State of Matter Print Wednesday, 13 October 2010 00:00 ALS user groups from Princeton and Stanford have been making waves this past year with several high-profile papers and extensive news coverage of their work on a new state of matter embodied by "topological insulators," materials that conduct electricity only on their surfaces. First identified at the ALS in 2007 by a Princeton team led by M. Zahid Hasan, topological insulators have

  1. Quintessence with quadratic coupling to dark matter

    SciTech Connect (OSTI)

    Boehmer, Christian G.; Chan, Nyein; Caldera-Cabral, Gabriela; Lazkoz, Ruth; Maartens, Roy

    2010-04-15

    We introduce a new form of coupling between dark energy and dark matter that is quadratic in their energy densities. Then we investigate the background dynamics when dark energy is in the form of exponential quintessence. The three types of quadratic coupling all admit late-time accelerating critical points, but these are not scaling solutions. We also show that two types of coupling allow for a suitable matter era at early times and acceleration at late times, while the third type of coupling does not admit a suitable matter era.

  2. Final Technical Report "Catalytic Hydrogenation of Carbon Monoxide and Olefin Oxidation" Grant number : DE-FG02-86ER13615

    SciTech Connect (OSTI)

    Wayland, B.B.

    2009-08-31

    Title: Catalytic Hydrogenation of Carbon Monoxide and Olefin Oxidation Grant No. DE-FG02-86ER13615 PI: Wayland, B. B. (wayland@sas.upenn.edu) Abstract Development of new mechanistic strategies and catalyst materials for activation of CO, H2, CH4, C2H4, O2, and related substrates relevant to the conversion of carbon monoxide, alkanes, and alkenes to organic oxygenates are central objectives encompassed by this program. Design and synthesis of metal complexes that manifest reactivity patterns associated with potential pathways for the hydrogenation of carbon monoxide through metallo-formyl (M-CHO), dimetal ketone (M-C(O)-M), and dimetal dionyl (M-C(O)-C(O)-M) species is one major focus. Hydrocarbon oxidation using molecular oxygen is a central goal for methane activation and functionalization as well as regioselective oxidation of olefins. Discovery of new reactivity patterns and control of selectivity are pursued through designing new metal complexes and adjusting reaction conditions. Variation of reaction media promotes distinct reaction pathways that control both reaction rates and selectivities. Dimetalloradical diporphyrin complexes preorganize transition states for substrate reactions that involve two metal centers and manifest large rate increases over mono-metalloradical reactions of hydrogen, methane, and other small molecule substrates. Another broad goal and recurring theme of this program is to contribute to the thermodynamic database for a wide scope of organo-metal transformations in a range of reaction media. One of the most complete descriptions of equilibrium thermodynamics for organometallic reactions in water and methanol is emerging from the study of rhodium porphyrin substrate reactions in aqueous and alcoholic media. Water soluble group nine metalloporphyrins manifest remarkably versatile substrate reactivity in aqueous and alcoholic media which includes producing rhodium formyl (Rh-CHO) and hydroxy methyl (Rh-CH2OH) species. Exploratory directions for this program include expending new strategies for anti-Markovnikov addition of water, alcohols, and amines with olefins, developing catalytic reactions of CO to give formamides and formic esters, and evaluating the potential for coupling reactions of CO to produce organic building blocks.

  3. Electronic Structure of Warm Dense Matter via Multicenter Green...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electronic Structure of Warm Dense Matter via Multicenter Green's Function Technique Research Personnel Modeling The proposed research addresses the Warm Dense Matter area...

  4. MPA Materials Matter December 2014 (Technical Report) | SciTech...

    Office of Scientific and Technical Information (OSTI)

    MPA Materials Matter December 2014 Citation Details In-Document Search Title: MPA Materials Matter December 2014 You are accessing a document from the Department of Energy's...

  5. MPA Materials Matter October 2015 (Technical Report) | SciTech...

    Office of Scientific and Technical Information (OSTI)

    MPA Materials Matter October 2015 Citation Details In-Document Search Title: MPA Materials Matter October 2015 In support of the U.S. Department of Energy's (DOE)...

  6. MPA Materials Matter September 2014 (Technical Report) | SciTech...

    Office of Scientific and Technical Information (OSTI)

    MPA Materials Matter September 2014 Citation Details In-Document Search Title: MPA Materials Matter September 2014 You are accessing a document from the Department of Energy's...

  7. Social Media and Messages that Matter - Top Tips and Tools |...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Social Media and Messages that Matter - Top Tips and Tools Better Buildings Residential Network Peer Exchange Call Series: Social Media and Messages that Matter - Top Tips and ...

  8. Properties of Nuclear Matter Within the JISP16 NN Interaction...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Properties of Nuclear Matter Within the JISP16 NN Interaction Citation Details In-Document Search Title: Properties of Nuclear Matter Within the JISP16 NN...

  9. Sandia Energy - Control of Strong Light-Matter Coupling Using...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Control of Strong Light-Matter Coupling Using the Capacitance of Metamaterial Nanocavities Home Highlights - Energy Research Control of Strong Light-Matter Coupling Using the...

  10. The Effective Field Theory of Dark Matter Direct Detection (Journal...

    Office of Scientific and Technical Information (OSTI)

    Effective Field Theory of Dark Matter Direct Detection Citation Details In-Document Search Title: The Effective Field Theory of Dark Matter Direct Detection You are accessing a...

