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Note: This page contains sample records for the topic "monoxide ozone lead" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

Carbon Monoxide Safety Tips  

E-Print Network [OSTI]

Protect yourself and your family from the deadly effects of carbon monoxide--a colorless, odorless poisonous gas. This publication describes the warning signs of carbon monoxide exposure and includes a home safety checklist....

Shaw, Bryan W.; Garcia, Monica L.

1999-07-26T23:59:59.000Z

2

Carbon monoxide absorbing liquid  

SciTech Connect (OSTI)

The present disclosure is directed to a carbon monoxide absorbing liquid containing a cuprous ion, hydrochloric acid and titanum trichloride. Titanium trichloride is effective in increasing the carbon monoxide absorption quantity. Furthermore, titanium trichloride remarkably increases the oxygen resistance. Therefore, this absorbing liquid can be used continuously and for a long time.

Arikawa, Y.; Horigome, S.; Kanehori, K.; Katsumoto, M.

1981-07-07T23:59:59.000Z

3

Lead  

Energy Savers [EERE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of Inspector General Office0-72.pdfGeorgeDoesn't Happen to HighJosephNOx Traps forLM2LarryLaws andtopic Lead

4

SENSITIVE OPTOACOUSTIC DETECTION OF CARBON MONOXIDE BY RESONANCE ABSORPTION  

E-Print Network [OSTI]

Monoxide by Resonance Absorption Robert Gerlach and Nabil M.MONOXIDE BY RESONANCE ABSORPTION Robert Gerlach and Nabil M.the context of atmospheric absorption. The carbon monoxide

Gerlach, R.

2011-01-01T23:59:59.000Z

5

Investigation of the Atmospheric Ozone Impacts of Methyl Iodide  

E-Print Network [OSTI]

J. R. Holmes (1977): “Nitrogen Dioxide Photolysis in the LosO3 Ozone NO Nitric Oxide NO2 Nitrogen Dioxide NO3 NitrateNitrogen Pentoxide HONO Nitrous Acid HNO3 Nitric Acid HNO4 Peroxynitric Acid HO2H Hydrogen Peroxide CO Carbon Monoxide SO2 Sulfur Dioxide

Carter, W P L

2007-01-01T23:59:59.000Z

6

Ozone Reductions Using Residential Building Envelopes  

SciTech Connect (OSTI)

Ozone is an air pollutant with that can have significant health effects and a significant source of ozone in some regions of California is outdoor air. Because people spend the vast majority of their time indoors, reduction in indoor levels of ozone could lead to improved health for many California residents. Ozone is removed from indoor air by surface reactions and can also be filtered by building envelopes. The magnitude of the envelope impact depends on the specific building materials that the air flows over and the geometry of the air flow paths through the envelope that can be changes by mechanical ventilation operation. The 2008 Residential Building Standards in California include minimum requirements for mechanical ventilation by referencing ASHRAE Standard 62.2. This study examines the changes in indoor ozone depending on the mechanical ventilation system selected to meet these requirements. This study used detailed simulations of ventilation in a house to examine the impacts of different ventilation systems on indoor ozone concentrations. The simulation results showed that staying indoors reduces exposure to ozone by 80percent to 90percent, that exhaust ventilation systems lead to lower indoor ozone concentrations, that opening of windows should be avoided at times of high outdoor ozone, and that changing the time at which mechanical ventilation occurs has the ability to halve exposure to ozone. Future work should focus on the products of ozone reactions in the building envelope and the fate of these products with respect to indoor exposures.

Walker, Iain S.; Sherman, Max; Nazaroff, William W.

2009-02-01T23:59:59.000Z

7

(Carbon monoxide metabolism by photosynthetic bacteria)  

SciTech Connect (OSTI)

Research continued on the metabolism of carbon monoxide by Rhodospirillum rubrum. This report discusses progress on the activity, induction, inhibition, and spectroscopic analysis of the enzyme Carbon Monoxide Dehydrogenase. (CBS)

Not Available

1989-01-01T23:59:59.000Z

8

Advanced Diesel Combustion with Low Hydrocarbon and Carbon Monoxide...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Combustion with Low Hydrocarbon and Carbon Monoxide Emissions Advanced Diesel Combustion with Low Hydrocarbon and Carbon Monoxide Emissions Poster presented at the 16th Directions...

9

Catalytic activation of carbon monoxide on metal surfaces  

SciTech Connect (OSTI)

In discussing the important basic aspects of carbon monoxide chemistry, this review covers the adsorption and reaction of CO with H/sub 2/O and H/sub 2/ on reduced metal surfaces. Carbon monoxide adsorption of the Group VIII metals exhibits certain patterns. Typically, as coverages exceed one-half, compression occurs in the monolayer and the molecules lose registry with the surface metal atoms. Particular sites associated with rough surfaces facilitate CO dissociation to the surface carbon; these sites may have a significant effect on selectivity in the CO hydrogenation reaction. The support used and the metal crystallite size both affect the catalyst activity and product selectivity. Indications are strong that a better knowledge of metal-support interactions combined with a more complete understanding of the surface chemistry involved will lead to improved catalyst systems in the future.

Vannice, M.A.

1982-01-01T23:59:59.000Z

10

Supporting Information for Impact of Chlorine Emissions from Sea-Salt Aerosol on Coastal Urban Ozone  

E-Print Network [OSTI]

DIOXIDE H2O2 HYDROGEN PEROXIDE NH3 AMMONIA NIT AEROSOL NITRATE SO2 SULFUR DIOXIDE SO3 SULFUR TRIOXIDE OSD extensions* NO NITRIC OXIDE NO2 NITROGEN DIOXIDE O3 OZONE HONO NITROUS ACID HNO3 NITRIC ACID HNO4 PERNITRIC ACID N2O5 NITROGEN PENTOXIDE NO3 NITRATE RADICAL HO2 HYDROPEROXY RADICAL CO CARBON MONOXIDE CO2 CARBON

Dabdub, Donald

11

Desorption of carbon monoxide from nickel using mercaptans  

SciTech Connect (OSTI)

An IR spectroscopic study on the displacement of carbon monoxide with 1-propyl, 2-propyl-, 1-butyl-, 2-butyl-, and tert.-butyl mercaptan from nickel foil and silica-supported nickel showed that at low carbon monoxide coverage on supported nickel, mercaptan adsorption initially converted bridged to linear carbon monoxide surface species. At higher mercaptan pressures, carbon monoxide desorbed into the gas phase. A small amount of carbon monoxide remained on the surface when the poisoned sample was evacuated, and additional carbon monoxide adsorbed when 5 mm Hg of carbon monoxide was added to the evacuated sample.

Neff, L.D.; Sturdivant, A.E.; Wallace, J.L.

1980-06-01T23:59:59.000Z

12

Carbon Monoxide Poisoning Avoided Through Weatherization | Department...  

Broader source: Energy.gov (indexed) [DOE]

systems in recipients' homes. "We had a chain -- one right after another," says Debbie Biggs, weatherization director for C-SCDC. "One had carbon monoxide levels so high we told...

13

Mechanism of methanol synthesis from carbon monoxide and hydrogen on copper catalysts  

SciTech Connect (OSTI)

The authors examine possible mechanisms of methanol synthesis from carbon monoxide and hydrogen on supported copper catalysts. Two broad categories of reaction mechanism can be identified: (a) Type I: Carbon monoxide, adsorbed on the copper surface, is hydrogenated by the addition of hydrogen atoms while the C-O bond remains intact. A second C-O bond is neither formed nor broken. (b) Type II: Carbon monoxide (or a partially hydrogenated intermediate, e.g., HCO) reacts with an oxygen atom on the catalyst surface to give an intermediate, typically a formate, which contains two C-O bonds. Subsequent reaction leads overall to methanol and the reformation of the surface oxygen atom. Both mechanisms are discussed.

Fakley, M.E.; Jennings, J.R.; Spencer, M.S. (ICI Chemicals and Polymers Ltd, Billingham, Cleveland (England))

1989-08-01T23:59:59.000Z

14

A study of the effect of ozone and antioxidants on ozone-sensitive loblolly pine  

E-Print Network [OSTI]

and exposed to LSX ambient ozone for two months. Arrows indicate pestained SDS-PAGE molecular weight standards (kD) and Rubisco large subunit. Lane R = pure spinach Rubisco large subunit. Lanes 1 and 2 = control seedlings in the Ozoban study. Lanes 3 and 4... radicals are produced during normal metabolism when oxygen is reduced to water. Grimes et al. (1983) studied the products that form from ozone in cells and found no detectable superoxide radicals, leading them to propose that either ozone or hydroxyl...

Posey, Karen Lashea

1995-01-01T23:59:59.000Z

15

[Carbon monoxide metabolism by photosynthetic bacteria]. Progress report  

SciTech Connect (OSTI)

Research continued on the metabolism of carbon monoxide by Rhodospirillum rubrum. This report discusses progress on the activity, induction, inhibition, and spectroscopic analysis of the enzyme Carbon Monoxide Dehydrogenase. (CBS)

Not Available

1989-12-31T23:59:59.000Z

16

Ozone heating and the destabilization of traveling waves during summer  

SciTech Connect (OSTI)

The effects of ozone heating on the linear stability of lower stratospheric traveling waves of the summertime, extratropical circulation are examined. Based on coupled equations for the quasigeostrophic potential vorticity and ozone volume mixing ratio, it is shown that the diabatic heating arising from ozone advection can offset the damping due to Newtonian cooling, leading to wave amplification and significant changes in the structure and zonally rectified fluxes of the wave fields in both the lower stratosphere and troposphere. The vertical profile of the zonal mean wind plays a crucial role in determining whether the ozone heating destabilizes eastward and/or westward traveling disturbances.

Nathan, T.R.; Cordero, E.C.; Li, L. [Univ. of California, Davis, CA (United States)] [Univ. of California, Davis, CA (United States)

1994-07-01T23:59:59.000Z

17

Population based exposure assessment methodology for carbon monoxide: Development of a Carbon Monoxide Passive Sampler and Occupational Dosimeter  

E-Print Network [OSTI]

Monoxide in Seatde Ice Skating Rinks." American Journal ofHockey Players in Ice Skating Rinks." Veterinary and Human

Apte, Michael G.

2010-01-01T23:59:59.000Z

18

NC State to lead NSF Nanosystems Engineering Research Center on self-powered health monitoring  

E-Print Network [OSTI]

than a human hair -- and thermoelectric and piezoelectric materials that use body heat and motion exposure data for environmental pollutants such as ozone and carbon monoxide, sick people could better manage chronic diseases, and healthy people could make even better decisions to keep themselves fit

Buckel, Jeffrey A.

19

Isotopic equilibration of carbon monoxide catalyzed by supported ruthenium  

SciTech Connect (OSTI)

Isotopic equilibration of carbon monoxide catalyzed by supported ruthenium was studied with oxygen-18 and carbon-13 labeled carbon monoxide in the presence and absence of hydrogen. The results showed that carbon monoxide was present on commercial alumina-supported ruthenium in a reactive undissociated form at 373/sup 0/K; that it adsorbed as a single carbonyl and in a geminal dicarbonyl form; and that hydrogen inhibited the exchange reaction by competitive adsorption and by stabilizing the carbonyl bond. The results elucidate the carbon monoxide methanation and Fischer-Tropsch reactions on this catalyst.

Bossi, A. (Cent. Ric. Novara); Zanderighi, L.; Carnisio, G.; Garbassi, F.; Giunchi, G.; Petrini, G.

1980-09-01T23:59:59.000Z

20

Advanced Diesel Combustion with Low Hydrocarbon and Carbon Monoxide...  

Broader source: Energy.gov (indexed) [DOE]

Combustion with Low Hydrocarbon and Carbon Monoxide Emissions Poster Location P-19 Gregory K. Lilik, Andr L. Boehman Department of Energy & Mineral Engineering EMS Energy...

Note: This page contains sample records for the topic "monoxide ozone lead" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

E-Print Network 3.0 - ambient carbon monoxide Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

FACT SHEET Carbon monoxide (CO), known as the Invisible Killer... , propane, oil, wood, coal, and gasoline. Exposure to carbon monoxide can cause flu-like symptoms and can... .)...

22

Process for producing carbon monoxide and hydrogen from methanol  

SciTech Connect (OSTI)

A process is described for producing carbon monoxide and hydrogen which comprises contacting methanol vapor at a temperature of 200 degrees to 300 degrees C with an indirectly heated zinc containing catalyst to obtain an effluent gas in which the components of carbon monoxide and hydrogen constitute at least 90% by volume of said gas. At least a part of the impurities from said effluent gas are removed and said effluent gas is deparated into its carbon monoxide and hydrogen components by adsorption. The effluent gas can be separated into its carbon monoxide and hydrogen components by use of a plurality of adsorbers containing zeolite-type molecular sieve material where the zeolite is substantially permeable to hydrogen but sorbs carbon monoxide.

Jockel, H.; Marschner, F.; Moller, F.W.; Mortel, H.

1982-02-23T23:59:59.000Z

23

Carbon monoxide exposure of subjects with documented cardiac arrhythmias  

SciTech Connect (OSTI)

The impact of low-level carbon monoxide exposure on ventricular arrhythmia frequency in patients with ischemic heart disease has not been thoroughly studied. The issue is of concern because of the potential proarrhythmic effect of carbon monoxide in patients with ischemic heart disease. We studied 30 subjects with well-documented coronary artery disease who had an average of at least 30 ventricular ectopic beats per hour over a 20-hour monitoring interval. By using appropriate inclusion and exclusion criteria, subjects were selected and enrolled in a randomized double-blind study to determine the effects of carbon monoxide exposure on ventricular arrhythmia frequency at rest, during exercise, and during ambulatory activities. The carbon monoxide exposure was designed to result in 3% or 5% carboxyhemoglobin levels, as measured by gas chromatography. The carbon monoxide exposure protocol produced target levels in 60 minutes, and the levels were maintained for an additional 90 minutes to provide adequate time to assess the impact of carbon monoxide on the frequency of ventricular ectopic beats. The data on total and repetitive ventricular arrhythmias were analyzed for seven specific time intervals: (1) two hours before carbon monoxide exposure; (2) during the two-hour carbon monoxide or air exposure; (3) during a two-hour rest period; (4) during an exercise period; (5) during an exercise recovery period; (6) six hours after carbon monoxide or air exposure; and (7) approximately 10 hours after exposure, or the remaining recording interval on the Holter monitor. There was no increase in ventricular arrhythmia frequency after carbon monoxide exposure, regardless of the level of carboxyhemoglobin or the type of activity.

Chaitman, B.R.; Dahms, T.E.; Byers, S.; Carroll, L.W.; Younis, L.T.; Wiens, R.D. (St. Louis Univ. School of Medicine, MO (United States))

1992-09-01T23:59:59.000Z

24

7, 97959828, 2007 Tropospheric ozone  

E-Print Network [OSTI]

ACPD 7, 9795­9828, 2007 Tropospheric ozone climatology over Beijing A. J. Ding et al. Title Page Chemistry and Physics Discussions Tropospheric ozone climatology over Beijing: analysis of aircraft data;ACPD 7, 9795­9828, 2007 Tropospheric ozone climatology over Beijing A. J. Ding et al. Title Page

Paris-Sud XI, Université de

25

8, 1106311101, 2008 Tropospheric Ozone  

E-Print Network [OSTI]

ACPD 8, 11063­11101, 2008 Tropospheric Ozone climatology in the southern subtropics G. Clain et al.0 License. Atmospheric Chemistry and Physics Discussions Tropospheric ozone climatology at two southern Tropospheric Ozone climatology in the southern subtropics G. Clain et al. Title Page Abstract Introduction

Paris-Sud XI, Université de

26

Carbon monoxide sensor for PEM fuel cell systems Christopher T. Holta,*  

E-Print Network [OSTI]

reforming) or with air and water (autothermal reforming). In the second step, carbon monoxide is reduced

Azad, Abdul-Majeed

27

Carbon monoxide sensor and method of use thereof  

DOE Patents [OSTI]

Carbon monoxide sensors suitable for use in hydrogen feed streams and methods of use thereof are disclosed. The sensors are palladium metal/insulator/semiconductor (Pd-MIS) sensors which may possess a gate metal layer having uniform, Type 1, or non-uniform, Type 2, film morphology. Type 1 sensors display an increased sensor response in the presence of carbon monoxide while Type 2 sensors display a decreased response to carbon monoxide. The methods and sensors disclosed herein are particularly suitable for use in proton exchange membrane fuel cells (PEMFCs).

McDaniel; Anthony H. (Livermore, CA), Medlin; J. Will (Boulder, CO), Bastasz; Robert J. (Livermore, CA)

2007-09-04T23:59:59.000Z

28

Carbon Monoxide, Ozone, Hydrocarbon Air Quality Standards, and Related Emission Requirements (Ohio)  

Broader source: Energy.gov [DOE]

This chapter defining the roles of the Ohio Environmental Protection Agency gives specific detail on the regulation point-source air pollution for a variety of industries and pollutants.

29

Vacancies in ordered and disordered titanium monoxide: Mechanism of B1 structure stabilization  

SciTech Connect (OSTI)

The electronic structure and stability of three phases of titanium monoxide TiO{sub y} with B1 type of the basic structure have been studied. Cubic phase without structural vacancies, TiO, and two phases with structural vacancies, monoclinic Ti{sub 5}O{sub 5} and cubic disordered TiO{sub 1.0}, was treated by means of first-principles calculations within the density functional theory with pseudo-potential approach based on the plane wave's basis. The ordered monoclinic phase Ti{sub 5}O{sub 5} was found to be the most stable and the cubic TiO without vacancies the less stable one. The role of structural vacancies in the titanium sublattice is to decrease the Fermi energy, the role of vacancies in the oxygen sublattice is to contribute to the appearance of Ti–Ti bonding interactions through these vacancies and to reinforce the Ti–Ti interactions close to them. Listed effects are significantly pronounced if the vacancies in the titanium and oxygen sublattices are associated in the so called “vacancy channels” which determine the formation of vacancy ordered structure of monoclinic Ti{sub 5}O{sub 5}-type. - Graphical abstract: Changes in total DOS of titanium monoxide when going from vacancy-free TiO to TiO with disordered structural vacancies and to TiO with ordered structural vacancies. Highlights: • Ordered monoclinic Ti{sub 5}O{sub 5} is the most stable phase of titanium monoxide. • Vacancy-free TiO is the less stable phase of the titanium monoxide. • Ordering of oxygen vacancies leads to the appearance of Ti–Ti bonding interactions. • Titanium vacancies contribute significantly to the decreasing of the Fermi energy.

Kostenko, M.G. [Institute of Solid State Chemistry, The Ural Branch of the Russian Academy of Sciences, Pervomayskaya 91, Ekaterinburg 620990 (Russian Federation); Lukoyanov, A.V. [Institute of Metal Physics, The Ural Branch of the Russian Academy of Sciences, S. Kovalevskoy 18, Ekaterinburg 620990 (Russian Federation); Ural Federal University named after First President of Russia B.N. Yeltsin, Mira 19, Ekaterinburg 620002 (Russian Federation); Zhukov, V.P. [Institute of Solid State Chemistry, The Ural Branch of the Russian Academy of Sciences, Pervomayskaya 91, Ekaterinburg 620990 (Russian Federation); Rempel, A.A., E-mail: rempel@ihim.uran.ru [Institute of Solid State Chemistry, The Ural Branch of the Russian Academy of Sciences, Pervomayskaya 91, Ekaterinburg 620990 (Russian Federation); Ural Federal University named after First President of Russia B.N. Yeltsin, Mira 19, Ekaterinburg 620002 (Russian Federation)

2013-08-15T23:59:59.000Z

30

Ozone decomposing filter  

DOE Patents [OSTI]

In an improved ozone decomposing air filter carbon fibers are held together with a carbonized binder in a perforated structure. The structure is made by combining rayon fibers with gelatin, forming the mixture in a mold, freeze-drying, and vacuum baking.

Simandl, Ronald F. (Farragut, TN); Brown, John D. (Harriman, TN); Whinnery, Jr., LeRoy L. (Dublin, CA)

1999-01-01T23:59:59.000Z

31

Molten metal reactor and method of forming hydrogen, carbon monoxide and carbon dioxide using the molten alkaline metal reactor  

DOE Patents [OSTI]

A molten metal reactor for converting a carbon material and steam into a gas comprising hydrogen, carbon monoxide, and carbon dioxide is disclosed. The reactor includes an interior crucible having a portion contained within an exterior crucible. The interior crucible includes an inlet and an outlet; the outlet leads to the exterior crucible and may comprise a diffuser. The exterior crucible may contain a molten alkaline metal compound. Contained between the exterior crucible and the interior crucible is at least one baffle.

Bingham, Dennis N.; Klingler, Kerry M.; Turner, Terry D.; Wilding, Bruce M.

2012-11-13T23:59:59.000Z

32

Predicting tropospheric ozone and hydroxyl radical in a global, three-dimensional, chemistry, transport, and deposition model  

SciTech Connect (OSTI)

Two of the most important chemically reactive tropospheric gases are ozone (O{sub 3}) and the hydroxyl radical (OH). Although ozone in the stratosphere is a necessary protector against the sun`s radiation, tropospheric ozone is actually a pollutant which damages materials and vegetation, acts as a respiratory irritant, and is a greenhouse gas. One of the two main sources of ozone in the troposphere is photochemical production. The photochemistry is initiated when hydrocarbons and carbon monoxide (CO) react with nitrogen oxides (NO{sub x} = NO + NO{sub 2}) in the presence of sunlight. Reaction with the hydroxyl radical, OH, is the main sink for many tropospheric gases. The hydroxyl radical is highly reactive and has a lifetime on the order of seconds. Its formation is initiated by the photolysis of tropospheric ozone. Tropospheric chemistry involves a complex, non-linear set of chemical reactions between atmospheric species that vary substantially in time and space. To model these and other species on a global scale requires the use of a global, three-dimensional chemistry, transport, and deposition (CTD) model. In this work, I developed two such three dimensional CTD models. The first model incorporated the chemistry necessary to model tropospheric ozone production from the reactions of nitrogen oxides with carbon monoxide (CO) and methane (CH{sub 4}). The second also included longer-lived alkane species and the biogenic hydrocarbon isoprene, which is emitted by growing plants and trees. The models` ability to predict a number of key variables (including the concentration of O{sub 3}, OH, and other species) were evaluated. Then, several scenarios were simulated to understand the change in the chemistry of the troposphere since preindustrial times and the role of anthropogenic NO{sub x} on present day conditions.

Atherton, C.S.

1995-01-05T23:59:59.000Z

33

Determination of the atherogenic potential of inhaled carbon monoxide  

SciTech Connect (OSTI)

he effects of chronic exposure to moderate levels of carbon monoxide upon the augmentation of arteriosclerotic plaque development were investigated in a series of in vivo studies in the cockerel (young rooster). This animal model has been well characterized, especially regarding the role of environmental agents in exacerbating early stages of plaque development. Cockerels injected with subtumorigenic doses of carcinogens exhibit markedly accelerated development of aortic arteriosclerotic plaques. Inhalation of mainstream smoke from two packs of cigarettes (100 minutes/day for 16 weeks) causes small but statistically significant increases in plaque size. As is the case with many animal models of plaque development, raised fat-proliferative plaques also appear in these animals following cholesterol feeding. Carbon monoxide is a ubiquitous pollutant in urban environments, where it is derived largely from mobile sources and cigarette smoke. Exposure to chronically elevated carbon monoxide levels has been implicated in a number of health-related problems. Whether such exposure plays a role in the development of arteriosclerosis has not been determined conclusively. In the present study, three questions were posed: 1. Will inhaled carbon monoxide at levels of 50 to 200 parts per million (ppm)* (two hours/day for 16 weeks) be sufficient to augment arteriosclerotic plaque development in cockerels, in the absence of other plaque-promoting agents 2. Will the inhalation of 100 ppm carbon monoxide (two hours/day for 16 weeks), concomitant with the feeding of low levels (0.1%) of cholesterol, yield larger plaques than those obtained with either of these agents administered alone 3. Will inhalation of 100 ppm carbon monoxide (two hours/day for 11 or 22 weeks), by cockerels in whom plaques have already appeared, further augment plaque development Cockerels were exposed to carefully regulated levels of carbon monoxide in stainless-steel and Plexiglas dynamic exposure chambers.

Penn, A. (New York Univ. Medical Center, NY (United States))

1993-05-01T23:59:59.000Z

34

Reductions in ozone concentrations due to controls on variability in industrial flare emissions in Houston, Texas  

E-Print Network [OSTI]

High concentrations of ozone in the Houston/Galveston area are associated with industrial plumes of highly reactive hydrocarbons, mixed with NOx. The emissions leading to these plumes can have significant temporal variability, ...

Nam, Junsang

2007-01-01T23:59:59.000Z

35

Ambient Air Quality Standards (New Jersey)  

Broader source: Energy.gov [DOE]

This article lists specific standards for ambient air quality standards for particulate matter, sulfur dioxide, carbon monoxide, ozone, lead and nitrogen dioxide.

36

Kinetic model of catalytic oxidation of carbon monoxide on nickel  

SciTech Connect (OSTI)

A mechanism is proposed for describing the previous disclosed multiplicity of equilibrium states in the oxidation of carbon monoxide on metallic nickel. In contrast to the known mechanism for oxidation of CO on platinum metals it includes a nonlinear stage of carbon monoxide adsorption and a linear stage of oxygen adsorption. A kinetic model has been obtained and stage velocity constants have been found, providing a basis for obtaining a quantitative agreement between the calculated and experimental relations between the reaction velocity and the reagent concentrations. Opinions are stated in relation to the causes for evolution of the CO oxidation reaction from platinum metals to nickel.

Pyatnitskii, Yu.I.; Ostapyuk, V.A.

1986-07-01T23:59:59.000Z

37

Photobiogeochemical cycling of carbon monoxide in the southeastern Beaufort Sea in spring and autumn  

E-Print Network [OSTI]

Photobiogeochemical cycling of carbon monoxide in the southeastern Beaufort Sea in spring the distribution, photoproduction, microbial uptake, and air­sea exchange of carbon monoxide (CO), a key that in warmer seas. Carbon monoxide (CO) is the dominant sink for hydroxyl radicals in the troposphere, thus

Vincent, Warwick F.

38

Mechanistical studies on the formation of carbon dioxide in extraterrestrial carbon monoxide ice analog samples  

E-Print Network [OSTI]

be produced via radiolysis of carbon monoxide ices.5 Indeed, the effects of ionizing radiation on pure carbonMechanistical studies on the formation of carbon dioxide in extraterrestrial carbon monoxide ice901220f Binary ice mixtures of two carbon monoxide isotopomers, 13 C16 O and 12 C18 O, were subjected

Kaiser, Ralf I.

39

Transformation of carbon monoxide dimer surface structures on yttrium oxide modified by silver  

SciTech Connect (OSTI)

It has been established that introducing ions of silver(II) in yttrium(III) oxide leads to the formation of a significant concentration of a paramagnetic dimer species (CO)/sub 2/-in the course of the adsorption of carbon monoxide, and that these dimers exhibit high thermal stability and reactivity. Reactions are proposed for the formation of the dimer species (CO)/sub 2//sup 2 -/ and (CO)/sub 2//sup -/ on the surface of the Ag/Y/sub 2/O/sub 3/ catalyst that involve the reduction of the anion vacancies and a change in the oxidation state of the silver ions. Modifying the yttrium oxide with ionic silver leads to a marked decrease in the strength of the oxidative ability of the surface of the catalyst for CO, while the nature of the active sites of the yttrium oxide, which adsorbs CO in three forms, remains unchanged.

Vydrin, S.N.; Bobolev, A.V.; Loginov, A.Yu.

1987-09-10T23:59:59.000Z

40

Titanium dioxide based high temperature carbon monoxide selective sensor  

E-Print Network [OSTI]

Titanium dioxide based high temperature carbon monoxide selective sensor Nancy O. Savagea , Sheikh as a trap for the oxidation products of CO and CH4. Upon oxidation of CO on ALC, carbonate species were detected, whereas the reaction of CH4 produced negligible carbonate species. The insensitivity of the ALC

Dutta, Prabir K.

Note: This page contains sample records for the topic "monoxide ozone lead" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Infrared spectra of carbon monoxide adsorbed on palladium black  

SciTech Connect (OSTI)

The authors investigate the heterogeneous adsorption of carbon monoxide and the concurrent catalytic and sorptive properties of palladium black from the standpoint of a comprehensive analysis of the infrared spectra of the reaction pathways and their various products as well as the pressure dependence of the line behavior at various wavelengths.

Vozdvizhenskii, V.F.; Levintova, T.D.; Sokol'skii, D.V.

1986-06-01T23:59:59.000Z

42

Disproportionation of carbon monoxide on supported nickel catalysts  

SciTech Connect (OSTI)

The disproportionation of carbon monoxide was investigated mainly on a 5.5% Ni/Al/sub 2/O/sub 3/ catalyst by infrared spectroscopy and temperature-programmed desorption. The reaction was found to be of first order with respect to the surface concentration of CO below 200/sup 0/C, while at 450/sup 0/C the reaction proceeded as a second order reaction for the pressure of CO. Results obtained with predeposited carbon indicated that the disproportionation reaction requires an ensemble of several nickel atoms. In agreement with this result, the disproportionation did not take place readily on a 1.1% Ni/Al/sub 2/O/sub 3/ catalyst on which a high dispersion of the metal was indicated by both infrared spectroscopy and the chemisorption of hydrogen. In the temperature-programmed desorption (TPD) carbon monoxide desorbed in a single peak before 300/sup 0/C. Some of the carbon monoxide, however, underwent disproportionation during TPD and a carbon dioxide peak appeared at about 220/sup 0/C. Furthermore, carbon thus deposited on the surface was oxidized to carbon monoxide by oxygen supplied from the catalysts and gave a second peak of CO in TPD at temperatures higher than 300/sup 0/C. Possible sources of the oxygen were discussed.

Galuszka, J.; Chang, J.R.; Amenomiya, Y.

1981-03-01T23:59:59.000Z

43

Detection of iodine monoxide in the tropical free troposphere  

E-Print Network [OSTI]

19, 2012) Atmospheric iodine monoxide (IO) is a radical that catalytically destroys heat trapping in the remote tropical marine boundary layer (MBL) (2­4). IO further affects the oxidative capacity iodine species over the remote ocean remain poorly understood (11, 14) but are currently thought

44

Quantitative analysis of SCIAMACHY carbon monoxide total column measurements  

E-Print Network [OSTI]

, SCIAMACHY CO total column retrievals are of sufficient quality to provide useful new information]. Ground-based FTIR measurements provide high quality total column measurements but have very limitedQuantitative analysis of SCIAMACHY carbon monoxide total column measurements A. T. J. de Laat,1,2 A

Laat, Jos de

45

Catalyst for the methanation of carbon monoxide in sour gas  

DOE Patents [OSTI]

The invention involves the synergistic effect of the specific catalytic constituents on a specific series of carriers for the methanation of carbon monoxide in the presence of sulfur at relatively high temperatures and at low steam to gas ratios in the range of 0.2:1 or less. This effect was obtained with catalysts comprising the mixed sulfides and oxides of nickel and chromium supported on carriers comprising magnesium aluminate and magnesium silicate. Conversion of carbon monoxide to methane was in the range of from 40 to 80%. Tests of this combination of metal oxides and sulfides on other carriers and tests of other metal oxides and sulfides on the same carrier produced a much lower level of conversion.

Kustes, William A. (Louisville, KY); Hausberger, Arthur L. (Louisville, KY)

1985-01-01T23:59:59.000Z

46

Composite catalyst for carbon monoxide and hydrocarbon oxidation  

DOE Patents [OSTI]

A method and composition for the complete oxidation of carbon monoxide and/or hydrocarbon compounds. The method involves reacting the carbon monoxide and/or hydrocarbons with an oxidizing agent in the presence of a metal oxide composite catalyst. The catalyst is prepared by combining fluorite-type oxygen ion conductors with active transition metals. The fluorite oxide, selected from the group consisting of cerium oxide, zirconium oxide, thorium oxide, hafnium oxide, and uranium oxide, and may be doped by alkaline earth and rare earth oxides. The transition metals, selected from the group consisting of molybdnum, copper, cobalt, maganese, nickel, and silver, are used as additives. The atomic ratio of transition metal to fluorite oxide is less than one.

Liu, Wei (Cambridge, MA); Flytzani-Stephanopoulos, Maria (Winchester, MA)

1996-01-01T23:59:59.000Z

47

Composite catalyst for carbon monoxide and hydrocarbon oxidation  

DOE Patents [OSTI]

A method and composition are disclosed for the complete oxidation of carbon monoxide and/or hydrocarbon compounds. The method involves reacting the carbon monoxide and/or hydrocarbons with an oxidizing agent in the presence of a metal oxide composite catalyst. The catalyst is prepared by combining fluorite-type oxygen ion conductors with active transition metals. The fluorite oxide, selected from the group consisting of cerium oxide, zirconium oxide, thorium oxide, hafnium oxide, and uranium oxide, and may be doped by alkaline earth and rare earth oxides. The transition metals, selected from the group consisting of molybdenum, copper, cobalt, manganese, nickel, and silver, are used as additives. The atomic ratio of transition metal to fluorite oxide is less than one.

Liu, W.; Flytzani-Stephanopoulos, M.

1996-03-19T23:59:59.000Z

48

Carbon and carbon monoxide hydrogenation on nickel: support effects  

SciTech Connect (OSTI)

Hydrogenation of carbon, deposited on nickel catalysts by CO disproportionation, was investigated by temperature-programmed surface reaction (TPSR) for four oxide supports, alumina (Al/sub 2/O/sub 3/), silica (SiO/sub 2/), titanium oxide (TiO/sub 2/), and SiO/sub 2/.Al/sub 2/O/sub 3/. The rate of carbon monoxide hydrogenation was measured by temperature-programmed reaction (TPR) for comparison. The rate of carbon hydrogenation to methane was found to be independent of the support and an average activation energy of 42 kJ/mol was estimated. In contrast, the rate of carbon monoxide hydrogenation was very sensitive to the catalyst support. Nickel (Ni) supported on TiO/sub 2/ exhibited the highest specific activity, and two distinct sites for methanation were observed on Ni/TiO/sub 2/ and Ni/Al/sub 2/O/sub 3/. The lowest specific activities were observed for Ni/SiO/sub 2/ and Ni/SiO/sub 2/.Al/sub 2/O/sub 3/. For all catalysts, carbon hydrogenation occurred at a lower temperature than carbon monoxide hydrogenation. For both TPR and TPSR, small amounts of ethane were formed and at a lower temperature than methane. The amount of less-active, ..beta..-carbon observed in TPSR experiments was very small on all catalysts. These results indicate that at high coverages, carbon hydrogenation does not depend on the support, and thus it is not rate-determining for CO hydrogenation in excess hydrogen. The support is also shown to change the specific rate of carbon monoxide methanation; activity differences seen in steady-state experiments are not just due to differences in site densities. 5 figures, 5 tables.

Ozdogan, S.Z.; Gochis, P.D.; Falconer, J.L.

1983-10-01T23:59:59.000Z

49

E-Print Network 3.0 - air pollutants ozone Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

1 Global Ozone Project Ozone Formation in Summary: , power plants and industry all emit air pollution that forms ground-level ozone. Ozone is a primary... Stratospheric and...

50

Growth direction of oblique angle electron beam deposited silicon monoxide thin films identified by optical second-harmonic generation  

SciTech Connect (OSTI)

Oblique angle deposited (OAD) silicon monoxide (SiO) thin films forming tilted columnar structures have been characterized by second-harmonic generation. It was found that OAD SiO leads to a rotationally anisotropic second-harmonic response, depending on the optical angle of incidence. A model for the observed dependence of the second-harmonic signal on optical angle of incidence allows extraction of the growth direction of OAD films. The optically determined growth directions show convincing agreement with cross-sectional scanning electron microscopy images. In addition to a powerful characterization tool, these results demonstrate the possibilities for designing nonlinear optical devices through SiO OAD.

Vejling Andersen, Søren; Lund Trolle, Mads; Pedersen, Kjeld [Department of Physics and Nanotechnology, Aalborg University, Skjernvej 4A, DK-9220 Aalborg Øst (Denmark)] [Department of Physics and Nanotechnology, Aalborg University, Skjernvej 4A, DK-9220 Aalborg Øst (Denmark)

2013-12-02T23:59:59.000Z

51

TEXIN2: a model for predicting carbon monoxide concentrations near intersections  

E-Print Network [OSTI]

reduction caused by congestion 49 10 Application of impedance factors Carbon monoxide emissions for vehicular speed changes 59 12 Pasquill stability classes, A-G, as related to wind speed and incoming solar radiation 77 13 Regression lines... The prediction of carbon monoxide concentrations near roadway intersections represents a serious and challenging problem in air pollution research. In many geographical regions, the major portion of carbon monoxide in the environment is attributable...

Korpics, J. J

1985-01-01T23:59:59.000Z

52

Method and system for producing lower alcohols. [Heteropolyatomic lead salt coated with alkali metal formate  

DOE Patents [OSTI]

It is an object of the present invention to provide an improved catalyst for the reaction of carbon monoxide with water to produce methanol and other lower alcohols. It is a further object to provide a process for the production of methanol from carbon monoxide and water in which a relatively inexpensive catalyst permits the reaction at low pressures. It is also an object to provide a process for the production of methanol from carbon monoxide and water in which a relatively inexpensive catalyst permits the reaction at low pressures. It is also an object to provide a process for the production of methanol in which ethanol is also directly produced. It is another object to provide a process for the production of mixtures of methanol with ethanol and propanol from the reaction of carbon monoxide and water at moderate pressure with inexpensive catalysts. It is likewise an object to provide a system for the catalytic production of lower alcohols from the reaction of carbon monoxide and water at moderate pressure with inexpensive catalysts. In accordance with the present invention, a catalyst is provided for the reaction of carbon monoxide and water to produce lower alcohols. The catalyst includes a lead heteropolyatomic salt in mixture with a metal formate or a precursor to a metal formate.

Rathke, J.W.; Klingler, R.J.; Heiberger, J.J.

1983-09-26T23:59:59.000Z

53

INFRARED ABSORPTION SPECTROSCOPY OF CARBON MONOXIDE ON NICKEL FILMS: A LOW TEMPERATURE THERMAL DETECTION TECHNIQUE  

E-Print Network [OSTI]

A. B. Optical System Absorption Signal C. Small SignalNoise . Sensitivity of Absorption Spectroscopy EXPERIMENTSINFRARED ABSORPTION SPECTROSCOPY OF CARBON MONOXIDE ON

Bailey, Robert Brian

2011-01-01T23:59:59.000Z

54

E-Print Network 3.0 - atmospheric carbon monoxide Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

reservoirs (storages, especially the atmosphere, terrestrial biosphere, oceans... emissions trading and the control of greenhouse gas emissions. Carbon monoxide a chemical...

55

E-Print Network 3.0 - acute carbon monoxide Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

28, 2007 Summary: OSHAReproToxin AcutelyHazardousWaste Carbon monoxide CalOSHAReproToxin Carbon Tetrachloride IARC-2BNTP Carbonic... toxins, biotoxins and acutely toxic...

56

Carbon monoxide adsorption/desorption processes over NaX zeolite and supported ruthenium catalyst  

SciTech Connect (OSTI)

The binding states of CO on NaX zeolite and RuNaX were investigated by thermal desorption spectroscopy. Desorption peaks centered at around 390, 430, 490, and 520 K were observed from NaX following room-temperature adsorption of CO. The activation energy values corresponding to these peaks were calculated to be 41.4, 45.7, 53.8, and 57.7 kJ mol{sup {minus}1}, respectively. These peaks were also observed in desorption profiles from RuNaX although their temperatures were higher by 10 to 20 K. In addition, the desorption spectra from RuNaX also comprise two high-temperature peaks at around 575 and 640 K. With both the RuNaX and the NaX samples the temperature and relative intensities of the desorption peaks depended on pretreatment conditions and on the lapsed time between CO exposure to the sample and the commencement of programmed heating. Mass spectral analysis revealed that the gas desorbed at 300-500 K consisted mainly of CO while at higher temperatures CO{sub 2} was the main component. The desorption peaks below 500 K are attributed to the release of carbon monoxide from structural and intragranular or intergranular zeolitic pores. Lewis sites on the zeolite surface are found to facilitate activation of CO, resulting in its transformation to CO{sub 2}. The initial adsorption of carbon monoxide in zeolite pores and subsequent diffusion to metal sites leading to its disproportionation/oxidation is found to play an important role in the CO adsorption/desorption process on RuNaX.

Kamble, V.S.; Gupta, N.M.; Iyer, R.M. (Bhabha Atomic Research Centre, Bombay (India))

1988-10-01T23:59:59.000Z

57

Ozone decomposition in water solutions  

E-Print Network [OSTI]

. Hewes, III; B. S. , Texas ASH University Directed by Dr. R. R. Davison The rate of the decomposition of ozone in water solutions at various pH's and temperatures were ob- tained by an iodometrical method. The orders of the reactions and the reaction...

Hewes, Cecil Grayson

1969-01-01T23:59:59.000Z

58

6, 74277469, 2006 Linear ozone  

E-Print Network [OSTI]

from biases in the schemes' climatology coefficients. Cariolle v2.1 analyses showed biases of up to 20 and Kelder (1998) ozone climatology into the scheme. Chem2D-OPP v2.1 analyses showed biases up to 20 analysed temperatures and the temperature climatology supplied with the scheme. Future developments should

Boyer, Edmond

59

2, 15091543, 2002 Ozone production  

E-Print Network [OSTI]

.atmos-chem-phys.org/acpd/2/1509/ c European Geosciences Union 2002 Atmospheric Chemistry and Physics Discussions Ozone as a consequence of local catabatic winds. Aver- age mid-day peroxy radical concentrations at Mt. Cimone; Atlas and Ridley, 1996; Fischer et al., 1998; Zanis et al., 2000a, b). Often, free tropospheric

Boyer, Edmond

60

Transient PrOx carbon monoxide measurement, control, and optimization  

SciTech Connect (OSTI)

Fuel processing systems for low temperature polymer electrolyte membrane (PEM) fuel cell systems require control of the carbon monoxide concentration to less than 100 ppm to 10 ppm in the anode feed. Conventional hydrocarbon fuel processors use a water-gas shift (WGS) reactor to react CO with water to form H2 and reduce the CO concentration. The CO conversion is limited by equilibrium at the outlet temperature of the WGS reactor. The WGS outlet CO concentration can range from over 1% to 2000 ppm depending on the system and its operating parameters. At these concentrations, CO poisons low temperature PEM fuel cells and the concentrations needs to be reduced further.

Inbody, M. A. (Michael A.); Borup, R. L. (Rodney L.); Tafoya, J. (Jose I.)

2002-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "monoxide ozone lead" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Removal of carbon monoxide. Physical adsorption on natural and synthetic zeolites  

SciTech Connect (OSTI)

The utilization of natural zeolite materials in the elimination of polluting gases is investigated. Carbon monoxide pollution is emphasized because its concentration may reach dangerous levels in places such as vehicle tunnels, underground parking lots, etc. The elimination of carbon monoxide is also of interest in some industrial processes relating to the production of pure gases.

Alfani, F.; Greco, G. Jr.; Iroio, G.

1982-07-01T23:59:59.000Z

62

Submitted to the Annals of Applied Statistics INTERPOLATING FIELDS OF CARBON MONOXIDE  

E-Print Network [OSTI]

and transport. CO AMS 2000 subject classifications: Carbon monoxide; satellite data; Bayesian hierarchi- cal models; interpolation; data assimilation 1 imsart-aoas ver. 2007/04/13 file: COpaper.tex date: March 24Submitted to the Annals of Applied Statistics INTERPOLATING FIELDS OF CARBON MONOXIDE DATA USING

Nychka, Douglas

63

An experimental investigation of the ignition properties of hydrogen and carbon monoxide  

E-Print Network [OSTI]

for syngas turbine applications S.M. Walton *, X. He, B.T. Zigler, M.S. Wooldridge Department of Mechanical of simulated syngas mixtures of hydrogen (H2), carbon monoxide (CO), oxygen (O2), nitrogen (N2), and carbon. Keywords: Carbon monoxide; Hydrogen; Syngas; Ignition; Rapid compression facility 1. Introduction Syngas

Wooldridge, Margaret S.

64

Carbon monoxide-assisted growth of carbon nanotubes Y.H. Tang a,b  

E-Print Network [OSTI]

Carbon monoxide-assisted growth of carbon nanotubes Y.H. Tang a,b , Y.F. Zheng a , C.S. Lee a , N was used to synthesize carbon nanotubes (CNTs) in a hot-®lament chemical vapor deposition (HFCVD) system in the formation of multi-walled carbon nanotubes (MWNT)s. The CNTs synthesized from carbon monoxide validate

Zheng, Yufeng

65

Method of removing nitrogen monoxide from a nitrogen monoxide-containing gas using a water-soluble iron ion-dithiocarbamate, xanthate or thioxanthate  

DOE Patents [OSTI]

The present invention relates to a method of removing of nitrogen monoxide from a nitrogen monoxide-containing gas which method comprises contacting a nitrogen oxide-containing gas with an aqueous solution of water soluble organic compound-iron ion chelate complex. The NO absorption efficiency of ferrous urea-dithiocarbamate and ferrous diethanolamine-xanthate as a function of time, oxygen content and solution ph is presented. 3 figs., 1 tab.

Liu, D. Kwok-Keung; Chang, Shih-Ger

1987-08-25T23:59:59.000Z

66

Meteorological Simulations of Ozone Episode Case Days during the 1996 Paso del Norte Ozone Study  

SciTech Connect (OSTI)

Meteorological simulations centered around the border cities of El Paso and Ciudad Juarez have been performed during an ozone episode that occurred on Aug. 13,1996 during the 1996 Paso del Norte Ozone Study field campaign. Simulations were petiormed using the HOTMAC mesoscale meteorological model using a 1,2,4, and 8 km horizontal grid size nested mesh system. Investigation of the vertical structure and evolution of the atmospheric boundary layer for the Aug. 11-13 time period is emphasized in this paper. Comparison of model-produced wind speed profiles to rawirisonde and radar profiler measurements shows reasonable agreement. A persistent upper-level jet was captured in the model simulations through data assimilation. In the evening hours, the model was not able to produce the strong wind direction shear seen in the radar wind profiles. Based on virtual potential temperature profile comparisons, the model appears to correctly simulate the daytime growth of the convective mixed layer. However, the model underestimates the cooling of the surface layer at night. We found that the upper-level jet significantly impacted the turbulence structure of the boundary layer, leading to relatively high turbulent kinetic energy (tke) values aloft at night. The model indicates that these high tke values aloft enhance the mid-morning growth of the boundary layer. No upper-level turbulence measurements were available to verify this finding, however. Radar profiler-derived mixing heights do indicate relatively rapid morning growth of the mixed layer.

Brown, M.J.; Costigan, K.; Muller, C.; Wang, G.

1999-02-01T23:59:59.000Z

67

Ozone production in transpacific Asian pollution plumes and implications for ozone air quality in California  

E-Print Network [OSTI]

Ozone production in transpacific Asian pollution plumes and implications for ozone air quality in transpacific Asian pollution plumes, and the implications for ozone air quality in California, by using pollution plumes. Strong dilution of Asian pollution plumes takes place during entrainment in the U

Park, Rokjin

68

Discharge cell for ozone generator  

DOE Patents [OSTI]

A discharge cell for use in an ozone generator is provided which can suppress a time-related reduction in ozone concentration without adding a catalytic gas such as nitrogen gas to oxygen gas as a raw material gas. The discharge cell includes a pair of electrodes disposed in an opposed spaced relation with a discharge space therebetween, and a dielectric layer of a three-layer structure consisting of three ceramic dielectric layers successively stacked on at least one of the electrodes, wherein a first dielectric layer of the dielectric layer contacting the one electrode contains no titanium dioxide, wherein a second dielectric layer of the dielectric layer exposed to the discharge space contains titanium dioxide in a metal element ratio of not lower than 10 wt %.

