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1

Advanced Diesel Combustion with Low Hydrocarbon and Carbon Monoxide...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Combustion with Low Hydrocarbon and Carbon Monoxide Emissions Advanced Diesel Combustion with Low Hydrocarbon and Carbon Monoxide Emissions Poster presented at the 16th Directions...

2

Advanced Diesel Combustion with Low Hydrocarbon and Carbon Monoxide...  

Broader source: Energy.gov (indexed) [DOE]

Combustion with Low Hydrocarbon and Carbon Monoxide Emissions Poster Location P-19 Gregory K. Lilik, Andr L. Boehman Department of Energy & Mineral Engineering EMS Energy...

3

Carbon Monoxide, Ozone, Hydrocarbon Air Quality Standards, and Related  

Broader source: Energy.gov (indexed) [DOE]

Monoxide, Ozone, Hydrocarbon Air Quality Standards, and Monoxide, Ozone, Hydrocarbon Air Quality Standards, and Related Emission Requirements (Ohio) Carbon Monoxide, Ozone, Hydrocarbon Air Quality Standards, and Related Emission Requirements (Ohio) < Back Eligibility Agricultural Commercial Construction Fuel Distributor Industrial Institutional Investor-Owned Utility Local Government Municipal/Public Utility Rural Electric Cooperative State/Provincial Govt Transportation Tribal Government Utility Savings Category Buying & Making Electricity Program Info State Ohio Program Type Environmental Regulations Provider Ohio Environmental Protection Agency This chapter defining the roles of the Ohio Environmental Protection Agency gives specific detail on the regulation point-source air pollution for a variety of industries and pollutants.

4

Oxidation of carbon monoxide and hydrocarbons on platinum and palladium catalysts in the presence of sulfur dioxide  

SciTech Connect (OSTI)

The authors report on a study of the effect of sulfur dioxide on the activity of platinum and palladium catalysts with respect to oxidation of the principal toxic components in the exhaust gases of internal combustion engines: carbon monoxide and hydrocarbons (propylene (C/sub 3/H/sub 6/) and propane (C/sub 3/H/sub 8/)). The experiments were carried out in a flow system equipped with Beckman infrared analyzers to monitor the concentrations of CO and hydrocarbons and of sulfur dioxide. A series of thermal desorption experiments was carried out in a low-pressure flow system with mass spectrometric analysis of the gas phase. The results indicate that the low-temperature adsorption of sulfur dioxide on platinum (and also palladium) catalysts inhibits the oxidation of carbon monoxide and propylene. The poisoning effect of O/sub 2/ is due to blockage of the platinum centers for adsorption of the oxidizable compounds and oxygen.

Panchishnyi, V.I.; Bondareva, N.K.; Sklyarov, A.V.; Rozanov, V.V.; Chadina, G.P.

1988-11-10T23:59:59.000Z

5

Catalysts for the production of hydrocarbons from carbon monoxide and water  

DOE Patents [OSTI]

A method of converting low H.sub.2 /CO ratio syngas to carbonaceous products comprising reacting the syngas with water or steam at 200.degree. to 350.degree. C. in the presence of a metal catalyst supported on zinc oxide. Hydrocarbons are produced with a catalyst selected from cobalt, nickel or ruthenium and alcohols are produced with a catalyst selected from palladium, platinium, ruthenium or copper on the zinc oxide support. The ratio of the reactants are such that for alcohols and saturated hydrocarbons: (2n+1).gtoreq.x.gtoreq.O and for olefinic hydrocarbons: 2n.gtoreq.x.gtoreq.O where n is the number of carbon atoms in the product and x is the molar amount of water in the reaction mixture.

Sapienza, Richard S. (Shoreham, NY); Slegeir, William A. (Hampton Bays, NY); Goldberg, Robert I. (Selden, NY)

1987-01-01T23:59:59.000Z

6

Catalysts for the production of hydrocarbons from carbon monoxide and water  

DOE Patents [OSTI]

A method of converting low H/sub 2//CO ratio syngas to carbonaceous products comprising reacting the syngas with water or steam at 200 to 350/sup 0/C in the presence of a metal catalyst supported on zinc oxide. Hydrocarbons are produced with a catalyst selected from cobalt, nickel or ruthenium and alcohols are produced with a catalyst selected from palladium, platinum, ruthenium or copper on the zinc oxide support. The ratio of the reactants are such that for alcohols and saturated hydrocarbons: (2n + 1) greater than or equal to x greater than or equal to O and for olefinic hydrocarbons: 2n greater than or equal to x greater than or equal to O where n is the number of carbon atoms in the product and x is the molar amount of water in the reaction mixture.

Sapienza, R.S.; Slegeir, W.A.; Goldberg, R.I.

1985-11-06T23:59:59.000Z

7

Increased combustion rate of chlorobenzene on Pt/?-Al2O3 in binary mixtures with hydrocarbons and with carbon monoxide  

Science Journals Connector (OSTI)

The catalytic combustion of chlorobenzene on a 2 wt.% Pt/?-Al2O3 catalyst in binary mixtures with various hydrocarbons (toluene, benzene, cyclohexane, cyclohexene, 1,4-cyclohexadiene, 2-butene, and ethene) and with carbon monoxide has been explored. For all binary mixtures used the (excess of) added hydrocarbon increased the rate of conversion of chlorobenzene. With 2-butene, T50% and T100% for chlorobenzene were reduced by 100 and 200°C, respectively. Toluene and ethene were almost equally efficient as 2-butene. Co-feeding benzene or carbon monoxide resulted in a much smaller decrease of the T50%. The additional heat and water production in hydrocarbon combustion may contribute to some extent to the observed rate acceleration, but removal of Cl from the surface due to the hydrocarbon appears to be the major factor. The co-feeding of hydrocarbons invariably reduced the output of polychlorinated benzenes, which are formed as byproducts in the combustion of chlorobenzene on Pt/?-Al2O3. Again, especially toluene, ethene, and 2-butene were very efficient. Benzene — as well as cyclohexane, cyclohexene, and 1,4-cyclohexadiene, which were converted in situ into benzene — was much less effective, due to chlorination of the aromatic nucleus. In chlorobenzene–CO mixtures the levels of polychlorinated benzenes were almost as high as with chlorobenzene per se. Removal of Cl from the surface (mainly in the form of HCl) by (non-aromatic) hydrocarbons is responsible for reducing the formation of byproducts.

R.W. van den Brink; R. Louw; P. Mulder

2000-01-01T23:59:59.000Z

8

Effect of the type of carrier on the properties of cobalt catalysts in the synthesis of aliphatic hydrocarbons from carbon monoxide and hydrogen  

SciTech Connect (OSTI)

The properties of catalysts used in the synthesis of hydrocarbons from CO and H/sub 2/ are determined to a significant degree by the carriers used in their preparation. This paper deals with a study of the effect of the type of carrier on the properties of cobalt-based catalysts in the synthesis of aliphatic hydrocarbons from CO and H/sub 2/. Co catalysts that are active in the synthesis of hydrocarbons from CO and H/sub 2/ are those on which the adsorption of H/sub 2/ exceeds 3.10/sup -2/ mmole/g Co and the adsorptin of carbon monoxide exceeds 7.10/sup -2/ mmole/g Co. Carbon monoxide and hydrogen are adsorbed on active catalysts in weakly bound forms. A mechanism is proposed for the formatin of an active center and the adsorption of carbon monoxide on Co-catalysts which includes the appearance of a partial positive charge on the cobalt atom.

Lapidus, A.L.; Jem, H.C.; Krylova, A.Y.

1983-04-10T23:59:59.000Z

9

Hydrocarbons from carbon monoxide hydrogen-steam mixtures, unusual product distributions and mechanistic implications  

SciTech Connect (OSTI)

Over recent years, considerable interest has developed in hydrocarbon synthesis via direct processing of H/sub 2/-lean synthesis gases which are produced by the ''second generation'' of thermally efficient coal gasifiers. To directly process gases with a H/sub 2//CO ratio less than 0.5, requires that water be mixed with the reactor feed gas so that additional H/sub 2/ is generated in-situ via the water-gas-shift (WGS) reaction. This obviously requires the use of catalysts which are active for both the synthesis and WGS reactions. The fact that most Group VIII metals are active for both reactions is well demonstrated by the development of the Kolbel-Engelhardt (KE) synthesis in which all the H/sub 2/ is formed in-situ. The authors previously examined the effect of H/sub 2//CO/H/sub 2/2O feed ratios on CO conversion rates (4); the present report concerns its effect upon hydrocarbon product distributions. In the experiments described, as the H/sub 2//CO ratio was reduced from 2.0 (Typical Fischer-Tropsch (FT) conditions), sufficient H/sub 2/O was added to compensate for the H/sub 2/ deficiency based on the assumption that all added H/sub 2/O was converted to H/sub 2/ via the WGS reaction.

Chaffee, A.L.; Ekstrom; Lapszewica, J.; Loeh, H.

1986-03-01T23:59:59.000Z

10

Bacteria Odors  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Bacteria Odors Bacteria Odors Name: Jason Location: N/A Country: N/A Date: N/A Question: I am doing a science project on food decomposition. I would like to know why food -- especially meat--smells bad when it goes bad. Also Why does bread grow mold and why is it green and blue? Thank you. Replies: Jason, When food is being eaten by bacteria, they produce byproducts just like we do. The compounds they produce cause the smell of rotten meat. There is a reason we don't like that smell: it warns us that that food is probably unsafe to eat. So biology has built in a safety rule: you would not normally eat something that you don't like the smell of. The molds on bread are a special kind that like bread. Their spores are everywhere but only when we leave our bread long enough can they grow to sufficient numbers so that we can see them. Again, you can smell the bread is off, you can see it, and if you hadn't noticed you will taste it. However you should not eat bread with molds on: they produce toxic substances. I don't think there is a reason for them to be green and blue, at least I don't know it.

11

The structure of adsorbed sulfur and carbon on molybdenum and rhenium single crystal surfaces, and their influence on carbon monoxide and hydrocarbon chemisorption  

SciTech Connect (OSTI)

An ultra-high vacuum (10/sup -10/ Torr) study was performed on the chemisorption and structures of S and C adsorbates on Mo(100), Re(0001), and Re(1010) single crystal surfaces. Both S and C adsorb strongly on Mo(100), Re(0001), and Re(1010), with adsorption energies >70 kcal/mol for coverages less than saturation. S was proposed to adsorb in the highest symmetry sites on all surfaces except for theta/sub s/ > 0.75 on Mo(100), where studies suggest two different adsorption sites. C adsorbs in a ''carbidic'' or active phase on Mo(100), where it is also proposed to adsorb in the highest symmetry sites. However, C adsorbs in a ''graphitic'' or inactive phase on Re(0001) and Re(1010). CO chemisorption on the S and C overlayers was found to be blocked (except for C on Mo(100)), with S blocking adsorption more efficiently than C. Changes in adsorption energy were determined to be caused by local crowding of CO molecules by S or C, rather than a long-range electronic interaction. Unsaturated hydrocarbons decomposed completely on Mo(100), Re(0001), and Re(1010). Similar to the results for CO chemisorption, strong adsorption of unsaturated hydrocarbons (leading to decomposition) was blocked by pre-adsorbed S, allowing only physisorption to occur (adsorption energies < 11 kcal/mol). The effect of pre-adsorbed ''graphitic'' C on Re(0001) and Re(1010) on unsaturated hydrocarbon chemisorption was the same; strong adsorption (leading to decomposition) was blocked allowing only physisorption. However, Mo(100) with pre-adsorbed ''carbidic'' carbon blocks only decomposition while allowing strong reversible molecular chemisorption (12 to 23 kcal/mol). Differences in inhibition efficiency of S and C are proposed to be caused by differences in bond distances of the adsorbates to the surface. Greater distance from the metal surface causes more interaction with neighboring metal atoms. These differences also suggest explanations for catalytic hydrodesulfurization of thiophene.

Kelly, D.G.

1987-08-01T23:59:59.000Z

12

Carbon Monoxide Safety Tips  

E-Print Network [OSTI]

Protect yourself and your family from the deadly effects of carbon monoxide--a colorless, odorless poisonous gas. This publication describes the warning signs of carbon monoxide exposure and includes a home safety checklist....

Shaw, Bryan W.; Garcia, Monica L.

1999-07-26T23:59:59.000Z

13

Carbon monoxide absorbing liquid  

SciTech Connect (OSTI)

The present disclosure is directed to a carbon monoxide absorbing liquid containing a cuprous ion, hydrochloric acid and titanum trichloride. Titanium trichloride is effective in increasing the carbon monoxide absorption quantity. Furthermore, titanium trichloride remarkably increases the oxygen resistance. Therefore, this absorbing liquid can be used continuously and for a long time.

Arikawa, Y.; Horigome, S.; Kanehori, K.; Katsumoto, M.

1981-07-07T23:59:59.000Z

14

Livestock Odor Reduction Demonstration Project  

E-Print Network [OSTI]

Livestock Odor Reduction Demonstration Project Objectives The 1996 and 1997 Iowa General Assembly-share basis to livestock producers and operators selected to carry out various demonstration projects. Organization The Livestock Odor Reduction Demonstration Project was administered by ISU Extension. Stewart

Lin, Zhiqun

15

Reformer-pressure swing adsorption process for the production of carbon monoxide  

SciTech Connect (OSTI)

An improved process for the production of carbon monoxide by the steam reforming of hydrocarbons is described comprising: (a) catalytically reacting a fluid hydrocarbon feed stream with steam in a steam reformer; (b) passing the reformer effluent containing hydrogen, carbon monoxide and carbon dioxide from the steam reformer, without scrubbing to remove the carbon dioxide content thereof, to a pressure swing adsorption system having at least four adsorbent beds, each bed of which, on a cyclic basis, undergoes a processing sequence; (c) recycling the carbon dioxide-rich stream to the steam reformer for reaction with additional quantities of the hydrocarbon feed stream being passed to the stream reformer to form additional quantities of carbon monoxide and hydrogen, with product recovery being enhanced and the need for employing a carbon dioxide wash system being obviated.

Fuderer, A.

1988-02-23T23:59:59.000Z

16

Characterization and analysis of diesel exhaust odor  

Science Journals Connector (OSTI)

Characterization and analysis of diesel exhaust odor ... Carbonyl and Nitrogen Dioxide Emissions From Gasoline- and Diesel-Powered Motor Vehicles ...

Patricia A. Partridge; Francis J. Shala; Nicholas P. Cernansky; Irwin H. Suffet

1987-04-01T23:59:59.000Z

17

SENSITIVE OPTOACOUSTIC DETECTION OF CARBON MONOXIDE BY RESONANCE ABSORPTION  

E-Print Network [OSTI]

Monoxide by Resonance Absorption Robert Gerlach and Nabil M.MONOXIDE BY RESONANCE ABSORPTION Robert Gerlach and Nabil M.the context of atmospheric absorption. The carbon monoxide

Gerlach, R.

2011-01-01T23:59:59.000Z

18

Odor Landscapes in Turbulent Environments  

Science Journals Connector (OSTI)

The olfactory system of male moths is exquisitely sensitive to pheromones emitted by females and transported in the environment by atmospheric turbulence. Moths respond to minute amounts of pheromones, and their behavior is sensitive to the fine-scale structure of turbulent plumes where pheromone concentration is detectible. The signal of pheromone whiffs is qualitatively known to be intermittent, yet quantitative characterization of its statistical properties is lacking. This challenging fluid dynamics problem is also relevant for entomology, neurobiology, and the technological design of olfactory stimulators aimed at reproducing physiological odor signals in well-controlled laboratory conditions. Here, we develop a Lagrangian approach to the transport of pheromones by turbulent flows and exploit it to predict the statistics of odor detection during olfactory searches. The theory yields explicit probability distributions for the intensity and the duration of pheromone detections, as well as their spacing in time. Predictions are favorably tested by using numerical simulations, laboratory experiments, and field data for the atmospheric surface layer. The resulting signal of odor detections lends itself to implementation with state-of-the-art technologies and quantifies the amount and the type of information that male moths can exploit during olfactory searches.

Antonio Celani; Emmanuel Villermaux; Massimo Vergassola

2014-10-28T23:59:59.000Z

19

Advanced Diesel Combustion with Low Hydrocarbon and Carbon Monoxide Emissions  

Broader source: Energy.gov [DOE]

Poster presented at the 16th Directions in Engine-Efficiency and Emissions Research (DEER) Conference in Detroit, MI, September 27-30, 2010.

20

ILENR/RE-AQ-ON-ROAD CARBON MONOXIDE AND HYDROCARBON  

E-Print Network [OSTI]

. McVey, and Stuart P. Beaton Prepared for: Illinois Department of Energy and Natural Resources Office A. Witter Director State of Illinois Illinois Department of Energy and Natural Resources #12;NOTE This report has been reviewed by the Illinois Department of Energy and Natural Resources (ENR) and approved

Denver, University of

Note: This page contains sample records for the topic "monoxide hydrocarbons odors" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

OXIDATION OF DRY HYDROCARBONS AT HIGH-POWER DENSITY ANODES  

SciTech Connect (OSTI)

This work builds upon discoveries by the University of Pennsylvania and others pertaining to the oxidation of dry hydrocarbon fuels in high temperature solid oxide fuel cells. The work reported here was restricted primarily to dry methane and confirms that YSZ-based cells, having ceria in the anode as a catalyst and copper in the anode as a current collector, can operate on dry methane for extended periods. Thirty-three lab-scale cells of various designs were fabricated and operated under a variety of conditions. The longest-lived cell gave stable performance on dry methane at 800 C for over 305 hours. Only slight carbon deposition was noted at the completion of the test. A corresponding nickel/YSZ-based anode would have lasted for less than an hour under these test conditions (which included open circuit potential measurements) before carbon fouling essentially destroyed the cell. The best performing cell achieved 112 mW/cm{sub 2} on dry methane at 800 C. Several problems were encountered with carbon fouling and declining open circuit voltages in many of the test cells after switching from operation on hydrogen to dry methane. Although not rigorously confirmed by experimentation, the results suggested that air infiltration through less than perfect perimeter seals or pinholes in the electrolytes, or both gave rise to conditions that caused the carbon fouling and OCV decline. Small amounts of air reacting with methane in a partial oxidation reaction could produce carbon monoxide that, in turn, would deposit the carbon. If this mechanism is confirmed, it implies that near perfect hardware is required for extended operation. Some evidence was also found for the formation of electrical shorts, probably from carbon deposits bridging the electrolyte. Work with odorized methane and with methane containing 100-ppm hydrogen sulfide confirmed that copper is stable at 800 C in dry hydrocarbon fuels in the presence of sulfur. In a number of cases, but not exclusively, the performance life on dry methane with sulfur compounds was much longer than with dry methane alone. The effect of sulfur compounds in these cases appeared to correlate with inhibition of carbon deposition. Mixed results were obtained for the effect of the sulfur compounds on power density. Progress also was made in understanding the mechanisms involved in direct utilization of dry natural gas. Evidence was developed for three possible mechanisms for dry methane utilization in addition to the usually cited mechanism--direct oxidation of methane by oxygen anions. Further work is required at a fundamental level before the knowledge gained here can be translated into higher levels of performance.

K.Krist; O. Spaldon-Stewart; R. Remick

2004-03-01T23:59:59.000Z

22

Fish odor syndrome: a case report of trimethylaminuria  

E-Print Network [OSTI]

JG, Hansen RC. Fish odor syndrome: trimethylaminuria withLS. Smelling like dead fish: a case of trimethylaminuria in1 January 2014 Letter Fish odor syndrome: a case report of

Ulman, Catherine A; Trevino, Julian J; Miller, Marvin; Gandhi, Rishi K

2014-01-01T23:59:59.000Z

23

Why sequence carbon monoxide oxidizing thermophiles?  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

carbon monoxide oxidizing thermophiles? carbon monoxide oxidizing thermophiles? Many microbes that use carbon monoxide as an energy source are found in high temperature environments such as geothermal areas. Researchers think that these carboxydotrophs may be involved in reducing potentially toxic carbon monoxide hotspots by combine with water to form hydrogen, carbon dioxide and acetate, which are in turn used for thermophilic energy conservation and carbon sequestration mechanisms. The project focuses on sequencing two closely related microbes, one of which is Carboxydothermus hydrogenformans. A strain of C. hydrogenformans has been grown in hydrogen-enriched synthesis gas (syngas), which contains a mix of hydrogen and carbon monoxide. Researchers are interested in sequencing both microbial strains to track the genome's evolution and

24

Population based exposure assessment methodology for carbon monoxide: Development of a Carbon Monoxide Passive Sampler and Occupational Dosimeter  

E-Print Network [OSTI]

Monoxide Poisoning from Propane- Fueled Forklifts." JournalMonoxide Poisoning from Propane- Fueled Fotklifts" Journalto the Indoor Use of Propane-Fueled Forklifts in Colorado

Apte, Michael G.

2010-01-01T23:59:59.000Z

25

Odor discrimination of "IP 3-" and “cAMP-increasing” odorants in the turtle olfactory bulb  

Science Journals Connector (OSTI)

The ability of the turtle olfactory system to discriminate between various odorants...P 3) in the olfactory bulb was examined by the cross-adaptation technique and analyzed by multidimensional sca...

Makoto Kashiwayanagi; Fumiko Nagasawa; Kouhei Inamura; Kenzo Kurihara

1996-03-01T23:59:59.000Z

26

Desorption of carbon monoxide from nickel using mercaptans  

SciTech Connect (OSTI)

An IR spectroscopic study on the displacement of carbon monoxide with 1-propyl, 2-propyl-, 1-butyl-, 2-butyl-, and tert.-butyl mercaptan from nickel foil and silica-supported nickel showed that at low carbon monoxide coverage on supported nickel, mercaptan adsorption initially converted bridged to linear carbon monoxide surface species. At higher mercaptan pressures, carbon monoxide desorbed into the gas phase. A small amount of carbon monoxide remained on the surface when the poisoned sample was evacuated, and additional carbon monoxide adsorbed when 5 mm Hg of carbon monoxide was added to the evacuated sample.

Neff, L.D.; Sturdivant, A.E.; Wallace, J.L.

1980-06-01T23:59:59.000Z

27

Naphthenic hydrocarbons  

SciTech Connect (OSTI)

An important type of naphthenic hydrocarbons is the monocyclic type, (k/sub 2/, 0, 0). In this instance the number of carbon atoms, n = k/sub 2/, and a formula, C/sub n/H/sub 2n/, can be written where H/C = 2. The value n can vary from 2 to infinity. In the case of n = 2, it is ethylene (I) (2-membered cyclic ring); n = 3, cyclopropane (II) (3-membered cyclic ring); n = 4, cyclobutane (III) (4-membered cyclic ring); etc. If the monocyclic naphthenic is planar, then the bond angle theta can be expressed as theta = (1 - 2/n)..pi.. where n is the number of carbon atoms. However, the tetrahedron angle of the carbon atom being phi = cos/sup -1/ (- 1/3).

Yen, T.F.; Kuo, J.F.; Chilingarian, G.V.

1987-01-01T23:59:59.000Z

28

Catalytic reactions on well-characterized vanadium oxide catalysts. 1. Oxidation of carbon monoxide  

SciTech Connect (OSTI)

The oxidation of carbon monoxide over unsupported and supported vanadium oxide catalysts was investigated from the standpoint of structure sensitivity. The activity of unsupported V/sub 2/O/sub 5/ markedly decreased the turnover frequency, while the reduction-oxidation treatment of the fused catalyst increased it. The turnover frequency of V/sub 2/O/sub 5//TiO/sub 2/ with low V/sub 2/O/sub 5/ content was much smaller than that of the V/sub 2/O/sub 5//TiO/sub 2/ with high V/sub 2/O/sub 5/ content or the unsupported V/sub 2/O/sub 5/. Such a retarding effect of the TiO/sub 2/ support on the activity of the oxidation of carbon monoxide is in contrast to the known promoting effect of TiO/sub 2/ for the oxidations of various hydrocarbons. From these results coupled with the characterization of the catalysts, it was concluded that the oxidation of carbon monoxide on vanadium oxide catalysts is a structure-sensitive reaction and that the activity of surface defects such as steps, kinks, and vacancies is much higher than that of the surface V=O species in the smooth (010) face of V/sub 2/O/sub 5/. 39 references, 9 figures, 2 tables.

Mori, K.; Miyamoto, A.; Murakami, Y.

1984-06-21T23:59:59.000Z

29

Managing Nuisance Odor and Dust from Poultry Growing Operations  

E-Print Network [OSTI]

The odor and dust from poultry growing operations can be a nuisance to neighbors. The tips for managing odor and dust contained in this leaflet cover the disposal of dead birds, maintenance of the ventilation system, composting and storing of litter...

Mukhtar, Saqib; Lacey, Ron; Carey, John B.

2001-08-08T23:59:59.000Z

30

Removing Odors from Refrigerators and Freezers after Food has Spoiled  

E-Print Network [OSTI]

ER-005 6-06 Extension Family and Consumer Science Specialists The Texas A&M University System If food has spoiled in a refrigerator or freezer because of a power failure or some other reason, undesirable odors can develop. To eliminate these odors...

FCS Project Team - FDRM UNIT

2005-09-30T23:59:59.000Z

31

Light-weight analyzer for odor recognition  

DOE Patents [OSTI]

The invention provides a light weight analyzer, e.g., detector, capable of locating clandestine graves. The detector utilizes the very specific and unique chemicals identified in the database of human decompositional odor. This detector, based on specific chemical compounds found relevant to human decomposition, is the next step forward in clandestine grave detection and will take the guess-work out of current methods using canines and ground-penetrating radar, which have historically been unreliable. The detector is self contained, portable and built for field use. Both visual and auditory cues are provided to the operator.

Vass, Arpad A; Wise, Marcus B

2014-05-20T23:59:59.000Z

32

Combustion of viscous hydrocarbons  

SciTech Connect (OSTI)

A method is described for utilizing viscous hydrocarbons as combustible fuels comprising: (A) forming a hydrocarbosol using a surfactant package in a proportion of about 1:100 to about 1:20,000 by weight based on hydrocarbon, (1) the surfactant package comprising (a) at least one water-soluble surfactant, an effective amount of which surfactant promotes emulsification of a hydrocarbon with API gravity of about 20/sup 0//sup o/ API or less; and (b) at least one water-soluble bioemulsifier, being a microboally-derived substance which predominantly resides at hydrocarbon/water interfaces to substantially surround hydrocarbon droplets in hydrocarbon-in-water emulsions; (2) the hydrocarbosol (a) comprising a hydrocarbon characterized by an API gravity of about 20/sup 0//sup o/ API or less; (b) having a hydrocarbon:water ratio of about 70:30 by volume; and (B) burning the resultant hydrocarbosol.

Hayes, M.E.; Hrebenar, K.R.; Murphy, P.L.; Futch, L.E. Jr.; Deal, J.F. III

1986-10-21T23:59:59.000Z

33

Carbon Monoxide Concentration Trends in Urban Atmospheres  

Science Journals Connector (OSTI)

...BOVE, J.L., AIRBORNE LEAD AND CARBON MONOXIDE...various procedures that release transmitter has been...conclusion for trans-mitter release. He also provided evidence...suburban counties, a larger fraction of the gasoline is undoubtedly...in the huts (indoor fires are used for space heating...

Merril Eisenbud; Laurel R. Ehrlich

1972-04-14T23:59:59.000Z

34

Envlron. Sci. Technol. 1993, 27, 1885-1891 On-Road Hydrocarbon Remote Sensing in the Denver Area  

E-Print Network [OSTI]

), oxides of nitrogen (NO,), and other toxic air pollutants. These emissions play important roles in all emission control technology. Introduction Automobile emissionsoriginate from fuelrich-burning, misfiring or nonfunctional emission control system can produce high emission rates for carbon monoxide (CO), hydrocarbon (HC

Denver, University of

35

Process for steam reforming of hydrocarbons  

SciTech Connect (OSTI)

A process is provided for the steam reforming of normally liquid hydrocarbons to produce carbon monoxide and hydrogen, which does not promote the deposition of carbonacious materials upon catalytic surfaces. The catalyst consists of nickel promoted with the oxides of iron and manganese within a specific manganese to iron ratio, said metal and metal oxides being supported upon a refractory support. The support is preferably aluminum oxide in its alpha phase having a surface area of more than 0.5 m2/gm but no more than 10 m2/gm. The metallic constituents are impregnated onto said refractory low surface area support as salts and are calcined at sufficiently high temperature to convert the salts to the oxide but at a sufficiently low temperature that they do not chemically react with the support.

Broughton, D.R.; Russ, K.J.

1980-11-11T23:59:59.000Z

36

Odorization system upgrades gas utility`s pipelines  

SciTech Connect (OSTI)

Mountain Fuel Supply Co., a subsidiary of Questar Corp., salt Lake City, is a natural gas holding company with $1.6 billion in assets. From 1929 to 1984, Mountain Fuel Supply Co. owned and operated many natural gas wells, gathering systems, and transmission pipelines to serve its Utah and Wyoming customers. Gas is odorized at convenient points on the transmission lines and at each downstream location where unodorized gas entered the system. Since 40 to 60% of the gas delivered to the company`s customers passes through Coalville Station, it was vital that a reliable, state-of-the-art odorant station be constructed at this site. Construction began during the summer of 1994 and the system came on line Sept. 1, 1994. The station odorized 435 MMcfd with 330 lbs. of odorant during last winter`s peak day, a mild winter. Mountain Fuel is subject to Department of Transportation (DOT) codes which mandate that gas be readily detectable at one fifth the lower explosive limit (LEL), or about 1% gas in air. However, the company strives to maintain a readily detectable odor at 0.25% of gas in air as measured by odormeter tests throughout the distribution system. Experience has shown that maintaining an odorant injection rate of 0.75 lbs/MMcf provides adequate odor levels. A blend of odorant consisting of 50% tertiary butyl mercaptan (TBM) and 50% tetrahydrothiophene (THT) was used for many years by Questar Pipeline. Presently, it is used at all Mountain Fuel stations. This paper reviews the design and operation of this odorization station.

Niebergall, B. [Mountain Fuel Supply, Salt Lake City, UT (United States)

1995-07-01T23:59:59.000Z

37

Enhanced carbon monoxide utilization in methanation process  

DOE Patents [OSTI]

Carbon monoxide - containing gas streams are passed over a catalyst to deposit a surface layer of active surface carbon thereon essentially without the formation of inactive coke. The active carbon is subsequently reacted with steam or hydrogen to form methane. Surprisingly, hydrogen and water vapor present in the feed gas do not adversely affect CO utilization significantly, and such hydrogen actually results in a significant increase in CO utilization.

Elek, Louis F. (Peekskill, NY); Frost, Albert C. (Congers, NY)

1984-01-01T23:59:59.000Z

38

Combustion of viscous hydrocarbons  

SciTech Connect (OSTI)

A method is described for utilizing viscous hydrocarbons as combustible pre-atomized fuels, comprising: (A) forming a hydrocarbon-in-water emulsion using an effective amount of a surfactant package comprising at least one water-soluble surfactant, the hydrocarbon-in-water emulsion (1) comprising a hydrocarbon characterized by API gravity of about 20/sup 0/ API or less, viscosity of about 1000 centipoise or greater at 212/sup 0/F., a paraffin content of about 50% by weight or less and, an aromatic content of about 15% by weight or greater, and (2) having a hydrocarbon water ratio from about 60:40 to about 90:10 by volume; and (B) burning the resultant hydrocarbon-in-water emulsion.

Hayes, M.E.; Hrebenar, K.R.; Murphy, P.L.; Futch, L.E. Jr.; Deal, J.F. III; Bolden, P.L. Jr.

1987-08-04T23:59:59.000Z

39

Catalysts and process for liquid hydrocarbon fuel production  

DOE Patents [OSTI]

The present invention provides a novel process and system in which a mixture of carbon monoxide and hydrogen synthesis gas, or syngas, is converted into hydrocarbon mixtures composed of high quality gasoline components, aromatic compounds, and lower molecular weight gaseous olefins in one reactor or step. The invention utilizes a novel molybdenum-zeolite catalyst in high pressure hydrogen for conversion, as well as a novel rhenium-zeolite catalyst in place of the molybdenum-zeolite catalyst, and provides for use of the novel catalysts in the process and system of the invention.

White, Mark G; Liu, Shetian

2014-12-09T23:59:59.000Z

40

Rats assess degree of relatedness from human odors Erin M. Ables a,b,, Leslie M. Kay a  

E-Print Network [OSTI]

Rats assess degree of relatedness from human odors Erin M. Ables a,b,, Leslie M. Kay a , Jill M objective odor qualities we tested odor similarity using rats in a habituation­discrimination paradigm. Rats compared. Because rats investigate novel odors longer than familiar odors, we were able to determine which

Mateo, Jill M.

Note: This page contains sample records for the topic "monoxide hydrocarbons odors" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Proper Lagoon Management to Reduce Odor and Excessive Sludge Accumulation  

E-Print Network [OSTI]

Proper management techniques to reduce odor and excessive sludge accumulation include maintaining pH and salt levels, pumping regularly, maintaining adequate bacteria levels, and designing for efficiency. Definitions of key words are boxed for easy...

Mukhtar, Saqib

1999-10-19T23:59:59.000Z

42

Isotopic equilibration of carbon monoxide catalyzed by supported ruthenium  

SciTech Connect (OSTI)

Isotopic equilibration of carbon monoxide catalyzed by supported ruthenium was studied with oxygen-18 and carbon-13 labeled carbon monoxide in the presence and absence of hydrogen. The results showed that carbon monoxide was present on commercial alumina-supported ruthenium in a reactive undissociated form at 373/sup 0/K; that it adsorbed as a single carbonyl and in a geminal dicarbonyl form; and that hydrogen inhibited the exchange reaction by competitive adsorption and by stabilizing the carbonyl bond. The results elucidate the carbon monoxide methanation and Fischer-Tropsch reactions on this catalyst.

Bossi, A. (Cent. Ric. Novara); Zanderighi, L.; Carnisio, G.; Garbassi, F.; Giunchi, G.; Petrini, G.

1980-09-01T23:59:59.000Z

43

Hydrocarbon Potential of Deep Water  

Science Journals Connector (OSTI)

...research-article Hydrocarbon Potential of Deep Water H. R. Warman In...the geology and hydrocarbon potential of the Earth's deeper water areas, an attempt...United Kingdom 1981 Hydrocarbon potential of deep water Warman H. R. Author...

1978-01-01T23:59:59.000Z

44

Recovering hydrocarbons from hydrocarbon-containing vapors  

DOE Patents [OSTI]

Values are recovered from a hydrocarbon-containing vapor by contacting the vapor with quench liquid consisting essentially of hydrocarbons to form a condensate and a vapor residue, the condensate and quench fluid forming a combined liquid stream. The combined liquid stream is mixed with a viscosity-lowering liquid to form a mixed liquid having a viscosity lower than the viscosity of the combined liquid stream to permit easy handling of the combined liquid stream. The quench liquid is a cooled portion of the mixed liquid. Viscosity-lowering liquid is separated from a portion of the mixed liquid and cycled to form additional mixed liquid.

Mirza, Zia I. (La Verne, CA); Knell, Everett W. (Los Alamitos, CA); Winter, Bruce L. (Danville, CA)

1980-09-30T23:59:59.000Z

45

CO (Carbon Monoxide Mixing Ratio System) Handbook  

SciTech Connect (OSTI)

The main function of the CO instrument is to provide continuous accurate measurements of carbon monoxide mixing ratio at the ARM SGP Central Facility (CF) 60-meter tower (36.607 °N, 97.489 °W, 314 meters above sea level). The essential feature of the control and data acquisition system is to record signals from a Thermo Electron 48C and periodically calibrate out zero and span drifts in the instrument using the combination of a CO scrubber and two concentrations of span gas (100 and 300 ppb CO in air). The system was deployed on May 25, 2005.

Biraud, S

2011-02-23T23:59:59.000Z

46

E-Print Network 3.0 - ambient carbon monoxide Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

FACT SHEET Carbon monoxide (CO), known as the Invisible Killer... , propane, oil, wood, coal, and gasoline. Exposure to carbon monoxide can cause flu-like symptoms and can... .)...

47

The Catalysis of the Carbon Monoxide-Steam Reaction  

Science Journals Connector (OSTI)

...The Catalysis of the Carbon Monoxide-Steam Reaction F. J. Long K. W. Sykes The kinetics of the carbon monoxide-steam reaction occurring heterogeneously at...nearly unity, while that with respect to steam is correspondingly lowered; a slight...

1952-01-01T23:59:59.000Z

48

Process for producing carbon monoxide and hydrogen from methanol  

SciTech Connect (OSTI)

A process is described for producing carbon monoxide and hydrogen which comprises contacting methanol vapor at a temperature of 200 degrees to 300 degrees C with an indirectly heated zinc containing catalyst to obtain an effluent gas in which the components of carbon monoxide and hydrogen constitute at least 90% by volume of said gas. At least a part of the impurities from said effluent gas are removed and said effluent gas is deparated into its carbon monoxide and hydrogen components by adsorption. The effluent gas can be separated into its carbon monoxide and hydrogen components by use of a plurality of adsorbers containing zeolite-type molecular sieve material where the zeolite is substantially permeable to hydrogen but sorbs carbon monoxide.

Jockel, H.; Marschner, F.; Moller, F.W.; Mortel, H.

1982-02-23T23:59:59.000Z

49

Carbon monoxide exposure of subjects with documented cardiac arrhythmias  

SciTech Connect (OSTI)

The impact of low-level carbon monoxide exposure on ventricular arrhythmia frequency in patients with ischemic heart disease has not been thoroughly studied. The issue is of concern because of the potential proarrhythmic effect of carbon monoxide in patients with ischemic heart disease. We studied 30 subjects with well-documented coronary artery disease who had an average of at least 30 ventricular ectopic beats per hour over a 20-hour monitoring interval. By using appropriate inclusion and exclusion criteria, subjects were selected and enrolled in a randomized double-blind study to determine the effects of carbon monoxide exposure on ventricular arrhythmia frequency at rest, during exercise, and during ambulatory activities. The carbon monoxide exposure was designed to result in 3% or 5% carboxyhemoglobin levels, as measured by gas chromatography. The carbon monoxide exposure protocol produced target levels in 60 minutes, and the levels were maintained for an additional 90 minutes to provide adequate time to assess the impact of carbon monoxide on the frequency of ventricular ectopic beats. The data on total and repetitive ventricular arrhythmias were analyzed for seven specific time intervals: (1) two hours before carbon monoxide exposure; (2) during the two-hour carbon monoxide or air exposure; (3) during a two-hour rest period; (4) during an exercise period; (5) during an exercise recovery period; (6) six hours after carbon monoxide or air exposure; and (7) approximately 10 hours after exposure, or the remaining recording interval on the Holter monitor. There was no increase in ventricular arrhythmia frequency after carbon monoxide exposure, regardless of the level of carboxyhemoglobin or the type of activity.

Chaitman, B.R.; Dahms, T.E.; Byers, S.; Carroll, L.W.; Younis, L.T.; Wiens, R.D. (St. Louis Univ. School of Medicine, MO (United States))

1992-09-01T23:59:59.000Z

50

Plasma Processing Of Hydrocarbon  

SciTech Connect (OSTI)

The Idaho National Laboratory (INL) developed several patented plasma technologies for hydrocarbon processing. The INL patents include nonthermal and thermal plasma technologies for direct natural gas to liquid conversion, upgrading low value heavy oil to synthetic light crude, and to convert refinery bottom heavy streams directly to transportation fuel products. Proof of concepts has been demonstrated with bench scale plasma processes and systems to convert heavy and light hydrocarbons to higher market value products. This paper provides an overview of three selected INL patented plasma technologies for hydrocarbon conversion or upgrade.

Grandy, Jon D; Peter C. Kong; Brent A. Detering; Larry D. Zuck

2007-05-01T23:59:59.000Z

51

Comparison of Three CarbonComparison of Three Carbon Monoxide Databases in ConnecticutMonoxide Databases in Connecticut  

E-Print Network [OSTI]

Comparison of Three CarbonComparison of Three Carbon Monoxide Databases in ConnecticutMonoxide Databases in Connecticut Brian Toal, MSPHBrian Toal, MSPH Patricia Miskell, MPHPatricia Miskell, MPH Connecticut Department of Public HealthConnecticut Department of Public Health Environmental & Occupational

52

Reduction of Carbon Monoxide. Past Research Summary  

DOE R&D Accomplishments [OSTI]

Research programs for the year on the preparation, characterization, and reactions of binuclear tantalum complexes are described. All evidence to date suggest the following of these dimeric molecules: (1) the dimer does not break into monomers under mild conditions; (2) intermolecular hydride exchange is not negligible, but it is slow; (3) intermolecular non-ionic halide exchange is fast; (4) the ends of the dimers can rotate partially with respect to one another. The binuclear tantalum hydride complexes were found to react with carbon monoxide to give a molecule which is the only example of reduction of CO by a transition metal hydride to give a complex containing a CHO ligand. Isonitrides also reacted in a similar manner with dimeric tantalum hydride. (ATT)

Schrock, R. R.

1982-00-00T23:59:59.000Z

53

Nickel and iron EXAFS of carbon monoxide dehydrogenase from Clostridium thermoaceticum strain DSM  

Science Journals Connector (OSTI)

Nickel and iron EXAFS of carbon monoxide dehydrogenase from Clostridium thermoaceticum strain DSM ...

Neil R. Bastian; Gabriele. Diekert; Eric C. Niederhoffer; Boon Keng. Teo; Christopher T. Walsh; William H. Orme-Johnson

1988-08-01T23:59:59.000Z

54

Carbon monoxide sensor and method of use thereof  

DOE Patents [OSTI]

Carbon monoxide sensors suitable for use in hydrogen feed streams and methods of use thereof are disclosed. The sensors are palladium metal/insulator/semiconductor (Pd-MIS) sensors which may possess a gate metal layer having uniform, Type 1, or non-uniform, Type 2, film morphology. Type 1 sensors display an increased sensor response in the presence of carbon monoxide while Type 2 sensors display a decreased response to carbon monoxide. The methods and sensors disclosed herein are particularly suitable for use in proton exchange membrane fuel cells (PEMFCs).

McDaniel; Anthony H. (Livermore, CA), Medlin; J. Will (Boulder, CO), Bastasz; Robert J. (Livermore, CA)

2007-09-04T23:59:59.000Z

55

Carbon Monoxide Poisoning Avoided Through Weatherization | Department of  

Broader source: Energy.gov (indexed) [DOE]

Carbon Monoxide Poisoning Avoided Through Weatherization Carbon Monoxide Poisoning Avoided Through Weatherization Carbon Monoxide Poisoning Avoided Through Weatherization October 5, 2010 - 10:56am Addthis Joshua DeLung What does this mean for me? Getting your heating pipes fixed can not only save you money, but also improve your health. "If we'd had a couple cold nights where I would've had to use my heat more than usual, it probably would've put me to sleep and left me there -- it was just too much carbon monoxide coming out in the house," says Mark Pickartz, of Van Buren, Ark. Pickartz's home was weatherized in February by his local community action agency, Crawford-Sebastian Community Development Council (C-SCDC). When energy auditors arrived to his house, they found that his home's heater was severely leaking the poisonous gas. C-SCDC, based in Fort Smith, Ark.,

56

Carbon Monoxide Toxicity after Lighting Coals at a Hookah Bar  

Science Journals Connector (OSTI)

Unintentional non-fire-related (UNFR) carbon monoxide (CO) poisonings continue to account for a significant health and economic burden in the United States. While most of these poisonings are related to faulty...

Ryan Misek; Christine Patte

2014-09-01T23:59:59.000Z

57

Carbon monoxide-silicon carbide interaction in HTGR fuel particles  

Science Journals Connector (OSTI)

The corrosion of the coating-layers of silicon carbide (SiC) by carbon monoxide (CO) was observed in irradiated Triso-coated uranium dioxide particles, used in high-temperature gas-cooled reactors, by optical ...

Kazuo Minato; Toru Ogawa; Satoru Kashimura; Kousaku Fukuda…

1991-05-01T23:59:59.000Z

58

Dispersant solutions for dispersing hydrocarbons  

DOE Patents [OSTI]

A dispersant solution includes a hydrocarbon dispersing solution derived from a bacterium from ATCC 75527, ATCC 75529, or ATCC 55638.

Tyndall, R.L.

