National Library of Energy BETA

Sample records for monoxide ozone lead

  1. The Ozone Layer in the 21st Lead Authors

    E-Print Network [OSTI]

    Robock, Alan

    CHAPTER 6 The Ozone Layer in the 21st Century Lead Authors: G.E. Bodeker D.W. Waugh Coauthors: H;#12;CHAPTER 6 THE OZONE LAYER IN THE 21ST CENTURY Contents SCIENTIFIC SUMMARY . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6.5 6.2 A FRAMEWORK FOR EVALUATING CHANGES IN OZONE ABUNDANCES

  2. Lead monoxide $\\alpha$-PbO: electronic properties and point defect formation

    E-Print Network [OSTI]

    Berashevich, J; Rubel, O; Rowlands, J A; Reznik, A

    2012-01-01

    The electronic properties of polycrystalline lead oxide consisting of a network of single-crystalline $\\alpha$-PbO platelets and the formation of the native point defects in $\\alpha$-PbO crystal lattice are studied using first principles calculations. The $\\alpha$-PbO lattice consists of weakly coupled layers with inter-layer interactions of 0.013 eV/atom that is too low to produce high efficiency charge transfer between the adjacent layers. In practice, the polycrystalline nature of $\\alpha$-PbO causes the formation of lattice defects in such a high concentration that defect-related conductivity becomes the dominant factor in the interlayer charge transition. We found that the formation energy for the O vacancies is low, such vacancies are occupied by two electrons in the zero charge state and tend to donate their electrons to the Pb vacancies that leads to ionization of both vacancies.The vacancies introduce localized states in the band gap which can affect charge transport. The O vacancy forms a defect sta...

  3. Carbon Monoxide Environmental Public

    E-Print Network [OSTI]

    The National Workgroup on Carbon Monoxide Surveillance Formed in April 2005 Membership: EPHT grantees Academic

  4. Impact of Emissions, Chemistry, and Climate on Atmospheric Carbon Monoxide: 100-year Predictions from a Global Chemistry-Climate Model

    E-Print Network [OSTI]

    of methane and the production of CO2, ozone, and sulfate aerosols and thus affects climate, while, producing formaldehyde (CH2O) and then carbon monoxide. This methane reaction, in combination with R1

  5. Lead

    Broader source: Energy.gov (indexed) [DOE]

    topic Lead 8:00 AM 8:15 AM Welcome and Webinar Rules Maloy 8:15 AM 8:30 AM NE Materials Introduction Lesica 8:30 AM 9:00 AM Advanced Reactor Concepts Sham 9:00 AM 9:30 AM SMR...

  6. What is carbon monoxide? Carbon monoxide (CO) is a poisonous,

    E-Print Network [OSTI]

    Johnson, Eric E.

    other material containing carbon such as gasoline, kerosene, oil, propane, coal, or wood. Forges, blast is the internal combustion engine. How does CO harm you? Carbon monoxide is harmful when breathed because

  7. Ozone Reductions Using Residential Building Envelopes

    SciTech Connect (OSTI)

    Walker, Iain S.; Sherman, Max; Nazaroff, William W.

    2009-02-01

    Ozone is an air pollutant with that can have significant health effects and a significant source of ozone in some regions of California is outdoor air. Because people spend the vast majority of their time indoors, reduction in indoor levels of ozone could lead to improved health for many California residents. Ozone is removed from indoor air by surface reactions and can also be filtered by building envelopes. The magnitude of the envelope impact depends on the specific building materials that the air flows over and the geometry of the air flow paths through the envelope that can be changes by mechanical ventilation operation. The 2008 Residential Building Standards in California include minimum requirements for mechanical ventilation by referencing ASHRAE Standard 62.2. This study examines the changes in indoor ozone depending on the mechanical ventilation system selected to meet these requirements. This study used detailed simulations of ventilation in a house to examine the impacts of different ventilation systems on indoor ozone concentrations. The simulation results showed that staying indoors reduces exposure to ozone by 80percent to 90percent, that exhaust ventilation systems lead to lower indoor ozone concentrations, that opening of windows should be avoided at times of high outdoor ozone, and that changing the time at which mechanical ventilation occurs has the ability to halve exposure to ozone. Future work should focus on the products of ozone reactions in the building envelope and the fate of these products with respect to indoor exposures.

  8. Advanced Diesel Combustion with Low Hydrocarbon and Carbon Monoxide...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Combustion with Low Hydrocarbon and Carbon Monoxide Emissions Advanced Diesel Combustion with Low Hydrocarbon and Carbon Monoxide Emissions Poster presented at the 16th Directions...

  9. Population based exposure assessment methodology for carbon monoxide: Development of a Carbon Monoxide Passive Sampler and Occupational Dosimeter

    E-Print Network [OSTI]

    Apte, Michael G.

    2010-01-01

    In. - Patty's Industrial Hygiene and Toxicology, Vol. 3A,Monoxide Detection. Industrial Hygiene Journal Match-April,Monoxide." Applied Industrial Hygiene, 4,119-125. Jabara, J.

  10. Stratospheric variability and tropospheric ozone

    E-Print Network [OSTI]

    Hsu, Juno; Prather, Michael J

    2009-01-01

    Global and zonal total ozone variations estimated fromon multidecadal total ozone simulations, J. Geophys. Res. ,and J. A. Logan (2007), Ozone climatolo- gical profiles for

  11. Quantifying the contributions to stratospheric ozone changes from ozone

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    Quantifying the contributions to stratospheric ozone changes from ozone depleting substances., Reader, M. C. and Jonsson, A. I. (2010) Quantifying the contributions to stratospheric ozone changes from ozone depleting substances and greenhouse gases. Atmospheric Chemistry and Physics, 10. pp. 8803

  12. Carbon monoxide in collapsing interstellar clouds

    E-Print Network [OSTI]

    De Jong, T.; Chu, Shih-I; Dalgarno, A.

    1975-07-01

    Calculations are made for the energy loss rates, brightness temperatures, and line profiles of carbon monoxide in collapsing interstellar clouds. The most recent data for the H2-CO collision rates have been used in the calculations; a useful...

  13. Carbon Monoxide Poisoning Avoided Through Weatherization | Department...

    Broader source: Energy.gov (indexed) [DOE]

    usual, it probably would've put me to sleep and left me there -- it was just too much carbon monoxide coming out in the house," says Mark Pickartz, of Van Buren, Ark. Pickartz's...

  14. Carbon monoxide sensor for PEM fuel cell systems Christopher T. Holta,*

    E-Print Network [OSTI]

    Azad, Abdul-Majeed

    monoxide can lead to poisoning of platinum electrocatalysts used in the fuel cells [1,2]. The reforming are converted to hydrogen and carbon mon- oxide by reactions with air (partial oxidation), with water (steam. In the third step, the gas mixture is reacted with air over a preferential oxidation (PROX) catalyst, so

  15. Effects of ozone cooling in the tropical lower stratosphere and upper troposphere

    E-Print Network [OSTI]

    Effects of ozone cooling in the tropical lower stratosphere and upper troposphere Piers M. Forster lower stratosphere and upper troposphere and elucidate the key role of ozone changes in driving of tropical ozone decreases at 70 hPa and lower pressures can lead to significant cooling not only

  16. Separating the Influence of Halogen and Climate Changes on Ozone Recovery in the Upper Stratosphere

    E-Print Network [OSTI]

    causes ozone destruction by enhancing production of water vapor via methane oxidation. Additionally. Including potential climate-induced stratospheric water vapor increases, the ozone change relative to 1980 depletion chemistry, and therefore indirectly leading to more ozone. Increases in methane directly affect

  17. The Ozone Hole Some perspective

    E-Print Network [OSTI]

    Toohey, Darin W.

    The Ozone Hole · Some perspective · The British Antarctic Survey · The "Ozone Hole" · International of the predicted ozone losses! This was quite a controversy. Ultimately, ozone losses started appearing in the late 1980s (see Figure below), but by then, there was already a credibility issue for ozone scientists. #12

  18. Midlatitude Ozone: Loss and Trends

    E-Print Network [OSTI]

    Toohey, Darin W.

    1 Lecture 17 Midlatitude Ozone: Loss and Trends ATOC/CHEM 5151 #12;2 Importance of midlatitude ozone · Covers most of the world's populated areas · Provides protection from UV #12;3 Ozone loss picture, c. 1988 #12;4 Lower vs. Upper stratosphere #12;5 Ozone loss, post 1988 · Discovery of ozone hole

  19. Ozone profile and tropospheric ozone retrievals from the Global Ozone Monitoring Experiment: Algorithm description and validation

    E-Print Network [OSTI]

    Chance, Kelly

    Ozone profile and tropospheric ozone retrievals from the Global Ozone Monitoring Experiment October 2005. [1] Ozone profiles are derived from back scattered radiance spectra in the ultraviolet (289­339 nm) measured by the Global Ozone Monitoring Experiment (GOME) using the optimal estimation technique

  20. 6, 74277469, 2006 Linear ozone

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 6, 7427­7469, 2006 Linear ozone photochemistry parametrizations A. J. Geer et al. Title Page Chemistry and Physics Discussions Evaluation of linear ozone photochemistry parametrizations Linear ozone photochemistry parametrizations A. J. Geer et al. Title Page Abstract Introduction

  1. Method and apparatus for selective removal of carbon monoxide

    DOE Patents [OSTI]

    Borup, Rodney L. (East Rochester, NY); Skala, Glenn W. (Churchville, NY); Brundage, Mark A. (Pittsford, NY); LaBarge, William J. (Bay City, MI)

    2000-01-01

    There is provided a method and apparatus for treatment of a hydrogen-rich gas to reduce the carbon monoxide content thereof by reacting the carbon monoxide in the gas with an amount of oxygen sufficient to oxidize at least a portion of the carbon monoxide in the presence of a catalyst in a desired temperature range without substantial reaction of hydrogen. The catalyst is an iridium-based catalyst dispersed on, and supported on, a carrier. In the presence of the catalyst, carbon monoxide in a hydrogen-rich feed gas is selectively oxidized such that a product stream is produced with a very low carbon monoxide content.

  2. Validation of operational ozone profiles from the Ozone Monitoring Instrument

    E-Print Network [OSTI]

    Validation of operational ozone profiles from the Ozone Monitoring Instrument M. Kroon,1 J. F. de we present the validation results of the operational vertical ozone profiles retrieved from the nadir observations by the Ozone Monitoring Instrument (OMI) aboard the NASA Earth Observing System (EOS) Aura

  3. NARSTO OZONE ASSESSMENT EXECUTIVE SUMMARY

    E-Print Network [OSTI]

    vi NARSTO OZONE ASSESSMENT EXECUTIVE SUMMARY Prepared as a NARSTO initiative, this tropospheric O3 in the accompanying Textbox, the NARSTO Ozone Assessment contains two product components. The first of these is a set aspects of tropospheric ozone pollution. The second component, the NARSTO Ozone Assessment Document

  4. Artificial ozone holes

    E-Print Network [OSTI]

    S. N. Dolya

    2014-10-18

    This article considers an opportunity of disinfecting a part of the Earth surface, occupying a large area of ten thousand square kilometers. The sunlight will cause dissociation of molecular bromine into atoms; each bromine atom kills thirty thousand molecules of ozone. Each bromine plate has a mass of forty milligrams grams and destroys ozone in the area of hundred square meters. Thus, to form the ozone hole over the area of ten thousand square kilometers, it is required to have the total mass of bromine equal to the following four tons.

  5. Size Effect of Ruthenium Nanoparticles in Catalytic Carbon Monoxide Oxidation

    E-Print Network [OSTI]

    Joo, Sang Hoon

    2011-01-01

    sensitivity The catalytic oxidation of carbon monoxide (CO)stabilizer. The catalytic activity of CO oxidation overintriguing catalytic behavior for CO oxidation 5-15 ; while

  6. ILENR/RE-AQ-ON-ROAD CARBON MONOXIDE AND HYDROCARBON

    E-Print Network [OSTI]

    Denver, University of

    #12;ILENR/RE-AQ- Printed: Contract: Project: ON-ROAD CARBON MONOXIDE AND HYDROCARBON REMOTE SENSING. Repeat Measurements of the Same Vehicle. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 22 F

  7. A global comparison of carbon monoxide profiles and column amounts from Tropospheric Emission Spectrometer (TES)

    E-Print Network [OSTI]

    and anthropogenic incomplete combustion processes. In the presence of nitrogen oxides, carbon monoxide (COA global comparison of carbon monoxide profiles and column amounts from Tropospheric Emission compare carbon monoxide (CO) products from the Measurements of Pollution in the Troposphere (MOPITT

  8. Search for the electric dipole moment of the electron with thorium monoxide

    E-Print Network [OSTI]

    2010-01-01

    moment of the electron with thorium monoxide A C Vutha, W Cmoment of the electron with thorium monoxide A C Vutha 1 , WeEDM, using a cold beam of thorium monoxide (ThO) molecules.

  9. Population based exposure assessment methodology for carbon monoxide: Development of a Carbon Monoxide Passive Sampler and Occupational Dosimeter

    E-Print Network [OSTI]

    Apte, Michael G.

    2010-01-01

    Passive Colorimetric Dosimeter Tubes for Carbon Monoxide."Passive Colorimetric Dosimeter Tubes for Ammonia, CarbonPassive Badges, and Dosimeter Tubes." In: Air Sampling

  10. CO (Carbon Monoxide Mixing Ratio System) Handbook

    SciTech Connect (OSTI)

    Biraud, S

    2011-02-23

    The main function of the CO instrument is to provide continuous accurate measurements of carbon monoxide mixing ratio at the ARM SGP Central Facility (CF) 60-meter tower (36.607 °N, 97.489 °W, 314 meters above sea level). The essential feature of the control and data acquisition system is to record signals from a Thermo Electron 48C and periodically calibrate out zero and span drifts in the instrument using the combination of a CO scrubber and two concentrations of span gas (100 and 300 ppb CO in air). The system was deployed on May 25, 2005.

  11. Search of medical literature for indoor carbon monoxide exposure

    SciTech Connect (OSTI)

    Brennan, T.; Ivanovich, M.

    1995-12-01

    This report documents a literature search on carbon monoxide. The search was limited to the medical and toxicological databases at the National Library of Medicine (MEDLARS). The databases searched were Medline, Toxline and TOXNET. Searches were performed using a variety of strategies. Combinations of the following keywords were used: carbon, monoxide, accidental, residential, occult, diagnosis, misdiagnosis, heating, furnace, and indoor. The literature was searched from 1966 to the present. Over 1000 references were identified and summarized using the following abbreviations: The major findings of the search are: (1) Acute and subacute carbon monoxide exposures result in a large number of symptoms affecting the brain, kidneys, respiratory system, retina, and motor functions. (2) Acute and subacute carbon monoxide (CO) poisonings have been misdiagnosed on many occasions. (3) Very few systematic investigations have been made into the frequency and consequences of carbon monoxide poisonings.

  12. Stratospheric variability and tropospheric ozone

    E-Print Network [OSTI]

    Hsu, Juno; Prather, Michael J

    2009-01-01

    models include a nearly complete set of chemical species and reactions that affect ozone, but are costly to Earth System

  13. 5, 59575985, 2005 European ozone

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ACPD 5, 5957­5985, 2005 European ozone trends J. E. Jonson et al. Title Page Abstract Introduction explain the trends in European ozone levels? J. E. Jonson 1 , D. Simpson 1 , H. Fagerli 1 , and S. Solberg License. 5957 #12;ACPD 5, 5957­5985, 2005 European ozone trends J. E. Jonson et al. Title Page Abstract

  14. 6, 56715709, 2006 Hemispheric ozone

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 6, 5671­5709, 2006 Hemispheric ozone variability indices T. Erbertseder et al. Title Page Chemistry and Physics Discussions Hemispheric ozone variability indices derived from satellite observations.erbertseder@dlr.de) 5671 #12;ACPD 6, 5671­5709, 2006 Hemispheric ozone variability indices T. Erbertseder et al. Title Page

  15. 4, 32853332, 2004 Tropospheric ozone

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ACPD 4, 3285­3332, 2004 Tropospheric ozone over Equatorial Africa B. Sauvage et al. Title Page and Physics Discussions Tropospheric ozone over Equatorial Africa: regional aspects from the MOZAIC data B Correspondence to: B. Sauvage (saub@aero.obs-mip.fr) 3285 #12;ACPD 4, 3285­3332, 2004 Tropospheric ozone over

  16. 2, 339356, 2002 Surface ozone

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 2, 339­356, 2002 Surface ozone depletion episodes D. W. Tarasick and J. W. Bottenheim Title ozone depletion episodes in the Arctic and Antarctic from historical ozonesonde records D. W. Tarasick.tarasick@ec.gc.ca) 339 #12;ACPD 2, 339­356, 2002 Surface ozone depletion episodes D. W. Tarasick and J. W. Bottenheim

  17. 5, 38113845, 2005 Antarctic ozone

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 5, 3811­3845, 2005 Antarctic ozone depletion indicators G. E. Bodeker et al. Title Page Discussions Indicators of Antarctic ozone depletion G. E. Bodeker 1 , H. Shiona 1 , and H. Eskes 2 1 National Commons License. 3811 #12;ACPD 5, 3811­3845, 2005 Antarctic ozone depletion indicators G. E. Bodeker et al

  18. Assimilation of Aura ozone data

    E-Print Network [OSTI]

    Assimilation of Aura ozone data I. Stajner, H. Hayashi, K. Wargan, L.-P. Chang, and S. Pawson Global Modeling and Assimilation Office (GMAO) NASA/Goddard AGU Fall meeting December 2004 #12;2 Ozone assimilation at GMAO · Total ozone columns and stratospheric profiles from SBUV/2 instrument are assimilated

  19. 2, 921942, 2002 Global ozone

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 2, 921­942, 2002 Global ozone forecasting H. J. Eskes et al. Title Page Abstract Introduction Geophysical Society 2002 Atmospheric Chemistry and Physics Discussions Global ozone forecasting based on ERS-2 July 2002 Correspondence to: H. J. Eskes (eskes@knmi.nl) 921 #12;ACPD 2, 921­942, 2002 Global ozone

  20. 6, 51375162, 2006 Oceanic ozone

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ACPD 6, 5137­5162, 2006 Oceanic ozone deposition velocity C. W. Fairall et al. Title Page Abstract Discussions Water-side turbulence enhancement of ozone deposition to the ocean C. W. Fairall1 , D. Helmig2 , L. Fairall (chris.fairall@noaa.gov) 5137 #12;ACPD 6, 5137­5162, 2006 Oceanic ozone deposition velocity C. W

  1. Ozone decomposition in water solutions 

    E-Print Network [OSTI]

    Hewes, Cecil Grayson

    1969-01-01

    OF LITERATUR 1V Vi ~ V111 III ~ EXPERIMENTAL SYSTEM AND ITS OPERATION 14 IV. DISCUSS10N OF RESULTS AND COiJCLUSION. . . 24 i~JOMENCLATUHE. BIBLIOGRAPIFY APPENDIX I. WASTE WATER REGENERATION BY OZONATION. II. AMINE REMOVAL BY OZONATION...ATER SOLUTIONS OF pH 8. XIII. REACTION RATE CONSTANTS FOR THE D'COMPOSITION OF OZONE IN INTER SOLUTIONS OF pH 8. XIV COD REMOVAL BY OZONE XV. OZONIZATION OF MATER CONTAINIiNG RESIDUAL AMINE. 57 60 LIST OF FIGURES FIGURE 1. FIOW DIAGRAM OF THZ...

  2. Ozone decomposing filter

    DOE Patents [OSTI]

    Simandl, Ronald F. (Farragut, TN); Brown, John D. (Harriman, TN); Whinnery, Jr., LeRoy L. (Dublin, CA)

    1999-01-01

    In an improved ozone decomposing air filter carbon fibers are held together with a carbonized binder in a perforated structure. The structure is made by combining rayon fibers with gelatin, forming the mixture in a mold, freeze-drying, and vacuum baking.

  3. Carbon Monoxide, Ozone, Hydrocarbon Air Quality Standards, and Related Emission Requirements (Ohio)

    Broader source: Energy.gov [DOE]

    This chapter defining the roles of the Ohio Environmental Protection Agency gives specific detail on the regulation point-source air pollution for a variety of industries and pollutants.

  4. Carbon monoxide sensor and method of use thereof

    DOE Patents [OSTI]

    McDaniel; Anthony H. (Livermore, CA), Medlin; J. Will (Boulder, CO), Bastasz; Robert J. (Livermore, CA)

    2007-09-04

    Carbon monoxide sensors suitable for use in hydrogen feed streams and methods of use thereof are disclosed. The sensors are palladium metal/insulator/semiconductor (Pd-MIS) sensors which may possess a gate metal layer having uniform, Type 1, or non-uniform, Type 2, film morphology. Type 1 sensors display an increased sensor response in the presence of carbon monoxide while Type 2 sensors display a decreased response to carbon monoxide. The methods and sensors disclosed herein are particularly suitable for use in proton exchange membrane fuel cells (PEMFCs).

  5. Multi-model assessment of stratospheric ozone return dates and ozone recovery in

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    Multi-model assessment of stratospheric ozone return dates and ozone recovery in CCMVal-2 models. (2010) Multi-model assessment of stratospheric ozone return dates and ozone recovery in CCMVal-2 models Chemistry and Physics Multi-model assessment of stratospheric ozone return dates and ozone recovery

  6. Solving the Tulsa ozone problem

    SciTech Connect (OSTI)

    Wagner, K.K. [Atmospheric Information Systems, Norman, OK (United States); Wilson, J.D. [Wilson Consulting Group, Tulsa, OK (United States); Gibeau, E. [Aeromet Inc., Tulsa, OK (United States)

    1998-12-31

    Local governments and interested parties in Tulsa, Oklahoma are planning actions to keep Tulsa in compliance with the ozone ambient air quality standard. Based on recent data Tulsa exceeds the new eight hour average national ambient air quality standard for ozone and occasionally exceeds the previous one hour standard. Currently, Tulsa is in attainment of the former one-hour ozone standard. The first planning step is to integrate the existing information about Tulsa`s ozone problem. Prior studies of Tulsa ozone are reviewed. Tulsa`s recent air quality and meteorological monitoring are evaluated. Emission inventory estimates are assessed. Factors identified with Tulsa`s ozone problem are the transport of ozone and precursor gases, a possible role for biogenic emissions, and a simplistic ozone forecasting method. The integration of information found that current air quality and meteorological monitoring is meager. Observations of volatile organic compounds and NO{sub y} are absent. Prior intensive studies in 1977 and 1985 are more than ten years old and lack relevance to today`s problem. Emission inventory estimates are scarce and uncertain. The current knowledge base was judged inadequate to properly characterize the present ozone problem. Actions are recommended to enlarge the information base to address Tulsa`s ozone problem.

  7. 6, 66276694, 2006 linearized ozone

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 6, 6627­6694, 2006 CHEM2D-OPP linearized ozone photochemistry J. P. McCormack et al. Title Chemistry and Physics Discussions CHEM2D-OPP: A new linearized gas-phase ozone photochemistry.mccormack@nrl.navy.mil) 6627 #12;ACPD 6, 6627­6694, 2006 CHEM2D-OPP linearized ozone photochemistry J. P. McCormack et al

  8. Molten metal reactor and method of forming hydrogen, carbon monoxide and carbon dioxide using the molten alkaline metal reactor

    DOE Patents [OSTI]

    Bingham, Dennis N.; Klingler, Kerry M.; Turner, Terry D.; Wilding, Bruce M.

    2012-11-13

    A molten metal reactor for converting a carbon material and steam into a gas comprising hydrogen, carbon monoxide, and carbon dioxide is disclosed. The reactor includes an interior crucible having a portion contained within an exterior crucible. The interior crucible includes an inlet and an outlet; the outlet leads to the exterior crucible and may comprise a diffuser. The exterior crucible may contain a molten alkaline metal compound. Contained between the exterior crucible and the interior crucible is at least one baffle.

  9. Reductions in ozone concentrations due to controls on variability in industrial flare emissions in Houston, Texas

    E-Print Network [OSTI]

    Nam, Junsang

    2007-01-01

    High concentrations of ozone in the Houston/Galveston area are associated with industrial plumes of highly reactive hydrocarbons, mixed with NOx. The emissions leading to these plumes can have significant temporal variability, ...

  10. Tax Credits, Rebates & Savings | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    ambient air quality standards for particulate matter, sulfur dioxide, carbon monoxide, ozone, lead and nitrogen dioxide. Eligibility: Agricultural, Commercial, Construction, Fed....

  11. Tax Credits, Rebates & Savings | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    standards for ambient air quality standards for particulate matter, sulfur dioxide, carbon monoxide, ozone, lead and nitrogen dioxide. Eligibility: Agricultural, Commercial,...

  12. Ozone production and hydrocarbon reactivity in Hong Kong, Southern China

    E-Print Network [OSTI]

    2007-01-01

    Middleton, P. , and Wang, T. : Ozone precursor relationshipsJ. Zhang et al. : Ozone production and hydrocarbonKiang, C. S. : Ground- level ozone pollution in Hong Kong,

  13. Oceanic alkyl nitrates as a natural source of tropospheric ozone

    E-Print Network [OSTI]

    Neu, Jessica L; Lawler, Michael J; Prather, Michael J; Saltzman, Eric S

    2008-01-01

    Chemical transport model ozone simulations for spring 2001ozonesondes, and Total Ozone Mapping Spectrometer columns,behaviour of tropospheric ozone precursors in a global 3-D

  14. Global tropospheric ozone modeling: Quantifying errors due to grid resolution

    E-Print Network [OSTI]

    Wild, Oliver; Prather, Michael J

    2006-01-01

    by and influencing ozone in unpolluted tropospheric air,R. C. , et al. (2004), Ozone production in transpacificplumes and implications for ozone air quality in California,

  15. Reactive nitrogen, ozone and ozone production in the Arctic troposphere and the impact of stratosphere-troposphere exchange

    E-Print Network [OSTI]

    2011-01-01

    Part I: NO x , PAN and Ozone Relationships, J. Atmos.Bromine measurements in ozone depleted air over the Arcticto springtime tropospheric ozone maxima using TOPSE measure-

  16. Ozone Conference II: Abstract Proceedings

    SciTech Connect (OSTI)

    None

    1999-11-01

    Ozone Conference II: Pre- and Post-Harvest Applications Two Years After Gras, was held September 27-28, 1999 in Tulare, California. This conference, sponsored by EPRI's Agricultural Technology Alliance and Southern California Edison's AgTAC facility, was coordinated and organized by the on-site ATA-AgTAC Regional Center. Approximately 175 people attended the day-and-a-half conference at AgTAC. During the Conference twenty-two presentations were given on ozone food processing and agricultural applications. Included in the presentations were topics on: (1) Ozone fumigation; (2) Ozone generation techniques; (3) System and design applications; (4) Prewater treatment requirements; (5) Poultry water reuse; (6) Soil treatments with ozone gas; and (7) Post-harvest aqueous and gaseous ozone research results. A live videoconference between Tulare and Washington, D.C. was held to discuss the regulators' view from inside the beltway. Attendees participated in two Roundtable Question and Answer sessions and visited fifteen exhibits and demonstrations. The attendees included university and governmental researchers, regulators, consultants and industry experts, technology developers and providers, and corporate and individual end-users. This report is comprised of the Abstracts of each presentation, biographical sketches for each speaker and a registration/attendees list.

  17. Ozone Depletion: Part 2 Antarctic Ozone Hole: Each spring, the ozone layer thins over the poles.

    E-Print Network [OSTI]

    Schofield, Jeremy

    via catalytic cycle: Under cold conditions, dimers ClO OCl form which are unstable in light. #3; Once concentration of ozone drops, reservoir reactions dominate and HCl and ClONO 2 reformed. #3; In antarctic spring

  18. ATOC 3500/CHEM 3151 Spring 2014 Stratospheric Ozone Destruction in the "Ozone Hole"

    E-Print Network [OSTI]

    Toohey, Darin W.

    ATOC 3500/CHEM 3151 Spring 2014 Problem 15 Stratospheric Ozone Destruction in the "Ozone Hole" The figure below shows typical observations of the total amount of ozone in a layer of air 8 km thick between 12 and 20 km over the South Pole (recall that we like to express the `thickness of ozone

  19. N:\\redesign\\guides\\Ozone.doc 1 Materials found in the IIT Archives concerning "Ozone"

    E-Print Network [OSTI]

    Heller, Barbara

    N:\\redesign\\guides\\Ozone.doc 1 Materials found in the IIT Archives concerning "Ozone" Search done of Ozone by G. C. Carnahan and O. A. DeCelle; Chemical Engineering program, 1914 Call No. Thesis 543.2 C22 Press releases issued by Illinois Institute of Technology, 1940-1968 that include the word "ozone

  20. Climatology of UTLS ozone and the ratio of ozone and potential vorticity over northern Europe

    E-Print Network [OSTI]

    Kirkwood, Sheila

    Climatology of UTLS ozone and the ratio of ozone and potential vorticity over northern Europe T variations of ozone in the upper troposphere and lower stratosphere (UTLS) region have been studied using of ozone exhibits a prominent annual cycle in the UTLS region. The observed change in the phase

  1. Composite catalyst for carbon monoxide and hydrocarbon oxidation

    DOE Patents [OSTI]

    Liu, W.; Flytzani-Stephanopoulos, M.

    1996-03-19

    A method and composition are disclosed for the complete oxidation of carbon monoxide and/or hydrocarbon compounds. The method involves reacting the carbon monoxide and/or hydrocarbons with an oxidizing agent in the presence of a metal oxide composite catalyst. The catalyst is prepared by combining fluorite-type oxygen ion conductors with active transition metals. The fluorite oxide, selected from the group consisting of cerium oxide, zirconium oxide, thorium oxide, hafnium oxide, and uranium oxide, and may be doped by alkaline earth and rare earth oxides. The transition metals, selected from the group consisting of molybdenum, copper, cobalt, manganese, nickel, and silver, are used as additives. The atomic ratio of transition metal to fluorite oxide is less than one.

  2. Composite catalyst for carbon monoxide and hydrocarbon oxidation

    DOE Patents [OSTI]

    Liu, Wei (Cambridge, MA); Flytzani-Stephanopoulos, Maria (Winchester, MA)

    1996-01-01

    A method and composition for the complete oxidation of carbon monoxide and/or hydrocarbon compounds. The method involves reacting the carbon monoxide and/or hydrocarbons with an oxidizing agent in the presence of a metal oxide composite catalyst. The catalyst is prepared by combining fluorite-type oxygen ion conductors with active transition metals. The fluorite oxide, selected from the group consisting of cerium oxide, zirconium oxide, thorium oxide, hafnium oxide, and uranium oxide, and may be doped by alkaline earth and rare earth oxides. The transition metals, selected from the group consisting of molybdnum, copper, cobalt, maganese, nickel, and silver, are used as additives. The atomic ratio of transition metal to fluorite oxide is less than one.

  3. 7, 1009710129, 2007 Chemical ozone loss

    E-Print Network [OSTI]

    ACPD 7, 10097­10129, 2007 Chemical ozone loss in the Arctic winter 1991­1992 S. Tilmes et al. Title Chemistry and Physics Discussions Chemical ozone loss in the Arctic winter 1991­1992 S. Tilmes 1 , R. M Chemical ozone loss in the Arctic winter 1991­1992 S. Tilmes et al. Title Page Abstract Introduction

  4. 5, 243286, 2005 Retrieval of ozone

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ACPD 5, 243­286, 2005 Retrieval of ozone column content during SOLVE II J. M. Livingston et al and Physics Discussions Retrieval of ozone column content from airborne Sun photometer measurements during Aerospace Center), Oberpfaffenhofen, Wessling, Germany 243 #12;ACPD 5, 243­286, 2005 Retrieval of ozone

  5. 4, 20552088, 2004 Aerosol-ozone

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 4, 2055­2088, 2004 Aerosol-ozone correlations during dust transport episodes P. Bonasoni et al and Physics Discussions Aerosol-ozone correlations during dust transport episodes P. Bonasoni1 , P.bonasoni@isac.cnr.it) 2055 #12;ACPD 4, 2055­2088, 2004 Aerosol-ozone correlations during dust transport episodes P. Bonasoni

  6. 6, 43254340, 2006 Scaling in ozone and

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 6, 4325­4340, 2006 Scaling in ozone and temperature C. Varotsos and D. Kirk-Davidoff Title Chemistry and Physics Discussions Long-memory processes in global ozone and temperature variations C #12;ACPD 6, 4325­4340, 2006 Scaling in ozone and temperature C. Varotsos and D. Kirk-Davidoff Title

  7. 7, 22492274, 2007 Vertical ozone over

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 7, 2249­2274, 2007 Vertical ozone over Eastern Mediterranean and Central Europe P. D a Creative Commons License. Atmospheric Chemistry and Physics Discussions Vertical ozone measurements (kalabokas pavlos@yahoo.gr) 2249 #12;ACPD 7, 2249­2274, 2007 Vertical ozone over Eastern Mediterranean

  8. 8, 31433162, 2008 Total ozone over

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ACPD 8, 3143­3162, 2008 Total ozone over oceanic regions M. C. R. Kalapureddy et al. Title Page Chemistry and Physics Discussions Total column ozone variations over oceanic region around Indian sub­3162, 2008 Total ozone over oceanic regions M. C. R. Kalapureddy et al. Title Page Abstract Introduction

  9. 8, 50075060, 2008 Evaluation of ozone

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 8, 5007­5060, 2008 Evaluation of ozone trends from g-b FTIR observations C. Vigouroux et al.0 License. Atmospheric Chemistry and Physics Discussions Evaluation of tropospheric and stratospheric ozone Publications on behalf of the European Geosciences Union. 5007 #12;ACPD 8, 5007­5060, 2008 Evaluation of ozone

  10. 8, 49114947, 2008 NOx-induced ozone

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 8, 4911­4947, 2008 NOx-induced ozone loss processes B. Vogel et al. Title Page Abstract Chemistry and Physics Discussions Model simulations of stratospheric ozone loss caused by enhanced on behalf of the European Geosciences Union. 4911 #12;ACPD 8, 4911­4947, 2008 NOx-induced ozone loss

  11. 5, 1133111375, 2005 NH total ozone

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ACPD 5, 11331­11375, 2005 NH total ozone increase S. Dhomse et al. Title Page Abstract Introduction On the possible causes of recent increases in NH total ozone from a statistical analysis of satellite data from License. 11331 #12;ACPD 5, 11331­11375, 2005 NH total ozone increase S. Dhomse et al. Title Page Abstract

  12. 6, 84578483, 2006 Low ozone over the

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ACPD 6, 8457­8483, 2006 Low ozone over the UK M. Keil et al. Title Page Abstract Introduction Discussions The January 2006 low ozone event over the UK M. Keil, D. R. Jackson, and M. C. Hort Met Office 2006 Correspondence to: M. Keil (mike.keil@metoffice.gov.uk) 8457 #12;ACPD 6, 8457­8483, 2006 Low ozone

  13. 5, 96419668, 2005 The origin of ozone

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ACPD 5, 9641­9668, 2005 The origin of ozone V. Grewe Title Page Abstract Introduction Conclusions-5-9641 European Geosciences Union Atmospheric Chemistry and Physics Discussions The origin of ozone V. Grewe The origin of ozone V. Grewe Title Page Abstract Introduction Conclusions References Tables Figures Back

  14. 6, 39133943, 2006 Svalbard total ozone

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 6, 3913­3943, 2006 Svalbard total ozone C. Vogler et al. Title Page Abstract Introduction Discussions Re-evaluation of the 1950­1962 total ozone record from Longyearbyen, Svalbard C. Vogler 1 , S. Br total ozone C. Vogler et al. Title Page Abstract Introduction Conclusions References Tables Figures Back

  15. 3, 187223, 2003 TOMS cloudy ozone

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ACPD 3, 187­223, 2003 TOMS cloudy ozone anomaly X. Liu et al. Title Page Abstract Introduction Geosciences Union 2003 Atmospheric Chemistry and Physics Discussions Occurrence of ozone anomalies over cloudy 2003 Correspondence to: X. Liu (xliu@nsstc.uah.edu) 187 #12;ACPD 3, 187­223, 2003 TOMS cloudy ozone

  16. 3, 10811107, 2003 Mid-latitude ozone

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 3, 1081­1107, 2003 Mid-latitude ozone changes in a 3D CTM M. P. Chipperfield Title Page-dimensional model study of long-term mid-high latitude lower stratosphere ozone changes M. P. Chipperfield School­1107, 2003 Mid-latitude ozone changes in a 3D CTM M. P. Chipperfield Title Page Abstract Introduction

  17. 4, 21672238, 2004 Ozone loss and

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ACPD 4, 2167­2238, 2004 Ozone loss and chlorine activation in the Arctic winters 1991­2003 S Union 2004 Atmospheric Chemistry and Physics Discussions Ozone loss and chlorine activation Correspondence to: S. Tilmes (simone.tilmes@t-online.de) 2167 #12;ACPD 4, 2167­2238, 2004 Ozone loss and chlorine

  18. Ozone: Integrating Structured and Semistructured Data ?

    E-Print Network [OSTI]

    Abiteboul, Serge

    Ozone: Integrating Structured and Semistructured Data ? Tirthankar Lahiri 1 , Serge Abiteboul 2 language, and we implement our extensions in a system called Ozone. In our approach, structured data may full knowledge of structure. Ozone also enhances both ODMG/OQL and OEM/Lorel by virtue

  19. Seasonal persistence of midlatitude total ozone anomalies

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    Seasonal persistence of midlatitude total ozone anomalies Article Published Version Fioletov, V. E. and Shepherd, T. G. (2003) Seasonal persistence of midlatitude total ozone anomalies. Geophysical Research persistence of midlatitude total ozone anomalies Vitali E. Fioletov Meteorological Service of Canada, Toronto

  20. Method and system for producing lower alcohols. [Heteropolyatomic lead salt coated with alkali metal formate

    DOE Patents [OSTI]

    Rathke, J.W.; Klingler, R.J.; Heiberger, J.J.