Nakatsuka, Suguru (Amagasaki, JP)

2000-01-01T23:59:59.000Z

69

Y-12 Plant Stratospheric Ozone Protection plan  

SciTech Connect (OSTI)

The Y-12 Plant staff is required by Lockheed Martin Energy Systems (Energy Systems) (formerly Martin Marietta Energy Systems) standard ESS-EP-129 to develop and implement a Stratospheric Ozone Protection Program which will minimize emissions of ozone-depleting substances to the environment and maximize the use of ozone-safe alternatives in order to comply with Title VI of the 1990 Clean Air Act (CAA) Amendments and the implementing regulations promulgated by the Environmental Protection Agency (EPA). This plan describes the requirements, initiatives, and accomplishments of the Y-12 Plant Stratospheric Ozone Protection Program.

NONE

1995-09-01T23:59:59.000Z

70

Tropospheric Ozone Pollution and Personal Exposure  

E-Print Network [OSTI]

://www.nctcog.org/trans/air/ozone/formation.gif #12;Health Effects · Chest pain, coughing, throat irritation, and congestion · Wheezing and difficulty

Toohey, Darin W.

71

DOE's Studies of Weekday/Weekend Ozone Pollution in Southern...  

Energy Savers [EERE]

DOE's Studies of WeekdayWeekend Ozone Pollution in Southern California DOE's Studies of WeekdayWeekend Ozone Pollution in Southern California 2002 DEER Conference Presentation:...

72

Weekday and Weekend Air Pollutant Levels in Ozone Problem Areas...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Ambient Ozone Formation as a Function of NOx Reductions Summary and Implications for Air Quality Impacts DOE's Studies of WeekdayWeekend Ozone Pollution in Southern...

73

The Weekend Ozone Effect - The Weekly Ambient Emissions Control...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

More Documents & Publications WeekendWeekday Ozone Study in the South Coast Air Basin DOE's Studies of WeekdayWeekend Ozone Pollution in Southern California...

74

Indoor Air Quality Poor indoor air quality comes from many sources. It can lead to having  

E-Print Network [OSTI]

Indoor Air Quality Fact Sheet Poor indoor air quality comes from many sources. It can lead Indoor Air Pollutants · Molds · Pollen · Dander from pet fur · Secondhand smoke · Formaldehyde · Carbon monoxide that comes from burning propane, other gases and fuels, and charcoal · Household products

75

Interaction of carbon monoxide with supported platinum catalysts  

SciTech Connect (OSTI)

The interaction of carbon monoxide with Pt/..gamma..-Al/sub 2/O/sub 3/ containing 0.5-5% Pt by weight has been investigated by means of thermal desorption and IR spectroscopy. It has been shown that CO is adsorbed in three different forms, corresponding to the desorption temperature intervals 25-250/sup 0/C (I), and 250-700/sup 0/C (II), and 550-850/sup 0/C (III). In the adsorption of CO in the first two forms, the metal takes part (absorption band at 2080 cm/sup -1/), and also the support (1800, 1260, 1390, 1470, 1550, and 1640 cm/sup -1/). The adsorption in form III probably takes place on oxidized platinum centers with the formation of strong surface carbonate structures. High temperatures tend to increase the adsorption of CO in forms II and III.

Savel'eva, G.A.; Galeev, T.K.; Popova, N.M.; Vozdvizhenskii, V.F.; Mishchenko, V.M.

1982-04-01T23:59:59.000Z

76

Methanation of gas streams containing carbon monoxide and hydrogen  

DOE Patents [OSTI]

Carbon monoxide-containing gas streams having a relatively high concentration of hydrogen are pretreated so as to remove the hydrogen in a recoverable form for use in the second step of a cyclic, essentially two-step process for the production of methane. The thus-treated streams are then passed over a catalyst to deposit a surface layer of active surface carbon thereon essentially without the formation of inactive coke. This active carbon is reacted with said hydrogen removed from the feed gas stream to form methane. The utilization of the CO in the feed gas stream is appreciably increased, enhancing the overall process for the production of relatively pure, low-cost methane from CO-containing waste gas streams.

Frost, Albert C. (Congers, NY)

1983-01-01T23:59:59.000Z

77

Some observations on the kinetics of the hydrogenation of carbon monoxide  

SciTech Connect (OSTI)

For the hydrogenation of CO a positive order of hydrogen and a slightly negative or a zero order in carbon monoxide are generally reported. The negative (or zero) order in carbon monoxide is often explained by assuming a strong adsorption of carbon monoxide on the same sites as used by the hydrogen. It is then assumed that the surface is ''almost totally'' covered by carbon monoxide. From experiments in which the surface products on an unsupported cobalt catalyst after the reaction were stripped off by a hydrogen treatment it was concluded that more than 95% of the surface (as determined from the adsorption of carbon monoxide at room temperature) was covered by carbon-containing species. This paper illustrates that ''zero order in carbon monoxide'' can be obtained with much lower coverage of carbon-containing species in equilibrium with gas-phase carbon monoxide than indicated above. Equations for reaction rates are presented, and data is calculated on the fraction of the catalyst surface covered by active carbon-containing species when the reaction is zero order in CO. The results suggest that only a small fraction of the catalyst surface is actively engaged in the hydrogenation of CO. This further suggests that the low turnover frequencies found for the Fischer-Tropsch synthesis could be caused by a small number of sites which are active in the rate-determining step. (MWF)

Rautavuoma, A.O.I.; van der Baan, H.S.

1981-10-01T23:59:59.000Z

78

An Assessment of Tropospheric Ozone Pollution  

E-Print Network [OSTI]

An Assessment of Tropospheric Ozone Pollution --A North American Perspective-- Surface Urban, California 94304 #12;AN ASSESSMENT OF TROPOSPHERIC OZONE POLLUTION: A NORTH AMERICAN PERSPECTIVE The NARSTO, Instituto Mexicano del Petroleo, Mexico, D.F., Mexico Alan Dunker, General Motors Research & Development

79

Relative and kinetic properties of carbon monoxide and carbon dioxide on a graphite surface  

SciTech Connect (OSTI)

Temperature-programmed desorption (TPD) results after chemisorption of carbon monoxide (CO) and carbon dioxide (CO/sub 2/) on polycrystalline graphite are presented. CO adsorbs onto graphite with a very low sticking coefficient. After CO chemisorption CO (mass 28 amu) desorbs in two temperature regions, between 400 and 700 K and between 1000 and 1300 K, and CO/sub 2/ (mass 44 amu) desorbs below 950 K. The intensity of the CO/sub 2/ signal is less than 1 order of magnitude lower than the CO intensity. After CO/sub 2/ adsorption the major desorption product is CO at high temperatures (1000 < T (K) < 1300), whereas a small amount of CO/sub 2/ desorbs around 450 K. The adsorption of C/sup 16/O/sub 2/ and C/sup 18/O/sub 2/ mixture leads to a nearly total oxygen scrambling of the CO/sub 2/ desorbed. A mechanism for CO and CO/sub 2/ interconversion on the graphite surface is presented in terms of surface oxide species, mainly lactones and semiquinones, and their relative stability. Assignments of the TPD features are proposed accordingly. Reaction studies on the CO/sub 2/ gasification of clean graphite and the CO disproportionation (Boudouard reaction) have been performed. A good agreement is found between the activation energies obtained and the desorption energies calculated from the analysis of the TPD results.

Marchon, B.; Tysoe, W.T.; Carrazza, J.; Heinemann, H.; Somorjai, G.A.

1988-10-06T23:59:59.000Z

80

Method of removing nitrogen monoxide from a nitrogen monoxide-containing gas using a water-soluble iron ion-dithiocarbamate, xanthate or thioxanthate  

DOE Patents [OSTI]

A method of removing nitrogen monoxide from a nitrogen monoxide-containing gas, which method comprises: (a) contacting a nitrogen oxide-containing gas with an aqueous solution of water soluble organic compound-iron ion chelate of the formula: ##STR1## wherein the water-soluble organic compound is selected from compounds of the formula: ##STR2## wherein: R is selected from hydrogen or an organic moiety having at least one polar functional group; Z is selected from oxygen, sulfur, or --N--A wherein N is nitrogen and A is hydrogen or lower alkyl having from one to four carbon atoms; and M is selected from hydrogen, sodium or potassium; and n is 1 or 2, in a contacting zone for a time and at a temperature effective to reduce the nitrogen monoxide. These mixtures are useful to provide an unexpensive method of removing NO from gases, thus reducing atmospheric pollution from flue gases.

Liu, David K. (San Pablo, CA); Chang, Shih-Ger (El Cerrito, CA)

1989-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "monoxide ozone lead" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Production of carbon monoxide-free hydrogen and helium from a high-purity source  

DOE Patents [OSTI]

The invention provides vacuum swing adsorption processes that produce an essentially carbon monoxide-free hydrogen or helium gas stream from, respectively, a high-purity (e.g., pipeline grade) hydrogen or helium gas stream using one or two adsorber beds. By using physical adsorbents with high heats of nitrogen adsorption, intermediate heats of carbon monoxide adsorption, and low heats of hydrogen and helium adsorption, and by using vacuum purging and high feed stream pressures (e.g., pressures of as high as around 1,000 bar), pipeline grade hydrogen or helium can purified to produce essentially carbon monoxide -free hydrogen and helium, or carbon monoxide, nitrogen, and methane-free hydrogen and helium.

Golden, Timothy Christopher (Allentown, PA); Farris, Thomas Stephen (Bethlehem, PA)

2008-11-18T23:59:59.000Z

82

A Micro-Computer-Based Fuel Optimization System Utilizing In-Situ Measurement of Carbon Monoxide  

E-Print Network [OSTI]

gas analyzer that mounts directly in the flue or stack to continuously measure carbon monoxide, unburned hydrocarbons, opacity and temperature. The control console interfaces directly with the boiler's existing analog control system to provide precise...

DeVivo, D. G.

1980-01-01T23:59:59.000Z

83

Laboratory measurement of secondary pollutant yields from ozone reaction with HVAC filters.  

E-Print Network [OSTI]

from Ozone Reaction with HVAC Filters Hugo Destaillats,from Ozone Reaction with HVAC Filters Hugo Destaillatsfrom Ozone Reaction with HVAC Filters Hugo Destaillats

Destaillats, Hugo

2012-01-01T23:59:59.000Z

84

E-Print Network 3.0 - aura-omi tropospheric ozone Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

atmospheric ozone. The Ozone Monitoring Instrument (OMI) onboard the satellite provides global total column ozone (TCO) and in combination Summary: with other instruments...

85

Influence of the electrode material on carbon monoxide adsorption and electroreduction in aqueous solutions  

SciTech Connect (OSTI)

Carbon monoxide electroreduction was studied at rotating disk electrodes made of different materials (Cu, Au, Zn, Cd; amalgamated Cu; Al, Ga, In, glassy carbon, Sn, Pb, Mo, Fe, Ni, and certain binary systems). Positive partial currents which are evidence for a direct electroreduction of CO have been observed only at Zn, Ga, and Cd. The observation that CO is less susceptible to electroreduction than carbon dioxide is explained by the stronger chemisorption of carbon monoxide on the electrodes.

Osetrova, N.V.; Vasil'ev, Yu.B.

1987-12-01T23:59:59.000Z

86

17 October 2014 Antarctic Ozone Bulletin  

E-Print Network [OSTI]

as measured with an electrochemical ozonesonde on 10 October. One can see two large "bite-outs" of ozone). Ushuaia is marked with a green dot. One can see that Ushuaia is well inside the polar vortex. The PV data

Toohey, Darin W.

87

Ozone treatment of biomass to enhance digestibility  

E-Print Network [OSTI]

is very resistant to enzymatic degradation. Lignocellulosic materials require pretreatment to enhance their digestibility. The main objective of this research was to further enhance the digestibility of biomass (bagasse) with ozonation as a follow...

Almendarez, Maria Elena

2000-01-01T23:59:59.000Z

88

Pinatubo fails to deepen the ozone hole  

SciTech Connect (OSTI)

When the Philippine volcano Pinatubo exploded last year, pumping the upper atmosphere full of find debris, researchers foresaw yet another assault on the stratosphere's beleaguered ozone layer. Some calculations of the effects of volcanic debris implied that as much as 25% to 30% of the ozone shield over temperature latitudes might be eaten away by the volcanic haze - five times the observed loss over the past decade. Early measurements didn't bear out that concern, but researchers weren't prepared to call off the alarm until the verdict came in from the most vulnerable part of the planet's ozone layer, the frigid stratosphere over Antarctica. Although the hole was more extensive than ever before, probably because of unusual weather patterns, total ozone bottomed out well above the record set last year - even a tad above the low levels seen in 1987, 1989, and 1990.

Kerr, R.A.

1992-10-15T23:59:59.000Z

89

Methane production from ozonated pulp mill effluent  

SciTech Connect (OSTI)

A study was made of the production of methane from desugared spent sulfite liquor (SSL) reacted with ozone. The ozonated SSL was fed continuously to three anaerobic fermenters for three months as the sole source of carbon and energy. The fermenters were inoculated with anaerobic bacteria obtained from sewage sludge and acclimated for 1 month in ozonated SSL prior to continuous fermentation. Chemical and biological parameters such as COD, BOD, total sulfur content, redox potential, pH, fatty acid composition, and methane bacteria populations were monitored to determine changes in the SSL during fermentation. Methane production from ozone-treated SSL averaged 1.7 liters/ liter or 17 ml of CH/sub 4/ produced/gram of volatile solids fed. Fatty acis analysis of fermenter effluent indicated a net production of 58 mM/ liter of acetate during ozonated SSL fermentation. This acetic acid production shows future potential for further fermentation by protein-producing yeast. Although the rate of conversion of volatile solids to CH/sub 4/ in this process was not competitive with domestic or agricultural waste digesters, this study did indicate the potential benefits of ozonating organic wastes for increased methane fermentation yields.

Bremmon, C.E.; Jurgensen, M.F.; Patton, J.T.

1980-07-01T23:59:59.000Z

90

Titanium monoxide spectroscopy following laser-induced optical breakdown  

SciTech Connect (OSTI)

This work investigates Titanium Monoxide (TiO) in ablation-plasma by employing laser-induced breakdown spectroscopy (LIBS) with 1 to 10 TW/cm{sup 2} irradiance, pulsed, 13 nanosecond, Q-switched Nd:YAG laser radiation at the fundamental wavelength of 1064 nm. The analysis of TiO is based on our first accurate determination of transition line strengths for selected TiO A-X, B-X, and E-X transitions, particularly TiO A-X {gamma} and B-X {gamma} Prime bands. Electric dipole line strengths for the A{sup 3}{Phi}-X{sup 3}{delta} and B{sup 3}{Pi}-X{sup 3}{delta} bands of TiO are computed. The molecular TiO spectra are observed subsequent to laser-induced breakdown (LIB). We discuss analysis of diatomic molecular spectra that may occur simultaneously with spectra originating from atomic species. Gated detection is applied to investigate the development in time of the emission spectra following LIB. Collected emission spectra allow one to infer micro-plasma parameters such as temperature and electron density. Insight into the state of the micro-plasma is gained by comparing measurements with predictions of atomic and molecular spectra. Nonlinear fitting of recorded and computed diatomic spectra provides the basis for molecular diagnostics, while atomic species may overlap and are simultaneously identified. Molecular diagnostic approaches similar to TiO have been performed for diatomic molecules such as AlO, C{sub 2}, CN, CH, N{sub 2}, NH, NO and OH.

Parigger, Christian G.; Woods, Alexander C.; Keszler, Anna; Nemes, Laszlo; Hornkohl, James O. [The University of Tennessee/UT Space Institute, Center for Laser Applications, 411 B.H. Goethert Parkway, Tullahoma, TN 37388-9700 (United States); Chemical Research Center of the Hungarian Academy of Sciences, Institute of Materials and Environmental Chemistry, Pusztaszeri ut 59-67, H-1025 Budapest (Hungary); Chemical Research Center of the Hungarian Academy of Sciences, Laser Spectroscopy Laboratory, Pusztaszeri ut 59-67, H-1025 Budapest (Hungary); Hornkohl Consulting, Tullahoma, TN 37388 (United States)

2012-07-30T23:59:59.000Z

91

Coadsorption of hydrogen and ethylene, and carbon monoxide and ethylene on the Ru(001) surface  

SciTech Connect (OSTI)

A detailed investigation of the coadsorption of ethylene with both preadsorbed hydrogen and preadsorbed carbon monoxide on the Ru(001) surface is reported here. Both preadsorbed hydrogen and carbon monoxide reduce the saturation coverage of subsequently chemisorbed ethylene. The coadsorption of hydrogen with ethylene results in detectable hydrogenation of ethylene to ethane below 250 K, whereas no self-hydrogenation of ethylene to ethane is observed. High-resolution electron energy loss spectra show that ethylene coadsorbed with either hydrogen or carbon monoxide decomposes to ethylidyne (CCH/sub 3/) and acetylide (CCH), as it does on the clean surface. Carbon monoxide preadsorption enhances the stability of the ethylidyne such that it decomposes at approximately 420 K, rather than 355 K as on the initially clean Ru(001) surface. Preadsorbed carbon monoxide also reduces the ratio of ethylidyne to acetylide that is formed from ethylene, compared to the ratio observed from an equivalent coverage of ethylene on the clean surface; hydrogen preadsorption, on the other hand, increases this ratio.

Hills, M.M.; Parmeter, J.E.; Weinberg, W.H.

1986-11-12T23:59:59.000Z

92

A population-based exposure assessment methodology for carbon monoxide: Development of a carbon monoxide passive sampler and occupational dosimeter  

SciTech Connect (OSTI)

Two devices, an occupational carbon monoxide (CO) dosimeter (LOCD), and an indoor air quality (IAQ) passive sampler were developed for use in population-based CO exposure assessment studies. CO exposure is a serious public health problem in the U.S., causing both morbidity and mortality (lifetime mortality risk approximately 10{sup -4}). Sparse data from population-based CO exposure assessments indicate that approximately 10% of the U.S. population is exposed to CO above the national ambient air quality standard. No CO exposure measurement technology is presently available for affordable population-based CO exposure assessment studies. The LOCD and IAQ Passive Sampler were tested in the laboratory and field. The palladium-molybdenum based CO sensor was designed into a compact diffusion tube sampler that can be worn. Time-weighted-average (TWA) CO exposure of the device is quantified by a simple spectrophotometric measurement. The LOCD and IAQ Passive Sampler were tested over an exposure range of 40 to 700 ppm-hours and 200 to 4200 ppm-hours, respectively. Both devices were capable of measuring precisely (relative standard deviation <20%), with low bias (<10%). The LOCD was screened for interferences by temperature, humidity, and organic and inorganic gases. Temperature effects were small in the range of 10{degrees}C to 30{degrees}C. Humidity effects were low between 20% and 90% RH. Ethylene (200 ppm) caused a positive interference and nitric oxide (50 ppm) caused a negative response without the presence of CO but not with CO.

Apte, M.G.

1997-09-01T23:59:59.000Z

93

The development and deployment of a ground-based, laser-induced fluorescence instrument for the in situ detection of iodine monoxide radicals  

SciTech Connect (OSTI)

High abundances of iodine monoxide (IO) are known to exist and to participate in local photochemistry of the marine boundary layer. Of particular interest are the roles IO plays in the formation of new particles in coastal marine environments and in depletion episodes of ozone and mercury in the Arctic polar spring. This paper describes a ground-based instrument that measures IO at mixing ratios less than one part in 10{sup 12}. The IO radical is measured by detecting laser-induced fluorescence at wavelengths longer that 500 nm. Tunable visible light is used to pump the A{sup 2}?{sub 3/2} (v{sup ?} = 2) ? X{sup 2}?{sub 3/2} (v{sup ?} = 0) transition of IO near 445 nm. The laser light is produced by a solid-state, Nd:YAG-pumped Ti:Sapphire laser at 5 kHz repetition rate. The laser-induced fluorescence instrument performs reliably with very high signal-to-noise ratios (>10) achieved in short integration times (<1 min). The observations from a validation deployment to the Shoals Marine Lab on Appledore Island, ME are presented and are broadly consistent with in situ observations from European Coastal Sites. Mixing ratios ranged from the instrumental detection limit (<1 pptv) to 10 pptv. These data represent the first in situ point measurements of IO in North America.

Thurlow, M. E., E-mail: thurlow@huarp.harvard.edu; Hannun, R. A.; Lapson, L. B.; Anderson, J. G. [Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, Massachusetts 02138 (United States)] [Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, Massachusetts 02138 (United States); Co, D. T. [Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, Massachusetts 02138 (United States) [Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, Massachusetts 02138 (United States); Argonne-Northwestern Solar Energy Research Center and Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208-3113 (United States); O'Brien, A. S. [Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, Massachusetts 02138 (United States) [Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, Massachusetts 02138 (United States); Department of Civil and Environmental Engineering, Princeton University, Princeton, New Jersey 08544 (United States); Hanisco, T. F. [Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, Massachusetts 02138 (United States) [Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, Massachusetts 02138 (United States); NASA Goddard Space Flight Center, Code 614, Greenbelt, Maryland 20771 (United States)

2014-04-15T23:59:59.000Z

94

Southern Hemisphere Additional Ozonesondes (SHADOZ) 19982000 tropical ozone climatology  

E-Print Network [OSTI]

ozone record from Paramaribo, Surinam (6°N, 55°W) (also in SHADOZ) shows a marked contrast to southern tropical ozone because Surinam is often north of the Intertropical Convergence Zone (ITCZ). A more

Thompson, Anne

95

Concentration of ozone in surface air over greater Boston  

E-Print Network [OSTI]

Surface ozone concentrations were measured in the Greater Boston area from November, 1964 to December, 1965. Ozone was monitored continuosly using a Mast microcoulombmetric sensor. A chromium trioxide filter was fitted to ...

Widen, Donald Allen

1966-01-01T23:59:59.000Z

96

Reformer-pressure swing adsorption process for the production of carbon monoxide  

SciTech Connect (OSTI)

An improved process for the production of carbon monoxide by the steam reforming of hydrocarbons is described comprising: (a) catalytically reacting a fluid hydrocarbon feed stream with steam in a steam reformer; (b) passing the reformer effluent containing hydrogen, carbon monoxide and carbon dioxide from the steam reformer, without scrubbing to remove the carbon dioxide content thereof, to a pressure swing adsorption system having at least four adsorbent beds, each bed of which, on a cyclic basis, undergoes a processing sequence; (c) recycling the carbon dioxide-rich stream to the steam reformer for reaction with additional quantities of the hydrocarbon feed stream being passed to the stream reformer to form additional quantities of carbon monoxide and hydrogen, with product recovery being enhanced and the need for employing a carbon dioxide wash system being obviated.

Fuderer, A.

1988-02-23T23:59:59.000Z

97

Ozone-depleting-substance control and phase-out plan  

SciTech Connect (OSTI)

Title VI of the Federal Clean Air Act Amendments of 1990 requires regulation of the use and disposal of ozone-depleting substances (ODSs) (e.g., Halon, Freon). Several important federal regulations have been promulgated that affect the use of such substances at the Hanford Site. On April 23, 1993, Executive Order (EO) 12843, Procurement Requirements and Policies for Federal Agencies for Ozone-Depleting Substances (EPA 1993) was issued for Federal facilities to conform to the new US Environmental Protection Agency (EPA) regulations implementing the Clean Air Act of 1963 (CAA), Section 613, as amended. To implement the requirements of Title VI the US Department of Energy, Richland Operations Office (RL), issued a directive to the Hanford Site contractors on May 25, 1994 (Wisness 1994). The directive assigns Westinghouse Hanford Company (WHC) the lead in coordinating the development of a sitewide comprehensive implementation plan to be drafted by July 29, 1994 and completed by September 30, 1994. The implementation plan will address several areas where immediate compliance action is required. It will identify all current uses of ODSs and inventories, document the remaining useful life of equipment that contains ODS chemicals, provide a phase-out schedule, and provide a strategy that will be implemented consistently by all the Hanford Site contractors. This plan also addresses the critical and required elements of Federal regulations, the EO, and US Department of Energy (DOE) guidance. This plan is intended to establish a sitewide management system to address the clean air requirements.

Nickels, J.M.; Brown, M.J.

1994-07-01T23:59:59.000Z

98

The impact of interannual variability on multidecadal total ozone simulations  

E-Print Network [OSTI]

to reinforce the chemical ozone depletion caused by the enhanced aerosol loading following the eruption of Mt

Jackman, Charles H.

99

Ozone treatment in a closed culture system for Macrobrachium rosenbergii  

E-Print Network [OSTI]

constant flow of air. The Orthotoridine-Manganese Method (OTM) wss employed to measure ozone in solution (APHA, 1976) . Because of the rapid rate of decomposition of ozone in water, it was determined that the production of ozone could not be measured... by introducing into water and then sampling that water for analysis with OTM. Therefore, ozone was introduced directly into a solution of OTM reagent with subsequent changes in color of the reagent, measured on a "B & L Spectronic 70" spectrophotometer, being...

Yamaguchi, Ryoji

1978-01-01T23:59:59.000Z

100

Secondary Pollutants from Ozone Reaction with Ventilation Filters and Degradation of Filter Media Additives  

SciTech Connect (OSTI)

Prior research suggests that chemical processes taking place on the surface of particle filters employed in buildings may lead to the formation of harmful secondary byproducts. We investigated ozone reactions with fiberglass, polyester, cotton/polyester and polyolefin filter media, as well as hydrolysis of filter media additives. Studies were carried out on unused media, and on filters that were installed for 3 months in buildings at two different locations in the San Francisco Bay Area. Specimens from each filter media were exposed to {approx}150 ppbv ozone in a flow tube under a constant flow of dry or humidified air (50percent RH). Ozone breakthrough was recorded for each sample over periods of {approx}1000 min; the ozone uptake rate was calculated for an initial transient period and for steady-state conditions. While ozone uptake was observed in all cases, we did not observe significant differences in the uptake rate and capacity for the various types of filter media tested. Most experiments were performed at an airflow rate of 1.3 L/min (face velocity = 0.013 m/s), and a few tests were also run at higher rates (8 to 10 L/min). Formaldehyde and acetaldehyde, two oxidation byproducts, were quantified downstream of each sample. Those aldehydes (m/z 31 and 45) and other volatile byproducts (m/z 57, 59, 61 and 101) were also detected in real-time using Proton-Transfer Reaction - Mass Spectrometry (PTR-MS). Low-ppbv byproduct emissions were consistently higher under humidified air than under dry conditions, and were higher when the filters were loaded with particles, as compared with unused filters. No significant differences were observed when ozone reacted over various types of filter media. Fiberglass filters heavily coated with impaction oil (tackifier) showed higher formaldehyde emissions than other samples. Those emissions were particularly high in the case of used filters, and were observed even in the absence of ozone, suggesting that hydrolysis of additives, rather than ozonolysis, is the main formaldehyde source in those filters. Emission rates of formaldehyde and acetaldehyde were not found to be large enough to substantially increase indoor concentrations in typical building scenarios. Nevertheless, ozone reactions on HVAC filters cannot be ignored as a source of low levels of indoor irritants.

Destaillats, Hugo; Chen, Wenhao; Apte, Michael; Li, Nuan; Spears, Michael; Almosni, Jérémie; Brunner, Gregory; Zhang, Jianshun (Jensen); Fisk, William J.

2011-05-01T23:59:59.000Z

Note: This page contains sample records for the topic "monoxide ozone lead" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Crystallographic Snapshots of Cyanide- and Water-Bound C-Clusters from Bifunctional Carbon Monoxide Dehydrogenase/Acetyl-CoA Synthase  

E-Print Network [OSTI]

Nickel-containing carbon monoxide dehydrogenases (CODHs) reversibly catalyze the oxidation of carbon monoxide to carbon dioxide and are of vital importance in the global carbon cycle. The unusual catalytic CODH C-cluster ...

Kung, Yan

102

Cyclic process for producing methane from carbon monoxide with heat removal  

DOE Patents [OSTI]

Carbon monoxide-containing gas streams are converted to methane by a cyclic, essentially two-step process in which said carbon monoxide is disproportionated to form carbon dioxide and active surface carbon deposited on the surface of a catalyst, and said carbon is reacted with steam to form product methane and by-product carbon dioxide. The exothermic heat of reaction generated in each step is effectively removed during each complete cycle so as to avoid a build up of heat from cycle-to-cycle, with particularly advantageous techniques being employed for fixed bed, tubular and fluidized bed reactor operations.

Frost, Albert C. (Congers, NY); Yang, Chang-lee (Spring Valley, NY)

1982-01-01T23:59:59.000Z

103

Ozone determination in different copying centers  

E-Print Network [OSTI]

&ixicolr&gi 1st ed. , New York. Hemisphere Publishing Corp, 1 987, ppl35-13(? 12. Menzel, D. B. : Toxicity of Ozone, Oxygen and Radiation. AI111 Rev. of Pharmacol. 1970; 10: 37&)-394. 13. Menzel, D. B. : Ozone: An overview of its toxicity in m;in . in...-Threshold Limit Values for Chemi?;il Substances and Physical Agents in the Work Environm?ni 1991-1992. Cincinnati, Ohio: ACGIH 1991 24. Wadden, R. A. , and P. A. Scheff: /ndoor At't Pollt&ttr ii l si ?d New York: John Wiley & Sons, inc. , 1983, ppl-5. 25...

Lai, Chen-Fu

1993-01-01T23:59:59.000Z

104

Primary lead smelter, Doe Run, Herculaneum, Missouri (kit)  

SciTech Connect (OSTI)

The United States Environmental Protection Agency`s (EPA) Emission Standards Division (ESD) is investigating the primary lead smelting source category to identify and quantify organic hazardous air pollutants (HAPs) emitted from blast furnaces. The primary objective was to obtain data on the emissions of volatile and semi-volatile organic HAPs, aldehydes, and ketones from primary lead smelter blast furnaces. A secondary objective was to obtain data on the emissions of carbon monoxide. The data will be used by ESD to determine whether organic HAPs are emitted at levels that would justify regulation under the Maximum Achievable Control Technology (MACT) program. The Doe Run Company, which operates a primary lead smelter in Herculaneum, Missouri was selected by the ESD as the host facility for this project.

NONE

1999-08-01T23:59:59.000Z

105

Carbon monoxide annealed TiO2 nanotube array electrodes for efficient biosensor applications  

E-Print Network [OSTI]

Carbon monoxide annealed TiO2 nanotube array electrodes for efficient biosensor applications by anodic oxidation of titanium foil followed with O2 and CO annealing were employed as matrices consisted of Ti3+ defects with carbon-doping and exhibited well defined quasi-reversible cyclic voltammetric

Cao, Guozhong

106

Crystallization and mutational studies of carbon monoxide dehydrogenase from moorella thermoacetica  

E-Print Network [OSTI]

Carbon Monoxide Dehydrogenase (CODH), also known as Acetyl-CoA synthase (ACS), is one of seven known Ni containing enzymes. CODH/ACS is a bifunctional enzyme which oxidizes CO to CO2 reversibly and synthesizes acetyl-CoA. Recently, X-ray crystal...

Kim, Eun Jin

2004-09-30T23:59:59.000Z

107

Effect of redox potential, sulfide ions and a persulfide forming cysteine residue on carbon monoxide dehydrogenase  

E-Print Network [OSTI]

The Ni-Fe-S C-cluster of carbon monoxide dehydrogenases (CODH), which catalyzes the reversible oxidation of CO to CO2, can be stabilized in four redox states: Cox, Cred1, Cint, and Cred2. The best-supported mechanism of catalysis involves a one...

Feng, Jian

2005-08-29T23:59:59.000Z

108

Study of hydrogen and carbon monoxide adsorption on modified Zn/Cr catalysts by adsorption calorimetry  

SciTech Connect (OSTI)

Differential heat of adsorption (q) of hydrogen (a) and carbon monoxide (b) as a function of the adsorbed amount (a) on Zn/Cr catalysts at 463/sup 0/K; 1) unpromoted catalyst, 2) catalyst promoted with 2.5% of K/sub 2/O.

Yoshin, S.V.; Klyacho, A.L.; Kondrat'ev, L.T.; Leonov, V.E.; Skripchenko, G.B.; Sushchaya, L.E.

1986-08-01T23:59:59.000Z

109

Process for producing methane from gas streams containing carbon monoxide and hydrogen  

DOE Patents [OSTI]

Carbon monoxide-containing gas streams are passed over a catalyst capable of catalyzing the disproportionation of carbon monoxide so as to deposit a surface layer of active surface carbon on the catalyst essentially without formation of inactive coke thereon. The surface layer is contacted with steam and is thus converted to methane and CO.sub.2, from which a relatively pure methane product may be obtained. While carbon monoxide-containing gas streams having hydrogen or water present therein can be used only the carbon monoxide available after reaction with said hydrogen or water is decomposed to form said active surface carbon. Although hydrogen or water will be converted, partially or completely, to methane that can be utilized in a combustion zone to generate heat for steam production or other energy recovery purposes, said hydrogen is selectively removed from a CO--H.sub.2 -containing feed stream by partial oxidation thereof prior to disproportionation of the CO content of said stream.

Frost, Albert C. (Congers, NY)

1980-01-01T23:59:59.000Z

110

Attosecond Control of Electron Dynamics in Carbon Monoxide I. Znakovskaya,1  

E-Print Network [OSTI]

Attosecond Control of Electron Dynamics in Carbon Monoxide I. Znakovskaya,1 P. von den Hoff,2 S by manipulating the laser frequency, phase and polarization in closed loop experiments [1]. Control- faces in the observed control? We describe experiments, where control of electron dynamics in carbon

Kling, Matthias

111

Effects of exogenous carbon monoxide on radiation-induced bystander effect in zebrafish embryos in vivo  

E-Print Network [OSTI]

that the dose-response of radiation in the low-dose regime deviated from the LNT model. A notable example radiation are linearly proportional to the absorbed dose, evidence accumulated in the past decades showed as a pharmaceutical agent to release a low dose of exogenous carbon monoxide (CO) to attenuate the effect on bystander

Yu, K.N.

112

Observations of rotating jets of carbon monoxide in comet Hale-Bopp with the IRAM interferometer  

E-Print Network [OSTI]

Observations of rotating jets of carbon monoxide in comet Hale-Bopp with the IRAM interferometer the projection of the jet mean velocity on the line of sight. As the jet rotates with the nucleus, the velocity, an interesting feature is to be noted. We have computed the mean photometric centre from the peak intensity

Demoulin, Pascal

113

Multimodel simulations of carbon monoxide: Comparison with observations and projected near-future changes  

E-Print Network [OSTI]

development of a gridded climatology for tropospheric ozone,et al. , 2000] O 3 climatology based on satellite and sondeO 3 nudged toward climatology above 380 K zonal mean O 3

2006-01-01T23:59:59.000Z

114

Nuclear conflict and ozone depletion Quick summary  

E-Print Network [OSTI]

Nuclear conflict and ozone depletion Quick summary o Regional nuclear war could cause global which traps pollutants o Nuclear weapons cause explosions, which then causes things around the vicinity to start burning, which in turn releases black carbon; it is not the nuclear material or fallout causing

Toohey, Darin W.

115

Drinking Water Problems: Lead  

E-Print Network [OSTI]

Lead in drinking water can damage the brain, kidneys, nervous system and red blood cells. This publication explains how lead can enter drinking water, how to have your water tested, and how to eliminate lead from drinking water....

Dozier, Monty; McFarland, Mark L.

2004-02-20T23:59:59.000Z

116

Retrieval of ozone and nitrogen dioxide concentrations from Stratospheric Aerosol and Gas Experiment III (SAGE III)  

E-Print Network [OSTI]

Retrieval of ozone and nitrogen dioxide concentrations from Stratospheric Aerosol and Gas extinction. We retrieve ozone and nitrogen dioxide number densities and aerosol extinction from transmission), Retrieval of ozone and nitrogen dioxide concentrations from Stratospheric Aerosol and Gas Experiment III

117

Satellite observations of ozone and nitrogen dioxide: from retrievals to emission estimates  

E-Print Network [OSTI]

Satellite observations of ozone and nitrogen dioxide: from retrievals to emission estimates #12 Satellite observations of ozone and nitrogen dioxide: from retrievals to emission es- timates / by Bas Subject headings: satellite retrieval / nitrogen dioxide / ozone / air pollution / emis- sion estimates

Haak, Hein

118

Application of gaseous disinfectants ozone and chlorine dioxide for inactivation of Bacillus subtilis spores  

E-Print Network [OSTI]

inhibitor line Ozone Generator Oxygen Concentrator CellSequal oxygen concentrator and Pure-O-Tech ozone generator.This oxygen is then supplied into the ozone generator for

Aydogan, Ahmet

2006-01-01T23:59:59.000Z

119

A Study of Vibrational Relaxation of B-State Carbon Monoxide in the Heme Pocket of Photolyzed Carboxymyoglobin  

E-Print Network [OSTI]

, Massachusetts 02215 ABSTRACT The vibrational energy relaxation of dissociated carbon monoxide in the heme pocket for the two CO substate frequencies, T1(B1) 335 115 ps and T1(B2) 330 145 ps. These simulation results

Straub, John E.

120

Top-down estimate of a large source of atmospheric carbon monoxide associated with fuel combustion in Asia  

E-Print Network [OSTI]

modeling methodology, we find that the source of carbon monoxide from fossil-fuel and biofuel combustion-fuel and- biofuel combustion sources in North America, Europe, Asia (including Indonesia and the Middle

Palmer, Paul

Note: This page contains sample records for the topic "monoxide ozone lead" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Impact of emissions, chemistry, and climate on atmospheric carbon monoxide : 100-year predictions from a global chemistry-climate model  

E-Print Network [OSTI]

The possible trends for atmospheric carbon monoxide in the next 100 yr have been illustrated using a coupled atmospheric chemistry and climate model driven by emissions predicted by a global economic development model. ...

Wang, Chien.; Prinn, Ronald G.

122

Ozone chemistry in the smoke from the Kuwait oil fires  

SciTech Connect (OSTI)

Ozone depletion occurred in the core of the plume of smoke from the Kuwait oil fires within 100 km of the fires, primarily in regions where NO{sub x} concentrations were high and ultraviolet flux was near zero. Rapid conversion of NO to NO{sub 2} can explain almost all of the ozone loss. Ozone was produced in diffuse regions of the plume, where the ultraviolet flux was higher than in the core. However, due to the relatively high ratio of nonmethane hydrocarbons to NO{sub x}, ozone production was slow. Since ozone was produced in a much larger volume than it was depleted, the plume as a whole was a source of ozone on a regional scale. 27 refs., 4 figs., 1 tab.

Herring, J.A.; Hobbs, P.V. [Univ. of Washington, Seattle, WA (United States)

1992-09-20T23:59:59.000Z

123

Ozone Removal by Filters Containing Activated Carbon: A Pilot Study  

SciTech Connect (OSTI)

This study evaluated the ozone removal performance of moderate-cost particle filters containing activated carbon when installed in a commercial building heating, ventilating, and air conditioning (HVAC) system. Filters containing 300 g of activated carbon per 0.09 m2 of filter face area were installed in two 'experimental' filter banks within an office building located in Sacramento, CA. The ozone removal performance of the filters was assessed through periodic measurements of ozone concentrations in the air upstream and downstream of the filters. Ozone concentrations were also measured upstream and downstream of a 'reference' filter bank containing filters without any activated carbon. The filter banks with prefilters containing activated carbon were removing 60percent to 70percent of the ozone 67 and 81 days after filter installation. In contrast, there was negligible ozone removal by the reference filter bank without activated carbon.

Fisk, William; Spears, Mike; Sullivan, Douglas; Mendell, Mark

2009-09-01T23:59:59.000Z

124

airborne antarctic ozone: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

winter weather conditions: Severe cold and isolated air ow: circumpolar vortex North pole vortex breakdown replenishes ozone layer from outside: mixes air 12; E11;ects...

125

antarctic ozone recovery: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

winter weather conditions: Severe cold and isolated air ow: circumpolar vortex North pole vortex breakdown replenishes ozone layer from outside: mixes air 12; E11;ects...

126

antarctic ozone hole: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

winter weather conditions: Severe cold and isolated air ow: circumpolar vortex North pole vortex breakdown replenishes ozone layer from outside: mixes air 12; E11;ects...

127

antarctic ozone experiment: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

winter weather conditions: Severe cold and isolated air ow: circumpolar vortex North pole vortex breakdown replenishes ozone layer from outside: mixes air 12; E11;ects...

128

antarctic ozone depletion: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

winter weather conditions: Severe cold and isolated air ow: circumpolar vortex North pole vortex breakdown replenishes ozone layer from outside: mixes air 12; E11;ects...

129

Exposure-Relevant Ozone Chemistry in Occupied Spaces  

E-Print Network [OSTI]

from the material balance on ozone (equation 4-1). S [O 3 ](equation 5-2, which reflects a steady-state material balance

Coleman, Beverly Kaye

2009-01-01T23:59:59.000Z

130

E-Print Network 3.0 - ambient ozone levels Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

level ozone. Lesson 2: Ozone Formation... , power plants and industry all emit air pollution that forms ... Source: Royer, Dana - Department of Earth and Environmental Sciences,...

131

E-Print Network 3.0 - ash ozonation technology Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

ozonation technology Search Powered by Explorit Topic List Advanced Search Sample search results for: ash ozonation technology Page: << < 1 2 3 4 5 > >> 1 Fine volcanic Predicting...

132

E-Print Network 3.0 - ambient ozone growth Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Climate and Environment (Climate) Impacts of ozone on trees and crops Summary: and carbon sequestration. Vegetation exposure to ozone reduces photosynthesis, growth, and...

133

Catalytic reactions on well-characterized vanadium oxide catalysts. 1. Oxidation of carbon monoxide  

SciTech Connect (OSTI)

The oxidation of carbon monoxide over unsupported and supported vanadium oxide catalysts was investigated from the standpoint of structure sensitivity. The activity of unsupported V/sub 2/O/sub 5/ markedly decreased the turnover frequency, while the reduction-oxidation treatment of the fused catalyst increased it. The turnover frequency of V/sub 2/O/sub 5//TiO/sub 2/ with low V/sub 2/O/sub 5/ content was much smaller than that of the V/sub 2/O/sub 5//TiO/sub 2/ with high V/sub 2/O/sub 5/ content or the unsupported V/sub 2/O/sub 5/. Such a retarding effect of the TiO/sub 2/ support on the activity of the oxidation of carbon monoxide is in contrast to the known promoting effect of TiO/sub 2/ for the oxidations of various hydrocarbons. From these results coupled with the characterization of the catalysts, it was concluded that the oxidation of carbon monoxide on vanadium oxide catalysts is a structure-sensitive reaction and that the activity of surface defects such as steps, kinks, and vacancies is much higher than that of the surface V=O species in the smooth (010) face of V/sub 2/O/sub 5/. 39 references, 9 figures, 2 tables.

Mori, K.; Miyamoto, A.; Murakami, Y.

1984-06-21T23:59:59.000Z

134

ORIGINAL CONTRIBUTION Ozone and Short-term Mortality  

E-Print Network [OSTI]

. With the National Morbidity, Mortality, and Air Pollution Study (NMMAPS), we have developed na- tional approaches Ambient Air Qual- ity Standard (NAAQS) for ozone, adding a daily maximum 8-hour stan- dard of 80 ppb.19 Because of the relevance of epidemiologic evi- dence to the NAAQS for ozone and other pollutants

Dominici, Francesca

135

Atmospheric Environment 41 (2007) 31513160 Ozone removal by HVAC filters  

E-Print Network [OSTI]

Atmospheric Environment 41 (2007) 3151­3160 Ozone removal by HVAC filters P. Zhao, J.A. Siegel�, R May 2006; accepted 14 June 2006 Abstract Residential and commercial HVAC filters that have been loaded of the relative importance of HVAC filters as a removal mechanism for ozone in residential and commercial

Siegel, Jeffrey

136

Proceedings: Indoor Air 2005 OZONE REMOVAL BY RESIDENTIAL HVAC FILTERS  

E-Print Network [OSTI]

Proceedings: Indoor Air 2005 2366 OZONE REMOVAL BY RESIDENTIAL HVAC FILTERS P Zhao1,2 , JA Siegel1, Austin, Texas 78758, USA ABSTRACT HVAC filters have a significant influence on indoor air quality% for Filter #2 at a face velocity of 0.81 cm/s. The potential for HVAC filters to affect ozone concentrations

Siegel, Jeffrey

137

URBAN OZONE CONCENTRATION FORECASTING WITH ARTIFICIAL NEURAL NETWORK IN CORSICA  

E-Print Network [OSTI]

Perceptron; Ozone concentration. 1. Introduction Tropospheric ozone is a major air pollution problem, both, Ajaccio, France, e-mail: balu@univ-corse.fr Abstract: Atmospheric pollutants concentration forecasting is an important issue in air quality monitoring. Qualitair Corse, the organization responsible for monitoring air

Boyer, Edmond

138

Effects of 20002050 changes in climate and emissions on global tropospheric ozone and the policy-relevant background surface ozone  

E-Print Network [OSTI]

) project major changes in anthro- pogenic emissions of greenhouse gases and ozone precur- sors over the 2Effects of 2000­2050 changes in climate and emissions on global tropospheric ozone and the policy; published 27 September 2008. [1] We use a global chemical transport model (GEOS-Chem) driven by a general

Mickley, Loretta J.

139

Theoretical and experimental studies of heterogeneous chemical processes leading to stratospheric ozone depletion  

E-Print Network [OSTI]

The microscopic chemical mechanisms of heterogeneous reactions involving HC on crystalline ice and nitric acid trihydrate (NAT) are of fundamental interest to physical chemists, because such reactions yield "active" chlorine ...

Mantz, Yves André, 1974-

2002-01-01T23:59:59.000Z

140

Proceedings: Indoor Air 2005 REACTIONS BETWEEN OZONE AND BUILDING PRODUCTS: IMPACT ON  

E-Print Network [OSTI]

Proceedings: Indoor Air 2005 2118 REACTIONS BETWEEN OZONE AND BUILDING PRODUCTS: IMPACT ON PRIMARY of reactions of ozone on building products and on their emissions in indoor air. For this purpose, 12 building products were exposed to ozone in a dedicated experimental setup. The measured ozone removal rate

Paris-Sud XI, Université de

Note: This page contains sample records for the topic "monoxide ozone lead" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Ozone ensemble forecast with machine learning Vivien Mallet,1,2  

E-Print Network [OSTI]

Ozone ensemble forecast with machine learning algorithms Vivien Mallet,1,2 Gilles Stoltz,3 forecasts. The latter rely on a multimodel ensemble built for ozone forecasting with the modeling system Europe in order to forecast ozone daily peaks and ozone hourly concentrations. On the basis of past

Paris-Sud XI, Université de

142

An ozone climatology of the Dallas-Fort Worth area and its relationship to meteorology  

E-Print Network [OSTI]

, no extensive studies on ozone in this area have been published. This study presents a broad overview of the ozone problem in the DFW area. An ozone spatial and temporal climatology was constructed using ozone data at 23 different monitoring sites from 1980...

Nobis, Timothy Edward

1998-01-01T23:59:59.000Z

143

Nonadiabatic calculations of ultraviolet absorption cross section of sulfur monoxide: Isotopic effects on the photodissociation reaction  

SciTech Connect (OSTI)

Ultraviolet absorption cross sections of the main and substituted sulfur monoxide (SO) isotopologues were calculated using R-Matrix expansion technique. Energies, transition dipole moments, and nonadiabatic coupling matrix elements were calculated at MRCI/AV6Z level. The calculated absorption cross section of {sup 32}S{sup 16}O was compared with experimental spectrum; the spectral feature and the absolute value of photoabsorption cross sections are in good agreement. Our calculation predicts a long lived photoexcited SO* species which causes large non-mass dependent isotopic effects depending on the excitation energy in the ultraviolet region.