  11. Neutrino Coherent Scattering Rates at Direct Dark Matter Detectors...

    Office of Scientific and Technical Information (OSTI)

    Neutrino Coherent Scattering Rates at Direct Dark Matter Detectors Citation Details In-Document Search Title: Neutrino Coherent Scattering Rates at Direct Dark Matter Detectors ...

  12. MPA Materials Matter February 2016 (Technical Report) | SciTech...

    Office of Scientific and Technical Information (OSTI)

    MPA Materials Matter February 2016 Citation Details In-Document Search Title: MPA Materials Matter February 2016 No abstract provided. Authors: Kippen, Karen Elizabeth 1 + Show ...

  13. Precision Determination Of The Nonlinear Matter Power Spectrum...

    Office of Scientific and Technical Information (OSTI)

    Precision Determination Of The Nonlinear Matter Power Spectrum Citation Details In-Document Search Title: Precision Determination Of The Nonlinear Matter Power Spectrum You are...

  14. TEE-0003 - In the Matter of Emerson Motor Technologies | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    03 - In the Matter of Emerson Motor Technologies TEE-0003 - In the Matter of Emerson Motor Technologies This Decision and Order considers an Application for Exception filed by...

  15. Properties of nuclear matter within the JISP16NNinteraction ...

    Office of Scientific and Technical Information (OSTI)

    Properties of nuclear matter within the JISP16NNinteraction Citation Details In-Document Search Title: Properties of nuclear matter within the JISP16NNinteraction Authors:...

  16. Manual for Classified Matter Protection and Control

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    1998-01-09

    Provides detailed requirements for the protection and control of classified matter which supplement DOE O 471.2A. Cancels DOE M 471.2-1 dated 09/26/1995.

  17. Supernova cooling in a dark matter smog

    SciTech Connect (OSTI)

    Zhang, Yue

    2014-11-27

    A light hidden gauge boson with kinetic mixing with the usual photon is a popular setup in theories of dark matter. The supernova cooling via radiating the hidden boson is known to put an important constraint on the mixing. I consider the possible role dark matter, which under reasonable assumptions naturally exists inside supernova, can play in the cooling picture. Because the interaction between the hidden gauge boson and DM is likely unsuppressed, even a small number of dark matter compared to protons inside the supernova could dramatically shorten the free streaming length of the hidden boson. A picture of a dark matter “smog” inside the supernova, which substantially relaxes the cooling constraint, is discussed in detail.

  18. ALS Reveals New State of Matter

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    New State of Matter Print ALS user groups from Princeton and Stanford have been making waves this past year with several high-profile papers and extensive news coverage of...

  19. Do New Technologies Matter? | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    People came from around the country to see the world's first 3D-printed car, a fuel cell for spacecraft and brand new battery storage units. They're cool. But do they matter? ...

  20. Method and apparatus for acoustically monitoring the flow of suspended solid particulate matter. [Patent application; monitoring char flow in coal gasifier

    DOE Patents [OSTI]

    Roach, P.D.; Raptis, A.C.

    1980-11-24

    A method and apparatus for monitoring char flow in a coal gasifier system includes flow monitor circuits which measure acoustic attenuation caused by the presence of char in a char line and provides a char flow/no flow indication and an indication of relative char density. The flow monitor circuits compute the ratio of signals in two frequency bands, a first frequency band representative of background noise, and a second higher frequency band in which background noise is attenuated by the presence of char. Since the second frequency band contains higher frequencies, the ratio can be used to provide a flow/no flow indication. The second band can also be selected so that attenuation is monotonically related to particle concentration, providing a quantitative measure of char concentration.

  1. The C-4 Dark Matter Experiment

    SciTech Connect (OSTI)

    Bonicalzi, Ricco; Collar, J. I.; Colaresi, J.; Fast, James E.; Fields, N.; Fuller, Erin S.; Hai, M.; Hossbach, Todd W.; Kos, Marek S.; Orrell, John L.; Overman, Cory T.; Reid, Douglas J.; VanDevender, Brent A.; Wiseman, Clinton G.; Yocum, K. M.

    2013-06-01

    Abstract We describe the experimental design of C-4, an expansion of the CoGeNT dark matter search to four identical detectors each approximately three times the mass of the p-type point contact (PPC) germanium diode presently taking data at the Soudan Underground Laboratory. Expected reductions of radioactive backgrounds and energy threshold are discussed, including an estimate of the additional sensitivity to low-mass dark matter candidates to be obtained with this search.