1997-03-11T23:59:59.000Z

59

Low severity hydrocarbon steam reforming process  

SciTech Connect (OSTI)

A process is described for producing ammonia which comprises: (a) primary catalytically reforming at super atmospheric pressure in a direct-fired primary reforming zone, a hydrocarbon feedstock with steam to produce a gas containing carbon oxides, hydrogen and methane; (b) secondary catalytically reforming the gas from step (a) by introducing air and bringing the mixture towards equilibrium thereby producing a secondary reformer effluent gas containing nitrogen, carbon oxides, hydrogen and a decreased quantity of methane; (c) converting carbon monoxide catalytically with steam to carbon dioxide and hydrogen; (d) removing carbon oxides to give an ammonia synthesis gas comprising nitrogen and hydrogen and compressing the gas to ammonia synthesis pressure; (e) reacting the synthesis gas in an ammonia synthesis zone to produce ammonia and recovering ammonia from the reacted gas to produce an ammonia-depleted gas stream; (f) recycling at least a portion of the ammonia-depleted gas stream to the ammonia synthesis zone; and (g) treating a sidestream of the ammonia-depleted gas to separate a stream enriched in hydrogen and an inerts-enriched gas stream, and returning the enriched hydrogen stream to the ammonia synthesis zone.

Osman, R.M.; Byington, R.G.

1986-06-03T23:59:59.000Z

60

Carbon neutral hydrocarbons  

Science Journals Connector (OSTI)

...depends on a source of primary energy to drive the required chemical...synthetic hydrocarbons are an energy carrier produced from a primary energy source such as wind, nuclear...Gustavsson et al. 2007), using a conversion value of $1.00=0.72...

2008-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "monoxide hydrocarbons odors" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Optrode for sensing hydrocarbons  

DOE Patents [OSTI]

A two-phase system employing the Fujiwara reaction is provided for the fluorometric detection of halogenated hydrocarbons. A fiber optic is utilized to illuminate a column of pyridine trapped in a capillary tube coaxially attached at one end to the illuminating end of the fiber optic. A strongly alkaline condition necessary for the reaction is maintained by providing a reservoir of alkali in contact with the column of pyridine, the surface of contact being adjacent to the illuminating end of the fiber optic. A semipermeable membrane caps the other end of the capillary tube, the membrane being preferentially permeable to the halogenated hydrocarbon and but preferentially impermeable to water and pyridine. As the halogenated hydrocarbon diffuses through the membrane and into the column of pyridine, fluorescent reaction products are formed. Light propagated by the fiber optic from a light source, excites the fluorescent products. Light from the fluorescence emission is also collected by the same fiber optic and transmitted to a detector. The intensity of the fluorescence gives a measure of the concentration of the halogenated hydrocarbons.

Miller, Holly (Bethel Island, CA); Milanovich, Fred P. (Lafayette, CA); Hirschfeld, Tomas B. (Livermore, CA); Miller, Fred S. (Bethel Island, CA)

1987-01-01T23:59:59.000Z

62

Optrode for sensing hydrocarbons  

DOE Patents [OSTI]

A two-phase system employing the Fujiwara reaction is provided for the fluorometric detection of halogenated hydrocarbons. A fiber optic is utilized to illuminate a column of pyridine trapped in a capillary tube coaxially attached at one end to the illuminating end of the fiber optic. A strongly alkaline condition necessary for the reaction is maintained by providing a reservoir of alkali in contact with the column of pyridine, the surface of contact being adjacent to the illuminating end of the fiber optic. A semipermeable membrane caps the other end of the capillary tube, the membrane being preferentially permeable to the halogenated hydrocarbon and but preferentially impermeable to water and pyridine. As the halogenated hydrocarbon diffuses through the membrane and into the column of pyridine, fluorescent reaction products are formed. Light propagated by the fiber optic from a light source, excites the fluorescent products. Light from the fluorescence emission is also collected by the same fiber optic and transmitted to a detector. The intensity of the fluorescence gives a measure of the concentration of the halogenated hydrocarbons. 5 figs.

Miller, H.; Milanovich, F.P.; Hirschfeld, T.B.; Miller, F.S.

1988-09-13T23:59:59.000Z

63

Optrode for sensing hydrocarbons  

DOE Patents [OSTI]

A two-phase system employing the Fujiwara reaction is provided for the fluorometric detection of halogenated hydrocarbons. A fiber optic is utilized to illuminate a column of pyridine trapped in a capillary tube coaxially attached at one end to the illuminating end of the fiber optic. A strongly alkaline condition necessary for the reaction is maintained by providing a reservoir of alkali in contact with the column of pyridine, the surface of contact being adjacent to the illuminating end of the fiber optic. A semipermeable membrane caps the other end of the capillary tube, the membrane being preferentially permeable to the halogenated hydrocarbon but preferentially impermeable to water and pyridine. As the halogenated hydrocarbon diffuses through the membrane and into the column of pyridine, fluorescent reaction products are formed. Light propagated by the fiber optic from a light source, excites the fluorescent products. Light from the fluorescence emission is also collected by the same fiber optic and transmitted to a detector. The intensity of the fluorescence gives a measure of the concentration of the halogenated hydrocarbons. 6 figs.

Miller, H.; Milanovich, F.P.; Hirschfeld, T.B.; Miller, F.S.

1987-05-19T23:59:59.000Z

64

Optrode for sensing hydrocarbons  

DOE Patents [OSTI]

A two-phase system employing the Fujiwara reaction is provided for the fluorometric detection of halogenated hydrocarbons. A fiber optic is utilized to illuminate a column of pyridine trapped in a capillary tube coaxially attached at one end to the illuminating end of the fiber optic. A strongly alkaline condition necessary for the reaction is maintained by providing a reservoir of alkali in contact with the column of pyridine, the surface of contact being adjacent to the illuminating end of the fiber optic. A semipermeable membrane caps the other end of the capillary tube, the membrane being preferentially permeable to the halogenated hydrocarbon and but preferentially impermeable to water and pyridine. As the halogenated hydrocarbon diffuses through the membrane and into the column of pyridine, fluorescent reaction products are formed. Light propagated by the fiber optic from a light source, excites the fluorescent products. Light from the fluorescence emission is also collected by the same fiber optic and transmitted to a detector. The intensity of the fluorescence gives a measure of the concentration of the halogenated hydrocarbons.

Miller, Holly (Bethel Island, CA); Milanovich, Fred P. (Lafayette, CA); Hirschfeld, Tomas B. (Livermore, CA); Miller, Fred S. (Bethel Island, CA)

1988-01-01T23:59:59.000Z

65

Determination of the atherogenic potential of inhaled carbon monoxide  

SciTech Connect (OSTI)

he effects of chronic exposure to moderate levels of carbon monoxide upon the augmentation of arteriosclerotic plaque development were investigated in a series of in vivo studies in the cockerel (young rooster). This animal model has been well characterized, especially regarding the role of environmental agents in exacerbating early stages of plaque development. Cockerels injected with subtumorigenic doses of carcinogens exhibit markedly accelerated development of aortic arteriosclerotic plaques. Inhalation of mainstream smoke from two packs of cigarettes (100 minutes/day for 16 weeks) causes small but statistically significant increases in plaque size. As is the case with many animal models of plaque development, raised fat-proliferative plaques also appear in these animals following cholesterol feeding. Carbon monoxide is a ubiquitous pollutant in urban environments, where it is derived largely from mobile sources and cigarette smoke. Exposure to chronically elevated carbon monoxide levels has been implicated in a number of health-related problems. Whether such exposure plays a role in the development of arteriosclerosis has not been determined conclusively. In the present study, three questions were posed: 1. Will inhaled carbon monoxide at levels of 50 to 200 parts per million (ppm)* (two hours/day for 16 weeks) be sufficient to augment arteriosclerotic plaque development in cockerels, in the absence of other plaque-promoting agents 2. Will the inhalation of 100 ppm carbon monoxide (two hours/day for 16 weeks), concomitant with the feeding of low levels (0.1%) of cholesterol, yield larger plaques than those obtained with either of these agents administered alone 3. Will inhalation of 100 ppm carbon monoxide (two hours/day for 11 or 22 weeks), by cockerels in whom plaques have already appeared, further augment plaque development Cockerels were exposed to carefully regulated levels of carbon monoxide in stainless-steel and Plexiglas dynamic exposure chambers.

Penn, A. (New York Univ. Medical Center, NY (United States))

1993-05-01T23:59:59.000Z

66

Taste and Odor Problems in Clinton Lake Reservoir's Drinking Water  

E-Print Network [OSTI]

Taste and Odor Problems in Clinton Lake Reservoir's Drinking Water Diana L. Restrepo-Osorio (McNair Scholar) Department of Ecology and Evolutionary Biology, INTRODUCTION Water is a requirement for human health and welfare; however..., an exceedingly large number of people around the world lack reliable sources of drinking water 1 . According to the World Health Organization, approximately 3.5 million people die every year, generally in developing countries, from diseases linked to poor...

Restrepo-Osorio, Dianna L.

2012-04-01T23:59:59.000Z

67

Location of odor sources and the affected population in Imperial County, California  

SciTech Connect (OSTI)

This report is divided into four sections. The first two sections contain general background information on Imperial County. The third section is a general discussion of odor sources in Imperial County, and the fourth maps the specific odor sources, the expected areas of perception, and the affected populations. this mapping is done for the Imperial Valley and each of the four Imperial County KGRA's (Known Geothermal Resource Areas) where odor from the development of the geothermal energy may affect population.

Hahn, J.L.

1981-08-01T23:59:59.000Z

68

THERMOCHEMISTRY OF HYDROCARBON RADICALS  

SciTech Connect (OSTI)

Gas phase negative ion chemistry methods are employed to determine enthalpies of formation of hydrocarbon radicals that are important in combustion processes and to investigate the dynamics of ion-molecule reactions. Using guided ion beam tandem mass spectrometry, we measure collisional threshold energies of endoergic proton transfer and hydrogen atom transfer reactions of hydrocarbon molecules with negative reagent ions. The measured reaction threshold energies for proton transfer yield the relative gas phase acidities. In an alternative methodology, competitive collision-induced dissociation of proton-bound ion-molecule complexes provides accurate gas phase acidities relative to a reference acid. Combined with the electron affinity of the R {center_dot} radical, the gas phase acidity yields the RH bond dissociation energy of the corresponding neutral molecule, or equivalently the enthalpy of formation of the R{center_dot} organic radical, using equation: D(R-H) = {Delta}{sub acid}H(RH) + EA(R) - IE(H). The threshold energy for hydrogen abstraction from a hydrocarbon molecule yields its hydrogen atom affinity relative to the reagent anion, providing the RH bond dissociation energy directly. Electronic structure calculations are used to evaluate the possibility of potential energy barriers or dynamical constrictions along the reaction path, and as input for RRKM and phase space theory calculations. In newer experiments, we have measured the product velocity distributions to obtain additional information on the energetics and dynamics of the reactions.

Kent M. Ervin, Principal Investigator

2004-08-17T23:59:59.000Z

69

Radical scavengers from heavy hydrocarbons  

SciTech Connect (OSTI)

The hydrogen-donating properties of some hydrocarbons form the basis for processes such as coal liquefaction and heavy oil upgrading. However, these hydrocarbons have seldom been used for other purposes, because their potential applications have not been well recognized. Research has indicated that these hydrogen-donating hydrocarbons can be used in important reactions as radical scavengers and have properties particular to those of pure hydrocarbons without functional groups containing heteroatoms. Over years of study researchers have found that pure hydrocarbons with radical-scavenging effects nearly as high as those in conventional hindered phenolic antioxidants can be produced from petroleum, and these hydrogen-donating hydrocarbons exhibit such effects even in oxidative atmospheres (i.e., they function as antioxidants). He has also shown that these mixtures have some properties particular to pure hydrocarbons without functional groups containing heteroatoms, and they`ve seen that a mechanism based on the steric effects appears when these hydrocarbons are used in heavy oil hydroprocessing. Hydrogen-donating hydrocarbons should be a viable resource in many applications. In this article, he presents radical-scavenging abilities, characteristics as pure hydrocarbons, and applications on the basis of the studies.

Kubo, Junichi [Nippon Oil Co. Ltd. (Japan)

1996-10-01T23:59:59.000Z

70

Kinetic model of catalytic oxidation of carbon monoxide on nickel  

SciTech Connect (OSTI)

A mechanism is proposed for describing the previous disclosed multiplicity of equilibrium states in the oxidation of carbon monoxide on metallic nickel. In contrast to the known mechanism for oxidation of CO on platinum metals it includes a nonlinear stage of carbon monoxide adsorption and a linear stage of oxygen adsorption. A kinetic model has been obtained and stage velocity constants have been found, providing a basis for obtaining a quantitative agreement between the calculated and experimental relations between the reaction velocity and the reagent concentrations. Opinions are stated in relation to the causes for evolution of the CO oxidation reaction from platinum metals to nickel.

Pyatnitskii, Yu.I.; Ostapyuk, V.A.

1986-07-01T23:59:59.000Z

71

Terpolymerization of ethylene, sulfur dioxide and carbon monoxide  

DOE Patents [OSTI]

This invention relates to a high molecular weight terpolymer of ethylene, sulfur dioxide and carbon monoxide stable to 280.degree. C. and containing as little as 36 mol % ethylene and about 41-51 mol % sulfur dioxide; and to the method of producing said terpolymer by irradiation of a liquid and gaseous mixture of ethylene, sulfur dioxide and carbon monoxide by means of Co-60 gamma rays or an electron beam, at a temperature of about 10.degree.-50.degree. C., and at a pressure of about 140 to 680 atmospheres, to initiate polymerization.

Johnson, Richard (Shirley, NY); Steinberg, Meyer (Huntington Station, NY)

1981-01-01T23:59:59.000Z

72

Hydrocarbon synthesis catalyst and method of preparation and use thereof. [DOE patent application  

SciTech Connect (OSTI)

A catalyst for the synthesis of hydrocarbons from carbon monoxide and hydrogen composed of palladium or platinum and cobalt supported on a solid phase is disclosed. The catalyst is prepared by heating a heterogeneous component of the palladium or platinum deposited on the solid support in a solution of cobalt carbonyl or precursors thereof. The catalyst exhibits excellent activity, stability in air, and produces highly desirable product fractions even with dilute gaseous reactants. The catalyst is preferably used in dilute slurry form, which is desirable from a heat transfer standpoint.

Sapienza, R.S.; Sansone, M.J.; Slegeir, W.A.R.

1981-08-14T23:59:59.000Z

73

Photobiogeochemical cycling of carbon monoxide in the southeastern Beaufort Sea in spring and autumn  

E-Print Network [OSTI]

Photobiogeochemical cycling of carbon monoxide in the southeastern Beaufort Sea in spring the distribution, photoproduction, microbial uptake, and air­sea exchange of carbon monoxide (CO), a key that in warmer seas. Carbon monoxide (CO) is the dominant sink for hydroxyl radicals in the troposphere, thus

Vincent, Warwick F.

74

Mechanistical studies on the formation of carbon dioxide in extraterrestrial carbon monoxide ice analog samples  

E-Print Network [OSTI]

be produced via radiolysis of carbon monoxide ices.5 Indeed, the effects of ionizing radiation on pure carbonMechanistical studies on the formation of carbon dioxide in extraterrestrial carbon monoxide ice901220f Binary ice mixtures of two carbon monoxide isotopomers, 13 C16 O and 12 C18 O, were subjected

Kaiser, Ralf I.

75

Water addition for increased CO/H[sub 2] hydrocarbon synthesis activity over catalysts comprising cobalt, ruthenium and mixtures thereof which may include a promoter metal  

SciTech Connect (OSTI)

A once-through, fixed or slurry bed Fischer Tropsch process is described with enhanced CO conversion activity and C[sub 5] + liquid hydrocarbon selectivity comprising contacting a feed mixture of carbon monoxide and hydrogen in a reaction zone with about 1 Vol % to about 70 Vol % water based on the total volume of feed mixture, at a pressure above one atmosphere and a temperature ranging from about 150 C to about 300 C, with a catalyst selected from the group consisting of cobalt, ruthenium, and mixtures thereof on a titania support, wherein said titania support is less than 40 m[sup 2]/g, converting at least 90 Vol % of the carbon monoxide to liquid hydrocarbons, and in the substantial absence of CO[sub 2] formation.

Kim, C.J.

1993-07-13T23:59:59.000Z

76

Titanium dioxide based high temperature carbon monoxide selective sensor  

E-Print Network [OSTI]

Titanium dioxide based high temperature carbon monoxide selective sensor Nancy O. Savagea , Sheikh as a trap for the oxidation products of CO and CH4. Upon oxidation of CO on ALC, carbonate species were detected, whereas the reaction of CH4 produced negligible carbonate species. The insensitivity of the ALC

Dutta, Prabir K.

77

Infrared spectra of carbon monoxide adsorbed on palladium black  

SciTech Connect (OSTI)

The authors investigate the heterogeneous adsorption of carbon monoxide and the concurrent catalytic and sorptive properties of palladium black from the standpoint of a comprehensive analysis of the infrared spectra of the reaction pathways and their various products as well as the pressure dependence of the line behavior at various wavelengths.

Vozdvizhenskii, V.F.; Levintova, T.D.; Sokol'skii, D.V.

1986-06-01T23:59:59.000Z

78

Disproportionation of carbon monoxide on supported nickel catalysts  

SciTech Connect (OSTI)

The disproportionation of carbon monoxide was investigated mainly on a 5.5% Ni/Al/sub 2/O/sub 3/ catalyst by infrared spectroscopy and temperature-programmed desorption. The reaction was found to be of first order with respect to the surface concentration of CO below 200/sup 0/C, while at 450/sup 0/C the reaction proceeded as a second order reaction for the pressure of CO. Results obtained with predeposited carbon indicated that the disproportionation reaction requires an ensemble of several nickel atoms. In agreement with this result, the disproportionation did not take place readily on a 1.1% Ni/Al/sub 2/O/sub 3/ catalyst on which a high dispersion of the metal was indicated by both infrared spectroscopy and the chemisorption of hydrogen. In the temperature-programmed desorption (TPD) carbon monoxide desorbed in a single peak before 300/sup 0/C. Some of the carbon monoxide, however, underwent disproportionation during TPD and a carbon dioxide peak appeared at about 220/sup 0/C. Furthermore, carbon thus deposited on the surface was oxidized to carbon monoxide by oxygen supplied from the catalysts and gave a second peak of CO in TPD at temperatures higher than 300/sup 0/C. Possible sources of the oxygen were discussed.

Galuszka, J.; Chang, J.R.; Amenomiya, Y.

1981-03-01T23:59:59.000Z

79

Detection of iodine monoxide in the tropical free troposphere  

E-Print Network [OSTI]

19, 2012) Atmospheric iodine monoxide (IO) is a radical that catalytically destroys heat trapping in the remote tropical marine boundary layer (MBL) (2­4). IO further affects the oxidative capacity iodine species over the remote ocean remain poorly understood (11, 14) but are currently thought

80

Training rats to search and alert on contraband odors James Ottoa,*  

E-Print Network [OSTI]

Training rats to search and alert on contraband odors James Ottoa,* , Michael F. Brownb , William experiments that were conducted to test a new concept using rats to detect contraband odors, such as explosives, drugs, or prohibited foodstuffs. Under this concept, the trained alerting behavior of rats

Cook, Robert

Note: This page contains sample records for the topic "monoxide hydrocarbons odors" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

The Utilization of Certain Hydrocarbons by Microorganisms  

Science Journals Connector (OSTI)

...UTILIZATION OF CERTAIN HYDROCARBONS BY MICROORGANISMS...1940 INTRODUCTION Hydrocarbons, as a class, represent...obtained by comparing the heat of combustion of some six carbon...biological utilization of hydrocarbons as sources of energy...

L. D. Bushnell; H. F. Haas

1941-05-01T23:59:59.000Z

82

Interaction between Carcinogenic Hydrocarbons and Nucleosides  

Science Journals Connector (OSTI)

...addition, the findings that hydrocarbons inhibit DNA syn thesis...for these carcinogens. Hydrocarbon-nucleic acid interaction...and the interactions of water molecules. Indeed, carcinogenic hydrocarbons tend to form 1 This investigation...

Ronald G. Harvey and Marilyn Halonen

1968-11-01T23:59:59.000Z

83

Effects of Sulfur Dioxide on Formation of Fishy Off-Odor and Undesirable Taste in Wine Consumed with Seafood  

Science Journals Connector (OSTI)

Effects of Sulfur Dioxide on Formation of Fishy Off-Odor and Undesirable Taste in Wine Consumed with Seafood ... These results suggest that sulfur dioxide in wine participated in degradation of unsaturated fatty acids, causing an increase in undesirable taste and fishy off-odor in wine and seafood pairings. ... Wine; seafood; fishy off-odor; undesirable taste; unsaturated fatty acids; sulfur dioxide ...

Akiko Fujita; Atsuko Isogai; Michiko Endo; Hitoshi Utsunomiya; Shigeyoshi Nakano; Hiroshi Iwata

2010-03-10T23:59:59.000Z

84

Enhanced liquid hydrocarbon recovery process  

SciTech Connect (OSTI)

This patent describes a process for recovering liquid hydrocarbons. It comprises: injecting into a fractured subterranean formation a polymer enhanced foam comprising a polymer selected from a synthetic polymer or a biopolymer, a surfactant, an aqueous solvent and a gas, recovering liquid hydrocarbons from the formation.

Sydansk, R.D.

1992-07-14T23:59:59.000Z

85

Hydrocarbon sensors and materials therefor  

DOE Patents [OSTI]

An electrochemical hydrocarbon sensor and materials for use in sensors. A suitable proton conducting electrolyte and catalytic materials have been found for specific application in the detection and measurement of non-methane hydrocarbons. The sensor comprises a proton conducting electrolyte sandwiched between two electrodes. At least one of the electrodes is covered with a hydrocarbon decomposition catalyst. Two different modes of operation for the hydrocarbon sensors can be used: equilibrium versus non-equilibrium measurements and differential catalytic. The sensor has particular application for on-board monitoring of automobile exhaust gases to evaluate the performance of catalytic converters. In addition, the sensor can be utilized in monitoring any process where hydrocarbons are exhausted, for instance, industrial power plants. The sensor is low cost, rugged, sensitive, simple to fabricate, miniature, and does not suffer cross sensitivities.

Pham, Ai Quoc (San Jose, CA); Glass, Robert S. (Livermore, CA)

2000-01-01T23:59:59.000Z

86

Process for recovering hydrocarbons from a hydrocarbon-bearing formation  

SciTech Connect (OSTI)

A method is described for transporting heavy crude oil through a pipeline which involves introducing into a pipeline or well-bore with the viscous hydrocarbons an aqueous solution containing (1) a sulfonate surfactant, (2) a rosin soap or a naphthenic acid soap and, optionally (3) coupling agent whereby there is spontaneously formed a low viscosity, salt tolerant, oil-in-water emulsion. Also disclosed is a method of recovery of hydrocarbons from a hydrocarbon bearing formation employing an aqueous solution containing (1) a sulfonate surfactant, (2) a rosin soap or a naphthenic acid soap and, optionally (3) a coupling agent.

Alston, R.B.; Braden, W.B.; Flournoy, K.H.

1980-03-11T23:59:59.000Z

87

Catalytic activation of carbon monoxide on metal surfaces  

SciTech Connect (OSTI)

In discussing the important basic aspects of carbon monoxide chemistry, this review covers the adsorption and reaction of CO with H/sub 2/O and H/sub 2/ on reduced metal surfaces. Carbon monoxide adsorption of the Group VIII metals exhibits certain patterns. Typically, as coverages exceed one-half, compression occurs in the monolayer and the molecules lose registry with the surface metal atoms. Particular sites associated with rough surfaces facilitate CO dissociation to the surface carbon; these sites may have a significant effect on selectivity in the CO hydrogenation reaction. The support used and the metal crystallite size both affect the catalyst activity and product selectivity. Indications are strong that a better knowledge of metal-support interactions combined with a more complete understanding of the surface chemistry involved will lead to improved catalyst systems in the future.

Vannice, M.A.

1982-01-01T23:59:59.000Z

88

Catalyst for the methanation of carbon monoxide in sour gas  

DOE Patents [OSTI]

The invention involves the synergistic effect of the specific catalytic constituents on a specific series of carriers for the methanation of carbon monoxide in the presence of sulfur at relatively high temperatures and at low steam to gas ratios in the range of 0.2:1 or less. This effect was obtained with catalysts comprising the mixed sulfides and oxides of nickel and chromium supported on carriers comprising magnesium aluminate and magnesium silicate. Conversion of carbon monoxide to methane was in the range of from 40 to 80%. Tests of this combination of metal oxides and sulfides on other carriers and tests of other metal oxides and sulfides on the same carrier produced a much lower level of conversion.

Kustes, William A. (Louisville, KY); Hausberger, Arthur L. (Louisville, KY)

1985-01-01T23:59:59.000Z

89

Carbon and carbon monoxide hydrogenation on nickel: support effects  

SciTech Connect (OSTI)

Hydrogenation of carbon, deposited on nickel catalysts by CO disproportionation, was investigated by temperature-programmed surface reaction (TPSR) for four oxide supports, alumina (Al/sub 2/O/sub 3/), silica (SiO/sub 2/), titanium oxide (TiO/sub 2/), and SiO/sub 2/.Al/sub 2/O/sub 3/. The rate of carbon monoxide hydrogenation was measured by temperature-programmed reaction (TPR) for comparison. The rate of carbon hydrogenation to methane was found to be independent of the support and an average activation energy of 42 kJ/mol was estimated. In contrast, the rate of carbon monoxide hydrogenation was very sensitive to the catalyst support. Nickel (Ni) supported on TiO/sub 2/ exhibited the highest specific activity, and two distinct sites for methanation were observed on Ni/TiO/sub 2/ and Ni/Al/sub 2/O/sub 3/. The lowest specific activities were observed for Ni/SiO/sub 2/ and Ni/SiO/sub 2/.Al/sub 2/O/sub 3/. For all catalysts, carbon hydrogenation occurred at a lower temperature than carbon monoxide hydrogenation. For both TPR and TPSR, small amounts of ethane were formed and at a lower temperature than methane. The amount of less-active, ..beta..-carbon observed in TPSR experiments was very small on all catalysts. These results indicate that at high coverages, carbon hydrogenation does not depend on the support, and thus it is not rate-determining for CO hydrogenation in excess hydrogen. The support is also shown to change the specific rate of carbon monoxide methanation; activity differences seen in steady-state experiments are not just due to differences in site densities. 5 figures, 5 tables.

Ozdogan, S.Z.; Gochis, P.D.; Falconer, J.L.

1983-10-01T23:59:59.000Z

90

Sensors and Actuators B 106 (2005) 122127 Eulerian-Lagrangian model for predicting odor dispersion using  

E-Print Network [OSTI]

mills. This paper de- scribes a paradigm for predicting the trajectory of odorous emissions from a CAFO: sss@acpub.duke.edu (S.S. Schiffman). long-distance dispersal of seeds by wind [1]. It is based

Katul, Gabriel

91

INFRARED ABSORPTION SPECTROSCOPY OF CARBON MONOXIDE ON NICKEL FILMS: A LOW TEMPERATURE THERMAL DETECTION TECHNIQUE  

E-Print Network [OSTI]

A. B. Optical System Absorption Signal C. Small SignalNoise . Sensitivity of Absorption Spectroscopy EXPERIMENTSINFRARED ABSORPTION SPECTROSCOPY OF CARBON MONOXIDE ON

Bailey, Robert Brian

2011-01-01T23:59:59.000Z

92

E-Print Network 3.0 - acute carbon monoxide Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

28, 2007 Summary: OSHAReproToxin AcutelyHazardousWaste Carbon monoxide CalOSHAReproToxin Carbon Tetrachloride IARC-2BNTP Carbonic... toxins, biotoxins and acutely toxic...

93

A new technology for producing synthetic liquid hydrocarbons from gaseous hydrocarbons  

Science Journals Connector (OSTI)

Conventional technologies of synthetic liquid fuels (SLF) production from gaseous hydrocarbons by producing synthesis ... liquid hydrocarbons are examined. A high-efficiency SLF production technology that allows ...

D. L. Astanovskii; L. Z. Astanovskii; A. L. Lapidus

2012-09-01T23:59:59.000Z

94

Enrichment of light hydrocarbon mixture  

DOE Patents [OSTI]

Light hydrocarbon enrichment is accomplished using a vertically oriented distillation column having a plurality of vertically oriented, nonselective micro/mesoporous hollow fibers. Vapor having, for example, both propylene and propane is sent upward through the distillation column in between the hollow fibers. Vapor exits neat the top of the column and is condensed to form a liquid phase that is directed back downward through the lumen of the hollow fibers. As vapor continues to ascend and liquid continues to countercurrently descend, the liquid at the bottom of the column becomes enriched in a higher boiling point, light hydrocarbon (propane, for example) and the vapor at the top becomes enriched in a lower boiling point light hydrocarbon (propylene, for example). The hollow fiber becomes wetted with liquid during the process.

Yang, Dali (Los Alamos, NM); Devlin, David (Santa Fe, NM); Barbero, Robert S. (Santa Cruz, NM); Carrera, Martin E. (Naperville, IL); Colling, Craig W. (Warrenville, IL)

2011-11-29T23:59:59.000Z

95

Conversion of Mixed Oxygenates Generated from Synthesis Gas to Fuel Range Hydrocarbon  

SciTech Connect (OSTI)

The growing dependence in the U.S. on foreign crude oil supplies and increased concerns regarding greenhouse gas emission has generated considerable interest in research to develop renewable and environmentally friendly liquid hydrocarbon transportation fuels. One of the strategies for achieving this is to produce intermediate compounds such as alcohols and other simple oxygenates from biomass generated synthesis gas (mixture of carbon monoxide and hydrogen) and further convert them into liquid hydrocarbons. The focus of this research is to investigate the effects of mixed oxygenates intermediate product compositions on the conversion step to produce hydrocarbon liquids. A typical mixed oxygenate stream is expected to contain water (around 50%), alcohols, such as methanol and ethanol (around 35%), and smaller quantities of oxygenates such as acetaldehyde, acetic acid and ethyl acetate. However the ratio and the composition of the mixed oxygenate stream generated from synthesis gas vary significantly depending on the catalyst used and the process conditions. Zeolite catalyzed deoxygenation of methanol accompanied by chain growth is well understood under Methanol-to-Gasoline (MTG) like reaction conditions using an H-ZSM-5 zeolite as the catalyst6-8. Research has also been conducted to a limited extent in the past with higher alcohols, but not with other oxygenates present9-11. Also there has been little experimental investigation into mixtures containing substantial amounts of water. The latter is of particular interest because water separation from the hydrocarbon product would be less energy intensive than first removing it from the oxygenate intermediate stream prior to hydrocarbon synthesis, potentially reducing overall processing costs.

Ramasamy, Karthikeyan K.; Gerber, Mark A.; Lilga, Michael A.; Flake, Matthew D.

2012-08-19T23:59:59.000Z

96

Correlation between speciated hydrocarbon emissions and flame ionization detector response for gasoline/alcohol blends .  

SciTech Connect (OSTI)

The U.S. renewable fuel standard has made it a requirement to increase the production of ethanol and advanced biofuels to 36 billion by 2022. Ethanol will be capped at 15 billion, which leaves 21 billion to come from other sources such as butanol. Butanol has a higher energy density and lower affinity for water than ethanol. Moreover, alcohol fueled engines in general have been shown to positively affect engine-out emissions of oxides of nitrogen and carbon monoxide compared with their gasoline fueled counterparts. In light of these developments, the variety and blend levels of oxygenated constituents is likely to increase in the foreseeable future. The effect on engine-out emissions for total hydrocarbons is less clear due to the relative insensitivity of the flame ionization detector (FID) toward alcohols and aldehydes. It is well documented that hydrocarbon (HC) measurement using a conventional FID in the presence of oxygenates in the engine exhaust stream can lead to a misinterpretation of HC emissions trends for alcohol fuel blends. Characterization of the exhaust stream for all expected hydrocarbon constituents is required to accurately determine the actual concentration of unburned fuel components in the exhaust. In addition to a conventional exhaust emissions bench, this characterization requires supplementary instrumentation capable of hydrocarbon speciation and response factor independent quantification. Although required for certification testing, this sort of instrumentation is not yet widely available in engine development facilities. Therefore, an attempt is made to empirically determine FID correction factors for oxygenate fuels. Exhaust emissions of an engine fueled with several blends of gasoline and ethanol, n-butanol and iso-Butanol were characterized using both a conventional FID and a Fourier transform infrared. Based on these results, a response factor predicting the actual hydrocarbon emissions based solely on FID results as a function of alcohol type and content is presented. Finally, the correlation derived from data presented in this study is compared with equations and results found in the literature.

Wallner, T. (Energy Systems)

2011-08-01T23:59:59.000Z

97

Biological enhancement of hydrocarbon extraction  

DOE Patents [OSTI]

A method of microbial enhanced oil recovery for recovering oil from an oil-bearing rock formation is provided. The methodology uses a consortium of bacteria including a mixture of surfactant producing bacteria and non-surfactant enzyme producing bacteria which may release hydrocarbons from bitumen containing sands. The described bioprocess can work with existing petroleum recovery protocols. The consortium microorganisms are also useful for treatment of above oil sands, ground waste tailings, subsurface oil recovery, and similar materials to enhance remediation and/or recovery of additional hydrocarbons from the materials.

Brigmon, Robin L. (North Augusta, SC); Berry, Christopher J. (Aiken, SC)

2009-01-06T23:59:59.000Z

98

Carbon Monoxide Oxidation by Bacteria Associated with the Roots of Freshwater Macrophytes  

Science Journals Connector (OSTI)

...consumption and production of atmospheric carbon monoxide by...the consumption of atmospheric carbon monoxide by...rapid oxidation of atmospheric CO to CO2 by soils...D. Influence of water table on carbon dioxide...rice fields and biogas generators: CH4, N2O, CO...

Jeremy J. Rich; G. M. King

1998-12-01T23:59:59.000Z

99

Removal of carbon monoxide. Physical adsorption on natural and synthetic zeolites  

SciTech Connect (OSTI)

The utilization of natural zeolite materials in the elimination of polluting gases is investigated. Carbon monoxide pollution is emphasized because its concentration may reach dangerous levels in places such as vehicle tunnels, underground parking lots, etc. The elimination of carbon monoxide is also of interest in some industrial processes relating to the production of pure gases.

Alfani, F.; Greco, G. Jr.; Iroio, G.

1982-07-01T23:59:59.000Z

100

Submitted to the Annals of Applied Statistics INTERPOLATING FIELDS OF CARBON MONOXIDE  

E-Print Network [OSTI]

and transport. CO AMS 2000 subject classifications: Carbon monoxide; satellite data; Bayesian hierarchi- cal models; interpolation; data assimilation 1 imsart-aoas ver. 2007/04/13 file: COpaper.tex date: March 24Submitted to the Annals of Applied Statistics INTERPOLATING FIELDS OF CARBON MONOXIDE DATA USING

Nychka, Douglas

Note: This page contains sample records for the topic "monoxide hydrocarbons odors" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Carbon monoxide-assisted growth of carbon nanotubes Y.H. Tang a,b  

E-Print Network [OSTI]

Carbon monoxide-assisted growth of carbon nanotubes Y.H. Tang a,b , Y.F. Zheng a , C.S. Lee a , N was used to synthesize carbon nanotubes (CNTs) in a hot-®lament chemical vapor deposition (HFCVD) system in the formation of multi-walled carbon nanotubes (MWNT)s. The CNTs synthesized from carbon monoxide validate

Zheng, Yufeng

102

Fluorescence Detection of Hydrocarbons in Harbour Water  

Science Journals Connector (OSTI)

In harbor water, the hydrocarbons pollution identification represents an important issue. Hydrocarbon presence derives from oil spills, for instance in bilge water, or it may come from industrial discharge ... Fl...

A. Catini; F. Dini; D. Polese; S. Petrocco; M. De Luca…

2011-01-01T23:59:59.000Z

103

Indoor air pollutants from unvented kerosene heater emissions in mobile homes: studies on particles, semivolatile organics, carbon monoxide, and mutagenicity  

Science Journals Connector (OSTI)

Indoor air pollutants from unvented kerosene heater emissions in mobile homes: studies on particles, semivolatile organics, carbon monoxide, and mutagenicity ...

Judy L. Mumford; Ron W. Williams; Debra B. Walsh; Robert M. Burton; David J. Svendsgaard; Jane C. Chuang; Virginia S. Houk; Joellen Lewtas

1991-10-01T23:59:59.000Z

104

Estimating The Thermodynamics And Kinetics Of Chlorinated Hydrocarbon...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Estimating The Thermodynamics And Kinetics Of Chlorinated Hydrocarbon Degradation. Estimating The Thermodynamics And Kinetics Of Chlorinated Hydrocarbon Degradation. Abstract: Many...

105

Extracting hydrocarbons from water using a centrifuge  

Science Journals Connector (OSTI)

An original method for the solid-phase microextraction of hydrocarbons from water using a centrifuge is proposed. Comparative results...

A. Yu. Ryabov; A. A. Ilyina; A. V. Chuikin…

2014-09-01T23:59:59.000Z

106

Photo-oxides of Carcinogenic Hydrocarbons  

Science Journals Connector (OSTI)

... are involved in the biological action of carcinogenic hydrocarbons, we have attempted to isolate the photo-oxides of some of these hydrocarbons. Such ... -oxides of some of these hydrocarbons. Such photo-oxides would naturally be insoluble in water and hence would represent merely one stage in ...

J. W. COOK; R. MARTIN; E. M. F. ROE

1939-06-17T23:59:59.000Z

107

Catalytic steam reforming of hydrocarbons  

SciTech Connect (OSTI)

The hot effluent from the catalytic steam reforming of a major portion of a fluid hydrocarbon feed stream in the reformer tubes of a primary reformer, or said effluent after secondary reforming thereof, is mixed with the hot effluent from the catalytic steam reforming of the remaining portion of the feed discharged from the reformer tubes of a primary reformer-exchanger. The combined gas steam is passed on the shell side of the reformer-exchanger countercurrently to the passage of feed in the reformer tubes thereof, thus supplying the heat for the reforming of the portion of the feed passed through the reformer tubes of the reformerexchanger. At least about 2/3 of the hydrocarbon feed stream is passed to the reformer tubes of said primary reformer, heated by radiant heat transfer and/or by contact with combustion gases, at a steam/hydrocarbon mole ratio of about 2-4/1. The remainder of said feed stream is passed to the reformer tubes of said reformer -exchanger at a steam/hydrocarbon mole ratio of about 3-6/1. The reformer shell of the reformer-exchanger is internally insulated by a refractory lining or by use of a double shell with passage of water or a portion of the feed material between the inner and outer shells. There is no significant difference between the pressure inside and outside of the reformer tubes of said primary reformer-exchanger.

Fuderer, A.

1982-06-29T23:59:59.000Z

108

Syngas Upgrading to Hydrocarbon Fuels Technology Pathway  

Broader source: Energy.gov [DOE]

This technology pathway case investigates the upgrading of woody biomass derived synthesis gas (syngas) to hydrocarbon biofuels. While this specific discussion focuses on the conversion of syngas via a methanol intermediate to hydrocarbon blendstocks, there are a number of alternative conversion routes for production of hydrocarbons through a wide array of intermediates from syngas. Future work will also consider the variations to this pathway to determine the most economically viable and lowest risk conversion route. Technical barriers and key research needs have been identified that should be pursued for the syngas-to-hydrocarbon pathway to be competitive with petroleum-derived gasoline-, diesel- and jet-range hydrocarbon blendstocks.

109

Some observations on the kinetics of the hydrogenation of carbon monoxide  

SciTech Connect (OSTI)

For the hydrogenation of CO a positive order of hydrogen and a slightly negative or a zero order in carbon monoxide are generally reported. The negative (or zero) order in carbon monoxide is often explained by assuming a strong adsorption of carbon monoxide on the same sites as used by the hydrogen. It is then assumed that the surface is ''almost totally'' covered by carbon monoxide. From experiments in which the surface products on an unsupported cobalt catalyst after the reaction were stripped off by a hydrogen treatment it was concluded that more than 95% of the surface (as determined from the adsorption of carbon monoxide at room temperature) was covered by carbon-containing species. This paper illustrates that ''zero order in carbon monoxide'' can be obtained with much lower coverage of carbon-containing species in equilibrium with gas-phase carbon monoxide than indicated above. Equations for reaction rates are presented, and data is calculated on the fraction of the catalyst surface covered by active carbon-containing species when the reaction is zero order in CO. The results suggest that only a small fraction of the catalyst surface is actively engaged in the hydrogenation of CO. This further suggests that the low turnover frequencies found for the Fischer-Tropsch synthesis could be caused by a small number of sites which are active in the rate-determining step. (MWF)

Rautavuoma, A.O.I.; van der Baan, H.S.

1981-10-01T23:59:59.000Z

110

Interaction of carbon monoxide with supported platinum catalysts  

SciTech Connect (OSTI)

The interaction of carbon monoxide with Pt/..gamma..-Al/sub 2/O/sub 3/ containing 0.5-5% Pt by weight has been investigated by means of thermal desorption and IR spectroscopy. It has been shown that CO is adsorbed in three different forms, corresponding to the desorption temperature intervals 25-250/sup 0/C (I), and 250-700/sup 0/C (II), and 550-850/sup 0/C (III). In the adsorption of CO in the first two forms, the metal takes part (absorption band at 2080 cm/sup -1/), and also the support (1800, 1260, 1390, 1470, 1550, and 1640 cm/sup -1/). The adsorption in form III probably takes place on oxidized platinum centers with the formation of strong surface carbonate structures. High temperatures tend to increase the adsorption of CO in forms II and III.

Savel'eva, G.A.; Galeev, T.K.; Popova, N.M.; Vozdvizhenskii, V.F.; Mishchenko, V.M.

1982-04-01T23:59:59.000Z

111

Reduction of carbon monoxide emissions with regenerative thermal oxidizers  

SciTech Connect (OSTI)

Regenerative thermal oxidizers (RTOs) have been extensively used for the control of volatile organic compound (VOC) emissions from various sources. However, very little information is available on the ability of RTOs to control carbon monoxide (CO) emissions. This paper presents the results of extensive tests conducted on two RTOs to determine their VOC and CO control efficiencies. The inlet gas stream to the RTOs includes VOC and CO concentrations as high as 2,000 ppm and 3,600 ppm, respectfully. The testing demonstrated that both RTOs were capable of controlling greater than 98% of both inlet VOCs and CO. While the destruction efficiencies within the combustion chambers exceeded 99.9%, direct leakage past valves accounted for the lower control efficiencies. The tests indicated that the overall VOC and CO control efficiencies of the RTOs may be limited by valve leakage. The design and permitting of a RTO should include conservative control estimates which account for possible valve leakage.

Firmin, S.M.; Lipke, S.; Baturay, A.

1996-09-01T23:59:59.000Z

112

Catalyst for steam reforming of hydrocarbons and process of preparing the catalyst  

SciTech Connect (OSTI)

A catalyst is provided for the steam reforming of normally liquid hydrocarbons to produce carbon monoxide and hydrogen, which does not promote the deposition of carbonaceous materials upon the catalytic surfaces. The catalyst consists of nickel promoted with the oxides of iron and manganese within a specific manganese to iron ratio, said metal and metal oxides being supported upon a refractory support. The support is preferably aluminum oxide in its alpha phase having a surface area of less than 15 m2/gm. The metallic constituents are impregnated onto said refractory low surface area support as salts and are calcined at sufficiently high temperature to convert the salts to the oxide but at a sufficiently low temperature that they do not chemically react with the support.

Broughton, D.R.; Russ, K.J.

1980-06-10T23:59:59.000Z

113

Hydrogen production in ultrarich combustion of hydrocarbon fuels in porous media  

Science Journals Connector (OSTI)

Rich and ultrarich combustion of methane, ethane, and propane inside inert porous media is studied experimentally and numerically to examine the suitability of the concept for hydrogen production. Temperature, velocities, and chemical products of the combustion waves were recorded experimentally at a range of equivalence ratios from stoichiometry (? = 1.0) to ? = 2.5, for a filtration velocity of 12 cm/s. Two-temperature numerical model based on comprehensive heat transfer and chemical mechanisms is found to be in a good qualitative agreement with experimental data. Partial oxidation products of methane, ethane, and propane (H2, CO, and C2 hydrocarbons) are dominant for ultrarich superadiabatic combustion. The maximum hydrogen yield is close to 50% for all fuels, and carbon monoxide yield is close to 80%.