    1983-09-26

    It is an object of the present invention to provide an improved catalyst for the reaction of carbon monoxide with water to produce methanol and other lower alcohols. It is a further object to provide a process for the production of methanol from carbon monoxide and water in which a relatively inexpensive catalyst permits the reaction at low pressures. It is also an object to provide a process for the production of methanol from carbon monoxide and water in which a relatively inexpensive catalyst permits the reaction at low pressures. It is also an object to provide a process for the production of methanol in which ethanol is also directly produced. It is another object to provide a process for the production of mixtures of methanol with ethanol and propanol from the reaction of carbon monoxide and water at moderate pressure with inexpensive catalysts. It is likewise an object to provide a system for the catalytic production of lower alcohols from the reaction of carbon monoxide and water at moderate pressure with inexpensive catalysts. In accordance with the present invention, a catalyst is provided for the reaction of carbon monoxide and water to produce lower alcohols. The catalyst includes a lead heteropolyatomic salt in mixture with a metal formate or a precursor to a metal formate.

  1. A study of the effect of ozone and antioxidants on ozone-sensitive loblolly pine 

    E-Print Network [OSTI]

    Posey, Karen Lashea

    1995-01-01

    Ozone, a phytotoxic air pollutant, is formed from photochemical reactions of hydrocarbons and nitrogen oxides in the troposphere. Ozone is taken into the plant through the stomata, and quickly broken down into hydroxyl radicals. These hydroxyl...

  2. Improving ozone profile retrieval from spaceborne UV backscatter

    E-Print Network [OSTI]

    Haak, Hein

    Chapter 2 Improving ozone profile retrieval from spaceborne UV backscatter spectrometers using convergence behaviour diagnostics Abstract The Ozone Profile Algorithm (OPERA), developed at KNMI, retrieves the vertical ozone distribution from nadir spectral satellite measurements of back scattered sunlight

  3. oZONE Faculty and Staff Enrolling Students

    E-Print Network [OSTI]

    Oklahoma, University of

    oZONE Faculty and Staff Enrolling Students Log in to ozone.ou.edu. Click the Advising tab. Please lecture schedule CRN ­ Course Reference Number In oZONE the Registration Add Errors will display one

  4. Controls over ozone deposition to a high elevation subalpine forest

    E-Print Network [OSTI]

    Turnipseed, AA; Burns, SP; Moore, DJP; Hu, J; Guenther, AB; Monson, RK

    2009-01-01

    D.L. , Fehsenfeld, F.C. , 1986b. Background ozone andanthropogenic ozone enhancement at Niwot Ridge, Colorado.Day-time variations of ozone eddy ?uxes to maize. Boundary-

  5. Ozone Removal by Filters Containing Activated Carbon: A Pilot Study

    E-Print Network [OSTI]

    Fisk, William

    2012-01-01

    carbon filters for the control of ozone, sulfur dioxide, andMendell (2008). "Outdoor ozone and building-related symptomsAir filter materials, outdoor ozone and building-related

  6. Exposure-Relevant Ozone Chemistry in Occupied Spaces

    E-Print Network [OSTI]

    Coleman, Beverly Kaye

    2009-01-01

    particles produced by ozone/limonene reactions in indoor airgas-phase reactions of ozone with organic compounds underNazaroff, W.W. , 2008. Ozone levels in passenger cabins of

  7. Ozone Standard Exceedance Days in the South San Joaquin Valley

    E-Print Network [OSTI]

    Jan de Leeuw; Shuojun Wang

    2011-01-01

    about the health e?ects of ozone. CES is looking at many8h national std. days OZONE STANDARDS F????? 2. Bakers?eld8h national std. days OZONE STANDARDS Time F????? 4. Shafter

  8. Ozone Standard Exceedance Days in the South San Joaquin Valley

    E-Print Network [OSTI]

    de Leeuw, Jan; Wang, Shuojun

    2007-01-01

    about the health e?ects of ozone. CES is looking at many8h national std. days OZONE STANDARDS F????? 2. Bakers?eld8h national std. days OZONE STANDARDS Time F????? 4. Shafter

  9. Inverting for emissions of carbon monoxide from Asia using aircraft observations over the western Pacific

    E-Print Network [OSTI]

    Palmer, Paul

    Inverting for emissions of carbon monoxide from Asia using aircraft observations over the western 2001), in combination with an optimal estimation inverse model, to improve emission estimates of carbon monoxide (CO) from Asia. A priori emissions and their errors are from a customized bottom-up Asian emission

  10. Quantifying the impact of model errors on topdown estimates of carbon monoxide emissions using satellite observations

    E-Print Network [OSTI]

    Heald, Colette L.

    Quantifying the impact of model errors on topdown estimates of carbon monoxide emissions using use of inverse modeling to better quantify regional surface emissions of carbon monoxide (CO), which to or larger than the combustion source, optimizing the CO from NMVOC emissions on larger spatial scales than

  11. Carbon monoxide (CO) maximum over the Zagros mountains in the Middle East: Signature of mountain venting?

    E-Print Network [OSTI]

    Jones, Dylan

    Carbon monoxide (CO) maximum over the Zagros mountains in the Middle East: Signature of mountain- posphere (MOPITT) satellite instrument. Enhanced CO is observed over the Zagros mountains of Iran), Carbon monoxide (CO) maximum over the Zagros mountains in the Middle East: Signature of mountain venting

  12. First principles study of carbon monoxide adsorption on zirconia-supported copper

    E-Print Network [OSTI]

    Rappe, Andrew M.

    First principles study of carbon monoxide adsorption on zirconia-supported copper Eric J. Walter a of carbon monoxide on a monolayer of copper adsorbed on the (1 1 1) face of cubic zirconia. For the bulk, oxidized and reduced (1 1 1) surfaces of cubic zirconia (c-ZrO2). For adsorption of copper

  13. Discharge cell for ozone generator

    DOE Patents [OSTI]

    Nakatsuka, Suguru (Amagasaki, JP)

    2000-01-01

    A discharge cell for use in an ozone generator is provided which can suppress a time-related reduction in ozone concentration without adding a catalytic gas such as nitrogen gas to oxygen gas as a raw material gas. The discharge cell includes a pair of electrodes disposed in an opposed spaced relation with a discharge space therebetween, and a dielectric layer of a three-layer structure consisting of three ceramic dielectric layers successively stacked on at least one of the electrodes, wherein a first dielectric layer of the dielectric layer contacting the one electrode contains no titanium dioxide, wherein a second dielectric layer of the dielectric layer exposed to the discharge space contains titanium dioxide in a metal element ratio of not lower than 10 wt %.

  14. 5, 58415874, 2005 Ozone/tracer

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 5, 5841­5874, 2005 Ozone/tracer relations in the polar vortex R. M¨uller et al. Title Page Discussions Impact of mixing and chemical change on ozone-tracer relations in the polar vortex R. M¨uller 1 Commons License. 5841 #12;ACPD 5, 5841­5874, 2005 Ozone/tracer relations in the polar vortex R. M¨uller et

  15. 17 October 2014 Antarctic Ozone Bulletin

    E-Print Network [OSTI]

    Toohey, Darin W.

    17 October 2014 Antarctic Ozone Bulletin No 4/2014 Global Atmosphere Watch 0 5 10 0 5 10 15 20 25 30 -80 -60 -40 -20 0 Ushuaia 2014-10-10 Total ozone = 180 DU 14-21 km column = 39 DU 12-20 km column = 53 DU Ozone Temperature ECMWF analysis of PV at 475 K on 2014-10-10 at 12h -65.0 -59.5 -54.0 -48

  16. A fast stratospheric ozone chemistry schemeA fast stratospheric ozone chemistry scheme Michel Bourqui1

    E-Print Network [OSTI]

    Bourqui, Michel

    A fast stratospheric ozone chemistry schemeA fast stratospheric ozone chemistry scheme Michel a computationally efficient chemical scheme, the FAst STratospheric Ozone Chemistry (FASTOC) scheme, which has advantages over many existing fast methods, as it does not rely on relaxation to assumed conditions, does

  17. Method of removing nitrogen monoxide from a nitrogen monoxide-containing gas using a water-soluble iron ion-dithiocarbamate, xanthate or thioxanthate

    DOE Patents [OSTI]

    Liu, D. Kwok-Keung; Chang, Shih-Ger

    1987-08-25

    The present invention relates to a method of removing of nitrogen monoxide from a nitrogen monoxide-containing gas which method comprises contacting a nitrogen oxide-containing gas with an aqueous solution of water soluble organic compound-iron ion chelate complex. The NO absorption efficiency of ferrous urea-dithiocarbamate and ferrous diethanolamine-xanthate as a function of time, oxygen content and solution ph is presented. 3 figs., 1 tab.

  18. Tropospheric Ozone Pollution and Personal Exposure

    E-Print Network [OSTI]

    Toohey, Darin W.

    ://www.nctcog.org/trans/air/ozone/formation.gif #12;Health Effects · Chest pain, coughing, throat irritation, and congestion · Wheezing and difficulty

  19. The NASA Aura satellite houses four instruments to study atmospheric ozone. The Ozone Monitoring Instrument (OMI) onboard the satellite provides global total column ozone (TCO) and in combination

    E-Print Network [OSTI]

    Thompson, Anne

    iii ABSTRACT The NASA Aura satellite houses four instruments to study atmospheric ozone. The Ozone Monitoring Instrument (OMI) onboard the satellite provides global total column ozone (TCO) and in combination with other instruments tropospheric ozone residual (TOR) can be derived. In this study, the trajectory

  20. DOE's Studies of Weekday/Weekend Ozone Pollution in Southern...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Studies of WeekdayWeekend Ozone Pollution in Southern California DOE's Studies of WeekdayWeekend Ozone Pollution in Southern California 2002 DEER Conference Presentation:...

  1. Exposure-Relevant Ozone Chemistry in Occupied Spaces

    E-Print Network [OSTI]

    Coleman, Beverly Kaye

    2009-01-01

    to determine deposition velocity, reaction probability, orOzone level, deposition velocity, reaction probability wereOzone level, deposition velocity, reaction probability were

  2. The Weekend Ozone Effect - The Weekly Ambient Emissions Control...

    Energy Savers [EERE]

    More Documents & Publications WeekendWeekday Ozone Study in the South Coast Air Basin DOE's Studies of WeekdayWeekend Ozone Pollution in Southern California...

  3. Top-down estimate of a large source of atmospheric carbon monoxide associated with fuel combustion in Asia

    E-Print Network [OSTI]

    Palmer, Paul

    Top-down estimate of a large source of atmospheric carbon monoxide associated with fuel combustion modeling methodology, we find that the source of carbon monoxide from fossil-fuel and biofuel combustion source of atmospheric carbon monoxide associated with fuel combustion in Asia, Geophys. Res. Lett., 29

  4. Mechanistical studies on the formation and destruction of carbon monoxide (CO), carbon dioxide (CO2), and carbon trioxide (CO3)

    E-Print Network [OSTI]

    Kaiser, Ralf I.

    Mechanistical studies on the formation and destruction of carbon monoxide (CO), carbon dioxide (CO2 monoxide (CO), carbon dioxide (CO2), and molecular oxygen (O2) with varying carbon-to-oxygen ratios from 1 and destruction pathways of carbon monoxide (CO), carbon dioxide (CO2), and carbon trioxide (CO3

  5. The Impact of Emission and Climate Change on Ozone in the United States under Representative Concentration Pathways (RCPs)

    SciTech Connect (OSTI)

    Gao, Yang; Fu, Joshua S.; Drake, John B.; Lamarque, J.-F.; Liu, Yang

    2013-09-27

    Dynamical downscaling was applied in this study to link the global climate-chemistry model Community Atmosphere Model (CAM-Chem) with the regional models: Weather Research and Forecasting (WRF) Model and Community Multi-scale Air Quality (CMAQ). Two Representative Concentration Pathway (RCP) scenarios (RCP 4.5 and RCP 8.5) were used to evaluate the climate impact on ozone concentrations in 2050s. Ozone concentrations in the lower-mid troposphere (surface to ~300 hPa), from mid- to high latitudes in the Northern Hemisphere (NH), show decreasing trends in RCP 4.5 between 2000s and 2050s, with the largest decrease of 4-10 ppbv occurring in the summer and the fall; and increasing trends (2-12 ppbv) in RCP 8.5 resulting from the increased methane emissions. In RCP 8.5, methane emissions increase by ~60% by the end of 2050s, accounting for more than 90% of ozone increases in summer and fall, and 60-80% in spring and winter. Under the RCP 4.5 scenario, in the summer when photochemical reactions are the most active, the large ozone precursor emissions reduction leads to the greatest decrease of downscaled surface ozone concentrations, ranging from 6 to 10 ppbv. However, a few major cities show ozone increases of 3 to 7 ppbv due to weakened NO titration. Under the RCP 8.5 scenario, in winter, downscaled ozone concentrations increase across nearly the entire continental US in winter, ranging from 3 to 10 ppbv due to increased methane emissions and enhanced stratosphere-troposphere exchange (STE). More intense heat waves are projected to occur by the end of 2050s in RCP 8.5, leading to more than 8 ppbv of the maximum daily 8-hour daily average (MDA8) ozone during the heat wave days than other days; this indicates the dramatic impact heat waves exert on high frequency ozone events.

  6. Methanation of gas streams containing carbon monoxide and hydrogen

    DOE Patents [OSTI]

    Frost, Albert C. (Congers, NY)

    1983-01-01

    Carbon monoxide-containing gas streams having a relatively high concentration of hydrogen are pretreated so as to remove the hydrogen in a recoverable form for use in the second step of a cyclic, essentially two-step process for the production of methane. The thus-treated streams are then passed over a catalyst to deposit a surface layer of active surface carbon thereon essentially without the formation of inactive coke. This active carbon is reacted with said hydrogen removed from the feed gas stream to form methane. The utilization of the CO in the feed gas stream is appreciably increased, enhancing the overall process for the production of relatively pure, low-cost methane from CO-containing waste gas streams.

  7. Size Effect of Ruthenium Nanoparticles in Catalytic Carbon Monoxide Oxidation

    SciTech Connect (OSTI)

    Joo, Sang Hoon; Park, Jeong Y.; Renzas, J. Russell; Butcher, Derek R.; Huang, Wenyu; Somorjai, Gabor A.

    2010-04-04

    Carbon monoxide oxidation over ruthenium catalysts has shown an unusual catalytic behavior. Here we report a particle size effect on CO oxidation over Ru nanoparticle (NP) catalysts. Uniform Ru NPs with a tunable particle size from 2 to 6 nm were synthesized by a polyol reduction of Ru(acac){sub 3} precursor in the presence of poly(vinylpyrrolidone) stabilizer. The measurement of catalytic activity of CO oxidation over two-dimensional Ru NPs arrays under oxidizing reaction conditions (40 Torr CO and 100 Torr O{sub 2}) showed an activity dependence on the Ru NP size. The CO oxidation activity increases with NP size, and the 6 nm Ru NP catalyst shows 8-fold higher activity than the 2 nm catalysts. The results gained from this study will provide the scientific basis for future design of Ru-based oxidation catalysts.

  8. Speeding up Ozone Profile Retrieval using Machine Learning Techniques

    E-Print Network [OSTI]

    Emmerich, Michael

    Speeding up Ozone Profile Retrieval using Machine Learning Techniques L.M. Strijbosch April 25 to the process of ozone profile retrieval, a method for retrieving a global ozone distribution from satellite Machines are selected to replace the forward model, which is the slowest part of ozone profile retrieval

  9. Effects of stratospheretroposphere chemistry coupling on tropospheric ozone

    E-Print Network [OSTI]

    Effects of stratospheretroposphere chemistry coupling on tropospheric ozone Wenshou Tian,1,2 Martyn in both the troposphere and stratosphere. The modeled total column ozone agrees well with Total Ozone Mapping Spectrometer observations. Modeled ozone profiles in the upper troposphere and lower stratosphere

  10. Atmospheric ozone and colors of the Antarctic twilight sky

    E-Print Network [OSTI]

    Lee Jr., Raymond L.

    Atmospheric ozone and colors of the Antarctic twilight sky Raymond L. Lee, Jr.,1, * Wolfgang Meyer absorption at longer wavelengths by ozone's Chappuis bands. Because stratospheric ozone is greatly depleted correlations between ozone concentration and twilight colors. We also used a spectroradiometer at a midlatitude

  11. Part III Research Project Stratosphere-Troposphere Exchange of Ozone

    E-Print Network [OSTI]

    Withers, Paul

    Part III Research Project Stratosphere-Troposphere Exchange of Ozone Observed by Data Assimilation Stratosphere-Troposphere exchange of ozone at tropopause folds is an important process in the atmosphere. Reconstruction of the evolution of ozone at a tropopause fold by conventional means requires synoptic ozone

  12. Tropospheric Ozone Satellite Retrievals in the Pacific Northwest

    E-Print Network [OSTI]

    Collins, Gary S.

    Tropospheric Ozone Satellite Retrievals in the Pacific Northwest Jacqueline Costello1, Farren: Tropospheric ozone is difficult to retrieve from satellites because of the abundance of ozone in the stratosphere. Tropospheric ozone has become a significant environmental issue and can be exacerbated by UT

  13. Ozone Depletion 2. O 3 generation and depletion

    E-Print Network [OSTI]

    Schofield, Jeremy

    Ozone Depletion Outline: 1. O 3 , O 2 evolution 2. O 3 generation and depletion 3. Antarctic ozone 2 converted to ozone via: O 2 h#23; ! 2O #3; O #3; +O 2 ! O 3 + heat #15; O 3 absorbs near #21;#1;l #15; Decreasing l increases transmittance Imagine all ozone in atmosphere forming a thin layer

  14. The Fourth Positive System of Carbon Monoxide in the Hubble Space Telescope Spectra of Comets

    E-Print Network [OSTI]

    Roxana E. Lupu; Paul D. Feldman; Harold A. Weaver; Gian-Paolo Tozzi

    2007-08-22

    The rich structure of the Fourth Positive System (A-X) of carbon monoxide accounts for many of the spectral features seen in long slit HST-STIS observations of comets 153P/Ikeya-Zhang, C/2001 Q4 (NEAT), and C/2000 WM1 (LINEAR), as well as in the HST-GHRS spectrum of comet C/1996 B2 Hyakutake. A detailed CO fluorescence model is developed to derive the CO abundances in these comets by simultaneously fitting all of the observed A-X bands. The model includes the latest values for the oscillator strengths and state parameters, and accounts for optical depth effects due to line overlap and self-absorption. The model fits yield radial profiles of CO column density that are consistent with a predominantly native source for all the comets observed by STIS. The derived CO abundances relative to water in these comets span a wide range, from 0.44% for C/2000 WM1 (LINEAR), 7.2% for 153P/Ikeya-Zhang, 8.8% for C/2001 Q4 (NEAT) to 20.9% for C/1996 B2 (Hyakutake). The subtraction of the CO spectral features using this model leads to the first identification of a molecular hydrogen line pumped by solar HI Lyman-beta longward of 1200A in the spectrum of comet 153P/Ikeya-Zhang. (Abridged)

  15. Ozone Climatologies Figure 1: Ozone climatology for control run in kg/m(a), percentage change in

    E-Print Network [OSTI]

    Feigon, Brooke

    Ozone Climatologies (a) (b) (c) Figure 1: Ozone climatology for control run in kg/m³(a), percentage change in ozone for the perturbed runs; tropopause region (b), whole stratosphere (c). Determining the impact of lower stratospheric ozone depletion on Southern Hemisphere climate Sarah P.E. Keeley and Nathan

  16. Effects of 20002050 changes in climate and emissions on global tropospheric ozone and the policy-relevant background surface ozone

    E-Print Network [OSTI]

    Wu, Shiliang

    Effects of 2000­2050 changes in climate and emissions on global tropospheric ozone and the policy-relevant background surface ozone in the United States Shiliang Wu,1 Loretta J. Mickley,1 Daniel J. Jacob,1 David Rind) on the global tropospheric ozone budget and on the policy-relevant background (PRB) ozone in the United States

  17. Microarray-based analysis of survival of soil microbial community during ozonation

    E-Print Network [OSTI]

    Wang, Jian

    2010-01-01

    3 ] in Ozonation time (h) Ozone BTC TSEM content was used to1. Ozone breakthrough curve (BTC) and TSEM removal during

  18. Exposure to Particulate Matter and Ozone of Outdoor Origin in Singapore

    E-Print Network [OSTI]

    Gall, Elliott T; Chen, Ailu; Chang, Victor; Nazaroff, William W

    2015-01-01

    ulate matter (PM) or ozone, at concentration increments of ~SL, Samet JM, Dominici F. Ozone and short-term mortality inthe penetration of ambient ozone into residential buildings.

  19. LARGE MULTICONFIGURATION SELF-CONSISTENT-FIELD WAVEFUNCTIONS FOR THE OZONE MOLECULE

    E-Print Network [OSTI]

    Schaefer III., Henry F.

    2013-01-01

    theory comparable to that employed here for ozone. HoweverB (cyclopentadiyl) > B (ozone) > B (methylene), based onfor the its state of ozone near geometry. Coefficients of

  20. Modeling Ozone Removal to Indoor Materials, Including the Effects of Porosity, Pore Diameter, and Thickness

    E-Print Network [OSTI]

    Gall, Elliott T; Siegel, Jeffrey A; Corsi, Richard L

    2015-01-01

    of healthy young volunteers to ozone causes cardiovasculareffects of five common ozone-initiated terpene reactiondecay rates, and removal of ozone and their relation to

  1. Stratospheric ozone, global warming, and the principle of unintended consequences - an ongoing science and policy story

    E-Print Network [OSTI]

    2013-01-01

    2008. Learning about ozone depletion. Climatic Change 89(1–and Physics of Stratospheric Ozone. San Diego, CA: AcademicPhotochemical behavior of the ozone layer. Report Number

  2. Ozone photochemical production in urban Shanghai, China: Analysis based on ground level observations

    E-Print Network [OSTI]

    2009-01-01

    of aerosols on surface ozone concentration in Tianjin,W. P. L. (1994), Development of ozone reactivity scales forand M. M. Fox (1953), Ozone formation in photochemical

  3. oZONE Faculty and Staff Exporting and Importing Grades

    E-Print Network [OSTI]

    Oklahoma, University of

    oZONE Faculty and Staff Exporting and Importing Grades Exporting/Importing Grades in oZONE The new - Log in to ozone.ou.edu using your OU Net ID (4+4) as you would in any other OU system. Click Importing Grades from a Exported oZONE template If you exported a course template from the oZONE grading

  4. Method of removing nitrogen monoxide from a nitrogen monoxide-containing gas using a water-soluble iron ion-dithiocarbamate, xanthate or thioxanthate

    DOE Patents [OSTI]

    Liu, David K. (San Pablo, CA); Chang, Shih-Ger (El Cerrito, CA)

    1989-01-01

    A method of removing nitrogen monoxide from a nitrogen monoxide-containing gas, which method comprises: (a) contacting a nitrogen oxide-containing gas with an aqueous solution of water soluble organic compound-iron ion chelate of the formula: ##STR1## wherein the water-soluble organic compound is selected from compounds of the formula: ##STR2## wherein: R is selected from hydrogen or an organic moiety having at least one polar functional group; Z is selected from oxygen, sulfur, or --N--A wherein N is nitrogen and A is hydrogen or lower alkyl having from one to four carbon atoms; and M is selected from hydrogen, sodium or potassium; and n is 1 or 2, in a contacting zone for a time and at a temperature effective to reduce the nitrogen monoxide. These mixtures are useful to provide an unexpensive method of removing NO from gases, thus reducing atmospheric pollution from flue gases.

  5. A role for nickel-iron cofactors in biological carbon monoxide and carbon dioxide utilization

    E-Print Network [OSTI]

    Kung, Yan

    Ni–Fe containing enzymes are involved in the biological utilization of carbon monoxide, carbon dioxide, and hydrogen. Interest in these enzymes has increased in recent years due to hydrogen fuel initiatives and concerns ...

  6. Production of carbon monoxide-free hydrogen and helium from a high-purity source

    DOE Patents [OSTI]

    Golden, Timothy Christopher (Allentown, PA); Farris, Thomas Stephen (Bethlehem, PA)

    2008-11-18

    The invention provides vacuum swing adsorption processes that produce an essentially carbon monoxide-free hydrogen or helium gas stream from, respectively, a high-purity (e.g., pipeline grade) hydrogen or helium gas stream using one or two adsorber beds. By using physical adsorbents with high heats of nitrogen adsorption, intermediate heats of carbon monoxide adsorption, and low heats of hydrogen and helium adsorption, and by using vacuum purging and high feed stream pressures (e.g., pressures of as high as around 1,000 bar), pipeline grade hydrogen or helium can purified to produce essentially carbon monoxide -free hydrogen and helium, or carbon monoxide, nitrogen, and methane-free hydrogen and helium.

  7. NAST-I remote sensing and carbon monoxide Daniel K. Zhoua

    E-Print Network [OSTI]

    Li, Jun

    of methane (CH4), carbon monoxide (CO), and formaldehyde (CH2O), with those of the hydroxyl radical (OH) often show elevated CO and O3, the latter resulting from photochemical production.2 The importance

  8. 5, 90039038, 2005 Ozone in Europe

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    that extensive forest fires on the Iberian Peninsula, resulting from the drought and heat, contributed to the peak ozone values observed in15 North Europe in August. Additionally, forest fires in Siberia probably

  9. Ozone determination in different copying centers 

    E-Print Network [OSTI]

    Lai, Chen-Fu

    1993-01-01

    Photocopying machines have been in existence for forty years: however, few people recognize their potential to create a human health hazard by ozone emission. This study was designed to determine the photocopier's emission rate and evaluate tile...

  10. Name __________________ Lab 8. Air pollution: carbon monoxide & dioxide lab

    E-Print Network [OSTI]

    Perfect, Ed

    and other particles become embedded in the lungs and leads to chronic coughing and lung damage. Carbon

  11. Increasing global agricultural production by reducing ozone damages via methane emission controls and ozone-

    E-Print Network [OSTI]

    Mauzerall, Denise

    Increasing global agricultural production by reducing ozone damages via methane emission controls demonstrate the significant potential to sustainably improve global agricultural production by decreasing O3 degradation poses a major challenge for agricultural production. Because surface ozone (O3) has a significant

  12. INCREASED LEAD ABSORPTION AND LEAD POISONING

    E-Print Network [OSTI]

    INCREASED LEAD ABSORPTION AND LEAD POISONING IN YOUNG CHILDREN A STATDIE:"IT BY THE CEJde slnt:t! the Surgeon GenerJi's Statement. "~edicJI Aspects of Childhood Lead POisoning," was issued:ld absorption Jnd lead poisoning. Such JCtivities for children will continue to be necessary until sources

  13. Carbon monoxide inhalation increases microparticles causing vascular and CNS dysfunction

    SciTech Connect (OSTI)

    Xu, Jiajun; Yang, Ming; Kosterin, Paul; Salzberg, Brian M.; Milovanova, Tatyana N.; Bhopale, Veena M.; Thom, Stephen R.

    2013-12-01

    We hypothesized that circulating microparticles (MPs) play a role in pro-inflammatory effects associated with carbon monoxide (CO) inhalation. Mice exposed for 1 h to 100 ppm CO or more exhibit increases in circulating MPs derived from a variety of vascular cells as well as neutrophil activation. Tissue injury was quantified as 2000 kDa dextran leakage from vessels and as neutrophil sequestration in the brain and skeletal muscle; and central nervous system nerve dysfunction was documented as broadening of the neurohypophysial action potential (AP). Indices of injury occurred following exposures to 1000 ppm for 1 h or to 1000 ppm for 40 min followed by 3000 ppm for 20 min. MPs were implicated in causing injuries because infusing the surfactant MP lytic agent, polyethylene glycol telomere B (PEGtB) abrogated elevations in MPs, vascular leak, neutrophil sequestration and AP prolongation. These manifestations of tissue injury also did not occur in mice lacking myeloperoxidase. Vascular leakage and AP prolongation were produced in naïve mice infused with MPs that had been obtained from CO poisoned mice, but this did not occur with MPs obtained from control mice. We conclude that CO poisoning triggers elevations of MPs that activate neutrophils which subsequently cause tissue injuries. - Highlights: • Circulating microparticles (MPs) increase in mice exposed to 100 ppm CO or more. • MPs are lysed by infusing the surfactant polyethylene glycol telomere B. • CO-induced MPs cause neutrophil activation, vascular leak and CNS dysfunction. • Similar tissue injuries do not arise with MPs obtained from air-exposed, control mice.

  14. Concentration of ozone in surface air over greater Boston

    E-Print Network [OSTI]

    Widen, Donald Allen

    1966-01-01

    Surface ozone concentrations were measured in the Greater Boston area from November, 1964 to December, 1965. Ozone was monitored continuosly using a Mast microcoulombmetric sensor. A chromium trioxide filter was fitted to ...

  15. Weekday and Weekend Air Pollutant Levels in Ozone Problem Areas...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Weekday and Weekend Air Pollutant Levels in Ozone Problem Areas in the U.S. Weekday and Weekend Air Pollutant Levels in Ozone Problem Areas in the U.S. 2005 Diesel Engine Emissions...

  16. Ozone-depleting-substance control and phase-out plan

    SciTech Connect (OSTI)

    Nickels, J.M.; Brown, M.J.

    1994-07-01

    Title VI of the Federal Clean Air Act Amendments of 1990 requires regulation of the use and disposal of ozone-depleting substances (ODSs) (e.g., Halon, Freon). Several important federal regulations have been promulgated that affect the use of such substances at the Hanford Site. On April 23, 1993, Executive Order (EO) 12843, Procurement Requirements and Policies for Federal Agencies for Ozone-Depleting Substances (EPA 1993) was issued for Federal facilities to conform to the new US Environmental Protection Agency (EPA) regulations implementing the Clean Air Act of 1963 (CAA), Section 613, as amended. To implement the requirements of Title VI the US Department of Energy, Richland Operations Office (RL), issued a directive to the Hanford Site contractors on May 25, 1994 (Wisness 1994). The directive assigns Westinghouse Hanford Company (WHC) the lead in coordinating the development of a sitewide comprehensive implementation plan to be drafted by July 29, 1994 and completed by September 30, 1994. The implementation plan will address several areas where immediate compliance action is required. It will identify all current uses of ODSs and inventories, document the remaining useful life of equipment that contains ODS chemicals, provide a phase-out schedule, and provide a strategy that will be implemented consistently by all the Hanford Site contractors. This plan also addresses the critical and required elements of Federal regulations, the EO, and US Department of Energy (DOE) guidance. This plan is intended to establish a sitewide management system to address the clean air requirements.

  17. What is Ozone? Ozone (O3) is a molecule made up of three atoms of oxygen (O), and is mostly found in the strato-

    E-Print Network [OSTI]

    What is Ozone? Ozone (O3) is a molecule made up of three atoms of oxygen (O), and is mostly found it represents only a tiny fraction of the atmosphere, ozone is crucial for life on Earth. Ozone--acts as a shield to protect Earth's surface from the sun's harmful ultraviolet radiation. With- out ozone, the Sun

  18. Ozone uptake by citrus trees exposed to a range of ozone concentrations Silvano Fares a,b,*, Jeong-Hoo Park a

    E-Print Network [OSTI]

    Goldstein, Allen

    Ozone uptake by citrus trees exposed to a range of ozone concentrations Silvano Fares a,b,*, Jeong Received in revised form 26 May 2010 Accepted 2 June 2010 Keywords: Ozone fluxes Citrus Tropospheric ozone climates. In the summer, orchards in California experience high levels of tropospheric ozone, formed

  19. Secondary Pollutants from Ozone Reaction with Ventilation Filters and Degradation of Filter Media Additives

    SciTech Connect (OSTI)

    Destaillats, Hugo; Chen, Wenhao; Apte, Michael; Li, Nuan; Spears, Michael; Almosni, Jérémie; Brunner, Gregory; Zhang, Jianshun (Jensen); Fisk, William J.

    2011-05-01

    Prior research suggests that chemical processes taking place on the surface of particle filters employed in buildings may lead to the formation of harmful secondary byproducts. We investigated ozone reactions with fiberglass, polyester, cotton/polyester and polyolefin filter media, as well as hydrolysis of filter media additives. Studies were carried out on unused media, and on filters that were installed for 3 months in buildings at two different locations in the San Francisco Bay Area. Specimens from each filter media were exposed to {approx}150 ppbv ozone in a flow tube under a constant flow of dry or humidified air (50percent RH). Ozone breakthrough was recorded for each sample over periods of {approx}1000 min; the ozone uptake rate was calculated for an initial transient period and for steady-state conditions. While ozone uptake was observed in all cases, we did not observe significant differences in the uptake rate and capacity for the various types of filter media tested. Most experiments were performed at an airflow rate of 1.3 L/min (face velocity = 0.013 m/s), and a few tests were also run at higher rates (8 to 10 L/min). Formaldehyde and acetaldehyde, two oxidation byproducts, were quantified downstream of each sample. Those aldehydes (m/z 31 and 45) and other volatile byproducts (m/z 57, 59, 61 and 101) were also detected in real-time using Proton-Transfer Reaction - Mass Spectrometry (PTR-MS). Low-ppbv byproduct emissions were consistently higher under humidified air than under dry conditions, and were higher when the filters were loaded with particles, as compared with unused filters. No significant differences were observed when ozone reacted over various types of filter media. Fiberglass filters heavily coated with impaction oil (tackifier) showed higher formaldehyde emissions than other samples. Those emissions were particularly high in the case of used filters, and were observed even in the absence of ozone, suggesting that hydrolysis of additives, rather than ozonolysis, is the main formaldehyde source in those filters. Emission rates of formaldehyde and acetaldehyde were not found to be large enough to substantially increase indoor concentrations in typical building scenarios. Nevertheless, ozone reactions on HVAC filters cannot be ignored as a source of low levels of indoor irritants.

  20. Seasonal ozone variations in the upper mesosphere

    SciTech Connect (OSTI)

    Thomas, R.J. (Univ. of Colorado, Boulder (United States))

    1990-05-20

    The global daytime ozone was measured by the Solar Mesosphere Explorer satellite (SME) for 5 years. The measurements extend through the mesosphere, covering from 50 km to over 90 km. The ozone in the upper mesosphere varies annually by up to a factor of 3. The observed seasonal variations may be summarized in several different ways. From year to year there is a great deal of repeatability of these variations. This repeatability occurs in most of the upper mesosphere outside the tropics. Near 0.01 mbar (80 km) the mid- and high-latitude mixing ratio peaks each year in mid-April. A secondary maximum in the altitude profile of ozone density usually occurs near 85 km. Changes in this structure are directly related to the April maximum and other seasonal changes seen at 0.01 mbar. The changing seasonal structure produces a bump at the ozone mixing ratio minimum that is largest just after spring equinox. This perturbation to the mixing ratio profile seems to move upward during the first half of the year. The seasonal changes of ozone were analyzed in terms of annual and semiannual structure. The variations generally have both an annual and semiannual component depending on altitude and latitude. The phases of the variations change quickly with both altitude and latitude. The semiannual component peaks in April, over most of the upper mesosphere.