  2. Ultrafast Spectroscopy of Warm Dense Matter

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Spectroscopy of Warm Dense Matter Print Being neither solid, liquid, gas, nor plasma, warm dense matter (WDM) occupies a no man's land in the map of material phases. Its temperature can range between that of planetary cores (tens of thousands K) to that of stellar cores (hundreds of thousands K). Not only is it prevalent throughout the universe, it is relevant to inertial confinement fusion (ICF) and material performance under extreme conditions. However, because of its extreme temperatures and

  3. Ultrafast Spectroscopy of Warm Dense Matter

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ultrafast Spectroscopy of Warm Dense Matter Print Being neither solid, liquid, gas, nor plasma, warm dense matter (WDM) occupies a no man's land in the map of material phases. Its temperature can range between that of planetary cores (tens of thousands K) to that of stellar cores (hundreds of thousands K). Not only is it prevalent throughout the universe, it is relevant to inertial confinement fusion (ICF) and material performance under extreme conditions. However, because of its extreme

  4. Ultrafast Spectroscopy of Warm Dense Matter

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ultrafast Spectroscopy of Warm Dense Matter Print Being neither solid, liquid, gas, nor plasma, warm dense matter (WDM) occupies a no man's land in the map of material phases. Its temperature can range between that of planetary cores (tens of thousands K) to that of stellar cores (hundreds of thousands K). Not only is it prevalent throughout the universe, it is relevant to inertial confinement fusion (ICF) and material performance under extreme conditions. However, because of its extreme

  5. Pinpointing the Magnetic Moments of Nuclear Matter

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Pinpointing the Magnetic Moments of Nuclear Matter Pinpointing the Magnetic Moments of Nuclear Matter Lattice QCD Calculations Reveal Inner Workings of Lightest Nuclei January 20, 2015 Contact: Kathy Kincade, +1 510 495 2124, kkincade@lbl.gov h3lattice Artist's impression of a triton, the atomic nucleus of a tritium atom. The image shows blue neutrons and a red proton with quarks inside; the arrows indicate the alignments of the spins. Image: William Detmold, MIT A team of nuclear physicists has

  6. Laser Driven Dynamic Loading of Condensed Matter

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Laser Driven Dynamic Loading of Condensed Matter Laser Driven Dynamic Loading of Condensed Matter Advanced diagnostics of experiments covering many orders of magnitude in strain rate Contact Eric Loomis (505) 665-3196 Email Dynamic materials experiments over a wide range of strain rates are essential to studying constitutive relations (e.g., plasticity), damage (e.g., spall), equations of state, phase transitions and kinetics, and novel materials. The Trident laser facility supplies unique,

  7. Near-ambient X-ray photoemission spectroscopy and kinetic approach to the mechanism of carbon monoxide oxidation over lanthanum substituted cobaltites

    SciTech Connect (OSTI)

    Hueso, J. L.; Martinez-Martinez, D.; Cabalerro, Alfonso; Gonzalez-Elipe, Agustin Rodriguez; Mun, Bongjin Simon; Salmeron, Miquel

    2009-07-31

    We have studied the oxidation of carbon monoxide over a lanthanum substituted perovskite (La0.5Sr0.5CoO3-d) catalyst prepared by spray pyrolysis. Under the assumption of a first-order kinetics mechanism for CO, it has been found that the activation energy barrier of the reaction changes from 80 to 40 kJ mol-1 at a threshold temperature of ca. 320 oC. In situ XPS near-ambient pressure ( 0.2 torr) shows that the gas phase oxygen concentration over the sample decreases sharply at ca. 300 oC. These two observations suggest that the oxidation of CO undergoes a change of mechanism at temperatures higher than 300 oC.

  8. Particulate emissions from residential wood combustion: Final report: Norteast regional Biomass Program

    SciTech Connect (OSTI)

    Not Available

    1987-01-01

    The objective of this study was to provide a resource document for the Northeastern states when pursuing the analysis of localized problems resulting from residential wood combustion. Specific tasks performed include assigning emission rates for total suspended particulates (TSP) and benzo(a)pyrene (BaP) from wood burning stoves, estimating the impact on ambient air quality from residential wood combustion and elucidating the policy options available to Northeastern states in their effort to limit any detrimental effects resulting from residential wood combustion. Ancillary tasks included providing a comprehensive review on the relevant health effects, indoor air pollution and toxic air pollutant studies. 77 refs., 11 figs., 25 tabs.

  9. Solid Phase Characterization of Tank 241-AY-102 Annulus Space Particulate

    SciTech Connect (OSTI)

    Cooke, G. A.

    2013-01-30

    The Special Analytical Studies Group at the 222-S Laboratory (222-S) examined the particulate recovered from a series of samples from the annular space of tank 241-AY-102 (AY-102) using solid phase characterization (SPC) methods. These include scanning electron microscopy (SEM) using the ASPEX?1 scanning electron microscope, X-ray diffraction (XRD) using the Rigaku?2 MiniFlex X-ray diffractometer, and polarized light microscopy (PLM) using the Nikon?3 Eclipse Pol optical microscope. The SEM is equipped with an energy dispersive X-ray spectrometer (EDS) to provide chemical information.

  10. Electrically resistive coating for remediation (regeneration) of a diesel particulate filter and method

    DOE Patents [OSTI]

    Phelps, Amanda C.; Kirby, Kevin K.; Gregoire, Daniel J.

    2012-02-14

    A resistively heated diesel particulate filter (DPF). The resistively heated DPF includes a DPF having an inlet surface and at least one resistive coating on the inlet surface. The at least one resistive coating is configured to substantially maintain its resistance in an operating range of the DPF. The at least one resistive coating has a first terminal and a second terminal for applying electrical power to resistively heat up the at least one resistive coating in order to increase the temperature of the DPF to a regeneration temperature. The at least one resistive coating includes metal and semiconductor constituents.

  11. Particulate Formation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Applications National Solar Thermal Test Facility ... Hydrogen Production Market Transformation Fuel Cells Predictive Simulation of Engines Transportation Energy Consortiums ...