Mario Toledo; Valeri Bubnovich; Alexei Saveliev; Lawrence Kennedy

2009-01-01T23:59:59.000Z

114

Hydrocarbon Technologies | Open Energy Information  

Open Energy Info (EERE)

Hydrocarbon Technologies Hydrocarbon Technologies Place Lawrenceville, New Jersey Zip 8648 Sector Efficiency Product String representation "Technology-base ... onmental risks." is too long. Coordinates 36.761678°, -77.845048° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":36.761678,"lon":-77.845048,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

115

Enhanced liquid hydrocarbon recovery process  

SciTech Connect (OSTI)

This patent describes a process for the recovery of liquid hydrocarbons from a subterranean hydrocarbon-bearing formation. It comprises injecting natural gas into the formation via a well in fluid communication with the formation, the natural gas being at a temperature which is insufficient to significantly mobilize light density oil in the formation and at a pressure such that the natural gas is immiscible with the light density oil in the formation, the natural gas being injected in a volume sufficient to contact light density oil in the formation within a radius from the well of about 50 meters; shutting in the well for a period of time of about 1 to about 100 days which is sufficient to render the contacted light density oil mobile; and producing the light density oil which has been mobilized by solution of the natural gas from the well.

Haines, H.K.; Monger, T.G.; Kenyon, D.E.; Galvin, L.J.

1991-06-25T23:59:59.000Z

116

Dry reforming of hydrocarbon feedstocks  

SciTech Connect (OSTI)

Developments in catalyst technology for the dry reforming of hydrocarbon feedstocks are reviewed for methane, higher hydrocarbons and alcohols. Thermodynamics, mechanisms and the kinetics of dry reforming are also reviewed. The literature on Ni catalysts, bi-metallic Ni catalysts and the role of promoters on Ni catalysts is critically evaluated. The use of noble and transitional metal catalysts for dry reforming is discussed. The application of solid oxide and metal carbide catalysts to dry reforming is also evaluated. Finally, various mechanisms for catalyst deactivation are assessed. This review also examines the various process related issues associated with dry reforming such as its application and heat optimization. Novel approaches such as supercritical dry reforming and microwave assisted dry reforming are briefly expanded upon.

Shah, Yatish T. [Norfolk State University; Gardner, Todd H. [U.S. DOE

2014-01-01T23:59:59.000Z

117

Chapter 3 - Hydrocarbons from Petroleum  

Science Journals Connector (OSTI)

Publisher Summary Petroleum products (in contrast to petrochemicals) are those hydrocarbon fractions that are derived from petroleum and have commercial value as a bulk product. A major group of hydrocarbon products from petroleum (petrochemicals) are the basis of a major industry. They are, in the strictest sense, different to petroleum products insofar as the petrochemicals are the basic building blocks of the chemical industry. The specific gravity of product gases, including liquefied petroleum gas, may be determined conveniently by a number of methods and a variety of instruments. The heat value of gases is generally determined at constant pressure in a flow calorimeter in which the heat released by the combustion of a definite quantity of gas is absorbed by a measured quantity of water or air. A continuous recording calorimeter is available for measuring heat values of natural gases.

James G. Speight

2011-01-01T23:59:59.000Z

118

Discharge produces hydrocarbons from coal  

Science Journals Connector (OSTI)

Discharge produces hydrocarbons from coal ... Studies of the reactions of coal in electric discharges by two chemists at the U.S. Bureau of Mines' Pittsburgh Coal Research Center may lead to improved ways of producing acetylene and other useful chemicals from coal. ... Other workers have produced high yields of acetylene from coal by extremely rapid pyrolysis using energy sources such as plasma jets, laser beams, arc-image reactors, and flash heaters. ...

1968-01-22T23:59:59.000Z

119

Deep desulfurization of hydrocarbon fuels  

DOE Patents [OSTI]

The invention relates to processes for reducing the sulfur content in hydrocarbon fuels such as gasoline, diesel fuel and jet fuel. The invention provides a method and materials for producing ultra low sulfur content transportation fuels for motor vehicles as well as for applications such as fuel cells. The materials and method of the invention may be used at ambient or elevated temperatures and at ambient or elevated pressures without the need for hydrogen.

Song, Chunshan (State College, PA); Ma, Xiaoliang (State College, PA); Sprague, Michael J. (Calgary, CA); Subramani, Velu (State College, PA)

2012-04-17T23:59:59.000Z

120

Method of removing nitrogen monoxide from a nitrogen monoxide-containing gas using a water-soluble iron ion-dithiocarbamate, xanthate or thioxanthate  

DOE Patents [OSTI]

A method of removing nitrogen monoxide from a nitrogen monoxide-containing gas, which method comprises: (a) contacting a nitrogen oxide-containing gas with an aqueous solution of water soluble organic compound-iron ion chelate of the formula: ##STR1## wherein the water-soluble organic compound is selected from compounds of the formula: ##STR2## wherein: R is selected from hydrogen or an organic moiety having at least one polar functional group; Z is selected from oxygen, sulfur, or --N--A wherein N is nitrogen and A is hydrogen or lower alkyl having from one to four carbon atoms; and M is selected from hydrogen, sodium or potassium; and n is 1 or 2, in a contacting zone for a time and at a temperature effective to reduce the nitrogen monoxide. These mixtures are useful to provide an unexpensive method of removing NO from gases, thus reducing atmospheric pollution from flue gases.

Liu, David K. (San Pablo, CA); Chang, Shih-Ger (El Cerrito, CA)

1989-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "monoxide hydrocarbons odors" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Role of Microorganisms in the Consumption and Production of Atmospheric Carbon Monoxide by Soil  

Science Journals Connector (OSTI)

...Winzer. 1932. Uber die Bildung von Essigsaure bei der biologischen Umsetzung von Kohlenoxyd und Kohlensaure mit Wasserstoff zu Methan. Biochem. Z. 245:2-12. 14. Fuchs, G., U. Schnitker, and R. K. Thauer. 1974. Carbon monoxide...

Ralf Conrad; Wolfgang Seiler

1980-09-01T23:59:59.000Z

122

Production of carbon monoxide-free hydrogen and helium from a high-purity source  

DOE Patents [OSTI]

The invention provides vacuum swing adsorption processes that produce an essentially carbon monoxide-free hydrogen or helium gas stream from, respectively, a high-purity (e.g., pipeline grade) hydrogen or helium gas stream using one or two adsorber beds. By using physical adsorbents with high heats of nitrogen adsorption, intermediate heats of carbon monoxide adsorption, and low heats of hydrogen and helium adsorption, and by using vacuum purging and high feed stream pressures (e.g., pressures of as high as around 1,000 bar), pipeline grade hydrogen or helium can purified to produce essentially carbon monoxide -free hydrogen and helium, or carbon monoxide, nitrogen, and methane-free hydrogen and helium.

Golden, Timothy Christopher (Allentown, PA); Farris, Thomas Stephen (Bethlehem, PA)

2008-11-18T23:59:59.000Z

123

Quantum cascade laser-based carbon monoxide detection on a second time scale from human breath  

Science Journals Connector (OSTI)

We present three different detection schemes for measuring carbon monoxide (CO) in direct absorption using a thermoelectrically cooled, distributed-feedback pulsed quantum cascade (qc) laser operating between 217...

B.W.M. Moeskops; H. Naus; S.M. Cristescu; F.J.M. Harren

2006-03-01T23:59:59.000Z

124

Volatile liquid hydrocarbon characterization of underwater hydrocarbon vents and formation waters from offshore production operations  

Science Journals Connector (OSTI)

Volatile liquid hydrocarbon characterization of underwater hydrocarbon vents and formation waters from offshore production operations ... The environmental implications of offshore oil and gas activities ... The environmental implications of offshore oil and gas activities ...

Theodor C. Sauer

1981-08-01T23:59:59.000Z

125

Continuous Measurement of Carbon Monoxide Improves Combustion Efficiency of CO Boilers  

E-Print Network [OSTI]

CONTINUOUS MEASUREMENT OF CARBON MONOXIDE IMPROVES COMBUSTION EFFICIENCY OF CO BOILERS Russell L. Branham ana James J. Prichard Ashland Oil Company Catlettsburg, KY ABSTRACT The paper describes the application of in-situ flue gas CO... measurement in the operation of CO Boilers and details the steps needed to optimize combustion efficiency. INTRODUCTION In the petroleum industry, the efficient operation of a fluid-cata1ytic-cracking unit, produces gases rich in carbon monoxide...

Gilmour, W. A.; Pregler, D. N.; Branham, R. L.; Prichard, J. J.

1981-01-01T23:59:59.000Z

126

Influence of the electrode material on carbon monoxide adsorption and electroreduction in aqueous solutions  

SciTech Connect (OSTI)

Carbon monoxide electroreduction was studied at rotating disk electrodes made of different materials (Cu, Au, Zn, Cd; amalgamated Cu; Al, Ga, In, glassy carbon, Sn, Pb, Mo, Fe, Ni, and certain binary systems). Positive partial currents which are evidence for a direct electroreduction of CO have been observed only at Zn, Ga, and Cd. The observation that CO is less susceptible to electroreduction than carbon dioxide is explained by the stronger chemisorption of carbon monoxide on the electrodes.

Osetrova, N.V.; Vasil'ev, Yu.B.

1987-12-01T23:59:59.000Z

127

HYDROCARBON AND SULFUR SENSORS FOR SOFC SYSTEMS  

SciTech Connect (OSTI)

The following report summarizes work conducted during the Phase I program Hydrocarbon and Sulfur Sensors for SOFC Systems under contract No. DE-FC26-02NT41576. For the SOFC application, sensors are required to monitor hydrocarbons and sulfur in order to increase the operation life of SOFC components. This report discusses the development of two such sensors, one based on thick film approach for sulfur monitoring and the second galvanic based for hydrocarbon monitoring.

A.M. Azad; Chris Holt; Todd Lesousky; Scott Swartz

2003-11-01T23:59:59.000Z

128

Hydrocarbon Separations in Metal–Organic Frameworks  

Science Journals Connector (OSTI)

Given the large differences in the physical properties of methane and C2 hydrocarbons, both size selective effects and metal–hydrocarbon interactions can be tuned to achieve a high selectivity within a metal–organic framework. ... Polycyclic aromatic hydrocarbons, or PAHs, are carcinogenic byproducts of incomplete combustion of organic matter such as fossil fuels. ... data and the heats of adsorption were found to fit well to a small group of mol. ...

Zoey R. Herm; Eric D. Bloch; Jeffrey R. Long

2013-11-22T23:59:59.000Z

129

An investigation of the use of odorants in liquefied natural gas used as a vehicle fuel  

SciTech Connect (OSTI)

Interest in liquefied natural gas (LNG) as an alternative vehicle fuel has increased significantly. Its greater storage density relative to compressed natural gas makes it an attractive option for both volume and weight constrained vehicle applications. The public transportation market, specifically transit bus properties, have been very aggressive in pursuing LNG as an alternative vehicle fuel. Naturally, when dealing with the general public and a new transportation fuel, the issue of safety must be addressed. With this in mind, the Gas Research Institute has initiated a number of safety related studies including an investigation of the use of odorants in LNG. This paper presents the preliminary results of an investigation performed by the Institute of Gas Technology to determine both the applicability and effectiveness of odorizing LNG. This includes an overview of the current state-of-the-art in LNG vehicle fueling and safety systems as well as a discussion of an LNG odorization program conducted by San Diego Gas & Electric in the mid 70`s. Finally, the paper discusses the results of the modeling effort to determine whether conventional odorants used in natural gas can be injected and remain soluble in LNG at temperatures and pressures encountered in LNG fueling and on-board storage systems.

Green, T.; Williams, T. [Gas Research Institute, Chicago, IL (United States)

1994-12-31T23:59:59.000Z

130

Plant Odor Analysis of Potato: Response of Guatemalan Moth to Above- and Belowground Potato Volatiles  

Science Journals Connector (OSTI)

Plant Odor Analysis of Potato: Response of Guatemalan Moth to Above- and Belowground Potato Volatiles ... Potatoes were planted in fertilized and limed peat soil (NPK 180:90:195 g/m3; Hydro Agri AB, Landskrona, Sweden) in 5-L plastic pots. ...

Miriam Frida Karlsson; Göran Birgersson; Alba Marina Cotes Prado; Felipe Bosa; Marie Bengtsson; Peter Witzgall

2009-06-04T23:59:59.000Z

131

ACCEPTED BY WATER ENVIRONMENT RESEARCH ODOR AND VOC REMOVAL FROM WASTEWATER TREATMENT PLANT  

E-Print Network [OSTI]

of their high rates of chemical consumption. Additionally, chemical scrubbers are ineffective for the removalACCEPTED BY WATER ENVIRONMENT RESEARCH _______ ODOR AND VOC REMOVAL FROM WASTEWATER TREATMENT PLANT of biofilters for sequential removal of H2S and VOCs from wastewater treatment plant waste air. The biofilter

132

Detecting odorous compounds emitted from building and consumer products within the European Project SysPAQ  

E-Print Network [OSTI]

Detecting odorous compounds emitted from building and consumer products within the European Project.horn@bam.de Keywords: Olfactory detection port, VOC analysis, Thermal extraction, Building material, Consumer products Introduction In 2006 the European research project Innovative Sensor System for Measuring Perceived Air Quality

Paris-Sud XI, Université de

133

Crucial role of copper in detection of metal-coordinating odorants  

Science Journals Connector (OSTI)

...and then at 2.9 kHz. For odorant-induced...filtered at 2.9 kHz and sampled...1 H NMR (300 MHz) 2.06 (s, 3H...1 H NMR (300 MHz) 1.86 (t, J...distilled off first at atmospheric pressure and...inductively coupled argon plasma-mass spectroscopy...

Xufang Duan; Eric Block; Zhen Li; Timothy Connelly; Jian Zhang; Zhimin Huang; Xubo Su; Yi Pan; Lifang Wu; Qiuyi Chi; Siji Thomas; Shaozhong Zhang; Minghong Ma; Hiroaki Matsunami; Guo-Qiang Chen; Hanyi Zhuang

2012-01-01T23:59:59.000Z

134

Membrane separation of hydrocarbons using cycloparaffinic solvents  

DOE Patents [OSTI]

Heavy crude oils which contain metal contaminants such as nickel, vanadium and iron may be separated from light hydrocarbon oils by passing a solution of the crude oil dissolved in a cycloparaffinic hydrocarbon solvent containing from about 5 to about 8 carbon atoms by passing through a polymeric membrane which is capable of maintaining its integrity in the presence of hydrocarbon compounds. The light hydrocarbon oils which possess relatively low molecular weights will be recovered as the permeate while the heavy oils which possess relatively high molecular weights as well as the metal contaminants will be recovered as the retentate.

Kulkarni, S.S.; Chang, Y.A.; Gatsis, J.G.; Funk, E.W.

1988-06-14T23:59:59.000Z

135

catalytic_upgrading_sugars_to_hydrocarbons  

Broader source: Energy.gov (indexed) [DOE]

phase reforming into hydrocarbons for fuels and co-product commodities. Process Block Diagram Next Steps Additional modeling is necessary to quantify baseline costs associated...

136

Application of advanced hydrocarbon characterization and its...  

Broader source: Energy.gov (indexed) [DOE]

advanced hydrocarbon characterization and its consequences on future fuel properties and advanced combustion research Rafal Gieleciak, Craig Fairbridge and Darcy Hager Poster...

137

Nox reduction system utilizing pulsed hydrocarbon injection  

DOE Patents [OSTI]

Hydrocarbon co-reductants, such as diesel fuel, are added by pulsed injection to internal combustion engine exhaust to reduce exhaust NO.sub.x to N.sub.2 in the presence of a catalyst. Exhaust NO.sub.x reduction of at least 50% in the emissions is achieved with the addition of less than 5% fuel as a source of the hydrocarbon co-reductants. By means of pulsing the hydrocarbon flow, the amount of pulsed hydrocarbon vapor (itself a pollutant) can be minimized relative to the amount of NO.sub.x species removed.

Brusasco, Raymond M. (Livermore, CA); Penetrante, Bernardino M. (San Ramon, CA); Vogtlin, George E. (Fremont, CA); Merritt, Bernard T. (Livermore, CA)

2001-01-01T23:59:59.000Z

138

Biodegradation of Aromatic Hydrocarbons in an Extremely Acidic Environment  

Science Journals Connector (OSTI)

...biodegradation of aromatic hydrocarbons can occur in environments...Polycyclic aromatic hydrocarbons (PAHs) occur as common...formed by incomplete combustion of fossil fuels...enrichments with aromatic hydrocarbons, mineralization assays...lysis was initiated by heat and sodium dodecyl...

Raymond D. Stapleton; Dwayne C. Savage; Gary S. Sayler; Gary Stacey

1998-11-01T23:59:59.000Z

139

High Levels of Carcinogenic Polycyclic Aromatic Hydrocarbons in Mate Drinks  

Science Journals Connector (OSTI)

...polycyclic aromatic hydrocarbons| Introduction Esophageal...polycyclic aromatic hydrocarbon (PAH) content. PAHs...usually exposed to combustion products from burning...SRM 2260a Aromatic Hydrocarbons in Toluene, SRM 2269...dichloromethane; heat: preheat cell at 100C...

Farin Kamangar; Michele M. Schantz; Christian C. Abnet; Renato B. Fagundes; and Sanford M. Dawsey

2008-05-01T23:59:59.000Z

140

High Levels of Carcinogenic Polycyclic Aromatic Hydrocarbons in Mate Drinks  

Science Journals Connector (OSTI)

...polycyclic aromatic hydrocarbons (PAH), including...polycyclic aromatic hydrocarbons| Introduction...mechanism. However, data on the association...polycyclic aromatic hydrocarbon (PAH) content...usually exposed to combustion products from burning...dichloromethane; heat: preheat cell...

Farin Kamangar; Michele M. Schantz; Christian C. Abnet; Renato B. Fagundes; and Sanford M. Dawsey

2008-05-01T23:59:59.000Z

Note: This page contains sample records for the topic "monoxide hydrocarbons odors" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

MICROCHEMICALJOURNAL39, 160-165Hydrocarbons in Air  

E-Print Network [OSTI]

from Waters Associates. Water used was deionized, distilled, and hydrocarbon filtered (BarnsteadMICROCHEMICALJOURNAL39, 160-165Hydrocarbons in Air to extract polycyclic aromatic hydrocarbons (PAH) from air particulate sampleswas investigated. High

Canberra, University of

142

Metabolism of Polycyclic Aromatic Hydrocarbons in Cell Cultures  

Science Journals Connector (OSTI)

...metabolism of polycyclic aromatic hydrocarbons to water-soluble and organic-soluble...metabolism of polycyclic aromatic hydrocarbons to water-soluble and organic-soluble...cytotoxicity and conversion of hydrocarbons to water-soluble products (Chart...

Eliezer Huberman; James K. Selkirk; and Charles Heidelberger

1971-12-01T23:59:59.000Z

143

High Levels of Carcinogenic Polycyclic Aromatic Hydrocarbons in Mate Drinks  

Science Journals Connector (OSTI)

...polycyclic aromatic hydrocarbons (PAH), including...80C) or cold (5C) water. Measurements were...polycyclic aromatic hydrocarbons in mate drinks. | Drinking...polycyclic aromatic hydrocarbons (PAH), including...cold (5 degrees C) water. Measurements were...

Farin Kamangar; Michele M. Schantz; Christian C. Abnet; Renato B. Fagundes; and Sanford M. Dawsey

2008-05-01T23:59:59.000Z

144

Hydrocarbons in rift basins: the role of stratigraphy  

Science Journals Connector (OSTI)

...versus shallow-water environments...A (1999) Hydrocarbons in rift basins...Facies and hydrocarbon potential The...availability of water. This can either...form seals for hydrocarbons. The shallow-water environ- ments...

1999-01-01T23:59:59.000Z

145

Learning and discrimination of cuticular hydrocarbons in a social insect  

Science Journals Connector (OSTI)

...colony members. Cuticular hydrocarbons (CHCs) play a central...CHC profile with synthetic hydrocarbons [4-6] reveal that some hydrocarbons elicit aggression. However...non-volatile, insoluble in water and therefore difficult...

2012-01-01T23:59:59.000Z

146

Tensile Effective Stresses in Hydrocarbon Storage Caverns  

E-Print Network [OSTI]

Tensile Effective Stresses in Hydrocarbon Storage Caverns Hippolyte Djizanne and Pierre BĂ©rest LMS, Germany,1-2 October 2012 TENSILE EFFECTIVE STRESSES IN HYDROCARBON STORAGE CAVERNS Hippolyte Djizanne1 that effective tensile stresses can be generated at a cavern wall after a rapid increase or decrease in pressure

Paris-Sud XI, Université de

147

Conversion of organic solids to hydrocarbons  

DOE Patents [OSTI]

A method of converting organic solids to liquid and gaseous hydrocarbons includes impregnating an organic solid with photosensitizing ions and exposing the impregnated solid to light in a non-oxidizing atmosphere for a time sufficient to photocatalytically reduce the solid to at least one of a liquid and a gaseous hydrocarbon. 5 Figs.

Greenbaum, E.

1995-05-23T23:59:59.000Z

148

The Effects of Two Isomeric Benzoflavones on Aryl Hydrocarbon Hydroxylase and the Toxicity and Carcinogenicity of Polycyclic Hydrocarbons  

Science Journals Connector (OSTI)

...recrystallized from alcohol : water. For tissue culture experiments the hydrocarbons and benzoflavones...metabolism of the hydrocarbons to water-soluble derivatives...chloroform:methanol. Hydrocarbon-3 H metabolized to water-soluble derivatives...

Leila Diamond; Rosemary McFall; Joel Miller; and Harry V. Gelboin

1972-04-01T23:59:59.000Z

149

Hydrocarbon fouling of SCR during Premixed Charge Compression...  

Broader source: Energy.gov (indexed) [DOE]

Hydrocarbon fouling of SCR during Premixed Charge Compression Ignition (PCCI) combustion Hydrocarbon fouling of SCR during Premixed Charge Compression Ignition (PCCI) combustion...

150

Algal Lipid Extraction and Upgrading to Hydrocarbons Technology...  

Broader source: Energy.gov (indexed) [DOE]

and upgrading pathway to be competitive with petroleum-derived gasoline-, diesel-, and jet-range hydrocarbon blendstocks. Algal Lipid Extraction and Upgrading to Hydrocarbons...

151

DOE Perspectives on Advanced Hydrocarbon-based Biofuels | Department...  

Broader source: Energy.gov (indexed) [DOE]

DOE Perspectives on Advanced Hydrocarbon-based Biofuels DOE Perspectives on Advanced Hydrocarbon-based Biofuels Zia Haq, DPA Coordinator, presentation on DOE Perspectives on...

152

Commercialization of IH2® Biomass Direct-to-Hydrocarbon Fuel...  

Broader source: Energy.gov (indexed) [DOE]

Commercialization of IH2 Biomass Direct-to-Hydrocarbon Fuel Technology Commercialization of IH2 Biomass Direct-to-Hydrocarbon Fuel Technology Breakout Session 2: Frontiers and...

153

Titanium monoxide spectroscopy following laser-induced optical breakdown  

SciTech Connect (OSTI)

This work investigates Titanium Monoxide (TiO) in ablation-plasma by employing laser-induced breakdown spectroscopy (LIBS) with 1 to 10 TW/cm{sup 2} irradiance, pulsed, 13 nanosecond, Q-switched Nd:YAG laser radiation at the fundamental wavelength of 1064 nm. The analysis of TiO is based on our first accurate determination of transition line strengths for selected TiO A-X, B-X, and E-X transitions, particularly TiO A-X {gamma} and B-X {gamma} Prime bands. Electric dipole line strengths for the A{sup 3}{Phi}-X{sup 3}{delta} and B{sup 3}{Pi}-X{sup 3}{delta} bands of TiO are computed. The molecular TiO spectra are observed subsequent to laser-induced breakdown (LIB). We discuss analysis of diatomic molecular spectra that may occur simultaneously with spectra originating from atomic species. Gated detection is applied to investigate the development in time of the emission spectra following LIB. Collected emission spectra allow one to infer micro-plasma parameters such as temperature and electron density. Insight into the state of the micro-plasma is gained by comparing measurements with predictions of atomic and molecular spectra. Nonlinear fitting of recorded and computed diatomic spectra provides the basis for molecular diagnostics, while atomic species may overlap and are simultaneously identified. Molecular diagnostic approaches similar to TiO have been performed for diatomic molecules such as AlO, C{sub 2}, CN, CH, N{sub 2}, NH, NO and OH.

Parigger, Christian G.; Woods, Alexander C.; Keszler, Anna; Nemes, Laszlo; Hornkohl, James O. [The University of Tennessee/UT Space Institute, Center for Laser Applications, 411 B.H. Goethert Parkway, Tullahoma, TN 37388-9700 (United States); Chemical Research Center of the Hungarian Academy of Sciences, Institute of Materials and Environmental Chemistry, Pusztaszeri ut 59-67, H-1025 Budapest (Hungary); Chemical Research Center of the Hungarian Academy of Sciences, Laser Spectroscopy Laboratory, Pusztaszeri ut 59-67, H-1025 Budapest (Hungary); Hornkohl Consulting, Tullahoma, TN 37388 (United States)

2012-07-30T23:59:59.000Z

154

Final Technical Report "Catalytic Hydrogenation of Carbon Monoxide and Olefin Oxidation" Grant number : DE-FG02-86ER13615  

SciTech Connect (OSTI)

Title: Catalytic Hydrogenation of Carbon Monoxide and Olefin Oxidation Grant No. DE-FG02-86ER13615 PI: Wayland, B. B. (wayland@sas.upenn.edu) Abstract Development of new mechanistic strategies and catalyst materials for activation of CO, H2, CH4, C2H4, O2, and related substrates relevant to the conversion of carbon monoxide, alkanes, and alkenes to organic oxygenates are central objectives encompassed by this program. Design and synthesis of metal complexes that manifest reactivity patterns associated with potential pathways for the hydrogenation of carbon monoxide through metallo-formyl (M-CHO), dimetal ketone (M-C(O)-M), and dimetal dionyl (M-C(O)-C(O)-M) species is one major focus. Hydrocarbon oxidation using molecular oxygen is a central goal for methane activation and functionalization as well as regioselective oxidation of olefins. Discovery of new reactivity patterns and control of selectivity are pursued through designing new metal complexes and adjusting reaction conditions. Variation of reaction media promotes distinct reaction pathways that control both reaction rates and selectivities. Dimetalloradical diporphyrin complexes preorganize transition states for substrate reactions that involve two metal centers and manifest large rate increases over mono-metalloradical reactions of hydrogen, methane, and other small molecule substrates. Another broad goal and recurring theme of this program is to contribute to the thermodynamic database for a wide scope of organo-metal transformations in a range of reaction media. One of the most complete descriptions of equilibrium thermodynamics for organometallic reactions in water and methanol is emerging from the study of rhodium porphyrin substrate reactions in aqueous and alcoholic media. Water soluble group nine metalloporphyrins manifest remarkably versatile substrate reactivity in aqueous and alcoholic media which includes producing rhodium formyl (Rh-CHO) and hydroxy methyl (Rh-CH2OH) species. Exploratory directions for this program include expending new strategies for anti-Markovnikov addition of water, alcohols, and amines with olefins, developing catalytic reactions of CO to give formamides and formic esters, and evaluating the potential for coupling reactions of CO to produce organic building blocks.

Wayland, B.B.

2009-08-31T23:59:59.000Z

155

Coadsorption of hydrogen and ethylene, and carbon monoxide and ethylene on the Ru(001) surface  

SciTech Connect (OSTI)

A detailed investigation of the coadsorption of ethylene with both preadsorbed hydrogen and preadsorbed carbon monoxide on the Ru(001) surface is reported here. Both preadsorbed hydrogen and carbon monoxide reduce the saturation coverage of subsequently chemisorbed ethylene. The coadsorption of hydrogen with ethylene results in detectable hydrogenation of ethylene to ethane below 250 K, whereas no self-hydrogenation of ethylene to ethane is observed. High-resolution electron energy loss spectra show that ethylene coadsorbed with either hydrogen or carbon monoxide decomposes to ethylidyne (CCH/sub 3/) and acetylide (CCH), as it does on the clean surface. Carbon monoxide preadsorption enhances the stability of the ethylidyne such that it decomposes at approximately 420 K, rather than 355 K as on the initially clean Ru(001) surface. Preadsorbed carbon monoxide also reduces the ratio of ethylidyne to acetylide that is formed from ethylene, compared to the ratio observed from an equivalent coverage of ethylene on the clean surface; hydrogen preadsorption, on the other hand, increases this ratio.

Hills, M.M.; Parmeter, J.E.; Weinberg, W.H.

1986-11-12T23:59:59.000Z

156

Preparation of synthetic hydrocarbon lubricants  

SciTech Connect (OSTI)

A process is described for preparing synthetic lubricating materials which process comprises: (a) reacting (i) at least a portion of a reaction product of the liquid phase oligomerization of propylene, butylene or mixtures thereof containing a C/sub 6/ olefin component, (ii) a linear olefin reactant having an average carbon number ranging from about 10 to about 18 in the presence of a catalyst, (b) separating from the reaction mixture of (a) hydrocarbons which distill at a temperature above about 660/sup 0/ F. (316/sup 0/ C.), and (c) hydrogenating the reaction product of (b) by contact with hydrogen with or without a catalyst at a temperature ranging from about 25/sup 0/ C. to about 300/sup 0/ C.

Johnson, T.H.

1986-10-07T23:59:59.000Z

157

A population-based exposure assessment methodology for carbon monoxide: Development of a carbon monoxide passive sampler and occupational dosimeter  

SciTech Connect (OSTI)

Two devices, an occupational carbon monoxide (CO) dosimeter (LOCD), and an indoor air quality (IAQ) passive sampler were developed for use in population-based CO exposure assessment studies. CO exposure is a serious public health problem in the U.S., causing both morbidity and mortality (lifetime mortality risk approximately 10{sup -4}). Sparse data from population-based CO exposure assessments indicate that approximately 10% of the U.S. population is exposed to CO above the national ambient air quality standard. No CO exposure measurement technology is presently available for affordable population-based CO exposure assessment studies. The LOCD and IAQ Passive Sampler were tested in the laboratory and field. The palladium-molybdenum based CO sensor was designed into a compact diffusion tube sampler that can be worn. Time-weighted-average (TWA) CO exposure of the device is quantified by a simple spectrophotometric measurement. The LOCD and IAQ Passive Sampler were tested over an exposure range of 40 to 700 ppm-hours and 200 to 4200 ppm-hours, respectively. Both devices were capable of measuring precisely (relative standard deviation <20%), with low bias (<10%). The LOCD was screened for interferences by temperature, humidity, and organic and inorganic gases. Temperature effects were small in the range of 10{degrees}C to 30{degrees}C. Humidity effects were low between 20% and 90% RH. Ethylene (200 ppm) caused a positive interference and nitric oxide (50 ppm) caused a negative response without the presence of CO but not with CO.

Apte, M.G.

1997-09-01T23:59:59.000Z

158

Mechanism of methanol synthesis from carbon monoxide and hydrogen on copper catalysts  

SciTech Connect (OSTI)

The authors examine possible mechanisms of methanol synthesis from carbon monoxide and hydrogen on supported copper catalysts. Two broad categories of reaction mechanism can be identified: (a) Type I: Carbon monoxide, adsorbed on the copper surface, is hydrogenated by the addition of hydrogen atoms while the C-O bond remains intact. A second C-O bond is neither formed nor broken. (b) Type II: Carbon monoxide (or a partially hydrogenated intermediate, e.g., HCO) reacts with an oxygen atom on the catalyst surface to give an intermediate, typically a formate, which contains two C-O bonds. Subsequent reaction leads overall to methanol and the reformation of the surface oxygen atom. Both mechanisms are discussed.

Fakley, M.E.; Jennings, J.R.; Spencer, M.S. (ICI Chemicals and Polymers Ltd, Billingham, Cleveland (England))

1989-08-01T23:59:59.000Z

159

Crystallographic Snapshots of Cyanide- and Water-Bound C-Clusters from Bifunctional Carbon Monoxide Dehydrogenase/Acetyl-CoA Synthase  

E-Print Network [OSTI]

Nickel-containing carbon monoxide dehydrogenases (CODHs) reversibly catalyze the oxidation of carbon monoxide to carbon dioxide and are of vital importance in the global carbon cycle. The unusual catalytic CODH C-cluster ...

Kung, Yan

160

Selective photooxidation of hydrocarbons in zeolites by oxygen  

DOE Patents [OSTI]

A selective photooxidation process for the conversion of hydrocarbon molecules to partially oxygenated derivatives, which comprises the steps of adsorbing a hydrocarbon and oxygen onto a dehydrated zeolite support matrix to form a hydrocarbon-oxygen contact pair, and subsequently exposing the hydrocarbon-oxygen contact pair to visible light, thereby forming a partially oxygenated derivative.

Frei, Heinz (Berkeley, CA); Blatter, Fritz (Berkeley, CA); Sun, Hai (Berkeley, CA)

1998-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "monoxide hydrocarbons odors" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Removal of trace olefins from aromatic hydrocarbons  

SciTech Connect (OSTI)

A process is described for treating a hydrocarbon process stream by converting trace quantities of olefinic impurities to nonolefinic hydrocarbons. The process comprises contacting the process stream, which contains trace olefins in an amount of from about 50 to about 2000 as measured by Bromine Index and at least 80% by weight of aromatic and naphthenic hydrocarbons having from 6 to 20 carbon atoms per molecule, at reaction conditions which ensure liquid phase operation with a solid catalyst composite comprising a crystalline aluminosilicate zeolite and a refractory inorganic oxide. A catalytic olefin-consuming alkylation reaction then produces an essentially olefinfree product stream with approximately the same quantity and distribution of aromatic and naphthenic hydrocarbons as contained in the process stream.

Sachtler, J.W.A.; Barger, P.T.

1989-01-03T23:59:59.000Z

162

Analyzing Biomass Conversion into Liquid Hydrocarbons  

Science Journals Connector (OSTI)

Variants of the Fischer–Tropsch producer-gas conversion into liquid hydrocarbons are analyzed under the ... is attained in the reactions occurring in the biomass gasification. When the raw material is wood ... th...

V. D. Meshcheryakov; V. A. Kirillov

2002-09-01T23:59:59.000Z

163

Solubilization of petroleum hydrocarbons using biosurfactants  

E-Print Network [OSTI]

Low solubility of petroleum hydrocarbons in water is the major factor limiting the degradation rates of these compounds (Zhang and Miller, 1994). The fraction that is more soluble in the aqueous phase is degraded at higher rates, while less soluble...

Kanga, Shahrukh

2012-06-07T23:59:59.000Z

164

Methanol conversion to higher hydrocarbons  

SciTech Connect (OSTI)

Several indirect options exist for producing chemicals and transportation fuels from coal, natural gas, or biomass. All involve an initial conversion step to synthesis gas (CO and H{sub 2}). Presently, there are two commercial technologies for converting syngas to liquids: Fischer-Tropsch, which yields a range of aliphatic hydrocarbons with molecular weights determined by Schulz-Flory kinetics, and methanol synthesis. Mobil`s diversity of technology for methanol conversion gives the methanol synthesis route flexibility for production of either gasoline, distillate or chemicals. Mobil`s ZSM-5 catalyst is the key in several processes for producing chemicals and transportation fuels from methanol: MTO for light olefins, MTG for gasoline, MOGD for distillates. The MTG process has been commercialized in New Zealand since 1985, producing one-third of the country`s gasoline supply, while MTO and MOGD have been developed and demonstrated at greater than 100 BPD scale. This paper will discuss recent work in understanding methanol conversion chemistry and the various options for its use.

Tabak, S.A. [Mobil Research and Development Corp., Princeton, NJ (United States). Central Research Lab.

1994-12-31T23:59:59.000Z

165

Carbon monoxide oxidation on Rh(111): Velocity and angular distributions of the CO2 product  

E-Print Network [OSTI]

Carbon monoxide oxidation on Rh(111): Velocity and angular distributions of the CO2 product J. I and angular distributions of CO2 produced by CO oxidation on Rh 111 have been measured as a function a fundamental and a practical point of view. CO2 formation serves as a model recombina- tion reaction

Sibener, Steven

166

Observations of rotating jets of carbon monoxide in comet Hale-Bopp with the IRAM interferometer  

E-Print Network [OSTI]

Observations of rotating jets of carbon monoxide in comet Hale-Bopp with the IRAM interferometer;eres, France Abstract. CO was observed on March 11, 1997 in comet Hale-Bopp with the IRAM Plateau de for parent molecules. We have developed a 3-D model simulating rotating spiral jets of CO gas. We present

Demoulin, Pascal

167

Carbon monoxide annealed TiO2 nanotube array electrodes for efficient biosensor applications  

E-Print Network [OSTI]

Carbon monoxide annealed TiO2 nanotube array electrodes for efficient biosensor applications by anodic oxidation of titanium foil followed with O2 and CO annealing were employed as matrices consisted of Ti3+ defects with carbon-doping and exhibited well defined quasi-reversible cyclic voltammetric

Cao, Guozhong

168

Crystallization and mutational studies of carbon monoxide dehydrogenase from moorella thermoacetica  

E-Print Network [OSTI]

Carbon Monoxide Dehydrogenase (CODH), also known as Acetyl-CoA synthase (ACS), is one of seven known Ni containing enzymes. CODH/ACS is a bifunctional enzyme which oxidizes CO to CO2 reversibly and synthesizes acetyl-CoA. Recently, X-ray crystal...

Kim, Eun Jin

2004-09-30T23:59:59.000Z

169

Effect of redox potential, sulfide ions and a persulfide forming cysteine residue on carbon monoxide dehydrogenase  

E-Print Network [OSTI]

The Ni-Fe-S C-cluster of carbon monoxide dehydrogenases (CODH), which catalyzes the reversible oxidation of CO to CO2, can be stabilized in four redox states: Cox, Cred1, Cint, and Cred2. The best-supported mechanism of catalysis involves a one...

Feng, Jian

2005-08-29T23:59:59.000Z

170

Study of hydrogen and carbon monoxide adsorption on modified Zn/Cr catalysts by adsorption calorimetry  

SciTech Connect (OSTI)

Differential heat of adsorption (q) of hydrogen (a) and carbon monoxide (b) as a function of the adsorbed amount (a) on Zn/Cr catalysts at 463/sup 0/K; 1) unpromoted catalyst, 2) catalyst promoted with 2.5% of K/sub 2/O.

Yoshin, S.V.; Klyacho, A.L.; Kondrat'ev, L.T.; Leonov, V.E.; Skripchenko, G.B.; Sushchaya, L.E.

1986-08-01T23:59:59.000Z

171

Dissociation and excitation coefficients of nitrogen molecules and nitrogen monoxide generation  

SciTech Connect (OSTI)

The excitation coefficient ?{sub N2} is calculated for the excited metastable level of N{sub 2}(A{sub 3}?{sub u}{sup +}) in nitrogen molecules. In addition, the dissociation coefficient of nitrogen molecules is investigated by making use of the Boltzmann distribution of the electrons in atmospheric plasmas. The excitation and electron-impact dissociation coefficients of nitrogen molecules are analytically expressed in terms of the electron temperature T{sub e} for evaluations of the reactive oxygen and nitrogen species in atmospheric plasmas. As an application example of these coefficients, the nitrogen monoxide generation through a microwave torch is carried out for a development of medical tool. The nitrogen monoxide concentration from a microwave plasma-torch can be easily controlled by the nitrogen flow rate, mole fraction of the oxygen gas, and the microwave power. A simple analytic expression of the nitrogen monoxide concentration is obtained in terms of the oxygen molecular density and gas flow rate. The experimental data agree remarkably well with the theoretical results from the analytical expression. A microwave nitrogen-torch can easily provide an appropriate nitrogen monoxide concentration for the wound healings.

Uhm, Han S.; Na, Young H.; Choi, Eun H.; Cho, Guangsup [Department of Electronic and Biological Physics, Kwangwoon University 447-1 Wolgye-Dong, Nowon-Gu, Seoul 137-701 (Korea, Republic of)] [Department of Electronic and Biological Physics, Kwangwoon University 447-1 Wolgye-Dong, Nowon-Gu, Seoul 137-701 (Korea, Republic of)

2013-08-15T23:59:59.000Z

172

Process for producing methane from gas streams containing carbon monoxide and hydrogen  

DOE Patents [OSTI]

Carbon monoxide-containing gas streams are passed over a catalyst capable of catalyzing the disproportionation of carbon monoxide so as to deposit a surface layer of active surface carbon on the catalyst essentially without formation of inactive coke thereon. The surface layer is contacted with steam and is thus converted to methane and CO.sub.2, from which a relatively pure methane product may be obtained. While carbon monoxide-containing gas streams having hydrogen or water present therein can be used only the carbon monoxide available after reaction with said hydrogen or water is decomposed to form said active surface carbon. Although hydrogen or water will be converted, partially or completely, to methane that can be utilized in a combustion zone to generate heat for steam production or other energy recovery purposes, said hydrogen is selectively removed from a CO--H.sub.2 -containing feed stream by partial oxidation thereof prior to disproportionation of the CO content of said stream.

Frost, Albert C. (Congers, NY)

1980-01-01T23:59:59.000Z

173

Association of hydrogen metabolism with unitrophic or mixotrophic growth of Methanosarcina barkeri on carbon monoxide.  

Science Journals Connector (OSTI)

...by the simultaneous consumption of methanol and CO...by the simultaneous consumption of methanol and CO...conbustion of fossil fuels. Carbon monoxide is...involves the production and consumption of a carbonyl group...served as experi- mental vessels. Immediately after...

J M O'Brien; R H Wolkin; T T Moench; J B Morgan; J G Zeikus

1984-04-01T23:59:59.000Z

174

Electrochemical Removal of Carbon Monoxide in Reformate Hydrogen for Fueling Proton Exchange Membrane  

E-Print Network [OSTI]

Electrochemical Removal of Carbon Monoxide in Reformate Hydrogen for Fueling Proton Exchange Membrane Fuel Cells Sivagaminathan Balasubramanian, Charles E. Holland,* and John W. Weidner*,z Center in reformate hydrogen. In this design, the potential and gas flow are switched between the two filter cells so

Weidner, John W.

175

An experimental investigation of the ignition properties of hydrogen and carbon monoxide  

E-Print Network [OSTI]

for syngas turbine applications S.M. Walton *, X. He, B.T. Zigler, M.S. Wooldridge Department of Mechanical of simulated syngas mixtures of hydrogen (H2), carbon monoxide (CO), oxygen (O2), nitrogen (N2), and carbon mechanism for H2 and CO. Ă? 2006 The Combustion Institute. Published by Elsevier Inc. All rights reserved

Wooldridge, Margaret S.

176

Factors Affecting the Efficiency of Carbon Monoxide Photoproduction in the St. Lawrence Estuarine System (Canada)  

Science Journals Connector (OSTI)

Factors Affecting the Efficiency of Carbon Monoxide Photoproduction in the St. Lawrence Estuarine System (Canada) ... The solar insolation-weighted mean apparent quantum yield of CO (?CO) decreased as much as fourfold with increasing salinity and showed a strong positive correlation with the dissolved organic carbon-specific absorption coefficient at 254 nm. ...