  1. Tree and forest effects on air quality and human health in the United David J. Nowak a, *

    E-Print Network [OSTI]

    ). These pollutants are: carbon monoxide (CO), nitrogen dioxide (NO2), ozone (O3), lead (Pb), sulfur dioxide (SO2 by intercepting particles, emitting particles (e.g., pollen) and resuspension of particles captured on the plant

  2. Substantially isotactic, linear, alternating copolymers of carbon monoxide and an olefin

    DOE Patents [OSTI]

    Sen, A.; Jiang, Z.

    1996-05-28

    The compound, [Pd(Me-DUPHOS)(MeCN){sub 2}](BF{sub 4}){sub 2}, [Me-DUPHOS: 1,2-bis(2,5-dimethylphospholano)benzene] is an effective catalyst for the highly enantioselective, alternating copolymerization of olefins, such as aliphatic {alpha}-olefins, with carbon monoxide to form optically active, isotactic polymers which can serve as excellent starting materials for the synthesis of other classes of chiral polymers. For example, the complete reduction of a propylene-carbon monoxide copolymer resulted in the formation of a novel, optically active poly(1,4-alcohol). Also, the previously described catalyst is a catalyst for the novel alternating isomerization cooligomerization of 2-butene with carbon monoxide to form optically active, isotactic poly(1,5-ketone).

  3. Substantially isotactic, linear, alternating copolymers of carbon monoxide and an olefin

    DOE Patents [OSTI]

    Sen, Ayusman (State College, PA); Jiang, Zhaozhong (State College, PA)

    1996-01-01

    The compound, [Pd(Me-DUPHOS)(MeCN).sub.2 ](BF.sub.4).sub.2, [Me-DUPHOS: 1,2-bis(2,5-dimethylphospholano)benzene] is an effective catalyst for the highly enantioselective, alternating copolymerization of olefins, such as aliphatic .alpha.-olefins, with carbon monoxide to form optically active, isotactic polymers which can serve as excellent starting materials for the synthesis of other classes of chiral polymers. For example, the complete reduction of a propylene-carbon monoxide copolymer resulted in the formation of a novel, optically active poly(1,4-alcohol). Also, the previously described catalyst is a catalyst for the novel alternating isomerization cooligomerization of 2-butene with carbon monoxide to form optically active, isotactic poly(1,5-ketone)

  4. Carbon Dioxide in Exoplanetary Atmospheres: Rarely Dominant Compared to Carbon Monoxide and Water

    E-Print Network [OSTI]

    Heng, Kevin

    2015-01-01

    We present a comprehensive study of the abundance of carbon dioxide in exoplanetary atmospheres. We construct analytical models of systems in chemical equilibrium that include carbon monoxide, carbon dioxide, water, methane and acetylene and relate the equilibrium constants of the chemical reactions to temperature and pressure via the tabulated Gibbs free energies. We prove that such chemical systems may be described by a quintic equation for the mixing ratio of methane. By examining the abundances of these molecules across a broad range of temperatures (spanning equilibrium temperatures from 600 to 2500 K), pressures (via temperature-pressure profiles that explore albedo and opacity variations) and carbon-to-oxygen ratios (from 0.1 to 100), we conclude that carbon dioxide is subdominant compared to carbon monoxide and water. Atmospheric mixing does not alter this conclusion if carbon dioxide is subdominant everywhere in the atmosphere. Carbon dioxide and carbon monoxide may attain comparable abundances if th...

  5. Ozone-depleting substances and the greenhouse gases HFCs, PFCs

    E-Print Network [OSTI]

    Ozone-depleting substances and the greenhouse gases HFCs, PFCs and SF6 Danish consumption contribution to the debate on environmental policy in Denmark. #12;3 Contents 1 SUMMARY 5 1.1 OZONE OZONE-DEPLETING SUBSTANCES 19 3.1 IMPORTS AND EXPORTS 19 3.1.1 CFCs 19 3.1.2 Tetrachloromethane 19 3

  6. Southern Hemisphere Additional Ozonesondes (SHADOZ) 19982000 tropical ozone climatology

    E-Print Network [OSTI]

    Thompson, Anne

    Southern Hemisphere Additional Ozonesondes (SHADOZ) 1998­2000 tropical ozone climatology 2; published 31 January 2003. [1] The first view of stratospheric and tropospheric ozone variability in the Southern Hemisphere tropics is provided by a 3-year record of ozone soundings from the Southern Hemisphere

  7. Ozone climatology using interactive chemistry: results from the Canadian

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    Ozone climatology using interactive chemistry: results from the Canadian Middle Atmosphere Model., Medvedev, A. S. and Shepherd, T. G. (2000) Ozone climatology using interactive chemistry: results from RESEARCH, VOL. 105,NO. D21, PAGES 26,475-26,491,NOVEMBER 16, 2000 Ozone climatology using interactive

  8. Chemistry climate model simulations of1 spring Antarctic ozone

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    Chemistry climate model simulations of1 spring Antarctic ozone Article Published Version Austin, J. (2010) Chemistry climate model simulations of spring Antarctic1 ozone. Journal of Geophysical Research ozone John Austin,1,2 H. Struthers,3 J. Scinocca,4 D. A. Plummer,5 H. Akiyoshi,6 A. J. G. Baumgaertner,7

  9. Assigning vibrational polyads using relative equilibria. Application to ozone

    E-Print Network [OSTI]

    Sadovskií, Dmitrií

    Assigning vibrational polyads using relative equilibria. Application to ozone I. N. Kozin a,1 , D equilibria. We use the ozone molecule as a concrete example where n­polyads or ``hyperpolyads'' should structure of the vibrational levels of ozone. We consider the classical mechanical analogue

  10. Using transport diagnostics to understand chemistry climate model ozone

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    Using transport diagnostics to understand chemistry climate model ozone simulations Article chemistry climate model ozone simulations. Journal of Geophysical Research - Atmospheres, 116 (D17). D17302 transport diagnostics to understand chemistry climate model ozone simulations S. E. Strahan,1 A. R. Douglass

  11. A comparison study of data assimilation algorithms for ozone forecasts

    E-Print Network [OSTI]

    Mallet, Vivien

    A comparison study of data assimilation algorithms for ozone forecasts Lin Wu,1,2 V. Mallet,1,2 M assimilation schemes with the aim of designing suitable assimilation algorithms for short- range ozone but stable systems with high uncertainties (e.g., over 20% for ozone daily peaks (Hanna et al., 1998; Mallet

  12. On the statistical modeling of persistence in total ozone anomalies

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    On the statistical modeling of persistence in total ozone anomalies Article Published Version in total ozone anomalies. Journal of Geophysical Research, 115. D16306. ISSN 0148-0227 doi: 10.1029/2009JD the statistical modeling of persistence in total ozone anomalies D. I. Vyushin,1 T. G. Shepherd,1 and V. E

  13. Ozone Chemistry in the High-Latitude Boundary Layer

    E-Print Network [OSTI]

    Toohey, Darin W.

    Ozone Chemistry in the High-Latitude Boundary Layer Linnea Avallone Department of Atmospheric layer ozone loss phenomenon · In situ observations of BrO at Arctic sites · Preliminary results from Antarctic experiments in 2002 and 2004 #12;Brief History · Springtime ozone loss observed at many sites

  14. Effectiveness of Houseplants in Reducing the Indoor Air Pollutant Ozone

    E-Print Network [OSTI]

    Decoteau, Dennis R.

    Effectiveness of Houseplants in Reducing the Indoor Air Pollutant Ozone Heather L. Papinchak1 , E for their species effectiveness in reducing ozone concentrations in a simulated indoor environment. Continuously supply system were used to simulate an indoor environment in which ozone concentrations could be measured

  15. Learning about ozone depletion Paul J. Crutzen & Michael Oppenheimer

    E-Print Network [OSTI]

    Oppenheimer, Michael

    Learning about ozone depletion Paul J. Crutzen & Michael Oppenheimer Received: 12 January 2007 ozone depletion has been much studied as a case history in the interaction between environmental science the photochemistry of ozone in order to illustrate how scientific learning has the potential to mislead policy makers

  16. A global picture of the seasonal persistence of stratospheric ozone

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    A global picture of the seasonal persistence of stratospheric ozone anomalies Article Published persistence of stratospheric ozone anomalies. Journal of Geophysical Research, 115. D18119. ISSN 0148-0227 doi global picture of the seasonal persistence of stratospheric ozone anomalies S. Tegtmeier,1,2 V. E

  17. Ozone Treatments of Fresh Atlantic Cod, Gadus morhua

    E-Print Network [OSTI]

    Ozone Treatments of Fresh Atlantic Cod, Gadus morhua ELINOR M. RAVESI, JOSEPH J. L1CCIARDELLO and LINDA D. RACICOT Introduction The strong oxidizing nature of ozone, known since its discovery in 1840 (1977) cited in a review article numerous reports of the successful use of ozone to I) control microbial

  18. Relative importance of radical families The "Ozone Hole"

    E-Print Network [OSTI]

    Toohey, Darin W.

    · Relative importance of radical families · The "Ozone Hole" · Introduction to heterogeneous chemistry Tuesday, March 8, 2011 #12;Review of important points so far Stratospheric ozone is only produced with these parameters Sir Sydney Chapman nearly got it right. He could account for the formation of the ozone layer

  19. oZONE Faculty and Staff Course Overrides

    E-Print Network [OSTI]

    Oklahoma, University of

    oZONE Faculty and Staff Course Overrides and the Registration Add Errors They Resolve Departments of the overrides within the registration component of oZONE. We have, however, retained a few instances where some. There is also a link to this document on the Student Training and Instructions page in the oZONE info site

  20. Quantum origin of an anomalous isotope effect in ozone formation

    E-Print Network [OSTI]

    Reid, Scott A.

    Quantum origin of an anomalous isotope effect in ozone formation D. Babikov *, B.K. Kendrick, R mechanical calculations of the ðJ ¼ 0Þ energies and lifetimes of the metastable states of ozone on a new effect in the reaction that forms ozone because of their role in the energy transfer mechanism, in which

  1. Southern Hemisphere Additional Ozonesondes (SHADOZ) 19982004 tropical ozone climatology

    E-Print Network [OSTI]

    Thompson, Anne

    Southern Hemisphere Additional Ozonesondes (SHADOZ) 1998­2004 tropical ozone climatology: 3 more than 3000 ozone profiles from 14 tropical and subtropical sites using balloon- borne technique might cause small station-to-station biases in the total ozone measurement. We present further

  2. Summertime total ozone variations over middle and polar latitudes

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    Summertime total ozone variations over middle and polar latitudes Article Published Version Fioletov, V. E. and Shepherd, T. G. (2005) Summertime total ozone variations over middle and polar's research outputs online #12;Summertime total ozone variations over middle and polar latitudes Vitali E

  3. Arctic ozone loss and climate sensitivity: Updated threedimensional model study

    E-Print Network [OSTI]

    Feng, Wuhu

    Arctic ozone loss and climate sensitivity: Updated three­dimensional model study Chipperfield winter­spring chemical ozone loss from 1991 2003, its observed correlation with low temperatures. CTM throughout studied. The model reproduces large column winters also captures shape of ozone loss profile

  4. Southern Hemisphere Additional Ozonesondes (SHADOZ) 19982000 tropical ozone climatology

    E-Print Network [OSTI]

    Thompson, Anne

    Southern Hemisphere Additional Ozonesondes (SHADOZ) 1998­2000 tropical ozone climatology 1. Comparison with Total Ozone Mapping Spectrometer (TOMS) and ground-based measurements Anne M. Thompson,1 Additional Ozonesondes (SHADOZ) project and established from operational sites, provided over 1000 ozone

  5. Constraints on Carbon Monoxide Emissions Based on Tall Tower Measurements in the U.S. Upper Midwest

    E-Print Network [OSTI]

    Minnesota, University of

    Constraints on Carbon Monoxide Emissions Based on Tall Tower Measurements in the U.S. Upper Midwest-up emission estimates in response to top-down constraints. 1. INTRODUCTION Carbon monoxide (CO) is a precursor is emitted during the combustion of biomass and fossil fuel and produced photochemically from the oxidation

  6. The isotopic record of Northern Hemisphere atmospheric carbon monoxide1 since 1950; implications for the CO budget Supplementary Material2

    E-Print Network [OSTI]

    Meskhidze, Nicholas

    1 The isotopic record of Northern Hemisphere atmospheric carbon monoxide1 since 1950 as a supplement to `The isotopic record of Northern Hemisphere23 atmospheric carbon monoxide since 1950 combustion, methane oxidation, NMHC oxidation, biofuel burning, biomass burning, direct57 biogenic

  7. Cyclic process for producing methane from carbon monoxide with heat removal

    DOE Patents [OSTI]

    Frost, Albert C. (Congers, NY); Yang, Chang-lee (Spring Valley, NY)

    1982-01-01

    Carbon monoxide-containing gas streams are converted to methane by a cyclic, essentially two-step process in which said carbon monoxide is disproportionated to form carbon dioxide and active surface carbon deposited on the surface of a catalyst, and said carbon is reacted with steam to form product methane and by-product carbon dioxide. The exothermic heat of reaction generated in each step is effectively removed during each complete cycle so as to avoid a build up of heat from cycle-to-cycle, with particularly advantageous techniques being employed for fixed bed, tubular and fluidized bed reactor operations.

  8. LEAD POISONING PREVENTION INFORMATION

    E-Print Network [OSTI]

    Families AreForever LEAD POISONING PREVENTION INFORMATION FOR PARENTS & PROSPECTIVE-lead levels There is no safe level of lead in the body. Often, symptoms are not obvious, so lead poisoning's medical examination in the U.S. or contact your state or local Childhood Lead Poisoning Prevention Program

  9. The Effects of Gaseous Ozone and Nitric Acid Deposition on two Crustose Lichen Species From Joshua Tree National Park

    E-Print Network [OSTI]

    Hessom, Elizabeth Curie

    2012-01-01

    photosynthetic rate responses to ozone in some foliose andof gaseous nitric acid and ozone on lichens. Dissertations &with nitric acid and ozone. Environmental Pollution, In

  10. Tropospheric column ozone: matching individual profiles from Aura OMI and TES with a chemistry-transport model

    E-Print Network [OSTI]

    Tang, Q.; Prather, M. J

    2012-01-01

    Science Objectives of the Ozone Monitoring In- strument,G. J. , and Logan, J. A. : Ozone climatolog- ical profilestroposphere ex- change ozone flux related to deep

  11. Megacity impacts on regional ozone formation: observations and WRF-Chem modeling for the MIRAGE-Shanghai field campaign

    E-Print Network [OSTI]

    2013-01-01

    Tie, X. : Analysis of ozone and VOCs measured in Shanghai: AMegacity impacts on regional ozone formation terminations inand Tie, X. : Study of ozone “weekend effect” in Shanghai,

  12. Ozone, water vapor, and temperature in the upper tropical troposphere: Variations over a decade of MOZAIC measurements

    E-Print Network [OSTI]

    Bortz, Sarah E; Prather, Michael J; Cammas, Jean-Pierre; Thouret, Valérie; Smit, Herman

    2006-01-01

    An extension of the measurement of ozone and water vapour byin-service Aircraft (MOZAIC) ozone climatologies usingcomparison with SHADOZ ozone and MODIS aerosol, J. Geophys.

  13. Poster Session 08: Bystander and other Low Dose Effect Exogenous carbon monoxide suppresses adaptive response induced

    E-Print Network [OSTI]

    Yu, Peter K.N.

    Poster Session 08: Bystander and other Low Dose Effect Exogenous carbon monoxide suppresses; adaptive response; zebrafish embryos Journal of Radiation Research, 2014, 55, i115 Supplement doi: 10 prepared medium with the chemical at different time points after the application of the priming dose. Our

  14. High Performance Silicon Monoxide (SiO) Electrode for Next Generation Lithium Ion Batteries

    Energy Innovation Portal (Marketing Summaries) [EERE]

    2015-02-27

    Berkeley Lab’s High Performance Silicon Monoxide Electrode has a capacity retention of more than 90% after ~500 cycles, which translates into a ~20% improvement over the limited energy density of conventional graphite anode-based lithium-ion batteries, enabling next-generation mobile electronics and electric/plug-in vehicles....

  15. Effects of exogenous carbon monoxide on radiation-induced bystander effect in zebrafish embryos in vivo

    E-Print Network [OSTI]

    Yu, Peter K.N.

    that the dose-response of radiation in the low-dose regime deviated from the LNT model. A notable example radiation are linearly proportional to the absorbed dose, evidence accumulated in the past decades showed as a pharmaceutical agent to release a low dose of exogenous carbon monoxide (CO) to attenuate the effect on bystander

  16. Crystallization and mutational studies of carbon monoxide dehydrogenase from moorella thermoacetica 

    E-Print Network [OSTI]

    Kim, Eun Jin

    2004-09-30

    Carbon Monoxide Dehydrogenase (CODH), also known as Acetyl-CoA synthase (ACS), is one of seven known Ni containing enzymes. CODH/ACS is a bifunctional enzyme which oxidizes CO to CO2 reversibly and synthesizes acetyl-CoA. Recently, X-ray crystal...

  17. Effect of redox potential, sulfide ions and a persulfide forming cysteine residue on carbon monoxide dehydrogenase 

    E-Print Network [OSTI]

    Feng, Jian

    2005-08-29

    The Ni-Fe-S C-cluster of carbon monoxide dehydrogenases (CODH), which catalyzes the reversible oxidation of CO to CO2, can be stabilized in four redox states: Cox, Cred1, Cint, and Cred2. The best-supported mechanism of catalysis involves a one...

  18. Stochastic resonance in surface catalytic oxidation of carbon monoxide Lingfa Yang, Zhonghuai Hou, and Houwen Xina)

    E-Print Network [OSTI]

    Yang, Lingfa

    Stochastic resonance in surface catalytic oxidation of carbon monoxide Lingfa Yang, Zhonghuai Hou: catalytic oxidation on a single sur- face, by analysis of the behavior of a set of ordinary differ- ential help researchers to find SR in this system experimentally. II. REACTION MODEL The catalytic oxidation

  19. Dissociation and excitation coefficients of nitrogen molecules and nitrogen monoxide generation

    SciTech Connect (OSTI)

    Uhm, Han S.; Na, Young H.; Choi, Eun H.; Cho, Guangsup [Department of Electronic and Biological Physics, Kwangwoon University 447-1 Wolgye-Dong, Nowon-Gu, Seoul 137-701 (Korea, Republic of)] [Department of Electronic and Biological Physics, Kwangwoon University 447-1 Wolgye-Dong, Nowon-Gu, Seoul 137-701 (Korea, Republic of)

    2013-08-15

    The excitation coefficient ?{sub N2} is calculated for the excited metastable level of N{sub 2}(A{sub 3}?{sub u}{sup +}) in nitrogen molecules. In addition, the dissociation coefficient of nitrogen molecules is investigated by making use of the Boltzmann distribution of the electrons in atmospheric plasmas. The excitation and electron-impact dissociation coefficients of nitrogen molecules are analytically expressed in terms of the electron temperature T{sub e} for evaluations of the reactive oxygen and nitrogen species in atmospheric plasmas. As an application example of these coefficients, the nitrogen monoxide generation through a microwave torch is carried out for a development of medical tool. The nitrogen monoxide concentration from a microwave plasma-torch can be easily controlled by the nitrogen flow rate, mole fraction of the oxygen gas, and the microwave power. A simple analytic expression of the nitrogen monoxide concentration is obtained in terms of the oxygen molecular density and gas flow rate. The experimental data agree remarkably well with the theoretical results from the analytical expression. A microwave nitrogen-torch can easily provide an appropriate nitrogen monoxide concentration for the wound healings.

  20. Process for producing methane from gas streams containing carbon monoxide and hydrogen

    DOE Patents [OSTI]

    Frost, Albert C. (Congers, NY)

    1980-01-01

    Carbon monoxide-containing gas streams are passed over a catalyst capable of catalyzing the disproportionation of carbon monoxide so as to deposit a surface layer of active surface carbon on the catalyst essentially without formation of inactive coke thereon. The surface layer is contacted with steam and is thus converted to methane and CO.sub.2, from which a relatively pure methane product may be obtained. While carbon monoxide-containing gas streams having hydrogen or water present therein can be used only the carbon monoxide available after reaction with said hydrogen or water is decomposed to form said active surface carbon. Although hydrogen or water will be converted, partially or completely, to methane that can be utilized in a combustion zone to generate heat for steam production or other energy recovery purposes, said hydrogen is selectively removed from a CO--H.sub.2 -containing feed stream by partial oxidation thereof prior to disproportionation of the CO content of said stream.

  1. Elevated levels of carbon monoxide in the patient compartment of ambulances

    SciTech Connect (OSTI)

    Iglewicz, R.; Rosenman, K.D.; Iglewicz, B.; O'Leary, K.; Hockemeier, R.

    1984-05-01

    Six hundred and ninety New Jersey ambulances were monitored for carbon monoxide (CO); 27 per cent had CO levels of 10 ppm or more greater than ambient air in the breathing zone of the patient. Twenty-nine of these ambulances had levels of at least 35 ppm greater than ambient air. Results indicate that a CO exposure problem exists in ambulances.

  2. Carbon monoxide oxidation on Rh(111): Velocity and angular distributions of the CO2 product

    E-Print Network [OSTI]

    Sibener, Steven

    Carbon monoxide oxidation on Rh(111): Velocity and angular distributions of the CO2 product J. I of surface temperature and oxygen coverage. Both the velocity and angular distributions are bimodal without first accommodating on the surface, the velocity, angular, and internal state distributions may

  3. PREFERENTIAL OXIDATION OF CARBON MONOXIDE IN A THIN-FILM CATALYTIC MICROREACTOR: ADVANTAGES AND LIMITATIONS

    E-Print Network [OSTI]

    Besser, Ronald S.

    PREFERENTIAL OXIDATION OF CARBON MONOXIDE IN A THIN-FILM CATALYTIC MICROREACTOR: ADVANTAGES stream after hydrocarbon fuel reforming and water-gas-shift reactions. This process, referred to as CO intermediate, which enhances the catalytic activity at temperatures below 200°C. With the same catalyst system

  4. Carbon monoxide annealed TiO2 nanotube array electrodes for efficient biosensor applications

    E-Print Network [OSTI]

    Cao, Guozhong

    Carbon monoxide annealed TiO2 nanotube array electrodes for efficient biosensor applications-grown and the O2-annealed TNT array electrodes. The improved biosensor properties of the TiO2 nanotube arrays were, particularly TiO2 nanotubes (TNT), which possess large surface areas, have been widely used as chemical sensors

  5. Submitted to the Annals of Applied Statistics INTERPOLATING FIELDS OF CARBON MONOXIDE

    E-Print Network [OSTI]

    Nychka, Douglas

    . Atmospheric Carbon Monoxide (CO) is an impor- tant trace gas in the atmosphere. It is produced by both natural emissions and human activities and is formed primarily through natural atmospheric oxidation processes fields of CO on short time scales. An observing framework for atmospheric composition that is analogous

  6. SWNT Synthesis by Carbon Monoxide Catalytic Thermal CVD (COCCVD) Method Toshiaki NISHII1,2

    E-Print Network [OSTI]

    Maruyama, Shigeo

    plants. Furthermore, carbon dioxide gas is exhausted from most industrial plants as one of Greenhouse. (2) R. Saito, G. Dresselhaus, M. S. Dresselhaus, Physical Properties of Carbon Nanotubes, (1988 CVD SWNT Synthesis by Carbon Monoxide Catalytic Thermal CVD (COCCVD) Method * Toshiaki

  7. New clean fuel from coal -- Direct dimethyl ether synthesis from hydrogen and carbon monoxide

    SciTech Connect (OSTI)

    Ogawa, T.; Ono, M.; Mizuguchi, M.; Tomura, K.; Shikada, T.; Ohono, Y.; Fujimoto, K.

    1997-12-31

    Dimethyl ether (DME), which has similar physical properties to propane and is easily liquefied at low pressure, has a significant possibility as a clean and non-toxic fuel from coal or coal bed methane. Equilibrium calculation also shows a big advantage of high carbon monoxide conversion of DME synthesis compared to methanol synthesis. By using a 50 kg/day DME bench scale test plant, direct synthesis of DME from hydrogen and carbon monoxide has been studied with newly developed catalysts which are very fine particles. This test plant features a high pressure three-phase slurry reactor and low temperature DME separator. DME is synthesized at temperatures around 533--553 K and at pressures around 3--5 MPa. According to the reaction stoichiometry, the same amount of hydrogen and carbon monoxide react to DME and carbon dioxide. Carbon conversion to DME is one third and the rest of carbon is converted to carbon dioxide. As a result of the experiments, make-up CO conversion is 35--50% on an once-through basis, which is extremely high compared to that of methanol synthesis from hydrogen and carbon monoxide. DME selectivity is around 60 c-mol %. Most of the by-product is CO{sub 2} with a small amount of methanol and water. No heavy by-products have been recognized. Effluent from the reactor is finally cooled to 233--253 K in a DME separator and liquid DME is recovered as a product.

  8. Ozone Reductions using Residential Building Envelopes

    E-Print Network [OSTI]

    for Energy Efficiency and Renewable Energy, Building Technologies Program, of the U.S. Department of Energy Residential Building Envelopes Prepared For: California Energy Commission Public Interest Energy ResearchOzone Reductions using Residential Building Envelopes I.S. Walker, M.H. Sherman and W.W. Nazaroff

  9. Nuclear conflict and ozone depletion Quick summary

    E-Print Network [OSTI]

    Toohey, Darin W.

    Nuclear conflict and ozone depletion Quick summary o Regional nuclear war could cause global which traps pollutants o Nuclear weapons cause explosions, which then causes things around the vicinity to start burning, which in turn releases black carbon; it is not the nuclear material or fallout causing

  10. Eliminating Lead Poisoning

    E-Print Network [OSTI]

    Eliminating Childhood Lead Poisoning: A Federal Strategy Targeting Lead Paint Hazards President Poisoning: A Federal Strategy Targeting Lead Paint Hazards February 2000 President`s Task Force poisoning can be prevented by identifying whether lead hazards in a home are present and by learning how

  11. Relations between isoprene and nitric oxide in exhaled breath and the potential influence of outdoor ozone: a pilot study

    E-Print Network [OSTI]

    Khan, Alya; Staimer, Norbert; Tjoa, Thomas; Galassetti, Pietro; Blake, Donald R.; Delfino, Ralph J.

    2013-01-01

    2-day 3-day 5-day a 12.7 ppb ozone b Adjusted for splines ofoutput after exposure to ozone. J Appl Physiol. 1996; 80:apparatus against ozone damage, quenches ozone products, and

  12. The Effects of Ozone Deposition and Dissolved Organic Matter on Manganese Speciation in the Surface Ocean 

    E-Print Network [OSTI]

    Smyth, Alison Michelle

    2014-07-31

    Despite the known reactivity of ozone (O_(3)) in water and ozone’s environmental importance in the atmosphere, there are relatively few studies published examining the chemistry of O_(3) in seawater. This study focused on ...

  13. Sensitivity analysis of ozone formation and transport for a Central California air pollution episode

    E-Print Network [OSTI]

    Jin, Ling

    2010-01-01

    Vertical distribution of ozone at four sites in the UnitedAltshuler, S. ; Franco, G. Ozone formation in California'sSeinfeld, J. H. Analysis of ozone in the San Joaquin Valley

  14. Reactivity of Ozone with Solid Potassium Iodide Investigated by Atomic Force Microscopy

    E-Print Network [OSTI]

    Brown, Matthew A.

    2008-01-01

    J. C. , Reactivity of ozone on solid potassium iodide.and mechanisms of aqueous ozone reactions with bromide,for Dry Deposition of Ozone to Seawater Surfaces. Journal of

  15. Ground-level ozone influenced by circadian control of isoprene emissions

    E-Print Network [OSTI]

    2011-01-01

    S. The relation between ozone, NO x and hydrocarbons inAmerican emissions on surface ozone in the US. Atmos. Chem.10.1038/NGEO1271 Ground-level ozone influenced by circadian

  16. OZONE INDUCED CONDUCTANCE INCREASES ASSAYED WITH LIPID IMPREGNATED FILTER MEMBRANES-EFFECT OF VITAMIN E

    E-Print Network [OSTI]

    Sheih, P.K

    2011-01-01

    29-44. R. L. Heath (1975) Ozone, in Response of Plants toSince it is possible that ozone absorption "is incompleteof the filter. After the ozone treatment was stopped the

  17. Secondary Pollutants from Ozone Reaction with Ventilation Filters and Degradation of Filter Media Additives

    E-Print Network [OSTI]

    Destaillats, Hugo

    2012-01-01

    used in LBNL, exposed to 150 ppb ozone at two different flowMendell, 2008. Outdoor ozone and building-related symptomsAir filter materials, outdoor ozone and building-related

  18. JOURNAL OF GEOPHYSICAL RESEARCH, VOL. 94, NO. D7, PAGES 9873-9887, JULY 20, 1989 The Sensitivity of Total Ozone and Ozone Perturbation Scenarios

    E-Print Network [OSTI]

    Jackman, Charles H.

    of Total Ozone and Ozone Perturbation Scenarios in a Two-Dimensional Model Due to Dynamical Inputs CHARLESTland The sensitivity of the total ozone distribution in our two-dimensional photochemical model to dynamical inputs has average total ozone varies by up to 10%. dependingon the various dynamical inputs, and the seasonaland

  19. Ozone treatment in a closed culture system for Macrobrachium rosenbergii 

    E-Print Network [OSTI]

    Yamaguchi, Ryoji

    1978-01-01

    periodically and analyzed for total ammonia nitrogen and nitrate nitrogen concentrations using the Direct Nessleriza- tion Method and the Cadmium Reduction Method, respectively (APHA, 1976) . 2. Chemical oxygen demand (COD) and ozonation: The solutions... level. 29 7. Tests of the homogeneity of variance and oneway analysis of variance for the effects of ozonation on two levels of nitrite nitrogen concentration with 95X confidence limit. . . . 31 8. Effects of ozone on ammonia, nitrite, nitrate, COD...

  20. Impact of emissions, chemistry, and climate on atmospheric carbon monoxide : 100-year predictions from a global chemistry-climate model

    E-Print Network [OSTI]

    Wang, Chien.; Prinn, Ronald G.

    The possible trends for atmospheric carbon monoxide in the next 100 yr have been illustrated using a coupled atmospheric chemistry and climate model driven by emissions predicted by a global economic development model. ...

  1. Tropospheric Ozone ATOC/CHEM 5151

    E-Print Network [OSTI]

    Toohey, Darin W.

    ) ( production! #12;18 Ozone production CO + OH CO2 + H loss · Photolysis (1.4 x 1011 cm-2 s-1) · Oxidation of CO (3.5 x 1011 cm-2 s-1) 4. Chemical production #12;23 Formaldehyde chemistry CH2O + h H + HCO H + O2 + M HO2 + M HCO + O2 CO + HO2 2x [HO2

  2. Fundamental differences between Arctic and Antarctic ozone depletion

    E-Print Network [OSTI]

    Solomon, Susan

    Antarctic ozone depletion is associated with enhanced chlorine from anthropogenic chlorofluorocarbons and heterogeneous chemistry under cold conditions. The deep Antarctic “hole” contrasts with the generally weaker depletions ...

  3. Estimating changes in urban ozone concentrations due to life cycle emissions from hydrogen transportation systems

    E-Print Network [OSTI]

    Wang, Guihua; Ogden, Joan M; Chang, Daniel P.Y.

    2007-01-01

    of natural gas to hydrogen pathways on urban air quality.Natural gas (NG); Hydrogen pathways; Ozone formation; Ozone air quality

  4. Ozone depletion, developing countries, and human rights: Seeking better ground on which to fight for protection of the ozone layer

    SciTech Connect (OSTI)

    Williams, V.

    1995-12-31

    I urge you not to take a complacent view of the situation. The state of depletion of the ozone layer continues to be alarming... In February, 1993, the ozone levels over North America and most of Europe were 20 percent below normal... Even now, millions of tons of CFC [chlorofluorocarbon] products are en route to their fatal stratospheric rendezvous... This exponential increase calls for increased reflection on the state of the ozone layer and calls for bold decisions.

  5. Effects on carbon monoxide levels in mobile homes using unvented kerosene heaters for residential heating

    SciTech Connect (OSTI)

    Williams, R.; Walsh, D.; White, J.; Jackson, M.; Mumford, J.

    1992-01-01

    Carbon monoxide (CO) emission levels were continuously monitored in 8 mobile trailer homes less than 10 years old. These homes were monitored in an US EPA study on indoor air quality as affected by unvented portable kerosene heaters. Respondents were asked to operate their heaters in a normal fashion. CO, air exchange and temperature values were measured during the study in each home. Results indicate that consumers using unvented kerosene heaters may be unknowingly exposed to high CO levels without taking proper precautions.

  6. Mechanistical studies on the formation of carbon dioxide in extraterrestrial carbon monoxide ice analog samples

    E-Print Network [OSTI]

    Kaiser, Ralf I.

    Mechanistical studies on the formation of carbon dioxide in extraterrestrial carbon monoxide ice O and 13 C18 O), carbon dioxide (12 C16 O2, 12 C18 O16 O, 12 C18 O2, 13 C16 O2, 13 C18 O16 O, and 13 and of carbon dioxide were extracted and fit to derive reaction mechanisms and information on the decomposition

  7. Carbon monoxide-assisted growth of carbon nanotubes Y.H. Tang a,b

    E-Print Network [OSTI]

    Zheng, Yufeng

    diameter of 30 nm and 20 layers. Nickel was observed in the tips of the nanotubes and played a crucial roleCarbon monoxide-assisted growth of carbon nanotubes Y.H. Tang a,b , Y.F. Zheng a , C.S. Lee a , N was used to synthesize carbon nanotubes (CNTs) in a hot-®lament chemical vapor deposition (HFCVD) system

  8. Generating Energy Efficiency Project Leads and Allocating Leads...

    Energy Savers [EERE]

    Generating Energy Efficiency Project Leads and Allocating Leads to Contractors Generating Energy Efficiency Project Leads and Allocating Leads to Contractors Better Buildings...

  9. Reactive uptake of ozone at simulated leaf surfaces: implications for "non-stomatal" ozone flux 

    E-Print Network [OSTI]

    Cape, J Neil; Hamilton, Richard P; Heal, Mathew R

    2009-01-01

    The reaction of ozone (O3) with ?-pinene has been studied as a function of temperature and relative humidity and in the presence of wax surfaces that simulate a leaf surface. The objective was to determine whether the presence of a wax surface...

  10. Observed relationships of ozone air pollution with temperature and emissions

    E-Print Network [OSTI]

    Stehr, Jeffrey

    Observed relationships of ozone air pollution with temperature and emissions Bryan J. Bloomer,1, and R. R. Dickerson (2009), Observed relationships of ozone air pollution with temperature and emissions decreased by 43% for the time period 1995 to 2002 compared with 2003 to 2006 as a result of air pollution

  11. URBAN OZONE CONCENTRATION FORECASTING WITH ARTIFICIAL NEURAL NETWORK IN CORSICA

    E-Print Network [OSTI]

    Boyer, Edmond

    Perceptron; Ozone concentration. 1. Introduction Tropospheric ozone is a major air pollution problem, both, Ajaccio, France, e-mail: balu@univ-corse.fr Abstract: Atmospheric pollutants concentration forecasting is an important issue in air quality monitoring. Qualitair Corse, the organization responsible for monitoring air

  12. ORIGINAL CONTRIBUTION Ozone and Short-term Mortality

    E-Print Network [OSTI]

    Dominici, Francesca

    . With the National Morbidity, Mortality, and Air Pollution Study (NMMAPS), we have developed na- tional approaches Ambient Air Qual- ity Standard (NAAQS) for ozone, adding a daily maximum 8-hour stan- dard of 80 ppb.19 Because of the relevance of epidemiologic evi- dence to the NAAQS for ozone and other pollutants

  13. Leading neutron spectra

    E-Print Network [OSTI]

    A. B. Kaidalov; V. A. Khoze; A. D. Martin; M. G. Ryskin

    2006-05-27

    It is shown that the observation of the spectra of leading neutrons from proton beams can be a good probe of absorptive and migration effects. We quantify how these effects modify the Reggeized pion-exchange description of the measurements of leading neutrons at HERA. We are able to obtain a satisfactory description of all the features of these data. We also briefly discuss the corresponding data for leading baryons produced in hadron-hadron collisions.