  12. Particulate Formation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Formation - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs Advanced Nuclear Energy

  13. Identifying dark matter interactions in monojet searches

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Agrawal, Prateek; Rentala, Vikram

    2014-05-22

    We study the discrimination of quark-initiated jets from gluon-initiated jets in monojet searches for dark matter using the technique of averaged jet energy profiles. We demonstrate our results in the context of effective field theories of dark matter interactions with quarks and gluons, but our methods apply more generally to a wide class of models. Different effective theories of dark matter and the standard model backgrounds each have a characteristic quark/gluon fraction for the leading jet. When used in conjunction with the traditional cut-and-count monojet search, the jet energy profile can be used to set stronger bounds on contact interactionsmore » of dark matter. In the event of a discovery of a monojet excess at the 14 TeV LHC, contact interactions between dark matter with quarks or with gluons can be differentiated at the 95% confidence level. For a given rate at the LHC, signal predictions at direct detection experiments for different dark matter interactions can span five orders of magnitude. Lastly, the ability to identify these interactions allows us to make a tighter connection between LHC searches and direct detection experiments.« less

  14. Identifying dark matter interactions in monojet searches

    SciTech Connect (OSTI)

    Agrawal, Prateek; Rentala, Vikram

    2014-05-01

    We study the discrimination of quark-initiated jets from gluon-initiated jets in monojet searches for dark matter using the technique of averaged jet energy profiles. We demonstrate our results in the context of effective field theories of dark matter interactions with quarks and gluons, but our methods apply more generally to a wide class of models. Different effective theories of dark matter and the standard model backgrounds each have a characteristic quark/gluon fraction for the leading jet. When used in conjunction with the traditional cut-and-count monojet search, the jet energy profile can be used to set stronger bounds on contact interactions of dark matter. In the event of a discovery of a monojet excess at the 14 TeV LHC, contact interactions between dark matter with quarks or with gluons can be differentiated at the 95% confidence level. For a given rate at the LHC, signal predictions at direct detection experiments for different dark matter interactions can span five orders of magnitude. The ability to identify these interactions allows us to make a tighter connection between LHC searches and direct detection experiments.

  15. Scientists Mix Matter and Anti-Matter Results to Resolve Decade-Old Proton

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Puzzle | Jefferson Lab Scientists Mix Matter and Anti-Matter to Resolve Decade-Old Proton Puzzle Hall B The CEBAF Large Acceptance Spectrometer, or CLAS, in Jefferson Lab's Experimental Hall B was used to measure electrons during the experiment. Fans of science and science fiction have been warned that mixing matter with anti-matter can yield explosive results. And that's just what physicists were counting on, in hopes of blowing wide open a puzzle that has confounded them for the last

  16. Dark matter directional detection in non-relativistic effective theories

    SciTech Connect (OSTI)

    Catena, Riccardo

    2015-07-20

    We extend the formalism of dark matter directional detection to arbitrary one-body dark matter-nucleon interactions. The new theoretical framework generalizes the one currently used, which is based on 2 types of dark matter-nucleon interaction only. It includes 14 dark matter-nucleon interaction operators, 8 isotope-dependent nuclear response functions, and the Radon transform of the first 2 moments of the dark matter velocity distribution. We calculate the recoil energy spectra at dark matter directional detectors made of CF{sub 4}, CS{sub 2} and {sup 3}He for the 14 dark matter-nucleon interactions, using nuclear response functions recently obtained through numerical nuclear structure calculations. We highlight the new features of the proposed theoretical framework, and present our results for a spherical dark matter halo and for a stream of dark matter particles. This study lays the foundations for model independent analyses of dark matter directional detection experiments.

  17. Cosmological constraints on the gravitational interactions of matter and dark matter

    SciTech Connect (OSTI)

    Bai, Yang; Salvado, Jordi; Stefanek, Ben A.

    2015-10-13

    Although there is overwhelming evidence of dark matter from its gravitational interaction, we still do not know its precise gravitational interaction strength or whether it obeys the equivalence principle. Using the latest available cosmological data and working within the framework of ΛCDM, we first update the measurement of the multiplicative factor of cosmology-relevant Newton’s constant over the standard laboratory-based value and find that it is consistent with one. In general relativity, dark matter equivalence principle breaking can be mimicked by a long-range dark matter force mediated by an ultra light scalar field. Using the Planck three year data, we find that the dark matter “fifth-force” strength is constrained to be weaker than 10{sup −4} of the gravitational force. We also introduce a phenomenological, post-Newtonian two-fluid description to explicitly break the equivalence principle by introducing a difference between dark matter inertial and gravitational masses. Depending on the decoupling time of the dark matter and ordinary matter fluids, the ratio of the dark matter gravitational mass to inertial mass is constrained to be unity at the 10{sup −6} level.

  18. Considerations for modeling small-particulate impacts from surface coal-mining operations based on wind-tunnel simulations

    SciTech Connect (OSTI)

    Perry, S.G.; Petersen, W.B.; Thompson, R.S.