Yong Zhang; Huixiang Xie; Guohua Chen

2006-11-01T23:59:59.000Z

177

PHASE BEHAVIOR OF LIGHT GASES IN HYDROCARBON AND AQUEOUS SOLVENTS  

SciTech Connect (OSTI)

Under previous support from the Department of Energy, an experimental facility has been established and operated to measure valuable vapor-liquid equilibrium data for systems of interest in the production and processing of coal fluids. To facilitate the development and testing of models for prediction of the phase behavior for such systems, we have acquired substantial amounts of data on the equilibrium phase compositions for binary mixtures of heavy hydrocarbon solvents with a variety of supercritical solutes, including hydrogen, methane, ethane, carbon monoxide, and carbon dioxide. The present project focuses on measuring the phase behavior of light gases and water in Fischer-Tropsch (F-T) type solvents at conditions encountered in indirect liquefaction processes and evaluating and developing theoretically-based correlating frameworks to predict the phase behavior of such systems. Specific goals of the proposed work include (a) developing a state-of-the-art experimental facility to permit highly accurate measurements of equilibrium phase compositions (solubilities) of challenging F-T systems, (b) measuring these properties for systematically-selected binary, ternary and molten F-T wax mixtures to provide critically needed input data for correlation development, (c) developing and testing models suitable for describing the phase behavior of such mixtures, and (d) presenting the modeling results in generalized, practical formats suitable for use in process engineering calculations. During the present period, the Park-Gasem-Robinson (PGR) equation of state (EOS) has been modified to improve its volumetric and equilibrium predictions. Specifically, the attractive term of the PGR equation was modified to enhance the flexibility of the model, and a new expression was developed for the temperature dependence of the attractive term in this segment-segment interaction model. The predictive capability of the modified PGR EOS for vapor pressure, and saturated liquid and vapor densities was evaluated for selected normal paraffins, normal alkenes, cyclo-paraffins, light aromatics, argon, carbon dioxide and water. The generalized EOS constants and substance-specific characteristic parameters in the modified PGR EOS were obtained from the pure component vapor pressures, and saturated liquid and vapor molar volumes. The calculated phase properties were compared to those of the Peng-Robinson (PR), the simplified-perturbed-hard-chain theory (SPHCT) and the original PGR equations. Generally, the performance of the proposed EOS was better than the PR, SPHCT and original PGR equations in predicting the pure fluid properties (%AAD of 1.3, 2.8 and 3.7 for vapor pressure, saturated liquid and vapor densities, respectively).

KHALED A.M. GASEM; ROBERT L. ROBINSON, JR.

1998-08-31T23:59:59.000Z

178

Gulf Hydrocarbon Inc | Open Energy Information  

Open Energy Info (EERE)

Hydrocarbon Inc Hydrocarbon Inc Jump to: navigation, search Name Gulf Hydrocarbon Inc Address 2016 Main St Place Houston, Texas Zip 77002 Sector Biofuels Product Wholesale marketing of biodiesel and ethanol to refiners, blenders and petroleum distributors Website http://www.gulfhydrocarbon.com Coordinates 29.749227°, -95.371693° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":29.749227,"lon":-95.371693,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

179

George A. Olah, Carbocation and Hydrocarbon Chemistry  

Office of Scientific and Technical Information (OSTI)

George A. Olah, Carbocation and Hydrocarbon Chemistry George A. Olah, Carbocation and Hydrocarbon Chemistry Resources with Additional Information · Patents George A. Olah Courtesy Rand Larson, Morningstar Productions George Olah received the 1994 Nobel Prize in Chemistry "for his contribution to carbocation chemistry" and his 'role in the chemistry of hydrocarbons. In particular, he developed superacids ... that are much stronger than ordinary acids, are non-nucleophilic, and are fluid at low temperatures. In such media ... carbocations are stable and their physical properties ... can be observed, thus allowing details of their structures to be determined. Besides trivalent ions ... Olah demonstrated the existence of higher coordinate carbocations ... . These species do not violate the octet rule, but involve 2-electron 3-center bonding. '1

180

Using supercritical fluids to refine hydrocarbons  

DOE Patents [OSTI]

This is a method to reactively refine hydrocarbons, such as heavy oils with API gravities of less than 20.degree. and bitumen-like hydrocarbons with viscosities greater than 1000 cp at standard temperature and pressure using a selected fluid at supercritical conditions. The reaction portion of the method delivers lighter weight, more volatile hydrocarbons to an attached contacting device that operates in mixed subcritical or supercritical modes. This separates the reaction products into portions that are viable for use or sale without further conventional refining and hydro-processing techniques. This method produces valuable products with fewer processing steps, lower costs, increased worker safety due to less processing and handling, allow greater opportunity for new oil field development and subsequent positive economic impact, reduce related carbon dioxide, and wastes typical with conventional refineries.

Yarbro, Stephen Lee

2014-11-25T23:59:59.000Z

Note: This page contains sample records for the topic "monoxide hydrocarbons odors" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

E-Print Network 3.0 - aromatic hydrocarbons evaluated Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

various hydrocarbons on monolithic hydrocarbon adsorber Dae Jung Kim,a Ji Man Kim,a Jae Eui Yie... and conversion of various hydrocarbons on monolithic hydrocarbon adsorbers were...

182

E-Print Network 3.0 - aromatic hydrocarbons part Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

various hydrocarbons on monolithic hydrocarbon adsorber Dae Jung Kim,a Ji Man Kim,a Jae Eui Yie... and conversion of various hydrocarbons on monolithic hydrocarbon adsorbers were...

183

Sexual selection on cuticular hydrocarbons of male sagebrush crickets in the wild  

Science Journals Connector (OSTI)

...association between cuticular hydrocarbon composition and desiccation...temperature on cuticular lipids and water balance in a desert Drosophila...interactions for cuticular hydrocarbon expression in Drosophila simulans...evolutionary roles of cuticular hydrocarbons in Diptera. In Insect hydrocarbons...

2013-01-01T23:59:59.000Z

184

Sustainable treatment of hydrocarbon-contaminated industrial land   

E-Print Network [OSTI]

Land contamination by petroleum hydrocarbons is a widespread and global environmental pollution issue from recovery and refining of crude oil and the ubiquitous use of hydrocarbons in industrial processes and applications. ...

Cunningham, Colin John

2012-06-25T23:59:59.000Z

185

Chemical nature of high-molecular hydrocarbons of gaseous condensates  

SciTech Connect (OSTI)

Mass spectrometry was used to study the group-structure composition of high-boiling 50 deg (200/degrees/-250/degrees/, 250/degrees/-300/degrees/, and 300/degrees/-350/degrees/C) fractions of East Turkmenistan condensates: the hydrocarbons composition is characterized by a high content of paraffinic hydrocarbons, and that of others by aromatic and naphthenic hydrocarbons. For all the condensates under investigation, as the boiling temperature of fractions increases, the content of paraffinic hydrocarbons in them is increased, while that of naphthenic hydrocarbons is reduced. The distribution of naphthenic hydrocarbons according to the number of rings is identical. In high-paraffin condensates, monoaromatic hydrocarbons consist mainly structures with alkyl substituents, but in condensates with a high content of aromatic and naphthenic hydrocarbons they consist mainly of structures with naphthenic substituents. 4 references, 1 figures, 2 tables.

Kul'dzhayev, B.A.; Makarov, V.V.; Sergiyenko, S.R.; Khramova, E.V.

1987-01-01T23:59:59.000Z

186

Chapter 9 - Chemical and Physical Properties of Hydrocarbons  

Science Journals Connector (OSTI)

Publisher Summary Hydrocarbons are the simplest organic compounds and contain only carbon and hydrogen but they can be straight chain or branched chain with the same empirical formula but showing differences in properties. Chemical change results in the hydrocarbon yielding a product that may be entirely different in composition to the starting hydrocarbon—the exception is the isomerization reaction where a straight-chain hydrocarbon is converted to a branched-chain hydrocarbon. Chemical properties of hydrocarbons describe the potential of hydrocarbons to undergo chemical change or reaction by virtue of the hydrocarbon structure. Physical properties can be observed or measured without changing the composition of matter. Physical properties are used to observe and describe matter. Physical properties that are of interest in the current context include: boiling point, melting point, density, vapor density, flash point, ignition temperature, and dew point.

James G. Speight

2011-01-01T23:59:59.000Z

187

E-Print Network 3.0 - aromatic hydrocarbons methyl Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Renewable Energy 2 Quantification of Local Ozone Production Attributable to Automobile Hydrocarbon Emissions Summary: -fueled automobiles, most cyclic hydrocarbons are...

188

E-Print Network 3.0 - aromatic hydrocarbons progress Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Collection: Chemistry 3 Quantification of Local Ozone Production Attributable to Automobile Hydrocarbon Emissions Summary: -fueled automobiles, most cyclic hydrocarbons are...

189

E-Print Network 3.0 - aromatic hydrocarbons fluorene Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hydrocarbons... Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous organic pollutants in urban environments... in the urbanized and rapidly urbanizing areas. Keywords...

190

E-Print Network 3.0 - aromatic hydrocarbon phenanthrene Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Abstract Polycyclic aromatic hydrocarbons (PAHs) and dioxins are lipophilic organic pollutants occurring... absorption, pig INTRODUCTION Polycyclic aromatic hydrocarbons (PAHs)...

191

E-Print Network 3.0 - aromatic hydrocarbons based Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Aromatic Hydrocarbons Volatile Organic... Compounds Toxic Organic Halogenated Dioxins Furans (dioxins) Polycyclic Aromatic Hydrocarbons found... Rana Novini ATOC 3500 Burn...

192

E-Print Network 3.0 - aromatic hydrocarbons Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hydrocarbons... Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous organic pollutants in urban environments... in the urbanized and rapidly urbanizing areas. Keywords...

193

E-Print Network 3.0 - aromatic hydrocarbons pah5 Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

hydrocarbons (PAHs) are ubiquitous, recalcitrant, and potentially carcinogenic pollutants. Plants Summary: 1461 Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous,...

194

E-Print Network 3.0 - aromatic hydrocarbons inenvironmental Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hydrocarbons... Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous organic pollutants in urban environments... in the urbanized and rapidly urbanizing areas. Keywords...

195

E-Print Network 3.0 - aromatic hydrocarbon o-quinones Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hydrocarbons... Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous organic pollutants in urban environments... in the urbanized and rapidly urbanizing areas. Keywords...

196

E-Print Network 3.0 - aromatic hydrocarbons assessment Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Aromatic Hydrocarbons Volatile Organic... Compounds Toxic Organic Halogenated Dioxins Furans (dioxins) Polycyclic Aromatic Hydrocarbons found... of airborne soot. The air...

197

Impact of emissions, chemistry, and climate on atmospheric carbon monoxide : 100-year predictions from a global chemistry-climate model  

E-Print Network [OSTI]

The possible trends for atmospheric carbon monoxide in the next 100 yr have been illustrated using a coupled atmospheric chemistry and climate model driven by emissions predicted by a global economic development model. ...

Wang, Chien.; Prinn, Ronald G.

198

Biological Conversion of Sugars to Hydrocarbons Technology Pathway  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Enzymes Acid + Caustic Wastewater Treatment Process Heat and Power Integration Biogas + Sludge Fuel Finishing (hydroprocessing, as needed) Electricity Hydrogen Hydrocarbon...

199

THE ELECTRON MICROSCOPY OF HYDROCARBON PRODUCTION IN PARTHENIUM ARGENTATUM (GUAYULE)  

E-Print Network [OSTI]

conversion of solar energy is the production of hydrocarbonsproduction of hydrocarbons. Mankind's use of biologically converted solar energy

Bauer, T.E.

2010-01-01T23:59:59.000Z

200

aromatic hydrocarbons coated: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: ??Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous environmental pollutants, known human lung carcinogens, and potent mammary carcinogens in animal models....

Note: This page contains sample records for the topic "monoxide hydrocarbons odors" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Method for converting hydrocarbon fuel into hydrogen gas and carbon dioxide  

DOE Patents [OSTI]

A method for converting hydrocarbon fuel into hydrogen gas and carbon dioxide within a reformer 10 is disclosed. According to the method, a stream including an oxygen-containing gas is directed adjacent to a first vessel 18 and the oxygen-containing gas is heated. A stream including unburned fuel is introduced into the oxygen-containing gas stream to form a mixture including oxygen-containing gas and fuel. The mixture of oxygen-containing gas and unburned fuel is directed tangentially into a partial oxidation reaction zone 24 within the first vessel 18. The mixture of oxygen-containing gas and fuel is further directed through the partial oxidation reaction zone 24 to produce a heated reformate stream including hydrogen gas and carbon monoxide. Steam may also be mixed with the oxygen-containing gas and fuel, and the reformate stream from the partial oxidation reaction zone 24 directed into a steam reforming zone 26. High- and low-temperature shift reaction zones 64,76 may be employed for further fuel processing.

Clawson, Lawrence G. (Dover, MA); Mitchell, William L. (Belmont, MA); Bentley, Jeffrey M. (Westford, MA); Thijssen, Johannes H. J. (Cambridge, MA)

2000-01-01T23:59:59.000Z

202

Production of hydrocarbons from hydrates. [DOE patent application  

DOE Patents [OSTI]

An economical and safe method of producing hydrocarbons (or natural gas) from in situ hydrocarbon-containing hydrates is given. Once started, the method will be self-driven and will continue producing hydrocarbons over an extended period of time (i.e., many days).

McGuire, P.L.

1981-09-08T23:59:59.000Z

203

Molecular carbon isotopic evidence for the origin of geothermal hydrocarbons  

Science Journals Connector (OSTI)

... in the flask's headspace. This procedure produced negligible amounts of contaminating hydrocarbons. The geothermal hydrocarbons were separated and combusted, and the carbon dioxide product purified and measured using ... of the pyrolysis and spark discharge experiments, b, Isotopic abundance of hydrocarbons from four geothermal localities as follows: D, Cerro Prieto, well M-5, sampled January 1979; ...

David J. Des Marais; Jason H. Donchin; Nancy L. Nehring; Alfred H. Truesdell

1981-08-27T23:59:59.000Z

204

Substantially self-powered method and apparatus for recovering hydrocarbons from hydrocarbon-containing solid hydrates  

DOE Patents [OSTI]

A method and apparatus are provided for producing gaseous hydrocarbons from formations comprising solid hydrocarbon hydrates located under either a body of land or a body of water. The vast natural resources of such hydrocarbon hydrates can thus now be economically mined. Relatively warm brine or water is brought down from an elevation above that of the hydrates through a portion of the apparatus, and passes in contact with the hydrates, thus melting them. The liquid then continues up another portion of the apparatus carrying entrained hydrocarbon vapors in the form of bubbles, which can easily be separated from the liquid. After a short startup procedure, the process and apparatus are substantially self-powered.

Elliott, G.R.B.; Barraclough, B.L.; Vanderborgh, N.E.

1981-02-19T23:59:59.000Z

205

Apparatus for recovering gaseous hydrocarbons from hydrocarbon-containing solid hydrates  

DOE Patents [OSTI]

A method and apparatus are provided for producing gaseous hydrocarbons from formations comprising solid hydrocarbon hydrates located under either a body of land or a body of water. The vast natural resources of such hydrocarbon hydrates can thus now be economically mined. Relatively warm brine or water is brought down from an elevation above that of the hydrates through a portion of the apparatus and passes in contact with the hydrates, thus melting them. The liquid then continues up another portion of the apparatus, carrying entrained hydrocarbon vapors in the form of bubbles, which can easily be separated from the liquid. After a short startup procedure, the process and apparatus are substantially self-powered.

Elliott, Guy R. B. (Los Alamos, NM); Barraclough, Bruce L. (Santa Fe, NM); Vanderborgh, Nicholas E. (Los Alamos, NM)

1984-01-01T23:59:59.000Z

206

Substantially self-powered method and apparatus for recovering hydrocarbons from hydrocarbon-containing solid hydrates  

DOE Patents [OSTI]

A method and apparatus are provided for producing gaseous hydrocarbons from formations comprising solid hydrocarbon hydrates located under either a body of land or a body of water. The vast natural resources of such hydrocarbon hydrates can thus now be economically mined. Relatively warm brine or water is brought down from an elevation above that of the hydrates through a portion of the apparatus and passes in contact with the hydrates, thus melting them. The liquid then continues up another portion of the apparatus, carrying entrained hydrocarbon vapors in the form of bubbles, which can easily be separated from the liquid. After a short startup procedure, the process and apparatus are substantially self-powered.

Elliott, Guy R. B. (Los Alamos, NM); Barraclough, Bruce L. (Santa Fe, NM); Vanderborgh, Nicholas E. (Los Alamos, NM)

1983-01-01T23:59:59.000Z

207

Nonlinear dependence of the solubility of water in hydrocarbons on the molar volume of the hydrocarbon  

Science Journals Connector (OSTI)

The solubility of water in fifty hydrocarbon solvents at 20°C is estimated by ... in nonspecific cohesion forces, and assuming that water is primarily monomeric in solution, the prediction ... breaking of the H-b...

Paul Ruelle; Ulrich W. Kesselring

1996-07-01T23:59:59.000Z

208

Mass Transfer of Polynuclear Aromatic Hydrocarbons from  

E-Print Network [OSTI]

of the individual components of four synthetic dense non-aqueous phase liquid (DNAPL) mixtures into the aqueous hydrocarbons (PAHs), were designed to serve as models for coal tars and creosotes. The reactor employed (PAHs) are often present in the environment as components of such dense non- aqueous phase liquids

Peters, Catherine A.

209

Vacancies in ordered and disordered titanium monoxide: Mechanism of B1 structure stabilization  

SciTech Connect (OSTI)

The electronic structure and stability of three phases of titanium monoxide TiO{sub y} with B1 type of the basic structure have been studied. Cubic phase without structural vacancies, TiO, and two phases with structural vacancies, monoclinic Ti{sub 5}O{sub 5} and cubic disordered TiO{sub 1.0}, was treated by means of first-principles calculations within the density functional theory with pseudo-potential approach based on the plane wave's basis. The ordered monoclinic phase Ti{sub 5}O{sub 5} was found to be the most stable and the cubic TiO without vacancies the less stable one. The role of structural vacancies in the titanium sublattice is to decrease the Fermi energy, the role of vacancies in the oxygen sublattice is to contribute to the appearance of Ti–Ti bonding interactions through these vacancies and to reinforce the Ti–Ti interactions close to them. Listed effects are significantly pronounced if the vacancies in the titanium and oxygen sublattices are associated in the so called “vacancy channels” which determine the formation of vacancy ordered structure of monoclinic Ti{sub 5}O{sub 5}-type. - Graphical abstract: Changes in total DOS of titanium monoxide when going from vacancy-free TiO to TiO with disordered structural vacancies and to TiO with ordered structural vacancies. Highlights: • Ordered monoclinic Ti{sub 5}O{sub 5} is the most stable phase of titanium monoxide. • Vacancy-free TiO is the less stable phase of the titanium monoxide. • Ordering of oxygen vacancies leads to the appearance of Ti–Ti bonding interactions. • Titanium vacancies contribute significantly to the decreasing of the Fermi energy.

Kostenko, M.G. [Institute of Solid State Chemistry, The Ural Branch of the Russian Academy of Sciences, Pervomayskaya 91, Ekaterinburg 620990 (Russian Federation); Lukoyanov, A.V. [Institute of Metal Physics, The Ural Branch of the Russian Academy of Sciences, S. Kovalevskoy 18, Ekaterinburg 620990 (Russian Federation); Ural Federal University named after First President of Russia B.N. Yeltsin, Mira 19, Ekaterinburg 620002 (Russian Federation); Zhukov, V.P. [Institute of Solid State Chemistry, The Ural Branch of the Russian Academy of Sciences, Pervomayskaya 91, Ekaterinburg 620990 (Russian Federation); Rempel, A.A., E-mail: rempel@ihim.uran.ru [Institute of Solid State Chemistry, The Ural Branch of the Russian Academy of Sciences, Pervomayskaya 91, Ekaterinburg 620990 (Russian Federation); Ural Federal University named after First President of Russia B.N. Yeltsin, Mira 19, Ekaterinburg 620002 (Russian Federation)

2013-08-15T23:59:59.000Z

210

Caenorhabditis elegans orthologs of the aryl hydrocarbon receptor and its heterodimerization partner the aryl hydrocarbon receptor nuclear translocator  

Science Journals Connector (OSTI)

...WI 53706 The aryl hydrocarbon receptor (AHR) is...The mammalian aryl hydrocarbon receptor (AHR) is...complex with the 90-kDa heat shock protein (HSP90) and...polycyclic aromatic hydrocarbons such as {beta...cigarette smoking and other combustion processes, initiate...

Jo Anne Powell-Coffman; Christopher A. Bradfield; William B. Wood

1998-01-01T23:59:59.000Z

211

Caenorhabditis elegans orthologs of the aryl hydrocarbon receptor and its heterodimerization partner the aryl hydrocarbon receptor nuclear translocator  

Science Journals Connector (OSTI)

...mammalian aryl hydrocarbon receptor...the 90-kDa heat shock protein (HSP90...polycyclic aromatic hydrocarbons such as {beta...smoking and other combustion processes...we searched data from the...Helminth HSP90 Heat-Shock Proteins...Molecular Sequence Data Protein Binding...Receptors, Aryl Hydrocarbon genetics metabolism...

Jo Anne Powell-Coffman; Christopher A. Bradfield; William B. Wood

1998-01-01T23:59:59.000Z

212

Hydrocarbon composition of crude oils near the Caspian depression  

SciTech Connect (OSTI)

The structural-group composition of hydrocarbons of Mesozoic crude oils near the Caspian depression was investigated by mass-spectrometry, followed by the analysis of the mass-spectra using a computer. The distribution of naphthenic hydrocarbons, according to the number of rings and of aromatic hydrocarbons, according to the degree of hydrogen unsaturation is similar for all the crude oils examined. The hydrocarbon composition of Mesozoic crude oils is characterized by a reduction in the content of aliphatic hydrocarbons and alkyl benzenes.

Botneva, T.A.; Khramova, E.V.; Nekhamkina, L.G.; Polyakova, A.A.

1983-01-01T23:59:59.000Z

213

Composition of paraffinic and naphthenic hydrocarbons in petroleum asphalts  

SciTech Connect (OSTI)

Uses a combination of chromatographic, chemical, and spectroscopic methods to determine the composition of the paraffinic and naphthenic hydrocarbons recovered from asphalts. Monitors the completeness of separation of the hydrocarbons from the aromatics on the basis of UV spectra. Finds that in the mixture of adduct-forming hydrocarbons, along with the n-paraffins there were admixtures of isoparaffins and longchain alkylnaphthenes. Concludes that a comparison of the structural-group composition of the asphalt fractions from the different crudes shows that there are only slight differences in the structure of the paraffinic/naphthenic hydrocarbons present in these asphalts, particularly with regard to those hydrocarbons that do not react with urea.

Botvin'eva, A.M.; Dubkova, R.V.; Shkredova, N.A.

1982-11-01T23:59:59.000Z

214

Plasma-assisted conversion of solid hydrocarbon to diamond  

DOE Patents [OSTI]

A process of preparing diamond, e.g., diamond fiber, by subjecting a hydrocarbon material, e.g., a hydrocarbon fiber, to a plasma treatment in a gaseous feedstream for a sufficient period of time to form diamond, e.g., a diamond fiber is disclosed. The method generally further involves pretreating the hydrocarbon material prior to treatment with the plasma by heating within an oxygen-containing atmosphere at temperatures sufficient to increase crosslinking within said hydrocarbon material, but at temperatures insufficient to melt or decompose said hydrocarbon material, followed by heating at temperatures sufficient to promote outgassing of said crosslinked hydrocarbon material, but at temperatures insufficient to convert said hydrocarbon material to carbon.

Valone, Steven M. (Santa Fe, NM); Pattillo, Stevan G. (Los Alamos, NM); Trkula, Mitchell (Los Alamos, NM); Coates, Don M. (Santa Fe, NM); Shah, S. Ismat (Wilmington, DE)

1996-01-01T23:59:59.000Z

215

Hydrous pyrolysis/oxidation process for in situ destruction of chlorinated hydrocarbon and fuel hydrocarbon contaminants in water and soil  

DOE Patents [OSTI]

In situ hydrous pyrolysis/oxidation process is useful for in situ degradation of hydrocarbon water and soil contaminants. Fuel hydrocarbons, chlorinated hydrocarbons, polycyclic aromatic hydrocarbons, petroleum distillates and other organic contaminants present in the soil and water are degraded by the process involving hydrous pyrolysis/oxidation into non-toxic products of the degradation. The process uses heat which is distributed through soils and water, optionally combined with oxygen and/or hydrocarbon degradation catalysts, and is particularly useful for remediation of solvent, fuel or other industrially contaminated sites.

Knauss, Kevin G. (Livermore, CA); Copenhaver, Sally C. (Livermore, CA); Aines, Roger D. (Livermore, CA)

2000-01-01T23:59:59.000Z

216

HYDROCARBONS FROM PLANTS: ANALYTICAL METHODS AND OBSERVATIONS  

SciTech Connect (OSTI)

We have suggested that certain plants rich in hydrocarbon-like materials might be cultivated for renewable photosynthetic products. Two species were selected for experimental plantations: Euphorbia lathyris, an annual from seed and Euphorbia tirucalli, a perennial from cuttings, The yield from each species is over 10 barrels of oil/acre/year without genetic or agronomic improvement. In addition to plants, there are trees, such as species of Copaifera in Brazil and other tropical areas, which produce a diesel-like oil upon tapping. Each tree produces approximately 40 liters of hydrocarbon per year, and this material can be used directly by a diesel-powered car. Further efforts to develop plants as alternate energy sources are underway, as well as a continuing search for additional plant species throughout the world which have a similar capability.

Calvin, Melvin

1980-05-01T23:59:59.000Z

217

Oxidative dehydrogenation of alkanes to unsaturated hydrocarbons  

DOE Patents [OSTI]

Oxidative dehydrogenation of alkanes to unsaturated hydrocarbons is carried out over metal vanadate catalysts under oxidizing conditions. The vanadate catalysts are represented by the formulas M[sub 3](VO[sub 4])[sub 2] and MV[sub 2]O[sub 6], M representing Mg, Zn, Ca, Pb, or Cd. The reaction is carried out in the presence of oxygen, but the formation of oxygenate by-products is suppressed.

Kung, H.H.; Chaar, M.A.

1988-10-11T23:59:59.000Z

218

Getter pump for hydrogen and hydrocarbon gases  

DOE Patents [OSTI]

A gettering device for hydrogen isotopes and gaseous hydrocarbons based on the interaction of a plasma and graphite used as cathodic material. The plasma is maintained at a current density within the range of about 1 to about 1000 mA/cm/sup 2/. The graphite may be heated to a temperature greater than 1000/degree/C. The new device offers high capacity, low noise, and gas species selectivity. 2 figs.

Hsu, Wen Ling

1987-10-14T23:59:59.000Z

219

Method of making a catalytic metal oxide selective for the conversion of a gas and a coating system for the selective oxidation of hydrocarbons and carbon monoxide  

SciTech Connect (OSTI)

A method is described of making a catalytic metal oxide selective to catalyzing the conversion of given gas species, comprising: intimately supporting a solid film of catalytic metal oxide on an electrically conducting material, said film having an exposed outer surface spaced no greater than 1,000 angstroms from said conducting material and said conducting material being matched to the composition of said oxide to change the electron state of the exposed outer surface to promote a reaction between given gas species and said oxide, said metal oxide being selected from the group consisting of TiO[sub 2], SnO[sub 2], FeO, SrTiO[sub 3], and CoO, and said conducting material being selected from the group consisting of Au, Pt, TiN, Pd, Rh, Ni, and Co.

Logothetis, E.M.; Soltis, R.E.

1993-07-20T23:59:59.000Z

220

ZIRCONIA-BASED MIXED POTENTIAL CARBON MONOXIDE/HYDROCARBON SENSORS WITH LANTHANUM MAGNESIUM OXIDE, AND TERBIUM-DOPED YTTRIUM STABILIZED ZIRCONIA ELECTRODES  

SciTech Connect (OSTI)

We have investigated the performance of dual metal oxide electrode mixed potential sensors in an engine-out, dynamometer environment. Sensors were fabricated by sputtering thin films of LaMnO{sub 3} and Tb-doped YSZ onto YSZ electrolyte. Au gauze held onto the metal oxide thin films with Au ink was used for current collection. The exhaust gas from a 4.8L, V8 engine operated in open loop, steady-state mode around stoichiometry at 1500 RPM and 50 Nm. The sensor showed a stable EMF response (with no hysteresis) to varying concentrations of total exhaust gas HC content. The sensor response was measured at 620 and 670 C and shows temperature behavior characteristic of mixed potential-type sensors. The results of these engine-dynamometer tests are encouraging; however, the limitations associated with Au current collection present the biggest impediment to automotive use.

E. L. BROSHA; R. MUKUNDAN; ET AL

2000-10-01T23:59:59.000Z

Note: This page contains sample records for the topic "monoxide hydrocarbons odors" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Phase Behavior of Light Gases in Hydrocarbon and Aqueous Solvents  

SciTech Connect (OSTI)

Under previous support from the Department of Energy, an experimental facility has been established and operated to measure valuable vapor-liquid equilibrium data for systems of interest in the production and processing of coal fluids. To facilitate the development and testing of models for prediction of the phase behavior for such systems, we have acquired substantial amounts of data on the equilibrium phase compositions for binary mixtures of heavy hydrocarbon solvents with a variety of supercritical solutes, including hydrogen, methane, ethane, carbon monoxide, and carbon dioxide. The present project focuses on measuring the phase behavior of light gases and water in Fischer-Tropsch (F-T) type solvents at conditions encountered in indirect liquefaction processes and evaluating and developing theoretically-based correlating frameworks to predict the phase behavior of such systems. Specific goals of the proposed work include (a) developing a state-of-the-art experimental facility to permit highly accurate measurements of equilibrium phase compositions (solubilities) of challenging F-T systems, (b) measuring these properties for systematically-selected binary, ternary and molten F-T wax mixtures to provide critically needed input data for correlation development, (c) developing and testing models suitable for describing the phase behavior of such mixtures, and (d) presenting the modeling results in generalized, practical formats suitable for use in process engineering calculations. During the present reporting period, our solubility apparatus was refurbished and restored to full service. To test the experimental apparatus and procedures used, measurements were obtained for the solubility Of C0{sub 2} in benzene at 160{degrees}F. Having confirmed the accuracy of the newly acquired data in comparison with our previous measurements and data reported in the literature for this test system, we have begun to measure the solubility of hydrogen in hexane. The measurements for this system will cover the temperature range from 160 to 280{degrees}F at pressures to 2,500 psia. As part of our model evaluation efforts, we examined the predictive abilities of an alternative approach we have proposed for calculating the phase behavior properties of highly non-ideal systems. Using this approach, the liquid phase fugacities generated from an equation of state (EOS) are augmented by a fugacity deviation function correction. The correlative abilities of this approach are compared with those of an EOS equipped with the recently introduced Wong-Sandler (MWS) mixing rules. These two approaches are compared with the current methods for vapor-liquid equilibrium (VLE) calculations, i.e., the EOS (0/0) approach with the van der Waals mixing rules and the split (y/0) approach. The evaluations were conducted on a database comprised of non-ideal low pressure binary systems as well as asymmetric high pressure binary systems. These systems are of interest in the coal liquefaction and utilization processes. The Peng-Robinson EOS was selected for the purposes of this evaluation.

Gasem, K.A.M.; Robinson, R.L., Jr.; Trvedi, N.J., Gao, W.

1997-09-01T23:59:59.000Z

222

Methods of Reforming Hydrocarbon Fuels Using Hexaaluminate Catalysts  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of Reforming Hydrocarbon Fuels Using of Reforming Hydrocarbon Fuels Using Hexaaluminate Catalysts Contact NETL Technology Transfer Group techtransfer@netl.doe.gov May 2012 Opportunity Research is currently active on the technology "Methods of Reforming Hydrocarbon Fuels Using Hexaaluminate Catalysts." The technology is available for licensing and/or further collaborative research from the U.S. Department of Energy's National Energy Technology Laboratory. Overview This invention discloses a method to reform hydrocarbon fuels using hexa- aluminate catalysts. In general, the method successfully disrupts the forma- tion of carbon that leads to the deactivation of the catalyst, a key element in the reforming of hydrocarbon fuels. When researchers are designing catalysts to reform hydrocarbon fuels, one

223

Catalytic Upgrading of Sugars to Hydrocarbons Technology Pathway  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Fractionation Hydrogen Acid, Caustic, Enzymes Wastewater Treatment Insoluble solids Biogas + Sludge Process Heat and Power Integration Corn Stover Hydrocarbon Biofuels (i.e....

224

Biological Conversion of Sugars to Hydrocarbons Technology Pathway...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

case investigates the biological conversion of biomass-derived sugars to hydrocarbon biofuels, utilizing data from recent literature references and information consistent with...

225

CSIA of Petroleum Hydrocarbons: Forensic Fingerprinting and Oil Spill Characterisation.  

E-Print Network [OSTI]

??This thesis has identified a suite of hydrocarbon diagnostic indices to be applied in the forensic fingerprinting of diesel oil characterisation and source identification using… (more)

Muhammad, Syahidah Akmal binti

2012-01-01T23:59:59.000Z

226

The mobility of petroleum hydrocarbons in Athabasca oil sands tailings.  

E-Print Network [OSTI]

??Several oil sands tailings from Suncor Energy Inc. were analysed with respect to the mobility and solubility of the petroleum hydrocarbon (PHC) contaminants. At sites… (more)

Brickner, Heather

2014-01-01T23:59:59.000Z

227

Process for making unsaturated hydrocarbons using microchannel process technology  

DOE Patents [OSTI]

The disclosed invention relates to a process for converting a feed composition comprising one or more hydrocarbons to a product comprising one or more unsaturated hydrocarbons, the process comprising: flowing the feed composition and steam in contact with each other in a microchannel reactor at a temperature in the range from about 200.degree. C. to about 1200.degree. C. to convert the feed composition to the product, the process being characterized by the absence of catalyst for converting the one or more hydrocarbons to one or more unsaturated hydrocarbons. Hydrogen and/or oxygen may be combined with the feed composition and steam.

Tonkovich, Anna Lee (Dublin, OH); Yuschak, Thomas (Lewis Center, OH); LaPlante, Timothy J. (Columbus, OH); Rankin, Scott (Columbus, OH); Perry, Steven T. (Galloway, OH); Fitzgerald, Sean Patrick (Columbus, OH); Simmons, Wayne W. (Dublin, OH); Mazanec, Terry (Solon, OH) Daymo, Eric (Dublin, OH)

2011-04-12T23:59:59.000Z

228

Carbonaceous adsorbent regeneration and halocarbon displacement by hydrocarbon gases  

DOE Patents [OSTI]

This invention describes a process for regeneration of halocarbon bearing carbonaceous adsorbents through which a carbonaceous adsorbent is contacted with hydrocarbon gases, preferably propane, butane and pentane at near room temperatures and at atmospheric pressure. As the hydrocarbon gases come in contact with the adsorbent, the hydrocarbons displace the halocarbons by physical adsorption. As a result of using this process, the halocarbon concentration and the hydrocarbon eluant is increased thereby allowing for an easier recovery of pure halocarbons. By using the process of this invention, carbonaceous adsorbents can be regenerated by an inexpensive process which also allows for subsequent re-use of the recovered halocarbons. 8 figures.

Senum, G.I.; Dietz, R.N.

1994-04-05T23:59:59.000Z

229

Carbonaceous adsorbent regeneration and halocarbon displacement by hydrocarbon gases  

DOE Patents [OSTI]

This invention describes a process for regeneration of halocarbon bearing carbonaceous adsorbents through which a carbonaceous adsorbent is contacted with hydrocarbon gases, preferably propane, butane and pentane at near room temperatures and at atmospheric pressure. As the hydrocarbon gases come in contact with the adsorbent, the hydrocarbons displace the halocarbons by physical adsorption. As a result of using this process, the halocarbon concentration and the hydrocarbon eluant is increased thereby allowing for an easier recovery of pure halocarbons. By using the process of this invention, carbonaceous adsorbents can be regenerated by an inexpensive process which also allows for subsequent re-use of the recovered halocarbons.

Senum, Gunnar I. (Patchogue, NY); Dietz, Russell N. (Patchogue, NY)

1994-01-01T23:59:59.000Z

230

Selective aerobic oxidation of hydrocarbons over supported gold catalysts.  

E-Print Network [OSTI]

??The selective oxidation of hydrocarbons is of vital importance for the production of valuable chemicals from crude oil and natural gas resources. Unfortunately, when using… (more)

Hereijgers, B.P.C.

2011-01-01T23:59:59.000Z

231

Catalytic Upgrading of Sugars to Hydrocarbons Technology Pathway...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

the catalytic conversion of solubilized carbohydrate streams to hydrocarbon biofuels, utilizing data from recent efforts within the National Advanced Biofuels Consortium...

232

Mechanisms of Hydrocarbon Poisoning of A Urea SCR Catalyst  

Broader source: Energy.gov [DOE]

Understanding what reactions and which catalytic functions are affected by hydrocarbons can lead to improved tolerances for selective catalytic reduction performance

233

Electrical dispersion of water drops suspended in hydrocarbons  

Science Journals Connector (OSTI)

The effects of alternating (50 Hz) and direct current fields on drops of distilled water in a nonpolar hydrocarbon medium were examined.

G. M. Panchenkov; V. V. Papko; V. Ya. Baranov

1968-10-01T23:59:59.000Z

234

Systems and methods for producing hydrocarbons from tar sands formations  

DOE Patents [OSTI]

A system for treating a tar sands formation is disclosed. A plurality of heaters are located in the formation. The heaters include at least partially horizontal heating sections at least partially in a hydrocarbon layer of the formation. The heating sections are at least partially arranged in a pattern in the hydrocarbon layer. The heaters are configured to provide heat to the hydrocarbon layer. The provided heat creates a plurality of drainage paths for mobilized fluids. At least two of the drainage paths converge. A production well is located to collect and produce mobilized fluids from at least one of the converged drainage paths in the hydrocarbon layer.

Li, Ruijian (Katy, TX); Karanikas, John Michael (Houston, TX)

2009-07-21T23:59:59.000Z

235

Ultraviolet photoelectron spectroscopic study of the interaction of potassium with carbon monoxide and benzene on the Pt(111) surface  

SciTech Connect (OSTI)

The interaction of potassium with carbon monoxide and benezene has been studied on the Pt(111) crystal surface by ultraviolet photoelectron spectroscopy (UPS). The adsorptive changes reported in previous studies for carbon monoxide and benzene when potassium is coadsorbed are correlated with the UPS results presented here and are explained with the aid of a molecular orbital analysis. The authors find that the valence molecular orbitals increase their binding energy slightly when the potassium is coadsorbed, implying a model in which the adsorbates sense the potassium-induced changes in dipole field at the surface. 36 references, 11 figures.

Kudo, M.; Garfunkel, E.L.; Somorjai, G.A.

1985-07-18T23:59:59.000Z

236

Observation of two-dimensional compositional ordering of a carbon monoxide and argon monolayer mixture physisorbed on graphite  

SciTech Connect (OSTI)

Commensurate monolayers of a mixture of 70% carbon monoxide and 30% argon on graphite are studied by neutron and low-energy-electron diffraction. A 2 x 2 superstructure due to 3:1 compositional ordering is observed below 25 K. The compositional ordering is most likely due to molecular-axis ordering of carbon monoxide molecules into a pinwheel pattern with argon atoms at the central sites of each pinwheel. Such a pinwheel structure has been predicted by Harris, Mouritsen, and Berlinsky for planar rotors with anisotropic interactions on a triangular lattice with vacancies.

You, H.; Fain, S.C. Jr.; Satija, S.; Passell, L.

1986-01-20T23:59:59.000Z

237

Optimizing hydrocarbon recoveries in nitrogen rejection units  

SciTech Connect (OSTI)

In order to address conceptual questions such as process selection and natural gas liquids plant integration, an understanding of the effects of several additional factors on nitrogen rejection unit design is important. These factors, which may influence optimum hydrocarbon recovery, installed compression, etc., include current and forecast values for natural gas and utilities, project life, plant size, feed gas composition and product specifications, feed pressure, and process variations. Prices, project life, and plant size are analyzed in detail and presented in terms of methane recoveries as a function of nitrogen content in the feed for both double and single column processes. Trends are qualitatively discussed for the remaining factors. 13 references.

Chesney, J.D.; Davis, R.A.; Hilton, M.F.; Vines, H.L.

1983-01-01T23:59:59.000Z

238

Adsorption and desorption of hydrogen and carbon monoxide were studied on alumina-supported iridium catalysts  

SciTech Connect (OSTI)

The adsorption and desorption of hydrogen and carbon monoxide were studied on alumina-supported iridium catalysts which were examined by a scanning transmission electron microscope (STEM). The metal particle size and number of particles per area of catalyst increased with increasing metal loading. The particles were approx. 10 A. in diameter, cubo-octahedral shaped, and approx. 80-90% disperse. The STEM electron beam caused negligible damage to the samples. Hydrogen adsorption measurements showed that the hydrogen-iridium atom ratio was 1.2:1-1.3:1 and increased with decreasing metal loading. Temperature-programed desorption showed four types of adsorbed hydrogen desorbing at -90/sup 0/C (I), 15/sup 0/C (IV), 115/sup 0/C (II), and 245/sup 0/C (III). Types II and IV desorb from single atom sites and Types I and III from multiple atom sites. Type I is in rapid equilibrium with the gas phase. All desorption processes appear to be first order. Carbon monoxide adsorbed nondissociatively at 25/sup 0/C with approx. 0.7:1 CO/Ir atom ratio. It adsorbed primarily in linear forms at low coverage, but a bridged form appeared at high coverage.

Etherton, B.P.

1980-01-01T23:59:59.000Z

239

Preliminary Geospatial Analysis of Arctic Ocean Hydrocarbon Resources  

SciTech Connect (OSTI)

Ice coverage of the Arctic Ocean is predicted to become thinner and to cover less area with time. The combination of more ice-free waters for exploration and navigation, along with increasing demand for hydrocarbons and improvements in technologies for the discovery and exploitation of new hydrocarbon resources have focused attention on the hydrocarbon potential of the Arctic Basin and its margins. The purpose of this document is to 1) summarize results of a review of published hydrocarbon resources in the Arctic, including both conventional oil and gas and methane hydrates and 2) develop a set of digital maps of the hydrocarbon potential of the Arctic Ocean. These maps can be combined with predictions of ice-free areas to enable estimates of the likely regions and sequence of hydrocarbon production development in the Arctic. In this report, conventional oil and gas resources are explicitly linked with potential gas hydrate resources. This has not been attempted previously and is particularly powerful as the likelihood of gas production from marine gas hydrates increases. Available or planned infrastructure, such as pipelines, combined with the geospatial distribution of hydrocarbons is a very strong determinant of the temporal-spatial development of Arctic hydrocarbon resources. Significant unknowns decrease the certainty of predictions for development of hydrocarbon resources. These include: 1) Areas in the Russian Arctic that are poorly mapped, 2) Disputed ownership: primarily the Lomonosov Ridge, 3) Lack of detailed information on gas hydrate distribution, and 4) Technical risk associated with the ability to extract methane gas from gas hydrates. Logistics may control areas of exploration more than hydrocarbon potential. Accessibility, established ownership, and leasing of exploration blocks may trump quality of source rock, reservoir, and size of target. With this in mind, the main areas that are likely to be explored first are the Bering Strait and Chukchi Sea, in spite of the fact that these areas do not have highest potential for future hydrocarbon reserves. Opportunities for improving the mapping and assessment of Arctic hydrocarbon resources include: 1) Refining hydrocarbon potential on a basin-by-basin basis, 2) Developing more realistic and detailed distribution of gas hydrate, and 3) Assessing the likely future scenarios for development of infrastructure and their interaction with hydrocarbon potential. It would also be useful to develop a more sophisticated approach to merging conventional and gas hydrate resource potential that considers the technical uncertainty associated with exploitation of gas hydrate resources. Taken together, additional work in these areas could significantly improve our understanding of the exploitation of Arctic hydrocarbons as ice-free areas increase in the future.

Long, Philip E.; Wurstner, Signe K.; Sullivan, E. C.; Schaef, Herbert T.; Bradley, Donald J.

2008-10-01T23:59:59.000Z

240

Mutagenicity of Soot and Associated Polycyclic Aromatic Hydrocarbons to Salmonella typhimurium  

Science Journals Connector (OSTI)

...polycyclic aromatic hydrocarbons were quantitatively...polycyclic aromatic hydrocarbon constituent in a kerosene...polycyclic aromatic hydrocarbon fraction in terms of...formed by the incomplete combustion of organic material...and sediments (1), heat and power generation...

Debra A. Kaden; Ronald A. Hites; and William G. Thilly

1979-10-01T23:59:59.000Z

Note: This page contains sample records for the topic "monoxide hydrocarbons odors" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

E-Print Network 3.0 - aromatic hydrocarbon investigation Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

various hydrocarbons on monolithic hydrocarbon adsorber Dae Jung Kim,a Ji Man Kim,a Jae Eui Yie... and conversion of various hydrocarbons on ... Source: Kim, Ji Man - Department...

242

E-Print Network 3.0 - aromatic hydrocarbons investigated Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

various hydrocarbons on monolithic hydrocarbon adsorber Dae Jung Kim,a Ji Man Kim,a Jae Eui Yie... and conversion of various hydrocarbons on ... Source: Kim, Ji Man - Department...