  14. Lead, Communications Specialist

    Broader source: Energy.gov [DOE]

    A successful candidate in this position will: Serve as Lead, Communications Specialist for the Communications Team. Assists the Communications Director in planning, coordinating and implementing...

  15. Theoretical and experimental studies of heterogeneous chemical processes leading to stratospheric ozone depletion

    E-Print Network [OSTI]

    Mantz, Yves André, 1974-

    2002-01-01

    The microscopic chemical mechanisms of heterogeneous reactions involving HC on crystalline ice and nitric acid trihydrate (NAT) are of fundamental interest to physical chemists, because such reactions yield "active" chlorine ...

  16. Lead carbonate scintillator materials

    DOE Patents [OSTI]

    Derenzo, Stephen E. (Pinole, CA); Moses, William W. (Berkeley, CA)

    1991-01-01

    Improved radiation detectors containing lead carbonate or basic lead carbonate as the scintillator element are disclosed. Both of these scintillators have been found to provide a balance of good stopping power, high light yield and short decay constant that is superior to other known scintillator materials. The radiation detectors disclosed are favorably suited for use in general purpose detection and in medical uses.

  17. Modeling Transport E ects on Ground-Level Ozone Using a

    E-Print Network [OSTI]

    Huang, Su-Yun

    Modeling Transport E ects on Ground-Level Ozone Using a Non-Stationary Space-Time Model Hsin on Ground-Level Ozone 1 #12;Summary This article presents a novel autoregressive space-time model for ground-level ozone data, which models not only spatio-temporal dynamics of hourly ozone con- centrations, but also

  18. Simulations of Ozone Distributions in an Aircraft Cabin Using Computational Fluid1 Aakash C. Rai1

    E-Print Network [OSTI]

    Chen, Qingyan "Yan"

    Simulations of Ozone Distributions in an Aircraft Cabin Using Computational Fluid1 Dynamics2 3 10 Ozone is a major pollutant of indoor air. Many studies have demonstrated the adverse health effect of11 ozone and the byproducts generated as a result of ozone-initiated reactive chemistry

  19. Improving total column ozone retrievals by using cloud pressures derived from Raman scattering in the UV

    E-Print Network [OSTI]

    Joiner, Joanna

    Improving total column ozone retrievals by using cloud pressures derived from Raman scattering resolution, coverage, and sampling of the Aura satellite ozone monitoring instrument (OMI), as compared with the total ozone mapping spectrometer (TOMS) should allow for improved ozone retrievals. By default, the TOMS

  20. Passive Ozone Control Through Use of Reactive Indoor Wall and Ceiling Materials

    E-Print Network [OSTI]

    Siegel, Jeffrey

    Passive Ozone Control Through Use of Reactive Indoor Wall and Ceiling Materials Paper # 715 Donna A) Austin, TX 78758, USA ABSTRACT Most ozone exposure occurs indoors even though some surfaces consume ozone and reduce its concentration relative to outdoors. Ozone consumption often results in emissions of secondary

  1. Why are there large differences between models in global budgets of tropospheric ozone?

    E-Print Network [OSTI]

    Wu, Shiliang

    Why are there large differences between models in global budgets of tropospheric ozone? Shiliang Wu for tropospheric ozone. The ozone production rate in the troposphere, P(Ox), varies from 2300 to 5300 Tg yrÀ1 compounds (NMVOCs, mostly biogenic isoprene), and ozone influx from stratosphere-troposphere exchange (STE

  2. An intramolecular theory of the mass-independent isotope effect for ozone. I.

    E-Print Network [OSTI]

    Hathorn, Bryan C.

    An intramolecular theory of the mass-independent isotope effect for ozone. I. B. C. Hathorn and R-independent isotope effect for ozone formation and dissociation is described. The experiments include the enrichment and asymmetric ozone isotopomers, the enrichment of ozone formed from heavily enriched oxygen isotopes

  3. A cohesive total ozone data set from the SBUV(/2) satellite system A. J. Miller,1

    E-Print Network [OSTI]

    Jackman, Charles H.

    A cohesive total ozone data set from the SBUV(/2) satellite system A. J. Miller,1 R. M. Nagatani,1 of total ozone estimates from the Solar Backscatter Ultraviolet Ozone Sensors (SBUVand SBUV/2) began of individual instruments are good, they give total ozone accuracies of approximately 2%. However, without

  4. Ozone hole and Southern Hemisphere climate change Seok-Woo Son,1

    E-Print Network [OSTI]

    Son, Seok-Woo

    Ozone hole and Southern Hemisphere climate change Seok-Woo Son,1 Neil F. Tandon,2 Lorenzo M cooling resulting from ozone depletion has only recently been examined and a comprehensive picture on the stratospheric ozone forcing used, we here show that stratospheric ozone affects the entire atmospheric

  5. PPPL-3281, Preprint: January 1998, UC-426 Synthesis of Ozone at Atmospheric Pressure

    E-Print Network [OSTI]

    in industrial processes is increasing. Applications for ozone include treatment of waste water, water

  6. Essays on the Impact of Climate Change and Building Codes on Energy Consumption and the Impact of Ozone on Crop Yield

    E-Print Network [OSTI]

    Aroonruengsawat, Anin

    2010-01-01

    14 Impact of ozone on crop yield15 Data 15.1 OzoneEstimated effect of mean ozone on crop yields. . . . . . .

  7. Ti{sub 5}O{sub 5} superstructures of cubic titanium monoxide

    SciTech Connect (OSTI)

    Gusev, A. I.

    2013-08-15

    A cubic model is proposed for the Ti{sub 5}O{sub 5} (Ti{sub 5} Black-Small-Square O{sub 5}{open_square} {identical_to} Ti{sub 90} Black-Small-Square {sub 18}O{sub 90}{open_square}{sub 18}) superstructure of nonstoichiometric titanium monoxide Ti{sub x}O{sub z} with double imperfection. The unit cell of the cubic Ti{sub 5}O{sub 5} superstructure has the threefold lattice parameter of the unit cell of the basis disordered B1 structure of Ti{sub x}O{sub z} monoxide and belongs to space group Pm 3-bar m . The channel of the disorder-order transition, i.e., Ti{sub x}O{sub z} (space group Fm 3-bar m)-Ti{sub 5}O{sub 5} (space group Pm 3-bar m), includes 75 superstructure vectors of seven stars (k{sub 10}), (k{sub 7}), (k{sub 6(1)}), (k{sub 6(2)}), (k{sub 4(1)}), (k{sub 4(2)}), and (k{sub 1}). The distribution functions of Ti and O atoms over the sites of the cubic Ti{sub 5}O{sub 5} superstructure are calculated. A comparison of the X-ray and electron diffraction data obtained for ordered TiO{sub 1.087} monoxide with the theoretical simulation results supports the existence of the cubic Ti{sub 5}O{sub 5} superstructure. The cubic (space group Pm 3-bar m) Ti{sub 5}O{sub 5} superstructure is shown to be a high-temperature structure relative to the well-known monoclinic (space group C2/m) superstructure of the same type.

  8. Evaluation of microporous carbon filters as catalysts for ozone decomposition

    SciTech Connect (OSTI)

    Whinnery, L.; Coutts, D.; Shen, C.; Adams, R. [Sandia National Labs., Livermore, CA (United States); Quintana, C.; Showalter, S. [Sandia National Labs., Albuquerque, NM (United States)

    1994-12-31

    Ozone is produced in small quantities in photocopiers and laser printers in the workplace and large quantities in industrial waste water treatment facilities. Carbon filters are commonly used to decompose this unwanted ozone. The three most important factors in producing a filter for this purpose are flow properties, efficiency, and cost. Most ozone decomposition applications require very low back-pressure at modest flow rates. The tradeoff between the number of pores and the size of the pores will be discussed. Typical unfiltered emissions in the workplace are approximately 1 ppm. The maximum permissible exposure limit, PEL, for worker exposure to ozone is 0.1 ppm over 8 hours. Several methods have been examined to increase the efficiency of ozone decomposition. Carbon surfaces were modified with catalysts, the surface activated, and the surface area was increased, in attempts to decompose ozone more effectively. Methods to reduce both the processing and raw material costs were investigated. Several sources of microporous carbon were investigated as ozone decomposition catalysts. Cheaper processing routes including macropore templating, faster drying and extracting methods were also studied.

  9. Lead carbonate scintillator materials

    DOE Patents [OSTI]

    Derenzo, S.E.; Moses, W.W.

    1991-05-14

    Improved radiation detectors containing lead carbonate or basic lead carbonate as the scintillator element are disclosed. Both of these scintillators have been found to provide a balance of good stopping power, high light yield and short decay constant that is superior to other known scintillator materials. The radiation detectors disclosed are favorably suited for use in general purpose detection and in medical uses. 3 figures.

  10. Exposure-Relevant Ozone Chemistry in Occupied Spaces

    SciTech Connect (OSTI)

    Coleman, Beverly Kaye

    2009-04-01

    Ozone, an ambient pollutant, is transformed into other airborne pollutants in the indoor environment. In this dissertation, the type and amount of byproducts that result from ozone reactions with common indoor surfaces, surface residues, and vapors were determined, pollutant concentrations were related to occupant exposure, and frameworks were developed to predict byproduct concentrations under various indoor conditions. In Chapter 2, an analysis is presented of secondary organic aerosol formation from the reaction of ozone with gas-phase, terpene-containing consumer products in small chamber experiments under conditions relevant for residential and commercial buildings. The full particle size distribution was continuously monitored, and ultrafine and fine particle concentrations were in the range of 10 to>300 mu g m-3. Particle nucleation and growth dynamics were characterized.Chapter 3 presents an investigation of ozone reactions with aircraft cabin surfaces including carpet, seat fabric, plastics, and laundered and worn clothing fabric. Small chamber experiments were used to determine ozone deposition velocities, ozone reaction probabilities, byproduct emission rates, and byproduct yields for each surface category. The most commonly detected byproducts included C1?C10 saturated aldehydes and skin oil oxidation products. For all materials, emission rates were higher with ozone than without. Experimental results were used to predict byproduct exposure in the cabin and compare to other environments. Byproduct levels are predicted to be similar to ozone levels in the cabin, which have been found to be tens to low hundreds of ppb in the absence of an ozone converter. In Chapter 4, a model is presented that predicts ozone uptake by and byproduct emission from residual chemicals on surfaces. The effects of input parameters (residue surface concentration, ozone concentration, reactivity of the residue and the surface, near-surface airflow conditions, and byproduct yield) were explored. In Chapter 5, the reaction of ozone with permethrin, a residual insecticide used in aircraft cabins, to form phosgene is investigated. A derivatization technique was developed to detect phosgene at low levels, and chamber experiments were conducted with permethrin-coated cabin materials. It was determined that phosgene formation, if it occurs in the aircraft cabin, is not likely to exceed the relevant, health-based phosgene exposure guidelines.

  11. Thermal device and method for production of carbon monoxide and hydrogen by thermal dissociation of hydrocarbon gases

    DOE Patents [OSTI]

    Detering, Brent A. (Idaho Falls, ID); Kong, Peter C. (Idaho Falls, ID)

    2001-01-01

    Carbon monoxide is produced in a fast quench reactor. The production of carbon monoxide includes injecting carbon dioxide and some air into a reactor chamber having a high temperature at its inlet and a rapidly expanding a reactant stream, such as a restrictive convergent-divergent nozzle at its outlet end. Carbon dioxide and other reactants such as methane and other low molecular weight hydrocarbons are injected into the reactor chamber. Other gas may be added at different stages in the process to form a desired end product and prevent back reactions. The resulting heated gaseous stream is then rapidly cooled by expansion of the gaseous stream.

  12. On the photoelectron velocity-map imaging of lutetium monoxide anion LuO{sup ?}

    SciTech Connect (OSTI)

    Liu, Zhiling; Xie, Hua; Qin, Zhengbo; Cong, Ran; Wu, Xia; Tang, Zichao, E-mail: zctang@dicp.ac.cn; Fan, Hongjun, E-mail: fanhj@dicp.ac.cn [State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 (China)] [State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 (China); Li, Quanjiang [School of Physics and Optoelectronic Technology, and College of Advanced Science and Technology, Dalian University of Technology, Dalian 116024 (China)] [School of Physics and Optoelectronic Technology, and College of Advanced Science and Technology, Dalian University of Technology, Dalian 116024 (China)

    2014-01-21

    We report a combined photoelectron velocity-map imaging spectroscopy and density functional theory investigation on lutetium monoxide anion. Transition between the X {sup 1}?{sup +} anion electronic ground state and the neutral X {sup 2}?{sup +} electronic ground state is observed. Vibrationally resolved spectra were obtained at four different photon energies, providing a wealth of spectroscopic information for the electronic ground states of the anionic lutetium monoxide and corresponding neutral species. Franck-Condon simulations of the ground-state transition are performed to assign vibrational structure in the spectra and to assist in identifying the observed spectral bands. The electronic ground state of LuO{sup ?} is found to have a vibrational frequency of 743 ± 10 cm{sup ?1} and an equilibrium bond length of 1.841 Å. The electron affinity of LuO is measured to be 1.624 ± 0.002 eV. The fundamental frequency of ground-state LuO is estimated to be 839 ± 10 cm{sup ?1}.

  13. Revised UV absorption spectra, ozone depletion potentials, and global warming potentials for the ozone-depleting substances CF2Br2,

    E-Print Network [OSTI]

    Jackman, Charles H.

    Revised UV absorption spectra, ozone depletion potentials, and global warming potentials for the ozone-depleting substances CF2Br2, CF2ClBr, and CF2BrCF2Br Dimitrios K. Papanastasiou,1,2,5 Nabilah. [1] The contribution of Halons, bromine-containing haloalkanes, to stratospheric ozone depletion

  14. Simulating the growth response of aspen to elevated ozone: a mechanistic approach to scaling a leaf-level model of ozone effects

    E-Print Network [OSTI]

    Simulating the growth response of aspen to elevated ozone: a mechanistic approach to scaling a leaf-level model of ozone effects on photosynthesis to a complex canopy architecture§ M.J. Martina, *, G.E. Hosta; accepted 17 July 2001 ``Capsule'': A process model is described that predicts the relative effects of ozone

  15. Global Health and Economic Impacts of Future Ozone Pollution

    E-Print Network [OSTI]

    Webster, Mort D.

    We assess the human health and economic impacts of projected 2000-2050 changes in ozone pollution using the MIT Emissions Prediction and Policy Analysis-Health Effects (EPPA-HE) model, in combination with results from the ...

  16. Assessing Global Terrestrial Sources of Methyl Halides - Ozone Regulating Gases 

    E-Print Network [OSTI]

    Gancarczyk, Maciej

    2010-11-24

    Methyl bromide (CH3Br) and methyl chloride (CH3Cl) play significant roles in the depletion of the stratospheric ozone layer. The vast portion of methyl halide sources and sinks sources and sinks are natural in origin. The ...

  17. Foliar ozone injury and gas exchange among black cherry genotypes

    SciTech Connect (OSTI)

    Kouterick, K.B.; Skelly, J.M.; Fredericksen, T.S.; Kolb, T.E.; Savage, J.E.; Snyder, K.R. (Penn State Univ., University Park, PA (United States))

    1994-06-01

    The effect of differing ozone exposures on seedlings of black cherry genotypes was investigated in northcentral Pennsylvania. Ozone exclusion treatments were administrated to half-sib families R12 and MO-7, and wild-type (WT) grown in open-top chambers. Over the 1993 growing season, left gas exchange and stem volume were related to percentage of foliar ozone injury observed as adaxial stipple. Ozone symptoms decreased significantly with increasing ozone filtration. R12 exhibited the most severe foliar injury, while WT seedlings showed slightly less symptoms. MO-7 had the least amount of foliar injury. No clear trends in stomatal conductance or net photosynthesis were observed until August. During August, foliar injury was positively related to stomatal conductance. Stomatal conductance values were greatest in R12, followed by WT and MO-7. Photosynthesis followed the same pattern at stomatal conductance. Dark respiration rates were variable across treatments for the entire growing season. Differing ozone exposures did not affect stem volume, but stem volume of seedlings of all families in the open plot were significantly lower than seedlings within chambers. Overall, R12 had higher stem volume than MO-7 and WT seedlings.

  18. Grant Reference Lead / Sole

    E-Print Network [OSTI]

    Rank Overall Score Grant Reference Lead / Sole Grant Grant Holder Research Organisation Project of Birmingham Controls on Soil Carbon Export revealed by Novel Tracers on multiple timescales (SCENT) Standard Grant DEC12 8 8 NE/K011871/1 N Melanie Leng NERC British Geological Survey A 500,000-year environmental

  19. Ozone Profile Retrieval from an Advanced Infrared Sounder: Experiments with Tropopause-Based Climatology and Optimal Estimation Approach

    E-Print Network [OSTI]

    Pan, Laura

    Ozone Profile Retrieval from an Advanced Infrared Sounder: Experiments with Tropopause for retrieving atmospheric ozone profile information from advanced satellite infrared sounders, this study investigates various methods to optimize ozone retrievals. A set of retrieval experiments has been performed

  20. Impact of isoprene and HONO chemistry on ozone and OVOC formation in a semirural South Korean forest

    E-Print Network [OSTI]

    2015-01-01

    VOC reactivity and its effect on ozone production during theand HONO chemistry on ozone A. , Molina, L. T. , Nenes, A. ,15/4357/2015/ emissions on ozone concentration during summer

  1. Process for producing hydrogen and carbonyl sulfide from hydrogen sulfide and carbon monoxide using a heteropolyanionic metal complex catalyst

    SciTech Connect (OSTI)

    Kuch, Ph. L.

    1984-12-18

    Hydrogen and carbonyl sulfide are produced by a process comprising contracting gaseous hydrogen sulfide with gaseous carbon monoxide in the presence of a heteropolymolybdate or tungstate complex. Use of these catalysts reduce the amount of by-product carbon dioxide and methane formation and thus enhance the make of hydrogen and carbonyl sulfide.

  2. Combined Crossed Molecular Beam and ab Initio Investigation of the Multichannel Reaction of Boron Monoxide (BO; X2

    E-Print Network [OSTI]

    Kaiser, Ralf I.

    in conventional carbon based jet fuel systems. The combustion of hydrocarbon based fuels can reach temperatures monoxide (11 BO; X2 + ) radical with unsaturated hydrocarbons are of importance in understanding the formation of small boron-oxygen bearing hydrocarbons in boron combustion processes. Over recent decades

  3. Revised and Updated Thermochemical Properties of the Gases Mercapto ,,HS..., Disulfur Monoxide ,,S2O..., Thiazyl ,,NS...,

    E-Print Network [OSTI]

    Fegley Jr., Bruce

    in the 4th edition of the NIST-JANAF Thermochemical Tables. Updated enthalpies of formation were includedRevised and Updated Thermochemical Properties of the Gases Mercapto ,,HS..., Disulfur Monoxide ,,S2 to compute the thermochemical tables for four ideal gases: mercapto HS , disulfur monox- ide (S2O), thiazyl

  4. ADVANCED OXIDATION: OXALATE DECOMPOSITION TESTING WITH OZONE

    SciTech Connect (OSTI)

    Ketusky, E.; Subramanian, K.

    2012-02-29

    At the Savannah River Site (SRS), oxalic acid is currently considered the preferred agent for chemically cleaning the large underground Liquid Radioactive Waste Tanks. It is applied only in the final stages of emptying a tank when generally less than 5,000 kg of waste solids remain, and slurrying based removal methods are no-longer effective. The use of oxalic acid is preferred because of its combined dissolution and chelating properties, as well as the fact that corrosion to the carbon steel tank walls can be controlled. Although oxalic acid is the preferred agent, there are significant potential downstream impacts. Impacts include: (1) Degraded evaporator operation; (2) Resultant oxalate precipitates taking away critically needed operating volume; and (3) Eventual creation of significant volumes of additional feed to salt processing. As an alternative to dealing with the downstream impacts, oxalate decomposition using variations of ozone based Advanced Oxidation Process (AOP) were investigated. In general AOPs use ozone or peroxide and a catalyst to create hydroxyl radicals. Hydroxyl radicals have among the highest oxidation potentials, and are commonly used to decompose organics. Although oxalate is considered among the most difficult organic to decompose, the ability of hydroxyl radicals to decompose oxalate is considered to be well demonstrated. In addition, as AOPs are considered to be 'green' their use enables any net chemical additions to the waste to be minimized. In order to test the ability to decompose the oxalate and determine the decomposition rates, a test rig was designed, where 10 vol% ozone would be educted into a spent oxalic acid decomposition loop, with the loop maintained at 70 C and recirculated at 40L/min. Each of the spent oxalic acid streams would be created from three oxalic acid strikes of an F-area simulant (i.e., Purex = high Fe/Al concentration) and H-area simulant (i.e., H area modified Purex = high Al/Fe concentration) after nearing dissolution equilibrium, and then decomposed to {le} 100 Parts per Million (ppm) oxalate. Since AOP technology largely originated on using ultraviolet (UV) light as a primary catalyst, decomposition of the spent oxalic acid, well exposed to a medium pressure mercury vapor light was considered the benchmark. However, with multi-valent metals already contained in the feed, and maintenance of the UV light a concern; testing was conducted to evaluate the impact from removing the UV light. Using current AOP terminology, the test without the UV light would likely be considered an ozone based, dark, ferrioxalate type, decomposition process. Specifically, as part of the testing, the impacts from the following were investigated: (1) Importance of the UV light on the decomposition rates when decomposing 1 wt% spent oxalic acid; (2) Impact of increasing the oxalic acid strength from 1 to 2.5 wt% on the decomposition rates; and (3) For F-area testing, the advantage of increasing the spent oxalic acid flowrate from 40 L/min (liters/minute) to 50 L/min during decomposition of the 2.5 wt% spent oxalic acid. The results showed that removal of the UV light (from 1 wt% testing) slowed the decomposition rates in both the F & H testing. Specifically, for F-Area Strike 1, the time increased from about 6 hours to 8 hours. In H-Area, the impact was not as significant, with the time required for Strike 1 to be decomposed to less than 100 ppm increasing slightly, from 5.4 to 6.4 hours. For the spent 2.5 wt% oxalic acid decomposition tests (all) without the UV light, the F-area decompositions required approx. 10 to 13 hours, while the corresponding required H-Area decompositions times ranged from 10 to 21 hours. For the 2.5 wt% F-Area sludge, the increased availability of iron likely caused the increased decomposition rates compared to the 1 wt% oxalic acid based tests. In addition, for the F-testing, increasing the recirculation flow rates from 40 liter/minute to 50 liter/minute resulted in an increased decomposition rate, suggesting a better use of ozone.

  5. Chapter 1 Childhood Lead Poisoning Childhood Lead Poisoning

    E-Print Network [OSTI]

    Chapter 1 Childhood Lead Poisoning 1 Childhood Lead Poisoning in the United States The problem of childhood lead poisoning. Child- hood lead poisoning is a major, preventable environmental health problem in the United States before 1978 still contain some lead- ScreeningfYoungfChildrenf orfLeadfPoisoning 13 #12

  6. Projections of Future Summertime Ozone over the U.S.

    SciTech Connect (OSTI)

    Pfister, G. G.; Walters, Stacy; Lamarque, J. F.; Fast, Jerome D.; Barth, Mary; Wong, John; Done, James; Holland, Greg; Bruyere, Cindy

    2014-05-05

    This study uses a regional fully coupled chemistry-transport model to assess changes in surface ozone over the summertime U.S. between present and a 2050 future time period at high spatial resolution (12 km grid spacing) under the SRES A2 climate and RCP8.5 anthropogenic pre-cursor emission scenario. The impact of predicted changes in climate and global background ozone is estimated to increase surface ozone over most of the U.S; the 5th - 95th percentile range for daily 8-hour maximum surface ozone increases from 31-79 ppbV to 30-87 ppbV between the present and future time periods. The analysis of a set of meteorological drivers suggests that these mostly will add to increasing ozone, but the set of simulations conducted does not allow to separate this effect from that through enhanced global background ozone. Statistically the most robust positive feedbacks are through increased temperature, biogenic emissions and solar radiation. Stringent emission controls can counteract these feedbacks and if considered, we estimate large reductions in surface ozone with the 5th-95th percentile reduced to 27-55 ppbV. A comparison of the high-resolution projections to global model projections shows that even though the global model is biased high in surface ozone compared to the regional model and compared to observations, both the global and the regional model predict similar changes in ozone between the present and future time periods. However, on smaller spatial scales, the regional predictions show more pronounced changes between urban and rural regimes that cannot be resolved at the coarse resolution of global model. In addition, the sign of the changes in overall ozone mixing ratios can be different between the global and the regional predictions in certain regions, such as the Western U.S. This study confirms the key role of emission control strategies in future air quality predictions and demonstrates the need for considering degradation of air quality with future climate change in emission policy making. It also illustrates the need for high resolution modeling when the objective is to address regional and local air quality or establish links to human health and society.

  7. Morphological basis of tolerance to ozone

    SciTech Connect (OSTI)

    Evans, M.J.; Dekker, N.P.; Cabral-Anderson, L.J.; Shami, S.G.

    1985-06-01

    The purpose of this research was to study Type 1 epithelial cells in the ozone (O/sub 3/)-tolerant lung epithelium. Rats were made tolerant by exposure to 0.5 ppm O/sub 3/ for 2 days and allowed to recover in air. Reexposure to a lethal concentration of O/sub 3/ (6 ppm) at 3, 7, and 15 days of recovery revealed that tolerance was present at 3 days but almost absent at 7 and 15 days of recovery. Using Type 2 cell proliferation as a means of quantitating Type 1 cell injury, it was observed that when the preexposed rats were reexposed to 0.5 ppm at 3, 7, and 15 days, very little Type 1 cell injury occurred at 3 days. However, at 7 and 15 days the amount of Type 1 cell injury was the same as that associated with the original exposure. To determine whether there was any change in the alveolar epithelial cell populations between the periods of tolerance (3 days) and its decline (7 and 15 days), the percentage of tritiated thymidine (( /sup 3/H)TdR-labeled Type 1 and 2 cells at these times were determined. There was a significant decrease in (/sup 3/H)TdR-labeled Type 1 and 2 cells between the third and fifteenth days of recovery as excess cells were sloughed off and the tissue returned to normal. Using electron microscopic morphometry, Type 1 and 2 cells were then studied during the decline of tolerance. No change was found in the morphology of Type 2 cells; however, the morphology of Type 1 cells revealed a 58% decrease in surface area and a 25% increase in the arithmetic mean thickness when tolerance was present at 3 days. As tolerance declined (7 and 15 days), Type 1 cell morphology returned to normal. It was concluded that tolerance exists when the surface area of a cell exposed to a particular concentration of ozone is small enough so that the existing antioxidant mechanism contained within that cell volume can protect it from damage.

  8. Will Monetized Carbon Emission Reductions Buy Enhanced Building Operations? 

    E-Print Network [OSTI]

    Millhone, J.

    2007-01-01

    transportation arteries and thus are capable of measuring impacts from mobile sources as well as stationary sources. Monitoring is performed to measure the criteria pollutants (sulfur dioxide, carbon monoxide, oxides of nitrogen, lead, particulate matter.... Monitoring is performed to measure the criteria pollutants (sulfur dioxide, carbon monoxide, oxides of nitrogen, lead, particulate matter, and ozone) as well as meteorological parameters (wind speed, wind direction, wind direction variance, temperature, net...

  9. Toolbox Safety Talk Lead Awareness

    E-Print Network [OSTI]

    Pawlowski, Wojtek

    Toolbox Safety Talk Lead Awareness Environmental Health & Safety Facilities Safety & Health Section Health & Safety for recordkeeping. Lead based paint is commonly found in homes built before 1978 and many industrial paints today still contain lead. Lead overexposure is one of the leading causes of workplace

  10. The Cost of Crop Damage Caused by Ozone Air Pollution From Motor Vehicles

    E-Print Network [OSTI]

    Murphy, James; Delucchi, Mark; McCubbin, Donald; Kim, H.J.

    1999-01-01

    Effects of Motor-Vehicle Air Pollution. UCD-ITS-RR-96-3 (by Ozone Air Pollution from Motor-Vehicles. UCD- ITS-RR-96-by ozone air pollution from motor vehicles J. J. Murphy†?,

  11. Past changes in the vertical distribution of ozone – Part 3: Analysis and interpretation of trends

    E-Print Network [OSTI]

    Harris, N. R. P.; Hassler, B.; Tummon, F.; Bodeker, G. E.; Hubert, D.; Petropavlovskikh, I.; Steinbrecht, W.; Anderson, J.; Bhartia, P. K.; Boone, C. D.; Bourassa, A.; Davis, S. M.; Degenstein, D.; Delcloo, A.; Frith, S. M.; Froidevaux, L.; Godin-Beekmann, S.; Jones, N.; Kurylo, M. J.; Kyrölä, E.; Laine, M.; Leblanc, S. T.; Lambert, J.-C.; Liley, B.; Mahieu, E.; Maycock, A.; de Mazière, M.; Parrish, A.; Querel, R.; Rosenlof, K. H.; Roth, C.; Sioris, C.; Staehelin, J.; Stolarski, R. S.; Stübi, R.; Tamminen, J.; Vigouroux, C.; Walker, K.; Wang, H. J.; Wild, J.; Zawodny, J. M.

    2015-03-23

    Trends in the vertical distribution of ozone are reported and compared for a number of new and recently revised datasets. The amount of ozone-depleting compounds in the stratosphere (as measured by Equivalent Effective Stratospheric Chlorine – EESC...

  12. Ozone-Based Atomic Layer Deposition of Crystalline V2O5Films...

    Office of Scientific and Technical Information (OSTI)

    Ozone-Based Atomic Layer Deposition of Crystalline V2O5Films for High Performance Electrochemical Energy Storage Citation Details In-Document Search Title: Ozone-Based Atomic Layer...

  13. Modeling Ozone Removal to Indoor Materials, Including the Effects of Porosity, Pore Diameter, and Thickness

    E-Print Network [OSTI]

    Gall, Elliott T; Siegel, Jeffrey A; Corsi, Richard L

    2015-01-01

    C. Ozone deposition velocities, reaction probabilities andreaction phenomena described by a single parameter, the ozone deposition velocity,velocity, v t (m h ?1 ), a characteristic of the ?uid mechanics of a space, and the reaction

  14. Weekend/Weekday Ozone Study in the South Coast Air Basin | Department...

    Energy Savers [EERE]

    Ozone Effect - The Weekly Ambient Emissions Control Experiment Weekday and Weekend Air Pollutant Levels in Ozone Problem Areas in the U.S. DOE's Studies of WeekdayWeekend...

  15. A global inventory of ecosystem sources of methyl bromide, an ozone destroying gas 

    E-Print Network [OSTI]

    Fenney, Gareth

    2008-12-11

    Stratospheric ozone depletion is affected by halogen radicals, such as bromine, which is 40 times more effective at depleting ozone than chlorine. Methyl bromide, the largest contributor of bromine to the stratosphere is ...

  16. Cardiovascular effects of lead exposure.

    E-Print Network [OSTI]

    Vaziri, N D; Gonick, H C

    2008-01-01

    air quality standards for lead exposure, 2006. ReferencesM, Wen SW. Environmental lead level and pregnancy-inducedDong W, Poulter N. Blood lead and blood pressure: evidence

  17. Cardiovascular effects of lead exposure.

    E-Print Network [OSTI]

    Vaziri, N D; Gonick, H C

    2008-01-01

    Ding Y. Effect of lead on nitric oxide synthase expressionND. Lead-induced hypertension: interplay of nitric oxide andZ. Nitric oxide synthase expression in the course of lead-

  18. Effect of ozonation on the composition of crude coal-tar benzene

    SciTech Connect (OSTI)

    Semenova, S.A.; Patrakov, Y.F.

    2007-05-15

    The effect of ozonation on the composition of crude benzene produced by the coal-tar chemical industry was studied.

  19. THE FILTERING OF OZONE CONCENTRATION MEASUREMENTS COLLECTED IN A TURBULENT AIR STREAM USING BAYESIAN MODELS

    E-Print Network [OSTI]

    West, Mike

    THE FILTERING OF OZONE CONCENTRATION MEASUREMENTS COLLECTED IN A TURBULENT AIR STREAM USING University. The authors thank Alex Guenther for supplying the high frequency ozone concentration measurements a multiscale Bayesian model for separating ozone (O 3 ) concentration turbulent fluctuations from such inherent

  20. EVIDENCE OF ELEVATED OZONE CONCENTRATIONS ON FORESTED SLOPES OF THE LOWER FRASER VALLEY, BRITISH

    E-Print Network [OSTI]

    McKendry, Ian

    EVIDENCE OF ELEVATED OZONE CONCENTRATIONS ON FORESTED SLOPES OF THE LOWER FRASER VALLEY, BRITISH, hourly average ozone concentrations were mea- sured at three sites of differing elevation (188, 588. Sites experienced ozone concentrations ranging from 0 to 88 ppb in 2001, and 0 to 96 ppb in 2002. Daily

  1. Effect of stratosphere-troposphere exchange on the future tropospheric ozone trend

    E-Print Network [OSTI]

    Effect of stratosphere-troposphere exchange on the future tropospheric ozone trend W. J. Collins, R of circulation changes in a changed climate on the exchange of ozone between the stratosphere and the troposphere. We have identified an increase in the net transport of ozone into the troposphere in the future

  2. The ozone response to ENSO in Aura satellite measurements and a chemistry-climate simulation

    E-Print Network [OSTI]

    Waugh, Darryn W.

    The ozone response to ENSO in Aura satellite measurements and a chemistry-climate simulation Luke D impact on tropospheric circulation causes significant changes to the distribution of ozone. Here we derive the lower tropospheric to lower stratospheric ozone response to ENSO from observations

  3. How Bromate and Ozone Concentrations can be Modelled at Full Scale

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 How Bromate and Ozone Concentrations can be Modelled at Full Scale based on Lab-Scale Experiments ­ A Case Study Running head title How to model bromate & ozone at full scale based on lab tests Pierre-scale modelling study of an industrial ozonation unit for practical application. The modelling framework combines

  4. Ozone-depleting substances and the greenhouse gases HFCs, PFCs and

    E-Print Network [OSTI]

    Ozone-depleting substances and the greenhouse gases HFCs, PFCs and SF6 Danish consumption contribution to the debate on environmental policy in Denmark. #12;3 Contents 1 SUMMARY 5 1.1 OZONE OZONE-DEPLETING SUBSTANCES 18 3.1 IMPORTS AND EXPORTS 18 3.1.1 CFCs 18 3.1.2 Tetrachloromethane 19 3

  5. Technical note Barriers and opportunities for passive removal of indoor ozone

    E-Print Network [OSTI]

    Siegel, Jeffrey

    Technical note Barriers and opportunities for passive removal of indoor ozone Elliott T. Gall presents a Monte Carlo simulation to assess passive removal materials (PRMs) that remove ozone of homes in Houston, Texas, were taken from the literature and combined with back- ground ozone removal

  6. Ground-level ozone in the 21st century: future trends,

    E-Print Network [OSTI]

    Ground-level ozone in the 21st century: future trends, impacts and policy implications October 2008. Courtesy of Dr Mhairi Coyle, CEH Edinburgh. #12;Ground-level ozone in the 21st century: future trends Limited #12;Ground-level ozone in the 21st century I October 2008 I iiiThe Royal Society Ground

  7. Pilot Scale Study of Excess Sludge Production Reduction in Wastewater Treatment by Ozone

    E-Print Network [OSTI]

    Barthelat, Francois

    Pilot Scale Study of Excess Sludge Production Reduction in Wastewater Treatment by Ozone Yuan Ma-scale reactors were operated at the LaPrairie Wastewater Treatment plant (one control and one ozonated) to investigate the sludge reduction potential of partially ozonating sludge return activated sludge (RAS

  8. 1 Ozone pollution forecasting 3 Herve Cardot, Christophe Crambes and Pascal Sarda.