Danielache, Sebastian O.; Tomoya, Suzuki; Nanbu, Shinkoh [Department of Materials and Life Sciences, Faculty of Science and Technology, Sophia University, Chiyoda Ku, Tokyo 102-8554 (Japan)] [Department of Materials and Life Sciences, Faculty of Science and Technology, Sophia University, Chiyoda Ku, Tokyo 102-8554 (Japan); Kondorsky, Alexey [P. N. Lebedev Physical Institute of Russian Academy of Science, Leninsky pr., 53, Moscow, 119991 (Russian Federation) [P. N. Lebedev Physical Institute of Russian Academy of Science, Leninsky pr., 53, Moscow, 119991 (Russian Federation); Moscow Institute of Physics and Technology (State University), Institutsky per., 9, Dolgoprudny Moscow region, 141700 (Russian Federation); Tokue, Ikuo [Department of Chemistry, Faculty of Science, Niigata University, Ikarashi, Niigata 950-2181 (Japan)] [Department of Chemistry, Faculty of Science, Niigata University, Ikarashi, Niigata 950-2181 (Japan)

2014-01-28T23:59:59.000Z

144

Evaluation of microporous carbon filters as catalysts for ozone decomposition  

SciTech Connect (OSTI)

Ozone is produced in small quantities in photocopiers and laser printers in the workplace and large quantities in industrial waste water treatment facilities. Carbon filters are commonly used to decompose this unwanted ozone. The three most important factors in producing a filter for this purpose are flow properties, efficiency, and cost. Most ozone decomposition applications require very low back-pressure at modest flow rates. The tradeoff between the number of pores and the size of the pores will be discussed. Typical unfiltered emissions in the workplace are approximately 1 ppm. The maximum permissible exposure limit, PEL, for worker exposure to ozone is 0.1 ppm over 8 hours. Several methods have been examined to increase the efficiency of ozone decomposition. Carbon surfaces were modified with catalysts, the surface activated, and the surface area was increased, in attempts to decompose ozone more effectively. Methods to reduce both the processing and raw material costs were investigated. Several sources of microporous carbon were investigated as ozone decomposition catalysts. Cheaper processing routes including macropore templating, faster drying and extracting methods were also studied.

Whinnery, L.; Coutts, D.; Shen, C.; Adams, R. [Sandia National Labs., Livermore, CA (United States); Quintana, C.; Showalter, S. [Sandia National Labs., Albuquerque, NM (United States)

1994-12-31T23:59:59.000Z

145

Exposure-Relevant Ozone Chemistry in Occupied Spaces  

SciTech Connect (OSTI)

Ozone, an ambient pollutant, is transformed into other airborne pollutants in the indoor environment. In this dissertation, the type and amount of byproducts that result from ozone reactions with common indoor surfaces, surface residues, and vapors were determined, pollutant concentrations were related to occupant exposure, and frameworks were developed to predict byproduct concentrations under various indoor conditions. In Chapter 2, an analysis is presented of secondary organic aerosol formation from the reaction of ozone with gas-phase, terpene-containing consumer products in small chamber experiments under conditions relevant for residential and commercial buildings. The full particle size distribution was continuously monitored, and ultrafine and fine particle concentrations were in the range of 10 to>300 mu g m-3. Particle nucleation and growth dynamics were characterized.Chapter 3 presents an investigation of ozone reactions with aircraft cabin surfaces including carpet, seat fabric, plastics, and laundered and worn clothing fabric. Small chamber experiments were used to determine ozone deposition velocities, ozone reaction probabilities, byproduct emission rates, and byproduct yields for each surface category. The most commonly detected byproducts included C1?C10 saturated aldehydes and skin oil oxidation products. For all materials, emission rates were higher with ozone than without. Experimental results were used to predict byproduct exposure in the cabin and compare to other environments. Byproduct levels are predicted to be similar to ozone levels in the cabin, which have been found to be tens to low hundreds of ppb in the absence of an ozone converter. In Chapter 4, a model is presented that predicts ozone uptake by and byproduct emission from residual chemicals on surfaces. The effects of input parameters (residue surface concentration, ozone concentration, reactivity of the residue and the surface, near-surface airflow conditions, and byproduct yield) were explored. In Chapter 5, the reaction of ozone with permethrin, a residual insecticide used in aircraft cabins, to form phosgene is investigated. A derivatization technique was developed to detect phosgene at low levels, and chamber experiments were conducted with permethrin-coated cabin materials. It was determined that phosgene formation, if it occurs in the aircraft cabin, is not likely to exceed the relevant, health-based phosgene exposure guidelines.

Coleman, Beverly Kaye

2009-04-01T23:59:59.000Z

146

Ozone generation by rock fracture: Earthquake early warning?  

SciTech Connect (OSTI)

We report the production of up to 10 ppm ozone during crushing and grinding of typical terrestrial crust rocks in air, O{sub 2} and CO{sub 2} at atmospheric pressure, but not in helium or nitrogen. Ozone is formed by exoelectrons emitted by high electric fields, resulting from charge separation during fracture. The results suggest that ground level ozone produced by rock fracture, besides its potential health hazard, can be used for early warning in earthquakes and other catastrophes, such as landslides or land shifts in excavation tunnels and underground mines.

Baragiola, Raul A.; Dukes, Catherine A.; Hedges, Dawn [Engineering Physics, University of Virginia, Charlottesville, Virginia 22904 (United States)

2011-11-14T23:59:59.000Z

147

Ultraviolet photoelectron spectroscopic study of the interaction of potassium with carbon monoxide and benzene on the Pt(111) surface  

SciTech Connect (OSTI)

The interaction of potassium with carbon monoxide and benezene has been studied on the Pt(111) crystal surface by ultraviolet photoelectron spectroscopy (UPS). The adsorptive changes reported in previous studies for carbon monoxide and benzene when potassium is coadsorbed are correlated with the UPS results presented here and are explained with the aid of a molecular orbital analysis. The authors find that the valence molecular orbitals increase their binding energy slightly when the potassium is coadsorbed, implying a model in which the adsorbates sense the potassium-induced changes in dipole field at the surface. 36 references, 11 figures.

Kudo, M.; Garfunkel, E.L.; Somorjai, G.A.

1985-07-18T23:59:59.000Z

148

Observation of two-dimensional compositional ordering of a carbon monoxide and argon monolayer mixture physisorbed on graphite  

SciTech Connect (OSTI)

Commensurate monolayers of a mixture of 70% carbon monoxide and 30% argon on graphite are studied by neutron and low-energy-electron diffraction. A 2 x 2 superstructure due to 3:1 compositional ordering is observed below 25 K. The compositional ordering is most likely due to molecular-axis ordering of carbon monoxide molecules into a pinwheel pattern with argon atoms at the central sites of each pinwheel. Such a pinwheel structure has been predicted by Harris, Mouritsen, and Berlinsky for planar rotors with anisotropic interactions on a triangular lattice with vacancies.

You, H.; Fain, S.C. Jr.; Satija, S.; Passell, L.

1986-01-20T23:59:59.000Z

149

Thermal device and method for production of carbon monoxide and hydrogen by thermal dissociation of hydrocarbon gases  

DOE Patents [OSTI]

Carbon monoxide is produced in a fast quench reactor. The production of carbon monoxide includes injecting carbon dioxide and some air into a reactor chamber having a high temperature at its inlet and a rapidly expanding a reactant stream, such as a restrictive convergent-divergent nozzle at its outlet end. Carbon dioxide and other reactants such as methane and other low molecular weight hydrocarbons are injected into the reactor chamber. Other gas may be added at different stages in the process to form a desired end product and prevent back reactions. The resulting heated gaseous stream is then rapidly cooled by expansion of the gaseous stream.

Detering, Brent A. (Idaho Falls, ID); Kong, Peter C. (Idaho Falls, ID)

2001-01-01T23:59:59.000Z

150

Adsorption and desorption of hydrogen and carbon monoxide were studied on alumina-supported iridium catalysts  

SciTech Connect (OSTI)

The adsorption and desorption of hydrogen and carbon monoxide were studied on alumina-supported iridium catalysts which were examined by a scanning transmission electron microscope (STEM). The metal particle size and number of particles per area of catalyst increased with increasing metal loading. The particles were approx. 10 A. in diameter, cubo-octahedral shaped, and approx. 80-90% disperse. The STEM electron beam caused negligible damage to the samples. Hydrogen adsorption measurements showed that the hydrogen-iridium atom ratio was 1.2:1-1.3:1 and increased with decreasing metal loading. Temperature-programed desorption showed four types of adsorbed hydrogen desorbing at -90/sup 0/C (I), 15/sup 0/C (IV), 115/sup 0/C (II), and 245/sup 0/C (III). Types II and IV desorb from single atom sites and Types I and III from multiple atom sites. Type I is in rapid equilibrium with the gas phase. All desorption processes appear to be first order. Carbon monoxide adsorbed nondissociatively at 25/sup 0/C with approx. 0.7:1 CO/Ir atom ratio. It adsorbed primarily in linear forms at low coverage, but a bridged form appeared at high coverage.

Etherton, B.P.

1980-01-01T23:59:59.000Z

151

Lead carbonate scintillator materials  

DOE Patents [OSTI]

Improved radiation detectors containing lead carbonate or basic lead carbonate as the scintillator element are disclosed. Both of these scintillators have been found to provide a balance of good stopping power, high light yield and short decay constant that is superior to other known scintillator materials. The radiation detectors disclosed are favorably suited for use in general purpose detection and in medical uses. 3 figures.

Derenzo, S.E.; Moses, W.W.

1991-05-14T23:59:59.000Z

152

Ozone concentrations in El Paso, Texas  

SciTech Connect (OSTI)

El Paso, Texas may have a problem in meeting ambient air standards due to influx of pollutants from foreign sources. Cd. Juarez, Chihuahua, and Fort Bliss abut the city and are areas over which the Texas Air Control Board (TACB) has little or no jurisdiction. The Board maintains two Continuous Air Monitoring Stations (CAM) in El Paso. Ozone, nitric oxide, and nitrogen dioxide data were obtained from these stations. If the EPA Empirical Kinetic Model is used for El Paso, reducing NMHC concentrations may increase rather than decrease O/sub 3/ concentrations. The Texas State Implementation Plan, while not based on Empirical Kinetic Modeling, calls for a reduction of 18% in NMHC. However, 31% of all NMHC in El Paso arise from sources over which Texas had little (a federal military reservation) or no (Cd. Juarez) jurisdiction. It appears the TACB is correct in believing the SIP for O/sub 3/ may not bring El Paso into compliance. (JMT)

Crocker, J.E. (Texas Air Control Board, Austin); Applegate, H.G.

1983-02-01T23:59:59.000Z

153

Attosecond electronic and nuclear quantum photodynamics of the ozone molecule  

SciTech Connect (OSTI)

Coupled electron-nuclear dynamics simulations are investigated for the ozone molecule on the attosecond time scale. The initial wavepacket is pumped as a coherent superposition of two or three electronic states.

Halász, G. J. [Department of Information Technology, University of Debrecen, H-4010 Debrecen, PO Box 12 (Hungary)] [Department of Information Technology, University of Debrecen, H-4010 Debrecen, PO Box 12 (Hungary); Perveaux, A.; Lasorne, B.; Gatti, F. [CTMM, Institut Charles Gerhardt Montpellier, F-34095 Montpellier Cedex 5 (France)] [CTMM, Institut Charles Gerhardt Montpellier, F-34095 Montpellier Cedex 5 (France); Robb, M. A. [Imperial College London, Department of Chemistry, London SW7 2AZ (United Kingdom)] [Imperial College London, Department of Chemistry, London SW7 2AZ (United Kingdom); Vibók, Á. [Department of Theoretical Physics, University of Debrecen, H-40410 Debrecen, PO Box 5 (Hungary)] [Department of Theoretical Physics, University of Debrecen, H-40410 Debrecen, PO Box 5 (Hungary)

2013-11-13T23:59:59.000Z

154

Global Health and Economic Impacts of Future Ozone Pollution  

E-Print Network [OSTI]

We assess the human health and economic impacts of projected 2000-2050 changes in ozone pollution using the MIT Emissions Prediction and Policy Analysis-Health Effects (EPPA-HE) model, in combination with results from the ...

Webster, Mort D.

155

The role of ozone in tracheal cell transformation  

SciTech Connect (OSTI)

This project examined the potential role of ozone as a respiratory carcinogen by characterizing its ability to induce or modulate the preneoplastic transformation of rat tracheal epithelial cells. The chemical reactivity of ozone and the types of damage it can cause suggest that it may have a role in environmental carcinogenesis. Few other studies have examined the direct cytotoxic or transforming effects of ozone after in vivo or in vitro exposure of cells, and no studies have been reported on the comparative effects of ozone on respiratory cells exposed in vivo or in vitro. The induction of early preneoplastic changes in populations of rat tracheal epithelial cells by carcinogens can be detected and quantified in vitro after exposures in vivo or in vitro of tracheal epithelial cells. This cell culture and transformation system was used to characterize the transforming potency of ozone. Tracheal epithelial cells were isolated from Fischer-344/N rats that had been exposed for six hours per day, five days per week for one, two, or four weeks to 0, 0.12, 0.5, or 1.0 parts per million (ppm)* ozone (sea-level equivalents). Cell populations were examined in culture for increases in the frequency of preneoplastic variants. Rats exposed to ozone did not exhibit an increase in the frequency of preneoplastic tracheal cells, although exposed tracheas did exhibit dose-dependent morphological changes. Rat tracheal epithelial cells were given single, 40-minute in vitro exposures to concentrations of ozone that did not result in any detectable decrease in colony-forming efficiency.

Thomassen, D.G.; Harkema, J.R.; Sun, J.D.; Stephens, N.D.; Griffith, W.C. (Inhalation Toxicology Research Institute, Lovelace Biomedical and Environmental Research Institute, Albuquerque, NM (United States))

1992-04-01T23:59:59.000Z

156

Design and Development of a Mid-Infrared Carbon Monoxide Sensor for a High-Pressure Combustor Rig  

E-Print Network [OSTI]

A sensor for carbon monoxide measurement has been developed using a mid-infrared quantum-cascade (QC) laser operating in the fundamental band (?v= 1) of CO near 4.5 ?m. The fundamental band was chosen due to its stronger absorption line...

Camou, Alejandro

2014-05-03T23:59:59.000Z

157

Analysis of black carbon and carbon monoxide observed over the Indian Ocean: Implications for emissions and photochemistry  

E-Print Network [OSTI]

and known emission factors for black carbon (BC) from South Asia yields 0.7 Tg yrÃ?1 (upper limit of about 1 Global Change: Atmosphere (0315, 0325); KEYWORDS: Soot, black carbon, CO, emissions, India Citation of black carbon and carbon monoxide observed over the Indian Ocean: Implications for emissions

Dickerson, Russell R.

158

Prediction of Carbon Monoxide and Hydrocarbon Emissions in Isooctane HCCI Engine Combustion Using Multi-Zone Simulations  

SciTech Connect (OSTI)

Homogeneous Charge Compression Ignitions (HCCI) engines show promise as an alternative to Diesel engines, yet research remains: development of practical HCCI engines will be aided greatly by accurate modeling tools. A novel detailed chemical kinetic model that incorporates information from a computational fluid mechanics code has been developed to simulate HCCI combustion. This model very accurately predicts many aspects of the HCCI combustion process. High-resolution computational grids can be used for the fluid mechanics portion of the simulation, but the chemical kinetics portion of the simulation can be reduced to a handful of computational zones (for all previous work 10 zones have been used). While overall this model has demonstrated a very good predictive capability for HCCI combustion, previous simulations using this model have tended to underpredict carbon monoxide emissions by an order of magnitude. A factor in the underprediction of carbon monoxide may be that all previous simulations have been conducted with 10 chemical kinetic zones. The chemistry that results in carbon monoxide emissions is very sensitive to small changes in temperature within the engine. The resolution in temperature is determined directly by the number of zones. This paper investigates how the number of zones (i.e. temperature resolution) affects the model's prediction of hydrocarbon and carbon monoxide emissions in an HCCI engine. Simulations with 10, 20, and 40 chemical kinetic zones have been conducted using a detailed chemical kinetic mechanism (859 species, 3606 reactions) to simulate an isooctane fueled HCCI engine. The results show that 10-zones are adequate to resolve the hydrocarbon emissions, but a greater numbers of zones are required to resolve carbon monoxide emissions. Results are also presented that explore spatial sources of the exhaust emissions within the HCCI engine combustion chamber.

Flowers, D; Aceves, S M; Martinez-Frias, J; Dibble, R

2002-05-02T23:59:59.000Z

159

Chemisorption of carbon monoxide and nitrogen oxides on highly dispersed technetium  

SciTech Connect (OSTI)

The purpose of this work is to study, in infrared spectroscopy, the surface compounds formed on adsorption of carbon monoxide and nitrogen oxides on Tc/SiO/sub 2/. The samples were prepared by soaking Aerosil with aqueous solution of ammonium pertechnetate containing 10 wt.% of Tc. Reduction with hydrogen to the metal was carried out at 700-800/sup 0/C. Results indicated that chemisorption of CO on highly dispersed technetium gives rise to a single type of linear and several types of multicentered adsorption forms. Occurrence of bridge form of adsorbed CO was also suggested on the basis of the data on chemisorption stoichiometry. Formation of a structure characterizable by absorption at 1790 cm/sup -1/ may indicate, only after protracted analysis, that the surface of the technetium introduced gradually suffers significant rearrangement facilitating formation of this type of complexes.

Serebryakova, N.V.; Sokolova, N.P.; Spitsyn, V.S.

1982-08-01T23:59:59.000Z

160

Infrared spectroscopic study of the adsorption of carbon monoxide on silica-supported copper oxide  

SciTech Connect (OSTI)

Adsorption of carbon monoxide at room temperature (0.1 to 50 Torr) on silica-supported copper oxide was studied by infrared spectroscopy. Catalysts were prepared by deposition-precipitation or impregnation. After calcination two types of adsorbed CO were identified showing absorption bands at 2136 +- 3 and 2204 +- 1 cm/sup -1/, which are ascribed to CO adsorbed on copper(II) oxide and on isolated copper(II) ions in the silica surface, respectively. Reduction and reoxidation removed the band at 2204 cm/sup -1/ with all samples and raised the intensity of the 2136-cm/sup -1/ band with the precipitated catalysts but not with the impregnation catalyst. Evidence is brought forward that the isolated copper ions are mobilized during reduction and generate new copper (oxide) surface. The change in background transmission of the samples could be used to obtain further information about the interaction of O/sub 2/ and CO with copper oxide.

De Jong, K.P.; Geus, J.W.; Joziasse, J.

1980-10-01T23:59:59.000Z

Note: This page contains sample records for the topic "monoxide ozone lead" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Primary lead smelter, Doe Run, Herculaneum, Missouri: Volume 2 -- Appendix B.1. Final report  

SciTech Connect (OSTI)

The United States Environmental Protection Agency`s (EPA) Emission Standards Division (ESD) is investigating the primary lead smelting source category to identify and quantify organic hazardous air pollutants (HAPs) emitted from blast furnaces. The primary objective was to obtain data on the emissions of volatile and semi-volatile organic HAPs, aldehydes, and ketones from primary lead smelter blast furnaces. A secondary objective was to obtain data on the emissions of carbon monoxide. The data will be used by ESD to determine whether organic HAPs are emitted at levels that would justify regulation under the Maximum Achievable Control Technology (MACT) program. The Doe Run Company, which operates a primary lead smelter in Herculaneum, Missouri was selected by the ESD as the host facility for this project. This volume consists of Appendix B.1.

Phoenix, F.J.

1999-08-01T23:59:59.000Z

162

Primary lead smelter, Doe Run, Herculaneum, Missouri: Volume 1 -- Text and Appendix A. Final report  

SciTech Connect (OSTI)

The United States Environmental Protection Agency`s (EPA) Emission Standards Division (ESD) is investigating the primary lead smelting source category to identify and quantify organic hazardous air pollutants (HAPs) emitted from blast furnaces. The primary objective was to obtain data on the emissions of volatile and semi-volatile organic HAPs, aldehydes, and ketones from primary lead smelter blast furnaces. A secondary objective was to obtain data on the emissions of carbon monoxide. The data will be used by ESD to determine whether organic HAPs are emitted at levels that would justify regulation under the Maximum Achievable Control Technology (MACT) program. The Doe Run Company, which operates a primary lead smelter in Herculaneum, Missouri was selected by the ESD as the host facility for this project. This volume consists of the report text and Appendix A.

Phoenix, F.J.

1999-08-01T23:59:59.000Z

163

Proceedings of Healthy Buildings 2009 Paper 141 Removal of Indoor Ozone with Reactive Materials: Preliminary Results and  

E-Print Network [OSTI]

Proceedings of Healthy Buildings 2009 Paper 141 Removal of Indoor Ozone with Reactive Materials air quality. #12;Proceedings of Healthy Buildings 2009 Paper 141 Removing ozone from indoor

Siegel, Jeffrey

164

Comparison of three vertically resolved ozone data sets: climatology, trends and radiative forcings  

E-Print Network [OSTI]

Climate models that do not simulate changes in stratospheric ozone concentrations require the prescription of ozone fields to accurately calculate UV fluxes and stratospheric heating rates. In this study, three different ...

Hassler, B.

165

Atmospheric Environment 38 (2004) 14251436 A development of ozone abatement strategies for the Grenoble  

E-Print Network [OSTI]

Atmospheric Environment 38 (2004) 1425­1436 A development of ozone abatement strategies are generated in the Grenoble plume. For developing ozone abatement strategies it is important to know whether

166

A delayed effect of ozone fumigation on photosynthesis of Norway spruce  

E-Print Network [OSTI]

A delayed effect of ozone fumigation on photosynthesis of Norway spruce D. Eamus1 A.W. Davis J into the long-lastincl effects of ozone fumiga- tion upon photosynthesis of Norway spruce. Measurements were

Paris-Sud XI, Université de

167

E-Print Network 3.0 - acute ozone-induced change Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Abstract Predicting ozone-induced reduction of carbon... a leaf-level model to the whole tree, it is possible to investigate whether the ozone-induced ... Source: Michigan...

168

Examination of the Effects of Sea Salt Aerosols on Southeast Texas Ozone and Secondary Organic Aerosol  

E-Print Network [OSTI]

such as ozone, reactive nitrogen, mercury, and sulfur containing compounds. Urban areas are most impacted by these trace gases, which is a concern because ozone especially affects the health of citizens. Experiments have three basic parts. First we generate mono...

Benoit, Mark David

2013-02-06T23:59:59.000Z

169

Pilot Scale Study of Excess Sludge Production Reduction in Wastewater Treatment by Ozone  

E-Print Network [OSTI]

Pilot Scale Study of Excess Sludge Production Reduction in Wastewater Treatment by Ozone Yuan Ma-scale reactors were operated at the LaPrairie Wastewater Treatment plant (one control and one ozonated

Barthelat, Francois

170

E-Print Network 3.0 - acid regulates ozone-induced Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

ozone-induced Search Powered by Explorit Topic List Advanced Search Sample search results for: acid regulates ozone-induced Page: << < 1 2 3 4 5 > >> 1 Plant Molecular Biology 51:...

171

1 Ozone pollution forecasting 3 Herve Cardot, Christophe Crambes and Pascal Sarda.  

E-Print Network [OSTI]

Contents 1 Ozone pollution forecasting 3 Herv´e Cardot, Christophe Crambes and Pascal Sarda. 1;1 Ozone pollution forecasting using conditional mean and conditional quantiles with functional covariates Herv´e Cardot, Christophe Crambes and Pascal Sarda. 1.1 Introduction Prediction of Ozone pollution

Crambes, Christophe

172

Oxidation of carbon monoxide and hydrocarbons on platinum and palladium catalysts in the presence of sulfur dioxide  

SciTech Connect (OSTI)

The authors report on a study of the effect of sulfur dioxide on the activity of platinum and palladium catalysts with respect to oxidation of the principal toxic components in the exhaust gases of internal combustion engines: carbon monoxide and hydrocarbons (propylene (C/sub 3/H/sub 6/) and propane (C/sub 3/H/sub 8/)). The experiments were carried out in a flow system equipped with Beckman infrared analyzers to monitor the concentrations of CO and hydrocarbons and of sulfur dioxide. A series of thermal desorption experiments was carried out in a low-pressure flow system with mass spectrometric analysis of the gas phase. The results indicate that the low-temperature adsorption of sulfur dioxide on platinum (and also palladium) catalysts inhibits the oxidation of carbon monoxide and propylene. The poisoning effect of O/sub 2/ is due to blockage of the platinum centers for adsorption of the oxidizable compounds and oxygen.

Panchishnyi, V.I.; Bondareva, N.K.; Sklyarov, A.V.; Rozanov, V.V.; Chadina, G.P.

1988-11-10T23:59:59.000Z

173

Ozone induces glucose intolerance and systemic metabolic effects in young and aged brown Norway rats  

SciTech Connect (OSTI)

Air pollutants have been associated with increased diabetes in humans. We hypothesized that ozone would impair glucose homeostasis by altering insulin signaling and/or endoplasmic reticular (ER) stress in young and aged rats. One, 4, 12, and 24 month old Brown Norway (BN) rats were exposed to air or ozone, 0.25 or 1.0 ppm, 6 h/day for 2 days (acute) or 2 d/week for 13 weeks (subchronic). Additionally, 4 month old rats were exposed to air or 1.0 ppm ozone, 6 h/day for 1 or 2 days (time-course). Glucose tolerance tests (GTT) were performed immediately after exposure. Serum and tissue biomarkers were analyzed 18 h after final ozone for acute and subchronic studies, and immediately after each day of exposure in the time-course study. Age-related glucose intolerance and increases in metabolic biomarkers were apparent at baseline. Acute ozone caused hyperglycemia and glucose intolerance in rats of all ages. Ozone-induced glucose intolerance was reduced in rats exposed for 13 weeks. Acute, but not subchronic ozone increased ?{sub 2}-macroglobulin, adiponectin and osteopontin. Time-course analysis indicated glucose intolerance at days 1 and 2 (2 > 1), and a recovery 18 h post ozone. Leptin increased day 1 and epinephrine at all times after ozone. Ozone tended to decrease phosphorylated insulin receptor substrate-1 in liver and adipose tissues. ER stress appeared to be the consequence of ozone induced acute metabolic impairment since transcriptional markers of ER stress increased only after 2 days of ozone. In conclusion, acute ozone exposure induces marked systemic metabolic impairments in BN rats of all ages, likely through sympathetic stimulation. - Highlights: • Air pollutants have been associated with increased diabetes in humans. • Acute ozone exposure produces profound metabolic alterations in rats. • Age influences metabolic risk factors in aging BN rats. • Acute metabolic effects are reversible and repeated exposure reduces these effects. • Ozone metabolic effects are only slightly exacerbated in geriatric rats.

Bass, V. [Environmental Public Health Division, National Health and Environmental Effects Research Laboratory, U.S. Environmental Protection Agency, Research Triangle Park, NC (United States); Gordon, C.J.; Jarema, K.A.; MacPhail, R.C. [Toxicity Assessment Division, National Health and Environmental Effects Research Laboratory, U.S. Environmental Protection Agency, Research Triangle Park, NC (United States); Cascio, W.E. [Environmental Public Health Division, National Health and Environmental Effects Research Laboratory, U.S. Environmental Protection Agency, Research Triangle Park, NC (United States); Phillips, P.M. [Toxicity Assessment Division, National Health and Environmental Effects Research Laboratory, U.S. Environmental Protection Agency, Research Triangle Park, NC (United States); Ledbetter, A.D.; Schladweiler, M.C. [Environmental Public Health Division, National Health and Environmental Effects Research Laboratory, U.S. Environmental Protection Agency, Research Triangle Park, NC (United States); Andrews, D. [Research Cores Unit, National Health and Environmental Effects Research Laboratory, U.S. Environmental Protection Agency, Research Triangle Park, NC (United States); Miller, D. [Curriculum in Toxicology, University of North Carolina, Chapel Hill, NC (United States); Doerfler, D.L. [Research Cores Unit, National Health and Environmental Effects Research Laboratory, U.S. Environmental Protection Agency, Research Triangle Park, NC (United States); Kodavanti, U.P., E-mail: kodavanti.urmila@epa.gov [Environmental Public Health Division, National Health and Environmental Effects Research Laboratory, U.S. Environmental Protection Agency, Research Triangle Park, NC (United States)

2013-12-15T23:59:59.000Z

174

Gas-phase energies of actinide oxides -- an assessment of neutral and cationic monoxides and dioxides from thorium to curium  

SciTech Connect (OSTI)

An assessment of the gas-phase energetics of neutral and singly and doubly charged cationic actinide monoxides and dioxides of thorium, protactinium, uranium, neptunium, plutonium, americium, and curium is presented. A consistent set of metal-oxygen bond dissociation enthalpies, ionization energies, and enthalpies of formation, including new or revised values, is proposed, mainly based on recent experimental data and on correlations with the electronic energetics of the atoms or cations and with condensed-phase thermochemistry.

Marcalo, Joaquim; Gibson, John K.

2009-08-10T23:59:59.000Z

175

Plasma Chemistry and Plasma Processing, Vol. 23, No. 3, September 2003 ( 2003) Ozone Production in the Negative DC Corona  

E-Print Network [OSTI]

: Corona discharge; corona plasma; plasma reacting flow; ozone; electrostatic precipitator; Damkohler

Chen, Junhong

176

Total oxidation of carbon monoxide and methane over transition metal-fluorite oxide composite catalysts. I. Catalyst composition and activity  

SciTech Connect (OSTI)

A novel metal oxide composite catalyst for the total oxidation of carbon monoxide and methane was prepared by combining fluorite oxides with active transition metals. The fluorite oxides, such as ceria and zirconia, are oxygen-ion-conducting materials having catalytic properties usually at high temperatures. Active base metal catalysts, such as copper, were used as additives to promote the catalytic properties of these oxides. The contact of the two types of materials gave rise to a high active oxidation catalyst. At a space velocity of about 42,000 h{sup {minus}1}, complete carbon monoxide oxidation in air occurred at room temperature on the Au{sub 0.05}[Ce(La)]{sub 0.95}L{sub x} catalyst and at ca. 100{degrees}C on Cu-Ce-O composite catalysts. At the same space velocity, total oxidation of methane on the Cu-Ce-O catalyst doped with La{sub 2}O{sub 3} or SrO took place at ca. 550{degrees}C. The specific carbon monoxide oxidation activity of the Cu-Ce-O catalyst was several orders of magnitude higher than that of conventional copper-based catalysts and comparable or superior to platinum catalysts. This type of composite catalyst also showed excellent resistance to water vapor poisoning. The enhanced catalyst activity and stability resulted from strong interaction of the transition metal and fluorite oxide materials. 44 refs., 14 figs., 5 tabs.

Liu, W.; Flytzani-Stephanopoulos, F. [Tufts Univ., Medford, MA (United States)] [Tufts Univ., Medford, MA (United States)

1995-05-01T23:59:59.000Z

177

Adsorption of carbon monoxide on a smooth palladium electrode: an in-situ infrared spectroscopic study  

SciTech Connect (OSTI)

Adsorption of carbon monoxide on a smooth palladium electrode in 1 M HClO/sub 4/ saturated with CO was studied by two in-situ IR reflectance spectroscopic methods: EMIRS (electrochemically modulated infrared reflectance spectroscopy) and LPSIRS (linear potential sweep infrared reflectance spectroscopy). Two types of adsorbed CO, linear and bridged, were identified from the observed IR spectra, the latter being the predominant surface species. The C-O stretching frequency of the linear CO shifts to higher frequencies at more positive potentials with a slope of 48 cm/sup -1//V. The frequency of the bridged CO increases by 63 cm/sup -1/ between -0.5 and 0.9 V(NHE) and its integrated band intensity decreases continuously in the same potential region while the intensity of the linear CO is almost constant up to 0.1 V and then decreases gradually with increasing positive potential. The surface selection rule of the IR reflection absorption spectroscopy was tested for the present system by using the p- and s-polarized light. It was found that only p-polarized light gave the IR spectra of CO adsorbed on the palladium electrode thus proving the selection rule at the electrode/solution interface.

Kunimatsu, K.

1984-05-24T23:59:59.000Z

178

Solar Carbon Monoxide, Thermal Profiling, and the Abundances of C, O, and their Isotopes  

E-Print Network [OSTI]

A solar photospheric "thermal profiling" analysis is presented, exploiting the infrared rovibrational bands of carbon monoxide (CO) as observed with the McMath-Pierce Fourier transform spectrometer (FTS) at Kitt Peak, and from above the Earth's atmosphere by the Shuttle-borne ATMOS experiment. Visible continuum intensities and center-limb behavior constrained the temperature profile of the deep photosphere, while CO center-limb behavior defined the thermal structure at higher altitudes. The oxygen abundance was self consistently determined from weak CO absorptions. Our analysis was meant to complement recent studies based on 3-D convection models which, among other things, have revised the historical solar oxygen (and carbon) abundance downward by a factor of nearly two; although in fact our conclusions do not support such a revision. Based on various considerations, an oxygen abundance of 700+/-100 ppm (parts per million relative to hydrogen) is recommended; the large uncertainty reflects the model sensitivity of CO. New solar isotopic ratios also are reported for 13C, 17O, and 18O.

Thomas R. Ayres; Claude Plymate; Christoph U. Keller

2006-06-07T23:59:59.000Z

179

Spectroscopic detection of Carbon Monoxide in the Young Supernova Remnant Cassiopeia A  

E-Print Network [OSTI]

We report the detection of carbon monoxide (CO) emission from the young supernova remnant Cassiopeia A (Cas A) at wavelengths corresponding to the fundamental vibrational mode at 4.65 micron. We obtained AKARI Infrared Camera spectra towards 4 positions which unambiguously reveal the broad characteristic CO ro-vibrational band profile. The observed positions include unshocked ejecta at the center, indicating that CO molecules form in the ejecta at an early phase. We extracted a dozen spectra across Cas A along the long 1 arcmin slits, and compared these to simple CO emission models in Local Thermodynamic Equilibrium to obtain first-order estimates of the excitation temperatures and CO masses involved. Our observations suggest that significant amounts of carbon may have been locked up in CO since the explosion 330 years ago. Surprisingly, CO has not been efficiently destroyed by reactions with ionized He or the energetic electrons created by the decay of the radiative nuclei. Our CO detection thus implies that...

Rho, Jeonghee; Cami, Jan; Reach, William

2012-01-01T23:59:59.000Z

180

Simultaneous Detection of Water, Methane and Carbon Monoxide in the Atmosphere of Exoplanet HR8799b  

E-Print Network [OSTI]

Absorption lines from water, methane and carbon monoxide are detected in the atmosphere of exoplanet HR8799b. A medium-resolution spectrum presented here shows well-resolved and easily identified spectral features from all three molecules across the K band. The majority of the lines are produced by CO and H2O, but several lines clearly belong to CH4. Comparisons between these data and atmosphere models covering a range of temperatures and gravities yield log mole fractions of H2O between -3.09 and -3.91, CO between -3.30 and -3.72 and CH4 between -5.06 and -5.85. More precise mole fractions are obtained for each temperature and gravity studied. A reanalysis of H-band data, previously obtained at similar spectral resolution, results in a nearly identical water abundance as determined from the K-band spectrum. The methane abundance is shown to be sensitive to vertical mixing and indicates an eddy diffusion coefficient in the range of 10^6 to 10^8 cm^2 s^-1, comparable to mixing in the deep troposphere of Jupite...

Barman, Travis S; Macintosh, Bruce; Marois, Christian

2015-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "monoxide ozone lead" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Search for the electric dipole moment of the electron with thorium monoxide  

E-Print Network [OSTI]

The electric dipole moment of the electron (eEDM) is a signature of CP-violating physics beyond the Standard Model. We describe an ongoing experiment to measure or set improved limits to the eEDM, using a cold beam of thorium monoxide (ThO) molecules. The metastable $H {}^3\\Delta_1$ state in ThO has important advantages for such an experiment. We argue that the statistical uncertainty of an eEDM measurement could be improved by as much as 3 orders of magnitude compared to the current experimental limit, in a first-generation apparatus using a cold ThO beam. We describe our measurements of the $H$ state lifetime and the production of ThO molecules in a beam, which provide crucial data for the eEDM sensitivity estimate. ThO also has ideal properties for the rejection of a number of known systematic errors; these properties and their implications are described.

Amar C. Vutha; Wesley C. Campbell; Yulia V. Gurevich; Nicholas R. Hutzler; Maxwell Parsons; David Patterson; Elizabeth Petrik; Benjamin Spaun; John M. Doyle; Gerald Gabrielse; David DeMille

2010-11-06T23:59:59.000Z

182

Relationship of respiratory symptoms and pulmonary function to tar, nicotine, and carbon monoxide yield of cigarettes  

SciTech Connect (OSTI)

The data from consecutive surveys of the Tucson Epidemiologic Study (1981-1988) were used to evaluate the relationship in cigarette smokers of respiratory symptoms and pulmonary function to tar, nicotine, and carbon monoxide (CO) yields of the cigarette. There were 690 subjects who reported smoking regularly in at least one survey, over age 15. After adjustment for intensity and duration of smoking and for depth of inhalation, the risk of chronic phlegm, cough, and dyspnea were not related to the tar and nicotine yields. In 414 subjects with pulmonary function tested in at least one of the three surveys the spirometric indices used were significantly related to the daily dose of tar, nicotine, and CO (product of the cigarette yield and daily number of cigarettes smoked). The effects were more pronounced for past than for current doses. However, the differentiation of pulmonary function due to various yields of cigarettes was small in comparison to the difference in pulmonary function between smokers and nonsmokers.

Krzyzanowski, M.; Sherrill, D.L.; Paoletti, P.; Lebowitz, M.D. (National Institute of Hygiene, Warsaw (Poland))

1991-02-01T23:59:59.000Z

183

Carbon monoxide oxidation over three different states of copper: Development of a model metal oxide catalyst  

SciTech Connect (OSTI)

Carbon monoxide oxidation was performed over the three different oxidation states of copper -- metallic (Cu), copper (I) oxide (Cu{sub 2}O), and copper (II) oxide (CuO) as a test case for developing a model metal oxide catalyst amenable to study by the methods of modern surface science and catalysis. Copper was deposited and oxidized on oxidized supports of aluminum, silicon, molybdenum, tantalum, stainless steel, and iron as well as on graphite. The catalytic activity was found to decrease with increasing oxidation state (Cu > Cu{sub 2}O > CuO) and the activation energy increased with increasing oxidation state (Cu, 9 kcal/mol < Cu{sub 2}O, 14 kcal/mol < CuO, 17 kcal/mol). Reaction mechanisms were determined for the different oxidation states. Lastly, NO reduction by CO was studied. A Cu and CuO catalyst were exposed to an equal mixture of CO and NO at 300--350 C to observe the production of N{sub 2} and CO{sub 2}. At the end of each reaction, the catalyst was found to be Cu{sub 2}O. There is a need to study the kinetics of this reaction over the different oxidation states of copper.

Jernigan, G.G. [California Univ., Berkeley, CA (United States). Dept. of Chemistry; [Lawrence Berkeley Lab., CA (United States). Materials and Chemical Sciences Div.

1994-10-01T23:59:59.000Z

184

Learning about ozone depletion Paul J. Crutzen & Michael Oppenheimer  

E-Print Network [OSTI]

Learning about ozone depletion Paul J. Crutzen & Michael Oppenheimer Received: 12 January 2007 Mainz, Germany M. Oppenheimer (*) Department of Geosciences, Princeton University, Princeton, NJ 08544, USA e-mail: omichael@princeton.edu M. Oppenheimer Woodrow Wilson School of Public and International

Oppenheimer, Michael

185

The Exposure-Response Curve for Ozone and Risk of Mortality and the Adequacy of Current Ozone  

E-Print Network [OSTI]

and applied several statistical models to data on air pollution, weather, and mortality for 98 U.S. urban mortality. Interventions to further reduce ozone pollution would benefit public health, even in regions pollutant linked to numerous harmful health effects, including reduced lung function, increased frequency

Dominici, Francesca

186

Breakthrough: Lead-free Solder  

ScienceCinema (OSTI)

Ames Laboratory senior metallurgist Iver Anderson explains the importance of lead-free solder in taking hazardous lead out of the environment by eliminating it from discarded computers and electronics that wind up in landfills. Anderson led a team that developed a tin-silver-copper replacement for traditional lead-tin solder that has been adopted by more than 50 companies worldwide.

Anderson, Iver

2013-03-01T23:59:59.000Z

187

Breakthrough: Lead-free Solder  

SciTech Connect (OSTI)

Ames Laboratory senior metallurgist Iver Anderson explains the importance of lead-free solder in taking hazardous lead out of the environment by eliminating it from discarded computers and electronics that wind up in landfills. Anderson led a team that developed a tin-silver-copper replacement for traditional lead-tin solder that has been adopted by more than 50 companies worldwide.

Anderson, Iver

2012-01-01T23:59:59.000Z

188

Carbon monoxide in the solar atmosphere I. Numerical method and two-dimensional models  

E-Print Network [OSTI]

The radiation hydrodynamic code CO5BOLD has been supplemented with the time-dependent treatment of chemical reaction networks. Advection of particle densities due to the hydrodynamic flow field is also included. The radiative transfer is treated frequency-independently, i.e. grey, so far. The upgraded code has been applied to two-dimensional simulations of carbon monoxide (CO) in the non-magnetic solar photosphere and low chromosphere. For this purpose a reaction network has been constructed, taking into account the reactions which are most important for the formation and dissociation of CO under the physical conditions of the solar atmosphere. The network has been strongly reduced to 27 reactions, involving the chemical species H, H2, C, O, CO, CH, OH, and a representative metal. The resulting CO number density is highest in the cool regions of the reversed granulation pattern at mid-photospheric heights and decreases strongly above. There, the CO abundance stays close to a value of 8.3 on the usual logarithmic abundance scale with [H]=12 but is reduced in hot shock waves which are a ubiquitous phenomenon of the model atmosphere. For comparison, the corresponding equilibrium densities have been calculated, based on the reaction network but also under assumption of instantaneous chemical equilibrium by applying the Rybicki & Hummer (RH) code by Uitenbroek (2001). Owing to the short chemical timescales, the assumption holds for a large fraction of the atmosphere, in particular the photosphere. In contrast, the CO number density deviates strongly from the corresponding equilibrium value in the vicinity of chromospheric shock waves. Simulations with altered reaction network clearly show that the formation channel via hydroxide (OH) is the most important one under the conditions of the solar atmosphere.

S. Wedemeyer-Boehm; I. Kamp; J. Bruls; B. Freytag

2005-03-23T23:59:59.000Z

189

Primary lead smelter, Doe Run, Herculaneum, Missouri: Volume 3 -- Appendix B.2 through Appendix F. Final report  

SciTech Connect (OSTI)

The United States Environmental Protection Agency`s (EPA) Emission Standards Division (ESD) is investigating the primary lead smelting source category to identify and quantify organic hazardous air pollutants (HAPs) emitted from blast furnaces. The primary objective was to obtain data on the emissions of volatile and semi-volatile organic HAPs, aldehydes, and ketones from primary lead smelter blast furnaces. A secondary objective was to obtain data on the emission of carbon monoxide. The data will be used by ESD to determine whether organic HAPs are emitted at levels that would justify regulation under the Maximum Achievable Control Technology (MACT) program. The Doe Run Company, which operates a primary lead smelter in Herculaneum, Missouri was selected by the ESD as the host facility for this project. This volume consists of Appendices B.2 through F.

NONE

1999-08-01T23:59:59.000Z

190

Decontaminating lead bricks and shielding  

SciTech Connect (OSTI)

Lead used for shielding is often surface contaminated with radioisotopes and is therefore a RCRA D008 mixed waste. The technology-based standard for treatment is macroencapsulation. However, decontaminating and recycling the clean lead is a more attractive solution. Los Alamos National Laboratory decontaminates material and equipment contaminated with radioisotopes. Decontaminating lead poses special problems because of the RCRA hazard classification and the size of the inventory, now about 50 tons and likely to grow substantially of planned decommissioning operations. Thus lead, in the form of bricks and other shield shapes, is surface contaminated with fission products. One of the best methods for contaminated lead is removing the superficial layer of contamination with an abrasive medium under pressure. For lead, a mixture of alumina with water and air at about 40 psig rapidly and effectively decontaminates the lead. The abrasive medium is sprayed onto the lead in a scaled-off area. The slurry of abrasive and particles of lead falls through a floor and is collected in a sump. A pump sends the slurry mixture back to the spray gun, creating a continuous process. The process generates small volumes of lead slurry that can be solidified and, because it passes the TCLP, is not a mixed waste. The decontaminated lead can be released for recycling.

Lussiez, G.

1994-02-01T23:59:59.000Z

191

Decontaminating lead bricks and shielding  

SciTech Connect (OSTI)

Lead used for shielding is often surface contaminated with radioisotopes and is therefore a RCRA D008 mixed waste. The technology-based standard for treatment is macroencapsulation. However, decontaminating and recycling the clean lead is a more attractive solution. Los Alamos National Laboratory decontaminates material and equipment contaminated with radioisotopes. Decontaminating lead poses special problems because of the RCRA hazard classification and the size of the inventory, now about 50 tons and likely to grow substantially because of planned decommissioning operations. This lead, in the form of bricks and other shield shapes, is surface contaminated with fission products. One of the best methods for decontaminating lead is removing the thin superficial layer of contamination with an abrasive medium trader pressure. For lead, a mixture of alumina with water and air at about 40 psig rapidly and effectively decontaminates the lead. The abrasive medium is sprayed onto the lead in a sealed-off area. The slurry of abrasive and particles of lead falls through a floor grating and is collected in a sump. A pump sends the slurry mixture back to the spray gun, creating a continuous process. The process generates small volumes of contaminated lead slurry that can be solidified and, because it passes the TCLP, is not a mixed waste. The decontaminated lead can be released for recycling.

Lussiez, G.W.

1993-05-01T23:59:59.000Z

192

Decontaminating lead bricks and shielding  

SciTech Connect (OSTI)

Lead used for shielding is often surface contaminated with radioisotopes and is therefore a RCRA D008 mixed waste. The technology-based standard for treatment is macroencapsulation. However, decontaminating and recycling the clean lead is a more attractive solution. Los Alamos National Laboratory decontaminates material and equipment contaminated with radioisotopes. Decontaminating lead poses special problems because of the RCRA hazard classification and the size of the inventory, now about 50 tons and likely to grow substantially because of planned decommissioning operations. This lead, in the form of bricks and other shield shapes, is surface contaminated with fission products. One of the best methods for decontaminating lead is removing the thin superficial layer of contamination with an abrasive medium trader pressure. For lead, a mixture of alumina with water and air at about 40 psig rapidly and effectively decontaminates the lead. The abrasive medium is sprayed onto the lead in a sealed-off area. The slurry of abrasive and particles of lead falls through a floor grating and is collected in a sump. A pump sends the slurry mixture back to the spray gun, creating a continuous process. The process generates small volumes of contaminated lead slurry that can be solidified and, because it passes the TCLP, is not a mixed waste. The decontaminated lead can be released for recycling.

Lussiez, G.W.

1993-01-01T23:59:59.000Z

193

Kinetics of the Reduction of Wüstite by Hydrogen and Carbon Monoxide for the Chemical Looping Production of Hydrogen  

E-Print Network [OSTI]

produced could be stored, e.g. by geological sequestration, making the overall process “carbon-neutral”, or “carbon-negative” when biomass is used as fuel. In addition, the hydrogen produced during the oxidation of FexO and metallic Fe in steam can be kept... Kinetics of the reduction of wüstite by hydrogen and carbon monoxide for the chemical looping production of hydrogen Wen Liu a,n, Jin Yang Lim b, Marco A. Saucedo a, Allan N. Hayhurst b, Stuart A. Scott a, J.S. Dennis b a Department of Engineering...

Liu, Wen; Lim, Jin Yang; Saucedo, Marco A.; Hayhurst, Allan N.; Scott, Stuart A.; Dennis, J. S.