243

E-Print Network 3.0 - aromatic hydrocarbon components Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

various hydrocarbons on monolithic hydrocarbon adsorber Dae Jung Kim,a Ji Man Kim,a Jae Eui Yie... and conversion of various hydrocarbons on ... Source: Kim, Ji Man - Department...

244

E-Print Network 3.0 - aromatic hydrocarbon molecules Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

various hydrocarbons on monolithic hydrocarbon adsorber Dae Jung Kim,a Ji Man Kim,a Jae Eui Yie... and conversion of various hydrocarbons on monolithic ... Source: Kim, Ji Man -...

245

E-Print Network 3.0 - aromatic hydrocarbons molecules Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

various hydrocarbons on monolithic hydrocarbon adsorber Dae Jung Kim,a Ji Man Kim,a Jae Eui Yie... and conversion of various hydrocarbons on monolithic ... Source: Kim, Ji Man -...

246

E-Print Network 3.0 - aromatic hydrocarbons resulting Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

various hydrocarbons on monolithic hydrocarbon adsorber Dae Jung Kim,a Ji Man Kim,a Jae Eui Yie... and conversion of various hydrocarbons on monolithic ... Source: Kim, Ji Man -...

247

The Fate of Fossil Fuel Hydrocarbons in Marine Animals [and Discussion  

Science Journals Connector (OSTI)

...research-article The Fate of Fossil Fuel Hydrocarbons in Marine Animals [and Discussion...mammals. The fate of fossil fuel hydrocarbons in marine animals. | Journal Article...Carcinogens 0 Epoxy Compounds 0 Fuel Oils 0 Hydrocarbons 0 Naphthalenes...

1975-01-01T23:59:59.000Z

248

Ozonation of Mutagenic and Carcinogenic Polyaromatic Amines and Polyaromatic Hydrocarbons in Water  

Science Journals Connector (OSTI)

...Amines and Polyaromatic Hydrocarbons in Water 1 1 Supported by a grant...amines and polyaromatic hydrocarbons in water. | The Salmonella-microsome...g., 13 halogenated hydrocarbons were identified in the drinking water of New Orleans (13...

Gary R. Burleson; Michael J. Caulfield; and Morris Pollard

1979-06-01T23:59:59.000Z

249

Determination of hydrocarbons in water – interlaboratory method validation before routine monitoring  

Science Journals Connector (OSTI)

The clarification of hydrocarbon input into the Baltic sea via rivers ... of a new method for the determination of hydrocarbons by solvent extraction and gas chromatography. Surrogate oil solutions with known hydrocarbon

P. Woitke; Reinhard Kreßner; Peter Lepom

2001-04-01T23:59:59.000Z

250

Process for using preferential physical solvents for selective processing of hydrocarbon gas streams  

SciTech Connect (OSTI)

This patent describes a process for the removal of hydrocarbon gas liquids, comprising hydrocarbons heavier than methane, from a hydrocarbon gas stream, wherein a need exists for recovering to any selected degree and at extremely high recoveries a selected hydrocarbon component and heavier hydrocarbons. The hydrocarbons are within the group consisting of ethane, propane, butane, and pentane without the need simultaneously to recover hydrocarbons lighter than the selected hydrocarbon component from the hydrocarbon gas stream, The improvement of selectively extracting the hydrocarbon gas liquids from the hydrocarbon gas stream with a preferential physical solvent is described here. The method provides selective capability for recovery according to the selected degree of (a) ethane in amounts ranging from 2-98%, (b) propane in amounts ranging from 2-99%, (c) butane in amounts ranging from 2-100%, or (d) pentanes and higher molecular weight hydrocarbons in amounts ranging up to 100%.

Mehra, Y.R.

1986-10-14T23:59:59.000Z

251

Some general laws of the hydrogenation of carbon monoxide on metals  

SciTech Connect (OSTI)

The catalytic properties of supported transition metals in the hydrogenation of CO to hydrocarbons have been studied. A kinetic model interpreting the unusual dependence of the activation energy on temperature is proposed. It is shown that the catalytic activity (r) decreases and the selectivity with respect to methane (SCH/sub 4/) increases with an increase in the heat of adsorption of CO.

Golodets, G.I.; Pavlenko, N.V.; Tripol'skii, A.I.

1988-01-01T23:59:59.000Z

252

Homologation and functionalization of carbon monoxide by a recyclable uranium complex  

Science Journals Connector (OSTI)

...C-5b (R = Ph) were confirmed by CHN combustion analyses, FTIR spectroscopy, and the...SiOCCOSiPh 3 , and 4 to estimate the heats of formation ({delta}H for ) for...resource from which to produce industrial hydrocarbon feedstocks as alternatives to crude oil...

Benedict M. Gardner; John C. Stewart; Adrienne L. Davis; Jonathan McMaster; William Lewis; Alexander J. Blake; Stephen T. Liddle

2012-01-01T23:59:59.000Z

253

Hydrocarbon steam reforming using series steam superheaters  

SciTech Connect (OSTI)

In a process for steam reforming of a hydrocarbon gas feedstream wherein: the hydrocarbon gas feedstream is partially reformed at elevated temperatures in indirect heat exchange with hot combustion gases in a direct fired primary reforming furnace provided with a convection section for recovery of excess heat from said combustion gases; and the partially reformed feedstream is then further reformed in the presence of an oxygen-containing gas and steam in a secondary reformer to form a secondary reformer gaseous effluent; the improvement which comprises recovering waste heat from said secondary reformer effluent gas and from said primary reforming combustion products by heating a high pressure saturated steam in a first steam superheating zone by indirect heat exchange with at least a portion of said secondary reformer effluent gas to form a first superheated steam stream; and further heating said first superheated steam in a second steam superheating zone by indirect heat exchange with at least a portion of said primary reformer hot combustion gases for form a second superheated steam stream.

Osman, R. M.

1985-10-08T23:59:59.000Z

254

Algal Lipid Extraction and Upgrading to Hydrocarbons Technology Pathway  

Broader source: Energy.gov [DOE]

This technology pathway case investigates the cultivation of algal biomass followed by further lipid extraction and upgrading to hydrocarbon biofuels. Technical barriers and key research needs have been assessed in order for the algal lipid extraction and upgrading pathway to be competitive with petroleum-derived gasoline-, diesel-, and jet-range hydrocarbon blendstocks.

255

Scroll compressor modelling for heat pumps using hydrocarbons as refrigerants  

E-Print Network [OSTI]

1 Scroll compressor modelling for heat pumps using hydrocarbons as refrigerants Paul BYRNE and to install heat pumps in unoccupied spaces. Nevertheless manufacturers keep working on components for hydrocarbons. In the frame of a research project on heat pumps for simultaneous heating and cooling, an R407C

Paris-Sud XI, Université de

256

Contemplation on the heats of combustion of isomeric hydrocarbons  

Science Journals Connector (OSTI)

Within the Hückel molecular orbital theory, the heats of combustion of isomeric hydrocarbons are related to some topological factors. The standard heats of combustion values of alternant hydrocarbons, expressed as kcal/g, seem to be related to a4 coefficient of their secular polynomials.

Lemi Türker

2004-01-01T23:59:59.000Z

257

Formation mechanism for polycyclic aromatic hydrocarbons in methane flames  

E-Print Network [OSTI]

aromatic hydrocarbons PAHs up to 788 amu (C64H20) were detected in the combustion gases. Only the most applications including heating systems and gas turbines for electric power generation.62­64 The combustionFormation mechanism for polycyclic aromatic hydrocarbons in methane flames K. Siegmanna) Swiss

Sattler, Klaus

258

Biological Conversion of Sugars to Hydrocarbons Technology Pathway  

SciTech Connect (OSTI)

This technology pathway case investigates the biological conversion of biomass-derived sugars to hydrocarbon biofuels, utilizing data from recent literature references and information consistent with recent pilot-scale demonstrations at NREL. Technical barriers and key research needs have been identified that should be pursued for the pathway to become competitive with petroleum-derived gasoline-, diesel-, and jet-range hydrocarbon blendstocks.

Davis, R.; Biddy, M.; Tan, E.; Tao, L.; Jones, S.

2013-03-01T23:59:59.000Z

259

Biological Conversion of Sugars to Hydrocarbons Technology Pathway  

Broader source: Energy.gov [DOE]

This technology pathway case investigates the biological conversion of biomass-derived sugars to hydrocarbon biofuels, utilizing data from recent literature references and information consistent with recent pilot-scale demonstrations at NREL. Technical barriers and key research needs have been identified that should be pursued for the pathway to become competitive with petroleum-derived gasoline-, diesel-, and jet-range hydrocarbon blendstocks.

260

Selective thermal and photooxidation of hydrocarbons in zeolites by oxygen  

DOE Patents [OSTI]

A process is described for selective thermal oxidation or photooxidation of hydrocarbons adsorbed onto zeolite matrices. A highly selective thermal oxidation and photooxidation of unsubstituted or alkyl substituted alkanes, alkenes, aromatics and cycloalkyls in solvent free zeolites under dark thermal conditions or under irradiation with visible light. The process oxidizes hydrocarbons almost completely selectively without substantial production of byproducts. 19 figs.

Frei, H.; Blatter, F.; Sun, H.

1999-06-22T23:59:59.000Z

Note: This page contains sample records for the topic "monoxide hydrocarbons odors" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

High levels of carcinogenic polycyclic aromatic hydrocarbons in mate drinks  

Science Journals Connector (OSTI)

...carcinogenic polycyclic aromatic hydrocarbons in mate drinks Farin Kamangar...exposure to polycyclic aromatic hydrocarbons (PAHs), including known...80 oC) or cold (4 oC) water and two commonly used brands...Infusions were made by adding water to the leaves, steeping for...

Farin Kamangar; Michele Schantz; Christian Abnet; Renato Fagundes; and Sanford Dawsey

2008-05-01T23:59:59.000Z

262

Total Synthesis of Convex Polyhedral Hydrocarbons The Platonic Solids  

E-Print Network [OSTI]

O H H Total Synthesis of Convex Polyhedral Hydrocarbons The Platonic Solids O O t-BuO3C Br O O Br Br Ph PhPh Ph PhPh Ph Ph COOH HOOC Total Synthesis of Convex Polyhedral Hydrocarbons The Five Matter Icosahedron Water · Polyhedron: a closed surface made up of polygonal regions. · Regular

Stoltz, Brian M.

263

Microbial Degradation in Soil Microcosms of Fuel Oil Hydrocarbons from Drilling Cuttings  

Science Journals Connector (OSTI)

Microbial Degradation in Soil Microcosms of Fuel Oil Hydrocarbons from Drilling Cuttings ... Relation between Bioavailability and Fuel Oil Hydrocarbon Composition in Contaminated Soils ...

Claude-Henri. ChaIneau; Jean-Louis. Morel; Jean. Oudot

1995-06-01T23:59:59.000Z

264

E-Print Network 3.0 - aromatic hydrocarbons affect Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Sciences and Ecology 3 Quantification of Local Ozone Production Attributable to Automobile Hydrocarbon Emissions Summary: -fueled automobiles, most cyclic hydrocarbons are...

265

E-Print Network 3.0 - aromatic hydrocarbons annual Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Page: << < 1 2 3 4 5 > >> 1 Quantification of Local Ozone Production Attributable to Automobile Hydrocarbon Emissions Summary: releases about 5 billion kilograms of hydrocarbons...

266

E-Print Network 3.0 - aromatic hydrocarbons implications Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Page: << < 1 2 3 4 5 > >> 1 Quantification of Local Ozone Production Attributable to Automobile Hydrocarbon Emissions Summary: -fueled automobiles, most cyclic hydrocarbons are...

267

E-Print Network 3.0 - aromatic hydrocarbon exposure Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Aust. J. Mar. Freshw. Res., 1984, 35, 119-28 Aromatic Hydrocarbons in Waters of Port Phillip Bay... of aromatic hydrocarbons in coastal waters, using solvent extraction and...

268

E-Print Network 3.0 - aromatic hydrocarbon contamination Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: called aromatic hydrocarbons. These include harmful pollutants like dioxins, PCBs and a group called... polycyclic aromatic hydrocarbons (PAHs). PAHs are...

269

E-Print Network 3.0 - aromatic hydrocarbon receptor Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

aromatic hydrocarbons... the aryl hydrocarbon receptor (AHR), through which dioxins and dioxin-like compounds cause altered gene... -methylcholanthrene AHH: aryl...

270

E-Print Network 3.0 - aromatic hydrocarbons extracted Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of Toxic Contamination Summary: called aromatic hydrocarbons. These include harmful pollutants like dioxins, PCBs and a group called... polycyclic aromatic hydrocarbons (PAHs)....

271

E-Print Network 3.0 - aromatic hydrocarbon metabolism Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

hydrocarbon is introduced into the ocean via oil spillage, offshore drilling leaks, industrial... hydrocarbons have been attributed to inhibition of ... Source: National...

272

E-Print Network 3.0 - aromatic hydrocarbon-degrading bacteria...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

ydrocarbonDegradation It was hypothesized... aromatic hydrocarbon degradation. Hypothesis Test Result Groundwater stimulates Fe(lll) reduction Cell... Hydrocarbon Degradation At...

273

Chlorinated C$_{1}$ and C$_{2}$ Hydrocarbons in the Marine Environment [and Discussion  

Science Journals Connector (OSTI)

...the marine environment. | Journal Article | 0 Hydrocarbons, Chlorinated | Air Pollution analysis Animals Fresh Water Great Britain Hydrocarbons, Chlorinated analysis metabolism Seawater Water Pollution, Chemical analysis The Royal Society...

1975-01-01T23:59:59.000Z

274

A generalized viscosity equation for pure heavy hydrocarbons  

SciTech Connect (OSTI)

This paper presents a method for the correlation and prediction of the viscosity of pure heavy hydrocarbons listed in API Research Project 42. The 273 heavy hydrocarbons in the database include branched/unbranched paraffins and olefins together with a variety of complex nonfused/fused aromatic and naphthenic compounds. A generalized one-parameter viscosity-temperature equation, log ({mu} + 0.8) = 100(0.01T){sup b}, is proposed (overall AAD {lt} 7-10%) for all heavy hydrocarbons in the database. For each hydrocarbon, an optimum value of parameter b is provided. It is shown that parameter b varies linearly with the logarithm of molar mass as well as the inverse of boiling temperature (at 10 mmHg). This important observation leads to the development of a predictive method for the liquid-phase viscosity of pure heavy hydrocarbons.

Mehrotra, A.K. (Dept. of Chemical and Petroleum Engineering, Univ. of Calgary, Calgary, Alberta T2N 1N4 (CA))

1991-02-01T23:59:59.000Z

275

Bioremediation of soil contaminated with hydrocarbons and heavy metals  

SciTech Connect (OSTI)

This investigation showed that a soil contaminated with petroleum hydrocarbons and heavy metals had sufficient indigenous microbial activity for hydrocarbon biodegradation under nonlimiting conditions. Nutrient supplementation with nitrogen and phosphate, together with aeration, seemed to be the most important factors for enhancing biodegradation. Hydrocarbon biodegradation occurred to a much greater extent under aerobic than under anaerobic conditions. Biodegradation did, however, induce low pH conditions and thus caused high heavy-metal concentrations in the leachate. Anaerobic conditions inhibited hydrocarbon biodegradation with no subsequent drop in pH and low heavy-metal concentrations in the leachate. Thus, anaerobic conditions were shown to facilitate less metal mobility than low pH conditions. Air sparging did not cause a significant increase in biodegradation. Adsorption of heavy-fraction hydrocarbons (> C{sub 20}) to microorganisms and colloidal material in the leachate was suspected of facilitating mobility of these fractions and thus their subsequent detection in the leachate.

Plessis, C.A. du; Phaal, C.B.; Senior, E. [Univ. of Natal, Scottsville (South Africa)

1995-12-31T23:59:59.000Z

276

Cogeneration systems and processes for treating hydrocarbon containing formations  

DOE Patents [OSTI]

A system for treating a hydrocarbon containing formation includes a steam and electricity cogeneration facility. At least one injection well is located in a first portion of the formation. The injection well provides steam from the steam and electricity cogeneration facility to the first portion of the formation. At least one production well is located in the first portion of the formation. The production well in the first portion produces first hydrocarbons. At least one electrical heater is located in a second portion of the formation. At least one of the electrical heaters is powered by electricity from the steam and electricity cogeneration facility. At least one production well is located in the second portion of the formation. The production well in the second portion produces second hydrocarbons. The steam and electricity cogeneration facility uses the first hydrocarbons and/or the second hydrocarbons to generate electricity.

Vinegar, Harold J. (Bellaire, TX); Fowler, Thomas David (Houston, TX); Karanikas, John Michael (Houston, TX)

2009-12-29T23:59:59.000Z

277

Heating hydrocarbon containing formations in a line drive staged process  

DOE Patents [OSTI]

Method for treating a hydrocarbon containing formation are described herein. Methods may include providing heat to a first section of the formation with one or more first heaters in the first section. First hydrocarbons may be heated in the first section such that at least some of the first hydrocarbons are mobilized. At least some of the mobilized first hydrocarbons may be produced through a production well located in a second section of the formation. The second section may be located substantially adjacent to the first section. A portion of the second section may be provided some heat from the mobilized first hydrocarbons, but is not conductively heated by heat from the first heaters. Heat may be provided to the second section with one or more second heaters in the second section to further heat the second section.

Miller, David Scott (Katy, TX)

2009-07-21T23:59:59.000Z

278

Design and Development of a Mid-Infrared Carbon Monoxide Sensor for a High-Pressure Combustor Rig  

E-Print Network [OSTI]

A sensor for carbon monoxide measurement has been developed using a mid-infrared quantum-cascade (QC) laser operating in the fundamental band (?v= 1) of CO near 4.5 ?m. The fundamental band was chosen due to its stronger absorption line...

Camou, Alejandro

2014-05-03T23:59:59.000Z

279

Analysis of black carbon and carbon monoxide observed over the Indian Ocean: Implications for emissions and photochemistry  

E-Print Network [OSTI]

and known emission factors for black carbon (BC) from South Asia yields 0.7 Tg yrĂ?1 (upper limit of about 1 Global Change: Atmosphere (0315, 0325); KEYWORDS: Soot, black carbon, CO, emissions, India Citation of black carbon and carbon monoxide observed over the Indian Ocean: Implications for emissions

Dickerson, Russell R.

280

Strain-induced band-gap engineering of graphene monoxide and its effect on graphene  

Science Journals Connector (OSTI)

Using first-principles calculations we demonstrate the feasibility of band-gap engineering in two-dimensional crystalline graphene monoxide (GMO), a recently reported graphene-based material with a 1:1 carbon/oxygen ratio. The band gap of GMO, which can be switched between direct and indirect, is tunable over a large range (0–1.35 eV) for accessible strains. Electron and hole transport occurs predominantly along the zigzag and armchair directions (armchair for both) when GMO is a direct- (indirect-) gap semiconductor. A band gap of ?0.5 eV is also induced in graphene at the K? points for GMO/graphene hybrid systems.

H. H. Pu; S. H. Rhim; C. J. Hirschmugl; M. Gajdardziska-Josifovska; M. Weinert; J. H. Chen

2013-02-13T23:59:59.000Z

Note: This page contains sample records for the topic "monoxide hydrocarbons odors" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Chemisorption of carbon monoxide and nitrogen oxides on highly dispersed technetium  

SciTech Connect (OSTI)

The purpose of this work is to study, in infrared spectroscopy, the surface compounds formed on adsorption of carbon monoxide and nitrogen oxides on Tc/SiO/sub 2/. The samples were prepared by soaking Aerosil with aqueous solution of ammonium pertechnetate containing 10 wt.% of Tc. Reduction with hydrogen to the metal was carried out at 700-800/sup 0/C. Results indicated that chemisorption of CO on highly dispersed technetium gives rise to a single type of linear and several types of multicentered adsorption forms. Occurrence of bridge form of adsorbed CO was also suggested on the basis of the data on chemisorption stoichiometry. Formation of a structure characterizable by absorption at 1790 cm/sup -1/ may indicate, only after protracted analysis, that the surface of the technetium introduced gradually suffers significant rearrangement facilitating formation of this type of complexes.

Serebryakova, N.V.; Sokolova, N.P.; Spitsyn, V.S.

1982-08-01T23:59:59.000Z

282

Transformation of carbon monoxide dimer surface structures on yttrium oxide modified by silver  

SciTech Connect (OSTI)

It has been established that introducing ions of silver(II) in yttrium(III) oxide leads to the formation of a significant concentration of a paramagnetic dimer species (CO)/sub 2/-in the course of the adsorption of carbon monoxide, and that these dimers exhibit high thermal stability and reactivity. Reactions are proposed for the formation of the dimer species (CO)/sub 2//sup 2 -/ and (CO)/sub 2//sup -/ on the surface of the Ag/Y/sub 2/O/sub 3/ catalyst that involve the reduction of the anion vacancies and a change in the oxidation state of the silver ions. Modifying the yttrium oxide with ionic silver leads to a marked decrease in the strength of the oxidative ability of the surface of the catalyst for CO, while the nature of the active sites of the yttrium oxide, which adsorbs CO in three forms, remains unchanged.

Vydrin, S.N.; Bobolev, A.V.; Loginov, A.Yu.

1987-09-10T23:59:59.000Z

283

Infrared spectroscopic study of the adsorption of carbon monoxide on silica-supported copper oxide  

SciTech Connect (OSTI)

Adsorption of carbon monoxide at room temperature (0.1 to 50 Torr) on silica-supported copper oxide was studied by infrared spectroscopy. Catalysts were prepared by deposition-precipitation or impregnation. After calcination two types of adsorbed CO were identified showing absorption bands at 2136 +- 3 and 2204 +- 1 cm/sup -1/, which are ascribed to CO adsorbed on copper(II) oxide and on isolated copper(II) ions in the silica surface, respectively. Reduction and reoxidation removed the band at 2204 cm/sup -1/ with all samples and raised the intensity of the 2136-cm/sup -1/ band with the precipitated catalysts but not with the impregnation catalyst. Evidence is brought forward that the isolated copper ions are mobilized during reduction and generate new copper (oxide) surface. The change in background transmission of the samples could be used to obtain further information about the interaction of O/sub 2/ and CO with copper oxide.

De Jong, K.P.; Geus, J.W.; Joziasse, J.

1980-10-01T23:59:59.000Z

284

Modification of copper-chromium catalyst for steam conversion of carbon monoxide  

SciTech Connect (OSTI)

This paper presents the results of model tests that show that the copperchromium sample is superior in stability and activity to the industrial NTK-5 catalyst. Under unfavorable conditions with the use of industrial converted gas containing more than 20 vol.% of carbon monoxide, and with sulfur compounds, chlorine, and ammonia as impurities, after 3 months of continuous operation in the temperature range 190-260 degrees the catalyst lost less than 10% of inactivity (with respect to the degree of CO conversion), whereas the activity of the industrial NTK-4 catalyst fell by 15% under the same conditions. It is shown that a catalyst not inferior in properties to the industrial NTK-4 catalyst can be obtained by modifying the copper-chromium catalyst with aluminum compounds.

Khabibullin, R.R.; Torocheshnikov, N.S.

1986-08-01T23:59:59.000Z

285

Method and apparatus for detecting halogenated hydrocarbons  

DOE Patents [OSTI]

A halogenated hydrocarbon (HHC) detector is formed from a silent discharge (also called a dielectric barrier discharge) plasma generator. A silent discharge plasma device receives a gas sample that may contain one or more HHCs and produces free radicals and excited electrons for oxidizing the HHCs in the gas sample to produce water, carbon dioxide, and an acid including halogens in the HHCs. A detector is used to sensitively detect the presence of the acid. A conductivity cell detector combines the oxidation products with a solvent where dissociation of the acid increases the conductivity of the solvent. The conductivity cell output signal is then functionally related to the presence of HHCs in the gas sample. Other detectors include electrochemical cells, infrared spectrometers, and negative ion mobility spectrometers.

Monagle, Matthew (Los Alamos, NM); Coogan, John J. (Los Alamos, NM)

1997-01-01T23:59:59.000Z

286

Carbon monoxide adsorption/desorption processes over NaX zeolite and supported ruthenium catalyst  

SciTech Connect (OSTI)

The binding states of CO on NaX zeolite and RuNaX were investigated by thermal desorption spectroscopy. Desorption peaks centered at around 390, 430, 490, and 520 K were observed from NaX following room-temperature adsorption of CO. The activation energy values corresponding to these peaks were calculated to be 41.4, 45.7, 53.8, and 57.7 kJ mol{sup {minus}1}, respectively. These peaks were also observed in desorption profiles from RuNaX although their temperatures were higher by 10 to 20 K. In addition, the desorption spectra from RuNaX also comprise two high-temperature peaks at around 575 and 640 K. With both the RuNaX and the NaX samples the temperature and relative intensities of the desorption peaks depended on pretreatment conditions and on the lapsed time between CO exposure to the sample and the commencement of programmed heating. Mass spectral analysis revealed that the gas desorbed at 300-500 K consisted mainly of CO while at higher temperatures CO{sub 2} was the main component. The desorption peaks below 500 K are attributed to the release of carbon monoxide from structural and intragranular or intergranular zeolitic pores. Lewis sites on the zeolite surface are found to facilitate activation of CO, resulting in its transformation to CO{sub 2}. The initial adsorption of carbon monoxide in zeolite pores and subsequent diffusion to metal sites leading to its disproportionation/oxidation is found to play an important role in the CO adsorption/desorption process on RuNaX.

Kamble, V.S.; Gupta, N.M.; Iyer, R.M. (Bhabha Atomic Research Centre, Bombay (India))

1988-10-01T23:59:59.000Z

287

Hydrocarbon concentrations at the Alpine mountain sites Jungfraujoch and Arosa  

Science Journals Connector (OSTI)

Volatile hydrocarbons have been measured for 1 yr at Arosa (2010 m asl) to determine the contribution of European emissions to the trace gas concentrations at this remote site. Results are compared to concurrent hydrocarbon concentrations at the high Alpine background site Jungfraujoch (3580 m asl). Hydrocarbon concentrations at Arosa are generally much higher than at Jungfraujoch. The influence of the Alpine boundary layer air was studied based on the diurnal variation of hydrocarbon concentrations, i.e. rising pollutant concentrations in the morning at Arosa and in the afternoon at Jungfraujoch. Different hydrocarbon emission sources of the uplifting air were found at the two sites. At Jungfraujoch, several transatlantic events were detected from October 2001 to January 2002 based on analysis of hydrocarbon ratios and air parcel trajectories. The OH concentration during the transatlantic transport was estimated to be around 5×105 cm?3, derived from simultaneous hydrocarbon oxidation and dilution in the free troposphere. These transatlantic transport events were tracked back to warm conveyor belts, characterized by uniform dynamics and relatively uniform surface sources. In addition, ozone production in the free tropospheric transport was also documented in these events.

Yingshi Li; Mike Campana; Stefan Reimann; Daniel Schaub; Konrad Stemmler; Johannes Staehelin; Thomas Peter

2005-01-01T23:59:59.000Z

288

ABSTRACT High-resolution (1875 Hz) microscale (three, 200 ~tnlaverage d~ametersensors) measure-ments of the turbulent distribution of chemicals from an odor source initiated from a platform at 900 m  

E-Print Network [OSTI]

- ments of the turbulent distribution of chemicals from an odor source initiated from a platform at 900 m sensors were attached to a movable mechanical arm on the submersible and signals from the chemical sensor The recordings showed that both r a p ~ dand slow time course chemical signals exlsted in the odor plume

Moore, Paul A.

289

Iraq`s significant hydrocarbon potential remains relatively undeveloped  

SciTech Connect (OSTI)

Iraq is probably one of the least explored countries in the Middle East, despite the fact that it possesses one of the richest hydrocarbon basins in the world almost on a par to Saudi Arabia`s potential, if not more. The aim of this article is to state the facts about Iraq and focus on the huge but untapped and undeveloped hydrocarbon resources to the international oil community. Perhaps it is best to start by describing briefly the sedimentary and tectonic elements responsible for accumulating such large hydrocarbon resources. The paper describes the basin, tectonic elements, structural anomalies, deep drilling, source rocks, reservoir rocks, characteristics, and new reserves.

AL-Gailani, M. [GeoDesign Ltd., Kingston-upon-Thames (United Kingdom)

1996-07-29T23:59:59.000Z

290

Method for making hydrogen rich gas from hydrocarbon fuel  

DOE Patents [OSTI]

A method of forming a hydrogen rich gas from a source of hydrocarbon fuel in which the hydrocarbon fuel contacts a two-part catalyst comprising a dehydrogenation portion and an oxide-ion conducting portion at a temperature not less than about 400 C for a time sufficient to generate the hydrogen rich gas while maintaining CO content less than about 5 volume percent. There is also disclosed a method of forming partially oxidized hydrocarbons from ethanes in which ethane gas contacts a two-part catalyst comprising a dehydrogenation portion and an oxide-ion conducting portion for a time and at a temperature sufficient to form an oxide. 4 figs.

Krumpelt, M.; Ahmed, S.; Kumar, R.; Doshi, R.

1999-07-27T23:59:59.000Z

291

Method for making hydrogen rich gas from hydrocarbon fuel  

DOE Patents [OSTI]

A method of forming a hydrogen rich gas from a source of hydrocarbon fuel in which the hydrocarbon fuel contacts a two-part catalyst comprising a dehydrogenation portion and an oxide-ion conducting portion at a temperature not less than about 400.degree. C. for a time sufficient to generate the hydrogen rich gas while maintaining CO content less than about 5 volume percent. There is also disclosed a method of forming partially oxidized hydrocarbons from ethanes in which ethane gas contacts a two-part catalyst comprising a dehydrogenation portion and an oxide-ion conducting portion for a time and at a temperature sufficient to form an oxide.

Krumpelt, Michael (Naperville, IL); Ahmed, Shabbir (Bolingbrook, IL); Kumar, Romesh (Naperville, IL); Doshi, Rajiv (Downers Grove, IL)

1999-01-01T23:59:59.000Z

292

E-Print Network 3.0 - aromatic hydrocarbon emission Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

emission Search Powered by Explorit Topic List Advanced Search Sample search results for: aromatic hydrocarbon emission...

293

Energy loss characteristics of heavy ions in nitrogen, carbon dioxide, argon, hydrocarbon gases and tradescantia tissue  

E-Print Network [OSTI]

Energy loss characteristics of heavy ions in nitrogen, carbon dioxide, argon, hydrocarbon gases and tradescantia tissue

Dennis, J A

1971-01-01T23:59:59.000Z

294

Separation of toxic metal ions, hydrophilic hydrocarbons, hydrophobic fuel and halogenated hydrocarbons and recovery of ethanol from a process stream  

DOE Patents [OSTI]

This invention provides a process to tremendously reduce the bulk volume of contaminants obtained from an effluent stream produced subsurface remediation. The chemicals used for the subsurface remediation are reclaimed for recycling to the remediation process. Additional reductions in contaminant bulk volume are achieved by the ultra-violet light destruction of halogenated hydrocarbons, and the complete oxidation of hydrophobic fuel hydrocarbons and hydrophilic hydrocarbons. The contaminated bulk volume will arise primarily from the disposal of the toxic metal ions. The entire process is modular, so if there are any technological breakthroughs in one or more of the component process modules, such modules can be readily replaced.

Kansa, Edward J. (Livermore, CA); Anderson, Brian L. (Lodi, CA); Wijesinghe, Ananda M. (Tracy, CA); Viani, Brian E. (Oakland, CA)

1999-01-01T23:59:59.000Z

295

Underground storage of natural gas, liquid hydrocarbons, and carbon dioxide  

Broader source: Energy.gov (indexed) [DOE]

storage of natural gas, liquid hydrocarbons, and carbon storage of natural gas, liquid hydrocarbons, and carbon dioxide (Louisiana) Underground storage of natural gas, liquid hydrocarbons, and carbon dioxide (Louisiana) < Back Eligibility Commercial Construction Industrial Investor-Owned Utility Municipal/Public Utility Utility Program Info State Louisiana Program Type Environmental Regulations Siting and Permitting The Louisiana Department of Environmental Quality regulates the underground storage of natural gas or liquid hydrocarbons and carbon dioxide. Prior to the use of any underground reservoir for the storage of natural gas and prior to the exercise of eminent domain by any person, firm, or corporation having such right under laws of the state of Louisiana, the commissioner, shall have found all of the following:

296

Determination of Total Petroleum Hydrocarbons (TPH) Using Total Carbon Analysis  

SciTech Connect (OSTI)

Several methods have been proposed to replace the Freon(TM)-extraction method to determine total petroleum hydrocarbon (TPH) content. For reasons of cost, sensitivity, precision, or simplicity, none of the replacement methods are feasible for analysis of radioactive samples at our facility. We have developed a method to measure total petroleum hydrocarbon content in aqueous sample matrixes using total organic carbon (total carbon) determination. The total carbon content (TC1) of the sample is measured using a total organic carbon analyzer. The sample is then contacted with a small volume of non-pokar solvent to extract the total petroleum hydrocarbons. The total carbon content of the resultant aqueous phase of the extracted sample (TC2) is measured. Total petroleum hydrocarbon content is calculated (TPH = TC1-TC2). The resultant data are consistent with results obtained using Freon(TM) extraction followed by infrared absorbance.

Ekechukwu, A.A.

2002-05-10T23:59:59.000Z

297

Temporary Anion States of Polyatomic Hydrocarbons KENNETH D. JORDAN'  

E-Print Network [OSTI]

Temporary Anion States of Polyatomic Hydrocarbons KENNETH D. JORDAN' OSpemnenr Of C%sITIkby. M k I. A biographyand photograph of Kenneth D. Jordan appear In previous paper in this issue. far outweighsthat

Simons, Jack

298

Biodegradability of select polycyclic aromatic hydrocarbon (pah) mixtures  

E-Print Network [OSTI]

Polycyclic aromatic hydrocarbons (PAHs) are environmentally significant because of their ubiquity and the toxicity of some. Their recalcitrance and persistence makes them problematic environmental contaminants. Microbial degradation is considered...

Desai, Anuradha M.

2007-04-25T23:59:59.000Z

299

Experiments on Hydrocarbon Gas Hydrates in Unconsolidated Sand  

Science Journals Connector (OSTI)

Experiments were carried out to observe the formation and decomposition of hydrocarbon gas hydrates in an unconsolidated sand pack 4.4 cm in diameter and ... 43 bars and 5 to 10°C; gas used was 90% methane and 10...

P. E. Baker

1974-01-01T23:59:59.000Z

300

Filtration Combustion in Hydrocarbon Desorption from a Porous Medium  

Science Journals Connector (OSTI)

We have investigated theoretically and experimentally the process of filtration combustion with hydrocarbon desorption from a porous skeleton realized, in particular, in heat cleaning of porous media out of resid...

S. I. Fut'ko; K. V. Dobrego; E. S. Shmelev…

2003-11-01T23:59:59.000Z

Note: This page contains sample records for the topic "monoxide hydrocarbons odors" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Fireball during combustion of hydrocarbon fueld releases II. Thermal radiation  

Science Journals Connector (OSTI)

The processes of radiative heat transfer in a fireball which develops upon ignition of a cloud of hydrocarbon fuel near the Earth’s surface are simulated numerically. The emissive characteristics of combustion pr...

G. M. Makhviladze; J. P. Roberts; S. E. Yakush

302

Mathematical modeling of solid oxide fuel cells using hydrocarbon fuels  

E-Print Network [OSTI]

Solid oxide fuel cells (SOFCs) are high efficiency conversion devices that use hydrogen or light hydrocarbon (HC) fuels in stationary applications to produce quiet and clean power. While successful, HC-fueled SOFCs face ...

Lee, Won Yong, Ph. D. Massachusetts Institute of Technology

2012-01-01T23:59:59.000Z

303

Effect of the Composition of Hydrocarbon Streams on HCCI Performance  

Broader source: Energy.gov (indexed) [DOE]

of hydrocarbon samples and can be treated as compositional variables which could describe bulk properties of the samples Sample fingerprint STEP 1: Data receiving Q(2d)RPR How...

304

Hydrocarbon pollution control and remediation of groundwater: a brief review  

Science Journals Connector (OSTI)

...oil-contaminated sediments. There are two main remediation techniques: soil washing and bio- remediation. With soil washing, contaminated soil is leached with water containing a surfactant to assist in hydrocarbon removal. In situ washing is undertaken...

L. Clark

305

THE HEATS OF COMBUSTION OF AROMATIC HYDROCARBONS AND HEXAMETHYLENE.  

Science Journals Connector (OSTI)

THE HEATS OF COMBUSTION OF AROMATIC HYDROCARBONS AND HEXAMETHYLENE. ... Citation data is made available by participants in CrossRef's Cited-by Linking service. ... Experimental methods included adiabatic heat-capacity calorimetry (5 K to 420 K), comparative ... ...

Theodore W. Richards; Frederick Barry

1915-01-01T23:59:59.000Z

306

Measurements of dissolved nonmethane hydrocarbons in sea water  

Science Journals Connector (OSTI)

An automated stripping technique for the measurement of dissolved hydrocarbons in sea water is presented together with some results obtained ... cruise from Europe to Brazil. The sea water concentrations of NMHC ...

C. Plass; R. Koppmann; J. Rudolph

307

Hygienic rating of hydrocarbons in bottom deposits of water ecosystems  

Science Journals Connector (OSTI)

The authors of this article draw the reader’s attention to the topical problem of the contamination of bottom deposits of water ecosystems by hydrocarbons, such as oil and gas condensate,...

Rauf Valievich Galiulin…

2014-05-01T23:59:59.000Z

308

Cooling and solidification of heavy hydrocarbon liquid streams  

DOE Patents [OSTI]

A process and apparatus for cooling and solidifying a stream of heavy hydrocarbon material normally boiling above about 850.degree. F., such as vacuum bottoms material from a coal liquefaction process. The hydrocarbon stream is dropped into a liquid bath, preferably water, which contains a screw conveyor device and the stream is rapidly cooled, solidified and broken therein to form discrete elongated particles. The solid extrudates or prills are then dried separately to remove substantially all surface moisture, and passed to further usage.

Antieri, Salvatore J. (Trenton, NJ); Comolli, Alfred G. (Yardley, PA)

1983-01-01T23:59:59.000Z

309

Conversion of methane and acetylene into gasoline range hydrocarbons  

E-Print Network [OSTI]

CONVERSION OF METHANE AND ACETYLENE INTO GASOLINE RANGE HYDROCARBONS A Thesis by AMMAR ALKHAWALDEH Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER... OF SCIENCE May 2000 Major Subject: Chemical Engineering CONVERSION OF METHANE AND ACETYLENE INTO GASOLINE RANGE HYDROCARBONS A Thesis by AMMAR ALKHAWALDEH Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment...

Alkhawaldeh, Ammar

2012-06-07T23:59:59.000Z

310

Emission of polycyclic aromatic hydrocarbons in China  

SciTech Connect (OSTI)

Emission of 16 polycyclic aromatic hydrocarbons (PAHs) listed as U.S. Environmental Protection Agency (U.S. EPA) priority pollutants from major sources in China were compiled. Geographical distribution and temporal change of the PAH emission, as well as emission profiles, are discussed. It was estimated that the total PAH emission in China was 25,300 tons in 2003. The emission profile featured a relatively higher portion of high molecular weight (HMW) species with carcinogenic potential due to large contributions of domestic coal and coking industry. Among various sources, biomass burning, domestic coal combustion, and the coking industry contributed 60%, 20%, and 16% of the total emission, respectively. Total emission, emission density, emission intensity, and emission per capita showed geographical variations. In general, the southeastern provinces were characterized by higher emission density, while those in western and northern China featured higher emission intensity and population-normalized emission. Although energy consumption in China went up continuously during the past two decades, annual emission of PAHs fluctuated depending on the amount of domestic coal consumption, coke production, and the efficiency of energy utilization. 47 refs., 6 figs.

Shanshan Xu; Wenxin Liu; Shu Tao [Peking University, Beijing (China). Laboratory for Earth Surface Processes, College of Environmental Sciences

2006-02-01T23:59:59.000Z

311

Rock types, pore types, and hydrocarbon exploration  

SciTech Connect (OSTI)

A proposed exploration-oriented method of classifying porosity in sedimentary rocks is based on microscopic examination cores or cuttings. Factors include geometry, size, abundance, and connectivity of the pores. The porosity classification is predictive of key petrophysical characteristics: porosity-permeability relationships, capillary pressures, and (less certainly) relative permeabilities. For instance, intercrystalline macroporosity typically is associated with high permeability for a given porosity, low capillarity, and favorable relative permeabilities. This is found to be true whether this porosity type occurs in a sucrosic dolomite or in a sandstone with pervasive quartz overgrowths. This predictive method was applied in three Rocky Mountain oil plays. Subtle pore throat traps could be recognized in the J sandstone (Cretaceous) in the Denver basin of Colorado by means of porosity permeability plotting. Variations in hydrocarbon productivity from a Teapot Formation (Cretaceous) field in the Powder River basin of Wyoming were related to porosity types and microfacies; the relationships were applied to exploration. Rock and porosity typing in the Red River Formation (Ordovician) reconciled apparent inconsistencies between drill-stem test, log, and mud-log data from a Williston basin wildcat. The well was reevaluated and completed successfully, resulting in a new field discovery. In each of these three examples, petrophysics was fundamental for proper evaluation of wildcat wells and exploration plays.

Coalson, E.B.; Hartmann, D.J.; Thomas, J.B.

1985-05-01T23:59:59.000Z

312

Using the HP-41CV calculator as a data acquisition system for personal carbon monoxide exposure monitors  

SciTech Connect (OSTI)

The use of small, personal monitors as instruments for air pollution data acquisition, storage, and retrieval presents a new set of monitoring considerations. Portability, ruggedness, power supplies, and data capture are functions to be addressed in designing personal monitoring systems. The emphasis herein is on the data capture function. This paper describes experiences using the Hewlett-Packard HP-41CV system as a data management system interfaced with personal carbon monoxide monitors (General Electric Carbon Monoxide Detector, Model 15EC53CO3). In general, the HP-41CV proved to be reliable, adaptable, and easy to use. Problems with the monitor power source (battery failure) were more frequent than with the HP-41CV itself. Using the HP-41CV for the specific data collection requirements of the Washington Microenvironment Study is a focal point of this presentation.

Fitz-Simons, T.; Sauls, H.B.

1984-09-01T23:59:59.000Z

313

A preliminary evaluation model for reservoir hydrocarbon-generating potential established based on dissolved hydrocarbons in oilfield water  

Science Journals Connector (OSTI)

A large number of oilfield water samples were analyzed in this work. Research ... relationship between the concentrations and distribution of dissolved hydrocarbons suggested that the contents and composition of ...

Hongjing Zhao; Weilin Sun; Baotian He; Bowen Mei…

2006-01-01T23:59:59.000Z

314

Molten metal reactor and method of forming hydrogen, carbon monoxide and carbon dioxide using the molten alkaline metal reactor  

DOE Patents [OSTI]

A molten metal reactor for converting a carbon material and steam into a gas comprising hydrogen, carbon monoxide, and carbon dioxide is disclosed. The reactor includes an interior crucible having a portion contained within an exterior crucible. The interior crucible includes an inlet and an outlet; the outlet leads to the exterior crucible and may comprise a diffuser. The exterior crucible may contain a molten alkaline metal compound. Contained between the exterior crucible and the interior crucible is at least one baffle.

Bingham, Dennis N.; Klingler, Kerry M.; Turner, Terry D.; Wilding, Bruce M.

2012-11-13T23:59:59.000Z

315

Total oxidation of carbon monoxide and methane over transition metal-fluorite oxide composite catalysts. I. Catalyst composition and activity  

SciTech Connect (OSTI)

A novel metal oxide composite catalyst for the total oxidation of carbon monoxide and methane was prepared by combining fluorite oxides with active transition metals. The fluorite oxides, such as ceria and zirconia, are oxygen-ion-conducting materials having catalytic properties usually at high temperatures. Active base metal catalysts, such as copper, were used as additives to promote the catalytic properties of these oxides. The contact of the two types of materials gave rise to a high active oxidation catalyst. At a space velocity of about 42,000 h{sup {minus}1}, complete carbon monoxide oxidation in air occurred at room temperature on the Au{sub 0.05}[Ce(La)]{sub 0.95}L{sub x} catalyst and at ca. 100{degrees}C on Cu-Ce-O composite catalysts. At the same space velocity, total oxidation of methane on the Cu-Ce-O catalyst doped with La{sub 2}O{sub 3} or SrO took place at ca. 550{degrees}C. The specific carbon monoxide oxidation activity of the Cu-Ce-O catalyst was several orders of magnitude higher than that of conventional copper-based catalysts and comparable or superior to platinum catalysts. This type of composite catalyst also showed excellent resistance to water vapor poisoning. The enhanced catalyst activity and stability resulted from strong interaction of the transition metal and fluorite oxide materials. 44 refs., 14 figs., 5 tabs.