    E-Print Network [OSTI]

    Crambes, Christophe

    Contents 1 Ozone pollution forecasting 3 Herv´e Cardot, Christophe Crambes and Pascal Sarda. 1;1 Ozone pollution forecasting using conditional mean and conditional quantiles with functional covariates Herv´e Cardot, Christophe Crambes and Pascal Sarda. 1.1 Introduction Prediction of Ozone pollution

  9. Formation of ozone: Metastable states and anomalous isotope effect Dmitri Babikov,a)

    E-Print Network [OSTI]

    Reid, Scott A.

    Formation of ozone: Metastable states and anomalous isotope effect Dmitri Babikov,a) Brian K for an anomalous isotope effect in ozone formation is given in terms of the energy transfer mechanism, where the metastable states of ozone are formed first, and then stabilized by collisions with other atoms. Unusual

  10. A review of statistical methods for the meteorological adjustment of tropospheric ozone

    E-Print Network [OSTI]

    Washington at Seattle, University of

    A review of statistical methods for the meteorological adjustment of tropospheric ozone Mary Lou adjustment of tropospheric ozone Mary Lou Thompson1 Joel Reynolds1 Lawrence H. Cox2 Peter Guttorp1 Paul D.larry@epamail.epa.gov ABSTRACT: A variety of statistical methods for meteorological adjustment of ozone have been proposed

  11. Ozone deposition to an orange orchard: Partitioning between stomatal and non-stomatal sinks

    E-Print Network [OSTI]

    Goldstein, Allen

    Ozone deposition to an orange orchard: Partitioning between stomatal and non-stomatal sinks Silvano January 2012 Keywords: Orange plants Ozone flux Stomatal deposition Non-stomatal deposition BVOC a b s t r a c t Orange trees are widely cultivated in regions with high concentrations of tropospheric ozone

  12. JOURNAL OF GEOPHYSICAL RESEARCH, VOL. , NO. , PAGES 1?? , Analysis of 19701995 Trends in Tropospheric Ozone at

    E-Print Network [OSTI]

    Jacob, Daniel J.

    in Tropospheric Ozone at Northern Hemisphere Midlatitudes with the GEOS­CHEM Model Andrew C. Fusco Department. The causes of trends in tropospheric ozone at Northern Hemisphere mid­ latitudes from 1970 to 1995 to investigate the sensitivity of tropospheric ozone with respect to (1) changes in the anthropogenic emission

  13. Impact of sudden Arctic sea-ice loss on stratospheric polar ozone recovery

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    Impact of sudden Arctic sea-ice loss on stratospheric polar ozone recovery Article Published.G. and Ravishankara, A.R. (2009) Impact of sudden Arctic sea-ice loss on stratospheric polar ozone recovery's research outputs online #12;Impact of sudden Arctic sea-ice loss on stratospheric polar ozone recovery J. F

  14. A Comparison of Bayesian and Conditional Density Models in Probabilistic Ozone Forecasting

    E-Print Network [OSTI]

    Hsieh, William

    A Comparison of Bayesian and Conditional Density Models in Probabilistic Ozone Forecasting Song Cai to provide predictive distributions of daily maximum surface level ozone concentrations. Five forecast models forecasts for extreme events, namely poor air quality events defined as having ozone concentration 82 ppb

  15. Projections of UV radiation changes in the 21st century: impact of ozone recovery

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    Projections of UV radiation changes in the 21st century: impact of ozone recovery and cloud effects radiation changes in the 21st century: impact of ozone recovery and cloud effects. Atmospheric Chemistry Chemistry and Physics Projections of UV radiation changes in the 21st century: impact of ozone recovery

  16. Tropospheric ozone reduces carbon assimilation in trees: estimates from analysis of continuous flux measurements

    E-Print Network [OSTI]

    Goldstein, Allen

    Tropospheric ozone reduces carbon assimilation in trees: estimates from analysis of continuous flux Abstract High ground-level ozone concentrations are typical of Mediterranean climates. Plant exposure to this oxidant is known to reduce carbon assimilation. Ozone damage has been traditionally measured through

  17. ATOC/CHEM 5151 Problem 10 Energetics of the Photolysis of Ozone

    E-Print Network [OSTI]

    Toohey, Darin W.

    ATOC/CHEM 5151 ­ Problem 10 Energetics of the Photolysis of Ozone Answers will be posted Thursday, October 9, 2014 Photolysis of ozone is important in the formation of the OH radical throughout much standard enthalpy tables to determine the bond strength of ozone (i.e., heat of reaction O + O2 O3) 105 k

  18. Quantifying stratospheric ozone response to changes in methane and nitrous oxide

    E-Print Network [OSTI]

    Bourqui, Michel

    Quantifying stratospheric ozone response to changes in methane and nitrous oxide concentrations of Ozone destruction and creation at different altitudes and concentrations of CH4 and N2O #12;Contents levels have varying conditions and are governed by different chemical regimes We will simulate ozone

  19. Tropospheric ozone climatology over Irene, South Africa, from 1990 to 1994 and 1998 to 2002

    E-Print Network [OSTI]

    Thompson, Anne

    Tropospheric ozone climatology over Irene, South Africa, from 1990 to 1994 and 1998 to 2002 R. D the characteristic Southern Hemisphere springtime tropospheric ozone maximum, but its seasonal features are modulated anticyclonic gyre over southern Africa permit the buildup of relatively high springtime midtropospheric ozone

  20. Tropical ozone as an indicator of deep convection Ian Folkins and Christopher Braun

    E-Print Network [OSTI]

    Folkins, Ian

    Tropical ozone as an indicator of deep convection Ian Folkins and Christopher Braun Department] The climatological ozone profile in the tropics is shaped like an ``S,'' with a minimum at the surface, a maximum. These features can be reproduced by a very simple model whose only free parameter is the mean ozone mixing ratio

  1. PublishedbyManeyPublishing(c)IOMCommunicationsLtd Influence of UV irradiation and ozone on

    E-Print Network [OSTI]

    PublishedbyManeyPublishing(c)IOMCommunicationsLtd Influence of UV irradiation and ozone. Kelly*1 The corrosion of Ag in an atmosphere of ozone and humidity with or without irradiation corrosion product to chloride in the reduction solution. The presence of both ozone and UV radiation

  2. Photochemical template removal and spatial patterning of zeolite MFI thin films using UV/ozone treatment

    E-Print Network [OSTI]

    Parikh, Atul N.

    Photochemical template removal and spatial patterning of zeolite MFI thin films using UV/ozone (structure code: MFI) following a previously published procedure. The films were illuminated using an ozone. Results presented here indicate that the UV/ozone treatment under nominally room temperature conditions

  3. Evaluating Ozone Air Pollution Effects on Pines in the Western United States

    E-Print Network [OSTI]

    Evaluating Ozone Air Pollution Effects on Pines in the Western United States United States. Evaluating ozone air pollution effects on pines in the western United States. Gen. Tech. Rep. PSW­GTR­155. Historical and technical background is provided about ozone air pollution effects on ponderosa (Pinus

  4. Ensemble-based air quality forecasts: A multimodel approach applied to ozone

    E-Print Network [OSTI]

    Mallet, Vivien

    Ensemble-based air quality forecasts: A multimodel approach applied to ozone Vivien Mallet1 21 September 2006. [1] The potential of ensemble techniques to improve ozone forecasts ozone-monitoring networks. We found that several linear combinations of models have the potential

  5. The potential to narrow uncertainty in projections of stratospheric ozone over the

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    The potential to narrow uncertainty in projections of stratospheric ozone over the 21st century of stratospheric ozone over the 21st century. Atmospheric Chemistry and Physics, 10 (19). pp. 9473-9486. ISSN 1680 of stratospheric ozone over the 21st century A. J. Charlton-Perez1, E. Hawkins1, V. Eyring2, I. Cionni2, G. E

  6. Ozone depletion during the solar proton events of October//November 2003 as seen by SCIAMACHY

    E-Print Network [OSTI]

    Jackman, Charles H.

    Ozone depletion during the solar proton events of October//November 2003 as seen by SCIAMACHY G; revised 4 May 2005; accepted 13 May 2005; published 20 August 2005. [1] We use atmospheric ozone density profiles between 35 and 65 km altitude derived from SCIAMACHY limb measurements to quantify the ozone

  7. Ozone database in support of CMIP5 simulations: results and corresponding

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    Ozone database in support of CMIP5 simulations: results and corresponding radiative forcing Article., Bodeker, G.E., Shepherd, T.G., Shindell, D.T. and Waugh, D.W. (2011) Ozone database in support of CMIP5 and Physics Ozone database in support of CMIP5 simulations: results and corresponding radiative forcing I

  8. Smoothing Parameter Selection When Errors are Correlated and Application to Ozone Data

    E-Print Network [OSTI]

    Heckman, Nancy E.

    Smoothing Parameter Selection When Errors are Correlated and Application to Ozone Data by Robert Jr trend of daily and monthly ground ozone levels in southern Ontario. iii #12; Contents Abstract ii.2 Air Pollution Data . . . . . . . . . . . . . . . . . . . . . . . . 79 5.2.1 Daily Ozone Data . . . . . . . . . . . . . . . . . . .

  9. Nighttime secondary ozone layer during major stratospheric sudden warmings in specified-dynamics WACCM

    E-Print Network [OSTI]

    Limpasuvan, Varavut

    Nighttime secondary ozone layer during major stratospheric sudden warmings in specified to the thermosphere. Currently, the role of atmospheric dynamics on polar ozone in the mesosphere-lower thermosphere "secondary" (90­105 km) ozone maximum by examining the dynamics and distribution of key species (like H and O

  10. Impact of Antarctic Ozone Depletion and Recovery on Southern Hemisphere Precipitation, Evaporation, and Extreme Changes

    E-Print Network [OSTI]

    Son, Seok-Woo

    Impact of Antarctic Ozone Depletion and Recovery on Southern Hemisphere Precipitation, Evaporation) ABSTRACT The possible impact of Antarctic ozone depletion and recovery on Southern Hemisphere (SH) mean- tercomparison Project 3 (CMIP3). By grouping models into four sets, those with and without ozone depletion

  11. Sources of tropospheric ozone along the Asian Pacific Rim: An analysis of ozonesonde observations

    E-Print Network [OSTI]

    Liu, Hongyu

    Sources of tropospheric ozone along the Asian Pacific Rim: An analysis of ozonesonde observations ozone over the Asian Pacific Rim in different seasons are quantified by analysis of Hong Kong at midlatitudes from fall at low latitudes due to monsoonal influence. The UT ozone minimum and high variability

  12. Analytica Chimica Acta 573574 (2006) 913 Metal oxide thin films as sensing layers for ozone detection

    E-Print Network [OSTI]

    2006-01-01

    Analytica Chimica Acta 573­574 (2006) 9­13 Metal oxide thin films as sensing layers for ozone. Their structural, electrical and ozone sensing properties were analyzed. Structural investigations carried out with ultraviolet light and subsequent oxidation in ozone atmosphere at room temperature. © 2006 Elsevier B.V. All

  13. Low ozone concentrations over Macquarie Island during 1997. Part I: trajectory analysis

    E-Print Network [OSTI]

    Cordero, Eugene

    Low ozone concentrations over Macquarie Island during 1997. Part I: trajectory analysis by Eugene C instruments show record low ozone column densities between 20°S and 60°S throughout 1997. The monthly averaged record from the Total Ozone Mapping Spectrometer (TOMS) indicates that measurements from 1997 are lower

  14. Ozone ensemble forecast with machine learning Vivien Mallet,1,2

    E-Print Network [OSTI]

    Mallet, Vivien

    Ozone ensemble forecast with machine learning algorithms Vivien Mallet,1,2 Gilles Stoltz,3; published 13 March 2009. [1] We apply machine learning algorithms to perform sequential aggregation of ozone forecasts. The latter rely on a multimodel ensemble built for ozone forecasting with the modeling system

  15. Efficient quantum-classical method for computing thermal rate constant of recombination: Application to ozone formation

    E-Print Network [OSTI]

    Reid, Scott A.

    : Application to ozone formation Mikhail V. Ivanov and Dmitri Babikov Citation: J. Chem. Phys. 136, 184304 (2012 for computing thermal rate constant of recombination: Application to ozone formation Mikhail V. Ivanov of ozone. Comparison of the predicted rate vs. experimental result is presented. © 2012 American Institute

  16. Conditional quantiles when the covariates are curves : an application to Ozone pollution

    E-Print Network [OSTI]

    Bercu, Bernard

    Conditional quantiles when the covariates are curves : an application to Ozone pollution forecasting Summary This work deals with the study of pollution data with the aim of forecas- ting the Ozone of the maximum of Ozone one day kno- wing one or several of these functional variables the day before. To do this

  17. Semiclassical wave packet study of anomalous isotope effect in ozone formation

    E-Print Network [OSTI]

    Reid, Scott A.

    Semiclassical wave packet study of anomalous isotope effect in ozone formation Evgeny Vetoshkin represent the metastable O3 * species and play a central role in the process of ozone formation.1063/1.2778432 I. INTRODUCTION Ozone O3 is formed in the stratosphere as a product of the following recombination

  18. Seedling insensitivity to ozone for three conifer species native to Great Smoky Mountains National Park$

    E-Print Network [OSTI]

    Neufeld, Howard S.

    Seedling insensitivity to ozone for three conifer species native to Great Smoky Mountains National concentrations of ozone had little eect on seedlings of three species of conifers commonly found in Great Smoky Mountains National Park. Abstract Field symptoms typical of ozone injury have been observed on several

  19. Quantification of Ozone Levels in Indoor Environments Generated by Ionization and Ozonolysis Air Purifiers

    E-Print Network [OSTI]

    Nizkorodov, Sergey

    Quantification of Ozone Levels in Indoor Environments Generated by Ionization and Ozonolysis Air ozone (O3) during operation, either in- tentionally or as a byproduct of air ionization standards. Sev- eral types of air purifiers were tested for their ability to produce ozone in various indoor

  20. The Effect of Ozone Stomatal Conductance on Isoprene Emissions above a Northern Hardwood Forest

    E-Print Network [OSTI]

    Collins, Gary S.

    The Effect of Ozone Stomatal Conductance on Isoprene Emissions above a Northern Hardwood Forest also acts as an antioxidant within a plant, reacting and neutralizing ozone and peroxides, though , and reacts photochemically in the presence of NOx to produce tropospheric ozone. The Model of Emissions

  1. Seasonal persistence of northern low-and middle-latitude anomalies of ozone and

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    Seasonal persistence of northern low- and middle-latitude anomalies of ozone and other trace gases) Seasonal persistence of northern low- and middle-latitude anomalies of ozone and other trace gases outputs online #12;Seasonal persistence of northern low- and middle-latitude anomalies of ozone and other

  2. Impact of long-range correlations on trend detection in total ozone

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    Impact of long-range correlations on trend detection in total ozone Article Published Version detection in total ozone. Journal of Geophysical Research, 112. D14307. ISSN 0148-0227 doi: 10.1029/2006JD of long-range correlations on trend detection in total ozone Dmitry I. Vyushin,1 Vitali E. Fioletov,2

  3. Semiclassical molecular dynamics simulations of ultrafast photodissociation dynamics associated with the Chappuis band of ozone

    E-Print Network [OSTI]

    Miller, William H.

    with the Chappuis band of ozone Victor S. Batista and William H. Millera) Department of Chemistry, University A ) of ozone following photoexcitation of the molecule in the gas phase with visible light. Our algorithm and recurrence events, as well as an interpretation of experimental studies of the Chappuis band of ozone

  4. Home refinishing, lead paint, and infant blood lead levels

    SciTech Connect (OSTI)

    Rabinowitz, M.; Leviton, A.; Bellinger, D.

    1985-04-01

    The blood lead levels of 249 infants were measured semi-annually from birth to two years of age; the home paint was sampled and any recent home refinishing activity recorded. Mean blood lead from birth to age 2 years did not vary systematically with age but did correlate significantly with the amount of lead in the indoor paint. Refinishing activity in homes with high lead paint was associated with elevations of blood lead averaging 69 per cent.

  5. LOT-G3: Plasma Lamp, Ozonator and CW transmitter

    E-Print Network [OSTI]

    Gobato, Ricardo; Gobato, Alekssander

    2015-01-01

    The LOT-G3 is designed to be a versatile equipment that perform several simple experiments for use in helping the physics classes for high school. Easy construction, low cost, using easily accessible materials. Its construction involves simple practices and knowledge of electromagnetism. It has the function of a plasma globe to demonstrate the ionization of a low pressure gas, as well as the formation of magnetic field. Can be used as sanitizer closed environments such as automotive vehicles in ozonator function, demonstrating the ionization of oxygen in the atmosphere, producing ozone, essential to life on earth. And as a sparks transmitter, low power, low frequency modulated continuous wave in (CW), for signals in Morse code. Therefore the equipment here called LOT-G3, has three functions: a plasma lamp, ozonator and CW transmitter.

  6. Ozone induces glucose intolerance and systemic metabolic effects in young and aged brown Norway rats

    SciTech Connect (OSTI)

    Bass, V.; Gordon, C.J.; Jarema, K.A.; MacPhail, R.C.; Cascio, W.E.; Phillips, P.M.; Ledbetter, A.D.; Schladweiler, M.C.; Andrews, D.; Miller, D.; Doerfler, D.L.; Kodavanti, U.P.

    2013-12-15

    Air pollutants have been associated with increased diabetes in humans. We hypothesized that ozone would impair glucose homeostasis by altering insulin signaling and/or endoplasmic reticular (ER) stress in young and aged rats. One, 4, 12, and 24 month old Brown Norway (BN) rats were exposed to air or ozone, 0.25 or 1.0 ppm, 6 h/day for 2 days (acute) or 2 d/week for 13 weeks (subchronic). Additionally, 4 month old rats were exposed to air or 1.0 ppm ozone, 6 h/day for 1 or 2 days (time-course). Glucose tolerance tests (GTT) were performed immediately after exposure. Serum and tissue biomarkers were analyzed 18 h after final ozone for acute and subchronic studies, and immediately after each day of exposure in the time-course study. Age-related glucose intolerance and increases in metabolic biomarkers were apparent at baseline. Acute ozone caused hyperglycemia and glucose intolerance in rats of all ages. Ozone-induced glucose intolerance was reduced in rats exposed for 13 weeks. Acute, but not subchronic ozone increased ?{sub 2}-macroglobulin, adiponectin and osteopontin. Time-course analysis indicated glucose intolerance at days 1 and 2 (2 > 1), and a recovery 18 h post ozone. Leptin increased day 1 and epinephrine at all times after ozone. Ozone tended to decrease phosphorylated insulin receptor substrate-1 in liver and adipose tissues. ER stress appeared to be the consequence of ozone induced acute metabolic impairment since transcriptional markers of ER stress increased only after 2 days of ozone. In conclusion, acute ozone exposure induces marked systemic metabolic impairments in BN rats of all ages, likely through sympathetic stimulation. - Highlights: • Air pollutants have been associated with increased diabetes in humans. • Acute ozone exposure produces profound metabolic alterations in rats. • Age influences metabolic risk factors in aging BN rats. • Acute metabolic effects are reversible and repeated exposure reduces these effects. • Ozone metabolic effects are only slightly exacerbated in geriatric rats.

  7. Ozone air quality measurement requirements for a geostationary satellite mission Peter Zoogman a,*, Daniel J. Jacob a,b

    E-Print Network [OSTI]

    Chance, Kelly

    Ozone air quality measurement requirements for a geostationary satellite mission Peter Zoogman a Accepted 23 May 2011 Keywords: Air quality Ozone Kalman filter Assimilation Remote sensing a b s t r a c satellite measurements of ozone in different spectral regions to constrain surface ozone concentrations

  8. Seasonal development of ozone-induced foliar injury on tall milkweed (Asclepias exaltata) in Great Smoky Mountains National Park

    E-Print Network [OSTI]

    Neufeld, Howard S.

    Seasonal development of ozone-induced foliar injury on tall milkweed (Asclepias exaltata) in Great by symptoms of foliar ozone injury. Abstract The goals of this study were to document the development of ozone-induced foliar injury, on a leaf-by-leaf basis, and to develop ozone exposure relationships for leaf cohorts

  9. Combined Crossed Molecular Beam and Ab Initio Investigation of the Reaction of Boron Monoxide (BO; X2

    E-Print Network [OSTI]

    Kaiser, Ralf I.

    ; X2 + ) with 1,3-Butadiene (CH2CHCHCH2; X1 Ag) and Its Deuterated Counterparts Surajit Maity, Beni B Information ABSTRACT: The reactions of the boron monoxide (11 BO; X2 + ) radical with 1,3- butadiene (CH2CHCHCH2; X1 Ag) and its partially deuterated counterparts, 1,3- butadiene-d2 (CH2CDCDCH2; X1 Ag) and 1

  10. Synthesis of Ozone at Atmospheric Pressure by a Quenched Induction-Coupled Plasma Torch

    SciTech Connect (OSTI)

    A. Blutke; B.C. Stratton; D.R. Mikkelsen; J. Vavruska; R. Knight

    1998-01-01

    The technical feasibility of using an induction-coupled plasma (ICP) torch to synthesize ozone at atmospheric pressure is explored. Ozone concentrations up to ~250 ppm were produced using a thermal plasma reactor system based on an ICP torch operating at 2.5 MHz and ~11 kVA with an argon/oxygen mixture as the plasma-forming gas. A gaseous oxygen quench formed ozone by rapid mixing of molecular oxygen with atomic oxygen produced by the torch. The ozone concentration in the reaction chamber was measured by Fourier Transform infrared (FTIR) spectroscopy over a wide range of experimental configurations. The geometry of the quench gas flow, the quench flow velocity, and the quench flow rate played important roles in determining the ozone concentration. The ozone concentration was sensitive to the torch RF power, but was insensitive to the torch gas flow rates. These observations are interpreted within the framework of a simple model of ozone synthesis.

  11. Massive global ozone loss predicted following regional nuclear conflict

    E-Print Network [OSTI]

    Robock, Alan

    that nuclear war could be winnable, and preceded the first significant reductions in nuclear weapons stockpiles, the proliferation of nuclear weapons has produced greater risks of a regional nuclear conflict. At the same timeMassive global ozone loss predicted following regional nuclear conflict Michael J. Mills* , Owen B

  12. Design and Usage of an Ozone Mapping App Ilyas Uyanik

    E-Print Network [OSTI]

    design, pollution visualiza- tion, air quality monitoring, ozone, user studies Permission to make digital-time, quantitative, and localized pollutant information has become available for a few big cities. Several mobile to conventional weather report- ing systems that provide a qualitative and static description of pollutant levels

  13. Tropospheric ozone over the North Pacific from ozonesonde observations

    E-Print Network [OSTI]

    Liu, Hongyu

    of urban air pollution. At sites in the mid and eastern Pacific the signature of transport of polluted air, Tsukuba, and Sapporo, Japan), a site in the central Pacific (Hilo, Hawaii), and a site on the west coast very high mixing ratios of ozone were observed that result from pollution transport from China

  14. EARTH OBSERVATION 400M Indians Endangered By Ozone

    E-Print Network [OSTI]

    Singh, Ramesh P.

    has been linked to increases in skin cancer rates. All rights reserved. © 2004 United Press using satellite and limited ground observations, the Press Trust of India reported Tuesday. The rate the reasons for the depletion, th e report states. Ozone is an important atmospheric trace gas that blocks

  15. Validation of satellite ozone profile retrievals using Beijing ozonesonde data

    E-Print Network [OSTI]

    Pan, Laura

    , the Atmospheric Infrared Sounder (AIRS) on the NASA Aqua satellite and the Microwave Limb Sounder (MLS in the stratosphere and troposphere. Stratospheric ozone forms a protective layer that absorbs enough solar) on the NASA Aqua satellite [Aumann et al., 2003] and the Microwave Limb Sounder (MLS) on the NASA Aura

  16. Search for the electric dipole moment of the electron with thorium monoxide

    E-Print Network [OSTI]

    Amar C. Vutha; Wesley C. Campbell; Yulia V. Gurevich; Nicholas R. Hutzler; Maxwell Parsons; David Patterson; Elizabeth Petrik; Benjamin Spaun; John M. Doyle; Gerald Gabrielse; David DeMille

    2010-11-06

    The electric dipole moment of the electron (eEDM) is a signature of CP-violating physics beyond the Standard Model. We describe an ongoing experiment to measure or set improved limits to the eEDM, using a cold beam of thorium monoxide (ThO) molecules. The metastable $H {}^3\\Delta_1$ state in ThO has important advantages for such an experiment. We argue that the statistical uncertainty of an eEDM measurement could be improved by as much as 3 orders of magnitude compared to the current experimental limit, in a first-generation apparatus using a cold ThO beam. We describe our measurements of the $H$ state lifetime and the production of ThO molecules in a beam, which provide crucial data for the eEDM sensitivity estimate. ThO also has ideal properties for the rejection of a number of known systematic errors; these properties and their implications are described.

  17. Simultaneous Detection of Water, Methane and Carbon Monoxide in the Atmosphere of Exoplanet HR8799b

    E-Print Network [OSTI]

    Barman, Travis S; Macintosh, Bruce; Marois, Christian

    2015-01-01

    Absorption lines from water, methane and carbon monoxide are detected in the atmosphere of exoplanet HR8799b. A medium-resolution spectrum presented here shows well-resolved and easily identified spectral features from all three molecules across the K band. The majority of the lines are produced by CO and H2O, but several lines clearly belong to CH4. Comparisons between these data and atmosphere models covering a range of temperatures and gravities yield log mole fractions of H2O between -3.09 and -3.91, CO between -3.30 and -3.72 and CH4 between -5.06 and -5.85. More precise mole fractions are obtained for each temperature and gravity studied. A reanalysis of H-band data, previously obtained at similar spectral resolution, results in a nearly identical water abundance as determined from the K-band spectrum. The methane abundance is shown to be sensitive to vertical mixing and indicates an eddy diffusion coefficient in the range of 10^6 to 10^8 cm^2 s^-1, comparable to mixing in the deep troposphere of Jupite...

  18. Solar Carbon Monoxide, Thermal Profiling, and the Abundances of C, O, and their Isotopes

    E-Print Network [OSTI]

    Thomas R. Ayres; Claude Plymate; Christoph U. Keller

    2006-06-07

    A solar photospheric "thermal profiling" analysis is presented, exploiting the infrared rovibrational bands of carbon monoxide (CO) as observed with the McMath-Pierce Fourier transform spectrometer (FTS) at Kitt Peak, and from above the Earth's atmosphere by the Shuttle-borne ATMOS experiment. Visible continuum intensities and center-limb behavior constrained the temperature profile of the deep photosphere, while CO center-limb behavior defined the thermal structure at higher altitudes. The oxygen abundance was self consistently determined from weak CO absorptions. Our analysis was meant to complement recent studies based on 3-D convection models which, among other things, have revised the historical solar oxygen (and carbon) abundance downward by a factor of nearly two; although in fact our conclusions do not support such a revision. Based on various considerations, an oxygen abundance of 700+/-100 ppm (parts per million relative to hydrogen) is recommended; the large uncertainty reflects the model sensitivity of CO. New solar isotopic ratios also are reported for 13C, 17O, and 18O.

  19. Relationship of respiratory symptoms and pulmonary function to tar, nicotine, and carbon monoxide yield of cigarettes

    SciTech Connect (OSTI)

    Krzyzanowski, M.; Sherrill, D.L.; Paoletti, P.; Lebowitz, M.D. )

    1991-02-01

    The data from consecutive surveys of the Tucson Epidemiologic Study (1981-1988) were used to evaluate the relationship in cigarette smokers of respiratory symptoms and pulmonary function to tar, nicotine, and carbon monoxide (CO) yields of the cigarette. There were 690 subjects who reported smoking regularly in at least one survey, over age 15. After adjustment for intensity and duration of smoking and for depth of inhalation, the risk of chronic phlegm, cough, and dyspnea were not related to the tar and nicotine yields. In 414 subjects with pulmonary function tested in at least one of the three surveys the spirometric indices used were significantly related to the daily dose of tar, nicotine, and CO (product of the cigarette yield and daily number of cigarettes smoked). The effects were more pronounced for past than for current doses. However, the differentiation of pulmonary function due to various yields of cigarettes was small in comparison to the difference in pulmonary function between smokers and nonsmokers.

  20. Breakthrough: Lead-free Solder

    SciTech Connect (OSTI)

    Anderson, Iver

    2012-01-01

    Ames Laboratory senior metallurgist Iver Anderson explains the importance of lead-free solder in taking hazardous lead out of the environment by eliminating it from discarded computers and electronics that wind up in landfills. Anderson led a team that developed a tin-silver-copper replacement for traditional lead-tin solder that has been adopted by more than 50 companies worldwide.

  1. Breakthrough: Lead-free Solder

    ScienceCinema (OSTI)

    Anderson, Iver

    2013-03-01

    Ames Laboratory senior metallurgist Iver Anderson explains the importance of lead-free solder in taking hazardous lead out of the environment by eliminating it from discarded computers and electronics that wind up in landfills. Anderson led a team that developed a tin-silver-copper replacement for traditional lead-tin solder that has been adopted by more than 50 companies worldwide.

  2. The Exposure-Response Curve for Ozone and Risk of Mortality and the Adequacy of Current Ozone

    E-Print Network [OSTI]

    Dominici, Francesca

    and applied several statistical models to data on air pollution, weather, and mortality for 98 U.S. urban mortality. Interventions to further reduce ozone pollution would benefit public health, even in regions pollutant linked to numerous harmful health effects, including reduced lung function, increased frequency

  3. Lead-based paint assessment

    SciTech Connect (OSTI)

    Lorie, C.; Cowdery, J.W.

    1994-12-31

    In 1977, The US consumer product safety commission banned the use of lead-based paint (LBP) in all industries, except the maritime industry which still has certain privileged uses. Unfortunately for property and building owners, the ban did not come soon enough. In response to this heightened awareness, several environmental market sectors addressing the issues have emerged. These include: residential; soil; commercial; water; and structures. The first and most important step in addressing the concerns posed by the existence of lead based contamination is to quantify the amount of lead-based product, to determine the location of the lead based product and the extent, if any, of lead based contamination, and to make recommendations for the remediation or abatement of the lead product and resultant contamination. In narrowing the focus of these issues, this paper discusses lead-based paint assessment; preparing and organizing the assessment, the regulatory considerations, assessment methodology, and presentation of results.

  4. Reaction of uranium oxides with chlorine and carbon or carbon monoxide to prepare uranium chlorides

    SciTech Connect (OSTI)

    Haas, P.A.; Lee, D.D.; Mailen, J.C.

    1991-11-01

    The preferred preparation concept of uranium metal for feed to an AVLIS uranium enrichment process requires preparation of uranium tetrachloride (UCI{sub 4}) by reacting uranium oxides (UO{sub 2}/UO{sub 3}) and chlorine (Cl{sub 2}) in a molten chloride salt medium. UO{sub 2} is a very stable metal oxide; thus, the chemical conversion requires both a chlorinating agent and a reducing agent that gives an oxide product which is much more stable than the corresponding chloride. Experimental studies in a quartz reactor of 4-cm ID have demonstrated the practically of some chemical flow sheets. Experimentation has illustrated a sequence of results concerning the chemical flow sheets. Tests with a graphite block at 850{degrees}C demonstrated rapid reactions of Cl{sub 2} and evolution of carbon dioxide (CO{sub 2}) as a product. Use of carbon monoxide (CO) as the reducing agent also gave rapid reactions of Cl{sub 2} and formation of CO{sub 2} at lower temperatures, but the reduction reactions were slower than the chlorinations. Carbon powder in the molten salt melt gave higher rates of reduction and better steady state utilization of Cl{sub 2}. Addition of UO{sub 2} feed while chlorination was in progress greatly improved the operation by avoiding the plugging effects from high UO{sub 2} concentrations and the poor Cl{sub 2} utilizations from low UO{sub 2} concentrations. An UO{sub 3} feed gave undesirable effects while a feed of UO{sub 2}-C spheres was excellent. The UO{sub 2}-C spheres also gave good rates of reaction as a fixed bed without any molten chloride salt. Results with a larger reactor and a bottom condenser for volatilized uranium show collection of condensed uranium chlorides as a loose powder and chlorine utilizations of 95--98% at high feed rates. 14 refs., 7 figs., 14 tabs.

  5. Results from the Cooler and Lead Tests

    E-Print Network [OSTI]

    Green, Michael A

    2010-01-01

    and D. Gupta, “Current Leads and Optimized Thermal Packagingtube Gas Cooled Electrical Leads for the g-2 Superconductinga pair of flexible copper leads attached. Figure 5. The Lead

  6. Sum frequency generation and catalytic reaction studies of the removal of the organic capping agents from Pt nanoparticles by UV-ozone treatment

    E-Print Network [OSTI]

    Aliaga, Cesar

    2010-01-01

    and (b) after 2 hours of UV/ozone treatment. (a) 50nm (b)a) before and (b) after UV/ozone treatment for 270 minutes.from Pt nanoparticles by UV-ozone treatment Cesar Aliaga, †

  7. JOURNAL OF GEOPHYSICAL RESEARCH, VOL. 91, NO. D1, PAGES 1103-1116, JANUARY 20, 1986 Two-Dimensional Monthly Average Ozone BalanceFrom

    E-Print Network [OSTI]

    Jackman, Charles H.

    -Dimensional Monthly Average Ozone BalanceFrom Limb Infrared Monitor of the Stratosphereand Stratosphericand consistency.We computethe diurnal averagephotochemicalproductionand lossterms of ozone usingmonthly ozone,whichisthelossrate by thechlorinefamily,iscalculatedfroma two

  8. High temperature superconductor current leads

    DOE Patents [OSTI]

    Hull, John R. (Hinsdale, IL); Poeppel, Roger B. (Glen Ellyn, IL)

    1995-01-01

    An electrical lead having one end for connection to an apparatus in a cryogenic environment and the other end for connection to an apparatus outside the cryogenic environment. The electrical lead includes a high temperature superconductor wire and an electrically conductive material distributed therein, where the conductive material is present at the one end of the lead at a concentration in the range of from 0 to about 3% by volume, and at the other end of the lead at a concentration of less than about 20% by volume. Various embodiments are shown for groups of high temperature superconductor wires and sheaths.

  9. Scale-Up and Demonstration of Fly Ash Ozonation Technology

    SciTech Connect (OSTI)

    Rui Afonso; R. Hurt; I. Kulaots

    2006-03-01

    The disposal of fly ash from the combustion of coal has become increasingly important. When the fly ash does not meet the required specification for the product or market intended, it is necessary to beneficiate it to achieve the desired quality. This project, conducted at PPL's Montour SES, is the first near full-scale ({approx}10 ton/day), demonstration of ash ozonation technology. Bituminous and sub bituminous ashes, including two ash samples that contained activated carbon, were treated during the project. Results from the tests were very promising. The ashes were successfully treated with ozone, yielding concrete-suitable ash quality. Preliminary process cost estimates indicate that capital and operating costs to treat unburned carbon are competitive with other commercial ash beneficiation technologies at a fraction of the cost of lost sales and/or ash disposal costs. This is the final technical report under DOE Cooperative Agreement No.: DE-FC26-03NT41730.

  10. The effect of solids retention time on tertiary ozonation and carbon adsorption of petrochemical wastewaters 

    E-Print Network [OSTI]

    Buys, Ronald Earl

    1980-01-01

    time of 30 days. 34 10 Correlation between measured and calculated nonadsorbable COD values for bio-oxidized samples. 37 Correlation between measured and calculated nonadsorbable COD values for bio-oxidized plus ozonated samples. 12 Effect... of solids retention time on nonadsorbable COD, with and without ozonation. 39 LIST OF TABLES Table Page Biochemical and chemical oxygen demand data. COD removal and ozone consumption data 21 26 iVon-adsorbable COD data for bio-oxidized effluent. . 3O...

  11. Effects of solar radiation on organic matter cycling: Formation of carbon monoxide and carbonyl sulfide (Chapter 11). Book chapter

    SciTech Connect (OSTI)

    Zepp, R.G.