2014-08-13T23:59:59.000Z

194

Scale-Up and Demonstration of Fly Ash Ozonation Technology  

SciTech Connect (OSTI)

The disposal of fly ash from the combustion of coal has become increasingly important. When the fly ash does not meet the required specification for the product or market intended, it is necessary to beneficiate it to achieve the desired quality. This project, conducted at PPL's Montour SES, is the first near full-scale ({approx}10 ton/day), demonstration of ash ozonation technology. Bituminous and sub bituminous ashes, including two ash samples that contained activated carbon, were treated during the project. Results from the tests were very promising. The ashes were successfully treated with ozone, yielding concrete-suitable ash quality. Preliminary process cost estimates indicate that capital and operating costs to treat unburned carbon are competitive with other commercial ash beneficiation technologies at a fraction of the cost of lost sales and/or ash disposal costs. This is the final technical report under DOE Cooperative Agreement No.: DE-FC26-03NT41730.

Rui Afonso; R. Hurt; I. Kulaots

2006-03-01T23:59:59.000Z

195

CF[sub 3] chemistry: Potential implications for stratospheric ozone  

SciTech Connect (OSTI)

The authors address questions about the chemistry of CF[sub 3] bearing compounds in the atmosphere, and the impact that the existence of and reaction rate constants for such species may have on stratospheric ozone. Species considered include CF[sub 3], CF[sub 3]O, CF[sub 3]O[sub 2], CF[sub 3]OH, CF[sub 3]OOH, CF[sub 3]ONO[sub 2], CF[sub 3]O[sub 2]NO[sub 2], and CF[sub 3]OOCl. Based on their calculational results, the authors suggest a number of experimental measurements which should substantially decrease uncertainties associated with the role of CF[sub 3] species in atmospheric chemistry related to ozone.

Ko, M.K.W.; Sze, N.D.; Rodriguez, J.M.; Weistenstein, D.K.; Heisey, C.W. (Atmospheric and Environmental Research, Inc., Cambridge, MA (United States)); Wayne, R.P.; Biggs, P.; Canosa-Mas, C.E. (Univ. of Oxford, Oxford (United Kingdom)); Sidebottom, H.W.; Treacy, J. (Univ. College, Dublin (Ireland))

1994-01-15T23:59:59.000Z

196

FORMATION OF MOLECULAR OXYGEN AND OZONE ON AMORPHOUS SILICATES  

SciTech Connect (OSTI)

Oxygen in the interstellar medium is seen in the gas phase, in ices (incorporated in H{sub 2}O, CO, and CO{sub 2}), and in grains such as (Mg{sub x} Fe{sub 1-x} )SiO{sub 3} or (Mg{sub x} Fe{sub 1-x} ){sub 2}SiO{sub 4}, 0 < x < 1. In this investigation, we study the diffusion of oxygen atoms and the formation of oxygen molecules and ozone on the surface of an amorphous silicate film. We find that ozone is formed at low temperature (<30 K), and molecular oxygen forms when the diffusion of oxygen atoms becomes significant, at around 60 K. This experiment, besides being the first determination of the diffusion energy barrier (1785 {+-} 35 K) for oxygen atoms on a silicate surface, suggests bare silicates as a possible storage place for oxygen atoms in low-A{sub v} environments.

Jing Dapeng; He Jiao; Vidali, Gianfranco [Physics Department, Syracuse University, Syracuse, NY 13244 (United States); Brucato, John Robert; Tozzetti, Lorenzo [Osservatorio Astrofisico di Arcetri, INAF, I-50125 Florence (Italy); De Sio, Antonio [Department of Physics and Astronomy, University of Florence, I-50125 Florence (Italy)

2012-09-01T23:59:59.000Z

197

Meeting the New Ozone Standard: Challenges and Opportunities  

Broader source: Energy.gov [DOE]

This presentation by Anna Garcia, executive director of the Ozone Transport Commission, was part of the July 2008 Webcast sponsored by the U.S. Department of Energy Office of Energy Efficiency and Renewable Energy Weatherization and Intergovernmental Program Clean Energy and Air Quality Integration Initiative that was titled Role of Energy Efficiency and Renewable Energy in Improving Air Quality and Addressing Greenhouse Gas Reduction Goals on High Electric Demand Days.

198

High temperature superconductor current leads  

DOE Patents [OSTI]

An electrical lead is disclosed having one end for connection to an apparatus in a cryogenic environment and the other end for connection to an apparatus outside the cryogenic environment. The electrical lead includes a high temperature superconductor wire and an electrically conductive material distributed therein, where the conductive material is present at the one end of the lead at a concentration in the range of from 0 to about 3% by volume, and at the other end of the lead at a concentration of less than about 20% by volume. Various embodiments are shown for groups of high temperature superconductor wires and sheaths. 9 figs.

Hull, J.R.; Poeppel, R.B.

1995-06-20T23:59:59.000Z

199

E-Print Network 3.0 - arctic ozone loss Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Chemistry Summary: stratospheric ozone losses during cold Arctic Januaries, M. Rex, R. J. Salaw- itch, M. L. Santee, J. W. Waters... , and UARS MLS to demonstrate that the...

200

E-Print Network 3.0 - atmospheric ozone depletion Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

78992007 Summary: ozone depletion based on sequential assimilation of satellite data from the ENVISATMIPAS and Odin... 2007 Abstract. The objective of this study...

Note: This page contains sample records for the topic "monoxide ozone lead" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

E-Print Network 3.0 - ambient ozone exposure Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Materials Science ; Energy Storage, Conversion and Utilization 12 Proceedings of Healthy Buildings 2009 Paper 141 Removal of Indoor Ozone with Reactive Materials: Preliminary...

202

E-Print Network 3.0 - atmospheric ozone increases Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Collection: Environmental Sciences and Ecology ; Geosciences 78 Proceedings of Healthy Buildings 2009 Paper 336 Time-Scale Analysis for Reactive Deposition of Ozone via Passive...

203

E-Print Network 3.0 - ameliorate ozone effects Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: students confuse the relationship between the ozone hole and the greenhouse effect, thus confusing... , and to suggest more effective teaching methods. 2....

204

E-Print Network 3.0 - analyzing ground ozone Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

are analyzed... to superposition of the "natural" pro- cesses. Comparison of the total ozone ... Source: Ecole Polytechnique, Centre de mathmatiques Collection:...

205

LEADING ADULT SQUAWFISH (Ptychocheilus oregonensis)  

E-Print Network [OSTI]

of Federal, State or cooperating agencies and in processed form for economy and to avoid delay in publicationLEADING ADULT SQUAWFISH (Ptychocheilus oregonensis) WITHIN AN ELECTRIC FIELD Marine Biological, Arnie J. Suomela, Commissioner LEADING ADULT SQUAWFISH ( PTYCHOCHEILUS OREGONENSIS ) WITHIN AN ELECTRIC

206

Lead reduction in ambient air  

SciTech Connect (OSTI)

The Bureau of Mines evaluated the emission control methods, including the capital investments and operating cost, necessary for further reducing lead levels in ambient air at the Glover, Herculaneum, and Buick smelter-refineries in Missouri and the East Helena, MT, smelter. This report presents theoretically achievable lead emission reductions and estimated capital and operating costs.

Smith, R.D.; Kiehn, O.A.; Wilburn, D.R.; Bowyer, R.C.

1987-01-01T23:59:59.000Z

207

Plasma Chemistry and Plasma Processing, Vol. 22, No. 4, December 2002 ( 2002) Ozone Production in the Positive DC Corona  

E-Print Network [OSTI]

Plasma Chemistry and Plasma Processing, Vol. 22, No. 4, December 2002 ( 2002) Ozone Production the distribution of ozone, but does not affect the rate of production. KEY WORDS: Corona discharge; corona plasma

Chen, Junhong

208

Electrochemical behavior of lead telluride  

SciTech Connect (OSTI)

The electrochemical behavior of lead telluride was studied in acidic, neutral, and alkaline solutions. It was shown that in the case of anodic polarization in 1 M NaOH the PbTe surface composition is nearly stoichiometric. During cathodic polarization in 1 M NaOH and during anodic polarization in 1 M HCl the surface layer is lead-rich. In the case of anodic polarization in 1 M HCl the surface is tellurium-rich. Cathodic polarization in 1 M NaCl leads to tellurium depletion of the surface layer. Reaction equations describing the electrochemical processes at the PbTe electrode are reported.

Danilova, M.G.; Sveshnikova, L.L.; Repinskii, S.M.

1987-07-01T23:59:59.000Z

209

Ground-based zenith sky abundances and in situ gas cross sections for ozone and nitrogen dioxide  

E-Print Network [OSTI]

Ground-based zenith sky abundances and in situ gas cross sections for ozone and nitrogen dioxide, in situ ambient absorption gas cell mea- surements for ozone and nitrogen dioxide, and ground-based zenith for ozone and nitrogen dioxide that are retrieved from measured spectra of the zenith sky

Dirksen, Ruud

210

Ensemble forecasting with machine learning algorithms for ozone, nitrogen dioxide and PM10 on the Prev'Air  

E-Print Network [OSTI]

Ensemble forecasting with machine learning algorithms for ozone, nitrogen dioxide and PM10'Air operational platform. This platform aims at forecasting maps, on a daily basis, for ozone, nitrogen dioxide models, ozone, nitrogen dioxide, particulate matter, threshold exceedance 1. Introduction1 Operational

Mallet, Vivien

211

Experimental study of reactions between ozone and building products M. Nicolas, O. Ramalho, F. Maupetit*  

E-Print Network [OSTI]

ozone and building products and document their potential impact on indoor air quality. PreliminaryExperimental study of reactions between ozone and building products M. Nicolas, O. Ramalho, F experiments were conducted on four building products: two carpets, a gypsum board and a pine wood board

Paris-Sud XI, Université de

212

Validation of Ozone Monitoring Instrument nitrogen dioxide columns E. A. Celarier,1  

E-Print Network [OSTI]

Validation of Ozone Monitoring Instrument nitrogen dioxide columns E. A. Celarier,1 E. J. Brinksma the standard nitrogen dioxide (NO2) data product (Version 1.0.), which is based on measurements made), Validation of Ozone Monitoring Instrument nitrogen dioxide columns, J. Geophys. Res., 113, D15S15, doi:10

213

Ground-level nitrogen dioxide concentrations inferred from the satellite-borne Ozone Monitoring Instrument  

E-Print Network [OSTI]

Ground-level nitrogen dioxide concentrations inferred from the satellite-borne Ozone Monitoring; published 28 August 2008. [1] We present an approach to infer ground-level nitrogen dioxide (NO2), Ground-level nitrogen dioxide concentrations inferred from the satellite-borne Ozone Monitoring

Martin, Randall

214

Satellite observations of ozone and nitrogen dioxide: from retrievals to emission estimates  

E-Print Network [OSTI]

Summary Satellite observations of ozone and nitrogen dioxide: from retrievals to emission estimates be inferred for important trace gases such as ozone (O3) and nitrogen dioxide (NO2). Chemical transport models.11 to 3.79. Total nitrogen dioxide columns can be retrieved from space in the 405­465 nm window

Haak, Hein

215

Tropospheric ozone trends at Mauna Loa Observatory tied to decadal climate variability  

E-Print Network [OSTI]

measurements at Mauna Loa Observatory in Hawaii reveal little change in tropospheric ozone levels during spring a suite of chemistry­climate model simulations. We show that the flow of ozone-rich air from Eurasia towards Hawaii during spring weakened in the 2000s as a result of La-Niña-like decadal cooling

216

PPPL-3281, Preprint: January 1998, UC-426 Synthesis of Ozone at Atmospheric Pressure  

E-Print Network [OSTI]

to ~250 ppm were produced using a thermal plasma reactor system based on an ICP torch operating at 2.5 MHz by rapid mixing of molecular oxygen with atomic oxygen produced by the torch. The ozone concentration in industrial processes is increasing. Applications for ozone include treatment of waste water, water

217

Separating the dynamical effects of climate change and ozone depletion. Part  

E-Print Network [OSTI]

) fixed at 1960 levels and ozone depleting substances (ODSs) varying in time, 2) ODSs fixed at 1960 levels averaged wave drag in SH spring and summer, as well as for final warming dates. Ozone depletion a significant impact on the stratosphere on both a global and a regional scale. Over the past three decades

Wirosoetisno, Djoko

218

Chapter Descriptions, Parties Request, and Timetable 2010 WMO/UNEP Ozone Assessment  

E-Print Network [OSTI]

AND SURFACE ULTRAVIOLET RADIATION CHAPTER 3: FUTURE OZONE AND ITS IMPACT ON SURFACE UV CHAPTER 4) of this 2010 ozone assessment. It provides updated information on degradation products which could have of understanding on ODS degradation products in the stratosphere (e.g., HCl, HF, BrO, CF2O), examines how

Jánosi, Imre M.

219

The Role of Material Porosity on Ozone Uptake for Metakaolin-Concrete Surfaces  

E-Print Network [OSTI]

to a diminished environmental impact, clay may cause increased removal of ozone, an important indoor pollutant velocity, Heterogeneous Chemistry, Construction Materials 1 Introduction Metakaolin-cement systems hold ozone uptake. Cement is an essential component in the building industry used in formulating concrete

Siegel, Jeffrey

220

Simultaneous retrievals of column ozone and aerosol optical properties from direct and diffuse solar irradiance measurements  

E-Print Network [OSTI]

of column ozone and aerosol optical properties from direct and diffuse solar irradiance measurements, JSimultaneous retrievals of column ozone and aerosol optical properties from direct and diffuse solar irradiance measurements Christian D. Goering,1 Tristan S. L'Ecuyer,1 Graeme L. Stephens,1 James R

Stephens, Graeme L.

Note: This page contains sample records for the topic "monoxide ozone lead" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Effects of Sodium Chloride Particles, Ozone, UV, and Relative Humidity on Atmospheric Corrosion of Silver  

E-Print Network [OSTI]

Effects of Sodium Chloride Particles, Ozone, UV, and Relative Humidity on Atmospheric Corrosion The corrosion of Ag contaminated with NaCl particles in gaseous environments containing humidity and ozone analyzed using a coulometric reduction technique. The atmospheric corrosion of Ag was greatly accelerated

222

Air Pollution Physics and Chemistry EAS 6790 Home Work Assignment Ozone Chemistry 2  

E-Print Network [OSTI]

1 Air Pollution Physics and Chemistry EAS 6790 Fall 2010 Home Work Assignment Ozone Chemistry 2 and Chemistry EAS 6790 Fall 2006 Home Work Assignment No. 4, Ozone Chemistry Problems 11.8 and 11.9 (sub-part 1 and 2 only). Daniel Jacob, Atmospheric Chemistry #12;2 Problem 2: 2 2. Consider an air parcel ventilated

Weber, Rodney

223

Can ozone depletion and global warming interact to produce rapid climate change?  

E-Print Network [OSTI]

Can ozone depletion and global warming interact to produce rapid climate change? Dennis L. Hartmann of Climate Change (IPCC) assess- ment of the status of global warming, which reported that winter stratospheric ozone depletion and greenhouse warming are possible. These interactions may be responsible

Limpasuvan, Varavut

224

NORTHEASTERN NATURALIST2009 16(2):307313 Variation in Ozone Sensitivity Within Indian Hemp and  

E-Print Network [OSTI]

NORTHEASTERN NATURALIST2009 16(2):307­313 Variation in Ozone Sensitivity Within Indian Hemp , and Dennis R. Decoteau1 Abstract - Sixteen selections of Apocynum cannabinum (Indian Hemp) and nine, adaxial stipple, similar to symptoms ascribed to ambient ozone in the field. Indian Hemp was more

Decoteau, Dennis R.

225

Surface ozone background in the United States: Canadian and Mexican pollution influences  

E-Print Network [OSTI]

of anthropogenic emissions from Canada, Mexico, and outside North America on daily maximum 8-hour average ozone Surface ozone Air quality standard Chemical transport model Global model a b s t r a c t We use a global chemical transport model (GEOS-Chem) with 1 Ã? 1 horizontal resolution to quantify the effects

Park, Rokjin

226

Stratospheric ozone depletion: a key driver of recent precipitation trends in South Eastern South America  

E-Print Network [OSTI]

. In this paper we focus on South Eastern South America (SESA), a region that has exhibited one of the largest South America 1 Introduction The depletion of ozone in the polar Antarctic strato- sphere (i.e. `theStratospheric ozone depletion: a key driver of recent precipitation trends in South Eastern South

227

Tropospheric ozone climatology over Irene, South Africa, from 1990 to 1994 and 1998 to 2002  

E-Print Network [OSTI]

Tropospheric ozone climatology over Irene, South Africa, from 1990 to 1994 and 1998 to 2002 R. D in South Africa are reported for the period 1990 to 1994 and a more recent period, 1998 to 2002, when), Tropospheric ozone climatology over Irene, South Africa, from 1990 to 1994 and 1998 to 2002, J. Geophys. Res

Thompson, Anne

228

Passive Ozone Control Through Use of Reactive Indoor Wall and Ceiling Materials  

E-Print Network [OSTI]

Passive Ozone Control Through Use of Reactive Indoor Wall and Ceiling Materials Paper # 715 Donna A and unpainted drywall as passive ozone control surfaces in a room-sized laboratory chamber. Mean deposition-50%, resulted in increased reactivity for activated carbon. In our model for a typical house, about 35

Siegel, Jeffrey

229

Process for the production of hydrogen and carbonyl sulfide from hydrogen sulfide and carbon monoxide using a metal boride, nitride, carbide and/or silicide catalyst  

SciTech Connect (OSTI)

Hydrogen and carbonyl sulfide are produced by a process comprising contacting gaseous hydrogen sulfide with gaseous carbon monoxide in the presence of a metal boride, carbide, nitride and/or silicide catalyst, such as titanium carbide, vanadium boride, manganese nitride or molybdenum silicide.

McGuiggan, M.F.; Kuch, P.L.

1984-05-08T23:59:59.000Z

230

J. Phys. Chem. 1994, 98, 11213-11219 11213 Vibrational Dynamics of Carbon Monoxide at the Active Site of Myoglobin: Picosecond  

E-Print Network [OSTI]

J. Phys. Chem. 1994, 98, 11213-11219 11213 Vibrational Dynamics of Carbon Monoxide at the Active Physics Laboratory, Stanford University, Stanford, Califomia 94305 Received: April 27, 1994: In Final Form at Urbana-Champaign. Deparlment of Chemistry, Sfanford University. Hansen ExperimentaJ Physics Laboratory

Fayer, Michael D.

231

Interaction of copper oxides with reaction medium in heterogeneous catalytic oxidation of carbon monoxide by molecular oxygen. IV. IR spectroscopic study of carbon monoxide interaction with copper oxide surface  

SciTech Connect (OSTI)

An IR spectroscopic study has been made of the interaction of CO with CuO prepared in different ways, and the interaction of O/sub 2/ with carbon monoxide preadsorbed on CuO. A number of Cu/sup +/CO surface complexes have been detected (2114-2148 cm/sup -1/) with a heat of adsorption about 79.5-180 kJ/mole. From an analysis of the nature of these complexes, we have evaluated the processes taking place on the CuO surface when it interacts with CO and have compared the properties of massive CuO with those of CuO on oxide supports. The data are interpreted on the assumption that extended defects - dislocations - exist and play an important role, determining to a considerable degree the properties of the massive CuO in the reaction of CO oxidation.

Lokhov, Y.A.; Popovskii, V.V.; Sadykov, V.A.; Tikhov, S.F.

1985-08-01T23:59:59.000Z

232

WearAir: Expressive T-shirts for Air Quality Sensing Sunyoung Kim and Eric Paulos  

E-Print Network [OSTI]

are less proactively concerned with air quality. AIR POLLUTANT: VOLATILE ORGANIC COMPOUNDS Different types of air pollutants contribute to air quality in different locations: Ozone, CO, NOx and VOCs are major contributors to outdoor air pollution; and particulate matters, VOCs, carbon monoxide and lead are common air

Mankoff, Jennifer

233

Resilience of gas-phase anharmonicity in the vibrational response of adsorbed carbon monoxide and breakdown under electrical conditions  

E-Print Network [OSTI]

In surface catalysis, the adsorption of carbon monoxide on transition-metal electrodes represents the prototype of strong chemisorption. Notwithstanding significant changes in the molecular orbitals of adsorbed CO, spectroscopic experiments highlight a close correlation between the adsorbate stretching frequency and equilibrium bond length for a wide range of adsorption geometries and substrate compositions. In this work, we study the origins of this correlation, commonly known as Badger's rule, by deconvoluting and examining contributions from the adsorption environment to the intramolecular potential using first-principles calculations. Noting that intramolecular anharmonicity is preserved upon CO chemisorption, we show that Badger's rule for adsorbed CO can be expressed solely in terms of the tabulated Herzberg spectroscopic constants of isolated CO. Moreover, although it had been previously established using finite-cluster models that Badger's rule is not affected by electrical conditions, we find here th...

Dabo, Ismaila

2012-01-01T23:59:59.000Z

234

Adsorbate effects on a mixed-valence compound: Carbon monoxide chemisorption on CeIr/sub 2/  

SciTech Connect (OSTI)

We have studied the effects of stoichiometry change and CO chemisorption on the surface electronic structure of the mixed-valence compound CeIr/sub 2/. We show that the surface iridium to cerium ratio can be varied by changing sample temperature while sputtering. Carbon monoxide is found to adsorb 80% molecularly on the surface and cause a mild surface oxidation which induces a shift of electron density into available cerium f orbitals. Peaks due to the 4sigma, 1..pi.., and 5sigma CO molecular orbitals appear at different binding energies than those due to molecular CO on the pure iridium surface. This binding-energy shift as well as the high percentage of molecular CO on the surface (CO adsorption on pure cerium is completely dissociative) points toward a surface which has lost much of the elemental character of its two constituents upon compound formation.

Lindquist, J.M.; Hemminger, J.C.; Lawrence, J.

1987-10-15T23:59:59.000Z

235

Auger electron spectroscopy, electron loss spectroscopy and low energy electron diffraction of oxygen and carbon monoxide adsorption of Pd films  

SciTech Connect (OSTI)

The adsorption of oxygen and carbon monoxide at room temperature on polycrystalline and (111) monocrystalline thin films of Pd vapor deposited on mice was investigated by AES, ELS, and LEED. The results show that adsorbate coverage depends strongly on surface microstructure, composition, and topography. Polycrystalline or Cl contaminated surfaces adsorb large amounts of the gases, while flat, monocrystalline surfaces will adsorb almost none. These results are quite different from those observed earlier using sputter etched and annealed bulk single cyrstals where adsorbate superlattices formed after rather low gaseous exposures. In the present work no superlattices were observed after exposures ranging up to several thousand langmuirs. The contradictory results obtained in the two cases are attributed to probable differences in surface microtopography and microstructure.

Vook, R.W.; De Cooman, B.C.; Vankar, V.D.

1983-01-01T23:59:59.000Z

236

Remarkable catalytic activity of cobalt tetraphenylporphyrin modified on a titania for the oxidation of carbon monoxide below room temperature  

SciTech Connect (OSTI)

CoTPP on TiO/sub 2/-120s modified at 250 /sup 0/C under vacuum catalytically oxidized carbon monoxide rapidly with oxygen even at -79/sup 0/C. Its catalytic activity was incomparably higher than that of commercial Hopcalite. Comparison of its catalytic performance with those of the same catalyst or different TiO/sub 2/ supporting catalyst both evacuated at 200 /sup 0/C revealed unique features of the present catalyst in terms of its oxygen adsorption, the poisoning of adsorbed oxygen, and the insolubility of the complex in benzene. Both significant structural modification of the complex and its strong interaction with properly dehydrated TiO/sub 2/-120s brought about by evacuation at 250 /sup 0/C may induce such extraordinary activity. 14 references, 4 figures, 5 tables.

Mochida, I.; Iwai, Y.; Kamo, T.; Fujitsu, H.

1985-12-05T23:59:59.000Z

237

Adsorbate effects on a mixed-valence compound: carbon monoxide chemisorption on CeIr/sub 2/  

SciTech Connect (OSTI)

The authors studied the effects of stoichiometry change and CO chemisorption on the surface electronic structure of the mixed-valence compound CeIr/sub 2/. It is shown that the surface iridium to cerium ratio can be varied by changing sample temperature while sputtering. Carbon monoxide is found to adsorb 80% molecularly on the surface and cause a mild surface oxidation which induces a shift of electron density into available cerium f orbitals. Peaks due to the 4 sigma, 1 pi, and 5 sigma CO molecular orbitals appear at different binding energies than those due to molecular CO on the pure iridium surface. This binding-energy shift as well as the high percentage of molecular CO on the surface (CO adsorption on pure cerium is completely dissociative) points toward a surface which has lost much of the elemental character of its two constituents upon compound formation.

Lindquist, J.M.; Hemminger, J.C.

1987-10-15T23:59:59.000Z

238

INFLUENCE OF ELEVATED OZONE AND CARBON DIOXIDE ON INSECT DENSITIES.  

SciTech Connect (OSTI)

The combustion of fossil fuels is profoundly altering the chemical composition of the atmosphere. Beginning with the Industrial Revolution, the concentration of carbon dioxide in the atmosphere has increased from approximately 280 to 370 {micro}l l{sup -1} in 2004, and it is expected to exceed 550 {micro}l l{sup -1} by 2050. Tropospheric ozone has risen even more rapidly than CO{sub 2} and average summer concentrations in the Northern Hemisphere are expected to continue to increase by 0.5-2.5% per year over the next 30 years. Although elevated CO{sub 2} stimulates photosynthesis and productivity of terrestrial ecosystems, ozone (O{sub 3}) is deleterious. In addition to directly affecting the physiology and productivity of crops, increased concentrations of tropospheric CO{sub 2} and O{sub 3} are predicted to lower the nutritional quality of leaves, which has the potential to increase herbivory as insects eat more to meet their nutritional demands. We tested the hypothesis that changes in tropospheric chemistry affect the relationship between plants and insect herbivores by changing leaf quality. The susceptibility to herbivory of soybean grown in elevated CO{sub 2} or O{sub 3} was examined using free air gas concentration enrichment (SoyFACE). FACE technology has the advantage that plants are cultivated under realistic field conditions with no unwanted alteration of microclimate or artificial constraints on the insect community.

DELUCIA, E.; DERMODY, O.; O'NEILL, B.; ALDEA, M.; HAMILTON, J.; ZANGERL, A.; ROGER, A.; BERENBAUM, M.

2005-01-05T23:59:59.000Z

239

NATIONAL LEAD COMPANY OF OHIO  

Office of Legacy Management (LM)

t-t AL- 1. + T fi r,y* t ,.- . NATIONAL LEAD COMPANY OF OHIO Ofll i iy Ci)wp HEALTH AND SAFETY DIVISION - ANALYTICAL DEPT. ANALYTICAL DATA SHEET U-G b ;33y jl:tL G c-w &3(y I...

240

Soluble Lead Flow Battery: Soluble Lead Flow Battery Technology  

SciTech Connect (OSTI)

GRIDS Project: General Atomics is developing a flow battery technology based on chemistry similar to that used in the traditional lead-acid battery found in nearly every car on the road today. Flow batteries store energy in chemicals that are held in tanks outside the battery. When the energy is needed, the chemicals are pumped through the battery. Using the same basic chemistry as a traditional battery but storing its energy outside of the cell allows for the use of very low cost materials. The goal is to develop a system that is far more durable than today’s lead-acid batteries, can be scaled to deliver megawatts of power, and which lowers the cost of energy storage below $100 per kilowatt hour.

None

2010-09-01T23:59:59.000Z

Note: This page contains sample records for the topic "monoxide ozone lead" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

THE IMPACT OF OZONE ON THE LOWER FLAMMABLE LIMIT OF HYDROGEN IN VESSELS CONTAINING SAVANNAH RIVER SITE HIGH LEVEL WASTE  

SciTech Connect (OSTI)

The Savannah River Site, in conjunction with AREVA Federal services, has designed a process to treat dissolved radioactive waste solids with ozone. It is known that in this radioactive waste process, radionuclides radiolytically break down water into gaseous hydrogen and oxygen, which presents a well defined flammability hazard. Flammability limits have been established for both ozone and hydrogen separately; however, there is little information on mixtures of hydrogen and ozone. Therefore, testing was designed to provide critical flammability information necessary to support safety related considerations for the development of ozone treatment and potential scale-up to the commercial level. Since information was lacking on flammability issues at low levels of hydrogen and ozone, a testing program was developed to focus on filling this portion of the information gap. A 2-L vessel was used to conduct flammability tests at atmospheric pressure and temperature using a fuse wire ignition source at 1 percent ozone intervals spanning from no ozone to the Lower Flammable Limit (LFL) of ozone in the vessel, determined as 8.4%(v/v) ozone. An ozone generator and ozone detector were used to generate and measure the ozone concentration within the vessel in situ, since ozone decomposes rapidly on standing. The lower flammability limit of hydrogen in an ozone-oxygen mixture was found to decrease from the LFL of hydrogen in air, determined as 4.2 % (v/v) in this vessel. From the results of this testing, Savannah River was able to develop safety procedures and operating parameters to effectively minimize the formation of a flammable atmosphere.

Sherburne, Carol [Savannah River Site (SRS), Aiken, SC (United States). Savannah River Remediation, LLC; Osterberg, Paul [Fauske and Associates, LLC, Burr Ridge, IL (United States); Johnson, Tom [Fauske and Associates, LLC, Burr Ridge, IL (United States); Frawely, Thomas [Fauske and Associates, LLC, Burr Ridge, IL (United States)

2013-01-23T23:59:59.000Z

242

Surface modification of nitrogen-doped carbon nanotubes by ozone via atomic layer deposition  

SciTech Connect (OSTI)

The use of ozone as an oxidizing agent for atomic layer deposition (ALD) processes is rapidly growing due to its strong oxidizing capabilities. However, the effect of ozone on nanostructured substrates such as nitrogen-doped multiwalled carbon nanotubes (NCNTs) and pristine multiwalled carbon nanotubes (PCNTs) are not very well understood and may provide an avenue toward functionalizing the carbon nanotube surface prior to deposition. The effects of ALD ozone treatment on NCNTs and PCNTs using 10?wt. % ozone at temperatures of 150, 250, and 300?°C are studied. The effect of ozone pulse time and ALD cycle number on NCNTs and PCNTs was also investigated. Morphological changes to the substrate were observed by scanning electron microscopy and high resolution transmission electron microscopy. Brunauer-Emmett-Teller measurements were also conducted to determine surface area, pore size, and pore size distribution following ozone treatment. The graphitic nature of both NCNTs and PCNTs was determined using Raman analysis while x-ray photoelectron spectroscopy (XPS) was employed to probe the chemical nature of NCNTs. It was found that O{sub 3} attack occurs preferentially to the outermost geometric surface of NCNTs. Our research also revealed that the deleterious effects of ozone are found only on NCNTs while little or no damage occurs on PCNTs. Furthermore, XPS analysis indicated that ALD ozone treatment on NCNTs, at elevated temperatures, results in loss of nitrogen content. Our studies demonstrate that ALD ozone treatment is an effective avenue toward creating low nitrogen content, defect rich substrates for use in electrochemical applications and ALD of various metal/metal oxides.

Lushington, Andrew; Liu, Jian; Tang, Yongji; Li, Ruying; Sun, Xueliang, E-mail: xsun@eng.uwo.ca [Department of Mechanical and Materials Engineering, University of Western Ontario, London, Ontario N6A 5B9 (Canada)

2014-01-15T23:59:59.000Z

243

LEAD PAINT DISCLOSURE Housing built before 1978 may contain lead-based paint. Lead from paint, paint chips, and dust  

E-Print Network [OSTI]

Your Family from Lead In Your Home. All Wesleyan housing was built before 1978 with the exceptionLEAD PAINT DISCLOSURE Housing built before 1978 may contain lead-based paint. Lead from paint, paint chips, and dust can pose health hazards if not taken care of properly. Lead exposure is especially

Royer, Dana

244

The LHC Lead Injector Chain  

E-Print Network [OSTI]

A sizeable part of the LHC physics programme foresees lead-lead collisions with a design luminosity of 1027 cm-2 s-1. This will be achieved after an upgrade of the ion injector chain comprising Linac3, LEIR, PS and SPS machines [1,2]. Each LHC ring will be filled in 10 min by almost 600 bunches, each of 7×107 lead ions. Central to the scheme is the Low Energy Ion Ring (LEIR) [3,4], which transforms long pulses from Linac3 into high-brilliance bunches by means of multi-turn injection, electron cooling and accumulation. Major limitations along the chain, including space charge, intrabeam scattering, vacuum issues and emittance preservation are highlighted. The conversion from LEAR (Low Energy Antiproton Ring) to LEIR involves new magnets and power converters, high-current electron cooling, broadband RF cavities, and a UHV vacuum system with getter (NEG) coatings to achieve a few 10-12 mbar. Major hardware changes in Linac3 and the PS are also covered. An early ion scheme with fewer bunches (but each at nominal...

Beuret, A; Blas, A; Burkhardt, H; Carli, Christian; Chanel, M; Fowler, A; Gourber-Pace, M; Hancock, S; Hourican, M; Hill, C E; Jowett, John M; Kahle, K; Küchler, D; Lombardi, A M; Mahner, E; Manglunki, Django; Martini, M; Maury, S; Pedersen, F; Raich, U; Rossi, C; Royer, J P; Schindl, Karlheinz; Scrivens, R; Sermeus, L; Shaposhnikova, Elena; Tranquille, G; Vretenar, Maurizio; Zickler, T

2004-01-01T23:59:59.000Z

245

Where Is Lead Found? Paint in many homes built before 1978 may contain lead.  

E-Print Network [OSTI]

in lead crystal or lead-glazed pottery may contain lead. Where Is Lead Most Likely to Be a Hazard on toys and furniture -- especially if antique or imported -- may contain lead. · Food or liquids stored

Liskiewicz, Maciej

246

Oxidation of methyl tert-butyl ether (MTBE) and ethyl tert-butyl ether (ETBE) by ozone and combined ozone/hydrogen peroxide  

SciTech Connect (OSTI)

The aim of this work was to study the reaction of ozone and combined ozone/hydrogen peroxide on oxygenated additives such as methyl tert-butyl ether (MTBE) and ethyl tert-butyl ether (ETBE) in dilute aqueous solution using controlled experimental conditions. Experiments conducted in a semi-continuous reactor with MTBE and ETBE in combination (initial concentration: 2 mmol/L of each) showed that ETBE was better eliminated than MTBE with both ozone and combined O[sub 3]/H[sub 2]O[sub 2]. batch experiments led to the determination of the ratio of the kinetic constants for the reaction of OH[degree]-radical with MTBE and ETBE (k[sub OH[degree]/ETBE]/k[sub OH[degree]//MTBE] = 1.7). Tert-butyl formate and tert-butyl acetate were identified as the ozonation byproducts of MTBE an ETBE, respectively, while tert-butyl alcohol was found to be produced during the ozonation of both compounds. 10 refs., 10 figs., 1 tab.

Leitner, N.K.V.; Papailhou, A.L.; Croue, J.P.; Dore, M. (Univ. de Poitiers (France)); Peyrot, J. (British Petroleum, Harfleur (France))

1994-01-01T23:59:59.000Z

247

Scale-Up and Demonstration of Fly Ash Ozonation Technology  

SciTech Connect (OSTI)

This is the fourth quarterly report under DOE Cooperative Agreement No.: DE-FC26-03NT41730. Due a number of circumstances, mostly associated with subcontractor agreements, the actual beginning of the project was delayed from its original award date of March 5, 2003. DOE's Project Manager was kept informed (verbally) by PPL's Project Manager throughout this period. Because of this delay, this is the fourth quarterly report and it refers to the time period from January to March 2004. The on-site deployment and testing of the ozonation system took place during this period. This report summarizes these activities including some preliminary results. No significant issues or concerns are identified.

Larry LaBuz; Rui Afonso

2005-03-31T23:59:59.000Z

248

Three-dimensional simulations of wintertime ozone variability in the lower stratosphere  

SciTech Connect (OSTI)

The evolution of ozone has been calculated for the winters of 1979 and 1989 using winds derived from the authors stratospheric data assimilation system (STRATAN). The ozone fields calculated using this technique are found to compare well with satellite-measured fields for simulations of 2-3 months. Here the authors present comparisons of model fields with both satellite and sonde measurements to verify that stratospheric transport processes are properly represented by this modeling technique. Attention is focussed on the northern hemisphere middle and high latitudes at the 10-hPa level and below, where transport processes are most important to the ozone distribution. First-order quantities and derived budgets from both the model and satellite data are presented. By sampling the model with a limb-viewing satellite and then Kalman filtering the observations of the model, it is shown that transient subplanetary-scale features that are essential to the ozone budget are missed by the satellite system.

Rood, R.B.; Douglass, A.R.; Kaye, J.A. (NASA Goddard Space Flight Center, Greenbelt, MD (USA)); Geller, M.A.; Yuechen, Chi (State Univ. of New York, Stony Brook (USA)); Allen, D.J.; Larson, E.M.; Nash, E.R.; Nielsen, J.E. (Applied Research Corp., Landover, MD (USA))

1991-03-20T23:59:59.000Z

249

The effect of variability in industrial emissions on ozone formation in Houston, Texas  

E-Print Network [OSTI]

Ambient observations have indicated that high concentrations of ozone observed in the Houston/Galveston area are associated with plumes of highly reactive hydrocarbons, mixed with NOx, from industrial facilities. Ambient ...

Webster, Mort David

2007-01-01T23:59:59.000Z

250

Climatology and Trends in the Forcing of the Stratospheric Ozone Transport  

E-Print Network [OSTI]

A thorough analysis of the ozone transport was carried out using the Transformed-Mean Eulerian (TEM) tracer transport equation and the European Centre for Medium-Range Weather Forecasts (ECMWF) Re- Analysis (ERA-40). In ...

Monier, Erwan

251

A Spatial Econometric Approach to Measuring Pollution Externalities: An Application to Ozone Smog  

E-Print Network [OSTI]

A Spatial Econometric Approach to Measuring Pollution Externalities: An Application to Ozone Smog C.-Y. Cynthia Lin University of California at Davis ­ USA Abstract. This paper uses spatial econometrics

Lin, C.-Y. Cynthia

252

Evaluation of a novel ozone generation technique for disinfection of poultry hatchers and processed broiler carcasses  

E-Print Network [OSTI]

When comparing electrochemically generated ozone(03)(2.94.2 wt % inside the (hatcher) and formaldehyde (16 n-A formalin + 7.5 g potassium pertnanganate) for disinfection of Salmonella enteiltidis (SE) contaminated agar plates and typical hatchery...

Ramirez, Gerardo Arturo

1994-01-01T23:59:59.000Z

253

Climatology and trends in the forcing of the stratospheric ozone transport  

E-Print Network [OSTI]

A thorough analysis of the ozone transport was carried out using the Transformed-Mean Eulerian (TEM) tracer continuity equation and the European Centre for Medium-Range Weather Forecasts (ECMWF) Re-Analysis (ERA-40). In ...

Monier, Erwan

254

Atmospheric Environment 39 (2005) 28292838 Diurnal and seasonal cycles of ozone precursors observed from  

E-Print Network [OSTI]

characteristics. Ethane and propane, largely originated from leakage of natural gas or liquefied petroleum gases) and nitrogen oxides (NO+NO2 ¼ NOx), ozone is photochemically pro- duced and can accumulate to hazardous levels

Wingenter, Oliver W.

255

Ozone response to emission changes: a modeling study during the MCMA-2006/MILAGRO Campaign  

E-Print Network [OSTI]

The sensitivity of ozone production to precursor emissions was investigated under five different meteorological conditions in the Mexico City Metropolitan Area (MCMA) during the MCMA-2006/MILAGRO field campaign using the ...

Song, Jihee

256

Real-World Studies of Ambient Ozone Formation as a Function of...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

-- Washington D.C. ace29lawson.pdf More Documents & Publications Weekday and Weekend Air Pollutant Levels in Ozone Problem Areas in the U.S. Health Impacts Program DOE's...

257

Ozone predictabilities due to meteorological uncertainties in the Mexico City basin using ensemble forecasts  

E-Print Network [OSTI]

The purpose of the present study is to investigate the sensitivity of ozone (O3)[(O subscript 3)] predictions in the Mexico City Metropolitan Area (MCMA) to meteorological initial uncertainties and planetary boundary layer ...

Bei, Naifang

258

States of cobalt and iron in catalysts supported in TiO{sub 2} from data of diffuse reflectance IR spectra of adsorbed carbon monoxide  

SciTech Connect (OSTI)

The variations in the oxidation states of cobalt and iron atoms in pure and mixed Co- and Fe-containing catalysts supported on TiO{sub 2} as a function of the conditions in which the catalysts were prepared and preliminarily treated were studied by analysis of the IR spectra of carbon monoxide adsorbed on these catalysts. A mutual influence of the components was discovered; iron was found to promote reduction of cobalt.

Davydov, A.A. [G.K. Boreskov Inst. of Catalysis, Novosibirsk (Russian Federation); Coville, N. [Univ. of the Wiswatersrand Wits, Johannesburg (South Africa)

1995-10-01T23:59:59.000Z

259

Relation between surface adsorption states and emf in a solid electrolyte concentration cell during carbon monoxide oxidation on platinum studied by local current measurement  

SciTech Connect (OSTI)

The importance of measuring adsorption during surface catalysis has been emphasized often. This is true for the oxidation of carbon monoxide on a platinum surface. Surface adsorption states during the reaction under steady states can be learned from electromotive force (emf) measurement with appropriate assumptions. Two mechanisms for emf generation have been proposed, one is that only oxygen activity generates emf, the other is that both oxygen and CO adsorption generates emf.

Okamoto, H.; Kawamura, G.; Kudo, T.

1984-04-01T23:59:59.000Z

260

Formation of ozone and oxidation of methane in a direct current corona discharge  

E-Print Network [OSTI]

FORMATION OF OZONE AND OXIDATION OF METHANE IN A DIRECT CURRENT CORONA DISCHARGE A Thesis by UMASHANKER TANGIRALA Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirement for the degree of MASTER... OF SCIENCE May 1976 Major Subject: Chemical Engineering FORMATION OF OZONE AND OXIDATION OF METHANE IN A DIRECT CURRENT CORONA DISCHARGE A Thesis by UMASHANKER TANGIRALA Approved as to style and content by: (Chairman of Committee) ( ad of Department...

Tangirala, Umashanker

1976-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "monoxide ozone lead" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Effect of the type of carrier on the properties of cobalt catalysts in the synthesis of aliphatic hydrocarbons from carbon monoxide and hydrogen  

SciTech Connect (OSTI)

The properties of catalysts used in the synthesis of hydrocarbons from CO and H/sub 2/ are determined to a significant degree by the carriers used in their preparation. This paper deals with a study of the effect of the type of carrier on the properties of cobalt-based catalysts in the synthesis of aliphatic hydrocarbons from CO and H/sub 2/. Co catalysts that are active in the synthesis of hydrocarbons from CO and H/sub 2/ are those on which the adsorption of H/sub 2/ exceeds 3.10/sup -2/ mmole/g Co and the adsorptin of carbon monoxide exceeds 7.10/sup -2/ mmole/g Co. Carbon monoxide and hydrogen are adsorbed on active catalysts in weakly bound forms. A mechanism is proposed for the formatin of an active center and the adsorption of carbon monoxide on Co-catalysts which includes the appearance of a partial positive charge on the cobalt atom.

Lapidus, A.L.; Jem, H.C.; Krylova, A.Y.

1983-04-10T23:59:59.000Z

262

Ozone response of foliage and cells of sensitive and tolerant potato cultivars  

SciTech Connect (OSTI)

The ozone response was contrasted between Cherokee' and Norchip', relatively ozone-sensitive and -tolerant potato cultivars, respectively. Leaf conductance of the two cultivars was determined with a diffusive resistance porometer before, during and after a 3-hour exposure to 0.25 ppm ozone (490 ..mu..g m3). While Cherokee foliage had a higher leaf conductance at the onset of the ozone exposure, conductance of Norchip foliage was too high throughout the experiment to account for relative tolerance of the latter cultivar. Norchip and Cherokee both exhibited abaxial and bifacial necrosis with more numerous lesions on the abaxial surface. Abaxial and bifacial necrosis were characterized by injured spongy, and spongy plus palisade cells, respectively. The percent of injured cell types were the same in both cultivars, but the absolute number of cells injured was greater in Cherokee than Norchip. Two types of cell injury were observed in necrotic lesions. One type of injury was characterized by collapsed, basophilic cells and the other by intact, basophilic cells. The ozone response of isolated leaf protoplasts of the two cultivars was similar. Two types of protoplast injury were observed, one characterized by lysis and the other by reduced staining with fluorescein diacetate. Maximum protoplast response to ozone was observed within the first 5 minutes of a 15 minute exposure. Little additional protoplast response occurred after 10 minutes.

Illman, B.L.

1983-01-01T23:59:59.000Z

263

Nick Wright Named Advanced Technologies Group Lead  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Nick Wright Named Advanced Technologies Group Lead Nick Wright Named Advanced Technologies Group Lead February 4, 2013 Nick Nick Wright has been named head of the National Energy...

264

NERSC seeks Computational Systems Group Lead  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

seeks Computational Systems Group Lead NERSC seeks Computational Systems Group Lead January 6, 2011 by Katie Antypas Note: This position is now closed. The Computational Systems...

265

Distributed Generation Lead-by-Example Resources  

Broader source: Energy.gov [DOE]

State governments can lead by example by promoting renewable energy programs and policies. Efforts to lead by example include using renewable energy resources (including alternative fuel for...

266

Methane and carbon monoxide emissions from asphalt pavement: Measurements and estimates of their important to global budgets  

SciTech Connect (OSTI)

The authors measured emissions of methane from asphalt surfaces used in pavement for roadways. Maximum emissions were 22 mg/m{sup 2}/hr for 1- to 4-week-old pavement during maximum sunlight intensity. Emissions were much smaller at low sunlight intensity and dropped off to negligible amounts at night. Smaller emissions were observed for asphalt pavement of 2.5 to 3 years approximate age under similar conditions. Comparison measurements of carbon monoxide emissions resulted in maximum emissions of about 2.6 mg/m{sup 2}hr for 1-week-old pavement. These findings indicate that emissions of CH{sub 4} and CO are a function of both sunlight and temperature. Based on these results, methane emissions from asphalt pavement cannot be a significant source of atmospheric methane as compared to other identified methane sources. Therefore, although asphalt methane emissions are a form of fossil fuel methane, they cannot explain the relatively high fraction of {sup 14}C-depleted methane in the atmosphere.

Tyler, S.C.; Dlugokencky, E.; Zimmerman, P.R.; Cicerone, R.J. (National Center for Atmospheric Research, Boulder, CO (USA)); Lowe, D.C. (Institute of Nuclear Sciences, Lower Hutt (New Zealand))

1990-08-20T23:59:59.000Z

267

Multi-lead heat sink  

DOE Patents [OSTI]

The disclosure relates to a heat sink used to protect integrated circuits from the heat resulting from soldering them to circuit boards. A tubular housing contains a slidable member which engages somewhat inwardly extending connecting rods, each of which is rotatably attached at one end to the bottom of the housing. The other end of each rod is fastened to an expandable coil spring loop. As the member is pushed downward in the housing, its bottom edge engages and forces outward the connecting rods, thereby expanding the spring so that it will fit over an integrated circuit. After the device is in place, the member is slid upward and the spring contracts about the leads of the integrated circuit. Soldering is now conducted and the spring absorbs excess heat therefrom to protect the integrated circuit. The placement steps are repeated in reverse order to remove the heat sink for use again.

Roose, Lars D. (Albuquerque, NM)

1984-01-01T23:59:59.000Z

268

Multi-lead heat sink  

DOE Patents [OSTI]

The disclosure relates to a heat sink used to protect integrated circuits from the heat resulting from soldering them to circuit boards. A tubular housing contains a slidable member which engages somewhat inwardly extending connecting rods, each of which is rotatably attached at one end to the bottom of the housing. The other end of each rod is fastened to an expandable coil spring loop. As the member is pushed downward in the housing, its bottom edge engages and forces outward the connecting rods, thereby expanding the spring so that it will fit over an integrated circuit. After the device is in place, the member is slid upward and the spring contracts about the leads of the integrated circuit. Soldering is now conducted and the spring absorbs excess heat therefrom to protect the integrated circuit. The placement steps are repeated in reverse order to remove the heat sink for use again.