Liu, W.; Flytzani-Stephanopoulos, F. [Tufts Univ., Medford, MA (United States)] [Tufts Univ., Medford, MA (United States)

1995-05-01T23:59:59.000Z

316

REFORMULATION OF COAL-DERIVED TRANSPORTATION FUELS: SELECTIVE OXIDATION OF CARBON MONOXIDE ON METAL FOAM CATALYSTS  

SciTech Connect (OSTI)

Hydrocarbon fuels must be reformed in a series of steps to provide hydrogen for use in proton exchange membrane fuel cells (PEMFCs). Preferential oxidation (PROX) is one method to reduce the CO concentration to less than 10 ppm in the presence of {approx}40% H{sub 2}, CO{sub 2}, and steam. This will prevent CO poisoning of the PEMFC anode. Structured supports, such as ceramic monoliths, can be used for the PROX reaction. Alternatively, metal foams offer a number of advantages over the traditional ceramic monolith.

Paul Chin; Xiaolei Sun; George W. Roberts; Amornmart Sirijarhuphan; Sourabh Pansare; James G. Goodwin Jr; Richard W. Rice; James J. Spivey

2005-06-01T23:59:59.000Z

317

Adsorption of carbon monoxide on a smooth palladium electrode: an in-situ infrared spectroscopic study  

SciTech Connect (OSTI)

Adsorption of carbon monoxide on a smooth palladium electrode in 1 M HClO/sub 4/ saturated with CO was studied by two in-situ IR reflectance spectroscopic methods: EMIRS (electrochemically modulated infrared reflectance spectroscopy) and LPSIRS (linear potential sweep infrared reflectance spectroscopy). Two types of adsorbed CO, linear and bridged, were identified from the observed IR spectra, the latter being the predominant surface species. The C-O stretching frequency of the linear CO shifts to higher frequencies at more positive potentials with a slope of 48 cm/sup -1//V. The frequency of the bridged CO increases by 63 cm/sup -1/ between -0.5 and 0.9 V(NHE) and its integrated band intensity decreases continuously in the same potential region while the intensity of the linear CO is almost constant up to 0.1 V and then decreases gradually with increasing positive potential. The surface selection rule of the IR reflection absorption spectroscopy was tested for the present system by using the p- and s-polarized light. It was found that only p-polarized light gave the IR spectra of CO adsorbed on the palladium electrode thus proving the selection rule at the electrode/solution interface.

Kunimatsu, K.

1984-05-24T23:59:59.000Z

318

Relative and kinetic properties of carbon monoxide and carbon dioxide on a graphite surface  

SciTech Connect (OSTI)

Temperature-programmed desorption (TPD) results after chemisorption of carbon monoxide (CO) and carbon dioxide (CO/sub 2/) on polycrystalline graphite are presented. CO adsorbs onto graphite with a very low sticking coefficient. After CO chemisorption CO (mass 28 amu) desorbs in two temperature regions, between 400 and 700 K and between 1000 and 1300 K, and CO/sub 2/ (mass 44 amu) desorbs below 950 K. The intensity of the CO/sub 2/ signal is less than 1 order of magnitude lower than the CO intensity. After CO/sub 2/ adsorption the major desorption product is CO at high temperatures (1000 < T (K) < 1300), whereas a small amount of CO/sub 2/ desorbs around 450 K. The adsorption of C/sup 16/O/sub 2/ and C/sup 18/O/sub 2/ mixture leads to a nearly total oxygen scrambling of the CO/sub 2/ desorbed. A mechanism for CO and CO/sub 2/ interconversion on the graphite surface is presented in terms of surface oxide species, mainly lactones and semiquinones, and their relative stability. Assignments of the TPD features are proposed accordingly. Reaction studies on the CO/sub 2/ gasification of clean graphite and the CO disproportionation (Boudouard reaction) have been performed. A good agreement is found between the activation energies obtained and the desorption energies calculated from the analysis of the TPD results.

Marchon, B.; Tysoe, W.T.; Carrazza, J.; Heinemann, H.; Somorjai, G.A.

1988-10-06T23:59:59.000Z

319

Solar Carbon Monoxide, Thermal Profiling, and the Abundances of C, O, and their Isotopes  

E-Print Network [OSTI]

A solar photospheric "thermal profiling" analysis is presented, exploiting the infrared rovibrational bands of carbon monoxide (CO) as observed with the McMath-Pierce Fourier transform spectrometer (FTS) at Kitt Peak, and from above the Earth's atmosphere by the Shuttle-borne ATMOS experiment. Visible continuum intensities and center-limb behavior constrained the temperature profile of the deep photosphere, while CO center-limb behavior defined the thermal structure at higher altitudes. The oxygen abundance was self consistently determined from weak CO absorptions. Our analysis was meant to complement recent studies based on 3-D convection models which, among other things, have revised the historical solar oxygen (and carbon) abundance downward by a factor of nearly two; although in fact our conclusions do not support such a revision. Based on various considerations, an oxygen abundance of 700+/-100 ppm (parts per million relative to hydrogen) is recommended; the large uncertainty reflects the model sensitivity of CO. New solar isotopic ratios also are reported for 13C, 17O, and 18O.

Thomas R. Ayres; Claude Plymate; Christoph U. Keller

2006-06-07T23:59:59.000Z

320

Cysteine 295 indirectly affects Ni coordination of carbon monoxide dehydrogenase-II C-cluster  

SciTech Connect (OSTI)

Highlights: •CODH-II harbors a unique [Ni-Fe-S] cluster. •We substituted the ligand residues of Cys{sup 295} and His{sup 261}. •Dramatic decreases in Ni content upon substitutions were observed. •All substitutions did not affect Fe-S clusters assembly. •CO oxidation activity was decreased by the substitutions. -- Abstract: A unique [Ni–Fe–S] cluster (C-cluster) constitutes the active center of Ni-containing carbon monoxide dehydrogenases (CODHs). His{sup 261}, which coordinates one of the Fe atoms with Cys{sup 295}, is suggested to be the only residue required for Ni coordination in the C-cluster. To evaluate the role of Cys{sup 295}, we constructed CODH-II variants. Ala substitution for the Cys{sup 295} substitution resulted in the decrease of Ni content and didn’t result in major change of Fe content. In addition, the substitution had no effect on the ability to assemble a full complement of [Fe–S] clusters. This strongly suggests Cys{sup 295} indirectly and His{sup 261} together affect Ni-coordination in the C-cluster.

Inoue, Takahiro; Takao, Kyosuke; Yoshida, Takashi [Division of Applied Biosciences, Graduate School of Agriculture, Kyoto University, Kyoto 606-8502 (Japan)] [Division of Applied Biosciences, Graduate School of Agriculture, Kyoto University, Kyoto 606-8502 (Japan); Wada, Kei [Organization for Promotion of Tenure Track, University of Miyazaki, Miyazaki 889-1692 (Japan)] [Organization for Promotion of Tenure Track, University of Miyazaki, Miyazaki 889-1692 (Japan); Daifuku, Takashi; Yoneda, Yasuko [Division of Applied Biosciences, Graduate School of Agriculture, Kyoto University, Kyoto 606-8502 (Japan)] [Division of Applied Biosciences, Graduate School of Agriculture, Kyoto University, Kyoto 606-8502 (Japan); Fukuyama, Keiichi [Department of Biological Sciences, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043 (Japan)] [Department of Biological Sciences, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043 (Japan); Sako, Yoshihiko, E-mail: sako@kais.kyoto-u.ac.jp [Division of Applied Biosciences, Graduate School of Agriculture, Kyoto University, Kyoto 606-8502 (Japan)] [Division of Applied Biosciences, Graduate School of Agriculture, Kyoto University, Kyoto 606-8502 (Japan)

2013-11-08T23:59:59.000Z

Note: This page contains sample records for the topic "monoxide hydrocarbons odors" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Kidney cancer and hydrocarbon exposures among petroleum refinery workers  

SciTech Connect (OSTI)

To evaluate the hypothesis of increased kidney cancer risk after exposure to hydrocarbons, especially those present in gasoline, we conducted a case-control study in a cohort of approximately 100,000 male refinery workers from five petroleum companies. A review of 18,323 death certificates identified 102 kidney cancer cases, to each of whom four controls were matched by refinery location and decade of birth. Work histories, containing an average of 15.7 job assignments per subject, were found for 98% of the cases and 94% of the controls. Tb each job, industrial hygienists assigned semiquantitative ratings for the intensity and frequency of exposures to three hydrocarbon categories: nonaromatic liquid gasoline distillates, aromatic hydrocarbons, and the more volatile hydrocarbons. Ratings of {open_quotes}present{close_quotes} or {open_quotes}absent{close_quotes} were assigned for seven additional exposures: higher boiling hydrocarbons, polynuclear aromatic hydrocarbons, asbestos, chlorinated solvents, ionizing radiation, and lead. Each exposure had either no association or a weak association with kidney cancer. For the hydrocarbon category of principal a priori interest, the nonaromatic liquid gasoline distillates, the estimated relative risk (RR) for any exposure above refinery background was 1.0 (95% confidence interval [CI] 0.5-1.9). Analyses of cumulative exposures and of exposures in varying time periods before kidney cancer occurrence also produced null or near-null results. In an analysis of the longest job held by each subject (average duration 9.2 years or 40% of the refiner&y work history), three groups appeared to be at increased risk: laborers (RR = 1.9,95% CI 1.0-3.9); workers in receipt, storage, and movements (RR = 2.5,95% CI 0.9-6.6); and unit cleaners (RR = 2.3, 95% CI 0.5-9.9). 53 refs., 7 tabs.

Poole, C.; Dreyer, N.A.; Satterfield, M.H. [Epidemiology Resources Inc., Newton Lower Falls, MA (United States); Levin, L. [Drexel Univ., Philadelphia, PA (United States)

1993-12-01T23:59:59.000Z

322

In Situ Hydrocarbon Degradation by Indigenous Nearshore Bacterial Populations  

SciTech Connect (OSTI)

Potential episodic hydrocarbon inputs associated with oil mining and transportation together with chronic introduction of hydrocarbons via urban runoff into the relatively pristine coastal Florida waters poses a significant threat to Florida's fragile marine environment. It is therefore important to understand the extent to which indigenous bacterial populations are able to degrade hydrocarbon compounds and also determine factors that could potentially control and promote the rate at which these compounds are broken down in situ. Previous controlled laboratory experiments carried out by our research group demonstrated that separately both photo-oxidation and cometabolism stimulate bacterial hydrocarbon degradation by natural bacterial assemblages collected from a chronically petroleum contaminated site in Bayboro Bay, Florida. Additionally, we also demonstrated that stable carbon and radiocarbon abundances of respired CO{sub 2} could be used to trace in situ hydrocarbon degradation by indigenous bacterial populations at this same site. This current proposal had two main objectives: (a) to evaluate the cumulative impact of cometabolism and photo-oxidation on hydrocarbon degradation by natural bacterial assemblages collected the same site in Bayboro Bay, Florida and (b) to determine if in situ hydrocarbon degradation by indigenous bacterial populations this site could be traced using natural radiocarbon and stable carbon abundances of assimilated bacterial carbon. Funds were used for 2 years of full support for one ESI Ph.D. student, April Croxton. To address our first objective a series of closed system bacterial incubations were carried out using photo-oxidized petroleum and pinfish (i.e. cometabolite). Bacterial production of CO{sub 2} was used as the indicator of hydrocarbon degradation and {delta}{sup 13}C analysis of the resultant CO{sub 2} was used to evaluate the source of the respired CO{sub 2} (i.e. petroleum hydrocarbons or the pinfish cometabolite). Results from these time series experiments demonstrated that short-term exposure of petroleum to UV light enhanced hydrocarbon degradation by 48% over that observed for non-photo-oxidized petroleum. Despite the greater bio-availability of the photo-oxidized over the non-photo-oxidized petroleum, an initial lag in CO{sub 2} production was observed indicating potential phototoxicity of the photo- by-products. {delta}{sup 13}C analysis and mass balance calculations reveal that co-metabolism with pinfish resulted in increased hydrocarbon degradation for both photo-oxidized and non-photo-oxidized petroleum each by over 100%. These results demonstrate the cumulative effect of photo-oxidation and co-metabolism on petroleum hydrocarbon degradation by natural bacterial populations indigenous to systems chronically impacted by hydrocarbon input. To address the second objective of this proposal bacterial concentrates were collected from Bayboro Harbor in April 2001 for nucleic acid extraction and subsequent natural radiocarbon abundance analyses. Unfortunately, however, all of these samples were lost due to a faulty compressor in our -70 freezer. The freezer was subsequently repaired and samples were again collected from Bayboro Harbor in June 2002 and again December 2002. Several attempts were made to extract the nucleic acid samples--however, the student was not able to successfully extract and an adequate amount of uncontaminated nucleic acid samples for subsequent natural radiocarbon abundance measurements of the bacterial carbon by accelerator mass spectrometry (i.e. require at least 50 {micro}g carbon for AMS measurement). Consequently, we were not able to address the second objective of this proposed work.

Cherrier, J.

2005-05-16T23:59:59.000Z

323

Preliminary assessment of hydrocarbon potential in southern Illinois  

SciTech Connect (OSTI)

Hydrocarbon exploration has been sparse south of the Cottage Grove fault system in southern Illinois. Over 240,000 ac in this area are within the Shawnee National Forest (SNF). Upcoming review of mineral exploration policy on SNF land and a recent amendment to the Mineral Leasing Act (1987) will result in release of portions of the SNF for competitive and potentially noncompetitive bidding for mineral exploration tracts in the near future. Preliminary assessment of hydrocarbon potential has been carried out in southern Illinois. Numerous oil shows occur in Paleozoic strata south of the Cottage Grove fault system, which, at present, describes the southern boundary of most oil production in Illinois. Only Mitchellsville oil field in southern Saline County lies south of the Cottage Grove fault system. The Upper Devonian New Albany Shale, though to be the primary source rock for Illinois basin hydrocarbons, underlies most of the area. Older potential source rocks may be present. Depositional trends of prolific oil-productive Mississippian strata in Illinois continue southward through the area. Few drill holes have tested strata older than Mississippian in the area. Complex faulting in the Rough Creek-Shawneetown fault system may have improved the potential for hydrocarbon emplacement and entrapment in this region. Preliminary assessment of hydrocarbon potential indicates that this wildcat region deserves further tests.

Crockett, J.E.; Oltz, D.F. (Illinois State Geological Survey, Champaign (USA))

1989-08-01T23:59:59.000Z

324

Methane-derived hydrocarbons produced under upper-mantle conditions  

SciTech Connect (OSTI)

There is widespread evidence that petroleum originates from biological processes. Whether hydrocarbons can also be produced from abiogenic precursor molecules under the high-pressure, high-temperature conditions characteristic of the upper mantle remains an open question. It has been proposed that hydrocarbons generated in the upper mantle could be transported through deep faults to shallower regions in the Earth's crust, and contribute to petroleum reserves. Here we use in situ Raman spectroscopy in laser-heated diamond anvil cells to monitor the chemical reactivity of methane and ethane under upper-mantle conditions. We show that when methane is exposed to pressures higher than 2 GPa, and to temperatures in the range of 1,000-1,500 K, it partially reacts to form saturated hydrocarbons containing 2-4 carbons (ethane, propane and butane) and molecular hydrogen and graphite. Conversely, exposure of ethane to similar conditions results in the production of methane, suggesting that the synthesis of saturated hydrocarbons is reversible. Our results support the suggestion that hydrocarbons heavier than methane can be produced by abiogenic processes in the upper mantle.

Kolesnikov, Anton; Kutcherov, Vladimir G.; Goncharov, Alexander F.; (CIW); (RITS)

2009-08-13T23:59:59.000Z

325

Determination of Polycyclic Aromatic Hydrocarbons in Fresh Milk by Hollow Fiber Liquid-Phase Microextraction–Gas Chromatography Mass Spectrometry  

Science Journals Connector (OSTI)

......Polycyclic Aromatic Hydrocarbons in Fresh Milk by...polycyclic aromatic hydrocarbons (PAHs) in fresh...more volatile and heat sensitive. The...Polycyclic aromatic hydrocarbons (PAHs) are compounds...the incomplete combustion of carbon-containing...respectively. Data were collected......

Mohd Marsin Sanagi; Saw Hong Loh; Wan Aini Wan Ibrahim; Mohamed Noor Hasan; Hassan Y. Aboul Enein

2013-02-01T23:59:59.000Z

326

Hepatic coenzyme Q redox balance of fishes as a potential bioindicator of environmental contamination by polycyclic aromatic hydrocarbons  

Science Journals Connector (OSTI)

...at the land-water interface are...polycyclic aromatic hydrocarbon (PAH) contamination...Markers 0 Polycyclic Hydrocarbons, Aromatic 0 Water Pollutants, Chemical...metabolism Polycyclic Hydrocarbons, Aromatic toxicity...Ubiquinone metabolism Water Pollutants, Chemical...

2011-01-01T23:59:59.000Z

327

Process for light-driven hydrocarbon oxidation at ambient temperatures  

DOE Patents [OSTI]

A photochemical reaction for the oxidation of hydrocarbons uses molecular oxygen as the oxidant. A reductive photoredox cycle that uses a tin(IV)- or antimony(V)-porphyrin photosensitizer generates the reducing equivalents required to activate oxygen. This artificial photosynthesis system drives a catalytic cycle, which mimics the cytochrome P.sub.450 reaction, to oxidize hydrocarbons. An iron(III)- or manganese(III)-porphyrin is used as the hydrocarbon-oxidation catalyst. Methylviologen can be used as a redox relay molecule to provide for electron-transfer from the reduced photosensitizer to the Fe or Mn porphyrin. The system is long-lived and may be used in photo-initiated spectroscopic studies of the reaction to determine reaction rates and intermediates.

Shelnutt, John A. (Tijeras, NM)

1990-01-01T23:59:59.000Z

328

Method and apparatus for producing oxygenates from hydrocarbons  

DOE Patents [OSTI]

A chemical reactor for oxygenating hydrocarbons includes: (a) a dielectric barrier discharge plasma cell, the plasma cell comprising a pair of electrodes having a dielectric material and void therebetween, the plasma cell comprising a hydrocarbon gas inlet feeding to the void; (b) a solid oxide electrochemical cell, the electrochemical cell comprising a solid oxide electrolyte positioned between a porous cathode and a porous anode, an oxygen containing gas inlet stream feeding to the porous cathode side of the electrochemical cell; (c) a first gas passageway feeding from the void to the anode side of the electrochemical cell; and (d) a gas outlet feeding from the anode side of the electrochemical cell to expel reaction products from the chemical reactor. A method of oxygenating hydrocarbons is also disclosed. 4 figs.

Kong, P.C.; Lessing, P.A.

1995-06-27T23:59:59.000Z

329

Carbon monoxide in the solar atmosphere I. Numerical method and two-dimensional models  

E-Print Network [OSTI]

The radiation hydrodynamic code CO5BOLD has been supplemented with the time-dependent treatment of chemical reaction networks. Advection of particle densities due to the hydrodynamic flow field is also included. The radiative transfer is treated frequency-independently, i.e. grey, so far. The upgraded code has been applied to two-dimensional simulations of carbon monoxide (CO) in the non-magnetic solar photosphere and low chromosphere. For this purpose a reaction network has been constructed, taking into account the reactions which are most important for the formation and dissociation of CO under the physical conditions of the solar atmosphere. The network has been strongly reduced to 27 reactions, involving the chemical species H, H2, C, O, CO, CH, OH, and a representative metal. The resulting CO number density is highest in the cool regions of the reversed granulation pattern at mid-photospheric heights and decreases strongly above. There, the CO abundance stays close to a value of 8.3 on the usual logarithmic abundance scale with [H]=12 but is reduced in hot shock waves which are a ubiquitous phenomenon of the model atmosphere. For comparison, the corresponding equilibrium densities have been calculated, based on the reaction network but also under assumption of instantaneous chemical equilibrium by applying the Rybicki & Hummer (RH) code by Uitenbroek (2001). Owing to the short chemical timescales, the assumption holds for a large fraction of the atmosphere, in particular the photosphere. In contrast, the CO number density deviates strongly from the corresponding equilibrium value in the vicinity of chromospheric shock waves. Simulations with altered reaction network clearly show that the formation channel via hydroxide (OH) is the most important one under the conditions of the solar atmosphere.

S. Wedemeyer-Boehm; I. Kamp; J. Bruls; B. Freytag

2005-03-23T23:59:59.000Z

330

Hydrocarbon composition of crude oil from Lam Bank  

SciTech Connect (OSTI)

The authors discuss the crude oil from a new offshore field called the Lam Bank in the Caspian Sea. A segregated commercial crude was distilled and the distillation data is shown. In order to determine the content of n-paraffins, the naphthenic-paraffinic part of the narrow cuts was subjected to adsorptive separation on CaA zeolite. Owing to the high contents of naphthenic and isoparaffinic hydrocarbons and the low content of aromatic hydrocarbons in the distillate part, this crude can be used to produce high-quality fuels and oils by the use of the dewaxing processes.

Samedova, F.I.; Agaeva, R.M.; Alieva, F.Z.; Valiev, M.A.

1987-07-01T23:59:59.000Z

331

Method and apparatus for production of subsea hydrocarbon formations  

DOE Patents [OSTI]

A system for controlling, separating, processing and exporting well fluids produced from subsea hydrocarbon formations is disclosed. The subsea well tender system includes a surface buoy supporting one or more decks above the water surface for accommodating equipment to process oil, gas and water recovered from the subsea hydrocarbon formation. The surface buoy includes a surface-piercing central flotation column connected to one or more external flotation tanks located below the water surface. The surface buoy is secured to the sea bed by one or more tendons which are anchored to a foundation with piles imbedded in the sea bed. The system accommodates multiple versions on the surface buoy configuration. 20 figures.

Blandford, J.W.

1995-01-17T23:59:59.000Z

332

Method and apparatus for production of subsea hydrocarbon formations  

DOE Patents [OSTI]

A system for controlling, separating, processing and exporting well fluids produced from subsea hydrocarbon formations is disclosed. The subsea well tender system includes a surface buoy supporting one or more decks above the water surface for accommodating equipment to process oil, gas and water recovered from the subsea hydrocarbon formation. The surface buoy includes a surface-piercing central flotation column connected to one or more external floatation tanks located below the water surface. The surface buoy is secured to the seabed by one or more tendons which are anchored to a foundation with piles imbedded in the seabed. The system accommodates multiple versions on the surface buoy configuration.

Blandford, Joseph W. (15 Mott La., Houston, TX 77024)

1995-01-01T23:59:59.000Z

333

Method for determining processability of a hydrocarbon containing feedstock  

SciTech Connect (OSTI)

Disclosed herein is a method involving the steps of (a) precipitating an amount of asphaltenes from a liquid sample of a first hydrocarbon-containing feedstock having solvated asphaltenes therein with one or more first solvents in a column; (b) determining one or more solubility characteristics of the precipitated asphaltenes; (c) analyzing the one or more solubility characteristics of the precipitated asphaltenes; and (d) correlating a measurement of feedstock reactivity for the first hydrocarbon-containing feedstock sample with a mathematical parameter derived from the results of analyzing the one or more solubility characteristics of the precipitated asphaltenes.

Schabron, John F.; Rovani, Jr., Joseph F.

2013-09-10T23:59:59.000Z

334

Upgrading of petroleum oil feedstocks using alkali metals and hydrocarbons  

DOE Patents [OSTI]

A method of upgrading an oil feedstock by removing heteroatoms and/or one or more heavy metals from the oil feedstock composition. This method reacts the oil feedstock with an alkali metal and an upgradant hydrocarbon. The alkali metal reacts with a portion of the heteroatoms and/or one or more heavy metals to form an inorganic phase separable from the organic oil feedstock material. The upgradant hydrocarbon bonds to the oil feedstock material and increases the number of carbon atoms in the product. This increase in the number of carbon atoms of the product increases the energy value of the resulting oil feedstock.

Gordon, John Howard

2014-09-09T23:59:59.000Z

335

Isoconversional Kinetic Analysis of the Combustion of Heavy Hydrocarbons  

Science Journals Connector (OSTI)

One method to access unconventional, heavy-oil resources as well as waterflood residual oil is to apply in situ combustion (ISC) to oxidize in place a small fraction of the hydrocarbon, thereby providing heat to reduce oil viscosity and pressure that enhances recovery. ... As shown by Vyazovkin,(12) these deviations of temperature yield erroneous values of activation energy, when such a data set is used with a model that assumes linear heating. ... Estimates were made of the heat produced, and a formula was derived for computing the heat of combustion of hydrocarbons in the high-temp. ...

Murat Cinar; Louis M. Castanier; Anthony R. Kovscek

2009-07-06T23:59:59.000Z

336

Experimental and artificial neural network modeling study on soot formation in premixed hydrocarbon flamesq  

E-Print Network [OSTI]

Experimental and artificial neural network modeling study on soot formation in premixed hydrocarbon after the methane flames, respectively. Three-layer, feed- forward type artificial neural networks rights reserved. Keywords: Soot; Hydrocarbon flames; Artificial neural networks 1. Introduction

Senkan, Selim M.

337

The Fate of Fossil Fuel Hydrocarbons in Marine Animals [and Discussion  

Science Journals Connector (OSTI)

20 May 1975 research-article The Fate of Fossil Fuel Hydrocarbons in Marine Animals [and Discussion] E...have been made of their fate in mammals. The fate of fossil fuel hydrocarbons in marine animals. | Journal Article...

1975-01-01T23:59:59.000Z

338

Bioenergy Technologies Office Conversion R&D Pathway: Syngas Upgrading to Hydrocarbon Fuels  

Broader source: Energy.gov [DOE]

Syngas upgrading to hydrocarbon fuels is one of eight priority pathways chosen to convert biomass into hydrocarbon fuels by the Bioenergy Technologies Office. These pathways were down-selected from an initial list of 18.

339

Dynamic study of coupled heavy hydrocarbon pyrolysis and combustion. N. Gascoina*  

E-Print Network [OSTI]

1/28 Dynamic study of coupled heavy hydrocarbon pyrolysis and combustion. N. Gascoina* , P of the heat transfer dynamics. Finally, the combustion mechanism is applied and validated experimentally for kerosene pyrolysis application. Keywords Regenerative cooling; Hydrocarbon pyrolysis; Supersonic Combustion

Boyer, Edmond

340

The Energies of the Atomic Linkages in the Normal Paraffin Hydrocarbons  

Science Journals Connector (OSTI)

...normal paraffin hydrocarbons, in the gaseous...values for the heats of combustion of these gases...values for the heats of combustion of the hydrocarbon gases,4'5...Jessup4 on the heats of combustion of normal heptane...

Frederick D. Rossini

1934-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "monoxide hydrocarbons odors" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

E-Print Network 3.0 - aromatic hydrocarbons molecular Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

various hydrocarbons on monolithic hydrocarbon adsorber Dae Jung Kim,a Ji Man Kim,a Jae Eui Yie... ,b, Seong Gyu Seo,c and Sang-Chai Kim d a Department of Molecular Science and...

342

LiMnPO4 Nanoplate Grown via Solid-State Reaction in Molten Hydrocarbon...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

LiMnPO4 Nanoplate Grown via Solid-State Reaction in Molten Hydrocarbon for Li-ion Battery Cathode. LiMnPO4 Nanoplate Grown via Solid-State Reaction in Molten Hydrocarbon for Li-ion...

343

Vibration Spectra of Hydrocarbon Molecules. II. Skeletal Frequencies in Certain Branched Paraffins  

Science Journals Connector (OSTI)

25 October 1949 research-article Vibration Spectra of Hydrocarbon Molecules. II...characteristic frequencies should be assigned as vibrations of the carbon skeleton of these structural...problem of the interpretation of the vibration spectra of hydrocarbons is considered...

1949-01-01T23:59:59.000Z

344

Environmental and Transport Effects on Core Measurements of Water Saturation, Salinity, Wettability, and Hydrocarbon Composition  

E-Print Network [OSTI]

and core surfacing operations can significantly alter the water saturation, salinity, hydrocarbon measurements of water saturation, salinity, hydrocarbon composition, and wettability are critical for accurateSPE 166154 Environmental and Transport Effects on Core Measurements of Water Saturation, Salinity

Torres-VerdĂ­n, Carlos

345

Light hydrocarbons in the surface water of the mid-Atlantic  

Science Journals Connector (OSTI)

During a cruise of RV Polarstern over the Atlantic in September/October 1988, C2?C4 hydrocarbons were measured in surface sea water. The ship passed through three different ocean ... at 8° N and 3° S. Hydrocarbon

C. Plass; R. Koppmann; J. Rudolph

1992-11-01T23:59:59.000Z

346

Is the situation and immediate threat to life and health? Spill/Leak/Release Medical Emergency Fire or Flammable Gas Spill/Leak/Release Medical Emergency Fire or Flammable Gas Chemical Odor? Possible Fire / Natural Gas  

E-Print Network [OSTI]

? Possible Fire / Natural Gas (including chemicals and bio agents") (not including chemicals or bio agents Fire or Flammable Gas Spill/Leak/Release Medical Emergency Fire or Flammable Gas Chemical Odor

347

Growth direction of oblique angle electron beam deposited silicon monoxide thin films identified by optical second-harmonic generation  

SciTech Connect (OSTI)

Oblique angle deposited (OAD) silicon monoxide (SiO) thin films forming tilted columnar structures have been characterized by second-harmonic generation. It was found that OAD SiO leads to a rotationally anisotropic second-harmonic response, depending on the optical angle of incidence. A model for the observed dependence of the second-harmonic signal on optical angle of incidence allows extraction of the growth direction of OAD films. The optically determined growth directions show convincing agreement with cross-sectional scanning electron microscopy images. In addition to a powerful characterization tool, these results demonstrate the possibilities for designing nonlinear optical devices through SiO OAD.

Vejling Andersen, Sřren; Lund Trolle, Mads; Pedersen, Kjeld [Department of Physics and Nanotechnology, Aalborg University, Skjernvej 4A, DK-9220 Aalborg Řst (Denmark)] [Department of Physics and Nanotechnology, Aalborg University, Skjernvej 4A, DK-9220 Aalborg Řst (Denmark)

2013-12-02T23:59:59.000Z

348

Kinetics of the Reduction of Wüstite by Hydrogen and Carbon Monoxide for the Chemical Looping Production of Hydrogen  

E-Print Network [OSTI]

produced could be stored, e.g. by geological sequestration, making the overall process “carbon-neutral”, or “carbon-negative” when biomass is used as fuel. In addition, the hydrogen produced during the oxidation of FexO and metallic Fe in steam can be kept... Kinetics of the reduction of wüstite by hydrogen and carbon monoxide for the chemical looping production of hydrogen Wen Liu a,n, Jin Yang Lim b, Marco A. Saucedo a, Allan N. Hayhurst b, Stuart A. Scott a, J.S. Dennis b a Department of Engineering...

Liu, Wen; Lim, Jin Yang; Saucedo, Marco A.; Hayhurst, Allan N.; Scott, Stuart A.; Dennis, J. S.

2014-08-13T23:59:59.000Z

349

UPTAKE AND LOSS OF PETROLEUM HYDROCARBONS BY THE MUSSEL, MYTILUS EDULIS, IN LABORATORY EXPERIMENTS  

E-Print Network [OSTI]

UPTAKE AND LOSS OF PETROLEUM HYDROCARBONS BY THE MUSSEL, MYTILUS EDULIS, IN LABORATORY EXPERIMENTS ROBERT C. CLARK, JR., AND JOHN S. FINLEY' ABSTRACT Petroleum paraffin hydrocarbons (n-CI4H30 to n-C37H76 system that simulated tides. The mussels were exposed to levels of petroleum hydrocarbons from a surface

350

A 4D Synchrotron X-Ray-Tomography Study of the Formation of Hydrocarbon-  

E-Print Network [OSTI]

hydrocarbons and the growing production of hydrocarbons from low-permeability tight rocks. Quantitative models, University of Oslo, Idaho National Laboratory, and Institute for Energy Technology Summary Recovery of oil from oil shales and the natural primary migration of hydrocarbons are closely related processes

Mazzini, Adriano

351

The Interaction of Carcinogenic Hydrocarbons with Tissues VII. Fractionation of Mouse Skin Proteins  

Science Journals Connector (OSTI)

...Inferaction of Hydrocarbons with Tissues. VII...separation of the water- soluble proteins...in Chart 1, and water-soluble proteins...Interaction of Hydrocarbons with Tissues. VII...noncarcinogenic hydrocarbons could be detected...electrophoretic separation of water-soluble proteins...

G. Rodman Davenport; C. W. Abell; and Charles Heidelberger

1961-06-01T23:59:59.000Z

352

Male-derived cuticular hydrocarbons signal sperm competition intensity and affect ejaculate expenditure in crickets  

Science Journals Connector (OSTI)

...taxa has shown that cuticular hydrocarbons (CHCs), contact pheromones...They were supplied with water and fed cat food ad libitum...between-family variation in male hydrocarbon profiles (Thomas Simmons...variation within the blends of hydrocarbons in this experiment, male...

2009-01-01T23:59:59.000Z

353

Speciation and Quantitation of Hydrocarbons in Gasoline Engine Exhaust  

Science Journals Connector (OSTI)

......laboratory engines or reactors. In this paper we...computer technology have advanced to the state where...2-1 m), and the heavy (C5 -C1 2 ) hydrocarbons...PLOT column with water or heavy hy drocarbons...technology to prevent water vapor from condensing...computer technology have advanced to the state where......

Keith L. Olson; Robert M. Sinkevitch; Thompson M. Sloane

1992-12-01T23:59:59.000Z

354

Hydrocarbon Condensation in Heavy-Duty Diesel Exhaust  

Science Journals Connector (OSTI)

Hydrocarbon Condensation in Heavy-Duty Diesel Exhaust ... The semivolatile mass fraction of diesel exhaust particles was studied using size-resolved on-line techniques (DMA-ELPI; TDMA-ELPI). ... The measured size resolved values of mass transfer imply that condensation, or diffusion-limited mass transfer, plays a major role in driving the volatile matter to the diesel exhaust particles. ...

Jyrki Ristimäki; Kati Vaaraslahti; Maija Lappi; Jorma Keskinen

2007-08-10T23:59:59.000Z

355

High Levels of Carcinogenic Polycyclic Aromatic Hydrocarbons in Mate Drinks  

Science Journals Connector (OSTI)

...leaves and/or exposure to combustion products or formation of ash...analysis of the mainstream smoke chemistry of samples of the U.S. cigarette...comparison of the tumors induced by coal tar and benzo[a]pyrene...Spectrometry Ilex paraguariensis chemistry Polycyclic Hydrocarbons, Aromatic...

Farin Kamangar; Michele M. Schantz; Christian C. Abnet; Renato B. Fagundes; and Sanford M. Dawsey

2008-05-01T23:59:59.000Z

356

Seismic Analysis Using Wavelet Transform for Hydrocarbon Detection  

E-Print Network [OSTI]

data quality is good. This technique can be directly applied to the processed 2D and 3 D pre-stack/post-stack data sets (1) to detect hydrocarbon zones in both clastic and carbonate reservoirs by analyzing the low frequency signals in the decomposed...

Cai, Rui

2012-02-14T23:59:59.000Z

357

Chemical Kinetics of Hydrocarbon Ignition in Practical Combustion Systems  

SciTech Connect (OSTI)

Chemical kinetic factors of hydrocarbon oxidation are examined in a variety of ignition problems. Ignition is related to the presence of a dominant chain branching reaction mechanism that can drive a chemical system to completion in a very short period of time. Ignition in laboratory environments is studied for problems including shock tubes and rapid compression machines. Modeling of the laboratory systems are used to develop kinetic models that can be used to analyze ignition in practical systems. Two major chain branching regimes are identified, one consisting of high temperature ignition with a chain branching reaction mechanism based on the reaction between atomic hydrogen with molecular oxygen, and the second based on an intermediate temperature thermal decomposition of hydrogen peroxide. Kinetic models are then used to describe ignition in practical combustion environments, including detonations and pulse combustors for high temperature ignition, and engine knock and diesel ignition for intermediate temperature ignition. The final example of ignition in a practical environment is homogeneous charge, compression ignition (HCCI) which is shown to be a problem dominated by the kinetics intermediate temperature hydrocarbon ignition. Model results show why high hydrocarbon and CO emissions are inevitable in HCCI combustion. The conclusion of this study is that the kinetics of hydrocarbon ignition are actually quite simple, since only one or two elementary reactions are dominant. However, there are many combustion factors that can influence these two major reactions, and these are the features that vary from one practical system to another.

Westbrook, C.K.

2000-07-07T23:59:59.000Z

358

Energy Conservation Opportunities in Hydrocarbon Resin Manufacturing Facilities  

E-Print Network [OSTI]

"The results of a plant-wide assessment of the manufacturing facilities of Neville Chemical Company, a manufacturer of hydrocarbon resins will be presented in this paper. The project was co-funded by US Department of Energy under its Plant...

Ganji, A. R.; Hackett, B.; Chow, S.; Lonergan, R.; Wimer, J.

359

Fundamental spectroscopic studies of carbenes and hydrocarbon radicals  

SciTech Connect (OSTI)

Highly reactive carbenes and carbon-chain radicals are studied at millimeter wavelengths by observing their rotational spectra. The purpose is to provide definitive spectroscopic identification, accurate spectroscopic constants in the lowest vibrational states, and reliable structures of the key intermediates in reactions leading to aromatic hydrocarbons and soot particles in combustion.

Gottlieb, C.A.; Thaddeus, P. [Harvard Univ., Cambridge, MA (United States)

1993-12-01T23:59:59.000Z

360

Climatically driven emissions of hydrocarbons from marine sediments during deglaciation  

Science Journals Connector (OSTI)

...destabilizing hydrates shown in the lighter...destabilization of methane hydrates and release of...in SBC suggest gas emissions during...investigate the sand-sized fraction...the presence of sand layers (23...hydrocarbons and methane hydrate, which is widely...4) (24). Gas hydrates commonly...

T. M. Hill; J. P. Kennett; D. L. Valentine; Z. Yang; C. M. Reddy; R. K. Nelson; R. J. Behl; C. Robert; L. Beaufort

2006-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "monoxide hydrocarbons odors" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Hydrocarbons Heterogeneous Pyrolysis: Experiments and Modeling for Scramjet Thermal Management  

E-Print Network [OSTI]

1 Hydrocarbons Heterogeneous Pyrolysis: Experiments and Modeling for Scramjet Thermal Management : United States (2008)" #12;2 I. Introduction One of the main issues of the development of scramjet, an air to the endothermicity of its thermal decomposition. Because of the large heat load found in a scramjet, engine

Paris-Sud XI, Université de

362

Hydrocarbon saturation determination using acoustic velocities obtained through casing  

DOE Patents [OSTI]

Compressional and shear velocities of earth formations are measured through casing. The determined compressional and shear velocities are used in a two component mixing model to provides improved quantitative values for the solid, the dry frame, and the pore compressibility. These are used in determination of hydrocarbon saturation.

Moos, Daniel (Houston, TX)

2010-03-09T23:59:59.000Z

363

Increased olefins production via recovery of refinery gas hydrocarbons  

SciTech Connect (OSTI)

In the process of catalytically cracking heavy petroleum fractions to make gasoline and light fuel oil, by-product waste gases are also generated. The waste gases, normally used as fuel, are themselves rich sources of ethylene, propylene and other light hydrocarbons which can be recovered inexpensively via a cryogenic dephlegmator process. This gas separation technique is exploited in a system, in operation since spring of 1987, which reclaims C/sub 2/+ hydrocarbons from a refinery gas. The reclamation process bolsters production in a nearby ethylene plant. Causing no disruption of ethylene plant operations, the cryogenic hydrocarbon recovery system functions smoothly with existing systems. The dephlegmation unit operation melds distillation and heat transfer processes in a single easily-controlled step which boosts the hydrocarbon purity and recovery above the levels profitably achievable with conventional cryogenic separation techniques. Very attractive operating economics follow from high purity, high recovery, and high energy efficiency. This paper discusses process concepts, economic benefits, plant operation, and early performance results.

Bernhard, D.P.; Rowles, H.C.; Moss, J.A.; Pickering, J.L. Jr.

1988-01-01T23:59:59.000Z

364

THERMOCATALYTIC CO2-FREE PRODUCTION OF HYDROGEN FROM HYDROCARBON FUELS  

E-Print Network [OSTI]

THERMOCATALYTIC CO2- FREE PRODUCTION OF HYDROGEN FROM HYDROCARBON FUELS N. Muradov Florida Solar Energy Center 1679 Clearlake Road, Cocoa, Florida 32922 tel. 321-638-1448, fax. 321-638-1010, muradov (except for the start-up operation). This results in the following advantages: (1) no CO/CO2 byproducts

365

Biodegradation of total petroleum hydrocarbon (TPH) in Jordanian petroleum sludge  

Science Journals Connector (OSTI)

Bioremediation, or the use of micro-organisms to decontaminate soil or groundwater, is being increasingly seen as an effective, environment-friendly treatment for oil-contaminated sites. In this study, the results are presented concerning a laboratory screening of several natural bacterial consortia and laboratory tests to establish the performance in degradation of hydrocarbons contained in oily sludge from the Jordan Oil Refinery Plant. As a result of the laboratory screening, 18 isolates were selected and grouped into two main clusters; cluster 1 containing 12 isolates grown at 43°C, and cluster 2 containing six isolates grown at 37°C. Three natural bacterial consortia with ability to degrade total petroleum hydrocarbons (TPH) were prepared from these isolates. Experiments were conducted in Erlenmeyer flasks under aerobic conditions, with TPH removal percentage varying from 5.9% to 25.1%, depending upon consortia type and concentration. Consortia 7B and 13B exhibited the highest TPH removal percentages of 25% and 23%, respectively before nutrient addition. TPH removal rate was enhanced after addition of nutrients to incubated flasks. The highest TPH reduction (37%) was estimated after addition of a combination of nitrogen, phosphorus and sulphur to consortia 7B. This is the first report concerning biological treatment of total petroleum hydrocarbon by bacteria isolated from the oil refinery plant, where it lay the ground for full integrated studies recommended for hydrocarbon degradation that assist in solving sludge problems.

Bassam Mrayyan; Mohammad Battikhi

2004-01-01T23:59:59.000Z

366

Hydrocarbons in rift basins: the role of stratigraphy  

Science Journals Connector (OSTI)

...succession that causes the shales to reach thermal maturity and generate hydrocarbons. Simple...T. J. 1988 Rift basins of interior Sudan--petroleum exploration and discovery...basins? Is that what we could call the thermal subsidence phase? J. J. Lambiase...

1999-01-01T23:59:59.000Z

367

Application of Resource-Ratio Theory to Hydrocarbon Biodegradation  

Science Journals Connector (OSTI)

Application of Resource-Ratio Theory to Hydrocarbon Biodegradation ... We suggest that the procedures outlined here can be used to help guide practical decisions about the nutrients that are most likely to be growth-limiting and help define the subsequent nutrient application rates. ...

Val H. Smith; David W. Graham; Dale D. Cleland

1998-09-12T23:59:59.000Z

368

Theoretical studies of hydrocarbon combustion chemistry. Annual progress report  

SciTech Connect (OSTI)

The author reports here the results of DZP CISD calculations for methylcarbene. Geometry, symmetry, and vibrational modes for the radical are reported for both the singlet and the triplet state. Future work will focus on the ethyl radical-oxygen interaction relevant to hydrocarbon combustion.