    1994-01-01

    The effects of photoinduced processes on carbon cycling and the biospheric emission of two important trace carbon gases--carbon monoxide and carbonyl sulfide--are examined. Both of these gases are likely to play an important role in the biospheric feedbacks that may reinforce or attenuate future changes in climate. Evidence is presented to support the hypothesis that a significant fraction of the global sources of both of these gases derives from the photochemical fragmentation of decayed plant materials and other biogenic organic matter in terrestrial and marine environments.

  12. Meeting the New Ozone Standard: Challenges and Opportunities

    Broader source: Energy.gov [DOE]

    This presentation by Anna Garcia, executive director of the Ozone Transport Commission, was part of the July 2008 Webcast sponsored by the U.S. Department of Energy Office of Energy Efficiency and Renewable Energy Weatherization and Intergovernmental Program Clean Energy and Air Quality Integration Initiative that was titled Role of Energy Efficiency and Renewable Energy in Improving Air Quality and Addressing Greenhouse Gas Reduction Goals on High Electric Demand Days.

  13. The Cost of Crop Damage Caused by Ozone Air Pollution From Motor Vehicles

    E-Print Network [OSTI]

    Delucchi, Mark A.; Murphy, James; Kim, Jin; McCubbin, Donald R.

    1996-01-01

    without motor-vehicle related pollution. This diagram is forBY OZONE AIR POLLUTION FROM MOTOR VEHICLES Report #12 in thePOLLUTION FROM MOTOR VEHICLES

  14. Lead-free primary explosives

    DOE Patents [OSTI]

    Huynh, My Hang V.

    2010-06-22

    Lead-free primary explosives of the formula (cat).sub.Y[M.sup.II(T).sub.X(H.sub.2O).sub.6-X].sub.Z, where T is 5-nitrotetrazolate, and syntheses thereof are described. Substantially stoichiometric equivalents of the reactants lead to high yields of pure compositions thereby avoiding dangerous purification steps.

  15. Waste Management Coordinating Lead Authors

    E-Print Network [OSTI]

    Columbia University

    10 Waste Management Coordinating Lead Authors: Jean Bogner (USA) Lead Authors: Mohammed Abdelrafie Ahmed, C. Diaz, A. Faaij, Q. Gao, S. Hashimoto, K. Mareckova, R. Pipatti, T. Zhang, Waste Management University Press, Cambridge, United Kingdom and New York, NY, USA. #12;586 Waste Management Chapter 10 Table

  16. Line Broadening and Temperature Dependence in the 0 --> 3 Overtone Band of Carbon Monoxide Cyril Hnatovsky , Adriana Predoi-Cross , Kimberly Strong , James R. Drummond , and D. Chris Benner1 1 1 1 2

    E-Print Network [OSTI]

    Strong, Kimberly

    Line Broadening and Temperature Dependence in the 0 --> 3 Overtone Band of Carbon Monoxide Cyril. Introduction Carbon monoxide (CO) is a trace constituent present in the Earth's atmosphere. It is produced, and the incomplete combustion of fossil fuels and biomass. The lifetime of an atmospheric CO molecule is relatively

  17. One-dimensional turbulence model simulations of autoignition of hydrogen/carbon monoxide fuel mixtures in a turbulent jet

    SciTech Connect (OSTI)

    Gupta, Kamlesh G.; Echekki, Tarek [Department of Mechanical and Aerospace Engineering, North Carolina State University, NC (United States)

    2011-02-15

    The autoignition of hydrogen/carbon monoxide in a turbulent jet with preheated co-flow air is studied using the one-dimensional turbulence (ODT) model. The simulations are performed at atmospheric pressure based on varying the jet Reynolds number and the oxidizer preheat temperature for two compositions corresponding to varying the ratios of H{sub 2} and CO in the fuel stream. Moreover, simulations for homogeneous autoignition are implemented for similar mixture conditions for comparison with the turbulent jet results. The results identify the key effects of differential diffusion and turbulence on the onset and eventual progress of autoignition in the turbulent jets. The differential diffusion of hydrogen fuels results in a reduction of the ignition delay relative to similar conditions of homogeneous autoignition. Turbulence may play an important role in delaying ignition at high-turbulence conditions, a process countered by the differential diffusion of hydrogen relative to carbon monoxide; however, when ignition is established, turbulence enhances the overall rates of combustion of the non-premixed flame downstream of the ignition point. (author)

  18. Seasonal and Diurnal Variations of Ozone near the Mesopause from Observations of the 11.072-GHz Line

    E-Print Network [OSTI]

    Pratap, P.

    Ground-based observations of the 11.072-GHz line of ozone were made from January 2008 through January 2009. These observations provide an estimate of the diurnal and seasonal variations of ozone in the mesopause region. ...

  19. Very low zonally asymmetric ozone values in March 1997 above the North Atlantic-European region, induced by dynamic processes

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Very low zonally asymmetric ozone values in March 1997 above the North Atlantic-European region September 1998 / Revised: 25 January 1999 / Accepted: 26 January 1999 Abstract. The total ozone distribution before. A spatial pattern correlation between the zonally asymmetric part of total ozone

  20. Sensitivity of China's ozone air quality to 2000-2050 global changes of1 climate and emissions2

    E-Print Network [OSTI]

    Wu, Shiliang

    1 Sensitivity of China's ozone air quality to 2000-2050 global changes of1 climate and emissions2 3 the effect on China's ozone air quality from 2000-2050 global15 changes in climate and anthropogenic emissions of ozone precursors. The climate and16 emission effect in combination will increase afternoon mean

  1. LA RPARTITION DE L'OZONE ATMOSPHRIQUE EN FONCTION DE L'ALTITUDE Par M. D. BARBIER.

    E-Print Network [OSTI]

    Boyer, Edmond

    LA RÉPARTITION DE L'OZONE ATMOSPHÉRIQUE EN FONCTION DE L'ALTITUDE Par M. D. BARBIER. Observatoire observations en déter- minant la distribution de l'ozone par une série de Charlier du type A. En général on ne peut déterminer que la quantité totale d'ozone et la hauteur moyenne de la distribution, ces quantités

  2. Photodissociation of Ozone from 321 to 329 nm: The Relative Yields P2) with O2(X 3

    E-Print Network [OSTI]

    Houston, Paul L.

    Photodissociation of Ozone from 321 to 329 nm: The Relative Yields of O(3 P2) with O2(X 3 g - ), O2 Supporting Information ABSTRACT: Product imaging of O(3 P2) following dissociation of ozone has been used to determine the relative yields of the product channels O(3 P2) + O2(X 3 g - ) of ozone. All three channels

  3. Measurement of ozone in ambient air with microsensors : on-site campaign Isabelle ZDANEVITCH*. Nicolas MOSER**, Caroline CHARPENTIER*, Alexis MOQUET*,

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Measurement of ozone in ambient air with microsensors : on-site campaign Isabelle ZDANEVITCH, Switzerland E-mail : Isabelle.Zdanevitch(a),iner is.fr (corresponding author) ABSTRACT Ozone is actually one by continuous monitors but a better information on ozone levels would be given by a denser monitoring network

  4. Vertical Ozone Profiling at UMBS K. O'Donnell, T. Jobson, M. Erickson, T. Vanreken, W. Wallace

    E-Print Network [OSTI]

    Collins, Gary S.

    Vertical Ozone Profiling at UMBS K. O'Donnell, T. Jobson, M. Erickson, T. Vanreken, W. Wallace been done to determine vertical ozone profiles, especially in environments such as the northern mixed forest where this field campaign is being run. What past research that has been done has shown that ozone

  5. Ozone injury on cutleaf coneflower (Rudbeckia laciniata) and crown-beard (Verbesina occidentalis) in Great Smoky Mountains

    E-Print Network [OSTI]

    Neufeld, Howard S.

    Ozone injury on cutleaf coneflower (Rudbeckia laciniata) and crown-beard (Verbesina occidentalis ``Capsule'': Ground-level ozone causes deleterious effects to cutleaf coneflower and crown-beard in Great Smoky Mountains National Park. Abstract Incidence and severity of visible foliar ozone injury on cutleaf

  6. The Huggins band of ozone: Unambiguous electronic and vibrational Zheng-Wang Qu, Hui Zhu, Motomichi Tashiro, and Reinhard Schinkea)

    E-Print Network [OSTI]

    Farantos, Stavros C.

    The Huggins band of ozone: Unambiguous electronic and vibrational assignment Zheng-Wang Qu, Hui Zhu 12 February 2004; accepted 2 March 2004 The Huggins band of ozone is investigated by means of exact.1063/1.1711589 Because of the importance of ozone for the shielding of harmful UV light, its photophysics has been

  7. Rapid formation of molecular bromine from deliquesced NaBr aerosol in the presence of ozone and UV light

    E-Print Network [OSTI]

    Dabdub, Donald

    Rapid formation of molecular bromine from deliquesced NaBr aerosol in the presence of ozone and UV deliquesced NaBr aerosols in the presence of OH radicals produced by ozone irradiated by UV light, depending on the availability of ozone and bromide in the system. Interface reactions, an important source

  8. The Huggins band of ozone: A theoretical analysis Zheng-Wang Qu, Hui Zhu, Sergy Yu. Grebenshchikov, and Reinhard Schinkea)

    E-Print Network [OSTI]

    Farantos, Stavros C.

    The Huggins band of ozone: A theoretical analysis Zheng-Wang Qu, Hui Zhu, Sergy Yu. Grebenshchikov; accepted 16 September 2004 The Huggins band of ozone is investigated by means of dynamics calculations American Institute of Physics. DOI: 10.1063/1.1814098 I. INTRODUCTION Because of the importance of ozone

  9. The vibrational energies of ozone up to the dissociation threshold: Dynamics calculations on an accurate potential energy surface

    E-Print Network [OSTI]

    Farantos, Stavros C.

    The vibrational energies of ozone up to the dissociation threshold: Dynamics calculations present an ab initio potential energy surface for the ground electronic state of ozone. It is global, i. All bound states of nonrotating ozone up to more than 99% of the dissociation energy are calculated

  10. Validation of AIRS v4 ozone profiles in the UTLS using ozonesondes from Lauder, NZ and Boulder, USA

    E-Print Network [OSTI]

    Pan, Laura

    Validation of AIRS v4 ozone profiles in the UTLS using ozonesondes from Lauder, NZ and Boulder, USA) are used to examine the quality of the Atmospheric Infrared Sounder (AIRS) v4 vertical ozone profile range), AIRS ozone mixing ratios are larger than ozonesonde measurements, and at higher altitudes ($100

  11. Products and Mechanisms of Ozone Reactions with Oleic Acid for Aerosol Particles Having Core-Shell Morphologies

    E-Print Network [OSTI]

    Products and Mechanisms of Ozone Reactions with Oleic Acid for Aerosol Particles Having Core of oleic acid aerosol particles with ozone are studied below 1% relative humidity. The particles have inert of the organic layer is monitored with increasing ozone exposure by using an aerosol mass spectrometer

  12. 3USDA Forest Service Gen.Tech.Rep. PSW-GTR-166. 1998. Biochemical Reactions of Ozone in Plants1

    E-Print Network [OSTI]

    3USDA Forest Service Gen.Tech.Rep. PSW-GTR-166. 1998. Biochemical Reactions of Ozone in Plants1 Abstract Plants react biochemically to ozone in three phases: with constitutive chemicals in the apoplastic, plant reactions with ozone result in constitutive molecules such as the ozonolysis of ethylene

  13. A New Application of UV-Ozone Treatment in the Preparation of Substrate-Supported, Mesoporous Thin

    E-Print Network [OSTI]

    Parikh, Atul N.

    A New Application of UV-Ozone Treatment in the Preparation of Substrate-Supported, Mesoporous Thin room temperature photochemical method, simply employing ultraviolet light- (187-254 nm) generated ozone. The structures and compositions of the thin film mesophases before and after exposure to UV/ozone were determined

  14. A neural emission-receptor model for ozone reduction S.Barazzetta, G. Corani

    E-Print Network [OSTI]

    Corani, Giorgio

    A neural emission-receptor model for ozone reduction planning S.Barazzetta, G. Corani , G- ulated areas. Ozone is produced by a series of photochemical reactions, activated by the emissions concen- trations are equally complex and cannot be directly used to optimize emission reduction policies

  15. Lusaka, Zambia, during SAFARI-2000: Convergence of local and imported ozone pollution

    E-Print Network [OSTI]

    Thompson, Anne

    Lusaka, Zambia, during SAFARI-2000: Convergence of local and imported ozone pollution Anne M of the southern African burning region were taken at Lusaka, Zambia (15.5S, 28E) in early September 2000. Maximum from trans- boundary recirculation. Starting out over Zambia, Angola, and Namibia, ozone-rich air

  16. White Pine Emission Trends of Monoterpenes and Sesquiterpenes After Acute Ozone Exposure

    E-Print Network [OSTI]

    Collins, Gary S.

    White Pine Emission Trends of Monoterpenes and Sesquiterpenes After Acute Ozone Exposure Daniel M on a large scale in forests. Monoterpene and sesquiterpene emissions from trees significantly contribute investigates the effect of an abiotic stress, specifically acute ozone exposure, on the terpene emissions

  17. Intercontinental source attribution of ozone pollution at western U.S. sites using an adjoint method

    E-Print Network [OSTI]

    Jacob, Daniel J.

    the history of air parcels reaching the site. MBO experiences distinct Asian ozone pollution episodes; most stringent air quality standards [Task Force on Hemispheric Transport of Air Pollution, 2007]. Ozone previously to pollutant transport to Hawaii [Vukic´evic´ and Hess, 2000; Hess and Vukic´evic´, 2003

  18. Thesis proposal CSF Brazil 2014 treatment of open pit mines wastewater by a coupled ozone technique

    E-Print Network [OSTI]

    Bordenave, Charles

    /or hydroxides such as MnO2 or Fe(OH)3. The disinfection power of ozone is also well known. Thus the efficiency of University of São Paulo (USP). It has more than 2000 installations in Brazil, Argentina and Peru, treating of new application of ozone permitting to support his growth. Powered by TCPDF (www.tcpdf.org) #12;

  19. Sources of tropospheric ozone along the Asian Pacific Rim: An analysis of ozonesonde observations

    E-Print Network [OSTI]

    Jacob, Daniel J.

    1 Sources of tropospheric ozone along the Asian Pacific Rim: An analysis of ozonesonde observations contributing to tropospheric ozone over the Asian Pacific Rim in different seasons are quantified by analysis influence along the Pacific Rim occurs in summer, reflecting rapid convective transport of surface pollution

  20. Formaldehyde columns from the Ozone Monitoring Instrument: Urban versus background levels and evaluation using aircraft

    E-Print Network [OSTI]

    Mlllet, Dylan B.

    Formaldehyde columns from the Ozone Monitoring Instrument: Urban versus background levels formaldehyde column (WHCHO) retrievals from the Ozone Monitoring Instrument (OMI) and assess the information (20­200 km) near many urban areas. Citation: Boeke, N. L., et al. (2011), Formaldehyde columns from

  1. Air Pollution Physics and Chemistry EAS 6790 Home Work Assignment Ozone Chemistry 2

    E-Print Network [OSTI]

    Weber, Rodney

    1 Air Pollution Physics and Chemistry EAS 6790 Fall 2010 Home Work Assignment Ozone Chemistry 2 and Chemistry EAS 6790 Fall 2006 Home Work Assignment No. 4, Ozone Chemistry Problems 11.8 and 11.9 (sub-part 1 and 2 only). Daniel Jacob, Atmospheric Chemistry #12;2 Problem 2: 2 2. Consider an air parcel ventilated

  2. The impact of large scale biomass production on ozone air pollution in Joost B. Beltman a

    E-Print Network [OSTI]

    Utrecht, Universiteit

    The impact of large scale biomass production on ozone air pollution in Europe Joost B. Beltman by up to 25% and 40%. Air pollution mitigation strategies should consider land use management. a r t i Poplar a b s t r a c t Tropospheric ozone contributes to the removal of air pollutants from

  3. Response of different-aged black cherry trees to ambient ozone exposure

    SciTech Connect (OSTI)

    Fredericksen, T.S.; Joyce, B.J.; Kouterick, K.B.; Kolb, T.E.; Skelly, J.M.; Steiner, K.C.; Savage, J.E.; Snyder, K.R. (Pennyslvania State Univ., Univ. Park, PA (United States))

    1994-06-01

    Black cherry (Prunus serotina Ehrh.) is a valuable commercial timber species which is also highly sensitive to ozone relative to other eastern deciduous tree species. Studies of ozone effects on forest trees have been restricted mostly to experiments using small seedlings under controlled conditions. Yet, mature trees may differ from seedlings in physiology, morphology, and exposure to air pollutants. An experiment was conducted in 1993 to determine differences in ozone uptake and foliar injury symptoms between open-ground seedlings, forest saplings, and mature forest trees of black cherry in northcentral Pennsylvania. Seedlings grew under the highest ozone concentrations and also had greater seasonal ozone uptake due to higher rates of stomatal conductance. However, because of their indeterminate growth habit, seedlings had lower cumulative ozone uptake per leaf lifespan than saplings or mature trees, both of which had determinate shoot growth. Although greater initially for seedlings, foliar injury was nearly identical between size classes by the end of the growing season. Leaves in the lower crown of larger trees had lower ozone uptake than leaves in the upper crown, but exhibited more foliar injury symptoms. Lower crown leaves received more effective exposure to ozone because of their thinner leaves and had less available photosynthate for repair or replacement of damaged tissue.

  4. Review: The Great Lead Water Pipe Disaster

    E-Print Network [OSTI]

    Karalus, Daniel E

    2010-01-01

    Review: The Great Lead Water Pipe Disaster By WernerUSA Troesken, Werner. The Great Lead Water Pipe Disaster.paper. Alkaline paper. Lead poisoning usually conjures

  5. Distinguishing the impacts of ozone-depleting substances and well-mixed greenhouse gases on Arctic stratospheric ozone and temperature trends

    E-Print Network [OSTI]

    Rieder, Harald E.

    Whether stratospheric cooling due to increases in well-mixed greenhouse gases (WMGHG) could increase the depletion of Arctic stratospheric ozone has been the subject of scientific and public attention for decades. Here we ...

  6. WearAir: Expressive T-shirts for Air Quality Sensing Sunyoung Kim and Eric Paulos

    E-Print Network [OSTI]

    Chen, Yiling

    are less proactively concerned with air quality. AIR POLLUTANT: VOLATILE ORGANIC COMPOUNDS Different types of air pollutants contribute to air quality in different locations: Ozone, CO, NOx and VOCs are major contributors to outdoor air pollution; and particulate matters, VOCs, carbon monoxide and lead are common air

  7. Contribution of isoprene to chemical budgets: A model tracer study with the NCAR CTM MOZART-4

    E-Print Network [OSTI]

    Palmer, Paul

    parameter inputs. We also included a tagging scheme in the CTM, which keeps track of the production monoxide (CO), formaldehyde (HCHO) and peroxyacetylnitrate (PAN) explained by isoprene oxidation ranges (OH), ozone (O3) and nitrate radicals (NO3) leading to the production of atmospheric key species

  8. LEAD PAINT DISCLOSURE Housing built before 1978 may contain lead-based paint. Lead from paint, paint chips, and dust

    E-Print Network [OSTI]

    Royer, Dana

    LEAD PAINT DISCLOSURE Housing built before 1978 may contain lead-based paint. Lead from paint, paint chips, and dust can pose health hazards if not taken care of properly. Lead exposure is especially the presence of known lead-based paint and lead-based paint hazards in the dwelling. Tenants must also receive

  9. Process for the production of hydrogen and carbonyl sulfide from hydrogen sulfide and carbon monoxide using a metal boride, nitride, carbide and/or silicide catalyst

    SciTech Connect (OSTI)

    McGuiggan, M.F.; Kuch, P.L.

    1984-05-08

    Hydrogen and carbonyl sulfide are produced by a process comprising contacting gaseous hydrogen sulfide with gaseous carbon monoxide in the presence of a metal boride, carbide, nitride and/or silicide catalyst, such as titanium carbide, vanadium boride, manganese nitride or molybdenum silicide.

  10. Contribution of gas phase oxidation of volatile organic compounds to atmospheric carbon monoxide levels in two areas of the United States

    E-Print Network [OSTI]

    Dabdub, Donald

    - house gas, but also the hydroperoxide radical (HO2). HO2 converts nitric oxide to nitrogen dioxideContribution of gas phase oxidation of volatile organic compounds to atmospheric carbon monoxide. Chen, K. Carmody, S. Vutukuru, and D. Dabdub (2007), Contribution of gas phase oxidation of volatile

  11. Potentiometric CO titrations of carbon monoxide dehydrogenase and CO-inhibition of the NI-removing reaction with 1,10--phenanthroline 

    E-Print Network [OSTI]

    Russell, William Kent

    1996-01-01

    Carbon monoxide dehydrogenase from Clostridium thermoaceticum catalyzes two reactions involving redox chemistry (the reversible oxidation Of CO to C02, and the synthesis of acetyl-CoA) using three types of Ni and Fe-S structures called the A-, B...

  12. JOURNAL OF GEOPHYSICAL RESEARCH, VOL. 106, NO. D22, PAGES28,481-28,495, NOVEMBER 27, 2001 Source analysis of carbon monoxide

    E-Print Network [OSTI]

    Laat, Jos de

    Source analysis of carbon monoxide pollution during INDOEX 1999 A.T.J. de Laat, J. Lelieveld, G and higher hydrocarbons, and is directly emitted by combustion processes. Fossil fuel combustion pollution. However, the large number of possible sources in combination with the long photochemical lifetime

  13. Industrial lead paint removal specifications

    SciTech Connect (OSTI)

    Stone, R.C.

    1997-06-01

    The purpose of this paper is to inform the reader as to some of the pertinent rules and regulations promulgated by the Environmental Protection Agency (EPA) and the Occupational Safety and Health Administration (OSHA) that may effect an industrial lead paint removal project. The paper discusses a recommended schedule of procedures and preparations to be followed by the lead paint removal specification writer when analyzing the possible impact of the project on the environment, the public and workers. Implications of the Clean Air Act, the Clean Water Act and the Resource Conservation and Recovery Act (RCRA) along with hazardous waste handling, manifesting, transporting and disposal procedures are discussed with special emphasis placed as to their impact on the writer and the facility owner. As the rules and regulations are highly complex, the writer has attempted to explain the methodology currently being used in state-of-the-art industrial lead abatement specifications.

  14. Soluble Lead Flow Battery: Soluble Lead Flow Battery Technology

    SciTech Connect (OSTI)

    2010-09-01

    GRIDS Project: General Atomics is developing a flow battery technology based on chemistry similar to that used in the traditional lead-acid battery found in nearly every car on the road today. Flow batteries store energy in chemicals that are held in tanks outside the battery. When the energy is needed, the chemicals are pumped through the battery. Using the same basic chemistry as a traditional battery but storing its energy outside of the cell allows for the use of very low cost materials. The goal is to develop a system that is far more durable than today’s lead-acid batteries, can be scaled to deliver megawatts of power, and which lowers the cost of energy storage below $100 per kilowatt hour.

  15. Sensitivity analysis of ozone formation and transport for a Central California air pollution episode

    SciTech Connect (OSTI)

    Jin, Ling; Tonse, Shaheen; Cohan, Daniel S.; Mao, Xiaoling; Harley, Robert A.; Brown, Nancy J.

    2009-05-15

    CMAQ-HDDM is used to determine spatial and temporal variations in ozone limiting reagents and local vs upwind source contributions for an air pollution episode in Central California. We developed a first- and second- order sensitivity analysis approach with the Decoupled Direct Method to examine spatial and temporal variations of ozone-limiting reagents and the importance of local vs upwind emission sources in the San Joaquin Valley of central California for a five-day ozone episode (29th July-3rd Aug, 2000). Despite considerable spatial variations, nitrogen oxides (NO{sub x}) emission reductions are overall more effective than volatile organic compound (VOC) control for attaining the 8-hr ozone standard in this region for this episode, in contrast to the VOC control that works better for attaining the prior 1-hr ozone standard. Inter-basin source contributions of NO{sub x} emissions are limited to the northern part of the SJV, while anthropogenic VOC (AVOC) emissions, especially those emitted at night, influence ozone formation in the SJV further downwind. Among model input parameters studied here, uncertainties in emissions of NO{sub x} and AVOC, and the rate coefficient of the OH + NO{sub 2} termination reaction, have the greatest effect on first-order ozone responses to changes in NO{sub x} emissions. Uncertainties in biogenic VOC emissions only have a modest effect because they are generally not collocated with anthropogenic sources in this region.

  16. THE IMPACT OF OZONE ON THE LOWER FLAMMABLE LIMIT OF HYDROGEN IN VESSELS CONTAINING SAVANNAH RIVER SITE HIGH LEVEL WASTE

    SciTech Connect (OSTI)

    Sherburne, Carol [Savannah River Site (SRS), Aiken, SC (United States). Savannah River Remediation, LLC; Osterberg, Paul [Fauske and Associates, LLC, Burr Ridge, IL (United States); Johnson, Tom [Fauske and Associates, LLC, Burr Ridge, IL (United States); Frawely, Thomas [Fauske and Associates, LLC, Burr Ridge, IL (United States)

    2013-01-23

    The Savannah River Site, in conjunction with AREVA Federal services, has designed a process to treat dissolved radioactive waste solids with ozone. It is known that in this radioactive waste process, radionuclides radiolytically break down water into gaseous hydrogen and oxygen, which presents a well defined flammability hazard. Flammability limits have been established for both ozone and hydrogen separately; however, there is little information on mixtures of hydrogen and ozone. Therefore, testing was designed to provide critical flammability information necessary to support safety related considerations for the development of ozone treatment and potential scale-up to the commercial level. Since information was lacking on flammability issues at low levels of hydrogen and ozone, a testing program was developed to focus on filling this portion of the information gap. A 2-L vessel was used to conduct flammability tests at atmospheric pressure and temperature using a fuse wire ignition source at 1 percent ozone intervals spanning from no ozone to the Lower Flammable Limit (LFL) of ozone in the vessel, determined as 8.4%(v/v) ozone. An ozone generator and ozone detector were used to generate and measure the ozone concentration within the vessel in situ, since ozone decomposes rapidly on standing. The lower flammability limit of hydrogen in an ozone-oxygen mixture was found to decrease from the LFL of hydrogen in air, determined as 4.2 % (v/v) in this vessel. From the results of this testing, Savannah River was able to develop safety procedures and operating parameters to effectively minimize the formation of a flammable atmosphere.

  17. Surface modification of nitrogen-doped carbon nanotubes by ozone via atomic layer deposition

    SciTech Connect (OSTI)

    Lushington, Andrew; Liu, Jian; Tang, Yongji; Li, Ruying; Sun, Xueliang, E-mail: xsun@eng.uwo.ca [Department of Mechanical and Materials Engineering, University of Western Ontario, London, Ontario N6A 5B9 (Canada)

    2014-01-15

    The use of ozone as an oxidizing agent for atomic layer deposition (ALD) processes is rapidly growing due to its strong oxidizing capabilities. However, the effect of ozone on nanostructured substrates such as nitrogen-doped multiwalled carbon nanotubes (NCNTs) and pristine multiwalled carbon nanotubes (PCNTs) are not very well understood and may provide an avenue toward functionalizing the carbon nanotube surface prior to deposition. The effects of ALD ozone treatment on NCNTs and PCNTs using 10?wt. % ozone at temperatures of 150, 250, and 300?°C are studied. The effect of ozone pulse time and ALD cycle number on NCNTs and PCNTs was also investigated. Morphological changes to the substrate were observed by scanning electron microscopy and high resolution transmission electron microscopy. Brunauer-Emmett-Teller measurements were also conducted to determine surface area, pore size, and pore size distribution following ozone treatment. The graphitic nature of both NCNTs and PCNTs was determined using Raman analysis while x-ray photoelectron spectroscopy (XPS) was employed to probe the chemical nature of NCNTs. It was found that O{sub 3} attack occurs preferentially to the outermost geometric surface of NCNTs. Our research also revealed that the deleterious effects of ozone are found only on NCNTs while little or no damage occurs on PCNTs. Furthermore, XPS analysis indicated that ALD ozone treatment on NCNTs, at elevated temperatures, results in loss of nitrogen content. Our studies demonstrate that ALD ozone treatment is an effective avenue toward creating low nitrogen content, defect rich substrates for use in electrochemical applications and ALD of various metal/metal oxides.

  18. CONDITIONBIASOF HUNTER-SHOTRING-NECKEDDUCKS EXPOSEDTO LEAD

    E-Print Network [OSTI]

    McCracken, Kevin G.

    CONDITIONBIASOF HUNTER-SHOTRING-NECKEDDUCKS EXPOSEDTO LEAD KEVING. McCRACKEN,U.S. Geological-neckedducks(Aythyacollaris)exposedto lead by testing the null hypothesis that ducks shot by hunters do not differ in physiological condition lead. Collection type-by-concentration of blood lead and age-by-sex-by-concentration of blood lead

  19. What is lead-based paint

    SciTech Connect (OSTI)

    Vernon, L.S.

    1994-03-01

    The number of variety of lead-abatement regulations and requirements make it difficult and confusing to identify and properly respond to dangerous levels of lead in every situation. Definitions of lead-based paint'' and three test methods for lead detection are described to help determine when and how to test for the presence of lead.

  20. ROLE OF THE LAND PLUME IN THE TRANSPORT OF OZONE OVER THE OCEAN DURING INDOEX (1999)

    E-Print Network [OSTI]

    Raman, Sethu

    1999-01-01

    from India to the North Indian Ocean (Satheesh, 1998). High concentrations of non-sea salt aerosols by agricultural burning and bio-fuel use that have greatly increased carbon monoxide concentrations over based on a comprehensive set of observations during the field phase of INDOEX in 1999. In addition

  1. One Vaccine Leads to Another

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMass mapSpeeding access toOctober 1996Technologies / OmbudsmanOne Vaccine Leads to Another

  2. One Vaccine Leads to Another

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMass mapSpeeding access toOctober 1996Technologies / OmbudsmanOne Vaccine Leads to

  3. One Vaccine Leads to Another

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformationJesseworkSURVEY UNIVERSEHowScientificOmbuds OfficeOne Vaccine Leads to Another

  4. Application of an all-solid-state diode-laser-based sensor for carbon monoxide detection by optical absorption in the 4.4 ? 4.8 µm spectral region 

    E-Print Network [OSTI]

    Rodolfo, Barron Jimenez

    2005-02-17

    An all-solid-state continuous-wave (cw) laser system for mid-infrared absorption measurements of the carbon monoxide (CO) molecule has been developed and demonstrated. The single-mode, tunable output of an external-cavity ...

  5. Next generation gas turbines will be required to produce low concentrations of pollutants such as oxides of nitrogen (NOx), carbon monoxide (CO), and soot. In order to design gas turbines which produce lower emissions it is essential

    E-Print Network [OSTI]

    Next generation gas turbines will be required to produce low concentrations of pollutants such as oxides of nitrogen (NOx), carbon monoxide (CO), and soot. In order to design gas turbines which produce

  6. CEC3002012003LCD LEAD COMMISSIONER DRAFT

    E-Print Network [OSTI]

    APRIL 2012 CEC3002012003LCD LEAD COMMISSIONER DRAFT GUIDEBOOK RENEWABLE ENERGY PROGRAM OVERALL PROGRAM GUIDEBOOK Fourth Edition Lead Commissioner Draft Guidebook CALIFORNIA ENERGY COMMISSION, California 95814 M Staff Proposed Errata to the Lead Commissioner Draft Renewables Portfolio Standard

  7. Lead-Safe Housing Policy Guidance

    E-Print Network [OSTI]

    Lead-Safe Housing Policy Guidance #12;ACKNOWLEDGEMENTS This guidance was prepared by the Alliance Gumm. The Alliance thanks the Childhood Lead Poisoning Prevention Branch of the Centers for Disease..............................................................................................................................1 PART I Basic Lead-Safe Housing Standards

  8. Where Is Lead Found? Paint in many homes built before 1978 may contain lead.

    E-Print Network [OSTI]

    Liskiewicz, Maciej

    Where Is Lead Found? · Paint in many homes built before 1978 may contain lead. · Soil surrounding a home may have lead from exterior paint dust or from leaded gasoline in cars. · Household dust can contain lead from deteriorating lead- based paint or from soil containing lead that is tracked

  9. Evaluation of a novel ozone generation technique for disinfection of poultry hatchers and processed broiler carcasses 

    E-Print Network [OSTI]

    Ramirez, Gerardo Arturo

    1994-01-01

    When comparing electrochemically generated ozone(03)(2.94.2 wt % inside the (hatcher) and formaldehyde (16 n-A formalin + 7.5 g potassium pertnanganate) for disinfection of Salmonella enteiltidis (SE) contaminated agar plates and typical hatchery...

  10. Isolation and characterization of five ozone-inductible cDNA clones from Atriplax canescens (saltbush) 

    E-Print Network [OSTI]

    No, Eun-Gyu

    1994-01-01

    Prolonged exposure of plants to ozone inhibits growth and development and produces visible signs of damage. Within a few hours of exposure, certain biochemical alterations have been observed with the induction of several stress-related proteins...

  11. An ozone climatology of the Dallas-Fort Worth area and its relationship to meteorology 

    E-Print Network [OSTI]

    Nobis, Timothy Edward

    1998-01-01

    The Environmental protection agency has established a hics. National Ambient Air Quality Standard for surface ozone through the Clean Air Act and its amendments. The Dallas / Fort Worth area is in violation of these standards, and to date...

  12. Controlling superconductivity in La2-xSrxCuO4+? by ozone and vacuum annealing

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Leng, Xiang; Bozovic, Ivan

    2014-11-21

    In this study we performed a series of ozone and vacuum annealing experiments on epitaxial La2-xSrxCuO4+? thin films. The transition temperature after each annealing step has been measured by the mutual inductance technique. The relationship between the effective doping and the vacuum annealing time has been studied. Short-time ozone annealing at 470 °C oxidizes an underdoped film all the way to the overdoped regime. The subsequent vacuum annealing at 350 °C to 380 °C slowly brings the sample across the optimal doping point back to the undoped, non-superconducting state. Several ozone and vacuum annealing cycles have been done on themore »same sample and the effects were found to be repeatable and reversible Vacuum annealing of ozone-loaded LSCO films is a very controllable process, allowing one to tune the doping level of LSCO in small steps across the superconducting dome, which can be used for fundamental physics studies.« less

  13. Climatology and Trends in the Forcing of the Stratospheric Ozone Transport

    E-Print Network [OSTI]

    Monier, Erwan

    A thorough analysis of the ozone transport was carried out using the Transformed-Mean Eulerian (TEM) tracer transport equation and the European Centre for Medium-Range Weather Forecasts (ECMWF) Re- Analysis (ERA-40). In ...

  14. Controlling superconductivity in La2-xSrxCuO4+? by ozone and...

    Office of Scientific and Technical Information (OSTI)

    time has been studied. Short-time ozone annealing at 470 C oxidizes an underdoped film all the way to the overdoped regime. The subsequent vacuum annealing at 350 C to 380...

  15. Why does surface ozone peak in summertime at Waliguan? Hajime Akimoto,1

    E-Print Network [OSTI]

    in the East Asian Pacific rim region. Model results suggest that there is band of a high ozone between 35°N$45 Hemisphere. In the East Asian Pacific Rim region, most monitoring sites are located downwind of the large

  16. Enhancing Low-Cost Ozone Spectrometers to Measure Mesospheric Winds and Tides

    E-Print Network [OSTI]

    Alam, O B

    2015-01-01

    Ground-based spectrometers have been developed to measure the concentration, velocity, and temperature of ozone in the mesosphere and lower thermosphere (MLT) using low-cost satellite television electronics to observe the 11.072 GHz spectral line of ozone. A two-channel spectrometer has been engineered to yield various performance improvements, including a doubling of the signal-to-noise ratio, improved data processing efficiency, and lower power consumption at 15 W. Following 2009 and 2012 observations of the seasonal and diurnal variations in ozone concentration near the mesopause, the ozone line was observed at an altitude near 95 km and latitude of 38 degrees north using three single-channel spectrometers located at the MIT Haystack Observatory (Westford, MA), Chelmsford High School (Chelmsford, MA), and Union College (Schenectady, NY) pointed south at 8 degrees. Observations from 2009 through 2014 are used to derive the nightly-averaged seasonal variation in meridional velocity, as well as the seasonally...