Roose, L.D.

1982-08-25T23:59:59.000Z

269

Multi-lead heat sink  

DOE Patents [OSTI]

The disclosure relates to a heat sink used to protect integrated circuits from the heat resulting from soldering them to circuit boards. A tubular housing contains a slidable member which engages somewhat inwardly extending connecting rods, each of which is rotatably attached at one end to the bottom of the housing. The other end of each rod is fastened to an expandable coil spring loop. As the member is pushed downward in the housing, its bottom edge engages and forces outward the connecting rods, thereby expanding the spring so that it will fit over an integrated circuit. After the device is in place, the member is slid upward and the spring contracts about the leads of the integrated circuit. Soldering is now conducted and the spring absorbs excess heat therefrom to protect the integrated circuit. The placement steps are repeated in reverse order to remove the heat sink for use again. 4 figs.

Roose, L.D.

1984-07-03T23:59:59.000Z

270

Optimization of stabilized leachate treatment using ozone/persulfate in the advanced oxidation process  

SciTech Connect (OSTI)

Highlights: ? Ozone and persulfate reagent (O{sub 3}/S{sub 2}O{sub 8}{sup 2-}) was used to treat stabilized leachate. ? Central composite design (CCD) with response surface methodology (RSM) was applied. ? Operating variables including ozone and persulfate dosage, pH variance, and reaction time. ? Optimum removal of COD, color, and NH{sub 3}–N was 72%, 96%, and 76%, respectively. ? A good value of ozone consumption (OC) obtained with 0.60 (kg O{sub 3}/kg COD). - Abstract: The objective of this study was to investigate the performance of employing persulfate reagent in the advanced oxidation of ozone to treat stabilized landfill leachate in an ozone reactor. A central composite design (CCD) with response surface methodology (RSM) was applied to evaluate the relationships between operating variables, such as ozone and persulfate dosages, pH, and reaction time, to identify the optimum operating conditions. Quadratic models for the following four responses proved to be significant with very low probabilities (<0.0001): COD, color, NH{sub 3}–N, and ozone consumption (OC). The obtained optimum conditions included a reaction time of 210 min, 30 g/m{sup 3} ozone, 1 g/1 g COD{sub 0}/S{sub 2}O{sub 8}{sup 2-} ratio, and pH 10. The experimental results were corresponded well with predicted models (COD, color, and NH{sub 3}–N removal rates of 72%, 96%, and 76%, respectively, and 0.60 (kg O{sub 3}/kg COD OC). The results obtained in the stabilized leachate treatment were compared with those from other treatment processes, such as ozone only and persulfate S{sub 2}O{sub 8}{sup 2-} only, to evaluate its effectiveness. The combined method (i.e., O{sub 3}/S{sub 2}O{sub 8}{sup 2-}) achieved higher removal efficiencies for COD, color, and NH{sub 3}–N compared with other studied applications. Furthermore, the new method is more efficient than ozone/Fenton in advanced oxidation process in the treatment of the same studied leachate.

Abu Amr, Salem S. [School of Civil Engineering, Engineering Campus, Universiti Sains Malaysia, 14300 Nibong Tebal, Penang (Malaysia); Aziz, Hamidi Abdul, E-mail: cehamidi@eng.usm.my [School of Civil Engineering, Engineering Campus, Universiti Sains Malaysia, 14300 Nibong Tebal, Penang (Malaysia); Adlan, Mohd Nordin [School of Civil Engineering, Engineering Campus, Universiti Sains Malaysia, 14300 Nibong Tebal, Penang (Malaysia)

2013-06-15T23:59:59.000Z

271

Lead Safety Awareness This Bulletin provides information on the safe handling of lead  

E-Print Network [OSTI]

. CONTROLLING THE HAZARDS: LEAD STORAGE · Use inventory tracking to facilitate proper lead storage and to keep lead inventories to a minimum. · Store lead in containers or covered in specially designed areas. · Routinely monitor lead inventories to check for lead dust contamination. GENERAL GOOD WORK PRACTICES · When

272

Carbon monoxide alleviates ethanol-induced oxidative damage and inflammatory stress through activating p38 MAPK pathway  

SciTech Connect (OSTI)

Stress-inducible protein heme oxygenase-1(HO-1) is well-appreciative to counteract oxidative damage and inflammatory stress involving the pathogenesis of alcoholic liver diseases (ALD). The potential role and signaling pathways of HO-1 metabolite carbon monoxide (CO), however, still remained unclear. To explore the precise mechanisms, ethanol-dosed adult male Balb/c mice (5.0 g/kg.bw.) or ethanol-incubated primary rat hepatocytes (100 mmol/L) were pretreated by tricarbonyldichlororuthenium (II) dimmer (CORM-2, 8 mg/kg for mice or 20 ?mol/L for hepatocytes), as well as other pharmacological reagents. Our data showed that CO released from HO-1 induction by quercetin prevented ethanol-derived oxidative injury, which was abolished by CO scavenger hemoglobin. The protection was mimicked by CORM-2 with the attenuation of GSH depletion, SOD inactivation, MDA overproduction, and the leakage of AST, ALT or LDH in serum and culture medium induced by ethanol. Moreover, CORM-2 injection or incubation stimulated p38 phosphorylation and suppressed abnormal Tnfa and IL-6, accompanying the alleviation of redox imbalance induced by ethanol and aggravated by inflammatory factors. The protective role of CORM-2 was abolished by SB203580 (p38 inhibitor) but not by PD98059 (ERK inhibitor) or SP600125 (JNK inhibitor). Thus, HO-1 released CO prevented ethanol-elicited hepatic oxidative damage and inflammatory stress through activating p38 MAPK pathway, suggesting a potential therapeutic role of gaseous signal molecule on ALD induced by naturally occurring phytochemicals. - Highlights: • CO alleviated ethanol-derived liver oxidative and inflammatory stress in mice. • CO eased ethanol and inflammatory factor-induced oxidative damage in hepatocytes. • The p38 MAPK is a key signaling mechanism for the protective function of CO in ALD.

Li, Yanyan; Gao, Chao; Shi, Yanru; Tang, Yuhan; Liu, Liang; Xiong, Ting; Du, Min [Department of Nutrition and Food Hygiene, School of Public Health, Tongji Medical College, Huazhong University of Science and Technology, 13 Hangkong Road, Wuhan 430030 (China); Ministry of Education Lab of Environment and Health, School of Public Health, Tongji Medical College, Huazhong University of Science and Technology, 13 Hangkong Road, Wuhan 430030 (China); Hubei Key Laboratory of Food Nutrition and Safety, School of Public Health, Tongji Medical College, Huazhong University of Science and Technology, 13 Hangkong Road, Wuhan 430030 (China); Xing, Mingyou [Department of Infectious Diseases, Tongji Hospital, Tongji Medical College, Huazhong University of Science and Technology, 13 Hangkong Road, Wuhan 430030 (China); Liu, Liegang [Department of Nutrition and Food Hygiene, School of Public Health, Tongji Medical College, Huazhong University of Science and Technology, 13 Hangkong Road, Wuhan 430030 (China); Ministry of Education Lab of Environment and Health, School of Public Health, Tongji Medical College, Huazhong University of Science and Technology, 13 Hangkong Road, Wuhan 430030 (China); Hubei Key Laboratory of Food Nutrition and Safety, School of Public Health, Tongji Medical College, Huazhong University of Science and Technology, 13 Hangkong Road, Wuhan 430030 (China); Yao, Ping, E-mail: yaoping@mails.tjmu.edu.cn [Department of Nutrition and Food Hygiene, School of Public Health, Tongji Medical College, Huazhong University of Science and Technology, 13 Hangkong Road, Wuhan 430030 (China); Ministry of Education Lab of Environment and Health, School of Public Health, Tongji Medical College, Huazhong University of Science and Technology, 13 Hangkong Road, Wuhan 430030 (China); Hubei Key Laboratory of Food Nutrition and Safety, School of Public Health, Tongji Medical College, Huazhong University of Science and Technology, 13 Hangkong Road, Wuhan 430030 (China)

2013-11-15T23:59:59.000Z

273

Carbon monoxide line emission as a CMB foreground: tomography of the star-forming universe with different spectral resolutions  

E-Print Network [OSTI]

The rotational lines of carbon monoxide and the fine structure lines of CII and of the most abundant metals, emitted during the epoch of enhanced star formation in the universe, are redshifted in the frequency channels where the present-day and future CMB experiments are sensitive. We estimate the contribution to the CMB angular power spectrum by the emission in such lines in merging star-forming galaxies. We used the Lacey-Cole approach to characterize the distribution of the merging halos, together with a parametrization for the star formation rate in each of them. Using observational data from a sample of local, low-redshift, and high-redshift objects, we calibrated the luminosity in each line as a function of the star formation rate. We show that the correlation term arising from CO line emission is a significant source of foreground for CMB in a broad range of frequencies (in particular in the 20-60 GHz band) and for 1000

Mattia Righi; Carlos Hernandez-Monteagudo; Rashid Sunyaev

2008-07-24T23:59:59.000Z

274

Overview of ozone human exposure and health risk analyses used in the U.S. EPA's review of the ozone air quality standard.  

SciTech Connect (OSTI)

This paper presents an overview of the ozone human exposure and health risk analyses developed under sponsorship of the U.S. Environmental Protection Agency (EPA). These analyses are being used in the current review of the national ambient air quality standards (NAAQS) for ozone. The analyses consist of three principal steps: (1) estimating short-term ozone exposure for particular populations (exposure model); (2) estimating population response to exposures or concentrations (exposure-response or concentration-response models); and (3) integrating concentrations or exposure with concentration-response or exposure-response models to produce overall risk estimates (risk model). The exposure model, called the probabilistic NAAQS exposure model for ozone (pNEM/03), incorporates the following factors: hourly ambient ozone concentrations; spatial distribution of concentrations; ventilation state of individuals at time of exposure; and movement of people through various microenvironments (e.g., outdoors, indoors, inside a vehicle) of varying air quality. Exposure estimates are represented by probability distributions. Exposure-response relationships have been developed for several respiratory symptom and lung function health effects, based on the results of controlled human exposure studies. These relationships also are probabilistic and reflect uncertainties associated with sample size and variability of response among subjects. The analyses also provide estimates of excess hospital admissions in the New York City area based on results from an epidemiology study. Overall risk results for selected health endpoints and recently analyzed air quality scenarios associated with alternative 8-hour NAAQS and the current 1-hour standard for outdoor children are used to illustrate application of the methodology.

Whitfield, R. G.

1999-03-04T23:59:59.000Z

275

Fading of alizarin and related artists's pigments by atmospheric ozone: reaction products and mechanisms  

SciTech Connect (OSTI)

The colorants alizarin and Alizarin Crimson (a calcium-aluminum lake pigment) and their simple structural homologue anthraquinone were deposited on silica gel, cellulose, and Teflon substrates and exposed in the dark to ozone in purified air (approx.0.4 ppm O/sub 3/ for 95 days and approx.10 ppm O/sub 3/ for 18-80 h). Exposed and control samples were analyzed by mass spectrometry. Alizarin Crimson reacted with ozone on all substrates, yielding phthalic acid (major), benzoic acid (minor), and other minor and unidentified products. Anthraquinone did not react with ozone irrespective of conditions. Alizarin did not react on Teflon or cellulose but reacted on silica gel to yield phthalic acid (major) and other products. A chemical mechanism responsible for the fading of these alizarin-related colorants by ozone is suggested that is consistent with the products distribution, the observed reactivity sequence, and the observed substrate-specific effects. The possible application of this work to predicting the ozone fastness of other alizarin-related pigments is discussed briefly. 33 references, 5 figures.

Grosjean, D.; Whitmore, P.M.; De Moor, C.P.; Cass, G.R.; Druzik, J.R.

1987-07-01T23:59:59.000Z

276

Children and lead: new findings and concerns  

SciTech Connect (OSTI)

An editorial dealing with lead in the environment and its health risks to children is presented. Young children are particularly vulnerable to lead exposure. Through hand-to-mouth activities, such as thumb sucking, nail biting, or eating with dirty hands, lead in house dust and garden soil readily enters their bodies. Children with pica are exposed to more lead because they eat such items as paint chips, broken plaster, and dirt. Moreover, intestinal lead absorption is greater in children than in adults. The author recommends a concerted effort to reduce undue lead absorption in children. (JMT)

Lin-Fu, J.S.

1982-09-02T23:59:59.000Z

277

Sensitivity of China's ozone air quality to 2000-2050 global changes of1 climate and emissions2  

E-Print Network [OSTI]

1 Sensitivity of China's ozone air quality to 2000-2050 global changes of1 climate and emissions2 3 emissions of ozone precursors. The climate and16 emission effect in combination will increase afternoon mean increases18 in global (excluding China) anthropogenic emissions, 37% to Chinese emission19 increases

Wu, Shiliang

278

A numerical study of mass transfer of ozone dissolution in bubble plumes with an Euler-Lagrange Method  

E-Print Network [OSTI]

, as a model problem for a water purification system. The effect of bubble diameter and plume structure on mass are widely observed and exploited in engineering applications, with water purification using ozone bubble the mass transfer process of ozone dissolution in a bubble plume inside a rectangular water tank

Huang, Huaxiong

279

Impact of ozone on indoor air quality: a preliminary field study M. Nicolas, O. Ramalho, F. Maupetit  

E-Print Network [OSTI]

indoor air quality (IAQ) since they produce secondary pollutants, mainly aldehydes which are known to document the impact on IAQ of outdoor ozone during summer air pollution episodes. For this purpose, a oneImpact of ozone on indoor air quality: a preliminary field study M. Nicolas, O. Ramalho, F

Boyer, Edmond

280

Australia and New Zealand Coordinating Lead Authors  

E-Print Network [OSTI]

11 Australia and New Zealand Coordinating Lead Authors: Kevin Hennessy (Australia), Blair Fitzharris (New Zealand) Lead Authors: Bryson C. Bates (Australia), Nick Harvey (Australia), Mark Howden (Australia), Lesley Hughes (Australia), Jim Salinger (New Zealand), Richard Warrick (New Zealand

Green, Donna

Note: This page contains sample records for the topic "monoxide ozone lead" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Laboratory measurement of secondary pollutant yields from ozone reaction with HVAC filters.  

SciTech Connect (OSTI)

We used Proton Transfer Reaction - Mass Spectrometry (PTR-MS) and conventional sampling methods to monitor and identify trace level organic pollutants formed in heterogeneous reactions between ozone and HVAC filters in real time. Experiments were carried out using a bench-scale flow tube reactor operating with dry air and humidified air (50% RH), at realistically high ozone concentrations (150 ppbv). We explored different filter media (i.e., fiberglass and cotton/polyester blends) and different particle loadings (i.e., clean filter and filters loaded with particles for 3 months at the Lawrence Berkeley National Laboratory and the Port of Oakland, CA). Detailed emission dynamics of very low levels of certain organic pollutants from filter media upon ozone exposure in the presence of moisture have been obtained and analyzed.

Destaillats, Hugo; Chen, Wenhao; Apte, Michael; Li, Nuan; Spears, Michael; Almosni, Jérémie; Zhang, Jianshun (Jensen); Fisk, William J.

2009-09-09T23:59:59.000Z

282

Thermochemical Kinetics for Multireference Systems: Addition Reactions of Ozone  

SciTech Connect (OSTI)

The 1,3-dipolar cycloadditions of ozone to ethyne and ethene provide extreme examples of multireference singlet-state chemistry, and they are examined here to test the applicability of several approaches to thermochemical kinetics of systems with large static correlation. Four different multireference diagnostics are applied to measure the multireference characters of the reactants, products, and transition states; all diagnostics indicate significant multireference character in the reactant portion of the potential energy surfaces. We make a more complete estimation of the effect of quadruple excitations than was previously available, and we use this with CCSDT/CBS estimation of Wheeler et al. (Wheeler, S. E.; Ess, D. H.; Houk, K. N. J. Phys. Chem. A 2008, 112, 1798.) to make new best estimates of the van der Waals association energy, the barrier height, and the reaction energy to form the cycloadduct for both reactions. Comparing with these best estimates, we present comprehensive mean unsigned errors for a variety of coupled cluster, multilevel, and density functional methods. Several computational aspects of multireference reactions are considered: (i) the applicability of multilevel theory, (ii) the convergence of coupled cluster theory for reaction barrier heights, (iii) the applicability of completely renormalized coupled cluster methods to multireference systems, (iv) the treatment by density functional theory, (v) the multireference perturbation theory for multireference reactions, and (vi) the relative accuracy of scaling-type multilevel methods as compared with additive ones. It is found that scaling-type multilevel methods do not perform better than the additive-type multilevel methods. Among the 48 tested density functionals, only M05 reproduces the best estimates within their uncertainty. Multireference perturbation theory based on the complete-active-space reference wave functions constructed using a small number of reaction-specific active orbitals gives accurate forward barrier heights; however, it significantly underestimates reaction energies.

Zhao, Yan; Tishchenko, Oksana; Gour, Jeffrey R.; Li, Wei; Lutz, Jesse; Piecuch, Piotr; Truhlar, Donald G.

2009-05-14T23:59:59.000Z

283

Infrared spectroscopic studies of carbon monoxide adsorbed on a series of silica-supported copper catalysts in different oxidation states  

SciTech Connect (OSTI)

Infrared spectroscopy has been used to study the adsorption of carbon monoxide (358-493 K, 0.1-20 kPa) on four copper-on-silica (2-10 wt% Cu) catalysts prepared by the ion-exchange technique. The measurements are made for each sample in three different states: unreduced (predominantly Cu{sup 2+}), and reduced (Cu{sup 0}), and partially reoxidized in nitrous oxide (Cu{sup +}). On unreduced samples, a major absorption band between 2127 and 2132 cm{sup {minus}1} due to CO adsorbed on small CuO particles and a weak band at 2199 cm{sup {minus}1} due to CO on isolated Cu{sup 2+} ions incorporated in the silica surface have been identified. The former adsorption obeys a Langmuir isotherm with a heat of adsorption of 29 kJ/mol independent of CuO particle size and surface coverage. After catalyst reduction, the major absorption band lies between 2090 and 2113 cm{sup {minus}1} and arises from CO linearly bound to very small (1- to 5-nm) copper metal clusters. The observed frequency shifts indicate the presence of steps and terraces similar to low index Cu planes in very small particles (1- to 2-nm), and the presence of similar higher index Cu planes on larger clusters (2- to 5-nm). The absorption is described by a Freundlich isotherm with the heat of CO adsorption decreasing with coverage from 50 to 22 kJ/mol on bigger particles but more constant (27 to 22 kJ/mol) on small particles. A surface copper/CO atomic ratio increasing from 5 to 12 is established at equilibrium saturation between 358 and 493 K using extinction coefficients determined in this study. In the reduced catalysts, a weakly adsorbed ({Delta}H{sub a} = {minus}20 kJ/mol) species assigned to CO bound to isolated Cu{sup +} ions is also found and absorbs at 2175 cm{sup {minus}1}. The frequency of this band does not vary with catalyst loading and is not affected by reoxidation of the catalyst in nitrous oxide.

Kohler, M.A.; Wainwright, M.S.; Trimm, D.L.; Cant, N.W. (Macquarie Univ., New South Wales (Australia) Univ. of South Wales (Australia))

1989-05-01T23:59:59.000Z

284

Application of an all-solid-state diode-laser-based sensor for carbon monoxide detection by optical absorption in the 4.4 ? 4.8 µm spectral region  

E-Print Network [OSTI]

APPLICATION OF AN ALL-SOLID-STATE DIODE-LASER-BASED SENSOR FOR CARBON MONOXIDE DETECTION BY OPTICAL ABSORPTION IN THE 4.4 ? 4.8 ?m SPECTRAL REGION A Dissertation by RODOLFO BARRON JIMENEZ Submitted to the Office of Graduate... FOR CARBON MONOXIDE DETECTION BY OPTICAL ABSORPTION IN THE 4.4 ? 4.8 ?m SPECTRAL REGION A Dissertation by RODOLFO BARRON JIMENEZ Submitted to Texas A&M University in partial fulfillment of the requirements for the degree of DOCTOR OF PHILOSOPHY...

Rodolfo, Barron Jimenez

2005-02-17T23:59:59.000Z

285

Infrared spectra of carbon monoxide adsorbed on SiO sub 2 -supported lanthanide-Ni bimetallic catalysts and their catalytic properties  

SciTech Connect (OSTI)

Recently the surface properties of the lanthanide (rare earth) - transition metal intermetallics and lanthanide metal overlayers have attracted a growing interest from the point of view of technical applications in catalyst and hydrogen storage. However, despite the intrinsic interest and considerable potential of these novel materials, very little detailed work has been carried out with a view to unveiling the specific properties upon interactions of lanthanides with transition metals. It has been shown that Eu and Yb metals dissolve in liquid ammonia to yield homogeneous solutions containing the ammoniated electrons. When the transition metal powders are added to this solution, the metal powders react with the dissolved lanthanide metals in liquid ammonia to form novel bimetallic catalysts. Such a system can be used as a catalyst probe for studying the catalytic actions induced by interactions between the lanthanide and transition metals. The present investigation was extended to include a SiO{sub 2}-supported bimetallic systems obtained when Eu or Yb dissolved in liquid ammonia reacts with silica-supported Ni. Using Fourier transform (FT)-IR studies of adsorbed carbon monoxide the authors provided information about the way the surface components were disposed in this bimetallic system. Adsorbed carbon monoxide was used as a molecular probe for the nature of bimetallic surface since the IR spectra of adsorbed probe molecules directly reflected variations in the surface.

Imamura, Hayao; Sugimoto, Hiromi; Sakata, Yoshihisa; Tsuchiya, Susumu (Yamaguchi Univ., Ube (Japan))

1992-07-01T23:59:59.000Z

286

Study of air pollution: Effects of ozone on neuropeptide-mediated responses in human subjects. Final report  

SciTech Connect (OSTI)

The study examined the hypothesis that ozone inactivates the enzyme, neutral endopeptidase, responsible for limiting the effects of neuropeptides released from afferent nerve endings. Cough response of capsaicin solution delivered from a nebulizer at 2 min. intervals until two or more coughs were produced. Other endpoints measured included irritative symptoms as rated by the subjects on a nonparametric scale, spirometry, of each concentration of ozone were compared to those of filtered air in a single-blind randomized sequence. The results indicate that a 2 h. exposure to 0.4 ppm of ozone with intermittent light exercise alters the sensitivity of airway nerves that mediate the cough response to inhaled materials. This dose of ozone also caused a change in FEV1. A lower level of ozone, 0.02 ppm, caused a change in neither cough threshold nor FEV1, even when the duration of exposure was extended to three hours. The findings are consistent with the author's hypothesis that ozone may sensitize nerve endings in the airways by inactivating neutral endopeptidase, an enzyme that regulates their activity, but they do not demonstrate that directly examining an effect directly mediated by airway nerves allows detection of effects of ozone at doses below those causing effects detected by standard tests of pulmonary function.

Boushey, H.A.

1991-11-01T23:59:59.000Z

287

Indoor Secondary Pollutants from Household Product Emissions inthe Presence of Ozone: A Bench-Scale Chamber Study  

SciTech Connect (OSTI)

Ozone-driven chemistry is a major source of indoor secondary pollutants of health concern. This study investigates secondary air pollutants formed from reactions between constituents of household products and ozone. Gas-phase product emissions were introduced along with ozone at constant rates into a 198-L Teflon-lined reaction chamber. Gas-phase concentrations of reactive terpenoids and oxidation products were measured. Formaldehyde was a predominant oxidation byproduct for the three studied products, with yields under most conditions of 20-30% with respect to ozone consumed. Acetaldehyde, acetone, glycolaldehyde, formic acid and acetic acid were each also detected for two or three of the products. Immediately upon mixing of reactants, a scanning mobility particle sizer detected particle nucleation events that were followed by a significant degree of ultrafine particle growth. The production of secondary gaseous pollutants and particles depended primarily on the ozone level and was influenced by other parameters such as the air-exchange rate. Hydroxyl radical concentrations in the range 0.04-200 x 10{sup 5} molecules cm{sup -3} were measured. OH concentrations were observed to vary strongly with residual ozone level in the chamber, which was in the range 1-25 ppb, as is consistent with expectations from a simplified kinetic model. In a separate test, we exposed the dry residue of two products to ozone in the chamber and observed the formation of gas-phase and particle-phase secondary oxidation products.

Destaillats, Hugo; Lunden, Melissa M.; Singer, Brett C.; Coleman,Beverly K.; Hodgson, Alfred T.; Weschler, Charles J.; Nazaroff, William W.

2005-10-01T23:59:59.000Z

288

Energy Policy 29 (2001) 11331143 Ethanol as a lead replacement: phasing out leaded gasoline in Africa  

E-Print Network [OSTI]

Energy Policy 29 (2001) 1133­1143 Ethanol as a lead replacement: phasing out leaded gasoline cost of lead additives and of gasoline, and the falling cost of ethanol and sugarcane, have created sugarcane is produced in Africa to replace all the lead used in African gasoline; this would require Africa

Thomas, Valerie

289

Procurement Standards Lead-by-Example Resources  

Broader source: Energy.gov [DOE]

State and local governments can lead by example by promoting energy efficiency programs and policies for public facilities, equipment, and government operations.

290

Energy Efficiency Lead-by-Example Resources  

Broader source: Energy.gov [DOE]

State and local governments can lead by example by promoting energy efficiency programs and policies for public facilities, equipment, and government operations.

291

Lead by Example with Smart Energy Management  

SciTech Connect (OSTI)

The Lead by Example with Smart Energy Management brochure describes FEMP's services, namely financing and acquisition support, technical assistance and policy, and outreach and coordination.

Not Available

2006-07-01T23:59:59.000Z

292

Imnaha Subbasin Inventory Subbasin Lead Entity  

E-Print Network [OSTI]

Imnaha Subbasin Inventory May 2004 Written by Ecovista Subbasin Lead Entity: Nez Perce Tribe.......................................................................... 15 List of Tables TABLE 1. ACRONYMS USED IN THE IMNAHA SUBBASIN INVENTORY

293

Kudzu (Pueraria montana) invasion doubles emissions of nitric oxide and increases ozone pollution  

E-Print Network [OSTI]

Kudzu (Pueraria montana) invasion doubles emissions of nitric oxide and increases ozone pollution) The nitrogen-fixing legume kudzu (Pueraria montana) is a wide- spread invasive plant in the southeastern United the effects of kudzu invasions on soils and trace N gas emissions at three sites in Madison County, Georgia

Mickley, Loretta J.

294

Effects of Ion-Exchange Treatment on Bromate Formation and Oxidation Efficiency during Ozonation  

E-Print Network [OSTI]

water treatment. In this study, we applied several different ion exchangers (i.e., anion exchange resins technologies in advanced drinking water treatment processes along with activated carbon treatment. Ozonation), chlorine-resistant pathogenic organisms, and various micropollutants in drinking water treatment. In Japan

Takada, Shoji

295

Constraining global isoprene emissions with Global Ozone Monitoring Experiment (GOME) formaldehyde column measurements  

E-Print Network [OSTI]

Constraining global isoprene emissions with Global Ozone Monitoring Experiment (GOME) formaldehyde emission estimates are highly uncertain because of a lack of direct observations. Formaldehyde (HCHO the observation of this trace gas to help constrain isoprene emissions. We use HCHO column observations from

Chance, Kelly

296

Three-dimensional modeling of ozone on Mars Franck Lefe`vre,1  

E-Print Network [OSTI]

picture of a global anticorrelation between the ozone (O3) and water vapor columns. However and Structure: Middle atmosphere--constituent transport and chemistry (3334); 5405 Planetology: Solid Surface Planets: Atmospheres--composition and chemistry; 6225 Planetology: Solar System Objects: Mars; KEYWORDS

Forget, François

297

The impact of large scale biomass production on ozone air pollution in Joost B. Beltman a  

E-Print Network [OSTI]

The impact of large scale biomass production on ozone air pollution in Europe Joost B. Beltman a , Carlijn Hendriks a , Markus Tum b , Martijn Schaap a,* a TNO, Department of Climate, Air by up to 25% and 40%. Air pollution mitigation strategies should consider land use management. a r t i

Utrecht, Universiteit

298

Synthesis of nickel–zinc ferrite magnetic nanoparticle and dye degradation using photocatalytic ozonation  

SciTech Connect (OSTI)

Graphical abstract: Display Omitted Highlights: ? Nickel–zinc ferrite magnetic nanoparticle (NZFMN) was synthesized and characterized. ? Dye degradation by photocatalytic ozonation using NZFMN was studied. ? Formate, acetate and oxalate were detected as dominant dye degradation aliphatic intermediates. ? Nitrate, sulfate and chloride ions were detected as mineralization products of dyes. ? NZFMN was an effective magnetic nanocatalyst to degrade dyes. -- Abstract: In this paper, nickel–zinc ferrite magnetic nanoparticle (NZFMN) was synthesized and its dye degradation ability using photocatalytic ozonation was investigated. The NZFMN was characterized by X-ray diffraction (XRD), scanning electron microscopic (SEM), Fourier transforms infrared (FTIR) and alternative gradient force magnetometer (AGFM). Reactive Red 198 (RR198) and Direct Green 6 (DG6) were used as dye models. UV–vis and ion chromatography (IC) analyses were employed to study dye degradation. The effects of operational parameters on decolorization such as NZFMN dosage, dye concentration, salt and pH were studied. RR198 and DG6 were completely decolorized (100%) by photocatalytic ozonation using NZFMN. Formate, acetate and oxalate anions were detected as dominant aliphatic intermediates. Nitrate, sulfate and chloride ions were detected as mineralization products of dyes. Results showed that the photocatalytic ozonation using NZFMN was a very effective method for dye degradation.

Mahmoodi, Niyaz Mohammad, E-mail: mahmoodi@icrc.ac.ir [Department of Environmental Research, Institute for Color Science and Technology, Tehran (Iran, Islamic Republic of); Bashiri, Marziyeh; Moeen, Shirin Jebeli [Department of Environmental Research, Institute for Color Science and Technology, Tehran (Iran, Islamic Republic of)] [Department of Environmental Research, Institute for Color Science and Technology, Tehran (Iran, Islamic Republic of)

2012-12-15T23:59:59.000Z

299

INTERRELAITONS BETWEEN VARIABILITY OF GROUND-LEVEL OZONE AND LAND COVER CHANGE  

E-Print Network [OSTI]

ozone monitoring stations in Connecticut and Rohde Island were used for the analysis. The monitoring stations were classified into different categories based on their locations and land cover characteristics. Cars and gasoline-burning engines are large sources of VOCs. VOCs also come from consumer products

Wang, Y.Q. "Yeqiao"

300

Growth and crown architecture of two aspen genotypes exposed to interacting ozone and carbon dioxide  

E-Print Network [OSTI]

Growth and crown architecture of two aspen genotypes exposed to interacting ozone and carbon to O3, atmos- pheric carbon dioxide (CO2) concentrations are increasing rapidly (Keeling et al., 1995 concentrations may offset the detrimental effects of increasing O3 (Allen, 1990). Some studies have shown that CO

Note: This page contains sample records for the topic "monoxide ozone lead" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

A Laboratory Method For Measuring The Ozone Emission From In-duct Air Cleaners.  

E-Print Network [OSTI]

: Emission rate, HVAC air cleaners, electrostatic precipitators, coronas, standard test method 1 Introduction Subchapter 8.7). However, in-duct air cleaners including electronic air cleaners, electrostatic precipitators of an ozone analyzer. Viner et al. (1992) studied commercial in-duct electrostatic precipitators and observed

Siegel, Jeffrey

302

Earth'sFuture Stratospheric ozone response to a solar irradiance reduction  

E-Print Network [OSTI]

the stratospheric ozone response to a proposed geoengineering activity wherein a reduced top-of-atmosphere (TOA to the Geoengineering Model Intercomparison Project (GeoMIP) Experiment G1. Three primary simulations were completed geoengineering activities have been proposed as possible techniques to help counteract the ongoing climate change

Jackman, Charles H.

303

Stratospheric ozone response to sulfate geoengineering: Results from the Geoengineering Model  

E-Print Network [OSTI]

Stratospheric ozone response to sulfate geoengineering: Results from the Geoengineering Model for Atmospheric Research, Boulder, Colorado, USA Abstract Geoengineering with stratospheric sulfate aerosols has the experiments G3 and G4 of the Geoengineering Model Intercomparison Project. On average, the models simulate

Robock, Alan

304

Probing into regional ozone and particulate matter pollution in the United States  

E-Print Network [OSTI]

) and fine particulate matter (PM2.5) air pollution and associated health effects have been one of the majorProbing into regional ozone and particulate matter pollution in the United States: 1. A 1 year CMAQ-term simulations using the Community Multiscale Air Quality (CMAQ) modeling system and subsequent process analyses

Jacobson, Mark

305

Ozone depletion during the solar proton events of October//November 2003 as seen by SCIAMACHY  

E-Print Network [OSTI]

Ozone depletion during the solar proton events of October//November 2003 as seen by SCIAMACHY G changes caused by the solar proton events from 26 October to 6 November 2003, known as the ``Halloween differences are given. Two regimes can be distinguished, one above about 50 km dominated by HOx (H, OH, HO2

Steinhoff, Heinz-Jürgen

306

PublishedbyManeyPublishing(c)IOMCommunicationsLtd Influence of UV irradiation and ozone on  

E-Print Network [OSTI]

of purified humid air containing predetermined quantities of SO2, NO2, H2S, Cl2, HCI, NH3 and O3. This lackPublishedbyManeyPublishing(c)IOMCommunicationsLtd Influence of UV irradiation and ozone by ultraviolet (UV) light was investigated. A modified coulometric reduction technique was used, substituting

307

Earth'sFuture Multidecadal global cooling and unprecedented ozone loss  

E-Print Network [OSTI]

Earth'sFuture Multidecadal global cooling and unprecedented ozone loss following a regional nuclear inertia and albedo effects in the ocean and expanded sea ice. The combined cooling and enhanced UV would put significant pressures on global food supplies and could trigger a global nuclear famine. Knowledge

Robock, Alan

308

Interactions of ozone and pathogens on the surface structure of Norway spruce needles  

E-Print Network [OSTI]

Interactions of ozone and pathogens on the surface structure of Norway spruce needles K. Ojanperä S and pathogens. It also acts as a barrier to air pollutants (Jeffree, 1986). The epicuticular wax of Norway and then a plate-like wax structure (Sauter and Voss, 1986). The life span of healthy needles of Norway spruce

Paris-Sud XI, Université de

309

Characterization and correction of Global Ozone Monitoring Experiment 2 ultraviolet measurements and application  

E-Print Network [OSTI]

analysis indicates that reflectance degradation began at the beginning of the mission; the reflectance degrades by 15% around 290 nm and by 2.2% around 325 nm from 2007 through 2009. Degradation shows of radiance in the ultraviolet (UV) region is essential for retrievals of ozone profiles especially

Chance, Kelly

310

White Pine Emission Trends of Monoterpenes and Sesquiterpenes After Acute Ozone Exposure  

E-Print Network [OSTI]

White Pine Emission Trends of Monoterpenes and Sesquiterpenes After Acute Ozone Exposure Daniel M of White Pine (Pinus strobus) specimens located at the University of Michigan Biological Station (UMBS). To measure terpene production, dynamic branch enclosures were simultaneously positioned on White Pine

Collins, Gary S.

311

Thickness influence on surface morphology and ozone sensing properties of nanostructured ZnO transparent  

E-Print Network [OSTI]

, 71004 Heraklion, Crete, Greece Available online 19 January 2006 Abstract Transparent zinc oxide (Zn Keywords: Zinc oxide; PLD; AFM; Ozone 1. Introduction Zinc oxide (ZnO) is an n-type semiconductor devices [3], varistors, planar optical waveguides [4], transparent electrodes [5,6], ultraviolet

312

A neural emission-receptor model for ozone reduction S.Barazzetta, G. Corani  

E-Print Network [OSTI]

in air pollution studies because of their impact on human health and agricultural crops and forests. High,guariso@elet.polimi.it Abstract: Ground level ozone pollution is a complex phenomenon heavily affecting industrialized and pop problem that determines the least cost alternatives to obtain a given air quality standard. The decision

Corani, Giorgio

313

Author's personal copy Digestive utilization of ozone-exposed forage by rabbits (Oryctolagus cuniculus)  

E-Print Network [OSTI]

Author's personal copy Digestive utilization of ozone-exposed forage by rabbits (Oryctolagus Digestibility Forage quality Herbivore nutrition Phenolics Rabbits Southern Piedmont a b s t r a c t A mixture) in a digestibility experiment. Forages and feed refusals were analyzed for concentrations of total cell wall

Ditchkoff, Steve

314

The Economic Impact of Global Climate and Tropospheric Ozone on World Agricultural Production  

E-Print Network [OSTI]

by Xiaodu (Dulles) Wang Bachelor of Science with majors in Electrical Engineering, Economics and ComputerThe Economic Impact of Global Climate and Tropospheric Ozone on World Agricultural Production Engineering The Johns Hopkins University, June 2003 Submitted to the Engineering Systems Division

315

Net ecosystem fluxes of isoprene over tropical South America inferred from Global Ozone Monitoring Experiment (GOME)  

E-Print Network [OSTI]

Net ecosystem fluxes of isoprene over tropical South America inferred from Global Ozone Monitoring estimate isoprene emissions over tropical South America during 1997­2001 using column measurements (ATSR) firecounts and GOME NO2 columns. We find that South America can be split into eastern and western

Chance, Kelly

316

Ground-level ozone in the 21st century: future trends,  

E-Print Network [OSTI]

Ground-level ozone in the 21st century: future trends, impacts and policy implications October 2008 Price £39 web royalsociety.org Science Policy REPORT 15/08 #12;Cover image: Sunrise over the River Ganges in Varanasi, India showing a sunny and polluted sky, characteristic of photochemical smog

317

Transport of Asian ozone pollution into surface air over the western United States in spring  

E-Print Network [OSTI]

Transport of Asian ozone pollution into surface air over the western United States in spring Meiyun the mechanisms involved in the transport of Asian pollution plumes into western U.S. surface air through, including the interleaving and mixing of Asian pollution and stratospheric air associated with complex

318

Failure of ozone and nitrogen dioxide to enhance lung tumor development in hamsters  

SciTech Connect (OSTI)

We tested the hypothesis that the two common oxidant air pollutants, ozone and nitrogen dioxide, modulate the development of respiratory tract tumors in Syrian golden hamsters. The animals received subcutaneous injections of the carcinogen diethylnitrosamine (20 mg/kg) twice a week while being exposed continuously to an atmosphere of 0.8 parts per million (ppm)* of ozone or 15 ppm of nitrogen dioxide. Animals were killed 16 weeks or 24 to 32 weeks after the beginning of the treatment. Ozone delayed the appearance of tracheal tumors and reduced the incidence of tumors in the lung periphery. A suspected neuroendocrine differentiation of those lung tumors could not be established by immunocytochemistry due to overfixation of tissues. On the other hand, ozone seemed to mitigate development of hepatotoxic lesions mediated by diethylnitrosamine. In animals treated with diethylnitrosamine and exposed to nitrogen dioxide, fewer tracheal tumors and no lung tumors were found. Only a few lung tumors were produced in animals treated with diethylnitrosamine and kept in an atmosphere of 65% oxygen. The previously observed neuroendocrine nature of tumors induced by simultaneous exposure to diethylnitrosamine and hyperoxia could not be established because the long fixation of tissues precluded immunocytochemical stains. Animals treated with diethylnitrosamine and kept in filtered air while being housed in wire-mesh cages developed fewer lung tumors than animals given the same treatment and kept on conventional bedding in shoebox cages. Although all inhalants tested are known to produce substantial cell proliferation in the respiratory tract, it was not possible to document whether this would enhance lung tumor development. The role of the two common air pollutants, ozone and nitrogen dioxide, as possible additional risks in the pathogenesis of lung cancer in animals continues to remain uncertain.

Witschi, H.; Breider, M.A.; Schuller, H.M. (Univ. of California, Davis, CA (United States))

1993-09-01T23:59:59.000Z

319

Sea Breeze characteristics during a high ozone event over Houston  

E-Print Network [OSTI]

representing the wind field in the lowest 4 km. Results show that changes in the large-scale wind pattern, as seen at 850 mb, can explain differences in the sea breeze circulation. Onshore flow leads to a faster moving sea breeze front whereas light opposing...

Naumann, Stephanie Alaine

2001-01-01T23:59:59.000Z

320

LEAD COMMISSIONER REPORT RENEWABLE POWER IN  

E-Print Network [OSTI]

, Public Interest Energy Research Program, Public Utilities Regulatory Policies Act, Renewable Energy1502011002LCFREV1 #12;CALIFORNIA ENERGY COMMISSION 2011 INTEGRATED ENERGY POLICY REPORT LEAD COMMISSIONER of the 2011 Integrated Energy Policy Report Lead Commissioner. It does not necessarily represent the views

Note: This page contains sample records for the topic "monoxide ozone lead" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

LEAD Academy *Leadership in Educational Administration Academy  

E-Print Network [OSTI]

LEAD Academy *Leadership in Educational Administration Academy Educational Administration for overnight accommodations if desired A time intensive component of the academy will occur on the UNO campus of practitioners will serve to facilitate the LEAD Academy, developing mentor/mentee networks that will continue

Farritor, Shane

322

EPA Lead Safety for Renovation, Repair and  

E-Print Network [OSTI]

than 20 f lead-based paint is dis- e exterior. Window replace- onsidered minor mainte- air. If you're of thousands of dollars in fines and put yourself and your company at risk of po- tential lawsuits. 2. ProtectEPA Lead Safety for Renovation, Repair and Painting (RRP) Course Certified Renovators Class

Tennessee, University of

323

Fan-fold shielded electrical leads  

DOE Patents [OSTI]

Disclosed are fan-folded electrical leads made from copper cladded Kapton, for example, with the copper cladding on one side serving as a ground plane and the copper cladding on the other side being etched to form the leads. The Kapton is fan folded with the leads located at the bottom of the fan-folds. Electrical connections are made by partially opening the folds of the fan and soldering, for example, the connections directly to the ground plane and/or the lead. The fan folded arrangement produces a number of advantages, such as electrically shielding the leads from the environment, is totally non-magnetic, and has a very low thermal conductivity, while being easy to fabricate. 3 figs.

Rohatgi, R.R.; Cowan, T.E.

1996-06-11T23:59:59.000Z

324

Fan-fold shielded electrical leads  

DOE Patents [OSTI]

Fan-folded electrical leads made from copper cladded Kapton, for example, with the copper cladding on one side serving as a ground plane and the copper cladding on the other side being etched to form the leads. The Kapton is fan folded with the leads located at the bottom of the fan-folds. Electrical connections are made by partially opening the folds of the fan and soldering, for example, the connections directly to the ground plane and/or the lead. The fan folded arrangement produces a number of advantages, such as electrically shielding the leads from the environment, is totally non-magnetic, and has a very low thermal conductivity, while being easy to fabricate.

Rohatgi, Rajeev R. (Mountain View, CA); Cowan, Thomas E. (Livermore, CA)

1996-01-01T23:59:59.000Z

325

Final Technical Report "Catalytic Hydrogenation of Carbon Monoxide and Olefin Oxidation" Grant number : DE-FG02-86ER13615  

SciTech Connect (OSTI)

Title: Catalytic Hydrogenation of Carbon Monoxide and Olefin Oxidation Grant No. DE-FG02-86ER13615 PI: Wayland, B. B. (wayland@sas.upenn.edu) Abstract Development of new mechanistic strategies and catalyst materials for activation of CO, H2, CH4, C2H4, O2, and related substrates relevant to the conversion of carbon monoxide, alkanes, and alkenes to organic oxygenates are central objectives encompassed by this program. Design and synthesis of metal complexes that manifest reactivity patterns associated with potential pathways for the hydrogenation of carbon monoxide through metallo-formyl (M-CHO), dimetal ketone (M-C(O)-M), and dimetal dionyl (M-C(O)-C(O)-M) species is one major focus. Hydrocarbon oxidation using molecular oxygen is a central goal for methane activation and functionalization as well as regioselective oxidation of olefins. Discovery of new reactivity patterns and control of selectivity are pursued through designing new metal complexes and adjusting reaction conditions. Variation of reaction media promotes distinct reaction pathways that control both reaction rates and selectivities. Dimetalloradical diporphyrin complexes preorganize transition states for substrate reactions that involve two metal centers and manifest large rate increases over mono-metalloradical reactions of hydrogen, methane, and other small molecule substrates. Another broad goal and recurring theme of this program is to contribute to the thermodynamic database for a wide scope of organo-metal transformations in a range of reaction media. One of the most complete descriptions of equilibrium thermodynamics for organometallic reactions in water and methanol is emerging from the study of rhodium porphyrin substrate reactions in aqueous and alcoholic media. Water soluble group nine metalloporphyrins manifest remarkably versatile substrate reactivity in aqueous and alcoholic media which includes producing rhodium formyl (Rh-CHO) and hydroxy methyl (Rh-CH2OH) species. Exploratory directions for this program include expending new strategies for anti-Markovnikov addition of water, alcohols, and amines with olefins, developing catalytic reactions of CO to give formamides and formic esters, and evaluating the potential for coupling reactions of CO to produce organic building blocks.

Wayland, B.B.

2009-08-31T23:59:59.000Z

326

Five blind men and the elephant: what can the NASA Aura ozone measurements tell us about stratosphere-troposphere exchange?  

E-Print Network [OSTI]

Five blind men and the elephant: what can the NASA Auraof the five blind men and the elephant, where the five Auramen” who are touching the “elephant” (ozone) in dif- ferent

Tang, Q.; Prather, M. J

2012-01-01T23:59:59.000Z

327

Climate change, ambient ozone, and health in 50 US cities Michelle L. Bell & Richard Goldberg & Christian Hogrefe &  

E-Print Network [OSTI]

Climate change, ambient ozone, and health in 50 US cities Michelle L. Bell & Richard Goldberg Haven, CT 06511, USA e-mail: michelle.bell@yale.edu R. Goldberg Center for Climate Systems Research emissions of volatile organic compounds (VOCs),

328

Re-evaluation of total and Umkehr ozone data from NOAA-CMDL Dobson spectrophotometer observatories. Final report  

SciTech Connect (OSTI)

This report describes work to improve the quality of total ozone and Umkehr data obtained in the past at the NOAA Climate Monitoring and Diagnostics Laboratory and the Dobson spectrophotometer ozone observatories. The authors present results of total ozone data re-evaluations for ten stations: Byrd, Antarctica; Fairbanks, Alaska; Hallett, Antarctica; Huancayo, Peru; Haute Provence, France; Lauder, New Zealand; Perth, Australia; Poker Flat, Alaska; Puerto Montt, Chile; and South Pole, Antarctica. The improved data will be submitted in early 1996 to the World Meteorological Organization (WMO) World Ozone Data Center (WODC), and the Atmospheric Environment Service for archiving. Considerable work has been accomplished, also, in reevaluating Umkehr data from seven of the stations, viz., Huancayo, Haute Provence, Lauder, Perth, Poker Flat, Boulder, Colorado; and Mauna Loa, Hawaii.

Komhyr, W.D.; Quincy, D.M.; Grass, R.D.; Koenig, G.L. [Univ. of Colorado, Boulder, CO (United States)] [Univ. of Colorado, Boulder, CO (United States); [National Oceanic and Atmospheric Administration, Boulder, CO (United States). Climate Monitoring and Diagnostics Lab.

1995-12-01T23:59:59.000Z

329

Effects of a modular two-step ozone-water and annealing process on silicon carbide graphene  

SciTech Connect (OSTI)

By combining ozone and water, the effect of exposing epitaxial graphene on silicon carbide to an aggressive wet-chemical process has been evaluated after high temperature annealing in ultra high vacuum. The decomposition of ozone in water produces a number of oxidizing species, however, despite long exposure times to the aqueous-ozone environment, no graphene oxide was observed after the two-step process. The systems were comprehensively characterized before and after processing using Raman spectroscopy, core level photoemission spectroscopy, and angle resolved photoemission spectroscopy together with low energy electron diffraction, low energy electron microscopy, and atomic force microscopy. In spite of the chemical potential of the aqueous-ozone reaction environment, the graphene domains were largely unaffected raising the prospect of employing such simple chemical and annealing protocols to clean or prepare epitaxial graphene surfaces.