    1994-12-31

    The Clean Air Act Amendments of 1990 provide for a reexamination of the current Environmental Protection Agency`s (USEPA) methods for modeling fugitive particulate (PM10) from open-pit, surface coal mines. The Industrial Source Complex Model (ISCST2) is specifically named as the method that needs further study. Title II, Part B, Section 234 of the Amendments states that {open_quotes}...the Administrator shall analyze the accuracy of such model and emission factors and make revisions as may be necessary to eliminate any significant over-predictions of air quality effect of fugitive particulate emissions from such sources.{close_quotes}

  19. Cold Positrons from Decaying Dark Matter

    SciTech Connect (OSTI)

    Boubekeur, Lotfi; Dodelson, Scott; Vives, Oscar

    2012-11-01

    Many models of dark matter contain more than one new particle beyond those in the Standard Model. Often heavier particles decay into the lightest dark matter particle as the Universe evolves. Here we explore the possibilities that arise if one of the products in a (Heavy Particle) $\\rightarrow$ (Dark Matter) decay is a positron, and the lifetime is shorter than the age of the Universe. The positrons cool down by scattering off the cosmic microwave background and eventually annihilate when they fall into Galactic potential wells. The resulting 511 keV flux not only places constraints on this class of models but might even be consistent with that observed by the INTEGRAL satellite.

  20. Cosmology of bigravity with doubly coupled matter

    SciTech Connect (OSTI)

    Comelli, D.; Crisostomi, M.; Koyama, K.; Pilo, L.; Tasinato, G.

    2015-04-20

    We study cosmology in the bigravity formulation of the dRGT model where matter couples to both metrics. At linear order in perturbation theory two mass scales emerge: an hard one from the dRGT potential, and an environmental dependent one from the coupling of bigravity with matter. At early time, the dynamics is dictated by the second mass scale which is of order of the Hubble scale. The set of gauge invariant perturbations that couples to matter follow closely the same behaviour as in GR. The remaining perturbations show no issue in the scalar sector, while problems arise in the tensor and vector sectors. During radiation domination, a tensor mode grows power-like at super-horizon scales. More dangerously, the only propagating vector mode features an exponential instability on sub-horizon scales. We discuss the consequences of such instabilities and speculate on possible ways to deal with them.

  1. Neutralino dark matter in BMSSM effective theory

    SciTech Connect (OSTI)

    Berg, Marcus; Edsj, Joakim; Lundstrm, Erik; Sjrs, Stefan; Gondolo, Paolo E-mail: edsjo@physto.se E-mail: erik@physto.se

    2009-08-01

    We study thermal neutralino dark matter in an effective field theory extension of the MSSM, called ''Beyond the MSSM'' (BMSSM) in Dine, Seiberg and Thomas (2007). In this class of effective field theories, the field content of the MSSM is unchanged, but the little hierarchy problem is alleviated by allowing small corrections to the Higgs/higgsino part of the Lagrangian. We perform parameter scans and compute the dark matter relic density. The light higgsino LSP scenario is modified the most; we find new regions of parameter space compared to the standard MSSM. This involves interesting interplay between the WMAP dark matter bounds and the LEP chargino bound. We also find some changes for gaugino LSPs, partly due to annihilation through a Higgs resonance, and partly due to coannihilation with light top squarks in models that are ruled in by the new effective terms.

  2. Alternatives to Diesel Fuel in California - Fuel Cycle Energy and Emission Effects of Possible Replacements Due to the TAC Diesel Particulate Decision

    SciTech Connect (OSTI)

    Christopher L. Saraicks; Donald M. Rote; Frank Stodolsky; James J. Eberhardt

    2000-05-01

    Limitations on petroleum-based diesel fuel in California could occur pursuant to the 1998 declaration by California's Air Resources Board (CARB) that the particulate matter component of diesel exhaust is a carcinogen, therefore a toxic air contaminant (TAC) subject to the state's Proposition 65. It is the declared intention of CARB not to ban or restrict diesel fuel, per se, at this time. Assuming no total ban, Argonne National Laboratory (ANL) explored two feasible ''mid-course'' strategies, each of which results in some degree of (conventional) diesel displacement. In the first case, with substantial displacement of compression ignition by spark ignition engines, diesel fuel is assumed admissible for ignition assistance as a pilot fuel in natural gas (NG)-powered heavy-duty vehicles. Gasoline demand in California increases by 32.2 million liters (8.5 million gallons) per day overall, about 21 percent above projected 2010 baseline demand. Natural gas demand increases by 13.6 million diesel liter (3.6 million gallon) equivalents per day, about 7 percent above projected (total) consumption level. In the second case, ressionignition engines utilize substitutes for petroleum-based diesel having similar ignition and performance properties. For each case we estimated localized air emission plus generalized greenhouse gas and energy changes. Fuel replacement by di-methyl ether yields the greatest overall reduction in NOx emissions, though all scenarios bring about PM10 reductions relative to the 2010 baseline, with greatest reductions from the first case described above and the least from fuel replacement by Fischer-Tropsch synthetic diesel. Economic implications of vehicle and engine replacement were not formally evaluated.

  3. Alternatives to diesel fuel in California - fuel cycle energy and emission effects of possible replacements due to the TAC diesel particulate decision.

    SciTech Connect (OSTI)

    Saricks, C. L.; Rote, D. M.; Stodolsky, F.; Eberhardt, J. J.