  17. Environmental Externalities in Electric Power Markets: Acid Rain, Urban Ozone, and Climate Change

    Reports and Publications (EIA)

    1995-01-01

    This article discusses the emissions resulting from the generation of electricity by utilities and their role in contributing to the environmental problems of acid rain, urban ozone, and climate change.

  18. Climatology and trends in the forcing of the stratospheric ozone transport

    E-Print Network [OSTI]

    Monier, Erwan

    A thorough analysis of the ozone transport was carried out using the Transformed-Mean Eulerian (TEM) tracer continuity equation and the European Centre for Medium-Range Weather Forecasts (ECMWF) Re-Analysis (ERA-40). In ...

  19. Ozone predictabilities due to meteorological uncertainties in the Mexico City basin using ensemble forecasts

    E-Print Network [OSTI]

    Bei, Naifang

    The purpose of the present study is to investigate the sensitivity of ozone (O3)[(O subscript 3)] predictions in the Mexico City Metropolitan Area (MCMA) to meteorological initial uncertainties and planetary boundary layer ...

  20. Ozone response to emission changes: a modeling study during the MCMA-2006/MILAGRO Campaign

    E-Print Network [OSTI]

    Song, Jihee

    The sensitivity of ozone production to precursor emissions was investigated under five different meteorological conditions in the Mexico City Metropolitan Area (MCMA) during the MCMA-2006/MILAGRO field campaign using the ...

  1. Structural carbohydrate availability with electrochemical ozonation and ammonia pressurization / depressurization pre-treatment technologies 

    E-Print Network [OSTI]

    Williams, James Jason

    1999-01-01

    Experiments were conducted to determine the quantity and conditions of electrochemical ozonation (O?) that maximize the dissolution of the lignin-cellulose complex. Combination treatments of anhydrous ammonia (NH?) and O? were also assessed...

  2. The effect of variability in industrial emissions on ozone formation in Houston, Texas

    E-Print Network [OSTI]

    Webster, Mort David

    2007-01-01

    Ambient observations have indicated that high concentrations of ozone observed in the Houston/Galveston area are associated with plumes of highly reactive hydrocarbons, mixed with NOx, from industrial facilities. Ambient ...

  3. Real-World Studies of Ambient Ozone Formation as a Function of...

    Energy Savers [EERE]

    -- Washington D.C. ace29lawson.pdf More Documents & Publications Weekday and Weekend Air Pollutant Levels in Ozone Problem Areas in the U.S. DOE's Studies of WeekdayWeekend...

  4. Ozone (o3) efficacy on reduction of phytophthora capsici in recirculated horticultural irrigation water 

    E-Print Network [OSTI]

    McDonald, Garry Vernon

    2009-05-15

    Microorganisms that cause plant disease have been isolated in recirculated irrigation water and increase the risks of disease incidence in horticultural operations. Ozone is an effective oxidizer used to disinfect drinking ...

  5. Ground-level ozone in eastern North America : its formation and transport

    E-Print Network [OSTI]

    Zemba, Stephen G.

    1990-01-01

    Ozone (Os), a natural component of the troposphere, is augmented by photochemical processes involving manmade emissions of nitrogen oxides (NOx) and volatile organic compounds (VOCs). Sufficiently high concentrations of ...

  6. Improved Potential Energy Surface of Ozone Constructed Using the Fitting by Permutationally Invariant Polynomial Function

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ayouz, Mehdi; Babikov, Dmitri

    2012-01-01

    New global potential energy surface for the ground electronic state of ozone is constructed at the complete basis set level of the multireference configuration interaction theory. A method of fitting the data points by analytical permutationally invariant polynomial function is adopted. A small set of 500 points is preoptimized using the old surface of ozone. In this procedure the positions of points in the configuration space are chosen such that the RMS deviation of the fit is minimized. Newab initiocalculations are carried out at these points and are used to build new surface. Additional points are added to the vicinitymore »of the minimum energy path in order to improve accuracy of the fit, particularly in the region where the surface of ozone exhibits a shallow van der Waals well. New surface can be used to study formation of ozone at thermal energies and its spectroscopy near the dissociation threshold.« less

  7. Verification of the WRF model during a high ozone event over Houston, TX 

    E-Print Network [OSTI]

    Ames, Douglas Seeley

    2003-01-01

    High ozone values were observed in Houston, TX during August 25 - September 1, 2000. A comparison of WRF data with observations and MM5 data was conducted to determine the WRF model's performance in simulating the meteorological conditions...

  8. Lead phosphate glass compositions for optical components

    DOE Patents [OSTI]

    Sales, Brian C. (Oak Ridge, TN); Boatner, Lynn A. (Oak Ridge, TN)

    1987-01-01

    A lead phosphate glass to which has been added indium oxide or scandium oe to improve chemical durability and provide a lead phosphate glass with good optical properties.

  9. Power Marketing Administrations Leading the Nation's Transition...

    Energy Savers [EERE]

    Leading the Nation's Transition to a 21st Century Electric Grid Power Marketing Administrations Leading the Nation's Transition to a 21st Century Electric Grid November 19, 2012 -...

  10. Cities Leading through Energy Analysis and Planning

    Broader source: Energy.gov [DOE]

    The Cities Leading through Energy Analysis and Planning (Cities-LEAP) project delivers standardized, localized energy data and analysis that enables cities to lead clean energy innovation and...

  11. Aerosolized neutral endopeptidase reverses ozone-induced airway hyperreactivity to substance P

    SciTech Connect (OSTI)

    Murlas, C.G.; Lang, Z.; Williams, G.J.; Chodimella, V. (Department of Medicine, Rush University, Chicago, IL (United States))

    1992-03-01

    The authors investigated the effects of ozone exposure (3.0 ppm, 2 h) on airway neutral endopeptidase (NEP) activity and bronchial reactivity to substance P in guinea pigs. Reactivity after ozone or air exposure was determined by measuring specific airway resistance in intact unanesthetized spontaneously breathing animals in response to increasing doses of intravenous substance P boluses. The effective dose of substance P (in micrograms) that produced a doubling of baseline specific airway resistance (ED200SP) was determined by interpolation of cumulative substance P dose-response curves. NEP activity was measured in tracheal homogenates made from each animal of other groups exposed to either ozone or room air. By reverse-phase high-pressure liquid chromatography, this activity was characterized by the phosphoramidon-inhibitable cleavage of alanine-p-nitroaniline from succinyl-(Ala)3-p-nitroaniline in the presence of 100 microM amastatin. Mean values of the changes in log ED200SP were 0.27 +/- 0.07 (SE) for the ozone-exposed group and 0.08 +/- 0.04 for the air-exposed group. We found that phosphoramidon significantly increased substance P reactivity in the air-exposed animals (P less than 0.01), but it had no effect in the ozone-exposed group. This finding was associated with a significant reduction in tracheal homogenate NEP activity of ozone-exposed animals compared with controls: mean values were 18.1 +/- 1.9 nmol.min-1.mg protein-1 for the ozone-exposed group and 25.1 +/- 2.4 nmol.min-1.mg protein-1 for air-exposed animals (P less than 0.05). Inhalation of an aerosolized NEP preparation, partially purified from guinea pig kidney, reversed the substance P hyperreactivity produced by ozone exposure.(ABSTRACT TRUNCATED AT 250 WORDS)

  12. On the formation of carbonyl sulfide in the reduction of sulfur dioxide by carbon monoxide on lanthanum oxysulfide catalyst: A study by XPS and TPR/MS

    SciTech Connect (OSTI)

    Lau, N.T.; Fang, M. [Hong Kong Univ. of Science and Technology, Clear Water Bay (Hong Kong). Applied Technology Center] [Hong Kong Univ. of Science and Technology, Clear Water Bay (Hong Kong). Applied Technology Center

    1998-10-25

    Both the X-ray photoelectron spectroscopy (XPS) and temperature-programmed reaction, coupled with mass spectrometry (TPR/MS), are used to study the formation of carbonyl sulfide in the reduction of sulfur dioxide on lanthanum oxysulfide catalyst. It was found that the lattice sulfur of the oxysulfide is released and reacts with carbon monoxide to form carbonyl sulfide when the oxysulfide is heated. The oxysulfide is postulated to form sulfur vacancies at a temperature lower than that for the formation of carbonyl sulfide and atomic sulfur is released in the process. The atomic sulfur can either enter the gas phase and leave the oxysulfide catalyst or react with carbon monoxide to form carbonyl sulfide.

  13. Ozone impacts on the productivity of selected crops. [Corn, wheat, soybean and peanut crops

    SciTech Connect (OSTI)

    Heck, W.W.; Cure, W.W.; Shriner, D.S.; Olson, R.J.; Heagle, A.S.

    1982-01-01

    The regional impacts of ozone on corn, wheat, soybean, and peanut crops are estimated by using dose-response functions to relate ambient maximum 7 h/d seasonal ozone concentrations to crop productivity data. Linear dose-response functions were developed from open-top field chamber studies. It was assumed that the limited number of cultivars and growing conditions available for the analysis were representative of major agricultural regions. Hourly ozone data were selected to represent rural concentrations and used to calculate maximum 7-h/d average values. Seasonal ozone averages for counties were extrapolated from approximately 300 monitoring sites. Results must be interpreted with knowledge of these assumptions and sources of uncertainty. Impacts are calculated for county units for the conterminous United States with maps showing patterns and tables summarizing the potential magnitude of ozone effects on selected crop yields. The assessment estimates that approximately three billion dollars of productivity could be gained if current maximum 7 hour per day ozone levels were reduced from present levels to below 25 parts per billion. Dollar values are based on 1978 crop prices, without accounting for price effects, to provide an overall estimate of the impact. Of the estimated economic impact, soybean represents 64%, corn 17%, wheat 12%, and peanuts 7%.

  14. Dissolution of lead paint in aqueous solutions

    SciTech Connect (OSTI)

    Barnes, G.L.; Davis, A.P.

    1996-07-01

    An analysis of the rate and extent of lead leaching from a lead-based paint was completed. At low-solution pH, dissolution was rapid and approached 80% of the total lead. Residual lead can be estimated based on the predicted solubility of lead carbonate and basic lead carbonate. Release of lead from the paint was slower than that from pure basic lead carbonate due to inhibition by the paint matrix. Although the dissolved concentration of lead in solution at neutral/high pH was low, the paint binder was apparently destroyed at these pH values, releasing colloidal lead pigment particles. The presence of ethylenediaminetetraacetic acid (EDTA) and nitrilotriacetic acid (NTA) enhanced both the rate and degree of lead dissolution, while benzoic acid had a minimal effect.

  15. Results from the Cooler and Lead Tests

    SciTech Connect (OSTI)

    Green, Michael A

    2010-06-10

    The report presents the results of testing MICE spectrometer magnet current leads on a test apparatus that combines both the copper leads and the high temperature superconducting (HTS) leads with a single Cryomech PT415 cooler and liquid helium tank. The current is carried through the copper leads from 300 K to the top of the HTS leads. The current is then carried through the HTS leads to a feed-through from the vacuum space to the inside of a liquid helium tank. The experiment allows one to measure the performance of both cooler stages along with the performance of the leads. While the leads were powered we measured the voltage drops through the copper leads, through the HTS leads, through spliced to the feed-through, through the feed-through and through the low-temperature superconducting loop that connects one lead to the other. Measurements were made using the leads that were used in spectrometer magnet 1A and spectrometer magnet 2A. These are the same leads that were used for Superbend and Venus magnets at LBNL. The IL/A for these leads was 5.2 x 10{sup 6} m{sup -1}. The leads turned out to be too long. The same measurements were made using the leads that were installed in magnet 2B. The magnet 2B leads had an IL/A of 3.3 x 10{sup 6} A m{sup -1}. This report discusses the cooler performance and the measured electrical performance of the lead circuit that contains the copper leads and the superconducting leads. All of the HTS leads that were installed in magnet 2B were current tested using this apparatus.

  16. EPA Lead Safety for Renovation, Repair and

    E-Print Network [OSTI]

    Tennessee, University of

    EPA Lead Safety for Renovation, Repair and Painting (RRP) Course Certified Renovators Class, CSP, CHMM, Certified Lead Paint Inspector.; Certified Renovator; EPA Ac- credited Lead RRP trainer or fax registratio Registration Form Cash Method of Payment Check Name Mailing Address Phone Lead Safety

  17. APPENDIX F Partition Coefficients For Lead

    E-Print Network [OSTI]

    APPENDIX F Partition Coefficients For Lead #12;Appendix F Partition Coefficients For Lead F.1.0 Background The review of lead Kd data reported in the literature for a number of soils led to the following important conclusions regarding the factors which influence lead adsorption on minerals, soils

  18. LEAD at Unidata Status Update, April 2009

    E-Print Network [OSTI]

    LEAD at Unidata Status Update, April 2009 Mohan Ramamurthy The LEAD project is currently in the no-cost extension period and nearing the end of its period of performance as an NSF Large ITR award. LEAD has and networking to huge data sets, human decision making and complex virtual organizations ­ LEAD functionality

  19. Henry and Fred Learn about Lead

    E-Print Network [OSTI]

    Holsinger, Kent

    Henry and Fred Learn about Lead Joan Bothell Activity book #12;Henry and Fred Learn about Lead the children's storybook Henry and Fred Learn about Lead/Enrique y Federico aprenden sobre el plomo (2003 of this activity book. The Henry and Fred storybook is about keeping children safe from lead poisoning, a serious

  20. Childhood Lead Poisoning What Is the Problem?

    E-Print Network [OSTI]

    CS239775 Childhood Lead Poisoning What Is the Problem? Approximately 500,000 U.S. children aged 1. Lead poisoning can affect nearly every system in the body. Because lead poisoning often occurs with no obvious symptoms, it frequently goes unrecognized. Lead poisoning can cause learning disabilities

  1. Chapter 6: Research Priorities Childhood Lead Poisoning

    E-Print Network [OSTI]

    Chapter 6: Research Priorities 6 Childhood Lead Poisoning Prevention Research Priorities If we are to improve lead poisoning prevention strategies, we need additional research in the following areas: 1 to control lead hazards in housing. · The effectiveness of family education about lead poisoning prevention

  2. Effect of quantity and route of administration of manganese monoxide on feed intake and serum manganese in ruminants

    SciTech Connect (OSTI)

    Black, J.R.; Ammerman, C.B.; Henry, P.R.

    1985-02-01

    The experiment investigated effects of high quantities of manganese and route of administration (diet versus capsule-dosed) on feed intake and blood characteristics in sheep. Twenty-four Florida native or Florida native by St. Croix crossbred wethers, 47 kg initially, were assigned randomly to eight treatments including basal diet supplemented with 0, 3000, 6000, or 9000 ppm manganese as a reagent grade manganese monoxide or basal diet plus gelatin capsules containing the equivalent of 0, 3000, 6000, or 9000 ppm manganese based on intake of the previous day. Three sheep per treatment were provided feed and tap water for ad libitum intake. Sheep were fed basal diet for 7 days followed by a 21-day experimental period, then placed back on the basal diet for 7 days. Average daily feed intake was reduced by increasing supplemental manganese, regardless of route. Animals dosed by capsule consumed less feed than those administered manganese in the diet. Serum manganese increased as manganese supplementation increased, but route of administration had no effect.

  3. Sensitivity and uncertainty analysis of atmospheric ozone photochemistry models. Final report, September 30, 1993--December 31, 1998

    SciTech Connect (OSTI)

    Smith, G.P.

    1999-03-01

    The author has examined the kinetic reliability of ozone model predictions by computing direct first-order sensitivities of model species concentrations to input parameters: S{sub ij} = [dC{sub i}/C{sub i}]/[dk{sub j}/k{sub j}], where C{sub i} is the abundance of species i (e.g., ozone) and k{sub j} is the rate constant of step j (reaction, photolysis, or transport), for localized boxes from the LLNL 2-D diurnally averaged atmospheric model. An ozone sensitivity survey of boxes at altitudes of 10--55 km, 2--62N latitude, for spring, equinox, and winter is presented. Ozone sensitivities are used to evaluate the response of model predictions of ozone to input rate coefficient changes, to propagate laboratory rate uncertainties through the model, and to select processes and regions suited to more precise measurements. By including the local chemical feedbacks, the sensitivities quantify the important roles of oxygen and ozone photolysis, transport from the tropics, and the relation of key catalytic steps and cycles in regulating stratospheric ozone as a function of altitude, latitude, and season. A sensitivity-uncertainty analysis uses the sensitivity coefficients to propagate laboratory error bars in input photochemical parameters and estimate the net model uncertainties of predicted ozone in isolated boxes; it was applied to potential problems in the upper stratospheric ozone budget, and also highlights superior regions for model validation.

  4. Tethered balloon-based soundings of ozone, aerosols, and solar radiation near Mexico City during MIRAGE-MEX

    E-Print Network [OSTI]

    Greenberg, JP; Guenther, AB; Turnipseed, A

    2009-01-01

    ozone, aerosols, and solar radiation near Mexico City duringand solar radiation in the atmospheric boundary layer on the northern edge of Mexico

  5. Tethered balloon-based soundings of ozone, aerosols, and solar radiation near Mexico City during MIRAGE-MEX

    E-Print Network [OSTI]

    Greenberg, JP; Guenther, AB; Turnipseed, A

    2009-01-01

    ozone, aerosols, and solar radiation near Mexico City duringsolar radiation in the atmospheric boundary layer on the northern edge of Mexico

  6. Lead exposure at uncovered outdoor firing ranges

    SciTech Connect (OSTI)

    Goldberg, R.L.; Hicks, A.M.; O'Leary, L.M.; London, S. (University of Southern California School of Medicine, Los Angeles (USA))

    1991-06-01

    Excessive lead exposure in shooting instructors at indoor firing ranges and covered outdoor firing ranges has been documented. The City of Los Angeles assessed exposure of its full-time shooting instructors at uncovered outdoor ranges via air monitoring and blood lead-level measurements. Results of these tests revealed that significant lead exposure and absorption can occur at outdoor firing ranges. The use of copper-jacketed ammunition may decrease air lead levels and decrease lead absorption by range instructors.

  7. Lead Safety Awareness This Bulletin provides information on the safe handling of lead

    E-Print Network [OSTI]

    Lead Safety Awareness PURPOSE This Bulletin provides information on the safe handling of lead and lead compounds during use and storage. Improper handling of lead and lead compounds may impact operations at Department of Energy (DOE) facilities. BACKGROUND Lead is found in batteries, pipes, solder

  8. The influence of cosmic rays on the size of the Antarctic Ozone Hole

    E-Print Network [OSTI]

    M. Alvarez Madrigal; J. Perez Peraza; V. M. Velasco

    2010-01-15

    The Antarctic region in which severe ozone depletion has taken place is known as the ozone hole. This region has two basic indicators: the area, where the ozone abundance is low (size), and the quantity of ozone mass deficit (depth). The energetic particles that penetrate deeply into the atmosphere and galactic cosmic rays (GCR) modify the ozone abundance in the stratosphere. With this research project, we are looking for evidence of a connection between variations in the cosmic ray flux and variations in the size of the ozone hole. In addition, we are looking for signs of the kind of processes that physically connect GCR fluxes with variations in the stratospheric ozone hole size (OHS) in the Antarctic region. With this goal in mind, we also analyze here the atmospheric temperature (AT) anomalies, which have often been linked with such variations. Using Morlet's wavelet spectral analysis to compute the coherence between two time series, we found that during the analyzed period (1982-2005), there existed a common signal of around 3 and 5 years between the OHS and GCR time series, during September and November, respectively. In both cases, the relationship showed a time-dependent anti-correlation between the two series. On the other hand, for October the analysis showed a time-dependent correlation that occurs around 1.7 years. These results seem to indicate that there exist at least two kinds of modulation processes of GCR fluxes on the OHS that work simultaneously but that change their relative relevance along the timeline.

  9. On the temperature dependence of organic reactivity, nitrogen oxides, ozone production, and the impact of emission controls in San Joaquin Valley, California

    E-Print Network [OSTI]

    Pusede, S. E.

    The San Joaquin Valley (SJV) experiences some of the worst ozone air quality in the US, frequently exceeding the California 8 h standard of 70.4 ppb. To improve our understanding of trends in the number of ozone violations ...

  10. Overview of ozone human exposure and health risk analyses used in the U.S. EPA's review of the ozone air quality standard.

    SciTech Connect (OSTI)

    Whitfield, R. G.

    1999-03-04

    This paper presents an overview of the ozone human exposure and health risk analyses developed under sponsorship of the U.S. Environmental Protection Agency (EPA). These analyses are being used in the current review of the national ambient air quality standards (NAAQS) for ozone. The analyses consist of three principal steps: (1) estimating short-term ozone exposure for particular populations (exposure model); (2) estimating population response to exposures or concentrations (exposure-response or concentration-response models); and (3) integrating concentrations or exposure with concentration-response or exposure-response models to produce overall risk estimates (risk model). The exposure model, called the probabilistic NAAQS exposure model for ozone (pNEM/03), incorporates the following factors: hourly ambient ozone concentrations; spatial distribution of concentrations; ventilation state of individuals at time of exposure; and movement of people through various microenvironments (e.g., outdoors, indoors, inside a vehicle) of varying air quality. Exposure estimates are represented by probability distributions. Exposure-response relationships have been developed for several respiratory symptom and lung function health effects, based on the results of controlled human exposure studies. These relationships also are probabilistic and reflect uncertainties associated with sample size and variability of response among subjects. The analyses also provide estimates of excess hospital admissions in the New York City area based on results from an epidemiology study. Overall risk results for selected health endpoints and recently analyzed air quality scenarios associated with alternative 8-hour NAAQS and the current 1-hour standard for outdoor children are used to illustrate application of the methodology.

  11. Post-treatment of fly ash by ozone in a fixed bed reactor

    SciTech Connect (OSTI)

    Kim Hougaard Pedersen; Merc Casanovas Meli; Anker Degn Jensen; Kim Dam-Johansen

    2009-01-15

    The residual carbon in fly ash produced from pulverized coal combustion can adsorb the air-entraining admixtures (AEAs) added to enhance air entrainment in concrete. This behavior of the ash can be suppressed by exposing the fly ash to oxidizing species, which oxidizes the carbon surface and thus prevents the AEA to be adsorbed. In the present work, two fly ashes have been ozonated in a fixed bed reactor and the results showed that ozonation is a potential post-treatment method that can lower the AEA requirements of a fly ash up to 6 times. The kinetics of the carbon oxidation by ozone was found to be fast. A kinetic model has been formulated, describing the passivation of carbon, and it includes the stoichiometry of the ozone consumption (0.8 mol of O{sub 3}/kg of C) and an ineffective ozone loss caused by catalytic decomposition. The simulated results correlated well with the experimental data. 28 refs., 7 figs., 3 tabs.

  12. Visible ozone injury on mature black cherry in two Class I wilderness areas

    SciTech Connect (OSTI)

    Chappelka, A. [Auburn Univ., AL (United States). School of Forestry; Skelly, J.; Hildebrand, E. [Pennsylvania Univ., University Park, PA (United States). Dept. of Plant Pathology; Renfro, J. [USDI-NPS, Gatlinburg, TN (United States)

    1995-12-31

    During the summer of 1991--1993, the incidence and severity of foliar symptoms due to ambient ozone exposures were documented on mature black cherry (Prunus serotina) in two Class 1 areas in the Appalachian mountains of the eastern US: Great Smoky Mountains National Park (GRSM) and Shenandoah National Park (SHEN). Three plots in each park containing 30 trees each (Big Meadows in SHEN had 60 trees evaluated each year) with 90 and 120 trees evaluated per GRSM and SHEN, respectively. Plots were established adjacent to ozone monitoring stations at different elevations. Samples of foliage from trees were collected by tree climbers and three exposed branches from the upper crown and three branches form the mid-to-lower crown were evaluated for symptoms of foliar injury due to ozone. Incidence was the greatest in 1991 at both locations; 45% and 60% for SHEN and GRSM, respectively. In 1992 and 1993, incidence was very similar in both parks, with approximately 33% of the trees affected. Black cherry at the highest elevations exhibited the greatest amount of symptoms in both parks all three years of investigation. These sites also exhibited the highest levels of ozone. The results indicate that visible injury due to ambient ozone is prevalent in Class 1 areas in the eastern US, indicative of the nature of this regional phytotoxicant.

  13. Occurrence and severity of foliar ozone symptoms on sensitive hardwood species in Shenandoah National Park, VA

    SciTech Connect (OSTI)

    Hildebrand, E.; Skelly, J.M. (Pennsylvania State Univ., University Park (United States))

    1993-02-01

    To assess the extent of foliar symptoms due to ozone on sensitive hardwoods in the Shenandoah National Park in Virginia, three species were sampled and evaluated at sites of differing elevations adjacent to 3 ozone monitors in 1991 and 1992: black cherry, yellow poplar, and white ash. All foliar samples were evaluated to precent of symptomatic leaves on each branch and average precent leaf area affected. The Horsfall-Barratt rating scale was used to estimate the precent leaf area symptomatic. Ozone symptoms were manifested as stipple on the adazial leaf surface. In the preliminary 1991 sampling, 40, 87, and 7% of black cherry trees sampled were found to be symptomatic at the 3 sites; 63 and 67% of yellow poplar trees sampled were found to be symptomatic at sites 1 and 3, as were 43 and 63% of the white ash at sites 1 and 2 (3 complete sets were not found in 1991). In 1992, the sampling and rating of injury were repeated. Symptoms of ozone injury appeared on 23, 88, and 10% of black cherry, on 17, 7, and 80% of yellow poplar, and 27, 40, and 40% of white ash. Elevation and ozone exposure will be discussed.

  14. Carbon monoxide alleviates ethanol-induced oxidative damage and inflammatory stress through activating p38 MAPK pathway

    SciTech Connect (OSTI)

    Li, Yanyan; Gao, Chao; Shi, Yanru; Tang, Yuhan; Liu, Liang; Xiong, Ting; Du, Min; Xing, Mingyou; Liu, Liegang; Yao, Ping

    2013-11-15

    Stress-inducible protein heme oxygenase-1(HO-1) is well-appreciative to counteract oxidative damage and inflammatory stress involving the pathogenesis of alcoholic liver diseases (ALD). The potential role and signaling pathways of HO-1 metabolite carbon monoxide (CO), however, still remained unclear. To explore the precise mechanisms, ethanol-dosed adult male Balb/c mice (5.0 g/kg.bw.) or ethanol-incubated primary rat hepatocytes (100 mmol/L) were pretreated by tricarbonyldichlororuthenium (II) dimmer (CORM-2, 8 mg/kg for mice or 20 ?mol/L for hepatocytes), as well as other pharmacological reagents. Our data showed that CO released from HO-1 induction by quercetin prevented ethanol-derived oxidative injury, which was abolished by CO scavenger hemoglobin. The protection was mimicked by CORM-2 with the attenuation of GSH depletion, SOD inactivation, MDA overproduction, and the leakage of AST, ALT or LDH in serum and culture medium induced by ethanol. Moreover, CORM-2 injection or incubation stimulated p38 phosphorylation and suppressed abnormal Tnfa and IL-6, accompanying the alleviation of redox imbalance induced by ethanol and aggravated by inflammatory factors. The protective role of CORM-2 was abolished by SB203580 (p38 inhibitor) but not by PD98059 (ERK inhibitor) or SP600125 (JNK inhibitor). Thus, HO-1 released CO prevented ethanol-elicited hepatic oxidative damage and inflammatory stress through activating p38 MAPK pathway, suggesting a potential therapeutic role of gaseous signal molecule on ALD induced by naturally occurring phytochemicals. - Highlights: • CO alleviated ethanol-derived liver oxidative and inflammatory stress in mice. • CO eased ethanol and inflammatory factor-induced oxidative damage in hepatocytes. • The p38 MAPK is a key signaling mechanism for the protective function of CO in ALD.

  15. Lead Exposure Alters the Development of Agonistic

    E-Print Network [OSTI]

    Delville, Yvon

    Lead Exposure Alters the Development of Agonistic Behavior in Golden Hamsters M. Catalina Cervantes@mail.utexas.edu ABSTRACT: We tested the effects of exposure to different doses of lead acetate (either 0, 25, 100, or 400-specific effect of lead exposure on the development of aggression during puberty at doses resulting in blood

  16. LEAD COMMISSIONER REPORT RENEWABLE POWER IN

    E-Print Network [OSTI]

    LEAD COMMISSIONER REPORT RENEWABLE POWER IN CALIFORNIA: STATUS AND ISSUES DECEMBER 2011 CEC1502011002LCFREV1 #12;CALIFORNIA ENERGY COMMISSION 2011 INTEGRATED ENERGY POLICY REPORT LEAD COMMISSIONER of the 2011 Integrated Energy Policy Report Lead Commissioner. It does not necessarily represent the views

  17. ELLIPSOMETRY OF SULFATE FILMS ON LEAD

    E-Print Network [OSTI]

    Muller, R. H.

    2011-01-01

    Of SUlfATE fILMS ON LEAD R. H. Muller R. D. Peters May 1979be due to changes on the lead surface (instead of in theELLIPSOMETRY OF SULFATE FILMS ON LEAD R. H. Muller and R. D.

  18. Safety Policy LEAD IN PAINT POLICY

    E-Print Network [OSTI]

    Powers, Robert

    Safety Policy (10/96) LEAD IN PAINT POLICY://ehs.unl.edu/) Purpose: Lead is a recognized health hazard, and consequently, regulations have been developed to assure protection from excessive exposure to lead. Paints and coatings manufactured prior to 1978 often contained

  19. LEAD at Unidata Status Update, October 2009

    E-Print Network [OSTI]

    LEAD at Unidata Status Update, October 2009 Mohan Ramamurthy The official period of performance for the LEAD project ended on 30 September 2009 after a one-year the no-cost extension period. The six year ITR computing and networking to huge data sets, human decision making and complex virtual organizations ­ LEAD

  20. Appendix C.1 THE LEAD LABORATORY

    E-Print Network [OSTI]

    Appendix C.1 THE LEAD LABORATORY By PATRICK J. PARSONS, Ph.D.1 J. JULIAN CHISOLM, JR., M.D.2 Role of the Laboratory Laboratories measure lead concentrations in either clinical samples between the clinical and environmental lead laboratories and the issues that they face. Often

  1. Contrasting Surface Ozone and Particulate Matter measurements with meteorological conditions in South Florida and its possible impacts on the number of Asthma cases: Five years of correlations.

    E-Print Network [OSTI]

    Miami, University of

    Contrasting Surface Ozone and Particulate Matter measurements with meteorological conditions, wind speed and direction), and air quality indicators (ozone O3 and particulate matter PM2.5) are presented in this study. Surface Ozone and Particulate Matter have been both important triggers of asthma

  2. Effects of ozone on the common bed bug (Cimex lectularius) James Feston, Marissa McDonough, Linda Mason, Timothy Gibb, Kurt Saltzmann

    E-Print Network [OSTI]

    Ginzel, Matthew

    Effects of ozone on the common bed bug (Cimex lectularius) James Feston, Marissa McDonough, Linda of ozone in stored maize. Journal of Stored Products Research 37(4): 371-382. McDonough, M., Mason, L., Woloshuk, C. 2011. Susceptibility of stored product insects to high concentrations of ozone at different

  3. Effects of Atmospheric Ozone on Microarray Data Thomas L. Fare, Ernest M. Coffey, Hongyue Dai, Yudong D. He, Deborah A. Kessler,

    E-Print Network [OSTI]

    Kilian, Kristopher A.

    Effects of Atmospheric Ozone on Microarray Data Quality Thomas L. Fare, Ernest M. Coffey, Hongyue. Ozone levels were monitored and highly correlated with the batch effect. Controlled exposures of microarrays to ozone confirmed this factor as the root cause, and we present data that show susceptibility

  4. Ozone fluxes in a Pinus ponderosa ecosystem are dominated by non-stomatal processes: Evidence from long-term continuous measurements

    E-Print Network [OSTI]

    Goldstein, Allen

    Ozone fluxes in a Pinus ponderosa ecosystem are dominated by non-stomatal processes: Evidence from and Atmospheric Research Utrecht, Utrecht University, Utrecht, The Netherlands 1. Introduction Ozone is considered one of the most dangerous oxidant molecules for plants (UNECE, 2004; EPA, 2007). Ozone concentra- tion

  5. IEEE TRANSACTIONS ON GEOSCIENCE AND REMOTE SENSING, VOL. 46, NO. 2, FEBRUARY 2008 479 Retrieval of Total Column Ozone From Imagers

    E-Print Network [OSTI]

    Li, Jun

    of Total Column Ozone From Imagers Onboard Geostationary Satellites Xin Jin, Jun Li, Christopher C. Schmidt) onboard METEOSAT 8 provide at- mospheric total column ozone (TCO) with high temporal (better than 15 min. The SEVIRI TCO demon- strates how well geostationary imagers can capture ozone trans- port and change at high

  6. Thesis proposal CSF Brazil 2014 Efficiency evaluation of ozonated water for control diseases in typical Brazilian crops

    E-Print Network [OSTI]

    Bordenave, Charles

    Thesis proposal CSF Brazil 2014 Title: Efficiency evaluation of ozonated water for control diseases., Violleau, F., 2013. Ozonated water as a potential biological control agent: Pruning wound protection is used for many years for water treatment. This powerful oxidant permits destruction of #12

  7. Repeatability of the Seasonal Variations of Ozone near the Mesopause from Observations of the 11.072-GHz Line

    E-Print Network [OSTI]

    Rogers, Alan E. E.

    Ground-based observations of the 11.072-GHz line of ozone were made from January 2008 through the middle of September 2011 to estimate the maximum in the nighttime ozone in the upper mesosphere at an altitude of about 95 ...

  8. Impact of ozone on indoor air quality: a preliminary field study M. Nicolas, O. Ramalho, F. Maupetit

    E-Print Network [OSTI]

    Boyer, Edmond

    indoor air quality (IAQ) since they produce secondary pollutants, mainly aldehydes which are known to document the impact on IAQ of outdoor ozone during summer air pollution episodes. For this purpose, a oneImpact of ozone on indoor air quality: a preliminary field study M. Nicolas, O. Ramalho, F

  9. Higher surface ozone concentrations over the Chesapeake Bay than over the adjacent land: Observations and models from the

    E-Print Network [OSTI]

    Dickerson, Russell R.

    , in high enough concentrations, is a hazardous secondary air pollutant regulated by the United States t s Observations of ozone are higher over the Chesapeake Bay than areas upwind on land. Dry deposition rates, slower dry deposition rates, and other lesser mechanisms, contribute to the local maximum of ozone over

  10. Leading the Way Leading the WayUniversity of Colorado Catalog

    E-Print Network [OSTI]

    Mojzsis, Stephen J.

    Leading the Way Leading the WayUniversity of Colorado Catalog Leading the Way Boulder 2002­03 #12 children in the village of San Pablo, Belize, don't haul water up a steep hill in buckets anymore because

  11. Ultrahigh vacuum and low-temperature cleaning of oxide surfaces using a low-concentration ozone beam

    SciTech Connect (OSTI)

    Pratt, A. [National Institute for Materials Science, 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047 (Japan); Department of Physics, University of York, Heslington, York YO10 5DD (United Kingdom); Graziosi, P.; Bergenti, I.; Dediu, A. [CNR – ISMN, Consiglio Nazionale delle Ricerche – Istituto per lo Studio dei Materiali Nanostrutturati, v. Gobetti 101, 40129 Bologna (Italy); Prezioso, M. [Department of Electrical and Computer Engineering, Harold Frank Hall, University of California, Santa Barbara, California 93106 (United States); Yamauchi, Y., E-mail: yamauchi.yasushi@nims.go.jp [National Institute for Materials Science, 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047 (Japan)

    2014-07-15

    We present a novel method of delivering a low-concentration (<15%) ozone beam to an ultra-high vacuum environment for the purpose of cleaning and dosing experimental samples through oxidation processing. The system described is safe, low-cost, and practical and overcomes the limitations of ozone transport in the molecular flow environment of high or ultrahigh vacuum whilst circumventing the use of pure ozone gas which is potentially highly explosive. The effectiveness of this method in removing surface contamination is demonstrated through comparison of high-temperature annealing of a simple oxide (MgO) in ozone and oxygen environments as monitored using quadrupole mass spectroscopy and Auger electron spectroscopy. Additionally, we demonstrate the potential of ozone for obtaining clean complex oxide surfaces without the need for high-temperature annealing which may significantly alter surface structure.