Webb, Matthew J., E-mail: matthew.webb@cantab.net; Lundstedt, Anna; Grennberg, Helena [Department of Chemistry—BMC, Uppsala University, Box 576, SE-751 23 Uppsala (Sweden); Polley, Craig; Niu, Yuran; Zakharov, Alexei A.; Balasubramanian, Thiagarajan [MAX IV Laboratory, Lund University, 22100 Lund (Sweden); Dirscherl, Kai [DFM—Danish Fundamental Metrology, Matematiktorvet 307, DK-2800 Lyngby (Denmark); Burwell, Gregory; Guy, Owen J. [College of Engineering, Faraday Tower, Singleton Park, Swansea University, Swansea SA2 8PP (United Kingdom); Palmgren, Pål [VG Scienta Scientific AB, Box 15120, Vallongatan 1, SE-750 15 Uppsala (Sweden); Yakimova, Rositsa [Department of Physics, Chemistry, and Biology, Linköping University, SE-581 83 Linköping (Sweden)

2014-08-25T23:59:59.000Z

330

Past and Future Effects of Ozone on Net Primary Production and Carbon Sequestration Using a Global Biogeochemical Model  

E-Print Network [OSTI]

Exposure of plants to ozone inhibits photosynthesis and therefore reduces vegetation production and carbon sequestration. Simulations with the Terrestrial Ecosystem Model (TEM) for the historical period (1860-1995) show ...

Felzer, Benjamin Seth.

331

Ozone effects on net primary production and carbon sequestration in the conterminous United States using a biogeochemistry model  

E-Print Network [OSTI]

The effects of air pollution on vegetation may provide an important control on the carbon cycle that has not yet been widely considered. Prolonged exposure to high levels of ozone, in particular, has been observed to inhibit ...

Felzer, Benjamin Seth.; Kicklighter, David W.; Melillo, Jerry M.; Wang, Chien.; Zhuang, Qianlai.; Prinn, Ronald G.

332

Quantum-chemical investigation of the interaction of nitrogen and carbon monoxide molecules with the Lewis acid sites of aluminium oxide  

SciTech Connect (OSTI)

Within the framework of the cluster approximation, using covalent and ionic models of Lewis acid sites of aluminumoxide, their electronic structure, as well as that of complexes of nitrogen and carbon monoxide molecules with them, was calculated. It was shown that the Lewis acid sites, representing a truncated tetrahedron, exhibit stronger electron-acceptor properties than the corresponding sites in the form of a truncated octahedron. For both molecules, the linear form of adsorption is energetically more profitable than the T-shaped form. The results obtained by the nonempirical SCF MO LCAO method in the STO-3GF basis and by semiempirical methods in CNDO/2 and INDO approximatations, are qualitatively the same.

Senchenya, I.N.; Chuvylkin, N.D.; Kazanskii, V.B.

1986-11-01T23:59:59.000Z

333

Demonstration of Advanced Technologies for Multi-Load Washers in Hospitality and Healthcare – Ozone Based Laundry Systems  

SciTech Connect (OSTI)

The objective of this demonstration project was to evaluate market-ready retrofit technologies for reducing the energy and water use of multi-load washers in healthcare and hospitality facilities. Specifically, this project evaluated laundry wastewater recycling technology in the hospitality sector and ozone laundry technology in both the healthcare and hospitality sectors. This report documents the demonstration of ozone laundry system installations at the Charleston Place Hotel in Charleston, Sout Carolina, and the Rogerson House assisted living facility in Boston, Massachusetts.

Boyd, Brian K.; Parker, Graham B.; Petersen, Joseph M.; Sullivan, Greg; Goetzler, W.; Sutherland, T. A.; Foley, K. J.

2014-08-14T23:59:59.000Z

334

Surfactants containing radioactive run-offs: Ozone treatment, influence on nuclear power plants water waste special treatment  

SciTech Connect (OSTI)

The authors discuss the problems encountered in the efficiency of radioactive waste treatment in nuclear power plants in Kursk. The ozonization of aqueous solutions of surfactants was carried out in the laboratory`s ozonization system. The surfactants which are discharged to the ion exchangers deteriorate resins, clog up the ion exchangers, and decrease filtration velocity. Therefore, this investigation focused on finding a method to increase the efficiency of this treatment process.

Prokudina, S.A.; Grachok, M.A. [Belarussian State Economic Univ., Minsk (Belarus)

1993-12-31T23:59:59.000Z

335

Corrosion by liquid lead and lead-bismuth: experimental results review and analysis  

SciTech Connect (OSTI)

Liquid metal technologies for liquid lead and lead-bismuth alloy are under wide investigation and development for advanced nuclear energy systems and waste transmutation systems. Material corrosion is one of the main issues studied a lot recently in the development of the liquid metal technology. This study reviews corrosion by liquid lead and lead bismuth, including the corrosion mechanisms, corrosion inhibitor and the formation of the protective oxide layer. The available experimental data are analyzed by using a corrosion model in which the oxidation and scale removal are coupled. Based on the model, long-term behaviors of steels in liquid lead and lead-bismuth are predictable. This report provides information for the selection of structural materials for typical nuclear reactor coolant systems when selecting liquid lead or lead bismuth as heat transfer media.

Zhang, Jinsuo [Los Alamos National Laboratory

2008-01-01T23:59:59.000Z

336

Sustainability Peer Educator Group Lead Positions Position: Sustainability Peer Educators Group Lead  

E-Print Network [OSTI]

Sustainability Peer Educator Group Lead Positions Position: Sustainability Peer Educators Group times) Term of position: September 2013 ­ April 2014 Position Summary: Working with the Sustainability Project Coordinator, the Sustainability Peer Educator Group Leads will be responsible

Boonstra, Rudy

337

Lightweight, durable lead-acid batteries  

DOE Patents [OSTI]

A lightweight, durable lead-acid battery is disclosed. Alternative electrode materials and configurations are used to reduce weight, to increase material utilization and to extend service life. The electrode can include a current collector having a buffer layer in contact with the current collector and an electrochemically active material in contact with the buffer layer. In one form, the buffer layer includes a carbide, and the current collector includes carbon fibers having the buffer layer. The buffer layer can include a carbide and/or a noble metal selected from of gold, silver, tantalum, platinum, palladium and rhodium. When the electrode is to be used in a lead-acid battery, the electrochemically active material is selected from metallic lead (for a negative electrode) or lead peroxide (for a positive electrode).

Lara-Curzio, Edgar (Lenoir City, TN); An, Ke (Knoxville, TX); Kiggans, Jr., James O. (Oak Ridge, TN); Dudney, Nancy J. (Knoxville, TN); Contescu, Cristian I. (Knoxville, TN); Baker, Frederick S. (Oak Ridge, TN); Armstrong, Beth L. (Clinton, TN)

2011-09-13T23:59:59.000Z

338

Lightweight, durable lead-acid batteries  

SciTech Connect (OSTI)

A lightweight, durable lead-acid battery is disclosed. Alternative electrode materials and configurations are used to reduce weight, to increase material utilization and to extend service life. The electrode can include a current collector having a buffer layer in contact with the current collector and an electrochemically active material in contact with the buffer layer. In one form, the buffer layer includes a carbide, and the current collector includes carbon fibers having the buffer layer. The buffer layer can include a carbide and/or a noble metal selected from of gold, silver, tantalum, platinum, palladium and rhodium. When the electrode is to be used in a lead-acid battery, the electrochemically active material is selected from metallic lead (for a negative electrode) or lead peroxide (for a positive electrode).

Lara-Curzio, Edgar; An, Ke; Kiggans, Jr., James O; Dudney, Nancy J; Contescu, Cristian I; Baker, Frederick S; Armstrong, Beth L

2013-05-21T23:59:59.000Z

339

INEEL Lead Recycling in a Moratorium Environment  

SciTech Connect (OSTI)

Since 1999, the Idaho National Engineering and Environmental Laboratory (INEEL) Lead Project successfully recycled over 700,000 pounds of excess INEEL lead to the private sector. On February 14, 2000, the Secretary of Energy, Bill Richardson, formalized the January 12, 2000, moratorium on recycling radioactive scrap metal that prevented the unrestricted release of recycled scrap metals to the private sector. This moratorium created significant problems for the INEEL lead recycling program and associated plans; however, through the cooperative efforts of the INEEL and Idaho State University as well as innovative planning and creative thinking the recycling issues were resolved. This collaboration has recycled over 160,000 pounds of excess lead to Idaho State University with a cost savings of over $.5M.

Kooda, K. E.; Galloway, K.; McCray, C. W.; Aitken, D. W.

2003-02-26T23:59:59.000Z

340

INEEL Lead Recycling in a Moratorium Environment  

SciTech Connect (OSTI)

Since 1999, the Idaho National Engineering and Environmental Laboratory (INEEL) Lead Project successfully recycled over 700,000 pounds of excess INEEL lead to the private sector. On February 14, 2000, the Secretary of Energy, Bill Richardson, formalized the January 12, 2000, moratorium on recycling radioactive scrap metal that prevented the unrestricted release of recycled scrap metals to the private sector. This moratorium created significant problems for the INEEL lead recycling program and associated plans; however, through the cooperative efforts of the INEEL and Idaho State University as well as innovative planning and creative thinking the recycling issues were resolved. This collaboration has recycled over 160,000 pounds of excess lead to Idaho State University with a cost savings of over $.5M.

Kooda, Kevin Evan; Mc Cray, Casey William; Aitken, Darren William; Galloway, Kelly

2003-02-01T23:59:59.000Z

Note: This page contains sample records for the topic "monoxide ozone lead" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Imnaha Subbasin Management Plan Subbasin Lead Entity  

E-Print Network [OSTI]

Imnaha Subbasin Management Plan May 2004 Written by Ecovista Subbasin Lead Entity: Nez Perce Tribe....................................................................................... 6 1.2.4 Ecovista Website Information.......................................................................... 59 4.3 Terrestrial Data and Information Gaps

342

Saturnine curse: a history of lead poisoning  

SciTech Connect (OSTI)

Over the past ten years there has been increasing recognition of subacute and chronic lead poisoning and a growing awareness of its pathophysiology and clinical effects. Besides the classic manifestations of abdominal colic, seizures, and anemia progressing to gout, renal disease, and neuropathy, more subtle manifestations are now being increasingly recognized, such as the development of hypertension, neurobehavioral changes, reproductive and endocrine abnormalities, a possible role in carcinogenesis, and an overall increase in morbidity and mortality. Lead was one of the seven metals of antiquity, and it has accompanied the Eurasian and American civilizations since their beginnings. Lead is an extremely pernicious metal with a multitude of adverse effects. The recurring nature of lead poisoning throughout the development of civilization can truly be referred to as the saturnine curse. 16 references.

Green, D.W.

1985-01-01T23:59:59.000Z

343

Primer on lead-acid storage batteries  

SciTech Connect (OSTI)

This handbook was developed to help DOE facility contractors prevent accidents caused during operation and maintenance of lead-acid storage batteries. Major types of lead-acid storage batteries are discussed as well as their operation, application, selection, maintenance, and disposal (storage, transportation, as well). Safety hazards and precautions are discussed in the section on battery maintenance. References to industry standards are included for selection, maintenance, and disposal.

NONE

1995-09-01T23:59:59.000Z

344

Information from leading neutrons at HERA  

E-Print Network [OSTI]

In principle, leading neutrons produced in photoproduction and deep-inelastic scattering at HERA have the potential to determine the pion structure function, the neutron absorptive cross section and the form of the pion flux. To explore this potential we compare theoretical predictions for the x_L and p_t spectra of leading neutrons, and the Q^2 dependence of the cross section, with the existing ZEUS data.

V. A. Khoze; A. D. Martin; M. G. Ryskin

2006-06-20T23:59:59.000Z

345

Membrane contactor/separator for an advanced ozone membrane reactor for treatment of recalcitrant organic pollutants in water  

SciTech Connect (OSTI)

An advanced ozone membrane reactor that synergistically combines membrane distributor for ozone gas, membrane contactor for pollutant adsorption and reaction, and membrane separator for clean water production is described. The membrane reactor represents an order of magnitude improvement over traditional semibatch reactor design and is capable of complete conversion of recalcitrant endocrine disrupting compounds (EDCs) in water at less than three minutes residence time. Coating the membrane contactor with alumina and hydrotalcite (Mg/Al=3) adsorbs and traps the organics in the reaction zone resulting in 30% increase of total organic carbon (TOC) removal. Large surface area coating that diffuses surface charges from adsorbed polar organic molecules is preferred as it reduces membrane polarization that is detrimental to separation. - Graphical abstract: Advanced ozone membrane reactor synergistically combines membrane distributor for ozone, membrane contactor for sorption and reaction and membrane separator for clean water production to achieve an order of magnitude enhancement in treatment performance compared to traditional ozone reactor. Highlights: Black-Right-Pointing-Pointer Novel reactor using membranes for ozone distributor, reaction contactor and water separator. Black-Right-Pointing-Pointer Designed to achieve an order of magnitude enhancement over traditional reactor. Black-Right-Pointing-Pointer Al{sub 2}O{sub 3} and hydrotalcite coatings capture and trap pollutants giving additional 30% TOC removal. Black-Right-Pointing-Pointer High surface area coating prevents polarization and improves membrane separation and life.

Chan, Wai Kit, E-mail: kekyeung@ust.hk [Department of Chemical and Biomolecular Engineering, Hong Kong University of Science and Technology, Clear Water Bay, Kowloon (Hong Kong); Joueet, Justine; Heng, Samuel; Yeung, King Lun [Department of Chemical and Biomolecular Engineering, Hong Kong University of Science and Technology, Clear Water Bay, Kowloon (Hong Kong); Schrotter, Jean-Christophe [Water Research Center of Veolia, Anjou Recherche, Chemin de la Digue, BP 76. 78603, Maisons Laffitte, Cedex (France)

2012-05-15T23:59:59.000Z

346

A study of ozone in the surface layer of Kiev and its impact on the human health  

E-Print Network [OSTI]

Ground-level ozone in Kiev for an episode of its high concentration in August 2000 was simulated with the model of the urban air pollution UAM-V (Urban Airshed Model). The study of total ozone over Kiev and its concentration changes with height in the troposphere is made on the basis of ground-based observations with the infrared Fourier spectrometer at the Main Astronomical Observatory of National Academy of Sciences of Ukraine as a part of the ESA-NIVR-KNMI no 2907. In 2008 the satellite Aura-OMI data OMO3PR on the atmosphere ozone profiles became available. Beginning in 2005, these data include the ozone concentration in the lower layer of the atmosphere and can be used for the evaluation of the ground-level ozone concentrations in all cities of Ukraine. Some statistical investigation of ozone air pollution in Kiev and medical statistics data on respiratory system was carried out with the application of the "Statistica" package. The regression analysis, prognostic regression simulation, and retrospective p...

Shavrina, A V; Kiforenko, S I; Sheminova, V A; Veles, A A; Blum, O B

2012-01-01T23:59:59.000Z

347

Synthesis of the entire standard lead electrocardiogram by transformation from a subset of the standard leads  

E-Print Network [OSTI]

in dimensionless form. An individual element r&& in the correlation matrix R will be the correlation coefficient th th between the i and ] variables. The principal components are the eigenvectors of the correlation matrix and the corresponding eigen- values...) and using the other lead as an exploring lead. Another classification is based on the location of the lead, that is, direct, semi-direct, or indirect. A direct lead is placed on the heart, an indirect lead is placed at a body surface location distant from...

Vallhonrat, Juan Braulio

1966-01-01T23:59:59.000Z

348

Resonating Valence Bond Quantum Monte Carlo: Application to the ozone molecule  

E-Print Network [OSTI]

We study the potential energy surface of the ozone molecule by means of Quantum Monte Carlo simulations based on the resonating valence bond concept. The trial wave function consists of an antisymmetrized geminal power arranged in a single-determinant that is multiplied by a Jastrow correlation factor. Whereas the determinantal part incorporates static correlation effects, the augmented real-space correlation factor accounts for the dynamics electron correlation. The accuracy of this approach is demonstrated by computing the potential energy surface for the ozone molecule in three vibrational states: symmetric, asymmetric and scissoring. We find that the employed wave function provides a detailed description of rather strongly-correlated multi-reference systems, which is in quantitative agreement with experiment.

Azadi, Sam; Kühne, Thomas D

2015-01-01T23:59:59.000Z

349

Total Ozone Mapping Spectrometer (TOMS) Derived Data, Global Earth Coverage (GEC) from NASA's Earth Probe Satellite  

DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

This is data from an external datastream processed through the ARM External Data Center (XDC) at Brookhaven National Laboratory. The XDC identifies sources and acquires data, called "external data", to augment the data being generated within the ARM program. The external data acquired are usually converted from native format to either netCDF or HDF formats. The GEC collection contains global data derived from the Total Ozone Mapping Spectrometer (TOMS) instrument on the Earth Probe satellite, consisting of daily values of aerosol index, ozone and reflectivity remapped into a regular 1x1.25 deg grid. Data are available from July 25, 1996 - December 31, 2005, but have been updated or replaced as of September 2007. See the explanation on the ARM web site at http://www.arm.gov/xds/static/toms.stm and the information at the NASA/TOMS web site: http://toms.gsfc.nasa.gov/ (Registration required)

350

Past changes in the vertical distribution of ozone – Part 1: Measurement techniques, uncertainties and availability  

E-Print Network [OSTI]

, Germany 28Research Institute for Sustainable Humanosphere, Kyoto University, Kyoto, Japan 29Association of International Research Initiatives for Environmental Studies, Tokyo, Japan 30Research Centre Jülich, Institute for Energy and Climate Research... Sciences, Göteborg, Sweden Published by Copernicus Publications on behalf of the European Geosciences Union. 1396 B. Hassler et al.: Ozone profile measurements 34Institut für Physik, Ernst-Moritz-Arndt-Universität Greifswald, Greifswald, Germany 35...

Hassler, B.; Petropavlovskikh, I.; Staehelin, J.; August, T.; Bhartia, P. K.; Clerbaux, C.; Degenstein, D.; Maziere, M. De; Dinelli, B. M.; Dudhia, A.; Dufour, G.; Frith, S. M.; Froidevaux, L.; Godin-Beekmann, S.; Granville, J.; Harris, N. R. P.; Hoppel, K.; Hubert, D.; Kasai, Y.; Kurylo, M. J.; Kyrola, E.; Lambert, J.-C.; Levelt, P. F.; McElroy, C. T.; McPeters, R. D.; Munro, R.; Nakajima, H.; Parrish, A.; Raspollini, P.; Remsberg, E. E.; Rosenlof, K. H.; Rozanov, A.; Sano, T.; Sasano, Y.; Shiotani, M.; Smit, H. G. J.; Stiller, G.; Tamminen, J.; Tarasick, D. W.; Urban, J.; van der A, R. J.; Veefkind, J. P.; Vigouroux, C.; von Clarmann, T.; von Savigny, C.; Walker, K. A.; Weber, M.; Wild, J.; Zawodny, J. M.

2014-05-21T23:59:59.000Z

351

An assessment of alternatives and technologies for replacing ozone- depleting substances at DOE facilities  

SciTech Connect (OSTI)

Title VI of the Clean Air Act, as amended, mandates a production phase-out for ozone-depleting substances (ODSs). These requirements will have a significant impact on US Department of Energy (DOE) facilities. Currently, DOE uses ODSs in three major activities: fire suppression (halon), refrigeration and cooling (chlorofluorocarbons [CFCs]), and cleaning that requires solvents (CFCs, methyl chloroform, and carbon tetrachloride). This report provides basic information on methods and strategies to phase out use of ODSs at DOE facilities.

Purcell, C.W.; Miller, K.B.; Friedman, J.R.; Rapoport, R.D.; Conover, D.R.; Hendrickson, P.L. [Pacific Northwest Lab., Richland, WA (United States); Koss, T.C. [USDOE Assistant Secretary for Environment, Safety, and Health, Washington, DC (United States). Office of Environmental Guidance

1992-10-01T23:59:59.000Z

352

Relationship between rubisco sulfhydryl content and relative sensitivity of potato cultivars to ozone  

SciTech Connect (OSTI)

Ozone (O{sub 3}) induced a reduction in quantity of rubisco in potato foliage. In vitro, O{sub 3} predisposed purified rubisco to elevated proteolysis; reagents which protected sulfhydryl (SH) groups suppressed this effect. We hypothesized that rubisco SH content correlated directly with foliar O{sub 3} sensitivity. Rubisco was purified from Solanum tuberosum L. O{sub 3}-tolerant cv. Superior (SP) and Norgold Russet (NR), and O{sub 3}-susceptible cv. Norland (NL) and Cherokee (CK). When native rubisco was titrated with DTNB, protein of NL contained 1.33 and 1.26 times more SH groups than SP and NR, respectively. Rubisco from CK also contained more SH groups than SP and NR, but the difference was not significant. Rubisco of SP, NR and CK denatured by SDS exhibited identical number of SH groups, however, NL exhibited 1.15 times more SH groups. The greater number of SH groups in rubisco from NL versus SP and NR may explain its relative sensitivity to ozone. The role of SH groups in ozone-sensitivity of CK will require further study.

Enyedi, A.J.; Pell, E.J. (Pennsylvania State Univ., University Park (USA))

1989-04-01T23:59:59.000Z

353

Secondary organic aerosol from ozone-initiated reactions with terpene-rich household products  

SciTech Connect (OSTI)

We analyzed secondary organic aerosol (SOA) data from a series of small-chamber experiments in which terpene-rich vapors from household products were combined with ozone under conditions analogous to product use indoors. Reagents were introduced into a continuously ventilated 198 L chamber at steady rates. Consistently, at the time of ozone introduction, nucleation occurred exhibiting behavior similar to atmospheric events. The initial nucleation burst and growth was followed by a period in which approximately stable particle levels were established reflecting a balance between new particle formation, condensational growth, and removal by ventilation. Airborne particles were measured with a scanning mobility particle sizer (SMPS, 10 to 400 nm) in every experiment and with an optical particle counter (OPC, 0.1 to 2.0 ?m) in a subset. Parameters for a three-mode lognormal fit to the size distribution at steady state were determined for each experiment. Increasing the supply ozone level increased the steady-state mass concentration and yield of SOA from each product tested. Decreasing the air-exchange rate increased the yield. The steady-state fine-particle mass concentration (PM1.1) ranged from 10 to> 300 mu g m-3 and yields ranged from 5percent to 37percent. Steady-state nucleation rates and SOA mass formation rates were on the order of 10 cm-3 s-1 and 10 mu g m-3 min-1, respectively.

Coleman, Beverly; Coleman, Beverly K.; Lunden, Melissa M.; Destaillats, Hugo; Nazaroff, William W.

2008-01-01T23:59:59.000Z

354

Effects of ozone on the respiratory health, allergic sensitization, and cellular immune system in children  

SciTech Connect (OSTI)

To investigate the lasting effects of high ozone concentrations under environmental conditions, we examined the respiratory health, pulmonary function, bronchial hyperresponsiveness to methacholine, allergic sensitization, and lymphocyte subpopulations of 10- to 14-yr-old children. A total of 218 children recruited from an area with high ozone concentrations (Group A) were tested against 281 children coming from an area with low ozone concentrations (Group B). As to subjective complaints, categorized as 'usually cough with or without phlegm,' 'breathlessness,' and 'susceptibility to chest colds,' there was no difference between the two groups. The lung function parameters were similar, but in Group A subjects' bronchial hyperresponsiveness occurred more frequently and was found to be more severe than in Group B (29.4 versus 19.9%, p less than 0.02; PD20 2,100 {plus minus} 87 versus 2,350 {plus minus} 58 micrograms, p less than 0.05). In both groups the number of children who had been suffering from allergic diseases and sensitization to aeroallergens, found by means of the skin test, was the same. Comparison of the total IgE levels showed no difference at all between the two groups. As far as the white blood cells are concerned, the total and differential cell count was the same, whereas lymphocyte subpopulations showed readily recognizable changes.

Zwick, H.; Popp, W.; Wagner, C.; Reiser, K.; Schmoeger, J.B.; Boeck, A.H.; Herkner, K.; Radunsky, K. (Pulmonary Department, Krankenhaus Lainz, Vienna (Austria))

1991-11-01T23:59:59.000Z

355

Thermoforming plastic in lead shield construction  

SciTech Connect (OSTI)

Radiation treatments using low energy X-rays or electrons frequently require a final field defining shield to be placed on the patient's skin. A custom made lead cut-out is used to provide a close fit to a particular patient's surface contours. We have developed a procedure which utilizes POLYFORM thermoplastic to obtain a negative mold of the patient instead of the traditional plaster bandage or dental impression gel. The Polyform is softened in warm water, molded carefully over the patient's surface, and is removed when set or hardened, usually within five minutes. Then lead sheet cut-outs can be formed within this negative. For shielding cut-outs requiring thicker lead sheet, a positive is made from dental stone using this Polyform negative. We have found this procedure to be neat, fast and comfortable for both patient and the dosimetrist.

Abrahams, M.E.; Chow, C.H.; Loyd, M.D. (Univ. of Texas Medical Branch, Galveston (USA))

1989-09-01T23:59:59.000Z

356

Multi-model Estimates of Intercontinental Source-Receptor Relationships for Ozone Pollution  

SciTech Connect (OSTI)

Understanding the surface O{sub 3} response over a 'receptor' region to emission changes over a foreign 'source' region is key to evaluating the potential gains from an international approach to abate ozone (O{sub 3}) pollution. We apply an ensemble of 21 global and hemispheric chemical transport models to estimate the spatial average surface O{sub 3} response over East Asia (EA), Europe (EU), North America (NA) and South Asia (SA) to 20% decreases in anthropogenic emissions of the O{sub 3} precursors, NO{sub x}, NMVOC, and CO (individually and combined), from each of these regions. We find that the ensemble mean surface O{sub 3} concentrations in the base case (year 2001) simulation matches available observations throughout the year over EU but overestimates them by >10 ppb during summer and early fall over the eastern U.S. and Japan. The sum of the O{sub 3} responses to NO{sub x}, CO, and NMVOC decreases separately is approximately equal to that from a simultaneous reduction of all precursors. We define a continental-scale 'import sensitivity' as the ratio of the O{sub 3} response to the 20% reductions in foreign versus 'domestic' (i.e., over the source region itself) emissions. For example, the combined reduction of emissions from the 3 foreign regions produces an ensemble spatial mean decrease of 0.6 ppb over EU (0.4 ppb from NA), less than the 0.8 ppb from the reduction of EU emissions, leading to an import sensitivity ratio of 0.7. The ensemble mean surface O{sub 3} response to foreign emissions is largest in spring and late fall (0.7-0.9 ppb decrease in all regions from the combined precursor reductions in the 3 foreign regions), with import sensitivities ranging from 0.5 to 1.1 (responses to domestic emission reductions are 0.8-1.6 ppb). High O{sub 3} values are much more sensitive to domestic emissions than to foreign emissions, as indicated by lower import sensitivities of 0.2 to 0.3 during July in EA, EU, and NA when O{sub 3} levels are typically highest, and by the weaker relative response of annual incidences of daily maximum 8-hour average O{sub 3} above 60 ppb to emission reductions in a foreign region (<10-20% of that to domestic) as compared to the annual mean response (up to 50% of that to domestic). Applying the ensemble annual mean results to changes in anthropogenic emissions from 1996 to 2002, we estimate a Northern Hemispheric increase in background surface O{sub 3} of about 0.1 ppb yr{sup -1}, at the low end of the 0.1-0.5 ppb yr{sup -1} derived from observations. From an additional simulation in which global atmospheric methane was reduced, we infer that 20% reductions in anthropogenic methane emissions from a foreign source region would yield an O{sub 3} response in a receptor region that roughly equals that produced by combined 20% reductions of anthropogenic NO{sub x}, NMVOC and CO emissions from the foreign source region.

Fiore, A M; Dentener, F J; Wild, O; Cuvelier, C; Schultz, M G; Hess, P; Textor, C; Schulz, M; Doherty, R; Horowitz, L W; MacKenzie, I A; Sanderson, M G; Shindell, D T; Stevenson, D S; Szopa, S; Van Dingenen, R; Zeng, G; Atherton, C; Bergmann, D; Bey, I; Carmichael, G; Collins, W J; Duncan, B N; Faluvegi, G; Folberth, G; Gauss, M; Gong, S; Hauglustaine, D; Holloway, T; Isaksen, I A; Jacob, D J; Jonson, J E; Kaminski, J W; Keating, T J; Lupu, A; Marmer, E; Montanaro, V; Park, R; Pitari, G; Pringle, K J; Pyle, J A; Schroeder, S; Vivanco, M G; Wind, P; Wojcik, G; Wu, S; Zuber, A

2008-10-16T23:59:59.000Z

357

Leading Edge Bacterial Genomics and Pathogen Evolution  

E-Print Network [OSTI]

Leading Edge Review Bacterial Genomics and Pathogen Evolution David M. Raskin,1 Rekha Seshadri,2 Medical School, Boston, MA 02115, USA 2 The Institute for Genomic Research, 9712 Medical Center Drive.02.002 The availability of hundreds of bacterial genome sequences has altered the study of bacte- rial pathogenesis

Mekalanos, John

358

Mechanisms leading to electrically isolated cell  

E-Print Network [OSTI]

Mechanisms leading to electrically isolated cell parts and power loss under mechanical loads F cracks are omnipresent #12;Power loss by cell cracks Humidity freeze cycle 0 50 100 150 200 Powerloss, isolated cell area Crack mode: #12;Power loss after mechanical load · Some solar cells with mode A cracks

359

Analyzing lead information from SAR images  

E-Print Network [OSTI]

means of gathering important information about the sea ice cover and its climatic influence, This paper describes: 1) a method for extracting and analyzing leads from ERS-1 synthetic aperture radar (SAR) images classified by ice type and 2) the results...

Van Dyne, M. M.; Tsatsoulis, Costas; Fetterer, F.

1998-03-01T23:59:59.000Z

360

Inadvertent Climate Modification Due to Anthropogenic Lead  

SciTech Connect (OSTI)

The relationship between atmospheric particulate matter and the formation of clouds is among the most uncertain aspects of our current understanding of climate change1. One specific question that remains unanswered is how anthropogenic particulate emissions are affecting the nucleation of ice crystals. Satellites show ice clouds cover more than a third of the globe2 and models suggest that ice nucleation initiates the majority of terrestrial precipitation3. It is therefore not possible to adequately understand either climate change or the global water cycle without understanding ice nucleation. Here we show that lead-containing particles are among the most efficient ice nucleating substances commonly found in the atmosphere. Field observations were conducted with mass spectrometry and electron microscopy at two remote stations on different continents, far removed from local emissions. Laboratory studies within two cloud chambers using controlled experimental conditions support the field data. Because the dominate sources of particulate lead are anthropogenic emissions such as aviation fuel, power generation, smelting, and the re-suspension of residue from tetra-ethyl leaded gasoline4, it is likely that cloud formation and precipitation have been affected when compared to pre-industrial times. A global climate model comparing pre-industrial and anthropogenically perturbed conditions shows that lead-containing particles may be increasing the outgoing longwave radiation by 0.2 to 0.8 W m-2, thereby offsetting a portion of the warming attributed to greenhouse gases1.

Cziczo, Daniel J.; Stetzer, Olaf; Worringen, Annette; Ebert, Martin; Weinbruch, Stephan; Kamphus, M.; Gallavardin, S. J.; Curtius, J.; Borrmann, S.; Froyd, Karl D.; Mertes, S.; Mohler, Ottmar; Lohmann, U.

2009-05-01T23:59:59.000Z

Note: This page contains sample records for the topic "monoxide ozone lead" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

The Commonwealth's Leading College of Engineering  

E-Print Network [OSTI]

and Ocean Engineering....................540-231-6611 Biological Systems EngineeringThe Commonwealth's Leading College of Engineering is at Virginia Tech Faculty ExpErtisE GuidE 2012-2014 Virginia Tech engineering students won the international EcoCAR Challenge, a 3-year design competition

Virginia Tech

362

Felix Wrsten ETH Zurich enjoys a leading  

E-Print Network [OSTI]

Felix Würsten ETH Zurich enjoys a leading position in the quantum sciences. The Executive Board now research in this area. "ETH Zurich has secured it- self a good starting position and now wishes to use physics will become the tool of the engineer." Fundamental development Together with the ETH Zurich Foun

Leonardo, Degiorgi

363

Quality Support G. Q. Kirk, Lead (4)  

E-Print Network [OSTI]

) Quality Systems and Services Division February 11, 2011 Operations Analysis E. L. Griffis L. R. Brown, Secy. Systems Engineering Y. S. Kwon, Manager HFIR Maintenance D. H. AbercQuality Support G. Q. Kirk, Lead (4) R. L. Bullock (4) A. C. Hendricks (4) G. H. Henkel (4) D. L

364

Lead in Your Drinking Water Lead (Pb) is an extremely toxic heavy metal that unfortunately occurs widely in  

E-Print Network [OSTI]

Lead in Your Drinking Water Lead (Pb) is an extremely toxic heavy metal that unfortunately occurs of metallic lead in the soil (4) Drinking water ­ water as it leaves the treatment plant has no lead plumbing components Your exposure to lead in drinking water is at the faucet, but the lead can come from

Maynard, J. Barry

365

Ozone generation by negative direct current corona discharges in dry air fed coaxial wire-cylinder reactors  

SciTech Connect (OSTI)

An analytical study was made in this paper for calculating the ozone generation by negative dc corona discharges. The corona discharges were formed in a coaxial wire-cylinder reactor. The reactor was fed by dry air flowing with constant rates at atmospheric pressure and room temperature, and stressed by a negative dc voltage. The current-voltage characteristics of the negative dc corona discharges formed inside the reactor were measured in parallel with concentration of the generated ozone under different operating conditions. An empirical equation was derived from the experimental results for calculating the ozone concentration generated inside the reactor. The results, that have been recalculated by using the derived equation, have agreed with the experimental results over the whole range of the investigated parameters, except in the saturation range for the ozone concentration. Therefore, the derived equation represents a suitable criterion for expecting the ozone concentration generated by negative dc corona discharges in dry air fed coaxial wire-cylinder reactors under any operating conditions in range of the investigated parameters.

Yehia, Ashraf [Department of Physics, Faculty of Science, Assiut University, Assiut 71516, Egypt and Department of Physics, College of Science and Humanitarian Studies in Alkharj, Salman bin Abdulaziz University, P.O. Box 83, Alkharj 11942 (Saudi Arabia)] [Department of Physics, Faculty of Science, Assiut University, Assiut 71516, Egypt and Department of Physics, College of Science and Humanitarian Studies in Alkharj, Salman bin Abdulaziz University, P.O. Box 83, Alkharj 11942 (Saudi Arabia); Mizuno, Akira [Department of Environmental and Life Sciences, Toyohashi University of Technology, Tempaku-cho, Toyohashi 441-8580 (Japan)] [Department of Environmental and Life Sciences, Toyohashi University of Technology, Tempaku-cho, Toyohashi 441-8580 (Japan)

2013-05-14T23:59:59.000Z

366

Towards modeling gadolinium-lead-borate glasses  

SciTech Connect (OSTI)

Infrared spectra of gadolinium-lead-borate glasses of the xGd{sub 2}O{sub 3}.(100 - x)[3B{sub 2}O{sub 3}.PbO] system, where x = 0, 5, 10, 15, 25, 35 and 50 mol.%, have been recorded to explore the role of content of gadolinium ions behaving as glass modifier. The FTIR spectroscopy data for the xGd{sub 2}O{sub 3}.(1 - x)[3B{sub 2}O{sub 3}.PbO] glasses show the structural role of lead ions as a network-formers and of the gadolinium ions network modifiers. Adding of the rare earth ion up to 35 mol.% into the glass matrix, the IR bands characteristic to the studied glasses become sharper and more pronounced. Structural changes, as recognized by analyzing band shapes of IR spectra, revealed that Gd{sub 2}O{sub 3} causes a change from the continuous borate network to the continuous lead-borate network interconnected through Pb-O-B and B-O-B bridges and the transformation of some tetrahedral [BO{sub 4}] units into trigonal [BO{sub 3}] units. Then, gadolinium ions have affinity towards [BO{sub 3}] structural units which contain non-bridging oxygens necessary for the charge compensation because the more electronegative [BO{sub 3}] structural units were implied in the formation of B-O-Gd bonds and the transformation of glass network into a glass ceramic. We propose a possible structural model of building blocks for the formation of continuous random 3B{sub 2}O{sub 3}.PbO network glass used by density functional theory (DFT) calculations. DFT calculations show that lead atoms occupy three different sites in the proposed model. The first is coordinated with six oxygen atoms forming distorted octahedral geometries. The second lead atom has an octahedral oxygen environment and the five longer Pb-O bonds are considered as participating in the metal coordination scheme. The third lead atom has ionic character. In agreement with the results offered by the experimental FTIR data, the theoretical IR data confirm that our proposed structure is highly possible.

Rada, S., E-mail: Simona.Rada@phys.utcluj.ro [Department of Physics, Technical University of Cluj-Napoca, 400641 Cluj-Napoca (Romania); Ristoiu, T. [Department of Physics, Technical University of Cluj-Napoca, 400641 Cluj-Napoca (Romania)] [Department of Physics, Technical University of Cluj-Napoca, 400641 Cluj-Napoca (Romania); Rada, M. [Department of Mechatronic, Technical University of Cluj-Napoca, 400641 Cluj-Napoca (Romania)] [Department of Mechatronic, Technical University of Cluj-Napoca, 400641 Cluj-Napoca (Romania); Coroiu, I. [Department of Physics, Technical University of Cluj-Napoca, 400641 Cluj-Napoca (Romania)] [Department of Physics, Technical University of Cluj-Napoca, 400641 Cluj-Napoca (Romania); Maties, V. [Department of Mechatronic, Technical University of Cluj-Napoca, 400641 Cluj-Napoca (Romania)] [Department of Mechatronic, Technical University of Cluj-Napoca, 400641 Cluj-Napoca (Romania); Culea, E. [Department of Physics, Technical University of Cluj-Napoca, 400641 Cluj-Napoca (Romania)] [Department of Physics, Technical University of Cluj-Napoca, 400641 Cluj-Napoca (Romania)

2010-01-15T23:59:59.000Z

367

CBER-DETR Nevada Coincident and Leading Employment Leading Index Hits Bump in the Road  

E-Print Network [OSTI]

the seasonally adjusted data reported by the Bureau of Labor Statistics. The Nevada Coincident Employment IndexCBER-DETR Nevada Coincident and Leading Employment Indexes1 Leading Index Hits Bump in the Road The Nevada Coincident Employment Index measures the ups and downs of the Nevada economy using an index

Ahmad, Sajjad

368

CBER-DETR Nevada Coincident and Leading Employment Coincident Index Rises, Leading Index Pauses  

E-Print Network [OSTI]

the seasonally adjusted data reported by the Bureau of Labor Statistics. The Nevada Coincident Employment IndexCBER-DETR Nevada Coincident and Leading Employment Indexes1 Coincident Index Rises, Leading Index Pauses The Nevada Coincident Employment Index measures the ups and downs of the Nevada economy using

Ahmad, Sajjad

369

Catalytic oxidation of carbon monoxide over Ir/SiO/sub 2/. An in situ infrared and kinetic study  

SciTech Connect (OSTI)

The oxidation of CO on a highly dispersed Ir/SiO/sub 2/ catalyst has been studied both in a Pyrex microreactor and by using an in situ infrared cell-reactor. Multiple steady states obtained under conditions of increasing and decreasing CO partial pressure were observed to lead to reaction rate hysteresis. The area under the hysteresis loop is strongly dependent on reaction temperature. This is explained by invoking competitive adsorption between CO and O/sub 2/ as a function of temperature. Self-sustained oscillations were obtained when certain conditions of partial pressure and temperature were met. Quantitative estimates of fluctuations in surface coverage and temperature during these oscillations were 10% and 3K, respectively. CO islands of reactivity were not observed under the conditions of this study. The presence of higher oxidation states of IR could not be unequivocally determined by using infrared spectroscopy. 29 references, 8 figures, 2 tables.

Saymeh, R.A.; Gonzalez, R.D.

1986-02-13T23:59:59.000Z

370

Lead magnesium niobate actuator for micropositioning  

DOE Patents [OSTI]

An improved lead magnesium niobate actuator is disclosed comprising a cylindrical lead magnesium niobate crystal stack mounted in a cylindrical casing wherein a bias means, such as one or more belleville washers, is located between one end of the crystal stack and a partially closed end of the casing; and adjustment means are provided which bear against the opposite end of the crystal stack, whereby an adjustable compressive force is constantly applied against the crystal stack, whether the crystal stack is actuated in an extended position, or is in an unactuated contracted position. In a preferred embodiment, cooling ports are provided for the circulation of coolant in the actuator to cool the crystal stack, and provision is made for removal and replacement of the crystal stack without disconnecting the actuator from the external device being actuated.

Swift, Charles D. (Livermore, CA); Bergum, John W. (Concord, CA)

1994-01-01T23:59:59.000Z

371

Lead magnesium niobate actuator for micropositioning  

DOE Patents [OSTI]

An improved lead magnesium niobate actuator is disclosed comprising a cylindrical lead magnesium niobate crystal stack mounted in a cylindrical casing wherein a bias means, such as one or more belleville washers, is located between one end of the crystal stack and a partially closed end of the casing; and adjustment means are provided which bear against the opposite end of the crystal stack, whereby an adjustable compressive force is constantly applied against the crystal stack, whether the crystal stack is actuated in an extended position, or is in an unactuated contracted position. In a preferred embodiment, cooling ports are provided for the circulation of coolant in the actuator to cool the crystal stack, and provision is made for removal and replacement of the crystal stack without disconnecting the actuator from the external device being actuated. 3 figs.

Swift, C.D.; Bergum, J.W.

1994-10-25T23:59:59.000Z

372

Integrated Removal of NOx with Carbon Monoxide as Reductant, and Capture of Mercury in a Low Temperature Selective Catalytic and Adsorptive Reactor  

SciTech Connect (OSTI)

Coal will likely continue to be a dominant component of power generation in the foreseeable future. This project addresses the issue of environmental compliance for two important pollutants: NO{sub x} and mercury. Integration of emission control units is in principle possible through a Low Temperature Selective Catalytic and Adsorptive Reactor (LTSCAR) in which NO{sub x} removal is achieved in a traditional SCR mode but at low temperature, and, uniquely, using carbon monoxide as a reductant. The capture of mercury is integrated into the same process unit. Such an arrangement would reduce mercury removal costs significantly, and provide improved control for the ultimate disposal of mercury. The work completed in this project demonstrates that the use of CO as a reductant in LTSCR is technically feasible using supported manganese oxide catalysts, that the simultaneous warm-gas capture of elemental and oxidized mercury is technically feasible using both nanostructured chelating adsorbents and ceria-titania-based materials, and that integrated removal of mercury and NO{sub x} is technically feasible using ceria-titania-based materials.

Neville Pinto; Panagiotis Smirniotis; Stephen Thiel

2010-08-31T23:59:59.000Z

373

Studies on the sulfur poisoning of Ru-RuO{sub x}/TiO{sub 2} catalyst for the adsorption and methanation of carbon monoxide  

SciTech Connect (OSTI)

The effects of sulfur poisoning on the chemisorption and on the methanation of carbon monoxide over Ru/TiO{sub 2} catalyst were investigated by FTIR spectroscopy and volumetric gas adsorption measurements. The CS{sub 2} molecules are {eta}` bonded to Ru sites through one of the sulfur atoms and decompose to the constituent elements on thermal activation. Each S atom may deactivate 3 to 10 metal sites even at low coverages, the effect being more pronounced on the chemisorption of hydrogen. The deposited sulfur (and possibly carbon also) sterically hinders the formation of certain multicarbonyl and monocarbonyl species (vCO in 2055-2140 cm{sup -1} region), which otherwise transform to methane via surface methylene groups in the presence of chemisorbed hydrogen and are found to play an important role in the low-temperature methanation activity of the studied catalyst. The Ru-CO species giving rise to lower frequency vibrational bands are affected to a lesser extent. The presence of sulfur also results in the development of some new CO binding states which are weak and are identified with the CO and S coadsorbed at Ru sites of different oxidation states or of varying crystallographic nature. The CO adsorbed in these states is not reactive to hydrogen. 45 refs., 9 figs., 1 tab.

Kamble, V.S.; Londhe, V.P.; Gupta, N.M. [Bhambha Atomic Research centre, Bombay (India)] [and others] [Bhambha Atomic Research centre, Bombay (India); and others

1996-02-01T23:59:59.000Z

374

Preliminary synchrotron analysis of lead in hair from a lead smelter worker  

SciTech Connect (OSTI)

Synchrotron X-ray fluorescence has been used to study the distribution of lead in a hair sample collected from a lead smelter worker. A mathematical model was used to imitate the transverse scan signal based on the analysis volume and concentration profiles. The results suggest that the Pb originates both from ingestion and environmental exposure, however direct deposition from the environment is the more important source of hair lead. The model could apply equally to any other analysis involving a thin cylindrical sample.

Martin, R.R.; Kempson, I.M.; Naftel, S.J.; Skinner, W.M. (Case Western); (U. South Australia)

2008-06-09T23:59:59.000Z

375

XRD, lead equivalent and UV-VIS properties study of Ce and Pr lead silicate glasses  

SciTech Connect (OSTI)

In this work, Cerium (Ce) and Praseodymium (Pr) containing lead silicate glasses were produced with 2 different molar ratios low (0.2 wt%) and high (0.4wt%). These types of glasses can satisfy the characteristics required for radiation shielding glasses and minimize the lead composition in glass. The radiation shielding properties of the synthesized glasses is explained in the form of lead equivalent study. The XRD diffraction and UV-VIS analysis were performed to observe the structural changes of the synthesis glasses at 1.5 Gy gamma radiation exposures.

Alias, Nor Hayati, E-mail: norhayati@nuclearmalaysia.gov.my; Abdullah, Wan Shafie Wan, E-mail: norhayati@nuclearmalaysia.gov.my; Isa, Norriza Mohd, E-mail: norhayati@nuclearmalaysia.gov.my; Isa, Muhammad Jamal Md, E-mail: norhayati@nuclearmalaysia.gov.my; Zali, Nurazila Mat; Abdullah, Nuhaslinda Ee [Malaysian Nuclear Agency, 43000, Bangi, Kajang, Selangor (Malaysia); Muhammad, Azali [Malaysian Society for Non-Destructive Testing (Malaysia)

2014-02-12T23:59:59.000Z

376

Climatological simulations of ozone and atmospheric aerosols in the Greater Cairo region  

SciTech Connect (OSTI)

An integrated chemistry-climate model (RegCM4-CHEM) simulates present-day climate, ozone and tropospheric aerosols over Egypt with a focus on Greater Cairo (GC) region. The densley populated GC region is known for its severe air quality issues driven by high levels of anthropogenic pollution in conjuction with natural sources such as dust and agricultural burning events. We find that current global emission inventories underestimate key pollutants such as nitrogen oxides and anthropogenic aerosol species. In the GC region, average-ground-based NO2 observations of 40-60 ppb are substantially higher than modeled estimates (5-10 ppb), likely due to model grid resolution, improper boundary layer representation, and poor emissions inventories. Observed ozone concentrations range from 35 ppb (winter) to 80 ppb (summer). The model reproduces the seasonal cycle fairly well, but modeled summer ozone is understimated by approximately 15 ppb and exhibits little interannual variability. For aerosols, springtime dust events dominate the seasonal aerosol cycle. The chemistry-climate model captures the springtime peak aerosol optical depth (AOD) of 0.7-1 but is slightly greater than satellite-derived AOD. Observed AOD decreases in the summer and increases again in the fall due to agricultural burning events in the Nile Delta, yet the model underestimates this fall observed AOD peak, as standard emissions inventories underestimate this burning and the resulting aerosol emissions. Our comparison of modeled gas and particulate phase atmospheric chemistry in the GC region indicates that improved emissions inventories of mobile sources and other anthropogenic activities are needed to improve air quality simulations in this region.