    1999-12-03

    Limitations on petroleum-based diesel fuel in California could occur pursuant to the 1998 declaration by California's Air Resources Board (CARB) that the particulate matter component of diesel exhaust is a carcinogen, therefore a toxic air contaminant (TAC) subject to the state's Proposition 65. It is the declared intention of CARB not to ban or restrict diesel fuel per se, at this time. Assuming no total ban, Argonne National Laboratory (ANL) explored two feasible mid-course strategies, each of which results in some degree of (conventional) diesel displacement. In the first case, with substantial displacement of compression-ignition by spark-ignition engines, diesel fuel is assumed admissible for ignition assistance as a pilot fuel in natural gas (NG)-powered heavy-duty vehicles. Gasoline demand in California increases by 32.2 million liters (8.5 million gallons) per day overall, about 21% above projected 2010 baseline demand. Natural gas demand increases by 13.6 million diesel liter (3.6 million gallon) equivalents per day, about 7% above projected (total) consumption level. In the second case, compression-ignition engines utilize substitutes for petroleum-based diesel having similar ignition and performance properties. For each case the authors estimated localized air emission plus generalized greenhouse gas and energy changes. Fuel replacement by di-methyl ether yields the greatest overall reduction in NOX emissions, though all scenarios bring about PM{sub 10} reductions relative to the 2010 baseline, with greatest reductions from the first case described above and the least from fuel replacement by Fischer-Tropsch synthetic diesel. Economic implications of vehicle and engine replacement were not formally evaluated.

  4. Results of Self-Absorption Study on the Versapor 3000 Filters for Radioactive Particulate Air Sampling

    SciTech Connect (OSTI)

    Barnett, J. M.; Cullinan, Valerie I.; Barnett, Debra S.; Trang-Le, Truc LT; Bliss, Mary; Greenwood, Lawrence R.; Ballinger, Marcel Y.

    2009-02-17

    Since the mid-1980s, Pacific Northwest National Laboratory (PNNL) has used a value of 0.85 as the correction factor for self absorption of activity for particulate radioactive air samples collected from building exhaust for environmental monitoring. This value accounts for activity that cannot be detected by direct counting of alpha and beta particles. Emissions can be degraded or blocked by filter fibers for particles buried in the filter material or by inactive dust particles collected with the radioactive particles. These filters are used for monitoring air emissions from PNNL stacks for radioactive particles. This paper describes an effort to re-evaluate self-absorption effects in particulate radioactive air sample filters (Versapor 3000, 47 mm diameter) used at PNNL. There were two methods used to characterize the samples. Sixty samples were selected from the archive for acid digestion to compare the radioactivity measured by direct gas-flow proportional counting of filters to the results obtained after acid digestion of the filter and counting again by gas-flow proportional detection. Thirty different sample filters were selected for visible light microscopy to evaluate filter loading and particulate characteristics. Mass-loading effects were also considered. Filter ratios were calculated by dividing the initial counts by the post-digestion counts with the expectation that post-digestion counts would be higher because digestion would expose radioactivity embedded in the filter in addition to that on top of the filter. Contrary to expectations, the post digestion readings were almost always lower than initial readings and averaged approximately half the initial readings for both alpha and beta activity. Before and after digestion readings appeared to be related to each other, but with a low coefficient of determination (R^2) value. The ratios had a wide range of values indicating that this method did not provide sufficient precision to quantify self-absorption effects. The microscopy analysis compares different filter loadings and shows that smaller particle sizes (under 10 micron) can readily be seen on the more lightly loaded filters. At higher loadings, however, the particle size is harder to differentiate. This study provides data on actual stack emission samples showing a range of mass loading conditions and visual evidence of particle size and distribution and also presents the difficulties in quantifying self-absorption effects using actual samples.

  5. Science On Tap - Matter over. Antimatter

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Science On Tap - Matter over Antimatter Science On Tap - Matter over. Antimatter WHEN: Aug 20, 2015 5:30 PM - 7:00 PM WHERE: UnQuarked Wine Room 145 Central Park Square, Los Alamos, New Mexico, 87544 CONTACT: Jessica Privette 505 667-0375 CATEGORY: Bradbury INTERNAL: Calendar Login Science On Tap Event Description Science On Tap happens every third Thursday of the month, featuring a new topic each week. It begins with an informal 15-minute talk and is followed by a lively group discussion.

  6. ALS Reveals New State of Matter

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ALS Reveals New State of Matter Print ALS user groups from Princeton and Stanford have been making waves this past year with several high-profile papers and extensive news coverage of their work on a new state of matter embodied by "topological insulators," materials that conduct electricity only on their surfaces. First identified at the ALS in 2007 by a Princeton team led by M. Zahid Hasan, topological insulators have been the subject of intense interest, based on unusual quantum

  7. ALS Reveals New State of Matter

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ALS Reveals New State of Matter Print ALS user groups from Princeton and Stanford have been making waves this past year with several high-profile papers and extensive news coverage of their work on a new state of matter embodied by "topological insulators," materials that conduct electricity only on their surfaces. First identified at the ALS in 2007 by a Princeton team led by M. Zahid Hasan, topological insulators have been the subject of intense interest, based on unusual quantum

  8. ALS Reveals New State of Matter

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ALS Reveals New State of Matter Print ALS user groups from Princeton and Stanford have been making waves this past year with several high-profile papers and extensive news coverage of their work on a new state of matter embodied by "topological insulators," materials that conduct electricity only on their surfaces. First identified at the ALS in 2007 by a Princeton team led by M. Zahid Hasan, topological insulators have been the subject of intense interest, based on unusual quantum

  9. Axions as hot and cold dark matter

    SciTech Connect (OSTI)

    Jeong, Kwang Sik; Kawasaki, Masahiro; Takahashi, Fuminobu E-mail: kawasaki@icrr.u-tokyo.ac.jp

    2014-02-01

    The presence of a hot dark matter component has been hinted at 3? by a combination of the results from different cosmological observations. We examine a possibility that pseudo Nambu-Goldstone bosons account for both hot and cold dark matter components. We show that the QCD axions can do the job for the axion decay constant f{sub a}?