Schaefer, H.F. III

1994-08-01T23:59:59.000Z

369

FROM INTERSTELLAR POLYCYCLIC AROMATIC HYDROCARBONS AND ICE TO ASTROBIOLOGY  

E-Print Network [OSTI]

photolysis of these ices produces a host of new compounds, some of which show intriguing prebiotic behavior1 FROM INTERSTELLAR POLYCYCLIC AROMATIC HYDROCARBONS AND ICE TO ASTROBIOLOGY LOUIS J. ALLAMANDOLA, the concept of ices in dense molecular clouds ignored, and the notion of large, abundant, gas phase, carbon

370

Novel Carbon Monoxide Sensor for PEM Fuel Cell Systems C.T. Holt, A.-M. Azad, S.L. Swartz, W.J. Dawson, and P.K. Dutta  

E-Print Network [OSTI]

Novel Carbon Monoxide Sensor for PEM Fuel Cell Systems C.T. Holt, A.-M. Azad, S.L. Swartz, W The importance of carbon monoxide sensors for automotive PEM fuel cell systems is illustrated by a schematic will protect the PEM fuel cell stack; detection of CO is extremely important because too much CO will poison

Azad, Abdul-Majeed

371

Reclamation and groundwater remediation at a hydrocarbon site in Alaska  

SciTech Connect (OSTI)

As part of a joint hydrocarbon cleanup project between Unocal and Marathon, we have initiated the use of constructed wetlands for restoration of the 40-acre Poppy Lane gravel pit located near Kenai, Alaska. Gravel excavated from this site was used to construct roads and drilling pads in the 1960`-70`s. During this period it was also used as a refuse dump for waste from the Kenai gas field and from local residents. The bulk wastes were removed and pockets of oily sand were removed, treated and returned to a stockpile on the site. This left the site with residual pockets of hydrocarbon-impacted sand (<1000 TPH) plus traces of hydrocarbon contamination in the uppermost shallow groundwater flowing through the outwash gravels. The final part of the cleanup will be land restoration and bioremediation of the final traces of hydrocarbons, which are predominantly diesel-range. High resolution gas chromatography analysis indicated that common plants already growing on the site (willow, cottonwood, and alder) did not concentrate diesel-range petroleum hydrocarbons in their foliage when growing in soils containing these contaminants. As part of the planned restoration and shallow groundwater remediation, two 1/3 acre test plots were constructed to promote in-situ biodegradation processes. In spring 1995, the first test, a tree root-barrier plot, was planted with dormant cuttings of four native wetland tree and shrub species, which were planted to depths up to five feet. Alder and elderberry did not succeed under any conditions, nor did any species planted in standing water. For cottonwood and willow species, approximately one half of each rooted and survived. When the water table dropped the second year, the willow cuttings rooted deeper in the vadose zone, while cottonwood did not. As a result of these findings, a tree root-barrier wetland is not considered to be a viable option for groundwater treatment at Poppy Lane.

Ririe, G.T. [Unocal, Brea, CA (United States); Drake, L.D. [Univ. of Iowa, Iowa City, IA (United States); Olson, S.S. [Marathon Oil, Tyler, TX (United States)

1997-12-31T23:59:59.000Z

372

Process for using alkyl substituted C8-C10 aromatic hydrocarbons as preferential physical solvents for selective processing of hydrocarbon gas streams  

SciTech Connect (OSTI)

This patent describes a process for the removal of hydrocarbon gas liquids, comprising hydrocarbons heavier than methane, from a hydrocarbon gas stream. The improvement consists of selectively extracting the hydrocarbon gas liquids from the hydrocarbon gas stream with a preferential physical solvent which provides selective capability for recovery according to the selected degree of (a) ethane in amounts ranging from 2-98%, (b) propane in amounts ranging from 2-99%, (c) butane in amounts ranging from 2-100%, or (d) pentanes and higher molecular weight hydrocarbons in amounts ranging up to 100% which comprises: A. selectively extracting and stripping the hydrocarbon gas stream with the physical solvent to produce a residue hydrocarbon gas stream of pipeline specifications and a rich solvent stream containing ethane and heavier hydrocarbon components, the preferential physical solvent being: (1) rich in C/sub 8/-C/sub 10/ aromatic compounds having methyl, ethyl, or propyl aliphatic groups and (2) selective for ethane and heavier hydrocarbon components of the gas stream such that: (a) the relative volatility of methane over ethane is at least 5.0 and the hydrocarbon loading capacity, defined as solubility of ethane in solvent, is at least 0.25 standard cubic feet of ethane per gallon of solvent, or (b) the preferential factor determined by the multiplication of relative volatility of methane over ethane by the solubility of ethane in solvent, in standard cubic feet of ethane per gallon of solvent, of at least 1.25; and B. distilling the rich solvent to produce the hydrocarbon gas liquids and the physical solvent.

Mehra, Y.R.

1987-09-08T23:59:59.000Z

373

Interaction of Carcinogenic Hydrocarbons with Tissues: VIII. Binding of Tritium-labeled Hydrocarbons to the Soluble Proteins of Mouse Skin  

Science Journals Connector (OSTI)

...treated as described in "Materials and Methods." A demonstration...of the unbound radio active hydrocarbon was removed...migrated toward the cathode, a neutral in dicator...pro teins toward the cathode was affected by electro...dermis as described in "Materials and Methods." The...

C. W. Abell and Charles Heidelberger

1962-09-01T23:59:59.000Z

374

J. Phys. Chem. 1994, 98, 11213-11219 11213 Vibrational Dynamics of Carbon Monoxide at the Active Site of Myoglobin: Picosecond  

E-Print Network [OSTI]

J. Phys. Chem. 1994, 98, 11213-11219 11213 Vibrational Dynamics of Carbon Monoxide at the Active Physics Laboratory, Stanford University, Stanford, Califomia 94305 Received: April 27, 1994: In Final Form at Urbana-Champaign. Deparlment of Chemistry, Sfanford University. Hansen ExperimentaJ Physics Laboratory

Fayer, Michael D.

375

Impact of the Presence of Carbon Monoxide and Carbon Dioxide on Gas Oil Hydrotreatment: Investigation on Liquids from Biomass Cotreatment with Petroleum Cuts  

Science Journals Connector (OSTI)

Impact of the Presence of Carbon Monoxide and Carbon Dioxide on Gas Oil Hydrotreatment: Investigation on Liquids from Biomass Cotreatment with Petroleum Cuts ... A potential way of utilizing these bioliquids as fuels could be the direct hydrotreatment(6) or the cohydrotreatment with petroleum fractions,(7) such as atmospheric gas oils, to achieve the technical and environmental fuel standards, especially in terms of sulfur content. ...

Ana Pinheiro; Nathalie Dupassieux; Damien Hudebine; Christophe Geantet

2011-01-18T23:59:59.000Z

376

Process for the production of hydrogen and carbonyl sulfide from hydrogen sulfide and carbon monoxide using a metal boride, nitride, carbide and/or silicide catalyst  

SciTech Connect (OSTI)

Hydrogen and carbonyl sulfide are produced by a process comprising contacting gaseous hydrogen sulfide with gaseous carbon monoxide in the presence of a metal boride, carbide, nitride and/or silicide catalyst, such as titanium carbide, vanadium boride, manganese nitride or molybdenum silicide.

McGuiggan, M.F.; Kuch, P.L.

1984-05-08T23:59:59.000Z

377

Apparatus for removing hydrocarbon contaminants from solid materials  

DOE Patents [OSTI]

A system for removing hydrocarbons from solid materials. Contaminated solids are combined with a solvent (preferably terpene based) to produce a mixture. The mixture is washed with water to generate a purified solid product (which is removed from the system) and a drainage product. The drainage product is separated into a first fraction (consisting mostly of contaminated solvent) and a second fraction (containing solids and water). The first fraction is separated into a third fraction (consisting mostly of contaminated solvent) and a fourth fraction (containing residual solids and water). The fourth fraction is combined with the second fraction to produce a sludge which is separated into a fifth fraction (containing water which is ultimately reused) and a sixth fraction (containing solids). The third fraction is then separated into a seventh fraction (consisting of recovered solvent which is ultimately reused) and an eighth fraction (containing hydrocarbon waste).

Bala, Gregory A. (Idaho Falls, ID); Thomas, Charles P. (Idaho Falls, ID)

1996-01-01T23:59:59.000Z

378

Method for removing hydrocarbon contaminants from solid materials  

DOE Patents [OSTI]

A system for removing hydrocarbons from solid materials. Contaminated solids are combined with a solvent (preferably terpene based) to produce a mixture. The mixture is washed with water to generate a purified solid product (which is removed from the system) and a drainage product. The drainage product is separated into a first fraction (consisting mostly of contaminated solvent) and a second fraction (containing solids and water). The first fraction is separated into a third fraction (consisting mostly of contaminated solvent) and a fourth fraction (containing residual solids and water). The fourth fraction is combined with the second fraction to produce a sludge which is separated into a fifth fraction (containing water which is ultimately reused) and a sixth fraction (containing solids). The third fraction is then separated into a seventh fraction (consisting of recovered solvent which is ultimately reused) and an eighth fraction (containing hydrocarbon waste).

Bala, Gregory A. (Idaho Falls, ID); Thomas, Charles P. (Idaho Falls, ID)

1995-01-01T23:59:59.000Z

379

Catalysts for conversion of methane to higher hydrocarbons  

DOE Patents [OSTI]

Catalysts for converting methane to higher hydrocarbons such as ethane and ethylene in the presence of oxygen at temperatures in the range of about 700.degree. to 900.degree. C. are described. These catalysts comprise calcium oxide or gadolinium oxide respectively promoted with about 0.025-0.4 mole and about 0.1-0.7 mole sodium pyrophosphate. A preferred reaction temperature in a range of about 800.degree. to 850.degree. C. with a preferred oxygen-to-methane ratio of about 2:1 provides an essentially constant C.sub.2 hydrocarbon yield in the range of about 12 to 19 percent over a period of time greater than about 20 hours.

Siriwardane, Ranjani V. (Morgantown, WV)

1993-01-01T23:59:59.000Z

380

Biological Conversion of Sugars to Hydrocarbons Technology Pathway  

SciTech Connect (OSTI)

In support of the Bioenergy Technologies Office, the National Renewable Energy Laboratory (NREL) and the Pacific Northwest National Laboratory (PNNL) are undertaking studies of biomass conversion technologies to identify barriers and target research toward reducing conversion costs. Process designs and preliminary economic estimates for each of these pathway cases were developed using rigorous modeling tools (Aspen Plus and Chemcad). These analyses incorporated the best information available at the time of development, including data from recent pilot and bench-scale demonstrations, collaborative industrial and academic partners, and published literature and patents. This technology pathway case investigates the biological conversion of biomass derived sugars to hydrocarbon biofuels, utilizing data from recent literature references and information consistent with recent pilot scale demonstrations at NREL. Technical barriers and key research needs have been identified that should be pursued for the pathway to become competitive with petroleum-derived gasoline, diesel and jet range hydrocarbon blendstocks.

Davis, Ryan; Biddy, Mary J.; Tan, Eric; Tao, Ling; Jones, Susanne B.

2013-03-31T23:59:59.000Z

Note: This page contains sample records for the topic "monoxide hydrocarbons odors" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Interaction of copper oxides with reaction medium in heterogeneous catalytic oxidation of carbon monoxide by molecular oxygen. IV. IR spectroscopic study of carbon monoxide interaction with copper oxide surface  

SciTech Connect (OSTI)

An IR spectroscopic study has been made of the interaction of CO with CuO prepared in different ways, and the interaction of O/sub 2/ with carbon monoxide preadsorbed on CuO. A number of Cu/sup +/CO surface complexes have been detected (2114-2148 cm/sup -1/) with a heat of adsorption about 79.5-180 kJ/mole. From an analysis of the nature of these complexes, we have evaluated the processes taking place on the CuO surface when it interacts with CO and have compared the properties of massive CuO with those of CuO on oxide supports. The data are interpreted on the assumption that extended defects - dislocations - exist and play an important role, determining to a considerable degree the properties of the massive CuO in the reaction of CO oxidation.

Lokhov, Y.A.; Popovskii, V.V.; Sadykov, V.A.; Tikhov, S.F.

1985-08-01T23:59:59.000Z

382

Faults as potential hydrocarbon barriers, Arroyo Grande, California  

E-Print Network [OSTI]

OPTICALMICROSCOPY. Composition. Grain Size Characteristics Deformation Fluorescence Observations . Microprobe Observations. CAPILLARY PRESSURE. Sample Preparation. Test Procedures. Interpretation of the Mercury Injection Capillary Pressure Curve... rim of hydrocarbons seen on the grains. 41 , , 42 25 Photomicrograph of one of the microcracks that contains oil, 43 26 Microprobe image of the zone of quartz cement seen in the quarry, 27 Mercury injection capillary pressure apparatus, 45 48...

Switek, Daniel Paul

2012-06-07T23:59:59.000Z

383

THE INFRARED SPECTROSCOPY OF NEUTRAL POLYCYCLIC AROMATIC HYDROCARBON CLUSTERS  

SciTech Connect (OSTI)

The mid-infrared spectra of neutral homogeneous polycyclic aromatic hydrocarbon (PAH) clusters have been computed using density functional theory including an empirical correction for dispersion. The C-H out-of-plane bending modes are redshifted for all the clusters considered in this work. The magnitude of the redshift and the peak broadening are dependent on PAH size, shape, and on the PAH arrangement in the cluster.

Ricca, Alessandra [Carl Sagan Center, SETI Institute, 189 Bernardo Avenue, Suite 100, Mountain View, CA 94043 (United States); Bauschlicher, Charles W. Jr. [Entry Systems and Technology Division, Mail Stop 230-3, NASA Ames Research Center, Moffett Field, CA 94035 (United States); Allamandola, Louis J., E-mail: Alessandra.Ricca-1@nasa.gov, E-mail: Charles.W.Bauschlicher@nasa.gov [Space Science Division, Mail Stop 245-6, NASA Ames Research Center, Moffett Field, CA 94035 (United States)

2013-10-10T23:59:59.000Z

384

Method and apparatus for production of subsea hydrocarbon formations  

DOE Patents [OSTI]

A well tender system for controlling, separating, storing and offloading well fluids produced from subsea hydrocarbon formations. The system comprises a vertically aligned series of tethered cylindrical tanks which are torsionally stabilized by flexible catenary production riser and expert riser bundles, and serviced by separate catenary pipe bundles. Piles are secured to the seabed, each pile assembly being pivotally connected to a lower rigid tendon, which is in turn connected to tendons arranged about the periphery of the interconnected cylindrical tanks.

Blandford, Joseph W. (15 Mott La., Houston, TX 77024)

1992-01-01T23:59:59.000Z

385

Method and apparatus for production of subsea hydrocarbon formations  

DOE Patents [OSTI]

A well tender system for controlling, separating, storing and offloading well fluids produced from subsea hydrocarbon formations. The system comprises a vertically aligned series of tethered cylindrical tanks which are torsionally stabilized by flexible catenary production riser and export riser bundles, and serviced by separate catenary pipe bundles. Piles are secured to the seabed, each pile assembly being pivotally connected to a lower rigid tendon, which is in turn connected to tendons arranged about the periphery of the interconnected cylindrical tanks.

Blandford, Joseph W. (15 Mott La., Houston, TX 77024)

1994-01-01T23:59:59.000Z

386

Petroleum hydrocarbon-degrading bacteria in the Galveston Bay system  

E-Print Network [OSTI]

PETROLEUM HYDRQCARBOiV-DEGRADING BACTERIA IN THE GALVESTON BAY SYSTEM A Thesis by STEVEN JAMES SCHROPP Submitted to the Graduate College of Texas ASM University in partial fulfillment of the requirement for the degree of MASTER OF SCIFNCE... December 1979 Major Subject: Biology PETROLEUM HYDROCARBON-DEGRADING BACTERIA IN THE GALVESTON BAY SYSTEM A Thesis by STEVEN JAMES SCHROPP Approved as to style and content by: (Co-Chairman of Committee) '( ~CA. ( -Chairman of Committee) (Head...

Schropp, Steven James

1979-01-01T23:59:59.000Z

387

Production of valuable hydrocarbons by flash pyrolysis of oil shale  

DOE Patents [OSTI]

A process for the production of gas and liquid hydrocarbons from particulated oil shale by reaction with a pyrolysis gas at a temperature of from about 700/sup 0/C to about 1100/sup 0/C, at a pressure of from about 400 psi to about 600 psi, for a period of about 0.2 second to about 20 seconds. Such a pyrolysis gas includes methane, helium, or hydrogen. 3 figs., 3 tabs.

Steinberg, M.; Fallon, P.T.

1985-04-01T23:59:59.000Z

388

Direct production of fractionated and upgraded hydrocarbon fuels from biomass  

SciTech Connect (OSTI)

Multistage processing of biomass to produce at least two separate fungible fuel streams, one dominated by gasoline boiling-point range liquids and the other by diesel boiling-point range liquids. The processing involves hydrotreating the biomass to produce a hydrotreatment product including a deoxygenated hydrocarbon product of gasoline and diesel boiling materials, followed by separating each of the gasoline and diesel boiling materials from the hydrotreatment product and each other.

Felix, Larry G.; Linck, Martin B.; Marker, Terry L.; Roberts, Michael J.

2014-08-26T23:59:59.000Z

389

Catalyst and process for steam-reforming of hydrocarbons  

SciTech Connect (OSTI)

An improved catalyst and an improved process for use of the catalyst in the steam-hydrocarbon reforming reaction are disclosed. The catalyst comprises a group VIII metal on a cylindrical ceramic support consisting essentially of alpha alumina and having a plurality of gas passages extending axially therethrough. These supported catalysts display a higher geometric surface area and a lower pressure drop than do standard rings.

Atwood, K.; Merriam, J.S.; Wright, J.H.

1980-11-11T23:59:59.000Z

390

Polycyclic aromatic hydrocarbon distributions in Mississippi Fan sediments  

E-Print Network [OSTI]

. Sandberg, B. A. , University of Colorado Chairman of Advisory Committee: Dr. James M. Brooks Polycyclic aromatic hydrocarbon (PAH) distributions in Upper Pleistocene sediments of the Mississippi Fan and two intraslope basins in the Gulf of Mexico... chemistries is separate phase migration driven by hydrodynamic flow upward along fault planes. The same variables at intraslope basin sites are highly altered, possibly due to extensive gravity slump faulting. High- performance liquid chromatography...

Sandberg, William Allan

2012-06-07T23:59:59.000Z

391

Aerobic microorganism for the degradation of chlorinated aliphatic hydrocarbons  

DOE Patents [OSTI]

A chlorinated aliphatic hydrocarbon-degrading microorganism, having American Type Culture Collection accession numbers ATCC 53570 and 53571, in a biologically pure culture aseptically collected from a deep subsurface habitat and enhanced, mineralizes trichloroethylene and tetrachloroethylene to HCl, H.sub.2 O and Co.sub.2 under aerobic conditions stimulated by methane, acetate, methanol, tryptone-yeast extract, propane and propane-methane.

Fliermans, Carl B. (Augusta, GA)

1989-01-01T23:59:59.000Z

392

Irregular spacing of heat sources for treating hydrocarbon containing formations  

DOE Patents [OSTI]

A method for treating a hydrocarbon containing formation includes providing heat input to a first section of the formation from one or more heat sources located in the first section. Fluids are produced from the first section through a production well located at or near the center of the first section. The heat sources are configured such that the average heat input per volume of formation in the first section increases with distance from the production well.

Miller, David Scott (Katy, TX); Uwechue, Uzo Philip (Houston, TX)

2012-06-12T23:59:59.000Z

393

Federal Environmental Regulations Impacting Hydrocarbon Exploration, Drilling, and Production Operations  

SciTech Connect (OSTI)

Waste handling and disposal from hydrocarbon exploration, drilling, and production are regulated by the US Environmental Protection Agency (EPA) through federal and state regulations and/or through implementation of federal regulations. Some wastes generated in these operations are exempt under the Resource Conservation and Recovery Act (RCRA) but are not exempt under the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA), Superfund Amendments and Reauthorization Act (SARA), and other federal environmental laws. Exempt wastes remain exempt only if they are not mixed with hazardous wastes or hazardous substances. Once mixture occurs, the waste must be disposed as a hazardous material in an approved hazardous waste disposal facility. Before the Clean Air Act as amended in 1990, air emissions from production, storage, steam generation, and compression facilities associated with hydrocarbon exploration, drilling, and production industry were not regulated. A critical proposed regulatory change which will significantly effect Class II injection wells for disposal of produced brine and injection for enhanced oil recovery is imminent. Federal regulations affecting hydrocarbon exploration, drilling and production, proposed EPA regulatory changes, and a recent significant US Court of Appeals decision are covered in this report. It appears that this industry will, in the future, fall under more stringent environmental regulations leading to increased costs for operators.

Carroll, Herbert B.; Johnson, William I.

1999-04-27T23:59:59.000Z

394

Paleotopography and hydrocarbon accumulation: Williston, Powder River, and Denver basins  

SciTech Connect (OSTI)

Recent geomorphic analyses of 1:24,000 scale topographic maps in the three major basins of the northern Great Plains have disclosed a persistent system of basement paleotopographic features that trend north-northeast throughout the region. Superimposed across this system and subtly influenced by it, are the northwesterly trending Laramide structural features. Paleozoic depositional patterns have been strongly influenced by the paleoridge and trough system formed by the north-northeast features. Mesozoic deposition has also been affected by the ancient subsurface system but in a more subtle manner. Many of the Paleozoic and Mezoxoic hydrocarbon locations in the three basins appear to be the results of paleotopographic control on hydrocarbon accumulation sites. This affect ranges from Paleozoic reef sites in the Williston basin through paleotrough localization of Pennsylvanian Minnelusa production in the Powder River basin to fractured Cretaceous Niobrara production at the Silo field in the Denver basin. Basement paleotopography is the underlying factor in all deposition and subsequent hydrocarbon migration in any basin. As such, it should be considered a major factor in the exploration for oil and gas.

Thomas, G.E. (Thomas and Associates, Denver, CO (United States))

1991-06-01T23:59:59.000Z

395

Resilience of gas-phase anharmonicity in the vibrational response of adsorbed carbon monoxide and breakdown under electrical conditions  

E-Print Network [OSTI]

In surface catalysis, the adsorption of carbon monoxide on transition-metal electrodes represents the prototype of strong chemisorption. Notwithstanding significant changes in the molecular orbitals of adsorbed CO, spectroscopic experiments highlight a close correlation between the adsorbate stretching frequency and equilibrium bond length for a wide range of adsorption geometries and substrate compositions. In this work, we study the origins of this correlation, commonly known as Badger's rule, by deconvoluting and examining contributions from the adsorption environment to the intramolecular potential using first-principles calculations. Noting that intramolecular anharmonicity is preserved upon CO chemisorption, we show that Badger's rule for adsorbed CO can be expressed solely in terms of the tabulated Herzberg spectroscopic constants of isolated CO. Moreover, although it had been previously established using finite-cluster models that Badger's rule is not affected by electrical conditions, we find here th...

Dabo, Ismaila

2012-01-01T23:59:59.000Z

396

Adsorbate effects on a mixed-valence compound: Carbon monoxide chemisorption on CeIr/sub 2/  

SciTech Connect (OSTI)

We have studied the effects of stoichiometry change and CO chemisorption on the surface electronic structure of the mixed-valence compound CeIr/sub 2/. We show that the surface iridium to cerium ratio can be varied by changing sample temperature while sputtering. Carbon monoxide is found to adsorb 80% molecularly on the surface and cause a mild surface oxidation which induces a shift of electron density into available cerium f orbitals. Peaks due to the 4sigma, 1..pi.., and 5sigma CO molecular orbitals appear at different binding energies than those due to molecular CO on the pure iridium surface. This binding-energy shift as well as the high percentage of molecular CO on the surface (CO adsorption on pure cerium is completely dissociative) points toward a surface which has lost much of the elemental character of its two constituents upon compound formation.

Lindquist, J.M.; Hemminger, J.C.; Lawrence, J.

1987-10-15T23:59:59.000Z

397

Auger electron spectroscopy, electron loss spectroscopy and low energy electron diffraction of oxygen and carbon monoxide adsorption of Pd films  

SciTech Connect (OSTI)

The adsorption of oxygen and carbon monoxide at room temperature on polycrystalline and (111) monocrystalline thin films of Pd vapor deposited on mice was investigated by AES, ELS, and LEED. The results show that adsorbate coverage depends strongly on surface microstructure, composition, and topography. Polycrystalline or Cl contaminated surfaces adsorb large amounts of the gases, while flat, monocrystalline surfaces will adsorb almost none. These results are quite different from those observed earlier using sputter etched and annealed bulk single cyrstals where adsorbate superlattices formed after rather low gaseous exposures. In the present work no superlattices were observed after exposures ranging up to several thousand langmuirs. The contradictory results obtained in the two cases are attributed to probable differences in surface microtopography and microstructure.

Vook, R.W.; De Cooman, B.C.; Vankar, V.D.

1983-01-01T23:59:59.000Z

398

Remarkable catalytic activity of cobalt tetraphenylporphyrin modified on a titania for the oxidation of carbon monoxide below room temperature  

SciTech Connect (OSTI)

CoTPP on TiO/sub 2/-120s modified at 250 /sup 0/C under vacuum catalytically oxidized carbon monoxide rapidly with oxygen even at -79/sup 0/C. Its catalytic activity was incomparably higher than that of commercial Hopcalite. Comparison of its catalytic performance with those of the same catalyst or different TiO/sub 2/ supporting catalyst both evacuated at 200 /sup 0/C revealed unique features of the present catalyst in terms of its oxygen adsorption, the poisoning of adsorbed oxygen, and the insolubility of the complex in benzene. Both significant structural modification of the complex and its strong interaction with properly dehydrated TiO/sub 2/-120s brought about by evacuation at 250 /sup 0/C may induce such extraordinary activity. 14 references, 4 figures, 5 tables.

Mochida, I.; Iwai, Y.; Kamo, T.; Fujitsu, H.

1985-12-05T23:59:59.000Z

399

Adsorbate effects on a mixed-valence compound: carbon monoxide chemisorption on CeIr/sub 2/  

SciTech Connect (OSTI)

The authors studied the effects of stoichiometry change and CO chemisorption on the surface electronic structure of the mixed-valence compound CeIr/sub 2/. It is shown that the surface iridium to cerium ratio can be varied by changing sample temperature while sputtering. Carbon monoxide is found to adsorb 80% molecularly on the surface and cause a mild surface oxidation which induces a shift of electron density into available cerium f orbitals. Peaks due to the 4 sigma, 1 pi, and 5 sigma CO molecular orbitals appear at different binding energies than those due to molecular CO on the pure iridium surface. This binding-energy shift as well as the high percentage of molecular CO on the surface (CO adsorption on pure cerium is completely dissociative) points toward a surface which has lost much of the elemental character of its two constituents upon compound formation.

Lindquist, J.M.; Hemminger, J.C.

1987-10-15T23:59:59.000Z

400

Method and apparatus for monitoring a hydrocarbon-selective catalytic reduction device  

DOE Patents [OSTI]

A method for monitoring a hydrocarbon-selective catalytic reactor device of an exhaust aftertreatment system of an internal combustion engine operating lean of stoichiometry includes injecting a reductant into an exhaust gas feedstream upstream of the hydrocarbon-selective catalytic reactor device at a predetermined mass flowrate of the reductant, and determining a space velocity associated with a predetermined forward portion of the hydrocarbon-selective catalytic reactor device. When the space velocity exceeds a predetermined threshold space velocity, a temperature differential across the predetermined forward portion of the hydrocarbon-selective catalytic reactor device is determined, and a threshold temperature as a function of the space velocity and the mass flowrate of the reductant is determined. If the temperature differential across the predetermined forward portion of the hydrocarbon-selective catalytic reactor device is below the threshold temperature, operation of the engine is controlled to regenerate the hydrocarbon-selective catalytic reactor device.

Schmieg, Steven J; Viola, Michael B; Cheng, Shi-Wai S; Mulawa, Patricia A; Hilden, David L; Sloane, Thompson M; Lee, Jong H

2014-05-06T23:59:59.000Z

Note: This page contains sample records for the topic "monoxide hydrocarbons odors" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

A Crossed Molecular Beam and Ab-Initio Investigation of the Reaction of Boron Monoxide (BO; X2  

E-Print Network [OSTI]

considerably more energy than conventional hydrocarbons such as JP-8 jet fuel, that is, 837 kJ mol-1 versus 230 by combustion of any element in the periodic system. At room temperature and pressure, the gravimetric and volumetric heats of oxidation of boron (58.7 kJ g-1 and 137.5 kJ cm-3 ) are greater than aluminum (31.0 kJ g

Kaiser, Ralf I.

402

Apparatus and method for rapid separation and detection of hydrocarbon fractions in a fluid stream  

DOE Patents [OSTI]

An apparatus and method for rapid fractionation of hydrocarbon phases in a sample fluid stream are disclosed. Examples of the disclosed apparatus and method include an assembly of elements in fluid communication with one another including one or more valves and at least one sorbent chamber for removing certain classifications of hydrocarbons and detecting the remaining fractions using a detector. The respective ratios of hydrocarbons are determined by comparison with a non separated fluid stream.

Sluder, Charles S.; Storey, John M.; Lewis, Sr., Samuel A.

2013-01-22T23:59:59.000Z

403

A study of the structure of the hydrocarbons of primary hard-coal tar  

SciTech Connect (OSTI)

The hydrocarbons isolated from primary hard-coal (G/sub 6/ gas coal) tar have been investigated by a combination of physicochemical and chemical methods. It has been established that the hydrocarbons boiling up to 573 K are mainly aliphatic, hydroaromatic, and naphthenic and are aromatic only to a smaller degree. Molecular and presumable structural formulas of the oxygen compounds isolated from the 473-573 K hydrocarbon fraction have been derived.

Platonov, V.V.; Gerasimova, N.I.; Ivleva, L.N.; Klyavina, O.A.; Vishnyakov, S.N.

1985-01-01T23:59:59.000Z

404

Initiation Mechanisms and Kinetics of Pyrolysis and Combustion of JP-10 Hydrocarbon Jet Fuel  

Science Journals Connector (OSTI)

Initiation Mechanisms and Kinetics of Pyrolysis and Combustion of JP-10 Hydrocarbon Jet Fuel ... We found that the primary decomposition reactions involve either (1) dissociation of ethylene from JP-10, resulting in the formation of a C8 hydrocarbon intermediate, or (2) the production of two C5 hydrocarbons. ... Heats of combustion (kcal/mole) were measured via O bomb calorimetry; adamantane (I) (c), -1441.95 ...

Kimberly Chenoweth; Adri C. T. van Duin; Siddharth Dasgupta; William A. Goddard III

2009-02-11T23:59:59.000Z

405

Characterizing and Biological Monitoring of Polycyclic Aromatic Hydrocarbons in Exposures to Diesel Exhaust  

Science Journals Connector (OSTI)

Characterizing and Biological Monitoring of Polycyclic Aromatic Hydrocarbons in Exposures to Diesel Exhaust ... Diesel and Gasoline Engine Exhausts and Some Nitroarenes; IARC:? Lyon, France 1989. ...

Wei Huang; Thomas J. Smith; Long Ngo; Tong Wang; Hongqiao Chen; Fanggu Wu; Robert F. Herrick; David C. Christiani; Hui Ding

2007-03-16T23:59:59.000Z

406

Naphthenic/paraffinic hydrocarbons of residual lube stock from West Siberian crudes  

SciTech Connect (OSTI)

The lube stocks from West Siberian crudes are characterized by high contents of aromatic hydrocarbons and by high viscosity indexes of the naphthenic/paraffinic and aromatic hydrocarbons. Mass spectrometric analysis showed that isoparaffins account for one-third of the total naphthenic/paraffinic hydrocarbons. The study showed that the naphthenic/paraffinic hydrocarbons of the residual lube stock from West Siberia crudes, even with a variation of molecular weight over broad limits, are relatively uniform in composition. They consist mainly of isoparaffinic and monocyclic and noncondensed naphthenic structures.

Detusheva, E.P.; Bogdanov, Sh.K.; Khramtsova, L.P.; Nekrasova, A.V.; Shkol'nikov, V.M.

1983-03-01T23:59:59.000Z

407

E-Print Network 3.0 - abundant accessible hydrocarbons Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Functionalization: An Energy Frontier Research... such as hydrocarbons, dioxygen, water, carbon dioxide and dihydrogen are central to new technologies for the use... of...

408

E-Print Network 3.0 - aromatic hydrocarbon exhaust Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Page: << < 1 2 3 4 5 > >> 1 Quantification of Local Ozone Production Attributable to Automobile Hydrocarbon Emissions Summary: : Acetylenes: Aromatics: 57 15 2 26 A breakdown of 17...

409

Calculation of the heats of combustion of aromatic hydrocarbons contained in power-generating fuel  

Science Journals Connector (OSTI)

The additive method of group contributions is used for the calculation of the heats of combustion of aromatic hydrocarbons of different structures.

E. V. Sagadeev; V. V. Sagadeev

2006-07-01T23:59:59.000Z

410

Calculation of the Heats of Combustion of Saturated Hydrocarbons Contained in Power-Generating Fuels  

Science Journals Connector (OSTI)

An empirical method is suggested for the calculation of the heats of combustion of saturated hydrocarbons by the additive scheme proceeding from their...

E. V. Sagadeev; V. V. Sagadeev

2002-07-01T23:59:59.000Z

411

E-Print Network 3.0 - aromatic hydrocarbon diol-epoxide Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

with a DNA... ), a polycyclic aromatic hydrocarbon. A residue of fuel and tobacco combustion and frequently ingested by humans... , BP is metabolized in mammals to...

412

Low-Temperature Hydrocarbon/CO Oxidation Catalysis in Support of HCCI Emission Control  

Broader source: Energy.gov [DOE]

Development of catalyst materials to facilitate the low-temperature oxidation of hydrocarbons and CO in homogeneous charge compression ignition (HCCI) emissions.

413

The Impact of Low Octane Hydrocarbon Blending Streams on "E85...  

Broader source: Energy.gov (indexed) [DOE]

Blending Streams on "E85" Engine Optimization The Impact of Low Octane Hydrocarbon Blending Streams on "E85" Engine Optimization deer12szybist.pdf More Documents &...

414

E-Print Network 3.0 - aromatic hydrocarbons adducted Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

hydrocarbon... to its high reactivity toward DNA and cellular proteins. The major acrolein-DNA adduct, -hydrox- ypropano... -hy- droxynonenal, and acrolein, that readily form...

415

E-Print Network 3.0 - aromatic hydrocarbon pah-degrading Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

degradation Summary: Removal of polycyclic aromatic hydrocarbons (PAHs) from sewage sludge by anaerobic degradation N... , terminate in the sludge, and can be released to the...

416

E-Print Network 3.0 - aromatic hydrocarbons pahs Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Environmental Sciences and Ecology 30 0600Fg--Chem--Forensic Oil Sampling 01 2010 ****DATA SOURCE**** Summary: M - Alkylated PAHs) Volatile Organic Hydrocarbons -- Paraffins,...

417

E-Print Network 3.0 - aromatic hydrocarbons pah Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Environmental Sciences and Ecology 30 0600Fg--Chem--Forensic Oil Sampling 01 2010 ****DATA SOURCE**** Summary: M - Alkylated PAHs) Volatile Organic Hydrocarbons -- Paraffins,...

418

E-Print Network 3.0 - aromatic hydrocarbon pah Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Environmental Sciences and Ecology 30 0600Fg--Chem--Forensic Oil Sampling 01 2010 ****DATA SOURCE**** Summary: M - Alkylated PAHs) Volatile Organic Hydrocarbons -- Paraffins,...

419

Polycyclic Aromatic Hydrocarbons Formation in Sludge Incineration by Fluidised Bed and Rotary Kiln Furnace  

Science Journals Connector (OSTI)

Polycyclic Aromatic Hydrocarbons (PAHs) are typical pollutants arising from incineration. They are produced in any incomplete combustion principally due to inhomogeneities in a combustion chamber. The effects ...

Giuseppe Mininni; Andrea Sbrilli; Ettore Guerriero…

2004-05-01T23:59:59.000Z

420

Polycyclic aromatic hydrocarbon (PAH) in four fish species from different trophic levels in the Persian Gulf  

Science Journals Connector (OSTI)

Concentration of ten polycyclic aromatic hydrocarbon (PAH) compounds were determined in liver of four fish species from different trophic levels (Aurigequula fasciata, omnivore; Alepes djedaba, carnivore; Liza ab...

Shirin Rahmanpour; Nasrin Farzaneh Ghorghani…

2014-11-01T23:59:59.000Z

Note: This page contains sample records for the topic "monoxide hydrocarbons odors" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

E-Print Network 3.0 - active aryl hydrocarbon Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Receptors in Fishes Summary: the aryl hydrocarbon receptor (AHR), through which dioxins and dioxin-like compounds cause altered gene... -methylcholanthrene AHH: aryl...

422

E-Print Network 3.0 - aromatic hydrocarbon compounds Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

bases in Iraq and Afghanistan that lack Summary: Compounds Toxic Organic Halogenated Dioxins Furans (dioxins) Polycyclic Aromatic Hydrocarbons found... and detected all of the...

423

E-Print Network 3.0 - aryl hydrocarbon receptor-dna Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Receptors in Fishes Summary: the aryl hydrocarbon receptor (AHR), through which dioxins and dioxin-like compounds cause altered gene... -methylcholanthrene AHH: aryl...

424

E-Print Network 3.0 - aromatic polycyclic hydrocarbons Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

coal, oil, gas... called aromatic hydrocarbons. These include harmful pollutants like dioxins, PCBs and a group called Source: Rock, Chris - Department of Biological Sciences,...

425

E-Print Network 3.0 - aromatic hydrocarbons modulate Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

S0045-6535(02)00145-5 Summary: Abstract Polycyclic aromatic hydrocarbons (PAHs) and dioxins are lipophilic organic pollutants occurring... absorption, pig INTRODUCTION...

426

E-Print Network 3.0 - aromatic hydrocarbon aryl Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Receptors in Fishes Summary: the aryl hydrocarbon receptor (AHR), through which dioxins and dioxin-like compounds cause altered gene... -methylcholanthrene AHH: aryl...

427

E-Print Network 3.0 - aryl hydrocarbon monooxygenase Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Receptors in Fishes Summary: the aryl hydrocarbon receptor (AHR), through which dioxins and dioxin-like compounds cause altered gene... -methylcholanthrene AHH: aryl...

428

E-Print Network 3.0 - aromatic hydrocarbon tracers Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

S0045-6535(02)00145-5 Summary: Abstract Polycyclic aromatic hydrocarbons (PAHs) and dioxins are lipophilic organic pollutants occurring... absorption, pig INTRODUCTION...

429

E-Print Network 3.0 - aryl hydrocarbon receptor-regulated Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

classes of the aryl hydrocarbon receptor (AHR). A grander objective is to provide... pollutants is a direct consequence of their interactions with the aryl ... Source: Bradfield,...

430

E-Print Network 3.0 - aryl hydrocarbon receptor-1 Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

PARENTAL FACTORS ON GAMETE CONDITION AND VIABILITY Summary: . 15. 16. 17. 18-21. 22. Pollutants - petroleum aromatic hydrocarbons, aryl Pollutants - pesticides... high levels of...

431

E-Print Network 3.0 - aryl hydrocarbon nuclear Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Receptors in Fishes Summary: the aryl hydrocarbon receptor (AHR), through which dioxins and dioxin-like compounds cause altered gene... -methylcholanthrene AHH: aryl...

432

E-Print Network 3.0 - ahr aryl hydrocarbon Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Receptors in Fishes Summary: the aryl hydrocarbon receptor (AHR), through which dioxins and dioxin-like compounds cause altered gene... -methylcholanthrene AHH: aryl...

433

E-Print Network 3.0 - aromatic hydrocarbon water-soluble Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

S0045-6535(02)00145-5 Summary: Abstract Polycyclic aromatic hydrocarbons (PAHs) and dioxins are lipophilic organic pollutants occurring... with their lipophilicity and water...

434

E-Print Network 3.0 - aromatic hydrocarbons phahs Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

WH, Caton JE. 1983. Extraction of polycyclic aromatic hydrocarbons for qualitative analysis. In... : Handbook of Polycyclic Aromatic ... Source: Rock, Chris - Department of...

435

E-Print Network 3.0 - aryl hydrocarbon receptor-independent Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

PARENTAL FACTORS ON GAMETE CONDITION AND VIABILITY Summary: . 15. 16. 17. 18-21. 22. Pollutants - petroleum aromatic hydrocarbons, aryl Pollutants - pesticides... high levels of...

436

E-Print Network 3.0 - aryl hydrocarbon receptor-mediated Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

4 TOXICOLOGICAL SCIENCES 106(1), 8392 (2008) doi:10.1093toxscikfn149 Summary: ). Analysis of aryl hydrocarbon receptor-mediated signaling during physiological hypoxia reveals...

437

E-Print Network 3.0 - aryl hydrocarbon receptor-dependent Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Receptors in Fishes Summary: the aryl hydrocarbon receptor (AHR), through which dioxins and dioxin-like compounds cause altered gene... -methylcholanthrene AHH: aryl...

438

E-Print Network 3.0 - aryl hydrocarbon receptor Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Receptors in Fishes Summary: the aryl hydrocarbon receptor (AHR), through which dioxins and dioxin-like compounds cause altered gene... -methylcholanthrene AHH: aryl...

439

E-Print Network 3.0 - aromatic hydrocarbon-contaminated soil...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

soil... hydrocarbon degraders, and polycyclic aromatic ... Source: Ma, Lena - Soil and Water Science Department, University of Florida Collection: Environmental Sciences and...

440

Examination of polycyclic aromatic hydrocarbons in an urban stormwater system and bioaccumulation in Odonata.  

E-Print Network [OSTI]

??Polycyclic aromatic hydrocarbons (PAHs) are toxic organic pollutants produced from combustion processes. Associated with urban runoff they have been detected worldwide in urban wetlands. PAH… (more)

Heintzman, Lucas

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "monoxide hydrocarbons odors" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Problems in Catalytic Oxidation of Hydrocarbons and Detailed Simulation of Combustion Processes.  

E-Print Network [OSTI]

??This dissertation research consists of two parts, with Part I on the kinetics of catalytic oxidation of hydrocarbons and Part II on aspects on the… (more)

Xin, Yuxuan

2014-01-01T23:59:59.000Z

442

New IR Fiber-Optic Chemical Sensor for in Situ Measurements of Chlorinated Hydrocarbons in Water  

Science Journals Connector (OSTI)

In this work the development and validation of a new MIR fiber-optic physicochemical sensor system for the continuous in situ analysis of chlorinated hydrocarbons (CHCs) in...

Krska, R; Taga, K; Kellner, R

1993-01-01T23:59:59.000Z

443

Detection of Hydrocarbons in Water by MIR Evanescent-Wave Spectroscopy with Flattened Silver Halide Fibers  

Science Journals Connector (OSTI)

IR transmitting AgClxBr1-x fibers were used as internal reflection elements for the spectroscopic detection of hydrocarbons that are dissolved in water in an...

Hahn, P; Tacke, M; Jakusch, M; Mizaikoff, B; Spector, O; Katzir, A

2001-01-01T23:59:59.000Z

444

Characterization of hydrocarbons found in the arctic aquatic environment near the Ekati diamond mine.  

E-Print Network [OSTI]

??Polycyclic aromatic hydrocarbons (PAHs) in the aquatic environment of the Ekati Diamond Mine were evaluated in snow, sediment, air and water (via passive membrane samplers).… (more)

Nabess, Stephanie Ann

2014-01-01T23:59:59.000Z

445

Hydrocarbon solubility and its migration processes: a look at the present status  

SciTech Connect (OSTI)

In this study we review the present status of knowledge of solubility of hydrocarbons and its implications on primary migration processes. The intent is to examine the solubility and the transportation mechanisms relevant to geopressured-geothermal reservoirs, although the discussion included here accommodates a wide range of related aspects. Influences of parameters associated with hydrocarbon (especially methane) solubility have been studied. We have sought to evaluate several primary hydrocarbon migration processes and to point out their attractive features as well as their limitations. A brief discussion of hydrocarbon generation processes is also included.

Mamun, C.K.; Ohkuma, H.; Sepehrnoori, K.

1985-12-01T23:59:59.000Z

446

Detonations in Hydrocarbon Fuel Blends J.M. Austin and J.E. Shepherd  

E-Print Network [OSTI]

.3), nitrogen dilutions (fuel-oxygen to fuel-air), and initial pressures (20-130 kPa). The cell widths of the JP to be comparable. The addition of lower molecular weight fuels (hydrogen, acetylene, ethylene, 1 #12;and carbon, but addition of more than about 75 % (by fuel mass) carbon monoxide results in a significant increase in cell

Low, Steven H.