Steiner, A. L.; Tawfik, A. B.; Shalaby, A.; Zakey, A. S.; Abdel Wahab, M. M.; Salah, Z.; Solmon, F.; Sillman, S.; Zaveri, Rahul A.

2014-04-16T23:59:59.000Z

377

Observations of the Temperature Dependent Response of Ozone to NOx Reductions in an Urban Plume  

SciTech Connect (OSTI)

Observations of NO{sub x} in the Sacramento, CA region show that mixing ratios decreased by 30% between 2001 and 2008. Here we use an observation-based method to quantify net ozone production rates in the outflow from the Sacramento metropolitan region and examine the O{sub 3} decrease resulting from reductions in NO{sub x} emissions. This observational method does not rely on assumptions about detailed chemistry of ozone production, rather it is an independent means to verify and test these assumptions. We use an instantaneous steady-state model as well as a detailed 1-D plume model to aid in interpretation of the ozone production inferred from observations. In agreement with the models, the observations show that early in the plume, the NO{sub x} dependence for O{sub x} (O{sub x} = O{sub 3}+NO{sub 2}) production is strongly coupled with temperature, suggesting that temperature dependent biogenic VOC emissions can drive O{sub x} production between NO{sub x}-limited and NO{sub x}-suppressed regimes. As a result, NO{sub x} reductions were found to be most effective at higher temperatures over the 7 year period. We show that violations of the California 1-hour O{sub 3} standard (90 ppb) in the region have been decreasing linearly with decreases in NO{sub x} (at a given temperature) and predict that reductions of NO{sub x} concentrations (and presumably emissions) by an additional 30% (relative to 2007 levels) will eliminate violations of the state 1 hour standard in the region. If current trends continue, a 30% decrease in NO{sub x} is expected by 2012, and an end to violations of the 1 hour standard in the Sacramento region appears to be imminent.

LaFranchi, B W; Goldstein, A H; Cohen, R C

2011-01-25T23:59:59.000Z

378

Effects of ambient ozone on respiratory function and symptoms in Mexico City schoolchildren  

SciTech Connect (OSTI)

The effects of ambient ozone (O3) on respiratory function and acute respiratory symptoms were evaluated in 143 7- to 9-yr-old schoolchildren followed longitudinally at 1- to 2-wk intervals over a period of 6 months at three schools in Pedregal, Mexico City. The maximum O3 level exceeded the World Health Organization guideline of 80 ppb and the U.S. standard of 120 ppb in every week. For an increase from lowest to highest in the mean O3 level during the 48 hr before spirometry (53 ppb), logistic regression estimated relative odds of 1.7 for a child reporting cough/phlegm on the day of spirometry. For the full population, the mean O3 level during the hour before spirometry, not adjusted for temperature and humidity, predicted a significant decrement in FVC but not in FEV1 or FEF25-75. In contrast, the mean O3 level during the previous 24-, 48-, and 168-h periods predicted significant decrements in FEV1 and FEF25-75 but not in FVC. Ozone was consistently associated with a greater decrement in lung function for the 15 children with chronic phlegm as compared with the children without chronic cough, chronic phlegm, or wheeze. Ozone in the previous 24-, 48-, and 168-h periods predicted decrements in FEV1 for children of mothers who were current or former smokers, but not for children of mothers who were never smokers. Many of these effects were reduced in multiple regression analyses including temperature and humidity, as temperature and O3 were highly correlated.

Castillejos, M.; Gold, D.R.; Dockery, D.; Tosteson, T.; Baum, T.; Speizer, F.E. (Universidad Autonoma Metropolitana-X, Mexico City, (Mexico))

1992-02-01T23:59:59.000Z

379

Know the Facts Lead poisoning is caused by swallowing or  

E-Print Network [OSTI]

;Protect Your Family 1. Test your home for lead. · If you live in a home built before 1978, have your home are most at risk. If you are pregnant, lead can harm your baby. Lead can cause learning and behavior on their hands and toys. FACT A lead test is the only way to know if your child has lead poisoning. Most

380

Lead Screening for NH Soils: Minimizing Health Risks  

E-Print Network [OSTI]

family. On your soil test report, if the lead screening levels are elevated, you will receive in populated areas include the use of lead paint around homes (pre- 1970s), the use of lead-arsenate for pest does a "lead screening" test that indicates whether or not lead could pose a health risk for your

New Hampshire, University of

Note: This page contains sample records for the topic "monoxide ozone lead" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Lagrangian methods for climatological analysis of regional atmospheric transport with an emphasis on Texas ozone exceedances  

E-Print Network [OSTI]

. ............ 43 19 48-hour backward trajectory for Event 2. Ozone values for 1998-08- 15?1998-08-17 are also shown. ...................... 45 20 Geopotential height in m at 1000 hPa on 1998-08-16 at 18Z and a plot of surface weather on 1998-08-17 at 0Z provided....1) for all possible delta-function initial conditions (all x0), that is, partialdiffG partialdifft +v ?nablaG =0,G(x, x0,t0)=delta(x -x0). (3.2) The principal advantage of this solution technique is that, if G can be found, the solution to (3...

Dexheimer, Darielle Nicole

2004-11-15T23:59:59.000Z

382

Highly reproducible and reliable metal/graphene contact by ultraviolet-ozone treatment  

SciTech Connect (OSTI)

Resist residue from the device fabrication process is a significant source of contamination at the metal/graphene contact interface. Ultraviolet Ozone (UVO) treatment is proven here, by X-ray photoelectron spectroscopy and Raman measurement, to be an effective way of cleaning the metal/graphene interface. Electrical measurements of devices that were fabricated by using UVO treatment of the metal/graphene contact region show that stable and reproducible low resistance metal/graphene contacts are obtained and the electrical properties of the graphene channel remain unaffected.

Li, Wei [Key Laboratory for the Physics and Chemistry of Nanodevices and Department of Electronics, Peking University, Beijing 100871 (China); Physical Measurement Laboratory, National Institute of Standards and Technology, Gaithersburg, MD 20899 (United States); Hacker, Christina A.; Cheng, Guangjun; Hight Walker, A. R.; Richter, Curt A.; Gundlach, David J., E-mail: david.gundlach@nist.gov, E-mail: liangxl@pku.edu.cn [Physical Measurement Laboratory, National Institute of Standards and Technology, Gaithersburg, MD 20899 (United States); Liang, Yiran; Tian, Boyuan; Liang, Xuelei, E-mail: david.gundlach@nist.gov, E-mail: liangxl@pku.edu.cn; Peng, Lianmao [Key Laboratory for the Physics and Chemistry of Nanodevices and Department of Electronics, Peking University, Beijing 100871 (China)

2014-03-21T23:59:59.000Z

383

Could the Earth's surface Ultraviolet irradiance be blamed for the global warming? (II) ----Ozone layer depth reconstruction via HEWV effect  

E-Print Network [OSTI]

It is suggested by Chen {\\it et al.} that the Earth's surface Ultraviolet irradiance ($280-400$ nm) could influence the Earth's surface temperature variation by "Highly Excited Water Vapor" (HEWV) effect. In this manuscript, we reconstruct the developing history of the ozone layer depth variation from 1860 to 2011 based on the HEWV effect. It is shown that the reconstructed ozone layer depth variation correlates with the observational variation from 1958 to 2005 very well ($R=0.8422$, $P>99.9\\%$). From this reconstruction, we may limit the spectra band of the surface Ultraviolet irradiance referred in HEWV effect to Ultraviolet B ($280-320$ nm).

Chen, Jilong; Zheng, Yujun

2014-01-01T23:59:59.000Z

384

Asian anthropogenic lead contamination in the North Pacific Ocean as evidenced by stable lead isotopic compositions  

E-Print Network [OSTI]

and North Central Pacific Ocean. Deep Sea Res. Part II Top.Lead Within the Northwest Pacific Ocean Evidenced by Leadventilation flux of the Pacific Ocean. J. Geophys. Res. 106(

Zurbrick, Cheryl Marie

2014-01-01T23:59:59.000Z

385

Properties of lead-lithium solutions  

SciTech Connect (OSTI)

Lead-lithium solutions are of interest to liquid metal wall ICF reactor designers because Pb may be present to some extent in both heavy ion beam and laser-driven ICF targets; therefore, Pb will be present as an impurity in a flowing lithium wall. In addition, Pb-Li solutions containing approx. 80 a/o Pb are a strong candidate for a heavy ion beam driven HYLIFE converter and a viable alternative to a pure Li wall for a laser driven converter. The properties of Pb-Li solutions including the effect of hydrogen impurities are reviewed, and the reactor design implications are discussed.

Hoffman, N.J.; Darnell, A.; Blink, J.A.

1980-10-01T23:59:59.000Z

386

Lead Slowing Down Spectrometer Status Report  

SciTech Connect (OSTI)

This report documents the progress that has been completed in the first half of FY2012 in the MPACT-funded Lead Slowing Down Spectrometer project. Significant progress has been made on the algorithm development. We have an improve understanding of the experimental responses in LSDS for fuel-related material. The calibration of the ultra-depleted uranium foils was completed, but the results are inconsistent from measurement to measurement. Future work includes developing a conceptual model of an LSDS system to assay plutonium in used fuel, improving agreement between simulations and measurement, design of a thorium fission chamber, and evaluation of additional detector techniques.

Warren, Glen A.; Anderson, Kevin K.; Bonebrake, Eric; Casella, Andrew M.; Danon, Yaron; Devlin, M.; Gavron, Victor A.; Haight, R. C.; Imel, G. R.; Kulisek, Jonathan A.; O'Donnell, J. M.; Weltz, Adam

2012-06-07T23:59:59.000Z

387

Thermal conductivity of bulk nanostructured lead telluride  

SciTech Connect (OSTI)

Thermal conductivity of lead telluride with embedded nanoinclusions was studied using Monte Carlo simulations with intrinsic phonon transport properties obtained from first-principles-based lattice dynamics. The nanoinclusion/matrix interfaces were set to completely reflect phonons to model the maximum interface-phonon-scattering scenario. The simulations with the geometrical cross section and volume fraction of the nanoinclusions matched to those of the experiment show that the experiment has already reached the theoretical limit of thermal conductivity. The frequency-dependent analysis further identifies that the thermal conductivity reduction is dominantly attributed to scattering of low frequency phonons and demonstrates mutual adaptability of nanostructuring and local disordering.

Hori, Takuma [Department of Mechanical Engineering, The University of Tokyo, Bunkyo, Tokyo 113-8656 (Japan); Chen, Gang [Department of Mechanical Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States); Shiomi, Junichiro, E-mail: shiomi@photon.t.u-tokyo.ac.jp [Department of Mechanical Engineering, The University of Tokyo, Bunkyo, Tokyo 113-8656 (Japan); PRESTO, Japan Science and Technology Agency, Kawaguchi, Saitama 332-0012 (Japan)

2014-01-13T23:59:59.000Z

388

Non-lead hollow point bullet  

DOE Patents [OSTI]

The non-lead hollow point bullet of the instant invention comprises a mixed construction slug further comprising, a monolithic metal insert having a tapered (preferred conical) hollow point tip and a tapered (preferred conical) tail protrusion, and an unsintered powdered metal composite core in tandem alignment with the insert. The core has a hollow tapered (preferred conical) cavity tip portion coupled with the tapered (preferred conical) tail protrusion on the insert. An open tip jacket envelops at least a portion of the insert and the core. The jacket is swaged at the open tip.

Vaughn, Norman L. (Knoxville, TN); Lowden, Richard A. (Clinton, TN)

2003-04-15T23:59:59.000Z

389

Leading Edge Technologies Inc | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to:46 - 429Lacey, Washington:Lakeville, MN)Lauderhill,5. ItLea Hill, Washington:Leading

390

Richard Gerber! NERSC! User Services Group Lead  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the1 -the Mid-Infrared0 Resource Program September 2010 BRichardGroup Lead Debugging and

391

Anthropogenic Lead Emissions in the Ocean: The Evolving Global Experiment  

E-Print Network [OSTI]

We review the current distribution of lead and lead isotopes in the ocean with regard to the evolving pattern of human emissions during the past decades and centuries.

Lee, Jong-Mi

392

Combined Heat and Power System Enables 100% Reliability at Leading...  

Broader source: Energy.gov (indexed) [DOE]

Enables 100% Reliability at Leading Medical Campus - Case Study, 2013 Combined Heat and Power System Enables 100% Reliability at Leading Medical Campus - Case Study, 2013 Thermal...

393

Scheibe named lead scientist for EMSL computing | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

lead scientist for EMSL computing He will oversee Multiscale Modeling and High Performance Computing Tim Scheibe EMSL has selected Tim Scheibe as lead scientist for Multiscale...

394

Research Led by Sandia Reveals Leading-Edge Erosion Significantly...  

Broader source: Energy.gov (indexed) [DOE]

Research Led by Sandia Reveals Leading-Edge Erosion Significantly Reduces Wind Turbine Performance Research Led by Sandia Reveals Leading-Edge Erosion Significantly Reduces Wind...

395

University of Maryland Wins Architecture Prize, Pulls Into Lead...  

Broader source: Energy.gov (indexed) [DOE]

Maryland Wins Architecture Prize, Pulls Into Lead in 2011 Solar Decathlon University of Maryland Wins Architecture Prize, Pulls Into Lead in 2011 Solar Decathlon September 28, 2011...

396

Electrochemical Sensors for the Detection of Lead and Other Toxic...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Sensors for the Detection of Lead and Other Toxic Heavy Metals: The Next Generation of Personal Exposure Electrochemical Sensors for the Detection of Lead and Other Toxic Heavy...

397

Hydrogen diffusion in Lead Zirconate Titanate and Barium Titanate...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

diffusion in Lead Zirconate Titanate and Barium Titanate. Hydrogen diffusion in Lead Zirconate Titanate and Barium Titanate. Abstract: Hydrogen is a potential clean-burning,...

398

New Superconducting Magnet Will Lead to Next Generation of Wind...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

New Superconducting Magnet Will Lead to Next Generation of Wind Turbine Generators New Superconducting Magnet Will Lead to Next Generation of Wind Turbine Generators September 12,...

399

Dow Chemical Company: Assessment Leads to Steam System Energy...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Dow Chemical Company: Assessment Leads to Steam System Energy Savings in a Petrochemical Plant Dow Chemical Company: Assessment Leads to Steam System Energy Savings in a...

400

Ozone Abundance in a Nitrogen-Carbon Dioxide Dominated Terrestrial Paleoatmosphere  

E-Print Network [OSTI]

We compute the ozone distribution for a model terrestrial paleoatmosphere in which the present oxygen abundance is largely replaced by carbon dioxide, which we argue is a reasonable working assumption. In principle, the presence of carbon dioxide might supplement the ozone shield as compared with models based on nitrogen without high carbon dioxide abundance so that early life need not have been as UV-resistant as often assumed. An extrasolar planet with a high-CO2 atmosphere might contain enough O3 to be a source of false positive biomarkers. We find that the globally averaged O3 column density can be the same, or nearly four times higher (depending upon the O2 partial pressure) when CO2 is used in place of N2 as the replacement component for lowered O2 in a 1-atm terrestrial planet with solar radiation. The effect is important for making quantitative deductions from future data, but does not invalidate the use of O3 as a biomarker for free oxygen. These results make prospects for detection of extrasolar planetary O3 absorption somewhat better than before.

B. C. Thomas; A. L. Melott; L. D. Martin; C. H. Jackman

2004-10-22T23:59:59.000Z

Note: This page contains sample records for the topic "monoxide ozone lead" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Ozone Abundance in a Nitrogen-Carbon Dioxide Dominated Terrestrial Paleoatmosphere  

E-Print Network [OSTI]

We compute the ozone distribution for a model terrestrial paleoatmosphere in which the present oxygen abundance is largely replaced by carbon dioxide, which we argue is a reasonable working assumption. In principle, the presence of carbon dioxide might supplement the ozone shield as compared with models based on nitrogen without high carbon dioxide abundance so that early life need not have been as UV-resistant as often assumed. An extrasolar planet with a high-CO2 atmosphere might contain enough O3 to be a source of false positive biomarkers. We find that the globally averaged O3 column density can be the same, or nearly four times higher (depending upon the O2 partial pressure) when CO2 is used in place of N2 as the replacement component for lowered O2 in a 1-atm terrestrial planet with solar radiation. The effect is important for making quantitative deductions from future data, but does not invalidate the use of O3 as a biomarker for free oxygen. These results make prospects for detection of extrasolar pla...

Thomas, B C; Martin, L D; Jackman, C H

2004-01-01T23:59:59.000Z

402

NOx Emission Reduction and its Effects on Ozone during the 2008 Olympic Games  

SciTech Connect (OSTI)

We applied a daily-assimilated inversion method to estimate NOx (NO+NO2) emissions for June-September 2007 and 2008 on the basis of the Aura Ozone Monitoring Instrument (OMI) observations of nitrogen dioxide (NO2) and model simulations using the Regional chEmistry and trAnsport Model (REAM). Over urban Beijing, rural Beijing, and the Huabei Plain, OMI column NO2 reductions are approximately 45%, 33%, and 14%, respectively, while the corresponding anthropogenic NOx emission reductions are only 28%, 24%, and 6%, during the full emission control period (July 20 – Sep 20, 2008). The emission reduction began in early July and was in full force by July 20, corresponding to the scheduled implementation of emission controls over Beijing. The emissions did not appear to recover after the emission control period. Meteorological change from summer 2007 to 2008 is the main factor contributing to the column NO2 decreases not accounted for by the emission reduction. Model simulations suggest that the effect of emission reduction on ozone concentrations over Beijing is relatively minor using a standard VOC emission inventory in China. With an adjustment of the model emissions to reflect in situ observations of VOCs in Beijing, the model simulation suggests a larger effect of the emission reduction.

Yang, Qing; Wang, Yuhang; Zhao, Chun; Liu, Zhen; Gustafson, William I.; Shao, Min

2011-07-15T23:59:59.000Z

403

Step-coverage simulation for tetraethoxysilane and ozone atmospheric pressure chemical vapor deposition  

SciTech Connect (OSTI)

A simulation model for atmospheric pressure (AP) CVD has bee developed using one-dimensional diffusion and mass conservation equations. The model was applied to trench step-coverage of the tetraethoxysilane (TEOS) and O[sub 3] CVD, in which it was not necessary to consider lateral diffusion because of narrow (and deep) trenches. For nondoped silicate glass (NSG), the step-coverage of a 4.5 aspect ratio trench showed a good fit if a sticking probability of 0.0039 was assumed for the 0.6% ozone (in oxygen) deposition and of 0.0026 for the 6% ozone deposition (both 400 C). The reaction rate constant was compared with the diffusion mass-transfer coefficient, and the reaction proved to be limited by diffusion of the reactant, TEOS, which directly participated in the CVD reaction. For the 2 m/o phosphosilicate glass (PSG) step-coverage, which had a slight overhang, the model matched the obtained results well only when an active growth species with a high sticking probability of 1.0 was added to the growth species of nondoped oxide. This analytical simulation method satisfactorily explains the experimental data.

Fujino, K. (Semiconductor Process Lab., Toyko (Japan)); Egashira, Y.; Shimogaki, Y.; Komiyama, H. (Univ. of Tokyo, (Japan). Dept. of Chemical Engineering)

1993-08-01T23:59:59.000Z

404

Lead Slowing Down Spectrometer Research Plans  

SciTech Connect (OSTI)

The MPACT-funded Lead Slowing Down Spectrometry (LSDS) project has been evaluating the feasibility of using LSDS techniques to assay fissile isotopes in used nuclear fuel assemblies. The approach has the potential to provide considerable improvement in the assay of fissile isotopic masses in fuel assemblies compared to other non-destructive techniques in a direct and independent manner. The LSDS collaborations suggests that the next step to in empirically testing the feasibility is to conduct measurements on fresh fuel assemblies to understand investigate self-attenuation and fresh mixed-oxide (MOX) fuel rodlets so we may betterto understand extraction of masses for 235U and 239Pu. While progressing toward these goals, the collaboration also strongly suggests the continued development of enabling technology such as detector development and algorithm development, thatwhich could provide significant performance benefits.

Warren, Glen A.; Kulisek, Jonathan A.; Gavron, Victor; Danon, Yaron; Weltz, Adam; Harris, Jason; Stewart, T.

2013-03-22T23:59:59.000Z

405

Synthesis and regeneration of lead (IV) acetate  

SciTech Connect (OSTI)

Lead acetate [Pb(O{sub 2}CMe){sub 4}] was easily synthesized from a warm solution of Pb{sub 3}O{sub 4}, HO{sub 2}CMe and O(OCMe){sub 2} following literature preparations when the appropriate measures to minimize water contamination were followed. Furthermore, Pb(O{sub 2}CMe){sub 4} which has been decomposed (evidenced by the appearance of a purple color due to oxidation) can be regenerated using a similar preparatory route. Introduction of Pb(O{sub 2}CMe){sub 4} from the two routes outlined above into the IMO process for production of PZT thin films gave films with comparable ferroelectric properties to commercially available Pb(O{sub 2}CMe){sub 4} precursors. However, the freshly synthesized material yields PZT films with better properties compared to the recycled material.

Boyle, T.J.; Al-Shareef, H.N.; Moore, G.J. [Sandia National Labs., Albuquerque, NM (United States). Advanced Materials Lab.

1996-11-01T23:59:59.000Z

406

FTIR study of carbon monoxide oxidation and scrambling at room temperature over copper supported on ZnO and TiO{sub 2} No. 1  

SciTech Connect (OSTI)

An FTIR and quadrupole mass spectroscopic study of CO adsorption and oxidation with {sup 16}O{sub 2} and {sup 18}O{sub 2} on copper supported on ZnO and TiO{sub 2} is presented. The experimental results indicate that CO is adsorbed on the metallic particles dispersed on both oxides on two kinds of sites, on the normal terrace sites and on sites at the borderline of the particles. Moreover, on titania, a band at 2126 cm{sup -1}, assigned to CO adsorbed on isolated Cu atoms and/or on two-dimensional small clusters, is detected. A frequency shift of the bands of CO adsorbed on the metallic particles observed in the CO-O{sub 2} coadsorption experiments and the occurrence of a scrambling reaction between CO and {sup 18}O{sub 2} reveal that on all these samples, there are metallic sites which are able to adsorb at the same time oxygen atoms and carbon monoxide. Carbon dioxide and carbonate-like species are formed: the asymmetric stretching frequencies of CO{sub 2} and the quadrupole mass spectroscopic analysis reveal that with {sup 18}O{sub 2}, different isotopic molecular CO{sub 2}`s are formed, while the carbonate-like species have the same frequencies of those produced in {sup 16}O{sub 2}. Moreover, these species are completely lacking in the absence of oxygen in the gas phase. The experimental results indicate the there are, on these samples, two independent pathways for the CO oxidation, a direct oxidation of CO at the surface of the metallic particles and an induced oxidation with the surface lattice oxygen species of the supports. 46 refs., 8 figs.

Baccuzzi, F.; Chiorino, A. [Universita di Torino (Italy)] [Universita di Torino (Italy)

1996-02-29T23:59:59.000Z

407

Extending surface-enhanced Raman spectroscopy to transition-metal surfaces: carbon monoxide adsorption and electrooxidation on platinum- and palladium-coated gold electrodes  

SciTech Connect (OSTI)

Thin (ca. one to three monolayers) films of platinum and palladium electrodeposited on electrochemically roughened gold are observed to yield surface-enhanced Raman (SER) spectra for adsorbed carbon monoxide. The major vibrational band(s) on these surfaces are diagnosed from their frequencies as arising from C-O stretching vibrations, nu/sub CO/ bound to the transition-metal overlayers rather than to residual gold sites. The observed SFR nu/sub CO/ frequencies are closely similar to (within ca. 10 cm/sup -1/ of) those obtained for these systems from potential-difference infrared (PDIR) spectra. The major SERS and PDIR nu/sub CO/ features for the platinum and palladium surfaces appear at 2060-2090 and 1965-1985 cm/sup -1/, respectively, consistent with the presence of terminal and bridging CO on these two electrodes. The infrared as well as electrochemical properties of these systems are closely similar to those for the corresponding polycrystalline bulk electrodes. A difference between the SER- and IR-active adsorbed CO, however, is that the former undergoes electrooxidation on both surfaces at 0.2-0.3 V higher overpotentials than the latter form. Examination of the potential-dependent SERS bands for metal oxide vibrations, nu/sub PtO/, on the platinum surface shows that the electrooxidation potential for the SERS-active adsorbed CO coincides with that for the appearance of the nu/sub PtO/ band. Some broader implications to the utilization of SERS for examining transition-metal surfaces are pointed out.

Leung, L.W.H.; Weaver, M.J.

1987-08-19T23:59:59.000Z

408

Comparison of leading and next-to-leading logarithmic electroweak corrections to Higgs production  

E-Print Network [OSTI]

Using soft-collinear effective theory, the leading-log radiative electroweak corrections are written in a closed and analytical form for the hadronic cross section of Higgs production through vector boson fusion, qq->qqH, one of the most promising channels for studying the Higgs boson at the LHC. The simple leading-log resummation is compared with a full next-to-leading-log calculation, and its accuracy is found to be of order 1% up to 10 TeV, i.e. better than the accuracy of PDFs. Corrections are found to be larger than predicted by one-loop fixed order approximations at LHC energies. The method provides a simple way of incorporating the electroweak corrections in software packages, improving the accuracy of simulations.

Fabio Siringo

2013-07-29T23:59:59.000Z

409

Comparison of leading and next-to-leading logarithmic electroweak corrections to Higgs production  

E-Print Network [OSTI]

Using soft-collinear effective theory, the leading-log radiative electroweak corrections are written in a closed and analytical form for the hadronic cross section of Higgs production through vector boson fusion, qq->qqH, one of the most promising channels for studying the Higgs boson at the LHC. The simple leading-log resummation is compared with a full next-to-leading-log calculation, and its accuracy is found to be of order 1% up to 10 TeV, i.e. comparable with the accuracy of PDFs. Corrections are found to be larger than predicted by one-loop fixed order approximations at LHC energies. The method provides a simple way of incorporating the electroweak corrections in software packages, improving the accuracy of simulations.

Siringo, Fabio

2013-01-01T23:59:59.000Z

410

GEOPHYSICAL RESEARCH LETTERS, VOL. 27, NO. 21, PAGES 3465-3468, NOVEMBER 1, 2000 Increasing background ozone in surface air  

E-Print Network [OSTI]

that an important consideration for pollution control strategies is the O3 back- ground present in surface air over background ozone in surface air over the United States C.-Y. Cynthia Lin, Daniel J. Jacob, J. William Munger in surface air over the United States from 1980 to 1998 is examined using monthly probability distributions

Lin, C.-Y. Cynthia

411

Ozone injury on cutleaf coneflower (Rudbeckia laciniata) and crown-beard (Verbesina occidentalis) in Great Smoky Mountains  

E-Print Network [OSTI]

upon Tyne NE1 7RU, UK d Resource Management and Science Division, 1314 Cherokee Orchard Road, Great and 2001: Clingmans Dome, Cherokee Orchard Road and Purchase Knob. Cutleaf coneflower exhibited a greater adjacent to the Cherokee Orchard Road Loop. Ozone injury was greatest on the lower leaves for both species

Neufeld, Howard S.

412

SOLA, 2008, Vol. 4, 117 120, doi:10.2151/sola.2008 030 We analyzed tropospheric column ozone (TCO)  

E-Print Network [OSTI]

SOLA, 2008, Vol. 4, 117 120, doi:10.2151/sola.2008 030 Abstract We analyzed tropospheric column the energy budget of the Earth's atmosphere. According to a recent IPCC report (2007), radiative forcing, recent increases in energy consumption have led to a significant amount of emissions of ozone precursors

Chance, Kelly

413

The effect of marine isoprene emissions on secondary organic aerosol and ozone formation in the coastal United States  

E-Print Network [OSTI]

The effect of marine isoprene emissions on secondary organic aerosol and ozone formation) in the coastal areas of the continental United States is studied using the U.S. Environmental Protection Agency regional-scale Community Multiscale Air Quality (CMAQ) modeling system. Marine isoprene emission rates

Zhang, Yang

414

The effects of ethylenediurea and sodium erythorbate on photosynthetic function of ozone-exposed loblolly pine seedlings  

E-Print Network [OSTI]

-top chambers in east Texas for one growing season beginning in April 1994 while being exposed to either sub-ambient (CF), approximate ambient (NF), 1.5Y,, 2.OX, or 2.5X ambient ozone levels. Net photosynthesis (A), stomatal conductance (g), and chloroplast...

Kuehler, Eric Anthony

1995-01-01T23:59:59.000Z

415

COMBUSTION AND FLAME 24, 27-34 (1975) 27 Flame Emission Studies of Ozone with Metal Alkyls  

E-Print Network [OSTI]

COMBUSTION AND FLAME 24, 27-34 (1975) 27 Flame Emission Studies of Ozone with Metal Alkyls: Zn (CH3 of combustion. Premixed [2, 3] anddiffusion [4] flames of metal alkyl compounds have been carried out to deter- tageous to study the combustion of polyatomic molecules under single-collision conditions, i

Zare, Richard N.

416

Development and application of a real time lead-in-air analyzer in controlling lead exposure at a primary lead smelter  

SciTech Connect (OSTI)

To assist in locating and quantifying fugitive emissions in a primary lead smelter, a real time lead-in-air analyzer has been developed. Dust is collected on paper tape filters and the lead analyzed by X-ray fluorescence. The unit has been used successfully to assist in the implementation of an engineering control monitoring program.

Smith, W.J.; Dekker, D.L.; Greenwood-Smith, R.

1986-12-01T23:59:59.000Z

417

Law Update Cover 2,3 No More Spreading Lead  

E-Print Network [OSTI]

to customers by contractors, of the "Protect Your Family from Lead in Your Home" pamphlet, be- fore beginning because the lead tastes sweet, you need to readjust your thinking. Lead poisoning occurs across allINSIDE Law Update Cover 2,3 No More Spreading Lead Tip of the Month Page 4 Rental Unit Condition

Hutyra, Lucy R.

418

Southern California Leading EconomicSouthern California Leading EconomicSouthern California Leading EconomicSouthern California Leading Economic IndicatorIndicatorIndicatorIndicator Aug 2013 Center for Economic Analysis and Forecasting (CEAF), California  

E-Print Network [OSTI]

Southern California Leading EconomicSouthern California Leading EconomicSouthern California Leading EconomicSouthern California Leading Economic IndicatorIndicatorIndicatorIndicator Aug 2013 © Center for Economic Analysis and Forecasting (CEAF), California State University Fullerton Adrian R. Fleissig, Ph

de Lijser, Peter

419

Southern California Leading EconomicSouthern California Leading EconomicSouthern California Leading EconomicSouthern California Leading Economic IndicatorIndicatorIndicatorIndicator November 2013 Center for Economic Analysis and Forecasting (CEAF), Calif  

E-Print Network [OSTI]

Southern California Leading EconomicSouthern California Leading EconomicSouthern California Leading EconomicSouthern California Leading Economic IndicatorIndicatorIndicatorIndicator November 2013 © Center for Economic Analysis and Forecasting (CEAF), California State University Fullerton Adrian R. Fleissig, Ph

de Lijser, Peter

420

Southern California Leading EconomicSouthern California Leading EconomicSouthern California Leading EconomicSouthern California Leading Economic IndicatorIndicatorIndicatorIndicator November 2010 Institute for Economic and Environmental Studies (IEES), C  

E-Print Network [OSTI]

Southern California Leading EconomicSouthern California Leading EconomicSouthern California Leading EconomicSouthern California Leading Economic IndicatorIndicatorIndicatorIndicator November 2010 © Institute for Economic and Environmental Studies (IEES), California State University Fullerton Adrian R. Fleissig, Ph

de Lijser, Peter

Note: This page contains sample records for the topic "monoxide ozone lead" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Southern California Leading EconomicSouthern California Leading EconomicSouthern California Leading EconomicSouthern California Leading Economic IndicatorIndicatorIndicatorIndicator May 2012 Institute for Economic and Environmental Studies (IEES), Califo  

E-Print Network [OSTI]

Southern California Leading EconomicSouthern California Leading EconomicSouthern California Leading EconomicSouthern California Leading Economic IndicatorIndicatorIndicatorIndicator May 2012 © Institute for Economic and Environmental Studies (IEES), California State University Fullerton Adrian R. Fleissig, Ph

de Lijser, Peter

422

Southern California Leading EconomicSouthern California Leading EconomicSouthern California Leading EconomicSouthern California Leading Economic IndicatorIndicatorIndicatorIndicator November 2012 Institute for Economic and Environmental Studies (IEES), C  

E-Print Network [OSTI]

Southern California Leading EconomicSouthern California Leading EconomicSouthern California Leading EconomicSouthern California Leading Economic IndicatorIndicatorIndicatorIndicator November 2012 © Institute for Economic and Environmental Studies (IEES), California State University Fullerton Adrian R. Fleissig, Ph

de Lijser, Peter

423

Southern California Leading EconomicSouthern California Leading EconomicSouthern California Leading EconomicSouthern California Leading Economic IndicatorIndicatorIndicatorIndicator May 2011 Institute for Economic and Environmental Studies (IEES), Califo  

E-Print Network [OSTI]

Southern California Leading EconomicSouthern California Leading EconomicSouthern California Leading EconomicSouthern California Leading Economic IndicatorIndicatorIndicatorIndicator May 2011 © Institute for Economic and Environmental Studies (IEES), California State University Fullerton Adrian R. Fleissig, Ph

de Lijser, Peter

424

Southern California Leading EconomicSouthern California Leading EconomicSouthern California Leading EconomicSouthern California Leading Economic IndicatorIndicatorIndicatorIndicator November 2011 Institute for Economic and Environmental Studies (IEES), C  

E-Print Network [OSTI]

Southern California Leading EconomicSouthern California Leading EconomicSouthern California Leading EconomicSouthern California Leading Economic IndicatorIndicatorIndicatorIndicator November 2011 © Institute for Economic and Environmental Studies (IEES), California State University Fullerton Adrian R. Fleissig, Ph

de Lijser, Peter

425

Southern California Leading EconomicSouthern California Leading EconomicSouthern California Leading EconomicSouthern California Leading Economic IndicatorIndicatorIndicatorIndicator May 2014 Center for Economic Analysis and Forecasting (CEAF), California  

E-Print Network [OSTI]

Southern California Leading EconomicSouthern California Leading EconomicSouthern California Leading EconomicSouthern California Leading Economic IndicatorIndicatorIndicatorIndicator May 2014 © Center for Economic Analysis and Forecasting (CEAF), California State University Fullerton Adrian R. Fleissig, Ph

de Lijser, Peter

426

Southern California Leading EconomicSouthern California Leading EconomicSouthern California Leading EconomicSouthern California Leading Economic IndicatorIndicatorIndicatorIndicator August 2012 Institute for Economic and Environmental Studies (IEES), Cal  

E-Print Network [OSTI]

Southern California Leading EconomicSouthern California Leading EconomicSouthern California Leading EconomicSouthern California Leading Economic IndicatorIndicatorIndicatorIndicator August 2012 © Institute for Economic and Environmental Studies (IEES), California State University Fullerton Adrian R. Fleissig, Ph

de Lijser, Peter

427

Southern California Leading EconomicSouthern California Leading EconomicSouthern California Leading EconomicSouthern California Leading Economic IndicatorIndicatorIndicatorIndicator August 2011 Institute for Economic and Environmental Studies (IEES), Cal  

E-Print Network [OSTI]

Southern California Leading EconomicSouthern California Leading EconomicSouthern California Leading EconomicSouthern California Leading Economic IndicatorIndicatorIndicatorIndicator August 2011 © Institute for Economic and Environmental Studies (IEES), California State University Fullerton Adrian R. Fleissig, Ph

de Lijser, Peter

428

Southern California Leading EconomicSouthern California Leading EconomicSouthern California Leading EconomicSouthern California Leading Economic IndicatorIndicatorIndicatorIndicator February 2014 Center for Economic Analysis and Forecasting (CEAF), Calif  

E-Print Network [OSTI]

Southern California Leading EconomicSouthern California Leading EconomicSouthern California Leading EconomicSouthern California Leading Economic IndicatorIndicatorIndicatorIndicator February 2014 © Center for Economic Analysis and Forecasting (CEAF), California State University Fullerton Adrian R. Fleissig, Ph

de Lijser, Peter

429

Southern California Leading EconomicSouthern California Leading EconomicSouthern California Leading EconomicSouthern California Leading Economic IndicatorIndicatorIndicatorIndicator August 2014 Center for Economic Analysis and Forecasting (CEAF), Califor  

E-Print Network [OSTI]

Southern California Leading EconomicSouthern California Leading EconomicSouthern California Leading EconomicSouthern California Leading Economic IndicatorIndicatorIndicatorIndicator August 2014 © Center for Economic Analysis and Forecasting (CEAF), California State University Fullerton Adrian R. Fleissig, Ph

de Lijser, Peter

430

Lead(ii) Detection An Exceptionally Selective Lead(ii)-Regulatory  

E-Print Network [OSTI]

-spore- forming bacillus that flourishes in millimolar concentrations of toxic heavy metals.[12] It is the only that responds to lead(ii) ions with a high selectivity over other heavy metal ions. This has not been achieved developed for the detection of other small molecules, but with limited success for heavy metal ions

He, Chuan

431

Cool horizons lead to information loss  

E-Print Network [OSTI]

There are two evidences for information loss during black hole evaporation: (i) a pure state evolves to a mixed state and (ii) the map from the initial state to final state is non-invertible. Any proposed resolution of the information paradox must address both these issues. The firewall argument focuses only on the first and this leads to order one deviations from the Unruh vacuum for maximally entangled black holes. The nature of the argument does not extend to black holes in pure states. It was shown by Avery, Puhm and the author that requiring the initial state to final state map to be invertible mandates structure at the horizon even for pure states. The proof works if black holes can be formed in generic states and in this paper we show that this is indeed the case. We also demonstrate how models proposed by Susskind, Papadodimas et al. and Maldacena et al. end up making the initial to final state map non-invertible and thus make the horizon "cool" at the cost of unitarity.

Borun D. Chowdhury

2013-07-29T23:59:59.000Z

432

Chemisorption and catalysis by metal clusters. II. Chemisorption of carbon monoxide and of oxygen by supported osmium clusters derived from Os/sub 3/(CO)/sub 12/ and from Os/sub 6/(CO)/sub 18/  

SciTech Connect (OSTI)

Carbon monoxide and oxygen have been chemisorbed at 293 K on the high-nuclearity carbonyl-protected clusters (the various species A) obtained by heating in vacuo to 523 K Os/sub 3/(CO)/sub 12/ or Os/sub 6/(CO)/sub 18/ impregnated on silica, alumina, or titania. The adsorption isotherms have a conventional appearance, but most are composed of a primary and a secondary region. Material adsorbed in the secondary region is removed by evacuation at room temperature whereas that adsorbed in the primary region is removed by evacuation at elevated temperatures. For species A/alumina and the species A/titania the primary region is complete and the secondary region commences when the pressure over the adsorbent is 0.2 Torr. Species A/silica gave no secondary region in oxygen adsorption. Adsorption and subsequent temperature-programmed desorption of (/sup 18/O)CO occurred without any dilution by (/sup 16/O)CO, indicating that ligand-(/sup 16/O)CO and adsorbed-(/sup 18/O)CO do not exchange even at elevated temperatures. The two species A/aluminas catalyzed oxygen isotope exchange at 293 K. From the experimental evidence it is deduced that carbon monoxide and oxygen each adsorbs molecularly in both the primary and the secondary regions. In the primary region carbon monoxide adsorption occurs at osmium sites on the cluster framework, whereas in the secondary region it occurs at ligand-carbon bonded to osmium. For oxygen, adsorption in the primary region is again at osmium sites on the cluster framework but that in the secondary region is at osmium sites of the cluster framework suitably modified as a result of the support-cluster interaction.

Hunt, D.J.; Jackson, S.D.; Moyes, R.B.; Wells, P.B.; Whyman, R.

1984-04-01T23:59:59.000Z

433

The effect of ozone on nicotine desorption from model surfaces:evidence for heterogeneous chemistry  

SciTech Connect (OSTI)

Assessment of secondhand tobacco smoke exposure using nicotine as a tracer or biomarker is affected by sorption of the alkaloid to indoor surfaces and by its long-term re-emission into the gas phase. However, surface chemical interactions of nicotine have not been sufficiently characterized. Here, the reaction of ozone with nicotine sorbed to Teflon and cotton surfaces was investigated in an environmental chamber by monitoring nicotine desorption over a week following equilibration in dry or humid air (65-70 % RH). The Teflon and cotton surfaces had N{sub 2}-BET surface areas of 0.19 and 1.17 m{sup 2} g{sup -1}, and water mass uptakes (at 70 % RH) of 0 and 7.1 % respectively. Compared with dry air baseline levels in the absence of O{sub 3}, gas phase nicotine concentrations decrease, by 2 orders of magnitude for Teflon after 50 h at 20-45 ppb O{sub 3}, and by a factor of 10 for cotton after 100 h with 13-15 ppb O{sub 3}. The ratios of pseudo first-order rate constants for surface reaction (r) to long-term desorption (k) were r/k = 3.5 and 2.0 for Teflon and cotton surfaces, respectively. These results show that surface oxidation was competitive with desorption. Hence, oxidative losses could significantly reduce long-term re-emissions of nicotine from indoor surfaces. Formaldehyde, N-methylformamide, nicotinaldehyde and cotinine were identified as oxidation products, indicating that the pyrrolidinic N was the site of electrophilic attack by O{sub 3}. The presence of water vapor had no effect on the nicotine-O{sub 3} reaction on Teflon surfaces. By contrast, nicotine desorption from cotton in humid air was unaffected by the presence of ozone. These observations are consistent with complete inhibition of ozone-nicotine surface reactions in an aqueous surface film present in cotton but not in Teflon surfaces.

Destaillats, Hugo; Singer, Brett C.; Lee, Sharon K.; Gundel, LaraA.

2005-05-01T23:59:59.000Z

434

Macroencapsulation of lead and steel SWARF  

SciTech Connect (OSTI)

The treatability study to macroencapsulate radioactively contaminated lead and steel swarf (cuttings and/or chips)and chunks, a low level mixed waste, from the dismantlement of excess surplus uranium fuel handling and transfer casks was successful. Macroencapsulation is the land disposal restriction treatment standard for this waste form per 40 CFR 268.42 Table 3. An epoxy-based thermoset system was employed due to cracking failures of other types of thermoset systems. Bench scale tests were performed with a two-part epoxy (resin and hardener) using cast iron chips as a surrogate waste media. A two stage encapsulation process was employed in treating the swarf. Two liters of epoxy were added to a 2.8{ell} (3 qt) container of swarf under 51K Pa vacuum (-15-inch of Hg) during the first stage of the process. In this stage each individual particle or chip was wetted by epoxy and allowed to harden into an initial monolith. The second stage encapsulated the initial monolith with a secondary layer of epoxy forming a larger final monolith. By evacuating the air from the swarf and epoxy during the initial monolith encapsulation, a higher density (higher swarf to epoxy ratio) was achieved. Tensile and compressive strength tests were performed on samples and without any media (cast iron chips). The coupons were prepared from a series of monoliths featuring various mixtures ratios and vacuum levels. The tensile strength of epoxy without chips averaged 41M Pa (6000 psi) and 1.4M Pa (2000 psi) with cast iron chips. Compression strengths averaged 140M Pa (20,000 psi) without chips and 66.2M Pa (9600 psi) with cast iron chips.

Zirker, L.; Thiesen, T.; Tyson, D.; Beitel, G.

1995-12-01T23:59:59.000Z

435

ARM - Ozone  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc Documentation RUC : XDCResearchWarmingMethane BackgroundFacilityOther Aircraft

436

Reducing the contribution of the power sector to ground-level ozone pollution : an assessment of time-differentiated pricing of nitrogen oxide emissions  

E-Print Network [OSTI]

Nitrogen oxide (NOx) is a prevalent air pollutant across the United States and a requisite precursor for tropospheric (ground-level) ozone formation. Both pollutants significantly impact human health and welfare, so National ...

Craig, Michael T. (Michael Timothy)

2014-01-01T23:59:59.000Z

437

A cost-effectiveness analysis of alternative ozone control strategies : flexible nitrogen oxide (NOx) abatement from power plants in the eastern United States  

E-Print Network [OSTI]

Ozone formation is a complex, non-linear process that depends on the atmospheric concentrations of its precursors, nitrogen oxide (NOx) and Volatile Organic Compounds (VOC), as well as on temperature and the available ...

Sun, Lin, S.M. Massachusetts Institute of Technology

2009-01-01T23:59:59.000Z

438

QCD analysis and effective temperature of direct photons in lead-lead collisions at the LHC  

E-Print Network [OSTI]

We present a systematic theoretical analysis of the ALICE measurement of low-$p_T$ direct-photon production in central lead-lead collisions at the LHC with a centre-of-mass energy of $\\sqrt{s_{NN}}=2.76$ TeV. Using next-to-leading order of perturbative QCD, we compute the relative contributions to prompt-photon production from different initial and final states and the theoretical uncertainties coming from independent variations of the renormalisation and factorisation scales, the nuclear parton densities and the fragmentation functions. Based on different fits to the unsubtracted and prompt-photon subtracted ALICE data, we consistently find an exponential, possibly thermal, photon spectrum from the quark-gluon plasma (or hot medium) with slope $T=304\\pm 58$ MeV and $309\\pm64$ MeV at $p_T\\in[0.8;2.2]$ GeV and $p_T\\in[1.5;3.5]$ GeV as well as a power-law ($p_T^{-4}$) behavior for $p_T>4$ GeV as predicted by QCD hard scattering.

M. Klasen; C. Klein-Bösing; F. König; J. P. Wessels

2014-09-11T23:59:59.000Z

439

Recent results on electroweak probes in lead-lead and proton-lead collisions from the ATLAS Detector at the LHC  

E-Print Network [OSTI]

Photons and weak bosons do not interact strongly with the dense and hot medium formed in nuclear collisions, and thus they should be sensitive to the nuclear modification of parton distribution functions (nPDFs). In particular, proton-lead collisions provide an excellent opportunity to test nPDFs in a less dense environment than lead-lead. The ATLAS detector, optimized for searching new physics in proton-proton collisions, is especially well equipped to measure photons, Z and W bosons in the high occupancy environment produced in heavy ion collisions. Using the full data samples of 2.76 TeV lead-lead and 5.02 TeV proton-lead collisions we will present recent results on the prompt photon, Z and W boson yields as a function of centrality, transverse momentum and rapidity, from the ATLAS experiment. The binary collision scaling of the yields will be discussed in detail.

Brooks, William; The ATLAS collaboration

2015-01-01T23:59:59.000Z

440

Solar Decathlon Team Leading the Way Toward Sustainable Living...  

Broader source: Energy.gov (indexed) [DOE]

Leading the Way Toward Sustainable Living, Even in the Wake of Disasters Solar Decathlon Team Leading the Way Toward Sustainable Living, Even in the Wake of Disasters August 18,...

Note: This page contains sample records for the topic "monoxide ozone lead" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Anaerobic microbial dissolution of lead and production of organic acids  

DOE Patents [OSTI]

The present invention relates to a method of solubilizing lead, in the form of lead oxide, found in industrial wastes, before these wastes are dumped into the environment. The lead is solubilized by dissolving the lead oxide in the wastes through contact with an anaerobic bacterial culture containing the bacterium ATCC No. 53464. The solubilized lead can then be removed from the wastes by chemical separation. It could also be removed by extending the contact period with the bacterial culture. As the culture grows, the solubilized lead is removed from the wastes by bioaccumulation by the microorganism or by immobilization by a polymer-like material produced by the microorganism. At this point, the lead is then removed from the wastes when the waste material is separated from the bacterial culture. If desired, the bacterial culture could be digested at this point to yield relatively pure lead for further industrial use.