  10. Exploring the Nature of Matter | Jefferson Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Exploring the Nature of Matter November 3, 2008 If you look at the header on a letter sent by any of us at Jefferson Laboratory, you will find the words, " Exploring the nature of matter." And you might ask, what do they mean? At Jefferson Laboratory, we scatter electrons like Hofstadter did in the '50s when he explored nuclei. That's why one of our roads is named for him. The scattering process is described as the exchange of a virtual photon between the electrons and the charged

  11. ALS Reveals New State of Matter

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ALS Reveals New State of Matter Print ALS user groups from Princeton and Stanford have been making waves this past year with several high-profile papers and extensive news coverage of their work on a new state of matter embodied by "topological insulators," materials that conduct electricity only on their surfaces. First identified at the ALS in 2007 by a Princeton team led by M. Zahid Hasan, topological insulators have been the subject of intense interest, based on unusual quantum

  12. ALS Reveals New State of Matter

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ALS Reveals New State of Matter Print ALS user groups from Princeton and Stanford have been making waves this past year with several high-profile papers and extensive news coverage of their work on a new state of matter embodied by "topological insulators," materials that conduct electricity only on their surfaces. First identified at the ALS in 2007 by a Princeton team led by M. Zahid Hasan, topological insulators have been the subject of intense interest, based on unusual quantum

  13. Cross-flow, filter-sorbent catalyst for particulate, SO sub 2 and NO sub x control

    SciTech Connect (OSTI)

    Not Available

    1990-03-01

    This synopsis describes a new concept for integrated pollutant control: a cross-flow filter comprised of layered, gas permeable membranes that act as a particulate filter, an SO{sub 2} sorbent, and a NO{sub x} reduction catalyst.

  14. Variable C : N : P stoichiometry of dissolved organic matter cycling in the Community Earth System Model

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Letscher, R. T.; Moore, J. K.; Teng, Y. -C.; Primeau, F.

    2015-01-12

    Dissolved organic matter (DOM) plays an important role in the ocean's biological carbon pump by providing an advective/mixing pathway for ~ 20% of export production. DOM is known to have a stoichiometry depleted in nitrogen (N) and phosphorus (P) compared to the particulate organic matter pool, a fact that is often omitted from biogeochemical ocean general circulation models. However the variable C : N : P stoichiometry of DOM becomes important when quantifying carbon export from the upper ocean and linking the nutrient cycles of N and P with that of carbon. Here we utilize recent advances in DOM observationalmore » data coverage and offline tracer-modeling techniques to objectively constrain the variable production and remineralization rates of the DOM C : N : P pools in a simple biogeochemical-ocean model of DOM cycling. The optimized DOM cycling parameters are then incorporated within the Biogeochemical Elemental Cycling (BEC) component of the Community Earth System Model (CESM) and validated against the compilation of marine DOM observations. The optimized BEC simulation including variable DOM C : N : P cycling was found to better reproduce the observed DOM spatial gradients than simulations that used the canonical Redfield ratio. Global annual average export of dissolved organic C, N, and P below 100 m was found to be 2.28 Pg C yr-1 (143 Tmol C yr-1, 16.4 Tmol N yr-1, and 1 Tmol P yr-1, respectively, with an average export C : N : P stoichiometry of 225 : 19 : 1 for the semilabile (degradable) DOM pool. Dissolved organic carbon (DOC) export contributed ~ 25% of the combined organic C export to depths greater than 100 m.« less

  15. Variable C : N : P stoichiometry of dissolved organic matter cycling in the Community Earth System Model

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Letscher, R. T.; Moore, J. K.; Teng, Y. -C.; Primeau, F.

    2014-06-16

    Dissolved organic matter (DOM) plays an important role in the ocean's biological carbon pump by providing an advective/mixing pathway for ~ 20% of export production. DOM is known to have a stoichiometry depleted in nitrogen (N) and phosphorus (P) compared to the particulate organic matter pool, a~fact that is often omitted from biogeochemical-ocean general circulation models. However the variable C : N : P stoichiometry of DOM becomes important when quantifying carbon export from the upper ocean and linking the nutrient cycles of N and P with that of carbon. Here we utilize recent advances in DOM observational data coveragemore » and offline tracer-modeling techniques to objectively constrain the variable production and remineralization rates of the DOM C / N / P pools in a simple biogeochemical-ocean model of DOM cycling. The optimized DOM cycling parameters are then incorporated within the Biogeochemical Elemental Cycling (BEC) component of the Community Earth System Model and validated against the compilation of marine DOM observations. The optimized BEC simulation including variable DOM C : N : P cycling was found to better reproduce the observed DOM spatial gradients than simulations that used the canonical Redfield ratio. Global annual average export of dissolved organic C, N, and P below 100 m was found to be 2.28 Pg C yr-1 (143 Tmol C yr-1), 16.4 Tmol N yr-1, and 1 Tmol P yr-1, respectively with an average export C : N : P stoichiometry of 225 : 19 : 1 for the semilabile (degradable) DOM pool. DOC export contributed ~ 25% of the combined organic C export to depths greater than 100 m.« less

  16. Accident Generated Particulate Materials and Their Characteristics -- A Review of Background Information

    SciTech Connect (OSTI)

    Sutter, S. L.