  12. Abiotic ozone and oxygen in atmospheres similar to prebiotic Earth

    SciTech Connect (OSTI)

    Domagal-Goldman, Shawn D.; Segura, Antígona; Claire, Mark W.; Robinson, Tyler D.; Meadows, Victoria S.

    2014-09-10

    The search for life on planets outside our solar system will use spectroscopic identification of atmospheric biosignatures. The most robust remotely detectable potential biosignature is considered to be the detection of oxygen (O{sub 2}) or ozone (O{sub 3}) simultaneous to methane (CH{sub 4}) at levels indicating fluxes from the planetary surface in excess of those that could be produced abiotically. Here we use an altitude-dependent photochemical model with the enhanced lower boundary conditions necessary to carefully explore abiotic O{sub 2} and O{sub 3} production on lifeless planets with a wide variety of volcanic gas fluxes and stellar energy distributions. On some of these worlds, we predict limited O{sub 2} and O{sub 3} buildup, caused by fast chemical production of these gases. This results in detectable abiotic O{sub 3} and CH{sub 4} features in the UV-visible, but no detectable abiotic O{sub 2} features. Thus, simultaneous detection of O{sub 3} and CH{sub 4} by a UV-visible mission is not a strong biosignature without proper contextual information. Discrimination between biological and abiotic sources of O{sub 2} and O{sub 3} is possible through analysis of the stellar and atmospheric context—particularly redox state and O atom inventory—of the planet in question. Specifically, understanding the spectral characteristics of the star and obtaining a broad wavelength range for planetary spectra should allow more robust identification of false positives for life. This highlights the importance of wide spectral coverage for future exoplanet characterization missions. Specifically, discrimination between true and false positives may require spectral observations that extend into infrared wavelengths and provide contextual information on the planet's atmospheric chemistry.

  13. Water relations of differentially irrigated cotton exposed to ozone

    SciTech Connect (OSTI)

    Temple, P.J.

    1990-01-01

    The field study was conducted to test the hypothesis that plants chronically exposed to O{sub 3} may be more susceptible to drought because O{sub 3} typically inhibits root growth and increases shoot-root ratios in plants. Cotton was grown in open-top chambers on Hanford coarse sandy loam in Riverside, CA. Plants were grown under three irrigation regimes: Optimum water for lint production (OW), suboptimum or moderate drought stress (SO), and severely drought stressed (SS) and were exposed to seasonal 12 h (0800-2000) O{sub 3} centrations of 0.015, 0.074, 0.094, or 0.111/microLL. Leaf xylem pressure potentials Psi(sub 1) and soil water content Theta(sub v) were measured weekly from June to October. Mean seasonal Psi(sub 1) increased from -1.89 MPa to -1.72 MPa in low to high O{sub 3} treatments, averaged across soil water regimes. Ozone had no effect on seasonal water use of cotton, but water use efficiency was significantly reduced by O{sub 3} in OW and SO, but not in SS treatments. Drought-stressed plants extracted proportionally greater amounts of water from deeper in the soil profile than OW cotton, and O{sub 3} had no apparent effect on this redistribution of roots in the soil. Since O{sub 3} had no apparent effect on the ability of drought-stressed cotton to maintain Psi(sub 1) and to increase root growth relative to shoot growth, this suggests that O{sub 3} may have little or no effect on the potential of cotton to adapt to or tolerate drought.

  14. Process for the production of hydrogen and carbonyl sulfide from hydrogen sulfide and carbon monoxide using a multi-metal oxide/sulfide catalyst

    SciTech Connect (OSTI)

    Jevnikar, M. G.; Kuch, Ph. L.

    1985-02-19

    Hydrogen and carbonyl sulfide are produced by a process comprising contacting gaseous hydrogen sulfide with gaseous carbon monoxide in the presence of a catalytic composition containing an oxide and/or sulfide of at least one of molybdenum, tungsten, iron, chromium and vanadium in combination with at least one promoter metal, e.g. a catalyst of the formula Cs Cu /SUB 0.2/ Zn /SUB 0.5/ Mn /SUB 0.5/ Sn /SUB 2.4/ Mo O /SUB x/ S /SUB y/ .

  15. NRF2 activation is involved in ozonated human serum upregulation of HO-1 in endothelial cells

    SciTech Connect (OSTI)

    Pecorelli, Alessandra [Department of Molecular and Developmental Medicine, University of Siena (Italy); Child Neuropsychiatry Unit, University Hospital, AOUS, Siena (Italy); Bocci, Velio [Department of Physiology, University of Siena (Italy); Acquaviva, Alessandra [Department of Molecular and Developmental Medicine, University of Siena (Italy); Belmonte, Giuseppe [Department of Biomedical Sciences, University of Siena (Italy); Gardi, Concetta [Department of Molecular and Developmental Medicine, University of Siena (Italy); Virgili, Fabio [INRAN, Rome (Italy); Ciccoli, Lucia [Department of Molecular and Developmental Medicine, University of Siena (Italy); Valacchi, Giuseppe, E-mail: giuseppe.valacchi@unife.it [Department of Life Sciences and Biotechnology, University of Ferrara (Italy); Department of Food and Nutrition, Kyung Hee University, Seoul (Korea, Republic of)

    2013-02-15

    During the last decade, it has been shown that the activation of NRF2 and the binding to electrophile-responsive element (EpREs), stimulates the expression of a great number of genes responsible for the synthesis of phase I and phase II proteins, including antioxidants enzymes and heme oxygenase-1 (HO-1). This critical cell response occurs in cardiovascular, degenerative and chronic infective diseases aggravated by a chronic oxidative stress. In our previous reports we have shown that ozonated plasma is able to up-regulate HO-1 expression in endothelial cells. In the present work we investigated a candidate mechanism involved in this process. After treatment with increasing doses of ozonated serum (20, 40 and 80 ?g/mL O{sub 3} per mL of serum), a clear dose dependent activation of NRF2 and the subsequent induction of HO-1 and NAD(P)H quinone oxidoreductase 1(NQO1) was observed. This effect was also present when cells were treated with serum and hydrogen peroxide (H{sub 2}O{sub 2}) or serum and 4-hydroxynonenal (4HNE). Moreover, the treatment with ozonated serum was associated with a dose-dependent activation of extracellular-signal-regulated kinases (ERK1/2) and p38 MAP kinases (p38), not directly involved in NRF2 activation. These data, provide a new insight on the mechanism responsible for the induction of HO-1 expression by ozonated serum in the endothelium, and have a practical importance as an expedient approach to the treatment of patients with both effective orthodox drugs and ozonated autohemotherapy, targeted to the restoration of redox homeostasis. - Highlights: ? Endothelial HO1 is upregulated by ozonated plasma ? This activation is induced by NRF2 and it is ERK independent. ? 4HNE and H{sub 2}O{sub 2} are the main molecules involved in this process. ? Ozonated plasma induced a hormetic effect ? Combination of orthodox medicine and ozonated plasma can be a useful treatment.

  16. 19USDA Forest Service Gen.Tech.Rep. PSW-GTR-166. 1998. A variety of vascular plant species exhibit typical foliar injury symptoms when exposed to ambient ozone, making

    E-Print Network [OSTI]

    exhibit typical foliar injury symptoms when exposed to ambient ozone, making them useful as bioindicators ozone monitors are not available. Bioindicators are often introduced plant species known as sentinels. They are known to be sensitive to ozone and will respond rapidly if they are given special care to ensure ozone

  17. Quality Support G. Q. Kirk, Lead (4)

    E-Print Network [OSTI]

    Quality Support G. Q. Kirk, Lead (4) R. L. Bullock (4) A. C. Hendricks (4) G. H. Henkel (4) D. L. Ramsey B. F. Siefken Electrical/I&C D. S. Wilder, Lead D. S. Asquith (5) B. L. Coday B. P. Ducamp C. D Technology J. K. Keith, Jr., Lead J. L. Anderson (8) M. B. Anderson (5) C. F. Guyett (8) S. N. Hammonds

  18. VOLUME 87, NUMBER 19 P H Y S I C A L R E V I E W L E T T E R S 5 NOVEMBER 2001 Distinct Reaction Mechanisms in the Catalytic Oxidation of Carbon Monoxide on Rh(110)

    E-Print Network [OSTI]

    Hla, Saw-Wai

    Mechanisms in the Catalytic Oxidation of Carbon Monoxide on Rh(110): Scanning Tunneling Microscopy for catalytic oxidation of hydrogen on a platinum surface [3]. In the latter case, the two different mechanisms calculations, we identify the reaction mechanism for the oxidation of carbon monoxide to carbon dioxide

  19. Pulmonary and gastric lead burden assessment for lead-recycling plant , J.J Sauvain2

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Pulmonary and gastric lead burden assessment for lead-recycling plant workers Uzu, G.1 , J Chimiques des Métaux, 30 Avenue de Fondeyre 31200 Toulouse, France Key words: bioaccessibility, DTT, lead) and origin (furnace, refining and channeled emissions), lead toxicity and bioaccessibility assessment were

  20. Lead(ii) Detection An Exceptionally Selective Lead(ii)-Regulatory

    E-Print Network [OSTI]

    He, Chuan

    Lead(ii) Detection An Exceptionally Selective Lead(ii)-Regulatory Protein from Ralstonia Metallidurans: Development of a Fluorescent Lead(ii) Probe** Peng Chen, Bill Greenberg, Safiyh Taghavi, Christine Romano, Daniel van der Lelie, and Chuan He* Lead contamination is a serious threat to human health

  1. Identification of sources of lead exposure in French children by lead isotope analysis: a cross-

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Identification of sources of lead exposure in French children by lead isotope analysis: a cross://www.ehjournal.net/content/10/1/75 (28 August 2011) #12;RESEARCH Open Access Identification of sources of lead exposure in French children by lead isotope analysis: a cross- sectional study Youssef Oulhote1,2,3* , Barbara Le Bot

  2. Compatibility of PETN with lead azide

    SciTech Connect (OSTI)

    Hurd, R.; Fronabarger, J.W.; Johnson, R.; Fleming, W.

    1983-01-01

    The compatibility of PETN with lead azide at elevated temperatures has been investigated. Ramped and isothermal DSC methods were used to obtain energies of activation at temperatures above the melting point of PETN. Mixtures were found to show exothermic activity at lower temperatures than pure PETN. High Pressure Liquid Chromatography was used to follow the decomposition of PETN and PETN/lead azide mixtures at temperatures below the melting point. Reaction below 120/sup 0/C appeared minimal, while at higher temperatures, both PETN and PETN/lead azide mixtures showed degradation. A PETN/lead azide sample exploded at or near the melting point of PETN.

  3. Thermal conductivity of bulk nanostructured lead telluride

    E-Print Network [OSTI]

    Hori, Takuma

    Thermal conductivity of lead telluride with embedded nanoinclusions was studied using Monte Carlo simulations with intrinsic phonon transport properties obtained from first-principles-based lattice dynamics. The ...

  4. LEAD SUBSTITUTION AND ELIMINATION STUDY, PART II

    SciTech Connect (OSTI)

    T. MARTINEZ; M. COURNOYER

    2001-01-01

    Within the Nuclear Materials Technology Division of Los Alamos National Laboratory, lead is used as shielding for a variety of operations, including actinide chemistry, weapons production, radiochemistry, and analytical chemistry. In this study, waste minimization issues associated with replacing lead shielding with non-hazardous materials are addressed. These include institutional program available to support this effort, the hazards and accompanying controls grouped with lead shielding, operations that use lead bricks and how this effects the selection of the substitute. Life cycle management issues are also examined. As a final step, an approach to get buy-in from both technical and budget minded employees is presented.

  5. Electrical Engineer (Power Electronics, Lead Engineer) | Princeton...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Engineer (Power Electronics, Lead Engineer) Department: Engineering Supervisor(s): Albert von Halle Requisition Number: 1500733 The Princeton University Plasma Physics Laboratory...

  6. Downregulation of Cinnamyl Alcohol Dehydrogenase (CAD) Leads...

    Office of Scientific and Technical Information (OSTI)

    of Cinnamyl Alcohol Dehydrogenase (CAD) Leads to Improved Saccharification Efficiency in Switchgrass Citation Details In-Document Search Title: Downregulation of Cinnamyl...

  7. Study of air pollution: Effects of ozone on neuropeptide-mediated responses in human subjects. Final report

    SciTech Connect (OSTI)

    Boushey, H.A.

    1991-11-01

    The study examined the hypothesis that ozone inactivates the enzyme, neutral endopeptidase, responsible for limiting the effects of neuropeptides released from afferent nerve endings. Cough response of capsaicin solution delivered from a nebulizer at 2 min. intervals until two or more coughs were produced. Other endpoints measured included irritative symptoms as rated by the subjects on a nonparametric scale, spirometry, of each concentration of ozone were compared to those of filtered air in a single-blind randomized sequence. The results indicate that a 2 h. exposure to 0.4 ppm of ozone with intermittent light exercise alters the sensitivity of airway nerves that mediate the cough response to inhaled materials. This dose of ozone also caused a change in FEV1. A lower level of ozone, 0.02 ppm, caused a change in neither cough threshold nor FEV1, even when the duration of exposure was extended to three hours. The findings are consistent with the author's hypothesis that ozone may sensitize nerve endings in the airways by inactivating neutral endopeptidase, an enzyme that regulates their activity, but they do not demonstrate that directly examining an effect directly mediated by airway nerves allows detection of effects of ozone at doses below those causing effects detected by standard tests of pulmonary function.

  8. INVESTIGATIONS ON THE USE OF ANODIC STRIPPING VOLTAMMETRY FOR THE ANALYSES OF LEAD IN SALINE ENVIRONMENTS

    E-Print Network [OSTI]

    Case, Charles W.

    2011-01-01

    A - Lead Data . . . . . . . . . . . . . . . . . . . . .10 Lead ..of Lead . . . . . . . . . . . . . . . . . . . . . 119 -2ce

  9. A Large Ozone-Circulation Feedback & Its Implications for Global Warming Assessments

    E-Print Network [OSTI]

    Jackson, Sophie

    Peer A Large Ozone-Circulation Feedback & Its Implications for Global Warming Assessments PeerCO2, b T by 4xCO2, c T by O3 and d water vapour by O3. 4. GLOBAL WARMING RESPONSE 0 50 100 150 200 250) Figure 1 | Temporal evolution of the annual and global mean surface tem- perature anomalies. Interactive

  10. A large ozone-circulation feedback and its implications for global warming assessments

    E-Print Network [OSTI]

    Nowack, Peer J.; Abraham, N. Luke; Maycock, Amanda C.; Braesicke, Peter; Gregory, Jonathan M.; Joshi, Manoj M.; Osprey, Annette; Pyle, John A.

    2014-12-01

    -climate model, we find an increase in global mean surface warming of around 1°C (~20%) after 75 years when ozone is prescribed at pre-industrial levels compared with when it is allowed to evolve self-consistently in response to an abrupt 4xCO2 forcing...

  11. A neural emission-receptor model for ozone reduction S.Barazzetta, G. Corani

    E-Print Network [OSTI]

    Corani, Giorgio

    in air pollution studies because of their impact on human health and agricultural crops and forests. High,guariso@elet.polimi.it Abstract: Ground level ozone pollution is a complex phenomenon heavily affecting industrialized and pop problem that determines the least cost alternatives to obtain a given air quality standard. The decision

  12. The sensitivity of modeled ozone to the temporal distribution of point, area, and mobile source emissions

    E-Print Network [OSTI]

    Dickerson, Russell R.

    emissions in the eastern United States Patricia Castellanos , Sheryl H. Ehrman* , Jeffrey W. Stehr , Russell pollution problems in the US. Hourly emissions fields used in air quality models (AQMs) generally show less of estimated emissions affects modeled ozone, we analyzed the effects of altering all anthropogenic emissions

  13. Constraining global isoprene emissions with Global Ozone Monitoring Experiment (GOME) formaldehyde column measurements

    E-Print Network [OSTI]

    Palmer, Paul

    Constraining global isoprene emissions with Global Ozone Monitoring Experiment (GOME) formaldehyde emission estimates are highly uncertain because of a lack of direct observations. Formaldehyde (HCHO the observation of this trace gas to help constrain isoprene emissions. We use HCHO column observations from

  14. Earth'sFuture Stratospheric ozone response to a solar irradiance reduction

    E-Print Network [OSTI]

    Jackman, Charles H.

    Earth'sFuture Stratospheric ozone response to a solar irradiance reduction in a quadrupled CO2) solar irradiance is imposed to help counteract a quadrupled CO2 atmo- sphere. This study is similar) a perturbed future atmosphere with 1140 ppmv CO2 and a 4% reduction in the TOA total solar irradiance (G1). We

  15. A Spatial Econometric Approach to Measuring Pollution Externalities: An Application to Ozone Smog

    E-Print Network [OSTI]

    Lin, C.-Y. Cynthia

    to analyze air pollution externalities. State-by-state source-receptor transfer coefficients that can be used of the six cri- teria pollutants for which National Ambient Air Quali- ty Standards have been establishedA Spatial Econometric Approach to Measuring Pollution Externalities: An Application to Ozone Smog C

  16. Future climate change in the Southern Hemisphere: Competing effects of ozone and greenhouse gases

    E-Print Network [OSTI]

    Arblaster, Julie

    Future climate change in the Southern Hemisphere: Competing effects of ozone and greenhouse gases J 2010; accepted 19 October 2010; published 19 January 2011. [1] Future anthropogenic climate change simulations. Citation: Arblaster, J. M., G. A. Meehl, and D. J. Karoly (2011), Future climate change

  17. D) Kinetic Study of Key Ozone Depleting Substances and Greenhouse Gases

    E-Print Network [OSTI]

    Jackman, Charles H.

    O(1 D) Kinetic Study of Key Ozone Depleting Substances and Greenhouse Gases Munkhbayar Baasandorj) and greenhouse gases (GHGs) is reaction with the O(1 D) atom. In this study, rate coefficients, k, for the O(1 D) and greenhouse gases (GHGs). Quantifying the atmospheric loss processes of ODSs and GHGs is essential

  18. Biogenic 2-methyl-3-buten-2-ol increases regional ozone and HOx sources

    E-Print Network [OSTI]

    Goldstein, Allen

    similar daily maxima of about 5 mg mÀ2 hrÀ1 . MBO oxidation causes an increase in ozone, formaldehyde, acetone and consequently hydrogen radical production (PHOx). The addition of MBO increases the daily in the Central Valley. Formaldehyde concentrations increase by as much as 1 ppb (40%) over the Sierra Nevada

  19. Sources of HOx and production of ozone in the upper troposphere over the United States

    E-Print Network [OSTI]

    Jacob, Daniel J.

    1 Sources of HOx and production of ozone in the upper troposphere over the United States L. Jaegl. Campos,3 G. W. Sachse4 Abstract. The sources of HOx (OH+peroxy radicals) and the as- sociated production injection of peroxides (CH3OOH and H2O2) and formaldehyde (CH2O) from the boundary layer to the upper tro

  20. Comparison of model estimates of the effects of aviation emissions on atmospheric ozone and methane

    E-Print Network [OSTI]

    Jacobson, Mark

    of the world econ- omy and demand for aviation and its emissions are expected to increase in the future from aviation (mainly carbon dioxide (CO2), water vapor (H2O), nitrogen oxides (NOx = NO + NO2), VOCsComparison of model estimates of the effects of aviation emissions on atmospheric ozone and methane

  1. Foliar ozone injury on different-sized Prumus serotina Ehrh. trees

    SciTech Connect (OSTI)

    Fredericksen, T.S.; Skelly, J.M.; Steiner, K.C. [Pennsylvania State Univ., University Park, PA (United States)

    1995-06-01

    Black cherry (Prunus serotina Ehrh.) is a common tree species in the eastern U.S. that is highly sensitive to ozone relative to other associated deciduous tree species. Because of difficulties in conducting exposure-response experiments on large trees, air pollution studies have often utilized seedlings and extrapolated the results to predict the potential response of larger forest trees. However, physiological differences between seedlings and mature forest trees may alter responses to air pollutants. A comparative study of seedling, sapling, and canopy black cherry trees was conducted to determine the response of different-sized trees to known ozone exposures and amounts of ozone uptake. Apparent foliar sensitivity to ozone, observed as a dark adaxial leaf stipple, decreased with increasing tree size. An average of 46% of seedling leaf area was symptomatic by early September, compared to 15% - 20% for saplings and canopy trees. In addition to visible symptoms, seedlings also appeared to have greater rates of early leaf abscission than larger trees. Greater sensitivity (i.e., foliar symptoms) per unit exposure with decreasing tree size was closely correlated with rates of stomatal conductance. However, after accounting for differences in stomatal conductance, sensitivity appeared to increase with tree size.

  2. Narrowband filter radiometer for ground-based measurements of global ultraviolet solar irradiance and total ozone

    SciTech Connect (OSTI)

    Petkov, Boyan; Vitale, Vito; Tomasi, Claudio; Bonafe, Ubaldo; Scaglione, Salvatore; Flori, Daniele; Santaguida, Riccardo; Gausa, Michael; Hansen, Georg; Colombo, Tiziano

    2006-06-20

    The ultraviolet narrowband filter radiometer (UV-RAD) designed by the authors to take ground-based measurements of UV solar irradiance, total ozone, and biological dose rate is described, together with the main characteristics of the seven blocked filters mounted on it, all of which have full widths at half maxima that range 0.67 to 0.98 nm. We have analyzed the causes of cosine response and calibration errors carefully to define the corresponding correction terms, paying particular attention to those that are due to the spectral displacements of the filter transmittance peaks from the integer wavelength values. The influence of the ozone profile on the retrieved ozone at large solar zenith angles has also been examined by means of field measurements. The opportunity of carrying out nearly monochromatic irradiance measurements offered by the UV-RAD allowed us to improve the procedure usually followed to reconstruct the solar spectrum at the surface by fitting the computed results, using radiative transfer models with field measurements of irradiance. Two long-term comparison campaigns took place, showing that a mean discrepancy of+0.3% exists between the UV-RAD total ozone values and those given by the Brewer no. 63 spectroradiometer and that mean differences of+0.3% and-0.9% exist between the erythemal dose rates determined with the UV-RAD and those obtained with the Brewer no. 63 and the Brewer no. 104 spectroradiometers, respectively.

  3. Ground-level ozone following astrophysical ionizing radiation events: an additional biological hazard?

    E-Print Network [OSTI]

    Thomas, Brian C

    2015-01-01

    Astrophysical ionizing radiation events such as supernovae, gamma-ray bursts, and solar proton events have been recognized as a potential threat to life on Earth, primarily through depletion of stratospheric ozone and subsequent increase in solar UV radiation at Earth's surface and in the upper levels of the ocean. Other work has also considered the potential impact of nitric acid rainout, concluding that no significant threat is likely. Not yet studied to-date is the potential impact of ozone produced in the lower atmosphere following an ionizing radiation event. Ozone is a known irritant to organisms on land and in water and therefore may be a significant additional hazard. Using previously completed atmospheric chemistry modeling we have examined the amount of ozone produced in the lower atmosphere for the case of a gamma-ray burst and find that the values are too small to pose a significant additional threat to the biosphere. These results may be extended to other ionizing radiation events, including supe...

  4. Carbon Monoxide Safety Tips 

    E-Print Network [OSTI]

    Shaw, Bryan W.; Garcia, Monica L.

    1999-07-26

    problems can stem from a number of common sources?automo- biles, furnaces, water heaters, fireplaces, wood stoves, charcoal grills, gas ranges, space heaters and portable generators. Serious problems can develop when these appliances are not in good working... from one type to another without proper knowledge, skills and tools. 3 Never use a gas range, oven or clothes dryer for heating your home. 3 Never operate unvented gas-burning appli- ances, such as kerosene or natural gas space heaters, in a closed room...

  5. Comprehensive study of tropospheric ozone in the western Pacific Rim: Data analysis and 3-dimensional model simulation

    SciTech Connect (OSTI)

    Sunwoo, Y.

    1993-01-01

    The behavior of tropospheric ozone in the western Pacific Rim is studied utilizing satellite, surface, and sonde measurements along with numerical simulations with a three dimensional model. The results from this study show that a combination of transport, both vertical and horizontal, and photochemistry, near source regions and following range transport, determine the spatial and temporal distribution of tropospheric ozone in the western Pacific Rim. Surface level point measurements are mostly affected by local and regional meteorology, elevation, and proximity to source regions. The seasonal cycle exhibits a strong spring maximum, with higher values relative to the rest of the world, and a summer minimum, the latter being a result of regional meteorology specific to this area. Interactions with dust originating from the Chinese deserts may be causing perturbations in the ozone concentrations as they are mixed together during long range transport. These basic features of ozone behavior are being confirmed at a site in nearby Korea. Measurements of the tropospheric ozone column densities in the western Pacific Rim from satellite data have been analyzed. The column ozone has a broad spring-summer peak for East Asia with the highest values located within the latitude band of 30[approximately]40[degrees]N. Correlation studies show that the influence of photochemistry is most prominent in the summer. In the colder months, the regions above and below 35[degrees]N appear to be governed by a different combination of influencing factors. Validation studies with ozonesonde and surface ozone measurements generally show good agreement but the discrepancy for the summer season has yet to be completely resolved. Three-dimensional simulation results from a transport/chemistry/removal model show that the long range transport of ozone and its precursors have a significant impact on the ozone concentrations at remote locations far removed from source regions.

  6. Photoproduction at HERA with a Leading Proton

    E-Print Network [OSTI]

    Photoproduction at HERA with a Leading Proton Hanna Mahlke­Kr¨uger H1 Collaboration, DESY Abstract. The total cross­section for the semi­inclusive photoproduction process with a leading proton in the final­sections refer to the kinematic range with transverse momenta of the scattered proton restricted to p T Ÿ 0:2 Ge

  7. Managing lead-based paint abatement wastes

    SciTech Connect (OSTI)

    Steele, N.L.C.

    1994-12-31

    Renovation, remodeling, demolition, and surface preparation for painting, in addition to specified lead abatement, are all activities that have the potential to produce hazardous wastes if a property was painted with lead-based paint. Lead-based paint was used on residential structures until 1978, when most residential uses were banned by the Consumer Products Safety Council. Prior to the 1950s, paints for residential uses may have contained up to 50% lead by weight. Today, commercial and military paints may still contain lead and can be used on non-residential structures. The lead content of residential paints is limited to 0.06% lead (by weight) in the dried film. This paper provides an overview of some of the information needed to properly manage lead-based paint abatement wastes. The issues covered in this paper include waste classification, generator status, treatment, and land disposal restrictions. The author assumes that the reader is familiar with the provision of the Health and Safety Code and the California Code of Regulations that pertain to generation and management of hazardous wastes. Citations provided herein do not constitute an exhaustive list of all the regulations with which a generator of hazardous waste must comply.

  8. Fan-fold shielded electrical leads

    DOE Patents [OSTI]

    Rohatgi, R.R.; Cowan, T.E.

    1996-06-11

    Disclosed are fan-folded electrical leads made from copper cladded Kapton, for example, with the copper cladding on one side serving as a ground plane and the copper cladding on the other side being etched to form the leads. The Kapton is fan folded with the leads located at the bottom of the fan-folds. Electrical connections are made by partially opening the folds of the fan and soldering, for example, the connections directly to the ground plane and/or the lead. The fan folded arrangement produces a number of advantages, such as electrically shielding the leads from the environment, is totally non-magnetic, and has a very low thermal conductivity, while being easy to fabricate. 3 figs.

  9. Atmospheric lead in downtown Guatemala City

    SciTech Connect (OSTI)

    Durando, M.L.; Aragon, S.R.

    1982-01-01

    Atomic absorption (AA) analysis was employed to determine, for the first time in this country, lead concentrations in aerosols collected in Nuclepore filter media during the months of February and March (1980) in Guatemala City, Guatemala. In particular, the lead in the atmospheric fine particulate was measured in different downtown locations around noontime and in a single location at 1-h intervals throughout the day. The first was used to study short-term variations from one location to the other, and the second one was used to correlate parameters such as traffic density and wind velocity with the levels of airborne lead on the same day. In addition, this paper presents a brief discussion of the lead content in Guatemalan gasoline, the lead levels in street dusts, and the total suspended particulate matter in downtown Guatemala City.

  10. Fan-fold shielded electrical leads

    DOE Patents [OSTI]

    Rohatgi, Rajeev R. (Mountain View, CA); Cowan, Thomas E. (Livermore, CA)

    1996-01-01

    Fan-folded electrical leads made from copper cladded Kapton, for example, with the copper cladding on one side serving as a ground plane and the copper cladding on the other side being etched to form the leads. The Kapton is fan folded with the leads located at the bottom of the fan-folds. Electrical connections are made by partially opening the folds of the fan and soldering, for example, the connections directly to the ground plane and/or the lead. The fan folded arrangement produces a number of advantages, such as electrically shielding the leads from the environment, is totally non-magnetic, and has a very low thermal conductivity, while being easy to fabricate.

  11. Sea Breeze characteristics during a high ozone event over Houston 

    E-Print Network [OSTI]

    Naumann, Stephanie Alaine

    2001-01-01

    representing the wind field in the lowest 4 km. Results show that changes in the large-scale wind pattern, as seen at 850 mb, can explain differences in the sea breeze circulation. Onshore flow leads to a faster moving sea breeze front whereas light opposing...

  12. Public Health in East and Southeast Asia: Challenges and Opportunities in the Twenty-First Century

    E-Print Network [OSTI]

    Detels, Roger; Sullivan, Sheena G.; Tan, Chorh Chuan

    2012-01-01

    Fuel or tobacco combustion Carbon monoxide (CO) RemodelingCarbon monoxide (CO) Reactions of NOx and other volatile organic compounds in the atmosphere ­ Ozone (O ) Fossil fuel combustion

  13. The risk of lead toxicity in homes with lead paint hazard

    SciTech Connect (OSTI)

    Schwartz, J.; Levin, R. )

    1991-02-01

    While lead paint has long been known to be a major source of lead poisoning, only a few small epidemiologic studies have attempted to assess directly the relative risk of lead poisoning due to the presence of lead paint. Using data from over 200,000 screening tests of children in the city of Chicago performed between 1976 and 1980, the relative risks can be quantified for children living in a major urban area. Lead paint was found to be a significant predictor of the probability of a child having lead toxicity. As expected, the reduction in leaded gasoline sales during the period reduced mean blood lead levels and increased the percentage of lead toxic children whose toxicity could be attributed to paint lead. Poisson regression models indicated that with the elimination of leaded gasoline, the relative risk of lead toxicity given lead paint exposure was 5.70 (95% CI, 4.13-7.86) during the winter and fall. The relative risk rose to 12.81 (95% CI, 7.33-22.4) in the spring and 15.8 (95% CI, 8.90-28.1) in the summer, probably due to increased exposure to window wells.

  14. Method for measuring lead concentrations in blood

    DOE Patents [OSTI]

    Nogar, Nicholas S. (Los Alamos, NM)

    2001-01-01

    Method for measuring lead concentrations in blood. The present invention includes the use of resonant laser ablation to analyze .ltoreq.1 .mu.L (or equivalent mass) samples of blood for lead content. A typical finger prick, for example, yields about 10 .mu.L. Solid samples may also readily be analyzed by resonant laser ablation. The sample is placed on a lead-free, electrically conducting substrate and irradiated with a single, focused laser beam which simultaneously vaporizes, atomizes, and resonantly ionizes an analyte of interest in a sample. The ions are then sorted, collected and detected using a mass spectrometer.

  15. Sustainability Peer Educator Group Lead Positions Position: Sustainability Peer Educators Group Lead

    E-Print Network [OSTI]

    Boonstra, Rudy

    Sustainability Peer Educator Group Lead Positions Position: Sustainability Peer Educators Group times) Term of position: September 2013 ­ April 2014 Position Summary: Working with the Sustainability Project Coordinator, the Sustainability Peer Educator Group Leads will be responsible

  16. Corrosion by liquid lead and lead-bismuth: experimental results review and analysis

    SciTech Connect (OSTI)

    Zhang, Jinsuo

    2008-01-01

    Liquid metal technologies for liquid lead and lead-bismuth alloy are under wide investigation and development for advanced nuclear energy systems and waste transmutation systems. Material corrosion is one of the main issues studied a lot recently in the development of the liquid metal technology. This study reviews corrosion by liquid lead and lead bismuth, including the corrosion mechanisms, corrosion inhibitor and the formation of the protective oxide layer. The available experimental data are analyzed by using a corrosion model in which the oxidation and scale removal are coupled. Based on the model, long-term behaviors of steels in liquid lead and lead-bismuth are predictable. This report provides information for the selection of structural materials for typical nuclear reactor coolant systems when selecting liquid lead or lead bismuth as heat transfer media.

  17. Measurement of the production of neighbouring jets in lead-lead...

    Office of Scientific and Technical Information (OSTI)

    Measurement of the production of neighbouring jets in lead-lead collisions at sNN2.76 TeV with the ATLAS detector Citation Details In-Document Search Title: Measurement of the...

  18. Novel Carbon Monoxide Sensor for PEM Fuel Cell Systems C.T. Holt, A.-M. Azad, S.L. Swartz, W.J. Dawson, and P.K. Dutta

    E-Print Network [OSTI]

    Azad, Abdul-Majeed

    Research has been conducted to develop a novel sensor for the detection of carbon monoxide in the presence of hydrogen and nitrogen. The automotive fuel cell application requires a sensor to detect low levels will protect the PEM fuel cell stack; detection of CO is extremely important because too much CO will poison

  19. Final Technical Report "Catalytic Hydrogenation of Carbon Monoxide and Olefin Oxidation" Grant number : DE-FG02-86ER13615

    SciTech Connect (OSTI)

    Wayland, B.B.

    2009-08-31

    Title: Catalytic Hydrogenation of Carbon Monoxide and Olefin Oxidation Grant No. DE-FG02-86ER13615 PI: Wayland, B. B. (wayland@sas.upenn.edu) Abstract Development of new mechanistic strategies and catalyst materials for activation of CO, H2, CH4, C2H4, O2, and related substrates relevant to the conversion of carbon monoxide, alkanes, and alkenes to organic oxygenates are central objectives encompassed by this program. Design and synthesis of metal complexes that manifest reactivity patterns associated with potential pathways for the hydrogenation of carbon monoxide through metallo-formyl (M-CHO), dimetal ketone (M-C(O)-M), and dimetal dionyl (M-C(O)-C(O)-M) species is one major focus. Hydrocarbon oxidation using molecular oxygen is a central goal for methane activation and functionalization as well as regioselective oxidation of olefins. Discovery of new reactivity patterns and control of selectivity are pursued through designing new metal complexes and adjusting reaction conditions. Variation of reaction media promotes distinct reaction pathways that control both reaction rates and selectivities. Dimetalloradical diporphyrin complexes preorganize transition states for substrate reactions that involve two metal centers and manifest large rate increases over mono-metalloradical reactions of hydrogen, methane, and other small molecule substrates. Another broad goal and recurring theme of this program is to contribute to the thermodynamic database for a wide scope of organo-metal transformations in a range of reaction media. One of the most complete descriptions of equilibrium thermodynamics for organometallic reactions in water and methanol is emerging from the study of rhodium porphyrin substrate reactions in aqueous and alcoholic media. Water soluble group nine metalloporphyrins manifest remarkably versatile substrate reactivity in aqueous and alcoholic media which includes producing rhodium formyl (Rh-CHO) and hydroxy methyl (Rh-CH2OH) species. Exploratory directions for this program include expending new strategies for anti-Markovnikov addition of water, alcohols, and amines with olefins, developing catalytic reactions of CO to give formamides and formic esters, and evaluating the potential for coupling reactions of CO to produce organic building blocks.

  20. Electron transport in lead selenide nanocrystal arrays

    E-Print Network [OSTI]

    Schriver, Maria C

    2005-01-01

    I have investigated electrical properties of arrays of lead selenide (PbSe) nanocrystals (NC's) of approximately 6nm diameter. The films become substantially more conducting when annealed at 400K, although no chemical ...