447

CATEE: Clean Air Through Energy Efficiency Conference  

E-Print Network [OSTI]

& dander • Carbon dioxide (CO2) • Carpet GARAGE • Carbon monoxide (CO) • Gas • Solvent • Pesticides & herbicides • Dust • Paint & chemical • Cleaning agents BATHROOM • Excess humidity • Personal hygiene products (aerosols, sprays, etc.) •Mold spores HOME... KITCHEN • Lingering odors • Bacteria • Cooking pollutants Basement • High humidity levels • Unpleasant odors •Mold • Carbon monoxide (CO) • Fireplace/smoke • Firewood • Radon • Solvents •Woodstove • Dust & dust mites • Combustion system • Paint & chemicals...

Tillman, S.

2014-01-01T23:59:59.000Z

448

Mach 2 combustion characteristics of hydrogen/hydrocarbon fuel mixtures  

SciTech Connect (OSTI)

The combustion of H/sub 2//CH/sub 4/ and H/sub 2//C/sub 2/H/sub 4/ mixtures containing 10 to 70 vol pct hydrocarbon at combustor inlet Mach number 2 and temperatures 2000 to 4000 R is investigated experimentally, applying direct-connect test hardware and techniques similar to those described by Diskin and Northam (1987) in the facilities of the NASA Langley Hypersonic Propulsion Branch. The experimental setup, procedures, and data-reduction methods are described; and the results are presented in extensive tables and graphs and characterized in detail. Fuel type and mixture are found to have little effect on the wall heating rate measured near the combustor exit, but H/sub 2//C/sub 2/H/sub 4/ is shown to burn much more efficiently than H/sub 2//CH/sub 4/, with no pilot-off blowout equivalence ratios greater than 0.5. It is suggested that H/sub 2//hydrocarbon mixtures are feasible fuels (at least in terms of combustion efficiency) for scramjet SSTO vehicles operating at freestream Mach numbers above 4.

Diskin, G.S.; Jachimowski, C.J.; Northam, G.B.; Bell, R.A.

1987-01-01T23:59:59.000Z

449

Oxygen sensor for monitoring gas mixtures containing hydrocarbons  

DOE Patents [OSTI]

A gas sensor measures O.sub.2 content of a reformable monitored gas containing hydrocarbons H.sub.2 O and/or CO.sub.2, preferably in association with an electrochemical power generation system. The gas sensor has a housing communicating with the monitored gas environment and carries the monitored gas through an integral catalytic hydrocarbon reforming chamber containing a reforming catalyst, and over a solid electrolyte electrochemical cell used for sensing purposes. The electrochemical cell includes a solid electrolyte between a sensor electrode that is exposed to the monitored gas, and a reference electrode that is isolated in the housing from the monitored gas and is exposed to a reference gas environment. A heating element is also provided in heat transfer communication with the gas sensor. A circuit that can include controls operable to adjust operations via valves or the like is connected between the sensor electrode and the reference electrode to process the electrical signal developed by the electrochemical cell. The electrical signal varies as a measure of the equilibrium oxygen partial pressure of the monitored gas. Signal noise is effectively reduced by maintaining a constant temperature in the area of the electrochemical cell and providing a monitored gas at chemical equilibria when contacting the electrochemical cell. The output gas from the electrochemical cell of the sensor is fed back into the conduits of the power generating system.

Ruka, Roswell J. (Pittsburgh, PA); Basel, Richard A. (Pittsburgh, PA)

1996-01-01T23:59:59.000Z

450

Preliminary Economics for Hydrocarbon Fuel Production from Cellulosic Sugars  

SciTech Connect (OSTI)

Biorefinery process and economic models built in CHEMCAD and a preliminary, genome-scale metabolic model for the oleaginous yeast Lipomyces starkeyi were used to simulate the bioconversion of corn stover to lipids, and the upgrading of these hydrocarbon precursors to diesel and jet fuel. The metabolic model was based on the recently released genome sequence for L. starkeyi and on metabolic pathway information from the literature. The process model was based on bioconversion, lipid extraction, and lipid oil upgrading data found in literature, on new laboratory experimental data, and on yield predictions from the preliminary L. starkeyi metabolic model. The current plant gate production cost for a distillate-range hydrocarbon fuel was estimated by the process model Base Case to be $9.5/gallon ($9.0 /gallon of gasoline equivalent) with assumptions of 2011$, 10% internal return on investment, and 2205 ton/day dry feed rate. Opportunities for reducing the cost to below $5.0/gallon, such as improving bioconversion lipid yield and hydrogenation catalyst selectivity, are presented in a Target Case. The process and economic models developed for this work will be updated in 2014 with new experimental data and predictions from a refined metabolic network model for L. starkeyi. Attaining a production cost of $3.0/gallon will require finding higher value uses for lignin other than power generation, such as conversion to additional fuel or to a co-product.

Collett, James R.; Meyer, Pimphan A.; Jones, Susanne B.

2014-05-18T23:59:59.000Z

451

Oxygen sensor for monitoring gas mixtures containing hydrocarbons  

DOE Patents [OSTI]

A gas sensor measures O{sub 2} content of a reformable monitored gas containing hydrocarbons, H{sub 2}O and/or CO{sub 2}, preferably in association with an electrochemical power generation system. The gas sensor has a housing communicating with the monitored gas environment and carries the monitored gas through an integral catalytic hydrocarbon reforming chamber containing a reforming catalyst, and over a solid electrolyte electrochemical cell used for sensing purposes. The electrochemical cell includes a solid electrolyte between a sensor electrode that is exposed to the monitored gas, and a reference electrode that is isolated in the housing from the monitored gas and is exposed to a reference gas environment. A heating element is also provided in heat transfer communication with the gas sensor. A circuit that can include controls operable to adjust operations via valves or the like is connected between the sensor electrode and the reference electrode to process the electrical signal developed by the electrochemical cell. The electrical signal varies as a measure of the equilibrium oxygen partial pressure of the monitored gas. Signal noise is effectively reduced by maintaining a constant temperature in the area of the electrochemical cell and providing a monitored gas at chemical equilibria when contacting the electrochemical cell. The output gas from the electrochemical cell of the sensor is fed back into the conduits of the power generating system. 4 figs.

Ruka, R.J.; Basel, R.A.

1996-03-12T23:59:59.000Z

452

Distillation sequence for the purification and recovery of hydrocarbons  

DOE Patents [OSTI]

This invention is an improved distillation sequence for the separation and purification of ethylene from a cracked gas. A hydrocarbon feed enters a C2 distributor column. The top of the C2 distributor column is thermally coupled to an ethylene distributor column, and the bottoms liquid of a C2 distributor column feeds a deethanizer column. The C2 distributor column utilizes a conventional reboiler. The top of the ethylene distributor is thermally coupled with a demethanizer column, and the bottoms liquid of the ethylene distributor feeds a C2 splitter column. The ethylene distributor column utilizes a conventional reboiler. The deethanizer and C2 splitter columns are also thermally coupled and operated at a substantially lower pressure than the C2 distributor column, the ethylene distributor column, and the demethanizer column. Alternatively, a hydrocarbon feed enters a deethanizer column. The top of the deethanizer is thermally coupled to an ethylene distributor column, and the ethylene distributor column utilizes a conventional reboiler. The top of the ethylene distributor column is thermally coupled with a demethanizer column, and the bottoms liquid of the ethylene distributor column feeds a C2 splitter column. The C2 splitter column operates at a pressure substantially lower than the ethylene distributor column, the demethanizer column, and the deethanizer column.

Reyneke, Rian (Katy, TX); Foral, Michael (Aurora, IL); Papadopoulos, Christos G. (Naperville, IL); Logsdon, Jeffrey S. (Naperville, IL); Eng, Wayne W. Y. (League City, TX); Lee, Guang-Chung (Houston, TX); Sinclair, Ian (Warrington, GB)

2007-12-25T23:59:59.000Z

453

Mutual solubilities of water and hydrocarbons from the Cubic plus Association equation of state: A new mixing rule for the correlation of observed minimum hydrocarbon solubilities  

Science Journals Connector (OSTI)

Abstract The cubic plus association (CPA) equation of state was employed to correlate the mutual solubilities of water and hydrocarbons (n-alkanes, cycloalkanes and aromatics). In order to reproduce the minimums observed in concentration vs. temperature curves, a new mixing rule is proposed based on Kabadi and Danner's idea, whereby the water–water dispersive term is corrected to include the hydrophobic hydration effect. With this correction, correlated hydrocarbon solubilities curves have observable curvature at low temperatures. Two binary interaction parameters are required for saturated hydrocarbons and three for aromatics, which is just one more than the original CPA formulation. Using parameters determined from binary data, this improved mixing rule was employed for multicomponent water–hydrocarbon systems, with no further regression, producing better predictions when compared to the conventional van der Waals’ rules.

Milton Medeiros

2014-01-01T23:59:59.000Z

454

NREL: Transportation Research - Alternative Fuel Fleet Vehicle...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

reduced particulate matter, carbon monoxide, and hydrocarbon emissions. Regional Transportation District Biodiesel Transit Buses In partnership with the Regional Transportation...

455

States of cobalt and iron in catalysts supported in TiO{sub 2} from data of diffuse reflectance IR spectra of adsorbed carbon monoxide  

SciTech Connect (OSTI)

The variations in the oxidation states of cobalt and iron atoms in pure and mixed Co- and Fe-containing catalysts supported on TiO{sub 2} as a function of the conditions in which the catalysts were prepared and preliminarily treated were studied by analysis of the IR spectra of carbon monoxide adsorbed on these catalysts. A mutual influence of the components was discovered; iron was found to promote reduction of cobalt.

Davydov, A.A. [G.K. Boreskov Inst. of Catalysis, Novosibirsk (Russian Federation); Coville, N. [Univ. of the Wiswatersrand Wits, Johannesburg (South Africa)

1995-10-01T23:59:59.000Z

456

Relation between surface adsorption states and emf in a solid electrolyte concentration cell during carbon monoxide oxidation on platinum studied by local current measurement  

SciTech Connect (OSTI)

The importance of measuring adsorption during surface catalysis has been emphasized often. This is true for the oxidation of carbon monoxide on a platinum surface. Surface adsorption states during the reaction under steady states can be learned from electromotive force (emf) measurement with appropriate assumptions. Two mechanisms for emf generation have been proposed, one is that only oxygen activity generates emf, the other is that both oxygen and CO adsorption generates emf.

Okamoto, H.; Kawamura, G.; Kudo, T.

1984-04-01T23:59:59.000Z

457

Desiccant bed on hydrocarbon charged to and removed from underground (salt) cavern  

SciTech Connect (OSTI)

A hydrocarbon fluid storage system is described which consists of in operable conjunction: a cavern formed within an underground salt strata below a ground surface, the cavern comprises a lower liquid volume of saturated sodium chloride storage brine and an upper fluid volume of wet hydrocarbon storage fluid, surface fluid handling means; conduit connecting the lower storage brine and upper storage hydrocarbon fluid with the surface fluid handling means, of fluid transfer means enabling transfer of brine and hydrocarbon fluid from the surface to the cavern and from the cavern to the surface, such that brine can be added to or withdrawn from the lower brine volume and hydrocarbon fluids can be added to or withdrawn from the upper hydrocarbon fluid volume, and at least one desiccant drier means positioned at the surface in operable association with the surface fluid handling means whereby the wet hydrocarbon fluid upon withdrawal from the cavern passes through the desiccant drier means and thereby becomes dry, and dry hydrocarbon fluid intended for storage passes through the desiccant drier prior to entering the storage cavern and thereby becomes wet.

Washer, S.P.

1986-06-03T23:59:59.000Z

458

Adsorption and Desorption of Hydrocarbons on a Supported Nickel Cracking Catalyst  

Science Journals Connector (OSTI)

...Hydrocarbons on a Supported Nickel Cracking Catalyst A. K. Galwey A study has been made...a high area supported nickel cracking catalyst. Measurements have been made of (i...adsorbed, after standard preparation of the catalyst, when a known volume of each hydrocarbon...

1963-01-01T23:59:59.000Z

459

Novel Methane, Ethane, and Propane Oxidizing Bacteria at Marine Hydrocarbon Seeps Identified by Stable Isotope Probing  

E-Print Network [OSTI]

Novel Methane, Ethane, and Propane Oxidizing Bacteria at Marine Hydrocarbon Seeps Identified by Stable Isotope Probing Running Title: Novel Methane, Ethane, and Propane Oxidizing Bacteria Section hydrocarbons in surface sediment from the Coal Oil Point seep field, offshore Santa4 Barbara, California. After

Sessions, Alex L.

460

The spatial scales, distribution, and intensity of natural marine hydrocarbon seeps near Coal Oil Point, California  

E-Print Network [OSTI]

area) are not well established, either globally or within strong source areas such as near Coal OilThe spatial scales, distribution, and intensity of natural marine hydrocarbon seeps near Coal Oil hydrocarbon seepage from marine environments is an important source of methane and other gases

Washburn, Libe

Note: This page contains sample records for the topic "monoxide hydrocarbons odors" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Mutagenicity of Soot and Associated Polycyclic Aromatic Hydrocarbons to Salmonella typhimurium  

Science Journals Connector (OSTI)

...polycyclic aromatic hydrocarbon fraction in terms...by the incomplete combustion of organic material...sediments (1), heat and power generation...PAH from fuel combustion found in the atmosphere...polycyclic aromatic hydrocarbons; PMS, postmitochondrial...amounts of mutation (data not presented...

Debra A. Kaden; Ronald A. Hites; and William G. Thilly

1979-10-01T23:59:59.000Z

462

Aryl hydrocarbon receptor polymorphisms and dioxin resistance in Atlantic killifish (Fundulus heteroclitus)  

E-Print Network [OSTI]

Aryl hydrocarbon receptor polymorphisms and dioxin resistance in Atlantic killifish (Fundulus aromatic hydrocarbons (HAHs) such as 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD) as well as polynuclear and that the frequencies of the major allele types differ between dioxin- sensitive and dioxin-resistant populations

Hahn, Mark E.

463

Assessment of natural and anthropogenic hydrocarbon inputs using PAHs as tracers.  

E-Print Network [OSTI]

to produce liquid hydrocarbons and water. -- Coal-to-liquids (CTLs) are derived either by pyrolysis of coal authors accept that conventional oil resources are at an advanced stage of depletion and that liquid fuels is a heterogeneous mix of hydrocarbons that remain in liquid phase when extracted to the surface. -- Condensate

464

QSPR models of boiling point, octanolwater partition coefficient and retention time index of polycyclic aromatic hydrocarbons  

E-Print Network [OSTI]

QSPR models of boiling point, octanol­water partition coefficient and retention time index of polycyclic aromatic hydrocarbons Fabiana Alves de Lima Ribeiro, Ma´rcia Miguel Castro Ferreira* Laborato Structure­Property Relationship (QSPR) analysis and study of polycyclic aromatic hydrocarbons (PAHs

Ferreira, Márcia M. C.

465

NEW MARINE DECAPOD CRUSTACEANS FROM WATERS INFLUENCED BY HYDROmERMAL DISCHARGE, BRINE, AND HYDROCARBON SEEPAGE  

E-Print Network [OSTI]

and waters influenced by brine and hydrocarbon seeps continue to yield species new to science. Such enNEW MARINE DECAPOD CRUSTACEANS FROM WATERS INFLUENCED BY HYDROmERMAL DISCHARGE, BRINE, AND HYDROCARBON SEEPAGE AUSTIN B. WILLIAMS} ABSTRACT Five species of decapod crustaceans new to science

466

Polycyclic aromatic hydrocarbons: a QSPR study Marcia M.C. Ferreira  

E-Print Network [OSTI]

Polycyclic aromatic hydrocarbons: a QSPR study Marcia M.C. Ferreira UNICAMP Instituto de Quõmica studies such as the boiling temperature (Tb), the retention index (RI), n-octanol/water partition coecient; Chemometrics 1. Introduction The polycyclic aromatic hydrocarbons (PAH) have been, for a long time, a focus

Ferreira, Márcia M. C.

467

PARTICLE-ASSOCIATED POLYCYCLIC AROMATIC HYDROCARBONS IN THE ATMOSPHERE OF HONG KONG  

E-Print Network [OSTI]

PARTICLE-ASSOCIATED POLYCYCLIC AROMATIC HYDROCARBONS IN THE ATMOSPHERE OF HONG KONG M. ZHENG and M Technology, Clear Water Bay, Hong Kong, China ( present address: Graduate School of Oceanography, University@ust.hk) (Received 3 June 1998; accepted 22 December 1998) Abstract. Polycyclic aromatic hydrocarbons (PAHs) in total

Zheng, Mei

468

Induced Microearthquake Patterns in Hydrocarbon and Geothermal Reservoirs: W. Scott Phillips  

E-Print Network [OSTI]

Induced Microearthquake Patterns in Hydrocarbon and Geothermal Reservoirs: A Review W. Scott or production of fluids can induce microseismic events in hydrocarbon and geothermal reservoirs. By deploying sensors downhole, data sets have been collected that consist of a few hundred to well over 10,000 induced

469

Biological Monitoring of Fire Fighters: Sister Chromatid Exchange and Polycyclic Aromatic Hydrocarbon-DNA Adducts in Peripheral Blood Cells  

Science Journals Connector (OSTI)

...polycyclic aromatic hydrocarbon-DNA adduct levels...exposure to carcinogenic combustion products. Cytoge...polycyclic aromatic hydrocarbon; CI, confidence interval...estimating exposures to combustion and pyrolysis products...into water, briefly heat denatured (100 Cfor...

Saou-Hsing Liou; David Jacobson-Kram; Miriam C. Poirier; Dung Nguyen; Paul T. Strickland; and Melvyn S. Tockman

1989-09-01T23:59:59.000Z

470

Biological Monitoring of Fire Fighters: Sister Chromatid Exchange and Polycyclic Aromatic Hydrocarbon-DNA Adducts in Peripheral Blood Cells  

Science Journals Connector (OSTI)

...polycyclic aromatic hydrocarbon-DNA adduct levels...to carcinogenic combustion products. Cytoge...polycyclic aromatic hydrocarbon; CI, confidence...controlled for during data analysis. Collection...estimating exposures to combustion and pyrolysis products...water, briefly heat denatured (100...

Saou-Hsing Liou; David Jacobson-Kram; Miriam C. Poirier; Dung Nguyen; Paul T. Strickland; and Melvyn S. Tockman

1989-09-01T23:59:59.000Z

471

Levels of Tobacco-Specific Nitrosamines and Polycyclic Aromatic Hydrocarbons in Mainstream Smoke from Different Tobacco Varieties  

Science Journals Connector (OSTI)

...carcinogenic polycyclic aromatic hydrocarbons in mainstream cigarette...21 U.S. EPA. Ambient Water Quality Criteria for Polynuclear Aromatic Hydrocarbons. EPA 440/5-80-069...Quality Criteria for Water; EPA 440/5-86-001...

Yan S. Ding; Liqin Zhang; Ram B. Jain; Ntasha Jain; Richard Y. Wang; David L. Ashley; and Clifford H. Watson

2008-12-01T23:59:59.000Z

472

Method for cracking hydrocarbon compositions using a submerged reactive plasma system  

DOE Patents [OSTI]

A method is described for cracking a liquid hydrocarbon composition (e.g. crude oil) to produce a cracked hydrocarbon product. A liquid hydrocarbon composition is initially provided. An electrical arc is generated directly within the hydrocarbon composition so that the arc is entirely submerged in the composition. Arc generation is preferably accomplished using a primary and secondary electrode each having a first end submerged in the composition. The first ends of the electrodes are separated from each other to form a gap there between. An electrical potential is then applied to the electrodes to generate the arc within the gap. A reactive gas is thereafter delivered to the arc which forms a bubble around the arc. Gas delivery may be accomplished by providing a passageway through each electrode and delivering the gas through the passageways. The arc and gas cooperate to produce a plasma which efficiently cracks the hydrocarbon composition. 6 figs.

Kong, P.C.

1997-05-06T23:59:59.000Z

473

New modified hydrocarbon resins; An alternative to styrenated terpene resins in hot melts  

SciTech Connect (OSTI)

This paper reports on the development of two hydrocarbon-based resin formulations that could be used with different thermoplastic block copolymers to formulate pressure-sensitive adhesives. Results are examined with one of these resins in formulations with styrene-isoprene-styrene (SIS) and styrene-butadiene (SB) compounds. The new modified hydrocarbon resin, with a softening point of 98{degrees} C, matches the adhesive performance of a terpene resin with a softening point of 105{degrees} C. The resin performs as well as the modified terpene in SIS-, SB-, and EVA-based adhesives. The new hydrocarbon resin is especially well suited for hot-melt adhesives. It exhibits low volatility, good color stability, and excellent melt viscosity stability. Since the new resin is based on petroleum hydrocarbon feedstocks, it should be available at moderate, stable prices. The other hydrocarbon resin, with a softening point of 85{degrees} C, produced comparable results.

Carper, J.D. (Hercules Inc., Wilmington, DE (US))

1990-06-01T23:59:59.000Z

474

Time sequenced heating of multiple layers in a hydrocarbon containing formation  

DOE Patents [OSTI]

A method for treating a hydrocarbon containing formation may include providing heat to a first hydrocarbon layer in the formation from a first heater located in an opening in the formation. The opening and the first heater may have a horizontal or inclined portion located in the first hydrocarbon layer and at least one connecting portion extending between the horizontal or inclined portion and the surface. Isolation material is placed in the opening such that the isolation material partially isolates the layer in which the horizontal or inclined portion of the first heater is located. An additional horizontal or inclined opening portion that extends from at least one of the connecting portions of the opening is formed in a second hydrocarbon layer. A second heater to provide heat the second hydrocarbon formation is placed in the additional substantially horizontal opening portion.

Goldberg, Bernard (Houston, TX); Hale, Arthur Herman (Houston, TX); Miller, David Scott (Katy, TX); Vinegar, Harold J. (Bellaire, TX)

2009-12-22T23:59:59.000Z

475

Method for cracking hydrocarbon compositions using a submerged reactive plasma system  

DOE Patents [OSTI]

A method for cracking a liquid hydrocarbon composition (e.g. crude oil) to produce a cracked hydrocarbon product. A liquid hydrocarbon composition is initially provided. An electrical arc is generated directly within the hydrocarbon composition so that the arc is entirely submerged in the composition. Arc generation is preferably accomplished using a primary and secondary electrode each having a first end submerged in the composition. The first ends of the electrodes are separated from each other to form a gap therebetween. An electrical potential is then applied to the electrodes to generate the arc within the gap. A reactive gas is thereafter delivered to the arc which forms a bubble around the arc. Gas delivery may be accomplished by providing a passageway through each electrode and delivering the gas through the passageways. The arc and gas cooperate to produce a plasma which efficiently cracks the hydrocarbon composition.

Kong, Peter C. (Idaho Falls, ID)

1997-01-01T23:59:59.000Z

476

Kinetic Studies on the Hydrogen Peroxide-Enhanced In Situ Biodegradation of Hydrocarbons in Water-Saturated Ground Zone  

Science Journals Connector (OSTI)

Techniques are rapidly developing for aerobic biodegradation of hydrocarbons in lower water-bearing formations. It is well known that...

Dr. E. R. Barenschee; Dr. O. Helmling; S. Dahmer; B. Del Grosso…

1990-01-01T23:59:59.000Z

477

One-Step Production of Superhydrophobic Coatings on Flat Substrates via Atmospheric Rf Plasma Process Using Non-Fluorinated Hydrocarbons  

Science Journals Connector (OSTI)

One-Step Production of Superhydrophobic Coatings on Flat Substrates via Atmospheric Rf Plasma Process Using Non-Fluorinated Hydrocarbons ... This paper describes the direct deposition of hydrocarbon coatings with a static water contact angle higher than 150 using simple C6 hydrocarbons as a reactive gas in helium plasma generated in ambient air without any preroughening of the silicon (100) substrate. ...

Seul Hee Lee; Zachary R. Dilworth; Erik Hsiao; Anna L. Barnette; Matthew Marino; Jeong Hoon Kim; Jung-Gu Kang; Tae-Hwan Jung; Seong H. Kim

2011-01-31T23:59:59.000Z

478

Identification of Novel Methane-, Ethane-, and Propane-Oxidizing Bacteria at Marine Hydrocarbon Seeps by Stable Isotope Probing  

Science Journals Connector (OSTI)

...detector. When the hydrocarbon gas had nearly been...additional 5 ml of hydrocarbon gas was added. Oxygen...second 5-ml aliquot of hydrocarbon had been consumed...splitless injector, a GC combustion III interface, and...at 37C, followed by heat inactivation for 20...

Molly C. Redmond; David L. Valentine; Alex L. Sessions

2010-07-30T23:59:59.000Z

479

Activated carbon and biochar amendments decrease pore-water concentrations of polycyclic aromatic hydrocarbons (PAHs) in sewage sludge  

E-Print Network [OSTI]

hydrocarbons (PAHs) in sewage sludge Patryk Oleszczuk a,b, , Sarah E. Hale a , Johannes Lehmann c , Gerard Polycyclic aromatic hydrocarbons Bioavailability Sewage sludge a b s t r a c t The aim of the research of polycyclic aromatic hydrocarbons (PAHs) in sewage sludge. Two different biochars (MSB and PMW) and two ACs

Lehmann, Johannes

480

Polycyclic Aromatic Hydrocarbons in C8 Isomer Aromatic Feed: Analysis by GC, GC/MS, and GC/FTIR Techniques  

Science Journals Connector (OSTI)

......the concentrated hydrocarbon residue of C 8...Polycyclic aromatic hydrocarbons (PAHs) are recognized...fossil fuels, combustion products, and...monocyclic aro matic hydrocarbons like benzene or...feed-effluent heat exchangers (16...and a Shimadzu data pro cessor (C-R......

V.N. Garg; B.D. Bhatt; V.K. Kaushik; K.R. Murthy

1987-06-01T23:59:59.000Z

Note: This page contains sample records for the topic "monoxide hydrocarbons odors" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Molecular Dynamics Simulations of End-to-End Contact Formation in Hydrocarbon Chains in Water and Aqueous Urea  

E-Print Network [OSTI]

Molecular Dynamics Simulations of End-to-End Contact Formation in Hydrocarbon Chains in Water is to probe contact formation between two ends of model hydrocarbon chains in water and 6 M aqueous urea "folding" event, namely, the formation of end-to-end contact in the linear hydrocarbon chain (HC) CH3(CH2

Thirumalai, Devarajan

482

Proceedings of the 8th Intl. Symp. On Olfaction and Electronic Nose, Washington, DC, March 25-30, 2001 USE OF AN ELECTRONIC NOSE TO EVALUATE ODORS FROM SWINE  

E-Print Network [OSTI]

Proceedings of the 8th Intl. Symp. On Olfaction and Electronic Nose, Washington, DC, March 25 industries are expanding rapidly in many areas of the globe, and this expansion is causing environmental-consuming and expensive. In addition, odor samples degrade rapidly so human panels must perform evaluations shortly after

Gutierrez-Osuna, Ricardo

483

Methane, Nonmethane Hydrocarbons, Alkyl Nitrates, and Chlorinated Carbon  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Atmospheric Trace Gases in Whole-Air Samples Atmospheric Trace Gases in Whole-Air Samples Methane, Nonmethane Hydrocarbons, Alkyl Nitrates, and Chlorinated Carbon Compounds including 3 Chlorofluorocarbons (CFC-11, CFC-12, and CFC-113) in Whole-air Samples graphics Graphics data Data Investigator Donald Blake Department of Chemistry, University of California Irvine, California, 92697 USA Period of Record April 1979 - December 2012 Methods Whole-air samples are collected in conditioned, evacuated, 2-L stainless steel canisters; each canister is filled to ambient pressure over a period of about 1 minute (approximately 20 seconds to 2 minutes). These canisters are returned to the University of California at Irvine for chromatographic analysis. Analysis for methane includes gas chromatography with flame ionization, as

484

Solution mining systems and methods for treating hydrocarbon containing formations  

DOE Patents [OSTI]

A method for treating an oil shale formation comprising nahcolite is disclosed. The method includes providing a first fluid to a portion of the formation through at least two injection wells. A second fluid is produced from the portion through at least one injection well until at least two injection wells are interconnected such that fluid can flow between the two injection wells. The second fluid includes at least some nahcolite dissolved in the first fluid. The first fluid is injected through one of the interconnected injection wells. The second fluid is produced from at least one of the interconnected injection wells. Heat is provided from one or more heaters to the formation to heat the formation. Hydrocarbon fluids are produced from the formation.

Vinegar, Harold J. (Bellaire, TX); de Rouffignac, Eric Pierre (Rijswijk, NL); Schoeling, Lanny Gene (Katy, TX)

2009-07-14T23:59:59.000Z

485

Chapter 4 - Physical Properties of Hydrocarbons and Petrochemicals  

Science Journals Connector (OSTI)

Abstract A brief description of the most common hydrocarbons and chemicals used in the process industries is provided, starting from the simplest to the more complex. Additionally, several tables are provided that identify the molecular compositions and typical fire hazards (flash points, flammability limits, autoignition temperatures) of these common materials. The specific fire hazard terms are explained in further detail for better understanding of the risks involved with processing and handling of the materials. An autoignition temperature approximation method is also provided for use where a mixture of material may be present. Physical properties that may influence the severity of an incident from these materials are mentioned and described, which includes vapor density, vapor pressure, and specific gravity.

Dennis P. Nolan

2014-01-01T23:59:59.000Z

486

Polynuclear aromatic hydrocarbons (PAHs) in fish from the Arabian Gulf  

SciTech Connect (OSTI)

Emphasis has been placed upon the identification and qualification of compounds with potential adverse health effects on humans. Prominent among this group are polynuclear aromatic hydrocarbons (PAHs), several of which are known or suspected carcinogens. PAHs enter the marine environment from a variety of sources including petroleum pollution, industrial and domestic effluents, atmospheric particles, and biosynthesis by plants and microorganisms. Although one-third of the world's oil is produced around the Arabian Gulf, no detailed analysis have been conducted to determine PAHs in this region. Nevertheless, numerous investigations have shown the ability of marine organisms including fish to accumulation PAHs from solution or dispersion in seawater. When fish are harvested, a human health hazard may result. In the present communication, high performance liquid chromatography (HPLC) was used to identify and measure sixteen PAHs priority pollutants issued by US Environmental Protection Agency (EPA) in fourteen species of commercially significant fish from the NW Arabian Gulf.

DouAbdul, A.A.Z.; Abaychi, J.K.; Al-Edanee, T.E.; Ghani, A.A.; Al-Saad, H.T.

1987-03-01T23:59:59.000Z

487

Method and apparatus for hydrocarbon recovery from tar sands  

DOE Patents [OSTI]

A method and apparatus for utilizing tar sands having a broad range of bitumen content is disclosed. More particularly, tar sands are pyrolyzed in a cyclone retort with high temperature gases recycled from the cyclone retort to produce oil and hydrocarbon products. The spent tar sands are then burned at 2000/degree/F in a burner to remove residual char and produce a solid waste that is easily disposable. The process and apparatus have the advantages of being able to utilize tar sands having a broad range of bitumen content and the advantage of producing product gases that are free from combustion gases and thereby have a higher heating value. Another important advantage is rapid pyrolysis of the tar sands in the cyclone so as to effectively utilize smaller sized reactor vessels for reducing capitol and operating costs. 1 fig., 1 tab.

Westhoff, J.D.; Harak, A.E.

1988-05-04T23:59:59.000Z

488

Method and apparatus for hydrocarbon recovery from tar sands  

DOE Patents [OSTI]

A method and apparatus for utilizing tar sands having a broad range of bitumen content is disclosed. More particularly, tar sands are pyrolyzed in a cyclone retort with high temperature gases recycled from the cyclone retort to produce oil and hydrocarbon products. The spent tar sands are then burned at 2000.degree. F. in a burner to remove residual char and produce a solid waste that is easily disposable. The process and apparatus have the advantages of being able to utilize tar sands having a broad range of bitumen content and the advantage of producing product gases that are free from combustion gases and thereby have a higher heating value. Another important advantage is rapid pyrolysis of the tar sands in the cyclone so as to effectively utilize smaller sized reactor vessels for reducing capitol and operating costs.

Westhoff, James D. (Laramie, WY); Harak, Arnold E. (Laramie, WY)

1989-01-01T23:59:59.000Z

489

Distribution of polycyclic aromatic hydrocarbons (PAH's) in marsh sediments, Iraq  

SciTech Connect (OSTI)

Recently there has been a growing concern in the release of harmful organics into the environment. Carcinogenic polycyclic aromatic hydrocarbons (PAH's) are a class of compounds of interset due to their possible harmful effects to man as well as organisms. Anthropogenic PAH's may reach aquatic environment as a result of both industrial and domestic effluents, deposition of airborne particles, surface runoff and oil spillage. Having a relatively low water solubility and high affinity to sorb to the suspended particulate matter, most of the PAH's introduced to the aquatic environment tend to accumulate in bottom sediments. Sedimentary PAH's may thus provide a record of the input and history of these pollutants. Consequently, the distribution of PAH's in aquatic sediments have received considerable attention. The purpose of the present work was to establish the distribution of PAH's in the sediments of the marsh region located in southern Iraq.

Al-Saad, H.T.; Al-Timari, A.A. (Univ. of Basrah (Iraq))

1989-12-01T23:59:59.000Z

490

Pyrochlore-type catalysts for the reforming of hydrocarbon fuels  

DOE Patents [OSTI]

A method of catalytically reforming a reactant gas mixture using a pyrochlore catalyst material comprised of one or more pyrochlores having the composition A.sub.2-w-xA'.sub.wA''.sub.xB.sub.2-y-zB'.sub.yB''.sub.zO.sub.7-.DELTA.. Distribution of catalytically active metals throughout the structure at the B site creates an active and well dispersed metal locked into place in the crystal structure. This greatly reduces the metal sintering that typically occurs on supported catalysts used in reforming reactions, and reduces deactivation by sulfur and carbon. Further, oxygen mobility may also be enhanced by elemental exchange of promoters at sites in the pyrochlore. The pyrochlore catalyst material may be utilized in catalytic reforming reactions for the conversion of hydrocarbon fuels into synthesis gas (H.sub.2+CO) for fuel cells, among other uses.

Berry, David A. (Morgantown, WV); Shekhawat, Dushyant (Morgantown, WV); Haynes, Daniel (Morgantown, WV); Smith, Mark (Morgantown, WV); Spivey, James J. (Baton Rouge, LA)

2012-03-13T23:59:59.000Z

491

Heating hydrocarbon containing formations in a spiral startup staged sequence  

DOE Patents [OSTI]

Methods for treating a hydrocarbon containing formation are described herein. Methods may include treating a first zone of the formation. Treatment of a plurality of zones of the formation may be begun at selected times after the treatment of the first zone begins. The treatment of at least two successively treated zones may begin at a selected time after treatment of the previous zone begins. At least two of the successively treated zones may be adjacent to the zone treated previously. The successive treatment of the zones proceeds in an outward, substantially spiral sequence from the first zone so that the treatment of the zones may move substantially spirally outwards towards a boundary of the treatment area.

Vinegar, Harold J. (Bellaire, TX); Miller, David Scott (Katy, TX)

2009-12-15T23:59:59.000Z

492

Hydrocarbon Gas Liquids (HGL): Recent Market Trends and Issues  

Reports and Publications (EIA)

Over the past five years, rapid growth in U.S. onshore natural gas and oil production has led to increased volumes of natural gas plant liquids (NGPL) and liquefied refinery gases (LRG). The increasing economic importance of these volumes, as a result of their significant growth in production, has revealed the need for better data accuracy and transparency to improve the quality of historical data and projections for supply, demand, and prices of these liquids, co-products, and competing products. To reduce confusion in terminology and improve its presentation of data, EIA has worked with industry and federal and state governments to clarify gas liquid terminology and has developed the term Hydrocarbon Gas Liquids, or HGL.

2014-01-01T23:59:59.000Z

493

Thermodynamic properties of hydrocarbon liquids at high pressures and temperatures  

SciTech Connect (OSTI)

Understanding the organic/inorganic interface in the Earth's crust requires values of the thermodynamic properties of hydrocarbon species in crude oil, coal, and natural gas at elevated temperatures and pressures. Values of the apparent standard partial molal Gibbs free energies and enthalpies of formation and the standard partial molal entropies and heat capacities of these organic species can be computed as a function of temperature at 1 bar using the equations of state adopted by Helgeson et al (1991). The pressure dependence of the thermodynamic properties can be calculated from a modified version of the Parameters From Group Contributions (PFGC) equation of state. To improve the accuracy of these predictions, critical evaluation of high-pressure density experiments reported in the literature was used in the present study to characterize b[sub j] as a function of pressure and temperature. The revised PFGC equation of state permits accurate calculation of the standard partial molal volumes of the major hydrocarbon species in the aliphatic, aromatic, and naphthenic fractions of crude oil, as well as fatty acids, phenols, and naphthenic acids at temperatures and pressures to 500 C and 5 kbar. Combining the revised PFGC equation of state and parameters with the standard partial molal properties of these species at one bar and those of aqueous species and minerals permits calculation of the apparent standard partial molal Gibbs Free energies of reaction, and thus equilibrium constants for a wide variety of chemical equilibria among organic liquids, solids, and gases, aqueous species, and minerals at temperatures and pressures characteristic of both diagenetic and low-grade metamorphic processes in the Earth's crust.

Aagaard, P. (Univ. of Oslo (Norway). Dept. of Geology); Oelkers, E.H. (Univ. Paul Sabatier, Toulouse (France). Lab. de Geochimie); Helgeson, H.C. (Univ. of California, Berkeley, CA (United States). Dept. of Geology and Geophysics)

1992-01-01T23:59:59.000Z

494

Soil Iodine Determination in Deccan Syneclise, India: Implications for Near Surface Geochemical Hydrocarbon Prospecting  

SciTech Connect (OSTI)

The association of iodine with organic matter in sedimentary basins is well documented. High iodine concentration in soils overlying oil and gas fields and areas with hydrocarbon microseepage has been observed and used as a geochemical exploratory tool for hydrocarbons in a few studies. In this study, we measure iodine concentration in soil samples collected from parts of Deccan Syneclise in the west central India to investigate its potential application as a geochemical indicator for hydrocarbons. The Deccan Syneclise consists of rifted depositional sites with Gondwana-Mesozoic sediments up to 3.5 km concealed under the Deccan Traps and is considered prospective for hydrocarbons. The concentration of iodine in soil samples is determined using ICP-MS and the values range between 1.1 and 19.3 ppm. High iodine values are characteristic of the northern part of the sampled region. The total organic carbon (TOC) content of the soil samples range between 0.1 and 1.3%. The TOC correlates poorly with the soil iodine (r{sup 2} < 1), indicating a lack of association of iodine with the surficial organic matter and the possibility of interaction between the seeping hydrocarbons and soil iodine. Further, the distribution pattern of iodine compares well with two surface geochemical indicators: the adsorbed light gaseous hydrocarbons (methane through butane) and the propane-oxidizing bacterial populations in the soil. The integration of geochemical observations show the occurrence of elevated values in the northern part of the study area, which is also coincident with the presence of exposed dyke swarms that probably serve as conduits for hydrocarbon microseepage. The corroboration of iodine with existing geological, geophysical, and geochemical data suggests its efficacy as one of the potential tool in surface geochemical exploration of hydrocarbons. Our study supports Deccan Syneclise to be promising in terms of its hydrocarbon prospects.

Mani, Devleena, E-mail: devleenatiwari@ngri.res.in [National Geophysical Research Institute (Council of Scientific and Industrial Research) (India); Kumar, T. Satish [Oil India Limited (India); Rasheed, M. A.; Patil, D. J.; Dayal, A. M.; Rao, T. Gnaneshwar; Balaram, V. [National Geophysical Research Institute (Council of Scientific and Industrial Research) (India)

2011-03-15T23:59:59.000Z

495

Observations of the Release of Non-methane Hydrocarbons from Fractured Shale  

Science Journals Connector (OSTI)

The organic content of shale has become of commercial interest as a source of hydrocarbons, owing to the development of hydraulic fracturing (“fracking”). ... These findings suggest that other hydrocarbons of commercial interest may be extracted from shale and open the possibility to optimize the “fracking” process, improving gas yields and reducing environmental impacts. ... This technique, termed hydraulic fracturing (commonly known as “fracking”), consists of drilling a well in the prospective shale units and injecting water under high pressure mixed with sand (?5%) and chemical additives (?0.2%) to fracture the rock and stimulate the release of hydrocarbons. ...

Roberto Sommariva; Robert S. Blake; Robert J. Cuss; Rebecca L. Cordell; Jon F. Harrington; Iain R. White; Paul S. Monks

2014-06-30T23:59:59.000Z

496

Method for silicon carbide production by reacting silica with hydrocarbon gas  

DOE Patents [OSTI]

A method is described for producing silicon carbide particles using a silicon source material and a hydrocarbon. The method is efficient and is characterized by high yield. Finely divided silicon source material is contacted with hydrocarbon at a temperature of 400.degree. C. to 1000.degree. C. where the hydrocarbon pyrolyzes and coats the particles with carbon. The particles are then heated to 1100.degree. C. to 1600.degree. C. to cause a reaction between the ingredients to form silicon carbide of very small particle size. No grinding of silicon carbide is required to obtain small particles. The method may be carried out as a batch process or as a continuous process.

Glatzmaier, Gregory C. (Boulder, CO)

1994-01-01T23:59:59.000Z

497

Method of treating emissions of a hybrid vehicle with a hydrocarbon absorber and a catalyst bypass system  

DOE Patents [OSTI]

A method of treating emissions from an internal combustion engine of a hybrid vehicle includes directing a flow of air created by the internal combustion engine when the internal combustion engine is spinning but not being fueled through a hydrocarbon absorber to collect hydrocarbons within the flow of air. When the hydrocarbon absorber is full and unable to collect additional hydrocarbons, the flow of air is directed through an electrically heated catalyst to treat the flow of air and remove the hydrocarbons. When the hydrocarbon absorber is not full and able to collect additional hydrocarbons, the flow of air is directed through a bypass path that bypasses the electrically heated catalyst to conserve the thermal energy stored within the electrically heated catalyst.

Roos, Bryan Nathaniel; Gonze, Eugene V; Santoso, Halim G; Spohn, Brian L

2014-01-14T23:59:59.000Z

498

Carbon monoxide line emission as a CMB foreground: tomography of the star-forming universe with different spectral resolutions  

E-Print Network [OSTI]

The rotational lines of carbon monoxide and the fine structure lines of CII and of the most abundant metals, emitted during the epoch of enhanced star formation in the universe, are redshifted in the frequency channels where the present-day and future CMB experiments are sensitive. We estimate the contribution to the CMB angular power spectrum by the emission in such lines in merging star-forming galaxies. We used the Lacey-Cole approach to characterize the distribution of the merging halos, together with a parametrization for the star formation rate in each of them. Using observational data from a sample of local, low-redshift, and high-redshift objects, we calibrated the luminosity in each line as a function of the star formation rate. We show that the correlation term arising from CO line emission is a significant source of foreground for CMB in a broad range of frequencies (in particular in the 20-60 GHz band) and for 1000

Mattia Righi; Carlos Hernandez-Monteagudo; Rashid Sunyaev

2008-07-24T23:59:59.000Z

499

Catalysis of hydrocarbon synthesis from CO and H{sub 2} on carbon membranes  

SciTech Connect (OSTI)

This paper describes the preparation of carbon membrane supports from polyacrylonitrile. The membranes were utilized for the preparation of cobalt catalysts. The catalysts were prepared by impregnating the membranes with a cobalt nitrate solution followed by drying on a water bath. The cobalt was sometimes introduced directly into the molding solution before the activation stage. The cobalt catalysts were utilized in the methanation of carbon monoxide. The products were dependent on the conditions utilized to obtain the carbon supports.

Lapidus, A.l.; Krylova, A.Yu.; Strupov, A.N.; Linkov, V.M.; Sanderson, R.D. [Rossiiskaya Akademiya, Nauk (Russian Federation)

1994-12-31T23:59:59.000Z

500

Hydrocarbon fouling of SCR during Premixed Charge Compression Ignition (PCCI) combustion  

Broader source: Energy.gov [DOE]

Analyzed the effects of higher hydrocarbon emissions from PCCI combustion on SCR catalysts in operating a light-duty 1.9-liter GM diesel engine in both PCCI and conventional combustion modes