    1982-05-01

    Safety assessments and environmental impact statements for nuclear fuel cycle facilities require an estimate of the amount of radioactive particulate material initially airborne (source term) during accidents. Pacific Northwest Laboratory (PNL) has surveyed the literature, gathering information on the amount and size of these particles that has been developed from limited experimental work, measurements made from operational accidents, and known aerosol behavior. Information useful for calculating both liquid and powder source terms is compiled in this report. Potential aerosol generating events discussed are spills, resuspension, aerodynamic entrainment, explosions and pressurized releases, comminution, and airborne chemical reactions. A discussion of liquid behavior in sprays, sparging, evaporation, and condensation as applied to accident situations is also included.

  17. Method and apparatus for removal of gaseous, liquid and particulate contaminants from molten metals

    DOE Patents [OSTI]

    Hobson, David O. (Oak Ridge, TN); Alexeff, Igor (Oak Ridge, TN); Sikka, Vinod K. (Clinton, TN)

    1988-01-01

    Method and apparatus for removal of nonelectrically-conducting gaseous, liquid, and particulate contaminants from molten metal compositions by applying a force thereto. The force (commonly referred to as the Lorentz Force) exerted by simultaneous application of an electric field and a magnetic field on a molten conductor causes an increase, in the same direction as the force, in the apparent specific gravity thereof, but does not affect the nonconducting materials. This difference in apparent densities cause the nonconducting materials to "float" in the opposite direction from the Lorentz Force at a rapid rate. Means are further provided for removal of the contaminants and prevention of stirring due to rotational forces generated by the applied fields.

  18. Method and apparatus for removal of gaseous, liquid and particulate contaminants from molten metals

    DOE Patents [OSTI]

    Hobson, D.O.; Alexeff, I.; Sikka, V.K.

    1987-08-10

    Method and apparatus for removal of nonelectrically-conducting gaseous, liquid, and particulate contaminants from molten metal compositions by applying a force thereto. The force (commonly referred to as the Lorentz Force) exerted by simultaneous application of an electric field and a magnetic field on a molten conductor causes an increase, in the same direction as the force, in the apparent specific gravity thereof, but does not affect the nonconducting materials. This difference in apparent densities cause the nonconducting materials to ''float'' in the opposite direction from the Lorentz Force at a rapid rate. Means are further provided for removal of the contaminants and prevention of stirring due to rotational forces generated by the applied fields. 6 figs.

  19. Dark-Matter-Induced Violation of the Weak Equivalence Principle

    SciTech Connect (OSTI)

    Carroll, Sean M.; Mantry, Sonny [California Institute of Technology, Pasadena, California 91125 (United States); Ramsey-Musolf, Michael J. [University of Wisconsin-Madison, Madison, Wisconsin 53706 (United States); California Institute of Technology, Pasadena, California 91125 (United States); Stubbs, Christoper W. [Harvard-Smithsonian Center for Astrophysics, Cambridge, Massachusetts 02138 (United States)

    2009-07-03

    A long-range fifth force coupled to dark matter can induce a coupling to ordinary matter if the dark matter interacts with standard model fields. We consider constraints on such a scenario from both astrophysical observations and laboratory experiments. We also examine the case where the dark matter is a weakly interacting massive particle, and derive relations between the coupling to dark matter and the coupling to ordinary matter for different models. Currently, this scenario is most tightly constrained by galactic dynamics, but improvements in Eoetvoes experiments can probe unconstrained regions of parameter space.

  20. Electroweak fragmentation functions for dark matter annihilation

    SciTech Connect (OSTI)

    Cavasonza, Leila Ali; Krämer, Michael; Pellen, Mathieu

    2015-02-18

    Electroweak corrections can play a crucial role in dark matter annihilation. The emission of gauge bosons, in particular, leads to a secondary flux consisting of all Standard Model particles, and may be described by electroweak fragmentation functions. To assess the quality of the fragmentation function approximation to electroweak radiation in dark matter annihilation, we have calculated the flux of secondary particles from gauge-boson emission in models with Majorana fermion and vector dark matter, respectively. For both models, we have compared cross sections and energy spectra of positrons and antiprotons after propagation through the galactic halo in the fragmentation function approximation and in the full calculation. Fragmentation functions fail to describe the particle fluxes in the case of Majorana fermion annihilation into light fermions: the helicity suppression of the lowest-order cross section in such models cannot be lifted by the leading logarithmic contributions included in the fragmentation function approach. However, for other classes of models like vector dark matter, where the lowest-order cross section is not suppressed, electroweak fragmentation functions provide a simple, model-independent and accurate description of secondary particle fluxes.