Francis, A.J.; Dodge, C.; Chendrayan, K.

1986-02-28T23:59:59.000Z

442

COWBOYS OR COMMANDERS: DOES INFORMATION TECHNOLOGY LEAD TO DECENTRALIZATION?  

E-Print Network [OSTI]

COWBOYS OR COMMANDERS: DOES INFORMATION TECHNOLOGY LEAD TO DECENTRALIZATION? George M. Wyner Thomas) predicted that information technology would lead to the elimination of middle managers and to greater (Eds.), International Conference on Information Systems, Cleveland, International Conference

443

FTIR study of hydrogen and carbon monoxide adsorption on Pt/TiO{sub 2}, Pt/ZrO{sub 2}, and Pt/Al{sub 2}O{sub 3}  

SciTech Connect (OSTI)

The Pt/TiO{sub 2}, Pt/ZrO{sub 2}, and Pt/Al{sub 2}O{sub 3} catalysts submitted to low-temperature reduction (LTR,200 C) and high-temperature reduction (HTR, 500 C) and exposed to hydrogen and carbon monoxide at room temperature were studied by infrared spectroscopy. There is a strong loss of transmission in the entire infrared spectra on Pt/TiO{sub 2} after its exposure to hydrogen, which is related to the reducibility of the support. A typical SMSI behavior (strong metal-support interaction), such as the decrease in carbon monoxide adsorption capacity, was detected on Pt/TiO{sub 2} and Pt/ZrO{sub 2} after exposure to hydrogen, even for the catalysts submitted to LTR treatment. Also a carbonyl band shift to lower wavenumber was observed on LTR-treated Pt/TiO{sub 2}, Pt/ZrO{sub 2}, and Pt/Al{sub 2}O{sub 3} after exposure to hydrogen. The authors interpreted this SMSI behavior as an electronic rather than morphological effect, which was induced by the presence of hydrogen spillover.

Benvenutti, E.V.; Franken, L.; Moro, C.C.; Davanzo, C.U.

1999-11-09T23:59:59.000Z

444

Lead-Free Surface Finishes for Electronic Components  

E-Print Network [OSTI]

Lead-Free Surface Finishes for Electronic Components: Tin Whisker Growth METALS This project degraded by the switch to lead- free technology. In particular, the state of compressive stress and the localized creep response (whisker growth) of tin-based lead-free electrodeposits are being measured

445

FOR MORE INFORMATION, CONTACT: TP Straatsma, Initiative Lead  

E-Print Network [OSTI]

FOR MORE INFORMATION, CONTACT: TP Straatsma, Initiative Lead 509-375-2802 tps@pnl.gov www.pnl.gov e Development of Exascale Algorithms for Molecular Modeling Lead investigator: Dr. Karol Kowalski Researchers Optimizations for Extreme Scale Systems Lead investigator: Dr. Daniel Chavarria Exascale systems will provide

446

THE LEAD AND COPPER RULE Anne Sandvig, HDR-EES  

E-Print Network [OSTI]

THE LEAD AND COPPER RULE Anne Sandvig, HDR-EES 2008 Historical Background The 1986 Safe Drinking districts and was not mandated. In 1991, the USEPA finalized the Lead and Copper Rule (LCR) in response components and by August 1998 manufacturers were required to comply. The Lead and Copper Rule #12;The USEPA

Maynard, J. Barry

447

Technical Note Ultrasound Probe with Integrated ECG Lead: Feasibility Study  

E-Print Network [OSTI]

Technical Note Ultrasound Probe with Integrated ECG Lead: Feasibility Study ARCHANA RAMIREDDY 27708 stephen.w.smith@duke.edu We integrated electrocardiogram (ECG) leads onto the face of a cardiac of devices needed to col- lect cardiac information. Since the ECG leads were not placed on their standard

Smith, Stephen

448

Sandia National Laboratories: carbon monoxide  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the1development Sandia, NREL Release Wavearc-faultbest

449

Removal of pollutant compounds from water supplies using ozone, ultraviolet light, and a counter, current packed column. Master's thesis  

SciTech Connect (OSTI)

Many water pollutants are determined to be carcinogenic and often appear in very low concentrations and still pose a health risk. Conventional water treatment processes cannot remove these contaminants and there is a great demand for the development of alternative removal technologies. The use of ozone and ultraviolet light in a counter current packed column could prove to be an effective treatment process to remove these contaminants.

Kelly, E.L.

1991-01-01T23:59:59.000Z

450

Lead contamination around a kindergarten near a battery recycling plant  

SciTech Connect (OSTI)

Lead poisoning has been noticed for more than a thousand years. Increased lead absorption and/or impaired neurobehavioral function among children who lived nearby lead smelters were reported in many different countries. In November of 1987, a worker from a lead battery recycling smelter suffered from anemia and bilateral weakness of his extremities. He was diagnosed as lead poisoning at the National Taiwan University Hospital (NTUH). A subsequent epidemiological survey of the workers from this recycling smelter showed that 31 out of 64 who came for a medical examination suffered from lead poisoning. Since there was a kindergarten next to the factory, we performed this study to determine whether there was an increased lead absorption among children of the exposed kindergarten and its association with the extent of air and soil pollution in the surrounding area. 12 refs., 1 fig., 4 tabs.

Jung-Der Wang; Chang-Sheng Jang; Yaw-Huei Hwang; Zueng-Sang Chen [National Taiwan Univ. (China)

1992-07-01T23:59:59.000Z

451

On the initial phenomena occurring in lead/lead collisions at relativistic energies  

E-Print Network [OSTI]

A new study of the initial phenomena occurring in the fireball should confirm the predicted creation of a new state of nuclear matter having a lifetime of 0.17 yoctosecond and releasing an energy of 3.87 GeV. The energy-time uncertainty relation might be connected with an up to now unsuspected momentum-position uncertainty relation holding in a three-dimensional time. This new point of view leads to the interpretation of the charge of a particle as being a rotational motion in time, to a new interpretation of inertia, and to a new interpretation of the color of a particle. The transverse momentum observed in the study of the fireball might be the signature of this motion in time of the charge.

C. Ythier; G. Mouze

2012-12-18T23:59:59.000Z

452

Time-integrated blood lead concentration is a valid surrogate for estimating the cumulative lead dose assessed by tibial lead measurement  

SciTech Connect (OSTI)

The concentration of lead in tibia (Pb-T) was measured in vivo by a {sup 109}Cd K-shell X-ray fluorescence technique in 123 workers from a primary lead smelter (age: mean, 45 years; range, 30-61; duration of employment: mean, 20 years; range, 7-45). Their cumulative blood lead index (CBLI) was also calculated on the basis of the blood lead (Pb-B) records available from the company`s medical files. Geometric mean for Pb-T was 49 {mu}g Pb/g bone mineral (range, 15-167). The company`s health surveillance programs, implemented since 1945, resulted in Pb-B values which rarely exceeded 70 {mu}g Pb/dl whole blood. Pb-B at the time of Pb-T measurement averaged 31 {mu}g Pb/dl (range, 6-62) and the geometric mean for CBLI amounted to 803 {mu}g Pb/dl x year (range, 220-2130). Despite various assumptions and uncertainties inherent in the assessment of the cumulative lead dose through Pb-T measurement or CBLI calculation, the relation between both variables in the present lead smelter population is very strong (r{sub pearson}= 0.80, P <0.0001; age explained at the most 9.5% of the variance). The slope of the regression equation of log Pb-T vs log CBLI showed that a doubling of CBLI also corresponds to a doubling of Pb-t. It may be concluded that a sound calculation of CBLI represents a valid surrogate for estimating the life time integrated dose of lead as assessed by the measurement of cortical bone lead (e.g., in tibia). 23 refs., 2 figs., 3 tabs.

Roels, H.; Konings, J.; Lauwerys, R. [Medical School of the Catholic Univ. of Louvain, Brussels (Belgium)] [and others] [Medical School of the Catholic Univ. of Louvain, Brussels (Belgium); and others

1995-05-01T23:59:59.000Z

453

Respiratory responses of vigorously exercising children to 0. 12 ppm ozone exposure  

SciTech Connect (OSTI)

Changes in respiratory function have been suggested for children exposed to less than 0.12 ppm ozone (O3) while engaged in normal activities. Because the results of these studies have been confounded by other variables, such as temperature or the presence of other pollutants or have been questioned as to the adequacy of exposure measurements, the authors determined the acute response of children exposed to 0.12 ppm O3 in a controlled chamber environment. Twenty-three white males 8 to 11 yr of age were exposed once to clean air and once to 0.12 ppm O3 in random order. Exposures were for 2.5 h and included 2 h of intermittent heavy exercise. Measures of forced expiratory volume in one second (FEV1) and the symptom cough were determined prior to and after each exposure. A significant decline in FEV1 was found after the O3 exposure compared to the air exposure, and it appeared to persist for 16 to 20 h. No significant increase in cough was found due to O3 exposure. Forced vital capacity, specific airways resistance, respiratory frequency, tidal volume, and other symptoms were measured in a secondary exploratory analysis of this study.

McDonnell, W.F. 3d.; Chapman, R.S.; Leigh, M.W.; Strope, G.L.; Collier, A.M.

1985-10-01T23:59:59.000Z

454

Comparison of the responses of children and adults to acute ozone exposure  

SciTech Connect (OSTI)

The purpose of the paper is to compare the results of two studies in which the respiratory responses of children and adults to acute ozone (O/sub 3/) exposure were measured. Forty-two 18-30 year old males were exposed for 2.5 hours in a controlled environmental chamber to either 0.0 or 0.12 ppm O3 while performing intermittent heavy exercise. Twenty-two 8-11 year old males were exposed in a similar manner to both air and 0.12 ppm O3. Measures of respiratory symptoms and function were made before and after exposure. Adults experienced an increase in the symptom cough and decrements in forced vital capacity and some measures of forced expiratory flow. Children experienced similar decrements in pulmonary function, but had no increase in symptoms. The authors concluded that as measured by pulmonary function children appear to be no more responsive to O3 exposure than are adults and may experience fewer symptoms.

McDonnell, W.F.; Chapman, R.S.; Horstman, D.H.; Leigh, M.W.; Salaam, S.A.

1986-07-01T23:59:59.000Z

455

ELLIPSOMETRY OF SURFACE LAYERS ON LEAD AND LITHIUM  

E-Print Network [OSTI]

Surface Layers on Lead and Lithium By Richard Dudley Peterssulfuric acid and and lithium to water, Acid concentrationsbeen observed in the reaction of lithium with water vapor. i

Peters, Richard Dudley

2011-01-01T23:59:59.000Z

456

Sec. Herrington Leads Delegation in Response to Chernobyl Accident...  

National Nuclear Security Administration (NNSA)

Herrington leads U.S. delegation to Special Session of the International Atomic Energy Agency General Conference in Vienna, Austria, to discuss measures to strengthen...

457

West Africa Emerges as Leading Region in Africa for Renewable...  

Open Energy Info (EERE)

West Africa Emerges as Leading Region in Africa for Renewable Energy and Energy Efficiency Home > Groups > Clean and Renewable Energy Dc's picture Submitted by Dc(107) Contributor...

458

United States Department Of The Navy Geothermal Exploration Leading...  

Open Energy Info (EERE)

Navy Geothermal Exploration Leading To Shallow And Intermediate-Deep Drilling At Hawthorne Ammunition Depot, Hawthorne, Nv Jump to: navigation, search OpenEI Reference LibraryAdd...

459

Researchers hope better catalysts lead to better ways of converting...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Researchers hope better catalysts lead to better ways of converting biomass to fuel By Jared Sagoff * August 7, 2013 Tweet EmailPrint ARGONNE, Ill. - Scientists and entrepreneurs...

460

acid mmaiii leads: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Theses and Dissertations Summary: ??The performance of lead-acid batteries for energy storage in photovoltaicdieselbattery hybrid systems strongly depends on several...

Note: This page contains sample records for the topic "monoxide ozone lead" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Sandia National Laboratories: Due Diligence on Lead Acid Battery...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

the lead acid batteries are processed and recycled legally under a regularly audited New Mexico hazardous waste management permit, Pollution Prevention (P2) was prompted to...

462

adult mice leads: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

tell parents Internet -While adults worry about unknowns, teens bond and learn social and lead- Computer Technologies and Information Sciences Websites Summary: Kid online? Relax,...

463

anterior resection leading: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

ear, High grade mucoepidermoid carcinoma, Temporal bone resection unknown authors 59 LEAD POISONING PREVENTION INFORMATION Environmental Sciences and Ecology Websites Summary:...

464

aureus pneumonia leading: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

words, phrases, or symbols indicated by the clue. When you think you Sherriff, Mark S. 92 LEAD POISONING PREVENTION INFORMATION Environmental Sciences and Ecology Websites Summary:...

465

adrenal medulla leads: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Inga Voges; Friedrich Pahlke; Christoph Dodt; Peter Dominiak; Olaf Jhren 2006-01-01 67 LEAD POISONING PREVENTION INFORMATION Environmental Sciences and Ecology Websites Summary:...

466

The Global Anthropogenic Lead Experiment Earth, Atmospheric and Planetary Sciences  

E-Print Network [OSTI]

, coal combustion, incineration, cement manufacture). · Leaded gasoline utilization creates fine activities (smelting, coal burning, etc.) · Incineration -------------------------- · "Tin" can solder seams

Einat, Aharonov

467

A leading index of drilling activity: Update and improvements  

SciTech Connect (OSTI)

A five-component composite leading index of United States rotary rig drilling activity is updated. The index is presented for 1949 through April 1986 and is shown to consistently lead turning points in drilling activity. Seven new leading indices based on some new components are also presented. A forecast of drilling activity is made for the remainder of 1986 based on the leading index and the current economic condition of the petroleum industry. The methods used to prepare time series and construct indices are reviewed.

Buell, R.S.; Maurer, R.A.

1986-01-01T23:59:59.000Z

468

Automated portable analyzer for lead(II) based on sequential...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

flow technique which required minimal volume of samples and reagents and allowed the automation of the analyzer operation. The portable analyzer was evaluated for lead (Pb)...

469

Energy Data Management Lead-by-Example Resources  

Broader source: Energy.gov [DOE]

State and local governments can lead by example by promoting energy efficiency programs and policies for public facilities, equipment, and government operations.

470

NERSC Leads Next-Generation Code Optimization Effort  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Leads Next-Generation Code Optimization Effort NERSC Launches Next-Generation Code Optimization Effort NERSC, Intel, Cray team up to prepare users for transition to exascale...

471

Paul Langan to lead ORNL's Neutron Sciences Directorate | ornl...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

science activities, which include two leading DOE Office of Science user facilities for neutron scattering analysis: The Spallation Neutron Source (SNS) and the High Flux Isotope...

472

AVTA: 2010 Honda Civic HEV with Experimental Ultra Lead Acid...  

Broader source: Energy.gov (indexed) [DOE]

and development. The following reports describe results of testing done on a 2010 Civic hybrid electric vehicle with an advanced experimental ultra-lead acid battery, an...

473

An Insoluble Titanium-Lead Anode for Sulfate Electrolytes  

SciTech Connect (OSTI)

The project is devoted to the development of novel insoluble anodes for copper electrowinning and electrolytic manganese dioxide (EMD) production. The anodes are made of titanium-lead composite material produced by techniques of powder metallurgy, compaction of titanium powder, sintering and subsequent lead infiltration. The titanium-lead anode combines beneficial electrochemical behavior of a lead anode with high mechanical properties and corrosion resistance of a titanium anode. In the titanium-lead anode, the titanium stabilizes the lead, preventing it from spalling, and the lead sheathes the titanium, protecting it from passivation. Interconnections between manufacturing process, structure, composition and properties of the titanium-lead composite material were investigated. The material containing 20-30 vol.% of lead had optimal combination of mechanical and electrochemical properties. Optimal process parameters to manufacture the anodes were identified. Prototypes having optimized composition and structure were produced for testing in operating conditions of copper electrowinning and EMD production. Bench-scale, mini-pilot scale and pilot scale tests were performed. The test anodes were of both a plate design and a flow-through cylindrical design. The cylindrical anodes were composed of cylinders containing titanium inner rods and fitting over titanium-lead bushings. The cylindrical design allows the electrolyte to flow through the anode, which enhances diffusion of the electrolyte reactants. The cylindrical anodes demonstrate higher mass transport capabilities and increased electrical efficiency compared to the plate anodes. Copper electrowinning represents the primary target market for the titanium-lead anode. A full-size cylindrical anode performance in copper electrowinning conditions was monitored over a year. The test anode to cathode voltage was stable in the 1.8 to 2.0 volt range. Copper cathode morphology was very smooth and uniform. There was no measurable anode weight loss during this time period. Quantitative chemical analysis of the anode surface showed that the lead content after testing remained at its initial level. No lead dissolution or transfer from the anode to the product occurred.A key benefit of the titanium-lead anode design is that cobalt additions to copper electrolyte should be eliminated. Cobalt is added to the electrolyte to help stabilize the lead oxide surface of conventional lead anodes. The presence of the titanium intimately mixed with the lead should eliminate the need for cobalt stabilization of the lead surface. The anode should last twice as long as the conventional lead anode. Energy savings should be achieved due to minimizing and stabilizing the anode-cathode distance in the electrowinning cells. The anode is easily substitutable into existing tankhouses without a rectifier change.The copper electrowinning test data indicate that the titanium-lead anode is a good candidate for further testing as a possible replacement for a conventional lead anode. A key consideration is the cost. Titanium costs have increased. One of the ways to get the anode cost down is manufacturing the anodes with fewer cylinders. Additional prototypes having different number of cylinders were constructed for a long-term commercial testing in a circuit without cobalt. The objective of the testing is to evaluate the need for cobalt, investigate the effect of decreasing the number of cylinders on the anode performance, and to optimize further the anode design in order to meet the operating requirements, minimize the voltage, maximize the life of the anode, and to balance this against a reasonable cost for the anode. It is anticipated that after testing of the additional prototypes, a whole cell commercial test will be conducted to complete evaluation of the titanium-lead anode costs/benefits.

Ferdman, Alla

2005-05-11T23:59:59.000Z

474

Activation of phospholipase A{sub 2} in 1-palmitoyl-2-oleoyl-sn-glycero-3-phosphocholine liposomes containing lipid ozonation products  

SciTech Connect (OSTI)

The activation of phospholipase A{sub 2} (PLA{sub 2}) by lipid ozonation products is reported. The principal products from the ozonation of 1-palmitoyl-2-oleoyl-sn-glycero-3-phosphocholine (POPC) are 1-palmitoyl-2-[8-3(5-octyl-1,2,4-trioxolan-3-yl)octanoyl]--sn-glycero-3-phosphocholine (PC-Criegee ozonide) and 1-palmitoyl-2-(9-oxononanoyl)-sn-glycero-3-phosphocholine (PC-aldehyde). Here we test the hypothesis that these two compounds are mediators of ozone toxicity. Using POPC vesicles, we find that PLA{sub 2} recognizes and hydrolyzes PC-Criegee ozonide at the same rate as that of arachidonic acid. Although the PC-aldehyde is not a substrate for PLA{sub 2}, the enzymatic rate of hydrolysis by PLA{sub 2} of unaltered fatty acids incorporated into POPC is enhanced when PC-aldehyde is present in the bilayer. Thus, both PC-Criegee ozonide and PC-aldehyde alter the activity of PLA{sub 2}, perhaps via an effect on membrane packing order. The capacity of PLA{sub 2} to recognize the PC-Criegee, and therefore ozone-induced damage, suggests a detoxification property of the enzyme and also a role in maintaining the structural properties of bilayer membranes that have been altered by exposure to ozone. 29 refs., 3 figs., 1 tab.

Salgo, M.G.; Squadrito, G.L.; Pryor, W.A. [Louisiana State Univ., Baton Rouge, LA (United States)

1994-05-01T23:59:59.000Z

475

Exhaust-catalyst development for methanol-fueled vehicles. II. Synergism between palladium and silver in methanol and carbon monoxide oxidation over an alumina-supported palladium-silver catalyst  

SciTech Connect (OSTI)

Methanol and carbon monoxide oxidation were examined over 0.01 Pd, 5% Ag, and 0.01% Pd/5% Ag catalysts - all supported on ..gamma..-alumina. The bimetallic catalyst showed greater CO and CH/sub 3/OH oxidation activity than either of the single-component catalysts; moreover, the Pd and Ag interacted synergistically in the bimetallic catalyst to produce greater CO and CH/sub 3/OH oxidation rates and lower yields of methanol partial oxidation products than expected from a mixture of the single-component catalysts. Temperature-programmed oxidation experiments and reactivity experiments involving changes in O/sub 2/ partial pressure both provided evidence that the Pd-Ag synergism results from Pd promoting the rate of O/sub 2/ adsorption and reaction with CO and CH/sub 3/OH on Ag. The data also indicate that virtually all of the Pd in the bimetallic catalyst is present in Pd-Ag crystallites.

McCabe, R.W.; Mitchell, P.J.

1987-02-01T23:59:59.000Z

476

Geochemical study of lead in soils from West Dallas, Texas  

SciTech Connect (OSTI)

Soil samples from West Dallas near the RSR smelter were collected and tested to see the content, source, and mobility of lead. 30 cm and 90 cm long cores were cut into 1 cm long pieces and each piece analyzed separately. The results showed that 90%--95% of the lead is readily extractable in cold dilute nitric acid. The lateral distribution of lead in West Dallas indicates an exponential-like decrease with distance from the RSR smelter. Concentrations greater than 500 ppm occur in soils below 10 cm within 1,000 feet of the smelter. In the vicinity of the smelter (300 feet radius), soil cores with total lead content as high as 18,000 ppm in the top 15 cm were obtained. At a distance of 2,400 feet of the smelter the lead in the soil amounts to 400 ppm and drops to 270 ppm at 4,000 feet. The total lead content with depth, correlates with previous clean-up and civil activities in the area: (1) where the soil is original, the lead concentration decreases exponentially with depth; (2) where the soil was cleaned up, the top 10 cm are devoid of lead but are underlain by soil whose lead content varies in response to distance from the smelter; (3) where the top soil had been disturbed (removed, replaced, mixed, etc.) as a result of civil works, the lead content is relatively lower than 1 (above). The underlying insitu soils exhibit similar lead concentration as those in 2 (above).

Ibrahim, N.M.; Carter, J.L. (Univ. of Texas, Dallas, TX (United States). Programs in Geosciences)

1993-02-01T23:59:59.000Z

477

Know Stroke Stroke is the third leading cause of  

E-Print Network [OSTI]

#12;Know Stroke Stroke is the third leading cause of death in the United States and a leading cause of serious, long-term disability in adults. About 600,000 new strokes are reported in the U.S. each year. The good news is that treatments are available that can greatly reduce the damage caused by a stroke

Bandettini, Peter A.

478

Biosorption of Lead and Nickel by Biomass of Marine Algae  

E-Print Network [OSTI]

Biosorption of Lead and Nickel by Biomass of Marine Algae Z.R. Holan and B. Volesky" Department 22, 1993 Screening tests of different marine algae biomass types revealed a high passive biosorptive uptake of lead up to 270 mg Pb/g of biomass in some brown marine algae. Members of the order Fucales

Volesky, Bohumil

479

Following Germany's Lead: Using International Monetary Linkages to Estimate  

E-Print Network [OSTI]

Following Germany's Lead: Using International Monetary Linkages to Estimate the Effect of Monetary to countries with the weakest economic ties to Germany. We thank participants at the 2004 NBER Summer Workshop (2001). 2 Many European countries followed Germany's lead in setting their monetary policy during our

Sadoulet, Elisabeth

480

A Study of Lead Ingot Cargoes from Ancient Mediterranean Shipwrecks  

E-Print Network [OSTI]

Lead is often relegated to a footnote or sidebar in the study of ancient metals. However, the hundreds of lead ingots discovered in underwater sites over the past half-century have attested to the widespread production and trade of this utilitarian...

Brown, Heather Gail

2011-10-21T23:59:59.000Z

Note: This page contains sample records for the topic "monoxide ozone lead" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

FINAL LEAD COMMISSIONER REPORT 2012 INTEGRATED ENERGY POLICY  

E-Print Network [OSTI]

FINAL LEAD COMMISSIONER REPORT 2012 INTEGRATED ENERGY POLICY REPORT UPDATE CALIFORNIA COMMISSION Carla J. Peterman Lead Commissioner, Integrated Energy Policy Report Robert P. Oglesby Executive was prepared under the 2012 Integrated Energy Policy Report proceeding, Docket #12-IEP-1A. The final report

482

assassination bullet lead: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

assassination bullet lead First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 August 2014 Lead isotopes and...

483

Partially Extracted Defibrillator Coils and Pacing Leads Alter Defibrillation Thresholds  

E-Print Network [OSTI]

effect on DFTs. Introduction: Sudden cardiac death is the leading cause of death in the United States with 325,000 deaths per year. This translates to 1,000 deaths per day or 1 death every two minutes.1 USA Summary: Abandoned ICD coils and pacing leads provide a conductor substrate for electric field

Utah, University of

484

Method for fabricating fan-fold shielded electrical leads  

DOE Patents [OSTI]

Fan-folded electrical leads made from copper cladded Kapton, for example, with the copper cladding on one side serving as a ground plane and the copper cladding on the other side being etched to form the leads. The Kapton is fan folded with the leads located at the bottom of the fan-folds. Electrical connections are made by partially opening the folds of the fan and soldering, for example, the connections directly to the ground plane and/or the lead. The fan folded arrangement produces a number of advantages, such as electrically shielding the leads from the environment, is totally non-magnetic, and has a very low thermal conductivity, while being easy to fabricate. 3 figures.

Rohatgi, R.R.; Cowan, T.E.

1994-12-27T23:59:59.000Z

485

Method for fabricating fan-fold shielded electrical leads  

DOE Patents [OSTI]

Fan-folded electrical leads made from copper cladded Kapton, for example, with the copper cladding on one side serving as a ground plane and the copper cladding on the other side being etched to form the leads. The Kapton is fan folded with the leads located at the bottom of the fan-folds. Electrical connections are made by partially opening the folds of the fan and soldering, for example, the connections directly to the ground plane and/or the lead. The fan folded arrangement produces a number of advantages, such as electrically shielding the leads from the environment, is totally non-magnetic, and has a very low thermal conductivity, while being easy to fabricate.

Rohatgi, Rajeev R. (Mountain View, CA); Cowan, Thomas E. (Livermore, CA)

1994-01-01T23:59:59.000Z

486

Development of lead-free solders for hybrid microcircuits  

SciTech Connect (OSTI)

Extensive work has been conducted by industry to develop lead-free solders for electronics applications. The driving force behind this effort is pressure to ban or tax the use of lead-bearing solders. There has been further interest to reduce the use of hazardous chemical cleaners. Lead-free soldering and low-residue, ``no clean`` assembly processing are being considered as solutions to these environmental issues. Most of the work has been directed toward commercial and military printed wiring board (PWB) technology, although similar problems confront the hybrid microcircuit (HMC) industry, where the development of lead-free HMC solders is generally lagging. Sandia National Laboratories is responsible for designing a variety of critical, high reliability hybrid components for radars. Sandia has consequently initiated a project, as part of its Environmentally Conscious Manufacturing program, to develop low-residue, lead-free soldering for HMCs. This paper discusses the progress of that work.

Hosking, F.M.; Vianco, P.T.; Frear, D.R.; Robinson, D.G.

1996-01-01T23:59:59.000Z

487

Effect of the {delta}-aminolevulinate dehydratase polymorphism on the accumulation of lead in bone and blood in lead smelter workers  

SciTech Connect (OSTI)

Lead inhibition of the zinc metalloenzyme {delta}-aminolevulinate dehydratase (ALAD) is one of the most sensitive indicators of blood lead levels. Whole blood lead, serum lead, and ALAD genotype were determined for 381 lead smelter workers, including 70 workers expressing the ALAD allele, whose blood lead elevations were observed for more than 20 years of employment. The same employees demonstrated higher serum lead levels. Using a cumulative blood lead index (CBLI) for each worker, based on individual blood lead histories, and in vivo X-ray fluorescence measurements of bone lead to estimate total lead body burden, the slopes of linear relations of bone lead to CBLI were greater for workers homoallelic for ALAD, indicating more efficient uptake of lead from blood into bone. This effect was most significant in calcaneus bone and for workers hired since 1977. Decreased transfer of blood lead into bone in individuals expressing the ALAD allele contrasted with increased blood lead.

Fleming, D.E.B.; Chettle, D.R. [McMaster Univ., Hamilton, Ontario (Canada). Dept. of Physics and Astronomy] [McMaster Univ., Hamilton, Ontario (Canada). Dept. of Physics and Astronomy; Wetmur, J.G.; Desnick, R.J. [Mount Sinai School of Medicine, New York, NY (United States)] [Mount Sinai School of Medicine, New York, NY (United States); Robin, J.P. [Noranda Inc., Montreal, Quebec (Canada)] [Noranda Inc., Montreal, Quebec (Canada); Boulay, D.; Richard, N.S. [Brunswick Mining and Smelting Corp. Ltd., Belledune, New Brunswick (Canada). Occupational Health Services] [Brunswick Mining and Smelting Corp. Ltd., Belledune, New Brunswick (Canada). Occupational Health Services; Gordon, C.L.; Webber, C.E. [Hamilton Health Sciences Corp., Hamilton, Ontario (Canada). Dept. of Nuclear Medicine] [Hamilton Health Sciences Corp., Hamilton, Ontario (Canada). Dept. of Nuclear Medicine

1998-04-01T23:59:59.000Z

488

Anaerobic microbial dissolution of lead and production of organic acids  

DOE Patents [OSTI]

The present invention relates to an anaerobic bacterial culture of Clostridium sp. ATCC No. 53464 which solubilizes lead oxide under anaerobic conditions in coal and industrial wastes and therefore presents a method of removing lead from such wastes before they are dumped into the environment. The rate of lead dissolution during logarithmic growth of the bacteria in 40 ml medium containing 3.32 .mu.moles of lead as lead oxide was 0.042 .mu.moles ml.sup.-1 hr.sup.-1. Dissolution of lead oxide by the bacterial isolate is due to the production of metabolites and acidity in the culture medium. The major metabolites are acetic, butyric and lactic acid. Clostridium sp. ATCC No. 53464 can be used in the recovery of strategic metals from ores and wastes and also for the production of lactic acid for commercial purposes. The process yields large quantities of lactic acid as well as lead complexed in a stable form with said acids.

Francis, Arokiasamy J. (Middle Island, NY); Dodge, Cleveland (Wading River, NY); Chendrayan, Krishnachetty (Coimbatore Tamil Nadu, IN); Quinby, Helen L. (Cambridge, MD)

1988-01-01T23:59:59.000Z

489

Anaerobic microbial dissolution of lead and production of organic acids  

DOE Patents [OSTI]

The present invention related to an anaerobic bacterial culture of Clostridium sp. ATCC No. 53464 which solubilizes lead oxide under anaerobic conditions in coal and industrial wastes and therefore presents a method of removing lead from such wastes before they are dumped into the environment. The rat of lead dissolution during logarithmic growth of the bacteria in 40 ml medium containing 3.32 ..mu..moles of lead as lead oxide was 0.042 ..mu..moles m1/sup /-/1/ hr/sup /-/1/. Dissolution of lead oxide by the bacterial isolate is due to the production of metabolites and acidity in the culture medium. The major metabolites are acetic, butyric and lactic acid. The major metabolites are acetic, butyric and lactic acid. Clostridium sp. ATCC No. 53464 can be used in the recovery of the strategic metals from ores and wastes and also for the production of lactic acid for commercial purposes. The process yields large quantities of lactic acid as well as lead complexed in a stable form with said acids. 4 figs., 3 tabs.

Francis, A.J.; Dodge, C.; Chendrayan, K.; Quinby, H.L.

1987-04-16T23:59:59.000Z

490

Pilot study dismantlement of 20 lead-lined shipping casks  

SciTech Connect (OSTI)

This report describes a pilot study conducted at the INEL to dismantle lead-lined casks and shielding devices, separate the radiologically contaminated and hazardous materials, and recycle resultant scrap lead. The facility areas where the work was performed, dismantlement methods, and process equipment are described. Issues and results associated with recycling the lead as a free-released scrap metal are presented and discussed. Data and results from the pilot study are summarized and presented. The study concluded that cask dismantlement at the INEL can be performed as a legitimate recycling activity for scrap lead. Ninety-one percent of the lead recovered passed free-release criteria. The value of the 50,375 lb of recovered lead is approximately $0.45/lb. Resultant waste streams can be satisfactorily treated and disposed. Only very low levels of bulk radiological contamination (47 picocuries/gram of 137 Cs and 3.2 picocuries/gram of {sup 6O}Co) were detected in the lead rejected for free release.

Thurmond, S.M.

1995-08-01T23:59:59.000Z

491

Blood lead levels and remediation of an abandoned smelter site  

SciTech Connect (OSTI)

Elevated soil lead levels were documented in a New Mexico community, with levels up to 24,800 ppm in a smelter slag pile, 20 or more feet from residences. The New Mexico Department of Health offered blood lead screening to residents of three geographic areas before and after an emergency cleanup by the US Environmental Protection Agency. Blood lead levels prior to the cleanup ranged from undetectable (< 5 {mu}g/dl) to 29 {mu}g/dl; after the cleanup, they ranged from undetectable to 10 {mu}g/dl. Significant reductions in mean blood lead levels after the cleanup were found for all three geographic areas: from 6.67 {mu}g/dl to 4 {mu}dl (smelter area), from 4.12 {mu}g/dl to 2.5 {mu}g/dl (town area), and from 5.5 {mu}g/dl to 2.5 {mu}g/dl (northeast area). In both years, the mean blood lead levels of individuals who lived near the smelter area were significantly higher than the levels for those living in town for those participating in both years of the study. Mean blood lead levels were significantly higher for smelter area participants who had a household member working at a lead battery plant (19.4 {mu}g/dl) compared to those residents who did not (5.83 {mu}g/dl).

Eidson, M. [New Mexico Dept. of Health, Santa Fe, NM (United States). Div. of Epidemiology, Evaluation, and Planning; Tollestrup, K. [Univ. of New Mexico School of Medicine, Albuquerque, NM (United States). Family and Community Medicine Dept.

1995-05-01T23:59:59.000Z

492

Air-Quality Data from NARSTO (North American Research Strategy for Tropospheric Ozone)  

DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

NARSTO is a public/private partnership dedicated to improving management of air quality in North America. It was established on February 13, 1995 when representatives of Canada, the United States, and Mexico signed the NARSTO Charter in a ceremony at the White House. The Department of Energy is one of the charter members providing funding. The central programmatic goal of NARSTO is to provide data and information for use in the determination of workable, efficient, and effective strategies for local and regional ozone and fine particle management. Since its founding, NARSTO has completed three major scientific Assessments of critical air quality management issues. NARSTO maintains the Quality Systems Science Center and the NARSTO Data Archive for storing data from NARSTO Affiliated Research Activities and making these data available to the scientific community. NARSTO also facilitates activities, such as the Reactivity Research Working Group, which provide critical reviews of the state of the science in areas of interest to air quality policy makers. In January 1997, the U.S. Department of Energy's Environmental Sciences Division announced their sponsorship of the NARSTO Quality Systems Science Center (QSSC). The QSSC is located at the Oak Ridge National Laboratory within the Carbon Dioxide Information Analysis Center (CDIAC). Quality Assurance and Data Management assistance and guidelines are provided by the QSCC, along with access to data files. The permanent data archive is maintained by the NASA EOSDIS Distributed Active Archive Center at the Langley Research Center. The archived data can be reached by a link from the QSSC.(Specialized Interface) See also the NARSTO web site at http://www.narsto.org/

493

An examination of utility emissions contributions to elevated ozone concentrations in the Chicago area  

SciTech Connect (OSTI)

In order to reduce the pollutant load to the atmosphere and subsequent damaging effects, Titles I and IV of the Clean Air Act Amendments of 1990 (CAAAs) require reductions in emissions of sulfur dioxide (SO{sub 2}), nitrogen oxides (NO{sub x}), and volatile organic compounds (VOCs). Title IV is aimed at reducing acidic deposition and requires utilities to reduce SO{sub 2} and NO{sub x} emissions to specified levels. As a consequence of this, many utilities will have to install SO{sub 2} and NO{sub x} control technologies. Title I is concerned with bringing regions into compliance with the National Ambient Air Quality Standards (NAAQS) for the criteria pollutants, among which is ozone (O{sub 3}). The NAAQS for O{sub 3} is 120 ppb (parts per billion by volume) hourly average concentration, not to be exceeded four times in three years. O{sub 3} is a secondary pollutant formed in the atmosphere when NO{sub x} and VOCs react together in the presence of sunlight. Utilities are a significant source of NO{sub x} and an unimportant source of VOCs. In the past, O{sub 3} control strategy has focused on reducing VOC emissions because of the possibility that reducing NO{sub x} actually might make O{sub 3} concentrations higher. However, this approach has not worked, perhaps because of underestimation of natural and manmade VOC emissions and transport of O{sub 3} from other regions. Computer modeling has shown that for many highly polluted areas massive NO{sub x} reductions may be necessary in addition to or in place of VOC controls. Utilities are a potential source of these NO{sub x} reductions.

Fernau, M.E.; Guziel, K.A.; South, D.W.

1993-05-01T23:59:59.000Z

494

Air pollution and childhood respiratory health: Exposure to sulfate and ozone in 10 Canadian Rural Communities  

SciTech Connect (OSTI)

This study was designed to examine differences in the respiratory health status of preadolescent school children, aged 7-11 years, who resided in 10 rural Canadian communities in areas of moderate and low exposure to regional sulfate and ozone pollution. Five of the communities were located in central Saskatchewan, a low-exposure region, and five were located in southwestern Ontario, an area with moderately elevated exposures resulting from long-range atmospheric transport of polluted air masses. In this cross-sectional study, the child's respiratory symptoms and illness history were evaluated using a parent-completed questionnaire, administered in September 1985. Respiratory function was assessed once for each child in the schools between October 1985 and March 1986, by the measurement of pulmonary function for forced vital capacity (FVC), forced expiratory volume in 1 sec (FEV[sub 1.0]), peak expiratory flow rate (PEFR), mean forced expiratory flow rate during the middle half of the FVC curve (FEF[sub 25-75]), and maximal expiratory flow at 50% of the expired vital capacity (V[sub 50]max). After controlling for the effects of age, sex, parental smoking, parental education and gas cooking, no significant regional differences were observed in rates of chronic cough or phlegm, persistent wheeze, current asthma, bronchitis in the past year, or any chest illness that kept the child at home for 3 or more consecutive days during the previous year. Children living in southwestern Ontario had statistically significant (P < 0.01) mean decrements of 1.7% in FVC and 1.3% in FEV[sub 1.0] compared with Saskatchewan children, after adjusting for age, sex, weight, standing height, parental smoking, and gas cooking. There were no statistically significant regional differences in the pulmonary flow parameters (P > 0.05). 54 refs., 1 fig., 7 tabs.

Stern, B.R.; Raizenne, M.E.; Burnett, R.T.; Jones, L.; Kearney, J.; Franklin, C.A. (Environmental Health Directorate, Ottawa, Ontario (Canada))

1994-08-01T23:59:59.000Z

495

The pulmonary response of white and black adults to six concentrations of ozone  

SciTech Connect (OSTI)

Many early studies of respiratory responsiveness to ozone (O3) were done on healthy, young, white males. The purpose of this study was to determine whether gender or race differences in O3 response exist among white and black, males and females, and to develop concentration-response curves for each of the gender-race groups. Three hundred seventy-two subjects (n > 90 in each gender-race group), ages 18 to 35 yr, were exposed once for 2.33 h to 0.0 (purified air), 0.12, 0.18, 0.24, 0.30, or 0.40 ppm O3. Each exposure was preceded by baseline pulmonary function tests and a symptom questionnaire. The first 2 h of exposure included alternating 15-min periods of rest and exercise on a motorized treadmill producing a minute ventilation (VE) of 25 L/min/m2 body surface area (BSA). After exposure, subjects completed a set of pulmonary function tests and a symptom questionnaire. Lung function and symptom responses were expressed as percent change from baseline and analyzed using a nonparametric two factor analysis of variance. Three primary variables were analyzed: FEV1, specific airway resistance (SRaw), and cough. Statistical analysis demonstrated no significant differences in response to O3 among the individual gender-race groups. For the group as a whole, changes in the variables FEV1, SRaw, and cough were first noted at 0.12, 0.18, and 0.18 ppm O3, respectively. Adjusted for exercise difference, concentration-response curves for FEV1 and cough among white males were consistent with previous reports (1).

Seal, E. Jr.; McDonnell, W.F.; House, D.E.; Salaam, S.A.; Dewitt, P.J.; Butler, S.O.; Green, J.; Raggio, L. (Environmental Protection Agency, Chapel Hill, NC (United States))

1993-04-01T23:59:59.000Z

496

Hydrocarbon Observations and Ozone Production Rates in Western Houston During the Texas 2000 Air Quality Study  

SciTech Connect (OSTI)

Measurements of total non-methane hydrocarbon in whole air canisters collected from the top of a skyscraper on the western edge of Houston, Texas are summarized with an emphasis on samples collected during the passage of plumes of O{sub 3} and the associated rapid increase in the mixing ratio of this species. The back-trajectories associated with these events showed a pronounced deceleration of air parcels over central and western Houston and were not necessarily associated with direct passage over the petrochemical plants located in the heavily industrialized eastern part of Houston. As a result of the time these air parcels spent over the central and western parts of Houston, their VOC mix and associated chemical production rates were expected to differ from similar observations made over eastern Houston from aircraft sampling at low altitudes. Although periods of high O{sub 3} in the western part of the city were closely associated with light alkenes, these same observations show isoprene to make a significant contribution to the total VOC reactivity in the early afternoon (the start of peak photochemical activity) in contrast to observations made east of our sampling site that found the reactivity to be dominated by anthropogenic species. By initializing a 0-dimensional chemical kinetic model with observations made at the Williams Tower, we find that the ozone production efficiency scaled linearly to the ratio of total hydrocarbons and NO{sub x}, with an average OPE of 7.2, ranging from 2.3 to 16.9; these values are smaller than those reported in eastern Houston, suggesting a strong gradient in photochemical productivity across the city.

Berkowitz, Carl M.; Spicer, Chet W.; Doskey, Paul V.

2005-06-01T23:59:59.000Z

497

Performance of the MFTF magnet cryogenic power leads  

SciTech Connect (OSTI)

The cryogenic power lead system for the MFTF superconducting magnets has been acceptance tested and operated with the magnets. This system, which includes 5-m-long superconducting buses, 1.5-m-long vapor-cooled transition leads, external warm buses, and a cryostack, can conduct up to 6000 A (dc) and operate adiabatically for long periods. We present both design details and performance data; our MFTF version is an example of a reliable lead system for large superconducting magnets contained in a much larger vacuum vessel.

VanSant, J.H.

1983-11-30T23:59:59.000Z

498

Surface dust wipes are the best predictors of blood leads in young children with elevated blood lead levels  

SciTech Connect (OSTI)

Background: As part of the only national survey of lead in Australian children, which was undertaken in 1996, lead isotopic and lead concentration measurements were obtained from children from 24 dwellings whose blood lead levels were ?15 µg/dL in an attempt to determine the source(s) of their elevated blood lead. Comparisons were made with data for six children with lower blood lead levels (<10 µg/dL). Methods: Thermal ionisation and isotope dilution mass spectrometry were used to determine high precision lead isotopic ratios ({sup 208}Pb/{sup 206}Pb, {sup 207}Pb/{sup 206}Pb and {sup 206}Pb/{sup 204}Pb) and lead concentrations in blood, dust from floor wipes, soil, drinking water and paint (where available). Evaluation of associations between blood and the environmental samples was based on the analysis of individual cases, and Pearson correlations and multiple regression analyses based on the whole dataset. Results and discussion: The correlations showed an association for isotopic ratios in blood and wipes (r=0.52, 95% CI 0.19–0.74), blood and soil (r=0.33, 95% CI ?0.05–0.62), and blood and paint (r=0.56, 95% CI 0.09–0.83). The regression analyses indicated that the only statistically significant relationship for blood isotopic ratios was with dust wipes (B=0.65, 95% CI 0.35–0.95); there were no significant associations for lead concentrations in blood and environmental samples. There is a strong isotopic correlation of soils and house dust (r=0.53, 95% CI 0.20–0.75) indicative of a common source(s) for lead in soil and house dust. In contrast, as with the regression analyses, no such association is present for bulk lead concentrations (r=?0.003, 95% CI ?0.37–0.36), the most common approach employed in source investigations. In evaluation of the isotopic results on a case by case basis, the strongest associations were for dust wipes and blood. -- Highlights: • Children with elevated blood lead ?15 µg/dL compared with a group with <10 µg/dL. • High precision lead isotopic ratios in blood, house dust wipes, soil, water, paint. • Associations for isotopic measures of blood and dust, blood and soil, blood and paint. • Regressions gave significance for isotopic measures of blood/dust and dust/soil.

Gulson, Brian, E-mail: brian.gulson@mq.edu.au [Graduate School of the Environment, Macquarie University, North Ryde NSW 2109 (Australia) [Graduate School of the Environment, Macquarie University, North Ryde NSW 2109 (Australia); CSIRO Earth Science and Resource Engineering, North Ryde NSW 2113 (Australia); Anderson, Phil [Information and Statistics Group, Australian Institute of Health and Welfare, Canberra ACT 2601 (Australia) [Information and Statistics Group, Australian Institute of Health and Welfare, Canberra ACT 2601 (Australia); Faculty of Health, University of Canberra, Canberra ACT 2601 (Australia); Taylor, Alan [Department of Psychology, Macquarie University, Sydney NSW 2109 (Australia)] [Department of Psychology, Macquarie University, Sydney NSW 2109 (Australia)

2013-10-15T23:59:59.000Z

499

Determinants of elevated blood lead during pregnancy in a population surrounding a lead smelter in Kosovo, Yugoslavia  

SciTech Connect (OSTI)

The authors are prospectively examining the relation between environmental lead exposure and pregnancy outcome in cohorts of women exposed to a wide range of air lead concentrations. Titova Mitrovica, Yugoslavia, is the site of a large lead smelter, refinery, and battery factory. At midpregnancy, 602 women in T. Mitrovica and 900 women in Pristina, a non-lead-exposed control town, were interviewed. Blood was obtained for blood lead (PbB), hemoglobin erythrocyte protoporphyrin, and serum ferritin measurements. Women were seen again at delivery, at which time maternal and umbilical cord blood samples were obtained. While many demographic and social characteristics were similar across the two towns, women in Pristina were more likely to report employment outside the home, cigarette smoking, and alcohol use during pregnancy. As expected, PbB levels were substantially higher in the smelter town. Within T. Mitrovica, distance between the home and the smelter was the most important predictor of PbB at mid-pregnancy and delivery. Husband's employment in the lead industry was associated with a significant increase in maternal PbB levels independent of place of residence. Overall, the placenta was a poor barrier to lead; the relationship between maternal PbB and umbilical cord PbB was linear across a wide range of PbB levels.

Graziano, J.H.; Factor-Litvak, P.; Murphy, M.J.; Zhao, Yuhua; Lolacono, N.J. (Columbia Univ., New York, NY (USA)); Popovac, D.; Ahmedi, X.; Zvicer, Z.; Nenezic, D.U. (Univ of Pristina Medical School (Yugoslavia)); Shrout, P.; Kline, J.; Stein, Z. (Columbia Univ., New York, NY (USA) New York State Psychiatric Institute, New York (USA)); Mehmeti, A.; Rajovic, B. (Medicinski Centar, Titova Mitrovica (Yugoslavia))

1990-11-01T23:59:59.000Z

500

Robert C. Seamans, Jr. Appointed to Lead Nuclear Weapons Program...  

National Nuclear Security Administration (NNSA)

Photo Gallery Jobs Apply for Our Jobs Our Jobs Working at NNSA Blog Home About Us Our History NNSA Timeline Robert C. Seamans, Jr. Appointed to Lead ... Robert C. Seamans,...